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HomeMy WebLinkAboutDRC-2023-068200 - 0901a0688123a796eJ::NERGYFUELS July 11, 2023 VIA PDF AND OVERNIGHT DELIVERY Doug Hansen Director Division of Waste Management and Radiation Control State of Utah Department of Environmental Quality 195 North 1950 West Salt Lake City, UT 84116 Energ)' Fuels Resources (USA) Inc. 225 Union Blvd. Suite 600 Lakewood, CO, US, 80228 303 974 2140 www.energyfuels.com J' 14223 Re: State of Utah Ground Water Discharge Permit No. UGW370004 White Mesa Uranium Mill -Notice Pursuant to Part I.G.1 (a) Dear Mr. Hansen: The White Mesa Mill (the "Mill") performed second quarter ("Q2") groundwater monitoring during the period from April 1, to June 30, 2023 under the March 8, 2021 version of the Mill's Groundwater Discharge Permit (the "GWDP"). All analytical data needed for comparison to the GWCLs were received during the period ending June 20, 2023. Pursuant to Part I.G. 1.a) of the GWDP, please take notice that the concentrations of specific constituents in the monitoring wells highlighted in yellow and bold italics in the columns for this quarter in the attached Table 1 exceeded their respective GWCLs. For ease of review, Table 1 has been formatted to simplify the tracking of any continued exceedances from one monitoring period to the next by charting ongoing monitoring of the same well in the same row, and by highlighting exceedances (in color and bold italics). As a result of the issuance of a revised GWDP on March 8, 2021, which sets revised GWCLs, requirements to perform accelerated monitoring for certain constituents under Part I.G.1 of the previous GWDP ceased effective on March 8, 2021 , and the effect of the issuance of the revised GWDP was to create a "clean slate" for certain constituents going forward . Part I.G.1 c) of the GWDP states "that the Permittee shall prepare and submit within 30 calendar days to the Director a plan and a time schedule for assessment of the sources, extent and potential dispersion of the contamination, and an evaluation of potential remedial action to restore and maintain groundwater quality to ensure that Permit limits will not be exceeded at the compliance monitoring point and that DMT or BAT will be reestablished." The summary below relating to exceedances includes, for each exceedance, a brief discussion of whether such a plan and schedule is or is not required or appropriate at this time in light of other actions currently being undertaken DRC-2023-068200 Letter to Mr. Doug Hansen July 11, 2023 Page 2 by Energy Fuels Resources (USA) Inc. ("EFRI") or in light of other reports submitted by EFRI, and as determined by Division of Waste Management and Radiation Control ("DWMRC") Staff. A description of the other actions and reports which have affected the requirement to submit a plan and time schedule are as follows: 1. Nitrate + nitrite and chloride in monitoring wells at the site have been the subject of ongoing investigations at the Mill. Based on the results of the previous investigations, EFRI and the Director acknowledged that it has not been possible to date to determine the source(s), cause(s), attribution, magnitudes of contribution, and proportion(s) of the local nitrate + nitrite and chloride in groundwater. EFRI submitted a Corrective Action Plan ("CAP") in February 2012 for nitrate+ nitrite and chloride in groundwater. The CAP was approved on December 12, 2012 and the activities associated with the CAP are on-going. Based on information provided by DWMRC in teleconferences on April 27, and May 2, 2011, due to the ongoing activities and actions, the 30-day plan and schedule for assessment is not required for nitrate + nitrite and chloride exceedances at this time. 2. A Plan and Time Schedule will not be prepared for monitoring wells with two successive exceedances if those successive exceedances were reported in a previous quarter and/or were included in a previous Source Assessment Report ("SAR") during the current permit period beginning March 8, 2021. Inclusion in a previous SAR means that the GWCLs were modified based on conclusions and actions delineated in the previous SAR which were accepted by DWMRC. 3. Chloroform and methylene chloride are the subject of the ongoing chloroform pumping program and are covered by State of Utah Notice of Violation ("NOV") and Groundwater Corrective Action Order ("CAO") State of Utah Department of Environmental Quality ("UDEQ") Docket No. UGW-20-01. As a result, the 30-day plan and schedule for assessment of chloroform and methylene chloride exceedances is not required. It is important to note that under the GWDP, GWCLs have been determined on a well-by-well basis to reflect background groundwater quality, as defined by the mean plus second standard deviation concentration, or the equivalent. Accordingly, the GWDP requires that constituent concentrations in each monitoring well shall not exceed the GWCLs set out in Table 2 of the GWDP. It should be noted that, because the GWCLs have been set at the mean plus second standard deviation, or the equivalent, un-impacted groundwater would normally be expected to exceed the GWCLs approximately 2.5% of the time. Therefore, exceedances are expected in approximately 2.5% of all sample results, and do not necessarily represent impacts to groundwater from Mill operations. In fact, more frequent sampling of a given analyte will increase the number of exceedances due to statistical variation and not due to Mill activity. Additionally, given the slow velocity of groundwater movement, accelerated sampling at a monthly frequency can result in resampling of essentially the same water and can lead to repeat exceedances for accelerated constituents not due to Mill activities, but due to repeat sampling of the same water. Letter to Mr. Doug Hansen July 11, 2023 Page 3 1.0 Exceedances in Required Quarterly Sampling Wells 1.1 Quarterly Wells with Two Successive Exceedances As indicated in the attached Table 1, the analytes discussed below exceeded their respective GWCLs for two successive sampling periods in Q2 2023. A 30-day plan and schedule contemplated in Part LG.I c) of the GWDP will not be required as noted below. One-time exceedances and non-successive exceedances are noted on Table 1, but not listed below. Consecutive exceedances which occurred in previous reporting periods are discussed in previously submitted SARs. MW-11 • The chloride concentration exceeded its GWCL in all of the Q2 2023 sampling events. As mentioned above, a CAP has been submitted and approved to address nitrate+nitrite contamination which is expected to address chloride in groundwater. The actions specified in the CAP are currently being implemented; therefore, a plan to address this consecutive exceedance is not necessary and is not being submitted. • The nitrate concentration exceeded its GWCL in in all of the Q2 2023 sampling events. As mentioned above, a CAP has been submitted and approved to address nitrate+nitrite contamination which is expected to address chloride in groundwater. The actions specified in the CAP are currently being implemented; therefore, a plan to address this consecutive exceedance is not necessary and is not being submitted. • The selenium concentration exceeded its GWCL in all of the Q2 2023 sampling events. A plan and schedule for assessment was submitted to DWMRC on May 24, 2023. An additional plan to address this consecutive exceedance is not necessary and is not being submitted. • Sulfate has exceeded the GWCL for both the March 2023 and Q2 2023 sampling events. A SAR was submitted on March 7, 2022. As a result of the SAR, the GWCLs have been recalculated and accepted by DWMRC. The recalculated GWCLs will become effective upon their publication in the next revision of the GWDP. As a result of DWMRC's acceptance of the recalculated GWCLs, a plan and schedule to address this consecutive exceedance is not necessary and will not be submitted. Until such time as the new GWCLs become effective, the exceedances will continue to be noted and reported. MW-26 MW-26 Note: As stated in the September 2009 Statement of Basis (page 23) in support of the January 20, 2010 revisions to the GWDP, "[i]t should be noted that, because MW-26 is a pumping well for chloroform removal, concentrations of all constituents in that well are subject to potential variation over time as a result of the pumping activity. This will be taken into account by the Executive Secretary in determining compliance for this well." Based on information provided by DWMRC in teleconferences on April 27, and May 2, 2011, due to the current pumping status as Letter to Mr. Doug Hansen July 11, 2023 Page 4 part of the chloroform investigation program, the 30-day plan and schedule for assessment is not required at this time for exceedances of chloroform and methylene chloride in MW-26. • Chloroform has exceeded its GWCL in all of the Q2 2023 sampling events. MW-26 is used as a pumping well for the ongoing chloroform capture program and is expected to yield increased concentrations of chloroform. Because this well is used in the chloroform capture program which is the subject of separate investigations and actions, a plan and time schedule to address the consecutive exceedances is not necessary and is not being submitted. • The nitrate concentration exceeded its GWCL in all of the Q2 2023 sampling events. As mentioned above, a CAP has been submitted and approved to address nitrate+nitrite contamination which is expected to address chloride in groundwater. The actions specified in the CAP are currently being implemented; therefore, a plan to address this consecutive exceedance is not necessary and is not being submitted. • The chloride concentration exceeded its GWCL in all of the Q2 2023 sampling events. As mentioned above, a CAP has been submitted and approved to address nitrate+nitrite contamination which is expected to address chloride in groundwater. The actions specified in the CAP are currently being implemented; therefore, a plan to address this consecutive exceedance is not necessary and is not being submitted. MW-30 • Nitrate + nitrite has exceeded its GWCL in all of the Q2 2023 sampling events. As mentioned above, a CAP has been submitted and approved and the specified actions are currently being implemented; therefore, a plan to address this consecutive exceedance is not necessary and is not being submitted. • The chloride concentration exceeded its GWCL in all of the Q2 2023 sampling events. As mentioned above, a CAP has been submitted and approved to address nitrate+nitrite contamination which is expected to address chloride in groundwater. The actions specified in the CAP are currently being implemented; therefore, a plan to address this consecutive exceedance is not necessary and is not being submitted. • Selenium has exceeded the GWCL for all of the Q2 2023 sampling events. A SAR was submitted on January 28, 2022. As a result of the SAR, the GWCLs have been recalculated and accepted by DWMRC. The recalculated GWCLs will become effective upon their publication in the next revision of the GWDP. As a result ofDWMRC's acceptance of the recalculated GWCLs, a plan and schedule to address this consecutive exceedance is not necessary and will not be submitted. Until such time as the new GWCLs become effective, the exceedances will continue to be noted and reported. • Uranium has exceeded the GWCL in the May and June 2023 sampling events. A SAR was submitted on January 28, 2022. As a result of the SAR, the GWCLs have been recalculated and accepted by DWMRC. The recalculated GWCLs will become effective upon their Letter to Mr. Doug Hansen July 11, 2023 Page 5 publication in the next revision of the GWDP. As a result ofDWMRC's acceptance of the recalculated GWCLs, a plan and schedule to address this consecutive exceedance is not necessary and will not be submitted. Until such time as the new GWCLs become effective, the exceedances will continue to be noted and reported. MW-31 • Nitrate + nitrite has exceeded its GWCL in all of the Q2 2023 sampling events. As mentioned above, a CAP has been submitted and approved and the specified actions are currently being implemented; therefore, a plan to address this consecutive exceedance is not necessary and is not being submitted. • The sulfate concentration exceeded its GWCL in all of the Q2 2023 sampling events. A SAR was submitted to DWMRC on June 24, 2020. As a result of the SAR, the GWCLs have been recalculated and accepted by DWMRC. The recalculated GWCLs will become effective upon their publication in the next revision of the GWDP. As a result of DWMRC's acceptance of the recalculated GWCLs, a plan and schedule to address this consecutive exceedance is not necessary and will not be submitted. Until such time as the new GWCLs become effective, the exceedances will continue to be noted and reported. • The TDS concentration exceeded its GWCL in all of the Q2 2023 sampling events. A SAR was submitted to DWMRC on June 24, 2020. As a result of the SAR, the GWCLs have been recalculated and accepted by DWMRC. The recalculated GWCLs will become effective upon their publication in the next revision of the GWDP. As a result of DWMRC's acceptance of the recalculated GWCLs, a plan and schedule to address this consecutive exceedance is not necessary and will not be submitted. Until such time as the new GWCLs become effective, the exceedances will continue to be noted and reported. • The chloride concentration exceeded its GWCL in all of the Q2 2023 sampling events. As mentioned above, a CAP has been submitted and approved to address nitrate+nitrite contamination which is expected to address chloride in groundwater. The actions specified in the CAP are currently being implemented; therefore, a plan to address this consecutive exceedance is not necessary and is not being submitted. • Uranium concentrations exceeded the GWCL in all of the Q2 2023 sampling events. A SAR was submitted to DWMRC on April 29, 2021. As a result of the SAR, the GWCLs have been recalculated and accepted by DWMRC. The recalculated GWCLs will become effective upon their publication in the next revision of the GWDP. As a result of DWMRC's acceptance of the recalculated GWCLs, a plan and schedule to address this consecutive exceedance is not necessary and will not be submitted. Until such time as the new GWCLs become effective, the exceedances will continue to be noted and reported. 1.2 Quarterly Wells with New Exceedances Reported in Q2 There are no new exceedances for the Q2 2023 quarterly well sampling program. Letter to Mr. Doug Hansen July 11, 2023 Page 6 2.0 Exceedances in Semiannual Sampling Wells Accelerated to Quarterly 2.1 Semi-annual Wells with Two Successive Exceedances As indicated in the attached Table 1, the analytes discussed below exceeded their respective GWCLs for two successive sampling periods (Ql 2023 and Q2 2023). MW-24 Beryllium, cadmium, fluoride, nickel, thallium, and field pH exceeded their GWCLs in MW-24 in the Q 1 2023 and Q2 2023 sampling events. The exceedances noted above are addressed in the SAR dated June 27, 2019. As a result of the SAR, EFRI installed a collocated well to study potential installation issues associated with MW- 24. DWMRC approved the collocated well strategy by letter dated September 5, 2019. In response to the previously identified exceedances and increasing trends, in 2020 EFRI voluntarily completed a study of MW-24A (collocated with MW-24) to determine what geochemical and hydrogeological influences are present which may be impacting monitoring data collected at these two wells and potentially other wells across the Mill site. The MW-24A study and report included several additional field data collection and analytical activities based on the conclusions of other Mill reports. The results of the analytical and test data collected during the MW-24A study demonstrated that natural processes unrelated to disposal of materials in the Tailings Management System can account for the behavior of all trace metals of concern, as well as fluoride, in groundwater at MW- 24 and MW-24A. Bottle-roll test results indicated that naturally-occurring trace metals can be mobilized at concentrations similar to or greater than in groundwater even without a large pH decrease, suggesting that agitation alone, such as would occur during routine purging and sampling of low permeability wells such as MW-24A, could result in metals mobilization. Based on the results of the MW-24A study EFRI has voluntarily agreed to implement a MW-24A Phase 2 study to determine what geochemical and hydrogeological influences are present that may be affecting monitoring data collected at other wells across the Mill site. EFRI coordinated the Phase 2 study efforts with DWMRC. DWMRC approved the Phase 2 study plan by letter dated June 16, 2022. The Phase 2 study will build on the results of the previous study and will supplement the data using eight other Mill site locations. As a result of D WMRC' s acceptance of the study strategy, a plan and schedule to address these consecutive exceedances is not necessary and will not be submitted. Until such time as the study is complete, the exceedances will continue to be noted and reported. MW-28 • Chloride has exceeded the GWCL for both the Ql 2023 and Q2 2023 sampling events and during previous quarters. As mentioned above, a CAP has been submitted and approved and the specified actions are currently being implemented; therefore, a plan to address this consecutive exceedance is not necessary and is not being submitted. Letter to Mr. Doug Hansen July I I, 2023 Page 7 • Uranium has exceeded the GWCL for both the Q 1 2023 and Q2 2023 sampling events. A SAR was submitted to DWMRC on October 19, 2020. As a result of the SAR, the GWCLs have been recalculated and accepted by DWMRC. The recalculated GWCLs will become effective upon their publication in the next revision of the GWDP. As a result of DWMRC's acceptance of the recalculated GWCLs, a plan and schedule to address this consecutive exceedance is not necessary and will not be submitted. Until such time as the new GWCLs become effective, the exceedances will continue to be noted and reported. 2.2 Semi-annual Wells with New Exceedances Reported in Q2 Three new single exceedances for the Q2 2023 semi-annual well sampling program are listed below. • Selenium in MW-03A was above the GWCL in the Q2 sampling event. • Uranium in MW-05 was above the GWCL in the Q2 sampling event. • TDS in MW-28 was above the GWCL in the Q2 sampling event. Relative to accelerated reporting requirements, reporting of exceedances is required to be completed within 30 days of receipt of the last data package for a quarterly monitoring event. Similarly, accelerated monitoring is required to commence the month following the submission of the Exceedance Notice for a specified quarter for wells that are being accelerated from quarterly to monthly and the quarter following the submission of the Exceedance Notice for wells that are being accelerated from semiannually to quarterly. Yours truly, i{ ~)t-~ ENERGY FUELS RESOURCES (USA) INC. Kathy Weinel Director, Regulatory Compliance cc: Scott Bakken, David Frydenlund. Logan Shumway, Garrin Palmer, Jordan App, Tanner Holliday Monitoring Well (Water Constituent Exceeding GWCL Class) Nitrate+ N itrite (as N) (mg/L) Chloride (mg/L} MW-II Manganese (ug/L} (Class II) Sulfate (mg/L) TDS (mg/L) Selenium (ug/L) MW-25 (Class TDS (mg/L) Ill) Chloride (mg/L} Nitrate+ Nitrite (as N) (mg/L) MW-26 Chloroform (ug/L} (Class [[I) Chloride (mg/L) Nitrate+ Nitrite (as N) (mg/L) Chloride (mg/L) MW-30 Selenium (ug/L) (Class II) Field pH (S.U.) Uranium (ug/L) Nitrate+ Nitrite (as N) (mg/L) Sulfate (mg/L) MW-31 TDS (mg/L) (Class II[) Uranium (ug/L) Chloride (mg/L) MW-03A Selenium (ug/L) (Class [[I) MW-05 (Class Uranium (ug/L) II} MW-12 Uranium (ug/L) (Class Ill) Selenium (ug/L} MW-17 Chloride (mg/L) (Class III) Beryllium (ug/L) Cadmium (ug/L) Fluoride (mg/L) Nickel (mg/L) MW-24 Manganese ( ug/L) (Class I[[) Thallium (ug/L) Gross Alpha (pCi/L) Sulfate (mg/L) T DS (mg/L) Field pH (S U ) MW-27 Nitrate + Nitrite (as N) (mg/L) (Class II[) Fluoride (mg/L) Chloride (mg/L} MW-28 Selenium (ug/L) Nitrate+ Nitrite (as N) (mg/L) (Class Ill) TDS (mg/L) Uranium (ug/L) MW-29 Uranium (ug/L} (Class [[!) MW-32 Chloride (mg/L) (Class Ill) MW-37 Field pH (S.U.) (Class [[[) Notes: NS= Not Required and Not Sampled NA= Not Appl icable Exceedances are shown in yellow GWCL in March 8, 2021 GWDP 2.5 39.16 237 1309 2528 12.5 2976 35 0.62 70 58.31 2.5 128 53.6 6.47 -8.5 9.82 5 993 2132 15 143 109.58 7.5 23.5 39 46.8 2 6.43 0.47 50 7507 2.01 7.5 2903 4450 5.03 -8.5 . 5.6 0.85 105 I I.I 5 3852 4.9 [5 35.39 6.61 -8.5 Qi 2021 Results February February March Ql 2021 QI 2021 2021 2021 2021 Sample Result Monthly Monthly Monthly Date Sample Sample Date Result Date Required Quarterly Sampling Wells 1.21 NA 46.4 46.4 1/12/21 185 2/9/21 254 3/8/21 1140 1260 2010 2160 <5 NA 1/11/21 2660 NS NA NS 34 NA 0.619 0. 764 1/14/21 2200 2/10/21 /930 3/9/21 57.4 71.3 17.7 /4.3 184 189 1/11 /21 55.6 2/10/21 55.3 3/9/21 7.49 7.25 9.86 11.6 17. I 14.3 1070 1130 1/1 2/21 2460 2/9/21 2960 3/8/21 /9. 7 22.2 354 380 Required Semiannual Sampling Wells NS NA NS NA NS NS NA NS NA NS 1/1 4/21 25.0 35.1 NS NA NS NS NA NS NA NS 2.75 NA 8. 79 NA 0.9/6 NA 70.4 NA 7460 NA 1/14/21 2.74 NS NA NS 2.94 NA 2980 NA 4260 NA 5.08 NA 5.16 1/1 4/21 NS NA NS NA 128 NA /4.0 NA 1/15/21 344 NS NA NS NA NA /0.3 NA 1/15/21 /6.9 NS NA NS 1/1 4/21 36.9 NS NA NS NS NA NS NA NS Table I -GWCL Exceedances under the March 8, 2021 GWDP Q2 2021 Results March May 2021 Jone 2021 2021 Q2 2021 Q2 2021 Monthly May 2021 Monthly June 2021 QJ 2021 Monthly Sample Result Sample Monthly Sample Monthly Sample Date Result Result Date Result Date Date Required Quarterly Sampling Wells NA 0.948 NA NA 46.9 47. 7 46.4 52.I 221 04/20/21 237 5/10/21 NA 6/8/21 NA 7/27/21 1270 1290 1280 1270 1950 2110 2190 1960 NA <5 NA NA NA 04/14/21 2720 NS NA NS NA 7/28/21 NA 34.8 NA NA 0.617 1.42 l.06 0.368 2190 04/21 /21 777 5/11/21 733 6/8/21 /590 7/28/21 63.9 57.5 69.6 54.9 17.0 17.7 18.6 /7.0 /92 162 188 170 56.3 04/14/21 55. 7 5/1 1/21 58.3 6/8/21 54. I 7/29/21 7.14 7.20 7.20 7.36 10.2 10.3 10.7 9.84 17.4 18.6 /8.9 20.6 /2 /0 11 70 1200 11 70 2400 04/1 3/21 2300 5/10/21 2610 6/7/21 2400 7/27/21 20.2 20.I 21. 7 20.8 388 377 384 374 Required Semiannual Sampling Wells NA 4/27/21 74.0 NS NA NS NA NS NA 4/20/21 0 599 NS NA NS NA NS NA 4/20/21 22.9 28.8 NS NA NS NA 7/21 /21 NA 4/26/21 32.6 NS NA NS NA NS NA 2.78 NA NA NA 8.08 NA NA NA 0.925 NA NA NA 72.4 NA NA NA 7540 NA NA NA 4/29/21 3.02 NS NA NS NA 7/29/21 NA 3.18 NA NA NA 2960 NA NA NA 4460 NA NA NA 5.00 NA NA 6.57 NA 4/1 5/21 NS NA NS NA 7/22/21 0.69 NA 144 NA NA NA /3.4 NA NA NA 4/15/21 4.09 NS NA NS NA 7/23/21 NA 3740 NA NA NA 8.52 NA NA NA 4/14/21 /6.2 NS NA NS NA 7/22/21 NA 4/13/21 31 8 NS NA NS NA 7/28/21 NA 5/1 2/21 7.00 NS NA NS NA NS These GWCLs were reset with the issuance of the March 8, 2021 GWDP. The n;w GWCLs became effective~on March 8, 2021 and the first exceedance under the re_llised GWDP was noted in_!tie_llllarch monthly data. QJ 2021 Results Q4 2021 Results August August September September November November December December QJ 2021 2021 2021 2021 2021 Q4 2021 Q4 2021 2021 2021 2021 2021 Result Monthly Monthly Monthly Monthly Sample Result Monthly Monthly Monthly Monthly Sample Date Date Result Sample Date Result Sample Date Result Sample Date Result Required Quarterly Sampling Wells Required Quarterly Sampling Wells 0.924 NA NA 1.5 NA NA 48.3 57.0 49.6 52.8 53.6 53.9 376 8/10/21 NA 9/7/21 NA 10/20/21 286 11/16/21 261 12/13/21 300 /470 13 70 1240 1360 1300 1350 2680 NA NA 2200 2230 2140 <5 NA NA 6.75 NA NA 3100 NS NA NA NS I 0/20/21 2680 11/16/21 2920 12/14/2 1 2590 34 2 NA NA 33.1 NA NA 0.352 1.42 0. 710 0.928 1.18 I. 76 723 8/10/21 996 9/9/21 516 10/21/21 540 11/16/21 568 12/15/21 1160 54.0 61.4 59.3 55.2 56.9 75.9 20.6 16.5 15.4 /4.3 18.0 18.6 188 161 183 182 182 /84 56.3 8/9/21 56./ 9/8/21 60.4 I 0/19/21 54.6 11/17/21 53.6 12/14/2 1 58.8 6.98 6.84 6.70 6.77 7.18 704 9.60 9.38 9.74 9.76 9.67 10. I 18. 7 /5. 7 16.0 18. I /9.3 17.9 1210 1130 1130 1220 1180 1220 3100 8/9/21 2600 9/7/21 2870 10/19/21 2600 11/1 5/21 26/0 12/1 3/21 2420 20.0 /9.3 20.2 20.9 21.5 21.8 39/ 365 356 371 366 376 Required Semiannual Sampling Wells Required Semiannual Sampling Wells NA NS NA NS NA 11/10/21 75.5 NS NA NS NA NA NS NA NS NA 10/26/21 0.446 NS NA NS NA 222 32.4 NS NA NS NA 11 /9/21 231 26.4 NS NA NS NA NA NS NA NS NA 11/8/21 33.4 NS NA NS NA 2. 71 NA NA 2.66 NA NA 9.26 NA NA 9.30 NA NA /.4 NA NA 0.988 NA NA 76. 7 NA NA 76. 7 NA NA 7890 NA NA 7430 NA NA 2.9 / NS NA NS NA 11/10/21 3./4 NS NA NS NA 1.92 NA NA 1.56 NA NA 3050 NA NA 3220 NA NA 4940 NA NA 4730 NA NA 5.85 NA NA 5.23 NA NA 6.32 3.88 NS NA NS NA 10/26/21 NS NA NS NA NA 0.65 152 NA NA /47 NA NA 18.5 NA NA 11.2 NA NA 6.09 NS NA NS NA 10/26/21 1.89 NS NA NS NA NA NA NA 3570.00 NA NA 13.80 NA NA 6.03 NA NA 15.8 NS NA NS NA 10/27/21 14.9 NS NA NS NA 36.5 NS NA NS NA 11/2/21 36. I NS NA NS NA NA NS NA NS NA 11/1 7/21 7 06 NS NA NS NA Table I -GWCL Exceedances under the March 8, 2021 GWDP QI 2022 Results Q2 2022 Results Q3 2022 Results Q4 2022 Results February February March 2022 March May 2022 June 2022 August August September September No\'ember No\'ember December December Monitoring GWCLin Q] 2022 2022 Q2 2022 May 2022 June 2022 Q3 2022 2022 Q4 2022 QI 2022 2022 Monthly 2022 Q2 2022 Monthly Monthly Q3 2022 2022 2022 2022 Q4 2022 2022 2022 2022 2022 Well (Water Constituent Exceeding GWCL March 8, 2021 Sample Result Monthly Monthly Sample Monthly Sample Result Sample Monthly Sample Monthly Sample Result Monthly Monthly Monthly Monthly Sample Result Monthly Monthly Monthly Monthly Class) GWDP Date Sample Date Result Result Date Sample Date Result Date Result Date Date Result Sample Date Result Sample Date Result Sample Date Result Date Date Required Quarterly Sampling Wells Required Quarterly Sampling Wells Required Quarterly Sampling Wells Required Quarterly Sampling Wells Nitrate+ Nitrite (as N) (mg/L) 2.5 2.55 NA NA 2.2 1.6 1.9 2.12 2.45 2.65 2.90 2.74 1.30 Chloride (mg/L) 39. 16 51. I 57.2 67. 7 54.9 59.5 46.4 54.0 67.4 68. I 72.I 71.9 52.3 MW-II Manganese ( ug/L) 237 156 233 224 180 254 228 297 201 212 214 220 273 (Class II) 1/18/22 2/8/22 3/8/22 4/18/22 5/4/22 6/6/22 7/12/22 8/8/22 9/21 /22 I 0/10/22 11/8/22 I 2/14/22 Sulfate (mg/L) 1309 1020 1240 1170 1240 1270 866 1390 1260 1300 1140 1140 1330 TDS (mg/L) 2528 2050 1900 2080 2060 2290 2360 2520 3230 2280 2570 2270 2370 Selenium (ug/L) 12.5 9.29 NA NA 10 8 NA NA 9.3 NA NA 15.5 NA NA MW-25 (Class TDS (mg/L) 2976 2720 2690 3/7/22 2610 3600 2660 2730 2830 2780 2750 2660 2690 2780 Ill) 1/17/22 2/9/22 4/12/22 5/3/22 6/7/22 7/13/22 8/9/22 9/20/22 I 0/10/22 11/9/22 12/14/22 Chloride (mg/L) 35 34.1 NA NA 33.4 NA NA 22.4 NA NA 35.8 NA NA MW-26 Nitrate+ Nitnte (as N) (mg/L) 0.62 0.601 0.367 0.600 0.8 I. I 0.60 /.63 1.56 0.49 1 0.632 0.408 2.66 (Class Ill) Chloroform (ug/L) 70 1/20/22 818 2/9/22 1580 3/8/22 1460 4/20/22 447 5/4/22 616 6/7/22 1250 7/14/22 <1.0 8/9/22 1120 9/20/22 8/0 I Oil 3/22 749 11 /10/22 512 12/15/22 460 Chloride (mg/L) 58.3 I 77. I 58.6 64.I 56.8 63.2 47.4 61.0 65.0 62./ 65.5 59.2 60.6 Nitrate+ Nitrite (as N) (mg/L) 2.5 14.5 /3.6 16.6 17 /5 11.0 /7.6 13.5 16.5 17.9 /5. 9 16. I MW-30 Chloride (mg/L) 128 181 /84 /96 173 195 126 108 185 /82 /96 156 /95 (Class[[) Selenium (ug/L) 53.6 1/17/22 56.7 2/9/22 57. 7 3/7/22 62.0 4/20/22 64.9 5/4/22 69.4 6/7/22 65.7 7/13/22 6/. I 8/9/22 64.3 9/20/22 70.0 10/13/22 65. I 11 /9/22 75.6 12/13/22 70.8 Field pH (S U) 6.47 -8.5 7.62 720 7.12 6.92 724 7.32 7.33 7.33 6.81 6.84 6.37 6.59 Uranium (ug/L) 9.82 JO. I /0.3 9.9 9.6 JO. I 9.6 10.0 JO. I 8.3 9.8 JO. I 13.0 Nitrate + Nitrite (as N) (mg/L) 5 18.0 13.5 17.0 18.0 13.0 /3.0 16.9 16.8 17. I 17.0 /6.0 12.6 MW-31 Sulfate (mg/L) 993 1210 1250 731 1180 1220 1110 1260 /230 1200 972 /380 1280 (Class [[[) TDS (mg/L) 2132 1/19/22 2620 2/8/22 2680 3/7/22 2530 4/1 1/22 4300 5/3/22 2660 6/6/22 2690 7/12/22 2700 8/8/22 2700 9/20/22 1830 10/11/22 2720 11 /8/22 2670 12/1 3/22 2700 Uranium (ug/L) 15 2 /. 7 22. I 22.5 22.0 22.9 21.5 22.6 22.7 18.8 23.3 24.5 26.2 Chloride (mg/L) 143 370 379 416 372 381 351 421 396 390 397 243 335 Required Semiannual Sampling Wells Required Semiannual Sampling Wells Required Semiannual Sampling \.Yells Required Semiannual Sampling Wells MW-OJA Selenium (ug/L) 109.58 NS NA NS NA NS NA 4/27/22 87.4 NS NA (Class Ill) NS NA NS NA NS NA NS NA 10/19/22 97.5 NS NA NS NA MW-05 (Class Uranium (ug/L) 7.5 NS NA NS NA NS NA 4/18/22 0.5 NS NA NS NA NS NA NS NA NS NA I 0/12/22 0.4 NS NA NS NA [[) MW-12 Uranium (ug/L) 23.5 1/20/22 22.1 NS NS 4/19/22 20.5 2 I 6 21.2 (Class rrr) NA NA NS NA NS NA 7/14/22 NS NA NS NA 10/13/22 NS NA NS NA Selenium (ug/L) 39 25 6 313 29.2 32. I MW-17 Chloride (mg/L) 46.8 NS NA NS NA NS NA 4/18/22 31.5 NS NA (Class [[[) NS NA NS NA NS NA NS NA 10/1 7/22 54.0 NS NA NS NA Beryllium (ug/L) 2 1. 71 NA NA 2.5 NA NA 2.7 NA NA 3.3 NA NA Cadmium (ug/L) 6.-13 8 . ./6 NA NA 9.20 NA NA 8.6 NA NA 10.9 NA NA Fluoride (mg/L) 0.47 I NA NA 0.8 NA NA 0.760 NA NA 1.53 NA NA Nickel (mg/L) 50 80.9 NA NA 74.3 NA NA 69.9 NA NA 86.9 NA NA MW-24 Manganese (ug/L) 7507 7630 NA NA 7070 NA NA 7540 NA NA 8130 NA NA (Class [I[) Thallium (ug/L) 2.0 1 1/27/22 NS NA NS 4/27/22 NS NS 7/20/22 NS NS 11/2/22 NS NS 2.66 NA 3.1 NA NA 3.0 NA NA 3.5 NA NA Gross Aloha (oCi/L) 7.5 2.26 2.28 7/28/22 NA NA NA NA 2.55 NA NA 2.70 NA NA Sulfate (mg/L) 2903 3060 NA NA 3110 NA NA 2800 NA NA 2680 NA NA TDS (mg/L) 4cl50 4140 NA NA 3350 NA NA 4200 NA NA 4440 NA NA Field pH (S.U.) 5.03 -8.5 5.3 I NA NA 4.81 NA NA 4.89 4.80 NA NA 4.39 NA NA MW-27 Nitrate+ Nitrite (as N) (mg/L) 5.6 6.15 6.30 5 18 5.26 (Class[[[) 1/18/22 NS NA NS NA 4/1 2/22 NS NA NS NA 7/1 5/22 NS NA NS NA 10/19/22 NS NA NS NA Fluoride (mg/L) 0.85 NA 0.90 0.530 0.722 Chloride (mg/L) 105 I.JO NA NA /30 NA NA 159 NA NA 161 NA NA MW-28 Selenium (ug/L) I I.I /3.3 NA NA /9.8 NA NA 20.8 NA NA 23.7 NA NA (Class Ill) Nitrate + Nitrite (as N) (mg/L) 5 1/20/22 4.03 NS NA NS NA 4/19/22 5.1 NS NA NS NA 7/15/22 5.16 NS NA NS NA 10/12/22 5.69 NS NA NS NA TDS (mg/L) 3852 NA NA NA 3320 NA NA NA NA NA 3550 NA NA Uranium (ug/L) 4.9 8.50 NA NA 10.10 NA NA 12.4 NA NA 12.5 NA NA MW-29 Uranium (ug/L) 15 1/18/22 15. I NS NA NS NA 4/14/22 /5. 7 NS NA (Class Ill) NS NA 7/14/22 15. I NS NA NS NA 10/12/22 IL! NS NA NS NA MW-32 Chloride (mg/L) 35.39 1/19/22 35 0 NS NA NS NA 4/11/22 28 6 NS NA (Class Ill) NS NA 7/1 5/22 28 2 NS NA NS NA I 0/1 1/22 37.I NS NA NS NA MW-37 Field pH (S.U) 6.61-8.5 NS NA NS NA NS NA 5/17/22 7.04 NS NA (Class II [) NS NA NS NA NS NA NS NA 11/1/22 6.60 NS NA NS NA Table I -GWCL Exceedances under the March 8, 2021 GWDP QI 2023 Results February February March 2023 Monitoring GWCLin Ql 2023 QI 2023 2023 2023 Monthly WelJ (Water Constituent Exceeding GWCL March 8, 2021 Sample Result Monthly Monthly Sample Class) GWDP Date Sample Date Result Date Required Quarterly Sampling Wells Nitrate+ Nitrite (as N) (mg/L) 2.5 3.49 2.89 Chloride (mg/L) 39.16 70.7 71.4 MW-II Manganese ( ug/L) 237 193 161 (Class II) 1/25/23 2/8/23 3/14/23 Sulfate (mg/L) 1309 1240 1100 TDS (mg/L) 2528 2390 2120 Selenium (ug/L) 12.5 17.5 17. 7 MW-25 (Class TDS (mg/L) 2976 1/23/23 2750 2/7/23 2610 3/15/23 Ill) Chloride (mg/L) 35 32.4 32.2 MW-26 Nitrate+ Nitrite (as N) (mg/L) 0.62 1.82 /.94 Chloroform (ug/L) 70 1/26/23 709 2/8/23 664 3/1 4/23 (Class Ill) Chloride (mg/L) 58.31 51.5 52.2 Nitrate+ Nitrite (as N) (mg/L) 2.5 18. l /5.9 Chloride (mg/L) 128 166 173 MW-30 Selenium (ug/L) 53.6 1/25/23 68.8 2/8/23 70.6 3/15/23 (Class II) Field pH (S.U.) 6.47 -8.5 7.01 6.77 Uranium (ug/L) 9.82 10.8 96 Nitrate+ Nitrite (as N) (mg/L) 5 18. 7 16.5 MW-31 Sulfate (mg/L) 993 1230 11 90 TDS (mg/L) 2132 1/24/23 2740 2/7/23 2730 3/14/23 (Class Ill) Uranium (ug/L) 15 25.4 23.3 Chloride (mg/L) 143 333 388 Required Semiannual Sampling Wells MW-03A Selenium (ug/L) 109.58 NS NA NS NA NS (Class Ill) MW-05 (Class Uranium (ug/L) 7.5 NS NA NS NA NS II) MW-12 Uranium (ug/L) 23.5 1/26/23 213 NS NS NA (Class Ill) Selenium (ug/L) 39 270 MW-17 Chloride (mg/L) 46.8 1/30/23 26.5 NS NA NS (Class III) Beryllium (ug/L) 2 2.4 NA Cadmium (ug/L) 6.43 9.2 NA Fluoride (mg/L) 0.47 0.699 NA Nickel (mg/L) 50 72.5 NA MW-24 Manganese (ug/L) 7507 7000 NA (Class Ill) Thallium (ug/L) 2.01 I /31/23 2.9 NS NA NS Gross Alpha (pCi/L) 7.5 2.27 NA Sulfate (mg/L) 2903 2720 NA TDS (mg/L) 4450 4220 NA Field pH (S.U) 5.03 -8.5 -1.76 NA MW-27 Nitrate+ Nitrite (as N) (mg/L) 5.6 5 25 (Class 111) 1/27/23 NS NA NS Fluoride (mg/L) 0.85 0.685 Chloride (mg/L) 105 140 NA MW-28 Selenium (ug/L) I LI <5.0 NA (Class Ill) Nitrate+ Nitrite (as N) (mg/L) 5 1/27/23 4.57 NS NA NS TDS (mg/L) 3852 NA NA Uranium (ug/L) 4.9 15.5 NA MW-29 Uranium (ug/L) 15 1/27/23 97 NS NA NS (Class Ill) MW-32 Chloride (mg/L) 35.39 1/30/23 27.9 NS NA NS (Class Ill) MW-37 Field pH (SU.) 6.61 -8.5 2/9/23 6.55 NS NA NS (Class III) Pursuant to tlie DINMRC ietter-ofJune 16, 2023, these constituents will no longer be mo nitored on an accelerated schedule. These constituents will be dropped from this report after this quarter. Q2 2023 Results March May2023 June 2023 2023 Q2 2023 Q2 2023 Monthly May2023 Monthly June 2023 Monthly Sample Result Sample Monthly Sample Monthly Date Result Result Result Date Date Required Quarterly Sampling Wells 2.53 2.98 2.64 2.86 66.3 70.6 66.0 69.0 211 224 233 283 4/17/23 5/9/23 6/5/23 1430 1330 1230 1340 2300 2450 2320 2160 /4. 9 14.2 16.8 /5.3 2600 4/19/23 2710 5/10/23 2330 6/6/23 2520 32.6 35.8 34.9 35.2 0.875 0.671 0.945 /.430 1060 4/27/23 650 5/10/23 512 6/6/23 426 47.7 64.4 64.4 60.0 17.3 /5.9 /5.3 16. l /99 202 181 203 72. l 4/26/23 65.I 5/10/23 70.9 6/6/23 71.4 7.15 6.94 6.96 7.13 9.6 9.5 /0.5 11.0 17.9 14.3 /5.4 16.4 951 1350 1270 1290 2520 4/24/23 2670 5/9/23 2570 6/5/23 2610 23. 7 24.0 25.2 26.7 302 297 388 397 Required Semiannual Sampling Wells NA 4/27/23 112.0 NS NA NS NA NA 4/19/23 26.3 NS NA NS NA NA 4/20/23 20.9 29.1 NS NA NS NA NA 4/25/23 27.9 NS NA NS NA NA 2.6 NA NA NA 9.4 NA NA NA 0.597 NA NA NA 72.7 NA NA NA 7030 NA NA NA 512123 3./ NS NA NS NA NA 3.15 NA NA NA 2720 NA NA NA 4020 NA NA NA -1.9-1 NA NA 5.32 NA 4/18/23 NS NA NS NA 0.613 NA 155 NA NA NA 22.8 NA NA NA 4/18/23 4.82 NS NA NS NA NA 3870 NA NA NA 11.8 NA NA NA 4/19/23 15.3 NS NA NS NA NA 4/25/23 36./ NS NA NS NA NA 5/11 /23 6 94 NS NA NS NA