DSHW-2025-000169

O
2024 Groundwater Monitoring
Report
MOOG, INC.
MOOG SALT LAKE OPERATIONS
2268 SOUTH 3270 WEST
WEST VALLEY CITY, UTAH

Intended for
State of Utah Department of Environmental Quality
Division of Waste Management and Radiation Control

Date
January 7, 2025

Project Number
1940110844

2024 Groundwater Monitoring Report
Moog, Inc. – West Valley City, Utah UTD 059513879

Prepared by:

Ramboll Americas Engineering Solutions, Inc.
1999 Broadway, Suite 2225
Denver, CO 80202
Tel: [phone]

Charles B. Goodwin, PG
Senior Managing Consultant

David Heinze, PE
Principal

2024 Groundwater Monitoring Report
Moog, Inc. – West Valley City, Utah UTD 059513879

CONTENTS
1. INTRODUCTION 1
2. GROUNDWATER MONITORING 1
2.1 Methodology 2
2.2 Groundwater Analytical Results 2
3. CONCLUSION 3
4. REFERENCES 3

TABLES
Table 1: Risk Based Levels for Groundwater Monitoring
Table 2: 2024 Groundwater Sampling Results (µg/L)

FIGURES
Figure 1: Site Location Map
Figure 2: Site Map with Groundwater Analytical Results

APPENDICES
Appendix A: Groundwater Sampling Field Data Forms
Appendix B: Laboratory Analytical Reports
2024 Groundwater Monitoring Report Moog, Inc. – West Valley City, Utah UTD 059513879

Page 1

1. INTRODUCTION
On behalf of Moog, Inc., Moog Salt Lake Operations, Ramboll Americas Engineering
Solutions, Inc. (Ramboll) has prepared this 2024 Groundwater Monitoring Report (Report)
for the Moog Salt Lake Operations facility located at 2268 South 3270 West, West Valley
City, Utah (Site). The Site and vicinity are illustrated on Figure 1. A Site plan of the
facility and surrounding properties is provided in Figure 2. The Site is under the
jurisdiction of the State of Utah Department of Environmental Quality (UDEQ), Division of
Waste Management and Radiation Control (DWMRC). The Site identification number is
UTD 059513879. This Report documents a groundwater monitoring event conducted in
Fall 2024 in accordance with the Site Management Plan – Revision 3 (2021).
Background
Shallow groundwater at the Site was found to be impacted in 1986 when an underground
tank was removed by E-Systems, the prior occupant of the Property before Moog, Inc.
The Site was subject to a Stipulated Consent Agreement dated June 5, 1991, issued by the
Executive Secretary—Division of Solid and Hazardous Waste (Executive Secretary) of the
Solid and Hazardous Waste Board to Moog, Inc. Institutional controls for managing soil
risk and engineering controls for managing groundwater risk were implemented. VOC
concentrations in groundwater decreased between 2000 and 2010 as a result of
engineering controls/groundwater remediation activities.
A Human Health Risk Assessment (HHRA) for the Site was updated in 2011 (Moog, 2011),
which was approved by the Executive Secretary. The 2011 HHRA evaluated the risk to
human health from current and potential future exposure to VOCs in shallow groundwater
at the Site. Risk Based Levels (RBLs) for Site contaminants of concern (COCs) in
groundwater, including trichloroethene (TCE), 1,2-dichloropropane (1,2-DCP), 1,1-
dichloroethane (1,1-DCA), and chloroform were established in the 2011 HHRA.
An updated Site Management Plan (Revision 3) was prepared, approved by the UDEQ, and
implemented in 2021. The Site Management Plan proposed a groundwater monitoring
schedule of every five years and incorporated the RBLs from the 2011 HHRA to evaluate
the current risk from groundwater impacts at the Site. The 2021 Site Management Plan
provided options for continued groundwater monitoring and termination of the monitoring.
Section 13 of the Site Management Plan stated that when groundwater sampling within the
Subject Area indicates that Federal maximum contaminant levels (MCLs) for applicable
constituents have been met for two consecutive sampling events, Moog may propose to
terminate groundwater monitoring. Starting in 2019, groundwater monitoring on a five-
year schedule has been initiated. A summary of the applicable RBLs, the maximum levels
evaluated in the 2011 HHRA, and Federal MCLs is included in Table 1.
An Environmental Covenant (EC) for the Site property was approved by the UDEQ and
implemented in 2021. The EC limits land use to commercial and restricts groundwater use
from the shallow unconfined aquifer at the Site.

2. GROUNDWATER MONITORING
The following sections describe the groundwater sampling methodology, and the analytical
results from the Fall 2024 monitoring event.
2024 Groundwater Monitoring Report Moog, Inc. – West Valley City, Utah UTD 059513879

Page 2

2.1 Methodology
Ramboll conducted a groundwater monitoring event at the Site on October 30, 2024. On-
Site well MW-61 and off-Site well MW-63 were sampled. MW-59 was unable to be located
on October 30th, including via use of a metal detector. The well was later found and
subsequently sampled on December 17, 2024. Prior to sampling, the monitoring wells
were gauged for depth to water and total depth with an electronic water level indicator.
The wells were purged and sampled with disposable bailers. Three well volumes were
purged from MW-59 and MW-63, and just under three volumes were purged from MW-61
due to the well being purged nearly dry and slow recharge. During the purge process,
water quality parameters including pH, temperature, dissolved oxygen (DO), oxidation-
reduction potential (ORP), specific conductivity, and turbidity were taken before and after
purging. Those readings and other purge information are included on the Groundwater
Sampling Field Data Forms in Appendix A.
Following the collection of groundwater quality field parameters, groundwater samples
were collected into laboratory-provided sample containers and packed on ice for shipment
to the analytical laboratory. For Quality Assurance/Quality Control (QA/QC) samples, a
field duplicate sample was collected from MW-61, a matrix spike and spike duplicate
(MS/MSD) sample was collected from MW-63, and a field blank sample was collected.
Additionally, one trip blank was maintained during the initial sampling event. When MW-
59 was sampled on December 17th, an additional field duplicate sample and field blank
were collected, and a trip blank was maintained with the samples. Groundwater and
QA/QC samples were submitted under proper chain of custody to Eurofins Environmental
Testing Laboratory (Eurofins) in Denver, Colorado for analysis of VOCs by USEPA Method
8260D. The data were reported with Level IV data quality objectives. Eurofins Denver is a
Utah-certified laboratory. The laboratory analytical reports for 2024 monitoring event are
included in Appendix B. The laboratory data has been validated.
All purge water and decontamination water from the sampling event was containerized on-
Site and will be disposed of at an off-Site disposal facility in accordance with State and
Federal regulations.
2.2 Groundwater Analytical Results
Table 2 summarizes the groundwater monitoring results and compares the data to
appliable RBLs and Federal MCLs. At MW-61, two VOCs were detected above the reporting
limit in the sample and in the corresponding field duplicate sample. The detected VOCs at
MW-61 included 180 micrograms per liter (ug/L) of 1,2-DCP and 9,900 ug/L of 1,1,2-
trichloro-1,2,2-trifluoroethane. MW-61 also had detections of 1,1-DCA, toluene and
xylene; however, the concentrations were below the laboratory reporting limit and above
the method detection limit. It should be noted that the MW-61 and field duplicate samples
were reported at a dilution due to the relatively high concentrations of 1,1,2-trichloro-
1,2,2-trifluoroethane in the samples. As a result, TCE, which had historically been
detected at MW-61, was unable to be reported as low as it’s Federal MCL of 5 ug/L. TCE
was not reported to be detected above the method detection limit of 15 ug/L. At on-Site
well MW-59, six VOCs were detected above the reporting limit in the sample and
corresponding field duplicate. These compounds included 1,1-DCA, 1,1-dichloroethene,
cis-1,2-dichloroethene, trans-1,2-dichloroethene, 1,2-DCP, and TCE. The TCE
concentration at MW-59 (35 ug/L) exceeded the Federal MCL. The concentrations of the
other compounds detected at MW-59 were below the MCLs (1,1-DCA does not have an
established MCL). No VOCs were detected at off-Site well MW-63. The groundwater
analytical results for the contaminants of concern are also shown on Figure 2.
2024 Groundwater Monitoring Report Moog, Inc. – West Valley City, Utah UTD 059513879

Page 3

No VOCs were detected in the October 30th field blank sample, and a trace detection of
tetrahydrofuran was reported in the trip blank. Trace concentrations of two VOCs were
detected above the reporting limit in the December 17th field blank, neither of which were
detected in the MW-59 sample and field duplicate. No VOCs were detected in the
December trip blank.
The concentrations of 1,2-DCP at MW-61 and TCE at MW-59 were above the Federal MCLs,
but well below the established On-Site Indoor Worker RBL. It should be noted that 1,2-
DCP was reportedly not used during Moog Inc.’s operations at the facility. In comparison
to the 2019 groundwater monitoring results, concentrations of 1,1-DCA, 1,2-DCP and
1,1,2-trichloro-1,2,2-trifluoroethane were lower at MW-61 in 2024. Also, TCE was
detected at 44 ug/L in 2019 at MW-61 but was not detected above the method detection
limit of 15 ug/L in 2024. The detected VOCs at MW-59 in 2024 were comparable to those
in 2019.

3. CONCLUSION
Groundwater monitoring results in Fall 2024 were generally similar to those in 2019, and
VOC concentrations at MW-61 were lower in 2024 compared to 2019. The detected VOC
concentrations at MW-59 in 2024 were similar to those in 2019. The VOCs concentrations
at MW-59 and MW-61 in 2024 were below their respective RBLs for groundwater
monitoring, per the 2021 Site Management Plan. The concentrations of TCE at MW-59 and
1,2-DCP at MW-61 were above the Federal MCLs. TCE was not detected above the
laboratory method detection limit at MW-61. Downgradient, off-Site well MW-63 did not
have VOCs detected, which indicates that residual VOCs in groundwater have remained on-
Site.
Section 11.b.ii of the 2021 Site Management Plan (Monitoring Schedule) states that
“groundwater monitoring shall continue on the Subject Area on a frequency of one
sampling event every five (5) years until Moog has demonstrated that the groundwater
monitoring may be terminated as specified in Section 13 of this SMP or as otherwise may
be established to the satisfaction of the Executive Secretary”. Section 13 (Termination of
Monitoring) states that “If at any time, groundwater sampling within the Subject Area
indicates that Federal MCLs for applicable constituents have been met for two consecutive
sampling events, Moog may propose to terminate groundwater monitoring”. Based on the
Site Management Plan requirements and the results from the 2024 monitoring event, an
additional five-year monitoring event will be conducted in 2029. Efforts will be made
achieve reporting TCE (and 1,2-DCP) to a level at or below the MCL of 5 ug/L for the MW-
61 sample. If VOC concentrations in groundwater continue to exhibit a decreasing trend in
2029, a request for terminating the groundwater monitoring will be made. In the
meantime, the Site Management Plan and EC will remain in place for the Site.

4. REFERENCES
Moog, Inc. (Moog), 2011. Updated Tier 2 Human Health Risk Assessment – Moog, Inc.,
Salt Lake Operations, West Valley City, Utah. March.
2024 Groundwater Monitoring Report Moog, Inc. – West Valley City, Utah UTD 059513879

Page 4

Moog, 2019. Site Management Plan Sampling Report, 2019 – Moog Salt Lake Operations,
Moog, Inc., West Valley City, Utah. September 13.
Moog, 2021a. Site Management Plan – Revision 3, Moog Salt Lake Operations, Moog Inc.,
West Valley City, Utah, March. March.
Moog, 2021b. Environmental Covenant. June 9.
Utah Department of Environmental Quality (UDEQ), 2021a. Revised Site Management
Plan – Revision 3, Moog Inc., West Valley City, Utah (approval letter). May 6.
UDEQ, 2021b. Revised Environmental Covenant (approval letter). August 5.
2024 Groundwater Monitoring Report Moog, Inc. – West Valley City, Utah UTD 059513879

TABLES

Table 1
Risk Based Levels for Groundwater Monitoring and Federal MCLs
Moog Salt Lake Operations, Moog, Inc.
West Valley City, Utah

Receptor COPC Risk Based Level
Associated with
Chemical Specific
Risk of 1E-06
(μg/L)1
Maximum Levels
Evaluated in
2011 HHRA
(μg/L)
Federal Maximum
Contaminant
Level (MCL)
(μg/L)
Offsite
Indoor
Worker
Trichloroethene 48 38 5
1,2-dichloropropane2 7.9 3.5 n/a
1,1-dichloroethane 50 2.7 5
Chloroform 9.1 0.46 n/a
Onsite
Indoor
Worker
Trichloroethene 4,551 38 5
1,2-dichloropropane2 3,297 260 n/a
1,1-dichloroethane 9,467 53 5
Chloroform 951 ND n/a
Onsite or
Offsite
Construction
Worker
Trichloroethene 11,806 38 5
1,2-dichloropropane2 2,391 260 n/a
1,1-dichloroethane 15,071 53 5
Chloroform 1,088 0.46 n/a
1Risk Based Levels taken from Site Management Plan – Revision 3, Moog Salt Lake Operations, Moog Inc., West Valley City, Utah, March 2021.
2 1,2-dichloropropane was reportedly not used at Moog. Concentrations of this chemical in groundwater may be a result of previous site occupants COPC – Contaminants of potential concern μg/L – micrograms per liter
ND – not detected above laboratory reporting limit
HHRA – Human Health Risk Assessment
MCL – Maximum Contaminant Level

Table 2
2024 Groundwater Monitoring Results (ug/L)
Moog Salt Lake Operations, Moog, Inc.
West Valley City, Utah
Location ID Sample ID Date Volatile Organic Compound (VOC)
Result 
(μg/L)MDL (μg/L) RL (μg/L)
Federal MCL 
(ug/L)
RBL On‐site Indoor 
Worker (μg/L)
RBL Off‐site Indoor 
Worker (μg/L)
RBL Onsite or Offsite 
Construction Worker 
(μg/L)
Chloroform ND 0.36 1.0 n/a 951 n/a 1,088
1,1‐Dichloroethane 4.5 0.22 1.0 n/a 9,467 n/a 15,071
1,1‐Dichloroethene 1.7 0.23 1.0 7 n/a n/a n/a
cis‐1,2‐Dichloroethene 33 0.32 1.0 70 n/a n/a n/a
trans‐1,2‐Dichloroethene 7.8 0.37 1.0 100 n/a n/a n/a
1,2‐Dichloropropane 3.4 0.24 1.0 5 3,297 n/a 2,391
Trichloroethene 35 0.30 1.0 5 4,551 n/a 11,806
All other VOCs ND n/a n/a n/a n/a n/a n/a
Chloroform ND 0.36 1.0 n/a 951 n/a 1,088
1,1‐Dichloroethane 4.6 0.22 1.0 n/a 9,467 n/a 15,071
1,1‐Dichloroethene 1.5 0.23 1.0 7 n/a n/a n/a
cis‐1,2‐Dichloroethene 33 0.32 1.0 70 n/a n/a n/a
trans‐1,2‐Dichloroethene 8.0 0.37 1.0 100 n/a n/a n/a
1,2‐Dichloropropane 3.3 0.24 1.0 5 3,297 n/a 2,391
Trichloroethene 42 0.30 1.0 5 4,551 n/a 11,806
All other VOCs ND n/a n/a n/a n/a n/a n/a
Chloroform ND 18 50 n/a 951 n/a 1,088
1,1‐Dichloroethane 44 J 11 50 n/a 9,467 n/a 15,071
1,2‐Dichloropropane 180 12 50 5 3,297 n/a 2,391
Trichloroethene ND(1)15 50 5 4,551 n/a 11,806
1,1,2‐Trichloro‐1,2,2‐trifluoroethane 9,900 J 36 150 n/a n/a n/a n/a
Toluene 33 J 16 50 n/a n/a n/a n/a
Xylene 8.9 J 5.7 50 n/a n/a n/a n/a
All other VOCs ND n/a n/a n/a n/a n/a n/a
Chloroform ND 36 100 n/a 951 n/a 1,088
1,1‐Dichloroethane ND 22 100 n/a 9,467 n/a 15,071
1,2‐Dichloropropane 150 24 100 5 3,297 n/a 2,391
Trichloroethene ND(1)30 100 5 4,551 n/a 11,806
1,1,2‐Trichloro‐1,2,2‐trifluoroethane 22,000 J 360 1,500 n/a n/a n/a n/a
Toluene 77 J 32 100 n/a n/a n/a n/a
All other VOCs ND n/a n/a n/a n/a n/a n/a
Chloroform ND 0.36 1.0 n/a n/a 9.1 1,088
1,1‐Dichloroethane ND 0.22 1.0 n/a n/a 50 15,071
1,2‐Dichloropropane ND 0.24 1.0 5 n/a 7.9 2,391
Trichloroethene ND 0.30 1.0 5 n/a 48 11,806
All VOCs ND n/a n/a n/a n/a n/a n/a
Field Blank FB‐01 10/30/24 All VOCs ND n/a n/a n/a n/a n/a n/a
Bromoform 3.1 0.25 2.0 n/a n/a n/a n/a
Trihalomethanes 4.6 0.19 1.0 n/a n/a n/a n/a
All other VOCs ND n/a n/a n/a n/a n/a n/a
Tetrahydrofuran 1.2 J 0.84 7.0 n/a n/a n/a n/a
All other VOCs ND n/a n/a n/a n/a n/a n/a
Trip Blank Trip Blank 12/17/24 All VOCs ND n/a n/a n/a n/a n/a n/a
Samples analyzed for VOCs using EPA Method 8260D.
Results reported in micrograms per liter (ug/L).
J ‐ Estimated concentration below RL but above MDL, or due to field duplicate precision
MCL ‐ Maximum Contaminant Level
MDL ‐ Method Detection Limit
n/a ‐ not appliable, or not established
ND ‐ Not Detected
RBL ‐ Risk Based Level, associated with chemical specific risk of 1E‐06 (Site Management Plan ‐ Revision 3, March 2021)
RL ‐ Reporting Limit
VOC ‐ Volatile Organic Compound
BOLD ‐ detections above RL
(1) Trichloroethene (TCE) result not detected above RL or MDL; however, laboratory was unable to report TCE at a concentration as low as the Federal MCL of 5 ug/L.
12/17/24
MW‐59
MW‐59‐241217 12/17/24
DS‐02‐241217 
(field duplicate 
sample from MW‐
59)
12/17/24
Off‐site Monitoring Well
MW‐63 MW‐63‐241030 10/30/24
Quality Control/Quality Assurance Samples 
Trip Blank Trip Blank 10/30/24
Field Blank FB‐02
On‐site Monitoring Wells
MW‐61
MW‐61‐241030 10/30/24
DS‐01 (field 
duplicate sample 
from MW‐61)
10/30/24
2024 Groundwater Monitoring Report
Moog, Inc. – West Valley City, Utah UTD 059513879

FIGURES

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Map Scale: 1:24,000 | Map Center: 111°58'15"W 40°43'16"N
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Service Layer Credits: World Topographic Map: County of Salt Lake, Utah Geospatial Resource Center, Esri, TomTom, Garmin, SafeGraph, GeoTechnologies, Inc, METI/NASA, USGS, Bureau of Land Management, EPA, NPS, US CensusBureau, USDA, USFWS
World Hillshade: Esri, NASA, NGA, USGS, FEMA
0 2,0001,000
Feet
RAMBOLL AMERICAS
ENGINEERING SOLUTIONS, INC.
A RAMBOLL COMPANY
FIGURE 01
Moog Salt Lake Operations
2268 S 3270 WWest Valley City, Utah
Approximate Site Boundary SITE LOCATION MAP
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LAST SAVE: 1/2/2025 1:51 PM
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!Ñ<
!Ñ<
!Ñ<!Ñ<
!Ñ<
!Ñ<
!Ñ<
!Ñ<
MW-54
MW-55
MW-62
MW-57
MW-58
MW-60
MW-61
MW-65
MW-63
MW-64
MW-53R
MW-59
PROJECT: 1940110844 | DATED: 1/2/2025 | DESIGNER: ATAYLOR C:\Users\ataylor\Ramboll\Western GIS Graphics Portal - General\Projects\Moog\Salt Lake City\03_GIS\20241118_GroundwaterResults\20241118_GroundwaterResults.aprx\Figure 02 - Site Map with Groundwater Analytical Results
Service Layer Credits: Bing Maps Hybrid: © 2024 Microsoft Corporation © 2024 Maxar ©CNES (2024) Distribution Airbus DS © 2024 TomTom
0 200100
Feet
RAMBOLL AMERICAS
ENGINEERING SOLUTIONS, INC.
A RAMBOLL COMPANY
FIGURE 02
Moog Salt Lake Operations
2268 S 3270 W
West Valley City, Utah
Aproximate Site Boundary
Moog Interceptor Trench
!Ñ<Monitoring Well
!Ñ<Groundwater Monitoring Location (2021 Site
Management Plan)
SITE MAP WITH GROUNDWATER
ANALYTICAL RESULTS
!á(N
Analyte 10/30/2024
1,1-DCA 44J
1,2-DCP 180
Chloroform ND*
TCE ND*
MW-61
Analyte 10/30/2024
1,1-DCA ND
1,2-DCP ND
Chloroform ND
TCE ND
MW-63
Analyte 12/17/2024
1,1-DCA 4.5
1,2-DCP 3.4
Chloroform ND
TCE 35
MW-59
Notes
1. Groundwater concentrations reported in µg/L.
2. Only Site contaminants of potential concern
depicted, per the 2021 Site Management Plan.
3. DCA – Dichloroethane
4. DCP - Dichloropropane
5. J – Estimated value
6. ND – Not Detected
7. ND* - Not Detected, elevated reporting limit8. TCE – Trichloroethene
2024 Groundwater Monitoring Report
Moog, Inc. – West Valley City, Utah UTD 059513879

APPENDIX A GROUNDWATER SAMPLING FIELD DATA FORMS

Site:Well #:
Location: Sample I.D. #:
Job #:
Sample Time:
Sample Date:
Personnel Present During Sampling:
Well/Purging Information:
Purging method: 1) Well depth (from top of measuring point) (1) (ft)
Sampling method: 2) Depth to water prior to purging (2) (ft)
Tubing material: 3) Length of water column in well: #1 - #2 = (3) (ft)
Screen Length:ft.4) Volume of water standing in well (4) (gal)
ft. below measuring point multiply #3 by 0.1632 for 2" ID and 0.0408 for 1" ID wells.
Pump intake set at: ft. below measuring point (Required for well volume purging approach only)
Casing radius: in. 5) Number of purge volumes required (5)
Well material: PVC / #316 SS / Galv. Steel 6) Maximum volume to be purged: #4 x #5 = (6) (gal)
Other:
Bladder Pump Controller Settings (if used):Recharge time: (sec) Pressure: -- (psi)
Discharge time: (sec) Cycles per minute: --
Stabilization:
Depth to Pumping ORP Conductance Turbidity DO
Time Water (ft) Rate (mL/min) Temp (°C) pH (mV) (mS/cm) (NTU) (%)
4.43 -- 17.9 7.44 155.1 1.07 2.8 33.0
13.25 -- 19.8 7.74 90.6 1.19 14.5 47.2
Sample Volume
40 mL
Comments/Observations/Weather Conditions:
Low Flow Sampling: Not Applicable
2
--
Pumped (mL)
--11:10
4.5 gallons purged at time of sample to avoid well becoming dry.
GROUND WATER SAMPLING
FIELD DATA FORM
Moog
Salt Lake City, Utah
1940110844
MW-61
MW-61-241030
MS/MSD : Yes/No; Dup: Yes/No, Name: DS-01QA/QC Samples:
10/30/2024
11:10
--11:00
Ramboll - Brian Mulroy
Volume
--
1.86
3
15.81
4.43
Top of well screen;
8260D
Method
HCl
Preservation
5.57
Bailer
Bailer
11.38
Number of BottlesSample Parameter
6voa
Bottle Type
VOC
# Confidential Ramboll
Site:Well #:
Location: Sample I.D. #:
Job #:
Sample Time:
Sample Date:
Personnel Present During Sampling:
Well/Purging Information:
Purging method: 1) Well depth (from top of measuring point) (1) (ft)
Sampling method: 2) Depth to water prior to purging (2) (ft)
Tubing material: 3) Length of water column in well: #1 - #2 = (3) (ft)
Screen Length:ft.4) Volume of water standing in well (4) (gal)
ft. below measuring point multiply #3 by 0.1632 for 2" ID and 0.0408 for 1" ID wells.
Pump intake set at: ft. below measuring point (Required for well volume purging approach only)
Casing radius: in. 5) Number of purge volumes required (5)
Well material: PVC / #316 SS / Galv. Steel 6) Maximum volume to be purged: #4 x #5 = (6) (gal)
Other:
Bladder Pump Controller Settings (if used):Recharge time: (sec) Pressure: -- (psi)
Discharge time: (sec) Cycles per minute: --
Stabilization:
Depth to Pumping ORP Conductance Turbidity DO
Time Water (ft) Rate (mL/min) Temp (°C) pH (mV) (mS/cm) (NTU) (%)
4.34 -- 18.0 6.93 -145.4 5.30 68.5 35.5
9.25 -- 16.9 7.47 -102.1 7.23 430.8 42.7
Sample Volume
40 mL
Comments/Observations/Weather Conditions:
Low Flow Sampling: Not Applicable
Water was black in color and had a hydrocarbon odor. Floating particles in water.
Sample Parameter Method Bottle Type Number of Bottles Preservation
VOC 8260D voa 9 HCl
Volume
Pumped (mL)
12:00 --
12:15 --
1.45
Top of well screen;
2 3
4.34
--
--
8.86
1940110844 QA/QC Samples: MS/MSD : Yes/No; Dup: Yes/No, Name: MW-63
12:20
10/30/2024
Ramboll - Brian Mulroy
Bailer 13.20
Bailer 4.34
GROUND WATER SAMPLING
FIELD DATA FORM
Moog MW-63
Salt Lake City, Utah MW-63-241030
# Confidential Ramboll
Site:Well #:
Location: Sample I.D. #:
Job #:
Sample Time:
Sample Date:
Personnel Present During Sampling:
Well/Purging Information:
Purging method: 1) Well depth (from top of measuring point) (1) (ft)
Sampling method: 2) Depth to water prior to purging (2) (ft)
Tubing material: 3) Length of water column in well: #1 - #2 = (3) (ft)
Screen Length:ft.4) Volume of water standing in well (4) (gal)
ft. below measuring point multiply #3 by 0.1632 for 2" ID and 0.0408 for 1" ID wells.
Pump intake set at: ft. below measuring point (Required for well volume purging approach only)
Casing radius: in. 5) Number of purge volumes required (5)
Well material: PVC / #316 SS / Galv. Steel 6) Maximum volume to be purged: #4 x #5 = (6) (gal)
Other:
Bladder Pump Controller Settings (if used):Recharge time: (sec) Pressure: -- (psi)
Discharge time: (sec) Cycles per minute: --
Stabilization:
Depth to Pumping ORP Conductance Turbidity DO
Time Water (ft) Rate (mL/min) Temp (°C) pH (mV) (mS/cm) (NTU) (%)
5.70 n/a 12.9 8.00 -164.0 7.194 NR 8.0
8.90 n/a 15.2 7.74 -143.4 8.900 NR 14.1
Sample Volume
40 mL
Comments/Observations/Weather Conditions:
Low Flow Sampling: Not Applicable
Purging started @ 0854.
Duplicate taken. Field blank collected.
Good recharge, no odor, water clear w/ sediment at botttom
Sample Parameter Method Bottle Type Number of Bottles Preservation
VOC 8260D voa 3 HCl
Volume
Pumped
0847 0 gal
0908 5 gal
1.55
Top of well screen;
2 3
4.65
--
--
9.52
1940110844 QA/QC Samples:Duplicate DS-02
9:15
12/17/2024
Ramboll - Drew Coffin
Bailer 15.22
Bailer 5.70
GROUND WATER SAMPLING
FIELD DATA FORM
Moog MW-59
West Valley City, Utah MW-59-241217
# Confidential Ramboll
2024 Groundwater Monitoring Report
Moog, Inc. – West Valley City, Utah UTD 059513879

APPENDIX B LABORATORY ANALYTICAL REPORT
ANALYTICAL REPORT
PREPARED FOR
Attn: Charles Goodwin
Ramboll Americas Engineering Solutions
1999 Broadway
Suite 2225
Denver CO 80202
Generated 11/15/2024 3:53 PM
JOB DESCRIPTION
Moog-SLC, UT
JOB NUMBER
280-198899-1
See page two for job notes and contact information.
Arvada CO 80002
4955 Yarrow Street
Eurofins Denver
Page 1 of 777
Eurofins Denver
Eurofins Denver is a laboratory within TestAmerica Laboratories, Inc., a company within Eurofins Environment Testing Group of Companies
Job Notes
This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the
samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this
page.
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the
methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written
approval of the laboratory. All questions should be directed to the Eurofins TestAmerica Project Manager.
Authorization
Generated
11/15/2024 3:53 PM
Authorized for release by
Dylan T Bieniulis, Project Manager I
[e-mail]
303 736-0138
11/15/2024
3:53:55 PM
Page 2 of 777
Table of Contents
Cover Title Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Data Summaries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6
Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .8
Default Detection Limits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .18
Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .20
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .21
QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .36
Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .37
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .38
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .39
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .40
Manual Integration Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .41
Reagent Traceability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .50
COAs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .75
Organic Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .143
GC/MS VOA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .143
8260D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .143
8260D QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .144
8260D Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .167
Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .232
8260D ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .232
8260D CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .636
Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .664
11/15/2024
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Page 3 of 777
Table of Contents
8260D Tune Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .664
8260D Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .689
8260D LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .709
8260D MS/MSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .741
8260D Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .759
8260D Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .765
Shipping and Receiving Documents . . . . . . . . . . . . . . . . . . . . . . . . . . .774
Client Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .775
Sample Receipt Checklist . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .777
11/15/2024
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Page 4 of 777
Definitions/Glossary
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Qualifiers
GC/MS VOA
Qualifier Description
*1 LCS/LCSD RPD exceeds control limits.
Qualifier
F1 MS and/or MSD recovery exceeds control limits.
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Glossary
These commonly used abbreviations may or may not be present in this report.
☼Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins Denver
11/15/2024
3:53:55 PM
Page 5 of 777
Job Narrative
280-198899-1
Analytical test results meet all requirements of the associated regulatory program listed on the
Accreditation/Certification Summary Page unless otherwise noted under the individual analysis.Data qualifiers and/or
narrative comments are included to explain any exceptions,if applicable.
Matrix QC may not be reported if insufficient sample is provided or site-specific QC samples were not
submitted.In these situations,to demonstrate precision and accuracy at a batch level,a LCS/LCSD may be
performed,unless otherwise specified in the method.
Surrogate and/or isotope dilution analyte recoveries (if applicable)which are outside of the QC window are
confirmed unless attributed to a dilution or otherwise noted in the narrative.
Regulated compliance samples (e.g.SDWA,NPDES)must comply with the associated agency requirements/permits.
Receipt
The samples were received on 10/31/2024 9:10 AM.Unless otherwise noted below,the samples arrived in good
condition,and,where required,properly preserved and on ice.The temperature of the cooler at receipt time was
0.9°C.
Method 8260D -Volatile Organic Compounds by GC/MSSamplesMW-61-241030 (280-198899-2),MW-63-241030 (280-198899-3),MW-63-241030 (280-198899-3MS),MW-63-241030 (280-198899-3MSD),FB-01 (280-198899-4),DS-01 (280-198899-5)and Trip Blank (280-198899-6)
were analyzed for Volatile Organic Compounds by GC/MS.The samples were analyzed on 11/11/2024 and
11/13/2024.
Samples MW-61-241030 (280-198899-2)[50x],DS-01 (280-198899-5)[100x]and DS-01 (280-198899-5)[500x]
required dilution prior to analysis.The reporting limits have been adjusted accordingly.
The matrix spike /matrix spike duplicate (MS/MSD)recoveries for analytical batch 280-674451 were outside control
limits for one or more analytes.See QC Sample Results for detail.Sample matrix interference and/or non-
homogeneity are suspected because the associated laboratory control sample (LCS)recovery is within acceptance
limits.The associated samples are:MW-63-241030 (280-198899-3[MS])and MW-63-241030 (280-198899-3[MSD]).
The following compounds were outside control limits of 20%D in the continuing calibration verification (CCV)
associated with batch 280-674451:Dichlorodifluoromethane (-30.6%D).This compound is considered a poor
performer and has recovered within LCS/LCSD limits.The following samples are affected:MW-61-241030
(280-198899-2),MW-63-241030 (280-198899-3),FB-01 (280-198899-4),DS-01 (280-198899-5),Trip Blank
(280-198899-6)and (CCV 280-674451/2).
The RPD of the laboratory control sample (LCS)and laboratory control sample duplicate (LCSD)for analytical batch
280-674451 recovered outside control limits for the following analyte:Bromomethane (RPD 43,limit 40).Laboratory
control sample /laboratory control sample duplicate (LCS/LCSD)percent recovery is in control for affected analyte.
Affected analyte was not detected in the associated samples.The associated samples are:MW-61-241030
(280-198899-2),MW-63-241030 (280-198899-3),FB-01 (280-198899-4),DS-01 (280-198899-5),Trip Blank
(280-198899-6)and (LCSD 280-674451/5).
Trip blank sample Trip Blank (280-198899-6)contained a detection for tetrahydrofuran above the MDL but less than1/2 of the RL.The associated method blank (MB)and all associated samples in this job do not contain detections for
tetrahydrofuran.
The continuing calibration verification (CCV)associated with batch 280-674813 recovered outside the control limit
20%D for Bromomethane -25.6%D.This analyte is a poor performer.The LCS/LCSD recovered within control limits
therefore the data were reported:DS-01 (280-198899-5)and (CCV 280-674813/2).
The method requirement for no headspace was not met.The following volatile sample was analyzed at a 500x dilution
in batch 674813 with significant headspace in the sample container:DS-01 (280-198899-5).Significant headspace is
defined as a bubble greater than 6 mm in diameter.
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Page 6 of 777
Detection Summary
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Client Sample ID: MW-61-241030 Lab Sample ID: 280-198899-2
Toluene
RL
50 ug/L
MDL
16
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA50J338260D
1,1-Dichloroethane 50 ug/L11 Total/NA5044J8260D
1,1,2-Trichloro-1,2,2-trifluoroethane 150 ug/L36 Total/NA5099008260D
1,2-Dichloropropane 50 ug/L12 Total/NA501808260D
o-Xylene 50 ug/L5.7 Total/NA508.9 J 8260D
Xylenes, Total 50 ug/L5.7 Total/NA508.9 J 8260D
Total BTEX 50 ug/L7.2 Total/NA5042J8260D
Client Sample ID: MW-63-241030 Lab Sample ID: 280-198899-3
No Detections.
Client Sample ID: FB-01 Lab Sample ID: 280-198899-4
No Detections.
Client Sample ID: DS-01 Lab Sample ID: 280-198899-5
Toluene
RL
100 ug/L
MDL
32
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA100J778260D
1,2-Dichloropropane 100 ug/L24 Total/NA1001508260D
Total BTEX 100 ug/L14 Total/NA10077J8260D
1,1,2-Trichloro-1,2,2-trifluoroethane -
DL
1500 ug/L360 Total/NA500220008260D
Client Sample ID: Trip Blank Lab Sample ID: 280-198899-6
Tetrahydrofuran
RL
7.0 ug/L
MDL
0.84
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1J1.2 8260D
Eurofins Denver
This Detection Summary does not include radiochemical test results.
11/15/2024
3:53:55 PM
Page 7 of 777
Client Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Lab Sample ID: 280-198899-2Client Sample ID: MW-61-241030
Matrix: WaterDate Collected: 10/30/24 11:10
Date Received: 10/31/24 09:10
Method: SW846 8260D - Volatile Organic Compounds by GC/MS
RL MDL
ND 50 7.2 ug/L 11/11/24 12:12 50
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Ethylbenzene
50 6.3 ug/L 11/11/24 12:12 50NDStyrene
50 7.8 ug/L 11/11/24 12:12 50NDcis-1,3-Dichloropropene
50 7.2 ug/L 11/11/24 12:12 50NDtrans-1,3-Dichloropropene
50 9.2 ug/L 11/11/24 12:12 50NDN-Propylbenzene
50 12 ug/L 11/11/24 12:12 50NDn-Butylbenzene
50 11 ug/L 11/11/24 12:12 50ND4-Chlorotoluene
50 19 ug/L 11/11/24 12:12 50ND1,4-Dichlorobenzene
50 9.2 ug/L 11/11/24 12:12 50NDEthylene Dibromide
100 23 ug/L 11/11/24 12:12 50ND3-Chloro-1-propene
50 14 ug/L 11/11/24 12:12 50ND1,2-Dichloroethane
150 18 ug/L 11/11/24 12:12 50NDVinyl acetate
250 49 ug/L 11/11/24 12:12 50ND4-Methyl-2-pentanone (MIBK)
50 6.1 ug/L 11/11/24 12:12 50ND1,3,5-Trimethylbenzene
50 9.5 ug/L 11/11/24 12:12 50NDBromobenzene
50 16 ug/L 11/11/24 12:12 50NDMethylcyclohexane
50 16 ug/L 11/11/24 12:12 5033JToluene
50 4.6 ug/L 11/11/24 12:12 50NDChlorobenzene
350 42 ug/L 11/11/24 12:12 50NDTetrahydrofuran
100 8.2 ug/L 11/11/24 12:12 50NDHexane
50 22 ug/L 11/11/24 12:12 50NDCyclohexane
50 29 ug/L 11/11/24 12:12 50ND1,2,4-Trichlorobenzene
50 14 ug/L 11/11/24 12:12 50NDChlorodibromomethane
50 20 ug/L 11/11/24 12:12 50NDTetrachloroethene
50 10 ug/L 11/11/24 12:12 50NDsec-Butylbenzene
50 8.7 ug/L 11/11/24 12:12 50ND1,3-Dichloropropane
50 16 ug/L 11/11/24 12:12 50NDcis-1,2-Dichloroethene
50 18 ug/L 11/11/24 12:12 50NDtrans-1,2-Dichloroethene
250 13 ug/L 11/11/24 12:12 50NDMethyl tert-butyl ether
100 18 ug/L 11/11/24 12:12 50NDm-Xylene & p-Xylene
50 17 ug/L 11/11/24 12:12 50ND1,3-Dichlorobenzene
50 11 ug/L 11/11/24 12:12 50NDCarbon tetrachloride
50 9.5 ug/L 11/11/24 12:12 50ND1,1-Dichloropropene
250 41 ug/L 11/11/24 12:12 50ND2-Hexanone
50 8.4 ug/L 11/11/24 12:12 50ND2,2-Dichloropropane
100 18 ug/L 11/11/24 12:12 50NDEthyl ether
50 7.8 ug/L 11/11/24 12:12 50ND1,1,1,2-Tetrachloroethane
750 330 ug/L 11/11/24 12:12 50NDAcetone
50 18 ug/L 11/11/24 12:12 50NDChloroform
50 7.2 ug/L 11/11/24 12:12 50NDBenzene
50 20 ug/L 11/11/24 12:12 50ND1,1,1-Trichloroethane
250 120 ug/L 11/11/24 12:12 50ND*1Bromomethane
100 11 ug/L 11/11/24 12:12 50NDChloromethane
250 130 ug/L 11/11/24 12:12 50NDIodomethane
50 17 ug/L 11/11/24 12:12 50NDDibromomethane
50 20 ug/L 11/11/24 12:12 50NDChlorobromomethane
100 32 ug/L 11/11/24 12:12 50NDChloroethane
50 11 ug/L 11/11/24 12:12 50NDVinyl chloride
100 47 ug/L 11/11/24 12:12 50NDMethylene Chloride
Eurofins Denver
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Client Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Lab Sample ID: 280-198899-2Client Sample ID: MW-61-241030
Matrix: WaterDate Collected: 10/30/24 11:10
Date Received: 10/31/24 09:10
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
ND 100 13 ug/L 11/11/24 12:12 50
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Carbon disulfide
100 12 ug/L 11/11/24 12:12 50NDBromoform
50 9.4 ug/L 11/11/24 12:12 50NDDichlorobromomethane
50 11 ug/L 11/11/24 12:12 5044J1,1-Dichloroethane
50 12 ug/L 11/11/24 12:12 50ND1,1-Dichloroethene
100 9.9 ug/L 11/11/24 12:12 50NDTrichlorofluoromethane
100 15 ug/L 11/11/24 12:12 50NDDichlorodifluoromethane
150 36 ug/L 11/11/24 12:12 5099001,1,2-Trichloro-1,2,2-trifluoroetha
ne
50 12 ug/L 11/11/24 12:12 501801,2-Dichloropropane
500 230 ug/L 11/11/24 12:12 50ND2-Butanone (MEK)
50 14 ug/L 11/11/24 12:12 50ND1,1,2-Trichloroethane
50 15 ug/L 11/11/24 12:12 50NDTrichloroethene
250 82 ug/L 11/11/24 12:12 50NDMethyl acetate
50 11 ug/L 11/11/24 12:12 50ND1,1,2,2-Tetrachloroethane
200 60 ug/L 11/11/24 12:12 50ND1,2,3-Trichlorobenzene
100 26 ug/L 11/11/24 12:12 50NDHexachlorobutadiene
150 50 ug/L 11/11/24 12:12 50NDNaphthalene
50 5.7 ug/L 11/11/24 12:12 508.9 Jo-Xylene
50 17 ug/L 11/11/24 12:12 50ND2-Chlorotoluene
50 7.2 ug/L 11/11/24 12:12 50ND1,2-Dichlorobenzene
50 7.5 ug/L 11/11/24 12:12 50ND1,2,4-Trimethylbenzene
250 21 ug/L 11/11/24 12:12 50ND1,2-Dibromo-3-Chloropropane
130 14 ug/L 11/11/24 12:12 50ND1,2,3-Trichloropropane
150 9.6 ug/L 11/11/24 12:12 50NDEthyl methacrylate
50 8.9 ug/L 11/11/24 12:12 50NDtert-Butylbenzene
50 7.9 ug/L 11/11/24 12:12 50NDIsopropylbenzene
50 9.3 ug/L 11/11/24 12:12 50ND4-Isopropyltoluene
50 5.7 ug/L 11/11/24 12:12 508.9 JXylenes, Total
50 16 ug/L 11/11/24 12:12 50ND1,2-Dichloroethene, Total
50 7.2 ug/L 11/11/24 12:12 50ND1,3-Dichloropropene, Total
50 9.4 ug/L 11/11/24 12:12 50NDTrihalomethanes, Total
50 7.2 ug/L 11/11/24 12:12 5042JTotal BTEX
1,2-Dichloroethane-d4 (Surr)91 70 -127 11/11/24 12:12 50
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)93 11/11/24 12:12 5077-120
Toluene-d8 (Surr)108 11/11/24 12:12 5080-125
4-Bromofluorobenzene (Surr)94 11/11/24 12:12 5078-120
Lab Sample ID: 280-198899-3Client Sample ID: MW-63-241030
Matrix: WaterDate Collected: 10/30/24 12:20
Date Received: 10/31/24 09:10
Method: SW846 8260D - Volatile Organic Compounds by GC/MS
RL MDL
ND 1.0 0.14 ug/L 11/11/24 09:25 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Ethylbenzene
1.0 0.13 ug/L 11/11/24 09:25 1NDStyrene
1.0 0.16 ug/L 11/11/24 09:25 1NDcis-1,3-Dichloropropene
1.0 0.14 ug/L 11/11/24 09:25 1NDF1trans-1,3-Dichloropropene
Eurofins Denver
11/15/2024
3:53:55 PM
Page 9 of 777
Client Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Lab Sample ID: 280-198899-3Client Sample ID: MW-63-241030
Matrix: WaterDate Collected: 10/30/24 12:20
Date Received: 10/31/24 09:10
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
ND 1.0 0.18 ug/L 11/11/24 09:25 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
N-Propylbenzene
1.0 0.23 ug/L 11/11/24 09:25 1NDF1n-Butylbenzene
1.0 0.21 ug/L 11/11/24 09:25 1ND4-Chlorotoluene
1.0 0.39 ug/L 11/11/24 09:25 1ND1,4-Dichlorobenzene
1.0 0.18 ug/L 11/11/24 09:25 1NDEthylene Dibromide
2.0 0.46 ug/L 11/11/24 09:25 1ND3-Chloro-1-propene
1.0 0.28 ug/L 11/11/24 09:25 1ND1,2-Dichloroethane
3.0 0.36 ug/L 11/11/24 09:25 1NDVinyl acetate
5.0 0.98 ug/L 11/11/24 09:25 1ND4-Methyl-2-pentanone (MIBK)
1.0 0.12 ug/L 11/11/24 09:25 1ND1,3,5-Trimethylbenzene
1.0 0.19 ug/L 11/11/24 09:25 1NDBromobenzene
1.0 0.31 ug/L 11/11/24 09:25 1NDF1Methylcyclohexane
1.0 0.32 ug/L 11/11/24 09:25 1NDToluene
1.0 0.092 ug/L 11/11/24 09:25 1NDChlorobenzene
7.0 0.84 ug/L 11/11/24 09:25 1NDTetrahydrofuran
2.0 0.16 ug/L 11/11/24 09:25 1NDF1Hexane
1.0 0.44 ug/L 11/11/24 09:25 1NDCyclohexane
1.0 0.58 ug/L 11/11/24 09:25 1NDF11,2,4-Trichlorobenzene
1.0 0.28 ug/L 11/11/24 09:25 1NDChlorodibromomethane
1.0 0.40 ug/L 11/11/24 09:25 1NDTetrachloroethene
1.0 0.20 ug/L 11/11/24 09:25 1NDF1sec-Butylbenzene
1.0 0.17 ug/L 11/11/24 09:25 1ND1,3-Dichloropropane
1.0 0.32 ug/L 11/11/24 09:25 1NDcis-1,2-Dichloroethene
1.0 0.37 ug/L 11/11/24 09:25 1NDtrans-1,2-Dichloroethene
5.0 0.25 ug/L 11/11/24 09:25 1NDMethyl tert-butyl ether
2.0 0.36 ug/L 11/11/24 09:25 1NDm-Xylene & p-Xylene
1.0 0.33 ug/L 11/11/24 09:25 1ND1,3-Dichlorobenzene
1.0 0.23 ug/L 11/11/24 09:25 1NDCarbon tetrachloride
1.0 0.19 ug/L 11/11/24 09:25 1ND1,1-Dichloropropene
5.0 0.81 ug/L 11/11/24 09:25 1ND2-Hexanone
1.0 0.17 ug/L 11/11/24 09:25 1ND2,2-Dichloropropane
2.0 0.35 ug/L 11/11/24 09:25 1NDEthyl ether
1.0 0.16 ug/L 11/11/24 09:25 1ND1,1,1,2-Tetrachloroethane
15 6.6 ug/L 11/11/24 09:25 1NDAcetone
1.0 0.36 ug/L 11/11/24 09:25 1NDChloroform
1.0 0.14 ug/L 11/11/24 09:25 1NDBenzene
1.0 0.39 ug/L 11/11/24 09:25 1ND1,1,1-Trichloroethane
5.0 2.4 ug/L 11/11/24 09:25 1ND*1Bromomethane
2.0 0.23 ug/L 11/11/24 09:25 1NDChloromethane
5.0 2.6 ug/L 11/11/24 09:25 1NDIodomethane
1.0 0.34 ug/L 11/11/24 09:25 1NDDibromomethane
1.0 0.40 ug/L 11/11/24 09:25 1NDChlorobromomethane
2.0 0.64 ug/L 11/11/24 09:25 1NDChloroethane
1.0 0.23 ug/L 11/11/24 09:25 1NDVinyl chloride
2.0 0.94 ug/L 11/11/24 09:25 1NDMethylene Chloride
2.0 0.26 ug/L 11/11/24 09:25 1NDCarbon disulfide
2.0 0.25 ug/L 11/11/24 09:25 1NDBromoform
1.0 0.19 ug/L 11/11/24 09:25 1NDDichlorobromomethane
1.0 0.22 ug/L 11/11/24 09:25 1ND1,1-Dichloroethane
Eurofins Denver
11/15/2024
3:53:55 PM
Page 10 of 777
Client Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Lab Sample ID: 280-198899-3Client Sample ID: MW-63-241030
Matrix: WaterDate Collected: 10/30/24 12:20
Date Received: 10/31/24 09:10
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
ND 1.0 0.23 ug/L 11/11/24 09:25 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1-Dichloroethene
2.0 0.20 ug/L 11/11/24 09:25 1NDTrichlorofluoromethane
2.0 0.30 ug/L 11/11/24 09:25 1NDDichlorodifluoromethane
3.0 0.73 ug/L 11/11/24 09:25 1ND1,1,2-Trichloro-1,2,2-trifluoroethane
1.0 0.24 ug/L 11/11/24 09:25 1ND1,2-Dichloropropane
10 4.6 ug/L 11/11/24 09:25 1ND2-Butanone (MEK)
1.0 0.27 ug/L 11/11/24 09:25 1ND1,1,2-Trichloroethane
1.0 0.30 ug/L 11/11/24 09:25 1NDTrichloroethene
5.0 1.6 ug/L 11/11/24 09:25 1NDMethyl acetate
1.0 0.21 ug/L 11/11/24 09:25 1ND1,1,2,2-Tetrachloroethane
4.0 1.2 ug/L 11/11/24 09:25 1ND1,2,3-Trichlorobenzene
2.0 0.53 ug/L 11/11/24 09:25 1NDF1Hexachlorobutadiene
3.0 0.99 ug/L 11/11/24 09:25 1NDNaphthalene
1.0 0.11 ug/L 11/11/24 09:25 1NDo-Xylene
1.0 0.34 ug/L 11/11/24 09:25 1ND2-Chlorotoluene
1.0 0.14 ug/L 11/11/24 09:25 1ND1,2-Dichlorobenzene
1.0 0.15 ug/L 11/11/24 09:25 1ND1,2,4-Trimethylbenzene
5.0 0.42 ug/L 11/11/24 09:25 1ND1,2-Dibromo-3-Chloropropane
2.5 0.28 ug/L 11/11/24 09:25 1ND1,2,3-Trichloropropane
3.0 0.19 ug/L 11/11/24 09:25 1NDEthyl methacrylate
1.0 0.18 ug/L 11/11/24 09:25 1NDF1tert-Butylbenzene
1.0 0.16 ug/L 11/11/24 09:25 1NDIsopropylbenzene
1.0 0.19 ug/L 11/11/24 09:25 1NDF14-Isopropyltoluene
1.0 0.11 ug/L 11/11/24 09:25 1NDXylenes, Total
1.0 0.32 ug/L 11/11/24 09:25 1ND1,2-Dichloroethene, Total
1.0 0.14 ug/L 11/11/24 09:25 1ND1,3-Dichloropropene, Total
1.0 0.19 ug/L 11/11/24 09:25 1NDTrihalomethanes, Total
1.0 0.14 ug/L 11/11/24 09:25 1NDTotal BTEX
1,2-Dichloroethane-d4 (Surr)92 70 -127 11/11/24 09:25 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)93 11/11/24 09:25 177-120
Toluene-d8 (Surr)106 11/11/24 09:25 180-125
4-Bromofluorobenzene (Surr)94 11/11/24 09:25 178-120
Lab Sample ID: 280-198899-4Client Sample ID: FB-01
Matrix: WaterDate Collected: 10/30/24 00:00
Date Received: 10/31/24 09:10
Method: SW846 8260D - Volatile Organic Compounds by GC/MS
RL MDL
ND 1.0 0.14 ug/L 11/11/24 08:24 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Ethylbenzene
1.0 0.13 ug/L 11/11/24 08:24 1NDStyrene
1.0 0.16 ug/L 11/11/24 08:24 1NDcis-1,3-Dichloropropene
1.0 0.14 ug/L 11/11/24 08:24 1NDtrans-1,3-Dichloropropene
1.0 0.18 ug/L 11/11/24 08:24 1NDN-Propylbenzene
1.0 0.23 ug/L 11/11/24 08:24 1NDn-Butylbenzene
1.0 0.21 ug/L 11/11/24 08:24 1ND4-Chlorotoluene
1.0 0.39 ug/L 11/11/24 08:24 1ND1,4-Dichlorobenzene
1.0 0.18 ug/L 11/11/24 08:24 1NDEthylene Dibromide
Eurofins Denver
11/15/2024
3:53:55 PM
Page 11 of 777
Client Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Lab Sample ID: 280-198899-4Client Sample ID: FB-01
Matrix: WaterDate Collected: 10/30/24 00:00
Date Received: 10/31/24 09:10
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
ND 2.0 0.46 ug/L 11/11/24 08:24 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
3-Chloro-1-propene
1.0 0.28 ug/L 11/11/24 08:24 1ND1,2-Dichloroethane
3.0 0.36 ug/L 11/11/24 08:24 1NDVinyl acetate
5.0 0.98 ug/L 11/11/24 08:24 1ND4-Methyl-2-pentanone (MIBK)
1.0 0.12 ug/L 11/11/24 08:24 1ND1,3,5-Trimethylbenzene
1.0 0.19 ug/L 11/11/24 08:24 1NDBromobenzene
1.0 0.31 ug/L 11/11/24 08:24 1NDMethylcyclohexane
1.0 0.32 ug/L 11/11/24 08:24 1NDToluene
1.0 0.092 ug/L 11/11/24 08:24 1NDChlorobenzene
7.0 0.84 ug/L 11/11/24 08:24 1NDTetrahydrofuran
2.0 0.16 ug/L 11/11/24 08:24 1NDHexane
1.0 0.44 ug/L 11/11/24 08:24 1NDCyclohexane
1.0 0.58 ug/L 11/11/24 08:24 1ND1,2,4-Trichlorobenzene
1.0 0.28 ug/L 11/11/24 08:24 1NDChlorodibromomethane
1.0 0.40 ug/L 11/11/24 08:24 1NDTetrachloroethene
1.0 0.20 ug/L 11/11/24 08:24 1NDsec-Butylbenzene
1.0 0.17 ug/L 11/11/24 08:24 1ND1,3-Dichloropropane
1.0 0.32 ug/L 11/11/24 08:24 1NDcis-1,2-Dichloroethene
1.0 0.37 ug/L 11/11/24 08:24 1NDtrans-1,2-Dichloroethene
5.0 0.25 ug/L 11/11/24 08:24 1NDMethyl tert-butyl ether
2.0 0.36 ug/L 11/11/24 08:24 1NDm-Xylene & p-Xylene
1.0 0.33 ug/L 11/11/24 08:24 1ND1,3-Dichlorobenzene
1.0 0.23 ug/L 11/11/24 08:24 1NDCarbon tetrachloride
1.0 0.19 ug/L 11/11/24 08:24 1ND1,1-Dichloropropene
5.0 0.81 ug/L 11/11/24 08:24 1ND2-Hexanone
1.0 0.17 ug/L 11/11/24 08:24 1ND2,2-Dichloropropane
2.0 0.35 ug/L 11/11/24 08:24 1NDEthyl ether
1.0 0.16 ug/L 11/11/24 08:24 1ND1,1,1,2-Tetrachloroethane
15 6.6 ug/L 11/11/24 08:24 1NDAcetone
1.0 0.36 ug/L 11/11/24 08:24 1NDChloroform
1.0 0.14 ug/L 11/11/24 08:24 1NDBenzene
1.0 0.39 ug/L 11/11/24 08:24 1ND1,1,1-Trichloroethane
5.0 2.4 ug/L 11/11/24 08:24 1ND*1Bromomethane
2.0 0.23 ug/L 11/11/24 08:24 1NDChloromethane
5.0 2.6 ug/L 11/11/24 08:24 1NDIodomethane
1.0 0.34 ug/L 11/11/24 08:24 1NDDibromomethane
1.0 0.40 ug/L 11/11/24 08:24 1NDChlorobromomethane
2.0 0.64 ug/L 11/11/24 08:24 1NDChloroethane
1.0 0.23 ug/L 11/11/24 08:24 1NDVinyl chloride
2.0 0.94 ug/L 11/11/24 08:24 1NDMethylene Chloride
2.0 0.26 ug/L 11/11/24 08:24 1NDCarbon disulfide
2.0 0.25 ug/L 11/11/24 08:24 1NDBromoform
1.0 0.19 ug/L 11/11/24 08:24 1NDDichlorobromomethane
1.0 0.22 ug/L 11/11/24 08:24 1ND1,1-Dichloroethane
1.0 0.23 ug/L 11/11/24 08:24 1ND1,1-Dichloroethene
2.0 0.20 ug/L 11/11/24 08:24 1NDTrichlorofluoromethane
2.0 0.30 ug/L 11/11/24 08:24 1NDDichlorodifluoromethane
3.0 0.73 ug/L 11/11/24 08:24 1ND1,1,2-Trichloro-1,2,2-trifluoroethane
1.0 0.24 ug/L 11/11/24 08:24 1ND1,2-Dichloropropane
Eurofins Denver
11/15/2024
3:53:55 PM
Page 12 of 777
Client Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Lab Sample ID: 280-198899-4Client Sample ID: FB-01
Matrix: WaterDate Collected: 10/30/24 00:00
Date Received: 10/31/24 09:10
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
ND 10 4.6 ug/L 11/11/24 08:24 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
2-Butanone (MEK)
1.0 0.27 ug/L 11/11/24 08:24 1ND1,1,2-Trichloroethane
1.0 0.30 ug/L 11/11/24 08:24 1NDTrichloroethene
5.0 1.6 ug/L 11/11/24 08:24 1NDMethyl acetate
1.0 0.21 ug/L 11/11/24 08:24 1ND1,1,2,2-Tetrachloroethane
4.0 1.2 ug/L 11/11/24 08:24 1ND1,2,3-Trichlorobenzene
2.0 0.53 ug/L 11/11/24 08:24 1NDHexachlorobutadiene
3.0 0.99 ug/L 11/11/24 08:24 1NDNaphthalene
1.0 0.11 ug/L 11/11/24 08:24 1NDo-Xylene
1.0 0.34 ug/L 11/11/24 08:24 1ND2-Chlorotoluene
1.0 0.14 ug/L 11/11/24 08:24 1ND1,2-Dichlorobenzene
1.0 0.15 ug/L 11/11/24 08:24 1ND1,2,4-Trimethylbenzene
5.0 0.42 ug/L 11/11/24 08:24 1ND1,2-Dibromo-3-Chloropropane
2.5 0.28 ug/L 11/11/24 08:24 1ND1,2,3-Trichloropropane
3.0 0.19 ug/L 11/11/24 08:24 1NDEthyl methacrylate
1.0 0.18 ug/L 11/11/24 08:24 1NDtert-Butylbenzene
1.0 0.16 ug/L 11/11/24 08:24 1NDIsopropylbenzene
1.0 0.19 ug/L 11/11/24 08:24 1ND4-Isopropyltoluene
1.0 0.11 ug/L 11/11/24 08:24 1NDXylenes, Total
1.0 0.32 ug/L 11/11/24 08:24 1ND1,2-Dichloroethene, Total
1.0 0.14 ug/L 11/11/24 08:24 1ND1,3-Dichloropropene, Total
1.0 0.19 ug/L 11/11/24 08:24 1NDTrihalomethanes, Total
1.0 0.14 ug/L 11/11/24 08:24 1NDTotal BTEX
1,2-Dichloroethane-d4 (Surr)92 70 -127 11/11/24 08:24 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)95 11/11/24 08:24 177-120
Toluene-d8 (Surr)109 11/11/24 08:24 180-125
4-Bromofluorobenzene (Surr)91 11/11/24 08:24 178-120
Lab Sample ID: 280-198899-5Client Sample ID: DS-01
Matrix: WaterDate Collected: 10/30/24 00:00
Date Received: 10/31/24 09:10
Method: SW846 8260D - Volatile Organic Compounds by GC/MS
RL MDL
ND 100 14 ug/L 11/11/24 11:50 100
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Ethylbenzene
100 13 ug/L 11/11/24 11:50 100NDStyrene
100 16 ug/L 11/11/24 11:50 100NDcis-1,3-Dichloropropene
100 14 ug/L 11/11/24 11:50 100NDtrans-1,3-Dichloropropene
100 18 ug/L 11/11/24 11:50 100NDN-Propylbenzene
100 23 ug/L 11/11/24 11:50 100NDn-Butylbenzene
100 21 ug/L 11/11/24 11:50 100ND4-Chlorotoluene
100 39 ug/L 11/11/24 11:50 100ND1,4-Dichlorobenzene
100 18 ug/L 11/11/24 11:50 100NDEthylene Dibromide
200 46 ug/L 11/11/24 11:50 100ND3-Chloro-1-propene
100 28 ug/L 11/11/24 11:50 100ND1,2-Dichloroethane
300 36 ug/L 11/11/24 11:50 100NDVinyl acetate
500 98 ug/L 11/11/24 11:50 100ND4-Methyl-2-pentanone (MIBK)
100 12 ug/L 11/11/24 11:50 100ND1,3,5-Trimethylbenzene
Eurofins Denver
11/15/2024
3:53:55 PM
Page 13 of 777
Client Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Lab Sample ID: 280-198899-5Client Sample ID: DS-01
Matrix: WaterDate Collected: 10/30/24 00:00
Date Received: 10/31/24 09:10
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
ND 100 19 ug/L 11/11/24 11:50 100
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Bromobenzene
100 31 ug/L 11/11/24 11:50 100NDMethylcyclohexane
100 32 ug/L 11/11/24 11:50 10077JToluene
100 9.2 ug/L 11/11/24 11:50 100NDChlorobenzene
700 84 ug/L 11/11/24 11:50 100NDTetrahydrofuran
200 16 ug/L 11/11/24 11:50 100NDHexane
100 44 ug/L 11/11/24 11:50 100NDCyclohexane
100 58 ug/L 11/11/24 11:50 100ND1,2,4-Trichlorobenzene
100 28 ug/L 11/11/24 11:50 100NDChlorodibromomethane
100 40 ug/L 11/11/24 11:50 100NDTetrachloroethene
100 20 ug/L 11/11/24 11:50 100NDsec-Butylbenzene
100 17 ug/L 11/11/24 11:50 100ND1,3-Dichloropropane
100 32 ug/L 11/11/24 11:50 100NDcis-1,2-Dichloroethene
100 37 ug/L 11/11/24 11:50 100NDtrans-1,2-Dichloroethene
500 25 ug/L 11/11/24 11:50 100NDMethyl tert-butyl ether
200 36 ug/L 11/11/24 11:50 100NDm-Xylene & p-Xylene
100 33 ug/L 11/11/24 11:50 100ND1,3-Dichlorobenzene
100 23 ug/L 11/11/24 11:50 100NDCarbon tetrachloride
100 19 ug/L 11/11/24 11:50 100ND1,1-Dichloropropene
500 81 ug/L 11/11/24 11:50 100ND2-Hexanone
100 17 ug/L 11/11/24 11:50 100ND2,2-Dichloropropane
200 35 ug/L 11/11/24 11:50 100NDEthyl ether
100 16 ug/L 11/11/24 11:50 100ND1,1,1,2-Tetrachloroethane
1500 660 ug/L 11/11/24 11:50 100NDAcetone
100 36 ug/L 11/11/24 11:50 100NDChloroform
100 14 ug/L 11/11/24 11:50 100NDBenzene
100 39 ug/L 11/11/24 11:50 100ND1,1,1-Trichloroethane
500 240 ug/L 11/11/24 11:50 100ND*1Bromomethane
200 23 ug/L 11/11/24 11:50 100NDChloromethane
500 260 ug/L 11/11/24 11:50 100NDIodomethane
100 34 ug/L 11/11/24 11:50 100NDDibromomethane
100 40 ug/L 11/11/24 11:50 100NDChlorobromomethane
200 64 ug/L 11/11/24 11:50 100NDChloroethane
100 23 ug/L 11/11/24 11:50 100NDVinyl chloride
200 94 ug/L 11/11/24 11:50 100NDMethylene Chloride
200 26 ug/L 11/11/24 11:50 100NDCarbon disulfide
200 25 ug/L 11/11/24 11:50 100NDBromoform
100 19 ug/L 11/11/24 11:50 100NDDichlorobromomethane
100 22 ug/L 11/11/24 11:50 100ND1,1-Dichloroethane
100 23 ug/L 11/11/24 11:50 100ND1,1-Dichloroethene
200 20 ug/L 11/11/24 11:50 100NDTrichlorofluoromethane
200 30 ug/L 11/11/24 11:50 100NDDichlorodifluoromethane
100 24 ug/L 11/11/24 11:50 1001501,2-Dichloropropane
1000 460 ug/L 11/11/24 11:50 100ND2-Butanone (MEK)
100 27 ug/L 11/11/24 11:50 100ND1,1,2-Trichloroethane
100 30 ug/L 11/11/24 11:50 100NDTrichloroethene
500 160 ug/L 11/11/24 11:50 100NDMethyl acetate
100 21 ug/L 11/11/24 11:50 100ND1,1,2,2-Tetrachloroethane
400 120 ug/L 11/11/24 11:50 100ND1,2,3-Trichlorobenzene
Eurofins Denver
11/15/2024
3:53:55 PM
Page 14 of 777
Client Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Lab Sample ID: 280-198899-5Client Sample ID: DS-01
Matrix: WaterDate Collected: 10/30/24 00:00
Date Received: 10/31/24 09:10
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
ND 200 53 ug/L 11/11/24 11:50 100
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Hexachlorobutadiene
300 99 ug/L 11/11/24 11:50 100NDNaphthalene
100 11 ug/L 11/11/24 11:50 100NDo-Xylene
100 34 ug/L 11/11/24 11:50 100ND2-Chlorotoluene
100 14 ug/L 11/11/24 11:50 100ND1,2-Dichlorobenzene
100 15 ug/L 11/11/24 11:50 100ND1,2,4-Trimethylbenzene
500 42 ug/L 11/11/24 11:50 100ND1,2-Dibromo-3-Chloropropane
250 28 ug/L 11/11/24 11:50 100ND1,2,3-Trichloropropane
300 19 ug/L 11/11/24 11:50 100NDEthyl methacrylate
100 18 ug/L 11/11/24 11:50 100NDtert-Butylbenzene
100 16 ug/L 11/11/24 11:50 100NDIsopropylbenzene
100 19 ug/L 11/11/24 11:50 100ND4-Isopropyltoluene
100 11 ug/L 11/11/24 11:50 100NDXylenes, Total
100 32 ug/L 11/11/24 11:50 100ND1,2-Dichloroethene, Total
100 14 ug/L 11/11/24 11:50 100ND1,3-Dichloropropene, Total
100 19 ug/L 11/11/24 11:50 100NDTrihalomethanes, Total
100 14 ug/L 11/11/24 11:50 10077JTotal BTEX
1,2-Dichloroethane-d4 (Surr)90 70 -127 11/11/24 11:50 100
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)94 11/11/24 11:50 10077-120
Toluene-d8 (Surr)106 11/11/24 11:50 10080-125
4-Bromofluorobenzene (Surr)92 11/11/24 11:50 10078-120
Method: SW846 8260D - Volatile Organic Compounds by GC/MS - DL
RL MDL
22000 1500 360 ug/L 11/13/24 15:34 500
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
1,2-Dichloroethane-d4 (Surr)106 70 -127 11/13/24 15:34 500
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)103 11/13/24 15:34 50077-120
Toluene-d8 (Surr)97 11/13/24 15:34 50080-125
4-Bromofluorobenzene (Surr)103 11/13/24 15:34 50078-120
Lab Sample ID: 280-198899-6Client Sample ID: Trip Blank
Matrix: WaterDate Collected: 10/30/24 00:00
Date Received: 10/31/24 09:10
Method: SW846 8260D - Volatile Organic Compounds by GC/MS
RL MDL
ND 1.0 0.14 ug/L 11/11/24 08:04 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Ethylbenzene
1.0 0.13 ug/L 11/11/24 08:04 1NDStyrene
1.0 0.16 ug/L 11/11/24 08:04 1NDcis-1,3-Dichloropropene
1.0 0.14 ug/L 11/11/24 08:04 1NDtrans-1,3-Dichloropropene
1.0 0.18 ug/L 11/11/24 08:04 1NDN-Propylbenzene
1.0 0.23 ug/L 11/11/24 08:04 1NDn-Butylbenzene
1.0 0.21 ug/L 11/11/24 08:04 1ND4-Chlorotoluene
1.0 0.39 ug/L 11/11/24 08:04 1ND1,4-Dichlorobenzene
1.0 0.18 ug/L 11/11/24 08:04 1NDEthylene Dibromide
2.0 0.46 ug/L 11/11/24 08:04 1ND3-Chloro-1-propene
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Page 15 of 777
Client Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Lab Sample ID: 280-198899-6Client Sample ID: Trip Blank
Matrix: WaterDate Collected: 10/30/24 00:00
Date Received: 10/31/24 09:10
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
ND 1.0 0.28 ug/L 11/11/24 08:04 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,2-Dichloroethane
3.0 0.36 ug/L 11/11/24 08:04 1NDVinyl acetate
5.0 0.98 ug/L 11/11/24 08:04 1ND4-Methyl-2-pentanone (MIBK)
1.0 0.12 ug/L 11/11/24 08:04 1ND1,3,5-Trimethylbenzene
1.0 0.19 ug/L 11/11/24 08:04 1NDBromobenzene
1.0 0.31 ug/L 11/11/24 08:04 1NDMethylcyclohexane
1.0 0.32 ug/L 11/11/24 08:04 1NDToluene
1.0 0.092 ug/L 11/11/24 08:04 1NDChlorobenzene
7.0 0.84 ug/L 11/11/24 08:04 11.2 JTetrahydrofuran
2.0 0.16 ug/L 11/11/24 08:04 1NDHexane
1.0 0.44 ug/L 11/11/24 08:04 1NDCyclohexane
1.0 0.58 ug/L 11/11/24 08:04 1ND1,2,4-Trichlorobenzene
1.0 0.28 ug/L 11/11/24 08:04 1NDChlorodibromomethane
1.0 0.40 ug/L 11/11/24 08:04 1NDTetrachloroethene
1.0 0.20 ug/L 11/11/24 08:04 1NDsec-Butylbenzene
1.0 0.17 ug/L 11/11/24 08:04 1ND1,3-Dichloropropane
1.0 0.32 ug/L 11/11/24 08:04 1NDcis-1,2-Dichloroethene
1.0 0.37 ug/L 11/11/24 08:04 1NDtrans-1,2-Dichloroethene
5.0 0.25 ug/L 11/11/24 08:04 1NDMethyl tert-butyl ether
2.0 0.36 ug/L 11/11/24 08:04 1NDm-Xylene & p-Xylene
1.0 0.33 ug/L 11/11/24 08:04 1ND1,3-Dichlorobenzene
1.0 0.23 ug/L 11/11/24 08:04 1NDCarbon tetrachloride
1.0 0.19 ug/L 11/11/24 08:04 1ND1,1-Dichloropropene
5.0 0.81 ug/L 11/11/24 08:04 1ND2-Hexanone
1.0 0.17 ug/L 11/11/24 08:04 1ND2,2-Dichloropropane
2.0 0.35 ug/L 11/11/24 08:04 1NDEthyl ether
1.0 0.16 ug/L 11/11/24 08:04 1ND1,1,1,2-Tetrachloroethane
15 6.6 ug/L 11/11/24 08:04 1NDAcetone
1.0 0.36 ug/L 11/11/24 08:04 1NDChloroform
1.0 0.14 ug/L 11/11/24 08:04 1NDBenzene
1.0 0.39 ug/L 11/11/24 08:04 1ND1,1,1-Trichloroethane
5.0 2.4 ug/L 11/11/24 08:04 1ND*1Bromomethane
2.0 0.23 ug/L 11/11/24 08:04 1NDChloromethane
5.0 2.6 ug/L 11/11/24 08:04 1NDIodomethane
1.0 0.34 ug/L 11/11/24 08:04 1NDDibromomethane
1.0 0.40 ug/L 11/11/24 08:04 1NDChlorobromomethane
2.0 0.64 ug/L 11/11/24 08:04 1NDChloroethane
1.0 0.23 ug/L 11/11/24 08:04 1NDVinyl chloride
2.0 0.94 ug/L 11/11/24 08:04 1NDMethylene Chloride
2.0 0.26 ug/L 11/11/24 08:04 1NDCarbon disulfide
2.0 0.25 ug/L 11/11/24 08:04 1NDBromoform
1.0 0.19 ug/L 11/11/24 08:04 1NDDichlorobromomethane
1.0 0.22 ug/L 11/11/24 08:04 1ND1,1-Dichloroethane
1.0 0.23 ug/L 11/11/24 08:04 1ND1,1-Dichloroethene
2.0 0.20 ug/L 11/11/24 08:04 1NDTrichlorofluoromethane
2.0 0.30 ug/L 11/11/24 08:04 1NDDichlorodifluoromethane
3.0 0.73 ug/L 11/11/24 08:04 1ND1,1,2-Trichloro-1,2,2-trifluoroethane
1.0 0.24 ug/L 11/11/24 08:04 1ND1,2-Dichloropropane
10 4.6 ug/L 11/11/24 08:04 1ND2-Butanone (MEK)
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Page 16 of 777
Client Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Lab Sample ID: 280-198899-6Client Sample ID: Trip Blank
Matrix: WaterDate Collected: 10/30/24 00:00
Date Received: 10/31/24 09:10
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
ND 1.0 0.27 ug/L 11/11/24 08:04 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,2-Trichloroethane
1.0 0.30 ug/L 11/11/24 08:04 1NDTrichloroethene
5.0 1.6 ug/L 11/11/24 08:04 1NDMethyl acetate
1.0 0.21 ug/L 11/11/24 08:04 1ND1,1,2,2-Tetrachloroethane
4.0 1.2 ug/L 11/11/24 08:04 1ND1,2,3-Trichlorobenzene
2.0 0.53 ug/L 11/11/24 08:04 1NDHexachlorobutadiene
3.0 0.99 ug/L 11/11/24 08:04 1NDNaphthalene
1.0 0.11 ug/L 11/11/24 08:04 1NDo-Xylene
1.0 0.34 ug/L 11/11/24 08:04 1ND2-Chlorotoluene
1.0 0.14 ug/L 11/11/24 08:04 1ND1,2-Dichlorobenzene
1.0 0.15 ug/L 11/11/24 08:04 1ND1,2,4-Trimethylbenzene
5.0 0.42 ug/L 11/11/24 08:04 1ND1,2-Dibromo-3-Chloropropane
2.5 0.28 ug/L 11/11/24 08:04 1ND1,2,3-Trichloropropane
3.0 0.19 ug/L 11/11/24 08:04 1NDEthyl methacrylate
1.0 0.18 ug/L 11/11/24 08:04 1NDtert-Butylbenzene
1.0 0.16 ug/L 11/11/24 08:04 1NDIsopropylbenzene
1.0 0.19 ug/L 11/11/24 08:04 1ND4-Isopropyltoluene
1.0 0.11 ug/L 11/11/24 08:04 1NDXylenes, Total
1.0 0.32 ug/L 11/11/24 08:04 1ND1,2-Dichloroethene, Total
1.0 0.14 ug/L 11/11/24 08:04 1ND1,3-Dichloropropene, Total
1.0 0.19 ug/L 11/11/24 08:04 1NDTrihalomethanes, Total
1.0 0.14 ug/L 11/11/24 08:04 1NDTotal BTEX
1,2-Dichloroethane-d4 (Surr)93 70 -127 11/11/24 08:04 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)95 11/11/24 08:04 177-120
Toluene-d8 (Surr)109 11/11/24 08:04 180-125
4-Bromofluorobenzene (Surr)92 11/11/24 08:04 178-120
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Default Detection Limits
Client: Ramboll Americas Engineering Solutions Job ID: 280-198899-1
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS
1.01,1,1,2-Tetrachloroethane ug/L
Analyte UnitsMDLRL
0.16
1.01,1,1-Trichloroethane ug/L0.39
1.01,1,2,2-Tetrachloroethane ug/L0.21
3.01,1,2-Trichloro-1,2,2-trifluoroethane ug/L0.73
1.01,1,2-Trichloroethane ug/L0.27
1.01,1-Dichloroethane ug/L0.22
1.01,1-Dichloroethene ug/L0.23
1.01,1-Dichloropropene ug/L0.19
4.01,2,3-Trichlorobenzene ug/L1.2
2.51,2,3-Trichloropropane ug/L0.28
1.01,2,4-Trichlorobenzene ug/L0.58
1.01,2,4-Trimethylbenzene ug/L0.15
5.01,2-Dibromo-3-Chloropropane ug/L0.42
1.01,2-Dichlorobenzene ug/L0.14
1.01,2-Dichloroethane ug/L0.28
1.01,2-Dichloroethene, Total ug/L0.32
1.01,2-Dichloropropane ug/L0.24
1.01,3,5-Trimethylbenzene ug/L0.12
1.01,3-Dichlorobenzene ug/L0.33
1.01,3-Dichloropropane ug/L0.17
1.01,3-Dichloropropene, Total ug/L0.14
1.01,4-Dichlorobenzene ug/L0.39
1.02,2-Dichloropropane ug/L0.17
102-Butanone (MEK)ug/L4.6
1.02-Chlorotoluene ug/L0.34
5.02-Hexanone ug/L0.81
2.03-Chloro-1-propene ug/L0.46
1.04-Chlorotoluene ug/L0.21
1.04-Isopropyltoluene ug/L0.19
5.04-Methyl-2-pentanone (MIBK)ug/L0.98
15Acetone ug/L6.6
1.0Benzene ug/L0.14
1.0Bromobenzene ug/L0.19
2.0Bromoform ug/L0.25
5.0Bromomethane ug/L2.4
2.0Carbon disulfide ug/L0.26
1.0Carbon tetrachloride ug/L0.23
1.0Chlorobenzene ug/L0.092
1.0Chlorobromomethane ug/L0.40
1.0Chlorodibromomethane ug/L0.28
2.0Chloroethane ug/L0.64
1.0Chloroform ug/L0.36
2.0Chloromethane ug/L0.23
1.0cis-1,2-Dichloroethene ug/L0.32
1.0cis-1,3-Dichloropropene ug/L0.16
1.0Cyclohexane ug/L0.44
1.0Dibromomethane ug/L0.34
1.0Dichlorobromomethane ug/L0.19
2.0Dichlorodifluoromethane ug/L0.30
2.0Ethyl ether ug/L0.35
3.0Ethyl methacrylate ug/L0.19
1.0Ethylbenzene ug/L0.14
1.0Ethylene Dibromide ug/L0.18
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Page 18 of 777
Default Detection Limits
Client: Ramboll Americas Engineering Solutions Job ID: 280-198899-1
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
2.0Hexachlorobutadiene ug/L
Analyte UnitsMDLRL
0.53
2.0Hexane ug/L0.16
5.0Iodomethane ug/L2.6
1.0Isopropylbenzene ug/L0.16
5.0Methyl acetate ug/L1.6
5.0Methyl tert-butyl ether ug/L0.25
1.0Methylcyclohexane ug/L0.31
2.0Methylene Chloride ug/L0.94
2.0m-Xylene & p-Xylene ug/L0.36
3.0Naphthalene ug/L0.99
1.0n-Butylbenzene ug/L0.23
1.0N-Propylbenzene ug/L0.18
1.0o-Xylene ug/L0.11
1.0sec-Butylbenzene ug/L0.20
1.0Styrene ug/L0.13
1.0tert-Butylbenzene ug/L0.18
1.0Tetrachloroethene ug/L0.40
7.0Tetrahydrofuran ug/L0.84
1.0Toluene ug/L0.32
1.0Total BTEX ug/L0.14
1.0trans-1,2-Dichloroethene ug/L0.37
1.0trans-1,3-Dichloropropene ug/L0.14
1.0Trichloroethene ug/L0.30
2.0Trichlorofluoromethane ug/L0.20
1.0Trihalomethanes, Total ug/L0.19
3.0Vinyl acetate ug/L0.36
1.0Vinyl chloride ug/L0.23
1.0Xylenes, Total ug/L0.11
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Page 19 of 777
Surrogate Summary
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS
Prep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (70-127)(77-120)(80-125)(78-120)
DCA DBFM TOL BFB
91 93 108 94280-198899-2
Percent Surrogate Recovery (Acceptance Limits)
MW-61-241030
92 93 106 94280-198899-3 MW-63-241030
90 100 106 93280-198899-3 MS MW-63-241030
92 101 105 91280-198899-3 MSD MW-63-241030
92 95 109 91280-198899-4 FB-01
90 94 106 92280-198899-5 DS-01
106 103 97 103280-198899-5 - DL DS-01
93 95 109 92280-198899-6 Trip Blank
95 103 103 95LCS 280-674451/4 Lab Control Sample
101 104 99 100LCS 280-674813/4 Lab Control Sample
98 103 100 95LCSD 280-674451/5 Lab Control Sample Dup
107 103 98 101LCSD 280-674813/5 Lab Control Sample Dup
93 96 106 91MB 280-674451/9 Method Blank
107 101 100 98MB 280-674813/9 Method Blank
Surrogate Legend
DCA = 1,2-Dichloroethane-d4 (Surr)
DBFM = Dibromofluoromethane (Surr)
TOL = Toluene-d8 (Surr)
BFB = 4-Bromofluorobenzene (Surr)
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Page 20 of 777
QC Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS
Client Sample ID: Method BlankLab Sample ID: MB 280-674451/9
Matrix: Water Prep Type: Total/NA
Analysis Batch: 674451
RL MDL
Ethylbenzene ND 1.0 0.14 ug/L 11/11/24 06:40 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
ND 0.131.0 ug/L 11/11/24 06:40 1Styrene
ND 0.161.0 ug/L 11/11/24 06:40 1cis-1,3-Dichloropropene
ND 0.141.0 ug/L 11/11/24 06:40 1trans-1,3-Dichloropropene
ND 0.181.0 ug/L 11/11/24 06:40 1N-Propylbenzene
ND 0.231.0 ug/L 11/11/24 06:40 1n-Butylbenzene
ND 0.211.0 ug/L 11/11/24 06:40 14-Chlorotoluene
ND 0.391.0 ug/L 11/11/24 06:40 11,4-Dichlorobenzene
ND 0.181.0 ug/L 11/11/24 06:40 1Ethylene Dibromide
ND 0.462.0 ug/L 11/11/24 06:40 13-Chloro-1-propene
ND 0.281.0 ug/L 11/11/24 06:40 11,2-Dichloroethane
ND 0.363.0 ug/L 11/11/24 06:40 1Vinyl acetate
ND 0.985.0 ug/L 11/11/24 06:40 14-Methyl-2-pentanone (MIBK)
ND 0.121.0 ug/L 11/11/24 06:40 11,3,5-Trimethylbenzene
ND 0.191.0 ug/L 11/11/24 06:40 1Bromobenzene
ND 0.311.0 ug/L 11/11/24 06:40 1Methylcyclohexane
ND 0.321.0 ug/L 11/11/24 06:40 1Toluene
ND 0.0921.0 ug/L 11/11/24 06:40 1Chlorobenzene
ND 0.847.0 ug/L 11/11/24 06:40 1Tetrahydrofuran
ND 0.162.0 ug/L 11/11/24 06:40 1Hexane
ND 0.441.0 ug/L 11/11/24 06:40 1Cyclohexane
ND 0.581.0 ug/L 11/11/24 06:40 11,2,4-Trichlorobenzene
ND 0.281.0 ug/L 11/11/24 06:40 1Chlorodibromomethane
ND 0.401.0 ug/L 11/11/24 06:40 1Tetrachloroethene
ND 0.201.0 ug/L 11/11/24 06:40 1sec-Butylbenzene
ND 0.171.0 ug/L 11/11/24 06:40 11,3-Dichloropropane
ND 0.321.0 ug/L 11/11/24 06:40 1cis-1,2-Dichloroethene
ND 0.371.0 ug/L 11/11/24 06:40 1trans-1,2-Dichloroethene
ND 0.255.0 ug/L 11/11/24 06:40 1Methyl tert-butyl ether
ND 0.362.0 ug/L 11/11/24 06:40 1m-Xylene & p-Xylene
ND 0.331.0 ug/L 11/11/24 06:40 11,3-Dichlorobenzene
ND 0.231.0 ug/L 11/11/24 06:40 1Carbon tetrachloride
ND 0.191.0 ug/L 11/11/24 06:40 11,1-Dichloropropene
ND 0.815.0 ug/L 11/11/24 06:40 12-Hexanone
ND 0.171.0 ug/L 11/11/24 06:40 12,2-Dichloropropane
ND 0.352.0 ug/L 11/11/24 06:40 1Ethyl ether
ND 0.161.0 ug/L 11/11/24 06:40 11,1,1,2-Tetrachloroethane
ND 6.615 ug/L 11/11/24 06:40 1Acetone
ND 0.361.0 ug/L 11/11/24 06:40 1Chloroform
ND 0.141.0 ug/L 11/11/24 06:40 1Benzene
ND 0.391.0 ug/L 11/11/24 06:40 11,1,1-Trichloroethane
ND 2.45.0 ug/L 11/11/24 06:40 1Bromomethane
ND 0.232.0 ug/L 11/11/24 06:40 1Chloromethane
ND 2.65.0 ug/L 11/11/24 06:40 1Iodomethane
ND 0.341.0 ug/L 11/11/24 06:40 1Dibromomethane
ND 0.401.0 ug/L 11/11/24 06:40 1Chlorobromomethane
ND 0.642.0 ug/L 11/11/24 06:40 1Chloroethane
ND 0.231.0 ug/L 11/11/24 06:40 1Vinyl chloride
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QC Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 280-674451/9
Matrix: Water Prep Type: Total/NA
Analysis Batch: 674451
RL MDL
Methylene Chloride ND 2.0 0.94 ug/L 11/11/24 06:40 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
ND 0.262.0 ug/L 11/11/24 06:40 1Carbon disulfide
ND 0.252.0 ug/L 11/11/24 06:40 1Bromoform
ND 0.191.0 ug/L 11/11/24 06:40 1Dichlorobromomethane
ND 0.221.0 ug/L 11/11/24 06:40 11,1-Dichloroethane
ND 0.231.0 ug/L 11/11/24 06:40 11,1-Dichloroethene
ND 0.202.0 ug/L 11/11/24 06:40 1Trichlorofluoromethane
ND 0.302.0 ug/L 11/11/24 06:40 1Dichlorodifluoromethane
ND 0.733.0 ug/L 11/11/24 06:40 11,1,2-Trichloro-1,2,2-trifluoroethane
ND 0.241.0 ug/L 11/11/24 06:40 11,2-Dichloropropane
ND 4.610 ug/L 11/11/24 06:40 12-Butanone (MEK)
ND 0.271.0 ug/L 11/11/24 06:40 11,1,2-Trichloroethane
ND 0.301.0 ug/L 11/11/24 06:40 1Trichloroethene
ND 1.65.0 ug/L 11/11/24 06:40 1Methyl acetate
ND 0.211.0 ug/L 11/11/24 06:40 11,1,2,2-Tetrachloroethane
ND 1.24.0 ug/L 11/11/24 06:40 11,2,3-Trichlorobenzene
ND 0.532.0 ug/L 11/11/24 06:40 1Hexachlorobutadiene
ND 0.993.0 ug/L 11/11/24 06:40 1Naphthalene
ND 0.111.0 ug/L 11/11/24 06:40 1o-Xylene
ND 0.341.0 ug/L 11/11/24 06:40 12-Chlorotoluene
ND 0.141.0 ug/L 11/11/24 06:40 11,2-Dichlorobenzene
ND 0.151.0 ug/L 11/11/24 06:40 11,2,4-Trimethylbenzene
ND 0.425.0 ug/L 11/11/24 06:40 11,2-Dibromo-3-Chloropropane
ND 0.282.5 ug/L 11/11/24 06:40 11,2,3-Trichloropropane
ND 0.193.0 ug/L 11/11/24 06:40 1Ethyl methacrylate
ND 0.181.0 ug/L 11/11/24 06:40 1tert-Butylbenzene
ND 0.161.0 ug/L 11/11/24 06:40 1Isopropylbenzene
ND 0.191.0 ug/L 11/11/24 06:40 14-Isopropyltoluene
ND 0.111.0 ug/L 11/11/24 06:40 1Xylenes, Total
ND 0.321.0 ug/L 11/11/24 06:40 11,2-Dichloroethene, Total
ND 0.141.0 ug/L 11/11/24 06:40 11,3-Dichloropropene, Total
ND 0.191.0 ug/L 11/11/24 06:40 1Trihalomethanes, Total
ND 0.141.0 ug/L 11/11/24 06:40 1Total BTEX
1,2-Dichloroethane-d4 (Surr)93 70 -127 11/11/24 06:40 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
96 11/11/24 06:40 1Dibromofluoromethane (Surr)77 -120
106 11/11/24 06:40 1Toluene-d8 (Surr)80 -125
91 11/11/24 06:40 14-Bromofluorobenzene (Surr)78 -120
Client Sample ID: Lab Control SampleLab Sample ID: LCS 280-674451/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 674451
Ethylbenzene 50.0 48.3 ug/L 97 80 -120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Styrene 50.0 48.6 ug/L 97 80 -120
cis-1,3-Dichloropropene 50.0 53.7 ug/L 107 76 -129
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QC Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 280-674451/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 674451
trans-1,3-Dichloropropene 50.0 44.2 ug/L 88 80 -123
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
N-Propylbenzene 50.0 48.8 ug/L 98 80 -123
n-Butylbenzene 50.0 43.5 ug/L 87 59 -140
4-Chlorotoluene 50.0 49.0 ug/L 98 80 -120
1,4-Dichlorobenzene 50.0 50.2 ug/L 100 80 -120
Ethylene Dibromide 50.0 51.5 ug/L 103 80 -120
3-Chloro-1-propene 50.0 48.3 ug/L 97 65 -132
1,2-Dichloroethane 50.0 46.2 ug/L 92 71 -121
Vinyl acetate 100 108 ug/L 108 55 -161
4-Methyl-2-pentanone (MIBK)200 191 ug/L 95 66 -135
1,3,5-Trimethylbenzene 50.0 47.2 ug/L 94 80 -122
Bromobenzene 50.0 50.5 ug/L 101 80 -120
Methylcyclohexane 50.0 40.2 ug/L 80 64 -130
Toluene 50.0 49.8 ug/L 100 80 -120
Chlorobenzene 50.0 49.2 ug/L 98 80 -120
Tetrahydrofuran 100 90.9 ug/L 91 62 -130
Hexane 50.0 40.8 ug/L 82 55 -143
Cyclohexane 50.0 44.2 ug/L 88 68 -125
1,2,4-Trichlorobenzene 50.0 49.0 ug/L 98 74 -126
Chlorodibromomethane 50.0 47.9 ug/L 96 80 -125
Tetrachloroethene 50.0 53.1 ug/L 106 80 -121
sec-Butylbenzene 50.0 46.7 ug/L 93 80 -123
1,3-Dichloropropane 50.0 49.5 ug/L 99 77 -122
cis-1,2-Dichloroethene 50.0 49.5 ug/L 99 80 -120
trans-1,2-Dichloroethene 50.0 49.1 ug/L 98 79 -121
Methyl tert-butyl ether 50.0 50.0 ug/L 100 80 -120
m-Xylene & p-Xylene 50.0 48.8 ug/L 98 80 -120
1,3-Dichlorobenzene 50.0 47.8 ug/L 96 80 -120
Carbon tetrachloride 50.0 48.5 ug/L 97 79 -127
1,1-Dichloropropene 50.0 47.6 ug/L 95 77 -123
2-Hexanone 200 190 ug/L 95 62 -137
2,2-Dichloropropane 50.0 51.4 ug/L 103 75 -131
Ethyl ether 50.0 52.5 ug/L 105 68 -132
1,1,1,2-Tetrachloroethane 50.0 51.4 ug/L 103 80 -124
Acetone 200 179 ug/L 89 61 -134
Chloroform 50.0 47.3 ug/L 95 80 -120
Benzene 50.0 48.6 ug/L 97 80 -120
1,1,1-Trichloroethane 50.0 49.2 ug/L 98 80 -123
Bromomethane 50.0 48.9 ug/L 98 29 -148
Chloromethane 50.0 47.9 ug/L 96 56 -133
Iodomethane 50.0 53.3 ug/L 107 43 -139
Dibromomethane 50.0 49.6 ug/L 99 80 -120
Chlorobromomethane 50.0 52.0 ug/L 104 80 -123
Chloroethane 50.0 47.6 ug/L 95 56 -141
Vinyl chloride 50.0 50.9 ug/L 102 67 -127
Methylene Chloride 50.0 48.3 ug/L 97 78 -120
Carbon disulfide 50.0 50.3 ug/L 101 70 -121
Bromoform 50.0 49.5 ug/L 99 79 -138
Dichlorobromomethane 50.0 44.9 ug/L 90 80 -123
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Page 23 of 777
QC Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 280-674451/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 674451
1,1-Dichloroethane 50.0 49.1 ug/L 98 78 -121
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
1,1-Dichloroethene 50.0 51.7 ug/L 103 77 -121
Trichlorofluoromethane 50.0 49.1 ug/L 98 54 -144
Dichlorodifluoromethane 50.0 34.7 ug/L 69 47 -135
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
50.0 47.0 ug/L 94 73 -132
1,2-Dichloropropane 50.0 47.9 ug/L 96 78 -120
2-Butanone (MEK)200 186 ug/L 93 58 -135
1,1,2-Trichloroethane 50.0 49.9 ug/L 100 80 -120
Trichloroethene 50.0 48.3 ug/L 97 80 -120
Methyl acetate 100 93.5 ug/L 93 59 -136
1,1,2,2-Tetrachloroethane 50.0 54.2 ug/L 108 74 -123
1,2,3-Trichlorobenzene 50.0 49.7 ug/L 99 65 -129
Hexachlorobutadiene 50.0 48.0 ug/L 96 73 -128
Naphthalene 50.0 45.8 ug/L 92 60 -124
o-Xylene 50.0 46.9 ug/L 94 80 -120
2-Chlorotoluene 50.0 48.8 ug/L 98 80 -120
1,2-Dichlorobenzene 50.0 48.9 ug/L 98 80 -120
1,2,4-Trimethylbenzene 50.0 46.1 ug/L 92 79 -124
1,2-Dibromo-3-Chloropropane 50.0 51.6 ug/L 103 73 -128
1,2,3-Trichloropropane 50.0 52.6 ug/L 105 80 -120
Ethyl methacrylate 50.0 50.8 ug/L 102 80 -122
tert-Butylbenzene 50.0 48.3 ug/L 97 80 -120
Isopropylbenzene 50.0 49.6 ug/L 99 78 -122
4-Isopropyltoluene 50.0 46.1 ug/L 92 80 -122
1,2-Dichloroethane-d4 (Surr)70 -127
Surrogate
95
LCS LCS
Qualifier Limits%Recovery
103Dibromofluoromethane (Surr)77 -120
103Toluene-d8 (Surr)80 -125
954-Bromofluorobenzene (Surr)78 -120
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 280-674451/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 674451
Ethylbenzene 50.0 47.4 ug/L 95 80 -120 2 20
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
Styrene 50.0 47.0 ug/L 94 80 -120 3 20
cis-1,3-Dichloropropene 50.0 53.6 ug/L 107 76 -129 0 20
trans-1,3-Dichloropropene 50.0 45.6 ug/L 91 80 -123 3 20
N-Propylbenzene 50.0 47.9 ug/L 96 80 -123 2 20
n-Butylbenzene 50.0 39.7 ug/L 79 59 -140 9 20
4-Chlorotoluene 50.0 49.1 ug/L 98 80 -120 0 20
1,4-Dichlorobenzene 50.0 51.4 ug/L 103 80 -120 2 20
Ethylene Dibromide 50.0 52.3 ug/L 105 80 -120 2 20
3-Chloro-1-propene 50.0 44.5 ug/L 89 65 -132 8 20
1,2-Dichloroethane 50.0 46.4 ug/L 93 71 -121 0 20
Vinyl acetate 100 96.2 ug/L 96 55 -161 11 23
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11/15/2024
3:53:55 PM
Page 24 of 777
QC Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 280-674451/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 674451
4-Methyl-2-pentanone (MIBK)200 196 ug/L 98 66 -135 3 20
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
1,3,5-Trimethylbenzene 50.0 45.3 ug/L 91 80 -122 4 20
Bromobenzene 50.0 52.0 ug/L 104 80 -120 3 20
Methylcyclohexane 50.0 40.3 ug/L 81 64 -130 0 21
Toluene 50.0 51.5 ug/L 103 80 -120 3 20
Chlorobenzene 50.0 49.2 ug/L 98 80 -120 0 20
Tetrahydrofuran 100 94.7 ug/L 95 62 -130 4 20
Hexane 50.0 39.8 ug/L 80 55 -143 3 23
Cyclohexane 50.0 43.4 ug/L 87 68 -125 2 32
1,2,4-Trichlorobenzene 50.0 51.6 ug/L 103 74 -126 5 20
Chlorodibromomethane 50.0 47.0 ug/L 94 80 -125 2 20
Tetrachloroethene 50.0 51.4 ug/L 103 80 -121 3 20
sec-Butylbenzene 50.0 46.2 ug/L 92 80 -123 1 20
1,3-Dichloropropane 50.0 50.4 ug/L 101 77 -122 2 20
cis-1,2-Dichloroethene 50.0 48.6 ug/L 97 80 -120 2 20
trans-1,2-Dichloroethene 50.0 46.7 ug/L 93 79 -121 5 20
Methyl tert-butyl ether 50.0 50.4 ug/L 101 80 -120 1 20
m-Xylene & p-Xylene 50.0 47.1 ug/L 94 80 -120 4 20
1,3-Dichlorobenzene 50.0 48.6 ug/L 97 80 -120 2 20
Carbon tetrachloride 50.0 45.1 ug/L 90 79 -127 7 20
1,1-Dichloropropene 50.0 45.3 ug/L 91 77 -123 5 20
2-Hexanone 200 191 ug/L 96 62 -137 1 21
2,2-Dichloropropane 50.0 47.8 ug/L 96 75 -131 7 22
Ethyl ether 50.0 50.0 ug/L 100 68 -132 5 20
1,1,1,2-Tetrachloroethane 50.0 51.9 ug/L 104 80 -124 1 20
Acetone 200 183 ug/L 91 61 -134 2 21
Chloroform 50.0 47.4 ug/L 95 80 -120 0 20
Benzene 50.0 47.4 ug/L 95 80 -120 2 20
1,1,1-Trichloroethane 50.0 47.3 ug/L 95 80 -123 4 20
Bromomethane 50.0 31.5 *1 ug/L 63 29 -148 43 40
Chloromethane 50.0 45.5 ug/L 91 56 -133 5 20
Iodomethane 50.0 49.2 ug/L 98 43 -139 8 38
Dibromomethane 50.0 51.5 ug/L 103 80 -120 4 20
Chlorobromomethane 50.0 51.5 ug/L 103 80 -123 1 20
Chloroethane 50.0 36.8 ug/L 74 56 -141 25 30
Vinyl chloride 50.0 50.0 ug/L 100 67 -127 2 25
Methylene Chloride 50.0 46.4 ug/L 93 78 -120 4 20
Carbon disulfide 50.0 45.5 ug/L 91 70 -121 10 20
Bromoform 50.0 47.1 ug/L 94 79 -138 5 20
Dichlorobromomethane 50.0 44.6 ug/L 89 80 -123 1 20
1,1-Dichloroethane 50.0 48.6 ug/L 97 78 -121 1 20
1,1-Dichloroethene 50.0 50.3 ug/L 101 77 -121 3 21
Trichlorofluoromethane 50.0 47.1 ug/L 94 54 -144 4 28
Dichlorodifluoromethane 50.0 37.3 ug/L 75 47 -135 7 21
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
50.0 46.0 ug/L 92 73 -132 2 23
1,2-Dichloropropane 50.0 49.0 ug/L 98 78 -120 2 20
2-Butanone (MEK)200 195 ug/L 97 58 -135 5 20
1,1,2-Trichloroethane 50.0 51.9 ug/L 104 80 -120 4 20
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Page 25 of 777
QC Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 280-674451/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 674451
Trichloroethene 50.0 47.5 ug/L 95 80 -120 2 20
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
Methyl acetate 100 94.1 ug/L 94 59 -136 1 20
1,1,2,2-Tetrachloroethane 50.0 55.5 ug/L 111 74 -123 2 20
1,2,3-Trichlorobenzene 50.0 53.0 ug/L 106 65 -129 6 20
Hexachlorobutadiene 50.0 50.7 ug/L 101 73 -128 5 20
Naphthalene 50.0 44.5 ug/L 89 60 -124 3 21
o-Xylene 50.0 45.1 ug/L 90 80 -120 4 20
2-Chlorotoluene 50.0 49.1 ug/L 98 80 -120 1 20
1,2-Dichlorobenzene 50.0 51.2 ug/L 102 80 -120 5 20
1,2,4-Trimethylbenzene 50.0 43.6 ug/L 87 79 -124 6 20
1,2-Dibromo-3-Chloropropane 50.0 53.9 ug/L 108 73 -128 4 21
1,2,3-Trichloropropane 50.0 55.2 ug/L 110 80 -120 5 20
Ethyl methacrylate 50.0 50.6 ug/L 101 80 -122 0 20
tert-Butylbenzene 50.0 47.3 ug/L 95 80 -120 2 20
Isopropylbenzene 50.0 49.0 ug/L 98 78 -122 1 20
4-Isopropyltoluene 50.0 43.7 ug/L 87 80 -122 5 20
1,2-Dichloroethane-d4 (Surr)70 -127
Surrogate
98
LCSD LCSD
Qualifier Limits%Recovery
103Dibromofluoromethane (Surr)77 -120
100Toluene-d8 (Surr)80 -125
954-Bromofluorobenzene (Surr)78 -120
Client Sample ID: MW-63-241030Lab Sample ID: 280-198899-3 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 674451
Ethylbenzene ND 25.0 23.6 ug/L 94 80 -120
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits
Styrene ND 25.0 23.6 ug/L 95 80 -120
cis-1,3-Dichloropropene ND 25.0 24.7 ug/L 99 76 -129
trans-1,3-Dichloropropene ND F1 25.0 18.9 F1 ug/L 76 80 -123
N-Propylbenzene ND 25.0 20.9 ug/L 83 80 -123
n-Butylbenzene ND F1 25.0 13.2 F1 ug/L 53 59 -140
4-Chlorotoluene ND 25.0 22.9 ug/L 91 80 -120
1,4-Dichlorobenzene ND 25.0 23.2 ug/L 93 80 -120
Ethylene Dibromide ND 25.0 25.0 ug/L 100 80 -120
3-Chloro-1-propene ND 25.0 20.8 ug/L 83 65 -132
1,2-Dichloroethane ND 25.0 21.8 ug/L 87 71 -121
Vinyl acetate ND 50.0 47.8 ug/L 96 55 -161
4-Methyl-2-pentanone (MIBK)ND 100 91.3 ug/L 91 66 -135
1,3,5-Trimethylbenzene ND 25.0 20.4 ug/L 81 80 -122
Bromobenzene ND 25.0 24.5 ug/L 98 80 -120
Methylcyclohexane ND F1 25.0 13.4 F1 ug/L 54 64 -130
Toluene ND 25.0 24.1 ug/L 96 80 -120
Chlorobenzene ND 25.0 24.5 ug/L 98 80 -120
Tetrahydrofuran ND 50.0 44.5 ug/L 89 62 -130
Hexane ND F1 25.0 13.5 F1 ug/L 54 55 -143
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3:53:55 PM
Page 26 of 777
QC Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: MW-63-241030Lab Sample ID: 280-198899-3 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 674451
Cyclohexane ND 25.0 18.8 ug/L 75 68 -125
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits
1,2,4-Trichlorobenzene ND F1 25.0 17.5 F1 ug/L 70 74 -126
Chlorodibromomethane ND 25.0 21.4 ug/L 86 80 -125
Tetrachloroethene ND 25.0 25.5 ug/L 102 80 -121
sec-Butylbenzene ND F1 25.0 16.2 F1 ug/L 65 80 -123
1,3-Dichloropropane ND 25.0 24.4 ug/L 97 77 -122
cis-1,2-Dichloroethene ND 25.0 24.0 ug/L 96 80 -120
trans-1,2-Dichloroethene ND 25.0 24.5 ug/L 98 79 -121
Methyl tert-butyl ether ND 25.0 24.2 ug/L 97 80 -120
m-Xylene & p-Xylene ND 25.0 24.6 ug/L 98 80 -120
1,3-Dichlorobenzene ND 25.0 21.5 ug/L 86 80 -120
Carbon tetrachloride ND 25.0 21.9 ug/L 88 79 -127
1,1-Dichloropropene ND 25.0 22.8 ug/L 91 77 -123
2-Hexanone ND 100 96.9 ug/L 97 62 -137
2,2-Dichloropropane ND 25.0 21.6 ug/L 86 75 -131
Ethyl ether ND 25.0 24.6 ug/L 98 68 -132
1,1,1,2-Tetrachloroethane ND 25.0 24.5 ug/L 98 80 -124
Acetone ND 100 87.2 ug/L 87 61 -134
Chloroform ND 25.0 23.3 ug/L 93 80 -120
Benzene ND 25.0 23.9 ug/L 96 80 -120
1,1,1-Trichloroethane ND 25.0 23.4 ug/L 94 80 -123
Bromomethane ND *1 25.0 27.0 ug/L 108 29 -148
Chloromethane ND 25.0 24.9 ug/L 100 56 -133
Iodomethane ND 25.0 27.8 ug/L 111 43 -139
Dibromomethane ND 25.0 22.9 ug/L 92 80 -120
Chlorobromomethane ND 25.0 25.7 ug/L 103 80 -123
Chloroethane ND 25.0 23.8 ug/L 95 56 -141
Vinyl chloride ND 25.0 24.2 ug/L 97 67 -127
Methylene Chloride ND 25.0 23.9 ug/L 96 78 -120
Carbon disulfide ND 25.0 23.3 ug/L 93 70 -121
Bromoform ND 25.0 20.6 ug/L 82 79 -138
Dichlorobromomethane ND 25.0 20.1 ug/L 80 80 -123
1,1-Dichloroethane ND 25.0 24.1 ug/L 97 78 -121
1,1-Dichloroethene ND 25.0 23.2 ug/L 93 77 -121
Trichlorofluoromethane ND 25.0 22.7 ug/L 91 54 -144
Dichlorodifluoromethane ND 25.0 20.3 ug/L 81 47 -135
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
ND 25.0 23.8 ug/L 95 73 -132
1,2-Dichloropropane ND 25.0 23.2 ug/L 93 78 -120
2-Butanone (MEK)ND 100 87.8 ug/L 88 58 -135
1,1,2-Trichloroethane ND 25.0 24.0 ug/L 96 80 -120
Trichloroethene ND 25.0 24.0 ug/L 96 80 -120
Methyl acetate ND 50.0 42.5 ug/L 85 59 -136
1,1,2,2-Tetrachloroethane ND 25.0 27.0 ug/L 108 74 -123
1,2,3-Trichlorobenzene ND 25.0 18.1 ug/L 73 65 -129
Hexachlorobutadiene ND F1 25.0 6.79 F1 ug/L 27 73 -128
Naphthalene ND 25.0 22.2 ug/L 89 60 -124
o-Xylene ND 25.0 23.9 ug/L 96 80 -120
2-Chlorotoluene ND 25.0 22.8 ug/L 91 80 -120
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Page 27 of 777
QC Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: MW-63-241030Lab Sample ID: 280-198899-3 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 674451
1,2-Dichlorobenzene ND 25.0 23.1 ug/L 92 80 -120
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits
1,2,4-Trimethylbenzene ND 25.0 20.3 ug/L 81 79 -124
1,2-Dibromo-3-Chloropropane ND 25.0 24.6 ug/L 98 73 -128
1,2,3-Trichloropropane ND 25.0 25.9 ug/L 104 80 -120
Ethyl methacrylate ND 25.0 24.4 ug/L 97 80 -122
tert-Butylbenzene ND F1 25.0 18.7 F1 ug/L 75 80 -120
Isopropylbenzene ND 25.0 21.5 ug/L 86 78 -122
4-Isopropyltoluene ND F1 25.0 16.8 F1 ug/L 67 80 -122
1,2-Dichloroethane-d4 (Surr)70 -127
Surrogate
90
MS MS
Qualifier Limits%Recovery
100Dibromofluoromethane (Surr)77 -120
106Toluene-d8 (Surr)80 -125
934-Bromofluorobenzene (Surr)78 -120
Client Sample ID: MW-63-241030Lab Sample ID: 280-198899-3 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 674451
Ethylbenzene ND 25.0 24.2 ug/L 97 80 -120 2 20
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits LimitRPD
RPD
Styrene ND 25.0 24.9 ug/L 100 80 -120 5 20
cis-1,3-Dichloropropene ND 25.0 26.6 ug/L 106 76 -129 7 20
trans-1,3-Dichloropropene ND F1 25.0 20.9 ug/L 84 80 -123 10 20
N-Propylbenzene ND 25.0 20.7 ug/L 83 80 -123 1 20
n-Butylbenzene ND F1 25.0 13.0 F1 ug/L 52 59 -140 1 20
4-Chlorotoluene ND 25.0 23.1 ug/L 92 80 -120 1 20
1,4-Dichlorobenzene ND 25.0 23.6 ug/L 94 80 -120 2 20
Ethylene Dibromide ND 25.0 26.4 ug/L 105 80 -120 5 20
3-Chloro-1-propene ND 25.0 23.2 ug/L 93 65 -132 11 20
1,2-Dichloroethane ND 25.0 24.0 ug/L 96 71 -121 10 20
Vinyl acetate ND 50.0 52.8 ug/L 106 55 -161 10 23
4-Methyl-2-pentanone (MIBK)ND 100 98.3 ug/L 98 66 -135 7 20
1,3,5-Trimethylbenzene ND 25.0 20.5 ug/L 82 80 -122 1 20
Bromobenzene ND 25.0 25.3 ug/L 101 80 -120 3 20
Methylcyclohexane ND F1 25.0 13.3 F1 ug/L 53 64 -130 0 21
Toluene ND 25.0 25.9 ug/L 104 80 -120 7 20
Chlorobenzene ND 25.0 25.3 ug/L 101 80 -120 3 20
Tetrahydrofuran ND 50.0 48.4 ug/L 97 62 -130 8 20
Hexane ND F1 25.0 13.6 ug/L 55 55 -143 1 23
Cyclohexane ND 25.0 19.9 ug/L 79 68 -125 6 32
1,2,4-Trichlorobenzene ND F1 25.0 17.2 F1 ug/L 69 74 -126 2 20
Chlorodibromomethane ND 25.0 23.1 ug/L 92 80 -125 7 20
Tetrachloroethene ND 25.0 26.5 ug/L 106 80 -121 4 20
sec-Butylbenzene ND F1 25.0 16.2 F1 ug/L 65 80 -123 0 20
1,3-Dichloropropane ND 25.0 25.2 ug/L 101 77 -122 3 20
cis-1,2-Dichloroethene ND 25.0 26.6 ug/L 106 80 -120 10 20
trans-1,2-Dichloroethene ND 25.0 26.8 ug/L 107 79 -121 9 20
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3:53:55 PM
Page 28 of 777
QC Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: MW-63-241030Lab Sample ID: 280-198899-3 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 674451
Methyl tert-butyl ether ND 25.0 26.5 ug/L 106 80 -120 9 20
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits LimitRPD
RPD
m-Xylene & p-Xylene ND 25.0 25.3 ug/L 101 80 -120 3 20
1,3-Dichlorobenzene ND 25.0 21.8 ug/L 87 80 -120 1 20
Carbon tetrachloride ND 25.0 24.9 ug/L 100 79 -127 13 20
1,1-Dichloropropene ND 25.0 24.2 ug/L 97 77 -123 6 20
2-Hexanone ND 100 102 ug/L 102 62 -137 5 21
2,2-Dichloropropane ND 25.0 24.0 ug/L 96 75 -131 11 22
Ethyl ether ND 25.0 26.8 ug/L 107 68 -132 9 20
1,1,1,2-Tetrachloroethane ND 25.0 26.0 ug/L 104 80 -124 6 20
Acetone ND 100 96.3 ug/L 96 61 -134 10 21
Chloroform ND 25.0 26.1 ug/L 104 80 -120 11 20
Benzene ND 25.0 26.2 ug/L 105 80 -120 9 20
1,1,1-Trichloroethane ND 25.0 25.2 ug/L 101 80 -123 7 20
Bromomethane ND *1 25.0 29.3 ug/L 117 29 -148 8 40
Chloromethane ND 25.0 27.6 ug/L 110 56 -133 10 20
Iodomethane ND 25.0 31.7 ug/L 127 43 -139 13 38
Dibromomethane ND 25.0 25.1 ug/L 100 80 -120 9 20
Chlorobromomethane ND 25.0 28.2 ug/L 113 80 -123 9 20
Chloroethane ND 25.0 26.7 ug/L 107 56 -141 11 30
Vinyl chloride ND 25.0 26.6 ug/L 107 67 -127 10 25
Methylene Chloride ND 25.0 25.8 ug/L 103 78 -120 8 20
Carbon disulfide ND 25.0 26.6 ug/L 106 70 -121 13 20
Bromoform ND 25.0 22.3 ug/L 89 79 -138 8 20
Dichlorobromomethane ND 25.0 22.5 ug/L 90 80 -123 11 20
1,1-Dichloroethane ND 25.0 26.6 ug/L 106 78 -121 10 20
1,1-Dichloroethene ND 25.0 25.3 ug/L 101 77 -121 9 21
Trichlorofluoromethane ND 25.0 24.6 ug/L 98 54 -144 8 28
Dichlorodifluoromethane ND 25.0 22.4 ug/L 89 47 -135 10 21
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
ND 25.0 25.4 ug/L 101 73 -132 6 23
1,2-Dichloropropane ND 25.0 25.2 ug/L 101 78 -120 8 20
2-Butanone (MEK)ND 100 98.1 ug/L 98 58 -135 11 20
1,1,2-Trichloroethane ND 25.0 24.8 ug/L 99 80 -120 3 20
Trichloroethene ND 25.0 24.8 ug/L 99 80 -120 3 20
Methyl acetate ND 50.0 46.6 ug/L 93 59 -136 9 20
1,1,2,2-Tetrachloroethane ND 25.0 27.4 ug/L 110 74 -123 2 20
1,2,3-Trichlorobenzene ND 25.0 17.5 ug/L 70 65 -129 3 20
Hexachlorobutadiene ND F1 25.0 6.45 F1 ug/L 26 73 -128 5 20
Naphthalene ND 25.0 22.2 ug/L 89 60 -124 0 21
o-Xylene ND 25.0 24.6 ug/L 98 80 -120 3 20
2-Chlorotoluene ND 25.0 22.9 ug/L 92 80 -120 0 20
1,2-Dichlorobenzene ND 25.0 23.3 ug/L 93 80 -120 1 20
1,2,4-Trimethylbenzene ND 25.0 20.9 ug/L 84 79 -124 3 20
1,2-Dibromo-3-Chloropropane ND 25.0 24.9 ug/L 100 73 -128 1 21
1,2,3-Trichloropropane ND 25.0 26.9 ug/L 107 80 -120 4 20
Ethyl methacrylate ND 25.0 25.7 ug/L 103 80 -122 5 20
tert-Butylbenzene ND F1 25.0 18.6 F1 ug/L 75 80 -120 0 20
Isopropylbenzene ND 25.0 21.7 ug/L 87 78 -122 1 20
4-Isopropyltoluene ND F1 25.0 16.5 F1 ug/L 66 80 -122 2 20
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Page 29 of 777
QC Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
1,2-Dichloroethane-d4 (Surr)70 -127
Surrogate
92
MSD MSD
Qualifier Limits%Recovery
101Dibromofluoromethane (Surr)77 -120
105Toluene-d8 (Surr)80 -125
914-Bromofluorobenzene (Surr)78 -120
Client Sample ID: Method BlankLab Sample ID: MB 280-674813/9
Matrix: Water Prep Type: Total/NA
Analysis Batch: 674813
RL MDL
Ethylbenzene ND 1.0 0.14 ug/L 11/13/24 09:05 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
ND 0.131.0 ug/L 11/13/24 09:05 1Styrene
ND 0.161.0 ug/L 11/13/24 09:05 1cis-1,3-Dichloropropene
ND 0.141.0 ug/L 11/13/24 09:05 1trans-1,3-Dichloropropene
ND 0.181.0 ug/L 11/13/24 09:05 1N-Propylbenzene
ND 0.231.0 ug/L 11/13/24 09:05 1n-Butylbenzene
ND 0.211.0 ug/L 11/13/24 09:05 14-Chlorotoluene
ND 0.391.0 ug/L 11/13/24 09:05 11,4-Dichlorobenzene
ND 0.181.0 ug/L 11/13/24 09:05 1Ethylene Dibromide
ND 0.462.0 ug/L 11/13/24 09:05 13-Chloro-1-propene
ND 0.281.0 ug/L 11/13/24 09:05 11,2-Dichloroethane
ND 0.363.0 ug/L 11/13/24 09:05 1Vinyl acetate
ND 0.985.0 ug/L 11/13/24 09:05 14-Methyl-2-pentanone (MIBK)
ND 0.121.0 ug/L 11/13/24 09:05 11,3,5-Trimethylbenzene
ND 0.191.0 ug/L 11/13/24 09:05 1Bromobenzene
ND 0.311.0 ug/L 11/13/24 09:05 1Methylcyclohexane
ND 0.321.0 ug/L 11/13/24 09:05 1Toluene
ND 0.0921.0 ug/L 11/13/24 09:05 1Chlorobenzene
ND 0.847.0 ug/L 11/13/24 09:05 1Tetrahydrofuran
ND 0.162.0 ug/L 11/13/24 09:05 1Hexane
ND 0.441.0 ug/L 11/13/24 09:05 1Cyclohexane
ND 0.581.0 ug/L 11/13/24 09:05 11,2,4-Trichlorobenzene
ND 0.281.0 ug/L 11/13/24 09:05 1Chlorodibromomethane
ND 0.401.0 ug/L 11/13/24 09:05 1Tetrachloroethene
ND 0.201.0 ug/L 11/13/24 09:05 1sec-Butylbenzene
ND 0.171.0 ug/L 11/13/24 09:05 11,3-Dichloropropane
ND 0.321.0 ug/L 11/13/24 09:05 1cis-1,2-Dichloroethene
ND 0.371.0 ug/L 11/13/24 09:05 1trans-1,2-Dichloroethene
ND 0.255.0 ug/L 11/13/24 09:05 1Methyl tert-butyl ether
ND 0.362.0 ug/L 11/13/24 09:05 1m-Xylene & p-Xylene
ND 0.331.0 ug/L 11/13/24 09:05 11,3-Dichlorobenzene
ND 0.231.0 ug/L 11/13/24 09:05 1Carbon tetrachloride
ND 0.191.0 ug/L 11/13/24 09:05 11,1-Dichloropropene
ND 0.815.0 ug/L 11/13/24 09:05 12-Hexanone
ND 0.171.0 ug/L 11/13/24 09:05 12,2-Dichloropropane
ND 0.352.0 ug/L 11/13/24 09:05 1Ethyl ether
ND 0.161.0 ug/L 11/13/24 09:05 11,1,1,2-Tetrachloroethane
ND 6.615 ug/L 11/13/24 09:05 1Acetone
ND 0.361.0 ug/L 11/13/24 09:05 1Chloroform
ND 0.141.0 ug/L 11/13/24 09:05 1Benzene
ND 0.391.0 ug/L 11/13/24 09:05 11,1,1-Trichloroethane
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Page 30 of 777
QC Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 280-674813/9
Matrix: Water Prep Type: Total/NA
Analysis Batch: 674813
RL MDL
Bromomethane ND 5.0 2.4 ug/L 11/13/24 09:05 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
ND 0.232.0 ug/L 11/13/24 09:05 1Chloromethane
ND 2.65.0 ug/L 11/13/24 09:05 1Iodomethane
ND 0.341.0 ug/L 11/13/24 09:05 1Dibromomethane
ND 0.401.0 ug/L 11/13/24 09:05 1Chlorobromomethane
ND 0.642.0 ug/L 11/13/24 09:05 1Chloroethane
ND 0.231.0 ug/L 11/13/24 09:05 1Vinyl chloride
ND 0.942.0 ug/L 11/13/24 09:05 1Methylene Chloride
ND 0.262.0 ug/L 11/13/24 09:05 1Carbon disulfide
ND 0.252.0 ug/L 11/13/24 09:05 1Bromoform
ND 0.191.0 ug/L 11/13/24 09:05 1Dichlorobromomethane
ND 0.221.0 ug/L 11/13/24 09:05 11,1-Dichloroethane
ND 0.231.0 ug/L 11/13/24 09:05 11,1-Dichloroethene
ND 0.202.0 ug/L 11/13/24 09:05 1Trichlorofluoromethane
ND 0.302.0 ug/L 11/13/24 09:05 1Dichlorodifluoromethane
ND 0.733.0 ug/L 11/13/24 09:05 11,1,2-Trichloro-1,2,2-trifluoroethane
ND 0.241.0 ug/L 11/13/24 09:05 11,2-Dichloropropane
ND 4.610 ug/L 11/13/24 09:05 12-Butanone (MEK)
ND 0.271.0 ug/L 11/13/24 09:05 11,1,2-Trichloroethane
ND 0.301.0 ug/L 11/13/24 09:05 1Trichloroethene
ND 1.65.0 ug/L 11/13/24 09:05 1Methyl acetate
ND 0.211.0 ug/L 11/13/24 09:05 11,1,2,2-Tetrachloroethane
ND 1.24.0 ug/L 11/13/24 09:05 11,2,3-Trichlorobenzene
ND 0.532.0 ug/L 11/13/24 09:05 1Hexachlorobutadiene
ND 0.993.0 ug/L 11/13/24 09:05 1Naphthalene
ND 0.111.0 ug/L 11/13/24 09:05 1o-Xylene
ND 0.341.0 ug/L 11/13/24 09:05 12-Chlorotoluene
ND 0.141.0 ug/L 11/13/24 09:05 11,2-Dichlorobenzene
ND 0.151.0 ug/L 11/13/24 09:05 11,2,4-Trimethylbenzene
ND 0.425.0 ug/L 11/13/24 09:05 11,2-Dibromo-3-Chloropropane
ND 0.282.5 ug/L 11/13/24 09:05 11,2,3-Trichloropropane
ND 0.193.0 ug/L 11/13/24 09:05 1Ethyl methacrylate
ND 0.181.0 ug/L 11/13/24 09:05 1tert-Butylbenzene
ND 0.161.0 ug/L 11/13/24 09:05 1Isopropylbenzene
ND 0.191.0 ug/L 11/13/24 09:05 14-Isopropyltoluene
ND 0.111.0 ug/L 11/13/24 09:05 1Xylenes, Total
ND 0.321.0 ug/L 11/13/24 09:05 11,2-Dichloroethene, Total
ND 0.141.0 ug/L 11/13/24 09:05 11,3-Dichloropropene, Total
ND 0.191.0 ug/L 11/13/24 09:05 1Trihalomethanes, Total
ND 0.141.0 ug/L 11/13/24 09:05 1Total BTEX
1,2-Dichloroethane-d4 (Surr)107 70 -127 11/13/24 09:05 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
101 11/13/24 09:05 1Dibromofluoromethane (Surr)77 -120
100 11/13/24 09:05 1Toluene-d8 (Surr)80 -125
98 11/13/24 09:05 14-Bromofluorobenzene (Surr)78 -120
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Page 31 of 777
QC Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 280-674813/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 674813
Ethylbenzene 50.0 51.4 ug/L 103 80 -120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Styrene 50.0 51.7 ug/L 103 80 -120
cis-1,3-Dichloropropene 50.0 53.7 ug/L 107 76 -129
trans-1,3-Dichloropropene 50.0 53.8 ug/L 108 80 -123
N-Propylbenzene 50.0 52.0 ug/L 104 80 -123
n-Butylbenzene 50.0 50.3 ug/L 101 59 -140
4-Chlorotoluene 50.0 50.9 ug/L 102 80 -120
1,4-Dichlorobenzene 50.0 49.6 ug/L 99 80 -120
Ethylene Dibromide 50.0 48.9 ug/L 98 80 -120
3-Chloro-1-propene 50.0 55.3 ug/L 111 65 -132
1,2-Dichloroethane 50.0 52.0 ug/L 104 71 -121
Vinyl acetate 100 116 ug/L 116 55 -161
4-Methyl-2-pentanone (MIBK)200 225 ug/L 112 66 -135
1,3,5-Trimethylbenzene 50.0 51.2 ug/L 102 80 -122
Bromobenzene 50.0 51.5 ug/L 103 80 -120
Methylcyclohexane 50.0 49.4 ug/L 99 64 -130
Toluene 50.0 52.2 ug/L 104 80 -120
Chlorobenzene 50.0 51.3 ug/L 103 80 -120
Tetrahydrofuran 100 102 ug/L 102 62 -130
Hexane 50.0 47.5 ug/L 95 55 -143
Cyclohexane 50.0 50.7 ug/L 101 68 -125
1,2,4-Trichlorobenzene 50.0 44.9 ug/L 90 74 -126
Chlorodibromomethane 50.0 54.1 ug/L 108 80 -125
Tetrachloroethene 50.0 51.4 ug/L 103 80 -121
sec-Butylbenzene 50.0 49.6 ug/L 99 80 -123
1,3-Dichloropropane 50.0 51.7 ug/L 103 77 -122
cis-1,2-Dichloroethene 50.0 51.5 ug/L 103 80 -120
trans-1,2-Dichloroethene 50.0 52.0 ug/L 104 79 -121
Methyl tert-butyl ether 50.0 52.0 ug/L 104 80 -120
m-Xylene & p-Xylene 50.0 50.3 ug/L 101 80 -120
1,3-Dichlorobenzene 50.0 50.5 ug/L 101 80 -120
Carbon tetrachloride 50.0 53.5 ug/L 107 79 -127
1,1-Dichloropropene 50.0 51.4 ug/L 103 77 -123
2-Hexanone 200 210 ug/L 105 62 -137
2,2-Dichloropropane 50.0 50.4 ug/L 101 75 -131
Ethyl ether 50.0 49.7 ug/L 99 68 -132
1,1,1,2-Tetrachloroethane 50.0 54.1 ug/L 108 80 -124
Acetone 200 195 ug/L 97 61 -134
Chloroform 50.0 52.4 ug/L 105 80 -120
Benzene 50.0 52.2 ug/L 104 80 -120
1,1,1-Trichloroethane 50.0 52.8 ug/L 106 80 -123
Bromomethane 50.0 37.2 ug/L 74 29 -148
Chloromethane 50.0 52.8 ug/L 106 56 -133
Iodomethane 50.0 56.0 ug/L 112 43 -139
Dibromomethane 50.0 47.7 ug/L 95 80 -120
Chlorobromomethane 50.0 49.6 ug/L 99 80 -123
Chloroethane 50.0 55.5 ug/L 111 56 -141
Vinyl chloride 50.0 56.3 ug/L 113 67 -127
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Page 32 of 777
QC Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 280-674813/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 674813
Methylene Chloride 50.0 50.2 ug/L 100 78 -120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Carbon disulfide 50.0 51.2 ug/L 102 70 -121
Bromoform 50.0 53.1 ug/L 106 79 -138
Dichlorobromomethane 50.0 54.0 ug/L 108 80 -123
1,1-Dichloroethane 50.0 52.1 ug/L 104 78 -121
1,1-Dichloroethene 50.0 50.2 ug/L 100 77 -121
Trichlorofluoromethane 50.0 53.5 ug/L 107 54 -144
Dichlorodifluoromethane 50.0 53.0 ug/L 106 47 -135
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
50.0 48.7 ug/L 97 73 -132
1,2-Dichloropropane 50.0 52.6 ug/L 105 78 -120
2-Butanone (MEK)200 204 ug/L 102 58 -135
1,1,2-Trichloroethane 50.0 52.6 ug/L 105 80 -120
Trichloroethene 50.0 45.9 ug/L 92 80 -120
Methyl acetate 100 106 ug/L 106 59 -136
1,1,2,2-Tetrachloroethane 50.0 54.5 ug/L 109 74 -123
1,2,3-Trichlorobenzene 50.0 45.5 ug/L 91 65 -129
Hexachlorobutadiene 50.0 51.5 ug/L 103 73 -128
Naphthalene 50.0 40.7 ug/L 81 60 -124
o-Xylene 50.0 51.6 ug/L 103 80 -120
2-Chlorotoluene 50.0 50.9 ug/L 102 80 -120
1,2-Dichlorobenzene 50.0 47.4 ug/L 95 80 -120
1,2,4-Trimethylbenzene 50.0 50.8 ug/L 102 79 -124
1,2-Dibromo-3-Chloropropane 50.0 47.8 ug/L 96 73 -128
1,2,3-Trichloropropane 50.0 49.5 ug/L 99 80 -120
Ethyl methacrylate 50.0 52.4 ug/L 105 80 -122
tert-Butylbenzene 50.0 50.6 ug/L 101 80 -120
Isopropylbenzene 50.0 51.4 ug/L 103 78 -122
4-Isopropyltoluene 50.0 51.1 ug/L 102 80 -122
1,2-Dichloroethane-d4 (Surr)70 -127
Surrogate
101
LCS LCS
Qualifier Limits%Recovery
104Dibromofluoromethane (Surr)77 -120
99Toluene-d8 (Surr)80 -125
1004-Bromofluorobenzene (Surr)78 -120
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 280-674813/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 674813
Ethylbenzene 50.0 51.1 ug/L 102 80 -120 0 20
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
Styrene 50.0 51.0 ug/L 102 80 -120 1 20
cis-1,3-Dichloropropene 50.0 52.5 ug/L 105 76 -129 2 20
trans-1,3-Dichloropropene 50.0 54.2 ug/L 108 80 -123 1 20
N-Propylbenzene 50.0 50.8 ug/L 102 80 -123 2 20
n-Butylbenzene 50.0 48.8 ug/L 98 59 -140 3 20
4-Chlorotoluene 50.0 49.2 ug/L 98 80 -120 3 20
1,4-Dichlorobenzene 50.0 49.0 ug/L 98 80 -120 1 20
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Page 33 of 777
QC Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 280-674813/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 674813
Ethylene Dibromide 50.0 48.4 ug/L 97 80 -120 1 20
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
3-Chloro-1-propene 50.0 55.8 ug/L 112 65 -132 1 20
1,2-Dichloroethane 50.0 52.6 ug/L 105 71 -121 1 20
Vinyl acetate 100 112 ug/L 112 55 -161 4 23
4-Methyl-2-pentanone (MIBK)200 226 ug/L 113 66 -135 1 20
1,3,5-Trimethylbenzene 50.0 50.3 ug/L 101 80 -122 2 20
Bromobenzene 50.0 50.4 ug/L 101 80 -120 2 20
Methylcyclohexane 50.0 48.1 ug/L 96 64 -130 3 21
Toluene 50.0 52.3 ug/L 105 80 -120 0 20
Chlorobenzene 50.0 50.5 ug/L 101 80 -120 1 20
Tetrahydrofuran 100 103 ug/L 103 62 -130 1 20
Hexane 50.0 45.3 ug/L 91 55 -143 5 23
Cyclohexane 50.0 49.6 ug/L 99 68 -125 2 32
1,2,4-Trichlorobenzene 50.0 44.1 ug/L 88 74 -126 2 20
Chlorodibromomethane 50.0 53.1 ug/L 106 80 -125 2 20
Tetrachloroethene 50.0 51.1 ug/L 102 80 -121 1 20
sec-Butylbenzene 50.0 48.5 ug/L 97 80 -123 2 20
1,3-Dichloropropane 50.0 51.2 ug/L 102 77 -122 1 20
cis-1,2-Dichloroethene 50.0 50.2 ug/L 100 80 -120 2 20
trans-1,2-Dichloroethene 50.0 51.1 ug/L 102 79 -121 2 20
Methyl tert-butyl ether 50.0 52.7 ug/L 105 80 -120 1 20
m-Xylene & p-Xylene 50.0 48.7 ug/L 97 80 -120 3 20
1,3-Dichlorobenzene 50.0 49.4 ug/L 99 80 -120 2 20
Carbon tetrachloride 50.0 53.4 ug/L 107 79 -127 0 20
1,1-Dichloropropene 50.0 51.6 ug/L 103 77 -123 0 20
2-Hexanone 200 206 ug/L 103 62 -137 2 21
2,2-Dichloropropane 50.0 49.0 ug/L 98 75 -131 3 22
Ethyl ether 50.0 51.6 ug/L 103 68 -132 4 20
1,1,1,2-Tetrachloroethane 50.0 53.4 ug/L 107 80 -124 1 20
Acetone 200 196 ug/L 98 61 -134 0 21
Chloroform 50.0 53.1 ug/L 106 80 -120 1 20
Benzene 50.0 52.5 ug/L 105 80 -120 1 20
1,1,1-Trichloroethane 50.0 53.3 ug/L 107 80 -123 1 20
Bromomethane 50.0 41.4 ug/L 83 29 -148 11 40
Chloromethane 50.0 53.9 ug/L 108 56 -133 2 20
Iodomethane 50.0 58.3 ug/L 117 43 -139 4 38
Dibromomethane 50.0 48.0 ug/L 96 80 -120 1 20
Chlorobromomethane 50.0 51.4 ug/L 103 80 -123 4 20
Chloroethane 50.0 52.7 ug/L 105 56 -141 5 30
Vinyl chloride 50.0 52.7 ug/L 105 67 -127 7 25
Methylene Chloride 50.0 49.8 ug/L 100 78 -120 1 20
Carbon disulfide 50.0 50.6 ug/L 101 70 -121 1 20
Bromoform 50.0 50.8 ug/L 102 79 -138 4 20
Dichlorobromomethane 50.0 53.9 ug/L 108 80 -123 0 20
1,1-Dichloroethane 50.0 52.3 ug/L 105 78 -121 0 20
1,1-Dichloroethene 50.0 50.2 ug/L 100 77 -121 0 21
Trichlorofluoromethane 50.0 48.7 ug/L 97 54 -144 9 28
Dichlorodifluoromethane 50.0 48.1 ug/L 96 47 -135 10 21
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QC Sample Results
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 280-674813/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 674813
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
50.0 48.7 ug/L 97 73 -132 0 23
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
1,2-Dichloropropane 50.0 52.8 ug/L 106 78 -120 0 20
2-Butanone (MEK)200 206 ug/L 103 58 -135 1 20
1,1,2-Trichloroethane 50.0 51.7 ug/L 103 80 -120 2 20
Trichloroethene 50.0 47.0 ug/L 94 80 -120 2 20
Methyl acetate 100 107 ug/L 107 59 -136 1 20
1,1,2,2-Tetrachloroethane 50.0 53.7 ug/L 107 74 -123 2 20
1,2,3-Trichlorobenzene 50.0 43.9 ug/L 88 65 -129 3 20
Hexachlorobutadiene 50.0 49.3 ug/L 99 73 -128 4 20
Naphthalene 50.0 40.6 ug/L 81 60 -124 0 21
o-Xylene 50.0 51.6 ug/L 103 80 -120 0 20
2-Chlorotoluene 50.0 49.2 ug/L 98 80 -120 3 20
1,2-Dichlorobenzene 50.0 48.2 ug/L 96 80 -120 2 20
1,2,4-Trimethylbenzene 50.0 50.4 ug/L 101 79 -124 1 20
1,2-Dibromo-3-Chloropropane 50.0 48.7 ug/L 97 73 -128 2 21
1,2,3-Trichloropropane 50.0 50.2 ug/L 100 80 -120 1 20
Ethyl methacrylate 50.0 50.5 ug/L 101 80 -122 4 20
tert-Butylbenzene 50.0 49.2 ug/L 98 80 -120 3 20
Isopropylbenzene 50.0 50.2 ug/L 100 78 -122 2 20
4-Isopropyltoluene 50.0 49.8 ug/L 100 80 -122 2 20
1,2-Dichloroethane-d4 (Surr)70 -127
Surrogate
107
LCSD LCSD
Qualifier Limits%Recovery
103Dibromofluoromethane (Surr)77 -120
98Toluene-d8 (Surr)80 -125
1014-Bromofluorobenzene (Surr)78 -120
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Page 35 of 777
QC Association Summary
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
GC/MS VOA
Analysis Batch: 674451
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 8260D280-198899-2 MW-61-241030 Total/NA
Water 8260D280-198899-3 MW-63-241030 Total/NA
Water 8260D280-198899-4 FB-01 Total/NA
Water 8260D280-198899-5 DS-01 Total/NA
Water 8260D280-198899-6 Trip Blank Total/NA
Water 8260DMB 280-674451/9 Method Blank Total/NA
Water 8260DLCS 280-674451/4 Lab Control Sample Total/NA
Water 8260DLCSD 280-674451/5 Lab Control Sample Dup Total/NA
Water 8260D280-198899-3 MS MW-63-241030 Total/NA
Water 8260D280-198899-3 MSD MW-63-241030 Total/NA
Analysis Batch: 674813
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 8260D280-198899-5 - DL DS-01 Total/NA
Water 8260DMB 280-674813/9 Method Blank Total/NA
Water 8260DLCS 280-674813/4 Lab Control Sample Total/NA
Water 8260DLCSD 280-674813/5 Lab Control Sample Dup Total/NA
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Lab Chronicle
Client: Ramboll Americas Engineering Solutions Job ID: 280-198899-1
Project/Site: Moog-SLC, UT
Client Sample ID: MW-61-241030 Lab Sample ID: 280-198899-2
Matrix: WaterDate Collected: 10/30/24 11:10
Date Received: 10/31/24 09:10
Analysis 8260D MD11/11/24 12:1250 EET DEN674451
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: MW-63-241030 Lab Sample ID: 280-198899-3
Matrix: WaterDate Collected: 10/30/24 12:20
Date Received: 10/31/24 09:10
Analysis 8260D MD11/11/24 09:251 EET DEN674451
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: FB-01 Lab Sample ID: 280-198899-4
Matrix: WaterDate Collected: 10/30/24 00:00
Date Received: 10/31/24 09:10
Analysis 8260D MD11/11/24 08:241 EET DEN674451
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: DS-01 Lab Sample ID: 280-198899-5
Matrix: WaterDate Collected: 10/30/24 00:00
Date Received: 10/31/24 09:10
Analysis 8260D MD11/11/24 11:50100 EET DEN674451
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Analysis 8260D DL 500 674813 11/13/24 15:34 TAW EET DENTotal/NA 5 mL 5 mL
Client Sample ID: Trip Blank Lab Sample ID: 280-198899-6
Matrix: WaterDate Collected: 10/30/24 00:00
Date Received: 10/31/24 09:10
Analysis 8260D MD11/11/24 08:041 EET DEN674451
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Laboratory References:
EET DEN = Eurofins Denver, 4955 Yarrow Street, Arvada, CO 80002, TEL [phone]
Eurofins Denver
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Page 37 of 777
Accreditation/Certification Summary
Client: Ramboll Americas Engineering Solutions Job ID: 280-198899-1
Project/Site: Moog-SLC, UT
Laboratory: Eurofins Denver
The accreditations/certifications listed below are applicable to this report.
Authority Program Identification Number Expiration Date
Utah NELAP CO00026 07-31-25
Eurofins Denver
11/15/2024
3:53:55 PM
Page 38 of 777
Method Summary
Job ID: 280-198899-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method Method Description LaboratoryProtocol
SW8468260DVolatile Organic Compounds by GC/MS EET DEN
SW8465030BPurge and Trap EET DEN
Protocol References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
EET DEN = Eurofins Denver, 4955 Yarrow Street, Arvada, CO 80002, TEL [phone]
Eurofins Denver
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3:53:55 PM
Page 39 of 777
Sample Summary
Client: Ramboll Americas Engineering Solutions Job ID: 280-198899-1
Project/Site: Moog-SLC, UT
Lab Sample ID Client Sample ID Matrix Collected Received
280-198899-2 MW-61-241030 Water 10/30/24 11:10 10/31/24 09:10
280-198899-3 MW-63-241030 Water 10/30/24 12:20 10/31/24 09:10
280-198899-4 FB-01 Water 10/30/24 00:00 10/31/24 09:10
280-198899-5 DS-01 Water 10/30/24 00:00 10/31/24 09:10
280-198899-6 Trip Blank Water 10/30/24 00:00 10/31/24 09:10
Eurofins Denver11/15/2024
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Page 40 of 777
Lab Name:Job No.:
GC/MS VOA MANUAL INTEGRATION SUMMARY
Eurofins Denver 280-198899-1
SDG No.:
Instrument ID:Analysis Batch Number:VMS_MS14 672942
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
IC 280-672942/40
VMS14_0000003776.D10/29/24 18:22 GC Column:DB-624 (60.25)ID:0.25(mm)
1,4-Dioxane Split Peak LP8K 10/29/24 19:045.90
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
IC 280-672942/41
VMS14_0000003777.D10/29/24 18:42 GC Column:DB-624 (60.25)ID:0.25(mm)
1,4-Dioxane Split Peak LP8K 10/29/24 19:045.90
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
IC 280-672942/42
VMS14_0000003778.D10/29/24 19:02 GC Column:DB-624 (60.25)ID:0.25(mm)
2-Methyl-2-propanol Split Peak LP8K 10/29/24 19:563.58
Chlorobromomethane Missed Peak LP8K 10/29/24 19:564.66
1,1,1-Trichloroethane Split Peak LP8K 10/29/24 19:574.88
Carbon tetrachloride Split Peak LP8K 10/29/24 20:155.00
1,2-Dichloroethane Split Peak LP8K 10/29/24 19:575.16
n-Heptane Split Peak LP8K 10/29/24 19:575.33
Methylcyclohexane Split Peak LP8K 10/29/24 19:575.84
1,4-Dioxane Split Peak LP8K 10/29/24 19:575.91
Dichlorobromomethane Split Peak LP8K 10/29/24 19:576.05
2-Chloroethyl vinyl ether Split Peak LP8K 10/29/24 19:576.24
Chlorodibromomethane Split Peak LP8K 10/29/24 19:577.40
1,2-Dibromo-3-Chloropropane Split Peak LP8K 10/29/24 19:5711.35
1,2,3-Trichlorobenzene Missed Peak LP8K 10/29/24 19:5712.69
8260D
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Page 41 of 777
Lab Name:Job No.:
GC/MS VOA MANUAL INTEGRATION SUMMARY
Eurofins Denver 280-198899-1
SDG No.:
Instrument ID:Analysis Batch Number:VMS_MS14 672942
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
IC 280-672942/43
VMS14_0000003779.D10/29/24 19:22 GC Column:DB-624 (60.25)ID:0.25(mm)
3-Chloro-1-propene Wrong peak LP8K 10/29/24 19:583.41
Methylene Chloride Split Peak LP8K 10/29/24 19:593.52
1,1-Dichloroethane Split Peak LP8K 10/29/24 19:594.06
2,2-Dichloropropane Split Peak LP8K 10/29/24 19:594.50
1,1,1-Trichloroethane Split Peak LP8K 10/29/24 19:594.88
Cyclohexane Split Peak LP8K 10/29/24 19:594.94
Carbon tetrachloride Split Peak LP8K 10/29/24 19:595.00
1,2-Dichloroethane Split Peak LP8K 10/29/24 19:595.17
1,4-Dioxane Split Peak LP8K 10/29/24 19:595.90
Dichlorobromomethane Split Peak LP8K 10/29/24 20:006.04
cis-1,3-Dichloropropene Split Peak LP8K 10/29/24 20:006.39
trans-1,3-Dichloropropene Split Peak LP8K 10/29/24 20:006.87
1,1,2-Trichloroethane Split Peak LP8K 10/29/24 20:007.04
m-Xylene & p-Xylene Split Peak LP8K 10/29/24 20:008.15
1,2-Dibromo-3-Chloropropane Split Peak LP8K 10/29/24 20:0011.34
Hexachlorobutadiene Split Peak LP8K 10/29/24 20:0012.33
8260D
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3:53:55 PM
Page 42 of 777
Lab Name:Job No.:
GC/MS VOA MANUAL INTEGRATION SUMMARY
Eurofins Denver 280-198899-1
SDG No.:
Instrument ID:Analysis Batch Number:VMS_MS14 672942
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
IC 280-672942/44
VMS14_0000003780.D10/29/24 19:42 GC Column:DB-624 (60.25)ID:0.25(mm)
Dichlorofluoromethane Split Peak LP8K 10/29/24 20:032.67
Ethyl ether Split Peak LP8K 10/29/24 20:032.94
Acrolein Split Peak LP8K 10/29/24 20:033.05
1,1,2-Trichloro-1,2,2-trifluoroet
hane
Split Peak LP8K 10/29/24 20:033.14
3-Chloro-1-propene Wrong peak LP8K 10/29/24 20:033.41
Methylene Chloride Split Peak LP8K 10/29/24 20:033.52
trans-1,2-Dichloroethene Split Peak LP8K 10/29/24 20:043.73
Hexane Split Peak LP8K 10/29/24 20:043.93
cis-1,2-Dichloroethene Split Peak LP8K 10/29/24 20:044.48
Chlorobromomethane Split Peak LP8K 10/29/24 20:044.65
Chloroform Split Peak LP8K 10/29/24 20:044.72
1,1,1-Trichloroethane Split Peak LP8K 10/29/24 20:044.87
1,1-Dichloropropene Split Peak LP8K 10/29/24 20:044.99
Methylcyclohexane Split Peak LP8K 10/29/24 20:055.85
Dibromomethane Split Peak LP8K 10/29/24 20:055.92
2-Chloroethyl vinyl ether Split Peak LP8K 10/29/24 20:056.25
cis-1,3-Dichloropropene Split Peak LP8K 10/29/24 20:056.40
Toluene Assign Peak LP8K 10/29/24 20:056.70
Ethyl methacrylate Split Peak LP8K 10/29/24 20:056.89
1,3-Dichloropropane Split Peak LP8K 10/29/24 20:057.20
Chlorodibromomethane Split Peak LP8K 10/29/24 20:057.40
Ethylene Dibromide Split Peak LP8K 10/29/24 20:067.52
1-Chlorohexane Split Peak LP8K 10/29/24 20:067.91
Isopropylbenzene Split Peak LP8K 10/29/24 20:068.87
1,3,5-Trimethylbenzene Split Peak LP8K 10/29/24 20:069.43
1,2-Dibromo-3-Chloropropane Split Peak LP8K 10/29/24 20:0611.34
Hexachlorobutadiene Split Peak LP8K 10/29/24 20:0612.33
1,2,3-Trichlorobenzene Split Peak LP8K 10/29/24 20:0612.69
8260D
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3:53:55 PM
Page 43 of 777
Lab Name:Job No.:
GC/MS VOA MANUAL INTEGRATION SUMMARY
Eurofins Denver 280-198899-1
SDG No.:
Instrument ID:Analysis Batch Number:VMS_MS14 674451
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
280-198899-3 MW-63-241030
VMS14_0000004278.D11/11/24 09:25 GC Column:DB-624 (60.25)ID:0.25(mm)
Carbon disulfide Split Peak LP8K 11/11/24 16:013.34
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
280-198899-5 DS-01
VMS14_0000004285.D11/11/24 11:50 GC Column:DB-624 (60.25)ID:0.25(mm)
m-Xylene & p-Xylene Split Peak LP8K 11/11/24 16:078.13
1,1-Dichloroethene Invalid Compound ID LP8K 11/11/24 16:07
Dichlorodifluoromethane Invalid Compound ID LP8K 11/11/24 16:07
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
280-198899-2 MW-61-241030
VMS14_0000004286.D11/11/24 12:12 GC Column:DB-624 (60.25)ID:0.25(mm)
1,1-Dichloroethane Split Peak LP8K 11/11/24 16:084.06
o-Xylene Split Peak LP8K 11/11/24 16:088.52
1,1-Dichloroethene Invalid Compound ID LP8K 11/11/24 16:08
Dichlorodifluoromethane Invalid Compound ID LP8K 11/11/24 17:30
8260D
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3:53:55 PM
Page 44 of 777
Lab Name:Job No.:
GC/MS VOA MANUAL INTEGRATION SUMMARY
Eurofins Denver 280-198899-1
SDG No.:
Instrument ID:Analysis Batch Number:VMS_X4 672931
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
IC 280-672931/35
X4_00008661.D10/29/24 17:11 GC Column:RXI-624SilMS ID:0.25(mm)
Iodomethane Assign Peak AK2J 10/29/24 20:523.17
sec-Butyl Alcohol Peak assignment corrected AK2J 10/29/24 17:404.44
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
IC 280-672931/36
X4_00008662.D10/29/24 17:32 GC Column:RXI-624SilMS ID:0.25(mm)
Iodomethane Assign Peak AK2J 10/29/24 20:513.17
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
IC 280-672931/37
X4_00008663.D10/29/24 17:53 GC Column:RXI-624SilMS ID:0.25(mm)
Iodomethane Assign Peak AK2J 10/29/24 20:513.17
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
ICIS 280-672931/38
X4_00008664.D10/29/24 18:14 GC Column:RXI-624SilMS ID:0.25(mm)
Iodomethane Assign Peak AK2J 10/29/24 20:513.17
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
IC 280-672931/39
X4_00008665.D10/29/24 18:35 GC Column:RXI-624SilMS ID:0.25(mm)
Iodomethane Assign Peak AK2J 10/29/24 20:503.17
8260D
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Page 45 of 777
Lab Name:Job No.:
GC/MS VOA MANUAL INTEGRATION SUMMARY
Eurofins Denver 280-198899-1
SDG No.:
Instrument ID:Analysis Batch Number:VMS_X4 672931
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
IC 280-672931/40
X4_00008666.D10/29/24 18:56 GC Column:RXI-624SilMS ID:0.25(mm)
Bromobenzene Assign Peak AK2J 10/29/24 19:458.98
1,4-Dichlorobenzene Assign Peak AK2J 10/29/24 19:469.98
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
IC 280-672931/41
X4_00008667.D10/29/24 19:17 GC Column:RXI-624SilMS ID:0.25(mm)
Chloroethane Assign Peak AK2J 10/29/24 19:412.42
Dichlorofluoromethane Assign Peak AK2J 10/29/24 19:452.60
1,1-Dichloroethene Assign Peak AK2J 10/29/24 19:443.04
Iodomethane Assign Peak AK2J 10/29/24 19:443.17
1,1,1-Trichloroethane Assign Peak AK2J 10/29/24 19:454.73
1,2-Dichloropropane Assign Peak AK2J 10/29/24 19:445.69
1,1,2-Trichloroethane Assign Peak AK2J 10/29/24 19:446.88
Chlorodibromomethane Assign Peak AK2J 10/29/24 20:107.21
Bromobenzene Assign Peak AK2J 10/29/24 19:438.98
1,2-Dibromo-3-Chloropropane Assign Peak AK2J 10/29/24 19:4311.13
8260D
11/15/2024
3:53:55 PM
Page 46 of 777
Lab Name:Job No.:
GC/MS VOA MANUAL INTEGRATION SUMMARY
Eurofins Denver 280-198899-1
SDG No.:
Instrument ID:Analysis Batch Number:VMS_X4 672931
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
IC 280-672931/42
X4_00008668.D10/29/24 19:38 GC Column:RXI-624SilMS ID:0.25(mm)
Ethyl ether Assign Peak AK2J 10/29/24 20:062.85
1,1,2-Trichloro-1,2,2-trifluoroet
hane
Assign Peak AK2J 10/29/24 20:073.03
Iodomethane Assign Peak AK2J 10/29/24 20:503.16
2,2-Dichloropropane Assign Peak AK2J 10/29/24 20:074.36
Chlorobromomethane Assign Peak AK2J 10/29/24 20:074.52
Chloroform Assign Peak AK2J 10/29/24 20:074.59
Dibromomethane Assign Peak AK2J 10/29/24 20:085.75
Dichlorobromomethane Assign Peak AK2J 10/29/24 20:085.88
1,1,2-Trichloroethane Assign Peak AK2J 10/29/24 20:086.87
Bromoform Assign Peak AK2J 10/29/24 20:088.52
1,2,3-Trichloropropane Assign Peak AK2J 10/29/24 20:119.01
N-Propylbenzene Assign Peak AK2J 10/29/24 20:119.06
2-Chlorotoluene Assign Peak AK2J 10/29/24 20:099.16
1,3-Dichlorobenzene Assign Peak AK2J 10/29/24 20:119.88
n-Butylbenzene Assign Peak AK2J 10/29/24 20:0910.31
1,2-Dichlorobenzene Assign Peak AK2J 10/29/24 20:0910.34
1,2,4-Trichlorobenzene Assign Peak AK2J 10/29/24 20:0911.96
Hexachlorobutadiene Assign Peak AK2J 10/29/24 20:0912.09
1,2,3-Trichlorobenzene Assign Peak AK2J 10/29/24 20:0912.43
8260D
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3:53:55 PM
Page 47 of 777
Lab Name:Job No.:
GC/MS VOA MANUAL INTEGRATION SUMMARY
Eurofins Denver 280-198899-1
SDG No.:
Instrument ID:Analysis Batch Number:VMS_X4 672931
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
IC 280-672931/43
X4_00008669.D10/29/24 20:00 GC Column:RXI-624SilMS ID:0.25(mm)
Vinyl chloride Assign Peak AK2J 10/29/24 20:192.04
Bromomethane Assign Peak AK2J 10/29/24 20:192.32
1,1-Dichloroethene Assign Peak AK2J 10/29/24 20:193.05
Iodomethane Assign Peak AK2J 10/29/24 20:493.18
Methyl tert-butyl ether Assign Peak AK2J 10/29/24 20:193.60
cis-1,2-Dichloroethene Assign Peak AK2J 10/29/24 20:204.35
2,2-Dichloropropane Assign Peak AK2J 10/29/24 20:204.36
1,1,1-Trichloroethane Assign Peak AK2J 10/29/24 20:204.73
Carbon tetrachloride Assign Peak AK2J 10/29/24 20:204.85
1,2-Dichloroethane Assign Peak AK2J 10/29/24 20:205.03
n-Heptane Assign Peak AK2J 10/29/24 20:205.17
Trichloroethene Assign Peak AK2J 10/29/24 20:215.48
1,2-Dichloropropane Assign Peak AK2J 10/29/24 20:215.69
trans-1,3-Dichloropropene Assign Peak AK2J 10/29/24 20:216.70
Chlorodibromomethane Assign Peak AK2J 10/29/24 20:217.21
1-Chlorohexane Assign Peak AK2J 10/29/24 20:217.72
1,1,1,2-Tetrachloroethane Assign Peak AK2J 10/29/24 20:227.82
Styrene Assign Peak AK2J 10/29/24 20:228.34
1,1,2,2-Tetrachloroethane Assign Peak AK2J 10/29/24 20:228.95
1,2,3-Trichloropropane Assign Peak AK2J 10/29/24 20:229.01
N-Propylbenzene Assign Peak AK2J 10/29/24 20:229.07
2-Chlorotoluene Assign Peak AK2J 10/29/24 20:229.15
sec-Butylbenzene Assign Peak AK2J 10/29/24 20:239.75
1,4-Dichlorobenzene Assign Peak AK2J 10/29/24 20:239.99
1,2-Dichlorobenzene Assign Peak AK2J 10/29/24 20:2310.35
1,2-Dibromo-3-Chloropropane Assign Peak AK2J 10/29/24 20:2311.13
8260D
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3:53:55 PM
Page 48 of 777
Lab Name:Job No.:
GC/MS VOA MANUAL INTEGRATION SUMMARY
Eurofins Denver 280-198899-1
SDG No.:
Instrument ID:Analysis Batch Number:VMS_X4 674813
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
MB 280-674813/9
X4_00009401.D11/13/24 09:05 GC Column:RXI-624SilMS ID:0.25(mm)
3-Chloro-1-propene Invalid Compound ID AF7X 11/13/24 10:02
m-Xylene & p-Xylene Invalid Compound ID AF7X 11/13/24 10:02
8260D
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3:53:55 PM
Page 49 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
MV-Gas A_00201 Bromomethane 5 ug/mL100 uL 2 uL11/01/24 10/28/24Cal Dil Std_00424 P&T Methanol, Lot EG359-US
Chloroethane 5 ug/mL
Chloromethane 5 ug/mL
Dichlorodifluoromethane 5 ug/mL
Dichlorofluoromethane 5 ug/mL
Trichlorofluoromethane 5 ug/mL
Vinyl chloride 5 ug/mL
2-Chloroethyl vinyl ether 5 ug/mL
Acrolein 49.375 ug/mLMV-MegaMainA_00118 5 uL
2-Butanone (MEK)20 ug/mL
2-Hexanone 20 ug/mL
4-Methyl-2-pentanone (MIBK)20 ug/mL
Acetone 20 ug/mL
Vinyl acetate 10 ug/mL
Cyclohexanone 150 ug/mL
1,1,1,2-Tetrachloroethane 5 ug/mL
1,1,1-Trichloroethane 5 ug/mL
1,1,2,2-Tetrachloroethane 5 ug/mL
1,1,2-Trichloro-1,2,2-trifluoroethane 5 ug/mL
1,1,2-Trichloroethane 5 ug/mL
1,1-Dichloroethane 5 ug/mL
1,1-Dichloroethene 5 ug/mL
1,1-Dichloropropene 5 ug/mL
1,2,3-Trichlorobenzene 5 ug/mL
1,2,3-Trichloropropane 5 ug/mL
1,2,4-Trichlorobenzene 5 ug/mL
1,2,4-Trimethylbenzene 5 ug/mL
1,2-Dibromo-3-Chloropropane 5 ug/mL
1,2-Dichlorobenzene 5 ug/mL
1,2-Dichloroethane 5 ug/mL
1,2-Dichloropropane 5 ug/mL
1,3,5-Trimethylbenzene 5 ug/mL
1,3-Dichlorobenzene 5 ug/mL
1,3-Dichloropropane 5 ug/mL
1,4-Dichlorobenzene 5 ug/mL
1,4-Dioxane 100 ug/mL
2,2-Dichloropropane 5 ug/mL
2-Chlorotoluene 5 ug/mL
2-Methyl-2-propanol 50 ug/mL
3-Chloro-1-propene 5 ug/mL
4-Chlorotoluene 5 ug/mL
4-Isopropyltoluene 5 ug/mL
Acrylonitrile 50 ug/mL
Benzene 5 ug/mL
Bromobenzene 5 ug/mL
11/15/2024
3:53:55 PM
Page 50 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Bromoform 5 ug/mL
Carbon disulfide 5 ug/mL
Carbon tetrachloride 5 ug/mL
Chlorobenzene 5 ug/mL
Chlorobromomethane 5 ug/mL
Chlorodibromomethane 5 ug/mL
Chloroform 5 ug/mL
cis-1,2-Dichloroethene 5 ug/mL
cis-1,3-Dichloropropene 5 ug/mL
Cyclohexane 5 ug/mL
Dibromomethane 5 ug/mL
Dichlorobromomethane 5 ug/mL
Ethyl ether 5 ug/mL
Ethyl methacrylate 5 ug/mL
Ethylbenzene 5 ug/mL
Ethylene Dibromide 5 ug/mL
Hexachlorobutadiene 5 ug/mL
Hexane 5 ug/mL
Iodomethane 5 ug/mL
Isobutyl alcohol 125 ug/mL
Isopropylbenzene 5 ug/mL
m-Xylene & p-Xylene 5 ug/mL
Methyl acetate 10 ug/mL
Methyl tert-butyl ether 5 ug/mL
Methylcyclohexane 5 ug/mL
Methylene Chloride 5 ug/mL
n-Butylbenzene 5 ug/mL
n-Heptane 5 ug/mL
N-Propylbenzene 5 ug/mL
Naphthalene 5 ug/mL
o-Xylene 5 ug/mL
sec-Butylbenzene 5 ug/mL
Styrene 5 ug/mL
tert-Butylbenzene 5 ug/mL
Tetrachloroethene 5 ug/mL
Tetrahydrofuran 10 ug/mL
Toluene 5 ug/mL
trans-1,2-Dichloroethene 5 ug/mL
trans-1,3-Dichloropropene 5 ug/mL
trans-1,4-Dichloro-2-butene 5 ug/mL
Trichloroethene 5 ug/mL
1-Chlorohexane 4 ug/mL
2-Pentanone 16 ug/mL
sec-Butyl Alcohol 120 ug/mL
MV-569722_00024 Bromomethane 250 ug/mL12.5 mL 1250 uL11/25/24 10/24/24.MV-Gas A_00201 P&T Methanol, Lot 198123
Chloroethane 250 ug/mL
Chloromethane 250 ug/mL
11/15/2024
3:53:55 PM
Page 51 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Dichlorodifluoromethane 250 ug/mL
Dichlorofluoromethane 250 ug/mL
Trichlorofluoromethane 250 ug/mL
Vinyl chloride 250 ug/mL
MV-569723_00019 1250 uL 2-Chloroethyl vinyl ether 250 ug/mL
05/28/27 (Purchased Reagent)Bromomethane 2500 ug/mLRESTEK, Lot A0211969..MV-569722_00024
Chloroethane 2500 ug/mL
Chloromethane 2500 ug/mL
Dichlorodifluoromethane 2500 ug/mL
Dichlorofluoromethane 2500 ug/mL
Trichlorofluoromethane 2500 ug/mL
Vinyl chloride 2500 ug/mL
06/30/27 (Purchased Reagent)2-Chloroethyl vinyl ether 2500 ug/mLRESTEK, Lot A0213181..MV-569723_00019
MV-568720_00049 Acrolein 987.5 ug/mL25 mL 1250 uL11/28/24 10/28/24.MV-MegaMainA_00118 P&T Methanol, Lot EG636-US
2-Butanone (MEK)400 ug/mLMV-569721_00016 800 uL
2-Hexanone 400 ug/mL
4-Methyl-2-pentanone (MIBK)400 ug/mL
Acetone 400 ug/mL
Vinyl acetate 200 ug/mLMV-569724_00038 1000 uL
Cyclohexanone 3000 ug/mLMV-569727_00025 3000 uL
1,1,1,2-Tetrachloroethane 100 ug/mLMV-571992_00017 1000 uL
1,1,1-Trichloroethane 100 ug/mL
1,1,2,2-Tetrachloroethane 100 ug/mL
1,1,2-Trichloro-1,2,2-trifluoroethane 100 ug/mL
1,1,2-Trichloroethane 100 ug/mL
1,1-Dichloroethane 100 ug/mL
1,1-Dichloroethene 100 ug/mL
1,1-Dichloropropene 100 ug/mL
1,2,3-Trichlorobenzene 100 ug/mL
1,2,3-Trichloropropane 100 ug/mL
1,2,4-Trichlorobenzene 100 ug/mL
1,2,4-Trimethylbenzene 100 ug/mL
1,2-Dibromo-3-Chloropropane 100 ug/mL
1,2-Dichlorobenzene 100 ug/mL
1,2-Dichloroethane 100 ug/mL
1,2-Dichloropropane 100 ug/mL
1,3,5-Trimethylbenzene 100 ug/mL
1,3-Dichlorobenzene 100 ug/mL
1,3-Dichloropropane 100 ug/mL
1,4-Dichlorobenzene 100 ug/mL
1,4-Dioxane 2000 ug/mL
2,2-Dichloropropane 100 ug/mL
2-Chlorotoluene 100 ug/mL
2-Methyl-2-propanol 1000 ug/mL
3-Chloro-1-propene 100 ug/mL
4-Chlorotoluene 100 ug/mL
11/15/2024
3:53:55 PM
Page 52 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
4-Isopropyltoluene 100 ug/mL
Acrylonitrile 1000 ug/mL
Benzene 100 ug/mL
Bromobenzene 100 ug/mL
Bromoform 100 ug/mL
Carbon disulfide 100 ug/mL
Carbon tetrachloride 100 ug/mL
Chlorobenzene 100 ug/mL
Chlorobromomethane 100 ug/mL
Chlorodibromomethane 100 ug/mL
Chloroform 100 ug/mL
cis-1,2-Dichloroethene 100 ug/mL
cis-1,3-Dichloropropene 100 ug/mL
Cyclohexane 100 ug/mL
Dibromomethane 100 ug/mL
Dichlorobromomethane 100 ug/mL
Ethyl ether 100 ug/mL
Ethyl methacrylate 100 ug/mL
Ethylbenzene 100 ug/mL
Ethylene Dibromide 100 ug/mL
Hexachlorobutadiene 100 ug/mL
Hexane 100 ug/mL
Iodomethane 100 ug/mL
Isobutyl alcohol 2500 ug/mL
Isopropylbenzene 100 ug/mL
m-Xylene & p-Xylene 100 ug/mL
Methyl acetate 200 ug/mL
Methyl tert-butyl ether 100 ug/mL
Methylcyclohexane 100 ug/mL
Methylene Chloride 100 ug/mL
n-Butylbenzene 100 ug/mL
n-Heptane 100 ug/mL
N-Propylbenzene 100 ug/mL
Naphthalene 100 ug/mL
o-Xylene 100 ug/mL
sec-Butylbenzene 100 ug/mL
Styrene 100 ug/mL
tert-Butylbenzene 100 ug/mL
Tetrachloroethene 100 ug/mL
Tetrahydrofuran 200 ug/mL
Toluene 100 ug/mL
trans-1,2-Dichloroethene 100 ug/mL
trans-1,3-Dichloropropene 100 ug/mL
trans-1,4-Dichloro-2-butene 100 ug/mL
Trichloroethene 100 ug/mL
1-Chlorohexane 80 ug/mLMV-CUS17739_00017 2000 uL
2-Pentanone 320 ug/mL
11/15/2024
3:53:55 PM
Page 53 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
sec-Butyl Alcohol 2400 ug/mL
09/30/25 (Purchased Reagent)Acrolein 19750 ug/mLRESTEK, Lot A0209476..MV-568720_00049
04/30/27 (Purchased Reagent)2-Butanone (MEK)12500 ug/mLRESTEK, Lot A0210935..MV-569721_00016
2-Hexanone 12500 ug/mL
4-Methyl-2-pentanone (MIBK)12500 ug/mL
Acetone 12500 ug/mL
09/30/25 (Purchased Reagent)Vinyl acetate 5000 ug/mLRESTEK, Lot A0209567..MV-569724_00038
03/31/27 (Purchased Reagent)Cyclohexanone 25000 ug/mLRESTEK, Lot A0209630..MV-569727_00025
04/30/26 (Purchased Reagent)1,1,1,2-Tetrachloroethane 2500 ug/mLRESTEK, Lot A0203458..MV-571992_00017
1,1,1-Trichloroethane 2500 ug/mL
1,1,2,2-Tetrachloroethane 2500 ug/mL
1,1,2-Trichloro-1,2,2-trifluoroethane 2500 ug/mL
1,1,2-Trichloroethane 2500 ug/mL
1,1-Dichloroethane 2500 ug/mL
1,1-Dichloroethene 2500 ug/mL
1,1-Dichloropropene 2500 ug/mL
1,2,3-Trichlorobenzene 2500 ug/mL
1,2,3-Trichloropropane 2500 ug/mL
1,2,4-Trichlorobenzene 2500 ug/mL
1,2,4-Trimethylbenzene 2500 ug/mL
1,2-Dibromo-3-Chloropropane 2500 ug/mL
1,2-Dichlorobenzene 2500 ug/mL
1,2-Dichloroethane 2500 ug/mL
1,2-Dichloropropane 2500 ug/mL
1,3,5-Trimethylbenzene 2500 ug/mL
1,3-Dichlorobenzene 2500 ug/mL
1,3-Dichloropropane 2500 ug/mL
1,4-Dichlorobenzene 2500 ug/mL
1,4-Dioxane 50000 ug/mL
2,2-Dichloropropane 2500 ug/mL
2-Chlorotoluene 2500 ug/mL
2-Methyl-2-propanol 25000 ug/mL
3-Chloro-1-propene 2500 ug/mL
4-Chlorotoluene 2500 ug/mL
4-Isopropyltoluene 2500 ug/mL
Acrylonitrile 25000 ug/mL
Benzene 2500 ug/mL
Bromobenzene 2500 ug/mL
Bromoform 2500 ug/mL
Carbon disulfide 2500 ug/mL
Carbon tetrachloride 2500 ug/mL
Chlorobenzene 2500 ug/mL
Chlorobromomethane 2500 ug/mL
Chlorodibromomethane 2500 ug/mL
Chloroform 2500 ug/mL
cis-1,2-Dichloroethene 2500 ug/mL
cis-1,3-Dichloropropene 2500 ug/mL
11/15/2024
3:53:55 PM
Page 54 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Cyclohexane 2500 ug/mL
Dibromomethane 2500 ug/mL
Dichlorobromomethane 2500 ug/mL
Ethyl ether 2500 ug/mL
Ethyl methacrylate 2500 ug/mL
Ethylbenzene 2500 ug/mL
Ethylene Dibromide 2500 ug/mL
Hexachlorobutadiene 2500 ug/mL
Hexane 2500 ug/mL
Iodomethane 2500 ug/mL
Isobutyl alcohol 62500 ug/mL
Isopropylbenzene 2500 ug/mL
m-Xylene & p-Xylene 2500 ug/mL
Methyl acetate 5000 ug/mL
Methyl tert-butyl ether 2500 ug/mL
Methylcyclohexane 2500 ug/mL
Methylene Chloride 2500 ug/mL
n-Butylbenzene 2500 ug/mL
n-Heptane 2500 ug/mL
N-Propylbenzene 2500 ug/mL
Naphthalene 2500 ug/mL
o-Xylene 2500 ug/mL
sec-Butylbenzene 2500 ug/mL
Styrene 2500 ug/mL
tert-Butylbenzene 2500 ug/mL
Tetrachloroethene 2500 ug/mL
Tetrahydrofuran 5000 ug/mL
Toluene 2500 ug/mL
trans-1,2-Dichloroethene 2500 ug/mL
trans-1,3-Dichloropropene 2500 ug/mL
trans-1,4-Dichloro-2-butene 2500 ug/mL
Trichloroethene 2500 ug/mL
08/31/26 (Purchased Reagent)1-Chlorohexane 1000 ug/mLAgilent, Lot 6808538..MV-CUS17739_00017
2-Pentanone 4000 ug/mL
sec-Butyl Alcohol 30000 ug/mL
MV-Gas A_00201 Bromomethane 5 ug/mL100 uL 2 uL11/19/24 10/29/24Cal Dil Std_00426 P&T Methanol, Lot EG359-US
Chloroethane 5 ug/mL
Chloromethane 5 ug/mL
Dichlorodifluoromethane 5 ug/mL
Dichlorofluoromethane 5 ug/mL
Trichlorofluoromethane 5 ug/mL
Vinyl chloride 5 ug/mL
2-Chloroethyl vinyl ether 5 ug/mL
Acrolein 49.375 ug/mLMV-MegaMainA_00118 5 uL
2-Butanone (MEK)20 ug/mL
2-Hexanone 20 ug/mL
11/15/2024
3:53:55 PM
Page 55 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
4-Methyl-2-pentanone (MIBK)20 ug/mL
Acetone 20 ug/mL
Vinyl acetate 10 ug/mL
Cyclohexanone 150 ug/mL
1,1,1,2-Tetrachloroethane 5 ug/mL
1,1,1-Trichloroethane 5 ug/mL
1,1,2,2-Tetrachloroethane 5 ug/mL
1,1,2-Trichloro-1,2,2-trifluoroethane 5 ug/mL
1,1,2-Trichloroethane 5 ug/mL
1,1-Dichloroethane 5 ug/mL
1,1-Dichloroethene 5 ug/mL
1,1-Dichloropropene 5 ug/mL
1,2,3-Trichlorobenzene 5 ug/mL
1,2,3-Trichloropropane 5 ug/mL
1,2,4-Trichlorobenzene 5 ug/mL
1,2,4-Trimethylbenzene 5 ug/mL
1,2-Dibromo-3-Chloropropane 5 ug/mL
1,2-Dichlorobenzene 5 ug/mL
1,2-Dichloroethane 5 ug/mL
1,2-Dichloropropane 5 ug/mL
1,3,5-Trimethylbenzene 5 ug/mL
1,3-Dichlorobenzene 5 ug/mL
1,3-Dichloropropane 5 ug/mL
1,4-Dichlorobenzene 5 ug/mL
1,4-Dioxane 100 ug/mL
2,2-Dichloropropane 5 ug/mL
2-Chlorotoluene 5 ug/mL
2-Methyl-2-propanol 50 ug/mL
3-Chloro-1-propene 5 ug/mL
4-Chlorotoluene 5 ug/mL
4-Isopropyltoluene 5 ug/mL
Acrylonitrile 50 ug/mL
Benzene 5 ug/mL
Bromobenzene 5 ug/mL
Bromoform 5 ug/mL
Carbon disulfide 5 ug/mL
Carbon tetrachloride 5 ug/mL
Chlorobenzene 5 ug/mL
Chlorobromomethane 5 ug/mL
Chlorodibromomethane 5 ug/mL
Chloroform 5 ug/mL
cis-1,2-Dichloroethene 5 ug/mL
cis-1,3-Dichloropropene 5 ug/mL
Cyclohexane 5 ug/mL
Dibromomethane 5 ug/mL
Dichlorobromomethane 5 ug/mL
Ethyl ether 5 ug/mL
11/15/2024
3:53:55 PM
Page 56 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Ethyl methacrylate 5 ug/mL
Ethylbenzene 5 ug/mL
Ethylene Dibromide 5 ug/mL
Hexachlorobutadiene 5 ug/mL
Hexane 5 ug/mL
Iodomethane 5 ug/mL
Isobutyl alcohol 125 ug/mL
Isopropylbenzene 5 ug/mL
m-Xylene & p-Xylene 5 ug/mL
Methyl acetate 10 ug/mL
Methyl tert-butyl ether 5 ug/mL
Methylcyclohexane 5 ug/mL
Methylene Chloride 5 ug/mL
n-Butylbenzene 5 ug/mL
n-Heptane 5 ug/mL
N-Propylbenzene 5 ug/mL
Naphthalene 5 ug/mL
o-Xylene 5 ug/mL
sec-Butylbenzene 5 ug/mL
Styrene 5 ug/mL
tert-Butylbenzene 5 ug/mL
Tetrachloroethene 5 ug/mL
Tetrahydrofuran 10 ug/mL
Toluene 5 ug/mL
trans-1,2-Dichloroethene 5 ug/mL
trans-1,3-Dichloropropene 5 ug/mL
trans-1,4-Dichloro-2-butene 5 ug/mL
Trichloroethene 5 ug/mL
1-Chlorohexane 4 ug/mL
2-Pentanone 16 ug/mL
sec-Butyl Alcohol 120 ug/mL
MV-569722_00024 Bromomethane 250 ug/mL12.5 mL 1250 uL11/25/24 10/24/24.MV-Gas A_00201 P&T Methanol, Lot 198123
Chloroethane 250 ug/mL
Chloromethane 250 ug/mL
Dichlorodifluoromethane 250 ug/mL
Dichlorofluoromethane 250 ug/mL
Trichlorofluoromethane 250 ug/mL
Vinyl chloride 250 ug/mL
MV-569723_00019 1250 uL 2-Chloroethyl vinyl ether 250 ug/mL
05/28/27 (Purchased Reagent)Bromomethane 2500 ug/mLRESTEK, Lot A0211969..MV-569722_00024
Chloroethane 2500 ug/mL
Chloromethane 2500 ug/mL
Dichlorodifluoromethane 2500 ug/mL
Dichlorofluoromethane 2500 ug/mL
Trichlorofluoromethane 2500 ug/mL
Vinyl chloride 2500 ug/mL
06/30/27 (Purchased Reagent)2-Chloroethyl vinyl ether 2500 ug/mLRESTEK, Lot A0213181..MV-569723_00019
11/15/2024
3:53:55 PM
Page 57 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
MV-568720_00049 Acrolein 987.5 ug/mL25 mL 1250 uL11/28/24 10/28/24.MV-MegaMainA_00118 P&T Methanol, Lot EG636-US
2-Butanone (MEK)400 ug/mLMV-569721_00016 800 uL
2-Hexanone 400 ug/mL
4-Methyl-2-pentanone (MIBK)400 ug/mL
Acetone 400 ug/mL
Vinyl acetate 200 ug/mLMV-569724_00038 1000 uL
Cyclohexanone 3000 ug/mLMV-569727_00025 3000 uL
1,1,1,2-Tetrachloroethane 100 ug/mLMV-571992_00017 1000 uL
1,1,1-Trichloroethane 100 ug/mL
1,1,2,2-Tetrachloroethane 100 ug/mL
1,1,2-Trichloro-1,2,2-trifluoroethane 100 ug/mL
1,1,2-Trichloroethane 100 ug/mL
1,1-Dichloroethane 100 ug/mL
1,1-Dichloroethene 100 ug/mL
1,1-Dichloropropene 100 ug/mL
1,2,3-Trichlorobenzene 100 ug/mL
1,2,3-Trichloropropane 100 ug/mL
1,2,4-Trichlorobenzene 100 ug/mL
1,2,4-Trimethylbenzene 100 ug/mL
1,2-Dibromo-3-Chloropropane 100 ug/mL
1,2-Dichlorobenzene 100 ug/mL
1,2-Dichloroethane 100 ug/mL
1,2-Dichloropropane 100 ug/mL
1,3,5-Trimethylbenzene 100 ug/mL
1,3-Dichlorobenzene 100 ug/mL
1,3-Dichloropropane 100 ug/mL
1,4-Dichlorobenzene 100 ug/mL
1,4-Dioxane 2000 ug/mL
2,2-Dichloropropane 100 ug/mL
2-Chlorotoluene 100 ug/mL
2-Methyl-2-propanol 1000 ug/mL
3-Chloro-1-propene 100 ug/mL
4-Chlorotoluene 100 ug/mL
4-Isopropyltoluene 100 ug/mL
Acrylonitrile 1000 ug/mL
Benzene 100 ug/mL
Bromobenzene 100 ug/mL
Bromoform 100 ug/mL
Carbon disulfide 100 ug/mL
Carbon tetrachloride 100 ug/mL
Chlorobenzene 100 ug/mL
Chlorobromomethane 100 ug/mL
Chlorodibromomethane 100 ug/mL
Chloroform 100 ug/mL
cis-1,2-Dichloroethene 100 ug/mL
cis-1,3-Dichloropropene 100 ug/mL
11/15/2024
3:53:55 PM
Page 58 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Cyclohexane 100 ug/mL
Dibromomethane 100 ug/mL
Dichlorobromomethane 100 ug/mL
Ethyl ether 100 ug/mL
Ethyl methacrylate 100 ug/mL
Ethylbenzene 100 ug/mL
Ethylene Dibromide 100 ug/mL
Hexachlorobutadiene 100 ug/mL
Hexane 100 ug/mL
Iodomethane 100 ug/mL
Isobutyl alcohol 2500 ug/mL
Isopropylbenzene 100 ug/mL
m-Xylene & p-Xylene 100 ug/mL
Methyl acetate 200 ug/mL
Methyl tert-butyl ether 100 ug/mL
Methylcyclohexane 100 ug/mL
Methylene Chloride 100 ug/mL
n-Butylbenzene 100 ug/mL
n-Heptane 100 ug/mL
N-Propylbenzene 100 ug/mL
Naphthalene 100 ug/mL
o-Xylene 100 ug/mL
sec-Butylbenzene 100 ug/mL
Styrene 100 ug/mL
tert-Butylbenzene 100 ug/mL
Tetrachloroethene 100 ug/mL
Tetrahydrofuran 200 ug/mL
Toluene 100 ug/mL
trans-1,2-Dichloroethene 100 ug/mL
trans-1,3-Dichloropropene 100 ug/mL
trans-1,4-Dichloro-2-butene 100 ug/mL
Trichloroethene 100 ug/mL
1-Chlorohexane 80 ug/mLMV-CUS17739_00017 2000 uL
2-Pentanone 320 ug/mL
sec-Butyl Alcohol 2400 ug/mL
09/30/25 (Purchased Reagent)Acrolein 19750 ug/mLRESTEK, Lot A0209476..MV-568720_00049
04/30/27 (Purchased Reagent)2-Butanone (MEK)12500 ug/mLRESTEK, Lot A0210935..MV-569721_00016
2-Hexanone 12500 ug/mL
4-Methyl-2-pentanone (MIBK)12500 ug/mL
Acetone 12500 ug/mL
09/30/25 (Purchased Reagent)Vinyl acetate 5000 ug/mLRESTEK, Lot A0209567..MV-569724_00038
03/31/27 (Purchased Reagent)Cyclohexanone 25000 ug/mLRESTEK, Lot A0209630..MV-569727_00025
04/30/26 (Purchased Reagent)1,1,1,2-Tetrachloroethane 2500 ug/mLRESTEK, Lot A0203458..MV-571992_00017
1,1,1-Trichloroethane 2500 ug/mL
1,1,2,2-Tetrachloroethane 2500 ug/mL
1,1,2-Trichloro-1,2,2-trifluoroethane 2500 ug/mL
1,1,2-Trichloroethane 2500 ug/mL
11/15/2024
3:53:55 PM
Page 59 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
1,1-Dichloroethane 2500 ug/mL
1,1-Dichloroethene 2500 ug/mL
1,1-Dichloropropene 2500 ug/mL
1,2,3-Trichlorobenzene 2500 ug/mL
1,2,3-Trichloropropane 2500 ug/mL
1,2,4-Trichlorobenzene 2500 ug/mL
1,2,4-Trimethylbenzene 2500 ug/mL
1,2-Dibromo-3-Chloropropane 2500 ug/mL
1,2-Dichlorobenzene 2500 ug/mL
1,2-Dichloroethane 2500 ug/mL
1,2-Dichloropropane 2500 ug/mL
1,3,5-Trimethylbenzene 2500 ug/mL
1,3-Dichlorobenzene 2500 ug/mL
1,3-Dichloropropane 2500 ug/mL
1,4-Dichlorobenzene 2500 ug/mL
1,4-Dioxane 50000 ug/mL
2,2-Dichloropropane 2500 ug/mL
2-Chlorotoluene 2500 ug/mL
2-Methyl-2-propanol 25000 ug/mL
3-Chloro-1-propene 2500 ug/mL
4-Chlorotoluene 2500 ug/mL
4-Isopropyltoluene 2500 ug/mL
Acrylonitrile 25000 ug/mL
Benzene 2500 ug/mL
Bromobenzene 2500 ug/mL
Bromoform 2500 ug/mL
Carbon disulfide 2500 ug/mL
Carbon tetrachloride 2500 ug/mL
Chlorobenzene 2500 ug/mL
Chlorobromomethane 2500 ug/mL
Chlorodibromomethane 2500 ug/mL
Chloroform 2500 ug/mL
cis-1,2-Dichloroethene 2500 ug/mL
cis-1,3-Dichloropropene 2500 ug/mL
Cyclohexane 2500 ug/mL
Dibromomethane 2500 ug/mL
Dichlorobromomethane 2500 ug/mL
Ethyl ether 2500 ug/mL
Ethyl methacrylate 2500 ug/mL
Ethylbenzene 2500 ug/mL
Ethylene Dibromide 2500 ug/mL
Hexachlorobutadiene 2500 ug/mL
Hexane 2500 ug/mL
Iodomethane 2500 ug/mL
Isobutyl alcohol 62500 ug/mL
Isopropylbenzene 2500 ug/mL
m-Xylene & p-Xylene 2500 ug/mL
11/15/2024
3:53:55 PM
Page 60 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Methyl acetate 5000 ug/mL
Methyl tert-butyl ether 2500 ug/mL
Methylcyclohexane 2500 ug/mL
Methylene Chloride 2500 ug/mL
n-Butylbenzene 2500 ug/mL
n-Heptane 2500 ug/mL
N-Propylbenzene 2500 ug/mL
Naphthalene 2500 ug/mL
o-Xylene 2500 ug/mL
sec-Butylbenzene 2500 ug/mL
Styrene 2500 ug/mL
tert-Butylbenzene 2500 ug/mL
Tetrachloroethene 2500 ug/mL
Tetrahydrofuran 5000 ug/mL
Toluene 2500 ug/mL
trans-1,2-Dichloroethene 2500 ug/mL
trans-1,3-Dichloropropene 2500 ug/mL
trans-1,4-Dichloro-2-butene 2500 ug/mL
Trichloroethene 2500 ug/mL
08/31/26 (Purchased Reagent)1-Chlorohexane 1000 ug/mLAgilent, Lot 6808538..MV-CUS17739_00017
2-Pentanone 4000 ug/mL
sec-Butyl Alcohol 30000 ug/mL
1,2-Dichloroethene, Totalmv-Cent BFB_00008
1,3-Dichloropropene, Total
Tentatively Identified
Compound
Total BTEX
Trihalomethanes, Total
Xylenes, Total
mv-IS/SS Tune_00002 10 mL BFB 50 ug/mL
05/31/26 (Purchased Reagent)BFB 250 ug/mLRestek, Lot 20401KO/A0172587.mv-IS/SS Tune_00002
MV-569722.sec_00019 Bromomethane 250 ug/mL12.5 mL 1250 uL11/12/24 10/12/24MV-Gas A_00200 P&T Methanol, Lot
198123
Chloroethane 250 ug/mL
Chloromethane 250 ug/mL
Dichlorodifluoromethane 250 ug/mL
Dichlorofluoromethane 250 ug/mL
Trichlorofluoromethane 250 ug/mL
Vinyl chloride 250 ug/mL
MV-569723_00019 1250 uL 2-Chloroethyl vinyl ether 250 ug/mL
04/30/27 (Purchased Reagent)Bromomethane 2500 ug/mLRESTEK, Lot A0210106.MV-569722.sec_00019
Chloroethane 2500 ug/mL
Chloromethane 2500 ug/mL
Dichlorodifluoromethane 2500 ug/mL
Dichlorofluoromethane 2500 ug/mL
Trichlorofluoromethane 2500 ug/mL
Vinyl chloride 2500 ug/mL
11/15/2024
3:53:55 PM
Page 61 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
06/30/27 (Purchased Reagent)2-Chloroethyl vinyl ether 2500 ug/mLRESTEK, Lot A0213181.MV-569723_00019
MV-569722_00024 Bromomethane 250 ug/mL12.5 mL 1250 uL11/25/24 10/24/24MV-Gas A_00201 P&T Methanol, Lot 198123
Chloroethane 250 ug/mL
Chloromethane 250 ug/mL
Dichlorodifluoromethane 250 ug/mL
Dichlorofluoromethane 250 ug/mL
Trichlorofluoromethane 250 ug/mL
Vinyl chloride 250 ug/mL
MV-569723_00019 1250 uL 2-Chloroethyl vinyl ether 250 ug/mL
05/28/27 (Purchased Reagent)Bromomethane 2500 ug/mLRESTEK, Lot A0211969.MV-569722_00024
Chloroethane 2500 ug/mL
Chloromethane 2500 ug/mL
Dichlorodifluoromethane 2500 ug/mL
Dichlorofluoromethane 2500 ug/mL
Trichlorofluoromethane 2500 ug/mL
Vinyl chloride 2500 ug/mL
06/30/27 (Purchased Reagent)2-Chloroethyl vinyl ether 2500 ug/mLRESTEK, Lot A0213181.MV-569723_00019
MV-569722_00024 Bromomethane 250 ug/mL12.5 mL 1250 uL12/06/24 11/06/24MV-Gas A_00202 P&T Methanol, Lot 198123
Chloroethane 250 ug/mL
Chloromethane 250 ug/mL
Dichlorodifluoromethane 250 ug/mL
Trichlorofluoromethane 250 ug/mL
Vinyl chloride 250 ug/mL
05/28/27 (Purchased Reagent)Bromomethane 2500 ug/mLRESTEK, Lot A0211969.MV-569722_00024
Chloroethane 2500 ug/mL
Chloromethane 2500 ug/mL
Dichlorodifluoromethane 2500 ug/mL
Trichlorofluoromethane 2500 ug/mL
Vinyl chloride 2500 ug/mL
MV-569722.sec_00020 Bromomethane 250 ug/mL12.5 mL 1250 uL11/28/24 10/28/24MV-Gas B_00174 P&T Methanol, Lot EG636-US
Chloroethane 250 ug/mL
Chloromethane 250 ug/mL
Dichlorodifluoromethane 250 ug/mL
Trichlorofluoromethane 250 ug/mL
Vinyl chloride 250 ug/mL
05/31/27 (Purchased Reagent)Bromomethane 2500 ug/mLRESTEK, Lot A0211505.MV-569722.sec_00020
Chloroethane 2500 ug/mL
Chloromethane 2500 ug/mL
Dichlorodifluoromethane 2500 ug/mL
Trichlorofluoromethane 2500 ug/mL
Vinyl chloride 2500 ug/mL
mv-30241_00014 1,4-Dichlorobenzene-d4 50 ug/mL50 mL 1000 uL03/01/25 08/15/24mv-IS_SS_00086 P&T Methanol, Lot EG636-US
Chlorobenzene-d5 50 ug/mL
11/15/2024
3:53:55 PM
Page 62 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Fluorobenzene 50 ug/mL
1,2-Dichloroethane-d4 (Surr)50 ug/mLMV-567650_00030 1000 uL
4-Bromofluorobenzene (Surr)50 ug/mL
Dibromofluoromethane (Surr)50 ug/mL
Toluene-d8 (Surr)50 ug/mL
05/31/28 (Purchased Reagent)1,4-Dichlorobenzene-d4 2500 ug/mLRestek, Lot A0198297.mv-30241_00014
Chlorobenzene-d5 2500 ug/mL
Fluorobenzene 2500 ug/mL
05/31/26 (Purchased Reagent)1,2-Dichloroethane-d4 (Surr)2500 ug/mLRestek, Lot A0172587.MV-567650_00030
4-Bromofluorobenzene (Surr)2500 ug/mL
Dibromofluoromethane (Surr)2500 ug/mL
Toluene-d8 (Surr)2500 ug/mL
mv-30241_00014 1,4-Dichlorobenzene-d4 50 ug/mL50 mL 1000 uL03/01/25 09/23/24mv-IS_SS_00089 P&T Methanol, Lot EG636-US
Chlorobenzene-d5 50 ug/mL
Fluorobenzene 50 ug/mL
1,2-Dichloroethane-d4 (Surr)50 ug/mLMV-567650_00033 1000 uL
4-Bromofluorobenzene (Surr)50 ug/mL
Dibromofluoromethane (Surr)50 ug/mL
Toluene-d8 (Surr)50 ug/mL
05/31/28 (Purchased Reagent)1,4-Dichlorobenzene-d4 2500 ug/mLRestek, Lot A0198297.mv-30241_00014
Chlorobenzene-d5 2500 ug/mL
Fluorobenzene 2500 ug/mL
05/31/29 (Purchased Reagent)1,2-Dichloroethane-d4 (Surr)2500 ug/mLRestek, Lot A0211048.MV-567650_00033
4-Bromofluorobenzene (Surr)2500 ug/mL
Dibromofluoromethane (Surr)2500 ug/mL
Toluene-d8 (Surr)2500 ug/mL
MV-569721.sec_00013 2-Butanone (MEK)400 ug/mL25 mL 800 uL11/29/24 10/29/24MV-MegaMain B_00111 P&T Methanol, Lot EG-636-US
2-Hexanone 400 ug/mL
4-Methyl-2-pentanone (MIBK)400 ug/mL
Acetone 400 ug/mL
Vinyl acetate 200 ug/mLMV-569724.sec_00038 1000 uL
1,1,1,2-Tetrachloroethane 100 ug/mLMV-571992.sec_00010 1000 uL
1,1,1-Trichloroethane 100 ug/mL
1,1,2,2-Tetrachloroethane 100 ug/mL
1,1,2-Trichloro-1,2,2-trifluoroethane 100 ug/mL
1,1,2-Trichloroethane 100 ug/mL
1,1-Dichloroethane 100 ug/mL
1,1-Dichloroethene 100 ug/mL
1,1-Dichloropropene 100 ug/mL
1,2,3-Trichlorobenzene 100 ug/mL
1,2,3-Trichloropropane 100 ug/mL
1,2,4-Trichlorobenzene 100 ug/mL
1,2,4-Trimethylbenzene 100 ug/mL
1,2-Dibromo-3-Chloropropane 100 ug/mL
11/15/2024
3:53:55 PM
Page 63 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
1,2-Dichlorobenzene 100 ug/mL
1,2-Dichloroethane 100 ug/mL
1,2-Dichloroethene, Total 200 ug/mL
1,2-Dichloropropane 100 ug/mL
1,3,5-Trimethylbenzene 100 ug/mL
1,3-Dichlorobenzene 100 ug/mL
1,3-Dichloropropane 100 ug/mL
1,3-Dichloropropene, Total 200 ug/mL
1,4-Dichlorobenzene 100 ug/mL
2,2-Dichloropropane 100 ug/mL
2-Chlorotoluene 100 ug/mL
3-Chloro-1-propene 100 ug/mL
4-Chlorotoluene 100 ug/mL
4-Isopropyltoluene 100 ug/mL
Benzene 100 ug/mL
Bromobenzene 100 ug/mL
Bromoform 100 ug/mL
Carbon disulfide 100 ug/mL
Carbon tetrachloride 100 ug/mL
Chlorobenzene 100 ug/mL
Chlorobromomethane 100 ug/mL
Chlorodibromomethane 100 ug/mL
Chloroform 100 ug/mL
cis-1,2-Dichloroethene 100 ug/mL
cis-1,3-Dichloropropene 100 ug/mL
Cyclohexane 100 ug/mL
Dibromomethane 100 ug/mL
Dichlorobromomethane 100 ug/mL
Ethyl ether 100 ug/mL
Ethyl methacrylate 100 ug/mL
Ethylbenzene 100 ug/mL
Ethylene Dibromide 100 ug/mL
Hexachlorobutadiene 100 ug/mL
Hexane 100 ug/mL
Iodomethane 100 ug/mL
Isopropylbenzene 100 ug/mL
m-Xylene & p-Xylene 100 ug/mL
Methyl acetate 200 ug/mL
Methyl tert-butyl ether 100 ug/mL
Methylcyclohexane 100 ug/mL
Methylene Chloride 100 ug/mL
n-Butylbenzene 100 ug/mL
N-Propylbenzene 100 ug/mL
Naphthalene 100 ug/mL
o-Xylene 100 ug/mL
sec-Butylbenzene 100 ug/mL
Styrene 100 ug/mL
11/15/2024
3:53:55 PM
Page 64 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
tert-Butylbenzene 100 ug/mL
Tetrachloroethene 100 ug/mL
Tetrahydrofuran 200 ug/mL
Toluene 100 ug/mL
trans-1,2-Dichloroethene 100 ug/mL
trans-1,3-Dichloropropene 100 ug/mL
Trichloroethene 100 ug/mL
Trihalomethanes, Total 400 ug/mL
Xylenes, Total 200 ug/mL
04/30/27 (Purchased Reagent)2-Butanone (MEK)12500 ug/mLRESTEK, Lot A0209876.MV-569721.sec_00013
2-Hexanone 12500 ug/mL
4-Methyl-2-pentanone (MIBK)12500 ug/mL
Acetone 12500 ug/mL
10/31/25 (Purchased Reagent)Vinyl acetate 5000 ug/mLRESTEK, Lot A0210661.MV-569724.sec_00038
08/31/25 (Purchased Reagent)1,1,1,2-Tetrachloroethane 2500 ug/mLRESTEK, Lot A0195252.MV-571992.sec_00010
1,1,1-Trichloroethane 2500 ug/mL
1,1,2,2-Tetrachloroethane 2500 ug/mL
1,1,2-Trichloro-1,2,2-trifluoroethane 2500 ug/mL
1,1,2-Trichloroethane 2500 ug/mL
1,1-Dichloroethane 2500 ug/mL
1,1-Dichloroethene 2500 ug/mL
1,1-Dichloropropene 2500 ug/mL
1,2,3-Trichlorobenzene 2500 ug/mL
1,2,3-Trichloropropane 2500 ug/mL
1,2,4-Trichlorobenzene 2500 ug/mL
1,2,4-Trimethylbenzene 2500 ug/mL
1,2-Dibromo-3-Chloropropane 2500 ug/mL
1,2-Dichlorobenzene 2500 ug/mL
1,2-Dichloroethane 2500 ug/mL
1,2-Dichloroethene, Total 5000 ug/mL
1,2-Dichloropropane 2500 ug/mL
1,3,5-Trimethylbenzene 2500 ug/mL
1,3-Dichlorobenzene 2500 ug/mL
1,3-Dichloropropane 2500 ug/mL
1,3-Dichloropropene, Total 5000 ug/mL
1,4-Dichlorobenzene 2500 ug/mL
2,2-Dichloropropane 2500 ug/mL
2-Chlorotoluene 2500 ug/mL
3-Chloro-1-propene 2500 ug/mL
4-Chlorotoluene 2500 ug/mL
4-Isopropyltoluene 2500 ug/mL
Benzene 2500 ug/mL
Bromobenzene 2500 ug/mL
Bromoform 2500 ug/mL
Carbon disulfide 2500 ug/mL
Carbon tetrachloride 2500 ug/mL
Chlorobenzene 2500 ug/mL
11/15/2024
3:53:55 PM
Page 65 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Chlorobromomethane 2500 ug/mL
Chlorodibromomethane 2500 ug/mL
Chloroform 2500 ug/mL
cis-1,2-Dichloroethene 2500 ug/mL
cis-1,3-Dichloropropene 2500 ug/mL
Cyclohexane 2500 ug/mL
Dibromomethane 2500 ug/mL
Dichlorobromomethane 2500 ug/mL
Ethyl ether 2500 ug/mL
Ethyl methacrylate 2500 ug/mL
Ethylbenzene 2500 ug/mL
Ethylene Dibromide 2500 ug/mL
Hexachlorobutadiene 2500 ug/mL
Hexane 2500 ug/mL
Iodomethane 2500 ug/mL
Isopropylbenzene 2500 ug/mL
m-Xylene & p-Xylene 2500 ug/mL
Methyl acetate 5000 ug/mL
Methyl tert-butyl ether 2500 ug/mL
Methylcyclohexane 2500 ug/mL
Methylene Chloride 2500 ug/mL
n-Butylbenzene 2500 ug/mL
N-Propylbenzene 2500 ug/mL
Naphthalene 2500 ug/mL
o-Xylene 2500 ug/mL
sec-Butylbenzene 2500 ug/mL
Styrene 2500 ug/mL
tert-Butylbenzene 2500 ug/mL
Tetrachloroethene 2500 ug/mL
Tetrahydrofuran 5000 ug/mL
Toluene 2500 ug/mL
trans-1,2-Dichloroethene 2500 ug/mL
trans-1,3-Dichloropropene 2500 ug/mL
Trichloroethene 2500 ug/mL
Trihalomethanes, Total 10000 ug/mL
Xylenes, Total 5000 ug/mL
MV-568720_00049 Acrolein 987.5 ug/mL25 mL 1250 uL11/18/24 10/22/24MV-MegaMainA_00117 P&T Methanol, Lot EG636-US
2-Butanone (MEK)400 ug/mLMV-569721_00016 800 uL
2-Hexanone 400 ug/mL
4-Methyl-2-pentanone (MIBK)400 ug/mL
Acetone 400 ug/mL
Vinyl acetate 200 ug/mLMV-569724_00038 1000 uL
Cyclohexanone 3000 ug/mLMV-569727_00025 3000 uL
1,1,1,2-Tetrachloroethane 100 ug/mLMV-571992_00017 1000 uL
1,1,1-Trichloroethane 100 ug/mL
1,1,2,2-Tetrachloroethane 100 ug/mL
11/15/2024
3:53:55 PM
Page 66 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
1,1,2-Trichloro-1,2,2-trifluoroethane 100 ug/mL
1,1,2-Trichloroethane 100 ug/mL
1,1-Dichloroethane 100 ug/mL
1,1-Dichloroethene 100 ug/mL
1,1-Dichloropropene 100 ug/mL
1,2,3-Trichlorobenzene 100 ug/mL
1,2,3-Trichloropropane 100 ug/mL
1,2,4-Trichlorobenzene 100 ug/mL
1,2,4-Trimethylbenzene 100 ug/mL
1,2-Dibromo-3-Chloropropane 100 ug/mL
1,2-Dichlorobenzene 100 ug/mL
1,2-Dichloroethane 100 ug/mL
1,2-Dichloropropane 100 ug/mL
1,3,5-Trimethylbenzene 100 ug/mL
1,3-Dichlorobenzene 100 ug/mL
1,3-Dichloropropane 100 ug/mL
1,4-Dichlorobenzene 100 ug/mL
1,4-Dioxane 2000 ug/mL
2,2-Dichloropropane 100 ug/mL
2-Chlorotoluene 100 ug/mL
2-Methyl-2-propanol 1000 ug/mL
3-Chloro-1-propene 100 ug/mL
4-Chlorotoluene 100 ug/mL
4-Isopropyltoluene 100 ug/mL
Acrylonitrile 1000 ug/mL
Benzene 100 ug/mL
Bromobenzene 100 ug/mL
Bromoform 100 ug/mL
Carbon disulfide 100 ug/mL
Carbon tetrachloride 100 ug/mL
Chlorobenzene 100 ug/mL
Chlorobromomethane 100 ug/mL
Chlorodibromomethane 100 ug/mL
Chloroform 100 ug/mL
cis-1,2-Dichloroethene 100 ug/mL
cis-1,3-Dichloropropene 100 ug/mL
Cyclohexane 100 ug/mL
Dibromomethane 100 ug/mL
Dichlorobromomethane 100 ug/mL
Ethyl ether 100 ug/mL
Ethyl methacrylate 100 ug/mL
Ethylbenzene 100 ug/mL
Ethylene Dibromide 100 ug/mL
Hexachlorobutadiene 100 ug/mL
Hexane 100 ug/mL
Iodomethane 100 ug/mL
Isobutyl alcohol 2500 ug/mL
11/15/2024
3:53:55 PM
Page 67 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Isopropylbenzene 100 ug/mL
m-Xylene & p-Xylene 100 ug/mL
Methyl acetate 200 ug/mL
Methyl tert-butyl ether 100 ug/mL
Methylcyclohexane 100 ug/mL
Methylene Chloride 100 ug/mL
n-Butylbenzene 100 ug/mL
n-Heptane 100 ug/mL
N-Propylbenzene 100 ug/mL
Naphthalene 100 ug/mL
o-Xylene 100 ug/mL
sec-Butylbenzene 100 ug/mL
Styrene 100 ug/mL
tert-Butylbenzene 100 ug/mL
Tetrachloroethene 100 ug/mL
Tetrahydrofuran 200 ug/mL
Toluene 100 ug/mL
trans-1,2-Dichloroethene 100 ug/mL
trans-1,3-Dichloropropene 100 ug/mL
trans-1,4-Dichloro-2-butene 100 ug/mL
Trichloroethene 100 ug/mL
1-Chlorohexane 80 ug/mLMV-CUS17739_00017 2000 uL
2-Pentanone 320 ug/mL
sec-Butyl Alcohol 2400 ug/mL
09/30/25 (Purchased Reagent)Acrolein 19750 ug/mLRESTEK, Lot A0209476.MV-568720_00049
04/30/27 (Purchased Reagent)2-Butanone (MEK)12500 ug/mLRESTEK, Lot A0210935.MV-569721_00016
2-Hexanone 12500 ug/mL
4-Methyl-2-pentanone (MIBK)12500 ug/mL
Acetone 12500 ug/mL
09/30/25 (Purchased Reagent)Vinyl acetate 5000 ug/mLRESTEK, Lot A0209567.MV-569724_00038
03/31/27 (Purchased Reagent)Cyclohexanone 25000 ug/mLRESTEK, Lot A0209630.MV-569727_00025
04/30/26 (Purchased Reagent)1,1,1,2-Tetrachloroethane 2500 ug/mLRESTEK, Lot A0203458.MV-571992_00017
1,1,1-Trichloroethane 2500 ug/mL
1,1,2,2-Tetrachloroethane 2500 ug/mL
1,1,2-Trichloro-1,2,2-trifluoroethane 2500 ug/mL
1,1,2-Trichloroethane 2500 ug/mL
1,1-Dichloroethane 2500 ug/mL
1,1-Dichloroethene 2500 ug/mL
1,1-Dichloropropene 2500 ug/mL
1,2,3-Trichlorobenzene 2500 ug/mL
1,2,3-Trichloropropane 2500 ug/mL
1,2,4-Trichlorobenzene 2500 ug/mL
1,2,4-Trimethylbenzene 2500 ug/mL
1,2-Dibromo-3-Chloropropane 2500 ug/mL
1,2-Dichlorobenzene 2500 ug/mL
1,2-Dichloroethane 2500 ug/mL
1,2-Dichloropropane 2500 ug/mL
11/15/2024
3:53:55 PM
Page 68 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
1,3,5-Trimethylbenzene 2500 ug/mL
1,3-Dichlorobenzene 2500 ug/mL
1,3-Dichloropropane 2500 ug/mL
1,4-Dichlorobenzene 2500 ug/mL
1,4-Dioxane 50000 ug/mL
2,2-Dichloropropane 2500 ug/mL
2-Chlorotoluene 2500 ug/mL
2-Methyl-2-propanol 25000 ug/mL
3-Chloro-1-propene 2500 ug/mL
4-Chlorotoluene 2500 ug/mL
4-Isopropyltoluene 2500 ug/mL
Acrylonitrile 25000 ug/mL
Benzene 2500 ug/mL
Bromobenzene 2500 ug/mL
Bromoform 2500 ug/mL
Carbon disulfide 2500 ug/mL
Carbon tetrachloride 2500 ug/mL
Chlorobenzene 2500 ug/mL
Chlorobromomethane 2500 ug/mL
Chlorodibromomethane 2500 ug/mL
Chloroform 2500 ug/mL
cis-1,2-Dichloroethene 2500 ug/mL
cis-1,3-Dichloropropene 2500 ug/mL
Cyclohexane 2500 ug/mL
Dibromomethane 2500 ug/mL
Dichlorobromomethane 2500 ug/mL
Ethyl ether 2500 ug/mL
Ethyl methacrylate 2500 ug/mL
Ethylbenzene 2500 ug/mL
Ethylene Dibromide 2500 ug/mL
Hexachlorobutadiene 2500 ug/mL
Hexane 2500 ug/mL
Iodomethane 2500 ug/mL
Isobutyl alcohol 62500 ug/mL
Isopropylbenzene 2500 ug/mL
m-Xylene & p-Xylene 2500 ug/mL
Methyl acetate 5000 ug/mL
Methyl tert-butyl ether 2500 ug/mL
Methylcyclohexane 2500 ug/mL
Methylene Chloride 2500 ug/mL
n-Butylbenzene 2500 ug/mL
n-Heptane 2500 ug/mL
N-Propylbenzene 2500 ug/mL
Naphthalene 2500 ug/mL
o-Xylene 2500 ug/mL
sec-Butylbenzene 2500 ug/mL
Styrene 2500 ug/mL
11/15/2024
3:53:55 PM
Page 69 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
tert-Butylbenzene 2500 ug/mL
Tetrachloroethene 2500 ug/mL
Tetrahydrofuran 5000 ug/mL
Toluene 2500 ug/mL
trans-1,2-Dichloroethene 2500 ug/mL
trans-1,3-Dichloropropene 2500 ug/mL
trans-1,4-Dichloro-2-butene 2500 ug/mL
Trichloroethene 2500 ug/mL
08/31/26 (Purchased Reagent)1-Chlorohexane 1000 ug/mLAgilent, Lot 6808538.MV-CUS17739_00017
2-Pentanone 4000 ug/mL
sec-Butyl Alcohol 30000 ug/mL
MV-571992_00017 1,2-Dichloroethene, Total 200 ug/mL25 mL 1000 uL11/18/24 10/22/24MV-MegaMainA_00117 P&T Methanol, Lot EG636-US
1,3-Dichloropropene, Total 200 ug/mL
Trihalomethanes, Total 400 ug/mL
Xylenes, Total 200 ug/mL
04/30/26 (Purchased Reagent)1,2-Dichloroethene, Total 5000 ug/mLRESTEK, Lot A0203458.MV-571992_00017
1,3-Dichloropropene, Total 5000 ug/mL
Trihalomethanes, Total 10000 ug/mL
Xylenes, Total 5000 ug/mL
MV-568720_00049 Acrolein 987.5 ug/mL25 mL 1250 uL11/28/24 10/28/24MV-MegaMainA_00118 P&T Methanol, Lot EG636-US
2-Butanone (MEK)400 ug/mLMV-569721_00016 800 uL
2-Hexanone 400 ug/mL
4-Methyl-2-pentanone (MIBK)400 ug/mL
Acetone 400 ug/mL
Vinyl acetate 200 ug/mLMV-569724_00038 1000 uL
Cyclohexanone 3000 ug/mLMV-569727_00025 3000 uL
1,1,1,2-Tetrachloroethane 100 ug/mLMV-571992_00017 1000 uL
1,1,1-Trichloroethane 100 ug/mL
1,1,2,2-Tetrachloroethane 100 ug/mL
1,1,2-Trichloro-1,2,2-trifluoroethane 100 ug/mL
1,1,2-Trichloroethane 100 ug/mL
1,1-Dichloroethane 100 ug/mL
1,1-Dichloroethene 100 ug/mL
1,1-Dichloropropene 100 ug/mL
1,2,3-Trichlorobenzene 100 ug/mL
1,2,3-Trichloropropane 100 ug/mL
1,2,4-Trichlorobenzene 100 ug/mL
1,2,4-Trimethylbenzene 100 ug/mL
1,2-Dibromo-3-Chloropropane 100 ug/mL
1,2-Dichlorobenzene 100 ug/mL
1,2-Dichloroethane 100 ug/mL
1,2-Dichloropropane 100 ug/mL
1,3,5-Trimethylbenzene 100 ug/mL
1,3-Dichlorobenzene 100 ug/mL
11/15/2024
3:53:55 PM
Page 70 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
1,3-Dichloropropane 100 ug/mL
1,4-Dichlorobenzene 100 ug/mL
1,4-Dioxane 2000 ug/mL
2,2-Dichloropropane 100 ug/mL
2-Chlorotoluene 100 ug/mL
2-Methyl-2-propanol 1000 ug/mL
3-Chloro-1-propene 100 ug/mL
4-Chlorotoluene 100 ug/mL
4-Isopropyltoluene 100 ug/mL
Acrylonitrile 1000 ug/mL
Benzene 100 ug/mL
Bromobenzene 100 ug/mL
Bromoform 100 ug/mL
Carbon disulfide 100 ug/mL
Carbon tetrachloride 100 ug/mL
Chlorobenzene 100 ug/mL
Chlorobromomethane 100 ug/mL
Chlorodibromomethane 100 ug/mL
Chloroform 100 ug/mL
cis-1,2-Dichloroethene 100 ug/mL
cis-1,3-Dichloropropene 100 ug/mL
Cyclohexane 100 ug/mL
Dibromomethane 100 ug/mL
Dichlorobromomethane 100 ug/mL
Ethyl ether 100 ug/mL
Ethyl methacrylate 100 ug/mL
Ethylbenzene 100 ug/mL
Ethylene Dibromide 100 ug/mL
Hexachlorobutadiene 100 ug/mL
Hexane 100 ug/mL
Iodomethane 100 ug/mL
Isobutyl alcohol 2500 ug/mL
Isopropylbenzene 100 ug/mL
m-Xylene & p-Xylene 100 ug/mL
Methyl acetate 200 ug/mL
Methyl tert-butyl ether 100 ug/mL
Methylcyclohexane 100 ug/mL
Methylene Chloride 100 ug/mL
n-Butylbenzene 100 ug/mL
n-Heptane 100 ug/mL
N-Propylbenzene 100 ug/mL
Naphthalene 100 ug/mL
o-Xylene 100 ug/mL
sec-Butylbenzene 100 ug/mL
Styrene 100 ug/mL
tert-Butylbenzene 100 ug/mL
Tetrachloroethene 100 ug/mL
11/15/2024
3:53:55 PM
Page 71 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Tetrahydrofuran 200 ug/mL
Toluene 100 ug/mL
trans-1,2-Dichloroethene 100 ug/mL
trans-1,3-Dichloropropene 100 ug/mL
trans-1,4-Dichloro-2-butene 100 ug/mL
Trichloroethene 100 ug/mL
1-Chlorohexane 80 ug/mLMV-CUS17739_00017 2000 uL
2-Pentanone 320 ug/mL
sec-Butyl Alcohol 2400 ug/mL
09/30/25 (Purchased Reagent)Acrolein 19750 ug/mLRESTEK, Lot A0209476.MV-568720_00049
04/30/27 (Purchased Reagent)2-Butanone (MEK)12500 ug/mLRESTEK, Lot A0210935.MV-569721_00016
2-Hexanone 12500 ug/mL
4-Methyl-2-pentanone (MIBK)12500 ug/mL
Acetone 12500 ug/mL
09/30/25 (Purchased Reagent)Vinyl acetate 5000 ug/mLRESTEK, Lot A0209567.MV-569724_00038
03/31/27 (Purchased Reagent)Cyclohexanone 25000 ug/mLRESTEK, Lot A0209630.MV-569727_00025
04/30/26 (Purchased Reagent)1,1,1,2-Tetrachloroethane 2500 ug/mLRESTEK, Lot A0203458.MV-571992_00017
1,1,1-Trichloroethane 2500 ug/mL
1,1,2,2-Tetrachloroethane 2500 ug/mL
1,1,2-Trichloro-1,2,2-trifluoroethane 2500 ug/mL
1,1,2-Trichloroethane 2500 ug/mL
1,1-Dichloroethane 2500 ug/mL
1,1-Dichloroethene 2500 ug/mL
1,1-Dichloropropene 2500 ug/mL
1,2,3-Trichlorobenzene 2500 ug/mL
1,2,3-Trichloropropane 2500 ug/mL
1,2,4-Trichlorobenzene 2500 ug/mL
1,2,4-Trimethylbenzene 2500 ug/mL
1,2-Dibromo-3-Chloropropane 2500 ug/mL
1,2-Dichlorobenzene 2500 ug/mL
1,2-Dichloroethane 2500 ug/mL
1,2-Dichloropropane 2500 ug/mL
1,3,5-Trimethylbenzene 2500 ug/mL
1,3-Dichlorobenzene 2500 ug/mL
1,3-Dichloropropane 2500 ug/mL
1,4-Dichlorobenzene 2500 ug/mL
1,4-Dioxane 50000 ug/mL
2,2-Dichloropropane 2500 ug/mL
2-Chlorotoluene 2500 ug/mL
2-Methyl-2-propanol 25000 ug/mL
3-Chloro-1-propene 2500 ug/mL
4-Chlorotoluene 2500 ug/mL
4-Isopropyltoluene 2500 ug/mL
Acrylonitrile 25000 ug/mL
Benzene 2500 ug/mL
Bromobenzene 2500 ug/mL
Bromoform 2500 ug/mL
11/15/2024
3:53:55 PM
Page 72 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Carbon disulfide 2500 ug/mL
Carbon tetrachloride 2500 ug/mL
Chlorobenzene 2500 ug/mL
Chlorobromomethane 2500 ug/mL
Chlorodibromomethane 2500 ug/mL
Chloroform 2500 ug/mL
cis-1,2-Dichloroethene 2500 ug/mL
cis-1,3-Dichloropropene 2500 ug/mL
Cyclohexane 2500 ug/mL
Dibromomethane 2500 ug/mL
Dichlorobromomethane 2500 ug/mL
Ethyl ether 2500 ug/mL
Ethyl methacrylate 2500 ug/mL
Ethylbenzene 2500 ug/mL
Ethylene Dibromide 2500 ug/mL
Hexachlorobutadiene 2500 ug/mL
Hexane 2500 ug/mL
Iodomethane 2500 ug/mL
Isobutyl alcohol 62500 ug/mL
Isopropylbenzene 2500 ug/mL
m-Xylene & p-Xylene 2500 ug/mL
Methyl acetate 5000 ug/mL
Methyl tert-butyl ether 2500 ug/mL
Methylcyclohexane 2500 ug/mL
Methylene Chloride 2500 ug/mL
n-Butylbenzene 2500 ug/mL
n-Heptane 2500 ug/mL
N-Propylbenzene 2500 ug/mL
Naphthalene 2500 ug/mL
o-Xylene 2500 ug/mL
sec-Butylbenzene 2500 ug/mL
Styrene 2500 ug/mL
tert-Butylbenzene 2500 ug/mL
Tetrachloroethene 2500 ug/mL
Tetrahydrofuran 5000 ug/mL
Toluene 2500 ug/mL
trans-1,2-Dichloroethene 2500 ug/mL
trans-1,3-Dichloropropene 2500 ug/mL
trans-1,4-Dichloro-2-butene 2500 ug/mL
Trichloroethene 2500 ug/mL
08/31/26 (Purchased Reagent)1-Chlorohexane 1000 ug/mLAgilent, Lot 6808538.MV-CUS17739_00017
2-Pentanone 4000 ug/mL
sec-Butyl Alcohol 30000 ug/mL
MV-571992_00017 1,2-Dichloroethene, Total 200 ug/mL25 mL 1000 uL11/28/24 10/28/24MV-MegaMainA_00118 P&T Methanol, Lot EG636-US
1,3-Dichloropropene, Total 200 ug/mL
Trihalomethanes, Total 400 ug/mL
Xylenes, Total 200 ug/mL
11/15/2024
3:53:55 PM
Page 73 of 777
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
04/30/26 (Purchased Reagent)1,2-Dichloroethene, Total 5000 ug/mLRESTEK, Lot A0203458.MV-571992_00017
1,3-Dichloropropene, Total 5000 ug/mL
Trihalomethanes, Total 10000 ug/mL
Xylenes, Total 5000 ug/mL
11/15/2024
3:53:55 PM
Page 74 of 777
Reagent
mv-30241_00014
11/15/2024
3:53:55 PM
Page 75 of 777
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :30241 Lot No.:A0198297
8260A Internal Standard MixDescription :
8260A Internal Standard Mix 2,500 µg/mL, P&T Methanol, 1mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
2 mL > 1 mLPkg Amt:
May 31, 2028
Ship:Ambient
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 2,504.7Fluorobenzene462-06-6 +/- 140.7155BCBZ5549
99% 2 µg/mL 2,513.3Chlorobenzene-d5 3114-55-4 +/- 141.2024PR-29571
99% 3 µg/mL 2,515.31,4-Dichlorobenzene-d4 3855-82-1 +/- 141.3148PR-30447
Solvent:P&T Methanol
99%
67-56-1CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
11/15/2024
3:53:55 PM
Page 76 of 777
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
105m x 0.53mm x 3.0µm
Rtx-502.2 (cat.#10910)
Column:
hydrogen-constant pressure 11.0 psi.
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
FID
1128342314Balance Serial #
24-May-2023Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
22-May-2023Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
40 ml/min
Inj. Vol
1µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
11/15/2024
3:53:55 PM
Page 77 of 777
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
11/15/2024
3:53:55 PM
Page 78 of 777
Reagent
MV-567650_00030
11/15/2024
3:53:55 PM
Page 79 of 777
11/15/2024
3:53:55 PM
Page 80 of 777
11/15/2024
3:53:55 PM
Page 81 of 777
Reagent
MV-567650_00033
11/15/2024
3:53:55 PM
Page 82 of 777
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :567650 Lot No.:A0211048
8260 Surrogate StandardDescription :
8260 Surrogate Standard 2,500µg/mL, P&T Methanol, 5mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
5 mL > 5 mLPkg Amt:
May 31, 2029
Ship:Ambient
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 2,502.2Dibromofluoromethane1868-53-7 +/- 140.5627022013
99% 2 µg/mL 2,501.31,2-Dichloroethane-d4 17060-07-0 +/- 140.5094PR-33313
99% 3 µg/mL 2,502.8Toluene-d8 2037-26-5 +/- 140.5965PR-34141
99% 4 µg/mL 2,501.61-Bromo-4-fluorobenzene (BFB)460-00-4 +/- 140.52620000194533
Solvent:P&T Methanol
99%
67-56-1CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
11/15/2024
3:53:55 PM
Page 83 of 777
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
105m x 0.53mm x 3.0µm
Rtx-502.2 (cat.#10910)
Column:
hydrogen-constant pressure 11.0 psi.
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
FID
1128342314Balance Serial #
06-May-2024Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
03-May-2024Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
40 ml/min
Inj. Vol
1µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
11/15/2024
3:53:55 PM
Page 84 of 777
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
11/15/2024
3:53:55 PM
Page 85 of 777
Reagent
MV-568720_00049
11/15/2024
3:53:55 PM
Page 86 of 777
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :568720 Lot No.:A0209476
8260 List 1/Std #5 Acrolein HighDescription :
8260 List 1/Std #5 Acrolein High 19,750µg/mL, Water, 1mL/ampul
Container Size :
Expiration Date :Storage:-20°C or colder
2 mL > 1 mLPkg Amt:
Handling:This product is photosensitive.
September 30, 2025
Ship:On Ice
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 19,917.5Acrolein107-02-8 +/- 585.1357RP240118CTH
Solvent:Water
99%
7732-18-5CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
11/15/2024
3:53:55 PM
Page 87 of 777
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
105m x 0.53mm x 3.0µm
Rtx-502.2 (cat.#10910)
Column:
hydrogen-constant pressure 11.0 psi.
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
FID
1128360905Balance Serial #
01-Apr-2024Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
26-Mar-2024Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
40 ml/min
Inj. Vol
1µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
11/15/2024
3:53:55 PM
Page 88 of 777
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
11/15/2024
3:53:55 PM
Page 89 of 777
Reagent
MV-569721.sec_00013
11/15/2024
3:53:55 PM
Page 90 of 777
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :569721.SEC Lot No.:A0209876
8260 List 1/ Std #2 Ketones (2015)Description :
8260 List 1/ Std #2 Ketones (2015) 12,500µg/mL, P&T Methanol/Water
(90:10), 1mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
2 mL > 1 mLPkg Amt:
April 30, 2027
Ship:Ambient
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 12,580.0Acetone67-64-1.SEC +/- 434.7940U19I024
99% 2 µg/mL 12,611.62-Butanone (MEK)78-93-3.SEC +/- 435.8862HDLUO
99% 3 µg/mL 12,576.44-Methyl-2-pentanone (MIBK)108-10-1.SEC +/- 434.6696E29T040
99% 4 µg/mL 12,574.82-Hexanone 591-78-6.SEC +/- 434.6143NXXXA
Solvent:P&T Methanol/Water (90:10)
99%
67-56-1/7732-18-5CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
11/15/2024
3:53:55 PM
Page 91 of 777
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
105m x 0.53mm x 3.0µm
Rtx-502.2 (cat.#10910)
Column:
hydrogen-constant pressure 11.0 psi.
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
FID
1127510105Balance Serial #
09-Apr-2024Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
05-Apr-2024Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
40 ml/min
Inj. Vol
0.2µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
11/15/2024
3:53:55 PM
Page 92 of 777
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
11/15/2024
3:53:55 PM
Page 93 of 777
Reagent
MV-569721_00016
11/15/2024
3:53:55 PM
Page 94 of 777
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :569721 Lot No.:A0210935
8260 List 1/ Std #2 Ketones (2015)Description :
8260 List 1/ Std #2 Ketones (2015) 12,500µg/mL, P&T Methanol/Water
(90:10), 1mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
2 mL > 1 mLPkg Amt:
April 30, 2027
Ship:Ambient
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 12,591.3Acetone67-64-1 +/- 435.1857SHBQ8504
99% 2 µg/mL 12,561.02-Butanone (MEK)78-93-3 +/- 434.1373SHBQ4704
99% 3 µg/mL 12,580.04-Methyl-2-pentanone (MIBK)108-10-1 +/- 434.7940SHBP9200
99% 4 µg/mL 12,580.72-Hexanone 591-78-6 +/- 434.8170MKCV1997
Solvent:P&T Methanol/Water (90:10)
99%
67-56-1/7732-18-5CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
11/15/2024
3:53:55 PM
Page 95 of 777
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
105m x 0.53mm x 3.0µm
Rtx-502.2 (cat.#10910)
Column:
hydrogen-constant pressure 11.0 psi.
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
FID
B707717271Balance Serial #
02-May-2024Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
30-Apr-2024Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
40 ml/min
Inj. Vol
0.2µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
11/15/2024
3:53:55 PM
Page 96 of 777
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
11/15/2024
3:53:55 PM
Page 97 of 777
Reagent
MV-569722.sec_00019
11/15/2024
3:53:55 PM
Page 98 of 777
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :569722.SEC Lot No.:A0210106
8260 List 1 / Std #3 Gases (2015)Description :
8260 List 1 / Std #3 Gases (2015) 2,500µg/mL, P&T Methanol,
1mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
2 mL > 1 mLPkg Amt:
April 30, 2027
Ship:Ambient
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 2,508.8Dichlorodifluoromethane (CFC-12)75-71-8.SEC +/- 141.969628888
99% 2 µg/mL 2,503.3Chloromethane (methyl chloride)74-87-3.SEC +/- 142.014400022694
99% 3 µg/mL 2,508.1Vinyl chloride 75-01-4 *+/- 141.591000015559
99% 4 µg/mL 2,509.71,3-Butadiene 106-99-0.SEC +/- 141.741728539
99% 5 µg/mL 2,506.6Bromomethane (methyl bromide)74-83-9 *+/- 141.420900017022
99% 6 µg/mL 2,510.1Chloroethane (ethyl chloride)75-00-3.SEC +/- 142.264200021903
90% 7 µg/mL 2,523.6Dichlorofluoromethane (CFC-21)75-43-4 *+/- 141.779214485600
99% 8 µg/mL 2,512.0Trichlorofluoromethane (CFC-11)75-69-4.SEC +/- 142.197600010739
Solvent:P&T Methanol
99%
67-56-1CAS #
Purity
* Restek is unable to identify a reliable and/or acceptable second source for this material - the same batch of neat
material may have been used to produce both the primary and secondary standard. The primary and secondary
standards were prepared using different equipment and personnel.
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
11/15/2024
3:53:55 PM
Page 99 of 777
Raw material may contain trace amounts of tert-Butanol.
Tech Tips:
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
60m x 0.25mm x 1.4µm
Rtx-502.2 (cat.#10916)
Column:
helium-constant pressure 30 psi
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
MSD
1127510105Balance Serial #
17-Apr-2024Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
10-Apr-2024Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
25.0 ml/min.
Inj. Vol
1µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
11/15/2024
3:53:55 PM
Page 100 of 777
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
11/15/2024
3:53:55 PM
Page 101 of 777
Reagent
MV-569722.sec_00020
11/15/2024
3:53:55 PM
Page 102 of 777
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :569722.SEC Lot No.:A0211505
8260 List 1 / Std #3 Gases (2015)Description :
8260 List 1 / Std #3 Gases (2015) 2,500µg/mL, P&T Methanol,
1mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
2 mL > 1 mLPkg Amt:
May 31, 2027
Ship:Ambient
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 2,506.6Dichlorodifluoromethane (CFC-12)75-71-8.SEC +/- 141.955728888
99% 2 µg/mL 2,508.3Chloromethane (methyl chloride)74-87-3.SEC +/- 142.103900022694
99% 3 µg/mL 2,513.8Vinyl chloride 75-01-4 *+/- 142.723500015559
99% 4 µg/mL 2,508.81,3-Butadiene 106-99-0.SEC +/- 142.027528539
99% 5 µg/mL 2,535.7Bromomethane (methyl bromide)74-83-9 *+/- 145.748700017022
99% 6 µg/mL 2,503.6Chloroethane (ethyl chloride)75-00-3.SEC +/- 141.418100021903
90% 7 µg/mL 2,523.6Dichlorofluoromethane (CFC-21)75-43-4 *+/- 141.779214485600
99% 8 µg/mL 2,509.1Trichlorofluoromethane (CFC-11)75-69-4.SEC +/- 141.818400010739
Solvent:P&T Methanol
99%
67-56-1CAS #
Purity
* Restek is unable to identify a reliable and/or acceptable second source for this material - the same batch of neat
material may have been used to produce both the primary and secondary standard. The primary and secondary
standards were prepared using different equipment and personnel.
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
11/15/2024
3:53:55 PM
Page 103 of 777
Raw material may contain trace amounts of tert-Butanol.
Tech Tips:
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
60m x 0.25mm x 1.4µm
Rtx-502.2 (cat.#10916)
Column:
helium-constant pressure 30 psi
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
MSD
1127510105Balance Serial #
21-May-2024Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
15-May-2024Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
25.0 ml/min.
Inj. Vol
1µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
11/15/2024
3:53:55 PM
Page 104 of 777
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
11/15/2024
3:53:55 PM
Page 105 of 777
Reagent
MV-569722_00024
11/15/2024
3:53:55 PM
Page 106 of 777
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :569722 Lot No.:A0211969
8260 List 1 / Std #3 Gases (2015)Description :
8260 List 1 / Std #3 Gases (2015) 2,500µg/mL, P&T Methanol,
1mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
2 mL > 1 mLPkg Amt:
May 31, 2027
Ship:Ambient
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 2,523.8Dichlorodifluoromethane (CFC-12)75-71-8 +/- 142.430100022922
99% 2 µg/mL 2,527.3Chloromethane (methyl chloride)74-87-3 +/- 142.5086SHBP8835
99% 3 µg/mL 2,526.1Vinyl chloride 75-01-4 +/- 142.407500015559
99% 4 µg/mL 2,523.91,3-Butadiene 106-99-0 +/- 142.385100019375
99% 5 µg/mL 2,520.8Bromomethane (methyl bromide)74-83-9 +/- 142.696200017022
99% 6 µg/mL 2,520.7Chloroethane (ethyl chloride)75-00-3 +/- 142.3441107-401039114-1
90% 7 µg/mL 2,524.5Dichlorofluoromethane (CFC-21)75-43-4 +/- 141.815514485600
99% 8 µg/mL 2,518.0Trichlorofluoromethane (CFC-11)75-69-4 +/- 141.8687MKCJ8658
Solvent:P&T Methanol
99%
67-56-1CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
11/15/2024
3:53:55 PM
Page 107 of 777
Raw material may contain trace amounts of tert-Butanol.
Tech Tips:
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
60m x 0.25mm x 1.4µm
Rtx-502.2 (cat.#10916)
Column:
helium-constant pressure 30 psi
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
MSD
B707717271Balance Serial #
04-Jun-2024Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
23-May-2024Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
25.0 ml/min.
Inj. Vol
1µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
11/15/2024
3:53:55 PM
Page 108 of 777
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
11/15/2024
3:53:55 PM
Page 109 of 777
Reagent
MV-569723_00019
11/15/2024
3:53:55 PM
Page 110 of 777
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :569723 Lot No.:A0213181
8260 List 1 / Std #4 2-CEVE (2015)Description :
8260 List 1 / Std #4 2-CEVE (2015) 2,500µg/mL, P&T Methanol,
1mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
2 mL > 1 mLPkg Amt:
June 30, 2027
Ship:Ambient
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 2,508.82-Chloroethyl vinyl ether 110-75-8 +/- 31.2225MKCV7865
Solvent:P&T Methanol
99%
67-56-1CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
Degradation of tetrachloroethylene to pentachloroethane may occur if solutions containing 2-chloroethyl vinyl ether are combined
with solutions that contain tetrachloroethylene.
Tech Tips:
01-Nov-2022 rev.Page 1 of 3
11/15/2024
3:53:55 PM
Page 111 of 777
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
105m x 0.53mm x 3.0µm
Rtx-502.2 (cat.#10910)
Column:
hydrogen-constant pressure 11.0 psi.
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
FID
B251644995Balance Serial #
27-Jun-2024Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
25-Jun-2024Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
40 ml/min
Inj. Vol
0.2µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
11/15/2024
3:53:55 PM
Page 112 of 777
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
11/15/2024
3:53:55 PM
Page 113 of 777
Reagent
MV-569724.sec_00038
11/15/2024
3:53:55 PM
Page 114 of 777
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :569724.SEC Lot No.:A0210661
8260 List 1 / Std #6 Vinyl Acetate (2015)Description :
8260 List 1 / Std #6 Vinyl Acetate (2015) 5,000µg/mL, P&T Methanol,
1mL/ampul
Container Size :
Expiration Date :Storage:-20°C or colder
2 mL > 1 mLPkg Amt:
Handling:This product is photosensitive.
October 31, 2025
Ship:On Ice
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
98% 1 µg/mL 5,046.0Vinyl acetate 108-05-4.SEC +/- 174.4022RD230301RSRA
Solvent:P&T Methanol
99%
67-56-1CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
Vinyl acetate is a volatile organic ester included in the target lists of several US EPA and other methods. Under acidic conditions,
esters react with alcohols to form new esters (transesterification). Methanol-based mixes containing halogenated compounds are
slightly acidic, so it is important to minimize exposure of vinyl acetate to mixes of halogenated compounds in methanol. For this
reason, we offer vinyl acetate in individual solution, and suggest that it be introduced into the working level calibration solution
immediately before use. This will minimize problems and ensure more consistent results.
Tech Tips:
01-Nov-2022 rev.Page 1 of 3
11/15/2024
3:53:55 PM
Page 115 of 777
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
105m x 0.53mm x 3.0µm
Rtx-502.2 (cat.#10910)
Column:
hydrogen-constant pressure 11.0 psi.
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
FID
1128342314Balance Serial #
25-Apr-2024Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
23-Apr-2024Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
40 ml/min
Inj. Vol
0.2µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
11/15/2024
3:53:55 PM
Page 116 of 777
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
11/15/2024
3:53:55 PM
Page 117 of 777
Reagent
MV-569724_00038
11/15/2024
3:53:55 PM
Page 118 of 777
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :569724 Lot No.:A0209567
8260 List 1 / Std #6 Vinyl Acetate (2015)Description :
8260 List 1 / Std #6 Vinyl Acetate (2015) 5,000µg/mL, P&T Methanol,
1mL/ampul
Container Size :
Expiration Date :Storage:-20°C or colder
2 mL > 1 mLPkg Amt:
Handling:This product is photosensitive.
September 30, 2025
Ship:On Ice
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
98% 1 µg/mL 5,034.8Vinyl acetate 108-05-4 +/- 173.9777RP231030CTH
Solvent:P&T Methanol
99%
67-56-1CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
Vinyl acetate is a volatile organic ester included in the target lists of several US EPA and other methods. Under acidic conditions,
esters react with alcohols to form new esters (transesterification). Methanol-based mixes containing halogenated compounds are
slightly acidic, so it is important to minimize exposure of vinyl acetate to mixes of halogenated compounds in methanol. For this
reason, we offer vinyl acetate in individual solution, and suggest that it be introduced into the working level calibration solution
immediately before use. This will minimize problems and ensure more consistent results.
Tech Tips:
01-Nov-2022 rev.Page 1 of 3
11/15/2024
3:53:55 PM
Page 119 of 777
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
105m x 0.53mm x 3.0µm
Rtx-502.2 (cat.#10910)
Column:
hydrogen-constant pressure 11.0 psi.
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
FID
B251644995Balance Serial #
29-Mar-2024Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
27-Mar-2024Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
40 ml/min
Inj. Vol
0.2µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
11/15/2024
3:53:55 PM
Page 120 of 777
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
11/15/2024
3:53:55 PM
Page 121 of 777
Reagent
MV-569727_00025
11/15/2024
3:53:55 PM
Page 122 of 777
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :569727 Lot No.:A0209630
8260 List 2/ Std #3 Cyclohexanone (2015)Description :
8260 List 2/ Std #3 Cyclohexanone (2015) 25,000µg/mL, Water,
1mL/ampul
Container Size :
Expiration Date :Storage:10°C or colder
2 mL > 1 mLPkg Amt:
March 31, 2027
Ship:Ambient
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 25,225.0Cyclohexanone108-94-1 +/- 871.8345MKCS0133
Solvent:Water
99%
7732-18-5CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
11/15/2024
3:53:55 PM
Page 123 of 777
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
105m x 0.53mm x 3.0µm
Rtx-502.2 (cat.#10910)
Column:
hydrogen-constant pressure 11.0 psi.
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
FID
1128360905Balance Serial #
02-Apr-2024Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
29-Mar-2024Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
40 ml/min
Inj. Vol
1µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
11/15/2024
3:53:55 PM
Page 124 of 777
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
11/15/2024
3:53:55 PM
Page 125 of 777
Reagent
MV-571992.sec_00010
11/15/2024
3:53:55 PM
Page 126 of 777
11/15/2024
3:53:55 PM
Page 127 of 777
11/15/2024
3:53:55 PM
Page 128 of 777
11/15/2024
3:53:55 PM
Page 129 of 777
11/15/2024
3:53:55 PM
Page 130 of 777
Reagent
MV-571992_00017
11/15/2024
3:53:55 PM
Page 131 of 777
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :571992 Lot No.:A0203458
8260 List 1 / Std #1 MegaMix (2017)Description :
8260 List 1 / Std #1 MegaMix (2017) 1,250-62,500µg/mL, P&T Methanol,
1mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
2 mL > 1 mLPkg Amt:
April 30, 2026
Ship:Ambient
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 2,515.0Diethyl ether (ethyl ether)60-29-7 +/- 86.9068SHBQ1495
99% 2 µg/mL 2,518.81,1,2-Trichlorotrifluoroethane (CFC-113)76-13-1 +/- 87.036400016133
99% 3 µg/mL 2,516.31,1-dichloroethene 75-35-4 +/- 86.9500SHBG8609V
99% 4 µg/mL 25,095.0tert-Butanol (TBA)75-65-0 +/- 867.1659SHBQ8002
99% 5 µg/mL 5,016.4Methyl acetate 79-20-9 +/- 173.3427SHBP3100
99% 6 µg/mL 2,517.4Iodomethane (methyl iodide)74-88-4 +/- 86.9888MKCN8012
99% 7 µg/mL 2,515.9Allyl chloride ( 3-chloropropene )107-05-1 +/- 86.9370RD230914ECS
99% 8 µg/mL 2,513.8Methylene chloride (dichloromethane)75-09-2 +/- 86.8636SHBQ6376
99% 9 µg/mL 2,512.9Carbon disulfide 75-15-0 +/- 86.8333Q30J743
99% 10 µg/mL 25,031.9Acrylonitrile107-13-1 +/- 864.9846102466R02E
99% 11 µg/mL 2,513.8Methyl-tert-butyl ether ( MTBE )1634-04-4 +/- 86.8636SHBP0179
99% 12 µg/mL 2,514.0cis-1,2-Dichloroethene 156-59-2 +/- 86.8722MKCP7830
99% 13 µg/mL 2,520.3n-Hexane (C6)110-54-3 +/- 87.0882STBG6381
99% 14 µg/mL 2,514.01,1-Dichloroethane 75-34-3 +/- 86.8722852900
99% 15 µg/mL 2,521.32,2-Dichloropropane 594-20-7 +/- 87.1227RD230426
99% 16 µg/mL 2,514.9trans-1,2-Dichloroethene 156-60-5 +/- 86.9025MKCP9516
01-Nov-2022 rev.Page 1 of 5
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99% 17 µg/mL 62,561.0Isobutanol (2-Methyl-1-propanol)78-83-1 +/- 2,161.8157SHBP7066
99% 18 µg/mL 2,513.6chloroform67-66-3 +/- 86.8593SHBN8469
99% 19 µg/mL 2,513.5Bromochloromethane74-97-5 +/- 86.8549230810JLM
99% 20 µg/mL 5,020.9Tetrahydrofuran109-99-9 +/- 173.4982SHBQ8516
99% 21 µg/mL 2,513.51,1,1-trichloroethane 71-55-6 +/- 86.8549RD230728RSR
99% 22 µg/mL 2,513.5Cyclohexane110-82-7 +/- 86.8549MKCQ2001
99% 23 µg/mL 2,514.31,1-Dichloropropene 563-58-6 +/- 86.8809230825JLM
99% 24 µg/mL 2,513.0carbon tetrachloride 56-23-5 +/- 86.8377SHBP4875
99% 25 µg/mL 2,515.4n-Heptane (C7)142-82-5 +/- 86.9197044743T01D
99% 26 µg/mL 2,513.51,2-Dichloroethane 107-06-2 +/- 86.8549SHBQ0693
99% 27 µg/mL 2,513.4Benzene71-43-2 +/- 86.8506MKCS3357
99% 28 µg/mL 2,513.6Trichloroethene79-01-6 +/- 86.8593SHBN3720
99% 29 µg/mL 2,514.8Methylcyclohexane108-87-2 +/- 86.8981SHBN1699
99% 30 µg/mL 2,514.91,2-Dichloropropane 78-87-5 +/- 86.9025BCBR0882V
99% 31 µg/mL 50,131.41,4-Dioxane 123-91-1 +/- 1,732.3059SHBQ2407
99% 32 µg/mL 2,514.6Dibromomethane74-95-3 +/- 86.893810233302
99% 33 µg/mL 2,513.5cis-1,3-Dichloropropene 10061-01-5 +/- 86.8549RD230406RSR
99% 34 µg/mL 2,512.9Toluene108-88-3 +/- 86.8333MKCS9989
97% 35 µg/mL 2,508.3Ethyl methacrylate 97-63-2 +/- 86.6752MKCN6206
99% 36 µg/mL 2,512.9trans-1,3-Dichloropropene 10061-02-6 +/- 86.8333RD220816
99% 37 µg/mL 2,513.51,1,2-Trichloroethane 79-00-5 +/- 86.8549FGB01
99% 38 µg/mL 2,514.11,3-Dichloropropane 142-28-9 +/- 86.8765BCCH5357
99% 39 µg/mL 2,514.0Tetrachloroethene127-18-4 +/- 86.8722SHBQ0051
99% 40 µg/mL 2,512.9dibromochloromethane124-48-1 +/- 86.8333MKCQ4517
99% 41 µg/mL 2,515.01,2-Dibromoethane (EDB)106-93-4 +/- 86.9068BCCH7113
99% 42 µg/mL 2,515.0Chlorobenzene108-90-7 +/- 86.9068SHBN6640
99% 43 µg/mL 1,254.8m-Xylene 108-38-3 +/- 43.3584SHBN6673
99% 44 µg/mL 1,257.0p-Xylene 106-42-3 +/- 43.4361SHBP5191
99% 45 µg/mL 2,514.1Ethylbenzene100-41-4 +/- 86.8765094632L21G
99% 46 µg/mL 2,514.91,1,1,2-Tetrachloroethane 630-20-6 +/- 86.9025GC01
99% 47 µg/mL 2,514.0o-Xylene 95-47-6 +/- 86.872250069309
99% 48 µg/mL 2,514.0Styrene100-42-5 +/- 86.8722MKCQ3390
99% 49 µg/mL 2,514.1Isopropylbenzene (cumene)98-82-8 +/- 86.8765Z20D022
99% 50 µg/mL 2,515.3bromoform75-25-2 +/- 86.9154050494L04R
99% 51 µg/mL 2,512.5bromodichloromethane75-27-4 +/- 86.8204MKCF8470
99% 52 µg/mL 2,515.31,1,2,2-Tetrachloroethane 79-34-5 +/- 86.9154QQJ41
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98% 53 µg/mL 2,513.51,2,3-Trichloropropane 96-18-4 +/- 86.8534Q91-34
94% 54 µg/mL 2,504.7trans-1,4-dichloro-2-butene 110-57-6 +/- 86.5525RD230720RSR
98% 55 µg/mL 2,511.4n-Propylbenzene 103-65-1 +/- 86.7814G08M
99% 56 µg/mL 2,514.8Bromobenzene108-86-1 +/- 86.8981MKCQ7174
99% 57 µg/mL 2,513.81,3,5-Trimethylbenzene 108-67-8 +/- 86.8636BCCF4166
99% 58 µg/mL 2,514.82-Chlorotoluene 95-49-8 +/- 86.8981235783M23T
99% 59 µg/mL 2,514.94-Chlorotoluene 106-43-4 +/- 86.9025BCCG9286
99% 60 µg/mL 2,514.0tert-Butylbenzene 98-06-6 +/- 86.8722STBJ1937
99% 61 µg/mL 2,515.91,2,4-Trimethylbenzene 95-63-6 +/- 86.9370MKCS3775
99% 62 µg/mL 2,515.3sec-Butylbenzene 135-98-8 +/- 86.9154MKCP2266
99% 63 µg/mL 2,514.9p-Isopropyltoluene (p-Cymene)99-87-6 +/- 86.9025MKCR6143
99% 64 µg/mL 2,515.31,3-Dichlorobenzene 541-73-1 +/- 86.9154BCCD5315
99% 65 µg/mL 2,514.91,4-Dichlorobenzene 106-46-7 +/- 86.9025MKBS7929V
99% 66 µg/mL 2,514.5n-Butylbenzene 104-51-8 +/- 86.889509418JJ
99% 67 µg/mL 2,514.31,2-Dichlorobenzene 95-50-1 +/- 86.8809SHBN3835
97% 68 µg/mL 2,510.41,2-Dibromo-3-chloropropane 96-12-8 +/- 86.7464HBMVB
99% 69 µg/mL 2,514.91,2,4-Trichlorobenzene 120-82-1 +/- 86.9025SHBP5900
98% 70 µg/mL 2,510.0Hexachlorobutadiene87-68-3 +/- 86.7349RP230823RSR
99% 71 µg/mL 2,514.3Naphthalene91-20-3 +/- 86.8809STBL1057
99% 72 µg/mL 2,514.11,2,3-Trichlorobenzene 87-61-6 +/- 86.8765MKBX7627V
Solvent:P&T Methanol
99%
67-56-1CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 3 of 5
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3:53:55 PM
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Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
60m x 0.25mm x 1.4µm
Rtx-502.2 (cat.#10916)
Column:
helium-constant pressure 30 psi
40°C (hold 6 min.) to 240°C
@ 6°C/min. (hold 10 min.)
200°C
250°C
MSD
B707717271Balance Serial #
08-Dec-2023Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
22-Oct-2023Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
20.0 ml/min.
Inj. Vol
0.2µl
Split Vent:
01-Nov-2022 rev.Page 4 of 5
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3:53:55 PM
Page 135 of 777
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 5 of 5
11/15/2024
3:53:55 PM
Page 136 of 777
Reagent
MV-CUS17739_00017
11/15/2024
3:53:55 PM
Page 137 of 777
ISO 17034
Reference Material Certificate
Product Information Sheet
Custom Standard
CUS-17739
Product Name:
Product Number:
31-Aug-2026Expiration Date:Store Frozen (-25° to -10°C).Storage Conditions:
31-Jul-2024Lot Issue Date:
0006808538Lot Number:
Traceability:
The balances used for these measurements are calibrated with weights traceable to NIST in compliance with ANSI/NCSL Z540.3,
ISO 9001, ISO 17025, and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are
calibrated against a NIST traceable thermometer in accordance with NIST Special Publication 1088.
Homogeneity:
This analytical reference standard was unitized according to an in-house procedure and is guaranteed to be homogeneous. There is
no minimum sub-sample size required.
Intended Use:
This analytical reference standard is intended for the preparation of working reference samples for use in routine laboratory
analyses, calibration of instruments, validation of analytical methods, assessments of measurement methods, and continuing
calibration verification.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at 20ºC to 25ºC immediately after opening the container and should be processed
without delay for the certified values to be valid within the stated uncertainties.
Safety:
Expiration of Certification:
The certification of this analytical reference standard is valid until the expiration date specified above, provided the material is
handled and stored in accordance with the instructions given in this certificate. This certification is nullified if the material is
damaged, contaminated, or otherwise modified.

Matrix:methanol (purge & trap grade)
Refer to the Safety Data Sheet on www.agilent.com for information regarding this analytical reference material.
This document is prepared in accordance with ISO 17034 and Guide 31. This analytical reference material standard was
manufactured and verified in accordance with an ISO 9001 registered quality system and analyte concentrations were verified by an
ISO 17025 accredited laboratory. The concentration and uncertainty value at the 95% confidence level for each analyte, determined
gravimetrically, is listed above.
Description:
Component Name CAS#Analyte LotConcentrationUncertainty
1-chlorohexane 000544-10-5 RM204861004 ± 5 µg/mL
2-pentanone 000107-87-9 RM134784017 ± 20 µg/mL
sec-butanol 000078-92-2 RM1350630013 ± 150 µg/mL
1 of 2Page:
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Cert No. AT-1937
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3:53:55 PM
Page 138 of 777
Maintenance of Certification:
If substantive changes are noted that affect the certification before the expiration of this certificate, Agilent will notify the purchaser.

Sample lot approver:
ISO 17034
RM was produced in accordance with the TUV/SUD registered ISO
9001:2015 Quality Management System. Cert# 951215321
2 of 2Page:
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CSD-QA-015.2 ISO 17025
Cert No. AR-1936 Cert No. AT-1937
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3:53:55 PM
Page 139 of 777
Reagent
mv-IS/SS Tune_00002
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8260D
Volatile Organic Compounds by GC/MS
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Page 143 of 777
FORM II
GC/MS VOA SURROGATE RECOVERY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Matrix:Water Level:Low
GC Column (1):DB-624 (60.25)ID:0.25(mm)
#Lab Sample IDClient Sample ID ###DBFM DCA TOL BFB
280-198899-2MW-61-241030 93 91 108 94
280-198899-3MW-63-241030 93 92 106 94
280-198899-4FB-01 95 92 109 91
280-198899-5DS-01 94 90 106 92
280-198899-5 DLDS-01 DL 103 106 97 103
280-198899-6Trip Blank 95 93 109 92
MB 280-674451/9 96 93 106 91
MB 280-674813/9 101 107 100 98
LCS 280-674451/4 103 95 103 95
LCS 280-674813/4 104 101 99 100
LCSD 280-674451/5 103 98 100 95
LCSD 280-674813/5 103 107 98 101
280-198899-3 MSMW-63-241030 MS 100 90 106 93
280-198899-3 MSDMW-63-241030 MSD 101 92 105 91
QC LIMITS
DBFM = Dibromofluoromethane (Surr)77-120
DCA = 1,2-Dichloroethane-d4 (Surr)70-127
TOL = Toluene-d8 (Surr)80-125
BFB = 4-Bromofluorobenzene (Surr)78-120
FORM II 8260D
# Column to be used to flag recovery values
11/15/2024
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Page 144 of 777
GC/MS VOA LAB CONTROL SAMPLE RECOVERY
FORM III
Job No.:Lab Name:280-198899-1Eurofins Denver
SDG No.:
Level:Matrix:Low Lab File ID:VMS14_0000004265A.DWater
Lab ID:LCS 280-674451/4 Client ID:
REC
%
REC
QC
LIMITSCONCENTRATION
(ug/L)
SPIKE
ADDED
(ug/L)
#
LCS LCS
COMPOUND
Ethylbenzene 50.0 48.3 80-12097
Styrene 50.0 48.6 80-12097
cis-1,3-Dichloropropene 50.0 53.7 76-129107
trans-1,3-Dichloropropene 50.0 44.2 80-12388
N-Propylbenzene 50.0 48.8 80-12398
n-Butylbenzene 50.0 43.5 59-14087
4-Chlorotoluene 50.0 49.0 80-12098
1,4-Dichlorobenzene 50.0 50.2 80-120100
Ethylene Dibromide 50.0 51.5 80-120103
3-Chloro-1-propene 50.0 48.3 65-13297
1,2-Dichloroethane 50.0 46.2 71-12192
Vinyl acetate 100 108 55-161108
4-Methyl-2-pentanone (MIBK)200 191 66-13595
1,3,5-Trimethylbenzene 50.0 47.2 80-12294
Bromobenzene 50.0 50.5 80-120101
Methylcyclohexane 50.0 40.2 64-13080
Toluene 50.0 49.8 80-120100
Chlorobenzene 50.0 49.2 80-12098
Tetrahydrofuran 100 90.9 62-13091
Hexane 50.0 40.8 55-14382
Cyclohexane 50.0 44.2 68-12588
1,2,4-Trichlorobenzene 50.0 49.0 74-12698
Chlorodibromomethane 50.0 47.9 80-12596
Tetrachloroethene 50.0 53.1 80-121106
sec-Butylbenzene 50.0 46.7 80-12393
1,3-Dichloropropane 50.0 49.5 77-12299
cis-1,2-Dichloroethene 50.0 49.5 80-12099
trans-1,2-Dichloroethene 50.0 49.1 79-12198
Methyl tert-butyl ether 50.0 50.0 80-120100
m-Xylene & p-Xylene 50.0 48.8 80-12098
1,3-Dichlorobenzene 50.0 47.8 80-12096
Carbon tetrachloride 50.0 48.5 79-12797
1,1-Dichloropropene 50.0 47.6 77-12395
2-Hexanone 200 190 62-13795
2,2-Dichloropropane 50.0 51.4 75-131103
Ethyl ether 50.0 52.5 68-132105
1,1,1,2-Tetrachloroethane 50.0 51.4 80-124103
Acetone 200 179 61-13489
Chloroform 50.0 47.3 80-12095
Benzene 50.0 48.6 80-12097
1,1,1-Trichloroethane 50.0 49.2 80-12398
Bromomethane 50.0 48.9 29-14898
FORM III 8260D
# Column to be used to flag recovery and RPD values
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Page 145 of 777
GC/MS VOA LAB CONTROL SAMPLE RECOVERY
FORM III
Job No.:Lab Name:280-198899-1Eurofins Denver
SDG No.:
Level:Matrix:Low Lab File ID:VMS14_0000004265A.DWater
Lab ID:LCS 280-674451/4 Client ID:
REC
%
REC
QC
LIMITSCONCENTRATION
(ug/L)
SPIKE
ADDED
(ug/L)
#
LCS LCS
COMPOUND
Chloromethane 50.0 47.9 56-13396
Iodomethane 50.0 53.3 43-139107
Dibromomethane 50.0 49.6 80-12099
Chlorobromomethane 50.0 52.0 80-123104
Chloroethane 50.0 47.6 56-14195
Vinyl chloride 50.0 50.9 67-127102
Methylene Chloride 50.0 48.3 78-12097
Carbon disulfide 50.0 50.3 70-121101
Bromoform 50.0 49.5 79-13899
Dichlorobromomethane 50.0 44.9 80-12390
1,1-Dichloroethane 50.0 49.1 78-12198
1,1-Dichloroethene 50.0 51.7 77-121103
Trichlorofluoromethane 50.0 49.1 54-14498
Dichlorodifluoromethane 50.0 34.7 47-13569
1,1,2-Trichloro-1,2,2-trifluor
oethane
50.0 47.0 73-13294
1,2-Dichloropropane 50.0 47.9 78-12096
2-Butanone (MEK)200 186 58-13593
1,1,2-Trichloroethane 50.0 49.9 80-120100
Trichloroethene 50.0 48.3 80-12097
Methyl acetate 100 93.5 59-13693
1,1,2,2-Tetrachloroethane 50.0 54.2 74-123108
1,2,3-Trichlorobenzene 50.0 49.7 65-12999
Hexachlorobutadiene 50.0 48.0 73-12896
Naphthalene 50.0 45.8 60-12492
o-Xylene 50.0 46.9 80-12094
2-Chlorotoluene 50.0 48.8 80-12098
1,2-Dichlorobenzene 50.0 48.9 80-12098
1,2,4-Trimethylbenzene 50.0 46.1 79-12492
1,2-Dibromo-3-Chloropropane 50.0 51.6 73-128103
1,2,3-Trichloropropane 50.0 52.6 80-120105
Ethyl methacrylate 50.0 50.8 80-122102
tert-Butylbenzene 50.0 48.3 80-12097
Isopropylbenzene 50.0 49.6 78-12299
4-Isopropyltoluene 50.0 46.1 80-12292
FORM III 8260D
# Column to be used to flag recovery and RPD values
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3:53:55 PM
Page 146 of 777
GC/MS VOA LAB CONTROL SAMPLE RECOVERY
FORM III
Job No.:Lab Name:280-198899-1Eurofins Denver
SDG No.:
Level:Matrix:Low Lab File ID:X4_00009396a.DWater
Lab ID:LCS 280-674813/4 Client ID:
REC
%
REC
QC
LIMITSCONCENTRATION
(ug/L)
SPIKE
ADDED
(ug/L)
#
LCS LCS
COMPOUND
Ethylbenzene 50.0 51.4 80-120103
Styrene 50.0 51.7 80-120103
cis-1,3-Dichloropropene 50.0 53.7 76-129107
trans-1,3-Dichloropropene 50.0 53.8 80-123108
N-Propylbenzene 50.0 52.0 80-123104
n-Butylbenzene 50.0 50.3 59-140101
4-Chlorotoluene 50.0 50.9 80-120102
1,4-Dichlorobenzene 50.0 49.6 80-12099
Ethylene Dibromide 50.0 48.9 80-12098
3-Chloro-1-propene 50.0 55.3 65-132111
1,2-Dichloroethane 50.0 52.0 71-121104
Vinyl acetate 100 116 55-161116
4-Methyl-2-pentanone (MIBK)200 225 66-135112
1,3,5-Trimethylbenzene 50.0 51.2 80-122102
Bromobenzene 50.0 51.5 80-120103
Methylcyclohexane 50.0 49.4 64-13099
Toluene 50.0 52.2 80-120104
Chlorobenzene 50.0 51.3 80-120103
Tetrahydrofuran 100 102 62-130102
Hexane 50.0 47.5 55-14395
Cyclohexane 50.0 50.7 68-125101
1,2,4-Trichlorobenzene 50.0 44.9 74-12690
Chlorodibromomethane 50.0 54.1 80-125108
Tetrachloroethene 50.0 51.4 80-121103
sec-Butylbenzene 50.0 49.6 80-12399
1,3-Dichloropropane 50.0 51.7 77-122103
cis-1,2-Dichloroethene 50.0 51.5 80-120103
trans-1,2-Dichloroethene 50.0 52.0 79-121104
Methyl tert-butyl ether 50.0 52.0 80-120104
m-Xylene & p-Xylene 50.0 50.3 80-120101
1,3-Dichlorobenzene 50.0 50.5 80-120101
Carbon tetrachloride 50.0 53.5 79-127107
1,1-Dichloropropene 50.0 51.4 77-123103
2-Hexanone 200 210 62-137105
2,2-Dichloropropane 50.0 50.4 75-131101
Ethyl ether 50.0 49.7 68-13299
1,1,1,2-Tetrachloroethane 50.0 54.1 80-124108
Acetone 200 195 61-13497
Chloroform 50.0 52.4 80-120105
Benzene 50.0 52.2 80-120104
1,1,1-Trichloroethane 50.0 52.8 80-123106
Bromomethane 50.0 37.2 29-14874
FORM III 8260D
# Column to be used to flag recovery and RPD values
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Page 147 of 777
GC/MS VOA LAB CONTROL SAMPLE RECOVERY
FORM III
Job No.:Lab Name:280-198899-1Eurofins Denver
SDG No.:
Level:Matrix:Low Lab File ID:X4_00009396a.DWater
Lab ID:LCS 280-674813/4 Client ID:
REC
%
REC
QC
LIMITSCONCENTRATION
(ug/L)
SPIKE
ADDED
(ug/L)
#
LCS LCS
COMPOUND
Chloromethane 50.0 52.8 56-133106
Iodomethane 50.0 56.0 43-139112
Dibromomethane 50.0 47.7 80-12095
Chlorobromomethane 50.0 49.6 80-12399
Chloroethane 50.0 55.5 56-141111
Vinyl chloride 50.0 56.3 67-127113
Methylene Chloride 50.0 50.2 78-120100
Carbon disulfide 50.0 51.2 70-121102
Bromoform 50.0 53.1 79-138106
Dichlorobromomethane 50.0 54.0 80-123108
1,1-Dichloroethane 50.0 52.1 78-121104
1,1-Dichloroethene 50.0 50.2 77-121100
Trichlorofluoromethane 50.0 53.5 54-144107
Dichlorodifluoromethane 50.0 53.0 47-135106
1,1,2-Trichloro-1,2,2-trifluor
oethane
50.0 48.7 73-13297
1,2-Dichloropropane 50.0 52.6 78-120105
2-Butanone (MEK)200 204 58-135102
1,1,2-Trichloroethane 50.0 52.6 80-120105
Trichloroethene 50.0 45.9 80-12092
Methyl acetate 100 106 59-136106
1,1,2,2-Tetrachloroethane 50.0 54.5 74-123109
1,2,3-Trichlorobenzene 50.0 45.5 65-12991
Hexachlorobutadiene 50.0 51.5 73-128103
Naphthalene 50.0 40.7 60-12481
o-Xylene 50.0 51.6 80-120103
2-Chlorotoluene 50.0 50.9 80-120102
1,2-Dichlorobenzene 50.0 47.4 80-12095
1,2,4-Trimethylbenzene 50.0 50.8 79-124102
1,2-Dibromo-3-Chloropropane 50.0 47.8 73-12896
1,2,3-Trichloropropane 50.0 49.5 80-12099
Ethyl methacrylate 50.0 52.4 80-122105
tert-Butylbenzene 50.0 50.6 80-120101
Isopropylbenzene 50.0 51.4 78-122103
4-Isopropyltoluene 50.0 51.1 80-122102
FORM III 8260D
# Column to be used to flag recovery and RPD values
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3:53:55 PM
Page 148 of 777
GC/MS VOA LAB CONTROL SAMPLE DUPLICATE RECOVERY
FORM III
Job No.:Lab Name:280-198899-1Eurofins Denver
SDG No.:
Level:Matrix:Low Lab File ID:VMS14_0000004267.DWater
Lab ID:LCSD 280-674451/5 Client ID:
COMPOUND
SPIKE
ADDED CONCENTRATION %
REC
%
QC LIMITS
REC (ug/L)(ug/L)
#
LCSD LCSD
RPD RPD
50.0 47.4 20 80-120Ethylbenzene295
50.0 47.0 20 80-120Styrene394
50.0 53.6 20 76-129cis-1,3-Dichloropropene 0107
50.0 45.6 20 80-123trans-1,3-Dichloropropene 391
50.0 47.9 20 80-123N-Propylbenzene 296
50.0 39.7 20 59-140n-Butylbenzene 979
50.0 49.1 20 80-1204-Chlorotoluene 098
50.0 51.4 20 80-1201,4-Dichlorobenzene 2103
50.0 52.3 20 80-120Ethylene Dibromide 2105
50.0 44.5 20 65-1323-Chloro-1-propene 889
50.0 46.4 20 71-1211,2-Dichloroethane 093
100 96.2 23 55-161Vinyl acetate 1196
200 196 20 66-1354-Methyl-2-pentanone (MIBK)398
50.0 45.3 20 80-1221,3,5-Trimethylbenzene 491
50.0 52.0 20 80-120Bromobenzene3104
50.0 40.3 21 64-130Methylcyclohexane081
50.0 51.5 20 80-120Toluene3103
50.0 49.2 20 80-120Chlorobenzene098
100 94.7 20 62-130Tetrahydrofuran495
50.0 39.8 23 55-143Hexane380
50.0 43.4 32 68-125Cyclohexane287
50.0 51.6 20 74-1261,2,4-Trichlorobenzene 5103
50.0 47.0 20 80-125Chlorodibromomethane294
50.0 51.4 20 80-121Tetrachloroethene3103
50.0 46.2 20 80-123sec-Butylbenzene 192
50.0 50.4 20 77-1221,3-Dichloropropane 2101
50.0 48.6 20 80-120cis-1,2-Dichloroethene 297
50.0 46.7 20 79-121trans-1,2-Dichloroethene 593
50.0 50.4 20 80-120Methyl tert-butyl ether 1101
50.0 47.1 20 80-120m-Xylene & p-Xylene 494
50.0 48.6 20 80-1201,3-Dichlorobenzene 297
50.0 45.1 20 79-127Carbon tetrachloride 790
50.0 45.3 20 77-1231,1-Dichloropropene 591
200 191 21 62-1372-Hexanone 196
50.0 47.8 22 75-1312,2-Dichloropropane 796
50.0 50.0 20 68-132Ethyl ether 5100
50.0 51.9 20 80-1241,1,1,2-Tetrachloroethane 1104
200 183 21 61-134Acetone291
50.0 47.4 20 80-120Chloroform095
50.0 47.4 20 80-120Benzene295
50.0 47.3 20 80-1231,1,1-Trichloroethane 495
50.0 31.5 40 29-148Bromomethane4363 *1
FORM III 8260D
# Column to be used to flag recovery and RPD values
11/15/2024
3:53:55 PM
Page 149 of 777
GC/MS VOA LAB CONTROL SAMPLE DUPLICATE RECOVERY
FORM III
Job No.:Lab Name:280-198899-1Eurofins Denver
SDG No.:
Level:Matrix:Low Lab File ID:VMS14_0000004267.DWater
Lab ID:LCSD 280-674451/5 Client ID:
COMPOUND
SPIKE
ADDED CONCENTRATION %
REC
%
QC LIMITS
REC (ug/L)(ug/L)
#
LCSD LCSD
RPD RPD
50.0 45.5 20 56-133Chloromethane591
50.0 49.2 38 43-139Iodomethane898
50.0 51.5 20 80-120Dibromomethane4103
50.0 51.5 20 80-123Chlorobromomethane1103
50.0 36.8 30 56-141Chloroethane2574
50.0 50.0 25 67-127Vinyl chloride 2100
50.0 46.4 20 78-120Methylene Chloride 493
50.0 45.5 20 70-121Carbon disulfide 1091
50.0 47.1 20 79-138Bromoform594
50.0 44.6 20 80-123Dichlorobromomethane189
50.0 48.6 20 78-1211,1-Dichloroethane 197
50.0 50.3 21 77-1211,1-Dichloroethene 3101
50.0 47.1 28 54-144Trichlorofluoromethane494
50.0 37.3 21 47-135Dichlorodifluoromethane775
50.0 46.0 23 73-1321,1,2-Trichloro-1,2,2-trifluor
oethane
292
50.0 49.0 20 78-1201,2-Dichloropropane 298
200 195 20 58-1352-Butanone (MEK)597
50.0 51.9 20 80-1201,1,2-Trichloroethane 4104
50.0 47.5 20 80-120Trichloroethene295
100 94.1 20 59-136Methyl acetate 194
50.0 55.5 20 74-1231,1,2,2-Tetrachloroethane 2111
50.0 53.0 20 65-1291,2,3-Trichlorobenzene 6106
50.0 50.7 20 73-128Hexachlorobutadiene5101
50.0 44.5 21 60-124Naphthalene389
50.0 45.1 20 80-120o-Xylene 490
50.0 49.1 20 80-1202-Chlorotoluene 198
50.0 51.2 20 80-1201,2-Dichlorobenzene 5102
50.0 43.6 20 79-1241,2,4-Trimethylbenzene 687
50.0 53.9 21 73-1281,2-Dibromo-3-Chloropropane 4108
50.0 55.2 20 80-1201,2,3-Trichloropropane 5110
50.0 50.6 20 80-122Ethyl methacrylate 0101
50.0 47.3 20 80-120tert-Butylbenzene 295
50.0 49.0 20 78-122Isopropylbenzene198
50.0 43.7 20 80-1224-Isopropyltoluene 587
FORM III 8260D
# Column to be used to flag recovery and RPD values
11/15/2024
3:53:55 PM
Page 150 of 777
GC/MS VOA LAB CONTROL SAMPLE DUPLICATE RECOVERY
FORM III
Job No.:Lab Name:280-198899-1Eurofins Denver
SDG No.:
Level:Matrix:Low Lab File ID:X4_00009398.DWater
Lab ID:LCSD 280-674813/5 Client ID:
COMPOUND
SPIKE
ADDED CONCENTRATION %
REC
%
QC LIMITS
REC (ug/L)(ug/L)
#
LCSD LCSD
RPD RPD
50.0 51.1 20 80-120Ethylbenzene0102
50.0 51.0 20 80-120Styrene1102
50.0 52.5 20 76-129cis-1,3-Dichloropropene 2105
50.0 54.2 20 80-123trans-1,3-Dichloropropene 1108
50.0 50.8 20 80-123N-Propylbenzene 2102
50.0 48.8 20 59-140n-Butylbenzene 398
50.0 49.2 20 80-1204-Chlorotoluene 398
50.0 49.0 20 80-1201,4-Dichlorobenzene 198
50.0 48.4 20 80-120Ethylene Dibromide 197
50.0 55.8 20 65-1323-Chloro-1-propene 1112
50.0 52.6 20 71-1211,2-Dichloroethane 1105
100 112 23 55-161Vinyl acetate 4112
200 226 20 66-1354-Methyl-2-pentanone (MIBK)1113
50.0 50.3 20 80-1221,3,5-Trimethylbenzene 2101
50.0 50.4 20 80-120Bromobenzene2101
50.0 48.1 21 64-130Methylcyclohexane396
50.0 52.3 20 80-120Toluene0105
50.0 50.5 20 80-120Chlorobenzene1101
100 103 20 62-130Tetrahydrofuran1103
50.0 45.3 23 55-143Hexane591
50.0 49.6 32 68-125Cyclohexane299
50.0 44.1 20 74-1261,2,4-Trichlorobenzene 288
50.0 53.1 20 80-125Chlorodibromomethane2106
50.0 51.1 20 80-121Tetrachloroethene1102
50.0 48.5 20 80-123sec-Butylbenzene 297
50.0 51.2 20 77-1221,3-Dichloropropane 1102
50.0 50.2 20 80-120cis-1,2-Dichloroethene 2100
50.0 51.1 20 79-121trans-1,2-Dichloroethene 2102
50.0 52.7 20 80-120Methyl tert-butyl ether 1105
50.0 48.7 20 80-120m-Xylene & p-Xylene 397
50.0 49.4 20 80-1201,3-Dichlorobenzene 299
50.0 53.4 20 79-127Carbon tetrachloride 0107
50.0 51.6 20 77-1231,1-Dichloropropene 0103
200 206 21 62-1372-Hexanone 2103
50.0 49.0 22 75-1312,2-Dichloropropane 398
50.0 51.6 20 68-132Ethyl ether 4103
50.0 53.4 20 80-1241,1,1,2-Tetrachloroethane 1107
200 196 21 61-134Acetone098
50.0 53.1 20 80-120Chloroform1106
50.0 52.5 20 80-120Benzene1105
50.0 53.3 20 80-1231,1,1-Trichloroethane 1107
50.0 41.4 40 29-148Bromomethane1183
FORM III 8260D
# Column to be used to flag recovery and RPD values
11/15/2024
3:53:55 PM
Page 151 of 777
GC/MS VOA LAB CONTROL SAMPLE DUPLICATE RECOVERY
FORM III
Job No.:Lab Name:280-198899-1Eurofins Denver
SDG No.:
Level:Matrix:Low Lab File ID:X4_00009398.DWater
Lab ID:LCSD 280-674813/5 Client ID:
COMPOUND
SPIKE
ADDED CONCENTRATION %
REC
%
QC LIMITS
REC (ug/L)(ug/L)
#
LCSD LCSD
RPD RPD
50.0 53.9 20 56-133Chloromethane2108
50.0 58.3 38 43-139Iodomethane4117
50.0 48.0 20 80-120Dibromomethane196
50.0 51.4 20 80-123Chlorobromomethane4103
50.0 52.7 30 56-141Chloroethane5105
50.0 52.7 25 67-127Vinyl chloride 7105
50.0 49.8 20 78-120Methylene Chloride 1100
50.0 50.6 20 70-121Carbon disulfide 1101
50.0 50.8 20 79-138Bromoform4102
50.0 53.9 20 80-123Dichlorobromomethane0108
50.0 52.3 20 78-1211,1-Dichloroethane 0105
50.0 50.2 21 77-1211,1-Dichloroethene 0100
50.0 48.7 28 54-144Trichlorofluoromethane997
50.0 48.1 21 47-135Dichlorodifluoromethane1096
50.0 48.7 23 73-1321,1,2-Trichloro-1,2,2-trifluor
oethane
097
50.0 52.8 20 78-1201,2-Dichloropropane 0106
200 206 20 58-1352-Butanone (MEK)1103
50.0 51.7 20 80-1201,1,2-Trichloroethane 2103
50.0 47.0 20 80-120Trichloroethene294
100 107 20 59-136Methyl acetate 1107
50.0 53.7 20 74-1231,1,2,2-Tetrachloroethane 2107
50.0 43.9 20 65-1291,2,3-Trichlorobenzene 388
50.0 49.3 20 73-128Hexachlorobutadiene499
50.0 40.6 21 60-124Naphthalene081
50.0 51.6 20 80-120o-Xylene 0103
50.0 49.2 20 80-1202-Chlorotoluene 398
50.0 48.2 20 80-1201,2-Dichlorobenzene 296
50.0 50.4 20 79-1241,2,4-Trimethylbenzene 1101
50.0 48.7 21 73-1281,2-Dibromo-3-Chloropropane 297
50.0 50.2 20 80-1201,2,3-Trichloropropane 1100
50.0 50.5 20 80-122Ethyl methacrylate 4101
50.0 49.2 20 80-120tert-Butylbenzene 398
50.0 50.2 20 78-122Isopropylbenzene2100
50.0 49.8 20 80-1224-Isopropyltoluene 2100
FORM III 8260D
# Column to be used to flag recovery and RPD values
11/15/2024
3:53:55 PM
Page 152 of 777
GC/MS VOA MATRIX SPIKE RECOVERY
FORM III
Job No.:Lab Name:280-198899-1Eurofins Denver
SDG No.:
Level:Matrix:Low Lab File ID:VMS14_0000004290.DWater
Lab ID:280-198899-3 MS Client ID:MW-63-241030 MS
LIMITS
COMPOUND
CONCENTRATION %
REC
QC
REC
SAMPLE
CONCENTRATION
SPIKE
ADDED
(ug/L)(ug/L)(ug/L)
#
MS MS
25.0 23.6 80-120Ethylbenzene94ND
25.0 23.6 80-120Styrene95ND
25.0 24.7 76-129cis-1,3-Dichloropropene 99ND
25.0 18.9 80-123trans-1,3-Dichloropropene 76ND F1
25.0 20.9 80-123N-Propylbenzene 83ND
25.0 13.2 59-140n-Butylbenzene 53ND F1
25.0 22.9 80-1204-Chlorotoluene 91ND
25.0 23.2 80-1201,4-Dichlorobenzene 93ND
25.0 25.0 80-120Ethylene Dibromide 100ND
25.0 20.8 65-1323-Chloro-1-propene 83ND
25.0 21.8 71-1211,2-Dichloroethane 87ND
50.0 47.8 55-161Vinyl acetate 96ND
100 91.3 66-1354-Methyl-2-pentanone (MIBK)91ND
25.0 20.4 80-1221,3,5-Trimethylbenzene 81ND
25.0 24.5 80-120Bromobenzene98ND
25.0 13.4 64-130Methylcyclohexane54ND F1
25.0 24.1 80-120Toluene96ND
25.0 24.5 80-120Chlorobenzene98ND
50.0 44.5 62-130Tetrahydrofuran89ND
25.0 13.5 55-143Hexane54ND F1
25.0 18.8 68-125Cyclohexane75ND
25.0 17.5 74-1261,2,4-Trichlorobenzene 70ND F1
25.0 21.4 80-125Chlorodibromomethane86ND
25.0 25.5 80-121Tetrachloroethene102ND
25.0 16.2 80-123sec-Butylbenzene 65ND F1
25.0 24.4 77-1221,3-Dichloropropane 97ND
25.0 24.0 80-120cis-1,2-Dichloroethene 96ND
25.0 24.5 79-121trans-1,2-Dichloroethene 98ND
25.0 24.2 80-120Methyl tert-butyl ether 97ND
25.0 24.6 80-120m-Xylene & p-Xylene 98ND
25.0 21.5 80-1201,3-Dichlorobenzene 86ND
25.0 21.9 79-127Carbon tetrachloride 88ND
25.0 22.8 77-1231,1-Dichloropropene 91ND
100 96.9 62-1372-Hexanone 97ND
25.0 21.6 75-1312,2-Dichloropropane 86ND
25.0 24.6 68-132Ethyl ether 98ND
25.0 24.5 80-1241,1,1,2-Tetrachloroethane 98ND
100 87.2 61-134Acetone87ND
25.0 23.3 80-120Chloroform93ND
25.0 23.9 80-120Benzene96ND
25.0 23.4 80-1231,1,1-Trichloroethane 94ND
25.0 27.0 29-148Bromomethane108ND
FORM III 8260D
# Column to be used to flag recovery and RPD values
11/15/2024
3:53:55 PM
Page 153 of 777
GC/MS VOA MATRIX SPIKE RECOVERY
FORM III
Job No.:Lab Name:280-198899-1Eurofins Denver
SDG No.:
Level:Matrix:Low Lab File ID:VMS14_0000004290.DWater
Lab ID:280-198899-3 MS Client ID:MW-63-241030 MS
LIMITS
COMPOUND
CONCENTRATION %
REC
QC
REC
SAMPLE
CONCENTRATION
SPIKE
ADDED
(ug/L)(ug/L)(ug/L)
#
MS MS
25.0 24.9 56-133Chloromethane100ND
25.0 27.8 43-139Iodomethane111ND
25.0 22.9 80-120Dibromomethane92ND
25.0 25.7 80-123Chlorobromomethane103ND
25.0 23.8 56-141Chloroethane95ND
25.0 24.2 67-127Vinyl chloride 97ND
25.0 23.9 78-120Methylene Chloride 96ND
25.0 23.3 70-121Carbon disulfide 93ND
25.0 20.6 79-138Bromoform82ND
25.0 20.1 80-123Dichlorobromomethane80ND
25.0 24.1 78-1211,1-Dichloroethane 97ND
25.0 23.2 77-1211,1-Dichloroethene 93ND
25.0 22.7 54-144Trichlorofluoromethane91ND
25.0 20.3 47-135Dichlorodifluoromethane81ND
25.0 23.8 73-1321,1,2-Trichloro-1,2,2-trifluor
oethane
95ND
25.0 23.2 78-1201,2-Dichloropropane 93ND
100 87.8 58-1352-Butanone (MEK)88ND
25.0 24.0 80-1201,1,2-Trichloroethane 96ND
25.0 24.0 80-120Trichloroethene96ND
50.0 42.5 59-136Methyl acetate 85ND
25.0 27.0 74-1231,1,2,2-Tetrachloroethane 108ND
25.0 18.1 65-1291,2,3-Trichlorobenzene 73ND
25.0 6.79 73-128Hexachlorobutadiene27ND F1
25.0 22.2 60-124Naphthalene89ND
25.0 23.9 80-120o-Xylene 96ND
25.0 22.8 80-1202-Chlorotoluene 91ND
25.0 23.1 80-1201,2-Dichlorobenzene 92ND
25.0 20.3 79-1241,2,4-Trimethylbenzene 81ND
25.0 24.6 73-1281,2-Dibromo-3-Chloropropane 98ND
25.0 25.9 80-1201,2,3-Trichloropropane 104ND
25.0 24.4 80-122Ethyl methacrylate 97ND
25.0 18.7 80-120tert-Butylbenzene 75ND F1
25.0 21.5 78-122Isopropylbenzene86ND
25.0 16.8 80-1224-Isopropyltoluene 67ND F1
FORM III 8260D
# Column to be used to flag recovery and RPD values
11/15/2024
3:53:55 PM
Page 154 of 777
GC/MS VOA MATRIX SPIKE DUPLICATE RECOVERY
FORM III
Job No.:Lab Name:280-198899-1Eurofins Denver
SDG No.:
Level:Matrix:Low Lab File ID:VMS14_0000004291.DWater
Lab ID:280-198899-3 MSD Client ID:MW-63-241030 MSD
COMPOUND
SPIKE
ADDED CONCENTRATION %
REC
%
QC LIMITS
REC (ug/L)(ug/L)
#
MSD MSD
RPD RPD
25.0 24.2 20 80-120Ethylbenzene297
25.0 24.9 20 80-120Styrene5100
25.0 26.6 20 76-129cis-1,3-Dichloropropene 7106
25.0 20.9 20 80-123trans-1,3-Dichloropropene 1084
25.0 20.7 20 80-123N-Propylbenzene 183
25.0 13.0 20 59-140n-Butylbenzene 152 F1
25.0 23.1 20 80-1204-Chlorotoluene 192
25.0 23.6 20 80-1201,4-Dichlorobenzene 294
25.0 26.4 20 80-120Ethylene Dibromide 5105
25.0 23.2 20 65-1323-Chloro-1-propene 1193
25.0 24.0 20 71-1211,2-Dichloroethane 1096
50.0 52.8 23 55-161Vinyl acetate 10106
100 98.3 20 66-1354-Methyl-2-pentanone (MIBK)798
25.0 20.5 20 80-1221,3,5-Trimethylbenzene 182
25.0 25.3 20 80-120Bromobenzene3101
25.0 13.3 21 64-130Methylcyclohexane053 F1
25.0 25.9 20 80-120Toluene7104
25.0 25.3 20 80-120Chlorobenzene3101
50.0 48.4 20 62-130Tetrahydrofuran897
25.0 13.6 23 55-143Hexane155
25.0 19.9 32 68-125Cyclohexane679
25.0 17.2 20 74-1261,2,4-Trichlorobenzene 269 F1
25.0 23.1 20 80-125Chlorodibromomethane792
25.0 26.5 20 80-121Tetrachloroethene4106
25.0 16.2 20 80-123sec-Butylbenzene 065 F1
25.0 25.2 20 77-1221,3-Dichloropropane 3101
25.0 26.6 20 80-120cis-1,2-Dichloroethene 10106
25.0 26.8 20 79-121trans-1,2-Dichloroethene 9107
25.0 26.5 20 80-120Methyl tert-butyl ether 9106
25.0 25.3 20 80-120m-Xylene & p-Xylene 3101
25.0 21.8 20 80-1201,3-Dichlorobenzene 187
25.0 24.9 20 79-127Carbon tetrachloride 13100
25.0 24.2 20 77-1231,1-Dichloropropene 697
100 102 21 62-1372-Hexanone 5102
25.0 24.0 22 75-1312,2-Dichloropropane 1196
25.0 26.8 20 68-132Ethyl ether 9107
25.0 26.0 20 80-1241,1,1,2-Tetrachloroethane 6104
100 96.3 21 61-134Acetone1096
25.0 26.1 20 80-120Chloroform11104
25.0 26.2 20 80-120Benzene9105
25.0 25.2 20 80-1231,1,1-Trichloroethane 7101
25.0 29.3 40 29-148Bromomethane8117
FORM III 8260D
# Column to be used to flag recovery and RPD values
11/15/2024
3:53:55 PM
Page 155 of 777
GC/MS VOA MATRIX SPIKE DUPLICATE RECOVERY
FORM III
Job No.:Lab Name:280-198899-1Eurofins Denver
SDG No.:
Level:Matrix:Low Lab File ID:VMS14_0000004291.DWater
Lab ID:280-198899-3 MSD Client ID:MW-63-241030 MSD
COMPOUND
SPIKE
ADDED CONCENTRATION %
REC
%
QC LIMITS
REC (ug/L)(ug/L)
#
MSD MSD
RPD RPD
25.0 27.6 20 56-133Chloromethane10110
25.0 31.7 38 43-139Iodomethane13127
25.0 25.1 20 80-120Dibromomethane9100
25.0 28.2 20 80-123Chlorobromomethane9113
25.0 26.7 30 56-141Chloroethane11107
25.0 26.6 25 67-127Vinyl chloride 10107
25.0 25.8 20 78-120Methylene Chloride 8103
25.0 26.6 20 70-121Carbon disulfide 13106
25.0 22.3 20 79-138Bromoform889
25.0 22.5 20 80-123Dichlorobromomethane1190
25.0 26.6 20 78-1211,1-Dichloroethane 10106
25.0 25.3 21 77-1211,1-Dichloroethene 9101
25.0 24.6 28 54-144Trichlorofluoromethane898
25.0 22.4 21 47-135Dichlorodifluoromethane1089
25.0 25.4 23 73-1321,1,2-Trichloro-1,2,2-trifluor
oethane
6101
25.0 25.2 20 78-1201,2-Dichloropropane 8101
100 98.1 20 58-1352-Butanone (MEK)1198
25.0 24.8 20 80-1201,1,2-Trichloroethane 399
25.0 24.8 20 80-120Trichloroethene399
50.0 46.6 20 59-136Methyl acetate 993
25.0 27.4 20 74-1231,1,2,2-Tetrachloroethane 2110
25.0 17.5 20 65-1291,2,3-Trichlorobenzene 370
25.0 6.45 20 73-128Hexachlorobutadiene526 F1
25.0 22.2 21 60-124Naphthalene089
25.0 24.6 20 80-120o-Xylene 398
25.0 22.9 20 80-1202-Chlorotoluene 092
25.0 23.3 20 80-1201,2-Dichlorobenzene 193
25.0 20.9 20 79-1241,2,4-Trimethylbenzene 384
25.0 24.9 21 73-1281,2-Dibromo-3-Chloropropane 1100
25.0 26.9 20 80-1201,2,3-Trichloropropane 4107
25.0 25.7 20 80-122Ethyl methacrylate 5103
25.0 18.6 20 80-120tert-Butylbenzene 075 F1
25.0 21.7 20 78-122Isopropylbenzene187
25.0 16.5 20 80-1224-Isopropyltoluene 266 F1
FORM III 8260D
# Column to be used to flag recovery and RPD values
11/15/2024
3:53:55 PM
Page 156 of 777
FORM IV
GC/MS VOA METHOD BLANK SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Date Analyzed:
GC Column:ID:
Instrument ID:11/11/2024 06:40
DB-624 (60.25)
NHeated Purge:(Y/N)
VMS_MS14
VMS14_0000004270.DLab File ID:Lab Sample ID:MB 280-674451/9
WaterMatrix:
0.25(mm)
THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES:
LAB SAMPLE ID
LAB
FILE ID DATE ANALYZEDCLIENT SAMPLE ID
11/11/2024 05:00VMS14_00000
04265A.D
LCS 280-674451/4
11/11/2024 05:40VMS14_00000
04267.D
LCSD 280-674451/5
11/11/2024 08:04VMS14_00000
04274.D
280-198899-6Trip Blank
11/11/2024 08:24VMS14_00000
04275.D
280-198899-4FB-01
11/11/2024 09:25VMS14_00000
04278.D
280-198899-3MW-63-241030
11/11/2024 11:50VMS14_00000
04285.D
280-198899-5DS-01
11/11/2024 12:12VMS14_00000
04286.D
280-198899-2MW-61-241030
11/11/2024 13:37VMS14_00000
04290.D
280-198899-3 MSMW-63-241030 MS
11/11/2024 13:57VMS14_00000
04291.D
280-198899-3 MSDMW-63-241030 MSD
FORM IV 8260D
11/15/2024
3:53:55 PM
Page 157 of 777
FORM IV
GC/MS VOA METHOD BLANK SUMMARY
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Date Analyzed:
GC Column:ID:
Instrument ID:11/13/2024 09:05
RXI-624SilMS
NHeated Purge:(Y/N)
VMS_X4
X4_00009401.DLab File ID:Lab Sample ID:MB 280-674813/9
WaterMatrix:
0.25(mm)
THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES:
LAB SAMPLE ID
LAB
FILE ID DATE ANALYZEDCLIENT SAMPLE ID
11/13/2024 07:20X4_00009396
a.D
LCS 280-674813/4
11/13/2024 08:02X4_00009398
.D
LCSD 280-674813/5
11/13/2024 15:34X4_00009419
.D
280-198899-5 DLDS-01 DL
FORM IV 8260D
11/15/2024
3:53:55 PM
Page 158 of 777
FORM V
BROMOFLUOROBENZENE (BFB)
Lab Name:Job No.:
GC/MS VOA INSTRUMENT PERFORMANCE CHECK
Eurofins Denver 280-198899-1
Lab File ID:
Instrument ID:
VMS14_0000000565.D
VMS_MS14
08/14/2024
16:57
BFB Injection Date:
BFB Injection Time:
M/E ION ABUNDANCE CRITERIA % RELATIVE
ABUNDANCE
Analysis Batch No.:664080
50 15.0 - 40.0 % of mass 95 17.1
75 30.0 - 60.0 % of mass 95 48.6
95 Base Peak, 100% relative abundance 100.0
96 5.0 - 9.0 % of mass 95 6.8
173 Less than 2.0 % of mass 174 0.0 (0.0)1
174 Greater than 50% of mass 95 83.8
175 5.0 - 9.0 % of mass 174 6.2 (7.4)1
176 95.0 - 101.0 % of mass 174 81.8 (97.6)1
177 5.0 - 9.0 % of mass 176 5.5 (6.8)2
1-Value is % mass 174 2-Value is % mass 176
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS:
SDG No.:
CLIENT SAMPLE ID LAB
FILE IDLAB SAMPLE ID DATE
ANALYZED
TIME
ANALYZED
ICV 280-664080/57 VMS14_0000000589.D08/15/2024 1:28
FORM V 8260D 11/15/2024
3:53:55 PM
Page 159 of 777
FORM V
BROMOFLUOROBENZENE (BFB)
Lab Name:Job No.:
GC/MS VOA INSTRUMENT PERFORMANCE CHECK
Eurofins Denver 280-198899-1
Lab File ID:
Instrument ID:
VMS14_0000003771.D
VMS_MS14
10/29/2024
16:42
BFB Injection Date:
BFB Injection Time:
M/E ION ABUNDANCE CRITERIA % RELATIVE
ABUNDANCE
Analysis Batch No.:672942
50 15.0 - 40.0 % of mass 95 17.2
75 30.0 - 60.0 % of mass 95 47.3
95 Base Peak, 100% relative abundance 100.0
96 5.0 - 9.0 % of mass 95 6.9
173 Less than 2.0 % of mass 174 0.0 (0.0)1
174 Greater than 50% of mass 95 71.6
175 5.0 - 9.0 % of mass 174 5.5 (7.6)1
176 95.0 - 101.0 % of mass 174 69.5 (97.0)1
177 5.0 - 9.0 % of mass 176 4.8 (6.9)2
1-Value is % mass 174 2-Value is % mass 176
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS:
SDG No.:
CLIENT SAMPLE ID LAB
FILE IDLAB SAMPLE ID DATE
ANALYZED
TIME
ANALYZED
IC 280-672942/36 VMS14_0000003772.D10/29/2024 17:02
IC 280-672942/37 VMS14_0000003773.D10/29/2024 17:22
IC 280-672942/38 VMS14_0000003774.D10/29/2024 17:42
ICIS 280-672942/39 VMS14_0000003775.D10/29/2024 18:02
IC 280-672942/40 VMS14_0000003776.D10/29/2024 18:22
IC 280-672942/41 VMS14_0000003777.D10/29/2024 18:42
IC 280-672942/42 VMS14_0000003778.D10/29/2024 19:02
IC 280-672942/43 VMS14_0000003779.D10/29/2024 19:22
IC 280-672942/44 VMS14_0000003780.D10/29/2024 19:42
ICV 280-672942/45 VMS14_0000003781.D10/29/2024 20:02
FORM V 8260D 11/15/2024
3:53:55 PM
Page 160 of 777
FORM V
BROMOFLUOROBENZENE (BFB)
Lab Name:Job No.:
GC/MS VOA INSTRUMENT PERFORMANCE CHECK
Eurofins Denver 280-198899-1
Lab File ID:
Instrument ID:
VMS14_0000004264A.D
VMS_MS14
11/11/2024
04:41
BFB Injection Date:
BFB Injection Time:
M/E ION ABUNDANCE CRITERIA % RELATIVE
ABUNDANCE
Analysis Batch No.:674451
50 15.0 - 40.0 % of mass 95 15.7
75 30.0 - 60.0 % of mass 95 45.4
95 Base Peak, 100% relative abundance 100.0
96 5.0 - 9.0 % of mass 95 6.6
173 Less than 2.0 % of mass 174 0.0 (0.0)1
174 Greater than 50% of mass 95 79.6
175 5.0 - 9.0 % of mass 174 5.8 (7.3)1
176 95.0 - 101.0 % of mass 174 78.2 (98.2)1
177 5.0 - 9.0 % of mass 176 5.1 (6.6)2
1-Value is % mass 174 2-Value is % mass 176
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS:
SDG No.:
CLIENT SAMPLE ID LAB
FILE IDLAB SAMPLE ID DATE
ANALYZED
TIME
ANALYZED
CCV 280-674451/2 VMS14_0000004265.D11/11/2024 5:00
LCS 280-674451/4 VMS14_0000004265A.D11/11/2024 5:00
LCSD 280-674451/5 VMS14_0000004267.D11/11/2024 5:40
MB 280-674451/9 VMS14_0000004270.D11/11/2024 6:40
Trip Blank 280-198899-6 VMS14_0000004274.D11/11/2024 8:04
FB-01 280-198899-4 VMS14_0000004275.D11/11/2024 8:24
MW-63-241030 280-198899-3 VMS14_0000004278.D11/11/2024 9:25
DS-01 280-198899-5 VMS14_0000004285.D11/11/2024 11:50
MW-61-241030 280-198899-2 VMS14_0000004286.D11/11/2024 12:12
MW-63-241030 MS 280-198899-3 MS VMS14_0000004290.D11/11/2024 13:37
MW-63-241030 MSD 280-198899-3 MSD VMS14_0000004291.D11/11/2024 13:57
FORM V 8260D 11/15/2024
3:53:55 PM
Page 161 of 777
FORM V
BROMOFLUOROBENZENE (BFB)
Lab Name:Job No.:
GC/MS VOA INSTRUMENT PERFORMANCE CHECK
Eurofins Denver 280-198899-1
Lab File ID:
Instrument ID:
X4_00006833.D
VMS_X4
09/23/2024
06:22
BFB Injection Date:
BFB Injection Time:
M/E ION ABUNDANCE CRITERIA % RELATIVE
ABUNDANCE
Analysis Batch No.:668235
50 15.0 - 40.0 % of mass 95 24.1
75 30.0 - 60.0 % of mass 95 52.3
95 Base Peak, 100% relative abundance 100.0
96 5.0 - 9.0 % of mass 95 6.8
173 Less than 2.0 % of mass 174 0.0 (0.0)1
174 Greater than 50% of mass 95 63.3
175 5.0 - 9.0 % of mass 174 4.4 (7.0)1
176 95.0 - 101.0 % of mass 174 63.0 (99.4)1
177 5.0 - 9.0 % of mass 176 3.9 (6.1)2
1-Value is % mass 174 2-Value is % mass 176
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS:
SDG No.:
CLIENT SAMPLE ID LAB
FILE IDLAB SAMPLE ID DATE
ANALYZED
TIME
ANALYZED
ICV 280-668235/21 X4_00006851.D 09/23/2024 14:12
FORM V 8260D 11/15/2024
3:53:55 PM
Page 162 of 777
FORM V
BROMOFLUOROBENZENE (BFB)
Lab Name:Job No.:
GC/MS VOA INSTRUMENT PERFORMANCE CHECK
Eurofins Denver 280-198899-1
Lab File ID:
Instrument ID:
X4_00008660.D
VMS_X4
10/29/2024
16:50
BFB Injection Date:
BFB Injection Time:
M/E ION ABUNDANCE CRITERIA % RELATIVE
ABUNDANCE
Analysis Batch No.:672931
50 15.0 - 40.0 % of mass 95 24.7
75 30.0 - 60.0 % of mass 95 55.1
95 Base Peak, 100% relative abundance 100.0
96 5.0 - 9.0 % of mass 95 6.5
173 Less than 2.0 % of mass 174 0.4 (0.5)1
174 Greater than 50% of mass 95 76.1
175 5.0 - 9.0 % of mass 174 6.2 (8.1)1
176 95.0 - 101.0 % of mass 174 73.4 (96.5)1
177 5.0 - 9.0 % of mass 176 4.9 (6.7)2
1-Value is % mass 174 2-Value is % mass 176
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS:
SDG No.:
CLIENT SAMPLE ID LAB
FILE IDLAB SAMPLE ID DATE
ANALYZED
TIME
ANALYZED
IC 280-672931/35 X4_00008661.D 10/29/2024 17:11
IC 280-672931/36 X4_00008662.D 10/29/2024 17:32
IC 280-672931/37 X4_00008663.D 10/29/2024 17:53
ICIS 280-672931/38 X4_00008664.D 10/29/2024 18:14
IC 280-672931/39 X4_00008665.D 10/29/2024 18:35
IC 280-672931/40 X4_00008666.D 10/29/2024 18:56
IC 280-672931/41 X4_00008667.D 10/29/2024 19:17
IC 280-672931/42 X4_00008668.D 10/29/2024 19:38
IC 280-672931/43 X4_00008669.D 10/29/2024 20:00
ICV 280-672931/44 X4_00008670.D 10/29/2024 20:20
FORM V 8260D 11/15/2024
3:53:55 PM
Page 163 of 777
FORM V
BROMOFLUOROBENZENE (BFB)
Lab Name:Job No.:
GC/MS VOA INSTRUMENT PERFORMANCE CHECK
Eurofins Denver 280-198899-1
Lab File ID:
Instrument ID:
X4_00009394.D
VMS_X4
11/13/2024
06:26
BFB Injection Date:
BFB Injection Time:
M/E ION ABUNDANCE CRITERIA % RELATIVE
ABUNDANCE
Analysis Batch No.:674813
50 15.0 - 40.0 % of mass 95 26.9
75 30.0 - 60.0 % of mass 95 53.7
95 Base Peak, 100% relative abundance 100.0
96 5.0 - 9.0 % of mass 95 6.7
173 Less than 2.0 % of mass 174 0.3 (0.4)1
174 Greater than 50% of mass 95 77.3
175 5.0 - 9.0 % of mass 174 6.1 (7.9)1
176 95.0 - 101.0 % of mass 174 75.2 (97.3)1
177 5.0 - 9.0 % of mass 176 4.5 (6.0)2
1-Value is % mass 174 2-Value is % mass 176
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS:
SDG No.:
CLIENT SAMPLE ID LAB
FILE IDLAB SAMPLE ID DATE
ANALYZED
TIME
ANALYZED
CCV 280-674813/2 X4_00009396.D 11/13/2024 7:20
LCS 280-674813/4 X4_00009396a.D 11/13/2024 7:20
LCSD 280-674813/5 X4_00009398.D 11/13/2024 8:02
MB 280-674813/9 X4_00009401.D 11/13/2024 9:05
DS-01 DL 280-198899-5 DL X4_00009419.D 11/13/2024 15:34
FORM V 8260D 11/15/2024
3:53:55 PM
Page 164 of 777
GC/MS VOA INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY
Lab Name:Job No.:
FORM VIII
Eurofins Denver 280-198899-1
SDG No.:
Sample No.:ICIS 280-672942/39 Date Analyzed:10/29/2024 18:02
Lab File ID (Standard):VMS14_0000003775.D
Instrument ID:VMS_MS14 GC Column:DB-624 (60.25)ID:0.25(mm)
Heated Purge: (Y/N)N
Calibration ID:98519
#RT #RT ##RT ##
FB CBNZd5 DCBd4
AREA AREA AREA
UPPER LIMIT
LOWER LIMIT
2732752
683188 191513
766050
342991
1371964
5.36 7.93 10.18INITIAL CALIBRATION MID-POINT
5.53
5.19
8.10
7.76
10.34
10.01
1366376 383025 685982
LAB SAMPLE ID CLIENT SAMPLE ID
ICV 280-672942/45 1457983 390849 678653 5.36 7.93 10.17
CCV 280-674451/2 1143144 303107 502015 5.36 7.93 10.17
LCS 280-674451/4 1143243 303107 502015 5.36 7.93 10.17
LCSD 280-674451/5 993484 267646 429107 5.36 7.93 10.17
MB 280-674451/9 1132550 272467 505850 5.36 7.93 10.17
280-198899-6 Trip Blank 1135748 260603 465226 5.36 7.93 10.17
280-198899-4 FB-01 999067 235129 437738 5.36 7.93 10.17
280-198899-3 MW-63-241030 1111633 266851 476625 5.36 7.93 10.17
280-198899-5 DS-01 1035611 250417 449271 5.36 7.93 10.18
280-198899-2 MW-61-241030 1043699 243514 421795 5.36 7.93 10.17
280-198899-3 MS MW-63-241030 MS 925276 233855 400939 5.36 7.93 10.17
280-198899-3 MSD MW-63-241030 MSD 910256 235709 416980 5.36 7.93 10.17
FB = Fluorobenzene
CBNZd5 = Chlorobenzene-d5
DCBd4 = 1,4-Dichlorobenzene-d4
Area Limit = 50%-200% of internal standard area
RT Limit = ± 0.167 minutes of internal standard RT
# Column used to flag values outside QC limits
FORM VIII 8260D 11/15/2024
3:53:55 PM
Page 165 of 777
GC/MS VOA INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY
Lab Name:Job No.:
FORM VIII
Eurofins Denver 280-198899-1
SDG No.:
Sample No.:ICIS 280-672931/38 Date Analyzed:10/29/2024 18:14
Lab File ID (Standard):X4_00008664.D
Instrument ID:VMS_X4 GC Column:RXI-624SilMS ID:0.25(mm)
Heated Purge: (Y/N)N
Calibration ID:98520
#RT #RT ##RT ##
FB CBNZd5 DCBd4
AREA AREA AREA
UPPER LIMIT
LOWER LIMIT
3323374
830844 176465
705858
272853
1091410
5.21 7.74 9.97INITIAL CALIBRATION MID-POINT
5.37
5.04
7.90
7.57
10.13
9.80
1661687 352929 545705
LAB SAMPLE ID CLIENT SAMPLE ID
ICV 280-672931/44 1652351 357229 572254 5.21 7.74 9.96
CCV 280-674813/2 1545225 343434 544351 5.21 7.74 9.96
LCS 280-674813/4 1545225 343434 544351 5.21 7.74 9.96
LCSD 280-674813/5 1565133 355259 559253 5.21 7.74 9.96
MB 280-674813/9 1576195 341886 554133 5.21 7.74 9.96
280-198899-5 DL DS-01 DL 1481638 329468 512762 5.21 7.74 9.96
FB = Fluorobenzene
CBNZd5 = Chlorobenzene-d5
DCBd4 = 1,4-Dichlorobenzene-d4
Area Limit = 50%-200% of internal standard area
RT Limit = ± 0.167 minutes of internal standard RT
# Column used to flag values outside QC limits
FORM VIII 8260D 11/15/2024
3:53:55 PM
Page 166 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:MW-61-241030 Lab Sample ID:280-198899-2
Matrix:VMS14_0000004286.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
10/30/2024 11:10
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:50
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 12:12
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
50 7.2100-41-4 Ethylbenzene ND
50 6.3100-42-5 Styrene ND
50 7.810061-01-5 cis-1,3-Dichloropropene ND
50 7.210061-02-6 trans-1,3-Dichloropropene ND
50 9.2103-65-1 N-Propylbenzene ND
50 12104-51-8 n-Butylbenzene ND
50 11106-43-4 4-Chlorotoluene ND
50 19106-46-7 1,4-Dichlorobenzene ND
50 9.2106-93-4 Ethylene Dibromide ND
100 23107-05-1 3-Chloro-1-propene ND
50 14107-06-2 1,2-Dichloroethane ND
150 18108-05-4 Vinyl acetate ND
250 49108-10-1 4-Methyl-2-pentanone (MIBK)ND
50 6.1108-67-8 1,3,5-Trimethylbenzene ND
50 9.5108-86-1 Bromobenzene ND
50 16108-87-2 Methylcyclohexane ND
50 16J108-88-3 Toluene 33
50 4.6108-90-7 Chlorobenzene ND
350 42109-99-9 Tetrahydrofuran ND
100 8.2110-54-3 Hexane ND
50 22110-82-7 Cyclohexane ND
50 29120-82-1 1,2,4-Trichlorobenzene ND
50 14124-48-1 Chlorodibromomethane ND
50 20127-18-4 Tetrachloroethene ND
50 10135-98-8 sec-Butylbenzene ND
50 8.7142-28-9 1,3-Dichloropropane ND
50 16156-59-2 cis-1,2-Dichloroethene ND
50 18156-60-5 trans-1,2-Dichloroethene ND
250 131634-04-4 Methyl tert-butyl ether ND
100 18179601-23-1 m-Xylene & p-Xylene ND
50 17541-73-1 1,3-Dichlorobenzene ND
50 1156-23-5 Carbon tetrachloride ND
FORM I 8260D
11/15/2024
3:53:55 PM
Page 167 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:MW-61-241030 Lab Sample ID:280-198899-2
Matrix:VMS14_0000004286.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
10/30/2024 11:10
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:50
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 12:12
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
50 9.5563-58-6 1,1-Dichloropropene ND
250 41591-78-6 2-Hexanone ND
50 8.4594-20-7 2,2-Dichloropropane ND
100 1860-29-7 Ethyl ether ND
50 7.8630-20-6 1,1,1,2-Tetrachloroethane ND
750 33067-64-1 Acetone ND
50 1867-66-3 Chloroform ND
50 7.271-43-2 Benzene ND
50 2071-55-6 1,1,1-Trichloroethane ND
250 120*174-83-9 Bromomethane ND
100 1174-87-3 Chloromethane ND
250 13074-88-4 Iodomethane ND
50 1774-95-3 Dibromomethane ND
50 2074-97-5 Chlorobromomethane ND
100 3275-00-3 Chloroethane ND
50 1175-01-4 Vinyl chloride ND
100 4775-09-2 Methylene Chloride ND
100 1375-15-0 Carbon disulfide ND
100 1275-25-2 Bromoform ND
50 9.475-27-4 Dichlorobromomethane ND
50 11J75-34-3 1,1-Dichloroethane 44
50 1275-35-4 1,1-Dichloroethene ND
100 9.975-69-4 Trichlorofluoromethane ND
100 1575-71-8 Dichlorodifluoromethane ND
150 3676-13-1 1,1,2-Trichloro-1,2,2-trifluoroethan
e
9900
50 1278-87-5 1,2-Dichloropropane 180
500 23078-93-3 2-Butanone (MEK)ND
50 1479-00-5 1,1,2-Trichloroethane ND
50 1579-01-6 Trichloroethene ND
250 8279-20-9 Methyl acetate ND
50 1179-34-5 1,1,2,2-Tetrachloroethane ND
200 6087-61-6 1,2,3-Trichlorobenzene ND
FORM I 8260D
11/15/2024
3:53:55 PM
Page 168 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:MW-61-241030 Lab Sample ID:280-198899-2
Matrix:VMS14_0000004286.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
10/30/2024 11:10
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:50
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 12:12
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
100 2687-68-3 Hexachlorobutadiene ND
150 5091-20-3 Naphthalene ND
50 5.7J95-47-6 o-Xylene 8.9
50 1795-49-8 2-Chlorotoluene ND
50 7.295-50-1 1,2-Dichlorobenzene ND
50 7.595-63-6 1,2,4-Trimethylbenzene ND
250 2196-12-8 1,2-Dibromo-3-Chloropropane ND
130 1496-18-4 1,2,3-Trichloropropane ND
150 9.697-63-2 Ethyl methacrylate ND
50 8.998-06-6 tert-Butylbenzene ND
50 7.998-82-8 Isopropylbenzene ND
50 9.399-87-6 4-Isopropyltoluene ND
50 5.7J1330-20-7 Xylenes, Total 8.9
50 16540-59-0 1,2-Dichloroethene, Total ND
50 7.2542-75-6 1,3-Dichloropropene, Total ND
50 9.4STL00209Trihalomethanes, Total ND
50 7.2JSTL00431Total BTEX 42
%RECCAS NO.LIMITSQSURROGATE
91 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr)
93 77-1201868-53-7 Dibromofluoromethane (Surr)
108 80-1252037-26-5 Toluene-d8 (Surr)
94 78-120460-00-4 4-Bromofluorobenzene (Surr)
FORM I 8260D
11/15/2024
3:53:55 PM
Page 169 of 777
Report Date: 11-Nov-2024 17:30:23 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004286.D
Lims ID:280-198899-B-2
Client ID:MW-61-241030
Sample Type:Client
Inject. Date:11-Nov-2024 12:12:40 ALS Bottle#:0 Worklist Smp#:28
Purge Vol: 5.000 mL Dil. Factor:50.0000
Sample Info:280-198899-B-2 50x
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:11-Nov-2024 17:30:16 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:11-Nov-2024 17:30:16
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.357 0.003 99 1043699 50.0
* 2 Chlorobenzene-d5 119 7.929 7.926 0.003 85 243514 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.173 0.000 95 421795 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.839 4.839 0.000 94 235498 46.6
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 97 287993 45.6
$ 6 Toluene-d8 (Surr) 98 6.636 6.637 -0.001 93 1040536 54.2
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 90 378922 46.9
10 Dichlorodifluoromethane 85 1.791 ND U
12 Chloromethane 50 1.974 ND
13 Vinyl chloride 62 2.090 ND
15 Bromomethane 94 2.389 ND
16 Chloroethane 64 2.489 ND
18 Trichlorofluoromethane 101 2.711 ND
21 Ethyl ether 59 2.936 ND
25 1,1-Dichloroethene 96 3.138 ND U
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.145 3.141 0.004 94 510056 198.0
26 Acetone 43 3.164 ND
29 Iodomethane 142 3.267 ND
30 Carbon disulfide 76 3.334 ND
32 Methyl acetate 43 3.399 ND
33 3-Chloro-1-propene 41 3.418 ND
34 Methylene Chloride 84 3.518 ND
37 Methyl tert-butyl ether 73 3.714 ND
38 trans-1,2-Dichloroethene 96 3.727 ND
39 Hexane 57 3.929 ND
40 Vinyl acetate 43 4.032 ND
42 1,1-Dichloroethane 63 4.061 4.055 0.006 92 6248 0.8704 M
45 2-Butanone (MEK) 43 4.456 ND
47 cis-1,2-Dichloroethene 96 4.482 ND
48 2,2-Dichloropropane 77 4.495 ND
52 Chlorobromomethane 128 4.662 ND
53 Tetrahydrofuran 42 4.678 ND
11/15/2024
3:53:55 PM
Page 170 of 777
Report Date: 11-Nov-2024 17:30:23 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004286.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
54 Chloroform 83 4.720 ND
55 1,1,1-Trichloroethane 97 4.871 ND
56 Cyclohexane 56 4.936 ND
57 1,1-Dichloropropene 75 4.987 ND
59 Carbon tetrachloride 117 4.990 ND
60 Benzene 78 5.145 ND
61 1,2-Dichloroethane 62 5.167 ND
65 Trichloroethene 95 5.640 ND
67 Methylcyclohexane 55 5.842 ND
69 1,2-Dichloropropane 63 5.855 5.849 0.006 95 16035 3.50
71 Dibromomethane 93 5.923 ND
72 Dichlorobromomethane 83 6.045 ND
75 cis-1,3-Dichloropropene 75 6.402 ND
76 4-Methyl-2-pentanone (MIBK) 43 6.501 ND
77 Toluene 91 6.701 6.694 0.007 99 13211 0.6697
78 trans-1,3-Dichloropropene 75 6.868 ND
79 Ethyl methacrylate 69 6.884 ND
80 1,1,2-Trichloroethane 97 7.045 ND
82 Tetrachloroethene 164 7.148 ND
83 1,3-Dichloropropane 76 7.196 ND
84 2-Hexanone 43 7.215 ND
85 Chlorodibromomethane 129 7.392 ND
86 Ethylene Dibromide 107 7.514 ND
88 Chlorobenzene 112 7.955 ND
89 1,1,1,2-Tetrachloroethane 131 8.022 ND
90 Ethylbenzene 106 8.029 ND
91 m-Xylene & p-Xylene 106 8.148 ND 7
92 o-Xylene 106 8.517 8.511 0.006 1 1382 0.1788 M
93 Styrene 104 8.527 ND
94 Bromoform 173 8.710 ND
95 Isopropylbenzene 105 8.858 ND
98 1,1,2,2-Tetrachloroethane 83 9.141 ND
100 Bromobenzene 156 9.186 ND
101 1,2,3-Trichloropropane 110 9.209 ND
102 N-Propylbenzene 120 9.257 ND
103 2-Chlorotoluene 126 9.360 ND
104 1,3,5-Trimethylbenzene 105 9.431 ND
105 4-Chlorotoluene 126 9.479 ND
107 tert-Butylbenzene 119 9.746 ND
108 1,2,4-Trimethylbenzene 105 9.804 ND
109 sec-Butylbenzene 134 9.968 ND
110 1,3-Dichlorobenzene 146 10.099 ND
111 4-Isopropyltoluene 119 10.112 ND
112 1,4-Dichlorobenzene 146 10.196 ND
114 n-Butylbenzene 91 10.524 ND
115 1,2-Dichlorobenzene 146 10.559 ND
116 1,2-Dibromo-3-Chloropropane 157 11.344 ND
118 1,2,4-Trichlorobenzene 180 12.180 ND
119 Hexachlorobutadiene 225 12.321 ND
120 Naphthalene 128 12.453 ND
121 1,2,3-Trichlorobenzene 180 12.678 ND
S 154 1,3-Dichloropropene, Total 1 0.000 ND 7
11/15/2024
3:53:55 PM
Page 171 of 777
Report Date: 11-Nov-2024 17:30:23 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004286.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
S 156 Total BTEX 1 0 0.8485
S 151 1,2-Dichloroethene, Total 1 0.000 ND 7
S 152 Trihalomethanes, Total 1 0.000 ND 7
S 155 Xylenes, Total 106 0 0.1788
QC Flag Legend
Processing Flags
7 - Failed Limit of Detection
Review Flags
M - Manually Integrated
U - Marked Undetected
Reagents:
mv-IS_SS_00089 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 172 of 777
Report Date: 11-Nov-2024 17:30:23 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004286.D
Injection Date:11-Nov-2024 12:12:40 Instrument ID:VMS_MS14 Operator ID:MED
Lims ID:280-198899-B-2 Lab Sample ID:280-198899-2 Worklist Smp#:28
Client ID:MW-61-241030
Purge Vol: 5.000 mL Dil. Factor:50.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0
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11/15/2024
3:53:55 PM
Page 173 of 777
Report Date: 11-Nov-2024 17:30:23 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004286.D
Lims ID:280-198899-B-2
Client ID:MW-61-241030
Sample Type:Client
Inject. Date:11-Nov-2024 12:12:40 ALS Bottle#:0 Worklist Smp#:28
Purge Vol: 5.000 mL Dil. Factor:50.0000
Sample Info:280-198899-B-2 50x
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:11-Nov-2024 17:30:16 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:11-Nov-2024 17:30:16
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 46.6 93.10
$5 1,2-Dichloroethane-d4 (Surr)50.0 45.6 91.16
$6 Toluene-d8 (Surr)50.0 54.2 108.43
$7 4-Bromofluorobenzene (Surr)50.0 46.9 93.90
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Report Date: 11-Nov-2024 17:30:23 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004286.D
Injection Date:11-Nov-2024 12:12:40 Instrument ID:VMS_MS14
Lims ID:280-198899-B-2 Lab Sample ID:280-198899-2
Client ID:MW-61-241030
Operator ID:MED ALS Bottle#:0 Worklist Smp#:28
Purge Vol: 5.000 mL Dil. Factor:50.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
77 Toluene, CAS: 108-88-3
30 70 110 150 190 230 270 310 350
m/z
0
10
20
30
40
50
60
70
Y ( X10
0
)
Raw Spec:Scan 1777(6.70)
91
92
65 89
30 70 110 150 190 230 270 310 350m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1776(6.70), Qvalue=99 Sig Qvalue=84
91
92
65 89
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X10
0
)
Ref Spec: 77 Toluene (NIST98.L)
91
92
65
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 6.700 min.(Qvalue: 99)
63 65
6.2 6.5 6.8 7.1
Min
RT
0
12
24
36
48
60
72
Y ( X10
0
)
0000004286[MS Quad Chro]:m/z 91

6
.
7
0
1
6.1 6.4 6.7 7.0Min
RT
0
8
16
24
32
40
48
Y ( X10
0
)
0000004286[MS Quad Chro]:m/z 92

6
.
6
9
1
6.1 6.4 6.7 7.0
Min
RT
0
3
6
9
12
15
18
Y ( X10
0
)
0000004286[MS Quad Chro]:m/z 65
6.1 6.4 6.7 7.0
Min
0
12
24
36
48
60
72
Y ( X10
0
)
0000004286[MS Quad Chro]:m/z 91
0000004286[MS Quad Chro]:m/z 92
0000004286[MS Quad Chro]:m/z 65
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3:53:55 PM
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Report Date: 11-Nov-2024 17:30:23 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004286.D
Injection Date:11-Nov-2024 12:12:40 Instrument ID:VMS_MS14
Lims ID:280-198899-B-2 Lab Sample ID:280-198899-2
Client ID:MW-61-241030
Operator ID:MED ALS Bottle#:0 Worklist Smp#:28
Purge Vol: 5.000 mL Dil. Factor:50.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
42 1,1-Dichloroethane, CAS: 75-34-3
30 70 110 150 190 230 270 310 350
m/z
0
5
10
15
20
25
30
35
Y ( X10
0
)
Raw Spec:Scan 956(4.06)
63
65
85
30 70 110 150 190 230 270 310 350m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 956(4.06), Qvalue=92 Sig Qvalue=93
63
65
83
61
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X10
0
)
Ref Spec: 42 1,1-Dichloroethane (NIST98.L)
63
65
62 83
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 4.060 min.(Qvalue: 92)
83 85
3.5 3.8 4.1 4.4
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
)
0000004286[MS Quad Chro]:m/z 63

4
.
0
6
1
3.5 3.8 4.1 4.4Min
RT
0
3
6
9
12
Y ( X10
0
)
0000004286[MS Quad Chro]:m/z 65

4
.
0
58
3.5 3.8 4.1 4.4
Min
RT
0
12
24
36
48
60
72
Y ( X10
)
0000004286[MS Quad Chro]:m/z 83
3.5 3.8 4.1 4.4
Min
0
6
12
18
24
30
36
Y ( X10
0
)
0000004286[MS Quad Chro]:m/z 63
0000004286[MS Quad Chro]:m/z 65
0000004286[MS Quad Chro]:m/z 83
11/15/2024
3:53:55 PM
Page 176 of 777
Report Date: 11-Nov-2024 17:30:23 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004286.D
Injection Date:11-Nov-2024 12:12:40 Instrument ID:VMS_MS14
Lims ID:280-198899-B-2 Lab Sample ID:280-198899-2
Client ID:MW-61-241030
Operator ID:MED ALS Bottle#:0 Worklist Smp#:28
Purge Vol: 5.000 mL Dil. Factor:50.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
24 1,1,2-Trichloro-1,2,2-trifluoroethane, CAS: 76-13-1
30 70 110 150 190 230 270 310 350
m/z
0
4
8
12
16
20
24
28
Y ( X10
0
0
0
)
Raw Spec:Scan 671(3.14)
101
151
103
153
85
66 105 155
30 70 110 150 190 230 270 310 350m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 670(3.14), Qvalue=94 Sig Qvalue=95
101
151
153
85
66 105 155
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X10
0
)
Ref Spec: 24 1,1,2-Trichloro-1,2,2-trifluoroethane (NIST98.L)
101
151103
85 153
66
105 155
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 3.140 min.(Qvalue: 94)
153116
2.6 2.9 3.2 3.5
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
0
0
)
0000004286[MS Quad Chro]:m/z 151

3
.
1
4
5
2.6 2.9 3.2 3.5Min
RT
0
5
10
15
20
25
30
Y ( X10
0
0
0
)
0000004286[MS Quad Chro]:m/z 101

3
.
1
4
1
2.6 2.9 3.2 3.5
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
0
)
0000004286[MS Quad Chro]:m/z 153

3
.
1
4
5
2.6 2.9 3.2 3.5
Min
0
5
10
15
20
25
30
Y ( X10
0
0
0
)
0000004286[MS Quad Chro]:m/z 151
0000004286[MS Quad Chro]:m/z 101
0000004286[MS Quad Chro]:m/z 153
11/15/2024
3:53:55 PM
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Report Date: 11-Nov-2024 17:30:23 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004286.D
Injection Date:11-Nov-2024 12:12:40 Instrument ID:VMS_MS14
Lims ID:280-198899-B-2 Lab Sample ID:280-198899-2
Client ID:MW-61-241030
Operator ID:MED ALS Bottle#:0 Worklist Smp#:28
Purge Vol: 5.000 mL Dil. Factor:50.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
69 1,2-Dichloropropane, CAS: 78-87-5
30 70 110 150 190 230 270 310 350
m/z
0
13
26
39
52
65
78
91
Y ( X10
0
)
Raw Spec:Scan 1514(5.86)
63
62
76
78
30 70 110 150 190 230 270 310 350m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1513(5.86), Qvalue=95 Sig Qvalue=100
63
62
76
78
112
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X10
0
)
Ref Spec: 69 1,2-Dichloropropane (NIST98.L)
63
62
65
77
112
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 5.850 min.(Qvalue: 95)
76 78
5.3 5.6 5.9 6.2
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
)
0000004286[MS Quad Chro]:m/z 63

5.8
55
5.3 5.6 5.9 6.2Min
RT
0
5
10
15
20
25
30
Y ( X10
0
)
0000004286[MS Quad Chro]:m/z 65

5.8
4
9
5.3 5.6 5.9 6.2
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
)
0000004286[MS Quad Chro]:m/z 41

5.8
4
5
5.3 5.6 5.9 6.2
Min
0
4
8
12
16
20
Y ( X10
0
0
)
0000004286[MS Quad Chro]:m/z 63
0000004286[MS Quad Chro]:m/z 65
0000004286[MS Quad Chro]:m/z 41
11/15/2024
3:53:55 PM
Page 178 of 777
Report Date: 11-Nov-2024 17:30:23 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004286.D
Injection Date:11-Nov-2024 12:12:40 Instrument ID:VMS_MS14
Lims ID:280-198899-B-2 Lab Sample ID:280-198899-2
Client ID:MW-61-241030
Operator ID:MED ALS Bottle#:0 Worklist Smp#:28
Purge Vol: 5.000 mL Dil. Factor:50.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
92 o-Xylene, CAS: 95-47-6
30 70 110 150 190 230 270 310 350
m/z
0
2
4
6
8
10
12
14
Y ( X10
0
)
Raw Spec:Scan 2342(8.52)
91
106
44
50
30 70 110 150 190 230 270 310 350m/z
0
2
4
6
8
10
12
14
Y ( X10
0
)
Enhanced Spec:Scan 2342(8.52) Bgrd 2333( 8.49), Qvalue=1 Sig Qvalue=96
91 106
50
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X10
0
)
Ref Spec: 92 o-Xylene (NIST98.L)
91
106
51 77
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 2342 @ 8.517 min.(Qvalue: 1)
106
50 52
8.0 8.3 8.6 8.9
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
)
0000004286[MS Quad Chro]:m/z 106

8
.
517
8.0 8.3 8.6 8.9Min
RT
0
4
8
12
16
20
24
Y ( X10
0
)
0000004286[MS Quad Chro]:m/z 91

8
.
511
8.0 8.3 8.6 8.9
Min
0
4
8
12
16
20
24
Y ( X10
0
)
0000004286[MS Quad Chro]:m/z 106
0000004286[MS Quad Chro]:m/z 91
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3:53:55 PM
Page 179 of 777
Report Date: 11-Nov-2024 17:30:23 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004286.D
Injection Date:11-Nov-2024 12:12:40 Instrument ID:VMS_MS14
Lims ID:280-198899-B-2 Lab Sample ID:280-198899-2
Client ID:MW-61-241030
Operator ID:MED ALS Bottle#:0 Worklist Smp#:28
Purge Vol: 5.000 mL Dil. Factor:50.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
42 1,1-Dichloroethane, CAS: 75-34-3
Signal: 1
Processing Integration Results
RT: 4.06
Area: 3823
Amount: 0.532563
Amount Units: ug/l
3.7 3.9 4.1 4.3
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
Y ( X10
0
)
0000004286[MS Quad Chro]:m/z 63

4
.
0
6
1
Manual Integration Results
RT: 4.06
Area: 6248
Amount: 0.870378
Amount Units: ug/l
3.7 3.9 4.1 4.3
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
Y ( X10
0
)
0000004286[MS Quad Chro]:m/z 63

4
.
0
6
1
Reviewer: LP8K, 11-Nov-2024 16:08:25 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 180 of 777
Report Date: 11-Nov-2024 17:30:23 Chrom Revision: 2.3 17-Oct-2024 11:42:22
User Disabled Compound Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004286.D
Injection Date:11-Nov-2024 12:12:40 Instrument ID:VMS_MS14
Lims ID:280-198899-B-2 Lab Sample ID:280-198899-2
Client ID:MW-61-241030
Operator ID:MED ALS Bottle#:0 Worklist Smp#:28
Purge Vol: 5.000 mL Dil. Factor:50.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
25 1,1-Dichloroethene, CAS: 75-35-4
Processing Results
30 70 110 150 190 230 270 310 350m/z
0
4
8
12
16
20
24
28
Y ( X10
0
0
0
)
Raw Spec:Scan 668(3.13)
101
151
103
153
85
66 105 155
30 70 110 150 190 230 270 310 350
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 667(3.13), Qvalue=36
12168
119
62 13675
98
60
30 70 110 150 190 230 270 310 350
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 25 1,1-Dichloroethene (NIST98.L)
61
96
98
63
60
100
2.9 3.2Min
RT
0
2
4
6
8
10
12
Y ( X10
0
)
0000004286[MS Quad Chro]:m/z 96

3
.
1
3
5
2.9 3.2
Min
RT
0
3
6
9
12
15
18
Y ( X10
0
)
0000004286[MS Quad Chro]:m/z 61

3
.
1
51
2.9 3.2
Min
RT
0
13
26
39
52
65
78
Y ( X10
)
0000004286[MS Quad Chro]:m/z 98
RT Mass Response Amount
3.13 96.00 2345 0.785966
3.15 61.00 1618
3.14 98.00 0
Reviewer: LP8K, 11-Nov-2024 16:08:17 -07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
11/15/2024
3:53:55 PM
Page 181 of 777
Report Date: 11-Nov-2024 17:30:23 Chrom Revision: 2.3 17-Oct-2024 11:42:22
User Disabled Compound Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004286.D
Injection Date:11-Nov-2024 12:12:40 Instrument ID:VMS_MS14
Lims ID:280-198899-B-2 Lab Sample ID:280-198899-2
Client ID:MW-61-241030
Operator ID:MED ALS Bottle#:0 Worklist Smp#:28
Purge Vol: 5.000 mL Dil. Factor:50.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
10 Dichlorodifluoromethane, CAS: 75-71-8
Processing Results
30 70 110 150 190 230 270 310 350m/z
0
6
12
18
24
30
36
42
Y ( X10
0
0
)
Raw Spec:Scan 239(1.76)
116
11885
30 70 110 150 190 230 270 310 350
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 239(1.76), Qvalue=50
116
11885
30 70 110 150 190 230 270 310 350
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 10 Dichlorodifluoromethane (NIST98.L)
85
87
50 101
1.5 1.8 2.1Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
0000004286[MS Quad Chro]:m/z 85

1
.
7
56
1.5 1.8 2.1
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
)
0000004286[MS Quad Chro]:m/z 87

1
.
7
59
1.5 1.8 2.1
Min
RT
0
5
10
15
20
25
Y ( X10
0
)
0000004286[MS Quad Chro]:m/z 50

1
.
7
59
RT Mass Response Amount
1.76 85.00 17082 3.378023
1.76 87.00 4900
1.76 50.00 3262
Reviewer: LP8K, 11-Nov-2024 17:30:14 -07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
11/15/2024
3:53:55 PM
Page 182 of 777
Report Date: 11-Nov-2024 17:30:23 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004286.D
Injection Date:11-Nov-2024 12:12:40 Instrument ID:VMS_MS14
Lims ID:280-198899-B-2 Lab Sample ID:280-198899-2
Client ID:MW-61-241030
Operator ID:MED ALS Bottle#:0 Worklist Smp#:28
Purge Vol: 5.000 mL Dil. Factor:50.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
92 o-Xylene, CAS: 95-47-6
Signal: 1
Processing Integration Results
RT: 8.52
Area: 1028
Amount: 0.132983
Amount Units: ug/l
8.2 8.4 8.6 8.8
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
Y ( X10
0
)
0000004286[MS Quad Chro]:m/z 106

8
.
517
Manual Integration Results
RT: 8.52
Area: 1382
Amount: 0.178777
Amount Units: ug/l
8.2 8.4 8.6 8.8
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
12
13
Y ( X10
0
)
0000004286[MS Quad Chro]:m/z 106

8
.
517
Reviewer: LP8K, 11-Nov-2024 16:08:33 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 183 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:MW-63-241030 Lab Sample ID:280-198899-3
Matrix:VMS14_0000004278.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
10/30/2024 12:20
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 09:25
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.14100-41-4 Ethylbenzene ND
1.0 0.13100-42-5 Styrene ND
1.0 0.1610061-01-5 cis-1,3-Dichloropropene ND
1.0 0.14F110061-02-6 trans-1,3-Dichloropropene ND
1.0 0.18103-65-1 N-Propylbenzene ND
1.0 0.23F1104-51-8 n-Butylbenzene ND
1.0 0.21106-43-4 4-Chlorotoluene ND
1.0 0.39106-46-7 1,4-Dichlorobenzene ND
1.0 0.18106-93-4 Ethylene Dibromide ND
2.0 0.46107-05-1 3-Chloro-1-propene ND
1.0 0.28107-06-2 1,2-Dichloroethane ND
3.0 0.36108-05-4 Vinyl acetate ND
5.0 0.98108-10-1 4-Methyl-2-pentanone (MIBK)ND
1.0 0.12108-67-8 1,3,5-Trimethylbenzene ND
1.0 0.19108-86-1 Bromobenzene ND
1.0 0.31F1108-87-2 Methylcyclohexane ND
1.0 0.32108-88-3 Toluene ND
1.0 0.092108-90-7 Chlorobenzene ND
7.0 0.84109-99-9 Tetrahydrofuran ND
2.0 0.16F1110-54-3 Hexane ND
1.0 0.44110-82-7 Cyclohexane ND
1.0 0.58F1120-82-1 1,2,4-Trichlorobenzene ND
1.0 0.28124-48-1 Chlorodibromomethane ND
1.0 0.40127-18-4 Tetrachloroethene ND
1.0 0.20F1135-98-8 sec-Butylbenzene ND
1.0 0.17142-28-9 1,3-Dichloropropane ND
1.0 0.32156-59-2 cis-1,2-Dichloroethene ND
1.0 0.37156-60-5 trans-1,2-Dichloroethene ND
5.0 0.251634-04-4 Methyl tert-butyl ether ND
2.0 0.36179601-23-1 m-Xylene & p-Xylene ND
1.0 0.33541-73-1 1,3-Dichlorobenzene ND
1.0 0.2356-23-5 Carbon tetrachloride ND
FORM I 8260D
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3:53:55 PM
Page 184 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:MW-63-241030 Lab Sample ID:280-198899-3
Matrix:VMS14_0000004278.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
10/30/2024 12:20
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 09:25
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.19563-58-6 1,1-Dichloropropene ND
5.0 0.81591-78-6 2-Hexanone ND
1.0 0.17594-20-7 2,2-Dichloropropane ND
2.0 0.3560-29-7 Ethyl ether ND
1.0 0.16630-20-6 1,1,1,2-Tetrachloroethane ND
15 6.667-64-1 Acetone ND
1.0 0.3667-66-3 Chloroform ND
1.0 0.1471-43-2 Benzene ND
1.0 0.3971-55-6 1,1,1-Trichloroethane ND
5.0 2.4*174-83-9 Bromomethane ND
2.0 0.2374-87-3 Chloromethane ND
5.0 2.674-88-4 Iodomethane ND
1.0 0.3474-95-3 Dibromomethane ND
1.0 0.4074-97-5 Chlorobromomethane ND
2.0 0.6475-00-3 Chloroethane ND
1.0 0.2375-01-4 Vinyl chloride ND
2.0 0.9475-09-2 Methylene Chloride ND
2.0 0.2675-15-0 Carbon disulfide ND
2.0 0.2575-25-2 Bromoform ND
1.0 0.1975-27-4 Dichlorobromomethane ND
1.0 0.2275-34-3 1,1-Dichloroethane ND
1.0 0.2375-35-4 1,1-Dichloroethene ND
2.0 0.2075-69-4 Trichlorofluoromethane ND
2.0 0.3075-71-8 Dichlorodifluoromethane ND
3.0 0.7376-13-1 1,1,2-Trichloro-1,2,2-trifluoroethan
e
ND
1.0 0.2478-87-5 1,2-Dichloropropane ND
10 4.678-93-3 2-Butanone (MEK)ND
1.0 0.2779-00-5 1,1,2-Trichloroethane ND
1.0 0.3079-01-6 Trichloroethene ND
5.0 1.679-20-9 Methyl acetate ND
1.0 0.2179-34-5 1,1,2,2-Tetrachloroethane ND
4.0 1.287-61-6 1,2,3-Trichlorobenzene ND
FORM I 8260D
11/15/2024
3:53:55 PM
Page 185 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:MW-63-241030 Lab Sample ID:280-198899-3
Matrix:VMS14_0000004278.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
10/30/2024 12:20
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 09:25
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
2.0 0.53F187-68-3 Hexachlorobutadiene ND
3.0 0.9991-20-3 Naphthalene ND
1.0 0.1195-47-6 o-Xylene ND
1.0 0.3495-49-8 2-Chlorotoluene ND
1.0 0.1495-50-1 1,2-Dichlorobenzene ND
1.0 0.1595-63-6 1,2,4-Trimethylbenzene ND
5.0 0.4296-12-8 1,2-Dibromo-3-Chloropropane ND
2.5 0.2896-18-4 1,2,3-Trichloropropane ND
3.0 0.1997-63-2 Ethyl methacrylate ND
1.0 0.18F198-06-6 tert-Butylbenzene ND
1.0 0.1698-82-8 Isopropylbenzene ND
1.0 0.19F199-87-6 4-Isopropyltoluene ND
1.0 0.111330-20-7 Xylenes, Total ND
1.0 0.32540-59-0 1,2-Dichloroethene, Total ND
1.0 0.14542-75-6 1,3-Dichloropropene, Total ND
1.0 0.19STL00209Trihalomethanes, Total ND
1.0 0.14STL00431Total BTEX ND
%RECCAS NO.LIMITSQSURROGATE
92 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr)
93 77-1201868-53-7 Dibromofluoromethane (Surr)
106 80-1252037-26-5 Toluene-d8 (Surr)
94 78-120460-00-4 4-Bromofluorobenzene (Surr)
FORM I 8260D
11/15/2024
3:53:55 PM
Page 186 of 777
Report Date: 11-Nov-2024 16:14:55 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004278.D
Lims ID:280-198899-B-3
Client ID:MW-63-241030
Sample Type:Client
Inject. Date:11-Nov-2024 09:25:32 ALS Bottle#:0 Worklist Smp#:20
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:280-198899-b-3
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:11-Nov-2024 16:14:22 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:11-Nov-2024 16:01:20
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.357 0.003 99 1111633 50.0
* 2 Chlorobenzene-d5 119 7.926 7.926 0.000 85 266851 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.174 10.173 0.001 95 476625 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.842 4.839 0.003 93 249773 46.4
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 97 308874 45.9
$ 6 Toluene-d8 (Surr) 98 6.637 6.637 0.000 93 1119597 53.2
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 89 427947 46.9
$ 8 BFB 95 9.032 9.032 0.000 88 427947 NR
9 Chlorotrifluoroethene 116 1.677 ND
10 Dichlorodifluoromethane 85 1.791 ND
11 Ethylene oxide 43 1.756 1.843 -0.087 83 3214 14.6
12 Chloromethane 50 1.974 ND
13 Vinyl chloride 62 2.090 ND
14 2-Chloro-1,1,1-Trifluoroethane 118 2.110 ND
15 Bromomethane 94 2.389 ND
16 Chloroethane 64 2.489 ND
17 Dichlorofluoromethane 67 2.675 ND
18 Trichlorofluoromethane 101 2.711 ND
19 Propene oxide 58 2.738 ND
20 Ethanol 45 2.875 ND
21 Ethyl ether 59 2.936 ND
22 Acrolein 56 3.055 ND
23 1,2-Dichloro-1,1,2-trifluoroetha 117 3.129 ND
25 1,1-Dichloroethene 96 3.138 ND
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.141 ND
26 Acetone 43 3.164 ND 7
27 1,1,1-Trifluoro-2,2-dichloroetha 83 3.213 ND
28 Isopropyl alcohol 45 3.257 3.257 0.000 99 41063 17.6 M
29 Iodomethane 142 3.267 ND
30 Carbon disulfide 76 3.338 3.334 0.004 63 2885 0.2400 M
31 Acetonitrile 41 3.379 ND
32 Methyl acetate 43 3.399 ND
11/15/2024
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Page 187 of 777
Report Date: 11-Nov-2024 16:14:55 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004278.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
33 3-Chloro-1-propene 41 3.418 ND
34 Methylene Chloride 84 3.518 ND
35 2-Methyl-2-propanol 59 3.576 3.579 -0.003 93 7590 1.59 M
36 Acrylonitrile 53 3.688 ND
37 Methyl tert-butyl ether 73 3.714 ND
38 trans-1,2-Dichloroethene 96 3.727 ND
39 Hexane 57 3.929 ND
40 Vinyl acetate 43 4.032 ND
42 1,1-Dichloroethane 63 4.055 ND
41 Isopropyl ether 87 4.055 ND
43 2-Chloro-1,3-butadiene 53 4.113 ND
44 Tert-butyl ethyl ether 59 4.325 ND
45 2-Butanone (MEK) 43 4.456 ND
46 Ethyl acetate 43 4.463 ND
47 cis-1,2-Dichloroethene 96 4.482 ND
48 2,2-Dichloropropane 77 4.495 ND
49 Propionitrile 54 4.505 ND
50 sec-Butyl Alcohol 45 4.575 ND
51 Methacrylonitrile 41 4.617 ND
52 Chlorobromomethane 128 4.662 ND
53 Tetrahydrofuran 42 4.678 ND
54 Chloroform 83 4.720 ND
55 1,1,1-Trichloroethane 97 4.871 ND
56 Cyclohexane 56 4.936 ND
57 1,1-Dichloropropene 75 4.987 ND
59 Carbon tetrachloride 117 4.990 ND
58 Isobutyl alcohol 41 5.003 ND U
60 Benzene 78 5.145 ND
61 1,2-Dichloroethane 62 5.167 ND
62 Tert-amyl methyl ether 73 5.209 ND
63 n-Heptane 43 5.328 ND
64 n-Butanol 56 5.502 ND
65 Trichloroethene 95 5.640 ND
66 2-Pentanone 43 5.743 ND
67 Methylcyclohexane 55 5.842 ND
68 Methyl methacrylate 100 5.846 ND
69 1,2-Dichloropropane 63 5.849 ND
70 1,4-Dioxane 88 5.903 ND
71 Dibromomethane 93 5.923 ND
72 Dichlorobromomethane 83 6.045 ND
73 2-Nitropropane 41 6.215 ND
74 2-Chloroethyl vinyl ether 63 6.247 ND
75 cis-1,3-Dichloropropene 75 6.402 ND
76 4-Methyl-2-pentanone (MIBK) 43 6.501 ND
77 Toluene 91 6.694 ND
78 trans-1,3-Dichloropropene 75 6.868 ND
79 Ethyl methacrylate 69 6.884 ND
80 1,1,2-Trichloroethane 97 7.045 ND
81 Tetrahydrothiophene 60 7.051 ND
82 Tetrachloroethene 164 7.148 ND
83 1,3-Dichloropropane 76 7.196 ND
84 2-Hexanone 43 7.215 ND
11/15/2024
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Page 188 of 777
Report Date: 11-Nov-2024 16:14:55 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004278.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
85 Chlorodibromomethane 129 7.392 ND
86 Ethylene Dibromide 107 7.514 ND
87 1-Chlorohexane 91 7.907 ND 7
88 Chlorobenzene 112 7.955 ND
89 1,1,1,2-Tetrachloroethane 131 8.022 ND
90 Ethylbenzene 106 8.029 ND
91 m-Xylene & p-Xylene 106 8.148 ND
92 o-Xylene 106 8.511 ND
93 Styrene 104 8.527 ND
94 Bromoform 173 8.710 ND
95 Isopropylbenzene 105 8.858 ND
96 cis-1,4-Dichloro-2-butene 53 8.907 ND
97 Cyclohexanone 55 8.958 ND
98 1,1,2,2-Tetrachloroethane 83 9.141 ND
99 trans-1,4-Dichloro-2-butene 53 9.177 ND
100 Bromobenzene 156 9.186 ND
101 1,2,3-Trichloropropane 110 9.209 ND
102 N-Propylbenzene 120 9.257 ND
103 2-Chlorotoluene 126 9.360 ND
104 1,3,5-Trimethylbenzene 105 9.431 ND
105 4-Chlorotoluene 126 9.479 ND
106 Pentachloroethane 167 9.479 ND
107 tert-Butylbenzene 119 9.746 ND
108 1,2,4-Trimethylbenzene 105 9.804 ND
109 sec-Butylbenzene 134 9.968 ND
110 1,3-Dichlorobenzene 146 10.099 ND
111 4-Isopropyltoluene 119 10.112 ND
112 1,4-Dichlorobenzene 146 10.196 ND
113 1,2,3-Trimethylbenzene 105 10.218 ND
114 n-Butylbenzene 91 10.524 ND
115 1,2-Dichlorobenzene 146 10.559 ND
116 1,2-Dibromo-3-Chloropropane 157 11.344 ND
117 1,3,5-Trichlorobenzene 180 11.540 ND
118 1,2,4-Trichlorobenzene 180 12.180 ND
119 Hexachlorobutadiene 225 12.321 ND
120 Naphthalene 128 12.453 ND
121 1,2,3-Trichlorobenzene 180 12.678 ND
140 2-Methylhexane 1 0.000 ND
136 Butadiene 54 0.000 ND
132 2,2,3-Trimethylbutane 1 0.000 ND
142 4-Bromofluorobenzene 95 0.000 ND
149 Dimethyl disulfide 1 0.000 ND
125 Benzene, 1-bromo-4-ethyl- 1 0.000 ND
124 cis-1,4-Dichloro-2-butene TIC 1 0.000 ND
135 1,2-dichloro-4-(trifluoromethyl) 1 0.000 ND
130 Benzyl chloride 126 0.000 ND
129 3,3-Dimethylpentane 1 0.000 ND
126 t-Amyl alcohol 1 0.000 ND
137 1-Chloro-1-fluoroethane TIC 1 0.000 ND
150 4-Chlorobenzotrifluoride 1 0.000 ND
127 Pentachloroethane TIC 1 0.000 ND
138 Benzene, 1-bromo-3-fluoro- 1 0.000 ND
11/15/2024
3:53:55 PM
Page 189 of 777
Report Date: 11-Nov-2024 16:14:55 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004278.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
123 Ethyl acrylate 55 0.000 ND
148 n-Nonyl Aldehyde 1 0.000 ND
133 1,4-Dibromobenzene 1 0.000 ND
143 3-Ethylpentane 1 0.000 ND
122 Isooctane 57 0.000 ND
144 n-Butyl acetate 43 0.000 ND
145 1-Bromo-2-chloroethane 1 0.000 ND
134 1,3-Dibromobenzene 1 0.000 ND
139 2,2-Dimethylpentane 1 0.000 ND
141 Ethylene oxide TIC 1 0.000 ND
146 2,3-Dimethylpentane 1 0.000 ND
128 2,4-Dimethylpentane 1 0.000 ND
131 1-Chlorohexane TIC 1 0.000 ND
147 3-Methylhexane 1 0.000 ND
S 154 1,3-Dichloropropene, Total 1 0.000 ND 7
S 153 TAH 1 0 0 7
S 156 Total BTEX 1 0.000 ND 7
S 151 1,2-Dichloroethene, Total 1 0.000 ND 7
S 152 Trihalomethanes, Total 1 0.000 ND 7
S 155 Xylenes, Total 106 0.000 ND 7
T 157 1,3-Butadiene TIC 39 1.788 ND 7
T 158 Cyclohexane TIC 1 4.565 ND
T 159 Methyl cyclohexane TIC 1 5.311 ND
T 160 2,3-dichloro-1-propene TIC 75 5.797 ND
T 161 4-Ethyltoluene TIC 105 9.045 9.131 -0.086 1 106 0.0199 7
T 164 Propene TIC 41 0.000 ND
T 166 Dichloroacetonitrile TIC 74 0.000 ND
T 163 2-Butoxyethanol TIC 1 0.000 ND
T 162 Dicyclopentadiene TIC 66 0.000 ND
T 167 Propene oxide TIC 58 0.000 ND
T 165 n-Nonane TIC 1 0.000 ND
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
7 - Failed Limit of Detection
Review Flags
M - Manually Integrated
U - Marked Undetected
Reagents:
mv-IS_SS_00089 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 190 of 777
Report Date: 11-Nov-2024 16:14:55 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004278.D
Injection Date:11-Nov-2024 09:25:32 Instrument ID:VMS_MS14 Operator ID:MED
Lims ID:280-198899-B-3 Lab Sample ID:280-198899-3 Worklist Smp#:20
Client ID:MW-63-241030
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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11/15/2024
3:53:55 PM
Page 191 of 777
Report Date: 11-Nov-2024 16:14:55 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004278.D
Lims ID:280-198899-B-3
Client ID:MW-63-241030
Sample Type:Client
Inject. Date:11-Nov-2024 09:25:32 ALS Bottle#:0 Worklist Smp#:20
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:280-198899-b-3
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:11-Nov-2024 16:14:22 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:11-Nov-2024 16:01:20
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 46.4 92.71
$5 1,2-Dichloroethane-d4 (Surr)50.0 45.9 91.80
$6 Toluene-d8 (Surr)50.0 53.2 106.47
$7 4-Bromofluorobenzene (Surr)50.0 46.9 93.85
11/15/2024
3:53:55 PM
Page 192 of 777
Report Date: 11-Nov-2024 16:14:56 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004278.D
Injection Date:11-Nov-2024 09:25:32 Instrument ID:VMS_MS14
Lims ID:280-198899-B-3 Lab Sample ID:280-198899-3
Client ID:MW-63-241030
Operator ID:MED ALS Bottle#:0 Worklist Smp#:20
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
30 Carbon disulfide, CAS: 75-15-0
Signal: 1
Processing Integration Results
RT: 3.34
Area: 2606
Amount: 0.216750
Amount Units: ug/l
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0000004278[MS Quad Chro]:m/z 76

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Manual Integration Results
RT: 3.34
Area: 2885
Amount: 0.239955
Amount Units: ug/l
3.0 3.2 3.4 3.6
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RT
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8
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Reviewer: LP8K, 11-Nov-2024 16:01:10 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 193 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:FB-01 Lab Sample ID:280-198899-4
Matrix:VMS14_0000004275.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
10/30/2024 00:00
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 08:24
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.14100-41-4 Ethylbenzene ND
1.0 0.13100-42-5 Styrene ND
1.0 0.1610061-01-5 cis-1,3-Dichloropropene ND
1.0 0.1410061-02-6 trans-1,3-Dichloropropene ND
1.0 0.18103-65-1 N-Propylbenzene ND
1.0 0.23104-51-8 n-Butylbenzene ND
1.0 0.21106-43-4 4-Chlorotoluene ND
1.0 0.39106-46-7 1,4-Dichlorobenzene ND
1.0 0.18106-93-4 Ethylene Dibromide ND
2.0 0.46107-05-1 3-Chloro-1-propene ND
1.0 0.28107-06-2 1,2-Dichloroethane ND
3.0 0.36108-05-4 Vinyl acetate ND
5.0 0.98108-10-1 4-Methyl-2-pentanone (MIBK)ND
1.0 0.12108-67-8 1,3,5-Trimethylbenzene ND
1.0 0.19108-86-1 Bromobenzene ND
1.0 0.31108-87-2 Methylcyclohexane ND
1.0 0.32108-88-3 Toluene ND
1.0 0.092108-90-7 Chlorobenzene ND
7.0 0.84109-99-9 Tetrahydrofuran ND
2.0 0.16110-54-3 Hexane ND
1.0 0.44110-82-7 Cyclohexane ND
1.0 0.58120-82-1 1,2,4-Trichlorobenzene ND
1.0 0.28124-48-1 Chlorodibromomethane ND
1.0 0.40127-18-4 Tetrachloroethene ND
1.0 0.20135-98-8 sec-Butylbenzene ND
1.0 0.17142-28-9 1,3-Dichloropropane ND
1.0 0.32156-59-2 cis-1,2-Dichloroethene ND
1.0 0.37156-60-5 trans-1,2-Dichloroethene ND
5.0 0.251634-04-4 Methyl tert-butyl ether ND
2.0 0.36179601-23-1 m-Xylene & p-Xylene ND
1.0 0.33541-73-1 1,3-Dichlorobenzene ND
1.0 0.2356-23-5 Carbon tetrachloride ND
FORM I 8260D
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Page 194 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:FB-01 Lab Sample ID:280-198899-4
Matrix:VMS14_0000004275.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
10/30/2024 00:00
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 08:24
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.19563-58-6 1,1-Dichloropropene ND
5.0 0.81591-78-6 2-Hexanone ND
1.0 0.17594-20-7 2,2-Dichloropropane ND
2.0 0.3560-29-7 Ethyl ether ND
1.0 0.16630-20-6 1,1,1,2-Tetrachloroethane ND
15 6.667-64-1 Acetone ND
1.0 0.3667-66-3 Chloroform ND
1.0 0.1471-43-2 Benzene ND
1.0 0.3971-55-6 1,1,1-Trichloroethane ND
5.0 2.4*174-83-9 Bromomethane ND
2.0 0.2374-87-3 Chloromethane ND
5.0 2.674-88-4 Iodomethane ND
1.0 0.3474-95-3 Dibromomethane ND
1.0 0.4074-97-5 Chlorobromomethane ND
2.0 0.6475-00-3 Chloroethane ND
1.0 0.2375-01-4 Vinyl chloride ND
2.0 0.9475-09-2 Methylene Chloride ND
2.0 0.2675-15-0 Carbon disulfide ND
2.0 0.2575-25-2 Bromoform ND
1.0 0.1975-27-4 Dichlorobromomethane ND
1.0 0.2275-34-3 1,1-Dichloroethane ND
1.0 0.2375-35-4 1,1-Dichloroethene ND
2.0 0.2075-69-4 Trichlorofluoromethane ND
2.0 0.3075-71-8 Dichlorodifluoromethane ND
3.0 0.7376-13-1 1,1,2-Trichloro-1,2,2-trifluoroethan
e
ND
1.0 0.2478-87-5 1,2-Dichloropropane ND
10 4.678-93-3 2-Butanone (MEK)ND
1.0 0.2779-00-5 1,1,2-Trichloroethane ND
1.0 0.3079-01-6 Trichloroethene ND
5.0 1.679-20-9 Methyl acetate ND
1.0 0.2179-34-5 1,1,2,2-Tetrachloroethane ND
4.0 1.287-61-6 1,2,3-Trichlorobenzene ND
FORM I 8260D
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3:53:55 PM
Page 195 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:FB-01 Lab Sample ID:280-198899-4
Matrix:VMS14_0000004275.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
10/30/2024 00:00
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 08:24
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
2.0 0.5387-68-3 Hexachlorobutadiene ND
3.0 0.9991-20-3 Naphthalene ND
1.0 0.1195-47-6 o-Xylene ND
1.0 0.3495-49-8 2-Chlorotoluene ND
1.0 0.1495-50-1 1,2-Dichlorobenzene ND
1.0 0.1595-63-6 1,2,4-Trimethylbenzene ND
5.0 0.4296-12-8 1,2-Dibromo-3-Chloropropane ND
2.5 0.2896-18-4 1,2,3-Trichloropropane ND
3.0 0.1997-63-2 Ethyl methacrylate ND
1.0 0.1898-06-6 tert-Butylbenzene ND
1.0 0.1698-82-8 Isopropylbenzene ND
1.0 0.1999-87-6 4-Isopropyltoluene ND
1.0 0.111330-20-7 Xylenes, Total ND
1.0 0.32540-59-0 1,2-Dichloroethene, Total ND
1.0 0.14542-75-6 1,3-Dichloropropene, Total ND
1.0 0.19STL00209Trihalomethanes, Total ND
1.0 0.14STL00431Total BTEX ND
%RECCAS NO.LIMITSQSURROGATE
92 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr)
95 77-1201868-53-7 Dibromofluoromethane (Surr)
109 80-1252037-26-5 Toluene-d8 (Surr)
91 78-120460-00-4 4-Bromofluorobenzene (Surr)
FORM I 8260D
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Page 196 of 777
Report Date: 11-Nov-2024 16:14:46 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004275.D
Lims ID:280-198899-B-4
Client ID:FB-01
Sample Type:Client
Inject. Date:11-Nov-2024 08:24:53 ALS Bottle#:0 Worklist Smp#:17
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:280-198899-B-4
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:11-Nov-2024 16:14:22 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:11-Nov-2024 16:00:28
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.357 0.003 99 999067 50.0
* 2 Chlorobenzene-d5 119 7.926 7.926 0.000 85 235129 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.173 0.000 95 437738 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.842 4.839 0.003 94 228901 47.3
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.112 5.109 0.003 97 279630 46.2
$ 6 Toluene-d8 (Surr) 98 6.636 6.637 -0.001 93 1005373 54.3
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 89 379805 45.3
10 Dichlorodifluoromethane 85 1.791 ND
12 Chloromethane 50 1.974 ND
13 Vinyl chloride 62 2.090 ND
15 Bromomethane 94 2.389 ND
16 Chloroethane 64 2.489 ND
18 Trichlorofluoromethane 101 2.711 ND
21 Ethyl ether 59 2.936 ND
25 1,1-Dichloroethene 96 3.138 ND
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.141 ND
26 Acetone 43 3.164 ND 7
29 Iodomethane 142 3.267 ND
30 Carbon disulfide 76 3.334 ND
32 Methyl acetate 43 3.399 ND
33 3-Chloro-1-propene 41 3.418 ND
34 Methylene Chloride 84 3.518 ND
37 Methyl tert-butyl ether 73 3.714 ND
38 trans-1,2-Dichloroethene 96 3.727 ND
39 Hexane 57 3.929 ND
40 Vinyl acetate 43 4.032 ND
42 1,1-Dichloroethane 63 4.055 ND
45 2-Butanone (MEK) 43 4.456 ND
47 cis-1,2-Dichloroethene 96 4.482 ND
48 2,2-Dichloropropane 77 4.495 ND
52 Chlorobromomethane 128 4.662 ND
53 Tetrahydrofuran 42 4.678 ND
11/15/2024
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Report Date: 11-Nov-2024 16:14:46 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004275.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
54 Chloroform 83 4.720 ND
55 1,1,1-Trichloroethane 97 4.871 ND
56 Cyclohexane 56 4.936 ND
57 1,1-Dichloropropene 75 4.987 ND
59 Carbon tetrachloride 117 4.990 ND
60 Benzene 78 5.145 ND
61 1,2-Dichloroethane 62 5.167 ND
65 Trichloroethene 95 5.640 ND
67 Methylcyclohexane 55 5.842 ND
69 1,2-Dichloropropane 63 5.849 ND
71 Dibromomethane 93 5.923 ND
72 Dichlorobromomethane 83 6.045 ND
75 cis-1,3-Dichloropropene 75 6.402 ND
76 4-Methyl-2-pentanone (MIBK) 43 6.501 ND
77 Toluene 91 6.694 ND
78 trans-1,3-Dichloropropene 75 6.868 ND
79 Ethyl methacrylate 69 6.884 ND
80 1,1,2-Trichloroethane 97 7.045 ND
82 Tetrachloroethene 164 7.148 ND
83 1,3-Dichloropropane 76 7.196 ND
84 2-Hexanone 43 7.215 ND
85 Chlorodibromomethane 129 7.392 ND
86 Ethylene Dibromide 107 7.514 ND
88 Chlorobenzene 112 7.955 ND
89 1,1,1,2-Tetrachloroethane 131 8.022 ND
90 Ethylbenzene 106 8.029 ND
91 m-Xylene & p-Xylene 106 8.148 ND
92 o-Xylene 106 8.511 ND
93 Styrene 104 8.527 ND
94 Bromoform 173 8.710 ND
95 Isopropylbenzene 105 8.858 ND
98 1,1,2,2-Tetrachloroethane 83 9.141 ND
100 Bromobenzene 156 9.186 ND
101 1,2,3-Trichloropropane 110 9.209 ND
102 N-Propylbenzene 120 9.257 ND
103 2-Chlorotoluene 126 9.360 ND
104 1,3,5-Trimethylbenzene 105 9.431 ND
105 4-Chlorotoluene 126 9.479 ND
107 tert-Butylbenzene 119 9.746 ND
108 1,2,4-Trimethylbenzene 105 9.804 ND
109 sec-Butylbenzene 134 9.968 ND
110 1,3-Dichlorobenzene 146 10.099 ND
111 4-Isopropyltoluene 119 10.112 ND
112 1,4-Dichlorobenzene 146 10.196 ND
114 n-Butylbenzene 91 10.524 ND
115 1,2-Dichlorobenzene 146 10.559 ND
116 1,2-Dibromo-3-Chloropropane 157 11.344 ND
118 1,2,4-Trichlorobenzene 180 12.180 ND
119 Hexachlorobutadiene 225 12.321 ND
120 Naphthalene 128 12.453 ND
121 1,2,3-Trichlorobenzene 180 12.678 ND
S 154 1,3-Dichloropropene, Total 1 0.000 ND 7
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Report Date: 11-Nov-2024 16:14:46 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004275.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
S 156 Total BTEX 1 0.000 ND 7
S 151 1,2-Dichloroethene, Total 1 0.000 ND 7
S 152 Trihalomethanes, Total 1 0.000 ND 7
S 155 Xylenes, Total 106 0.000 ND 7
QC Flag Legend
Processing Flags
7 - Failed Limit of Detection
Reagents:
mv-IS_SS_00089 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 199 of 777
Report Date: 11-Nov-2024 16:14:46 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004275.D
Injection Date:11-Nov-2024 08:24:53 Instrument ID:VMS_MS14 Operator ID:MED
Lims ID:280-198899-B-4 Lab Sample ID:280-198899-4 Worklist Smp#:17
Client ID:FB-01
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
Y ( X10
0
0
0
0
)
0000004275[MS Quad Chro]:Total
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11/15/2024
3:53:55 PM
Page 200 of 777
Report Date: 11-Nov-2024 16:14:46 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004275.D
Lims ID:280-198899-B-4
Client ID:FB-01
Sample Type:Client
Inject. Date:11-Nov-2024 08:24:53 ALS Bottle#:0 Worklist Smp#:17
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:280-198899-B-4
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:11-Nov-2024 16:14:22 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:11-Nov-2024 16:00:28
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 47.3 94.54
$5 1,2-Dichloroethane-d4 (Surr)50.0 46.2 92.47
$6 Toluene-d8 (Surr)50.0 54.3 108.50
$7 4-Bromofluorobenzene (Surr)50.0 45.3 90.69
11/15/2024
3:53:55 PM
Page 201 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:DS-01 Lab Sample ID:280-198899-5
Matrix:VMS14_0000004285.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
10/30/2024 00:00
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:100
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 11:50
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
100 14100-41-4 Ethylbenzene ND
100 13100-42-5 Styrene ND
100 1610061-01-5 cis-1,3-Dichloropropene ND
100 1410061-02-6 trans-1,3-Dichloropropene ND
100 18103-65-1 N-Propylbenzene ND
100 23104-51-8 n-Butylbenzene ND
100 21106-43-4 4-Chlorotoluene ND
100 39106-46-7 1,4-Dichlorobenzene ND
100 18106-93-4 Ethylene Dibromide ND
200 46107-05-1 3-Chloro-1-propene ND
100 28107-06-2 1,2-Dichloroethane ND
300 36108-05-4 Vinyl acetate ND
500 98108-10-1 4-Methyl-2-pentanone (MIBK)ND
100 12108-67-8 1,3,5-Trimethylbenzene ND
100 19108-86-1 Bromobenzene ND
100 31108-87-2 Methylcyclohexane ND
100 32J108-88-3 Toluene 77
100 9.2108-90-7 Chlorobenzene ND
700 84109-99-9 Tetrahydrofuran ND
200 16110-54-3 Hexane ND
100 44110-82-7 Cyclohexane ND
100 58120-82-1 1,2,4-Trichlorobenzene ND
100 28124-48-1 Chlorodibromomethane ND
100 40127-18-4 Tetrachloroethene ND
100 20135-98-8 sec-Butylbenzene ND
100 17142-28-9 1,3-Dichloropropane ND
100 32156-59-2 cis-1,2-Dichloroethene ND
100 37156-60-5 trans-1,2-Dichloroethene ND
500 251634-04-4 Methyl tert-butyl ether ND
200 36179601-23-1 m-Xylene & p-Xylene ND
100 33541-73-1 1,3-Dichlorobenzene ND
100 2356-23-5 Carbon tetrachloride ND
FORM I 8260D
11/15/2024
3:53:55 PM
Page 202 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:DS-01 Lab Sample ID:280-198899-5
Matrix:VMS14_0000004285.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
10/30/2024 00:00
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:100
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 11:50
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
100 19563-58-6 1,1-Dichloropropene ND
500 81591-78-6 2-Hexanone ND
100 17594-20-7 2,2-Dichloropropane ND
200 3560-29-7 Ethyl ether ND
100 16630-20-6 1,1,1,2-Tetrachloroethane ND
1500 66067-64-1 Acetone ND
100 3667-66-3 Chloroform ND
100 1471-43-2 Benzene ND
100 3971-55-6 1,1,1-Trichloroethane ND
500 240*174-83-9 Bromomethane ND
200 2374-87-3 Chloromethane ND
500 26074-88-4 Iodomethane ND
100 3474-95-3 Dibromomethane ND
100 4074-97-5 Chlorobromomethane ND
200 6475-00-3 Chloroethane ND
100 2375-01-4 Vinyl chloride ND
200 9475-09-2 Methylene Chloride ND
200 2675-15-0 Carbon disulfide ND
200 2575-25-2 Bromoform ND
100 1975-27-4 Dichlorobromomethane ND
100 2275-34-3 1,1-Dichloroethane ND
100 2375-35-4 1,1-Dichloroethene ND
200 2075-69-4 Trichlorofluoromethane ND
200 3075-71-8 Dichlorodifluoromethane ND
100 2478-87-5 1,2-Dichloropropane 150
1000 46078-93-3 2-Butanone (MEK)ND
100 2779-00-5 1,1,2-Trichloroethane ND
100 3079-01-6 Trichloroethene ND
500 16079-20-9 Methyl acetate ND
100 2179-34-5 1,1,2,2-Tetrachloroethane ND
400 12087-61-6 1,2,3-Trichlorobenzene ND
200 5387-68-3 Hexachlorobutadiene ND
FORM I 8260D
11/15/2024
3:53:55 PM
Page 203 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:DS-01 Lab Sample ID:280-198899-5
Matrix:VMS14_0000004285.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
10/30/2024 00:00
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:100
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 11:50
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
300 9991-20-3 Naphthalene ND
100 1195-47-6 o-Xylene ND
100 3495-49-8 2-Chlorotoluene ND
100 1495-50-1 1,2-Dichlorobenzene ND
100 1595-63-6 1,2,4-Trimethylbenzene ND
500 4296-12-8 1,2-Dibromo-3-Chloropropane ND
250 2896-18-4 1,2,3-Trichloropropane ND
300 1997-63-2 Ethyl methacrylate ND
100 1898-06-6 tert-Butylbenzene ND
100 1698-82-8 Isopropylbenzene ND
100 1999-87-6 4-Isopropyltoluene ND
100 111330-20-7 Xylenes, Total ND
100 32540-59-0 1,2-Dichloroethene, Total ND
100 14542-75-6 1,3-Dichloropropene, Total ND
100 19STL00209Trihalomethanes, Total ND
100 14JSTL00431Total BTEX 77
%RECCAS NO.LIMITSQSURROGATE
90 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr)
94 77-1201868-53-7 Dibromofluoromethane (Surr)
106 80-1252037-26-5 Toluene-d8 (Surr)
92 78-120460-00-4 4-Bromofluorobenzene (Surr)
FORM I 8260D
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Report Date: 11-Nov-2024 16:15:19 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004285.D
Lims ID:280-198899-B-5
Client ID:DS-01
Sample Type:Client
Inject. Date:11-Nov-2024 11:50:28 ALS Bottle#:0 Worklist Smp#:27
Purge Vol: 5.000 mL Dil. Factor:100.0000
Sample Info:280-198899-B-5 100x
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:11-Nov-2024 16:14:22 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:11-Nov-2024 16:07:35
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.357 0.003 99 1035611 50.0
* 2 Chlorobenzene-d5 119 7.929 7.926 0.003 85 250417 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.177 10.173 0.004 95 449271 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.842 4.839 0.003 94 235703 47.0
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 97 283152 45.2
$ 6 Toluene-d8 (Surr) 98 6.636 6.637 -0.001 92 1047468 53.1
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 90 396203 46.1
10 Dichlorodifluoromethane 85 1.791 ND U
12 Chloromethane 50 1.974 ND
13 Vinyl chloride 62 2.090 ND
15 Bromomethane 94 2.389 ND
16 Chloroethane 64 2.489 ND
18 Trichlorofluoromethane 101 2.711 ND
21 Ethyl ether 59 2.936 ND
25 1,1-Dichloroethene 96 3.138 ND U
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.141 3.141 0.000 93 515557 201.7 E
26 Acetone 43 3.164 ND
29 Iodomethane 142 3.267 ND
30 Carbon disulfide 76 3.334 ND
32 Methyl acetate 43 3.399 ND
33 3-Chloro-1-propene 41 3.418 ND
34 Methylene Chloride 84 3.518 ND
37 Methyl tert-butyl ether 73 3.714 ND
38 trans-1,2-Dichloroethene 96 3.727 ND
39 Hexane 57 3.929 ND
40 Vinyl acetate 43 4.032 ND
42 1,1-Dichloroethane 63 4.055 ND
45 2-Butanone (MEK) 43 4.456 ND
47 cis-1,2-Dichloroethene 96 4.482 ND
48 2,2-Dichloropropane 77 4.495 ND
52 Chlorobromomethane 128 4.662 ND
53 Tetrahydrofuran 42 4.678 ND
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Report Date: 11-Nov-2024 16:15:19 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004285.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
54 Chloroform 83 4.720 ND
55 1,1,1-Trichloroethane 97 4.871 ND
56 Cyclohexane 56 4.936 ND
57 1,1-Dichloropropene 75 4.987 ND
59 Carbon tetrachloride 117 4.990 ND
60 Benzene 78 5.145 ND
61 1,2-Dichloroethane 62 5.167 ND
65 Trichloroethene 95 5.640 ND
67 Methylcyclohexane 55 5.842 ND
69 1,2-Dichloropropane 63 5.852 5.849 0.003 94 6996 1.54
71 Dibromomethane 93 5.923 ND
72 Dichlorobromomethane 83 6.045 ND
75 cis-1,3-Dichloropropene 75 6.402 ND
76 4-Methyl-2-pentanone (MIBK) 43 6.501 ND
77 Toluene 91 6.698 6.694 0.004 97 15113 0.7721
78 trans-1,3-Dichloropropene 75 6.868 ND
79 Ethyl methacrylate 69 6.884 ND
80 1,1,2-Trichloroethane 97 7.045 ND
82 Tetrachloroethene 164 7.148 ND
83 1,3-Dichloropropane 76 7.196 ND
84 2-Hexanone 43 7.215 ND
85 Chlorodibromomethane 129 7.392 ND
86 Ethylene Dibromide 107 7.514 ND
88 Chlorobenzene 112 7.955 ND
89 1,1,1,2-Tetrachloroethane 131 8.022 ND
90 Ethylbenzene 106 8.029 ND
91 m-Xylene & p-Xylene 106 8.132 8.148 -0.016 1 1384 0.1790 M
92 o-Xylene 106 8.511 ND
93 Styrene 104 8.527 ND
94 Bromoform 173 8.710 ND
95 Isopropylbenzene 105 8.858 ND
98 1,1,2,2-Tetrachloroethane 83 9.141 ND
100 Bromobenzene 156 9.186 ND
101 1,2,3-Trichloropropane 110 9.209 ND
102 N-Propylbenzene 120 9.257 ND
103 2-Chlorotoluene 126 9.360 ND
104 1,3,5-Trimethylbenzene 105 9.431 ND
105 4-Chlorotoluene 126 9.479 ND
107 tert-Butylbenzene 119 9.746 ND
108 1,2,4-Trimethylbenzene 105 9.804 ND
109 sec-Butylbenzene 134 9.968 ND
110 1,3-Dichlorobenzene 146 10.099 ND
111 4-Isopropyltoluene 119 10.112 ND
112 1,4-Dichlorobenzene 146 10.196 ND
114 n-Butylbenzene 91 10.524 ND
115 1,2-Dichlorobenzene 146 10.559 ND
116 1,2-Dibromo-3-Chloropropane 157 11.344 ND
118 1,2,4-Trichlorobenzene 180 12.180 ND
119 Hexachlorobutadiene 225 12.321 ND
120 Naphthalene 128 12.453 ND
121 1,2,3-Trichlorobenzene 180 12.678 ND
S 154 1,3-Dichloropropene, Total 1 0.000 ND 7
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Report Date: 11-Nov-2024 16:15:19 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004285.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
S 156 Total BTEX 1 0 0.9511
S 151 1,2-Dichloroethene, Total 1 0.000 ND 7
S 152 Trihalomethanes, Total 1 0.000 ND 7
S 155 Xylenes, Total 106 0 0.1790
QC Flag Legend
Processing Flags
E - Exceeded Maximum Amount
7 - Failed Limit of Detection
Review Flags
M - Manually Integrated
U - Marked Undetected
Reagents:
mv-IS_SS_00089 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 207 of 777
Report Date: 11-Nov-2024 16:15:19 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004285.D
Injection Date:11-Nov-2024 11:50:28 Instrument ID:VMS_MS14 Operator ID:MED
Lims ID:280-198899-B-5 Lab Sample ID:280-198899-5 Worklist Smp#:27
Client ID:DS-01
Purge Vol: 5.000 mL Dil. Factor:100.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
Y ( X10
0
0
0
0
)
0000004285[MS Quad Chro]:Total

1
,1,2-
Tri
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11/15/2024
3:53:55 PM
Page 208 of 777
Report Date: 11-Nov-2024 16:15:19 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004285.D
Lims ID:280-198899-B-5
Client ID:DS-01
Sample Type:Client
Inject. Date:11-Nov-2024 11:50:28 ALS Bottle#:0 Worklist Smp#:27
Purge Vol: 5.000 mL Dil. Factor:100.0000
Sample Info:280-198899-B-5 100x
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:11-Nov-2024 16:14:22 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:11-Nov-2024 16:07:35
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 47.0 93.91
$5 1,2-Dichloroethane-d4 (Surr)50.0 45.2 90.33
$6 Toluene-d8 (Surr)50.0 53.1 106.15
$7 4-Bromofluorobenzene (Surr)50.0 46.1 92.18
11/15/2024
3:53:55 PM
Page 209 of 777
Report Date: 11-Nov-2024 16:15:19 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004285.D
Injection Date:11-Nov-2024 11:50:28 Instrument ID:VMS_MS14
Lims ID:280-198899-B-5 Lab Sample ID:280-198899-5
Client ID:DS-01
Operator ID:MED ALS Bottle#:0 Worklist Smp#:27
Purge Vol: 5.000 mL Dil. Factor:100.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
77 Toluene, CAS: 108-88-3
30 70 110 150 190 230 270 310 350
m/z
0
2
4
6
8
10
Y ( X10
0
0
)
Raw Spec:Scan 1776(6.70)
91
92
65
30 70 110 150 190 230 270 310 350m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1775(6.70), Qvalue=97 Sig Qvalue=91
91
92
65 89
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X10
0
)
Ref Spec: 77 Toluene (NIST98.L)
91
92
65
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 6.700 min.(Qvalue: 97)
63
65
6.1 6.4 6.7 7.0
Min
RT
0
2
4
6
8
10
Y ( X10
0
0
)
0000004285[MS Quad Chro]:m/z 91

6
.
6
9
8
6.1 6.4 6.7 7.0Min
RT
0
9
18
27
36
45
54
Y ( X10
0
)
0000004285[MS Quad Chro]:m/z 92

6
.
6
9
8
6.1 6.4 6.7 7.0
Min
RT
0
3
6
9
12
15
Y ( X10
0
)
0000004285[MS Quad Chro]:m/z 65
6.1 6.4 6.7 7.0
Min
0
2
4
6
8
10
Y ( X10
0
0
)
0000004285[MS Quad Chro]:m/z 91
0000004285[MS Quad Chro]:m/z 92
0000004285[MS Quad Chro]:m/z 65
11/15/2024
3:53:55 PM
Page 210 of 777
Report Date: 11-Nov-2024 16:15:19 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004285.D
Injection Date:11-Nov-2024 11:50:28 Instrument ID:VMS_MS14
Lims ID:280-198899-B-5 Lab Sample ID:280-198899-5
Client ID:DS-01
Operator ID:MED ALS Bottle#:0 Worklist Smp#:27
Purge Vol: 5.000 mL Dil. Factor:100.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
69 1,2-Dichloropropane, CAS: 78-87-5
30 70 110 150 190 230 270 310 350
m/z
0
6
12
18
24
30
36
42
Y ( X10
0
)
Raw Spec:Scan 1513(5.85)
63
62
76
78
30 70 110 150 190 230 270 310 350m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1512(5.85), Qvalue=94 Sig Qvalue=99
63
62
76
78
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X10
0
)
Ref Spec: 69 1,2-Dichloropropane (NIST98.L)
63
62
65
77
112
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 5.850 min.(Qvalue: 94)
76 78
5.3 5.6 5.9 6.2
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
)
0000004285[MS Quad Chro]:m/z 63

5
.
8
5
2
5.3 5.6 5.9 6.2Min
RT
0
3
6
9
12
15
18
Y ( X10
0
)
0000004285[MS Quad Chro]:m/z 65

5
.
8
5
2
5.3 5.6 5.9 6.2
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
)
0000004285[MS Quad Chro]:m/z 41

5
.
8
5
2
5.3 5.6 5.9 6.2
Min
0
4
8
12
16
20
Y ( X10
0
0
)
0000004285[MS Quad Chro]:m/z 63
0000004285[MS Quad Chro]:m/z 65
0000004285[MS Quad Chro]:m/z 41
11/15/2024
3:53:55 PM
Page 211 of 777
Report Date: 11-Nov-2024 16:15:19 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004285.D
Injection Date:11-Nov-2024 11:50:28 Instrument ID:VMS_MS14
Lims ID:280-198899-B-5 Lab Sample ID:280-198899-5
Client ID:DS-01
Operator ID:MED ALS Bottle#:0 Worklist Smp#:27
Purge Vol: 5.000 mL Dil. Factor:100.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
91 m-Xylene & p-Xylene, CAS: 179601-23-1
Signal: 1
Processing Integration Results
RT: 8.14
Area: 556
Amount: 0.071912
Amount Units: ug/l
7.8 8.0 8.2 8.4
Min
0
6
12
18
24
30
36
42
48
54
60
66
72
78
84
90
Y ( X10
)
0000004285[MS Quad Chro]:m/z 106

8
.
1
4
1
Manual Integration Results
RT: 8.13
Area: 1384
Amount: 0.179003
Amount Units: ug/l
7.8 8.0 8.2 8.4
Min
RT
0
7
14
21
28
35
42
49
56
63
70
77
84
Y ( X10
)
0000004285[MS Quad Chro]:m/z 106

8
.
1
3
2
Reviewer: LP8K, 11-Nov-2024 16:07:30 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 212 of 777
Report Date: 11-Nov-2024 16:15:19 Chrom Revision: 2.3 17-Oct-2024 11:42:22
User Disabled Compound Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004285.D
Injection Date:11-Nov-2024 11:50:28 Instrument ID:VMS_MS14
Lims ID:280-198899-B-5 Lab Sample ID:280-198899-5
Client ID:DS-01
Operator ID:MED ALS Bottle#:0 Worklist Smp#:27
Purge Vol: 5.000 mL Dil. Factor:100.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
25 1,1-Dichloroethene, CAS: 75-35-4
Processing Results
30 70 110 150 190 230 270 310 350m/z
0
5
10
15
20
25
30
Y ( X10
0
0
0
)
Raw Spec:Scan 670(3.14)
101
151
103
153
85
66 105 155
30 70 110 150 190 230 270 310 350
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 669(3.14), Qvalue=33
151
153
116
117 15578105
30 70 110 150 190 230 270 310 350
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 25 1,1-Dichloroethene (NIST98.L)
61
96
98
63
60
100
2.9 3.2Min
RT
0
3
6
9
12
Y ( X10
0
)
0000004285[MS Quad Chro]:m/z 96

3
.
1
4
1
2.9 3.2
Min
RT
0
15
30
45
60
75
90
Y ( X10
)
0000004285[MS Quad Chro]:m/z 61

3
.
1
2
8
2.9 3.2
Min
RT
0
8
16
24
32
40
Y ( X10
)
0000004285[MS Quad Chro]:m/z 98
RT Mass Response Amount
3.14 96.00 2036 0.708972
3.13 61.00 1008
3.14 98.00 0
Reviewer: LP8K, 11-Nov-2024 16:07:19 -07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
11/15/2024
3:53:55 PM
Page 213 of 777
Report Date: 11-Nov-2024 16:15:19 Chrom Revision: 2.3 17-Oct-2024 11:42:22
User Disabled Compound Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004285.D
Injection Date:11-Nov-2024 11:50:28 Instrument ID:VMS_MS14
Lims ID:280-198899-B-5 Lab Sample ID:280-198899-5
Client ID:DS-01
Operator ID:MED ALS Bottle#:0 Worklist Smp#:27
Purge Vol: 5.000 mL Dil. Factor:100.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
10 Dichlorodifluoromethane, CAS: 75-71-8
Processing Results
30 70 110 150 190 230 270 310 350m/z
0
6
12
18
24
30
36
42
Y ( X10
0
0
)
Raw Spec:Scan 239(1.76)
116
11885
30 70 110 150 190 230 270 310 350
m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 239(1.76), Qvalue=49
116
11885
30 70 110 150 190 230 270 310 350
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 10 Dichlorodifluoromethane (NIST98.L)
85
87
50 101
1.5 1.8 2.1Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
)
0000004285[MS Quad Chro]:m/z 85

1
.
7
5
6
1.5 1.8 2.1
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
)
0000004285[MS Quad Chro]:m/z 87

1
.
7
5
6
1.5 1.8 2.1
Min
RT
0
4
8
12
16
20
24
Y ( X10
0
)
0000004285[MS Quad Chro]:m/z 50

1
.
7
5
6
RT Mass Response Amount
1.76 85.00 14628 2.991668
1.76 87.00 4524
1.76 50.00 2674
Reviewer: LP8K, 11-Nov-2024 16:07:05 -07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
11/15/2024
3:53:55 PM
Page 214 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:DS-01 DL Lab Sample ID:280-198899-5 DL
Matrix:X4_00009419.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
10/30/2024 00:00
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:500
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/13/2024 15:34
ID:RXI-624SilMS
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674813 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_X4
CAS NO.COMPOUND NAME RESULT Q MDLRL
1500 36076-13-1 1,1,2-Trichloro-1,2,2-trifluoroethan
e
22000
%RECCAS NO.LIMITSQSURROGATE
106 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr)
103 77-1201868-53-7 Dibromofluoromethane (Surr)
97 80-1252037-26-5 Toluene-d8 (Surr)
103 78-120460-00-4 4-Bromofluorobenzene (Surr)
FORM I 8260D
11/15/2024
3:53:55 PM
Page 215 of 777
Report Date: 13-Nov-2024 23:13:17 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009419.D
Lims ID:280-198899-A-5
Client ID:DS-01
Sample Type:Client
Inject. Date:13-Nov-2024 15:34:30 ALS Bottle#:25 Worklist Smp#:30
Purge Vol: 5.000 mL Dil. Factor:500.0000
Sample Info:280-198899-A-5
Operator ID:wickhamt Instrument ID:VMS_X4
Method:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:13-Nov-2024 23:12:49 Calib Date:29-Oct-2024 20:00:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1653
First Level Reviewer: AK2J Date:13-Nov-2024 23:11:03
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.207 5.207 0.000 97 1481638 50.0
* 2 Chlorobenzene-d5 119 7.736 7.736 0.000 91 329468 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.961 9.961 0.000 97 512762 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.701 4.697 0.004 93 309926 51.6
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.966 4.962 0.004 0 478069 53.1
$ 6 Toluene-d8 (Surr) 98 6.463 6.463 0.000 95 1505449 48.6
$ 7 4-Bromofluorobenzene (Surr) 95 8.832 8.832 0.000 84 515986 51.6
$ 8 BFB 95 8.832 8.832 0.000 83 515986 NR
9 Dichlorodifluoromethane 85 1.709 1.749 -0.040 56 2943 0.3476
10 Chloromethane 50 1.934 ND
11 Vinyl chloride 62 2.035 ND
12 Bromomethane 94 2.312 ND 7
13 Chloroethane 64 2.412 ND
15 Propene oxide 58 2.504 ND
14 Dichlorofluoromethane 67 2.593 ND
16 Trichlorofluoromethane 101 2.629 ND
17 Ethanol 45 2.757 ND
18 Ethyl ether 59 2.846 ND
19 Acrolein 56 2.958 ND
21 1,1-Dichloroethene 96 3.042 ND
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.042 3.042 0.000 97 180985 43.2
22 Acetone 43 3.062 ND 7
23 Isopropyl alcohol 45 3.151 ND 7
24 Iodomethane 142 3.167 ND
25 Carbon disulfide 76 3.227 ND 7
26 Acetonitrile 41 3.275 ND 7
27 Methyl acetate 43 3.291 ND
28 3-Chloro-1-propene 41 3.315 ND U
29 Methylene Chloride 84 3.412 ND 7
30 2-Methyl-2-propanol 59 3.460 ND
31 Acrylonitrile 53 3.576 ND
32 Methyl tert-butyl ether 73 3.596 ND 7
11/15/2024
3:53:55 PM
Page 216 of 777
Report Date: 13-Nov-2024 23:13:17 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009419.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
33 trans-1,2-Dichloroethene 96 3.613 ND
34 Hexane 57 3.805 ND
35 Vinyl acetate 43 3.910 ND
37 Isopropyl ether 87 3.934 ND
36 1,1-Dichloroethane 63 3.934 ND
38 2-Chloro-1,3-butadiene 53 3.986 ND
39 Tert-butyl ethyl ether 59 4.191 ND
40 2-Butanone (MEK) 43 4.319 ND
41 Ethyl acetate 43 4.331 ND
42 cis-1,2-Dichloroethene 96 4.347 ND
43 2,2-Dichloropropane 77 4.355 ND
44 Propionitrile 54 4.371 ND
45 sec-Butyl Alcohol 45 4.432 ND
46 Methacrylonitrile 41 4.484 ND
47 Chlorobromomethane 128 4.524 ND
48 Tetrahydrofuran 42 4.536 ND
49 Chloroform 83 4.580 ND
50 1,1,1-Trichloroethane 97 4.725 ND
51 Cyclohexane 56 4.789 ND
52 1,1-Dichloropropene 75 4.837 ND
53 Carbon tetrachloride 117 4.845 ND
54 Isobutyl alcohol 41 4.853 ND U
55 Benzene 78 4.998 4.994 0.004 94 53561 1.61
56 1,2-Dichloroethane 62 5.022 ND
57 Tert-amyl methyl ether 73 5.058 ND
58 n-Heptane 43 5.174 ND
59 n-Butanol 56 5.347 ND
60 Trichloroethene 95 5.484 ND
61 2-Pentanone 43 5.584 ND
62 Methylcyclohexane 55 5.676 ND
64 Methyl methacrylate 100 5.688 ND
63 1,2-Dichloropropane 63 5.692 5.688 0.004 88 6648 0.7027
65 1,4-Dioxane 88 5.729 ND
66 Dibromomethane 93 5.761 ND
67 Dichlorobromomethane 83 5.881 ND
68 2-Nitropropane 41 6.050 ND
69 2-Chloroethyl vinyl ether 63 6.082 ND
70 cis-1,3-Dichloropropene 75 6.231 ND
71 4-Methyl-2-pentanone (MIBK) 43 6.331 ND
72 Toluene 91 6.520 ND
73 trans-1,3-Dichloropropene 75 6.692 ND
74 Ethyl methacrylate 69 6.712 ND
75 1,1,2-Trichloroethane 97 6.869 ND
76 Tetrachloroethene 164 6.961 ND
77 1,3-Dichloropropane 76 7.018 ND
78 2-Hexanone 43 7.034 ND
79 Chlorodibromomethane 129 7.210 ND
80 Ethylene Dibromide 107 7.331 ND
81 1-Chlorohexane 91 7.716 ND 7
82 Chlorobenzene 112 7.764 ND
83 1,1,1,2-Tetrachloroethane 131 7.833 ND
84 Ethylbenzene 106 7.837 ND
11/15/2024
3:53:55 PM
Page 217 of 777
Report Date: 13-Nov-2024 23:13:17 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009419.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
85 m-Xylene & p-Xylene 106 7.953 ND U
86 o-Xylene 106 8.318 ND
87 Styrene 104 8.331 ND
88 Bromoform 173 8.515 ND
89 Isopropylbenzene 105 8.656 ND
90 cis-1,4-Dichloro-2-butene 53 8.708 ND
91 Cyclohexanone 55 8.760 ND U
92 1,1,2,2-Tetrachloroethane 83 8.941 ND
94 trans-1,4-Dichloro-2-butene 53 8.981 ND
93 Bromobenzene 156 8.981 ND
95 1,2,3-Trichloropropane 110 9.009 ND
96 N-Propylbenzene 120 9.057 ND
97 2-Chlorotoluene 126 9.158 ND
98 1,3,5-Trimethylbenzene 105 9.226 ND
99 4-Chlorotoluene 126 9.274 ND
101 Pentachloroethane 167 9.411 ND
100 tert-Butylbenzene 119 9.539 ND
102 1,2,4-Trimethylbenzene 105 9.599 ND
103 sec-Butylbenzene 134 9.756 ND
104 1,3-Dichlorobenzene 146 9.888 ND
105 4-Isopropyltoluene 119 9.905 ND
106 1,4-Dichlorobenzene 146 9.985 ND
107 1,2,3-Trimethylbenzene 105 10.005 ND
108 n-Butylbenzene 91 10.310 ND
109 1,2-Dichlorobenzene 146 10.346 ND
110 1,2-Dibromo-3-Chloropropane 157 11.125 ND
111 1,3,5-Trichlorobenzene 180 11.310 ND
112 1,2,4-Trichlorobenzene 180 11.948 ND
113 Hexachlorobutadiene 225 12.085 ND
114 Naphthalene 128 12.221 ND
115 1,2,3-Trichlorobenzene 180 12.438 ND
116 Ethylene oxide TIC 1 0.000 ND
117 t-Amyl alcohol 1 0.000 ND
118 Ethyl acrylate 55 0.000 ND
119 1-Chloro-1-fluoroethane TIC 1 0.000 ND
120 Tetrahydrothiophene TIC 1 0.000 ND
121 Propene oxide TIC 58 5.334 ND
S 122 1,2-Dichloroethene, Total (URS) 96 2.000 ND 7
S 129 1,2-Dichloroethene, Total 1 0.000 ND 7
S 123 Xylenes, Total (URS) 1 0.000 ND 7
S 128 TAH 1 0 0
S 127 Trihalomethanes, Total 1 0.000 ND 7
S 125 Xylenes, Total 106 0.000 ND 7
S 126 Total BTEX 1 0 1.61
S 124 1,3-Dichloropropene, Total 1 0.000 ND 7
T 130 Dichloroacetonitrile TIC 74 1.000 ND
T 134 2-Butoxyethanol TIC 1 0.000 ND
T 133 Dicyclopentadiene TIC 1 0.000 ND
T 132 1-Chlorohexane TIC 1 0.000 ND
T 131 Methyl cyclohexane TIC 1 0.000 ND
T 140 2,3-Dichloro-1-propene TIC 75 0.000 ND
T 139 Propene TIC 1 0.000 ND
11/15/2024
3:53:55 PM
Page 218 of 777
Report Date: 13-Nov-2024 23:13:17 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009419.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
T 138 n-Nonane TIC 1 0.000 ND
T 137 1,3-Butadiene TIC 1 0.000 ND
T 136 Cyclohexane TIC 1 0.000 ND
T 135 4-Ethyltoluene TIC 1 0.000 ND
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
7 - Failed Limit of Detection
Review Flags
U - Marked Undetected
Reagents:
mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 219 of 777
Report Date: 13-Nov-2024 23:13:17 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009419.D
Injection Date:13-Nov-2024 15:34:30 Instrument ID:VMS_X4 Operator ID:wickhamt
Lims ID:280-198899-A-5 Lab Sample ID:280-198899-5 Worklist Smp#:30
Client ID:DS-01
Purge Vol: 5.000 mL Dil. Factor:500.0000 ALS Bottle#:25
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0
Min
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11/15/2024
3:53:55 PM
Page 220 of 777
Report Date: 13-Nov-2024 23:13:17 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009419.D
Lims ID:280-198899-A-5
Client ID:DS-01
Sample Type:Client
Inject. Date:13-Nov-2024 15:34:30 ALS Bottle#:25 Worklist Smp#:30
Purge Vol: 5.000 mL Dil. Factor:500.0000
Sample Info:280-198899-A-5
Operator ID:wickhamt Instrument ID:VMS_X4
Method:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:13-Nov-2024 23:12:49 Calib Date:29-Oct-2024 20:00:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1653
First Level Reviewer: AK2J Date:13-Nov-2024 23:11:03
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 51.6 51616.33
$5 1,2-Dichloroethane-d4 (Surr)50.0 53.1 53102.20
$6 Toluene-d8 (Surr)50.0 48.6 48630.93
$7 4-Bromofluorobenzene (Surr)50.0 51.6 51598.46
11/15/2024
3:53:55 PM
Page 221 of 777
Report Date: 13-Nov-2024 23:13:17 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009419.D
Injection Date:13-Nov-2024 15:34:30 Instrument ID:VMS_X4
Lims ID:280-198899-A-5 Lab Sample ID:280-198899-5
Client ID:DS-01
Operator ID:wickhamt ALS Bottle#:25 Worklist Smp#:30
Purge Vol: 5.000 mL Dil. Factor:500.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
20 1,1,2-Trichloro-1,2,2-trifluoroethane, CAS: 76-13-1
30 70 110 150 190 230 270 310 350
m/z
0
2
4
6
8
10
12
14
Y ( X
1
0
0
0
0
)
Raw Spec:Scan 487(3.04)
101
151103
85 153
66
116 155
30 70 110 150 190 230 270 310 350m/z
0
13
26
39
52
65
78
91
Y ( X
1
0
)
Amdis Enhanced Spec: Scan 487(3.04), Qvalue=97 Sig Qvalue=99
101
151
15385
66
116 155
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X
1
0
0
)
Ref Spec: 20 1,1,2-Trichloro-1,2,2-trifluoroethane (NIST98.L)
101
151103
85 153
66
105 155
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 3.040 min.(Qvalue: 97)
151116 153
2.5 2.8 3.1 3.4
Min
RT
0
2
4
6
8
10
Y ( X
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3
6
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0
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m/z 151.0
m/z 101.0
m/z 153.0
11/15/2024
3:53:55 PM
Page 222 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:Trip Blank Lab Sample ID:280-198899-6
Matrix:VMS14_0000004274.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
10/30/2024 00:00
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 08:04
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.14100-41-4 Ethylbenzene ND
1.0 0.13100-42-5 Styrene ND
1.0 0.1610061-01-5 cis-1,3-Dichloropropene ND
1.0 0.1410061-02-6 trans-1,3-Dichloropropene ND
1.0 0.18103-65-1 N-Propylbenzene ND
1.0 0.23104-51-8 n-Butylbenzene ND
1.0 0.21106-43-4 4-Chlorotoluene ND
1.0 0.39106-46-7 1,4-Dichlorobenzene ND
1.0 0.18106-93-4 Ethylene Dibromide ND
2.0 0.46107-05-1 3-Chloro-1-propene ND
1.0 0.28107-06-2 1,2-Dichloroethane ND
3.0 0.36108-05-4 Vinyl acetate ND
5.0 0.98108-10-1 4-Methyl-2-pentanone (MIBK)ND
1.0 0.12108-67-8 1,3,5-Trimethylbenzene ND
1.0 0.19108-86-1 Bromobenzene ND
1.0 0.31108-87-2 Methylcyclohexane ND
1.0 0.32108-88-3 Toluene ND
1.0 0.092108-90-7 Chlorobenzene ND
7.0 0.84J109-99-9 Tetrahydrofuran 1.2
2.0 0.16110-54-3 Hexane ND
1.0 0.44110-82-7 Cyclohexane ND
1.0 0.58120-82-1 1,2,4-Trichlorobenzene ND
1.0 0.28124-48-1 Chlorodibromomethane ND
1.0 0.40127-18-4 Tetrachloroethene ND
1.0 0.20135-98-8 sec-Butylbenzene ND
1.0 0.17142-28-9 1,3-Dichloropropane ND
1.0 0.32156-59-2 cis-1,2-Dichloroethene ND
1.0 0.37156-60-5 trans-1,2-Dichloroethene ND
5.0 0.251634-04-4 Methyl tert-butyl ether ND
2.0 0.36179601-23-1 m-Xylene & p-Xylene ND
1.0 0.33541-73-1 1,3-Dichlorobenzene ND
1.0 0.2356-23-5 Carbon tetrachloride ND
FORM I 8260D
11/15/2024
3:53:55 PM
Page 223 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:Trip Blank Lab Sample ID:280-198899-6
Matrix:VMS14_0000004274.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
10/30/2024 00:00
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 08:04
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.19563-58-6 1,1-Dichloropropene ND
5.0 0.81591-78-6 2-Hexanone ND
1.0 0.17594-20-7 2,2-Dichloropropane ND
2.0 0.3560-29-7 Ethyl ether ND
1.0 0.16630-20-6 1,1,1,2-Tetrachloroethane ND
15 6.667-64-1 Acetone ND
1.0 0.3667-66-3 Chloroform ND
1.0 0.1471-43-2 Benzene ND
1.0 0.3971-55-6 1,1,1-Trichloroethane ND
5.0 2.4*174-83-9 Bromomethane ND
2.0 0.2374-87-3 Chloromethane ND
5.0 2.674-88-4 Iodomethane ND
1.0 0.3474-95-3 Dibromomethane ND
1.0 0.4074-97-5 Chlorobromomethane ND
2.0 0.6475-00-3 Chloroethane ND
1.0 0.2375-01-4 Vinyl chloride ND
2.0 0.9475-09-2 Methylene Chloride ND
2.0 0.2675-15-0 Carbon disulfide ND
2.0 0.2575-25-2 Bromoform ND
1.0 0.1975-27-4 Dichlorobromomethane ND
1.0 0.2275-34-3 1,1-Dichloroethane ND
1.0 0.2375-35-4 1,1-Dichloroethene ND
2.0 0.2075-69-4 Trichlorofluoromethane ND
2.0 0.3075-71-8 Dichlorodifluoromethane ND
3.0 0.7376-13-1 1,1,2-Trichloro-1,2,2-trifluoroethan
e
ND
1.0 0.2478-87-5 1,2-Dichloropropane ND
10 4.678-93-3 2-Butanone (MEK)ND
1.0 0.2779-00-5 1,1,2-Trichloroethane ND
1.0 0.3079-01-6 Trichloroethene ND
5.0 1.679-20-9 Methyl acetate ND
1.0 0.2179-34-5 1,1,2,2-Tetrachloroethane ND
4.0 1.287-61-6 1,2,3-Trichlorobenzene ND
FORM I 8260D
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3:53:55 PM
Page 224 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:Trip Blank Lab Sample ID:280-198899-6
Matrix:VMS14_0000004274.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
10/30/2024 00:00
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 08:04
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
2.0 0.5387-68-3 Hexachlorobutadiene ND
3.0 0.9991-20-3 Naphthalene ND
1.0 0.1195-47-6 o-Xylene ND
1.0 0.3495-49-8 2-Chlorotoluene ND
1.0 0.1495-50-1 1,2-Dichlorobenzene ND
1.0 0.1595-63-6 1,2,4-Trimethylbenzene ND
5.0 0.4296-12-8 1,2-Dibromo-3-Chloropropane ND
2.5 0.2896-18-4 1,2,3-Trichloropropane ND
3.0 0.1997-63-2 Ethyl methacrylate ND
1.0 0.1898-06-6 tert-Butylbenzene ND
1.0 0.1698-82-8 Isopropylbenzene ND
1.0 0.1999-87-6 4-Isopropyltoluene ND
1.0 0.111330-20-7 Xylenes, Total ND
1.0 0.32540-59-0 1,2-Dichloroethene, Total ND
1.0 0.14542-75-6 1,3-Dichloropropene, Total ND
1.0 0.19STL00209Trihalomethanes, Total ND
1.0 0.14STL00431Total BTEX ND
%RECCAS NO.LIMITSQSURROGATE
93 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr)
95 77-1201868-53-7 Dibromofluoromethane (Surr)
109 80-1252037-26-5 Toluene-d8 (Surr)
92 78-120460-00-4 4-Bromofluorobenzene (Surr)
FORM I 8260D
11/15/2024
3:53:55 PM
Page 225 of 777
Report Date: 11-Nov-2024 16:14:43 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004274.D
Lims ID:280-198899-B-6
Client ID:Trip Blank
Sample Type:Client
Inject. Date:11-Nov-2024 08:04:49 ALS Bottle#:0 Worklist Smp#:16
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:280-198899-B-6
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:11-Nov-2024 16:14:22 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:11-Nov-2024 16:00:16
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.357 0.003 99 1135748 50.0
* 2 Chlorobenzene-d5 119 7.929 7.926 0.003 85 260603 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.170 10.173 -0.003 95 465226 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.842 4.839 0.003 93 260716 47.4
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.112 5.109 0.003 97 320153 46.6
$ 6 Toluene-d8 (Surr) 98 6.636 6.637 -0.001 92 1116663 54.4
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 90 409138 46.0
10 Dichlorodifluoromethane 85 1.791 ND
12 Chloromethane 50 1.974 ND
13 Vinyl chloride 62 2.090 ND
15 Bromomethane 94 2.389 ND
16 Chloroethane 64 2.489 ND
18 Trichlorofluoromethane 101 2.711 ND
21 Ethyl ether 59 2.936 ND
25 1,1-Dichloroethene 96 3.138 ND
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.141 ND
26 Acetone 43 3.164 ND
29 Iodomethane 142 3.267 ND
30 Carbon disulfide 76 3.334 ND
32 Methyl acetate 43 3.399 ND
33 3-Chloro-1-propene 41 3.418 ND
34 Methylene Chloride 84 3.518 ND
37 Methyl tert-butyl ether 73 3.714 ND
38 trans-1,2-Dichloroethene 96 3.727 ND
39 Hexane 57 3.929 ND
40 Vinyl acetate 43 4.032 ND
42 1,1-Dichloroethane 63 4.055 ND
45 2-Butanone (MEK) 43 4.456 ND
47 cis-1,2-Dichloroethene 96 4.482 ND
48 2,2-Dichloropropane 77 4.495 ND
52 Chlorobromomethane 128 4.662 ND
53 Tetrahydrofuran 42 4.678 4.678 0.000 88 8753 1.23
11/15/2024
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Page 226 of 777
Report Date: 11-Nov-2024 16:14:43 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004274.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
54 Chloroform 83 4.720 ND
55 1,1,1-Trichloroethane 97 4.871 ND
56 Cyclohexane 56 4.936 ND
57 1,1-Dichloropropene 75 4.987 ND
59 Carbon tetrachloride 117 4.990 ND
60 Benzene 78 5.145 ND
61 1,2-Dichloroethane 62 5.167 ND
65 Trichloroethene 95 5.640 ND
67 Methylcyclohexane 55 5.842 ND
69 1,2-Dichloropropane 63 5.849 ND
71 Dibromomethane 93 5.923 ND
72 Dichlorobromomethane 83 6.045 ND
75 cis-1,3-Dichloropropene 75 6.402 ND
76 4-Methyl-2-pentanone (MIBK) 43 6.501 ND
77 Toluene 91 6.694 ND
78 trans-1,3-Dichloropropene 75 6.868 ND
79 Ethyl methacrylate 69 6.884 ND
80 1,1,2-Trichloroethane 97 7.045 ND
82 Tetrachloroethene 164 7.148 ND
83 1,3-Dichloropropane 76 7.196 ND
84 2-Hexanone 43 7.215 ND
85 Chlorodibromomethane 129 7.392 ND
86 Ethylene Dibromide 107 7.514 ND
88 Chlorobenzene 112 7.955 ND
89 1,1,1,2-Tetrachloroethane 131 8.022 ND
90 Ethylbenzene 106 8.029 ND
91 m-Xylene & p-Xylene 106 8.148 ND
92 o-Xylene 106 8.511 ND
93 Styrene 104 8.527 ND
94 Bromoform 173 8.710 ND
95 Isopropylbenzene 105 8.858 ND
98 1,1,2,2-Tetrachloroethane 83 9.141 ND
100 Bromobenzene 156 9.186 ND
101 1,2,3-Trichloropropane 110 9.209 ND
102 N-Propylbenzene 120 9.257 ND
103 2-Chlorotoluene 126 9.360 ND
104 1,3,5-Trimethylbenzene 105 9.431 ND
105 4-Chlorotoluene 126 9.479 ND
107 tert-Butylbenzene 119 9.746 ND
108 1,2,4-Trimethylbenzene 105 9.804 ND
109 sec-Butylbenzene 134 9.968 ND
110 1,3-Dichlorobenzene 146 10.099 ND
111 4-Isopropyltoluene 119 10.112 ND
112 1,4-Dichlorobenzene 146 10.196 ND
114 n-Butylbenzene 91 10.524 ND
115 1,2-Dichlorobenzene 146 10.559 ND
116 1,2-Dibromo-3-Chloropropane 157 11.344 ND
118 1,2,4-Trichlorobenzene 180 12.180 ND
119 Hexachlorobutadiene 225 12.321 ND
120 Naphthalene 128 12.453 ND
121 1,2,3-Trichlorobenzene 180 12.678 ND
S 154 1,3-Dichloropropene, Total 1 0.000 ND 7
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Page 227 of 777
Report Date: 11-Nov-2024 16:14:43 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004274.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
S 156 Total BTEX 1 0.000 ND 7
S 151 1,2-Dichloroethene, Total 1 0.000 ND 7
S 152 Trihalomethanes, Total 1 0.000 ND 7
S 155 Xylenes, Total 106 0.000 ND 7
QC Flag Legend
Processing Flags
7 - Failed Limit of Detection
Reagents:
mv-IS_SS_00089 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 228 of 777
Report Date: 11-Nov-2024 16:14:43 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004274.D
Injection Date:11-Nov-2024 08:04:49 Instrument ID:VMS_MS14 Operator ID:MED
Lims ID:280-198899-B-6 Lab Sample ID:280-198899-6 Worklist Smp#:16
Client ID:Trip Blank
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
Y ( X10
0
0
0
0
)
0000004274[MS Quad Chro]:Total

T
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11/15/2024
3:53:55 PM
Page 229 of 777
Report Date: 11-Nov-2024 16:14:43 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004274.D
Lims ID:280-198899-B-6
Client ID:Trip Blank
Sample Type:Client
Inject. Date:11-Nov-2024 08:04:49 ALS Bottle#:0 Worklist Smp#:16
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:280-198899-B-6
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:11-Nov-2024 16:14:22 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:11-Nov-2024 16:00:16
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 47.4 94.72
$5 1,2-Dichloroethane-d4 (Surr)50.0 46.6 93.13
$6 Toluene-d8 (Surr)50.0 54.4 108.73
$7 4-Bromofluorobenzene (Surr)50.0 46.0 91.92
11/15/2024
3:53:55 PM
Page 230 of 777
Report Date: 11-Nov-2024 16:14:43 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004274.D
Injection Date:11-Nov-2024 08:04:49 Instrument ID:VMS_MS14
Lims ID:280-198899-B-6 Lab Sample ID:280-198899-6
Client ID:Trip Blank
Operator ID:MED ALS Bottle#:0 Worklist Smp#:16
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
53 Tetrahydrofuran, CAS: 109-99-9
30 70 110 150 190 230 270 310 350
m/z
0
7
14
21
28
35
42
49
Y ( X10
0
)
Raw Spec:Scan 1148(4.68)
71
72
43
30 70 110 150 190 230 270 310 350m/z
0
7
14
21
28
35
42
49
Y ( X10
0
)
Enhanced Spec:Scan 1148(4.68) Bgrd 1136( 4.64), Qvalue=88 Sig Qvalue=96
71
72
43
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X10
0
)
Ref Spec: 53 Tetrahydrofuran (NIST98.L)
72
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1148 @ 4.678 min.(Qvalue: 88)
71
4.1 4.4 4.7 5.0
Min
RT
0
9
18
27
36
45
Y ( X10
0
)
0000004274[MS Quad Chro]:m/z 42

4
.
6
7
8
4.1 4.4 4.7 5.0Min
RT
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8
12
16
20
Y ( X10
0
)
0000004274[MS Quad Chro]:m/z 71

4
.
6
6
9
4.1 4.4 4.7 5.0
Min
0
8
16
24
32
40
48
Y ( X10
0
)
0000004274[MS Quad Chro]:m/z 42
0000004274[MS Quad Chro]:m/z 71
11/15/2024
3:53:55 PM
Page 231 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672942
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_MS14
98519Calibration Start Date:Calibration End Date:10/29/2024 17:02
N
10/29/2024 19:42
0.25(mm)DB-624 (60.25)ID:
Calibration Files
LEVEL:LAB SAMPLE ID:LAB FILE ID:1Level IC 280-672942/44 VMS14_0000003780.D
2Level IC 280-672942/43 VMS14_0000003779.D
3Level IC 280-672942/42 VMS14_0000003778.D
4Level IC 280-672942/41 VMS14_0000003777.D
5Level IC 280-672942/40 VMS14_0000003776.D
6Level ICIS 280-672942/39 VMS14_0000003775.D
7Level IC 280-672942/38 VMS14_0000003774.D
8Level IC 280-672942/37 VMS14_0000003773.D
9Level IC 280-672942/36 VMS14_0000003772.D
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
Dichlorodifluoromethane +++++0.1386 0.1994 0.2341 0.2623 Lin2 0.9960
0.3099 0.3095 0.2865 0.2818
0.9900-0.16
2
0.290
1Chloromethane0.3890 0.3573 0.3585 0.3713 0.3348 Ave 5.0
0.3881 0.3930 0.3774 0.3762
0.1000 15.00.371
7Vinyl chloride 0.2813 0.2776 0.2854 0.2862 0.2653 Ave 4.0
0.2991 0.3016 0.2783 0.2759
30.00.283
4Bromomethane+++++0.2014 0.1924 0.1744 0.1727 Ave 5.6
0.1906 0.1892 0.1840 0.1749
15.00.184
9Chloroethane+++++0.1761 0.1710 0.1700 0.1700 Ave 3.9
0.1862 0.1875 0.1776 0.1760
15.00.176
8Dichlorofluoromethane0.4985 0.4424 0.4339 0.4294 0.4202 Ave 5.3
0.4585 0.4556 0.4374 0.4294
15.00.445
0Trichlorofluoromethane0.2964 0.2896 0.2807 0.2820 0.2826 Ave 8.2
0.3408 0.3417 0.3243 0.2988
15.00.304
1Ethyl ether 0.1909 0.1895 0.1856 0.1803 0.1787 Ave 5.4
0.2070 0.1988 0.1907 0.2064
15.00.192
0Acrolein0.0958 0.0879 0.0875 0.0915 0.0904 Ave 8.9
0.1072 0.1038 0.1025 0.1100
15.00.097
4
1,1,2-Trichloro-1,2,2-trifluoroeth
ane
+++++0.1219 0.1270 0.1209 0.1052 Ave 10.3
0.1453 0.1362 0.1148 0.1159
15.00.123
4
1,1-Dichloroethene +++++0.1790 0.1637 0.1650 0.1470 Lin1 0.9960
0.2004 0.1952 0.1719 0.1795
0.9900-0.03
1
0.182
4Acetone1.3426 0.8852 0.5481 0.4204 0.3388 Lin2 0.9930
0.3398 0.3226 0.3100 0.3212
0.99002.094
0
0.312
7
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
11/15/2024
3:53:55 PM
Page 232 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672942
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_MS14
98519Calibration Start Date:Calibration End Date:10/29/2024 17:02
N
10/29/2024 19:42
0.25(mm)DB-624 (60.25)ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
Iodomethane +++++++++++++++0.1532 0.1656 Lin2 0.9970
0.2248 0.2215 0.2122 0.2245
0.9900-0.39
0
0.222
9Carbon disulfide ++++++++++0.5158 0.4782 0.4745 Ave 10.6
0.6209 0.6057 0.5365 0.5539
15.00.540
8Methyl acetate 0.6700 0.5823 0.5063 0.4881 0.4642 Ave 11.7
0.5390 0.5080 0.4969 0.5255
15.00.531
13-Chloro-1-propene ++++++++++0.3453 0.3408 0.2732 Ave 10.0
0.3366 0.3185 0.2847 0.2801
15.00.311
3Methylene Chloride +++++0.3123 0.2597 0.2563 0.2419 Ave 10.0
0.2593 0.2470 0.2277 0.2390
15.00.255
42-Methyl-2-propanol 0.2177 0.2323 0.2074 0.2173 0.2010 Ave 4.1
0.2193 0.2118 0.2092 0.2163
15.00.214
7Acrylonitrile0.3002 0.2783 0.2797 0.2804 0.2767 Ave 4.0
0.3016 0.2852 0.2740 0.2681
15.00.282
7Methyl tert-butyl ether +++++0.7159 0.7219 0.6837 0.6978 Ave 3.9
0.7632 0.7279 0.6845 0.6864
15.00.710
2trans-1,2-Dichloroethene 0.2293 0.1972 0.2031 0.1871 0.1804 Ave 9.6
0.2036 0.1922 0.1716 0.1696
15.00.192
7Hexane1.3135 1.1399 1.1187 1.0013 0.9423 Ave 14.4
1.1126 1.0010 0.8823 0.8285
15.01.037
8Vinyl acetate 0.5204 0.4926 0.5149 0.5336 0.5095 Lin2 0.9930
0.6229 0.6094 0.5846 0.6099
0.9900-0.08
7
0.573
91,1-Dichloroethane 0.3341 0.3456 0.3435 0.3419 0.3337 Ave 4.5
0.3746 0.3607 0.3240 0.3369
0.1000 15.00.343
92-Butanone (MEK)1.1474 0.8834 0.6725 0.5882 0.4774 Lin2 0.9950
0.5364 0.5112 0.4884 0.4935
0.99001.341
0
0.500
9cis-1,2-Dichloroethene 0.2414 0.2363 0.2235 0.2176 0.2126 Ave 5.3
0.2359 0.2285 0.2075 0.2149
15.00.224
22,2-Dichloropropane +++++0.2561 0.2657 0.2527 0.2433 Ave 7.7
0.3027 0.2955 0.2641 0.2642
15.00.268
0sec-Butyl Alcohol 0.1540 0.1597 0.1452 0.1539 0.1452 Ave 3.6
0.1537 0.1476 0.1460 0.1449
15.00.150
0Chlorobromomethane0.1295 0.1116 0.1243 0.1138 0.1117 Ave 5.9
0.1227 0.1204 0.1104 0.1120
15.00.117
4Tetrahydrofuran0.3605 0.3318 0.3039 0.3101 0.2897 Ave 7.1
0.3182 0.3039 0.2916 0.2998
15.00.312
2
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
11/15/2024
3:53:55 PM
Page 233 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672942
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_MS14
98519Calibration Start Date:Calibration End Date:10/29/2024 17:02
N
10/29/2024 19:42
0.25(mm)DB-624 (60.25)ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
Chloroform 0.3861 0.3582 0.3386 0.3367 0.3287 Ave 6.2
0.3653 0.3562 0.3208 0.3264
30.00.346
31,1,1-Trichloroethane 0.3122 0.2571 0.2602 0.2412 0.2367 Ave 10.2
0.3049 0.2902 0.2554 0.2575
15.00.268
4Cyclohexane0.3885 0.3503 0.3186 0.3101 0.2714 Ave 11.9
0.3704 0.3489 0.2950 0.2940
15.00.327
51,1-Dichloropropene 0.3307 0.3072 0.2884 0.2743 0.2506 Ave 9.9
0.3112 0.2918 0.2548 0.2562
15.00.285
0Carbon tetrachloride +++++0.1099 0.1485 0.1527 0.1589 Lin1 0.9950
0.2276 0.2222 0.1951 0.1972
0.9900-0.12
3
0.204
8Isobutyl alcohol +++++0.0603 0.0474 0.0581 0.0558 Ave 6.9
0.0590 0.0566 0.0562 0.0560
15.00.056
2Benzene0.9365 0.8690 0.8445 0.8000 0.7734 Ave 7.6
0.8708 0.8381 0.7478 0.7535
15.00.825
91,2-Dichloroethane +++++0.3235 0.2943 0.2907 0.2830 Ave 5.0
0.3090 0.2965 0.2774 0.2873
15.00.295
2n-Heptane ++++++++++0.3486 0.3063 0.2512 Ave 11.9
0.3197 0.2950 0.2645 0.2652
15.00.292
9Trichloroethene+++++1.0129 0.8993 0.8483 0.8402 Ave 11.3
0.8567 0.8229 0.7507 0.6955
15.00.840
82-Pentanone 0.8362 0.7860 0.7022 0.6885 0.6403 Ave 8.7
0.7293 0.7008 0.6749 0.6662
15.00.713
8Methylcyclohexane0.3442 0.2923 0.2747 0.2651 0.2270 Ave 13.4
0.2985 0.2760 0.2402 0.2365
15.00.272
71,2-Dichloropropane 0.2194 0.2272 0.2129 0.2160 0.2050 Ave 4.3
0.2341 0.2294 0.2113 0.2186
30.00.219
31,4-Dioxane +++++0.0167 0.0131 0.0135 0.0106 Lin2 0.9920
0.0113 0.0113 0.0107 0.0128
0.99000.101
4
0.011
3Dibromomethane0.1437 0.1334 0.1553 0.1428 0.1360 Ave 6.1
0.1595 0.1532 0.1455 0.1529
15.00.146
9Dichlorobromomethane+++++0.1668 0.1802 0.1997 0.2073 Lin1 0.9980
0.2604 0.2646 0.2472 0.2721
0.9900-0.17
0
0.264
02-Chloroethyl vinyl ether +++++0.1264 0.1500 0.1584 0.1522 Lin2 0.9950
0.1817 0.1830 0.1824 0.1923
0.9900-0.05
6
0.178
8cis-1,3-Dichloropropene 1.1024 1.1113 1.1003 1.1150 1.2336 Ave 9.5
1.3835 1.3419 1.3051 1.3110
15.01.222
7
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
11/15/2024
3:53:55 PM
Page 234 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672942
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_MS14
98519Calibration Start Date:Calibration End Date:10/29/2024 17:02
N
10/29/2024 19:42
0.25(mm)DB-624 (60.25)ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
4-Methyl-2-pentanone (MIBK)0.6244 0.5915 0.5665 0.5867 0.5725 Ave 5.0
0.6561 0.6267 0.5964 0.5786
15.00.599
9Toluene1.0866 0.9676 0.9657 0.9131 0.8671 Ave 7.5
0.9936 0.9569 0.8737 0.8814
30.00.945
1trans-1,3-Dichloropropene +++++0.2619 0.2533 0.2715 0.2776 Lin1 0.9970
0.3609 0.3667 0.3539 0.3863
0.9900-0.24
2
0.372
5Ethyl methacrylate 1.5219 1.6001 1.5502 1.5610 1.5574 Ave 4.5
1.7600 1.6470 1.6286 1.5703
15.01.599
61,1,2-Trichloroethane +++++0.2197 0.2165 0.2134 0.2152 Ave 6.3
0.2429 0.2415 0.2338 0.2495
15.00.229
1Tetrachloroethene0.5998 0.6418 0.6470 0.6451 0.5634 Ave 8.5
0.6337 0.5954 0.5422 0.5056
15.00.597
11,3-Dichloropropane 1.5793 1.4945 1.5028 1.5231 1.5099 Ave 2.8
1.5643 1.5002 1.4692 1.4424
15.01.509
52-Hexanone 2.1286 2.1193 1.9982 2.0627 2.0921 Ave 6.7
2.1162 1.9386 1.9216 1.7166
15.02.010
4Chlorodibromomethane+++++0.4878 0.4938 0.5177 0.5972 Lin1 0.9980
0.7654 0.7700 0.7677 0.7992
0.9900-0.58
1
0.784
0Ethylene Dibromide 0.9736 0.8947 0.8761 0.9048 0.9114 Ave 3.8
0.9836 0.9473 0.9326 0.9254
15.00.927
71-Chlorohexane +++++1.5695 1.4823 1.2409 1.0827 Lin2 0.9930
1.2290 1.1396 1.0657 1.0234
0.99000.412
8
1.109
9Chlorobenzene2.7503 2.5559 2.4133 2.3575 2.3086 Ave 8.0
2.3898 2.2785 2.1826 2.1301
0.3000 15.02.374
11,1,1,2-Tetrachloroethane +++++0.5008 0.5985 0.5877 0.6517 Lin2 0.9950
0.7626 0.7569 0.7275 0.7395
0.9900-0.24
2
0.721
5Ethylbenzene1.5344 1.2316 1.2639 1.2808 1.2029 Ave 9.5
1.2943 1.2207 1.1604 1.1104
30.01.255
5m-Xylene & p-Xylene +++++1.7138 1.5536 1.5673 1.5488 Ave 6.8
1.6399 1.5071 1.4389 1.3807
15.01.543
8o-Xylene 1.7886 1.6413 1.7235 1.6014 1.5257 Ave 7.9
1.6333 1.5160 1.4469 1.4084
15.01.587
2Styrene3.0614 2.7083 2.6777 2.6746 2.5754 Ave 7.1
2.7862 2.5972 2.5074 2.3920
15.02.664
5Bromoform++++++++++0.3542 0.3635 0.4308 Lin1 0.9980
0.5902 0.6079 0.6254 0.6330
0.1000 0.9900-0.93
3
0.628
1
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
11/15/2024
3:53:55 PM
Page 235 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672942
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_MS14
98519Calibration Start Date:Calibration End Date:10/29/2024 17:02
N
10/29/2024 19:42
0.25(mm)DB-624 (60.25)ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
Isopropylbenzene 2.1657 2.1439 2.1419 2.0116 1.9727 Ave 4.6
2.1770 2.2683 2.1226 2.0025
15.02.111
8Cyclohexanone0.2218 0.2361 0.2083 0.2229 0.2044 Ave 11.0
0.1911 0.1820 0.1804 0.1715
15.00.202
11,1,2,2-Tetrachloroethane +++++0.8053 0.7271 0.7621 0.7755 Ave 7.6
0.8602 0.8973 0.8864 0.8559
0.3000 15.00.821
2trans-1,4-Dichloro-2-butene +++++0.2297 0.2627 0.2151 0.2828 Lin1 0.9980
0.3199 0.3408 0.3405 0.3241
0.9900-0.17
9
0.330
8Bromobenzene+++++0.6287 0.6214 0.5702 0.5609 Ave 4.5
0.5875 0.6038 0.5907 0.5587
15.00.590
21,2,3-Trichloropropane 0.3352 0.2756 0.3211 0.3175 0.3179 Ave 6.6
0.3405 0.3448 0.3413 0.3174
15.00.323
5N-Propylbenzene +++++0.6870 0.6548 0.6182 0.6204 Ave 5.6
0.6423 0.6476 0.5995 0.5739
15.00.630
52-Chlorotoluene +++++0.5969 0.5825 0.5225 0.5449 Ave 5.3
0.5511 0.5650 0.5290 0.5149
15.00.550
91,3,5-Trimethylbenzene 2.2383 2.0815 2.1181 1.9549 1.9374 Ave 7.3
2.0094 1.9367 1.8210 1.7781
15.01.986
24-Chlorotoluene +++++0.6259 0.6533 0.5872 0.5825 Ave 6.2
0.5828 0.5776 0.5575 0.5379
15.00.588
1tert-Butylbenzene 1.9013 1.8291 1.7328 1.6436 1.6379 Ave 6.2
1.7583 1.7737 1.6476 1.5678
15.01.721
31,2,4-Trimethylbenzene 2.4693 2.2090 2.2177 2.1266 2.0931 Ave 8.2
2.1209 2.0543 1.9185 1.8772
15.02.120
7sec-Butylbenzene 0.5705 0.5646 0.5594 0.4870 0.4836 Ave 7.7
0.5291 0.5256 0.4870 0.4642
15.00.519
01,3-Dichlorobenzene 1.4096 1.3279 1.2454 1.1356 1.1353 Ave 10.1
1.1537 1.1451 1.0801 1.0403
15.01.185
94-Isopropyltoluene 2.6427 2.3416 2.3520 2.2327 2.1698 Ave 8.6
2.3069 2.2421 2.0591 1.9596
15.02.256
31,4-Dichlorobenzene +++++1.3539 1.3756 1.2173 1.1860 Lin2 0.9960
1.1495 1.1389 1.0666 1.0462
0.99000.292
0
1.124
3n-Butylbenzene +++++2.4483 2.3411 2.1597 2.1227 Ave 8.7
2.1926 2.1186 1.9334 1.8920
15.02.151
11,2-Dichlorobenzene +++++1.2358 1.2377 1.1389 1.1190 Ave 6.9
1.1244 1.0893 1.0508 1.0225
15.01.127
3
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
11/15/2024
3:53:55 PM
Page 236 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672942
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_MS14
98519Calibration Start Date:Calibration End Date:10/29/2024 17:02
N
10/29/2024 19:42
0.25(mm)DB-624 (60.25)ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
1,2-Dibromo-3-Chloropropane ++++++++++0.2290 0.2441 0.2969 Lin2 0.9900
0.3441 0.3680 0.3816 0.3808
0.9900-0.31
1
0.358
31,2,4-Trichlorobenzene +++++1.0940 1.0185 0.9022 0.8498 Lin2 0.9970
0.8285 0.7948 0.7577 0.7709
0.99000.327
6
0.801
4Hexachlorobutadiene+++++0.3942 0.3645 0.3328 0.3227 Ave 7.2
0.3434 0.3457 0.3208 0.3270
15.00.343
9Naphthalene3.4937 3.4920 3.2643 3.2209 3.2196 Ave 5.5
3.1422 3.1234 3.1147 2.9518
15.03.224
71,2,3-Trichlorobenzene +++++1.0524 0.9439 0.8541 0.8311 Lin2 0.9990
0.8032 0.7784 0.7613 0.7501
0.99000.287
2
0.780
5Dibromofluoromethane (Surr)0.2310 0.2343 0.2355 0.2403 0.2428 Ave 3.1
0.2489 0.2513 0.2470 0.2501
15.00.242
41,2-Dichloroethane-d4 (Surr)0.3072 0.3040 0.3072 0.3062 0.2980 Ave 1.3
0.3031 0.2998 0.2964 0.3025
15.00.302
7Toluene-d8 (Surr)4.0556 4.0714 4.0665 4.0828 4.1228 Ave 4.5
3.8549 3.7906 3.7999 3.6222
15.03.940
74-Bromofluorobenzene (Surr)0.9198 0.9344 0.9426 0.9471 0.9436 Ave 3.3
0.9396 1.0169 0.9951 0.9714
15.00.956
7
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
11/15/2024
3:53:55 PM
Page 237 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672942
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_MS14
98519Calibration Start Date:Calibration End Date:10/29/2024 17:02
N
10/29/2024 19:42
GC Column:DB-624 (60.25)ID:0.25(mm)
Calibration Files:
LEVEL:LAB SAMPLE ID:LAB FILE ID:
Level 1 IC 280-672942/44 VMS14_0000003780.D
Level 2 IC 280-672942/43 VMS14_0000003779.D
Level 3 IC 280-672942/42 VMS14_0000003778.D
Level 4 IC 280-672942/41 VMS14_0000003777.D
Level 5 IC 280-672942/40 VMS14_0000003776.D
Level 6 ICIS 280-672942/39 VMS14_0000003775.D
Level 7 IC 280-672942/38 VMS14_0000003774.D
Level 8 IC 280-672942/37 VMS14_0000003773.D
Level 9 IC 280-672942/36 VMS14_0000003772.D
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
Dichlorodifluoromethane Lin2FB +++++4032 11770 34291 78357 +++++1.00 2.00 5.00 10.0
423454 20010075.050.01593403813984660308
Chloromethane AveFB 5859 10397 21161 54396 100026 0.500 1.00 2.00 5.00 10.0
530246 20010075.050.021272161072325838366
Vinyl chloride AveFB 4237 8079 16846 41924 79262 0.500 1.00 2.00 5.00 10.0
408639 20010075.050.01560196790806643412
Bromomethane AveFB +++++5861 11355 25548 51598 +++++1.00 2.00 5.00 10.0
260399 20010075.050.0988753522856403515
Chloroethane AveFB +++++5123 10095 24903 50787 +++++1.00 2.00 5.00 10.0
254379 20010075.050.0995302504635399995
Dichlorofluoromethane AveFB 7508 12874 25607 62899 125520 0.500 1.00 2.00 5.00 10.0
626473 20010075.050.024284071242735971844
Trichlorofluoromethane AveFB 4465 8427 16564 41308 84418 0.500 1.00 2.00 5.00 10.0
465599 20010075.050.01689557921314728841
Ethyl ether AveFB 2876 5514 10955 26406 53387 0.500 1.00 2.00 5.00 10.0
282867 20010075.050.01167369541799423987
Acrolein AveFB 14247 25249 50968 132334 266765 4.94 9.88 19.8 49.4 98.8
1446824 1975988741494614463428744482187381
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
AveFB +++++3548 7493 17718 31428 +++++1.00 2.00 5.00 10.0
198558 20010075.050.0655636326156290621
1,1-Dichloroethene Lin1FB +++++5210 9660 24172 43911 +++++1.00 2.00 5.00 10.0
273839 20010075.050.01014813488352416373
Acetone Lin2FB 80891 103027 129392 246345 404785 2.00 4.00 8.00 20.0 40.0
1857237 800400300200726609635236512752790
Iodomethane Lin2FB +++++++++++++++22446 49467 +++++++++++++++5.00 10.0
307130 20010075.050.01269354602862472509
Carbon disulfide AveFB ++++++++++30442 70061 141737 ++++++++++2.00 5.00 10.0
848413 20010075.050.0313225315241761292017
FORM VI 8260D 11/15/2024
3:53:55 PM
Page 238 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672942
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_MS14
98519Calibration Start Date:Calibration End Date:10/29/2024 17:02
N
10/29/2024 19:42
GC Column:DB-624 (60.25)ID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
Methyl acetate AveFB 20183 33890 59766 143006 277337 1.00 2.00 4.00 10.0 20.0
1472932 400200150100594294728233862167234
3-Chloro-1-propene AveFB ++++++++++20380 49923 81625 ++++++++++2.00 5.00 10.0
459881 20010075.050.01584144808944679422
Methylene Chloride AveFB +++++9086 15325 37545 72264 +++++1.00 2.00 5.00 10.0
354260 20010075.050.01351230646845526978
2-Methyl-2-propanol AveFB 32795 67598 122425 318286 600388 5.00 10.0 20.0 50.0 100
2996340 200010007505001223160259446444518836
Acrylonitrile AveFB 45221 80993 165096 410766 826665 5.00 10.0 20.0 50.0 100
4121166 200010007505001516278377848856084208
Methyl tert-butyl ether AveFB +++++20831 42607 100166 208461 +++++1.00 2.00 5.00 10.0
1042880 20010075.050.0388137119447631552707
trans-1,2-Dichloroethene AveFB 3454 5737 11987 27411 53885 0.500 1.00 2.00 5.00 10.0
278162 20010075.050.0959154487550410075
Hexane AveCBNZd
5
5151 8522 17104 37954 71552 0.500 1.00 2.00 5.00 10.0
426162 20010075.050.01428020708025618110
Vinyl acetate Lin2FB 15677 28665 60777 156327 304385 1.00 2.00 4.00 10.0 20.0
1702192 400200150100689762433221142600010
1,1-Dichloroethane AveFB 5032 10057 20276 50089 99689 0.500 1.00 2.00 5.00 10.0
511810 20010075.050.01905023920508769515
2-Butanone (MEK)Lin2FB 69128 102827 158755 344674 570463 2.00 4.00 8.00 20.0 40.0
2931896 8004003002001116263855506324361478
cis-1,2-Dichloroethene AveFB 3636 6877 13188 31874 63513 0.500 1.00 2.00 5.00 10.0
322267 20010075.050.01215273589548487444
2,2-Dichloropropane AveFB +++++7453 15684 37012 72679 +++++1.00 2.00 5.00 10.0
413652 20010075.050.01493854750350630282
sec-Butyl Alcohol AveFB 55656 111546 205735 541115 1041222 12.0 24.0 48.0 120 240
5041291 48002400180012001966084299556017556240
Chlorobromomethane AveFB 1951 3247 7335 16678 33370 0.500 1.00 2.00 5.00 10.0
167649 20010075.050.0633456313572256824
Tetrahydrofuran AveFB 10859 19312 35869 90856 173068 1.00 2.00 4.00 10.0 20.0
869567 400200150100339063316568641296522
Chloroform AveFB 5815 10423 19986 49323 98199 0.500 1.00 2.00 5.00 10.0
499112 20010075.050.01845835911513759823
1,1,1-Trichloroethane AveFB 4703 7481 15355 35330 70719 0.500 1.00 2.00 5.00 10.0
416666 20010075.050.01455835725688618990
Cyclohexane AveFB 5851 10194 18806 45433 81063 0.500 1.00 2.00 5.00 10.0
506106 20010075.050.01662536838275744238
1,1-Dichloropropene AveFB 4981 8939 17024 40178 74865 0.500 1.00 2.00 5.00 10.0
425262 20010075.050.01449039723830622430
FORM VI 8260D 11/15/2024
3:53:55 PM
Page 239 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672942
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_MS14
98519Calibration Start Date:Calibration End Date:10/29/2024 17:02
N
10/29/2024 19:42
GC Column:DB-624 (60.25)ID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
Carbon tetrachloride Lin1FB +++++3197 8762 22366 47469 +++++1.00 2.00 5.00 10.0
310957 20010075.050.01114966554300473911
Isobutyl alcohol AveFB +++++43876 69967 212844 416809 +++++25.0 50.0 125 250
2016158 5000250018751250792154139893283016443
Benzene AveFB 14105 25285 49844 117202 231035 0.500 1.00 2.00 5.00 10.0
1189820 20010075.050.0426064321247541787722
1,2-Dichloroethane AveFB +++++9412 17368 42590 84548 +++++1.00 2.00 5.00 10.0
422176 20010075.050.01624660788267632536
n-Heptane AveFB ++++++++++20573 44866 75040 ++++++++++2.00 5.00 10.0
436858 20010075.050.01499788751614629313
Trichloroethene AveCBNZd
5
+++++7572 13750 32154 63804 +++++1.00 2.00 5.00 10.0
328128 20010075.050.01198842602409508137
2-Pentanone AveFB 40304 73186 132620 322746 612128 1.60 3.20 6.40 16.0 32.0
3188582 6403202401601205563261363204783620
Methylcyclohexane AveFB 5184 8505 16214 38843 67820 0.500 1.00 2.00 5.00 10.0
407818 20010075.050.01337243682411588660
1,2-Dichloropropane AveFB 3304 6611 12565 31647 61227 0.500 1.00 2.00 5.00 10.0
319841 20010075.050.01236390600435489410
1,4-Dioxane Lin2FB +++++9697 15518 39442 63473 +++++20.0 40.0 100 200
308138 40002000150010001443409610463483642
Dibromomethane AveFB 2164 3882 9166 20915 40636 0.500 1.00 2.00 5.00 10.0
217876 20010075.050.0864523413350326783
Dichlorobromomethane Lin1FB +++++4854 10634 29250 61918 +++++1.00 2.00 5.00 10.0
355841 20010075.050.01538776702395564463
2-Chloroethyl vinyl ether Lin2FB +++++3679 8854 23203 45467 +++++1.00 2.00 5.00 10.0
248280 20010075.050.01087678518202390399
cis-1,3-Dichloropropene AveCBNZd
5
4323 8308 16823 42264 93675 0.500 1.00 2.00 5.00 10.0
529909 20010075.050.022596411047356828574
4-Methyl-2-pentanone (MIBK)AveFB 37620 68849 133735 343818 684028 2.00 4.00 8.00 20.0 40.0
3585776 8004003002001308685367780575347518
Toluene AveFB 16366 28156 56998 133760 259024 0.500 1.00 2.00 5.00 10.0
1357635 20010075.050.0498402024823692041113
trans-1,3-Dichloropropene Lin1FB +++++7621 14951 39780 82939 +++++1.00 2.00 5.00 10.0
493160 20010075.050.021844981005369782249
Ethyl methacrylate AveCBNZd
5
5968 11962 23702 59170 118264 0.500 1.00 2.00 5.00 10.0
674124 20010075.050.0270660513068961016966
1,1,2-Trichloroethane AveFB +++++6394 12779 31267 64278 +++++1.00 2.00 5.00 10.0
331845 20010075.050.01410816664172515161
FORM VI 8260D 11/15/2024
3:53:55 PM
Page 240 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672942
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_MS14
98519Calibration Start Date:Calibration End Date:10/29/2024 17:02
N
10/29/2024 19:42
GC Column:DB-624 (60.25)ID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
Tetrachloroethene AveCBNZd
5
2352 4798 9892 24453 42782 0.500 1.00 2.00 5.00 10.0
242737 20010075.050.0871539435118367637
1,3-Dichloropropane AveCBNZd
5
6193 11173 22977 57731 114660 0.500 1.00 2.00 5.00 10.0
599149 20010075.050.024860561179003926329
2-Hexanone AveCBNZd5 33389 63374 122207 312740 635479 2.00 4.00 8.00 20.0 40.0
3242236 8004003002001183486461681384788047
Chlorodibromomethane Lin1CBNZd
5
+++++3647 7550 19624 45347 +++++1.00 2.00 5.00 10.0
293163 20010075.050.01377484616089475431
Ethylene Dibromide AveCBNZd
5
3818 6689 13395 34294 69209 0.500 1.00 2.00 5.00 10.0
376747 20010075.050.01594971748391584918
1-Chlorohexane Lin2CBNZd
5
+++++9387 18131 37628 65775 +++++0.800 1.60 4.00 8.00
376603 16080.060.040.01411155684168562940
Chlorobenzene AveCBNZd
5
10785 19108 36898 89361 175306 0.500 1.00 2.00 5.00 10.0
915363 20010075.050.0367138117515481406901
1,1,1,2-Tetrachloroethane Lin2CBNZd
5
+++++3744 9150 22277 49488 +++++1.00 2.00 5.00 10.0
292090 20010075.050.01274618583845467346
Ethylbenzene AveCBNZd
5 6017 9207 19324 48546 91345 0.500 1.00 2.00 5.00 10.0
495768 20010075.050.01913880931218753725
m-Xylene & p-Xylene AveCBNZd5 +++++12812 23753 59409 117614 +++++1.00 2.00 5.00 10.0
628118 20010075.050.023798411154708930575
o-Xylene AveCBNZd
5
7014 12270 26352 60699 115861 0.500 1.00 2.00 5.00 10.0
625580 20010075.050.024274931161157936071
Styrene AveCBNZd
5
12005 20247 40940 101377 195567 0.500 1.00 2.00 5.00 10.0
1067185 20010075.050.0412290520121901603679
Bromoform Lin1CBNZd
5
++++++++++5415 13780 32715 ++++++++++2.00 5.00 10.0
226066 20010075.050.01091079501908375364
Isopropylbenzene AveDCBd4 15769 28940 58458 137873 261053 0.500 1.00 2.00 5.00 10.0
1493408 20010075.050.0547093227438362246246
Cyclohexanone AveCBNZd
5
26095 52944 95555 253436 465684 15.0 30.0 60.0 150 300
FORM VI 8260D 11/15/2024
3:53:55 PM
Page 241 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672942
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_MS14
98519Calibration Start Date:Calibration End Date:10/29/2024 17:02
N
10/29/2024 19:42
GC Column:DB-624 (60.25)ID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
2195821 6000300022501500886928243428353370777
1,1,2,2-Tetrachloroethane AveDCBd4 +++++10870 19844 52231 102624 +++++1.00 2.00 5.00 10.0
590063 20010075.050.023384131145869888522
trans-1,4-Dichloro-2-butene Lin1DCBd4 +++++3101 7170 14745 37425 +++++1.00 2.00 5.00 10.0
219464 20010075.050.0885584440136337532
Bromobenzene AveDCBd4 +++++8486 16959 39078 74226 +++++1.00 2.00 5.00 10.0
403031 20010075.050.01526454763620597883
1,2,3-Trichloropropane AveDCBd4 2441 3720 8763 21761 42075 0.500 1.00 2.00 5.00 10.0
233551 20010075.050.0867110441205341489
N-Propylbenzene AveDCBd4 +++++9274 17870 42372 82098 +++++1.00 2.00 5.00 10.0
440574 20010075.050.01568014774990641292
2-Chlorotoluene AveDCBd4 +++++8058 15899 35814 72114 +++++1.00 2.00 5.00 10.0
378039 20010075.050.01406836683816559498
1,3,5-Trimethylbenzene AveDCBd4 16298 28098 57808 133991 256381 0.500 1.00 2.00 5.00 10.0
1378443 20010075.050.0485788723539601917881
4-Chlorotoluene AveDCBd4 +++++8449 17829 40245 77079 +++++1.00 2.00 5.00 10.0
399786 20010075.050.01469546720627571974
tert-Butylbenzene AveDCBd4 13844 24690 47291 112653 216755 0.500 1.00 2.00 5.00 10.0
1206143 20010075.050.0428328921298351756402
1,2,4-Trimethylbenzene AveDCBd4 17980 29818 60526 145759 276990 0.500 1.00 2.00 5.00 10.0
1454933 20010075.050.0512856224800372034297
sec-Butylbenzene AveDCBd4 4154 7621 15267 33379 63993 0.500 1.00 2.00 5.00 10.0
362987 20010075.050.01268132629466520437
1,3-Dichlorobenzene AveDCBd4 10264 17925 33991 77835 150233 0.500 1.00 2.00 5.00 10.0
791409 20010075.050.0284209713961521133955
4-Isopropyltoluene AveDCBd4 19242 31609 64193 153026 287139 0.500 1.00 2.00 5.00 10.0
1582460 20010075.050.0535361926617522220260
1,4-Dichlorobenzene Lin2DCBd4 +++++18276 37543 83431 156943 +++++1.00 2.00 5.00 10.0
788525 20010075.050.0285832013787441127851
n-Butylbenzene AveDCBd4 +++++33049 63895 148026 280898 +++++1.00 2.00 5.00 10.0
1504085 20010075.050.0516913424991772098008
1,2-Dichlorobenzene AveDCBd4 +++++16682 33779 78062 148081 +++++1.00 2.00 5.00 10.0
771289 20010075.050.0279362313583881078683
1,2-Dibromo-3-Chloropropane Lin2DCBd4 ++++++++++6251 16730 39290 ++++++++++2.00 5.00 10.0
236077 20010075.050.01040315493340364455
1,2,4-Trichlorobenzene Lin2DCBd4 +++++14767 27797 61836 112462 +++++1.00 2.00 5.00 10.0
568362 20010075.050.02106019979388787046
Hexachlorobutadiene AveDCBd4 +++++5321 9947 22809 42702 +++++1.00 2.00 5.00 10.0
235598 20010075.050.0893326414642342378
Naphthalene AveDCBd4 25439 47137 89090 220758 426056 0.500 1.00 2.00 5.00 10.0
2155523 20010075.050.0806442840262893093054
FORM VI 8260D 11/15/2024
3:53:55 PM
Page 242 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672942
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_MS14
98519Calibration Start Date:Calibration End Date:10/29/2024 17:02
N
10/29/2024 19:42
GC Column:DB-624 (60.25)ID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
1,2,3-Trichlorobenzene Lin2DCBd4 +++++14206 25762 58538 109982 +++++1.00 2.00 5.00 10.0
551010 20010075.050.02049349984063770852
Dibromofluoromethane (Surr)AveFB 347976 340868 347508 352051 362630 50.0 50.0 50.0 50.0 50.0
340083 50.050.050.050.0353542350905357385
1,2-Dichloroethane-d4 (Surr)AveFB 462657 442345 453237 448518 445088 50.0 50.0 50.0 50.0 50.0
414134 50.050.050.050.0427583420998426335
Toluene-d8 (Surr)AveCBNZd
5
1590373 1521861 1554364 1547549 1565369 50.0 50.0 50.0 50.0 50.0
1476507 50.050.050.050.0156083115246721560400
4-Bromofluorobenzene (Surr)AveDCBd4 669748 630640 643127 649171 624348 50.0 50.0 50.0 50.0 50.0
644540 50.050.050.050.0663464643174671345
Curve Type Legend:
Ave = Average ISTD
Lin1 = Linear 1/conc ISTDLin2 = Linear 1/conc^2 ISTD
FORM VI 8260D 11/15/2024
3:53:55 PM
Page 243 of 777
Report Date: 29-Oct-2024 20:24:30 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003772.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:9
Inject. Date:29-Oct-2024 17:02:26 ALS Bottle#:0 Worklist Smp#:36
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ic 200
Operator ID:bustillose Instrument ID:VMS_MS14
Sublist:chrom-AQ_VMS14_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:29-Oct-2024 20:24:29 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:29-Oct-2024 17:42:07
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 99 1413702 50.0 50.0
* 2 Chlorobenzene-d5 119 7.929 7.929 0.000 87 430902 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.177 -0.004 95 683014 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.842 4.842 0.000 93 353542 50.0 51.6
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.112 -0.003 88 427583 50.0 50.0
$ 6 Toluene-d8 (Surr) 98 6.636 6.637 -0.001 93 1560831 50.0 46.0
$ 7 4-Bromofluorobenzene (Surr) 95 9.035 9.035 0.000 86 663464 50.0 50.8
10 Dichlorodifluoromethane 85 1.791 1.791 0.000 99 1593403 200.0 194.8
12 Chloromethane 50 1.971 1.971 0.000 99 2127216 200.0 202.4
13 Vinyl chloride 62 2.086 2.087 -0.001 98 1560196 200.0 194.7
15 Bromomethane 94 2.382 2.399 -0.017 90 988753 200.0 189.1
16 Chloroethane 64 2.485 2.495 -0.010 99 995302 200.0 199.1
17 Dichlorofluoromethane 67 2.672 2.675 -0.003 97 2428407 200.0 193.0
18 Trichlorofluoromethane 101 2.713 2.717 -0.004 98 1689557 200.0 196.5
21 Ethyl ether 59 2.935 2.942 -0.007 90 1167369 200.0 215.0
22 Acrolein 56 3.054 3.055 -0.001 100 6144634 1975.0 2231.3
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.138 3.138 0.000 95 655636 200.0 187.9
25 1,1-Dichloroethene 96 3.141 3.145 -0.004 98 1014813 200.0 197.0
26 Acetone 43 3.164 3.158 0.006 100 7266096 800.0 815.2
29 Iodomethane 142 3.267 3.270 -0.003 99 1269354 200.0 203.2
30 Carbon disulfide 76 3.334 3.334 0.000 99 3132253 200.0 204.9
32 Methyl acetate 43 3.398 3.395 0.003 97 5942947 400.0 395.7
33 3-Chloro-1-propene 41 3.421 3.424 -0.003 93 1584144 200.0 180.0
34 Methylene Chloride 84 3.517 3.521 -0.004 91 1351230 200.0 187.1
35 2-Methyl-2-propanol 59 3.585 3.566 0.019 100 12231602 2000.0 2014.9
36 Acrylonitrile 53 3.691 3.688 0.003 100 15162783 2000.0 1896.9
37 Methyl tert-butyl ether 73 3.713 3.717 -0.004 95 3881371 200.0 193.3
38 trans-1,2-Dichloroethene 96 3.726 3.730 -0.004 99 959154 200.0 176.1
39 Hexane 57 3.929 3.932 -0.003 91 1428020 200.0 159.7
40 Vinyl acetate 43 4.029 4.029 0.000 97 6897624 400.0 425.2
42 1,1-Dichloroethane 63 4.058 4.058 0.000 96 1905023 200.0 195.9
11/15/2024
3:53:55 PM
Page 244 of 777
Report Date: 29-Oct-2024 20:24:30 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003772.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
45 2-Butanone (MEK) 43 4.456 4.453 0.003 99 11162638 800.0 785.5
47 cis-1,2-Dichloroethene 96 4.482 4.482 0.000 80 1215273 200.0 191.7
48 2,2-Dichloropropane 77 4.495 4.495 0.000 84 1493854 200.0 197.1
50 sec-Butyl Alcohol 45 4.578 4.569 0.009 99 19660842 4800.0 4634.9
52 Chlorobromomethane 128 4.662 4.662 0.000 96 633456 200.0 190.9
53 Tetrahydrofuran 42 4.675 4.672 0.003 89 3390633 400.0 384.2
54 Chloroform 83 4.720 4.723 -0.003 93 1845835 200.0 188.5
55 1,1,1-Trichloroethane 97 4.874 4.875 -0.001 98 1455835 200.0 191.9
56 Cyclohexane 56 4.935 4.939 -0.004 89 1662536 200.0 179.6
57 1,1-Dichloropropene 75 4.987 4.987 0.000 98 1449039 200.0 179.8
59 Carbon tetrachloride 117 4.993 4.997 -0.004 95 1114966 200.0 193.2
58 Isobutyl alcohol 41 5.006 4.997 0.009 95 7921541 5000.0 4987.0
60 Benzene 78 5.144 5.145 -0.001 96 4260643 200.0 182.4
61 1,2-Dichloroethane 62 5.170 5.167 0.003 97 1624660 200.0 194.6
63 n-Heptane 43 5.331 5.331 0.000 92 1499788 200.0 181.1
65 Trichloroethene 95 5.639 5.640 -0.001 99 1198842 200.0 165.4
66 2-Pentanone 43 5.746 5.743 0.003 98 12055632 640.0 597.3
67 Methylcyclohexane 55 5.842 5.846 -0.004 88 1337243 200.0 173.4
69 1,2-Dichloropropane 63 5.848 5.849 -0.001 97 1236390 200.0 199.4
70 1,4-Dioxane 88 5.900 5.900 0.000 93 1443409 4000.0 4497.0
71 Dibromomethane 93 5.922 5.926 -0.004 97 864523 200.0 208.1
72 Dichlorobromomethane 83 6.045 6.045 0.000 100 1538776 200.0 206.8
74 2-Chloroethyl vinyl ether 63 6.247 6.244 0.003 92 1087678 200.0 215.4
75 cis-1,3-Dichloropropene 75 6.398 6.405 -0.007 96 2259641 200.0 214.4
76 4-Methyl-2-pentanone (MIBK) 43 6.501 6.502 -0.001 95 13086853 800.0 771.5
77 Toluene 91 6.697 6.698 -0.001 99 4984020 200.0 186.5
78 trans-1,3-Dichloropropene 75 6.868 6.871 -0.003 96 2184498 200.0 208.0
79 Ethyl methacrylate 69 6.887 6.887 0.000 95 2706605 200.0 196.3
80 1,1,2-Trichloroethane 97 7.045 7.048 -0.003 91 1410816 200.0 217.8
82 Tetrachloroethene 164 7.147 7.148 -0.001 97 871539 200.0 169.4
83 1,3-Dichloropropane 76 7.196 7.196 0.000 97 2486056 200.0 191.1
84 2-Hexanone 43 7.215 7.215 0.000 93 11834864 800.0 683.1
85 Chlorodibromomethane 129 7.395 7.395 0.000 90 1377484 200.0 204.6
86 Ethylene Dibromide 107 7.517 7.518 -0.001 99 1594971 200.0 199.5
87 1-Chlorohexane 91 7.906 7.907 -0.001 96 1411155 160.0 147.2
88 Chlorobenzene 112 7.955 7.955 0.000 94 3671381 200.0 179.4
89 1,1,1,2-Tetrachloroethane 131 8.028 8.026 0.002 95 1274618 200.0 205.3
90 Ethylbenzene 106 8.032 8.029 0.003 98 1913880 200.0 176.9
91 m-Xylene & p-Xylene 106 8.147 8.148 -0.001 100 2379841 200.0 178.9
92 o-Xylene 106 8.514 8.514 0.000 97 2427493 200.0 177.5
93 Styrene 104 8.530 8.530 0.000 94 4122905 200.0 179.6
94 Bromoform 173 8.717 8.717 0.000 96 1091079 200.0 203.1
95 Isopropylbenzene 105 8.858 8.858 0.000 96 5470932 200.0 189.6
97 Cyclohexanone 55 8.961 8.961 0.000 91 8869282 6000.0 5093.5
98 1,1,2,2-Tetrachloroethane 83 9.144 9.141 0.003 94 2338413 200.0 208.5
99 trans-1,4-Dichloro-2-butene 53 9.180 9.177 0.003 89 885584 200.0 196.5
100 Bromobenzene 156 9.186 9.186 0.000 98 1526454 200.0 189.3
101 1,2,3-Trichloropropane 110 9.212 9.206 0.006 81 867110 200.0 196.2
102 N-Propylbenzene 120 9.260 9.264 -0.004 99 1568014 200.0 182.1
103 2-Chlorotoluene 126 9.363 9.363 0.000 96 1406836 200.0 187.0
104 1,3,5-Trimethylbenzene 105 9.430 9.434 -0.004 95 4857887 200.0 179.0
105 4-Chlorotoluene 126 9.479 9.479 0.000 98 1469546 200.0 182.9
11/15/2024
3:53:55 PM
Page 245 of 777
Report Date: 29-Oct-2024 20:24:30 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003772.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
107 tert-Butylbenzene 119 9.749 9.749 0.000 93 4283289 200.0 182.2
108 1,2,4-Trimethylbenzene 105 9.807 9.807 0.000 98 5128562 200.0 177.0
109 sec-Butylbenzene 134 9.971 9.968 0.003 94 1268132 200.0 178.9
110 1,3-Dichlorobenzene 146 10.102 10.100 0.002 98 2842097 200.0 175.4
111 4-Isopropyltoluene 119 10.115 10.116 -0.001 97 5353619 200.0 173.7
112 1,4-Dichlorobenzene 146 10.199 10.199 0.000 94 2858320 200.0 185.9
114 n-Butylbenzene 91 10.524 10.524 0.000 97 5169134 200.0 175.9
115 1,2-Dichlorobenzene 146 10.562 10.563 -0.001 97 2793623 200.0 181.4
116 1,2-Dibromo-3-Chloropropane 157 11.347 11.347 0.000 89 1040315 200.0 213.4
118 1,2,4-Trichlorobenzene 180 12.183 12.183 0.000 93 2106019 200.0 192.0
119 Hexachlorobutadiene 225 12.324 12.328 -0.004 98 893326 200.0 190.2
120 Naphthalene 128 12.456 12.456 0.000 97 8064428 200.0 183.1
121 1,2,3-Trichlorobenzene 180 12.681 12.681 0.000 95 2049349 200.0 191.9
136 Butadiene 54 0.000 ND ND
S 154 1,3-Dichloropropene, Total 1 0 400.0 422.5
S 156 Total BTEX 1 0 902.2
S 151 1,2-Dichloroethene, Total 1 0 400.0 367.7
S 152 Trihalomethanes, Total 1 0 800.0 802.9
S 155 Xylenes, Total 106 0 400.0 356.3
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
MV-MegaMainA_00118 Amount Added: 100.00 Units: uL
MV-Gas A_00201 Amount Added: 40.00 Units: uL
mv-IS_SS_00089 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 246 of 777
Report Date: 29-Oct-2024 20:24:30 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003772.D
Injection Date:29-Oct-2024 17:02:26 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:ic Worklist Smp#:36
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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11/15/2024
3:53:55 PM
Page 247 of 777
Report Date: 29-Oct-2024 20:24:33 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003773.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:8
Inject. Date:29-Oct-2024 17:22:25 ALS Bottle#:0 Worklist Smp#:37
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ic 100
Operator ID:bustillose Instrument ID:VMS_MS14
Sublist:chrom-AQ_VMS14_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:29-Oct-2024 20:24:32 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:29-Oct-2024 18:00:53
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 98 1420599 50.0 50.0
* 2 Chlorobenzene-d5 119 7.929 7.929 0.000 85 401244 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.177 -0.004 95 646332 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.839 4.842 -0.003 93 350905 50.0 51.0
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.113 5.112 0.000 97 420998 50.0 49.0
$ 6 Toluene-d8 (Surr) 98 6.637 6.637 0.000 93 1524672 50.0 48.2
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.035 -0.003 87 643174 50.0 52.0
10 Dichlorodifluoromethane 85 1.791 1.791 0.000 99 813984 100.0 99.3
12 Chloromethane 50 1.974 1.971 0.003 99 1072325 100.0 101.5
13 Vinyl chloride 62 2.087 2.087 0.000 98 790806 100.0 98.2
15 Bromomethane 94 2.392 2.399 -0.007 90 522856 100.0 99.5
16 Chloroethane 64 2.492 2.495 -0.003 100 504635 100.0 100.5
17 Dichlorofluoromethane 67 2.675 2.675 0.000 97 1242735 100.0 98.3
18 Trichlorofluoromethane 101 2.714 2.717 -0.003 98 921314 100.0 106.6
21 Ethyl ether 59 2.936 2.942 -0.006 91 541799 100.0 99.3
22 Acrolein 56 3.051 3.055 -0.004 100 2874448 987.5 1038.7
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.138 3.138 0.000 95 326156 100.0 93.0
25 1,1-Dichloroethene 96 3.141 3.145 -0.004 98 488352 100.0 94.4
26 Acetone 43 3.161 3.158 0.003 100 3523651 400.0 389.9
29 Iodomethane 142 3.270 3.270 0.000 98 602862 100.0 96.9
30 Carbon disulfide 76 3.338 3.334 0.004 99 1524176 100.0 99.2
32 Methyl acetate 43 3.399 3.395 0.004 97 2823386 200.0 187.1
33 3-Chloro-1-propene 41 3.421 3.424 -0.003 92 808944 100.0 91.5
34 Methylene Chloride 84 3.521 3.521 0.000 91 646845 100.0 89.1
35 2-Methyl-2-propanol 59 3.572 3.566 0.006 100 5944644 1000.0 974.5
36 Acrylonitrile 53 3.688 3.688 0.000 99 7784885 1000.0 969.2
37 Methyl tert-butyl ether 73 3.714 3.717 -0.003 94 1944763 100.0 96.4
38 trans-1,2-Dichloroethene 96 3.727 3.730 -0.003 99 487550 100.0 89.1
39 Hexane 57 3.932 3.932 0.000 91 708025 100.0 85.0
40 Vinyl acetate 43 4.029 4.029 0.000 97 3322114 200.0 203.9
42 1,1-Dichloroethane 63 4.058 4.058 0.000 96 920508 100.0 94.2
11/15/2024
3:53:55 PM
Page 248 of 777
Report Date: 29-Oct-2024 20:24:33 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003773.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
45 2-Butanone (MEK) 43 4.453 4.453 0.000 99 5550632 400.0 387.3
47 cis-1,2-Dichloroethene 96 4.482 4.482 0.000 80 589548 100.0 92.5
48 2,2-Dichloropropane 77 4.495 4.495 0.000 87 750350 100.0 98.5
50 sec-Butyl Alcohol 45 4.572 4.569 0.003 99 9955601 2400.0 2335.6
52 Chlorobromomethane 128 4.662 4.662 0.000 97 313572 100.0 94.0
53 Tetrahydrofuran 42 4.675 4.672 0.003 87 1656864 200.0 186.8
54 Chloroform 83 4.723 4.723 0.000 93 911513 100.0 92.6
55 1,1,1-Trichloroethane 97 4.875 4.875 0.000 98 725688 100.0 95.2
56 Cyclohexane 56 4.939 4.939 0.000 88 838275 100.0 90.1
57 1,1-Dichloropropene 75 4.987 4.987 0.000 98 723830 100.0 89.4
59 Carbon tetrachloride 117 4.994 4.997 -0.003 96 554300 100.0 95.9
58 Isobutyl alcohol 41 5.003 4.997 0.006 95 3989328 2500.0 2499.3
60 Benzene 78 5.145 5.145 0.000 96 2124754 100.0 90.5
61 1,2-Dichloroethane 62 5.170 5.167 0.003 97 788267 100.0 94.0
63 n-Heptane 43 5.334 5.331 0.003 92 751614 100.0 90.3
65 Trichloroethene 95 5.643 5.640 0.003 99 602409 100.0 89.3
66 2-Pentanone 43 5.743 5.743 0.000 99 6136320 320.0 302.6
67 Methylcyclohexane 55 5.842 5.846 -0.004 91 682411 100.0 88.1
69 1,2-Dichloropropane 63 5.849 5.849 0.000 96 600435 100.0 96.4
70 1,4-Dioxane 88 5.900 5.900 0.000 92 610463 2000.0 1887.5
71 Dibromomethane 93 5.920 5.926 -0.006 97 413350 100.0 99.0
72 Dichlorobromomethane 83 6.048 6.045 0.003 99 702395 100.0 94.3
74 2-Chloroethyl vinyl ether 63 6.248 6.244 0.004 91 518202 100.0 102.3
75 cis-1,3-Dichloropropene 75 6.399 6.405 -0.006 96 1047356 100.0 106.7
76 4-Methyl-2-pentanone (MIBK) 43 6.505 6.502 0.003 98 6778057 400.0 397.7
77 Toluene 91 6.694 6.698 -0.004 98 2482369 100.0 92.4
78 trans-1,3-Dichloropropene 75 6.868 6.871 -0.003 97 1005369 100.0 95.6
79 Ethyl methacrylate 69 6.887 6.887 0.000 88 1306896 100.0 101.8
80 1,1,2-Trichloroethane 97 7.048 7.048 0.000 90 664172 100.0 102.1
82 Tetrachloroethene 164 7.148 7.148 0.000 96 435118 100.0 90.8
83 1,3-Dichloropropane 76 7.196 7.196 0.000 89 1179003 100.0 97.3
84 2-Hexanone 43 7.215 7.215 0.000 95 6168138 400.0 382.3
85 Chlorodibromomethane 129 7.395 7.395 0.000 90 616089 100.0 98.7
86 Ethylene Dibromide 107 7.518 7.518 0.000 98 748391 100.0 100.5
87 1-Chlorohexane 91 7.907 7.907 0.000 96 684168 80.0 76.4
88 Chlorobenzene 112 7.958 7.955 0.003 94 1751548 100.0 91.9
89 1,1,1,2-Tetrachloroethane 131 8.026 8.026 0.000 95 583845 100.0 101.2
90 Ethylbenzene 106 8.032 8.029 0.003 98 931218 100.0 92.4
91 m-Xylene & p-Xylene 106 8.148 8.148 0.000 100 1154708 100.0 93.2
92 o-Xylene 106 8.514 8.514 0.000 97 1161157 100.0 91.2
93 Styrene 104 8.530 8.530 0.000 94 2012190 100.0 94.1
94 Bromoform 173 8.714 8.717 -0.003 96 501908 100.0 101.1
95 Isopropylbenzene 105 8.855 8.858 -0.003 96 2743836 100.0 100.5
97 Cyclohexanone 55 8.961 8.961 0.000 91 4342835 3000.0 2678.4
98 1,1,2,2-Tetrachloroethane 83 9.145 9.141 0.004 94 1145869 100.0 107.9
99 trans-1,4-Dichloro-2-butene 53 9.183 9.177 0.006 91 440136 100.0 103.5
100 Bromobenzene 156 9.186 9.186 0.000 97 763620 100.0 100.1
101 1,2,3-Trichloropropane 110 9.209 9.206 0.003 84 441205 100.0 105.5
102 N-Propylbenzene 120 9.260 9.264 -0.004 99 774990 100.0 95.1
103 2-Chlorotoluene 126 9.363 9.363 0.000 96 683816 100.0 96.0
104 1,3,5-Trimethylbenzene 105 9.431 9.434 -0.003 95 2353960 100.0 91.7
105 4-Chlorotoluene 126 9.479 9.479 0.000 98 720627 100.0 94.8
11/15/2024
3:53:55 PM
Page 249 of 777
Report Date: 29-Oct-2024 20:24:33 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003773.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
107 tert-Butylbenzene 119 9.749 9.749 0.000 93 2129835 100.0 95.7
108 1,2,4-Trimethylbenzene 105 9.804 9.807 -0.003 97 2480037 100.0 90.5
109 sec-Butylbenzene 134 9.968 9.968 0.000 94 629466 100.0 93.8
110 1,3-Dichlorobenzene 146 10.100 10.100 0.000 98 1396152 100.0 91.1
111 4-Isopropyltoluene 119 10.116 10.116 0.000 97 2661752 100.0 91.3
112 1,4-Dichlorobenzene 146 10.199 10.199 0.000 93 1378744 100.0 94.6
114 n-Butylbenzene 91 10.524 10.524 0.000 98 2499177 100.0 89.9
115 1,2-Dichlorobenzene 146 10.563 10.563 0.000 97 1358388 100.0 93.2
116 1,2-Dibromo-3-Chloropropane 157 11.347 11.347 0.000 90 493340 100.0 107.4
118 1,2,4-Trichlorobenzene 180 12.180 12.183 -0.003 94 979388 100.0 94.1
119 Hexachlorobutadiene 225 12.325 12.328 -0.003 98 414642 100.0 93.3
120 Naphthalene 128 12.456 12.456 0.000 97 4026289 100.0 96.6
121 1,2,3-Trichlorobenzene 180 12.681 12.681 0.000 95 984063 100.0 97.2
136 Butadiene 54 0.000 ND ND
S 154 1,3-Dichloropropene, Total 1 0 200.0 202.4
S 156 Total BTEX 1 0 459.8
S 151 1,2-Dichloroethene, Total 1 0 200.0 181.6
S 152 Trihalomethanes, Total 1 0 400.0 386.6
S 155 Xylenes, Total 106 0 200.0 184.4
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
MV-MegaMainA_00118 Amount Added: 50.00 Units: uL
MV-Gas A_00201 Amount Added: 20.00 Units: uL
mv-IS_SS_00089 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 250 of 777
Report Date: 29-Oct-2024 20:24:33 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003773.D
Injection Date:29-Oct-2024 17:22:25 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:ic Worklist Smp#:37
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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11/15/2024
3:53:55 PM
Page 251 of 777
Report Date: 29-Oct-2024 20:24:36 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003774.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:7
Inject. Date:29-Oct-2024 17:42:20 ALS Bottle#:0 Worklist Smp#:38
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ic 75
Operator ID:bustillose Instrument ID:VMS_MS14
Sublist:chrom-AQ_VMS14_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:29-Oct-2024 20:24:35 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:29-Oct-2024 20:15:11
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 98 1422085 50.0 50.0
* 2 Chlorobenzene-d5 119 7.926 7.929 -0.003 85 411645 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.174 10.177 -0.003 95 660180 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.842 4.842 0.000 93 357385 50.0 51.8
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.112 -0.003 97 426335 50.0 49.5
$ 6 Toluene-d8 (Surr) 98 6.637 6.637 0.000 93 1560400 50.0 48.1
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.035 -0.003 91 671345 50.0 53.1
10 Dichlorodifluoromethane 85 1.791 1.791 0.000 99 660308 75.0 80.6
12 Chloromethane 50 1.974 1.971 0.003 99 838366 75.0 79.3
13 Vinyl chloride 62 2.087 2.087 0.000 98 643412 75.0 79.8
15 Bromomethane 94 2.386 2.399 -0.013 90 403515 75.0 76.7
16 Chloroethane 64 2.489 2.495 -0.006 99 399995 75.0 79.5
17 Dichlorofluoromethane 67 2.675 2.675 0.000 97 971844 75.0 76.8
18 Trichlorofluoromethane 101 2.714 2.717 -0.003 98 728841 75.0 84.3
21 Ethyl ether 59 2.936 2.942 -0.006 90 423987 75.0 77.6
22 Acrolein 56 3.052 3.055 -0.003 100 2187381 740.6 789.6
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.138 3.138 0.000 94 290621 75.0 82.8
25 1,1-Dichloroethene 96 3.142 3.145 -0.003 98 416373 75.0 80.4
26 Acetone 43 3.161 3.158 0.003 100 2752790 300.0 302.8
29 Iodomethane 142 3.267 3.270 -0.003 99 472509 75.0 76.3
30 Carbon disulfide 76 3.334 3.334 0.000 99 1292017 75.0 84.0
32 Methyl acetate 43 3.396 3.395 0.001 97 2167234 150.0 143.5
33 3-Chloro-1-propene 41 3.421 3.424 -0.003 92 679422 75.0 76.7
34 Methylene Chloride 84 3.521 3.521 0.000 91 526978 75.0 72.6
35 2-Methyl-2-propanol 59 3.576 3.566 0.010 100 4518836 750.0 740.0
36 Acrylonitrile 53 3.688 3.688 0.000 98 6084208 750.0 756.7
37 Methyl tert-butyl ether 73 3.711 3.717 -0.006 93 1552707 75.0 76.9
38 trans-1,2-Dichloroethene 96 3.730 3.730 0.000 99 410075 75.0 74.8
39 Hexane 57 3.929 3.932 -0.003 90 618110 75.0 72.3
40 Vinyl acetate 43 4.032 4.029 0.003 97 2600010 150.0 159.4
42 1,1-Dichloroethane 63 4.058 4.058 0.000 96 769515 75.0 78.7
11/15/2024
3:53:55 PM
Page 252 of 777
Report Date: 29-Oct-2024 20:24:36 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003774.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
45 2-Butanone (MEK) 43 4.453 4.453 0.000 99 4361478 300.0 303.5
47 cis-1,2-Dichloroethene 96 4.482 4.482 0.000 80 487444 75.0 76.4
48 2,2-Dichloropropane 77 4.495 4.495 0.000 84 630282 75.0 82.7
50 sec-Butyl Alcohol 45 4.572 4.569 0.003 99 7556240 1800.0 1770.8
52 Chlorobromomethane 128 4.662 4.662 0.000 96 256824 75.0 76.9
53 Tetrahydrofuran 42 4.672 4.672 0.000 87 1296522 150.0 146.0
54 Chloroform 83 4.720 4.723 -0.003 93 759823 75.0 77.1
55 1,1,1-Trichloroethane 97 4.875 4.875 0.000 98 618990 75.0 81.1
56 Cyclohexane 56 4.936 4.939 -0.003 88 744238 75.0 79.9
57 1,1-Dichloropropene 75 4.987 4.987 0.000 98 622430 75.0 76.8
59 Carbon tetrachloride 117 4.994 4.997 -0.003 85 473911 75.0 82.0
58 Isobutyl alcohol 41 5.003 4.997 0.006 95 3016443 1875.0 1887.8
60 Benzene 78 5.148 5.145 0.003 95 1787722 75.0 76.1
61 1,2-Dichloroethane 62 5.170 5.167 0.003 97 632536 75.0 75.3
63 n-Heptane 43 5.328 5.331 -0.003 92 629313 75.0 75.5
65 Trichloroethene 95 5.640 5.640 0.000 99 508137 75.0 73.4
66 2-Pentanone 43 5.743 5.743 0.000 99 4783620 240.0 235.6
67 Methylcyclohexane 55 5.842 5.846 -0.004 91 588660 75.0 75.9
69 1,2-Dichloropropane 63 5.849 5.849 0.000 97 489410 75.0 78.5
70 1,4-Dioxane 88 5.900 5.900 0.000 93 483642 1500.0 1491.9
71 Dibromomethane 93 5.920 5.926 -0.006 97 326783 75.0 78.2
72 Dichlorobromomethane 83 6.045 6.045 0.000 100 564463 75.0 75.8
74 2-Chloroethyl vinyl ether 63 6.248 6.244 0.004 91 390399 75.0 77.1
75 cis-1,3-Dichloropropene 75 6.402 6.405 -0.003 96 828574 75.0 82.3
76 4-Methyl-2-pentanone (MIBK) 43 6.502 6.502 0.000 95 5347518 300.0 313.4
77 Toluene 91 6.695 6.698 -0.003 98 2041113 75.0 75.9
78 trans-1,3-Dichloropropene 75 6.868 6.871 -0.003 96 782249 75.0 74.5
79 Ethyl methacrylate 69 6.884 6.887 -0.003 89 1016966 75.0 77.2
80 1,1,2-Trichloroethane 97 7.045 7.048 -0.003 91 515161 75.0 79.1
82 Tetrachloroethene 164 7.148 7.148 0.000 97 367637 75.0 74.8
83 1,3-Dichloropropane 76 7.196 7.196 0.000 89 926329 75.0 74.5
84 2-Hexanone 43 7.215 7.215 0.000 96 4788047 300.0 289.3
85 Chlorodibromomethane 129 7.392 7.395 -0.003 90 475431 75.0 74.4
86 Ethylene Dibromide 107 7.518 7.518 0.000 98 584918 75.0 76.6
87 1-Chlorohexane 91 7.907 7.907 0.000 96 562940 60.0 61.2
88 Chlorobenzene 112 7.955 7.955 0.000 94 1406901 75.0 72.0
89 1,1,1,2-Tetrachloroethane 131 8.029 8.026 0.003 96 467346 75.0 79.0
90 Ethylbenzene 106 8.032 8.029 0.003 98 753725 75.0 72.9
91 m-Xylene & p-Xylene 106 8.148 8.148 0.000 100 930575 75.0 73.2
92 o-Xylene 106 8.514 8.514 0.000 95 936071 75.0 71.6
93 Styrene 104 8.527 8.530 -0.003 94 1603679 75.0 73.1
94 Bromoform 173 8.714 8.717 -0.003 96 375364 75.0 74.1
95 Isopropylbenzene 105 8.858 8.858 0.000 96 2246246 75.0 80.6
97 Cyclohexanone 55 8.961 8.961 0.000 91 3370777 2250.0 2026.3
98 1,1,2,2-Tetrachloroethane 83 9.145 9.141 0.004 94 888522 75.0 81.9
99 trans-1,4-Dichloro-2-butene 53 9.180 9.177 0.003 93 337532 75.0 77.8
100 Bromobenzene 156 9.186 9.186 0.000 97 597883 75.0 76.7
101 1,2,3-Trichloropropane 110 9.209 9.206 0.003 84 341489 75.0 80.0
102 N-Propylbenzene 120 9.260 9.264 -0.004 99 641292 75.0 77.0
103 2-Chlorotoluene 126 9.363 9.363 0.000 96 559498 75.0 76.9
104 1,3,5-Trimethylbenzene 105 9.431 9.434 -0.003 95 1917881 75.0 73.1
105 4-Chlorotoluene 126 9.479 9.479 0.000 98 571974 75.0 73.7
11/15/2024
3:53:55 PM
Page 253 of 777
Report Date: 29-Oct-2024 20:24:36 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003774.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
107 tert-Butylbenzene 119 9.749 9.749 0.000 93 1756402 75.0 77.3
108 1,2,4-Trimethylbenzene 105 9.804 9.807 -0.003 97 2034297 75.0 72.6
109 sec-Butylbenzene 134 9.968 9.968 0.000 94 520437 75.0 75.9
110 1,3-Dichlorobenzene 146 10.100 10.100 0.000 97 1133955 75.0 72.4
111 4-Isopropyltoluene 119 10.116 10.116 0.000 97 2220260 75.0 74.5
112 1,4-Dichlorobenzene 146 10.199 10.199 0.000 94 1127851 75.0 75.7
114 n-Butylbenzene 91 10.524 10.524 0.000 98 2098008 75.0 73.9
115 1,2-Dichlorobenzene 146 10.563 10.563 0.000 97 1078683 75.0 72.5
116 1,2-Dibromo-3-Chloropropane 157 11.347 11.347 0.000 85 364455 75.0 77.9
118 1,2,4-Trichlorobenzene 180 12.180 12.183 -0.003 94 787046 75.0 74.0
119 Hexachlorobutadiene 225 12.325 12.328 -0.003 98 342378 75.0 75.4
120 Naphthalene 128 12.456 12.456 0.000 97 3093054 75.0 72.6
121 1,2,3-Trichlorobenzene 180 12.678 12.681 -0.003 95 770852 75.0 74.4
136 Butadiene 54 0.000 ND ND
S 154 1,3-Dichloropropene, Total 1 0 150.0 156.8
S 156 Total BTEX 1 0 369.8
S 151 1,2-Dichloroethene, Total 1 0 150.0 151.3
S 152 Trihalomethanes, Total 1 0 300.0 301.4
S 155 Xylenes, Total 106 0 150.0 144.9
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
MV-MegaMainA_00118 Amount Added: 37.50 Units: uL
MV-Gas A_00201 Amount Added: 15.00 Units: uL
mv-IS_SS_00089 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 254 of 777
Report Date: 29-Oct-2024 20:24:36 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003774.D
Injection Date:29-Oct-2024 17:42:20 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:ic Worklist Smp#:38
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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11/15/2024
3:53:55 PM
Page 255 of 777
Report Date: 29-Oct-2024 20:24:38 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003775.D
Lims ID:icis
Client ID:
Sample Type:ICIS Calib Level:6
Inject. Date:29-Oct-2024 18:02:22 ALS Bottle#:0 Worklist Smp#:39
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:icis
Operator ID:bustillose Instrument ID:VMS_MS14
Sublist:chrom-AQ_VMS14_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:29-Oct-2024 20:24:38 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:29-Oct-2024 18:23:06
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 99 1366376 50.0 50.0
* 2 Chlorobenzene-d5 119 7.929 7.929 0.000 86 383025 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.176 10.176 0.000 96 685982 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.839 4.839 0.000 93 340083 50.0 51.3
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 94 414134 50.0 50.1
$ 6 Toluene-d8 (Surr) 98 6.636 6.636 0.000 93 1476507 50.0 48.9
$ 7 4-Bromofluorobenzene (Surr) 95 9.035 9.035 0.000 87 644540 50.0 49.1
10 Dichlorodifluoromethane 85 1.791 1.791 0.000 99 423454 50.0 54.0
12 Chloromethane 50 1.977 1.977 0.000 99 530246 50.0 52.2
13 Vinyl chloride 62 2.087 2.087 0.000 98 408639 50.0 52.8
15 Bromomethane 94 2.392 2.392 0.000 90 260399 50.0 51.5
16 Chloroethane 64 2.492 2.492 0.000 99 254379 50.0 52.6
17 Dichlorofluoromethane 67 2.675 2.675 0.000 97 626473 50.0 51.5
18 Trichlorofluoromethane 101 2.714 2.714 0.000 98 465599 50.0 56.0
21 Ethyl ether 59 2.939 2.939 0.000 91 282867 50.0 53.9
22 Acrolein 56 3.054 3.054 0.000 99 1446824 493.8 543.6
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.138 3.138 0.000 95 198558 50.0 58.9
25 1,1-Dichloroethene 96 3.138 3.138 0.000 98 273839 50.0 55.1
26 Acetone 43 3.160 3.160 0.000 100 1857237 200.0 210.7
29 Iodomethane 142 3.270 3.270 0.000 98 307130 50.0 52.2
30 Carbon disulfide 76 3.334 3.334 0.000 99 848413 50.0 57.4
32 Methyl acetate 43 3.398 3.398 0.000 97 1472932 100.0 101.5
33 3-Chloro-1-propene 41 3.421 3.421 0.000 92 459881 50.0 54.1
34 Methylene Chloride 84 3.517 3.517 0.000 91 354260 50.0 50.8
35 2-Methyl-2-propanol 59 3.575 3.575 0.000 100 2996340 500.0 510.7
36 Acrylonitrile 53 3.688 3.688 0.000 99 4121166 500.0 533.4
37 Methyl tert-butyl ether 73 3.717 3.717 0.000 93 1042880 50.0 53.7
38 trans-1,2-Dichloroethene 96 3.730 3.730 0.000 99 278162 50.0 52.8
39 Hexane 57 3.929 3.929 0.000 90 426162 50.0 53.6
40 Vinyl acetate 43 4.032 4.032 0.000 97 1702192 100.0 108.7
42 1,1-Dichloroethane 63 4.058 4.058 0.000 96 511810 50.0 54.5
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Report Date: 29-Oct-2024 20:24:38 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003775.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
45 2-Butanone (MEK) 43 4.456 4.456 0.000 100 2931896 200.0 211.5
47 cis-1,2-Dichloroethene 96 4.482 4.482 0.000 80 322267 50.0 52.6
48 2,2-Dichloropropane 77 4.495 4.495 0.000 85 413652 50.0 56.5
50 sec-Butyl Alcohol 45 4.575 4.575 0.000 99 5041291 1200.0 1229.6
52 Chlorobromomethane 128 4.662 4.662 0.000 96 167649 50.0 52.3
53 Tetrahydrofuran 42 4.675 4.675 0.000 88 869567 100.0 101.9
54 Chloroform 83 4.723 4.723 0.000 92 499112 50.0 52.7
55 1,1,1-Trichloroethane 97 4.874 4.874 0.000 98 416666 50.0 56.8
56 Cyclohexane 56 4.935 4.935 0.000 88 506106 50.0 56.6
57 1,1-Dichloropropene 75 4.987 4.987 0.000 99 425262 50.0 54.6
59 Carbon tetrachloride 117 4.993 4.993 0.000 94 310957 50.0 56.2
58 Isobutyl alcohol 41 5.003 5.003 0.000 95 2016158 1250.0 1313.2
60 Benzene 78 5.144 5.144 0.000 95 1189820 50.0 52.7
61 1,2-Dichloroethane 62 5.170 5.170 0.000 97 422176 50.0 52.3
63 n-Heptane 43 5.331 5.331 0.000 91 436858 50.0 54.6
65 Trichloroethene 95 5.640 5.640 0.000 99 328128 50.0 50.9
66 2-Pentanone 43 5.742 5.742 0.000 99 3188582 160.0 163.5
67 Methylcyclohexane 55 5.842 5.842 0.000 90 407818 50.0 54.7
69 1,2-Dichloropropane 63 5.849 5.849 0.000 97 319841 50.0 53.4
70 1,4-Dioxane 88 5.910 5.910 0.000 92 308138 1000.0 986.3
71 Dibromomethane 93 5.922 5.922 0.000 96 217876 50.0 54.3
72 Dichlorobromomethane 83 6.048 6.048 0.000 100 355841 50.0 50.0
74 2-Chloroethyl vinyl ether 63 6.247 6.247 0.000 92 248280 50.0 51.1
75 cis-1,3-Dichloropropene 75 6.402 6.402 0.000 97 529909 50.0 56.6
76 4-Methyl-2-pentanone (MIBK) 43 6.501 6.501 0.000 95 3585776 200.0 218.7
77 Toluene 91 6.697 6.697 0.000 98 1357635 50.0 52.6
78 trans-1,3-Dichloropropene 75 6.868 6.868 0.000 97 493160 50.0 49.1
79 Ethyl methacrylate 69 6.887 6.887 0.000 88 674124 50.0 55.0
80 1,1,2-Trichloroethane 97 7.048 7.048 0.000 91 331845 50.0 53.0
82 Tetrachloroethene 164 7.148 7.148 0.000 96 242737 50.0 53.1
83 1,3-Dichloropropane 76 7.196 7.196 0.000 89 599149 50.0 51.8
84 2-Hexanone 43 7.215 7.215 0.000 95 3242236 200.0 210.5
85 Chlorodibromomethane 129 7.395 7.395 0.000 90 293163 50.0 49.6
86 Ethylene Dibromide 107 7.517 7.517 0.000 97 376747 50.0 53.0
87 1-Chlorohexane 91 7.906 7.906 0.000 95 376603 40.0 43.9
88 Chlorobenzene 112 7.955 7.955 0.000 94 915363 50.0 50.3
89 1,1,1,2-Tetrachloroethane 131 8.025 8.025 0.000 95 292090 50.0 53.2
90 Ethylbenzene 106 8.032 8.032 0.000 98 495768 50.0 51.5
91 m-Xylene & p-Xylene 106 8.148 8.148 0.000 100 628118 50.0 53.1
92 o-Xylene 106 8.514 8.514 0.000 97 625580 50.0 51.4
93 Styrene 104 8.530 8.530 0.000 94 1067185 50.0 52.3
94 Bromoform 173 8.713 8.713 0.000 96 226066 50.0 48.5
95 Isopropylbenzene 105 8.858 8.858 0.000 96 1493408 50.0 51.5
97 Cyclohexanone 55 8.961 8.961 0.000 91 2195821 1500.0 1418.7
98 1,1,2,2-Tetrachloroethane 83 9.141 9.141 0.000 94 590063 50.0 52.4
99 trans-1,4-Dichloro-2-butene 53 9.183 9.183 0.000 85 219464 50.0 48.9
100 Bromobenzene 156 9.186 9.186 0.000 97 403031 50.0 49.8
101 1,2,3-Trichloropropane 110 9.212 9.212 0.000 76 233551 50.0 52.6
102 N-Propylbenzene 120 9.260 9.260 0.000 99 440574 50.0 50.9
103 2-Chlorotoluene 126 9.363 9.363 0.000 96 378039 50.0 50.0
104 1,3,5-Trimethylbenzene 105 9.430 9.430 0.000 95 1378443 50.0 50.6
105 4-Chlorotoluene 126 9.479 9.479 0.000 98 399786 50.0 49.6
11/15/2024
3:53:55 PM
Page 257 of 777
Report Date: 29-Oct-2024 20:24:38 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003775.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
107 tert-Butylbenzene 119 9.746 9.746 0.000 93 1206143 50.0 51.1
108 1,2,4-Trimethylbenzene 105 9.803 9.803 0.000 98 1454933 50.0 50.0
109 sec-Butylbenzene 134 9.967 9.967 0.000 94 362987 50.0 51.0
110 1,3-Dichlorobenzene 146 10.102 10.102 0.000 98 791409 50.0 48.6
111 4-Isopropyltoluene 119 10.115 10.115 0.000 97 1582460 50.0 51.1
112 1,4-Dichlorobenzene 146 10.199 10.199 0.000 95 788525 50.0 50.9
114 n-Butylbenzene 91 10.524 10.524 0.000 98 1504085 50.0 51.0
115 1,2-Dichlorobenzene 146 10.562 10.562 0.000 97 771289 50.0 49.9
116 1,2-Dibromo-3-Chloropropane 157 11.347 11.347 0.000 85 236077 50.0 48.9
118 1,2,4-Trichlorobenzene 180 12.183 12.183 0.000 94 568362 50.0 51.3
119 Hexachlorobutadiene 225 12.324 12.324 0.000 99 235598 50.0 49.9
120 Naphthalene 128 12.456 12.456 0.000 97 2155523 50.0 48.7
121 1,2,3-Trichlorobenzene 180 12.681 12.681 0.000 95 551010 50.0 51.1
136 Butadiene 54 0.000 ND ND
S 154 1,3-Dichloropropene, Total 1 0 100.0 105.7
S 151 1,2-Dichloroethene, Total 1 0 100.0 105.4
S 152 Trihalomethanes, Total 1 0 200.0 200.7
S 155 Xylenes, Total 106 0 100.0 104.6
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
MV-MegaMainA_00118 Amount Added: 25.00 Units: uL
MV-Gas A_00201 Amount Added: 10.00 Units: uL
mv-IS_SS_00089 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 258 of 777
Report Date: 29-Oct-2024 20:24:38 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003775.D
Injection Date:29-Oct-2024 18:02:22 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:icis Worklist Smp#:39
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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11/15/2024
3:53:55 PM
Page 259 of 777
Report Date: 29-Oct-2024 20:24:44 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003776.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:5
Inject. Date:29-Oct-2024 18:22:19 ALS Bottle#:0 Worklist Smp#:40
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ic 10
Operator ID:bustillose Instrument ID:VMS_MS14
Sublist:chrom-AQ_VMS14_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:29-Oct-2024 20:24:43 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:29-Oct-2024 19:04:27
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 99 1493641 50.0 50.0
* 2 Chlorobenzene-d5 119 7.929 7.929 0.000 86 379686 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.177 10.177 0.000 96 661667 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.842 4.842 0.000 93 362630 50.0 50.1
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.112 5.112 0.000 97 445088 50.0 49.2
$ 6 Toluene-d8 (Surr) 98 6.637 6.637 0.000 93 1565369 50.0 52.3
$ 7 4-Bromofluorobenzene (Surr) 95 9.035 9.035 0.000 86 624348 50.0 49.3
10 Dichlorodifluoromethane 85 1.791 1.791 0.000 99 78357 10.0 9.60
12 Chloromethane 50 1.971 1.971 0.000 99 100026 10.0 9.01
13 Vinyl chloride 62 2.087 2.087 0.000 97 79262 10.0 9.36
15 Bromomethane 94 2.399 2.399 0.000 91 51598 10.0 9.34
16 Chloroethane 64 2.495 2.495 0.000 99 50787 10.0 9.62
17 Dichlorofluoromethane 67 2.675 2.675 0.000 96 125520 10.0 9.44
18 Trichlorofluoromethane 101 2.717 2.717 0.000 98 84418 10.0 9.29
21 Ethyl ether 59 2.942 2.942 0.000 92 53387 10.0 9.31
22 Acrolein 56 3.055 3.055 0.000 100 266765 98.8 91.7
25 1,1-Dichloroethene 96 3.145 3.145 0.000 98 43911 10.0 8.23
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.138 3.138 0.000 80 31428 10.0 8.52
26 Acetone 43 3.158 3.158 0.000 100 404785 40.0 36.6
29 Iodomethane 142 3.270 3.270 0.000 98 49467 10.0 9.18
30 Carbon disulfide 76 3.334 3.334 0.000 99 141737 10.0 8.77
32 Methyl acetate 43 3.395 3.395 0.000 98 277337 20.0 17.5
33 3-Chloro-1-propene 41 3.424 3.424 0.000 93 81625 10.0 8.78
34 Methylene Chloride 84 3.521 3.521 0.000 89 72264 10.0 9.47
35 2-Methyl-2-propanol 59 3.566 3.566 0.000 100 600388 100.0 93.6
36 Acrylonitrile 53 3.688 3.688 0.000 99 826665 100.0 97.9
37 Methyl tert-butyl ether 73 3.717 3.717 0.000 94 208461 10.0 9.83
38 trans-1,2-Dichloroethene 96 3.730 3.730 0.000 99 53885 10.0 9.36
39 Hexane 57 3.932 3.932 0.000 92 71552 10.0 9.08
40 Vinyl acetate 43 4.029 4.029 0.000 97 304385 20.0 17.9
42 1,1-Dichloroethane 63 4.058 4.058 0.000 96 99689 10.0 9.70
11/15/2024
3:53:55 PM
Page 260 of 777
Report Date: 29-Oct-2024 20:24:44 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003776.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
45 2-Butanone (MEK) 43 4.453 4.453 0.000 100 570463 40.0 35.4
47 cis-1,2-Dichloroethene 96 4.482 4.482 0.000 80 63513 10.0 9.48
48 2,2-Dichloropropane 77 4.495 4.495 0.000 85 72679 10.0 9.08
50 sec-Butyl Alcohol 45 4.569 4.569 0.000 99 1041222 240.0 232.3
52 Chlorobromomethane 128 4.662 4.662 0.000 97 33370 10.0 9.52
53 Tetrahydrofuran 42 4.672 4.672 0.000 87 173068 20.0 18.6
54 Chloroform 83 4.723 4.723 0.000 93 98199 10.0 9.49
55 1,1,1-Trichloroethane 97 4.875 4.875 0.000 97 70719 10.0 8.82
56 Cyclohexane 56 4.939 4.939 0.000 89 81063 10.0 8.29
57 1,1-Dichloropropene 75 4.987 4.987 0.000 97 74865 10.0 8.79
59 Carbon tetrachloride 117 4.997 4.997 0.000 58 47469 10.0 8.36
58 Isobutyl alcohol 41 4.997 4.997 0.000 95 416809 250.0 248.4
60 Benzene 78 5.145 5.145 0.000 93 231035 10.0 9.36
61 1,2-Dichloroethane 62 5.167 5.167 0.000 97 84548 10.0 9.59
63 n-Heptane 43 5.331 5.331 0.000 87 75040 10.0 8.58
65 Trichloroethene 95 5.640 5.640 0.000 99 63804 10.0 10.0
66 2-Pentanone 43 5.743 5.743 0.000 99 612128 32.0 28.7
67 Methylcyclohexane 55 5.846 5.846 0.000 90 67820 10.0 8.32
69 1,2-Dichloropropane 63 5.849 5.849 0.000 96 61227 10.0 9.34
70 1,4-Dioxane 88 5.900 5.900 0.000 88 63473 200.0 178.6 M
71 Dibromomethane 93 5.926 5.926 0.000 97 40636 10.0 9.26
72 Dichlorobromomethane 83 6.045 6.045 0.000 99 61918 10.0 8.49
74 2-Chloroethyl vinyl ether 63 6.244 6.244 0.000 92 45467 10.0 8.83
75 cis-1,3-Dichloropropene 75 6.405 6.405 0.000 96 93675 10.0 10.1
76 4-Methyl-2-pentanone (MIBK) 43 6.502 6.502 0.000 95 684028 40.0 38.2
77 Toluene 91 6.698 6.698 0.000 98 259024 10.0 9.17
78 trans-1,3-Dichloropropene 75 6.871 6.871 0.000 93 82939 10.0 8.10
79 Ethyl methacrylate 69 6.887 6.887 0.000 88 118264 10.0 9.74
80 1,1,2-Trichloroethane 97 7.048 7.048 0.000 90 64278 10.0 9.39
82 Tetrachloroethene 164 7.148 7.148 0.000 97 42782 10.0 9.44
83 1,3-Dichloropropane 76 7.196 7.196 0.000 89 114660 10.0 10.0
84 2-Hexanone 43 7.215 7.215 0.000 95 635479 40.0 41.6
85 Chlorodibromomethane 129 7.395 7.395 0.000 90 45347 10.0 8.36
86 Ethylene Dibromide 107 7.518 7.518 0.000 98 69209 10.0 9.82
87 1-Chlorohexane 91 7.907 7.907 0.000 95 65775 8.00 7.43
88 Chlorobenzene 112 7.955 7.955 0.000 96 175306 10.0 9.72
89 1,1,1,2-Tetrachloroethane 131 8.026 8.026 0.000 93 49488 10.0 9.37
90 Ethylbenzene 106 8.029 8.029 0.000 98 91345 10.0 9.58
91 m-Xylene & p-Xylene 106 8.148 8.148 0.000 99 117614 10.0 10.0
92 o-Xylene 106 8.514 8.514 0.000 97 115861 10.0 9.61
93 Styrene 104 8.530 8.530 0.000 95 195567 10.0 9.67
94 Bromoform 173 8.717 8.717 0.000 95 32715 10.0 8.34
95 Isopropylbenzene 105 8.858 8.858 0.000 96 261053 10.0 9.34
97 Cyclohexanone 55 8.961 8.961 0.000 91 465684 300.0 303.5
98 1,1,2,2-Tetrachloroethane 83 9.141 9.141 0.000 94 102624 10.0 9.44
99 trans-1,4-Dichloro-2-butene 53 9.177 9.177 0.000 53 37425 10.0 9.09
100 Bromobenzene 156 9.186 9.186 0.000 96 74226 10.0 9.50
101 1,2,3-Trichloropropane 110 9.206 9.206 0.000 84 42075 10.0 9.83
102 N-Propylbenzene 120 9.264 9.264 0.000 99 82098 10.0 9.84
103 2-Chlorotoluene 126 9.363 9.363 0.000 96 72114 10.0 9.89
104 1,3,5-Trimethylbenzene 105 9.434 9.434 0.000 95 256381 10.0 9.75
105 4-Chlorotoluene 126 9.479 9.479 0.000 98 77079 10.0 9.90
11/15/2024
3:53:55 PM
Page 261 of 777
Report Date: 29-Oct-2024 20:24:44 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003776.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
107 tert-Butylbenzene 119 9.749 9.749 0.000 93 216755 10.0 9.52
108 1,2,4-Trimethylbenzene 105 9.807 9.807 0.000 97 276990 10.0 9.87
109 sec-Butylbenzene 134 9.968 9.968 0.000 94 63993 10.0 9.32
110 1,3-Dichlorobenzene 146 10.100 10.100 0.000 97 150233 10.0 9.57
111 4-Isopropyltoluene 119 10.116 10.116 0.000 97 287139 10.0 9.62
112 1,4-Dichlorobenzene 146 10.199 10.199 0.000 94 156943 10.0 10.3
114 n-Butylbenzene 91 10.524 10.524 0.000 98 280898 10.0 9.87
115 1,2-Dichlorobenzene 146 10.563 10.563 0.000 97 148081 10.0 9.93
116 1,2-Dibromo-3-Chloropropane 157 11.347 11.347 0.000 81 39290 10.0 9.15
118 1,2,4-Trichlorobenzene 180 12.183 12.183 0.000 94 112462 10.0 10.2
119 Hexachlorobutadiene 225 12.328 12.328 0.000 98 42702 10.0 9.38
120 Naphthalene 128 12.456 12.456 0.000 97 426056 10.0 9.98
121 1,2,3-Trichlorobenzene 180 12.681 12.681 0.000 95 109982 10.0 10.3
136 Butadiene 54 0.000 ND ND
S 154 1,3-Dichloropropene, Total 1 0 20.0 18.2
S 156 Total BTEX 1 0 47.8
S 151 1,2-Dichloroethene, Total 1 0 20.0 18.8
S 152 Trihalomethanes, Total 1 0 40.0 34.7
S 155 Xylenes, Total 106 0 20.0 19.6
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Review Flags
M - Manually Integrated
Reagents:
MV-MegaMainA_00118 Amount Added: 5.00 Units: uL
MV-Gas A_00201 Amount Added: 2.00 Units: uL
mv-IS_SS_00089 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 262 of 777
Report Date: 29-Oct-2024 20:24:44 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003776.D
Injection Date:29-Oct-2024 18:22:19 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:ic Worklist Smp#:40
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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11/15/2024
3:53:55 PM
Page 263 of 777
Report Date: 29-Oct-2024 20:24:44 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003776.D
Injection Date:29-Oct-2024 18:22:19 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:40
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
70 1,4-Dioxane, CAS: 123-91-1
Signal: 1
Processing Integration Results
RT: 5.91
Area: 45482
Amount: 195.0512
Amount Units: ug/l
5.6 5.8 6.0 6.2
Min
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4
6
8
10
12
14
16
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Y ( X10
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)
0000003776[MS Quad Chro]:m/z 88

5.9
1
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Manual Integration Results
RT: 5.90
Area: 63473
Amount: 178.5864
Amount Units: ug/l
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Reviewer: LP8K, 29-Oct-2024 19:04:01 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 264 of 777
Report Date: 29-Oct-2024 20:24:47 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003777.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:4
Inject. Date:29-Oct-2024 18:42:20 ALS Bottle#:0 Worklist Smp#:41
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ic 5
Operator ID:bustillose Instrument ID:VMS_MS14
Sublist:chrom-AQ_VMS14_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:29-Oct-2024 20:24:47 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:29-Oct-2024 19:56:30
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 99 1464951 50.0 50.0
* 2 Chlorobenzene-d5 119 7.929 7.929 0.000 86 379043 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.177 -0.004 96 685398 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.842 4.842 0.000 93 352051 50.0 49.6
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.112 5.112 0.000 98 448518 50.0 50.6
$ 6 Toluene-d8 (Surr) 98 6.636 6.637 -0.001 93 1547549 50.0 51.8
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.035 -0.003 86 649171 50.0 49.5
10 Dichlorodifluoromethane 85 1.791 1.791 0.000 98 34291 5.00 4.59
12 Chloromethane 50 1.974 1.971 0.003 99 54396 5.00 4.99
13 Vinyl chloride 62 2.086 2.087 -0.001 98 41924 5.00 5.05
15 Bromomethane 94 2.385 2.399 -0.014 91 25548 5.00 4.71
16 Chloroethane 64 2.485 2.495 -0.010 98 24903 5.00 4.81
17 Dichlorofluoromethane 67 2.672 2.675 -0.003 97 62899 5.00 4.82
18 Trichlorofluoromethane 101 2.710 2.717 -0.007 96 41308 5.00 4.64
21 Ethyl ether 59 2.938 2.942 -0.004 91 26406 5.00 4.69
22 Acrolein 56 3.054 3.055 -0.001 98 132334 49.4 46.4
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.138 3.138 0.000 66 17718 5.00 4.90
25 1,1-Dichloroethene 96 3.141 3.145 -0.004 97 24172 5.00 4.69
26 Acetone 43 3.164 3.158 0.006 100 246345 20.0 20.2
29 Iodomethane 142 3.266 3.270 -0.004 99 22446 5.00 5.18
30 Carbon disulfide 76 3.334 3.334 0.000 99 70061 5.00 4.42
32 Methyl acetate 43 3.395 3.395 0.000 97 143006 10.0 9.19
33 3-Chloro-1-propene 41 3.418 3.424 -0.006 85 49923 5.00 5.47
34 Methylene Chloride 84 3.520 3.521 -0.001 89 37545 5.00 5.02
35 2-Methyl-2-propanol 59 3.578 3.566 0.012 100 318286 50.0 50.6
36 Acrylonitrile 53 3.691 3.688 0.003 98 410766 50.0 49.6
37 Methyl tert-butyl ether 73 3.710 3.717 -0.007 93 100166 5.00 4.81
38 trans-1,2-Dichloroethene 96 3.726 3.730 -0.004 97 27411 5.00 4.86
39 Hexane 57 3.926 3.932 -0.006 93 37954 5.00 4.82
40 Vinyl acetate 43 4.032 4.029 0.003 97 156327 10.0 9.45
42 1,1-Dichloroethane 63 4.061 4.058 0.003 96 50089 5.00 4.97
11/15/2024
3:53:55 PM
Page 265 of 777
Report Date: 29-Oct-2024 20:24:47 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003777.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
45 2-Butanone (MEK) 43 4.456 4.453 0.003 100 344674 20.0 20.8
47 cis-1,2-Dichloroethene 96 4.482 4.482 0.000 79 31874 5.00 4.85
48 2,2-Dichloropropane 77 4.495 4.495 0.000 86 37012 5.00 4.71
50 sec-Butyl Alcohol 45 4.572 4.569 0.003 99 541115 120.0 123.1
52 Chlorobromomethane 128 4.662 4.662 0.000 95 16678 5.00 4.85
53 Tetrahydrofuran 42 4.678 4.672 0.006 88 90856 10.0 9.93
54 Chloroform 83 4.720 4.723 -0.003 93 49323 5.00 4.86
55 1,1,1-Trichloroethane 97 4.874 4.875 -0.001 97 35330 5.00 4.49
56 Cyclohexane 56 4.935 4.939 -0.004 89 45433 5.00 4.74
57 1,1-Dichloropropene 75 4.987 4.987 0.000 96 40178 5.00 4.81
59 Carbon tetrachloride 117 4.996 4.997 -0.001 83 22366 5.00 4.33
58 Isobutyl alcohol 41 5.003 4.997 0.006 94 212844 125.0 129.3
60 Benzene 78 5.144 5.145 -0.001 94 117202 5.00 4.84
61 1,2-Dichloroethane 62 5.170 5.167 0.003 97 42590 5.00 4.92
63 n-Heptane 43 5.331 5.331 0.000 84 44866 5.00 5.23
65 Trichloroethene 95 5.643 5.640 0.003 97 32154 5.00 5.04
66 2-Pentanone 43 5.745 5.743 0.002 99 322746 16.0 15.4
67 Methylcyclohexane 55 5.842 5.846 -0.004 92 38843 5.00 4.86
69 1,2-Dichloropropane 63 5.848 5.849 -0.001 90 31647 5.00 4.92
70 1,4-Dioxane 88 5.900 5.900 0.000 94 39442 100.0 109.9 M
71 Dibromomethane 93 5.919 5.926 -0.007 97 20915 5.00 4.86
72 Dichlorobromomethane 83 6.048 6.045 0.003 99 29250 5.00 4.42
74 2-Chloroethyl vinyl ether 63 6.247 6.244 0.003 93 23203 5.00 4.74
75 cis-1,3-Dichloropropene 75 6.405 6.405 0.000 96 42264 5.00 4.56
76 4-Methyl-2-pentanone (MIBK) 43 6.504 6.502 0.002 95 343818 20.0 19.6
77 Toluene 91 6.697 6.698 -0.001 98 133760 5.00 4.83
78 trans-1,3-Dichloropropene 75 6.871 6.871 0.000 92 39780 5.00 4.30
79 Ethyl methacrylate 69 6.884 6.887 -0.003 88 59170 5.00 4.88
80 1,1,2-Trichloroethane 97 7.048 7.048 0.000 91 31267 5.00 4.66
82 Tetrachloroethene 164 7.147 7.148 -0.001 93 24453 5.00 5.40
83 1,3-Dichloropropane 76 7.199 7.196 0.003 88 57731 5.00 5.04
84 2-Hexanone 43 7.215 7.215 0.000 95 312740 20.0 20.5
85 Chlorodibromomethane 129 7.395 7.395 0.000 92 19624 5.00 4.04
86 Ethylene Dibromide 107 7.514 7.518 -0.004 100 34294 5.00 4.88
87 1-Chlorohexane 91 7.906 7.907 -0.001 94 37628 4.00 4.10
88 Chlorobenzene 112 7.958 7.955 0.003 95 89361 5.00 4.97
89 1,1,1,2-Tetrachloroethane 131 8.025 8.026 -0.001 40 22277 5.00 4.41
90 Ethylbenzene 106 8.028 8.029 -0.001 98 48546 5.00 5.10
91 m-Xylene & p-Xylene 106 8.147 8.148 -0.001 99 59409 5.00 5.08
92 o-Xylene 106 8.517 8.514 0.003 92 60699 5.00 5.04
93 Styrene 104 8.527 8.530 -0.003 94 101377 5.00 5.02
94 Bromoform 173 8.713 8.717 -0.004 91 13780 5.00 4.38
95 Isopropylbenzene 105 8.855 8.858 -0.003 96 137873 5.00 4.76
97 Cyclohexanone 55 8.961 8.961 0.000 92 253436 150.0 165.5
98 1,1,2,2-Tetrachloroethane 83 9.141 9.141 0.000 96 52231 5.00 4.64
99 trans-1,4-Dichloro-2-butene 53 9.183 9.177 0.006 49 14745 5.00 3.79
100 Bromobenzene 156 9.186 9.186 0.000 96 39078 5.00 4.83
101 1,2,3-Trichloropropane 110 9.212 9.206 0.006 78 21761 5.00 4.91
102 N-Propylbenzene 120 9.260 9.264 -0.004 99 42372 5.00 4.90
103 2-Chlorotoluene 126 9.363 9.363 0.000 96 35814 5.00 4.74
104 1,3,5-Trimethylbenzene 105 9.430 9.434 -0.004 94 133991 5.00 4.92
105 4-Chlorotoluene 126 9.479 9.479 -0.001 98 40245 5.00 4.99
11/15/2024
3:53:55 PM
Page 266 of 777
Report Date: 29-Oct-2024 20:24:47 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003777.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
107 tert-Butylbenzene 119 9.745 9.749 -0.004 92 112653 5.00 4.77
108 1,2,4-Trimethylbenzene 105 9.806 9.807 -0.001 97 145759 5.00 5.01
109 sec-Butylbenzene 134 9.970 9.968 0.002 94 33379 5.00 4.69
110 1,3-Dichlorobenzene 146 10.102 10.100 0.002 97 77835 5.00 4.79
111 4-Isopropyltoluene 119 10.118 10.116 0.002 97 153026 5.00 4.95
112 1,4-Dichlorobenzene 146 10.199 10.199 0.000 94 83431 5.00 5.15
114 n-Butylbenzene 91 10.523 10.524 -0.001 98 148026 5.00 5.02
115 1,2-Dichlorobenzene 146 10.562 10.563 -0.001 97 78062 5.00 5.05
116 1,2-Dibromo-3-Chloropropane 157 11.347 11.347 0.000 78 16730 5.00 4.27
118 1,2,4-Trichlorobenzene 180 12.186 12.183 0.003 94 61836 5.00 5.22
119 Hexachlorobutadiene 225 12.324 12.328 -0.004 97 22809 5.00 4.84
120 Naphthalene 128 12.459 12.456 0.003 97 220758 5.00 4.99
121 1,2,3-Trichlorobenzene 180 12.684 12.681 0.003 95 58538 5.00 5.10
136 Butadiene 54 0.000 ND ND
S 154 1,3-Dichloropropene, Total 1 0 10.0 8.86
S 156 Total BTEX 1 0 24.9
S 151 1,2-Dichloroethene, Total 1 0 10.0 9.71
S 152 Trihalomethanes, Total 1 0 20.0 17.7
S 155 Xylenes, Total 106 0 10.0 10.1
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Review Flags
M - Manually Integrated
Reagents:
Cal Dil Std_00424 Amount Added: 50.00 Units: uL
mv-IS_SS_00089 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 267 of 777
Report Date: 29-Oct-2024 20:24:47 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003777.D
Injection Date:29-Oct-2024 18:42:20 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:ic Worklist Smp#:41
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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11/15/2024
3:53:55 PM
Page 268 of 777
Report Date: 29-Oct-2024 20:24:47 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003777.D
Injection Date:29-Oct-2024 18:42:20 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:41
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
70 1,4-Dioxane, CAS: 123-91-1
Signal: 1
Processing Integration Results
RT: 5.89
Area: 11583
Amount: 91.555965
Amount Units: ug/l
5.6 5.8 6.0 6.2
Min
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0000003777[MS Quad Chro]:m/z 88

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Manual Integration Results
RT: 5.90
Area: 39442
Amount: 109.8656
Amount Units: ug/l
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Reviewer: LP8K, 29-Oct-2024 19:04:51 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 269 of 777
Report Date: 29-Oct-2024 20:24:51 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003778.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:3
Inject. Date:29-Oct-2024 19:02:19 ALS Bottle#:0 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ic 2
Operator ID:bustillose Instrument ID:VMS_MS14
Sublist:chrom-AQ_VMS14_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:29-Oct-2024 20:24:50 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:29-Oct-2024 19:58:03
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 99 1475488 50.0 50.0
* 2 Chlorobenzene-d5 119 7.929 7.929 0.000 86 382237 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.177 -0.004 96 682311 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.839 4.842 -0.003 93 347508 50.0 48.6
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.112 -0.003 98 453237 50.0 50.7
$ 6 Toluene-d8 (Surr) 98 6.637 6.637 0.000 93 1554364 50.0 51.6
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.035 -0.003 86 643127 50.0 49.3
10 Dichlorodifluoromethane 85 1.794 1.791 0.003 97 11770 2.00 1.93
12 Chloromethane 50 1.971 1.971 0.000 99 21161 2.00 1.93
13 Vinyl chloride 62 2.087 2.087 0.000 97 16846 2.00 2.01
15 Bromomethane 94 2.389 2.399 -0.010 87 11355 2.00 2.08
16 Chloroethane 64 2.489 2.495 -0.006 99 10095 2.00 1.93
17 Dichlorofluoromethane 67 2.675 2.675 0.000 97 25607 2.00 1.95
18 Trichlorofluoromethane 101 2.717 2.717 0.000 97 16564 2.00 1.85
21 Ethyl ether 59 2.942 2.942 0.000 90 10955 2.00 1.93
22 Acrolein 56 3.055 3.055 0.000 99 50968 19.8 17.7
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.135 3.138 -0.003 62 7493 2.00 2.06
25 1,1-Dichloroethene 96 3.142 3.145 -0.003 83 9660 2.00 1.96
26 Acetone 43 3.161 3.158 0.003 100 129392 8.00 7.33
29 Iodomethane 142 3.273 3.270 0.003 98 10192 2.00 3.30
30 Carbon disulfide 76 3.334 3.334 0.000 99 30442 2.00 1.91
32 Methyl acetate 43 3.402 3.395 0.007 97 59766 4.00 3.81
33 3-Chloro-1-propene 41 3.421 3.424 -0.003 82 20380 2.00 2.22
34 Methylene Chloride 84 3.521 3.521 0.000 88 15325 2.00 2.03
35 2-Methyl-2-propanol 59 3.579 3.566 0.013 99 122425 20.0 19.3 M
36 Acrylonitrile 53 3.688 3.688 0.000 99 165096 20.0 19.8
37 Methyl tert-butyl ether 73 3.717 3.717 0.000 95 42607 2.00 2.03
38 trans-1,2-Dichloroethene 96 3.730 3.730 0.000 90 11987 2.00 2.11
39 Hexane 57 3.929 3.932 -0.003 88 17104 2.00 2.16
40 Vinyl acetate 43 4.029 4.029 0.000 97 60777 4.00 3.74
42 1,1-Dichloroethane 63 4.061 4.058 0.003 95 20276 2.00 2.00
11/15/2024
3:53:55 PM
Page 270 of 777
Report Date: 29-Oct-2024 20:24:51 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003778.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
45 2-Butanone (MEK) 43 4.453 4.453 0.000 100 158755 8.00 8.06
47 cis-1,2-Dichloroethene 96 4.482 4.482 0.000 81 13188 2.00 1.99
48 2,2-Dichloropropane 77 4.498 4.495 0.003 85 15684 2.00 1.98
50 sec-Butyl Alcohol 45 4.572 4.569 0.003 98 205735 48.0 46.5
52 Chlorobromomethane 128 4.662 4.662 0.000 87 7335 2.00 2.12 Ma
53 Tetrahydrofuran 42 4.678 4.672 0.006 89 35869 4.00 3.89
54 Chloroform 83 4.720 4.723 -0.003 91 19986 2.00 1.96
55 1,1,1-Trichloroethane 97 4.878 4.875 0.003 64 15355 2.00 1.94 M
56 Cyclohexane 56 4.939 4.939 0.000 89 18806 2.00 1.95
57 1,1-Dichloropropene 75 4.990 4.987 0.003 96 17024 2.00 2.02
59 Carbon tetrachloride 117 5.000 4.997 0.003 65 8762 2.00 2.05 M
58 Isobutyl alcohol 41 5.010 4.997 0.013 94 69967 50.0 42.2
60 Benzene 78 5.148 5.145 0.003 91 49844 2.00 2.05
61 1,2-Dichloroethane 62 5.164 5.167 -0.003 93 17368 2.00 1.99 a
63 n-Heptane 43 5.328 5.331 -0.003 78 20573 2.00 2.38 a
65 Trichloroethene 95 5.640 5.640 0.000 97 13750 2.00 2.14
66 2-Pentanone 43 5.743 5.743 0.000 99 132620 6.40 6.30
67 Methylcyclohexane 55 5.839 5.846 -0.007 89 16214 2.00 2.01 M
69 1,2-Dichloropropane 63 5.849 5.849 0.000 74 12565 2.00 1.94
70 1,4-Dioxane 88 5.910 5.900 0.010 89 15518 40.0 37.5 M
71 Dibromomethane 93 5.923 5.926 -0.003 92 9166 2.00 2.11
72 Dichlorobromomethane 83 6.045 6.045 0.000 96 10634 2.00 2.01 M
74 2-Chloroethyl vinyl ether 63 6.241 6.244 -0.003 91 8854 2.00 1.99 M
75 cis-1,3-Dichloropropene 75 6.402 6.405 -0.003 95 16823 2.00 1.80
76 4-Methyl-2-pentanone (MIBK) 43 6.505 6.502 0.003 96 133735 8.00 7.55
77 Toluene 91 6.694 6.698 -0.004 98 56998 2.00 2.04
78 trans-1,3-Dichloropropene 75 6.865 6.871 -0.006 81 14951 2.00 2.01
79 Ethyl methacrylate 69 6.881 6.887 -0.006 90 23702 2.00 1.94
80 1,1,2-Trichloroethane 97 7.045 7.048 -0.003 90 12779 2.00 1.89
82 Tetrachloroethene 164 7.151 7.148 0.003 96 9892 2.00 2.17
83 1,3-Dichloropropane 76 7.196 7.196 0.000 89 22977 2.00 1.99
84 2-Hexanone 43 7.215 7.215 0.000 95 122207 8.00 7.95
85 Chlorodibromomethane 129 7.399 7.395 0.004 87 7550 2.00 2.00 M
86 Ethylene Dibromide 107 7.514 7.518 -0.004 96 13395 2.00 1.89
87 1-Chlorohexane 91 7.907 7.907 0.000 95 18131 1.60 1.76
88 Chlorobenzene 112 7.958 7.955 0.003 94 36898 2.00 2.03
89 1,1,1,2-Tetrachloroethane 131 8.026 8.026 0.000 41 9150 2.00 1.99
90 Ethylbenzene 106 8.035 8.029 0.006 98 19324 2.00 2.01
91 m-Xylene & p-Xylene 106 8.148 8.148 0.000 99 23753 2.00 2.01
92 o-Xylene 106 8.514 8.514 0.000 97 26352 2.00 2.17
93 Styrene 104 8.527 8.530 -0.003 94 40940 2.00 2.01
94 Bromoform 173 8.711 8.717 -0.007 94 5415 2.00 2.61
95 Isopropylbenzene 105 8.855 8.858 -0.003 96 58458 2.00 2.03
97 Cyclohexanone 55 8.958 8.961 -0.003 91 95555 60.0 61.9
98 1,1,2,2-Tetrachloroethane 83 9.138 9.141 -0.003 95 19844 2.00 1.77
99 trans-1,4-Dichloro-2-butene 53 9.177 9.177 0.000 49 7170 2.00 2.13
100 Bromobenzene 156 9.186 9.186 0.000 96 16959 2.00 2.11
101 1,2,3-Trichloropropane 110 9.209 9.206 0.003 79 8763 2.00 1.99
102 N-Propylbenzene 120 9.264 9.264 0.000 99 17870 2.00 2.08
103 2-Chlorotoluene 126 9.360 9.363 -0.003 96 15899 2.00 2.11
104 1,3,5-Trimethylbenzene 105 9.431 9.434 -0.003 95 57808 2.00 2.13
105 4-Chlorotoluene 126 9.479 9.479 0.000 97 17829 2.00 2.22
11/15/2024
3:53:55 PM
Page 271 of 777
Report Date: 29-Oct-2024 20:24:51 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003778.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
107 tert-Butylbenzene 119 9.746 9.749 -0.003 93 47291 2.00 2.01
108 1,2,4-Trimethylbenzene 105 9.804 9.807 -0.003 97 60526 2.00 2.09
109 sec-Butylbenzene 134 9.965 9.968 -0.004 94 15267 2.00 2.16
110 1,3-Dichlorobenzene 146 10.103 10.100 0.003 97 33991 2.00 2.10
111 4-Isopropyltoluene 119 10.116 10.116 0.000 97 64193 2.00 2.08
112 1,4-Dichlorobenzene 146 10.199 10.199 0.000 94 37543 2.00 2.19
114 n-Butylbenzene 91 10.527 10.524 0.003 97 63895 2.00 2.18
115 1,2-Dichlorobenzene 146 10.566 10.563 0.003 97 33779 2.00 2.20
116 1,2-Dibromo-3-Chloropropane 157 11.350 11.347 0.003 80 6251 2.00 2.15 M
118 1,2,4-Trichlorobenzene 180 12.180 12.183 -0.003 92 27797 2.00 2.13
119 Hexachlorobutadiene 225 12.325 12.328 -0.003 97 9947 2.00 2.12
120 Naphthalene 128 12.453 12.456 -0.003 97 89090 2.00 2.02
121 1,2,3-Trichlorobenzene 180 12.685 12.681 0.004 93 25762 2.00 2.05 Ma
136 Butadiene 54 0.000 ND ND
S 154 1,3-Dichloropropene, Total 1 0 4.00 3.81
S 156 Total BTEX 1 0 10.3
S 151 1,2-Dichloroethene, Total 1 0 4.00 4.10
S 152 Trihalomethanes, Total 1 0 8.00 8.58
S 155 Xylenes, Total 106 0 4.00 4.18
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Review Flags
M - Manually Integrated
a - User Assigned ID
Reagents:
Cal Dil Std_00424 Amount Added: 20.00 Units: uL
mv-IS_SS_00089 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 272 of 777
Report Date: 29-Oct-2024 20:24:51 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003778.D
Injection Date:29-Oct-2024 19:02:19 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:ic Worklist Smp#:42
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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11/15/2024
3:53:55 PM
Page 273 of 777
Report Date: 29-Oct-2024 20:24:51 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003778.D
Injection Date:29-Oct-2024 19:02:19 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
35 2-Methyl-2-propanol, CAS: 75-65-0
Signal: 1
Processing Integration Results
RT: 3.57
Area: 34952
Amount: 15.388236
Amount Units: ug/l
3.2 3.4 3.6 3.8 4.0
Min
0
3
6
9
12
15
18
21
24
27
30
33
Y ( X10
0
0
)
0000003778[MS Quad Chro]:m/z 59

3
.
5
69
Manual Integration Results
RT: 3.58
Area: 122425
Amount: 19.322027
Amount Units: ug/l
3.2 3.4 3.6 3.8 4.0
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
Y ( X10
0
0
)
0000003778[MS Quad Chro]:m/z 59

3
.
5
7
9
Reviewer: LP8K, 29-Oct-2024 19:56:45 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 274 of 777
Report Date: 29-Oct-2024 20:24:51 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003778.D
Injection Date:29-Oct-2024 19:02:19 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
52 Chlorobromomethane, CAS: 74-97-5
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 4.66
4.3 4.5 4.7 4.9
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
Y ( X10
0
)
0000003778[MS Quad Chro]:m/z 128
Manual Integration Results
RT: 4.66
Area: 7335
Amount: 2.117556
Amount Units: ug/l
4.3 4.5 4.7 4.9
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
Y ( X10
0
)
0000003778[MS Quad Chro]:m/z 128

4
.
66
2
Reviewer: LP8K, 29-Oct-2024 19:56:57 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Missed Peak
11/15/2024
3:53:55 PM
Page 275 of 777
Report Date: 29-Oct-2024 20:24:51 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003778.D
Injection Date:29-Oct-2024 19:02:19 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
55 1,1,1-Trichloroethane, CAS: 71-55-6
Signal: 1
Processing Integration Results
RT: 4.87
Area: 6285
Amount: 1.930768
Amount Units: ug/l
4.5 4.7 4.9 5.1
Min
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
Y ( X10
0
)
0000003778[MS Quad Chro]:m/z 97

4
.
8
68
Manual Integration Results
RT: 4.88
Area: 15355
Amount: 1.938825
Amount Units: ug/l
4.5 4.7 4.9 5.1
Min
RT
0
6
12
18
24
30
36
42
48
54
60
66
72
78
Y ( X10
0
)
0000003778[MS Quad Chro]:m/z 97

4
.
8
7
8
Reviewer: LP8K, 29-Oct-2024 19:57:04 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 276 of 777
Report Date: 29-Oct-2024 20:24:51 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003778.D
Injection Date:29-Oct-2024 19:02:19 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
59 Carbon tetrachloride, CAS: 56-23-5
Signal: 1
Processing Integration Results
RT: 5.00
Area: 5180
Amount: 1.620263
Amount Units: ug/l
4.7 4.9 5.1 5.3
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
45
Y ( X10
0
)
0000003778[MS Quad Chro]:m/z 117

5
.
0
0
0
Manual Integration Results
RT: 5.00
Area: 8762
Amount: 2.048059
Amount Units: ug/l
4.7 4.9 5.1 5.3
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
Y ( X10
0
)
0000003778[MS Quad Chro]:m/z 117

5
.
0
0
0
Reviewer: LP8K, 29-Oct-2024 20:15:33 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 277 of 777
Report Date: 29-Oct-2024 20:24:51 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003778.D
Injection Date:29-Oct-2024 19:02:19 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
61 1,2-Dichloroethane, CAS: 107-06-2
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 5.17
4.8 5.0 5.2 5.4
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
Y ( X10
0
0
)
0000003778[MS Quad Chro]:m/z 62
Manual Integration Results
RT: 5.16
Area: 17368
Amount: 1.993621
Amount Units: ug/l
4.8 5.0 5.2 5.4
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
12
Y ( X10
0
0
)
0000003778[MS Quad Chro]:m/z 62

5
.
1
64
Reviewer: LP8K, 29-Oct-2024 19:57:09 -06:00:00 (UTC)
Audit Action: Assigned Compound ID Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 278 of 777
Report Date: 29-Oct-2024 20:24:51 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003778.D
Injection Date:29-Oct-2024 19:02:19 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
63 n-Heptane, CAS: 142-82-5
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 5.33
5.0 5.2 5.4 5.6
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
Y ( X10
0
0
)
0000003778[MS Quad Chro]:m/z 43
Manual Integration Results
RT: 5.33
Area: 20573
Amount: 2.379911
Amount Units: ug/l
5.0 5.2 5.4 5.6
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
12
13
Y ( X10
0
0
)
0000003778[MS Quad Chro]:m/z 43

5
.
3
2
8
Reviewer: LP8K, 29-Oct-2024 19:57:13 -06:00:00 (UTC)
Audit Action: Assigned Compound ID Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 279 of 777
Report Date: 29-Oct-2024 20:24:51 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003778.D
Injection Date:29-Oct-2024 19:02:19 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
67 Methylcyclohexane, CAS: 108-87-2
Signal: 1
Processing Integration Results
RT: 5.84
Area: 12251
Amount: 1.688882
Amount Units: ug/l
5.5 5.7 5.9 6.1
Min
0
6
12
18
24
30
36
42
48
54
60
66
72
78
84
90
Y ( X10
0
)
0000003778[MS Quad Chro]:m/z 55

5
.
8
3
9
Manual Integration Results
RT: 5.84
Area: 16214
Amount: 2.014710
Amount Units: ug/l
5.5 5.7 5.9 6.1
Min
RT
0
7
14
21
28
35
42
49
56
63
70
77
84
91
Y ( X10
0
)
0000003778[MS Quad Chro]:m/z 55

5
.
8
3
9
Reviewer: LP8K, 29-Oct-2024 19:57:19 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 280 of 777
Report Date: 29-Oct-2024 20:24:51 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003778.D
Injection Date:29-Oct-2024 19:02:19 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
70 1,4-Dioxane, CAS: 123-91-1
Signal: 1
Processing Integration Results
RT: 5.89
Area: 2390
Amount: 30.207103
Amount Units: ug/l
5.6 5.8 6.0 6.2
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
Y ( X10
0
)
0000003778[MS Quad Chro]:m/z 88

5
.
8
9
4
Manual Integration Results
RT: 5.91
Area: 15518
Amount: 37.460570
Amount Units: ug/l
5.6 5.8 6.0 6.2
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
39
Y ( X10
0
)
0000003778[MS Quad Chro]:m/z 88

5
.
9
1
0
Reviewer: LP8K, 29-Oct-2024 19:57:22 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 281 of 777
Report Date: 29-Oct-2024 20:24:51 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003778.D
Injection Date:29-Oct-2024 19:02:19 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
72 Dichlorobromomethane, CAS: 75-27-4
Signal: 1
Processing Integration Results
RT: 6.04
Area: 8364
Amount: 2.055399
Amount Units: ug/l
5.7 5.9 6.1 6.3
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
Y ( X10
0
0
)
0000003778[MS Quad Chro]:m/z 83

6.0
4
5
Manual Integration Results
RT: 6.04
Area: 10634
Amount: 2.008210
Amount Units: ug/l
5.7 5.9 6.1 6.3
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
12
13
Y ( X10
0
0
)
0000003778[MS Quad Chro]:m/z 83

6.0
4
5
Reviewer: LP8K, 29-Oct-2024 19:57:27 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 282 of 777
Report Date: 29-Oct-2024 20:24:51 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003778.D
Injection Date:29-Oct-2024 19:02:19 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
74 2-Chloroethyl vinyl ether, CAS: 110-75-8
Signal: 1
Processing Integration Results
RT: 6.24
Area: 4814
Amount: 1.975211
Amount Units: ug/l
5.9 6.1 6.3 6.5
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
Y ( X10
0
)
0000003778[MS Quad Chro]:m/z 63

6.2
4
1
Manual Integration Results
RT: 6.24
Area: 8854
Amount: 1.993017
Amount Units: ug/l
5.9 6.1 6.3 6.5
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
48
Y ( X10
0
)
0000003778[MS Quad Chro]:m/z 63

6.2
4
1
Reviewer: LP8K, 29-Oct-2024 19:57:29 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 283 of 777
Report Date: 29-Oct-2024 20:24:51 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003778.D
Injection Date:29-Oct-2024 19:02:19 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
85 Chlorodibromomethane, CAS: 124-48-1
Signal: 1
Processing Integration Results
RT: 7.40
Area: 4583
Amount: 2.079437
Amount Units: ug/l
7.1 7.3 7.5 7.7
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
52
56
Y ( X10
0
)
0000003778[MS Quad Chro]:m/z 129

7
.
3
9
9
Manual Integration Results
RT: 7.40
Area: 7550
Amount: 2.000276
Amount Units: ug/l
7.1 7.3 7.5 7.7
Min
RT
0
5
10
15
20
25
30
35
40
45
50
55
Y ( X10
0
)
0000003778[MS Quad Chro]:m/z 129

7
.
3
9
9
Reviewer: LP8K, 29-Oct-2024 19:57:36 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 284 of 777
Report Date: 29-Oct-2024 20:24:51 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003778.D
Injection Date:29-Oct-2024 19:02:19 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
116 1,2-Dibromo-3-Chloropropane, CAS: 96-12-8
Signal: 1
Processing Integration Results
RT: 11.35
Area: 4700
Amount: 2.098493
Amount Units: ug/l
11.0 11.2 11.4 11.6
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
Y ( X10
0
)
0000003778[MS Quad Chro]:m/z 157
1
1
.
3
5
0
Manual Integration Results
RT: 11.35
Area: 6251
Amount: 2.145580
Amount Units: ug/l
11.0 11.2 11.4 11.6
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
Y ( X10
0
)
0000003778[MS Quad Chro]:m/z 157
1
1
.
3
5
0
Reviewer: LP8K, 29-Oct-2024 19:57:48 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 285 of 777
Report Date: 29-Oct-2024 20:24:51 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003778.D
Injection Date:29-Oct-2024 19:02:19 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
121 1,2,3-Trichlorobenzene, CAS: 87-61-6
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 12.68
12.3 12.5 12.7 12.9
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Y ( X10
0
0
)
0000003778[MS Quad Chro]:m/z 180
Manual Integration Results
RT: 12.68
Area: 25762
Amount: 2.050912
Amount Units: ug/l
12.3 12.5 12.7 12.9
Min
RT
0
2
4
6
8
10
12
14
Y ( X10
0
0
)
0000003778[MS Quad Chro]:m/z 180
1
2
.
685
Reviewer: LP8K, 29-Oct-2024 19:57:58 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Missed Peak
11/15/2024
3:53:55 PM
Page 286 of 777
Report Date: 29-Oct-2024 20:24:54 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003779.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:2
Inject. Date:29-Oct-2024 19:22:16 ALS Bottle#:0 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ic 1
Operator ID:bustillose Instrument ID:VMS_MS14
Sublist:chrom-AQ_VMS14_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:29-Oct-2024 20:24:54 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:29-Oct-2024 19:58:55
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 99 1454915 50.0 50.0
* 2 Chlorobenzene-d5 119 7.929 7.929 0.000 86 373796 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.177 -0.004 96 674931 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.839 4.842 -0.003 93 340868 50.0 48.3
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.112 5.112 0.000 98 442345 50.0 50.2
$ 6 Toluene-d8 (Surr) 98 6.637 6.637 0.000 93 1521861 50.0 51.7
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.035 -0.003 91 630640 50.0 48.8
10 Dichlorodifluoromethane 85 1.788 1.791 -0.003 96 4032 1.00 1.03
12 Chloromethane 50 1.974 1.971 0.003 99 10397 1.00 0.9612
13 Vinyl chloride 62 2.090 2.087 0.003 97 8079 1.00 0.9796
15 Bromomethane 94 2.376 2.399 -0.023 91 5861 1.00 1.09
16 Chloroethane 64 2.489 2.495 -0.006 48 5123 1.00 1.00
17 Dichlorofluoromethane 67 2.678 2.675 0.003 96 12874 1.00 0.99
18 Trichlorofluoromethane 101 2.714 2.717 -0.003 96 8427 1.00 0.9524
21 Ethyl ether 59 2.939 2.942 -0.003 92 5514 1.00 0.9870
22 Acrolein 56 3.055 3.055 0.000 97 25249 9.88 8.91
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.138 3.138 0.000 75 3548 1.00 0.9880
25 1,1-Dichloroethene 96 3.151 3.145 0.006 95 5210 1.00 1.15
26 Acetone 43 3.164 3.158 0.006 100 103027 4.00 4.63
29 Iodomethane 142 3.270 3.270 0.000 98 5058 1.00 2.53
30 Carbon disulfide 76 3.334 3.334 0.000 98 13806 1.00 0.8774
32 Methyl acetate 43 3.395 3.395 0.000 98 33890 2.00 2.19
33 3-Chloro-1-propene 41 3.412 3.424 -0.012 65 15127 1.00 1.67 Ma
34 Methylene Chloride 84 3.521 3.521 0.000 92 9086 1.00 1.22 M
35 2-Methyl-2-propanol 59 3.582 3.566 0.016 100 67598 10.0 10.8
36 Acrylonitrile 53 3.685 3.688 -0.003 98 80993 10.0 9.85
37 Methyl tert-butyl ether 73 3.714 3.717 -0.003 95 20831 1.00 1.01
38 trans-1,2-Dichloroethene 96 3.730 3.730 0.000 96 5737 1.00 1.02
39 Hexane 57 3.926 3.932 -0.006 91 8522 1.00 1.10
40 Vinyl acetate 43 4.032 4.029 0.003 97 28665 2.00 1.87
42 1,1-Dichloroethane 63 4.061 4.058 0.003 92 10057 1.00 1.01 M
11/15/2024
3:53:55 PM
Page 287 of 777
Report Date: 29-Oct-2024 20:24:54 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003779.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
45 2-Butanone (MEK) 43 4.457 4.453 0.004 100 102827 4.00 4.38
47 cis-1,2-Dichloroethene 96 4.486 4.482 0.004 47 6877 1.00 1.05
48 2,2-Dichloropropane 77 4.495 4.495 0.000 57 7453 1.00 0.9556 a
50 sec-Butyl Alcohol 45 4.576 4.569 0.007 99 111546 24.0 25.6
52 Chlorobromomethane 128 4.662 4.662 0.000 74 3247 1.00 0.9506
53 Tetrahydrofuran 42 4.678 4.672 0.006 87 19312 2.00 2.13
54 Chloroform 83 4.723 4.723 0.000 92 10423 1.00 1.03
55 1,1,1-Trichloroethane 97 4.875 4.875 0.000 96 7481 1.00 0.9580 M
56 Cyclohexane 56 4.936 4.939 -0.003 88 10194 1.00 1.07 M
57 1,1-Dichloropropene 75 4.987 4.987 0.000 93 8939 1.00 1.08
59 Carbon tetrachloride 117 5.003 4.997 0.006 47 3197 1.00 1.13 M
58 Isobutyl alcohol 41 5.000 4.997 0.003 95 43876 25.0 26.8
60 Benzene 78 5.141 5.145 -0.004 95 25285 1.00 1.05
61 1,2-Dichloroethane 62 5.167 5.167 0.000 88 9412 1.00 1.10 a
63 n-Heptane 43 5.334 5.331 0.003 90 12739 1.00 1.49
65 Trichloroethene 95 5.637 5.640 -0.003 95 7572 1.00 1.20
66 2-Pentanone 43 5.743 5.743 0.000 99 73186 3.20 3.52
67 Methylcyclohexane 55 5.849 5.846 0.003 84 8505 1.00 1.07
69 1,2-Dichloropropane 63 5.852 5.849 0.003 89 6611 1.00 1.04
70 1,4-Dioxane 88 5.897 5.900 -0.003 87 9697 20.0 20.5 M
71 Dibromomethane 93 5.920 5.926 -0.006 92 3882 1.00 0.9081
72 Dichlorobromomethane 83 6.042 6.045 -0.003 94 4854 1.00 1.28 M
74 2-Chloroethyl vinyl ether 63 6.244 6.244 0.000 90 3679 1.00 1.02
75 cis-1,3-Dichloropropene 75 6.392 6.405 -0.013 96 8308 1.00 0.9089 M
76 4-Methyl-2-pentanone (MIBK) 43 6.505 6.502 0.003 96 68849 4.00 3.94
77 Toluene 91 6.698 6.698 0.000 99 28156 1.00 1.02
78 trans-1,3-Dichloropropene 75 6.865 6.871 -0.006 51 7621 1.00 1.35 Ma
79 Ethyl methacrylate 69 6.887 6.887 0.000 87 11962 1.00 1.00
80 1,1,2-Trichloroethane 97 7.042 7.048 -0.006 88 6394 1.00 0.9593 M
82 Tetrachloroethene 164 7.145 7.148 -0.003 82 4798 1.00 1.07
83 1,3-Dichloropropane 76 7.196 7.196 0.000 88 11173 1.00 0.99
84 2-Hexanone 43 7.212 7.215 -0.003 95 63374 4.00 4.22
85 Chlorodibromomethane 129 7.389 7.395 -0.006 72 3647 1.00 1.36
86 Ethylene Dibromide 107 7.518 7.518 0.000 98 6689 1.00 0.9645
87 1-Chlorohexane 91 7.910 7.907 0.003 86 9387 0.8000 0.7594
88 Chlorobenzene 112 7.952 7.955 -0.003 90 19108 1.00 1.08
89 1,1,1,2-Tetrachloroethane 131 8.026 8.026 0.000 41 3744 1.00 1.03
90 Ethylbenzene 106 8.026 8.029 -0.003 99 9207 1.00 0.9809
91 m-Xylene & p-Xylene 106 8.151 8.148 0.003 99 12812 1.00 1.11 M
92 o-Xylene 106 8.518 8.514 0.004 93 12270 1.00 1.03
93 Styrene 104 8.527 8.530 -0.003 94 20247 1.00 1.02
94 Bromoform 173 8.717 ND ND
95 Isopropylbenzene 105 8.855 8.858 -0.003 96 28940 1.00 1.02
97 Cyclohexanone 55 8.961 8.961 0.000 92 52944 30.0 35.1
98 1,1,2,2-Tetrachloroethane 83 9.141 9.141 0.000 94 10870 1.00 0.9806
99 trans-1,4-Dichloro-2-butene 53 9.180 9.177 0.003 46 3101 1.00 1.23
100 Bromobenzene 156 9.180 9.186 -0.006 93 8486 1.00 1.07
101 1,2,3-Trichloropropane 110 9.212 9.206 0.006 70 3720 1.00 0.8519
102 N-Propylbenzene 120 9.264 9.264 0.000 99 9274 1.00 1.09
103 2-Chlorotoluene 126 9.360 9.363 -0.003 95 8058 1.00 1.08
104 1,3,5-Trimethylbenzene 105 9.431 9.434 -0.003 95 28098 1.00 1.05
105 4-Chlorotoluene 126 9.482 9.479 0.003 98 8449 1.00 1.06
11/15/2024
3:53:55 PM
Page 288 of 777
Report Date: 29-Oct-2024 20:24:54 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003779.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
107 tert-Butylbenzene 119 9.749 9.749 0.000 93 24690 1.00 1.06
108 1,2,4-Trimethylbenzene 105 9.807 9.807 0.000 98 29818 1.00 1.04
109 sec-Butylbenzene 134 9.971 9.968 0.003 93 7621 1.00 1.09
110 1,3-Dichlorobenzene 146 10.096 10.100 -0.004 80 17925 1.00 1.12
111 4-Isopropyltoluene 119 10.116 10.116 0.000 95 31609 1.00 1.04
112 1,4-Dichlorobenzene 146 10.206 10.199 0.007 87 18276 1.00 0.9445
114 n-Butylbenzene 91 10.527 10.524 0.003 98 33049 1.00 1.14
115 1,2-Dichlorobenzene 146 10.559 10.563 -0.004 96 16682 1.00 1.10
116 1,2-Dibromo-3-Chloropropane 157 11.341 11.347 -0.006 78 3018 1.00 1.49 M
118 1,2,4-Trichlorobenzene 180 12.180 12.183 -0.003 92 14767 1.00 0.9564
119 Hexachlorobutadiene 225 12.328 12.328 0.000 94 5321 1.00 1.15 M
120 Naphthalene 128 12.456 12.456 0.000 97 47137 1.00 1.08
121 1,2,3-Trichlorobenzene 180 12.681 12.681 0.000 94 14206 1.00 0.9805
136 Butadiene 54 0.000 ND ND
S 154 1,3-Dichloropropene, Total 1 0 2.00 2.26
S 156 Total BTEX 1 0 5.20
S 151 1,2-Dichloroethene, Total 1 0 2.00 2.08
S 152 Trihalomethanes, Total 1 0 4.00 3.67
S 155 Xylenes, Total 106 0 2.00 2.14
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Review Flags
M - Manually Integrated
a - User Assigned ID
Reagents:
Cal Dil Std_00424 Amount Added: 10.00 Units: uL
mv-IS_SS_00089 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 289 of 777
Report Date: 29-Oct-2024 20:24:54 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003779.D
Injection Date:29-Oct-2024 19:22:16 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:ic Worklist Smp#:43
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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11/15/2024
3:53:55 PM
Page 290 of 777
Report Date: 29-Oct-2024 20:24:54 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003779.D
Injection Date:29-Oct-2024 19:22:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
33 3-Chloro-1-propene, CAS: 107-05-1
Signal: 1
Processing Integration Results
RT: 3.39
Area: 15761
Amount: 1.136990
Amount Units: ug/l
3.0 3.2 3.4 3.6 3.8
Min
0
1
2
3
4
5
6
7
8
9
10
11
Y ( X10
0
0
)
0000003779[MS Quad Chro]:m/z 41

3
.
3
86
Manual Integration Results
RT: 3.41
Area: 15127
Amount: 1.669827
Amount Units: ug/l
3.0 3.2 3.4 3.6 3.8
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
Y ( X10
0
0
)
0000003779[MS Quad Chro]:m/z 41

3
.
4
1
2
Reviewer: LP8K, 29-Oct-2024 19:58:43 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Wrong peak
11/15/2024
3:53:55 PM
Page 291 of 777
Report Date: 29-Oct-2024 20:24:54 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003779.D
Injection Date:29-Oct-2024 19:22:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
34 Methylene Chloride, CAS: 75-09-2
Signal: 1
Processing Integration Results
RT: 3.52
Area: 5948
Amount: 0.847597
Amount Units: ug/l
3.2 3.4 3.6 3.8
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
52
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 84

3
.
5
2
1
Manual Integration Results
RT: 3.52
Area: 9086
Amount: 1.222696
Amount Units: ug/l
3.2 3.4 3.6 3.8
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
48
52
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 84

3
.
5
2
1
Reviewer: LP8K, 29-Oct-2024 19:59:21 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 292 of 777
Report Date: 29-Oct-2024 20:24:54 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003779.D
Injection Date:29-Oct-2024 19:22:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
42 1,1-Dichloroethane, CAS: 75-34-3
Signal: 1
Processing Integration Results
RT: 4.06
Area: 7642
Amount: 0.793350
Amount Units: ug/l
3.7 3.9 4.1 4.3
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
52
56
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 63

4
.
0
6
1
Manual Integration Results
RT: 4.06
Area: 10057
Amount: 1.005015
Amount Units: ug/l
3.7 3.9 4.1 4.3
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
48
52
56
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 63

4
.
0
6
1
Reviewer: LP8K, 29-Oct-2024 19:59:27 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 293 of 777
Report Date: 29-Oct-2024 20:24:54 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003779.D
Injection Date:29-Oct-2024 19:22:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
48 2,2-Dichloropropane, CAS: 594-20-7
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 4.50
4.2 4.4 4.6 4.8
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 77
Manual Integration Results
RT: 4.50
Area: 7453
Amount: 0.955582
Amount Units: ug/l
4.2 4.4 4.6 4.8
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 77

4
.
4
9
5
Reviewer: LP8K, 29-Oct-2024 19:59:32 -06:00:00 (UTC)
Audit Action: Assigned Compound ID Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 294 of 777
Report Date: 29-Oct-2024 20:24:54 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003779.D
Injection Date:29-Oct-2024 19:22:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
55 1,1,1-Trichloroethane, CAS: 71-55-6
Signal: 1
Processing Integration Results
RT: 4.87
Area: 5942
Amount: 0.812138
Amount Units: ug/l
4.5 4.7 4.9 5.1
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
45
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 97

4
.
875
Manual Integration Results
RT: 4.87
Area: 7481
Amount: 0.957958
Amount Units: ug/l
4.5 4.7 4.9 5.1
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 97

4
.
875
Reviewer: LP8K, 29-Oct-2024 19:59:38 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 295 of 777
Report Date: 29-Oct-2024 20:24:54 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003779.D
Injection Date:29-Oct-2024 19:22:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
56 Cyclohexane, CAS: 110-82-7
Signal: 1
Processing Integration Results
RT: 4.94
Area: 5563
Amount: 0.777309
Amount Units: ug/l
4.6 4.8 5.0 5.2
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
52
56
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 56

4
.
9
3
6
Manual Integration Results
RT: 4.94
Area: 10194
Amount: 1.069795
Amount Units: ug/l
4.6 4.8 5.0 5.2
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
48
52
56
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 56

4
.
9
3
6
Reviewer: LP8K, 29-Oct-2024 19:59:41 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 296 of 777
Report Date: 29-Oct-2024 20:24:54 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003779.D
Injection Date:29-Oct-2024 19:22:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
59 Carbon tetrachloride, CAS: 56-23-5
Signal: 1
Processing Integration Results
RT: 4.99
Area: 2155
Amount: 1.224904
Amount Units: ug/l
4.7 4.9 5.1 5.3
Min
0
2
4
6
8
10
12
14
16
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 117

4
.
9
9
4
Manual Integration Results
RT: 5.00
Area: 3197
Amount: 1.134710
Amount Units: ug/l
4.7 4.9 5.1 5.3
Min
RT
0
2
4
6
8
10
12
14
16
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 117

5
.
0
0
3
Reviewer: LP8K, 29-Oct-2024 19:59:45 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 297 of 777
Report Date: 29-Oct-2024 20:24:54 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003779.D
Injection Date:29-Oct-2024 19:22:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
61 1,2-Dichloroethane, CAS: 107-06-2
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 5.17
4.8 5.0 5.2 5.4
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
Y ( X10
0
0
)
0000003779[MS Quad Chro]:m/z 62
Manual Integration Results
RT: 5.17
Area: 9412
Amount: 1.095653
Amount Units: ug/l
4.8 5.0 5.2 5.4
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
12
13
Y ( X10
0
0
)
0000003779[MS Quad Chro]:m/z 62

5
.
1
6
7
Reviewer: LP8K, 29-Oct-2024 19:59:50 -06:00:00 (UTC)
Audit Action: Assigned Compound ID Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 298 of 777
Report Date: 29-Oct-2024 20:24:54 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003779.D
Injection Date:29-Oct-2024 19:22:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
70 1,4-Dioxane, CAS: 123-91-1
Signal: 1
Processing Integration Results
RT: 5.90
Area: 6875
Amount: 19.729613
Amount Units: ug/l
5.6 5.8 6.0 6.2
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 88

5
.
897
Manual Integration Results
RT: 5.90
Area: 9697
Amount: 20.460115
Amount Units: ug/l
5.6 5.8 6.0 6.2
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 88

5
.
897
Reviewer: LP8K, 29-Oct-2024 19:59:57 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 299 of 777
Report Date: 29-Oct-2024 20:24:54 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003779.D
Injection Date:29-Oct-2024 19:22:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
72 Dichlorobromomethane, CAS: 75-27-4
Signal: 1
Processing Integration Results
RT: 6.04
Area: 3486
Amount: 1.026566
Amount Units: ug/l
5.7 5.9 6.1 6.3
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
52
56
60
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 83

6
.
0
4
2
Manual Integration Results
RT: 6.04
Area: 4854
Amount: 1.275214
Amount Units: ug/l
5.7 5.9 6.1 6.3
Min
RT
0
5
10
15
20
25
30
35
40
45
50
55
60
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 83

6
.
0
4
2
Reviewer: LP8K, 29-Oct-2024 20:00:00 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 300 of 777
Report Date: 29-Oct-2024 20:24:54 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003779.D
Injection Date:29-Oct-2024 19:22:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
75 cis-1,3-Dichloropropene, CAS: 10061-01-5
Signal: 1
Processing Integration Results
RT: 6.40
Area: 5720
Amount: 0.993712
Amount Units: ug/l
6.1 6.3 6.5 6.7
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 75

6
.
4
0
2
Manual Integration Results
RT: 6.39
Area: 8308
Amount: 0.908907
Amount Units: ug/l
6.1 6.3 6.5 6.7
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
48
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 75

6
.
3
9
2
Reviewer: LP8K, 29-Oct-2024 20:00:04 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 301 of 777
Report Date: 29-Oct-2024 20:24:54 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003779.D
Injection Date:29-Oct-2024 19:22:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
78 trans-1,3-Dichloropropene, CAS: 10061-02-6
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 6.87
6.5 6.7 6.9 7.1
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
45
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 75
Manual Integration Results
RT: 6.86
Area: 7621
Amount: 1.353869
Amount Units: ug/l
6.5 6.7 6.9 7.1
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 75

6
.
865
Reviewer: LP8K, 29-Oct-2024 20:00:10 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 302 of 777
Report Date: 29-Oct-2024 20:24:55 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003779.D
Injection Date:29-Oct-2024 19:22:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
80 1,1,2-Trichloroethane, CAS: 79-00-5
Signal: 1
Processing Integration Results
RT: 7.05
Area: 3006
Amount: 0.937514
Amount Units: ug/l
6.7 6.9 7.1 7.3
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 97

7
.
0
5
1
Manual Integration Results
RT: 7.04
Area: 6394
Amount: 0.959298
Amount Units: ug/l
6.7 6.9 7.1 7.3
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 97

7
.
0
4
2
Reviewer: LP8K, 29-Oct-2024 20:00:14 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 303 of 777
Report Date: 29-Oct-2024 20:24:55 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003779.D
Injection Date:29-Oct-2024 19:22:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
91 m-Xylene & p-Xylene, CAS: 179601-23-1
Signal: 1
Processing Integration Results
RT: 8.14
Area: 6834
Amount: 0.646077
Amount Units: ug/l
7.8 8.0 8.2 8.4
Min
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 106

8.1
4
5
Manual Integration Results
RT: 8.15
Area: 12812
Amount: 1.110124
Amount Units: ug/l
7.8 8.0 8.2 8.4
Min
RT
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 106

8.1
5
1
Reviewer: LP8K, 29-Oct-2024 20:00:23 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 304 of 777
Report Date: 29-Oct-2024 20:24:55 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003779.D
Injection Date:29-Oct-2024 19:22:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
116 1,2-Dibromo-3-Chloropropane, CAS: 96-12-8
Signal: 1
Processing Integration Results
RT: 11.34
Area: 1441
Amount: 1.231858
Amount Units: ug/l
11.0 11.2 11.4 11.6
Min
0
2
4
6
8
10
12
14
16
18
20
22
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 157
1
1
.
3
4
1
Manual Integration Results
RT: 11.34
Area: 3018
Amount: 1.491145
Amount Units: ug/l
11.0 11.2 11.4 11.6
Min
RT
0
2
4
6
8
10
12
14
16
18
20
22
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 157
1
1
.
3
4
1
Reviewer: LP8K, 29-Oct-2024 20:00:36 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 305 of 777
Report Date: 29-Oct-2024 20:24:55 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003779.D
Injection Date:29-Oct-2024 19:22:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
119 Hexachlorobutadiene, CAS: 87-68-3
Signal: 1
Processing Integration Results
RT: 12.32
Area: 3091
Amount: 0.715548
Amount Units: ug/l
12.0 12.2 12.4 12.6
Min
0
3
6
9
12
15
18
21
24
27
30
33
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 225
1
2
.
3
2
1
Manual Integration Results
RT: 12.33
Area: 5321
Amount: 1.146292
Amount Units: ug/l
12.0 12.2 12.4 12.6
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
Y ( X10
0
)
0000003779[MS Quad Chro]:m/z 225
1
2
.
3
2
8
Reviewer: LP8K, 29-Oct-2024 20:00:39 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 306 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:1
Inject. Date:29-Oct-2024 19:42:16 ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ic 0.5
Operator ID:bustillose Instrument ID:VMS_MS14
Sublist:chrom-AQ_VMS14_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:29-Oct-2024 20:24:57 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:29-Oct-2024 20:06:41
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 99 1506210 50.0 50.0
* 2 Chlorobenzene-d5 119 7.929 7.929 0.000 86 392145 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.174 10.177 -0.003 96 728130 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.843 4.842 0.001 93 347976 50.0 47.7
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.113 5.112 0.001 98 462657 50.0 50.7
$ 6 Toluene-d8 (Surr) 98 6.637 6.637 0.000 93 1590373 50.0 51.5
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.035 -0.003 86 669748 50.0 48.1
10 Dichlorodifluoromethane 85 1.791 ND ND
12 Chloromethane 50 1.974 1.971 0.003 98 5859 0.5000 0.5232
13 Vinyl chloride 62 2.081 2.087 -0.006 94 4237 0.5000 0.4963
15 Bromomethane 94 2.392 2.399 -0.007 74 3704 0.5000 0.6648
16 Chloroethane 64 2.495 ND ND
17 Dichlorofluoromethane 67 2.672 2.675 -0.003 95 7508 0.5000 0.5600 M
18 Trichlorofluoromethane 101 2.708 2.717 -0.009 95 4465 0.5000 0.4874
21 Ethyl ether 59 2.942 2.942 0.000 80 2876 0.5000 0.4973 M
22 Acrolein 56 3.052 3.055 -0.003 97 14247 4.94 4.86 M
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.138 3.138 0.000 71 1739 0.5000 0.4677 M
25 1,1-Dichloroethene 96 3.142 3.145 -0.003 71 2674 0.5000 0.6567
26 Acetone 43 3.164 3.158 0.006 100 80891 2.00 1.89
29 Iodomethane 142 3.270 ND ND
30 Carbon disulfide 76 3.335 3.334 0.001 99 9072 0.5000 0.5569
32 Methyl acetate 43 3.392 3.395 -0.003 95 20183 1.00 1.26
33 3-Chloro-1-propene 41 3.405 3.424 -0.019 81 12038 0.5000 1.28 M
34 Methylene Chloride 84 3.518 3.521 -0.003 92 6165 0.5000 0.8014 M
35 2-Methyl-2-propanol 59 3.579 3.566 0.013 98 32795 5.00 5.07
36 Acrylonitrile 53 3.688 3.688 0.000 99 45221 5.00 5.31
37 Methyl tert-butyl ether 73 3.714 3.717 -0.003 80 10526 0.5000 0.4920
38 trans-1,2-Dichloroethene 96 3.727 3.730 -0.003 60 3454 0.5000 0.5951 M
39 Hexane 57 3.926 3.932 -0.006 90 5151 0.5000 0.6329 M
40 Vinyl acetate 43 4.029 4.029 0.000 97 15677 1.00 1.06
42 1,1-Dichloroethane 63 4.058 4.058 0.000 94 5032 0.5000 0.4857
11/15/2024
3:53:55 PM
Page 307 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
45 2-Butanone (MEK) 43 4.457 4.453 0.004 100 69128 2.00 1.90
47 cis-1,2-Dichloroethene 96 4.476 4.482 -0.006 71 3636 0.5000 0.5383 M
48 2,2-Dichloropropane 77 4.495 ND ND
50 sec-Butyl Alcohol 45 4.579 4.569 0.010 98 55656 12.0 12.3
52 Chlorobromomethane 128 4.653 4.662 -0.009 80 1951 0.5000 0.5517 M
53 Tetrahydrofuran 42 4.679 4.672 0.007 86 10859 1.00 1.15
54 Chloroform 83 4.720 4.723 -0.003 91 5815 0.5000 0.5574 M
55 1,1,1-Trichloroethane 97 4.871 4.875 -0.004 76 4703 0.5000 0.5817 M
56 Cyclohexane 56 4.933 4.939 -0.006 86 5851 0.5000 0.5931
57 1,1-Dichloropropene 75 4.987 4.987 0.000 58 4981 0.5000 0.5801 M
59 Carbon tetrachloride 117 4.997 ND ND
58 Isobutyl alcohol 41 5.000 4.997 0.003 74 8525 12.5 5.04
60 Benzene 78 5.142 5.145 -0.003 42 14105 0.5000 0.5669
61 1,2-Dichloroethane 62 5.167 ND ND
63 n-Heptane 43 5.331 5.331 0.000 32 5184 0.5000 0.5875
65 Trichloroethene 95 5.634 5.640 -0.006 22 1413 0.5000 0.2143
66 2-Pentanone 43 5.743 5.743 0.000 99 40304 1.60 1.87
67 Methylcyclohexane 55 5.846 5.846 0.000 85 5184 0.5000 0.6310 M
69 1,2-Dichloropropane 63 5.852 5.849 0.003 77 3304 0.5000 0.5001
70 1,4-Dioxane 88 5.900 ND ND
71 Dibromomethane 93 5.923 5.926 -0.003 92 2164 0.5000 0.4890 M
72 Dichlorobromomethane 83 6.045 6.045 0.000 9 3069 0.5000 1.03
74 2-Chloroethyl vinyl ether 63 6.248 6.244 0.004 85 1891 0.5000 0.6664 M
75 cis-1,3-Dichloropropene 75 6.402 6.405 -0.003 91 4323 0.5000 0.4508 M
76 4-Methyl-2-pentanone (MIBK) 43 6.502 6.502 0.000 95 37620 2.00 2.08
77 Toluene 91 6.698 6.698 0.000 98 16366 0.5000 0.5749 Ma
78 trans-1,3-Dichloropropene 75 6.868 6.871 -0.003 91 3542 0.5000 0.9665
79 Ethyl methacrylate 69 6.888 6.887 0.001 84 5968 0.5000 0.4757 M
80 1,1,2-Trichloroethane 97 7.048 ND ND
82 Tetrachloroethene 164 7.148 7.148 0.000 89 2352 0.5000 0.5022
83 1,3-Dichloropropane 76 7.196 7.196 0.000 92 6193 0.5000 0.5231 M
84 2-Hexanone 43 7.219 7.215 0.004 93 33389 2.00 2.12
85 Chlorodibromomethane 129 7.396 7.395 0.001 84 1867 0.5000 1.04 M
86 Ethylene Dibromide 107 7.518 7.518 0.000 90 3818 0.5000 0.5247 M
87 1-Chlorohexane 91 7.913 7.907 0.006 33 7073 0.4000 0.4406 M
88 Chlorobenzene 112 7.958 7.955 0.003 80 10785 0.5000 0.5792
89 1,1,1,2-Tetrachloroethane 131 8.026 ND ND
90 Ethylbenzene 106 8.029 8.029 0.000 99 6017 0.5000 0.6111
91 m-Xylene & p-Xylene 106 8.148 ND ND
92 o-Xylene 106 8.511 8.514 -0.003 96 7014 0.5000 0.5634
93 Styrene 104 8.531 8.530 0.001 94 12005 0.5000 0.5745
94 Bromoform 173 8.717 ND ND
95 Isopropylbenzene 105 8.865 8.858 0.007 95 15769 0.5000 0.5128 M
97 Cyclohexanone 55 8.961 8.961 0.000 92 26095 15.0 16.5
98 1,1,2,2-Tetrachloroethane 83 9.141 9.141 0.000 92 5168 0.5000 0.4321
99 trans-1,4-Dichloro-2-butene 53 9.180 9.177 0.003 44 1654 0.5000 0.8836
100 Bromobenzene 156 9.186 9.186 0.000 84 4995 0.5000 0.5811
101 1,2,3-Trichloropropane 110 9.215 9.206 0.009 78 2441 0.5000 0.5182
102 N-Propylbenzene 120 9.260 9.264 -0.004 98 5500 0.5000 0.5991
103 2-Chlorotoluene 126 9.363 9.363 0.000 96 4984 0.5000 0.6213
104 1,3,5-Trimethylbenzene 105 9.434 9.434 0.000 94 16298 0.5000 0.5635 M
105 4-Chlorotoluene 126 9.476 9.479 -0.003 98 5025 0.5000 0.5868
11/15/2024
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Page 308 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
107 tert-Butylbenzene 119 9.752 9.749 0.003 92 13844 0.5000 0.5523
108 1,2,4-Trimethylbenzene 105 9.810 9.807 0.003 96 17980 0.5000 0.5822
109 sec-Butylbenzene 134 9.971 9.968 0.003 95 4154 0.5000 0.5496
110 1,3-Dichlorobenzene 146 10.103 10.100 0.003 74 10264 0.5000 0.5943
111 4-Isopropyltoluene 119 10.116 10.116 0.000 97 19242 0.5000 0.5856
112 1,4-Dichlorobenzene 146 10.196 10.199 -0.003 74 11587 0.5000 0.4480
114 n-Butylbenzene 91 10.521 10.524 -0.003 94 19552 0.5000 0.6242
115 1,2-Dichlorobenzene 146 10.563 10.563 0.000 96 10124 0.5000 0.6167
116 1,2-Dibromo-3-Chloropropane 157 11.341 11.347 -0.006 83 1524 0.5000 1.16 M
118 1,2,4-Trichlorobenzene 180 12.183 12.183 0.000 92 7919 0.5000 0.2698
119 Hexachlorobutadiene 225 12.331 12.328 0.003 90 3241 0.5000 0.6472 M
120 Naphthalene 128 12.450 12.456 -0.006 98 25439 0.5000 0.5417
121 1,2,3-Trichlorobenzene 180 12.685 12.681 0.004 93 7944 0.5000 0.3310 M
136 Butadiene 54 0.000 ND ND
S 154 1,3-Dichloropropene, Total 1 0 1.00 1.42
S 156 Total BTEX 1 0 2.32
S 151 1,2-Dichloroethene, Total 1 0 1.00 1.13
S 152 Trihalomethanes, Total 1 0 2.00 2.63
S 155 Xylenes, Total 106 0 1.00 0.5634
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Review Flags
M - Manually Integrated
a - User Assigned ID
Reagents:
Cal Dil Std_00424 Amount Added: 5.00 Units: uL
mv-IS_SS_00089 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 309 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:ic Worklist Smp#:44
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0
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23
24
25
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Y ( X10
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0000003780[MS Quad Chro]:Total

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11/15/2024
3:53:55 PM
Page 310 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
17 Dichlorofluoromethane, CAS: 75-43-4
Signal: 1
Processing Integration Results
RT: 2.67
Area: 3742
Amount: 0.455496
Amount Units: ug/l
2.3 2.4 2.5 2.6 2.7 2.8 2.9 3.0
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 67

2
.
6
7
2
Manual Integration Results
RT: 2.67
Area: 7508
Amount: 0.560044
Amount Units: ug/l
2.3 2.4 2.5 2.6 2.7 2.8 2.9 3.0
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 67

2
.
6
7
2
Reviewer: LP8K, 29-Oct-2024 20:03:07 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 311 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
21 Ethyl ether, CAS: 60-29-7
Signal: 1
Processing Integration Results
RT: 2.94
Area: 1997
Amount: 0.360574
Amount Units: ug/l
2.6 2.8 3.0 3.2
Min
0
2
4
6
8
10
12
14
16
18
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 59

2
.
9
4
2
Manual Integration Results
RT: 2.94
Area: 2876
Amount: 0.497265
Amount Units: ug/l
2.6 2.8 3.0 3.2
Min
RT
0
2
4
6
8
10
12
14
16
18
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 59

2
.
9
4
2
Reviewer: LP8K, 29-Oct-2024 20:03:10 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 312 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
22 Acrolein, CAS: 107-02-8
Signal: 1
Processing Integration Results
RT: 3.05
Area: 8445
Amount: 4.852062
Amount Units: ug/l
2.7 2.9 3.1 3.3
Min
0
6
12
18
24
30
36
42
48
54
60
66
72
78
84
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 56

3
.
0
5
2
Manual Integration Results
RT: 3.05
Area: 14247
Amount: 4.855823
Amount Units: ug/l
2.7 2.9 3.1 3.3
Min
RT
0
6
12
18
24
30
36
42
48
54
60
66
72
78
84
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 56

3
.
0
5
2
Reviewer: LP8K, 29-Oct-2024 20:03:13 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 313 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
24 1,1,2-Trichloro-1,2,2-trifluoroe, CAS: 76-13-1
Signal: 1
Processing Integration Results
RT: 3.14
Area: 1024
Amount: 0.366727
Amount Units: ug/l
2.8 3.0 3.2 3.4
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 151

3
.
1
3
8
Manual Integration Results
RT: 3.14
Area: 1739
Amount: 0.467744
Amount Units: ug/l
2.8 3.0 3.2 3.4
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
12
13
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 151

3
.
1
3
8
Reviewer: LP8K, 29-Oct-2024 20:03:15 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 314 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
33 3-Chloro-1-propene, CAS: 107-05-1
Signal: 1
Processing Integration Results
RT: 3.39
Area: 5735
Amount: 0.248441
Amount Units: ug/l
3.1 3.3 3.5 3.7
Min
0
7
14
21
28
35
42
49
56
63
70
77
84
91
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 41

3
.
3
8
9
Manual Integration Results
RT: 3.41
Area: 12038
Amount: 1.283586
Amount Units: ug/l
3.1 3.3 3.5 3.7
Min
RT
0
7
14
21
28
35
42
49
56
63
70
77
84
91
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 41

3
.
4
0
5
Reviewer: LP8K, 29-Oct-2024 20:03:40 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Wrong peak
11/15/2024
3:53:55 PM
Page 315 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
34 Methylene Chloride, CAS: 75-09-2
Signal: 1
Processing Integration Results
RT: 3.52
Area: 4630
Amount: 0.584569
Amount Units: ug/l
3.2 3.4 3.6 3.8
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 84

3
.
5
1
8
Manual Integration Results
RT: 3.52
Area: 6165
Amount: 0.801366
Amount Units: ug/l
3.2 3.4 3.6 3.8
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 84

3
.
5
1
8
Reviewer: LP8K, 29-Oct-2024 20:03:53 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 316 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
38 trans-1,2-Dichloroethene, CAS: 156-60-5
Signal: 1
Processing Integration Results
RT: 3.73
Area: 1801
Amount: 0.296979
Amount Units: ug/l
3.4 3.6 3.8 4.0
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 96

3
.
7
2
7
Manual Integration Results
RT: 3.73
Area: 3454
Amount: 0.595077
Amount Units: ug/l
3.4 3.6 3.8 4.0
Min
RT
0
3
6
9
12
15
18
21
24
27
30
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 96

3
.
7
2
7
Reviewer: LP8K, 29-Oct-2024 20:04:18 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 317 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
39 Hexane, CAS: 110-54-3
Signal: 1
Processing Integration Results
RT: 3.93
Area: 2674
Amount: 0.353885
Amount Units: ug/l
3.6 3.8 4.0 4.2
Min
0
3
6
9
12
15
18
21
24
27
30
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 57

3
.
9
2
6
Manual Integration Results
RT: 3.93
Area: 5151
Amount: 0.632853
Amount Units: ug/l
3.6 3.8 4.0 4.2
Min
RT
0
3
6
9
12
15
18
21
24
27
30
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 57

3
.
9
2
6
Reviewer: LP8K, 29-Oct-2024 20:04:21 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 318 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
47 cis-1,2-Dichloroethene, CAS: 156-59-2
Signal: 1
Processing Integration Results
RT: 4.49
Area: 2223
Amount: 0.348122
Amount Units: ug/l
4.1 4.3 4.5 4.7
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 96

4
.
4
8
6
Manual Integration Results
RT: 4.48
Area: 3636
Amount: 0.538266
Amount Units: ug/l
4.1 4.3 4.5 4.7
Min
RT
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 96

4
.
4
7
6
Reviewer: LP8K, 29-Oct-2024 20:04:26 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 319 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
52 Chlorobromomethane, CAS: 74-97-5
Signal: 1
Processing Integration Results
RT: 4.66
Area: 1207
Amount: 0.361522
Amount Units: ug/l
4.3 4.5 4.7 4.9
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 128

4
.
6
6
2
Manual Integration Results
RT: 4.65
Area: 1951
Amount: 0.551750
Amount Units: ug/l
4.3 4.5 4.7 4.9
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
12
13
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 128

4
.
6
5
3
Reviewer: LP8K, 29-Oct-2024 20:04:31 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 320 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
54 Chloroform, CAS: 67-66-3
Signal: 1
Processing Integration Results
RT: 4.72
Area: 1880
Amount: 0.199740
Amount Units: ug/l
4.4 4.6 4.8 5.0
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 83

4
.
7
2
0
Manual Integration Results
RT: 4.72
Area: 5815
Amount: 0.557359
Amount Units: ug/l
4.4 4.6 4.8 5.0
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 83

4
.
7
2
0
Reviewer: LP8K, 29-Oct-2024 20:04:44 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 321 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
55 1,1,1-Trichloroethane, CAS: 71-55-6
Signal: 1
Processing Integration Results
RT: 4.87
Area: 3584
Amount: 0.464081
Amount Units: ug/l
4.5 4.7 4.9 5.1
Min
0
3
6
9
12
15
18
21
24
27
30
33
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 97

4
.
8
7
1
Manual Integration Results
RT: 4.87
Area: 4703
Amount: 0.581720
Amount Units: ug/l
4.5 4.7 4.9 5.1
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 97

4
.
8
7
1
Reviewer: LP8K, 29-Oct-2024 20:04:47 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 322 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
57 1,1-Dichloropropene, CAS: 563-58-6
Signal: 1
Processing Integration Results
RT: 4.99
Area: 2168
Amount: 0.295473
Amount Units: ug/l
4.7 4.9 5.1 5.3
Min
0
3
6
9
12
15
18
21
24
27
30
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 75

4
.
9
8
7
Manual Integration Results
RT: 4.99
Area: 4981
Amount: 0.580113
Amount Units: ug/l
4.7 4.9 5.1 5.3
Min
RT
0
3
6
9
12
15
18
21
24
27
30
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 75

4
.
9
8
7
Reviewer: LP8K, 29-Oct-2024 20:04:50 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 323 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
67 Methylcyclohexane, CAS: 108-87-2
Signal: 1
Processing Integration Results
RT: 5.85
Area: 3322
Amount: 0.429329
Amount Units: ug/l
5.5 5.7 5.9 6.1
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 55

5
.
8
4
6
Manual Integration Results
RT: 5.85
Area: 5184
Amount: 0.631012
Amount Units: ug/l
5.5 5.7 5.9 6.1
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 55

5
.
8
4
6
Reviewer: LP8K, 29-Oct-2024 20:05:17 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 324 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
71 Dibromomethane, CAS: 74-95-3
Signal: 1
Processing Integration Results
RT: 5.92
Area: 1125
Amount: 0.466217
Amount Units: ug/l
5.6 5.8 6.0 6.2
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 93

5
.
9
1
6
Manual Integration Results
RT: 5.92
Area: 2164
Amount: 0.488975
Amount Units: ug/l
5.6 5.8 6.0 6.2
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 93

5
.
9
2
3
Reviewer: LP8K, 29-Oct-2024 20:05:22 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 325 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
74 2-Chloroethyl vinyl ether, CAS: 110-75-8
Signal: 1
Processing Integration Results
RT: 6.25
Area: 1224
Amount: 0.507816
Amount Units: ug/l
5.9 6.1 6.3 6.5
Min
0
2
4
6
8
10
12
14
16
18
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 63

6
.
2
4
8
Manual Integration Results
RT: 6.25
Area: 1891
Amount: 0.666368
Amount Units: ug/l
5.9 6.1 6.3 6.5
Min
RT
0
2
4
6
8
10
12
14
16
18
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 63

6
.
2
4
8
Reviewer: LP8K, 29-Oct-2024 20:05:27 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 326 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
75 cis-1,3-Dichloropropene, CAS: 10061-01-5
Signal: 1
Processing Integration Results
RT: 6.40
Area: 3043
Amount: 0.496263
Amount Units: ug/l
6.1 6.3 6.5 6.7
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 75

6
.
4
0
2
Manual Integration Results
RT: 6.40
Area: 4323
Amount: 0.450813
Amount Units: ug/l
6.1 6.3 6.5 6.7
Min
RT
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 75

6
.
4
0
2
Reviewer: LP8K, 29-Oct-2024 20:05:30 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 327 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
77 Toluene, CAS: 108-88-3
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 6.70
6.4 6.6 6.8 7.0
Min
0
7
14
21
28
35
42
49
56
63
70
77
84
91
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 91
Manual Integration Results
RT: 6.70
Area: 16366
Amount: 0.574861
Amount Units: ug/l
6.4 6.6 6.8 7.0
Min
RT
0
7
14
21
28
35
42
49
56
63
70
77
84
91
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 91

6
.
6
9
8
Reviewer: LP8K, 29-Oct-2024 20:05:39 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 328 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
79 Ethyl methacrylate, CAS: 97-63-2
Signal: 1
Processing Integration Results
RT: 6.89
Area: 3861
Amount: 0.322493
Amount Units: ug/l
6.6 6.8 7.0 7.2
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
45
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 69

6
.
8
8
8
Manual Integration Results
RT: 6.89
Area: 5968
Amount: 0.475706
Amount Units: ug/l
6.6 6.8 7.0 7.2
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 69

6
.
8
8
8
Reviewer: LP8K, 29-Oct-2024 20:05:46 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 329 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
83 1,3-Dichloropropane, CAS: 142-28-9
Signal: 1
Processing Integration Results
RT: 7.20
Area: 5275
Amount: 0.454015
Amount Units: ug/l
6.9 7.1 7.3 7.5
Min
0
3
6
9
12
15
18
21
24
27
30
33
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 76

7
.
1
9
6
Manual Integration Results
RT: 7.20
Area: 6193
Amount: 0.523104
Amount Units: ug/l
6.9 7.1 7.3 7.5
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 76

7
.
1
9
6
Reviewer: LP8K, 29-Oct-2024 20:05:53 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 330 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
85 Chlorodibromomethane, CAS: 124-48-1
Signal: 1
Processing Integration Results
RT: 7.40
Area: 1542
Amount: 0.729252
Amount Units: ug/l
7.1 7.3 7.5 7.7
Min
0
2
4
6
8
10
12
14
16
18
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 129

7
.
3
9
6
Manual Integration Results
RT: 7.40
Area: 1867
Amount: 1.044194
Amount Units: ug/l
7.1 7.3 7.5 7.7
Min
RT
0
2
4
6
8
10
12
14
16
18
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 129

7
.
3
9
6
Reviewer: LP8K, 29-Oct-2024 20:05:57 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 331 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
86 Ethylene Dibromide, CAS: 106-93-4
Signal: 1
Processing Integration Results
RT: 7.52
Area: 2737
Amount: 0.391752
Amount Units: ug/l
7.2 7.4 7.6 7.8
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 107

7
.
5
1
8
Manual Integration Results
RT: 7.52
Area: 3818
Amount: 0.524740
Amount Units: ug/l
7.2 7.4 7.6 7.8
Min
RT
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 107

7
.
5
1
8
Reviewer: LP8K, 29-Oct-2024 20:06:00 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 332 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
87 1-Chlorohexane, CAS: 544-10-5
Signal: 1
Processing Integration Results
RT: 7.91
Area: 1474
Amount: 0.053489
Amount Units: ug/l
7.6 7.8 8.0 8.2
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
Y ( X10
0
0
)
0000003780[MS Quad Chro]:m/z 91

7
.
9
1
3
Manual Integration Results
RT: 7.91
Area: 7073
Amount: 0.440596
Amount Units: ug/l
7.6 7.8 8.0 8.2
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
12
Y ( X10
0
0
)
0000003780[MS Quad Chro]:m/z 91

7
.
9
1
3
Reviewer: LP8K, 29-Oct-2024 20:06:02 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 333 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
95 Isopropylbenzene, CAS: 98-82-8
Signal: 1
Processing Integration Results
RT: 8.86
Area: 9021
Amount: 0.452206
Amount Units: ug/l
8.5 8.7 8.9 9.1
Min
0
6
12
18
24
30
36
42
48
54
60
66
72
78
84
90
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 105

8
.
8
5
5
Manual Integration Results
RT: 8.86
Area: 15769
Amount: 0.512756
Amount Units: ug/l
8.5 8.7 8.9 9.1
Min
RT
0
7
14
21
28
35
42
49
56
63
70
77
84
91
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 105

8
.
8
6
5
Reviewer: LP8K, 29-Oct-2024 20:06:13 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 334 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
104 1,3,5-Trimethylbenzene, CAS: 108-67-8
Signal: 1
Processing Integration Results
RT: 9.43
Area: 10880
Amount: 0.393356
Amount Units: ug/l
9.1 9.3 9.5 9.7
Min
0
1
2
3
4
5
6
7
8
9
10
11
Y ( X10
0
0
)
0000003780[MS Quad Chro]:m/z 105

9
.
4
3
4
Manual Integration Results
RT: 9.43
Area: 16298
Amount: 0.563479
Amount Units: ug/l
9.1 9.3 9.5 9.7
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
Y ( X10
0
0
)
0000003780[MS Quad Chro]:m/z 105

9
.
4
3
4
Reviewer: LP8K, 29-Oct-2024 20:06:19 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 335 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
116 1,2-Dibromo-3-Chloropropane, CAS: 96-12-8
Signal: 1
Processing Integration Results
RT: 11.35
Area: 811
Amount: 0.695822
Amount Units: ug/l
11.0 11.2 11.4 11.6
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 157
1
1
.
3
5
0
Manual Integration Results
RT: 11.34
Area: 1524
Amount: 1.159244
Amount Units: ug/l
11.0 11.2 11.4 11.6
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
12
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 157
1
1
.
3
4
1
Reviewer: LP8K, 29-Oct-2024 20:06:26 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 336 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
119 Hexachlorobutadiene, CAS: 87-68-3
Signal: 1
Processing Integration Results
RT: 12.32
Area: 561
Amount: 0.232057
Amount Units: ug/l
12.0 12.2 12.4 12.6
Min
0
2
4
6
8
10
12
14
16
18
20
22
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 225
1
2
.
3
2
5
Manual Integration Results
RT: 12.33
Area: 3241
Amount: 0.647189
Amount Units: ug/l
12.0 12.2 12.4 12.6
Min
RT
0
2
4
6
8
10
12
14
16
18
20
22
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 225
1
2
.
3
3
1
Reviewer: LP8K, 29-Oct-2024 20:06:29 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 337 of 777
Report Date: 29-Oct-2024 20:24:58 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Injection Date:29-Oct-2024 19:42:16 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
121 1,2,3-Trichlorobenzene, CAS: 87-61-6
Signal: 1
Processing Integration Results
RT: 12.68
Area: 4158
Amount: 0.215833
Amount Units: ug/l
12.3 12.5 12.7 12.9
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 180
1
2
.
6
7
8
Manual Integration Results
RT: 12.68
Area: 7944
Amount: 0.330994
Amount Units: ug/l
12.3 12.5 12.7 12.9
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
48
Y ( X10
0
)
0000003780[MS Quad Chro]:m/z 180
1
2
.
6
8
5
Reviewer: LP8K, 29-Oct-2024 20:06:32 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
11/15/2024
3:53:55 PM
Page 338 of 777
Calibration / Dichlorodifluoromethane
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.1617
Slope:0.2901
Error Coefficients
Relative Standard Deviation:6.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.0 50.0 1506210.0 0.0 N
2 IC 280-672942/43 1.0 0.138565 50.0 1454915.0 0.138565 Y
3 IC 280-672942/42 2.0 0.398851 50.0 1475488.0 0.199426 Y
4 IC 280-672942/41 5.0 1.17038 50.0 1464951.0 0.234076 Y
5 IC 280-672942/40 10.0 2.62302 50.0 1493641.0 0.262302 Y
6 ICIS 280-672942/39 50.0 15.495515 50.0 1366376.0 0.30991 Y
7 IC 280-672942/38 75.0 23.216193 50.0 1422085.0 0.309549 Y
8 IC 280-672942/37 100.0 28.649323 50.0 1420599.0 0.286493 Y
9 IC 280-672942/36 200.0 56.355689 50.0 1413702.0 0.281778 Y
RelResp = [-0.1617] + [0.2901]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
Intercept = 0.557
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3:53:55 PM
Page 339 of 777
Calibration / Chloromethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3717
Error Coefficients
Relative Standard Deviation:5.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.194495 50.0 1506210.0 0.38899 Y
2 IC 280-672942/43 1.0 0.357306 50.0 1454915.0 0.357306 Y
3 IC 280-672942/42 2.0 0.717085 50.0 1475488.0 0.358542 Y
4 IC 280-672942/41 5.0 1.856581 50.0 1464951.0 0.371316 Y
5 IC 280-672942/40 10.0 3.348395 50.0 1493641.0 0.334839 Y
6 ICIS 280-672942/39 50.0 19.403371 50.0 1366376.0 0.388067 Y
7 IC 280-672942/38 75.0 29.476649 50.0 1422085.0 0.393022 Y
8 IC 280-672942/37 100.0 37.742002 50.0 1420599.0 0.37742 Y
9 IC 280-672942/36 200.0 75.235658 50.0 1413702.0 0.376178 Y
RelResp = [0.3717]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/36
11/15/2024
3:53:55 PM
Page 340 of 777
Calibration / Vinyl chloride
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2834
Error Coefficients
Relative Standard Deviation:4.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.140651 50.0 1506210.0 0.281302 Y
2 IC 280-672942/43 1.0 0.277645 50.0 1454915.0 0.277645 Y
3 IC 280-672942/42 2.0 0.570862 50.0 1475488.0 0.285431 Y
4 IC 280-672942/41 5.0 1.430901 50.0 1464951.0 0.28618 Y
5 IC 280-672942/40 10.0 2.653315 50.0 1493641.0 0.265331 Y
6 ICIS 280-672942/39 50.0 14.953388 50.0 1366376.0 0.299068 Y
7 IC 280-672942/38 75.0 22.622136 50.0 1422085.0 0.301628 Y
8 IC 280-672942/37 100.0 27.833541 50.0 1420599.0 0.278335 Y
9 IC 280-672942/36 200.0 55.181219 50.0 1413702.0 0.275906 Y
RelResp = [0.2834]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
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Page 341 of 777
Calibration / Bromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1849
Error Coefficients
Relative Standard Deviation:5.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.122958 50.0 1506210.0 0.245915 N
2 IC 280-672942/43 1.0 0.201421 50.0 1454915.0 0.201421 Y
3 IC 280-672942/42 2.0 0.384788 50.0 1475488.0 0.192394 Y
4 IC 280-672942/41 5.0 0.871975 50.0 1464951.0 0.174395 Y
5 IC 280-672942/40 10.0 1.727256 50.0 1493641.0 0.172726 Y
6 ICIS 280-672942/39 50.0 9.528819 50.0 1366376.0 0.190576 Y
7 IC 280-672942/38 75.0 14.187443 50.0 1422085.0 0.189166 Y
8 IC 280-672942/37 100.0 18.40266 50.0 1420599.0 0.184027 Y
9 IC 280-672942/36 200.0 34.970347 50.0 1413702.0 0.174852 Y
RelResp = [0.1849]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
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Page 342 of 777
Calibration / Chloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1768
Error Coefficients
Relative Standard Deviation:3.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.0 50.0 1506210.0 0.0 N
2 IC 280-672942/43 1.0 0.176058 50.0 1454915.0 0.176058 Y
3 IC 280-672942/42 2.0 0.34209 50.0 1475488.0 0.171045 Y
4 IC 280-672942/41 5.0 0.84996 50.0 1464951.0 0.169992 Y
5 IC 280-672942/40 10.0 1.700107 50.0 1493641.0 0.170011 Y
6 ICIS 280-672942/39 50.0 9.308529 50.0 1366376.0 0.186171 Y
7 IC 280-672942/38 75.0 14.063681 50.0 1422085.0 0.187516 Y
8 IC 280-672942/37 100.0 17.761346 50.0 1420599.0 0.177613 Y
9 IC 280-672942/36 200.0 35.201973 50.0 1413702.0 0.17601 Y
RelResp = [0.1768]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
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Page 343 of 777
Calibration / Dichlorofluoromethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.445
Error Coefficients
Relative Standard Deviation:5.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.249235 50.0 1506210.0 0.49847 Y
2 IC 280-672942/43 1.0 0.442431 50.0 1454915.0 0.442431 Y
3 IC 280-672942/42 2.0 0.867747 50.0 1475488.0 0.433873 Y
4 IC 280-672942/41 5.0 2.146795 50.0 1464951.0 0.429359 Y
5 IC 280-672942/40 10.0 4.201813 50.0 1493641.0 0.420181 Y
6 ICIS 280-672942/39 50.0 22.92462 50.0 1366376.0 0.458492 Y
7 IC 280-672942/38 75.0 34.169687 50.0 1422085.0 0.455596 Y
8 IC 280-672942/37 100.0 43.739824 50.0 1420599.0 0.437398 Y
9 IC 280-672942/36 200.0 85.888221 50.0 1413702.0 0.429441 Y
RelResp = [0.445]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
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Page 344 of 777
Calibration / Trichlorofluoromethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3041
Error Coefficients
Relative Standard Deviation:8.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.14822 50.0 1506210.0 0.296439 Y
2 IC 280-672942/43 1.0 0.289605 50.0 1454915.0 0.289605 Y
3 IC 280-672942/42 2.0 0.561306 50.0 1475488.0 0.280653 Y
4 IC 280-672942/41 5.0 1.409877 50.0 1464951.0 0.281975 Y
5 IC 280-672942/40 10.0 2.825913 50.0 1493641.0 0.282591 Y
6 ICIS 280-672942/39 50.0 17.037733 50.0 1366376.0 0.340755 Y
7 IC 280-672942/38 75.0 25.625789 50.0 1422085.0 0.341677 Y
8 IC 280-672942/37 100.0 32.426955 50.0 1420599.0 0.32427 Y
9 IC 280-672942/36 200.0 59.756476 50.0 1413702.0 0.298782 Y
RelResp = [0.3041]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
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Calibration / Ethyl ether
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.192
Error Coefficients
Relative Standard Deviation:5.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.095471 50.0 1506210.0 0.190943 Y
2 IC 280-672942/43 1.0 0.189496 50.0 1454915.0 0.189496 Y
3 IC 280-672942/42 2.0 0.371233 50.0 1475488.0 0.185617 Y
4 IC 280-672942/41 5.0 0.901259 50.0 1464951.0 0.180252 Y
5 IC 280-672942/40 10.0 1.787143 50.0 1493641.0 0.178714 Y
6 ICIS 280-672942/39 50.0 10.350994 50.0 1366376.0 0.20702 Y
7 IC 280-672942/38 75.0 14.907231 50.0 1422085.0 0.198763 Y
8 IC 280-672942/37 100.0 19.069386 50.0 1420599.0 0.190694 Y
9 IC 280-672942/36 200.0 41.287662 50.0 1413702.0 0.206438 Y
RelResp = [0.192]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
IC 280-672942/36
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Calibration / Acrolein
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.0974
Error Coefficients
Relative Standard Deviation:8.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 4.9375 0.472942 50.0 1506210.0 0.095786 Y
2 IC 280-672942/43 9.875 0.867714 50.0 1454915.0 0.08787 Y
3 IC 280-672942/42 19.75 1.727157 50.0 1475488.0 0.087451 Y
4 IC 280-672942/41 49.375 4.51667 50.0 1464951.0 0.091477 Y
5 IC 280-672942/40 98.75 8.930024 50.0 1493641.0 0.090431 Y
6 ICIS 280-672942/39 493.75 52.943846 50.0 1366376.0 0.107228 Y
7 IC 280-672942/38 740.625 76.907534 50.0 1422085.0 0.103841 Y
8 IC 280-672942/37 987.5 101.170281 50.0 1420599.0 0.102451 Y
9 IC 280-672942/36 1975.0 217.324231 50.0 1413702.0 0.110038 Y
RelResp = [0.0974]x
Concentration
0 1000 2000
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/36
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Page 347 of 777
Calibration / 1,1,2-Trichloro-1,2,2-trifluoroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1234
Error Coefficients
Relative Standard Deviation:10.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.057728 50.0 1506210.0 0.115455 N
2 IC 280-672942/43 1.0 0.121932 50.0 1454915.0 0.121932 Y
3 IC 280-672942/42 2.0 0.253916 50.0 1475488.0 0.126958 Y
4 IC 280-672942/41 5.0 0.60473 50.0 1464951.0 0.120946 Y
5 IC 280-672942/40 10.0 1.05206 50.0 1493641.0 0.105206 Y
6 ICIS 280-672942/39 50.0 7.265862 50.0 1366376.0 0.145317 Y
7 IC 280-672942/38 75.0 10.21813 50.0 1422085.0 0.136242 Y
8 IC 280-672942/37 100.0 11.479524 50.0 1420599.0 0.114795 Y
9 IC 280-672942/36 200.0 23.188621 50.0 1413702.0 0.115943 Y
RelResp = [0.1234]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
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Page 348 of 777
Calibration / 1,1-Dichloroethene
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.031
Slope:0.1824
Error Coefficients
Relative Standard Deviation:11.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.088766 50.0 1506210.0 0.177532 N
2 IC 280-672942/43 1.0 0.179048 50.0 1454915.0 0.179048 Y
3 IC 280-672942/42 2.0 0.327349 50.0 1475488.0 0.163675 Y
4 IC 280-672942/41 5.0 0.825011 50.0 1464951.0 0.165002 Y
5 IC 280-672942/40 10.0 1.469932 50.0 1493641.0 0.146993 Y
6 ICIS 280-672942/39 50.0 10.020631 50.0 1366376.0 0.200413 Y
7 IC 280-672942/38 75.0 14.639526 50.0 1422085.0 0.195194 Y
8 IC 280-672942/37 100.0 17.188242 50.0 1420599.0 0.171882 Y
9 IC 280-672942/36 200.0 35.892041 50.0 1413702.0 0.17946 Y
RelResp = [-0.031] + [0.1824]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
Intercept = 0.170
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Page 349 of 777
Calibration / Acetone
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:2.094
Slope:0.3127
Error Coefficients
Relative Standard Deviation:8.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 2.0 2.68525 50.0 1506210.0 1.342625 Y
2 IC 280-672942/43 4.0 3.540654 50.0 1454915.0 0.885163 Y
3 IC 280-672942/42 8.0 4.384719 50.0 1475488.0 0.54809 Y
4 IC 280-672942/41 20.0 8.40796 50.0 1464951.0 0.420398 Y
5 IC 280-672942/40 40.0 13.550277 50.0 1493641.0 0.338757 Y
6 ICIS 280-672942/39 200.0 67.96215 50.0 1366376.0 0.339811 Y
7 IC 280-672942/38 300.0 96.787112 50.0 1422085.0 0.322624 Y
8 IC 280-672942/37 400.0 124.019903 50.0 1420599.0 0.31005 Y
9 IC 280-672942/36 800.0 256.988248 50.0 1413702.0 0.321235 Y
RelResp = [2.094] + [0.3127]x
Concentration
0 100 200 300 400 500 600 700 800
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
IC 280-672942/36
Intercept = -6.70
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Page 350 of 777
Calibration / Iodomethane
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.3895
Slope:0.2229
Error Coefficients
Relative Standard Deviation:5.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.0 50.0 1506210.0 0.0 N
2 IC 280-672942/43 1.0 0.173825 50.0 1454915.0 0.173825 N
3 IC 280-672942/42 2.0 0.345377 50.0 1475488.0 0.172689 N
4 IC 280-672942/41 5.0 0.766101 50.0 1464951.0 0.15322 Y
5 IC 280-672942/40 10.0 1.65592 50.0 1493641.0 0.165592 Y
6 ICIS 280-672942/39 50.0 11.238854 50.0 1366376.0 0.224777 Y
7 IC 280-672942/38 75.0 16.613247 50.0 1422085.0 0.22151 Y
8 IC 280-672942/37 100.0 21.218585 50.0 1420599.0 0.212186 Y
9 IC 280-672942/36 200.0 44.894681 50.0 1413702.0 0.224473 Y
RelResp = [-0.3895] + [0.2229]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
IC 280-672942/36
Intercept = 1.75
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Page 351 of 777
Calibration / Carbon disulfide
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5408
Error Coefficients
Relative Standard Deviation:10.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.301153 50.0 1506210.0 0.602306 N
2 IC 280-672942/43 1.0 0.474461 50.0 1454915.0 0.474461 N
3 IC 280-672942/42 2.0 1.031591 50.0 1475488.0 0.515795 Y
4 IC 280-672942/41 5.0 2.39124 50.0 1464951.0 0.478248 Y
5 IC 280-672942/40 10.0 4.744681 50.0 1493641.0 0.474468 Y
6 ICIS 280-672942/39 50.0 31.046103 50.0 1366376.0 0.620922 Y
7 IC 280-672942/38 75.0 45.426856 50.0 1422085.0 0.605691 Y
8 IC 280-672942/37 100.0 53.64554 50.0 1420599.0 0.536455 Y
9 IC 280-672942/36 200.0 110.78194 50.0 1413702.0 0.55391 Y
RelResp = [0.5408]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
IC 280-672942/36
11/15/2024
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Page 352 of 777
Calibration / Methyl acetate
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5311
Error Coefficients
Relative Standard Deviation:11.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 1.0 0.669993 50.0 1506210.0 0.669993 Y
2 IC 280-672942/43 2.0 1.164673 50.0 1454915.0 0.582336 Y
3 IC 280-672942/42 4.0 2.025296 50.0 1475488.0 0.506324 Y
4 IC 280-672942/41 10.0 4.880914 50.0 1464951.0 0.488091 Y
5 IC 280-672942/40 20.0 9.283924 50.0 1493641.0 0.464196 Y
6 ICIS 280-672942/39 100.0 53.89922 50.0 1366376.0 0.538992 Y
7 IC 280-672942/38 150.0 76.199172 50.0 1422085.0 0.507994 Y
8 IC 280-672942/37 200.0 99.373081 50.0 1420599.0 0.496865 Y
9 IC 280-672942/36 400.0 210.190938 50.0 1413702.0 0.525477 Y
RelResp = [0.5311]x
Concentration
0 100 200 300 400
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
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Page 353 of 777
Calibration / 3-Chloro-1-propene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3113
Error Coefficients
Relative Standard Deviation:10.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.399612 50.0 1506210.0 0.799225 N
2 IC 280-672942/43 1.0 0.519859 50.0 1454915.0 0.519859 N
3 IC 280-672942/42 2.0 0.690619 50.0 1475488.0 0.345309 Y
4 IC 280-672942/41 5.0 1.703914 50.0 1464951.0 0.340783 Y
5 IC 280-672942/40 10.0 2.732417 50.0 1493641.0 0.273242 Y
6 ICIS 280-672942/39 50.0 16.828494 50.0 1366376.0 0.33657 Y
7 IC 280-672942/38 75.0 23.888235 50.0 1422085.0 0.31851 Y
8 IC 280-672942/37 100.0 28.471933 50.0 1420599.0 0.284719 Y
9 IC 280-672942/36 200.0 56.028215 50.0 1413702.0 0.280141 Y
RelResp = [0.3113]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
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Page 354 of 777
Calibration / Methylene Chloride
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2554
Error Coefficients
Relative Standard Deviation:10.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.204653 50.0 1506210.0 0.409305 N
2 IC 280-672942/43 1.0 0.312252 50.0 1454915.0 0.312252 Y
3 IC 280-672942/42 2.0 0.51932 50.0 1475488.0 0.25966 Y
4 IC 280-672942/41 5.0 1.281442 50.0 1464951.0 0.256288 Y
5 IC 280-672942/40 10.0 2.419055 50.0 1493641.0 0.241906 Y
6 ICIS 280-672942/39 50.0 12.963489 50.0 1366376.0 0.25927 Y
7 IC 280-672942/38 75.0 18.528358 50.0 1422085.0 0.247045 Y
8 IC 280-672942/37 100.0 22.766629 50.0 1420599.0 0.227666 Y
9 IC 280-672942/36 200.0 47.790482 50.0 1413702.0 0.238952 Y
RelResp = [0.2554]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
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Page 355 of 777
Calibration / 2-Methyl-2-propanol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2147
Error Coefficients
Relative Standard Deviation:4.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 5.0 1.08866 50.0 1506210.0 0.217732 Y
2 IC 280-672942/43 10.0 2.323091 50.0 1454915.0 0.232309 Y
3 IC 280-672942/42 20.0 4.148627 50.0 1475488.0 0.207431 Y
4 IC 280-672942/41 50.0 10.863367 50.0 1464951.0 0.217267 Y
5 IC 280-672942/40 100.0 20.098136 50.0 1493641.0 0.200981 Y
6 ICIS 280-672942/39 500.0 109.645515 50.0 1366376.0 0.219291 Y
7 IC 280-672942/38 750.0 158.880658 50.0 1422085.0 0.211841 Y
8 IC 280-672942/37 1000.0 209.230191 50.0 1420599.0 0.20923 Y
9 IC 280-672942/36 2000.0 432.608923 50.0 1413702.0 0.216304 Y
RelResp = [0.2147]x
Concentration
0 1000 2000
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
IC 280-672942/36
11/15/2024
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Page 356 of 777
Calibration / Acrylonitrile
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2827
Error Coefficients
Relative Standard Deviation:4.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 5.0 1.501152 50.0 1506210.0 0.30023 Y
2 IC 280-672942/43 10.0 2.783427 50.0 1454915.0 0.278343 Y
3 IC 280-672942/42 20.0 5.594624 50.0 1475488.0 0.279731 Y
4 IC 280-672942/41 50.0 14.019786 50.0 1464951.0 0.280396 Y
5 IC 280-672942/40 100.0 27.672814 50.0 1493641.0 0.276728 Y
6 ICIS 280-672942/39 500.0 150.80644 50.0 1366376.0 0.301613 Y
7 IC 280-672942/38 750.0 213.918577 50.0 1422085.0 0.285225 Y
8 IC 280-672942/37 1000.0 274.000087 50.0 1420599.0 0.274 Y
9 IC 280-672942/36 2000.0 536.279322 50.0 1413702.0 0.26814 Y
RelResp = [0.2827]x
Concentration
0 1000 2000
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 357 of 777
Calibration / Methyl tert-butyl ether
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7102
Error Coefficients
Relative Standard Deviation:3.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.34942 50.0 1506210.0 0.69884 N
2 IC 280-672942/43 1.0 0.715884 50.0 1454915.0 0.715884 Y
3 IC 280-672942/42 2.0 1.443827 50.0 1475488.0 0.721914 Y
4 IC 280-672942/41 5.0 3.418749 50.0 1464951.0 0.68375 Y
5 IC 280-672942/40 10.0 6.978283 50.0 1493641.0 0.697828 Y
6 ICIS 280-672942/39 50.0 38.162263 50.0 1366376.0 0.763245 Y
7 IC 280-672942/38 75.0 54.592623 50.0 1422085.0 0.727902 Y
8 IC 280-672942/37 100.0 68.448697 50.0 1420599.0 0.684487 Y
9 IC 280-672942/36 200.0 137.276845 50.0 1413702.0 0.686384 Y
RelResp = [0.7102]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
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Page 358 of 777
Calibration / trans-1,2-Dichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1927
Error Coefficients
Relative Standard Deviation:9.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.114659 50.0 1506210.0 0.229317 Y
2 IC 280-672942/43 1.0 0.197159 50.0 1454915.0 0.197159 Y
3 IC 280-672942/42 2.0 0.406205 50.0 1475488.0 0.203102 Y
4 IC 280-672942/41 5.0 0.93556 50.0 1464951.0 0.187112 Y
5 IC 280-672942/40 10.0 1.803814 50.0 1493641.0 0.180381 Y
6 ICIS 280-672942/39 50.0 10.178823 50.0 1366376.0 0.203576 Y
7 IC 280-672942/38 75.0 14.41809 50.0 1422085.0 0.192241 Y
8 IC 280-672942/37 100.0 17.160015 50.0 1420599.0 0.1716 Y
9 IC 280-672942/36 200.0 33.923486 50.0 1413702.0 0.169617 Y
RelResp = [0.1927]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
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Page 359 of 777
Calibration / Hexane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.038
Error Coefficients
Relative Standard Deviation:14.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.656772 50.0 392145.0 1.313545 Y
2 IC 280-672942/43 1.0 1.139927 50.0 373796.0 1.139927 Y
3 IC 280-672942/42 2.0 2.237355 50.0 382237.0 1.118678 Y
4 IC 280-672942/41 5.0 5.006556 50.0 379043.0 1.001311 Y
5 IC 280-672942/40 10.0 9.422523 50.0 379686.0 0.942252 Y
6 ICIS 280-672942/39 50.0 55.631095 50.0 383025.0 1.112622 Y
7 IC 280-672942/38 75.0 75.078041 50.0 411645.0 1.001041 Y
8 IC 280-672942/37 100.0 88.228734 50.0 401244.0 0.882287 Y
9 IC 280-672942/36 200.0 165.70125 50.0 430902.0 0.828506 Y
RelResp = [1.038]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 360 of 777
Calibration / Vinyl acetate
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.08702
Slope:0.5739
Error Coefficients
Relative Standard Deviation:7.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 1.0 0.520412 50.0 1506210.0 0.520412 Y
2 IC 280-672942/43 2.0 0.985109 50.0 1454915.0 0.492555 Y
3 IC 280-672942/42 4.0 2.059556 50.0 1475488.0 0.514889 Y
4 IC 280-672942/41 10.0 5.335571 50.0 1464951.0 0.533557 Y
5 IC 280-672942/40 20.0 10.189363 50.0 1493641.0 0.509468 Y
6 ICIS 280-672942/39 100.0 62.288565 50.0 1366376.0 0.622886 Y
7 IC 280-672942/38 150.0 91.415422 50.0 1422085.0 0.609436 Y
8 IC 280-672942/37 200.0 116.926522 50.0 1420599.0 0.584633 Y
9 IC 280-672942/36 400.0 243.956081 50.0 1413702.0 0.60989 Y
RelResp = [-0.08702] + [0.5739]x
Concentration
0 100 200 300 400
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/36
Intercept = 0.152
11/15/2024
3:53:55 PM
Page 361 of 777
Calibration / 1,1-Dichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3439
Error Coefficients
Relative Standard Deviation:4.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.167042 50.0 1506210.0 0.334084 Y
2 IC 280-672942/43 1.0 0.345622 50.0 1454915.0 0.345622 Y
3 IC 280-672942/42 2.0 0.687095 50.0 1475488.0 0.343547 Y
4 IC 280-672942/41 5.0 1.709579 50.0 1464951.0 0.341916 Y
5 IC 280-672942/40 10.0 3.337114 50.0 1493641.0 0.333711 Y
6 ICIS 280-672942/39 50.0 18.728739 50.0 1366376.0 0.374575 Y
7 IC 280-672942/38 75.0 27.055872 50.0 1422085.0 0.360745 Y
8 IC 280-672942/37 100.0 32.398587 50.0 1420599.0 0.323986 Y
9 IC 280-672942/36 200.0 67.377106 50.0 1413702.0 0.336886 Y
RelResp = [0.3439]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 362 of 777
Calibration / 2-Butanone (MEK)
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:1.341
Slope:0.5009
Error Coefficients
Relative Standard Deviation:6.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 2.0 2.294766 50.0 1506210.0 1.147383 Y
2 IC 280-672942/43 4.0 3.53378 50.0 1454915.0 0.883445 Y
3 IC 280-672942/42 8.0 5.379746 50.0 1475488.0 0.672468 Y
4 IC 280-672942/41 20.0 11.764011 50.0 1464951.0 0.588201 Y
5 IC 280-672942/40 40.0 19.096389 50.0 1493641.0 0.47741 Y
6 ICIS 280-672942/39 200.0 107.287306 50.0 1366376.0 0.536437 Y
7 IC 280-672942/38 300.0 153.348007 50.0 1422085.0 0.51116 Y
8 IC 280-672942/37 400.0 195.362379 50.0 1420599.0 0.488406 Y
9 IC 280-672942/36 800.0 394.801663 50.0 1413702.0 0.493502 Y
RelResp = [1.341] + [0.5009]x
Concentration
0 100 200 300 400 500 600 700 800
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
Intercept = -2.68
11/15/2024
3:53:55 PM
Page 363 of 777
Calibration / cis-1,2-Dichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2242
Error Coefficients
Relative Standard Deviation:5.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.1207 50.0 1506210.0 0.241401 Y
2 IC 280-672942/43 1.0 0.236337 50.0 1454915.0 0.236337 Y
3 IC 280-672942/42 2.0 0.446903 50.0 1475488.0 0.223451 Y
4 IC 280-672942/41 5.0 1.087886 50.0 1464951.0 0.217577 Y
5 IC 280-672942/40 10.0 2.126113 50.0 1493641.0 0.212611 Y
6 ICIS 280-672942/39 50.0 11.792764 50.0 1366376.0 0.235855 Y
7 IC 280-672942/38 75.0 17.138357 50.0 1422085.0 0.228511 Y
8 IC 280-672942/37 100.0 20.749979 50.0 1420599.0 0.2075 Y
9 IC 280-672942/36 200.0 42.981937 50.0 1413702.0 0.21491 Y
RelResp = [0.2242]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 364 of 777
Calibration / 2,2-Dichloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.268
Error Coefficients
Relative Standard Deviation:7.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.0 50.0 1506210.0 0.0 N
2 IC 280-672942/43 1.0 0.256132 50.0 1454915.0 0.256132 Y
3 IC 280-672942/42 2.0 0.531485 50.0 1475488.0 0.265743 Y
4 IC 280-672942/41 5.0 1.26325 50.0 1464951.0 0.25265 Y
5 IC 280-672942/40 10.0 2.432947 50.0 1493641.0 0.243295 Y
6 ICIS 280-672942/39 50.0 15.136829 50.0 1366376.0 0.302737 Y
7 IC 280-672942/38 75.0 22.16049 50.0 1422085.0 0.295473 Y
8 IC 280-672942/37 100.0 26.409634 50.0 1420599.0 0.264096 Y
9 IC 280-672942/36 200.0 52.834827 50.0 1413702.0 0.264174 Y
RelResp = [0.268]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 365 of 777
Calibration / sec-Butyl Alcohol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.15
Error Coefficients
Relative Standard Deviation:3.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 12.0 1.847551 50.0 1506210.0 0.153963 Y
2 IC 280-672942/43 24.0 3.83342 50.0 1454915.0 0.159726 Y
3 IC 280-672942/42 48.0 6.971761 50.0 1475488.0 0.145245 Y
4 IC 280-672942/41 120.0 18.468706 50.0 1464951.0 0.153906 Y
5 IC 280-672942/40 240.0 34.855163 50.0 1493641.0 0.14523 Y
6 ICIS 280-672942/39 1200.0 184.476711 50.0 1366376.0 0.153731 Y
7 IC 280-672942/38 1800.0 265.674696 50.0 1422085.0 0.147597 Y
8 IC 280-672942/37 2400.0 350.401521 50.0 1420599.0 0.146001 Y
9 IC 280-672942/36 4800.0 695.36727 50.0 1413702.0 0.144868 Y
RelResp = [0.15]x
Concentration
0 1000 2000 3000 4000 5000
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 366 of 777
Calibration / Chlorobromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1174
Error Coefficients
Relative Standard Deviation:5.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.064765 50.0 1506210.0 0.12953 Y
2 IC 280-672942/43 1.0 0.111587 50.0 1454915.0 0.111587 Y
3 IC 280-672942/42 2.0 0.248562 50.0 1475488.0 0.124281 Y
4 IC 280-672942/41 5.0 0.569234 50.0 1464951.0 0.113847 Y
5 IC 280-672942/40 10.0 1.117069 50.0 1493641.0 0.111707 Y
6 ICIS 280-672942/39 50.0 6.134805 50.0 1366376.0 0.122696 Y
7 IC 280-672942/38 75.0 9.02984 50.0 1422085.0 0.120398 Y
8 IC 280-672942/37 100.0 11.036612 50.0 1420599.0 0.110366 Y
9 IC 280-672942/36 200.0 22.404156 50.0 1413702.0 0.112021 Y
RelResp = [0.1174]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 367 of 777
Calibration / Tetrahydrofuran
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3122
Error Coefficients
Relative Standard Deviation:7.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 1.0 0.360474 50.0 1506210.0 0.360474 Y
2 IC 280-672942/43 2.0 0.663681 50.0 1454915.0 0.331841 Y
3 IC 280-672942/42 4.0 1.215496 50.0 1475488.0 0.303874 Y
4 IC 280-672942/41 10.0 3.100991 50.0 1464951.0 0.310099 Y
5 IC 280-672942/40 20.0 5.793494 50.0 1493641.0 0.289675 Y
6 ICIS 280-672942/39 100.0 31.820194 50.0 1366376.0 0.318202 Y
7 IC 280-672942/38 150.0 45.58525 50.0 1422085.0 0.303902 Y
8 IC 280-672942/37 200.0 58.315682 50.0 1420599.0 0.291578 Y
9 IC 280-672942/36 400.0 119.920358 50.0 1413702.0 0.299801 Y
RelResp = [0.3122]x
Concentration
0 100 200 300 400
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 368 of 777
Calibration / Chloroform
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3463
Error Coefficients
Relative Standard Deviation:6.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.193034 50.0 1506210.0 0.386068 Y
2 IC 280-672942/43 1.0 0.3582 50.0 1454915.0 0.3582 Y
3 IC 280-672942/42 2.0 0.677267 50.0 1475488.0 0.338634 Y
4 IC 280-672942/41 5.0 1.683435 50.0 1464951.0 0.336687 Y
5 IC 280-672942/40 10.0 3.287236 50.0 1493641.0 0.328724 Y
6 ICIS 280-672942/39 50.0 18.26408 50.0 1366376.0 0.365282 Y
7 IC 280-672942/38 75.0 26.715105 50.0 1422085.0 0.356201 Y
8 IC 280-672942/37 100.0 32.081995 50.0 1420599.0 0.32082 Y
9 IC 280-672942/36 200.0 65.283737 50.0 1413702.0 0.326419 Y
RelResp = [0.3463]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 369 of 777
Calibration / Dibromofluoromethane (Surr)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2424
Error Coefficients
Relative Standard Deviation:3.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/36 50.0 12.50412 50.0 1413702.0 0.250082 Y
2 IC 280-672942/37 50.0 12.3506 50.0 1420599.0 0.247012 Y
3 IC 280-672942/38 50.0 12.565529 50.0 1422085.0 0.251311 Y
4 ICIS 280-672942/39 50.0 12.444708 50.0 1366376.0 0.248894 Y
5 IC 280-672942/40 50.0 12.139128 50.0 1493641.0 0.242783 Y
6 IC 280-672942/41 50.0 12.015794 50.0 1464951.0 0.240316 Y
7 IC 280-672942/42 50.0 11.776036 50.0 1475488.0 0.235521 Y
8 IC 280-672942/43 50.0 11.714361 50.0 1454915.0 0.234287 Y
9 IC 280-672942/44 50.0 11.551377 50.0 1506210.0 0.231028 Y
RelResp = [0.2424]x
Concentration
0 10 20 30 40 50
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/36IC 280-672942/37IC 280-672942/38ICIS 280-672942/39IC 280-672942/40
11/15/2024
3:53:55 PM
Page 370 of 777
Calibration / 1,1,1-Trichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2684
Error Coefficients
Relative Standard Deviation:10.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.15612 50.0 1506210.0 0.312241 Y
2 IC 280-672942/43 1.0 0.257094 50.0 1454915.0 0.257094 Y
3 IC 280-672942/42 2.0 0.520336 50.0 1475488.0 0.260168 Y
4 IC 280-672942/41 5.0 1.205842 50.0 1464951.0 0.241168 Y
5 IC 280-672942/40 10.0 2.367336 50.0 1493641.0 0.236734 Y
6 ICIS 280-672942/39 50.0 15.247121 50.0 1366376.0 0.304942 Y
7 IC 280-672942/38 75.0 21.763467 50.0 1422085.0 0.29018 Y
8 IC 280-672942/37 100.0 25.54162 50.0 1420599.0 0.255416 Y
9 IC 280-672942/36 200.0 51.490166 50.0 1413702.0 0.257451 Y
RelResp = [0.2684]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 371 of 777
Calibration / Cyclohexane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3275
Error Coefficients
Relative Standard Deviation:11.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.194229 50.0 1506210.0 0.388458 Y
2 IC 280-672942/43 1.0 0.35033 50.0 1454915.0 0.35033 Y
3 IC 280-672942/42 2.0 0.637281 50.0 1475488.0 0.31864 Y
4 IC 280-672942/41 5.0 1.550666 50.0 1464951.0 0.310133 Y
5 IC 280-672942/40 10.0 2.713604 50.0 1493641.0 0.27136 Y
6 ICIS 280-672942/39 50.0 18.520012 50.0 1366376.0 0.3704 Y
7 IC 280-672942/38 75.0 26.167142 50.0 1422085.0 0.348895 Y
8 IC 280-672942/37 100.0 29.50428 50.0 1420599.0 0.295043 Y
9 IC 280-672942/36 200.0 58.800794 50.0 1413702.0 0.294004 Y
RelResp = [0.3275]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 372 of 777
Calibration / 1,1-Dichloropropene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.285
Error Coefficients
Relative Standard Deviation:9.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.165349 50.0 1506210.0 0.330698 Y
2 IC 280-672942/43 1.0 0.3072 50.0 1454915.0 0.3072 Y
3 IC 280-672942/42 2.0 0.576894 50.0 1475488.0 0.288447 Y
4 IC 280-672942/41 5.0 1.371309 50.0 1464951.0 0.274262 Y
5 IC 280-672942/40 10.0 2.506124 50.0 1493641.0 0.250612 Y
6 ICIS 280-672942/39 50.0 15.561676 50.0 1366376.0 0.311234 Y
7 IC 280-672942/38 75.0 21.884416 50.0 1422085.0 0.291792 Y
8 IC 280-672942/37 100.0 25.476225 50.0 1420599.0 0.254762 Y
9 IC 280-672942/36 200.0 51.249804 50.0 1413702.0 0.256249 Y
RelResp = [0.285]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
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Page 373 of 777
Calibration / Carbon tetrachloride
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.1225
Slope:0.2048
Error Coefficients
Relative Standard Deviation:12.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.0 50.0 1506210.0 0.0 N
2 IC 280-672942/43 1.0 0.109869 50.0 1454915.0 0.109869 Y
3 IC 280-672942/42 2.0 0.296919 50.0 1475488.0 0.148459 Y
4 IC 280-672942/41 5.0 0.76337 50.0 1464951.0 0.152674 Y
5 IC 280-672942/40 10.0 1.589036 50.0 1493641.0 0.158904 Y
6 ICIS 280-672942/39 50.0 11.378896 50.0 1366376.0 0.227578 Y
7 IC 280-672942/38 75.0 16.662541 50.0 1422085.0 0.222167 Y
8 IC 280-672942/37 100.0 19.509376 50.0 1420599.0 0.195094 Y
9 IC 280-672942/36 200.0 39.434265 50.0 1413702.0 0.197171 Y
RelResp = [-0.1225] + [0.2048]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
Intercept = 0.598
11/15/2024
3:53:55 PM
Page 374 of 777
Calibration / Isobutyl alcohol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.05618
Error Coefficients
Relative Standard Deviation:6.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 12.5 0.282995 50.0 1506210.0 0.02264 N
2 IC 280-672942/43 25.0 1.507854 50.0 1454915.0 0.060314 Y
3 IC 280-672942/42 50.0 2.370978 50.0 1475488.0 0.04742 Y
4 IC 280-672942/41 125.0 7.264543 50.0 1464951.0 0.058116 Y
5 IC 280-672942/40 250.0 13.952784 50.0 1493641.0 0.055811 Y
6 ICIS 280-672942/39 1250.0 73.777569 50.0 1366376.0 0.059022 Y
7 IC 280-672942/38 1875.0 106.057057 50.0 1422085.0 0.056564 Y
8 IC 280-672942/37 2500.0 140.410066 50.0 1420599.0 0.056164 Y
9 IC 280-672942/36 5000.0 280.170114 50.0 1413702.0 0.056034 Y
RelResp = [0.05618]x
Concentration
0 1000 2000 3000 4000 5000
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
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Page 375 of 777
Calibration / 1,2-Dichloroethane-d4 (Surr)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3027
Error Coefficients
Relative Standard Deviation:1.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/36 50.0 15.122812 50.0 1413702.0 0.302456 Y
2 IC 280-672942/37 50.0 14.817623 50.0 1420599.0 0.296352 Y
3 IC 280-672942/38 50.0 14.989786 50.0 1422085.0 0.299796 Y
4 ICIS 280-672942/39 50.0 15.154467 50.0 1366376.0 0.303089 Y
5 IC 280-672942/40 50.0 14.89943 50.0 1493641.0 0.297989 Y
6 IC 280-672942/41 50.0 15.308294 50.0 1464951.0 0.306166 Y
7 IC 280-672942/42 50.0 15.358885 50.0 1475488.0 0.307178 Y
8 IC 280-672942/43 50.0 15.201747 50.0 1454915.0 0.304035 Y
9 IC 280-672942/44 50.0 15.358317 50.0 1506210.0 0.307166 Y
RelResp = [0.3027]x
Concentration
0 10 20 30 40 50
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
ICIS 280-672942/39IC 280-672942/41IC 280-672942/42IC 280-672942/43IC 280-672942/44
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Page 376 of 777
Calibration / Benzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8259
Error Coefficients
Relative Standard Deviation:7.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.468228 50.0 1506210.0 0.936456 Y
2 IC 280-672942/43 1.0 0.868951 50.0 1454915.0 0.868951 Y
3 IC 280-672942/42 2.0 1.689068 50.0 1475488.0 0.844534 Y
4 IC 280-672942/41 5.0 4.000202 50.0 1464951.0 0.80004 Y
5 IC 280-672942/40 10.0 7.733953 50.0 1493641.0 0.773395 Y
6 ICIS 280-672942/39 50.0 43.53926 50.0 1366376.0 0.870785 Y
7 IC 280-672942/38 75.0 62.855666 50.0 1422085.0 0.838076 Y
8 IC 280-672942/37 100.0 74.783736 50.0 1420599.0 0.747837 Y
9 IC 280-672942/36 200.0 150.690987 50.0 1413702.0 0.753455 Y
RelResp = [0.8259]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
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Page 377 of 777
Calibration / 1,2-Dichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2952
Error Coefficients
Relative Standard Deviation:5.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.0 50.0 1506210.0 0.0 N
2 IC 280-672942/43 1.0 0.323455 50.0 1454915.0 0.323455 Y
3 IC 280-672942/42 2.0 0.588551 50.0 1475488.0 0.294276 Y
4 IC 280-672942/41 5.0 1.453632 50.0 1464951.0 0.290726 Y
5 IC 280-672942/40 10.0 2.830265 50.0 1493641.0 0.283027 Y
6 ICIS 280-672942/39 50.0 15.448749 50.0 1366376.0 0.308975 Y
7 IC 280-672942/38 75.0 22.23974 50.0 1422085.0 0.29653 Y
8 IC 280-672942/37 100.0 27.744177 50.0 1420599.0 0.277442 Y
9 IC 280-672942/36 200.0 57.461191 50.0 1413702.0 0.287306 Y
RelResp = [0.2952]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
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Page 378 of 777
Calibration / n-Heptane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2929
Error Coefficients
Relative Standard Deviation:11.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.172088 50.0 1506210.0 0.344175 N
2 IC 280-672942/43 1.0 0.437792 50.0 1454915.0 0.437792 N
3 IC 280-672942/42 2.0 0.697159 50.0 1475488.0 0.34858 Y
4 IC 280-672942/41 5.0 1.531314 50.0 1464951.0 0.306263 Y
5 IC 280-672942/40 10.0 2.511982 50.0 1493641.0 0.251198 Y
6 ICIS 280-672942/39 50.0 15.98601 50.0 1366376.0 0.31972 Y
7 IC 280-672942/38 75.0 22.12642 50.0 1422085.0 0.295019 Y
8 IC 280-672942/37 100.0 26.454123 50.0 1420599.0 0.264541 Y
9 IC 280-672942/36 200.0 53.044701 50.0 1413702.0 0.265224 Y
RelResp = [0.2929]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
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Page 379 of 777
Calibration / Trichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8408
Error Coefficients
Relative Standard Deviation:11.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.180163 50.0 392145.0 0.360326 N
2 IC 280-672942/43 1.0 1.012852 50.0 373796.0 1.012852 Y
3 IC 280-672942/42 2.0 1.798622 50.0 382237.0 0.899311 Y
4 IC 280-672942/41 5.0 4.241471 50.0 379043.0 0.848294 Y
5 IC 280-672942/40 10.0 8.402206 50.0 379686.0 0.840221 Y
6 ICIS 280-672942/39 50.0 42.833758 50.0 383025.0 0.856675 Y
7 IC 280-672942/38 75.0 61.720293 50.0 411645.0 0.822937 Y
8 IC 280-672942/37 100.0 75.067665 50.0 401244.0 0.750677 Y
9 IC 280-672942/36 200.0 139.108428 50.0 430902.0 0.695542 Y
RelResp = [0.8408]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
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Page 380 of 777
Calibration / 2-Pentanone
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7138
Error Coefficients
Relative Standard Deviation:8.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 1.6 1.337928 50.0 1506210.0 0.836205 Y
2 IC 280-672942/43 3.2 2.51513 50.0 1454915.0 0.785978 Y
3 IC 280-672942/42 6.4 4.494106 50.0 1475488.0 0.702204 Y
4 IC 280-672942/41 16.0 11.01559 50.0 1464951.0 0.688474 Y
5 IC 280-672942/40 32.0 20.491135 50.0 1493641.0 0.640348 Y
6 ICIS 280-672942/39 160.0 116.680255 50.0 1366376.0 0.729252 Y
7 IC 280-672942/38 240.0 168.190368 50.0 1422085.0 0.700793 Y
8 IC 280-672942/37 320.0 215.9765 50.0 1420599.0 0.674927 Y
9 IC 280-672942/36 640.0 426.385193 50.0 1413702.0 0.666227 Y
RelResp = [0.7138]x
Concentration
0 100 200 300 400 500 600 700
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
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Page 381 of 777
Calibration / Methylcyclohexane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2727
Error Coefficients
Relative Standard Deviation:13.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.172088 50.0 1506210.0 0.344175 Y
2 IC 280-672942/43 1.0 0.292285 50.0 1454915.0 0.292285 Y
3 IC 280-672942/42 2.0 0.549445 50.0 1475488.0 0.274723 Y
4 IC 280-672942/41 5.0 1.325744 50.0 1464951.0 0.265149 Y
5 IC 280-672942/40 10.0 2.270291 50.0 1493641.0 0.227029 Y
6 ICIS 280-672942/39 50.0 14.923345 50.0 1366376.0 0.298467 Y
7 IC 280-672942/38 75.0 20.697075 50.0 1422085.0 0.275961 Y
8 IC 280-672942/37 100.0 24.018425 50.0 1420599.0 0.240184 Y
9 IC 280-672942/36 200.0 47.295788 50.0 1413702.0 0.236479 Y
RelResp = [0.2727]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
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Page 382 of 777
Calibration / 1,2-Dichloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2193
Error Coefficients
Relative Standard Deviation:4.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.109679 50.0 1506210.0 0.219359 Y
2 IC 280-672942/43 1.0 0.227195 50.0 1454915.0 0.227195 Y
3 IC 280-672942/42 2.0 0.425791 50.0 1475488.0 0.212896 Y
4 IC 280-672942/41 5.0 1.080139 50.0 1464951.0 0.216028 Y
5 IC 280-672942/40 10.0 2.049589 50.0 1493641.0 0.204959 Y
6 ICIS 280-672942/39 50.0 11.703989 50.0 1366376.0 0.23408 Y
7 IC 280-672942/38 75.0 17.207481 50.0 1422085.0 0.229433 Y
8 IC 280-672942/37 100.0 21.133163 50.0 1420599.0 0.211332 Y
9 IC 280-672942/36 200.0 43.728806 50.0 1413702.0 0.218644 Y
RelResp = [0.2193]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
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Page 383 of 777
Calibration / 1,4-Dioxane
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.1014
Slope:0.01133
Error Coefficients
Relative Standard Deviation:8.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 10.0 0.0 50.0 1506210.0 0.0 N
2 IC 280-672942/43 20.0 0.33325 50.0 1454915.0 0.016662 Y
3 IC 280-672942/42 40.0 0.52586 50.0 1475488.0 0.013146 Y
4 IC 280-672942/41 100.0 1.346188 50.0 1464951.0 0.013462 Y
5 IC 280-672942/40 200.0 2.124774 50.0 1493641.0 0.010624 Y
6 ICIS 280-672942/39 1000.0 11.27574 50.0 1366376.0 0.011276 Y
7 IC 280-672942/38 1500.0 17.00468 50.0 1422085.0 0.011336 Y
8 IC 280-672942/37 2000.0 21.486113 50.0 1420599.0 0.010743 Y
9 IC 280-672942/36 4000.0 51.050681 50.0 1413702.0 0.012763 Y
RelResp = [0.1014] + [0.01133]x
Concentration
0 1000 2000 3000 4000
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
IC 280-672942/36
Intercept = -8.95
11/15/2024
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Page 384 of 777
Calibration / Dibromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1469
Error Coefficients
Relative Standard Deviation:6.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.071836 50.0 1506210.0 0.143672 Y
2 IC 280-672942/43 1.0 0.13341 50.0 1454915.0 0.13341 Y
3 IC 280-672942/42 2.0 0.310609 50.0 1475488.0 0.155305 Y
4 IC 280-672942/41 5.0 0.713846 50.0 1464951.0 0.142769 Y
5 IC 280-672942/40 10.0 1.3603 50.0 1493641.0 0.13603 Y
6 ICIS 280-672942/39 50.0 7.972769 50.0 1366376.0 0.159455 Y
7 IC 280-672942/38 75.0 11.489573 50.0 1422085.0 0.153194 Y
8 IC 280-672942/37 100.0 14.54844 50.0 1420599.0 0.145484 Y
9 IC 280-672942/36 200.0 30.576564 50.0 1413702.0 0.152883 Y
RelResp = [0.1469]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
IC 280-672942/36
11/15/2024
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Page 385 of 777
Calibration / Dichlorobromomethane
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.1699
Slope:0.264
Error Coefficients
Relative Standard Deviation:13.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.101878 50.0 1506210.0 0.203756 N
2 IC 280-672942/43 1.0 0.166814 50.0 1454915.0 0.166814 Y
3 IC 280-672942/42 2.0 0.360355 50.0 1475488.0 0.180178 Y
4 IC 280-672942/41 5.0 0.998327 50.0 1464951.0 0.199665 Y
5 IC 280-672942/40 10.0 2.07272 50.0 1493641.0 0.207272 Y
6 ICIS 280-672942/39 50.0 13.021343 50.0 1366376.0 0.260427 Y
7 IC 280-672942/38 75.0 19.846317 50.0 1422085.0 0.264618 Y
8 IC 280-672942/37 100.0 24.72179 50.0 1420599.0 0.247218 Y
9 IC 280-672942/36 200.0 54.423634 50.0 1413702.0 0.272118 Y
RelResp = [-0.1699] + [0.264]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
IC 280-672942/36
Intercept = 0.643
11/15/2024
3:53:55 PM
Page 386 of 777
Calibration / 2-Chloroethyl vinyl ether
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.0564
Slope:0.1788
Error Coefficients
Relative Standard Deviation:6.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.062773 50.0 1506210.0 0.125547 N
2 IC 280-672942/43 1.0 0.126434 50.0 1454915.0 0.126434 Y
3 IC 280-672942/42 2.0 0.300036 50.0 1475488.0 0.150018 Y
4 IC 280-672942/41 5.0 0.791938 50.0 1464951.0 0.158388 Y
5 IC 280-672942/40 10.0 1.522019 50.0 1493641.0 0.152202 Y
6 ICIS 280-672942/39 50.0 9.085347 50.0 1366376.0 0.181707 Y
7 IC 280-672942/38 75.0 13.726289 50.0 1422085.0 0.183017 Y
8 IC 280-672942/37 100.0 18.238856 50.0 1420599.0 0.182389 Y
9 IC 280-672942/36 200.0 38.46914 50.0 1413702.0 0.192346 Y
RelResp = [-0.0564] + [0.1788]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/36
Intercept = 0.315
11/15/2024
3:53:55 PM
Page 387 of 777
Calibration / cis-1,3-Dichloropropene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.223
Error Coefficients
Relative Standard Deviation:9.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.551199 50.0 392145.0 1.102398 Y
2 IC 280-672942/43 1.0 1.111301 50.0 373796.0 1.111301 Y
3 IC 280-672942/42 2.0 2.200598 50.0 382237.0 1.100299 Y
4 IC 280-672942/41 5.0 5.575093 50.0 379043.0 1.115019 Y
5 IC 280-672942/40 10.0 12.335851 50.0 379686.0 1.233585 Y
6 ICIS 280-672942/39 50.0 69.174205 50.0 383025.0 1.383484 Y
7 IC 280-672942/38 75.0 100.641815 50.0 411645.0 1.341891 Y
8 IC 280-672942/37 100.0 130.513603 50.0 401244.0 1.305136 Y
9 IC 280-672942/36 200.0 262.198945 50.0 430902.0 1.310995 Y
RelResp = [1.223]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40 ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/36
11/15/2024
3:53:55 PM
Page 388 of 777
Calibration / 4-Methyl-2-pentanone (MIBK)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5999
Error Coefficients
Relative Standard Deviation:5.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 2.0 1.24883 50.0 1506210.0 0.624415 Y
2 IC 280-672942/43 4.0 2.366083 50.0 1454915.0 0.591521 Y
3 IC 280-672942/42 8.0 4.53189 50.0 1475488.0 0.566486 Y
4 IC 280-672942/41 20.0 11.734795 50.0 1464951.0 0.58674 Y
5 IC 280-672942/40 40.0 22.898006 50.0 1493641.0 0.57245 Y
6 ICIS 280-672942/39 200.0 131.214834 50.0 1366376.0 0.656074 Y
7 IC 280-672942/38 300.0 188.01682 50.0 1422085.0 0.626723 Y
8 IC 280-672942/37 400.0 238.563345 50.0 1420599.0 0.596408 Y
9 IC 280-672942/36 800.0 462.857554 50.0 1413702.0 0.578572 Y
RelResp = [0.5999]x
Concentration
0 100 200 300 400 500 600 700 800
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 389 of 777
Calibration / Toluene-d8 (Surr)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:3.941
Error Coefficients
Relative Standard Deviation:4.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/36 50.0 181.112063 50.0 430902.0 3.622241 Y
2 IC 280-672942/37 50.0 189.993121 50.0 401244.0 3.799862 Y
3 IC 280-672942/38 50.0 189.532243 50.0 411645.0 3.790645 Y
4 ICIS 280-672942/39 50.0 192.742902 50.0 383025.0 3.854858 Y
5 IC 280-672942/40 50.0 206.139942 50.0 379686.0 4.122799 Y
6 IC 280-672942/41 50.0 204.138976 50.0 379043.0 4.08278 Y
7 IC 280-672942/42 50.0 203.324639 50.0 382237.0 4.066493 Y
8 IC 280-672942/43 50.0 203.56839 50.0 373796.0 4.071368 Y
9 IC 280-672942/44 50.0 202.778692 50.0 392145.0 4.055574 Y
RelResp = [3.941]x
Concentration
0 10 20 30 40 50
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/40IC 280-672942/41IC 280-672942/42IC 280-672942/43IC 280-672942/44
11/15/2024
3:53:55 PM
Page 390 of 777
Calibration / Toluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9451
Error Coefficients
Relative Standard Deviation:7.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.543284 50.0 1506210.0 1.086568 Y
2 IC 280-672942/43 1.0 0.967617 50.0 1454915.0 0.967617 Y
3 IC 280-672942/42 2.0 1.931497 50.0 1475488.0 0.965748 Y
4 IC 280-672942/41 5.0 4.56534 50.0 1464951.0 0.913068 Y
5 IC 280-672942/40 10.0 8.670892 50.0 1493641.0 0.867089 Y
6 ICIS 280-672942/39 50.0 49.680139 50.0 1366376.0 0.993603 Y
7 IC 280-672942/38 75.0 71.764803 50.0 1422085.0 0.956864 Y
8 IC 280-672942/37 100.0 87.370504 50.0 1420599.0 0.873705 Y
9 IC 280-672942/36 200.0 176.275481 50.0 1413702.0 0.881377 Y
RelResp = [0.9451]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 391 of 777
Calibration / trans-1,3-Dichloropropene
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.2425
Slope:0.3725
Error Coefficients
Relative Standard Deviation:17.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.11758 50.0 1506210.0 0.23516 N
2 IC 280-672942/43 1.0 0.261905 50.0 1454915.0 0.261905 Y
3 IC 280-672942/42 2.0 0.506646 50.0 1475488.0 0.253323 Y
4 IC 280-672942/41 5.0 1.357725 50.0 1464951.0 0.271545 Y
5 IC 280-672942/40 10.0 2.776403 50.0 1493641.0 0.27764 Y
6 ICIS 280-672942/39 50.0 18.046277 50.0 1366376.0 0.360926 Y
7 IC 280-672942/38 75.0 27.503595 50.0 1422085.0 0.366715 Y
8 IC 280-672942/37 100.0 35.38539 50.0 1420599.0 0.353854 Y
9 IC 280-672942/36 200.0 77.261615 50.0 1413702.0 0.386308 Y
RelResp = [-0.2425] + [0.3725]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
IC 280-672942/36
Intercept = 0.651
11/15/2024
3:53:55 PM
Page 392 of 777
Calibration / Ethyl methacrylate
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.6
Error Coefficients
Relative Standard Deviation:4.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.760943 50.0 392145.0 1.521886 Y
2 IC 280-672942/43 1.0 1.600071 50.0 373796.0 1.600071 Y
3 IC 280-672942/42 2.0 3.100432 50.0 382237.0 1.550216 Y
4 IC 280-672942/41 5.0 7.805183 50.0 379043.0 1.561037 Y
5 IC 280-672942/40 10.0 15.573922 50.0 379686.0 1.557392 Y
6 ICIS 280-672942/39 50.0 88.0 50.0 383025.0 1.76 Y
7 IC 280-672942/38 75.0 123.524639 50.0 411645.0 1.646995 Y
8 IC 280-672942/37 100.0 162.855519 50.0 401244.0 1.628555 Y
9 IC 280-672942/36 200.0 314.06271 50.0 430902.0 1.570314 Y
RelResp = [1.6]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
11/15/2024
3:53:55 PM
Page 393 of 777
Calibration / 1,1,2-Trichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2291
Error Coefficients
Relative Standard Deviation:6.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.0 50.0 1506210.0 0.0 N
2 IC 280-672942/43 1.0 0.219738 50.0 1454915.0 0.219738 Y
3 IC 280-672942/42 2.0 0.433043 50.0 1475488.0 0.216522 Y
4 IC 280-672942/41 5.0 1.067169 50.0 1464951.0 0.213434 Y
5 IC 280-672942/40 10.0 2.151722 50.0 1493641.0 0.215172 Y
6 ICIS 280-672942/39 50.0 12.143253 50.0 1366376.0 0.242865 Y
7 IC 280-672942/38 75.0 18.112877 50.0 1422085.0 0.241505 Y
8 IC 280-672942/37 100.0 23.376477 50.0 1420599.0 0.233765 Y
9 IC 280-672942/36 200.0 49.897928 50.0 1413702.0 0.24949 Y
RelResp = [0.2291]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/36
11/15/2024
3:53:55 PM
Page 394 of 777
Calibration / Tetrachloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5971
Error Coefficients
Relative Standard Deviation:8.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.299889 50.0 392145.0 0.599778 Y
2 IC 280-672942/43 1.0 0.641794 50.0 373796.0 0.641794 Y
3 IC 280-672942/42 2.0 1.293962 50.0 382237.0 0.646981 Y
4 IC 280-672942/41 5.0 3.225623 50.0 379043.0 0.645125 Y
5 IC 280-672942/40 10.0 5.633866 50.0 379686.0 0.563387 Y
6 ICIS 280-672942/39 50.0 31.686835 50.0 383025.0 0.633737 Y
7 IC 280-672942/38 75.0 44.654617 50.0 411645.0 0.595395 Y
8 IC 280-672942/37 100.0 54.221122 50.0 401244.0 0.542211 Y
9 IC 280-672942/36 200.0 101.129607 50.0 430902.0 0.505648 Y
RelResp = [0.5971]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 395 of 777
Calibration / 1,3-Dichloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.51
Error Coefficients
Relative Standard Deviation:2.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.789631 50.0 392145.0 1.579263 Y
2 IC 280-672942/43 1.0 1.494532 50.0 373796.0 1.494532 Y
3 IC 280-672942/42 2.0 3.005596 50.0 382237.0 1.502798 Y
4 IC 280-672942/41 5.0 7.615363 50.0 379043.0 1.523073 Y
5 IC 280-672942/40 10.0 15.099319 50.0 379686.0 1.509932 Y
6 ICIS 280-672942/39 50.0 78.21278 50.0 383025.0 1.564256 Y
7 IC 280-672942/38 75.0 112.515517 50.0 411645.0 1.500207 Y
8 IC 280-672942/37 100.0 146.918459 50.0 401244.0 1.469185 Y
9 IC 280-672942/36 200.0 288.47116 50.0 430902.0 1.442356 Y
RelResp = [1.51]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 396 of 777
Calibration / 2-Hexanone
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.01
Error Coefficients
Relative Standard Deviation:6.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 2.0 4.257226 50.0 392145.0 2.128613 Y
2 IC 280-672942/43 4.0 8.477084 50.0 373796.0 2.119271 Y
3 IC 280-672942/42 8.0 15.985763 50.0 382237.0 1.99822 Y
4 IC 280-672942/41 20.0 41.253895 50.0 379043.0 2.062695 Y
5 IC 280-672942/40 40.0 83.684808 50.0 379686.0 2.09212 Y
6 ICIS 280-672942/39 200.0 423.240781 50.0 383025.0 2.116204 Y
7 IC 280-672942/38 300.0 581.574779 50.0 411645.0 1.938583 Y
8 IC 280-672942/37 400.0 768.626821 50.0 401244.0 1.921567 Y
9 IC 280-672942/36 800.0 1373.266311 50.0 430902.0 1.716583 Y
RelResp = [2.01]x
Concentration
0 100 200 300 400 500 600 700 800
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 397 of 777
Calibration / Chlorodibromomethane
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.5806
Slope:0.784
Error Coefficients
Relative Standard Deviation:18.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.23805 50.0 392145.0 0.476099 N
2 IC 280-672942/43 1.0 0.487833 50.0 373796.0 0.487833 Y
3 IC 280-672942/42 2.0 0.987607 50.0 382237.0 0.493804 Y
4 IC 280-672942/41 5.0 2.588625 50.0 379043.0 0.517725 Y
5 IC 280-672942/40 10.0 5.971645 50.0 379686.0 0.597164 Y
6 ICIS 280-672942/39 50.0 38.269434 50.0 383025.0 0.765389 Y
7 IC 280-672942/38 75.0 57.747695 50.0 411645.0 0.769969 Y
8 IC 280-672942/37 100.0 76.772363 50.0 401244.0 0.767724 Y
9 IC 280-672942/36 200.0 159.837272 50.0 430902.0 0.799186 Y
RelResp = [-0.5806] + [0.784]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
IC 280-672942/36
Intercept = 0.741
11/15/2024
3:53:55 PM
Page 398 of 777
Calibration / Ethylene Dibromide
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9277
Error Coefficients
Relative Standard Deviation:3.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.48681 50.0 392145.0 0.973619 Y
2 IC 280-672942/43 1.0 0.894739 50.0 373796.0 0.894739 Y
3 IC 280-672942/42 2.0 1.752185 50.0 382237.0 0.876093 Y
4 IC 280-672942/41 5.0 4.523761 50.0 379043.0 0.904752 Y
5 IC 280-672942/40 10.0 9.113978 50.0 379686.0 0.911398 Y
6 ICIS 280-672942/39 50.0 49.180471 50.0 383025.0 0.983609 Y
7 IC 280-672942/38 75.0 71.046411 50.0 411645.0 0.947285 Y
8 IC 280-672942/37 100.0 93.25884 50.0 401244.0 0.932588 Y
9 IC 280-672942/36 200.0 185.07352 50.0 430902.0 0.925368 Y
RelResp = [0.9277]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
11/15/2024
3:53:55 PM
Page 399 of 777
Calibration / 1-Chlorohexane
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.4128
Slope:1.11
Error Coefficients
Relative Standard Deviation:7.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.4 0.901835 50.0 392145.0 2.254587 N
2 IC 280-672942/43 0.8 1.255631 50.0 373796.0 1.569539 Y
3 IC 280-672942/42 1.6 2.371696 50.0 382237.0 1.48231 Y
4 IC 280-672942/41 4.0 4.963553 50.0 379043.0 1.240888 Y
5 IC 280-672942/40 8.0 8.661763 50.0 379686.0 1.08272 Y
6 ICIS 280-672942/39 40.0 49.161674 50.0 383025.0 1.229042 Y
7 IC 280-672942/38 60.0 68.376878 50.0 411645.0 1.139615 Y
8 IC 280-672942/37 80.0 85.255854 50.0 401244.0 1.065698 Y
9 IC 280-672942/36 160.0 163.744308 50.0 430902.0 1.023402 Y
RelResp = [0.4128] + [1.11]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
Intercept = -0.372
11/15/2024
3:53:55 PM
Page 400 of 777
Calibration / Chlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.374
Error Coefficients
Relative Standard Deviation:8.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 1.375129 50.0 392145.0 2.750258 Y
2 IC 280-672942/43 1.0 2.55594 50.0 373796.0 2.55594 Y
3 IC 280-672942/42 2.0 4.826587 50.0 382237.0 2.413293 Y
4 IC 280-672942/41 5.0 11.787713 50.0 379043.0 2.357543 Y
5 IC 280-672942/40 10.0 23.085655 50.0 379686.0 2.308565 Y
6 ICIS 280-672942/39 50.0 119.491286 50.0 383025.0 2.389826 Y
7 IC 280-672942/38 75.0 170.887658 50.0 411645.0 2.278502 Y
8 IC 280-672942/37 100.0 218.264697 50.0 401244.0 2.182647 Y
9 IC 280-672942/36 200.0 426.011135 50.0 430902.0 2.130056 Y
RelResp = [2.374]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 401 of 777
Calibration / 1,1,1,2-Tetrachloroethane
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.2418
Slope:0.7215
Error Coefficients
Relative Standard Deviation:6.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.0 50.0 392145.0 0.0 N
2 IC 280-672942/43 1.0 0.500808 50.0 373796.0 0.500808 Y
3 IC 280-672942/42 2.0 1.196901 50.0 382237.0 0.598451 Y
4 IC 280-672942/41 5.0 2.938585 50.0 379043.0 0.587717 Y
5 IC 280-672942/40 10.0 6.516964 50.0 379686.0 0.651696 Y
6 ICIS 280-672942/39 50.0 38.129365 50.0 383025.0 0.762587 Y
7 IC 280-672942/38 75.0 56.76566 50.0 411645.0 0.756875 Y
8 IC 280-672942/37 100.0 72.754359 50.0 401244.0 0.727544 Y
9 IC 280-672942/36 200.0 147.901147 50.0 430902.0 0.739506 Y
RelResp = [-0.2418] + [0.7215]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/36
Intercept = 0.335
11/15/2024
3:53:55 PM
Page 402 of 777
Calibration / Ethylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.255
Error Coefficients
Relative Standard Deviation:9.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.767191 50.0 392145.0 1.534381 Y
2 IC 280-672942/43 1.0 1.231554 50.0 373796.0 1.231554 Y
3 IC 280-672942/42 2.0 2.527751 50.0 382237.0 1.263876 Y
4 IC 280-672942/41 5.0 6.403759 50.0 379043.0 1.280752 Y
5 IC 280-672942/40 10.0 12.029019 50.0 379686.0 1.202902 Y
6 ICIS 280-672942/39 50.0 64.717447 50.0 383025.0 1.294349 Y
7 IC 280-672942/38 75.0 91.550365 50.0 411645.0 1.220672 Y
8 IC 280-672942/37 100.0 116.041361 50.0 401244.0 1.160414 Y
9 IC 280-672942/36 200.0 222.078338 50.0 430902.0 1.110392 Y
RelResp = [1.255]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 403 of 777
Calibration / m-Xylene & p-Xylene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.544
Error Coefficients
Relative Standard Deviation:6.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.0 50.0 392145.0 0.0 N
2 IC 280-672942/43 1.0 1.713769 50.0 373796.0 1.713769 Y
3 IC 280-672942/42 2.0 3.107104 50.0 382237.0 1.553552 Y
4 IC 280-672942/41 5.0 7.83671 50.0 379043.0 1.567342 Y
5 IC 280-672942/40 10.0 15.488325 50.0 379686.0 1.548832 Y
6 ICIS 280-672942/39 50.0 81.994387 50.0 383025.0 1.639888 Y
7 IC 280-672942/38 75.0 113.031253 50.0 411645.0 1.507083 Y
8 IC 280-672942/37 100.0 143.890999 50.0 401244.0 1.43891 Y
9 IC 280-672942/36 200.0 276.146432 50.0 430902.0 1.380732 Y
RelResp = [1.544]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 404 of 777
Calibration / o-Xylene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.587
Error Coefficients
Relative Standard Deviation:7.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.894312 50.0 392145.0 1.788624 Y
2 IC 280-672942/43 1.0 1.64127 50.0 373796.0 1.64127 Y
3 IC 280-672942/42 2.0 3.447076 50.0 382237.0 1.723538 Y
4 IC 280-672942/41 5.0 8.006875 50.0 379043.0 1.601375 Y
5 IC 280-672942/40 10.0 15.257476 50.0 379686.0 1.525748 Y
6 ICIS 280-672942/39 50.0 81.663077 50.0 383025.0 1.633262 Y
7 IC 280-672942/38 75.0 113.698818 50.0 411645.0 1.515984 Y
8 IC 280-672942/37 100.0 144.694625 50.0 401244.0 1.446946 Y
9 IC 280-672942/36 200.0 281.675764 50.0 430902.0 1.408379 Y
RelResp = [1.587]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 405 of 777
Calibration / Styrene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.664
Error Coefficients
Relative Standard Deviation:7.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 1.530684 50.0 392145.0 3.061368 Y
2 IC 280-672942/43 1.0 2.708295 50.0 373796.0 2.708295 Y
3 IC 280-672942/42 2.0 5.355316 50.0 382237.0 2.677658 Y
4 IC 280-672942/41 5.0 13.372757 50.0 379043.0 2.674551 Y
5 IC 280-672942/40 10.0 25.753781 50.0 379686.0 2.575378 Y
6 ICIS 280-672942/39 50.0 139.310097 50.0 383025.0 2.786202 Y
7 IC 280-672942/38 75.0 194.789078 50.0 411645.0 2.597188 Y
8 IC 280-672942/37 100.0 250.743936 50.0 401244.0 2.507439 Y
9 IC 280-672942/36 200.0 478.404022 50.0 430902.0 2.39202 Y
RelResp = [2.664]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 406 of 777
Calibration / Bromoform
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.9331
Slope:0.6281
Error Coefficients
Relative Standard Deviation:16.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.0 50.0 392145.0 0.0 N
2 IC 280-672942/43 1.0 0.0 50.0 373796.0 0.0 N
3 IC 280-672942/42 2.0 0.70833 50.0 382237.0 0.354165 Y
4 IC 280-672942/41 5.0 1.817736 50.0 379043.0 0.363547 Y
5 IC 280-672942/40 10.0 4.308165 50.0 379686.0 0.430817 Y
6 ICIS 280-672942/39 50.0 29.510606 50.0 383025.0 0.590212 Y
7 IC 280-672942/38 75.0 45.593169 50.0 411645.0 0.607909 Y
8 IC 280-672942/37 100.0 62.543988 50.0 401244.0 0.62544 Y
9 IC 280-672942/36 200.0 126.604077 50.0 430902.0 0.63302 Y
RelResp = [-0.9331] + [0.6281]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
IC 280-672942/36
Intercept = 1.49
11/15/2024
3:53:55 PM
Page 407 of 777
Calibration / Isopropylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.112
Error Coefficients
Relative Standard Deviation:4.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 1.082842 50.0 728130.0 2.165685 Y
2 IC 280-672942/43 1.0 2.143923 50.0 674931.0 2.143923 Y
3 IC 280-672942/42 2.0 4.283824 50.0 682311.0 2.141912 Y
4 IC 280-672942/41 5.0 10.057879 50.0 685398.0 2.011576 Y
5 IC 280-672942/40 10.0 19.726917 50.0 661667.0 1.972692 Y
6 ICIS 280-672942/39 50.0 108.851836 50.0 685982.0 2.177037 Y
7 IC 280-672942/38 75.0 170.123754 50.0 660180.0 2.268317 Y
8 IC 280-672942/37 100.0 212.262119 50.0 646332.0 2.122621 Y
9 IC 280-672942/36 200.0 400.499258 50.0 683014.0 2.002496 Y
RelResp = [2.112]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
11/15/2024
3:53:55 PM
Page 408 of 777
Calibration / Cyclohexanone
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2021
Error Coefficients
Relative Standard Deviation:11.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 15.0 3.327213 50.0 392145.0 0.221814 Y
2 IC 280-672942/43 30.0 7.081938 50.0 373796.0 0.236065 Y
3 IC 280-672942/42 60.0 12.499444 50.0 382237.0 0.208324 Y
4 IC 280-672942/41 150.0 33.431036 50.0 379043.0 0.222874 Y
5 IC 280-672942/40 300.0 61.324884 50.0 379686.0 0.204416 Y
6 ICIS 280-672942/39 1500.0 286.641995 50.0 383025.0 0.191095 Y
7 IC 280-672942/38 2250.0 409.427662 50.0 411645.0 0.181968 Y
8 IC 280-672942/37 3000.0 541.171332 50.0 401244.0 0.18039 Y
9 IC 280-672942/36 6000.0 1029.153032 50.0 430902.0 0.171526 Y
RelResp = [0.2021]x
Concentration
0 1000 2000 3000 4000 5000 6000
0.0
0.2
0.4
0.6
0.8
1.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 409 of 777
Calibration / 4-Bromofluorobenzene (Surr)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9567
Error Coefficients
Relative Standard Deviation:3.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/36 50.0 48.568843 50.0 683014.0 0.971377 Y
2 IC 280-672942/37 50.0 49.755698 50.0 646332.0 0.995114 Y
3 IC 280-672942/38 50.0 50.845603 50.0 660180.0 1.016912 Y
4 ICIS 280-672942/39 50.0 46.979367 50.0 685982.0 0.939587 Y
5 IC 280-672942/40 50.0 47.179926 50.0 661667.0 0.943599 Y
6 IC 280-672942/41 50.0 47.357229 50.0 685398.0 0.947145 Y
7 IC 280-672942/42 50.0 47.128582 50.0 682311.0 0.942572 Y
8 IC 280-672942/43 50.0 46.71885 50.0 674931.0 0.934377 Y
9 IC 280-672942/44 50.0 45.990963 50.0 728130.0 0.919819 Y
RelResp = [0.9567]x
Concentration
0 10 20 30 40 50
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/36IC 280-672942/37IC 280-672942/38
11/15/2024
3:53:55 PM
Page 410 of 777
Calibration / 1,1,2,2-Tetrachloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8212
Error Coefficients
Relative Standard Deviation:7.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.354882 50.0 728130.0 0.709763 N
2 IC 280-672942/43 1.0 0.805268 50.0 674931.0 0.805268 Y
3 IC 280-672942/42 2.0 1.454176 50.0 682311.0 0.727088 Y
4 IC 280-672942/41 5.0 3.810268 50.0 685398.0 0.762054 Y
5 IC 280-672942/40 10.0 7.754958 50.0 661667.0 0.775496 Y
6 ICIS 280-672942/39 50.0 43.008636 50.0 685982.0 0.860173 Y
7 IC 280-672942/38 75.0 67.29392 50.0 660180.0 0.897252 Y
8 IC 280-672942/37 100.0 88.643994 50.0 646332.0 0.88644 Y
9 IC 280-672942/36 200.0 171.183387 50.0 683014.0 0.855917 Y
RelResp = [0.8212]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/36
11/15/2024
3:53:55 PM
Page 411 of 777
Calibration / trans-1,4-Dichloro-2-butene
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.1787
Slope:0.3308
Error Coefficients
Relative Standard Deviation:14.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.113579 50.0 728130.0 0.227157 N
2 IC 280-672942/43 1.0 0.229727 50.0 674931.0 0.229727 Y
3 IC 280-672942/42 2.0 0.52542 50.0 682311.0 0.26271 Y
4 IC 280-672942/41 5.0 1.075652 50.0 685398.0 0.21513 Y
5 IC 280-672942/40 10.0 2.828084 50.0 661667.0 0.282808 Y
6 ICIS 280-672942/39 50.0 15.996338 50.0 685982.0 0.319927 Y
7 IC 280-672942/38 75.0 25.563634 50.0 660180.0 0.340848 Y
8 IC 280-672942/37 100.0 34.048755 50.0 646332.0 0.340488 Y
9 IC 280-672942/36 200.0 64.829125 50.0 683014.0 0.324146 Y
RelResp = [-0.1787] + [0.3308]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
Intercept = 0.540
11/15/2024
3:53:55 PM
Page 412 of 777
Calibration / Bromobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5902
Error Coefficients
Relative Standard Deviation:4.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.343002 50.0 728130.0 0.686004 N
2 IC 280-672942/43 1.0 0.628657 50.0 674931.0 0.628657 Y
3 IC 280-672942/42 2.0 1.242762 50.0 682311.0 0.621381 Y
4 IC 280-672942/41 5.0 2.850752 50.0 685398.0 0.57015 Y
5 IC 280-672942/40 10.0 5.609015 50.0 661667.0 0.560901 Y
6 ICIS 280-672942/39 50.0 29.376208 50.0 685982.0 0.587524 Y
7 IC 280-672942/38 75.0 45.281817 50.0 660180.0 0.603758 Y
8 IC 280-672942/37 100.0 59.073355 50.0 646332.0 0.590734 Y
9 IC 280-672942/36 200.0 111.743976 50.0 683014.0 0.55872 Y
RelResp = [0.5902]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
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3:53:55 PM
Page 413 of 777
Calibration / 1,2,3-Trichloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3235
Error Coefficients
Relative Standard Deviation:6.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.167621 50.0 728130.0 0.335242 Y
2 IC 280-672942/43 1.0 0.275584 50.0 674931.0 0.275584 Y
3 IC 280-672942/42 2.0 0.642156 50.0 682311.0 0.321078 Y
4 IC 280-672942/41 5.0 1.587472 50.0 685398.0 0.317494 Y
5 IC 280-672942/40 10.0 3.179469 50.0 661667.0 0.317947 Y
6 ICIS 280-672942/39 50.0 17.023114 50.0 685982.0 0.340462 Y
7 IC 280-672942/38 75.0 25.863325 50.0 660180.0 0.344844 Y
8 IC 280-672942/37 100.0 34.131453 50.0 646332.0 0.341315 Y
9 IC 280-672942/36 200.0 63.476737 50.0 683014.0 0.317384 Y
RelResp = [0.3235]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
11/15/2024
3:53:55 PM
Page 414 of 777
Calibration / N-Propylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6305
Error Coefficients
Relative Standard Deviation:5.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.37768 50.0 728130.0 0.75536 N
2 IC 280-672942/43 1.0 0.687033 50.0 674931.0 0.687033 Y
3 IC 280-672942/42 2.0 1.30952 50.0 682311.0 0.65476 Y
4 IC 280-672942/41 5.0 3.091051 50.0 685398.0 0.61821 Y
5 IC 280-672942/40 10.0 6.203876 50.0 661667.0 0.620388 Y
6 ICIS 280-672942/39 50.0 32.11265 50.0 685982.0 0.642253 Y
7 IC 280-672942/38 75.0 48.569481 50.0 660180.0 0.647593 Y
8 IC 280-672942/37 100.0 59.952934 50.0 646332.0 0.599529 Y
9 IC 280-672942/36 200.0 114.786373 50.0 683014.0 0.573932 Y
RelResp = [0.6305]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 415 of 777
Calibration / 2-Chlorotoluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5509
Error Coefficients
Relative Standard Deviation:5.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.342247 50.0 728130.0 0.684493 N
2 IC 280-672942/43 1.0 0.59695 50.0 674931.0 0.59695 Y
3 IC 280-672942/42 2.0 1.165085 50.0 682311.0 0.582542 Y
4 IC 280-672942/41 5.0 2.612643 50.0 685398.0 0.522529 Y
5 IC 280-672942/40 10.0 5.449418 50.0 661667.0 0.544942 Y
6 ICIS 280-672942/39 50.0 27.554586 50.0 685982.0 0.551092 Y
7 IC 280-672942/38 75.0 42.374655 50.0 660180.0 0.564995 Y
8 IC 280-672942/37 100.0 52.899748 50.0 646332.0 0.528997 Y
9 IC 280-672942/36 200.0 102.987347 50.0 683014.0 0.514937 Y
RelResp = [0.5509]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 416 of 777
Calibration / 1,3,5-Trimethylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.986
Error Coefficients
Relative Standard Deviation:7.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 1.119168 50.0 728130.0 2.238337 Y
2 IC 280-672942/43 1.0 2.081546 50.0 674931.0 2.081546 Y
3 IC 280-672942/42 2.0 4.236191 50.0 682311.0 2.118096 Y
4 IC 280-672942/41 5.0 9.774686 50.0 685398.0 1.954937 Y
5 IC 280-672942/40 10.0 19.373869 50.0 661667.0 1.937387 Y
6 ICIS 280-672942/39 50.0 100.472243 50.0 685982.0 2.009445 Y
7 IC 280-672942/38 75.0 145.2544 50.0 660180.0 1.936725 Y
8 IC 280-672942/37 100.0 182.101459 50.0 646332.0 1.821015 Y
9 IC 280-672942/36 200.0 355.621334 50.0 683014.0 1.778107 Y
RelResp = [1.986]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 417 of 777
Calibration / 4-Chlorotoluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5881
Error Coefficients
Relative Standard Deviation:6.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.345062 50.0 728130.0 0.690124 N
2 IC 280-672942/43 1.0 0.625916 50.0 674931.0 0.625916 Y
3 IC 280-672942/42 2.0 1.306516 50.0 682311.0 0.653258 Y
4 IC 280-672942/41 5.0 2.935885 50.0 685398.0 0.587177 Y
5 IC 280-672942/40 10.0 5.824607 50.0 661667.0 0.582461 Y
6 ICIS 280-672942/39 50.0 29.139686 50.0 685982.0 0.582794 Y
7 IC 280-672942/38 75.0 43.319549 50.0 660180.0 0.577594 Y
8 IC 280-672942/37 100.0 55.747433 50.0 646332.0 0.557474 Y
9 IC 280-672942/36 200.0 107.578029 50.0 683014.0 0.53789 Y
RelResp = [0.5881]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 418 of 777
Calibration / tert-Butylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.721
Error Coefficients
Relative Standard Deviation:6.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.950654 50.0 728130.0 1.901309 Y
2 IC 280-672942/43 1.0 1.829076 50.0 674931.0 1.829076 Y
3 IC 280-672942/42 2.0 3.465502 50.0 682311.0 1.732751 Y
4 IC 280-672942/41 5.0 8.218072 50.0 685398.0 1.643614 Y
5 IC 280-672942/40 10.0 16.379463 50.0 661667.0 1.637946 Y
6 ICIS 280-672942/39 50.0 87.913604 50.0 685982.0 1.758272 Y
7 IC 280-672942/38 75.0 133.024478 50.0 660180.0 1.77366 Y
8 IC 280-672942/37 100.0 164.763233 50.0 646332.0 1.647632 Y
9 IC 280-672942/36 200.0 313.557921 50.0 683014.0 1.56779 Y
RelResp = [1.721]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 419 of 777
Calibration / 1,2,4-Trimethylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.121
Error Coefficients
Relative Standard Deviation:8.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 1.23467 50.0 728130.0 2.469339 Y
2 IC 280-672942/43 1.0 2.208967 50.0 674931.0 2.208967 Y
3 IC 280-672942/42 2.0 4.435367 50.0 682311.0 2.217684 Y
4 IC 280-672942/41 5.0 10.633165 50.0 685398.0 2.126633 Y
5 IC 280-672942/40 10.0 20.931224 50.0 661667.0 2.093122 Y
6 ICIS 280-672942/39 50.0 106.047462 50.0 685982.0 2.120949 Y
7 IC 280-672942/38 75.0 154.07139 50.0 660180.0 2.054285 Y
8 IC 280-672942/37 100.0 191.854728 50.0 646332.0 1.918547 Y
9 IC 280-672942/36 200.0 375.436082 50.0 683014.0 1.87718 Y
RelResp = [2.121]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 420 of 777
Calibration / sec-Butylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.519
Error Coefficients
Relative Standard Deviation:7.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.285251 50.0 728130.0 0.570503 Y
2 IC 280-672942/43 1.0 0.564576 50.0 674931.0 0.564576 Y
3 IC 280-672942/42 2.0 1.118771 50.0 682311.0 0.559386 Y
4 IC 280-672942/41 5.0 2.435009 50.0 685398.0 0.487002 Y
5 IC 280-672942/40 10.0 4.835741 50.0 661667.0 0.483574 Y
6 ICIS 280-672942/39 50.0 26.457473 50.0 685982.0 0.529149 Y
7 IC 280-672942/38 75.0 39.416296 50.0 660180.0 0.525551 Y
8 IC 280-672942/37 100.0 48.695253 50.0 646332.0 0.486953 Y
9 IC 280-672942/36 200.0 92.833529 50.0 683014.0 0.464168 Y
RelResp = [0.519]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 421 of 777
Calibration / 1,3-Dichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.186
Error Coefficients
Relative Standard Deviation:10.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.704819 50.0 728130.0 1.409638 Y
2 IC 280-672942/43 1.0 1.327914 50.0 674931.0 1.327914 Y
3 IC 280-672942/42 2.0 2.490873 50.0 682311.0 1.245436 Y
4 IC 280-672942/41 5.0 5.678088 50.0 685398.0 1.135618 Y
5 IC 280-672942/40 10.0 11.352614 50.0 661667.0 1.135261 Y
6 ICIS 280-672942/39 50.0 57.684385 50.0 685982.0 1.153688 Y
7 IC 280-672942/38 75.0 85.882259 50.0 660180.0 1.145097 Y
8 IC 280-672942/37 100.0 108.005793 50.0 646332.0 1.080058 Y
9 IC 280-672942/36 200.0 208.055545 50.0 683014.0 1.040278 Y
RelResp = [1.186]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 422 of 777
Calibration / 4-Isopropyltoluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.256
Error Coefficients
Relative Standard Deviation:8.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 1.32133 50.0 728130.0 2.64266 Y
2 IC 280-672942/43 1.0 2.341647 50.0 674931.0 2.341647 Y
3 IC 280-672942/42 2.0 4.704087 50.0 682311.0 2.352043 Y
4 IC 280-672942/41 5.0 11.163295 50.0 685398.0 2.232659 Y
5 IC 280-672942/40 10.0 21.69815 50.0 661667.0 2.169815 Y
6 ICIS 280-672942/39 50.0 115.342677 50.0 685982.0 2.306854 Y
7 IC 280-672942/38 75.0 168.155655 50.0 660180.0 2.242075 Y
8 IC 280-672942/37 100.0 205.912132 50.0 646332.0 2.059121 Y
9 IC 280-672942/36 200.0 391.911366 50.0 683014.0 1.959557 Y
RelResp = [2.256]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 423 of 777
Calibration / 1,4-Dichlorobenzene
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.292
Slope:1.124
Error Coefficients
Relative Standard Deviation:6.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.795668 50.0 728130.0 1.591337 N
2 IC 280-672942/43 1.0 1.353916 50.0 674931.0 1.353916 Y
3 IC 280-672942/42 2.0 2.751165 50.0 682311.0 1.375582 Y
4 IC 280-672942/41 5.0 6.086318 50.0 685398.0 1.217264 Y
5 IC 280-672942/40 10.0 11.859667 50.0 661667.0 1.185967 Y
6 ICIS 280-672942/39 50.0 57.474176 50.0 685982.0 1.149484 Y
7 IC 280-672942/38 75.0 85.419961 50.0 660180.0 1.138933 Y
8 IC 280-672942/37 100.0 106.659116 50.0 646332.0 1.066591 Y
9 IC 280-672942/36 200.0 209.243149 50.0 683014.0 1.046216 Y
RelResp = [0.292] + [1.124]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
Intercept = -0.260
11/15/2024
3:53:55 PM
Page 424 of 777
Calibration / n-Butylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.151
Error Coefficients
Relative Standard Deviation:8.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 1.342617 50.0 728130.0 2.685235 N
2 IC 280-672942/43 1.0 2.448324 50.0 674931.0 2.448324 Y
3 IC 280-672942/42 2.0 4.682249 50.0 682311.0 2.341125 Y
4 IC 280-672942/41 5.0 10.798543 50.0 685398.0 2.159709 Y
5 IC 280-672942/40 10.0 21.226538 50.0 661667.0 2.122654 Y
6 ICIS 280-672942/39 50.0 109.630063 50.0 685982.0 2.192601 Y
7 IC 280-672942/38 75.0 158.896665 50.0 660180.0 2.118622 Y
8 IC 280-672942/37 100.0 193.335391 50.0 646332.0 1.933354 Y
9 IC 280-672942/36 200.0 378.406153 50.0 683014.0 1.892031 Y
RelResp = [2.151]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 425 of 777
Calibration / 1,2-Dichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.127
Error Coefficients
Relative Standard Deviation:6.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.695206 50.0 728130.0 1.390411 N
2 IC 280-672942/43 1.0 1.23583 50.0 674931.0 1.23583 Y
3 IC 280-672942/42 2.0 2.475337 50.0 682311.0 1.237669 Y
4 IC 280-672942/41 5.0 5.694647 50.0 685398.0 1.138929 Y
5 IC 280-672942/40 10.0 11.189994 50.0 661667.0 1.118999 Y
6 ICIS 280-672942/39 50.0 56.217875 50.0 685982.0 1.124357 Y
7 IC 280-672942/38 75.0 81.696128 50.0 660180.0 1.089282 Y
8 IC 280-672942/37 100.0 105.084384 50.0 646332.0 1.050844 Y
9 IC 280-672942/36 200.0 204.507009 50.0 683014.0 1.022535 Y
RelResp = [1.127]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 426 of 777
Calibration / 1,2-Dibromo-3-Chloropropane
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.3107
Slope:0.3583
Error Coefficients
Relative Standard Deviation:9.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.104652 50.0 728130.0 0.209303 N
2 IC 280-672942/43 1.0 0.223578 50.0 674931.0 0.223578 N
3 IC 280-672942/42 2.0 0.458076 50.0 682311.0 0.229038 Y
4 IC 280-672942/41 5.0 1.220459 50.0 685398.0 0.244092 Y
5 IC 280-672942/40 10.0 2.969016 50.0 661667.0 0.296902 Y
6 ICIS 280-672942/39 50.0 17.20723 50.0 685982.0 0.344145 Y
7 IC 280-672942/38 75.0 27.602699 50.0 660180.0 0.368036 Y
8 IC 280-672942/37 100.0 38.164597 50.0 646332.0 0.381646 Y
9 IC 280-672942/36 200.0 76.156199 50.0 683014.0 0.380781 Y
RelResp = [-0.3107] + [0.3583]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/36
Intercept = 0.867
11/15/2024
3:53:55 PM
Page 427 of 777
Calibration / 1,2,4-Trichlorobenzene
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.3276
Slope:0.8014
Error Coefficients
Relative Standard Deviation:4.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.54379 50.0 728130.0 1.087581 N
2 IC 280-672942/43 1.0 1.093964 50.0 674931.0 1.093964 Y
3 IC 280-672942/42 2.0 2.036974 50.0 682311.0 1.018487 Y
4 IC 280-672942/41 5.0 4.510956 50.0 685398.0 0.902191 Y
5 IC 280-672942/40 10.0 8.498384 50.0 661667.0 0.849838 Y
6 ICIS 280-672942/39 50.0 41.426889 50.0 685982.0 0.828538 Y
7 IC 280-672942/38 75.0 59.60844 50.0 660180.0 0.794779 Y
8 IC 280-672942/37 100.0 75.765087 50.0 646332.0 0.757651 Y
9 IC 280-672942/36 200.0 154.170998 50.0 683014.0 0.770855 Y
RelResp = [0.3276] + [0.8014]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
Intercept = -0.409
11/15/2024
3:53:55 PM
Page 428 of 777
Calibration / Hexachlorobutadiene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3439
Error Coefficients
Relative Standard Deviation:7.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.222556 50.0 728130.0 0.445113 N
2 IC 280-672942/43 1.0 0.394188 50.0 674931.0 0.394188 Y
3 IC 280-672942/42 2.0 0.72892 50.0 682311.0 0.36446 Y
4 IC 280-672942/41 5.0 1.663924 50.0 685398.0 0.332785 Y
5 IC 280-672942/40 10.0 3.22685 50.0 661667.0 0.322685 Y
6 ICIS 280-672942/39 50.0 17.172316 50.0 685982.0 0.343446 Y
7 IC 280-672942/38 75.0 25.930655 50.0 660180.0 0.345742 Y
8 IC 280-672942/37 100.0 32.076549 50.0 646332.0 0.320765 Y
9 IC 280-672942/36 200.0 65.395878 50.0 683014.0 0.326979 Y
RelResp = [0.3439]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 429 of 777
Calibration / Naphthalene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:3.225
Error Coefficients
Relative Standard Deviation:5.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 1.746872 50.0 728130.0 3.493744 Y
2 IC 280-672942/43 1.0 3.491987 50.0 674931.0 3.491987 Y
3 IC 280-672942/42 2.0 6.528548 50.0 682311.0 3.264274 Y
4 IC 280-672942/41 5.0 16.104366 50.0 685398.0 3.220873 Y
5 IC 280-672942/40 10.0 32.195651 50.0 661667.0 3.219565 Y
6 ICIS 280-672942/39 50.0 157.112213 50.0 685982.0 3.142244 Y
7 IC 280-672942/38 75.0 234.258384 50.0 660180.0 3.123445 Y
8 IC 280-672942/37 100.0 311.4722 50.0 646332.0 3.114722 Y
9 IC 280-672942/36 200.0 590.355981 50.0 683014.0 2.95178 Y
RelResp = [3.225]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
11/15/2024
3:53:55 PM
Page 430 of 777
Calibration / 1,2,3-Trichlorobenzene
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.2872
Slope:0.7805
Error Coefficients
Relative Standard Deviation:3.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672942/44 0.5 0.545507 50.0 728130.0 1.091014 N
2 IC 280-672942/43 1.0 1.052404 50.0 674931.0 1.052404 Y
3 IC 280-672942/42 2.0 1.887849 50.0 682311.0 0.943924 Y
4 IC 280-672942/41 5.0 4.270366 50.0 685398.0 0.854073 Y
5 IC 280-672942/40 10.0 8.310978 50.0 661667.0 0.831098 Y
6 ICIS 280-672942/39 50.0 40.162133 50.0 685982.0 0.803243 Y
7 IC 280-672942/38 75.0 58.381956 50.0 660180.0 0.778426 Y
8 IC 280-672942/37 100.0 76.126743 50.0 646332.0 0.761267 Y
9 IC 280-672942/36 200.0 150.022474 50.0 683014.0 0.750112 Y
RelResp = [0.2872] + [0.7805]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672942/44
IC 280-672942/43
IC 280-672942/42
IC 280-672942/41
IC 280-672942/40
ICIS 280-672942/39
IC 280-672942/38
IC 280-672942/37
Intercept = -0.368
11/15/2024
3:53:55 PM
Page 431 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672931
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_X4
98520Calibration Start Date:Calibration End Date:10/29/2024 17:11
N
10/29/2024 20:00
0.25(mm)RXI-624SilMSID:
Calibration Files
LEVEL:LAB SAMPLE ID:LAB FILE ID:1Level IC 280-672931/43 X4_00008669.D
2Level IC 280-672931/42 X4_00008668.D
3Level IC 280-672931/41 X4_00008667.D
4Level IC 280-672931/40 X4_00008666.D
5Level IC 280-672931/39 X4_00008665.D
6Level ICIS 280-672931/38 X4_00008664.D
7Level IC 280-672931/37 X4_00008663.D
8Level IC 280-672931/36 X4_00008662.D
9Level IC 280-672931/35 X4_00008661.D
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
Dichlorodifluoromethane 0.2476 0.3107 0.2678 0.2988 0.2980 Ave 7.4
0.2848 0.2649 0.3044 0.2943
15.00.285
7Chloromethane0.4584 0.4760 0.4246 0.4378 0.4276 Ave 7.2
0.3909 0.3873 0.4331 0.3931
0.1000 15.00.425
4Vinyl chloride 0.2834 0.3102 0.3318 0.3150 0.3510 Ave 6.3
0.3185 0.3171 0.3451 0.3329
30.00.322
8Bromomethane0.2893 0.1977 0.1504 0.1148 0.1209 Lin2 0.9980
0.1045 0.1049 0.1045 +++++
0.99000.092
9
0.103
7Chloroethane0.2267 0.1875 0.2311 0.2153 0.2113 Ave 6.2
0.2058 0.2011 0.2152 0.2070
15.00.211
2Dichlorofluoromethane0.5383 0.4718 0.4520 0.5035 0.5243 Ave 5.7
0.4954 0.4794 0.5298 0.5100
15.00.500
5Trichlorofluoromethane0.3290 0.3095 0.2790 0.3109 0.3147 Ave 5.7
0.2906 0.2777 0.3143 0.3084
15.00.303
8Ethyl ether 0.3436 0.2813 0.2645 0.2521 0.2933 Ave 9.3
0.2734 0.2761 0.2758 0.2679
15.00.280
9Acrolein0.1015 0.0877 0.0806 0.0827 0.0891 Lin2 0.9970
0.0842 0.0869 0.0876 0.0860
0.99000.065
9
0.084
5
1,1,2-Trichloro-1,2,2-trifluoroeth
ane
0.1504 0.1396 0.1544 0.1392 0.1315 Ave 5.3
0.1367 0.1351 0.1467 0.1394
15.00.141
5
1,1-Dichloroethene 0.2473 0.1722 0.2109 0.2074 0.1955 Ave 9.7
0.1952 0.2002 0.2097 0.2096
30.00.205
3Acetone++++++++++0.6515 0.4402 0.4143 Lin2 0.9970
0.3180 0.3198 0.3233 0.3155
0.99002.696
9
0.315
8
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
11/15/2024
3:53:55 PM
Page 432 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672931
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_X4
98520Calibration Start Date:Calibration End Date:10/29/2024 17:11
N
10/29/2024 20:00
0.25(mm)RXI-624SilMSID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
Iodomethane ++++++++++0.0917 0.0808 0.0944 Qua 1.0000
0.1089 0.1298 0.1479 +++++
0.99000.070
0
0.070
4
0.0007699
Carbon disulfide 1.1529 0.9214 0.8007 0.7804 0.7922 Lin2 0.9980
0.7449 0.7573 0.7911 0.7775
0.99000.187
4
0.755
2Methyl acetate 0.6521 0.5918 0.5842 0.6033 0.6634 Ave 4.8
0.6197 0.6418 0.6487 0.6609
15.00.629
53-Chloro-1-propene 0.6922 0.5894 0.6160 0.6571 0.6661 Ave 4.9
0.6605 0.6634 0.6695 0.6283
15.00.649
2Methylene Chloride 0.6041 0.4714 0.3530 0.3084 0.2930 Lin2 0.9960
0.2503 0.2593 0.2624 0.2528
0.99000.178
7
0.263
02-Methyl-2-propanol 0.1873 0.1700 0.1590 0.1570 0.1836 Ave 7.0
0.1700 0.1794 0.1845 0.1912
15.00.175
8Acrylonitrile0.2953 0.2847 0.2868 0.2864 0.3219 Ave 6.4
0.2941 0.3070 0.3118 0.2568
15.00.293
9Methyl tert-butyl ether 0.8907 0.8340 0.8626 0.8270 0.9384 Ave 4.4
0.8765 0.9100 0.9268 0.9100
15.00.886
2trans-1,2-Dichloroethene 0.2512 0.2282 0.2339 0.2349 0.2383 Ave 3.7
0.2227 0.2240 0.2377 0.2320
15.00.233
6Hexane2.4604 1.9975 1.9159 2.0398 1.9382 Ave 7.9
2.0762 1.9784 2.1255 2.1080
15.02.071
1Vinyl acetate 0.8944 0.8882 0.8962 0.8783 0.9934 Ave 4.9
0.9512 0.9407 0.9870 0.9758
15.00.933
91,1-Dichloroethane 0.5358 0.5567 0.5264 0.5008 0.5297 Ave 3.2
0.5115 0.5251 0.5461 0.5300
0.1000 15.00.529
12-Butanone (MEK)0.9495 0.7822 0.5814 0.5510 0.6302 Lin2 0.9940
0.5512 0.5652 0.5799 0.5644
0.99000.778
7
0.556
2cis-1,2-Dichloroethene 0.3063 0.2810 0.2519 0.2455 0.2581 Ave 7.4
0.2468 0.2556 0.2599 0.2586
15.00.262
62,2-Dichloropropane 0.4483 0.3750 0.3721 0.3772 0.4017 Ave 6.0
0.3813 0.3888 0.4060 0.4017
15.00.394
7sec-Butyl Alcohol 0.1556 0.1417 0.1436 0.1524 0.1836 Ave 12.1
0.1757 0.1870 0.1920 0.1498
15.00.164
6Chlorobromomethane0.1187 0.1315 0.1268 0.1030 0.1138 Ave 9.2
0.1056 0.1092 0.1060 0.1039
15.00.113
2Tetrahydrofuran0.3805 0.3730 0.3494 0.3569 0.4036 Ave 4.5
0.3685 0.3809 0.3874 0.3912
15.00.376
8
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
11/15/2024
3:53:55 PM
Page 433 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672931
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_X4
98520Calibration Start Date:Calibration End Date:10/29/2024 17:11
N
10/29/2024 20:00
0.25(mm)RXI-624SilMSID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
Chloroform 0.4334 0.4229 0.4288 0.3881 0.4190 Ave 3.6
0.3976 0.4095 0.4245 0.4119
30.00.415
11,1,1-Trichloroethane 0.2936 0.3492 0.2957 0.2993 0.3406 Ave 6.8
0.3241 0.3270 0.3443 0.3379
15.00.323
5Cyclohexane0.5054 0.5936 0.6027 0.5711 0.5803 Ave 5.5
0.5727 0.5790 0.6107 0.6057
15.00.580
11,1-Dichloropropene 0.3643 0.3569 0.3888 0.3678 0.3777 Ave 3.8
0.3702 0.3794 0.4007 0.3915
15.00.377
5Carbon tetrachloride 0.2506 0.2410 0.2326 0.2461 0.2504 Ave 4.6
0.2476 0.2600 0.2693 0.2647
15.00.251
4Isobutyl alcohol 0.0617 0.0571 0.0533 0.0630 0.0714 Ave 12.3
0.0672 0.0722 0.0748 0.0770
15.00.066
4Benzene1.1599 1.1341 1.0524 1.0936 1.1253 Ave 3.4
1.0948 1.1241 1.1671 1.1590
15.01.123
41,2-Dichloroethane 0.4179 0.3906 0.3974 0.3728 0.4094 Ave 3.6
0.3772 0.3886 0.4005 0.3903
15.00.393
9n-Heptane 0.6058 0.4021 0.4677 0.4082 0.4641 Ave 12.7
0.4500 0.4407 0.4764 0.4687
15.00.464
9Trichloroethene1.2234 1.2412 1.1456 1.0989 1.2197 Ave 3.8
1.1949 1.1894 1.2033 1.1590
15.01.186
12-Pentanone 0.9172 0.8576 0.8007 0.7976 0.9180 Ave 6.0
0.8413 0.8852 0.9086 0.7990
15.00.858
3Methylcyclohexane0.4342 0.4393 0.4103 0.4177 0.4263 Ave 3.3
0.4063 0.4018 0.4390 0.4271
15.00.422
51,2-Dichloropropane 0.3540 0.3068 0.2883 0.3152 0.3205 Ave 5.7
0.3077 0.3240 0.3303 0.3264
30.00.319
21,4-Dioxane 0.0148 0.0124 0.0124 0.0129 0.0144 Ave 6.7
0.0124 0.0129 0.0133 0.0128
15.00.013
1Dibromomethane0.1996 0.1817 0.1610 0.1424 0.1485 Ave 12.2
0.1477 0.1499 0.1496 0.1470
15.00.158
6Dichlorobromomethane0.2755 0.2722 0.2870 0.2822 0.3070 Ave 5.5
0.2956 0.3105 0.3137 0.3103
15.00.294
92-Chloroethyl vinyl ether 0.1253 0.2886 0.2354 0.2276 0.2471 Lin1 0.9990
0.2461 0.2541 0.2729 0.2643
0.9900-0.05
2
0.262
5cis-1,3-Dichloropropene 1.9055 1.9546 1.5293 1.9213 2.1961 Ave 10.2
2.0877 2.1303 2.1292 2.1289
15.01.998
1
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
11/15/2024
3:53:55 PM
Page 434 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672931
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_X4
98520Calibration Start Date:Calibration End Date:10/29/2024 17:11
N
10/29/2024 20:00
0.25(mm)RXI-624SilMSID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
4-Methyl-2-pentanone (MIBK)0.7955 0.7955 0.7998 0.8089 0.9686 Ave 10.8
0.8987 0.9468 0.9648 0.7121
15.00.854
5Toluene1.2194 1.1168 1.1086 1.0667 1.1553 Ave 4.2
1.1132 1.1530 1.1931 1.1812
30.01.145
3trans-1,3-Dichloropropene 0.3642 0.3565 0.3776 0.3982 0.4339 Ave 7.5
0.4063 0.4267 0.4330 0.4271
15.00.402
6Ethyl methacrylate 2.3012 1.9944 2.2159 2.1592 2.5434 Ave 8.1
2.4324 2.4684 2.4982 2.5055
15.02.346
51,1,2-Trichloroethane 0.2345 0.2200 0.2204 0.2216 0.2344 Ave 3.3
0.2208 0.2338 0.2375 0.2338
15.00.228
5Tetrachloroethene0.7727 0.7497 0.7816 0.7741 0.8602 Ave 4.9
0.8227 0.8262 0.8501 0.8415
15.00.808
81,3-Dichloropropane 2.0930 1.9806 1.9212 1.9640 2.3168 Ave 6.5
2.2056 2.1674 2.2458 2.1857
15.02.120
02-Hexanone 3.2119 3.3477 3.0898 3.1932 3.7203 Ave 7.3
3.5427 3.6209 3.7002 +++++
15.03.428
3Chlorodibromomethane0.8181 0.7966 0.7675 0.8028 0.9388 Ave 9.6
0.9379 0.9674 0.9655 0.9569
15.00.883
5Ethylene Dibromide 0.4849 0.8405 1.0918 0.9761 1.1148 Lin2 0.9960
1.0969 1.0798 1.0964 1.0791
0.9900-0.29
4
1.110
01-Chlorohexane 2.5095 1.7727 1.6827 1.5885 1.5377 Lin2 0.9960
1.5473 1.5103 1.6031 1.5586
0.99000.357
4
1.510
1Chlorobenzene3.1612 2.9316 2.7947 2.8669 3.1837 Ave 4.4
3.0538 3.0333 3.1029 3.0700
0.3000 15.03.022
01,1,1,2-Tetrachloroethane 0.9413 0.8247 0.7842 0.8634 0.7205 Ave 9.6
0.9377 0.9284 0.9476 0.9530
15.00.877
9Ethylbenzene1.8401 1.7626 1.5100 1.5919 1.7410 Ave 6.0
1.6908 1.6863 1.7892 1.7598
30.01.708
0m-Xylene & p-Xylene 0.6154 1.5317 1.9625 2.0537 2.1835 Lin2 0.9980
2.1227 2.1003 2.1608 2.1265
0.9900-0.74
8
2.192
7o-Xylene 2.0344 2.0870 1.9921 1.9612 2.0112 Ave 2.1
2.0299 2.0437 2.0993 2.0496
15.02.034
2Styrene3.5328 3.3088 3.1107 3.1409 3.4412 Ave 4.7
3.3753 3.4440 3.5309 3.4899
15.03.374
9Bromoform0.5169 0.5902 0.6068 0.5793 0.6280 Ave 8.1
0.6395 0.6571 0.6614 0.6785
0.1000 15.00.617
5
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
11/15/2024
3:53:55 PM
Page 435 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672931
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_X4
98520Calibration Start Date:Calibration End Date:10/29/2024 17:11
N
10/29/2024 20:00
0.25(mm)RXI-624SilMSID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
Isopropylbenzene 3.2317 2.8774 2.7149 2.7943 3.1218 Ave 5.6
2.9801 2.9972 3.0140 2.8057
15.02.948
6Cyclohexanone0.2768 0.2271 0.2272 0.2491 0.2940 Ave 8.8
0.2683 0.2744 0.2776 0.2641
15.00.262
01,1,2,2-Tetrachloroethane 1.0477 1.1114 1.0469 1.0606 1.2069 Ave 4.6
1.1146 1.1396 1.1156 1.1102
0.3000 15.01.106
0Bromobenzene0.7362 0.7807 0.7435 0.7088 0.7673 Ave 3.7
0.7258 0.7493 0.7393 0.6926
15.00.738
2trans-1,4-Dichloro-2-butene 0.2928 0.2417 0.2675 0.2214 0.2684 Ave 8.2
0.2742 0.2781 0.2749 0.2536
15.00.263
61,2,3-Trichloropropane 0.4342 0.3753 0.2945 0.3684 0.4156 Ave 10.2
0.3865 0.3948 0.3845 0.3729
15.00.380
8N-Propylbenzene 0.9310 0.7604 0.8251 0.8331 0.8869 Ave 5.7
0.8594 0.8571 0.8643 0.8110
15.00.847
62-Chlorotoluene 0.8815 0.7373 0.6361 0.7053 0.7596 Ave 9.2
0.7113 0.7306 0.7220 0.6787
15.00.729
21,3,5-Trimethylbenzene 2.7973 2.5990 2.2789 2.5285 2.7038 Ave 5.8
2.5603 2.6260 2.6201 2.4459
15.02.573
34-Chlorotoluene 0.9985 0.7528 0.6619 0.7289 0.7763 Ave 12.1
0.7534 0.7635 0.7488 0.7203
15.00.767
1tert-Butylbenzene 2.3651 2.2095 2.0310 1.9667 2.1990 Ave 5.8
2.0778 2.1000 2.1402 2.0085
15.02.122
01,2,4-Trimethylbenzene 3.0400 2.7287 2.5928 2.5522 2.7981 Ave 5.6
2.6372 2.7131 2.7094 2.5663
15.02.704
2sec-Butylbenzene 0.6599 0.6895 0.5615 0.6099 0.6580 Ave 6.6
0.6044 0.6081 0.6134 0.5787
15.00.620
41,3-Dichlorobenzene 1.5181 1.3922 1.4043 1.3581 1.4441 Ave 3.8
1.3808 1.3942 1.3818 1.3344
15.01.400
94-Isopropyltoluene 2.8099 2.6439 2.4139 2.4222 2.7313 Ave 5.0
2.6205 2.6352 2.6458 2.5489
15.02.608
01,4-Dichlorobenzene 1.6253 1.5397 1.4407 1.3504 1.4885 Ave 5.9
1.4103 1.4299 1.4177 1.3741
15.01.453
0n-Butylbenzene 2.7608 2.2845 2.3635 2.2744 2.5315 Ave 6.1
2.4169 2.4501 2.4796 2.3827
15.02.438
21,2-Dichlorobenzene 1.6235 1.5731 1.2737 1.3278 1.4351 Ave 8.8
1.3238 1.3527 1.3461 1.3067
15.01.395
8
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
11/15/2024
3:53:55 PM
Page 436 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672931
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_X4
98520Calibration Start Date:Calibration End Date:10/29/2024 17:11
N
10/29/2024 20:00
0.25(mm)RXI-624SilMSID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
1,2-Dibromo-3-Chloropropane 0.3651 0.3610 0.2838 0.3126 0.3547 Ave 7.9
0.3380 0.3471 0.3531 0.3218
15.00.337
51,2,4-Trichlorobenzene 0.9240 1.0433 0.8514 0.8159 0.8672 Ave 11.0
0.7974 0.7953 0.7875 0.7256
15.00.845
3Hexachlorobutadiene++++++++++0.2232 0.2782 0.3340 Lin1 0.9960
0.2873 0.2942 0.3052 0.2704
0.9900-0.00
8
0.285
7Naphthalene3.9807 3.9096 3.5118 3.2283 3.7369 Lin2 0.9950
3.1369 3.1918 3.2034 +++++
0.99000.399
6
3.295
51,2,3-Trichlorobenzene 1.0477 0.8992 0.8100 0.8157 0.9034 Lin2 0.9900
0.7304 0.7310 0.7306 0.6410
0.99000.153
9
0.746
3Dibromofluoromethane (Surr)0.2052 0.2003 0.2080 0.2042 0.2035 Ave 1.5
0.1979 0.2012 0.2001 0.2033
15.00.202
61,2-Dichloroethane-d4 (Surr)0.3109 0.3007 0.3130 0.3028 0.2944 Ave 2.0
0.3014 0.2981 0.3060 0.3069
15.00.303
8Toluene-d8 (Surr)4.6481 4.6553 4.6514 4.6553 4.7351 Ave 1.3
4.8336 4.6930 4.6890 4.7209
15.04.698
04-Bromofluorobenzene (Surr)0.9639 1.0023 0.9658 0.9716 0.9734 Ave 2.3
0.9933 0.9866 0.9915 0.9276
15.00.975
1
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
11/15/2024
3:53:55 PM
Page 437 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672931
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_X4
98520Calibration Start Date:Calibration End Date:10/29/2024 17:11
N
10/29/2024 20:00
GC Column:RXI-624SilMSID:0.25(mm)
Calibration Files:
LEVEL:LAB SAMPLE ID:LAB FILE ID:
Level 1 IC 280-672931/43 X4_00008669.D
Level 2 IC 280-672931/42 X4_00008668.D
Level 3 IC 280-672931/41 X4_00008667.D
Level 4 IC 280-672931/40 X4_00008666.D
Level 5 IC 280-672931/39 X4_00008665.D
Level 6 ICIS 280-672931/38 X4_00008664.D
Level 7 IC 280-672931/37 X4_00008663.D
Level 8 IC 280-672931/36 X4_00008662.D
Level 9 IC 280-672931/35 X4_00008661.D
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
Dichlorodifluoromethane AveFB 4215 9910 17138 47156 96142 0.500 1.00 2.00 5.00 10.0
473298 20010075.050.01904093947600638007
Chloromethane AveFB 7804 15179 27171 69091 137937 0.500 1.00 2.00 5.00 10.0
649628 20010075.050.025432031348201932877
Vinyl chloride AveFB 4825 9893 21232 49718 113220 0.500 1.00 2.00 5.00 10.0
529218 20010075.050.021540051074209763876
Bromomethane Lin2FB 4926 6305 9624 18118 39013 0.500 1.00 2.00 5.00 10.0
173587 +++++10075.050.0+++++325148252617
Chloroethane AveFB 3860 5981 14786 33971 68179 0.500 1.00 2.00 5.00 10.0
342053 20010075.050.01339157669968484443
Dichlorofluoromethane AveFB 9164 15045 28923 79465 169127 0.500 1.00 2.00 5.00 10.0
823171 20010075.050.0329977316491901154754
Trichlorofluoromethane AveFB 5601 9870 17855 49067 101512 0.500 1.00 2.00 5.00 10.0
482966 20010075.050.01995281978446669064
Ethyl ether AveFB 5849 8970 16923 39783 94634 0.500 1.00 2.00 5.00 10.0
454376 20010075.050.01733057858576665065
Acrolein Lin2FB 17066 27634 50952 128876 283996 4.94 9.88 19.8 49.4 98.8
1381732 1975988741494549461626937672068220
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
AveFB 2560 4453 9879 21974 42433 0.500 1.00 2.00 5.00 10.0
227138 20010075.050.0902180456668325401
1,1-Dichloroethene AveFB 4211 5492 13497 32732 63078 0.500 1.00 2.00 5.00 10.0
324365 20010075.050.01356117652709482268
Acetone Lin2FB ++++++++++166761 277864 534594 ++++++++++8.00 20.0 40.0
2113633 800400300200816415740260363081052
Iodomethane QuaFB ++++++++++5871 12750 30452 ++++++++++2.00 5.00 10.0
180965 +++++10075.050.0+++++460345312666
Carbon disulfide Lin2FB 19628 29383 51238 123153 255548 0.500 1.00 2.00 5.00 10.0
1237714 20010075.050.0502976724624571824251
FORM VI 8260D 11/15/2024
3:53:55 PM
Page 438 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672931
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_X4
98520Calibration Start Date:Calibration End Date:10/29/2024 17:11
N
10/29/2024 20:00
GC Column:RXI-624SilMSID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
Methyl acetate AveFB 22205 37749 74771 190423 428035 1.00 2.00 4.00 10.0 20.0
2059337 400200150100855119740385673091847
3-Chloro-1-propene AveFB 11784 18795 39421 103707 214873 0.500 1.00 2.00 5.00 10.0
1097602 20010075.050.0406504020840381598130
Methylene Chloride Lin2FB 10284 15033 22591 48664 94507 0.500 1.00 2.00 5.00 10.0
415918 20010075.050.01635397816841624724
2-Methyl-2-propanol AveFB 31880 54202 101723 247725 592354 5.00 10.0 20.0 50.0 100
2824708 200010007505001236830857434454320500
Acrylonitrile AveFB 50279 90793 183549 451934 1038532 5.00 10.0 20.0 50.0 100
4886648 200010007505001661105897070877394077
Methyl tert-butyl ether AveFB 15165 26598 55197 130516 302730 0.500 1.00 2.00 5.00 10.0
1456520 20010075.050.0588701428849302192037
trans-1,2-Dichloroethene AveFB 4276 7278 14968 37063 76879 0.500 1.00 2.00 5.00 10.0
370077 20010075.050.01500798739877539562
Hexane AveCBNZd
5
8992 13879 27071 70117 134960 0.500 1.00 2.00 5.00 10.0
732737 20010075.050.0299355214668891049591
Vinyl acetate AveFB 30453 56654 114695 277204 640960 1.00 2.00 4.00 10.0 20.0
3161048 4002001501001262543161445634532304
1,1-Dichloroethane AveFB 9122 17754 33683 79030 170885 0.500 1.00 2.00 5.00 10.0
849872 20010075.050.0342894616999361264938
2-Butanone (MEK)Lin2FB 64663 99784 148815 347796 813240 2.00 4.00 8.00 20.0 40.0
3664007 8004003002001460473172201835445767
cis-1,2-Dichloroethene AveFB 5215 8960 16121 38738 83260 0.500 1.00 2.00 5.00 10.0
410022 20010075.050.01672755808894615734
2,2-Dichloropropane AveFB 7633 11960 23811 59521 129575 0.500 1.00 2.00 5.00 10.0
633551 20010075.050.025986331263972936555
sec-Butyl Alcohol AveFB 63566 108417 220619 577307 1421493 12.0 24.0 48.0 120 240
7006037 4800240018001200232558501434629210811584
Chlorobromomethane AveFB 2021 4195 8114 16252 36724 0.500 1.00 2.00 5.00 10.0
175515 20010075.050.0672378330089263137
Tetrahydrofuran AveFB 12956 23788 44724 112650 260402 1.00 2.00 4.00 10.0 20.0
1224815 400200150100506170724119701835076
Chloroform AveFB 7378 13486 27440 61252 135155 0.500 1.00 2.00 5.00 10.0
660621 20010075.050.026648051321396986474
1,1,1-Trichloroethane AveFB 4998 11135 18924 47230 109862 0.500 1.00 2.00 5.00 10.0
538635 20010075.050.021862011071611787750
Cyclohexane AveFB 8605 18929 38569 90128 187197 0.500 1.00 2.00 5.00 10.0
951702 20010075.050.0391886219010241394756
1,1-Dichloropropene AveFB 6203 11382 24882 58037 121841 0.500 1.00 2.00 5.00 10.0
615191 20010075.050.025328361247224913943
FORM VI 8260D 11/15/2024
3:53:55 PM
Page 439 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672931
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_X4
98520Calibration Start Date:Calibration End Date:10/29/2024 17:11
N
10/29/2024 20:00
GC Column:RXI-624SilMSID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
Carbon tetrachloride AveFB 4266 7685 14886 38836 80770 0.500 1.00 2.00 5.00 10.0
411402 20010075.050.01712333838153626351
Isobutyl alcohol AveFB 26264 45554 85261 248493 575714 12.5 25.0 50.0 125 250
2792334 50002500187512501245026658234694345248
Benzene AveFB 19747 36166 67348 172584 363025 0.500 1.00 2.00 5.00 10.0
1819140 20010075.050.0749838536330652707796
1,2-Dichloroethane AveFB 7114 12458 25431 58834 132080 0.500 1.00 2.00 5.00 10.0
626843 20010075.050.025251931246587936153
n-Heptane AveFB 10314 12822 29927 64414 149731 0.500 1.00 2.00 5.00 10.0
747797 20010075.050.0303255514830341061657
Trichloroethene AveCBNZd
5
4471 8624 16187 37775 84927 0.500 1.00 2.00 5.00 10.0
421702 20010075.050.01645848830426631001
2-Pentanone AveFB 49968 87522 163973 402776 947619 1.60 3.20 6.40 16.0 32.0
4473663 6403202401601654101090505396823206
Methylcyclohexane AveFB 7393 14010 26256 65912 137523 0.500 1.00 2.00 5.00 10.0
675154 20010075.050.027633791366649967935
1,2-Dichloropropane AveFB 6027 9785 18446 49749 103385 0.500 1.00 2.00 5.00 10.0
511265 20010075.050.021114901028326780550
1,4-Dioxane AveFB 5027 7900 15903 40666 92808 10.0 20.0 40.0 100 200
412410 40002000150010001651184829447619628
Dibromomethane AveFB 3398 5793 10305 22470 47891 0.500 1.00 2.00 5.00 10.0
245435 20010075.050.0950959465548361056
Dichlorobromomethane AveFB 4690 8682 18363 44529 99034 0.500 1.00 2.00 5.00 10.0
491218 20010075.050.02007292976628748073
2-Chloroethyl vinyl ether Lin1FB 2134 9203 15064 35911 79711 0.500 1.00 2.00 5.00 10.0
408861 20010075.050.01710191849456612137
cis-1,3-Dichloropropene AveCBNZd
5
6964 13581 21608 66043 152917 0.500 1.00 2.00 5.00 10.0
736799 20010075.050.0302317714694791130219
4-Methyl-2-pentanone (MIBK)AveFB 54177 101481 204731 510599 1249853 2.00 4.00 8.00 20.0 40.0
5973506 80040030020018426676120127729122893
Toluene AveFB 20761 35616 70945 168341 372693 0.500 1.00 2.00 5.00 10.0
1849820 20010075.050.0764160937140762777478
trans-1,3-Dichloropropene AveFB 6201 11368 24165 62842 139990 0.500 1.00 2.00 5.00 10.0
675147 20010075.050.0276332013478951027973
Ethyl methacrylate AveCBNZd
5
8410 13858 31310 74219 177100 0.500 1.00 2.00 5.00 10.0
858470 20010075.050.0355803717241131309593
1,1,2-Trichloroethane AveFB 3992 7015 14102 34971 75602 0.500 1.00 2.00 5.00 10.0
366895 20010075.050.01512652739375563315
FORM VI 8260D 11/15/2024
3:53:55 PM
Page 440 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672931
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_X4
98520Calibration Start Date:Calibration End Date:10/29/2024 17:11
N
10/29/2024 20:00
GC Column:RXI-624SilMSID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
Tetrachloroethene AveCBNZd
5
2824 5209 11044 26610 59895 0.500 1.00 2.00 5.00 10.0
290339 20010075.050.01195017586723438303
1,3-Dichloropropane AveCBNZd
5
7649 13762 27146 67511 161325 0.500 1.00 2.00 5.00 10.0
778433 20010075.050.0310395415499381149882
2-Hexanone AveCBNZd5 46953 93045 174629 439057 1036190 2.00 4.00 8.00 20.0 40.0
5001332 +++++400300200+++++102147807684129
Chlorodibromomethane AveCBNZd
5
2990 5535 10844 27596 65367 0.500 1.00 2.00 5.00 10.0
331008 20010075.050.01358900666322513262
Ethylene Dibromide Lin2CBNZd
5
1772 5840 15426 33553 77627 0.500 1.00 2.00 5.00 10.0
387120 20010075.050.01532414756690572887
1-Chlorohexane Lin2CBNZd
5
7337 9854 19020 43682 85660 0.400 0.800 1.60 4.00 8.00
436861 16080.060.040.01770676885119641025
Chlorobenzene AveCBNZd
5
11553 20370 39487 98548 221685 0.500 1.00 2.00 5.00 10.0
1077782 20010075.050.0435971521414891609262
1,1,1,2-Tetrachloroethane AveCBNZd
5
3440 5730 11081 29679 50172 0.500 1.00 2.00 5.00 10.0
330938 20010075.050.01353320654019492554
Ethylbenzene AveCBNZd
5 6725 12247 21336 54719 121226 0.500 1.00 2.00 5.00 10.0
596741 20010075.050.024991331234815894664
m-Xylene & p-Xylene Lin2CBNZd5 2249 10643 27729 70594 152041 0.500 1.00 2.00 5.00 10.0
749180 20010075.050.0301982914913081114269
o-Xylene AveCBNZd
5
7435 14501 28147 67413 140039 0.500 1.00 2.00 5.00 10.0
716397 20010075.050.0291058414488321084226
Styrene AveCBNZd
5
12911 22991 43953 107964 239613 0.500 1.00 2.00 5.00 10.0
1191244 20010075.050.0495597524368431827158
Bromoform AveCBNZd
5
1889 4101 8574 19914 43726 0.500 1.00 2.00 5.00 10.0
225700 20010075.050.0963543456482348613
Isopropylbenzene AveDCBd4 17967 31341 60309 153236 335484 0.500 1.00 2.00 5.00 10.0
1626274 20010075.050.0670160033229072441355
Cyclohexanone AveCBNZd
5
30352 47330 96299 256835 614054 15.0 30.0 60.0 150 300
FORM VI 8260D 11/15/2024
3:53:55 PM
Page 441 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672931
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_X4
98520Calibration Start Date:Calibration End Date:10/29/2024 17:11
N
10/29/2024 20:00
GC Column:RXI-624SilMSID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
2840612 60003000225015001125165757469794367180
1,1,2,2-Tetrachloroethane AveDCBd4 5825 12105 23256 58165 129695 0.500 1.00 2.00 5.00 10.0
608261 20010075.050.026518501229969928203
Bromobenzene AveDCBd4 4093 8504 16516 38872 82456 0.500 1.00 2.00 5.00 10.0
396064 20010075.050.01654377815101610304
trans-1,4-Dichloro-2-butene AveDCBd4 1628 2633 5942 12144 28842 0.500 1.00 2.00 5.00 10.0
149649 20010075.050.0605722303055226533
1,2,3-Trichloropropane AveDCBd4 2414 4088 6542 20204 44662 0.500 1.00 2.00 5.00 10.0
210923 20010075.050.0890672423928321611
N-Propylbenzene AveDCBd4 5176 8282 18329 45689 95308 0.500 1.00 2.00 5.00 10.0
468954 20010075.050.01937078952871698116
2-Chlorotoluene AveDCBd4 4901 8031 14131 38676 81628 0.500 1.00 2.00 5.00 10.0
388140 20010075.050.01621004795992595138
1,3,5-Trimethylbenzene AveDCBd4 15552 28309 50623 138660 290557 0.500 1.00 2.00 5.00 10.0
1397194 20010075.050.0584219928886852138953
4-Chlorotoluene AveDCBd4 5551 8200 14704 39970 83423 0.500 1.00 2.00 5.00 10.0
411145 20010075.050.01720430825501621889
tert-Butylbenzene AveDCBd4 13149 24066 45117 107852 236317 0.500 1.00 2.00 5.00 10.0
1133850 20010075.050.0479745823595991710497
1,2,4-Trimethylbenzene AveDCBd4 16901 29721 57597 139959 300698 0.500 1.00 2.00 5.00 10.0
1439113 20010075.050.0612968329870542209900
sec-Butylbenzene AveDCBd4 3669 7510 12473 33447 70708 0.500 1.00 2.00 5.00 10.0
329825 20010075.050.01382327676290495309
1,3-Dichlorobenzene AveDCBd4 8440 15164 31196 74477 155193 0.500 1.00 2.00 5.00 10.0
753501 20010075.050.0318715315234071135601
4-Isopropyltoluene AveDCBd4 15622 28798 53621 132830 293519 0.500 1.00 2.00 5.00 10.0
1430022 20010075.050.0608820229169692146478
1,4-Dichlorobenzene AveDCBd4 9036 16771 32004 74053 159954 0.500 1.00 2.00 5.00 10.0
769605 20010075.050.0328212015630491164740
n-Butylbenzene AveDCBd4 15349 24883 52502 124725 272045 0.500 1.00 2.00 5.00 10.0
1318898 20010075.050.0569128327337661995679
1,2-Dichlorobenzene AveDCBd4 9026 17134 28293 72813 154221 0.500 1.00 2.00 5.00 10.0
722417 20010075.050.0312108614840261101843
1,2-Dibromo-3-Chloropropane AveDCBd4 2030 3932 6305 17142 38119 0.500 1.00 2.00 5.00 10.0
184469 20010075.050.0768638389337282724
1,2,4-Trichlorobenzene AveDCBd4 5137 11364 18912 44741 93190 0.500 1.00 2.00 5.00 10.0
435156 20010075.050.01733011868189647772
Hexachlorobutadiene Lin1DCBd4 ++++++++++4959 15255 35888 ++++++++++2.00 5.00 10.0
156794 20010075.050.0645811336517239618
Naphthalene Lin2DCBd4 22131 42584 78011 177039 401580 0.500 1.00 2.00 5.00 10.0
1711815 +++++10075.050.0+++++35317492599859
FORM VI 8260D 11/15/2024
3:53:55 PM
Page 442 of 777
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-198899-1 Analy Batch No.:672931
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_X4
98520Calibration Start Date:Calibration End Date:10/29/2024 17:11
N
10/29/2024 20:00
GC Column:RXI-624SilMSID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
1,2,3-Trichlorobenzene Lin2DCBd4 5825 9794 17994 44735 97079 0.500 1.00 2.00 5.00 10.0
398586 20010075.050.01530950805508595449
Dibromofluoromethane (Surr)AveFB 349334 319442 332716 322207 328263 50.0 50.0 50.0 50.0 50.0
328790 50.050.050.050.0328818311444323126
1,2-Dichloroethane-d4 (Surr)AveFB 529270 479492 500773 477924 474823 50.0 50.0 50.0 50.0 50.0
500903 50.050.050.050.0496339476342478780
Toluene-d8 (Surr)AveCBNZd
5
1698714 1617314 1643039 1600226 1648560 50.0 50.0 50.0 50.0 50.0
1705903 50.050.050.050.0167603816180731659875
4-Bromofluorobenzene (Surr)AveDCBd4 535883 545845 536380 532822 523027 50.0 50.0 50.0 50.0 50.0
542063 50.050.050.050.0553914546547535736
Curve Type Legend:
Ave = Average ISTD
Lin1 = Linear 1/conc ISTDLin2 = Linear 1/conc^2 ISTD
Qua = Quadratic ISTD
FORM VI 8260D 11/15/2024
3:53:55 PM
Page 443 of 777
Report Date: 29-Oct-2024 21:08:37 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008661.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:9
Inject. Date:29-Oct-2024 17:11:30 ALS Bottle#:2 Worklist Smp#:35
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:IC
Operator ID:CF Instrument ID:VMS_X4
Sublist:chrom-VMS_X4_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:29-Oct-2024 21:08:36 Calib Date:29-Oct-2024 20:00:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1635
First Level Reviewer: AK2J Date:29-Oct-2024 17:48:20
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.207 5.207 0.000 97 1617392 50.0 50.0
* 2 Chlorobenzene-d5 119 7.736 7.736 0.000 89 355024 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.965 9.965 0.000 95 597134 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.701 4.701 0.000 93 328818 50.0 50.2
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.966 4.966 0.000 0 496339 50.0 50.5
$ 6 Toluene-d8 (Surr) 98 6.463 6.463 0.000 95 1676038 50.0 50.2
$ 7 4-Bromofluorobenzene (Surr) 95 8.832 8.832 0.000 85 553914 50.0 47.6
9 Dichlorodifluoromethane 85 1.749 1.753 -0.004 99 1904093 200.0 206.0
10 Chloromethane 50 1.934 1.934 0.000 99 2543203 200.0 184.8
11 Vinyl chloride 62 2.039 2.034 0.004 98 2154005 200.0 206.3
12 Bromomethane 94 2.300 2.312 -0.012 89 427249 200.0 126.4
13 Chloroethane 64 2.400 2.416 -0.016 99 1339157 200.0 196.0
14 Dichlorofluoromethane 67 2.593 2.597 -0.004 97 3299773 200.0 203.8
16 Trichlorofluoromethane 101 2.625 2.633 -0.008 98 1995281 200.0 203.0
18 Ethyl ether 59 2.846 2.850 -0.004 95 1733057 200.0 190.7
19 Acrolein 56 2.958 2.962 -0.004 99 5494616 1975.0 2008.5
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.034 3.038 -0.004 95 902180 200.0 197.2
21 1,1-Dichloroethene 96 3.038 3.042 -0.004 92 1356117 200.0 204.2
22 Acetone 43 3.066 3.066 0.000 98 8164157 800.0 790.7
24 Iodomethane 142 3.167 3.167 0.000 97 984885 200.0 158.1 M
25 Carbon disulfide 76 3.227 3.231 -0.004 100 5029767 200.0 205.6
27 Methyl acetate 43 3.291 3.295 -0.004 100 8551197 400.0 419.9
28 3-Chloro-1-propene 41 3.311 3.315 -0.004 90 4065040 200.0 193.6
29 Methylene Chloride 84 3.408 3.412 -0.004 95 1635397 200.0 191.6
30 2-Methyl-2-propanol 59 3.484 3.460 0.024 99 12368308 2000.0 2175.5
31 Acrylonitrile 53 3.572 3.576 -0.004 97 16611058 2000.0 1747.5 e
32 Methyl tert-butyl ether 73 3.596 3.600 -0.004 99 5887014 200.0 205.4
33 trans-1,2-Dichloroethene 96 3.608 3.613 -0.004 92 1500798 200.0 198.6
34 Hexane 57 3.805 3.805 0.000 97 2993552 200.0 203.6
35 Vinyl acetate 43 3.910 3.910 0.000 96 12625431 400.0 417.9 e
36 1,1-Dichloroethane 63 3.934 3.934 0.000 96 3428946 200.0 200.3
11/15/2024
3:53:55 PM
Page 444 of 777
Report Date: 29-Oct-2024 21:08:37 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008661.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
40 2-Butanone (MEK) 43 4.323 4.323 0.000 98 14604731 800.0 810.3 e
42 cis-1,2-Dichloroethene 96 4.347 4.347 0.000 87 1672755 200.0 196.9
43 2,2-Dichloropropane 77 4.355 4.359 -0.004 91 2598633 200.0 203.5
45 sec-Butyl Alcohol 45 4.440 4.436 0.004 96 23255850 4800.0 4367.8 ea
47 Chlorobromomethane 128 4.524 4.524 0.000 87 672378 200.0 183.6
48 Tetrahydrofuran 42 4.536 4.536 0.000 96 5061707 400.0 415.2
49 Chloroform 83 4.580 4.584 -0.004 96 2664805 200.0 198.5
50 1,1,1-Trichloroethane 97 4.729 4.729 0.000 97 2186201 200.0 208.9
51 Cyclohexane 56 4.785 4.789 -0.004 97 3918862 200.0 208.8
52 1,1-Dichloropropene 75 4.837 4.841 -0.004 94 2532836 200.0 207.4
53 Carbon tetrachloride 117 4.845 4.849 -0.004 97 1712333 200.0 210.6
54 Isobutyl alcohol 41 4.873 4.857 0.016 92 12450266 5000.0 5795.7
55 Benzene 78 4.994 4.998 -0.004 97 7498385 200.0 206.3
56 1,2-Dichloroethane 62 5.022 5.022 0.000 96 2525193 200.0 198.2
58 n-Heptane 43 5.174 5.178 -0.004 96 3032555 200.0 201.7
60 Trichloroethene 95 5.480 5.480 0.000 97 1645848 200.0 195.4
61 2-Pentanone 43 5.580 5.584 -0.004 98 16541010 640.0 595.7 e
62 Methylcyclohexane 55 5.676 5.676 0.000 96 2763379 200.0 202.2
63 1,2-Dichloropropane 63 5.688 5.688 0.000 93 2111490 200.0 204.5
65 1,4-Dioxane 88 5.741 5.733 0.008 96 1651184 4000.0 3886.7
66 Dibromomethane 93 5.761 5.757 0.004 97 950959 200.0 185.4
67 Dichlorobromomethane 83 5.881 5.881 0.000 97 2007292 200.0 210.4
69 2-Chloroethyl vinyl ether 63 6.082 6.082 0.000 89 1710191 200.0 201.6
70 cis-1,3-Dichloropropene 75 6.230 6.230 0.000 90 3023177 200.0 213.1
71 4-Methyl-2-pentanone (MIBK) 43 6.327 6.335 -0.008 98 18426676 800.0 666.6 e
72 Toluene 91 6.524 6.524 0.000 97 7641609 200.0 206.3
73 trans-1,3-Dichloropropene 75 6.696 6.696 0.000 99 2763320 200.0 212.2
74 Ethyl methacrylate 69 6.712 6.712 0.000 98 3558037 200.0 213.5
75 1,1,2-Trichloroethane 97 6.869 6.873 -0.004 93 1512652 200.0 204.6
76 Tetrachloroethene 164 6.965 6.965 0.000 97 1195017 200.0 208.1
77 1,3-Dichloropropane 76 7.017 7.021 -0.004 98 3103954 200.0 206.2
78 2-Hexanone 43 7.030 7.038 -0.008 96 10691528 800.0 439.2 e
79 Chlorodibromomethane 129 7.214 7.214 0.000 90 1358900 200.0 216.6
80 Ethylene Dibromide 107 7.331 7.331 0.000 99 1532414 200.0 194.7
81 1-Chlorohexane 91 7.716 7.716 0.000 81 1770676 160.0 164.9
82 Chlorobenzene 112 7.764 7.764 0.000 90 4359715 200.0 203.2
83 1,1,1,2-Tetrachloroethane 131 7.833 7.833 0.000 94 1353320 200.0 217.1
84 Ethylbenzene 106 7.841 7.841 0.000 99 2499133 200.0 206.1
85 m-Xylene & p-Xylene 106 7.953 7.957 -0.004 0 3019829 200.0 194.3
86 o-Xylene 106 8.318 8.318 0.000 99 2910584 200.0 201.5
87 Styrene 104 8.335 8.334 0.000 95 4955975 200.0 206.8
88 Bromoform 173 8.515 8.515 0.000 96 963543 200.0 219.7
89 Isopropylbenzene 105 8.660 8.660 0.000 96 6701600 200.0 190.3
91 Cyclohexanone 55 8.764 8.760 0.004 99 11251657 6000.0 6047.1
92 1,1,2,2-Tetrachloroethane 83 8.945 8.945 0.000 93 2651850 200.0 200.8
93 Bromobenzene 156 8.981 8.981 0.000 96 1654377 200.0 187.7
94 trans-1,4-Dichloro-2-butene 53 8.981 8.985 -0.004 68 605722 200.0 192.4
95 1,2,3-Trichloropropane 110 9.009 9.013 -0.004 87 890672 200.0 195.9
96 N-Propylbenzene 120 9.057 9.057 0.000 100 1937078 200.0 191.4
97 2-Chlorotoluene 126 9.158 9.158 0.000 95 1621004 200.0 186.1
98 1,3,5-Trimethylbenzene 105 9.230 9.230 0.000 96 5842199 200.0 190.1
99 4-Chlorotoluene 126 9.274 9.270 0.004 99 1720430 200.0 187.8
11/15/2024
3:53:55 PM
Page 445 of 777
Report Date: 29-Oct-2024 21:08:37 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008661.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
100 tert-Butylbenzene 119 9.539 9.539 0.000 96 4797458 200.0 189.3
102 1,2,4-Trimethylbenzene 105 9.599 9.599 0.000 98 6129683 200.0 189.8
103 sec-Butylbenzene 134 9.760 9.760 0.000 95 1382327 200.0 186.6
104 1,3-Dichlorobenzene 146 9.888 9.888 0.000 97 3187153 200.0 190.5
105 4-Isopropyltoluene 119 9.904 9.904 0.000 98 6088202 200.0 195.5
106 1,4-Dichlorobenzene 146 9.989 9.985 0.004 94 3282120 200.0 189.1
108 n-Butylbenzene 91 10.310 10.310 0.000 99 5691283 200.0 195.4
109 1,2-Dichlorobenzene 146 10.346 10.346 0.000 96 3121086 200.0 187.2
110 1,2-Dibromo-3-Chloropropane 157 11.125 11.125 0.000 76 768638 200.0 190.7
112 1,2,4-Trichlorobenzene 180 11.948 11.948 0.000 93 1733011 200.0 171.7
113 Hexachlorobutadiene 225 12.089 12.089 0.000 95 645811 200.0 189.3
114 Naphthalene 128 12.221 12.221 0.000 97 6814879 200.0 173.0
115 1,2,3-Trichlorobenzene 180 12.442 12.442 0.000 94 1530950 200.0 171.6
S 122 1,2-Dichloroethene, Total (URS) 96 0 400.0 395.5
S 129 1,2-Dichloroethene, Total 1 0 400.0 395.5
S 123 Xylenes, Total (URS) 1 0 400.0 395.8
S 127 Trihalomethanes, Total 1 0 800.0 845.3
S 125 Xylenes, Total 106 0 400.0 395.8
S 126 Total BTEX 1 0 1014.5
S 124 1,3-Dichloropropene, Total 1 0 400.0 425.3
QC Flag Legend
Processing Flags
e - Potential Peak Saturated
Review Flags
M - Manually Integrated
a - User Assigned ID
Reagents:
MV-MegaMainA_00117 Amount Added: 100.00 Units: uL
MV-Gas A_00200 Amount Added: 40.00 Units: uL
mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 446 of 777
Report Date: 29-Oct-2024 21:08:37 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008661.D
Injection Date:29-Oct-2024 17:11:30 Instrument ID:VMS_X4 Operator ID:CF
Lims ID:ic Worklist Smp#:35
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:2
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0
Min
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X4_00008661[MS SCAN Chro]:Total

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11/15/2024
3:53:55 PM
Page 447 of 777
Report Date: 29-Oct-2024 21:08:37 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008661.D
Injection Date:29-Oct-2024 17:11:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:2 Worklist Smp#:35
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
24 Iodomethane, CAS: 74-88-4
Signal: 1
Processing Integration Results
RT: 3.17
Area: 1016740
Amount: 206.0421
Amount Units: ug/l
2.8 3.0 3.2 3.4
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
52
Y ( X
1
0
0
0
0
)
m/z 142.0

3
.
1
6
7
Manual Integration Results
RT: 3.17
Area: 984885
Amount: 158.1278
Amount Units: ug/l
2.8 3.0 3.2 3.4
Min
RT
-1
3
7
11
15
19
23
27
31
35
39
43
47
51
Y ( X
1
0
0
0
0
)
m/z 142.0

3
.
1
6
7
Reviewer: AK2J, 29-Oct-2024 20:52:40 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 448 of 777
Report Date: 29-Oct-2024 21:08:37 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008661.D
Injection Date:29-Oct-2024 17:11:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:2 Worklist Smp#:35
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
45 sec-Butyl Alcohol, CAS: 78-92-2
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 4.44
4.1 4.3 4.5 4.7 4.9
Min
0
6
12
18
24
30
36
42
48
54
60
66
72
78
84
Y ( X
1
0
0
0
0
0
)
m/z 45.0
Manual Integration Results
RT: 4.44
Area: 23255850
Amount: 4367.7982
Amount Units: ug/l
4.1 4.3 4.5 4.7 4.9
Min
RT
0
6
12
18
24
30
36
42
48
54
60
66
72
78
84
Y ( X
1
0
0
0
0
0
)
m/z 45.0

4
.
4
4
0
Reviewer: AK2J, 29-Oct-2024 17:40:18 -06:00:00 (UTC)
Audit Action: Assigned Compound ID Audit Reason: Peak assignment corrected
11/15/2024
3:53:55 PM
Page 449 of 777
Report Date: 29-Oct-2024 21:08:39 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008662.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:8
Inject. Date:29-Oct-2024 17:32:30 ALS Bottle#:3 Worklist Smp#:36
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:IC
Operator ID:CF Instrument ID:VMS_X4
Sublist:chrom-VMS_X4_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:29-Oct-2024 21:08:38 Calib Date:29-Oct-2024 20:00:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1635
First Level Reviewer: AK2J Date:29-Oct-2024 20:49:13
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.206 5.207 -0.001 98 1556436 50.0 50.0
* 2 Chlorobenzene-d5 119 7.736 7.736 0.000 89 345076 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.965 9.965 0.000 96 551245 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.701 4.701 0.000 93 311444 50.0 49.4
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.962 4.966 -0.004 0 476342 50.0 50.4
$ 6 Toluene-d8 (Surr) 98 6.463 6.463 0.000 95 1618073 50.0 49.9
$ 7 4-Bromofluorobenzene (Surr) 95 8.832 8.832 0.000 84 546547 50.0 50.8
9 Dichlorodifluoromethane 85 1.749 1.753 -0.004 99 947600 100.0 106.5
10 Chloromethane 50 1.934 1.934 0.000 99 1348201 100.0 101.8
11 Vinyl chloride 62 2.034 2.034 0.000 98 1074209 100.0 106.9
12 Bromomethane 94 2.307 2.312 -0.005 91 325148 100.0 99.8
13 Chloroethane 64 2.412 2.416 -0.004 99 669968 100.0 101.9
14 Dichlorofluoromethane 67 2.593 2.597 -0.004 97 1649190 100.0 105.9
16 Trichlorofluoromethane 101 2.629 2.633 -0.004 98 978446 100.0 103.5
18 Ethyl ether 59 2.845 2.850 -0.005 95 858576 100.0 98.2
19 Acrolein 56 2.958 2.962 -0.004 99 2693767 987.5 1022.8
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.038 3.038 0.000 96 456668 100.0 103.7
21 1,1-Dichloroethene 96 3.042 3.042 0.000 91 652709 100.0 102.1
22 Acetone 43 3.062 3.066 -0.004 98 4026036 400.0 401.0
24 Iodomethane 142 3.167 3.167 0.000 97 460345 100.0 99.9 M
25 Carbon disulfide 76 3.227 3.231 -0.004 100 2462457 100.0 104.5
27 Methyl acetate 43 3.291 3.295 -0.004 100 4038567 200.0 206.1
28 3-Chloro-1-propene 41 3.315 3.315 0.000 90 2084038 100.0 103.1
29 Methylene Chloride 84 3.412 3.412 0.000 95 816841 100.0 99.1
30 2-Methyl-2-propanol 59 3.464 3.460 0.004 98 5743445 1000.0 1049.8
31 Acrylonitrile 53 3.576 3.576 0.000 99 9707087 1000.0 1061.2
32 Methyl tert-butyl ether 73 3.596 3.600 -0.004 98 2884930 100.0 104.6
33 trans-1,2-Dichloroethene 96 3.612 3.613 0.000 92 739877 100.0 101.7
34 Hexane 57 3.805 3.805 0.000 97 1466889 100.0 102.6
35 Vinyl acetate 43 3.910 3.910 0.000 96 6144563 200.0 211.4
36 1,1-Dichloroethane 63 3.934 3.934 0.000 96 1699936 100.0 103.2
11/15/2024
3:53:55 PM
Page 450 of 777
Report Date: 29-Oct-2024 21:08:39 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008662.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
40 2-Butanone (MEK) 43 4.323 4.323 0.000 98 7220183 400.0 415.6
42 cis-1,2-Dichloroethene 96 4.347 4.347 0.000 88 808894 100.0 98.9
43 2,2-Dichloropropane 77 4.359 4.359 0.000 92 1263972 100.0 102.9
45 sec-Butyl Alcohol 45 4.440 4.436 0.004 100 14346292 2400.0 2800.0
47 Chlorobromomethane 128 4.524 4.524 0.000 87 330089 100.0 93.7
48 Tetrahydrofuran 42 4.536 4.536 0.000 96 2411970 200.0 205.6
49 Chloroform 83 4.584 4.584 0.000 96 1321396 100.0 102.3
50 1,1,1-Trichloroethane 97 4.729 4.729 0.000 96 1071611 100.0 106.4
51 Cyclohexane 56 4.789 4.789 0.000 96 1901024 100.0 105.3
52 1,1-Dichloropropene 75 4.841 4.841 0.000 91 1247224 100.0 106.1
53 Carbon tetrachloride 117 4.845 4.849 -0.004 96 838153 100.0 107.1
54 Isobutyl alcohol 41 4.857 4.857 0.000 96 5823469 2500.0 2817.0
55 Benzene 78 4.994 4.998 -0.004 98 3633065 100.0 103.9
56 1,2-Dichloroethane 62 5.022 5.022 0.000 96 1246587 100.0 101.7
58 n-Heptane 43 5.174 5.178 -0.004 98 1483034 100.0 102.5
60 Trichloroethene 95 5.484 5.480 0.004 97 830426 100.0 101.4
61 2-Pentanone 43 5.584 5.584 0.000 97 9050539 320.0 338.7
62 Methylcyclohexane 55 5.676 5.676 0.000 96 1366649 100.0 103.9
63 1,2-Dichloropropane 63 5.688 5.688 0.000 93 1028326 100.0 103.5
65 1,4-Dioxane 88 5.737 5.733 0.003 96 829447 2000.0 2028.9
66 Dibromomethane 93 5.761 5.757 0.004 96 465548 100.0 94.3
67 Dichlorobromomethane 83 5.881 5.881 0.000 97 976628 100.0 106.4
69 2-Chloroethyl vinyl ether 63 6.082 6.082 0.000 90 849456 100.0 104.2
70 cis-1,3-Dichloropropene 75 6.230 6.230 0.000 91 1469479 100.0 106.6
71 4-Methyl-2-pentanone (MIBK) 43 6.335 6.335 0.000 98 12012772 400.0 451.6
72 Toluene 91 6.524 6.524 0.000 97 3714076 100.0 104.2
73 trans-1,3-Dichloropropene 75 6.696 6.696 0.000 99 1347895 100.0 107.5
74 Ethyl methacrylate 69 6.712 6.712 0.000 97 1724113 100.0 106.5
75 1,1,2-Trichloroethane 97 6.869 6.873 -0.004 93 739375 100.0 103.9
76 Tetrachloroethene 164 6.965 6.965 0.000 97 586723 100.0 105.1
77 1,3-Dichloropropane 76 7.017 7.021 -0.004 99 1549938 100.0 105.9
78 2-Hexanone 43 7.037 7.038 -0.001 99 10214780 400.0 431.7
79 Chlorodibromomethane 129 7.210 7.214 -0.004 90 666322 100.0 109.3
80 Ethylene Dibromide 107 7.331 7.331 0.000 99 756690 100.0 99.0
81 1-Chlorohexane 91 7.720 7.716 0.004 80 885119 80.0 84.7
82 Chlorobenzene 112 7.764 7.764 0.000 90 2141489 100.0 102.7
83 1,1,1,2-Tetrachloroethane 131 7.837 7.833 0.003 93 654019 100.0 107.9
84 Ethylbenzene 106 7.841 7.841 0.000 99 1234815 100.0 104.8
85 m-Xylene & p-Xylene 106 7.957 7.957 0.000 0 1491308 100.0 98.9
86 o-Xylene 106 8.318 8.318 0.000 98 1448832 100.0 103.2
87 Styrene 104 8.334 8.334 0.000 95 2436843 100.0 104.6
88 Bromoform 173 8.515 8.515 0.000 95 456482 100.0 107.1
89 Isopropylbenzene 105 8.660 8.660 0.000 97 3322907 100.0 102.2
91 Cyclohexanone 55 8.760 8.760 0.000 99 5746979 3000.0 3177.7
92 1,1,2,2-Tetrachloroethane 83 8.945 8.945 0.000 94 1229969 100.0 100.9
93 Bromobenzene 156 8.981 8.981 0.000 96 815101 100.0 100.2
94 trans-1,4-Dichloro-2-butene 53 8.981 8.985 -0.004 59 303055 100.0 104.3
95 1,2,3-Trichloropropane 110 9.009 9.013 -0.004 86 423928 100.0 101.0
96 N-Propylbenzene 120 9.057 9.057 0.000 100 952871 100.0 102.0
97 2-Chlorotoluene 126 9.158 9.158 0.000 95 795992 100.0 99.0
98 1,3,5-Trimethylbenzene 105 9.230 9.230 0.000 95 2888685 100.0 101.8
99 4-Chlorotoluene 126 9.274 9.270 0.004 99 825501 100.0 97.6
11/15/2024
3:53:55 PM
Page 451 of 777
Report Date: 29-Oct-2024 21:08:39 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008662.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
100 tert-Butylbenzene 119 9.539 9.539 0.000 96 2359599 100.0 100.9
102 1,2,4-Trimethylbenzene 105 9.599 9.599 0.000 98 2987054 100.0 100.2
103 sec-Butylbenzene 134 9.760 9.760 0.000 95 676290 100.0 98.9
104 1,3-Dichlorobenzene 146 9.888 9.888 0.000 97 1523407 100.0 98.6
105 4-Isopropyltoluene 119 9.904 9.904 0.000 98 2916969 100.0 101.5
106 1,4-Dichlorobenzene 146 9.985 9.985 0.000 92 1563049 100.0 97.6
108 n-Butylbenzene 91 10.310 10.310 0.000 99 2733766 100.0 101.7
109 1,2-Dichlorobenzene 146 10.346 10.346 0.000 96 1484026 100.0 96.4
110 1,2-Dibromo-3-Chloropropane 157 11.125 11.125 0.000 75 389337 100.0 104.6
112 1,2,4-Trichlorobenzene 180 11.948 11.948 0.000 93 868189 100.0 93.2
113 Hexachlorobutadiene 225 12.089 12.089 0.000 95 336517 100.0 106.9
114 Naphthalene 128 12.221 12.221 0.000 97 3531749 100.0 97.1
115 1,2,3-Trichlorobenzene 180 12.442 12.442 0.000 92 805508 100.0 97.7
S 122 1,2-Dichloroethene, Total (URS) 96 0 200.0 200.7
S 129 1,2-Dichloroethene, Total 1 0 200.0 200.7
S 123 Xylenes, Total (URS) 1 0 200.0 202.1
S 127 Trihalomethanes, Total 1 0 400.0 425.1
S 125 Xylenes, Total 106 0 200.0 202.1
S 126 Total BTEX 1 0 514.9
S 124 1,3-Dichloropropene, Total 1 0 200.0 214.1
QC Flag Legend
Processing Flags
Review Flags
M - Manually Integrated
Reagents:
MV-MegaMainA_00117 Amount Added: 50.00 Units: uL
MV-Gas A_00200 Amount Added: 20.00 Units: uL
mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 452 of 777
Report Date: 29-Oct-2024 21:08:39 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008662.D
Injection Date:29-Oct-2024 17:32:30 Instrument ID:VMS_X4 Operator ID:CF
Lims ID:ic Worklist Smp#:36
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:3
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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X4_00008662[MS SCAN Chro]:Total

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11/15/2024
3:53:55 PM
Page 453 of 777
Report Date: 29-Oct-2024 21:08:39 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008662.D
Injection Date:29-Oct-2024 17:32:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:3 Worklist Smp#:36
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
24 Iodomethane, CAS: 74-88-4
Signal: 1
Processing Integration Results
RT: 3.17
Area: 486688
Amount: 103.6283
Amount Units: ug/l
2.8 3.0 3.2 3.4
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
Y ( X
1
0
0
0
0
)
m/z 142.0

3
.
1
6
7
Manual Integration Results
RT: 3.17
Area: 460345
Amount: 99.927388
Amount Units: ug/l
2.8 3.0 3.2 3.4
Min
RT
-1
1
3
5
7
9
11
13
15
17
19
21
23
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Y ( X
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0
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)
m/z 142.0

3
.
1
6
7
Reviewer: AK2J, 29-Oct-2024 20:51:55 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 454 of 777
Report Date: 29-Oct-2024 21:08:40 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008663.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:7
Inject. Date:29-Oct-2024 17:53:30 ALS Bottle#:4 Worklist Smp#:37
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:IC
Operator ID:CF Instrument ID:VMS_X4
Sublist:chrom-VMS_X4_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:29-Oct-2024 21:08:40 Calib Date:29-Oct-2024 20:00:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1635
First Level Reviewer: AK2J Date:29-Oct-2024 20:38:53
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.206 5.207 -0.001 98 1605924 50.0 50.0
* 2 Chlorobenzene-d5 119 7.736 7.736 0.000 89 353689 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.965 9.965 0.000 96 543023 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.701 4.701 0.000 93 323126 50.0 49.6
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.966 4.966 0.000 0 478780 50.0 49.1
$ 6 Toluene-d8 (Surr) 98 6.463 6.463 0.000 95 1659875 50.0 49.9
$ 7 4-Bromofluorobenzene (Surr) 95 8.832 8.832 0.000 86 535736 50.0 50.6
9 Dichlorodifluoromethane 85 1.749 1.753 -0.004 99 638007 75.0 69.5
10 Chloromethane 50 1.934 1.934 0.000 99 932877 75.0 68.3
11 Vinyl chloride 62 2.038 2.034 0.004 97 763876 75.0 73.7
12 Bromomethane 94 2.311 2.312 -0.001 90 252617 75.0 74.9
13 Chloroethane 64 2.412 2.416 -0.004 99 484443 75.0 71.4
14 Dichlorofluoromethane 67 2.597 2.597 0.000 97 1154754 75.0 71.8
16 Trichlorofluoromethane 101 2.629 2.633 -0.004 98 669064 75.0 68.6
18 Ethyl ether 59 2.845 2.850 -0.005 95 665065 75.0 73.7
19 Acrolein 56 2.958 2.962 -0.004 99 2068220 740.6 760.9
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.038 3.038 0.000 95 325401 75.0 71.6
21 1,1-Dichloroethene 96 3.042 3.042 0.000 92 482268 75.0 73.1
22 Acetone 43 3.066 3.066 0.000 98 3081052 300.0 295.2
24 Iodomethane 142 3.167 3.167 0.000 97 312666 75.0 75.3 M
25 Carbon disulfide 76 3.231 3.231 0.000 100 1824251 75.0 75.0
27 Methyl acetate 43 3.291 3.295 -0.004 100 3091847 150.0 152.9
28 3-Chloro-1-propene 41 3.315 3.315 0.000 90 1598130 75.0 76.6
29 Methylene Chloride 84 3.412 3.412 0.000 96 624724 75.0 73.3
30 2-Methyl-2-propanol 59 3.460 3.460 0.000 99 4320500 750.0 765.4
31 Acrylonitrile 53 3.576 3.576 0.000 99 7394077 750.0 783.4
32 Methyl tert-butyl ether 73 3.600 3.600 0.000 98 2192037 75.0 77.0
33 trans-1,2-Dichloroethene 96 3.612 3.613 0.000 91 539562 75.0 71.9
34 Hexane 57 3.805 3.805 0.000 97 1049591 75.0 71.6
35 Vinyl acetate 43 3.910 3.910 0.000 96 4532304 150.0 151.1
36 1,1-Dichloroethane 63 3.934 3.934 0.000 96 1264938 75.0 74.4
11/15/2024
3:53:55 PM
Page 455 of 777
Report Date: 29-Oct-2024 21:08:40 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008663.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
40 2-Butanone (MEK) 43 4.323 4.323 0.000 98 5445767 300.0 303.4
42 cis-1,2-Dichloroethene 96 4.347 4.347 0.000 88 615734 75.0 73.0
43 2,2-Dichloropropane 77 4.359 4.359 0.000 91 936555 75.0 73.9
45 sec-Butyl Alcohol 45 4.436 4.436 0.000 100 10811584 1800.0 2045.1
47 Chlorobromomethane 128 4.528 4.524 0.004 87 263137 75.0 72.4
48 Tetrahydrofuran 42 4.536 4.536 0.000 96 1835076 150.0 151.6
49 Chloroform 83 4.584 4.584 0.000 96 986474 75.0 74.0
50 1,1,1-Trichloroethane 97 4.729 4.729 0.000 96 787750 75.0 75.8
51 Cyclohexane 56 4.789 4.789 0.000 97 1394756 75.0 74.9
52 1,1-Dichloropropene 75 4.841 4.841 0.000 90 913943 75.0 75.4
53 Carbon tetrachloride 117 4.849 4.849 0.000 95 626351 75.0 77.6
54 Isobutyl alcohol 41 4.857 4.857 0.000 96 4345248 1875.0 2037.2
55 Benzene 78 4.994 4.998 -0.004 98 2707796 75.0 75.0
56 1,2-Dichloroethane 62 5.022 5.022 0.000 96 936153 75.0 74.0
58 n-Heptane 43 5.174 5.178 -0.004 98 1061657 75.0 71.1
60 Trichloroethene 95 5.484 5.480 0.004 96 631001 75.0 75.2
61 2-Pentanone 43 5.588 5.584 0.004 97 6823206 240.0 247.5
62 Methylcyclohexane 55 5.680 5.676 0.004 96 967935 75.0 71.3
63 1,2-Dichloropropane 63 5.692 5.688 0.004 93 780550 75.0 76.1
65 1,4-Dioxane 88 5.732 5.733 -0.001 97 619628 1500.0 1469.0
66 Dibromomethane 93 5.761 5.757 0.004 96 361056 75.0 70.9
67 Dichlorobromomethane 83 5.885 5.881 0.004 97 748073 75.0 79.0
69 2-Chloroethyl vinyl ether 63 6.086 6.082 0.004 90 612137 75.0 72.8
70 cis-1,3-Dichloropropene 75 6.234 6.230 0.004 90 1130219 75.0 80.0
71 4-Methyl-2-pentanone (MIBK) 43 6.335 6.335 0.000 98 9122893 300.0 332.4
72 Toluene 91 6.524 6.524 0.000 97 2777478 75.0 75.5
73 trans-1,3-Dichloropropene 75 6.696 6.696 0.000 99 1027973 75.0 79.5
74 Ethyl methacrylate 69 6.712 6.712 0.000 98 1309593 75.0 78.9
75 1,1,2-Trichloroethane 97 6.869 6.873 -0.004 93 563315 75.0 76.7
76 Tetrachloroethene 164 6.965 6.965 0.000 97 438303 75.0 76.6
77 1,3-Dichloropropane 76 7.017 7.021 -0.004 98 1149882 75.0 76.7
78 2-Hexanone 43 7.037 7.038 -0.001 99 7684129 300.0 316.9
79 Chlorodibromomethane 129 7.210 7.214 -0.004 90 513262 75.0 82.1
80 Ethylene Dibromide 107 7.331 7.331 0.000 99 572887 75.0 73.2
81 1-Chlorohexane 91 7.720 7.716 0.004 81 641025 60.0 59.8
82 Chlorobenzene 112 7.764 7.764 0.000 91 1609262 75.0 75.3
83 1,1,1,2-Tetrachloroethane 131 7.833 7.833 -0.001 94 492554 75.0 79.3
84 Ethylbenzene 106 7.841 7.841 0.000 99 894664 75.0 74.1
85 m-Xylene & p-Xylene 106 7.957 7.957 0.000 0 1114269 75.0 72.2
86 o-Xylene 106 8.318 8.318 0.000 98 1084226 75.0 75.3
87 Styrene 104 8.334 8.334 0.000 95 1827158 75.0 76.5
88 Bromoform 173 8.515 8.515 0.000 96 348613 75.0 79.8
89 Isopropylbenzene 105 8.660 8.660 0.000 97 2441355 75.0 76.2
91 Cyclohexanone 55 8.760 8.760 0.000 99 4367180 2250.0 2356.0
92 1,1,2,2-Tetrachloroethane 83 8.945 8.945 0.000 93 928203 75.0 77.3
93 Bromobenzene 156 8.981 8.981 0.000 96 610304 75.0 76.1
94 trans-1,4-Dichloro-2-butene 53 8.985 8.985 0.000 60 226533 75.0 79.1
95 1,2,3-Trichloropropane 110 9.009 9.013 -0.004 87 321611 75.0 77.8
96 N-Propylbenzene 120 9.057 9.057 0.000 100 698116 75.0 75.8
97 2-Chlorotoluene 126 9.158 9.158 0.000 95 595138 75.0 75.2
98 1,3,5-Trimethylbenzene 105 9.230 9.230 0.000 95 2138953 75.0 76.5
99 4-Chlorotoluene 126 9.274 9.270 0.004 99 621889 75.0 74.6
11/15/2024
3:53:55 PM
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Report Date: 29-Oct-2024 21:08:40 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008663.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
100 tert-Butylbenzene 119 9.543 9.539 0.004 96 1710497 75.0 74.2
102 1,2,4-Trimethylbenzene 105 9.599 9.599 0.000 98 2209900 75.0 75.2
103 sec-Butylbenzene 134 9.760 9.760 0.000 95 495309 75.0 73.5
104 1,3-Dichlorobenzene 146 9.888 9.888 0.000 97 1135601 75.0 74.6
105 4-Isopropyltoluene 119 9.904 9.904 0.000 98 2146478 75.0 75.8
106 1,4-Dichlorobenzene 146 9.989 9.985 0.004 93 1164740 75.0 73.8
108 n-Butylbenzene 91 10.310 10.310 0.000 99 1995679 75.0 75.4
109 1,2-Dichlorobenzene 146 10.350 10.346 0.004 96 1101843 75.0 72.7
110 1,2-Dibromo-3-Chloropropane 157 11.125 11.125 0.000 74 282724 75.0 77.1
112 1,2,4-Trichlorobenzene 180 11.948 11.948 0.000 93 647772 75.0 70.6
113 Hexachlorobutadiene 225 12.089 12.089 0.000 96 239618 75.0 77.3
114 Naphthalene 128 12.221 12.221 0.000 97 2599859 75.0 72.5
115 1,2,3-Trichlorobenzene 180 12.442 12.442 0.000 93 595449 75.0 73.3
S 122 1,2-Dichloroethene, Total (URS) 96 0 150.0 144.9
S 129 1,2-Dichloroethene, Total 1 0 150.0 144.9
S 123 Xylenes, Total (URS) 1 0 150.0 147.5
S 127 Trihalomethanes, Total 1 0 300.0 314.9
S 125 Xylenes, Total 106 0 150.0 147.5
S 126 Total BTEX 1 0 372.1
S 124 1,3-Dichloropropene, Total 1 0 150.0 159.5
QC Flag Legend
Processing Flags
Review Flags
M - Manually Integrated
Reagents:
MV-MegaMainA_00117 Amount Added: 37.50 Units: uL
MV-Gas A_00200 Amount Added: 15.00 Units: uL
mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 457 of 777
Report Date: 29-Oct-2024 21:08:40 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008663.D
Injection Date:29-Oct-2024 17:53:30 Instrument ID:VMS_X4 Operator ID:CF
Lims ID:ic Worklist Smp#:37
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:4
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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X4_00008663[MS SCAN Chro]:Total

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11/15/2024
3:53:55 PM
Page 458 of 777
Report Date: 29-Oct-2024 21:08:41 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008663.D
Injection Date:29-Oct-2024 17:53:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:4 Worklist Smp#:37
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
24 Iodomethane, CAS: 74-88-4
Signal: 1
Processing Integration Results
RT: 3.17
Area: 314558
Amount: 66.370457
Amount Units: ug/l
2.8 3.0 3.2 3.4
Min
0
2
4
6
8
10
12
14
16
Y ( X
1
0
0
0
0
)
m/z 142.0

3
.
1
6
7
Manual Integration Results
RT: 3.17
Area: 312666
Amount: 75.308337
Amount Units: ug/l
2.8 3.0 3.2 3.4
Min
RT
-1
1
3
5
7
9
11
13
15
17
Y ( X
1
0
0
0
0
)
m/z 142.0

3
.
1
6
7
Reviewer: AK2J, 29-Oct-2024 20:51:23 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 459 of 777
Report Date: 29-Oct-2024 21:08:35 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008664.D
Lims ID:icis
Client ID:
Sample Type:ICIS Calib Level:6
Inject. Date:29-Oct-2024 18:14:30 ALS Bottle#:5 Worklist Smp#:38
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ICIS
Operator ID:CF Instrument ID:VMS_X4
Sublist:chrom-VMS_X4_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:29-Oct-2024 21:08:34 Calib Date:29-Oct-2024 20:00:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1635
First Level Reviewer: AK2J Date:29-Oct-2024 21:08:34
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.207 5.207 0.000 98 1661687 50.0 50.0
* 2 Chlorobenzene-d5 119 7.736 7.736 0.000 90 352929 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.965 9.965 0.000 96 545705 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.701 4.701 0.000 93 328790 50.0 48.8
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.966 4.966 0.000 0 500903 50.0 49.6
$ 6 Toluene-d8 (Surr) 98 6.463 6.463 0.000 95 1705903 50.0 51.4
$ 7 4-Bromofluorobenzene (Surr) 95 8.832 8.832 0.000 86 542063 50.0 50.9
9 Dichlorodifluoromethane 85 1.753 1.753 0.000 99 473298 50.0 49.8
10 Chloromethane 50 1.934 1.934 0.000 99 649628 50.0 45.9
11 Vinyl chloride 62 2.034 2.034 0.000 98 529218 50.0 49.3
12 Bromomethane 94 2.312 2.312 0.000 91 173587 50.0 49.5
13 Chloroethane 64 2.416 2.416 0.000 99 342053 50.0 48.7
14 Dichlorofluoromethane 67 2.597 2.597 0.000 96 823171 50.0 49.5
16 Trichlorofluoromethane 101 2.633 2.633 0.000 97 482966 50.0 47.8
18 Ethyl ether 59 2.850 2.850 0.000 96 454376 50.0 48.7
19 Acrolein 56 2.962 2.962 0.000 99 1381732 493.8 491.0
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.038 3.038 0.000 96 227138 50.0 48.3
21 1,1-Dichloroethene 96 3.042 3.042 0.000 93 324365 50.0 47.5
22 Acetone 43 3.066 3.066 0.000 98 2113633 200.0 192.9
24 Iodomethane 142 3.167 3.167 0.000 97 180965 50.0 49.5 M
25 Carbon disulfide 76 3.231 3.231 0.000 100 1237714 50.0 49.1
27 Methyl acetate 43 3.295 3.295 0.000 100 2059337 100.0 98.4
28 3-Chloro-1-propene 41 3.315 3.315 0.000 90 1097602 50.0 50.9
29 Methylene Chloride 84 3.412 3.412 0.000 95 415918 50.0 46.9
30 2-Methyl-2-propanol 59 3.460 3.460 0.000 98 2824708 500.0 483.6
31 Acrylonitrile 53 3.576 3.576 0.000 99 4886648 500.0 500.4
32 Methyl tert-butyl ether 73 3.600 3.600 0.000 98 1456520 50.0 49.5
33 trans-1,2-Dichloroethene 96 3.613 3.613 0.000 93 370077 50.0 47.7
34 Hexane 57 3.805 3.805 0.000 97 732737 50.0 50.1
35 Vinyl acetate 43 3.910 3.910 0.000 96 3161048 100.0 101.8
36 1,1-Dichloroethane 63 3.934 3.934 0.000 96 849872 50.0 48.3
11/15/2024
3:53:55 PM
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Report Date: 29-Oct-2024 21:08:35 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008664.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
40 2-Butanone (MEK) 43 4.323 4.323 0.000 98 3664007 200.0 196.8
42 cis-1,2-Dichloroethene 96 4.347 4.347 0.000 88 410022 50.0 47.0
43 2,2-Dichloropropane 77 4.359 4.359 0.000 91 633551 50.0 48.3
45 sec-Butyl Alcohol 45 4.436 4.436 0.000 100 7006037 1200.0 1280.8
47 Chlorobromomethane 128 4.524 4.524 0.000 88 175515 50.0 46.7
48 Tetrahydrofuran 42 4.536 4.536 0.000 96 1224815 100.0 97.8
49 Chloroform 83 4.584 4.584 0.000 96 660621 50.0 47.9
50 1,1,1-Trichloroethane 97 4.729 4.729 0.000 96 538635 50.0 50.1
51 Cyclohexane 56 4.789 4.789 0.000 97 951702 50.0 49.4
52 1,1-Dichloropropene 75 4.841 4.841 0.000 92 615191 50.0 49.0
53 Carbon tetrachloride 117 4.849 4.849 0.000 93 411402 50.0 49.3
54 Isobutyl alcohol 41 4.857 4.857 0.000 95 2792334 1250.0 1265.2
55 Benzene 78 4.998 4.998 0.000 98 1819140 50.0 48.7
56 1,2-Dichloroethane 62 5.022 5.022 0.000 96 626843 50.0 47.9
58 n-Heptane 43 5.178 5.178 0.000 97 747797 50.0 48.4
60 Trichloroethene 95 5.480 5.480 0.000 97 421702 50.0 50.4
61 2-Pentanone 43 5.584 5.584 0.000 97 4473663 160.0 156.8
62 Methylcyclohexane 55 5.676 5.676 0.000 96 675154 50.0 48.1
63 1,2-Dichloropropane 63 5.688 5.688 0.000 92 511265 50.0 48.2
65 1,4-Dioxane 88 5.733 5.733 0.000 96 412410 1000.0 944.9
66 Dibromomethane 93 5.757 5.757 0.000 94 245435 50.0 46.6
67 Dichlorobromomethane 83 5.881 5.881 0.000 98 491218 50.0 50.1
69 2-Chloroethyl vinyl ether 63 6.082 6.082 0.000 90 408861 50.0 47.1
70 cis-1,3-Dichloropropene 75 6.230 6.230 0.000 90 736799 50.0 52.2
71 4-Methyl-2-pentanone (MIBK) 43 6.335 6.335 0.000 97 5973506 200.0 210.3
72 Toluene 91 6.524 6.524 0.000 97 1849820 50.0 48.6
73 trans-1,3-Dichloropropene 75 6.696 6.696 0.000 99 675147 50.0 50.5
74 Ethyl methacrylate 69 6.712 6.712 0.000 98 858470 50.0 51.8
75 1,1,2-Trichloroethane 97 6.873 6.873 0.000 93 366895 50.0 48.3
76 Tetrachloroethene 164 6.965 6.965 0.000 96 290339 50.0 50.9
77 1,3-Dichloropropane 76 7.021 7.021 0.000 99 778433 50.0 52.0
78 2-Hexanone 43 7.038 7.038 0.000 99 5001332 200.0 206.7
79 Chlorodibromomethane 129 7.214 7.214 0.000 91 331008 50.0 53.1
80 Ethylene Dibromide 107 7.331 7.331 0.000 98 387120 50.0 49.7
81 1-Chlorohexane 91 7.716 7.716 0.000 82 436861 40.0 40.7
82 Chlorobenzene 112 7.764 7.764 0.000 91 1077782 50.0 50.5
83 1,1,1,2-Tetrachloroethane 131 7.833 7.833 0.000 93 330938 50.0 53.4
84 Ethylbenzene 106 7.841 7.841 0.000 99 596741 50.0 49.5
85 m-Xylene & p-Xylene 106 7.957 7.957 0.000 0 749180 50.0 48.7
86 o-Xylene 106 8.318 8.318 0.000 98 716397 50.0 49.9
87 Styrene 104 8.334 8.334 0.000 94 1191244 50.0 50.0
88 Bromoform 173 8.515 8.515 0.000 95 225700 50.0 51.8
89 Isopropylbenzene 105 8.660 8.660 0.000 97 1626274 50.0 50.5
91 Cyclohexanone 55 8.760 8.760 0.000 99 2840612 1500.0 1535.7
92 1,1,2,2-Tetrachloroethane 83 8.945 8.945 0.000 95 608261 50.0 50.4
93 Bromobenzene 156 8.981 8.981 0.000 95 396064 50.0 49.2
94 trans-1,4-Dichloro-2-butene 53 8.985 8.985 0.000 63 149649 50.0 52.0
95 1,2,3-Trichloropropane 110 9.013 9.013 0.000 86 210923 50.0 50.8
96 N-Propylbenzene 120 9.057 9.057 0.000 100 468954 50.0 50.7
97 2-Chlorotoluene 126 9.158 9.158 0.000 95 388140 50.0 48.8
98 1,3,5-Trimethylbenzene 105 9.230 9.230 0.000 96 1397194 50.0 49.7
99 4-Chlorotoluene 126 9.270 9.270 0.000 99 411145 50.0 49.1
11/15/2024
3:53:55 PM
Page 461 of 777
Report Date: 29-Oct-2024 21:08:35 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008664.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
100 tert-Butylbenzene 119 9.539 9.539 0.000 96 1133850 50.0 49.0
102 1,2,4-Trimethylbenzene 105 9.599 9.599 0.000 99 1439113 50.0 48.8
103 sec-Butylbenzene 134 9.760 9.760 0.000 95 329825 50.0 48.7
104 1,3-Dichlorobenzene 146 9.888 9.888 0.000 97 753501 50.0 49.3
105 4-Isopropyltoluene 119 9.904 9.904 0.000 98 1430022 50.0 50.2
106 1,4-Dichlorobenzene 146 9.985 9.985 0.000 94 769605 50.0 48.5
108 n-Butylbenzene 91 10.310 10.310 0.000 99 1318898 50.0 49.6
109 1,2-Dichlorobenzene 146 10.346 10.346 0.000 96 722417 50.0 47.4
110 1,2-Dibromo-3-Chloropropane 157 11.125 11.125 0.000 74 184469 50.0 50.1
112 1,2,4-Trichlorobenzene 180 11.948 11.948 0.000 93 435156 50.0 47.2
113 Hexachlorobutadiene 225 12.089 12.089 0.000 94 156794 50.0 50.3
114 Naphthalene 128 12.221 12.221 0.000 97 1711815 50.0 47.5
115 1,2,3-Trichlorobenzene 180 12.442 12.442 0.000 94 398586 50.0 48.7
S 122 1,2-Dichloroethene, Total (URS) 96 0 100.0 94.6
S 129 1,2-Dichloroethene, Total 1 0 100.0 94.6
S 123 Xylenes, Total (URS) 1 0 100.0 98.6
S 127 Trihalomethanes, Total 1 0 200.0 202.9
S 125 Xylenes, Total 106 0 100.0 98.6
S 124 1,3-Dichloropropene, Total 1 0 100.0 102.7
QC Flag Legend
Processing Flags
Review Flags
M - Manually Integrated
Reagents:
MV-MegaMainA_00117 Amount Added: 25.00 Units: uL
MV-Gas A_00200 Amount Added: 10.00 Units: uL
mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 462 of 777
Report Date: 29-Oct-2024 21:08:35 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008664.D
Injection Date:29-Oct-2024 18:14:30 Instrument ID:VMS_X4 Operator ID:CF
Lims ID:icis Worklist Smp#:38
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:5
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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11/15/2024
3:53:55 PM
Page 463 of 777
Report Date: 29-Oct-2024 21:08:35 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008664.D
Injection Date:29-Oct-2024 18:14:30 Instrument ID:VMS_X4
Lims ID:icis
Client ID:
Operator ID:CF ALS Bottle#:5 Worklist Smp#:38
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
24 Iodomethane, CAS: 74-88-4
Signal: 1
Processing Integration Results
RT: 3.17
Area: 178801
Amount: 38.306198
Amount Units: ug/l
2.8 3.0 3.2 3.4
Min
0
1
2
3
4
5
6
7
8
9
10
11
Y ( X
1
0
0
0
0
)
m/z 142.0

3
.
1
6
7
Manual Integration Results
RT: 3.17
Area: 180965
Amount: 49.542345
Amount Units: ug/l
2.8 3.0 3.2 3.4
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
Y ( X
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)
m/z 142.0

3
.
1
6
7
Reviewer: AK2J, 29-Oct-2024 20:51:01 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 464 of 777
Report Date: 29-Oct-2024 21:08:42 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008665.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:5
Inject. Date:29-Oct-2024 18:35:30 ALS Bottle#:6 Worklist Smp#:39
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:IC
Operator ID:CF Instrument ID:VMS_X4
Sublist:chrom-VMS_X4_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:29-Oct-2024 21:08:42 Calib Date:29-Oct-2024 20:00:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1635
First Level Reviewer: AK2J Date:29-Oct-2024 21:04:18
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.207 5.207 0.000 97 1612993 50.0 50.0
* 2 Chlorobenzene-d5 119 7.736 7.736 0.000 91 348156 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.961 9.961 0.000 97 537317 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.701 4.701 0.000 93 328263 50.0 50.2
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.966 4.966 0.000 0 474823 50.0 48.4
$ 6 Toluene-d8 (Surr) 98 6.463 6.463 0.000 95 1648560 50.0 50.4
$ 7 4-Bromofluorobenzene (Surr) 95 8.832 8.832 0.000 86 523027 50.0 49.9
9 Dichlorodifluoromethane 85 1.753 1.753 0.000 99 96142 10.0 10.4
10 Chloromethane 50 1.938 1.938 0.000 99 137937 10.0 10.1
11 Vinyl chloride 62 2.039 2.039 0.000 98 113220 10.0 10.9
12 Bromomethane 94 2.320 2.320 0.000 90 39013 10.0 10.8
13 Chloroethane 64 2.420 2.420 0.000 98 68179 10.0 10.0
14 Dichlorofluoromethane 67 2.597 2.597 0.000 97 169127 10.0 10.5
16 Trichlorofluoromethane 101 2.629 2.629 0.000 97 101512 10.0 10.4
18 Ethyl ether 59 2.846 2.846 0.000 98 94634 10.0 10.4
19 Acrolein 56 2.962 2.962 0.000 99 283996 98.8 103.4
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.038 3.038 0.000 61 42433 10.0 9.30
21 1,1-Dichloroethene 96 3.046 3.046 0.000 92 63078 10.0 9.52
22 Acetone 43 3.066 3.066 0.000 99 534594 40.0 43.9
24 Iodomethane 142 3.171 3.171 0.000 96 30452 10.0 11.1 M
25 Carbon disulfide 76 3.227 3.227 0.000 100 255548 10.0 10.2
27 Methyl acetate 43 3.291 3.291 0.000 100 428035 20.0 21.1
28 3-Chloro-1-propene 41 3.315 3.315 0.000 89 214873 10.0 10.3
29 Methylene Chloride 84 3.416 3.416 0.000 96 94507 10.0 10.5
30 2-Methyl-2-propanol 59 3.456 3.456 0.000 99 592354 100.0 104.5
31 Acrylonitrile 53 3.576 3.576 0.000 99 1038532 100.0 109.5
32 Methyl tert-butyl ether 73 3.596 3.596 0.000 99 302730 10.0 10.6
33 trans-1,2-Dichloroethene 96 3.617 3.617 0.000 92 76879 10.0 10.2
34 Hexane 57 3.809 3.809 0.000 95 134960 10.0 9.36
35 Vinyl acetate 43 3.910 3.910 0.000 98 640960 20.0 21.3
36 1,1-Dichloroethane 63 3.938 3.938 0.000 96 170885 10.0 10.0
11/15/2024
3:53:55 PM
Page 465 of 777
Report Date: 29-Oct-2024 21:08:42 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008665.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
40 2-Butanone (MEK) 43 4.323 4.323 0.000 98 813240 40.0 43.9
42 cis-1,2-Dichloroethene 96 4.351 4.351 0.000 85 83260 10.0 9.83
43 2,2-Dichloropropane 77 4.363 4.363 0.000 90 129575 10.0 10.2
45 sec-Butyl Alcohol 45 4.432 4.432 0.000 100 1421493 240.0 267.7
47 Chlorobromomethane 128 4.524 4.524 0.000 86 36724 10.0 10.1
48 Tetrahydrofuran 42 4.536 4.536 0.000 96 260402 20.0 21.4
49 Chloroform 83 4.584 4.584 0.000 96 135155 10.0 10.1
50 1,1,1-Trichloroethane 97 4.729 4.729 0.000 96 109862 10.0 10.5
51 Cyclohexane 56 4.789 4.789 0.000 95 187197 10.0 10.0
52 1,1-Dichloropropene 75 4.841 4.841 0.000 87 121841 10.0 10.0
53 Carbon tetrachloride 117 4.845 4.845 0.000 55 80770 10.0 9.96
54 Isobutyl alcohol 41 4.849 4.849 0.000 94 575714 250.0 268.7
55 Benzene 78 4.994 4.994 0.000 97 363025 10.0 10.0
56 1,2-Dichloroethane 62 5.026 5.026 0.000 96 132080 10.0 10.4
58 n-Heptane 43 5.174 5.174 0.000 95 149731 10.0 9.98
60 Trichloroethene 95 5.480 5.480 0.000 94 84927 10.0 10.3
61 2-Pentanone 43 5.588 5.588 0.000 98 947619 32.0 34.2
62 Methylcyclohexane 55 5.676 5.676 0.000 97 137523 10.0 10.1
63 1,2-Dichloropropane 63 5.692 5.692 0.000 95 103385 10.0 10.0
65 1,4-Dioxane 88 5.737 5.737 0.000 99 92808 200.0 219.1
66 Dibromomethane 93 5.761 5.761 0.000 97 47891 10.0 9.36
67 Dichlorobromomethane 83 5.885 5.885 0.000 98 99034 10.0 10.4
69 2-Chloroethyl vinyl ether 63 6.082 6.082 0.000 90 79711 10.0 9.61
70 cis-1,3-Dichloropropene 75 6.235 6.235 0.000 90 152917 10.0 11.0
71 4-Methyl-2-pentanone (MIBK) 43 6.335 6.335 0.000 98 1249853 40.0 45.3
72 Toluene 91 6.524 6.524 0.000 96 372693 10.0 10.1
73 trans-1,3-Dichloropropene 75 6.696 6.696 0.000 97 139990 10.0 10.8
74 Ethyl methacrylate 69 6.712 6.712 0.000 97 177100 10.0 10.8
75 1,1,2-Trichloroethane 97 6.873 6.873 0.000 91 75602 10.0 10.3
76 Tetrachloroethene 164 6.965 6.965 0.000 94 59895 10.0 10.6
77 1,3-Dichloropropane 76 7.018 7.018 0.000 99 161325 10.0 10.9
78 2-Hexanone 43 7.038 7.038 0.000 99 1036190 40.0 43.4
79 Chlorodibromomethane 129 7.210 7.210 0.000 89 65367 10.0 10.6
80 Ethylene Dibromide 107 7.335 7.335 0.000 99 77627 10.0 10.3
81 1-Chlorohexane 91 7.720 7.720 0.000 79 85660 8.00 7.91
82 Chlorobenzene 112 7.764 7.764 0.000 91 221685 10.0 10.5
83 1,1,1,2-Tetrachloroethane 131 7.837 7.837 0.000 42 50172 10.0 8.21
84 Ethylbenzene 106 7.841 7.841 0.000 99 121226 10.0 10.2
85 m-Xylene & p-Xylene 106 7.957 7.957 0.000 0 152041 10.0 10.3
86 o-Xylene 106 8.318 8.318 0.000 98 140039 10.0 9.89
87 Styrene 104 8.335 8.335 0.000 94 239613 10.0 10.2
88 Bromoform 173 8.511 8.511 0.000 94 43726 10.0 10.2
89 Isopropylbenzene 105 8.656 8.656 0.000 97 335484 10.0 10.6
91 Cyclohexanone 55 8.756 8.756 0.000 98 614054 300.0 336.5
92 1,1,2,2-Tetrachloroethane 83 8.945 8.945 0.000 94 129695 10.0 10.9
93 Bromobenzene 156 8.981 8.981 0.000 96 82456 10.0 10.4
94 trans-1,4-Dichloro-2-butene 53 8.985 8.985 0.000 48 28842 10.0 10.2
95 1,2,3-Trichloropropane 110 9.009 9.009 0.000 86 44662 10.0 10.9
96 N-Propylbenzene 120 9.057 9.057 0.000 100 95308 10.0 10.5
97 2-Chlorotoluene 126 9.158 9.158 0.000 95 81628 10.0 10.4
98 1,3,5-Trimethylbenzene 105 9.230 9.230 0.000 95 290557 10.0 10.5
99 4-Chlorotoluene 126 9.274 9.274 0.000 99 83423 10.0 10.1
11/15/2024
3:53:55 PM
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Report Date: 29-Oct-2024 21:08:42 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008665.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
100 tert-Butylbenzene 119 9.539 9.539 0.000 96 236317 10.0 10.4
102 1,2,4-Trimethylbenzene 105 9.599 9.599 0.000 98 300698 10.0 10.3
103 sec-Butylbenzene 134 9.756 9.756 0.000 95 70708 10.0 10.6
104 1,3-Dichlorobenzene 146 9.888 9.888 0.000 97 155193 10.0 10.3
105 4-Isopropyltoluene 119 9.901 9.901 0.000 98 293519 10.0 10.5
106 1,4-Dichlorobenzene 146 9.989 9.989 0.000 95 159954 10.0 10.2
108 n-Butylbenzene 91 10.310 10.310 0.000 99 272045 10.0 10.4
109 1,2-Dichlorobenzene 146 10.346 10.346 0.000 94 154221 10.0 10.3
110 1,2-Dibromo-3-Chloropropane 157 11.125 11.125 0.000 73 38119 10.0 10.5
112 1,2,4-Trichlorobenzene 180 11.948 11.948 0.000 92 93190 10.0 10.3
113 Hexachlorobutadiene 225 12.089 12.089 0.000 95 35888 10.0 11.7
114 Naphthalene 128 12.221 12.221 0.000 97 401580 10.0 11.2
115 1,2,3-Trichlorobenzene 180 12.442 12.442 0.000 94 97079 10.0 11.9
S 122 1,2-Dichloroethene, Total (URS) 96 0 20.0 20.0
S 129 1,2-Dichloroethene, Total 1 0 20.0 20.0
S 123 Xylenes, Total (URS) 1 0 20.0 20.2
S 127 Trihalomethanes, Total 1 0 40.0 41.3
S 125 Xylenes, Total 106 0 20.0 20.2
S 126 Total BTEX 1 0 50.5
S 124 1,3-Dichloropropene, Total 1 0 20.0 21.8
QC Flag Legend
Processing Flags
Review Flags
M - Manually Integrated
Reagents:
MV-MegaMainA_00117 Amount Added: 5.00 Units: uL
MV-Gas A_00200 Amount Added: 2.00 Units: uL
mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 467 of 777
Report Date: 29-Oct-2024 21:08:42 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008665.D
Injection Date:29-Oct-2024 18:35:30 Instrument ID:VMS_X4 Operator ID:CF
Lims ID:ic Worklist Smp#:39
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:6
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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X4_00008665[MS SCAN Chro]:Total

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11/15/2024
3:53:55 PM
Page 468 of 777
Report Date: 29-Oct-2024 21:08:42 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008665.D
Injection Date:29-Oct-2024 18:35:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:6 Worklist Smp#:39
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
24 Iodomethane, CAS: 74-88-4
Signal: 1
Processing Integration Results
RT: 3.17
Area: 28241
Amount: 9.682578
Amount Units: ug/l
2.8 3.0 3.2 3.4
Min
0
2
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10
12
14
16
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Y ( X
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Manual Integration Results
RT: 3.17
Area: 30452
Amount: 11.079497
Amount Units: ug/l
2.8 3.0 3.2 3.4
Min
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Reviewer: AK2J, 29-Oct-2024 20:50:41 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 469 of 777
Report Date: 29-Oct-2024 21:08:44 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008666.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:4
Inject. Date:29-Oct-2024 18:56:30 ALS Bottle#:7 Worklist Smp#:40
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:IC
Operator ID:CF Instrument ID:VMS_X4
Sublist:chrom-VMS_X4_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:29-Oct-2024 21:08:44 Calib Date:29-Oct-2024 20:00:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1635
First Level Reviewer: AK2J Date:29-Oct-2024 19:46:26
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.206 5.207 -0.001 97 1578144 50.0 50.0
* 2 Chlorobenzene-d5 119 7.740 7.736 0.004 91 343741 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.961 9.961 0.000 97 548393 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.701 4.701 0.000 93 322207 50.0 50.4
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.962 4.966 -0.004 0 477924 50.0 49.8
$ 6 Toluene-d8 (Surr) 98 6.463 6.463 0.000 95 1600226 50.0 49.5
$ 7 4-Bromofluorobenzene (Surr) 95 8.828 8.832 -0.004 85 532822 50.0 49.8
9 Dichlorodifluoromethane 85 1.749 1.753 -0.004 98 47156 5.00 5.23
10 Chloromethane 50 1.934 1.938 -0.004 98 69091 5.00 5.15
11 Vinyl chloride 62 2.034 2.039 -0.005 98 49718 5.00 4.88
12 Bromomethane 94 2.303 2.320 -0.017 90 18118 5.00 4.64
13 Chloroethane 64 2.408 2.420 -0.012 98 33971 5.00 5.10
14 Dichlorofluoromethane 67 2.593 2.597 -0.005 98 79465 5.00 5.03
16 Trichlorofluoromethane 101 2.629 2.629 0.000 97 49067 5.00 5.12
18 Ethyl ether 59 2.845 2.846 -0.001 91 39783 5.00 4.49
19 Acrolein 56 2.962 2.962 0.000 99 128876 49.4 47.5
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.042 3.038 0.004 67 21974 5.00 4.92
21 1,1-Dichloroethene 96 3.038 3.046 -0.008 96 32732 5.00 5.05
22 Acetone 43 3.062 3.066 -0.004 98 277864 20.0 19.3
24 Iodomethane 142 3.163 3.171 -0.008 75 12750 5.00 4.52
25 Carbon disulfide 76 3.231 3.227 0.004 100 123153 5.00 4.92
27 Methyl acetate 43 3.291 3.291 0.000 100 190423 10.0 9.58
28 3-Chloro-1-propene 41 3.315 3.315 0.000 89 103707 5.00 5.06
29 Methylene Chloride 84 3.412 3.416 -0.004 97 48664 5.00 5.18
30 2-Methyl-2-propanol 59 3.460 3.456 0.004 98 247725 50.0 44.7
31 Acrylonitrile 53 3.576 3.576 0.000 99 451934 50.0 48.7
32 Methyl tert-butyl ether 73 3.600 3.596 0.004 99 130516 5.00 4.67
33 trans-1,2-Dichloroethene 96 3.608 3.617 -0.009 93 37063 5.00 5.03
34 Hexane 57 3.809 3.809 0.000 97 70117 5.00 4.92
35 Vinyl acetate 43 3.910 3.910 0.000 97 277204 10.0 9.40
36 1,1-Dichloroethane 63 3.934 3.938 -0.004 94 79030 5.00 4.73
11/15/2024
3:53:55 PM
Page 470 of 777
Report Date: 29-Oct-2024 21:08:44 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008666.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
40 2-Butanone (MEK) 43 4.323 4.323 0.000 99 347796 20.0 18.4
42 cis-1,2-Dichloroethene 96 4.343 4.351 -0.008 86 38738 5.00 4.67
43 2,2-Dichloropropane 77 4.355 4.363 -0.008 91 59521 5.00 4.78
45 sec-Butyl Alcohol 45 4.432 4.432 0.000 100 577307 120.0 111.1
47 Chlorobromomethane 128 4.524 4.524 0.000 85 16252 5.00 4.55
48 Tetrahydrofuran 42 4.536 4.536 0.000 96 112650 10.0 9.47
49 Chloroform 83 4.580 4.584 -0.004 95 61252 5.00 4.68
50 1,1,1-Trichloroethane 97 4.729 4.729 0.000 96 47230 5.00 4.63
51 Cyclohexane 56 4.789 4.789 0.000 96 90128 5.00 4.92
52 1,1-Dichloropropene 75 4.837 4.841 -0.004 79 58037 5.00 4.87
53 Carbon tetrachloride 117 4.845 4.845 0.000 60 38836 5.00 4.90
54 Isobutyl alcohol 41 4.853 4.849 0.004 96 248493 125.0 118.6
55 Benzene 78 4.998 4.994 0.004 97 172584 5.00 4.87
56 1,2-Dichloroethane 62 5.022 5.026 -0.004 94 58834 5.00 4.73
58 n-Heptane 43 5.174 5.174 0.000 95 64414 5.00 4.39
60 Trichloroethene 95 5.480 5.480 0.000 92 37775 5.00 4.63
61 2-Pentanone 43 5.588 5.588 0.000 97 402776 16.0 14.9
62 Methylcyclohexane 55 5.676 5.676 0.000 89 65912 5.00 4.94
63 1,2-Dichloropropane 63 5.692 5.692 0.000 83 49749 5.00 4.94
65 1,4-Dioxane 88 5.728 5.737 -0.009 97 40666 100.0 98.1
66 Dibromomethane 93 5.761 5.761 0.000 94 22470 5.00 4.49
67 Dichlorobromomethane 83 5.877 5.885 -0.008 95 44529 5.00 4.78
69 2-Chloroethyl vinyl ether 63 6.086 6.082 0.004 89 35911 5.00 4.53
70 cis-1,3-Dichloropropene 75 6.234 6.235 -0.001 91 66043 5.00 4.81
71 4-Methyl-2-pentanone (MIBK) 43 6.335 6.335 0.000 98 510599 20.0 18.9
72 Toluene 91 6.523 6.524 -0.001 97 168341 5.00 4.66
73 trans-1,3-Dichloropropene 75 6.696 6.696 0.000 97 62842 5.00 4.95
74 Ethyl methacrylate 69 6.716 6.712 0.004 98 74219 5.00 4.60
75 1,1,2-Trichloroethane 97 6.869 6.873 -0.004 90 34971 5.00 4.85
76 Tetrachloroethene 164 6.965 6.965 0.000 93 26610 5.00 4.79
77 1,3-Dichloropropane 76 7.021 7.018 0.003 96 67511 5.00 4.63
78 2-Hexanone 43 7.037 7.038 -0.001 99 439057 20.0 18.6
79 Chlorodibromomethane 129 7.206 7.210 -0.004 94 27596 5.00 4.54
80 Ethylene Dibromide 107 7.335 7.335 0.000 100 33553 5.00 4.66
81 1-Chlorohexane 91 7.724 7.720 0.004 85 43682 4.00 3.97
82 Chlorobenzene 112 7.768 7.764 0.004 91 98548 5.00 4.74
83 1,1,1,2-Tetrachloroethane 131 7.832 7.837 -0.005 41 29679 5.00 4.92
84 Ethylbenzene 106 7.836 7.841 -0.005 99 54719 5.00 4.66
85 m-Xylene & p-Xylene 106 7.953 7.957 -0.004 0 70594 5.00 5.02
86 o-Xylene 106 8.314 8.318 -0.004 97 67413 5.00 4.82
87 Styrene 104 8.334 8.335 -0.001 93 107964 5.00 4.65
88 Bromoform 173 8.515 8.511 0.004 95 19914 5.00 4.69
89 Isopropylbenzene 105 8.656 8.656 0.000 97 153236 5.00 4.74
91 Cyclohexanone 55 8.760 8.756 0.004 98 256835 150.0 142.6
92 1,1,2,2-Tetrachloroethane 83 8.945 8.945 0.000 95 58165 5.00 4.80
93 Bromobenzene 156 8.977 8.981 -0.004 96 38872 5.00 4.80 M
94 trans-1,4-Dichloro-2-butene 53 8.981 8.985 -0.004 53 12144 5.00 4.20
95 1,2,3-Trichloropropane 110 9.009 9.009 0.000 87 20204 5.00 4.84
96 N-Propylbenzene 120 9.057 9.057 0.000 99 45689 5.00 4.91
97 2-Chlorotoluene 126 9.154 9.158 -0.004 95 38676 5.00 4.84
98 1,3,5-Trimethylbenzene 105 9.226 9.230 -0.004 94 138660 5.00 4.91
99 4-Chlorotoluene 126 9.278 9.274 0.004 98 39970 5.00 4.75
11/15/2024
3:53:55 PM
Page 471 of 777
Report Date: 29-Oct-2024 21:08:44 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008666.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
100 tert-Butylbenzene 119 9.539 9.539 0.000 96 107852 5.00 4.63
102 1,2,4-Trimethylbenzene 105 9.595 9.599 -0.004 98 139959 5.00 4.72
103 sec-Butylbenzene 134 9.760 9.756 0.004 94 33447 5.00 4.92
104 1,3-Dichlorobenzene 146 9.888 9.888 0.000 96 74477 5.00 4.85
105 4-Isopropyltoluene 119 9.904 9.901 0.004 98 132830 5.00 4.64
106 1,4-Dichlorobenzene 146 9.981 9.989 -0.008 91 74053 5.00 4.65 M
108 n-Butylbenzene 91 10.310 10.310 0.000 99 124725 5.00 4.66
109 1,2-Dichlorobenzene 146 10.350 10.346 0.004 94 72813 5.00 4.76
110 1,2-Dibromo-3-Chloropropane 157 11.125 11.125 0.000 75 17142 5.00 4.63
112 1,2,4-Trichlorobenzene 180 11.952 11.948 0.004 92 44741 5.00 4.83
113 Hexachlorobutadiene 225 12.089 12.089 0.000 93 15255 5.00 4.90
114 Naphthalene 128 12.217 12.221 -0.004 97 177039 5.00 4.78
115 1,2,3-Trichlorobenzene 180 12.438 12.442 -0.004 94 44735 5.00 5.26
S 122 1,2-Dichloroethene, Total (URS) 96 0 10.0 9.70
S 129 1,2-Dichloroethene, Total 1 0 10.0 9.70
S 123 Xylenes, Total (URS) 1 0 10.0 9.84
S 127 Trihalomethanes, Total 1 0 20.0 18.7
S 125 Xylenes, Total 106 0 10.0 9.84
S 126 Total BTEX 1 0 24.0
S 124 1,3-Dichloropropene, Total 1 0 10.0 9.75
QC Flag Legend
Processing Flags
Review Flags
M - Manually Integrated
Reagents:
MV-MegaMainA_00117 Amount Added: 2.50 Units: uL
MV-Gas A_00200 Amount Added: 1.00 Units: uL
mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 472 of 777
Report Date: 29-Oct-2024 21:08:44 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008666.D
Injection Date:29-Oct-2024 18:56:30 Instrument ID:VMS_X4 Operator ID:CF
Lims ID:ic Worklist Smp#:40
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:7
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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11/15/2024
3:53:55 PM
Page 473 of 777
Report Date: 29-Oct-2024 21:08:44 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008666.D
Injection Date:29-Oct-2024 18:56:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:7 Worklist Smp#:40
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
93 Bromobenzene, CAS: 108-86-1
Signal: 1
Processing Integration Results
RT: 8.98
Area: 20380
Amount: 2.542189
Amount Units: ug/l
8.6 8.8 9.0 9.2
Min
0
2
4
6
8
10
12
14
16
18
20
22
Y ( X
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m/z 156.0

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9
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Manual Integration Results
RT: 8.98
Area: 38872
Amount: 4.801254
Amount Units: ug/l
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Min
RT
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Reviewer: AK2J, 29-Oct-2024 19:45:57 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 474 of 777
Report Date: 29-Oct-2024 21:08:44 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008666.D
Injection Date:29-Oct-2024 18:56:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:7 Worklist Smp#:40
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
106 1,4-Dichlorobenzene, CAS: 106-46-7
Signal: 1
Processing Integration Results
RT: 9.98
Area: 37457
Amount: 2.354229
Amount Units: ug/l
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Min
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Manual Integration Results
RT: 9.98
Area: 74053
Amount: 4.646931
Amount Units: ug/l
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Reviewer: AK2J, 29-Oct-2024 19:46:05 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 475 of 777
Report Date: 29-Oct-2024 21:08:46 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008667.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:3
Inject. Date:29-Oct-2024 19:17:30 ALS Bottle#:8 Worklist Smp#:41
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:IC
Operator ID:CF Instrument ID:VMS_X4
Sublist:chrom-VMS_X4_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:29-Oct-2024 21:08:46 Calib Date:29-Oct-2024 20:00:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1635
First Level Reviewer: AK2J Date:29-Oct-2024 19:41:40
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.206 5.207 -0.001 97 1599819 50.0 50.0
* 2 Chlorobenzene-d5 119 7.740 7.736 0.004 91 353236 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.965 9.961 0.004 97 555347 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.700 4.701 -0.001 92 332716 50.0 51.3
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.965 4.966 -0.001 0 500773 50.0 51.5
$ 6 Toluene-d8 (Surr) 98 6.467 6.463 0.004 95 1643039 50.0 49.5
$ 7 4-Bromofluorobenzene (Surr) 95 8.832 8.832 0.000 85 536380 50.0 49.5
9 Dichlorodifluoromethane 85 1.749 1.753 -0.004 97 17138 2.00 1.87
10 Chloromethane 50 1.934 1.938 -0.004 99 27171 2.00 2.00
11 Vinyl chloride 62 2.034 2.039 -0.005 96 21232 2.00 2.06
12 Bromomethane 94 2.315 2.320 -0.005 88 9624 2.00 2.00
13 Chloroethane 64 2.416 2.420 -0.004 96 14786 2.00 2.19 M
14 Dichlorofluoromethane 67 2.596 2.597 -0.001 95 28923 2.00 1.81 M
16 Trichlorofluoromethane 101 2.633 2.629 0.004 98 17855 2.00 1.84
18 Ethyl ether 59 2.849 2.846 0.003 94 16923 2.00 1.88
19 Acrolein 56 2.958 2.962 -0.004 98 50952 19.8 18.1
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.046 3.038 0.008 68 9879 2.00 2.18
21 1,1-Dichloroethene 96 3.038 3.046 -0.008 92 13497 2.00 2.05 M
22 Acetone 43 3.066 3.066 0.000 98 166761 8.00 7.96
24 Iodomethane 142 3.167 3.171 -0.004 91 5871 2.00 1.59 M
25 Carbon disulfide 76 3.231 3.227 0.004 100 51238 2.00 1.87
27 Methyl acetate 43 3.295 3.291 0.004 100 74771 4.00 3.71
28 3-Chloro-1-propene 41 3.315 3.315 0.000 91 39421 2.00 1.90
29 Methylene Chloride 84 3.408 3.416 -0.008 93 22591 2.00 2.01
30 2-Methyl-2-propanol 59 3.460 3.456 0.004 99 101723 20.0 18.1
31 Acrylonitrile 53 3.576 3.576 0.000 99 183549 20.0 19.5
32 Methyl tert-butyl ether 73 3.600 3.596 0.004 98 55197 2.00 1.95
33 trans-1,2-Dichloroethene 96 3.608 3.617 -0.009 90 14968 2.00 2.00
34 Hexane 57 3.805 3.809 -0.004 95 27071 2.00 1.85
35 Vinyl acetate 43 3.909 3.910 -0.001 97 114695 4.00 3.84
36 1,1-Dichloroethane 63 3.934 3.938 -0.004 95 33683 2.00 1.99
11/15/2024
3:53:55 PM
Page 476 of 777
Report Date: 29-Oct-2024 21:08:46 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008667.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
40 2-Butanone (MEK) 43 4.327 4.323 0.004 99 148815 8.00 6.96
42 cis-1,2-Dichloroethene 96 4.347 4.351 -0.004 75 16121 2.00 1.92
43 2,2-Dichloropropane 77 4.363 4.363 0.000 83 23811 2.00 1.89
45 sec-Butyl Alcohol 45 4.431 4.432 -0.001 99 220619 48.0 41.9
47 Chlorobromomethane 128 4.520 4.524 -0.004 92 8114 2.00 2.24
48 Tetrahydrofuran 42 4.540 4.536 0.004 95 44724 4.00 3.71
49 Chloroform 83 4.580 4.584 -0.004 95 27440 2.00 2.07
50 1,1,1-Trichloroethane 97 4.733 4.729 0.004 89 18924 2.00 1.83 M
51 Cyclohexane 56 4.789 4.789 0.000 91 38569 2.00 2.08
52 1,1-Dichloropropene 75 4.841 4.841 0.000 83 24882 2.00 2.06
53 Carbon tetrachloride 117 4.853 4.845 0.008 58 14886 2.00 1.85
54 Isobutyl alcohol 41 4.853 4.849 0.004 98 85261 50.0 40.1
55 Benzene 78 4.998 4.994 0.004 97 67348 2.00 1.87
56 1,2-Dichloroethane 62 5.018 5.026 -0.008 96 25431 2.00 2.02
58 n-Heptane 43 5.174 5.174 0.000 91 29927 2.00 2.01
60 Trichloroethene 95 5.483 5.480 0.003 93 16187 2.00 1.93
61 2-Pentanone 43 5.588 5.588 0.000 97 163973 6.40 5.97
62 Methylcyclohexane 55 5.676 5.676 0.000 92 26256 2.00 1.94
63 1,2-Dichloropropane 63 5.692 5.692 0.000 85 18446 2.00 1.81 M
65 1,4-Dioxane 88 5.732 5.737 -0.005 90 15903 40.0 37.8
66 Dibromomethane 93 5.765 5.761 0.004 92 10305 2.00 2.03
67 Dichlorobromomethane 83 5.889 5.885 0.004 96 18363 2.00 1.95
69 2-Chloroethyl vinyl ether 63 6.086 6.082 0.004 93 15064 2.00 1.99
70 cis-1,3-Dichloropropene 75 6.234 6.235 -0.001 90 21608 2.00 1.53
71 4-Methyl-2-pentanone (MIBK) 43 6.339 6.335 0.004 97 204731 8.00 7.49
72 Toluene 91 6.523 6.524 -0.001 97 70945 2.00 1.94
73 trans-1,3-Dichloropropene 75 6.696 6.696 0.000 97 24165 2.00 1.88
74 Ethyl methacrylate 69 6.716 6.712 0.004 96 31310 2.00 1.89
75 1,1,2-Trichloroethane 97 6.877 6.873 0.004 91 14102 2.00 1.93 M
76 Tetrachloroethene 164 6.969 6.965 0.004 94 11044 2.00 1.93
77 1,3-Dichloropropane 76 7.017 7.018 -0.001 97 27146 2.00 1.81
78 2-Hexanone 43 7.037 7.038 -0.001 98 174629 8.00 7.21
79 Chlorodibromomethane 129 7.210 7.210 0.000 94 10844 2.00 1.74 M
80 Ethylene Dibromide 107 7.330 7.335 -0.005 95 15426 2.00 2.23
81 1-Chlorohexane 91 7.720 7.720 0.000 77 19020 1.60 1.55
82 Chlorobenzene 112 7.764 7.764 0.000 92 39487 2.00 1.85
83 1,1,1,2-Tetrachloroethane 131 7.832 7.837 -0.005 86 11081 2.00 1.79
84 Ethylbenzene 106 7.840 7.841 -0.001 99 21336 2.00 1.77
85 m-Xylene & p-Xylene 106 7.957 7.957 0.000 0 27729 2.00 2.13
86 o-Xylene 106 8.318 8.318 0.000 98 28147 2.00 1.96
87 Styrene 104 8.334 8.335 -0.001 94 43953 2.00 1.84
88 Bromoform 173 8.519 8.511 0.008 90 8574 2.00 1.97
89 Isopropylbenzene 105 8.660 8.656 0.004 96 60309 2.00 1.84
91 Cyclohexanone 55 8.756 8.756 0.000 98 96299 60.0 52.0
92 1,1,2,2-Tetrachloroethane 83 8.945 8.945 0.000 92 23256 2.00 1.89
93 Bromobenzene 156 8.977 8.981 -0.004 95 16516 2.00 2.01 M
94 trans-1,4-Dichloro-2-butene 53 8.985 8.985 0.000 51 5942 2.00 2.03
95 1,2,3-Trichloropropane 110 9.005 9.009 -0.004 89 6542 2.00 1.55
96 N-Propylbenzene 120 9.057 9.057 0.000 99 18329 2.00 1.95
97 2-Chlorotoluene 126 9.157 9.158 -0.001 94 14131 2.00 1.74
98 1,3,5-Trimethylbenzene 105 9.226 9.230 -0.004 96 50623 2.00 1.77
99 4-Chlorotoluene 126 9.274 9.274 0.000 99 14704 2.00 1.73
11/15/2024
3:53:55 PM
Page 477 of 777
Report Date: 29-Oct-2024 21:08:46 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008667.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
100 tert-Butylbenzene 119 9.539 9.539 0.000 94 45117 2.00 1.91
102 1,2,4-Trimethylbenzene 105 9.599 9.599 0.000 99 57597 2.00 1.92
103 sec-Butylbenzene 134 9.756 9.756 0.000 95 12473 2.00 1.81
104 1,3-Dichlorobenzene 146 9.888 9.888 0.000 96 31196 2.00 2.00
105 4-Isopropyltoluene 119 9.904 9.901 0.004 97 53621 2.00 1.85
106 1,4-Dichlorobenzene 146 9.989 9.989 0.000 91 32004 2.00 1.98
108 n-Butylbenzene 91 10.314 10.310 0.004 99 52502 2.00 1.94
109 1,2-Dichlorobenzene 146 10.346 10.346 0.000 93 28293 2.00 1.82
110 1,2-Dibromo-3-Chloropropane 157 11.133 11.125 0.008 79 6305 2.00 1.68 M
112 1,2,4-Trichlorobenzene 180 11.948 11.948 0.000 92 18912 2.00 2.01
113 Hexachlorobutadiene 225 12.089 12.089 0.000 85 4959 2.00 1.59
114 Naphthalene 128 12.225 12.221 0.004 96 78011 2.00 2.01
115 1,2,3-Trichlorobenzene 180 12.442 12.442 0.000 87 17994 2.00 1.96
S 122 1,2-Dichloroethene, Total (URS) 96 0 4.00 3.92
S 129 1,2-Dichloroethene, Total 1 0 4.00 3.92
S 123 Xylenes, Total (URS) 1 0 4.00 4.09
S 127 Trihalomethanes, Total 1 0 8.00 7.72
S 125 Xylenes, Total 106 0 4.00 4.09
S 126 Total BTEX 1 0 9.67
S 124 1,3-Dichloropropene, Total 1 0 4.00 3.41
QC Flag Legend
Processing Flags
Review Flags
M - Manually Integrated
Reagents:
Cal Dil Std_00426 Amount Added: 20.00 Units: uL
mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 478 of 777
Report Date: 29-Oct-2024 21:08:46 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008667.D
Injection Date:29-Oct-2024 19:17:30 Instrument ID:VMS_X4 Operator ID:CF
Lims ID:ic Worklist Smp#:41
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:8
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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11/15/2024
3:53:55 PM
Page 479 of 777
Report Date: 29-Oct-2024 21:08:46 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008667.D
Injection Date:29-Oct-2024 19:17:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:8 Worklist Smp#:41
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
13 Chloroethane, CAS: 75-00-3
Signal: 1
Processing Integration Results
RT: 2.42
Area: 4857
Amount: 0.736961
Amount Units: ug/l
2.1 2.3 2.5 2.7
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
Y ( X
1
0
0
0
)
m/z 64.0

2
.
4
2
4
Manual Integration Results
RT: 2.42
Area: 14786
Amount: 2.187697
Amount Units: ug/l
2.1 2.3 2.5 2.7
Min
RT
-1
0
1
2
3
4
5
6
7
8
9
10
11
12
13
Y ( X
1
0
0
0
)
m/z 64.0

2
.
4
1
6
Reviewer: AK2J, 29-Oct-2024 19:41:32 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 480 of 777
Report Date: 29-Oct-2024 21:08:46 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008667.D
Injection Date:29-Oct-2024 19:17:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:8 Worklist Smp#:41
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
14 Dichlorofluoromethane, CAS: 75-43-4
Signal: 1
Processing Integration Results
RT: 2.60
Area: 28112
Amount: 1.539779
Amount Units: ug/l
2.3 2.5 2.7 2.9
Min
0
2
4
6
8
10
12
14
16
18
20
Y ( X
1
0
0
0
)
m/z 67.0

2
.
596
Manual Integration Results
RT: 2.60
Area: 28923
Amount: 1.806127
Amount Units: ug/l
2.3 2.5 2.7 2.9
Min
RT
0
2
4
6
8
10
12
14
16
18
20
Y ( X
1
0
0
0
)
m/z 67.0

2
.
596
Reviewer: AK2J, 29-Oct-2024 19:45:07 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 481 of 777
Report Date: 29-Oct-2024 21:08:46 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008667.D
Injection Date:29-Oct-2024 19:17:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:8 Worklist Smp#:41
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
21 1,1-Dichloroethene, CAS: 75-35-4
Signal: 1
Processing Integration Results
RT: 3.04
Area: 7027
Amount: 1.133415
Amount Units: ug/l
2.7 2.9 3.1 3.3
Min
0
1
2
3
4
5
6
7
8
9
10
11
Y ( X
1
0
0
0
)
m/z 96.0

3
.
0
3
8
Manual Integration Results
RT: 3.04
Area: 13497
Amount: 2.054242
Amount Units: ug/l
2.7 2.9 3.1 3.3
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
Y ( X
1
0
0
0
)
m/z 96.0

3
.
0
3
8
Reviewer: AK2J, 29-Oct-2024 19:44:41 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 482 of 777
Report Date: 29-Oct-2024 21:08:46 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008667.D
Injection Date:29-Oct-2024 19:17:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:8 Worklist Smp#:41
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
24 Iodomethane, CAS: 74-88-4
Signal: 1
Processing Integration Results
RT: 3.17
Area: 3632
Amount: 0.836612
Amount Units: ug/l
2.8 3.0 3.2 3.4
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
Y ( X
1
0
0
)
m/z 142.0

3
.
1
6
7
Manual Integration Results
RT: 3.17
Area: 5871
Amount: 1.586128
Amount Units: ug/l
2.8 3.0 3.2 3.4
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
39
Y ( X
1
0
0
)
m/z 142.0

3
.
1
6
7
Reviewer: AK2J, 29-Oct-2024 19:44:32 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 483 of 777
Report Date: 29-Oct-2024 21:08:46 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008667.D
Injection Date:29-Oct-2024 19:17:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:8 Worklist Smp#:41
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
50 1,1,1-Trichloroethane, CAS: 71-55-6
Signal: 1
Processing Integration Results
RT: 4.73
Area: 18792
Amount: 1.678158
Amount Units: ug/l
4.4 4.6 4.8 5.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
Y ( X
1
0
0
0
)
m/z 97.0

4
.
7
3
3
Manual Integration Results
RT: 4.73
Area: 18924
Amount: 1.828187
Amount Units: ug/l
4.4 4.6 4.8 5.0
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
12
13
Y ( X
1
0
0
0
)
m/z 97.0

4
.
7
3
3
Reviewer: AK2J, 29-Oct-2024 19:45:31 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 484 of 777
Report Date: 29-Oct-2024 21:08:46 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008667.D
Injection Date:29-Oct-2024 19:17:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:8 Worklist Smp#:41
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
63 1,2-Dichloropropane, CAS: 78-87-5
Signal: 1
Processing Integration Results
RT: 5.69
Area: 13958
Amount: 1.400940
Amount Units: ug/l
5.4 5.6 5.8 6.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
Y ( X
1
0
0
0
)
m/z 63.0

5.6
9
2
Manual Integration Results
RT: 5.69
Area: 18446
Amount: 1.805819
Amount Units: ug/l
5.4 5.6 5.8 6.0
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
12
Y ( X
1
0
0
0
)
m/z 63.0

5.6
9
2
Reviewer: AK2J, 29-Oct-2024 19:44:16 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 485 of 777
Report Date: 29-Oct-2024 21:08:46 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008667.D
Injection Date:29-Oct-2024 19:17:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:8 Worklist Smp#:41
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
75 1,1,2-Trichloroethane, CAS: 79-00-5
Signal: 1
Processing Integration Results
RT: 6.86
Area: 6264
Amount: 0.864917
Amount Units: ug/l
6.5 6.7 6.9 7.1
Min
0
6
12
18
24
30
36
42
48
54
60
66
72
78
84
Y ( X
1
0
0
)
m/z 97.0

6
.
8
6
5
Manual Integration Results
RT: 6.88
Area: 14102
Amount: 1.928602
Amount Units: ug/l
6.5 6.7 6.9 7.1
Min
RT
0
6
12
18
24
30
36
42
48
54
60
66
72
78
84
Y ( X
1
0
0
)
m/z 97.0

6
.
8
7
7
Reviewer: AK2J, 29-Oct-2024 19:44:05 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 486 of 777
Report Date: 29-Oct-2024 21:08:46 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008667.D
Injection Date:29-Oct-2024 19:17:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:8 Worklist Smp#:41
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
79 Chlorodibromomethane, CAS: 124-48-1
Signal: 1
Processing Integration Results
RT: 7.21
Area: 8880
Amount: 1.437612
Amount Units: ug/l
6.9 7.1 7.3 7.5
Min
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
Y ( X
1
0
0
)
m/z 129.0

7
.
2
1
0
Manual Integration Results
RT: 7.21
Area: 10844
Amount: 1.737354
Amount Units: ug/l
6.9 7.1 7.3 7.5
Min
RT
0
6
12
18
24
30
36
42
48
54
60
66
72
78
Y ( X
1
0
0
)
m/z 129.0

7
.
2
1
0
Reviewer: AK2J, 29-Oct-2024 20:10:31 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 487 of 777
Report Date: 29-Oct-2024 21:08:46 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008667.D
Injection Date:29-Oct-2024 19:17:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:8 Worklist Smp#:41
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
93 Bromobenzene, CAS: 108-86-1
Signal: 1
Processing Integration Results
RT: 8.98
Area: 10619
Amount: 1.359350
Amount Units: ug/l
8.7 8.9 9.1 9.3
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
Y ( X
1
0
0
0
)
m/z 156.0

8
.
9
7
7
Manual Integration Results
RT: 8.98
Area: 16516
Amount: 2.014420
Amount Units: ug/l
8.7 8.9 9.1 9.3
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
12
Y ( X
1
0
0
0
)
m/z 156.0

8
.
9
7
7
Reviewer: AK2J, 29-Oct-2024 19:43:30 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 488 of 777
Report Date: 29-Oct-2024 21:08:46 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008667.D
Injection Date:29-Oct-2024 19:17:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:8 Worklist Smp#:41
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
110 1,2-Dibromo-3-Chloropropane, CAS: 96-12-8
Signal: 1
Processing Integration Results
RT: 11.12
Area: 4082
Amount: 1.311146
Amount Units: ug/l
10.8 11.0 11.2 11.4
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
45
Y ( X
1
0
0
)
m/z 157.0
1
1
.
1
2
5
Manual Integration Results
RT: 11.13
Area: 6305
Amount: 1.682050
Amount Units: ug/l
10.8 11.0 11.2 11.4
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
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1
0
0
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m/z 157.0
1
1
.
1
3
3
Reviewer: AK2J, 29-Oct-2024 19:43:10 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 489 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:2
Inject. Date:29-Oct-2024 19:38:30 ALS Bottle#:9 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:IC
Operator ID:CF Instrument ID:VMS_X4
Sublist:chrom-VMS_X4_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:29-Oct-2024 21:08:48 Calib Date:29-Oct-2024 20:00:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1635
First Level Reviewer: AK2J Date:29-Oct-2024 20:10:03
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.207 5.207 0.000 97 1594549 50.0 50.0
* 2 Chlorobenzene-d5 119 7.736 7.736 0.000 91 347417 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.965 9.961 0.004 97 544605 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.701 4.701 0.000 93 319442 50.0 49.4
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.962 4.966 -0.004 0 479492 50.0 49.5
$ 6 Toluene-d8 (Surr) 98 6.463 6.463 0.000 95 1617314 50.0 49.5
$ 7 4-Bromofluorobenzene (Surr) 95 8.832 8.832 0.000 84 545845 50.0 51.4
9 Dichlorodifluoromethane 85 1.753 1.753 0.000 99 9910 1.00 1.09
10 Chloromethane 50 1.934 1.938 -0.004 98 15179 1.00 1.12
11 Vinyl chloride 62 2.038 2.039 -0.001 98 9893 1.00 0.9611
12 Bromomethane 94 2.324 2.320 0.004 86 6305 1.00 1.01
13 Chloroethane 64 2.420 2.420 0.000 59 5981 1.00 0.8879
14 Dichlorofluoromethane 67 2.597 2.597 0.000 96 15045 1.00 0.9426
16 Trichlorofluoromethane 101 2.629 2.629 0.000 95 9870 1.00 1.02
18 Ethyl ether 59 2.854 2.846 0.008 98 8970 1.00 1.00 M
19 Acrolein 56 2.962 2.962 0.000 97 27634 9.88 9.47
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.034 3.038 -0.004 74 4453 1.00 0.9871 M
21 1,1-Dichloroethene 96 3.042 3.046 -0.004 79 5492 1.00 0.8386
22 Acetone 43 3.066 3.066 0.000 98 155642 4.00 6.91
24 Iodomethane 142 3.163 3.171 -0.008 23 2890 1.00 0.2927 M
25 Carbon disulfide 76 3.227 3.227 0.000 99 29383 1.00 0.9719
27 Methyl acetate 43 3.295 3.291 0.004 98 37749 2.00 1.88
28 3-Chloro-1-propene 41 3.319 3.315 0.004 92 18795 1.00 0.9079
29 Methylene Chloride 84 3.408 3.416 -0.008 96 15033 1.00 1.11
30 2-Methyl-2-propanol 59 3.460 3.456 0.004 97 54202 10.0 9.67
31 Acrylonitrile 53 3.580 3.576 0.004 97 90793 10.0 9.69
32 Methyl tert-butyl ether 73 3.596 3.596 0.000 91 26598 1.00 0.9411
33 trans-1,2-Dichloroethene 96 3.612 3.617 -0.005 88 7278 1.00 0.9768
34 Hexane 57 3.809 3.809 0.000 94 13879 1.00 0.9644
35 Vinyl acetate 43 3.910 3.910 0.000 97 56654 2.00 1.90
36 1,1-Dichloroethane 63 3.926 3.938 -0.012 57 17754 1.00 1.05
11/15/2024
3:53:55 PM
Page 490 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
40 2-Butanone (MEK) 43 4.323 4.323 0.000 98 99784 4.00 4.23
42 cis-1,2-Dichloroethene 96 4.351 4.351 0.000 67 8960 1.00 1.07
43 2,2-Dichloropropane 77 4.359 4.363 -0.004 92 11960 1.00 0.9502 M
45 sec-Butyl Alcohol 45 4.436 4.432 0.004 99 108417 24.0 20.7
47 Chlorobromomethane 128 4.524 4.524 0.000 89 4195 1.00 1.16 M
48 Tetrahydrofuran 42 4.540 4.536 0.004 98 23788 2.00 1.98
49 Chloroform 83 4.588 4.584 0.004 93 13486 1.00 1.02 M
50 1,1,1-Trichloroethane 97 4.725 4.729 -0.004 64 11135 1.00 1.08
51 Cyclohexane 56 4.785 4.789 -0.004 93 18929 1.00 1.02
52 1,1-Dichloropropene 75 4.845 4.841 0.004 59 11382 1.00 0.9455
53 Carbon tetrachloride 117 4.841 4.845 -0.004 34 7685 1.00 0.9587
54 Isobutyl alcohol 41 4.849 4.849 0.000 92 45554 25.0 21.5
55 Benzene 78 4.994 4.994 0.000 94 36166 1.00 1.01
56 1,2-Dichloroethane 62 5.018 5.026 -0.008 92 12458 1.00 0.99
58 n-Heptane 43 5.182 5.174 0.008 50 12822 1.00 0.8649
60 Trichloroethene 95 5.480 5.480 0.000 89 8624 1.00 1.05
61 2-Pentanone 43 5.588 5.588 0.000 97 87522 3.20 3.20
62 Methylcyclohexane 55 5.680 5.676 0.004 86 14010 1.00 1.04
63 1,2-Dichloropropane 63 5.692 5.692 0.000 83 9785 1.00 0.9611
65 1,4-Dioxane 88 5.725 5.737 -0.012 78 7900 20.0 18.9
66 Dibromomethane 93 5.753 5.761 -0.008 90 5793 1.00 1.15 M
67 Dichlorobromomethane 83 5.881 5.885 -0.004 94 8682 1.00 0.9232 M
69 2-Chloroethyl vinyl ether 63 6.086 6.082 0.004 88 9203 1.00 1.30
70 cis-1,3-Dichloropropene 75 6.230 6.235 -0.005 84 13581 1.00 0.9782
71 4-Methyl-2-pentanone (MIBK) 43 6.335 6.335 0.000 99 101481 4.00 3.72
72 Toluene 91 6.520 6.524 -0.004 97 35616 1.00 0.9751
73 trans-1,3-Dichloropropene 75 6.700 6.696 0.004 96 11368 1.00 0.8853
74 Ethyl methacrylate 69 6.716 6.712 0.004 96 13858 1.00 0.8500
75 1,1,2-Trichloroethane 97 6.865 6.873 -0.008 91 7015 1.00 0.9625 M
76 Tetrachloroethene 164 6.961 6.965 -0.004 94 5209 1.00 0.9270
77 1,3-Dichloropropane 76 7.017 7.018 -0.001 87 13762 1.00 0.9342
78 2-Hexanone 43 7.038 7.038 0.000 97 93045 4.00 3.91
79 Chlorodibromomethane 129 7.206 7.210 -0.004 87 5535 1.00 0.9016
80 Ethylene Dibromide 107 7.331 7.335 -0.004 96 5840 1.00 1.02
81 1-Chlorohexane 91 7.720 7.720 0.000 85 9854 0.8000 0.7025
82 Chlorobenzene 112 7.764 7.764 0.000 58 20370 1.00 0.9701
83 1,1,1,2-Tetrachloroethane 131 7.833 7.837 -0.004 41 5730 1.00 0.9394
84 Ethylbenzene 106 7.841 7.841 0.000 98 12247 1.00 1.03
85 m-Xylene & p-Xylene 106 7.965 7.957 0.008 0 10643 1.00 1.04
86 o-Xylene 106 8.318 8.318 0.000 96 14501 1.00 1.03
87 Styrene 104 8.334 8.335 -0.001 95 22991 1.00 0.9804
88 Bromoform 173 8.519 8.511 0.008 88 4101 1.00 0.9558 M
89 Isopropylbenzene 105 8.656 8.656 0.000 96 31341 1.00 0.9759
91 Cyclohexanone 55 8.760 8.756 0.004 98 47330 30.0 26.0
92 1,1,2,2-Tetrachloroethane 83 8.941 8.945 -0.004 47 12105 1.00 1.00
93 Bromobenzene 156 8.981 8.981 0.000 92 8504 1.00 1.06
94 trans-1,4-Dichloro-2-butene 53 8.985 8.985 0.000 45 2633 1.00 0.9169
95 1,2,3-Trichloropropane 110 9.013 9.009 0.004 79 4088 1.00 0.9857 M
96 N-Propylbenzene 120 9.061 9.057 0.004 99 8282 1.00 0.8971 M
97 2-Chlorotoluene 126 9.158 9.158 0.000 94 8031 1.00 1.01 M
98 1,3,5-Trimethylbenzene 105 9.230 9.230 0.000 95 28309 1.00 1.01
99 4-Chlorotoluene 126 9.274 9.274 0.000 97 8200 1.00 0.9813
11/15/2024
3:53:55 PM
Page 491 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
100 tert-Butylbenzene 119 9.543 9.539 0.004 95 24066 1.00 1.04
102 1,2,4-Trimethylbenzene 105 9.595 9.599 -0.004 96 29721 1.00 1.01
103 sec-Butylbenzene 134 9.756 9.756 0.000 95 7510 1.00 1.11
104 1,3-Dichlorobenzene 146 9.884 9.888 -0.004 55 15164 1.00 0.99 M
105 4-Isopropyltoluene 119 9.904 9.901 0.004 97 28798 1.00 1.01
106 1,4-Dichlorobenzene 146 9.989 9.989 0.000 88 16771 1.00 1.06
108 n-Butylbenzene 91 10.314 10.310 0.004 97 24883 1.00 0.9370 M
109 1,2-Dichlorobenzene 146 10.338 10.346 -0.008 73 17134 1.00 1.13 M
110 1,2-Dibromo-3-Chloropropane 157 11.125 11.125 0.000 75 3932 1.00 1.07
112 1,2,4-Trichlorobenzene 180 11.960 11.948 0.012 89 11364 1.00 1.23 M
113 Hexachlorobutadiene 225 12.089 12.089 0.000 83 4082 1.00 1.34 M
114 Naphthalene 128 12.221 12.221 0.000 97 42584 1.00 1.07
115 1,2,3-Trichlorobenzene 180 12.434 12.442 -0.008 92 9794 1.00 1.00 M
S 122 1,2-Dichloroethene, Total (URS) 96 0 2.00 2.05
S 129 1,2-Dichloroethene, Total 1 0 2.00 2.05
S 123 Xylenes, Total (URS) 1 0 2.00 2.07
S 127 Trihalomethanes, Total 1 0 4.00 3.80
S 125 Xylenes, Total 106 0 2.00 2.07
S 126 Total BTEX 1 0 5.08
S 124 1,3-Dichloropropene, Total 1 0 2.00 1.86
QC Flag Legend
Processing Flags
Review Flags
M - Manually Integrated
Reagents:
Cal Dil Std_00426 Amount Added: 10.00 Units: uL
mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 492 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Injection Date:29-Oct-2024 19:38:30 Instrument ID:VMS_X4 Operator ID:CF
Lims ID:ic Worklist Smp#:42
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:9
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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11/15/2024
3:53:55 PM
Page 493 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Injection Date:29-Oct-2024 19:38:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:9 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
18 Ethyl ether, CAS: 60-29-7
Signal: 1
Processing Integration Results
RT: 2.84
Area: 3991
Amount: 0.480021
Amount Units: ug/l
2.5 2.7 2.9 3.1
Min
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
Y ( X
1
0
0
)
m/z 59.0

2
.
8
4
2
Manual Integration Results
RT: 2.85
Area: 8970
Amount: 1.001385
Amount Units: ug/l
2.5 2.7 2.9 3.1
Min
RT
0
6
12
18
24
30
36
42
48
54
60
66
72
Y ( X
1
0
0
)
m/z 59.0

2
.
8
54
Reviewer: AK2J, 29-Oct-2024 20:06:59 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 494 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Injection Date:29-Oct-2024 19:38:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:9 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
20 1,1,2-Trichloro-1,2,2-trifluoroe, CAS: 76-13-1
Signal: 1
Processing Integration Results
RT: 3.03
Area: 2160
Amount: 0.592109
Amount Units: ug/l
2.7 2.9 3.1 3.3
Min
0
3
6
9
12
15
18
21
24
27
30
33
Y ( X
1
0
0
)
m/z 151.0

3
.
0
3
4
Manual Integration Results
RT: 3.03
Area: 4453
Amount: 0.987126
Amount Units: ug/l
2.7 2.9 3.1 3.3
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
Y ( X
1
0
0
)
m/z 151.0

3
.
0
3
4
Reviewer: AK2J, 29-Oct-2024 20:07:06 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 495 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Injection Date:29-Oct-2024 19:38:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:9 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
24 Iodomethane, CAS: 74-88-4
Signal: 1
Processing Integration Results
RT: 3.16
Area: 1444
Amount: 0.414868
Amount Units: ug/l
2.8 3.0 3.2 3.4
Min
0
2
4
6
8
10
12
14
16
18
Y ( X
1
0
0
)
m/z 142.0

3
.
1
6
3
Manual Integration Results
RT: 3.16
Area: 2890
Amount: 0.292702
Amount Units: ug/l
2.8 3.0 3.2 3.4
Min
RT
0
2
4
6
8
10
12
14
16
18
Y ( X
1
0
0
)
m/z 142.0

3
.
1
6
3
Reviewer: AK2J, 29-Oct-2024 20:50:00 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 496 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Injection Date:29-Oct-2024 19:38:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:9 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
43 2,2-Dichloropropane, CAS: 594-20-7
Signal: 1
Processing Integration Results
RT: 4.36
Area: 8898
Amount: 0.730808
Amount Units: ug/l
4.0 4.2 4.4 4.6
Min
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
Y ( X
1
0
0
)
m/z 77.0

4
.
3
59
Manual Integration Results
RT: 4.36
Area: 11960
Amount: 0.950225
Amount Units: ug/l
4.0 4.2 4.4 4.6
Min
RT
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
Y ( X
1
0
0
)
m/z 77.0

4
.
3
59
Reviewer: AK2J, 29-Oct-2024 20:07:39 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 497 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Injection Date:29-Oct-2024 19:38:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:9 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
47 Chlorobromomethane, CAS: 74-97-5
Signal: 1
Processing Integration Results
RT: 4.52
Area: 2412
Amount: 0.715251
Amount Units: ug/l
4.2 4.4 4.6 4.8
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
Y ( X
1
0
0
)
m/z 128.0

4
.
524
Manual Integration Results
RT: 4.52
Area: 4195
Amount: 1.162151
Amount Units: ug/l
4.2 4.4 4.6 4.8
Min
RT
0
3
6
9
12
15
18
21
24
27
30
Y ( X
1
0
0
)
m/z 128.0

4
.
524
Reviewer: AK2J, 29-Oct-2024 20:07:48 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 498 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Injection Date:29-Oct-2024 19:38:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:9 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
49 Chloroform, CAS: 67-66-3
Signal: 1
Processing Integration Results
RT: 4.59
Area: 7442
Amount: 0.576193
Amount Units: ug/l
4.3 4.5 4.7 4.9
Min
0
6
12
18
24
30
36
42
48
54
60
66
72
78
84
Y ( X
1
0
0
)
m/z 83.0

4
.
588
Manual Integration Results
RT: 4.59
Area: 13486
Amount: 1.018823
Amount Units: ug/l
4.3 4.5 4.7 4.9
Min
RT
0
7
14
21
28
35
42
49
56
63
70
77
84
Y ( X
1
0
0
)
m/z 83.0

4
.
588
Reviewer: AK2J, 29-Oct-2024 20:07:56 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 499 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Injection Date:29-Oct-2024 19:38:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:9 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
66 Dibromomethane, CAS: 74-95-3
Signal: 1
Processing Integration Results
RT: 5.75
Area: 1349
Amount: 0.314919
Amount Units: ug/l
5.4 5.6 5.8 6.0
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
Y ( X
1
0
0
)
m/z 93.0

5.7
53
Manual Integration Results
RT: 5.75
Area: 5793
Amount: 1.145462
Amount Units: ug/l
5.4 5.6 5.8 6.0
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
Y ( X
1
0
0
)
m/z 93.0

5.7
53
Reviewer: AK2J, 29-Oct-2024 20:08:12 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 500 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Injection Date:29-Oct-2024 19:38:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:9 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
67 Dichlorobromomethane, CAS: 75-27-4
Signal: 1
Processing Integration Results
RT: 5.88
Area: 5175
Amount: 0.774192
Amount Units: ug/l
5.6 5.8 6.0 6.2
Min
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
Y ( X
1
0
0
)
m/z 83.0

5.8
8
1
Manual Integration Results
RT: 5.88
Area: 8682
Amount: 0.923200
Amount Units: ug/l
5.6 5.8 6.0 6.2
Min
RT
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
Y ( X
1
0
0
)
m/z 83.0

5.8
8
1
Reviewer: AK2J, 29-Oct-2024 20:08:20 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 501 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Injection Date:29-Oct-2024 19:38:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:9 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
75 1,1,2-Trichloroethane, CAS: 79-00-5
Signal: 1
Processing Integration Results
RT: 6.86
Area: 5222
Amount: 0.723236
Amount Units: ug/l
6.5 6.7 6.9 7.1
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
Y ( X
1
0
0
)
m/z 97.0

6
.
8
6
5
Manual Integration Results
RT: 6.86
Area: 7015
Amount: 0.962549
Amount Units: ug/l
6.5 6.7 6.9 7.1
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
48
Y ( X
1
0
0
)
m/z 97.0

6
.
8
6
5
Reviewer: AK2J, 29-Oct-2024 20:08:35 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 502 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Injection Date:29-Oct-2024 19:38:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:9 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
88 Bromoform, CAS: 75-25-2
Signal: 1
Processing Integration Results
RT: 8.52
Area: 2978
Amount: 0.709683
Amount Units: ug/l
8.2 8.4 8.6 8.8
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
Y ( X
1
0
0
)
m/z 173.0

8
.
519
Manual Integration Results
RT: 8.52
Area: 4101
Amount: 0.955770
Amount Units: ug/l
8.2 8.4 8.6 8.8
Min
RT
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
Y ( X
1
0
0
)
m/z 173.0

8
.
519
Reviewer: AK2J, 29-Oct-2024 20:08:50 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 503 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Injection Date:29-Oct-2024 19:38:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:9 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
95 1,2,3-Trichloropropane, CAS: 96-18-4
Signal: 1
Processing Integration Results
RT: 9.01
Area: 2419
Amount: 0.812618
Amount Units: ug/l
8.7 8.9 9.1 9.3
Min
0
3
6
9
12
15
18
21
24
27
30
33
Y ( X
1
0
0
)
m/z 110.0

9
.
0
1
3
Manual Integration Results
RT: 9.01
Area: 4088
Amount: 0.985715
Amount Units: ug/l
8.7 8.9 9.1 9.3
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
Y ( X
1
0
0
)
m/z 110.0

9
.
0
1
3
Reviewer: AK2J, 29-Oct-2024 20:11:35 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 504 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Injection Date:29-Oct-2024 19:38:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:9 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
96 N-Propylbenzene, CAS: 103-65-1
Signal: 1
Processing Integration Results
RT: 9.06
Area: 4911
Amount: 0.545331
Amount Units: ug/l
8.7 8.9 9.1 9.3
Min
0
6
12
18
24
30
36
42
48
54
60
66
72
78
84
90
Y ( X
1
0
0
)
m/z 120.0

9
.
0
6
1
Manual Integration Results
RT: 9.06
Area: 8282
Amount: 0.897104
Amount Units: ug/l
8.7 8.9 9.1 9.3
Min
RT
0
7
14
21
28
35
42
49
56
63
70
77
84
91
Y ( X
1
0
0
)
m/z 120.0

9
.
0
6
1
Reviewer: AK2J, 29-Oct-2024 20:11:26 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 505 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Injection Date:29-Oct-2024 19:38:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:9 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
97 2-Chlorotoluene, CAS: 95-49-8
Signal: 1
Processing Integration Results
RT: 9.16
Area: 5048
Amount: 0.674082
Amount Units: ug/l
8.8 9.0 9.2 9.4
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
Y ( X
1
0
0
)
m/z 126.0

9
.
1
58
Manual Integration Results
RT: 9.16
Area: 8031
Amount: 1.011200
Amount Units: ug/l
8.8 9.0 9.2 9.4
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
48
Y ( X
1
0
0
)
m/z 126.0

9
.
1
58
Reviewer: AK2J, 29-Oct-2024 20:09:07 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 506 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Injection Date:29-Oct-2024 19:38:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:9 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
104 1,3-Dichlorobenzene, CAS: 541-73-1
Signal: 1
Processing Integration Results
RT: 9.89
Area: 9009
Amount: 0.603052
Amount Units: ug/l
9.6 9.8 10.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
Y ( X
1
0
0
0
)
m/z 146.0

9
.
8
9
2
Manual Integration Results
RT: 9.88
Area: 15164
Amount: 0.993800
Amount Units: ug/l
9.6 9.8 10.0
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
Y ( X
1
0
0
0
)
m/z 146.0

9
.
8
8
4
Reviewer: AK2J, 29-Oct-2024 20:11:44 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 507 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Injection Date:29-Oct-2024 19:38:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:9 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
108 n-Butylbenzene, CAS: 104-51-8
Signal: 1
Processing Integration Results
RT: 10.31
Area: 18900
Amount: 0.716657
Amount Units: ug/l
10.0 10.2 10.4 10.6
Min
0
2
4
6
8
10
12
14
16
18
20
Y ( X
1
0
0
0
)
m/z 91.0
1
0
.
3
1
4
Manual Integration Results
RT: 10.31
Area: 24883
Amount: 0.936953
Amount Units: ug/l
10.0 10.2 10.4 10.6
Min
RT
0
2
4
6
8
10
12
14
16
18
20
Y ( X
1
0
0
0
)
m/z 91.0
1
0
.
3
1
4
Reviewer: AK2J, 29-Oct-2024 20:09:20 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 508 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Injection Date:29-Oct-2024 19:38:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:9 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
109 1,2-Dichlorobenzene, CAS: 95-50-1
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 10.35
10.0 10.2 10.4 10.6
Min
0
1
2
3
4
5
6
7
8
9
10
11
Y ( X
1
0
0
0
)
m/z 146.0
Manual Integration Results
RT: 10.34
Area: 17134
Amount: 1.126983
Amount Units: ug/l
10.0 10.2 10.4 10.6
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
Y ( X
1
0
0
0
)
m/z 146.0
1
0
.
3
3
8
Reviewer: AK2J, 29-Oct-2024 20:09:29 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 509 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Injection Date:29-Oct-2024 19:38:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:9 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
112 1,2,4-Trichlorobenzene, CAS: 120-82-1
Signal: 1
Processing Integration Results
RT: 11.94
Area: 6844
Amount: 0.828652
Amount Units: ug/l
11.6 11.8 12.0 12.2
Min
0
5
10
15
20
25
30
35
40
45
50
55
60
65
Y ( X
1
0
0
)
m/z 180.0
1
1
.
9
4
4
Manual Integration Results
RT: 11.96
Area: 11364
Amount: 1.234310
Amount Units: ug/l
11.6 11.8 12.0 12.2
Min
RT
0
5
10
15
20
25
30
35
40
45
50
55
60
65
Y ( X
1
0
0
)
m/z 180.0
1
1
.
9
6
0
Reviewer: AK2J, 29-Oct-2024 20:09:41 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 510 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Injection Date:29-Oct-2024 19:38:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:9 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
113 Hexachlorobutadiene, CAS: 87-68-3
Signal: 1
Processing Integration Results
RT: 12.09
Area: 2325
Amount: 0.766268
Amount Units: ug/l
11.8 12.0 12.2
Min
0
3
6
9
12
15
18
21
24
27
30
33
Y ( X
1
0
0
)
m/z 225.0
1
2
.
0
8
9
Manual Integration Results
RT: 12.09
Area: 4082
Amount: 1.341554
Amount Units: ug/l
11.8 12.0 12.2
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
Y ( X
1
0
0
)
m/z 225.0
1
2
.
0
8
9
Reviewer: AK2J, 29-Oct-2024 20:09:51 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 511 of 777
Report Date: 29-Oct-2024 21:08:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008668.D
Injection Date:29-Oct-2024 19:38:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:9 Worklist Smp#:42
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
115 1,2,3-Trichlorobenzene, CAS: 87-61-6
Signal: 1
Processing Integration Results
RT: 12.45
Area: 6675
Amount: 0.883618
Amount Units: ug/l
12.1 12.3 12.5 12.7
Min
0
6
12
18
24
30
36
42
48
54
60
66
72
78
Y ( X
1
0
0
)
m/z 180.0
1
2
.
4
4
6
Manual Integration Results
RT: 12.43
Area: 9794
Amount: 0.998581
Amount Units: ug/l
12.1 12.3 12.5 12.7
Min
RT
0
6
12
18
24
30
36
42
48
54
60
66
72
78
Y ( X
1
0
0
)
m/z 180.0
1
2
.
4
3
4
Reviewer: AK2J, 29-Oct-2024 20:09:58 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 512 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:1
Inject. Date:29-Oct-2024 20:00:30 ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:IC
Operator ID:CF Instrument ID:VMS_X4
Sublist:chrom-VMS_X4_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:29-Oct-2024 21:08:50 Calib Date:29-Oct-2024 20:00:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1635
First Level Reviewer: AK2J Date:29-Oct-2024 21:05:22
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.206 5.207 -0.001 97 1702505 50.0 50.0
* 2 Chlorobenzene-d5 119 7.736 7.736 0.000 92 365464 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.961 9.961 0.000 97 555961 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.701 4.701 0.000 92 349334 50.0 50.6
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.962 4.966 -0.004 0 529270 50.0 51.2
$ 6 Toluene-d8 (Surr) 98 6.463 6.463 0.000 95 1698714 50.0 49.5
$ 7 4-Bromofluorobenzene (Surr) 95 8.832 8.832 0.000 85 535883 50.0 49.4
9 Dichlorodifluoromethane 85 1.753 1.753 0.000 98 4215 0.5000 0.4333
10 Chloromethane 50 1.938 1.938 0.000 98 7804 0.5000 0.5387
11 Vinyl chloride 62 2.038 2.039 -0.001 63 4825 0.5000 0.4390 M
12 Bromomethane 94 2.319 2.320 -0.001 87 4926 0.5000 0.4990 M
13 Chloroethane 64 2.416 2.420 -0.004 86 3860 0.5000 0.5367
14 Dichlorofluoromethane 67 2.597 2.597 0.000 96 9164 0.5000 0.5377
16 Trichlorofluoromethane 101 2.629 2.629 0.000 63 5601 0.5000 0.5414
18 Ethyl ether 59 2.850 2.846 0.004 91 5849 0.5000 0.6116
19 Acrolein 56 2.962 2.962 0.000 97 17066 4.94 5.15
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.042 3.038 0.004 56 2560 0.5000 0.5315
21 1,1-Dichloroethene 96 3.050 3.046 0.004 88 4211 0.5000 0.6023 M
22 Acetone 43 3.066 3.066 0.000 98 130679 2.00 3.61
24 Iodomethane 142 3.175 3.171 0.004 23 2132 0.5000 -0.1046 Ma
25 Carbon disulfide 76 3.235 3.227 0.008 99 19628 0.5000 0.5152
27 Methyl acetate 43 3.295 3.291 0.004 99 22205 1.00 1.04
28 3-Chloro-1-propene 41 3.311 3.315 -0.004 79 11784 0.5000 0.5331
29 Methylene Chloride 84 3.412 3.416 -0.004 95 10284 0.5000 0.4689
30 2-Methyl-2-propanol 59 3.460 3.456 0.004 97 31880 5.00 5.33
31 Acrylonitrile 53 3.576 3.576 0.000 98 50279 5.00 5.02
32 Methyl tert-butyl ether 73 3.596 3.596 0.000 94 15165 0.5000 0.5026 M
33 trans-1,2-Dichloroethene 96 3.612 3.617 -0.005 85 4276 0.5000 0.5375
34 Hexane 57 3.805 3.809 -0.004 95 8992 0.5000 0.5940
35 Vinyl acetate 43 3.910 3.910 0.000 97 30453 1.00 0.9577
36 1,1-Dichloroethane 63 3.934 3.938 -0.004 44 9122 0.5000 0.5063
11/15/2024
3:53:55 PM
Page 513 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
40 2-Butanone (MEK) 43 4.323 4.323 0.000 97 64663 2.00 2.01
42 cis-1,2-Dichloroethene 96 4.351 4.351 0.000 37 5215 0.5000 0.5832 M
43 2,2-Dichloropropane 77 4.363 4.363 0.000 67 7633 0.5000 0.5680 M
45 sec-Butyl Alcohol 45 4.436 4.432 0.004 99 63566 12.0 11.3
47 Chlorobromomethane 128 4.524 4.524 0.000 58 2021 0.5000 0.5244
48 Tetrahydrofuran 42 4.536 4.536 0.000 86 12956 1.00 1.01
49 Chloroform 83 4.580 4.584 -0.004 92 7378 0.5000 0.5220
50 1,1,1-Trichloroethane 97 4.733 4.729 0.004 93 4998 0.5000 0.4537 M
51 Cyclohexane 56 4.785 4.789 -0.004 92 8605 0.5000 0.4356
52 1,1-Dichloropropene 75 4.837 4.841 -0.004 55 6203 0.5000 0.4826
53 Carbon tetrachloride 117 4.849 4.845 0.004 48 4266 0.5000 0.4985 M
54 Isobutyl alcohol 41 4.853 4.849 0.004 96 26264 12.5 11.6
55 Benzene 78 4.998 4.994 0.004 88 19747 0.5000 0.5163
56 1,2-Dichloroethane 62 5.030 5.026 0.004 37 7114 0.5000 0.5305 M
58 n-Heptane 43 5.174 5.174 0.000 40 10314 0.5000 0.6516 M
60 Trichloroethene 95 5.484 5.480 0.004 88 4471 0.5000 0.5157 M
61 2-Pentanone 43 5.588 5.588 0.000 97 49968 1.60 1.71
62 Methylcyclohexane 55 5.676 5.676 0.000 77 7393 0.5000 0.5140
63 1,2-Dichloropropane 63 5.688 5.692 -0.004 57 6027 0.5000 0.5544 M
65 1,4-Dioxane 88 5.728 5.737 -0.009 90 5027 10.0 11.2
66 Dibromomethane 93 5.753 5.761 -0.008 52 3398 0.5000 0.6293
67 Dichlorobromomethane 83 5.881 5.885 -0.004 85 4690 0.5000 0.4671
69 2-Chloroethyl vinyl ether 63 6.078 6.082 -0.004 47 2134 0.5000 0.4379
70 cis-1,3-Dichloropropene 75 6.230 6.235 -0.005 86 6964 0.5000 0.4768
71 4-Methyl-2-pentanone (MIBK) 43 6.339 6.335 0.004 98 54177 2.00 1.86
72 Toluene 91 6.524 6.524 0.000 95 20761 0.5000 0.5324
73 trans-1,3-Dichloropropene 75 6.696 6.696 0.000 57 6201 0.5000 0.4523 M
74 Ethyl methacrylate 69 6.716 6.712 0.004 69 8410 0.5000 0.4903
75 1,1,2-Trichloroethane 97 6.873 6.873 0.000 86 3992 0.5000 0.5130
76 Tetrachloroethene 164 6.965 6.965 0.000 89 2824 0.5000 0.4777
77 1,3-Dichloropropane 76 7.021 7.018 0.003 97 7649 0.5000 0.4936
78 2-Hexanone 43 7.041 7.038 0.003 99 46953 2.00 1.87
79 Chlorodibromomethane 129 7.210 7.210 0.000 18 2990 0.5000 0.4630 M
80 Ethylene Dibromide 107 7.335 7.335 0.000 48 1772 0.5000 0.4829
81 1-Chlorohexane 91 7.716 7.720 -0.004 33 7337 0.4000 0.4281 M
82 Chlorobenzene 112 7.760 7.764 -0.004 87 11553 0.5000 0.5230
83 1,1,1,2-Tetrachloroethane 131 7.820 7.837 -0.017 22 3440 0.5000 0.5361 M
84 Ethylbenzene 106 7.833 7.841 -0.009 97 6725 0.5000 0.5387
85 m-Xylene & p-Xylene 106 7.957 7.957 0.000 0 2249 0.5000 0.4813
86 o-Xylene 106 8.318 8.318 0.000 90 7435 0.5000 0.5000
87 Styrene 104 8.338 8.335 0.003 80 12911 0.5000 0.5234 M
88 Bromoform 173 8.515 8.511 0.004 12 1889 0.5000 0.4185
89 Isopropylbenzene 105 8.660 8.656 0.004 95 17967 0.5000 0.5480
91 Cyclohexanone 55 8.764 8.756 0.008 98 30352 15.0 15.8
92 1,1,2,2-Tetrachloroethane 83 8.945 8.945 0.000 25 5825 0.5000 0.4737 M
93 Bromobenzene 156 8.981 8.981 0.000 94 4093 0.5000 0.4987
94 trans-1,4-Dichloro-2-butene 53 8.985 8.985 0.000 51 1628 0.5000 0.5554
95 1,2,3-Trichloropropane 110 9.013 9.009 0.004 53 2414 0.5000 0.5702 M
96 N-Propylbenzene 120 9.065 9.057 0.008 99 5176 0.5000 0.5492 M
97 2-Chlorotoluene 126 9.154 9.158 -0.004 95 4901 0.5000 0.6045 M
98 1,3,5-Trimethylbenzene 105 9.226 9.230 -0.004 95 15552 0.5000 0.5435
99 4-Chlorotoluene 126 9.278 9.274 0.004 94 5551 0.5000 0.6508
11/15/2024
3:53:55 PM
Page 514 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
100 tert-Butylbenzene 119 9.543 9.539 0.004 92 13149 0.5000 0.5573
102 1,2,4-Trimethylbenzene 105 9.599 9.599 0.000 94 16901 0.5000 0.5621
103 sec-Butylbenzene 134 9.752 9.756 -0.004 94 3669 0.5000 0.5319 M
104 1,3-Dichlorobenzene 146 9.888 9.888 0.000 88 8440 0.5000 0.5418
105 4-Isopropyltoluene 119 9.908 9.901 0.008 93 15622 0.5000 0.5387
106 1,4-Dichlorobenzene 146 9.993 9.989 0.004 69 9036 0.5000 0.5593 M
108 n-Butylbenzene 91 10.310 10.310 0.000 97 15349 0.5000 0.5662
109 1,2-Dichlorobenzene 146 10.346 10.346 0.000 71 9026 0.5000 0.5816 M
110 1,2-Dibromo-3-Chloropropane 157 11.129 11.125 0.004 5 2030 0.5000 0.5410 M
112 1,2,4-Trichlorobenzene 180 11.944 11.948 -0.004 90 5137 0.5000 0.5466
113 Hexachlorobutadiene 225 12.085 12.089 -0.004 81 2335 0.5000 0.7648
114 Naphthalene 128 12.221 12.221 0.000 96 22131 0.5000 0.4827
115 1,2,3-Trichlorobenzene 180 12.446 12.442 0.004 87 5825 0.5000 0.4957
S 122 1,2-Dichloroethene, Total (URS) 96 0 1.00 1.12
S 129 1,2-Dichloroethene, Total 1 0 1.00 1.12
S 123 Xylenes, Total (URS) 1 0 1.00 0.9813
S 127 Trihalomethanes, Total 1 0 2.00 1.87
S 125 Xylenes, Total 106 0 1.00 0.9813
S 126 Total BTEX 1 0 2.57
S 124 1,3-Dichloropropene, Total 1 0 1.00 0.9291
QC Flag Legend
Processing Flags
Review Flags
M - Manually Integrated
a - User Assigned ID
Reagents:
Cal Dil Std_00426 Amount Added: 5.00 Units: uL
mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 515 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4 Operator ID:CF
Lims ID:ic Worklist Smp#:43
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:10
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
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11/15/2024
3:53:55 PM
Page 516 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
11 Vinyl chloride, CAS: 75-01-4
Signal: 1
Processing Integration Results
RT: 2.04
Area: 4240
Amount: 0.387528
Amount Units: ug/l
1.7 1.9 2.1 2.3
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
45
Y ( X
1
0
0
)
m/z 62.0

2
.
0
3
8
Manual Integration Results
RT: 2.04
Area: 4825
Amount: 0.439006
Amount Units: ug/l
1.7 1.9 2.1 2.3
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
Y ( X
1
0
0
)
m/z 62.0

2
.
0
3
8
Reviewer: AK2J, 29-Oct-2024 20:19:22 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 517 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
12 Bromomethane, CAS: 74-83-9
Signal: 1
Processing Integration Results
RT: 2.32
Area: 3250
Amount: 0.396190
Amount Units: ug/l
2.0 2.2 2.4 2.6
Min
0
3
6
9
12
15
18
21
24
27
30
33
Y ( X
1
0
0
)
m/z 94.0

2
.
3
1
9
Manual Integration Results
RT: 2.32
Area: 4926
Amount: 0.498976
Amount Units: ug/l
2.0 2.2 2.4 2.6
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
Y ( X
1
0
0
)
m/z 94.0

2
.
3
1
9
Reviewer: AK2J, 29-Oct-2024 20:19:29 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 518 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
21 1,1-Dichloroethene, CAS: 75-35-4
Signal: 1
Processing Integration Results
RT: 3.04
Area: 2488
Amount: 0.378366
Amount Units: ug/l
2.7 2.9 3.1 3.3
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
Y ( X
1
0
0
)
m/z 96.0

3
.
0
3
8
Manual Integration Results
RT: 3.05
Area: 4211
Amount: 0.602257
Amount Units: ug/l
2.7 2.9 3.1 3.3
Min
RT
0
3
6
9
12
15
18
21
24
27
30
Y ( X
1
0
0
)
m/z 96.0

3
.
0
5
0
Reviewer: AK2J, 29-Oct-2024 20:19:41 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 519 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
24 Iodomethane, CAS: 74-88-4
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 3.17
2.8 3.0 3.2 3.4
Min
0
2
4
6
8
10
12
14
16
Y ( X
1
0
0
)
m/z 142.0
Manual Integration Results
RT: 3.17
Area: 2132
Amount: -0.104578
Amount Units: ug/l
2.8 3.0 3.2 3.4
Min
RT
0
2
4
6
8
10
12
14
16
Y ( X
1
0
0
)
m/z 142.0

3
.
1
7
5
Reviewer: AK2J, 29-Oct-2024 20:49:44 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 520 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
32 Methyl tert-butyl ether, CAS: 1634-04-4
Signal: 1
Processing Integration Results
RT: 3.60
Area: 13108
Amount: 0.442292
Amount Units: ug/l
3.3 3.5 3.7 3.9
Min
0
6
12
18
24
30
36
42
48
54
60
66
72
78
84
Y ( X
1
0
0
)
m/z 73.0

3
.
5
9
6
Manual Integration Results
RT: 3.60
Area: 15165
Amount: 0.502553
Amount Units: ug/l
3.3 3.5 3.7 3.9
Min
RT
0
7
14
21
28
35
42
49
56
63
70
77
84
Y ( X
1
0
0
)
m/z 73.0

3
.
5
9
6
Reviewer: AK2J, 29-Oct-2024 20:19:56 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 521 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
42 cis-1,2-Dichloroethene, CAS: 156-59-2
Signal: 1
Processing Integration Results
RT: 4.35
Area: 4173
Amount: 0.481685
Amount Units: ug/l
4.0 4.2 4.4 4.6
Min
0
3
6
9
12
15
18
21
24
27
30
33
Y ( X
1
0
0
)
m/z 96.0

4
.
3
5
1
Manual Integration Results
RT: 4.35
Area: 5215
Amount: 0.583203
Amount Units: ug/l
4.0 4.2 4.4 4.6
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
Y ( X
1
0
0
)
m/z 96.0

4
.
3
5
1
Reviewer: AK2J, 29-Oct-2024 20:20:07 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 522 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
43 2,2-Dichloropropane, CAS: 594-20-7
Signal: 1
Processing Integration Results
RT: 4.36
Area: 4527
Amount: 0.357353
Amount Units: ug/l
4.0 4.2 4.4 4.6
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
Y ( X
1
0
0
)
m/z 77.0

4
.
3
6
3
Manual Integration Results
RT: 4.36
Area: 7633
Amount: 0.567989
Amount Units: ug/l
4.0 4.2 4.4 4.6
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
48
Y ( X
1
0
0
)
m/z 77.0

4
.
3
6
3
Reviewer: AK2J, 29-Oct-2024 20:20:15 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 523 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
50 1,1,1-Trichloroethane, CAS: 71-55-6
Signal: 1
Processing Integration Results
RT: 4.73
Area: 3604
Amount: 0.338595
Amount Units: ug/l
4.4 4.6 4.8 5.0
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
Y ( X
1
0
0
)
m/z 97.0

4
.
7
3
3
Manual Integration Results
RT: 4.73
Area: 4998
Amount: 0.453718
Amount Units: ug/l
4.4 4.6 4.8 5.0
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
Y ( X
1
0
0
)
m/z 97.0

4
.
7
3
3
Reviewer: AK2J, 29-Oct-2024 20:20:28 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 524 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
53 Carbon tetrachloride, CAS: 56-23-5
Signal: 1
Processing Integration Results
RT: 4.85
Area: 3094
Amount: 0.375006
Amount Units: ug/l
4.5 4.7 4.9 5.1
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
Y ( X
1
0
0
)
m/z 117.0

4
.
8
4
9
Manual Integration Results
RT: 4.85
Area: 4266
Amount: 0.498451
Amount Units: ug/l
4.5 4.7 4.9 5.1
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
39
Y ( X
1
0
0
)
m/z 117.0

4
.
8
4
9
Reviewer: AK2J, 29-Oct-2024 20:20:40 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 525 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
56 1,2-Dichloroethane, CAS: 107-06-2
Signal: 1
Processing Integration Results
RT: 5.03
Area: 5184
Amount: 0.400346
Amount Units: ug/l
4.7 4.9 5.1 5.3
Min
0
2
4
6
8
10
12
14
16
18
20
Y ( X
1
0
0
0
)
m/z 62.0

5
.
0
3
0
Manual Integration Results
RT: 5.03
Area: 7114
Amount: 0.530456
Amount Units: ug/l
4.7 4.9 5.1 5.3
Min
RT
0
2
4
6
8
10
12
14
16
18
20
Y ( X
1
0
0
0
)
m/z 62.0

5
.
0
3
0
Reviewer: AK2J, 29-Oct-2024 20:20:48 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 526 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
58 n-Heptane, CAS: 142-82-5
Signal: 1
Processing Integration Results
RT: 5.17
Area: 6749
Amount: 0.447761
Amount Units: ug/l
4.8 5.0 5.2 5.4
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
52
Y ( X
1
0
0
)
m/z 43.0

5
.
1
7
4
Manual Integration Results
RT: 5.17
Area: 10314
Amount: 0.651607
Amount Units: ug/l
4.8 5.0 5.2 5.4
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
48
52
Y ( X
1
0
0
)
m/z 43.0

5
.
1
7
4
Reviewer: AK2J, 29-Oct-2024 20:20:58 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 527 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
60 Trichloroethene, CAS: 79-01-6
Signal: 1
Processing Integration Results
RT: 5.48
Area: 2635
Amount: 0.322327
Amount Units: ug/l
5.2 5.4 5.6 5.8
Min
0
5
10
15
20
25
30
35
40
45
50
55
60
65
Y ( X
1
0
0
)
m/z 95.0

5
.
4
8
4
Manual Integration Results
RT: 5.48
Area: 4471
Amount: 0.515698
Amount Units: ug/l
5.2 5.4 5.6 5.8
Min
RT
0
5
10
15
20
25
30
35
40
45
50
55
60
65
Y ( X
1
0
0
)
m/z 95.0

5
.
4
8
4
Reviewer: AK2J, 29-Oct-2024 20:21:08 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 528 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
63 1,2-Dichloropropane, CAS: 78-87-5
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 5.69
5.4 5.6 5.8 6.0
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
Y ( X
1
0
0
)
m/z 63.0
Manual Integration Results
RT: 5.69
Area: 6027
Amount: 0.554441
Amount Units: ug/l
5.4 5.6 5.8 6.0
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
48
Y ( X
1
0
0
)
m/z 63.0

5
.
6
8
8
Reviewer: AK2J, 29-Oct-2024 20:21:16 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 529 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
73 trans-1,3-Dichloropropene, CAS: 10061-02-6
Signal: 1
Processing Integration Results
RT: 6.70
Area: 4845
Amount: 0.360536
Amount Units: ug/l
6.4 6.6 6.8 7.0
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
Y ( X
1
0
0
)
m/z 75.0

6
.
6
9
6
Manual Integration Results
RT: 6.70
Area: 6201
Amount: 0.452315
Amount Units: ug/l
6.4 6.6 6.8 7.0
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
Y ( X
1
0
0
)
m/z 75.0

6
.
6
9
6
Reviewer: AK2J, 29-Oct-2024 20:21:32 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 530 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
79 Chlorodibromomethane, CAS: 124-48-1
Signal: 1
Processing Integration Results
RT: 7.21
Area: 2369
Amount: 0.374950
Amount Units: ug/l
6.9 7.1 7.3 7.5
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
Y ( X
1
0
0
)
m/z 129.0

7
.
2
1
0
Manual Integration Results
RT: 7.21
Area: 2990
Amount: 0.463010
Amount Units: ug/l
6.9 7.1 7.3 7.5
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
Y ( X
1
0
0
)
m/z 129.0

7
.
2
1
0
Reviewer: AK2J, 29-Oct-2024 20:21:41 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 531 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
81 1-Chlorohexane, CAS: 544-10-5
Signal: 1
Processing Integration Results
RT: 7.72
Area: 4070
Amount: 0.353140
Amount Units: ug/l
7.4 7.6 7.8 8.0
Min
0
2
4
6
8
10
12
14
16
Y ( X
1
0
0
0
)
m/z 91.0

7
.
7
1
6
Manual Integration Results
RT: 7.72
Area: 7337
Amount: 0.428057
Amount Units: ug/l
7.4 7.6 7.8 8.0
Min
RT
0
2
4
6
8
10
12
14
16
Y ( X
1
0
0
0
)
m/z 91.0

7
.
7
1
6
Reviewer: AK2J, 29-Oct-2024 20:21:56 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 532 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
83 1,1,1,2-Tetrachloroethane, CAS: 630-20-6
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 7.84
7.5 7.7 7.9 8.1
Min
0
2
4
6
8
10
12
14
16
18
20
Y ( X
1
0
0
)
m/z 131.0
Manual Integration Results
RT: 7.82
Area: 3440
Amount: 0.536108
Amount Units: ug/l
7.5 7.7 7.9 8.1
Min
RT
0
2
4
6
8
10
12
14
16
18
20
Y ( X
1
0
0
)
m/z 131.0

7
.
8
2
0
Reviewer: AK2J, 29-Oct-2024 20:22:06 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 533 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
87 Styrene, CAS: 100-42-5
Signal: 1
Processing Integration Results
RT: 8.34
Area: 7275
Amount: 0.310629
Amount Units: ug/l
8.0 8.2 8.4 8.6
Min
0
6
12
18
24
30
36
42
48
54
60
66
72
78
Y ( X
1
0
0
)
m/z 104.0

8
.
3
3
8
Manual Integration Results
RT: 8.34
Area: 12911
Amount: 0.523383
Amount Units: ug/l
8.0 8.2 8.4 8.6
Min
RT
0
6
12
18
24
30
36
42
48
54
60
66
72
78
Y ( X
1
0
0
)
m/z 104.0

8
.
3
3
8
Reviewer: AK2J, 29-Oct-2024 20:22:18 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 534 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
92 1,1,2,2-Tetrachloroethane, CAS: 79-34-5
Signal: 1
Processing Integration Results
RT: 8.94
Area: 4390
Amount: 0.361818
Amount Units: ug/l
8.6 8.8 9.0 9.2
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
Y ( X
1
0
0
)
m/z 83.0

8
.
9
4
5
Manual Integration Results
RT: 8.94
Area: 5825
Amount: 0.473680
Amount Units: ug/l
8.6 8.8 9.0 9.2
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
Y ( X
1
0
0
)
m/z 83.0

8
.
9
4
5
Reviewer: AK2J, 29-Oct-2024 20:22:28 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 535 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
95 1,2,3-Trichloropropane, CAS: 96-18-4
Signal: 1
Processing Integration Results
RT: 9.01
Area: 1747
Amount: 0.428971
Amount Units: ug/l
8.7 8.9 9.1 9.3
Min
0
2
4
6
8
10
12
14
16
18
20
22
Y ( X
1
0
0
)
m/z 110.0

9
.
0
1
3
Manual Integration Results
RT: 9.01
Area: 2414
Amount: 0.570184
Amount Units: ug/l
8.7 8.9 9.1 9.3
Min
RT
0
2
4
6
8
10
12
14
16
18
20
22
Y ( X
1
0
0
)
m/z 110.0

9
.
0
1
3
Reviewer: AK2J, 29-Oct-2024 20:22:36 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 536 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
96 N-Propylbenzene, CAS: 103-65-1
Signal: 1
Processing Integration Results
RT: 9.07
Area: 2812
Amount: 0.315915
Amount Units: ug/l
8.7 8.9 9.1 9.3
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
52
Y ( X
1
0
0
)
m/z 120.0

9
.
0
6
5
Manual Integration Results
RT: 9.07
Area: 5176
Amount: 0.549211
Amount Units: ug/l
8.7 8.9 9.1 9.3
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
48
52
Y ( X
1
0
0
)
m/z 120.0

9
.
0
6
5
Reviewer: AK2J, 29-Oct-2024 20:22:45 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 537 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
97 2-Chlorotoluene, CAS: 95-49-8
Signal: 1
Processing Integration Results
RT: 9.15
Area: 3396
Amount: 0.436446
Amount Units: ug/l
8.8 9.0 9.2 9.4
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
Y ( X
1
0
0
)
m/z 126.0

9
.
1
5
4
Manual Integration Results
RT: 9.15
Area: 4901
Amount: 0.604491
Amount Units: ug/l
8.8 9.0 9.2 9.4
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
39
Y ( X
1
0
0
)
m/z 126.0

9
.
1
5
4
Reviewer: AK2J, 29-Oct-2024 20:22:54 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 538 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
103 sec-Butylbenzene, CAS: 135-98-8
Signal: 1
Processing Integration Results
RT: 9.75
Area: 2099
Amount: 0.320419
Amount Units: ug/l
9.4 9.6 9.8 10.0
Min
0
3
6
9
12
15
18
21
24
27
30
33
Y ( X
1
0
0
)
m/z 134.0

9
.
7
5
2
Manual Integration Results
RT: 9.75
Area: 3669
Amount: 0.531879
Amount Units: ug/l
9.4 9.6 9.8 10.0
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
Y ( X
1
0
0
)
m/z 134.0

9
.
7
5
2
Reviewer: AK2J, 29-Oct-2024 20:23:11 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 539 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
106 1,4-Dichlorobenzene, CAS: 106-46-7
Signal: 1
Processing Integration Results
RT: 9.98
Area: 4591
Amount: 0.348457
Amount Units: ug/l
9.7 9.9 10.1 10.3
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
52
Y ( X
1
0
0
)
m/z 146.0

9
.
9
7
7
Manual Integration Results
RT: 9.99
Area: 9036
Amount: 0.559303
Amount Units: ug/l
9.7 9.9 10.1 10.3
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
48
52
Y ( X
1
0
0
)
m/z 146.0

9
.
9
9
3
Reviewer: AK2J, 29-Oct-2024 20:23:23 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 540 of 777
Report Date: 29-Oct-2024 21:08:50 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
109 1,2-Dichlorobenzene, CAS: 95-50-1
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 10.35
10.0 10.2 10.4 10.6
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
52
56
Y ( X
1
0
0
)
m/z 146.0
Manual Integration Results
RT: 10.35
Area: 9026
Amount: 0.581556
Amount Units: ug/l
10.0 10.2 10.4 10.6
Min
RT
0
5
10
15
20
25
30
35
40
45
50
55
Y ( X
1
0
0
)
m/z 146.0
1
0
.
3
4
6
Reviewer: AK2J, 29-Oct-2024 20:23:31 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 541 of 777
Report Date: 29-Oct-2024 21:08:51 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Injection Date:29-Oct-2024 20:00:30 Instrument ID:VMS_X4
Lims ID:ic
Client ID:
Operator ID:CF ALS Bottle#:10 Worklist Smp#:43
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
110 1,2-Dibromo-3-Chloropropane, CAS: 96-12-8
Signal: 1
Processing Integration Results
RT: 11.13
Area: 1335
Amount: 0.374600
Amount Units: ug/l
10.8 11.0 11.2
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
Y ( X
1
0
0
)
m/z 157.0
1
1
.
1
2
9
Manual Integration Results
RT: 11.13
Area: 2030
Amount: 0.540966
Amount Units: ug/l
10.8 11.0 11.2
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
12
13
Y ( X
1
0
0
)
m/z 157.0
1
1
.
1
2
9
Reviewer: AK2J, 29-Oct-2024 20:23:40 -06:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
11/15/2024
3:53:55 PM
Page 542 of 777
Calibration / Dichlorodifluoromethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2857
Error Coefficients
Relative Standard Deviation:7.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.123788 50.0 1702505.0 0.247576 Y
2 IC 280-672931/42 1.0 0.310746 50.0 1594549.0 0.310746 Y
3 IC 280-672931/41 2.0 0.535623 50.0 1599819.0 0.267812 Y
4 IC 280-672931/40 5.0 1.494033 50.0 1578144.0 0.298807 Y
5 IC 280-672931/39 10.0 2.980236 50.0 1612993.0 0.298024 Y
6 ICIS 280-672931/38 50.0 14.241491 50.0 1661687.0 0.28483 Y
7 IC 280-672931/37 75.0 19.864172 50.0 1605924.0 0.264856 Y
8 IC 280-672931/36 100.0 30.441342 50.0 1556436.0 0.304413 Y
9 IC 280-672931/35 200.0 58.863065 50.0 1617392.0 0.294315 Y
RelResp = [0.2857]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
IC 280-672931/35
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Page 543 of 777
Calibration / Chloromethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4254
Error Coefficients
Relative Standard Deviation:7.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.229192 50.0 1702505.0 0.458383 Y
2 IC 280-672931/42 1.0 0.475965 50.0 1594549.0 0.475965 Y
3 IC 280-672931/41 2.0 0.84919 50.0 1599819.0 0.424595 Y
4 IC 280-672931/40 5.0 2.188995 50.0 1578144.0 0.437799 Y
5 IC 280-672931/39 10.0 4.275809 50.0 1612993.0 0.427581 Y
6 ICIS 280-672931/38 50.0 19.547243 50.0 1661687.0 0.390945 Y
7 IC 280-672931/37 75.0 29.044868 50.0 1605924.0 0.387265 Y
8 IC 280-672931/36 100.0 43.310518 50.0 1556436.0 0.433105 Y
9 IC 280-672931/35 200.0 78.620489 50.0 1617392.0 0.393102 Y
RelResp = [0.4254]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
11/15/2024
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Page 544 of 777
Calibration / Vinyl chloride
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3228
Error Coefficients
Relative Standard Deviation:6.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.141703 50.0 1702505.0 0.283406 Y
2 IC 280-672931/42 1.0 0.310213 50.0 1594549.0 0.310213 Y
3 IC 280-672931/41 2.0 0.663575 50.0 1599819.0 0.331788 Y
4 IC 280-672931/40 5.0 1.575205 50.0 1578144.0 0.315041 Y
5 IC 280-672931/39 10.0 3.509625 50.0 1612993.0 0.350962 Y
6 ICIS 280-672931/38 50.0 15.924118 50.0 1661687.0 0.318482 Y
7 IC 280-672931/37 75.0 23.783068 50.0 1605924.0 0.317108 Y
8 IC 280-672931/36 100.0 34.508615 50.0 1556436.0 0.345086 Y
9 IC 280-672931/35 200.0 66.588836 50.0 1617392.0 0.332944 Y
RelResp = [0.3228]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 545 of 777
Calibration / Bromomethane
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.09291
Slope:0.1037
Error Coefficients
Relative Standard Deviation:4.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.144669 50.0 1702505.0 0.289338 Y
2 IC 280-672931/42 1.0 0.197705 50.0 1594549.0 0.197705 Y
3 IC 280-672931/41 2.0 0.300784 50.0 1599819.0 0.150392 Y
4 IC 280-672931/40 5.0 0.574029 50.0 1578144.0 0.114806 Y
5 IC 280-672931/39 10.0 1.209336 50.0 1612993.0 0.120934 Y
6 ICIS 280-672931/38 50.0 5.223216 50.0 1661687.0 0.104464 Y
7 IC 280-672931/37 75.0 7.86516 50.0 1605924.0 0.104869 Y
8 IC 280-672931/36 100.0 10.445274 50.0 1556436.0 0.104453 Y
9 IC 280-672931/35 200.0 13.207961 50.0 1617392.0 0.06604 N
RelResp = [0.09291] + [0.1037]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
Intercept = -0.896
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Page 546 of 777
Calibration / Chloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2112
Error Coefficients
Relative Standard Deviation:6.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.113362 50.0 1702505.0 0.226725 Y
2 IC 280-672931/42 1.0 0.187545 50.0 1594549.0 0.187545 Y
3 IC 280-672931/41 2.0 0.462115 50.0 1599819.0 0.231057 Y
4 IC 280-672931/40 5.0 1.076296 50.0 1578144.0 0.215259 Y
5 IC 280-672931/39 10.0 2.113431 50.0 1612993.0 0.211343 Y
6 ICIS 280-672931/38 50.0 10.292341 50.0 1661687.0 0.205847 Y
7 IC 280-672931/37 75.0 15.082999 50.0 1605924.0 0.201107 Y
8 IC 280-672931/36 100.0 21.522504 50.0 1556436.0 0.215225 Y
9 IC 280-672931/35 200.0 41.398653 50.0 1617392.0 0.206993 Y
RelResp = [0.2112]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
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Page 547 of 777
Calibration / Dichlorofluoromethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5005
Error Coefficients
Relative Standard Deviation:5.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.269133 50.0 1702505.0 0.538266 Y
2 IC 280-672931/42 1.0 0.471763 50.0 1594549.0 0.471763 Y
3 IC 280-672931/41 2.0 0.903946 50.0 1599819.0 0.451973 Y
4 IC 280-672931/40 5.0 2.517673 50.0 1578144.0 0.503535 Y
5 IC 280-672931/39 10.0 5.242645 50.0 1612993.0 0.524265 Y
6 ICIS 280-672931/38 50.0 24.769135 50.0 1661687.0 0.495383 Y
7 IC 280-672931/37 75.0 35.952947 50.0 1605924.0 0.479373 Y
8 IC 280-672931/36 100.0 52.979692 50.0 1556436.0 0.529797 Y
9 IC 280-672931/35 200.0 102.009068 50.0 1617392.0 0.510045 Y
RelResp = [0.5005]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
IC 280-672931/35
11/15/2024
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Page 548 of 777
Calibration / Trichlorofluoromethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3038
Error Coefficients
Relative Standard Deviation:5.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.164493 50.0 1702505.0 0.328986 Y
2 IC 280-672931/42 1.0 0.309492 50.0 1594549.0 0.309492 Y
3 IC 280-672931/41 2.0 0.558032 50.0 1599819.0 0.279016 Y
4 IC 280-672931/40 5.0 1.554579 50.0 1578144.0 0.310916 Y
5 IC 280-672931/39 10.0 3.146697 50.0 1612993.0 0.31467 Y
6 ICIS 280-672931/38 50.0 14.5324 50.0 1661687.0 0.290648 Y
7 IC 280-672931/37 75.0 20.831123 50.0 1605924.0 0.277748 Y
8 IC 280-672931/36 100.0 31.432259 50.0 1556436.0 0.314323 Y
9 IC 280-672931/35 200.0 61.682047 50.0 1617392.0 0.30841 Y
RelResp = [0.3038]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
IC 280-672931/35
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Page 549 of 777
Calibration / Ethyl ether
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2809
Error Coefficients
Relative Standard Deviation:9.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.171776 50.0 1702505.0 0.343553 Y
2 IC 280-672931/42 1.0 0.281271 50.0 1594549.0 0.281271 Y
3 IC 280-672931/41 2.0 0.528904 50.0 1599819.0 0.264452 Y
4 IC 280-672931/40 5.0 1.260436 50.0 1578144.0 0.252087 Y
5 IC 280-672931/39 10.0 2.933491 50.0 1612993.0 0.293349 Y
6 ICIS 280-672931/38 50.0 13.67213 50.0 1661687.0 0.273443 Y
7 IC 280-672931/37 75.0 20.706615 50.0 1605924.0 0.276088 Y
8 IC 280-672931/36 100.0 27.581475 50.0 1556436.0 0.275815 Y
9 IC 280-672931/35 200.0 53.575664 50.0 1617392.0 0.267878 Y
RelResp = [0.2809]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
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Page 550 of 777
Calibration / Acrolein
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.06586
Slope:0.08454
Error Coefficients
Relative Standard Deviation:4.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 4.9375 0.501203 50.0 1702505.0 0.101509 Y
2 IC 280-672931/42 9.875 0.866515 50.0 1594549.0 0.087748 Y
3 IC 280-672931/41 19.75 1.59243 50.0 1599819.0 0.080629 Y
4 IC 280-672931/40 49.375 4.083151 50.0 1578144.0 0.082697 Y
5 IC 280-672931/39 98.75 8.803386 50.0 1612993.0 0.089148 Y
6 ICIS 280-672931/38 493.75 41.576181 50.0 1661687.0 0.084205 Y
7 IC 280-672931/37 740.625 64.393458 50.0 1605924.0 0.086945 Y
8 IC 280-672931/36 987.5 86.536388 50.0 1556436.0 0.087632 Y
9 IC 280-672931/35 1975.0 169.860368 50.0 1617392.0 0.086005 Y
RelResp = [0.06586] + [0.08454]x
Concentration
0 1000 2000
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
Intercept = -0.779
11/15/2024
3:53:55 PM
Page 551 of 777
Calibration / 1,1,2-Trichloro-1,2,2-trifluoroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1415
Error Coefficients
Relative Standard Deviation:5.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.075183 50.0 1702505.0 0.150367 Y
2 IC 280-672931/42 1.0 0.139632 50.0 1594549.0 0.139632 Y
3 IC 280-672931/41 2.0 0.308754 50.0 1599819.0 0.154377 Y
4 IC 280-672931/40 5.0 0.696198 50.0 1578144.0 0.13924 Y
5 IC 280-672931/39 10.0 1.31535 50.0 1612993.0 0.131535 Y
6 ICIS 280-672931/38 50.0 6.83456 50.0 1661687.0 0.136691 Y
7 IC 280-672931/37 75.0 10.13127 50.0 1605924.0 0.135084 Y
8 IC 280-672931/36 100.0 14.670311 50.0 1556436.0 0.146703 Y
9 IC 280-672931/35 200.0 27.889961 50.0 1617392.0 0.13945 Y
RelResp = [0.1415]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
11/15/2024
3:53:55 PM
Page 552 of 777
Calibration / 1,1-Dichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2053
Error Coefficients
Relative Standard Deviation:9.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.123671 50.0 1702505.0 0.247341 Y
2 IC 280-672931/42 1.0 0.172212 50.0 1594549.0 0.172212 Y
3 IC 280-672931/41 2.0 0.421829 50.0 1599819.0 0.210914 Y
4 IC 280-672931/40 5.0 1.037041 50.0 1578144.0 0.207408 Y
5 IC 280-672931/39 10.0 1.955309 50.0 1612993.0 0.195531 Y
6 ICIS 280-672931/38 50.0 9.760111 50.0 1661687.0 0.195202 Y
7 IC 280-672931/37 75.0 15.015281 50.0 1605924.0 0.200204 Y
8 IC 280-672931/36 100.0 20.968064 50.0 1556436.0 0.209681 Y
9 IC 280-672931/35 200.0 41.922954 50.0 1617392.0 0.209615 Y
RelResp = [0.2053]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 553 of 777
Calibration / Acetone
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:2.697
Slope:0.3158
Error Coefficients
Relative Standard Deviation:5.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 2.0 3.837845 50.0 1702505.0 1.918922 N
2 IC 280-672931/42 4.0 4.88044 50.0 1594549.0 1.22011 N
3 IC 280-672931/41 8.0 5.211871 50.0 1599819.0 0.651484 Y
4 IC 280-672931/40 20.0 8.803506 50.0 1578144.0 0.440175 Y
5 IC 280-672931/39 40.0 16.571492 50.0 1612993.0 0.414287 Y
6 ICIS 280-672931/38 200.0 63.599011 50.0 1661687.0 0.317995 Y
7 IC 280-672931/37 300.0 95.927703 50.0 1605924.0 0.319759 Y
8 IC 280-672931/36 400.0 129.335096 50.0 1556436.0 0.323338 Y
9 IC 280-672931/35 800.0 252.386465 50.0 1617392.0 0.315483 Y
RelResp = [2.697] + [0.3158]x
Concentration
0 100 200 300 400 500 600 700 800
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
Intercept = -8.54
11/15/2024
3:53:55 PM
Page 554 of 777
Calibration / Iodomethane
Curve Type:Quadratic
Weighting:None
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.06996
Slope:0.07035
Second Order:0.0007699
Error Coefficients
Relative Standard Deviation:14.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.062614 50.0 1702505.0 0.125227 N
2 IC 280-672931/42 1.0 0.090621 50.0 1594549.0 0.090621 N
3 IC 280-672931/41 2.0 0.18349 50.0 1599819.0 0.091745 Y
4 IC 280-672931/40 5.0 0.403956 50.0 1578144.0 0.080791 Y
5 IC 280-672931/39 10.0 0.943959 50.0 1612993.0 0.094396 Y
6 ICIS 280-672931/38 50.0 5.445219 50.0 1661687.0 0.108904 Y
7 IC 280-672931/37 75.0 9.73477 50.0 1605924.0 0.129797 Y
8 IC 280-672931/36 100.0 14.788433 50.0 1556436.0 0.147884 Y
9 IC 280-672931/35 200.0 30.446701 50.0 1617392.0 0.152234 N
RelResp = [0.06996] + [0.07035]x + [0.0007699]x^2
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
Intercept = -1.01
11/15/2024
3:53:55 PM
Page 555 of 777
Calibration / Carbon disulfide
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.1874
Slope:0.7552
Error Coefficients
Relative Standard Deviation:3.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.576445 50.0 1702505.0 1.152889 Y
2 IC 280-672931/42 1.0 0.921358 50.0 1594549.0 0.921358 Y
3 IC 280-672931/41 2.0 1.601369 50.0 1599819.0 0.800684 Y
4 IC 280-672931/40 5.0 3.90183 50.0 1578144.0 0.780366 Y
5 IC 280-672931/39 10.0 7.921547 50.0 1612993.0 0.792155 Y
6 ICIS 280-672931/38 50.0 37.242694 50.0 1661687.0 0.744854 Y
7 IC 280-672931/37 75.0 56.797551 50.0 1605924.0 0.757301 Y
8 IC 280-672931/36 100.0 79.10563 50.0 1556436.0 0.791056 Y
9 IC 280-672931/35 200.0 155.490042 50.0 1617392.0 0.77745 Y
RelResp = [0.1874] + [0.7552]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
IC 280-672931/35
Intercept = -0.248
11/15/2024
3:53:55 PM
Page 556 of 777
Calibration / Methyl acetate
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6295
Error Coefficients
Relative Standard Deviation:4.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 1.0 0.652127 50.0 1702505.0 0.652127 Y
2 IC 280-672931/42 2.0 1.183689 50.0 1594549.0 0.591844 Y
3 IC 280-672931/41 4.0 2.336858 50.0 1599819.0 0.584215 Y
4 IC 280-672931/40 10.0 6.033131 50.0 1578144.0 0.603313 Y
5 IC 280-672931/39 20.0 13.268346 50.0 1612993.0 0.663417 Y
6 ICIS 280-672931/38 100.0 61.96525 50.0 1661687.0 0.619652 Y
7 IC 280-672931/37 150.0 96.263802 50.0 1605924.0 0.641759 Y
8 IC 280-672931/36 200.0 129.737651 50.0 1556436.0 0.648688 Y
9 IC 280-672931/35 400.0 264.351406 50.0 1617392.0 0.660879 Y
RelResp = [0.6295]x
Concentration
0 100 200 300 400
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 557 of 777
Calibration / 3-Chloro-1-propene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6492
Error Coefficients
Relative Standard Deviation:4.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.346078 50.0 1702505.0 0.692157 Y
2 IC 280-672931/42 1.0 0.589352 50.0 1594549.0 0.589352 Y
3 IC 280-672931/41 2.0 1.232046 50.0 1599819.0 0.616023 Y
4 IC 280-672931/40 5.0 3.285727 50.0 1578144.0 0.657145 Y
5 IC 280-672931/39 10.0 6.660692 50.0 1612993.0 0.666069 Y
6 ICIS 280-672931/38 50.0 33.026737 50.0 1661687.0 0.660535 Y
7 IC 280-672931/37 75.0 49.757336 50.0 1605924.0 0.663431 Y
8 IC 280-672931/36 100.0 66.949043 50.0 1556436.0 0.66949 Y
9 IC 280-672931/35 200.0 125.666505 50.0 1617392.0 0.628333 Y
RelResp = [0.6492]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
11/15/2024
3:53:55 PM
Page 558 of 777
Calibration / Methylene Chloride
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.1787
Slope:0.263
Error Coefficients
Relative Standard Deviation:6.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.302026 50.0 1702505.0 0.604051 Y
2 IC 280-672931/42 1.0 0.471387 50.0 1594549.0 0.471387 Y
3 IC 280-672931/41 2.0 0.706049 50.0 1599819.0 0.353024 Y
4 IC 280-672931/40 5.0 1.541811 50.0 1578144.0 0.308362 Y
5 IC 280-672931/39 10.0 2.929554 50.0 1612993.0 0.292955 Y
6 ICIS 280-672931/38 50.0 12.514932 50.0 1661687.0 0.250299 Y
7 IC 280-672931/37 75.0 19.450609 50.0 1605924.0 0.259341 Y
8 IC 280-672931/36 100.0 26.240751 50.0 1556436.0 0.262408 Y
9 IC 280-672931/35 200.0 50.556606 50.0 1617392.0 0.252783 Y
RelResp = [0.1787] + [0.263]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
Intercept = -0.680
11/15/2024
3:53:55 PM
Page 559 of 777
Calibration / 2-Methyl-2-propanol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1758
Error Coefficients
Relative Standard Deviation:7.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 5.0 0.936267 50.0 1702505.0 0.187253 Y
2 IC 280-672931/42 10.0 1.699603 50.0 1594549.0 0.16996 Y
3 IC 280-672931/41 20.0 3.179203 50.0 1599819.0 0.15896 Y
4 IC 280-672931/40 50.0 7.848618 50.0 1578144.0 0.156972 Y
5 IC 280-672931/39 100.0 18.361952 50.0 1612993.0 0.18362 Y
6 ICIS 280-672931/38 500.0 84.995189 50.0 1661687.0 0.16999 Y
7 IC 280-672931/37 750.0 134.517574 50.0 1605924.0 0.179357 Y
8 IC 280-672931/36 1000.0 184.506302 50.0 1556436.0 0.184506 Y
9 IC 280-672931/35 2000.0 382.353443 50.0 1617392.0 0.191177 Y
RelResp = [0.1758]x
Concentration
0 1000 2000
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 560 of 777
Calibration / Acrylonitrile
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2939
Error Coefficients
Relative Standard Deviation:6.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 5.0 1.476618 50.0 1702505.0 0.295324 Y
2 IC 280-672931/42 10.0 2.846981 50.0 1594549.0 0.284698 Y
3 IC 280-672931/41 20.0 5.736555 50.0 1599819.0 0.286828 Y
4 IC 280-672931/40 50.0 14.318529 50.0 1578144.0 0.286371 Y
5 IC 280-672931/39 100.0 32.1927 50.0 1612993.0 0.321927 Y
6 ICIS 280-672931/38 500.0 147.038762 50.0 1661687.0 0.294078 Y
7 IC 280-672931/37 750.0 230.212544 50.0 1605924.0 0.30695 Y
8 IC 280-672931/36 1000.0 311.837011 50.0 1556436.0 0.311837 Y
9 IC 280-672931/35 2000.0 513.513669 50.0 1617392.0 0.256757 Y
RelResp = [0.2939]x
Concentration
0 1000 2000
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
11/15/2024
3:53:55 PM
Page 561 of 777
Calibration / Methyl tert-butyl ether
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8862
Error Coefficients
Relative Standard Deviation:4.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.445373 50.0 1702505.0 0.890746 Y
2 IC 280-672931/42 1.0 0.834029 50.0 1594549.0 0.834029 Y
3 IC 280-672931/41 2.0 1.725101 50.0 1599819.0 0.862551 Y
4 IC 280-672931/40 5.0 4.135111 50.0 1578144.0 0.827022 Y
5 IC 280-672931/39 10.0 9.384108 50.0 1612993.0 0.938411 Y
6 ICIS 280-672931/38 50.0 43.826545 50.0 1661687.0 0.876531 Y
7 IC 280-672931/37 75.0 68.248466 50.0 1605924.0 0.90998 Y
8 IC 280-672931/36 100.0 92.677437 50.0 1556436.0 0.926774 Y
9 IC 280-672931/35 200.0 181.990946 50.0 1617392.0 0.909955 Y
RelResp = [0.8862]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37 IC 280-672931/35
11/15/2024
3:53:55 PM
Page 562 of 777
Calibration / trans-1,2-Dichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2336
Error Coefficients
Relative Standard Deviation:3.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.12558 50.0 1702505.0 0.251159 Y
2 IC 280-672931/42 1.0 0.228215 50.0 1594549.0 0.228215 Y
3 IC 280-672931/41 2.0 0.467803 50.0 1599819.0 0.233901 Y
4 IC 280-672931/40 5.0 1.174259 50.0 1578144.0 0.234852 Y
5 IC 280-672931/39 10.0 2.383116 50.0 1612993.0 0.238312 Y
6 ICIS 280-672931/38 50.0 11.135581 50.0 1661687.0 0.222712 Y
7 IC 280-672931/37 75.0 16.799114 50.0 1605924.0 0.223988 Y
8 IC 280-672931/36 100.0 23.768308 50.0 1556436.0 0.237683 Y
9 IC 280-672931/35 200.0 46.395617 50.0 1617392.0 0.231978 Y
RelResp = [0.2336]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
11/15/2024
3:53:55 PM
Page 563 of 777
Calibration / Hexane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.071
Error Coefficients
Relative Standard Deviation:7.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 1.230217 50.0 365464.0 2.460434 Y
2 IC 280-672931/42 1.0 1.997456 50.0 347417.0 1.997456 Y
3 IC 280-672931/41 2.0 3.831857 50.0 353236.0 1.915929 Y
4 IC 280-672931/40 5.0 10.199103 50.0 343741.0 2.039821 Y
5 IC 280-672931/39 10.0 19.382116 50.0 348156.0 1.938212 Y
6 ICIS 280-672931/38 50.0 103.80799 50.0 352929.0 2.07616 Y
7 IC 280-672931/37 75.0 148.377671 50.0 353689.0 1.978369 Y
8 IC 280-672931/36 100.0 212.545787 50.0 345076.0 2.125458 Y
9 IC 280-672931/35 200.0 421.59854 50.0 355024.0 2.107993 Y
RelResp = [2.071]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
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Page 564 of 777
Calibration / Vinyl acetate
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9339
Error Coefficients
Relative Standard Deviation:4.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 1.0 0.894359 50.0 1702505.0 0.894359 Y
2 IC 280-672931/42 2.0 1.77649 50.0 1594549.0 0.888245 Y
3 IC 280-672931/41 4.0 3.584624 50.0 1599819.0 0.896156 Y
4 IC 280-672931/40 10.0 8.782595 50.0 1578144.0 0.87826 Y
5 IC 280-672931/39 20.0 19.868654 50.0 1612993.0 0.993433 Y
6 ICIS 280-672931/38 100.0 95.115626 50.0 1661687.0 0.951156 Y
7 IC 280-672931/37 150.0 141.112033 50.0 1605924.0 0.940747 Y
8 IC 280-672931/36 200.0 197.392087 50.0 1556436.0 0.98696 Y
9 IC 280-672931/35 400.0 390.302135 50.0 1617392.0 0.975755 Y
RelResp = [0.9339]x
Concentration
0 100 200 300 400
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39 ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 565 of 777
Calibration / 1,1-Dichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5291
Error Coefficients
Relative Standard Deviation:3.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.267899 50.0 1702505.0 0.535799 Y
2 IC 280-672931/42 1.0 0.556709 50.0 1594549.0 0.556709 Y
3 IC 280-672931/41 2.0 1.052713 50.0 1599819.0 0.526356 Y
4 IC 280-672931/40 5.0 2.503891 50.0 1578144.0 0.500778 Y
5 IC 280-672931/39 10.0 5.29714 50.0 1612993.0 0.529714 Y
6 ICIS 280-672931/38 50.0 25.572566 50.0 1661687.0 0.511451 Y
7 IC 280-672931/37 75.0 39.383495 50.0 1605924.0 0.525113 Y
8 IC 280-672931/36 100.0 54.609891 50.0 1556436.0 0.546099 Y
9 IC 280-672931/35 200.0 106.002317 50.0 1617392.0 0.530012 Y
RelResp = [0.5291]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 566 of 777
Calibration / 2-Butanone (MEK)
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.7787
Slope:0.5562
Error Coefficients
Relative Standard Deviation:7.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 2.0 1.899055 50.0 1702505.0 0.949527 Y
2 IC 280-672931/42 4.0 3.12891 50.0 1594549.0 0.782227 Y
3 IC 280-672931/41 8.0 4.650995 50.0 1599819.0 0.581374 Y
4 IC 280-672931/40 20.0 11.019147 50.0 1578144.0 0.550957 Y
5 IC 280-672931/39 40.0 25.209037 50.0 1612993.0 0.630226 Y
6 ICIS 280-672931/38 200.0 110.249614 50.0 1661687.0 0.551248 Y
7 IC 280-672931/37 300.0 169.552451 50.0 1605924.0 0.565175 Y
8 IC 280-672931/36 400.0 231.946029 50.0 1556436.0 0.579865 Y
9 IC 280-672931/35 800.0 451.490146 50.0 1617392.0 0.564363 Y
RelResp = [0.7787] + [0.5562]x
Concentration
0 100 200 300 400 500 600 700 800
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
Intercept = -1.40
11/15/2024
3:53:55 PM
Page 567 of 777
Calibration / cis-1,2-Dichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2626
Error Coefficients
Relative Standard Deviation:7.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.153157 50.0 1702505.0 0.306313 Y
2 IC 280-672931/42 1.0 0.280957 50.0 1594549.0 0.280957 Y
3 IC 280-672931/41 2.0 0.503838 50.0 1599819.0 0.251919 Y
4 IC 280-672931/40 5.0 1.227328 50.0 1578144.0 0.245466 Y
5 IC 280-672931/39 10.0 2.580916 50.0 1612993.0 0.258092 Y
6 ICIS 280-672931/38 50.0 12.337522 50.0 1661687.0 0.24675 Y
7 IC 280-672931/37 75.0 19.170708 50.0 1605924.0 0.255609 Y
8 IC 280-672931/36 100.0 25.985457 50.0 1556436.0 0.259855 Y
9 IC 280-672931/35 200.0 51.71149 50.0 1617392.0 0.258557 Y
RelResp = [0.2626]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
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3:53:55 PM
Page 568 of 777
Calibration / 2,2-Dichloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3947
Error Coefficients
Relative Standard Deviation:6.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.22417 50.0 1702505.0 0.448339 Y
2 IC 280-672931/42 1.0 0.375028 50.0 1594549.0 0.375028 Y
3 IC 280-672931/41 2.0 0.744178 50.0 1599819.0 0.372089 Y
4 IC 280-672931/40 5.0 1.885791 50.0 1578144.0 0.377158 Y
5 IC 280-672931/39 10.0 4.016601 50.0 1612993.0 0.40166 Y
6 ICIS 280-672931/38 50.0 19.063488 50.0 1661687.0 0.38127 Y
7 IC 280-672931/37 75.0 29.159381 50.0 1605924.0 0.388792 Y
8 IC 280-672931/36 100.0 40.604689 50.0 1556436.0 0.406047 Y
9 IC 280-672931/35 200.0 80.33405 50.0 1617392.0 0.40167 Y
RelResp = [0.3947]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 569 of 777
Calibration / sec-Butyl Alcohol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1646
Error Coefficients
Relative Standard Deviation:12.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 12.0 1.866837 50.0 1702505.0 0.15557 Y
2 IC 280-672931/42 24.0 3.399613 50.0 1594549.0 0.141651 Y
3 IC 280-672931/41 48.0 6.895124 50.0 1599819.0 0.143648 Y
4 IC 280-672931/40 120.0 18.290695 50.0 1578144.0 0.152422 Y
5 IC 280-672931/39 240.0 44.06383 50.0 1612993.0 0.183599 Y
6 ICIS 280-672931/38 1200.0 210.810971 50.0 1661687.0 0.175676 Y
7 IC 280-672931/37 1800.0 336.61568 50.0 1605924.0 0.187009 Y
8 IC 280-672931/36 2400.0 460.869962 50.0 1556436.0 0.192029 Y
9 IC 280-672931/35 4800.0 718.930538 50.0 1617392.0 0.149777 Y
RelResp = [0.1646]x
Concentration
0 1000 2000 3000 4000 5000
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
11/15/2024
3:53:55 PM
Page 570 of 777
Calibration / Chlorobromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1132
Error Coefficients
Relative Standard Deviation:9.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.059354 50.0 1702505.0 0.118707 Y
2 IC 280-672931/42 1.0 0.131542 50.0 1594549.0 0.131542 Y
3 IC 280-672931/41 2.0 0.253591 50.0 1599819.0 0.126796 Y
4 IC 280-672931/40 5.0 0.514909 50.0 1578144.0 0.102982 Y
5 IC 280-672931/39 10.0 1.138381 50.0 1612993.0 0.113838 Y
6 ICIS 280-672931/38 50.0 5.281229 50.0 1661687.0 0.105625 Y
7 IC 280-672931/37 75.0 8.192698 50.0 1605924.0 0.109236 Y
8 IC 280-672931/36 100.0 10.604002 50.0 1556436.0 0.10604 Y
9 IC 280-672931/35 200.0 20.78587 50.0 1617392.0 0.103929 Y
RelResp = [0.1132]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
11/15/2024
3:53:55 PM
Page 571 of 777
Calibration / Tetrahydrofuran
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3768
Error Coefficients
Relative Standard Deviation:4.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 1.0 0.380498 50.0 1702505.0 0.380498 Y
2 IC 280-672931/42 2.0 0.745916 50.0 1594549.0 0.372958 Y
3 IC 280-672931/41 4.0 1.397783 50.0 1599819.0 0.349446 Y
4 IC 280-672931/40 10.0 3.569066 50.0 1578144.0 0.356907 Y
5 IC 280-672931/39 20.0 8.072013 50.0 1612993.0 0.403601 Y
6 ICIS 280-672931/38 100.0 36.854564 50.0 1661687.0 0.368546 Y
7 IC 280-672931/37 150.0 57.134584 50.0 1605924.0 0.380897 Y
8 IC 280-672931/36 200.0 77.483751 50.0 1556436.0 0.387419 Y
9 IC 280-672931/35 400.0 156.477434 50.0 1617392.0 0.391194 Y
RelResp = [0.3768]x
Concentration
0 100 200 300 400
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 572 of 777
Calibration / Chloroform
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4151
Error Coefficients
Relative Standard Deviation:3.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.216681 50.0 1702505.0 0.433361 Y
2 IC 280-672931/42 1.0 0.422878 50.0 1594549.0 0.422878 Y
3 IC 280-672931/41 2.0 0.857597 50.0 1599819.0 0.428799 Y
4 IC 280-672931/40 5.0 1.940634 50.0 1578144.0 0.388127 Y
5 IC 280-672931/39 10.0 4.189572 50.0 1612993.0 0.418957 Y
6 ICIS 280-672931/38 50.0 19.878022 50.0 1661687.0 0.39756 Y
7 IC 280-672931/37 75.0 30.713595 50.0 1605924.0 0.409515 Y
8 IC 280-672931/36 100.0 42.449416 50.0 1556436.0 0.424494 Y
9 IC 280-672931/35 200.0 82.379689 50.0 1617392.0 0.411898 Y
RelResp = [0.4151]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
11/15/2024
3:53:55 PM
Page 573 of 777
Calibration / Dibromofluoromethane (Surr)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2026
Error Coefficients
Relative Standard Deviation:1.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/35 50.0 10.165068 50.0 1617392.0 0.203301 Y
2 IC 280-672931/36 50.0 10.005037 50.0 1556436.0 0.200101 Y
3 IC 280-672931/37 50.0 10.060439 50.0 1605924.0 0.201209 Y
4 ICIS 280-672931/38 50.0 9.893259 50.0 1661687.0 0.197865 Y
5 IC 280-672931/39 50.0 10.175587 50.0 1612993.0 0.203512 Y
6 IC 280-672931/40 50.0 10.208416 50.0 1578144.0 0.204168 Y
7 IC 280-672931/41 50.0 10.398551 50.0 1599819.0 0.207971 Y
8 IC 280-672931/42 50.0 10.016688 50.0 1594549.0 0.200334 Y
9 IC 280-672931/43 50.0 10.259412 50.0 1702505.0 0.205188 Y
RelResp = [0.2026]x
Concentration
0 10 20 30 40 50
0.0
0.2
0.4
0.6
0.8
1.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/35IC 280-672931/39IC 280-672931/40IC 280-672931/41IC 280-672931/43
11/15/2024
3:53:55 PM
Page 574 of 777
Calibration / 1,1,1-Trichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3235
Error Coefficients
Relative Standard Deviation:6.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.146784 50.0 1702505.0 0.293567 Y
2 IC 280-672931/42 1.0 0.349158 50.0 1594549.0 0.349158 Y
3 IC 280-672931/41 2.0 0.591442 50.0 1599819.0 0.295721 Y
4 IC 280-672931/40 5.0 1.496378 50.0 1578144.0 0.299276 Y
5 IC 280-672931/39 10.0 3.405532 50.0 1612993.0 0.340553 Y
6 ICIS 280-672931/38 50.0 16.207475 50.0 1661687.0 0.324149 Y
7 IC 280-672931/37 75.0 24.526379 50.0 1605924.0 0.327018 Y
8 IC 280-672931/36 100.0 34.425155 50.0 1556436.0 0.344252 Y
9 IC 280-672931/35 200.0 67.584142 50.0 1617392.0 0.337921 Y
RelResp = [0.3235]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 575 of 777
Calibration / Cyclohexane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5801
Error Coefficients
Relative Standard Deviation:5.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.252716 50.0 1702505.0 0.505432 Y
2 IC 280-672931/42 1.0 0.593553 50.0 1594549.0 0.593553 Y
3 IC 280-672931/41 2.0 1.205418 50.0 1599819.0 0.602709 Y
4 IC 280-672931/40 5.0 2.855506 50.0 1578144.0 0.571101 Y
5 IC 280-672931/39 10.0 5.802784 50.0 1612993.0 0.580278 Y
6 ICIS 280-672931/38 50.0 28.63662 50.0 1661687.0 0.572732 Y
7 IC 280-672931/37 75.0 43.425343 50.0 1605924.0 0.579005 Y
8 IC 280-672931/36 100.0 61.069777 50.0 1556436.0 0.610698 Y
9 IC 280-672931/35 200.0 121.147563 50.0 1617392.0 0.605738 Y
RelResp = [0.5801]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 576 of 777
Calibration / 1,1-Dichloropropene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3775
Error Coefficients
Relative Standard Deviation:3.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.182173 50.0 1702505.0 0.364345 Y
2 IC 280-672931/42 1.0 0.356903 50.0 1594549.0 0.356903 Y
3 IC 280-672931/41 2.0 0.77765 50.0 1599819.0 0.388825 Y
4 IC 280-672931/40 5.0 1.838774 50.0 1578144.0 0.367755 Y
5 IC 280-672931/39 10.0 3.776861 50.0 1612993.0 0.377686 Y
6 ICIS 280-672931/38 50.0 18.511037 50.0 1661687.0 0.370221 Y
7 IC 280-672931/37 75.0 28.455363 50.0 1605924.0 0.379405 Y
8 IC 280-672931/36 100.0 40.066665 50.0 1556436.0 0.400667 Y
9 IC 280-672931/35 200.0 78.300004 50.0 1617392.0 0.3915 Y
RelResp = [0.3775]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
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Page 577 of 777
Calibration / Carbon tetrachloride
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2514
Error Coefficients
Relative Standard Deviation:4.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.125286 50.0 1702505.0 0.250572 Y
2 IC 280-672931/42 1.0 0.240977 50.0 1594549.0 0.240977 Y
3 IC 280-672931/41 2.0 0.46524 50.0 1599819.0 0.23262 Y
4 IC 280-672931/40 5.0 1.230433 50.0 1578144.0 0.246087 Y
5 IC 280-672931/39 10.0 2.503731 50.0 1612993.0 0.250373 Y
6 ICIS 280-672931/38 50.0 12.379046 50.0 1661687.0 0.247581 Y
7 IC 280-672931/37 75.0 19.501265 50.0 1605924.0 0.260017 Y
8 IC 280-672931/36 100.0 26.925392 50.0 1556436.0 0.269254 Y
9 IC 280-672931/35 200.0 52.935003 50.0 1617392.0 0.264675 Y
RelResp = [0.2514]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
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Page 578 of 777
Calibration / Isobutyl alcohol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.06641
Error Coefficients
Relative Standard Deviation:12.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 12.5 0.771334 50.0 1702505.0 0.061707 Y
2 IC 280-672931/42 25.0 1.428429 50.0 1594549.0 0.057137 Y
3 IC 280-672931/41 50.0 2.664708 50.0 1599819.0 0.053294 Y
4 IC 280-672931/40 125.0 7.872951 50.0 1578144.0 0.062984 Y
5 IC 280-672931/39 250.0 17.846141 50.0 1612993.0 0.071385 Y
6 ICIS 280-672931/38 1250.0 84.021058 50.0 1661687.0 0.067217 Y
7 IC 280-672931/37 1875.0 135.288096 50.0 1605924.0 0.072154 Y
8 IC 280-672931/36 2500.0 187.077047 50.0 1556436.0 0.074831 Y
9 IC 280-672931/35 5000.0 384.88709 50.0 1617392.0 0.076977 Y
RelResp = [0.06641]x
Concentration
0 1000 2000 3000 4000 5000
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39 ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
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Page 579 of 777
Calibration / 1,2-Dichloroethane-d4 (Surr)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3038
Error Coefficients
Relative Standard Deviation:2.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/35 50.0 15.343807 50.0 1617392.0 0.306876 Y
2 IC 280-672931/36 50.0 15.302332 50.0 1556436.0 0.306047 Y
3 IC 280-672931/37 50.0 14.906683 50.0 1605924.0 0.298134 Y
4 ICIS 280-672931/38 50.0 15.072122 50.0 1661687.0 0.301442 Y
5 IC 280-672931/39 50.0 14.718694 50.0 1612993.0 0.294374 Y
6 IC 280-672931/40 50.0 15.141964 50.0 1578144.0 0.302839 Y
7 IC 280-672931/41 50.0 15.650927 50.0 1599819.0 0.313019 Y
8 IC 280-672931/42 50.0 15.035349 50.0 1594549.0 0.300707 Y
9 IC 280-672931/43 50.0 15.54386 50.0 1702505.0 0.310877 Y
RelResp = [0.3038]x
Concentration
0 10 20 30 40 50
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/35IC 280-672931/36IC 280-672931/41IC 280-672931/43
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Page 580 of 777
Calibration / Benzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.123
Error Coefficients
Relative Standard Deviation:3.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.57994 50.0 1702505.0 1.159879 Y
2 IC 280-672931/42 1.0 1.134051 50.0 1594549.0 1.134051 Y
3 IC 280-672931/41 2.0 2.104863 50.0 1599819.0 1.052432 Y
4 IC 280-672931/40 5.0 5.467942 50.0 1578144.0 1.093588 Y
5 IC 280-672931/39 10.0 11.253149 50.0 1612993.0 1.125315 Y
6 ICIS 280-672931/38 50.0 54.737745 50.0 1661687.0 1.094755 Y
7 IC 280-672931/37 75.0 84.30648 50.0 1605924.0 1.124086 Y
8 IC 280-672931/36 100.0 116.711031 50.0 1556436.0 1.16711 Y
9 IC 280-672931/35 200.0 231.804813 50.0 1617392.0 1.159024 Y
RelResp = [1.123]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
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Page 581 of 777
Calibration / 1,2-Dichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3939
Error Coefficients
Relative Standard Deviation:3.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.208927 50.0 1702505.0 0.417855 Y
2 IC 280-672931/42 1.0 0.390643 50.0 1594549.0 0.390643 Y
3 IC 280-672931/41 2.0 0.794809 50.0 1599819.0 0.397404 Y
4 IC 280-672931/40 5.0 1.864025 50.0 1578144.0 0.372805 Y
5 IC 280-672931/39 10.0 4.094252 50.0 1612993.0 0.409425 Y
6 ICIS 280-672931/38 50.0 18.861645 50.0 1661687.0 0.377233 Y
7 IC 280-672931/37 75.0 29.146865 50.0 1605924.0 0.388625 Y
8 IC 280-672931/36 100.0 40.046202 50.0 1556436.0 0.400462 Y
9 IC 280-672931/35 200.0 78.063729 50.0 1617392.0 0.390319 Y
RelResp = [0.3939]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
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Page 582 of 777
Calibration / n-Heptane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4649
Error Coefficients
Relative Standard Deviation:12.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.302907 50.0 1702505.0 0.605813 Y
2 IC 280-672931/42 1.0 0.402057 50.0 1594549.0 0.402057 Y
3 IC 280-672931/41 2.0 0.935325 50.0 1599819.0 0.467662 Y
4 IC 280-672931/40 5.0 2.040815 50.0 1578144.0 0.408163 Y
5 IC 280-672931/39 10.0 4.641403 50.0 1612993.0 0.46414 Y
6 ICIS 280-672931/38 50.0 22.501139 50.0 1661687.0 0.450023 Y
7 IC 280-672931/37 75.0 33.054397 50.0 1605924.0 0.440725 Y
8 IC 280-672931/36 100.0 47.641985 50.0 1556436.0 0.47642 Y
9 IC 280-672931/35 200.0 93.7483 50.0 1617392.0 0.468741 Y
RelResp = [0.4649]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
IC 280-672931/35
11/15/2024
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Page 583 of 777
Calibration / Trichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.186
Error Coefficients
Relative Standard Deviation:3.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.611688 50.0 365464.0 1.223376 Y
2 IC 280-672931/42 1.0 1.24116 50.0 347417.0 1.24116 Y
3 IC 280-672931/41 2.0 2.291244 50.0 353236.0 1.145622 Y
4 IC 280-672931/40 5.0 5.494689 50.0 343741.0 1.098938 Y
5 IC 280-672931/39 10.0 12.196688 50.0 348156.0 1.219669 Y
6 ICIS 280-672931/38 50.0 59.743178 50.0 352929.0 1.194864 Y
7 IC 280-672931/37 75.0 89.202802 50.0 353689.0 1.189371 Y
8 IC 280-672931/36 100.0 120.325088 50.0 345076.0 1.203251 Y
9 IC 280-672931/35 200.0 231.793907 50.0 355024.0 1.15897 Y
RelResp = [1.186]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
11/15/2024
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Page 584 of 777
Calibration / 2-Pentanone
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8583
Error Coefficients
Relative Standard Deviation:6.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 1.6 1.467485 50.0 1702505.0 0.917178 Y
2 IC 280-672931/42 3.2 2.744412 50.0 1594549.0 0.857629 Y
3 IC 280-672931/41 6.4 5.124736 50.0 1599819.0 0.80074 Y
4 IC 280-672931/40 16.0 12.761066 50.0 1578144.0 0.797567 Y
5 IC 280-672931/39 32.0 29.374554 50.0 1612993.0 0.917955 Y
6 ICIS 280-672931/38 160.0 134.612084 50.0 1661687.0 0.841326 Y
7 IC 280-672931/37 240.0 212.438633 50.0 1605924.0 0.885161 Y
8 IC 280-672931/36 320.0 290.74562 50.0 1556436.0 0.90858 Y
9 IC 280-672931/35 640.0 511.348207 50.0 1617392.0 0.798982 Y
RelResp = [0.8583]x
Concentration
0 100 200 300 400 500 600 700
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
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Page 585 of 777
Calibration / Methylcyclohexane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4225
Error Coefficients
Relative Standard Deviation:3.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.217121 50.0 1702505.0 0.434242 Y
2 IC 280-672931/42 1.0 0.439309 50.0 1594549.0 0.439309 Y
3 IC 280-672931/41 2.0 0.820593 50.0 1599819.0 0.410296 Y
4 IC 280-672931/40 5.0 2.088276 50.0 1578144.0 0.417655 Y
5 IC 280-672931/39 10.0 4.262976 50.0 1612993.0 0.426298 Y
6 ICIS 280-672931/38 50.0 20.315318 50.0 1661687.0 0.406306 Y
7 IC 280-672931/37 75.0 30.136389 50.0 1605924.0 0.401819 Y
8 IC 280-672931/36 100.0 43.903154 50.0 1556436.0 0.439032 Y
9 IC 280-672931/35 200.0 85.427002 50.0 1617392.0 0.427135 Y
RelResp = [0.4225]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
IC 280-672931/35
11/15/2024
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Page 586 of 777
Calibration / 1,2-Dichloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3192
Error Coefficients
Relative Standard Deviation:5.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.177004 50.0 1702505.0 0.354008 Y
2 IC 280-672931/42 1.0 0.306827 50.0 1594549.0 0.306827 Y
3 IC 280-672931/41 2.0 0.576503 50.0 1599819.0 0.288251 Y
4 IC 280-672931/40 5.0 1.576187 50.0 1578144.0 0.315237 Y
5 IC 280-672931/39 10.0 3.204757 50.0 1612993.0 0.320476 Y
6 ICIS 280-672931/38 50.0 15.383914 50.0 1661687.0 0.307678 Y
7 IC 280-672931/37 75.0 24.302209 50.0 1605924.0 0.324029 Y
8 IC 280-672931/36 100.0 33.034638 50.0 1556436.0 0.330346 Y
9 IC 280-672931/35 200.0 65.274528 50.0 1617392.0 0.326373 Y
RelResp = [0.3192]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
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Page 587 of 777
Calibration / 1,4-Dioxane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.01313
Error Coefficients
Relative Standard Deviation:6.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 10.0 0.147635 50.0 1702505.0 0.014764 Y
2 IC 280-672931/42 20.0 0.247719 50.0 1594549.0 0.012386 Y
3 IC 280-672931/41 40.0 0.497025 50.0 1599819.0 0.012426 Y
4 IC 280-672931/40 100.0 1.288412 50.0 1578144.0 0.012884 Y
5 IC 280-672931/39 200.0 2.876888 50.0 1612993.0 0.014384 Y
6 ICIS 280-672931/38 1000.0 12.409377 50.0 1661687.0 0.012409 Y
7 IC 280-672931/37 1500.0 19.291947 50.0 1605924.0 0.012861 Y
8 IC 280-672931/36 2000.0 26.645715 50.0 1556436.0 0.013323 Y
9 IC 280-672931/35 4000.0 51.044645 50.0 1617392.0 0.012761 Y
RelResp = [0.01313]x
Concentration
0 1000 2000 3000 4000
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
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Page 588 of 777
Calibration / Dibromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1586
Error Coefficients
Relative Standard Deviation:12.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.099794 50.0 1702505.0 0.199588 Y
2 IC 280-672931/42 1.0 0.18165 50.0 1594549.0 0.18165 Y
3 IC 280-672931/41 2.0 0.322068 50.0 1599819.0 0.161034 Y
4 IC 280-672931/40 5.0 0.711912 50.0 1578144.0 0.142382 Y
5 IC 280-672931/39 10.0 1.484538 50.0 1612993.0 0.148454 Y
6 ICIS 280-672931/38 50.0 7.385115 50.0 1661687.0 0.147702 Y
7 IC 280-672931/37 75.0 11.241379 50.0 1605924.0 0.149885 Y
8 IC 280-672931/36 100.0 14.955578 50.0 1556436.0 0.149556 Y
9 IC 280-672931/35 200.0 29.397913 50.0 1617392.0 0.14699 Y
RelResp = [0.1586]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
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Page 589 of 777
Calibration / Dichlorobromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2949
Error Coefficients
Relative Standard Deviation:5.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.137738 50.0 1702505.0 0.275476 Y
2 IC 280-672931/42 1.0 0.27224 50.0 1594549.0 0.27224 Y
3 IC 280-672931/41 2.0 0.573909 50.0 1599819.0 0.286954 Y
4 IC 280-672931/40 5.0 1.410803 50.0 1578144.0 0.282161 Y
5 IC 280-672931/39 10.0 3.069883 50.0 1612993.0 0.306988 Y
6 ICIS 280-672931/38 50.0 14.780702 50.0 1661687.0 0.295614 Y
7 IC 280-672931/37 75.0 23.291046 50.0 1605924.0 0.310547 Y
8 IC 280-672931/36 100.0 31.373857 50.0 1556436.0 0.313739 Y
9 IC 280-672931/35 200.0 62.053355 50.0 1617392.0 0.310267 Y
RelResp = [0.2949]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39 ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
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Page 590 of 777
Calibration / 2-Chloroethyl vinyl ether
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.05227
Slope:0.2625
Error Coefficients
Relative Standard Deviation:13.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.062672 50.0 1702505.0 0.125345 Y
2 IC 280-672931/42 1.0 0.288577 50.0 1594549.0 0.288577 Y
3 IC 280-672931/41 2.0 0.470803 50.0 1599819.0 0.235402 Y
4 IC 280-672931/40 5.0 1.137761 50.0 1578144.0 0.227552 Y
5 IC 280-672931/39 10.0 2.470903 50.0 1612993.0 0.24709 Y
6 ICIS 280-672931/38 50.0 12.302588 50.0 1661687.0 0.246052 Y
7 IC 280-672931/37 75.0 19.058716 50.0 1605924.0 0.254116 Y
8 IC 280-672931/36 100.0 27.288498 50.0 1556436.0 0.272885 Y
9 IC 280-672931/35 200.0 52.868785 50.0 1617392.0 0.264344 Y
RelResp = [-0.05227] + [0.2625]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
IC 280-672931/35
Intercept = 0.199
11/15/2024
3:53:55 PM
Page 591 of 777
Calibration / cis-1,3-Dichloropropene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.998
Error Coefficients
Relative Standard Deviation:10.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.952761 50.0 365464.0 1.905523 Y
2 IC 280-672931/42 1.0 1.954568 50.0 347417.0 1.954568 Y
3 IC 280-672931/41 2.0 3.058578 50.0 353236.0 1.529289 Y
4 IC 280-672931/40 5.0 9.606506 50.0 343741.0 1.921301 Y
5 IC 280-672931/39 10.0 21.960989 50.0 348156.0 2.196099 Y
6 ICIS 280-672931/38 50.0 104.38346 50.0 352929.0 2.087669 Y
7 IC 280-672931/37 75.0 159.77582 50.0 353689.0 2.130344 Y
8 IC 280-672931/36 100.0 212.921067 50.0 345076.0 2.129211 Y
9 IC 280-672931/35 200.0 425.770793 50.0 355024.0 2.128854 Y
RelResp = [1.998]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39 ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 592 of 777
Calibration / 4-Methyl-2-pentanone (MIBK)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8545
Error Coefficients
Relative Standard Deviation:10.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 2.0 1.591097 50.0 1702505.0 0.795548 Y
2 IC 280-672931/42 4.0 3.182122 50.0 1594549.0 0.795531 Y
3 IC 280-672931/41 8.0 6.398568 50.0 1599819.0 0.799821 Y
4 IC 280-672931/40 20.0 16.177199 50.0 1578144.0 0.80886 Y
5 IC 280-672931/39 40.0 38.743287 50.0 1612993.0 0.968582 Y
6 ICIS 280-672931/38 200.0 179.742214 50.0 1661687.0 0.898711 Y
7 IC 280-672931/37 300.0 284.038753 50.0 1605924.0 0.946796 Y
8 IC 280-672931/36 400.0 385.906391 50.0 1556436.0 0.964766 Y
9 IC 280-672931/35 800.0 569.641621 50.0 1617392.0 0.712052 Y
RelResp = [0.8545]x
Concentration
0 100 200 300 400 500 600 700 800
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39 ICIS 280-672931/38
IC 280-672931/37
11/15/2024
3:53:55 PM
Page 593 of 777
Calibration / Toluene-d8 (Surr)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:4.698
Error Coefficients
Relative Standard Deviation:1.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/35 50.0 236.045732 50.0 355024.0 4.720915 Y
2 IC 280-672931/36 50.0 234.451686 50.0 345076.0 4.689034 Y
3 IC 280-672931/37 50.0 234.65177 50.0 353689.0 4.693035 Y
4 ICIS 280-672931/38 50.0 241.67793 50.0 352929.0 4.833559 Y
5 IC 280-672931/39 50.0 236.755937 50.0 348156.0 4.735119 Y
6 IC 280-672931/40 50.0 232.76624 50.0 343741.0 4.655325 Y
7 IC 280-672931/41 50.0 232.569585 50.0 353236.0 4.651392 Y
8 IC 280-672931/42 50.0 232.762645 50.0 347417.0 4.655253 Y
9 IC 280-672931/43 50.0 232.405107 50.0 365464.0 4.648102 Y
RelResp = [4.698]x
Concentration
0 10 20 30 40 50
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/35ICIS 280-672931/38IC 280-672931/39
11/15/2024
3:53:55 PM
Page 594 of 777
Calibration / Toluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.145
Error Coefficients
Relative Standard Deviation:4.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.609719 50.0 1702505.0 1.219438 Y
2 IC 280-672931/42 1.0 1.116805 50.0 1594549.0 1.116805 Y
3 IC 280-672931/41 2.0 2.217282 50.0 1599819.0 1.108641 Y
4 IC 280-672931/40 5.0 5.333512 50.0 1578144.0 1.066702 Y
5 IC 280-672931/39 10.0 11.55284 50.0 1612993.0 1.155284 Y
6 ICIS 280-672931/38 50.0 55.660904 50.0 1661687.0 1.113218 Y
7 IC 280-672931/37 75.0 86.47601 50.0 1605924.0 1.153013 Y
8 IC 280-672931/36 100.0 119.313483 50.0 1556436.0 1.193135 Y
9 IC 280-672931/35 200.0 236.232435 50.0 1617392.0 1.181162 Y
RelResp = [1.145]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 595 of 777
Calibration / trans-1,3-Dichloropropene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4026
Error Coefficients
Relative Standard Deviation:7.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.182114 50.0 1702505.0 0.364228 Y
2 IC 280-672931/42 1.0 0.356464 50.0 1594549.0 0.356464 Y
3 IC 280-672931/41 2.0 0.755242 50.0 1599819.0 0.377621 Y
4 IC 280-672931/40 5.0 1.99101 50.0 1578144.0 0.398202 Y
5 IC 280-672931/39 10.0 4.339448 50.0 1612993.0 0.433945 Y
6 ICIS 280-672931/38 50.0 20.315107 50.0 1661687.0 0.406302 Y
7 IC 280-672931/37 75.0 32.005655 50.0 1605924.0 0.426742 Y
8 IC 280-672931/36 100.0 43.300688 50.0 1556436.0 0.433007 Y
9 IC 280-672931/35 200.0 85.425178 50.0 1617392.0 0.427126 Y
RelResp = [0.4026]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39 ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 596 of 777
Calibration / Ethyl methacrylate
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.347
Error Coefficients
Relative Standard Deviation:8.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 1.150592 50.0 365464.0 2.301184 Y
2 IC 280-672931/42 1.0 1.994433 50.0 347417.0 1.994433 Y
3 IC 280-672931/41 2.0 4.431881 50.0 353236.0 2.215941 Y
4 IC 280-672931/40 5.0 10.795774 50.0 343741.0 2.159155 Y
5 IC 280-672931/39 10.0 25.434001 50.0 348156.0 2.5434 Y
6 ICIS 280-672931/38 50.0 121.620779 50.0 352929.0 2.432416 Y
7 IC 280-672931/37 75.0 185.133408 50.0 353689.0 2.468445 Y
8 IC 280-672931/36 100.0 249.816417 50.0 345076.0 2.498164 Y
9 IC 280-672931/35 200.0 501.098095 50.0 355024.0 2.50549 Y
RelResp = [2.347]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39 ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 597 of 777
Calibration / 1,1,2-Trichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2285
Error Coefficients
Relative Standard Deviation:3.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.117239 50.0 1702505.0 0.234478 Y
2 IC 280-672931/42 1.0 0.219968 50.0 1594549.0 0.219968 Y
3 IC 280-672931/41 2.0 0.440737 50.0 1599819.0 0.220369 Y
4 IC 280-672931/40 5.0 1.107979 50.0 1578144.0 0.221596 Y
5 IC 280-672931/39 10.0 2.343532 50.0 1612993.0 0.234353 Y
6 ICIS 280-672931/38 50.0 11.039835 50.0 1661687.0 0.220797 Y
7 IC 280-672931/37 75.0 17.538657 50.0 1605924.0 0.233849 Y
8 IC 280-672931/36 100.0 23.752181 50.0 1556436.0 0.237522 Y
9 IC 280-672931/35 200.0 46.762071 50.0 1617392.0 0.23381 Y
RelResp = [0.2285]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 598 of 777
Calibration / Tetrachloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8088
Error Coefficients
Relative Standard Deviation:4.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.386358 50.0 365464.0 0.772716 Y
2 IC 280-672931/42 1.0 0.749675 50.0 347417.0 0.749675 Y
3 IC 280-672931/41 2.0 1.563261 50.0 353236.0 0.78163 Y
4 IC 280-672931/40 5.0 3.870647 50.0 343741.0 0.774129 Y
5 IC 280-672931/39 10.0 8.601747 50.0 348156.0 0.860175 Y
6 ICIS 280-672931/38 50.0 41.132777 50.0 352929.0 0.822656 Y
7 IC 280-672931/37 75.0 61.961639 50.0 353689.0 0.826155 Y
8 IC 280-672931/36 100.0 85.013591 50.0 345076.0 0.850136 Y
9 IC 280-672931/35 200.0 168.300875 50.0 355024.0 0.841504 Y
RelResp = [0.8088]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39 ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 599 of 777
Calibration / 1,3-Dichloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.12
Error Coefficients
Relative Standard Deviation:6.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 1.046478 50.0 365464.0 2.092956 Y
2 IC 280-672931/42 1.0 1.980617 50.0 347417.0 1.980617 Y
3 IC 280-672931/41 2.0 3.842474 50.0 353236.0 1.921237 Y
4 IC 280-672931/40 5.0 9.820039 50.0 343741.0 1.964008 Y
5 IC 280-672931/39 10.0 23.168493 50.0 348156.0 2.316849 Y
6 ICIS 280-672931/38 50.0 110.281813 50.0 352929.0 2.205636 Y
7 IC 280-672931/37 75.0 162.555522 50.0 353689.0 2.167407 Y
8 IC 280-672931/36 100.0 224.579223 50.0 345076.0 2.245792 Y
9 IC 280-672931/35 200.0 437.147066 50.0 355024.0 2.185735 Y
RelResp = [2.12]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39 ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 600 of 777
Calibration / 2-Hexanone
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:3.428
Error Coefficients
Relative Standard Deviation:7.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 2.0 6.423752 50.0 365464.0 3.211876 Y
2 IC 280-672931/42 4.0 13.390968 50.0 347417.0 3.347742 Y
3 IC 280-672931/41 8.0 24.71846 50.0 353236.0 3.089808 Y
4 IC 280-672931/40 20.0 63.864508 50.0 343741.0 3.193225 Y
5 IC 280-672931/39 40.0 148.811165 50.0 348156.0 3.720279 Y
6 ICIS 280-672931/38 200.0 708.546478 50.0 352929.0 3.542732 Y
7 IC 280-672931/37 300.0 1086.283288 50.0 353689.0 3.620944 Y
8 IC 280-672931/36 400.0 1480.076853 50.0 345076.0 3.700192 Y
9 IC 280-672931/35 800.0 1505.747217 50.0 355024.0 1.882184 N
RelResp = [3.428]x
Concentration
0 100 200 300 400 500 600 700 800
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39 ICIS 280-672931/38
IC 280-672931/37
11/15/2024
3:53:55 PM
Page 601 of 777
Calibration / Chlorodibromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8835
Error Coefficients
Relative Standard Deviation:9.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.409069 50.0 365464.0 0.818138 Y
2 IC 280-672931/42 1.0 0.796593 50.0 347417.0 0.796593 Y
3 IC 280-672931/41 2.0 1.534951 50.0 353236.0 0.767476 Y
4 IC 280-672931/40 5.0 4.014069 50.0 343741.0 0.802814 Y
5 IC 280-672931/39 10.0 9.387602 50.0 348156.0 0.93876 Y
6 ICIS 280-672931/38 50.0 46.894418 50.0 352929.0 0.937888 Y
7 IC 280-672931/37 75.0 72.558378 50.0 353689.0 0.967445 Y
8 IC 280-672931/36 100.0 96.547137 50.0 345076.0 0.965471 Y
9 IC 280-672931/35 200.0 191.381428 50.0 355024.0 0.956907 Y
RelResp = [0.8835]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39 ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 602 of 777
Calibration / Ethylene Dibromide
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.2936
Slope:1.11
Error Coefficients
Relative Standard Deviation:5.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.242432 50.0 365464.0 0.484863 Y
2 IC 280-672931/42 1.0 0.840489 50.0 347417.0 0.840489 Y
3 IC 280-672931/41 2.0 2.183526 50.0 353236.0 1.091763 Y
4 IC 280-672931/40 5.0 4.880564 50.0 343741.0 0.976113 Y
5 IC 280-672931/39 10.0 11.148307 50.0 348156.0 1.114831 Y
6 ICIS 280-672931/38 50.0 54.843892 50.0 352929.0 1.096878 Y
7 IC 280-672931/37 75.0 80.987393 50.0 353689.0 1.079832 Y
8 IC 280-672931/36 100.0 109.641065 50.0 345076.0 1.096411 Y
9 IC 280-672931/35 200.0 215.818367 50.0 355024.0 1.079092 Y
RelResp = [-0.2936] + [1.11]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
Intercept = 0.264
11/15/2024
3:53:55 PM
Page 603 of 777
Calibration / 1-Chlorohexane
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.3574
Slope:1.51
Error Coefficients
Relative Standard Deviation:6.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.4 1.003792 50.0 365464.0 2.509481 Y
2 IC 280-672931/42 0.8 1.41818 50.0 347417.0 1.772726 Y
3 IC 280-672931/41 1.6 2.692251 50.0 353236.0 1.682657 Y
4 IC 280-672931/40 4.0 6.353912 50.0 343741.0 1.588478 Y
5 IC 280-672931/39 8.0 12.301957 50.0 348156.0 1.537745 Y
6 ICIS 280-672931/38 40.0 61.890777 50.0 352929.0 1.547269 Y
7 IC 280-672931/37 60.0 90.619867 50.0 353689.0 1.510331 Y
8 IC 280-672931/36 80.0 128.249864 50.0 345076.0 1.603123 Y
9 IC 280-672931/35 160.0 249.374127 50.0 355024.0 1.558588 Y
RelResp = [0.3574] + [1.51]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
IC 280-672931/35
Intercept = -0.237
11/15/2024
3:53:55 PM
Page 604 of 777
Calibration / Chlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:3.022
Error Coefficients
Relative Standard Deviation:4.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 1.580593 50.0 365464.0 3.161187 Y
2 IC 280-672931/42 1.0 2.931635 50.0 347417.0 2.931635 Y
3 IC 280-672931/41 2.0 5.589323 50.0 353236.0 2.794661 Y
4 IC 280-672931/40 5.0 14.33463 50.0 343741.0 2.866926 Y
5 IC 280-672931/39 10.0 31.837021 50.0 348156.0 3.183702 Y
6 ICIS 280-672931/38 50.0 152.691051 50.0 352929.0 3.053821 Y
7 IC 280-672931/37 75.0 227.496756 50.0 353689.0 3.03329 Y
8 IC 280-672931/36 100.0 310.29237 50.0 345076.0 3.102924 Y
9 IC 280-672931/35 200.0 614.002856 50.0 355024.0 3.070014 Y
RelResp = [3.022]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 605 of 777
Calibration / 1,1,1,2-Tetrachloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8779
Error Coefficients
Relative Standard Deviation:9.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.470635 50.0 365464.0 0.941269 Y
2 IC 280-672931/42 1.0 0.824657 50.0 347417.0 0.824657 Y
3 IC 280-672931/41 2.0 1.568498 50.0 353236.0 0.784249 Y
4 IC 280-672931/40 5.0 4.317058 50.0 343741.0 0.863412 Y
5 IC 280-672931/39 10.0 7.205391 50.0 348156.0 0.720539 Y
6 ICIS 280-672931/38 50.0 46.884501 50.0 352929.0 0.93769 Y
7 IC 280-672931/37 75.0 69.630947 50.0 353689.0 0.928413 Y
8 IC 280-672931/36 100.0 94.764487 50.0 345076.0 0.947645 Y
9 IC 280-672931/35 200.0 190.595565 50.0 355024.0 0.952978 Y
RelResp = [0.8779]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 606 of 777
Calibration / Ethylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.708
Error Coefficients
Relative Standard Deviation:6.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.920063 50.0 365464.0 1.840127 Y
2 IC 280-672931/42 1.0 1.762579 50.0 347417.0 1.762579 Y
3 IC 280-672931/41 2.0 3.020077 50.0 353236.0 1.510039 Y
4 IC 280-672931/40 5.0 7.959336 50.0 343741.0 1.591867 Y
5 IC 280-672931/39 10.0 17.409724 50.0 348156.0 1.740972 Y
6 ICIS 280-672931/38 50.0 84.541225 50.0 352929.0 1.690825 Y
7 IC 280-672931/37 75.0 126.476085 50.0 353689.0 1.686348 Y
8 IC 280-672931/36 100.0 178.919282 50.0 345076.0 1.789193 Y
9 IC 280-672931/35 200.0 351.966768 50.0 355024.0 1.759834 Y
RelResp = [1.708]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 607 of 777
Calibration / m-Xylene & p-Xylene
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.7476
Slope:2.193
Error Coefficients
Relative Standard Deviation:4.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.307691 50.0 365464.0 0.615382 Y
2 IC 280-672931/42 1.0 1.531733 50.0 347417.0 1.531733 Y
3 IC 280-672931/41 2.0 3.924996 50.0 353236.0 1.962498 Y
4 IC 280-672931/40 5.0 10.268487 50.0 343741.0 2.053697 Y
5 IC 280-672931/39 10.0 21.835183 50.0 348156.0 2.183518 Y
6 ICIS 280-672931/38 50.0 106.137495 50.0 352929.0 2.12275 Y
7 IC 280-672931/37 75.0 157.521014 50.0 353689.0 2.10028 Y
8 IC 280-672931/36 100.0 216.083993 50.0 345076.0 2.16084 Y
9 IC 280-672931/35 200.0 425.299276 50.0 355024.0 2.126496 Y
RelResp = [-0.7476] + [2.193]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
Intercept = 0.341
11/15/2024
3:53:55 PM
Page 608 of 777
Calibration / o-Xylene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.034
Error Coefficients
Relative Standard Deviation:2.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 1.0172 50.0 365464.0 2.0344 Y
2 IC 280-672931/42 1.0 2.086973 50.0 347417.0 2.086973 Y
3 IC 280-672931/41 2.0 3.984164 50.0 353236.0 1.992082 Y
4 IC 280-672931/40 5.0 9.805784 50.0 343741.0 1.961157 Y
5 IC 280-672931/39 10.0 20.11153 50.0 348156.0 2.011153 Y
6 ICIS 280-672931/38 50.0 101.493077 50.0 352929.0 2.029862 Y
7 IC 280-672931/37 75.0 153.273921 50.0 353689.0 2.043652 Y
8 IC 280-672931/36 100.0 209.929407 50.0 345076.0 2.099294 Y
9 IC 280-672931/35 200.0 409.913696 50.0 355024.0 2.049568 Y
RelResp = [2.034]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 609 of 777
Calibration / Styrene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:3.375
Error Coefficients
Relative Standard Deviation:4.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 1.766385 50.0 365464.0 3.532769 Y
2 IC 280-672931/42 1.0 3.308848 50.0 347417.0 3.308848 Y
3 IC 280-672931/41 2.0 6.221478 50.0 353236.0 3.110739 Y
4 IC 280-672931/40 5.0 15.704266 50.0 343741.0 3.140853 Y
5 IC 280-672931/39 10.0 34.411729 50.0 348156.0 3.441173 Y
6 ICIS 280-672931/38 50.0 168.765389 50.0 352929.0 3.375308 Y
7 IC 280-672931/37 75.0 258.300088 50.0 353689.0 3.444001 Y
8 IC 280-672931/36 100.0 353.08787 50.0 345076.0 3.530879 Y
9 IC 280-672931/35 200.0 697.977461 50.0 355024.0 3.489887 Y
RelResp = [3.375]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 610 of 777
Calibration / Bromoform
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6175
Error Coefficients
Relative Standard Deviation:8.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.258439 50.0 365464.0 0.516877 Y
2 IC 280-672931/42 1.0 0.590213 50.0 347417.0 0.590213 Y
3 IC 280-672931/41 2.0 1.213636 50.0 353236.0 0.606818 Y
4 IC 280-672931/40 5.0 2.896658 50.0 343741.0 0.579332 Y
5 IC 280-672931/39 10.0 6.279656 50.0 348156.0 0.627966 Y
6 ICIS 280-672931/38 50.0 31.97527 50.0 352929.0 0.639505 Y
7 IC 280-672931/37 75.0 49.28242 50.0 353689.0 0.657099 Y
8 IC 280-672931/36 100.0 66.142241 50.0 345076.0 0.661422 Y
9 IC 280-672931/35 200.0 135.701108 50.0 355024.0 0.678506 Y
RelResp = [0.6175]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39 ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 611 of 777
Calibration / Isopropylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.949
Error Coefficients
Relative Standard Deviation:5.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 1.615851 50.0 555961.0 3.231702 Y
2 IC 280-672931/42 1.0 2.877407 50.0 544605.0 2.877407 Y
3 IC 280-672931/41 2.0 5.429848 50.0 555347.0 2.714924 Y
4 IC 280-672931/40 5.0 13.971367 50.0 548393.0 2.794273 Y
5 IC 280-672931/39 10.0 31.218443 50.0 537317.0 3.121844 Y
6 ICIS 280-672931/38 50.0 149.006698 50.0 545705.0 2.980134 Y
7 IC 280-672931/37 75.0 224.792965 50.0 543023.0 2.99724 Y
8 IC 280-672931/36 100.0 301.400194 50.0 551245.0 3.014002 Y
9 IC 280-672931/35 200.0 561.147079 50.0 597134.0 2.805735 Y
RelResp = [2.949]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
11/15/2024
3:53:55 PM
Page 612 of 777
Calibration / Cyclohexanone
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.262
Error Coefficients
Relative Standard Deviation:8.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 15.0 4.152529 50.0 365464.0 0.276835 Y
2 IC 280-672931/42 30.0 6.811699 50.0 347417.0 0.227057 Y
3 IC 280-672931/41 60.0 13.630972 50.0 353236.0 0.227183 Y
4 IC 280-672931/40 150.0 37.358796 50.0 343741.0 0.249059 Y
5 IC 280-672931/39 300.0 88.186617 50.0 348156.0 0.293955 Y
6 ICIS 280-672931/38 1500.0 402.433917 50.0 352929.0 0.268289 Y
7 IC 280-672931/37 2250.0 617.375717 50.0 353689.0 0.274389 Y
8 IC 280-672931/36 3000.0 832.712069 50.0 345076.0 0.277571 Y
9 IC 280-672931/35 6000.0 1584.633292 50.0 355024.0 0.264106 Y
RelResp = [0.262]x
Concentration
0 1000 2000 3000 4000 5000 6000
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 613 of 777
Calibration / 4-Bromofluorobenzene (Surr)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9751
Error Coefficients
Relative Standard Deviation:2.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/35 50.0 46.381047 50.0 597134.0 0.927621 Y
2 IC 280-672931/36 50.0 49.573874 50.0 551245.0 0.991477 Y
3 IC 280-672931/37 50.0 49.329034 50.0 543023.0 0.986581 Y
4 ICIS 280-672931/38 50.0 49.666303 50.0 545705.0 0.993326 Y
5 IC 280-672931/39 50.0 48.670245 50.0 537317.0 0.973405 Y
6 IC 280-672931/40 50.0 48.580306 50.0 548393.0 0.971606 Y
7 IC 280-672931/41 50.0 48.292329 50.0 555347.0 0.965847 Y
8 IC 280-672931/42 50.0 50.113844 50.0 544605.0 1.002277 Y
9 IC 280-672931/43 50.0 48.194298 50.0 555961.0 0.963886 Y
RelResp = [0.9751]x
Concentration
0 10 20 30 40 50
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/36IC 280-672931/37ICIS 280-672931/38IC 280-672931/42
11/15/2024
3:53:55 PM
Page 614 of 777
Calibration / 1,1,2,2-Tetrachloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.106
Error Coefficients
Relative Standard Deviation:4.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.523868 50.0 555961.0 1.047735 Y
2 IC 280-672931/42 1.0 1.111356 50.0 544605.0 1.111356 Y
3 IC 280-672931/41 2.0 2.093826 50.0 555347.0 1.046913 Y
4 IC 280-672931/40 5.0 5.303222 50.0 548393.0 1.060644 Y
5 IC 280-672931/39 10.0 12.06876 50.0 537317.0 1.206876 Y
6 ICIS 280-672931/38 50.0 55.731668 50.0 545705.0 1.114633 Y
7 IC 280-672931/37 75.0 85.466269 50.0 543023.0 1.13955 Y
8 IC 280-672931/36 100.0 111.562826 50.0 551245.0 1.115628 Y
9 IC 280-672931/35 200.0 222.04815 50.0 597134.0 1.110241 Y
RelResp = [1.106]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/35
11/15/2024
3:53:55 PM
Page 615 of 777
Calibration / Bromobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7382
Error Coefficients
Relative Standard Deviation:3.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.368101 50.0 555961.0 0.736203 Y
2 IC 280-672931/42 1.0 0.780749 50.0 544605.0 0.780749 Y
3 IC 280-672931/41 2.0 1.486998 50.0 555347.0 0.743499 Y
4 IC 280-672931/40 5.0 3.544174 50.0 548393.0 0.708835 Y
5 IC 280-672931/39 10.0 7.672938 50.0 537317.0 0.767294 Y
6 ICIS 280-672931/38 50.0 36.289204 50.0 545705.0 0.725784 Y
7 IC 280-672931/37 75.0 56.195041 50.0 543023.0 0.749267 Y
8 IC 280-672931/36 100.0 73.932734 50.0 551245.0 0.739327 Y
9 IC 280-672931/35 200.0 138.526445 50.0 597134.0 0.692632 Y
RelResp = [0.7382]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
11/15/2024
3:53:55 PM
Page 616 of 777
Calibration / trans-1,4-Dichloro-2-butene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2636
Error Coefficients
Relative Standard Deviation:8.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.146413 50.0 555961.0 0.292826 Y
2 IC 280-672931/42 1.0 0.241735 50.0 544605.0 0.241735 Y
3 IC 280-672931/41 2.0 0.534981 50.0 555347.0 0.26749 Y
4 IC 280-672931/40 5.0 1.107235 50.0 548393.0 0.221447 Y
5 IC 280-672931/39 10.0 2.683891 50.0 537317.0 0.268389 Y
6 ICIS 280-672931/38 50.0 13.711529 50.0 545705.0 0.274231 Y
7 IC 280-672931/37 75.0 20.858509 50.0 543023.0 0.278113 Y
8 IC 280-672931/36 100.0 27.488231 50.0 551245.0 0.274882 Y
9 IC 280-672931/35 200.0 50.719102 50.0 597134.0 0.253596 Y
RelResp = [0.2636]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
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Page 617 of 777
Calibration / 1,2,3-Trichloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3808
Error Coefficients
Relative Standard Deviation:10.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.217102 50.0 555961.0 0.434203 Y
2 IC 280-672931/42 1.0 0.375318 50.0 544605.0 0.375318 Y
3 IC 280-672931/41 2.0 0.589001 50.0 555347.0 0.294501 Y
4 IC 280-672931/40 5.0 1.84211 50.0 548393.0 0.368422 Y
5 IC 280-672931/39 10.0 4.15602 50.0 537317.0 0.415602 Y
6 ICIS 280-672931/38 50.0 19.325735 50.0 545705.0 0.386515 Y
7 IC 280-672931/37 75.0 29.613018 50.0 543023.0 0.39484 Y
8 IC 280-672931/36 100.0 38.451868 50.0 551245.0 0.384519 Y
9 IC 280-672931/35 200.0 74.578905 50.0 597134.0 0.372895 Y
RelResp = [0.3808]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
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3:53:55 PM
Page 618 of 777
Calibration / N-Propylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8476
Error Coefficients
Relative Standard Deviation:5.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.4655 50.0 555961.0 0.931001 Y
2 IC 280-672931/42 1.0 0.760368 50.0 544605.0 0.760368 Y
3 IC 280-672931/41 2.0 1.650229 50.0 555347.0 0.825115 Y
4 IC 280-672931/40 5.0 4.165717 50.0 548393.0 0.833143 Y
5 IC 280-672931/39 10.0 8.86888 50.0 537317.0 0.886888 Y
6 ICIS 280-672931/38 50.0 42.967721 50.0 545705.0 0.859354 Y
7 IC 280-672931/37 75.0 64.280519 50.0 543023.0 0.857074 Y
8 IC 280-672931/36 100.0 86.428993 50.0 551245.0 0.86429 Y
9 IC 280-672931/35 200.0 162.197932 50.0 597134.0 0.81099 Y
RelResp = [0.8476]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
11/15/2024
3:53:55 PM
Page 619 of 777
Calibration / 2-Chlorotoluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7292
Error Coefficients
Relative Standard Deviation:9.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.440768 50.0 555961.0 0.881537 Y
2 IC 280-672931/42 1.0 0.737323 50.0 544605.0 0.737323 Y
3 IC 280-672931/41 2.0 1.272268 50.0 555347.0 0.636134 Y
4 IC 280-672931/40 5.0 3.526303 50.0 548393.0 0.705261 Y
5 IC 280-672931/39 10.0 7.595888 50.0 537317.0 0.759589 Y
6 ICIS 280-672931/38 50.0 35.563171 50.0 545705.0 0.711263 Y
7 IC 280-672931/37 75.0 54.7986 50.0 543023.0 0.730648 Y
8 IC 280-672931/36 100.0 72.199476 50.0 551245.0 0.721995 Y
9 IC 280-672931/35 200.0 135.732013 50.0 597134.0 0.67866 Y
RelResp = [0.7292]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
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3:53:55 PM
Page 620 of 777
Calibration / 1,3,5-Trimethylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.573
Error Coefficients
Relative Standard Deviation:5.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 1.398659 50.0 555961.0 2.797319 Y
2 IC 280-672931/42 1.0 2.59904 50.0 544605.0 2.59904 Y
3 IC 280-672931/41 2.0 4.557781 50.0 555347.0 2.27889 Y
4 IC 280-672931/40 5.0 12.642393 50.0 548393.0 2.528479 Y
5 IC 280-672931/39 10.0 27.037764 50.0 537317.0 2.703776 Y
6 ICIS 280-672931/38 50.0 128.017335 50.0 545705.0 2.560347 Y
7 IC 280-672931/37 75.0 196.948656 50.0 543023.0 2.625982 Y
8 IC 280-672931/36 100.0 262.014621 50.0 551245.0 2.620146 Y
9 IC 280-672931/35 200.0 489.186598 50.0 597134.0 2.445933 Y
RelResp = [2.573]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
11/15/2024
3:53:55 PM
Page 621 of 777
Calibration / 4-Chlorotoluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7671
Error Coefficients
Relative Standard Deviation:12.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.499226 50.0 555961.0 0.998451 Y
2 IC 280-672931/42 1.0 0.752839 50.0 544605.0 0.752839 Y
3 IC 280-672931/41 2.0 1.323857 50.0 555347.0 0.661928 Y
4 IC 280-672931/40 5.0 3.644284 50.0 548393.0 0.728857 Y
5 IC 280-672931/39 10.0 7.762922 50.0 537317.0 0.776292 Y
6 ICIS 280-672931/38 50.0 37.670994 50.0 545705.0 0.75342 Y
7 IC 280-672931/37 75.0 57.261755 50.0 543023.0 0.76349 Y
8 IC 280-672931/36 100.0 74.876053 50.0 551245.0 0.748761 Y
9 IC 280-672931/35 200.0 144.05728 50.0 597134.0 0.720286 Y
RelResp = [0.7671]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
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3:53:55 PM
Page 622 of 777
Calibration / tert-Butylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.122
Error Coefficients
Relative Standard Deviation:5.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 1.182547 50.0 555961.0 2.365094 Y
2 IC 280-672931/42 1.0 2.209491 50.0 544605.0 2.209491 Y
3 IC 280-672931/41 2.0 4.062055 50.0 555347.0 2.031027 Y
4 IC 280-672931/40 5.0 9.833459 50.0 548393.0 1.966692 Y
5 IC 280-672931/39 10.0 21.990464 50.0 537317.0 2.199046 Y
6 ICIS 280-672931/38 50.0 103.888548 50.0 545705.0 2.077771 Y
7 IC 280-672931/37 75.0 157.497657 50.0 543023.0 2.099969 Y
8 IC 280-672931/36 100.0 214.024526 50.0 551245.0 2.140245 Y
9 IC 280-672931/35 200.0 401.706987 50.0 597134.0 2.008535 Y
RelResp = [2.122]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
11/15/2024
3:53:55 PM
Page 623 of 777
Calibration / 1,2,4-Trimethylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.704
Error Coefficients
Relative Standard Deviation:5.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 1.519981 50.0 555961.0 3.039961 Y
2 IC 280-672931/42 1.0 2.728675 50.0 544605.0 2.728675 Y
3 IC 280-672931/41 2.0 5.185677 50.0 555347.0 2.592838 Y
4 IC 280-672931/40 5.0 12.76083 50.0 548393.0 2.552166 Y
5 IC 280-672931/39 10.0 27.981434 50.0 537317.0 2.798143 Y
6 ICIS 280-672931/38 50.0 131.858147 50.0 545705.0 2.637163 Y
7 IC 280-672931/37 75.0 203.481252 50.0 543023.0 2.713083 Y
8 IC 280-672931/36 100.0 270.937061 50.0 551245.0 2.709371 Y
9 IC 280-672931/35 200.0 513.258582 50.0 597134.0 2.566293 Y
RelResp = [2.704]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
11/15/2024
3:53:55 PM
Page 624 of 777
Calibration / sec-Butylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6204
Error Coefficients
Relative Standard Deviation:6.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.329969 50.0 555961.0 0.659938 Y
2 IC 280-672931/42 1.0 0.689491 50.0 544605.0 0.689491 Y
3 IC 280-672931/41 2.0 1.122992 50.0 555347.0 0.561496 Y
4 IC 280-672931/40 5.0 3.049547 50.0 548393.0 0.609909 Y
5 IC 280-672931/39 10.0 6.579729 50.0 537317.0 0.657973 Y
6 ICIS 280-672931/38 50.0 30.220082 50.0 545705.0 0.604402 Y
7 IC 280-672931/37 75.0 45.606632 50.0 543023.0 0.608088 Y
8 IC 280-672931/36 100.0 61.342053 50.0 551245.0 0.613421 Y
9 IC 280-672931/35 200.0 115.746801 50.0 597134.0 0.578734 Y
RelResp = [0.6204]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
11/15/2024
3:53:55 PM
Page 625 of 777
Calibration / 1,3-Dichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.401
Error Coefficients
Relative Standard Deviation:3.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.759046 50.0 555961.0 1.518092 Y
2 IC 280-672931/42 1.0 1.392202 50.0 544605.0 1.392202 Y
3 IC 280-672931/41 2.0 2.808694 50.0 555347.0 1.404347 Y
4 IC 280-672931/40 5.0 6.790477 50.0 548393.0 1.358095 Y
5 IC 280-672931/39 10.0 14.441475 50.0 537317.0 1.444147 Y
6 ICIS 280-672931/38 50.0 69.039224 50.0 545705.0 1.380784 Y
7 IC 280-672931/37 75.0 104.562882 50.0 543023.0 1.394172 Y
8 IC 280-672931/36 100.0 138.178759 50.0 551245.0 1.381788 Y
9 IC 280-672931/35 200.0 266.870836 50.0 597134.0 1.334354 Y
RelResp = [1.401]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
11/15/2024
3:53:55 PM
Page 626 of 777
Calibration / 4-Isopropyltoluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.608
Error Coefficients
Relative Standard Deviation:5.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 1.404955 50.0 555961.0 2.809909 Y
2 IC 280-672931/42 1.0 2.643935 50.0 544605.0 2.643935 Y
3 IC 280-672931/41 2.0 4.827702 50.0 555347.0 2.413851 Y
4 IC 280-672931/40 5.0 12.11084 50.0 548393.0 2.422168 Y
5 IC 280-672931/39 10.0 27.313392 50.0 537317.0 2.731339 Y
6 ICIS 280-672931/38 50.0 131.025188 50.0 545705.0 2.620504 Y
7 IC 280-672931/37 75.0 197.641536 50.0 543023.0 2.63522 Y
8 IC 280-672931/36 100.0 264.580087 50.0 551245.0 2.645801 Y
9 IC 280-672931/35 200.0 509.785241 50.0 597134.0 2.548926 Y
RelResp = [2.608]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
11/15/2024
3:53:55 PM
Page 627 of 777
Calibration / 1,4-Dichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.453
Error Coefficients
Relative Standard Deviation:5.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.812647 50.0 555961.0 1.625294 Y
2 IC 280-672931/42 1.0 1.53974 50.0 544605.0 1.53974 Y
3 IC 280-672931/41 2.0 2.881442 50.0 555347.0 1.440721 Y
4 IC 280-672931/40 5.0 6.751818 50.0 548393.0 1.350364 Y
5 IC 280-672931/39 10.0 14.88451 50.0 537317.0 1.488451 Y
6 ICIS 280-672931/38 50.0 70.514747 50.0 545705.0 1.410295 Y
7 IC 280-672931/37 75.0 107.245918 50.0 543023.0 1.429946 Y
8 IC 280-672931/36 100.0 141.774438 50.0 551245.0 1.417744 Y
9 IC 280-672931/35 200.0 274.822737 50.0 597134.0 1.374114 Y
RelResp = [1.453]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
11/15/2024
3:53:55 PM
Page 628 of 777
Calibration / n-Butylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.438
Error Coefficients
Relative Standard Deviation:6.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 1.380403 50.0 555961.0 2.760805 Y
2 IC 280-672931/42 1.0 2.2845 50.0 544605.0 2.2845 Y
3 IC 280-672931/41 2.0 4.726954 50.0 555347.0 2.363477 Y
4 IC 280-672931/40 5.0 11.371863 50.0 548393.0 2.274373 Y
5 IC 280-672931/39 10.0 25.315131 50.0 537317.0 2.531513 Y
6 ICIS 280-672931/38 50.0 120.843496 50.0 545705.0 2.41687 Y
7 IC 280-672931/37 75.0 183.756397 50.0 543023.0 2.450085 Y
8 IC 280-672931/36 100.0 247.962884 50.0 551245.0 2.479629 Y
9 IC 280-672931/35 200.0 476.549903 50.0 597134.0 2.38275 Y
RelResp = [2.438]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
11/15/2024
3:53:55 PM
Page 629 of 777
Calibration / 1,2-Dichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.396
Error Coefficients
Relative Standard Deviation:8.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.811748 50.0 555961.0 1.623495 Y
2 IC 280-672931/42 1.0 1.573067 50.0 544605.0 1.573067 Y
3 IC 280-672931/41 2.0 2.547326 50.0 555347.0 1.273663 Y
4 IC 280-672931/40 5.0 6.638761 50.0 548393.0 1.327752 Y
5 IC 280-672931/39 10.0 14.351026 50.0 537317.0 1.435103 Y
6 ICIS 280-672931/38 50.0 66.191166 50.0 545705.0 1.323823 Y
7 IC 280-672931/37 75.0 101.454542 50.0 543023.0 1.352727 Y
8 IC 280-672931/36 100.0 134.606754 50.0 551245.0 1.346068 Y
9 IC 280-672931/35 200.0 261.338828 50.0 597134.0 1.306694 Y
RelResp = [1.396]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
11/15/2024
3:53:55 PM
Page 630 of 777
Calibration / 1,2-Dibromo-3-Chloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3375
Error Coefficients
Relative Standard Deviation:7.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.182567 50.0 555961.0 0.365134 Y
2 IC 280-672931/42 1.0 0.360996 50.0 544605.0 0.360996 Y
3 IC 280-672931/41 2.0 0.567663 50.0 555347.0 0.283832 Y
4 IC 280-672931/40 5.0 1.56293 50.0 548393.0 0.312586 Y
5 IC 280-672931/39 10.0 3.547161 50.0 537317.0 0.354716 Y
6 ICIS 280-672931/38 50.0 16.901898 50.0 545705.0 0.338038 Y
7 IC 280-672931/37 75.0 26.032415 50.0 543023.0 0.347099 Y
8 IC 280-672931/36 100.0 35.314334 50.0 551245.0 0.353143 Y
9 IC 280-672931/35 200.0 64.360596 50.0 597134.0 0.321803 Y
RelResp = [0.3375]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
11/15/2024
3:53:55 PM
Page 631 of 777
Calibration / 1,2,4-Trichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8453
Error Coefficients
Relative Standard Deviation:11.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.461993 50.0 555961.0 0.923986 Y
2 IC 280-672931/42 1.0 1.043325 50.0 544605.0 1.043325 Y
3 IC 280-672931/41 2.0 1.702719 50.0 555347.0 0.85136 Y
4 IC 280-672931/40 5.0 4.079283 50.0 548393.0 0.815857 Y
5 IC 280-672931/39 10.0 8.67179 50.0 537317.0 0.867179 Y
6 ICIS 280-672931/38 50.0 39.870993 50.0 545705.0 0.79742 Y
7 IC 280-672931/37 75.0 59.644987 50.0 543023.0 0.795266 Y
8 IC 280-672931/36 100.0 78.748016 50.0 551245.0 0.78748 Y
9 IC 280-672931/35 200.0 145.110729 50.0 597134.0 0.725554 Y
RelResp = [0.8453]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
11/15/2024
3:53:55 PM
Page 632 of 777
Calibration / Hexachlorobutadiene
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.008471
Slope:0.2857
Error Coefficients
Relative Standard Deviation:12.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.209997 50.0 555961.0 0.419993 N
2 IC 280-672931/42 1.0 0.374767 50.0 544605.0 0.374767 N
3 IC 280-672931/41 2.0 0.446478 50.0 555347.0 0.223239 Y
4 IC 280-672931/40 5.0 1.390882 50.0 548393.0 0.278176 Y
5 IC 280-672931/39 10.0 3.339556 50.0 537317.0 0.333956 Y
6 ICIS 280-672931/38 50.0 14.366187 50.0 545705.0 0.287324 Y
7 IC 280-672931/37 75.0 22.063338 50.0 543023.0 0.294178 Y
8 IC 280-672931/36 100.0 30.523361 50.0 551245.0 0.305234 Y
9 IC 280-672931/35 200.0 54.075886 50.0 597134.0 0.270379 Y
RelResp = [-0.008471] + [0.2857]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
Intercept = 0.0297
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3:53:55 PM
Page 633 of 777
Calibration / Naphthalene
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.3996
Slope:3.295
Error Coefficients
Relative Standard Deviation:6.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 1.990337 50.0 555961.0 3.980675 Y
2 IC 280-672931/42 1.0 3.909623 50.0 544605.0 3.909623 Y
3 IC 280-672931/41 2.0 7.023627 50.0 555347.0 3.511813 Y
4 IC 280-672931/40 5.0 16.141617 50.0 548393.0 3.228323 Y
5 IC 280-672931/39 10.0 37.369002 50.0 537317.0 3.7369 Y
6 ICIS 280-672931/38 50.0 156.844357 50.0 545705.0 3.136887 Y
7 IC 280-672931/37 75.0 239.387558 50.0 543023.0 3.191834 Y
8 IC 280-672931/36 100.0 320.342951 50.0 551245.0 3.20343 Y
9 IC 280-672931/35 200.0 570.632304 50.0 597134.0 2.853162 N
RelResp = [0.3996] + [3.295]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
Intercept = -0.121
11/15/2024
3:53:55 PM
Page 634 of 777
Calibration / 1,2,3-Trichlorobenzene
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.1539
Slope:0.7463
Error Coefficients
Relative Standard Deviation:9.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-672931/43 0.5 0.523868 50.0 555961.0 1.047735 Y
2 IC 280-672931/42 1.0 0.899184 50.0 544605.0 0.899184 Y
3 IC 280-672931/41 2.0 1.620068 50.0 555347.0 0.810034 Y
4 IC 280-672931/40 5.0 4.078736 50.0 548393.0 0.815747 Y
5 IC 280-672931/39 10.0 9.03368 50.0 537317.0 0.903368 Y
6 ICIS 280-672931/38 50.0 36.520281 50.0 545705.0 0.730406 Y
7 IC 280-672931/37 75.0 54.827236 50.0 543023.0 0.73103 Y
8 IC 280-672931/36 100.0 73.062613 50.0 551245.0 0.730626 Y
9 IC 280-672931/35 200.0 128.191495 50.0 597134.0 0.640957 Y
RelResp = [0.1539] + [0.7463]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-672931/43
IC 280-672931/42
IC 280-672931/41
IC 280-672931/40
IC 280-672931/39
ICIS 280-672931/38
IC 280-672931/37
IC 280-672931/36
Intercept = -0.206
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3:53:55 PM
Page 635 of 777
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-198899-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_MS14
10/29/2024 20:02
10/29/2024 17:02
10/29/2024 19:42
ICV 280-672942/45
DB-624 (60.25)
Lab File ID:VMS14_0000003781.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Dichlorodifluoromethane 0.2869 0.1000 50.0 50.0 0.0 30.0Lin2
Chloromethane 0.35450.3717 0.1000 47.7 50.0 -4.6 30.0Ave
Vinyl chloride 0.32400.2834 0.0100 57.2 50.0 14.3 30.0Ave
Bromomethane 0.19120.1849 0.0100 51.7 50.0 3.4 30.0Ave
Chloroethane 0.18970.1768 0.0100 53.6 50.0 7.3 30.0Ave
Dichlorofluoromethane 0.47090.4450 0.0100 52.9 50.0 5.8 30.0Ave
Trichlorofluoromethane 0.34970.3041 0.0100 57.5 50.0 15.0 30.0Ave
Ethyl ether 0.21260.1920 0.0100 55.4 50.0 10.7 30.0Ave
Acrolein 0.04980.0974 0.0010 252 494 -48.9*30.0Ave
1,1,2-Trichloro-1,2,2-trifluoroethane 0.14450.1234 0.0500 58.5 50.0 17.1 30.0Ave
1,1-Dichloroethene 0.2000 0.0600 55.0 50.0 10.0 30.0Lin1
Acetone 0.3348 0.0100 207 200 3.7 30.0Lin2
Iodomethane 0.2286 0.0100 53.0 50.0 6.1 30.0Lin2
Carbon disulfide 0.56660.5408 0.1000 52.4 50.0 4.8 30.0Ave
Methyl acetate 0.54200.5311 0.0100 102 100 2.0 30.0Ave
3-Chloro-1-propene 0.33080.3113 0.0100 53.1 50.0 6.2 30.0Ave
Methylene Chloride 0.26080.2554 0.0100 51.1 50.0 2.1 30.0Ave
2-Methyl-2-propanol 0.20500.2147 0.0010 477 500 -4.5 30.0Ave
Acrylonitrile 0.29410.2827 0.0100 520 500 4.0 30.0Ave
Methyl tert-butyl ether 0.76360.7102 0.1000 53.8 50.0 7.5 30.0Ave
trans-1,2-Dichloroethene 0.20160.1927 0.1000 52.3 50.0 4.6 30.0Ave
Hexane 1.0741.038 0.0100 51.8 50.0 3.5 30.0Ave
Vinyl acetate 0.5445 0.0100 95.0 100 -5.0 30.0Lin2
1,1-Dichloroethane 0.38230.3439 0.1000 55.6 50.0 11.2 30.0Ave
2-Butanone (MEK)0.5180 0.0100 204 200 2.1 30.0Lin2
cis-1,2-Dichloroethene 0.23730.2242 0.1000 52.9 50.0 5.8 30.0Ave
2,2-Dichloropropane 0.29530.2680 0.0100 55.1 50.0 10.2 30.0Ave
sec-Butyl Alcohol 0.14560.1500 0.0100 1160 1200 -3.0 30.0Ave
Chlorobromomethane 0.12100.1174 0.0500 51.6 50.0 3.1 30.0Ave
Tetrahydrofuran 0.30570.3122 0.0010 97.9 100 -2.1 30.0Ave
Chloroform 0.36350.3463 0.2000 52.5 50.0 4.9 30.0Ave
1,1,1-Trichloroethane 0.29650.2684 0.0500 55.2 50.0 10.5 30.0Ave
Cyclohexane 0.36600.3275 0.0100 55.9 50.0 11.8 30.0Ave
1,1-Dichloropropene 0.29320.2850 0.0100 51.4 50.0 2.9 30.0Ave
Carbon tetrachloride 0.2142 0.1000 52.9 50.0 5.8 30.0Lin1
Isobutyl alcohol 0.05520.0562 0.0010 1230 1250 -1.8 30.0Ave
Benzene 0.86370.8259 0.2000 52.3 50.0 4.6 30.0Ave
1,2-Dichloroethane 0.30430.2952 0.0700 51.5 50.0 3.1 30.0Ave
n-Heptane 0.29230.2929 49.9 50.0 -0.2 20.0Ave
Trichloroethene 0.89610.8408 0.2000 53.3 50.0 6.6 30.0Ave
FORM VII 8260D
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Page 636 of 777
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-198899-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_MS14
10/29/2024 20:02
10/29/2024 17:02
10/29/2024 19:42
ICV 280-672942/45
DB-624 (60.25)
Lab File ID:VMS14_0000003781.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
2-Pentanone 0.69130.7138 0.0010 155 160 -3.2 30.0Ave
Methylcyclohexane 0.28370.2727 0.0500 52.0 50.0 4.0 30.0Ave
1,2-Dichloropropane 0.23460.2193 0.1000 53.5 50.0 7.0 30.0Ave
1,4-Dioxane 0.0105 0.0010 921 1000 -7.9 30.0Lin2
Dibromomethane 0.15440.1469 0.0100 52.6 50.0 5.1 30.0Ave
Dichlorobromomethane 0.2567 0.2000 49.2 50.0 -1.5 30.0Lin1
2-Chloroethyl vinyl ether 0.1608 0.0100 45.3 50.0 -9.5 30.0Lin2
cis-1,3-Dichloropropene 1.2931.223 0.2000 52.9 50.0 5.8 30.0Ave
4-Methyl-2-pentanone (MIBK)0.61720.5999 0.0300 206 200 2.9 30.0Ave
Toluene 0.95180.9451 0.3000 50.4 50.0 0.7 30.0Ave
trans-1,3-Dichloropropene 0.3515 0.2000 47.8 50.0 -4.3 30.0Lin1
Ethyl methacrylate 1.6801.600 0.0100 52.5 50.0 5.0 30.0Ave
1,1,2-Trichloroethane 0.23340.2291 0.1000 50.9 50.0 1.9 30.0Ave
Tetrachloroethene 0.64970.5971 0.1000 54.4 50.0 8.8 30.0Ave
1,3-Dichloropropane 1.5701.510 0.0100 52.0 50.0 4.0 30.0Ave
2-Hexanone 2.1032.010 0.0100 209 200 4.6 30.0Ave
Chlorodibromomethane 0.7309 0.1000 47.4 50.0 -5.3 30.0Lin1
Ethylene Dibromide 0.97120.9277 0.1000 52.3 50.0 4.7 30.0Ave
1-Chlorohexane 1.243 0.0100 44.4 40.0 11.1 30.0Lin2
Chlorobenzene 2.4102.374 0.3000 50.7 50.0 1.5 30.0Ave
1,1,1,2-Tetrachloroethane 0.7670 0.0100 53.5 50.0 7.0 30.0Lin2
Ethylbenzene 1.3151.255 0.3000 52.4 50.0 4.8 30.0Ave
m-Xylene & p-Xylene 1.6581.544 0.1000 53.7 50.0 7.4 30.0Ave
o-Xylene 1.6691.587 0.2000 52.6 50.0 5.2 30.0Ave
Styrene 2.8612.664 0.2000 53.7 50.0 7.4 30.0Ave
Bromoform 0.5498 0.1000 45.3 50.0 -9.5 30.0Lin1
Isopropylbenzene 2.4872.112 0.3000 58.9 50.0 17.8 30.0Ave
Cyclohexanone 0.36310.2021 0.0010 2700 1500 79.7*30.0Ave
1,1,2,2-Tetrachloroethane 0.84320.8212 0.3000 51.3 50.0 2.7 30.0Ave
trans-1,4-Dichloro-2-butene 0.3108 0.0100 47.5 50.0 -5.0 30.0Lin1
Bromobenzene 0.59150.5902 0.0100 50.1 50.0 0.2 30.0Ave
1,2,3-Trichloropropane 0.33270.3235 0.0100 51.4 50.0 2.8 30.0Ave
N-Propylbenzene 0.66390.6305 0.0100 52.7 50.0 5.3 30.0Ave
2-Chlorotoluene 0.57070.5509 0.0100 51.8 50.0 3.6 30.0Ave
1,3,5-Trimethylbenzene 2.0791.986 0.0100 52.3 50.0 4.7 30.0Ave
4-Chlorotoluene 0.58850.5881 0.0100 50.0 50.0 0.0 30.0Ave
tert-Butylbenzene 1.8031.721 0.0100 52.4 50.0 4.8 30.0Ave
1,2,4-Trimethylbenzene 2.1582.121 0.3000 50.9 50.0 1.8 30.0Ave
sec-Butylbenzene 0.53960.5190 0.0100 52.0 50.0 4.0 30.0Ave
1,3-Dichlorobenzene 1.1561.186 0.5000 48.7 50.0 -2.5 30.0Ave
4-Isopropyltoluene 2.2572.256 0.0100 50.0 50.0 0.0 30.0Ave
FORM VII 8260D
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3:53:55 PM
Page 637 of 777
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-198899-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_MS14
10/29/2024 20:02
10/29/2024 17:02
10/29/2024 19:42
ICV 280-672942/45
DB-624 (60.25)
Lab File ID:VMS14_0000003781.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
1,4-Dichlorobenzene 1.164 0.5000 51.5 50.0 3.1 30.0Lin2
n-Butylbenzene 2.1532.151 0.0100 50.0 50.0 0.0 30.0Ave
1,2-Dichlorobenzene 1.1231.127 0.5000 49.8 50.0 -0.4 30.0Ave
1,2-Dibromo-3-Chloropropane 0.3220 0.0100 45.8 50.0 -8.4 30.0Lin2
1,2,4-Trichlorobenzene 0.8209 0.2000 50.8 50.0 1.6 30.0Lin2
Hexachlorobutadiene 0.33760.3439 0.0100 49.1 50.0 -1.8 30.0Ave
Naphthalene 3.0923.225 0.0100 47.9 50.0 -4.1 30.0Ave
1,2,3-Trichlorobenzene 0.7827 0.3000 49.8 50.0 -0.4 30.0Lin2
Dibromofluoromethane (Surr)0.25100.2424 0.0100 51.8 50.0 3.6 30.0Ave
1,2-Dichloroethane-d4 (Surr)0.30230.3027 0.0100 49.9 50.0 -0.1 30.0Ave
Toluene-d8 (Surr)4.0133.941 0.0100 50.9 50.0 1.8 30.0Ave
4-Bromofluorobenzene (Surr)0.93580.9567 0.0100 48.9 50.0 -2.2 30.0Ave
FORM VII 8260D
11/15/2024
3:53:55 PM
Page 638 of 777
Report Date: 29-Oct-2024 20:43:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003781.D
Lims ID:icv
Client ID:
Sample Type:ICV
Inject. Date:29-Oct-2024 20:02:15 ALS Bottle#:0 Worklist Smp#:45
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:icv
Operator ID:bustillose Instrument ID:VMS_MS14
Sublist:
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:29-Oct-2024 20:43:03 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:29-Oct-2024 20:42:50
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.363 5.360 0.003 99 1457983 50.0 50.0
* 2 Chlorobenzene-d5 119 7.929 7.929 0.000 86 390849 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.177 -0.004 95 678653 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.839 4.842 -0.003 93 365946 50.0 51.8
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.112 -0.003 95 440683 50.0 49.9
$ 6 Toluene-d8 (Surr) 98 6.636 6.637 -0.001 93 1568523 50.0 50.9
$ 7 4-Bromofluorobenzene (Surr) 95 9.035 9.035 0.000 87 635082 50.0 48.9
10 Dichlorodifluoromethane 85 1.791 1.791 0.000 99 418291 50.0 50.0
12 Chloromethane 50 1.971 1.971 0.000 99 516878 50.0 47.7
13 Vinyl chloride 62 2.087 2.087 0.000 98 472439 50.0 57.2
15 Bromomethane 94 2.392 2.399 -0.007 90 278762 50.0 51.7
16 Chloroethane 64 2.492 2.495 -0.003 100 276537 50.0 53.6
17 Dichlorofluoromethane 67 2.675 2.675 0.000 97 686536 50.0 52.9
18 Trichlorofluoromethane 101 2.717 2.717 0.000 98 509789 50.0 57.5
21 Ethyl ether 59 2.939 2.942 -0.003 90 309972 50.0 55.4
22 Acrolein 56 3.051 3.055 -0.004 99 716838 493.8 252.4
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.141 3.138 0.003 94 210660 50.0 58.5
25 1,1-Dichloroethene 96 3.141 3.145 -0.004 98 291531 50.0 55.0
26 Acetone 43 3.161 3.158 0.003 100 1952247 200.0 207.4
29 Iodomethane 142 3.267 3.270 -0.003 99 333336 50.0 53.0
30 Carbon disulfide 76 3.334 3.334 0.000 99 826153 50.0 52.4
32 Methyl acetate 43 3.399 3.395 0.004 98 1580463 100.0 102.0
33 3-Chloro-1-propene 41 3.421 3.424 -0.003 92 482250 50.0 53.1
34 Methylene Chloride 84 3.521 3.521 0.000 90 380210 50.0 51.1
35 2-Methyl-2-propanol 59 3.579 3.566 0.013 100 2988569 500.0 477.3
36 Acrylonitrile 53 3.688 3.688 0.000 99 4288581 500.0 520.2
37 Methyl tert-butyl ether 73 3.714 3.717 -0.003 93 1113285 50.0 53.8
38 trans-1,2-Dichloroethene 96 3.730 3.730 0.000 99 293882 50.0 52.3
39 Hexane 57 3.932 3.932 0.000 91 419828 50.0 51.8
40 Vinyl acetate 43 4.029 4.029 0.000 97 1587670 100.0 95.0
42 1,1-Dichloroethane 63 4.058 4.058 0.000 96 557409 50.0 55.6
11/15/2024
3:53:55 PM
Page 639 of 777
Report Date: 29-Oct-2024 20:43:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003781.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
45 2-Butanone (MEK) 43 4.456 4.453 0.003 99 3021177 200.0 204.2
47 cis-1,2-Dichloroethene 96 4.482 4.482 0.000 80 345931 50.0 52.9
48 2,2-Dichloropropane 77 4.495 4.495 0.000 85 430525 50.0 55.1
50 sec-Butyl Alcohol 45 4.579 4.569 0.010 99 5093231 1200.0 1164.2
52 Chlorobromomethane 128 4.662 4.662 0.000 96 176456 50.0 51.6
53 Tetrahydrofuran 42 4.675 4.672 0.003 88 891438 100.0 97.9
54 Chloroform 83 4.723 4.723 0.000 93 529948 50.0 52.5
55 1,1,1-Trichloroethane 97 4.874 4.875 -0.001 99 432316 50.0 55.2
56 Cyclohexane 56 4.936 4.939 -0.003 88 533646 50.0 55.9
57 1,1-Dichloropropene 75 4.987 4.987 0.000 97 427517 50.0 51.4
59 Carbon tetrachloride 117 4.993 4.997 -0.004 93 312271 50.0 52.9
58 Isobutyl alcohol 41 5.006 4.997 0.009 95 2011744 1250.0 1228.0
60 Benzene 78 5.145 5.145 0.000 95 1259230 50.0 52.3
61 1,2-Dichloroethane 62 5.170 5.167 0.003 97 443607 50.0 51.5
63 n-Heptane 43 5.331 5.331 0.000 92 426137 50.0 49.9
65 Trichloroethene 95 5.640 5.640 0.000 99 350251 50.0 53.3
66 2-Pentanone 43 5.743 5.743 0.000 99 3225404 160.0 155.0
67 Methylcyclohexane 55 5.842 5.846 -0.004 89 413677 50.0 52.0
69 1,2-Dichloropropane 63 5.849 5.849 0.000 96 342099 50.0 53.5
70 1,4-Dioxane 88 5.910 5.900 0.010 78 307313 1000.0 921.3
71 Dibromomethane 93 5.923 5.926 -0.003 96 225164 50.0 52.6
72 Dichlorobromomethane 83 6.048 6.045 0.003 100 374201 50.0 49.2
74 2-Chloroethyl vinyl ether 63 6.247 6.244 0.003 91 234433 50.0 45.3
75 cis-1,3-Dichloropropene 75 6.402 6.405 -0.003 96 505467 50.0 52.9
76 4-Methyl-2-pentanone (MIBK) 43 6.501 6.502 -0.001 95 3599576 200.0 205.8
77 Toluene 91 6.694 6.698 -0.004 99 1387771 50.0 50.4
78 trans-1,3-Dichloropropene 75 6.868 6.871 -0.003 97 512517 50.0 47.8
79 Ethyl methacrylate 69 6.887 6.887 0.000 88 656749 50.0 52.5
80 1,1,2-Trichloroethane 97 7.045 7.048 -0.003 91 340298 50.0 50.9
82 Tetrachloroethene 164 7.148 7.148 0.000 96 253943 50.0 54.4
83 1,3-Dichloropropane 76 7.196 7.196 0.000 89 613439 50.0 52.0
84 2-Hexanone 43 7.212 7.215 -0.003 95 3287354 200.0 209.2
85 Chlorodibromomethane 129 7.395 7.395 0.000 90 285677 50.0 47.4
86 Ethylene Dibromide 107 7.514 7.518 -0.004 99 379605 50.0 52.3
87 1-Chlorohexane 91 7.907 7.907 0.000 95 388736 40.0 44.4
88 Chlorobenzene 112 7.955 7.955 0.000 94 941764 50.0 50.7
89 1,1,1,2-Tetrachloroethane 131 8.029 8.026 0.003 94 299762 50.0 53.5
90 Ethylbenzene 106 8.029 8.029 0.000 98 514048 50.0 52.4
91 m-Xylene & p-Xylene 106 8.148 8.148 0.000 100 648101 50.0 53.7
92 o-Xylene 106 8.514 8.514 0.000 97 652500 50.0 52.6
93 Styrene 104 8.530 8.530 0.000 94 1118092 50.0 53.7
94 Bromoform 173 8.714 8.717 -0.003 95 214902 50.0 45.3
95 Isopropylbenzene 105 8.855 8.858 -0.003 96 1688034 50.0 58.9
97 Cyclohexanone 55 8.961 8.961 0.000 91 4258011 1500.0 2695.9
98 1,1,2,2-Tetrachloroethane 83 9.141 9.141 0.000 94 572214 50.0 51.3
99 trans-1,4-Dichloro-2-butene 53 9.177 9.177 0.000 91 210909 50.0 47.5
100 Bromobenzene 156 9.183 9.186 -0.003 97 401431 50.0 50.1
101 1,2,3-Trichloropropane 110 9.209 9.206 0.003 84 225771 50.0 51.4
102 N-Propylbenzene 120 9.260 9.264 -0.004 99 450581 50.0 52.7
103 2-Chlorotoluene 126 9.360 9.363 -0.003 96 387336 50.0 51.8
104 1,3,5-Trimethylbenzene 105 9.431 9.434 -0.003 95 1411137 50.0 52.3
105 4-Chlorotoluene 126 9.479 9.479 0.000 98 399384 50.0 50.0
11/15/2024
3:53:55 PM
Page 640 of 777
Report Date: 29-Oct-2024 20:43:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003781.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
107 tert-Butylbenzene 119 9.749 9.749 0.000 93 1223711 50.0 52.4
108 1,2,4-Trimethylbenzene 105 9.804 9.807 -0.003 98 1464695 50.0 50.9
109 sec-Butylbenzene 134 9.968 9.968 0.000 94 366172 50.0 52.0
110 1,3-Dichlorobenzene 146 10.103 10.100 0.003 97 784670 50.0 48.7
111 4-Isopropyltoluene 119 10.115 10.116 -0.001 97 1531853 50.0 50.0
112 1,4-Dichlorobenzene 146 10.199 10.199 0.000 95 790242 50.0 51.5
114 n-Butylbenzene 91 10.524 10.524 0.000 98 1460870 50.0 50.0
115 1,2-Dichlorobenzene 146 10.562 10.563 -0.001 97 761914 50.0 49.8
116 1,2-Dibromo-3-Chloropropane 157 11.347 11.347 0.000 93 218549 50.0 45.8
118 1,2,4-Trichlorobenzene 180 12.180 12.183 -0.003 94 557092 50.0 50.8
119 Hexachlorobutadiene 225 12.324 12.328 -0.004 98 229125 50.0 49.1
120 Naphthalene 128 12.453 12.456 -0.003 97 2098100 50.0 47.9
121 1,2,3-Trichlorobenzene 180 12.681 12.681 0.000 95 531209 50.0 49.8
136 Butadiene 54 0.000 ND ND
S 154 1,3-Dichloropropene, Total 1 0 100.0 100.7
S 151 1,2-Dichloroethene, Total 1 0 100.0 105.2
S 152 Trihalomethanes, Total 1 0 200.0 194.3
S 155 Xylenes, Total 106 0 100.0 106.3
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
MV-MegaMain B_00111 Amount Added: 25.00 Units: uL
MV-Gas B_00174 Amount Added: 10.00 Units: uL
mv-IS_SS_00089 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 641 of 777
Report Date: 29-Oct-2024 20:43:48 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003781.D
Injection Date:29-Oct-2024 20:02:15 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:icv Worklist Smp#:45
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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11/15/2024
3:53:55 PM
Page 642 of 777
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-198899-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_MS14
11/11/2024 05:00
10/29/2024 17:02
10/29/2024 19:42
CCV 280-674451/2
DB-624 (60.25)
Lab File ID:VMS14_0000004265.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Dichlorodifluoromethane 0.1982 0.1000 34.7 50.0 -30.6*20.0Lin2
Chloromethane 0.35590.3717 0.1000 47.9 50.0 -4.3 20.0Ave
Vinyl chloride 0.28860.2834 0.0100 50.9 50.0 1.8 20.0Ave
Bromomethane 0.18100.1849 0.0100 48.9 50.0 -2.1 20.0Ave
Chloroethane 0.16820.1768 0.0100 47.6 50.0 -4.9 20.0Ave
Dichlorofluoromethane 0.44220.4450 0.0100 49.7 50.0 -0.6 20.0Ave
Trichlorofluoromethane 0.29840.3041 0.0100 49.1 50.0 -1.9 20.0Ave
Ethyl ether 0.20160.1920 0.0100 52.5 50.0 5.0 20.0Ave
Acrolein 0.10390.0974 0.0010 527 494 6.7 20.0Ave
1,1-Dichloroethene 0.1880 0.0600 51.7 50.0 3.4 20.0Lin1
1,1,2-Trichloro-1,2,2-trifluoroethane 0.11600.1234 0.0500 47.0 50.0 -6.0 20.0Ave
Acetone 0.2901 0.0100 179 200 -10.6 20.0Lin2
Iodomethane 0.2299 0.0100 53.3 50.0 6.6 20.0Lin2
Carbon disulfide 0.54460.5408 0.1000 50.3 50.0 0.7 20.0Ave
Methyl acetate 0.49660.5311 0.0100 93.5 100 -6.5 20.0Ave
3-Chloro-1-propene 0.30070.3113 0.0100 48.3 50.0 -3.4 20.0Ave
Methylene Chloride 0.24660.2554 0.0100 48.3 50.0 -3.4 20.0Ave
2-Methyl-2-propanol 0.19240.2147 0.0010 448 500 -10.4 20.0Ave
Acrylonitrile 0.27670.2827 0.0100 489 500 -2.1 20.0Ave
Methyl tert-butyl ether 0.71080.7102 0.1000 50.0 50.0 0.0 20.0Ave
trans-1,2-Dichloroethene 0.18940.1927 0.1000 49.1 50.0 -1.7 20.0Ave
Hexane 0.84771.038 0.0100 40.8 50.0 -18.3 20.0Ave
Vinyl acetate 0.6184 0.0100 108 100 7.9 20.0Lin2
1,1-Dichloroethane 0.33770.3439 0.1000 49.1 50.0 -1.8 20.0Ave
2-Butanone (MEK)0.4722 0.0100 186 200 -7.1 20.0Lin2
cis-1,2-Dichloroethene 0.22220.2242 0.1000 49.5 50.0 -0.9 20.0Ave
2,2-Dichloropropane 0.27580.2680 0.0100 51.4 50.0 2.9 20.0Ave
sec-Butyl Alcohol 0.13710.1500 0.0100 1100 1200 -8.6 20.0Ave
Chlorobromomethane 0.12220.1174 0.0500 52.0 50.0 4.1 20.0Ave
Tetrahydrofuran 0.28380.3122 0.0010 90.9 100 -9.1 20.0Ave
Chloroform 0.32770.3463 0.2000 47.3 50.0 -5.4 20.0Ave
1,1,1-Trichloroethane 0.26390.2684 0.0500 49.2 50.0 -1.7 20.0Ave
Cyclohexane 0.28940.3275 0.0100 44.2 50.0 -11.6 20.0Ave
1,1-Dichloropropene 0.27110.2850 0.0100 47.6 50.0 -4.9 20.0Ave
Carbon tetrachloride 0.1964 0.1000 48.6 50.0 -2.9 20.0Lin1
Isobutyl alcohol 0.05100.0562 0.0010 1140 1250 -9.2 20.0Ave
Benzene 0.80340.8259 0.2000 48.6 50.0 -2.7 20.0Ave
1,2-Dichloroethane 0.27300.2952 0.0700 46.2 50.0 -7.5 20.0Ave
n-Heptane 0.22630.2929 38.6 50.0 -22.7Ave
Trichloroethene 0.81150.8408 0.2000 48.3 50.0 -3.5 20.0Ave
FORM VII 8260D
11/15/2024
3:53:55 PM
Page 643 of 777
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-198899-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_MS14
11/11/2024 05:00
10/29/2024 17:02
10/29/2024 19:42
CCV 280-674451/2
DB-624 (60.25)
Lab File ID:VMS14_0000004265.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
2-Pentanone 0.63380.7138 0.0010 142 160 -11.2 20.0Ave
Methylcyclohexane 0.21950.2727 0.0500 40.2 50.0 -19.5 20.0Ave
1,2-Dichloropropane 0.21030.2193 0.1000 47.9 50.0 -4.1 20.0Ave
1,4-Dioxane 0.0104 0.0010 905 1000 -9.5 20.0Lin2
Dibromomethane 0.14580.1469 0.0100 49.6 50.0 -0.8 20.0Ave
Dichlorobromomethane 0.2337 0.2000 44.9 50.0 -10.2 20.0Lin1
2-Chloroethyl vinyl ether 0.0299 0.0100 8.66 50.0 -82.7*20.0Lin2
cis-1,3-Dichloropropene 1.3131.223 0.2000 53.7 50.0 7.4 20.0Ave
4-Methyl-2-pentanone (MIBK)0.57280.5999 0.0300 191 200 -4.5 20.0Ave
Toluene 0.94160.9451 0.3000 49.8 50.0 -0.4 20.0Ave
trans-1,3-Dichloropropene 0.3242 0.2000 44.2 50.0 -11.7 20.0Lin1
Ethyl methacrylate 1.6251.600 0.0100 50.8 50.0 1.6 20.0Ave
1,1,2-Trichloroethane 0.22840.2291 0.1000 49.9 50.0 -0.3 20.0Ave
Tetrachloroethene 0.63460.5971 0.1000 53.1 50.0 6.3 20.0Ave
1,3-Dichloropropane 1.4941.510 0.0100 49.5 50.0 -1.0 20.0Ave
2-Hexanone 1.9062.010 0.0100 190 200 -5.2 20.0Ave
Chlorodibromomethane 0.7387 0.1000 47.9 50.0 -4.3 20.0Lin1
Ethylene Dibromide 0.95500.9277 0.1000 51.5 50.0 2.9 20.0Ave
1-Chlorohexane 1.069 0.0100 38.2 40.0 -4.6 20.0Lin2
Chlorobenzene 2.3372.374 0.3000 49.2 50.0 -1.5 20.0Ave
1,1,1,2-Tetrachloroethane 0.7376 0.0100 51.4 50.0 2.9 20.0Lin2
Ethylbenzene 1.2121.255 0.3000 48.3 50.0 -3.5 20.0Ave
m-Xylene & p-Xylene 1.5081.544 0.1000 48.8 50.0 -2.3 20.0Ave
o-Xylene 1.4891.587 0.2000 46.9 50.0 -6.2 20.0Ave
Styrene 2.5902.664 0.2000 48.6 50.0 -2.8 20.0Ave
Bromoform 0.6028 0.1000 49.5 50.0 -1.1 20.0Lin1
Isopropylbenzene 2.0972.112 0.3000 49.6 50.0 -0.7 20.0Ave
Cyclohexanone 0.24600.2021 0.0010 1830 1500 21.7*20.0Ave
1,1,2,2-Tetrachloroethane 0.89090.8212 0.3000 54.2 50.0 8.5 20.0Ave
trans-1,4-Dichloro-2-butene 0.3033 0.0100 46.4 50.0 -7.2 20.0Lin1
Bromobenzene 0.59620.5902 0.0100 50.5 50.0 1.0 20.0Ave
1,2,3-Trichloropropane 0.34040.3235 0.0100 52.6 50.0 5.2 20.0Ave
N-Propylbenzene 0.61540.6305 0.0100 48.8 50.0 -2.4 20.0Ave
2-Chlorotoluene 0.53770.5509 0.0100 48.8 50.0 -2.4 20.0Ave
1,3,5-Trimethylbenzene 1.8741.986 0.0100 47.2 50.0 -5.6 20.0Ave
4-Chlorotoluene 0.57680.5881 0.0100 49.0 50.0 -1.9 20.0Ave
tert-Butylbenzene 1.6631.721 0.0100 48.3 50.0 -3.4 20.0Ave
1,2,4-Trimethylbenzene 1.9542.121 0.3000 46.1 50.0 -7.9 20.0Ave
sec-Butylbenzene 0.48500.5190 0.0100 46.7 50.0 -6.5 20.0Ave
1,3-Dichlorobenzene 1.1331.186 0.5000 47.8 50.0 -4.4 20.0Ave
4-Isopropyltoluene 2.0792.256 0.0100 46.1 50.0 -7.9 20.0Ave
FORM VII 8260D
11/15/2024
3:53:55 PM
Page 644 of 777
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-198899-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_MS14
11/11/2024 05:00
10/29/2024 17:02
10/29/2024 19:42
CCV 280-674451/2
DB-624 (60.25)
Lab File ID:VMS14_0000004265.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
1,4-Dichlorobenzene 1.135 0.5000 50.2 50.0 0.5 20.0Lin2
n-Butylbenzene 1.8712.151 0.0100 43.5 50.0 -13.0 20.0Ave
1,2-Dichlorobenzene 1.1021.127 0.5000 48.9 50.0 -2.3 20.0Ave
1,2-Dibromo-3-Chloropropane 0.3636 0.0100 51.6 50.0 3.2 20.0Lin2
1,2,4-Trichlorobenzene 0.7913 0.2000 49.0 50.0 -2.1 20.0Lin2
Hexachlorobutadiene 0.33010.3439 0.0100 48.0 50.0 -4.0 20.0Ave
Naphthalene 2.9543.225 0.0100 45.8 50.0 -8.4 20.0Ave
1,2,3-Trichlorobenzene 0.7822 0.3000 49.7 50.0 -0.5 20.0Lin2
Dibromofluoromethane (Surr)0.24910.2424 0.0100 51.4 50.0 2.8 20.0Ave
1,2-Dichloroethane-d4 (Surr)0.28640.3027 0.0100 47.3 50.0 -5.4 20.0Ave
Toluene-d8 (Surr)4.0713.941 0.0100 51.6 50.0 3.3 20.0Ave
4-Bromofluorobenzene (Surr)0.91200.9567 0.0100 47.7 50.0 -4.7 20.0Ave
FORM VII 8260D
11/15/2024
3:53:55 PM
Page 645 of 777
Report Date: 11-Nov-2024 05:54:26 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004265.D
Lims ID:CCV
Client ID:
Sample Type:CCV
Inject. Date:11-Nov-2024 05:00:59 ALS Bottle#:0 Worklist Smp#:2
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ccv m
Operator ID:MED Instrument ID:VMS_MS14
Sublist:chrom-AQ_VMS14_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:11-Nov-2024 05:54:25 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1688
First Level Reviewer: BX8N Date:11-Nov-2024 05:20:28
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.357 5.357 0.000 99 1143144 50.0 50.0
* 2 Chlorobenzene-d5 119 7.929 7.929 0.000 85 303107 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.173 0.000 95 502015 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.839 4.839 0.000 94 284726 50.0 51.4
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 96 327440 50.0 47.3
$ 6 Toluene-d8 (Surr) 98 6.633 6.633 0.000 92 1233861 50.0 51.6
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 89 457847 50.0 47.7
10 Dichlorodifluoromethane 85 1.791 1.791 0.000 99 226622 50.0 34.7
12 Chloromethane 50 1.974 1.974 0.000 99 406841 50.0 47.9
13 Vinyl chloride 62 2.090 2.090 0.000 98 329874 50.0 50.9
15 Bromomethane 94 2.389 2.389 0.000 90 206962 50.0 48.9
16 Chloroethane 64 2.489 2.489 0.000 99 192278 50.0 47.6
17 Dichlorofluoromethane 67 2.675 2.675 0.000 97 505452 50.0 49.7
18 Trichlorofluoromethane 101 2.711 2.711 0.000 97 341079 50.0 49.1
21 Ethyl ether 59 2.936 2.936 0.000 90 230475 50.0 52.5
22 Acrolein 56 3.055 3.055 0.000 100 1173135 493.8 526.8
25 1,1-Dichloroethene 96 3.138 3.138 0.000 97 214956 50.0 51.7
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.141 3.141 0.000 95 132584 50.0 47.0
26 Acetone 43 3.164 3.164 0.000 100 1326587 200.0 178.9
29 Iodomethane 142 3.267 3.267 0.000 98 262842 50.0 53.3
30 Carbon disulfide 76 3.334 3.334 0.000 98 622521 50.0 50.3
32 Methyl acetate 43 3.399 3.399 0.000 97 1135322 100.0 93.5
33 3-Chloro-1-propene 41 3.418 3.418 0.000 94 343711 50.0 48.3
34 Methylene Chloride 84 3.518 3.518 0.000 90 281947 50.0 48.3
35 2-Methyl-2-propanol 59 3.579 3.579 0.000 100 2199242 500.0 448.0
36 Acrylonitrile 53 3.688 3.688 0.000 99 3162837 500.0 489.3
37 Methyl tert-butyl ether 73 3.714 3.714 0.000 93 812549 50.0 50.0
38 trans-1,2-Dichloroethene 96 3.727 3.727 0.000 99 216456 50.0 49.1
39 Hexane 57 3.929 3.929 0.000 90 256933 50.0 40.8
40 Vinyl acetate 43 4.032 4.032 0.000 97 1413752 100.0 107.9
42 1,1-Dichloroethane 63 4.055 4.055 0.000 95 386012 50.0 49.1
11/15/2024
3:53:55 PM
Page 646 of 777
Report Date: 11-Nov-2024 05:54:26 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004265.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
45 2-Butanone (MEK) 43 4.456 4.456 0.000 99 2159163 200.0 185.9
47 cis-1,2-Dichloroethene 96 4.482 4.482 0.000 79 254002 50.0 49.5
48 2,2-Dichloropropane 77 4.495 4.495 0.000 84 315290 50.0 51.4
50 sec-Butyl Alcohol 45 4.575 4.575 0.000 99 3762685 1200.0 1097.0
52 Chlorobromomethane 128 4.662 4.662 0.000 95 139664 50.0 52.0
53 Tetrahydrofuran 42 4.678 4.678 0.000 88 648828 100.0 90.9
54 Chloroform 83 4.720 4.720 0.000 92 374624 50.0 47.3
55 1,1,1-Trichloroethane 97 4.871 4.871 0.000 98 301631 50.0 49.2
56 Cyclohexane 56 4.936 4.936 0.000 87 330845 50.0 44.2
57 1,1-Dichloropropene 75 4.987 4.987 0.000 99 309937 50.0 47.6
59 Carbon tetrachloride 117 4.990 4.990 0.000 94 224539 50.0 48.6
58 Isobutyl alcohol 41 5.003 5.003 0.000 95 1458393 1250.0 1135.4
60 Benzene 78 5.145 5.145 0.000 94 918369 50.0 48.6
61 1,2-Dichloroethane 62 5.167 5.167 0.000 97 312121 50.0 46.2
63 n-Heptane 43 5.328 5.328 0.000 92 258713 50.0 38.6
65 Trichloroethene 95 5.640 5.640 0.000 98 245960 50.0 48.3
66 2-Pentanone 43 5.743 5.743 0.000 99 2318640 160.0 142.1
67 Methylcyclohexane 55 5.842 5.842 0.000 89 250907 50.0 40.2
69 1,2-Dichloropropane 63 5.849 5.849 0.000 97 240428 50.0 47.9
70 1,4-Dioxane 88 5.903 5.903 0.000 89 236823 1000.0 905.3
71 Dibromomethane 93 5.923 5.923 0.000 96 166659 50.0 49.6
72 Dichlorobromomethane 83 6.045 6.045 0.000 99 267181 50.0 44.9
74 2-Chloroethyl vinyl ether 63 6.247 6.247 0.000 91 34129 50.0 8.66
75 cis-1,3-Dichloropropene 75 6.402 6.402 0.000 97 398081 50.0 53.7
76 4-Methyl-2-pentanone (MIBK) 43 6.501 6.501 0.000 94 2619252 200.0 191.0
77 Toluene 91 6.694 6.694 0.000 98 1076343 50.0 49.8
78 trans-1,3-Dichloropropene 75 6.868 6.868 0.000 96 370589 50.0 44.2
79 Ethyl methacrylate 69 6.884 6.884 0.000 87 492544 50.0 50.8
80 1,1,2-Trichloroethane 97 7.045 7.045 0.000 90 261130 50.0 49.9
82 Tetrachloroethene 164 7.148 7.148 0.000 97 192338 50.0 53.1
83 1,3-Dichloropropane 76 7.196 7.196 0.000 88 452915 50.0 49.5
84 2-Hexanone 43 7.215 7.215 0.000 95 2310993 200.0 189.6
85 Chlorodibromomethane 129 7.392 7.392 0.000 90 223920 50.0 47.9
86 Ethylene Dibromide 107 7.514 7.514 0.000 99 289459 50.0 51.5
87 1-Chlorohexane 91 7.907 7.907 0.000 95 259283 40.0 38.2
88 Chlorobenzene 112 7.955 7.955 0.000 95 708463 50.0 49.2
89 1,1,1,2-Tetrachloroethane 131 8.022 8.022 0.000 95 223563 50.0 51.4
90 Ethylbenzene 106 8.029 8.029 0.000 98 367259 50.0 48.3
91 m-Xylene & p-Xylene 106 8.148 8.148 0.000 100 456951 50.0 48.8
92 o-Xylene 106 8.511 8.511 0.000 96 451264 50.0 46.9
93 Styrene 104 8.527 8.527 0.000 94 784935 50.0 48.6
94 Bromoform 173 8.710 8.710 0.000 97 182714 50.0 49.5
95 Isopropylbenzene 105 8.858 8.858 0.000 95 1052579 50.0 49.6
97 Cyclohexanone 55 8.958 8.958 0.000 90 2236546 1500.0 1825.9
98 1,1,2,2-Tetrachloroethane 83 9.141 9.141 0.000 94 447247 50.0 54.2
99 trans-1,4-Dichloro-2-butene 53 9.177 9.177 0.000 88 152239 50.0 46.4
100 Bromobenzene 156 9.186 9.186 0.000 95 299314 50.0 50.5
101 1,2,3-Trichloropropane 110 9.209 9.209 0.000 84 170897 50.0 52.6
102 N-Propylbenzene 120 9.257 9.257 0.000 99 308930 50.0 48.8
103 2-Chlorotoluene 126 9.360 9.360 0.000 96 269953 50.0 48.8
104 1,3,5-Trimethylbenzene 105 9.431 9.431 0.000 95 940982 50.0 47.2
105 4-Chlorotoluene 126 9.479 9.479 0.000 97 289575 50.0 49.0
11/15/2024
3:53:55 PM
Page 647 of 777
Report Date: 11-Nov-2024 05:54:26 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004265.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
107 tert-Butylbenzene 119 9.746 9.746 0.000 93 835011 50.0 48.3
108 1,2,4-Trimethylbenzene 105 9.804 9.804 0.000 97 980721 50.0 46.1
109 sec-Butylbenzene 134 9.968 9.968 0.000 94 243474 50.0 46.7
110 1,3-Dichlorobenzene 146 10.099 10.099 0.000 98 568851 50.0 47.8
111 4-Isopropyltoluene 119 10.112 10.112 0.000 97 1043592 50.0 46.1
112 1,4-Dichlorobenzene 146 10.196 10.196 0.000 95 570001 50.0 50.2
114 n-Butylbenzene 91 10.524 10.524 0.000 98 939155 50.0 43.5
115 1,2-Dichlorobenzene 146 10.559 10.559 0.000 98 553100 50.0 48.9
116 1,2-Dibromo-3-Chloropropane 157 11.344 11.344 0.000 88 182522 50.0 51.6
118 1,2,4-Trichlorobenzene 180 12.180 12.180 0.000 94 397265 50.0 49.0
119 Hexachlorobutadiene 225 12.321 12.321 0.000 97 165736 50.0 48.0
120 Naphthalene 128 12.453 12.453 0.000 97 1483000 50.0 45.8
121 1,2,3-Trichlorobenzene 180 12.678 12.678 0.000 96 392654 50.0 49.7
136 Butadiene 54 0.000 ND ND
S 154 1,3-Dichloropropene, Total 1 0 100.0 97.9
S 151 1,2-Dichloroethene, Total 1 0 100.0 98.7
S 152 Trihalomethanes, Total 1 0 200.0 189.5
S 155 Xylenes, Total 106 0 100.0 95.7
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
MV-MegaMainA_00118 Amount Added: 25.00 Units: uL
MV-Gas A_00202 Amount Added: 10.00 Units: uL
mv-IS_SS_00089 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 648 of 777
Report Date: 11-Nov-2024 05:54:26 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004265.D
Injection Date:11-Nov-2024 05:00:59 Instrument ID:VMS_MS14 Operator ID:MED
Lims ID:CCV Worklist Smp#:2
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
32
34
36
38
40
42
44
46
48
Y ( X10
0
0
0
0
)
0000004265[MS Quad Chro]:Total

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11/15/2024
3:53:55 PM
Page 649 of 777
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-198899-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_X4
10/29/2024 20:20
10/29/2024 17:11
10/29/2024 20:00
ICV 280-672931/44
RXI-624SilMS
Lab File ID:X4_00008670.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Dichlorodifluoromethane 0.25740.2857 0.1000 45.0 50.0 -9.9 30.0Ave
Chloromethane 0.36530.4254 0.1000 42.9 50.0 -14.1 30.0Ave
Vinyl chloride 0.33260.3228 0.0100 51.5 50.0 3.0 30.0Ave
Bromomethane 0.0902 0.0100 42.6 50.0 -14.9 30.0Lin2
Chloroethane 0.20260.2112 0.0100 48.0 50.0 -4.1 30.0Ave
Dichlorofluoromethane 0.49360.5005 0.0100 49.3 50.0 -1.4 30.0Ave
Trichlorofluoromethane 0.28770.3038 0.0100 47.4 50.0 -5.3 30.0Ave
Ethyl ether 0.26580.2809 0.0100 47.3 50.0 -5.4 30.0Ave
Acrolein 0.0383 0.0010 223 494 -54.8*30.0Lin2
1,1,2-Trichloro-1,2,2-trifluoroethane 0.12960.1415 0.0500 45.8 50.0 -8.4 30.0Ave
1,1-Dichloroethene 0.18510.2053 0.0600 45.1 50.0 -9.9 30.0Ave
Acetone 0.3135 0.0100 190 200 -5.0 30.0Lin2
Iodomethane 0.0836 0.0100 40.5 50.0 -19.1 30.0Qua
Carbon disulfide 0.7051 0.1000 46.4 50.0 -7.1 30.0Lin2
Methyl acetate 0.61770.6295 0.0100 98.1 100 -1.9 30.0Ave
3-Chloro-1-propene 0.63490.6492 0.0100 48.9 50.0 -2.2 30.0Ave
Methylene Chloride 0.2506 0.0100 47.0 50.0 -6.1 30.0Lin2
2-Methyl-2-propanol 0.16510.1758 0.0010 470 500 -6.1 30.0Ave
Acrylonitrile 0.29290.2939 0.0100 498 500 -0.3 30.0Ave
Methyl tert-butyl ether 0.88410.8862 0.1000 49.9 50.0 -0.2 30.0Ave
trans-1,2-Dichloroethene 0.21260.2336 0.1000 45.5 50.0 -9.0 30.0Ave
Hexane 1.8932.071 0.0100 45.7 50.0 -8.6 30.0Ave
Vinyl acetate 0.91800.9339 0.0100 98.3 100 -1.7 30.0Ave
1,1-Dichloroethane 0.51210.5291 0.1000 48.4 50.0 -3.2 30.0Ave
2-Butanone (MEK)0.5464 0.0100 195 200 -2.5 30.0Lin2
cis-1,2-Dichloroethene 0.24090.2626 0.1000 45.9 50.0 -8.3 30.0Ave
2,2-Dichloropropane 0.36430.3947 0.0100 46.2 50.0 -7.7 30.0Ave
sec-Butyl Alcohol 0.17140.1646 0.0100 1250 1200 4.1 30.0Ave
Chlorobromomethane 0.10530.1132 0.0500 46.5 50.0 -7.0 30.0Ave
Tetrahydrofuran 0.36250.3768 0.0010 96.2 100 -3.8 30.0Ave
Chloroform 0.39520.4151 0.2000 47.6 50.0 -4.8 30.0Ave
1,1,1-Trichloroethane 0.31030.3235 0.0500 48.0 50.0 -4.1 30.0Ave
Cyclohexane 0.55160.5801 0.0100 47.5 50.0 -4.9 30.0Ave
1,1-Dichloropropene 0.34920.3775 0.0100 46.3 50.0 -7.5 30.0Ave
Carbon tetrachloride 0.24120.2514 0.1000 48.0 50.0 -4.0 30.0Ave
Isobutyl alcohol 0.06590.0664 0.0010 1240 1250 -0.7 30.0Ave
Benzene 1.0851.123 0.2000 48.3 50.0 -3.4 30.0Ave
1,2-Dichloroethane 0.37730.3939 0.0700 47.9 50.0 -4.2 30.0Ave
n-Heptane 0.43670.4649 47.0 50.0 -6.1 20.0Ave
Trichloroethene 1.1331.186 0.2000 47.8 50.0 -4.5 30.0Ave
FORM VII 8260D
11/15/2024
3:53:55 PM
Page 650 of 777
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-198899-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_X4
10/29/2024 20:20
10/29/2024 17:11
10/29/2024 20:00
ICV 280-672931/44
RXI-624SilMS
Lab File ID:X4_00008670.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
2-Pentanone 0.83220.8583 0.0010 155 160 -3.0 30.0Ave
Methylcyclohexane 0.38930.4225 0.0500 46.1 50.0 -7.8 30.0Ave
1,2-Dichloropropane 0.31000.3192 0.1000 48.6 50.0 -2.9 30.0Ave
1,4-Dioxane 0.01200.0131 0.0010 915 1000 -8.5 30.0Ave
Dibromomethane 0.14620.1586 0.0100 46.1 50.0 -7.8 30.0Ave
Dichlorobromomethane 0.29890.2949 0.2000 50.7 50.0 1.4 30.0Ave
2-Chloroethyl vinyl ether 0.2606 0.0100 49.8 50.0 -0.3 30.0Lin1
cis-1,3-Dichloropropene 1.9161.998 0.2000 47.9 50.0 -4.1 30.0Ave
4-Methyl-2-pentanone (MIBK)0.88340.8545 0.0300 207 200 3.4 30.0Ave
Toluene 1.0801.145 0.3000 47.1 50.0 -5.7 30.0Ave
trans-1,3-Dichloropropene 0.41750.4026 0.2000 51.8 50.0 3.7 30.0Ave
Ethyl methacrylate 2.3082.347 0.0100 49.2 50.0 -1.7 30.0Ave
1,1,2-Trichloroethane 0.22310.2285 0.1000 48.8 50.0 -2.4 30.0Ave
Tetrachloroethene 0.78130.8088 0.1000 48.3 50.0 -3.4 30.0Ave
1,3-Dichloropropane 2.1132.120 0.0100 49.8 50.0 -0.3 30.0Ave
2-Hexanone 3.4803.428 0.0100 203 200 1.5 30.0Ave
Chlorodibromomethane 0.89710.8835 0.1000 50.8 50.0 1.5 30.0Ave
Ethylene Dibromide 1.052 0.1000 47.7 50.0 -4.7 30.0Lin2
1-Chlorohexane 1.501 0.0100 39.5 40.0 -1.2 30.0Lin2
Chlorobenzene 2.9553.022 0.3000 48.9 50.0 -2.2 30.0Ave
1,1,1,2-Tetrachloroethane 0.89540.8779 0.0100 51.0 50.0 2.0 30.0Ave
Ethylbenzene 1.6371.708 0.3000 47.9 50.0 -4.2 30.0Ave
m-Xylene & p-Xylene 2.021 0.1000 46.4 50.0 -7.2 30.0Lin2
o-Xylene 1.9772.034 0.2000 48.6 50.0 -2.8 30.0Ave
Styrene 3.3473.375 0.2000 49.6 50.0 -0.8 30.0Ave
Bromoform 0.63380.6175 0.1000 51.3 50.0 2.6 30.0Ave
Isopropylbenzene 3.0622.949 0.3000 51.9 50.0 3.8 30.0Ave
Cyclohexanone 0.31060.2620 0.0010 1780 1500 18.5 30.0Ave
1,1,2,2-Tetrachloroethane 1.0521.106 0.3000 47.6 50.0 -4.9 30.0Ave
Bromobenzene 0.68400.7382 0.0100 46.3 50.0 -7.3 30.0Ave
trans-1,4-Dichloro-2-butene 0.26100.2636 0.0100 49.5 50.0 -1.0 30.0Ave
1,2,3-Trichloropropane 0.35440.3808 0.0100 46.5 50.0 -6.9 30.0Ave
N-Propylbenzene 0.80950.8476 0.0100 47.8 50.0 -4.5 30.0Ave
2-Chlorotoluene 0.67360.7292 0.0100 46.2 50.0 -7.6 30.0Ave
1,3,5-Trimethylbenzene 2.4102.573 0.0100 46.8 50.0 -6.3 30.0Ave
4-Chlorotoluene 0.71830.7671 0.0100 46.8 50.0 -6.4 30.0Ave
tert-Butylbenzene 1.9522.122 0.0100 46.0 50.0 -8.0 30.0Ave
1,2,4-Trimethylbenzene 2.4882.704 0.3000 46.0 50.0 -8.0 30.0Ave
sec-Butylbenzene 0.58270.6204 0.0100 47.0 50.0 -6.1 30.0Ave
1,3-Dichlorobenzene 1.2901.401 0.5000 46.0 50.0 -7.9 30.0Ave
4-Isopropyltoluene 2.3622.608 0.0100 45.3 50.0 -9.4 30.0Ave
FORM VII 8260D
11/15/2024
3:53:55 PM
Page 651 of 777
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-198899-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_X4
10/29/2024 20:20
10/29/2024 17:11
10/29/2024 20:00
ICV 280-672931/44
RXI-624SilMS
Lab File ID:X4_00008670.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
1,4-Dichlorobenzene 1.3341.453 0.5000 45.9 50.0 -8.2 30.0Ave
n-Butylbenzene 2.2442.438 0.0100 46.0 50.0 -8.0 30.0Ave
1,2-Dichlorobenzene 1.2511.396 0.5000 44.8 50.0 -10.4 30.0Ave
1,2-Dibromo-3-Chloropropane 0.30000.3375 0.0100 44.5 50.0 -11.1 30.0Ave
1,2,4-Trichlorobenzene 0.71260.8453 0.2000 42.1 50.0 -15.7 30.0Ave
Hexachlorobutadiene 0.2763 0.0100 48.4 50.0 -3.2 30.0Lin1
Naphthalene 2.701 0.0100 40.9 50.0 -18.3 30.0Lin2
1,2,3-Trichlorobenzene 0.6376 0.3000 42.5 50.0 -15.0 30.0Lin2
Dibromofluoromethane (Surr)0.20320.2026 0.0100 50.1 50.0 0.3 30.0Ave
1,2-Dichloroethane-d4 (Surr)0.31040.3038 0.0100 51.1 50.0 2.2 30.0Ave
Toluene-d8 (Surr)4.8004.698 0.0100 51.1 50.0 2.2 30.0Ave
4-Bromofluorobenzene (Surr)0.96900.9751 0.0100 49.7 50.0 -0.6 30.0Ave
FORM VII 8260D
11/15/2024
3:53:55 PM
Page 652 of 777
Report Date: 29-Oct-2024 21:38:01 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008670.D
Lims ID:icv
Client ID:
Sample Type:ICV
Inject. Date:29-Oct-2024 20:20:30 ALS Bottle#:11 Worklist Smp#:44
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ICV
Operator ID:CF Instrument ID:VMS_X4
Sublist:
Method:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:29-Oct-2024 21:38:00 Calib Date:29-Oct-2024 20:00:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1635
First Level Reviewer: AK2J Date:29-Oct-2024 20:58:50
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.206 5.207 -0.001 98 1652351 50.0 50.0
* 2 Chlorobenzene-d5 119 7.736 7.736 0.000 89 357229 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.961 9.961 0.000 96 572254 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.700 4.701 -0.001 93 335805 50.0 50.1
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.961 4.966 -0.005 0 512877 50.0 51.1
$ 6 Toluene-d8 (Surr) 98 6.463 6.463 0.000 95 1714697 50.0 51.1
$ 7 4-Bromofluorobenzene (Surr) 95 8.832 8.832 0.000 85 554501 50.0 49.7
9 Dichlorodifluoromethane 85 1.753 1.753 0.000 98 425309 50.0 45.0
10 Chloromethane 50 1.934 1.938 -0.004 99 603582 50.0 42.9
11 Vinyl chloride 62 2.038 2.039 -0.001 97 549601 50.0 51.5
12 Bromomethane 94 2.311 2.320 -0.009 91 148969 50.0 42.6
13 Chloroethane 64 2.416 2.420 -0.004 99 334764 50.0 48.0
14 Dichlorofluoromethane 67 2.596 2.597 -0.001 98 815650 50.0 49.3
16 Trichlorofluoromethane 101 2.629 2.629 0.000 98 475456 50.0 47.4
18 Ethyl ether 59 2.849 2.846 0.003 96 439115 50.0 47.3
19 Acrolein 56 2.962 2.962 0.000 99 625236 493.8 223.0
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.038 3.038 0.000 96 214168 50.0 45.8
21 1,1-Dichloroethene 96 3.042 3.046 -0.004 92 305827 50.0 45.1
22 Acetone 43 3.066 3.066 0.000 99 2072069 200.0 190.0
24 Iodomethane 142 3.167 3.171 -0.004 98 138054 50.0 40.5
25 Carbon disulfide 76 3.231 3.227 0.004 100 1165064 50.0 46.4
27 Methyl acetate 43 3.295 3.291 0.004 100 2041163 100.0 98.1
28 3-Chloro-1-propene 41 3.315 3.315 0.000 90 1049071 50.0 48.9
29 Methylene Chloride 84 3.412 3.416 -0.004 95 414142 50.0 47.0
30 2-Methyl-2-propanol 59 3.460 3.456 0.004 98 2727539 500.0 469.6
31 Acrylonitrile 53 3.576 3.576 0.000 99 4839751 500.0 498.4
32 Methyl tert-butyl ether 73 3.600 3.596 0.004 98 1460864 50.0 49.9
33 trans-1,2-Dichloroethene 96 3.612 3.617 -0.005 92 351233 50.0 45.5
34 Hexane 57 3.809 3.809 0.000 97 676365 50.0 45.7
35 Vinyl acetate 43 3.909 3.910 -0.001 96 3033734 100.0 98.3
36 1,1-Dichloroethane 63 3.934 3.938 -0.004 96 846133 50.0 48.4
11/15/2024
3:53:55 PM
Page 653 of 777
Report Date: 29-Oct-2024 21:38:01 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008670.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
40 2-Butanone (MEK) 43 4.323 4.323 0.000 98 3611435 200.0 195.1
42 cis-1,2-Dichloroethene 96 4.347 4.351 -0.004 90 397974 50.0 45.9
43 2,2-Dichloropropane 77 4.359 4.363 -0.004 92 601980 50.0 46.2
45 sec-Butyl Alcohol 45 4.435 4.432 0.003 100 6796746 1200.0 1249.5
47 Chlorobromomethane 128 4.524 4.524 0.000 86 173937 50.0 46.5
48 Tetrahydrofuran 42 4.536 4.536 0.000 95 1198004 100.0 96.2
49 Chloroform 83 4.584 4.584 0.000 96 652935 50.0 47.6
50 1,1,1-Trichloroethane 97 4.729 4.729 0.000 97 512661 50.0 48.0
51 Cyclohexane 56 4.789 4.789 0.000 96 911518 50.0 47.5
52 1,1-Dichloropropene 75 4.841 4.841 0.000 94 577064 50.0 46.3
53 Carbon tetrachloride 117 4.845 4.845 0.000 97 398546 50.0 48.0
54 Isobutyl alcohol 41 4.853 4.849 0.004 96 2723778 1250.0 1241.1
55 Benzene 78 4.998 4.994 0.004 98 1793319 50.0 48.3
56 1,2-Dichloroethane 62 5.022 5.026 -0.004 96 623488 50.0 47.9
58 n-Heptane 43 5.174 5.174 0.000 97 721617 50.0 47.0
60 Trichloroethene 95 5.483 5.480 0.003 97 404851 50.0 47.8
61 2-Pentanone 43 5.588 5.588 0.000 97 4400103 160.0 155.1
62 Methylcyclohexane 55 5.676 5.676 0.000 91 643253 50.0 46.1
63 1,2-Dichloropropane 63 5.692 5.692 0.000 92 512228 50.0 48.6
65 1,4-Dioxane 88 5.732 5.737 -0.005 95 397333 1000.0 915.5
66 Dibromomethane 93 5.761 5.761 -0.001 95 241495 50.0 46.1
67 Dichlorobromomethane 83 5.885 5.885 0.000 97 493912 50.0 50.7
69 2-Chloroethyl vinyl ether 63 6.086 6.082 0.004 90 430548 50.0 49.8
70 cis-1,3-Dichloropropene 75 6.234 6.235 -0.001 90 684376 50.0 47.9
71 4-Methyl-2-pentanone (MIBK) 43 6.335 6.335 0.000 97 5838477 200.0 206.8
72 Toluene 91 6.523 6.524 -0.001 97 1783810 50.0 47.1
73 trans-1,3-Dichloropropene 75 6.692 6.696 -0.004 99 689880 50.0 51.8
74 Ethyl methacrylate 69 6.712 6.712 0.000 98 824355 50.0 49.2
75 1,1,2-Trichloroethane 97 6.869 6.873 -0.004 93 368705 50.0 48.8
76 Tetrachloroethene 164 6.961 6.965 -0.004 96 279119 50.0 48.3
77 1,3-Dichloropropane 76 7.021 7.018 0.003 98 754702 50.0 49.8
78 2-Hexanone 43 7.037 7.038 -0.001 99 4972753 200.0 203.0
79 Chlorodibromomethane 129 7.214 7.210 0.004 90 320484 50.0 50.8
80 Ethylene Dibromide 107 7.330 7.335 -0.005 96 375810 50.0 47.7
81 1-Chlorohexane 91 7.716 7.720 -0.004 85 428925 40.0 39.5
82 Chlorobenzene 112 7.764 7.764 0.000 91 1055453 50.0 48.9
83 1,1,1,2-Tetrachloroethane 131 7.836 7.837 -0.001 92 319858 50.0 51.0
84 Ethylbenzene 106 7.840 7.841 -0.001 99 584741 50.0 47.9
85 m-Xylene & p-Xylene 106 7.957 7.957 0.000 0 721817 50.0 46.4
86 o-Xylene 106 8.318 8.318 0.000 98 706254 50.0 48.6
87 Styrene 104 8.334 8.335 -0.001 95 1195511 50.0 49.6
88 Bromoform 173 8.519 8.511 0.008 96 226419 50.0 51.3
89 Isopropylbenzene 105 8.660 8.656 0.004 97 1752073 50.0 51.9
91 Cyclohexanone 55 8.760 8.756 0.004 99 3328912 1500.0 1778.0
92 1,1,2,2-Tetrachloroethane 83 8.945 8.945 0.000 94 602020 50.0 47.6
93 Bromobenzene 156 8.981 8.981 0.000 96 391427 50.0 46.3
94 trans-1,4-Dichloro-2-butene 53 8.985 8.985 0.000 66 149343 50.0 49.5
95 1,2,3-Trichloropropane 110 9.013 9.009 0.004 87 202812 50.0 46.5
96 N-Propylbenzene 120 9.057 9.057 0.000 100 463223 50.0 47.8
97 2-Chlorotoluene 126 9.153 9.158 -0.005 95 385473 50.0 46.2
98 1,3,5-Trimethylbenzene 105 9.226 9.230 -0.004 96 1379142 50.0 46.8
99 4-Chlorotoluene 126 9.270 9.274 -0.004 99 411035 50.0 46.8
11/15/2024
3:53:55 PM
Page 654 of 777
Report Date: 29-Oct-2024 21:38:01 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008670.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
100 tert-Butylbenzene 119 9.539 9.539 0.000 96 1116761 50.0 46.0
102 1,2,4-Trimethylbenzene 105 9.599 9.599 0.000 99 1423804 50.0 46.0
103 sec-Butylbenzene 134 9.760 9.756 0.004 95 333462 50.0 47.0
104 1,3-Dichlorobenzene 146 9.888 9.888 0.000 97 737936 50.0 46.0
105 4-Isopropyltoluene 119 9.904 9.901 0.004 98 1351424 50.0 45.3
106 1,4-Dichlorobenzene 146 9.985 9.989 -0.004 93 763339 50.0 45.9
108 n-Butylbenzene 91 10.310 10.310 0.000 99 1283880 50.0 46.0
109 1,2-Dichlorobenzene 146 10.346 10.346 0.000 96 715827 50.0 44.8
110 1,2-Dibromo-3-Chloropropane 157 11.125 11.125 0.000 73 171692 50.0 44.5
112 1,2,4-Trichlorobenzene 180 11.948 11.948 0.000 93 407763 50.0 42.1
113 Hexachlorobutadiene 225 12.089 12.089 0.000 95 158094 50.0 48.4
114 Naphthalene 128 12.221 12.221 0.000 97 1545733 50.0 40.9
115 1,2,3-Trichlorobenzene 180 12.442 12.442 0.000 94 364879 50.0 42.5
S 122 1,2-Dichloroethene, Total (URS) 96 0 100.0 91.3
S 129 1,2-Dichloroethene, Total 1 0 100.0 91.3
S 123 Xylenes, Total (URS) 1 0 100.0 95.0
S 127 Trihalomethanes, Total 1 0 200.0 200.4
S 125 Xylenes, Total 106 0 100.0 95.0
S 124 1,3-Dichloropropene, Total 1 0 100.0 99.8
QC Flag Legend
Processing Flags
Reagents:
MV-MegaMain B_00111 Amount Added: 25.00 Units: uL
MV-Gas B_00174 Amount Added: 10.00 Units: uL
mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 655 of 777
Report Date: 29-Oct-2024 21:38:01 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008670.D
Injection Date:29-Oct-2024 20:20:30 Instrument ID:VMS_X4 Operator ID:CF
Lims ID:icv Worklist Smp#:44
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:11
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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X4_00008670[MS SCAN Chro]:Total

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11/15/2024
3:53:55 PM
Page 656 of 777
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-198899-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_X4
11/13/2024 07:20
10/29/2024 17:11
10/29/2024 20:00
CCV 280-674813/2
RXI-624SilMS
Lab File ID:X4_00009396.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Dichlorodifluoromethane 0.30280.2857 0.1000 53.0 50.0 6.0 20.0Ave
Chloromethane 0.44910.4254 0.1000 52.8 50.0 5.6 20.0Ave
Vinyl chloride 0.36350.3228 0.0100 56.3 50.0 12.6 20.0Ave
Bromomethane 0.0790 0.0100 37.2 50.0 -25.6*20.0Lin2
Chloroethane 0.23440.2112 0.0100 55.5 50.0 11.0 20.0Ave
Dichlorofluoromethane 0.57380.5005 0.0100 57.3 50.0 14.6 20.0Ave
Trichlorofluoromethane 0.32480.3038 0.0100 53.5 50.0 6.9 20.0Ave
Ethyl ether 0.27930.2809 0.0100 49.7 50.0 -0.6 20.0Ave
Acrolein 0.0879 0.0010 512 494 3.8 20.0Lin2
1,1,2-Trichloro-1,2,2-trifluoroethane 0.13780.1415 0.0500 48.7 50.0 -2.6 20.0Ave
1,1-Dichloroethene 0.20630.2053 0.0600 50.2 50.0 0.5 20.0Ave
Acetone 0.3209 0.0100 195 200 -2.7 20.0Lin2
Iodomethane 0.1284 0.0100 56.0 50.0 12.0 20.0Qua
Carbon disulfide 0.7778 0.1000 51.2 50.0 2.5 20.0Lin2
Methyl acetate 0.66740.6295 0.0100 106 100 6.0 20.0Ave
3-Chloro-1-propene 0.71840.6492 0.0100 55.3 50.0 10.7 20.0Ave
Methylene Chloride 0.2678 0.0100 50.2 50.0 0.5 20.0Lin2
2-Methyl-2-propanol 0.17380.1758 0.0010 494 500 -1.1 20.0Ave
Acrylonitrile 0.30470.2939 0.0100 518 500 3.7 20.0Ave
Methyl tert-butyl ether 0.92170.8862 0.1000 52.0 50.0 4.0 20.0Ave
trans-1,2-Dichloroethene 0.24300.2336 0.1000 52.0 50.0 4.0 20.0Ave
Hexane 1.9662.071 0.0100 47.5 50.0 -5.1 20.0Ave
Vinyl acetate 1.0840.9339 0.0100 116 100 16.1 20.0Ave
1,1-Dichloroethane 0.55180.5291 0.1000 52.1 50.0 4.3 20.0Ave
2-Butanone (MEK)0.5699 0.0100 204 200 1.8 20.0Lin2
cis-1,2-Dichloroethene 0.27030.2626 0.1000 51.5 50.0 2.9 20.0Ave
2,2-Dichloropropane 0.39790.3947 0.0100 50.4 50.0 0.8 20.0Ave
sec-Butyl Alcohol 0.17870.1646 0.0100 1300 1200 8.5 20.0Ave
Chlorobromomethane 0.11220.1132 0.0500 49.6 50.0 -0.9 20.0Ave
Tetrahydrofuran 0.38500.3768 0.0010 102 100 2.2 20.0Ave
Chloroform 0.43540.4151 0.2000 52.4 50.0 4.9 20.0Ave
1,1,1-Trichloroethane 0.34190.3235 0.0500 52.8 50.0 5.7 20.0Ave
Cyclohexane 0.58780.5801 0.0100 50.7 50.0 1.3 20.0Ave
1,1-Dichloropropene 0.38770.3775 0.0100 51.4 50.0 2.7 20.0Ave
Carbon tetrachloride 0.26910.2514 0.1000 53.5 50.0 7.1 20.0Ave
Isobutyl alcohol 0.06800.0664 0.0010 1280 1250 2.3 20.0Ave
Benzene 1.1721.123 0.2000 52.2 50.0 4.3 20.0Ave
1,2-Dichloroethane 0.40950.3939 0.0700 52.0 50.0 4.0 20.0Ave
n-Heptane 0.45510.4649 49.0 50.0 -2.1Ave
Trichloroethene 1.0891.186 0.2000 45.9 50.0 -8.2 20.0Ave
FORM VII 8260D
11/15/2024
3:53:55 PM
Page 657 of 777
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-198899-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_X4
11/13/2024 07:20
10/29/2024 17:11
10/29/2024 20:00
CCV 280-674813/2
RXI-624SilMS
Lab File ID:X4_00009396.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
2-Pentanone 0.89330.8583 0.0010 167 160 4.1 20.0Ave
Methylcyclohexane 0.41760.4225 0.0500 49.4 50.0 -1.1 20.0Ave
1,2-Dichloropropane 0.33610.3192 0.1000 52.6 50.0 5.3 20.0Ave
1,4-Dioxane 0.01240.0131 0.0010 946 1000 -5.4 20.0Ave
Dibromomethane 0.15120.1586 0.0100 47.7 50.0 -4.6 20.0Ave
Dichlorobromomethane 0.31860.2949 0.2000 54.0 50.0 8.0 20.0Ave
2-Chloroethyl vinyl ether 0.2751 0.0100 52.6 50.0 5.2 20.0Lin1
cis-1,3-Dichloropropene 2.1451.998 0.2000 53.7 50.0 7.3 20.0Ave
4-Methyl-2-pentanone (MIBK)0.96020.8545 0.0300 225 200 12.4 20.0Ave
Toluene 1.1951.145 0.3000 52.2 50.0 4.4 20.0Ave
trans-1,3-Dichloropropene 0.43320.4026 0.2000 53.8 50.0 7.6 20.0Ave
Ethyl methacrylate 2.4602.347 0.0100 52.4 50.0 4.9 20.0Ave
1,1,2-Trichloroethane 0.24040.2285 0.1000 52.6 50.0 5.2 20.0Ave
Tetrachloroethene 0.83220.8088 0.1000 51.4 50.0 2.9 20.0Ave
1,3-Dichloropropane 2.1922.120 0.0100 51.7 50.0 3.4 20.0Ave
2-Hexanone 3.6023.428 0.0100 210 200 5.1 20.0Ave
Chlorodibromomethane 0.95620.8835 0.1000 54.1 50.0 8.2 20.0Ave
Ethylene Dibromide 1.079 0.1000 48.9 50.0 -2.3 20.0Lin2
1-Chlorohexane 1.555 0.0100 40.9 40.0 2.4 20.0Lin2
Chlorobenzene 3.1003.022 0.3000 51.3 50.0 2.6 20.0Ave
1,1,1,2-Tetrachloroethane 0.94930.8779 0.0100 54.1 50.0 8.1 20.0Ave
Ethylbenzene 1.7551.708 0.3000 51.4 50.0 2.8 20.0Ave
m-Xylene & p-Xylene 2.190 0.1000 50.3 50.0 0.6 20.0Lin2
o-Xylene 2.0982.034 0.2000 51.6 50.0 3.1 20.0Ave
Styrene 3.4923.375 0.2000 51.7 50.0 3.5 20.0Ave
Bromoform 0.65610.6175 0.1000 53.1 50.0 6.2 20.0Ave
Isopropylbenzene 3.0302.949 0.3000 51.4 50.0 2.8 20.0Ave
Cyclohexanone 0.26530.2620 0.0010 1520 1500 1.2 20.0Ave
1,1,2,2-Tetrachloroethane 1.2061.106 0.3000 54.5 50.0 9.1 20.0Ave
Bromobenzene 0.75970.7382 0.0100 51.5 50.0 2.9 20.0Ave
trans-1,4-Dichloro-2-butene 0.34050.2636 0.0100 64.6 50.0 29.2*20.0Ave
1,2,3-Trichloropropane 0.37690.3808 0.0100 49.5 50.0 -1.0 20.0Ave
N-Propylbenzene 0.88200.8476 0.0100 52.0 50.0 4.1 20.0Ave
2-Chlorotoluene 0.74190.7292 0.0100 50.9 50.0 1.7 20.0Ave
1,3,5-Trimethylbenzene 2.6342.573 0.0100 51.2 50.0 2.4 20.0Ave
4-Chlorotoluene 0.78090.7671 0.0100 50.9 50.0 1.8 20.0Ave
tert-Butylbenzene 2.1472.122 0.0100 50.6 50.0 1.2 20.0Ave
1,2,4-Trimethylbenzene 2.7482.704 0.3000 50.8 50.0 1.6 20.0Ave
sec-Butylbenzene 0.61580.6204 0.0100 49.6 50.0 -0.7 20.0Ave
1,3-Dichlorobenzene 1.4141.401 0.5000 50.5 50.0 0.9 20.0Ave
4-Isopropyltoluene 2.6642.608 0.0100 51.1 50.0 2.2 20.0Ave
FORM VII 8260D
11/15/2024
3:53:55 PM
Page 658 of 777
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-198899-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_X4
11/13/2024 07:20
10/29/2024 17:11
10/29/2024 20:00
CCV 280-674813/2
RXI-624SilMS
Lab File ID:X4_00009396.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
1,4-Dichlorobenzene 1.4431.453 0.5000 49.6 50.0 -0.7 20.0Ave
n-Butylbenzene 2.4542.438 0.0100 50.3 50.0 0.7 20.0Ave
1,2-Dichlorobenzene 1.3231.396 0.5000 47.4 50.0 -5.2 20.0Ave
1,2-Dibromo-3-Chloropropane 0.32230.3375 0.0100 47.8 50.0 -4.5 20.0Ave
1,2,4-Trichlorobenzene 0.75990.8453 0.2000 44.9 50.0 -10.1 20.0Ave
Hexachlorobutadiene 0.2938 0.0100 51.5 50.0 2.9 20.0Lin1
Naphthalene 2.694 0.0100 40.7 50.0 -18.5 20.0Lin2
1,2,3-Trichlorobenzene 0.6819 0.3000 45.5 50.0 -9.0 20.0Lin2
Dibromofluoromethane (Surr)0.21140.2026 0.0100 52.2 50.0 4.3 20.0Ave
1,2-Dichloroethane-d4 (Surr)0.30760.3038 0.0100 50.6 50.0 1.3 20.0Ave
Toluene-d8 (Surr)4.6734.698 0.0100 49.7 50.0 -0.5 20.0Ave
4-Bromofluorobenzene (Surr)0.97460.9751 0.0100 50.0 50.0 -0.0 20.0Ave
FORM VII 8260D
11/15/2024
3:53:55 PM
Page 659 of 777
Report Date: 13-Nov-2024 10:03:23 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009396.D
Lims ID:CCV
Client ID:
Sample Type:CCV
Inject. Date:13-Nov-2024 07:20:30 ALS Bottle#:2 Worklist Smp#:2
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ccv m
Operator ID:wickhamt Instrument ID:VMS_X4
Sublist:chrom-VMS_X4_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:13-Nov-2024 10:03:22 Calib Date:29-Oct-2024 20:00:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1654
First Level Reviewer: AF7X Date:13-Nov-2024 07:59:36
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.207 5.207 0.000 98 1545225 50.0 50.0
* 2 Chlorobenzene-d5 119 7.736 7.736 0.000 91 343434 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.961 9.961 0.000 96 544351 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.697 4.697 0.000 92 326712 50.0 52.2
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.962 4.962 0.000 0 475342 50.0 50.6
$ 6 Toluene-d8 (Surr) 98 6.463 6.463 0.000 96 1604897 50.0 49.7
$ 7 4-Bromofluorobenzene (Surr) 95 8.832 8.832 0.000 86 530521 50.0 50.0
9 Dichlorodifluoromethane 85 1.749 1.749 0.000 99 467897 50.0 53.0
10 Chloromethane 50 1.934 1.934 0.000 99 693997 50.0 52.8
11 Vinyl chloride 62 2.035 2.035 0.000 98 561696 50.0 56.3
12 Bromomethane 94 2.312 2.312 0.000 92 122134 50.0 37.2
13 Chloroethane 64 2.412 2.412 0.000 98 362167 50.0 55.5
14 Dichlorofluoromethane 67 2.593 2.593 0.000 97 886587 50.0 57.3
16 Trichlorofluoromethane 101 2.629 2.629 0.000 98 501853 50.0 53.5
18 Ethyl ether 59 2.846 2.846 0.000 95 431605 50.0 49.7
19 Acrolein 56 2.958 2.958 0.000 99 1340552 493.8 512.3
21 1,1-Dichloroethene 96 3.042 3.042 0.000 92 318761 50.0 50.2
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.042 3.042 0.000 97 212870 50.0 48.7
22 Acetone 43 3.062 3.062 0.000 98 1983312 200.0 194.7
24 Iodomethane 142 3.167 3.167 0.000 99 198432 50.0 56.0
25 Carbon disulfide 76 3.227 3.227 0.000 100 1201940 50.0 51.2
27 Methyl acetate 43 3.291 3.291 0.000 100 2062578 100.0 106.0
28 3-Chloro-1-propene 41 3.315 3.315 0.000 90 1110071 50.0 55.3
29 Methylene Chloride 84 3.412 3.412 0.000 96 413778 50.0 50.2
30 2-Methyl-2-propanol 59 3.460 3.460 0.000 98 2685876 500.0 494.5
31 Acrylonitrile 53 3.576 3.576 0.000 99 4707617 500.0 518.4
32 Methyl tert-butyl ether 73 3.596 3.596 0.000 99 1424167 50.0 52.0
33 trans-1,2-Dichloroethene 96 3.613 3.613 0.000 92 375457 50.0 52.0
34 Hexane 57 3.805 3.805 0.000 96 675031 50.0 47.5
35 Vinyl acetate 43 3.910 3.910 0.000 96 3350555 100.0 116.1
36 1,1-Dichloroethane 63 3.934 3.934 0.000 96 852679 50.0 52.1
11/15/2024
3:53:55 PM
Page 660 of 777
Report Date: 13-Nov-2024 10:03:23 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009396.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
40 2-Butanone (MEK) 43 4.319 4.319 0.000 98 3522602 200.0 203.5
42 cis-1,2-Dichloroethene 96 4.347 4.347 0.000 89 417710 50.0 51.5
43 2,2-Dichloropropane 77 4.355 4.355 0.000 90 614862 50.0 50.4
45 sec-Butyl Alcohol 45 4.432 4.432 0.000 100 6625777 1200.0 1302.5
47 Chlorobromomethane 128 4.524 4.524 0.000 86 173358 50.0 49.6
48 Tetrahydrofuran 42 4.536 4.536 0.000 96 1189683 100.0 102.2
49 Chloroform 83 4.580 4.580 0.000 96 672777 50.0 52.4
50 1,1,1-Trichloroethane 97 4.725 4.725 0.000 96 528323 50.0 52.8
51 Cyclohexane 56 4.789 4.789 0.000 97 908289 50.0 50.7
52 1,1-Dichloropropene 75 4.837 4.837 0.000 92 599070 50.0 51.4
53 Carbon tetrachloride 117 4.845 4.845 0.000 94 415856 50.0 53.5
54 Isobutyl alcohol 41 4.853 4.853 0.000 95 2625514 1250.0 1279.3
55 Benzene 78 4.994 4.994 0.000 98 1810845 50.0 52.2
56 1,2-Dichloroethane 62 5.022 5.022 0.000 96 632803 50.0 52.0
58 n-Heptane 43 5.174 5.174 0.000 97 703230 50.0 49.0
60 Trichloroethene 95 5.484 5.484 0.000 96 373854 50.0 45.9
61 2-Pentanone 43 5.584 5.584 0.000 97 4416901 160.0 166.5
62 Methylcyclohexane 55 5.676 5.676 0.000 96 645319 50.0 49.4
63 1,2-Dichloropropane 63 5.688 5.688 0.000 91 519371 50.0 52.6
65 1,4-Dioxane 88 5.729 5.729 0.000 94 384016 1000.0 946.1
66 Dibromomethane 93 5.761 5.761 0.000 96 233703 50.0 47.7
67 Dichlorobromomethane 83 5.881 5.881 0.000 97 492293 50.0 54.0
69 2-Chloroethyl vinyl ether 63 6.082 6.082 0.000 89 425052 50.0 52.6
70 cis-1,3-Dichloropropene 75 6.231 6.231 0.000 89 736573 50.0 53.7
71 4-Methyl-2-pentanone (MIBK) 43 6.331 6.331 0.000 97 5934984 200.0 224.7
72 Toluene 91 6.520 6.520 0.000 97 1846908 50.0 52.2
73 trans-1,3-Dichloropropene 75 6.692 6.692 0.000 99 669407 50.0 53.8
74 Ethyl methacrylate 69 6.712 6.712 0.000 98 844990 50.0 52.4
75 1,1,2-Trichloroethane 97 6.869 6.869 0.000 93 371532 50.0 52.6
76 Tetrachloroethene 164 6.961 6.961 0.000 95 285806 50.0 51.4
77 1,3-Dichloropropane 76 7.018 7.018 0.000 98 752853 50.0 51.7
78 2-Hexanone 43 7.034 7.034 0.000 99 4948513 200.0 210.1
79 Chlorodibromomethane 129 7.210 7.210 0.000 90 328397 50.0 54.1
80 Ethylene Dibromide 107 7.331 7.331 0.000 99 370432 50.0 48.9
81 1-Chlorohexane 91 7.716 7.716 0.000 80 427174 40.0 40.9
82 Chlorobenzene 112 7.764 7.764 0.000 90 1064642 50.0 51.3
83 1,1,1,2-Tetrachloroethane 131 7.833 7.833 0.000 95 326029 50.0 54.1
84 Ethylbenzene 106 7.837 7.837 0.000 99 602743 50.0 51.4
85 m-Xylene & p-Xylene 106 7.953 7.953 0.000 0 752169 50.0 50.3
86 o-Xylene 106 8.318 8.318 0.000 98 720488 50.0 51.6
87 Styrene 104 8.331 8.331 0.000 94 1199156 50.0 51.7
88 Bromoform 173 8.515 8.515 0.000 95 225320 50.0 53.1
89 Isopropylbenzene 105 8.656 8.656 0.000 97 1649532 50.0 51.4
91 Cyclohexanone 55 8.760 8.760 0.000 99 2733056 1500.0 1518.4
92 1,1,2,2-Tetrachloroethane 83 8.941 8.941 0.000 94 656666 50.0 54.5
94 trans-1,4-Dichloro-2-butene 53 8.981 8.981 0.000 60 185377 50.0 64.6
93 Bromobenzene 156 8.981 8.981 0.000 96 413521 50.0 51.5
95 1,2,3-Trichloropropane 110 9.009 9.009 0.000 88 205186 50.0 49.5
96 N-Propylbenzene 120 9.057 9.057 0.000 100 480136 50.0 52.0
97 2-Chlorotoluene 126 9.158 9.158 0.000 95 403839 50.0 50.9
98 1,3,5-Trimethylbenzene 105 9.226 9.226 0.000 96 1434069 50.0 51.2
99 4-Chlorotoluene 126 9.274 9.274 0.000 99 425086 50.0 50.9
11/15/2024
3:53:55 PM
Page 661 of 777
Report Date: 13-Nov-2024 10:03:23 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009396.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
100 tert-Butylbenzene 119 9.539 9.539 0.000 96 1168933 50.0 50.6
102 1,2,4-Trimethylbenzene 105 9.599 9.599 0.000 99 1495794 50.0 50.8
103 sec-Butylbenzene 134 9.756 9.756 0.000 95 335236 50.0 49.6
104 1,3-Dichlorobenzene 146 9.888 9.888 0.000 97 769459 50.0 50.5
105 4-Isopropyltoluene 119 9.905 9.905 0.000 98 1450281 50.0 51.1
106 1,4-Dichlorobenzene 146 9.985 9.985 0.000 92 785326 50.0 49.6
108 n-Butylbenzene 91 10.310 10.310 0.000 99 1336105 50.0 50.3
109 1,2-Dichlorobenzene 146 10.346 10.346 0.000 95 719939 50.0 47.4
110 1,2-Dibromo-3-Chloropropane 157 11.125 11.125 0.000 92 175465 50.0 47.8
112 1,2,4-Trichlorobenzene 180 11.948 11.948 0.000 93 413647 50.0 44.9
113 Hexachlorobutadiene 225 12.085 12.085 0.000 96 159955 50.0 51.5
114 Naphthalene 128 12.221 12.221 0.000 97 1466256 50.0 40.7
115 1,2,3-Trichlorobenzene 180 12.438 12.438 0.000 94 371195 50.0 45.5
S 122 1,2-Dichloroethene, Total (URS) 96 0 100.0 103.5
S 129 1,2-Dichloroethene, Total 1 0 100.0 103.5
S 123 Xylenes, Total (URS) 1 0 100.0 101.8
S 127 Trihalomethanes, Total 1 0 200.0 213.7
S 125 Xylenes, Total 106 0 100.0 101.8
S 124 1,3-Dichloropropene, Total 1 0 100.0 107.5
QC Flag Legend
Processing Flags
Reagents:
MV-MegaMainA_00118 Amount Added: 25.00 Units: uL
MV-Gas A_00202 Amount Added: 10.00 Units: uL
mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 662 of 777
Report Date: 13-Nov-2024 10:03:23 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009396.D
Injection Date:13-Nov-2024 07:20:30 Instrument ID:VMS_X4 Operator ID:wickhamt
Lims ID:CCV Worklist Smp#:2
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:2
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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11/15/2024
3:53:55 PM
Page 663 of 777
Report Date: 15-Aug-2024 07:29:37 Chrom Revision: 2.3 16-Jul-2024 14:17:34
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20240814-136504.b\VMS14_0000000565.D
Lims ID:BFB
Client ID:
Sample Type:BFB
Inject. Date:14-Aug-2024 16:57:05 ALS Bottle#:0 Worklist Smp#:1
Injection Vol:2.0 uL Dil. Factor:1.0000
Sample Info:BFB
Operator ID:bustillose Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20240814-136504.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:15-Aug-2024 07:29:36 Calib Date:15-Aug-2024 00:48:38
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20240814-136504.b\VMS14_0000000587.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1610
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
$ 9 BFB 95 9.032 9.032 0.000 90 527370 NR NR
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
Reagents:
mv-Cent BFB_00008 Amount Added: 5.00 Units: uL
11/15/2024
3:53:55 PM
Page 664 of 777
Report Date: 15-Aug-2024 07:29:37 Chrom Revision: 2.3 16-Jul-2024 14:17:34
MS Tune Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20240814-136504.b\VMS14_0000000565.D
Injection Date:14-Aug-2024 16:57:05 Instrument ID:VMS_MS14
Lims ID:BFB
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:1
Injection Vol:2.0 uL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Tune Method: BFB Method 8260
$ 9 BFB
30 50 70 90 110 130 150 170 190 210 230 250 270 290
m/z
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
Y ( X10
0
0
0
)
Tune Spec :Average 2501-2503( 9.03-9.04 ) Bgrd 2487( 8.98)
95
174 176
75
50 74
94
96 17751
m/z Ion Abundance Criteria %Relative
Abundance
95 Base peak,100%relative abundance 100.0
50 15 to 40%of m/z 95 17.1
75 30 to 60%of m/z 95 48.6
96 5 to 9%of m/z 95 6.8
173 Less than 2%of m/z 174 0.0 (0.0)
174 50 to 120%of m/z 95 83.8
175 5 to 9%of m/z 174 6.2 (7.4)
176 Greater than 95%but less than 101%of m/z 174 81.8 (97.6)
177 5 to 9%of m/z 176 5.5 (6.8)
11/15/2024
3:53:55 PM
Page 665 of 777
Report Date: 15-Aug-2024 07:29:37 Chrom Revision: 2.3 16-Jul-2024 14:17:34
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20240814-136504.b\VMS14_0000000565.D\AQ_VMS14_8260.rslt\spectra.d
Injection Date:14-Aug-2024 16:57:05
Spectrum:Tune Spec :Average 2501-2503( 9.03-9.04 ) Bgrd 2487( 8.98)
Base Peak:95.05
Minimum % Base Peak:0
Number of Points:108
m/z Y m/z Y m/z Y m/z Y
36.00 2500 70.00 2333 106.00 1158 148.00 726
37.00 12525 71.00 112 107.00 244 150.00 283
38.00 10810 72.00 1742 110.00 164 153.00 182
39.00 3920 73.00 13240 111.00 340 154.00 97
43.00 558 74.00 48336 112.00 90 155.00 824
44.00 1711 75.00 147648 113.00 270 157.00 633
45.00 2371 76.00 13180 115.00 271 159.00 458
46.00 176 77.00 1723 116.00 1073 161.00 342
47.00 3093 78.00 1124 117.00 2020 174.00 254528
48.00 1934 79.00 7508 118.00 1296 175.00 18840
49.00 11028 80.00 2290 119.00 1686 176.00 248448
50.00 51968 81.00 8360 125.00 115 177.00 16816
51.00 15354 82.00 1829 128.00 1410 178.00 580
52.00 584 83.00 296 129.00 522 179.00 109
55.00 598 86.00 128 130.00 915 191.00 530
56.00 3897 87.00 11848 131.00 499 192.00 118
57.00 7085 88.00 11696 133.00 566 193.00 698
58.00 406 91.00 1146 134.00 117 207.00 660
59.00 173 92.00 8264 135.00 531 249.00 469
60.00 2653 93.00 12404 137.00 543 250.00 95
61.00 13278 94.00 35464 140.00 140 251.00 104
62.00 12440 95.00 303680 141.00 2625 265.00 549
63.00 9607 96.00 20712 142.00 385 266.00 105
64.00 877 97.00 811 143.00 3127 281.00 7098
67.00 636 103.00 287 145.00 278 282.00 2052
68.00 29256 104.00 1235 146.00 436 283.00 1506
69.00 29248 105.00 532 147.00 193 284.00 358
11/15/2024
3:53:55 PM
Page 666 of 777
Report Date: 15-Aug-2024 07:29:37 Chrom Revision: 2.3 16-Jul-2024 14:17:34
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20240814-136504.b\VMS14_0000000565.D
Injection Date:14-Aug-2024 16:57:05 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:BFB Worklist Smp#:1
Client ID:
Injection Vol:2.0 uL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
Y ( X10
0
0
0
0
)
0000000565[MS Quad Chro]:Total
$ B
F
B
(
9
.
0
3
2
)
11/15/2024
3:53:55 PM
Page 667 of 777
Report Date: 29-Oct-2024 20:43:03 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003771.D
Lims ID:BFB
Client ID:
Sample Type:BFB
Inject. Date:29-Oct-2024 16:42:30 ALS Bottle#:0 Worklist Smp#:1
Injection Vol:2.0 uL Dil. Factor:1.0000
Sample Info:BFB
Operator ID:bustillose Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:29-Oct-2024 20:43:03 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:29-Oct-2024 17:18:49
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
$ 8 BFB 95 9.032 9.032 0.000 85 695992 NR NR
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
Reagents:
mv-Cent BFB_00008 Amount Added: 5.00 Units: uL
11/15/2024
3:53:55 PM
Page 668 of 777
Report Date: 29-Oct-2024 20:43:03 Chrom Revision: 2.3 17-Oct-2024 11:42:22
MS Tune Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003771.D
Injection Date:29-Oct-2024 16:42:30 Instrument ID:VMS_MS14
Lims ID:BFB
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:1
Injection Vol:2.0 uL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Tune Method: BFB Method 8260
$ 8 BFB
30 50 70 90 110 130 150 170 190 210 230 250 270 290
m/z
0
3
6
9
12
15
18
21
24
27
30
33
36
39
Y ( X10
0
0
0
)
Tune Spec :Average 2501-2503( 9.03-9.04 ) Bgrd 2488( 8.99) Apex 2502( 9.03)
95
174 176
75
50 74
94
9651
m/z Ion Abundance Criteria %Relative
Abundance
95 Base peak,100%relative abundance 100.0
50 15 to 40%of m/z 95 17.2
75 30 to 60%of m/z 95 47.3
96 5 to 9%of m/z 95 6.9
173 Less than 2%of m/z 174 0.0 (0.0)
174 50 to 120%of m/z 95 71.6
175 5 to 9%of m/z 174 5.5 (7.6)
176 Greater than 95%but less than 101%of m/z 174 69.5 (97.0)
177 5 to 9%of m/z 176 4.8 (6.9)
11/15/2024
3:53:55 PM
Page 669 of 777
Report Date: 29-Oct-2024 20:43:03 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003771.D\AQ_VMS14_8260.rslt\spectra.d
Injection Date:29-Oct-2024 16:42:30
Spectrum:Tune Spec :Average 2501-2503( 9.03-9.04 ) Bgrd 2488( 8.99) Apex 2502( 9.03)
Base Peak:94.95
Minimum % Base Peak:0
Number of Points:98
m/z Y m/z Y m/z Y m/z Y
36.00 3280 69.00 38544 103.00 92 145.00 467
37.00 16712 70.00 2983 104.00 1513 146.00 551
38.00 14424 71.00 127 105.00 567 148.00 1148
39.00 6597 72.00 2060 106.00 1518 149.00 178
43.00 261 73.00 16063 107.00 258 150.00 94
44.00 1464 74.00 62704 111.00 111 152.00 96
45.00 3338 75.00 190720 113.00 279 153.00 228
46.00 248 76.00 15914 115.00 326 155.00 792
47.00 5578 77.00 2478 116.00 1166 157.00 610
48.00 2570 78.00 1585 117.00 1969 159.00 395
49.00 13879 79.00 8201 118.00 1314 161.00 402
50.00 69296 80.00 2267 119.00 1498 172.00 273
51.00 23080 81.00 8177 128.00 1324 174.00 288768
52.00 654 82.00 1818 129.00 678 175.00 22032
55.00 418 83.00 90 130.00 1400 176.00 280192
56.00 5841 86.00 490 131.00 533 177.00 19328
57.00 9977 87.00 17448 133.00 187 178.00 497
58.00 445 88.00 17016 135.00 600 191.00 90
60.00 3307 91.00 1207 137.00 545 207.00 176
61.00 15696 92.00 9659 139.00 139 249.00 96
62.00 17632 93.00 14836 140.00 208 281.00 1548
63.00 12740 94.00 45824 141.00 3163 282.00 361
64.00 1235 95.00 403328 142.00 482 283.00 412
67.00 951 96.00 27984 143.00 2974
68.00 38080 97.00 977 144.00 102
11/15/2024
3:53:55 PM
Page 670 of 777
Report Date: 29-Oct-2024 20:43:03 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003771.D
Injection Date:29-Oct-2024 16:42:30 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:BFB Worklist Smp#:1
Client ID:
Injection Vol:2.0 uL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
Y ( X10
0
0
0
0
)
0000003771[MS Quad Chro]:Total
$ B
F
B
(
9
.
0
3
5)
11/15/2024
3:53:55 PM
Page 671 of 777
Report Date: 11-Nov-2024 05:57:09 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004264A.D
Lims ID:BFB
Client ID:
Sample Type:BFB
Inject. Date:11-Nov-2024 04:41:02 ALS Bottle#:0 Worklist Smp#:1
Injection Vol:2.0 uL Dil. Factor:1.0000
Sample Info:ccv s
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:11-Nov-2024 05:57:08 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1688
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
$ 8 BFB 95 9.032 9.032 0.000 88 467123 NR NR
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
Reagents:
mv-Cent BFB_00008 Amount Added: 5.00 Units: uL
11/15/2024
3:53:55 PM
Page 672 of 777
Report Date: 11-Nov-2024 05:57:09 Chrom Revision: 2.3 17-Oct-2024 11:42:22
MS Tune Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004264A.D
Injection Date:11-Nov-2024 04:41:02 Instrument ID:VMS_MS14
Lims ID:BFB
Client ID:
Operator ID:MED ALS Bottle#:0 Worklist Smp#:1
Injection Vol:2.0 uL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Tune Method: BFB Method 8260
$ 8 BFB
30 50 70 90 110 130 150 170 190 210 230 250 270 290
m/z
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
Y ( X10
0
0
0
)
Tune Spec :Average 2501-2503( 9.03-9.04 ) Bgrd 2488( 8.99) Apex 2502( 9.03)
95
174 176
75
50 74
94
96 177
m/z Ion Abundance Criteria %Relative
Abundance
95 Base peak,100%relative abundance 100.0
50 15 to 40%of m/z 95 15.7
75 30 to 60%of m/z 95 45.4
96 5 to 9%of m/z 95 6.6
173 Less than 2%of m/z 174 0.0 (0.0)
174 50 to 120%of m/z 95 79.6
175 5 to 9%of m/z 174 5.8 (7.3)
176 Greater than 95%but less than 101%of m/z 174 78.2 (98.2)
177 5 to 9%of m/z 176 5.1 (6.6)
11/15/2024
3:53:55 PM
Page 673 of 777
Report Date: 11-Nov-2024 05:57:09 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004264A.D\AQ_VMS14_8260.rslt\spectra.d
Injection Date:11-Nov-2024 04:41:02
Spectrum:Tune Spec :Average 2501-2503( 9.03-9.04 ) Bgrd 2488( 8.99) Apex 2502( 9.03)
Base Peak:94.95
Minimum % Base Peak:0
Number of Points:85
m/z Y m/z Y m/z Y m/z Y
36.00 2110 64.00 760 94.00 28856 141.00 2002
37.00 9973 67.00 1064 95.00 274368 142.00 269
38.00 10463 68.00 24560 96.00 18144 143.00 2100
39.00 3756 69.00 24240 97.00 415 145.00 89
40.00 256 70.00 1797 104.00 877 146.00 196
44.00 1041 72.00 1434 105.00 245 148.00 556
45.00 1705 73.00 11060 106.00 989 150.00 114
47.00 3454 74.00 40544 107.00 155 153.00 105
48.00 917 75.00 124648 113.00 137 155.00 727
49.00 8744 76.00 11133 115.00 210 157.00 528
50.00 43176 77.00 1254 116.00 572 161.00 355
51.00 12451 78.00 1000 117.00 1165 172.00 308
52.00 649 79.00 4325 118.00 848 174.00 218368
55.00 144 80.00 1811 119.00 1159 175.00 16041
56.00 3683 81.00 5556 124.00 205 176.00 214528
57.00 5753 82.00 1084 128.00 922 177.00 14066
58.00 261 86.00 240 129.00 438 178.00 609
59.00 228 87.00 12288 130.00 852 281.00 1074
60.00 2244 88.00 11508 131.00 240 282.00 281
61.00 10255 91.00 802 135.00 239
62.00 10733 92.00 6794 137.00 431
63.00 7799 93.00 10011 140.00 131
11/15/2024
3:53:55 PM
Page 674 of 777
Report Date: 11-Nov-2024 05:57:09 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004264A.D
Injection Date:11-Nov-2024 04:41:02 Instrument ID:VMS_MS14 Operator ID:MED
Lims ID:BFB Worklist Smp#:1
Client ID:
Injection Vol:2.0 uL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
Y ( X10
0
0
0
0
)
000004264A[MS Quad Chro]:Total
$ B
F
B
(
9
.
0
3
2
)
11/15/2024
3:53:55 PM
Page 675 of 777
Report Date: 23-Sep-2024 17:47:47 Chrom Revision: 2.3 26-Aug-2024 17:14:48
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20240923-137770.b\X4_00006833.D
Lims ID:BFB
Client ID:
Sample Type:BFB
Inject. Date:23-Sep-2024 06:22:30 ALS Bottle#:100 Worklist Smp#:1
Injection Vol:2.0 uL Dil. Factor:1.0000
Sample Info:bfb
Operator ID:wickhamt Instrument ID:VMS_X4
Method:\\chromfs\Denver\ChromData\VMS_X4\20240923-137770.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:23-Sep-2024 17:47:47 Calib Date:23-Sep-2024 13:51:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20240923-137770.b\X4_00006850.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1626
First Level Reviewer: AF7X Date:23-Sep-2024 07:22:07
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
$ 8 BFB 95 8.824 8.824 0.000 79 499300 NR NR
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
Reagents:
mv-Cent BFB_00008 Amount Added: 5.00 Units: uL
11/15/2024
3:53:55 PM
Page 676 of 777
Report Date: 23-Sep-2024 17:47:47 Chrom Revision: 2.3 26-Aug-2024 17:14:48
MS Tune Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20240923-137770.b\X4_00006833.D
Injection Date:23-Sep-2024 06:22:30 Instrument ID:VMS_X4
Lims ID:BFB
Client ID:
Operator ID:wickhamt ALS Bottle#:100 Worklist Smp#:1
Injection Vol:2.0 uL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Tune Method: BFB Method 8260
$ 8 BFB
30 50 70 90 110 130 150 170 190 210 230 250 270 290 310
m/z
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
Y ( X
1
0
0
0
0
)
Tune Spec :Average 1926-1928( 8.82-8.83 ) Bgrd 1914( 8.77)
95
174 176
75
50
74
9451 9638
m/z Ion Abundance Criteria %Relative
Abundance
95 Base peak,100%relative abundance 100.0
50 15 to 40%of m/z 95 24.1
75 30 to 60%of m/z 95 52.3
96 5 to 9%of m/z 95 6.8
173 Less than 2%of m/z 174 0.0 (0.0)
174 50 to 120%of m/z 95 63.3
175 5 to 9%of m/z 174 4.4 (7.0)
176 Greater than 95%but less than 101%of m/z 174 63.0 (99.4)
177 5 to 9%of m/z 176 3.9 (6.1)
11/15/2024
3:53:55 PM
Page 677 of 777
Report Date: 23-Sep-2024 17:47:47 Chrom Revision: 2.3 26-Aug-2024 17:14:48
Data File:\\chromfs\Denver\ChromData\VMS_X4\20240923-137770.b\X4_00006833.D\VMS_X4_8260.rslt\spectra.d
Injection Date:23-Sep-2024 06:22:30
Spectrum:Tune Spec :Average 1926-1928( 8.82-8.83 ) Bgrd 1914( 8.77)
Base Peak:95.00
Minimum % Base Peak:0
Number of Points:112
m/z Y m/z Y m/z Y m/z Y
36.00 3919 70.00 2384 107.00 158 148.00 400
37.00 20376 72.00 1944 110.00 112 149.00 243
38.00 18536 73.00 13770 111.00 146 150.00 278
39.00 6820 74.00 47616 113.00 116 152.00 78
40.00 323 75.00 153600 115.00 334 153.00 181
43.00 300 76.00 12753 116.00 907 154.00 60
44.00 2148 77.00 2178 117.00 1051 155.00 389
45.00 3691 78.00 1378 118.00 615 157.00 392
46.00 181 79.00 5864 119.00 1110 158.00 189
47.00 6669 80.00 1990 124.00 142 159.00 105
48.00 2393 81.00 5744 125.00 281 160.00 107
49.00 14490 82.00 1145 126.00 104 161.00 94
50.00 70624 83.00 161 128.00 838 168.00 71
51.00 22728 86.00 419 129.00 367 172.00 302
52.00 1089 87.00 15088 130.00 589 174.00 185920
55.00 667 88.00 13279 131.00 255 175.00 13023
56.00 4955 89.00 181 132.00 57 176.00 184832
57.00 8632 91.00 1046 135.00 453 177.00 11356
58.00 412 92.00 6755 137.00 259 178.00 283
60.00 2748 93.00 10911 139.00 143 191.00 99
61.00 16156 94.00 30448 140.00 213 207.00 106
62.00 14105 95.00 293504 141.00 1819 265.00 65
63.00 11057 96.00 20072 142.00 261 280.00 147
64.00 847 97.00 781 143.00 1817 281.00 835
65.00 56 103.00 142 144.00 188 282.00 309
67.00 946 104.00 1157 145.00 87 283.00 84
68.00 30376 105.00 345 146.00 240 284.00 100
69.00 29384 106.00 941 148.00 118 303.00 54
11/15/2024
3:53:55 PM
Page 678 of 777
Report Date: 23-Sep-2024 17:47:47 Chrom Revision: 2.3 26-Aug-2024 17:14:48
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20240923-137770.b\X4_00006833.D
Injection Date:23-Sep-2024 06:22:30 Instrument ID:VMS_X4 Operator ID:wickhamt
Lims ID:BFB Worklist Smp#:1
Client ID:
Injection Vol:2.0 uL Dil. Factor:1.0000 ALS Bottle#:100
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Y ( X
1
0
0
0
0
0
)
X4_00006833[MS SCAN Chro]:Total
$ B
F
B
(
8
.
8
2
4
)
11/15/2024
3:53:55 PM
Page 679 of 777
Report Date: 29-Oct-2024 21:38:00 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008660.D
Lims ID:BFB
Client ID:
Sample Type:BFB
Inject. Date:29-Oct-2024 16:50:30 ALS Bottle#:1 Worklist Smp#:1
Injection Vol:2.0 uL Dil. Factor:1.0000
Sample Info:BFB
Operator ID:CF Instrument ID:VMS_X4
Method:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:29-Oct-2024 21:38:00 Calib Date:29-Oct-2024 20:00:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1635
First Level Reviewer: AK2J Date:29-Oct-2024 17:40:01
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
$ 8 BFB 95 8.832 8.832 0.000 84 508282 NR NR
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
Reagents:
mv-Cent BFB_00008 Amount Added: 5.00 Units: uL
11/15/2024
3:53:55 PM
Page 680 of 777
Report Date: 29-Oct-2024 21:38:00 Chrom Revision: 2.3 17-Oct-2024 11:42:22
MS Tune Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008660.D
Injection Date:29-Oct-2024 16:50:30 Instrument ID:VMS_X4
Lims ID:BFB
Client ID:
Operator ID:CF ALS Bottle#:1 Worklist Smp#:1
Injection Vol:2.0 uL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Tune Method: BFB Method 8260
$ 8 BFB
30 50 70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370
m/z
0
2
4
6
8
10
12
14
16
18
20
22
Y ( X
1
0
0
0
0
)
Tune Spec :Average 1925-1932( 8.82-8.84 ) Bgrd 1917( 8.78) Apex 1929( 8.83)
95
174 176
75
50
74
9468
96
m/z Ion Abundance Criteria %Relative
Abundance
95 Base peak,100%relative abundance 100.0
50 15 to 40%of m/z 95 24.7
75 30 to 60%of m/z 95 55.1
96 5 to 9%of m/z 95 6.5
173 Less than 2%of m/z 174 0.4 (0.5)
174 50 to 120%of m/z 95 76.1
175 5 to 9%of m/z 174 6.2 (8.1)
176 Greater than 95%but less than 101%of m/z 174 73.4 (96.5)
177 5 to 9%of m/z 176 4.9 (6.7)
11/15/2024
3:53:55 PM
Page 681 of 777
Report Date: 29-Oct-2024 21:38:00 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008660.D\VMS_X4_8260.rslt\spectra.d
Injection Date:29-Oct-2024 16:50:30
Spectrum:Tune Spec :Average 1925-1932( 8.82-8.84 ) Bgrd 1917( 8.78) Apex 1929( 8.83)
Base Peak:95.00
Minimum % Base Peak:0
Number of Points:128
m/z Y m/z Y m/z Y m/z Y
36.00 3108 74.00 41072 115.00 253 156.00 83
37.00 16560 75.00 126112 116.00 762 157.00 326
38.00 14543 76.00 10485 117.00 1159 158.00 22
39.00 5181 77.00 1530 118.00 918 159.00 126
43.00 357 78.00 949 119.00 807 161.00 339
44.00 1610 79.00 4035 120.00 63 166.00 78
45.00 2821 80.00 1470 125.00 22 168.00 125
46.00 152 81.00 4851 128.00 703 169.00 86
47.00 5176 82.00 1232 129.00 421 170.00 78
48.00 1778 83.00 164 130.00 812 172.00 169
49.00 12953 86.00 394 131.00 289 173.00 748
50.00 56536 87.00 9536 134.00 55 173.00 180
51.00 18552 88.00 9143 135.00 392 174.00 174016
52.00 779 89.00 152 136.00 20 175.00 14125
54.00 49 90.00 87 137.00 419 176.00 168000
55.00 780 91.00 799 138.00 31 177.00 11297
56.00 3688 92.00 5503 139.00 129 178.00 400
57.00 7804 93.00 9617 140.00 245 187.00 54
58.00 257 94.00 26000 141.00 1999 189.00 39
60.00 2560 95.00 228736 142.00 80 190.00 65
61.00 12922 96.00 14968 143.00 1960 193.00 82
62.00 12465 97.00 504 144.00 53 194.00 19
63.00 8744 98.00 106 146.00 114 207.00 165
64.00 616 104.00 970 146.00 293 210.00 28
66.00 29 105.00 288 147.00 88 249.00 34
67.00 838 106.00 899 148.00 216 250.00 34
68.00 25208 107.00 126 150.00 230 281.00 646
69.00 26360 110.00 50 151.00 32 282.00 200
70.00 1869 111.00 306 152.00 28 283.00 40
71.00 245 112.00 173 154.00 38 343.00 26
72.00 1105 113.00 86 155.00 21 350.00 23
73.00 10864 114.00 55 155.00 508 362.00 21
11/15/2024
3:53:55 PM
Page 682 of 777
Report Date: 29-Oct-2024 21:38:00 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008660.D
Injection Date:29-Oct-2024 16:50:30 Instrument ID:VMS_X4 Operator ID:CF
Lims ID:BFB Worklist Smp#:1
Client ID:
Injection Vol:2.0 uL Dil. Factor:1.0000 ALS Bottle#:1
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
Y ( X
1
0
0
0
0
0
)
X4_00008660[MS SCAN Chro]:Total
$ B
F
B
(
8
.
8
3
2
)
11/15/2024
3:53:55 PM
Page 683 of 777
Report Date: 13-Nov-2024 10:03:21 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009394.D
Lims ID:BFB
Client ID:
Sample Type:BFB
Inject. Date:13-Nov-2024 06:26:30 ALS Bottle#:100 Worklist Smp#:1
Injection Vol:2.0 uL Dil. Factor:1.0000
Sample Info:bfb
Operator ID:wickhamt Instrument ID:VMS_X4
Method:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:13-Nov-2024 10:03:21 Calib Date:29-Oct-2024 20:00:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1654
First Level Reviewer: AF7X Date:13-Nov-2024 07:55:12
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
$ 8 BFB 95 8.832 8.832 0.000 85 477813 NR NR
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
Reagents:
mv-Cent BFB_00008 Amount Added: 5.00 Units: uL
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Page 684 of 777
Report Date: 13-Nov-2024 10:03:21 Chrom Revision: 2.3 12-Nov-2024 16:55:22
MS Tune Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009394.D
Injection Date:13-Nov-2024 06:26:30 Instrument ID:VMS_X4
Lims ID:BFB
Client ID:
Operator ID:wickhamt ALS Bottle#:100 Worklist Smp#:1
Injection Vol:2.0 uL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Tune Method: BFB Method 8260
$ 8 BFB
30 50 70 90 110 130 150 170 190 210 230 250 270 290
m/z
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
Y ( X
1
0
0
0
0
)
Tune Spec :Average 1928-1930( 8.83-8.84 ) Bgrd 1917( 8.78) Apex 1929( 8.83)
95
174 176
75
50
74
9468 2819638
m/z Ion Abundance Criteria %Relative
Abundance
95 Base peak,100%relative abundance 100.0
50 15 to 40%of m/z 95 26.9
75 30 to 60%of m/z 95 53.7
96 5 to 9%of m/z 95 6.7
173 Less than 2%of m/z 174 0.3 (0.4)
174 50 to 120%of m/z 95 77.3
175 5 to 9%of m/z 174 6.1 (7.9)
176 Greater than 95%but less than 101%of m/z 174 75.2 (97.3)
177 5 to 9%of m/z 176 4.5 (6.0)
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Report Date: 13-Nov-2024 10:03:21 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009394.D\VMS_X4_8260.rslt\spectra.d
Injection Date:13-Nov-2024 06:26:30
Spectrum:Tune Spec :Average 1928-1930( 8.83-8.84 ) Bgrd 1917( 8.78) Apex 1929( 8.83)
Base Peak:95.00
Minimum % Base Peak:0
Number of Points:146
m/z Y m/z Y m/z Y m/z Y
36.00 4603 78.00 1024 128.00 850 179.00 546
37.00 20392 79.00 5993 129.00 106 181.00 59
38.00 18272 80.00 1999 130.00 1040 189.00 341
39.00 6482 81.00 5627 131.00 477 190.00 91
40.00 699 82.00 1137 132.00 73 191.00 1661
43.00 128 86.00 377 133.00 2214 192.00 408
44.00 1821 87.00 12165 134.00 913 193.00 1967
45.00 3742 88.00 11137 135.00 485 194.00 418
46.00 257 89.00 394 137.00 367 195.00 206
47.00 6400 90.00 182 140.00 62 199.00 69
48.00 2464 91.00 1013 141.00 2104 203.00 249
49.00 14367 92.00 7608 142.00 389 205.00 554
50.00 75640 93.00 10692 143.00 2603 206.00 50
51.00 21376 94.00 30472 145.00 389 207.00 1484
52.00 1608 95.00 281216 146.00 271 208.00 507
55.00 204 96.00 18800 148.00 557 209.00 150
55.00 792 97.00 832 149.00 186 221.00 69
56.00 5725 101.00 83 150.00 149 224.00 57
57.00 9671 103.00 413 152.00 138 235.00 144
58.00 483 104.00 1414 153.00 206 249.00 1598
59.00 456 105.00 963 155.00 729 250.00 711
60.00 3645 106.00 980 156.00 87 251.00 778
61.00 14721 107.00 251 157.00 485 252.00 58
62.00 14990 109.00 70 159.00 294 265.00 1478
63.00 11178 110.00 599 161.00 275 266.00 617
64.00 749 111.00 231 163.00 649 267.00 636
67.00 1399 112.00 167 165.00 73 268.00 62
68.00 29096 113.00 110 170.00 54 277.00 50
69.00 30648 115.00 696 170.00 183 279.00 317
70.00 2841 116.00 857 171.00 505 280.00 145
71.00 259 117.00 1786 172.00 859 281.00 23840
72.00 1427 118.00 1161 173.00 782 282.00 7376
73.00 14457 119.00 1608 174.00 217408 283.00 4663
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Report Date: 13-Nov-2024 10:03:21 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009394.D\VMS_X4_8260.rslt\spectra.d
Injection Date:13-Nov-2024 06:26:30
Spectrum:Tune Spec :Average 1928-1930( 8.83-8.84 ) Bgrd 1917( 8.78) Apex 1929( 8.83)
Base Peak:95.00
Minimum % Base Peak:0
Number of Points:146
m/z Y m/z Y m/z Y m/z Y
74.00 48376 122.00 126 175.00 17208 284.00 971
75.00 151104 124.00 54 176.00 211584 285.00 273
76.00 12226 125.00 1567 177.00 12715
77.00 2094 126.00 211 178.00 515
11/15/2024
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Page 687 of 777
Report Date: 13-Nov-2024 10:03:21 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009394.D
Injection Date:13-Nov-2024 06:26:30 Instrument ID:VMS_X4 Operator ID:wickhamt
Lims ID:BFB Worklist Smp#:1
Client ID:
Injection Vol:2.0 uL Dil. Factor:1.0000 ALS Bottle#:100
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
Y ( X
1
0
0
0
0
0
)
X4_00009394[MS SCAN Chro]:Total
$ B
F
B
(
8.832
)
11/15/2024
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Page 688 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:MB 280-674451/9
Matrix:VMS14_0000004270.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 06:40
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.14100-41-4 Ethylbenzene ND
1.0 0.13100-42-5 Styrene ND
1.0 0.1610061-01-5 cis-1,3-Dichloropropene ND
1.0 0.1410061-02-6 trans-1,3-Dichloropropene ND
1.0 0.18103-65-1 N-Propylbenzene ND
1.0 0.23104-51-8 n-Butylbenzene ND
1.0 0.21106-43-4 4-Chlorotoluene ND
1.0 0.39106-46-7 1,4-Dichlorobenzene ND
1.0 0.18106-93-4 Ethylene Dibromide ND
2.0 0.46107-05-1 3-Chloro-1-propene ND
1.0 0.28107-06-2 1,2-Dichloroethane ND
3.0 0.36108-05-4 Vinyl acetate ND
5.0 0.98108-10-1 4-Methyl-2-pentanone (MIBK)ND
1.0 0.12108-67-8 1,3,5-Trimethylbenzene ND
1.0 0.19108-86-1 Bromobenzene ND
1.0 0.31108-87-2 Methylcyclohexane ND
1.0 0.32108-88-3 Toluene ND
1.0 0.092108-90-7 Chlorobenzene ND
7.0 0.84109-99-9 Tetrahydrofuran ND
2.0 0.16110-54-3 Hexane ND
1.0 0.44110-82-7 Cyclohexane ND
1.0 0.58120-82-1 1,2,4-Trichlorobenzene ND
1.0 0.28124-48-1 Chlorodibromomethane ND
1.0 0.40127-18-4 Tetrachloroethene ND
1.0 0.20135-98-8 sec-Butylbenzene ND
1.0 0.17142-28-9 1,3-Dichloropropane ND
1.0 0.32156-59-2 cis-1,2-Dichloroethene ND
1.0 0.37156-60-5 trans-1,2-Dichloroethene ND
5.0 0.251634-04-4 Methyl tert-butyl ether ND
2.0 0.36179601-23-1 m-Xylene & p-Xylene ND
1.0 0.33541-73-1 1,3-Dichlorobenzene ND
1.0 0.2356-23-5 Carbon tetrachloride ND
FORM I 8260D
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Page 689 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:MB 280-674451/9
Matrix:VMS14_0000004270.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 06:40
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.19563-58-6 1,1-Dichloropropene ND
5.0 0.81591-78-6 2-Hexanone ND
1.0 0.17594-20-7 2,2-Dichloropropane ND
2.0 0.3560-29-7 Ethyl ether ND
1.0 0.16630-20-6 1,1,1,2-Tetrachloroethane ND
15 6.667-64-1 Acetone ND
1.0 0.3667-66-3 Chloroform ND
1.0 0.1471-43-2 Benzene ND
1.0 0.3971-55-6 1,1,1-Trichloroethane ND
5.0 2.474-83-9 Bromomethane ND
2.0 0.2374-87-3 Chloromethane ND
5.0 2.674-88-4 Iodomethane ND
1.0 0.3474-95-3 Dibromomethane ND
1.0 0.4074-97-5 Chlorobromomethane ND
2.0 0.6475-00-3 Chloroethane ND
1.0 0.2375-01-4 Vinyl chloride ND
2.0 0.9475-09-2 Methylene Chloride ND
2.0 0.2675-15-0 Carbon disulfide ND
2.0 0.2575-25-2 Bromoform ND
1.0 0.1975-27-4 Dichlorobromomethane ND
1.0 0.2275-34-3 1,1-Dichloroethane ND
1.0 0.2375-35-4 1,1-Dichloroethene ND
2.0 0.2075-69-4 Trichlorofluoromethane ND
2.0 0.3075-71-8 Dichlorodifluoromethane ND
3.0 0.7376-13-1 1,1,2-Trichloro-1,2,2-trifluoroethan
e
ND
1.0 0.2478-87-5 1,2-Dichloropropane ND
10 4.678-93-3 2-Butanone (MEK)ND
1.0 0.2779-00-5 1,1,2-Trichloroethane ND
1.0 0.3079-01-6 Trichloroethene ND
5.0 1.679-20-9 Methyl acetate ND
1.0 0.2179-34-5 1,1,2,2-Tetrachloroethane ND
4.0 1.287-61-6 1,2,3-Trichlorobenzene ND
FORM I 8260D
11/15/2024
3:53:55 PM
Page 690 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:MB 280-674451/9
Matrix:VMS14_0000004270.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 06:40
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
2.0 0.5387-68-3 Hexachlorobutadiene ND
3.0 0.9991-20-3 Naphthalene ND
1.0 0.1195-47-6 o-Xylene ND
1.0 0.3495-49-8 2-Chlorotoluene ND
1.0 0.1495-50-1 1,2-Dichlorobenzene ND
1.0 0.1595-63-6 1,2,4-Trimethylbenzene ND
5.0 0.4296-12-8 1,2-Dibromo-3-Chloropropane ND
2.5 0.2896-18-4 1,2,3-Trichloropropane ND
3.0 0.1997-63-2 Ethyl methacrylate ND
1.0 0.1898-06-6 tert-Butylbenzene ND
1.0 0.1698-82-8 Isopropylbenzene ND
1.0 0.1999-87-6 4-Isopropyltoluene ND
1.0 0.111330-20-7 Xylenes, Total ND
1.0 0.32540-59-0 1,2-Dichloroethene, Total ND
1.0 0.14542-75-6 1,3-Dichloropropene, Total ND
1.0 0.19STL00209Trihalomethanes, Total ND
1.0 0.14STL00431Total BTEX ND
%RECCAS NO.LIMITSQSURROGATE
93 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr)
96 77-1201868-53-7 Dibromofluoromethane (Surr)
106 80-1252037-26-5 Toluene-d8 (Surr)
91 78-120460-00-4 4-Bromofluorobenzene (Surr)
FORM I 8260D
11/15/2024
3:53:55 PM
Page 691 of 777
Report Date: 11-Nov-2024 08:55:27 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004270.D
Lims ID:MB
Client ID:
Sample Type:MB
Inject. Date:11-Nov-2024 06:40:47 ALS Bottle#:0 Worklist Smp#:9
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:mb
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:11-Nov-2024 08:54:38 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1688
First Level Reviewer: BX8N Date:11-Nov-2024 08:54:38
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.357 0.003 99 1132550 50.0 50.0
* 2 Chlorobenzene-d5 119 7.929 7.926 0.003 85 272467 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.173 0.000 95 505850 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.842 4.839 0.003 94 263037 50.0 47.9
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 97 318606 50.0 46.5
$ 6 Toluene-d8 (Surr) 98 6.636 6.637 -0.001 92 1142017 50.0 53.2
$ 7 4-Bromofluorobenzene (Surr) 95 9.035 9.032 0.003 89 441222 50.0 45.6
$ 8 BFB 95 9.035 9.032 0.003 88 441222 NR
9 Chlorotrifluoroethene 116 1.677 ND
10 Dichlorodifluoromethane 85 1.791 ND
11 Ethylene oxide 43 1.756 1.843 -0.087 76 3135 13.1
12 Chloromethane 50 1.974 ND
13 Vinyl chloride 62 2.090 ND
14 2-Chloro-1,1,1-Trifluoroethane 118 2.110 ND
15 Bromomethane 94 2.389 ND
16 Chloroethane 64 2.489 ND
17 Dichlorofluoromethane 67 2.675 ND
18 Trichlorofluoromethane 101 2.711 ND
19 Propene oxide 58 2.738 ND
20 Ethanol 45 2.875 ND
21 Ethyl ether 59 2.936 ND
22 Acrolein 56 3.055 ND
23 1,2-Dichloro-1,1,2-trifluoroetha 117 3.129 ND
25 1,1-Dichloroethene 96 3.138 ND
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.141 ND
26 Acetone 43 3.164 ND 7
27 1,1,1-Trifluoro-2,2-dichloroetha 83 3.213 ND
28 Isopropyl alcohol 45 3.257 ND
29 Iodomethane 142 3.267 ND
30 Carbon disulfide 76 3.334 ND
31 Acetonitrile 41 3.376 3.379 -0.003 97 12806 4.71 M
32 Methyl acetate 43 3.399 ND
11/15/2024
3:53:55 PM
Page 692 of 777
Report Date: 11-Nov-2024 08:55:27 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004270.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
33 3-Chloro-1-propene 41 3.418 ND
34 Methylene Chloride 84 3.518 ND
35 2-Methyl-2-propanol 59 3.579 ND
36 Acrylonitrile 53 3.688 ND
37 Methyl tert-butyl ether 73 3.714 ND
38 trans-1,2-Dichloroethene 96 3.727 ND
39 Hexane 57 3.929 ND
40 Vinyl acetate 43 4.032 ND
42 1,1-Dichloroethane 63 4.055 ND
41 Isopropyl ether 87 4.055 ND
43 2-Chloro-1,3-butadiene 53 4.113 ND
44 Tert-butyl ethyl ether 59 4.325 ND
45 2-Butanone (MEK) 43 4.456 ND
46 Ethyl acetate 43 4.463 ND
47 cis-1,2-Dichloroethene 96 4.482 ND
48 2,2-Dichloropropane 77 4.495 ND
49 Propionitrile 54 4.505 ND
50 sec-Butyl Alcohol 45 4.575 ND
51 Methacrylonitrile 41 4.617 ND
52 Chlorobromomethane 128 4.662 ND
53 Tetrahydrofuran 42 4.678 ND
54 Chloroform 83 4.720 ND
55 1,1,1-Trichloroethane 97 4.871 ND
56 Cyclohexane 56 4.936 ND
57 1,1-Dichloropropene 75 4.987 ND
59 Carbon tetrachloride 117 4.990 ND
58 Isobutyl alcohol 41 5.003 ND U
60 Benzene 78 5.145 ND
61 1,2-Dichloroethane 62 5.167 ND
62 Tert-amyl methyl ether 73 5.209 ND
63 n-Heptane 43 5.328 ND
64 n-Butanol 56 5.502 ND
65 Trichloroethene 95 5.640 ND
66 2-Pentanone 43 5.743 ND
67 Methylcyclohexane 55 5.842 ND
68 Methyl methacrylate 100 5.846 ND
69 1,2-Dichloropropane 63 5.849 ND
70 1,4-Dioxane 88 5.903 ND
71 Dibromomethane 93 5.923 ND
72 Dichlorobromomethane 83 6.045 ND
73 2-Nitropropane 41 6.215 ND
74 2-Chloroethyl vinyl ether 63 6.247 ND
75 cis-1,3-Dichloropropene 75 6.402 ND
76 4-Methyl-2-pentanone (MIBK) 43 6.501 ND
77 Toluene 91 6.694 ND
78 trans-1,3-Dichloropropene 75 6.868 ND
79 Ethyl methacrylate 69 6.884 ND
80 1,1,2-Trichloroethane 97 7.045 ND
81 Tetrahydrothiophene 60 7.051 ND
82 Tetrachloroethene 164 7.148 ND
83 1,3-Dichloropropane 76 7.196 ND
84 2-Hexanone 43 7.215 ND
11/15/2024
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Page 693 of 777
Report Date: 11-Nov-2024 08:55:27 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004270.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
85 Chlorodibromomethane 129 7.392 ND
86 Ethylene Dibromide 107 7.514 ND
87 1-Chlorohexane 91 7.907 ND 7
88 Chlorobenzene 112 7.955 ND
89 1,1,1,2-Tetrachloroethane 131 8.022 ND
90 Ethylbenzene 106 8.029 ND
91 m-Xylene & p-Xylene 106 8.148 ND 7
92 o-Xylene 106 8.511 ND
93 Styrene 104 8.527 ND
94 Bromoform 173 8.710 ND
95 Isopropylbenzene 105 8.858 ND
96 cis-1,4-Dichloro-2-butene 53 8.907 ND
97 Cyclohexanone 55 8.958 ND
98 1,1,2,2-Tetrachloroethane 83 9.141 ND
99 trans-1,4-Dichloro-2-butene 53 9.177 ND
100 Bromobenzene 156 9.186 ND
101 1,2,3-Trichloropropane 110 9.209 ND
102 N-Propylbenzene 120 9.257 ND
103 2-Chlorotoluene 126 9.360 ND
104 1,3,5-Trimethylbenzene 105 9.431 ND
105 4-Chlorotoluene 126 9.479 ND
106 Pentachloroethane 167 9.479 ND
107 tert-Butylbenzene 119 9.746 ND
108 1,2,4-Trimethylbenzene 105 9.804 ND
109 sec-Butylbenzene 134 9.968 ND
110 1,3-Dichlorobenzene 146 10.099 ND
111 4-Isopropyltoluene 119 10.112 ND
112 1,4-Dichlorobenzene 146 10.196 ND 7
113 1,2,3-Trimethylbenzene 105 10.218 ND
114 n-Butylbenzene 91 10.524 ND
115 1,2-Dichlorobenzene 146 10.559 ND
116 1,2-Dibromo-3-Chloropropane 157 11.344 ND
117 1,3,5-Trichlorobenzene 180 11.540 ND
118 1,2,4-Trichlorobenzene 180 12.180 ND 7
119 Hexachlorobutadiene 225 12.321 ND
120 Naphthalene 128 12.453 ND 7
121 1,2,3-Trichlorobenzene 180 12.678 ND
140 2-Methylhexane 1 0.000 ND
150 4-Chlorobenzotrifluoride 1 0.000 ND
127 Pentachloroethane TIC 1 0.000 ND
138 Benzene, 1-bromo-3-fluoro- 1 0.000 ND
123 Ethyl acrylate 55 0.000 ND
148 n-Nonyl Aldehyde 1 0.000 ND
133 1,4-Dibromobenzene 1 0.000 ND
129 3,3-Dimethylpentane 1 0.000 ND
130 Benzyl chloride 126 0.000 ND
126 t-Amyl alcohol 1 0.000 ND
135 1,2-dichloro-4-(trifluoromethyl) 1 0.000 ND
137 1-Chloro-1-fluoroethane TIC 1 0.000 ND
134 1,3-Dibromobenzene 1 0.000 ND
139 2,2-Dimethylpentane 1 0.000 ND
141 Ethylene oxide TIC 1 0.000 ND
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3:53:55 PM
Page 694 of 777
Report Date: 11-Nov-2024 08:55:27 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004270.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
146 2,3-Dimethylpentane 1 0.000 ND
128 2,4-Dimethylpentane 1 0.000 ND
131 1-Chlorohexane TIC 1 0.000 ND
147 3-Methylhexane 1 0.000 ND
122 Isooctane 57 0.000 ND
143 3-Ethylpentane 1 0.000 ND
145 1-Bromo-2-chloroethane 1 0.000 ND
136 Butadiene 54 0.000 ND
132 2,2,3-Trimethylbutane 1 0.000 ND
142 4-Bromofluorobenzene 95 0.000 ND
149 Dimethyl disulfide 1 0.000 ND
125 Benzene, 1-bromo-4-ethyl- 1 0.000 ND
124 cis-1,4-Dichloro-2-butene TIC 1 0.000 ND
144 n-Butyl acetate 43 0.000 ND
S 154 1,3-Dichloropropene, Total 1 0.000 ND 7
S 153 TAH 1 0 0 7
S 156 Total BTEX 1 0.000 ND 7
S 151 1,2-Dichloroethene, Total 1 0.000 ND 7
S 152 Trihalomethanes, Total 1 0.000 ND 7
S 155 Xylenes, Total 106 0.000 ND 7
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
7 - Failed Limit of Detection
Review Flags
M - Manually Integrated
U - Marked Undetected
Reagents:
mv-IS_SS_00089 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 695 of 777
Report Date: 11-Nov-2024 08:55:27 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004270.D
Injection Date:11-Nov-2024 06:40:47 Instrument ID:VMS_MS14 Operator ID:MED
Lims ID:MB Worklist Smp#:9
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0
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0000004270[MS Quad Chro]:Total

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11/15/2024
3:53:55 PM
Page 696 of 777
Report Date: 11-Nov-2024 08:55:27 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004270.D
Lims ID:MB
Client ID:
Sample Type:MB
Inject. Date:11-Nov-2024 06:40:47 ALS Bottle#:0 Worklist Smp#:9
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:mb
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:11-Nov-2024 08:54:38 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1688
First Level Reviewer: BX8N Date:11-Nov-2024 08:54:38
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 47.9 95.83
$5 1,2-Dichloroethane-d4 (Surr)50.0 46.5 92.94
$6 Toluene-d8 (Surr)50.0 53.2 106.36
$7 4-Bromofluorobenzene (Surr)50.0 45.6 91.17
11/15/2024
3:53:55 PM
Page 697 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:MB 280-674813/9
Matrix:X4_00009401.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/13/2024 09:05
ID:RXI-624SilMS
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674813 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_X4
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.14100-41-4 Ethylbenzene ND
1.0 0.13100-42-5 Styrene ND
1.0 0.1610061-01-5 cis-1,3-Dichloropropene ND
1.0 0.1410061-02-6 trans-1,3-Dichloropropene ND
1.0 0.18103-65-1 N-Propylbenzene ND
1.0 0.23104-51-8 n-Butylbenzene ND
1.0 0.21106-43-4 4-Chlorotoluene ND
1.0 0.39106-46-7 1,4-Dichlorobenzene ND
1.0 0.18106-93-4 Ethylene Dibromide ND
2.0 0.46107-05-1 3-Chloro-1-propene ND
1.0 0.28107-06-2 1,2-Dichloroethane ND
3.0 0.36108-05-4 Vinyl acetate ND
5.0 0.98108-10-1 4-Methyl-2-pentanone (MIBK)ND
1.0 0.12108-67-8 1,3,5-Trimethylbenzene ND
1.0 0.19108-86-1 Bromobenzene ND
1.0 0.31108-87-2 Methylcyclohexane ND
1.0 0.32108-88-3 Toluene ND
1.0 0.092108-90-7 Chlorobenzene ND
7.0 0.84109-99-9 Tetrahydrofuran ND
2.0 0.16110-54-3 Hexane ND
1.0 0.44110-82-7 Cyclohexane ND
1.0 0.58120-82-1 1,2,4-Trichlorobenzene ND
1.0 0.28124-48-1 Chlorodibromomethane ND
1.0 0.40127-18-4 Tetrachloroethene ND
1.0 0.20135-98-8 sec-Butylbenzene ND
1.0 0.17142-28-9 1,3-Dichloropropane ND
1.0 0.32156-59-2 cis-1,2-Dichloroethene ND
1.0 0.37156-60-5 trans-1,2-Dichloroethene ND
5.0 0.251634-04-4 Methyl tert-butyl ether ND
2.0 0.36179601-23-1 m-Xylene & p-Xylene ND
1.0 0.33541-73-1 1,3-Dichlorobenzene ND
1.0 0.2356-23-5 Carbon tetrachloride ND
FORM I 8260D
11/15/2024
3:53:55 PM
Page 698 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:MB 280-674813/9
Matrix:X4_00009401.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/13/2024 09:05
ID:RXI-624SilMS
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674813 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_X4
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.19563-58-6 1,1-Dichloropropene ND
5.0 0.81591-78-6 2-Hexanone ND
1.0 0.17594-20-7 2,2-Dichloropropane ND
2.0 0.3560-29-7 Ethyl ether ND
1.0 0.16630-20-6 1,1,1,2-Tetrachloroethane ND
15 6.667-64-1 Acetone ND
1.0 0.3667-66-3 Chloroform ND
1.0 0.1471-43-2 Benzene ND
1.0 0.3971-55-6 1,1,1-Trichloroethane ND
5.0 2.474-83-9 Bromomethane ND
2.0 0.2374-87-3 Chloromethane ND
5.0 2.674-88-4 Iodomethane ND
1.0 0.3474-95-3 Dibromomethane ND
1.0 0.4074-97-5 Chlorobromomethane ND
2.0 0.6475-00-3 Chloroethane ND
1.0 0.2375-01-4 Vinyl chloride ND
2.0 0.9475-09-2 Methylene Chloride ND
2.0 0.2675-15-0 Carbon disulfide ND
2.0 0.2575-25-2 Bromoform ND
1.0 0.1975-27-4 Dichlorobromomethane ND
1.0 0.2275-34-3 1,1-Dichloroethane ND
1.0 0.2375-35-4 1,1-Dichloroethene ND
2.0 0.2075-69-4 Trichlorofluoromethane ND
2.0 0.3075-71-8 Dichlorodifluoromethane ND
3.0 0.7376-13-1 1,1,2-Trichloro-1,2,2-trifluoroethan
e
ND
1.0 0.2478-87-5 1,2-Dichloropropane ND
10 4.678-93-3 2-Butanone (MEK)ND
1.0 0.2779-00-5 1,1,2-Trichloroethane ND
1.0 0.3079-01-6 Trichloroethene ND
5.0 1.679-20-9 Methyl acetate ND
1.0 0.2179-34-5 1,1,2,2-Tetrachloroethane ND
4.0 1.287-61-6 1,2,3-Trichlorobenzene ND
FORM I 8260D
11/15/2024
3:53:55 PM
Page 699 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:MB 280-674813/9
Matrix:X4_00009401.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/13/2024 09:05
ID:RXI-624SilMS
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674813 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_X4
CAS NO.COMPOUND NAME RESULT Q MDLRL
2.0 0.5387-68-3 Hexachlorobutadiene ND
3.0 0.9991-20-3 Naphthalene ND
1.0 0.1195-47-6 o-Xylene ND
1.0 0.3495-49-8 2-Chlorotoluene ND
1.0 0.1495-50-1 1,2-Dichlorobenzene ND
1.0 0.1595-63-6 1,2,4-Trimethylbenzene ND
5.0 0.4296-12-8 1,2-Dibromo-3-Chloropropane ND
2.5 0.2896-18-4 1,2,3-Trichloropropane ND
3.0 0.1997-63-2 Ethyl methacrylate ND
1.0 0.1898-06-6 tert-Butylbenzene ND
1.0 0.1698-82-8 Isopropylbenzene ND
1.0 0.1999-87-6 4-Isopropyltoluene ND
1.0 0.111330-20-7 Xylenes, Total ND
1.0 0.32540-59-0 1,2-Dichloroethene, Total ND
1.0 0.14542-75-6 1,3-Dichloropropene, Total ND
1.0 0.19STL00209Trihalomethanes, Total ND
1.0 0.14STL00431Total BTEX ND
%RECCAS NO.LIMITSQSURROGATE
107 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr)
101 77-1201868-53-7 Dibromofluoromethane (Surr)
100 80-1252037-26-5 Toluene-d8 (Surr)
98 78-120460-00-4 4-Bromofluorobenzene (Surr)
FORM I 8260D
11/15/2024
3:53:55 PM
Page 700 of 777
Report Date: 13-Nov-2024 10:03:40 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009401.D
Lims ID:MB
Client ID:
Sample Type:MB
Inject. Date:13-Nov-2024 09:05:30 ALS Bottle#:7 Worklist Smp#:9
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:mb
Operator ID:wickhamt Instrument ID:VMS_X4
Method:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:13-Nov-2024 10:03:25 Calib Date:29-Oct-2024 20:00:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1654
First Level Reviewer: AF7X Date:13-Nov-2024 10:02:46
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.207 5.207 0.000 97 1576195 50.0 50.0
* 2 Chlorobenzene-d5 119 7.740 7.736 0.004 92 341886 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.961 9.961 0.000 97 554133 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.697 4.697 0.000 93 322337 50.0 50.5
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.966 4.962 0.004 0 513348 50.0 53.6
$ 6 Toluene-d8 (Surr) 98 6.463 6.463 0.000 96 1606508 50.0 50.0
$ 7 4-Bromofluorobenzene (Surr) 95 8.832 8.832 0.000 91 529529 50.0 49.0
$ 8 BFB 95 8.832 8.832 0.000 84 529529 NR
9 Dichlorodifluoromethane 85 1.749 ND
10 Chloromethane 50 1.934 ND
11 Vinyl chloride 62 2.035 ND
12 Bromomethane 94 2.312 ND 7
13 Chloroethane 64 2.412 ND
15 Propene oxide 58 2.504 ND
14 Dichlorofluoromethane 67 2.593 ND
16 Trichlorofluoromethane 101 2.629 ND
17 Ethanol 45 2.757 ND
18 Ethyl ether 59 2.846 ND
19 Acrolein 56 2.958 ND
21 1,1-Dichloroethene 96 3.042 ND
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.042 ND
22 Acetone 43 3.062 ND 7
23 Isopropyl alcohol 45 3.151 ND 7
24 Iodomethane 142 3.167 ND
25 Carbon disulfide 76 3.227 ND 7
26 Acetonitrile 41 3.275 ND 7
27 Methyl acetate 43 3.291 ND
28 3-Chloro-1-propene 41 3.315 ND U
29 Methylene Chloride 84 3.412 ND 7
30 2-Methyl-2-propanol 59 3.460 ND
31 Acrylonitrile 53 3.576 ND 7
32 Methyl tert-butyl ether 73 3.596 ND
11/15/2024
3:53:55 PM
Page 701 of 777
Report Date: 13-Nov-2024 10:03:40 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009401.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
33 trans-1,2-Dichloroethene 96 3.613 ND
34 Hexane 57 3.805 ND
35 Vinyl acetate 43 3.910 ND
37 Isopropyl ether 87 3.934 ND
36 1,1-Dichloroethane 63 3.934 ND
38 2-Chloro-1,3-butadiene 53 3.986 ND
39 Tert-butyl ethyl ether 59 4.191 ND
40 2-Butanone (MEK) 43 4.319 ND
41 Ethyl acetate 43 4.331 ND 7
42 cis-1,2-Dichloroethene 96 4.347 ND
43 2,2-Dichloropropane 77 4.355 ND
44 Propionitrile 54 4.371 ND
45 sec-Butyl Alcohol 45 4.432 ND
46 Methacrylonitrile 41 4.484 ND
47 Chlorobromomethane 128 4.524 ND
48 Tetrahydrofuran 42 4.536 ND
49 Chloroform 83 4.580 ND
50 1,1,1-Trichloroethane 97 4.725 ND
51 Cyclohexane 56 4.789 ND
52 1,1-Dichloropropene 75 4.837 ND
53 Carbon tetrachloride 117 4.845 ND
54 Isobutyl alcohol 41 4.853 ND U
55 Benzene 78 4.994 ND
56 1,2-Dichloroethane 62 5.022 ND
57 Tert-amyl methyl ether 73 5.058 ND
58 n-Heptane 43 5.174 ND
59 n-Butanol 56 5.347 ND
60 Trichloroethene 95 5.484 ND
61 2-Pentanone 43 5.584 ND
62 Methylcyclohexane 55 5.676 ND
64 Methyl methacrylate 100 5.688 ND
63 1,2-Dichloropropane 63 5.688 ND
65 1,4-Dioxane 88 5.729 ND
66 Dibromomethane 93 5.761 ND
67 Dichlorobromomethane 83 5.881 ND
68 2-Nitropropane 41 6.050 ND
69 2-Chloroethyl vinyl ether 63 6.082 ND
70 cis-1,3-Dichloropropene 75 6.231 ND
71 4-Methyl-2-pentanone (MIBK) 43 6.331 ND
72 Toluene 91 6.520 ND
73 trans-1,3-Dichloropropene 75 6.692 ND
74 Ethyl methacrylate 69 6.712 ND
75 1,1,2-Trichloroethane 97 6.869 ND
76 Tetrachloroethene 164 6.961 ND
77 1,3-Dichloropropane 76 7.018 ND
78 2-Hexanone 43 7.034 ND
79 Chlorodibromomethane 129 7.210 ND
80 Ethylene Dibromide 107 7.331 ND
81 1-Chlorohexane 91 7.716 ND 7
82 Chlorobenzene 112 7.764 ND
83 1,1,1,2-Tetrachloroethane 131 7.833 ND
84 Ethylbenzene 106 7.837 ND
11/15/2024
3:53:55 PM
Page 702 of 777
Report Date: 13-Nov-2024 10:03:40 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009401.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
85 m-Xylene & p-Xylene 106 7.953 ND U
86 o-Xylene 106 8.318 ND
87 Styrene 104 8.331 ND
88 Bromoform 173 8.515 ND
89 Isopropylbenzene 105 8.656 ND
90 cis-1,4-Dichloro-2-butene 53 8.708 ND
91 Cyclohexanone 55 8.760 ND U
92 1,1,2,2-Tetrachloroethane 83 8.941 ND
94 trans-1,4-Dichloro-2-butene 53 8.981 ND
93 Bromobenzene 156 8.981 ND
95 1,2,3-Trichloropropane 110 9.009 ND
96 N-Propylbenzene 120 9.057 ND
97 2-Chlorotoluene 126 9.158 ND
98 1,3,5-Trimethylbenzene 105 9.226 ND
99 4-Chlorotoluene 126 9.274 ND
101 Pentachloroethane 167 9.411 ND
100 tert-Butylbenzene 119 9.539 ND
102 1,2,4-Trimethylbenzene 105 9.599 ND
103 sec-Butylbenzene 134 9.756 ND
104 1,3-Dichlorobenzene 146 9.888 ND 7
105 4-Isopropyltoluene 119 9.905 ND
106 1,4-Dichlorobenzene 146 9.985 ND 7
107 1,2,3-Trimethylbenzene 105 10.005 ND
108 n-Butylbenzene 91 10.310 ND
109 1,2-Dichlorobenzene 146 10.346 ND
110 1,2-Dibromo-3-Chloropropane 157 11.125 ND
111 1,3,5-Trichlorobenzene 180 11.310 ND
112 1,2,4-Trichlorobenzene 180 11.948 ND
113 Hexachlorobutadiene 225 12.085 ND
114 Naphthalene 128 12.221 ND
115 1,2,3-Trichlorobenzene 180 12.438 ND
116 Ethylene oxide TIC 1 0.000 ND
117 t-Amyl alcohol 1 0.000 ND
118 Ethyl acrylate 55 0.000 ND
119 1-Chloro-1-fluoroethane TIC 1 0.000 ND
120 Tetrahydrothiophene TIC 1 0.000 ND
121 Propene oxide TIC 58 5.334 ND
S 122 1,2-Dichloroethene, Total (URS) 96 2.000 ND 7
S 129 1,2-Dichloroethene, Total 1 0.000 ND 7
S 123 Xylenes, Total (URS) 1 0.000 ND 7
S 128 TAH 1 0 0
S 127 Trihalomethanes, Total 1 0.000 ND 7
S 125 Xylenes, Total 106 0.000 ND 7
S 126 Total BTEX 1 0.000 ND 7
S 124 1,3-Dichloropropene, Total 1 0.000 ND 7
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
7 - Failed Limit of Detection
11/15/2024
3:53:55 PM
Page 703 of 777
Report Date: 13-Nov-2024 10:03:40 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Review Flags
U - Marked Undetected
Reagents:
mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 704 of 777
Report Date: 13-Nov-2024 10:03:40 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009401.D
Injection Date:13-Nov-2024 09:05:30 Instrument ID:VMS_X4 Operator ID:wickhamt
Lims ID:MB Worklist Smp#:9
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:7
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0
Min
0
1
2
3
4
5
6
7
8
9
10
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13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
Y ( X
1
0
0
0
0
0
)
X4_00009401[MS SCAN Chro]:Total
$ D
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8.832
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11/15/2024
3:53:55 PM
Page 705 of 777
Report Date: 13-Nov-2024 10:03:40 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009401.D
Lims ID:MB
Client ID:
Sample Type:MB
Inject. Date:13-Nov-2024 09:05:30 ALS Bottle#:7 Worklist Smp#:9
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:mb
Operator ID:wickhamt Instrument ID:VMS_X4
Method:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:13-Nov-2024 10:03:25 Calib Date:29-Oct-2024 20:00:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1654
First Level Reviewer: AF7X Date:13-Nov-2024 10:02:46
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 50.5 100.93
$5 1,2-Dichloroethane-d4 (Surr)50.0 53.6 107.20
$6 Toluene-d8 (Surr)50.0 50.0 100.02
$7 4-Bromofluorobenzene (Surr)50.0 49.0 98.00
11/15/2024
3:53:55 PM
Page 706 of 777
Report Date: 13-Nov-2024 10:03:40 Chrom Revision: 2.3 12-Nov-2024 16:55:22
User Disabled Compound Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009401.D
Injection Date:13-Nov-2024 09:05:30 Instrument ID:VMS_X4
Lims ID:MB
Client ID:
Operator ID:wickhamt ALS Bottle#:7 Worklist Smp#:9
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
28 3-Chloro-1-propene, CAS: 107-05-1
Processing Results
30 70 110 150 190 230 270 310 350m/z
0
3
6
9
12
15
18
Y ( X
1
0
0
0
)
Raw Spec:Scan 545(3.28)
30 70 110 150 190 230 270 310 350
m/z
0
13
26
39
52
65
78
91
Y ( X
1
0
)
Amdis Enhanced Spec: Scan 545(3.28), Qvalue=76
30 70 110 150 190 230 270 310 350
0
13
26
39
52
65
78
91
( X
1
0
0
)
Ref Spec: 28 3-Chloro-1-propene (NIST98.L)
76
78
3.1 3.4Min
RT
0
4
8
12
16
20
Y ( X
1
0
0
0
)
m/z 41.0

3
.
2
7
5
3.1 3.4
Min
RT
0
8
16
24
32
40
48
Y ( X
1
0
0
)
m/z 39.0

3
.
2
7
5
3.1 3.4
Min
RT
0
4
8
12
16
20
Y ( X
1
0
0
)
m/z 76.0
RT Mass Response Amount
3.28 41.00 30484 1.489612
3.28 39.00 8452
3.32 76.00 0
Reviewer: AF7X, 13-Nov-2024 10:02:17 -07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
11/15/2024
3:53:55 PM
Page 707 of 777
Report Date: 13-Nov-2024 10:03:40 Chrom Revision: 2.3 12-Nov-2024 16:55:22
User Disabled Compound Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009401.D
Injection Date:13-Nov-2024 09:05:30 Instrument ID:VMS_X4
Lims ID:MB
Client ID:
Operator ID:wickhamt ALS Bottle#:7 Worklist Smp#:9
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column:Rxi-624Sil MS ( 0.25 mm)Detector MS SCAN
85 m-Xylene & p-Xylene, CAS: 179601-23-1
Processing Results
30 70 110 150 190 230 270 310 350m/z
0
2
4
6
8
10
12
Y ( X
1
0
0
)
Raw Spec:Scan 1710(7.95)
106
91
44
12477 177
30 70 110 150 190 230 270 310 350
m/z
0
2
4
6
8
10
12
Y ( X
1
0
0
)
Enhanced Spec:Scan 1710(7.95), Qvalue=0
106
91
44
12477 177
7.8 8.1Min
RT
0
2
4
6
8
10
Y ( X
1
0
0
)
m/z 106.0

7
.
9
5
3
7.8 8.1
Min
RT
0
2
4
6
8
10
Y ( X
1
0
0
)
m/z 91.0

7
.
9
5
3
7.8 8.1
Min
RT
0
8
16
24
32
40
48
Y ( X
1
0
)
m/z 77.0

7
.
9
5
7
RT Mass Response Amount
7.95 106.00 605 0.381289
7.95 91.00 564
7.96 77.00 114
Reviewer: AF7X, 13-Nov-2024 10:02:22 -07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
11/15/2024
3:53:55 PM
Page 708 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LCS 280-674451/4
Matrix:VMS14_0000004265A.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 05:00
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.14100-41-4 Ethylbenzene 48.3
1.0 0.13100-42-5 Styrene 48.6
1.0 0.1610061-01-5 cis-1,3-Dichloropropene 53.7
1.0 0.1410061-02-6 trans-1,3-Dichloropropene 44.2
1.0 0.18103-65-1 N-Propylbenzene 48.8
1.0 0.23104-51-8 n-Butylbenzene 43.5
1.0 0.21106-43-4 4-Chlorotoluene 49.0
1.0 0.39106-46-7 1,4-Dichlorobenzene 50.2
1.0 0.18106-93-4 Ethylene Dibromide 51.5
2.0 0.46107-05-1 3-Chloro-1-propene 48.3
1.0 0.28107-06-2 1,2-Dichloroethane 46.2
3.0 0.36108-05-4 Vinyl acetate 108
5.0 0.98108-10-1 4-Methyl-2-pentanone (MIBK)191
1.0 0.12108-67-8 1,3,5-Trimethylbenzene 47.2
1.0 0.19108-86-1 Bromobenzene 50.5
1.0 0.31108-87-2 Methylcyclohexane 40.2
1.0 0.32108-88-3 Toluene 49.8
1.0 0.092108-90-7 Chlorobenzene 49.2
7.0 0.84109-99-9 Tetrahydrofuran 90.9
2.0 0.16110-54-3 Hexane 40.8
1.0 0.44110-82-7 Cyclohexane 44.2
1.0 0.58120-82-1 1,2,4-Trichlorobenzene 49.0
1.0 0.28124-48-1 Chlorodibromomethane 47.9
1.0 0.40127-18-4 Tetrachloroethene 53.1
1.0 0.20135-98-8 sec-Butylbenzene 46.7
1.0 0.17142-28-9 1,3-Dichloropropane 49.5
1.0 0.32156-59-2 cis-1,2-Dichloroethene 49.5
1.0 0.37156-60-5 trans-1,2-Dichloroethene 49.1
5.0 0.251634-04-4 Methyl tert-butyl ether 50.0
2.0 0.36179601-23-1 m-Xylene & p-Xylene 48.8
1.0 0.33541-73-1 1,3-Dichlorobenzene 47.8
1.0 0.2356-23-5 Carbon tetrachloride 48.5
FORM I 8260D
11/15/2024
3:53:55 PM
Page 709 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LCS 280-674451/4
Matrix:VMS14_0000004265A.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 05:00
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.19563-58-6 1,1-Dichloropropene 47.6
5.0 0.81591-78-6 2-Hexanone 190
1.0 0.17594-20-7 2,2-Dichloropropane 51.4
2.0 0.3560-29-7 Ethyl ether 52.5
1.0 0.16630-20-6 1,1,1,2-Tetrachloroethane 51.4
15 6.667-64-1 Acetone 179
1.0 0.3667-66-3 Chloroform 47.3
1.0 0.1471-43-2 Benzene 48.6
1.0 0.3971-55-6 1,1,1-Trichloroethane 49.2
5.0 2.474-83-9 Bromomethane 48.9
2.0 0.2374-87-3 Chloromethane 47.9
5.0 2.674-88-4 Iodomethane 53.3
1.0 0.3474-95-3 Dibromomethane 49.6
1.0 0.4074-97-5 Chlorobromomethane 52.0
2.0 0.6475-00-3 Chloroethane 47.6
1.0 0.2375-01-4 Vinyl chloride 50.9
2.0 0.9475-09-2 Methylene Chloride 48.3
2.0 0.2675-15-0 Carbon disulfide 50.3
2.0 0.2575-25-2 Bromoform 49.5
1.0 0.1975-27-4 Dichlorobromomethane 44.9
1.0 0.2275-34-3 1,1-Dichloroethane 49.1
1.0 0.2375-35-4 1,1-Dichloroethene 51.7
2.0 0.2075-69-4 Trichlorofluoromethane 49.1
2.0 0.3075-71-8 Dichlorodifluoromethane 34.7
3.0 0.7376-13-1 1,1,2-Trichloro-1,2,2-trifluoroethan
e
47.0
1.0 0.2478-87-5 1,2-Dichloropropane 47.9
10 4.678-93-3 2-Butanone (MEK)186
1.0 0.2779-00-5 1,1,2-Trichloroethane 49.9
1.0 0.3079-01-6 Trichloroethene 48.3
5.0 1.679-20-9 Methyl acetate 93.5
1.0 0.2179-34-5 1,1,2,2-Tetrachloroethane 54.2
4.0 1.287-61-6 1,2,3-Trichlorobenzene 49.7
FORM I 8260D
11/15/2024
3:53:55 PM
Page 710 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LCS 280-674451/4
Matrix:VMS14_0000004265A.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 05:00
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
2.0 0.5387-68-3 Hexachlorobutadiene 48.0
3.0 0.9991-20-3 Naphthalene 45.8
1.0 0.1195-47-6 o-Xylene 46.9
1.0 0.3495-49-8 2-Chlorotoluene 48.8
1.0 0.1495-50-1 1,2-Dichlorobenzene 48.9
1.0 0.1595-63-6 1,2,4-Trimethylbenzene 46.1
5.0 0.4296-12-8 1,2-Dibromo-3-Chloropropane 51.6
2.5 0.2896-18-4 1,2,3-Trichloropropane 52.6
3.0 0.1997-63-2 Ethyl methacrylate 50.8
1.0 0.1898-06-6 tert-Butylbenzene 48.3
1.0 0.1698-82-8 Isopropylbenzene 49.6
1.0 0.1999-87-6 4-Isopropyltoluene 46.1
1.0 0.111330-20-7 Xylenes, Total 95.7
1.0 0.32540-59-0 1,2-Dichloroethene, Total 98.6
1.0 0.14542-75-6 1,3-Dichloropropene, Total 97.9
1.0 0.19STL00209Trihalomethanes, Total 190
1.0 0.14STL00431Total BTEX 242
%RECCAS NO.LIMITSQSURROGATE
95 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr)
103 77-1201868-53-7 Dibromofluoromethane (Surr)
103 80-1252037-26-5 Toluene-d8 (Surr)
95 78-120460-00-4 4-Bromofluorobenzene (Surr)
FORM I 8260D
11/15/2024
3:53:55 PM
Page 711 of 777
Report Date: 11-Nov-2024 05:55:03 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004265A.D
Lims ID:LCS
Client ID:
Sample Type:LCS
Inject. Date:11-Nov-2024 05:00:59 ALS Bottle#:0 Worklist Smp#:4
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ccv m
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:11-Nov-2024 05:55:01 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1688
First Level Reviewer: BX8N Date:11-Nov-2024 05:54:49
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.357 5.357 0.000 99 1143243 50.0 50.0
* 2 Chlorobenzene-d5 119 7.929 7.926 0.003 85 303107 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.173 0.000 95 502015 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.839 4.839 0.000 94 284726 50.0 51.4
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 96 327440 50.0 47.3
$ 6 Toluene-d8 (Surr) 98 6.633 6.637 -0.004 92 1233861 50.0 51.6
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 89 457887 50.0 47.7
10 Dichlorodifluoromethane 85 1.791 1.791 0.000 99 226622 50.0 34.7
12 Chloromethane 50 1.974 1.974 0.000 99 406841 50.0 47.9
13 Vinyl chloride 62 2.090 2.090 0.000 98 329874 50.0 50.9
15 Bromomethane 94 2.389 2.389 0.000 90 206962 50.0 48.9
16 Chloroethane 64 2.489 2.489 0.000 99 192278 50.0 47.6
17 Dichlorofluoromethane 67 2.675 2.675 0.000 97 505452 50.0 49.7
18 Trichlorofluoromethane 101 2.711 2.711 0.000 97 341079 50.0 49.1
21 Ethyl ether 59 2.936 2.936 0.000 90 230475 50.0 52.5
22 Acrolein 56 3.055 3.055 0.000 100 1173135 493.8 526.8
25 1,1-Dichloroethene 96 3.138 3.138 0.000 97 214956 50.0 51.7
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.141 3.141 0.000 95 132584 50.0 47.0
26 Acetone 43 3.164 3.164 0.000 100 1326587 200.0 178.9
29 Iodomethane 142 3.267 3.267 0.000 98 262842 50.0 53.3
30 Carbon disulfide 76 3.334 3.334 0.000 98 622521 50.0 50.3
32 Methyl acetate 43 3.399 3.399 0.000 97 1135322 100.0 93.5
33 3-Chloro-1-propene 41 3.418 3.418 0.000 94 343711 50.0 48.3
34 Methylene Chloride 84 3.518 3.518 0.000 90 281947 50.0 48.3
35 2-Methyl-2-propanol 59 3.579 3.579 0.000 100 2199242 500.0 448.0
36 Acrylonitrile 53 3.688 3.688 0.000 99 3162837 500.0 489.3
37 Methyl tert-butyl ether 73 3.714 3.714 0.000 93 812549 50.0 50.0
38 trans-1,2-Dichloroethene 96 3.727 3.727 0.000 99 216456 50.0 49.1
39 Hexane 57 3.929 3.929 0.000 90 256933 50.0 40.8
40 Vinyl acetate 43 4.032 4.032 0.000 97 1413752 100.0 107.9
42 1,1-Dichloroethane 63 4.055 4.055 0.000 95 386012 50.0 49.1
45 2-Butanone (MEK) 43 4.456 4.456 0.000 99 2159163 200.0 185.8
11/15/2024
3:53:55 PM
Page 712 of 777
Report Date: 11-Nov-2024 05:55:03 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004265A.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
47 cis-1,2-Dichloroethene 96 4.482 4.482 0.000 79 254002 50.0 49.5
48 2,2-Dichloropropane 77 4.495 4.495 0.000 84 315290 50.0 51.4
50 sec-Butyl Alcohol 45 4.575 4.575 0.000 99 3762685 1200.0 1096.9
52 Chlorobromomethane 128 4.662 4.662 0.000 95 139664 50.0 52.0
53 Tetrahydrofuran 42 4.678 4.678 0.000 88 648828 100.0 90.9
54 Chloroform 83 4.720 4.720 0.000 92 374624 50.0 47.3
55 1,1,1-Trichloroethane 97 4.871 4.871 0.000 98 301631 50.0 49.2
56 Cyclohexane 56 4.936 4.936 0.000 87 330845 50.0 44.2
57 1,1-Dichloropropene 75 4.987 4.987 0.000 99 309937 50.0 47.6
59 Carbon tetrachloride 117 4.990 4.990 0.000 94 224539 50.0 48.5
58 Isobutyl alcohol 41 5.003 5.003 0.000 95 1458393 1250.0 1135.3
60 Benzene 78 5.145 5.145 0.000 94 918369 50.0 48.6
61 1,2-Dichloroethane 62 5.167 5.167 0.000 97 312121 50.0 46.2
63 n-Heptane 43 5.328 5.328 0.000 92 258713 50.0 38.6
65 Trichloroethene 95 5.640 5.640 0.000 98 245960 50.0 48.3
66 2-Pentanone 43 5.743 5.743 0.000 99 2318640 160.0 142.1
67 Methylcyclohexane 55 5.842 5.842 0.000 89 250907 50.0 40.2
69 1,2-Dichloropropane 63 5.849 5.849 0.000 97 240428 50.0 47.9
70 1,4-Dioxane 88 5.903 5.903 0.000 89 236823 1000.0 905.2
71 Dibromomethane 93 5.923 5.923 0.000 96 166659 50.0 49.6
72 Dichlorobromomethane 83 6.045 6.045 0.000 99 267181 50.0 44.9
74 2-Chloroethyl vinyl ether 63 6.247 6.247 0.000 91 34129 50.0 8.66
75 cis-1,3-Dichloropropene 75 6.402 6.402 0.000 97 398081 50.0 53.7
76 4-Methyl-2-pentanone (MIBK) 43 6.501 6.501 0.000 94 2619252 200.0 190.9
77 Toluene 91 6.694 6.694 0.000 98 1076343 50.0 49.8
78 trans-1,3-Dichloropropene 75 6.868 6.868 0.000 96 370589 50.0 44.2
79 Ethyl methacrylate 69 6.884 6.884 0.000 87 492544 50.0 50.8
80 1,1,2-Trichloroethane 97 7.045 7.045 0.000 90 261130 50.0 49.9
82 Tetrachloroethene 164 7.148 7.148 0.000 97 192338 50.0 53.1
83 1,3-Dichloropropane 76 7.196 7.196 0.000 88 452915 50.0 49.5
84 2-Hexanone 43 7.215 7.215 0.000 95 2310993 200.0 189.6
85 Chlorodibromomethane 129 7.392 7.392 0.000 90 223920 50.0 47.9
86 Ethylene Dibromide 107 7.514 7.514 0.000 99 289459 50.0 51.5
87 1-Chlorohexane 91 7.907 7.907 0.000 95 259283 40.0 38.2
88 Chlorobenzene 112 7.955 7.955 0.000 95 708463 50.0 49.2
89 1,1,1,2-Tetrachloroethane 131 8.022 8.022 0.000 95 223563 50.0 51.4
90 Ethylbenzene 106 8.029 8.029 0.000 98 367259 50.0 48.3
91 m-Xylene & p-Xylene 106 8.148 8.148 0.000 100 456951 50.0 48.8
92 o-Xylene 106 8.511 8.511 0.000 96 451264 50.0 46.9
93 Styrene 104 8.527 8.527 0.000 94 784935 50.0 48.6
94 Bromoform 173 8.710 8.710 0.000 97 182714 50.0 49.5
95 Isopropylbenzene 105 8.858 8.858 0.000 95 1052579 50.0 49.6
97 Cyclohexanone 55 8.958 8.958 0.000 90 2236546 1500.0 1825.9
98 1,1,2,2-Tetrachloroethane 83 9.141 9.141 0.000 94 447247 50.0 54.2
99 trans-1,4-Dichloro-2-butene 53 9.177 9.177 0.000 88 152239 50.0 46.4
100 Bromobenzene 156 9.186 9.186 0.000 95 299314 50.0 50.5
101 1,2,3-Trichloropropane 110 9.209 9.209 0.000 84 170897 50.0 52.6
102 N-Propylbenzene 120 9.257 9.257 0.000 99 308930 50.0 48.8
103 2-Chlorotoluene 126 9.360 9.360 0.000 96 269953 50.0 48.8
104 1,3,5-Trimethylbenzene 105 9.431 9.431 0.000 95 940982 50.0 47.2
105 4-Chlorotoluene 126 9.479 9.479 0.000 97 289575 50.0 49.0
107 tert-Butylbenzene 119 9.746 9.746 0.000 93 835011 50.0 48.3
11/15/2024
3:53:55 PM
Page 713 of 777
Report Date: 11-Nov-2024 05:55:03 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004265A.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
108 1,2,4-Trimethylbenzene 105 9.804 9.804 0.000 97 980721 50.0 46.1
109 sec-Butylbenzene 134 9.968 9.968 0.000 94 243474 50.0 46.7
110 1,3-Dichlorobenzene 146 10.099 10.099 0.000 98 568851 50.0 47.8
111 4-Isopropyltoluene 119 10.112 10.112 0.000 97 1043592 50.0 46.1
112 1,4-Dichlorobenzene 146 10.196 10.196 0.000 95 570001 50.0 50.2
114 n-Butylbenzene 91 10.524 10.524 0.000 98 939155 50.0 43.5
115 1,2-Dichlorobenzene 146 10.559 10.559 0.000 98 553100 50.0 48.9
116 1,2-Dibromo-3-Chloropropane 157 11.344 11.344 0.000 88 182522 50.0 51.6
118 1,2,4-Trichlorobenzene 180 12.180 12.180 0.000 94 397265 50.0 49.0
119 Hexachlorobutadiene 225 12.321 12.321 0.000 97 165736 50.0 48.0
120 Naphthalene 128 12.453 12.453 0.000 97 1483000 50.0 45.8
121 1,2,3-Trichlorobenzene 180 12.678 12.678 0.000 96 392654 50.0 49.7
136 Butadiene 54 0.000 ND ND
S 154 1,3-Dichloropropene, Total 1 0 100.0 97.9
S 151 1,2-Dichloroethene, Total 1 0 100.0 98.7
S 152 Trihalomethanes, Total 1 0 200.0 189.5
S 155 Xylenes, Total 106 0 100.0 95.7
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
MV-MegaMainA_00118 Amount Added: 25.00 Units: uL
MV-Gas A_00202 Amount Added: 10.00 Units: uL
mv-IS_SS_00089 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 714 of 777
Report Date: 11-Nov-2024 05:55:03 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004265A.D
Injection Date:11-Nov-2024 05:00:59 Instrument ID:VMS_MS14 Operator ID:MED
Lims ID:LCS Worklist Smp#:4
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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11/15/2024
3:53:55 PM
Page 715 of 777
Report Date: 11-Nov-2024 05:55:03 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004265A.D
Lims ID:LCS
Client ID:
Sample Type:LCS
Inject. Date:11-Nov-2024 05:00:59 ALS Bottle#:0 Worklist Smp#:4
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ccv m
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:11-Nov-2024 05:55:01 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1688
First Level Reviewer: BX8N Date:11-Nov-2024 05:54:49
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 51.4 102.76
$5 1,2-Dichloroethane-d4 (Surr)50.0 47.3 94.62
$6 Toluene-d8 (Surr)50.0 51.6 103.30
$7 4-Bromofluorobenzene (Surr)50.0 47.7 95.34
11/15/2024
3:53:55 PM
Page 716 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LCS 280-674813/4
Matrix:X4_00009396a.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/13/2024 07:20
ID:RXI-624SilMS
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674813 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_X4
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.14100-41-4 Ethylbenzene 51.4
1.0 0.13100-42-5 Styrene 51.7
1.0 0.1610061-01-5 cis-1,3-Dichloropropene 53.7
1.0 0.1410061-02-6 trans-1,3-Dichloropropene 53.8
1.0 0.18103-65-1 N-Propylbenzene 52.0
1.0 0.23104-51-8 n-Butylbenzene 50.3
1.0 0.21106-43-4 4-Chlorotoluene 50.9
1.0 0.39106-46-7 1,4-Dichlorobenzene 49.6
1.0 0.18106-93-4 Ethylene Dibromide 48.9
2.0 0.46107-05-1 3-Chloro-1-propene 55.3
1.0 0.28107-06-2 1,2-Dichloroethane 52.0
3.0 0.36108-05-4 Vinyl acetate 116
5.0 0.98108-10-1 4-Methyl-2-pentanone (MIBK)225
1.0 0.12108-67-8 1,3,5-Trimethylbenzene 51.2
1.0 0.19108-86-1 Bromobenzene 51.5
1.0 0.31108-87-2 Methylcyclohexane 49.4
1.0 0.32108-88-3 Toluene 52.2
1.0 0.092108-90-7 Chlorobenzene 51.3
7.0 0.84109-99-9 Tetrahydrofuran 102
2.0 0.16110-54-3 Hexane 47.5
1.0 0.44110-82-7 Cyclohexane 50.7
1.0 0.58120-82-1 1,2,4-Trichlorobenzene 44.9
1.0 0.28124-48-1 Chlorodibromomethane 54.1
1.0 0.40127-18-4 Tetrachloroethene 51.4
1.0 0.20135-98-8 sec-Butylbenzene 49.6
1.0 0.17142-28-9 1,3-Dichloropropane 51.7
1.0 0.32156-59-2 cis-1,2-Dichloroethene 51.5
1.0 0.37156-60-5 trans-1,2-Dichloroethene 52.0
5.0 0.251634-04-4 Methyl tert-butyl ether 52.0
2.0 0.36179601-23-1 m-Xylene & p-Xylene 50.3
1.0 0.33541-73-1 1,3-Dichlorobenzene 50.5
1.0 0.2356-23-5 Carbon tetrachloride 53.5
FORM I 8260D
11/15/2024
3:53:55 PM
Page 717 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LCS 280-674813/4
Matrix:X4_00009396a.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/13/2024 07:20
ID:RXI-624SilMS
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674813 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_X4
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.19563-58-6 1,1-Dichloropropene 51.4
5.0 0.81591-78-6 2-Hexanone 210
1.0 0.17594-20-7 2,2-Dichloropropane 50.4
2.0 0.3560-29-7 Ethyl ether 49.7
1.0 0.16630-20-6 1,1,1,2-Tetrachloroethane 54.1
15 6.667-64-1 Acetone 195
1.0 0.3667-66-3 Chloroform 52.4
1.0 0.1471-43-2 Benzene 52.2
1.0 0.3971-55-6 1,1,1-Trichloroethane 52.8
5.0 2.474-83-9 Bromomethane 37.2
2.0 0.2374-87-3 Chloromethane 52.8
5.0 2.674-88-4 Iodomethane 56.0
1.0 0.3474-95-3 Dibromomethane 47.7
1.0 0.4074-97-5 Chlorobromomethane 49.6
2.0 0.6475-00-3 Chloroethane 55.5
1.0 0.2375-01-4 Vinyl chloride 56.3
2.0 0.9475-09-2 Methylene Chloride 50.2
2.0 0.2675-15-0 Carbon disulfide 51.2
2.0 0.2575-25-2 Bromoform 53.1
1.0 0.1975-27-4 Dichlorobromomethane 54.0
1.0 0.2275-34-3 1,1-Dichloroethane 52.1
1.0 0.2375-35-4 1,1-Dichloroethene 50.2
2.0 0.2075-69-4 Trichlorofluoromethane 53.5
2.0 0.3075-71-8 Dichlorodifluoromethane 53.0
3.0 0.7376-13-1 1,1,2-Trichloro-1,2,2-trifluoroethan
e
48.7
1.0 0.2478-87-5 1,2-Dichloropropane 52.6
10 4.678-93-3 2-Butanone (MEK)204
1.0 0.2779-00-5 1,1,2-Trichloroethane 52.6
1.0 0.3079-01-6 Trichloroethene 45.9
5.0 1.679-20-9 Methyl acetate 106
1.0 0.2179-34-5 1,1,2,2-Tetrachloroethane 54.5
4.0 1.287-61-6 1,2,3-Trichlorobenzene 45.5
FORM I 8260D
11/15/2024
3:53:55 PM
Page 718 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LCS 280-674813/4
Matrix:X4_00009396a.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/13/2024 07:20
ID:RXI-624SilMS
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674813 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_X4
CAS NO.COMPOUND NAME RESULT Q MDLRL
2.0 0.5387-68-3 Hexachlorobutadiene 51.5
3.0 0.9991-20-3 Naphthalene 40.7
1.0 0.1195-47-6 o-Xylene 51.6
1.0 0.3495-49-8 2-Chlorotoluene 50.9
1.0 0.1495-50-1 1,2-Dichlorobenzene 47.4
1.0 0.1595-63-6 1,2,4-Trimethylbenzene 50.8
5.0 0.4296-12-8 1,2-Dibromo-3-Chloropropane 47.8
2.5 0.2896-18-4 1,2,3-Trichloropropane 49.5
3.0 0.1997-63-2 Ethyl methacrylate 52.4
1.0 0.1898-06-6 tert-Butylbenzene 50.6
1.0 0.1698-82-8 Isopropylbenzene 51.4
1.0 0.1999-87-6 4-Isopropyltoluene 51.1
1.0 0.111330-20-7 Xylenes, Total 102
1.0 0.32540-59-0 1,2-Dichloroethene, Total 104
1.0 0.14542-75-6 1,3-Dichloropropene, Total 108
1.0 0.19STL00209Trihalomethanes, Total 214
1.0 0.14STL00431Total BTEX 258
%RECCAS NO.LIMITSQSURROGATE
101 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr)
104 77-1201868-53-7 Dibromofluoromethane (Surr)
99 80-1252037-26-5 Toluene-d8 (Surr)
100 78-120460-00-4 4-Bromofluorobenzene (Surr)
FORM I 8260D
11/15/2024
3:53:55 PM
Page 719 of 777
Report Date: 13-Nov-2024 10:03:27 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009396a.D
Lims ID:LCS
Client ID:
Sample Type:LCS
Inject. Date:13-Nov-2024 07:20:30 ALS Bottle#:2 Worklist Smp#:4
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ccv m
Operator ID:wickhamt Instrument ID:VMS_X4
Method:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:13-Nov-2024 10:03:25 Calib Date:29-Oct-2024 20:00:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1654
First Level Reviewer: AF7X Date:13-Nov-2024 08:36:12
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.207 5.207 0.000 98 1545225 50.0 50.0
* 2 Chlorobenzene-d5 119 7.736 7.736 0.000 91 343434 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.961 9.961 0.000 96 544351 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.697 4.697 0.000 92 326712 50.0 52.2
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.962 4.962 0.000 0 475342 50.0 50.6
$ 6 Toluene-d8 (Surr) 98 6.463 6.463 0.000 96 1604897 50.0 49.7
$ 7 4-Bromofluorobenzene (Surr) 95 8.832 8.832 0.000 86 530521 50.0 50.0
9 Dichlorodifluoromethane 85 1.749 1.749 0.000 99 467897 50.0 53.0
10 Chloromethane 50 1.934 1.934 0.000 99 693997 50.0 52.8
11 Vinyl chloride 62 2.035 2.035 0.000 98 561696 50.0 56.3
12 Bromomethane 94 2.312 2.312 0.000 92 122134 50.0 37.2
13 Chloroethane 64 2.412 2.412 0.000 98 362167 50.0 55.5
14 Dichlorofluoromethane 67 2.593 2.593 0.000 97 886587 50.0 57.3
16 Trichlorofluoromethane 101 2.629 2.629 0.000 98 501853 50.0 53.5
18 Ethyl ether 59 2.846 2.846 0.000 95 431605 50.0 49.7
19 Acrolein 56 2.958 2.958 0.000 99 1340552 493.8 512.3
21 1,1-Dichloroethene 96 3.042 3.042 0.000 92 318761 50.0 50.2
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.042 3.042 0.000 97 212870 50.0 48.7
22 Acetone 43 3.062 3.062 0.000 98 1983312 200.0 194.7
24 Iodomethane 142 3.167 3.167 0.000 99 198432 50.0 56.0
25 Carbon disulfide 76 3.227 3.227 0.000 100 1201940 50.0 51.2
27 Methyl acetate 43 3.291 3.291 0.000 100 2062578 100.0 106.0
28 3-Chloro-1-propene 41 3.315 3.315 0.000 90 1110071 50.0 55.3
29 Methylene Chloride 84 3.412 3.412 0.000 96 413778 50.0 50.2
30 2-Methyl-2-propanol 59 3.460 3.460 0.000 98 2685876 500.0 494.5
31 Acrylonitrile 53 3.576 3.576 0.000 99 4707617 500.0 518.4
32 Methyl tert-butyl ether 73 3.596 3.596 0.000 99 1424167 50.0 52.0
33 trans-1,2-Dichloroethene 96 3.613 3.613 0.000 92 375457 50.0 52.0
34 Hexane 57 3.805 3.805 0.000 96 675031 50.0 47.5
35 Vinyl acetate 43 3.910 3.910 0.000 96 3350555 100.0 116.1
36 1,1-Dichloroethane 63 3.934 3.934 0.000 96 852679 50.0 52.1
40 2-Butanone (MEK) 43 4.319 4.319 0.000 98 3522602 200.0 203.5
11/15/2024
3:53:55 PM
Page 720 of 777
Report Date: 13-Nov-2024 10:03:27 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009396a.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
42 cis-1,2-Dichloroethene 96 4.347 4.347 0.000 89 417710 50.0 51.5
43 2,2-Dichloropropane 77 4.355 4.355 0.000 90 614862 50.0 50.4
45 sec-Butyl Alcohol 45 4.432 4.432 0.000 100 6625777 1200.0 1302.5
47 Chlorobromomethane 128 4.524 4.524 0.000 86 173358 50.0 49.6
48 Tetrahydrofuran 42 4.536 4.536 0.000 96 1189683 100.0 102.2
49 Chloroform 83 4.580 4.580 0.000 96 672777 50.0 52.4
50 1,1,1-Trichloroethane 97 4.725 4.725 0.000 96 528323 50.0 52.8
51 Cyclohexane 56 4.789 4.789 0.000 97 908289 50.0 50.7
52 1,1-Dichloropropene 75 4.837 4.837 0.000 92 599070 50.0 51.4
53 Carbon tetrachloride 117 4.845 4.845 0.000 94 415856 50.0 53.5
54 Isobutyl alcohol 41 4.853 4.853 0.000 95 2625514 1250.0 1279.3
55 Benzene 78 4.994 4.994 0.000 98 1810845 50.0 52.2
56 1,2-Dichloroethane 62 5.022 5.022 0.000 96 632803 50.0 52.0
58 n-Heptane 43 5.174 5.174 0.000 97 703230 50.0 49.0
60 Trichloroethene 95 5.484 5.484 0.000 96 373854 50.0 45.9
61 2-Pentanone 43 5.584 5.584 0.000 97 4416901 160.0 166.5
62 Methylcyclohexane 55 5.676 5.676 0.000 96 645319 50.0 49.4
63 1,2-Dichloropropane 63 5.688 5.688 0.000 91 519371 50.0 52.6
65 1,4-Dioxane 88 5.729 5.729 0.000 94 384016 1000.0 946.1
66 Dibromomethane 93 5.761 5.761 0.000 96 233703 50.0 47.7
67 Dichlorobromomethane 83 5.881 5.881 0.000 97 492293 50.0 54.0
69 2-Chloroethyl vinyl ether 63 6.082 6.082 0.000 89 425052 50.0 52.6
70 cis-1,3-Dichloropropene 75 6.231 6.231 0.000 89 736573 50.0 53.7
71 4-Methyl-2-pentanone (MIBK) 43 6.331 6.331 0.000 97 5934984 200.0 224.7
72 Toluene 91 6.520 6.520 0.000 97 1846908 50.0 52.2
73 trans-1,3-Dichloropropene 75 6.692 6.692 0.000 99 669407 50.0 53.8
74 Ethyl methacrylate 69 6.712 6.712 0.000 98 844990 50.0 52.4
75 1,1,2-Trichloroethane 97 6.869 6.869 0.000 93 371532 50.0 52.6
76 Tetrachloroethene 164 6.961 6.961 0.000 95 285806 50.0 51.4
77 1,3-Dichloropropane 76 7.018 7.018 0.000 98 752853 50.0 51.7
78 2-Hexanone 43 7.034 7.034 0.000 99 4948513 200.0 210.1
79 Chlorodibromomethane 129 7.210 7.210 0.000 90 328397 50.0 54.1
80 Ethylene Dibromide 107 7.331 7.331 0.000 99 370432 50.0 48.9
81 1-Chlorohexane 91 7.716 7.716 0.000 80 427174 40.0 40.9
82 Chlorobenzene 112 7.764 7.764 0.000 90 1064642 50.0 51.3
83 1,1,1,2-Tetrachloroethane 131 7.833 7.833 0.000 95 326029 50.0 54.1
84 Ethylbenzene 106 7.837 7.837 0.000 99 602743 50.0 51.4
85 m-Xylene & p-Xylene 106 7.953 7.953 0.000 0 752169 50.0 50.3
86 o-Xylene 106 8.318 8.318 0.000 98 720488 50.0 51.6
87 Styrene 104 8.331 8.331 0.000 94 1199156 50.0 51.7
88 Bromoform 173 8.515 8.515 0.000 95 225320 50.0 53.1
89 Isopropylbenzene 105 8.656 8.656 0.000 97 1649532 50.0 51.4
91 Cyclohexanone 55 8.760 8.760 0.000 99 2733056 1500.0 1518.4
92 1,1,2,2-Tetrachloroethane 83 8.941 8.941 0.000 94 656666 50.0 54.5
94 trans-1,4-Dichloro-2-butene 53 8.981 8.981 0.000 60 185377 50.0 64.6
93 Bromobenzene 156 8.981 8.981 0.000 96 413521 50.0 51.5
95 1,2,3-Trichloropropane 110 9.009 9.009 0.000 88 205186 50.0 49.5
96 N-Propylbenzene 120 9.057 9.057 0.000 100 480136 50.0 52.0
97 2-Chlorotoluene 126 9.158 9.158 0.000 95 403839 50.0 50.9
98 1,3,5-Trimethylbenzene 105 9.226 9.226 0.000 96 1434069 50.0 51.2
99 4-Chlorotoluene 126 9.274 9.274 0.000 99 425086 50.0 50.9
100 tert-Butylbenzene 119 9.539 9.539 0.000 96 1168933 50.0 50.6
11/15/2024
3:53:55 PM
Page 721 of 777
Report Date: 13-Nov-2024 10:03:27 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009396a.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
102 1,2,4-Trimethylbenzene 105 9.599 9.599 0.000 99 1495794 50.0 50.8
103 sec-Butylbenzene 134 9.756 9.756 0.000 95 335236 50.0 49.6
104 1,3-Dichlorobenzene 146 9.888 9.888 0.000 97 769459 50.0 50.5
105 4-Isopropyltoluene 119 9.905 9.905 0.000 98 1450281 50.0 51.1
106 1,4-Dichlorobenzene 146 9.985 9.985 0.000 92 785326 50.0 49.6
108 n-Butylbenzene 91 10.310 10.310 0.000 99 1336105 50.0 50.3
109 1,2-Dichlorobenzene 146 10.346 10.346 0.000 95 719939 50.0 47.4
110 1,2-Dibromo-3-Chloropropane 157 11.125 11.125 0.000 92 175465 50.0 47.8
112 1,2,4-Trichlorobenzene 180 11.948 11.948 0.000 93 413647 50.0 44.9
113 Hexachlorobutadiene 225 12.085 12.085 0.000 96 159955 50.0 51.5
114 Naphthalene 128 12.221 12.221 0.000 97 1466256 50.0 40.7
115 1,2,3-Trichlorobenzene 180 12.438 12.438 0.000 94 371195 50.0 45.5
S 122 1,2-Dichloroethene, Total (URS) 96 0 100.0 103.5
S 129 1,2-Dichloroethene, Total 1 0 100.0 103.5
S 123 Xylenes, Total (URS) 1 0 100.0 101.8
S 127 Trihalomethanes, Total 1 0 200.0 213.7
S 125 Xylenes, Total 106 0 100.0 101.8
S 124 1,3-Dichloropropene, Total 1 0 100.0 107.5
QC Flag Legend
Processing Flags
Reagents:
MV-MegaMainA_00118 Amount Added: 25.00 Units: uL
MV-Gas A_00202 Amount Added: 10.00 Units: uL
mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 722 of 777
Report Date: 13-Nov-2024 10:03:27 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009396a.D
Injection Date:13-Nov-2024 07:20:30 Instrument ID:VMS_X4 Operator ID:wickhamt
Lims ID:LCS Worklist Smp#:4
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:2
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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11/15/2024
3:53:55 PM
Page 723 of 777
Report Date: 13-Nov-2024 10:03:27 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009396a.D
Lims ID:LCS
Client ID:
Sample Type:LCS
Inject. Date:13-Nov-2024 07:20:30 ALS Bottle#:2 Worklist Smp#:4
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ccv m
Operator ID:wickhamt Instrument ID:VMS_X4
Method:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:13-Nov-2024 10:03:25 Calib Date:29-Oct-2024 20:00:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1654
First Level Reviewer: AF7X Date:13-Nov-2024 08:36:12
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 52.2 104.35
$5 1,2-Dichloroethane-d4 (Surr)50.0 50.6 101.25
$6 Toluene-d8 (Surr)50.0 49.7 99.47
$7 4-Bromofluorobenzene (Surr)50.0 50.0 99.95
11/15/2024
3:53:55 PM
Page 724 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LCSD 280-674451/5
Matrix:VMS14_0000004267.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 05:40
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.14100-41-4 Ethylbenzene 47.4
1.0 0.13100-42-5 Styrene 47.0
1.0 0.1610061-01-5 cis-1,3-Dichloropropene 53.6
1.0 0.1410061-02-6 trans-1,3-Dichloropropene 45.6
1.0 0.18103-65-1 N-Propylbenzene 47.9
1.0 0.23104-51-8 n-Butylbenzene 39.7
1.0 0.21106-43-4 4-Chlorotoluene 49.1
1.0 0.39106-46-7 1,4-Dichlorobenzene 51.4
1.0 0.18106-93-4 Ethylene Dibromide 52.3
2.0 0.46107-05-1 3-Chloro-1-propene 44.5
1.0 0.28107-06-2 1,2-Dichloroethane 46.4
3.0 0.36108-05-4 Vinyl acetate 96.2
5.0 0.98108-10-1 4-Methyl-2-pentanone (MIBK)196
1.0 0.12108-67-8 1,3,5-Trimethylbenzene 45.3
1.0 0.19108-86-1 Bromobenzene 52.0
1.0 0.31108-87-2 Methylcyclohexane 40.3
1.0 0.32108-88-3 Toluene 51.5
1.0 0.092108-90-7 Chlorobenzene 49.2
7.0 0.84109-99-9 Tetrahydrofuran 94.7
2.0 0.16110-54-3 Hexane 39.8
1.0 0.44110-82-7 Cyclohexane 43.4
1.0 0.58120-82-1 1,2,4-Trichlorobenzene 51.6
1.0 0.28124-48-1 Chlorodibromomethane 47.0
1.0 0.40127-18-4 Tetrachloroethene 51.4
1.0 0.20135-98-8 sec-Butylbenzene 46.2
1.0 0.17142-28-9 1,3-Dichloropropane 50.4
1.0 0.32156-59-2 cis-1,2-Dichloroethene 48.6
1.0 0.37156-60-5 trans-1,2-Dichloroethene 46.7
5.0 0.251634-04-4 Methyl tert-butyl ether 50.4
2.0 0.36179601-23-1 m-Xylene & p-Xylene 47.1
1.0 0.33541-73-1 1,3-Dichlorobenzene 48.6
1.0 0.2356-23-5 Carbon tetrachloride 45.1
FORM I 8260D
11/15/2024
3:53:55 PM
Page 725 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LCSD 280-674451/5
Matrix:VMS14_0000004267.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 05:40
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.19563-58-6 1,1-Dichloropropene 45.3
5.0 0.81591-78-6 2-Hexanone 191
1.0 0.17594-20-7 2,2-Dichloropropane 47.8
2.0 0.3560-29-7 Ethyl ether 50.0
1.0 0.16630-20-6 1,1,1,2-Tetrachloroethane 51.9
15 6.667-64-1 Acetone 183
1.0 0.3667-66-3 Chloroform 47.4
1.0 0.1471-43-2 Benzene 47.4
1.0 0.3971-55-6 1,1,1-Trichloroethane 47.3
5.0 2.474-83-9 Bromomethane 31.5
2.0 0.2374-87-3 Chloromethane 45.5
5.0 2.674-88-4 Iodomethane 49.2
1.0 0.3474-95-3 Dibromomethane 51.5
1.0 0.4074-97-5 Chlorobromomethane 51.5
2.0 0.6475-00-3 Chloroethane 36.8
1.0 0.2375-01-4 Vinyl chloride 50.0
2.0 0.9475-09-2 Methylene Chloride 46.4
2.0 0.2675-15-0 Carbon disulfide 45.5
2.0 0.2575-25-2 Bromoform 47.1
1.0 0.1975-27-4 Dichlorobromomethane 44.6
1.0 0.2275-34-3 1,1-Dichloroethane 48.6
1.0 0.2375-35-4 1,1-Dichloroethene 50.3
2.0 0.2075-69-4 Trichlorofluoromethane 47.1
2.0 0.3075-71-8 Dichlorodifluoromethane 37.3
3.0 0.7376-13-1 1,1,2-Trichloro-1,2,2-trifluoroethan
e
46.0
1.0 0.2478-87-5 1,2-Dichloropropane 49.0
10 4.678-93-3 2-Butanone (MEK)195
1.0 0.2779-00-5 1,1,2-Trichloroethane 51.9
1.0 0.3079-01-6 Trichloroethene 47.5
5.0 1.679-20-9 Methyl acetate 94.1
1.0 0.2179-34-5 1,1,2,2-Tetrachloroethane 55.5
4.0 1.287-61-6 1,2,3-Trichlorobenzene 53.0
FORM I 8260D
11/15/2024
3:53:55 PM
Page 726 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LCSD 280-674451/5
Matrix:VMS14_0000004267.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 05:40
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
2.0 0.5387-68-3 Hexachlorobutadiene 50.7
3.0 0.9991-20-3 Naphthalene 44.5
1.0 0.1195-47-6 o-Xylene 45.1
1.0 0.3495-49-8 2-Chlorotoluene 49.1
1.0 0.1495-50-1 1,2-Dichlorobenzene 51.2
1.0 0.1595-63-6 1,2,4-Trimethylbenzene 43.6
5.0 0.4296-12-8 1,2-Dibromo-3-Chloropropane 53.9
2.5 0.2896-18-4 1,2,3-Trichloropropane 55.2
3.0 0.1997-63-2 Ethyl methacrylate 50.6
1.0 0.1898-06-6 tert-Butylbenzene 47.3
1.0 0.1698-82-8 Isopropylbenzene 49.0
1.0 0.1999-87-6 4-Isopropyltoluene 43.7
1.0 0.111330-20-7 Xylenes, Total 92.2
1.0 0.32540-59-0 1,2-Dichloroethene, Total 95.3
1.0 0.14542-75-6 1,3-Dichloropropene, Total 99.2
1.0 0.19STL00209Trihalomethanes, Total 186
1.0 0.14STL00431Total BTEX 239
%RECCAS NO.LIMITSQSURROGATE
98 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr)
103 77-1201868-53-7 Dibromofluoromethane (Surr)
100 80-1252037-26-5 Toluene-d8 (Surr)
95 78-120460-00-4 4-Bromofluorobenzene (Surr)
FORM I 8260D
11/15/2024
3:53:55 PM
Page 727 of 777
Report Date: 11-Nov-2024 06:01:14 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004267.D
Lims ID:LCSD
Client ID:
Sample Type:LCSD
Inject. Date:11-Nov-2024 05:40:59 ALS Bottle#:0 Worklist Smp#:5
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:lcs m
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:11-Nov-2024 06:01:00 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1688
First Level Reviewer: BX8N Date:11-Nov-2024 06:01:00
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.357 0.003 99 993484 50.0 50.0
* 2 Chlorobenzene-d5 119 7.926 7.926 0.000 84 267646 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.174 10.173 0.001 95 429107 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.839 4.839 0.000 94 249071 50.0 51.7
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 94 294972 50.0 49.0
$ 6 Toluene-d8 (Surr) 98 6.637 6.637 0.000 93 1056945 50.0 50.1
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 89 392019 50.0 47.7
10 Dichlorodifluoromethane 85 1.791 1.791 0.000 99 212023 50.0 37.3
12 Chloromethane 50 1.971 1.974 -0.003 99 335802 50.0 45.5
13 Vinyl chloride 62 2.087 2.090 -0.003 98 281397 50.0 50.0
15 Bromomethane 94 2.376 2.389 -0.013 91 115930 50.0 31.5
16 Chloroethane 64 2.473 2.489 -0.016 99 129354 50.0 36.8
17 Dichlorofluoromethane 67 2.666 2.675 -0.009 97 417417 50.0 47.2
18 Trichlorofluoromethane 101 2.701 2.711 -0.010 98 284395 50.0 47.1
21 Ethyl ether 59 2.936 2.936 0.000 90 190614 50.0 50.0
22 Acrolein 56 3.055 3.055 0.000 99 966279 493.8 499.3
25 1,1-Dichloroethene 96 3.135 3.138 -0.003 98 181754 50.0 50.3
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.135 3.141 -0.006 95 112806 50.0 46.0
26 Acetone 43 3.174 3.164 0.010 100 1176779 200.0 182.7
29 Iodomethane 142 3.264 3.267 -0.003 98 210302 50.0 49.2
30 Carbon disulfide 76 3.331 3.334 -0.003 98 489068 50.0 45.5
32 Methyl acetate 43 3.402 3.399 0.003 97 993325 100.0 94.1
33 3-Chloro-1-propene 41 3.418 3.418 0.000 94 275280 50.0 44.5
34 Methylene Chloride 84 3.518 3.518 0.000 90 235251 50.0 46.4
35 2-Methyl-2-propanol 59 3.595 3.579 0.016 100 1959061 500.0 459.2
36 Acrylonitrile 53 3.691 3.688 0.003 99 2771349 500.0 493.4
37 Methyl tert-butyl ether 73 3.714 3.714 0.000 93 711264 50.0 50.4
38 trans-1,2-Dichloroethene 96 3.724 3.727 -0.003 99 178659 50.0 46.7
39 Hexane 57 3.926 3.929 -0.003 90 220984 50.0 39.8
40 Vinyl acetate 43 4.029 4.032 -0.003 97 1094780 100.0 96.2
42 1,1-Dichloroethane 63 4.058 4.055 0.003 96 331855 50.0 48.6
45 2-Butanone (MEK) 43 4.463 4.456 0.007 99 1967149 200.0 195.0
11/15/2024
3:53:55 PM
Page 728 of 777
Report Date: 11-Nov-2024 06:01:14 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004267.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
47 cis-1,2-Dichloroethene 96 4.479 4.482 -0.003 80 216568 50.0 48.6
48 2,2-Dichloropropane 77 4.492 4.495 -0.003 86 254330 50.0 47.8
50 sec-Butyl Alcohol 45 4.588 4.575 0.013 99 3407468 1200.0 1143.0
52 Chlorobromomethane 128 4.659 4.662 -0.003 93 120135 50.0 51.5
53 Tetrahydrofuran 42 4.678 4.678 0.000 89 587140 100.0 94.7
54 Chloroform 83 4.720 4.720 0.000 92 326047 50.0 47.4
55 1,1,1-Trichloroethane 97 4.871 4.871 0.000 97 252454 50.0 47.3
56 Cyclohexane 56 4.936 4.936 0.000 87 282271 50.0 43.4
57 1,1-Dichloropropene 75 4.984 4.987 -0.003 98 256565 50.0 45.3
59 Carbon tetrachloride 117 4.990 4.990 0.000 95 181153 50.0 45.1
58 Isobutyl alcohol 41 5.016 5.003 0.013 96 1320508 1250.0 1182.9
60 Benzene 78 5.145 5.145 0.000 93 778677 50.0 47.4
61 1,2-Dichloroethane 62 5.170 5.167 0.003 97 272141 50.0 46.4
63 n-Heptane 43 5.328 5.328 0.000 91 229405 50.0 39.4
65 Trichloroethene 95 5.640 5.640 0.000 98 213817 50.0 47.5
66 2-Pentanone 43 5.749 5.743 0.006 99 2093920 160.0 147.6
67 Methylcyclohexane 55 5.839 5.842 -0.003 88 218617 50.0 40.3
69 1,2-Dichloropropane 63 5.846 5.849 -0.003 96 213695 50.0 49.0
70 1,4-Dioxane 88 5.904 5.903 0.001 88 223083 1000.0 982.0
71 Dibromomethane 93 5.920 5.923 -0.003 96 150428 50.0 51.5
72 Dichlorobromomethane 83 6.048 6.045 0.003 100 230598 50.0 44.6
74 2-Chloroethyl vinyl ether 63 6.244 6.247 -0.003 91 55019 50.0 15.8
75 cis-1,3-Dichloropropene 75 6.402 6.402 0.000 97 350990 50.0 53.6
76 4-Methyl-2-pentanone (MIBK) 43 6.505 6.501 0.004 95 2337634 200.0 196.1
77 Toluene 91 6.694 6.694 0.000 98 967453 50.0 51.5
78 trans-1,3-Dichloropropene 75 6.865 6.868 -0.003 96 332630 50.0 45.6
79 Ethyl methacrylate 69 6.884 6.884 0.000 87 432995 50.0 50.6
80 1,1,2-Trichloroethane 97 7.048 7.045 0.003 90 236262 50.0 51.9
82 Tetrachloroethene 164 7.148 7.148 0.000 98 164307 50.0 51.4
83 1,3-Dichloropropane 76 7.196 7.196 0.000 91 407316 50.0 50.4
84 2-Hexanone 43 7.215 7.215 0.000 95 2060674 200.0 191.5
85 Chlorodibromomethane 129 7.395 7.392 0.003 91 194162 50.0 47.0
86 Ethylene Dibromide 107 7.514 7.514 0.000 98 259832 50.0 52.3
87 1-Chlorohexane 91 7.907 7.907 0.000 94 222326 40.0 37.0
88 Chlorobenzene 112 7.955 7.955 0.000 95 624940 50.0 49.2
89 1,1,1,2-Tetrachloroethane 131 8.026 8.022 0.004 96 199060 50.0 51.9
90 Ethylbenzene 106 8.029 8.029 0.000 98 318446 50.0 47.4
91 m-Xylene & p-Xylene 106 8.148 8.148 0.000 100 389199 50.0 47.1
92 o-Xylene 106 8.514 8.511 0.003 96 383257 50.0 45.1
93 Styrene 104 8.527 8.527 0.000 94 669846 50.0 47.0
94 Bromoform 173 8.714 8.710 0.004 97 153256 50.0 47.1
95 Isopropylbenzene 105 8.855 8.858 -0.003 95 888665 50.0 49.0
97 Cyclohexanone 55 8.961 8.958 0.003 90 2207068 1500.0 2040.6
98 1,1,2,2-Tetrachloroethane 83 9.141 9.141 0.000 94 390823 50.0 55.5
99 trans-1,4-Dichloro-2-butene 53 9.180 9.177 0.003 91 137410 50.0 48.9
100 Bromobenzene 156 9.186 9.186 0.000 95 263551 50.0 52.0
101 1,2,3-Trichloropropane 110 9.209 9.209 0.000 76 153123 50.0 55.2
102 N-Propylbenzene 120 9.264 9.257 0.007 99 259169 50.0 47.9
103 2-Chlorotoluene 126 9.363 9.360 0.003 97 232214 50.0 49.1
104 1,3,5-Trimethylbenzene 105 9.431 9.431 0.000 95 771658 50.0 45.3
105 4-Chlorotoluene 126 9.479 9.479 0.000 97 247554 50.0 49.1
107 tert-Butylbenzene 119 9.746 9.746 0.000 93 699256 50.0 47.3
11/15/2024
3:53:55 PM
Page 729 of 777
Report Date: 11-Nov-2024 06:01:14 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004267.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
108 1,2,4-Trimethylbenzene 105 9.804 9.804 0.000 97 792957 50.0 43.6
109 sec-Butylbenzene 134 9.968 9.968 0.000 94 205942 50.0 46.2
110 1,3-Dichlorobenzene 146 10.100 10.099 0.001 98 494311 50.0 48.6
111 4-Isopropyltoluene 119 10.112 10.112 0.000 97 845556 50.0 43.7
112 1,4-Dichlorobenzene 146 10.199 10.196 0.003 95 498103 50.0 51.4
114 n-Butylbenzene 91 10.524 10.524 0.000 98 733156 50.0 39.7
115 1,2-Dichlorobenzene 146 10.563 10.559 0.004 98 494937 50.0 51.2
116 1,2-Dibromo-3-Chloropropane 157 11.347 11.344 0.003 89 163122 50.0 53.9
118 1,2,4-Trichlorobenzene 180 12.180 12.180 0.000 94 357712 50.0 51.6
119 Hexachlorobutadiene 225 12.321 12.321 0.000 97 149596 50.0 50.7
120 Naphthalene 128 12.453 12.453 0.000 97 1231075 50.0 44.5
121 1,2,3-Trichlorobenzene 180 12.678 12.678 0.000 96 357617 50.0 53.0
136 Butadiene 54 0.000 ND ND
S 154 1,3-Dichloropropene, Total 1 0 100.0 99.2
S 151 1,2-Dichloroethene, Total 1 0 100.0 95.3
S 152 Trihalomethanes, Total 1 0 200.0 186.1
S 155 Xylenes, Total 106 0 100.0 92.2
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
MV-MegaMainA_00118 Amount Added: 25.00 Units: uL
MV-Gas A_00202 Amount Added: 10.00 Units: uL
mv-IS_SS_00089 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 730 of 777
Report Date: 11-Nov-2024 06:01:14 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004267.D
Injection Date:11-Nov-2024 05:40:59 Instrument ID:VMS_MS14 Operator ID:MED
Lims ID:LCSD Worklist Smp#:5
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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11/15/2024
3:53:55 PM
Page 731 of 777
Report Date: 11-Nov-2024 06:01:14 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004267.D
Lims ID:LCSD
Client ID:
Sample Type:LCSD
Inject. Date:11-Nov-2024 05:40:59 ALS Bottle#:0 Worklist Smp#:5
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:lcs m
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:11-Nov-2024 06:01:00 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1688
First Level Reviewer: BX8N Date:11-Nov-2024 06:01:00
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 51.7 103.44
$5 1,2-Dichloroethane-d4 (Surr)50.0 49.0 98.09
$6 Toluene-d8 (Surr)50.0 50.1 100.21
$7 4-Bromofluorobenzene (Surr)50.0 47.7 95.49
11/15/2024
3:53:55 PM
Page 732 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LCSD 280-674813/5
Matrix:X4_00009398.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/13/2024 08:02
ID:RXI-624SilMS
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674813 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_X4
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.14100-41-4 Ethylbenzene 51.1
1.0 0.13100-42-5 Styrene 51.0
1.0 0.1610061-01-5 cis-1,3-Dichloropropene 52.5
1.0 0.1410061-02-6 trans-1,3-Dichloropropene 54.2
1.0 0.18103-65-1 N-Propylbenzene 50.8
1.0 0.23104-51-8 n-Butylbenzene 48.8
1.0 0.21106-43-4 4-Chlorotoluene 49.2
1.0 0.39106-46-7 1,4-Dichlorobenzene 49.0
1.0 0.18106-93-4 Ethylene Dibromide 48.4
2.0 0.46107-05-1 3-Chloro-1-propene 55.8
1.0 0.28107-06-2 1,2-Dichloroethane 52.6
3.0 0.36108-05-4 Vinyl acetate 112
5.0 0.98108-10-1 4-Methyl-2-pentanone (MIBK)226
1.0 0.12108-67-8 1,3,5-Trimethylbenzene 50.3
1.0 0.19108-86-1 Bromobenzene 50.4
1.0 0.31108-87-2 Methylcyclohexane 48.1
1.0 0.32108-88-3 Toluene 52.3
1.0 0.092108-90-7 Chlorobenzene 50.5
7.0 0.84109-99-9 Tetrahydrofuran 103
2.0 0.16110-54-3 Hexane 45.3
1.0 0.44110-82-7 Cyclohexane 49.6
1.0 0.58120-82-1 1,2,4-Trichlorobenzene 44.1
1.0 0.28124-48-1 Chlorodibromomethane 53.1
1.0 0.40127-18-4 Tetrachloroethene 51.1
1.0 0.20135-98-8 sec-Butylbenzene 48.5
1.0 0.17142-28-9 1,3-Dichloropropane 51.2
1.0 0.32156-59-2 cis-1,2-Dichloroethene 50.2
1.0 0.37156-60-5 trans-1,2-Dichloroethene 51.1
5.0 0.251634-04-4 Methyl tert-butyl ether 52.7
2.0 0.36179601-23-1 m-Xylene & p-Xylene 48.7
1.0 0.33541-73-1 1,3-Dichlorobenzene 49.4
1.0 0.2356-23-5 Carbon tetrachloride 53.4
FORM I 8260D
11/15/2024
3:53:55 PM
Page 733 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LCSD 280-674813/5
Matrix:X4_00009398.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/13/2024 08:02
ID:RXI-624SilMS
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674813 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_X4
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.19563-58-6 1,1-Dichloropropene 51.6
5.0 0.81591-78-6 2-Hexanone 206
1.0 0.17594-20-7 2,2-Dichloropropane 49.0
2.0 0.3560-29-7 Ethyl ether 51.6
1.0 0.16630-20-6 1,1,1,2-Tetrachloroethane 53.4
15 6.667-64-1 Acetone 196
1.0 0.3667-66-3 Chloroform 53.1
1.0 0.1471-43-2 Benzene 52.5
1.0 0.3971-55-6 1,1,1-Trichloroethane 53.3
5.0 2.474-83-9 Bromomethane 41.4
2.0 0.2374-87-3 Chloromethane 53.9
5.0 2.674-88-4 Iodomethane 58.3
1.0 0.3474-95-3 Dibromomethane 48.0
1.0 0.4074-97-5 Chlorobromomethane 51.4
2.0 0.6475-00-3 Chloroethane 52.7
1.0 0.2375-01-4 Vinyl chloride 52.7
2.0 0.9475-09-2 Methylene Chloride 49.8
2.0 0.2675-15-0 Carbon disulfide 50.6
2.0 0.2575-25-2 Bromoform 50.8
1.0 0.1975-27-4 Dichlorobromomethane 53.9
1.0 0.2275-34-3 1,1-Dichloroethane 52.3
1.0 0.2375-35-4 1,1-Dichloroethene 50.2
2.0 0.2075-69-4 Trichlorofluoromethane 48.7
2.0 0.3075-71-8 Dichlorodifluoromethane 48.1
3.0 0.7376-13-1 1,1,2-Trichloro-1,2,2-trifluoroethan
e
48.7
1.0 0.2478-87-5 1,2-Dichloropropane 52.8
10 4.678-93-3 2-Butanone (MEK)206
1.0 0.2779-00-5 1,1,2-Trichloroethane 51.7
1.0 0.3079-01-6 Trichloroethene 47.0
5.0 1.679-20-9 Methyl acetate 107
1.0 0.2179-34-5 1,1,2,2-Tetrachloroethane 53.7
4.0 1.287-61-6 1,2,3-Trichlorobenzene 43.9
FORM I 8260D
11/15/2024
3:53:55 PM
Page 734 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LCSD 280-674813/5
Matrix:X4_00009398.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/13/2024 08:02
ID:RXI-624SilMS
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674813 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_X4
CAS NO.COMPOUND NAME RESULT Q MDLRL
2.0 0.5387-68-3 Hexachlorobutadiene 49.3
3.0 0.9991-20-3 Naphthalene 40.6
1.0 0.1195-47-6 o-Xylene 51.6
1.0 0.3495-49-8 2-Chlorotoluene 49.2
1.0 0.1495-50-1 1,2-Dichlorobenzene 48.2
1.0 0.1595-63-6 1,2,4-Trimethylbenzene 50.4
5.0 0.4296-12-8 1,2-Dibromo-3-Chloropropane 48.7
2.5 0.2896-18-4 1,2,3-Trichloropropane 50.2
3.0 0.1997-63-2 Ethyl methacrylate 50.5
1.0 0.1898-06-6 tert-Butylbenzene 49.2
1.0 0.1698-82-8 Isopropylbenzene 50.2
1.0 0.1999-87-6 4-Isopropyltoluene 49.8
1.0 0.111330-20-7 Xylenes, Total 100
1.0 0.32540-59-0 1,2-Dichloroethene, Total 101
1.0 0.14542-75-6 1,3-Dichloropropene, Total 107
1.0 0.19STL00209Trihalomethanes, Total 211
1.0 0.14STL00431Total BTEX 256
%RECCAS NO.LIMITSQSURROGATE
107 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr)
103 77-1201868-53-7 Dibromofluoromethane (Surr)
98 80-1252037-26-5 Toluene-d8 (Surr)
101 78-120460-00-4 4-Bromofluorobenzene (Surr)
FORM I 8260D
11/15/2024
3:53:55 PM
Page 735 of 777
Report Date: 13-Nov-2024 10:03:33 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009398.D
Lims ID:LCSD
Client ID:
Sample Type:LCSD
Inject. Date:13-Nov-2024 08:02:30 ALS Bottle#:4 Worklist Smp#:5
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:lcsd m
Operator ID:wickhamt Instrument ID:VMS_X4
Method:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:13-Nov-2024 10:03:25 Calib Date:29-Oct-2024 20:00:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1654
First Level Reviewer: AF7X Date:13-Nov-2024 08:37:42
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.206 5.207 -0.001 98 1565133 50.0 50.0
* 2 Chlorobenzene-d5 119 7.736 7.736 0.000 92 355259 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 9.961 9.961 0.000 96 559253 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.696 4.697 -0.001 93 326850 50.0 51.5
$ 5 1,2-Dichloroethane-d4 (Surr) 65 4.962 4.962 0.000 0 506949 50.0 53.3
$ 6 Toluene-d8 (Surr) 98 6.463 6.463 0.000 96 1627458 50.0 48.8
$ 7 4-Bromofluorobenzene (Surr) 95 8.832 8.832 0.000 83 550085 50.0 50.4
9 Dichlorodifluoromethane 85 1.749 1.749 0.000 99 430508 50.0 48.1
10 Chloromethane 50 1.934 1.934 0.000 99 717987 50.0 53.9
11 Vinyl chloride 62 2.038 2.035 0.003 98 532831 50.0 52.7
12 Bromomethane 94 2.311 2.312 -0.001 91 137310 50.0 41.4
13 Chloroethane 64 2.416 2.412 0.004 99 348785 50.0 52.7
14 Dichlorofluoromethane 67 2.596 2.593 0.003 96 885167 50.0 56.5
16 Trichlorofluoromethane 101 2.629 2.629 0.000 98 462867 50.0 48.7
18 Ethyl ether 59 2.845 2.846 -0.001 95 453433 50.0 51.6
19 Acrolein 56 2.958 2.958 0.000 99 1369015 493.8 516.6
21 1,1-Dichloroethene 96 3.042 3.042 0.000 92 322534 50.0 50.2
20 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.038 3.042 -0.004 97 215702 50.0 48.7
22 Acetone 43 3.062 3.062 0.000 98 2017412 200.0 195.5
24 Iodomethane 142 3.167 3.167 0.000 98 212255 50.0 58.3
25 Carbon disulfide 76 3.231 3.227 0.004 100 1202600 50.0 50.6
27 Methyl acetate 43 3.291 3.291 0.000 100 2110836 100.0 107.1
28 3-Chloro-1-propene 41 3.315 3.315 0.000 89 1134616 50.0 55.8
29 Methylene Chloride 84 3.412 3.412 0.000 94 415247 50.0 49.8
30 2-Methyl-2-propanol 59 3.460 3.460 0.000 98 2757552 500.0 501.2
31 Acrylonitrile 53 3.576 3.576 0.000 99 4848626 500.0 527.1
32 Methyl tert-butyl ether 73 3.596 3.596 0.000 98 1462190 50.0 52.7
33 trans-1,2-Dichloroethene 96 3.612 3.613 -0.001 92 373635 50.0 51.1
34 Hexane 57 3.805 3.805 0.000 97 666006 50.0 45.3
35 Vinyl acetate 43 3.909 3.910 -0.001 96 3266380 100.0 111.7
36 1,1-Dichloroethane 63 3.934 3.934 0.000 96 866593 50.0 52.3
40 2-Butanone (MEK) 43 4.323 4.319 0.004 98 3603734 200.0 205.6
11/15/2024
3:53:55 PM
Page 736 of 777
Report Date: 13-Nov-2024 10:03:33 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009398.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
42 cis-1,2-Dichloroethene 96 4.347 4.347 0.000 89 412863 50.0 50.2
43 2,2-Dichloropropane 77 4.359 4.355 0.004 92 605090 50.0 49.0
45 sec-Butyl Alcohol 45 4.435 4.432 0.003 100 6947126 1200.0 1348.3
47 Chlorobromomethane 128 4.524 4.524 0.000 87 182034 50.0 51.4
48 Tetrahydrofuran 42 4.536 4.536 0.000 96 1211819 100.0 102.7
49 Chloroform 83 4.580 4.580 0.000 97 689972 50.0 53.1
50 1,1,1-Trichloroethane 97 4.725 4.725 0.000 97 540060 50.0 53.3
51 Cyclohexane 56 4.789 4.789 0.000 98 901019 50.0 49.6
52 1,1-Dichloropropene 75 4.841 4.837 0.004 90 609553 50.0 51.6
53 Carbon tetrachloride 117 4.845 4.845 0.000 93 420413 50.0 53.4
54 Isobutyl alcohol 41 4.853 4.853 0.000 95 2729192 1250.0 1312.9
55 Benzene 78 4.994 4.994 0.000 98 1845840 50.0 52.5
56 1,2-Dichloroethane 62 5.022 5.022 0.000 95 648002 50.0 52.6
58 n-Heptane 43 5.178 5.174 0.004 97 689745 50.0 47.4
60 Trichloroethene 95 5.479 5.484 -0.005 97 396057 50.0 47.0
61 2-Pentanone 43 5.584 5.584 0.000 97 4527088 160.0 168.5
62 Methylcyclohexane 55 5.676 5.676 0.000 90 635863 50.0 48.1
63 1,2-Dichloropropane 63 5.692 5.688 0.004 92 527277 50.0 52.8
65 1,4-Dioxane 88 5.732 5.729 0.003 99 405177 1000.0 985.6
66 Dibromomethane 93 5.761 5.761 0.000 96 238515 50.0 48.0
67 Dichlorobromomethane 83 5.885 5.881 0.004 97 497303 50.0 53.9
69 2-Chloroethyl vinyl ether 63 6.082 6.082 0.000 89 438269 50.0 53.5
70 cis-1,3-Dichloropropene 75 6.230 6.231 -0.001 90 746040 50.0 52.5
71 4-Methyl-2-pentanone (MIBK) 43 6.335 6.331 0.004 97 6050364 200.0 226.2
72 Toluene 91 6.523 6.520 0.003 97 1874839 50.0 52.3
73 trans-1,3-Dichloropropene 75 6.692 6.692 0.000 99 683726 50.0 54.2
74 Ethyl methacrylate 69 6.712 6.712 0.000 97 841615 50.0 50.5
75 1,1,2-Trichloroethane 97 6.869 6.869 0.000 93 370146 50.0 51.7
76 Tetrachloroethene 164 6.965 6.961 0.004 97 293494 50.0 51.1
77 1,3-Dichloropropane 76 7.017 7.018 -0.001 97 771221 50.0 51.2
78 2-Hexanone 43 7.037 7.034 0.003 98 5028099 200.0 206.4
79 Chlorodibromomethane 129 7.210 7.210 0.000 89 333167 50.0 53.1
80 Ethylene Dibromide 107 7.331 7.331 0.000 99 379276 50.0 48.4
81 1-Chlorohexane 91 7.716 7.716 0.000 80 433840 40.0 40.2
82 Chlorobenzene 112 7.764 7.764 0.000 90 1085338 50.0 50.5
83 1,1,1,2-Tetrachloroethane 131 7.836 7.833 0.003 95 332970 50.0 53.4
84 Ethylbenzene 106 7.836 7.837 -0.001 99 620482 50.0 51.1
85 m-Xylene & p-Xylene 106 7.957 7.953 0.004 0 752752 50.0 48.7
86 o-Xylene 106 8.318 8.318 0.000 99 746494 50.0 51.6
87 Styrene 104 8.334 8.331 0.003 95 1222542 50.0 51.0
88 Bromoform 173 8.515 8.515 0.000 95 223093 50.0 50.8
89 Isopropylbenzene 105 8.656 8.656 0.000 97 1654396 50.0 50.2
91 Cyclohexanone 55 8.760 8.760 0.000 99 2778398 1500.0 1492.2
92 1,1,2,2-Tetrachloroethane 83 8.945 8.941 0.004 94 664197 50.0 53.7
94 trans-1,4-Dichloro-2-butene 53 8.981 8.981 0.000 59 198154 50.0 67.2
93 Bromobenzene 156 8.981 8.981 0.000 95 416173 50.0 50.4
95 1,2,3-Trichloropropane 110 9.009 9.009 0.000 88 213734 50.0 50.2
96 N-Propylbenzene 120 9.057 9.057 0.000 100 482014 50.0 50.8
97 2-Chlorotoluene 126 9.157 9.158 -0.001 95 400965 50.0 49.2
98 1,3,5-Trimethylbenzene 105 9.230 9.226 0.004 96 1447815 50.0 50.3
99 4-Chlorotoluene 126 9.274 9.274 0.000 99 422535 50.0 49.2
100 tert-Butylbenzene 119 9.539 9.539 0.000 95 1168113 50.0 49.2
11/15/2024
3:53:55 PM
Page 737 of 777
Report Date: 13-Nov-2024 10:03:33 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009398.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
102 1,2,4-Trimethylbenzene 105 9.595 9.599 -0.004 99 1523731 50.0 50.4
103 sec-Butylbenzene 134 9.756 9.756 0.000 95 336515 50.0 48.5
104 1,3-Dichlorobenzene 146 9.888 9.888 0.000 97 773343 50.0 49.4
105 4-Isopropyltoluene 119 9.904 9.905 -0.001 98 1453646 50.0 49.8
106 1,4-Dichlorobenzene 146 9.989 9.985 0.004 94 796801 50.0 49.0
108 n-Butylbenzene 91 10.310 10.310 0.000 99 1329885 50.0 48.8
109 1,2-Dichlorobenzene 146 10.346 10.346 0.000 96 753123 50.0 48.2
110 1,2-Dibromo-3-Chloropropane 157 11.125 11.125 0.000 74 183771 50.0 48.7
112 1,2,4-Trichlorobenzene 180 11.948 11.948 0.000 93 416914 50.0 44.1
113 Hexachlorobutadiene 225 12.085 12.085 0.000 95 157421 50.0 49.3
114 Naphthalene 128 12.221 12.221 0.000 97 1500136 50.0 40.6
115 1,2,3-Trichlorobenzene 180 12.442 12.438 0.004 94 368348 50.0 43.9
S 122 1,2-Dichloroethene, Total (URS) 96 0 100.0 101.3
S 129 1,2-Dichloroethene, Total 1 0 100.0 101.3
S 123 Xylenes, Total (URS) 1 0 100.0 100.3
S 127 Trihalomethanes, Total 1 0 200.0 210.9
S 125 Xylenes, Total 106 0 100.0 100.3
S 124 1,3-Dichloropropene, Total 1 0 100.0 106.8
QC Flag Legend
Processing Flags
Reagents:
MV-MegaMainA_00118 Amount Added: 25.00 Units: uL
MV-Gas A_00202 Amount Added: 10.00 Units: uL
mv-IS_SS_00086 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 738 of 777
Report Date: 13-Nov-2024 10:03:33 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009398.D
Injection Date:13-Nov-2024 08:02:30 Instrument ID:VMS_X4 Operator ID:wickhamt
Lims ID:LCSD Worklist Smp#:5
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:4
Method:VMS_X4_8260 Limit Group:MSV - 8260B Water and Solid
Column: Rxi-624Sil MS ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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11/15/2024
3:53:55 PM
Page 739 of 777
Report Date: 13-Nov-2024 10:03:33 Chrom Revision: 2.3 12-Nov-2024 16:55:22
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\X4_00009398.D
Lims ID:LCSD
Client ID:
Sample Type:LCSD
Inject. Date:13-Nov-2024 08:02:30 ALS Bottle#:4 Worklist Smp#:5
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:lcsd m
Operator ID:wickhamt Instrument ID:VMS_X4
Method:\\chromfs\Denver\ChromData\VMS_X4\20241113-139753.b\VMS_X4_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:13-Nov-2024 10:03:25 Calib Date:29-Oct-2024 20:00:30
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_X4\20241029-139167.b\X4_00008669.D
Column 1 :Rxi-624Sil MS ( 0.25 mm)Det: MS SCAN
Process Host:CTX1654
First Level Reviewer: AF7X Date:13-Nov-2024 08:37:42
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 51.5 103.06
$5 1,2-Dichloroethane-d4 (Surr)50.0 53.3 106.61
$6 Toluene-d8 (Surr)50.0 48.8 97.51
$7 4-Bromofluorobenzene (Surr)50.0 50.4 100.87
11/15/2024
3:53:55 PM
Page 740 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:MW-63-241030 MS Lab Sample ID:280-198899-3 MS
Matrix:VMS14_0000004290.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
10/30/2024 12:20
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 13:37
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.14100-41-4 Ethylbenzene 23.6
1.0 0.13100-42-5 Styrene 23.6
1.0 0.1610061-01-5 cis-1,3-Dichloropropene 24.7
1.0 0.1410061-02-6 trans-1,3-Dichloropropene 18.9
1.0 0.18103-65-1 N-Propylbenzene 20.9
1.0 0.23104-51-8 n-Butylbenzene 13.2
1.0 0.21106-43-4 4-Chlorotoluene 22.9
1.0 0.39106-46-7 1,4-Dichlorobenzene 23.2
1.0 0.18106-93-4 Ethylene Dibromide 25.0
2.0 0.46107-05-1 3-Chloro-1-propene 20.8
1.0 0.28107-06-2 1,2-Dichloroethane 21.8
3.0 0.36108-05-4 Vinyl acetate 47.8
5.0 0.98108-10-1 4-Methyl-2-pentanone (MIBK)91.3
1.0 0.12108-67-8 1,3,5-Trimethylbenzene 20.4
1.0 0.19108-86-1 Bromobenzene 24.5
1.0 0.31108-87-2 Methylcyclohexane 13.4
1.0 0.32108-88-3 Toluene 24.1
1.0 0.092108-90-7 Chlorobenzene 24.5
7.0 0.84109-99-9 Tetrahydrofuran 44.5
2.0 0.16110-54-3 Hexane 13.5
1.0 0.44110-82-7 Cyclohexane 18.8
1.0 0.58120-82-1 1,2,4-Trichlorobenzene 17.5
1.0 0.28124-48-1 Chlorodibromomethane 21.4
1.0 0.40127-18-4 Tetrachloroethene 25.5
1.0 0.20135-98-8 sec-Butylbenzene 16.2
1.0 0.17142-28-9 1,3-Dichloropropane 24.4
1.0 0.32156-59-2 cis-1,2-Dichloroethene 24.0
1.0 0.37156-60-5 trans-1,2-Dichloroethene 24.5
5.0 0.251634-04-4 Methyl tert-butyl ether 24.2
2.0 0.36179601-23-1 m-Xylene & p-Xylene 24.6
1.0 0.33541-73-1 1,3-Dichlorobenzene 21.5
1.0 0.2356-23-5 Carbon tetrachloride 21.9
FORM I 8260D
11/15/2024
3:53:55 PM
Page 741 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:MW-63-241030 MS Lab Sample ID:280-198899-3 MS
Matrix:VMS14_0000004290.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
10/30/2024 12:20
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 13:37
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.19563-58-6 1,1-Dichloropropene 22.8
5.0 0.81591-78-6 2-Hexanone 96.9
1.0 0.17594-20-7 2,2-Dichloropropane 21.6
2.0 0.3560-29-7 Ethyl ether 24.6
1.0 0.16630-20-6 1,1,1,2-Tetrachloroethane 24.5
15 6.667-64-1 Acetone 87.2
1.0 0.3667-66-3 Chloroform 23.3
1.0 0.1471-43-2 Benzene 23.9
1.0 0.3971-55-6 1,1,1-Trichloroethane 23.4
5.0 2.474-83-9 Bromomethane 27.0
2.0 0.2374-87-3 Chloromethane 24.9
5.0 2.674-88-4 Iodomethane 27.8
1.0 0.3474-95-3 Dibromomethane 22.9
1.0 0.4074-97-5 Chlorobromomethane 25.7
2.0 0.6475-00-3 Chloroethane 23.8
1.0 0.2375-01-4 Vinyl chloride 24.2
2.0 0.9475-09-2 Methylene Chloride 23.9
2.0 0.2675-15-0 Carbon disulfide 23.3
2.0 0.2575-25-2 Bromoform 20.6
1.0 0.1975-27-4 Dichlorobromomethane 20.1
1.0 0.2275-34-3 1,1-Dichloroethane 24.1
1.0 0.2375-35-4 1,1-Dichloroethene 23.2
2.0 0.2075-69-4 Trichlorofluoromethane 22.7
2.0 0.3075-71-8 Dichlorodifluoromethane 20.3
3.0 0.7376-13-1 1,1,2-Trichloro-1,2,2-trifluoroethan
e
23.8
1.0 0.2478-87-5 1,2-Dichloropropane 23.2
10 4.678-93-3 2-Butanone (MEK)87.8
1.0 0.2779-00-5 1,1,2-Trichloroethane 24.0
1.0 0.3079-01-6 Trichloroethene 24.0
5.0 1.679-20-9 Methyl acetate 42.5
1.0 0.2179-34-5 1,1,2,2-Tetrachloroethane 27.0
4.0 1.287-61-6 1,2,3-Trichlorobenzene 18.1
FORM I 8260D
11/15/2024
3:53:55 PM
Page 742 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:MW-63-241030 MS Lab Sample ID:280-198899-3 MS
Matrix:VMS14_0000004290.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
10/30/2024 12:20
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 13:37
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
2.0 0.5387-68-3 Hexachlorobutadiene 6.79
3.0 0.9991-20-3 Naphthalene 22.2
1.0 0.1195-47-6 o-Xylene 23.9
1.0 0.3495-49-8 2-Chlorotoluene 22.8
1.0 0.1495-50-1 1,2-Dichlorobenzene 23.1
1.0 0.1595-63-6 1,2,4-Trimethylbenzene 20.3
5.0 0.4296-12-8 1,2-Dibromo-3-Chloropropane 24.6
2.5 0.2896-18-4 1,2,3-Trichloropropane 25.9
3.0 0.1997-63-2 Ethyl methacrylate 24.4
1.0 0.1898-06-6 tert-Butylbenzene 18.7
1.0 0.1698-82-8 Isopropylbenzene 21.5
1.0 0.1999-87-6 4-Isopropyltoluene 16.8
1.0 0.111330-20-7 Xylenes, Total 48.5
1.0 0.32540-59-0 1,2-Dichloroethene, Total 48.5
1.0 0.14542-75-6 1,3-Dichloropropene, Total 43.6
1.0 0.19STL00209Trihalomethanes, Total 85.4
1.0 0.14STL00431Total BTEX 120
%RECCAS NO.LIMITSQSURROGATE
90 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr)
100 77-1201868-53-7 Dibromofluoromethane (Surr)
106 80-1252037-26-5 Toluene-d8 (Surr)
93 78-120460-00-4 4-Bromofluorobenzene (Surr)
FORM I 8260D
11/15/2024
3:53:55 PM
Page 743 of 777
Report Date: 11-Nov-2024 16:15:45 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004290.D
Lims ID:280-198899-B-3 MS
Client ID:MW-63-241030
Sample Type:MS
Inject. Date:11-Nov-2024 13:37:49 ALS Bottle#:0 Worklist Smp#:32
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:280-198899-B-3 MS
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:11-Nov-2024 16:14:22 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:11-Nov-2024 16:13:55
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.357 0.003 99 925276 50.0 50.0
* 2 Chlorobenzene-d5 119 7.929 7.926 0.003 84 233855 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.173 0.000 94 400939 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.842 4.839 0.003 94 225367 50.0 50.2
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 95 251859 50.0 45.0
$ 6 Toluene-d8 (Surr) 98 6.640 6.637 0.003 92 976808 50.0 53.0
$ 7 4-Bromofluorobenzene (Surr) 95 9.035 9.032 0.003 90 356796 50.0 46.5
$ 8 BFB 95 9.035 9.032 0.003 85 356796 NR
9 Chlorotrifluoroethene 116 1.677 ND
10 Dichlorodifluoromethane 85 1.791 1.791 0.000 99 105893 25.0 20.3
11 Ethylene oxide 43 1.756 1.843 -0.087 50 3235 21.8
12 Chloromethane 50 1.974 1.974 0.000 99 171195 25.0 24.9
13 Vinyl chloride 62 2.087 2.090 -0.003 98 126693 25.0 24.2
14 2-Chloro-1,1,1-Trifluoroethane 118 2.110 ND
15 Bromomethane 94 2.395 2.389 0.006 90 92352 25.0 27.0
16 Chloroethane 64 2.492 2.489 0.003 99 77869 25.0 23.8
17 Dichlorofluoromethane 67 2.675 2.675 0.000 96 199761 25.0 24.3
18 Trichlorofluoromethane 101 2.717 2.711 0.006 97 127481 25.0 22.7
19 Propene oxide 58 2.738 ND
20 Ethanol 45 2.875 ND U
21 Ethyl ether 59 2.939 2.936 0.003 90 87461 25.0 24.6
22 Acrolein 56 3.055 3.055 0.000 99 437109 246.9 242.5
23 1,2-Dichloro-1,1,2-trifluoroetha 117 3.129 ND
25 1,1-Dichloroethene 96 3.145 3.138 0.007 97 77689 25.0 23.2
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.141 3.141 0.000 65 54464 25.0 23.8
26 Acetone 43 3.164 3.164 0.000 100 543202 100.0 87.2
27 1,1,1-Trifluoro-2,2-dichloroetha 83 3.213 ND
28 Isopropyl alcohol 45 3.257 ND U
29 Iodomethane 142 3.270 3.267 0.003 98 107428 25.0 27.8
30 Carbon disulfide 76 3.337 3.334 0.003 98 233577 25.0 23.3
31 Acetonitrile 41 3.379 ND
32 Methyl acetate 43 3.395 3.399 -0.004 97 417353 50.0 42.5
11/15/2024
3:53:55 PM
Page 744 of 777
Report Date: 11-Nov-2024 16:15:45 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004290.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
33 3-Chloro-1-propene 41 3.424 3.418 0.006 94 119835 25.0 20.8
34 Methylene Chloride 84 3.521 3.518 0.003 89 113108 25.0 23.9
35 2-Methyl-2-propanol 59 3.569 3.579 -0.010 100 992527 250.0 249.8
36 Acrylonitrile 53 3.688 3.688 0.000 99 1247120 250.0 238.4
37 Methyl tert-butyl ether 73 3.714 3.714 0.000 94 317466 25.0 24.2
38 trans-1,2-Dichloroethene 96 3.730 3.727 0.003 99 87394 25.0 24.5
39 Hexane 57 3.932 3.929 0.003 89 65380 25.0 13.5
40 Vinyl acetate 43 4.032 4.032 0.000 97 506069 50.0 47.8
42 1,1-Dichloroethane 63 4.061 4.055 0.006 95 153563 25.0 24.1
41 Isopropyl ether 87 4.055 ND
43 2-Chloro-1,3-butadiene 53 4.113 ND
44 Tert-butyl ethyl ether 59 4.325 ND
45 2-Butanone (MEK) 43 4.453 4.456 -0.003 99 839138 100.0 87.8
46 Ethyl acetate 43 4.463 ND
47 cis-1,2-Dichloroethene 96 4.485 4.482 0.003 78 99405 25.0 24.0
48 2,2-Dichloropropane 77 4.492 4.495 -0.003 83 107029 25.0 21.6
49 Propionitrile 54 4.505 ND U
50 sec-Butyl Alcohol 45 4.569 4.575 -0.006 99 1737965 600.0 626.0
51 Methacrylonitrile 41 4.617 ND
52 Chlorobromomethane 128 4.662 4.662 0.000 93 55875 25.0 25.7
53 Tetrahydrofuran 42 4.672 4.678 -0.006 87 256812 50.0 44.5
54 Chloroform 83 4.720 4.720 0.000 92 149422 25.0 23.3
55 1,1,1-Trichloroethane 97 4.874 4.871 0.003 98 116381 25.0 23.4
56 Cyclohexane 56 4.936 4.936 0.000 86 113788 25.0 18.8
57 1,1-Dichloropropene 75 4.990 4.987 0.003 97 120019 25.0 22.8
59 Carbon tetrachloride 117 4.993 4.990 0.003 80 80910 25.0 21.9
58 Isobutyl alcohol 41 4.997 5.003 -0.006 96 671427 625.0 645.8
60 Benzene 78 5.145 5.145 0.000 94 365065 25.0 23.9
61 1,2-Dichloroethane 62 5.170 5.167 0.003 97 119331 25.0 21.8
62 Tert-amyl methyl ether 73 5.209 ND
63 n-Heptane 43 5.331 5.328 0.003 91 39966 25.0 7.37
64 n-Butanol 56 5.502 ND
65 Trichloroethene 95 5.646 5.640 0.006 97 94446 25.0 24.0
66 2-Pentanone 43 5.743 5.743 0.000 99 917864 80.0 69.5
67 Methylcyclohexane 55 5.842 5.842 0.000 86 67601 25.0 13.4
68 Methyl methacrylate 100 5.846 ND U
69 1,2-Dichloropropane 63 5.852 5.849 0.003 96 94048 25.0 23.2
70 1,4-Dioxane 88 5.907 5.903 0.004 92 135218 500.0 636.0
71 Dibromomethane 93 5.923 5.923 0.000 95 62297 25.0 22.9
72 Dichlorobromomethane 83 6.045 6.045 0.000 99 95177 25.0 20.1
73 2-Nitropropane 41 6.215 ND
74 2-Chloroethyl vinyl ether 63 6.247 ND ND
75 cis-1,3-Dichloropropene 75 6.402 6.402 0.000 98 141094 25.0 24.7
76 4-Methyl-2-pentanone (MIBK) 43 6.501 6.501 0.000 95 1013831 100.0 91.3
77 Toluene 91 6.698 6.694 0.004 98 421371 25.0 24.1
78 trans-1,3-Dichloropropene 75 6.871 6.868 0.003 90 125778 25.0 18.9
79 Ethyl methacrylate 69 6.887 6.884 0.003 88 182293 25.0 24.4
80 1,1,2-Trichloroethane 97 7.048 7.045 0.003 89 101595 25.0 24.0
81 Tetrahydrothiophene 60 7.051 ND
82 Tetrachloroethene 164 7.148 7.148 0.000 98 71089 25.0 25.5
83 1,3-Dichloropropane 76 7.199 7.196 0.003 87 172072 25.0 24.4
84 2-Hexanone 43 7.212 7.215 -0.003 94 910841 100.0 96.9
11/15/2024
3:53:55 PM
Page 745 of 777
Report Date: 11-Nov-2024 16:15:45 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004290.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
85 Chlorodibromomethane 129 7.392 7.392 0.000 90 75928 25.0 21.4
86 Ethylene Dibromide 107 7.514 7.514 0.000 98 108488 25.0 25.0
87 1-Chlorohexane 91 7.907 7.907 -0.001 91 84270 20.0 15.9
88 Chlorobenzene 112 7.955 7.955 0.000 96 272210 25.0 24.5
89 1,1,1,2-Tetrachloroethane 131 8.025 8.022 0.003 93 81668 25.0 24.5
90 Ethylbenzene 106 8.032 8.029 0.003 98 138598 25.0 23.6
91 m-Xylene & p-Xylene 106 8.144 8.148 -0.004 99 177458 25.0 24.6
92 o-Xylene 106 8.514 8.511 0.003 96 177718 25.0 23.9
93 Styrene 104 8.530 8.527 0.003 94 294720 25.0 23.6
94 Bromoform 173 8.714 8.710 0.004 97 56158 25.0 20.6
95 Isopropylbenzene 105 8.855 8.858 -0.003 95 363868 25.0 21.5
96 cis-1,4-Dichloro-2-butene 53 8.906 8.907 -0.001 56 1563 0.6293
97 Cyclohexanone 55 8.964 8.958 0.006 89 750528 750.0 794.2
98 1,1,2,2-Tetrachloroethane 83 9.144 9.141 0.003 94 177507 25.0 27.0
99 trans-1,4-Dichloro-2-butene 53 9.180 9.177 0.003 53 49723 25.0 19.3
100 Bromobenzene 156 9.186 9.186 0.000 93 115976 25.0 24.5
101 1,2,3-Trichloropropane 110 9.212 9.209 0.003 76 67263 25.0 25.9
102 N-Propylbenzene 120 9.260 9.257 0.003 99 105430 25.0 20.9
103 2-Chlorotoluene 126 9.363 9.360 0.003 97 100920 25.0 22.8
104 1,3,5-Trimethylbenzene 105 9.431 9.431 0.000 94 324298 25.0 20.4
105 4-Chlorotoluene 126 9.479 9.479 0.000 97 107761 25.0 22.9
106 Pentachloroethane 167 9.479 ND
107 tert-Butylbenzene 119 9.749 9.746 0.003 93 258432 25.0 18.7
108 1,2,4-Trimethylbenzene 105 9.807 9.804 0.003 97 345292 25.0 20.3
109 sec-Butylbenzene 134 9.968 9.968 0.000 94 67252 25.0 16.2
110 1,3-Dichlorobenzene 146 10.103 10.099 0.004 98 204709 25.0 21.5
111 4-Isopropyltoluene 119 10.115 10.112 0.003 97 304080 25.0 16.8
112 1,4-Dichlorobenzene 146 10.199 10.196 0.003 96 211665 25.0 23.2
113 1,2,3-Trimethylbenzene 105 10.218 ND
114 n-Butylbenzene 91 10.524 10.524 0.000 98 227177 25.0 13.2
115 1,2-Dichlorobenzene 146 10.562 10.559 0.003 98 208691 25.0 23.1
116 1,2-Dibromo-3-Chloropropane 157 11.347 11.344 0.003 87 68157 25.0 24.6
117 1,3,5-Trichlorobenzene 180 11.540 ND
118 1,2,4-Trichlorobenzene 180 12.180 12.180 0.000 94 115145 25.0 17.5
119 Hexachlorobutadiene 225 12.324 12.321 0.003 97 18736 25.0 6.79
120 Naphthalene 128 12.456 12.453 0.003 97 573345 25.0 22.2
121 1,2,3-Trichlorobenzene 180 12.681 12.678 0.003 97 115779 25.0 18.1
140 2-Methylhexane 1 0.000 ND
136 Butadiene 54 0.000 ND ND
132 2,2,3-Trimethylbutane 1 0.000 ND
142 4-Bromofluorobenzene 95 0.000 ND
149 Dimethyl disulfide 1 0.000 ND
125 Benzene, 1-bromo-4-ethyl- 1 0.000 ND
124 cis-1,4-Dichloro-2-butene TIC 1 0.000 ND
135 1,2-dichloro-4-(trifluoromethyl) 1 0.000 ND
130 Benzyl chloride 126 0.000 ND
129 3,3-Dimethylpentane 1 0.000 ND
126 t-Amyl alcohol 1 0.000 ND
137 1-Chloro-1-fluoroethane TIC 1 0.000 ND
150 4-Chlorobenzotrifluoride 1 0.000 ND
127 Pentachloroethane TIC 1 0.000 ND
138 Benzene, 1-bromo-3-fluoro- 1 0.000 ND
11/15/2024
3:53:55 PM
Page 746 of 777
Report Date: 11-Nov-2024 16:15:45 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004290.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
123 Ethyl acrylate 55 0.000 ND
148 n-Nonyl Aldehyde 1 0.000 ND
133 1,4-Dibromobenzene 1 0.000 ND
143 3-Ethylpentane 1 0.000 ND
122 Isooctane 57 0.000 ND
144 n-Butyl acetate 43 0.000 ND
145 1-Bromo-2-chloroethane 1 0.000 ND
134 1,3-Dibromobenzene 1 0.000 ND
139 2,2-Dimethylpentane 1 0.000 ND
141 Ethylene oxide TIC 1 0.000 ND
146 2,3-Dimethylpentane 1 0.000 ND
128 2,4-Dimethylpentane 1 0.000 ND
131 1-Chlorohexane TIC 1 0.000 ND
147 3-Methylhexane 1 0.000 ND
S 154 1,3-Dichloropropene, Total 1 0 50.0 43.6
S 153 TAH 1 0 0 7
S 156 Total BTEX 1 0 120.1
S 151 1,2-Dichloroethene, Total 1 0 50.0 48.5
S 152 Trihalomethanes, Total 1 0 100.0 85.5
S 155 Xylenes, Total 106 0 50.0 48.5
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
ND - Not Detected or Marked ND
7 - Failed Limit of Detection
Review Flags
U - Marked Undetected
Reagents:
MV-Gas A_00202 Amount Added: 5.00 Units: uL
MV-MegaMainA_00118 Amount Added: 12.50 Units: uL
mv-IS_SS_00089 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
3:53:55 PM
Page 747 of 777
Report Date: 11-Nov-2024 16:15:45 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004290.D
Injection Date:11-Nov-2024 13:37:49 Instrument ID:VMS_MS14 Operator ID:MED
Lims ID:280-198899-B-3 MS Worklist Smp#:32
Client ID:MW-63-241030
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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11/15/2024
3:53:55 PM
Page 748 of 777
Report Date: 11-Nov-2024 16:15:45 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004290.D
Lims ID:280-198899-B-3 MS
Client ID:MW-63-241030
Sample Type:MS
Inject. Date:11-Nov-2024 13:37:49 ALS Bottle#:0 Worklist Smp#:32
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:280-198899-B-3 MS
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:11-Nov-2024 16:14:22 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:11-Nov-2024 16:13:55
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 50.2 100.50
$5 1,2-Dichloroethane-d4 (Surr)50.0 45.0 89.93
$6 Toluene-d8 (Surr)50.0 53.0 106.00
$7 4-Bromofluorobenzene (Surr)50.0 46.5 93.02
11/15/2024
3:53:55 PM
Page 749 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:MW-63-241030 MSD Lab Sample ID:280-198899-3 MSD
Matrix:VMS14_0000004291.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
10/30/2024 12:20
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 13:57
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.14100-41-4 Ethylbenzene 24.2
1.0 0.13100-42-5 Styrene 24.9
1.0 0.1610061-01-5 cis-1,3-Dichloropropene 26.6
1.0 0.1410061-02-6 trans-1,3-Dichloropropene 20.9
1.0 0.18103-65-1 N-Propylbenzene 20.7
1.0 0.23104-51-8 n-Butylbenzene 13.0
1.0 0.21106-43-4 4-Chlorotoluene 23.1
1.0 0.39106-46-7 1,4-Dichlorobenzene 23.6
1.0 0.18106-93-4 Ethylene Dibromide 26.4
2.0 0.46107-05-1 3-Chloro-1-propene 23.2
1.0 0.28107-06-2 1,2-Dichloroethane 24.0
3.0 0.36108-05-4 Vinyl acetate 52.8
5.0 0.98108-10-1 4-Methyl-2-pentanone (MIBK)98.3
1.0 0.12108-67-8 1,3,5-Trimethylbenzene 20.5
1.0 0.19108-86-1 Bromobenzene 25.3
1.0 0.31108-87-2 Methylcyclohexane 13.3
1.0 0.32108-88-3 Toluene 25.9
1.0 0.092108-90-7 Chlorobenzene 25.3
7.0 0.84109-99-9 Tetrahydrofuran 48.4
2.0 0.16110-54-3 Hexane 13.6
1.0 0.44110-82-7 Cyclohexane 19.9
1.0 0.58120-82-1 1,2,4-Trichlorobenzene 17.2
1.0 0.28124-48-1 Chlorodibromomethane 23.1
1.0 0.40127-18-4 Tetrachloroethene 26.5
1.0 0.20135-98-8 sec-Butylbenzene 16.2
1.0 0.17142-28-9 1,3-Dichloropropane 25.2
1.0 0.32156-59-2 cis-1,2-Dichloroethene 26.6
1.0 0.37156-60-5 trans-1,2-Dichloroethene 26.8
5.0 0.251634-04-4 Methyl tert-butyl ether 26.5
2.0 0.36179601-23-1 m-Xylene & p-Xylene 25.3
1.0 0.33541-73-1 1,3-Dichlorobenzene 21.8
1.0 0.2356-23-5 Carbon tetrachloride 24.9
FORM I 8260D
11/15/2024
3:53:55 PM
Page 750 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:MW-63-241030 MSD Lab Sample ID:280-198899-3 MSD
Matrix:VMS14_0000004291.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
10/30/2024 12:20
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 13:57
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.19563-58-6 1,1-Dichloropropene 24.2
5.0 0.81591-78-6 2-Hexanone 102
1.0 0.17594-20-7 2,2-Dichloropropane 24.0
2.0 0.3560-29-7 Ethyl ether 26.8
1.0 0.16630-20-6 1,1,1,2-Tetrachloroethane 26.0
15 6.667-64-1 Acetone 96.3
1.0 0.3667-66-3 Chloroform 26.1
1.0 0.1471-43-2 Benzene 26.2
1.0 0.3971-55-6 1,1,1-Trichloroethane 25.2
5.0 2.474-83-9 Bromomethane 29.3
2.0 0.2374-87-3 Chloromethane 27.6
5.0 2.674-88-4 Iodomethane 31.7
1.0 0.3474-95-3 Dibromomethane 25.1
1.0 0.4074-97-5 Chlorobromomethane 28.2
2.0 0.6475-00-3 Chloroethane 26.7
1.0 0.2375-01-4 Vinyl chloride 26.6
2.0 0.9475-09-2 Methylene Chloride 25.8
2.0 0.2675-15-0 Carbon disulfide 26.6
2.0 0.2575-25-2 Bromoform 22.3
1.0 0.1975-27-4 Dichlorobromomethane 22.5
1.0 0.2275-34-3 1,1-Dichloroethane 26.6
1.0 0.2375-35-4 1,1-Dichloroethene 25.3
2.0 0.2075-69-4 Trichlorofluoromethane 24.6
2.0 0.3075-71-8 Dichlorodifluoromethane 22.4
3.0 0.7376-13-1 1,1,2-Trichloro-1,2,2-trifluoroethan
e
25.4
1.0 0.2478-87-5 1,2-Dichloropropane 25.2
10 4.678-93-3 2-Butanone (MEK)98.1
1.0 0.2779-00-5 1,1,2-Trichloroethane 24.8
1.0 0.3079-01-6 Trichloroethene 24.8
5.0 1.679-20-9 Methyl acetate 46.6
1.0 0.2179-34-5 1,1,2,2-Tetrachloroethane 27.4
4.0 1.287-61-6 1,2,3-Trichlorobenzene 17.5
FORM I 8260D
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Page 751 of 777
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-198899-1Eurofins Denver
SDG No.:
Client Sample ID:MW-63-241030 MSD Lab Sample ID:280-198899-3 MSD
Matrix:VMS14_0000004291.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
10/30/2024 12:20
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:11/11/2024 13:57
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:674451 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
2.0 0.5387-68-3 Hexachlorobutadiene 6.45
3.0 0.9991-20-3 Naphthalene 22.2
1.0 0.1195-47-6 o-Xylene 24.6
1.0 0.3495-49-8 2-Chlorotoluene 22.9
1.0 0.1495-50-1 1,2-Dichlorobenzene 23.3
1.0 0.1595-63-6 1,2,4-Trimethylbenzene 20.9
5.0 0.4296-12-8 1,2-Dibromo-3-Chloropropane 24.9
2.5 0.2896-18-4 1,2,3-Trichloropropane 26.9
3.0 0.1997-63-2 Ethyl methacrylate 25.7
1.0 0.1898-06-6 tert-Butylbenzene 18.6
1.0 0.1698-82-8 Isopropylbenzene 21.7
1.0 0.1999-87-6 4-Isopropyltoluene 16.5
1.0 0.111330-20-7 Xylenes, Total 49.9
1.0 0.32540-59-0 1,2-Dichloroethene, Total 53.4
1.0 0.14542-75-6 1,3-Dichloropropene, Total 47.5
1.0 0.19STL00209Trihalomethanes, Total 94.0
1.0 0.14STL00431Total BTEX 126
%RECCAS NO.LIMITSQSURROGATE
92 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr)
101 77-1201868-53-7 Dibromofluoromethane (Surr)
105 80-1252037-26-5 Toluene-d8 (Surr)
91 78-120460-00-4 4-Bromofluorobenzene (Surr)
FORM I 8260D
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Page 752 of 777
Report Date: 11-Nov-2024 16:15:52 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004291.D
Lims ID:280-198899-B-3 MSD
Client ID:MW-63-241030
Sample Type:MSD
Inject. Date:11-Nov-2024 13:57:50 ALS Bottle#:0 Worklist Smp#:33
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:280-198899-B-3 MSD
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:11-Nov-2024 16:14:22 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:11-Nov-2024 16:14:22
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.357 0.003 99 910256 50.0 50.0
* 2 Chlorobenzene-d5 119 7.929 7.926 0.003 84 235709 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.170 10.173 -0.003 94 416980 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.842 4.839 0.003 93 223833 50.0 50.7
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 94 253205 50.0 45.9
$ 6 Toluene-d8 (Surr) 98 6.640 6.637 0.003 92 971341 50.0 52.3
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 91 361353 50.0 45.3
$ 8 BFB 95 9.032 9.032 0.000 82 361341 NR
9 Chlorotrifluoroethene 116 1.677 ND
10 Dichlorodifluoromethane 85 1.794 1.791 0.003 99 115207 25.0 22.4
11 Ethylene oxide 43 1.759 1.843 -0.084 74 3361 24.1
12 Chloromethane 50 1.974 1.974 0.000 99 186679 25.0 27.6
13 Vinyl chloride 62 2.087 2.090 -0.003 98 137468 25.0 26.6
14 2-Chloro-1,1,1-Trifluoroethane 118 2.110 ND
15 Bromomethane 94 2.395 2.389 0.006 90 98710 25.0 29.3
16 Chloroethane 64 2.495 2.489 0.006 99 85786 25.0 26.7
17 Dichlorofluoromethane 67 2.678 2.675 0.003 96 218635 25.0 27.0
18 Trichlorofluoromethane 101 2.714 2.711 0.003 98 135971 25.0 24.6
19 Propene oxide 58 2.738 ND
20 Ethanol 45 2.875 ND U
21 Ethyl ether 59 2.939 2.936 0.003 90 93840 25.0 26.8
22 Acrolein 56 3.055 3.055 0.000 100 471078 246.9 265.7
23 1,2-Dichloro-1,1,2-trifluoroetha 117 3.129 ND
25 1,1-Dichloroethene 96 3.145 3.138 0.007 97 83291 25.0 25.3
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.135 3.141 -0.006 82 56988 25.0 25.4
26 Acetone 43 3.161 3.164 -0.003 100 586484 100.0 96.3
27 1,1,1-Trifluoro-2,2-dichloroetha 83 3.213 ND
28 Isopropyl alcohol 45 3.257 ND U
29 Iodomethane 142 3.270 3.267 0.003 98 121669 25.0 31.7
30 Carbon disulfide 76 3.338 3.334 0.004 98 261499 25.0 26.6
31 Acetonitrile 41 3.379 ND
32 Methyl acetate 43 3.399 3.399 0.000 97 450637 50.0 46.6
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Report Date: 11-Nov-2024 16:15:52 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004291.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
33 3-Chloro-1-propene 41 3.421 3.418 0.003 94 131604 25.0 23.2
34 Methylene Chloride 84 3.518 3.518 0.000 90 119999 25.0 25.8
35 2-Methyl-2-propanol 59 3.572 3.579 -0.007 100 1068788 250.0 273.4
36 Acrylonitrile 53 3.688 3.688 0.000 100 1366184 250.0 265.4
37 Methyl tert-butyl ether 73 3.714 3.714 0.000 93 342466 25.0 26.5
38 trans-1,2-Dichloroethene 96 3.727 3.727 0.000 99 94005 25.0 26.8
39 Hexane 57 3.932 3.929 0.003 90 66765 25.0 13.6
40 Vinyl acetate 43 4.032 4.032 0.000 97 549761 50.0 52.8
42 1,1-Dichloroethane 63 4.058 4.055 0.003 96 166293 25.0 26.6
41 Isopropyl ether 87 4.055 ND
43 2-Chloro-1,3-butadiene 53 4.113 ND
44 Tert-butyl ethyl ether 59 4.325 ND
45 2-Butanone (MEK) 43 4.457 4.456 0.000 99 918929 100.0 98.1
46 Ethyl acetate 43 4.463 ND
47 cis-1,2-Dichloroethene 96 4.482 4.482 0.000 79 108496 25.0 26.6
48 2,2-Dichloropropane 77 4.495 4.495 0.000 84 116965 25.0 24.0
49 Propionitrile 54 4.505 ND U
50 sec-Butyl Alcohol 45 4.569 4.575 -0.006 99 1822044 600.0 667.1
51 Methacrylonitrile 41 4.617 ND
52 Chlorobromomethane 128 4.662 4.662 0.000 93 60189 25.0 28.2
53 Tetrahydrofuran 42 4.675 4.678 -0.003 87 274840 50.0 48.4
54 Chloroform 83 4.723 4.720 0.003 92 164277 25.0 26.1
55 1,1,1-Trichloroethane 97 4.874 4.871 0.003 97 123070 25.0 25.2
56 Cyclohexane 56 4.936 4.936 0.000 86 118481 25.0 19.9
57 1,1-Dichloropropene 75 4.990 4.987 0.003 98 125357 25.0 24.2
59 Carbon tetrachloride 117 4.993 4.990 0.003 61 90533 25.0 24.9
58 Isobutyl alcohol 41 5.000 5.003 -0.003 95 678013 625.0 662.9
60 Benzene 78 5.145 5.145 0.000 95 394408 25.0 26.2
61 1,2-Dichloroethane 62 5.170 5.167 0.003 97 129141 25.0 24.0
62 Tert-amyl methyl ether 73 5.209 ND
63 n-Heptane 43 5.331 5.328 0.003 90 36577 25.0 6.86
64 n-Butanol 56 5.502 ND
65 Trichloroethene 95 5.643 5.640 0.003 97 98235 25.0 24.8
66 2-Pentanone 43 5.743 5.743 0.000 99 973765 80.0 74.9
67 Methylcyclohexane 55 5.842 5.842 0.000 85 66199 25.0 13.3
68 Methyl methacrylate 100 5.846 ND
69 1,2-Dichloropropane 63 5.849 5.849 0.000 95 100704 25.0 25.2
70 1,4-Dioxane 88 5.903 5.903 0.000 91 138054 500.0 660.4
71 Dibromomethane 93 5.923 5.923 0.000 95 67036 25.0 25.1
72 Dichlorobromomethane 83 6.045 6.045 0.000 99 104941 25.0 22.5
73 2-Nitropropane 41 6.215 ND
74 2-Chloroethyl vinyl ether 63 6.247 ND ND
75 cis-1,3-Dichloropropene 75 6.402 6.402 0.000 98 153222 25.0 26.6
76 4-Methyl-2-pentanone (MIBK) 43 6.505 6.501 0.004 95 1073952 100.0 98.3
77 Toluene 91 6.698 6.694 0.004 99 445314 25.0 25.9
78 trans-1,3-Dichloropropene 75 6.868 6.868 0.000 91 137473 25.0 20.9
79 Ethyl methacrylate 69 6.887 6.884 0.003 88 193954 25.0 25.7
80 1,1,2-Trichloroethane 97 7.048 7.045 0.003 90 103485 25.0 24.8
81 Tetrahydrothiophene 60 7.051 ND
82 Tetrachloroethene 164 7.151 7.148 0.003 97 74660 25.0 26.5
83 1,3-Dichloropropane 76 7.199 7.196 0.003 87 179341 25.0 25.2
84 2-Hexanone 43 7.212 7.215 -0.003 94 967627 100.0 102.1
11/15/2024
3:53:55 PM
Page 754 of 777
Report Date: 11-Nov-2024 16:15:52 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004291.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
85 Chlorodibromomethane 129 7.392 7.392 0.000 90 82550 25.0 23.1
86 Ethylene Dibromide 107 7.518 7.514 0.004 97 115300 25.0 26.4
87 1-Chlorohexane 91 7.910 7.907 0.003 93 83946 20.0 15.7
88 Chlorobenzene 112 7.958 7.955 0.003 96 283551 25.0 25.3
89 1,1,1,2-Tetrachloroethane 131 8.026 8.022 0.004 94 87242 25.0 26.0
90 Ethylbenzene 106 8.032 8.029 0.003 98 143066 25.0 24.2
91 m-Xylene & p-Xylene 106 8.151 8.148 0.003 100 183832 25.0 25.3
92 o-Xylene 106 8.514 8.511 0.003 96 183824 25.0 24.6
93 Styrene 104 8.530 8.527 0.003 94 312626 25.0 24.9
94 Bromoform 173 8.714 8.710 0.004 97 61671 25.0 22.3
95 Isopropylbenzene 105 8.858 8.858 0.000 95 382163 25.0 21.7
96 cis-1,4-Dichloro-2-butene 53 8.855 8.907 -0.052 36 3825 1.48
97 Cyclohexanone 55 8.961 8.958 0.003 89 748562 750.0 785.9
98 1,1,2,2-Tetrachloroethane 83 9.141 9.141 0.000 94 187644 25.0 27.4
99 trans-1,4-Dichloro-2-butene 53 9.180 9.177 0.003 78 52715 25.0 19.7
100 Bromobenzene 156 9.183 9.186 -0.003 94 124320 25.0 25.3
101 1,2,3-Trichloropropane 110 9.209 9.209 0.000 83 72466 25.0 26.9
102 N-Propylbenzene 120 9.260 9.257 0.003 99 108916 25.0 20.7
103 2-Chlorotoluene 126 9.363 9.360 0.003 97 105155 25.0 22.9
104 1,3,5-Trimethylbenzene 105 9.431 9.431 0.000 95 340362 25.0 20.5
105 4-Chlorotoluene 126 9.476 9.479 -0.003 97 113071 25.0 23.1
106 Pentachloroethane 167 9.479 ND
107 tert-Butylbenzene 119 9.749 9.746 0.003 92 267467 25.0 18.6
108 1,2,4-Trimethylbenzene 105 9.807 9.804 0.003 97 369857 25.0 20.9
109 sec-Butylbenzene 134 9.971 9.968 0.003 94 69937 25.0 16.2
110 1,3-Dichlorobenzene 146 10.096 10.099 -0.003 98 215736 25.0 21.8
111 4-Isopropyltoluene 119 10.116 10.112 0.004 97 310098 25.0 16.5
112 1,4-Dichlorobenzene 146 10.202 10.196 0.006 96 223783 25.0 23.6
113 1,2,3-Trimethylbenzene 105 10.218 ND
114 n-Butylbenzene 91 10.524 10.524 0.000 98 233996 25.0 13.0
115 1,2-Dichlorobenzene 146 10.562 10.559 0.003 98 219133 25.0 23.3
116 1,2-Dibromo-3-Chloropropane 157 11.347 11.344 0.003 87 71810 25.0 24.9
117 1,3,5-Trichlorobenzene 180 11.540 ND
118 1,2,4-Trichlorobenzene 180 12.180 12.180 0.000 93 117687 25.0 17.2
119 Hexachlorobutadiene 225 12.321 12.321 0.000 95 18500 25.0 6.45
120 Naphthalene 128 12.456 12.453 0.003 97 598137 25.0 22.2
121 1,2,3-Trichlorobenzene 180 12.678 12.678 0.000 96 116538 25.0 17.5
140 2-Methylhexane 1 0.000 ND
136 Butadiene 54 0.000 ND ND
132 2,2,3-Trimethylbutane 1 0.000 ND
142 4-Bromofluorobenzene 95 0.000 ND
149 Dimethyl disulfide 1 0.000 ND
125 Benzene, 1-bromo-4-ethyl- 1 0.000 ND
124 cis-1,4-Dichloro-2-butene TIC 1 0.000 ND
135 1,2-dichloro-4-(trifluoromethyl) 1 0.000 ND
130 Benzyl chloride 126 0.000 ND
129 3,3-Dimethylpentane 1 0.000 ND
126 t-Amyl alcohol 1 0.000 ND
137 1-Chloro-1-fluoroethane TIC 1 0.000 ND
150 4-Chlorobenzotrifluoride 1 0.000 ND
127 Pentachloroethane TIC 1 0.000 ND
138 Benzene, 1-bromo-3-fluoro- 1 0.000 ND
11/15/2024
3:53:55 PM
Page 755 of 777
Report Date: 11-Nov-2024 16:15:52 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004291.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
123 Ethyl acrylate 55 0.000 ND
148 n-Nonyl Aldehyde 1 0.000 ND
133 1,4-Dibromobenzene 1 0.000 ND
143 3-Ethylpentane 1 0.000 ND
122 Isooctane 57 0.000 ND
144 n-Butyl acetate 43 0.000 ND
145 1-Bromo-2-chloroethane 1 0.000 ND
134 1,3-Dibromobenzene 1 0.000 ND
139 2,2-Dimethylpentane 1 0.000 ND
141 Ethylene oxide TIC 1 0.000 ND
146 2,3-Dimethylpentane 1 0.000 ND
128 2,4-Dimethylpentane 1 0.000 ND
131 1-Chlorohexane TIC 1 0.000 ND
147 3-Methylhexane 1 0.000 ND
S 154 1,3-Dichloropropene, Total 1 0 50.0 47.5
S 153 TAH 1 0 0 7
S 156 Total BTEX 1 0 126.1
S 151 1,2-Dichloroethene, Total 1 0 50.0 53.4
S 152 Trihalomethanes, Total 1 0 100.0 93.9
S 155 Xylenes, Total 106 0 50.0 49.8
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
ND - Not Detected or Marked ND
7 - Failed Limit of Detection
Review Flags
U - Marked Undetected
Reagents:
MV-Gas A_00202 Amount Added: 5.00 Units: uL
MV-MegaMainA_00118 Amount Added: 12.50 Units: uL
mv-IS_SS_00089 Amount Added: 5.00 Units: uL Run Reagent
11/15/2024
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Page 756 of 777
Report Date: 11-Nov-2024 16:15:52 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004291.D
Injection Date:11-Nov-2024 13:57:50 Instrument ID:VMS_MS14 Operator ID:MED
Lims ID:280-198899-B-3 MSD Worklist Smp#:33
Client ID:MW-63-241030
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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11/15/2024
3:53:55 PM
Page 757 of 777
Report Date: 11-Nov-2024 16:15:52 Chrom Revision: 2.3 17-Oct-2024 11:42:22
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\VMS14_0000004291.D
Lims ID:280-198899-B-3 MSD
Client ID:MW-63-241030
Sample Type:MSD
Inject. Date:11-Nov-2024 13:57:50 ALS Bottle#:0 Worklist Smp#:33
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:280-198899-B-3 MSD
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241111-139630.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:11-Nov-2024 16:14:22 Calib Date:29-Oct-2024 19:42:16
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241029-139171.b\VMS14_0000003780.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1692
First Level Reviewer: LP8K Date:11-Nov-2024 16:14:22
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 50.7 101.46
$5 1,2-Dichloroethane-d4 (Surr)50.0 45.9 91.90
$6 Toluene-d8 (Surr)50.0 52.3 104.57
$7 4-Bromofluorobenzene (Surr)50.0 45.3 90.58
11/15/2024
3:53:55 PM
Page 758 of 777
Lab Name:Job No.:
GC/MS VOA ANALYSIS RUN LOG
Eurofins Denver 280-198899-1
SDG No.:
Instrument ID:
Analysis Batch Number:
DILUTION
FACTOR
COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID
VMS_MS14
664080
Start Date:
End Date:08/15/2024 01:28
08/14/2024 16:57
BFB 280-664080/1 DB-624 (60.25) 0.25(mm)108/14/2024 16:57 VMS14_0000000565.D
IC 280-664080/38 DB-624 (60.25) 0.25(mm)108/14/2024 18:10
IC 280-664080/39 DB-624 (60.25) 0.25(mm)108/14/2024 18:29
IC 280-664080/40 DB-624 (60.25) 0.25(mm)108/14/2024 18:49
IC 280-664080/41 DB-624 (60.25) 0.25(mm)108/14/2024 19:09
IC 280-664080/42 DB-624 (60.25) 0.25(mm)108/14/2024 19:29
ICIS 280-664080/43 DB-624 (60.25) 0.25(mm)108/14/2024 19:49
IC 280-664080/44 DB-624 (60.25) 0.25(mm)108/14/2024 20:09
IC 280-664080/45 DB-624 (60.25) 0.25(mm)108/14/2024 20:29
IC 280-664080/46 DB-624 (60.25) 0.25(mm)108/14/2024 20:49
ICV 280-664080/47 DB-624 (60.25) 0.25(mm)108/14/2024 21:29
IC 280-664080/49 DB-624 (60.25) 0.25(mm)108/14/2024 22:29
IC 280-664080/50 DB-624 (60.25) 0.25(mm)108/14/2024 22:49
IC 280-664080/51 DB-624 (60.25) 0.25(mm)108/14/2024 23:09
IC 280-664080/52 DB-624 (60.25) 0.25(mm)108/14/2024 23:29
IC 280-664080/53 DB-624 (60.25) 0.25(mm)108/14/2024 23:48
IC 280-664080/54 DB-624 (60.25) 0.25(mm)108/15/2024 00:08
IC 280-664080/55 DB-624 (60.25) 0.25(mm)108/15/2024 00:28
IC 280-664080/56 DB-624 (60.25) 0.25(mm)108/15/2024 00:48
ICV 280-664080/57 DB-624 (60.25) 0.25(mm)108/15/2024 01:28 VMS14_0000000589.D
8260D
11/15/2024
3:53:55 PM
Page 759 of 777
Lab Name:Job No.:
GC/MS VOA ANALYSIS RUN LOG
Eurofins Denver 280-198899-1
SDG No.:
Instrument ID:
Analysis Batch Number:
DILUTION
FACTOR
COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID
VMS_X4
668235
Start Date:
End Date:09/23/2024 14:12
09/23/2024 06:22
BFB 280-668235/1 RXI-624SilMS 0.25(mm)109/23/2024 06:22 X4_00006833.D
ZZZZZ (QC)RXI-624SilMS 0.25(mm)109/23/2024 11:03
ZZZZZ (QC)RXI-624SilMS 0.25(mm)109/23/2024 11:03
IC 280-668235/13 RXI-624SilMS 0.25(mm)109/23/2024 11:24
ZZZZZ (QC)RXI-624SilMS 0.25(mm)109/23/2024 11:24
ZZZZZ (QC)RXI-624SilMS 0.25(mm)109/23/2024 11:24
IC 280-668235/14 RXI-624SilMS 0.25(mm)109/23/2024 11:45
ZZZZZ (QC)RXI-624SilMS 0.25(mm)109/23/2024 11:45
ZZZZZ (QC)RXI-624SilMS 0.25(mm)109/23/2024 11:45
IC 280-668235/15 RXI-624SilMS 0.25(mm)109/23/2024 12:06
ZZZZZ (QC)RXI-624SilMS 0.25(mm)109/23/2024 12:06
ZZZZZ (QC)RXI-624SilMS 0.25(mm)109/23/2024 12:06
IC 280-668235/16 RXI-624SilMS 0.25(mm)109/23/2024 12:27
ZZZZZ (QC)RXI-624SilMS 0.25(mm)109/23/2024 12:27
ZZZZZ (QC)RXI-624SilMS 0.25(mm)109/23/2024 12:27
IC 280-668235/17 RXI-624SilMS 0.25(mm)109/23/2024 12:48
IC 280-668235/18 RXI-624SilMS 0.25(mm)109/23/2024 13:09
IC 280-668235/19 RXI-624SilMS 0.25(mm)109/23/2024 13:30
IC 280-668235/20 RXI-624SilMS 0.25(mm)109/23/2024 13:51
ICV 280-668235/21 RXI-624SilMS 0.25(mm)109/23/2024 14:12 X4_00006851.D
8260D
11/15/2024
3:53:55 PM
Page 760 of 777
Lab Name:Job No.:
GC/MS VOA ANALYSIS RUN LOG
Eurofins Denver 280-198899-1
SDG No.:
Instrument ID:
Analysis Batch Number:
DILUTION
FACTOR
COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID
VMS_X4
672931
Start Date:
End Date:10/29/2024 20:20
10/29/2024 16:50
BFB 280-672931/1 RXI-624SilMS 0.25(mm)110/29/2024 16:50 X4_00008660.D
IC 280-672931/35 RXI-624SilMS 0.25(mm)110/29/2024 17:11 X4_00008661.D
IC 280-672931/36 RXI-624SilMS 0.25(mm)110/29/2024 17:32 X4_00008662.D
IC 280-672931/37 RXI-624SilMS 0.25(mm)110/29/2024 17:53 X4_00008663.D
ICIS 280-672931/38 RXI-624SilMS 0.25(mm)110/29/2024 18:14 X4_00008664.D
IC 280-672931/39 RXI-624SilMS 0.25(mm)110/29/2024 18:35 X4_00008665.D
IC 280-672931/40 RXI-624SilMS 0.25(mm)110/29/2024 18:56 X4_00008666.D
IC 280-672931/41 RXI-624SilMS 0.25(mm)110/29/2024 19:17 X4_00008667.D
IC 280-672931/42 RXI-624SilMS 0.25(mm)110/29/2024 19:38 X4_00008668.D
IC 280-672931/43 RXI-624SilMS 0.25(mm)110/29/2024 20:00 X4_00008669.D
ICV 280-672931/44 RXI-624SilMS 0.25(mm)110/29/2024 20:20 X4_00008670.D
8260D
11/15/2024
3:53:55 PM
Page 761 of 777
Lab Name:Job No.:
GC/MS VOA ANALYSIS RUN LOG
Eurofins Denver 280-198899-1
SDG No.:
Instrument ID:
Analysis Batch Number:
DILUTION
FACTOR
COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID
VMS_MS14
672942
Start Date:
End Date:10/29/2024 20:02
10/29/2024 16:42
BFB 280-672942/1 DB-624 (60.25) 0.25(mm)110/29/2024 16:42 VMS14_0000003771.D
IC 280-672942/36 DB-624 (60.25) 0.25(mm)110/29/2024 17:02 VMS14_0000003772.D
IC 280-672942/37 DB-624 (60.25) 0.25(mm)110/29/2024 17:22 VMS14_0000003773.D
IC 280-672942/38 DB-624 (60.25) 0.25(mm)110/29/2024 17:42 VMS14_0000003774.D
ICIS 280-672942/39 DB-624 (60.25) 0.25(mm)110/29/2024 18:02 VMS14_0000003775.D
IC 280-672942/40 DB-624 (60.25) 0.25(mm)110/29/2024 18:22 VMS14_0000003776.D
IC 280-672942/41 DB-624 (60.25) 0.25(mm)110/29/2024 18:42 VMS14_0000003777.D
IC 280-672942/42 DB-624 (60.25) 0.25(mm)110/29/2024 19:02 VMS14_0000003778.D
IC 280-672942/43 DB-624 (60.25) 0.25(mm)110/29/2024 19:22 VMS14_0000003779.D
IC 280-672942/44 DB-624 (60.25) 0.25(mm)110/29/2024 19:42 VMS14_0000003780.D
ICV 280-672942/45 DB-624 (60.25) 0.25(mm)110/29/2024 20:02 VMS14_0000003781.D
8260D
11/15/2024
3:53:55 PM
Page 762 of 777
Lab Name:Job No.:
GC/MS VOA ANALYSIS RUN LOG
Eurofins Denver 280-198899-1
SDG No.:
Instrument ID:
Analysis Batch Number:
DILUTION
FACTOR
COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID
VMS_MS14
674451
Start Date:
End Date:11/11/2024 14:37
11/11/2024 04:41
BFB 280-674451/1 DB-624 (60.25) 0.25(mm)111/11/2024 04:41 VMS14_0000004264A.D
CCV 280-674451/3 DB-624 (60.25) 0.25(mm)111/11/2024 04:41
ZZZZZ (QC)DB-624 (60.25) 0.25(mm)111/11/2024 04:41
CCV 280-674451/2 DB-624 (60.25) 0.25(mm)111/11/2024 05:00 VMS14_0000004265.D
LCS 280-674451/4 DB-624 (60.25) 0.25(mm)111/11/2024 05:00 VMS14_0000004265A.D
LCSD 280-674451/5 DB-624 (60.25) 0.25(mm)111/11/2024 05:40 VMS14_0000004267.D
ZZZZZ (QC)DB-624 (60.25) 0.25(mm)111/11/2024 06:00
MB 280-674451/9 DB-624 (60.25) 0.25(mm)111/11/2024 06:40 VMS14_0000004270.D
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)111/11/2024 07:04
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)111/11/2024 07:24
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)111/11/2024 07:44
280-198899-6 Trip Blank DB-624 (60.25) 0.25(mm)111/11/2024 08:04 VMS14_0000004274.D
280-198899-4 FB-01 DB-624 (60.25) 0.25(mm)111/11/2024 08:24 VMS14_0000004275.D
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)111/11/2024 08:44
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)111/11/2024 09:05
280-198899-3 MW-63-241030 DB-624 (60.25) 0.25(mm)111/11/2024 09:25 VMS14_0000004278.D
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)111/11/2024 09:45
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)111/11/2024 10:05
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)111/11/2024 10:25
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)111/11/2024 10:45
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)111/11/2024 11:05
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)111/11/2024 11:28
280-198899-5 DS-01 DB-624 (60.25) 0.25(mm)10011/11/2024 11:50 VMS14_0000004285.D
280-198899-2 MW-61-241030 DB-624 (60.25) 0.25(mm)5011/11/2024 12:12 VMS14_0000004286.D
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)1011/11/2024 12:34
ZZZZZ (QC)DB-624 (60.25) 0.25(mm)111/11/2024 12:57
ZZZZZ (QC)DB-624 (60.25) 0.25(mm)111/11/2024 13:17
280-198899-3 MS MW-63-241030 MS DB-624 (60.25) 0.25(mm)111/11/2024 13:37 VMS14_0000004290.D
280-198899-3 MSD MW-63-241030 MSD DB-624 (60.25) 0.25(mm)111/11/2024 13:57 VMS14_0000004291.D
CCVC 280-674451/35 DB-624 (60.25) 0.25(mm)111/11/2024 14:17
CCVC 280-674451/36 DB-624 (60.25) 0.25(mm)111/11/2024 14:37
8260D
11/15/2024
3:53:55 PM
Page 763 of 777
Lab Name:Job No.:
GC/MS VOA ANALYSIS RUN LOG
Eurofins Denver 280-198899-1
SDG No.:
Instrument ID:
Analysis Batch Number:
DILUTION
FACTOR
COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID
VMS_X4
674813
Start Date:
End Date:11/13/2024 16:59
11/13/2024 06:26
BFB 280-674813/1 RXI-624SilMS 0.25(mm)111/13/2024 06:26 X4_00009394.D
CCV 280-674813/3 RXI-624SilMS 0.25(mm)111/13/2024 06:59
ZZZZZ (QC)RXI-624SilMS 0.25(mm)111/13/2024 06:59
CCV 280-674813/2 RXI-624SilMS 0.25(mm)111/13/2024 07:20 X4_00009396.D
LCS 280-674813/4 RXI-624SilMS 0.25(mm)111/13/2024 07:20 X4_00009396a.D
ZZZZZ (QC)RXI-624SilMS 0.25(mm)111/13/2024 07:41
LCSD 280-674813/5 RXI-624SilMS 0.25(mm)111/13/2024 08:02 X4_00009398.D
MB 280-674813/9 RXI-624SilMS 0.25(mm)111/13/2024 09:05 X4_00009401.D
ZZZZZ (Client)RXI-624SilMS 0.25(mm)111/13/2024 09:34
ZZZZZ (Client)RXI-624SilMS 0.25(mm)111/13/2024 09:55
ZZZZZ (Client)RXI-624SilMS 0.25(mm)111/13/2024 10:17
ZZZZZ (Client)RXI-624SilMS 0.25(mm)111/13/2024 10:38
ZZZZZ (Client)RXI-624SilMS 0.25(mm)111/13/2024 10:59
ZZZZZ (Client)RXI-624SilMS 0.25(mm)111/13/2024 11:20
ZZZZZ (Client)RXI-624SilMS 0.25(mm)111/13/2024 11:41
ZZZZZ (Client)RXI-624SilMS 0.25(mm)111/13/2024 12:02
ZZZZZ (Client)RXI-624SilMS 0.25(mm)111/13/2024 12:23
ZZZZZ (Client)RXI-624SilMS 0.25(mm)111/13/2024 12:44
ZZZZZ (Client)RXI-624SilMS 0.25(mm)111/13/2024 13:05
ZZZZZ (Client)RXI-624SilMS 0.25(mm)111/13/2024 13:27
ZZZZZ (Client)RXI-624SilMS 0.25(mm)111/13/2024 13:48
ZZZZZ (Client)RXI-624SilMS 0.25(mm)111/13/2024 14:09
ZZZZZ (Client)RXI-624SilMS 0.25(mm)111/13/2024 14:30
ZZZZZ (Client)RXI-624SilMS 0.25(mm)111/13/2024 14:51
ZZZZZ (Client)RXI-624SilMS 0.25(mm)211/13/2024 15:13
280-198899-5 DL DS-01 DL RXI-624SilMS 0.25(mm)50011/13/2024 15:34 X4_00009419.D
ZZZZZ (QC)RXI-624SilMS 0.25(mm)111/13/2024 15:55
ZZZZZ (QC)RXI-624SilMS 0.25(mm)111/13/2024 16:16
CCVC 280-674813/33 RXI-624SilMS 0.25(mm)111/13/2024 16:37
CCVC 280-674813/34 RXI-624SilMS 0.25(mm)111/13/2024 16:59
8260D
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3:53:55 PM
Page 764 of 777
Lab Name:Job No.:
SDG No.:
GC/MS VOA BATCH WORKSHEET
280-198899-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Dobransky, Michael E08/14/24 16:57664080
Batch Method:
Eurofins Denver
8260D
Lab Sample ID Client Sample
ID
Method Chain Basis InitialAmount FinalAmount mv-Cent BFB
00008
mv-Cent IS
00009
MV-Supp B
00073
Matrix
2 uL 2 uL 5 uL8260DBFB
280-664080/1
5 mL 5 mL 5 uL 50 uL8260DICV
280-664080/57
Batch Notes
Basis Basis Description
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
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Page 765 of 777
Lab Name:Job No.:
SDG No.:
GC/MS VOA BATCH WORKSHEET
280-198899-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Wickham, Tom A09/23/24 06:22668235
Batch Method:
Eurofins Denver
8260D
Lab Sample ID Client Sample
ID
Method Chain Basis InitialAmount FinalAmount mv-Cent BFB
00008
mv-Cent IS
00009
MV-Supp B
00074
Matrix
2 uL 2 uL 5 uL8260DBFB
280-668235/1
5 mL 5 mL 5 uL 25 uL8260DICV
280-668235/21
Batch Notes
Basis Basis Description
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 18260D
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Page 766 of 777
Lab Name:Job No.:
SDG No.:
GC/MS VOA BATCH WORKSHEET
280-198899-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Fogg, Cameron C10/29/24 16:50672931
Batch Method:
Eurofins Denver
8260D
Lab Sample ID Client Sample
ID
Method Chain Basis InitialAmount FinalAmount Cal Dil Std
00426
mv-Cent BFB
00008
MV-Gas A 00200 MV-Gas B 00174Matrix
2 uL 2 uL 5 uL8260DBFB
280-672931/1
5 mL 5 mL 40 uL8260DIC
280-672931/35
5 mL 5 mL 20 uL8260DIC
280-672931/36
5 mL 5 mL 15 uL8260DIC
280-672931/37
5 mL 5 mL 10 uL8260DICIS
280-672931/38
5 mL 5 mL 2 uL8260DIC
280-672931/39
5 mL 5 mL 1 uL8260DIC
280-672931/40
5 mL 5 mL 20 uL8260DIC
280-672931/41
5 mL 5 mL 10 uL8260DIC
280-672931/42
5 mL 5 mL 5 uL8260DIC
280-672931/43
5 mL 5 mL 10 uL8260DICV
280-672931/44
Lab Sample ID Client Sample
ID
Method Chain Basis mv-IS_SS 00086 MV-MegaMain B
00111
MV-MegaMainA
00117
Matrix
8260DBFB
280-672931/1
5 uL 100 uL8260DIC
280-672931/35
5 uL 50 uL8260DIC
280-672931/36
5 uL 37.5 uL8260DIC
280-672931/37
5 uL 25 uL8260DICIS
280-672931/38
5 uL 5 uL8260DIC
280-672931/39
5 uL 2.5 uL8260DIC
280-672931/40
5 uL8260DIC
280-672931/41
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 28260D
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Page 767 of 777
Lab Name:Job No.:
SDG No.:
GC/MS VOA BATCH WORKSHEET
280-198899-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Fogg, Cameron C10/29/24 16:50672931
Batch Method:
Eurofins Denver
8260D
Lab Sample ID Client Sample
ID
Method Chain Basis mv-IS_SS 00086 MV-MegaMain B
00111
MV-MegaMainA
00117
Matrix
5 uL8260DIC
280-672931/42
5 uL8260DIC
280-672931/43
5 uL 25 uL8260DICV
280-672931/44
Batch Notes
Basis Basis Description
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 2 of 28260D
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Page 768 of 777
Lab Name:Job No.:
SDG No.:
GC/MS VOA BATCH WORKSHEET
280-198899-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Bustillos, Ethan T10/29/24 16:42672942
Batch Method:
Eurofins Denver
8260D
Lab Sample ID Client Sample
ID
Method Chain Basis InitialAmount FinalAmount Cal Dil Std
00424
mv-Cent BFB
00008
MV-Gas A 00201 MV-Gas B 00174Matrix
2 uL 2 uL 5 uL8260DBFB
280-672942/1
5 mL 5 mL 40 uL8260DIC
280-672942/36
5 mL 5 mL 20 uL8260DIC
280-672942/37
5 mL 5 mL 15 uL8260DIC
280-672942/38
5 mL 5 mL 10 uL8260DICIS
280-672942/39
5 mL 5 mL 2 uL8260DIC
280-672942/40
5 mL 5 mL 50 uL8260DIC
280-672942/41
5 mL 5 mL 20 uL8260DIC
280-672942/42
5 mL 5 mL 10 uL8260DIC
280-672942/43
5 mL 5 mL 5 uL8260DIC
280-672942/44
5 mL 5 mL 10 uL8260DICV
280-672942/45
Lab Sample ID Client Sample
ID
Method Chain Basis mv-IS_SS 00089 MV-MegaMain B
00111
MV-MegaMainA
00118
Matrix
8260DBFB
280-672942/1
5 uL 100 uL8260DIC
280-672942/36
5 uL 50 uL8260DIC
280-672942/37
5 uL 37.5 uL8260DIC
280-672942/38
5 uL 25 uL8260DICIS
280-672942/39
5 uL 5 uL8260DIC
280-672942/40
5 uL8260DIC
280-672942/41
5 uL8260DIC
280-672942/42
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 28260D
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Page 769 of 777
Lab Name:Job No.:
SDG No.:
GC/MS VOA BATCH WORKSHEET
280-198899-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Bustillos, Ethan T10/29/24 16:42672942
Batch Method:
Eurofins Denver
8260D
Lab Sample ID Client Sample
ID
Method Chain Basis mv-IS_SS 00089 MV-MegaMain B
00111
MV-MegaMainA
00118
Matrix
5 uL8260DIC
280-672942/43
5 uL8260DIC
280-672942/44
5 uL 25 uL8260DICV
280-672942/45
Batch Notes
Basis Basis Description
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 2 of 28260D
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Page 770 of 777
Lab Name:Job No.:
SDG No.:
GC/MS VOA BATCH WORKSHEET
280-198899-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Dobransky, Michael E11/11/24 04:41674451
Batch Method:
Eurofins Denver
8260D
Lab Sample ID Client Sample
ID
Method Chain Basis InitialAmount FinalAmount Initial pH Headspace mv-Cent BFB
00008
MV-Gas A 00202Matrix
2 uL 2 uL 5 uL8260DBFB
280-674451/1
5 mL 5 mL 10 uL8260DCCV
280-674451/2
5 mL 5 mL 10 uL8260DLCS
280-674451/4
5 mL 5 mL 10 uL8260DLCSD
280-674451/5
5 mL 5 mL8260DMB 280-674451/9
Trip Blank 5 mL 5 mL <2 SU No8260DT280-198899-B-6 Water
FB-01 5 mL 5 mL <2 SU No8260DT280-198899-B-4 Water
MW-63-241030 5 mL 5 mL <2 SU No8260DT280-198899-B-3 Water
DS-01 5 mL 5 mL <2 SU No8260DT280-198899-B-5 Water
MW-61-241030 5 mL 5 mL <2 SU No8260DT280-198899-B-2 Water
MW-63-241030 5 mL 5 mL <2 SU No 5 uL8260DT280-198899-B-3
MS
Water
MW-63-241030 5 mL 5 mL <2 SU No 5 uL8260DT280-198899-B-3
MSD
Water
Lab Sample ID Client Sample
ID
Method Chain Basis mv-IS_SS 00089 MV-MegaMainA
00118
Matrix
8260DBFB
280-674451/1
5 uL 25 uL8260DCCV
280-674451/2
5 uL 25 uL8260DLCS
280-674451/4
5 uL 25 uL8260DLCSD
280-674451/5
5 uL8260DMB 280-674451/9
Trip Blank 5 uL8260DT280-198899-B-6 Water
FB-01 5 uL8260DT280-198899-B-4 Water
MW-63-241030 5 uL8260DT280-198899-B-3 Water
DS-01 5 uL8260DT280-198899-B-5 Water
MW-61-241030 5 uL8260DT280-198899-B-2 Water
MW-63-241030 5 uL 12.5 uL8260DT280-198899-B-3
MS
Water
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 28260D
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Page 771 of 777
Lab Name:Job No.:
SDG No.:
GC/MS VOA BATCH WORKSHEET
280-198899-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Dobransky, Michael E11/11/24 04:41674451
Batch Method:
Eurofins Denver
8260D
Lab Sample ID Client Sample
ID
Method Chain Basis mv-IS_SS 00089 MV-MegaMainA
00118
Matrix
MW-63-241030 5 uL 12.5 uL8260DT280-198899-B-3
MSD
Water
Batch Notes
Basis Basis Description
T Total/NA
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 2 of 28260D
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Page 772 of 777
Lab Name:Job No.:
SDG No.:
GC/MS VOA BATCH WORKSHEET
280-198899-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Wickham, Tom A11/13/24 06:26674813
Batch Method:
Eurofins Denver
8260D
Lab Sample ID Client Sample
ID
Method Chain Basis InitialAmount FinalAmount Headspace mv-Cent BFB
00008
MV-Gas A 00202 mv-IS_SS 00086Matrix
2 uL 2 uL 5 uL8260DBFB
280-674813/1
5 mL 5 mL 10 uL 5 uL8260DCCV
280-674813/2
5 mL 5 mL 10 uL 5 uL8260DLCS
280-674813/4
5 mL 5 mL 10 uL 5 uL8260DLCSD
280-674813/5
5 mL 5 mL 5 uL8260DMB 280-674813/9
DS-01 5 mL 5 mL yes 5 uL8260DT280-198899-A-5 Water
Lab Sample ID Client Sample
ID
Method Chain Basis MV-MegaMainA
00118
Matrix
8260DBFB
280-674813/1
25 uL8260DCCV
280-674813/2
25 uL8260DLCS
280-674813/4
25 uL8260DLCSD
280-674813/5
8260DMB 280-674813/9
DS-01 8260D T280-198899-A-5 Water
Batch Notes
Basis Basis Description
T Total/NA
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 18260D
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Page 773 of 777
Shipping and
Receiving
Documents
11/15/2024
3:53:55 PM
Page 774 of 777
11/15/2024
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Page 775 of 777
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Page 776 of 777
Login Sample Receipt Checklist
Client: Ramboll Americas Engineering Solutions Job Number: 280-198899-1
Login Number: 198899
Question Answer Comment
Creator: Held, Wesley
List Source: Eurofins Denver
List Number: 1
N/ARadioactivity wasn't checked or is </= background as measured by a survey
meter.
TrueThe cooler's custody seal, if present, is intact.
TrueSample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or
tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
FalseThere are no discrepancies between the containers received and the COC.Received Trip Blank(s) not listed on COC.
TrueSamples are received within Holding Time (excluding tests with immediate
HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
N/ASample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
TrueContainers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
Eurofins Denver 11/15/2024
3:53:55 PM
Page 777 of 777
ANALYTICAL REPORT
PREPARED FOR
Attn: Charles Goodwin
Ramboll Americas Engineering Solutions
1999 Broadway
Suite 2225
Denver CO 80202
Generated 12/27/2024 9:26 AM
JOB DESCRIPTION
Moog-SLC, UT
JOB NUMBER
280-201015-1
See page two for job notes and contact information.
Arvada CO 80002
4955 Yarrow Street
Eurofins Denver
Page 1 of 428
Eurofins Denver
Eurofins Denver is a laboratory within TestAmerica Laboratories, Inc., a company within Eurofins Environment Testing Group of Companies
Job Notes
This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the
samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this
page.
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the
methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written
approval of the laboratory. All questions should be directed to the Eurofins TestAmerica Project Manager.
Authorization
Generated
12/27/2024 9:26 AM
Authorized for release by
Dylan T Bieniulis, Project Manager I
[e-mail]
303 736-0138
12/27/2024
9:26:49 AM
Page 2 of 428
Table of Contents
Cover Title Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Data Summaries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6
Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .8
Default Detection Limits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .16
Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .18
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .19
QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .25
Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .26
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .27
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .28
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .29
Manual Integration Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .30
Reagent Traceability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .35
COAs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .50
Organic Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .111
GC/MS VOA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .111
8260D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .111
8260D QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .112
8260D Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .122
Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .175
8260D ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .175
8260D CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .366
Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .380
12/27/2024
9:26:49 AM
Page 3 of 428
Table of Contents
8260D Tune Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .380
8260D Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .392
8260D LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .402
8260D Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .418
8260D Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .421
Shipping and Receiving Documents . . . . . . . . . . . . . . . . . . . . . . . . . . .426
Client Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .427
Sample Receipt Checklist . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .428
12/27/2024
9:26:49 AM
Page 4 of 428
Definitions/Glossary
Job ID: 280-201015-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Qualifiers
GC/MS VOA
Qualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Qualifier
Glossary
These commonly used abbreviations may or may not be present in this report.
☼Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins Denver
12/27/2024
9:26:49 AM
Page 5 of 428
Job Narrative
280-201015-1
Analytical test results meet all requirements of the associated regulatory program listed on the
Accreditation/Certification Summary Page unless otherwise noted under the individual analysis.Data qualifiers and/or
narrative comments are included to explain any exceptions,if applicable.
Matrix QC may not be reported if insufficient sample is provided or site-specific QC samples were not
submitted.In these situations,to demonstrate precision and accuracy at a batch level,a LCS/LCSD may be
performed,unless otherwise specified in the method.
Surrogate and/or isotope dilution analyte recoveries (if applicable)which are outside of the QC window are
confirmed unless attributed to a dilution or otherwise noted in the narrative.
Regulated compliance samples (e.g.SDWA,NPDES)must comply with the associated agency requirements/permits.
Receipt
The samples were received on 12/18/2024 9:45 AM.Unless otherwise noted below,the samples arrived in good
condition,and,where required,properly preserved and on ice.The temperature of the cooler at receipt time was
2.1°C.
Receipt ExceptionsThesamplecollection time was not recorded on the sample containers for the following samples:MW-59-241217(280-201015-1)and DS-02-241217 (280-201015-2).The sample collection times were logged per the Chain-of-
Custody (COC).
There was no sample collection time recorded on the chain of custody or container labels for FB-02-241217
(280-201015-3)and Trip Blank (280-201015-4).The sample collection date/time was logged as 12/17/2024 at the
default time of 00:00 for FB-02-241217 (280-201015-3)and the sample collection date/time was logged as
12/17/2024 at 09:15 for Trip Blank (280-201015-4).
Method 8260D -Volatile Organic Compounds by GC/MS
Samples MW-59-241217 (280-201015-1),DS-02-241217 (280-201015-2),FB-02-241217 (280-201015-3)and Trip
Blank (280-201015-4)were analyzed for Volatile Organic Compounds by GC/MS.The samples were analyzed on
12/23/2024.
The following compounds were outside control limits (20%)in the continuing calibration verification (CCV)associated
with batch 280-679543:Chloromethane at -23.2%.This compound is considered a poor performer and the laboratory
control sample and laboratory control sample duplicate (LCS/LCSD)recoveries are within limits;therefore,the data
have been reported.The associated samples were non-detect for the affected analytes.
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Page 6 of 428
Detection Summary
Job ID: 280-201015-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Client Sample ID: MW-59-241217 Lab Sample ID: 280-201015-1
cis-1,2-Dichloroethene
RL
1.0 ug/L
MDL
0.32
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1338260D
trans-1,2-Dichloroethene 1.0 ug/L0.37 Total/NA17.8 8260D
1,1-Dichloroethane 1.0 ug/L0.22 Total/NA14.5 8260D
1,1-Dichloroethene 1.0 ug/L0.23 Total/NA11.7 8260D
1,2-Dichloropropane 1.0 ug/L0.24 Total/NA13.4 8260D
Trichloroethene 1.0 ug/L0.30 Total/NA1358260D
1,2-Dichloroethene, Total 1.0 ug/L0.32 Total/NA1418260D
Client Sample ID: DS-02-241217 Lab Sample ID: 280-201015-2
cis-1,2-Dichloroethene
RL
1.0 ug/L
MDL
0.32
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1338260D
trans-1,2-Dichloroethene 1.0 ug/L0.37 Total/NA18.0 8260D
1,1-Dichloroethane 1.0 ug/L0.22 Total/NA14.6 8260D
1,1-Dichloroethene 1.0 ug/L0.23 Total/NA11.5 8260D
1,2-Dichloropropane 1.0 ug/L0.24 Total/NA13.3 8260D
Trichloroethene 1.0 ug/L0.30 Total/NA1428260D
1,2-Dichloroethene, Total 1.0 ug/L0.32 Total/NA1418260D
Client Sample ID: FB-02-241217 Lab Sample ID: 280-201015-3
Chlorodibromomethane
RL
1.0 ug/L
MDL
0.28
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1J0.87 8260D
Chloroform 1.0 ug/L0.36 Total/NA10.67 J 8260D
Bromoform 2.0 ug/L0.25 Total/NA13.1 8260D
Trihalomethanes, Total 1.0 ug/L0.19 Total/NA14.6 8260D
Client Sample ID: Trip Blank Lab Sample ID: 280-201015-4
No Detections.
Eurofins Denver
This Detection Summary does not include radiochemical test results.
12/27/2024
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Page 7 of 428
Client Sample Results
Job ID: 280-201015-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Lab Sample ID: 280-201015-1Client Sample ID: MW-59-241217
Matrix: WaterDate Collected: 12/17/24 09:15
Date Received: 12/18/24 09:45
Method: SW846 8260D - Volatile Organic Compounds by GC/MS
RL MDL
ND 1.0 0.14 ug/L 12/23/24 22:28 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Ethylbenzene
1.0 0.13 ug/L 12/23/24 22:28 1NDStyrene
1.0 0.16 ug/L 12/23/24 22:28 1NDcis-1,3-Dichloropropene
1.0 0.14 ug/L 12/23/24 22:28 1NDtrans-1,3-Dichloropropene
1.0 0.18 ug/L 12/23/24 22:28 1NDN-Propylbenzene
1.0 0.23 ug/L 12/23/24 22:28 1NDn-Butylbenzene
1.0 0.21 ug/L 12/23/24 22:28 1ND4-Chlorotoluene
1.0 0.39 ug/L 12/23/24 22:28 1ND1,4-Dichlorobenzene
1.0 0.18 ug/L 12/23/24 22:28 1NDEthylene Dibromide
2.0 0.46 ug/L 12/23/24 22:28 1ND3-Chloro-1-propene
1.0 0.28 ug/L 12/23/24 22:28 1ND1,2-Dichloroethane
3.0 0.36 ug/L 12/23/24 22:28 1NDVinyl acetate
5.0 0.98 ug/L 12/23/24 22:28 1ND4-Methyl-2-pentanone (MIBK)
1.0 0.12 ug/L 12/23/24 22:28 1ND1,3,5-Trimethylbenzene
1.0 0.19 ug/L 12/23/24 22:28 1NDBromobenzene
1.0 0.31 ug/L 12/23/24 22:28 1NDMethylcyclohexane
1.0 0.32 ug/L 12/23/24 22:28 1NDToluene
1.0 0.092 ug/L 12/23/24 22:28 1NDChlorobenzene
7.0 0.84 ug/L 12/23/24 22:28 1NDTetrahydrofuran
2.0 0.16 ug/L 12/23/24 22:28 1NDHexane
1.0 0.44 ug/L 12/23/24 22:28 1NDCyclohexane
1.0 0.58 ug/L 12/23/24 22:28 1ND1,2,4-Trichlorobenzene
1.0 0.28 ug/L 12/23/24 22:28 1NDChlorodibromomethane
1.0 0.40 ug/L 12/23/24 22:28 1NDTetrachloroethene
1.0 0.20 ug/L 12/23/24 22:28 1NDsec-Butylbenzene
1.0 0.17 ug/L 12/23/24 22:28 1ND1,3-Dichloropropane
1.0 0.32 ug/L 12/23/24 22:28 133cis-1,2-Dichloroethene
1.0 0.37 ug/L 12/23/24 22:28 17.8trans-1,2-Dichloroethene
5.0 0.25 ug/L 12/23/24 22:28 1NDMethyl tert-butyl ether
2.0 0.36 ug/L 12/23/24 22:28 1NDm-Xylene & p-Xylene
1.0 0.33 ug/L 12/23/24 22:28 1ND1,3-Dichlorobenzene
1.0 0.23 ug/L 12/23/24 22:28 1NDCarbon tetrachloride
1.0 0.19 ug/L 12/23/24 22:28 1ND1,1-Dichloropropene
5.0 0.81 ug/L 12/23/24 22:28 1ND2-Hexanone
1.0 0.17 ug/L 12/23/24 22:28 1ND2,2-Dichloropropane
2.0 0.35 ug/L 12/23/24 22:28 1NDEthyl ether
1.0 0.16 ug/L 12/23/24 22:28 1ND1,1,1,2-Tetrachloroethane
15 6.6 ug/L 12/23/24 22:28 1NDAcetone
1.0 0.36 ug/L 12/23/24 22:28 1NDChloroform
1.0 0.14 ug/L 12/23/24 22:28 1NDBenzene
1.0 0.39 ug/L 12/23/24 22:28 1ND1,1,1-Trichloroethane
5.0 2.4 ug/L 12/23/24 22:28 1NDBromomethane
2.0 0.23 ug/L 12/23/24 22:28 1NDChloromethane
5.0 2.6 ug/L 12/23/24 22:28 1NDIodomethane
1.0 0.34 ug/L 12/23/24 22:28 1NDDibromomethane
1.0 0.40 ug/L 12/23/24 22:28 1NDChlorobromomethane
2.0 0.64 ug/L 12/23/24 22:28 1NDChloroethane
1.0 0.23 ug/L 12/23/24 22:28 1NDVinyl chloride
2.0 0.94 ug/L 12/23/24 22:28 1NDMethylene Chloride
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Page 8 of 428
Client Sample Results
Job ID: 280-201015-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Lab Sample ID: 280-201015-1Client Sample ID: MW-59-241217
Matrix: WaterDate Collected: 12/17/24 09:15
Date Received: 12/18/24 09:45
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
ND 2.0 0.26 ug/L 12/23/24 22:28 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Carbon disulfide
2.0 0.25 ug/L 12/23/24 22:28 1NDBromoform
1.0 0.19 ug/L 12/23/24 22:28 1NDDichlorobromomethane
1.0 0.22 ug/L 12/23/24 22:28 14.51,1-Dichloroethane
1.0 0.23 ug/L 12/23/24 22:28 11.71,1-Dichloroethene
2.0 0.20 ug/L 12/23/24 22:28 1NDTrichlorofluoromethane
2.0 0.30 ug/L 12/23/24 22:28 1NDDichlorodifluoromethane
3.0 0.73 ug/L 12/23/24 22:28 1ND1,1,2-Trichloro-1,2,2-trifluoroethane
1.0 0.24 ug/L 12/23/24 22:28 13.41,2-Dichloropropane
10 4.6 ug/L 12/23/24 22:28 1ND2-Butanone (MEK)
1.0 0.27 ug/L 12/23/24 22:28 1ND1,1,2-Trichloroethane
1.0 0.30 ug/L 12/23/24 22:28 135Trichloroethene
5.0 1.6 ug/L 12/23/24 22:28 1NDMethyl acetate
1.0 0.21 ug/L 12/23/24 22:28 1ND1,1,2,2-Tetrachloroethane
4.0 1.2 ug/L 12/23/24 22:28 1ND1,2,3-Trichlorobenzene
2.0 0.53 ug/L 12/23/24 22:28 1NDHexachlorobutadiene
3.0 0.99 ug/L 12/23/24 22:28 1NDNaphthalene
1.0 0.11 ug/L 12/23/24 22:28 1NDo-Xylene
1.0 0.34 ug/L 12/23/24 22:28 1ND2-Chlorotoluene
1.0 0.14 ug/L 12/23/24 22:28 1ND1,2-Dichlorobenzene
1.0 0.15 ug/L 12/23/24 22:28 1ND1,2,4-Trimethylbenzene
5.0 0.42 ug/L 12/23/24 22:28 1ND1,2-Dibromo-3-Chloropropane
2.5 0.28 ug/L 12/23/24 22:28 1ND1,2,3-Trichloropropane
3.0 0.19 ug/L 12/23/24 22:28 1NDEthyl methacrylate
1.0 0.18 ug/L 12/23/24 22:28 1NDtert-Butylbenzene
1.0 0.16 ug/L 12/23/24 22:28 1NDIsopropylbenzene
1.0 0.19 ug/L 12/23/24 22:28 1ND4-Isopropyltoluene
1.0 0.11 ug/L 12/23/24 22:28 1NDXylenes, Total
1.0 0.32 ug/L 12/23/24 22:28 1411,2-Dichloroethene, Total
1.0 0.14 ug/L 12/23/24 22:28 1ND1,3-Dichloropropene, Total
1.0 0.19 ug/L 12/23/24 22:28 1NDTrihalomethanes, Total
1.0 0.14 ug/L 12/23/24 22:28 1NDTotal BTEX
1,2-Dichloroethane-d4 (Surr)99 70 -127 12/23/24 22:28 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)95 12/23/24 22:28 177-120
Toluene-d8 (Surr)101 12/23/24 22:28 180-125
4-Bromofluorobenzene (Surr)98 12/23/24 22:28 178-120
Lab Sample ID: 280-201015-2Client Sample ID: DS-02-241217
Matrix: WaterDate Collected: 12/17/24 09:15
Date Received: 12/18/24 09:45
Method: SW846 8260D - Volatile Organic Compounds by GC/MS
RL MDL
ND 1.0 0.14 ug/L 12/23/24 22:48 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Ethylbenzene
1.0 0.13 ug/L 12/23/24 22:48 1NDStyrene
1.0 0.16 ug/L 12/23/24 22:48 1NDcis-1,3-Dichloropropene
1.0 0.14 ug/L 12/23/24 22:48 1NDtrans-1,3-Dichloropropene
1.0 0.18 ug/L 12/23/24 22:48 1NDN-Propylbenzene
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12/27/2024
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Page 9 of 428
Client Sample Results
Job ID: 280-201015-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Lab Sample ID: 280-201015-2Client Sample ID: DS-02-241217
Matrix: WaterDate Collected: 12/17/24 09:15
Date Received: 12/18/24 09:45
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
ND 1.0 0.23 ug/L 12/23/24 22:48 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
n-Butylbenzene
1.0 0.21 ug/L 12/23/24 22:48 1ND4-Chlorotoluene
1.0 0.39 ug/L 12/23/24 22:48 1ND1,4-Dichlorobenzene
1.0 0.18 ug/L 12/23/24 22:48 1NDEthylene Dibromide
2.0 0.46 ug/L 12/23/24 22:48 1ND3-Chloro-1-propene
1.0 0.28 ug/L 12/23/24 22:48 1ND1,2-Dichloroethane
3.0 0.36 ug/L 12/23/24 22:48 1NDVinyl acetate
5.0 0.98 ug/L 12/23/24 22:48 1ND4-Methyl-2-pentanone (MIBK)
1.0 0.12 ug/L 12/23/24 22:48 1ND1,3,5-Trimethylbenzene
1.0 0.19 ug/L 12/23/24 22:48 1NDBromobenzene
1.0 0.31 ug/L 12/23/24 22:48 1NDMethylcyclohexane
1.0 0.32 ug/L 12/23/24 22:48 1NDToluene
1.0 0.092 ug/L 12/23/24 22:48 1NDChlorobenzene
7.0 0.84 ug/L 12/23/24 22:48 1NDTetrahydrofuran
2.0 0.16 ug/L 12/23/24 22:48 1NDHexane
1.0 0.44 ug/L 12/23/24 22:48 1NDCyclohexane
1.0 0.58 ug/L 12/23/24 22:48 1ND1,2,4-Trichlorobenzene
1.0 0.28 ug/L 12/23/24 22:48 1NDChlorodibromomethane
1.0 0.40 ug/L 12/23/24 22:48 1NDTetrachloroethene
1.0 0.20 ug/L 12/23/24 22:48 1NDsec-Butylbenzene
1.0 0.17 ug/L 12/23/24 22:48 1ND1,3-Dichloropropane
1.0 0.32 ug/L 12/23/24 22:48 133cis-1,2-Dichloroethene
1.0 0.37 ug/L 12/23/24 22:48 18.0trans-1,2-Dichloroethene
5.0 0.25 ug/L 12/23/24 22:48 1NDMethyl tert-butyl ether
2.0 0.36 ug/L 12/23/24 22:48 1NDm-Xylene & p-Xylene
1.0 0.33 ug/L 12/23/24 22:48 1ND1,3-Dichlorobenzene
1.0 0.23 ug/L 12/23/24 22:48 1NDCarbon tetrachloride
1.0 0.19 ug/L 12/23/24 22:48 1ND1,1-Dichloropropene
5.0 0.81 ug/L 12/23/24 22:48 1ND2-Hexanone
1.0 0.17 ug/L 12/23/24 22:48 1ND2,2-Dichloropropane
2.0 0.35 ug/L 12/23/24 22:48 1NDEthyl ether
1.0 0.16 ug/L 12/23/24 22:48 1ND1,1,1,2-Tetrachloroethane
15 6.6 ug/L 12/23/24 22:48 1NDAcetone
1.0 0.36 ug/L 12/23/24 22:48 1NDChloroform
1.0 0.14 ug/L 12/23/24 22:48 1NDBenzene
1.0 0.39 ug/L 12/23/24 22:48 1ND1,1,1-Trichloroethane
5.0 2.4 ug/L 12/23/24 22:48 1NDBromomethane
2.0 0.23 ug/L 12/23/24 22:48 1NDChloromethane
5.0 2.6 ug/L 12/23/24 22:48 1NDIodomethane
1.0 0.34 ug/L 12/23/24 22:48 1NDDibromomethane
1.0 0.40 ug/L 12/23/24 22:48 1NDChlorobromomethane
2.0 0.64 ug/L 12/23/24 22:48 1NDChloroethane
1.0 0.23 ug/L 12/23/24 22:48 1NDVinyl chloride
2.0 0.94 ug/L 12/23/24 22:48 1NDMethylene Chloride
2.0 0.26 ug/L 12/23/24 22:48 1NDCarbon disulfide
2.0 0.25 ug/L 12/23/24 22:48 1NDBromoform
1.0 0.19 ug/L 12/23/24 22:48 1NDDichlorobromomethane
1.0 0.22 ug/L 12/23/24 22:48 14.61,1-Dichloroethane
1.0 0.23 ug/L 12/23/24 22:48 11.51,1-Dichloroethene
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Page 10 of 428
Client Sample Results
Job ID: 280-201015-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Lab Sample ID: 280-201015-2Client Sample ID: DS-02-241217
Matrix: WaterDate Collected: 12/17/24 09:15
Date Received: 12/18/24 09:45
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
ND 2.0 0.20 ug/L 12/23/24 22:48 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Trichlorofluoromethane
2.0 0.30 ug/L 12/23/24 22:48 1NDDichlorodifluoromethane
3.0 0.73 ug/L 12/23/24 22:48 1ND1,1,2-Trichloro-1,2,2-trifluoroethane
1.0 0.24 ug/L 12/23/24 22:48 13.31,2-Dichloropropane
10 4.6 ug/L 12/23/24 22:48 1ND2-Butanone (MEK)
1.0 0.27 ug/L 12/23/24 22:48 1ND1,1,2-Trichloroethane
1.0 0.30 ug/L 12/23/24 22:48 142Trichloroethene
5.0 1.6 ug/L 12/23/24 22:48 1NDMethyl acetate
1.0 0.21 ug/L 12/23/24 22:48 1ND1,1,2,2-Tetrachloroethane
4.0 1.2 ug/L 12/23/24 22:48 1ND1,2,3-Trichlorobenzene
2.0 0.53 ug/L 12/23/24 22:48 1NDHexachlorobutadiene
3.0 0.99 ug/L 12/23/24 22:48 1NDNaphthalene
1.0 0.11 ug/L 12/23/24 22:48 1NDo-Xylene
1.0 0.34 ug/L 12/23/24 22:48 1ND2-Chlorotoluene
1.0 0.14 ug/L 12/23/24 22:48 1ND1,2-Dichlorobenzene
1.0 0.15 ug/L 12/23/24 22:48 1ND1,2,4-Trimethylbenzene
5.0 0.42 ug/L 12/23/24 22:48 1ND1,2-Dibromo-3-Chloropropane
2.5 0.28 ug/L 12/23/24 22:48 1ND1,2,3-Trichloropropane
3.0 0.19 ug/L 12/23/24 22:48 1NDEthyl methacrylate
1.0 0.18 ug/L 12/23/24 22:48 1NDtert-Butylbenzene
1.0 0.16 ug/L 12/23/24 22:48 1NDIsopropylbenzene
1.0 0.19 ug/L 12/23/24 22:48 1ND4-Isopropyltoluene
1.0 0.11 ug/L 12/23/24 22:48 1NDXylenes, Total
1.0 0.32 ug/L 12/23/24 22:48 1411,2-Dichloroethene, Total
1.0 0.14 ug/L 12/23/24 22:48 1ND1,3-Dichloropropene, Total
1.0 0.19 ug/L 12/23/24 22:48 1NDTrihalomethanes, Total
1.0 0.14 ug/L 12/23/24 22:48 1NDTotal BTEX
1,2-Dichloroethane-d4 (Surr)100 70 -127 12/23/24 22:48 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)96 12/23/24 22:48 177-120
Toluene-d8 (Surr)101 12/23/24 22:48 180-125
4-Bromofluorobenzene (Surr)99 12/23/24 22:48 178-120
Lab Sample ID: 280-201015-3Client Sample ID: FB-02-241217
Matrix: WaterDate Collected: 12/17/24 00:00
Date Received: 12/18/24 09:45
Method: SW846 8260D - Volatile Organic Compounds by GC/MS
RL MDL
ND 1.0 0.14 ug/L 12/23/24 21:03 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Ethylbenzene
1.0 0.13 ug/L 12/23/24 21:03 1NDStyrene
1.0 0.16 ug/L 12/23/24 21:03 1NDcis-1,3-Dichloropropene
1.0 0.14 ug/L 12/23/24 21:03 1NDtrans-1,3-Dichloropropene
1.0 0.18 ug/L 12/23/24 21:03 1NDN-Propylbenzene
1.0 0.23 ug/L 12/23/24 21:03 1NDn-Butylbenzene
1.0 0.21 ug/L 12/23/24 21:03 1ND4-Chlorotoluene
1.0 0.39 ug/L 12/23/24 21:03 1ND1,4-Dichlorobenzene
1.0 0.18 ug/L 12/23/24 21:03 1NDEthylene Dibromide
2.0 0.46 ug/L 12/23/24 21:03 1ND3-Chloro-1-propene
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Client Sample Results
Job ID: 280-201015-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Lab Sample ID: 280-201015-3Client Sample ID: FB-02-241217
Matrix: WaterDate Collected: 12/17/24 00:00
Date Received: 12/18/24 09:45
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
ND 1.0 0.28 ug/L 12/23/24 21:03 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,2-Dichloroethane
3.0 0.36 ug/L 12/23/24 21:03 1NDVinyl acetate
5.0 0.98 ug/L 12/23/24 21:03 1ND4-Methyl-2-pentanone (MIBK)
1.0 0.12 ug/L 12/23/24 21:03 1ND1,3,5-Trimethylbenzene
1.0 0.19 ug/L 12/23/24 21:03 1NDBromobenzene
1.0 0.31 ug/L 12/23/24 21:03 1NDMethylcyclohexane
1.0 0.32 ug/L 12/23/24 21:03 1NDToluene
1.0 0.092 ug/L 12/23/24 21:03 1NDChlorobenzene
7.0 0.84 ug/L 12/23/24 21:03 1NDTetrahydrofuran
2.0 0.16 ug/L 12/23/24 21:03 1NDHexane
1.0 0.44 ug/L 12/23/24 21:03 1NDCyclohexane
1.0 0.58 ug/L 12/23/24 21:03 1ND1,2,4-Trichlorobenzene
1.0 0.28 ug/L 12/23/24 21:03 10.87 JChlorodibromomethane
1.0 0.40 ug/L 12/23/24 21:03 1NDTetrachloroethene
1.0 0.20 ug/L 12/23/24 21:03 1NDsec-Butylbenzene
1.0 0.17 ug/L 12/23/24 21:03 1ND1,3-Dichloropropane
1.0 0.32 ug/L 12/23/24 21:03 1NDcis-1,2-Dichloroethene
1.0 0.37 ug/L 12/23/24 21:03 1NDtrans-1,2-Dichloroethene
5.0 0.25 ug/L 12/23/24 21:03 1NDMethyl tert-butyl ether
2.0 0.36 ug/L 12/23/24 21:03 1NDm-Xylene & p-Xylene
1.0 0.33 ug/L 12/23/24 21:03 1ND1,3-Dichlorobenzene
1.0 0.23 ug/L 12/23/24 21:03 1NDCarbon tetrachloride
1.0 0.19 ug/L 12/23/24 21:03 1ND1,1-Dichloropropene
5.0 0.81 ug/L 12/23/24 21:03 1ND2-Hexanone
1.0 0.17 ug/L 12/23/24 21:03 1ND2,2-Dichloropropane
2.0 0.35 ug/L 12/23/24 21:03 1NDEthyl ether
1.0 0.16 ug/L 12/23/24 21:03 1ND1,1,1,2-Tetrachloroethane
15 6.6 ug/L 12/23/24 21:03 1NDAcetone
1.0 0.36 ug/L 12/23/24 21:03 10.67 JChloroform
1.0 0.14 ug/L 12/23/24 21:03 1NDBenzene
1.0 0.39 ug/L 12/23/24 21:03 1ND1,1,1-Trichloroethane
5.0 2.4 ug/L 12/23/24 21:03 1NDBromomethane
2.0 0.23 ug/L 12/23/24 21:03 1NDChloromethane
5.0 2.6 ug/L 12/23/24 21:03 1NDIodomethane
1.0 0.34 ug/L 12/23/24 21:03 1NDDibromomethane
1.0 0.40 ug/L 12/23/24 21:03 1NDChlorobromomethane
2.0 0.64 ug/L 12/23/24 21:03 1NDChloroethane
1.0 0.23 ug/L 12/23/24 21:03 1NDVinyl chloride
2.0 0.94 ug/L 12/23/24 21:03 1NDMethylene Chloride
2.0 0.26 ug/L 12/23/24 21:03 1NDCarbon disulfide
2.0 0.25 ug/L 12/23/24 21:03 13.1Bromoform
1.0 0.19 ug/L 12/23/24 21:03 1NDDichlorobromomethane
1.0 0.22 ug/L 12/23/24 21:03 1ND1,1-Dichloroethane
1.0 0.23 ug/L 12/23/24 21:03 1ND1,1-Dichloroethene
2.0 0.20 ug/L 12/23/24 21:03 1NDTrichlorofluoromethane
2.0 0.30 ug/L 12/23/24 21:03 1NDDichlorodifluoromethane
3.0 0.73 ug/L 12/23/24 21:03 1ND1,1,2-Trichloro-1,2,2-trifluoroethane
1.0 0.24 ug/L 12/23/24 21:03 1ND1,2-Dichloropropane
10 4.6 ug/L 12/23/24 21:03 1ND2-Butanone (MEK)
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9:26:49 AM
Page 12 of 428
Client Sample Results
Job ID: 280-201015-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Lab Sample ID: 280-201015-3Client Sample ID: FB-02-241217
Matrix: WaterDate Collected: 12/17/24 00:00
Date Received: 12/18/24 09:45
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
ND 1.0 0.27 ug/L 12/23/24 21:03 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,2-Trichloroethane
1.0 0.30 ug/L 12/23/24 21:03 1NDTrichloroethene
5.0 1.6 ug/L 12/23/24 21:03 1NDMethyl acetate
1.0 0.21 ug/L 12/23/24 21:03 1ND1,1,2,2-Tetrachloroethane
4.0 1.2 ug/L 12/23/24 21:03 1ND1,2,3-Trichlorobenzene
2.0 0.53 ug/L 12/23/24 21:03 1NDHexachlorobutadiene
3.0 0.99 ug/L 12/23/24 21:03 1NDNaphthalene
1.0 0.11 ug/L 12/23/24 21:03 1NDo-Xylene
1.0 0.34 ug/L 12/23/24 21:03 1ND2-Chlorotoluene
1.0 0.14 ug/L 12/23/24 21:03 1ND1,2-Dichlorobenzene
1.0 0.15 ug/L 12/23/24 21:03 1ND1,2,4-Trimethylbenzene
5.0 0.42 ug/L 12/23/24 21:03 1ND1,2-Dibromo-3-Chloropropane
2.5 0.28 ug/L 12/23/24 21:03 1ND1,2,3-Trichloropropane
3.0 0.19 ug/L 12/23/24 21:03 1NDEthyl methacrylate
1.0 0.18 ug/L 12/23/24 21:03 1NDtert-Butylbenzene
1.0 0.16 ug/L 12/23/24 21:03 1NDIsopropylbenzene
1.0 0.19 ug/L 12/23/24 21:03 1ND4-Isopropyltoluene
1.0 0.11 ug/L 12/23/24 21:03 1NDXylenes, Total
1.0 0.32 ug/L 12/23/24 21:03 1ND1,2-Dichloroethene, Total
1.0 0.14 ug/L 12/23/24 21:03 1ND1,3-Dichloropropene, Total
1.0 0.19 ug/L 12/23/24 21:03 14.6Trihalomethanes, Total
1.0 0.14 ug/L 12/23/24 21:03 1NDTotal BTEX
1,2-Dichloroethane-d4 (Surr)99 70 -127 12/23/24 21:03 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)90 12/23/24 21:03 177-120
Toluene-d8 (Surr)101 12/23/24 21:03 180-125
4-Bromofluorobenzene (Surr)99 12/23/24 21:03 178-120
Lab Sample ID: 280-201015-4Client Sample ID: Trip Blank
Matrix: WaterDate Collected: 12/17/24 09:15
Date Received: 12/18/24 09:45
Method: SW846 8260D - Volatile Organic Compounds by GC/MS
RL MDL
ND 1.0 0.14 ug/L 12/23/24 21:28 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Ethylbenzene
1.0 0.13 ug/L 12/23/24 21:28 1NDStyrene
1.0 0.16 ug/L 12/23/24 21:28 1NDcis-1,3-Dichloropropene
1.0 0.14 ug/L 12/23/24 21:28 1NDtrans-1,3-Dichloropropene
1.0 0.18 ug/L 12/23/24 21:28 1NDN-Propylbenzene
1.0 0.23 ug/L 12/23/24 21:28 1NDn-Butylbenzene
1.0 0.21 ug/L 12/23/24 21:28 1ND4-Chlorotoluene
1.0 0.39 ug/L 12/23/24 21:28 1ND1,4-Dichlorobenzene
1.0 0.18 ug/L 12/23/24 21:28 1NDEthylene Dibromide
2.0 0.46 ug/L 12/23/24 21:28 1ND3-Chloro-1-propene
1.0 0.28 ug/L 12/23/24 21:28 1ND1,2-Dichloroethane
3.0 0.36 ug/L 12/23/24 21:28 1NDVinyl acetate
5.0 0.98 ug/L 12/23/24 21:28 1ND4-Methyl-2-pentanone (MIBK)
1.0 0.12 ug/L 12/23/24 21:28 1ND1,3,5-Trimethylbenzene
1.0 0.19 ug/L 12/23/24 21:28 1NDBromobenzene
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Page 13 of 428
Client Sample Results
Job ID: 280-201015-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Lab Sample ID: 280-201015-4Client Sample ID: Trip Blank
Matrix: WaterDate Collected: 12/17/24 09:15
Date Received: 12/18/24 09:45
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
ND 1.0 0.31 ug/L 12/23/24 21:28 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Methylcyclohexane
1.0 0.32 ug/L 12/23/24 21:28 1NDToluene
1.0 0.092 ug/L 12/23/24 21:28 1NDChlorobenzene
7.0 0.84 ug/L 12/23/24 21:28 1NDTetrahydrofuran
2.0 0.16 ug/L 12/23/24 21:28 1NDHexane
1.0 0.44 ug/L 12/23/24 21:28 1NDCyclohexane
1.0 0.58 ug/L 12/23/24 21:28 1ND1,2,4-Trichlorobenzene
1.0 0.28 ug/L 12/23/24 21:28 1NDChlorodibromomethane
1.0 0.40 ug/L 12/23/24 21:28 1NDTetrachloroethene
1.0 0.20 ug/L 12/23/24 21:28 1NDsec-Butylbenzene
1.0 0.17 ug/L 12/23/24 21:28 1ND1,3-Dichloropropane
1.0 0.32 ug/L 12/23/24 21:28 1NDcis-1,2-Dichloroethene
1.0 0.37 ug/L 12/23/24 21:28 1NDtrans-1,2-Dichloroethene
5.0 0.25 ug/L 12/23/24 21:28 1NDMethyl tert-butyl ether
2.0 0.36 ug/L 12/23/24 21:28 1NDm-Xylene & p-Xylene
1.0 0.33 ug/L 12/23/24 21:28 1ND1,3-Dichlorobenzene
1.0 0.23 ug/L 12/23/24 21:28 1NDCarbon tetrachloride
1.0 0.19 ug/L 12/23/24 21:28 1ND1,1-Dichloropropene
5.0 0.81 ug/L 12/23/24 21:28 1ND2-Hexanone
1.0 0.17 ug/L 12/23/24 21:28 1ND2,2-Dichloropropane
2.0 0.35 ug/L 12/23/24 21:28 1NDEthyl ether
1.0 0.16 ug/L 12/23/24 21:28 1ND1,1,1,2-Tetrachloroethane
15 6.6 ug/L 12/23/24 21:28 1NDAcetone
1.0 0.36 ug/L 12/23/24 21:28 1NDChloroform
1.0 0.14 ug/L 12/23/24 21:28 1NDBenzene
1.0 0.39 ug/L 12/23/24 21:28 1ND1,1,1-Trichloroethane
5.0 2.4 ug/L 12/23/24 21:28 1NDBromomethane
2.0 0.23 ug/L 12/23/24 21:28 1NDChloromethane
5.0 2.6 ug/L 12/23/24 21:28 1NDIodomethane
1.0 0.34 ug/L 12/23/24 21:28 1NDDibromomethane
1.0 0.40 ug/L 12/23/24 21:28 1NDChlorobromomethane
2.0 0.64 ug/L 12/23/24 21:28 1NDChloroethane
1.0 0.23 ug/L 12/23/24 21:28 1NDVinyl chloride
2.0 0.94 ug/L 12/23/24 21:28 1NDMethylene Chloride
2.0 0.26 ug/L 12/23/24 21:28 1NDCarbon disulfide
2.0 0.25 ug/L 12/23/24 21:28 1NDBromoform
1.0 0.19 ug/L 12/23/24 21:28 1NDDichlorobromomethane
1.0 0.22 ug/L 12/23/24 21:28 1ND1,1-Dichloroethane
1.0 0.23 ug/L 12/23/24 21:28 1ND1,1-Dichloroethene
2.0 0.20 ug/L 12/23/24 21:28 1NDTrichlorofluoromethane
2.0 0.30 ug/L 12/23/24 21:28 1NDDichlorodifluoromethane
3.0 0.73 ug/L 12/23/24 21:28 1ND1,1,2-Trichloro-1,2,2-trifluoroethane
1.0 0.24 ug/L 12/23/24 21:28 1ND1,2-Dichloropropane
10 4.6 ug/L 12/23/24 21:28 1ND2-Butanone (MEK)
1.0 0.27 ug/L 12/23/24 21:28 1ND1,1,2-Trichloroethane
1.0 0.30 ug/L 12/23/24 21:28 1NDTrichloroethene
5.0 1.6 ug/L 12/23/24 21:28 1NDMethyl acetate
1.0 0.21 ug/L 12/23/24 21:28 1ND1,1,2,2-Tetrachloroethane
4.0 1.2 ug/L 12/23/24 21:28 1ND1,2,3-Trichlorobenzene
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Page 14 of 428
Client Sample Results
Job ID: 280-201015-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Lab Sample ID: 280-201015-4Client Sample ID: Trip Blank
Matrix: WaterDate Collected: 12/17/24 09:15
Date Received: 12/18/24 09:45
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
ND 2.0 0.53 ug/L 12/23/24 21:28 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Hexachlorobutadiene
3.0 0.99 ug/L 12/23/24 21:28 1NDNaphthalene
1.0 0.11 ug/L 12/23/24 21:28 1NDo-Xylene
1.0 0.34 ug/L 12/23/24 21:28 1ND2-Chlorotoluene
1.0 0.14 ug/L 12/23/24 21:28 1ND1,2-Dichlorobenzene
1.0 0.15 ug/L 12/23/24 21:28 1ND1,2,4-Trimethylbenzene
5.0 0.42 ug/L 12/23/24 21:28 1ND1,2-Dibromo-3-Chloropropane
2.5 0.28 ug/L 12/23/24 21:28 1ND1,2,3-Trichloropropane
3.0 0.19 ug/L 12/23/24 21:28 1NDEthyl methacrylate
1.0 0.18 ug/L 12/23/24 21:28 1NDtert-Butylbenzene
1.0 0.16 ug/L 12/23/24 21:28 1NDIsopropylbenzene
1.0 0.19 ug/L 12/23/24 21:28 1ND4-Isopropyltoluene
1.0 0.11 ug/L 12/23/24 21:28 1NDXylenes, Total
1.0 0.32 ug/L 12/23/24 21:28 1ND1,2-Dichloroethene, Total
1.0 0.14 ug/L 12/23/24 21:28 1ND1,3-Dichloropropene, Total
1.0 0.19 ug/L 12/23/24 21:28 1NDTrihalomethanes, Total
1.0 0.14 ug/L 12/23/24 21:28 1NDTotal BTEX
1,2-Dichloroethane-d4 (Surr)99 70 -127 12/23/24 21:28 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane (Surr)95 12/23/24 21:28 177-120
Toluene-d8 (Surr)101 12/23/24 21:28 180-125
4-Bromofluorobenzene (Surr)99 12/23/24 21:28 178-120
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Page 15 of 428
Default Detection Limits
Client: Ramboll Americas Engineering Solutions Job ID: 280-201015-1
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS
1.01,1,1,2-Tetrachloroethane ug/L
Analyte UnitsMDLRL
0.16
1.01,1,1-Trichloroethane ug/L0.39
1.01,1,2,2-Tetrachloroethane ug/L0.21
3.01,1,2-Trichloro-1,2,2-trifluoroethane ug/L0.73
1.01,1,2-Trichloroethane ug/L0.27
1.01,1-Dichloroethane ug/L0.22
1.01,1-Dichloroethene ug/L0.23
1.01,1-Dichloropropene ug/L0.19
4.01,2,3-Trichlorobenzene ug/L1.2
2.51,2,3-Trichloropropane ug/L0.28
1.01,2,4-Trichlorobenzene ug/L0.58
1.01,2,4-Trimethylbenzene ug/L0.15
5.01,2-Dibromo-3-Chloropropane ug/L0.42
1.01,2-Dichlorobenzene ug/L0.14
1.01,2-Dichloroethane ug/L0.28
1.01,2-Dichloroethene, Total ug/L0.32
1.01,2-Dichloropropane ug/L0.24
1.01,3,5-Trimethylbenzene ug/L0.12
1.01,3-Dichlorobenzene ug/L0.33
1.01,3-Dichloropropane ug/L0.17
1.01,3-Dichloropropene, Total ug/L0.14
1.01,4-Dichlorobenzene ug/L0.39
1.02,2-Dichloropropane ug/L0.17
102-Butanone (MEK)ug/L4.6
1.02-Chlorotoluene ug/L0.34
5.02-Hexanone ug/L0.81
2.03-Chloro-1-propene ug/L0.46
1.04-Chlorotoluene ug/L0.21
1.04-Isopropyltoluene ug/L0.19
5.04-Methyl-2-pentanone (MIBK)ug/L0.98
15Acetone ug/L6.6
1.0Benzene ug/L0.14
1.0Bromobenzene ug/L0.19
2.0Bromoform ug/L0.25
5.0Bromomethane ug/L2.4
2.0Carbon disulfide ug/L0.26
1.0Carbon tetrachloride ug/L0.23
1.0Chlorobenzene ug/L0.092
1.0Chlorobromomethane ug/L0.40
1.0Chlorodibromomethane ug/L0.28
2.0Chloroethane ug/L0.64
1.0Chloroform ug/L0.36
2.0Chloromethane ug/L0.23
1.0cis-1,2-Dichloroethene ug/L0.32
1.0cis-1,3-Dichloropropene ug/L0.16
1.0Cyclohexane ug/L0.44
1.0Dibromomethane ug/L0.34
1.0Dichlorobromomethane ug/L0.19
2.0Dichlorodifluoromethane ug/L0.30
2.0Ethyl ether ug/L0.35
3.0Ethyl methacrylate ug/L0.19
1.0Ethylbenzene ug/L0.14
1.0Ethylene Dibromide ug/L0.18
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Page 16 of 428
Default Detection Limits
Client: Ramboll Americas Engineering Solutions Job ID: 280-201015-1
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
2.0Hexachlorobutadiene ug/L
Analyte UnitsMDLRL
0.53
2.0Hexane ug/L0.16
5.0Iodomethane ug/L2.6
1.0Isopropylbenzene ug/L0.16
5.0Methyl acetate ug/L1.6
5.0Methyl tert-butyl ether ug/L0.25
1.0Methylcyclohexane ug/L0.31
2.0Methylene Chloride ug/L0.94
2.0m-Xylene & p-Xylene ug/L0.36
3.0Naphthalene ug/L0.99
1.0n-Butylbenzene ug/L0.23
1.0N-Propylbenzene ug/L0.18
1.0o-Xylene ug/L0.11
1.0sec-Butylbenzene ug/L0.20
1.0Styrene ug/L0.13
1.0tert-Butylbenzene ug/L0.18
1.0Tetrachloroethene ug/L0.40
7.0Tetrahydrofuran ug/L0.84
1.0Toluene ug/L0.32
1.0Total BTEX ug/L0.14
1.0trans-1,2-Dichloroethene ug/L0.37
1.0trans-1,3-Dichloropropene ug/L0.14
1.0Trichloroethene ug/L0.30
2.0Trichlorofluoromethane ug/L0.20
1.0Trihalomethanes, Total ug/L0.19
3.0Vinyl acetate ug/L0.36
1.0Vinyl chloride ug/L0.23
1.0Xylenes, Total ug/L0.11
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Surrogate Summary
Job ID: 280-201015-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS
Prep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (70-127)(77-120)(80-125)(78-120)
DCA DBFM TOL BFB
99 95 101 98280-201015-1
Percent Surrogate Recovery (Acceptance Limits)
MW-59-241217
100 96 101 99280-201015-2 DS-02-241217
99 90 101 99280-201015-3 FB-02-241217
99 95 101 99280-201015-4 Trip Blank
96 99 99 97LCS 280-679543/4 Lab Control Sample
95 99 102 99LCSD 280-679543/5 Lab Control Sample Dup
97 94 104 99MB 280-679543/9 Method Blank
Surrogate Legend
DCA = 1,2-Dichloroethane-d4 (Surr)
DBFM = Dibromofluoromethane (Surr)
TOL = Toluene-d8 (Surr)
BFB = 4-Bromofluorobenzene (Surr)
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Page 18 of 428
QC Sample Results
Job ID: 280-201015-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS
Client Sample ID: Method BlankLab Sample ID: MB 280-679543/9
Matrix: Water Prep Type: Total/NA
Analysis Batch: 679543
RL MDL
Ethylbenzene ND 1.0 0.14 ug/L 12/23/24 19:23 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
ND 0.131.0 ug/L 12/23/24 19:23 1Styrene
ND 0.161.0 ug/L 12/23/24 19:23 1cis-1,3-Dichloropropene
ND 0.141.0 ug/L 12/23/24 19:23 1trans-1,3-Dichloropropene
ND 0.181.0 ug/L 12/23/24 19:23 1N-Propylbenzene
ND 0.231.0 ug/L 12/23/24 19:23 1n-Butylbenzene
ND 0.211.0 ug/L 12/23/24 19:23 14-Chlorotoluene
ND 0.391.0 ug/L 12/23/24 19:23 11,4-Dichlorobenzene
ND 0.181.0 ug/L 12/23/24 19:23 1Ethylene Dibromide
ND 0.462.0 ug/L 12/23/24 19:23 13-Chloro-1-propene
ND 0.281.0 ug/L 12/23/24 19:23 11,2-Dichloroethane
ND 0.363.0 ug/L 12/23/24 19:23 1Vinyl acetate
ND 0.985.0 ug/L 12/23/24 19:23 14-Methyl-2-pentanone (MIBK)
ND 0.121.0 ug/L 12/23/24 19:23 11,3,5-Trimethylbenzene
ND 0.191.0 ug/L 12/23/24 19:23 1Bromobenzene
ND 0.311.0 ug/L 12/23/24 19:23 1Methylcyclohexane
ND 0.321.0 ug/L 12/23/24 19:23 1Toluene
ND 0.0921.0 ug/L 12/23/24 19:23 1Chlorobenzene
ND 0.847.0 ug/L 12/23/24 19:23 1Tetrahydrofuran
ND 0.162.0 ug/L 12/23/24 19:23 1Hexane
ND 0.441.0 ug/L 12/23/24 19:23 1Cyclohexane
ND 0.581.0 ug/L 12/23/24 19:23 11,2,4-Trichlorobenzene
ND 0.281.0 ug/L 12/23/24 19:23 1Chlorodibromomethane
ND 0.401.0 ug/L 12/23/24 19:23 1Tetrachloroethene
ND 0.201.0 ug/L 12/23/24 19:23 1sec-Butylbenzene
ND 0.171.0 ug/L 12/23/24 19:23 11,3-Dichloropropane
ND 0.321.0 ug/L 12/23/24 19:23 1cis-1,2-Dichloroethene
ND 0.371.0 ug/L 12/23/24 19:23 1trans-1,2-Dichloroethene
ND 0.255.0 ug/L 12/23/24 19:23 1Methyl tert-butyl ether
ND 0.362.0 ug/L 12/23/24 19:23 1m-Xylene & p-Xylene
ND 0.331.0 ug/L 12/23/24 19:23 11,3-Dichlorobenzene
ND 0.231.0 ug/L 12/23/24 19:23 1Carbon tetrachloride
ND 0.191.0 ug/L 12/23/24 19:23 11,1-Dichloropropene
ND 0.815.0 ug/L 12/23/24 19:23 12-Hexanone
ND 0.171.0 ug/L 12/23/24 19:23 12,2-Dichloropropane
ND 0.352.0 ug/L 12/23/24 19:23 1Ethyl ether
ND 0.161.0 ug/L 12/23/24 19:23 11,1,1,2-Tetrachloroethane
ND 6.615 ug/L 12/23/24 19:23 1Acetone
ND 0.361.0 ug/L 12/23/24 19:23 1Chloroform
ND 0.141.0 ug/L 12/23/24 19:23 1Benzene
ND 0.391.0 ug/L 12/23/24 19:23 11,1,1-Trichloroethane
ND 2.45.0 ug/L 12/23/24 19:23 1Bromomethane
ND 0.232.0 ug/L 12/23/24 19:23 1Chloromethane
ND 2.65.0 ug/L 12/23/24 19:23 1Iodomethane
ND 0.341.0 ug/L 12/23/24 19:23 1Dibromomethane
ND 0.401.0 ug/L 12/23/24 19:23 1Chlorobromomethane
ND 0.642.0 ug/L 12/23/24 19:23 1Chloroethane
ND 0.231.0 ug/L 12/23/24 19:23 1Vinyl chloride
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QC Sample Results
Job ID: 280-201015-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 280-679543/9
Matrix: Water Prep Type: Total/NA
Analysis Batch: 679543
RL MDL
Methylene Chloride ND 2.0 0.94 ug/L 12/23/24 19:23 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
ND 0.262.0 ug/L 12/23/24 19:23 1Carbon disulfide
ND 0.252.0 ug/L 12/23/24 19:23 1Bromoform
ND 0.191.0 ug/L 12/23/24 19:23 1Dichlorobromomethane
ND 0.221.0 ug/L 12/23/24 19:23 11,1-Dichloroethane
ND 0.231.0 ug/L 12/23/24 19:23 11,1-Dichloroethene
ND 0.202.0 ug/L 12/23/24 19:23 1Trichlorofluoromethane
ND 0.302.0 ug/L 12/23/24 19:23 1Dichlorodifluoromethane
ND 0.733.0 ug/L 12/23/24 19:23 11,1,2-Trichloro-1,2,2-trifluoroethane
ND 0.241.0 ug/L 12/23/24 19:23 11,2-Dichloropropane
ND 4.610 ug/L 12/23/24 19:23 12-Butanone (MEK)
ND 0.271.0 ug/L 12/23/24 19:23 11,1,2-Trichloroethane
ND 0.301.0 ug/L 12/23/24 19:23 1Trichloroethene
ND 1.65.0 ug/L 12/23/24 19:23 1Methyl acetate
ND 0.211.0 ug/L 12/23/24 19:23 11,1,2,2-Tetrachloroethane
ND 1.24.0 ug/L 12/23/24 19:23 11,2,3-Trichlorobenzene
ND 0.532.0 ug/L 12/23/24 19:23 1Hexachlorobutadiene
ND 0.993.0 ug/L 12/23/24 19:23 1Naphthalene
ND 0.111.0 ug/L 12/23/24 19:23 1o-Xylene
ND 0.341.0 ug/L 12/23/24 19:23 12-Chlorotoluene
ND 0.141.0 ug/L 12/23/24 19:23 11,2-Dichlorobenzene
ND 0.151.0 ug/L 12/23/24 19:23 11,2,4-Trimethylbenzene
ND 0.425.0 ug/L 12/23/24 19:23 11,2-Dibromo-3-Chloropropane
ND 0.282.5 ug/L 12/23/24 19:23 11,2,3-Trichloropropane
ND 0.193.0 ug/L 12/23/24 19:23 1Ethyl methacrylate
ND 0.181.0 ug/L 12/23/24 19:23 1tert-Butylbenzene
ND 0.161.0 ug/L 12/23/24 19:23 1Isopropylbenzene
ND 0.191.0 ug/L 12/23/24 19:23 14-Isopropyltoluene
ND 0.111.0 ug/L 12/23/24 19:23 1Xylenes, Total
ND 0.321.0 ug/L 12/23/24 19:23 11,2-Dichloroethene, Total
ND 0.141.0 ug/L 12/23/24 19:23 11,3-Dichloropropene, Total
ND 0.191.0 ug/L 12/23/24 19:23 1Trihalomethanes, Total
ND 0.141.0 ug/L 12/23/24 19:23 1Total BTEX
1,2-Dichloroethane-d4 (Surr)97 70 -127 12/23/24 19:23 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
94 12/23/24 19:23 1Dibromofluoromethane (Surr)77 -120
104 12/23/24 19:23 1Toluene-d8 (Surr)80 -125
99 12/23/24 19:23 14-Bromofluorobenzene (Surr)78 -120
Client Sample ID: Lab Control SampleLab Sample ID: LCS 280-679543/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 679543
Ethylbenzene 50.0 47.8 ug/L 96 80 -120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Styrene 50.0 49.6 ug/L 99 80 -120
cis-1,3-Dichloropropene 50.0 51.6 ug/L 103 76 -129
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Page 20 of 428
QC Sample Results
Job ID: 280-201015-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 280-679543/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 679543
trans-1,3-Dichloropropene 50.0 42.1 ug/L 84 80 -123
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
N-Propylbenzene 50.0 46.7 ug/L 93 80 -123
n-Butylbenzene 50.0 47.1 ug/L 94 59 -140
4-Chlorotoluene 50.0 47.0 ug/L 94 80 -120
1,4-Dichlorobenzene 50.0 46.3 ug/L 93 80 -120
Ethylene Dibromide 50.0 48.4 ug/L 97 80 -120
3-Chloro-1-propene 50.0 46.0 ug/L 92 65 -132
1,2-Dichloroethane 50.0 44.6 ug/L 89 71 -121
Vinyl acetate 100 103 ug/L 103 55 -161
4-Methyl-2-pentanone (MIBK)200 191 ug/L 95 66 -135
1,3,5-Trimethylbenzene 50.0 47.5 ug/L 95 80 -122
Bromobenzene 50.0 47.2 ug/L 94 80 -120
Methylcyclohexane 50.0 45.7 ug/L 91 64 -130
Toluene 50.0 46.4 ug/L 93 80 -120
Chlorobenzene 50.0 47.2 ug/L 94 80 -120
Tetrahydrofuran 100 90.9 ug/L 91 62 -130
Hexane 50.0 46.5 ug/L 93 55 -143
Cyclohexane 50.0 45.8 ug/L 92 68 -125
1,2,4-Trichlorobenzene 50.0 48.1 ug/L 96 74 -126
Chlorodibromomethane 50.0 44.8 ug/L 90 80 -125
Tetrachloroethene 50.0 47.6 ug/L 95 80 -121
sec-Butylbenzene 50.0 46.8 ug/L 94 80 -123
1,3-Dichloropropane 50.0 48.1 ug/L 96 77 -122
cis-1,2-Dichloroethene 50.0 47.1 ug/L 94 80 -120
trans-1,2-Dichloroethene 50.0 48.1 ug/L 96 79 -121
Methyl tert-butyl ether 50.0 43.6 ug/L 87 80 -120
m-Xylene & p-Xylene 50.0 47.1 ug/L 94 80 -120
1,3-Dichlorobenzene 50.0 46.8 ug/L 94 80 -120
Carbon tetrachloride 50.0 43.4 ug/L 87 79 -127
1,1-Dichloropropene 50.0 46.7 ug/L 93 77 -123
2-Hexanone 200 192 ug/L 96 62 -137
2,2-Dichloropropane 50.0 48.7 ug/L 97 75 -131
Ethyl ether 50.0 49.6 ug/L 99 68 -132
1,1,1,2-Tetrachloroethane 50.0 51.2 ug/L 102 80 -124
Acetone 200 185 ug/L 93 61 -134
Chloroform 50.0 47.3 ug/L 95 80 -120
Benzene 50.0 47.1 ug/L 94 80 -120
1,1,1-Trichloroethane 50.0 47.3 ug/L 95 80 -123
Bromomethane 50.0 44.5 ug/L 89 29 -148
Chloromethane 50.0 38.4 ug/L 77 56 -133
Iodomethane 50.0 45.6 ug/L 91 43 -139
Dibromomethane 50.0 46.1 ug/L 92 80 -120
Chlorobromomethane 50.0 48.7 ug/L 97 80 -123
Chloroethane 50.0 44.8 ug/L 90 56 -141
Vinyl chloride 50.0 42.4 ug/L 85 67 -127
Methylene Chloride 50.0 43.8 ug/L 88 78 -120
Carbon disulfide 50.0 41.6 ug/L 83 70 -121
Bromoform 50.0 42.1 ug/L 84 79 -138
Dichlorobromomethane 50.0 49.0 ug/L 98 80 -123
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QC Sample Results
Job ID: 280-201015-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 280-679543/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 679543
1,1-Dichloroethane 50.0 47.9 ug/L 96 78 -121
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
1,1-Dichloroethene 50.0 47.1 ug/L 94 77 -121
Trichlorofluoromethane 50.0 51.0 ug/L 102 54 -144
Dichlorodifluoromethane 50.0 51.0 ug/L 102 47 -135
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
50.0 49.0 ug/L 98 73 -132
1,2-Dichloropropane 50.0 47.9 ug/L 96 78 -120
2-Butanone (MEK)200 183 ug/L 91 58 -135
1,1,2-Trichloroethane 50.0 47.6 ug/L 95 80 -120
Trichloroethene 50.0 49.4 ug/L 99 80 -120
Methyl acetate 100 91.9 ug/L 92 59 -136
1,1,2,2-Tetrachloroethane 50.0 49.7 ug/L 99 74 -123
1,2,3-Trichlorobenzene 50.0 46.0 ug/L 92 65 -129
Hexachlorobutadiene 50.0 46.4 ug/L 93 73 -128
Naphthalene 50.0 44.9 ug/L 90 60 -124
o-Xylene 50.0 48.0 ug/L 96 80 -120
2-Chlorotoluene 50.0 46.7 ug/L 93 80 -120
1,2-Dichlorobenzene 50.0 48.4 ug/L 97 80 -120
1,2,4-Trimethylbenzene 50.0 48.4 ug/L 97 79 -124
1,2-Dibromo-3-Chloropropane 50.0 42.1 ug/L 84 73 -128
1,2,3-Trichloropropane 50.0 48.3 ug/L 97 80 -120
Ethyl methacrylate 50.0 50.6 ug/L 101 80 -122
tert-Butylbenzene 50.0 46.4 ug/L 93 80 -120
Isopropylbenzene 50.0 47.7 ug/L 95 78 -122
4-Isopropyltoluene 50.0 47.7 ug/L 95 80 -122
1,2-Dichloroethane-d4 (Surr)70 -127
Surrogate
96
LCS LCS
Qualifier Limits%Recovery
99Dibromofluoromethane (Surr)77 -120
99Toluene-d8 (Surr)80 -125
974-Bromofluorobenzene (Surr)78 -120
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 280-679543/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 679543
Ethylbenzene 50.0 53.2 ug/L 106 80 -120 11 20
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
Styrene 50.0 53.6 ug/L 107 80 -120 8 20
cis-1,3-Dichloropropene 50.0 57.0 ug/L 114 76 -129 10 20
trans-1,3-Dichloropropene 50.0 44.9 ug/L 90 80 -123 6 20
N-Propylbenzene 50.0 52.0 ug/L 104 80 -123 11 20
n-Butylbenzene 50.0 52.0 ug/L 104 59 -140 10 20
4-Chlorotoluene 50.0 51.8 ug/L 104 80 -120 10 20
1,4-Dichlorobenzene 50.0 50.5 ug/L 101 80 -120 9 20
Ethylene Dibromide 50.0 53.9 ug/L 108 80 -120 11 20
3-Chloro-1-propene 50.0 48.9 ug/L 98 65 -132 6 20
1,2-Dichloroethane 50.0 47.6 ug/L 95 71 -121 7 20
Vinyl acetate 100 111 ug/L 111 55 -161 8 23
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QC Sample Results
Job ID: 280-201015-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 280-679543/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 679543
4-Methyl-2-pentanone (MIBK)200 200 ug/L 100 66 -135 5 20
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
1,3,5-Trimethylbenzene 50.0 51.1 ug/L 102 80 -122 7 20
Bromobenzene 50.0 53.3 ug/L 107 80 -120 12 20
Methylcyclohexane 50.0 49.0 ug/L 98 64 -130 7 21
Toluene 50.0 49.6 ug/L 99 80 -120 7 20
Chlorobenzene 50.0 52.2 ug/L 104 80 -120 10 20
Tetrahydrofuran 100 97.6 ug/L 98 62 -130 7 20
Hexane 50.0 51.1 ug/L 102 55 -143 9 23
Cyclohexane 50.0 49.9 ug/L 100 68 -125 9 32
1,2,4-Trichlorobenzene 50.0 54.0 ug/L 108 74 -126 12 20
Chlorodibromomethane 50.0 49.4 ug/L 99 80 -125 10 20
Tetrachloroethene 50.0 52.9 ug/L 106 80 -121 10 20
sec-Butylbenzene 50.0 51.4 ug/L 103 80 -123 9 20
1,3-Dichloropropane 50.0 52.6 ug/L 105 77 -122 9 20
cis-1,2-Dichloroethene 50.0 50.6 ug/L 101 80 -120 7 20
trans-1,2-Dichloroethene 50.0 51.1 ug/L 102 79 -121 6 20
Methyl tert-butyl ether 50.0 48.4 ug/L 97 80 -120 10 20
m-Xylene & p-Xylene 50.0 51.4 ug/L 103 80 -120 9 20
1,3-Dichlorobenzene 50.0 51.7 ug/L 103 80 -120 10 20
Carbon tetrachloride 50.0 47.3 ug/L 95 79 -127 9 20
1,1-Dichloropropene 50.0 50.6 ug/L 101 77 -123 8 20
2-Hexanone 200 208 ug/L 104 62 -137 8 21
2,2-Dichloropropane 50.0 51.4 ug/L 103 75 -131 5 22
Ethyl ether 50.0 52.5 ug/L 105 68 -132 6 20
1,1,1,2-Tetrachloroethane 50.0 56.5 ug/L 113 80 -124 10 20
Acetone 200 190 ug/L 95 61 -134 3 21
Chloroform 50.0 50.5 ug/L 101 80 -120 7 20
Benzene 50.0 50.2 ug/L 100 80 -120 6 20
1,1,1-Trichloroethane 50.0 51.2 ug/L 102 80 -123 8 20
Bromomethane 50.0 46.7 ug/L 93 29 -148 5 40
Chloromethane 50.0 38.4 ug/L 77 56 -133 0 20
Iodomethane 50.0 50.6 ug/L 101 43 -139 10 38
Dibromomethane 50.0 48.3 ug/L 97 80 -120 5 20
Chlorobromomethane 50.0 51.5 ug/L 103 80 -123 6 20
Chloroethane 50.0 49.0 ug/L 98 56 -141 9 30
Vinyl chloride 50.0 43.6 ug/L 87 67 -127 3 25
Methylene Chloride 50.0 46.4 ug/L 93 78 -120 6 20
Carbon disulfide 50.0 44.9 ug/L 90 70 -121 8 20
Bromoform 50.0 45.5 ug/L 91 79 -138 8 20
Dichlorobromomethane 50.0 52.3 ug/L 105 80 -123 7 20
1,1-Dichloroethane 50.0 51.8 ug/L 104 78 -121 8 20
1,1-Dichloroethene 50.0 50.1 ug/L 100 77 -121 6 21
Trichlorofluoromethane 50.0 50.9 ug/L 102 54 -144 0 28
Dichlorodifluoromethane 50.0 52.8 ug/L 106 47 -135 3 21
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
50.0 51.9 ug/L 104 73 -132 6 23
1,2-Dichloropropane 50.0 51.3 ug/L 103 78 -120 7 20
2-Butanone (MEK)200 189 ug/L 95 58 -135 3 20
1,1,2-Trichloroethane 50.0 51.2 ug/L 102 80 -120 7 20
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Page 23 of 428
QC Sample Results
Job ID: 280-201015-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 280-679543/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 679543
Trichloroethene 50.0 55.3 ug/L 111 80 -120 11 20
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
Methyl acetate 100 97.2 ug/L 97 59 -136 6 20
1,1,2,2-Tetrachloroethane 50.0 56.1 ug/L 112 74 -123 12 20
1,2,3-Trichlorobenzene 50.0 51.4 ug/L 103 65 -129 11 20
Hexachlorobutadiene 50.0 53.9 ug/L 108 73 -128 15 20
Naphthalene 50.0 50.0 ug/L 100 60 -124 11 21
o-Xylene 50.0 51.8 ug/L 104 80 -120 8 20
2-Chlorotoluene 50.0 51.9 ug/L 104 80 -120 10 20
1,2-Dichlorobenzene 50.0 53.0 ug/L 106 80 -120 9 20
1,2,4-Trimethylbenzene 50.0 52.0 ug/L 104 79 -124 7 20
1,2-Dibromo-3-Chloropropane 50.0 46.7 ug/L 93 73 -128 10 21
1,2,3-Trichloropropane 50.0 53.2 ug/L 106 80 -120 10 20
Ethyl methacrylate 50.0 55.5 ug/L 111 80 -122 9 20
tert-Butylbenzene 50.0 52.3 ug/L 105 80 -120 12 20
Isopropylbenzene 50.0 53.9 ug/L 108 78 -122 12 20
4-Isopropyltoluene 50.0 52.5 ug/L 105 80 -122 10 20
1,2-Dichloroethane-d4 (Surr)70 -127
Surrogate
95
LCSD LCSD
Qualifier Limits%Recovery
99Dibromofluoromethane (Surr)77 -120
102Toluene-d8 (Surr)80 -125
994-Bromofluorobenzene (Surr)78 -120
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Page 24 of 428
QC Association Summary
Job ID: 280-201015-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
GC/MS VOA
Analysis Batch: 679543
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 8260D280-201015-1 MW-59-241217 Total/NA
Water 8260D280-201015-2 DS-02-241217 Total/NA
Water 8260D280-201015-3 FB-02-241217 Total/NA
Water 8260D280-201015-4 Trip Blank Total/NA
Water 8260DMB 280-679543/9 Method Blank Total/NA
Water 8260DLCS 280-679543/4 Lab Control Sample Total/NA
Water 8260DLCSD 280-679543/5 Lab Control Sample Dup Total/NA
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Page 25 of 428
Lab Chronicle
Client: Ramboll Americas Engineering Solutions Job ID: 280-201015-1
Project/Site: Moog-SLC, UT
Client Sample ID: MW-59-241217 Lab Sample ID: 280-201015-1
Matrix: WaterDate Collected: 12/17/24 09:15
Date Received: 12/18/24 09:45
Analysis 8260D ETB12/23/24 22:281 EET DEN679543
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: DS-02-241217 Lab Sample ID: 280-201015-2
Matrix: WaterDate Collected: 12/17/24 09:15
Date Received: 12/18/24 09:45
Analysis 8260D ETB12/23/24 22:481 EET DEN679543
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: FB-02-241217 Lab Sample ID: 280-201015-3
Matrix: WaterDate Collected: 12/17/24 00:00
Date Received: 12/18/24 09:45
Analysis 8260D ETB12/23/24 21:031 EET DEN679543
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: Trip Blank Lab Sample ID: 280-201015-4
Matrix: WaterDate Collected: 12/17/24 09:15
Date Received: 12/18/24 09:45
Analysis 8260D ETB12/23/24 21:281 EET DEN679543
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Laboratory References:
EET DEN = Eurofins Denver, 4955 Yarrow Street, Arvada, CO 80002, TEL [phone]
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Page 26 of 428
Accreditation/Certification Summary
Client: Ramboll Americas Engineering Solutions Job ID: 280-201015-1
Project/Site: Moog-SLC, UT
Laboratory: Eurofins Denver
The accreditations/certifications listed below are applicable to this report.
Authority Program Identification Number Expiration Date
Utah NELAP CO00026 07-31-25
Eurofins Denver
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Page 27 of 428
Method Summary
Job ID: 280-201015-1Client: Ramboll Americas Engineering Solutions
Project/Site: Moog-SLC, UT
Method Method Description LaboratoryProtocol
SW8468260DVolatile Organic Compounds by GC/MS EET DEN
SW8465030BPurge and Trap EET DEN
Protocol References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
EET DEN = Eurofins Denver, 4955 Yarrow Street, Arvada, CO 80002, TEL [phone]
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Page 28 of 428
Sample Summary
Client: Ramboll Americas Engineering Solutions Job ID: 280-201015-1
Project/Site: Moog-SLC, UT
Lab Sample ID Client Sample ID Matrix Collected Received
280-201015-1 MW-59-241217 Water 12/17/24 09:15 12/18/24 09:45
280-201015-2 DS-02-241217 Water 12/17/24 09:15 12/18/24 09:45
280-201015-3 FB-02-241217 Water 12/17/24 00:00 12/18/24 09:45
280-201015-4 Trip Blank Water 12/17/24 09:15 12/18/24 09:45
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Page 29 of 428
Lab Name:Job No.:
GC/MS VOA MANUAL INTEGRATION SUMMARY
Eurofins Denver 280-201015-1
SDG No.:
Instrument ID:Analysis Batch Number:VMS_MS14 678685
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
IC 280-678685/13
VMS14_0000005223.D12/17/24 01:00 GC Column:DB-624 (60.25)ID:0.25(mm)
Acrolein Split Peak LP8K 12/17/24 14:503.06
Methyl tert-butyl ether Split Peak LP8K 12/17/24 14:503.72
Hexane Split Peak LP8K 12/17/24 14:503.92
1,1-Dichloroethane Split Peak LP8K 12/17/24 14:514.06
2,2-Dichloropropane Split Peak LP8K 12/17/24 15:294.49
Chlorobromomethane Split Peak LP8K 12/17/24 14:514.66
Tetrahydrofuran Split Peak LP8K 12/17/24 14:514.68
Chloroform Split Peak LP8K 12/17/24 14:514.72
Cyclohexane Split Peak LP8K 12/17/24 14:514.94
Carbon tetrachloride Assign Peak LP8K 12/17/24 15:094.99
Isobutyl alcohol Split Peak LP8K 12/17/24 14:515.00
1,2-Dichloroethane Split Peak LP8K 12/17/24 14:515.17
n-Heptane Split Peak LP8K 12/17/24 14:515.33
Trichloroethene Split Peak LP8K 12/17/24 14:515.65
Tetrachloroethene Split Peak LP8K 12/17/24 14:527.15
1,3-Dichloropropane Split Peak LP8K 12/17/24 14:527.19
Ethylene Dibromide Split Peak LP8K 12/17/24 14:527.51
1-Chlorohexane Split Peak LP8K 12/17/24 14:527.91
Chlorobenzene Split Peak LP8K 12/17/24 14:527.96
1,1,1,2-Tetrachloroethane Split Peak LP8K 12/17/24 14:528.03
1,2-Dibromo-3-Chloropropane Split Peak LP8K 12/17/24 14:5211.35
Hexachlorobutadiene Split Peak LP8K 12/17/24 14:5212.33
8260D
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Page 30 of 428
Lab Name:Job No.:
GC/MS VOA MANUAL INTEGRATION SUMMARY
Eurofins Denver 280-201015-1
SDG No.:
Instrument ID:Analysis Batch Number:VMS_MS14 678685
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
IC 280-678685/14
VMS14_0000005224.D12/17/24 01:20 GC Column:DB-624 (60.25)ID:0.25(mm)
Chloroethane Split Peak LP8K 12/17/24 14:532.49
Ethyl ether Split Peak LP8K 12/17/24 14:532.94
1,1,2-Trichloro-1,2,2-trifluoroet
hane
Split Peak LP8K 12/17/24 14:533.15
Iodomethane Split Peak LP8K 12/17/24 14:533.27
2-Methyl-2-propanol Split Peak LP8K 12/17/24 14:533.57
trans-1,2-Dichloroethene Split Peak LP8K 12/17/24 14:533.73
Carbon tetrachloride Split Peak LP8K 12/17/24 14:535.00
1,2-Dichloroethane Split Peak LP8K 12/17/24 14:535.17
Dibromomethane Split Peak LP8K 12/17/24 14:545.93
2-Chloroethyl vinyl ether Assign Peak LP8K 12/17/24 14:546.25
cis-1,3-Dichloropropene Split Peak LP8K 12/17/24 14:546.40
trans-1,3-Dichloropropene Split Peak LP8K 12/17/24 14:546.87
1,3-Dichloropropane Split Peak LP8K 12/17/24 14:547.20
1-Chlorohexane Split Peak LP8K 12/17/24 14:547.91
Bromoform Split Peak LP8K 12/17/24 14:548.71
trans-1,4-Dichloro-2-butene Split Peak LP8K 12/17/24 14:549.18
1,2-Dibromo-3-Chloropropane Split Peak LP8K 12/17/24 14:5411.35
1,2,3-Trichlorobenzene Split Peak LP8K 12/17/24 14:5512.68
8260D
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9:26:49 AM
Page 31 of 428
Lab Name:Job No.:
GC/MS VOA MANUAL INTEGRATION SUMMARY
Eurofins Denver 280-201015-1
SDG No.:
Instrument ID:Analysis Batch Number:VMS_MS14 678685
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
IC 280-678685/15
VMS14_0000005225.D12/17/24 01:40 GC Column:DB-624 (60.25)ID:0.25(mm)
1,1,2-Trichloro-1,2,2-trifluoroet
hane
Split Peak LP8K 12/17/24 14:553.14
3-Chloro-1-propene Incomplete Integration LP8K 12/17/24 14:563.42
1,4-Dioxane Incomplete Integration LP8K 12/17/24 14:565.92
2-Chloroethyl vinyl ether Incomplete Integration LP8K 12/17/24 14:566.24
1,1,2-Trichloroethane Assign Peak LP8K 12/17/24 14:577.05
1,2-Dibromo-3-Chloropropane Split Peak LP8K 12/17/24 14:5711.35
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
IC 280-678685/16
VMS14_0000005226.D12/17/24 02:00 GC Column:DB-624 (60.25)ID:0.25(mm)
Iodomethane Split Peak LP8K 12/17/24 14:583.27
3-Chloro-1-propene Incomplete Integration LP8K 12/17/24 14:583.42
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
IC 280-678685/17
VMS14_0000005227.D12/17/24 02:20 GC Column:DB-624 (60.25)ID:0.25(mm)
Carbon tetrachloride Incomplete Integration LP8K 12/17/24 14:595.00
1,1,1,2-Tetrachloroethane Incomplete Integration LP8K 12/17/24 14:598.03
8260D
12/27/2024
9:26:49 AM
Page 32 of 428
Lab Name:Job No.:
GC/MS VOA MANUAL INTEGRATION SUMMARY
Eurofins Denver 280-201015-1
SDG No.:
Instrument ID:Analysis Batch Number:VMS_MS14 679543
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
MB 280-679543/9
VMS14_0000005449.D12/23/24 19:23 GC Column:DB-624 (60.25)ID:0.25(mm)
Carbon disulfide Split Peak LP8K 12/23/24 19:40
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
280-201015-3 FB-02-241217
VMS14_0000005452.D12/23/24 21:03 GC Column:DB-624 (60.25)ID:0.25(mm)
Bromomethane Invalid Compound ID LP8K 12/23/24 22:19
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
280-201015-4 Trip Blank
VMS14_0000005453.D12/23/24 21:28 GC Column:DB-624 (60.25)ID:0.25(mm)
Bromomethane Invalid Compound ID LP8K 12/23/24 22:19
Naphthalene Split Peak LP8K 12/23/24 22:1912.45
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
280-201015-1 MW-59-241217
VMS14_0000005456.D12/23/24 22:28 GC Column:DB-624 (60.25)ID:0.25(mm)
Bromomethane Invalid Compound ID LP8K 12/23/24 23:08
8260D
12/27/2024
9:26:49 AM
Page 33 of 428
Lab Name:Job No.:
GC/MS VOA MANUAL INTEGRATION SUMMARY
Eurofins Denver 280-201015-1
SDG No.:
Instrument ID:Analysis Batch Number:VMS_MS14 679543
Lab Sample ID:Client Sample ID:
Date Analyzed:Lab File ID:
COMPOUND NAME RETENTION
TIME
MANUAL INTEGRATION
DATEANALYSTREASON
280-201015-2 DS-02-241217
VMS14_0000005457.D12/23/24 22:48 GC Column:DB-624 (60.25)ID:0.25(mm)
Tetrahydrofuran Split Peak LP8K 12/23/24 23:104.68
Bromomethane Invalid Compound ID LP8K 12/23/24 23:10
8260D
12/27/2024
9:26:49 AM
Page 34 of 428
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
MV-Gas A_00206 Bromomethane 5 ug/mL100 uL 2 uL12/26/24 12/16/24Cal Dil Std_00438 P&T Methanol, Lot EG359-US
Chloroethane 5 ug/mL
Chloromethane 5 ug/mL
Dichlorodifluoromethane 5 ug/mL
Dichlorofluoromethane 5 ug/mL
Trichlorofluoromethane 5 ug/mL
Vinyl chloride 5 ug/mL
2-Chloroethyl vinyl ether 5 ug/mL
Acrolein 49.375 ug/mLMV-MegaMainA_00121 5 uL
2-Butanone (MEK)20 ug/mL
2-Hexanone 20 ug/mL
4-Methyl-2-pentanone (MIBK)20 ug/mL
Acetone 20 ug/mL
Vinyl acetate 10 ug/mL
Cyclohexanone 150 ug/mL
1,1,1,2-Tetrachloroethane 5 ug/mL
1,1,1-Trichloroethane 5 ug/mL
1,1,2,2-Tetrachloroethane 5 ug/mL
1,1,2-Trichloro-1,2,2-trifluoroethane 5 ug/mL
1,1,2-Trichloroethane 5 ug/mL
1,1-Dichloroethane 5 ug/mL
1,1-Dichloroethene 5 ug/mL
1,1-Dichloropropene 5 ug/mL
1,2,3-Trichlorobenzene 5 ug/mL
1,2,3-Trichloropropane 5 ug/mL
1,2,4-Trichlorobenzene 5 ug/mL
1,2,4-Trimethylbenzene 5 ug/mL
1,2-Dibromo-3-Chloropropane 5 ug/mL
1,2-Dichlorobenzene 5 ug/mL
1,2-Dichloroethane 5 ug/mL
1,2-Dichloropropane 5 ug/mL
1,3,5-Trimethylbenzene 5 ug/mL
1,3-Dichlorobenzene 5 ug/mL
1,3-Dichloropropane 5 ug/mL
1,4-Dichlorobenzene 5 ug/mL
1,4-Dioxane 100 ug/mL
2,2-Dichloropropane 5 ug/mL
2-Chlorotoluene 5 ug/mL
2-Methyl-2-propanol 50 ug/mL
3-Chloro-1-propene 5 ug/mL
4-Chlorotoluene 5 ug/mL
4-Isopropyltoluene 5 ug/mL
Acrylonitrile 50 ug/mL
Benzene 5 ug/mL
Bromobenzene 5 ug/mL
12/27/2024
9:26:49 AM
Page 35 of 428
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Bromoform 5 ug/mL
Carbon disulfide 5 ug/mL
Carbon tetrachloride 5 ug/mL
Chlorobenzene 5 ug/mL
Chlorobromomethane 5 ug/mL
Chlorodibromomethane 5 ug/mL
Chloroform 5 ug/mL
cis-1,2-Dichloroethene 5 ug/mL
cis-1,3-Dichloropropene 5 ug/mL
Cyclohexane 5 ug/mL
Dibromomethane 5 ug/mL
Dichlorobromomethane 5 ug/mL
Ethyl ether 5 ug/mL
Ethyl methacrylate 5 ug/mL
Ethylbenzene 5 ug/mL
Ethylene Dibromide 5 ug/mL
Hexachlorobutadiene 5 ug/mL
Hexane 5 ug/mL
Iodomethane 5 ug/mL
Isobutyl alcohol 125 ug/mL
Isopropylbenzene 5 ug/mL
m-Xylene & p-Xylene 5 ug/mL
Methyl acetate 10 ug/mL
Methyl tert-butyl ether 5 ug/mL
Methylcyclohexane 5 ug/mL
Methylene Chloride 5 ug/mL
n-Butylbenzene 5 ug/mL
n-Heptane 5 ug/mL
N-Propylbenzene 5 ug/mL
Naphthalene 5 ug/mL
o-Xylene 5 ug/mL
sec-Butylbenzene 5 ug/mL
Styrene 5 ug/mL
tert-Butylbenzene 5 ug/mL
Tetrachloroethene 5 ug/mL
Tetrahydrofuran 10 ug/mL
Toluene 5 ug/mL
trans-1,2-Dichloroethene 5 ug/mL
trans-1,3-Dichloropropene 5 ug/mL
trans-1,4-Dichloro-2-butene 5 ug/mL
Trichloroethene 5 ug/mL
1-Chlorohexane 4 ug/mL
2-Pentanone 16 ug/mL
sec-Butyl Alcohol 120 ug/mL
MV-569722_00024 Bromomethane 250 ug/mL12.5 mL 1250 uL01/13/25 12/13/24.MV-Gas A_00206 P&T Methanol, Lot 198123
Chloroethane 250 ug/mL
Chloromethane 250 ug/mL
12/27/2024
9:26:49 AM
Page 36 of 428
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Dichlorodifluoromethane 250 ug/mL
Dichlorofluoromethane 250 ug/mL
Trichlorofluoromethane 250 ug/mL
Vinyl chloride 250 ug/mL
MV-569723_00019 1250 uL 2-Chloroethyl vinyl ether 250 ug/mL
05/28/27 (Purchased Reagent)Bromomethane 2500 ug/mLRESTEK, Lot A0211969..MV-569722_00024
Chloroethane 2500 ug/mL
Chloromethane 2500 ug/mL
Dichlorodifluoromethane 2500 ug/mL
Dichlorofluoromethane 2500 ug/mL
Trichlorofluoromethane 2500 ug/mL
Vinyl chloride 2500 ug/mL
06/30/27 (Purchased Reagent)2-Chloroethyl vinyl ether 2500 ug/mLRESTEK, Lot A0213181..MV-569723_00019
MV-568720_00049 Acrolein 987.5 ug/mL25 mL 1250 uL01/13/25 12/13/24.MV-MegaMainA_00121 P&T Methanol, Lot EG636-US
2-Butanone (MEK)400 ug/mLMV-569721_00016 800 uL
2-Hexanone 400 ug/mL
4-Methyl-2-pentanone (MIBK)400 ug/mL
Acetone 400 ug/mL
Vinyl acetate 200 ug/mLMV-569724_00038 1000 uL
Cyclohexanone 3000 ug/mLMV-569727_00025 3000 uL
1,1,1,2-Tetrachloroethane 100 ug/mLMV-571992_00017 1000 uL
1,1,1-Trichloroethane 100 ug/mL
1,1,2,2-Tetrachloroethane 100 ug/mL
1,1,2-Trichloro-1,2,2-trifluoroethane 100 ug/mL
1,1,2-Trichloroethane 100 ug/mL
1,1-Dichloroethane 100 ug/mL
1,1-Dichloroethene 100 ug/mL
1,1-Dichloropropene 100 ug/mL
1,2,3-Trichlorobenzene 100 ug/mL
1,2,3-Trichloropropane 100 ug/mL
1,2,4-Trichlorobenzene 100 ug/mL
1,2,4-Trimethylbenzene 100 ug/mL
1,2-Dibromo-3-Chloropropane 100 ug/mL
1,2-Dichlorobenzene 100 ug/mL
1,2-Dichloroethane 100 ug/mL
1,2-Dichloropropane 100 ug/mL
1,3,5-Trimethylbenzene 100 ug/mL
1,3-Dichlorobenzene 100 ug/mL
1,3-Dichloropropane 100 ug/mL
1,4-Dichlorobenzene 100 ug/mL
1,4-Dioxane 2000 ug/mL
2,2-Dichloropropane 100 ug/mL
2-Chlorotoluene 100 ug/mL
2-Methyl-2-propanol 1000 ug/mL
3-Chloro-1-propene 100 ug/mL
4-Chlorotoluene 100 ug/mL
12/27/2024
9:26:49 AM
Page 37 of 428
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
4-Isopropyltoluene 100 ug/mL
Acrylonitrile 1000 ug/mL
Benzene 100 ug/mL
Bromobenzene 100 ug/mL
Bromoform 100 ug/mL
Carbon disulfide 100 ug/mL
Carbon tetrachloride 100 ug/mL
Chlorobenzene 100 ug/mL
Chlorobromomethane 100 ug/mL
Chlorodibromomethane 100 ug/mL
Chloroform 100 ug/mL
cis-1,2-Dichloroethene 100 ug/mL
cis-1,3-Dichloropropene 100 ug/mL
Cyclohexane 100 ug/mL
Dibromomethane 100 ug/mL
Dichlorobromomethane 100 ug/mL
Ethyl ether 100 ug/mL
Ethyl methacrylate 100 ug/mL
Ethylbenzene 100 ug/mL
Ethylene Dibromide 100 ug/mL
Hexachlorobutadiene 100 ug/mL
Hexane 100 ug/mL
Iodomethane 100 ug/mL
Isobutyl alcohol 2500 ug/mL
Isopropylbenzene 100 ug/mL
m-Xylene & p-Xylene 100 ug/mL
Methyl acetate 200 ug/mL
Methyl tert-butyl ether 100 ug/mL
Methylcyclohexane 100 ug/mL
Methylene Chloride 100 ug/mL
n-Butylbenzene 100 ug/mL
n-Heptane 100 ug/mL
N-Propylbenzene 100 ug/mL
Naphthalene 100 ug/mL
o-Xylene 100 ug/mL
sec-Butylbenzene 100 ug/mL
Styrene 100 ug/mL
tert-Butylbenzene 100 ug/mL
Tetrachloroethene 100 ug/mL
Tetrahydrofuran 200 ug/mL
Toluene 100 ug/mL
trans-1,2-Dichloroethene 100 ug/mL
trans-1,3-Dichloropropene 100 ug/mL
trans-1,4-Dichloro-2-butene 100 ug/mL
Trichloroethene 100 ug/mL
1-Chlorohexane 80 ug/mLMV-CUS17739_00017 2000 uL
2-Pentanone 320 ug/mL
12/27/2024
9:26:49 AM
Page 38 of 428
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
sec-Butyl Alcohol 2400 ug/mL
09/30/25 (Purchased Reagent)Acrolein 19750 ug/mLRESTEK, Lot A0209476..MV-568720_00049
04/30/27 (Purchased Reagent)2-Butanone (MEK)12500 ug/mLRESTEK, Lot A0210935..MV-569721_00016
2-Hexanone 12500 ug/mL
4-Methyl-2-pentanone (MIBK)12500 ug/mL
Acetone 12500 ug/mL
09/30/25 (Purchased Reagent)Vinyl acetate 5000 ug/mLRESTEK, Lot A0209567..MV-569724_00038
03/31/27 (Purchased Reagent)Cyclohexanone 25000 ug/mLRESTEK, Lot A0209630..MV-569727_00025
04/30/26 (Purchased Reagent)1,1,1,2-Tetrachloroethane 2500 ug/mLRESTEK, Lot A0203458..MV-571992_00017
1,1,1-Trichloroethane 2500 ug/mL
1,1,2,2-Tetrachloroethane 2500 ug/mL
1,1,2-Trichloro-1,2,2-trifluoroethane 2500 ug/mL
1,1,2-Trichloroethane 2500 ug/mL
1,1-Dichloroethane 2500 ug/mL
1,1-Dichloroethene 2500 ug/mL
1,1-Dichloropropene 2500 ug/mL
1,2,3-Trichlorobenzene 2500 ug/mL
1,2,3-Trichloropropane 2500 ug/mL
1,2,4-Trichlorobenzene 2500 ug/mL
1,2,4-Trimethylbenzene 2500 ug/mL
1,2-Dibromo-3-Chloropropane 2500 ug/mL
1,2-Dichlorobenzene 2500 ug/mL
1,2-Dichloroethane 2500 ug/mL
1,2-Dichloropropane 2500 ug/mL
1,3,5-Trimethylbenzene 2500 ug/mL
1,3-Dichlorobenzene 2500 ug/mL
1,3-Dichloropropane 2500 ug/mL
1,4-Dichlorobenzene 2500 ug/mL
1,4-Dioxane 50000 ug/mL
2,2-Dichloropropane 2500 ug/mL
2-Chlorotoluene 2500 ug/mL
2-Methyl-2-propanol 25000 ug/mL
3-Chloro-1-propene 2500 ug/mL
4-Chlorotoluene 2500 ug/mL
4-Isopropyltoluene 2500 ug/mL
Acrylonitrile 25000 ug/mL
Benzene 2500 ug/mL
Bromobenzene 2500 ug/mL
Bromoform 2500 ug/mL
Carbon disulfide 2500 ug/mL
Carbon tetrachloride 2500 ug/mL
Chlorobenzene 2500 ug/mL
Chlorobromomethane 2500 ug/mL
Chlorodibromomethane 2500 ug/mL
Chloroform 2500 ug/mL
cis-1,2-Dichloroethene 2500 ug/mL
cis-1,3-Dichloropropene 2500 ug/mL
12/27/2024
9:26:49 AM
Page 39 of 428
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Cyclohexane 2500 ug/mL
Dibromomethane 2500 ug/mL
Dichlorobromomethane 2500 ug/mL
Ethyl ether 2500 ug/mL
Ethyl methacrylate 2500 ug/mL
Ethylbenzene 2500 ug/mL
Ethylene Dibromide 2500 ug/mL
Hexachlorobutadiene 2500 ug/mL
Hexane 2500 ug/mL
Iodomethane 2500 ug/mL
Isobutyl alcohol 62500 ug/mL
Isopropylbenzene 2500 ug/mL
m-Xylene & p-Xylene 2500 ug/mL
Methyl acetate 5000 ug/mL
Methyl tert-butyl ether 2500 ug/mL
Methylcyclohexane 2500 ug/mL
Methylene Chloride 2500 ug/mL
n-Butylbenzene 2500 ug/mL
n-Heptane 2500 ug/mL
N-Propylbenzene 2500 ug/mL
Naphthalene 2500 ug/mL
o-Xylene 2500 ug/mL
sec-Butylbenzene 2500 ug/mL
Styrene 2500 ug/mL
tert-Butylbenzene 2500 ug/mL
Tetrachloroethene 2500 ug/mL
Tetrahydrofuran 5000 ug/mL
Toluene 2500 ug/mL
trans-1,2-Dichloroethene 2500 ug/mL
trans-1,3-Dichloropropene 2500 ug/mL
trans-1,4-Dichloro-2-butene 2500 ug/mL
Trichloroethene 2500 ug/mL
08/31/26 (Purchased Reagent)1-Chlorohexane 1000 ug/mLAgilent, Lot 6808538..MV-CUS17739_00017
2-Pentanone 4000 ug/mL
sec-Butyl Alcohol 30000 ug/mL
1,2-Dichloroethene, Totalmv-Cent BFB_00008
1,3-Dichloropropene, Total
Tentatively Identified
Compound
Total BTEX
Trihalomethanes, Total
Xylenes, Total
mv-IS/SS Tune_00002 10 mL BFB 50 ug/mL
05/31/26 (Purchased Reagent)BFB 250 ug/mLRestek, Lot 20401KO/A0172587.mv-IS/SS Tune_00002
MV-569722_00024 Bromomethane 250 ug/mL12.5 mL 1250 uL01/13/25 12/13/24MV-Gas A_00206 P&T Methanol, Lot
198123
Chloroethane 250 ug/mL
12/27/2024
9:26:49 AM
Page 40 of 428
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Chloromethane 250 ug/mL
Dichlorodifluoromethane 250 ug/mL
Dichlorofluoromethane 250 ug/mL
Trichlorofluoromethane 250 ug/mL
Vinyl chloride 250 ug/mL
MV-569723_00019 1250 uL 2-Chloroethyl vinyl ether 250 ug/mL
05/28/27 (Purchased Reagent)Bromomethane 2500 ug/mLRESTEK, Lot A0211969.MV-569722_00024
Chloroethane 2500 ug/mL
Chloromethane 2500 ug/mL
Dichlorodifluoromethane 2500 ug/mL
Dichlorofluoromethane 2500 ug/mL
Trichlorofluoromethane 2500 ug/mL
Vinyl chloride 2500 ug/mL
06/30/27 (Purchased Reagent)2-Chloroethyl vinyl ether 2500 ug/mLRESTEK, Lot A0213181.MV-569723_00019
MV-569722.sec_00020 Bromomethane 250 ug/mL12.5 mL 1250 uL01/13/25 12/10/24MV-Gas B_00177 P&T Methanol, Lot EG636-US
Chloroethane 250 ug/mL
Chloromethane 250 ug/mL
Dichlorodifluoromethane 250 ug/mL
Trichlorofluoromethane 250 ug/mL
Vinyl chloride 250 ug/mL
05/31/27 (Purchased Reagent)Bromomethane 2500 ug/mLRESTEK, Lot A0211505.MV-569722.sec_00020
Chloroethane 2500 ug/mL
Chloromethane 2500 ug/mL
Dichlorodifluoromethane 2500 ug/mL
Trichlorofluoromethane 2500 ug/mL
Vinyl chloride 2500 ug/mL
mv-30241_00014 1,4-Dichlorobenzene-d4 50 ug/mL50 mL 1000 uL04/01/25 11/26/24mv-IS_SS_00093 P&T Methanol, Lot EG636-US
Chlorobenzene-d5 50 ug/mL
Fluorobenzene 50 ug/mL
1,2-Dichloroethane-d4 (Surr)50 ug/mLMV-567650_00033 1000 uL
4-Bromofluorobenzene (Surr)50 ug/mL
Dibromofluoromethane (Surr)50 ug/mL
Toluene-d8 (Surr)50 ug/mL
05/31/28 (Purchased Reagent)1,4-Dichlorobenzene-d4 2500 ug/mLRestek, Lot A0198297.mv-30241_00014
Chlorobenzene-d5 2500 ug/mL
Fluorobenzene 2500 ug/mL
05/31/29 (Purchased Reagent)1,2-Dichloroethane-d4 (Surr)2500 ug/mLRestek, Lot A0211048.MV-567650_00033
4-Bromofluorobenzene (Surr)2500 ug/mL
Dibromofluoromethane (Surr)2500 ug/mL
Toluene-d8 (Surr)2500 ug/mL
mv-30241_00014 1,4-Dichlorobenzene-d4 50 ug/mL50 mL 1000 uL04/01/25 12/13/24mv-IS_SS_00094 P&T Methanol, Lot EG636-US
Chlorobenzene-d5 50 ug/mL
Fluorobenzene 50 ug/mL
05/31/28 (Purchased Reagent)1,4-Dichlorobenzene-d4 2500 ug/mLRestek, Lot A0198297.mv-30241_00014
12/27/2024
9:26:49 AM
Page 41 of 428
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Chlorobenzene-d5 2500 ug/mL
Fluorobenzene 2500 ug/mL
MV-567650_00033 1,2-Dichloroethane-d4 (Surr)50 ug/mL50 mL 1000 uL04/01/25 12/13/24mv-IS_SS_00094 P&T Methanol, Lot EG636-US
4-Bromofluorobenzene (Surr)50 ug/mL
Dibromofluoromethane (Surr)50 ug/mL
Toluene-d8 (Surr)50 ug/mL
05/31/29 (Purchased Reagent)1,2-Dichloroethane-d4 (Surr)2500 ug/mLRestek, Lot A0211048.MV-567650_00033
4-Bromofluorobenzene (Surr)2500 ug/mL
Dibromofluoromethane (Surr)2500 ug/mL
Toluene-d8 (Surr)2500 ug/mL
MV-569721.sec_00013 2-Butanone (MEK)400 ug/mL25 mL 800 uL12/30/24 11/26/24MV-MegaMain B_00112 P&T Methanol, Lot EG-636-US
2-Hexanone 400 ug/mL
4-Methyl-2-pentanone (MIBK)400 ug/mL
Acetone 400 ug/mL
Vinyl acetate 200 ug/mLMV-569724.sec_00038 1000 uL
1,1,1,2-Tetrachloroethane 100 ug/mLMV-571992.sec_00010 1000 uL
1,1,1-Trichloroethane 100 ug/mL
1,1,2,2-Tetrachloroethane 100 ug/mL
1,1,2-Trichloro-1,2,2-trifluoroethane 100 ug/mL
1,1,2-Trichloroethane 100 ug/mL
1,1-Dichloroethane 100 ug/mL
1,1-Dichloroethene 100 ug/mL
1,1-Dichloropropene 100 ug/mL
1,2,3-Trichlorobenzene 100 ug/mL
1,2,3-Trichloropropane 100 ug/mL
1,2,4-Trichlorobenzene 100 ug/mL
1,2,4-Trimethylbenzene 100 ug/mL
1,2-Dibromo-3-Chloropropane 100 ug/mL
1,2-Dichlorobenzene 100 ug/mL
1,2-Dichloroethane 100 ug/mL
1,2-Dichloroethene, Total 200 ug/mL
1,2-Dichloropropane 100 ug/mL
1,3,5-Trimethylbenzene 100 ug/mL
1,3-Dichlorobenzene 100 ug/mL
1,3-Dichloropropane 100 ug/mL
1,3-Dichloropropene, Total 200 ug/mL
1,4-Dichlorobenzene 100 ug/mL
2,2-Dichloropropane 100 ug/mL
2-Chlorotoluene 100 ug/mL
3-Chloro-1-propene 100 ug/mL
4-Chlorotoluene 100 ug/mL
4-Isopropyltoluene 100 ug/mL
Benzene 100 ug/mL
Bromobenzene 100 ug/mL
12/27/2024
9:26:49 AM
Page 42 of 428
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Bromoform 100 ug/mL
Carbon disulfide 100 ug/mL
Carbon tetrachloride 100 ug/mL
Chlorobenzene 100 ug/mL
Chlorobromomethane 100 ug/mL
Chlorodibromomethane 100 ug/mL
Chloroform 100 ug/mL
cis-1,2-Dichloroethene 100 ug/mL
cis-1,3-Dichloropropene 100 ug/mL
Cyclohexane 100 ug/mL
Dibromomethane 100 ug/mL
Dichlorobromomethane 100 ug/mL
Ethyl ether 100 ug/mL
Ethyl methacrylate 100 ug/mL
Ethylbenzene 100 ug/mL
Ethylene Dibromide 100 ug/mL
Hexachlorobutadiene 100 ug/mL
Hexane 100 ug/mL
Iodomethane 100 ug/mL
Isopropylbenzene 100 ug/mL
m-Xylene & p-Xylene 100 ug/mL
Methyl acetate 200 ug/mL
Methyl tert-butyl ether 100 ug/mL
Methylcyclohexane 100 ug/mL
Methylene Chloride 100 ug/mL
n-Butylbenzene 100 ug/mL
N-Propylbenzene 100 ug/mL
Naphthalene 100 ug/mL
o-Xylene 100 ug/mL
sec-Butylbenzene 100 ug/mL
Styrene 100 ug/mL
tert-Butylbenzene 100 ug/mL
Tetrachloroethene 100 ug/mL
Tetrahydrofuran 200 ug/mL
Toluene 100 ug/mL
trans-1,2-Dichloroethene 100 ug/mL
trans-1,3-Dichloropropene 100 ug/mL
Trichloroethene 100 ug/mL
Trihalomethanes, Total 400 ug/mL
Xylenes, Total 200 ug/mL
04/30/27 (Purchased Reagent)2-Butanone (MEK)12500 ug/mLRESTEK, Lot A0209876.MV-569721.sec_00013
2-Hexanone 12500 ug/mL
4-Methyl-2-pentanone (MIBK)12500 ug/mL
Acetone 12500 ug/mL
10/31/25 (Purchased Reagent)Vinyl acetate 5000 ug/mLRESTEK, Lot A0210661.MV-569724.sec_00038
08/31/25 (Purchased Reagent)1,1,1,2-Tetrachloroethane 2500 ug/mLRESTEK, Lot A0195252.MV-571992.sec_00010
1,1,1-Trichloroethane 2500 ug/mL
12/27/2024
9:26:49 AM
Page 43 of 428
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
1,1,2,2-Tetrachloroethane 2500 ug/mL
1,1,2-Trichloro-1,2,2-trifluoroethane 2500 ug/mL
1,1,2-Trichloroethane 2500 ug/mL
1,1-Dichloroethane 2500 ug/mL
1,1-Dichloroethene 2500 ug/mL
1,1-Dichloropropene 2500 ug/mL
1,2,3-Trichlorobenzene 2500 ug/mL
1,2,3-Trichloropropane 2500 ug/mL
1,2,4-Trichlorobenzene 2500 ug/mL
1,2,4-Trimethylbenzene 2500 ug/mL
1,2-Dibromo-3-Chloropropane 2500 ug/mL
1,2-Dichlorobenzene 2500 ug/mL
1,2-Dichloroethane 2500 ug/mL
1,2-Dichloroethene, Total 5000 ug/mL
1,2-Dichloropropane 2500 ug/mL
1,3,5-Trimethylbenzene 2500 ug/mL
1,3-Dichlorobenzene 2500 ug/mL
1,3-Dichloropropane 2500 ug/mL
1,3-Dichloropropene, Total 5000 ug/mL
1,4-Dichlorobenzene 2500 ug/mL
2,2-Dichloropropane 2500 ug/mL
2-Chlorotoluene 2500 ug/mL
3-Chloro-1-propene 2500 ug/mL
4-Chlorotoluene 2500 ug/mL
4-Isopropyltoluene 2500 ug/mL
Benzene 2500 ug/mL
Bromobenzene 2500 ug/mL
Bromoform 2500 ug/mL
Carbon disulfide 2500 ug/mL
Carbon tetrachloride 2500 ug/mL
Chlorobenzene 2500 ug/mL
Chlorobromomethane 2500 ug/mL
Chlorodibromomethane 2500 ug/mL
Chloroform 2500 ug/mL
cis-1,2-Dichloroethene 2500 ug/mL
cis-1,3-Dichloropropene 2500 ug/mL
Cyclohexane 2500 ug/mL
Dibromomethane 2500 ug/mL
Dichlorobromomethane 2500 ug/mL
Ethyl ether 2500 ug/mL
Ethyl methacrylate 2500 ug/mL
Ethylbenzene 2500 ug/mL
Ethylene Dibromide 2500 ug/mL
Hexachlorobutadiene 2500 ug/mL
Hexane 2500 ug/mL
Iodomethane 2500 ug/mL
Isopropylbenzene 2500 ug/mL
12/27/2024
9:26:49 AM
Page 44 of 428
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
m-Xylene & p-Xylene 2500 ug/mL
Methyl acetate 5000 ug/mL
Methyl tert-butyl ether 2500 ug/mL
Methylcyclohexane 2500 ug/mL
Methylene Chloride 2500 ug/mL
n-Butylbenzene 2500 ug/mL
N-Propylbenzene 2500 ug/mL
Naphthalene 2500 ug/mL
o-Xylene 2500 ug/mL
sec-Butylbenzene 2500 ug/mL
Styrene 2500 ug/mL
tert-Butylbenzene 2500 ug/mL
Tetrachloroethene 2500 ug/mL
Tetrahydrofuran 5000 ug/mL
Toluene 2500 ug/mL
trans-1,2-Dichloroethene 2500 ug/mL
trans-1,3-Dichloropropene 2500 ug/mL
Trichloroethene 2500 ug/mL
Trihalomethanes, Total 10000 ug/mL
Xylenes, Total 5000 ug/mL
MV-568720_00049 Acrolein 987.5 ug/mL25 mL 1250 uL01/13/25 12/13/24MV-MegaMainA_00121 P&T Methanol, Lot EG636-US
2-Butanone (MEK)400 ug/mLMV-569721_00016 800 uL
2-Hexanone 400 ug/mL
4-Methyl-2-pentanone (MIBK)400 ug/mL
Acetone 400 ug/mL
Vinyl acetate 200 ug/mLMV-569724_00038 1000 uL
Cyclohexanone 3000 ug/mLMV-569727_00025 3000 uL
1,1,1,2-Tetrachloroethane 100 ug/mLMV-571992_00017 1000 uL
1,1,1-Trichloroethane 100 ug/mL
1,1,2,2-Tetrachloroethane 100 ug/mL
1,1,2-Trichloro-1,2,2-trifluoroethane 100 ug/mL
1,1,2-Trichloroethane 100 ug/mL
1,1-Dichloroethane 100 ug/mL
1,1-Dichloroethene 100 ug/mL
1,1-Dichloropropene 100 ug/mL
1,2,3-Trichlorobenzene 100 ug/mL
1,2,3-Trichloropropane 100 ug/mL
1,2,4-Trichlorobenzene 100 ug/mL
1,2,4-Trimethylbenzene 100 ug/mL
1,2-Dibromo-3-Chloropropane 100 ug/mL
1,2-Dichlorobenzene 100 ug/mL
1,2-Dichloroethane 100 ug/mL
1,2-Dichloropropane 100 ug/mL
1,3,5-Trimethylbenzene 100 ug/mL
1,3-Dichlorobenzene 100 ug/mL
12/27/2024
9:26:49 AM
Page 45 of 428
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
1,3-Dichloropropane 100 ug/mL
1,4-Dichlorobenzene 100 ug/mL
1,4-Dioxane 2000 ug/mL
2,2-Dichloropropane 100 ug/mL
2-Chlorotoluene 100 ug/mL
2-Methyl-2-propanol 1000 ug/mL
3-Chloro-1-propene 100 ug/mL
4-Chlorotoluene 100 ug/mL
4-Isopropyltoluene 100 ug/mL
Acrylonitrile 1000 ug/mL
Benzene 100 ug/mL
Bromobenzene 100 ug/mL
Bromoform 100 ug/mL
Carbon disulfide 100 ug/mL
Carbon tetrachloride 100 ug/mL
Chlorobenzene 100 ug/mL
Chlorobromomethane 100 ug/mL
Chlorodibromomethane 100 ug/mL
Chloroform 100 ug/mL
cis-1,2-Dichloroethene 100 ug/mL
cis-1,3-Dichloropropene 100 ug/mL
Cyclohexane 100 ug/mL
Dibromomethane 100 ug/mL
Dichlorobromomethane 100 ug/mL
Ethyl ether 100 ug/mL
Ethyl methacrylate 100 ug/mL
Ethylbenzene 100 ug/mL
Ethylene Dibromide 100 ug/mL
Hexachlorobutadiene 100 ug/mL
Hexane 100 ug/mL
Iodomethane 100 ug/mL
Isobutyl alcohol 2500 ug/mL
Isopropylbenzene 100 ug/mL
m-Xylene & p-Xylene 100 ug/mL
Methyl acetate 200 ug/mL
Methyl tert-butyl ether 100 ug/mL
Methylcyclohexane 100 ug/mL
Methylene Chloride 100 ug/mL
n-Butylbenzene 100 ug/mL
n-Heptane 100 ug/mL
N-Propylbenzene 100 ug/mL
Naphthalene 100 ug/mL
o-Xylene 100 ug/mL
sec-Butylbenzene 100 ug/mL
Styrene 100 ug/mL
tert-Butylbenzene 100 ug/mL
Tetrachloroethene 100 ug/mL
12/27/2024
9:26:49 AM
Page 46 of 428
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Tetrahydrofuran 200 ug/mL
Toluene 100 ug/mL
trans-1,2-Dichloroethene 100 ug/mL
trans-1,3-Dichloropropene 100 ug/mL
trans-1,4-Dichloro-2-butene 100 ug/mL
Trichloroethene 100 ug/mL
1-Chlorohexane 80 ug/mLMV-CUS17739_00017 2000 uL
2-Pentanone 320 ug/mL
sec-Butyl Alcohol 2400 ug/mL
09/30/25 (Purchased Reagent)Acrolein 19750 ug/mLRESTEK, Lot A0209476.MV-568720_00049
04/30/27 (Purchased Reagent)2-Butanone (MEK)12500 ug/mLRESTEK, Lot A0210935.MV-569721_00016
2-Hexanone 12500 ug/mL
4-Methyl-2-pentanone (MIBK)12500 ug/mL
Acetone 12500 ug/mL
09/30/25 (Purchased Reagent)Vinyl acetate 5000 ug/mLRESTEK, Lot A0209567.MV-569724_00038
03/31/27 (Purchased Reagent)Cyclohexanone 25000 ug/mLRESTEK, Lot A0209630.MV-569727_00025
04/30/26 (Purchased Reagent)1,1,1,2-Tetrachloroethane 2500 ug/mLRESTEK, Lot A0203458.MV-571992_00017
1,1,1-Trichloroethane 2500 ug/mL
1,1,2,2-Tetrachloroethane 2500 ug/mL
1,1,2-Trichloro-1,2,2-trifluoroethane 2500 ug/mL
1,1,2-Trichloroethane 2500 ug/mL
1,1-Dichloroethane 2500 ug/mL
1,1-Dichloroethene 2500 ug/mL
1,1-Dichloropropene 2500 ug/mL
1,2,3-Trichlorobenzene 2500 ug/mL
1,2,3-Trichloropropane 2500 ug/mL
1,2,4-Trichlorobenzene 2500 ug/mL
1,2,4-Trimethylbenzene 2500 ug/mL
1,2-Dibromo-3-Chloropropane 2500 ug/mL
1,2-Dichlorobenzene 2500 ug/mL
1,2-Dichloroethane 2500 ug/mL
1,2-Dichloropropane 2500 ug/mL
1,3,5-Trimethylbenzene 2500 ug/mL
1,3-Dichlorobenzene 2500 ug/mL
1,3-Dichloropropane 2500 ug/mL
1,4-Dichlorobenzene 2500 ug/mL
1,4-Dioxane 50000 ug/mL
2,2-Dichloropropane 2500 ug/mL
2-Chlorotoluene 2500 ug/mL
2-Methyl-2-propanol 25000 ug/mL
3-Chloro-1-propene 2500 ug/mL
4-Chlorotoluene 2500 ug/mL
4-Isopropyltoluene 2500 ug/mL
Acrylonitrile 25000 ug/mL
Benzene 2500 ug/mL
Bromobenzene 2500 ug/mL
Bromoform 2500 ug/mL
12/27/2024
9:26:49 AM
Page 47 of 428
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
Carbon disulfide 2500 ug/mL
Carbon tetrachloride 2500 ug/mL
Chlorobenzene 2500 ug/mL
Chlorobromomethane 2500 ug/mL
Chlorodibromomethane 2500 ug/mL
Chloroform 2500 ug/mL
cis-1,2-Dichloroethene 2500 ug/mL
cis-1,3-Dichloropropene 2500 ug/mL
Cyclohexane 2500 ug/mL
Dibromomethane 2500 ug/mL
Dichlorobromomethane 2500 ug/mL
Ethyl ether 2500 ug/mL
Ethyl methacrylate 2500 ug/mL
Ethylbenzene 2500 ug/mL
Ethylene Dibromide 2500 ug/mL
Hexachlorobutadiene 2500 ug/mL
Hexane 2500 ug/mL
Iodomethane 2500 ug/mL
Isobutyl alcohol 62500 ug/mL
Isopropylbenzene 2500 ug/mL
m-Xylene & p-Xylene 2500 ug/mL
Methyl acetate 5000 ug/mL
Methyl tert-butyl ether 2500 ug/mL
Methylcyclohexane 2500 ug/mL
Methylene Chloride 2500 ug/mL
n-Butylbenzene 2500 ug/mL
n-Heptane 2500 ug/mL
N-Propylbenzene 2500 ug/mL
Naphthalene 2500 ug/mL
o-Xylene 2500 ug/mL
sec-Butylbenzene 2500 ug/mL
Styrene 2500 ug/mL
tert-Butylbenzene 2500 ug/mL
Tetrachloroethene 2500 ug/mL
Tetrahydrofuran 5000 ug/mL
Toluene 2500 ug/mL
trans-1,2-Dichloroethene 2500 ug/mL
trans-1,3-Dichloropropene 2500 ug/mL
trans-1,4-Dichloro-2-butene 2500 ug/mL
Trichloroethene 2500 ug/mL
08/31/26 (Purchased Reagent)1-Chlorohexane 1000 ug/mLAgilent, Lot 6808538.MV-CUS17739_00017
2-Pentanone 4000 ug/mL
sec-Butyl Alcohol 30000 ug/mL
MV-571992_00017 1,2-Dichloroethene, Total 200 ug/mL25 mL 1000 uL01/13/25 12/13/24MV-MegaMainA_00121 P&T Methanol, Lot EG636-US
1,3-Dichloropropene, Total 200 ug/mL
Trihalomethanes, Total 400 ug/mL
Xylenes, Total 200 ug/mL
12/27/2024
9:26:49 AM
Page 48 of 428
REAGENT TRACEABILITY SUMMARY
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Reagent ID
Exp
Date Date
Prep Dilutant
Used
Reagent
Final
Volume
Parent Reagent
Reagent ID
Volume
Added ConcentrationAnalyte
04/30/26 (Purchased Reagent)1,2-Dichloroethene, Total 5000 ug/mLRESTEK, Lot A0203458.MV-571992_00017
1,3-Dichloropropene, Total 5000 ug/mL
Trihalomethanes, Total 10000 ug/mL
Xylenes, Total 5000 ug/mL
12/27/2024
9:26:49 AM
Page 49 of 428
Reagent
mv-30241_00014
12/27/2024
9:26:49 AM
Page 50 of 428
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :30241 Lot No.:A0198297
8260A Internal Standard MixDescription :
8260A Internal Standard Mix 2,500 µg/mL, P&T Methanol, 1mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
2 mL > 1 mLPkg Amt:
May 31, 2028
Ship:Ambient
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 2,504.7Fluorobenzene462-06-6 +/- 140.7155BCBZ5549
99% 2 µg/mL 2,513.3Chlorobenzene-d5 3114-55-4 +/- 141.2024PR-29571
99% 3 µg/mL 2,515.31,4-Dichlorobenzene-d4 3855-82-1 +/- 141.3148PR-30447
Solvent:P&T Methanol
99%
67-56-1CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
12/27/2024
9:26:49 AM
Page 51 of 428
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
105m x 0.53mm x 3.0µm
Rtx-502.2 (cat.#10910)
Column:
hydrogen-constant pressure 11.0 psi.
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
FID
1128342314Balance Serial #
24-May-2023Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
22-May-2023Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
40 ml/min
Inj. Vol
1µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
12/27/2024
9:26:49 AM
Page 52 of 428
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
12/27/2024
9:26:49 AM
Page 53 of 428
Reagent
MV-567650_00033
12/27/2024
9:26:49 AM
Page 54 of 428
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :567650 Lot No.:A0211048
8260 Surrogate StandardDescription :
8260 Surrogate Standard 2,500µg/mL, P&T Methanol, 5mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
5 mL > 5 mLPkg Amt:
May 31, 2029
Ship:Ambient
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 2,502.2Dibromofluoromethane1868-53-7 +/- 140.5627022013
99% 2 µg/mL 2,501.31,2-Dichloroethane-d4 17060-07-0 +/- 140.5094PR-33313
99% 3 µg/mL 2,502.8Toluene-d8 2037-26-5 +/- 140.5965PR-34141
99% 4 µg/mL 2,501.61-Bromo-4-fluorobenzene (BFB)460-00-4 +/- 140.52620000194533
Solvent:P&T Methanol
99%
67-56-1CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
12/27/2024
9:26:49 AM
Page 55 of 428
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
105m x 0.53mm x 3.0µm
Rtx-502.2 (cat.#10910)
Column:
hydrogen-constant pressure 11.0 psi.
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
FID
1128342314Balance Serial #
06-May-2024Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
03-May-2024Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
40 ml/min
Inj. Vol
1µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
12/27/2024
9:26:49 AM
Page 56 of 428
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
12/27/2024
9:26:49 AM
Page 57 of 428
Reagent
MV-568720_00049
12/27/2024
9:26:49 AM
Page 58 of 428
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :568720 Lot No.:A0209476
8260 List 1/Std #5 Acrolein HighDescription :
8260 List 1/Std #5 Acrolein High 19,750µg/mL, Water, 1mL/ampul
Container Size :
Expiration Date :Storage:-20°C or colder
2 mL > 1 mLPkg Amt:
Handling:This product is photosensitive.
September 30, 2025
Ship:On Ice
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 19,917.5Acrolein107-02-8 +/- 585.1357RP240118CTH
Solvent:Water
99%
7732-18-5CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
12/27/2024
9:26:49 AM
Page 59 of 428
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
105m x 0.53mm x 3.0µm
Rtx-502.2 (cat.#10910)
Column:
hydrogen-constant pressure 11.0 psi.
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
FID
1128360905Balance Serial #
01-Apr-2024Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
26-Mar-2024Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
40 ml/min
Inj. Vol
1µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
12/27/2024
9:26:49 AM
Page 60 of 428
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
12/27/2024
9:26:49 AM
Page 61 of 428
Reagent
MV-569721.sec_00013
12/27/2024
9:26:49 AM
Page 62 of 428
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :569721.SEC Lot No.:A0209876
8260 List 1/ Std #2 Ketones (2015)Description :
8260 List 1/ Std #2 Ketones (2015) 12,500µg/mL, P&T Methanol/Water
(90:10), 1mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
2 mL > 1 mLPkg Amt:
April 30, 2027
Ship:Ambient
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 12,580.0Acetone67-64-1.SEC +/- 434.7940U19I024
99% 2 µg/mL 12,611.62-Butanone (MEK)78-93-3.SEC +/- 435.8862HDLUO
99% 3 µg/mL 12,576.44-Methyl-2-pentanone (MIBK)108-10-1.SEC +/- 434.6696E29T040
99% 4 µg/mL 12,574.82-Hexanone 591-78-6.SEC +/- 434.6143NXXXA
Solvent:P&T Methanol/Water (90:10)
99%
67-56-1/7732-18-5CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
12/27/2024
9:26:49 AM
Page 63 of 428
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
105m x 0.53mm x 3.0µm
Rtx-502.2 (cat.#10910)
Column:
hydrogen-constant pressure 11.0 psi.
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
FID
1127510105Balance Serial #
09-Apr-2024Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
05-Apr-2024Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
40 ml/min
Inj. Vol
0.2µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
12/27/2024
9:26:49 AM
Page 64 of 428
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
12/27/2024
9:26:49 AM
Page 65 of 428
Reagent
MV-569721_00016
12/27/2024
9:26:49 AM
Page 66 of 428
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :569721 Lot No.:A0210935
8260 List 1/ Std #2 Ketones (2015)Description :
8260 List 1/ Std #2 Ketones (2015) 12,500µg/mL, P&T Methanol/Water
(90:10), 1mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
2 mL > 1 mLPkg Amt:
April 30, 2027
Ship:Ambient
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 12,591.3Acetone67-64-1 +/- 435.1857SHBQ8504
99% 2 µg/mL 12,561.02-Butanone (MEK)78-93-3 +/- 434.1373SHBQ4704
99% 3 µg/mL 12,580.04-Methyl-2-pentanone (MIBK)108-10-1 +/- 434.7940SHBP9200
99% 4 µg/mL 12,580.72-Hexanone 591-78-6 +/- 434.8170MKCV1997
Solvent:P&T Methanol/Water (90:10)
99%
67-56-1/7732-18-5CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
12/27/2024
9:26:49 AM
Page 67 of 428
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
105m x 0.53mm x 3.0µm
Rtx-502.2 (cat.#10910)
Column:
hydrogen-constant pressure 11.0 psi.
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
FID
B707717271Balance Serial #
02-May-2024Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
30-Apr-2024Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
40 ml/min
Inj. Vol
0.2µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
12/27/2024
9:26:49 AM
Page 68 of 428
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
12/27/2024
9:26:49 AM
Page 69 of 428
Reagent
MV-569722.sec_00020
12/27/2024
9:26:49 AM
Page 70 of 428
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :569722.SEC Lot No.:A0211505
8260 List 1 / Std #3 Gases (2015)Description :
8260 List 1 / Std #3 Gases (2015) 2,500µg/mL, P&T Methanol,
1mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
2 mL > 1 mLPkg Amt:
May 31, 2027
Ship:Ambient
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 2,506.6Dichlorodifluoromethane (CFC-12)75-71-8.SEC +/- 141.955728888
99% 2 µg/mL 2,508.3Chloromethane (methyl chloride)74-87-3.SEC +/- 142.103900022694
99% 3 µg/mL 2,513.8Vinyl chloride 75-01-4 *+/- 142.723500015559
99% 4 µg/mL 2,508.81,3-Butadiene 106-99-0.SEC +/- 142.027528539
99% 5 µg/mL 2,535.7Bromomethane (methyl bromide)74-83-9 *+/- 145.748700017022
99% 6 µg/mL 2,503.6Chloroethane (ethyl chloride)75-00-3.SEC +/- 141.418100021903
90% 7 µg/mL 2,523.6Dichlorofluoromethane (CFC-21)75-43-4 *+/- 141.779214485600
99% 8 µg/mL 2,509.1Trichlorofluoromethane (CFC-11)75-69-4.SEC +/- 141.818400010739
Solvent:P&T Methanol
99%
67-56-1CAS #
Purity
* Restek is unable to identify a reliable and/or acceptable second source for this material - the same batch of neat
material may have been used to produce both the primary and secondary standard. The primary and secondary
standards were prepared using different equipment and personnel.
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
12/27/2024
9:26:49 AM
Page 71 of 428
Raw material may contain trace amounts of tert-Butanol.
Tech Tips:
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
60m x 0.25mm x 1.4µm
Rtx-502.2 (cat.#10916)
Column:
helium-constant pressure 30 psi
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
MSD
1127510105Balance Serial #
21-May-2024Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
15-May-2024Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
25.0 ml/min.
Inj. Vol
1µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
12/27/2024
9:26:49 AM
Page 72 of 428
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
12/27/2024
9:26:49 AM
Page 73 of 428
Reagent
MV-569722_00024
12/27/2024
9:26:49 AM
Page 74 of 428
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :569722 Lot No.:A0211969
8260 List 1 / Std #3 Gases (2015)Description :
8260 List 1 / Std #3 Gases (2015) 2,500µg/mL, P&T Methanol,
1mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
2 mL > 1 mLPkg Amt:
May 31, 2027
Ship:Ambient
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 2,523.8Dichlorodifluoromethane (CFC-12)75-71-8 +/- 142.430100022922
99% 2 µg/mL 2,527.3Chloromethane (methyl chloride)74-87-3 +/- 142.5086SHBP8835
99% 3 µg/mL 2,526.1Vinyl chloride 75-01-4 +/- 142.407500015559
99% 4 µg/mL 2,523.91,3-Butadiene 106-99-0 +/- 142.385100019375
99% 5 µg/mL 2,520.8Bromomethane (methyl bromide)74-83-9 +/- 142.696200017022
99% 6 µg/mL 2,520.7Chloroethane (ethyl chloride)75-00-3 +/- 142.3441107-401039114-1
90% 7 µg/mL 2,524.5Dichlorofluoromethane (CFC-21)75-43-4 +/- 141.815514485600
99% 8 µg/mL 2,518.0Trichlorofluoromethane (CFC-11)75-69-4 +/- 141.8687MKCJ8658
Solvent:P&T Methanol
99%
67-56-1CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
12/27/2024
9:26:49 AM
Page 75 of 428
Raw material may contain trace amounts of tert-Butanol.
Tech Tips:
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
60m x 0.25mm x 1.4µm
Rtx-502.2 (cat.#10916)
Column:
helium-constant pressure 30 psi
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
MSD
B707717271Balance Serial #
04-Jun-2024Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
23-May-2024Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
25.0 ml/min.
Inj. Vol
1µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
12/27/2024
9:26:49 AM
Page 76 of 428
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
12/27/2024
9:26:49 AM
Page 77 of 428
Reagent
MV-569723_00019
12/27/2024
9:26:49 AM
Page 78 of 428
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :569723 Lot No.:A0213181
8260 List 1 / Std #4 2-CEVE (2015)Description :
8260 List 1 / Std #4 2-CEVE (2015) 2,500µg/mL, P&T Methanol,
1mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
2 mL > 1 mLPkg Amt:
June 30, 2027
Ship:Ambient
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 2,508.82-Chloroethyl vinyl ether 110-75-8 +/- 31.2225MKCV7865
Solvent:P&T Methanol
99%
67-56-1CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
Degradation of tetrachloroethylene to pentachloroethane may occur if solutions containing 2-chloroethyl vinyl ether are combined
with solutions that contain tetrachloroethylene.
Tech Tips:
01-Nov-2022 rev.Page 1 of 3
12/27/2024
9:26:49 AM
Page 79 of 428
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
105m x 0.53mm x 3.0µm
Rtx-502.2 (cat.#10910)
Column:
hydrogen-constant pressure 11.0 psi.
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
FID
B251644995Balance Serial #
27-Jun-2024Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
25-Jun-2024Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
40 ml/min
Inj. Vol
0.2µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
12/27/2024
9:26:49 AM
Page 80 of 428
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
12/27/2024
9:26:49 AM
Page 81 of 428
Reagent
MV-569724.sec_00038
12/27/2024
9:26:49 AM
Page 82 of 428
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :569724.SEC Lot No.:A0210661
8260 List 1 / Std #6 Vinyl Acetate (2015)Description :
8260 List 1 / Std #6 Vinyl Acetate (2015) 5,000µg/mL, P&T Methanol,
1mL/ampul
Container Size :
Expiration Date :Storage:-20°C or colder
2 mL > 1 mLPkg Amt:
Handling:This product is photosensitive.
October 31, 2025
Ship:On Ice
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
98% 1 µg/mL 5,046.0Vinyl acetate 108-05-4.SEC +/- 174.4022RD230301RSRA
Solvent:P&T Methanol
99%
67-56-1CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
Vinyl acetate is a volatile organic ester included in the target lists of several US EPA and other methods. Under acidic conditions,
esters react with alcohols to form new esters (transesterification). Methanol-based mixes containing halogenated compounds are
slightly acidic, so it is important to minimize exposure of vinyl acetate to mixes of halogenated compounds in methanol. For this
reason, we offer vinyl acetate in individual solution, and suggest that it be introduced into the working level calibration solution
immediately before use. This will minimize problems and ensure more consistent results.
Tech Tips:
01-Nov-2022 rev.Page 1 of 3
12/27/2024
9:26:49 AM
Page 83 of 428
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
105m x 0.53mm x 3.0µm
Rtx-502.2 (cat.#10910)
Column:
hydrogen-constant pressure 11.0 psi.
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
FID
1128342314Balance Serial #
25-Apr-2024Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
23-Apr-2024Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
40 ml/min
Inj. Vol
0.2µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
12/27/2024
9:26:49 AM
Page 84 of 428
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
12/27/2024
9:26:49 AM
Page 85 of 428
Reagent
MV-569724_00038
12/27/2024
9:26:49 AM
Page 86 of 428
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :569724 Lot No.:A0209567
8260 List 1 / Std #6 Vinyl Acetate (2015)Description :
8260 List 1 / Std #6 Vinyl Acetate (2015) 5,000µg/mL, P&T Methanol,
1mL/ampul
Container Size :
Expiration Date :Storage:-20°C or colder
2 mL > 1 mLPkg Amt:
Handling:This product is photosensitive.
September 30, 2025
Ship:On Ice
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
98% 1 µg/mL 5,034.8Vinyl acetate 108-05-4 +/- 173.9777RP231030CTH
Solvent:P&T Methanol
99%
67-56-1CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
Vinyl acetate is a volatile organic ester included in the target lists of several US EPA and other methods. Under acidic conditions,
esters react with alcohols to form new esters (transesterification). Methanol-based mixes containing halogenated compounds are
slightly acidic, so it is important to minimize exposure of vinyl acetate to mixes of halogenated compounds in methanol. For this
reason, we offer vinyl acetate in individual solution, and suggest that it be introduced into the working level calibration solution
immediately before use. This will minimize problems and ensure more consistent results.
Tech Tips:
01-Nov-2022 rev.Page 1 of 3
12/27/2024
9:26:49 AM
Page 87 of 428
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
105m x 0.53mm x 3.0µm
Rtx-502.2 (cat.#10910)
Column:
hydrogen-constant pressure 11.0 psi.
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
FID
B251644995Balance Serial #
29-Mar-2024Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
27-Mar-2024Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
40 ml/min
Inj. Vol
0.2µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
12/27/2024
9:26:49 AM
Page 88 of 428
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
12/27/2024
9:26:49 AM
Page 89 of 428
Reagent
MV-569727_00025
12/27/2024
9:26:49 AM
Page 90 of 428
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :569727 Lot No.:A0209630
8260 List 2/ Std #3 Cyclohexanone (2015)Description :
8260 List 2/ Std #3 Cyclohexanone (2015) 25,000µg/mL, Water,
1mL/ampul
Container Size :
Expiration Date :Storage:10°C or colder
2 mL > 1 mLPkg Amt:
March 31, 2027
Ship:Ambient
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 25,225.0Cyclohexanone108-94-1 +/- 871.8345MKCS0133
Solvent:Water
99%
7732-18-5CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 1 of 3
12/27/2024
9:26:49 AM
Page 91 of 428
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
105m x 0.53mm x 3.0µm
Rtx-502.2 (cat.#10910)
Column:
hydrogen-constant pressure 11.0 psi.
40°C (hold 2 min.) to 240°C
@ 8°C/min. (hold 5 min.)
200°C
250°C
FID
1128360905Balance Serial #
02-Apr-2024Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
29-Mar-2024Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
40 ml/min
Inj. Vol
1µl
Split Vent:
01-Nov-2022 rev.Page 2 of 3
12/27/2024
9:26:49 AM
Page 92 of 428
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 3 of 3
12/27/2024
9:26:49 AM
Page 93 of 428
Reagent
MV-571992.sec_00010
12/27/2024
9:26:49 AM
Page 94 of 428
12/27/2024
9:26:49 AM
Page 95 of 428
12/27/2024
9:26:49 AM
Page 96 of 428
12/27/2024
9:26:49 AM
Page 97 of 428
12/27/2024
9:26:49 AM
Page 98 of 428
Reagent
MV-571992_00017
12/27/2024
9:26:49 AM
Page 99 of 428
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
CERTIFIED REFERENCE MATERIAL
chromatographic plus
Certificate of Analysis
Catalog No. :571992 Lot No.:A0203458
8260 List 1 / Std #1 MegaMix (2017)Description :
8260 List 1 / Std #1 MegaMix (2017) 1,250-62,500µg/mL, P&T Methanol,
1mL/ampul
Container Size :
Expiration Date :Storage:0°C or colder
2 mL > 1 mLPkg Amt:
April 30, 2026
Ship:Ambient
Elution
Order Compound Grav. Conc.
(weight/volume)
Expanded
Uncertainty *
(95% C.L.; K=2)
C E R T I F I E D V A L U E S
CAS #Lot #Purity
99% 1 µg/mL 2,515.0Diethyl ether (ethyl ether)60-29-7 +/- 86.9068SHBQ1495
99% 2 µg/mL 2,518.81,1,2-Trichlorotrifluoroethane (CFC-113)76-13-1 +/- 87.036400016133
99% 3 µg/mL 2,516.31,1-dichloroethene 75-35-4 +/- 86.9500SHBG8609V
99% 4 µg/mL 25,095.0tert-Butanol (TBA)75-65-0 +/- 867.1659SHBQ8002
99% 5 µg/mL 5,016.4Methyl acetate 79-20-9 +/- 173.3427SHBP3100
99% 6 µg/mL 2,517.4Iodomethane (methyl iodide)74-88-4 +/- 86.9888MKCN8012
99% 7 µg/mL 2,515.9Allyl chloride ( 3-chloropropene )107-05-1 +/- 86.9370RD230914ECS
99% 8 µg/mL 2,513.8Methylene chloride (dichloromethane)75-09-2 +/- 86.8636SHBQ6376
99% 9 µg/mL 2,512.9Carbon disulfide 75-15-0 +/- 86.8333Q30J743
99% 10 µg/mL 25,031.9Acrylonitrile107-13-1 +/- 864.9846102466R02E
99% 11 µg/mL 2,513.8Methyl-tert-butyl ether ( MTBE )1634-04-4 +/- 86.8636SHBP0179
99% 12 µg/mL 2,514.0cis-1,2-Dichloroethene 156-59-2 +/- 86.8722MKCP7830
99% 13 µg/mL 2,520.3n-Hexane (C6)110-54-3 +/- 87.0882STBG6381
99% 14 µg/mL 2,514.01,1-Dichloroethane 75-34-3 +/- 86.8722852900
99% 15 µg/mL 2,521.32,2-Dichloropropane 594-20-7 +/- 87.1227RD230426
99% 16 µg/mL 2,514.9trans-1,2-Dichloroethene 156-60-5 +/- 86.9025MKCP9516
01-Nov-2022 rev.Page 1 of 5
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9:26:49 AM
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99% 17 µg/mL 62,561.0Isobutanol (2-Methyl-1-propanol)78-83-1 +/- 2,161.8157SHBP7066
99% 18 µg/mL 2,513.6chloroform67-66-3 +/- 86.8593SHBN8469
99% 19 µg/mL 2,513.5Bromochloromethane74-97-5 +/- 86.8549230810JLM
99% 20 µg/mL 5,020.9Tetrahydrofuran109-99-9 +/- 173.4982SHBQ8516
99% 21 µg/mL 2,513.51,1,1-trichloroethane 71-55-6 +/- 86.8549RD230728RSR
99% 22 µg/mL 2,513.5Cyclohexane110-82-7 +/- 86.8549MKCQ2001
99% 23 µg/mL 2,514.31,1-Dichloropropene 563-58-6 +/- 86.8809230825JLM
99% 24 µg/mL 2,513.0carbon tetrachloride 56-23-5 +/- 86.8377SHBP4875
99% 25 µg/mL 2,515.4n-Heptane (C7)142-82-5 +/- 86.9197044743T01D
99% 26 µg/mL 2,513.51,2-Dichloroethane 107-06-2 +/- 86.8549SHBQ0693
99% 27 µg/mL 2,513.4Benzene71-43-2 +/- 86.8506MKCS3357
99% 28 µg/mL 2,513.6Trichloroethene79-01-6 +/- 86.8593SHBN3720
99% 29 µg/mL 2,514.8Methylcyclohexane108-87-2 +/- 86.8981SHBN1699
99% 30 µg/mL 2,514.91,2-Dichloropropane 78-87-5 +/- 86.9025BCBR0882V
99% 31 µg/mL 50,131.41,4-Dioxane 123-91-1 +/- 1,732.3059SHBQ2407
99% 32 µg/mL 2,514.6Dibromomethane74-95-3 +/- 86.893810233302
99% 33 µg/mL 2,513.5cis-1,3-Dichloropropene 10061-01-5 +/- 86.8549RD230406RSR
99% 34 µg/mL 2,512.9Toluene108-88-3 +/- 86.8333MKCS9989
97% 35 µg/mL 2,508.3Ethyl methacrylate 97-63-2 +/- 86.6752MKCN6206
99% 36 µg/mL 2,512.9trans-1,3-Dichloropropene 10061-02-6 +/- 86.8333RD220816
99% 37 µg/mL 2,513.51,1,2-Trichloroethane 79-00-5 +/- 86.8549FGB01
99% 38 µg/mL 2,514.11,3-Dichloropropane 142-28-9 +/- 86.8765BCCH5357
99% 39 µg/mL 2,514.0Tetrachloroethene127-18-4 +/- 86.8722SHBQ0051
99% 40 µg/mL 2,512.9dibromochloromethane124-48-1 +/- 86.8333MKCQ4517
99% 41 µg/mL 2,515.01,2-Dibromoethane (EDB)106-93-4 +/- 86.9068BCCH7113
99% 42 µg/mL 2,515.0Chlorobenzene108-90-7 +/- 86.9068SHBN6640
99% 43 µg/mL 1,254.8m-Xylene 108-38-3 +/- 43.3584SHBN6673
99% 44 µg/mL 1,257.0p-Xylene 106-42-3 +/- 43.4361SHBP5191
99% 45 µg/mL 2,514.1Ethylbenzene100-41-4 +/- 86.8765094632L21G
99% 46 µg/mL 2,514.91,1,1,2-Tetrachloroethane 630-20-6 +/- 86.9025GC01
99% 47 µg/mL 2,514.0o-Xylene 95-47-6 +/- 86.872250069309
99% 48 µg/mL 2,514.0Styrene100-42-5 +/- 86.8722MKCQ3390
99% 49 µg/mL 2,514.1Isopropylbenzene (cumene)98-82-8 +/- 86.8765Z20D022
99% 50 µg/mL 2,515.3bromoform75-25-2 +/- 86.9154050494L04R
99% 51 µg/mL 2,512.5bromodichloromethane75-27-4 +/- 86.8204MKCF8470
99% 52 µg/mL 2,515.31,1,2,2-Tetrachloroethane 79-34-5 +/- 86.9154QQJ41
01-Nov-2022 rev.Page 2 of 5
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9:26:49 AM
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98% 53 µg/mL 2,513.51,2,3-Trichloropropane 96-18-4 +/- 86.8534Q91-34
94% 54 µg/mL 2,504.7trans-1,4-dichloro-2-butene 110-57-6 +/- 86.5525RD230720RSR
98% 55 µg/mL 2,511.4n-Propylbenzene 103-65-1 +/- 86.7814G08M
99% 56 µg/mL 2,514.8Bromobenzene108-86-1 +/- 86.8981MKCQ7174
99% 57 µg/mL 2,513.81,3,5-Trimethylbenzene 108-67-8 +/- 86.8636BCCF4166
99% 58 µg/mL 2,514.82-Chlorotoluene 95-49-8 +/- 86.8981235783M23T
99% 59 µg/mL 2,514.94-Chlorotoluene 106-43-4 +/- 86.9025BCCG9286
99% 60 µg/mL 2,514.0tert-Butylbenzene 98-06-6 +/- 86.8722STBJ1937
99% 61 µg/mL 2,515.91,2,4-Trimethylbenzene 95-63-6 +/- 86.9370MKCS3775
99% 62 µg/mL 2,515.3sec-Butylbenzene 135-98-8 +/- 86.9154MKCP2266
99% 63 µg/mL 2,514.9p-Isopropyltoluene (p-Cymene)99-87-6 +/- 86.9025MKCR6143
99% 64 µg/mL 2,515.31,3-Dichlorobenzene 541-73-1 +/- 86.9154BCCD5315
99% 65 µg/mL 2,514.91,4-Dichlorobenzene 106-46-7 +/- 86.9025MKBS7929V
99% 66 µg/mL 2,514.5n-Butylbenzene 104-51-8 +/- 86.889509418JJ
99% 67 µg/mL 2,514.31,2-Dichlorobenzene 95-50-1 +/- 86.8809SHBN3835
97% 68 µg/mL 2,510.41,2-Dibromo-3-chloropropane 96-12-8 +/- 86.7464HBMVB
99% 69 µg/mL 2,514.91,2,4-Trichlorobenzene 120-82-1 +/- 86.9025SHBP5900
98% 70 µg/mL 2,510.0Hexachlorobutadiene87-68-3 +/- 86.7349RP230823RSR
99% 71 µg/mL 2,514.3Naphthalene91-20-3 +/- 86.8809STBL1057
99% 72 µg/mL 2,514.11,2,3-Trichlorobenzene 87-61-6 +/- 86.8765MKBX7627V
Solvent:P&T Methanol
99%
67-56-1CAS #
Purity
* Expanded Uncertainty displayed in same units as Grav. Conc.
01-Nov-2022 rev.Page 3 of 5
12/27/2024
9:26:49 AM
Page 102 of 428
Carrier Gas:
Temp. Program:
Inj. Temp:
Det. Type:
Det. Temp:
60m x 0.25mm x 1.4µm
Rtx-502.2 (cat.#10916)
Column:
helium-constant pressure 30 psi
40°C (hold 6 min.) to 240°C
@ 6°C/min. (hold 10 min.)
200°C
250°C
MSD
B707717271Balance Serial #
08-Dec-2023Date Passed:Manufactured under Restek's ISO 9001:2015
Registered Quality System
Certificate #FM 80397
22-Oct-2023Date Mixed:
This chromatogram represents a general set of testing conditions chosen for product
acceptance. For optimal results in your lab, conditions should be adjusted for your
specific instrument, method, and application.
Quality Confirmation Test
20.0 ml/min.
Inj. Vol
0.2µl
Split Vent:
01-Nov-2022 rev.Page 4 of 5
12/27/2024
9:26:49 AM
Page 103 of 428
General Certified Reference Material Notes
Expiration Notes:
·Expiration date valid for unopened ampul stored in compliance with the recommended conditions.
·Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the
recommended condition found in the storage field.
Purity Notes:
·Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD,
GC/MS, LC/MS, RI, and/or melting point.
·Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A
correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the
parent compound in solution.
·Purity of isomeric compounds is reported as the sum of the isomers.
·Purity values are rounded to the nearest whole number.
Certified Uncertainty Value Notes:
·The uncertainties are determined in accordance with ISO 17034 and Guide 35. The certified expanded
uncertainty value includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability
uncertainty and shipping stability uncertainty and were combined using the following formula:
k is a coverage factor of 2, which gives a level of confidence of approximately 95%.
·The packaged amount is the minimum sample size for which uncertainty is valid. The ampuls are over-filled to ensure
that the minimum packaged amount can be sufficiently transferred.
Manufacturing Notes:
·Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily
using NIST traceable weights, and/or dilutions with Class A glassware.
Handling Notes:
·Stability of the unopened product, when stored in compliance with the recommended conditions, is guaranteed through
the expiration displayed on the product label and certificate. Contact Restek for additional opened product stability
information, with the knowledge/understanding that open product stability is subject to the specific handling and
environmental conditions to which the product is exposed. For your convenience Restek supplies deactivated vials with
most standards packed in 2mL ampuls. Larger volume deactivated vials are available through Restek as a custom
ordered item. Additionally, Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31861,
which includes complete instructions.
·If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely
dissolved.
01-Nov-2022 rev.Page 5 of 5
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Reagent
MV-CUS17739_00017
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Page 105 of 428
ISO 17034
Reference Material Certificate
Product Information Sheet
Custom Standard
CUS-17739
Product Name:
Product Number:
31-Aug-2026Expiration Date:Store Frozen (-25° to -10°C).Storage Conditions:
31-Jul-2024Lot Issue Date:
0006808538Lot Number:
Traceability:
The balances used for these measurements are calibrated with weights traceable to NIST in compliance with ANSI/NCSL Z540.3,
ISO 9001, ISO 17025, and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are
calibrated against a NIST traceable thermometer in accordance with NIST Special Publication 1088.
Homogeneity:
This analytical reference standard was unitized according to an in-house procedure and is guaranteed to be homogeneous. There is
no minimum sub-sample size required.
Intended Use:
This analytical reference standard is intended for the preparation of working reference samples for use in routine laboratory
analyses, calibration of instruments, validation of analytical methods, assessments of measurement methods, and continuing
calibration verification.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at 20ºC to 25ºC immediately after opening the container and should be processed
without delay for the certified values to be valid within the stated uncertainties.
Safety:
Expiration of Certification:
The certification of this analytical reference standard is valid until the expiration date specified above, provided the material is
handled and stored in accordance with the instructions given in this certificate. This certification is nullified if the material is
damaged, contaminated, or otherwise modified.

Matrix:methanol (purge & trap grade)
Refer to the Safety Data Sheet on www.agilent.com for information regarding this analytical reference material.
This document is prepared in accordance with ISO 17034 and Guide 31. This analytical reference material standard was
manufactured and verified in accordance with an ISO 9001 registered quality system and analyte concentrations were verified by an
ISO 17025 accredited laboratory. The concentration and uncertainty value at the 95% confidence level for each analyte, determined
gravimetrically, is listed above.
Description:
Component Name CAS#Analyte LotConcentrationUncertainty
1-chlorohexane 000544-10-5 RM204861004 ± 5 µg/mL
2-pentanone 000107-87-9 RM134784017 ± 20 µg/mL
sec-butanol 000078-92-2 RM1350630013 ± 150 µg/mL
1 of 2Page:
CSD-QA-015.2 ISO 17025
Cert No. AT-1937
250 Smith Street North Kingstown, Rhode Island 02852 www.agilent.com/quality 12/27/2024
9:26:49 AM
Page 106 of 428
Maintenance of Certification:
If substantive changes are noted that affect the certification before the expiration of this certificate, Agilent will notify the purchaser.

Sample lot approver:
ISO 17034
RM was produced in accordance with the TUV/SUD registered ISO
9001:2015 Quality Management System. Cert# 951215321
2 of 2Page:
www.agilent.com/quality/
CSD-QA-015.2 ISO 17025
Cert No. AR-1936 Cert No. AT-1937
250 Smith Street North Kingstown, Rhode Island 02852 www.agilent.com/quality 12/27/2024
9:26:49 AM
Page 107 of 428
Reagent
mv-IS/SS Tune_00002
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8260D
Volatile Organic Compounds by GC/MS
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FORM II
GC/MS VOA SURROGATE RECOVERY
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Matrix:Water Level:Low
GC Column (1):DB-624 (60.25)ID:0.25(mm)
#Lab Sample IDClient Sample ID ###DBFM DCA TOL BFB
280-201015-1MW-59-241217 95 99 101 98
280-201015-2DS-02-241217 96 100 101 99
280-201015-3FB-02-241217 90 99 101 99
280-201015-4Trip Blank 95 99 101 99
MB 280-679543/9 94 97 104 99
LCS 280-679543/4 99 96 99 97
LCSD 280-679543/5 99 95 102 99
QC LIMITS
DBFM = Dibromofluoromethane (Surr)77-120
DCA = 1,2-Dichloroethane-d4 (Surr)70-127
TOL = Toluene-d8 (Surr)80-125
BFB = 4-Bromofluorobenzene (Surr)78-120
FORM II 8260D
# Column to be used to flag recovery values
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GC/MS VOA LAB CONTROL SAMPLE RECOVERY
FORM III
Job No.:Lab Name:280-201015-1Eurofins Denver
SDG No.:
Level:Matrix:Low Lab File ID:VMS14_0000005443b.DWater
Lab ID:LCS 280-679543/4 Client ID:
REC
%
REC
QC
LIMITSCONCENTRATION
(ug/L)
SPIKE
ADDED
(ug/L)
#
LCS LCS
COMPOUND
Ethylbenzene 50.0 47.8 80-12096
Styrene 50.0 49.6 80-12099
cis-1,3-Dichloropropene 50.0 51.6 76-129103
trans-1,3-Dichloropropene 50.0 42.1 80-12384
N-Propylbenzene 50.0 46.7 80-12393
n-Butylbenzene 50.0 47.1 59-14094
4-Chlorotoluene 50.0 47.0 80-12094
1,4-Dichlorobenzene 50.0 46.3 80-12093
Ethylene Dibromide 50.0 48.4 80-12097
3-Chloro-1-propene 50.0 46.0 65-13292
1,2-Dichloroethane 50.0 44.6 71-12189
Vinyl acetate 100 103 55-161103
4-Methyl-2-pentanone (MIBK)200 191 66-13595
1,3,5-Trimethylbenzene 50.0 47.5 80-12295
Bromobenzene 50.0 47.2 80-12094
Methylcyclohexane 50.0 45.7 64-13091
Toluene 50.0 46.4 80-12093
Chlorobenzene 50.0 47.2 80-12094
Tetrahydrofuran 100 90.9 62-13091
Hexane 50.0 46.5 55-14393
Cyclohexane 50.0 45.8 68-12592
1,2,4-Trichlorobenzene 50.0 48.1 74-12696
Chlorodibromomethane 50.0 44.8 80-12590
Tetrachloroethene 50.0 47.6 80-12195
sec-Butylbenzene 50.0 46.8 80-12394
1,3-Dichloropropane 50.0 48.1 77-12296
cis-1,2-Dichloroethene 50.0 47.1 80-12094
trans-1,2-Dichloroethene 50.0 48.1 79-12196
Methyl tert-butyl ether 50.0 43.6 80-12087
m-Xylene & p-Xylene 50.0 47.1 80-12094
1,3-Dichlorobenzene 50.0 46.8 80-12094
Carbon tetrachloride 50.0 43.4 79-12787
1,1-Dichloropropene 50.0 46.7 77-12393
2-Hexanone 200 192 62-13796
2,2-Dichloropropane 50.0 48.7 75-13197
Ethyl ether 50.0 49.6 68-13299
1,1,1,2-Tetrachloroethane 50.0 51.2 80-124102
Acetone 200 185 61-13493
Chloroform 50.0 47.3 80-12095
Benzene 50.0 47.1 80-12094
1,1,1-Trichloroethane 50.0 47.3 80-12395
Bromomethane 50.0 44.5 29-14889
FORM III 8260D
# Column to be used to flag recovery and RPD values
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GC/MS VOA LAB CONTROL SAMPLE RECOVERY
FORM III
Job No.:Lab Name:280-201015-1Eurofins Denver
SDG No.:
Level:Matrix:Low Lab File ID:VMS14_0000005443b.DWater
Lab ID:LCS 280-679543/4 Client ID:
REC
%
REC
QC
LIMITSCONCENTRATION
(ug/L)
SPIKE
ADDED
(ug/L)
#
LCS LCS
COMPOUND
Chloromethane 50.0 38.4 56-13377
Iodomethane 50.0 45.6 43-13991
Dibromomethane 50.0 46.1 80-12092
Chlorobromomethane 50.0 48.7 80-12397
Chloroethane 50.0 44.8 56-14190
Vinyl chloride 50.0 42.4 67-12785
Methylene Chloride 50.0 43.8 78-12088
Carbon disulfide 50.0 41.6 70-12183
Bromoform 50.0 42.1 79-13884
Dichlorobromomethane 50.0 49.0 80-12398
1,1-Dichloroethane 50.0 47.9 78-12196
1,1-Dichloroethene 50.0 47.1 77-12194
Trichlorofluoromethane 50.0 51.0 54-144102
Dichlorodifluoromethane 50.0 51.0 47-135102
1,1,2-Trichloro-1,2,2-trifluor
oethane
50.0 49.0 73-13298
1,2-Dichloropropane 50.0 47.9 78-12096
2-Butanone (MEK)200 183 58-13591
1,1,2-Trichloroethane 50.0 47.6 80-12095
Trichloroethene 50.0 49.4 80-12099
Methyl acetate 100 91.9 59-13692
1,1,2,2-Tetrachloroethane 50.0 49.7 74-12399
1,2,3-Trichlorobenzene 50.0 46.0 65-12992
Hexachlorobutadiene 50.0 46.4 73-12893
Naphthalene 50.0 44.9 60-12490
o-Xylene 50.0 48.0 80-12096
2-Chlorotoluene 50.0 46.7 80-12093
1,2-Dichlorobenzene 50.0 48.4 80-12097
1,2,4-Trimethylbenzene 50.0 48.4 79-12497
1,2-Dibromo-3-Chloropropane 50.0 42.1 73-12884
1,2,3-Trichloropropane 50.0 48.3 80-12097
Ethyl methacrylate 50.0 50.6 80-122101
tert-Butylbenzene 50.0 46.4 80-12093
Isopropylbenzene 50.0 47.7 78-12295
4-Isopropyltoluene 50.0 47.7 80-12295
FORM III 8260D
# Column to be used to flag recovery and RPD values
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GC/MS VOA LAB CONTROL SAMPLE DUPLICATE RECOVERY
FORM III
Job No.:Lab Name:280-201015-1Eurofins Denver
SDG No.:
Level:Matrix:Low Lab File ID:VMS14_0000005445.DWater
Lab ID:LCSD 280-679543/5 Client ID:
COMPOUND
SPIKE
ADDED CONCENTRATION %
REC
%
QC LIMITS
REC (ug/L)(ug/L)
#
LCSD LCSD
RPD RPD
50.0 53.2 20 80-120Ethylbenzene11106
50.0 53.6 20 80-120Styrene8107
50.0 57.0 20 76-129cis-1,3-Dichloropropene 10114
50.0 44.9 20 80-123trans-1,3-Dichloropropene 690
50.0 52.0 20 80-123N-Propylbenzene 11104
50.0 52.0 20 59-140n-Butylbenzene 10104
50.0 51.8 20 80-1204-Chlorotoluene 10104
50.0 50.5 20 80-1201,4-Dichlorobenzene 9101
50.0 53.9 20 80-120Ethylene Dibromide 11108
50.0 48.9 20 65-1323-Chloro-1-propene 698
50.0 47.6 20 71-1211,2-Dichloroethane 795
100 111 23 55-161Vinyl acetate 8111
200 200 20 66-1354-Methyl-2-pentanone (MIBK)5100
50.0 51.1 20 80-1221,3,5-Trimethylbenzene 7102
50.0 53.3 20 80-120Bromobenzene12107
50.0 49.0 21 64-130Methylcyclohexane798
50.0 49.6 20 80-120Toluene799
50.0 52.2 20 80-120Chlorobenzene10104
100 97.6 20 62-130Tetrahydrofuran798
50.0 51.1 23 55-143Hexane9102
50.0 49.9 32 68-125Cyclohexane9100
50.0 54.0 20 74-1261,2,4-Trichlorobenzene 12108
50.0 49.4 20 80-125Chlorodibromomethane1099
50.0 52.9 20 80-121Tetrachloroethene10106
50.0 51.4 20 80-123sec-Butylbenzene 9103
50.0 52.6 20 77-1221,3-Dichloropropane 9105
50.0 50.6 20 80-120cis-1,2-Dichloroethene 7101
50.0 51.1 20 79-121trans-1,2-Dichloroethene 6102
50.0 48.4 20 80-120Methyl tert-butyl ether 1097
50.0 51.4 20 80-120m-Xylene & p-Xylene 9103
50.0 51.7 20 80-1201,3-Dichlorobenzene 10103
50.0 47.3 20 79-127Carbon tetrachloride 995
50.0 50.6 20 77-1231,1-Dichloropropene 8101
200 208 21 62-1372-Hexanone 8104
50.0 51.4 22 75-1312,2-Dichloropropane 5103
50.0 52.5 20 68-132Ethyl ether 6105
50.0 56.5 20 80-1241,1,1,2-Tetrachloroethane 10113
200 190 21 61-134Acetone395
50.0 50.5 20 80-120Chloroform7101
50.0 50.2 20 80-120Benzene6100
50.0 51.2 20 80-1231,1,1-Trichloroethane 8102
50.0 46.7 40 29-148Bromomethane593
FORM III 8260D
# Column to be used to flag recovery and RPD values
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GC/MS VOA LAB CONTROL SAMPLE DUPLICATE RECOVERY
FORM III
Job No.:Lab Name:280-201015-1Eurofins Denver
SDG No.:
Level:Matrix:Low Lab File ID:VMS14_0000005445.DWater
Lab ID:LCSD 280-679543/5 Client ID:
COMPOUND
SPIKE
ADDED CONCENTRATION %
REC
%
QC LIMITS
REC (ug/L)(ug/L)
#
LCSD LCSD
RPD RPD
50.0 38.4 20 56-133Chloromethane077
50.0 50.6 38 43-139Iodomethane10101
50.0 48.3 20 80-120Dibromomethane597
50.0 51.5 20 80-123Chlorobromomethane6103
50.0 49.0 30 56-141Chloroethane998
50.0 43.6 25 67-127Vinyl chloride 387
50.0 46.4 20 78-120Methylene Chloride 693
50.0 44.9 20 70-121Carbon disulfide 890
50.0 45.5 20 79-138Bromoform891
50.0 52.3 20 80-123Dichlorobromomethane7105
50.0 51.8 20 78-1211,1-Dichloroethane 8104
50.0 50.1 21 77-1211,1-Dichloroethene 6100
50.0 50.9 28 54-144Trichlorofluoromethane0102
50.0 52.8 21 47-135Dichlorodifluoromethane3106
50.0 51.9 23 73-1321,1,2-Trichloro-1,2,2-trifluor
oethane
6104
50.0 51.3 20 78-1201,2-Dichloropropane 7103
200 189 20 58-1352-Butanone (MEK)395
50.0 51.2 20 80-1201,1,2-Trichloroethane 7102
50.0 55.3 20 80-120Trichloroethene11111
100 97.2 20 59-136Methyl acetate 697
50.0 56.1 20 74-1231,1,2,2-Tetrachloroethane 12112
50.0 51.4 20 65-1291,2,3-Trichlorobenzene 11103
50.0 53.9 20 73-128Hexachlorobutadiene15108
50.0 50.0 21 60-124Naphthalene11100
50.0 51.8 20 80-120o-Xylene 8104
50.0 51.9 20 80-1202-Chlorotoluene 10104
50.0 53.0 20 80-1201,2-Dichlorobenzene 9106
50.0 52.0 20 79-1241,2,4-Trimethylbenzene 7104
50.0 46.7 21 73-1281,2-Dibromo-3-Chloropropane 1093
50.0 53.2 20 80-1201,2,3-Trichloropropane 10106
50.0 55.5 20 80-122Ethyl methacrylate 9111
50.0 52.3 20 80-120tert-Butylbenzene 12105
50.0 53.9 20 78-122Isopropylbenzene12108
50.0 52.5 20 80-1224-Isopropyltoluene 10105
FORM III 8260D
# Column to be used to flag recovery and RPD values
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Page 116 of 428
FORM IV
GC/MS VOA METHOD BLANK SUMMARY
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Date Analyzed:
GC Column:ID:
Instrument ID:12/23/2024 19:23
DB-624 (60.25)
NHeated Purge:(Y/N)
VMS_MS14
VMS14_0000005449.DLab File ID:Lab Sample ID:MB 280-679543/9
WaterMatrix:
0.25(mm)
THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES:
LAB SAMPLE ID
LAB
FILE ID DATE ANALYZEDCLIENT SAMPLE ID
12/23/2024 17:23VMS14_00000
05443b.D
LCS 280-679543/4
12/23/2024 18:03VMS14_00000
05445.D
LCSD 280-679543/5
12/23/2024 21:03VMS14_00000
05452.D
280-201015-3FB-02-241217
12/23/2024 21:28VMS14_00000
05453.D
280-201015-4Trip Blank
12/23/2024 22:28VMS14_00000
05456.D
280-201015-1MW-59-241217
12/23/2024 22:48VMS14_00000
05457.D
280-201015-2DS-02-241217
FORM IV 8260D
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FORM V
BROMOFLUOROBENZENE (BFB)
Lab Name:Job No.:
GC/MS VOA INSTRUMENT PERFORMANCE CHECK
Eurofins Denver 280-201015-1
Lab File ID:
Instrument ID:
VMS14_0000005135.D
VMS_MS14
12/13/2024
18:15
BFB Injection Date:
BFB Injection Time:
M/E ION ABUNDANCE CRITERIA % RELATIVE
ABUNDANCE
Analysis Batch No.:678523
50 15.0 - 40.0 % of mass 95 19.6
75 30.0 - 60.0 % of mass 95 50.7
95 Base Peak, 100% relative abundance 100.0
96 5.0 - 9.0 % of mass 95 6.8
173 Less than 2.0 % of mass 174 0.3 (0.4)1
174 Greater than 50% of mass 95 71.4
175 5.0 - 9.0 % of mass 174 5.6 (7.9)1
176 95.0 - 101.0 % of mass 174 68.8 (96.4)1
177 5.0 - 9.0 % of mass 176 4.3 (6.3)2
1-Value is % mass 174 2-Value is % mass 176
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS:
SDG No.:
CLIENT SAMPLE ID LAB
FILE IDLAB SAMPLE ID DATE
ANALYZED
TIME
ANALYZED
ICV 280-678523/44 VMS14_0000005144.D12/13/2024 21:15
FORM V 8260D 12/27/2024
9:26:49 AM
Page 118 of 428
FORM V
BROMOFLUOROBENZENE (BFB)
Lab Name:Job No.:
GC/MS VOA INSTRUMENT PERFORMANCE CHECK
Eurofins Denver 280-201015-1
Lab File ID:
Instrument ID:
VMS14_0000005222.D
VMS_MS14
12/16/2024
23:25
BFB Injection Date:
BFB Injection Time:
M/E ION ABUNDANCE CRITERIA % RELATIVE
ABUNDANCE
Analysis Batch No.:678685
50 15.0 - 40.0 % of mass 95 19.4
75 30.0 - 60.0 % of mass 95 51.2
95 Base Peak, 100% relative abundance 100.0
96 5.0 - 9.0 % of mass 95 6.8
173 Less than 2.0 % of mass 174 0.4 (0.5)1
174 Greater than 50% of mass 95 72.0
175 5.0 - 9.0 % of mass 174 5.3 (7.4)1
176 95.0 - 101.0 % of mass 174 68.5 (95.1)1
177 5.0 - 9.0 % of mass 176 4.5 (6.6)2
1-Value is % mass 174 2-Value is % mass 176
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS:
SDG No.:
CLIENT SAMPLE ID LAB
FILE IDLAB SAMPLE ID DATE
ANALYZED
TIME
ANALYZED
IC 280-678685/13 VMS14_0000005223.D12/17/2024 1:00
IC 280-678685/14 VMS14_0000005224.D12/17/2024 1:20
IC 280-678685/15 VMS14_0000005225.D12/17/2024 1:40
IC 280-678685/16 VMS14_0000005226.D12/17/2024 2:00
IC 280-678685/17 VMS14_0000005227.D12/17/2024 2:20
ICIS 280-678685/18 VMS14_0000005228.D12/17/2024 2:40
IC 280-678685/19 VMS14_0000005229.D12/17/2024 3:00
IC 280-678685/20 VMS14_0000005230.D12/17/2024 3:20
IC 280-678685/21 VMS14_0000005231.D12/17/2024 3:40
ICV 280-678685/22 VMS14_0000005233.D12/17/2024 4:21
FORM V 8260D 12/27/2024
9:26:49 AM
Page 119 of 428
FORM V
BROMOFLUOROBENZENE (BFB)
Lab Name:Job No.:
GC/MS VOA INSTRUMENT PERFORMANCE CHECK
Eurofins Denver 280-201015-1
Lab File ID:
Instrument ID:
VMS14_0000005443a.D
VMS_MS14
12/23/2024
17:23
BFB Injection Date:
BFB Injection Time:
M/E ION ABUNDANCE CRITERIA % RELATIVE
ABUNDANCE
Analysis Batch No.:679543
50 15.0 - 40.0 % of mass 95 17.4
75 30.0 - 60.0 % of mass 95 48.7
95 Base Peak, 100% relative abundance 100.0
96 5.0 - 9.0 % of mass 95 6.5
173 Less than 2.0 % of mass 174 0.4 (0.5)1
174 Greater than 50% of mass 95 71.6
175 5.0 - 9.0 % of mass 174 5.4 (7.5)1
176 95.0 - 101.0 % of mass 174 69.4 (96.9)1
177 5.0 - 9.0 % of mass 176 4.9 (7.1)2
1-Value is % mass 174 2-Value is % mass 176
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS:
SDG No.:
CLIENT SAMPLE ID LAB
FILE IDLAB SAMPLE ID DATE
ANALYZED
TIME
ANALYZED
CCV 280-679543/2 VMS14_0000005443.D12/23/2024 17:23
LCS 280-679543/4 VMS14_0000005443b.D12/23/2024 17:23
LCSD 280-679543/5 VMS14_0000005445.D12/23/2024 18:03
MB 280-679543/9 VMS14_0000005449.D12/23/2024 19:23
FB-02-241217 280-201015-3 VMS14_0000005452.D12/23/2024 21:03
Trip Blank 280-201015-4 VMS14_0000005453.D12/23/2024 21:28
MW-59-241217 280-201015-1 VMS14_0000005456.D12/23/2024 22:28
DS-02-241217 280-201015-2 VMS14_0000005457.D12/23/2024 22:48
FORM V 8260D 12/27/2024
9:26:49 AM
Page 120 of 428
GC/MS VOA INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY
Lab Name:Job No.:
FORM VIII
Eurofins Denver 280-201015-1
SDG No.:
Sample No.:ICIS 280-678685/18 Date Analyzed:12/17/2024 02:40
Lab File ID (Standard):VMS14_0000005228.D
Instrument ID:VMS_MS14 GC Column:DB-624 (60.25)ID:0.25(mm)
Heated Purge: (Y/N)N
Calibration ID:99935
#RT #RT ##RT ##
FB CBNZd5 DCBd4
AREA AREA AREA
UPPER LIMIT
LOWER LIMIT
3744060
936015 234444
937776
381751
1527002
5.36 7.93 10.17INITIAL CALIBRATION MID-POINT
5.53
5.19
8.09
7.76
10.34
10.01
1872030 468888 763501
LAB SAMPLE ID CLIENT SAMPLE ID
ICV 280-678685/22 1940806 481995 768801 5.36 7.93 10.17
CCV 280-679543/2 2081420 501851 803693 5.36 7.93 10.17
LCS 280-679543/4 2081420 501851 803693 5.36 7.93 10.17
LCSD 280-679543/5 1980065 457853 708154 5.36 7.93 10.17
MB 280-679543/9 2261628 497889 811540 5.36 7.93 10.17
280-201015-3 FB-02-241217 2298779 533305 877879 5.36 7.93 10.17
280-201015-4 Trip Blank 2285139 524540 854109 5.36 7.93 10.17
280-201015-1 MW-59-241217 2248660 514556 845844 5.36 7.93 10.17
280-201015-2 DS-02-241217 2314155 531710 861885 5.36 7.93 10.17
FB = Fluorobenzene
CBNZd5 = Chlorobenzene-d5
DCBd4 = 1,4-Dichlorobenzene-d4
Area Limit = 50%-200% of internal standard area
RT Limit = ± 0.167 minutes of internal standard RT
# Column used to flag values outside QC limits
FORM VIII 8260D 12/27/2024
9:26:49 AM
Page 121 of 428
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Client Sample ID:MW-59-241217 Lab Sample ID:280-201015-1
Matrix:VMS14_0000005456.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
12/17/2024 09:15
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:12/23/2024 22:28
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:679543 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.14100-41-4 Ethylbenzene ND
1.0 0.13100-42-5 Styrene ND
1.0 0.1610061-01-5 cis-1,3-Dichloropropene ND
1.0 0.1410061-02-6 trans-1,3-Dichloropropene ND
1.0 0.18103-65-1 N-Propylbenzene ND
1.0 0.23104-51-8 n-Butylbenzene ND
1.0 0.21106-43-4 4-Chlorotoluene ND
1.0 0.39106-46-7 1,4-Dichlorobenzene ND
1.0 0.18106-93-4 Ethylene Dibromide ND
2.0 0.46107-05-1 3-Chloro-1-propene ND
1.0 0.28107-06-2 1,2-Dichloroethane ND
3.0 0.36108-05-4 Vinyl acetate ND
5.0 0.98108-10-1 4-Methyl-2-pentanone (MIBK)ND
1.0 0.12108-67-8 1,3,5-Trimethylbenzene ND
1.0 0.19108-86-1 Bromobenzene ND
1.0 0.31108-87-2 Methylcyclohexane ND
1.0 0.32108-88-3 Toluene ND
1.0 0.092108-90-7 Chlorobenzene ND
7.0 0.84109-99-9 Tetrahydrofuran ND
2.0 0.16110-54-3 Hexane ND
1.0 0.44110-82-7 Cyclohexane ND
1.0 0.58120-82-1 1,2,4-Trichlorobenzene ND
1.0 0.28124-48-1 Chlorodibromomethane ND
1.0 0.40127-18-4 Tetrachloroethene ND
1.0 0.20135-98-8 sec-Butylbenzene ND
1.0 0.17142-28-9 1,3-Dichloropropane ND
1.0 0.32156-59-2 cis-1,2-Dichloroethene 33
1.0 0.37156-60-5 trans-1,2-Dichloroethene 7.8
5.0 0.251634-04-4 Methyl tert-butyl ether ND
2.0 0.36179601-23-1 m-Xylene & p-Xylene ND
1.0 0.33541-73-1 1,3-Dichlorobenzene ND
1.0 0.2356-23-5 Carbon tetrachloride ND
FORM I 8260D
12/27/2024
9:26:49 AM
Page 122 of 428
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Client Sample ID:MW-59-241217 Lab Sample ID:280-201015-1
Matrix:VMS14_0000005456.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
12/17/2024 09:15
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:12/23/2024 22:28
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:679543 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.19563-58-6 1,1-Dichloropropene ND
5.0 0.81591-78-6 2-Hexanone ND
1.0 0.17594-20-7 2,2-Dichloropropane ND
2.0 0.3560-29-7 Ethyl ether ND
1.0 0.16630-20-6 1,1,1,2-Tetrachloroethane ND
15 6.667-64-1 Acetone ND
1.0 0.3667-66-3 Chloroform ND
1.0 0.1471-43-2 Benzene ND
1.0 0.3971-55-6 1,1,1-Trichloroethane ND
5.0 2.474-83-9 Bromomethane ND
2.0 0.2374-87-3 Chloromethane ND
5.0 2.674-88-4 Iodomethane ND
1.0 0.3474-95-3 Dibromomethane ND
1.0 0.4074-97-5 Chlorobromomethane ND
2.0 0.6475-00-3 Chloroethane ND
1.0 0.2375-01-4 Vinyl chloride ND
2.0 0.9475-09-2 Methylene Chloride ND
2.0 0.2675-15-0 Carbon disulfide ND
2.0 0.2575-25-2 Bromoform ND
1.0 0.1975-27-4 Dichlorobromomethane ND
1.0 0.2275-34-3 1,1-Dichloroethane 4.5
1.0 0.2375-35-4 1,1-Dichloroethene 1.7
2.0 0.2075-69-4 Trichlorofluoromethane ND
2.0 0.3075-71-8 Dichlorodifluoromethane ND
3.0 0.7376-13-1 1,1,2-Trichloro-1,2,2-trifluoroethan
e
ND
1.0 0.2478-87-5 1,2-Dichloropropane 3.4
10 4.678-93-3 2-Butanone (MEK)ND
1.0 0.2779-00-5 1,1,2-Trichloroethane ND
1.0 0.3079-01-6 Trichloroethene 35
5.0 1.679-20-9 Methyl acetate ND
1.0 0.2179-34-5 1,1,2,2-Tetrachloroethane ND
4.0 1.287-61-6 1,2,3-Trichlorobenzene ND
FORM I 8260D
12/27/2024
9:26:49 AM
Page 123 of 428
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Client Sample ID:MW-59-241217 Lab Sample ID:280-201015-1
Matrix:VMS14_0000005456.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
12/17/2024 09:15
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:12/23/2024 22:28
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:679543 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
2.0 0.5387-68-3 Hexachlorobutadiene ND
3.0 0.9991-20-3 Naphthalene ND
1.0 0.1195-47-6 o-Xylene ND
1.0 0.3495-49-8 2-Chlorotoluene ND
1.0 0.1495-50-1 1,2-Dichlorobenzene ND
1.0 0.1595-63-6 1,2,4-Trimethylbenzene ND
5.0 0.4296-12-8 1,2-Dibromo-3-Chloropropane ND
2.5 0.2896-18-4 1,2,3-Trichloropropane ND
3.0 0.1997-63-2 Ethyl methacrylate ND
1.0 0.1898-06-6 tert-Butylbenzene ND
1.0 0.1698-82-8 Isopropylbenzene ND
1.0 0.1999-87-6 4-Isopropyltoluene ND
1.0 0.111330-20-7 Xylenes, Total ND
1.0 0.32540-59-0 1,2-Dichloroethene, Total 41
1.0 0.14542-75-6 1,3-Dichloropropene, Total ND
1.0 0.19STL00209Trihalomethanes, Total ND
1.0 0.14STL00431Total BTEX ND
%RECCAS NO.LIMITSQSURROGATE
99 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr)
95 77-1201868-53-7 Dibromofluoromethane (Surr)
101 80-1252037-26-5 Toluene-d8 (Surr)
98 78-120460-00-4 4-Bromofluorobenzene (Surr)
FORM I 8260D
12/27/2024
9:26:49 AM
Page 124 of 428
Report Date: 23-Dec-2024 23:10:24 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005456.D
Lims ID:280-201015-C-1
Client ID:MW-59-241217
Sample Type:Client
Inject. Date:23-Dec-2024 22:28:51 ALS Bottle#:7 Worklist Smp#:19
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:280-201015-C-1
Operator ID:bustillose Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:23-Dec-2024 23:10:17 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1673
First Level Reviewer: LP8K Date:23-Dec-2024 23:09:11
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 98 2248660 50.0
* 2 Chlorobenzene-d5 119 7.926 7.926 0.000 88 514556 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.173 0.000 97 845844 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.842 4.842 0.000 93 540712 47.3
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.112 -0.003 98 752091 49.5
$ 6 Toluene-d8 (Surr) 98 6.636 6.636 0.000 94 2226537 50.7
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 84 850100 49.1
10 Dichlorodifluoromethane 85 1.794 ND
12 Chloromethane 50 1.974 ND
13 Vinyl chloride 62 2.090 2.090 0.000 1 2015 0.1760
15 Bromomethane 94 2.395 ND U
16 Chloroethane 64 2.495 ND
18 Trichlorofluoromethane 101 2.717 ND
21 Ethyl ether 59 2.939 ND
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.138 3.138 0.000 49 3241 0.5720
25 1,1-Dichloroethene 96 3.141 3.144 -0.003 97 13334 1.65
26 Acetone 43 3.160 ND 7
29 Iodomethane 142 3.270 ND
30 Carbon disulfide 76 3.337 ND
32 Methyl acetate 43 3.395 ND
33 3-Chloro-1-propene 41 3.421 ND
34 Methylene Chloride 84 3.521 ND
37 Methyl tert-butyl ether 73 3.713 ND
38 trans-1,2-Dichloroethene 96 3.730 3.730 0.000 97 67831 7.83
39 Hexane 57 3.932 ND
40 Vinyl acetate 43 4.032 ND
42 1,1-Dichloroethane 63 4.054 4.058 -0.004 96 73587 4.45
45 2-Butanone (MEK) 43 4.453 4.450 0.003 36 2339 0.1263
47 cis-1,2-Dichloroethene 96 4.482 4.482 0.000 81 330234 32.5
48 2,2-Dichloropropane 77 4.492 ND
52 Chlorobromomethane 128 4.662 ND
53 Tetrahydrofuran 42 4.672 ND
12/27/2024
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Page 125 of 428
Report Date: 23-Dec-2024 23:10:24 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005456.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
54 Chloroform 83 4.720 ND
55 1,1,1-Trichloroethane 97 4.871 ND
56 Cyclohexane 56 4.935 ND
57 1,1-Dichloropropene 75 4.987 ND
59 Carbon tetrachloride 117 4.993 ND
60 Benzene 78 5.144 ND
61 1,2-Dichloroethane 62 5.170 ND
65 Trichloroethene 95 5.640 5.639 0.001 98 300403 35.3
67 Methylcyclohexane 55 5.842 ND
69 1,2-Dichloropropane 63 5.849 5.848 0.001 94 33465 3.41
71 Dibromomethane 93 5.919 ND
72 Dichlorobromomethane 83 6.045 ND
75 cis-1,3-Dichloropropene 75 6.398 ND
76 4-Methyl-2-pentanone (MIBK) 43 6.501 ND
77 Toluene 91 6.694 ND
78 trans-1,3-Dichloropropene 75 6.868 ND
79 Ethyl methacrylate 69 6.884 ND
80 1,1,2-Trichloroethane 97 7.048 ND
82 Tetrachloroethene 164 7.147 ND
83 1,3-Dichloropropane 76 7.196 ND
84 2-Hexanone 43 7.212 ND
85 Chlorodibromomethane 129 7.395 ND
86 Ethylene Dibromide 107 7.514 ND
88 Chlorobenzene 112 7.955 ND
89 1,1,1,2-Tetrachloroethane 131 8.025 ND
90 Ethylbenzene 106 8.032 ND
91 m-Xylene & p-Xylene 106 8.144 ND
92 o-Xylene 106 8.514 ND
93 Styrene 104 8.527 ND
94 Bromoform 173 8.713 ND
95 Isopropylbenzene 105 8.858 ND
98 1,1,2,2-Tetrachloroethane 83 9.141 ND
100 Bromobenzene 156 9.183 ND
101 1,2,3-Trichloropropane 110 9.209 ND
102 N-Propylbenzene 120 9.260 ND
103 2-Chlorotoluene 126 9.360 ND
104 1,3,5-Trimethylbenzene 105 9.430 ND
105 4-Chlorotoluene 126 9.479 ND
107 tert-Butylbenzene 119 9.745 ND
108 1,2,4-Trimethylbenzene 105 9.803 ND
109 sec-Butylbenzene 134 9.971 ND
110 1,3-Dichlorobenzene 146 10.099 ND
111 4-Isopropyltoluene 119 10.115 ND
112 1,4-Dichlorobenzene 146 10.199 ND
114 n-Butylbenzene 91 10.524 ND
115 1,2-Dichlorobenzene 146 10.562 ND
116 1,2-Dibromo-3-Chloropropane 157 11.347 ND
118 1,2,4-Trichlorobenzene 180 12.183 ND
119 Hexachlorobutadiene 225 12.324 ND
120 Naphthalene 128 12.456 ND
121 1,2,3-Trichlorobenzene 180 12.678 ND
S 156 Total BTEX 1 0.000 ND 7
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Report Date: 23-Dec-2024 23:10:24 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005456.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
S 155 Xylenes, Total 106 0.000 ND 7
S 152 Trihalomethanes, Total 1 0.000 ND 7
S 154 1,3-Dichloropropene, Total 1 0.000 ND 7
S 151 1,2-Dichloroethene, Total 1 0 40.4
QC Flag Legend
Processing Flags
7 - Failed Limit of Detection
Review Flags
U - Marked Undetected
Reagents:
mv-IS_SS_00094 Amount Added: 5.00 Units: uL Run Reagent
12/27/2024
9:26:49 AM
Page 127 of 428
Report Date: 23-Dec-2024 23:10:24 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005456.D
Injection Date:23-Dec-2024 22:28:51 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:280-201015-C-1 Lab Sample ID:280-201015-1 Worklist Smp#:19
Client ID:MW-59-241217
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:7
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0
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12/27/2024
9:26:49 AM
Page 128 of 428
Report Date: 23-Dec-2024 23:10:24 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005456.D
Lims ID:280-201015-C-1
Client ID:MW-59-241217
Sample Type:Client
Inject. Date:23-Dec-2024 22:28:51 ALS Bottle#:7 Worklist Smp#:19
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:280-201015-C-1
Operator ID:bustillose Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:23-Dec-2024 23:10:17 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1673
First Level Reviewer: LP8K Date:23-Dec-2024 23:09:11
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 47.3 94.63
$5 1,2-Dichloroethane-d4 (Surr)50.0 49.5 98.95
$6 Toluene-d8 (Surr)50.0 50.7 101.37
$7 4-Bromofluorobenzene (Surr)50.0 49.1 98.28
12/27/2024
9:26:49 AM
Page 129 of 428
Report Date: 23-Dec-2024 23:10:24 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005456.D
Injection Date:23-Dec-2024 22:28:51 Instrument ID:VMS_MS14
Lims ID:280-201015-C-1 Lab Sample ID:280-201015-1
Client ID:MW-59-241217
Operator ID:bustillose ALS Bottle#:7 Worklist Smp#:19
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
47 cis-1,2-Dichloroethene, CAS: 156-59-2
30 70 110 150 190 230 270 310 350
m/z
0
4
8
12
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20
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Raw Spec:Scan 1087(4.48)
61
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98
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Amdis Enhanced Spec: Scan 1087(4.48), Qvalue=81 Sig Qvalue=83
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Ref Spec: 47 cis-1,2-Dichloroethene (NIST98.L)
61
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Differenc Spec:Scan 1 @ 4.480 min.(Qvalue: 81)
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0000005456[MS Quad Chro]:m/z 96
0000005456[MS Quad Chro]:m/z 61
0000005456[MS Quad Chro]:m/z 98
12/27/2024
9:26:49 AM
Page 130 of 428
Report Date: 23-Dec-2024 23:10:24 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005456.D
Injection Date:23-Dec-2024 22:28:51 Instrument ID:VMS_MS14
Lims ID:280-201015-C-1 Lab Sample ID:280-201015-1
Client ID:MW-59-241217
Operator ID:bustillose ALS Bottle#:7 Worklist Smp#:19
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
38 trans-1,2-Dichloroethene, CAS: 156-60-5
30 70 110 150 190 230 270 310 350
m/z
0
8
16
24
32
40
48
56
Y ( X10
0
0
)
Raw Spec:Scan 853(3.73)
61
96
98
6360
100
30 70 110 150 190 230 270 310 350m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 853(3.73), Qvalue=97 Sig Qvalue=96
61
96
98
6360
100
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X10
0
)
Ref Spec: 38 trans-1,2-Dichloroethene (NIST98.L)
61
96
98
63
60
100
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 3.730 min.(Qvalue: 97)
60
3.2 3.5 3.8 4.1
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
0
)
0000005456[MS Quad Chro]:m/z 96

3
.
7
3
0
3.2 3.5 3.8 4.1Min
RT
0
10
20
30
40
50
60
Y ( X10
0
0
)
0000005456[MS Quad Chro]:m/z 61

3
.
7
3
0
3.2 3.5 3.8 4.1
Min
RT
0
5
10
15
20
25
Y ( X10
0
0
)
0000005456[MS Quad Chro]:m/z 98

3
.
7
3
0
3.2 3.5 3.8 4.1
Min
0
10
20
30
40
50
60
Y ( X10
0
0
)
0000005456[MS Quad Chro]:m/z 96
0000005456[MS Quad Chro]:m/z 61
0000005456[MS Quad Chro]:m/z 98
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Report Date: 23-Dec-2024 23:10:24 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005456.D
Injection Date:23-Dec-2024 22:28:51 Instrument ID:VMS_MS14
Lims ID:280-201015-C-1 Lab Sample ID:280-201015-1
Client ID:MW-59-241217
Operator ID:bustillose ALS Bottle#:7 Worklist Smp#:19
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
42 1,1-Dichloroethane, CAS: 75-34-3
30 70 110 150 190 230 270 310 350
m/z
0
6
12
18
24
30
36
Y ( X10
0
0
)
Raw Spec:Scan 954(4.05)
63
65
8361
30 70 110 150 190 230 270 310 350m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 954(4.05), Qvalue=96 Sig Qvalue=99
63
65
8361
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X10
0
)
Ref Spec: 42 1,1-Dichloroethane (NIST98.L)
63
65
62 83
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 4.060 min.(Qvalue: 96)
65 85
3.5 3.8 4.1 4.4
Min
RT
0
13
26
39
52
65
78
Y ( X10
0
0
)
0000005456[MS Quad Chro]:m/z 63

4
.
0
5
4
3.5 3.8 4.1 4.4Min
RT
0
3
6
9
12
Y ( X10
0
0
)
0000005456[MS Quad Chro]:m/z 65

4
.
0
5
8
3.5 3.8 4.1 4.4
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
)
0000005456[MS Quad Chro]:m/z 83

4
.
0
5
4
3.5 3.8 4.1 4.4
Min
0
13
26
39
52
65
78
Y ( X10
0
0
)
0000005456[MS Quad Chro]:m/z 63
0000005456[MS Quad Chro]:m/z 65
0000005456[MS Quad Chro]:m/z 83
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Report Date: 23-Dec-2024 23:10:24 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005456.D
Injection Date:23-Dec-2024 22:28:51 Instrument ID:VMS_MS14
Lims ID:280-201015-C-1 Lab Sample ID:280-201015-1
Client ID:MW-59-241217
Operator ID:bustillose ALS Bottle#:7 Worklist Smp#:19
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
25 1,1-Dichloroethene, CAS: 75-35-4
30 70 110 150 190 230 270 310 350
m/z
0
2
4
6
8
10
12
Y ( X10
0
0
)
Raw Spec:Scan 670(3.14)
61
96
9863
60 101
151 15385
30 70 110 150 190 230 270 310 350m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 670(3.14), Qvalue=97 Sig Qvalue=98
61
96
9863
10160 151
15385
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X10
0
)
Ref Spec: 25 1,1-Dichloroethene (NIST98.L)
61
96
98
63
60
100
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 3.150 min.(Qvalue: 97)
101 151103
2.6 2.9 3.2 3.5
Min
RT
0
14
28
42
56
70
84
Y ( X10
0
)
0000005456[MS Quad Chro]:m/z 96

3
.
1
4
1
2.6 2.9 3.2 3.5Min
RT
0
3
6
9
12
Y ( X10
0
0
)
0000005456[MS Quad Chro]:m/z 61

3
.
1
4
8
2.6 2.9 3.2 3.5
Min
RT
0
9
18
27
36
45
54
Y ( X10
0
)
0000005456[MS Quad Chro]:m/z 98

3
.
1
4
5
2.6 2.9 3.2 3.5
Min
0
3
6
9
12
Y ( X10
0
0
)
0000005456[MS Quad Chro]:m/z 96
0000005456[MS Quad Chro]:m/z 61
0000005456[MS Quad Chro]:m/z 98
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Report Date: 23-Dec-2024 23:10:24 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005456.D
Injection Date:23-Dec-2024 22:28:51 Instrument ID:VMS_MS14
Lims ID:280-201015-C-1 Lab Sample ID:280-201015-1
Client ID:MW-59-241217
Operator ID:bustillose ALS Bottle#:7 Worklist Smp#:19
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
69 1,2-Dichloropropane, CAS: 78-87-5
30 70 110 150 190 230 270 310 350
m/z
0
3
6
9
12
15
18
Y ( X10
0
0
)
Raw Spec:Scan 1512(5.85)
63
62
76
78
112
30 70 110 150 190 230 270 310 350m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1512(5.85), Qvalue=94 Sig Qvalue=95
63
62
76
78
112
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X10
0
)
Ref Spec: 69 1,2-Dichloropropane (NIST98.L)
63
62
65
77
112
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 5.850 min.(Qvalue: 94)
76 78
5.3 5.6 5.9 6.2
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
0
)
0000005456[MS Quad Chro]:m/z 63

5
.
8
4
9
5.3 5.6 5.9 6.2Min
RT
0
10
20
30
40
50
60
Y ( X10
0
)
0000005456[MS Quad Chro]:m/z 65

5
.
8
5
2
5.3 5.6 5.9 6.2
Min
RT
0
2
4
6
8
10
Y ( X10
0
0
)
0000005456[MS Quad Chro]:m/z 41

5
.
8
4
5
5.3 5.6 5.9 6.2
Min
0
8
16
24
32
40
48
Y ( X10
0
0
)
0000005456[MS Quad Chro]:m/z 63
0000005456[MS Quad Chro]:m/z 65
0000005456[MS Quad Chro]:m/z 41
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Report Date: 23-Dec-2024 23:10:24 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005456.D
Injection Date:23-Dec-2024 22:28:51 Instrument ID:VMS_MS14
Lims ID:280-201015-C-1 Lab Sample ID:280-201015-1
Client ID:MW-59-241217
Operator ID:bustillose ALS Bottle#:7 Worklist Smp#:19
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
65 Trichloroethene, CAS: 79-01-6
30 70 110 150 190 230 270 310 350
m/z
0
3
6
9
12
15
18
Y ( X10
0
0
0
)
Raw Spec:Scan 1447(5.64)
95 132
97
60
134
62 99
30 70 110 150 190 230 270 310 350m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1447(5.64), Qvalue=98 Sig Qvalue=100
95 130 132
97
60
134
62 99
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X10
0
)
Ref Spec: 65 Trichloroethene (NIST98.L)
95 130 132
97
60
134
62 99
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 5.640 min.(Qvalue: 98)
60 62 134
5.1 5.4 5.7 6.0
Min
RT
0
3
6
9
12
15
18
Y ( X10
0
0
0
)
0000005456[MS Quad Chro]:m/z 95

5
.
6
4
0
5.1 5.4 5.7 6.0Min
RT
0
3
6
9
12
15
18
Y ( X10
0
0
0
)
0000005456[MS Quad Chro]:m/z 130

5
.
6
4
3
5.1 5.4 5.7 6.0
Min
RT
0
2
4
6
8
10
12
Y ( X10
0
0
0
)
0000005456[MS Quad Chro]:m/z 97

5
.
6
4
3
5.1 5.4 5.7 6.0
Min
0
3
6
9
12
15
18
Y ( X10
0
0
0
)
0000005456[MS Quad Chro]:m/z 95
0000005456[MS Quad Chro]:m/z 130
0000005456[MS Quad Chro]:m/z 97
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Page 135 of 428
Report Date: 23-Dec-2024 23:10:24 Chrom Revision: 2.3 17-Dec-2024 12:44:46
User Disabled Compound Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005456.D
Injection Date:23-Dec-2024 22:28:51 Instrument ID:VMS_MS14
Lims ID:280-201015-C-1 Lab Sample ID:280-201015-1
Client ID:MW-59-241217
Operator ID:bustillose ALS Bottle#:7 Worklist Smp#:19
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
15 Bromomethane, CAS: 74-83-9
Processing Results
30 70 110 150 190 230 270 310 350m/z
0
10
20
30
40
50
60
70
Y ( X10
0
)
Raw Spec:Scan 438(2.40)
9449 96
30 70 110 150 190 230 270 310 350
m/z
0
2
4
6
8
10
12
Y ( X10
0
)
Enhanced Spec:Scan 438(2.40) Bgrd 432( 2.38), Qvalue=35
94 96
93
105
30 70 110 150 190 230 270 310 350
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 15 Bromomethane (NIST98.L)
94 96
79
2.2 2.5Min
RT
0
10
20
30
40
50
60
Y ( X10
)
0000005456[MS Quad Chro]:m/z 94

2
.
3
9
5
2.2 2.5
Min
RT
0
10
20
30
40
50
60
Y ( X10
)
0000005456[MS Quad Chro]:m/z 96

2
.
4
0
5
2.2 2.5
Min
RT
0
2
4
6
8
10
Y ( X10
0
)
0000005456[MS Quad Chro]:m/z 79

2
.
3
8
9
RT Mass Response Amount
2.40 94.00 754 1.411046
2.41 96.00 640
2.39 79.00 981
Reviewer: LP8K, 23-Dec-2024 23:08:56 -07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
12/27/2024
9:26:49 AM
Page 136 of 428
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Client Sample ID:DS-02-241217 Lab Sample ID:280-201015-2
Matrix:VMS14_0000005457.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
12/17/2024 09:15
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:12/23/2024 22:48
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:679543 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.14100-41-4 Ethylbenzene ND
1.0 0.13100-42-5 Styrene ND
1.0 0.1610061-01-5 cis-1,3-Dichloropropene ND
1.0 0.1410061-02-6 trans-1,3-Dichloropropene ND
1.0 0.18103-65-1 N-Propylbenzene ND
1.0 0.23104-51-8 n-Butylbenzene ND
1.0 0.21106-43-4 4-Chlorotoluene ND
1.0 0.39106-46-7 1,4-Dichlorobenzene ND
1.0 0.18106-93-4 Ethylene Dibromide ND
2.0 0.46107-05-1 3-Chloro-1-propene ND
1.0 0.28107-06-2 1,2-Dichloroethane ND
3.0 0.36108-05-4 Vinyl acetate ND
5.0 0.98108-10-1 4-Methyl-2-pentanone (MIBK)ND
1.0 0.12108-67-8 1,3,5-Trimethylbenzene ND
1.0 0.19108-86-1 Bromobenzene ND
1.0 0.31108-87-2 Methylcyclohexane ND
1.0 0.32108-88-3 Toluene ND
1.0 0.092108-90-7 Chlorobenzene ND
7.0 0.84109-99-9 Tetrahydrofuran ND
2.0 0.16110-54-3 Hexane ND
1.0 0.44110-82-7 Cyclohexane ND
1.0 0.58120-82-1 1,2,4-Trichlorobenzene ND
1.0 0.28124-48-1 Chlorodibromomethane ND
1.0 0.40127-18-4 Tetrachloroethene ND
1.0 0.20135-98-8 sec-Butylbenzene ND
1.0 0.17142-28-9 1,3-Dichloropropane ND
1.0 0.32156-59-2 cis-1,2-Dichloroethene 33
1.0 0.37156-60-5 trans-1,2-Dichloroethene 8.0
5.0 0.251634-04-4 Methyl tert-butyl ether ND
2.0 0.36179601-23-1 m-Xylene & p-Xylene ND
1.0 0.33541-73-1 1,3-Dichlorobenzene ND
1.0 0.2356-23-5 Carbon tetrachloride ND
FORM I 8260D
12/27/2024
9:26:49 AM
Page 137 of 428
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Client Sample ID:DS-02-241217 Lab Sample ID:280-201015-2
Matrix:VMS14_0000005457.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
12/17/2024 09:15
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:12/23/2024 22:48
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:679543 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.19563-58-6 1,1-Dichloropropene ND
5.0 0.81591-78-6 2-Hexanone ND
1.0 0.17594-20-7 2,2-Dichloropropane ND
2.0 0.3560-29-7 Ethyl ether ND
1.0 0.16630-20-6 1,1,1,2-Tetrachloroethane ND
15 6.667-64-1 Acetone ND
1.0 0.3667-66-3 Chloroform ND
1.0 0.1471-43-2 Benzene ND
1.0 0.3971-55-6 1,1,1-Trichloroethane ND
5.0 2.474-83-9 Bromomethane ND
2.0 0.2374-87-3 Chloromethane ND
5.0 2.674-88-4 Iodomethane ND
1.0 0.3474-95-3 Dibromomethane ND
1.0 0.4074-97-5 Chlorobromomethane ND
2.0 0.6475-00-3 Chloroethane ND
1.0 0.2375-01-4 Vinyl chloride ND
2.0 0.9475-09-2 Methylene Chloride ND
2.0 0.2675-15-0 Carbon disulfide ND
2.0 0.2575-25-2 Bromoform ND
1.0 0.1975-27-4 Dichlorobromomethane ND
1.0 0.2275-34-3 1,1-Dichloroethane 4.6
1.0 0.2375-35-4 1,1-Dichloroethene 1.5
2.0 0.2075-69-4 Trichlorofluoromethane ND
2.0 0.3075-71-8 Dichlorodifluoromethane ND
3.0 0.7376-13-1 1,1,2-Trichloro-1,2,2-trifluoroethan
e
ND
1.0 0.2478-87-5 1,2-Dichloropropane 3.3
10 4.678-93-3 2-Butanone (MEK)ND
1.0 0.2779-00-5 1,1,2-Trichloroethane ND
1.0 0.3079-01-6 Trichloroethene 42
5.0 1.679-20-9 Methyl acetate ND
1.0 0.2179-34-5 1,1,2,2-Tetrachloroethane ND
4.0 1.287-61-6 1,2,3-Trichlorobenzene ND
FORM I 8260D
12/27/2024
9:26:49 AM
Page 138 of 428
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Client Sample ID:DS-02-241217 Lab Sample ID:280-201015-2
Matrix:VMS14_0000005457.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
12/17/2024 09:15
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:12/23/2024 22:48
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:679543 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
2.0 0.5387-68-3 Hexachlorobutadiene ND
3.0 0.9991-20-3 Naphthalene ND
1.0 0.1195-47-6 o-Xylene ND
1.0 0.3495-49-8 2-Chlorotoluene ND
1.0 0.1495-50-1 1,2-Dichlorobenzene ND
1.0 0.1595-63-6 1,2,4-Trimethylbenzene ND
5.0 0.4296-12-8 1,2-Dibromo-3-Chloropropane ND
2.5 0.2896-18-4 1,2,3-Trichloropropane ND
3.0 0.1997-63-2 Ethyl methacrylate ND
1.0 0.1898-06-6 tert-Butylbenzene ND
1.0 0.1698-82-8 Isopropylbenzene ND
1.0 0.1999-87-6 4-Isopropyltoluene ND
1.0 0.111330-20-7 Xylenes, Total ND
1.0 0.32540-59-0 1,2-Dichloroethene, Total 41
1.0 0.14542-75-6 1,3-Dichloropropene, Total ND
1.0 0.19STL00209Trihalomethanes, Total ND
1.0 0.14STL00431Total BTEX ND
%RECCAS NO.LIMITSQSURROGATE
100 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr)
96 77-1201868-53-7 Dibromofluoromethane (Surr)
101 80-1252037-26-5 Toluene-d8 (Surr)
99 78-120460-00-4 4-Bromofluorobenzene (Surr)
FORM I 8260D
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9:26:49 AM
Page 139 of 428
Report Date: 23-Dec-2024 23:10:26 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005457.D
Lims ID:280-201015-B-2
Client ID:DS-02-241217
Sample Type:Client
Inject. Date:23-Dec-2024 22:48:51 ALS Bottle#:8 Worklist Smp#:20
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:280-201015-B-2
Operator ID:bustillose Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:23-Dec-2024 23:10:17 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1673
First Level Reviewer: LP8K Date:23-Dec-2024 23:10:17
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 98 2314155 50.0
* 2 Chlorobenzene-d5 119 7.926 7.926 0.000 88 531710 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.170 10.173 -0.003 97 861885 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.839 4.842 -0.003 93 564195 48.0
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.112 5.112 0.000 99 780283 49.9
$ 6 Toluene-d8 (Surr) 98 6.636 6.636 0.000 94 2298714 50.6
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 84 869633 49.3
10 Dichlorodifluoromethane 85 1.794 ND
12 Chloromethane 50 1.974 ND
13 Vinyl chloride 62 2.090 ND
15 Bromomethane 94 2.395 ND U
16 Chloroethane 64 2.495 ND
18 Trichlorofluoromethane 101 2.717 ND
21 Ethyl ether 59 2.939 ND
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.151 3.138 0.013 50 3533 0.6059
25 1,1-Dichloroethene 96 3.145 3.144 0.001 98 12670 1.52
26 Acetone 43 3.160 ND
29 Iodomethane 142 3.270 ND
30 Carbon disulfide 76 3.337 ND
32 Methyl acetate 43 3.395 ND
33 3-Chloro-1-propene 41 3.421 ND
34 Methylene Chloride 84 3.521 ND
37 Methyl tert-butyl ether 73 3.713 ND
38 trans-1,2-Dichloroethene 96 3.730 3.730 0.000 97 71138 7.98
39 Hexane 57 3.932 ND
40 Vinyl acetate 43 4.032 ND
42 1,1-Dichloroethane 63 4.061 4.058 0.003 97 78137 4.60
45 2-Butanone (MEK) 43 4.456 4.450 0.006 33 2537 0.1332
47 cis-1,2-Dichloroethene 96 4.482 4.482 0.000 81 346671 33.2
48 2,2-Dichloropropane 77 4.492 ND
52 Chlorobromomethane 128 4.662 ND
53 Tetrahydrofuran 42 4.678 4.672 0.006 84 4287 0.3699 M
12/27/2024
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Report Date: 23-Dec-2024 23:10:26 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005457.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
54 Chloroform 83 4.720 ND
55 1,1,1-Trichloroethane 97 4.871 ND
56 Cyclohexane 56 4.935 ND
57 1,1-Dichloropropene 75 4.987 ND
59 Carbon tetrachloride 117 4.993 ND
60 Benzene 78 5.144 ND 7
61 1,2-Dichloroethane 62 5.170 ND
65 Trichloroethene 95 5.643 5.639 0.004 98 370353 42.1
67 Methylcyclohexane 55 5.842 ND
69 1,2-Dichloropropane 63 5.849 5.848 0.001 93 33699 3.33
71 Dibromomethane 93 5.919 ND
72 Dichlorobromomethane 83 6.045 ND
75 cis-1,3-Dichloropropene 75 6.398 ND
76 4-Methyl-2-pentanone (MIBK) 43 6.501 ND
77 Toluene 91 6.694 ND
78 trans-1,3-Dichloropropene 75 6.868 ND
79 Ethyl methacrylate 69 6.884 ND
80 1,1,2-Trichloroethane 97 7.048 ND
82 Tetrachloroethene 164 7.147 ND
83 1,3-Dichloropropane 76 7.196 ND
84 2-Hexanone 43 7.212 ND
85 Chlorodibromomethane 129 7.395 ND
86 Ethylene Dibromide 107 7.514 ND
88 Chlorobenzene 112 7.955 ND
89 1,1,1,2-Tetrachloroethane 131 8.025 ND
90 Ethylbenzene 106 8.032 ND
91 m-Xylene & p-Xylene 106 8.144 ND
92 o-Xylene 106 8.514 ND
93 Styrene 104 8.527 ND
94 Bromoform 173 8.713 ND
95 Isopropylbenzene 105 8.858 ND
98 1,1,2,2-Tetrachloroethane 83 9.141 ND
100 Bromobenzene 156 9.183 ND
101 1,2,3-Trichloropropane 110 9.209 ND
102 N-Propylbenzene 120 9.260 ND
103 2-Chlorotoluene 126 9.360 ND
104 1,3,5-Trimethylbenzene 105 9.430 ND
105 4-Chlorotoluene 126 9.479 ND
107 tert-Butylbenzene 119 9.745 ND
108 1,2,4-Trimethylbenzene 105 9.803 ND
109 sec-Butylbenzene 134 9.971 ND
110 1,3-Dichlorobenzene 146 10.099 ND
111 4-Isopropyltoluene 119 10.115 ND
112 1,4-Dichlorobenzene 146 10.199 ND
114 n-Butylbenzene 91 10.524 ND
115 1,2-Dichlorobenzene 146 10.562 ND
116 1,2-Dibromo-3-Chloropropane 157 11.347 ND
118 1,2,4-Trichlorobenzene 180 12.183 ND
119 Hexachlorobutadiene 225 12.324 ND
120 Naphthalene 128 12.456 ND
121 1,2,3-Trichlorobenzene 180 12.678 ND
S 156 Total BTEX 1 0.000 ND 7
12/27/2024
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Page 141 of 428
Report Date: 23-Dec-2024 23:10:26 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005457.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
S 155 Xylenes, Total 106 0.000 ND 7
S 152 Trihalomethanes, Total 1 0.000 ND 7
S 154 1,3-Dichloropropene, Total 1 0.000 ND 7
S 151 1,2-Dichloroethene, Total 1 0 41.2
QC Flag Legend
Processing Flags
7 - Failed Limit of Detection
Review Flags
M - Manually Integrated
U - Marked Undetected
Reagents:
mv-IS_SS_00094 Amount Added: 5.00 Units: uL Run Reagent
12/27/2024
9:26:49 AM
Page 142 of 428
Report Date: 23-Dec-2024 23:10:26 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005457.D
Injection Date:23-Dec-2024 22:48:51 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:280-201015-B-2 Lab Sample ID:280-201015-2 Worklist Smp#:20
Client ID:DS-02-241217
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:8
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0
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4
6
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10
12
14
16
18
20
22
24
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28
30
32
34
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0
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0000005457[MS Quad Chro]:Total

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12/27/2024
9:26:49 AM
Page 143 of 428
Report Date: 23-Dec-2024 23:10:26 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005457.D
Lims ID:280-201015-B-2
Client ID:DS-02-241217
Sample Type:Client
Inject. Date:23-Dec-2024 22:48:51 ALS Bottle#:8 Worklist Smp#:20
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:280-201015-B-2
Operator ID:bustillose Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:23-Dec-2024 23:10:17 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1673
First Level Reviewer: LP8K Date:23-Dec-2024 23:10:17
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 48.0 95.94
$5 1,2-Dichloroethane-d4 (Surr)50.0 49.9 99.76
$6 Toluene-d8 (Surr)50.0 50.6 101.28
$7 4-Bromofluorobenzene (Surr)50.0 49.3 98.66
12/27/2024
9:26:49 AM
Page 144 of 428
Report Date: 23-Dec-2024 23:10:26 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005457.D
Injection Date:23-Dec-2024 22:48:51 Instrument ID:VMS_MS14
Lims ID:280-201015-B-2 Lab Sample ID:280-201015-2
Client ID:DS-02-241217
Operator ID:bustillose ALS Bottle#:8 Worklist Smp#:20
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
47 cis-1,2-Dichloroethene, CAS: 156-59-2
30 70 110 150 190 230 270 310 350
m/z
0
4
8
12
16
20
24
28
Y ( X10
0
0
0
)
Raw Spec:Scan 1087(4.48)
61
96
98
63
60
100
30 70 110 150 190 230 270 310 350m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1087(4.48), Qvalue=81 Sig Qvalue=83
61
96
98
63
60
100
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X10
0
)
Ref Spec: 47 cis-1,2-Dichloroethene (NIST98.L)
61
96
9860
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 4.480 min.(Qvalue: 81)
96 98
63
3.9 4.2 4.5 4.8
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
0
)
0000005457[MS Quad Chro]:m/z 96

4
.
4
8
2
3.9 4.2 4.5 4.8Min
RT
0
5
10
15
20
25
Y ( X10
0
0
0
)
0000005457[MS Quad Chro]:m/z 61

4
.
4
8
2
3.9 4.2 4.5 4.8
Min
RT
0
3
6
9
12
Y ( X10
0
0
0
)
0000005457[MS Quad Chro]:m/z 98

4
.
4
8
2
3.9 4.2 4.5 4.8
Min
0
5
10
15
20
25
Y ( X10
0
0
0
)
0000005457[MS Quad Chro]:m/z 96
0000005457[MS Quad Chro]:m/z 61
0000005457[MS Quad Chro]:m/z 98
12/27/2024
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Page 145 of 428
Report Date: 23-Dec-2024 23:10:26 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005457.D
Injection Date:23-Dec-2024 22:48:51 Instrument ID:VMS_MS14
Lims ID:280-201015-B-2 Lab Sample ID:280-201015-2
Client ID:DS-02-241217
Operator ID:bustillose ALS Bottle#:8 Worklist Smp#:20
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
38 trans-1,2-Dichloroethene, CAS: 156-60-5
30 70 110 150 190 230 270 310 350
m/z
0
9
18
27
36
45
54
63
Y ( X10
0
0
)
Raw Spec:Scan 853(3.73)
61
96
98
6360
100
30 70 110 150 190 230 270 310 350m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 853(3.73), Qvalue=97 Sig Qvalue=98
61
96
98
6360
100
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X10
0
)
Ref Spec: 38 trans-1,2-Dichloroethene (NIST98.L)
61
96
98
63
60
100
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 3.730 min.(Qvalue: 97)
60 62
3.2 3.5 3.8 4.1
Min
RT
0
7
14
21
28
35
42
Y ( X10
0
0
)
0000005457[MS Quad Chro]:m/z 96

3
.
7
3
0
3.2 3.5 3.8 4.1Min
RT
0
10
20
30
40
50
60
Y ( X10
0
0
)
0000005457[MS Quad Chro]:m/z 61

3
.
7
3
0
3.2 3.5 3.8 4.1
Min
RT
0
5
10
15
20
25
Y ( X10
0
0
)
0000005457[MS Quad Chro]:m/z 98

3
.
7
2
7
3.2 3.5 3.8 4.1
Min
0
10
20
30
40
50
60
Y ( X10
0
0
)
0000005457[MS Quad Chro]:m/z 96
0000005457[MS Quad Chro]:m/z 61
0000005457[MS Quad Chro]:m/z 98
12/27/2024
9:26:49 AM
Page 146 of 428
Report Date: 23-Dec-2024 23:10:26 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005457.D
Injection Date:23-Dec-2024 22:48:51 Instrument ID:VMS_MS14
Lims ID:280-201015-B-2 Lab Sample ID:280-201015-2
Client ID:DS-02-241217
Operator ID:bustillose ALS Bottle#:8 Worklist Smp#:20
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
42 1,1-Dichloroethane, CAS: 75-34-3
30 70 110 150 190 230 270 310 350
m/z
0
6
12
18
24
30
36
42
Y ( X10
0
0
)
Raw Spec:Scan 956(4.06)
63
65
8361
30 70 110 150 190 230 270 310 350m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 956(4.06), Qvalue=97 Sig Qvalue=99
63
65
8361
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X10
0
)
Ref Spec: 42 1,1-Dichloroethane (NIST98.L)
63
65
62 83
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 4.060 min.(Qvalue: 97)
65
83
3.5 3.8 4.1 4.4
Min
RT
0
14
28
42
56
70
84
Y ( X10
0
0
)
0000005457[MS Quad Chro]:m/z 63

4
.
0
6
1
3.5 3.8 4.1 4.4Min
RT
0
3
6
9
12
15
Y ( X10
0
0
)
0000005457[MS Quad Chro]:m/z 65

4
.
0
5
8
3.5 3.8 4.1 4.4
Min
RT
0
10
20
30
40
50
60
Y ( X10
0
)
0000005457[MS Quad Chro]:m/z 83

4
.
0
6
1
3.5 3.8 4.1 4.4
Min
0
14
28
42
56
70
84
Y ( X10
0
0
)
0000005457[MS Quad Chro]:m/z 63
0000005457[MS Quad Chro]:m/z 65
0000005457[MS Quad Chro]:m/z 83
12/27/2024
9:26:49 AM
Page 147 of 428
Report Date: 23-Dec-2024 23:10:26 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005457.D
Injection Date:23-Dec-2024 22:48:51 Instrument ID:VMS_MS14
Lims ID:280-201015-B-2 Lab Sample ID:280-201015-2
Client ID:DS-02-241217
Operator ID:bustillose ALS Bottle#:8 Worklist Smp#:20
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
25 1,1-Dichloroethene, CAS: 75-35-4
30 70 110 150 190 230 270 310 350
m/z
0
2
4
6
8
10
12
Y ( X10
0
0
)
Raw Spec:Scan 671(3.14)
61
96
98
6360 101
15385
30 70 110 150 190 230 270 310 350m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 671(3.14), Qvalue=98 Sig Qvalue=98
61
96
9863
10160 151 15385
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X10
0
)
Ref Spec: 25 1,1-Dichloroethene (NIST98.L)
61
96
98
63
60
100
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 3.140 min.(Qvalue: 98)
101 103 151 153
2.6 2.9 3.2 3.5
Min
RT
0
13
26
39
52
65
78
Y ( X10
0
)
0000005457[MS Quad Chro]:m/z 96

3
.
1
4
5
2.6 2.9 3.2 3.5Min
RT
0
3
6
9
12
Y ( X10
0
0
)
0000005457[MS Quad Chro]:m/z 61

3
.
1
4
1
2.6 2.9 3.2 3.5
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
)
0000005457[MS Quad Chro]:m/z 98

3
.
1
4
1
2.6 2.9 3.2 3.5
Min
0
3
6
9
12
Y ( X10
0
0
)
0000005457[MS Quad Chro]:m/z 96
0000005457[MS Quad Chro]:m/z 61
0000005457[MS Quad Chro]:m/z 98
12/27/2024
9:26:49 AM
Page 148 of 428
Report Date: 23-Dec-2024 23:10:26 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005457.D
Injection Date:23-Dec-2024 22:48:51 Instrument ID:VMS_MS14
Lims ID:280-201015-B-2 Lab Sample ID:280-201015-2
Client ID:DS-02-241217
Operator ID:bustillose ALS Bottle#:8 Worklist Smp#:20
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
69 1,2-Dichloropropane, CAS: 78-87-5
30 70 110 150 190 230 270 310 350
m/z
0
3
6
9
12
15
18
Y ( X10
0
0
)
Raw Spec:Scan 1512(5.85)
63
62
76
78
112
30 70 110 150 190 230 270 310 350m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1512(5.85), Qvalue=93 Sig Qvalue=93
63
62
76
78
112
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X10
0
)
Ref Spec: 69 1,2-Dichloropropane (NIST98.L)
63
62
65
77
112
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 5.850 min.(Qvalue: 93)
44 76
5.3 5.6 5.9 6.2
Min
RT
0
8
16
24
32
40
48
Y ( X10
0
0
)
0000005457[MS Quad Chro]:m/z 63

5
.
8
4
9
5.3 5.6 5.9 6.2Min
RT
0
10
20
30
40
50
60
Y ( X10
0
)
0000005457[MS Quad Chro]:m/z 65

5
.
8
4
9
5.3 5.6 5.9 6.2
Min
RT
0
3
6
9
12
Y ( X10
0
0
)
0000005457[MS Quad Chro]:m/z 41

5
.
8
4
6
5.3 5.6 5.9 6.2
Min
0
8
16
24
32
40
48
Y ( X10
0
0
)
0000005457[MS Quad Chro]:m/z 63
0000005457[MS Quad Chro]:m/z 65
0000005457[MS Quad Chro]:m/z 41
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Report Date: 23-Dec-2024 23:10:26 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005457.D
Injection Date:23-Dec-2024 22:48:51 Instrument ID:VMS_MS14
Lims ID:280-201015-B-2 Lab Sample ID:280-201015-2
Client ID:DS-02-241217
Operator ID:bustillose ALS Bottle#:8 Worklist Smp#:20
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
65 Trichloroethene, CAS: 79-01-6
30 70 110 150 190 230 270 310 350
m/z
0
3
6
9
12
15
18
21
Y ( X10
0
0
0
)
Raw Spec:Scan 1448(5.64)
95 130 132
97
60
134
62 99
30 70 110 150 190 230 270 310 350m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1448(5.64), Qvalue=98 Sig Qvalue=99
95 130 132
97
60
134
62 99
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X10
0
)
Ref Spec: 65 Trichloroethene (NIST98.L)
95 130 132
97
60
134
62 99
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 5.640 min.(Qvalue: 98)
60 94
5.1 5.4 5.7 6.0
Min
RT
0
4
8
12
16
20
Y ( X10
0
0
0
)
0000005457[MS Quad Chro]:m/z 95

5
.
6
4
3
5.1 5.4 5.7 6.0Min
RT
0
4
8
12
16
20
Y ( X10
0
0
0
)
0000005457[MS Quad Chro]:m/z 130

5
.
6
4
3
5.1 5.4 5.7 6.0
Min
RT
0
3
6
9
12
15
Y ( X10
0
0
0
)
0000005457[MS Quad Chro]:m/z 97

5
.
6
4
0
5.1 5.4 5.7 6.0
Min
0
4
8
12
16
20
Y ( X10
0
0
0
)
0000005457[MS Quad Chro]:m/z 95
0000005457[MS Quad Chro]:m/z 130
0000005457[MS Quad Chro]:m/z 97
12/27/2024
9:26:49 AM
Page 150 of 428
Report Date: 23-Dec-2024 23:10:26 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005457.D
Injection Date:23-Dec-2024 22:48:51 Instrument ID:VMS_MS14
Lims ID:280-201015-B-2 Lab Sample ID:280-201015-2
Client ID:DS-02-241217
Operator ID:bustillose ALS Bottle#:8 Worklist Smp#:20
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
53 Tetrahydrofuran, CAS: 109-99-9
Signal: 1
Processing Integration Results
RT: 4.68
Area: 2340
Amount: 0.201930
Amount Units: ug/l
4.3 4.5 4.7 4.9
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
Y ( X10
0
)
0000005457[MS Quad Chro]:m/z 42

4
.
6
7
8
Manual Integration Results
RT: 4.68
Area: 4287
Amount: 0.369946
Amount Units: ug/l
4.3 4.5 4.7 4.9
Min
RT
0
2
4
6
8
10
12
14
16
18
20
22
24
Y ( X10
0
)
0000005457[MS Quad Chro]:m/z 42

4
.
6
7
8
Reviewer: LP8K, 23-Dec-2024 23:10:09 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 151 of 428
Report Date: 23-Dec-2024 23:10:26 Chrom Revision: 2.3 17-Dec-2024 12:44:46
User Disabled Compound Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005457.D
Injection Date:23-Dec-2024 22:48:51 Instrument ID:VMS_MS14
Lims ID:280-201015-B-2 Lab Sample ID:280-201015-2
Client ID:DS-02-241217
Operator ID:bustillose ALS Bottle#:8 Worklist Smp#:20
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
15 Bromomethane, CAS: 74-83-9
Processing Results
30 70 110 150 190 230 270 310 350m/z
0
8
16
24
32
40
48
56
Y ( X10
0
)
Raw Spec:Scan 437(2.39)
49 80 106
30 70 110 150 190 230 270 310 350
m/z
0
7
14
21
28
35
42
49
Y ( X10
)
Enhanced Spec:Scan 437(2.39) Bgrd 426( 2.36), Qvalue=1
84
83
106
108
79
30 70 110 150 190 230 270 310 350
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 15 Bromomethane (NIST98.L)
94 96
79
2.2 2.5Min
RT
0
9
18
27
36
45
54
Y ( X10
)
0000005457[MS Quad Chro]:m/z 94

2
.
3
92
2.2 2.5
Min
RT
0
8
16
24
32
40
48
Y ( X10
)
0000005457[MS Quad Chro]:m/z 96

2
.
3
92
2.2 2.5
Min
RT
0
14
28
42
56
70
84
Y ( X10
)
0000005457[MS Quad Chro]:m/z 79

2
.
3
6
6
RT Mass Response Amount
2.39 94.00 468 1.374693
2.39 96.00 520
2.37 79.00 2549
Reviewer: LP8K, 23-Dec-2024 23:10:00 -07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
12/27/2024
9:26:49 AM
Page 152 of 428
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Client Sample ID:FB-02-241217 Lab Sample ID:280-201015-3
Matrix:VMS14_0000005452.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
12/17/2024 00:00
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:12/23/2024 21:03
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:679543 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.14100-41-4 Ethylbenzene ND
1.0 0.13100-42-5 Styrene ND
1.0 0.1610061-01-5 cis-1,3-Dichloropropene ND
1.0 0.1410061-02-6 trans-1,3-Dichloropropene ND
1.0 0.18103-65-1 N-Propylbenzene ND
1.0 0.23104-51-8 n-Butylbenzene ND
1.0 0.21106-43-4 4-Chlorotoluene ND
1.0 0.39106-46-7 1,4-Dichlorobenzene ND
1.0 0.18106-93-4 Ethylene Dibromide ND
2.0 0.46107-05-1 3-Chloro-1-propene ND
1.0 0.28107-06-2 1,2-Dichloroethane ND
3.0 0.36108-05-4 Vinyl acetate ND
5.0 0.98108-10-1 4-Methyl-2-pentanone (MIBK)ND
1.0 0.12108-67-8 1,3,5-Trimethylbenzene ND
1.0 0.19108-86-1 Bromobenzene ND
1.0 0.31108-87-2 Methylcyclohexane ND
1.0 0.32108-88-3 Toluene ND
1.0 0.092108-90-7 Chlorobenzene ND
7.0 0.84109-99-9 Tetrahydrofuran ND
2.0 0.16110-54-3 Hexane ND
1.0 0.44110-82-7 Cyclohexane ND
1.0 0.58120-82-1 1,2,4-Trichlorobenzene ND
1.0 0.28J124-48-1 Chlorodibromomethane 0.87
1.0 0.40127-18-4 Tetrachloroethene ND
1.0 0.20135-98-8 sec-Butylbenzene ND
1.0 0.17142-28-9 1,3-Dichloropropane ND
1.0 0.32156-59-2 cis-1,2-Dichloroethene ND
1.0 0.37156-60-5 trans-1,2-Dichloroethene ND
5.0 0.251634-04-4 Methyl tert-butyl ether ND
2.0 0.36179601-23-1 m-Xylene & p-Xylene ND
1.0 0.33541-73-1 1,3-Dichlorobenzene ND
1.0 0.2356-23-5 Carbon tetrachloride ND
FORM I 8260D
12/27/2024
9:26:49 AM
Page 153 of 428
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Client Sample ID:FB-02-241217 Lab Sample ID:280-201015-3
Matrix:VMS14_0000005452.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
12/17/2024 00:00
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:12/23/2024 21:03
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:679543 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.19563-58-6 1,1-Dichloropropene ND
5.0 0.81591-78-6 2-Hexanone ND
1.0 0.17594-20-7 2,2-Dichloropropane ND
2.0 0.3560-29-7 Ethyl ether ND
1.0 0.16630-20-6 1,1,1,2-Tetrachloroethane ND
15 6.667-64-1 Acetone ND
1.0 0.36J67-66-3 Chloroform 0.67
1.0 0.1471-43-2 Benzene ND
1.0 0.3971-55-6 1,1,1-Trichloroethane ND
5.0 2.474-83-9 Bromomethane ND
2.0 0.2374-87-3 Chloromethane ND
5.0 2.674-88-4 Iodomethane ND
1.0 0.3474-95-3 Dibromomethane ND
1.0 0.4074-97-5 Chlorobromomethane ND
2.0 0.6475-00-3 Chloroethane ND
1.0 0.2375-01-4 Vinyl chloride ND
2.0 0.9475-09-2 Methylene Chloride ND
2.0 0.2675-15-0 Carbon disulfide ND
2.0 0.2575-25-2 Bromoform 3.1
1.0 0.1975-27-4 Dichlorobromomethane ND
1.0 0.2275-34-3 1,1-Dichloroethane ND
1.0 0.2375-35-4 1,1-Dichloroethene ND
2.0 0.2075-69-4 Trichlorofluoromethane ND
2.0 0.3075-71-8 Dichlorodifluoromethane ND
3.0 0.7376-13-1 1,1,2-Trichloro-1,2,2-trifluoroethan
e
ND
1.0 0.2478-87-5 1,2-Dichloropropane ND
10 4.678-93-3 2-Butanone (MEK)ND
1.0 0.2779-00-5 1,1,2-Trichloroethane ND
1.0 0.3079-01-6 Trichloroethene ND
5.0 1.679-20-9 Methyl acetate ND
1.0 0.2179-34-5 1,1,2,2-Tetrachloroethane ND
4.0 1.287-61-6 1,2,3-Trichlorobenzene ND
FORM I 8260D
12/27/2024
9:26:49 AM
Page 154 of 428
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Client Sample ID:FB-02-241217 Lab Sample ID:280-201015-3
Matrix:VMS14_0000005452.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
12/17/2024 00:00
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:12/23/2024 21:03
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:679543 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
2.0 0.5387-68-3 Hexachlorobutadiene ND
3.0 0.9991-20-3 Naphthalene ND
1.0 0.1195-47-6 o-Xylene ND
1.0 0.3495-49-8 2-Chlorotoluene ND
1.0 0.1495-50-1 1,2-Dichlorobenzene ND
1.0 0.1595-63-6 1,2,4-Trimethylbenzene ND
5.0 0.4296-12-8 1,2-Dibromo-3-Chloropropane ND
2.5 0.2896-18-4 1,2,3-Trichloropropane ND
3.0 0.1997-63-2 Ethyl methacrylate ND
1.0 0.1898-06-6 tert-Butylbenzene ND
1.0 0.1698-82-8 Isopropylbenzene ND
1.0 0.1999-87-6 4-Isopropyltoluene ND
1.0 0.111330-20-7 Xylenes, Total ND
1.0 0.32540-59-0 1,2-Dichloroethene, Total ND
1.0 0.14542-75-6 1,3-Dichloropropene, Total ND
1.0 0.19STL00209Trihalomethanes, Total 4.6
1.0 0.14STL00431Total BTEX ND
%RECCAS NO.LIMITSQSURROGATE
99 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr)
90 77-1201868-53-7 Dibromofluoromethane (Surr)
101 80-1252037-26-5 Toluene-d8 (Surr)
99 78-120460-00-4 4-Bromofluorobenzene (Surr)
FORM I 8260D
12/27/2024
9:26:49 AM
Page 155 of 428
Report Date: 23-Dec-2024 22:19:58 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005452.D
Lims ID:280-201015-A-3
Client ID:FB-02-241217
Sample Type:Client
Inject. Date:23-Dec-2024 21:03:34 ALS Bottle#:3 Worklist Smp#:15
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:280-201015-A-3
Operator ID:bustillose Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:23-Dec-2024 22:19:41 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1673
First Level Reviewer: LP8K Date:23-Dec-2024 22:19:08
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 99 2298779 50.0
* 2 Chlorobenzene-d5 119 7.929 7.926 0.003 88 533305 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.174 10.173 0.001 97 877879 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.842 4.839 0.003 92 527273 45.1
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 98 766134 49.3
$ 6 Toluene-d8 (Surr) 98 6.637 6.636 0.001 94 2299544 50.5
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 84 885632 49.3
10 Dichlorodifluoromethane 85 1.794 ND
12 Chloromethane 50 1.974 ND
13 Vinyl chloride 62 2.090 ND
15 Bromomethane 94 2.395 ND U
16 Chloroethane 64 2.495 ND
18 Trichlorofluoromethane 101 2.717 ND
21 Ethyl ether 59 2.939 ND
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.138 ND
25 1,1-Dichloroethene 96 3.144 ND
26 Acetone 43 3.160 ND
29 Iodomethane 142 3.270 ND
30 Carbon disulfide 76 3.337 ND
32 Methyl acetate 43 3.395 ND
33 3-Chloro-1-propene 41 3.421 ND
34 Methylene Chloride 84 3.521 ND
37 Methyl tert-butyl ether 73 3.713 ND
38 trans-1,2-Dichloroethene 96 3.730 ND
39 Hexane 57 3.932 ND
40 Vinyl acetate 43 4.032 ND
42 1,1-Dichloroethane 63 4.058 ND
45 2-Butanone (MEK) 43 4.450 ND
47 cis-1,2-Dichloroethene 96 4.482 ND
48 2,2-Dichloropropane 77 4.492 ND
52 Chlorobromomethane 128 4.662 ND
53 Tetrahydrofuran 42 4.672 ND
12/27/2024
9:26:49 AM
Page 156 of 428
Report Date: 23-Dec-2024 22:19:58 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005452.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
54 Chloroform 83 4.720 4.720 0.000 94 11150 0.6664
55 1,1,1-Trichloroethane 97 4.871 ND
56 Cyclohexane 56 4.935 ND
57 1,1-Dichloropropene 75 4.987 ND
59 Carbon tetrachloride 117 4.993 ND
60 Benzene 78 5.144 ND
61 1,2-Dichloroethane 62 5.170 ND
65 Trichloroethene 95 5.639 ND
67 Methylcyclohexane 55 5.842 ND
69 1,2-Dichloropropane 63 5.848 ND
71 Dibromomethane 93 5.919 ND
72 Dichlorobromomethane 83 6.045 ND
75 cis-1,3-Dichloropropene 75 6.398 ND
76 4-Methyl-2-pentanone (MIBK) 43 6.501 ND
77 Toluene 91 6.694 ND
78 trans-1,3-Dichloropropene 75 6.868 ND
79 Ethyl methacrylate 69 6.884 ND
80 1,1,2-Trichloroethane 97 7.048 ND
82 Tetrachloroethene 164 7.147 ND
83 1,3-Dichloropropane 76 7.196 ND
84 2-Hexanone 43 7.212 ND
85 Chlorodibromomethane 129 7.392 7.395 -0.003 90 1576 0.8699
86 Ethylene Dibromide 107 7.514 ND
88 Chlorobenzene 112 7.955 ND
89 1,1,1,2-Tetrachloroethane 131 8.025 ND
90 Ethylbenzene 106 8.032 ND
91 m-Xylene & p-Xylene 106 8.144 ND
92 o-Xylene 106 8.514 ND
93 Styrene 104 8.527 ND
94 Bromoform 173 8.711 8.713 -0.002 92 10722 3.15
95 Isopropylbenzene 105 8.858 ND
98 1,1,2,2-Tetrachloroethane 83 9.141 ND
100 Bromobenzene 156 9.183 ND
101 1,2,3-Trichloropropane 110 9.209 ND
102 N-Propylbenzene 120 9.260 ND
103 2-Chlorotoluene 126 9.360 ND
104 1,3,5-Trimethylbenzene 105 9.430 ND
105 4-Chlorotoluene 126 9.479 ND
107 tert-Butylbenzene 119 9.745 ND
108 1,2,4-Trimethylbenzene 105 9.803 ND
109 sec-Butylbenzene 134 9.971 ND
110 1,3-Dichlorobenzene 146 10.099 ND
111 4-Isopropyltoluene 119 10.115 ND
112 1,4-Dichlorobenzene 146 10.199 ND
114 n-Butylbenzene 91 10.524 ND
115 1,2-Dichlorobenzene 146 10.562 ND
116 1,2-Dibromo-3-Chloropropane 157 11.347 ND
118 1,2,4-Trichlorobenzene 180 12.183 ND
119 Hexachlorobutadiene 225 12.324 ND
120 Naphthalene 128 12.456 ND
121 1,2,3-Trichlorobenzene 180 12.678 ND
S 156 Total BTEX 1 0.000 ND 7
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Report Date: 23-Dec-2024 22:19:58 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005452.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
S 155 Xylenes, Total 106 0.000 ND 7
S 152 Trihalomethanes, Total 1 0 4.68
S 154 1,3-Dichloropropene, Total 1 0.000 ND 7
S 151 1,2-Dichloroethene, Total 1 0.000 ND 7
QC Flag Legend
Processing Flags
7 - Failed Limit of Detection
Review Flags
U - Marked Undetected
Reagents:
mv-IS_SS_00094 Amount Added: 5.00 Units: uL Run Reagent
12/27/2024
9:26:49 AM
Page 158 of 428
Report Date: 23-Dec-2024 22:19:58 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005452.D
Injection Date:23-Dec-2024 21:03:34 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:280-201015-A-3 Lab Sample ID:280-201015-3 Worklist Smp#:15
Client ID:FB-02-241217
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:3
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
32
34
36
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0
0
0
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)
0000005452[MS Quad Chro]:Total

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12/27/2024
9:26:49 AM
Page 159 of 428
Report Date: 23-Dec-2024 22:19:58 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005452.D
Lims ID:280-201015-A-3
Client ID:FB-02-241217
Sample Type:Client
Inject. Date:23-Dec-2024 21:03:34 ALS Bottle#:3 Worklist Smp#:15
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:280-201015-A-3
Operator ID:bustillose Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:23-Dec-2024 22:19:41 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1673
First Level Reviewer: LP8K Date:23-Dec-2024 22:19:08
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 45.1 90.26
$5 1,2-Dichloroethane-d4 (Surr)50.0 49.3 98.60
$6 Toluene-d8 (Surr)50.0 50.5 101.02
$7 4-Bromofluorobenzene (Surr)50.0 49.3 98.65
12/27/2024
9:26:49 AM
Page 160 of 428
Report Date: 23-Dec-2024 22:19:58 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005452.D
Injection Date:23-Dec-2024 21:03:34 Instrument ID:VMS_MS14
Lims ID:280-201015-A-3 Lab Sample ID:280-201015-3
Client ID:FB-02-241217
Operator ID:bustillose ALS Bottle#:3 Worklist Smp#:15
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
85 Chlorodibromomethane, CAS: 124-48-1
30 70 110 150 190 230 270 310 350
m/z
0
2
4
6
8
10
12
14
Y ( X10
0
)
Raw Spec:Scan 1992(7.39)
129
131
79
30 70 110 150 190 230 270 310 350m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1992(7.39), Qvalue=90 Sig Qvalue=92
129
131
81 93
207
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X10
0
)
Ref Spec: 85 Chlorodibromomethane (NIST98.L)
127 129
131489193 208 21050
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 7.390 min.(Qvalue: 90)
81 131 207
6.8 7.1 7.4 7.7
Min
RT
0
3
6
9
12
Y ( X10
0
)
0000005452[MS Quad Chro]:m/z 129

7
.
3
9
2
6.8 7.1 7.4 7.7Min
RT
0
2
4
6
8
10
12
Y ( X10
0
)
0000005452[MS Quad Chro]:m/z 127

7
.
3
9
2
6.8 7.1 7.4 7.7
Min
RT
0
9
18
27
36
45
54
Y ( X10
)
0000005452[MS Quad Chro]:m/z 131
6.8 7.1 7.4 7.7
Min
0
3
6
9
12
Y ( X10
0
)
0000005452[MS Quad Chro]:m/z 129
0000005452[MS Quad Chro]:m/z 127
0000005452[MS Quad Chro]:m/z 131
12/27/2024
9:26:49 AM
Page 161 of 428
Report Date: 23-Dec-2024 22:19:58 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005452.D
Injection Date:23-Dec-2024 21:03:34 Instrument ID:VMS_MS14
Lims ID:280-201015-A-3 Lab Sample ID:280-201015-3
Client ID:FB-02-241217
Operator ID:bustillose ALS Bottle#:3 Worklist Smp#:15
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
54 Chloroform, CAS: 67-66-3
30 70 110 150 190 230 270 310 350
m/z
0
9
18
27
36
45
54
63
72
Y ( X10
0
)
Raw Spec:Scan 1161(4.72)
83
85
48 87
30 70 110 150 190 230 270 310 350m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 1161(4.72), Qvalue=94 Sig Qvalue=91
83
85
48 87
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X10
0
)
Ref Spec: 54 Chloroform (NIST98.L)
83
85
48 87
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 4.720 min.(Qvalue: 94)
87
4.2 4.5 4.8 5.1
Min
RT
0
12
24
36
48
60
72
Y ( X10
0
)
0000005452[MS Quad Chro]:m/z 83

4
.
7
2
0
4.2 4.5 4.8 5.1Min
RT
0
8
16
24
32
40
48
Y ( X10
0
)
0000005452[MS Quad Chro]:m/z 85

4
.
7
1
7
4.2 4.5 4.8 5.1
Min
RT
0
6
12
18
24
30
36
Y ( X10
0
)
0000005452[MS Quad Chro]:m/z 47

4
.
7
2
7
4.2 4.5 4.8 5.1
Min
0
2
4
6
8
10
12
Y ( X10
0
0
)
0000005452[MS Quad Chro]:m/z 83
0000005452[MS Quad Chro]:m/z 85
0000005452[MS Quad Chro]:m/z 47
12/27/2024
9:26:49 AM
Page 162 of 428
Report Date: 23-Dec-2024 22:19:58 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005452.D
Injection Date:23-Dec-2024 21:03:34 Instrument ID:VMS_MS14
Lims ID:280-201015-A-3 Lab Sample ID:280-201015-3
Client ID:FB-02-241217
Operator ID:bustillose ALS Bottle#:3 Worklist Smp#:15
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
94 Bromoform, CAS: 75-25-2
30 70 110 150 190 230 270 310 350
m/z
0
9
18
27
36
45
54
63
Y ( X10
0
)
Raw Spec:Scan 2402(8.71)
173
171
175
79 91
94 254 256160
30 70 110 150 190 230 270 310 350m/z
0
13
26
39
52
65
78
91
Y ( X10
)
Amdis Enhanced Spec: Scan 2402(8.71), Qvalue=92 Sig Qvalue=82
173
175171
91 93
252 254
30 70 110 150 190 230 270 310 350
0
2
4
6
8
10
( X10
0
)
Ref Spec: 94 Bromoform (NIST98.L)
173
171 175
91 93 252 254
30 70 110 150 190 230 270 310 350
m/z
-100
-75
-50
-25
0
25
50
75
100
Y
Differenc Spec:Scan 1 @ 8.710 min.(Qvalue: 92)
81 91
8.2 8.5 8.8 9.1
Min
RT
0
12
24
36
48
60
72
Y ( X10
0
)
0000005452[MS Quad Chro]:m/z 173

8
.
7
1
1
8.2 8.5 8.8 9.1Min
RT
0
6
12
18
24
30
Y ( X10
0
)
0000005452[MS Quad Chro]:m/z 171

8
.
7
0
4
8.2 8.5 8.8 9.1
Min
RT
0
11
22
33
44
55
66
Y ( X10
0
)
0000005452[MS Quad Chro]:m/z 175

8
.
7
0
7
8.2 8.5 8.8 9.1
Min
0
5
10
15
20
25
30
Y ( X10
0
0
)
0000005452[MS Quad Chro]:m/z 173
0000005452[MS Quad Chro]:m/z 171
0000005452[MS Quad Chro]:m/z 175
12/27/2024
9:26:49 AM
Page 163 of 428
Report Date: 23-Dec-2024 22:19:58 Chrom Revision: 2.3 17-Dec-2024 12:44:46
User Disabled Compound Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005452.D
Injection Date:23-Dec-2024 21:03:34 Instrument ID:VMS_MS14
Lims ID:280-201015-A-3 Lab Sample ID:280-201015-3
Client ID:FB-02-241217
Operator ID:bustillose ALS Bottle#:3 Worklist Smp#:15
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
15 Bromomethane, CAS: 74-83-9
Processing Results
30 70 110 150 190 230 270 310 350m/z
0
10
20
30
40
50
60
70
Y ( X10
0
)
Raw Spec:Scan 435(2.39)
9656 116
30 70 110 150 190 230 270 310 350
m/z
0
3
6
9
12
15
18
21
Y ( X10
0
)
Enhanced Spec:Scan 435(2.39) Bgrd 426( 2.36), Qvalue=1
96
54 116
30 70 110 150 190 230 270 310 350
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 15 Bromomethane (NIST98.L)
94 96
79
2.2 2.5Min
RT
0
9
18
27
36
45
54
Y ( X10
)
0000005452[MS Quad Chro]:m/z 94

2
.
3
8
6
2.2 2.5
Min
RT
0
12
24
36
48
60
72
Y ( X10
)
0000005452[MS Quad Chro]:m/z 96

2
.
3
8
6
2.2 2.5
Min
RT
0
15
30
45
60
75
90
Y ( X10
)
0000005452[MS Quad Chro]:m/z 79

2
.
3
9
9
RT Mass Response Amount
2.39 94.00 1042 1.443272
2.39 96.00 280
2.40 79.00 925
Reviewer: LP8K, 23-Dec-2024 22:19:00 -07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
12/27/2024
9:26:49 AM
Page 164 of 428
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Client Sample ID:Trip Blank Lab Sample ID:280-201015-4
Matrix:VMS14_0000005453.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
12/17/2024 09:15
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:12/23/2024 21:28
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:679543 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.14100-41-4 Ethylbenzene ND
1.0 0.13100-42-5 Styrene ND
1.0 0.1610061-01-5 cis-1,3-Dichloropropene ND
1.0 0.1410061-02-6 trans-1,3-Dichloropropene ND
1.0 0.18103-65-1 N-Propylbenzene ND
1.0 0.23104-51-8 n-Butylbenzene ND
1.0 0.21106-43-4 4-Chlorotoluene ND
1.0 0.39106-46-7 1,4-Dichlorobenzene ND
1.0 0.18106-93-4 Ethylene Dibromide ND
2.0 0.46107-05-1 3-Chloro-1-propene ND
1.0 0.28107-06-2 1,2-Dichloroethane ND
3.0 0.36108-05-4 Vinyl acetate ND
5.0 0.98108-10-1 4-Methyl-2-pentanone (MIBK)ND
1.0 0.12108-67-8 1,3,5-Trimethylbenzene ND
1.0 0.19108-86-1 Bromobenzene ND
1.0 0.31108-87-2 Methylcyclohexane ND
1.0 0.32108-88-3 Toluene ND
1.0 0.092108-90-7 Chlorobenzene ND
7.0 0.84109-99-9 Tetrahydrofuran ND
2.0 0.16110-54-3 Hexane ND
1.0 0.44110-82-7 Cyclohexane ND
1.0 0.58120-82-1 1,2,4-Trichlorobenzene ND
1.0 0.28124-48-1 Chlorodibromomethane ND
1.0 0.40127-18-4 Tetrachloroethene ND
1.0 0.20135-98-8 sec-Butylbenzene ND
1.0 0.17142-28-9 1,3-Dichloropropane ND
1.0 0.32156-59-2 cis-1,2-Dichloroethene ND
1.0 0.37156-60-5 trans-1,2-Dichloroethene ND
5.0 0.251634-04-4 Methyl tert-butyl ether ND
2.0 0.36179601-23-1 m-Xylene & p-Xylene ND
1.0 0.33541-73-1 1,3-Dichlorobenzene ND
1.0 0.2356-23-5 Carbon tetrachloride ND
FORM I 8260D
12/27/2024
9:26:49 AM
Page 165 of 428
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Client Sample ID:Trip Blank Lab Sample ID:280-201015-4
Matrix:VMS14_0000005453.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
12/17/2024 09:15
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:12/23/2024 21:28
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:679543 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.19563-58-6 1,1-Dichloropropene ND
5.0 0.81591-78-6 2-Hexanone ND
1.0 0.17594-20-7 2,2-Dichloropropane ND
2.0 0.3560-29-7 Ethyl ether ND
1.0 0.16630-20-6 1,1,1,2-Tetrachloroethane ND
15 6.667-64-1 Acetone ND
1.0 0.3667-66-3 Chloroform ND
1.0 0.1471-43-2 Benzene ND
1.0 0.3971-55-6 1,1,1-Trichloroethane ND
5.0 2.474-83-9 Bromomethane ND
2.0 0.2374-87-3 Chloromethane ND
5.0 2.674-88-4 Iodomethane ND
1.0 0.3474-95-3 Dibromomethane ND
1.0 0.4074-97-5 Chlorobromomethane ND
2.0 0.6475-00-3 Chloroethane ND
1.0 0.2375-01-4 Vinyl chloride ND
2.0 0.9475-09-2 Methylene Chloride ND
2.0 0.2675-15-0 Carbon disulfide ND
2.0 0.2575-25-2 Bromoform ND
1.0 0.1975-27-4 Dichlorobromomethane ND
1.0 0.2275-34-3 1,1-Dichloroethane ND
1.0 0.2375-35-4 1,1-Dichloroethene ND
2.0 0.2075-69-4 Trichlorofluoromethane ND
2.0 0.3075-71-8 Dichlorodifluoromethane ND
3.0 0.7376-13-1 1,1,2-Trichloro-1,2,2-trifluoroethan
e
ND
1.0 0.2478-87-5 1,2-Dichloropropane ND
10 4.678-93-3 2-Butanone (MEK)ND
1.0 0.2779-00-5 1,1,2-Trichloroethane ND
1.0 0.3079-01-6 Trichloroethene ND
5.0 1.679-20-9 Methyl acetate ND
1.0 0.2179-34-5 1,1,2,2-Tetrachloroethane ND
4.0 1.287-61-6 1,2,3-Trichlorobenzene ND
FORM I 8260D
12/27/2024
9:26:49 AM
Page 166 of 428
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Client Sample ID:Trip Blank Lab Sample ID:280-201015-4
Matrix:VMS14_0000005453.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
12/17/2024 09:15
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:12/23/2024 21:28
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:679543 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
2.0 0.5387-68-3 Hexachlorobutadiene ND
3.0 0.9991-20-3 Naphthalene ND
1.0 0.1195-47-6 o-Xylene ND
1.0 0.3495-49-8 2-Chlorotoluene ND
1.0 0.1495-50-1 1,2-Dichlorobenzene ND
1.0 0.1595-63-6 1,2,4-Trimethylbenzene ND
5.0 0.4296-12-8 1,2-Dibromo-3-Chloropropane ND
2.5 0.2896-18-4 1,2,3-Trichloropropane ND
3.0 0.1997-63-2 Ethyl methacrylate ND
1.0 0.1898-06-6 tert-Butylbenzene ND
1.0 0.1698-82-8 Isopropylbenzene ND
1.0 0.1999-87-6 4-Isopropyltoluene ND
1.0 0.111330-20-7 Xylenes, Total ND
1.0 0.32540-59-0 1,2-Dichloroethene, Total ND
1.0 0.14542-75-6 1,3-Dichloropropene, Total ND
1.0 0.19STL00209Trihalomethanes, Total ND
1.0 0.14STL00431Total BTEX ND
%RECCAS NO.LIMITSQSURROGATE
99 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr)
95 77-1201868-53-7 Dibromofluoromethane (Surr)
101 80-1252037-26-5 Toluene-d8 (Surr)
99 78-120460-00-4 4-Bromofluorobenzene (Surr)
FORM I 8260D
12/27/2024
9:26:49 AM
Page 167 of 428
Report Date: 23-Dec-2024 22:20:00 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005453.D
Lims ID:280-201015-B-4
Client ID:Trip Blank
Sample Type:Client
Inject. Date:23-Dec-2024 21:28:52 ALS Bottle#:4 Worklist Smp#:16
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:280-201015-B-4
Operator ID:bustillose Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:23-Dec-2024 22:19:41 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1673
First Level Reviewer: LP8K Date:23-Dec-2024 22:19:20
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 98 2285139 50.0
* 2 Chlorobenzene-d5 119 7.929 7.926 0.003 88 524540 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.170 10.173 -0.003 97 854109 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.839 4.839 0.000 92 554472 47.7
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 98 762941 49.4
$ 6 Toluene-d8 (Surr) 98 6.636 6.636 0.000 94 2251211 50.3
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 84 862281 49.4
10 Dichlorodifluoromethane 85 1.794 ND
12 Chloromethane 50 1.974 ND
13 Vinyl chloride 62 2.090 ND
15 Bromomethane 94 2.395 ND U
16 Chloroethane 64 2.495 ND
18 Trichlorofluoromethane 101 2.717 ND
21 Ethyl ether 59 2.939 ND
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.138 ND
25 1,1-Dichloroethene 96 3.144 ND
26 Acetone 43 3.160 ND 7
29 Iodomethane 142 3.270 ND
30 Carbon disulfide 76 3.337 ND
32 Methyl acetate 43 3.395 ND
33 3-Chloro-1-propene 41 3.421 ND
34 Methylene Chloride 84 3.521 ND
37 Methyl tert-butyl ether 73 3.713 ND
38 trans-1,2-Dichloroethene 96 3.730 ND
39 Hexane 57 3.932 ND
40 Vinyl acetate 43 4.032 ND
42 1,1-Dichloroethane 63 4.058 ND
45 2-Butanone (MEK) 43 4.450 ND
47 cis-1,2-Dichloroethene 96 4.482 ND
48 2,2-Dichloropropane 77 4.492 ND
52 Chlorobromomethane 128 4.662 ND
53 Tetrahydrofuran 42 4.672 ND
12/27/2024
9:26:49 AM
Page 168 of 428
Report Date: 23-Dec-2024 22:20:00 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005453.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
54 Chloroform 83 4.720 ND
55 1,1,1-Trichloroethane 97 4.871 ND
56 Cyclohexane 56 4.935 ND
57 1,1-Dichloropropene 75 4.987 ND
59 Carbon tetrachloride 117 4.993 ND
60 Benzene 78 5.144 ND
61 1,2-Dichloroethane 62 5.170 ND
65 Trichloroethene 95 5.639 ND
67 Methylcyclohexane 55 5.842 ND
69 1,2-Dichloropropane 63 5.848 ND
71 Dibromomethane 93 5.919 ND
72 Dichlorobromomethane 83 6.045 ND
75 cis-1,3-Dichloropropene 75 6.398 ND
76 4-Methyl-2-pentanone (MIBK) 43 6.501 ND
77 Toluene 91 6.694 ND
78 trans-1,3-Dichloropropene 75 6.868 ND
79 Ethyl methacrylate 69 6.884 ND
80 1,1,2-Trichloroethane 97 7.048 ND
82 Tetrachloroethene 164 7.147 ND
83 1,3-Dichloropropane 76 7.196 ND
84 2-Hexanone 43 7.212 ND
85 Chlorodibromomethane 129 7.395 ND
86 Ethylene Dibromide 107 7.514 ND
88 Chlorobenzene 112 7.955 ND
89 1,1,1,2-Tetrachloroethane 131 8.025 ND
90 Ethylbenzene 106 8.032 ND
91 m-Xylene & p-Xylene 106 8.144 ND
92 o-Xylene 106 8.514 ND
93 Styrene 104 8.527 ND
94 Bromoform 173 8.713 ND
95 Isopropylbenzene 105 8.858 ND
98 1,1,2,2-Tetrachloroethane 83 9.141 ND
100 Bromobenzene 156 9.183 ND
101 1,2,3-Trichloropropane 110 9.209 ND
102 N-Propylbenzene 120 9.260 ND
103 2-Chlorotoluene 126 9.360 ND
104 1,3,5-Trimethylbenzene 105 9.430 ND
105 4-Chlorotoluene 126 9.479 ND
107 tert-Butylbenzene 119 9.745 ND
108 1,2,4-Trimethylbenzene 105 9.803 ND
109 sec-Butylbenzene 134 9.971 ND
110 1,3-Dichlorobenzene 146 10.099 ND
111 4-Isopropyltoluene 119 10.115 ND
112 1,4-Dichlorobenzene 146 10.199 ND 7
114 n-Butylbenzene 91 10.524 ND
115 1,2-Dichlorobenzene 146 10.562 ND
116 1,2-Dibromo-3-Chloropropane 157 11.347 ND
118 1,2,4-Trichlorobenzene 180 12.183 ND
119 Hexachlorobutadiene 225 12.324 ND
120 Naphthalene 128 12.447 12.456 -0.009 1 1670 0.5810 M
121 1,2,3-Trichlorobenzene 180 12.678 ND
S 156 Total BTEX 1 0.000 ND 7
12/27/2024
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Page 169 of 428
Report Date: 23-Dec-2024 22:20:00 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005453.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
OnCol Amt
ug/l Flags
S 155 Xylenes, Total 106 0.000 ND 7
S 152 Trihalomethanes, Total 1 0.000 ND 7
S 154 1,3-Dichloropropene, Total 1 0.000 ND 7
S 151 1,2-Dichloroethene, Total 1 0.000 ND 7
QC Flag Legend
Processing Flags
7 - Failed Limit of Detection
Review Flags
M - Manually Integrated
U - Marked Undetected
Reagents:
mv-IS_SS_00094 Amount Added: 5.00 Units: uL Run Reagent
12/27/2024
9:26:49 AM
Page 170 of 428
Report Date: 23-Dec-2024 22:20:00 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005453.D
Injection Date:23-Dec-2024 21:28:52 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:280-201015-B-4 Lab Sample ID:280-201015-4 Worklist Smp#:16
Client ID:Trip Blank
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:4
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
32
34
36
Y ( X10
0
0
0
0
)
0000005453[MS Quad Chro]:Total
$ D
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12/27/2024
9:26:49 AM
Page 171 of 428
Report Date: 23-Dec-2024 22:20:00 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005453.D
Lims ID:280-201015-B-4
Client ID:Trip Blank
Sample Type:Client
Inject. Date:23-Dec-2024 21:28:52 ALS Bottle#:4 Worklist Smp#:16
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:280-201015-B-4
Operator ID:bustillose Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:23-Dec-2024 22:19:41 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1673
First Level Reviewer: LP8K Date:23-Dec-2024 22:19:20
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 47.7 95.49
$5 1,2-Dichloroethane-d4 (Surr)50.0 49.4 98.78
$6 Toluene-d8 (Surr)50.0 50.3 100.54
$7 4-Bromofluorobenzene (Surr)50.0 49.4 98.72
12/27/2024
9:26:49 AM
Page 172 of 428
Report Date: 23-Dec-2024 22:20:00 Chrom Revision: 2.3 17-Dec-2024 12:44:46
User Disabled Compound Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005453.D
Injection Date:23-Dec-2024 21:28:52 Instrument ID:VMS_MS14
Lims ID:280-201015-B-4 Lab Sample ID:280-201015-4
Client ID:Trip Blank
Operator ID:bustillose ALS Bottle#:4 Worklist Smp#:16
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
15 Bromomethane, CAS: 74-83-9
Processing Results
30 70 110 150 190 230 270 310 350m/z
0
8
16
24
32
40
48
56
64
Y ( X10
0
)
Raw Spec:Scan 438(2.40)
94 96
30 70 110 150 190 230 270 310 350
m/z
0
10
20
30
40
50
60
70
Y ( X10
)
Enhanced Spec:Scan 438(2.40) Bgrd 426( 2.36), Qvalue=31
94
81
54 96
105
30 70 110 150 190 230 270 310 350
0
13
26
39
52
65
78
91
( X10
0
)
Ref Spec: 15 Bromomethane (NIST98.L)
94 96
79
2.1 2.4Min
RT
0
12
24
36
48
60
72
Y ( X10
)
0000005453[MS Quad Chro]:m/z 94

2
.
3
95
2.1 2.4
Min
RT
0
14
28
42
56
70
84
Y ( X10
)
0000005453[MS Quad Chro]:m/z 96

2
.
4
0
2
2.1 2.4
Min
RT
0
14
28
42
56
70
84
Y ( X10
)
0000005453[MS Quad Chro]:m/z 79

2
.
4
0
8
RT Mass Response Amount
2.40 94.00 1486 1.497087
2.40 96.00 709
2.41 79.00 416
Reviewer: LP8K, 23-Dec-2024 22:19:12 -07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
12/27/2024
9:26:49 AM
Page 173 of 428
Report Date: 23-Dec-2024 22:20:00 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005453.D
Injection Date:23-Dec-2024 21:28:52 Instrument ID:VMS_MS14
Lims ID:280-201015-B-4 Lab Sample ID:280-201015-4
Client ID:Trip Blank
Operator ID:bustillose ALS Bottle#:4 Worklist Smp#:16
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
120 Naphthalene, CAS: 91-20-3
Signal: 1
Processing Integration Results
RT: 12.45
Area: 916
Amount: 0.567084
Amount Units: ug/l
12.1 12.3 12.5 12.7
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
Y ( X10
0
)
0000005453[MS Quad Chro]:m/z 128
1
2
.
4
4
7
Manual Integration Results
RT: 12.45
Area: 1670
Amount: 0.581009
Amount Units: ug/l
12.1 12.3 12.5 12.7
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
Y ( X10
0
)
0000005453[MS Quad Chro]:m/z 128
1
2
.
4
4
7
Reviewer: LP8K, 23-Dec-2024 22:19:17 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 174 of 428
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-201015-1 Analy Batch No.:678685
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_MS14
99935Calibration Start Date:Calibration End Date:12/17/2024 01:00
N
12/17/2024 03:40
0.25(mm)DB-624 (60.25)ID:
Calibration Files
LEVEL:LAB SAMPLE ID:LAB FILE ID:1Level IC 280-678685/13 VMS14_0000005223.D
2Level IC 280-678685/14 VMS14_0000005224.D
3Level IC 280-678685/15 VMS14_0000005225.D
4Level IC 280-678685/16 VMS14_0000005226.D
5Level IC 280-678685/17 VMS14_0000005227.D
6Level ICIS 280-678685/18 VMS14_0000005228.D
7Level IC 280-678685/19 VMS14_0000005229.D
8Level IC 280-678685/20 VMS14_0000005230.D
9Level IC 280-678685/21 VMS14_0000005231.D
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
Dichlorodifluoromethane 0.3048 0.2817 0.2394 0.2550 0.2605 Ave 11.5
0.3170 0.3216 ++++++++++
15.00.282
9Chloromethane0.3943 0.3494 0.2892 0.2814 0.2744 Ave 13.6
0.3262 0.3237 0.3943 0.3535
0.1000 15.00.331
8Vinyl chloride 0.2548 0.2347 0.2160 0.2301 0.2179 Ave 13.9
0.2593 0.2634 0.3236 0.2907
30.00.254
5Bromomethane++++++++++0.1311 0.1155 0.1253 Lin1 0.9920
0.1531 0.1665 0.2001 0.1849
0.9900-0.24
2
0.183
0Chloroethane0.1737 0.1557 0.1427 0.1360 0.1445 Ave 12.1
0.1640 0.1672 0.1987 0.1749
15.00.161
9Dichlorofluoromethane0.4097 0.3892 0.3836 0.3874 0.3930 Ave 11.2
0.4410 0.4443 0.5268 0.4638
15.00.426
5Trichlorofluoromethane0.3147 0.2591 0.2781 0.2709 0.2672 Ave 14.2
0.3046 0.3150 0.3909 0.3494
15.00.305
5Ethyl ether 0.2154 0.2007 0.1847 0.1841 0.1735 Ave 8.1
0.2043 0.2052 0.2233 0.2104
15.00.200
2Acrolein0.0625 0.0550 0.0463 0.0501 0.0522 Ave 11.9
0.0628 0.0622 0.0662 0.0602
15.00.057
5
1,1,2-Trichloro-1,2,2-trifluoroeth
ane
0.1412 0.1168 0.1220 0.1186 0.0989 Ave 10.9
0.1299 0.1328 0.1432 0.1306
15.00.126
0
1,1-Dichloroethene 0.1967 0.1831 0.1724 0.1633 0.1440 Ave 9.8
0.1813 0.1860 0.2000 0.1903
30.00.179
7Acetone+++++0.8152 0.5024 0.3383 0.2962 Lin2 0.9930
0.2831 0.2582 0.2723 0.2311
0.99002.217
1
0.246
6
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
12/27/2024
9:26:49 AM
Page 175 of 428
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-201015-1 Analy Batch No.:678685
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_MS14
99935Calibration Start Date:Calibration End Date:12/17/2024 01:00
N
12/17/2024 03:40
0.25(mm)DB-624 (60.25)ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
Iodomethane +++++++++++++++0.0978 0.0988 Lin1 0.9950
0.1734 0.1921 0.2173 0.1997
0.9900-0.73
8
0.206
1Carbon disulfide +++++0.5234 0.4942 0.4733 0.4237 Lin1 0.9950
0.6007 0.6262 0.6854 0.6218
0.9900-0.33
6
0.633
7Methyl acetate 0.5750 0.4858 0.4101 0.4200 0.4171 Ave 11.0
0.4716 0.4602 0.4898 0.4453
15.00.463
93-Chloro-1-propene +++++0.4328 0.4504 0.3531 0.2774 Lin1 0.9970
0.3377 0.3325 0.3492 +++++
0.99000.093
3
0.337
3Methylene Chloride ++++++++++0.3013 0.2469 0.2166 Ave 10.7
0.2402 0.2394 0.2560 0.2345
15.00.247
92-Methyl-2-propanol 0.1823 0.1477 0.1187 0.1387 0.1444 Ave 12.4
0.1630 0.1555 0.1686 0.1402
15.00.151
0Acrylonitrile0.2584 0.2227 0.2134 0.2098 0.2152 Ave 7.8
0.2401 0.2265 0.2368 0.2018
15.00.225
0Methyl tert-butyl ether 0.8412 0.7344 0.6974 0.6968 0.6818 Ave 6.8
0.7318 0.7242 0.7813 0.7069
15.00.732
9trans-1,2-Dichloroethene 0.2075 0.1981 0.1997 0.1813 0.1611 Ave 7.5
0.1947 0.1936 0.2081 0.1896
15.00.192
7Hexane1.4978 1.2434 1.1414 1.1135 0.9185 Ave 13.5
1.1372 1.0810 1.2049 1.0843
15.01.158
0Vinyl acetate 0.6090 0.5625 0.5464 0.5200 0.5084 Ave 5.8
0.5746 0.5550 0.5926 0.5405
15.00.556
61,1-Dichloroethane 0.4031 0.3464 0.3706 0.3521 0.3145 Ave 7.5
0.3723 0.3730 0.4027 0.3716
0.1000 15.00.367
42-Butanone (MEK)0.5134 0.4241 0.3843 0.3719 0.3807 Ave 10.9
0.4259 0.4028 0.4300 0.3717
15.00.411
6cis-1,2-Dichloroethene 0.2377 0.2306 0.2163 0.2237 0.1931 Ave 6.8
0.2251 0.2264 0.2485 0.2295
15.00.225
72,2-Dichloropropane 0.3209 0.3011 0.2852 0.2828 0.2485 Ave 8.1
0.3075 0.3073 0.3307 0.3023
15.00.298
5sec-Butyl Alcohol 0.1136 0.0931 0.0876 0.0980 0.0991 Ave 9.8
0.1119 0.1072 0.1144 0.0934
15.00.102
0Chlorobromomethane0.1146 0.0801 0.1110 0.0987 0.0930 Ave 10.9
0.1097 0.1061 0.1139 0.1038
15.00.103
4Tetrahydrofuran0.2978 0.2519 0.2331 0.2353 0.2301 Ave 8.6
0.2598 0.2473 0.2639 0.2342
15.00.250
4
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
12/27/2024
9:26:49 AM
Page 176 of 428
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-201015-1 Analy Batch No.:678685
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_MS14
99935Calibration Start Date:Calibration End Date:12/17/2024 01:00
N
12/17/2024 03:40
0.25(mm)DB-624 (60.25)ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
Chloroform 0.4020 0.3501 0.3667 0.3464 0.3126 Ave 7.3
0.3675 0.3650 0.3966 0.3683
30.00.363
91,1,1-Trichloroethane 0.3350 0.2687 0.2933 0.2722 0.2392 Ave 10.8
0.3022 0.3092 0.3351 0.3157
15.00.296
7Cyclohexane0.4259 0.3569 0.3484 0.3341 0.2797 Ave 11.1
0.3498 0.3567 0.3874 0.3514
15.00.354
51,1-Dichloropropene 0.3544 0.2736 0.2895 0.2787 0.2336 Ave 11.2
0.2905 0.2918 0.3197 0.2923
15.00.291
6Carbon tetrachloride +++++0.1482 0.1761 0.1750 0.1579 Lin1 0.9950
0.2221 0.2353 0.2597 0.2432
0.9900-0.17
7
0.243
2Isobutyl alcohol 0.0383 0.0300 0.0364 0.0381 0.0384 Ave 11.4
0.0442 0.0418 0.0441 0.0366
15.00.038
7Benzene0.9536 0.8520 0.8289 0.7861 0.6994 Ave 8.5
0.8227 0.8261 0.9041 0.8260
15.00.833
21,2-Dichloroethane 0.4289 0.3484 0.3294 0.3014 0.2886 Ave 12.2
0.3166 0.3194 0.3457 0.3216
15.00.333
3n-Heptane +++++0.3065 0.2665 0.2638 0.2210 Ave 9.7
0.2764 0.2812 0.3030 0.2758
15.00.274
3Trichloroethene0.7008 0.8989 0.8188 0.8217 0.7144 Ave 9.6
0.8464 0.8292 0.9440 0.8759
15.00.827
82-Pentanone 0.6122 0.5663 0.5340 0.5357 0.5411 Ave 6.5
0.6109 0.5897 0.6224 0.5358
15.00.572
0Methylcyclohexane0.3470 0.2941 0.2791 0.2617 0.2192 Ave 12.1
0.2766 0.2790 0.3041 0.2753
15.00.281
81,2-Dichloropropane 0.2492 0.2106 0.2113 0.2003 0.1875 Ave 8.8
0.2184 0.2211 0.2422 0.2256
30.00.218
41,4-Dioxane ++++++++++0.0055 0.0068 0.0067 Ave 12.8
0.0072 0.0070 0.0076 0.0054
15.00.006
6Dibromomethane0.1723 0.1498 0.1414 0.1340 0.1308 Ave 9.1
0.1465 0.1510 0.1657 0.1546
15.00.149
6Dichlorobromomethane0.2479 0.2293 0.2186 0.2112 0.2103 Ave 14.9
0.2601 0.2769 0.3100 0.2985
15.00.251
42-Chloroethyl vinyl ether ++++++++++0.0437 0.0356 0.0288 Ave 14.7
0.0326 0.0399 0.0391 +++++
15.00.036
6cis-1,3-Dichloropropene 1.3695 1.2621 1.2803 1.2541 1.2241 Ave 11.0
1.4497 1.4508 1.6598 1.5730
15.01.391
5
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
12/27/2024
9:26:49 AM
Page 177 of 428
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-201015-1 Analy Batch No.:678685
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_MS14
99935Calibration Start Date:Calibration End Date:12/17/2024 01:00
N
12/17/2024 03:40
0.25(mm)DB-624 (60.25)ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
4-Methyl-2-pentanone (MIBK)0.5878 0.5478 0.5106 0.5073 0.5200 Ave 6.4
0.5811 0.5616 0.5942 +++++
15.00.551
3Toluene1.0214 0.9070 0.8809 0.8510 0.7481 Ave 9.0
0.9130 0.9202 1.0121 0.9151
30.00.907
7trans-1,3-Dichloropropene +++++0.2829 0.2638 0.2712 0.2667 Lin1 0.9960
0.3408 0.3583 0.4007 0.3804
0.9900-0.24
2
0.376
6Ethyl methacrylate 1.6153 1.4967 1.4941 1.4790 1.5224 Ave 8.2
1.7264 1.6531 1.8602 1.7155
15.01.618
11,1,2-Trichloroethane 0.2199 0.1954 0.2027 0.1981 0.1837 Ave 9.6
0.2185 0.2265 0.2474 0.2338
15.00.214
0Tetrachloroethene0.7275 0.6696 0.6553 0.5903 0.5103 Ave 9.9
0.6178 0.6149 0.6942 0.6395
15.00.635
51,3-Dichloropropane 1.8840 1.5998 1.4791 1.4817 1.4878 Ave 8.4
1.5796 1.5274 1.7207 1.5785
15.01.593
22-Hexanone 2.2449 1.9356 1.8351 1.8341 1.9175 Ave 8.3
2.0285 1.8461 1.9901 1.6736
15.01.922
8Chlorodibromomethane+++++0.5609 0.6089 0.5955 0.6313 Lin1 0.9910
0.7921 0.8160 0.9449 +++++
0.9900-0.60
6
0.866
7Ethylene Dibromide 1.1092 0.8758 0.8806 0.8561 0.8568 Ave 10.0
0.9767 0.9568 1.0780 1.0098
15.00.955
51-Chlorohexane +++++1.6718 1.3109 1.1437 0.9403 Lin1 0.9960
1.1689 1.1469 1.3219 1.2039
0.99000.100
1
1.209
6Chlorobenzene2.7109 2.5934 2.3264 2.2217 2.0259 Ave 8.9
2.3578 2.2674 2.5662 2.3373
0.3000 15.02.378
61,1,1,2-Tetrachloroethane 0.7411 0.6228 0.6277 0.6349 0.6041 Ave 13.3
0.7526 0.7571 0.8660 0.8160
15.00.713
6Ethylbenzene1.4529 1.2526 1.1166 1.2012 1.0442 Ave 10.0
1.2702 1.2221 1.3913 1.2397
30.01.243
4m-Xylene & p-Xylene 1.9661 1.6218 1.5017 1.4930 1.3079 Ave 11.8
1.5586 1.4621 1.6905 1.4871
15.01.565
4o-Xylene 1.7838 1.6082 1.3658 1.4664 1.3265 Ave 9.6
1.5824 1.4640 1.6844 1.5012
15.01.531
4Styrene2.8064 2.5110 2.3354 2.3830 2.1999 Ave 8.5
2.6865 2.5387 2.8564 2.5331
15.02.538
9Bromoform++++++++++0.3862 0.4013 0.4202 Lin1 0.9920
0.5752 0.6095 0.7159 0.7060
0.1000 0.9900-1.14
7
0.683
9
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
12/27/2024
9:26:49 AM
Page 178 of 428
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-201015-1 Analy Batch No.:678685
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_MS14
99935Calibration Start Date:Calibration End Date:12/17/2024 01:00
N
12/17/2024 03:40
0.25(mm)DB-624 (60.25)ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
Isopropylbenzene 2.5242 2.2206 2.0576 2.1664 1.8009 Ave 10.9
2.2909 2.2611 2.6284 2.3722
15.02.258
0Cyclohexanone0.2205 0.1572 0.1495 0.1648 0.1707 Ave 14.0
0.1811 0.1623 0.1817 0.1379
15.00.169
51,1,2,2-Tetrachloroethane 1.0739 0.9208 0.8676 0.9003 0.8535 Ave 9.9
0.9994 0.9910 1.1234 1.0569
0.3000 15.00.976
3trans-1,4-Dichloro-2-butene +++++0.1010 0.1750 0.2000 0.2114 Lin1 0.9930
0.3157 0.3318 0.3880 0.3701
0.9900-0.43
6
0.362
4Bromobenzene0.6222 0.5913 0.5820 0.5581 0.4972 Ave 8.4
0.5959 0.5916 0.6794 0.6265
15.00.593
81,2,3-Trichloropropane 0.4087 0.3335 0.3019 0.3357 0.3151 Ave 10.0
0.3616 0.3462 0.3968 0.3620
15.00.351
3N-Propylbenzene 0.7968 0.6593 0.5957 0.6168 0.5045 Ave 12.6
0.6448 0.6188 0.7231 0.6447
15.00.644
92-Chlorotoluene 0.6705 0.6191 0.5332 0.5522 0.4601 Ave 10.8
0.5566 0.5344 0.6218 0.5681
15.00.568
51,3,5-Trimethylbenzene 2.3661 2.0128 1.9563 1.9341 1.6808 Ave 10.0
2.0310 1.8343 2.2184 1.9552
15.01.998
84-Chlorotoluene 0.7390 0.5842 0.5613 0.5821 0.5003 Ave 11.3
0.5764 0.5586 0.6479 0.5803
15.00.592
2tert-Butylbenzene 2.0243 1.8150 1.7089 1.7286 1.4398 Ave 9.7
1.7823 1.7265 2.0034 1.7863
15.01.779
41,2,4-Trimethylbenzene 2.4661 1.9864 1.9613 2.0118 1.7727 Ave 10.3
2.1047 1.8786 2.3010 2.0526
15.02.059
5sec-Butylbenzene 0.5918 0.4916 0.4823 0.4979 0.4171 Ave 10.0
0.5148 0.4997 0.5743 0.5119
15.00.509
01,3-Dichlorobenzene 1.4217 1.1567 1.1098 1.0944 0.9658 Ave 11.0
1.1299 1.1122 1.2770 1.1559
15.01.158
24-Isopropyltoluene 2.5452 2.0373 2.0410 2.0843 1.8291 Ave 10.1
2.2715 2.0996 2.4291 2.1505
15.02.165
31,4-Dichlorobenzene 1.5061 1.2161 1.1326 1.0996 0.9585 Ave 12.9
1.1277 1.0893 1.2616 1.1536
15.01.171
7n-Butylbenzene 2.5352 1.9732 1.9140 1.9602 1.6984 Ave 11.9
2.1520 1.9924 2.3330 2.1124
15.02.074
51,2-Dichlorobenzene 1.2614 1.1215 1.0520 1.0565 0.9463 Ave 8.5
1.1299 1.0795 1.2231 1.1312
15.01.111
3
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
12/27/2024
9:26:49 AM
Page 179 of 428
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-201015-1 Analy Batch No.:678685
CURVE EVALUATION
SDG No.:
Calibration ID:
Instrument ID:GC Column:Heated Purge: (Y/N)VMS_MS14
99935Calibration Start Date:Calibration End Date:12/17/2024 01:00
N
12/17/2024 03:40
0.25(mm)DB-624 (60.25)ID:
ANALYTE RRF
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CURVE
TYPE
COEFFICIENT
B M1 M2
#%RSD #MAX
%RSD R^2
OR COD
#MIN R^2
OR COD
MIN RRF
/RSE /RSE
LVL 6 LVL 7 LVL 8 LVL 9
1,2-Dibromo-3-Chloropropane ++++++++++0.2257 0.2389 0.2389 Lin1 0.9940
0.3386 0.3418 0.4028 0.3930
0.9900-0.59
8
0.383
81,2,4-Trichlorobenzene +++++0.6431 0.6136 0.6474 0.6010 Ave 14.6
0.7222 0.7610 0.8777 0.8326
15.00.712
3Hexachlorobutadiene0.2982 0.2706 0.2725 0.2846 0.2510 Ave 11.8
0.3170 0.3206 0.3649 0.3319
15.00.301
2Naphthalene+++++2.4418 2.2903 2.3743 2.3801 Lin1 0.9950
3.0561 3.0036 3.4832 3.1060
0.9900-1.74
4
3.169
91,2,3-Trichlorobenzene 0.7828 0.6937 0.6367 0.6191 0.6013 Ave 12.6
0.7221 0.7479 0.8663 0.8054
15.00.719
5Dibromofluoromethane (Surr)0.2489 0.2444 0.2522 0.2495 0.2542 Ave 2.3
0.2573 0.2596 0.2595 0.2613
15.00.254
11,2-Dichloroethane-d4 (Surr)0.3452 0.3398 0.3403 0.3382 0.3393 Ave 1.2
0.3319 0.3374 0.3381 0.3317
15.00.338
0Toluene-d8 (Surr)4.3597 4.3657 4.3556 4.4050 4.3849 Ave 3.2
4.2287 4.0421 4.1526 4.1226
15.04.268
54-Bromofluorobenzene (Surr)1.0303 1.0199 1.0050 1.0188 0.9901 Ave 1.8
1.0146 1.0350 1.0355 1.0547
15.01.022
7
FORM VI 8260D
Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.
12/27/2024
9:26:49 AM
Page 180 of 428
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-201015-1 Analy Batch No.:678685
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_MS14
99935Calibration Start Date:Calibration End Date:12/17/2024 01:00
N
12/17/2024 03:40
GC Column:DB-624 (60.25)ID:0.25(mm)
Calibration Files:
LEVEL:LAB SAMPLE ID:LAB FILE ID:
Level 1 IC 280-678685/13 VMS14_0000005223.D
Level 2 IC 280-678685/14 VMS14_0000005224.D
Level 3 IC 280-678685/15 VMS14_0000005225.D
Level 4 IC 280-678685/16 VMS14_0000005226.D
Level 5 IC 280-678685/17 VMS14_0000005227.D
Level 6 ICIS 280-678685/18 VMS14_0000005228.D
Level 7 IC 280-678685/19 VMS14_0000005229.D
Level 8 IC 280-678685/20 VMS14_0000005230.D
Level 9 IC 280-678685/21 VMS14_0000005231.D
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
Dichlorodifluoromethane AveFB 7267 12694 22120 58705 112429 0.500 1.00 2.00 5.00 10.0
593405 ++++++++++75.050.0++++++++++972109
Chloromethane AveFB 9401 15742 26720 64777 118417 0.500 1.00 2.00 5.00 10.0
610672 20010075.050.029276101508221978356
Vinyl chloride AveFB 6075 10575 19958 52971 94009 0.500 1.00 2.00 5.00 10.0
485497 20010075.050.024075361238026796163
Bromomethane Lin1FB ++++++++++12113 26576 54084 ++++++++++2.00 5.00 10.0
286595 20010075.050.01531269765276503129
Chloroethane AveFB 4142 7014 13185 31299 62371 0.500 1.00 2.00 5.00 10.0
306968 20010075.050.01448643760117505232
Dichlorofluoromethane AveFB 9769 17538 35439 89173 169597 0.500 1.00 2.00 5.00 10.0
825528 20010075.050.0384146420152781342908
Trichlorofluoromethane AveFB 7504 11674 25699 62351 115318 0.500 1.00 2.00 5.00 10.0
570167 20010075.050.028942321495220951986
Ethyl ether AveFB 5135 9042 17064 42381 74874 0.500 1.00 2.00 5.00 10.0
382366 20010075.050.01742373854385620240
Acrolein AveFB 14718 24456 42210 113865 222245 4.94 9.88 19.8 49.4 98.8
1161162 1975988741494492257925002861857772
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
AveFB 3366 5262 11275 27305 42666 0.500 1.00 2.00 5.00 10.0
243092 20010075.050.01081922547730401417
1,1-Dichloroethene AveFB 4691 8251 15926 37596 62147 0.500 1.00 2.00 5.00 10.0
339421 20010075.050.01576155765098562064
Acetone Lin2FB +++++146918 185690 311465 511350 +++++4.00 8.00 20.0 40.0
2120070 800400300200765782641664673121494
Iodomethane Lin1FB +++++++++++++++22503 42624 +++++++++++++++5.00 10.0
324583 20010075.050.01654247831414580671
Carbon disulfide Lin1FB +++++23583 45659 108938 182854 +++++1.00 2.00 5.00 10.0
1124493 20010075.050.0515050426219911892618
FORM VI 8260D 12/27/2024
9:26:49 AM
Page 181 of 428
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-201015-1 Analy Batch No.:678685
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_MS14
99935Calibration Start Date:Calibration End Date:12/17/2024 01:00
N
12/17/2024 03:40
GC Column:DB-624 (60.25)ID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
Methyl acetate AveFB 27420 43778 75774 193365 359941 1.00 2.00 4.00 10.0 20.0
1765672 400200150100737738137473642781652
3-Chloro-1-propene Lin1FB +++++19500 41612 81285 119689 +++++1.00 2.00 5.00 10.0
632154 +++++10075.050.0+++++13358041004965
Methylene Chloride AveFB ++++++++++27840 56837 93482 ++++++++++2.00 5.00 10.0
449723 20010075.050.01942456979468723460
2-Methyl-2-propanol AveFB 43478 66545 109669 319232 623253 5.00 10.0 20.0 50.0 100
3051902 200010007505001161258764513624698819
Acrylonitrile AveFB 61617 100340 197208 482853 928772 5.00 10.0 20.0 50.0 100
4494248 200010007505001671545490573546845362
Methyl tert-butyl ether AveFB 20059 33092 64436 160384 294217 0.500 1.00 2.00 5.00 10.0
1369888 20010075.050.0585503729888602188764
trans-1,2-Dichloroethene AveFB 4949 8927 18451 41738 69509 0.500 1.00 2.00 5.00 10.0
364567 20010075.050.01570154796126585249
Hexane AveCBNZd
5
8301 13369 25111 60607 93808 0.500 1.00 2.00 5.00 10.0
533228 20010075.050.023211341183304862768
Vinyl acetate AveFB 29041 50685 100975 239377 438810 1.00 2.00 4.00 10.0 20.0
2151296 400200150100895460645334733354728
1,1-Dichloroethane AveFB 9611 15606 34245 81033 135731 0.500 1.00 2.00 5.00 10.0
697031 20010075.050.0307764615406411127206
2-Butanone (MEK)AveFB 48968 76432 142037 342387 657087 2.00 4.00 8.00 20.0 40.0
3189266 8004003002001231665365801944869179
cis-1,2-Dichloroethene AveFB 5668 10392 19987 51492 83322 0.500 1.00 2.00 5.00 10.0
421444 20010075.050.01900770950519684155
2,2-Dichloropropane AveFB 7652 13566 26350 65087 107248 0.500 1.00 2.00 5.00 10.0
575579 20010075.050.025037921264972928879
sec-Butyl Alcohol AveFB 64989 100697 194348 541144 1025844 12.0 24.0 48.0 120 240
5029635 480024001800120018571721105073857778215
Chlorobromomethane AveFB 2733 3609 10256 22724 40113 0.500 1.00 2.00 5.00 10.0
205409 20010075.050.0859366435620320610
Tetrahydrofuran AveFB 14203 22699 43068 108306 198579 1.00 2.00 4.00 10.0 20.0
972563 400200150100388041820191881494929
Chloroform AveFB 9586 15774 33880 79736 134908 0.500 1.00 2.00 5.00 10.0
687984 20010075.050.0305056115172791103259
1,1,1-Trichloroethane AveFB 7988 12108 27101 62645 103224 0.500 1.00 2.00 5.00 10.0
565817 20010075.050.026152251281735934516
Cyclohexane AveFB 10156 16079 32194 76899 120685 0.500 1.00 2.00 5.00 10.0
654860 20010075.050.0291025714818371078214
1,1-Dichloropropene AveFB 8451 12326 26747 64149 100796 0.500 1.00 2.00 5.00 10.0
543794 20010075.050.024210221223094881985
FORM VI 8260D 12/27/2024
9:26:49 AM
Page 182 of 428
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-201015-1 Analy Batch No.:678685
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_MS14
99935Calibration Start Date:Calibration End Date:12/17/2024 01:00
N
12/17/2024 03:40
GC Column:DB-624 (60.25)ID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
Carbon tetrachloride Lin1FB +++++6678 16267 40291 68146 +++++1.00 2.00 5.00 10.0
415782 20010075.050.02014519993323711267
Isobutyl alcohol AveFB 22856 33795 84110 219304 413984 12.5 25.0 50.0 125 250
2070468 5000250018751250758023542219693159561
Benzene AveFB 22739 38390 76586 180934 301812 0.500 1.00 2.00 5.00 10.0
1540202 20010075.050.0684193534583942496743
1,2-Dichloroethane AveFB 10228 15697 30436 69373 124533 0.500 1.00 2.00 5.00 10.0
592598 20010075.050.026639751322488965314
n-Heptane AveFB +++++13812 24627 60715 95364 +++++1.00 2.00 5.00 10.0
517475 20010075.050.022847771158885849859
Trichloroethene AveCBNZd
5
3884 9665 18014 44725 72960 0.500 1.00 2.00 5.00 10.0
396862 20010075.050.01875058927111661836
2-Pentanone AveFB 46713 81648 157868 394548 747205 1.60 3.20 6.40 16.0 32.0
3659782 6403202401601420065476182615703155
Methylcyclohexane AveFB 8273 13250 25790 60243 94579 0.500 1.00 2.00 5.00 10.0
517741 20010075.050.022804471163413843292
1,2-Dichloropropane AveFB 5942 9487 19521 46102 80898 0.500 1.00 2.00 5.00 10.0
408781 20010075.050.01868466926574668177
1,4-Dioxane AveFB ++++++++++10134 31440 57839 ++++++++++40.0 100 200
269292 4000200015001000888674578982423979
Dibromomethane AveFB 4108 6751 13064 30845 56425 0.500 1.00 2.00 5.00 10.0
274336 20010075.050.01280607633827456504
Dichlorobromomethane AveFB 5912 10333 20193 48615 90742 0.500 1.00 2.00 5.00 10.0
486872 20010075.050.024726701185880836885
2-Chloroethyl vinyl ether AveFB ++++++++++4037 8187 12449 ++++++++++2.00 5.00 10.0
61020 +++++10075.050.0+++++149626120465
cis-1,3-Dichloropropene AveCBNZd
5
7590 13570 28167 68258 125025 0.500 1.00 2.00 5.00 10.0
679725 20010075.050.0336726816300691157896
4-Methyl-2-pentanone (MIBK)AveFB 56060 98736 188706 467022 897523 2.00 4.00 8.00 20.0 40.0
4351443 +++++400300200+++++90921076789199
Toluene AveFB 24356 40866 81393 195872 322839 0.500 1.00 2.00 5.00 10.0
1709226 20010075.050.0757934738717972781057
trans-1,3-Dichloropropene Lin1FB +++++12745 24377 62431 115090 +++++1.00 2.00 5.00 10.0
637945 20010075.050.0315084615329021082921
Ethyl methacrylate AveCBNZd
5
8952 16093 32871 80501 155488 0.500 1.00 2.00 5.00 10.0
809490 20010075.050.0367227518269291319358
1,1,2-Trichloroethane AveFB 5244 8804 18729 45605 79280 0.500 1.00 2.00 5.00 10.0
409117 20010075.050.01936225946439684456
FORM VI 8260D 12/27/2024
9:26:49 AM
Page 183 of 428
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-201015-1 Analy Batch No.:678685
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_MS14
99935Calibration Start Date:Calibration End Date:12/17/2024 01:00
N
12/17/2024 03:40
GC Column:DB-624 (60.25)ID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
Tetrachloroethene AveCBNZd
5
4032 7200 14417 32131 52119 0.500 1.00 2.00 5.00 10.0
289702 20010075.050.01369028681809490736
1,3-Dichloropropane AveCBNZd
5
10441 17201 32540 80644 151954 0.500 1.00 2.00 5.00 10.0
740643 20010075.050.0337898716899191219083
2-Hexanone AveCBNZd5 49764 83248 161491 399312 783373 2.00 4.00 8.00 20.0 40.0
3804567 8004003002001433016078179035893796
Chlorodibromomethane Lin1CBNZd
5
+++++6031 13396 32411 64474 +++++1.00 2.00 5.00 10.0
371398 +++++10075.050.0+++++928041651290
Ethylene Dibromide AveCBNZd
5
6147 9417 19373 46598 87507 0.500 1.00 2.00 5.00 10.0
457945 20010075.050.021615461058672763628
1-Chlorohexane Lin1CBNZd
5
+++++14380 23072 49797 76826 +++++0.800 1.60 4.00 8.00
438465 16080.060.040.020617811038632732283
Chlorobenzene AveCBNZd
5
15024 27885 51181 120922 206909 0.500 1.00 2.00 5.00 10.0
1105567 20010075.050.0500338825202321809710
1,1,1,2-Tetrachloroethane AveCBNZd
5
4107 6696 13810 34555 61699 0.500 1.00 2.00 5.00 10.0
352872 20010075.050.01746719850540604243
Ethylbenzene AveCBNZd
5 8052 13468 24565 65379 106648 0.500 1.00 2.00 5.00 10.0
595598 20010075.050.026537351366356975360
m-Xylene & p-Xylene AveCBNZd5 10896 17438 33037 81258 133576 0.500 1.00 2.00 5.00 10.0
730820 20010075.050.0318336716602831166938
o-Xylene AveCBNZd
5
9886 17292 30048 79812 135484 0.500 1.00 2.00 5.00 10.0
741953 20010075.050.0321358616542751168496
Styrene AveCBNZd
5
15553 26999 51378 129699 224686 0.500 1.00 2.00 5.00 10.0
1259662 20010075.050.0542241128052732026174
Bromoform Lin1CBNZd
5
++++++++++8497 21843 42920 ++++++++++2.00 5.00 10.0
269696 20010075.050.01511311703097486494
Isopropylbenzene AveDCBd4 22524 39584 73732 189992 307682 0.500 1.00 2.00 5.00 10.0
1749109 20010075.050.0757692939612062832836
Cyclohexanone AveCBNZd
5
36658 50714 98671 269155 523013 15.0 30.0 60.0 150 300
FORM VI 8260D 12/27/2024
9:26:49 AM
Page 184 of 428
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-201015-1 Analy Batch No.:678685
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_MS14
99935Calibration Start Date:Calibration End Date:12/17/2024 01:00
N
12/17/2024 03:40
GC Column:DB-624 (60.25)ID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
2547982 6000300022501500885497653530533886912
1,1,2,2-Tetrachloroethane AveDCBd4 9583 16413 31088 78955 145818 0.500 1.00 2.00 5.00 10.0
763061 20010075.050.0337581916931321241589
trans-1,4-Dichloro-2-butene Lin1DCBd4 +++++1801 6272 17544 36122 +++++1.00 2.00 5.00 10.0
241044 20010075.050.01182136584799415692
Bromobenzene AveDCBd4 5552 10541 20855 48946 84950 0.500 1.00 2.00 5.00 10.0
454983 20010075.050.020011061023976741232
1,2,3-Trichloropropane AveDCBd4 3647 5945 10817 29438 53831 0.500 1.00 2.00 5.00 10.0
276059 20010075.050.01156251597967433696
N-Propylbenzene AveDCBd4 7110 11753 21346 54094 86193 0.500 1.00 2.00 5.00 10.0
492278 20010075.050.020593401089819775253
2-Chlorotoluene AveDCBd4 5983 11036 19108 48426 78607 0.500 1.00 2.00 5.00 10.0
424990 20010075.050.01814693937096669511
1,3,5-Trimethylbenzene AveDCBd4 21113 35880 70100 169622 287174 0.500 1.00 2.00 5.00 10.0
1550656 20010075.050.0624498733433202298155
4-Chlorotoluene AveDCBd4 6594 10413 20113 51051 85470 0.500 1.00 2.00 5.00 10.0
440056 20010075.050.01853579976446699852
tert-Butylbenzene AveDCBd4 18063 32354 61234 151597 245996 0.500 1.00 2.00 5.00 10.0
1360770 20010075.050.0570578030192702163046
1,2,4-Trimethylbenzene AveDCBd4 22006 35409 70279 176431 302870 0.500 1.00 2.00 5.00 10.0
1606966 20010075.050.0655633534679032353619
sec-Butylbenzene AveDCBd4 5281 8763 17281 43666 71255 0.500 1.00 2.00 5.00 10.0
393021 20010075.050.01635162865556626094
1,3-Dichlorobenzene AveDCBd4 12686 20619 39767 95983 165011 0.500 1.00 2.00 5.00 10.0
862717 20010075.050.0369205419246381393389
4-Isopropyltoluene AveDCBd4 22712 36316 73136 182789 312505 0.500 1.00 2.00 5.00 10.0
1734296 20010075.050.0686899436609312630429
1,4-Dichlorobenzene AveDCBd4 13439 21678 40584 96438 163762 0.500 1.00 2.00 5.00 10.0
860986 20010075.050.0368482619014121364764
n-Butylbenzene AveDCBd4 22622 35174 68584 171912 290178 0.500 1.00 2.00 5.00 10.0
1643023 20010075.050.0674718535161302496130
1,2-Dichlorobenzene AveDCBd4 11256 19992 37697 92658 161672 0.500 1.00 2.00 5.00 10.0
862661 20010075.050.0361320718433761352416
1,2-Dibromo-3-Chloropropane Lin1DCBd4 ++++++++++8086 20954 40820 ++++++++++2.00 5.00 10.0
258496 20010075.050.01255228607047428181
1,2,4-Trichlorobenzene AveDCBd4 +++++11463 21988 56774 102690 +++++1.00 2.00 5.00 10.0
551379 20010075.050.026595241322794953445
Hexachlorobutadiene AveDCBd4 2661 4823 9763 24959 42891 0.500 1.00 2.00 5.00 10.0
242051 20010075.050.01060004549962401633
Naphthalene Lin1DCBd4 +++++43527 82070 208224 406650 +++++1.00 2.00 5.00 10.0
2333336 20010075.050.0992096952495923763068
FORM VI 8260D 12/27/2024
9:26:49 AM
Page 185 of 428
FORM VI
Lab Name:Job No.:
GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA
Eurofins Denver 280-201015-1 Analy Batch No.:678685
RESPONSE AND CONCENTRATION
SDG No.:
Calibration ID:
Instrument ID:Heated Purge: (Y/N)VMS_MS14
99935Calibration Start Date:Calibration End Date:12/17/2024 01:00
N
12/17/2024 03:40
GC Column:DB-624 (60.25)ID:0.25(mm)
ANALYTE CURVE
TYPE
IS
REF
RESPONSE
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
CONCENTRATION (UG/L)
LVL 1 LVL 2 LVL 3 LVL 4 LVL 5
LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9
1,2,3-Trichlorobenzene AveDCBd4 6985 12365 22816 54293 102726 0.500 1.00 2.00 5.00 10.0
551306 20010075.050.025724811305664936964
Dibromofluoromethane (Surr)AveFB 593445 550525 582600 574305 548543 50.0 50.0 50.0 50.0 50.0
481603 50.050.050.050.0541166496371523151
1,2-Dichloroethane-d4 (Surr)AveFB 823181 765621 786057 778359 732114 50.0 50.0 50.0 50.0 50.0
621403 50.050.050.050.0686951646604679742
Toluene-d8 (Surr)AveCBNZd
5
2416136 2347047 2395593 2397535 2239193 50.0 50.0 50.0 50.0 50.0
1982786 50.050.050.050.0220626820391512150722
4-Bromofluorobenzene (Surr)AveDCBd4 919335 908988 900357 893477 845784 50.0 50.0 50.0 50.0 50.0
774660 50.050.050.050.0842211780326864454
Curve Type Legend:
Ave = Average ISTD
Lin1 = Linear 1/conc ISTDLin2 = Linear 1/conc^2 ISTD
FORM VI 8260D 12/27/2024
9:26:49 AM
Page 186 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:1
Inject. Date:17-Dec-2024 01:00:10 ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ic
Misc. Info.:0.5
Operator ID:bustillose Instrument ID:VMS_MS14
Sublist:chrom-AQ_VMS14_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:18-Dec-2024 06:16:20 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: LP8K Date:17-Dec-2024 14:52:50
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 98 2384488 50.0 50.0
* 2 Chlorobenzene-d5 119 7.926 7.929 -0.003 89 554198 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.170 0.003 97 892330 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.839 4.839 0.000 93 593445 50.0 49.0
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 99 823181 50.0 51.1
$ 6 Toluene-d8 (Surr) 98 6.633 6.636 -0.003 94 2416136 50.0 51.1
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 84 919335 50.0 50.4
10 Dichlorodifluoromethane 85 1.791 1.794 -0.003 98 7267 0.5000 0.5387
12 Chloromethane 50 1.974 1.974 0.000 99 9401 0.5000 0.5941
13 Vinyl chloride 62 2.090 2.087 0.003 97 6075 0.5000 0.5005
15 Bromomethane 94 2.383 2.399 -0.016 86 6528 0.5000 2.07
16 Chloroethane 64 2.482 2.498 -0.016 37 4142 0.5000 0.5364
17 Dichlorofluoromethane 67 2.672 2.678 -0.006 97 9769 0.5000 0.4802
18 Trichlorofluoromethane 101 2.717 2.720 -0.003 96 7504 0.5000 0.5150
21 Ethyl ether 59 2.939 2.939 0.000 90 5135 0.5000 0.5379
22 Acrolein 56 3.055 3.055 0.000 97 14718 4.94 5.37 M
25 1,1-Dichloroethene 96 3.148 3.141 0.007 84 4691 0.5000 0.5474
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.141 3.141 0.000 64 3366 0.5000 0.5602
26 Acetone 43 3.158 3.161 -0.003 99 141943 2.00 3.08
29 Iodomethane 142 3.270 ND ND
30 Carbon disulfide 76 3.331 3.337 -0.006 99 15780 0.5000 1.05
32 Methyl acetate 43 3.395 3.399 -0.004 96 27420 1.00 1.24
33 3-Chloro-1-propene 41 3.386 3.421 -0.035 74 54208 0.5000 3.09
34 Methylene Chloride 84 3.518 3.521 -0.003 92 13579 0.5000 1.15
35 2-Methyl-2-propanol 59 3.569 3.566 0.003 99 43478 5.00 6.04
36 Acrylonitrile 53 3.685 3.688 -0.003 99 61617 5.00 5.74
37 Methyl tert-butyl ether 73 3.717 3.714 0.003 93 20059 0.5000 0.5739 M
38 trans-1,2-Dichloroethene 96 3.723 3.730 -0.007 74 4949 0.5000 0.5387
39 Hexane 57 3.923 3.936 -0.013 86 8301 0.5000 0.6467 M
40 Vinyl acetate 43 4.029 4.032 -0.003 97 29041 1.00 1.09
12/27/2024
9:26:49 AM
Page 187 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
42 1,1-Dichloroethane 63 4.061 4.058 0.003 90 9611 0.5000 0.5486 M
45 2-Butanone (MEK) 43 4.453 4.450 0.003 99 48968 2.00 2.49
47 cis-1,2-Dichloroethene 96 4.476 4.482 -0.006 39 5668 0.5000 0.5267
48 2,2-Dichloropropane 77 4.489 4.495 -0.006 57 7652 0.5000 0.5376 Ma
50 sec-Butyl Alcohol 45 4.569 4.566 0.003 99 64989 12.0 13.4
52 Chlorobromomethane 128 4.659 4.659 0.000 63 2733 0.5000 0.5541 M
53 Tetrahydrofuran 42 4.678 4.672 0.006 88 14203 1.00 1.19 M
54 Chloroform 83 4.717 4.720 -0.003 93 9586 0.5000 0.5523 M
55 1,1,1-Trichloroethane 97 4.871 4.871 0.000 77 7988 0.5000 0.5645
56 Cyclohexane 56 4.936 4.936 0.000 90 10156 0.5000 0.6008 M
57 1,1-Dichloropropene 75 4.990 4.987 0.003 62 8451 0.5000 0.6078
59 Carbon tetrachloride 117 4.993 4.997 -0.004 21 4109 0.5000 1.08 M
58 Isobutyl alcohol 41 4.997 4.997 0.000 92 22856 12.5 12.4 M
60 Benzene 78 5.141 5.148 -0.007 91 22739 0.5000 0.5722
61 1,2-Dichloroethane 62 5.167 5.170 -0.003 95 10228 0.5000 0.6434 a
63 n-Heptane 43 5.328 5.331 -0.003 42 9091 0.5000 0.6950 M
65 Trichloroethene 95 5.646 5.640 0.006 95 3884 0.5000 0.4233 M
66 2-Pentanone 43 5.739 5.739 0.000 99 46713 1.60 1.71
67 Methylcyclohexane 55 5.839 5.842 -0.003 93 8273 0.5000 0.6156
69 1,2-Dichloropropane 63 5.842 5.849 -0.007 81 5942 0.5000 0.5704
70 1,4-Dioxane 88 5.891 5.913 -0.022 80 4793 10.0 15.2
71 Dibromomethane 93 5.920 5.919 0.001 86 4108 0.5000 0.5759
72 Dichlorobromomethane 83 6.045 6.045 0.000 97 5912 0.5000 0.4931
74 2-Chloroethyl vinyl ether 63 6.247 ND ND
75 cis-1,3-Dichloropropene 75 6.402 6.402 0.000 91 7590 0.5000 0.4921
76 4-Methyl-2-pentanone (MIBK) 43 6.501 6.501 0.000 96 56060 2.00 2.13
77 Toluene 91 6.691 6.694 -0.003 97 24356 0.5000 0.5627
78 trans-1,3-Dichloropropene 75 6.862 6.868 -0.006 82 6829 0.5000 1.02
79 Ethyl methacrylate 69 6.887 6.887 0.000 91 8952 0.5000 0.4991
80 1,1,2-Trichloroethane 97 7.042 7.048 -0.006 89 5244 0.5000 0.5138
82 Tetrachloroethene 164 7.151 7.151 0.000 89 4032 0.5000 0.5724 M
83 1,3-Dichloropropane 76 7.193 7.196 -0.003 68 10441 0.5000 0.5913 Ma
84 2-Hexanone 43 7.212 7.212 0.000 97 49764 2.00 2.33
85 Chlorodibromomethane 129 7.395 7.395 0.000 87 3510 0.5000 1.06
86 Ethylene Dibromide 107 7.511 7.514 -0.003 95 6147 0.5000 0.5804 M
87 1-Chlorohexane 91 7.913 7.906 0.007 34 12103 0.4000 0.8199 M
88 Chlorobenzene 112 7.958 7.955 0.003 41 15024 0.5000 0.5699 M
89 1,1,1,2-Tetrachloroethane 131 8.026 8.029 -0.003 53 4107 0.5000 0.5193 M
90 Ethylbenzene 106 8.035 8.032 0.003 99 8052 0.5000 0.5842
91 m-Xylene & p-Xylene 106 8.148 8.148 0.000 97 10896 0.5000 0.6280
92 o-Xylene 106 8.511 8.511 0.000 96 9886 0.5000 0.5824
93 Styrene 104 8.527 8.527 0.000 93 15553 0.5000 0.5527
94 Bromoform 173 8.710 ND ND
95 Isopropylbenzene 105 8.852 8.855 -0.003 97 22524 0.5000 0.5589
97 Cyclohexanone 55 8.961 8.961 0.000 92 36658 15.0 19.5
98 1,1,2,2-Tetrachloroethane 83 9.141 9.141 0.000 96 9583 0.5000 0.5500
99 trans-1,4-Dichloro-2-butene 53 9.177 9.177 0.000 39 1624 0.5000 1.45
100 Bromobenzene 156 9.186 9.186 0.000 95 5552 0.5000 0.5239
101 1,2,3-Trichloropropane 110 9.215 9.209 0.006 81 3647 0.5000 0.5818
102 N-Propylbenzene 120 9.260 9.260 0.000 99 7110 0.5000 0.6177
103 2-Chlorotoluene 126 9.360 9.360 0.000 95 5983 0.5000 0.5898
104 1,3,5-Trimethylbenzene 105 9.427 9.431 -0.004 95 21113 0.5000 0.5919
12/27/2024
9:26:49 AM
Page 188 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
105 4-Chlorotoluene 126 9.472 9.479 -0.007 98 6594 0.5000 0.6239
107 tert-Butylbenzene 119 9.749 9.749 0.000 92 18063 0.5000 0.5688
108 1,2,4-Trimethylbenzene 105 9.804 9.800 0.004 96 22006 0.5000 0.5987
109 sec-Butylbenzene 134 9.974 9.964 0.010 95 5281 0.5000 0.5813
110 1,3-Dichlorobenzene 146 10.099 10.096 0.003 96 12686 0.5000 0.6138
111 4-Isopropyltoluene 119 10.116 10.112 0.004 97 22712 0.5000 0.5877
112 1,4-Dichlorobenzene 146 10.202 10.199 0.003 86 13439 0.5000 0.6427
114 n-Butylbenzene 91 10.527 10.524 0.003 98 22622 0.5000 0.6110
115 1,2-Dichlorobenzene 146 10.562 10.559 0.003 88 11256 0.5000 0.5676
116 1,2-Dibromo-3-Chloropropane 157 11.350 11.344 0.006 65 2176 0.5000 1.88 M
118 1,2,4-Trichlorobenzene 180 12.180 12.180 0.000 91 8190 0.5000 0.6442
119 Hexachlorobutadiene 225 12.334 12.324 0.010 84 2661 0.5000 0.4950 M
120 Naphthalene 128 12.460 12.456 0.004 89 25984 0.5000 1.01
121 1,2,3-Trichlorobenzene 180 12.681 12.681 0.000 92 6985 0.5000 0.5440
136 Butadiene 54 0.000 ND ND
S 156 Total BTEX 1 0 2.93
S 155 Xylenes, Total 106 0 1.00 1.21
S 152 Trihalomethanes, Total 1 0 2.00 2.11
S 154 1,3-Dichloropropene, Total 1 0 1.00 1.52
S 151 1,2-Dichloroethene, Total 1 0 1.00 1.07
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Review Flags
M - Manually Integrated
a - User Assigned ID
Reagents:
Cal Dil Std_00438 Amount Added: 5.00 Units: uL
mv-IS_SS_00093 Amount Added: 5.00 Units: uL Run Reagent
12/27/2024
9:26:49 AM
Page 189 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:ic Worklist Smp#:13
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:1
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
32
34
36
38
Y ( X10
0
0
0
0
)
0000005223[MS Quad Chro]:Total

D
i
c
h
l
o
r
o
dif
l
u
o
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12/27/2024
9:26:49 AM
Page 190 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
22 Acrolein, CAS: 107-02-8
Signal: 1
Processing Integration Results
RT: 3.05
Area: 9053
Amount: 5.775246
Amount Units: ug/l
2.7 2.9 3.1 3.3
Min
0
6
12
18
24
30
36
42
48
54
60
66
72
78
84
90
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 56

3
.
0
5
5
Manual Integration Results
RT: 3.05
Area: 14718
Amount: 5.368208
Amount Units: ug/l
2.7 2.9 3.1 3.3
Min
RT
0
7
14
21
28
35
42
49
56
63
70
77
84
91
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 56

3
.
0
5
5
Reviewer: LP8K, 17-Dec-2024 14:50:44 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 191 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
37 Methyl tert-butyl ether, CAS: 1634-04-4
Signal: 1
Processing Integration Results
RT: 3.72
Area: 10135
Amount: 0.309511
Amount Units: ug/l
3.4 3.6 3.8 4.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
Y ( X10
0
0
)
0000005223[MS Quad Chro]:m/z 73

3
.
7
1
7
Manual Integration Results
RT: 3.72
Area: 20059
Amount: 0.573925
Amount Units: ug/l
3.4 3.6 3.8 4.0
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
Y ( X10
0
0
)
0000005223[MS Quad Chro]:m/z 73

3
.
7
1
7
Reviewer: LP8K, 17-Dec-2024 14:50:54 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 192 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
39 Hexane, CAS: 110-54-3
Signal: 1
Processing Integration Results
RT: 3.92
Area: 4407
Amount: 0.368173
Amount Units: ug/l
3.6 3.8 4.0 4.2
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 57

3
.
9
2
3
Manual Integration Results
RT: 3.92
Area: 8301
Amount: 0.646734
Amount Units: ug/l
3.6 3.8 4.0 4.2
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
48
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 57

3
.
9
2
3
Reviewer: LP8K, 17-Dec-2024 14:50:59 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 193 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
42 1,1-Dichloroethane, CAS: 75-34-3
Signal: 1
Processing Integration Results
RT: 4.05
Area: 5350
Amount: 0.322823
Amount Units: ug/l
3.7 3.9 4.1 4.3
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
52
56
60
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 63

4
.
0
5
5
Manual Integration Results
RT: 4.06
Area: 9611
Amount: 0.548590
Amount Units: ug/l
3.7 3.9 4.1 4.3
Min
RT
0
5
10
15
20
25
30
35
40
45
50
55
60
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 63

4
.
0
6
1
Reviewer: LP8K, 17-Dec-2024 14:51:03 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 194 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
48 2,2-Dichloropropane, CAS: 594-20-7
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 4.49
4.2 4.4 4.6 4.8
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 77
Manual Integration Results
RT: 4.49
Area: 7652
Amount: 0.537582
Amount Units: ug/l
4.2 4.4 4.6 4.8
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
39
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 77

4
.
4
8
9
Reviewer: LP8K, 17-Dec-2024 15:29:20 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 195 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
52 Chlorobromomethane, CAS: 74-97-5
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 4.66
4.3 4.5 4.7 4.9
Min
0
2
4
6
8
10
12
14
16
18
20
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 128
Manual Integration Results
RT: 4.66
Area: 2733
Amount: 0.554095
Amount Units: ug/l
4.3 4.5 4.7 4.9
Min
RT
0
2
4
6
8
10
12
14
16
18
20
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 128

4
.
6
5
9
Reviewer: LP8K, 17-Dec-2024 14:51:16 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 196 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
53 Tetrahydrofuran, CAS: 109-99-9
Signal: 1
Processing Integration Results
RT: 4.67
Area: 5740
Amount: 0.790494
Amount Units: ug/l
4.3 4.5 4.7 4.9
Min
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 42

4
.
6
6
9
Manual Integration Results
RT: 4.68
Area: 14203
Amount: 1.189496
Amount Units: ug/l
4.3 4.5 4.7 4.9
Min
RT
0
6
12
18
24
30
36
42
48
54
60
66
72
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 42

4
.
6
7
8
Reviewer: LP8K, 17-Dec-2024 14:51:13 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 197 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
54 Chloroform, CAS: 67-66-3
Signal: 1
Processing Integration Results
RT: 4.72
Area: 8313
Amount: 0.486921
Amount Units: ug/l
4.4 4.6 4.8 5.0
Min
0
5
10
15
20
25
30
35
40
45
50
55
60
65
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 83

4
.
7
1
7
Manual Integration Results
RT: 4.72
Area: 9586
Amount: 0.552333
Amount Units: ug/l
4.4 4.6 4.8 5.0
Min
RT
0
5
10
15
20
25
30
35
40
45
50
55
60
65
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 83

4
.
7
1
7
Reviewer: LP8K, 17-Dec-2024 14:51:21 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 198 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
56 Cyclohexane, CAS: 110-82-7
Signal: 1
Processing Integration Results
RT: 4.94
Area: 6809
Amount: 0.421321
Amount Units: ug/l
4.6 4.8 5.0 5.2
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
52
56
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 56

4
.
9
3
6
Manual Integration Results
RT: 4.94
Area: 10156
Amount: 0.600775
Amount Units: ug/l
4.6 4.8 5.0 5.2
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
48
52
56
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 56

4
.
9
3
6
Reviewer: LP8K, 17-Dec-2024 14:51:25 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 199 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
59 Carbon tetrachloride, CAS: 56-23-5
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 5.00
4.7 4.9 5.1 5.3
Min
0
2
4
6
8
10
12
14
16
18
20
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 117
Manual Integration Results
RT: 4.99
Area: 4109
Amount: 1.084099
Amount Units: ug/l
4.7 4.9 5.1 5.3
Min
RT
0
2
4
6
8
10
12
14
16
18
20
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 117

4
.
9
9
3
Reviewer: LP8K, 17-Dec-2024 15:09:08 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
12/27/2024
9:26:49 AM
Page 200 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
58 Isobutyl alcohol, CAS: 78-83-1
Signal: 1
Processing Integration Results
RT: 5.00
Area: 12965
Amount: 12.688673
Amount Units: ug/l
4.7 4.9 5.1 5.3
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
Y ( X10
0
0
)
0000005223[MS Quad Chro]:m/z 41

4
.
9
9
7
Manual Integration Results
RT: 5.00
Area: 22856
Amount: 12.392905
Amount Units: ug/l
4.7 4.9 5.1 5.3
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
Y ( X10
0
0
)
0000005223[MS Quad Chro]:m/z 41

4
.
9
9
7
Reviewer: LP8K, 17-Dec-2024 14:51:34 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 201 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
61 1,2-Dichloroethane, CAS: 107-06-2
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 5.17
4.8 5.0 5.2 5.4
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
Y ( X10
0
0
)
0000005223[MS Quad Chro]:m/z 62
Manual Integration Results
RT: 5.17
Area: 10228
Amount: 0.643407
Amount Units: ug/l
4.8 5.0 5.2 5.4
Min
RT
0
2
4
6
8
10
12
14
16
18
20
22
24
Y ( X10
0
0
)
0000005223[MS Quad Chro]:m/z 62

5
.
1
6
7
Reviewer: LP8K, 17-Dec-2024 14:51:39 -07:00:00 (UTC)
Audit Action: Assigned Compound ID Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 202 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
63 n-Heptane, CAS: 142-82-5
Signal: 1
Processing Integration Results
RT: 5.33
Area: 5385
Amount: 0.419922
Amount Units: ug/l
5.0 5.2 5.4 5.6
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
52
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 43

5
.
3
2
8
Manual Integration Results
RT: 5.33
Area: 9091
Amount: 0.695003
Amount Units: ug/l
5.0 5.2 5.4 5.6
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
48
52
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 43

5
.
3
2
8
Reviewer: LP8K, 17-Dec-2024 14:51:52 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 203 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
65 Trichloroethene, CAS: 79-01-6
Signal: 1
Processing Integration Results
RT: 5.64
Area: 3307
Amount: 0.365533
Amount Units: ug/l
5.3 5.5 5.7 5.9
Min
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 95

5
.
6
4
0
Manual Integration Results
RT: 5.65
Area: 3884
Amount: 0.423311
Amount Units: ug/l
5.3 5.5 5.7 5.9
Min
RT
0
7
14
21
28
35
42
49
56
63
70
77
84
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 95

5
.
6
4
6
Reviewer: LP8K, 17-Dec-2024 14:51:45 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 204 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
82 Tetrachloroethene, CAS: 127-18-4
Signal: 1
Processing Integration Results
RT: 7.14
Area: 2025
Amount: 0.460410
Amount Units: ug/l
6.8 7.0 7.2 7.4
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 164

7
.
1
4
1
Manual Integration Results
RT: 7.15
Area: 4032
Amount: 0.572403
Amount Units: ug/l
6.8 7.0 7.2 7.4
Min
RT
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 164

7
.
1
5
1
Reviewer: LP8K, 17-Dec-2024 14:52:01 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 205 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
83 1,3-Dichloropropane, CAS: 142-28-9
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 7.20
6.9 7.1 7.3 7.5
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
52
56
60
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 76
Manual Integration Results
RT: 7.19
Area: 10441
Amount: 0.591270
Amount Units: ug/l
6.9 7.1 7.3 7.5
Min
RT
0
5
10
15
20
25
30
35
40
45
50
55
60
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 76

7
.
1
9
3
Reviewer: LP8K, 17-Dec-2024 14:52:09 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 206 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
86 Ethylene Dibromide, CAS: 106-93-4
Signal: 1
Processing Integration Results
RT: 7.51
Area: 4058
Amount: 0.400722
Amount Units: ug/l
7.2 7.4 7.6 7.8
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 107

7
.
5
1
1
Manual Integration Results
RT: 7.51
Area: 6147
Amount: 0.580402
Amount Units: ug/l
7.2 7.4 7.6 7.8
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
39
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 107

7
.
5
1
1
Reviewer: LP8K, 17-Dec-2024 14:52:14 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 207 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
87 1-Chlorohexane, CAS: 544-10-5
Signal: 1
Processing Integration Results
RT: 7.90
Area: 4776
Amount: 0.375009
Amount Units: ug/l
7.6 7.8 8.0 8.2
Min
0
2
4
6
8
10
12
14
16
Y ( X10
0
0
)
0000005223[MS Quad Chro]:m/z 91

7
.
9
0
3
Manual Integration Results
RT: 7.91
Area: 12103
Amount: 0.819935
Amount Units: ug/l
7.6 7.8 8.0 8.2
Min
RT
0
2
4
6
8
10
12
14
16
Y ( X10
0
0
)
0000005223[MS Quad Chro]:m/z 91

7
.
9
1
3
Reviewer: LP8K, 17-Dec-2024 14:52:18 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 208 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
88 Chlorobenzene, CAS: 108-90-7
Signal: 1
Processing Integration Results
RT: 7.95
Area: 8013
Amount: 0.441067
Amount Units: ug/l
7.6 7.8 8.0 8.2
Min
0
7
14
21
28
35
42
49
56
63
70
77
84
91
98
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 112

7
.
9
4
8
Manual Integration Results
RT: 7.96
Area: 15024
Amount: 0.569869
Amount Units: ug/l
7.6 7.8 8.0 8.2
Min
RT
0
7
14
21
28
35
42
49
56
63
70
77
84
91
98
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 112

7
.
9
5
8
Reviewer: LP8K, 17-Dec-2024 14:52:22 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 209 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
89 1,1,1,2-Tetrachloroethane, CAS: 630-20-6
Signal: 1
Processing Integration Results
RT: 8.03
Area: 3485
Amount: 0.770395
Amount Units: ug/l
7.7 7.9 8.1 8.3
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 131

8
.
0
2
6
Manual Integration Results
RT: 8.03
Area: 4107
Amount: 0.519265
Amount Units: ug/l
7.7 7.9 8.1 8.3
Min
RT
0
2
4
6
8
10
12
14
16
18
20
22
24
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 131

8
.
0
2
6
Reviewer: LP8K, 17-Dec-2024 14:52:25 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 210 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
116 1,2-Dibromo-3-Chloropropane, CAS: 96-12-8
Signal: 1
Processing Integration Results
RT: 11.35
Area: 1943
Amount: 0.402209
Amount Units: ug/l
11.0 11.2 11.4 11.6
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 157
1
1
.
3
5
0
Manual Integration Results
RT: 11.35
Area: 2176
Amount: 1.875491
Amount Units: ug/l
11.0 11.2 11.4 11.6
Min
RT
0
2
4
6
8
10
12
14
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 157
1
1
.
3
5
0
Reviewer: LP8K, 17-Dec-2024 14:52:40 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 211 of 428
Report Date: 18-Dec-2024 06:16:22 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005223.D
Injection Date:17-Dec-2024 01:00:10 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:1 Worklist Smp#:13
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
119 Hexachlorobutadiene, CAS: 87-68-3
Signal: 1
Processing Integration Results
RT: 12.33
Area: 1935
Amount: 0.621698
Amount Units: ug/l
12.0 12.2 12.4 12.6
Min
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2
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14
16
18
20
Y ( X10
0
)
0000005223[MS Quad Chro]:m/z 225
1
2
.
3
3
4
Manual Integration Results
RT: 12.33
Area: 2661
Amount: 0.494952
Amount Units: ug/l
12.0 12.2 12.4 12.6
Min
RT
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0000005223[MS Quad Chro]:m/z 225
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Reviewer: LP8K, 17-Dec-2024 14:52:43 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 212 of 428
Report Date: 18-Dec-2024 06:16:27 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005224.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:2
Inject. Date:17-Dec-2024 01:20:09 ALS Bottle#:2 Worklist Smp#:14
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ic
Operator ID:bustillose Instrument ID:VMS_MS14
Sublist:chrom-AQ_VMS14_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:18-Dec-2024 06:16:27 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: LP8K Date:17-Dec-2024 14:55:07
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 98 2252863 50.0 50.0
* 2 Chlorobenzene-d5 119 7.929 7.929 0.000 89 537610 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.170 10.170 0.000 97 891281 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.839 4.839 0.000 92 550525 50.0 48.1
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 99 765621 50.0 50.3
$ 6 Toluene-d8 (Surr) 98 6.637 6.636 0.001 94 2347047 50.0 51.1
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 84 908988 50.0 49.9
10 Dichlorodifluoromethane 85 1.791 1.794 -0.003 97 12694 1.00 1.00
12 Chloromethane 50 1.974 1.974 0.000 99 15742 1.00 1.05
13 Vinyl chloride 62 2.090 2.087 0.003 97 10575 1.00 0.9222
15 Bromomethane 94 2.402 2.399 0.003 88 7090 1.00 2.18
16 Chloroethane 64 2.489 2.498 -0.009 95 7014 1.00 0.9614 M
17 Dichlorofluoromethane 67 2.675 2.678 -0.003 96 17538 1.00 0.9126
18 Trichlorofluoromethane 101 2.720 2.720 0.000 97 11674 1.00 0.8480
21 Ethyl ether 59 2.936 2.939 -0.003 92 9042 1.00 1.00 M
22 Acrolein 56 3.055 3.055 0.000 97 24456 9.88 9.44
25 1,1-Dichloroethene 96 3.145 3.141 0.004 66 8251 1.00 1.02
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.145 3.141 0.004 41 5262 1.00 0.9269 M
26 Acetone 43 3.161 3.161 0.000 99 146918 4.00 4.23
29 Iodomethane 142 3.267 3.270 -0.003 79 3687 1.00 3.98 M
30 Carbon disulfide 76 3.335 3.337 -0.003 99 23583 1.00 1.36
32 Methyl acetate 43 3.396 3.399 -0.003 98 43778 2.00 2.09
33 3-Chloro-1-propene 41 3.415 3.421 -0.006 74 19500 1.00 1.01
34 Methylene Chloride 84 3.521 3.521 0.000 93 16410 1.00 1.47
35 2-Methyl-2-propanol 59 3.572 3.566 0.006 99 66545 10.0 9.78 M
36 Acrylonitrile 53 3.685 3.688 -0.003 98 100340 10.0 9.90
37 Methyl tert-butyl ether 73 3.717 3.714 0.003 94 33092 1.00 1.00
38 trans-1,2-Dichloroethene 96 3.730 3.730 0.000 97 8927 1.00 1.03 M
39 Hexane 57 3.929 3.936 -0.007 89 13369 1.00 1.07
40 Vinyl acetate 43 4.032 4.032 0.000 97 50685 2.00 2.02
42 1,1-Dichloroethane 63 4.052 4.058 -0.006 95 15606 1.00 0.9428
12/27/2024
9:26:49 AM
Page 213 of 428
Report Date: 18-Dec-2024 06:16:27 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005224.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
45 2-Butanone (MEK) 43 4.453 4.450 0.003 100 76432 4.00 4.12
47 cis-1,2-Dichloroethene 96 4.479 4.482 -0.003 85 10392 1.00 1.02
48 2,2-Dichloropropane 77 4.495 4.495 0.000 91 13566 1.00 1.01
50 sec-Butyl Alcohol 45 4.566 4.566 0.000 98 100697 24.0 21.9
52 Chlorobromomethane 128 4.656 4.659 -0.003 96 3609 1.00 0.7744
53 Tetrahydrofuran 42 4.672 4.672 0.000 91 22699 2.00 2.01
54 Chloroform 83 4.720 4.720 0.000 94 15774 1.00 0.9620
55 1,1,1-Trichloroethane 97 4.875 4.871 0.004 91 12108 1.00 0.9056
56 Cyclohexane 56 4.939 4.936 0.003 89 16079 1.00 1.01
57 1,1-Dichloropropene 75 4.984 4.987 -0.003 83 12326 1.00 0.9383
59 Carbon tetrachloride 117 4.997 4.997 0.000 41 6678 1.00 1.34 M
58 Isobutyl alcohol 41 4.997 4.997 0.000 92 33795 25.0 19.4
60 Benzene 78 5.142 5.148 -0.006 90 38390 1.00 1.02
61 1,2-Dichloroethane 62 5.170 5.170 0.000 96 15697 1.00 1.05 a
63 n-Heptane 43 5.331 5.331 0.000 53 13812 1.00 1.12
65 Trichloroethene 95 5.640 5.640 0.000 96 9665 1.00 1.09
66 2-Pentanone 43 5.736 5.739 -0.003 99 81648 3.20 3.17
67 Methylcyclohexane 55 5.836 5.842 -0.006 86 13250 1.00 1.04
69 1,2-Dichloropropane 63 5.849 5.849 0.000 73 9487 1.00 0.9639
70 1,4-Dioxane 88 5.894 5.913 -0.019 27 3526 20.0 11.9
71 Dibromomethane 93 5.926 5.919 0.007 90 6751 1.00 1.00 M
72 Dichlorobromomethane 83 6.045 6.045 0.000 97 10333 1.00 0.9121
74 2-Chloroethyl vinyl ether 63 6.248 6.247 0.001 15 1502 1.00 0.9105 M
75 cis-1,3-Dichloropropene 75 6.402 6.402 0.000 94 13570 1.00 0.9070 M
76 4-Methyl-2-pentanone (MIBK) 43 6.498 6.501 -0.003 97 98736 4.00 3.97
77 Toluene 91 6.698 6.694 0.004 98 40866 1.00 1.00
78 trans-1,3-Dichloropropene 75 6.865 6.868 -0.003 90 12745 1.00 1.39 M
79 Ethyl methacrylate 69 6.887 6.887 0.000 91 16093 1.00 0.9250
80 1,1,2-Trichloroethane 97 7.042 7.048 -0.006 90 8804 1.00 0.9130
82 Tetrachloroethene 164 7.148 7.151 -0.003 94 7200 1.00 1.05
83 1,3-Dichloropropane 76 7.203 7.196 0.007 92 17201 1.00 1.00 M
84 2-Hexanone 43 7.212 7.212 0.000 96 83248 4.00 4.03
85 Chlorodibromomethane 129 7.389 7.395 -0.006 87 6031 1.00 1.35
86 Ethylene Dibromide 107 7.518 7.514 0.004 97 9417 1.00 0.9166
87 1-Chlorohexane 91 7.910 7.906 0.004 85 14380 0.8000 1.02 M
88 Chlorobenzene 112 7.952 7.955 -0.003 94 27885 1.00 1.09
89 1,1,1,2-Tetrachloroethane 131 8.026 8.029 -0.003 42 6696 1.00 0.8727
90 Ethylbenzene 106 8.026 8.032 -0.006 99 13468 1.00 1.01
91 m-Xylene & p-Xylene 106 8.148 8.148 0.000 99 17438 1.00 1.04
92 o-Xylene 106 8.514 8.511 0.003 97 17292 1.00 1.05
93 Styrene 104 8.531 8.527 0.003 93 26999 1.00 0.9890
94 Bromoform 173 8.714 8.710 0.004 82 3947 1.00 2.21 M
95 Isopropylbenzene 105 8.855 8.855 0.000 96 39584 1.00 0.9834
97 Cyclohexanone 55 8.958 8.961 -0.003 93 50714 30.0 27.8
98 1,1,2,2-Tetrachloroethane 83 9.141 9.141 0.000 95 16413 1.00 0.9431
99 trans-1,4-Dichloro-2-butene 53 9.183 9.177 0.006 44 1801 1.00 1.48 M
100 Bromobenzene 156 9.183 9.186 -0.003 97 10541 1.00 1.00
101 1,2,3-Trichloropropane 110 9.212 9.209 0.003 85 5945 1.00 0.9495
102 N-Propylbenzene 120 9.257 9.260 -0.003 99 11753 1.00 1.02
103 2-Chlorotoluene 126 9.360 9.360 0.000 95 11036 1.00 1.09
104 1,3,5-Trimethylbenzene 105 9.428 9.431 -0.003 93 35880 1.00 1.01
105 4-Chlorotoluene 126 9.479 9.479 0.000 98 10413 1.00 0.9864
12/27/2024
9:26:49 AM
Page 214 of 428
Report Date: 18-Dec-2024 06:16:27 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005224.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
107 tert-Butylbenzene 119 9.749 9.749 0.000 93 32354 1.00 1.02
108 1,2,4-Trimethylbenzene 105 9.804 9.800 0.004 97 35409 1.00 0.9645
109 sec-Butylbenzene 134 9.968 9.964 0.004 95 8763 1.00 0.9657
110 1,3-Dichlorobenzene 146 10.103 10.096 0.007 82 20619 1.00 1.00
111 4-Isopropyltoluene 119 10.112 10.112 0.000 98 36316 1.00 0.9409
112 1,4-Dichlorobenzene 146 10.193 10.199 -0.006 93 21678 1.00 1.04
114 n-Butylbenzene 91 10.524 10.524 0.000 99 35174 1.00 0.9512
115 1,2-Dichlorobenzene 146 10.559 10.559 0.000 95 19992 1.00 1.01
116 1,2-Dibromo-3-Chloropropane 157 11.347 11.344 0.003 68 3530 1.00 2.07 M
118 1,2,4-Trichlorobenzene 180 12.177 12.180 -0.003 92 11463 1.00 0.9028
119 Hexachlorobutadiene 225 12.321 12.324 -0.003 92 4823 1.00 0.8981
120 Naphthalene 128 12.453 12.456 -0.003 98 43527 1.00 1.32
121 1,2,3-Trichlorobenzene 180 12.682 12.681 0.001 94 12365 1.00 0.9641 Ma
136 Butadiene 54 0.000 ND ND
S 156 Total BTEX 1 0 5.12
S 155 Xylenes, Total 106 0 2.00 2.09
S 152 Trihalomethanes, Total 1 0 4.00 5.43
S 154 1,3-Dichloropropene, Total 1 0 2.00 2.30
S 151 1,2-Dichloroethene, Total 1 0 2.00 2.05
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Review Flags
M - Manually Integrated
a - User Assigned ID
Reagents:
Cal Dil Std_00438 Amount Added: 10.00 Units: uL
mv-IS_SS_00093 Amount Added: 5.00 Units: uL Run Reagent
12/27/2024
9:26:49 AM
Page 215 of 428
Report Date: 18-Dec-2024 06:16:27 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005224.D
Injection Date:17-Dec-2024 01:20:09 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:ic Worklist Smp#:14
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:2
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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12/27/2024
9:26:49 AM
Page 216 of 428
Report Date: 18-Dec-2024 06:16:27 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005224.D
Injection Date:17-Dec-2024 01:20:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:2 Worklist Smp#:14
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
16 Chloroethane, CAS: 75-00-3
Signal: 1
Processing Integration Results
RT: 2.50
Area: 4103
Amount: 0.811408
Amount Units: ug/l
2.2 2.4 2.6 2.8
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 64

2
.
4
9
9
Manual Integration Results
RT: 2.49
Area: 7014
Amount: 0.961353
Amount Units: ug/l
2.2 2.4 2.6 2.8
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
39
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 64

2
.
4
8
9
Reviewer: LP8K, 17-Dec-2024 14:53:10 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 217 of 428
Report Date: 18-Dec-2024 06:16:27 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005224.D
Injection Date:17-Dec-2024 01:20:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:2 Worklist Smp#:14
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
21 Ethyl ether, CAS: 60-29-7
Signal: 1
Processing Integration Results
RT: 2.94
Area: 7488
Amount: 0.846441
Amount Units: ug/l
2.6 2.8 3.0 3.2
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
52
56
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 59

2
.
9
3
6
Manual Integration Results
RT: 2.94
Area: 9042
Amount: 1.002537
Amount Units: ug/l
2.6 2.8 3.0 3.2
Min
RT
0
5
10
15
20
25
30
35
40
45
50
55
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 59

2
.
9
3
6
Reviewer: LP8K, 17-Dec-2024 14:53:15 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 218 of 428
Report Date: 18-Dec-2024 06:16:27 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005224.D
Injection Date:17-Dec-2024 01:20:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:2 Worklist Smp#:14
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
24 1,1,2-Trichloro-1,2,2-trifluoroe, CAS: 76-13-1
Signal: 1
Processing Integration Results
RT: 3.14
Area: 3490
Amount: 0.886883
Amount Units: ug/l
2.8 3.0 3.2 3.4
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 151

3
.
1
3
5
Manual Integration Results
RT: 3.14
Area: 5262
Amount: 0.926898
Amount Units: ug/l
2.8 3.0 3.2 3.4
Min
RT
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 151

3
.
1
4
5
Reviewer: LP8K, 17-Dec-2024 14:53:18 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 219 of 428
Report Date: 18-Dec-2024 06:16:27 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005224.D
Injection Date:17-Dec-2024 01:20:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:2 Worklist Smp#:14
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
29 Iodomethane, CAS: 74-88-4
Signal: 1
Processing Integration Results
RT: 3.27
Area: 2984
Amount: 3.079271
Amount Units: ug/l
2.9 3.1 3.3 3.5
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 142

3
.
2
6
7
Manual Integration Results
RT: 3.27
Area: 3687
Amount: 3.980624
Amount Units: ug/l
2.9 3.1 3.3 3.5
Min
RT
0
2
4
6
8
10
12
14
16
18
20
22
24
26
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 142

3
.
2
6
7
Reviewer: LP8K, 17-Dec-2024 14:53:23 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 220 of 428
Report Date: 18-Dec-2024 06:16:27 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005224.D
Injection Date:17-Dec-2024 01:20:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:2 Worklist Smp#:14
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
35 2-Methyl-2-propanol, CAS: 75-65-0
Signal: 1
Processing Integration Results
RT: 3.57
Area: 42962
Amount: 7.320571
Amount Units: ug/l
3.2 3.4 3.6 3.8 4.0
Min
0
2
4
6
8
10
12
14
16
18
20
Y ( X10
0
0
)
0000005224[MS Quad Chro]:m/z 59

3
.
5
7
2
Manual Integration Results
RT: 3.57
Area: 66545
Amount: 9.779413
Amount Units: ug/l
3.2 3.4 3.6 3.8 4.0
Min
RT
0
2
4
6
8
10
12
14
16
18
20
Y ( X10
0
0
)
0000005224[MS Quad Chro]:m/z 59

3
.
5
7
2
Reviewer: LP8K, 17-Dec-2024 14:53:33 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 221 of 428
Report Date: 18-Dec-2024 06:16:27 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005224.D
Injection Date:17-Dec-2024 01:20:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:2 Worklist Smp#:14
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
38 trans-1,2-Dichloroethene, CAS: 156-60-5
Signal: 1
Processing Integration Results
RT: 3.73
Area: 5816
Amount: 0.697810
Amount Units: ug/l
3.4 3.6 3.8 4.0
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
52
56
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 96

3
.
7
3
0
Manual Integration Results
RT: 3.73
Area: 8927
Amount: 1.028419
Amount Units: ug/l
3.4 3.6 3.8 4.0
Min
RT
0
4
8
12
16
20
24
28
32
36
40
44
48
52
56
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 96

3
.
7
3
0
Reviewer: LP8K, 17-Dec-2024 14:53:41 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 222 of 428
Report Date: 18-Dec-2024 06:16:27 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005224.D
Injection Date:17-Dec-2024 01:20:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:2 Worklist Smp#:14
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
59 Carbon tetrachloride, CAS: 56-23-5
Signal: 1
Processing Integration Results
RT: 5.00
Area: 5505
Amount: 0.645807
Amount Units: ug/l
4.7 4.9 5.1 5.3
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 117

4
.
9
9
7
Manual Integration Results
RT: 5.00
Area: 6678
Amount: 1.339236
Amount Units: ug/l
4.7 4.9 5.1 5.3
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
39
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 117

4
.
9
9
7
Reviewer: LP8K, 17-Dec-2024 14:53:49 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 223 of 428
Report Date: 18-Dec-2024 06:16:27 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005224.D
Injection Date:17-Dec-2024 01:20:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:2 Worklist Smp#:14
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
61 1,2-Dichloroethane, CAS: 107-06-2
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 5.17
4.8 5.0 5.2 5.4
Min
0
2
4
6
8
10
12
14
16
18
20
22
Y ( X10
0
0
)
0000005224[MS Quad Chro]:m/z 62
Manual Integration Results
RT: 5.17
Area: 15697
Amount: 1.045134
Amount Units: ug/l
4.8 5.0 5.2 5.4
Min
RT
0
2
4
6
8
10
12
14
16
18
20
22
Y ( X10
0
0
)
0000005224[MS Quad Chro]:m/z 62

5
.
1
7
0
Reviewer: LP8K, 17-Dec-2024 14:53:53 -07:00:00 (UTC)
Audit Action: Assigned Compound ID Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 224 of 428
Report Date: 18-Dec-2024 06:16:27 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005224.D
Injection Date:17-Dec-2024 01:20:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:2 Worklist Smp#:14
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
71 Dibromomethane, CAS: 74-95-3
Signal: 1
Processing Integration Results
RT: 5.92
Area: 1712
Amount: 0.277046
Amount Units: ug/l
5.6 5.8 6.0 6.2
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 93

5
.
9
1
6
Manual Integration Results
RT: 5.93
Area: 6751
Amount: 1.001726
Amount Units: ug/l
5.6 5.8 6.0 6.2
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 93

5
.
9
2
6
Reviewer: LP8K, 17-Dec-2024 14:54:01 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 225 of 428
Report Date: 18-Dec-2024 06:16:27 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005224.D
Injection Date:17-Dec-2024 01:20:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:2 Worklist Smp#:14
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
74 2-Chloroethyl vinyl ether, CAS: 110-75-8
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 6.25
5.9 6.1 6.3 6.5
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 63
Manual Integration Results
RT: 6.25
Area: 1502
Amount: 0.910471
Amount Units: ug/l
5.9 6.1 6.3 6.5
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
12
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 63

6
.
2
4
8
Reviewer: LP8K, 17-Dec-2024 14:54:12 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
12/27/2024
9:26:49 AM
Page 226 of 428
Report Date: 18-Dec-2024 06:16:27 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005224.D
Injection Date:17-Dec-2024 01:20:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:2 Worklist Smp#:14
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
75 cis-1,3-Dichloropropene, CAS: 10061-01-5
Signal: 1
Processing Integration Results
RT: 6.40
Area: 8876
Amount: 0.848094
Amount Units: ug/l
6.1 6.3 6.5 6.7
Min
0
6
12
18
24
30
36
42
48
54
60
66
72
78
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 75

6
.
4
0
2
Manual Integration Results
RT: 6.40
Area: 13570
Amount: 0.906993
Amount Units: ug/l
6.1 6.3 6.5 6.7
Min
RT
0
6
12
18
24
30
36
42
48
54
60
66
72
78
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 75

6
.
4
0
2
Reviewer: LP8K, 17-Dec-2024 14:54:19 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 227 of 428
Report Date: 18-Dec-2024 06:16:27 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005224.D
Injection Date:17-Dec-2024 01:20:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:2 Worklist Smp#:14
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
78 trans-1,3-Dichloropropene, CAS: 10061-02-6
Signal: 1
Processing Integration Results
RT: 6.86
Area: 7127
Amount: 0.872252
Amount Units: ug/l
6.5 6.7 6.9 7.1
Min
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 75

6
.
8
6
5
Manual Integration Results
RT: 6.86
Area: 12745
Amount: 1.394682
Amount Units: ug/l
6.5 6.7 6.9 7.1
Min
RT
0
6
12
18
24
30
36
42
48
54
60
66
72
78
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 75

6
.
8
6
5
Reviewer: LP8K, 17-Dec-2024 14:54:24 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 228 of 428
Report Date: 18-Dec-2024 06:16:27 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005224.D
Injection Date:17-Dec-2024 01:20:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:2 Worklist Smp#:14
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
83 1,3-Dichloropropane, CAS: 142-28-9
Signal: 1
Processing Integration Results
RT: 7.19
Area: 9272
Amount: 0.570618
Amount Units: ug/l
6.9 7.1 7.3 7.5
Min
0
1
2
3
4
5
6
7
8
9
10
11
Y ( X10
0
0
)
0000005224[MS Quad Chro]:m/z 76

7
.
1
9
3
Manual Integration Results
RT: 7.20
Area: 17201
Amount: 1.004142
Amount Units: ug/l
6.9 7.1 7.3 7.5
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
Y ( X10
0
0
)
0000005224[MS Quad Chro]:m/z 76

7
.
2
0
3
Reviewer: LP8K, 17-Dec-2024 14:54:29 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 229 of 428
Report Date: 18-Dec-2024 06:16:27 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005224.D
Injection Date:17-Dec-2024 01:20:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:2 Worklist Smp#:14
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
87 1-Chlorohexane, CAS: 544-10-5
Signal: 1
Processing Integration Results
RT: 7.91
Area: 8838
Amount: 0.616798
Amount Units: ug/l
7.6 7.8 8.0 8.2
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
Y ( X10
0
0
)
0000005224[MS Quad Chro]:m/z 91

7
.
9
1
0
Manual Integration Results
RT: 7.91
Area: 14380
Amount: 1.022862
Amount Units: ug/l
7.6 7.8 8.0 8.2
Min
RT
0
2
4
6
8
10
12
14
16
18
20
22
24
26
Y ( X10
0
0
)
0000005224[MS Quad Chro]:m/z 91

7
.
9
1
0
Reviewer: LP8K, 17-Dec-2024 14:54:35 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 230 of 428
Report Date: 18-Dec-2024 06:16:27 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005224.D
Injection Date:17-Dec-2024 01:20:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:2 Worklist Smp#:14
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
94 Bromoform, CAS: 75-25-2
Signal: 1
Processing Integration Results
RT: 8.71
Area: 2107
Amount: 1.419250
Amount Units: ug/l
8.4 8.6 8.8 9.0
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 173

8
.
7
1
4
Manual Integration Results
RT: 8.71
Area: 3947
Amount: 2.213441
Amount Units: ug/l
8.4 8.6 8.8 9.0
Min
RT
0
3
6
9
12
15
18
21
24
27
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 173

8
.
7
1
4
Reviewer: LP8K, 17-Dec-2024 14:54:40 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 231 of 428
Report Date: 18-Dec-2024 06:16:27 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005224.D
Injection Date:17-Dec-2024 01:20:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:2 Worklist Smp#:14
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
99 trans-1,4-Dichloro-2-butene, CAS: 110-57-6
Signal: 1
Processing Integration Results
RT: 9.18
Area: 1152
Amount: 0.259802
Amount Units: ug/l
8.9 9.1 9.3 9.5
Min
0
2
4
6
8
10
12
14
16
18
20
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 53

9
.
1
7
7
Manual Integration Results
RT: 9.18
Area: 1801
Amount: 1.482195
Amount Units: ug/l
8.9 9.1 9.3 9.5
Min
RT
0
2
4
6
8
10
12
14
16
18
20
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 53

9
.
1
8
3
Reviewer: LP8K, 17-Dec-2024 14:54:45 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 232 of 428
Report Date: 18-Dec-2024 06:16:27 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005224.D
Injection Date:17-Dec-2024 01:20:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:2 Worklist Smp#:14
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
116 1,2-Dibromo-3-Chloropropane, CAS: 96-12-8
Signal: 1
Processing Integration Results
RT: 11.34
Area: 1746
Amount: 0.358018
Amount Units: ug/l
11.0 11.2 11.4 11.6
Min
0
2
4
6
8
10
12
14
16
18
20
22
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 157
1
1
.
3
3
8
Manual Integration Results
RT: 11.35
Area: 3530
Amount: 2.073755
Amount Units: ug/l
11.0 11.2 11.4 11.6
Min
RT
0
2
4
6
8
10
12
14
16
18
20
22
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 157
1
1
.
3
4
7
Reviewer: LP8K, 17-Dec-2024 14:54:54 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 233 of 428
Report Date: 18-Dec-2024 06:16:27 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005224.D
Injection Date:17-Dec-2024 01:20:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:2 Worklist Smp#:14
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
121 1,2,3-Trichlorobenzene, CAS: 87-61-6
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 12.68
12.3 12.5 12.7 12.9
Min
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 180
Manual Integration Results
RT: 12.68
Area: 12365
Amount: 0.964141
Amount Units: ug/l
12.3 12.5 12.7 12.9
Min
RT
0
6
12
18
24
30
36
42
48
54
60
66
72
Y ( X10
0
)
0000005224[MS Quad Chro]:m/z 180
1
2
.
6
8
2
Reviewer: LP8K, 17-Dec-2024 14:55:02 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 234 of 428
Report Date: 18-Dec-2024 06:16:32 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005225.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:3
Inject. Date:17-Dec-2024 01:40:09 ALS Bottle#:3 Worklist Smp#:15
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ic
Operator ID:bustillose Instrument ID:VMS_MS14
Sublist:chrom-AQ_VMS14_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:18-Dec-2024 06:16:32 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: LP8K Date:17-Dec-2024 14:55:45
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.357 5.360 -0.003 98 2309819 50.0 50.0
* 2 Chlorobenzene-d5 119 7.926 7.929 -0.003 89 550003 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.170 0.003 97 895835 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.839 4.839 0.000 92 582600 50.0 49.6
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 98 786057 50.0 50.3
$ 6 Toluene-d8 (Surr) 98 6.637 6.636 0.001 94 2395593 50.0 51.0
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 84 900357 50.0 49.1
10 Dichlorodifluoromethane 85 1.791 1.794 -0.003 99 22120 2.00 1.69
12 Chloromethane 50 1.971 1.974 -0.003 99 26720 2.00 1.74
13 Vinyl chloride 62 2.087 2.087 0.000 98 19958 2.00 1.70
15 Bromomethane 94 2.399 2.399 0.000 93 12113 2.00 2.75
16 Chloroethane 64 2.495 2.498 -0.003 98 13185 2.00 1.76
17 Dichlorofluoromethane 67 2.675 2.678 -0.003 97 35439 2.00 1.80
18 Trichlorofluoromethane 101 2.720 2.720 0.000 98 25699 2.00 1.82
21 Ethyl ether 59 2.939 2.939 0.000 92 17064 2.00 1.85
22 Acrolein 56 3.051 3.055 -0.004 99 42210 19.8 15.9
25 1,1-Dichloroethene 96 3.145 3.141 0.004 95 15926 2.00 1.92
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.138 3.141 -0.003 63 11275 2.00 1.94 M
26 Acetone 43 3.161 3.161 0.000 99 185690 8.00 7.31
29 Iodomethane 142 3.270 3.270 0.000 98 8307 2.00 4.46
30 Carbon disulfide 76 3.334 3.337 -0.003 99 45659 2.00 2.09
32 Methyl acetate 43 3.399 3.399 0.000 98 75774 4.00 3.54
33 3-Chloro-1-propene 41 3.418 3.421 -0.003 90 41612 2.00 2.39 M
34 Methylene Chloride 84 3.521 3.521 0.000 93 27840 2.00 2.43
35 2-Methyl-2-propanol 59 3.566 3.566 0.000 100 109669 20.0 15.7
36 Acrylonitrile 53 3.688 3.688 0.000 99 197208 20.0 19.0
37 Methyl tert-butyl ether 73 3.711 3.714 -0.003 93 64436 2.00 1.90
38 trans-1,2-Dichloroethene 96 3.727 3.730 -0.003 98 18451 2.00 2.07
39 Hexane 57 3.929 3.936 -0.007 90 25111 2.00 1.97
40 Vinyl acetate 43 4.032 4.032 0.000 97 100975 4.00 3.93
42 1,1-Dichloroethane 63 4.058 4.058 0.000 96 34245 2.00 2.02
12/27/2024
9:26:49 AM
Page 235 of 428
Report Date: 18-Dec-2024 06:16:32 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005225.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
45 2-Butanone (MEK) 43 4.457 4.450 0.007 100 142037 8.00 7.47
47 cis-1,2-Dichloroethene 96 4.482 4.482 0.000 87 19987 2.00 1.92
48 2,2-Dichloropropane 77 4.495 4.495 0.000 79 26350 2.00 1.91
50 sec-Butyl Alcohol 45 4.569 4.566 0.003 99 194348 48.0 41.2
52 Chlorobromomethane 128 4.662 4.659 0.003 96 10256 2.00 2.15
53 Tetrahydrofuran 42 4.672 4.672 0.000 93 43068 4.00 3.72
54 Chloroform 83 4.717 4.720 -0.003 92 33880 2.00 2.02
55 1,1,1-Trichloroethane 97 4.875 4.871 0.003 97 27101 2.00 1.98
56 Cyclohexane 56 4.936 4.936 0.000 89 32194 2.00 1.97
57 1,1-Dichloropropene 75 4.990 4.987 0.003 88 26747 2.00 1.99
59 Carbon tetrachloride 117 4.990 4.997 -0.007 53 16267 2.00 2.18
58 Isobutyl alcohol 41 5.000 4.997 0.003 93 84110 50.0 47.1
60 Benzene 78 5.145 5.148 -0.003 94 76586 2.00 1.99
61 1,2-Dichloroethane 62 5.170 5.170 0.000 96 30436 2.00 1.98
63 n-Heptane 43 5.331 5.331 0.000 92 24627 2.00 1.94
65 Trichloroethene 95 5.640 5.640 0.000 94 18014 2.00 1.98
66 2-Pentanone 43 5.739 5.739 0.000 99 157868 6.40 5.97
67 Methylcyclohexane 55 5.839 5.842 -0.003 90 25790 2.00 1.98
69 1,2-Dichloropropane 63 5.846 5.849 -0.003 75 19521 2.00 1.93
70 1,4-Dioxane 88 5.923 5.913 0.010 28 10134 40.0 33.3 M
71 Dibromomethane 93 5.920 5.919 0.001 93 13064 2.00 1.89
72 Dichlorobromomethane 83 6.042 6.045 -0.003 90 20193 2.00 1.74
74 2-Chloroethyl vinyl ether 63 6.244 6.247 -0.003 90 4037 2.00 2.39 M
75 cis-1,3-Dichloropropene 75 6.399 6.402 -0.003 95 28167 2.00 1.84
76 4-Methyl-2-pentanone (MIBK) 43 6.501 6.501 0.000 97 188706 8.00 7.41
77 Toluene 91 6.698 6.694 0.004 98 81393 2.00 1.94
78 trans-1,3-Dichloropropene 75 6.865 6.868 -0.003 93 24377 2.00 2.04
79 Ethyl methacrylate 69 6.884 6.887 -0.003 89 32871 2.00 1.85
80 1,1,2-Trichloroethane 97 7.045 7.048 -0.003 93 18729 2.00 1.89 Ma
82 Tetrachloroethene 164 7.145 7.151 -0.006 91 14417 2.00 2.06
83 1,3-Dichloropropane 76 7.196 7.196 0.000 92 32540 2.00 1.86
84 2-Hexanone 43 7.215 7.212 0.003 96 161491 8.00 7.64
85 Chlorodibromomethane 129 7.392 7.395 -0.003 90 13396 2.00 2.10
86 Ethylene Dibromide 107 7.514 7.514 0.000 97 19373 2.00 1.84
87 1-Chlorohexane 91 7.907 7.906 0.001 96 23072 1.60 1.65
88 Chlorobenzene 112 7.952 7.955 -0.003 96 51181 2.00 1.96
89 1,1,1,2-Tetrachloroethane 131 8.022 8.029 -0.007 82 13810 2.00 1.76
90 Ethylbenzene 106 8.032 8.032 0.000 99 24565 2.00 1.80
91 m-Xylene & p-Xylene 106 8.148 8.148 0.000 99 33037 2.00 1.92
92 o-Xylene 106 8.514 8.511 0.003 97 30048 2.00 1.78
93 Styrene 104 8.527 8.527 0.000 95 51378 2.00 1.84
94 Bromoform 173 8.710 8.710 0.000 75 8497 2.00 2.81
95 Isopropylbenzene 105 8.855 8.855 0.000 97 73732 2.00 1.82
97 Cyclohexanone 55 8.961 8.961 0.000 92 98671 60.0 52.9
98 1,1,2,2-Tetrachloroethane 83 9.141 9.141 0.000 95 31088 2.00 1.78
99 trans-1,4-Dichloro-2-butene 53 9.177 9.177 0.000 46 6272 2.00 2.17
100 Bromobenzene 156 9.180 9.186 -0.006 97 20855 2.00 1.96
101 1,2,3-Trichloropropane 110 9.206 9.209 -0.003 84 10817 2.00 1.72
102 N-Propylbenzene 120 9.254 9.260 -0.006 99 21346 2.00 1.85
103 2-Chlorotoluene 126 9.357 9.360 -0.003 95 19108 2.00 1.88
104 1,3,5-Trimethylbenzene 105 9.431 9.431 0.000 94 70100 2.00 1.96
105 4-Chlorotoluene 126 9.476 9.479 -0.003 98 20113 2.00 1.90
12/27/2024
9:26:49 AM
Page 236 of 428
Report Date: 18-Dec-2024 06:16:32 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005225.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
107 tert-Butylbenzene 119 9.746 9.749 -0.003 93 61234 2.00 1.92
108 1,2,4-Trimethylbenzene 105 9.804 9.800 0.004 98 70279 2.00 1.90
109 sec-Butylbenzene 134 9.971 9.964 0.007 95 17281 2.00 1.89
110 1,3-Dichlorobenzene 146 10.103 10.096 0.007 96 39767 2.00 1.92
111 4-Isopropyltoluene 119 10.112 10.112 0.000 96 73136 2.00 1.89
112 1,4-Dichlorobenzene 146 10.196 10.199 -0.003 96 40584 2.00 1.93
114 n-Butylbenzene 91 10.524 10.524 0.000 98 68584 2.00 1.85
115 1,2-Dichlorobenzene 146 10.562 10.559 0.003 96 37697 2.00 1.89
116 1,2-Dibromo-3-Chloropropane 157 11.347 11.344 0.003 76 8086 2.00 2.73 M
118 1,2,4-Trichlorobenzene 180 12.180 12.180 0.000 96 21988 2.00 1.72
119 Hexachlorobutadiene 225 12.328 12.324 0.004 94 9763 2.00 1.81
120 Naphthalene 128 12.453 12.456 -0.003 97 82070 2.00 2.00
121 1,2,3-Trichlorobenzene 180 12.678 12.681 -0.003 94 22816 2.00 1.77
136 Butadiene 54 0.000 ND ND
S 156 Total BTEX 1 0 9.43
S 155 Xylenes, Total 106 0 4.00 3.70
S 152 Trihalomethanes, Total 1 0 8.00 8.66
S 154 1,3-Dichloropropene, Total 1 0 4.00 3.88
S 151 1,2-Dichloroethene, Total 1 0 4.00 3.99
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Review Flags
M - Manually Integrated
a - User Assigned ID
Reagents:
Cal Dil Std_00438 Amount Added: 20.00 Units: uL
mv-IS_SS_00093 Amount Added: 5.00 Units: uL Run Reagent
12/27/2024
9:26:49 AM
Page 237 of 428
Report Date: 18-Dec-2024 06:16:32 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005225.D
Injection Date:17-Dec-2024 01:40:09 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:ic Worklist Smp#:15
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:3
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
32
34
36
38
Y ( X10
0
0
0
0
)
0000005225[MS Quad Chro]:Total

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12/27/2024
9:26:49 AM
Page 238 of 428
Report Date: 18-Dec-2024 06:16:32 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005225.D
Injection Date:17-Dec-2024 01:40:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:3 Worklist Smp#:15
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
24 1,1,2-Trichloro-1,2,2-trifluoroe, CAS: 76-13-1
Signal: 1
Processing Integration Results
RT: 3.14
Area: 6507
Amount: 1.284732
Amount Units: ug/l
2.8 3.0 3.2 3.4
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
52
56
Y ( X10
0
)
0000005225[MS Quad Chro]:m/z 151

3
.
1
3
8
Manual Integration Results
RT: 3.14
Area: 11275
Amount: 1.937110
Amount Units: ug/l
2.8 3.0 3.2 3.4
Min
RT
0
5
10
15
20
25
30
35
40
45
50
55
Y ( X10
0
)
0000005225[MS Quad Chro]:m/z 151

3
.
1
3
8
Reviewer: LP8K, 17-Dec-2024 14:55:26 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 239 of 428
Report Date: 18-Dec-2024 06:16:32 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005225.D
Injection Date:17-Dec-2024 01:40:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:3 Worklist Smp#:15
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
33 3-Chloro-1-propene, CAS: 107-05-1
Signal: 1
Processing Integration Results
RT: 3.42
Area: 34849
Amount: 1.371541
Amount Units: ug/l
3.1 3.3 3.5 3.7
Min
0
2
4
6
8
10
12
14
16
18
20
22
Y ( X10
0
0
)
0000005225[MS Quad Chro]:m/z 41

3
.
4
1
8
Manual Integration Results
RT: 3.42
Area: 41612
Amount: 2.393890
Amount Units: ug/l
3.1 3.3 3.5 3.7
Min
RT
0
2
4
6
8
10
12
14
16
18
20
22
Y ( X10
0
0
)
0000005225[MS Quad Chro]:m/z 41

3
.
4
1
8
Reviewer: LP8K, 17-Dec-2024 14:56:22 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Incomplete Integration
12/27/2024
9:26:49 AM
Page 240 of 428
Report Date: 18-Dec-2024 06:16:32 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005225.D
Injection Date:17-Dec-2024 01:40:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:3 Worklist Smp#:15
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
70 1,4-Dioxane, CAS: 123-91-1
Signal: 1
Processing Integration Results
RT: 5.90
Area: 2920
Amount: 10.119908
Amount Units: ug/l
5.6 5.8 6.0 6.2
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
26
28
30
Y ( X10
0
)
0000005225[MS Quad Chro]:m/z 88

5
.
9
0
3
Manual Integration Results
RT: 5.92
Area: 10134
Amount: 33.270434
Amount Units: ug/l
5.6 5.8 6.0 6.2
Min
RT
0
3
6
9
12
15
18
21
24
27
30
Y ( X10
0
)
0000005225[MS Quad Chro]:m/z 88

5
.
9
2
3
Reviewer: LP8K, 17-Dec-2024 14:56:38 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Incomplete Integration
12/27/2024
9:26:49 AM
Page 241 of 428
Report Date: 18-Dec-2024 06:16:32 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005225.D
Injection Date:17-Dec-2024 01:40:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:3 Worklist Smp#:15
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
74 2-Chloroethyl vinyl ether, CAS: 110-75-8
Signal: 1
Processing Integration Results
RT: 6.24
Area: 2290
Amount: 1.965669
Amount Units: ug/l
5.9 6.1 6.3 6.5
Min
0
2
4
6
8
10
12
14
16
18
20
22
24
Y ( X10
0
)
0000005225[MS Quad Chro]:m/z 63

6
.
2
4
4
Manual Integration Results
RT: 6.24
Area: 4037
Amount: 2.386778
Amount Units: ug/l
5.9 6.1 6.3 6.5
Min
RT
0
2
4
6
8
10
12
14
16
18
20
22
24
Y ( X10
0
)
0000005225[MS Quad Chro]:m/z 63

6
.
2
4
4
Reviewer: LP8K, 17-Dec-2024 14:56:59 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Incomplete Integration
12/27/2024
9:26:49 AM
Page 242 of 428
Report Date: 18-Dec-2024 06:16:32 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005225.D
Injection Date:17-Dec-2024 01:40:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:3 Worklist Smp#:15
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
80 1,1,2-Trichloroethane, CAS: 79-00-5
Signal: 1
Processing Integration Results
Not Detected
Expected RT: 7.05
6.7 6.9 7.1 7.3
Min
0
1
2
3
4
5
6
7
8
9
10
11
Y ( X10
0
0
)
0000005225[MS Quad Chro]:m/z 97
Manual Integration Results
RT: 7.04
Area: 18729
Amount: 1.894431
Amount Units: ug/l
6.7 6.9 7.1 7.3
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
Y ( X10
0
0
)
0000005225[MS Quad Chro]:m/z 97

7
.
0
4
5
Reviewer: LP8K, 17-Dec-2024 14:57:10 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Assign Peak
12/27/2024
9:26:49 AM
Page 243 of 428
Report Date: 18-Dec-2024 06:16:32 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005225.D
Injection Date:17-Dec-2024 01:40:09 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:3 Worklist Smp#:15
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
116 1,2-Dibromo-3-Chloropropane, CAS: 96-12-8
Signal: 1
Processing Integration Results
RT: 11.35
Area: 5967
Amount: 1.458230
Amount Units: ug/l
11.0 11.2 11.4 11.6
Min
0
4
8
12
16
20
24
28
32
36
40
44
48
52
56
Y ( X10
0
)
0000005225[MS Quad Chro]:m/z 157
1
1
.
3
4
7
Manual Integration Results
RT: 11.35
Area: 8086
Amount: 2.733616
Amount Units: ug/l
11.0 11.2 11.4 11.6
Min
RT
0
5
10
15
20
25
30
35
40
45
50
55
Y ( X10
0
)
0000005225[MS Quad Chro]:m/z 157
1
1
.
3
4
7
Reviewer: LP8K, 17-Dec-2024 14:57:26 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 244 of 428
Report Date: 18-Dec-2024 06:16:37 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005226.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:4
Inject. Date:17-Dec-2024 02:00:08 ALS Bottle#:4 Worklist Smp#:16
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ic
Operator ID:bustillose Instrument ID:VMS_MS14
Sublist:chrom-AQ_VMS14_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:18-Dec-2024 06:16:36 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: LP8K Date:17-Dec-2024 14:59:03
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.357 5.360 -0.003 98 2301721 50.0 50.0
* 2 Chlorobenzene-d5 119 7.926 7.929 -0.003 88 544277 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.174 10.170 0.004 97 876998 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.839 4.839 0.000 92 574305 50.0 49.1
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 98 778359 50.0 50.0
$ 6 Toluene-d8 (Surr) 98 6.637 6.636 0.001 94 2397535 50.0 51.6
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 84 893477 50.0 49.8
10 Dichlorodifluoromethane 85 1.794 1.794 0.000 98 58705 5.00 4.51
12 Chloromethane 50 1.971 1.974 -0.003 99 64777 5.00 4.24
13 Vinyl chloride 62 2.090 2.087 0.003 97 52971 5.00 4.52
15 Bromomethane 94 2.396 2.399 -0.003 90 26576 5.00 4.47
16 Chloroethane 64 2.492 2.498 -0.006 99 31299 5.00 4.20
17 Dichlorofluoromethane 67 2.679 2.678 0.001 97 89173 5.00 4.54
18 Trichlorofluoromethane 101 2.714 2.720 -0.006 98 62351 5.00 4.43
21 Ethyl ether 59 2.939 2.939 0.000 93 42381 5.00 4.60
22 Acrolein 56 3.052 3.055 -0.003 100 113865 49.4 43.0
25 1,1-Dichloroethene 96 3.142 3.141 0.001 96 37596 5.00 4.55
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.142 3.141 0.001 67 27305 5.00 4.71
26 Acetone 43 3.161 3.161 0.000 99 311465 20.0 18.4
29 Iodomethane 142 3.267 3.270 -0.003 97 22503 5.00 5.96 M
30 Carbon disulfide 76 3.338 3.337 0.001 100 108938 5.00 4.26
32 Methyl acetate 43 3.399 3.399 0.000 98 193365 10.0 9.06
33 3-Chloro-1-propene 41 3.418 3.421 -0.003 89 81285 5.00 4.96 M
34 Methylene Chloride 84 3.521 3.521 0.000 93 56837 5.00 4.98
35 2-Methyl-2-propanol 59 3.569 3.566 0.003 99 319232 50.0 45.9
36 Acrylonitrile 53 3.688 3.688 0.000 99 482853 50.0 46.6
37 Methyl tert-butyl ether 73 3.711 3.714 -0.003 94 160384 5.00 4.75
38 trans-1,2-Dichloroethene 96 3.727 3.730 -0.003 96 41738 5.00 4.71
39 Hexane 57 3.933 3.936 -0.004 93 60607 5.00 4.81
40 Vinyl acetate 43 4.032 4.032 0.000 97 239377 10.0 9.34
42 1,1-Dichloroethane 63 4.058 4.058 0.000 96 81033 5.00 4.79
12/27/2024
9:26:49 AM
Page 245 of 428
Report Date: 18-Dec-2024 06:16:37 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005226.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
45 2-Butanone (MEK) 43 4.453 4.450 0.003 100 342387 20.0 18.1
47 cis-1,2-Dichloroethene 96 4.482 4.482 0.000 83 51492 5.00 4.96
48 2,2-Dichloropropane 77 4.492 4.495 -0.003 88 65087 5.00 4.74
50 sec-Butyl Alcohol 45 4.566 4.566 0.000 99 541144 120.0 115.2
52 Chlorobromomethane 128 4.662 4.659 0.003 97 22724 5.00 4.77
53 Tetrahydrofuran 42 4.672 4.672 0.000 87 108306 10.0 9.40
54 Chloroform 83 4.717 4.720 -0.003 93 79736 5.00 4.76
55 1,1,1-Trichloroethane 97 4.868 4.871 -0.003 97 62645 5.00 4.59
56 Cyclohexane 56 4.939 4.936 0.003 90 76899 5.00 4.71
57 1,1-Dichloropropene 75 4.984 4.987 -0.003 95 64149 5.00 4.78
59 Carbon tetrachloride 117 4.990 4.997 -0.007 64 40291 5.00 4.33
58 Isobutyl alcohol 41 5.000 4.997 0.003 94 219304 125.0 123.2
60 Benzene 78 5.145 5.148 -0.003 96 180934 5.00 4.72
61 1,2-Dichloroethane 62 5.167 5.170 -0.003 97 69373 5.00 4.52
63 n-Heptane 43 5.331 5.331 0.000 92 60715 5.00 4.81
65 Trichloroethene 95 5.640 5.640 0.000 96 44725 5.00 4.96
66 2-Pentanone 43 5.740 5.739 0.001 99 394548 16.0 15.0
67 Methylcyclohexane 55 5.846 5.842 0.004 87 60243 5.00 4.64
69 1,2-Dichloropropane 63 5.849 5.849 0.000 77 46102 5.00 4.58
70 1,4-Dioxane 88 5.913 5.913 0.000 80 31440 100.0 103.6
71 Dibromomethane 93 5.923 5.919 0.004 94 30845 5.00 4.48
72 Dichlorobromomethane 83 6.042 6.045 -0.003 98 48615 5.00 4.20
74 2-Chloroethyl vinyl ether 63 6.248 6.247 0.001 92 8187 5.00 4.86
75 cis-1,3-Dichloropropene 75 6.399 6.402 -0.003 94 68258 5.00 4.51
76 4-Methyl-2-pentanone (MIBK) 43 6.502 6.501 0.001 97 467022 20.0 18.4
77 Toluene 91 6.691 6.694 -0.003 99 195872 5.00 4.69
78 trans-1,3-Dichloropropene 75 6.868 6.868 0.000 94 62431 5.00 4.24
79 Ethyl methacrylate 69 6.881 6.887 -0.006 90 80501 5.00 4.57
80 1,1,2-Trichloroethane 97 7.045 7.048 -0.003 91 45605 5.00 4.63
82 Tetrachloroethene 164 7.148 7.151 -0.003 94 32131 5.00 4.64
83 1,3-Dichloropropane 76 7.196 7.196 0.000 95 80644 5.00 4.65
84 2-Hexanone 43 7.212 7.212 0.000 95 399312 20.0 19.1
85 Chlorodibromomethane 129 7.392 7.395 -0.003 91 32411 5.00 4.13
86 Ethylene Dibromide 107 7.514 7.514 0.000 98 46598 5.00 4.48
87 1-Chlorohexane 91 7.907 7.906 0.001 97 49797 4.00 3.70
88 Chlorobenzene 112 7.955 7.955 0.000 94 120922 5.00 4.67
89 1,1,1,2-Tetrachloroethane 131 8.022 8.029 -0.007 91 34555 5.00 4.45
90 Ethylbenzene 106 8.029 8.032 -0.003 99 65379 5.00 4.83
91 m-Xylene & p-Xylene 106 8.145 8.148 -0.003 99 81258 5.00 4.77
92 o-Xylene 106 8.514 8.511 0.003 97 79812 5.00 4.79
93 Styrene 104 8.527 8.527 0.000 95 129699 5.00 4.69
94 Bromoform 173 8.711 8.710 0.001 92 21843 5.00 4.61
95 Isopropylbenzene 105 8.858 8.855 0.003 96 189992 5.00 4.80
97 Cyclohexanone 55 8.961 8.961 0.000 93 269155 150.0 145.8
98 1,1,2,2-Tetrachloroethane 83 9.141 9.141 0.000 96 78955 5.00 4.61
99 trans-1,4-Dichloro-2-butene 53 9.177 9.177 0.000 60 17544 5.00 3.96
100 Bromobenzene 156 9.186 9.186 0.000 97 48946 5.00 4.70
101 1,2,3-Trichloropropane 110 9.209 9.209 0.000 88 29438 5.00 4.78
102 N-Propylbenzene 120 9.260 9.260 0.000 99 54094 5.00 4.78
103 2-Chlorotoluene 126 9.360 9.360 0.000 96 48426 5.00 4.86
104 1,3,5-Trimethylbenzene 105 9.431 9.431 0.000 95 169622 5.00 4.84
105 4-Chlorotoluene 126 9.479 9.479 0.000 98 51051 5.00 4.91
12/27/2024
9:26:49 AM
Page 246 of 428
Report Date: 18-Dec-2024 06:16:37 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005226.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
107 tert-Butylbenzene 119 9.749 9.749 0.000 93 151597 5.00 4.86
108 1,2,4-Trimethylbenzene 105 9.804 9.800 0.004 98 176431 5.00 4.88
109 sec-Butylbenzene 134 9.968 9.964 0.004 95 43666 5.00 4.89
110 1,3-Dichlorobenzene 146 10.096 10.096 0.000 97 95983 5.00 4.72
111 4-Isopropyltoluene 119 10.112 10.112 0.000 97 182789 5.00 4.81
112 1,4-Dichlorobenzene 146 10.196 10.199 -0.003 94 96438 5.00 4.69
114 n-Butylbenzene 91 10.524 10.524 0.000 98 171912 5.00 4.72
115 1,2-Dichlorobenzene 146 10.563 10.559 0.004 96 92658 5.00 4.75
116 1,2-Dibromo-3-Chloropropane 157 11.344 11.344 0.000 76 20954 5.00 4.67
118 1,2,4-Trichlorobenzene 180 12.180 12.180 0.000 93 56774 5.00 4.54
119 Hexachlorobutadiene 225 12.325 12.324 0.001 87 24959 5.00 4.72
120 Naphthalene 128 12.453 12.456 -0.003 98 208224 5.00 4.30
121 1,2,3-Trichlorobenzene 180 12.681 12.681 0.000 94 54293 5.00 4.30
136 Butadiene 54 0.000 ND ND
S 156 Total BTEX 1 0 23.8
S 155 Xylenes, Total 106 0 10.0 9.56
S 152 Trihalomethanes, Total 1 0 20.0 17.7
S 154 1,3-Dichloropropene, Total 1 0 10.0 8.75
S 151 1,2-Dichloroethene, Total 1 0 10.0 9.66
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Review Flags
M - Manually Integrated
Reagents:
Cal Dil Std_00438 Amount Added: 50.00 Units: uL
mv-IS_SS_00093 Amount Added: 5.00 Units: uL Run Reagent
12/27/2024
9:26:49 AM
Page 247 of 428
Report Date: 18-Dec-2024 06:16:37 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005226.D
Injection Date:17-Dec-2024 02:00:08 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:ic Worklist Smp#:16
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:4
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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12/27/2024
9:26:49 AM
Page 248 of 428
Report Date: 18-Dec-2024 06:16:37 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005226.D
Injection Date:17-Dec-2024 02:00:08 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:4 Worklist Smp#:16
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
29 Iodomethane, CAS: 74-88-4
Signal: 1
Processing Integration Results
RT: 3.27
Area: 12669
Amount: 4.083222
Amount Units: ug/l
2.9 3.1 3.3 3.5
Min
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3
4
5
6
7
8
9
10
11
12
13
14
Y ( X10
0
0
)
0000005226[MS Quad Chro]:m/z 142

3
.
2
6
7
Manual Integration Results
RT: 3.27
Area: 22503
Amount: 5.955846
Amount Units: ug/l
2.9 3.1 3.3 3.5
Min
RT
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
Y ( X10
0
0
)
0000005226[MS Quad Chro]:m/z 142

3
.
2
6
7
Reviewer: LP8K, 17-Dec-2024 14:58:15 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Split Peak
12/27/2024
9:26:49 AM
Page 249 of 428
Report Date: 18-Dec-2024 06:16:37 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005226.D
Injection Date:17-Dec-2024 02:00:08 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:4 Worklist Smp#:16
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
33 3-Chloro-1-propene, CAS: 107-05-1
Signal: 1
Processing Integration Results
RT: 3.42
Area: 68215
Amount: 2.654903
Amount Units: ug/l
3.1 3.3 3.5 3.7
Min
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
Y ( X10
0
0
)
0000005226[MS Quad Chro]:m/z 41

3
.
4
1
8
Manual Integration Results
RT: 3.42
Area: 81285
Amount: 4.958380
Amount Units: ug/l
3.1 3.3 3.5 3.7
Min
RT
0
3
6
9
12
15
18
21
24
27
30
33
36
39
42
Y ( X10
0
0
)
0000005226[MS Quad Chro]:m/z 41

3
.
4
1
8
Reviewer: LP8K, 17-Dec-2024 14:58:37 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Incomplete Integration
12/27/2024
9:26:49 AM
Page 250 of 428
Report Date: 18-Dec-2024 06:16:42 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005227.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:5
Inject. Date:17-Dec-2024 02:20:30 ALS Bottle#:5 Worklist Smp#:17
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ic
Misc. Info.:10
Operator ID:bustillose Instrument ID:VMS_MS14
Sublist:chrom-AQ_VMS14_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:18-Dec-2024 06:16:41 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: LP8K Date:17-Dec-2024 14:59:55
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 98 2157605 50.0 50.0
* 2 Chlorobenzene-d5 119 7.929 7.929 0.000 88 510664 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.170 10.170 0.000 97 854263 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.839 4.839 0.000 93 548543 50.0 50.0
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 99 732114 50.0 50.2
$ 6 Toluene-d8 (Surr) 98 6.636 6.636 0.000 94 2239193 50.0 51.4
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 84 845784 50.0 48.4
10 Dichlorodifluoromethane 85 1.794 1.794 0.000 99 112429 10.0 9.21
12 Chloromethane 50 1.974 1.974 0.000 99 118417 10.0 8.27
13 Vinyl chloride 62 2.087 2.087 0.000 98 94009 10.0 8.56
15 Bromomethane 94 2.399 2.399 0.000 92 54084 10.0 8.17
16 Chloroethane 64 2.498 2.498 0.000 99 62371 10.0 8.93
17 Dichlorofluoromethane 67 2.678 2.678 0.000 97 169597 10.0 9.21
18 Trichlorofluoromethane 101 2.720 2.720 0.000 98 115318 10.0 8.75
21 Ethyl ether 59 2.939 2.939 0.000 90 74874 10.0 8.67
22 Acrolein 56 3.055 3.055 0.000 99 222245 98.8 89.6
25 1,1-Dichloroethene 96 3.141 3.141 0.000 97 62147 10.0 8.02
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.141 3.141 0.000 65 42666 10.0 7.85
26 Acetone 43 3.161 3.161 0.000 99 511350 40.0 39.1
29 Iodomethane 142 3.270 3.270 0.000 99 42624 10.0 8.38
30 Carbon disulfide 76 3.337 3.337 0.000 99 182854 10.0 7.22
32 Methyl acetate 43 3.399 3.399 0.000 98 359941 20.0 18.0
33 3-Chloro-1-propene 41 3.421 3.421 0.000 90 119689 10.0 7.95
34 Methylene Chloride 84 3.521 3.521 0.000 92 93482 10.0 8.74
35 2-Methyl-2-propanol 59 3.566 3.566 0.000 100 623253 100.0 95.6
36 Acrylonitrile 53 3.688 3.688 0.000 99 928772 100.0 95.7
37 Methyl tert-butyl ether 73 3.714 3.714 0.000 94 294217 10.0 9.30
38 trans-1,2-Dichloroethene 96 3.730 3.730 0.000 96 69509 10.0 8.36
39 Hexane 57 3.936 3.936 0.000 93 93808 10.0 7.93
40 Vinyl acetate 43 4.032 4.032 0.000 97 438810 20.0 18.3
12/27/2024
9:26:49 AM
Page 251 of 428
Report Date: 18-Dec-2024 06:16:42 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005227.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
42 1,1-Dichloroethane 63 4.058 4.058 0.000 96 135731 10.0 8.56
45 2-Butanone (MEK) 43 4.450 4.450 0.000 100 657087 40.0 37.0
47 cis-1,2-Dichloroethene 96 4.482 4.482 0.000 82 83322 10.0 8.56
48 2,2-Dichloropropane 77 4.495 4.495 0.000 87 107248 10.0 8.33
50 sec-Butyl Alcohol 45 4.566 4.566 0.000 98 1025844 240.0 233.0
52 Chlorobromomethane 128 4.659 4.659 0.000 97 40113 10.0 8.99
53 Tetrahydrofuran 42 4.672 4.672 0.000 86 198579 20.0 18.4
54 Chloroform 83 4.720 4.720 0.000 93 134908 10.0 8.59
55 1,1,1-Trichloroethane 97 4.871 4.871 0.000 99 103224 10.0 8.06
56 Cyclohexane 56 4.936 4.936 0.000 89 120685 10.0 7.89
57 1,1-Dichloropropene 75 4.987 4.987 0.000 95 100796 10.0 8.01
59 Carbon tetrachloride 117 4.997 4.997 0.000 40 68146 10.0 7.22 M
58 Isobutyl alcohol 41 4.997 4.997 0.000 94 413984 250.0 248.1
60 Benzene 78 5.148 5.148 0.000 94 301812 10.0 8.39
61 1,2-Dichloroethane 62 5.170 5.170 0.000 97 124533 10.0 8.66
63 n-Heptane 43 5.331 5.331 0.000 89 95364 10.0 8.06
65 Trichloroethene 95 5.640 5.640 0.000 97 72960 10.0 8.63
66 2-Pentanone 43 5.739 5.739 0.000 99 747205 32.0 30.3
67 Methylcyclohexane 55 5.842 5.842 0.000 91 94579 10.0 7.78
69 1,2-Dichloropropane 63 5.849 5.849 0.000 93 80898 10.0 8.58
70 1,4-Dioxane 88 5.913 5.913 0.000 89 57839 200.0 203.3
71 Dibromomethane 93 5.919 5.919 0.000 93 56425 10.0 8.74
72 Dichlorobromomethane 83 6.045 6.045 0.000 99 90742 10.0 8.36
74 2-Chloroethyl vinyl ether 63 6.247 6.247 0.000 92 12449 10.0 7.88
75 cis-1,3-Dichloropropene 75 6.402 6.402 0.000 93 125025 10.0 8.80
76 4-Methyl-2-pentanone (MIBK) 43 6.501 6.501 0.000 96 897523 40.0 37.7
77 Toluene 91 6.694 6.694 0.000 98 322839 10.0 8.24
78 trans-1,3-Dichloropropene 75 6.868 6.868 0.000 96 115090 10.0 7.73
79 Ethyl methacrylate 69 6.887 6.887 0.000 89 155488 10.0 9.41
80 1,1,2-Trichloroethane 97 7.048 7.048 0.000 92 79280 10.0 8.58
82 Tetrachloroethene 164 7.151 7.151 0.000 91 52119 10.0 8.03
83 1,3-Dichloropropane 76 7.196 7.196 0.000 91 151954 10.0 9.34
84 2-Hexanone 43 7.212 7.212 0.000 95 783373 40.0 39.9
85 Chlorodibromomethane 129 7.395 7.395 0.000 89 64474 10.0 7.98
86 Ethylene Dibromide 107 7.514 7.514 0.000 99 87507 10.0 8.97
87 1-Chlorohexane 91 7.906 7.906 0.000 97 76826 8.00 6.14
88 Chlorobenzene 112 7.955 7.955 0.000 94 206909 10.0 8.52
89 1,1,1,2-Tetrachloroethane 131 8.029 8.029 0.000 92 61699 10.0 8.47 M
90 Ethylbenzene 106 8.032 8.032 0.000 99 106648 10.0 8.40
91 m-Xylene & p-Xylene 106 8.148 8.148 0.000 99 133576 10.0 8.35
92 o-Xylene 106 8.511 8.511 0.000 98 135484 10.0 8.66
93 Styrene 104 8.527 8.527 0.000 94 224686 10.0 8.66
94 Bromoform 173 8.710 8.710 0.000 93 42920 10.0 7.82
95 Isopropylbenzene 105 8.855 8.855 0.000 96 307682 10.0 7.98
97 Cyclohexanone 55 8.961 8.961 0.000 93 523013 300.0 302.1
98 1,1,2,2-Tetrachloroethane 83 9.141 9.141 0.000 95 145818 10.0 8.74
99 trans-1,4-Dichloro-2-butene 53 9.177 9.177 0.000 71 36122 10.0 7.04
100 Bromobenzene 156 9.186 9.186 0.000 98 84950 10.0 8.37
101 1,2,3-Trichloropropane 110 9.209 9.209 0.000 85 53831 10.0 8.97
102 N-Propylbenzene 120 9.260 9.260 0.000 99 86193 10.0 7.82
103 2-Chlorotoluene 126 9.360 9.360 0.000 95 78607 10.0 8.09
104 1,3,5-Trimethylbenzene 105 9.431 9.431 0.000 95 287174 10.0 8.41
12/27/2024
9:26:49 AM
Page 252 of 428
Report Date: 18-Dec-2024 06:16:42 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005227.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
105 4-Chlorotoluene 126 9.479 9.479 0.000 98 85470 10.0 8.45
107 tert-Butylbenzene 119 9.749 9.749 0.000 93 245996 10.0 8.09
108 1,2,4-Trimethylbenzene 105 9.800 9.800 0.000 98 302870 10.0 8.61
109 sec-Butylbenzene 134 9.964 9.964 0.000 95 71255 10.0 8.19
110 1,3-Dichlorobenzene 146 10.096 10.096 0.000 97 165011 10.0 8.34
111 4-Isopropyltoluene 119 10.112 10.112 0.000 97 312505 10.0 8.45
112 1,4-Dichlorobenzene 146 10.199 10.199 0.000 93 163762 10.0 8.18
114 n-Butylbenzene 91 10.524 10.524 0.000 98 290178 10.0 8.19
115 1,2-Dichlorobenzene 146 10.559 10.559 0.000 95 161672 10.0 8.52
116 1,2-Dibromo-3-Chloropropane 157 11.344 11.344 0.000 77 40820 10.0 7.78
118 1,2,4-Trichlorobenzene 180 12.180 12.180 0.000 93 102690 10.0 8.44
119 Hexachlorobutadiene 225 12.324 12.324 0.000 95 42891 10.0 8.33
120 Naphthalene 128 12.456 12.456 0.000 97 406650 10.0 8.06
121 1,2,3-Trichlorobenzene 180 12.681 12.681 0.000 95 102726 10.0 8.36
136 Butadiene 54 0.000 ND ND
S 156 Total BTEX 1 0 42.1
S 155 Xylenes, Total 106 0 20.0 17.0
S 152 Trihalomethanes, Total 1 0 40.0 32.8
S 154 1,3-Dichloropropene, Total 1 0 20.0 16.5
S 151 1,2-Dichloroethene, Total 1 0 20.0 16.9
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Review Flags
M - Manually Integrated
Reagents:
MV-MegaMainA_00121 Amount Added: 5.00 Units: uL
MV-Gas A_00206 Amount Added: 2.00 Units: uL
mv-IS_SS_00093 Amount Added: 5.00 Units: uL Run Reagent
12/27/2024
9:26:49 AM
Page 253 of 428
Report Date: 18-Dec-2024 06:16:42 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005227.D
Injection Date:17-Dec-2024 02:20:30 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:ic Worklist Smp#:17
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:5
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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12/27/2024
9:26:49 AM
Page 254 of 428
Report Date: 18-Dec-2024 06:16:42 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005227.D
Injection Date:17-Dec-2024 02:20:30 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:5 Worklist Smp#:17
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
59 Carbon tetrachloride, CAS: 56-23-5
Signal: 1
Processing Integration Results
RT: 4.99
Area: 34472
Amount: 4.151144
Amount Units: ug/l
4.7 4.9 5.1 5.3
Min
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0000005227[MS Quad Chro]:m/z 117

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Manual Integration Results
RT: 5.00
Area: 68146
Amount: 7.223154
Amount Units: ug/l
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Reviewer: LP8K, 17-Dec-2024 14:59:26 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Incomplete Integration
12/27/2024
9:26:49 AM
Page 255 of 428
Report Date: 18-Dec-2024 06:16:42 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Manual Integration/User Assign Peak Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005227.D
Injection Date:17-Dec-2024 02:20:30 Instrument ID:VMS_MS14
Lims ID:ic
Client ID:
Operator ID:bustillose ALS Bottle#:5 Worklist Smp#:17
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
89 1,1,1,2-Tetrachloroethane, CAS: 630-20-6
Signal: 1
Processing Integration Results
RT: 8.02
Area: 35279
Amount: 4.649603
Amount Units: ug/l
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Manual Integration Results
RT: 8.03
Area: 61699
Amount: 8.465877
Amount Units: ug/l
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Reviewer: LP8K, 17-Dec-2024 14:59:44 -07:00:00 (UTC)
Audit Action: Manually Integrated Audit Reason: Incomplete Integration
12/27/2024
9:26:49 AM
Page 256 of 428
Report Date: 18-Dec-2024 06:16:46 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005228.D
Lims ID:icis
Client ID:
Sample Type:ICIS Calib Level:6
Inject. Date:17-Dec-2024 02:40:52 ALS Bottle#:6 Worklist Smp#:18
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:icis
Misc. Info.:50
Operator ID:bustillose Instrument ID:VMS_MS14
Sublist:chrom-AQ_VMS14_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:18-Dec-2024 06:16:46 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: LP8K Date:17-Dec-2024 15:00:24
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 99 1872030 50.0 50.0
* 2 Chlorobenzene-d5 119 7.926 7.926 0.000 88 468888 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.173 0.000 96 763501 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.842 4.842 0.000 92 481603 50.0 50.6
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 98 621403 50.0 49.1
$ 6 Toluene-d8 (Surr) 98 6.636 6.636 0.000 94 1982786 50.0 49.5
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 84 774660 50.0 49.6
10 Dichlorodifluoromethane 85 1.794 1.794 0.000 99 593405 50.0 56.0
12 Chloromethane 50 1.974 1.974 0.000 99 610672 50.0 49.2
13 Vinyl chloride 62 2.087 2.087 0.000 98 485497 50.0 51.0
15 Bromomethane 94 2.399 2.399 0.000 91 286595 50.0 43.1
16 Chloroethane 64 2.498 2.498 0.000 100 306968 50.0 50.6
17 Dichlorofluoromethane 67 2.678 2.678 0.000 97 825528 50.0 51.7
18 Trichlorofluoromethane 101 2.717 2.717 0.000 99 570167 50.0 49.8
21 Ethyl ether 59 2.939 2.939 0.000 91 382366 50.0 51.0
22 Acrolein 56 3.055 3.055 0.000 99 1161162 493.8 539.5
25 1,1-Dichloroethene 96 3.141 3.141 0.000 96 339421 50.0 50.5
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.141 3.141 0.000 93 243092 50.0 51.5
26 Acetone 43 3.161 3.161 0.000 100 2120070 200.0 220.7
29 Iodomethane 142 3.270 3.270 0.000 99 324583 50.0 45.7
30 Carbon disulfide 76 3.337 3.337 0.000 99 1124493 50.0 47.9
32 Methyl acetate 43 3.399 3.399 0.000 98 1765672 100.0 101.7
33 3-Chloro-1-propene 41 3.421 3.421 0.000 90 632154 50.0 49.8
34 Methylene Chloride 84 3.521 3.521 0.000 92 449723 50.0 48.5
35 2-Methyl-2-propanol 59 3.566 3.566 0.000 100 3051902 500.0 539.7
36 Acrylonitrile 53 3.688 3.688 0.000 99 4494248 500.0 533.6
37 Methyl tert-butyl ether 73 3.714 3.714 0.000 94 1369888 50.0 49.9
38 trans-1,2-Dichloroethene 96 3.730 3.730 0.000 97 364567 50.0 50.5
39 Hexane 57 3.932 3.932 0.000 92 533228 50.0 49.1
40 Vinyl acetate 43 4.029 4.029 0.000 97 2151296 100.0 103.2
12/27/2024
9:26:49 AM
Page 257 of 428
Report Date: 18-Dec-2024 06:16:46 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005228.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
42 1,1-Dichloroethane 63 4.058 4.058 0.000 96 697031 50.0 50.7
45 2-Butanone (MEK) 43 4.453 4.453 0.000 100 3189266 200.0 206.9
47 cis-1,2-Dichloroethene 96 4.482 4.482 0.000 83 421444 50.0 49.9
48 2,2-Dichloropropane 77 4.495 4.495 0.000 88 575579 50.0 51.5
50 sec-Butyl Alcohol 45 4.569 4.569 0.000 99 5029635 1200.0 1316.5
52 Chlorobromomethane 128 4.659 4.659 0.000 98 205409 50.0 53.0
53 Tetrahydrofuran 42 4.675 4.675 0.000 86 972563 100.0 103.7
54 Chloroform 83 4.723 4.723 0.000 94 687984 50.0 50.5
55 1,1,1-Trichloroethane 97 4.874 4.874 0.000 99 565817 50.0 50.9
56 Cyclohexane 56 4.936 4.936 0.000 94 654860 50.0 49.3
57 1,1-Dichloropropene 75 4.987 4.987 0.000 96 543794 50.0 49.8
59 Carbon tetrachloride 117 4.997 4.997 0.000 93 415782 50.0 46.4
58 Isobutyl alcohol 41 4.997 4.997 0.000 94 2070468 1250.0 1430.0
60 Benzene 78 5.145 5.145 0.000 96 1540202 50.0 49.4
61 1,2-Dichloroethane 62 5.167 5.167 0.000 98 592598 50.0 47.5
63 n-Heptane 43 5.331 5.331 0.000 91 517475 50.0 50.4
65 Trichloroethene 95 5.640 5.640 0.000 98 396862 50.0 51.1
66 2-Pentanone 43 5.739 5.739 0.000 99 3659782 160.0 170.9
67 Methylcyclohexane 55 5.842 5.842 0.000 92 517741 50.0 49.1
69 1,2-Dichloropropane 63 5.849 5.849 0.000 96 408781 50.0 50.0
70 1,4-Dioxane 88 5.919 5.919 0.000 91 269292 1000.0 1090.9
71 Dibromomethane 93 5.923 5.923 0.000 94 274336 50.0 49.0
72 Dichlorobromomethane 83 6.045 6.045 0.000 99 486872 50.0 51.7
74 2-Chloroethyl vinyl ether 63 6.247 6.247 0.000 92 61020 50.0 44.5
75 cis-1,3-Dichloropropene 75 6.399 6.399 0.000 95 679725 50.0 52.1
76 4-Methyl-2-pentanone (MIBK) 43 6.501 6.501 0.000 96 4351443 200.0 210.8
77 Toluene 91 6.694 6.694 0.000 98 1709226 50.0 50.3
78 trans-1,3-Dichloropropene 75 6.868 6.868 0.000 95 637945 50.0 45.9
79 Ethyl methacrylate 69 6.887 6.887 0.000 90 809490 50.0 53.3
80 1,1,2-Trichloroethane 97 7.045 7.045 0.000 92 409117 50.0 51.1
82 Tetrachloroethene 164 7.148 7.148 0.000 93 289702 50.0 48.6
83 1,3-Dichloropropane 76 7.196 7.196 0.000 92 740643 50.0 49.6
84 2-Hexanone 43 7.212 7.212 0.000 95 3804567 200.0 211.0
85 Chlorodibromomethane 129 7.395 7.395 0.000 90 371398 50.0 46.4
86 Ethylene Dibromide 107 7.517 7.517 0.000 98 457945 50.0 51.1
87 1-Chlorohexane 91 7.907 7.907 0.000 98 438465 40.0 38.6
88 Chlorobenzene 112 7.955 7.955 0.000 93 1105567 50.0 49.6
89 1,1,1,2-Tetrachloroethane 131 8.025 8.025 0.000 94 352872 50.0 52.7
90 Ethylbenzene 106 8.032 8.032 0.000 99 595598 50.0 51.1
91 m-Xylene & p-Xylene 106 8.151 8.151 0.000 100 730820 50.0 49.8
92 o-Xylene 106 8.514 8.514 0.000 97 741953 50.0 51.7
93 Styrene 104 8.527 8.527 0.000 95 1259662 50.0 52.9
94 Bromoform 173 8.710 8.710 0.000 94 269696 50.0 43.7
95 Isopropylbenzene 105 8.855 8.855 0.000 96 1749109 50.0 50.7
97 Cyclohexanone 55 8.958 8.958 0.000 93 2547982 1500.0 1602.7
98 1,1,2,2-Tetrachloroethane 83 9.141 9.141 0.000 94 763061 50.0 51.2
99 trans-1,4-Dichloro-2-butene 53 9.180 9.180 0.000 86 241044 50.0 44.8
100 Bromobenzene 156 9.183 9.183 0.000 98 454983 50.0 50.2
101 1,2,3-Trichloropropane 110 9.206 9.206 0.000 86 276059 50.0 51.5
102 N-Propylbenzene 120 9.257 9.257 0.000 99 492278 50.0 50.0
103 2-Chlorotoluene 126 9.360 9.360 0.000 96 424990 50.0 49.0
104 1,3,5-Trimethylbenzene 105 9.431 9.431 0.000 95 1550656 50.0 50.8
12/27/2024
9:26:49 AM
Page 258 of 428
Report Date: 18-Dec-2024 06:16:46 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005228.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
105 4-Chlorotoluene 126 9.476 9.476 0.000 99 440056 50.0 48.7
107 tert-Butylbenzene 119 9.746 9.746 0.000 93 1360770 50.0 50.1
108 1,2,4-Trimethylbenzene 105 9.804 9.804 0.000 98 1606966 50.0 51.1
109 sec-Butylbenzene 134 9.968 9.968 0.000 95 393021 50.0 50.6
110 1,3-Dichlorobenzene 146 10.099 10.099 0.000 97 862717 50.0 48.8
111 4-Isopropyltoluene 119 10.112 10.112 0.000 97 1734296 50.0 52.5
112 1,4-Dichlorobenzene 146 10.199 10.199 0.000 94 860986 50.0 48.1
114 n-Butylbenzene 91 10.524 10.524 0.000 98 1643023 50.0 51.9
115 1,2-Dichlorobenzene 146 10.562 10.562 0.000 96 862661 50.0 50.8
116 1,2-Dibromo-3-Chloropropane 157 11.344 11.344 0.000 80 258496 50.0 45.7
118 1,2,4-Trichlorobenzene 180 12.180 12.180 0.000 94 551379 50.0 50.7
119 Hexachlorobutadiene 225 12.321 12.321 0.000 96 242051 50.0 52.6
120 Naphthalene 128 12.453 12.453 0.000 98 2333336 50.0 48.8
121 1,2,3-Trichlorobenzene 180 12.678 12.678 0.000 95 551306 50.0 50.2
136 Butadiene 54 0.000 ND ND
S 155 Xylenes, Total 106 0 100.0 101.4
S 152 Trihalomethanes, Total 1 0 200.0 192.3
S 154 1,3-Dichloropropene, Total 1 0 100.0 98.0
S 151 1,2-Dichloroethene, Total 1 0 100.0 100.4
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
MV-MegaMainA_00121 Amount Added: 25.00 Units: uL
MV-Gas A_00206 Amount Added: 10.00 Units: uL
mv-IS_SS_00093 Amount Added: 5.00 Units: uL Run Reagent
12/27/2024
9:26:49 AM
Page 259 of 428
Report Date: 18-Dec-2024 06:16:46 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005228.D
Injection Date:17-Dec-2024 02:40:52 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:icis Worklist Smp#:18
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:6
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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12/27/2024
9:26:49 AM
Page 260 of 428
Report Date: 18-Dec-2024 06:16:51 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005229.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:7
Inject. Date:17-Dec-2024 03:00:52 ALS Bottle#:7 Worklist Smp#:19
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ic
Misc. Info.:75
Operator ID:bustillose Instrument ID:VMS_MS14
Sublist:chrom-AQ_VMS14_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:18-Dec-2024 06:16:50 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: LP8K Date:17-Dec-2024 15:01:08
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 98 2014927 50.0 50.0
* 2 Chlorobenzene-d5 119 7.926 7.926 0.000 88 532086 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.173 0.000 96 835230 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.839 4.842 -0.003 93 523151 50.0 51.1
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 89 679742 50.0 49.9
$ 6 Toluene-d8 (Surr) 98 6.637 6.636 0.001 94 2150722 50.0 47.3
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 84 864454 50.0 50.6
10 Dichlorodifluoromethane 85 1.791 1.794 -0.003 99 972109 75.0 85.3
12 Chloromethane 50 1.971 1.974 -0.003 99 978356 75.0 73.2
13 Vinyl chloride 62 2.087 2.087 0.000 98 796163 75.0 77.6
15 Bromomethane 94 2.396 2.399 -0.003 92 503129 75.0 69.5
16 Chloroethane 64 2.495 2.498 -0.003 100 505232 75.0 77.4
17 Dichlorofluoromethane 67 2.678 2.678 0.000 97 1342908 75.0 78.1
18 Trichlorofluoromethane 101 2.717 2.717 0.000 98 951986 75.0 77.3
21 Ethyl ether 59 2.939 2.939 0.000 91 620240 75.0 76.9
22 Acrolein 56 3.055 3.055 0.000 99 1857772 740.6 801.9
25 1,1-Dichloroethene 96 3.141 3.141 0.000 97 562064 75.0 77.6
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.141 3.141 0.000 96 401417 75.0 79.1
26 Acetone 43 3.161 3.161 0.000 100 3121494 300.0 305.2
29 Iodomethane 142 3.270 3.270 0.000 100 580671 75.0 73.5
30 Carbon disulfide 76 3.338 3.337 0.001 99 1892618 75.0 74.6
32 Methyl acetate 43 3.399 3.399 0.000 98 2781652 150.0 148.8
33 3-Chloro-1-propene 41 3.421 3.421 0.000 90 1004965 75.0 73.7
34 Methylene Chloride 84 3.521 3.521 0.000 92 723460 75.0 72.4
35 2-Methyl-2-propanol 59 3.572 3.566 0.006 100 4698819 750.0 772.1
36 Acrylonitrile 53 3.688 3.688 0.000 98 6845362 750.0 755.1
37 Methyl tert-butyl ether 73 3.711 3.714 -0.003 94 2188764 75.0 74.1
38 trans-1,2-Dichloroethene 96 3.727 3.730 -0.003 98 585249 75.0 75.4
39 Hexane 57 3.932 3.932 0.000 93 862768 75.0 70.0
40 Vinyl acetate 43 4.032 4.029 0.003 97 3354728 150.0 149.6
12/27/2024
9:26:49 AM
Page 261 of 428
Report Date: 18-Dec-2024 06:16:51 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005229.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
42 1,1-Dichloroethane 63 4.058 4.058 0.000 96 1127206 75.0 76.1
45 2-Butanone (MEK) 43 4.453 4.453 0.000 99 4869179 300.0 293.5
47 cis-1,2-Dichloroethene 96 4.479 4.482 -0.003 83 684155 75.0 75.2
48 2,2-Dichloropropane 77 4.495 4.495 0.000 86 928879 75.0 77.2
50 sec-Butyl Alcohol 45 4.569 4.569 0.000 99 7778215 1800.0 1891.5
52 Chlorobromomethane 128 4.659 4.659 0.000 98 320610 75.0 76.9
53 Tetrahydrofuran 42 4.675 4.675 0.000 86 1494929 150.0 148.2
54 Chloroform 83 4.720 4.723 -0.003 94 1103259 75.0 75.2
55 1,1,1-Trichloroethane 97 4.871 4.874 -0.003 99 934516 75.0 78.1
56 Cyclohexane 56 4.936 4.936 0.000 90 1078214 75.0 75.5
57 1,1-Dichloropropene 75 4.987 4.987 0.000 96 881985 75.0 75.1
59 Carbon tetrachloride 117 4.994 4.997 -0.003 94 711267 75.0 73.3
58 Isobutyl alcohol 41 5.000 4.997 0.003 92 3159561 1875.0 2027.4
60 Benzene 78 5.145 5.145 0.000 96 2496743 75.0 74.4
61 1,2-Dichloroethane 62 5.170 5.167 0.003 97 965314 75.0 71.9
63 n-Heptane 43 5.331 5.331 0.000 92 849859 75.0 76.9
65 Trichloroethene 95 5.640 5.640 0.000 98 661836 75.0 75.1
66 2-Pentanone 43 5.739 5.739 0.000 99 5703155 240.0 247.4
67 Methylcyclohexane 55 5.842 5.842 0.000 90 843292 75.0 74.3
69 1,2-Dichloropropane 63 5.849 5.849 0.000 94 668177 75.0 75.9
70 1,4-Dioxane 88 5.907 5.919 -0.012 89 423979 1500.0 1595.7
71 Dibromomethane 93 5.923 5.923 0.000 95 456504 75.0 75.7
72 Dichlorobromomethane 83 6.045 6.045 0.000 99 836885 75.0 82.6
74 2-Chloroethyl vinyl ether 63 6.248 6.247 0.001 91 120465 75.0 81.6
75 cis-1,3-Dichloropropene 75 6.402 6.399 0.004 95 1157896 75.0 78.2
76 4-Methyl-2-pentanone (MIBK) 43 6.502 6.501 0.001 96 6789199 300.0 305.6
77 Toluene 91 6.694 6.694 0.000 98 2781057 75.0 76.0
78 trans-1,3-Dichloropropene 75 6.868 6.868 0.000 96 1082921 75.0 72.0
79 Ethyl methacrylate 69 6.884 6.887 -0.003 89 1319358 75.0 76.6
80 1,1,2-Trichloroethane 97 7.048 7.045 0.003 92 684456 75.0 79.4
82 Tetrachloroethene 164 7.148 7.148 0.000 94 490736 75.0 72.6
83 1,3-Dichloropropane 76 7.196 7.196 0.000 91 1219083 75.0 71.9
84 2-Hexanone 43 7.212 7.212 0.000 95 5893796 300.0 288.0
85 Chlorodibromomethane 129 7.392 7.395 -0.003 90 651290 75.0 71.3
86 Ethylene Dibromide 107 7.514 7.517 -0.003 98 763628 75.0 75.1
87 1-Chlorohexane 91 7.907 7.907 0.001 98 732283 60.0 56.8
88 Chlorobenzene 112 7.955 7.955 0.000 93 1809710 75.0 71.5
89 1,1,1,2-Tetrachloroethane 131 8.022 8.025 -0.003 95 604243 75.0 79.6
90 Ethylbenzene 106 8.032 8.032 0.000 99 975360 75.0 73.7
91 m-Xylene & p-Xylene 106 8.145 8.151 -0.006 99 1166938 75.0 70.0
92 o-Xylene 106 8.514 8.514 0.000 97 1168496 75.0 71.7
93 Styrene 104 8.527 8.527 0.000 95 2026174 75.0 75.0
94 Bromoform 173 8.714 8.710 0.004 94 486494 75.0 68.5
95 Isopropylbenzene 105 8.855 8.855 0.000 96 2832836 75.0 75.1
97 Cyclohexanone 55 8.958 8.958 0.000 93 3886912 2250.0 2154.5
98 1,1,2,2-Tetrachloroethane 83 9.141 9.141 0.000 95 1241589 75.0 76.1
99 trans-1,4-Dichloro-2-butene 53 9.177 9.180 -0.003 83 415692 75.0 69.9
100 Bromobenzene 156 9.186 9.183 0.003 98 741232 75.0 74.7
101 1,2,3-Trichloropropane 110 9.209 9.206 0.003 86 433696 75.0 73.9
102 N-Propylbenzene 120 9.260 9.257 0.003 99 775253 75.0 72.0
103 2-Chlorotoluene 126 9.360 9.360 0.000 95 669511 75.0 70.5
104 1,3,5-Trimethylbenzene 105 9.431 9.431 0.000 96 2298155 75.0 68.8
12/27/2024
9:26:49 AM
Page 262 of 428
Report Date: 18-Dec-2024 06:16:51 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005229.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
105 4-Chlorotoluene 126 9.479 9.476 0.003 99 699852 75.0 70.7
107 tert-Butylbenzene 119 9.746 9.746 0.000 93 2163046 75.0 72.8
108 1,2,4-Trimethylbenzene 105 9.804 9.804 0.000 98 2353619 75.0 68.4
109 sec-Butylbenzene 134 9.971 9.968 0.003 95 626094 75.0 73.6
110 1,3-Dichlorobenzene 146 10.099 10.099 0.000 97 1393389 75.0 72.0
111 4-Isopropyltoluene 119 10.116 10.112 0.004 97 2630429 75.0 72.7
112 1,4-Dichlorobenzene 146 10.199 10.199 0.000 93 1364764 75.0 69.7
114 n-Butylbenzene 91 10.524 10.524 0.000 98 2496130 75.0 72.0
115 1,2-Dichlorobenzene 146 10.563 10.562 0.000 96 1352416 75.0 72.9
116 1,2-Dibromo-3-Chloropropane 157 11.344 11.344 0.000 85 428181 75.0 68.3
118 1,2,4-Trichlorobenzene 180 12.180 12.180 0.000 93 953445 75.0 80.1
119 Hexachlorobutadiene 225 12.321 12.321 0.000 96 401633 75.0 79.8
120 Naphthalene 128 12.453 12.453 0.000 98 3763068 75.0 71.6
121 1,2,3-Trichlorobenzene 180 12.678 12.678 0.000 95 936964 75.0 78.0
136 Butadiene 54 0.000 ND ND
S 156 Total BTEX 1 0 365.9
S 155 Xylenes, Total 106 0 150.0 141.7
S 152 Trihalomethanes, Total 1 0 300.0 297.7
S 154 1,3-Dichloropropene, Total 1 0 150.0 150.2
S 151 1,2-Dichloroethene, Total 1 0 150.0 150.6
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
MV-MegaMainA_00121 Amount Added: 37.50 Units: uL
MV-Gas A_00206 Amount Added: 15.00 Units: uL
mv-IS_SS_00093 Amount Added: 5.00 Units: uL Run Reagent
12/27/2024
9:26:49 AM
Page 263 of 428
Report Date: 18-Dec-2024 06:16:51 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005229.D
Injection Date:17-Dec-2024 03:00:52 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:ic Worklist Smp#:19
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:7
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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12/27/2024
9:26:49 AM
Page 264 of 428
Report Date: 18-Dec-2024 06:16:55 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005230.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:8
Inject. Date:17-Dec-2024 03:20:50 ALS Bottle#:8 Worklist Smp#:20
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ic
Misc. Info.:100
Operator ID:bustillose Instrument ID:VMS_MS14
Sublist:chrom-AQ_VMS14_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:18-Dec-2024 06:16:55 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: LP8K Date:17-Dec-2024 15:02:04
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 98 1912664 50.0 50.0
* 2 Chlorobenzene-d5 119 7.926 7.926 0.000 86 491053 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.173 0.000 96 753550 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.839 4.842 -0.003 92 496371 50.0 51.1
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 94 646604 50.0 50.0
$ 6 Toluene-d8 (Surr) 98 6.636 6.636 0.000 93 2039151 50.0 48.6
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 85 780326 50.0 50.6
10 Dichlorodifluoromethane 85 1.794 1.794 0.000 100 1522426 100.0 140.7
12 Chloromethane 50 1.974 1.974 0.000 99 1508221 100.0 118.8
13 Vinyl chloride 62 2.087 2.087 0.000 98 1238026 100.0 127.2
15 Bromomethane 94 2.392 2.399 -0.007 91 765276 100.0 110.6
16 Chloroethane 64 2.492 2.498 -0.006 100 760117 100.0 122.7
17 Dichlorofluoromethane 67 2.675 2.678 -0.003 97 2015278 100.0 123.5
18 Trichlorofluoromethane 101 2.714 2.717 -0.003 98 1495220 100.0 127.9
21 Ethyl ether 59 2.939 2.939 0.000 91 854385 100.0 111.6
22 Acrolein 56 3.055 3.055 0.000 99 2500286 987.5 1136.9
25 1,1-Dichloroethene 96 3.141 3.141 0.000 97 765098 100.0 111.3
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.138 3.141 -0.003 96 547730 100.0 113.6
26 Acetone 43 3.164 3.161 0.003 100 4166467 400.0 432.8
29 Iodomethane 142 3.270 3.270 0.000 99 831414 100.0 109.1
30 Carbon disulfide 76 3.334 3.337 -0.003 99 2621991 100.0 108.7
32 Methyl acetate 43 3.399 3.399 0.000 98 3747364 200.0 211.2
33 3-Chloro-1-propene 41 3.421 3.421 0.000 90 1335804 100.0 103.3
34 Methylene Chloride 84 3.518 3.521 -0.003 92 979468 100.0 103.3
35 2-Methyl-2-propanol 59 3.572 3.566 0.006 100 6451362 1000.0 1116.7
36 Acrylonitrile 53 3.691 3.688 0.003 98 9057354 1000.0 1052.5
37 Methyl tert-butyl ether 73 3.714 3.714 0.000 94 2988860 100.0 106.6
38 trans-1,2-Dichloroethene 96 3.730 3.730 0.000 97 796126 100.0 108.0
39 Hexane 57 3.932 3.932 0.000 92 1183304 100.0 104.0
40 Vinyl acetate 43 4.032 4.029 0.003 97 4533473 200.0 212.9
12/27/2024
9:26:49 AM
Page 265 of 428
Report Date: 18-Dec-2024 06:16:55 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005230.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
42 1,1-Dichloroethane 63 4.058 4.058 0.000 96 1540641 100.0 109.6
45 2-Butanone (MEK) 43 4.453 4.453 0.000 100 6580194 400.0 417.9
47 cis-1,2-Dichloroethene 96 4.482 4.482 0.000 82 950519 100.0 110.1
48 2,2-Dichloropropane 77 4.495 4.495 0.000 86 1264972 100.0 110.8
50 sec-Butyl Alcohol 45 4.569 4.569 0.000 99 10507385 2400.0 2691.8
52 Chlorobromomethane 128 4.659 4.659 0.000 98 435620 100.0 110.1
53 Tetrahydrofuran 42 4.675 4.675 0.000 87 2019188 200.0 210.8
54 Chloroform 83 4.720 4.723 -0.003 94 1517279 100.0 109.0
55 1,1,1-Trichloroethane 97 4.874 4.874 0.000 99 1281735 100.0 112.9
56 Cyclohexane 56 4.936 4.936 0.000 90 1481837 100.0 109.3
57 1,1-Dichloropropene 75 4.987 4.987 0.000 96 1223094 100.0 109.7
59 Carbon tetrachloride 117 4.993 4.997 -0.004 95 993323 100.0 107.5
58 Isobutyl alcohol 41 5.000 4.997 0.003 94 4221969 2500.0 2853.9
60 Benzene 78 5.145 5.145 0.000 96 3458394 100.0 108.5
61 1,2-Dichloroethane 62 5.170 5.167 0.003 97 1322488 100.0 103.7
63 n-Heptane 43 5.331 5.331 0.000 92 1158885 100.0 110.5
65 Trichloroethene 95 5.640 5.640 0.000 98 927111 100.0 114.0
66 2-Pentanone 43 5.743 5.739 0.004 99 7618261 320.0 348.2
67 Methylcyclohexane 55 5.842 5.842 0.000 91 1163413 100.0 107.9
69 1,2-Dichloropropane 63 5.849 5.849 0.000 94 926574 100.0 110.9
70 1,4-Dioxane 88 5.903 5.919 -0.016 89 578982 2000.0 2295.5
71 Dibromomethane 93 5.923 5.923 0.000 94 633827 100.0 110.8
72 Dichlorobromomethane 83 6.045 6.045 0.000 99 1185880 100.0 123.3
74 2-Chloroethyl vinyl ether 63 6.244 6.247 -0.003 92 149626 100.0 106.8
75 cis-1,3-Dichloropropene 75 6.399 6.399 0.001 95 1630069 100.0 119.3
76 4-Methyl-2-pentanone (MIBK) 43 6.501 6.501 0.000 96 9092107 400.0 431.1
77 Toluene 91 6.694 6.694 0.000 98 3871797 100.0 111.5
78 trans-1,3-Dichloropropene 75 6.868 6.868 0.000 96 1532902 100.0 107.0
79 Ethyl methacrylate 69 6.884 6.887 -0.003 90 1826929 100.0 115.0
80 1,1,2-Trichloroethane 97 7.045 7.045 0.000 92 946439 100.0 115.6
82 Tetrachloroethene 164 7.148 7.148 0.000 94 681809 100.0 109.2
83 1,3-Dichloropropane 76 7.196 7.196 0.000 91 1689919 100.0 108.0
84 2-Hexanone 43 7.212 7.212 0.000 95 7817903 400.0 414.0
85 Chlorodibromomethane 129 7.392 7.395 -0.003 91 928041 100.0 109.7
86 Ethylene Dibromide 107 7.514 7.517 -0.003 99 1058672 100.0 112.8
87 1-Chlorohexane 91 7.907 7.907 0.001 98 1038632 80.0 87.3
88 Chlorobenzene 112 7.955 7.955 0.000 93 2520232 100.0 107.9
89 1,1,1,2-Tetrachloroethane 131 8.022 8.025 -0.003 94 850540 100.0 121.4
90 Ethylbenzene 106 8.029 8.032 -0.003 99 1366356 100.0 111.9
91 m-Xylene & p-Xylene 106 8.144 8.151 -0.007 99 1660283 100.0 108.0
92 o-Xylene 106 8.514 8.514 0.000 97 1654275 100.0 110.0
93 Styrene 104 8.527 8.527 0.000 94 2805273 100.0 112.5
94 Bromoform 173 8.714 8.710 0.004 94 703097 100.0 106.4
95 Isopropylbenzene 105 8.855 8.855 0.000 96 3961206 100.0 116.4
97 Cyclohexanone 55 8.961 8.958 0.003 93 5353053 3000.0 3215.1
98 1,1,2,2-Tetrachloroethane 83 9.141 9.141 0.000 94 1693132 100.0 115.1
99 trans-1,4-Dichloro-2-butene 53 9.180 9.180 0.000 85 584799 100.0 108.3
100 Bromobenzene 156 9.183 9.183 0.000 98 1023976 100.0 114.4
101 1,2,3-Trichloropropane 110 9.206 9.206 0.000 84 597967 100.0 113.0
102 N-Propylbenzene 120 9.257 9.257 0.000 99 1089819 100.0 112.1
103 2-Chlorotoluene 126 9.363 9.360 0.003 96 937096 100.0 109.4
104 1,3,5-Trimethylbenzene 105 9.431 9.431 0.000 95 3343320 100.0 111.0
12/27/2024
9:26:49 AM
Page 266 of 428
Report Date: 18-Dec-2024 06:16:55 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005230.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
105 4-Chlorotoluene 126 9.479 9.476 0.003 99 976446 100.0 109.4
107 tert-Butylbenzene 119 9.746 9.746 0.000 93 3019270 100.0 112.6
108 1,2,4-Trimethylbenzene 105 9.804 9.804 0.000 98 3467903 100.0 111.7
109 sec-Butylbenzene 134 9.968 9.968 0.000 95 865556 100.0 112.8
110 1,3-Dichlorobenzene 146 10.099 10.099 0.000 97 1924638 100.0 110.3
111 4-Isopropyltoluene 119 10.112 10.112 0.000 97 3660931 100.0 112.2
112 1,4-Dichlorobenzene 146 10.196 10.199 -0.003 93 1901412 100.0 107.7
114 n-Butylbenzene 91 10.524 10.524 0.000 98 3516130 100.0 112.5
115 1,2-Dichlorobenzene 146 10.562 10.562 0.000 96 1843376 100.0 110.1
116 1,2-Dibromo-3-Chloropropane 157 11.347 11.344 0.003 82 607047 100.0 106.5
118 1,2,4-Trichlorobenzene 180 12.180 12.180 0.000 94 1322794 100.0 123.2
119 Hexachlorobutadiene 225 12.318 12.321 -0.003 96 549962 100.0 121.1
120 Naphthalene 128 12.453 12.453 0.000 98 5249592 100.0 110.4
121 1,2,3-Trichlorobenzene 180 12.681 12.678 0.003 95 1305664 100.0 120.4
136 Butadiene 54 0.000 ND ND
S 156 Total BTEX 1 0 549.9
S 155 Xylenes, Total 106 0 200.0 218.0
S 152 Trihalomethanes, Total 1 0 400.0 448.4
S 154 1,3-Dichloropropene, Total 1 0 200.0 226.3
S 151 1,2-Dichloroethene, Total 1 0 200.0 218.1
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
MV-MegaMainA_00121 Amount Added: 50.00 Units: uL
MV-Gas A_00206 Amount Added: 20.00 Units: uL
mv-IS_SS_00093 Amount Added: 5.00 Units: uL Run Reagent
12/27/2024
9:26:49 AM
Page 267 of 428
Report Date: 18-Dec-2024 06:16:55 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005230.D
Injection Date:17-Dec-2024 03:20:50 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:ic Worklist Smp#:20
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:8
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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12/27/2024
9:26:49 AM
Page 268 of 428
Report Date: 18-Dec-2024 06:16:59 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Lims ID:ic
Client ID:
Sample Type:IC Calib Level:9
Inject. Date:17-Dec-2024 03:40:54 ALS Bottle#:9 Worklist Smp#:21
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ic
Misc. Info.:200
Operator ID:bustillose Instrument ID:VMS_MS14
Sublist:chrom-AQ_VMS14_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:18-Dec-2024 06:16:59 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: LP8K Date:17-Dec-2024 15:08:58
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 99 2070734 50.0 50.0
* 2 Chlorobenzene-d5 119 7.929 7.926 0.003 86 535163 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.173 0.000 96 798527 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.842 4.842 0.000 93 541166 50.0 51.4
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 88 686951 50.0 49.1
$ 6 Toluene-d8 (Surr) 98 6.637 6.636 0.000 93 2206268 50.0 48.3
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 84 842211 50.0 51.6
10 Dichlorodifluoromethane 85 1.791 1.794 -0.003 99 2905497 200.0 248.0
12 Chloromethane 50 1.971 1.974 -0.003 99 2927610 200.0 213.0
13 Vinyl chloride 62 2.087 2.087 0.000 98 2407536 200.0 228.4
15 Bromomethane 94 2.392 2.399 -0.007 92 1531269 200.0 203.3
16 Chloroethane 64 2.492 2.498 -0.006 100 1448643 200.0 216.0
17 Dichlorofluoromethane 67 2.675 2.678 -0.003 97 3841464 200.0 217.5
18 Trichlorofluoromethane 101 2.714 2.717 -0.003 98 2894232 200.0 228.7
21 Ethyl ether 59 2.939 2.939 0.000 91 1742373 200.0 210.2
22 Acrolein 56 3.055 3.055 0.000 99 4922579 1975.0 2067.5
25 1,1-Dichloroethene 96 3.141 3.141 0.000 98 1576155 200.0 211.8
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.138 3.141 -0.003 97 1081922 200.0 207.3
26 Acetone 43 3.167 3.161 0.006 100 7657826 800.0 741.0
29 Iodomethane 142 3.267 3.270 -0.003 99 1654247 200.0 197.4
30 Carbon disulfide 76 3.334 3.337 -0.003 99 5150504 200.0 196.8
32 Methyl acetate 43 3.399 3.399 0.000 98 7377381 400.0 384.0
33 3-Chloro-1-propene 41 3.421 3.421 0.000 91 2266857 200.0 162.0
34 Methylene Chloride 84 3.518 3.521 -0.003 92 1942456 200.0 189.2
35 2-Methyl-2-propanol 59 3.582 3.566 0.016 100 11612587 2000.0 1856.7
36 Acrylonitrile 53 3.688 3.688 0.000 98 16715454 2000.0 1794.1
37 Methyl tert-butyl ether 73 3.714 3.714 0.000 95 5855037 200.0 192.9
38 trans-1,2-Dichloroethene 96 3.727 3.730 -0.003 98 1570154 200.0 196.8
39 Hexane 57 3.929 3.932 -0.003 92 2321134 200.0 187.3
40 Vinyl acetate 43 4.029 4.029 0.000 97 8954606 400.0 388.5
12/27/2024
9:26:49 AM
Page 269 of 428
Report Date: 18-Dec-2024 06:16:59 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
42 1,1-Dichloroethane 63 4.058 4.058 0.000 96 3077646 200.0 202.3
45 2-Butanone (MEK) 43 4.457 4.453 0.003 99 12316653 800.0 722.5
47 cis-1,2-Dichloroethene 96 4.479 4.482 -0.003 83 1900770 200.0 203.4
48 2,2-Dichloropropane 77 4.492 4.495 -0.003 87 2503792 200.0 202.6
50 sec-Butyl Alcohol 45 4.575 4.569 0.006 99 18571721 4800.0 4394.5
52 Chlorobromomethane 128 4.662 4.659 0.003 98 859366 200.0 200.6
53 Tetrahydrofuran 42 4.675 4.675 0.000 88 3880418 400.0 374.2
54 Chloroform 83 4.720 4.723 -0.003 93 3050561 200.0 202.4
55 1,1,1-Trichloroethane 97 4.871 4.874 -0.003 98 2615225 200.0 212.8
56 Cyclohexane 56 4.936 4.936 0.000 90 2910257 200.0 198.2
57 1,1-Dichloropropene 75 4.987 4.987 0.000 96 2421022 200.0 200.5
59 Carbon tetrachloride 117 4.993 4.997 -0.004 93 2014519 200.0 200.7
58 Isobutyl alcohol 41 5.006 4.997 0.009 94 7580235 5000.0 4732.9
60 Benzene 78 5.145 5.145 0.000 96 6841935 200.0 198.3
61 1,2-Dichloroethane 62 5.170 5.167 0.003 98 2663975 200.0 193.0
63 n-Heptane 43 5.328 5.331 -0.003 92 2284777 200.0 201.1
65 Trichloroethene 95 5.640 5.640 0.000 98 1875058 200.0 211.6
66 2-Pentanone 43 5.743 5.739 0.004 98 14200654 640.0 599.5
67 Methylcyclohexane 55 5.842 5.842 0.000 91 2280447 200.0 195.4
69 1,2-Dichloropropane 63 5.849 5.849 0.000 94 1868466 200.0 206.5
70 1,4-Dioxane 88 5.910 5.919 -0.009 94 888674 4000.0 3254.4
71 Dibromomethane 93 5.923 5.923 0.000 95 1280607 200.0 206.7
72 Dichlorobromomethane 83 6.045 6.045 0.000 99 2472670 200.0 237.5
74 2-Chloroethyl vinyl ether 63 6.247 6.247 0.000 92 399841 200.0 263.7
75 cis-1,3-Dichloropropene 75 6.402 6.399 0.004 95 3367268 200.0 226.1
76 4-Methyl-2-pentanone (MIBK) 43 6.498 6.501 -0.003 94 16411021 800.0 718.8 e
77 Toluene 91 6.694 6.694 0.000 98 7579347 200.0 201.6
78 trans-1,3-Dichloropropene 75 6.868 6.868 0.000 97 3150846 200.0 202.7
79 Ethyl methacrylate 69 6.887 6.887 0.000 90 3672275 200.0 212.0
80 1,1,2-Trichloroethane 97 7.048 7.045 0.003 92 1936225 200.0 218.5
82 Tetrachloroethene 164 7.148 7.148 0.000 95 1369028 200.0 201.3
83 1,3-Dichloropropane 76 7.196 7.196 0.000 91 3378987 200.0 198.2
84 2-Hexanone 43 7.215 7.212 0.003 93 14330160 800.0 696.3
85 Chlorodibromomethane 129 7.395 7.395 0.000 95 1982921 200.0 214.5
86 Ethylene Dibromide 107 7.518 7.517 0.001 98 2161546 200.0 211.4
87 1-Chlorohexane 91 7.907 7.907 0.001 98 2061781 160.0 159.2
88 Chlorobenzene 112 7.955 7.955 0.000 93 5003388 200.0 196.5
89 1,1,1,2-Tetrachloroethane 131 8.026 8.025 0.001 95 1746719 200.0 228.7
90 Ethylbenzene 106 8.029 8.032 -0.003 99 2653735 200.0 199.4
91 m-Xylene & p-Xylene 106 8.148 8.151 -0.003 99 3183367 200.0 190.0
92 o-Xylene 106 8.514 8.514 0.000 96 3213586 200.0 196.1
93 Styrene 104 8.527 8.527 0.000 94 5422411 200.0 199.5
94 Bromoform 173 8.714 8.710 0.004 94 1511311 200.0 208.1
95 Isopropylbenzene 105 8.855 8.855 0.000 97 7576929 200.0 210.1
97 Cyclohexanone 55 8.961 8.958 0.003 93 8854976 6000.0 4880.0
98 1,1,2,2-Tetrachloroethane 83 9.141 9.141 0.000 95 3375819 200.0 216.5
99 trans-1,4-Dichloro-2-butene 53 9.180 9.180 0.000 88 1182136 200.0 205.4
100 Bromobenzene 156 9.186 9.183 0.003 98 2001106 200.0 211.0
101 1,2,3-Trichloropropane 110 9.209 9.206 0.003 83 1156251 200.0 206.1
102 N-Propylbenzene 120 9.260 9.257 0.003 99 2059340 200.0 199.9
103 2-Chlorotoluene 126 9.363 9.360 0.003 95 1814693 200.0 199.9
104 1,3,5-Trimethylbenzene 105 9.431 9.431 0.000 95 6244987 200.0 195.6
12/27/2024
9:26:49 AM
Page 270 of 428
Report Date: 18-Dec-2024 06:16:59 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
105 4-Chlorotoluene 126 9.479 9.476 0.003 98 1853579 200.0 196.0
107 tert-Butylbenzene 119 9.749 9.746 0.003 93 5705780 200.0 200.8
108 1,2,4-Trimethylbenzene 105 9.804 9.804 0.000 98 6556335 200.0 199.3
109 sec-Butylbenzene 134 9.968 9.968 0.000 95 1635162 200.0 201.1
110 1,3-Dichlorobenzene 146 10.099 10.099 0.000 97 3692054 200.0 199.6
111 4-Isopropyltoluene 119 10.116 10.112 0.004 97 6868994 200.0 198.6
112 1,4-Dichlorobenzene 146 10.199 10.199 0.000 93 3684826 200.0 196.9
114 n-Butylbenzene 91 10.524 10.524 0.000 98 6747185 200.0 203.6
115 1,2-Dichlorobenzene 146 10.562 10.562 0.000 96 3613207 200.0 203.6
116 1,2-Dibromo-3-Chloropropane 157 11.344 11.344 0.000 82 1255228 200.0 206.3
118 1,2,4-Trichlorobenzene 180 12.180 12.180 0.000 94 2659524 200.0 233.8
119 Hexachlorobutadiene 225 12.321 12.321 0.000 95 1060004 200.0 220.3
120 Naphthalene 128 12.453 12.453 0.000 98 9920969 200.0 196.5
121 1,2,3-Trichlorobenzene 180 12.681 12.678 0.003 92 2572481 200.0 223.9
136 Butadiene 54 0.000 ND ND
S 156 Total BTEX 1 0 985.4
S 155 Xylenes, Total 106 0 400.0 386.0
S 152 Trihalomethanes, Total 1 0 800.0 862.5
S 154 1,3-Dichloropropene, Total 1 0 400.0 428.7
S 151 1,2-Dichloroethene, Total 1 0 400.0 400.2
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
e - Potential Peak Saturated
Reagents:
MV-MegaMainA_00121 Amount Added: 100.00 Units: uL
MV-Gas A_00206 Amount Added: 40.00 Units: uL
mv-IS_SS_00093 Amount Added: 5.00 Units: uL Run Reagent
12/27/2024
9:26:49 AM
Page 271 of 428
Report Date: 18-Dec-2024 06:16:59 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Injection Date:17-Dec-2024 03:40:54 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:ic Worklist Smp#:21
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:9
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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12/27/2024
9:26:49 AM
Page 272 of 428
Calibration / Dichlorodifluoromethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2829
Error Coefficients
Relative Standard Deviation:11.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.152381 50.0 2384488.0 0.304761 Y
2 IC 280-678685/14 1.0 0.28173 50.0 2252863.0 0.28173 Y
3 IC 280-678685/15 2.0 0.478825 50.0 2309819.0 0.239413 Y
4 IC 280-678685/16 5.0 1.275241 50.0 2301721.0 0.255048 Y
5 IC 280-678685/17 10.0 2.605412 50.0 2157605.0 0.260541 Y
6 ICIS 280-678685/18 50.0 15.849239 50.0 1872030.0 0.316985 Y
7 IC 280-678685/19 75.0 24.122685 50.0 2014927.0 0.321636 Y
8 IC 280-678685/20 100.0 39.798574 50.0 1912664.0 0.397986 N
9 IC 280-678685/21 200.0 70.15621 50.0 2070734.0 0.350781 N
RelResp = [0.2829]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
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IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
9:26:49 AM
Page 273 of 428
Calibration / Chloromethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3318
Error Coefficients
Relative Standard Deviation:13.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.197128 50.0 2384488.0 0.394257 Y
2 IC 280-678685/14 1.0 0.349378 50.0 2252863.0 0.349378 Y
3 IC 280-678685/15 2.0 0.5784 50.0 2309819.0 0.2892 Y
4 IC 280-678685/16 5.0 1.407143 50.0 2301721.0 0.281429 Y
5 IC 280-678685/17 10.0 2.744177 50.0 2157605.0 0.274418 Y
6 ICIS 280-678685/18 50.0 16.310422 50.0 1872030.0 0.326208 Y
7 IC 280-678685/19 75.0 24.277703 50.0 2014927.0 0.323703 Y
8 IC 280-678685/20 100.0 39.427233 50.0 1912664.0 0.394272 Y
9 IC 280-678685/21 200.0 70.690151 50.0 2070734.0 0.353451 Y
RelResp = [0.3318]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
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IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
IC 280-678685/21
12/27/2024
9:26:49 AM
Page 274 of 428
Calibration / Vinyl chloride
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2545
Error Coefficients
Relative Standard Deviation:13.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.127386 50.0 2384488.0 0.254772 Y
2 IC 280-678685/14 1.0 0.234701 50.0 2252863.0 0.234701 Y
3 IC 280-678685/15 2.0 0.432025 50.0 2309819.0 0.216013 Y
4 IC 280-678685/16 5.0 1.150682 50.0 2301721.0 0.230136 Y
5 IC 280-678685/17 10.0 2.17855 50.0 2157605.0 0.217855 Y
6 ICIS 280-678685/18 50.0 12.967127 50.0 1872030.0 0.259343 Y
7 IC 280-678685/19 75.0 19.756621 50.0 2014927.0 0.263422 Y
8 IC 280-678685/20 100.0 32.363918 50.0 1912664.0 0.323639 Y
9 IC 280-678685/21 200.0 58.13243 50.0 2070734.0 0.290662 Y
RelResp = [0.2545]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
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IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
9:26:49 AM
Page 275 of 428
Calibration / Bromomethane
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.2415
Slope:0.183
Error Coefficients
Relative Standard Deviation:21.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.136885 50.0 2384488.0 0.273769 N
2 IC 280-678685/14 1.0 0.157355 50.0 2252863.0 0.157355 N
3 IC 280-678685/15 2.0 0.262207 50.0 2309819.0 0.131103 Y
4 IC 280-678685/16 5.0 0.577307 50.0 2301721.0 0.115461 Y
5 IC 280-678685/17 10.0 1.253334 50.0 2157605.0 0.125333 Y
6 ICIS 280-678685/18 50.0 7.654658 50.0 1872030.0 0.153093 Y
7 IC 280-678685/19 75.0 12.485043 50.0 2014927.0 0.166467 Y
8 IC 280-678685/20 100.0 20.0055 50.0 1912664.0 0.200055 Y
9 IC 280-678685/21 200.0 36.974063 50.0 2070734.0 0.18487 Y
RelResp = [-0.2415] + [0.183]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
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s
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)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
IC 280-678685/21
Intercept = 1.32
12/27/2024
9:26:49 AM
Page 276 of 428
Calibration / Chloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1619
Error Coefficients
Relative Standard Deviation:12.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.086853 50.0 2384488.0 0.173706 Y
2 IC 280-678685/14 1.0 0.155669 50.0 2252863.0 0.155669 Y
3 IC 280-678685/15 2.0 0.285412 50.0 2309819.0 0.142706 Y
4 IC 280-678685/16 5.0 0.679904 50.0 2301721.0 0.135981 Y
5 IC 280-678685/17 10.0 1.445376 50.0 2157605.0 0.144538 Y
6 ICIS 280-678685/18 50.0 8.1988 50.0 1872030.0 0.163976 Y
7 IC 280-678685/19 75.0 12.537228 50.0 2014927.0 0.167163 Y
8 IC 280-678685/20 100.0 19.870636 50.0 1912664.0 0.198706 Y
9 IC 280-678685/21 200.0 34.978974 50.0 2070734.0 0.174895 Y
RelResp = [0.1619]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
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Calibration / Dichlorofluoromethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4265
Error Coefficients
Relative Standard Deviation:11.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.204845 50.0 2384488.0 0.40969 Y
2 IC 280-678685/14 1.0 0.389238 50.0 2252863.0 0.389238 Y
3 IC 280-678685/15 2.0 0.767138 50.0 2309819.0 0.383569 Y
4 IC 280-678685/16 5.0 1.937094 50.0 2301721.0 0.387419 Y
5 IC 280-678685/17 10.0 3.930214 50.0 2157605.0 0.393021 Y
6 ICIS 280-678685/18 50.0 22.049006 50.0 1872030.0 0.44098 Y
7 IC 280-678685/19 75.0 33.323986 50.0 2014927.0 0.44432 Y
8 IC 280-678685/20 100.0 52.682489 50.0 1912664.0 0.526825 Y
9 IC 280-678685/21 200.0 92.756095 50.0 2070734.0 0.46378 Y
RelResp = [0.4265]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
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Page 278 of 428
Calibration / Trichlorofluoromethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3055
Error Coefficients
Relative Standard Deviation:14.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.15735 50.0 2384488.0 0.314701 Y
2 IC 280-678685/14 1.0 0.259093 50.0 2252863.0 0.259093 Y
3 IC 280-678685/15 2.0 0.556299 50.0 2309819.0 0.27815 Y
4 IC 280-678685/16 5.0 1.354443 50.0 2301721.0 0.270889 Y
5 IC 280-678685/17 10.0 2.672361 50.0 2157605.0 0.267236 Y
6 ICIS 280-678685/18 50.0 15.228575 50.0 1872030.0 0.304572 Y
7 IC 280-678685/19 75.0 23.623337 50.0 2014927.0 0.314978 Y
8 IC 280-678685/20 100.0 39.087367 50.0 1912664.0 0.390874 Y
9 IC 280-678685/21 200.0 69.884205 50.0 2070734.0 0.349421 Y
RelResp = [0.3055]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
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Page 279 of 428
Calibration / Ethyl ether
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2002
Error Coefficients
Relative Standard Deviation:8.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.107675 50.0 2384488.0 0.21535 Y
2 IC 280-678685/14 1.0 0.200678 50.0 2252863.0 0.200678 Y
3 IC 280-678685/15 2.0 0.36938 50.0 2309819.0 0.18469 Y
4 IC 280-678685/16 5.0 0.920637 50.0 2301721.0 0.184127 Y
5 IC 280-678685/17 10.0 1.735118 50.0 2157605.0 0.173512 Y
6 ICIS 280-678685/18 50.0 10.212603 50.0 1872030.0 0.204252 Y
7 IC 280-678685/19 75.0 15.391128 50.0 2014927.0 0.205215 Y
8 IC 280-678685/20 100.0 22.334947 50.0 1912664.0 0.223349 Y
9 IC 280-678685/21 200.0 42.071386 50.0 2070734.0 0.210357 Y
RelResp = [0.2002]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
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Page 280 of 428
Calibration / Acrolein
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.05749
Error Coefficients
Relative Standard Deviation:11.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 4.9375 0.30862 50.0 2384488.0 0.062505 Y
2 IC 280-678685/14 9.875 0.542776 50.0 2252863.0 0.054965 Y
3 IC 280-678685/15 19.75 0.913708 50.0 2309819.0 0.046264 Y
4 IC 280-678685/16 49.375 2.473475 50.0 2301721.0 0.050096 Y
5 IC 280-678685/17 98.75 5.150271 50.0 2157605.0 0.052155 Y
6 ICIS 280-678685/18 493.75 31.013445 50.0 1872030.0 0.062812 Y
7 IC 280-678685/19 740.625 46.100231 50.0 2014927.0 0.062245 Y
8 IC 280-678685/20 987.5 65.361349 50.0 1912664.0 0.066189 Y
9 IC 280-678685/21 1975.0 118.860728 50.0 2070734.0 0.060183 Y
RelResp = [0.05749]x
Concentration
0 1000 2000
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
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Page 281 of 428
Calibration / 1,1,2-Trichloro-1,2,2-trifluoroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.126
Error Coefficients
Relative Standard Deviation:10.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.070581 50.0 2384488.0 0.141162 Y
2 IC 280-678685/14 1.0 0.116785 50.0 2252863.0 0.116785 Y
3 IC 280-678685/15 2.0 0.244067 50.0 2309819.0 0.122033 Y
4 IC 280-678685/16 5.0 0.593143 50.0 2301721.0 0.118629 Y
5 IC 280-678685/17 10.0 0.988735 50.0 2157605.0 0.098874 Y
6 ICIS 280-678685/18 50.0 6.492738 50.0 1872030.0 0.129855 Y
7 IC 280-678685/19 75.0 9.96108 50.0 2014927.0 0.132814 Y
8 IC 280-678685/20 100.0 14.318511 50.0 1912664.0 0.143185 Y
9 IC 280-678685/21 200.0 26.124118 50.0 2070734.0 0.130621 Y
RelResp = [0.126]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
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Calibration / 1,1-Dichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1797
Error Coefficients
Relative Standard Deviation:9.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.098365 50.0 2384488.0 0.19673 Y
2 IC 280-678685/14 1.0 0.183123 50.0 2252863.0 0.183123 Y
3 IC 280-678685/15 2.0 0.344746 50.0 2309819.0 0.172373 Y
4 IC 280-678685/16 5.0 0.816693 50.0 2301721.0 0.163339 Y
5 IC 280-678685/17 10.0 1.440185 50.0 2157605.0 0.144018 Y
6 ICIS 280-678685/18 50.0 9.065587 50.0 1872030.0 0.181312 Y
7 IC 280-678685/19 75.0 13.947503 50.0 2014927.0 0.185967 Y
8 IC 280-678685/20 100.0 20.000847 50.0 1912664.0 0.200008 Y
9 IC 280-678685/21 200.0 38.057882 50.0 2070734.0 0.190289 Y
RelResp = [0.1797]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
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Page 283 of 428
Calibration / Acetone
Curve Type:Linear
Weighting:Conc_Sq
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:2.217
Slope:0.2466
Error Coefficients
Relative Standard Deviation:8.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 2.0 2.976383 50.0 2384488.0 1.488192 N
2 IC 280-678685/14 4.0 3.260695 50.0 2252863.0 0.815174 Y
3 IC 280-678685/15 8.0 4.019579 50.0 2309819.0 0.502447 Y
4 IC 280-678685/16 20.0 6.765916 50.0 2301721.0 0.338296 Y
5 IC 280-678685/17 40.0 11.849945 50.0 2157605.0 0.296249 Y
6 ICIS 280-678685/18 200.0 56.624894 50.0 1872030.0 0.283124 Y
7 IC 280-678685/19 300.0 77.459233 50.0 2014927.0 0.258197 Y
8 IC 280-678685/20 400.0 108.917902 50.0 1912664.0 0.272295 Y
9 IC 280-678685/21 800.0 184.906077 50.0 2070734.0 0.231133 Y
RelResp = [2.217] + [0.2466]x
Concentration
0 100 200 300 400 500 600 700 800
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
Intercept = -8.99
12/27/2024
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Page 284 of 428
Calibration / Iodomethane
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.7384
Slope:0.2061
Error Coefficients
Relative Standard Deviation:14.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.0 50.0 2384488.0 0.0 N
2 IC 280-678685/14 1.0 0.081829 50.0 2252863.0 0.081829 N
3 IC 280-678685/15 2.0 0.179819 50.0 2309819.0 0.08991 N
4 IC 280-678685/16 5.0 0.48883 50.0 2301721.0 0.097766 Y
5 IC 280-678685/17 10.0 0.987762 50.0 2157605.0 0.098776 Y
6 ICIS 280-678685/18 50.0 8.669279 50.0 1872030.0 0.173386 Y
7 IC 280-678685/19 75.0 14.409232 50.0 2014927.0 0.192123 Y
8 IC 280-678685/20 100.0 21.73445 50.0 1912664.0 0.217344 Y
9 IC 280-678685/21 200.0 39.943493 50.0 2070734.0 0.199717 Y
RelResp = [-0.7384] + [0.2061]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
Intercept = 3.58
12/27/2024
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Page 285 of 428
Calibration / Carbon disulfide
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.3357
Slope:0.6337
Error Coefficients
Relative Standard Deviation:19.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.330889 50.0 2384488.0 0.661777 N
2 IC 280-678685/14 1.0 0.523401 50.0 2252863.0 0.523401 Y
3 IC 280-678685/15 2.0 0.988367 50.0 2309819.0 0.494184 Y
4 IC 280-678685/16 5.0 2.366447 50.0 2301721.0 0.473289 Y
5 IC 280-678685/17 10.0 4.23743 50.0 2157605.0 0.423743 Y
6 ICIS 280-678685/18 50.0 30.034054 50.0 1872030.0 0.600681 Y
7 IC 280-678685/19 75.0 46.964927 50.0 2014927.0 0.626199 Y
8 IC 280-678685/20 100.0 68.542907 50.0 1912664.0 0.685429 Y
9 IC 280-678685/21 200.0 124.364211 50.0 2070734.0 0.621821 Y
RelResp = [-0.3357] + [0.6337]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
Intercept = 0.530
12/27/2024
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Page 286 of 428
Calibration / 3-Chloro-1-propene
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.09332
Slope:0.3373
Error Coefficients
Relative Standard Deviation:12.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 1.13668 50.0 2384488.0 2.27336 N
2 IC 280-678685/14 1.0 0.432783 50.0 2252863.0 0.432783 Y
3 IC 280-678685/15 2.0 0.900763 50.0 2309819.0 0.450382 Y
4 IC 280-678685/16 5.0 1.765744 50.0 2301721.0 0.353149 Y
5 IC 280-678685/17 10.0 2.773654 50.0 2157605.0 0.277365 Y
6 ICIS 280-678685/18 50.0 16.884185 50.0 1872030.0 0.337684 Y
7 IC 280-678685/19 75.0 24.938 50.0 2014927.0 0.332507 Y
8 IC 280-678685/20 100.0 34.919986 50.0 1912664.0 0.3492 Y
9 IC 280-678685/21 200.0 54.735591 50.0 2070734.0 0.273678 N
RelResp = [0.09332] + [0.3373]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
Intercept = -0.277
12/27/2024
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Page 287 of 428
Calibration / Methyl acetate
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4639
Error Coefficients
Relative Standard Deviation:11.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 1.0 0.574966 50.0 2384488.0 0.574966 Y
2 IC 280-678685/14 2.0 0.971608 50.0 2252863.0 0.485804 Y
3 IC 280-678685/15 4.0 1.640258 50.0 2309819.0 0.410065 Y
4 IC 280-678685/16 10.0 4.200444 50.0 2301721.0 0.420044 Y
5 IC 280-678685/17 20.0 8.341216 50.0 2157605.0 0.417061 Y
6 ICIS 280-678685/18 100.0 47.159287 50.0 1872030.0 0.471593 Y
7 IC 280-678685/19 150.0 69.026124 50.0 2014927.0 0.460174 Y
8 IC 280-678685/20 200.0 97.9619 50.0 1912664.0 0.48981 Y
9 IC 280-678685/21 400.0 178.134444 50.0 2070734.0 0.445336 Y
RelResp = [0.4639]x
Concentration
0 100 200 300 400
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
12/27/2024
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Page 288 of 428
Calibration / Methylene Chloride
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2479
Error Coefficients
Relative Standard Deviation:10.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.284736 50.0 2384488.0 0.569472 N
2 IC 280-678685/14 1.0 0.364203 50.0 2252863.0 0.364203 N
3 IC 280-678685/15 2.0 0.602645 50.0 2309819.0 0.301322 Y
4 IC 280-678685/16 5.0 1.234663 50.0 2301721.0 0.246933 Y
5 IC 280-678685/17 10.0 2.166337 50.0 2157605.0 0.216634 Y
6 ICIS 280-678685/18 50.0 12.01164 50.0 1872030.0 0.240233 Y
7 IC 280-678685/19 75.0 17.952511 50.0 2014927.0 0.239367 Y
8 IC 280-678685/20 100.0 25.604811 50.0 1912664.0 0.256048 Y
9 IC 280-678685/21 200.0 46.902596 50.0 2070734.0 0.234513 Y
RelResp = [0.2479]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
12/27/2024
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Calibration / 2-Methyl-2-propanol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.151
Error Coefficients
Relative Standard Deviation:12.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 5.0 0.911684 50.0 2384488.0 0.182337 Y
2 IC 280-678685/14 10.0 1.476899 50.0 2252863.0 0.14769 Y
3 IC 280-678685/15 20.0 2.373974 50.0 2309819.0 0.118699 Y
4 IC 280-678685/16 50.0 6.934637 50.0 2301721.0 0.138693 Y
5 IC 280-678685/17 100.0 14.443167 50.0 2157605.0 0.144432 Y
6 ICIS 280-678685/18 500.0 81.51317 50.0 1872030.0 0.163026 Y
7 IC 280-678685/19 750.0 116.600229 50.0 2014927.0 0.155467 Y
8 IC 280-678685/20 1000.0 168.648597 50.0 1912664.0 0.168649 Y
9 IC 280-678685/21 2000.0 280.397844 50.0 2070734.0 0.140199 Y
RelResp = [0.151]x
Concentration
0 1000 2000
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
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Calibration / Acrylonitrile
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.225
Error Coefficients
Relative Standard Deviation:7.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 5.0 1.292038 50.0 2384488.0 0.258408 Y
2 IC 280-678685/14 10.0 2.226944 50.0 2252863.0 0.222694 Y
3 IC 280-678685/15 20.0 4.268906 50.0 2309819.0 0.213445 Y
4 IC 280-678685/16 50.0 10.488956 50.0 2301721.0 0.209779 Y
5 IC 280-678685/17 100.0 21.523217 50.0 2157605.0 0.215232 Y
6 ICIS 280-678685/18 500.0 120.036752 50.0 1872030.0 0.240074 Y
7 IC 280-678685/19 750.0 169.866253 50.0 2014927.0 0.226488 Y
8 IC 280-678685/20 1000.0 236.773265 50.0 1912664.0 0.236773 Y
9 IC 280-678685/21 2000.0 403.611811 50.0 2070734.0 0.201806 Y
RelResp = [0.225]x
Concentration
0 1000 2000
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
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Page 291 of 428
Calibration / Methyl tert-butyl ether
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7329
Error Coefficients
Relative Standard Deviation:6.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.420614 50.0 2384488.0 0.841229 Y
2 IC 280-678685/14 1.0 0.734443 50.0 2252863.0 0.734443 Y
3 IC 280-678685/15 2.0 1.394828 50.0 2309819.0 0.697414 Y
4 IC 280-678685/16 5.0 3.484002 50.0 2301721.0 0.6968 Y
5 IC 280-678685/17 10.0 6.818139 50.0 2157605.0 0.681814 Y
6 ICIS 280-678685/18 50.0 36.588303 50.0 1872030.0 0.731766 Y
7 IC 280-678685/19 75.0 54.313729 50.0 2014927.0 0.724183 Y
8 IC 280-678685/20 100.0 78.133431 50.0 1912664.0 0.781334 Y
9 IC 280-678685/21 200.0 141.375884 50.0 2070734.0 0.706879 Y
RelResp = [0.7329]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
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Page 292 of 428
Calibration / trans-1,2-Dichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1927
Error Coefficients
Relative Standard Deviation:7.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.103775 50.0 2384488.0 0.20755 Y
2 IC 280-678685/14 1.0 0.198126 50.0 2252863.0 0.198126 Y
3 IC 280-678685/15 2.0 0.399404 50.0 2309819.0 0.199702 Y
4 IC 280-678685/16 5.0 0.906669 50.0 2301721.0 0.181334 Y
5 IC 280-678685/17 10.0 1.610791 50.0 2157605.0 0.161079 Y
6 ICIS 280-678685/18 50.0 9.73721 50.0 1872030.0 0.194744 Y
7 IC 280-678685/19 75.0 14.522834 50.0 2014927.0 0.193638 Y
8 IC 280-678685/20 100.0 20.811967 50.0 1912664.0 0.20812 Y
9 IC 280-678685/21 200.0 37.912982 50.0 2070734.0 0.189565 Y
RelResp = [0.1927]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
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Calibration / Hexane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.158
Error Coefficients
Relative Standard Deviation:13.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.74892 50.0 554198.0 1.49784 Y
2 IC 280-678685/14 1.0 1.243373 50.0 537610.0 1.243373 Y
3 IC 280-678685/15 2.0 2.282806 50.0 550003.0 1.141403 Y
4 IC 280-678685/16 5.0 5.567661 50.0 544277.0 1.113532 Y
5 IC 280-678685/17 10.0 9.184904 50.0 510664.0 0.91849 Y
6 ICIS 280-678685/18 50.0 56.860913 50.0 468888.0 1.137218 Y
7 IC 280-678685/19 75.0 81.074112 50.0 532086.0 1.080988 Y
8 IC 280-678685/20 100.0 120.486383 50.0 491053.0 1.204864 Y
9 IC 280-678685/21 200.0 216.862339 50.0 535163.0 1.084312 Y
RelResp = [1.158]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
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Calibration / Vinyl acetate
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5566
Error Coefficients
Relative Standard Deviation:5.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 1.0 0.608957 50.0 2384488.0 0.608957 Y
2 IC 280-678685/14 2.0 1.124902 50.0 2252863.0 0.562451 Y
3 IC 280-678685/15 4.0 2.185777 50.0 2309819.0 0.546444 Y
4 IC 280-678685/16 10.0 5.199957 50.0 2301721.0 0.519996 Y
5 IC 280-678685/17 20.0 10.168914 50.0 2157605.0 0.508446 Y
6 ICIS 280-678685/18 100.0 57.458908 50.0 1872030.0 0.574589 Y
7 IC 280-678685/19 150.0 83.246887 50.0 2014927.0 0.554979 Y
8 IC 280-678685/20 200.0 118.512007 50.0 1912664.0 0.59256 Y
9 IC 280-678685/21 400.0 216.218162 50.0 2070734.0 0.540545 Y
RelResp = [0.5566]x
Concentration
0 100 200 300 400
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
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Page 295 of 428
Calibration / 1,1-Dichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3674
Error Coefficients
Relative Standard Deviation:7.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.201532 50.0 2384488.0 0.403063 Y
2 IC 280-678685/14 1.0 0.346359 50.0 2252863.0 0.346359 Y
3 IC 280-678685/15 2.0 0.741292 50.0 2309819.0 0.370646 Y
4 IC 280-678685/16 5.0 1.76027 50.0 2301721.0 0.352054 Y
5 IC 280-678685/17 10.0 3.145409 50.0 2157605.0 0.314541 Y
6 ICIS 280-678685/18 50.0 18.616983 50.0 1872030.0 0.37234 Y
7 IC 280-678685/19 75.0 27.971386 50.0 2014927.0 0.372952 Y
8 IC 280-678685/20 100.0 40.274742 50.0 1912664.0 0.402747 Y
9 IC 280-678685/21 200.0 74.312925 50.0 2070734.0 0.371565 Y
RelResp = [0.3674]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
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Calibration / 2-Butanone (MEK)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.4116
Error Coefficients
Relative Standard Deviation:10.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 2.0 1.026803 50.0 2384488.0 0.513402 Y
2 IC 280-678685/14 4.0 1.69633 50.0 2252863.0 0.424083 Y
3 IC 280-678685/15 8.0 3.074635 50.0 2309819.0 0.384329 Y
4 IC 280-678685/16 20.0 7.43763 50.0 2301721.0 0.371882 Y
5 IC 280-678685/17 40.0 15.227231 50.0 2157605.0 0.380681 Y
6 ICIS 280-678685/18 200.0 85.182022 50.0 1872030.0 0.42591 Y
7 IC 280-678685/19 300.0 120.827678 50.0 2014927.0 0.402759 Y
8 IC 280-678685/20 400.0 172.016465 50.0 1912664.0 0.430041 Y
9 IC 280-678685/21 800.0 297.398241 50.0 2070734.0 0.371748 Y
RelResp = [0.4116]x
Concentration
0 100 200 300 400 500 600 700 800
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
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Calibration / cis-1,2-Dichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2257
Error Coefficients
Relative Standard Deviation:6.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.118852 50.0 2384488.0 0.237703 Y
2 IC 280-678685/14 1.0 0.23064 50.0 2252863.0 0.23064 Y
3 IC 280-678685/15 2.0 0.432653 50.0 2309819.0 0.216326 Y
4 IC 280-678685/16 5.0 1.118554 50.0 2301721.0 0.223711 Y
5 IC 280-678685/17 10.0 1.930891 50.0 2157605.0 0.193089 Y
6 ICIS 280-678685/18 50.0 11.256337 50.0 1872030.0 0.225127 Y
7 IC 280-678685/19 75.0 16.977166 50.0 2014927.0 0.226362 Y
8 IC 280-678685/20 100.0 24.848039 50.0 1912664.0 0.24848 Y
9 IC 280-678685/21 200.0 45.896045 50.0 2070734.0 0.22948 Y
RelResp = [0.2257]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
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Calibration / 2,2-Dichloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2985
Error Coefficients
Relative Standard Deviation:8.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.160454 50.0 2384488.0 0.320907 Y
2 IC 280-678685/14 1.0 0.301084 50.0 2252863.0 0.301084 Y
3 IC 280-678685/15 2.0 0.570391 50.0 2309819.0 0.285196 Y
4 IC 280-678685/16 5.0 1.413877 50.0 2301721.0 0.282775 Y
5 IC 280-678685/17 10.0 2.485348 50.0 2157605.0 0.248535 Y
6 ICIS 280-678685/18 50.0 15.373124 50.0 1872030.0 0.307462 Y
7 IC 280-678685/19 75.0 23.049942 50.0 2014927.0 0.307333 Y
8 IC 280-678685/20 100.0 33.068328 50.0 1912664.0 0.330683 Y
9 IC 280-678685/21 200.0 60.45663 50.0 2070734.0 0.302283 Y
RelResp = [0.2985]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
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Calibration / sec-Butyl Alcohol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.102
Error Coefficients
Relative Standard Deviation:9.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 12.0 1.362745 50.0 2384488.0 0.113562 Y
2 IC 280-678685/14 24.0 2.234867 50.0 2252863.0 0.093119 Y
3 IC 280-678685/15 48.0 4.206996 50.0 2309819.0 0.087646 Y
4 IC 280-678685/16 120.0 11.755204 50.0 2301721.0 0.09796 Y
5 IC 280-678685/17 240.0 23.772748 50.0 2157605.0 0.099053 Y
6 ICIS 280-678685/18 1200.0 134.336389 50.0 1872030.0 0.111947 Y
7 IC 280-678685/19 1800.0 193.014809 50.0 2014927.0 0.10723 Y
8 IC 280-678685/20 2400.0 274.679322 50.0 1912664.0 0.11445 Y
9 IC 280-678685/21 4800.0 448.433285 50.0 2070734.0 0.093424 Y
RelResp = [0.102]x
Concentration
0 1000 2000 3000 4000 5000
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
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Calibration / Chlorobromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1034
Error Coefficients
Relative Standard Deviation:10.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.057308 50.0 2384488.0 0.114616 Y
2 IC 280-678685/14 1.0 0.080098 50.0 2252863.0 0.080098 Y
3 IC 280-678685/15 2.0 0.222009 50.0 2309819.0 0.111004 Y
4 IC 280-678685/16 5.0 0.493631 50.0 2301721.0 0.098726 Y
5 IC 280-678685/17 10.0 0.929572 50.0 2157605.0 0.092957 Y
6 ICIS 280-678685/18 50.0 5.486264 50.0 1872030.0 0.109725 Y
7 IC 280-678685/19 75.0 7.955871 50.0 2014927.0 0.106078 Y
8 IC 280-678685/20 100.0 11.387782 50.0 1912664.0 0.113878 Y
9 IC 280-678685/21 200.0 20.750275 50.0 2070734.0 0.103751 Y
RelResp = [0.1034]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
9:26:49 AM
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Calibration / Tetrahydrofuran
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2504
Error Coefficients
Relative Standard Deviation:8.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 1.0 0.297821 50.0 2384488.0 0.297821 Y
2 IC 280-678685/14 2.0 0.503781 50.0 2252863.0 0.251891 Y
3 IC 280-678685/15 4.0 0.932281 50.0 2309819.0 0.23307 Y
4 IC 280-678685/16 10.0 2.352718 50.0 2301721.0 0.235272 Y
5 IC 280-678685/17 20.0 4.601839 50.0 2157605.0 0.230092 Y
6 ICIS 280-678685/18 100.0 25.97616 50.0 1872030.0 0.259762 Y
7 IC 280-678685/19 150.0 37.096356 50.0 2014927.0 0.247309 Y
8 IC 280-678685/20 200.0 52.784702 50.0 1912664.0 0.263924 Y
9 IC 280-678685/21 400.0 93.69668 50.0 2070734.0 0.234242 Y
RelResp = [0.2504]x
Concentration
0 100 200 300 400
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
12/27/2024
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Calibration / Chloroform
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3639
Error Coefficients
Relative Standard Deviation:7.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.201008 50.0 2384488.0 0.402015 Y
2 IC 280-678685/14 1.0 0.350088 50.0 2252863.0 0.350088 Y
3 IC 280-678685/15 2.0 0.733391 50.0 2309819.0 0.366695 Y
4 IC 280-678685/16 5.0 1.732095 50.0 2301721.0 0.346419 Y
5 IC 280-678685/17 10.0 3.126337 50.0 2157605.0 0.312634 Y
6 ICIS 280-678685/18 50.0 18.375347 50.0 1872030.0 0.367507 Y
7 IC 280-678685/19 75.0 27.377146 50.0 2014927.0 0.365029 Y
8 IC 280-678685/20 100.0 39.664024 50.0 1912664.0 0.39664 Y
9 IC 280-678685/21 200.0 73.65893 50.0 2070734.0 0.368295 Y
RelResp = [0.3639]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
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Page 303 of 428
Calibration / Dibromofluoromethane (Surr)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2541
Error Coefficients
Relative Standard Deviation:2.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 50.0 12.443866 50.0 2384488.0 0.248877 Y
2 IC 280-678685/14 50.0 12.218342 50.0 2252863.0 0.244367 Y
3 IC 280-678685/15 50.0 12.611378 50.0 2309819.0 0.252228 Y
4 IC 280-678685/16 50.0 12.475556 50.0 2301721.0 0.249511 Y
5 IC 280-678685/17 50.0 12.711849 50.0 2157605.0 0.254237 Y
6 ICIS 280-678685/18 50.0 12.863122 50.0 1872030.0 0.257262 Y
7 IC 280-678685/19 50.0 12.981885 50.0 2014927.0 0.259638 Y
8 IC 280-678685/20 50.0 12.975907 50.0 1912664.0 0.259518 Y
9 IC 280-678685/21 50.0 13.067009 50.0 2070734.0 0.26134 Y
RelResp = [0.2541]x
Concentration
0 10 20 30 40 50
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/17ICIS 280-678685/18IC 280-678685/19IC 280-678685/20IC 280-678685/21
12/27/2024
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Page 304 of 428
Calibration / 1,1,1-Trichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2967
Error Coefficients
Relative Standard Deviation:10.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.167499 50.0 2384488.0 0.334999 Y
2 IC 280-678685/14 1.0 0.268725 50.0 2252863.0 0.268725 Y
3 IC 280-678685/15 2.0 0.586648 50.0 2309819.0 0.293324 Y
4 IC 280-678685/16 5.0 1.36083 50.0 2301721.0 0.272166 Y
5 IC 280-678685/17 10.0 2.392097 50.0 2157605.0 0.23921 Y
6 ICIS 280-678685/18 50.0 15.112391 50.0 1872030.0 0.302248 Y
7 IC 280-678685/19 75.0 23.189823 50.0 2014927.0 0.309198 Y
8 IC 280-678685/20 100.0 33.506539 50.0 1912664.0 0.335065 Y
9 IC 280-678685/21 200.0 63.147295 50.0 2070734.0 0.315736 Y
RelResp = [0.2967]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
9:26:49 AM
Page 305 of 428
Calibration / Cyclohexane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3545
Error Coefficients
Relative Standard Deviation:11.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.21296 50.0 2384488.0 0.42592 Y
2 IC 280-678685/14 1.0 0.356857 50.0 2252863.0 0.356857 Y
3 IC 280-678685/15 2.0 0.696894 50.0 2309819.0 0.348447 Y
4 IC 280-678685/16 5.0 1.670467 50.0 2301721.0 0.334093 Y
5 IC 280-678685/17 10.0 2.796735 50.0 2157605.0 0.279674 Y
6 ICIS 280-678685/18 50.0 17.490639 50.0 1872030.0 0.349813 Y
7 IC 280-678685/19 75.0 26.755659 50.0 2014927.0 0.356742 Y
8 IC 280-678685/20 100.0 38.737515 50.0 1912664.0 0.387375 Y
9 IC 280-678685/21 200.0 70.271145 50.0 2070734.0 0.351356 Y
RelResp = [0.3545]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
12/27/2024
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Page 306 of 428
Calibration / 1,1-Dichloropropene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2916
Error Coefficients
Relative Standard Deviation:11.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.177208 50.0 2384488.0 0.354416 Y
2 IC 280-678685/14 1.0 0.273563 50.0 2252863.0 0.273563 Y
3 IC 280-678685/15 2.0 0.578985 50.0 2309819.0 0.289492 Y
4 IC 280-678685/16 5.0 1.393501 50.0 2301721.0 0.2787 Y
5 IC 280-678685/17 10.0 2.335831 50.0 2157605.0 0.233583 Y
6 ICIS 280-678685/18 50.0 14.52418 50.0 1872030.0 0.290484 Y
7 IC 280-678685/19 75.0 21.886277 50.0 2014927.0 0.291817 Y
8 IC 280-678685/20 100.0 31.973572 50.0 1912664.0 0.319736 Y
9 IC 280-678685/21 200.0 58.458064 50.0 2070734.0 0.29229 Y
RelResp = [0.2916]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
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Calibration / Carbon tetrachloride
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.1775
Slope:0.2432
Error Coefficients
Relative Standard Deviation:19.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.086161 50.0 2384488.0 0.172322 N
2 IC 280-678685/14 1.0 0.148211 50.0 2252863.0 0.148211 Y
3 IC 280-678685/15 2.0 0.352127 50.0 2309819.0 0.176064 Y
4 IC 280-678685/16 5.0 0.875236 50.0 2301721.0 0.175047 Y
5 IC 280-678685/17 10.0 1.579205 50.0 2157605.0 0.15792 Y
6 ICIS 280-678685/18 50.0 11.10511 50.0 1872030.0 0.222102 Y
7 IC 280-678685/19 75.0 17.649945 50.0 2014927.0 0.235333 Y
8 IC 280-678685/20 100.0 25.967002 50.0 1912664.0 0.25967 Y
9 IC 280-678685/21 200.0 48.642631 50.0 2070734.0 0.243213 Y
RelResp = [-0.1775] + [0.2432]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
IC 280-678685/21
Intercept = 0.730
12/27/2024
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Page 308 of 428
Calibration / Isobutyl alcohol
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.03867
Error Coefficients
Relative Standard Deviation:11.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 12.5 0.479264 50.0 2384488.0 0.038341 Y
2 IC 280-678685/14 25.0 0.750046 50.0 2252863.0 0.030002 Y
3 IC 280-678685/15 50.0 1.820705 50.0 2309819.0 0.036414 Y
4 IC 280-678685/16 125.0 4.763914 50.0 2301721.0 0.038111 Y
5 IC 280-678685/17 250.0 9.5936 50.0 2157605.0 0.038374 Y
6 ICIS 280-678685/18 1250.0 55.300075 50.0 1872030.0 0.04424 Y
7 IC 280-678685/19 1875.0 78.403858 50.0 2014927.0 0.041815 Y
8 IC 280-678685/20 2500.0 110.36881 50.0 1912664.0 0.044148 Y
9 IC 280-678685/21 5000.0 183.032562 50.0 2070734.0 0.036607 Y
RelResp = [0.03867]x
Concentration
0 1000 2000 3000 4000 5000
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
12/27/2024
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Page 309 of 428
Calibration / 1,2-Dichloroethane-d4 (Surr)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.338
Error Coefficients
Relative Standard Deviation:1.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 50.0 17.261169 50.0 2384488.0 0.345223 Y
2 IC 280-678685/14 50.0 16.992178 50.0 2252863.0 0.339844 Y
3 IC 280-678685/15 50.0 17.015554 50.0 2309819.0 0.340311 Y
4 IC 280-678685/16 50.0 16.908196 50.0 2301721.0 0.338164 Y
5 IC 280-678685/17 50.0 16.965895 50.0 2157605.0 0.339318 Y
6 ICIS 280-678685/18 50.0 16.597036 50.0 1872030.0 0.331941 Y
7 IC 280-678685/19 50.0 16.867658 50.0 2014927.0 0.337353 Y
8 IC 280-678685/20 50.0 16.90323 50.0 1912664.0 0.338065 Y
9 IC 280-678685/21 50.0 16.587138 50.0 2070734.0 0.331743 Y
RelResp = [0.338]x
Concentration
0 10 20 30 40 50
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13IC 280-678685/14IC 280-678685/15IC 280-678685/16IC 280-678685/17IC 280-678685/20
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9:26:49 AM
Page 310 of 428
Calibration / Benzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8332
Error Coefficients
Relative Standard Deviation:8.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.476811 50.0 2384488.0 0.953622 Y
2 IC 280-678685/14 1.0 0.852027 50.0 2252863.0 0.852027 Y
3 IC 280-678685/15 2.0 1.657836 50.0 2309819.0 0.828918 Y
4 IC 280-678685/16 5.0 3.930407 50.0 2301721.0 0.786081 Y
5 IC 280-678685/17 10.0 6.994144 50.0 2157605.0 0.699414 Y
6 ICIS 280-678685/18 50.0 41.137215 50.0 1872030.0 0.822744 Y
7 IC 280-678685/19 75.0 61.956165 50.0 2014927.0 0.826082 Y
8 IC 280-678685/20 100.0 90.407777 50.0 1912664.0 0.904078 Y
9 IC 280-678685/21 200.0 165.20555 50.0 2070734.0 0.826028 Y
RelResp = [0.8332]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
12/27/2024
9:26:49 AM
Page 311 of 428
Calibration / 1,2-Dichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3333
Error Coefficients
Relative Standard Deviation:12.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.21447 50.0 2384488.0 0.428939 Y
2 IC 280-678685/14 1.0 0.348379 50.0 2252863.0 0.348379 Y
3 IC 280-678685/15 2.0 0.65884 50.0 2309819.0 0.32942 Y
4 IC 280-678685/16 5.0 1.506981 50.0 2301721.0 0.301396 Y
5 IC 280-678685/17 10.0 2.885908 50.0 2157605.0 0.288591 Y
6 ICIS 280-678685/18 50.0 15.827684 50.0 1872030.0 0.316554 Y
7 IC 280-678685/19 75.0 23.954069 50.0 2014927.0 0.319388 Y
8 IC 280-678685/20 100.0 34.571885 50.0 1912664.0 0.345719 Y
9 IC 280-678685/21 200.0 64.324413 50.0 2070734.0 0.321622 Y
RelResp = [0.3333]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
12/27/2024
9:26:49 AM
Page 312 of 428
Calibration / n-Heptane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2743
Error Coefficients
Relative Standard Deviation:9.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.190628 50.0 2384488.0 0.381256 N
2 IC 280-678685/14 1.0 0.306543 50.0 2252863.0 0.306543 Y
3 IC 280-678685/15 2.0 0.533094 50.0 2309819.0 0.266547 Y
4 IC 280-678685/16 5.0 1.318904 50.0 2301721.0 0.263781 Y
5 IC 280-678685/17 10.0 2.20995 50.0 2157605.0 0.220995 Y
6 ICIS 280-678685/18 50.0 13.821226 50.0 1872030.0 0.276425 Y
7 IC 280-678685/19 75.0 21.089077 50.0 2014927.0 0.281188 Y
8 IC 280-678685/20 100.0 30.295049 50.0 1912664.0 0.30295 Y
9 IC 280-678685/21 200.0 55.168288 50.0 2070734.0 0.275841 Y
RelResp = [0.2743]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
9:26:49 AM
Page 313 of 428
Calibration / Trichloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.8278
Error Coefficients
Relative Standard Deviation:9.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.350416 50.0 554198.0 0.700833 Y
2 IC 280-678685/14 1.0 0.898886 50.0 537610.0 0.898886 Y
3 IC 280-678685/15 2.0 1.637627 50.0 550003.0 0.818814 Y
4 IC 280-678685/16 5.0 4.108662 50.0 544277.0 0.821732 Y
5 IC 280-678685/17 10.0 7.14364 50.0 510664.0 0.714364 Y
6 ICIS 280-678685/18 50.0 42.319488 50.0 468888.0 0.84639 Y
7 IC 280-678685/19 75.0 62.192578 50.0 532086.0 0.829234 Y
8 IC 280-678685/20 100.0 94.400299 50.0 491053.0 0.944003 Y
9 IC 280-678685/21 200.0 175.185691 50.0 535163.0 0.875928 Y
RelResp = [0.8278]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
9:26:49 AM
Page 314 of 428
Calibration / 2-Pentanone
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.572
Error Coefficients
Relative Standard Deviation:6.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 1.6 0.979518 50.0 2384488.0 0.612199 Y
2 IC 280-678685/14 3.2 1.812094 50.0 2252863.0 0.566279 Y
3 IC 280-678685/15 6.4 3.417324 50.0 2309819.0 0.533957 Y
4 IC 280-678685/16 16.0 8.570717 50.0 2301721.0 0.53567 Y
5 IC 280-678685/17 32.0 17.315612 50.0 2157605.0 0.541113 Y
6 ICIS 280-678685/18 160.0 97.749021 50.0 1872030.0 0.610931 Y
7 IC 280-678685/19 240.0 141.522621 50.0 2014927.0 0.589678 Y
8 IC 280-678685/20 320.0 199.153145 50.0 1912664.0 0.622354 Y
9 IC 280-678685/21 640.0 342.889381 50.0 2070734.0 0.535765 Y
RelResp = [0.572]x
Concentration
0 100 200 300 400 500 600 700
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
12/27/2024
9:26:49 AM
Page 315 of 428
Calibration / Methylcyclohexane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2818
Error Coefficients
Relative Standard Deviation:12.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.173475 50.0 2384488.0 0.346951 Y
2 IC 280-678685/14 1.0 0.29407 50.0 2252863.0 0.29407 Y
3 IC 280-678685/15 2.0 0.558269 50.0 2309819.0 0.279134 Y
4 IC 280-678685/16 5.0 1.308651 50.0 2301721.0 0.26173 Y
5 IC 280-678685/17 10.0 2.191759 50.0 2157605.0 0.219176 Y
6 ICIS 280-678685/18 50.0 13.828331 50.0 1872030.0 0.276567 Y
7 IC 280-678685/19 75.0 20.926118 50.0 2014927.0 0.279015 Y
8 IC 280-678685/20 100.0 30.413418 50.0 1912664.0 0.304134 Y
9 IC 280-678685/21 200.0 55.063736 50.0 2070734.0 0.275319 Y
RelResp = [0.2818]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
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Calibration / 1,2-Dichloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2184
Error Coefficients
Relative Standard Deviation:8.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.124597 50.0 2384488.0 0.249194 Y
2 IC 280-678685/14 1.0 0.210554 50.0 2252863.0 0.210554 Y
3 IC 280-678685/15 2.0 0.422566 50.0 2309819.0 0.211283 Y
4 IC 280-678685/16 5.0 1.001468 50.0 2301721.0 0.200294 Y
5 IC 280-678685/17 10.0 1.874718 50.0 2157605.0 0.187472 Y
6 ICIS 280-678685/18 50.0 10.918121 50.0 1872030.0 0.218362 Y
7 IC 280-678685/19 75.0 16.580675 50.0 2014927.0 0.221076 Y
8 IC 280-678685/20 100.0 24.22208 50.0 1912664.0 0.242221 Y
9 IC 280-678685/21 200.0 45.116031 50.0 2070734.0 0.22558 Y
RelResp = [0.2184]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
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Page 317 of 428
Calibration / 1,4-Dioxane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.006593
Error Coefficients
Relative Standard Deviation:12.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 10.0 0.100504 50.0 2384488.0 0.01005 N
2 IC 280-678685/14 20.0 0.078256 50.0 2252863.0 0.003913 N
3 IC 280-678685/15 40.0 0.219368 50.0 2309819.0 0.005484 Y
4 IC 280-678685/16 100.0 0.682967 50.0 2301721.0 0.00683 Y
5 IC 280-678685/17 200.0 1.340352 50.0 2157605.0 0.006702 Y
6 ICIS 280-678685/18 1000.0 7.192513 50.0 1872030.0 0.007193 Y
7 IC 280-678685/19 1500.0 10.520952 50.0 2014927.0 0.007014 Y
8 IC 280-678685/20 2000.0 15.135486 50.0 1912664.0 0.007568 Y
9 IC 280-678685/21 4000.0 21.457947 50.0 2070734.0 0.005364 Y
RelResp = [0.006593]x
Concentration
0 1000 2000 3000 4000
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
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Page 318 of 428
Calibration / Dibromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1496
Error Coefficients
Relative Standard Deviation:9.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.08614 50.0 2384488.0 0.17228 Y
2 IC 280-678685/14 1.0 0.149832 50.0 2252863.0 0.149832 Y
3 IC 280-678685/15 2.0 0.282793 50.0 2309819.0 0.141396 Y
4 IC 280-678685/16 5.0 0.670042 50.0 2301721.0 0.134008 Y
5 IC 280-678685/17 10.0 1.307584 50.0 2157605.0 0.130758 Y
6 ICIS 280-678685/18 50.0 7.327233 50.0 1872030.0 0.146545 Y
7 IC 280-678685/19 75.0 11.328053 50.0 2014927.0 0.151041 Y
8 IC 280-678685/20 100.0 16.56922 50.0 1912664.0 0.165692 Y
9 IC 280-678685/21 200.0 30.921572 50.0 2070734.0 0.154608 Y
RelResp = [0.1496]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
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Page 319 of 428
Calibration / Dichlorobromomethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.2514
Error Coefficients
Relative Standard Deviation:14.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.123968 50.0 2384488.0 0.247936 Y
2 IC 280-678685/14 1.0 0.22933 50.0 2252863.0 0.22933 Y
3 IC 280-678685/15 2.0 0.437112 50.0 2309819.0 0.218556 Y
4 IC 280-678685/16 5.0 1.056058 50.0 2301721.0 0.211212 Y
5 IC 280-678685/17 10.0 2.102841 50.0 2157605.0 0.210284 Y
6 ICIS 280-678685/18 50.0 13.003851 50.0 1872030.0 0.260077 Y
7 IC 280-678685/19 75.0 20.76713 50.0 2014927.0 0.276895 Y
8 IC 280-678685/20 100.0 31.00074 50.0 1912664.0 0.310007 Y
9 IC 280-678685/21 200.0 59.705158 50.0 2070734.0 0.298526 Y
RelResp = [0.2514]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
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Page 320 of 428
Calibration / 2-Chloroethyl vinyl ether
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.03661
Error Coefficients
Relative Standard Deviation:14.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.0 50.0 2384488.0 0.0 N
2 IC 280-678685/14 1.0 0.033335 50.0 2252863.0 0.033335 N
3 IC 280-678685/15 2.0 0.087388 50.0 2309819.0 0.043694 Y
4 IC 280-678685/16 5.0 0.177845 50.0 2301721.0 0.035569 Y
5 IC 280-678685/17 10.0 0.288491 50.0 2157605.0 0.028849 Y
6 ICIS 280-678685/18 50.0 1.629782 50.0 1872030.0 0.032596 Y
7 IC 280-678685/19 75.0 2.989314 50.0 2014927.0 0.039858 Y
8 IC 280-678685/20 100.0 3.911455 50.0 1912664.0 0.039115 Y
9 IC 280-678685/21 200.0 9.654572 50.0 2070734.0 0.048273 N
RelResp = [0.03661]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
9:26:49 AM
Page 321 of 428
Calibration / cis-1,3-Dichloropropene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.391
Error Coefficients
Relative Standard Deviation:11.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.684773 50.0 554198.0 1.369547 Y
2 IC 280-678685/14 1.0 1.262067 50.0 537610.0 1.262067 Y
3 IC 280-678685/15 2.0 2.560622 50.0 550003.0 1.280311 Y
4 IC 280-678685/16 5.0 6.27052 50.0 544277.0 1.254104 Y
5 IC 280-678685/17 10.0 12.241415 50.0 510664.0 1.224142 Y
6 ICIS 280-678685/18 50.0 72.482661 50.0 468888.0 1.449653 Y
7 IC 280-678685/19 75.0 108.807223 50.0 532086.0 1.450763 Y
8 IC 280-678685/20 100.0 165.97689 50.0 491053.0 1.659769 Y
9 IC 280-678685/21 200.0 314.602093 50.0 535163.0 1.57301 Y
RelResp = [1.391]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
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Page 322 of 428
Calibration / 4-Methyl-2-pentanone (MIBK)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5513
Error Coefficients
Relative Standard Deviation:6.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 2.0 1.175514 50.0 2384488.0 0.587757 Y
2 IC 280-678685/14 4.0 2.191345 50.0 2252863.0 0.547836 Y
3 IC 280-678685/15 8.0 4.084866 50.0 2309819.0 0.510608 Y
4 IC 280-678685/16 20.0 10.145061 50.0 2301721.0 0.507253 Y
5 IC 280-678685/17 40.0 20.799057 50.0 2157605.0 0.519976 Y
6 ICIS 280-678685/18 200.0 116.222577 50.0 1872030.0 0.581113 Y
7 IC 280-678685/19 300.0 168.47258 50.0 2014927.0 0.561575 Y
8 IC 280-678685/20 400.0 237.681762 50.0 1912664.0 0.594204 Y
9 IC 280-678685/21 800.0 396.260964 50.0 2070734.0 0.495326 N
RelResp = [0.5513]x
Concentration
0 100 200 300 400 500 600 700 800
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
12/27/2024
9:26:49 AM
Page 323 of 428
Calibration / Toluene-d8 (Surr)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:4.269
Error Coefficients
Relative Standard Deviation:3.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 50.0 217.984908 50.0 554198.0 4.359698 Y
2 IC 280-678685/14 50.0 218.285281 50.0 537610.0 4.365706 Y
3 IC 280-678685/15 50.0 217.779994 50.0 550003.0 4.3556 Y
4 IC 280-678685/16 50.0 220.249524 50.0 544277.0 4.40499 Y
5 IC 280-678685/17 50.0 219.243279 50.0 510664.0 4.384866 Y
6 ICIS 280-678685/18 50.0 211.434927 50.0 468888.0 4.228699 Y
7 IC 280-678685/19 50.0 202.102856 50.0 532086.0 4.042057 Y
8 IC 280-678685/20 50.0 207.630439 50.0 491053.0 4.152609 Y
9 IC 280-678685/21 50.0 206.130469 50.0 535163.0 4.122609 Y
RelResp = [4.269]x
Concentration
0 10 20 30 40 50
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13IC 280-678685/14IC 280-678685/15IC 280-678685/16IC 280-678685/17
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9:26:49 AM
Page 324 of 428
Calibration / Toluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9077
Error Coefficients
Relative Standard Deviation:9.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.510718 50.0 2384488.0 1.021435 Y
2 IC 280-678685/14 1.0 0.906979 50.0 2252863.0 0.906979 Y
3 IC 280-678685/15 2.0 1.761891 50.0 2309819.0 0.880946 Y
4 IC 280-678685/16 5.0 4.254903 50.0 2301721.0 0.850981 Y
5 IC 280-678685/17 10.0 7.48142 50.0 2157605.0 0.748142 Y
6 ICIS 280-678685/18 50.0 45.651672 50.0 1872030.0 0.913033 Y
7 IC 280-678685/19 75.0 69.011359 50.0 2014927.0 0.920151 Y
8 IC 280-678685/20 100.0 101.214772 50.0 1912664.0 1.012148 Y
9 IC 280-678685/21 200.0 183.011121 50.0 2070734.0 0.915056 Y
RelResp = [0.9077]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
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Page 325 of 428
Calibration / trans-1,3-Dichloropropene
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.2424
Slope:0.3766
Error Coefficients
Relative Standard Deviation:20.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.143196 50.0 2384488.0 0.286393 N
2 IC 280-678685/14 1.0 0.282862 50.0 2252863.0 0.282862 Y
3 IC 280-678685/15 2.0 0.527682 50.0 2309819.0 0.263841 Y
4 IC 280-678685/16 5.0 1.356181 50.0 2301721.0 0.271236 Y
5 IC 280-678685/17 10.0 2.667078 50.0 2157605.0 0.266708 Y
6 ICIS 280-678685/18 50.0 17.038856 50.0 1872030.0 0.340777 Y
7 IC 280-678685/19 75.0 26.872462 50.0 2014927.0 0.358299 Y
8 IC 280-678685/20 100.0 40.072433 50.0 1912664.0 0.400724 Y
9 IC 280-678685/21 200.0 76.080414 50.0 2070734.0 0.380402 Y
RelResp = [-0.2424] + [0.3766]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
IC 280-678685/21
Intercept = 0.644
12/27/2024
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Page 326 of 428
Calibration / Ethyl methacrylate
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.618
Error Coefficients
Relative Standard Deviation:8.2
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.807654 50.0 554198.0 1.615307 Y
2 IC 280-678685/14 1.0 1.496717 50.0 537610.0 1.496717 Y
3 IC 280-678685/15 2.0 2.988256 50.0 550003.0 1.494128 Y
4 IC 280-678685/16 5.0 7.395223 50.0 544277.0 1.479045 Y
5 IC 280-678685/17 10.0 15.2241 50.0 510664.0 1.52241 Y
6 ICIS 280-678685/18 50.0 86.320187 50.0 468888.0 1.726404 Y
7 IC 280-678685/19 75.0 123.97977 50.0 532086.0 1.653064 Y
8 IC 280-678685/20 100.0 186.02157 50.0 491053.0 1.860216 Y
9 IC 280-678685/21 200.0 343.098738 50.0 535163.0 1.715494 Y
RelResp = [1.618]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
9:26:49 AM
Page 327 of 428
Calibration / 1,1,2-Trichloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.214
Error Coefficients
Relative Standard Deviation:9.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.109961 50.0 2384488.0 0.219921 Y
2 IC 280-678685/14 1.0 0.195396 50.0 2252863.0 0.195396 Y
3 IC 280-678685/15 2.0 0.405421 50.0 2309819.0 0.202711 Y
4 IC 280-678685/16 5.0 0.990672 50.0 2301721.0 0.198134 Y
5 IC 280-678685/17 10.0 1.837222 50.0 2157605.0 0.183722 Y
6 ICIS 280-678685/18 50.0 10.927095 50.0 1872030.0 0.218542 Y
7 IC 280-678685/19 75.0 16.984635 50.0 2014927.0 0.226462 Y
8 IC 280-678685/20 100.0 24.741382 50.0 1912664.0 0.247414 Y
9 IC 280-678685/21 200.0 46.752142 50.0 2070734.0 0.233761 Y
RelResp = [0.214]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
9:26:49 AM
Page 328 of 428
Calibration / Tetrachloroethene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6355
Error Coefficients
Relative Standard Deviation:9.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.363769 50.0 554198.0 0.727538 Y
2 IC 280-678685/14 1.0 0.66963 50.0 537610.0 0.66963 Y
3 IC 280-678685/15 2.0 1.310629 50.0 550003.0 0.655315 Y
4 IC 280-678685/16 5.0 2.951714 50.0 544277.0 0.590343 Y
5 IC 280-678685/17 10.0 5.103062 50.0 510664.0 0.510306 Y
6 ICIS 280-678685/18 50.0 30.892452 50.0 468888.0 0.617849 Y
7 IC 280-678685/19 75.0 46.11435 50.0 532086.0 0.614858 Y
8 IC 280-678685/20 100.0 69.423158 50.0 491053.0 0.694232 Y
9 IC 280-678685/21 200.0 127.907572 50.0 535163.0 0.639538 Y
RelResp = [0.6355]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
IC 280-678685/21
12/27/2024
9:26:49 AM
Page 329 of 428
Calibration / 1,3-Dichloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.593
Error Coefficients
Relative Standard Deviation:8.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.941992 50.0 554198.0 1.883984 Y
2 IC 280-678685/14 1.0 1.599766 50.0 537610.0 1.599766 Y
3 IC 280-678685/15 2.0 2.958166 50.0 550003.0 1.479083 Y
4 IC 280-678685/16 5.0 7.40836 50.0 544277.0 1.481672 Y
5 IC 280-678685/17 10.0 14.87808 50.0 510664.0 1.487808 Y
6 ICIS 280-678685/18 50.0 78.978669 50.0 468888.0 1.579573 Y
7 IC 280-678685/19 75.0 114.556951 50.0 532086.0 1.527426 Y
8 IC 280-678685/20 100.0 172.070937 50.0 491053.0 1.720709 Y
9 IC 280-678685/21 200.0 315.696993 50.0 535163.0 1.578485 Y
RelResp = [1.593]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
12/27/2024
9:26:49 AM
Page 330 of 428
Calibration / 2-Hexanone
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.923
Error Coefficients
Relative Standard Deviation:8.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 2.0 4.489731 50.0 554198.0 2.244866 Y
2 IC 280-678685/14 4.0 7.742416 50.0 537610.0 1.935604 Y
3 IC 280-678685/15 8.0 14.68092 50.0 550003.0 1.835115 Y
4 IC 280-678685/16 20.0 36.682792 50.0 544277.0 1.83414 Y
5 IC 280-678685/17 40.0 76.701412 50.0 510664.0 1.917535 Y
6 ICIS 280-678685/18 200.0 405.701042 50.0 468888.0 2.028505 Y
7 IC 280-678685/19 300.0 553.838665 50.0 532086.0 1.846129 Y
8 IC 280-678685/20 400.0 796.034542 50.0 491053.0 1.990086 Y
9 IC 280-678685/21 800.0 1338.859376 50.0 535163.0 1.673574 Y
RelResp = [1.923]x
Concentration
0 100 200 300 400 500 600 700 800
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
12/27/2024
9:26:49 AM
Page 331 of 428
Calibration / Chlorodibromomethane
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.6062
Slope:0.8667
Error Coefficients
Relative Standard Deviation:20.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.316674 50.0 554198.0 0.633348 N
2 IC 280-678685/14 1.0 0.560908 50.0 537610.0 0.560908 Y
3 IC 280-678685/15 2.0 1.217812 50.0 550003.0 0.608906 Y
4 IC 280-678685/16 5.0 2.977436 50.0 544277.0 0.595487 Y
5 IC 280-678685/17 10.0 6.312761 50.0 510664.0 0.631276 Y
6 ICIS 280-678685/18 50.0 39.604127 50.0 468888.0 0.792083 Y
7 IC 280-678685/19 75.0 61.201573 50.0 532086.0 0.816021 Y
8 IC 280-678685/20 100.0 94.494993 50.0 491053.0 0.94495 Y
9 IC 280-678685/21 200.0 185.263275 50.0 535163.0 0.926316 N
RelResp = [-0.6062] + [0.8667]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
IC 280-678685/21
Intercept = 0.699
12/27/2024
9:26:49 AM
Page 332 of 428
Calibration / Ethylene Dibromide
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9555
Error Coefficients
Relative Standard Deviation:10.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.554585 50.0 554198.0 1.10917 Y
2 IC 280-678685/14 1.0 0.875821 50.0 537610.0 0.875821 Y
3 IC 280-678685/15 2.0 1.761172 50.0 550003.0 0.880586 Y
4 IC 280-678685/16 5.0 4.280725 50.0 544277.0 0.856145 Y
5 IC 280-678685/17 10.0 8.567962 50.0 510664.0 0.856796 Y
6 ICIS 280-678685/18 50.0 48.83309 50.0 468888.0 0.976662 Y
7 IC 280-678685/19 75.0 71.757949 50.0 532086.0 0.956773 Y
8 IC 280-678685/20 100.0 107.796103 50.0 491053.0 1.077961 Y
9 IC 280-678685/21 200.0 201.952116 50.0 535163.0 1.009761 Y
RelResp = [0.9555]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
9:26:49 AM
Page 333 of 428
Calibration / 1-Chlorohexane
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0.1001
Slope:1.21
Error Coefficients
Relative Standard Deviation:15.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.4 1.091938 50.0 554198.0 2.729846 N
2 IC 280-678685/14 0.8 1.337401 50.0 537610.0 1.671751 Y
3 IC 280-678685/15 1.6 2.097443 50.0 550003.0 1.310902 Y
4 IC 280-678685/16 4.0 4.574601 50.0 544277.0 1.14365 Y
5 IC 280-678685/17 8.0 7.522167 50.0 510664.0 0.940271 Y
6 ICIS 280-678685/18 40.0 46.755835 50.0 468888.0 1.168896 Y
7 IC 280-678685/19 60.0 68.812466 50.0 532086.0 1.146874 Y
8 IC 280-678685/20 80.0 105.755591 50.0 491053.0 1.321945 Y
9 IC 280-678685/21 160.0 192.631124 50.0 535163.0 1.203945 Y
RelResp = [0.1001] + [1.21]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
Intercept = -0.0828
12/27/2024
9:26:49 AM
Page 334 of 428
Calibration / Chlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.379
Error Coefficients
Relative Standard Deviation:8.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 1.355472 50.0 554198.0 2.710944 Y
2 IC 280-678685/14 1.0 2.593423 50.0 537610.0 2.593423 Y
3 IC 280-678685/15 2.0 4.652793 50.0 550003.0 2.326396 Y
4 IC 280-678685/16 5.0 11.108498 50.0 544277.0 2.2217 Y
5 IC 280-678685/17 10.0 20.25882 50.0 510664.0 2.025882 Y
6 ICIS 280-678685/18 50.0 117.892439 50.0 468888.0 2.357849 Y
7 IC 280-678685/19 75.0 170.058036 50.0 532086.0 2.26744 Y
8 IC 280-678685/20 100.0 256.61507 50.0 491053.0 2.566151 Y
9 IC 280-678685/21 200.0 467.463932 50.0 535163.0 2.33732 Y
RelResp = [2.379]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
12/27/2024
9:26:49 AM
Page 335 of 428
Calibration / 1,1,1,2-Tetrachloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7136
Error Coefficients
Relative Standard Deviation:13.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.370535 50.0 554198.0 0.741071 Y
2 IC 280-678685/14 1.0 0.622756 50.0 537610.0 0.622756 Y
3 IC 280-678685/15 2.0 1.255448 50.0 550003.0 0.627724 Y
4 IC 280-678685/16 5.0 3.174395 50.0 544277.0 0.634879 Y
5 IC 280-678685/17 10.0 6.041056 50.0 510664.0 0.604106 Y
6 ICIS 280-678685/18 50.0 37.628602 50.0 468888.0 0.752572 Y
7 IC 280-678685/19 75.0 56.780577 50.0 532086.0 0.757074 Y
8 IC 280-678685/20 100.0 86.603686 50.0 491053.0 0.866037 Y
9 IC 280-678685/21 200.0 163.195045 50.0 535163.0 0.815975 Y
RelResp = [0.7136]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
9:26:49 AM
Page 336 of 428
Calibration / Ethylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.243
Error Coefficients
Relative Standard Deviation:10.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.726455 50.0 554198.0 1.45291 Y
2 IC 280-678685/14 1.0 1.252581 50.0 537610.0 1.252581 Y
3 IC 280-678685/15 2.0 2.23317 50.0 550003.0 1.116585 Y
4 IC 280-678685/16 5.0 6.006041 50.0 544277.0 1.201208 Y
5 IC 280-678685/17 10.0 10.442091 50.0 510664.0 1.044209 Y
6 ICIS 280-678685/18 50.0 63.511755 50.0 468888.0 1.270235 Y
7 IC 280-678685/19 75.0 91.654357 50.0 532086.0 1.222058 Y
8 IC 280-678685/20 100.0 139.125105 50.0 491053.0 1.391251 Y
9 IC 280-678685/21 200.0 247.937077 50.0 535163.0 1.239685 Y
RelResp = [1.243]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
12/27/2024
9:26:49 AM
Page 337 of 428
Calibration / m-Xylene & p-Xylene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.565
Error Coefficients
Relative Standard Deviation:11.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.983042 50.0 554198.0 1.966084 Y
2 IC 280-678685/14 1.0 1.621808 50.0 537610.0 1.621808 Y
3 IC 280-678685/15 2.0 3.003347 50.0 550003.0 1.501674 Y
4 IC 280-678685/16 5.0 7.464765 50.0 544277.0 1.492953 Y
5 IC 280-678685/17 10.0 13.078658 50.0 510664.0 1.307866 Y
6 ICIS 280-678685/18 50.0 77.93119 50.0 468888.0 1.558624 Y
7 IC 280-678685/19 75.0 109.656898 50.0 532086.0 1.462092 Y
8 IC 280-678685/20 100.0 169.05334 50.0 491053.0 1.690533 Y
9 IC 280-678685/21 200.0 297.420319 50.0 535163.0 1.487102 Y
RelResp = [1.565]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
12/27/2024
9:26:49 AM
Page 338 of 428
Calibration / o-Xylene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.531
Error Coefficients
Relative Standard Deviation:9.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.891919 50.0 554198.0 1.783839 Y
2 IC 280-678685/14 1.0 1.608229 50.0 537610.0 1.608229 Y
3 IC 280-678685/15 2.0 2.731621 50.0 550003.0 1.365811 Y
4 IC 280-678685/16 5.0 7.331928 50.0 544277.0 1.466386 Y
5 IC 280-678685/17 10.0 13.265474 50.0 510664.0 1.326547 Y
6 ICIS 280-678685/18 50.0 79.118361 50.0 468888.0 1.582367 Y
7 IC 280-678685/19 75.0 109.803302 50.0 532086.0 1.464044 Y
8 IC 280-678685/20 100.0 168.441594 50.0 491053.0 1.684416 Y
9 IC 280-678685/21 200.0 300.243664 50.0 535163.0 1.501218 Y
RelResp = [1.531]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
12/27/2024
9:26:49 AM
Page 339 of 428
Calibration / Styrene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.539
Error Coefficients
Relative Standard Deviation:8.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 1.403199 50.0 554198.0 2.806398 Y
2 IC 280-678685/14 1.0 2.511021 50.0 537610.0 2.511021 Y
3 IC 280-678685/15 2.0 4.670702 50.0 550003.0 2.335351 Y
4 IC 280-678685/16 5.0 11.914797 50.0 544277.0 2.382959 Y
5 IC 280-678685/17 10.0 21.999397 50.0 510664.0 2.19994 Y
6 ICIS 280-678685/18 50.0 134.324402 50.0 468888.0 2.686488 Y
7 IC 280-678685/19 75.0 190.399108 50.0 532086.0 2.538655 Y
8 IC 280-678685/20 100.0 285.638516 50.0 491053.0 2.856385 Y
9 IC 280-678685/21 200.0 506.613032 50.0 535163.0 2.533065 Y
RelResp = [2.539]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
12/27/2024
9:26:49 AM
Page 340 of 428
Calibration / Bromoform
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-1.147
Slope:0.6839
Error Coefficients
Relative Standard Deviation:22.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.0 50.0 554198.0 0.0 N
2 IC 280-678685/14 1.0 0.367088 50.0 537610.0 0.367088 N
3 IC 280-678685/15 2.0 0.77245 50.0 550003.0 0.386225 Y
4 IC 280-678685/16 5.0 2.006607 50.0 544277.0 0.401321 Y
5 IC 280-678685/17 10.0 4.202372 50.0 510664.0 0.420237 Y
6 ICIS 280-678685/18 50.0 28.759107 50.0 468888.0 0.575182 Y
7 IC 280-678685/19 75.0 45.71573 50.0 532086.0 0.609543 Y
8 IC 280-678685/20 100.0 71.590745 50.0 491053.0 0.715907 Y
9 IC 280-678685/21 200.0 141.200999 50.0 535163.0 0.706005 Y
RelResp = [-1.147] + [0.6839]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
IC 280-678685/21
Intercept = 1.68
12/27/2024
9:26:49 AM
Page 341 of 428
Calibration / Isopropylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.258
Error Coefficients
Relative Standard Deviation:10.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 1.262089 50.0 892330.0 2.524178 Y
2 IC 280-678685/14 1.0 2.220624 50.0 891281.0 2.220624 Y
3 IC 280-678685/15 2.0 4.115267 50.0 895835.0 2.057633 Y
4 IC 280-678685/16 5.0 10.831952 50.0 876998.0 2.16639 Y
5 IC 280-678685/17 10.0 18.008623 50.0 854263.0 1.800862 Y
6 ICIS 280-678685/18 50.0 114.545299 50.0 763501.0 2.290906 Y
7 IC 280-678685/19 75.0 169.584186 50.0 835230.0 2.261122 Y
8 IC 280-678685/20 100.0 262.836308 50.0 753550.0 2.628363 Y
9 IC 280-678685/21 200.0 474.43161 50.0 798527.0 2.372158 Y
RelResp = [2.258]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
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Calibration / Cyclohexanone
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.1695
Error Coefficients
Relative Standard Deviation:14.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 15.0 3.307302 50.0 554198.0 0.220487 Y
2 IC 280-678685/14 30.0 4.716616 50.0 537610.0 0.157221 Y
3 IC 280-678685/15 60.0 8.970042 50.0 550003.0 0.149501 Y
4 IC 280-678685/16 150.0 24.725921 50.0 544277.0 0.164839 Y
5 IC 280-678685/17 300.0 51.209112 50.0 510664.0 0.170697 Y
6 ICIS 280-678685/18 1500.0 271.704757 50.0 468888.0 0.181137 Y
7 IC 280-678685/19 2250.0 365.252234 50.0 532086.0 0.162334 Y
8 IC 280-678685/20 3000.0 545.058578 50.0 491053.0 0.181686 Y
9 IC 280-678685/21 6000.0 827.31579 50.0 535163.0 0.137886 Y
RelResp = [0.1695]x
Concentration
0 1000 2000 3000 4000 5000 6000
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
12/27/2024
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Page 343 of 428
Calibration / 4-Bromofluorobenzene (Surr)
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.023
Error Coefficients
Relative Standard Deviation:1.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 50.0 51.513173 50.0 892330.0 1.030263 Y
2 IC 280-678685/14 50.0 50.993346 50.0 891281.0 1.019867 Y
3 IC 280-678685/15 50.0 50.25239 50.0 895835.0 1.005048 Y
4 IC 280-678685/16 50.0 50.939512 50.0 876998.0 1.01879 Y
5 IC 280-678685/17 50.0 49.503724 50.0 854263.0 0.990074 Y
6 ICIS 280-678685/18 50.0 50.730778 50.0 763501.0 1.014616 Y
7 IC 280-678685/19 50.0 51.749458 50.0 835230.0 1.034989 Y
8 IC 280-678685/20 50.0 51.776657 50.0 753550.0 1.035533 Y
9 IC 280-678685/21 50.0 52.735286 50.0 798527.0 1.054706 Y
RelResp = [1.023]x
Concentration
0 10 20 30 40 50
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13IC 280-678685/19IC 280-678685/20IC 280-678685/21
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Page 344 of 428
Calibration / 1,1,2,2-Tetrachloroethane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.9763
Error Coefficients
Relative Standard Deviation:9.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.536965 50.0 892330.0 1.07393 Y
2 IC 280-678685/14 1.0 0.920753 50.0 891281.0 0.920753 Y
3 IC 280-678685/15 2.0 1.735141 50.0 895835.0 0.86757 Y
4 IC 280-678685/16 5.0 4.501436 50.0 876998.0 0.900287 Y
5 IC 280-678685/17 10.0 8.534725 50.0 854263.0 0.853473 Y
6 ICIS 280-678685/18 50.0 49.971185 50.0 763501.0 0.999424 Y
7 IC 280-678685/19 75.0 74.326174 50.0 835230.0 0.991016 Y
8 IC 280-678685/20 100.0 112.343706 50.0 753550.0 1.123437 Y
9 IC 280-678685/21 200.0 211.377887 50.0 798527.0 1.056889 Y
RelResp = [0.9763]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
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Page 345 of 428
Calibration / trans-1,4-Dichloro-2-butene
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.4361
Slope:0.3624
Error Coefficients
Relative Standard Deviation:25.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.090998 50.0 892330.0 0.181995 N
2 IC 280-678685/14 1.0 0.101034 50.0 891281.0 0.101034 Y
3 IC 280-678685/15 2.0 0.350064 50.0 895835.0 0.175032 Y
4 IC 280-678685/16 5.0 1.00023 50.0 876998.0 0.200046 Y
5 IC 280-678685/17 10.0 2.11422 50.0 854263.0 0.211422 Y
6 ICIS 280-678685/18 50.0 15.785441 50.0 763501.0 0.315709 Y
7 IC 280-678685/19 75.0 24.884882 50.0 835230.0 0.331798 Y
8 IC 280-678685/20 100.0 38.802933 50.0 753550.0 0.388029 Y
9 IC 280-678685/21 200.0 74.019789 50.0 798527.0 0.370099 Y
RelResp = [-0.4361] + [0.3624]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
IC 280-678685/21
Intercept = 1.20
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Page 346 of 428
Calibration / Bromobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5938
Error Coefficients
Relative Standard Deviation:8.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.311096 50.0 892330.0 0.622191 Y
2 IC 280-678685/14 1.0 0.59134 50.0 891281.0 0.59134 Y
3 IC 280-678685/15 2.0 1.163998 50.0 895835.0 0.581999 Y
4 IC 280-678685/16 5.0 2.790542 50.0 876998.0 0.558108 Y
5 IC 280-678685/17 10.0 4.972122 50.0 854263.0 0.497212 Y
6 ICIS 280-678685/18 50.0 29.795835 50.0 763501.0 0.595917 Y
7 IC 280-678685/19 75.0 44.372927 50.0 835230.0 0.591639 Y
8 IC 280-678685/20 100.0 67.943468 50.0 753550.0 0.679435 Y
9 IC 280-678685/21 200.0 125.299833 50.0 798527.0 0.626499 Y
RelResp = [0.5938]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
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Page 347 of 428
Calibration / 1,2,3-Trichloropropane
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3513
Error Coefficients
Relative Standard Deviation:10.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.204353 50.0 892330.0 0.408705 Y
2 IC 280-678685/14 1.0 0.333509 50.0 891281.0 0.333509 Y
3 IC 280-678685/15 2.0 0.603738 50.0 895835.0 0.301869 Y
4 IC 280-678685/16 5.0 1.678339 50.0 876998.0 0.335668 Y
5 IC 280-678685/17 10.0 3.150728 50.0 854263.0 0.315073 Y
6 ICIS 280-678685/18 50.0 18.078496 50.0 763501.0 0.36157 Y
7 IC 280-678685/19 75.0 25.962669 50.0 835230.0 0.346169 Y
8 IC 280-678685/20 100.0 39.676664 50.0 753550.0 0.396767 Y
9 IC 280-678685/21 200.0 72.398992 50.0 798527.0 0.361995 Y
RelResp = [0.3513]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
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Page 348 of 428
Calibration / N-Propylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.6449
Error Coefficients
Relative Standard Deviation:12.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.398395 50.0 892330.0 0.79679 Y
2 IC 280-678685/14 1.0 0.659332 50.0 891281.0 0.659332 Y
3 IC 280-678685/15 2.0 1.191402 50.0 895835.0 0.595701 Y
4 IC 280-678685/16 5.0 3.084044 50.0 876998.0 0.616809 Y
5 IC 280-678685/17 10.0 5.044875 50.0 854263.0 0.504487 Y
6 ICIS 280-678685/18 50.0 32.238203 50.0 763501.0 0.644764 Y
7 IC 280-678685/19 75.0 46.409552 50.0 835230.0 0.618794 Y
8 IC 280-678685/20 100.0 72.312322 50.0 753550.0 0.723123 Y
9 IC 280-678685/21 200.0 128.946172 50.0 798527.0 0.644731 Y
RelResp = [0.6449]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
12/27/2024
9:26:49 AM
Page 349 of 428
Calibration / 2-Chlorotoluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5685
Error Coefficients
Relative Standard Deviation:10.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.335246 50.0 892330.0 0.670492 Y
2 IC 280-678685/14 1.0 0.619109 50.0 891281.0 0.619109 Y
3 IC 280-678685/15 2.0 1.066491 50.0 895835.0 0.533246 Y
4 IC 280-678685/16 5.0 2.760896 50.0 876998.0 0.552179 Y
5 IC 280-678685/17 10.0 4.600866 50.0 854263.0 0.460087 Y
6 ICIS 280-678685/18 50.0 27.83166 50.0 763501.0 0.556633 Y
7 IC 280-678685/19 75.0 40.079439 50.0 835230.0 0.534393 Y
8 IC 280-678685/20 100.0 62.178754 50.0 753550.0 0.621788 Y
9 IC 280-678685/21 200.0 113.627529 50.0 798527.0 0.568138 Y
RelResp = [0.5685]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
12/27/2024
9:26:49 AM
Page 350 of 428
Calibration / 1,3,5-Trimethylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.999
Error Coefficients
Relative Standard Deviation:10.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 1.183026 50.0 892330.0 2.366053 Y
2 IC 280-678685/14 1.0 2.012833 50.0 891281.0 2.012833 Y
3 IC 280-678685/15 2.0 3.912551 50.0 895835.0 1.956275 Y
4 IC 280-678685/16 5.0 9.670604 50.0 876998.0 1.934121 Y
5 IC 280-678685/17 10.0 16.80829 50.0 854263.0 1.680829 Y
6 ICIS 280-678685/18 50.0 101.549048 50.0 763501.0 2.030981 Y
7 IC 280-678685/19 75.0 137.576177 50.0 835230.0 1.834349 Y
8 IC 280-678685/20 100.0 221.837967 50.0 753550.0 2.21838 Y
9 IC 280-678685/21 200.0 391.031675 50.0 798527.0 1.955158 Y
RelResp = [1.999]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
12/27/2024
9:26:49 AM
Page 351 of 428
Calibration / 4-Chlorotoluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.5922
Error Coefficients
Relative Standard Deviation:11.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.369482 50.0 892330.0 0.738964 Y
2 IC 280-678685/14 1.0 0.584159 50.0 891281.0 0.584159 Y
3 IC 280-678685/15 2.0 1.122584 50.0 895835.0 0.561292 Y
4 IC 280-678685/16 5.0 2.910554 50.0 876998.0 0.582111 Y
5 IC 280-678685/17 10.0 5.002558 50.0 854263.0 0.500256 Y
6 ICIS 280-678685/18 50.0 28.818299 50.0 763501.0 0.576366 Y
7 IC 280-678685/19 75.0 41.895765 50.0 835230.0 0.55861 Y
8 IC 280-678685/20 100.0 64.789729 50.0 753550.0 0.647897 Y
9 IC 280-678685/21 200.0 116.062387 50.0 798527.0 0.580312 Y
RelResp = [0.5922]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
1.2
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
12/27/2024
9:26:49 AM
Page 352 of 428
Calibration / tert-Butylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.779
Error Coefficients
Relative Standard Deviation:9.7
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 1.012126 50.0 892330.0 2.024251 Y
2 IC 280-678685/14 1.0 1.815028 50.0 891281.0 1.815028 Y
3 IC 280-678685/15 2.0 3.417705 50.0 895835.0 1.708853 Y
4 IC 280-678685/16 5.0 8.64295 50.0 876998.0 1.72859 Y
5 IC 280-678685/17 10.0 14.398142 50.0 854263.0 1.439814 Y
6 ICIS 280-678685/18 50.0 89.113832 50.0 763501.0 1.782277 Y
7 IC 280-678685/19 75.0 129.488045 50.0 835230.0 1.726507 Y
8 IC 280-678685/20 100.0 200.336408 50.0 753550.0 2.003364 Y
9 IC 280-678685/21 200.0 357.269072 50.0 798527.0 1.786345 Y
RelResp = [1.779]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
9:26:49 AM
Page 353 of 428
Calibration / 1,2,4-Trimethylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.059
Error Coefficients
Relative Standard Deviation:10.3
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 1.233064 50.0 892330.0 2.466128 Y
2 IC 280-678685/14 1.0 1.986411 50.0 891281.0 1.986411 Y
3 IC 280-678685/15 2.0 3.922542 50.0 895835.0 1.961271 Y
4 IC 280-678685/16 5.0 10.058803 50.0 876998.0 2.011761 Y
5 IC 280-678685/17 10.0 17.726976 50.0 854263.0 1.772698 Y
6 ICIS 280-678685/18 50.0 105.236666 50.0 763501.0 2.104733 Y
7 IC 280-678685/19 75.0 140.89646 50.0 835230.0 1.878619 Y
8 IC 280-678685/20 100.0 230.104373 50.0 753550.0 2.301044 Y
9 IC 280-678685/21 200.0 410.52682 50.0 798527.0 2.052634 Y
RelResp = [2.059]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
12/27/2024
9:26:49 AM
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Calibration / sec-Butylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.509
Error Coefficients
Relative Standard Deviation:10.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.295911 50.0 892330.0 0.591821 Y
2 IC 280-678685/14 1.0 0.491596 50.0 891281.0 0.491596 Y
3 IC 280-678685/15 2.0 0.964519 50.0 895835.0 0.48226 Y
4 IC 280-678685/16 5.0 2.489515 50.0 876998.0 0.497903 Y
5 IC 280-678685/17 10.0 4.170554 50.0 854263.0 0.417055 Y
6 ICIS 280-678685/18 50.0 25.73808 50.0 763501.0 0.514762 Y
7 IC 280-678685/19 75.0 37.480335 50.0 835230.0 0.499738 Y
8 IC 280-678685/20 100.0 57.431889 50.0 753550.0 0.574319 Y
9 IC 280-678685/21 200.0 102.386143 50.0 798527.0 0.511931 Y
RelResp = [0.509]x
Concentration
0 100 200
0.0
0.2
0.4
0.6
0.8
1.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
9:26:49 AM
Page 355 of 428
Calibration / 1,3-Dichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.158
Error Coefficients
Relative Standard Deviation:11.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.710836 50.0 892330.0 1.421671 Y
2 IC 280-678685/14 1.0 1.156706 50.0 891281.0 1.156706 Y
3 IC 280-678685/15 2.0 2.219549 50.0 895835.0 1.109775 Y
4 IC 280-678685/16 5.0 5.472247 50.0 876998.0 1.094449 Y
5 IC 280-678685/17 10.0 9.658091 50.0 854263.0 0.965809 Y
6 ICIS 280-678685/18 50.0 56.497437 50.0 763501.0 1.129949 Y
7 IC 280-678685/19 75.0 83.413491 50.0 835230.0 1.11218 Y
8 IC 280-678685/20 100.0 127.704731 50.0 753550.0 1.277047 Y
9 IC 280-678685/21 200.0 231.179033 50.0 798527.0 1.155895 Y
RelResp = [1.158]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
12/27/2024
9:26:49 AM
Page 356 of 428
Calibration / 4-Isopropyltoluene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.165
Error Coefficients
Relative Standard Deviation:10.1
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 1.272623 50.0 892330.0 2.545247 Y
2 IC 280-678685/14 1.0 2.037292 50.0 891281.0 2.037292 Y
3 IC 280-678685/15 2.0 4.082002 50.0 895835.0 2.041001 Y
4 IC 280-678685/16 5.0 10.421289 50.0 876998.0 2.084258 Y
5 IC 280-678685/17 10.0 18.290913 50.0 854263.0 1.829091 Y
6 ICIS 280-678685/18 50.0 113.575228 50.0 763501.0 2.271505 Y
7 IC 280-678685/19 75.0 157.467344 50.0 835230.0 2.099565 Y
8 IC 280-678685/20 100.0 242.912282 50.0 753550.0 2.429123 Y
9 IC 280-678685/21 200.0 430.104054 50.0 798527.0 2.15052 Y
RelResp = [2.165]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
12/27/2024
9:26:49 AM
Page 357 of 428
Calibration / 1,4-Dichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.172
Error Coefficients
Relative Standard Deviation:12.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.753029 50.0 892330.0 1.506057 Y
2 IC 280-678685/14 1.0 1.216115 50.0 891281.0 1.216115 Y
3 IC 280-678685/15 2.0 2.265149 50.0 895835.0 1.132575 Y
4 IC 280-678685/16 5.0 5.498188 50.0 876998.0 1.099638 Y
5 IC 280-678685/17 10.0 9.584987 50.0 854263.0 0.958499 Y
6 ICIS 280-678685/18 50.0 56.384078 50.0 763501.0 1.127682 Y
7 IC 280-678685/19 75.0 81.699891 50.0 835230.0 1.089332 Y
8 IC 280-678685/20 100.0 126.163626 50.0 753550.0 1.261636 Y
9 IC 280-678685/21 200.0 230.72645 50.0 798527.0 1.153632 Y
RelResp = [1.172]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
12/27/2024
9:26:49 AM
Page 358 of 428
Calibration / n-Butylbenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:2.075
Error Coefficients
Relative Standard Deviation:11.9
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 1.26758 50.0 892330.0 2.535161 Y
2 IC 280-678685/14 1.0 1.973227 50.0 891281.0 1.973227 Y
3 IC 280-678685/15 2.0 3.827937 50.0 895835.0 1.913969 Y
4 IC 280-678685/16 5.0 9.801163 50.0 876998.0 1.960233 Y
5 IC 280-678685/17 10.0 16.984114 50.0 854263.0 1.698411 Y
6 ICIS 280-678685/18 50.0 107.59796 50.0 763501.0 2.151959 Y
7 IC 280-678685/19 75.0 149.427703 50.0 835230.0 1.992369 Y
8 IC 280-678685/20 100.0 233.304359 50.0 753550.0 2.333044 Y
9 IC 280-678685/21 200.0 422.476948 50.0 798527.0 2.112385 Y
RelResp = [2.075]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
9:26:49 AM
Page 359 of 428
Calibration / 1,2-Dichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:1.111
Error Coefficients
Relative Standard Deviation:8.5
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.630708 50.0 892330.0 1.261417 Y
2 IC 280-678685/14 1.0 1.121532 50.0 891281.0 1.121532 Y
3 IC 280-678685/15 2.0 2.104015 50.0 895835.0 1.052007 Y
4 IC 280-678685/16 5.0 5.28268 50.0 876998.0 1.056536 Y
5 IC 280-678685/17 10.0 9.46266 50.0 854263.0 0.946266 Y
6 ICIS 280-678685/18 50.0 56.49377 50.0 763501.0 1.129875 Y
7 IC 280-678685/19 75.0 80.960693 50.0 835230.0 1.079476 Y
8 IC 280-678685/20 100.0 122.312786 50.0 753550.0 1.223128 Y
9 IC 280-678685/21 200.0 226.242006 50.0 798527.0 1.13121 Y
RelResp = [1.111]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
2.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
9:26:49 AM
Page 360 of 428
Calibration / 1,2-Dibromo-3-Chloropropane
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-0.598
Slope:0.3838
Error Coefficients
Relative Standard Deviation:20.4
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.121928 50.0 892330.0 0.243856 N
2 IC 280-678685/14 1.0 0.19803 50.0 891281.0 0.19803 N
3 IC 280-678685/15 2.0 0.451311 50.0 895835.0 0.225655 Y
4 IC 280-678685/16 5.0 1.194644 50.0 876998.0 0.238929 Y
5 IC 280-678685/17 10.0 2.389194 50.0 854263.0 0.238919 Y
6 ICIS 280-678685/18 50.0 16.928334 50.0 763501.0 0.338567 Y
7 IC 280-678685/19 75.0 25.63252 50.0 835230.0 0.341767 Y
8 IC 280-678685/20 100.0 40.279145 50.0 753550.0 0.402791 Y
9 IC 280-678685/21 200.0 78.596466 50.0 798527.0 0.392982 Y
RelResp = [-0.598] + [0.3838]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
IC 280-678685/21
Intercept = 1.56
12/27/2024
9:26:49 AM
Page 361 of 428
Calibration / 1,2,4-Trichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7123
Error Coefficients
Relative Standard Deviation:14.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.458911 50.0 892330.0 0.917822 N
2 IC 280-678685/14 1.0 0.643063 50.0 891281.0 0.643063 Y
3 IC 280-678685/15 2.0 1.227235 50.0 895835.0 0.613617 Y
4 IC 280-678685/16 5.0 3.236837 50.0 876998.0 0.647367 Y
5 IC 280-678685/17 10.0 6.010444 50.0 854263.0 0.601044 Y
6 ICIS 280-678685/18 50.0 36.108597 50.0 763501.0 0.722172 Y
7 IC 280-678685/19 75.0 57.076793 50.0 835230.0 0.761024 Y
8 IC 280-678685/20 100.0 87.770818 50.0 753550.0 0.877708 Y
9 IC 280-678685/21 200.0 166.526868 50.0 798527.0 0.832634 Y
RelResp = [0.7123]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
9:26:49 AM
Page 362 of 428
Calibration / Hexachlorobutadiene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.3012
Error Coefficients
Relative Standard Deviation:11.8
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.149104 50.0 892330.0 0.298208 Y
2 IC 280-678685/14 1.0 0.270566 50.0 891281.0 0.270566 Y
3 IC 280-678685/15 2.0 0.544911 50.0 895835.0 0.272455 Y
4 IC 280-678685/16 5.0 1.422979 50.0 876998.0 0.284596 Y
5 IC 280-678685/17 10.0 2.51041 50.0 854263.0 0.251041 Y
6 ICIS 280-678685/18 50.0 15.851387 50.0 763501.0 0.317028 Y
7 IC 280-678685/19 75.0 24.043258 50.0 835230.0 0.320577 Y
8 IC 280-678685/20 100.0 36.491407 50.0 753550.0 0.364914 Y
9 IC 280-678685/21 200.0 66.372458 50.0 798527.0 0.331862 Y
RelResp = [0.3012]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
9:26:49 AM
Page 363 of 428
Calibration / Naphthalene
Curve Type:Linear
Weighting:Conc
Origin:None
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:-1.744
Slope:3.17
Error Coefficients
Relative Standard Deviation:17.0
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 1.455964 50.0 892330.0 2.911927 N
2 IC 280-678685/14 1.0 2.441823 50.0 891281.0 2.441823 Y
3 IC 280-678685/15 2.0 4.580643 50.0 895835.0 2.290321 Y
4 IC 280-678685/16 5.0 11.871407 50.0 876998.0 2.374281 Y
5 IC 280-678685/17 10.0 23.801218 50.0 854263.0 2.380122 Y
6 ICIS 280-678685/18 50.0 152.805039 50.0 763501.0 3.056101 Y
7 IC 280-678685/19 75.0 225.271362 50.0 835230.0 3.003618 Y
8 IC 280-678685/20 100.0 348.324066 50.0 753550.0 3.483241 Y
9 IC 280-678685/21 200.0 621.204355 50.0 798527.0 3.106022 Y
RelResp = [-1.744] + [3.17]x
Concentration
0 100 200
0.0
1.0
2.0
3.0
4.0
5.0
6.0
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/20
Intercept = 0.550
12/27/2024
9:26:49 AM
Page 364 of 428
Calibration / 1,2,3-Trichlorobenzene
Curve Type:Average
Weighting:Conc_Sq
Origin:Force
Dependency:Response
Calib Mode:ISTD
Response Base:AREA
RF Rounding:0
Curve Coefficients
Intercept:0
Slope:0.7195
Error Coefficients
Relative Standard Deviation:12.6
ID Level Concentration Rel. Resp.IS Amount IS Response RRF Used
1 IC 280-678685/13 0.5 0.391391 50.0 892330.0 0.782782 Y
2 IC 280-678685/14 1.0 0.693665 50.0 891281.0 0.693665 Y
3 IC 280-678685/15 2.0 1.273449 50.0 895835.0 0.636724 Y
4 IC 280-678685/16 5.0 3.095389 50.0 876998.0 0.619078 Y
5 IC 280-678685/17 10.0 6.012551 50.0 854263.0 0.601255 Y
6 ICIS 280-678685/18 50.0 36.103816 50.0 763501.0 0.722076 Y
7 IC 280-678685/19 75.0 56.090179 50.0 835230.0 0.747869 Y
8 IC 280-678685/20 100.0 86.634198 50.0 753550.0 0.866342 Y
9 IC 280-678685/21 200.0 161.076645 50.0 798527.0 0.805383 Y
RelResp = [0.7195]x
Concentration
0 100 200
0.0
0.5
1.0
1.5
Re
l
a
t
i
v
e

R
e
s
p
o
n
s
e

(

X

1
0
0
)
IC 280-678685/13
IC 280-678685/14
IC 280-678685/15
IC 280-678685/16
IC 280-678685/17
ICIS 280-678685/18
IC 280-678685/19
IC 280-678685/21
12/27/2024
9:26:49 AM
Page 365 of 428
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-201015-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_MS14
12/17/2024 04:21
12/17/2024 01:00
12/17/2024 03:40
ICV 280-678685/22
DB-624 (60.25)
Lab File ID:VMS14_0000005233.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Dichlorodifluoromethane 0.27060.2829 0.1000 47.8 50.0 -4.3 30.0Ave
Chloromethane 0.28700.3318 0.1000 43.2 50.0 -13.5 30.0Ave
Vinyl chloride 0.26450.2545 0.0100 52.0 50.0 3.9 30.0Ave
Bromomethane 0.1608 0.0100 45.2 50.0 -9.5 30.0Lin1
Chloroethane 0.15690.1619 0.0100 48.4 50.0 -3.1 30.0Ave
Dichlorofluoromethane 0.42880.4265 0.0100 50.3 50.0 0.5 30.0Ave
Trichlorofluoromethane 0.30090.3055 0.0100 49.2 50.0 -1.5 30.0Ave
Ethyl ether 0.19810.2002 0.0100 49.5 50.0 -1.0 30.0Ave
Acrolein 0.06500.0575 0.0010 559 494 13.1 30.0Ave
1,1,2-Trichloro-1,2,2-trifluoroethane 0.12730.1260 0.0500 50.5 50.0 1.1 30.0Ave
1,1-Dichloroethene 0.17300.1797 0.0600 48.1 50.0 -3.7 30.0Ave
Acetone 0.2746 0.0100 214 200 6.9 30.0Lin2
Iodomethane 0.1727 0.0100 45.5 50.0 -9.0 30.0Lin1
Carbon disulfide 0.5525 0.1000 44.1 50.0 -11.8 30.0Lin1
Methyl acetate 0.44530.4639 0.0100 96.0 100 -4.0 30.0Ave
3-Chloro-1-propene 0.3167 0.0100 46.7 50.0 -6.7 30.0Lin1
Methylene Chloride 0.23400.2479 0.0100 47.2 50.0 -5.6 30.0Ave
2-Methyl-2-propanol 0.16250.1510 0.0010 538 500 7.6 30.0Ave
Acrylonitrile 0.23240.2250 0.0100 517 500 3.3 30.0Ave
Methyl tert-butyl ether 0.71730.7329 0.1000 48.9 50.0 -2.1 30.0Ave
trans-1,2-Dichloroethene 0.18450.1927 0.1000 47.9 50.0 -4.2 30.0Ave
Hexane 1.0051.158 0.0100 43.4 50.0 -13.2 30.0Ave
Vinyl acetate 0.49370.5566 0.0100 88.7 100 -11.3 30.0Ave
1,1-Dichloroethane 0.36280.3674 0.1000 49.4 50.0 -1.3 30.0Ave
2-Butanone (MEK)0.41580.4116 0.0100 202 200 1.0 30.0Ave
cis-1,2-Dichloroethene 0.22380.2257 0.1000 49.6 50.0 -0.8 30.0Ave
2,2-Dichloropropane 0.28160.2985 0.0100 47.2 50.0 -5.7 30.0Ave
sec-Butyl Alcohol 0.11250.1020 0.0100 1320 1200 10.3 30.0Ave
Chlorobromomethane 0.10270.1034 0.0500 49.6 50.0 -0.7 30.0Ave
Tetrahydrofuran 0.24730.2504 0.0010 98.8 100 -1.2 30.0Ave
Chloroform 0.35830.3639 0.2000 49.2 50.0 -1.5 30.0Ave
1,1,1-Trichloroethane 0.29750.2967 0.0500 50.1 50.0 0.3 30.0Ave
Cyclohexane 0.32780.3545 0.0100 46.2 50.0 -7.5 30.0Ave
1,1-Dichloropropene 0.27420.2916 0.0100 47.0 50.0 -6.0 30.0Ave
Carbon tetrachloride 0.2185 0.1000 45.6 50.0 -8.7 30.0Lin1
Isobutyl alcohol 0.04380.0387 0.0010 1420 1250 13.4 30.0Ave
Benzene 0.80480.8332 0.2000 48.3 50.0 -3.4 30.0Ave
1,2-Dichloroethane 0.31170.3333 0.0700 46.8 50.0 -6.5 30.0Ave
n-Heptane 0.24630.2743 44.9 50.0 -10.2 20.0Ave
Trichloroethene 0.87710.8278 0.2000 53.0 50.0 6.0 30.0Ave
FORM VII 8260D
12/27/2024
9:26:49 AM
Page 366 of 428
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-201015-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_MS14
12/17/2024 04:21
12/17/2024 01:00
12/17/2024 03:40
ICV 280-678685/22
DB-624 (60.25)
Lab File ID:VMS14_0000005233.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
2-Pentanone 0.59040.5720 0.0010 165 160 3.2 30.0Ave
Methylcyclohexane 0.25500.2818 0.0500 45.3 50.0 -9.5 30.0Ave
1,2-Dichloropropane 0.21530.2184 0.1000 49.3 50.0 -1.4 30.0Ave
1,4-Dioxane 0.00730.0066 0.0010 1110 1000 10.9 30.0Ave
Dibromomethane 0.14750.1496 0.0100 49.3 50.0 -1.4 30.0Ave
Dichlorobromomethane 0.27030.2514 0.2000 53.7 50.0 7.5 30.0Ave
2-Chloroethyl vinyl ether 0.02970.0366 0.0100 40.6 50.0 -18.9 30.0Ave
cis-1,3-Dichloropropene 1.3611.391 0.2000 48.9 50.0 -2.2 30.0Ave
4-Methyl-2-pentanone (MIBK)0.56090.5513 0.0300 203 200 1.7 30.0Ave
Toluene 0.87560.9077 0.3000 48.2 50.0 -3.5 30.0Ave
trans-1,3-Dichloropropene 0.3446 0.2000 46.4 50.0 -7.2 30.0Lin1
Ethyl methacrylate 1.6601.618 0.0100 51.3 50.0 2.6 30.0Ave
1,1,2-Trichloroethane 0.21890.2140 0.1000 51.1 50.0 2.3 30.0Ave
Tetrachloroethene 0.61020.6355 0.1000 48.0 50.0 -4.0 30.0Ave
1,3-Dichloropropane 1.5551.593 0.0100 48.8 50.0 -2.4 30.0Ave
2-Hexanone 2.0041.923 0.0100 208 200 4.2 30.0Ave
Chlorodibromomethane 0.8117 0.1000 47.5 50.0 -5.0 30.0Lin1
Ethylene Dibromide 0.95310.9555 0.1000 49.9 50.0 -0.3 30.0Ave
1-Chlorohexane 1.178 0.0100 38.9 40.0 -2.8 30.0Lin1
Chlorobenzene 2.3302.379 0.3000 49.0 50.0 -2.0 30.0Ave
1,1,1,2-Tetrachloroethane 0.77360.7136 0.0100 54.2 50.0 8.4 30.0Ave
Ethylbenzene 1.2601.243 0.3000 50.7 50.0 1.3 30.0Ave
m-Xylene & p-Xylene 1.5101.565 0.1000 48.2 50.0 -3.5 30.0Ave
o-Xylene 1.5271.531 0.2000 49.9 50.0 -0.3 30.0Ave
Styrene 2.6412.539 0.2000 52.0 50.0 4.0 30.0Ave
Bromoform 0.6003 0.1000 45.6 50.0 -8.9 30.0Lin1
Isopropylbenzene 2.5102.258 0.3000 55.6 50.0 11.2 30.0Ave
Cyclohexanone 0.29360.1695 0.0010 2600 1500 73.2*30.0Ave
1,1,2,2-Tetrachloroethane 0.97020.9763 0.3000 49.7 50.0 -0.6 30.0Ave
trans-1,4-Dichloro-2-butene 0.3241 0.0100 45.9 50.0 -8.2 30.0Lin1
Bromobenzene 0.59100.5938 0.0100 49.8 50.0 -0.5 30.0Ave
1,2,3-Trichloropropane 0.35490.3513 0.0100 50.5 50.0 1.0 30.0Ave
N-Propylbenzene 0.64490.6449 0.0100 50.0 50.0 -0.0 30.0Ave
2-Chlorotoluene 0.55380.5685 0.0100 48.7 50.0 -2.6 30.0Ave
1,3,5-Trimethylbenzene 2.0171.999 0.0100 50.4 50.0 0.9 30.0Ave
4-Chlorotoluene 0.58240.5922 0.0100 49.2 50.0 -1.7 30.0Ave
tert-Butylbenzene 1.7691.779 0.0100 49.7 50.0 -0.6 30.0Ave
1,2,4-Trimethylbenzene 2.0642.059 0.3000 50.1 50.0 0.2 30.0Ave
sec-Butylbenzene 0.50990.5090 0.0100 50.1 50.0 0.2 30.0Ave
1,3-Dichlorobenzene 1.1421.158 0.5000 49.3 50.0 -1.4 30.0Ave
4-Isopropyltoluene 2.1832.165 0.0100 50.4 50.0 0.8 30.0Ave
FORM VII 8260D
12/27/2024
9:26:49 AM
Page 367 of 428
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-201015-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_MS14
12/17/2024 04:21
12/17/2024 01:00
12/17/2024 03:40
ICV 280-678685/22
DB-624 (60.25)
Lab File ID:VMS14_0000005233.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
1,4-Dichlorobenzene 1.1561.172 0.5000 49.3 50.0 -1.4 30.0Ave
n-Butylbenzene 2.1072.075 0.0100 50.8 50.0 1.6 30.0Ave
1,2-Dichlorobenzene 1.1421.111 0.5000 51.4 50.0 2.8 30.0Ave
1,2-Dibromo-3-Chloropropane 0.3364 0.0100 45.4 50.0 -9.3 30.0Lin1
1,2,4-Trichlorobenzene 0.78020.7123 0.2000 54.8 50.0 9.5 30.0Ave
Hexachlorobutadiene 0.32430.3012 0.0100 53.8 50.0 7.7 30.0Ave
Naphthalene 3.067 0.0100 48.9 50.0 -2.1 30.0Lin1
1,2,3-Trichlorobenzene 0.75070.7195 0.3000 52.2 50.0 4.3 30.0Ave
Dibromofluoromethane (Surr)0.25850.2541 0.0100 50.9 50.0 1.7 30.0Ave
1,2-Dichloroethane-d4 (Surr)0.33570.3380 0.0100 49.7 50.0 -0.7 30.0Ave
Toluene-d8 (Surr)4.2244.269 0.0100 49.5 50.0 -1.0 30.0Ave
4-Bromofluorobenzene (Surr)1.0141.023 0.0100 49.6 50.0 -0.8 30.0Ave
FORM VII 8260D
12/27/2024
9:26:49 AM
Page 368 of 428
Report Date: 18-Dec-2024 06:17:49 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005233.D
Lims ID:icv
Client ID:
Sample Type:ICV
Inject. Date:17-Dec-2024 04:21:35 ALS Bottle#:11 Worklist Smp#:22
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:icv
Operator ID:bustillose Instrument ID:VMS_MS14
Sublist:
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:18-Dec-2024 06:17:47 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1671
First Level Reviewer: LP8K Date:17-Dec-2024 16:09:04
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 99 1940806 50.0 50.0
* 2 Chlorobenzene-d5 119 7.926 7.926 0.000 88 481995 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.173 0.000 96 768801 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.839 4.842 -0.003 92 501785 50.0 50.9
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 96 651476 50.0 49.7
$ 6 Toluene-d8 (Surr) 98 6.636 6.636 0.000 93 2036111 50.0 49.5
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 83 779644 50.0 49.6
10 Dichlorodifluoromethane 85 1.794 1.794 0.000 100 525191 50.0 47.8
12 Chloromethane 50 1.971 1.974 -0.003 99 557018 50.0 43.2
13 Vinyl chloride 62 2.087 2.087 0.000 98 513314 50.0 52.0
15 Bromomethane 94 2.399 2.399 0.000 91 312056 50.0 45.2
16 Chloroethane 64 2.495 2.498 -0.003 100 304460 50.0 48.4
17 Dichlorofluoromethane 67 2.678 2.678 0.000 97 832242 50.0 50.3
18 Trichlorofluoromethane 101 2.717 2.717 0.000 98 583915 50.0 49.2
21 Ethyl ether 59 2.939 2.939 0.000 91 384503 50.0 49.5
22 Acrolein 56 3.055 3.055 0.000 99 1246382 493.8 558.5
25 1,1-Dichloroethene 96 3.145 3.141 0.004 96 335813 50.0 48.1
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.141 3.141 0.000 96 247150 50.0 50.5
26 Acetone 43 3.161 3.161 0.000 100 2131607 200.0 213.7
29 Iodomethane 142 3.270 3.270 0.000 99 335243 50.0 45.5
30 Carbon disulfide 76 3.337 3.337 0.000 99 1072256 50.0 44.1
32 Methyl acetate 43 3.399 3.399 0.000 98 1728301 100.0 96.0
33 3-Chloro-1-propene 41 3.421 3.421 0.000 90 614602 50.0 46.7
34 Methylene Chloride 84 3.521 3.521 0.000 92 454234 50.0 47.2
35 2-Methyl-2-propanol 59 3.569 3.566 0.003 99 3154703 500.0 538.2
36 Acrylonitrile 53 3.688 3.688 0.000 98 4510524 500.0 516.5
37 Methyl tert-butyl ether 73 3.714 3.714 0.000 95 1392112 50.0 48.9
38 trans-1,2-Dichloroethene 96 3.730 3.730 0.000 98 358152 50.0 47.9
39 Hexane 57 3.932 3.932 0.000 92 484560 50.0 43.4
40 Vinyl acetate 43 4.032 4.029 0.003 97 1916396 100.0 88.7
42 1,1-Dichloroethane 63 4.058 4.058 0.000 96 704034 50.0 49.4
12/27/2024
9:26:49 AM
Page 369 of 428
Report Date: 18-Dec-2024 06:17:49 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005233.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
45 2-Butanone (MEK) 43 4.453 4.453 0.000 100 3227642 200.0 202.0
47 cis-1,2-Dichloroethene 96 4.482 4.482 0.000 82 434266 50.0 49.6
48 2,2-Dichloropropane 77 4.492 4.495 -0.003 86 546441 50.0 47.2
50 sec-Butyl Alcohol 45 4.566 4.569 -0.003 99 5241314 1200.0 1323.3
52 Chlorobromomethane 128 4.662 4.659 0.003 97 199307 50.0 49.6
53 Tetrahydrofuran 42 4.675 4.675 0.000 86 960051 100.0 98.8
54 Chloroform 83 4.720 4.723 -0.003 94 695424 50.0 49.2
55 1,1,1-Trichloroethane 97 4.871 4.874 -0.003 99 577404 50.0 50.1
56 Cyclohexane 56 4.936 4.936 0.000 89 636292 50.0 46.2
57 1,1-Dichloropropene 75 4.987 4.987 0.000 96 532085 50.0 47.0
59 Carbon tetrachloride 117 4.997 4.997 0.000 95 424050 50.0 45.6
58 Isobutyl alcohol 41 5.000 4.997 0.003 95 2127236 1250.0 1417.1
60 Benzene 78 5.145 5.145 0.000 96 1561914 50.0 48.3
61 1,2-Dichloroethane 62 5.170 5.167 0.003 97 604990 50.0 46.8
63 n-Heptane 43 5.331 5.331 0.000 92 478112 50.0 44.9
65 Trichloroethene 95 5.643 5.640 0.003 98 422770 50.0 53.0
66 2-Pentanone 43 5.739 5.739 0.000 99 3666640 160.0 165.1
67 Methylcyclohexane 55 5.845 5.842 0.003 91 494956 50.0 45.3
69 1,2-Dichloropropane 63 5.849 5.849 0.000 94 417949 50.0 49.3
70 1,4-Dioxane 88 5.913 5.919 -0.006 91 283936 1000.0 1109.4
71 Dibromomethane 93 5.919 5.923 -0.004 94 286332 50.0 49.3
72 Dichlorobromomethane 83 6.045 6.045 0.000 99 524525 50.0 53.7
74 2-Chloroethyl vinyl ether 63 6.247 6.247 0.000 91 57655 50.0 40.6
75 cis-1,3-Dichloropropene 75 6.399 6.399 0.000 95 656058 50.0 48.9
76 4-Methyl-2-pentanone (MIBK) 43 6.501 6.501 0.000 96 4354101 200.0 203.5
77 Toluene 91 6.698 6.694 0.004 98 1699378 50.0 48.2
78 trans-1,3-Dichloropropene 75 6.868 6.868 0.000 94 668805 50.0 46.4
79 Ethyl methacrylate 69 6.887 6.887 0.000 89 800174 50.0 51.3
80 1,1,2-Trichloroethane 97 7.048 7.045 0.003 92 424805 50.0 51.1
82 Tetrachloroethene 164 7.151 7.148 0.003 94 294121 50.0 48.0
83 1,3-Dichloropropane 76 7.196 7.196 0.000 91 749265 50.0 48.8
84 2-Hexanone 43 7.212 7.212 0.000 95 3864192 200.0 208.5
85 Chlorodibromomethane 129 7.395 7.395 0.000 91 391219 50.0 47.5
86 Ethylene Dibromide 107 7.514 7.517 -0.003 98 459376 50.0 49.9
87 1-Chlorohexane 91 7.907 7.907 0.000 98 454411 40.0 38.9
88 Chlorobenzene 112 7.955 7.955 0.000 93 1123068 50.0 49.0
89 1,1,1,2-Tetrachloroethane 131 8.025 8.025 0.000 94 372893 50.0 54.2
90 Ethylbenzene 106 8.029 8.032 -0.003 99 607210 50.0 50.7
91 m-Xylene & p-Xylene 106 8.148 8.151 -0.003 99 727855 50.0 48.2
92 o-Xylene 106 8.514 8.514 0.000 97 736201 50.0 49.9
93 Styrene 104 8.527 8.527 0.000 94 1273168 50.0 52.0
94 Bromoform 173 8.714 8.710 0.004 94 289318 50.0 45.6
95 Isopropylbenzene 105 8.855 8.855 0.000 96 1929934 50.0 55.6
97 Cyclohexanone 55 8.961 8.958 0.003 93 4245612 1500.0 2597.9
98 1,1,2,2-Tetrachloroethane 83 9.144 9.141 0.003 95 745861 50.0 49.7
99 trans-1,4-Dichloro-2-butene 53 9.183 9.180 0.003 63 249200 50.0 45.9
100 Bromobenzene 156 9.186 9.183 0.003 98 454375 50.0 49.8
101 1,2,3-Trichloropropane 110 9.209 9.206 0.003 82 272872 50.0 50.5
102 N-Propylbenzene 120 9.260 9.257 0.003 99 495807 50.0 50.0
103 2-Chlorotoluene 126 9.360 9.360 0.000 95 425800 50.0 48.7
104 1,3,5-Trimethylbenzene 105 9.431 9.431 0.000 95 1550331 50.0 50.4
105 4-Chlorotoluene 126 9.479 9.476 0.003 98 447768 50.0 49.2
12/27/2024
9:26:49 AM
Page 370 of 428
Report Date: 18-Dec-2024 06:17:49 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005233.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
107 tert-Butylbenzene 119 9.749 9.746 0.003 93 1360293 50.0 49.7
108 1,2,4-Trimethylbenzene 105 9.807 9.804 0.003 98 1587017 50.0 50.1
109 sec-Butylbenzene 134 9.968 9.968 0.000 95 392007 50.0 50.1
110 1,3-Dichlorobenzene 146 10.099 10.099 0.000 97 878029 50.0 49.3
111 4-Isopropyltoluene 119 10.112 10.112 0.000 97 1678540 50.0 50.4
112 1,4-Dichlorobenzene 146 10.199 10.199 0.000 94 888410 50.0 49.3
114 n-Butylbenzene 91 10.524 10.524 0.000 98 1619963 50.0 50.8
115 1,2-Dichlorobenzene 146 10.562 10.562 0.000 96 877884 50.0 51.4
116 1,2-Dibromo-3-Chloropropane 157 11.347 11.344 0.003 81 258599 50.0 45.4
118 1,2,4-Trichlorobenzene 180 12.180 12.180 0.000 94 599790 50.0 54.8
119 Hexachlorobutadiene 225 12.324 12.321 0.003 96 249338 50.0 53.8
120 Naphthalene 128 12.453 12.453 0.000 97 2358162 50.0 48.9
121 1,2,3-Trichlorobenzene 180 12.678 12.678 0.000 94 577169 50.0 52.2
136 Butadiene 54 0.000 ND ND
S 155 Xylenes, Total 106 0 100.0 98.1
S 152 Trihalomethanes, Total 1 0 200.0 196.1
S 154 1,3-Dichloropropene, Total 1 0 100.0 95.3
S 151 1,2-Dichloroethene, Total 1 0 100.0 97.5
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
MV-MegaMain B_00112 Amount Added: 25.00 Units: uL
MV-Gas B_00177 Amount Added: 10.00 Units: uL
mv-IS_SS_00093 Amount Added: 5.00 Units: uL Run Reagent
12/27/2024
9:26:49 AM
Page 371 of 428
Report Date: 18-Dec-2024 06:17:49 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005233.D
Injection Date:17-Dec-2024 04:21:35 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:icv Worklist Smp#:22
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:11
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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Page 372 of 428
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-201015-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_MS14
12/23/2024 17:23
12/17/2024 01:00
12/17/2024 03:40
CCV 280-679543/2
DB-624 (60.25)
Lab File ID:VMS14_0000005443.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
Dichlorodifluoromethane 0.28870.2829 0.1000 51.0 50.0 2.1 20.0Ave
Chloromethane 0.25480.3318 0.1000 38.4 50.0 -23.2*20.0Ave
Vinyl chloride 0.21570.2545 0.0100 42.4 50.0 -15.2 20.0Ave
Bromomethane 0.1579 0.0100 44.5 50.0 -11.1 20.0Lin1
Chloroethane 0.14500.1619 0.0100 44.8 50.0 -10.5 20.0Ave
Dichlorofluoromethane 0.43050.4265 0.0100 50.5 50.0 0.9 20.0Ave
Trichlorofluoromethane 0.31170.3055 0.0100 51.0 50.0 2.0 20.0Ave
Ethyl ether 0.19840.2002 0.0100 49.6 50.0 -0.9 20.0Ave
Acrolein 0.05960.0575 0.0010 512 494 3.7 20.0Ave
1,1,2-Trichloro-1,2,2-trifluoroethane 0.12340.1260 0.0500 49.0 50.0 -2.1 20.0Ave
1,1-Dichloroethene 0.16940.1797 0.0600 47.1 50.0 -5.7 20.0Ave
Acetone 0.2392 0.0100 185 200 -7.5 20.0Lin2
Iodomethane 0.1731 0.0100 45.6 50.0 -8.8 20.0Lin1
Carbon disulfide 0.5204 0.1000 41.6 50.0 -16.8 20.0Lin1
Methyl acetate 0.42610.4639 0.0100 91.9 100 -8.1 20.0Ave
3-Chloro-1-propene 0.3120 0.0100 46.0 50.0 -8.0 20.0Lin1
Methylene Chloride 0.21730.2479 0.0100 43.8 50.0 -12.3 20.0Ave
2-Methyl-2-propanol 0.14000.1510 0.0010 464 500 -7.3 20.0Ave
Acrylonitrile 0.20750.2250 0.0100 461 500 -7.8 20.0Ave
Methyl tert-butyl ether 0.63930.7329 0.1000 43.6 50.0 -12.8 20.0Ave
trans-1,2-Dichloroethene 0.18550.1927 0.1000 48.1 50.0 -3.7 20.0Ave
Hexane 1.0761.158 0.0100 46.5 50.0 -7.1 20.0Ave
Vinyl acetate 0.57480.5566 0.0100 103 100 3.3 20.0Ave
1,1-Dichloroethane 0.35160.3674 0.1000 47.9 50.0 -4.3 20.0Ave
2-Butanone (MEK)0.37600.4116 0.0100 183 200 -8.7 20.0Ave
cis-1,2-Dichloroethene 0.21250.2257 0.1000 47.1 50.0 -5.8 20.0Ave
2,2-Dichloropropane 0.29080.2985 0.0100 48.7 50.0 -2.6 20.0Ave
sec-Butyl Alcohol 0.09790.1020 0.0100 1150 1200 -4.0 20.0Ave
Chlorobromomethane 0.10060.1034 0.0500 48.7 50.0 -2.7 20.0Ave
Tetrahydrofuran 0.22750.2504 0.0010 90.9 100 -9.1 20.0Ave
Chloroform 0.34460.3639 0.2000 47.3 50.0 -5.3 20.0Ave
1,1,1-Trichloroethane 0.28060.2967 0.0500 47.3 50.0 -5.5 20.0Ave
Cyclohexane 0.32450.3545 0.0100 45.8 50.0 -8.5 20.0Ave
1,1-Dichloropropene 0.27250.2916 0.0100 46.7 50.0 -6.6 20.0Ave
Carbon tetrachloride 0.2077 0.1000 43.4 50.0 -13.1 20.0Lin1
Isobutyl alcohol 0.03820.0387 0.0010 1230 1250 -1.3 20.0Ave
Benzene 0.78560.8332 0.2000 47.1 50.0 -5.7 20.0Ave
1,2-Dichloroethane 0.29700.3333 0.0700 44.6 50.0 -10.9 20.0Ave
n-Heptane 0.25560.2743 46.6 50.0 -6.8Ave
Trichloroethene 0.81800.8278 0.2000 49.4 50.0 -1.2 20.0Ave
FORM VII 8260D
12/27/2024
9:26:49 AM
Page 373 of 428
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-201015-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_MS14
12/23/2024 17:23
12/17/2024 01:00
12/17/2024 03:40
CCV 280-679543/2
DB-624 (60.25)
Lab File ID:VMS14_0000005443.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
2-Pentanone 0.53900.5720 0.0010 151 160 -5.8 20.0Ave
Methylcyclohexane 0.25760.2818 0.0500 45.7 50.0 -8.6 20.0Ave
1,2-Dichloropropane 0.20910.2184 0.1000 47.9 50.0 -4.3 20.0Ave
1,4-Dioxane 0.00720.0066 0.0010 1090 1000 9.1 20.0Ave
Dibromomethane 0.13810.1496 0.0100 46.1 50.0 -7.7 20.0Ave
Dichlorobromomethane 0.24660.2514 0.2000 49.0 50.0 -1.9 20.0Ave
cis-1,3-Dichloropropene 1.4371.391 0.2000 51.6 50.0 3.3 20.0Ave
4-Methyl-2-pentanone (MIBK)0.52590.5513 0.0300 191 200 -4.6 20.0Ave
Toluene 0.84200.9077 0.3000 46.4 50.0 -7.2 20.0Ave
trans-1,3-Dichloropropene 0.3121 0.2000 42.1 50.0 -15.8 20.0Lin1
Ethyl methacrylate 1.6371.618 0.0100 50.6 50.0 1.1 20.0Ave
1,1,2-Trichloroethane 0.20370.2140 0.1000 47.6 50.0 -4.8 20.0Ave
Tetrachloroethene 0.60560.6355 0.1000 47.6 50.0 -4.7 20.0Ave
1,3-Dichloropropane 1.5341.593 0.0100 48.1 50.0 -3.7 20.0Ave
2-Hexanone 1.8441.923 0.0100 192 200 -4.1 20.0Ave
Chlorodibromomethane 0.7648 0.1000 44.8 50.0 -10.4 20.0Lin1
Ethylene Dibromide 0.92490.9555 0.1000 48.4 50.0 -3.2 20.0Ave
1-Chlorohexane 1.125 0.0100 37.1 40.0 -7.2 20.0Lin1
Chlorobenzene 2.2442.379 0.3000 47.2 50.0 -5.6 20.0Ave
1,1,1,2-Tetrachloroethane 0.73040.7136 0.0100 51.2 50.0 2.4 20.0Ave
Ethylbenzene 1.1881.243 0.3000 47.8 50.0 -4.5 20.0Ave
m-Xylene & p-Xylene 1.4741.565 0.1000 47.1 50.0 -5.8 20.0Ave
o-Xylene 1.4701.531 0.2000 48.0 50.0 -4.0 20.0Ave
Styrene 2.5182.539 0.2000 49.6 50.0 -0.8 20.0Ave
Bromoform 0.5532 0.1000 42.1 50.0 -15.8 20.0Lin1
Isopropylbenzene 2.1562.258 0.3000 47.7 50.0 -4.5 20.0Ave
Cyclohexanone 0.18610.1695 0.0010 1650 1500 9.8 20.0Ave
1,1,2,2-Tetrachloroethane 0.97050.9763 0.3000 49.7 50.0 -0.6 20.0Ave
trans-1,4-Dichloro-2-butene 0.2924 0.0100 41.5 50.0 -16.9 20.0Lin1
Bromobenzene 0.56070.5938 0.0100 47.2 50.0 -5.6 20.0Ave
1,2,3-Trichloropropane 0.33920.3513 0.0100 48.3 50.0 -3.4 20.0Ave
N-Propylbenzene 0.60210.6449 0.0100 46.7 50.0 -6.6 20.0Ave
2-Chlorotoluene 0.53100.5685 0.0100 46.7 50.0 -6.6 20.0Ave
1,3,5-Trimethylbenzene 1.8971.999 0.0100 47.5 50.0 -5.1 20.0Ave
4-Chlorotoluene 0.55720.5922 0.0100 47.0 50.0 -5.9 20.0Ave
tert-Butylbenzene 1.6531.779 0.0100 46.4 50.0 -7.1 20.0Ave
1,2,4-Trimethylbenzene 1.9942.059 0.3000 48.4 50.0 -3.2 20.0Ave
sec-Butylbenzene 0.47650.5090 0.0100 46.8 50.0 -6.4 20.0Ave
1,3-Dichlorobenzene 1.0851.158 0.5000 46.8 50.0 -6.3 20.0Ave
4-Isopropyltoluene 2.0642.165 0.0100 47.7 50.0 -4.7 20.0Ave
1,4-Dichlorobenzene 1.0851.172 0.5000 46.3 50.0 -7.4 20.0Ave
FORM VII 8260D
12/27/2024
9:26:49 AM
Page 374 of 428
FORM VII
Lab Name:Job No.:
GC/MS VOA CONTINUING CALIBRATION DATA
280-201015-1Eurofins Denver
SDG No.:
Instrument ID:
Calibration Date:
Calib Start Date:
Lab Sample ID:
Calib End Date:GC Column: ID:0.25(mm)
VMS_MS14
12/23/2024 17:23
12/17/2024 01:00
12/17/2024 03:40
CCV 280-679543/2
DB-624 (60.25)
Lab File ID:VMS14_0000005443.D Heated Purge: (Y/N)NConc. Units:ug/L
ANALYTE CURVE CALC SPIKE %D MAX
TYPE AMOUNT AMOUNT %D
AVE RRF RRF MIN RRF
n-Butylbenzene 1.9562.075 0.0100 47.1 50.0 -5.7 20.0Ave
1,2-Dichlorobenzene 1.0751.111 0.5000 48.4 50.0 -3.2 20.0Ave
1,2-Dibromo-3-Chloropropane 0.3116 0.0100 42.1 50.0 -15.7 20.0Lin1
1,2,4-Trichlorobenzene 0.68550.7123 0.2000 48.1 50.0 -3.8 20.0Ave
Hexachlorobutadiene 0.27930.3012 0.0100 46.4 50.0 -7.3 20.0Ave
Naphthalene 2.813 0.0100 44.9 50.0 -10.2 20.0Lin1
1,2,3-Trichlorobenzene 0.66150.7195 0.3000 46.0 50.0 -8.1 20.0Ave
2-Chloroethyl vinyl ether 0.0366 50.0Ave
Dibromofluoromethane (Surr)0.25140.2541 0.0100 49.5 50.0 -1.1 20.0Ave
1,2-Dichloroethane-d4 (Surr)0.32500.3380 0.0100 48.1 50.0 -3.8 20.0Ave
Toluene-d8 (Surr)4.2404.269 0.0100 49.7 50.0 -0.7 20.0Ave
4-Bromofluorobenzene (Surr)0.9961.023 0.0100 48.7 50.0 -2.6 20.0Ave
FORM VII 8260D
12/27/2024
9:26:49 AM
Page 375 of 428
Report Date: 23-Dec-2024 22:20:05 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005443.D
Lims ID:CCV
Client ID:
Sample Type:CCV
Inject. Date:23-Dec-2024 17:23:03 ALS Bottle#:26 Worklist Smp#:2
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ccv
Operator ID:MED Instrument ID:VMS_MS14
Sublist:chrom-AQ_VMS14_8260*sub1
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:23-Dec-2024 22:20:05 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1673
First Level Reviewer: LP8K Date:23-Dec-2024 18:29:19
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 99 2081420 50.0 50.0
* 2 Chlorobenzene-d5 119 7.926 7.926 0.000 88 501851 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.173 0.000 97 803693 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.839 4.839 0.000 93 523183 50.0 49.5
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.109 0.000 99 676522 50.0 48.1
$ 6 Toluene-d8 (Surr) 98 6.636 6.636 0.000 93 2127775 50.0 49.7
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 84 800143 50.0 48.7
10 Dichlorodifluoromethane 85 1.794 1.794 0.000 99 601000 50.0 51.0
12 Chloromethane 50 1.974 1.974 0.000 99 530304 50.0 38.4
13 Vinyl chloride 62 2.090 2.090 0.000 98 448950 50.0 42.4
15 Bromomethane 94 2.395 2.395 0.000 92 328701 50.0 44.5
16 Chloroethane 64 2.495 2.495 0.000 100 301744 50.0 44.8
17 Dichlorofluoromethane 67 2.678 2.678 0.000 97 896155 50.0 50.5
18 Trichlorofluoromethane 101 2.717 2.717 0.000 98 648746 50.0 51.0
21 Ethyl ether 59 2.939 2.939 0.000 91 412897 50.0 49.6
22 Acrolein 56 3.054 3.054 0.000 99 1225047 493.8 511.9
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.138 3.138 0.000 96 256751 50.0 49.0
25 1,1-Dichloroethene 96 3.144 3.144 0.000 96 352584 50.0 47.1
26 Acetone 43 3.160 3.160 0.000 100 1991102 200.0 185.0
29 Iodomethane 142 3.270 3.270 0.000 100 360196 50.0 45.6
30 Carbon disulfide 76 3.337 3.337 0.000 99 1083088 50.0 41.6
32 Methyl acetate 43 3.395 3.395 0.000 98 1773838 100.0 91.9
33 3-Chloro-1-propene 41 3.421 3.421 0.000 90 649416 50.0 46.0
34 Methylene Chloride 84 3.521 3.521 0.000 93 452244 50.0 43.8
35 2-Methyl-2-propanol 59 3.566 3.566 0.000 99 2913986 500.0 463.5
36 Acrylonitrile 53 3.685 3.685 0.000 98 4318802 500.0 461.2
37 Methyl tert-butyl ether 73 3.713 3.713 0.000 94 1330753 50.0 43.6
38 trans-1,2-Dichloroethene 96 3.730 3.730 0.000 97 386031 50.0 48.1
39 Hexane 57 3.932 3.932 0.000 92 540080 50.0 46.5
40 Vinyl acetate 43 4.032 4.032 0.000 97 2392615 100.0 103.3
42 1,1-Dichloroethane 63 4.058 4.058 0.000 97 731811 50.0 47.9
12/27/2024
9:26:49 AM
Page 376 of 428
Report Date: 23-Dec-2024 22:20:05 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005443.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
45 2-Butanone (MEK) 43 4.450 4.450 0.000 100 3130173 200.0 182.7
47 cis-1,2-Dichloroethene 96 4.482 4.482 0.000 85 442363 50.0 47.1
48 2,2-Dichloropropane 77 4.492 4.492 0.000 87 605317 50.0 48.7
50 sec-Butyl Alcohol 45 4.566 4.566 0.000 99 4892133 1200.0 1151.7
52 Chlorobromomethane 128 4.662 4.662 0.000 97 209484 50.0 48.7
53 Tetrahydrofuran 42 4.672 4.672 0.000 86 947084 100.0 90.9
54 Chloroform 83 4.720 4.720 0.000 94 717169 50.0 47.3
55 1,1,1-Trichloroethane 97 4.871 4.871 0.000 98 583948 50.0 47.3
56 Cyclohexane 56 4.935 4.935 0.000 90 675392 50.0 45.8
57 1,1-Dichloropropene 75 4.987 4.987 0.000 98 567109 50.0 46.7
59 Carbon tetrachloride 117 4.993 4.993 0.000 41 432373 50.0 43.4
58 Isobutyl alcohol 41 4.996 4.996 0.000 94 1986816 1250.0 1234.1
60 Benzene 78 5.144 5.144 0.000 96 1635222 50.0 47.1
61 1,2-Dichloroethane 62 5.170 5.170 0.000 97 618184 50.0 44.6
63 n-Heptane 43 5.328 5.328 0.000 92 532097 50.0 46.6
65 Trichloroethene 95 5.639 5.639 0.000 98 410490 50.0 49.4
66 2-Pentanone 43 5.739 5.739 0.000 99 3589912 160.0 150.8
67 Methylcyclohexane 55 5.842 5.842 0.000 90 536247 50.0 45.7
69 1,2-Dichloropropane 63 5.848 5.848 0.000 94 435222 50.0 47.9
70 1,4-Dioxane 88 5.893 5.893 0.000 92 299587 1000.0 1091.5
71 Dibromomethane 93 5.919 5.919 0.000 95 287352 50.0 46.1
72 Dichlorobromomethane 83 6.045 6.045 0.000 99 513204 50.0 49.0
74 2-Chloroethyl vinyl ether 63 6.247 ND ND
75 cis-1,3-Dichloropropene 75 6.398 6.398 0.000 95 721096 50.0 51.6
76 4-Methyl-2-pentanone (MIBK) 43 6.501 6.501 0.000 96 4378536 200.0 190.8
77 Toluene 91 6.694 6.694 0.000 98 1752546 50.0 46.4
78 trans-1,3-Dichloropropene 75 6.868 6.868 0.000 98 649583 50.0 42.1
79 Ethyl methacrylate 69 6.884 6.884 0.000 90 821313 50.0 50.6
80 1,1,2-Trichloroethane 97 7.048 7.048 0.000 92 423894 50.0 47.6
82 Tetrachloroethene 164 7.147 7.147 0.000 95 303929 50.0 47.6
83 1,3-Dichloropropane 76 7.196 7.196 0.000 92 769931 50.0 48.1
84 2-Hexanone 43 7.212 7.212 0.000 97 3701631 200.0 191.8
85 Chlorodibromomethane 129 7.395 7.395 0.000 91 383814 50.0 44.8
86 Ethylene Dibromide 107 7.514 7.514 0.000 98 464154 50.0 48.4
87 1-Chlorohexane 91 7.906 7.906 0.000 98 451818 40.0 37.1
88 Chlorobenzene 112 7.955 7.955 0.000 93 1126275 50.0 47.2
89 1,1,1,2-Tetrachloroethane 131 8.025 8.025 0.000 94 366566 50.0 51.2
90 Ethylbenzene 106 8.032 8.032 0.000 99 596079 50.0 47.8
91 m-Xylene & p-Xylene 106 8.144 8.144 0.000 99 739892 50.0 47.1
92 o-Xylene 106 8.514 8.514 0.000 97 737748 50.0 48.0
93 Styrene 104 8.527 8.527 0.000 95 1263907 50.0 49.6
94 Bromoform 173 8.713 8.713 0.000 94 277619 50.0 42.1
95 Isopropylbenzene 105 8.858 8.858 0.000 96 1733089 50.0 47.7
97 Cyclohexanone 55 8.961 8.961 0.000 93 2801706 1500.0 1646.5
98 1,1,2,2-Tetrachloroethane 83 9.141 9.141 0.000 95 779989 50.0 49.7
99 trans-1,4-Dichloro-2-butene 53 9.180 9.180 0.000 86 234975 50.0 41.5
100 Bromobenzene 156 9.183 9.183 0.000 98 450645 50.0 47.2
101 1,2,3-Trichloropropane 110 9.209 9.209 0.000 83 272594 50.0 48.3
102 N-Propylbenzene 120 9.260 9.260 0.000 99 483884 50.0 46.7
103 2-Chlorotoluene 126 9.360 9.360 0.000 95 426768 50.0 46.7
104 1,3,5-Trimethylbenzene 105 9.430 9.430 0.000 95 1524905 50.0 47.5
105 4-Chlorotoluene 126 9.479 9.479 0.000 98 447805 50.0 47.0
12/27/2024
9:26:49 AM
Page 377 of 428
Report Date: 23-Dec-2024 22:20:05 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005443.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
107 tert-Butylbenzene 119 9.745 9.745 0.000 93 1328213 50.0 46.4
108 1,2,4-Trimethylbenzene 105 9.803 9.803 0.000 98 1602597 50.0 48.4
109 sec-Butylbenzene 134 9.971 9.971 0.000 95 382966 50.0 46.8
110 1,3-Dichlorobenzene 146 10.099 10.099 0.000 97 872153 50.0 46.8
111 4-Isopropyltoluene 119 10.115 10.115 0.000 97 1658814 50.0 47.7
112 1,4-Dichlorobenzene 146 10.199 10.199 0.000 94 872144 50.0 46.3
114 n-Butylbenzene 91 10.524 10.524 0.000 98 1571974 50.0 47.1
115 1,2-Dichlorobenzene 146 10.562 10.562 0.000 96 864142 50.0 48.4
116 1,2-Dibromo-3-Chloropropane 157 11.347 11.347 0.000 81 250444 50.0 42.1
118 1,2,4-Trichlorobenzene 180 12.183 12.183 0.000 93 550939 50.0 48.1
119 Hexachlorobutadiene 225 12.324 12.324 0.000 97 224444 50.0 46.4
120 Naphthalene 128 12.456 12.456 0.000 97 2260730 50.0 44.9
121 1,2,3-Trichlorobenzene 180 12.678 12.678 0.000 94 531611 50.0 46.0
136 Butadiene 54 0.000 ND ND
S 155 Xylenes, Total 106 0 100.0 95.1
S 152 Trihalomethanes, Total 1 0 200.0 183.3
S 154 1,3-Dichloropropene, Total 1 0 100.0 93.7
S 151 1,2-Dichloroethene, Total 1 0 100.0 95.2
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
MV-MegaMainA_00121 Amount Added: 25.00 Units: uL
MV-Gas A_00206 Amount Added: 10.00 Units: uL
mv-IS_SS_00094 Amount Added: 5.00 Units: uL Run Reagent
12/27/2024
9:26:49 AM
Page 378 of 428
Report Date: 23-Dec-2024 22:20:05 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005443.D
Injection Date:23-Dec-2024 17:23:03 Instrument ID:VMS_MS14 Operator ID:MED
Lims ID:CCV Worklist Smp#:2
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:26
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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12/27/2024
9:26:49 AM
Page 379 of 428
Report Date: 13-Dec-2024 23:33:56 Chrom Revision: 2.3 10-Dec-2024 14:14:50
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241213-140794.b\VMS14_0000005135.D
Lims ID:BFB
Client ID:
Sample Type:BFB
Inject. Date:13-Dec-2024 18:15:20 ALS Bottle#:0 Worklist Smp#:1
Injection Vol:2.0 uL Dil. Factor:1.0000
Sample Info:BFB
Operator ID:bustillose Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241213-140794.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:13-Dec-2024 23:33:56 Calib Date:13-Dec-2024 20:55:31
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241213-140794.b\VMS14_0000005143.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1694
First Level Reviewer: LP8K Date:13-Dec-2024 18:30:18
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
$ 8 BFB 95 9.032 9.032 0.000 83 652332 NR NR
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
Reagents:
mv-Cent BFB_00008 Amount Added: 5.00 Units: uL
12/27/2024
9:26:49 AM
Page 380 of 428
Report Date: 13-Dec-2024 23:33:56 Chrom Revision: 2.3 10-Dec-2024 14:14:50
MS Tune Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241213-140794.b\VMS14_0000005135.D
Injection Date:13-Dec-2024 18:15:20 Instrument ID:VMS_MS14
Lims ID:BFB
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:1
Injection Vol:2.0 uL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Tune Method: BFB Method 8260
$ 8 BFB
30 50 70 90 110 130 150 170 190 210 230 250 270 290
m/z
0
3
6
9
12
15
18
21
24
27
30
33
36
Y ( X10
0
0
0
)
Tune Spec :Average 2501-2503( 9.03-9.04 ) Bgrd 2488( 8.99) Apex 2502( 9.03)
95
174 176
75
50 74
94
9651
m/z Ion Abundance Criteria %Relative
Abundance
95 Base peak,100%relative abundance 100.0
50 15 to 40%of m/z 95 19.6
75 30 to 60%of m/z 95 50.7
96 5 to 9%of m/z 95 6.8
173 Less than 2%of m/z 174 0.3 (0.4)
174 50 to 120%of m/z 95 71.4
175 5 to 9%of m/z 174 5.6 (7.9)
176 Greater than 95%but less than 101%of m/z 174 68.8 (96.4)
177 5 to 9%of m/z 176 4.3 (6.3)
12/27/2024
9:26:49 AM
Page 381 of 428
Report Date: 13-Dec-2024 23:33:56 Chrom Revision: 2.3 10-Dec-2024 14:14:50
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241213-140794.b\VMS14_0000005135.D\AQ_VMS14_8260.rslt\spectra.d
Injection Date:13-Dec-2024 18:15:20
Spectrum:Tune Spec :Average 2501-2503( 9.03-9.04 ) Bgrd 2488( 8.99) Apex 2502( 9.03)
Base Peak:95.10
Minimum % Base Peak:0
Number of Points:98
m/z Y m/z Y m/z Y m/z Y
36.00 3622 67.00 1147 95.00 378624 141.00 3267
37.00 18736 68.00 38720 96.00 25912 142.00 450
38.00 16255 69.00 37712 97.00 785 143.00 2902
39.00 6192 70.00 3058 104.00 1439 144.00 94
40.00 545 71.00 104 105.00 599 145.00 577
41.00 221 72.00 1864 106.00 1760 146.00 401
43.00 425 73.00 17320 107.00 167 147.00 102
44.00 1721 74.00 62296 110.00 103 148.00 843
45.00 3043 75.00 191936 111.00 333 150.00 388
46.00 141 76.00 17352 112.00 234 152.00 197
47.00 4706 77.00 1896 113.00 206 153.00 128
48.00 1945 78.00 1670 115.00 356 155.00 848
49.00 15379 79.00 9955 116.00 1224 157.00 526
50.00 74112 80.00 2989 117.00 1994 159.00 452
51.00 22272 81.00 10591 118.00 1307 161.00 304
52.00 1200 82.00 2122 119.00 2145 172.00 255
55.00 1383 83.00 91 126.00 100 173.00 1199
56.00 5788 86.00 117 128.00 1292 174.00 270336
57.00 9932 86.00 343 129.00 562 175.00 21328
58.00 335 87.00 15032 130.00 1182 176.00 260480
60.00 3965 88.00 14839 131.00 560 177.00 16309
61.00 18280 91.00 1381 134.00 100 178.00 242
62.00 17024 92.00 10417 135.00 722 281.00 221
63.00 13491 93.00 16123 137.00 510
64.00 1667 94.00 44632 140.00 92
12/27/2024
9:26:49 AM
Page 382 of 428
Report Date: 13-Dec-2024 23:33:56 Chrom Revision: 2.3 10-Dec-2024 14:14:50
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241213-140794.b\VMS14_0000005135.D
Injection Date:13-Dec-2024 18:15:20 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:BFB Worklist Smp#:1
Client ID:
Injection Vol:2.0 uL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
Y ( X10
0
0
0
0
)
0000005135[MS Quad Chro]:Total
$ B
F
B
(
9
.
0
3
2
)
12/27/2024
9:26:49 AM
Page 383 of 428
Report Date: 18-Dec-2024 07:40:28 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005222.D
Lims ID:BFB
Client ID:
Sample Type:BFB
Inject. Date:16-Dec-2024 23:25:33 ALS Bottle#:0 Worklist Smp#:1
Injection Vol:2.0 uL Dil. Factor:1.0000
Sample Info:BFB
Operator ID:bustillose Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:18-Dec-2024 07:40:28 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1695
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
$ 8 BFB 95 9.032 9.032 0.000 83 943187 NR NR
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
Reagents:
mv-Cent BFB_00008 Amount Added: 5.00 Units: uL
12/27/2024
9:26:49 AM
Page 384 of 428
Report Date: 18-Dec-2024 07:40:28 Chrom Revision: 2.3 17-Dec-2024 12:44:46
MS Tune Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005222.D
Injection Date:16-Dec-2024 23:25:33 Instrument ID:VMS_MS14
Lims ID:BFB
Client ID:
Operator ID:bustillose ALS Bottle#:0 Worklist Smp#:1
Injection Vol:2.0 uL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Tune Method: BFB Method 8260
$ 8 BFB
30 50 70 90 110 130 150 170 190 210 230 250 270 290
m/z
0
4
8
12
16
20
24
28
32
36
40
44
48
52
Y ( X10
0
0
0
)
Tune Spec :Average 2501-2503( 9.03-9.04 ) Bgrd 2487( 8.98) Apex 2502( 9.03)
95
174 176
75
50 74
9469 96
m/z Ion Abundance Criteria %Relative
Abundance
95 Base peak,100%relative abundance 100.0
50 15 to 40%of m/z 95 19.4
75 30 to 60%of m/z 95 51.2
96 5 to 9%of m/z 95 6.8
173 Less than 2%of m/z 174 0.4 (0.5)
174 50 to 120%of m/z 95 72.0
175 5 to 9%of m/z 174 5.3 (7.4)
176 Greater than 95%but less than 101%of m/z 174 68.5 (95.1)
177 5 to 9%of m/z 176 4.5 (6.6)
12/27/2024
9:26:49 AM
Page 385 of 428
Report Date: 18-Dec-2024 07:40:28 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005222.D\AQ_VMS14_8260.rslt\spectra.d
Injection Date:16-Dec-2024 23:25:33
Spectrum:Tune Spec :Average 2501-2503( 9.03-9.04 ) Bgrd 2487( 8.98) Apex 2502( 9.03)
Base Peak:95.10
Minimum % Base Peak:0
Number of Points:107
m/z Y m/z Y m/z Y m/z Y
36.00 4882 67.00 1618 103.00 227 142.00 828
37.00 27688 68.00 54672 104.00 1978 143.00 4843
38.00 24216 69.00 55208 105.00 948 144.00 257
39.00 9067 70.00 4446 106.00 1969 145.00 355
40.00 299 71.00 105 107.00 501 146.00 687
41.00 184 72.00 3185 110.00 467 147.00 364
43.00 291 73.00 23408 111.00 589 148.00 1189
44.00 2992 74.00 91504 113.00 441 149.00 394
45.00 4820 75.00 277888 115.00 570 150.00 576
46.00 260 76.00 22456 116.00 1568 152.00 108
47.00 7875 77.00 3212 117.00 3066 153.00 511
48.00 3778 78.00 2152 118.00 1737 154.00 448
49.00 22864 79.00 14297 119.00 2639 155.00 1295
50.00 105448 80.00 4161 125.00 92 157.00 815
51.00 32608 81.00 15177 126.00 151 159.00 595
52.00 1717 82.00 3066 127.00 145 161.00 507
53.00 105 83.00 383 128.00 1839 171.00 96
55.00 1578 86.00 482 129.00 861 172.00 426
56.00 8489 87.00 22344 130.00 1984 173.00 2060
57.00 13677 88.00 23248 131.00 640 174.00 390656
58.00 623 91.00 1460 134.00 100 175.00 28952
60.00 4958 92.00 14566 135.00 904 176.00 371520
61.00 26000 93.00 21680 136.00 93 177.00 24528
62.00 24320 94.00 60200 137.00 798 178.00 921
63.00 18192 95.00 542336 139.00 183 281.00 943
64.00 1859 96.00 36712 140.00 238 282.00 323
65.00 126 97.00 1301 141.00 4525
12/27/2024
9:26:49 AM
Page 386 of 428
Report Date: 18-Dec-2024 07:40:28 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005222.D
Injection Date:16-Dec-2024 23:25:33 Instrument ID:VMS_MS14 Operator ID:bustillose
Lims ID:BFB Worklist Smp#:1
Client ID:
Injection Vol:2.0 uL Dil. Factor:1.0000 ALS Bottle#:0
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
Y ( X10
0
0
0
0
)
0000005222[MS Quad Chro]:Total
$ B
F
B
(
9
.
0
3
2
)
12/27/2024
9:26:49 AM
Page 387 of 428
Report Date: 27-Dec-2024 10:19:19 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005443a.D
Lims ID:BFB
Client ID:
Sample Type:BFB
Inject. Date:23-Dec-2024 17:23:03 ALS Bottle#:26 Worklist Smp#:1
Injection Vol:2.0 uL Dil. Factor:1.0000
Sample Info:ccv
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:27-Dec-2024 10:19:19 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1607
First Level Reviewer: RGG9 Date:27-Dec-2024 10:19:19
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
$ 8 BFB 95 9.032 9.032 0.000 83 799986 NR NR
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
Reagents:
mv-Cent BFB_00008 Amount Added: 5.00 Units: uL
12/27/2024
9:26:49 AM
Page 388 of 428
Report Date: 27-Dec-2024 10:19:19 Chrom Revision: 2.3 17-Dec-2024 12:44:46
MS Tune Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005443a.D
Injection Date:23-Dec-2024 17:23:03 Instrument ID:VMS_MS14
Lims ID:BFB
Client ID:
Operator ID:MED ALS Bottle#:26 Worklist Smp#:1
Injection Vol:2.0 uL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Tune Method: BFB Method 8260
$ 8 BFB
30 50 70 90 110 130 150 170 190 210 230 250 270 290
m/z
0
4
8
12
16
20
24
28
32
36
40
44
48
Y ( X10
0
0
0
)
Tune Spec :Average 2501-2503( 9.03-9.03 ) Bgrd 2487( 8.98) Apex 2502( 9.03)
95
174 176
75
50 74
9468 96
m/z Ion Abundance Criteria %Relative
Abundance
95 Base peak,100%relative abundance 100.0
50 15 to 40%of m/z 95 17.4
75 30 to 60%of m/z 95 48.7
96 5 to 9%of m/z 95 6.5
173 Less than 2%of m/z 174 0.4 (0.5)
174 50 to 120%of m/z 95 71.6
175 5 to 9%of m/z 174 5.4 (7.5)
176 Greater than 95%but less than 101%of m/z 174 69.4 (96.9)
177 5 to 9%of m/z 176 4.9 (7.1)
12/27/2024
9:26:49 AM
Page 389 of 428
Report Date: 27-Dec-2024 10:19:19 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005443a.D\AQ_VMS14_8260.rslt\spectra.d
Injection Date:23-Dec-2024 17:23:03
Spectrum:Tune Spec :Average 2501-2503( 9.03-9.03 ) Bgrd 2487( 8.98) Apex 2502( 9.03)
Base Peak:95.10
Minimum % Base Peak:0
Number of Points:89
m/z Y m/z Y m/z Y m/z Y
36.00 3707 76.00 21096 112.00 218 147.00 217
37.00 20312 77.00 1756 113.00 271 148.00 956
38.00 14046 78.00 2073 115.00 463 149.00 116
44.00 469 79.00 7758 116.00 1484 150.00 482
45.00 4450 81.00 11095 117.00 2429 152.00 86
46.00 269 82.00 1762 118.00 1676 153.00 282
47.00 5765 85.00 1022 119.00 1950 154.00 115
48.00 2401 86.00 660 123.00 108 155.00 1001
49.00 19688 87.00 20240 128.00 1386 157.00 940
50.00 82000 88.00 20368 129.00 916 159.00 377
51.00 20336 91.00 1570 130.00 1233 161.00 401
57.00 10122 92.00 12825 131.00 593 171.00 225
58.00 134 93.00 18440 134.00 86 172.00 260
60.00 4127 94.00 53688 135.00 1080 173.00 1713
61.00 21592 95.00 472128 137.00 1353 174.00 338048
62.00 20048 96.00 30792 139.00 100 175.00 25456
63.00 13391 103.00 247 140.00 192 176.00 327552
64.00 1405 104.00 1572 141.00 3833 177.00 23112
68.00 43744 105.00 727 142.00 401 178.00 610
72.00 2967 106.00 1817 143.00 3273 281.00 222
73.00 20040 107.00 532 144.00 108
74.00 77352 110.00 382 145.00 440
75.00 229696 111.00 151 146.00 734
12/27/2024
9:26:49 AM
Page 390 of 428
Report Date: 27-Dec-2024 10:19:19 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005443a.D
Injection Date:23-Dec-2024 17:23:03 Instrument ID:VMS_MS14 Operator ID:MED
Lims ID:BFB Worklist Smp#:1
Client ID:
Injection Vol:2.0 uL Dil. Factor:1.0000 ALS Bottle#:26
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0
Min
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
Y ( X10
0
0
0
0
)
000005443a[MS Quad Chro]:Total
$ B
F
B
(
9
.
0
3
2
)
12/27/2024
9:26:49 AM
Page 391 of 428
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:MB 280-679543/9
Matrix:VMS14_0000005449.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:12/23/2024 19:23
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:679543 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.14100-41-4 Ethylbenzene ND
1.0 0.13100-42-5 Styrene ND
1.0 0.1610061-01-5 cis-1,3-Dichloropropene ND
1.0 0.1410061-02-6 trans-1,3-Dichloropropene ND
1.0 0.18103-65-1 N-Propylbenzene ND
1.0 0.23104-51-8 n-Butylbenzene ND
1.0 0.21106-43-4 4-Chlorotoluene ND
1.0 0.39106-46-7 1,4-Dichlorobenzene ND
1.0 0.18106-93-4 Ethylene Dibromide ND
2.0 0.46107-05-1 3-Chloro-1-propene ND
1.0 0.28107-06-2 1,2-Dichloroethane ND
3.0 0.36108-05-4 Vinyl acetate ND
5.0 0.98108-10-1 4-Methyl-2-pentanone (MIBK)ND
1.0 0.12108-67-8 1,3,5-Trimethylbenzene ND
1.0 0.19108-86-1 Bromobenzene ND
1.0 0.31108-87-2 Methylcyclohexane ND
1.0 0.32108-88-3 Toluene ND
1.0 0.092108-90-7 Chlorobenzene ND
7.0 0.84109-99-9 Tetrahydrofuran ND
2.0 0.16110-54-3 Hexane ND
1.0 0.44110-82-7 Cyclohexane ND
1.0 0.58120-82-1 1,2,4-Trichlorobenzene ND
1.0 0.28124-48-1 Chlorodibromomethane ND
1.0 0.40127-18-4 Tetrachloroethene ND
1.0 0.20135-98-8 sec-Butylbenzene ND
1.0 0.17142-28-9 1,3-Dichloropropane ND
1.0 0.32156-59-2 cis-1,2-Dichloroethene ND
1.0 0.37156-60-5 trans-1,2-Dichloroethene ND
5.0 0.251634-04-4 Methyl tert-butyl ether ND
2.0 0.36179601-23-1 m-Xylene & p-Xylene ND
1.0 0.33541-73-1 1,3-Dichlorobenzene ND
1.0 0.2356-23-5 Carbon tetrachloride ND
FORM I 8260D
12/27/2024
9:26:49 AM
Page 392 of 428
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:MB 280-679543/9
Matrix:VMS14_0000005449.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:12/23/2024 19:23
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:679543 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.19563-58-6 1,1-Dichloropropene ND
5.0 0.81591-78-6 2-Hexanone ND
1.0 0.17594-20-7 2,2-Dichloropropane ND
2.0 0.3560-29-7 Ethyl ether ND
1.0 0.16630-20-6 1,1,1,2-Tetrachloroethane ND
15 6.667-64-1 Acetone ND
1.0 0.3667-66-3 Chloroform ND
1.0 0.1471-43-2 Benzene ND
1.0 0.3971-55-6 1,1,1-Trichloroethane ND
5.0 2.474-83-9 Bromomethane ND
2.0 0.2374-87-3 Chloromethane ND
5.0 2.674-88-4 Iodomethane ND
1.0 0.3474-95-3 Dibromomethane ND
1.0 0.4074-97-5 Chlorobromomethane ND
2.0 0.6475-00-3 Chloroethane ND
1.0 0.2375-01-4 Vinyl chloride ND
2.0 0.9475-09-2 Methylene Chloride ND
2.0 0.2675-15-0 Carbon disulfide ND
2.0 0.2575-25-2 Bromoform ND
1.0 0.1975-27-4 Dichlorobromomethane ND
1.0 0.2275-34-3 1,1-Dichloroethane ND
1.0 0.2375-35-4 1,1-Dichloroethene ND
2.0 0.2075-69-4 Trichlorofluoromethane ND
2.0 0.3075-71-8 Dichlorodifluoromethane ND
3.0 0.7376-13-1 1,1,2-Trichloro-1,2,2-trifluoroethan
e
ND
1.0 0.2478-87-5 1,2-Dichloropropane ND
10 4.678-93-3 2-Butanone (MEK)ND
1.0 0.2779-00-5 1,1,2-Trichloroethane ND
1.0 0.3079-01-6 Trichloroethene ND
5.0 1.679-20-9 Methyl acetate ND
1.0 0.2179-34-5 1,1,2,2-Tetrachloroethane ND
4.0 1.287-61-6 1,2,3-Trichlorobenzene ND
FORM I 8260D
12/27/2024
9:26:49 AM
Page 393 of 428
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:MB 280-679543/9
Matrix:VMS14_0000005449.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:12/23/2024 19:23
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:679543 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
2.0 0.5387-68-3 Hexachlorobutadiene ND
3.0 0.9991-20-3 Naphthalene ND
1.0 0.1195-47-6 o-Xylene ND
1.0 0.3495-49-8 2-Chlorotoluene ND
1.0 0.1495-50-1 1,2-Dichlorobenzene ND
1.0 0.1595-63-6 1,2,4-Trimethylbenzene ND
5.0 0.4296-12-8 1,2-Dibromo-3-Chloropropane ND
2.5 0.2896-18-4 1,2,3-Trichloropropane ND
3.0 0.1997-63-2 Ethyl methacrylate ND
1.0 0.1898-06-6 tert-Butylbenzene ND
1.0 0.1698-82-8 Isopropylbenzene ND
1.0 0.1999-87-6 4-Isopropyltoluene ND
1.0 0.111330-20-7 Xylenes, Total ND
1.0 0.32540-59-0 1,2-Dichloroethene, Total ND
1.0 0.14542-75-6 1,3-Dichloropropene, Total ND
1.0 0.19STL00209Trihalomethanes, Total ND
1.0 0.14STL00431Total BTEX ND
%RECCAS NO.LIMITSQSURROGATE
97 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr)
94 77-1201868-53-7 Dibromofluoromethane (Surr)
104 80-1252037-26-5 Toluene-d8 (Surr)
99 78-120460-00-4 4-Bromofluorobenzene (Surr)
FORM I 8260D
12/27/2024
9:26:49 AM
Page 394 of 428
Report Date: 26-Dec-2024 14:02:37 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005449.D
Lims ID:MB
Client ID:
Sample Type:MB
Inject. Date:23-Dec-2024 19:23:13 ALS Bottle#:32 Worklist Smp#:9
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:mb
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:26-Dec-2024 14:02:36 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1655
First Level Reviewer: BX8N Date:26-Dec-2024 14:02:36
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 98 2261628 50.0 50.0
* 2 Chlorobenzene-d5 119 7.926 7.926 0.000 88 497889 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.170 10.173 -0.003 97 811540 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.842 4.842 0.000 93 539868 50.0 47.0
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.112 -0.003 98 743331 50.0 48.6
$ 6 Toluene-d8 (Surr) 98 6.636 6.636 0.000 94 2212209 50.0 52.0
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 84 819367 50.0 49.4
$ 8 BFB 95 9.032 9.032 0.000 84 819367 NR
9 Chlorotrifluoroethene 116 1.677 ND
10 Dichlorodifluoromethane 85 1.794 ND
11 Ethylene oxide 43 1.765 1.843 -0.078 75 3979 1.08
12 Chloromethane 50 1.974 ND
13 Vinyl chloride 62 2.090 ND
14 2-Chloro-1,1,1-Trifluoroethane 118 2.110 ND
15 Bromomethane 94 2.399 2.395 0.004 33 953 1.43
16 Chloroethane 64 2.495 ND
17 Dichlorofluoromethane 67 2.678 ND
18 Trichlorofluoromethane 101 2.717 ND
19 Propene oxide 58 2.738 ND
20 Ethanol 45 2.842 ND
21 Ethyl ether 59 2.939 ND
22 Acrolein 56 3.054 ND
23 1,2-Dichloro-1,1,2-trifluoroetha 117 3.129 ND
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.138 ND
25 1,1-Dichloroethene 96 3.144 ND
26 Acetone 43 3.160 ND 7
27 1,1,1-Trifluoro-2,2-dichloroetha 83 3.213 ND
28 Isopropyl alcohol 45 3.251 ND
29 Iodomethane 142 3.270 ND
30 Carbon disulfide 76 3.337 ND MU
31 Acetonitrile 41 3.379 ND
32 Methyl acetate 43 3.395 ND
12/27/2024
9:26:49 AM
Page 395 of 428
Report Date: 26-Dec-2024 14:02:37 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005449.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
33 3-Chloro-1-propene 41 3.421 ND
34 Methylene Chloride 84 3.514 3.521 -0.007 98 4221 0.3765
35 2-Methyl-2-propanol 59 3.579 3.566 0.013 88 3873 0.5670 M
36 Acrylonitrile 53 3.685 ND
37 Methyl tert-butyl ether 73 3.713 ND
38 trans-1,2-Dichloroethene 96 3.730 ND
39 Hexane 57 3.932 ND
40 Vinyl acetate 43 4.032 ND
41 Isopropyl ether 87 4.055 ND
42 1,1-Dichloroethane 63 4.058 ND
43 2-Chloro-1,3-butadiene 53 4.116 ND
44 Tert-butyl ethyl ether 59 4.325 ND
45 2-Butanone (MEK) 43 4.450 ND
46 Ethyl acetate 43 4.466 ND 7
47 cis-1,2-Dichloroethene 96 4.482 ND
48 2,2-Dichloropropane 77 4.492 ND
49 Propionitrile 54 4.505 ND
50 sec-Butyl Alcohol 45 4.566 ND
51 Methacrylonitrile 41 4.620 ND
52 Chlorobromomethane 128 4.662 ND
53 Tetrahydrofuran 42 4.672 ND
54 Chloroform 83 4.720 ND
55 1,1,1-Trichloroethane 97 4.871 ND
56 Cyclohexane 56 4.935 ND
57 1,1-Dichloropropene 75 4.987 ND
59 Carbon tetrachloride 117 4.993 ND
58 Isobutyl alcohol 41 4.996 ND 7
60 Benzene 78 5.144 ND
61 1,2-Dichloroethane 62 5.170 ND
62 Tert-amyl methyl ether 73 5.209 ND
63 n-Heptane 43 5.328 ND
64 n-Butanol 56 5.498 ND
65 Trichloroethene 95 5.639 ND
66 2-Pentanone 43 5.739 ND
67 Methylcyclohexane 55 5.842 ND
68 Methyl methacrylate 100 5.845 ND
69 1,2-Dichloropropane 63 5.848 ND
70 1,4-Dioxane 88 5.893 ND
71 Dibromomethane 93 5.919 ND
72 Dichlorobromomethane 83 6.045 ND
73 2-Nitropropane 41 6.215 ND
74 2-Chloroethyl vinyl ether 63 6.247 ND
75 cis-1,3-Dichloropropene 75 6.398 ND
76 4-Methyl-2-pentanone (MIBK) 43 6.501 ND
77 Toluene 91 6.694 ND
78 trans-1,3-Dichloropropene 75 6.868 ND
79 Ethyl methacrylate 69 6.884 ND
80 1,1,2-Trichloroethane 97 7.048 ND
81 Tetrahydrothiophene 60 7.051 ND
82 Tetrachloroethene 164 7.147 ND
83 1,3-Dichloropropane 76 7.196 ND
84 2-Hexanone 43 7.212 ND
12/27/2024
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Page 396 of 428
Report Date: 26-Dec-2024 14:02:37 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005449.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
85 Chlorodibromomethane 129 7.395 ND
86 Ethylene Dibromide 107 7.514 ND
87 1-Chlorohexane 91 7.906 ND U
88 Chlorobenzene 112 7.955 ND
89 1,1,1,2-Tetrachloroethane 131 8.025 ND
90 Ethylbenzene 106 8.032 ND
91 m-Xylene & p-Xylene 106 8.144 ND 7
92 o-Xylene 106 8.514 ND
93 Styrene 104 8.527 ND
94 Bromoform 173 8.713 ND
95 Isopropylbenzene 105 8.858 ND
96 cis-1,4-Dichloro-2-butene 53 8.906 ND
97 Cyclohexanone 55 8.961 ND U
98 1,1,2,2-Tetrachloroethane 83 9.141 ND
99 trans-1,4-Dichloro-2-butene 53 9.180 ND
100 Bromobenzene 156 9.183 ND
101 1,2,3-Trichloropropane 110 9.209 ND
102 N-Propylbenzene 120 9.260 ND
103 2-Chlorotoluene 126 9.360 ND
104 1,3,5-Trimethylbenzene 105 9.430 ND
105 4-Chlorotoluene 126 9.479 ND
106 Pentachloroethane 167 9.479 ND
107 tert-Butylbenzene 119 9.745 ND
108 1,2,4-Trimethylbenzene 105 9.803 ND
109 sec-Butylbenzene 134 9.971 ND
110 1,3-Dichlorobenzene 146 10.099 ND 7
111 4-Isopropyltoluene 119 10.115 ND
112 1,4-Dichlorobenzene 146 10.199 10.199 0.000 73 2574 0.1353
113 1,2,3-Trimethylbenzene 105 10.218 ND
114 n-Butylbenzene 91 10.524 ND 7
115 1,2-Dichlorobenzene 146 10.562 ND
116 1,2-Dibromo-3-Chloropropane 157 11.347 ND
117 1,3,5-Trichlorobenzene 180 11.537 ND 7
118 1,2,4-Trichlorobenzene 180 12.189 12.183 0.006 87 1686 0.1458
119 Hexachlorobutadiene 225 12.324 ND
120 Naphthalene 128 12.453 12.456 -0.003 91 3946 0.6269
121 1,2,3-Trichlorobenzene 180 12.678 ND
134 1,3-Dibromobenzene 1 0.000 ND
144 n-Butyl acetate 43 0.000 ND
126 t-Amyl alcohol 1 0.000 ND
142 4-Bromofluorobenzene 95 0.000 ND
133 1,4-Dibromobenzene 1 0.000 ND
125 Benzene, 1-bromo-4-ethyl- 1 0.000 ND
139 2,2-Dimethylpentane 1 0.000 ND
150 4-Chlorobenzotrifluoride 1 0.000 ND
128 2,4-Dimethylpentane 1 0.000 ND
138 Benzene, 1-bromo-3-fluoro- 1 0.000 ND
146 2,3-Dimethylpentane 1 0.000 ND
148 n-Nonyl Aldehyde 1 0.000 ND
123 Ethyl acrylate 55 0.000 ND
141 Ethylene oxide TIC 1 0.000 ND
149 Dimethyl disulfide 1 0.000 ND
12/27/2024
9:26:49 AM
Page 397 of 428
Report Date: 26-Dec-2024 14:02:37 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005449.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
145 1-Bromo-2-chloroethane 1 0.000 ND
130 Benzyl chloride 126 0.000 ND
136 Butadiene 54 0.000 ND
122 Isooctane 57 0.000 ND
137 1-Chloro-1-fluoroethane TIC 1 0.000 ND
135 1,2-dichloro-4-(trifluoromethyl) 1 0.000 ND
140 2-Methylhexane 1 0.000 ND
143 3-Ethylpentane 1 0.000 ND
147 3-Methylhexane 1 0.000 ND
132 2,2,3-Trimethylbutane 1 0.000 ND
131 1-Chlorohexane TIC 1 0.000 ND
129 3,3-Dimethylpentane 1 0.000 ND
127 Pentachloroethane TIC 1 0.000 ND
124 cis-1,4-Dichloro-2-butene TIC 1 0.000 ND
S 156 Total BTEX 1 0.000 ND 7
S 155 Xylenes, Total 106 0.000 ND 7
S 152 Trihalomethanes, Total 1 0.000 ND 7
S 153 TAH 1 0 0 7
S 154 1,3-Dichloropropene, Total 1 0.000 ND 7
S 151 1,2-Dichloroethene, Total 1 0.000 ND 7
QC Flag Legend
Processing Flags
NR - Missing Quant Standard
7 - Failed Limit of Detection
Review Flags
M - Manually Integrated
U - Marked Undetected
Reagents:
mv-IS_SS_00094 Amount Added: 5.00 Units: uL Run Reagent
12/27/2024
9:26:49 AM
Page 398 of 428
Report Date: 26-Dec-2024 14:02:37 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005449.D
Injection Date:23-Dec-2024 19:23:13 Instrument ID:VMS_MS14 Operator ID:MED
Lims ID:MB Worklist Smp#:9
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:32
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0
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12/27/2024
9:26:49 AM
Page 399 of 428
Report Date: 26-Dec-2024 14:02:37 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005449.D
Lims ID:MB
Client ID:
Sample Type:MB
Inject. Date:23-Dec-2024 19:23:13 ALS Bottle#:32 Worklist Smp#:9
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:mb
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:26-Dec-2024 14:02:36 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1655
First Level Reviewer: BX8N Date:26-Dec-2024 14:02:36
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 47.0 93.94
$5 1,2-Dichloroethane-d4 (Surr)50.0 48.6 97.24
$6 Toluene-d8 (Surr)50.0 52.0 104.09
$7 4-Bromofluorobenzene (Surr)50.0 49.4 98.73
12/27/2024
9:26:49 AM
Page 400 of 428
Report Date: 26-Dec-2024 14:02:37 Chrom Revision: 2.3 17-Dec-2024 12:44:46
User Disabled Compound Report
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005449.D
Injection Date:23-Dec-2024 19:23:13 Instrument ID:VMS_MS14
Lims ID:MB
Client ID:
Operator ID:MED ALS Bottle#:32 Worklist Smp#:9
Purge Vol: 5.000 mL Dil. Factor:1.0000
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column:DB-624 (60.25) ( 0.25 mm)Detector MS SCAN
30 Carbon disulfide, CAS: 75-15-0
Processing Results
30 70 110 150 190 230 270 310 350m/z
0
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9
12
15
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Y ( X10
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)
Raw Spec:Scan 729(3.33)
76
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m/z
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6
8
10
12
Y ( X10
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)
Enhanced Spec:Scan 729(3.33) Bgrd 723( 3.31), Qvalue=60
76
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0
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26
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52
65
78
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( X10
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)
Ref Spec: 30 Carbon disulfide (NIST98.L)
76
78
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RT
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Y ( X10
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0000005449[MS Quad Chro]:m/z 76

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RT
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0000005449[MS Quad Chro]:m/z 78
RT Mass Response Amount
3.33 76.00 1374 0.577702
3.34 78.00 0
Reviewer: BX8N, 26-Dec-2024 14:02:01 -07:00:00 (UTC)
Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
12/27/2024
9:26:49 AM
Page 401 of 428
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LCS 280-679543/4
Matrix:VMS14_0000005443b.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:12/23/2024 17:23
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:679543 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.14100-41-4 Ethylbenzene 47.8
1.0 0.13100-42-5 Styrene 49.6
1.0 0.1610061-01-5 cis-1,3-Dichloropropene 51.6
1.0 0.1410061-02-6 trans-1,3-Dichloropropene 42.1
1.0 0.18103-65-1 N-Propylbenzene 46.7
1.0 0.23104-51-8 n-Butylbenzene 47.1
1.0 0.21106-43-4 4-Chlorotoluene 47.0
1.0 0.39106-46-7 1,4-Dichlorobenzene 46.3
1.0 0.18106-93-4 Ethylene Dibromide 48.4
2.0 0.46107-05-1 3-Chloro-1-propene 46.0
1.0 0.28107-06-2 1,2-Dichloroethane 44.6
3.0 0.36108-05-4 Vinyl acetate 103
5.0 0.98108-10-1 4-Methyl-2-pentanone (MIBK)191
1.0 0.12108-67-8 1,3,5-Trimethylbenzene 47.5
1.0 0.19108-86-1 Bromobenzene 47.2
1.0 0.31108-87-2 Methylcyclohexane 45.7
1.0 0.32108-88-3 Toluene 46.4
1.0 0.092108-90-7 Chlorobenzene 47.2
7.0 0.84109-99-9 Tetrahydrofuran 90.9
2.0 0.16110-54-3 Hexane 46.5
1.0 0.44110-82-7 Cyclohexane 45.8
1.0 0.58120-82-1 1,2,4-Trichlorobenzene 48.1
1.0 0.28124-48-1 Chlorodibromomethane 44.8
1.0 0.40127-18-4 Tetrachloroethene 47.6
1.0 0.20135-98-8 sec-Butylbenzene 46.8
1.0 0.17142-28-9 1,3-Dichloropropane 48.1
1.0 0.32156-59-2 cis-1,2-Dichloroethene 47.1
1.0 0.37156-60-5 trans-1,2-Dichloroethene 48.1
5.0 0.251634-04-4 Methyl tert-butyl ether 43.6
2.0 0.36179601-23-1 m-Xylene & p-Xylene 47.1
1.0 0.33541-73-1 1,3-Dichlorobenzene 46.8
1.0 0.2356-23-5 Carbon tetrachloride 43.4
FORM I 8260D
12/27/2024
9:26:49 AM
Page 402 of 428
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LCS 280-679543/4
Matrix:VMS14_0000005443b.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:12/23/2024 17:23
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:679543 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.19563-58-6 1,1-Dichloropropene 46.7
5.0 0.81591-78-6 2-Hexanone 192
1.0 0.17594-20-7 2,2-Dichloropropane 48.7
2.0 0.3560-29-7 Ethyl ether 49.6
1.0 0.16630-20-6 1,1,1,2-Tetrachloroethane 51.2
15 6.667-64-1 Acetone 185
1.0 0.3667-66-3 Chloroform 47.3
1.0 0.1471-43-2 Benzene 47.1
1.0 0.3971-55-6 1,1,1-Trichloroethane 47.3
5.0 2.474-83-9 Bromomethane 44.5
2.0 0.2374-87-3 Chloromethane 38.4
5.0 2.674-88-4 Iodomethane 45.6
1.0 0.3474-95-3 Dibromomethane 46.1
1.0 0.4074-97-5 Chlorobromomethane 48.7
2.0 0.6475-00-3 Chloroethane 44.8
1.0 0.2375-01-4 Vinyl chloride 42.4
2.0 0.9475-09-2 Methylene Chloride 43.8
2.0 0.2675-15-0 Carbon disulfide 41.6
2.0 0.2575-25-2 Bromoform 42.1
1.0 0.1975-27-4 Dichlorobromomethane 49.0
1.0 0.2275-34-3 1,1-Dichloroethane 47.9
1.0 0.2375-35-4 1,1-Dichloroethene 47.1
2.0 0.2075-69-4 Trichlorofluoromethane 51.0
2.0 0.3075-71-8 Dichlorodifluoromethane 51.0
3.0 0.7376-13-1 1,1,2-Trichloro-1,2,2-trifluoroethan
e
49.0
1.0 0.2478-87-5 1,2-Dichloropropane 47.9
10 4.678-93-3 2-Butanone (MEK)183
1.0 0.2779-00-5 1,1,2-Trichloroethane 47.6
1.0 0.3079-01-6 Trichloroethene 49.4
5.0 1.679-20-9 Methyl acetate 91.9
1.0 0.2179-34-5 1,1,2,2-Tetrachloroethane 49.7
4.0 1.287-61-6 1,2,3-Trichlorobenzene 46.0
FORM I 8260D
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9:26:49 AM
Page 403 of 428
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LCS 280-679543/4
Matrix:VMS14_0000005443b.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:12/23/2024 17:23
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:679543 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
2.0 0.5387-68-3 Hexachlorobutadiene 46.4
3.0 0.9991-20-3 Naphthalene 44.9
1.0 0.1195-47-6 o-Xylene 48.0
1.0 0.3495-49-8 2-Chlorotoluene 46.7
1.0 0.1495-50-1 1,2-Dichlorobenzene 48.4
1.0 0.1595-63-6 1,2,4-Trimethylbenzene 48.4
5.0 0.4296-12-8 1,2-Dibromo-3-Chloropropane 42.1
2.5 0.2896-18-4 1,2,3-Trichloropropane 48.3
3.0 0.1997-63-2 Ethyl methacrylate 50.6
1.0 0.1898-06-6 tert-Butylbenzene 46.4
1.0 0.1698-82-8 Isopropylbenzene 47.7
1.0 0.1999-87-6 4-Isopropyltoluene 47.7
1.0 0.111330-20-7 Xylenes, Total 95.1
1.0 0.32540-59-0 1,2-Dichloroethene, Total 95.2
1.0 0.14542-75-6 1,3-Dichloropropene, Total 93.7
1.0 0.19STL00209Trihalomethanes, Total 183
1.0 0.14STL00431Total BTEX 236
%RECCAS NO.LIMITSQSURROGATE
96 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr)
99 77-1201868-53-7 Dibromofluoromethane (Surr)
99 80-1252037-26-5 Toluene-d8 (Surr)
97 78-120460-00-4 4-Bromofluorobenzene (Surr)
FORM I 8260D
12/27/2024
9:26:49 AM
Page 404 of 428
Report Date: 23-Dec-2024 22:20:08 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005443b.D
Lims ID:LCS
Client ID:
Sample Type:LCS
Inject. Date:23-Dec-2024 17:23:03 ALS Bottle#:26 Worklist Smp#:4
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ccv
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:23-Dec-2024 22:20:06 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1673
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 99 2081420 50.0 50.0
* 2 Chlorobenzene-d5 119 7.926 7.926 0.000 88 501851 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.173 0.000 97 803693 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.839 4.842 -0.003 93 523183 50.0 49.5
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.112 -0.003 99 676522 50.0 48.1
$ 6 Toluene-d8 (Surr) 98 6.636 6.636 0.000 93 2127775 50.0 49.7
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 84 800143 50.0 48.7
10 Dichlorodifluoromethane 85 1.794 1.794 0.000 99 601000 50.0 51.0
12 Chloromethane 50 1.974 1.974 0.000 99 530304 50.0 38.4
13 Vinyl chloride 62 2.090 2.090 0.000 98 448950 50.0 42.4
15 Bromomethane 94 2.395 2.395 0.000 92 328701 50.0 44.5
16 Chloroethane 64 2.495 2.495 0.000 100 301744 50.0 44.8
17 Dichlorofluoromethane 67 2.678 2.678 0.000 97 896155 50.0 50.5
18 Trichlorofluoromethane 101 2.717 2.717 0.000 98 648746 50.0 51.0
21 Ethyl ether 59 2.939 2.939 0.000 91 412897 50.0 49.6
22 Acrolein 56 3.054 3.054 0.000 99 1225047 493.8 511.9
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.138 3.138 0.000 96 256751 50.0 49.0
25 1,1-Dichloroethene 96 3.144 3.144 0.000 96 352584 50.0 47.1
26 Acetone 43 3.160 3.160 0.000 100 1991102 200.0 185.0
29 Iodomethane 142 3.270 3.270 0.000 100 360196 50.0 45.6
30 Carbon disulfide 76 3.337 3.337 0.000 99 1083088 50.0 41.6
32 Methyl acetate 43 3.395 3.395 0.000 98 1773838 100.0 91.9
33 3-Chloro-1-propene 41 3.421 3.421 0.000 90 649416 50.0 46.0
34 Methylene Chloride 84 3.521 3.521 0.000 93 452244 50.0 43.8
35 2-Methyl-2-propanol 59 3.566 3.566 0.000 99 2913986 500.0 463.5
36 Acrylonitrile 53 3.685 3.685 0.000 98 4318802 500.0 461.2
37 Methyl tert-butyl ether 73 3.713 3.713 0.000 94 1330753 50.0 43.6
38 trans-1,2-Dichloroethene 96 3.730 3.730 0.000 97 386031 50.0 48.1
39 Hexane 57 3.932 3.932 0.000 92 540080 50.0 46.5
40 Vinyl acetate 43 4.032 4.032 0.000 97 2392615 100.0 103.3
42 1,1-Dichloroethane 63 4.058 4.058 0.000 97 731811 50.0 47.9
45 2-Butanone (MEK) 43 4.450 4.450 0.000 100 3130173 200.0 182.7
47 cis-1,2-Dichloroethene 96 4.482 4.482 0.000 85 442363 50.0 47.1
12/27/2024
9:26:49 AM
Page 405 of 428
Report Date: 23-Dec-2024 22:20:08 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005443b.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
48 2,2-Dichloropropane 77 4.492 4.492 0.000 87 605317 50.0 48.7
50 sec-Butyl Alcohol 45 4.566 4.566 0.000 99 4892133 1200.0 1151.7
52 Chlorobromomethane 128 4.662 4.662 0.000 97 209484 50.0 48.7
53 Tetrahydrofuran 42 4.672 4.672 0.000 86 947084 100.0 90.9
54 Chloroform 83 4.720 4.720 0.000 94 717169 50.0 47.3
55 1,1,1-Trichloroethane 97 4.871 4.871 0.000 98 583948 50.0 47.3
56 Cyclohexane 56 4.935 4.935 0.000 90 675392 50.0 45.8
57 1,1-Dichloropropene 75 4.987 4.987 0.000 98 567109 50.0 46.7
59 Carbon tetrachloride 117 4.993 4.993 0.000 41 432373 50.0 43.4
58 Isobutyl alcohol 41 4.996 4.996 0.000 94 1986816 1250.0 1234.1
60 Benzene 78 5.144 5.144 0.000 96 1635222 50.0 47.1
61 1,2-Dichloroethane 62 5.170 5.170 0.000 97 618184 50.0 44.6
63 n-Heptane 43 5.328 5.328 0.000 92 532097 50.0 46.6
65 Trichloroethene 95 5.639 5.639 0.000 98 410490 50.0 49.4
66 2-Pentanone 43 5.739 5.739 0.000 99 3589912 160.0 150.8
67 Methylcyclohexane 55 5.842 5.842 0.000 90 536247 50.0 45.7
69 1,2-Dichloropropane 63 5.848 5.848 0.000 94 435222 50.0 47.9
70 1,4-Dioxane 88 5.893 5.893 0.000 92 299587 1000.0 1091.5
71 Dibromomethane 93 5.919 5.919 0.000 95 287352 50.0 46.1
72 Dichlorobromomethane 83 6.045 6.045 0.000 99 513204 50.0 49.0
74 2-Chloroethyl vinyl ether 63 6.247 ND ND
75 cis-1,3-Dichloropropene 75 6.398 6.398 0.000 95 721096 50.0 51.6
76 4-Methyl-2-pentanone (MIBK) 43 6.501 6.501 0.000 96 4378536 200.0 190.8
77 Toluene 91 6.694 6.694 0.000 98 1752546 50.0 46.4
78 trans-1,3-Dichloropropene 75 6.868 6.868 0.000 98 649583 50.0 42.1
79 Ethyl methacrylate 69 6.884 6.884 0.000 90 821313 50.0 50.6
80 1,1,2-Trichloroethane 97 7.048 7.048 0.000 92 423894 50.0 47.6
82 Tetrachloroethene 164 7.147 7.147 0.000 95 303929 50.0 47.6
83 1,3-Dichloropropane 76 7.196 7.196 0.000 92 769931 50.0 48.1
84 2-Hexanone 43 7.212 7.212 0.000 97 3701631 200.0 191.8
85 Chlorodibromomethane 129 7.395 7.395 0.000 91 383814 50.0 44.8
86 Ethylene Dibromide 107 7.514 7.514 0.000 98 464154 50.0 48.4
87 1-Chlorohexane 91 7.906 7.906 0.000 98 451818 40.0 37.1
88 Chlorobenzene 112 7.955 7.955 0.000 93 1126275 50.0 47.2
89 1,1,1,2-Tetrachloroethane 131 8.025 8.025 0.000 94 366566 50.0 51.2
90 Ethylbenzene 106 8.032 8.032 0.000 99 596079 50.0 47.8
91 m-Xylene & p-Xylene 106 8.144 8.144 0.000 99 739892 50.0 47.1
92 o-Xylene 106 8.514 8.514 0.000 97 737748 50.0 48.0
93 Styrene 104 8.527 8.527 0.000 95 1263907 50.0 49.6
94 Bromoform 173 8.713 8.713 0.000 94 277619 50.0 42.1
95 Isopropylbenzene 105 8.858 8.858 0.000 96 1733089 50.0 47.7
97 Cyclohexanone 55 8.961 8.961 0.000 93 2801706 1500.0 1646.5
98 1,1,2,2-Tetrachloroethane 83 9.141 9.141 0.000 95 779989 50.0 49.7
99 trans-1,4-Dichloro-2-butene 53 9.180 9.180 0.000 86 234975 50.0 41.5
100 Bromobenzene 156 9.183 9.183 0.000 98 450645 50.0 47.2
101 1,2,3-Trichloropropane 110 9.209 9.209 0.000 83 272594 50.0 48.3
102 N-Propylbenzene 120 9.260 9.260 0.000 99 483884 50.0 46.7
103 2-Chlorotoluene 126 9.360 9.360 0.000 95 426768 50.0 46.7
104 1,3,5-Trimethylbenzene 105 9.430 9.430 0.000 95 1524905 50.0 47.5
105 4-Chlorotoluene 126 9.479 9.479 0.000 98 447805 50.0 47.0
107 tert-Butylbenzene 119 9.745 9.745 0.000 93 1328213 50.0 46.4
108 1,2,4-Trimethylbenzene 105 9.803 9.803 0.000 98 1602597 50.0 48.4
12/27/2024
9:26:49 AM
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Report Date: 23-Dec-2024 22:20:08 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005443b.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
109 sec-Butylbenzene 134 9.971 9.971 0.000 95 382966 50.0 46.8
110 1,3-Dichlorobenzene 146 10.099 10.099 0.000 97 872153 50.0 46.8
111 4-Isopropyltoluene 119 10.115 10.115 0.000 97 1658814 50.0 47.7
112 1,4-Dichlorobenzene 146 10.199 10.199 0.000 94 872144 50.0 46.3
114 n-Butylbenzene 91 10.524 10.524 0.000 98 1571974 50.0 47.1
115 1,2-Dichlorobenzene 146 10.562 10.562 0.000 96 864142 50.0 48.4
116 1,2-Dibromo-3-Chloropropane 157 11.347 11.347 0.000 81 250444 50.0 42.1
118 1,2,4-Trichlorobenzene 180 12.183 12.183 0.000 93 550939 50.0 48.1
119 Hexachlorobutadiene 225 12.324 12.324 0.000 97 224444 50.0 46.4
120 Naphthalene 128 12.456 12.456 0.000 97 2260730 50.0 44.9
121 1,2,3-Trichlorobenzene 180 12.678 12.678 0.000 94 531611 50.0 46.0
136 Butadiene 54 0.000 ND ND
S 155 Xylenes, Total 106 0 100.0 95.1
S 152 Trihalomethanes, Total 1 0 200.0 183.3
S 154 1,3-Dichloropropene, Total 1 0 100.0 93.7
S 151 1,2-Dichloroethene, Total 1 0 100.0 95.2
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Reagents:
MV-MegaMainA_00121 Amount Added: 25.00 Units: uL
MV-Gas A_00206 Amount Added: 10.00 Units: uL
mv-IS_SS_00094 Amount Added: 5.00 Units: uL Run Reagent
12/27/2024
9:26:49 AM
Page 407 of 428
Report Date: 23-Dec-2024 22:20:08 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005443b.D
Injection Date:23-Dec-2024 17:23:03 Instrument ID:VMS_MS14 Operator ID:MED
Lims ID:LCS Worklist Smp#:4
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:26
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
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12/27/2024
9:26:49 AM
Page 408 of 428
Report Date: 23-Dec-2024 22:20:08 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005443b.D
Lims ID:LCS
Client ID:
Sample Type:LCS
Inject. Date:23-Dec-2024 17:23:03 ALS Bottle#:26 Worklist Smp#:4
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:ccv
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:23-Dec-2024 22:20:06 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1673
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 49.5 98.92
$5 1,2-Dichloroethane-d4 (Surr)50.0 48.1 96.16
$6 Toluene-d8 (Surr)50.0 49.7 99.33
$7 4-Bromofluorobenzene (Surr)50.0 48.7 97.35
12/27/2024
9:26:49 AM
Page 409 of 428
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LCSD 280-679543/5
Matrix:VMS14_0000005445.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:12/23/2024 18:03
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:679543 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.14100-41-4 Ethylbenzene 53.2
1.0 0.13100-42-5 Styrene 53.6
1.0 0.1610061-01-5 cis-1,3-Dichloropropene 57.0
1.0 0.1410061-02-6 trans-1,3-Dichloropropene 44.9
1.0 0.18103-65-1 N-Propylbenzene 52.0
1.0 0.23104-51-8 n-Butylbenzene 52.0
1.0 0.21106-43-4 4-Chlorotoluene 51.8
1.0 0.39106-46-7 1,4-Dichlorobenzene 50.5
1.0 0.18106-93-4 Ethylene Dibromide 53.9
2.0 0.46107-05-1 3-Chloro-1-propene 48.9
1.0 0.28107-06-2 1,2-Dichloroethane 47.6
3.0 0.36108-05-4 Vinyl acetate 111
5.0 0.98108-10-1 4-Methyl-2-pentanone (MIBK)200
1.0 0.12108-67-8 1,3,5-Trimethylbenzene 51.1
1.0 0.19108-86-1 Bromobenzene 53.3
1.0 0.31108-87-2 Methylcyclohexane 49.0
1.0 0.32108-88-3 Toluene 49.6
1.0 0.092108-90-7 Chlorobenzene 52.2
7.0 0.84109-99-9 Tetrahydrofuran 97.6
2.0 0.16110-54-3 Hexane 51.1
1.0 0.44110-82-7 Cyclohexane 49.9
1.0 0.58120-82-1 1,2,4-Trichlorobenzene 54.0
1.0 0.28124-48-1 Chlorodibromomethane 49.4
1.0 0.40127-18-4 Tetrachloroethene 52.9
1.0 0.20135-98-8 sec-Butylbenzene 51.4
1.0 0.17142-28-9 1,3-Dichloropropane 52.6
1.0 0.32156-59-2 cis-1,2-Dichloroethene 50.6
1.0 0.37156-60-5 trans-1,2-Dichloroethene 51.1
5.0 0.251634-04-4 Methyl tert-butyl ether 48.4
2.0 0.36179601-23-1 m-Xylene & p-Xylene 51.4
1.0 0.33541-73-1 1,3-Dichlorobenzene 51.7
1.0 0.2356-23-5 Carbon tetrachloride 47.3
FORM I 8260D
12/27/2024
9:26:49 AM
Page 410 of 428
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LCSD 280-679543/5
Matrix:VMS14_0000005445.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:12/23/2024 18:03
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:679543 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
1.0 0.19563-58-6 1,1-Dichloropropene 50.6
5.0 0.81591-78-6 2-Hexanone 208
1.0 0.17594-20-7 2,2-Dichloropropane 51.4
2.0 0.3560-29-7 Ethyl ether 52.5
1.0 0.16630-20-6 1,1,1,2-Tetrachloroethane 56.5
15 6.667-64-1 Acetone 190
1.0 0.3667-66-3 Chloroform 50.5
1.0 0.1471-43-2 Benzene 50.2
1.0 0.3971-55-6 1,1,1-Trichloroethane 51.2
5.0 2.474-83-9 Bromomethane 46.7
2.0 0.2374-87-3 Chloromethane 38.4
5.0 2.674-88-4 Iodomethane 50.6
1.0 0.3474-95-3 Dibromomethane 48.3
1.0 0.4074-97-5 Chlorobromomethane 51.5
2.0 0.6475-00-3 Chloroethane 49.0
1.0 0.2375-01-4 Vinyl chloride 43.6
2.0 0.9475-09-2 Methylene Chloride 46.4
2.0 0.2675-15-0 Carbon disulfide 44.9
2.0 0.2575-25-2 Bromoform 45.5
1.0 0.1975-27-4 Dichlorobromomethane 52.3
1.0 0.2275-34-3 1,1-Dichloroethane 51.8
1.0 0.2375-35-4 1,1-Dichloroethene 50.1
2.0 0.2075-69-4 Trichlorofluoromethane 50.9
2.0 0.3075-71-8 Dichlorodifluoromethane 52.8
3.0 0.7376-13-1 1,1,2-Trichloro-1,2,2-trifluoroethan
e
51.9
1.0 0.2478-87-5 1,2-Dichloropropane 51.3
10 4.678-93-3 2-Butanone (MEK)189
1.0 0.2779-00-5 1,1,2-Trichloroethane 51.2
1.0 0.3079-01-6 Trichloroethene 55.3
5.0 1.679-20-9 Methyl acetate 97.2
1.0 0.2179-34-5 1,1,2,2-Tetrachloroethane 56.1
4.0 1.287-61-6 1,2,3-Trichlorobenzene 51.4
FORM I 8260D
12/27/2024
9:26:49 AM
Page 411 of 428
FORM I
GC/MS VOA ORGANICS ANALYSIS DATA SHEET
Lab Name:Job No.:280-201015-1Eurofins Denver
SDG No.:
Client Sample ID:Lab Sample ID:LCSD 280-679543/5
Matrix:VMS14_0000005445.DLab File ID:
Date Collected:8260DAnalysis Method:
Water
Sample wt/vol:
% Moisture:
GC Column:Soil Extract Vol.:
Dilution Factor:Soil Aliquot Vol:1
Level: (low/med)Low
5(mL)
0.25(mm)
Date Analyzed:12/23/2024 18:03
ID:DB-624 (60.25)
% Solids:
NHeated Purge: (Y/N)Purge Volume:5.0(mL)pH:
Analysis Batch No.:679543 ug/LUnits:
Preparation Batch No.:Instrument ID:VMS_MS14
CAS NO.COMPOUND NAME RESULT Q MDLRL
2.0 0.5387-68-3 Hexachlorobutadiene 53.9
3.0 0.9991-20-3 Naphthalene 50.0
1.0 0.1195-47-6 o-Xylene 51.8
1.0 0.3495-49-8 2-Chlorotoluene 51.9
1.0 0.1495-50-1 1,2-Dichlorobenzene 53.0
1.0 0.1595-63-6 1,2,4-Trimethylbenzene 52.0
5.0 0.4296-12-8 1,2-Dibromo-3-Chloropropane 46.7
2.5 0.2896-18-4 1,2,3-Trichloropropane 53.2
3.0 0.1997-63-2 Ethyl methacrylate 55.5
1.0 0.1898-06-6 tert-Butylbenzene 52.3
1.0 0.1698-82-8 Isopropylbenzene 53.9
1.0 0.1999-87-6 4-Isopropyltoluene 52.5
1.0 0.111330-20-7 Xylenes, Total 103
1.0 0.32540-59-0 1,2-Dichloroethene, Total 102
1.0 0.14542-75-6 1,3-Dichloropropene, Total 102
1.0 0.19STL00209Trihalomethanes, Total 198
1.0 0.14STL00431Total BTEX 256
%RECCAS NO.LIMITSQSURROGATE
95 70-12717060-07-0 1,2-Dichloroethane-d4 (Surr)
99 77-1201868-53-7 Dibromofluoromethane (Surr)
102 80-1252037-26-5 Toluene-d8 (Surr)
99 78-120460-00-4 4-Bromofluorobenzene (Surr)
FORM I 8260D
12/27/2024
9:26:49 AM
Page 412 of 428
Report Date: 23-Dec-2024 22:20:12 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Target Compound Quantitation Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005445.D
Lims ID:LCSD
Client ID:
Sample Type:LCSD
Inject. Date:23-Dec-2024 18:03:07 ALS Bottle#:28 Worklist Smp#:5
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:lcsd
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:23-Dec-2024 22:20:06 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1673
First Level Reviewer: LP8K Date:23-Dec-2024 18:30:41
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
* 1 Fluorobenzene 96 5.360 5.360 0.000 99 1980065 50.0 50.0
* 2 Chlorobenzene-d5 119 7.929 7.926 0.003 88 457853 50.0 50.0
* 3 1,4-Dichlorobenzene-d4 152 10.173 10.173 0.000 96 708154 50.0 50.0
$ 4 Dibromofluoromethane (Surr) 111 4.839 4.842 -0.003 93 496072 50.0 49.3
$ 5 1,2-Dichloroethane-d4 (Surr) 65 5.109 5.112 -0.003 97 638385 50.0 47.7
$ 6 Toluene-d8 (Surr) 98 6.636 6.636 0.000 94 1997589 50.0 51.1
$ 7 4-Bromofluorobenzene (Surr) 95 9.032 9.032 0.000 85 715737 50.0 49.4
10 Dichlorodifluoromethane 85 1.791 1.794 -0.003 99 591025 50.0 52.8
12 Chloromethane 50 1.974 1.974 0.000 99 504127 50.0 38.4
13 Vinyl chloride 62 2.087 2.090 -0.003 98 439364 50.0 43.6
15 Bromomethane 94 2.399 2.395 0.004 92 328675 50.0 46.7
16 Chloroethane 64 2.495 2.495 0.000 100 314349 50.0 49.0
17 Dichlorofluoromethane 67 2.678 2.678 0.000 97 871625 50.0 51.6
18 Trichlorofluoromethane 101 2.720 2.717 0.003 99 615581 50.0 50.9
21 Ethyl ether 59 2.939 2.939 0.000 91 416531 50.0 52.5
22 Acrolein 56 3.054 3.054 0.000 99 1216166 493.8 534.2
24 1,1,2-Trichloro-1,2,2-trifluoroe 151 3.141 3.138 0.003 96 258754 50.0 51.9
25 1,1-Dichloroethene 96 3.144 3.144 0.000 96 356145 50.0 50.1
26 Acetone 43 3.161 3.160 0.001 100 1945859 200.0 190.3
29 Iodomethane 142 3.270 3.270 0.000 99 383793 50.0 50.6
30 Carbon disulfide 76 3.337 3.337 0.000 99 1114365 50.0 44.9
32 Methyl acetate 43 3.399 3.395 0.003 98 1785352 100.0 97.2
33 3-Chloro-1-propene 41 3.421 3.421 0.000 90 657117 50.0 48.9
34 Methylene Chloride 84 3.517 3.521 -0.004 93 455288 50.0 46.4
35 2-Methyl-2-propanol 59 3.569 3.566 0.003 100 2865992 500.0 479.2
36 Acrylonitrile 53 3.688 3.685 0.003 98 4200911 500.0 471.5
37 Methyl tert-butyl ether 73 3.714 3.713 0.001 94 1404321 50.0 48.4
38 trans-1,2-Dichloroethene 96 3.726 3.730 -0.004 97 389750 50.0 51.1
39 Hexane 57 3.932 3.932 0.000 92 541532 50.0 51.1
40 Vinyl acetate 43 4.032 4.032 0.000 98 2454235 100.0 111.4
42 1,1-Dichloroethane 63 4.058 4.058 0.000 96 754192 50.0 51.8
45 2-Butanone (MEK) 43 4.453 4.450 0.003 100 3081576 200.0 189.0
12/27/2024
9:26:49 AM
Page 413 of 428
Report Date: 23-Dec-2024 22:20:12 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005445.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
47 cis-1,2-Dichloroethene 96 4.482 4.482 0.000 83 452216 50.0 50.6
48 2,2-Dichloropropane 77 4.495 4.492 0.003 87 607030 50.0 51.4
50 sec-Butyl Alcohol 45 4.569 4.566 0.003 99 4924395 1200.0 1218.6
52 Chlorobromomethane 128 4.662 4.662 0.000 97 210841 50.0 51.5
53 Tetrahydrofuran 42 4.672 4.672 0.000 87 967394 100.0 97.6
54 Chloroform 83 4.720 4.720 0.000 93 728206 50.0 50.5
55 1,1,1-Trichloroethane 97 4.874 4.871 0.003 99 602058 50.0 51.2
56 Cyclohexane 56 4.935 4.935 0.000 90 700487 50.0 49.9
57 1,1-Dichloropropene 75 4.987 4.987 0.000 96 584578 50.0 50.6
59 Carbon tetrachloride 117 4.993 4.993 0.000 95 448885 50.0 47.3
58 Isobutyl alcohol 41 5.000 4.996 0.004 95 1996368 1250.0 1303.6
60 Benzene 78 5.144 5.144 0.000 95 1656944 50.0 50.2
61 1,2-Dichloroethane 62 5.170 5.170 0.000 97 628964 50.0 47.6
63 n-Heptane 43 5.331 5.328 0.003 92 530689 50.0 48.9
65 Trichloroethene 95 5.643 5.639 0.004 98 419043 50.0 55.3
66 2-Pentanone 43 5.739 5.739 0.000 99 3579803 160.0 158.0
67 Methylcyclohexane 55 5.842 5.842 0.000 91 546421 50.0 49.0
69 1,2-Dichloropropane 63 5.849 5.848 0.001 93 444132 50.0 51.3
70 1,4-Dioxane 88 5.906 5.893 0.013 93 259043 1000.0 992.1
71 Dibromomethane 93 5.919 5.919 0.000 95 286316 50.0 48.3
72 Dichlorobromomethane 83 6.045 6.045 0.000 99 521183 50.0 52.3
74 2-Chloroethyl vinyl ether 63 6.244 6.247 -0.003 59 6204 50.0 4.28 M
75 cis-1,3-Dichloropropene 75 6.398 6.398 0.000 95 726382 50.0 57.0
76 4-Methyl-2-pentanone (MIBK) 43 6.501 6.501 0.000 96 4373434 200.0 200.3
77 Toluene 91 6.697 6.694 0.003 98 1781992 50.0 49.6
78 trans-1,3-Dichloropropene 75 6.868 6.868 0.000 98 659442 50.0 44.9
79 Ethyl methacrylate 69 6.884 6.884 0.000 90 821885 50.0 55.5
80 1,1,2-Trichloroethane 97 7.045 7.048 -0.003 92 434074 50.0 51.2
82 Tetrachloroethene 164 7.148 7.147 0.001 95 307989 50.0 52.9
83 1,3-Dichloropropane 76 7.196 7.196 0.000 92 766943 50.0 52.6
84 2-Hexanone 43 7.212 7.212 0.000 96 3668327 200.0 208.3
85 Chlorodibromomethane 129 7.392 7.395 -0.003 90 386632 50.0 49.4
86 Ethylene Dibromide 107 7.514 7.514 0.000 98 471292 50.0 53.9
87 1-Chlorohexane 91 7.906 7.906 0.000 98 447788 40.0 40.3
88 Chlorobenzene 112 7.955 7.955 0.000 93 1137807 50.0 52.2
89 1,1,1,2-Tetrachloroethane 131 8.025 8.025 0.000 95 368986 50.0 56.5
90 Ethylbenzene 106 8.029 8.032 -0.003 99 606025 50.0 53.2
91 m-Xylene & p-Xylene 106 8.148 8.144 0.004 100 736872 50.0 51.4
92 o-Xylene 106 8.514 8.514 0.000 97 727009 50.0 51.8
93 Styrene 104 8.527 8.527 0.000 95 1245760 50.0 53.6
94 Bromoform 173 8.710 8.713 -0.003 94 274427 50.0 45.5
95 Isopropylbenzene 105 8.855 8.858 -0.003 96 1724345 50.0 53.9
97 Cyclohexanone 55 8.961 8.961 0.000 93 2687650 1500.0 1731.3
98 1,1,2,2-Tetrachloroethane 83 9.141 9.141 0.000 94 775090 50.0 56.1
99 trans-1,4-Dichloro-2-butene 53 9.176 9.180 -0.004 84 224362 50.0 44.9
100 Bromobenzene 156 9.183 9.183 0.000 97 448260 50.0 53.3
101 1,2,3-Trichloropropane 110 9.209 9.209 0.001 83 264468 50.0 53.2
102 N-Propylbenzene 120 9.260 9.260 0.000 99 474869 50.0 52.0
103 2-Chlorotoluene 126 9.360 9.360 0.000 95 417473 50.0 51.9
104 1,3,5-Trimethylbenzene 105 9.431 9.430 0.000 95 1447681 50.0 51.1
105 4-Chlorotoluene 126 9.479 9.479 0.000 98 434362 50.0 51.8
107 tert-Butylbenzene 119 9.746 9.745 0.001 93 1318245 50.0 52.3
12/27/2024
9:26:49 AM
Page 414 of 428
Report Date: 23-Dec-2024 22:20:12 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005445.D
Compound Sig
RT
(min.)
Exp RT
(min.)
Dlt RT
(min.)Q Response
Cal Amt
ug/l
OnCol Amt
ug/l Flags
108 1,2,4-Trimethylbenzene 105 9.800 9.803 -0.003 98 1515587 50.0 52.0
109 sec-Butylbenzene 134 9.967 9.971 -0.004 95 370518 50.0 51.4
110 1,3-Dichlorobenzene 146 10.099 10.099 0.000 97 847602 50.0 51.7
111 4-Isopropyltoluene 119 10.112 10.115 -0.003 97 1610070 50.0 52.5
112 1,4-Dichlorobenzene 146 10.196 10.199 -0.003 94 837741 50.0 50.5
114 n-Butylbenzene 91 10.524 10.524 0.000 98 1528253 50.0 52.0
115 1,2-Dichlorobenzene 146 10.562 10.562 0.000 96 834500 50.0 53.0
116 1,2-Dibromo-3-Chloropropane 157 11.344 11.347 -0.003 81 245155 50.0 46.7
118 1,2,4-Trichlorobenzene 180 12.180 12.183 -0.003 94 545072 50.0 54.0
119 Hexachlorobutadiene 225 12.318 12.324 -0.006 96 230157 50.0 53.9
120 Naphthalene 128 12.450 12.456 -0.006 98 2221808 50.0 50.0
121 1,2,3-Trichlorobenzene 180 12.675 12.678 -0.003 94 523965 50.0 51.4
136 Butadiene 54 0.000 ND ND
S 155 Xylenes, Total 106 0 100.0 103.2
S 152 Trihalomethanes, Total 1 0 200.0 197.8
S 154 1,3-Dichloropropene, Total 1 0 100.0 101.9
S 151 1,2-Dichloroethene, Total 1 0 100.0 101.7
QC Flag Legend
Processing Flags
ND - Not Detected or Marked ND
Review Flags
M - Manually Integrated
Reagents:
MV-MegaMainA_00121 Amount Added: 25.00 Units: uL
MV-Gas A_00206 Amount Added: 10.00 Units: uL
mv-IS_SS_00094 Amount Added: 5.00 Units: uL Run Reagent
12/27/2024
9:26:49 AM
Page 415 of 428
Report Date: 23-Dec-2024 22:20:12 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005445.D
Injection Date:23-Dec-2024 18:03:07 Instrument ID:VMS_MS14 Operator ID:MED
Lims ID:LCSD Worklist Smp#:5
Client ID:
Purge Vol: 5.000 mL Dil. Factor:1.0000 ALS Bottle#:28
Method:AQ_VMS14_8260 Limit Group:MSV - 8260B Water and Solid
Column: DB-624 (60.25) ( 0.25 mm)Y Scaling: Method Defined: Scale to the Nth Largest Target: 1
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0
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12/27/2024
9:26:49 AM
Page 416 of 428
Report Date: 23-Dec-2024 22:20:12 Chrom Revision: 2.3 17-Dec-2024 12:44:46
Eurofins Denver
Recovery Report
Data File:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\VMS14_0000005445.D
Lims ID:LCSD
Client ID:
Sample Type:LCSD
Inject. Date:23-Dec-2024 18:03:07 ALS Bottle#:28 Worklist Smp#:5
Purge Vol: 5.000 mL Dil. Factor:1.0000
Sample Info:lcsd
Operator ID:MED Instrument ID:VMS_MS14
Method:\\chromfs\Denver\ChromData\VMS_MS14\20241223-141077.b\AQ_VMS14_8260.m
Limit Group:MSV - 8260B Water and Solid
Last Update:23-Dec-2024 22:20:06 Calib Date:17-Dec-2024 03:40:54
Integrator:RTE ID Type: Deconvolution ID
Quant Method:Internal Standard Quant By:Initial Calibration
Last ICal File:\\chromfs\Denver\ChromData\VMS_MS14\20241216-140839.b\VMS14_0000005231.D
Column 1 :DB-624 (60.25) ( 0.25 mm)Det: MS SCAN
Process Host:CTX1673
First Level Reviewer: LP8K Date:23-Dec-2024 18:30:41
Compound
Amount
Added
Amount
Recovered %Rec.
$4 Dibromofluoromethane (Surr)50.0 49.3 98.59
$5 1,2-Dichloroethane-d4 (Surr)50.0 47.7 95.39
$6 Toluene-d8 (Surr)50.0 51.1 102.21
$7 4-Bromofluorobenzene (Surr)50.0 49.4 98.83
12/27/2024
9:26:49 AM
Page 417 of 428
Lab Name:Job No.:
GC/MS VOA ANALYSIS RUN LOG
Eurofins Denver 280-201015-1
SDG No.:
Instrument ID:
Analysis Batch Number:
DILUTION
FACTOR
COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID
VMS_MS14
678523
Start Date:
End Date:12/13/2024 21:55
12/13/2024 18:15
BFB 280-678523/1 DB-624 (60.25) 0.25(mm)112/13/2024 18:15 VMS14_0000005135.D
IC 280-678523/36 DB-624 (60.25) 0.25(mm)112/13/2024 18:35
IC 280-678523/37 DB-624 (60.25) 0.25(mm)112/13/2024 18:55
IC 280-678523/38 DB-624 (60.25) 0.25(mm)112/13/2024 19:15
IC 280-678523/39 DB-624 (60.25) 0.25(mm)112/13/2024 19:35
IC 280-678523/40 DB-624 (60.25) 0.25(mm)112/13/2024 19:55
IC 280-678523/41 DB-624 (60.25) 0.25(mm)112/13/2024 20:15
IC 280-678523/42 DB-624 (60.25) 0.25(mm)112/13/2024 20:35
IC 280-678523/43 DB-624 (60.25) 0.25(mm)112/13/2024 20:55
ICV 280-678523/44 DB-624 (60.25) 0.25(mm)112/13/2024 21:15 VMS14_0000005144.D
ZZZZZ (QC)DB-624 (60.25) 0.25(mm)112/13/2024 21:35
ZZZZZ (QC)DB-624 (60.25) 0.25(mm)112/13/2024 21:55
8260D
12/27/2024
9:26:49 AM
Page 418 of 428
Lab Name:Job No.:
GC/MS VOA ANALYSIS RUN LOG
Eurofins Denver 280-201015-1
SDG No.:
Instrument ID:
Analysis Batch Number:
DILUTION
FACTOR
COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID
VMS_MS14
678685
Start Date:
End Date:12/17/2024 05:02
12/16/2024 23:25
BFB 280-678685/1 DB-624 (60.25) 0.25(mm)112/16/2024 23:25 VMS14_0000005222.D
IC 280-678685/13 DB-624 (60.25) 0.25(mm)112/17/2024 01:00 VMS14_0000005223.D
IC 280-678685/14 DB-624 (60.25) 0.25(mm)112/17/2024 01:20 VMS14_0000005224.D
IC 280-678685/15 DB-624 (60.25) 0.25(mm)112/17/2024 01:40 VMS14_0000005225.D
IC 280-678685/16 DB-624 (60.25) 0.25(mm)112/17/2024 02:00 VMS14_0000005226.D
IC 280-678685/17 DB-624 (60.25) 0.25(mm)112/17/2024 02:20 VMS14_0000005227.D
ICIS 280-678685/18 DB-624 (60.25) 0.25(mm)112/17/2024 02:40 VMS14_0000005228.D
IC 280-678685/19 DB-624 (60.25) 0.25(mm)112/17/2024 03:00 VMS14_0000005229.D
IC 280-678685/20 DB-624 (60.25) 0.25(mm)112/17/2024 03:20 VMS14_0000005230.D
IC 280-678685/21 DB-624 (60.25) 0.25(mm)112/17/2024 03:40 VMS14_0000005231.D
ICV 280-678685/22 DB-624 (60.25) 0.25(mm)112/17/2024 04:21 VMS14_0000005233.D
ZZZZZ (QC)DB-624 (60.25) 0.25(mm)112/17/2024 05:02
8260D
12/27/2024
9:26:49 AM
Page 419 of 428
Lab Name:Job No.:
GC/MS VOA ANALYSIS RUN LOG
Eurofins Denver 280-201015-1
SDG No.:
Instrument ID:
Analysis Batch Number:
DILUTION
FACTOR
COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID
VMS_MS14
679543
Start Date:
End Date:12/24/2024 04:16
12/23/2024 17:23
BFB 280-679543/1 DB-624 (60.25) 0.25(mm)112/23/2024 17:23 VMS14_0000005443a.D
CCV 280-679543/2 DB-624 (60.25) 0.25(mm)112/23/2024 17:23 VMS14_0000005443.D
LCS 280-679543/4 DB-624 (60.25) 0.25(mm)112/23/2024 17:23 VMS14_0000005443b.D
CCV 280-679543/3 DB-624 (60.25) 0.25(mm)112/23/2024 17:43
ZZZZZ (QC)DB-624 (60.25) 0.25(mm)112/23/2024 17:43
LCSD 280-679543/5 DB-624 (60.25) 0.25(mm)112/23/2024 18:03 VMS14_0000005445.D
ZZZZZ (QC)DB-624 (60.25) 0.25(mm)112/23/2024 18:23
MB 280-679543/9 DB-624 (60.25) 0.25(mm)112/23/2024 19:23 VMS14_0000005449.D
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)112/23/2024 20:23
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)112/23/2024 20:43
280-201015-3 FB-02-241217 DB-624 (60.25) 0.25(mm)112/23/2024 21:03 VMS14_0000005452.D
280-201015-4 Trip Blank DB-624 (60.25) 0.25(mm)112/23/2024 21:28 VMS14_0000005453.D
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)112/23/2024 21:48
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)112/23/2024 22:08
280-201015-1 MW-59-241217 DB-624 (60.25) 0.25(mm)112/23/2024 22:28 VMS14_0000005456.D
280-201015-2 DS-02-241217 DB-624 (60.25) 0.25(mm)112/23/2024 22:48 VMS14_0000005457.D
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)112/23/2024 23:08
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)112/23/2024 23:29
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)112/23/2024 23:49
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)112/24/2024 00:09
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)112/24/2024 00:29
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)112/24/2024 00:48
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)112/24/2024 01:08
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)112/24/2024 01:28
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)2512/24/2024 01:51
ZZZZZ (Client)DB-624 (60.25) 0.25(mm)2512/24/2024 02:13
ZZZZZ (QC)DB-624 (60.25) 0.25(mm)112/24/2024 02:36
ZZZZZ (QC)DB-624 (60.25) 0.25(mm)112/24/2024 02:56
ZZZZZ (QC)DB-624 (60.25) 0.25(mm)112/24/2024 03:16
ZZZZZ (QC)DB-624 (60.25) 0.25(mm)112/24/2024 03:36
CCVC 280-679543/35 DB-624 (60.25) 0.25(mm)112/24/2024 03:56
CCVC 280-679543/36 DB-624 (60.25) 0.25(mm)112/24/2024 04:16
8260D
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Lab Name:Job No.:
SDG No.:
GC/MS VOA BATCH WORKSHEET
280-201015-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Bustillos, Ethan T12/13/24 18:15678523
Batch Method:
Eurofins Denver
8260D
Lab Sample ID Client Sample
ID
Method Chain Basis InitialAmount FinalAmount mv-Cent BFB
00008
mv-Cent IS
00009
MV-Supp B
00076
Matrix
2 uL 2 uL 5 uL8260DBFB
280-678523/1
5 mL 5 mL 5 uL 50 uL8260DICV
280-678523/44
Batch Notes
Basis Basis Description
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
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Page 421 of 428
Lab Name:Job No.:
SDG No.:
GC/MS VOA BATCH WORKSHEET
280-201015-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Dobransky, Michael E12/16/24 23:25678685
Batch Method:
Eurofins Denver
8260D
Lab Sample ID Client Sample
ID
Method Chain Basis InitialAmount FinalAmount Cal Dil Std
00438
mv-Cent BFB
00008
MV-Gas A 00206 MV-Gas B 00177Matrix
2 uL 2 uL 5 uL8260DBFB
280-678685/1
5 mL 5 mL 5 uL8260DIC
280-678685/13
5 mL 5 mL 10 uL8260DIC
280-678685/14
5 mL 5 mL 20 uL8260DIC
280-678685/15
5 mL 5 mL 50 uL8260DIC
280-678685/16
5 mL 5 mL 2 uL8260DIC
280-678685/17
5 mL 5 mL 10 uL8260DICIS
280-678685/18
5 mL 5 mL 15 uL8260DIC
280-678685/19
5 mL 5 mL 20 uL8260DIC
280-678685/20
5 mL 5 mL 40 uL8260DIC
280-678685/21
5 mL 5 mL 10 uL8260DICV
280-678685/22
Lab Sample ID Client Sample
ID
Method Chain Basis mv-IS_SS 00093 MV-MegaMain B
00112
MV-MegaMainA
00121
Matrix
8260DBFB
280-678685/1
5 uL8260DIC
280-678685/13
5 uL8260DIC
280-678685/14
5 uL8260DIC
280-678685/15
5 uL8260DIC
280-678685/16
5 uL 5 uL8260DIC
280-678685/17
5 uL 25 uL8260DICIS
280-678685/18
5 uL 37.5 uL8260DIC
280-678685/19
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
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Lab Name:Job No.:
SDG No.:
GC/MS VOA BATCH WORKSHEET
280-201015-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Dobransky, Michael E12/16/24 23:25678685
Batch Method:
Eurofins Denver
8260D
Lab Sample ID Client Sample
ID
Method Chain Basis mv-IS_SS 00093 MV-MegaMain B
00112
MV-MegaMainA
00121
Matrix
5 uL 50 uL8260DIC
280-678685/20
5 uL 100 uL8260DIC
280-678685/21
5 uL 25 uL8260DICV
280-678685/22
Batch Notes
Basis Basis Description
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
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Page 423 of 428
Lab Name:Job No.:
SDG No.:
GC/MS VOA BATCH WORKSHEET
280-201015-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Bustillos, Ethan T12/23/24 17:23679543
Batch Method:
Eurofins Denver
8260D
Lab Sample ID Client Sample
ID
Method Chain Basis InitialAmount FinalAmount Initial pH Headspace mv-Cent BFB
00008
MV-Gas A 00206Matrix
2 uL 2 uL 5 uL8260DBFB
280-679543/1
5 mL 5 mL 10 uL8260DCCV
280-679543/2
5 mL 5 mL 10 uL8260DLCS
280-679543/4
5 mL 5 mL 10 uL8260DLCSD
280-679543/5
5 mL 5 mL8260DMB 280-679543/9
FB-02-241217 5 mL 5 mL <2 SU No8260DT280-201015-A-3 Water
Trip Blank 5 mL 5 mL <2 SU No8260DT280-201015-B-4 Water
MW-59-241217 5 mL 5 mL <2 SU No8260DT280-201015-C-1 Water
DS-02-241217 5 mL 5 mL <2 SU No8260DT280-201015-B-2 Water
Lab Sample ID Client Sample
ID
Method Chain Basis mv-IS_SS 00094 MV-MegaMainA
00121
Matrix
8260DBFB
280-679543/1
5 uL 25 uL8260DCCV
280-679543/2
5 uL 25 uL8260DLCS
280-679543/4
5 uL 25 uL8260DLCSD
280-679543/5
5 uL8260DMB 280-679543/9
FB-02-241217 5 uL8260DT280-201015-A-3 Water
Trip Blank 5 uL8260DT280-201015-B-4 Water
MW-59-241217 5 uL8260DT280-201015-C-1 Water
DS-02-241217 5 uL8260DT280-201015-B-2 Water
Batch Notes
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
Page 1 of 28260D
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Page 424 of 428
Lab Name:Job No.:
SDG No.:
GC/MS VOA BATCH WORKSHEET
280-201015-1
Batch Number:Batch Analyst:Batch Start Date:
Batch End Date:
Bustillos, Ethan T12/23/24 17:23679543
Batch Method:
Eurofins Denver
8260D
Basis Basis Description
T Total/NA
The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for
this reagent.
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Shipping and
Receiving
Documents
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Login Sample Receipt Checklist
Client: Ramboll Americas Engineering Solutions Job Number: 280-201015-1
Login Number: 201015
Question Answer Comment
Creator: Roehsner, Karen P
List Source: Eurofins Denver
List Number: 1
TrueRadioactivity wasn't checked or is </= background as measured by a survey
meter.
TrueThe cooler's custody seal, if present, is intact.
TrueSample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or
tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
FalseThere are no discrepancies between the containers received and the COC.Refer to Job Narrative for details.
TrueSamples are received within Holding Time (excluding tests with immediate
HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
N/ASample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
TrueContainers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
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