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HomeMy WebLinkAboutDRC-2023-076494 - 0901a068812bba68November 15, 2023 Div of Waste Management and Radiation Control NOV 1 7 2023 Sent VIA E-MAIL AND EXPRESS DELIVERY Doug Hansen Director Division of Waste Management and Radiation Control State of Utah Department of Environmental Quality 195 North 1950 West Salt Lake City, UT 84116 Energy Fuels Resources (USA) Inc. 225 Union Blvd. Suite 600 Lakewood, CO, US, 80228 303 974 2140 www .energyfuels.com Re: Transmittal of Plan and Time Schedule under Utah Ground Water Discharge Permit UGW370004 Part I.G.4 (c) White Mesa Mill (the "Mill") Dear Mr. Hansen: This letter transmits Energy Fuels Resources (USA) Inc. 's ("EFRl's") Plan and Time Schedule pursuant to State of Utah Groundwater Discharge Permit UGW370004 (the "Pennit") Part I.G.4(c) for MW-03A for the third quarter of 2023. Part I.G.2 of the Permit provides that out-of-compliance ("OOC") status exists when the concentration of a pollutant in two consecutive samples from a compliance monitoring point exceeds a groundwater compliance limit ("GWCL"). While consecutive exceedance have been noted in other wells at the site, a plan and time schedule have not been required or appropriate in light of other actions currently being undertaken by EFRI or in light of other reports submitted by EFRI. This Plan covers selenium in MW-03A that was identified as being in violation of Part I.G.2 of the Penn it, in the Thirdt Quarter 2023 Exceedance Notice, dated October 25, 2023. Please contact me if you have any questions or require any further infonnation. Yours very truly, ENERGY FUELS RESOURCES (USA) INC. -f{~)y~ Kathy Weinel Director, Regulatory Compliance cc: Jordan App Scott Bakken David Frydenlund Garrin Palmer Logan Shumway Angie Persico (lntera) Stewart Smith (HGC) DRC-2023-076494 WHITE MESA MILL State of Utah Ground Water Discharge Permit UGW370004 Plan and Time Schedule Under Part I.G.4 (c) For Exceedance in MW-03A in the Third Quarter of2023 Energy Fuels Resources (USA) Inc. 225 Union Boulevard, Suite 600 Lakewood, CO 80228 November 15, 2023 1. INTRODUCTION Energy Fuels Resources (USA) Inc. ("EFRI") operates the White Mesa Uranium Mill (the "Mill"), located near Blanding Utah, under State of Utah Ground Water Discharge Permit UGW370004 (the "Permit"). This is the plan and time schedule (the "Plan") required under Part I.G.4(c) of the Permit relating to violations of Part I.G.2 of the Permit for the MW-03A for the third quarter of 2023. Part I.G.2 of the Permit provides that out-of-compliance status exists when the concentration of a pollutant in two consecutive samples from a compliance monitoring point exceeds a groundwater compliance limit ("GWCL") in Table 2 of the Permit. Selenium concentrations in MW-03A exceeded their respective GWCLs during the third quarter of2023 and are the subject of this Plan. While consecutive exceedances of other constituents may have been noted in other wells, a P&TS and SAR have not been required or appropriate in light of other actions currently being undertaken by EFRI or in light of other reports submitted by EFRI, and as determined by Division of Waste Management and Radiation Control ("DWMRC") Staff. Specifically, consecutive exceedances, which occurred in previous reporting periods are discussed in previous SARs submitted to DWMRC. A description of the other actions and reports which have affected the requirement to submit a P&TS are as follows: 1. Nitrate + nitrite and chloride in monitoring wells at the site have been the subject of ongoing investigations at the Mill. Based on the results of the previous investigations, EFRI and the Director acknowledge that it has not been possible to date to determine the source(s), cause(s), attribution, magnitudes of contribution, and proportion(s) of the local nitrate + nitrite and chloride in groundwater. However, as the commingled nitrate and chloride plumes ( collectively the nitrate/chloride plume) extended upgradient of the tailings management system ("TMS"), it can be concluded that at least the northern portion of the plume had an upgradient source. EFRI submitted a Corrective Action Plan ("CAP") in February 2012 for nitrate+ nitrite and chloride in groundwater. The CAP was approved on December 12, 2012 and the activities associated with the CAP are on-going. Based on information provided by DWMRC in teleconferences on April 27, and May 2, 2011, due to the ongoing activities and actions, the 30-day plan and schedule for assessment is not required for nitrate + nitrite and chloride exceedances at this time. 2. A P&TS will not be prepared for monitoring wells with two successive exceedances, if those successive exceedances were reported in a previous quarter and /or were included in a previous SAR during the current permit period beginning March 8, 2021, because the conclusions and actions delineated in those reports were accepted by DWMRC. 3. A chloroform plume commingles with the central portion of the nitrate/chloride plume. Chloroform and associated daughter product methylene chloride are the subject of the ongoing chloroform pumping program and are covered by State of Utah Notice of Violation ("NOV") and Groundwater Corrective Action Order ("CAO") State of Utah Department of Environmental Quality ("UDEQ") Docket No. UGW-20-01. As a result, the 30-day plan and schedule for assessment of chloroform and its daughter product exceedances is not required. 1 Groundwater at the Mill site has been evaluated in multiple recent investigations and reports, including the 2007 Revised Background Groundwater Quality Report and the 2008 New Wells Background Report, an isotopic investigation performed by Hurst and Solomon in 2008, the 2012 Pyrite Report, and multiple SARs. Based on a review of the Background Reports and other information and analyses the Director re- opened the Permit and modified the GWCLs to be equal to the mean concentration plus two standard deviations or the equivalent of background for each constituent on an intrawell basis. The modified GWCLs became effective on January 20, 2010. A new GWDP was issued on January 19, 2018. The January 19, 2018 GWDP incorporated the revised GWCLs that resulted from previous SARs. Revised GWDPs were issued on March 19, 2019 and March 8, 2021. The revised GWDPs incorporated the revised GWCLs that resulted from previous SARs among other changes. Part I.G.4 c) of the GWDP states, with respect to exceedances ofGWCLs, "that the Permittee shall prepare and submit within 30 calendar days to the Executive Secretary a P&TS for assessment of the sources, extent and potential dispersion of the contamination, and an evaluation of potential remedial action to restore and maintain groundwater quality to insure that Permit limits will not be exceeded at the compliance monitoring point and that DMT or BAT will be reestablished." Pursuant to this requirement, EFRI has previously submitted P&TSs and SARs to address previous dual exceedances ( as required in light of other actions currently being undertaken by EFRI and as determined by DWMRC Staff and stated in teleconferences with EFRI on April 27 and May 2, 2011). This Plan covers selenium in MW-03A, identified as being in violation of Part I.G.2 of the Permit, in the Third Quarter 2023 Exceedance Notice, dated October 25, 2023. 2. CONSTITUENTS AND WELLS SUBJECT TO THIS PLAN The following constituent is covered by this Plan: Table 1 Constituent and Well Subject to this Plan Constituent POCWell Current Results GWCL Q2 Q3 2023 2023 Selenium (ug/L) MW-03A 109.58 112.0 171 It should be noted that the third quarter 2023 Exceedance Notice identifies a number of wells, with consecutive exceedances of other constituents. None of those constituents are included in this Plan, for the reasons stated in Section 1 above and in the Third Quarter Exceedance Notice. 2 3. CATEGORIES FOR ANALYSIS Previously EFRI has categorized wells and constituents in several categories as follows: 1. Constituents Potentially Impacted by Decreasing pH Trends Across the Site 2. Newly Installed Wells with Interim GWCLs 3. Constituents in Wells with Previously Identified Rising Trends 4. Pumping Wells 5. Other Constituents Selenium can fall within the first category when downward pH trends are noted, and pH in MW- 03A does exhibit a decreasing trend during certain time periods; although the overall trend is nearly flat. Selenium in MW-03A can also fall within the third category: constituents in wells with previously identified rising trends, because a rising trend was noted for selenium in the 2012 SAR. Due to the multiple categories that are applicable to selenium in MW-03A, for this SAR the fifth category: Other Constituents will be used. Assessment of this constituent in MW-03A will follow the process noted below. 3 .1. Other Constituents Preliminary analysis of indicator parameters shows that chloride and sulfate concentrations are stable and fluoride and uranium concentrations are decreasing. Stable to decreasing indicator parameters demonstrates that MW-03A is un-impacted by the TMS. In addition, the 2008 Hurst and Solomon isotopic study, noted that MW-03A was tritium-free, contained very small amounts of chlorofluorocarbons ("CFCs"), and did not bear isotopic signatures similar to those of either the tailings cells or the wildlife pond, which suggests that trace metal concentrations and trends in the groundwater system near MW-03A result from natural, background influences. 4. PLAN 4 .1. General This Plan is a plan and time schedule to assess the potential sources, extent and potential dispersion of selenium, and to evaluate potential remedial action to restore and maintain groundwater quality to ensure that Permit limits will not be exceeded at the compliance monitoring point and that, to the extent applicable, discharge minimization technology and best available technology will be reestablished. The first step in the analysis will be an assessment of the potential sources to determine whether the exceedance is due to background influences or Mill activities. If an exceedance is determined to be the result of background influences then it will not be necessary to perform any further evaluations on the extent and potential dispersion of any contamination or to perform an evaluation of potential remedial actions. Monitoring will continue, and where appropriate revised GWCLs will be proposed to reflect changes in background conditions at the site. 3 However, if any exceedance is determined to be caused by Mill activities, then EFRI will proceed to the next step and will consider the extent and potential dispersion of the contamination, and will perform an evaluation of potential remedial actions to restore and maintain groundwater quality to ensure that Permit limits will not be exceeded at the compliance monitoring point. This two-step approach is necessary, because, as a result of variable background conditions at the site, it cannot be assumed that consecutive exceedances of a constituent in a well represents contamination that has been introduced to the groundwater. It is first necessary to establish whether or not any exceedance results from background influences. Based on the site-wide analyses provided in the Background Reports, SARs, Pyrite Report and other recent information and investigations at the site, exceedances in MW-03A are likely due to natural background influences that impact the geochemical conditions at MW-03A (including changing water levels and enhanced oxygen transport to groundwater via the well casing). In particular, stable to decreasing indicator parameters chloride, fluoride, sulfate and uranium demonstrate that increasing selenium cannot result from potential TMS seepage. Therefore it is unlikely that analysis will reveal the need for any further evaluation of the extent and potential dispersion of any contamination or for an evaluation of potential remedial actions. 4.2. Approach for Analysis The first step in the analysis will be an assessment of the potential sources for selenium in MW- 03A to determine whether the exceedances are due to background influences or Mill activities. This assessment will include an analysis of selenium and field pH as well as the other indicator parameters chloride, sulfate, fluoride and uranium to determine if the behavior of the water in MW-03A has changed since the time of the Background Reports. As discussed above, preliminary analysis of indicator parameters chloride, fluoride, sulfate and uranium indicate that these parameters are stable to decreasing, demonstrating that MW-03A cannot be impacted by potential TMS seepage. Therefore the selenium exceedance is attributable to background influences, and it is anticipated that any further evaluations on the extent and potential dispersion of the contamination, or an evaluation of potential remedial actions, will be unnecessary. Monitoring will continue, and revised GWCLs are anticipated to be proposed to reflect changes in background conditions at the site. The revised GWCL process will include a statistical analysis of selenium data from MW-03A using the methods described in the Existing Wells Background Report (INTERA, 2007a) and the State of Utah Department of Environmental Quality approved Flowsheet ("the Flowsheet"). As mentioned in the SARs, the United States Environmental Protection Agency ("EPA") has recognized the need to update compliance limits periodically to reflect changes to background conditions. 4 In 2009 guidance, EPA states: "We recommend that other reviews of background also take place periodically. These include the following situations: • When periodically updating background, say every 1-2 years • When performing a 5-10 year permit review During these reviews, all observations designated as background should be evaluated to ensure that they still adequately reflect current natural or baseline groundwater conditions. In particular, the background samples should be investigated for apparent trends or outliers. Statistical outliers may need to be removed, especially if an error or discrepancy can be identified, so that subsequent compliance tests can be improved. If trends are indicated, a change in the statistical method or approach may be warranted." and "Site-wide changes in the underlying aquifer should be identifiable as similar trends in both upgradient and compliance wells. In this case, it might be possible to remove a common trend from both the background and compliance point wells and to perform interwell testing on the trend residuals." (EPA 530/R-09-007, March 2009, Statistical Analysis Of Groundwater Monitoring Data At RCRA Facilities Unified Guidance, Environmental Protection Agency, Office Of Resource Conservation And Recovery.) 4.3. Experts Reports to be Prepared The results of the statistical analysis and, if appropriate, recalculation of the GWCL will be compiled as a SAR that will be submitted to DWMRC within 90 days of the approval of this Plan. The SAR will detail the results of all analyses to be performed and the conclusions to be drawn from such analyses, including proposed revision to the existing GWCL. Specifically, the SAR will follow the format of the originally submitted SAR (October 10, 2012) and will include discussions, results and conclusions of the analyses and appendices containing the following: A Statistical analysis of SAR Parameters Comparison of calculated and measured TDS for samples with complete major ions Charge balance calculations Descriptive statistics Box plots to identify extreme outliers Histograms and Shapiro Wilk test for normality Regression or Mann Kendall trend analysis Evaluation of inflection points and data subsets Proposed Revised GWCLs 5 ) . A statistical analysis of Indicator Parameters Descriptive Statistics Box plots to identify extreme outliers Histograms and Shapiro Wilk test for normality Regression and/or Mann Kendall trend analysis 5. TIME SCHEDULE The SAR will be submitted to the Director within 90 days after approval of this Plan. The SAR contemplated by this submission, may be combined with any subsequent SARs resulting from other Plans and Schedules for other out of compliance constituents, as necessary. 6. CONCLUSION Given the varied background groundwater quality at the site it cannot be assumed that consecutive exceedances of a constituent in a monitoring well means that contamination has been introduced to groundwater in that well. Preliminary analysis of MW-03A indicator parameters shows that chloride and sulfate concentrations are stable and fluoride and uranium concentrations are decreasing. Stable to decreasing indicator parameters demonstrate that MW-03A is un-impacted by the TMS. In addition, the 2008 Hurst and Solomon isotopic study noted that MW-03A was tritium-free, contained very small amounts of chlorofluorocarbons ("CFCs"), and did not bear isotopic signatures similar to those of either the tailings cells or the wildlife pond, which suggests that trace metal concentrations and trends in the groundwater system near MW-03A result from natural, background influences. That the selenium exceedance in MW-03A is likely due to natural background influences that impact the groundwater geochemistry near MW-03A (including changing water levels and enhanced oxygen transport to groundwater via the well casing) is also consistent with recent site-wide analyses in the Background Reports, SARs, and the Pyrite Report. 6