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Home My WebLink AboutDAQ-2025-0001371 DAQC-003-25 Site ID 11841 (B4) MEMORANDUM TO: STACK TEST FILE – PEPPERIDGE FARM INCORPORATED – Commercial Bakery THROUGH: Chad Gilgen, Minor Source Compliance Section Manager FROM: Kyle Greenberg, Environmental Scientist DATE: January 2, 2025 SUBJECT: Source: Process Line No. 11 Location: 901 North 200 West, Richmond, Cache County, Utah Contact: Tony Hernandez: 435-750-8405 Tester: Alliance Source Testing Site ID #: 11841 Permit/AO #: DAQE-AN118410010-24, dated July 26, 2024 Subject: Review of Stack Test Report dated December 16, 2024 On December 16, 2024, Utah Division of Air Quality (DAQ) received a test report for the above listed unit. Testing was performed on October 24, 2024, to demonstrate compliance with the emission limits found in Condition II.B.2.a of DAQE-AN1184100010-24. The calculated test results are: Source Test Date Test Method Pollutant Tester Results DAQ Results Limits Line No. 11 October 24, 2024 25A VOC (reported as C3H8) 5.2 lb/hr 5.133 lb/hr 3.45 lb/hr DEVIATIONS: None. CONCLUSION: Process Line 11 is out of compliance with its emission limits. RECOMMENDATION: It is recommended the process line 11 to be out of compliance with the emission limits of the AO during the time of the stack tests. The methods used in stack test appear to be conducted in an acceptable manner. ATTACHMENTS: DAQ stack test review excel spreadsheet, Pepperidge Farm Incorporated stack test report. 4 ' - ) - " Emissions Pepperidge Farm Inc. Commercial Bakery Cache County Process Line No. 11 Test Date: 10/24/24 Run # 1 2 3 Average Start Time 11:55 13:25 14:58 Stop Time 12:55 14:25 15:58 Sample Duration (minutes) 60 60 60 DS Stack Diameter (inches) 27.0 27.0 27.0 27.0 PAVG Average (Delta P)½ (" H2O)½0.6140 0.6080 0.6110 0.6110 CP Pitot Tube Constant (unitless) 0.84 0.84 0.84 0.84 TS Stack Temperature (°F) 596 596 596 596 Pbar Barometric Pressure (" Hg) 25.34 25.34 25.34 25.34 Ps Stack Pressure ('' H2O)0.20 0.20 0.20 0.20 Yd Meter Y Factor (unitless) 1.0030 1.0030 1.0030 1.0030 Tm Meter Temperature (°F) 60 69 68 66 Vm Sample Volume (ft3)43.402 42.029 42.367 42.599 H Orifice Pressure Delta H (" H2O)1.4 1.2 1.2 1.3 Vlc Moisture (g) 239.9 236.3 223.0 233.1 O2%vd O2 (%vd)13.9 13.8 13.8 13.8 CO2%vd CO2 (%vd)4.1 4.1 4.0 4.1 N2%vd N2 (%vd)82.1 82.1 82.2 82.1 wet NMNEOC (ppmvw as C3H8)143.1 131.9 129.7 134.9 Run # 1 2 3 Average Vmstd Sample Volume (dscf) 37.564 35.736 36.092 36.464 Vwstd Moisture Volume (scf) 11.31 11.14 10.52 10.99 Bws Measured Moisture Content (%/100) 0.231 0.238 0.226 0.232 Bws Saturated Moisture Content (%/100) 118.758 119.018 118.845 118.874 Bws Actual Moisture Content (%/100) 0.231 0.238 0.226 0.232 MD Molecular Weight Dry (lb/lb-mole) 29.20 29.20 29.20 29.20 MA Molecular Weight Wet (lb/lb-mole) 26.61 26.54 26.67 26.61 VS Gas Velocity (ft/sec) 55.1 54.7 54.8 54.9 FACFM Gas Flow (acfm) 13155 13046 13077 13093 FDSCFM Gas Flow (dscfm) 4283 4212 4289 4261 FWSCFM Gas Flow (wscfm) 5577 5529 5543 5549 FKWSCFH Gas Flow (kwscfh) 335 332 333 333 FKWSCFM Gas Flow (kwscfm) 6666 lb/hr Gas Flow (lb/hr) 23113 22853 23025 22997 Fo Fo (unitless)1.733 1.747 1.758 1.746 wet O2 (%vw)10.6 10.5 10.7 10.6 wet CO2 (%vw)3.1 3.1 3.1 3.1 dry NMNEOC (ppmvd as C3H8)186.238 173.013 167.527 175.593 15 NMNEOC (ppmvd as C3H8 @ 15% O2)155.884 143.226 139.080 146.063 lb/hr NMNEOC (lb/hr as C3H8)5.471 4.998 4.929 5.133 3.45 Permit Limits Field Reference Method Data Reference Method Calculations Page 1 of 5 Linearity Pepperidge Farm Inc. Commercial Bakery Cache County Process Line No. 11 Test Date: 10/24/24 O2 CO2 TVOC 23.8 10.0 500.0 12.00 5.00 250.0 0.0 0.0 3.2 12.1 5.1 251.6 Linearity Bias (Zero) 0.0 0.0 0.2 Linearity Bias (Span) 12.1 5.1 249.0 % % (ppm) 0.00 0.00 0.0 12.00 5.00 150.0 23.84 10.00 250.0 400.0 0.0 0.0 0.2 12.1 5.1 149.3 23.9 10.0 249.0 401.2 0.0 0.0 0.2 0.1 0.1 -1.2 0.0 0.0 -1.8 0.0 0.0 1.2 0.00% 0.00% 0.61% 0.04% 0.30% 0.51% 0.25% 0.70% 0.81% Gas Concentration 1 2 3 Linearity Information Gas Span Gas Value/Range Bias Gas Value 4 Difference 1 4 Response 1 2 Span Bias Max Calibration Error Bias Check (Zero) Bias Check (Span) 2 3 4 Results 3 Zero Bias Page 2 of 5 Run 1 Pepperidge Farm Inc. Run 1 Commercial Bakery Cache County Start Time 11:55 Process Line No. 11 Run Length 60 Test Date: 10/24/24 Stop Time 12:55 O2 CO2 TVOC 23.8 10.0 500 12.00 5.00 250.0 0.0 0.0 3.2 12.1 5.1 251.6 0.0 0.1 3.7 12.0 5.1 251.6 0.1% 0.5% 0.7% 0.2% 0.2% 0.5% 0.1% 0.5% 0.1% 0.1% 0.1% 0.0% Corrected O2 % Corrected CO2 % Corrected TVOC ppm 13.9 4.1 143.1 Run Length (Minutes) Uncorrected O2 % Uncorrected CO2 % Uncorrected TVOC ppm 60 13.9 4.2 145.5 Zero% Span% Absolute Bias (Zero) Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Results Post Test Calibration Calibration Information Instrument Range Span Gas Value Gas Calibration Pretest Calibration Zero% Span% Page 3 of 5 Run 2 Pepperidge Farm Inc. Run 2 Commercial Bakery Cache County Start Time 13:25 Process Line No. 11 Run Length 60 Test Date: 10/24/24 Stop Time 14:25 O2 CO2 TVOC 23.8 10.0 500 12.00 5.00 250.0 0.0 0.1 3.7 12.0 5.1 251.6 0.0 0.1 3.7 12.0 5.1 250.1 0.0% 0.7% 0.7% 0.4% 0.6% 0.2% 0.1% 0.2% 0.0% 0.3% 0.4% 0.3% Corrected O2 % Corrected CO2 % Corrected TVOC ppm 13.8 4.1 131.9 Run Length (Minutes) Uncorrected O2 % Uncorrected CO2 % Uncorrected TVOC ppm 60 13.8 4.2 134.1 Gas Instrument Range Post Test Calibration Zero% Span Gas Value Calibration Pretest Calibration Zero% Calibration Information Results Absolute Bias (Zero) Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Span% Span% Page 4 of 5 Run 3 Pepperidge Farm Inc. Run 3 Commercial Bakery Cache County Start Time 14:58 Process Line No. 11 Run Length 60 Test Date: 10/24/24 Stop Time 15:58 O2 CO2 TVOC 23.8 10.0 500 12.00 5.00 250.0 0.0 0.1 3.7 12.0 5.1 250.1 0.0 0.1 3.2 11.9 5.1 253.2 0.0% 0.7% 0.6% 0.5% 0.6% 0.8% 0.0% 0.0% 0.1% 0.1% 0.0% 0.6% Corrected O2 % Corrected CO2 % Corrected TVOC ppm 13.8 4.0 129.7 Run Length (Minutes) Uncorrected O2 % Uncorrected CO2 % Uncorrected TVOC ppm 60 13.7 4.2 132.2 Post Test Calibration Instrument Range Zero% Results Absolute Bias (Zero) Span% Span% Zero% Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Calibration Information Span Gas Value Calibration Pretest Calibration Gas Page 5 of 5 December 16, 2024 Division of Air Quality Utah Department of Environmental Quality RE: AST-2024-4537 Oxidizer Test Report Comments Dear reviewer, The purpose of the oxidizer test conducted on October 24, 2024 was to obtain data from the oxidizer moved to our new production line. We will conduct a follow up test to verify the ethane data and eliminate the possibility of any inaccuracies. The upcoming, real-time test will utilize method 320 and is scheduled for the first quarter of 2025. Please reach out with any questions you may have, Ashley Peterson EHS Manager, Pepperidge Farm Richmond, UT 435-361-1202 Source Test Report Pepperidge Farm Incorporated Commercial Bakery 901 North 200 West Richmond, UT 84333 Source Tested: Process Line No. 11 Test Date: October 24, 2024 Project No. AST-2024-4537 Prepared By Alliance Technical Group, LLC 3683 W 2270 S, Suite E West Valley City, UT 84120 Source Test Report Test Program Summary AST-2024-4537 Pepperidge – Richmond, UT Page i Regulatory Information Permit No. DAQE-AN118410010-24 Source Information Source Name Target Parameter Process Line No. 11 VOC Contact Information Test Location Test Company Analytical Laboratory Pepperidge Farm Incorporated Commercial Bakery 901 North 200 West Richmond, UT 84333 Tony Hernandez tony_j_hernandez@campbells.com (435) 750-8405 Alliance Technical Group, LLC 3683 W 2270 S, Suite E West Valley City, UT 84120 Project Manager Charles Horton charles.horton@alliancetg.com (352) 663-7568 Field Team Leader Ryan Lyons ryan.lyons@stacktest.com (708) 214-4850 QA/QC Manager Kathleen Shonk katie.shonk@alliancetg.com (812) 452-4785 Report Coordinator Delaine Spangler delaine.spangler@alliancetg.com Report Reviewer Sarah Perry sarah.perry@alliancetg.com Alliance Technical Group, LLC Analytical Servives 5530 Marshall St. Arvada, CO 80002 James Davidson james.davidson@alliancetg.com (217) 317-1116 3 of 91 Source Test Report Certification Statement AST-2024-4537 Pepperidge – Richmond, UT Page ii Alliance Technical Group, LLC (Alliance) has completed the source testing as described in this report. Results apply only to the source(s) tested and operating condition(s) for the specific test date(s) and time(s) identified within this report. All results are intended to be considered in their entirety, and Alliance is not responsible for use of less than the complete test report without written consent. This report shall not be reproduced in full or in part without written approval from the customer. To the best of my knowledge and abilities, all information, facts and test data are correct. Data presented in this report has been checked for completeness and is accurate, error-free and legible. Onsite testing was conducted in accordance with approved internal Standard Operating Procedures. Any deviations or problems are detailed in the relevant sections in the test report. This report is only considered valid once an authorized representative of Alliance has signed in the space provided below; any other version is considered draft. This document was prepared in portable document format (.pdf) and contains pages as identified in the bottom footer of this document. Charles Horton, QSTI Alliance Technical Group, LLC Date 12/17/2024 4 of 91 Source Test Report Table of Contents AST-2024-4537 Pepperidge – Richmond, UT Page iii TABLE OF CONTENTS 1.0 Introduction ................................................................................................................................................. 1-1 1.1 Facility Description ..................................................................................................................................... 1-1 1.2 Project Team ............................................................................................................................................... 1-1 1.3 Site Specific Test Plan & Notification ........................................................................................................ 1-1 1.4 Test Program Notes ..................................................................................................................................... 1-1 2.0 Summary of Results .................................................................................................................................... 2-1 3.0 Testing Methodology .................................................................................................................................. 3-1 3.1 U.S. EPA Reference Test Methods 1 and 2 – Sampling/Traverse Points and Volumetric Flow Rate ........ 3-1 3.2 U.S. EPA Reference Test Method 3A – Oxygen/Carbon Dioxide .............................................................. 3-1 3.3 U.S. EPA Reference Test Method 4 – Moisture Content ............................................................................ 3-1 3.4 U.S. EPA Alternative Test Method ALT-096– Non-Methane Volatile Organic Compounds .................... 3-1 3.5 U.S. EPA Reference Test Method 205 – Gas Dilution System Certification .............................................. 3-2 3.6 Quality Assurance/Quality Control – U.S. EPA Reference Test Method 3A.............................................. 3-2 3.7 Quality Assurance/Quality Control – U.S. EPA Reference Method ALT-096 ........................................... 3-3 LIST OF TABLES Table 1-1: Project Team ........................................................................................................................................... 1-1 Table 2-1: Summary of Results ................................................................................................................................ 2-1 Table 3-1: Source Testing Methodology .................................................................................................................. 3-1 APPENDICES Appendix A Sample Calculations Appendix B Field Data Appendix C Laboratory Report Appendix D Quality Assurance/Quality Control Data Appendix E Process Operating/Control System Data 5 of 91 Introduction 6 of 91 Source Test Report Introduction AST-2024-4537 Pepperidge – Richmond, UT Page 1-1 1.0 Introduction Alliance Technical Group, LLC (Alliance) was retained by Pepperidge Farm Incorporated (Pepperidge) to conduct compliance testing at the Richmond, Utah facility. Portions of the facility are subject to provisions of the Utah Department of Environmental Quality, Division of Air Quality (UDAQ) Permit No. DAQE-AN118410010-24. Testing was conducted to determine the emission rate of volatile organic compounds (VOC) from the Catalytic Oxidizer installed on Process Line No.11. 1.1 Facility Description Pepperidge Farm Inc. owns and operates a commercial baking plant in Richmond, Utah. The plant operates Process Line No. 11. Process line No. 11 is a Natural Gas/Propane Fired Oven; emissions are controlled with a Catalytic Oxidizer for VOC (ethanol) destruction. 1.2 Project Team Personnel involved in this project are identified in the following table. Table 1-1: Project Team Pepperidge Personnel Tony Hernandez Alan Brooks Alliance Personnel Ryan Lyons Grace Ratchford Patrick Doyle Mitchell Manwaring 1.3 Site Specific Test Plan & Notification Testing was conducted in accordance with the Site Specific Test Plan (SSTP) submitted to UDAQ by Alliance on September 23, 2024. 7 of 91 Summary of Results 8 of 91 Source Test Report Summary of Results AST-2024-4537 Pepperidge – Richmond, UT Page 2-1 2.0 Summary of Results Alliance conducted compliance testing at the Richmond, Utah facility on October 24, 2024. Testing consisted of determining the emission rates of rate of VOC from the Catalytic Oxidizers installed on Process Line No. 11. Table 2-1 provides a summary of the emission testing results with comparisons to the applicable permit limits. Any difference between the summary results listed in the following table and the detailed results contained in appendices is due to rounding for presentation. Table 2-1: Summary of Results Run Number Run 1 Run 2 Run 3 Average Date 10/24/24 10/24/24 10/24/24 -- Non-Methane Hydrocarbon Data Concentration as C3H8, ppmvd 187.52 175.74 170.86 178.04 Concentration as C3H8, ppmvw 145.52 134.09 132.24 137.28 Emission Rate as C3H8, lb/hr 5.6 5.1 5.0 5.2 Concentration as Ethanol, ppmvd 548.18 513.73 499.47 520.46 Emission Rate as Ethanol, lb/hr 17.0 15.5 15.4 16.0 Permit Limit, lb/hr -- -- -- 3.45 Percent of Limit, % -- -- -- > 100 9 of 91 Testing Methodology 10 of 91 Source Test Report Testing Methodology AST-2024-4537 Pepperidge – Richmond, UT Page 3-1 3.0 Testing Methodology The emission testing program was conducted in accordance with the test methods listed in Table 3-1. Method descriptions are provided below while quality assurance/quality control data is provided in Appendix D. Table 3-1: Source Testing Methodology Parameter U.S. EPA Reference Test Methods Notes/Remarks Volumetric Flow Rate 1 & 2 Full Velocity Traverses Oxygen / Carbon Dioxide 3A Instrumental Analysis Moisture Content 4 Gravimetric Analysis Non-Methane Volatile Organic Compounds ALT-096 Instrumental Analysis Gas Dilution System Certification 205 --- 3.1 U.S. EPA Reference Test Methods 1 and 2 – Sampling/Traverse Points and Volumetric Flow Rate The sampling location and number of traverse (sampling) points were selected in accordance with U.S. EPA Reference Test Method 1. To determine the minimum number of traverse points, the upstream and downstream distances were equated into equivalent diameters and compared to Figure 1-2 in U.S. EPA Reference Test Method 1. Full velocity traverses were conducted in accordance with U.S. EPA Reference Test Method 2 to determine the average stack gas velocity pressure, static pressure and temperature. The velocity and static pressure measurement system consisted of a pitot tube and inclined manometer. The stack gas temperature was measured with a K-type thermocouple and pyrometer. Stack gas velocity pressure and temperature readings were recorded during each test run. The data collected was utilized to calculate the volumetric flow rate in accordance with U.S. EPA Reference Test Method 2. 3.2 U.S. EPA Reference Test Method 3A – Oxygen/Carbon Dioxide The oxygen (O2) and carbon dioxide (CO2) testing was conducted in accordance with U.S. EPA Reference Test Method 3A. Data was collected online and reported in one-minute averages. The sampling system consisted of a stainless-steel probe, Teflon sample line(s), gas conditioning system and the identified gas analyzer. The gas conditioning system was a non-contact condenser used to remove moisture from the stack gas. If an unheated Teflon sample line was used, then a portable non-contact condenser was placed in the system directly after the probe. Otherwise, a heated Teflon sample line was used. The quality control measures are described in Section 3.6. 3.3 U.S. EPA Reference Test Method 4 – Moisture Content The stack gas moisture content (BWS) was determined in accordance with U.S. EPA Reference Test Method 4. The gas conditioning train consisted of a series of chilled impingers. Prior to testing, each impinger was filled with a known quantity of water or silica gel. Each impinger was analyzed gravimetrically before and after each test run on the same balance to determine the amount of moisture condensed. 3.4 U.S. EPA Alternative Test Method ALT-096– Non-Methane Volatile Organic Compounds The non-methane volatile organic compounds (NMVOC) testing was conducted in accordance with U.S. EPA Alternate Test Method ALT-096. EPA Method 25A is incorporated by reference. The sampling system consisted of a stainless 11 of 91 Source Test Report Testing Methodology AST-2024-4537 Pepperidge – Richmond, UT Page 3-2 steel probe, heated Teflon sample line(s) and the Thermo 55i analyzer. The quality control measures are described in Section 3.7. 3.5 U.S. EPA Reference Test Method 205 – Gas Dilution System Certification A calibration gas dilution system field check was conducted in accordance with U.S. EPA Reference Method 205. An initial three (3) point calibration was conducted, using individual Protocol 1 gases, on the analyzer used to complete the dilution system field check. Multiple dilution rates and total gas flow rates were utilized to force the dilution system to perform two dilutions on each mass flow controller. The diluted calibration gases was sent directly to the analyzer, and the analyzer response recorded in an electronic field data sheet. A mid-level supply gas, with a cylinder concentration within 10% of one of the gas divider settings described above, was introduced directly to the analyzer, and the analyzer response recorded in an electronic field data sheet. The cylinder concentration and the analyzer response agreed within 2%. These steps were repeated three (3) times. The average analyzer response agreed within 2% of the predicted gas concentration. No single injection differed more than 2% from the average instrument response for that dilution. Copies of the Method 205 data can be found in the Quality Assurance/Quality Control Appendix. 3.6 Quality Assurance/Quality Control – U.S. EPA Reference Test Method 3A Cylinder calibration gases used met EPA Protocol 1 (+/- 2%) standards. Copies of all calibration gas certificates can be found in the Quality Assurance/Quality Control Appendix. Low Level gas was introduced directly to the analyzer. After adjusting the analyzer to the Low-Level gas concentration and once the analyzer reading was stable, the analyzer value was recorded. This process was repeated for the High-Level gas. For the Calibration Error Test, Low, Mid, and High Level calibration gases were sequentially introduced directly to the analyzer. All values were within 2.0 percent of the Calibration Span or 0.5% absolute difference. High or Mid-Level gas (whichever was closer to the stack gas concentration) was introduced at the probe and the time required for the analyzer reading to reach 95 percent or 0.5% (whichever was less restrictive) of the gas concentration was recorded. The analyzer reading was observed until it reached a stable value, and this value was recorded. Next, Low Level gas was introduced at the probe and the time required for the analyzer reading to decrease to a value within 5.0 percent or 0.5% (whichever was less restrictive) was recorded. If the Low-Level gas was zero gas, the response was 0.5% or 5.0 percent of the upscale gas concentration (whichever was less restrictive). The analyzer reading was observed until it reached a stable value and this value was recorded. The measurement system response time and initial system bias were determined from these data. The System Bias was within 5.0 percent of the Calibration Span or 0.5% absolute difference. High or Mid-Level gas (whichever was closer to the stack gas concentration) was introduced at the probe. After the analyzer response was stable, the value was recorded. Next, Low Level gas was introduced at the probe, and the analyzer value recorded once it reached a stable response. The System Bias was within 5.0 percent of the Calibration Span or 0.5% absolute difference or the data was invalidated and the Calibration Error Test and System Bias were repeated. Drift between pre- and post-run System Bias was within 3 percent of the Calibration Span or 0.5% absolute difference. If the drift exceeded 3 percent or 0.5%, the Calibration Error Test and System Bias were repeated. 12 of 91 Source Test Report Testing Methodology AST-2024-4537 Pepperidge – Richmond, UT Page 3-3 To determine the number of sampling points, a gas stratification check was conducted prior to initiating testing. The pollutant concentrations were measured at twelve traverse points (as described in Method 1). Each traverse point was sampled for a minimum of twice the system response time. If the diluent concentration at each traverse point did not differ more than 5 percent or 0.3% (whichever was less restrictive) of the average pollutant concentration, then single point sampling was conducted during the test runs. If the pollutant concentration did not meet these specifications but differed less than 10 percent or 0.5% from the average concentration, then three (3) point sampling was conducted (stacks less than 7.8 feet in diameter - 16.7, 50.0 and 83.3 percent of the measurement line; stacks greater than 7.8 feet in diameter – 0.4, 1.0, and 2.0 meters from the stack wall). If the pollutant concentration differed by more than 10 percent or 0.5% from the average concentration, then sampling was conducted at a minimum of twelve (12) traverse points. Copies of stratification check data can be found in the Quality Assurance/Quality Control Appendix. A Data Acquisition System with battery backup was used to record the instrument response in one (1) minute averages. The data was continuously stored as a *.CSV file in Excel format on the hard drive of a computer. At the completion of testing, the data was also saved to the Alliance server. All data was reviewed by the Field Team Leader before leaving the facility. Once arriving at Alliance’s office, all written and electronic data was relinquished to the report coordinator and then a final review was performed by the Project Manager. 3.7 Quality Assurance/Quality Control – U.S. EPA Reference Method ALT-096 Cylinder calibration gases used met EPA Protocol 1 (+/- 2%) standards. Copies of all calibration gas certificates are provided in the Quality Assurance/Quality Control Appendix. Zero gas was introduced through the sampling system to the analyzer. After adjusting the analyzer to the Zero gas concentration and once the analyzer reading was stable, the analyzer value was recorded. This process was repeated for the High Level gas, and the time required for the analyzer reading to reach 95 percent of the gas concentration was recorded to determine the response time. Next, Mid and Low Level gases were introduced through the sampling system to the analyzer, and the response was recorded when it is stable. All values must be within +/- 5% of the calibration gas concentrations. A separation efficiency check was performed using a certified (+/- 2%) blend of methane, ethane, acetylene, and propane in nitrogen. The recorded residual value must be within 5% of the predicted cylinder concentration. Mid Level gas were introduced through the sampling system. After the analyzer response was stable, the value was recorded. Next, Zero gas was introduced through the sampling system, and the analyzer value recorded once it reached a stable response. The Analyzer Drift must be less than 3 percent of the Calibration Span. A Data Acquisition System with battery backup was used to record the instrument response (analog 0-10 volt signal) in one (1) minute averages. The data was continuously stored as a *.CSV file in Excel format on the hard drive of a desktop computer. At the completion of the emissions testing the data was also saved to disk. 13 of 91 Appendix A 14 of 91 Example Calculations Location Source Project No. Run No. Parameter(s) Meter Pressure (Pm), in. Hg where, Pb 25.34 = barometric pressure, in. Hg ΔH 1.400 = pressure differential of orifice, in H2O Pm 25.44 = in. Hg Absolute Stack Gas Pressure (Ps), in. Hg where, Pb 25.34 = barometric pressure, in. Hg Pg 0.20 = static pressure, in. H2O Ps 25.35 = in. Hg Standard Meter Volume (Vmstd), dscf where, Y 1.003 = meter correction factor Vm 43.402 = meter volume, cf Pm 25.44 = absolute meter pressure, in. Hg Tm 520.1 = absolute meter temperature, °R Vmstd 37.560 = dscf Standard Wet Volume (Vwstd), scf where, Vlc 229.9 = weight of H2O collected, g Vwstd 10.842 = scf Moisture Fraction (BWSsat), dimensionless (theoretical at saturated conditions) where, Ts 595.5 = stack temperature, °F Ps 25.4 = absolute stack gas pressure, in. Hg BWSsat 1.000 = dimensionless Moisture Fraction (BWS), dimensionless where, Vwstd 10.842 = standard wet volume, scf Vmstd 37.560 = standard meter volume, dscf BWS 0.224 = dimensionless Moisture Fraction (BWS), dimensionless where, BWSsat 1.000 = moisture fraction (theoretical at saturated conditions) BWSmsd 0.224 = moisture fraction (measured) BWS 0.224 Molecular Weight (DRY) (Md), lb/lb-mole where, CO2 4.1 = carbon dioxide concentration, % O2 13.9 = oxygen concentration, % Md 29.21 = lb/lb mol Pepperidge Farm Incorporated - Richmond, UT Process Line No. 11 AST-2024-4537 1 VFR Vwstd = 0.04716 x Vlc Vmstd =17.636 x Vm x Pm x Y Tm BWS ൌ Vwstd ሺVwstd ൅ Vmstdሻ Md ൌ ሺ0.44 ൈ % COଶሻ ൅ ሺ0.32 ൈ % O2ሻ ൅ ሺ0.28 ሺ100 െ % COଶ െ % O2ሻሻ BWS ൌ BWSmsd unless BWSsat ൏ BWSmsd BWSsat ൌ 10଺.ଷ଻ି ଶ,଼ଶ଻୘ୱାଷ଺ହ Ps Ps ൌ Pb ൅ Pg 13.6 Pm ൌ Pb ൅ Δ H 13.6 15 of 91 Example Calculations Location Source Project No. Run No. Parameter(s) Pepperidge Farm Incorporated - Richmond, UT Process Line No. 11 AST-2024-4537 1 VFR Molecular Weight (WET) (Ms), lb/lb-mole where, Md 29.21 = molecular weight (DRY), lb/lb mol BWS 0.224 = moisture fraction, dimensionless Ms 26.70 = lb/lb mol Average Velocity (Vs), ft/sec where, Cp 0.84 = pitot tube coefficient Δ P1/2 0.614 = average pre/post test velocity head of stack gas, (in. H2O)1/2 Ts 1055.2 = average pre/post test absolute stack temperature, °R Ps 25.35 = absolute stack gas pressure, in. Hg Ms 26.70 = molecular weight of stack gas, lb/lb mol Vs 55.1 = ft/sec Average Stack Gas Flow at Stack Conditions (Qa), acfm where, Vs 55.1 = stack gas velocity, ft/sec As 3.98 = cross-sectional area of stack, ft 2 Qa 13,139 = acfm Average Stack Gas Flow at Standard Conditions (Qs), dscfm Ps Ts where, Qa 13,139 = average stack gas flow at stack conditions, acfm BWS 0.224 = moisture fraction, dimensionless Ps 25.35 = absolute stack gas pressure, in. Hg Ts 1055.2 = average pre/post test absolute stack temperature, °R Qs 4,321 = dscfm Dry Gas Meter Calibration Check (Yqa), percent where, Y 1.003 = meter correction factor, dimensionlessΘ60 = run time, min. Vm 43.402 = total meter volume, dcf Tm 520.1 = absolute meter temperature, °R ΔH@ 1.681 = orifice meter calibration coefficient, in. H2O Pb 25.34 = barometric pressure, in. Hg ΔH avg 1.400 = average pressure differential of orifice, in H2O Md 29.21 = molecular weight (DRY), lb/lb mol (Δ H)1/2 1.183 = average square root pressure differential of orifice, (in. H2O)1/2 Yqa -1.2 = percent Qsd = 17.636 x Qa x (1 - BWS) x Ms ൌ Md ሺ1 െ BWSሻ ൅ 18.015 ሺBWSሻ Vs ൌ 85.49 ൈ Cp ൈ ሺΔ P ଵ/ଶሻ avg ൈ Ts Ps x Ms Qa ൌ 60 ൈ Vs ൈ As Yqa ൌ Y െ Θ Vm 0.0319 ൈ Tm ൈ29 ΔH@ ൈ Pb ൅ Δ Havg.13.6 ൈ Md ΔH avg. Y ൈ 100 16 of 91 Location: Source: Project No.: Run No. /Method O₂ - Outlet Concentration (CO₂), % dry CMA( CM - C0 ) where,Cobs 13.89 = average analyzer value during test, % dry Co 0.01 = average of pretest & posttest zero responses, % dry CMA 12.00 = actual concentration of calibration gas, % dry CM 12.04 = average of pretest & posttest calibration responses, % dry CO₂13.85 = O₂ Concentration, % dry Pepperidge Farm Incorporated - Richmond, UT Process Line No. 11 AST-2024-4537 Run 1 / Method 3A CO₂ = ( Cobs - C0 ) x Example Calculations CO₂ - Outlet Concentration (CCO₂), % dry C M A ( CM - C 0 ) where,Cobs 4.15 Co 0.03 CMA 5.00 CM 5.10 CCO₂4.07 = average analyzer value during test, % dry = average of pretest & posttest zero responses, % dry = actual concentration of calibration gas, % dry = average of pretest & posttest calibration responses, % dry = CO₂ Concentration, % dry CCO₂ = ( Cobs - C0 ) x 17 of 91 Location: Source: Project No.: Run No. /Method NMHC - Outlet Concentration (as C3H8) (CNMHC), ppmvd CNMHCw 1 - BWS where,CNMHCw 145.5 = NMHC - Outlet Concentration (as C3H8), ppmvw BWS 0.224 = moisture fraction, unitlessCNMHC187.52 = ppmvd NMHC - Outlet Emission Rate (as C3H8) (ERNMHC), lb/hr where,CNMHC 187.5 = NMHC - Outlet Concentration (as C3H8), ppmvd MW 44.1 = NMHC molecular weight, g/g-mole Qs 4,321 = stack gas volumetric flow rate at standard conditions, dscfm ERNMHC 5.6 = lb/hr NMHC - Outlet Concentration (CNMHCc), ppmvd as Ethanol CNMHCRF where, CNMHC 187.52 = NMHC - Outlet Concentration, ppmvd RF 0.34 = Response Factor, dimensionless CNMHCc 548.18 = ppmvd NMHC - Outlet Emission Rate (ERNMHC), lb/hr where, CNMHCc 548.2 = NMHC - Outlet Concentration, ppmvd as Ethanol MW 46.068 = NMHC molecular weight, g/g-mole Qs 4,321 = stack gas volumetric flow rate at standard conditions, dscfmERNMHC17.0 = lb/hr CNMHCc = ERNMHC =CNMHC x MW x Qs x 60 x 28.32 x 1.0E06 x 454 ERNMHC =CNMHC x MW x Qs x 60 x 28.32 24.04 x 1.0E06 x 454 CNMHC = Pepperidge Farm Incorporated - Richmond, UT Process Line No. 11 AST-2024-4537 Run 1 / Method Alt-096 𝑚𝑖𝑛 ℎ𝑟 𝐿 𝑓𝑡ଷ 𝐿 𝑔െ𝑚𝑜𝑙𝑒 𝑔 𝑙𝑏 𝑚𝑖𝑛 ℎ𝑟 𝐿 𝑓𝑡ଷ 𝐿 𝑔െ𝑚𝑜𝑙𝑒 𝑔 𝑙𝑏 18 of 91 Appendix B 19 of 91 Emissions Calculations Location Source Project No. Run Number Run 1 Run 2 Run 3 Average Date 10/24/24 10/24/24 10/24/24 -- Start Time 11:55 13:25 14:58 -- Stop Time 12:54 14:24 15:57 -- Response Factor, dimensionless RF 0.34 0.34 0.34 0.34 Moisture Fraction, dimensionless BWS 0.224 0.237 0.226 0.229 Volumetric Flow Rate (M1-4), dscfm Qs 4,321 4,211 4,288 4,273 O₂ Concentration, % dry CO₂13.85 13.78 13.79 13.81 CO₂ Concentration, % dry CCO₂4.07 4.08 4.05 4.07 NMHC (as C₃H₈) Concentration, ppmvd CNMHC 187.52 175.74 170.86 178.04 NMHC (as C₃H₈) Concentration, ppmvw CNMHCw 145.52 134.09 132.24 137.28 NMHC (as C₃H₈) Emission Rate, lb/hr ERNMHC 5.6 5.1 5.0 5.2 NMHC (as Ethanol) Concentration, ppmvd CNMHCcc 548.18 513.73 499.47 520.46 NMHC (as Ethanol) Concentration, lb/hr ERNMHCc 17.0 15.5 15.4 16.0 CH4 Concentration, ppmvd CCH4 841.00 774.00 724.00 779.67 CH4 Concentration (as C₃H₈), ppmvd CCH4 as propane 280.33 258.00 241.33 259.89 CH4 Emission Rate, lb/hr ERCH4 9.1 8.1 7.8 8.3 C2H6 Concentration, ppmvd CC2H6 34.40 31.50 31.30 32.40 C2H6 Concentration (as C₃H₈), ppmvd CC2H6 as propane 22.93 21.00 20.87 21.60 C2H6 Emission Rate, lb/hr ERC2H6 0.70 0.62 0.63 0.65 Pepperidge Farm Incorporated - Richmond, UT Process Line No. 11 AST-2024-4537 Source Data Input Data - Outlet Calculated Data - Outlet 20 of 91 Method 1 Data Location Source Project No. Date Vertical Circular 31.00 in 4.00 in 27.00 in 3.98 ft2 2 1 3.0 ft 1.3 (must be > 0.5) 10.0 ft 4.4 (must be > 2) 16 16 Measurer (Initial and Date):MDM Reviewer (Initial and Date):GIR 2345 6 789101112 1 14.6 -- 6.7 --4.4 -- 3.2 -- 2.6 -- 2.1 1 3.2 1.00 5 2 85.4 -- 25.0 -- 14.6 -- 10.5 -- 8.2 -- 6.7 2 10.5 2.84 6 13/16 3 -- -- 75.0 -- 29.6 -- 19.4 -- 14.6 -- 11.8 3 19.4 5.24 9 1/4 4 -- -- 93.3 -- 70.4 -- 32.3 -- 22.6 -- 17.7 4 32.3 8.72 12 3/4 5 -- -- -- -- 85.4 -- 67.7 -- 34.2 -- 25.0 5 67.7 18.28 22 1/4 6 -- -- -- -- 95.6 -- 80.6 -- 65.8 -- 35.6 6 80.6 21.76 25 3/4 7 -- -- -- ------ 89.5 -- 77.4 -- 64.4 7 89.5 24.17 28 3/16 8 -- -- -- ------ 96.8 -- 85.4 -- 75.0 8 96.8 26.00 30 9 -- -- -- ------ -- -- 91.8 -- 82.3 9 -- -- -- 10 -- -- -- ------ -- -- 97.4 -- 88.2 10 -- -- -- 11 -- -- -- ------ -- -- -- -- 93.3 11 -- -- -- 12 -- -- -- ------ -- -- -- -- 97.9 12 -- -- -- *Percent of stack diameter from inside wall to traverse point. A = 3 ft. B = 10 ft. Depth of Duct = 27 in. Cross Sectional Area of Duct: Pepperidge Farm Incorporated - Richmond, UT Process Line No. 11 AST-2024-4537 10/23/24 Stack Parameters Duct Orientation: Duct Design: Distance from Far Wall to Outside of Port: Nipple Length: Depth of Duct: No. of Test Ports: Number of Readings per Point: Distance A: Distance A Duct Diameters: Distance B: Distance B Duct Diameters: Minimum Number of Traverse Points: Actual Number of Traverse Points: CIRCULAR DUCT Number of traverse points on a diameter Stack Diagram Cross Sectional Area LOCATION OF TRAVERSE POINTS Traverse Point % of Diameter Distance from inside wall Distance from outside of port Upstream Disturbance Downstream Disturbance B A 21 of 91 Cyclonic Flow Check Location Source Project No. Date Sample Point Angle (ΔP=0) 1 5 2 7 3 8 4 10 5 10 6 5 7 0 8 0 9 5 10 5 11 10 12 15 13 10 14 10 15 5 16 5 Average 6.9 Pepperidge Farm Incorporated - Richmond, UT Process Line No. 11 AST-2024-4537 10/24/24 22 of 91 Field Data Method 2 Data Location Source Project No. Δ P (in. WC) Ts (°F) Δ P (in. WC) Ts (°F) Δ P (in. WC) Ts (°F) 0.39 596 0.39 596 0.38 596 0.35 596 0.36 596 0.36 596 0.38 596 0.38 596 0.35 596 0.36 596 0.39 595 0.34 595 0.39 595 0.36 595 0.38 595 0.39 595 0.38 595 0.39 595 0.40 595 0.35 596 0.40 596 0.39 596 0.35 596 0.39 596 0.39 596 0.39 596 0.38 595 0.36 596 0.38 596 0.36 595 0.39 596 0.38 596 0.35 596 0.38 595 0.36 597 0.37 596 0.35 595 0.35 597 0.36 595 0.36 595 0.35 596 0.38 596 0.39 595 0.36 595 0.39 596 0.37 595 0.38 595 0.39 596 Average Square Root of ΔP, (in. WC)1/2 (ΔP)1/2 0.611 Average ΔP, in. WC (ΔP)0.37 Pitot Tube Coefficient (Cp)0.840 Barometric Pressure, in. Hg (Pb)25.34 Static Pressure, in. WC (Pg)0.20 Stack Pressure, in. Hg (Ps)25.35 Average Temperature, °F (Ts)595.6 Average Temperature, °R (Ts)1055.3 Measured Moisture Fraction (BWSmsd)0.229 Moisture Fraction @ Saturation (BWSsat)1.000 Moisture Fraction (BWS)0.229 O2 Concentration, % (O2)13.81 CO2 Concentration, % (CO2)4.07 Molecular Weight, lb/lb-mole (dry) (Md)29.20 Molecular Weight, lb/lb-mole (wet) (Ms)26.64 Velocity, ft/sec (Vs)54.8 VFR at stack conditions, acfm (Qa)13,081 VFR at standard conditions, scfh (Qsw)332,550 VFR at standard conditions, scfm (Qsw)5,542 VFR at standard conditions, dscfm (Qsd)4,273 8 Pepperidge Farm Incorporated - Richmond, UT Process Line No. 11 AST-2024-4537 Run No.1 2 3 Status VALID VALID VALID Date 10/24/24 10/24/24 10/24/24 Stop Time 12:54 14:25 15:58 Start Time 11:55 13:25 14:58 Traverse Point 1 2 3 4 Leak Check Pass Pass Pass 3 4 5 6 7 5 6 7 8 1 2 0.840 0.840 0.840 0.38 0.37 0.37 0.614 0.608 0.611 0.20 0.20 0.20 25.34 25.34 25.34 595.5 595.8 595.6 25.35 25.35 25.35 0.224 0.237 0.226 1055.2 1055.5 1055.3 29.21 29.20 29.20 13.85 13.78 13.79 4.07 4.08 4.05 55.1 54.6 54.8 26.70 26.55 26.68 13,139 13,036 13,068 5,568 5,523 5,537 334,069 331,350 332,231 4,321 4,211 4,288 1.0001.0001.000 0.2260.2370.224 23 of 91 Method 4 Data Location SourceProject No. Parameter(s) Console Units / Methodft3 M4 Run No. Date Status Start Time End Time Run Time, min (θ) Meter ID Meter Correction Factor (Y) Orifice Calibration Value (ΔH @) Max Vacuum, in. Hg Post Leak Check, ft3/min (at max vac.) Meter Volume, ft3 Total Meter Volume, ft3 (Vm) Meter Probe Filter Vacuum Imp. Exit Meter Probe Filter Vacuum Imp. Exit Meter Probe Filter Vacuum Imp. Exit 55 -- -- 2 41 65 -- -- 2 54 68 -- -- 2 45 56 -- -- 2 39 66 -- -- 2 44 67 -- -- 2 42 56 -- -- 2 39 67 -- -- 2 40 67 -- -- 2 42 57 -- -- 2 39 67 -- -- 2 41 67 -- -- 2 43 57 -- -- 2 41 67 -- -- 2 41 67 -- -- 2 43 58 -- -- 2 43 68 -- -- 2 42 68 -- -- 2 43 61 -- -- 2 44 69 -- -- 2 42 68 -- -- 2 44 62 -- -- 2 45 69 -- -- 2 42 68 -- -- 2 44 62 -- -- 2 47 70 -- -- 2 42 69 -- -- 2 44 64 -- -- 2 48 71 -- -- 2 42 69 -- -- 2 43 65 -- -- 2 47 71 -- -- 2 41 69 -- -- 2 44 66 -- -- 2 47 71 -- -- 2 40 69 -- -- 2 44 66 -- -- 2 48 70 -- -- 2 42 70 -- -- 2 45 Average Temperature, °F (Tm)60 -- -- 2 44 69 -- -- 2 43 68 -- -- 2 44 Average Temperature, °R (Tm)520 -- -- -- -- 528 -- -- -- -- 528 -- -- -- -- Minimum Temperature, °F 55 -- -- 2 39 65 -- -- 2 40 67 -- -- 2 42 Maximum Temperature, °F 66 -- -- 2 48 71 -- -- 2 54 70 -- -- 2 45 Barometric Pressure, in. Hg (Pb) Meter Orifice Pressure , in. WC (ΔH) Meter Pressure, in. Hg (Pm) Standard Meter Volume, ft3 (Vmstd) Analysis Type Impinger 1, Pre/Post Test, g 743.6 925.3 181.7 753.4 968.0 214.6 741.5 942.2 200.7 Impinger 2, Pre/Post Test, g 732.6 765.7 33.1 681.3 694.1 12.8 694.1 707.4 13.3 Impinger 3, Pre/Post Test, g 666.8 672.5 5.7 672.5 675.5 3.0 675.5 677.9 2.4 Impinger 4, Pre/Post Test, g 970.0 979.4 9.4 979.4 985.3 5.9 985.3 991.9 6.6 Volume Water Collected, mL (Vlc) Standard Water Volume, ft3 (Vwstd) Moisture Fraction Measured (BWS) Gas Molecular Weight, lb/lb-mole (dry) (Md) DGM Calibration Check Value (Yqa) Temperature, °F 0 5 30 35 60 Pepperidge Farm Incorporated - Richmond, UT Process Line No. 11AST-2024-4537 VFR 1 VALID 10/24/24 11:55 12:54 60 M5-14 1.003 1.681 VALID 14:58 15:58 60 M5-14 1.003 1.681 2 0.001 29.20 2.4 223.0 10.517 0.226 3.3 29.20 H2O H2O Empty H2O Empty 25.34 1.200 25.34 1.200 2 10/24/24 3 10/24/24 VALID 13:25 14:25 60 M5-14 1.003 1.681 2 0.001 136.978 140.710 144.300 147.560 150.820 154.430 158.040 161.630 165.220 168.780 172.330 175.850 179.345 126.445 129.941 133.418 136.891 94.862 98.250 101.750 105.223 108.691 112.280 115.849 119.392 122.935 43.402 42.029 42.367 H2O 236.3 11.144 0.237 29.21 -1.2 25.43 35.790 25.43 36.104 Gravimetric Gravimetric Silica Silica Silica 25.34 229.9 10.842 0.224 1.400 25.44 37.560 H2O H2O Empty Gravimetric 2 0.001 51.020 54.745 58.480 61.740 65.460 69.150 72.830 76.471 80.103 83.722 87.234 90.860 94.42260 0 5 10 15 20 25 10 15 20 25 40 45 50 55 30 35 40 45 50 55 24 of 91 Run 1 - RM Data Location: Source: Project No.: Date: Time O₂ - Outlet CO₂ - Outlet NMHC - Outlet Unit % dry % dry ppmvw Status Valid Valid Valid Uncorrected Run Average (Cobs)13.89 4.15 145.52 Cal Gas Concentration (CMA)12.00 5.00 250.00 Pretest System Zero Response 0.00 0.00 3.21 Posttest System Zero Response 0.02 0.05 3.74 Average Zero Response (Co)0.01 0.03 3.48 Pretest System Cal Response 12.05 5.10 251.57 Posttest System Cal Response 12.02 5.09 251.59 Average Cal Response (CM)12.04 5.10 251.58 Corrected Run Average (Corr)13.85 4.07 NA 11:55 13.93 4.11 129.97 11:56 13.92 4.12 132.40 11:57 13.93 4.11 134.71 11:58 14.00 4.14 136.54 11:59 13.89 4.08 137.19 12:00 13.82 4.19 140.75 12:01 14.05 4.14 140.52 12:02 14.09 4.05 142.91 12:03 14.27 4.00 143.94 12:04 14.47 3.85 133.66 12:05 13.79 3.93 144.54 12:06 13.70 4.25 145.20 12:07 13.88 4.23 147.82 12:08 13.98 4.13 148.76 12:09 13.85 4.11 148.09 12:10 13.97 4.15 146.50 12:11 13.89 4.09 144.51 12:12 13.80 4.19 143.64 12:13 14.09 4.14 145.06 12:14 13.96 4.04 147.76 12:15 13.95 4.10 148.81 12:16 14.09 4.09 147.16 12:17 14.03 4.03 147.22 12:18 13.89 4.10 147.62 12:19 13.99 4.13 143.42 12:20 14.11 4.05 151.92 12:21 13.90 4.06 152.85 12:22 14.08 4.12 151.19 12:23 14.03 4.02 154.00 12:24 13.86 4.12 155.41 12:25 14.00 4.14 152.63 12:26 13.97 4.09 151.96 12:27 13.79 4.14 153.40 12:28 13.91 4.20 151.55 12:29 13.91 4.12 149.10 12:30 13.87 4.17 151.83 12:31 13.92 4.13 153.80 12:32 13.79 4.17 150.86 12:33 13.71 4.22 148.03 12:34 13.79 4.25 146.11 12:35 13.90 4.18 148.77 12:36 13.72 4.18 149.27 12:37 13.71 4.25 147.44 12:38 13.69 4.28 147.19 12:39 13.81 4.25 146.78 12:40 13.78 4.23 147.02 12:41 13.86 4.21 145.20 12:42 13.74 4.19 144.55 12:43 13.78 4.23 144.26 12:44 13.79 4.22 142.36 12:45 13.71 4.23 141.57 12:46 13.66 4.26 142.91 12:47 13.89 4.27 142.68 12:48 13.81 4.15 142.19 12:49 13.61 4.26 143.73 12:50 13.83 4.29 141.35 12:51 13.76 4.20 141.35 12:52 13.75 4.25 142.86 12:53 13.92 4.21 142.44 12:54 13.80 4.14 143.70 Pepperidge Farm Incorporated - Richmond, UT Process Line No. 11 AST-2024-4537 10/24/24 25 of 91 Run 2 - RM Data Location: Source: Project No.: Date: Time O₂ - Outlet CO₂ - Outlet NMHC - Outlet Unit % dry % dry ppmvw Status Valid Valid Valid Uncorrected Run Average (Cobs)13.76 4.18 134.09 Cal Gas Concentration (CMA)12.00 5.00 250.00 Pretest System Zero Response 0.02 0.05 3.74 Posttest System Zero Response 0.00 0.07 3.68 Average Zero Response (Co)0.01 0.06 3.71 Pretest System Cal Response 12.02 5.09 251.59 Posttest System Cal Response 11.96 5.11 250.12 Average Cal Response (CM)11.99 5.10 250.86 Corrected Run Average (Corr)13.78 4.08 NA 13:25 13.82 4.15 113.57 13:26 13.67 4.20 117.67 13:27 13.65 4.25 120.04 13:28 13.76 4.25 122.34 13:29 13.87 4.17 124.90 13:30 13.92 4.14 128.24 13:31 13.93 4.08 131.30 13:32 13.65 4.14 131.64 13:33 13.60 4.30 130.47 13:34 13.71 4.26 131.30 13:35 13.75 4.19 132.70 13:36 13.62 4.24 131.52 13:37 13.80 4.25 131.59 13:38 13.88 4.14 132.33 13:39 13.82 4.13 137.24 13:40 13.74 4.17 138.72 13:41 13.74 4.20 134.95 13:42 13.79 4.17 133.37 13:43 13.72 4.18 132.32 13:44 13.85 4.18 132.47 13:45 13.78 4.13 132.29 13:46 13.92 4.17 136.28 13:47 14.01 4.04 139.81 13:48 13.81 4.08 140.07 13:49 13.82 4.16 138.79 13:50 13.81 4.14 136.69 13:51 13.73 4.19 135.77 13:52 13.65 4.20 136.80 13:53 13.85 4.22 139.24 13:54 13.90 4.10 139.44 13:55 13.82 4.11 142.37 13:56 13.79 4.16 140.83 13:57 13.74 4.16 138.86 13:58 13.55 4.22 139.18 13:59 13.69 4.29 139.24 14:00 13.69 4.21 137.77 14:01 13.77 4.21 136.54 14:02 13.94 4.13 134.93 14:03 13.71 4.09 136.05 14:04 13.61 4.24 136.77 14:05 13.73 4.23 134.42 14:06 13.70 4.21 132.77 14:07 13.71 4.20 133.35 14:08 13.87 4.18 134.98 14:09 13.94 4.08 138.76 14:10 13.77 4.11 139.12 14:11 13.64 4.18 137.72 14:12 13.68 4.24 131.51 14:13 13.69 4.22 133.49 14:14 13.74 4.22 133.18 14:15 13.83 4.15 134.29 14:16 13.74 4.14 134.58 14:17 13.81 4.17 135.29 14:18 13.74 4.15 136.90 14:19 13.80 4.15 138.55 14:20 13.64 4.16 135.91 14:21 13.68 4.25 132.72 14:22 13.72 4.17 133.98 14:23 13.67 4.23 134.09 14:24 13.89 4.17 133.23 Pepperidge Farm Incorporated - Richmond, UT Process Line No. 11 AST-2024-4537 10/24/24 26 of 91 Run 3 - RM Data Location: Source: Project No.: Date: Time O₂ - Outlet CO₂ - Outlet NMHC - Outlet Unit % dry % dry ppmvw Status Valid Valid Valid Uncorrected Run Average (Cobs)13.73 4.16 132.24 Cal Gas Concentration (CMA)12.00 5.00 250.00 Pretest System Zero Response 0.00 0.07 3.68 Posttest System Zero Response 0.00 0.07 3.23 Average Zero Response (Co)0.00 0.07 3.46 Pretest System Cal Response 11.96 5.11 250.12 Posttest System Cal Response 11.93 5.13 253.16 Average Cal Response (CM)11.95 5.12 251.64 Corrected Run Average (Corr)13.79 4.05 NA 14:58 13.82 3.86 105.11 14:59 13.89 4.14 110.42 15:00 13.81 4.08 116.33 15:01 13.92 4.12 121.66 15:02 13.97 4.02 118.43 15:03 13.82 4.04 117.88 15:04 13.86 4.11 122.48 15:05 13.86 4.07 126.74 15:06 13.81 4.09 129.51 15:07 13.78 4.13 131.91 15:08 13.70 4.15 135.36 15:09 13.83 4.15 137.93 15:10 13.84 4.10 137.48 15:11 13.80 4.13 136.32 15:12 13.84 4.09 137.23 15:13 13.64 4.15 139.30 15:14 13.75 4.20 139.82 15:15 13.78 4.13 140.81 15:16 13.80 4.15 140.82 15:17 13.86 4.09 140.83 15:18 13.76 4.12 140.82 15:19 13.80 4.14 142.08 15:20 13.74 4.13 141.60 15:21 13.91 4.13 140.64 15:22 13.89 4.04 140.31 15:23 13.76 4.10 138.89 15:24 13.90 4.11 135.96 15:25 13.74 4.08 134.72 15:26 13.59 4.19 134.77 15:27 13.70 4.24 133.14 15:28 13.74 4.15 133.81 15:29 13.64 4.19 135.67 15:30 13.74 4.19 132.86 15:31 13.66 4.15 135.62 15:32 13.45 4.27 135.11 15:33 13.68 4.28 134.60 15:34 13.61 4.21 131.88 15:35 13.66 4.23 131.52 15:36 13.74 4.19 132.32 15:37 13.71 4.15 131.86 15:38 13.58 4.21 133.08 15:39 13.64 4.26 133.53 15:40 13.79 4.18 131.83 15:41 13.60 4.16 130.48 15:42 13.74 4.24 129.97 15:43 13.77 4.12 129.89 15:44 13.54 4.19 131.96 15:45 13.70 4.26 131.23 15:46 13.68 4.17 129.65 15:47 13.61 4.23 130.49 15:48 13.68 4.22 129.98 15:49 13.69 4.20 131.99 15:50 13.57 4.22 131.59 15:51 13.51 4.28 131.98 15:52 13.65 4.28 131.28 15:53 13.59 4.21 131.02 15:54 13.55 4.29 132.91 15:55 13.76 4.22 132.70 15:56 13.56 4.19 132.32 15:57 13.63 4.26 132.25 Pepperidge Farm Incorporated - Richmond, UT Process Line No. 11 AST-2024-4537 10/24/24 27 of 91 Appendix C 28 of 91 www.alliancetg.com Alliance Technical Group, LLC Analytical Servives 5530 Marshall St. Arvada, CO 80002 (720) 457-9504 Project No.AST-2024-4537 Analytical Laboratory Report Pepperidge Farm 901 North 200 West Richmond, UT 84333 1 of 46 29 of 9129 of 91 James Davidson Date Quality Assurance Associate Certification Statement Alliance Source Testing, LLC (AST) has completed the analysis as described in this report. Results apply only to the source(s) tested and operating condition(s) for the specific test date(s) and time(s) identified within this report. All results are intended to be considered in their entirety, and AST is not responsible for use of less than the complete test report without written consent. This report shall not be reproduced in full or in part without written approval from the customer. To the best of my knowledge and abilities, all information, facts and test data are correct. Data presented in this report has been checked for completeness and is accurate, error-free and legible. Any deviations or problems are detailed in the relevant sections on the test report. This document was prepared in portable document format (.pdf) and contains pages as identified in the bottom footer of this document. Validation Signature The analytical data and all QC contained within this report was reviewed and validated by the following individual. 2 of 46 Digitally signed by James DavidsonDN: C=US, CN=James Davidson, E=james.davidson@stacktest.comReason: I attest to the accuracy and integrity of this documentLocation: your signing location hereDate: 2024.11.06 14:08:06-06'00'Foxit PDF Editor Version: 11.2.11James Davidson 30 of 9130 of 91 Project Narrative Analytical Method:Method 18—Measurement of Gaseous Organic Compound Emissions by Gas Chromatography Calibration:Three certified calibration standards containing each analyte of interest were analyzed, each in triplicate agreement of 5% of their mean, to produce a regression line of concentration versus area count. Sample Analysis:The retention times of the analytes in the calibration standards were used to identify peaks in the sample chromatograms. The area counts of the peaks in the sample chromatograms were multiplied by the slope of the appropriate calibration line to determine the concentration of target analytes in the samples. MDL:The Minimum Detection Level (MDL) is 0.02 (C1) and 0.05 (C2) ppm per fraction. If the measured result for a fraction is less than the MDL, the MDL was used in ensuing calculations. Custody:The samples were received by Carson Williamson on 10/28/2024 at 11:00 in Arvada, CO. The samples were received in good condition with proper Chain-of-Custody documentation. No apparent container problems were noted upon receipt. Prior to analysis, the samples were kept secure with access limited to authorized personnel of AST. Number of Samples:6 (3 on hold) Labeling: Acceptable Analyst:Carson Williamson-Laboratory Analyst I Equipment:Agilent 8890 GC-FID System S/N: US2131A004; Column: Restek MXT-1 S/N:1646930 QC Notes:The samples met the minimum criteria established by the relevant method. Reporting Notes:none 3 of 46 31 of 9131 of 91 LocationSourceProject No.Method AnalystAnalysis Date InstrumentAnalyte Lower Curve Limit ppm Upper Curve Limit ppm J - Estimated Value, Value less than the lowest standard Limit of Detection ppm E - Estimated Value, Value greater than the highest standard Lab ID Field ID Ret. Time #1 (min.)Ret. Time #2 (min.)Ret. Time #3 (min.)%RD Dilution Factor Recovery Eff.Measured Conc. (ppm) D49439 M18-Line No.11 Primary Bag-Run 1 4.73 4.73 4.73 821 821 821 821 0.03 1 0.976 821 841 D49440 M18-Line No.11 Primary Bag-Run 2 4.73 4.73 4.73 755 754 755 755 0.08 1 0.976 755 774 D49441 M18-Line No.11 Primary Bag-Run 3 4.73 4.73 4.73 707 707 707 707 0.03 1 0.976 707 724 AST-2024-4537 EPA Method 18: Determination of Gaseous Organic Compounds using Gas Chromatography Agilent 8890 GC-FID System S/N: US2131A004; Column: Restek MXT-1 S/N:1646930 10/28,29/2024Carson Williamson-Laboratory Analyst I Pepperidge FarmLine No.11 Average (ppm) Adjusted Conc. (ppm) ND - Non Detect Sample #3 (ppm) Sample #2 (ppm) Sample #1 (ppm) 0.022010 0.422Methane 4 of 46 32 o f 9 1 32 of 91 LocationSourceProject No.Method AnalystAnalysis Date InstrumentAnalyte Lower Curve Limit ppm Upper Curve Limit ppm J - Estimated Value, Value less than the lowest standard Limit of Detection ppm E - Estimated Value, Value greater than the highest standard Lab ID Field ID Ret. Time #1 (min.)Ret. Time #2 (min.)Ret. Time #3 (min.)%RD Dilution Factor Recovery Eff.Measured Conc. (ppm) D49439 M18-Line No.11 Primary Bag-Run 1 4.96 4.96 4.96 33.6 33.4 33.5 33.5 0.18 1 0.975 33.5 34.4 D49440 M18-Line No.11 Primary Bag-Run 2 4.96 4.96 4.96 30.7 30.8 30.7 30.7 0.19 1 0.975 30.7 31.5 D49441 M18-Line No.11 Primary Bag-Run 3 4.96 4.96 4.96 30.5 30.6 30.5 30.5 0.08 1 0.975 30.5 31.3 2008 0.503Ethane 10/28,29/2024Carson Williamson-Laboratory Analyst I AST-2024-4537 EPA Method 18: Determination of Gaseous Organic Compounds using Gas Chromatography Adjusted Conc. (ppm) ND - Non Detect Sample #1 (ppm) Sample #2 (ppm) Sample #3 (ppm) Average (ppm) Agilent 8890 GC-FID System S/N: US2131A004; Column: Restek MXT-1 S/N:1646930 0.05 Pepperidge FarmLine No.11 5 of 46 33 o f 9 1 33 of 91 LocationSourceProject No.Method Cpd Inj. 1 Inj. 2 Inj. 3 ID RT AC ppm RT AC ppm RT AC ppm RT AC ppm Methane 4.73 565 821 4.73 565 821 4.73 565 821 4.73 565 821 Ethane 4.96 42.1 33.6 4.96 42.0 33.4 4.96 42.0 33.5 4.96 42.0 33.5 Cpd Inj. 1 Inj. 2 Inj. 3IDRTACppmRTACppmRTAC ppm RT AC ppmMethane4.73 520 755 4.73 519 754 4.73 520 755 4.73 520 755Ethane4.96 38.5 30.7 4.96 38.6 30.8 4.96 38.5 30.7 4.96 38.5 30.7 Cpd Inj. 1 Inj. 2 Inj. 3 ID RT AC ppm RT AC ppm RT AC ppm RT AC ppm Methane 4.73 487 707 4.73 487 707 4.73 487 707 4.73 487 707 Ethane 4.96 38.3 30.5 4.96 38.4 30.6 4.96 38.3 30.5 4.96 38.3 30.5 M18-Line No.11 Primary Bag-Run 3 Average Average Sample Analysis M18-Line No.11 Primary Bag-Run 1 M18-Line No.11 Primary Bag-Run 2 Average EPA Method 18: Determination of Gaseous Organic Compounds using Gas Chromatography Pepperidge FarmLine No.11AST-2024-4537 6 of 46 34 of 9134 of 91 LocationSource Project No.Method Cpd Conc. ID (ppm)RT AC RT AC RT AC RT AC OK? Methane 2010 4.73 1387 4.73 1381 4.73 1372 4.73 1380 YEthane20084.96 2517 4.96 2507 4.96 2491 4.96 2505 Y Cpd Conc. ID (ppm)RT AC RT AC RT AC RT AC OK? Methane 998 4.73 696 4.73 696 4.73 696 4.73 696 YEthane9864.96 1267 4.96 1266 4.96 1266 4.96 1266 Y Cpd Conc. ID (ppm)RT AC RT AC RT AC RT AC OK? Methane 0.422 4.72 0.300 4.72 0.300 4.72 0.294 4.72 0.298 YEthane0.503 4.96 0.643 4.96 0.640 4.96 0.642 4.96 0.642 Y Inj. 1 Pepperidge FarmLine No.11 AST-2024-4537EPA Method 18: Determination of Gaseous Organic Compounds using Gas Chromatography Initial Three-Point Calibration High Level Calibration Standard Mid-Level Calibration Standard Inj. 3Inj. 2 Average Inj. 1 Inj. 2 Inj. 3Low-Level Calibration Standard Inj. 1 Inj. 2 Inj. 3 Average Average 7 of 46 35 of 91 LocationSourceProject No.Method Certified Average ppm from Certified Average ppm fromppmACcurveppmACcurve 2010 1380 R2 M 2004 2008 2505 R2 M 19969986961010986126610090.422 0.298 0.433 0.503 0.642 0.511 EPA Method 18: Determination of Gaseous Organic Compounds using Gas ChromatographyAST-2024-4537Line No.11Pepperidge Farm Linear Regression Linear RegressionMethaneEthane 0.7970.99971.450.9999 Linear Regression Calculations Statistics Statistics 0 500 1000 1500 2000 2500 0 500 1000 1500 2000 2500 3000 pp m Area Counts Methane Ethane Linear (Methane) Linear (Ethane) 8 of 46 36 of 9136 of 91 LocationSource Project No.Method Analysis Date Cpd Conc.ID (ppm)RT AC RT AC RT AC RT AC ppm Methane 0.00 n/a 0 n/a 0.00 0.00Ethane0.00 n/a 0 n/a 0.00 0.00 Cpd Conc.ID (ppm)RT AC RT AC RT AC RT AC ppm Methane 998 4.73 670 4.73 670 4.73 670 4.73 670 973Ethane9864.96 1214 4.96 1214 4.96 1214 4.96 1214 967 Cpd Conc.ID (ppm)RT AC RT AC RT AC RT AC ppm Methane 998 4.73 668 4.73 668 4.73 668 4.73 668 970Ethane9864.96 1208 4.96 1209 4.96 1208 4.96 1208 963 Average Average Nitrogen Blank Inj. 1 Inj. 2 Inj. 3 Inj. 1 Inj. 2 Inj. 3 Post CCV Average Inj. 1 Inj. 2 Inj. 3 Initial CCV Quality Assurance Pepperidge FarmLine No.11 AST-2024-4537EPA Method 18: Determination of Gaseous Organic Compounds using Gas Chromatography 10/28/2024 9 of 46 37 of 91 LocationSource Project No.Method Analysis Date Cpd Conc.ID (ppm)RT AC RT AC RT AC RT AC ppm Methane 518 4.72 348 4.72 348 4.72 348 4.72 348 506 Ethane 21.5 4.96 26.2 4.96 26.3 4.96 26.2 4.96 26.2 20.9 Cpd Conc.ID (ppm)RT AC RT AC RT AC RT AC ppm Methane 0.00 n/a 0.000 n/a 0.000 0.000Ethane0.00 n/a 0.000 n/a 0.000 0.000 Cpd Conc. ID (ppm)RT AC RT AC RT AC RT AC ppm Methane 998 4.73 662 4.73 660 4.73 659 4.73 660 959Ethane9864.96 1195 4.96 1192 4.96 1190 4.96 1192 950 Cpd Conc. ID (ppm)RT AC RT AC RT AC RT AC ppmMethane9984.73 659 4.73 659 4.73 660 4.73 660 958 Ethane 986 4.96 1191 4.96 1190 4.96 1192 4.96 1191 949 Pepperidge Farm Line No.11 AST-2024-4537 EPA Method 18: Determination of Gaseous Organic Compounds using Gas Chromatography Quality Assurance 1L-M18-Line No.11 Primary Bag Run 3 : 1L-329.4 ppm C1; 12.357 ppm C2 Cal Standard Concentration Inj. 1 Inj. 2 Inj. 3 Average 10/29/2024 Nitrogen Blank Inj. 1 Inj. 2 Inj. 3 Average Initial CCVInj. 1 Inj. 2 Inj. 3 Average Post CCVInj. 1 Inj. 2 Inj. 3 Average 10 of 46 38 of 9138 of 91 11 of 46 39 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 27 Sample Operator : SYSTEM min3456789101112 pA 0 50 100 150 200 250 300 4. 7 2 5 - M e t h a n e 4. 9 6 2 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.725 MF 565.39301 1.41706 801.19306 Methane 4.962 FM 42.10220 7.78803e-1 32.78932 Ethane Totals : 833.98238 W8250 AST 10/29/2024 9:28:00 AM SYSTEM Page 1 of 2 Data File C:\Users\P...7 102824 2024-10-28 15-18-01\F-027-9-Line No.11-Primary Bag Run 1.D Sample Name: Line No.11-Primary Bag Run 1 Acq. Instrument : W8250 AST Location : 9 (F) Injection Date : 10/28/2024 9:51:28 PM Inj : 1 Inj Volume : 10 µl Acq. Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M Last changed : 10/15/2024 5:27:03 PM by SYSTEM Analysis Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/29/2024 8:44:03 AM by SYSTEM (modified after loading) Additional Info : Peak(s) manually integrated FID1 A, Front Signal (AST-2024-4...487 102824 2024-10-28 15-18-01\F-027-9-Line No.11-Primary Bag Run 1.D) 12 of 46 40 of 9140 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 28 Sample Operator : SYSTEM min3456789101112 pA 0 50 100 150 200 250 300 4. 7 2 5 - M e t h a n e 4. 9 6 2 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.725 BV 565.14221 1.41706 800.83772 Methane 4.962 VB 41.95267 7.78796e-1 32.67259 Ethane Totals : 833.51031 W8250 AST 10/29/2024 9:28:40 AM SYSTEM Page 1 of 2 Data File C:\Users\P...7 102824 2024-10-28 15-18-01\F-028-9-Line No.11-Primary Bag Run 1.D Sample Name: Line No.11-Primary Bag Run 1 Acq. Instrument : W8250 AST Location : 9 (F) Injection Date : 10/28/2024 10:06:32 PM Inj : 2 Inj Volume : 10 µl Acq. Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M Last changed : 10/15/2024 5:27:03 PM by SYSTEM Analysis Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/29/2024 8:44:03 AM by SYSTEM (modified after loading) Additional Info : Peak(s) manually integrated FID1 A, Front Signal (AST-2024-4...487 102824 2024-10-28 15-18-01\F-028-9-Line No.11-Primary Bag Run 1.D) 13 of 46 41 of 9141 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 29 Sample Operator : SYSTEM min3456789101112 pA 0 50 100 150 200 250 300 4. 7 2 5 - M e t h a n e 4. 9 6 2 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.725 MF 565.14667 1.41706 800.84404 Methane 4.962 VB 42.01976 7.78799e-1 32.72497 Ethane Totals : 833.56900 W8250 AST 10/29/2024 9:29:57 AM SYSTEM Page 1 of 2 Data File C:\Users\P...7 102824 2024-10-28 15-18-01\F-029-9-Line No.11-Primary Bag Run 1.D Sample Name: Line No.11-Primary Bag Run 1 Acq. Instrument : W8250 AST Location : 9 (F) Injection Date : 10/28/2024 10:21:40 PM Inj : 3 Inj Volume : 10 µl Acq. Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M Last changed : 10/15/2024 5:27:03 PM by SYSTEM Analysis Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/29/2024 8:44:03 AM by SYSTEM (modified after loading) Additional Info : Peak(s) manually integrated FID1 A, Front Signal (AST-2024-4...487 102824 2024-10-28 15-18-01\F-029-9-Line No.11-Primary Bag Run 1.D) 14 of 46 42 of 9142 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 30 Sample Operator : SYSTEM min3456789101112 pA 0 50 100 150 200 250 FID1 A, Front Signal (AST-2024-4...87 102824 2024-10-28 15-18-01\F-030-10-Line No.10-Primary Bag Run 2.D) 4. 7 2 6 - M e t h a n e 4. 9 6 2 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.726 MF 520.00244 1.41707 736.88119 Methane 4.962 VB 38.52835 7.78626e-1 29.99919 Ethane Totals : 766.88038 W8250 AST 10/29/2024 9:30:50 AM SYSTEM Page 1 of 2 Data File C:\Users\P... 102824 2024-10-28 15-18-01\F-030-10-Line No.10-Primary Bag Run 2.D Sample Name: Line No.11-Primary Bag Run 2 Acq. Instrument : W8250 AST Location : 10 (F) Injection Date : 10/28/2024 10:36:43 PM Inj : 1 Inj Volume : 10 µl Acq. Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M Last changed : 10/15/2024 5:27:03 PM by SYSTEM Analysis Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/29/2024 8:44:03 AM by SYSTEM (modified after loading) Additional Info : Peak(s) manually integrated 15 of 46 43 of 9143 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 31 Sample Operator : SYSTEM min3456789101112 pA 0 50 100 150 200 250 FID1 A, Front Signal (AST-2024-4...87 102824 2024-10-28 15-18-01\F-031-10-Line No.10-Primary Bag Run 2.D) 4. 7 2 5 - M e t h a n e 4. 9 6 1 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.725 MF 519.43390 1.41707 736.07565 Methane 4.961 FM 38.62339 7.78631e-1 30.07338 Ethane Totals : 766.14903 W8250 AST 10/29/2024 9:32:24 AM SYSTEM Page 1 of 2 Data File C:\Users\P... 102824 2024-10-28 15-18-01\F-031-10-Line No.10-Primary Bag Run 2.D Sample Name: Line No.11-Primary Bag Run 2 Acq. Instrument : W8250 AST Location : 10 (F) Injection Date : 10/28/2024 10:51:49 PM Inj : 2 Inj Volume : 10 µl Acq. Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M Last changed : 10/15/2024 5:27:03 PM by SYSTEM Analysis Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/29/2024 8:44:03 AM by SYSTEM (modified after loading) Additional Info : Peak(s) manually integrated 16 of 46 44 of 9144 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 32 Sample Operator : SYSTEM min3456789101112 pA 0 50 100 150 200 250 FID1 A, Front Signal (AST-2024-4...87 102824 2024-10-28 15-18-01\F-032-10-Line No.10-Primary Bag Run 2.D) 4. 7 2 6 - M e t h a n e 4. 9 6 2 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.726 BV 520.18463 1.41707 737.13933 Methane 4.962 VB 38.49572 7.78625e-1 29.97371 Ethane Totals : 767.11304 W8250 AST 10/29/2024 9:32:52 AM SYSTEM Page 1 of 2 Data File C:\Users\P... 102824 2024-10-28 15-18-01\F-032-10-Line No.10-Primary Bag Run 2.D Sample Name: Line No.11-Primary Bag Run 2 Acq. Instrument : W8250 AST Location : 10 (F) Injection Date : 10/28/2024 11:06:51 PM Inj : 3 Inj Volume : 10 µl Acq. Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M Last changed : 10/15/2024 5:27:03 PM by SYSTEM Analysis Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/29/2024 8:44:03 AM by SYSTEM (modified after loading) Additional Info : Peak(s) manually integrated 17 of 46 45 of 9145 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 33 Sample Operator : SYSTEM min3456789101112 pA 0 50 100 150 200 250 FID1 A, Front Signal (AST-2024-4...87 102824 2024-10-28 15-18-01\F-033-11-Line No.10-Primary Bag Run 3.D) 4. 7 2 5 - M e t h a n e 4. 9 6 1 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.725 BV 486.79147 1.41709 689.82605 Methane 4.961 VB 38.31608 7.78615e-1 29.83346 Ethane Totals : 719.65952 W8250 AST 10/29/2024 9:35:53 AM SYSTEM Page 1 of 2 Data File C:\Users\P... 102824 2024-10-28 15-18-01\F-033-11-Line No.10-Primary Bag Run 3.D Sample Name: Line No.11-Primary Bag Run 3 Acq. Instrument : W8250 AST Location : 11 (F) Injection Date : 10/28/2024 11:22:02 PM Inj : 1 Inj Volume : 10 µl Acq. Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M Last changed : 10/15/2024 5:27:03 PM by SYSTEM Analysis Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/29/2024 8:44:03 AM by SYSTEM (modified after loading) Additional Info : Peak(s) manually integrated 18 of 46 46 of 9146 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 34 Sample Operator : SYSTEM min3456789101112 pA 0 50 100 150 200 250 FID1 A, Front Signal (AST-2024-4...87 102824 2024-10-28 15-18-01\F-034-11-Line No.10-Primary Bag Run 3.D) 4. 7 2 5 - M e t h a n e 4. 9 6 2 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.725 BV 486.93793 1.41709 690.03356 Methane 4.962 VB 38.36242 7.78617e-1 29.86965 Ethane Totals : 719.90320 W8250 AST 10/29/2024 9:37:04 AM SYSTEM Page 1 of 2 Data File C:\Users\P... 102824 2024-10-28 15-18-01\F-034-11-Line No.10-Primary Bag Run 3.D Sample Name: Line No.11-Primary Bag Run 3 Acq. Instrument : W8250 AST Location : 11 (F) Injection Date : 10/28/2024 11:37:10 PM Inj : 2 Inj Volume : 10 µl Acq. Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M Last changed : 10/15/2024 5:27:03 PM by SYSTEM Analysis Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/29/2024 8:44:03 AM by SYSTEM (modified after loading) Additional Info : Peak(s) manually integrated 19 of 46 47 of 9147 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 35 Sample Operator : SYSTEM min3456789101112 pA 0 50 100 150 200 250 FID1 A, Front Signal (AST-2024-4...87 102824 2024-10-28 15-18-01\F-035-11-Line No.10-Primary Bag Run 3.D) 4. 7 2 5 - M e t h a n e 4. 9 6 1 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.725 BV 486.70361 1.41709 689.70157 Methane 4.961 VB 38.31884 7.78615e-1 29.83562 Ethane Totals : 719.53719 W8250 AST 10/29/2024 9:38:01 AM SYSTEM Page 1 of 2 Data File C:\Users\P... 102824 2024-10-28 15-18-01\F-035-11-Line No.10-Primary Bag Run 3.D Sample Name: Line No.11-Primary Bag Run 3 Acq. Instrument : W8250 AST Location : 11 (F) Injection Date : 10/28/2024 11:52:23 PM Inj : 3 Inj Volume : 10 µl Acq. Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M Last changed : 10/15/2024 5:27:03 PM by SYSTEM Analysis Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/29/2024 8:44:03 AM by SYSTEM (modified after loading) Additional Info : Peak(s) manually integrated 20 of 46 48 of 9148 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 9 Sample Operator : SYSTEM Additional Info : Peak(s) manually integrated min3456789101112 pA 0 25 50 75 100 125 150 175 FID1 A, Front Signal (AST-2024-4...102924 2024-10-29 10-54-01\F-009-6-Line No.10 Primary Bag Run 3 C1 .D) 4. 7 2 3 - M e t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.723 MF 348.44354 1.41718 493.80704 Methane 4.960 - - - Ethane Totals : 493.80704 Uncalibrated peaks RF : 1.00000 W8250 AST 10/29/2024 2:19:44 PM SYSTEM Page 1 of 2 Data File C:\Users\P...2924 2024-10-29 10-54-01\F-009-6-Line No.10 Primary Bag Run 3 C1 .D Sample Name: Line No.11 Primary Bag Run 3 C1 Spk Acq. Instrument : W8250 AST Location : 6 (F) Injection Date : 10/29/2024 12:57:15 PM Inj : 1 Inj Volume : 10 µl Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537 Spk 102924 2024- 10-29 10-54-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/15/2024 5:27:03 PM by SYSTEM 21 of 46 49 of 9149 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 10 Sample Operator : SYSTEM Additional Info : Peak(s) manually integrated min3456789101112 pA 0 25 50 75 100 125 150 175 FID1 A, Front Signal (AST-2024-4...102924 2024-10-29 10-54-01\F-010-6-Line No.10 Primary Bag Run 3 C1 .D) 4. 7 2 3 - M e t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.723 MF 348.34674 1.41718 493.66988 Methane 4.960 - - - Ethane Totals : 493.66988 Uncalibrated peaks RF : 1.00000 W8250 AST 10/29/2024 2:20:34 PM SYSTEM Page 1 of 2 Data File C:\Users\P...2924 2024-10-29 10-54-01\F-010-6-Line No.10 Primary Bag Run 3 C1 .D Sample Name: Line No.11 Primary Bag Run 3 C1 Spk Acq. Instrument : W8250 AST Location : 6 (F) Injection Date : 10/29/2024 1:12:36 PM Inj : 2 Inj Volume : 10 µl Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537 Spk 102924 2024- 10-29 10-54-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/15/2024 5:27:03 PM by SYSTEM 22 of 46 50 of 9150 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 11 Sample Operator : SYSTEM Additional Info : Peak(s) manually integrated min3456789101112 pA 0 25 50 75 100 125 150 175 FID1 A, Front Signal (AST-2024-4...102924 2024-10-29 10-54-01\F-011-6-Line No.10 Primary Bag Run 3 C1 .D) 4. 7 2 4 - M e t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.724 MF 347.93698 1.41718 493.08931 Methane 4.960 - - - Ethane Totals : 493.08931 Uncalibrated peaks RF : 1.00000 W8250 AST 10/29/2024 2:20:51 PM SYSTEM Page 1 of 2 Data File C:\Users\P...2924 2024-10-29 10-54-01\F-011-6-Line No.10 Primary Bag Run 3 C1 .D Sample Name: Line No.11 Primary Bag Run 3 C1 Spk Acq. Instrument : W8250 AST Location : 6 (F) Injection Date : 10/29/2024 1:27:47 PM Inj : 3 Inj Volume : 10 µl Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537 Spk 102924 2024- 10-29 10-54-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/15/2024 5:27:03 PM by SYSTEM 23 of 46 51 of 9151 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 12 Sample Operator : SYSTEM Additional Info : Peak(s) manually integrated min3456789101112 pA 0 20 40 60 80 100 120 FID1 A, Front Signal (AST-2024-4...102924 2024-10-29 10-54-01\F-012-7-Line No.10 Primary Bag Run 3 C2 .D) 4. 9 5 9 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.720 - - - Methane 4.959 VB 26.19981 7.77646e-1 20.37417 Ethane Totals : 20.37417 Uncalibrated peaks RF : 1.00000 W8250 AST 10/29/2024 2:21:10 PM SYSTEM Page 1 of 2 Data File C:\Users\P...2924 2024-10-29 10-54-01\F-012-7-Line No.10 Primary Bag Run 3 C2 .D Sample Name: Line No.11 Primary Bag Run 3 C2 Spk Acq. Instrument : W8250 AST Location : 7 (F) Injection Date : 10/29/2024 1:43:07 PM Inj : 1 Inj Volume : 10 µl Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537 Spk 102924 2024- 10-29 10-54-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/15/2024 5:27:03 PM by SYSTEM 24 of 46 52 of 9152 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 13 Sample Operator : SYSTEM Additional Info : Peak(s) manually integrated min3456789101112 pA 0 20 40 60 80 100 120 FID1 A, Front Signal (AST-2024-4...102924 2024-10-29 10-54-01\F-013-7-Line No.10 Primary Bag Run 3 C2 .D) 4. 9 6 0 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.720 - - - Methane 4.960 VB 26.30844 7.77658e-1 20.45898 Ethane Totals : 20.45898 Uncalibrated peaks RF : 1.00000 W8250 AST 10/29/2024 2:21:34 PM SYSTEM Page 1 of 2 Data File C:\Users\P...2924 2024-10-29 10-54-01\F-013-7-Line No.10 Primary Bag Run 3 C2 .D Sample Name: Line No.11 Primary Bag Run 3 C2 Spk Acq. Instrument : W8250 AST Location : 7 (F) Injection Date : 10/29/2024 1:58:17 PM Inj : 2 Inj Volume : 10 µl Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537 Spk 102924 2024- 10-29 10-54-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/15/2024 5:27:03 PM by SYSTEM 25 of 46 53 of 9153 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 14 Sample Operator : SYSTEM Additional Info : Peak(s) manually integrated min3456789101112 pA 0 20 40 60 80 100 120 FID1 A, Front Signal (AST-2024-4...102924 2024-10-29 10-54-01\F-014-7-Line No.10 Primary Bag Run 3 C2 .D) 4. 9 5 9 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.720 - - - Methane 4.959 VB 26.16619 7.77642e-1 20.34792 Ethane Totals : 20.34792 Uncalibrated peaks RF : 1.00000 W8250 AST 10/29/2024 3:14:37 PM SYSTEM Page 1 of 2 Data File C:\Users\P...2924 2024-10-29 10-54-01\F-014-7-Line No.10 Primary Bag Run 3 C2 .D Sample Name: Line No.11 Primary Bag Run 3 C2 Spk Acq. Instrument : W8250 AST Location : 7 (F) Injection Date : 10/29/2024 2:13:39 PM Inj : 3 Inj Volume : 10 µl Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537 Spk 102924 2024- 10-29 10-54-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/15/2024 5:27:03 PM by SYSTEM 26 of 46 54 of 9154 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 2 Sample Operator : SYSTEM Acq. Instrument : W8250 AST Location : 1 (F) Injection Date : 10/28/2024 3:33:58 PM Inj : 2 Inj Volume : 10 µl Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/15/2024 5:27:03 PM by SYSTEM Additional Info : Peak(s) manually integrated min3456789101112 pA 4 4.25 4.5 4.75 5 5.25 5.5 5.75 6 FID1 A, Front Signal (AST-2024-4537,4487 102824 2024-10-28 15-18-01\F-002-1-N2 Blank.D) ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.720 - - - Methane 4.960 - - - Ethane Totals : 0.00000 Uncalibrated peaks RF : 1.00000 Data File C:\Users\P...ta\AST-2024-4537,4487 102824 2024-10-28 15-18-01\F-002-1-N2 Blank.D Sample Name: N2 Blank W8250 AST 10/30/2024 1:54:10 PM SYSTEM Page 1 of 2 27 of 46 55 of 9155 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 2 Sample Operator : SYSTEM Acq. Instrument : W8250 AST Location : 1 (F) Injection Date : 10/29/2024 11:09:55 AM Inj : 2 Inj Volume : 10 µl Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537 Spk 102924 2024- 10-29 10-54-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/15/2024 5:27:03 PM by SYSTEM Additional Info : Peak(s) manually integrated min3456789101112 pA 4.5 5 5.5 6 6.5 7 7.5 FID1 A, Front Signal (AST-2024-4537 Spk 102924 2024-10-29 10-54-01\F-002-1-N2 Blank.D) ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.720 - - - Methane 4.960 - - - Ethane Totals : 0.00000 Uncalibrated peaks RF : 1.00000 Data File C:\Users\P...ata\AST-2024-4537 Spk 102924 2024-10-29 10-54-01\F-002-1-N2 Blank.D Sample Name: N2 Blank W8250 AST 10/29/2024 2:16:57 PM SYSTEM Page 1 of 2 28 of 46 56 of 9156 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 24 Sample Operator : SYSTEM Acq. Instrument : W8250 AST Location : 8 (F) Injection Date : 10/28/2024 9:06:15 PM Inj : 1 Inj Volume : 10 µl Acq. Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M Last changed : 10/15/2024 5:27:03 PM by SYSTEM Analysis Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/29/2024 8:44:03 AM by SYSTEM (modified after loading) Additional Info : Peak(s) manually integrated min3456789101112 pA 0 100 200 300 400 500 FID1 A, Front Signal (AST-2024-4537,4487 102824 2024-10-28 15-18-01\F-024-8-CCVi 1000ppm 102824.D) 4. 7 2 5 - M e t h a n e 4. 9 6 1 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.725 BB 669.98199 1.41702 949.38054 Methane 4.961 BB 1213.74194 7.80644e-1 947.50044 Ethane Totals : 1896.88098 Data File C:\Users\P...-4537,4487 102824 2024-10-28 15-18-01\F-024-8-CCVi 1000ppm 102824.D Sample Name: CCVi 1000ppm 102824 W8250 AST 10/29/2024 9:23:56 AM SYSTEM Page 1 of 2 29 of 46 57 of 9157 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 25 Sample Operator : SYSTEM Acq. Instrument : W8250 AST Location : 8 (F) Injection Date : 10/28/2024 9:21:16 PM Inj : 2 Inj Volume : 10 µl Acq. Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M Last changed : 10/15/2024 5:27:03 PM by SYSTEM Analysis Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/29/2024 8:44:03 AM by SYSTEM (modified after loading) Additional Info : Peak(s) manually integrated min3456789101112 pA 0 100 200 300 400 500 FID1 A, Front Signal (AST-2024-4537,4487 102824 2024-10-28 15-18-01\F-025-8-CCVi 1000ppm 102824.D) 4. 7 2 5 - M e t h a n e 4. 9 6 1 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.725 BB 669.85217 1.41702 949.19660 Methane 4.961 BB 1213.50696 7.80644e-1 947.31698 Ethane Totals : 1896.51358 Data File C:\Users\P...-4537,4487 102824 2024-10-28 15-18-01\F-025-8-CCVi 1000ppm 102824.D Sample Name: CCVi 1000ppm 102824 W8250 AST 10/29/2024 9:25:30 AM SYSTEM Page 1 of 2 30 of 46 58 of 9158 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 26 Sample Operator : SYSTEM Acq. Instrument : W8250 AST Location : 8 (F) Injection Date : 10/28/2024 9:36:22 PM Inj : 3 Inj Volume : 10 µl Acq. Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M Last changed : 10/15/2024 5:27:03 PM by SYSTEM Analysis Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/29/2024 8:44:03 AM by SYSTEM (modified after loading) Additional Info : Peak(s) manually integrated min3456789101112 pA 0 100 200 300 400 500 FID1 A, Front Signal (AST-2024-4537,4487 102824 2024-10-28 15-18-01\F-026-8-CCVi 1000ppm 102824.D) 4. 7 2 5 - M e t h a n e 4. 9 6 1 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.725 BB 670.20300 1.41702 949.69368 Methane 4.961 BB 1214.25037 7.80644e-1 947.89737 Ethane Totals : 1897.59105 Data File C:\Users\P...-4537,4487 102824 2024-10-28 15-18-01\F-026-8-CCVi 1000ppm 102824.D Sample Name: CCVi 1000ppm 102824 W8250 AST 10/29/2024 9:26:12 AM SYSTEM Page 1 of 2 31 of 46 59 of 9159 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 36 Sample Operator : SYSTEM Acq. Instrument : W8250 AST Location : 8 (F) Injection Date : 10/29/2024 12:07:40 AM Inj : 1 Inj Volume : 10 µl Acq. Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M Last changed : 10/15/2024 5:27:03 PM by SYSTEM Analysis Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/29/2024 8:44:03 AM by SYSTEM (modified after loading) Additional Info : Peak(s) manually integrated min3456789101112 pA 0 100 200 300 400 500 FID1 A, Front Signal (AST-2024-4537,4487 102824 2024-10-28 15-18-01\F-036-8-CCVf 1000ppm 102824.D) 4. 7 2 5 - M e t h a n e 4. 9 6 0 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.725 BB 667.49976 1.41702 945.86356 Methane 4.960 BB 1207.72583 7.80644e-1 942.80360 Ethane Totals : 1888.66716 Data File C:\Users\P...-4537,4487 102824 2024-10-28 15-18-01\F-036-8-CCVf 1000ppm 102824.D Sample Name: CCVf 1000ppm 102824 W8250 AST 10/29/2024 9:39:24 AM SYSTEM Page 1 of 2 32 of 46 60 of 9160 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 37 Sample Operator : SYSTEM Acq. Instrument : W8250 AST Location : 8 (F) Injection Date : 10/29/2024 12:22:51 AM Inj : 2 Inj Volume : 10 µl Acq. Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M Last changed : 10/15/2024 5:27:03 PM by SYSTEM Analysis Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/29/2024 8:44:03 AM by SYSTEM (modified after loading) Additional Info : Peak(s) manually integrated min3456789101112 pA 0 100 200 300 400 500 FID1 A, Front Signal (AST-2024-4537,4487 102824 2024-10-28 15-18-01\F-037-8-CCVf 1000ppm 102824.D) 4. 7 2 4 - M e t h a n e 4. 9 6 0 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.724 BB 667.98779 1.41702 946.55504 Methane 4.960 BB 1208.68030 7.80644e-1 943.54876 Ethane Totals : 1890.10380 Data File C:\Users\P...-4537,4487 102824 2024-10-28 15-18-01\F-037-8-CCVf 1000ppm 102824.D Sample Name: CCVf 1000ppm 102824 W8250 AST 10/29/2024 9:39:58 AM SYSTEM Page 1 of 2 33 of 46 61 of 9161 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 38 Sample Operator : SYSTEM Acq. Instrument : W8250 AST Location : 8 (F) Injection Date : 10/29/2024 12:38:00 AM Inj : 3 Inj Volume : 10 µl Acq. Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M Last changed : 10/15/2024 5:27:03 PM by SYSTEM Analysis Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537,4487 102824 2024 -10-28 15-18-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/29/2024 8:44:03 AM by SYSTEM (modified after loading) Additional Info : Peak(s) manually integrated min3456789101112 pA 0 100 200 300 400 500 FID1 A, Front Signal (AST-2024-4537,4487 102824 2024-10-28 15-18-01\F-038-8-CCVf 1000ppm 102824.D) 4. 7 2 5 - M e t h a n e 4. 9 6 1 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.725 BB 667.85437 1.41702 946.36600 Methane 4.961 BB 1208.40222 7.80644e-1 943.33166 Ethane Totals : 1889.69767 Data File C:\Users\P...-4537,4487 102824 2024-10-28 15-18-01\F-038-8-CCVf 1000ppm 102824.D Sample Name: CCVf 1000ppm 102824 W8250 AST 10/29/2024 9:40:34 AM SYSTEM Page 1 of 2 34 of 46 62 of 9162 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 6 Sample Operator : SYSTEM Additional Info : Peak(s) manually integrated min3456789101112 pA 0 100 200 300 400 500 FID1 A, Front Signal (AST-2024-4537 Spk 102924 2024-10-29 10-54-01\F-006-2-CCVi 1000ppm 102824.D) 4.7 2 4 - M e t h a n e 4. 9 6 0 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.724 MF 661.78473 1.41703 937.76620 Methane 4.960 FM 1195.12817 7.80643e-1 932.96848 Ethane Totals : 1870.73468 Uncalibrated peaks RF : 1.00000 W8250 AST 10/29/2024 2:18:10 PM SYSTEM Page 1 of 2 Data File C:\Users\P...4-4537 Spk 102924 2024-10-29 10-54-01\F-006-2-CCVi 1000ppm 102824.D Sample Name: CCVi 1000ppm 102924 Acq. Instrument : W8250 AST Location : 2 (F) Injection Date : 10/29/2024 12:11:16 PM Inj : 1 Inj Volume : 10 µl Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537 Spk 102924 2024- 10-29 10-54-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/15/2024 5:27:03 PM by SYSTEM 35 of 46 63 of 9163 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 7 Sample Operator : SYSTEM Additional Info : Peak(s) manually integrated min3456789101112 pA 0 100 200 300 400 500 FID1 A, Front Signal (AST-2024-4537 Spk 102924 2024-10-29 10-54-01\F-007-2-CCVi 1000ppm 102824.D) 4. 7 2 3 - M e t h a n e 4. 9 5 9 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.723 BB 660.02899 1.41703 935.27857 Methane 4.959 BB 1191.54602 7.80643e-1 930.17186 Ethane Totals : 1865.45043 Uncalibrated peaks RF : 1.00000 W8250 AST 10/29/2024 2:18:57 PM SYSTEM Page 1 of 2 Data File C:\Users\P...4-4537 Spk 102924 2024-10-29 10-54-01\F-007-2-CCVi 1000ppm 102824.D Sample Name: CCVi 1000ppm 102924 Acq. Instrument : W8250 AST Location : 2 (F) Injection Date : 10/29/2024 12:26:35 PM Inj : 2 Inj Volume : 10 µl Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537 Spk 102924 2024- 10-29 10-54-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/15/2024 5:27:03 PM by SYSTEM 36 of 46 64 of 9164 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 8 Sample Operator : SYSTEM Additional Info : Peak(s) manually integrated min3456789101112 pA 0 100 200 300 400 500 FID1 A, Front Signal (AST-2024-4537 Spk 102924 2024-10-29 10-54-01\F-008-2-CCVi 1000ppm 102824.D) 4. 7 2 3 - M e t h a n e 4. 9 5 9 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.723 BB 659.10657 1.41703 933.97163 Methane 4.959 BB 1189.69641 7.80643e-1 928.72785 Ethane Totals : 1862.69948 Uncalibrated peaks RF : 1.00000 W8250 AST 10/29/2024 2:19:21 PM SYSTEM Page 1 of 2 Data File C:\Users\P...4-4537 Spk 102924 2024-10-29 10-54-01\F-008-2-CCVi 1000ppm 102824.D Sample Name: CCVi 1000ppm 102924 Acq. Instrument : W8250 AST Location : 2 (F) Injection Date : 10/29/2024 12:41:54 PM Inj : 3 Inj Volume : 10 µl Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537 Spk 102924 2024- 10-29 10-54-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/15/2024 5:27:03 PM by SYSTEM 37 of 46 65 of 9165 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 15 Sample Operator : SYSTEM Additional Info : Peak(s) manually integrated min3456789101112 pA 0 100 200 300 400 500 FID1 A, Front Signal (AST-2024-4537 Spk 102924 2024-10-29 10-54-01\F-015-2-CCVf 1000ppm 102824.D) 4. 7 2 3 - M e t h a n e 4. 9 5 9 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.723 BB 659.41077 1.41703 934.40264 Methane 4.959 BB 1190.60034 7.80643e-1 929.43355 Ethane Totals : 1863.83619 Uncalibrated peaks RF : 1.00000 W8250 AST 10/29/2024 3:15:24 PM SYSTEM Page 1 of 2 Data File C:\Users\P...4-4537 Spk 102924 2024-10-29 10-54-01\F-015-2-CCVf 1000ppm 102824.D Sample Name: CCVf 1000ppm 102924 Acq. Instrument : W8250 AST Location : 2 (F) Injection Date : 10/29/2024 2:29:05 PM Inj : 1 Inj Volume : 10 µl Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537 Spk 102924 2024- 10-29 10-54-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/15/2024 5:27:03 PM by SYSTEM 38 of 46 66 of 9166 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 16 Sample Operator : SYSTEM Additional Info : Peak(s) manually integrated min3456789101112 pA 0 100 200 300 400 500 FID1 A, Front Signal (AST-2024-4537 Spk 102924 2024-10-29 10-54-01\F-016-2-CCVf 1000ppm 102824.D) 4. 7 2 3 - M e t h a n e 4. 9 5 9 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.723 BB 659.12012 1.41703 933.99083 Methane 4.959 BB 1190.00537 7.80643e-1 928.96905 Ethane Totals : 1862.95988 Uncalibrated peaks RF : 1.00000 W8250 AST 10/29/2024 3:16:08 PM SYSTEM Page 1 of 2 Data File C:\Users\P...4-4537 Spk 102924 2024-10-29 10-54-01\F-016-2-CCVf 1000ppm 102824.D Sample Name: CCVf 1000ppm 102924 Acq. Instrument : W8250 AST Location : 2 (F) Injection Date : 10/29/2024 2:44:25 PM Inj : 2 Inj Volume : 10 µl Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537 Spk 102924 2024- 10-29 10-54-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/15/2024 5:27:03 PM by SYSTEM 39 of 46 67 of 9167 of 91 ===================================================================== Acq. Operator : SYSTEM Seq. Line : 17 Sample Operator : SYSTEM Additional Info : Peak(s) manually integrated min3456789101112 pA 0 100 200 300 400 500 FID1 A, Front Signal (AST-2024-4537 Spk 102924 2024-10-29 10-54-01\F-017-2-CCVf 1000ppm 102824.D) 4. 7 2 3 - M e t h a n e 4. 9 5 9 - E t h a n e ===================================================================== External Standard Report ===================================================================== Sorted By : Signal Calib. Data Modified : 5/30/2024 3:21:53 PM Multiplier : 1.0000 Dilution : 1.0000 Do not use Multiplier & Dilution Factor with ISTDs Signal 1: FID1 A, Front Signal RetTime Type Area Amt/Area Amount Grp Name [min] [pA*s] [ppm] -------|------|----------|----------|----------|--|------------------ 4.723 BB 660.19202 1.41703 935.50955 Methane 4.959 BB 1192.06079 7.80643e-1 930.57374 Ethane Totals : 1866.08330 Uncalibrated peaks RF : 1.00000 W8250 AST 10/29/2024 3:16:41 PM SYSTEM Page 1 of 2 Data File C:\Users\P...4-4537 Spk 102924 2024-10-29 10-54-01\F-017-2-CCVf 1000ppm 102824.D Sample Name: CCVf 1000ppm 102924 Acq. Instrument : W8250 AST Location : 2 (F) Injection Date : 10/29/2024 2:59:44 PM Inj : 3 Inj Volume : 10 µl Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-4537 Spk 102924 2024- 10-29 10-54-01\FID B, C1C2_TAS.M (Sequence Method) Last changed : 10/15/2024 5:27:03 PM by SYSTEM 40 of 46 68 of 9168 of 91 41 of 46 69 of 91 42 of 46 70 of 91 43 of 46 71 of 91 44 of 46 72 of 91 45 of 46 73 of 91 Appendix D 74 of 91 QA Data Location Source Project No. O₂ - Outlet CO₂ - Outlet NMHC - Outlet Make SERVOMEX SERVOMEX THERMO Model 4900 4900 55i S/N 0410403-2409 0410403-2409 1209052150 Operating Range 100 100 2000 Cylinder ID Zero NA NA NA Low NA NA EB718971 Mid EB0078022 EB0078022 EB718971 High EB0078022 EB0078022 EB718971 Cylinder Certified Values Zero NA NA NA Mid 23.84 24 502 High 23.84 24 502 Cylinder Expiration Date Zero NA NA NA Mid 7/6/32 7/6/32 4/9/32 High 7/6/32 7/6/32 4/9/32 Type of Sample Line Heated Sample Line Parameter Pepperidge Farm Incorporated - Richmond, UT Process Line No. 11 AST-2024-4537 75 of 91 Response Times Location: Source: Project No.: O₂ - Outlet CO₂ - Outlet NMHC - Outlet Zero 46 46 60 Low NA NA 60 Mid 48 48 60 High ------ Average 47.0 47.0 60.0 Pepperidge Farm Incorporated - Richmond, UT Process Line No. 11 AST-2024-4537 Parameter Response Times, seconds 76 of 91 Calibration Data Location: Source: Project No.: Date: O₂ - Outlet CO₂ - Outlet NMHC - Outlet Expected Average Concentration 14.00 5.00 200.00 Span Between Low 14.00 5.00 300.00 High 70.00 25.00 500.00 Desired Span 23.84 10.00 500.00 Low Range Gas Low NA NA 125.00 High NA NA 175.00 Mid Range Gas Low 9.54 4.00 225.00 High 14.30 6.00 275.00 High Range Gas Low NA NA 400.00 High NA NA 450.00 Actual Concentration (% or ppm) Zero 0.00 0.00 0.00 Low NA NA 150.00 Mid 12.00 5.00 250.00 High 23.84 10.00 400.00 Response Time (seconds)47.00 47.00 60.00 Upscale Calibration Gas (CMA)Mid Mid Mid Instrument Response (% or ppm) Zero 0.00 0.00 0.15 Low NA NA 149.33 Mid 12.06 5.07 249.04 High 23.85 9.99 401.19 Performance (% of Span or Cal. Gas Conc.) Zero 0.00 0.00 0.00 Low NA NA -0.81 Mid 0.25 0.70 -0.70 High 0.04 0.10 0.00 Status Zero PASS PASS PASS Low NA NA PASS Mid PASS PASS PASS High PASS PASS PASS Process Line No. 11 Pepperidge Farm Incorporated - Richmond, UT Parameter 10/24/24 AST-2024-4537 77 of 91 Bias/Drift Determinations Location: Source: Project No.: O₂ - Outlet CO₂ - Outlet NMHC - Outlet Pretest System Zero Response 0.00 0.00 3.21 Posttest System Zero Response 0.02 0.05 3.74 Pretest System Upscale Response 12.05 5.10 251.57 Posttest System Upscale Response 12.02 5.09 251.59 Pretest System Zero Response 0.02 0.05 3.74 Posttest System Zero Response 0.00 0.07 3.68 Pretest System Upscale Response 12.02 5.09 251.59 Posttest System Upscale Response 11.96 5.11 250.12 Pretest System Zero Response 0.00 0.07 3.68 Posttest System Zero Response 0.00 0.07 3.23 Pretest System Upscale Response 11.96 5.11 250.12 Posttest System Upscale Response 11.93 5.13 253.16 Run 2 Pepperidge Farm Incorporated - Richmond, UT Process Line No. 11 AST-2024-4537 Parameter Run 1 Run 3 78 of 91 Bias/Drift Determinations Location: Source: Project No.: O₂ - Outlet CO₂ - Outlet NMHC - Outlet Run 1 Date 10/24/24 Span Value 23.84 10.00 500.00 Initial Instrument Zero Cal Response 0.00 0.00 0.15 Initial Instrument Upscale Cal Response 12.06 5.07 249.04 Pretest System Zero Response 0.00 0.00 3.21 Posttest System Zero Response 0.02 0.05 3.74 Pretest System Upscale Response 12.05 5.10 251.57 Posttest System Upscale Response 12.02 5.09 251.59 Bias (%) Pretest Zero 0.00 0.00 NA Posttest Zero 0.08 0.50 NA Pretest Span -0.04 0.30 NA Posttest Span -0.17 0.20 NA Drift (%) Zero 0.08 0.50 0.11 Mid -0.13 -0.10 0.00 Run 2 Date 10/24/24 Span Value 23.84 10.00 500.00 Instrument Zero Cal Response 0.00 0.00 0.15 Instrument Upscale Cal Response 12.06 5.07 249.04 Pretest System Zero Response 0.02 0.05 3.74 Posttest System Zero Response 0.00 0.07 3.68 Pretest System Upscale Response 12.02 5.09 251.59 Posttest System Upscale Response 11.96 5.11 250.12 Bias (%) Pretest Zero 0.08 0.50 NA Posttest Zero 0.00 0.70 NA Pretest Span -0.17 0.20 NA Posttest Span -0.42 0.40 NA Drift (%) Zero -0.08 0.20 -0.01 Mid -0.25 0.20 -0.29 Run 3 Date 10/24/24 Span Value 23.84 10.00 500.00 Instrument Zero Cal Response 0.00 0.00 0.15 Instrument Upscale Cal Response 12.06 5.07 249.04 Pretest System Zero Response 0.00 0.07 3.68 Posttest System Zero Response 0.00 0.07 3.23 Pretest System Upscale Response 11.96 5.11 250.12 Posttest System Upscale Response 11.93 5.13 253.16 Bias (%) Pretest Zero 0.00 0.70 NA Posttest Zero 0.00 0.70 NA Pretest Span -0.42 0.40 NA Posttest Span -0.55 0.60 NA Drift (%) Zero 0.00 0.00 -0.09 Mid -0.13 0.20 0.61 Parameter Pepperidge Farm Incorporated - Richmond, UT Process Line No. 11 AST-2024-4537 79 of 91 Balance Red Ball Technical Gas Service 555 Craig Kennedy Way Shreveport, LA 71107 800-551-8150 Accreditation #62754 PGVP Vendor ID # G12024 EPA PROTOCOL GAS CERTIFICATE OF ANALYSIS Cylinder Number:EB0078022 Certification Date:07/08/2024 Product ID Number:127907 Expiration Date:07/06/2032 Cylinder Pressure:1900 PSIG MFG Facility: - Shreveport - LA COA #EB0078022.20240701-0 Lot Number:EB0078022.20240701 Customer PO. NO.:Tracking Number:084267623 Customer:Previous Certification Dates: This calibration standard has been certified per the May 2012 EPA Traceability Protocol, Document EPA-600/R-12/531, using procedure G2. Do Not Use This Cylinder Below 100 psig (0.7 Megapascal). Certified Concentration(s) Component Concentration Uncertainty Analytical Principle Assayed On Carbon Dioxide 24.0 %±0.14 %FTIR 07/08/2024 Oxygen 23.84 %±0.09 %MPA 07/08/2024 Nitrogen Analytical Measurement Data Available Online. Reference Standard(s) Serial Number Lot Expiration Type Balance Component Concentration Uncertainty(%)NIST Reference FF61042 71-F-31 02/27/2026 SRM N2 O2 20.753 %0.101 SRM 2659a CC738420 CC738420.20230109 07/09/2031 GMIS N2 O2 12.003 %0.122 SRM 2659a EB0022009 EB0022009.20201022 04/05/2030 GMIS N2 CO2 24.76 %0.237 C1847810.03 Analytical Instrumentation SMART-CERT Component Principle Make MPC Date CO2 FTIR MKS 07/08/2024 O2 MPA Thermo 06/27/2024 Serial 017146467 1162980025 This is to certify the gases referenced have been calibrated/tested, and verified to meet the defined specifications. This calibration/test was performed using Gases or Scales that are traceable through National Institute of Standards and Technology (NIST) to the International System of Units (SI). The basis of compliance stated is a comparison of the measurement parameters to the specified or required calibration/testing process. The expanded uncertainties use a coverage factor of k=2 to approximate the 95% confidence level of the measurement, unless otherwise noted. This calibration certificate applies only to the item described and shall not be reproduced other than in full, without written approval from Red Ball Technical Gas Services. If not included, the uncertainty of calibrations are available upon request and were taken into account when determining pass or fail. Hayden Hartley Analyst Assay Laboratory: Red Ball TGS Version 02-J, Revised on 2018-09-17 Model MKS 2031DJG2EKVS13T 410i 80 of 91 Balance Red Ball Technical Gas Service 555 Craig Kennedy Way Shreveport, LA 71107 800-551-8150 Accreditation #62754 PGVP Vendor ID # G12024 EPA PROTOCOL GAS CERTIFICATE OF ANALYSIS Cylinder Number:CC718971 Certification Date:04/11/2024 Product ID Number:125058 Expiration Date:04/09/2032 Cylinder Pressure:1900 PSIG MFG Facility: - Shreveport - LA COA #CC718971.20240324-0 Lot Number:CC718971.20240324 Customer PO. NO.:Tracking Number:098504035 Customer:Previous Certification Dates: This calibration standard has been certified per the May 2012 EPA Traceability Protocol, Document EPA-600/R-12/531, using procedure G1. Do Not Use This Cylinder Below 100 psig (0.7 Megapascal). Certified Concentration(s) Component Concentration Uncertainty Analytical Principle Assayed On Propane 502 PPM ±3 PPM FTIR 04/11/2024 Air Analytical Measurement Data Available Online. Reference Standard(s) Serial Number Lot Expiration Type Balance Component Concentration Uncertainty(%)NIST Reference EB0055482 EB0055482.20160107 05/17/2024 GMIS N2 C3H8 750 PPM 0.635 2647A Analytical Instrumentation SMART-CERT Component Principle Make MPC Date C3H8 FTIR MKS 04/11/2024 Serial 017146467 This is to certify the gases referenced have been calibrated/tested, and verified to meet the defined specifications. This calibration/test was performed using Gases or Scales that are traceable through National Institute of Standards and Technology (NIST) to the International System of Units (SI). The basis of compliance stated is a comparison of the measurement parameters to the specified or required calibration/testing process. The expanded uncertainties use a coverage factor of k=2 to approximate the 95% confidence level of the measurement, unless otherwise noted. This calibration certificate applies only to the item described and shall not be reproduced other than in full, without written approval from Red Ball Technical Gas Services. If not included, the uncertainty of calibrations are available upon request and were taken into account when determining pass or fail. Gabriel Ouma Analytical Chemist Assay Laboratory: Red Ball TGS Version 02-J, Revised on 2018-09-17 Model MKS 2031DJG2EKVS13T 81 of 91 Location: Source: Project No.: Date EPA O2 SERVOMEX 4900 0410403-2409 100.0 Cylinder Number ID Zero NA Mid EB0042240 High EB0078022 Cylinder Certified Values Zero 0.0 Mid 10.99 High 23.84 Instrument Response (% or ppm) Zero 0.0 Mid 10.9 High 23.9 Calibration Gas Selection (% of Span) Mid 11.0 High 23.8 Calibration Error Performance (% of Span) Zero 0.0 Mid -0.1 High 0.0 Linearity (% of Range) -0.1 (%) lpm (%) (%) (%) (%) (%) (%) (%)( ± 2 %) 10L/5L 80.0 5.0 19.1 19.1 19.2 19.2 19.2 19.19 0.09 0.5% 10L/5L 50.0 5.0 11.9 11.9 12.0 12.0 12.0 11.97 0.07 0.6% 10L/1L 20.0 4.0 4.8 4.8 4.8 4.9 4.9 4.85 0.05 1.1% 10L/1L 10.0 4.0 2.4 2.4 2.4 2.4 2.4 2.43 0.03 1.4% (%)( ± 2 %)( ± 2 %)( ± 2 %) 19.19 -0.1% 0.0% 0.1% 11.97 0.1% -0.2% 0.1% 4.85 -0.3% -0.1% 0.3% 2.43 -0.5% 0.3% 0.3% Mid-Level Supply Gas Calibration Direct to Analyzer Calibration Injection 1 Injection 2 Injection 3 Average Gas Analyzer Analyzer Analyzer Analyzer Concentration Concentration Concentration Concentration Concentration (%) (%) (%) (%) (%) (%)( ± 2 %) 10.99 11.0 11.0 11.0 10.98 -0.01 -0.1% Average Analyzer Concentration Injection 1 Error Injection 2 Error Injection 3 Error Difference Average Error *Not all AST Environics Units have 2-10L Mass Flow Controllers. For these units the 90% @ 7lpm and 80% @ 7lpm injections will not be conducted. Cylinder Gas ID (Mid-Level): EB0042240 Cylinder Gas Concentration (Mid-Level), %: 10.99 Target Mass Flow Contollers Target Dilution Target Flow Rate Target Concentration Actual Concentration Injection 1 Analyzer Concentration Injection 2 Analyzer Concentration Injection 3 Analyzer Concentration Average Analyzer Concentration Difference Average Error Component/Balance Gas: O2/N2 Cylinder Gas ID (Dilution): EB0078022 Cylinder Gas Concentration (Dilution), %: 23.84 Analyzer Model: 4900 Analyzer SN: 0410403-2409 Environics ID: 8027 Analyzer Make: SERVOMEX Pepperidge Farm Incorporated - Richmond, UT Process Line No. 11 AST-2024-4537 10/22/24 Parameter Make Model S/N Span Method Criteria 82 of 91 Dilution System Make: Dilution System Model: Dilution System S/N: Calibration Equipment Make: Calibration Equipment Model: Calibration Equipment S/N: Flow Cell S/N: Flow Cell S/N: Calibration Gas: Barometric Pressure, mmHg: Ambient Temperature, °F: Mass Flow Controller ID Size, ccm: Make: Model: S/N: Set Flow True Flow Difference Set Flow True Flow Difference Set Flow True Flow Difference cc/min cc/min cc/min cc/min cc/min cc/min 5%500 505 1.0%500 498 0.4%50 49.4 1.2% 10%1,000 1,019 1.9%1,000 1,012 1.2%100 100.2 0.2% 20%2,000 2,043 2.2%2,000 2,033 1.7%200 202.6 1.3% 30%3,000 3,060 2.0%3,000 3,051 1.7%300 305.0 1.7% 40%4,000 4,082 2.1%4,000 4,069 1.7%400 406.2 1.6% 50%5,000 5,098 2.0%5,000 5,088 1.8%500 506.9 1.4% 60%6,000 6,116 1.9%6,000 6,099 1.7%600 608.5 1.4% 70%7,000 7,136 1.9%7,000 7,123 1.8%700 710.5 1.5% 80%8,000 8,155 1.9%8,000 8,152 1.9%800 813.0 1.6% 90%9,000 9,184 2.0%9,000 9,179 2.0%900 916.5 1.8% 100%10,000 10,215 2.2%10,000 10,201 2.0%1,000 1,020.8 2.1% Date EFC202 EFC202 70 Environics 8027 #1 10,000 Hastings 4040 Alicat Scientific 272121/272120 272121 272120 Nitrogen 25.8 Calibration Performed By TCH 2/23/24 455242007 Mass Flow Controller Calibration Note: The mass flow controller's calibration values are used by the dilution system's operating software to improve accuracy. These calibrations are not necessarily indicative of the systems overall performance. Performance is verified by conducting a Method 205 prior to each field use. M-10SLPD/5MM-D/5M, M-1SLPM-D/5M EFC202 10,000 # 2 # 3 Hastings 455242008 1,000 Hastings 455238004 83 of 91 Balance Red Ball Technical Gas Service 555 Craig Kennedy Way Shreveport, LA 71107 800-551-8150 Accreditation #62754 PGVP Vendor ID # G12023 EPA PROTOCOL GAS CERTIFICATE OF ANALYSIS Cylinder Number:EB0042240 Certification Date:12/29/2023 Product ID Number:125371 Expiration Date:12/27/2031 Cylinder Pressure:1900 PSIG MFG Facility: - Shreveport - LA COA #EB0042240.20231220-0 Lot Number:EB0042240.20231220 Customer PO. NO.:Tracking Number:065126635 Customer:Previous Certification Dates: This calibration standard has been certified per the May 2012 EPA Traceability Protocol, Document EPA-600/R-12/531, using procedure G1. Do Not Use This Cylinder Below 100 psig (0.7 Megapascal). Certified Concentration(s) Component Concentration Uncertainty Analytical Principle Assayed On Carbon Dioxide 10.97 %±0.09 %NDIR 12/29/2023 Oxygen 10.99 %±0.03 %MPA 12/27/2023 Nitrogen Analytical Measurement Data Available Online. Reference Standard(s) Serial Number Lot Expiration Type Balance Component Concentration Uncertainty(%)NIST Reference CC716408 CC716408.20230109 07/09/2031 GMIS N2 O2 12.003 %0.122 SRM 2659a CC749145 CC749145.20230108 07/09/2031 GMIS N2 O2 20.03 %0.112 SRM 2659a EB0004315 EB0004315.20201022 04/05/2030 GMIS N2 CO2 24.75 %0.237 C2190301.03 EB0014830 EB0014830.20150605 10/03/2030 GMIS N2 CO2 9.53 %0.191 C2190301.03 Analytical Instrumentation SMART-CERT Component Principle Make MPC Date O2 MPA Thermo 12/18/2023 CO2 NDIR Thermo 12/14/2023 Serial 1162980025 1162980025 This is to certify the gases referenced have been calibrated/tested, and verified to meet the defined specifications. This calibration/test was performed using Gases or Scales that are traceable through National Institute of Standards and Technology (NIST) to the International System of Units (SI). The basis of compliance stated is a comparison of the measurement parameters to the specified or required calibration/testing process. The expanded uncertainties use a coverage factor of k=2 to approximate the 95% confidence level of the measurement, unless otherwise noted. This calibration certificate applies only to the item described and shall not be reproduced other than in full, without written approval from Red Ball Technical Gas Services. If not included, the uncertainty of calibrations are available upon request and were taken into account when determining pass or fail. Hayden Hartley Analyst Assay Laboratory: Red Ball TGS Version 02-J, Revised on 2018-09-17 Model 410i 410i 84 of 91 QA Data Location Source Project No. Parameter(s) Date Pitot ID Evidence of damage? Evidence of mis-alignment? Calibration or Repair required? 10/23/24 PR-704-1 no no no Date Probe or Thermocouple ID Reference Temp. (°F) Indicated Temp. (°F)Difference Criteria 10/23/24 PR-704-1 250.0 250.0 0.0% Date 10/24/24 Balance ID:5A2882051 Certified Weight ID:1KG-SLC-1 Certified Weight (g):1000.0 Measured Weight (g):999.9 Weight Difference (g):0.1-------- Date Barometric Pressure Evidence of damage?Reading Verified Calibration or Repair required? 10/23/24 Weather Station NA NA NA 10/23/24 M5-14 Reagent Lot#Field Prep performed Field Lot Date By DI Water 233598 Pepperidge Farm Incorporated - Richmond, UT Process Line No. 11 AST-2024-4537 VFR ± 1.5 % (absolute) Field Balance Check Pass Weather Station Location Logan, UT Date Meter Box ID Positive Pressure Leak Check 85 of 91 Document ID 620.004 Revision 24.0 Effective Date 1/31/24 Issuing Department Page 1 of 1 Console ID: Meter S/N: Critical Orifice S/N: (PbI) (PbF) (Pb) (Y)SH-73 SH-73 SH-63 SH-63 SH-55 SH-55 (K')0.7864 0.7864 0.6007 0.601 0.4524 0.452 (VP)12.0 12.0 16.5 16.5 17.5 17.5 Initial DGM Volume, ft3 (VmI)551.000 577.300 603.900 623.900 659.200 674.900 Final DGM Volume, ft3 (VmF)576.358 602.720 623.468 643.491 673.919 689.615 Total DGM Volume, ft3 (Vm)25.358 25.420 19.568 19.591 14.719 14.715 Ambient Temperature, °F (Ta)68 72 73 74 75 76 Initial DGM Temperature, °F (TmI)68 72 73 74 75 76 Final DGM Temperature, °F (TmF)69 73 74 75 76 76 Average DGM Temperature, °F ( Tm)69 73 74 75 76 76 Elapsed Time (Θ)25.00 25.00 25.00 25.00 25.00 25.00 Meter Orifice Pressure, in. WC (ΔH)2.70 2.70 1.60 1.60 0.85 0.85 Standard Meter volume, ft3 (Vmstd)21.8483 21.7371 16.6492 16.6376 12.4500 12.4350 Standard Critical Orifice Volume, ft3 (Vcr)21.9096 21.8270 16.6571 16.6415 12.5214 12.5097 Meter Correction Factor (Y)1.003 1.004 1.000 1.000 1.006 1.006 Tolerance --0.000 0.001 0.003 0.003 0.003 0.003 Orifice Calibration Value (ΔH @)1.704 1.704 1.725 1.725 1.612 1.614 Tolerance --0.023 0.023 0.044 0.044 0.068 0.067 Orifice Cal Check -- Meter Correction Factor (Y) Orifice Calibration Value (ΔH @) Accuracy Absolute Difference oF oR oF oR %oF 0 460 0 460 0.0 0 68 528 66 526 0.4 2 100 560 98 558 0.4 2 223 683 223 683 0.0 0 248 708 248 708 0.0 0 273 733 273 733 0.0 0 300 760 300 760 0.0 0 400 860 398 858 0.2 2 500 960 497 957 0.3 3 600 1,060 599 1,059 0.1 1 700 1,160 701 1,161 -0.1 1 800 1,260 800 1,260 0.0 0 900 1,360 900 1,360 0.0 0 1,000 1,460 1,000 1,460 0.0 0 1,100 1,560 1,101 1,561 -0.1 1 1,200 1,660 1,201 1,661 -0.1 1 Calibration Date: Shamit NakraReviewed By: Xander Gray KrahnCalibration By: 5/16/2024 Equipment Detail - Thermocouple Sensor Reference Temp.Display Temp. Practical Instrument Electronics 887216 Personnel Reference Calibrator Make: Reference Calibrator Model: Reference Calibrator S/N: Calibration Detail K' Factor, ft3·R1/2 / in. WC·min Piecal 520B Vacuum Pressure, in. Hg Initial Barometric Pressure, in. Hg Final Barometric Pressure, in. Hg Average Barometric Pressure, in. Hg Critifcal Orifice ID Calibration Detail M5-14 8219521 SH 40-73 Positive Pressure Leak Check Equipment Detail - Dry Gas Meter 1.003 1.681 Yes 0.31 0.55 0.55 DGM Calibration-Orifices Tech Services 25.60 25.60 25.60 86 of 91 Location Pepperidge Farm Incorporated - Richmond, UT Source Process Line No. 11 Project No.AST-2024-4537 Date 10/24/24 Analyzer CAI Model 300 HFID Serial Number -- Parameter Ethanol Certified Concentration, ppm 102.9 Analyzer Response 1, ppm 35.2 Analyzer Response 2, ppm 35.2 Analyzer Response 3, ppm 35.2 Average Response, ppm 35.20 Response Factor 0.34 87 of 91 Location: Source: Project No.: Date: Time O2 CO2 (%) (%) A-1 10:09 13.34 4.52 2 10:11 12.87 4.53 3 10:13 13.62 4.52 13.3 4.5 Single Point Single Point Pepperidge Farm Incorporated - Richmond, UT Process Line No. 11 AST-2024-4537 10/24/2024 Average Criteria Met Traverse Point 88 of 91 Appendix E 89 of 91 Time Production Status Production Rate (lbs/hr) Residence Time (minutes) Catalyst Inlet Temp (F) Catalyst Outlet Temp (F) Temp Rise Across Catalyst (F) 10:17 Running 2.7 715 816 101 10:32 Running 2.7 700 810 110 10:47 Running 2.7 698 815 117 11:02 Running 2.7 698 835 137 11:17 Running 2.7 697 807 110 11:55 Running 2.71 699 828 129 12:10 Running 2.71 696 828 132 12:25 Running 2.71 699 823 124 12:40 Running 2.73 700 826 126 12:55 Running 2.73 701 837 136 13:25 Running 2.75 702 836 134 13:40 Running 2.75 700 833 133 13:55 Running 2.75 699 831 132 14:10 Running 2.75 697 832 135 14:25 Running 2.75 699 830 131 14:58 Running 2.75 700 820 120 15:13 Running 2.75 698 830 132 15:28 Running 2.75 699 827 128 15:43 Running 2.75 700 830 130 15:58 Running 2.75 700 835 135 L11 Oxidizer Data - 10/24/2024 7554 7554 7488 7488 90 of 91 Last Page of Report 91 of 91