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DRC-2023-070746 - 0901a06881260681
State of Utah SPENCER J. COX Governor DEIDRE HENDERSON lieutenant Governor Department of Environmental Quality Kimberly D. Shelley Executive Director DIVISION OF WASTE MANAGEMENT AND RADIATION CONTROL Douglas J. Hansen Director MEMORANDUM TO: Phil Goble Pe C e,/4/.t) FROM: Dean Henderson 0?J4 6 /r3 / ,u. "1-7 DATE: June 13, 2023 SUBJECT: Review of the February 6, 2023 4th Quarter 2022 Nitrate Monitoring Report (DRC-2023- 001467) for the Nitrate Contamination Investigation, Energy Fuels Resources (USA) Inc. ("EFRI") White Mesa Uranium Mill, near Blanding, Utah The Utah Division of Waste Management and Radiation Control ("Division") has reviewed the EFRI February 6, 2023, 4th Quarter, 2022 White Mesa Uranium Mill Nitrate Monitoring Report ("Report") for the Nitrate Contamination Investigation. For the review of this Report the following regulatory enforcement documents were used: • Energy Fuels Resources (USA) Inc., White Mesa Uranium Mill, Groundwater Discharge Permit No. UGW370004, signed March 19, 2019 ("Permit"). • Corrective Action Plan for Nitrate White Mesa Uranium Mill near Blanding, Utah, May 7, 2012, ("CAP") approved December 12, 2012. • -The EFR Quality Assurance Plan ("QAP") February 15, 2022 (Revision. 7.7) REVIEW The CAP requires the 4th quarter Nitrate Monitoring Report for the Nitrate Contamination Investigation to be submitted to Division on or before March 1, of each year. The Report was received by the Division on February 14, 2023 (date of Report February 6, 2023) which meets the CAP requirement. Monitor Wells Sampled and Parameters Analyzed The following monitor wells were sampled and analyzed for inorganic chloride and nitrate + nitrite ( as N), and field data work sheets were filled out for each well as required in the CAP: DRC-20 195 North 1950 West• Salt Lake City, UT Mailing Address: P.O. Box 144880 • Salt Lake City, UT 84114-4880 Telephone (801) 536-0200 • Fax (801) 536-0222 • T.D.D. (801) 536-4284 www.deq.1ttah.gov Printed on I 00% recycled paper DRC-2023-070746 Page2 TWN-1, TWN-2, TWN-3, TWN-4, TWN-7, TWN-18, TNW-20, TWN-21, TW4-22 (pumping well), TW4-24 (pumping well), and TW4-25 (pumping well), and Piezometer 1, Piezometer 2, and Piezometer 3A. Groundwater Head Monitoring For the 4th Quarter, 2022 depth to groundwater was measured in the following wells and/or piezometers as required in Part I.E.3 of the Permit: • The quarterly groundwater compliance monitoring wells. • Existing monitoring well MW-4 and all of the temporary chloroform investigation wells. • Piezometers P-1, P-2, P-3A, P-4 and P-5. • MW-20, MW-22 and MW-34 • Nitrate monitoring wells. • The DR piezometers which were installed during the Southwest Hydrologic Investigation. In addition to the above, depth to water measurements are routinely observed in conjunction with sampling events for all wells sampled during quarterly and accelerated efforts, regardless of the sampling purpose. All well levels used for groundwater contour mapping were measured and recorded within 5 calendar days of each other. The monitoring wells were purged using the three approved QAP well purging strategies and meet QAP requirements for each strategy: I. Purging two casing volumes with stable field parameters for specific conductivity, turbidity, pH, redox potential, and water temperature (within 10% RPD): Wells: TWN-1, TWN-4, and TWN-18. 2. Purging a well to dryness and stability of field parameters for pH, specific conductivity, and water temperature only after recovery: Wells: TWN-3, TWN-7, TWN-20, and TWN-21 3. Continuously Pumped Wells that are considered sufficiently evacuated to immediately collect a sample: Wells: TWN-2, TW4-22, TW4-24, and TW4-25. Detection Limits All sample sets were measured and reported to the required QAP reporting limits. Page 3 Sample Duplicates One duplicate sample was collected at TWN-20 and identified as TWN-65. The duplicate sample analytical results for this sample/duplicate pair QA/QC were within the 20% acceptance limits as required in the QAP except for nitrate (see Table 2 below). Holding Times The method holding times for each parameter for samples collected at each monitor well were received and analyzed within the required holding times in the QAP. Receipt Temperature All samples were received within the required QAP temperature limit of 6° C. Analytical Methods Chloride and nitrate+ nitrite (as N) were analyzed for methods consistent with the requirements of the QAP. Estimation of Pumped Nitrate Mass Removal An estimated 64 lbs. of nitrate were removed from the chloroform pumping wells (MW-4, MW-26, TW4-1, TW4-2, TW4-4, TW4-11, TW4-19, TW4-37, TW4-39 and TW4-41) and the nitrate pumping wells (TWN-2, TW4-22, TW4-24, and TW4-25). Of the 64 lbs. removed, approximately 38 lbs. was removed by the nitrate pumping wells. In the attached Table 3, the Division shows calculations that verify these reported estimates. Reporting The Report included the following information as required in the CAP: a) Introduction b) Sampling and Monitoring Plan: i. Description of monitor wells sampled; ii. Description of sampling methodology, equipment and decontamination procedures; iii. Identification of all quality assurance samples, e.g. equipment blanks duplicate samples, etc. c) Data Interpretation: 1. Interpretation of groundwater levels, gradients, and flow directions. The interpretation will include a discussion on: 1) current site groundwater contour map, 2) hydrographs to show groundwater elevation in each monitor well over time, 3) depth to groundwater measured and groundwater elevation from each monitor well summarized in data table that includes historic groundwater level data for each well, 4) calculations documenting quarterly nitrate mass removed by pumping; n. Interpretation of all analytical results for each well including a discussion on: 1) a current nitrate isoconcentration map, 2) graphs showing nitrate concentration trends in each well through time and, analytical results for each well summarized in data table that includes historic analytical results for each well; and Page4 iii. An electronic copy of all laboratory results for groundwater quality monitoring conducted during the quarter will be provided to the Executive Secretary. d) Conclusions and Recommendations e) Copies of EFR field reports, laboratory reports, and chain of custody forms. Evaluation of the Nitrate Contaminate Plume and Its Associated Contaminants The groundwater monitoring data appeared to show that the nitrate contaminate plume ("Plume") is bound by up gradient, cross gradient, and down gradient wells that have nitrate concentrations below the Utah 10 mg/L GWQS. Based on water level data, groundwater contour, and capture zone maps in the it appears that up-gradient of pumping wells TW4-19, TW4-22, TW4-24, TW4-37, and TW4-39 the nitrate plume appears to being captured. Conclusions on Compliance with the CAP, QAP Per the Division review it appears that the 4th Quarter, 2022 Nitrate Monitoring Report for the Nitrate Contamination Investigation, Energy Fuels Resources (USA) Inc. complies with the CAP and QAP. Therefore, a letter will be drafted notifying EFRI of the review and closing out of this Report. Page 5 References Energy Fuels Resources (USA) Inc., White Mesa Uranium Mill, Groundwater Discharge Permit No. UGW370004, signed March 19, 2019. Energy Fuels Resources (USA) Inc., June 5, 2019, White Mesa Uranium Mill, Ground Water Monitoring Quality Assurance Plan (Revision 7. 7). Energy Fuels Resources (USA) Inc., White Mesa Uranium Mill 3rd Quarter, 2022 Nitrate Monitoring Report, November 15, 2022. HYDRO GEO CHEM, INC, May 7, 2012, Corrective Action Plan for Nitrate White Mesa Uranium Mill near Blanding, Utah. Table 1 of 16 Historic Nitrate, Nitrate+ Nitrite and Cloride Concentrations in Monitor Wells Up to the 4th Quarter 2022 Nitrate Contamination Investigation White Mesa Uranium Mill TWN-1 Parameter TWN-2 (Pumping well starting in January2013) Sampling Event GWQS Sampling Event Nitrate, Nitrate + Nitrite Chloride (mg/I) (10 mg/L) NoGWQS lstQtr 3/17/2010 0.50 17 1st Qtr 3/24/2010 2nd Qtr 5/26/2010 0.6 20 2nd Qtr 6/2/2010 3rd Qtr 9/27/2010 0.6 19 3rd Qtr 9/29/2010 4th Qtr 12/7/2010 0.6 14 4th Qtr 12/9/2010 lstQtr 1/26/2011 0.5 17 1st Qtr 2/1/2011 2nd Qtr 4/20/2011 0.5 19 2nd Qtr 4/28/2011 3rd Qtr 7/26/2011 0.5 14 3rd Qtr 7/28/2011 4thQtr 10/17/2011 0.5 10 4th Qtr 10/20/2011 lstQtr 1/9/2012 0.6 15 1st Qtr 1/12/2012 2nd Qtr 4/18/2012 0.6 17 2nd Qtr 4/20/2012 3;;ia_;---------------------------------7/31/2012 7/24/2012 0.6 17 3rd Qtr 4thQtr 10/17/2012 0.43 17.5 4thQtr 7/17/2012 l~Qt7°---------------------------------2/19/2013 2/18/2013 0.68 17.6 1st Qtr 2nd Qtr 4/23/2013 0.84 17.4 2nd Qtr 4/24/2013 3rd Qtr 8/27/2013 1.24 24.1 3rd Qtr 8/27/2013 4thQtr 10/16/2013 1.61 26.8 4thQtr 7/16/2013 TWN-65 duplicat of TWN-1 1.48 27.1 DRC split ofTWN-2 DRC split ofTWN-1 1.6 30 DRC duplicate of TWN-1 0.22 30 1st Qtr I 1/14/2014 1.47 29.2 1st Qtr 1/13/2014 2nd Qtr 5/6/2014 1.63 31.1 2nd Qtr 5/7/2014 3rd Qtr 8/5/2014 1.7 28 3rd Qtr 8/6/2014 TWN-65 duplicate ofTWN-1 1.4 28 14th Qtr I 10/8/2014 1.46 27.6 4thQtr 10/8/2014 lstQtr I 2/18/2015 1.37 27.8 1st Qtr 2/18/2015 TWN-65 dup ofTWN-1 1.41 29.0 2nd Qtr 5/13/2015 0.65 29.2 2nd Qtr 5/12/2015 3rdQtr 8/25/2015 0.624 33.2 3rd Qtr 8/25/2015 14th Qtr 10/13/2015 1.35 27.7 4th Qtr 10/14/2015 lstQtr 2/23/2016 1.51 30.3 1st Qtr 2/23/2016 2nd Qtr 5/17/2016 1.73 32.1 2nd Qtr 5/17/2016 3rdQtr 7/20/2016 1.76 29.6 3rd Qtr 7/20/2016 4th Qtr 10/6/2016 1.98 33 4th Qtr 10/1_1/2016 lstQtr 2/15/2017 2.06 31.2 1st Qtr 2/15/2017 TWN-65 duplicate ofTWN-1 1.98 31.5 2nd Qtr I 6/1/2017 1.89 32.7 2nd Qtr I 6/1/20171 TWN-65 duplicate ofTWN-1 1.88 31.5 3rd Qtr I 7/19/2017 2.07 31.2 3rd Qtr I 7/19/20171 TWN-65 duplicate of TWN-1 1.89 31.4 4th Qtr I 10/4/2017 1.95 30.8 4th Qtr I 10/4/20171 WN-65 duplicate of TWN-1 1.99 32.0 stQtr 1/18/2018 1.86 30.4 1st Qtr 1/19/2018 2nd Qtr 5/8/2018 1.89 28.4 2nd Qtr 5/9/2018 3rd Qtr 8/8/2018 1.97 34.2 3rd Qtr 8/8/2018 4th Qtr 11/20/2018 1.98 28.9 4th Qtr 11/20/2018 st Qtr 2/20/2019 2.1 31.4 1st Qtr 2/20/2019 ndQtr 5/29/2019 1.93 32.6 2nd Qtr 5/29/2019 :rdQtr 8/14/2019 2.15 30.3 3rd Qtr 8/14/2019 -th Qtr 10/16/2019 2.35 32.0 4th Qtr 10/16/2019 ~WMRr split ofTWN-1 2.1 31.0 DWMRC split ofTWN-2 1st Qtr 1/29/2020 2.24 33.8 1st Qtr 1/29/2020 2nd Qtr 5/20/2020 2.24 33.0 2nd Qtr 5/20/2020 3rd Qtr 7/15/2020 2.36 30.8 3rd Qtr 7/15/2020 thQtr 11/12/2020 1.89 29.2 4th Qtr 11/12/2020 st Qtr 2/17/2021 2.53 34.1 1st Qtr 2/18/2021 ndQtr 5/25/2021 3.18 34.7 2nd Qtr 5/25/2021 lrdQtr 8/18/2021 2.47 35.7 3rd Qtr 8/18/2021 thQtr 11/23/2021 1.91 37.4 4thQtr 11/23/2021 st Qtr 2/15/2022 3.01 35.6 1st Qtr 2/15/2022 ndQtr 5/24/2022 2.1 33.7 2nd Qtr 5/24/2022 rd Qtr 8/17/2022 2.94 36.7 3rd Qtr 8/17/2022 thQtr 10/25/2022 2.75 30.1 4thQtr 10/25/2022 Shaded = Nitrate, Nitrate + Nitrite concentrations greater than the Ground Water Quality Standard of 10 mg/I DRC = Utah Division or Radiation Control. DWMRC = Utah Division of Waste Management and Radiation Control Nitrate Pumping System Started in January 2013 As of March 2012 both north and south wild life ponds no longer receiving water. Parameter GWQS Nitrate, Nitrate + Nitrite (10 mg/L) 62 69 69 48 43 40 33 33 31 48 ------------54 22.1 ------------57.3 57.7 80.0 111 200 42.6 44.7 42 71 48.6 52.8 49.7 45 86.3 45.4 35.3 32.6 27.4 25.ol 2391 31.91 19.6 19.8 18.6 19.6 19.0 45.1 23.2 18.2 16.0 16.5 16.1 17.2 12 15.4 13.8 15.3 12.7 15.3 14.0 13.9 14.0 Chloride (mg/I) NoGWQS 85 97 104 93 93 85 74 76 86 103 -------93 79 -------80.5 82.1 75.9 70.4 75 72.4 84.9 80 81 87.8 83.6 87.8 74.9 73.9 74.5 68.8 69.8 65.8 61.5 64.2 60.5 57.1 62.3 61.5 56 50.7 102 50.7 53 52 66.1 59.6 55.6 53.5 61.8 61.5 58.9 62.3 59.5 60.2 61.8 48.9 Table 2 of 16 Historic Nitrate, Nitrate+ Nitrite and Cloride Concentrations in Monitor Wells Up to the 4th Quarter 2022 Nitrate Contamination Investigation White Mesa Uranium Mill IWN•3 Parameter TWN-4 Sampling Event GWQS Sampling Event Nitrate, Nitrate + Nitrite Chloride (mg/I) (10 mg/L) NoGWQ5 l stQtr 3/25/2010 25.3 111 1st Qtr 3/16/2010 2nd Qtr 6/3/2010 26 118 2nd Qtr 5/27/2010 3rd Qtr 7/16/2010 27 106 3rd Qtr 9/27/2010 4th Qtr 12/10/2010 24 117 4thQtr 12/8/2010 1st Qtr 2/1/2011 24 138 1st Qtr 1/25/2011 2nd Qtr 4/28/2011 26 128 2nd Qtr 4/20/2011 3rd Qtr 7/29/2011 25 134 3rd Qtr 7/26/2011 4th Qtr 10/20/2011 25 129 4thQtr 10/18/2011 lstQtr 1/12/2012 25 143 1st Qtr 1/9/2012 2nd Qtr 4/20/2012 24 152 2nd Qtr _4Lt'2f~g ------------------L-------------TWN-65 duplicate ofTWN-4 3rd Qtr 7/31/2012 27 158 3rd Qtr I 7/25/2012 TWN-65 duplicate oflWN-4 4!!'.9-~-10/17/2012 12.1 149 4th Qtr -t 7/15/2012 --------------------------1st Qtr 2/19/2013 22.2 157 1st Qtr 2/18/2013 TWN-65 duplicate ofTWN-4 2nd Qtr 4/24/2013 27.2 158 2nd Qtr I 4/23/2013 3rd Qtr 8/28/2013 20.9 171 3rdQtr 8/27/2013 TWN-65 duplicate ofTWN-4 4th Qtr 10/17/2013 23.5 163 4th Qtr I 7/16/2013 TWN-65 duplicate of TWN-4 lstQtr 1/15/2014 19.6 160 lstQtr 1111412014 TWN-65 duplicate of TWN-4 2nd Qtr 5/7/2014 23.6 168 2nd Qtr I 5/612014 TWN-65 duplicate of TWN-4 3rdQtr 8/6/2014 19.5 174 3rdQtr 8/5/2014 4th Qtr 10{~/2014 19.1 153 4th Qtr 10/8/2014 lstQtr 2/19/2015 19.4 164 lstQtr 2/18/2015 2nd Qtr 5/14/2015 17.2 141 2nd Qtr 5/13/2015 3rdQtr 8/26/2015 16.2 156 3rd Qtr 8/25/2015 TWN-65 duplicate of TWN-4 4th Qtr 10/14/2015 16.3 129 4th Qtr I 10/13/2015 TWN-65 duplicate of TWN-4 ------------------------------------------1st Qtr 2/24/2016 16.8 128 lstQtr 2/23/2016 2nd Qtr 5/18/2016 13.5 116 2nd Qtr 5/17/2016 3rdQtr 7/20/2016 16.8 110 3rd Qtr 7/20/2016 4th Qtr 10/7/2016 15.8 113 4thQtr 10/6/2016 1st Qtr 2/16/2017 17.4 113 1st Qtr 2/15/2017 2ndQtr 6/2/2017 15.9 108 2nd Qtr 6/1/2017 3rd Qtr 7/20/2017 15.9 106 3rd Qtr 7/19/2017 4th Qtr 10/4/2017 15.6 111 4thQtr 10/4/2017 lstQtr 1/19/2018 14.4 107 1st Qtr 1/18/2018 2nd Qtr 5/9/2018 16.4 115 2nd Qtr 5/9/2018 3rd Qtr 8/9/2018 19.4 149 3rd Qtr 8/8/2018 TWN-65 duplicate of TWN-4 4th Qtr 11/21/20181 20.11 123 4thQtr I 1112012018 TWN-65 duplicate ofTWN-4 lstQtr 2/21/2019 20.7 140 1st Qtr 2/20/2019 2nd Qtr 5/30/2019 18.7 137 2nd Qtr 5/29/2019 3rd Qtr 8/15/2019 19.8 133 3rd Qtr 8/14/2019 4th Qtr 10/17/2019 19.6 126 4thQtr 10/16/2019 DWMRC split ofTWN-3 17.0 130 TWN-65 duplicate ofTWN-4 OWMRC split ofTWN-4 TW4-40 OWMRC duplicate of TWN 4 1st Qtr I 1/30/202~1 19~1 156 1st Qtr I 1/29/2020 2nd Qtr 5/21/2020 24 136 2nd Qtr 5/20/2020 TWN-65 duplicate ofTWN-4 3rd Qtr I 7/15/20201 22.21 130 3rd Qtr I 7/15/2020 TWN-65 duplicate ofTWN-4 4thQtr 11/13/2020 18 137 4th Qtr 11/12/2020 1st Qtr 2/18/2021 23.8 145 1st Qtr 2/17/2021 2nd Qtr 5/27/2021 25 156 2nd Qtr 5/25/2021 3rd Qtr 8/19/2021 24.3 146 3rd Qtr 8/18/2021 4th Qtr 11/24/2021 17.4 147 4th Qtr 11/23/2021 TWN-65 duplicate of TWN-4 lstQtr 2/16/2022 25.3 140 1st Qtr 2/16/2021 2ndQtr 5/25/2022 24 157 2nd Qtr 5/25/2022 3rd Qtr 8/18/2022 28.2 163 3rd Qtr 8/18/2022 4th Qtr 10/26/2022 26 156 4thQtr 10/25/2022 Shaded = Nitrate, Nitrate+ N1tnte concentrations greater than the Ground Water Quality Standard of 10 mg/I Nitrate Pumping System Started in January 2013 As of March 2012 both north and south wild life ponds no longer receiving water Parameter GWQS Nitrate, Nitrate+ Nitrite (10 mg/L) 0.9 1.0 0.9 1.0 0.9 0.9 1.1 0.9 0.9 1.1 ------------1.1 1.4 1.5 1.45 ------------1.5 1.5 1.63 1.6 1.57 1.69 0.22 1.41 1.33 1.55 1.54 2.0 1.44 1.48 0.733 0.974 1.160 1.58 .............................. 1.45 2.02 2.97 3.14 3.09 2.63 2.4 2.35 2.27 2.63 1.9 1.54 1.51 1.48 1.51 1.53 1.5 1.81 2.15 2.15 1.9 1.9 1.89 1.75 1.71 1.75 1.73 1.18 1.64 1.70 1.28 1.18 1.02 1.5 1.20 1.39 1.31 Chloride (mg/I) NoGWQ5 22 22 19 21 21 21 35 20 20 24 -------24 25 26 26.4 -------25.3 25.9 24.4 27.2 29.0 29.4 32 28.4 26.4 29.1 26.1 28 30.7 31.5 31.9 35.2 35.2 28.4 ..?.5_,6 30.7 31.7 28.0 31.3 31.2 28.6 28.0 27.4 31.2 27.7 28 27.6 22.7 23.2 25.3 26.5 23.7 25.4 24.7 26.0 26.0 27.2 25.1 25.4 23.1 23.1 22.8 24.2 23.2 23.7 23.2 23.2 22.7 20.9 21.6 21.2 TWN-5 Sampling Event Table3 of 16 Historic Nitrate, Nitrate + Nitrite and Cloride Concentrations in Monitor Wells Up to the 4th Quarter 2022 Nitrate Contamination Investigation Parameter GWQS Nitrate, Nitrate + Nitrite (10 mg/L) White Mesa Uranium Mill Chloride (mg/I) NoGWQS TWN-6 Sampling Event Parameter GWQS Nitrate, Nitrate + Nitrite (10 mg/L) Chloride (mg/I) No"GWQS 1st. (ltr .. 3/16/2010 ... 4.3. 1st Qtr 3/23/2010 19 2nd (ltr ........... s/ii,/i.oio .. .. . 0.3 44 2nd Qtr 6/1/2010 22 3rd Qtr 7 /iiiioio 0.3 43 3rd Qtr 7/13/2010 1.4 73 11_4_th_Q~t_r ___ 1_2~/7~)_2o_i_o+-·· ________ 0_.3-+-_____ 4 .... 5 4th Qtr 12/7/2010,__ _______ --, _____ 21_., 1st ().tr. 1/25/2011 0.4 .... 47 1st Qtr 1/26/2011 18 ?nd (ltr ·· ·· · ·· ·· ·· 4/20/20ii 0.3 .44 2nd Qtr 4/20/2011 1.5 22 3rd ().tr jji.i;ji.oii 0.3 44 3rd Qtr 7/27/2011 1.1 17 ll-'4-"th'-Q"'-t"-r_ .. _ .. _ .. _ .. cccio"-/...,.17~j_io~i_it-.. -------~-+------4-f5 4th Qtr 10/18/20111-----------t-----21'-II 1st (ltr . 1/9/2012 ........ 4.5 1st Qtr 1/10/2012 20 2nd ().tr ............ 4/1s/i.oii .. . . 39 2nd Qtr 4/18/2012 22 3rd (ltr 7/24hoii ..... 48 3rd Qtr 7/25/2012 22 4th Qtr ······· 10/is/_2~01_2+ .. <~0'-.1 _______ ~ ____ 4_3_.5-t-4_th~Q'-tr __ ~7/15/2012 20.4 1st ().tr 2013 NA .. . .. .. .. . .. .. .. .. .. 1st qtr 2013 NA IF2'-"n..;;.d..;;Q:;;tr ____ -'-'-'-'-'-----------------12nd(ltr2013 .. TWN-5 abandoned on July 31, 2013 .3rd qtrJ013 . 4th Qtr 2013 NA= Per the CAP and SCO, not sampled 1st (ltr 2014 .. 2nd Qtr 2014 3rd Qtr 2014 4th Qtr 2014 1st Qtr 2.01.5 . 2nd Qtr 2015 3rd Qtr 2015 4th Qtr 2015 .ls.t. (ltr 2016 .. 2nd Qtr 2016 3rd().tr .2.01.6 .... 4th Qtr 2016 1st Qtr 2.017 . . 2nd qtrJ017 3rd qtr 2017 4th Qtr 2017 1st (ltr 2018 .. 2nd(ltr .201.8. 3rd().tr 2018 4th Qtr 2018 1st Qtr 2()19 . 2~d Cltr 2019 .. .3.r.d qtr 2019 .. 4th Qtr 2019 .ls.t. (ltr 202() ... 2nd qtr 2020 . 3rd. qtr .2020 .. 4th Qtr 2020 1st Qtr 2()21 . . 2nd qtr 2021 .3r.d qtr 2.021 ... 4th Qtr 2021 1st Clt.r .. 202.2 .... 2nd(ltr2022 3rd Qtr 2022 ii iii oii ioff ·· NA NA NA NA NA NA NA NA NA TWN-7 Table 4 of 16 Historic Nitrate, Nitrate + Nitrite and Cloride Concentrations in Monitor Wells Up to the 4th Quarter 2022 Nitrate Contamination Investigation White Mesa Uranium Mill Parameter TWN-8 Parameter Sampling Event GWQS Sampling Event GWQS Nitrate, Nitrate + Nitrite Chloride (mg/I} Nitrate, Nitrate + Nitrite (10 mg/L) NoGWQS (10 mg/L) lstQtr 3/17/2010 0.8 6 1st Qtr 3/16/2010 <0.1 2nd Qtr 5/28/2010 1.2 6 2nd Qtr 5/26/2010 <0.1 3rd Qtr 7/14/2010 1.8 7 3rd Qtr 7/12/2010 <0.1 4thQtr 12/10/2010 1 4 4th Qtr 12/7/2010 <0.1 lstQtr 1/27/2011 1.3 6 1st Qtr 1/25/2011 <0.1 2nd Qtr 4/21/2011 1.7 6 2nd Qtr 4/19/2011 <0.1 3rd Qtr 7/29/2011 0.7 5 3rd Qtr 7/26/2011 <0.1 4th Qtr 10/19/2011 2.2 6 4th Qtr 10/17/2011 <0.1 lstQtr 1/11/2012 2.3 5 lstQtr 1/9/2012 <0.1 2nd Qtr 4/20/2012 1.2 6 2nd Qtr 4/18/2012 <0.1 ------------------~-------------7/24/2012 ------------3rd Qtr 7/26/2012 0.9 6 3rd Qtr <0.1 4thQtr 10/16/2012 0.64 5.67 4thQtr 10/15/2012 <0.1 Chloride (mg/I) NoGWQS 11 11 11 9 13 10 18 10 11 15 -------11 11.1 -2j19ji013 ------------~------------· ------------------------1st Qtr 0.59 5.68 1st Qtr 2013 NA 2nd Qtr 4/24/2013 1.16 5.88 2nd Qtr I 2013 NA 3rd Qtr 8/28/2013 0.835 6.96 TWN-8 abandoned on July 31, 2013 4th Qtr 10/16/2013 0.986 5.7 lstQtr 1/15/2014 0.882 5.75 2nd Qtr 5/7/2014 0.564 5.26 3rd Qtr 8/6/2014 0.9 6 4thQtr 10/9/2014 0.968 5.93 lstQtr 2/19/2015 1.04 5.58 2nd Qtr 5/14/2015 0.779 6.18 3rd Qtr 8/6/2015 0.348 6.12 4th Qtr _____ 10/14/20;~ 0.672 5.84 ----------------------------------------------------------lstQtr 2/24/2016 0.24 6.06 2nd Qtr 5/18/2016 0.732 6.26 3rd Qtr 7/21/2016 0.81 5.97 4th Qtr 10/7/2016 0.698 6.17 lstQtr 2/16/2017 1.63 14.0 2nd Qtr 6/2/2017 3.74 29.7 3rd Qtr 7/20/2017 2.7 29.0 4th Qtr 10/5/2017 3.58 41.4 1st Qtr 1/19/2018 5.82 69.4 2nd Qtr 5/9/2018 10.2 94.7 3rdQtr 8/9/2018 10.6 105 4th Qtr 11/21/2018 11.5 104 lstQtr 2/21/2019 12.9 107 2nd Qtr 5/30/2019 13.5 122 3rd Qtr 8/15/2019 12.9 120 4thQtr 10/17/2019 14.5 119 OWMRC split ofTWN-7 12.0 120 lstQtr 1/30/2020 14.2 128 2nd Qtr 5/21/2020 14.6 126 3rdQtr 7/16/2020 15.2 116 4th Qtr 11/13/2020 11.8 121 1st Qtr 2/18/2021 16.0 129 2nd Qtr 5/27/2021 16.4 129 3rd Qtr 8/19/2021 15.1 121 4thQtr 11/24/2021 7.66 130 1st Qtr 2/17/2022 16.9 120 2nd Qtr 5/25/2022 16.0 127 3rdQtr 8/18/2022 14.6 128 14th Qtr 10/26/2022 15.7 129 Shaded = Nitrate, Nitrate+ Nitrite concentrations greater than the Ground Water Quality Standard of 10 mg/l _J NA= Per the CAP and SCO, not sampled Nitrate Pumping System Started in January 2013 As of March 2012 both north and south wild life ponds no longer receiving water. Table 5 of 16 Historic Nitrate, Nitrate+ Nitrite and Cloride Concentrations in Monitor Wells Up to the 4th Quarter 2022 Nitrate Contamination Investigation White Mesa Uranium Mill TWN-9 Parameter TWN-10 Parameter Sampling Event GWQS Sampling Event GWQS Nitrate, Nitrate+ Nitrite Chloride (mg/I) Nitrate, Nitrate + Nitrite (10 mg/L) NoGWQS (10 mg/L) lstQtr 3/23/2010 7.6 183 1st Qtr 3/23/2010 1.5 2nd Qtr 6/1/2010 7.7 175 2nd Qtr 6/2/2010 1.0 3rd Qtr 7/15/2010 10.7 210 3rdQtr 7/14/2010 0.2 4th Qtr 12/9/2010 8.0 172 4th Qtr 12/8/2010 1.3 lstQtr 2/1/2011 9.5 217 lstQtr 1/26/2011 0.3 2nd Qtr 4/28/2011 10.0 192 2nd Qtr 4/21/2011 1.2 3rd Qtr 7/29/2011 11.0 208 3rdQtr 7/27/2011 0.1 4thQtr 10/20/2011 10.9 134 4th Qtr 10/18/2011 0.2 lstQtr 1/12/2012 12.2 202 lstQtr 1/10/2012 0.8 TW4-65 dup of TWN-10 0.7 2nd Qtr 4/20/2012 10.6 209 2nd Qtr I 4/19/2012 0.9 3rd Qtr 7/31/2012 12.3 215 3rd Qtr 7/25/2012 0.6 4thQtr 10/17/2012 12.5 194 4th Qtr 7/16/2012 0.12 1st Qtr 2013 NA 1st Qtr 2013 NA 2nd Qtr 2013 NA 2nd Qtr 2013 NA TWN-9 abandoned on July 31, 2013 TWN-10 abandoned on July 31, 2013 TWN-11 Parameter TWN-12 Parameter Sampling Event GWQS Sampling Event GWQS Nitrate, Nitrate + Nitrite Chloride (mg/I) Nitrate, Nitrate + Nitrite (10 mg/L) NoGWQS (10 mg/L) lstQtr 3/17/2010 1.4 73 1st Qtr 3/17/2010 0.7 2nd Qtr I 6/1/2010 1.3 72 2nd Qtr 5/26/2010 0.8 3rdQtr 9/27/2010 1.4 76 3rd Qtr 7/12/2010 0.7 4th Qtr 12/8/2010 1.4 72 4th Qtr 12/7/2010 0.7 lstQtr 1/27/2011 1.4 84 1st Qtr 1/26/2011 4.2 2nd Qtr I 4/26/2011 1.4 76 2nd Qtr 4/26/2011 1.0 3rd Qtr 7/27/2011 0.1 76 3rd Qtr 7/26/2011 0.6 4th Qtr 10/17/2011 1.6 76 4th Qtr 10/17/2011 1.2 1st Qtr 1/10/2012 1.6 69 1st Qtr 1/10/2012 0.9 ate of TWN-11 1.6 70 2nd Qtr I 4/19/2012 1.6 71 2nd Qtr 4/18/2012 1.2 3rd Qtr 7/25/2012 1.8 77 3rd Qtr 7/25/2012 1.4 4thQtr 10/16/2012 1.84 76.4 4th Qtr 7/16/2012 1.41 1st Qtr 2013 NA 1st Qtr 2013 NA 2nd Qtr 2013 NA 2nd Qtr 2013 NA TWN-11 abandoned on July 31, 2013 TWN-12 abandoned on July 31, 2013 Shaded = Nitrate, Nitrate+ Nitrite concentrations greater than the Ground Water Quality Standard of 10 mg/I NA= Per the CAP and SCO, not sampled Shaded = Nitrate, Nitrate+ Nitrite concentrations greater than the Ground Water Quality Standard of 10 mg/I Chloride (mg/I) NoGWQS 54 31 2 2: 4, 2: 2: 33 44 28 33 30.8 Chloride (mg/I) NoGWQS 113 106 112 103 87 109 102 87 104 106 102 101 TWN-13 Sampling Event Table& of 16 Historic Nitrate, Nitrate+ Nitrite and Cloride Concentrations in Monitor Wells Up to the 4th Quarter 2022 Nitrate Contamination Investigation Parameter GWQS Nitrate, Nitrate + Nitrite (10 mg/L) White Mesa Uranium Mill Chloride (mg/I) NoGWQS TWN-14 Sampling Event Parameter GWQS Nitrate, Nitrate + Nitrite (10 mg/L) Chloride (mg/I) NoGWQS 1st O.tr . .. .. . }/17/2010 <0,1 . .. .. .. .. .. .. .. 47. 1st O.tr 3/24/2010 .. . .. .. .. . .. . . . 2.9 24 2nd O.tr 5/26/2()10 .49 2nd O.tr 6/2(2010 2.9 30 3rd.Q.tr 9/27/2010 53 3rd O.tr 7f15/2010 3.5 26 4th Qtr . 12/j)-"20"-'i'-"o+--------"--t------....C5-'--71-'4-"th-'--QCOt'-r--+-"'12='-/-"10"'-/-"20"-'1'-"0+-------~-"-"t------....C2:=.j81 1st Qtr ........... 1/25/20.1_1 _ 1.6 28/2Clll 24 2nd.Q.tr 4/~~/291150,1 27/2011 30 3rd(ltr ... ]/26/201! . 0.1 29 2 4th Qtr 10/17/c.c2c.c0.ccllc+-<0"".""1 _______ +-----=1--'-""-""'--+.=,, 1st O.tr .. 1/9/2012 <0.1 2nd Qtr ..... 4/is/i.oii <Oj. 3rd O.tr . . . )A4/2oii 0.1 7 4th Qtr 1st O.tr 2nd Qtr TWN-13 abandoned on July 31, 2013 3 r_d Cltr_ . 2013 NA NA= Per the CAP and sea, not sampled 4th Qtr lstQtr 2nd O.tr 3rd O.tr ... 4th Qtr lstQ.tr. 2nd O.tr _3_r_d Cltr ... 4th Qtr lstqtr 2n.dCl,tr .. 3rd(:ltr .. 4th Qtr 1st Qtr. 2ndQtr ... . . 3r.d Cltr .. . 4th Qtr lstqtr. 2n.d_O.tr ..... 3rd(:ltr 4th Qtr lstCltr . 2nd Qtr. 3rdCltr ... 4th Qtr 1st (ltr 2nd O.tr .. 3rdQtr 4th Qtr lstO.tr .. 2nd(:ltr. 3rdqtr .... 4th Qtr 1st qtr 2n_d qtr . 3rd Qtr .iiiio.tr 2014 NA 2016,_N_A _____________ _,, 2016 NA TWN-15 Sampling Event Table7 of 16 Historic Nitrate, Nitrate+ Nitrite and Cloride Concentrations in Monitor Wells Up to the 4th Quarter 2022 Nitrate Contamination Investigation Parameter GWQS Nitrate, Nitrate + Nitrite (10 mg/L) White Mesa Uranium Mill Chloride (mg/I) NoGWQS TWN-16 Sampling Event Parameter GWQS Nitrate, Nitrate + Nitrite (10 mg/L) Chloride (mg/I) NoGWQS 1st Qtr 3/18/2010 ............. _g:z _ ............................. '.1.~. ~st ().tr . 3/17/2010 ..................................... 1.-? ........ ·····--35 2nd Qtr -sJi.S/2010 _ 1.0 3.~ 2nd qtr 5/27/2010 1.3 . . .................. 35 3rd(),tr .. 7/13/2010 36 3rd Qtr 9/27/2010 2.6 35 4th Qtr ......... iiJiihoio 38 4th Qtr 12/9/2010 30 1st (),tr 1/27/2011 1.4 43 1st qtr ..... . 1/27(2011 . 34 2".~ (ltr · ·· · "i,ii.i /iii ii · 1.6 49 2nd (ltr 4/27/2011 1.6 39 3r.d .Cl.tr.. . . . . iiistiiiii ... 7/27 hoii 31 4th Qtr .... iOl.!9:.c/::;20:..:i;.::;11-· ·--------=:+------=,l-'-"-'-='----!-'-1=0/18/~:2_0_11_,· ________ __,_ _____ 3_,4, ~~t Cl.tr. 1/11/2012 .. 1/10/2012 33 2nd Qtr .. 4/iojioii 1.6 4/19/2()12 . TW4-70 duplicate ofTWN-15 !~t ~; .··.· ,~i~~~ciii NA= Per the CAP and sea, not sampled 1.7 2.1 ............. s() 3r~qtr . 1/25f2oii 1.79 47 4th Qtr 7/16/2012 2.0 44.4 1st Qtr 2n.dO,tr 3rd (ltr ............. 20.15 NA 4th Qtr .1.st Qtr 2nd Qtr 3rd O,tr 4th Qtr 1st (),tr . 2n.d. (),tr ... 3rd (ltr 4th Qtr 1st Qtr .. 2n.d Qtr _3r.d Cltr. 4th Qtr lst(),U 2n.d.Qtr. 3rd(ltr ... 4th Qtr .1s.t.O,tr 2ndQtr 3rd qtr .. 4th Qtr 1st Qtr in<101:r······· 3rd Cl.tr 4th Qtr lst(l.t,t. 2nd Qtr .. 3rd Qtr 4thQfr 2019 NA ............ 2019 NA 2020 NA 2021 NA ···········""'' ., .... . .2022. N.A .... 2022 NA ioii NA so ............... 33 32.1 Table 8 of 16 Historic Nitrate, Nitrate+ Nitrite and Cloride Concentrations in Monitor Wells Up to the 4th Quarter 2022 Nitrate Contamination Investigation White Mesa Uranium Mill TWN-17 Parameter TWN-18 Sampling Event GWQS Sampling Event Nitrate, Nitrate + Nitrite Chloride (mg/I) (10 mg/L) NoGWQS lstQtr 3/24/2010 10.4 78 1st Qtr 3/17/2010 2nd Qtr 6/3/2010 11 87 2nd Qtr 6/1/2010 3rd Qtr 7/15/2010 8.9 66 3rd d.tr 9/27/2010 4th Qtr 12/10/2010 8 65 4th Qtr 12/9/2010 lstQtr 2/1/2011 8.6 90 1st Qtr 1/27/2011 2nd Qtr 4/28/2011 9 81 2nd Qtr 4/26/2011 3rd Qtr 7/29/2011 8.5 74 3rd Qtr 7/28/2011 l4thQtr 10/20/2011 8.1 71 4th Qtr 10/18/2011 1st Qtr 1/12/2012 8.7 79 1st Qtr 1/10/2012 9.1 80 2nd Qtr 2nd Qtr 4/20/2012 4/19/2012 ----------------------~-------------7/26/2012 3rd Qtr 7/27/2012 9.5 85 3rd Qtr 14th Qtr 10/17/2012 9.65 84.8 4thQtr 7/16/2012 ------------------~------------2/18/2013 1st Qtr 2013 NA 1st Qtr 2nd Qtr 2013 NA 2nd Qtr 4/23/2013 TW4-65 dup ofTWN-18 3rd Qtr 2013 NA 3rd Qtr I 8/27/2013 TWN-17 abandoned on July 31, 2013 4th Qtr 10/16/2013 ORC split sample lstQtr 2/14/2014 2nd Qtr 5/6/2014 3rdQtr 8/5/2014 4th Qtr 10/8/2014 TW4-65 dup of TWN-18 lstQtr I 2/18/2015 2nd Qtr 5/13/2015 TW4-65 dup of TWN-18 3rd Qtr I 8/25/2015 4thQtr 10/13/2015 TW4-65 dup ofTWN-18 lstQtr 2/23/2016 2nd Qtr 5/17/2016 3rd Qtr 7/21/2016 4thQtr 10/6/2016 1st Qtr 2/15/2017 2nd Qtr 6/1/2017 3rdQtr 7/19/2017 4thQtr 10/4/2017 lstQtr 1/18/2018 2nd Qtr 5/8/2018 3rd Qtr 8/8/2018 4th Qtr 11/2_1/2018 lstQtr 2/20/2019 TWN-65 dup ofTWN-18 2nd Qtr I 5/29/2019 TWN-65 dup ofTWN-18 3rd Qtr I 8/14/2019 TWN-65 dup ofTWN-18 4th Qtr I 1011612019 DWMRC duplicate of TWN-18 lstQtr I 1/29/2020 TWN-65 dup of TWN-18 2nd Qtr I 5/20/2020 3rdQtr 7/15/2020 4th Qtr 11/12/2020 TWN-65 dup ofTWN-18 lstQtr I 2/17/2021 TWN-65 dup ofTWN-18 2nd Qtr I 5/25/2021 TWN-65 dup ofTWN-18 3rd Qtr I 8/17/2021 TWN-65 dup of TWN-18 4th Qtr I 11/23/2021 1st Qtr I 2/15/2022 TWN-65 dup of TWN-18 2nd Qtr I 5/24/2022 TWN-65 dup ofTWN-18 3rd Qtr I 8/17/2022 TWN-65 dup of TWN-18 4th Qtr I 10/25/2022 NA= Per the CAP and SCO, not sampled Shaded= Nitrate, Nitrate+ Nitrite concentrations greater than the Ground Water Quality Standard of 10 mg/I DRC = Utah Division of Radiation Control Nitrate Pumping System Started in January 2013 As of March 2012 both north and south wild life ponds no longer receiving water. __ Parameter GWQS Nitrate, Nitrate+ Nitrite (10 mg/L) 1.6 1.8 1.8 1.6 1.4 1.8 1.8 1.9 1.9 2.1 ------------2.3 1.95 ------------2.27 2.32 2.46 2.04 2.15 0.29 2.33 2.18 1.8 1.47 1.47 1 1.35 <0.10 0.35 0.668 0.645 0.648 0.497 <0.100 0.501 0.47 0.392 0.419 0.256 0.332 0.283 0.348 0.16 0.155 0.174 0.129 0.152 0.181 0.184 0.162 0.13 0.224 0.249 0.223 0.232 0.208 0.171 0.228 0.227 0.22 0.247 0.199 0.208 0.245 0.199 <0.1 0.34 0.3 0.328 0.349 0.212 Chloride (mg/I) NoGWQS 42 63 64 59 61 67 65 60 64 64 -------67 67.5 -------68.7 64.3 66.1 70.4 67.3 74 68.4 76.5 70 74.8 72.3 73.3 76.6 76.9 81.3 69 68.6 67.6 69.9 52.7 67.4 62.1 63.9 59.0 56.6 53.1 57.8 59.7 48.1 46.4 49.9 50.0 53.3 46.9 47.3 47.1 43.0 51.9 50.6 47.4 44.0 42.3 41.9 46.2 46.1 44.9 44.1 42.9 44.1 46.5 40.9 40.5 40.7 39.6 40.8 40.7 35.6 Table 9 of 16 Historic Nitrate, Nitrate + Nitrite and Cloride Concentrations in Monitor Wells Up to the 4th Quarter 2022 Nitrate Contamination Investigation TWN-19 Sampling -Event Parameter GWQS Nitrate, Nitrate + Nitrite (10 mg/L) 1st_ Cltr __ __ _ ____ 3/23/2_010 __ _ 2nd Qtr 6/1/2010 3rd qtr 9/21{2010 4th Qtr 12/9/2010 1st Cl.tr__ 2/1/2011 2nd Cltr _ .iiisiioii 3-_rd Cl.tr -----7 /is/~011 4th Qt~ 10/18/2011 1.S.t Cltr 1/10/2_012 ______ _ 2nd (),tr 4/19/2012_ 3rd qtr 7/26/2012 4th Qtr --iob:.shoi:i 1st (ltr 2013 NA 2_nd (),tr __ 2013 NA 3rd (ltr 2013 NA 4th Qtr 2013 NA 1st Cltr ______ _ 2nd Qtr 3rd(),tr __ 4th Qtr ~st Cl.tr_ 2n_d(ltr __ 3r~ (ltr _ 4th Qtr 1st_ (ltr __ 2nd Cl.tr 3rd Cl.tr 4th Qtr 1st (ltr 2_n_d Qtr 3r_d(ltr_ 4th Qtr ls_t_ Cltr __ _ 2nd(ltr 3rd (ltr ___ _ 4th Qtr 1st Qtr 2nd_(ltr __ 3rd_ Cl.tr 4th Qtr 1st_ Cltr __ _ 2nd qtr 3rd qtr 4th Qtr 1st (ltr _ 2nd_(),tr 3r_d Cltr __ 4th Qtr 1st Cltr ____ _ 2ndqtr 3rdQtr 4thQtr-- 2015 NA 2015 NA 2015 NA 2018 NA 2018 NA 2018 NA .... "'"'""'"'"'"" 2019 NA 2019 NA 2019 NA 2020 NA 2020 NA 2020 NA 2020 NA 2021 NA 2021 NA 2022 NA --ioi2Nli - TWN-20 Sampling Event 7.2 6.9 Parameter GWQS Nitrate, Nitrate + Nitrite (10 mg/L) White Mesa Uranium Mill Upper Wildlife Pond Sampling Event Parameter GWQS Chloride (mg/I) NoGWQS Nitrate, Nitrate + Nitrite (10 mg/L) 3/18/2010 <0.1 -----i,ii{2oio <0.1_ 7/19/2010_ <O,l 12/10/2010 <0.1 __________ 114 1st Cl.tr _ _ _ __ _ 1{31/2011 _ go 2n_d Cltr 4/25/2CJ11 ~0,1 ___ 1_1_3_ 3-rd (ltr 7 /2S/2011 <0.1 108 4th Qtr -io/1.9/io1i <O.i - _ 1_14_ 1st Qtr 1/31/2012 117 Pond no longer in service 117 118 Chloride (mg/I) NoGWQS TWN-21 Sampling Event Parameter GWQS Nitrate, Nitrate + Nitrite (10 mg/L) 2nd qtr 6/3/2021 1.88 SO 2nd(ltr 6/3/2021 3rd(ltr __ _-.-_. _. Sfl9{202i 0.96 _ 35,3 3rd Cltr _____ ·····_ 8/19/2CJ2~ 1.03 1.16 Chloride (mg/I) NoGWQS <1.0 Chloride (mg/I) NoGWQS 41.9 40.5 4th Qtr 11/23/,.:2:.::0=:21-_______ o:.;_•:=;28:..:6+-___ ...:3:..:3~.6'1-4~t-"-h-"Q"'tr_-+-=11/23/'-"2CC0=:21---------'--'-'--'+-- 1st Cl.tr 2/16/20_2_2 _ _ o,436 ____ 31_,2 1st Qtr 2/16/2022 Q_696 42.6 1.1 40.4 2nd (ltr _________ 5/25/2.02? 0.54 __ 29_.? 2nd(ltr ----5/25/2022 3rd Qtr 8/18/2022 0.48 32.4 3rd Qtr -8/18/2022 · ------ 4th a.tr io/2"ii/Z022 o.«ii 3i.o 4th a.tr -10126/ioii 1.1 39.8 1..19 42.7 1~08 -4ij NA= Per the CAP and sea, not sampled Table 10 of 16 Historic Nitrate, Nitrate + Nitrite and Cloride Concentrations in Monitor Wells Up to the 4th Quarter 2022 Nitrate Contamination Investigation White Mesa Uranium Mill Pizometer 1 Parameter Pizometer 2 Parameter Sampling Event GWQS Sampling Event GWQS Nitrate, Nitrate+ Nitrite Chloride (mg/I) Nitrate, Nitrate+ Nitrite (10 mg/L) NoGWQS (10 mg/L) 2nd Qtr 6/2/2010 7.2 52 2nd Qtr 6/2/2010 0.6 3rd Qtr 7/19/2010 6.8 52 3rd Qtr 7/19/2010 0.6 4thQtr 12/10/2010 6.5 60 4th Qtr 12/10/2010 0.2 1st Qtr 1/31/2011 7 60 1st Qtr 1/31/2011 0.3 2nd Qtr 4/25/2011 6.8 58 2nd Qtr 4/25/2011 0.3 3rd Qtr 7/25/2011 7 53 3rd Qtr 7/25/2011 0.1 4thQtr 10/19/2011 6.6 55 4th Qtr 10/19/2011 0.1 lstQtr 1/11/2012 7.1 78 1st Qtr 1/11/2012 0.1 lstQtr 1/10/2012 7.0 114 1st Qtr 1/31/2012 0.1 2nd Qtr 4/20/2012 6.6 _______ 5~ 2nd Qtr 4/20/2012 0.2 ----------------------------7/27/2012 ------------3rd Qtr 7/27/2012 7.2 56 3rd Qtr 0.2 4thQtr 10/17/2012 7.66 55 4thQtr 7/17/2012 0.19 --------------------------------2/19/2013 ------------lstQtr 2/19/2013 8.11 56.7 1st Qtr 0.22 2nd Qtr 4/24/2013 8.88 53.3 2nd Qtr 4/24/2013 0.172 3rd Qtr 8/28/2013 7.83 55.1 3rd Qtr 8/28/2013 0.198 4thQtr 10/16/2013 6.68 54.1 4th Qtr 10/16/2013 0.36 DRC split of Piez-1 1.3 60 ORC split of Piez-2 0.27 lstQtr 1/13/2014 6.79 56.2 lstQtr 1/13/2014 0.169 2nd Qtr 5/7/2014 7.57 52.1 2nd Qtr 5/7/2014 0.736 3rdQtr 8/6/2014 5.1 55 3rd Qtr 8/6/2014 0.8 4th Qtr 10/8/2014 5.75 57.6 4th Qtr 10/8/2014 0.755 lstQtr 2/18/2015 6.41 55.9 lstQtr 2/18/2015 0.749 2nd Qtr 5/12/2015 5.95 57.5 2nd Qtr 5/12/2015 0.646 3rd Qtr 8/26/2015 4.96 64.2 3rdQtr 8/6/2015 0.7 ~~~_gtr 10/14/20~~ 6.17 54.4 4th Qtr ______ _ 10/14/2015 0.692 --------------------------------------------- lstQtr 2/23/2016 8.31 56.S lstQtr 2/23/2016 0.615 2nd Qtr 5/12/2016 6.33 59.1 2nd Qtr 5/12/2016 0.665 3rd Qtr 7/19/2016 6.78 53.9 3rdQtr 7/19/2016 0.669 4th Qtr 10/11/2016 6.42 58.1 4th Qtr 10/11/2016 0.732 lstQtr 2/15/2017 6.75 54.5 lstQtr 2/15/2017 0.696 2nd Qtr 6/1/2017 6.6 54.7 2nd Qtr 6/1/2017 0.345 3rdQtr 7/20/2017 6.8 58 3rd Qtr 7/20/2017 0.555 4th Qtr 1or.y2011 6.21 54.4 4th Qtr 10/4/2017 0.684 lstQtr 1/17/2018 6.35 55.3 lstQtr 1/17/2018 0.716 2nd Qtr 5/9/2018 6.56 58 2nd Qtr 5/9/2018 0.776 3rdQtr 8/8/2018 6.66 63.S 3rd Qtr 8/8/2018 0.818 4thQtr 11/21/2018 6.7 55.5 4th Qtr 11/20/2018 0.648 lstQtr 2/19/2019 6.72 56.8 lstQtr 2/19/2019 0.599 2nd Qtr 5/30/2019 6.75 59.4 2nd Qtr 5/30/2019 0.702 3rdQtr 8/14/2019 6.81 61.1 3rdQtr 8/14/2019 0.606 4th Qtr 10/16/2019 7.21 59.3 4th Qtr 10/16/2019 0.573 DWMRC_duplicate of P-1 6.4 60 DWMRC duplicate of P-2 0.36 lstQtr 1/30/2020 7.12 68.9 lstQtr 1/30/2020 0.740 2nd Qtr 5/20/2020 6.95 67.7 2nd Qtr 5/20/2020 0.679 3rdQtr 7/15/2020 7.3? 63.6 3rdQtr 7/15/2020 0.793 4th Qtr 11/13/2020 7.51 63.9 4th Qtr 11/13/2020 0.544 lstQtr 2/18/2021 7.34 57.5 lstQtr 2/18/2021 0.401 2nd Qtr 5/27/2021 7.89 69.9 2nd Qtr 5/27/2021 <0.1 3rdQtr 8/19/2021 7.6 70 3rd Qtr 8/19/2021 0.11 4th Qtr 11/23/2021 4.69 65.5 4th Qtr 11/23/2021 <0.1 lstQtr 2/16/2022 7.4 68.8 lstQtr 2/16/2022 0.330 2nd Qtr 5/24/2022 5.9 70.3 2nd Qtr 5/24/2022 0.48 3rdQtr 8/17/2022 6.37 72 3rdQtr 8/17/2022 0.71 4thQtr 10/25/2022 6.36 73.6 4th Qtr 10/25/2022 0.703 DRC = Utah Division of Radiation Control Nitrate Pumping System Started In January 2013 ______ , As of March 2012 both north and south wild life ponds no longer receiving water. __ Chloride (mg/I) NoGWQS 8 8 6 9 8 9 8 9 1 8 -------9 9.5 -------9.67 10.3 9.66 9.22 11 11.4 11.4 12 12.2 12.S 13.1 15.S 13.3 --------------13.4 14 12.4 13.4 12.4 13.2 13.4 12.7 13.0 14.0 15.1 12.3 12.9 12.6 13.2 12.6 21 14.2 14.4 12.7 12.9 15.7 13.9 14.6 14.8 14.0 12.6 14.7 13.4 Table 11 of 16 Historic Nitrate, Nitrate + Nitrite and Cloride Concentrations in Monitor Wells Up to the 4th Quarter 2022 Nitrate Contamination Investigation White Mesa Uranium Mill Pizometer 3 Parameter Pizometer 3A Parameter Sampling Event GWQS Sampling Event GWQS Nitrate, Nitrate + Nitrite Chloride (mg/I) Nitrate, Nitrate + Nitrite (10 mg/L) NoGWQS (10 mg/L) 1st Qtr 3/24/2010 1.7 116 2nd Qtr 6/2/2010 1.6 36 3rdQtr 7/19/2010 1.8 35 l4thQtr 12/9/2010 1.8 25 1st Qtr 1/31/2011 1.8 40 2nd Qtr 4/25/2011 1.7 35 3rdQtr 7/25/2011 1.8 61 l4thQtr 10/19/2011 1.7 12 1st Qtr 1/11/2012 1.8 20 2nd Qtr 4/20/2012 1.7 53 ------------------1---------3rdQtr 7/27/2012 1.8 21 4th Qtr 10/17/2012 2.75 20.1 ------------------1---------l stQtr 2/24/2013 1.85 21 2nd Qtr 4/24/2013 1.83 21.2 3rd Qtr 8/28/2013 1.81 22.4 4th Qtr 10/16/2013 1.8 23,5 DRC split sample 0.33 27 1st Qtr 1/13/2014 1.7 26 2nd Qtr 5/7/2014 1.79 23,9 3rdQtr 8/6/2014 1.7 26 4th Qtr 10/8/2014 1.74 28,3 lstQtr 2/18/2015 1.82 27.3 2nd Qtr 5/12/2015 1.75 30.2 3rd Qtr 8/26/2015 1.87 54.8 Chloride (mg/I) NoGWQS 4th Qtr _____ --10/14/2015 2.24 39.5 New piezometer P-3A to replace piezometer P-3 drilled and installed in ----------------------------------------------------------lstQtr 2/23/2016 1.82 27.3 Pizometer-3 abandonded May 2016 (1)2nd Qtr 5/12/2016 3rdQtr 7/19/2016 4th Qtr 10/11/2016 lstQtr 2/15/2017 2nd Qtr 6/1/2017 3rd Qtr 7/20/2017 4th Qtr ______ ---10/4/2017 1st Qtr 2/17/2018 2nd Qtr 5/9/2018 3rdQtr 8/8/2018 4th Qtr 11/20/2018 lstQtr 2/17/2019 2nd Qtr 5/30/2019 3rd Qtr 8/14/2019 4th Qtr 10/16/2019 DWMRC duplicate of P-3a lstQtr 1/30/2020 2nd Qtr 5/20/2020 3rd Qtr 7/15/2020 4th Qtr 11/13/2020 lstQtr 2/18/2021 2nd Qtr 5/27/2021 3rdQtr 8/19/2021 4th Qtr 11/23/2021 lstQtr 2/16/2022 2nd Qtr 5/24/2022 3rdQtr 8/17/2022 4th Qtr 10/25/2022 1. New piezometer PIEZ-3A to replace PtEZ-3 drilled and installed in May 2016. First monitoring event. Shaded= Nitrate, Nitrate+ Nitrite concentrations greater than the Ground Water Quality Standard of 10 mg/l ORC = Utah Division of Radiation Control Nitrate Pumping System Started in January 2013 ______ , As of March 2012 both north and south wild life ponds no longer receiving water. __ May 2016. 8.33 109 8.83 93.8 8.44 100 10.0 111 10.1 124 9.31 105 9.65 107 ---------------------------8.61 94,3 9.98 100 12.1 122 11.8 105 11.8 102 11.8 104 10.7 96,2 8,97 83.0 6,4 98.0 105 99.5 12.4 88.3 12.8 82.7 13 72.8 11.1 85.9 14.4 85.6 11.2 81.5 9.11 84.6 12.1 91.7 8.8 114.0 10.6 109 11.5 81.5 Table 12 of 16 Historic Nitrate, Nitrate + Nitrite and Cloride Concentrations in Monitor Wells Up to the 4th Quarter 2022 Nitrate Contamination Investigation White Mesa Uranium Mill TW4-19(Pumping well startin1 in Parameter TW4-20 (Pumping well statin1 in Parameter April 2003) August2005) Sampling Event GWQS Sampling Event GWQS Nitrate, Nitrate+ Nitrite Chloride (mg/I) Nitrate, Nitrate + Nitrite (10 mg/L) NoGWQ5 (10 mg/L) lstQtr 3/16/2005 5.3 NA 2nd Qtr 5/25/2005 5.7 NA 2nd Qtr 5/25/2005 10.10 3rd Qtr 8/31/2005 4.6 NA 3rd Qtr 8/31/2005 2.90 4th Qtr 12/7/2005 81 4th0tr---12/7/2005 ------------<0.1 1.80 lstQtr 3/9/2006 4 86 1st Qtr 3/9/2006 3.80 2nd Qtr 6/14/2006 5.2 116 2nd Qtr 6/14/2006 9.40 3rdQtr 7/20/2006 4.3 123 3rd Qtr 7/20/2006 2.90 4th Qtr 11/8/2006 4.6 134 4thQtr 11/8/2006 3.50 lstQtr 2/28/2007 4 133 1st Qtr 2/28/2007 4.20 2nd Qtr 6/27/2007 not sampled 2nd Qtr 6/27/2007 2.30 3rd Qtr 8/15/2007 4.1 129 3rd Qtr 8/15/2007 2.10 4th Qtr 10/10/2007 4 132 4th Qtr 10/10/2007 5.60 lstQtr 3/28/2008 2.2 131 1st Qtr 3/28/2008 0.90 2nd Qtr 6/25/2008 2.8 128 2nd Qtr 6/25/2008 8.00 3rd Qtr 9/10/2008 35.2 113 3rd Qtr 9/10/2008 4.44 4thQtr 10/15/2008 47.8 124 4th Qtr 10/15/2008 5.51 lstQtr 3/4/2009 3.2 127 1st Qtr 3/4/2009 5.10 2nd Qtr 6/23/2009 2.4 132 2nd Qtr 6/23/2009 2.90 3rd Qtr 9/14/2009 <0.1 43 3rd Qtr 9/14/2009 3.30 4thQtr 12/22/2009 26.7 124 4th Qtr 12/22/2009 5.30 lstQtr 2/17/2010 2 144 1st Qtr 2/17/2010 2.00 2nd Qtr 6/14/2010 4.4 132 2nd Qtr 6/14/2010 5.60 3rd Qtr 8/16/2010 5.9 142 3rd Qtr 8/16/2010 5.30 4thQtr 10/15/2010 2.7 146 4th Qtr 10/15/2010 4.60 lstQtr 2/17/2011 17.0 135 lstQtr 2/17/2011 4.40 2nd Qtr 6/7/2011 12.0 148 2nd Qtr 6/7/2011 4.80 3rd Qtr 8/17/2011 3.0 148 3rdQtr 8/17/2011 6.50 4thQtr 11/17/2011 5.0 148 4th Qtr 11/17/2011 4.20 lstQtr 1/23/2012 0.6 138 lstQtr 1/23/2012 ---------7;99_ -------------------L--------------6/6/2012 2nd Qtr 6/6/2012 2.4 149 2nd Qtr 11.00 3rd Qtr 9/4/2012 2.5 149 3rdQtr 9/4/2012 10.80 4thQtr 10/3/2012 4.1 150 4th Qtr 10/3/2012 11.00 1st Qtr 2/13/2013 8.0 164 lstQtr 2/13/2013 9.07 2nd Qtr 6/5/2013 3.0 148 2nd Qtr 6/5/2013 9.80 3rd Qtr 9/3/2013 17.6 179 3rdQtr 9/3/2013 8.65 4thQtr 10/29/2013 4.7 134 4th Qtr 10/29/2013 9.64 1st Qtr 1/27/2014 1.6 134 lstQtr 1/27/2014 7.56 2nd Qtr 5/19/2014 1.3 152 2nd Qtr 5/19/2014 5.95 3rd Qtr 8/11/2014 1.6 140 3rd Qtr 8/11/2014 4.30 4th Qtr 10/21/2014 4.7 130 4th Qtr 10/21/2014 7.67 lstQtr 3/9/2015 8.56 238 lstQtr 3/9/2015 9.80 2nd Qtr 6/8/2015 0.916 180 2nd Qtr 6/8/2015 5.76 3rd Qtr 8/31/2015 11.6 326 3rd Qtr 8/31/2015 9.3 ~~-~_gtr 10/19/201~ 10.6 252 4th Qtr 10/19/2015 6.23 ----------------------------------------------------------------------------------------- 1st Qtr 3/9/2016 15.70 276 lstQtr 3/9/2016 10.30 2nd Qtr 5/26/2016 1.27 204 2nd Qtr 5/26/2016 11.2 3rdQtr 7/25/2016 10.5 214 3rd Qtr 7/25/2016 11.3 4th Qtr 10/13/2016 10.0 200 4th Qtr 10/13/2016 11.4 lstQtr 3/8/2017 11.1 461 lstQtr 3/8/2017 12.0 2nd Qtr 6/13/2017 0.243 135 2nd Qtr 6/13/2017 9.76 3rd Qtr 7/26/2017 1.120 218 3rdQtr 7/26/2017 10.8 4th Qtr 10/11/2017 0.377 139 4th Qtr 10/11/2017 8.91 1st Qtr 3/12/2018 8.6 193 1st Qtr 3/12/2018 9.5 2nd Qtr 6/8/2018 0.494 138 2nd Qtr 6/8/2018 10.40 3rd Qtr 8/30/2018 2.55 166 3rdQtr 8/30/2018 8.14 4thQtr 11/28/2018 0.233 140 4th Qtr 11/28/2018 9.72 1st Qtr 3/8/2019 6.6 197 lstQtr 3/8/2019 6.7 2ndQtr 6/5/2019 6.580 160 2nd Qtr 6/5/2019 9.59 3rd Qtr 9/4/2019 0.33 153 3rd Qtr 9/4/2019 10.2 4thQtr 12/10/2019 0.535 147 4th Qtr 12/10/2019 9.75 1st Qtr 2/19/2020 10.1 205 lstQtr 2/19/2020 9.81 2nd Qtr 5/27/2020 1.140 147 2nd Qtr 5/27/2020 7.23 3rd Qtr 9/4/2020 11.6 188 TW4-20 Abandonded October 2020 4thQtr 12/10/2020 1.1 104 1st Qtr 2/23/2021 6.6 167 2ndQtr 6/9/2021 4.04 115 3rd Qtr 8/24/2021 6.68 172 4thQtr 12/1/2021 11.1 184 lstQtr 3/9/2022 1.7 119 2ndQtr 6/8/2022 1.4 128 3rd Qtr 8/30/2022 4.76 178 4th Qtr 11/30/2022 3.6 129 Shaded = Nitrate, Nitrate-+ Nitrite concentrations greater than the Ground Water Quality Standard of 10 mg/I As of March 2012 both north and south wild life ponds no longer receiving water. __ (2)Pumping well stating in August 2005 Chloride (mg/I) NoGWQ5 NA NA -------131 120 235 134 124 124 112 117 170 132 191 156 168 164 164 153 187 179 200 196 203 220 177 207 186 207 -------262 289 302 252 250 260 272 254 269 299 292 290 296 365 293 ------293 318 307 301 290 281 292 293 289 258 282 295 272 279 286 307 310 301 Table 13 of 16 Historic Nitrate, Nitrate+ Nitrite and Cloride Concentrations in Monitor Wells Up to the 4th Quarter 2022 Nitrate Contamination Investigation White Mesa Uranium Mill TW4-21 (Pumping well starting In Parameter TW4-22 (Pumping well stating in Parameter June2015) August2005) Sampling Event GWQS Sampling Event GWQS Nitrate, Nitrate + Nitrite Chloride (mg/I) Nitrate, Nitrate + Nitrite (10 mg/L) NoGWQS (10 mg/L) Chloride (mg/I) NoGWQS 1st Qtr 3/16/2005 was not sampled 1st Qtr 3/16/2005 was not sampled 2nd Qtr 5/25/2005 14.6 NA 2nd Qtr 5/25/2005 3rd Qtr 8/31/2005 10.1 NA 3rd Qtr 8/31/2005 4thQtr 12/7/2005 9.6 353 4th Qtr 12/7/2005 lstQtr 3/9/2006 8.5 347 1st Qtr 3/9/2006 2ndQtr 6/14/2006 10.2 318 2nd Qtr 6/14/2006 3rd Qtr 7/20/2006 8.9 357 3rd Qtr 7/20/2006 4thQtr 11/8/2006 8.7 296 4th Qtr 11/8/2006 1st Qtr 2/28/2007 8.7 306 1st Qtr 2/28/2007 2nd Qtr 6/27/2007 8.6 327 2nd Qtr 6/27/2007 3rd Qtr 8/15/2007 8.6 300 3rd Qtr 8/15/2007 4th Qtr 10/10/2007 8.3 288 4th Qtr 10/10/2007 1st Qtr 3/28/2008 14.3 331 lstQtr 3/28/2008 2nd Qtr 6/25/2008 8.8 271 2nd Qtr 6/25/2008 3rd Qtr 9/10/2008 7.57 244 3rdQtr 9/10/2008 4th Qtr 10/15/2008 8.0 284 4th Qtr 10/15/2008 1st Qtr 3/11/2009 8.3 279 lstQtr 3/11/2009 2nd Qtr 6/23/2009 8.1 291 2nd Qtr 6/23/2009 3rdQtr 9/14/2009 9.2 281 3rd Qtr 9/14/2009 14th Qtr _____ 12/22/200~ 8.4 256 4th Qtr 12/29/2009 ----------------------------------------------------------1st Qtr 2/25/2010 8.4 228 1st Qtr 3/3/2010 2nd Qtr 6/14/2010 12.0 266 2nd Qtr 6/14/2010 3rdQtr 8/13/2010 14.0 278 3rd Qtr 8/24/2010 4th Qtr 10/15/201g 7.0 210 4th Qtr 10/15/2010 ----------------------------------------------------------1st Qtr 2/22/2011 9.0 303 lstQtr 2/22/2011 2nd Qtr 6/28/2011 12.0 290 2nd Qtr 6/1/2011 3rdQtr 8/17/2011 14.0 287 3rd Qtr 8/17/2011 4th Qtr 11/16/2011 13.0 287 4thQtr 11/16/2011 ~l~t_9~ 1/19/2012 15.0 228 {i)lst Qtr 1/19/2012 ------------------i.... _______ ------6/13/2012 2nd Qtr 6/13/2012 11.0 285 2nd Qtr 3rd Qtr 9/13/2012 13.0 142 3rd Qtr 9/12/2012 4th Qtr 10/4/2012 14.0 270 4thQtr 10/4/2012 lstQtr 2/13/2013 11.8 221 !3ii'stQtr--2/11/2013 2ndQtr 6/18/2013 13.8 243 2nd Qtr 6/5/2013 3rd Qtr 9/13/2013 10.3 207 3rdQtr 9/3/2013 4thQtr 11/13/2013 9.0 206 4th Qtr 10/29/2013 lstQtr 2/5/2014 11.4 200 1st Qtr 1/27/2014 2nd Qtr 5/22/2014 11.5 243 2nd Qtr 5/19/2014 3rd Qtr 8/27/2014 7.1 230 3rd Qtr 8/11/2014 4thQtr 10/29/2014 10.0 252 4th Qtr 10/29/2014 1st Qtr 3/12/2015 10.9 255 1st Qtr 3/9/2015 (2)2nd Qtr 6/8/2015 13.1 494 2nd Qtr 6/8/2015 -8/31/2015 --------------------3rd Qtr 14.7 499 3rd Qtr 8/31/2015 ~~-~_g.tr 10/19/201~ 14.3 413 4th Qtr ______ _ 10/19/2015 ----------------------------------------1st Qtr 3/9/2016 14.6 452 lstQtr 3/9/2016 2nd Qtr 5/23/2016 13.1 425 2nd Qtr 5/23/2016 3rd Qtr 7/25/2016 16.5 457 3rd Qtr 7/25/2016 4thQtr 10/12/2016 13.5 439 4th Qtr 10/12/2016 1st Qtr 3/8/2017 17.7 452 lstQtr 3/8/2017 2nd Qtr 6/13/2017 9.53 309 2nd Qtr 6/13/2017 3rd Qtr 7/26/2017 18.20 447 3rdQtr 7/26/2017 4th Qtr 10/11/2017 16.90 378 4th Qtr 10/11/2017 DWMRC split TW4-21 11.0 310 OWMRC split of TW4-22 1st Qtr 3/12/2018 15.8 447 lstQtr 3/12/2018 2nd Qtr 6/8/2018 14.1 387 2nd Qtr 6/8/2018 3rdQtr 8/22/2018 0.236 182 3rd Qtr 8/22/2018 4th Qtr 10/22/2018 15.2 378 4th Qtr 11/28/2018 1st Qtr 3/8/2019 9.0 180 lstQtr 3/8/2019 2nd Qtr 6/5/2019 17.5 456 2nd Qtr 6/5/2019 3rdQtr 9/4/2019 14.7 478 3rdQtr 9/4/2019 4th Qtr 12/10/2019 5.73 339 4th Qtr 12/10/2019 lstQtr 2/19/2020 8.9 446 lstQtr 2/19/2020 2ndQtr 5/27/2020 15.4 353 2nd Qtr 5/27/2020 3rd Qtr 9/4/2020 12.6 382 3rdQtr 9/4/2020 4th Qtr 10/28/2020 16.30 411 4th Qtr 10/28/2020 1st Qtr 2/23/2021 15.2 454 lstQtr 2/23/2021 2nd Qtr 6/9/2021 21.5 461 2nd Qtr 6/9/2021 3rd Qtr 8/24/2021 12.9 375 3rd Qtr 8/24/2021 4th Qtr 12/1/2021 17.2 227 4th Qtr 12/1/2021 1st Qtr 3/9/2022 2.2 110 1st Qtr 3/9/2022 2nd Qtr 6/8/2022 8.9 331 2nd Qtr 6/8/2022 3rd Qtr 8/30/2022 14.3 425 3rd Qtr 8/30/2022 4thQtr 11/30/2022 2.1 158 4th Qtr 11/30/2022 NA= not analyzed (1) As of March 2012 both north and south wild life ponds no longer receiving water (2) Chloroform pumping well started 6/9/15. (3) Chloroform pumping well started 1126/13. Shaded= Nitrate, Nitrate+ Nitrite concentrations greater than the Ground Water Quality Standard of 10 mg/I DWMRC = Utah Division of Waste Management and Radiation Control 18.2 NA 15.7 NA 15.1 253 15.3 236 14.3 221 14.5 221 15.9 236 20.9 347 19.3 273 19.3 259 18.8 238 39.1 519 41.9 271 38.7 524 36.3 539 20.7 177 20.6 177 40.3 391 17.8 175 36.8 427 19.0 134 15.0 13C 16.0 134 18.0 114 17.0 138 15.0 120 19.0 174 14.0 36 -------------------12.8 35 7.0 121 14.0 130 -------------------58.0 130 50.2 586 29.7 487 45.2 501 54.6 598 47.2 614 41.5 540 54.9 596 69.2 675 47.1 390 64.7 557 56.1 567 ---------------------------------------------------------31.1 58, 58.4 59! 61.3 61' 61.5 58: 69.8 566 70.8 572 66.1 391 80.1 600 79.0 610 62.3 607 72.5 580 55.4 613 75.7 567 71.9 52 83.9 6€ 72.5 58 59.9 5n 57.7 60 60.5 51 64.8 51 64.9 52 69.6 :~: 89.3 35.1 410 68.8 586 40.4 442 45.0 564 69.9 637 62.0 601 Table 14 of 16 Historic Nitrate, Nitrate+ Nitrite and Cloride Concentrations in Monitor Wells Up to the 4th Quarter 2022 Nitrate Contamination Investigation White Mesa Uranium Mill TW4•24(Pumping well starting in Parameter January2013) Sampling Event GWQS Nitrate, Nitrate + Nitrite Chloride (mg/I) (10 mg/L) NoGWQS 2ndQtr 6/27/2007 26.1 770 3rd Qtr 8/15/2007 29 791 4thQtr 10/10/2007 24.7 692 1st Qtr 3/28/2008 24.4 740 2nd Qtr 6/25/2008 45.3 834 3rd Qtr 9/10/2008 38.4 1,180 4thQtr 10/15/2008 44.8 1,130 1st Qtr 3/4/2009 30.5 1,010 2nd Qtr 6/23/2009 30.4 759 3rdQtr 9/14/2009 30.7 618 4thQtr 12/16/2009 28.3 1,080 1st Qtr 2/25/2010 33.1 896 2nd Qtr 6/14/2010 30 639 3rdQtr 8/24/2010 31 587 4th Qtr 10/15/2010 31 522 1st Qtr 2/17/2011 31 1,100 2nd Qtr 5/26/2011 35 1,110 3rdQtr 8/17/2011 34 967 4th Qtr 11/16/2011 35 608 lstQtr 1/16/2012 37 373 ------------------L--------2nd Qtr 6/6/2012 37 355 3rdQtr 8/30/2012 37 489 4th Qtr 10/3/2012 38 405 lstQtr 2/11/2013 35.9 1,260 ------------------~-------2ndQtr 6/5/2013 23.7 916 3rd Qtr 8/30/2013 33 998 4thQtr 10/29/2013 35 1,030 lstQtr 1/27/2014 31.6 809 2ndQtr 5/19/2014 35.0 1,020 3rd Qtr 8/11/2014 31.5 1,150 4thQtr 10/21/2014 35.7 1,050 lstQtr 3/9/2015 34.6 944 2ndQtr 6/8/2015 31.8 1,290 3rd Qtr 8/31/2015 25.3 788 4thQtr 10/19/2015 29.6 909 1st Qtr 3/9/2016 29.1 989 2ndQtr 5/23/2016 24.2 771 3rd Qtr 7/25/2016 34.4 1,180 4thQtr 10/12/2016 31.9 1,010 1st Qtr 3/8/2017 41.3 1,090 2nd Qtr 6/13/2017 39.9 1,080 3rd Qtr 7/26/2017 40.0 1,230 4thQtr 10/11/2017 31.7 895 DWMRC split ofTW4-24 32.0 1,100 1st Qtr 3/16/2018 44.9 1,320 2nd Qtr 6/14/2018 33.6 792 3rd Qtr 8/22/2018 33.8 996 4thQtr 11/28/2018 38.4 1,100 1st Qtr 3/8/2019 39.3 1,040 2nd Qtr 6/5/2019 33.2 1,020 3rd Qtr 9/4/2019 36.4 1,130 4th Qtr 12/10/2019 33.8 1,090 1st Qtr 2/19/2020 37.1 1,010 2nd Qtr 5/27/2020 41.7 1060 3rd Qtr 9/4/2020 39.1 1100 4th Qtr 10/28/2020 35.90 1050 1st Qtr 2/23/2021 41.9 1,170 2nd Qtr 6/9/2021 48.0 938 3rd Qtr 8/24/2021 26.7 1010 4thQtr 12/1/2021 43.60 1140 1st Qtr 3/9/2022 36.2 890 2nd Qtr 6/8/2022 35.0 944 3rd Qtr 8/30/2022 32.0 868 4th Qtr 11/30/2022 27.6 972 As of March 2012 both north and south wild life ponds no longer rece,v,ng water Chloroform pumping well started January 2013 TW4-25 (Pumpins well stating in January2013) Sampling Event 2nd Qtr 6/27/2007 3rd Qtr 8/15/2007 4thQtr 10/10/2007 lstQtr 3/28/2008 2nd Qtr 6/25/2008 3rd Qtr 9/10/2008 4thQtr 10/15/2008 1st Qtr 3/4/2009 2nd Qtr 6/23/2009 3rdQtr 9/14/2009 4th Qtr 12/14/2009 lstQtr 2/23/2010 2nd Qtr 6/14/2010 3rd Qtr 8/10/2010 4th Qtr 10/15/2010 lstQtr 2/16/2011 2nd Qtr 5/25/2011 3rdQtr 8/16/2011 4th Qtr 11/15/2011 lstQtr 1/16/2012 ------5/31/2012 2nd Qtr 3rdQtr 9/4/2012 4th Qtr 10/3/2012 lstQtr 2/11/2013 ------6/5/2013 (2)2nd Qtr 3rd Qtr 9/4/2013 4th Qtr 10/31/2013 lstQtr 1/27/2014 2nd Qtr 5/19/2014 3rd Qtr 8/11/2014 4thQtr 10/21/2014 lstQtr 3/9/2015 2nd Qtr 6/8/2015 3rd Qtr 8/31/2015 4thQtr 10/19/2015 DWMRC split of TW4-25 1st Qtr 3/9/2016 2nd Qtr S/23/2016 3rd Qtr 7/25/2016 4thQtr 10/12/2016 1st Qtr 3/8/2017 2nd Qtr 6/13/2017 3rd Qtr 7/26/2017 4th Qtr 10/11/2017 1st Qtr 3/12/2018 2nd Qtr 6/14/2018 3rd Qtr 8/22/2018 4thQtr 11/28/2018 1st Qtr 3/8/2019 2nd Qtr 6/5/2019 3rdQtr 9/4/2019 4thQtr 12/10/2019 1st Qtr 2/19/2020 2nd Qtr 5/27/2020 3rd Qtr 9/4/2020 4thQtr 10/28/2020 1st Qtr 2/23/2021 2nd Qtr 6/9/2021 3rd Qtr 8/24/2021 4thQtr 12/1/2021 1st Qtr 3/9/2022 2nd Qtr 6/8/2022 3rd Qtr 8/30/2022 4th Qtr 11/30/2022 Shaded= Nitrate, Nitrate+ Nitrite concentrations greater than the Ground Water Quality Standard of 10 mg/I DWMRC = Utah Division of Waste Management and Radiation Control Parameter GWQS Nitrate, Nitrate + Nitrite (10 mg/L) 17.1 29 17 18.7 22.1 18.8 21.3 15.3 15.3 3.3 14.2 14.4 16 14 15 15 16 16 16 16 ------------16 17 17 9.04 -----------5.24 5.69 6.1 2.16 1.21 1.6 1.03 14.4 1.14 1.63 1.78 1.50 0.837 0.959 1.78 1.24 17.0 0.976 1.23 1.29 2.23 1.14 0.810 0.634 0.639 0.821 0.548 0.841 0.607 0.851 0.994 1.6 3.43 1.57 0.793 0.978 1.8 0.88 1.51 1.47 Chloride (mg/I) NoGWQS 395 382 358 374 344 333 366 332 328 328 371 296 306 250 312 315 321 276 294 304 -------287 334 3~! 19( ------:i36 119 88.6 85.7 51.1 67 58.1 310 58.3 69.2 93.7 94 62.7 75.5 74.1 59.8 285 69.8 70.1 68.0 70.5 60.3 69.1 59.70 65.0 59.0 58.1 73.10 86.0 76.8 67.3 61.3 100.0 55.1 69.3 93.7 70.3 72.8 82.5 67.2 Table 15 of 16 Historic Nitrate, Nitrate+ Nitrite and Cloride Concentrations in Monitor Wells Up to the 4th Quarter 2022 Nitrate Contamination Investigation White Mesa Uranium Mill TW4•37(Pumping well starting in Parameter June2015) Sampling Event GWQS Nitrate, Nitrate+ Nitrite Chloride (mg/I) (10 mg/L) NoGWQS 2nd Qtr J 6/8/2015 35.2 345 !;~ 6:: _____ --1~~~!~~~~! 32.4 374 34.6 399 -----------------------------------------lstQtr 3/9/2016 28.4 332 2nd Qtr I 5/23/2016 27.9 389 3rd Qtr 7/25/2016 33.4 294 4th Qtr 10/12/2016 26.1 304 lstQtr 3/8/2017 32.3 305 2nd Qtr 6/15/2017 31.2 281 3rd Qtr 7/26/2017 30.5 277 4thQtr 10/11/2017 30.6 255 lstQtr 3/12/2018 30.0 263 2nd Qtr 6/8/2018 28.6 275 3rd Qtr 8/22/2018 25.3 387 4thQtr 11/28/2018 27.3 264 lstQtr 3/8/2018 30.1 209 2nd Qtr 6/5/2019 31.2 250 3rd Qtr 9/4/2019 25.8 228 4thQtr 12/10/2019 25.5 220 lstQtr 2/19/2020 28.3 236 2nd Qtr 5/27/2020 28.3 321 3rd Qtr 9/4/2020 29.5 273 4thQtr 10/28/2020 28.7 254 lstQtr 2/23/2021 26.9 242 2nd Qtr 6/9/2021 26.6 176 3rd Qtr 8/24/2021 25.8 220 4thQtr 12/1/2021 31.3 410 lstQtr 3/9/2022 29.8 414 2nd Qtr 6/8/2022 28.0 276 3rd Qtr 8/30/2022 26.6 243 4thQtr 11/30/2022 30.9 578 Shaded = Nrtrate, Nitrate+ N1tnte concentrat,ons greater than the Ground Water Quality Standard of 10 mg/I MW-30 Table 16 of 16 Historic Nitrate, Nitrate+ Nitrite and Cloride Concentrations in Monitor Wells Up to the 4th Quarter 2022 Nitrate Contamination Investigation White Mesa Uranium Mill Parameter MW-31 Parameter Sampling Event GWQS Sampling Event GWQS Nitrate, Nitrate + Nitrite Chloride (mg/I) Nitrate, Nitrate + Nitrite (10 mg/L) NoGWQS (10 mg/L) 2nd Qtr 6/22/2005 12.4 125 2nd Qtr 6/22/2005 24.2 3rdQtr 9/22/2005 12.8 125 3rdQtr 9/22/2005 22.4 4th Qtr 12/14/2005 13.6 128 4th Qtr 12/14/2005 23.8 lstQtr 3/22/2006 13.8 125 lstQtr 3/22/2006 24.1 2nd Qtr 6/21/2006 14.5 124 2nd Qtr 6/21/2006 25.3 3rdQtr 9/13/2006 14.1 118 3rdQtr 9/13/2006 24.6 4th Qtr 10/25/2006 14.6 124 4th Qtr 10/25/2006 25.1 1st Qtr 3/15/2007 14.4 125 lstQtr 3/15/2007 23.2 Chloride (mg/I) NoGWQS 139 136 135 133 138 131 127 132 2nd Qtr 2007 not sampled 2nd Qtr 2007 not sampled 3rd Qtr 8/22/2007 14.6 126 3rdQtr 8/22/2007 23.3 136 4thQtr 10/24/2007 14.9 122 4thQtr 10/24/2007 24.6 122 lstQtr 3/19/2008 14.8 118 lstQtr 3/19/2008 25 124 2ndQtr 6/3/2008 18.7 125 2nd Qtr 6/3/2008 29.3 128 3rd Qtr 8/4/2008 17.3 121 3rd Qtr 8/4/2008 28.7 124 4thQtr 11/5/2008 15.6 162 4thQtr 11/5/2008 29.9 119 lstQtr 2/3/2009 15.3 113 1st Qtr 2/3/2009 23.4 115 2ndQtr 5/13/2009 15.1 122 2nd Qtr 5/13/2009 22.4 124 3rd Qtr 8/24/2009 20.9 118 3rd Qtr 8/24/2009 15.4 122 l4thQtr 10/14/2009 15.0 129 4thQtr 10/14/2009 22.6 138 lstQtr 2/9/2010 16.l 127 1st Qtr 2/9/2010 21.7 128 2ndQtr 4/27/2010 15.8 97 2nd Qtr 5/21/2010 23 128 3rd Qtr 9/14/2010 15.0 111 3rd Qtr 9/13/2010 21 139 4thQtr 12/14/2010 16.0 126 4thQtr 11/9/2010 20 138 1st Qtr 2/1/2011 16.0 134 1st Qtr 2/1/2011 21 145 2nd Qtr 6/20/2011 16.0 124 2nd Qtr 6/20/2011 22 145 3rd Qtr 9/7/2011 17.0 127 3rd Qtr 9/7/2011 21 148 4th Qtr 12/12/2011 16.0 124 4th Qtr 12/12/2011 21 148 1st Qtr 3/14/2012 18.0 128 lstQtr 3/13/2012 22 152 2nd Qtr 6/18/2012 15 131 2nd Qtr 6/18/2012 21.6 138 3rdQtr 9/19/2012 16 130 3rdQtr 9/18/2012 21 172 4th Qtr 12/26/2012 17.2 122 4th Qtr 12/18/2012 22.2 170 1st Qtr 2/26/2013 21.4 129 lstQtr 2/19/2013 19.3 174 2nd Qtr 5/15/2013 18.8 119 2nd Qtr 5/13/2013 23.8 169 3rdQtr 7/10/2013 17.6 130 3rdQtr 7/9/2013 21.7 182 4thQtr 11/20/2013 19.5 124 4th Qtr 11/18/2013 23 9 174 1st Qtr 2/25/2014 18.4 135 lstQtr 2/17/2014 20.6 197 2nd Qtr 6/3/2014 19.5 128 2nd Qtr 6/3/2014 23.1 173 3rdQtr 9/9/2014 16.8 139 3rdQtr 9/3/2014 18.9 210 4th Qtr 11/10/2014 16.2 154 4thQtr 11/4/2014 20.9 204 lstQtr 2/4/2015 14.9 136 lstQtr 2/2/2015 18.7 211 2nd Qtr 4/8/2015 17 142 2nd Qtr 4/7/2015 19 211 3rdQtr 8/11/2015 17.9 165 3rd Qtr 8/10/2015 19.9 264 4th Qtr 11/11/2015 16.3 140 4thQtr 11/9/2015 18.4 215 lstQtr 2/10/2016 20 145 lstQtr 2/10/2016 18.8 246 2nd Qtr 5/4/2016 17.3 139 2nd Qtr 5/3/2016 18.6 243 3rd Qtr 8/18/2016 18 150 3rd Qtr 8/16/2016 19.7 272 14th Qtr 11/3/2016 18 143 4thQtr 11/1/2016 19.8 267 1st Qtr 2/2/2017 17.4 150 lstQtr 2/7/2017 21.1 266 12nd Qtr 4/5/2017 18.3 146 2nd Qtr 5/1/2017 18.3 263 13rd Qtr 8/14/2017 19.2 173 3rd Qtr 8/14/2017 19.5 310 14th Qtr 11/1/2017 17.4 156 4thQtr 11/1/2017 19 292 lstQtr 2/22/2018 17.6 158 1st Qtr 2/20/2018 18.8 292 2ndQtr 4/12/2018 17.3 145 2nd Qtr 4/17/2018 19 308 3rd Qtr 9/11/2018 18 183 3rd Qtr 9/10/2018 20.1 333 4thQtr _____ --10/22/2018 17.2 140 4thQtr ______ __;9/24/2018 18.3 286 ----------------------------------------------------------------------------------lstQtr 2/13/2019 18.2 167 1st Qtr 2/12/2019 18.6 296 2nd Qtr 4/10/2019 18.S 138 2nd Qtr 4/10/2019 19.7 294 3rd Qtr 7/16/2019 19.3 181 3rd Qtr 7/16/2019 19.8 374 4thQtr 10/8/2019 18.2 170 4th Qtr 10/9/2019 19.8 318 lstQtr 1/15/2020 16.4 182 1st Qtr 1/15/2020 17.5 381 2nd Qtr 4/6/2020 18.1 195 2nd Qtr 4/6/2020 18.8 376 3rd Qtr 7/6/2020 18.4 185 3rd Qtr 7/7/2020 19.2 370 4th Qtr 12/8/2020 12 166 4thQtr 12/7/2020 18.8 311 lstQtr 3/8/2021 17 192 lstQtr 3/9/2021 17.4 388 2nd Qtr 4/14/2021 17.7 162 2nd Qtr 4/13/2021 18.6 377 3rd Qtr 7/29/2021 20.6 188 3rd Qtr 7/27/2021 18.7 391 4th Qtr 10/19/2021 14.3 182 4thQtr 10/19/2021 18.1 371 lstQtr 1/17/2022 14.S 181 1st Qtr 1/19/2022 18.0 370 2nd Qtr 4/20/2022 17.0 173 2nd Qtr 4/11/2022 18.0 372 3rd Qtr 7/12/2022 17.6 108 3rd Qtr 7/12/2022 16.9 421 4th Qtr 10/13/2022 17.9 195 4thQtr 10/11/2022 17 397 Shaded = Nitrate, Nitrate+ Nitrite concentrations greater than the Ground Water Quality Standard of 10 mg/1 Table 2 Summary of QA/QC Duplicate Sample 4th Quarter 2022 Parameter GWQS Duplicate of TWN-20 TWN-20 TWN-65 Nitrate + Nitrite (as N) 10 mg/L 0.446 Chloride none 32.0 High lighted exceeding PRO (Rel1tve % difference) of 20% NA= Not Analyzed 0.405 32 .0 RPO 9.6 0.0 Data Discrlptions MW4 MW-26 TW4-1 Nitrate (mg/L) . 4.05 t-i~r!lte (9/~f ...... . ........ 4.0SE-03 f'JitrajEl(lbs/~L 8.95E-06 N.~r11tEl (l~s,/gal) .. ..................... ... ..... ....... 3.39E-05 0.337 .... 3.62 3.37E-04 3.62E-03 1.<1sE~ci1 8.00E-06 2.s2E:as 3.03E-05 !C>t11i g11llc,115,Jllllllf>El~ ......... ~1 :"~!c41····· 2~:'11.1 ... :".,............. 8450.8 lbs of nit~f~ir:ieo~~oved ... .. ...... ... . . . ......... }½~ ..... ·········· ri'.ri~ .... . ri:~~ lbs nitrate removed from all pumping wells lbs nitrate removed from nitrate pumping wells TW4-2 3.74 Tabel3 DWMRC Nitrate Mass Removal Calculations Energy Fuels Resorses Inc. White Mesa Mill, Bland, Utah 4th Quarter 2022 Chloroform Pum_j>l_rlg_ Wells TW4-4 I TW4-11 I TW4-19 I TW4-21 TW4-37 3.580 30.9 6.591 7.051 -·---, -··-i .. -----·-, 3. 7 4E-03 j ~'~~.1::.0..3..~ ···························· 1.46E-05 8.26E-06 3.13E-05 12148.6 0.38 0.03 7.05E-03 1.56E-05 3.58E-03 7.91E-06 2.12E-03 4.68E-06 3.09E-02 s.a3E:os s:s1E:os 8777.0 ii:48 a:a.i 63.17 38 5.90E-05 1442.4 0.09 0.01 2.99E-05 1.77E-05 2.58E-04 137474.5 4.12 0.33 9,i,ir~!l ·· 43~!~; Nitrate Pumping Wells TW4-39 TW4-40 TW4-41 TWN-2 I TW4-22 I TW4-24 I TW4-25 7.86 7.86E-03 1.74E-05 6.57E-05 . r~!~ ~ :mt :~i mi: E mi: .. tl!!;i 27.6 1.47 3,9T~~I "~2:60~ 11722.6 9,591 0.05 15,606.0 1.83 0.15 22398.4 100289.8 95056.0 ~-··· ...... 11.61 23.15 0.94 1.88 1.17 0.10