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HomeMy WebLinkAboutDRC-2023-074830 - 0901a068812a688fOctober 25 , 2023 Div of Waste Managoment and Radiation Control OCT 2 7 2023 VIA PDF AND OVERNIGHT DELIVERY Doug Hansen Director Division of Waste Management and Radiation Control State of Utah Department of Environmental Quality 195 North 1950 West Salt Lake City, UT 84116 Energy Fuels Resources (USA) Inc. 225 Union Blvd. Suite 600 Lakewood, CO, US, 80228 303 974 2140 www .energyfuels.com Re: State of Utah Ground Water Discharge Permit No. UGW370004 White Mesa Uranium Mill-Notice Pursuant to Part I.G.1 (a) Dear Mr. Hansen: The White Mesa Mill (the "Mill") performed third quarter ("Q3") groundwater monitoring during the period from July 1, to September 30, 2023 under the March 8, 2021 version of the Mill's Groundwater Discharge Permit (the "GWDP"). All analytical data needed for comparison to the GWCLs were received during the period ending September 25 , 2023 . Pursuant to Part LG. I.a) of the GWDP, please take notice that the concentrations of specific constituents in the monitoring wells highlighted in yellow and bold italics in the columns for this quarter in the attached Table 1 exceeded their respective GWCLs. For ease ofreview, Table 1 has been formatted to simplify the tracking of any continued exceedances from one monitoring period to the next by charting ongoing monitoring of the same well in the same row, and by highlighting exceedances (in color and bold italics). As a result of the issuance of a revised GWDP on March 8, 2021 , which sets revised GWCLs, requirements to perform accelerated monitoring for certain constituents under Part LG.I of the previous GWDP ceased effective on March 8, 2021 , and the effect of the issuance of the revised GWDP was to create a "clean slate" for certain constituents going forward. Part LG. I c) of the GWDP states "that the Permittee shall prepare and submit within 30 calendar days to the Director a plan and a time schedule for assessment of the sources, extent and potential dispersion of the contamination, and an evaluation of potential remedial action to restore and maintain groundwater quality to ensure that Permit limits will not be exceeded at the compliance monitoring point and that DMT or BAT will be reestablished." The summary below relating to exceedances includes, for each exceedance, a brief discussion of whether such a plan and schedule is or is not required or appropriate at this time in light of other actions currently being undertaken by Energy Fuels Resources (USA) Inc. ("EFRI") or in light of other reports submitted by EFRI, DRC-2023-074830 Letter to Mr. Doug Hansen October 25, 2023 Page2 and as determined by Division of Waste Management and Radiation Control ("DWMRC") Staff. A description of the other actions and reports which have affected the requirement to submit a plan and time schedule are as follows: 1. Nitrate + nitrite and chloride in monitoring wells at the site have been the subject of ongoing investigations at the Mill. Based on the results of the previous investigations, EFRI and the Director acknowledged that it has not been possible to date to determine the source( s ), cause( s ), attribution, magnitudes of contribution, and proportion( s) of the local nitrate + nitrite and chloride in groundwater. EFRI submitted a Corrective Action Plan ("CAP") in February 2012 for nitrate+ nitrite and chloride in groundwater. The CAP was approved on December 12, 2012 and the activities associated with the CAP are on-going. Based on information provided by DWMRC in teleconferences on April 27, and May 2, 2011, due to the ongoing activities and actions, the 30-day plan and schedule for assessment is not required for nitrate + nitrite and chloride exceedances at this time. 2. A Plan and Time Schedule will not be prepared for monitoring wells with two successive exceedances if those successive exceedances were reported in a previous quarter and/or were included in a previous Source Assessment Report ("SAR") during the current permit period beginning March 8, 2021. Inclusion in a previous SAR means that the GWCLs were modified based on conclusions and actions delineated in the previous SAR which were accepted by DWMRC. 3. Chloroform and methylene chloride are the subject of the ongoing chloroform pumping program and are covered by State of Utah Notice of Violation ("NOV") and Groundwater Corrective Action Order ("CAO") State of Utah Department of Environmental Quality ("UDEQ") Docket No. UGW-20-01. As a result, the 30-day plan and schedule for assessment of chloroform and methylene chloride exceedances is not required. It is important to note that under the GWDP, GWCLs have been determined on a well-by-well basis to reflect background groundwater quality, as defined by the mean plus second standard deviation concentration, or the equivalent. Accordingly, the GWDP requires that constituent concentrations in each monitoring well shall not exceed the GWCLs set out in Table 2 of the GWDP. It should be noted that, because the GWCLs have been set at the mean plus second standard deviation, or the equivalent, un-impacted groundwater would normally be expected to exceed the GWCLs approximately 2.5% of the time. Therefore, exceedances are expected in approximately 2.5% of all sample results, and do not necessarily represent impacts to groundwater from Mill operations. In fact, more frequent sampling of a given analyte will increase the number of exceedances due to statistical variation and not due to Mill activity. Additionally, given the slow velocity of groundwater movement, accelerated sampling at a monthly frequency can result in resampling of essentially the same water and can lead to repeat exceedances for accelerated constituents not due to Mill activities, but due to repeat sampling of the same water. Letter to Mr. Doug Hansen October 25, 2023 Page 3 1.0 Exceedances in Required Quarterly Sampling Wells 1.1 Quarterly Wells with Two Successive Exceedances As indicated in the attached Table 1, the analytes discussed below exceeded their respective GWCLs for two successive sampling periods in Q3 2023. A 30-day plan and schedule contemplated in Part LG. I c) of the GWDP will not be required for quarterly wells as noted below. One-time exceedances and non-successive exceedances are noted on Table 1, but not listed below. Consecutive exceedances which occurred in previous reporting periods are discussed in previously submitted SARs. MW-11 • The chloride concentration exceeded its GWCL in all of the Q3 2023 sampling events. As mentioned above, a CAP has been submitted and approved to address nitrate+nitrite contamination which is expected to address chloride in groundwater. The actions specified in the CAP are currently being implemented; therefore, a plan to address this consecutive exceedance is not necessary and is not being submitted. • The nitrate concentration exceeded its GWCL in in all of the Q3 2023 sampling events. As mentioned above, a CAP has been submitted and approved to address nitrate+nitrite contamination which is expected to address chloride in groundwater. The actions specified in the CAP are currently being implemented; therefore, a plan to address this consecutive exceedance is not necessary and is not being submitted. • The selenium concentration exceeded its GWCL in all of the Q3 2023 sampling events. A plan and schedule for assessment was submitted to DWMRC on May 24, 2023. The plan and schedule was approved by DWMRC by letter dated June 29, 2023 and a SAR was submitted September 27, 2023. An additional plan to address this consecutive exceedance is not necessary and is not being submitted. • Sulfate has exceeded the GWCL for both the September 2023 and Q3 2023 sampling events. A SAR was submitted on March 7, 2022. As a result of the SAR, the GWCLs have been recalculated and accepted by DWMRC. The recalculated GWCLs will become effective upon their publication in the next revision of the GWDP. As a result of DWMRC's acceptance of the recalculated GWCLs, a plan and schedule to address this consecutive exceedance is not necessary and will not be submitted. Until such time as the new GWCLs become effective, the exceedances will continue to be noted and reported. • Manganese has exceeded the GWCL for both the June 2023 and Q3 2023 sampling events. A SAR was submitted on March 7, 2022. As a result of the SAR, the GWCLs have been recalculated and accepted by DWMRC. The recalculated GWCLs will become effective upon their publication in the next revision of the GWDP. As a result of DWMRC's acceptance of the recalculated GWCLs, a plan and schedule to address this consecutive exceedance is not necessary and will not be submitted. Until such time as the new GWCLs become effective, the exceedances will continue to be noted and reported. Letter to Mr. Doug Hansen October 25, 2023 Page4 MW-25 • The chloride concentration exceeded its GWCL in June 2023 and Q3 2023 sampling events. As mentioned above, a CAP has been submitted and approved to address nitrate+nitrite contamination which is expected to address chloride in groundwater. The actions specified in the CAP are currently being implemented; therefore, a plan to address this consecutive exceedance is not necessary and is not being submitted. MW-26 MW-26 Note: As stated in the September 2009 Statement of Basis (page 23) in support of the January 20, 2010 revisions to the GWDP, "[i]t should be noted that, because MW-26 is a pumping well for chloroform removal, concentrations of all constituents in that well are subject to potential variation over time as a result of the pumping activity. This will be taken into account by the Executive Secretary in determining compliance for this well." Based on information provided by DWMRC in teleconferences on April 27, and May 2, 2011, due to the current pumping status as part of the chloroform investigation program, the 30-day plan and schedule for assessment is not required at this time for exceedances of chloroform and methylene chloride in MW-26. • Chloroform has exceeded its GWCL in all of the Q3 2023 sampling events. MW-26 is used as a pumping well for the ongoing chloroform capture program and is expected to yield increased concentrations of chloroform. Because this well is used in the chloroform capture program which is the subject of separate investigations and actions, a plan and time schedule to address the consecutive exceedances is not necessary and is not being submitted. • The nitrate concentration exceeded its GWCL in the June 2023 and Q3 2023 sampling events. As mentioned above, a CAP has been submitted and approved to address nitrate+nitrite contamination which is expected to address chloride in groundwater. The actions specified in the CAP are currently being implemented; therefore, a plan to address this consecutive exceedance is not necessary and is not being submitted. • The chloride concentration exceeded its GWCL in June 2023 and Q3 2023 sampling events. As mentioned above, a CAP has been submitted and approved to address nitrate+nitrite contamination which is expected to address chloride in groundwater. The actions specified in the CAP are currently being implemented; therefore, a plan to address this consecutive exceedance is not necessary and is not being submitted. MW-30 • Nitrate + nitrite has exceeded its GWCL in all of the Q3 2023 sampling events. As mentioned above, a CAP has been submitted and approved and the specified actions are currently being implemented; therefore, a plan to address this consecutive exceedance is not necessary and is not being submitted. • The chloride concentration exceeded its GWCL in all of the Q3 2023 sampling events. As mentioned above, a CAP has been submitted and approved to address nitrate+nitrite Letter to Mr. Doug Hansen October 25, 2023 Page 5 contamination which is expected to address chloride in groundwater. The actions specified in the CAP are currently being implemented; therefore, a plan to address this consecutive exceedance is not necessary and is not being submitted. • Selenium has exceeded the GWCL for all of the Q3 2023 sampling events. A SAR was submitted on January 28, 2022. As a result of the SAR, the GWCLs have been recalculated and accepted by DWMRC. The recalculated GWCLs will become effective upon their publication in the next revision of the GWDP. As a result ofDWMRC's acceptance of the recalculated GWCLs, a plan and schedule to address this consecutive exceedance is not necessary and will not be submitted. Until such time as the new GWCLs become effective, the exceedances will continue to be noted and reported. • Uranium has exceeded the GWCL in the August and September 2023 sampling events. A SAR was submitted on January 28, 2022. As a result of the SAR, the GWCLs have been recalculated and accepted by DWMRC. The recalculated GWCLs will become effective upon their publication in the next revision of the GWDP. As a result of DWMRC's acceptance of the recalculated GWCLs, a plan and schedule to address this consecutive exceedance is not necessary and will not be submitted. Until such time as the new GWCLs become effective, the exceedances will continue to be noted and reported. MW-31 • Nitrate + nitrite has exceeded its GWCL in all of the Q3 2023 sampling events. As mentioned above, a CAP has been submitted and approved and the specified actions are currently being implemented; therefore, a plan to address this consecutive exceedance is not necessary and is not being submitted. • The sulfate concentration exceeded its GWCL in all of the Q3 2023 sampling events. A SAR was submitted to DWMRC on June 24, 2020. As a result of the SAR, the GWCLs have been recalculated and accepted by DWMRC. The recalculated GWCLs will become effective upon their publication in the next revision of the GWDP. As a result of DWMRC's acceptance of the recalculated GWCLs, a plan and schedule to address this consecutive exceedance is not necessary and will not be submitted. Until such time as the new GWCLs become effective, the exceedances will continue to be noted and reported. • The TDS concentration exceeded its GWCL in all of the Q3 2023 sampling events. A SAR was submitted to DWMRC on June 24, 2020. As a result of the SAR, the GWCLs have been recalculated and accepted by DWMRC. The recalculated GWCLs will become effective upon their publication in the next revision of the GWDP. As a result of DWMRC's acceptance of the recalculated GWCLs, a plan and schedule to address this consecutive exceedance is not necessary and will not be submitted. Until such time as the new GWCLs become effective, the exceedances will continue to be noted and reported. • The chloride concentration exceeded its GWCL in all of the Q3 2023 sampling events. As mentioned above, a CAP has been submitted and approved to address nitrate+nitrite contamination which is expected to address chloride in groundwater. The actions specified Letter to Mr. Doug Hansen October 25, 2023 Page 6 in the CAP are currently being implemented; therefore, a plan to address this consecutive exceedance is not necessary and is not being submitted. • Uranium concentrations exceeded the GWCL in all of the Q3 2023 sampling events. A SAR was submitted to DWMRC on April 29, 2021. As a result of the SAR, the GWCLs have been recalculated and accepted by DWMRC. The recalculated GWCLs will become effective upon their publication in the next revision of the GWDP. As a result of DWMRC's acceptance of the recalculated GWCLs, a plan and schedule to address this consecutive exceedance is not necessary and will not be submitted. Until such time as the new GWCLs become effective, the exceedances will continue to be noted and reported. 1.2 Quarterly Wells with New Exceedances Reported in Q3 There are no new exceedances for the Q3 2023 quarterly well sampling program. 2.0 Exceedances in Semiannual Sampling Wells Accelerated to Quarterly 2.1 Semi-annual Wells with Two Successive Exceedances As indicated in the attached Table 1, the analytes discussed below exceeded their respective GWCLs for two successive sampling periods (Q2 2023 and Q3 2023). MW-03A • The selenium concentration exceeded its GWCL in the Q2 and Q3 2023 sampling events. This is the first consecutive exceedance for selenium in MW-03A. Therefore, a plan and schedule for assessment will be submitted under separate cover within 30 days of this Exceedance Notice. MW-24 Beryllium, cadmium, fluoride, nickel, thallium, and field pH exceeded their GWCLs in MW-24 in the Q2 2023 and Q3 2023 sampling events. The exceedances noted above are addressed in the SAR dated June 27, 2019. As a result of the SAR, EFRI installed a collocated well to study potential installation issues associated with MW- 24. DWMRC approved the collocated well strategy by letter dated September 5, 2019. In response to the previously identified exceedances and increasing trends, in 2020 EFRI voluntarily completed a study of MW-24A (collocated with MW-24) to determine what geochemical and hydrogeological influences are present which may be impacting monitoring data collected at these two wells and potentially other wells across the Mill site. The MW-24A study and report included several additional field data collection and analytical activities based on the conclusions of other Mill reports. The results of the analytical and test data collected during the MW-24A study demonstrated that natural processes unrelated to disposal of materials in the Tailings Management System can account for the behavior of all trace metals of concern, as well as fluoride, in groundwater at MW- 24 and MW-24A. Bottle-roll test results indicated that naturally-occurring trace metals can be mobilized at concentrations similar to or greater than in groundwater even without a large pH Letter to Mr. Doug Hansen October 25, 2023 Page 7 decrease, suggesting that agitation alone, such as would occur during routine purging and sampling of low permeability wells such as MW-24A, could result in metals mobilization. Based on the results of the MW-24A study EFRI has voluntarily agreed to implement a MW-24A Phase 2 study to determine what geochemical and hydrogeological influences are present that may be affecting monitoring data collected at other wells across the Mill site. EFRI coordinated the Phase 2 study efforts with DWMRC. DWMRC approved the Phase 2 study plan by letter dated June 16, 2022. The Phase 2 study will build on the results of the previous study and will supplement the data using eight other Mill site locations. As a result of DWMRC's acceptance of the study strategy, a plan and schedule to address these consecutive exceedances is not necessary and will not be submitted. Until such time as the study is complete, the exceedances will continue to be noted and reported. MW-28 • Chloride has exceeded the GWCL for both the Q2 2023 and Q3 2023 sampling events and during previous quarters. As mentioned above, a CAP has been submitted and approved and the specified actions are currently being implemented; therefore, a plan to address this consecutive exceedance is not necessary and is not being submitted. • Uranium has exceeded the GWCL for both the Q2 2023 and Q3 2023 sampling events. A SAR was submitted to DWMRC on October 19, 2020. As a result of the SAR, the GWCLs have been recalculated and accepted by DWMRC. The recalculated GWCLs will become effective upon their publication in the next revision of the GWDP. As a result of DWMRC's acceptance of the recalculated GWCLs, a plan and schedule to address this consecutive exceedance is not necessary and will not be submitted. Until such time as the new GWCLs become effective, the exceedances will continue to be noted and reported. • Selenium has exceeded the GWCL for both the Q2 2023 and Q3 2023 sampling events. A SAR was submitted to DWMRC on October 19, 2020. As a result of the SAR, the GWCLs have been recalculated and accepted by DWMRC. The recalculated GWCLs will become effective upon their publication in the next revision of the GWDP. As a result of DWMRC's acceptance of the recalculated GWCLs, a plan and schedule to address this consecutive exceedance is not necessary and will not be submitted. Until such time as the new GWCLs become effective, the exceedances will continue to be noted and reported. MW-32 • The chloride concentration exceeded its GWCL in Q2 2023 and Q3 2023 sampling events. As mentioned above, a CAP has been submitted and approved to address chloride in groundwater. The actions specified in the CAP are currently being implemented; therefore, a plan to address this consecutive exceedance is not necessary and is not being submitted. Letter to Mr. Doug Hansen October 25, 2023 Page 8 2.2 Semi-annual Wells with New Exceedances Reported in Q3 There are no new single exceedances for the Q3 2023 semi-annual well sampling program. Yours truly, r(~){r;.uJ ENERGY FUELS RESOURCES (USA) INC. Kathy Weinel Director, Regulatory Compliance cc: Scott Bakken, David Frydenlund, Logan Shumway, Garrin Palmer, Jordan App, Tanner Holliday Monitoring Well (Water Constituent Exceeding GWCL Class) Nitrate+ Nitrite (as N) (mg/L) Chloride (mg/L) MW-II Manganese (ug/L) (Class Il) Sulfate (mg/L) TDS (mg/L) Selenium (ug/L) MW-25 (Class Chloride (mg/L) [JJ) MW-26 Nitrate+ Nitrite (as N) (mg/L) (Class III) Chloroform (ug/L) Chl oride (mg/L) Nitrate+ Nitrite (as N) (mg/L) MW-30 Chloride (mg/L) (Class 11) Selenium (ug/L) Field pH (SU) Uranium (ug/L) Nitrate+ Nitrite (as N) (mg/L) MW-31 Sulfate (mg/L) (Class III) TDS (mg/L) Uranium (ug/L) Chloride (mg/L) MW-03A Selenium (ug/L) (Class Ill) MW-05 (Class Uranium (ug/L) II) MW-17 Chloride (mg/L) (Class III) Beryllium (ug/L) Cadmium (ug/L) Fluoride (mg/L) Nickel (mg/L) MW-24 Manganese ( ug/L) (Class lll) Thallium (ug/L) Gross Alpha (pCi/L) Sulfate (mg/L) TDS (mg/L) Field pH (S.U) MW-27 Nitrate+ Nitrite (as N) (mg/L) (Class III) Fluoride (mg/L) Chloride (mg/L) MW-28 Selenium (ug/L) (Class III) Nitrate + Nitrite (as N) (mg/L) TDS (mg/L) Uranium (ug/L) MW-29 Uranium (ug/L) (Class III) MW-32 Chloride (mg/L) (Class III) MW-37 Field pH (S.U.) (Class [II) Notes: NS= Not Required and Not Sampled NA= Not Applicable Exceedances are shown in yellow I GWCLin March 8, 2021 GWDP 2.5 39.16 237 1309 2528 12.5 35 0.62 70 58.31 2.5 128 53.6 6.47 -8.5 9.82 5 993 2132 15 143 109.58 7.5 46.8 2 6.43 0.47 50 7507 2.0 1 7.5 2903 4450 5.03 -8.5 5.6 0.85 105 111 5 3852 4.9 15 35.39 6.61 -8.5 Ql 2021 Results February February March Ql 2021 Qt 2021 2021 2021 2021 Sample Monthly Monthly Date Result Sample Monthly Sample Date Result Date Required Quarterly Sampling Wells 1.21 NA 46.4 46.4 1/12/21 185 2/9/21 254 3/8/21 1140 1260 2010 2 160 <5 NA 1/11/21 34 NS NA NS 0.6 19 0.764 1/14/21 2200 2/10/21 1930 3/9/21 57.4 71.3 17.7 14.3 184 189 1/1 1/21 55.6 2/10/21 55.3 3/9/21 7.49 7.25 9.86 11.6 17. I 14.3 1070 1130 1/12/21 2460 2/9/21 2960 3/8/21 /9. 7 22.2 354 380 Required Semiannual Sampling Wells NS NA NS NA NS NS NA NS NA NS NS NA NS NA NS 2.75 NA 8.79 NA 0.916 NA 70.4 NA 7460 NA 1/14/21 2. 74 NS NA NS 2.94 NA 2980 NA 4260 NA 5.08 NA 5. 16 1/1 4/21 NS NA NS NA 128 NA 14.0 NA 1/15/21 3.44 NS NA NS NA NA 10.3 NA 1/15/21 16.9 NS NA NS 1/14/21 36.9 NS NA NS NS NA NS NA NS Table I -GWCL Exceedances under the March 8, 2021 GWDP Q2 2021 Results March May 2021 June 2021 2021 Q2 2021 Q2 2021 Monthly May 2021 Monthly June 2021 Q3 2021 Sample Monthly Monthly Sample Monthly Date Result Sample Result Sample Result Date Result Date Date Required Quarterly Sampling Wells NA 0.948 NA NA 46.9 47.7 46.4 52.l 221 04/20/21 237 5/10/21 NA 6/8/21 NA 7/27/21 1270 1290 1280 1270 1950 2110 2190 1960 NA <5 NA NA NA 04/14/21 34.8 NS NA NS NA 7//8/21 0.617 1.42 1.06 0.368 2190 04/21 /21 777 5/11/21 733 6/8/21 1590 7/28/21 63.9 57.5 69.6 54.9 17.0 17.7 18.6 17.0 192 162 188 170 56.3 04/14/21 55.7 5/11/21 58.3 6/8/21 54.l 7/29/21 7.14 7.20 720 7.36 10.2 /0.3 10. 7 9.84 17.4 /8.6 18.9 20.6 1210 1170 1200 1170 2400 04/13/21 2300 5/10/21 2610 6/7/21 2400 7/27/21 20.2 20.1 21. 7 20.8 388 377 384 374 Required Semiannual Sampling Wells NA 4/27/21 74.0 NS NA NS NA NS NA 4/20/21 0.599 NS NA NS NA NS NA 4/26/21 32.6 NS NA NS NA NS NA 2.78 NA NA NA 8.08 NA NA NA 0.925 NA NA NA 72.4 NA NA NA 7540 NA NA NA 4/29/21 3.02 NS NA NS NA 7/29/21 NA 3.18 NA NA NA 2960 NA NA NA 4460 NA NA NA 5.00 NA NA 6.57 NA 4/15/21 NS NA NS NA 7/22/2 I 0.69 NA 144 NA NA NA 13.4 NA NA NA 4/15/21 4.09 NS NA NS NA 7/23/2 I NA 3740 NA NA NA 8.52 NA NA NA 4/14/21 16.2 NS NA NS NA 7/22/21 NA 4/13/2 I 31.8 NS NA NS NA 7/28/21 NA 5/12/21 7.00 NS NA NS NA NS [These GWCLs were reset with the issuance of the March 8, 2021 GWDP. The new GWCLs became effective on March 8, 2021 and the first exceedance under the revised GWDP was noted in the March monthly data. Q3 2021 Results Q4 2021 Results August August September September November November December December Q3 2021 2021 2021 2021 2021 Q4 2021 Q4 2021 2021 2021 2021 2021 Monthly Sample Result Sample Monthly Monthly Monthly Date Result Monthly Monthly Monthly Monthly Date Result Sample Date Result Sample Date Result Sample Date Result Required Quarterly Sampling Wells Required Quarterly Sampling Wells 0.924 NA NA 1.5 NA NA 48.3 57.0 49.6 52.8 53.6 53.9 376 8/10/21 NA 9/7/21 NA 10/20/21 286 11/16/21 261 12/13/21 300 1470 1370 1240 1360 1300 1350 2680 NA NA 2200 2230 2140 <5 NA NA 6.75 NA NA 34.2 NS NA NS NA 10/21/21 33.1 NS NA NS NA 0.352 1.42 0.710 0.928 1.18 1. 76 723 8/10/21 996 9/9/21 516 10/21/21 540 11/16/21 568 12/15/21 1160 54.0 61.4 59.3 55.2 56.9 75.9 20.6 16.5 15.4 14.3 18.0 18.6 /88 161 183 182 182 184 56.3 8/9/21 56.1 9/8/21 60.4 10/19/21 54.6 11/17/21 53.6 12/14/21 58.8 6.98 6.84 6.70 6.77 7. 18 7.04 9.60 9.38 9.74 9.76 9.67 10.1 18. 7 15.7 16.0 /8. l 19.3 17.9 1210 1130 1130 /220 1180 1220 3100 8/9/21 2600 9/7/21 2870 I 0/19/21 2600 11/15/21 2610 12/13/21 2420 20.0 /9.3 20.2 20.9 21.5 21.8 391 365 356 371 366 376 Required Semiannual Sampling Wells Required Semiannual Sampling Wells NA NS NA NS NA 11/10/21 75.5 NS NA NS NA NA NS NA NS NA 10/26/21 0.446 NS NA NS NA NA NS NA NS NA 11/8/21 33.4 NS NA NS NA 2.71 NA NA 2.66 NA NA 9.26 NA NA 9.30 NA NA 1.4 NA NA 0.988 NA NA 76. 7 NA NA 76. 7 NA NA 7890 NA NA 7430 NA NA 2.91 NS NA NS NA 11/10/21 3.14 NS NA NS NA 1.92 NA NA 1.56 NA NA 3050 NA NA 3220 NA NA 4940 NA NA 4730 NA NA 5.85 NA NA 5.23 NA NA 6.32 3.88 NS NA NS NA 10/26/21 NS NA NS NA NA 0.65 152 NA NA 147 NA NA 18.5 NA NA . 11.2 NA NA 6.09 NS NA NS NA 10/26/21 1.89 NS NA NS NA NA NA NA 3570 NA NA 13.80 NA NA 6.03 NA NA 15.8 NS NA NS NA 10/27/21 14.9 NS NA NS NA 36.5 NS NA NS NA 11/2/2 I 36. l NS NA NS NA NA NS NA NS NA 11/17/21 7.06 NS NA NS NA Table 1-GWCL Exceedances under the March 8, 2021 GWDP QI 2022 Results Q2 2022 Results Q3 2022 Results Q4 2022 Results February February March 2022 March May 2022 June 2022 August August September September November November December December Monitoring GWCLin QI 2022 2022 Q2 2022 May 2022 June 2022 Q3 2022 2022 Q4 2022 Well (Water Constituent Exceeding GWCL March 8, 2021 Sample QI 2022 Monthly 2022 Monthly 2022 Sample Q2 2022 Monthly Monthly Monthly Monthly Sample Q3 2022 Monthly 2022 2022 2022 Sample Q4 2022 2022 2022 2022 2022 Class) GWDP Date Result Sample Monthly Sample Monthly Date Result Sample Result Sample Result Date Result Sample Monthly Monthly Monthly Date Result Monthly Monthly Monthly Monthly Date Result Date Result Date Date Date Result Sample Date Result Sample Date Result Sample Date Result Required Quarterly Sampling Wells Required Quarterly Sampling Wells Required Quarterly Sampling Wells Required Quarterly Sampling Wells Nitrate+ Nitrite (as N) (mg/L) 2.5 2.55 NA NA 2.2 1.6 1.9 2.12 2.45 2.65 2.90 2.74 1.30 Chloride (mg/L) 39.16 51./ 57.2 67.7 54.9 59.5 46.4 54.0 67.4 68.I 72.I 71.9 52.3 MW-11 Manganese (ug/L) 237 1/18/22 156 2/8/22 233 3/8/22 224 180 254 228 297 201 212 2 14 220 273 (Class 11) 4/18/22 5/4/22 6/6/22 7/12/22 8/8/22 9/2 1/22 I 0/10/22 11/8/22 12/14/22 Sulfate (mg/L) 1309 1020 1240 1170 1240 1270 866 1390 1260 1300 1140 1140 1330 TDS (mg/L) 2528 2050 1900 2080 2060 2290 2360 2520 3230 2280 2570 2270 2370 Selenium (ug/L) 12.5 9.29 NA NA 10.8 NA NA 9.3 NA NA 15.5 NA NA MW-25 (Class Chloride (mg/L) 35 1/7/22 34.1 NS NA NS NA 4/12/22 33.4 NS NA NS NA 7/13/22 22.4 NS NA NS NA 10/10/22 35.8 NS NA NS NA lIJ) MW-26 Nitrate + Nitrite (as N) (mg/L) 0.62 0.601 0.367 0.600 0.8 I.I 0.60 /.63 1.56 0.491 0.632 0.408 2.66 (Class Ill) Chloroform (ug/L) 70 1/20/22 818 2/9/22 1580 3/8/22 1460 4/20/22 447 5/4/22 6/6 6/7/22 1250 7/14/22 <1.0 8/9/22 1120 9/20/22 810 I 0/13/22 749 11/10/22 512 12/15/22 460 Chloride ( mg/L) 58.31 77.I 58.6 64./ 56.8 63.2 47.4 61.0 65.0 62. I 65.5 59.2 60.6 Nitrate+ Nitrite (as N) (mg/L) 2.5 14.5 13.6 /6.6 17 15 J/.0 17.6 13.5 16.5 17.9 15.9 16./ MW-30 Chloride (mg/L) 128 181 184 196 173 195 126 108 185 182 /96 156 195 (Class II) Selenium (ug/L) 53.6 1/17/22 56.7 2/9/22 57. 7 3/7/22 62.0 4/20/22 64.9 5/4/22 69.4 6/7/22 65.7 7/13/22 61. I 8/9/22 64.3 9/20/22 70.0 I 0/13/22 65./ I l/9/22 75.6 12/13/22 70.8 Field pH (S U) 6.47 -8.5 7.62 720 7.12 6.92 7.24 7.32 7.33 7.33 6.81 6.84 6.37 6.59 Uranium (ug/L) 9.82 IO. I /0.3 9.9 9.6 IO. I 9.6 10.0 JO.I 8.3 9.8 IO. I 13.0 Nitrate + Nitrite (as N) (mg/L) 5 18.0 /3.5 17.0 18.0 13.0 13.0 16.9 /6.8 17.1 17.0 16.0 12.6 MW-31 Sulfate (mg/L) 993 1210 1250 731 1180 1220 1110 1260 1230 /200 972 1380 1280 (Class III) TDS (mg/L) 2132 1/19/22 2620 2/8/22 2680 3/7/22 2530 4/11/22 4300 5/3/22 2660 6/6/22 2690 7/12/22 2700 8/8/22 2700 9/20/22 2830 10/11/22 2720 11/8/22 2670 12/13/22 2700 Uranium (ug/L) 15 21. 7 22./ 22.5 22.0 22.9 21.5 22.6 22.7 18.8 23.3 24.5 26.2 Chloride (mg/L) 143 370 379 416 372 38/ 351 421 396 390 397 243 335 Required Semiannual Sampling Wells Required Semiannual Sampling Wells Required Semiannual Sampling Wells Required Semiannual Sampling Wells MW-03A Selenium (ug/L) 109.58 NS NA NS NA NS NA 4/27/22 87.4 NS NA (Class III) NS NA NS NA NS NA NS NA 10/19/22 97.5 NS NA NS NA MW-05 (Class Uranium (ug/L) 7.5 NS NA NS NA NS NA 4/18/22 0.5 NS NA NS NA NS NA NS NA NS NA 10/12/22 0.4 NS NA NS NA II) MW-17 Chloride (mg/L) 46.8 NS NA NS NA NS NA 4/18/22 31.5 NS NA (Class III) NS NA NS NA NS NA NS NA I 0/17/22 54.0 NS NA NS NA Beryll ium (ug/L) 2 2. 71 NA NA 2.5 NA NA 2.7 NA NA 3.3 NA NA Cadmium (ug/L) 6.43 8.46 NA NA 9.20 NA NA 8.6 NA NA 10.9 NA NA Fluoride (mg/L) 0.47 I NA NA 0.8 NA NA 0.760 NA NA 1.53 NA NA Nickel (mg/L) 50 80.9 NA NA 74.3 NA NA 69.9 NA NA 86.9 NA NA MW-24 Manganese (ug/L) 7507 7630 NA NA 7070 NA NA 7/20/22 7540 NA NA 8/30 NA NA (Class Ill) Thallium (ug/L) 2.01 1/27/22 2.66 NS NA NS NA 4/27/22 3./ NS NA NS NA 7/28/22 3.0 NS NA NS NA 11 /2/22 3.5 NS NA NS NA Gross Aloha (oCi/L) 7.5 2.26 NA NA 2.28 NA NA 2.55 NA NA 2.70 NA NA Sulfate (mg/L) 2903 3060 NA NA 3120 NA NA 2800 NA NA 2680 NA NA TDS (mg/L) 4450 4140 NA NA 3350 NA NA 4200 NA NA 4440 NA NA Field pH (S.U.) 5.03 -8.5 5.31 NA NA 4.81 NA NA 4.89 NA NA 4.39 NA NA 4.80 MW-27 Nitrate + Nitrite (as N) (mg/L) 5.6 6.25 6.30 5.18 5.26 (Class Ill) 1/18/22 NS NA NS NA 4/12/22 NS NA NS NA 7/15/22 NS NA NS NA 10/19/22 NS NA NS NA Fluoride (mg/L) 0.85 NA 0.90 0.530 0.722 Chloride (mg/L) 105 140 NA NA 130 NA NA 159 NA NA /61 NA NA MW-28 Selenium (ug/L) 11.1 13.3 NA NA 19.8 NA NA 20.8 NA NA 23.7 NA NA (Class III) Nitrate+ Nitrite (as N) (mg/L) 5 1/20/22 4 03 NS NA NS NA 4/19/22 5.1 NS NA NS NA 7/15/22 5.16 NS NA NS NA 10/12/22 5.69 NS NA NS NA TDS (mg/L) 3852 NA NA NA 3320 NA NA NA NA NA 3550 NA NA Uranium (ug/L) 4.9 8.50 NA NA IO. IO NA NA 12.4 NA NA 12.5 NA NA MW-29 Uranium (ug/L) 15 1/18/22 15. I NS (Class III) NA NS NA 4/14/22 15. 7 NS NA NS NA 7/14/22 15. I NS NA NS NA 10/12/22 15.2 NS NA NS NA MW-32 Chloride ( mg/L) 35.39 1/19/22 35.0 NS NA NS NA 4/11/22 28.6 NS NA (Class Ill) NS NA 7/15/22 28.2 NS NA NS NA 10/1 1/22 37.I NS NA NS NA MW-37 Field pH (S.U.) 6.61 -8.5 NS NA NS NA NS NA 5/17/22 7 04 NS NA (Class [II) NS NA NS NA NS NA NS NA 11/1/22 6.60 NS NA NS NA . . Table I -GWCL Exceedances under the March 8, 2021 GWDP QI 2023 Results February February March 2023 Monitoring GWCLin QI 2023 2023 Well (Water Constituent Exceeding GWCL March 8, 2021 Sample QI 2023 Monthly 2023 Monthly Class) GWDP Date Result Sample Monthly Sample Date Result Date Required Quarterly Sampling Wells Nitrate+ Nitrite (as N) (mg/L) 2.5 3.49 2.89 Chloride (mg/L) 39.16 70. 7 71.4 MW-II Manganese ( ug/L) 237 193 161 (Class II) 1/25/23 2/8/23 3/14/23 Sulfate (mg/L) 1309 1240 1100 TDS (mg/L) 2528 2390 2120 Selenium (ug/L) 12.5 17.5 17. 7 MW-25 (Class Chloride (mg/L) 35 1/23/23 32.4 2/7/23 32.2 3/15/23 Ill) MW-26 Nitrate + Nitrite (as N) (mg/L) 0.62 1.82 /.94 (Class Ill) Chloroform (ug/L) 70 1/26/23 709 2/8/23 664 3/14/23 Chloride ( mg/L) 58.31 51.5 52.2 Nitrate + Nitrite (as N) (mg/L) 2.5 18./ 15.9 MW-30 Chloride (mg/L) 128 166 173 (Class II) Selenium (ug/L) 53.6 1/25/23 68.8 2/8/23 70.6 3/1 5/23 Field pH (S.U.) 6.47 -8.5 7.01 6.77 Uranium (ug/L) 9.82 10.8 9.6 Nitrate + Nitrite (as N) (mg/L) 5 18. 7 16.5 MW-31 Sulfate (mg/L) 993 1230 I 190 (Class Ill) TDS (mg/L) 2132 1/24/23 2740 217/23 2730 3/14/23 Uranium (ug/L) 15 25.4 23.3 Chloride (mg/L) 143 333 388 Required Semiannual Sampling Wells MW-03A Selenium (ug/L) 109.58 NS NA NS NA NS (Class 111) MW-05 (Class Uranium (ug/L) 7.5 NS NA NS NA NS II) MW-17 Chloride (mg/L) 46.8 1/30/23 26.5 NS NA NS (Class III) Beryllium (ug/L) 2 2.4 NA Cadmium (ug/L) 6.43 9.2 NA Fluoride (mg/L) 0.47 0.699 NA Nickel (mg/L) 50 72.5 NA MW-24 Manganese (ug/L) 7507 7000 NA (Class Ill) Thallium (ug/L) 2.01 1/31 /23 2.9 NS NA NS Gross Alpha (pCi/L) 7.5 2.27 NA Sulfate (mg/L) 2903 2720 NA TDS (mg/L) 4450 4220 NA Field pH (SU) 5.03 -8.5 4.76 NA MW-27 Nitrate + Nitrite (as N) (mg/L) 5.6 5.25 (Class Ill) 1/27/23 NS NA NS Fluoride (mg/L) 0.85 0.685 Chloride ( mg/L) 105 /40 NA MW-28 Selenium (ug/L) I LI <5.0 NA (Class lll) Nitrate + Nitrite (as N) (mg/L) 5 1/27/23 4.57 NS NA NS TDS (mg/L) 3852 NA NA Uranium (ug/L) 4.9 15.5 NA MW-29 Uranium (ug/L) 15 1/27/23 9.7 NS NA NS (Class Ill) MW-32 Chloride (mg/L) 35.39 1/30/23 27.9 NS NA NS (Class III) MW-37 Field pH (S U) 6.61-8.5 2/9/23 6.55 NS NA NS (Class Ill) Pursuant to the DWM RC letter of August 22, 2023, these constituents will no longer be monitored ori ari acc:eleratedscfiedule. These constituents will be dropped from this report after this quarter. Q2 2023 Results March May 2023 June 2023 Q2 2023 May 2023 2023 Sample Q2 2023 Monthly Monthly Monthly Monthly Date Result Sample Result Sample Result Date Date Required Quarterly Sampling Wells 2.53 2.98 2.64 66.3 70.6 66.0 211 4/17/23 224 5/9/23 233 6/5/23 1430 1330 1230 2300 2450 2320 14.9 14.2 16.8 32.6 4/19/23 35.8 5/10/23 34.9 6/6/23 0.875 0.671 0.945 1060 4/27/23 650 5/10/23 512 6/6/23 47.7 64.4 64.4 17.3 15.9 15.3 199 202 181 72.I 4/26/23 65.l 5/10/23 70.9 616123 7.15 6.94 6.96 9.6 9.5 10.5 17.9 14.3 15.4 951 1350 12 70 2520 4/24/23 2670 519/23 2570 6/5/23 23.7 24.0 25.2 302 297 388 Required Semiannual Sampling Wells NA 4/27/23 112.0 NS NA NS NA 4/1 9/23 26.3 NS NA NS NA 4/25/23 27.9 NS NA NS NA 2.6 NA NA 9.4 NA NA 0.597 NA NA 72. 7 NA NA 7030 NA NA 5/2/23 3./ NS NA NS NA 3.15 NA NA 2720 NA NA 4020 NA NA 4.94 NA 5.32 NA 4/1 8/23 NS NA NS 0.613 NA 155 NA NA 22.8 NA NA 4/18/23 4.82 NS NA NS NA 3870 NA NA 11.8 NA NA 4/19/23 15.3 NS NA NS NA 4/25/23 36.1 NS NA NS NA 5/11/23 6.94 NS NA NS Q3 2023 Results August 2023 September September June 2023 Q3 2023 August2023 Monthly Sample Q3 2023 Monthly Monthly 2023 2023 Result Date Result Sample Result Monthly Monthly Date Sample Date Result Required Quarterly Sampling Wells 2.86 3.22 4.30 4.10 69.0 77./ 87.2 80.3 283 7/11/23 238 8/2/23 149 9/5/23 233 1340 1370 1190 1330 2160 2350 2080 NA 15.3 17.1 22.0 21./ 35.2 7/11/23 36.7 8/1/23 33 .7 9/6/23 33.1 1.430 0.726 0.383 1.530 426 7/13/23 2190 8/2/23 777 9/6/23 475 60.0 68.0 52.5 55 .5 16.I 16.6 17.4 17.1 203 205 204 186 71.4 7/11/23 70. 7 8/2/23 70.8 9/5/23 73.0 7.13 6.89 7.16 6.93 11.0 9.5 10.3 11.4 16.4 16.6 17.5 16.8 1290 1290 1290 1220 2610 7/10/23 2780 8/1/23 2630 9/6/23 2940 26.7 23.4 25.8 27.1 397 429 404 417 Required Semiannual Sampling Wells NA 7/12/23 171 NS NA NS NA NA 7/13/23 5.5 NS NA NS NA NA 7/13/23 33.1 NS NA NS NA NA 2.4 NA NA NA 9.4 NA NA NA 0.544 NA NA NA 70.1 NA NA NA 7300 NA NA NA 7/12/23 2.8 NS NA NS NA NA 360 NA NA NA 2810 NA NA NA 4180 NA NA NA 4.96 NA NA 5.24 NA 7/13/23 NS NA NS NA 0.561 NA 150 NA NA NA 23.5 NA NA NA 7/13/23 5.41 NS NA NS NA NA 3840 NA NA NA 11.2 NA NA NA 7/12/23 14.1 NS NA NS NA NA 7/10/23 38.4 NS NA NS NA NA 7/17/23 7 02 NS NA NS NA