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HomeMy WebLinkAboutDERR-2024-012089 6440 South Millrock Drive Suite 300 Holladay, Utah 84121 O +1.385.474.8500 www.jacobs.com AX0228191105SLC Mazie Cox UDEQ-DERR 195 North 1950 West Salt Lake City, UT 84114 November 30, 2023 Subject: 2023 Annual Groundwater Monitoring Report, Operable Units 1 and 4 Union Pacific Railroad, Ogden, Utah Civil Action No. 1:06-cv-00115 BSJ Dear Ms. Cox, This annual groundwater monitoring report for 2023 is being submitted by Jacobs Engineering Group Inc. (Jacobs) on behalf of Union Pacific Railroad (UPRR) for Operable Units (OU) 1 and 4 at the UPRR Ogden Railroad facility (site) in Ogden, Utah (Figure 1). This report summarizes the results of the 2023 annual sampling event at the Ogden Railyard and Weber River. Field activities were performed in accordance with the Quality Assurance Project Plan, Union Pacific Ogden Railroad Facility, Operable Units 1 and 4 (QAPP)1. The Remedial Investigation Report2 and the Ogden Railroad Yard Superfund Site Second Five Year Review3, contain site background and historical data, respectively. Groundwater Gauging and Monitoring Results The 2023 annual monitoring and sampling event, which was performed on October 6th and 19th , included the required long-term monitoring (LTM) activities at OU 1 and OU 4 North as specified in Tables 2-1 and 2-2 of the QAPP. The activities performed at OU 1 included collecting a grab water sample and field duplicate of surface water at Goode Lake for volatile organic compound (VOC) analysis. The surface water sample was collected from the southern bank near the buoys in the eastern portion of the pond (Figure 2). Results of the grab sample are included in Table 1. No constituents of concern were detected above their respective MCLs. The activities performed at OU 4 North included gauging the Weber River and wells 34-MW8 and 34- MW10 to determine whether the Weber River was a gaining stream with respect to the wells. Locations of the wells, the Weber River gauge, and the 2022 estimated vinyl chloride plume and potentiometric contours (Spring 2022) for OU 4 North are included on Figure 3. The gauging results demonstrated that the river was gaining (see Table 2); therefore, a groundwater sample was collected from 34-MW8 and analyzed for monitored natural attenuation (MNA) parameters and VOCs, as specified in the QAPP. Field 1 CH2M HILL, Inc. 2016. Quality Assurance Project Plan, Union Pacific Ogden Railroad Facility, Operable Units 1 and 4. Union Pacific Railroad. Ogden, Utah. Draft. August. 2 Forrester Group. 2003. Remedial Investigation Report. Union Pacific Railroad. Ogden, Utah. Final. September. 3 U.S. Environmental Protection Agency. 2021. Ogden Railroad Yard Superfund Site Second Five Year Review, Weber County, Ogden, UT. July. parameters and MNA results are included in Table 3, and VOC results are included in Table 4. Well 34- MW10 was found to be dry. The sampling logs and laboratory reports are presented in Attachments 1 and 2, respectively, and the data validation report is included in Attachment 3. Groundwater concentrations for COCs were compared with the EPA maximum contaminant levels (MCLs) for drinking water4, where established. No constituents of concern were detected above their respective MCLs. Note that only analytical data for contaminants of concern (COCs) or potential COCs are included in Table 4. Monitoring Well Abandonment Activities In the 2022 Annual Report5, UPRR requested to abandon 5 wells at the site that had blockages or were damaged. Approval of the annual report was provided by the UDEQ in an email dated March 20, 2023. A preliminary inventory of the wells to be abandoned was conducted on September 18, 2023, and it was discovered that well 30-B16(P) could not be located. On September 19th a surveyor was brought on-site to locate the well. The area around the surveyed location was cleared of debris by Durbano Metals. The well could not be located and is considered permanently lost. The remaining 4 wells were abandoned by a Utah licensed driller. Table 5 documents the well abandonment activities and wells to replace the abandoned wells in the monitoring program. These replacement wells were documented and approved in the 2022 Annual Report. Attachment 4 contains the well abandonment logs. In compliance with state regulations, abandonment was completed by attempting to remove the upper 2 feet of well casing beneath the ground surface with a direct-push drill rig and filling the remaining casing and open hole with a Portland cement grout plus bentonite chips. All well completion materials including pads, vaults, and bollards were removed and the ground surface was returned to conditions matching the surrounding area. Non-recyclable waste generated during well abandonment was disposed of as non- hazardous waste at the Weber County Transfer Station. Metal waste (bollards and vaults) were salvaged and stored for future use by UPRR. Path Forward The next monitoring event for the site is the biennial sampling scheduled for spring 2024. This work will be completed in accordance with the QAPP. The next report will be submitted following completion of the fall annual monitoring event. If you have questions or need additional information, please feel free to call me at (385) 474-8535. Sincerely, Jacobs Terence Mares Project Manager cc: Kevin Wangerud/EPA Rebecca Rewey/UPRR 4 U.S. Environmental Protection Agency (EPA). 2023. Regional Screening Level Summary Table. May. 5 Jacobs. 2022. 2022 Annual Groundwater Monitoring Report, Operable Units 1 and 4. Union Pacific Railroad. Ogden, Utah. November. Enclosures Tables 1 Operable Unit 1 CVOC Concentrations 2 Operable Unit 4 North Fluid Level Measurements 3 Operable Unit 4 North MNA Parameters and Measured Field Parameters 4 Operable Unit 4 North CVOC Concentrations 5 Well Abandonment Activities Figures 1 Site Location Map 2 OU1 Map 3 OU4 North CVOC Plume Area 4 OU 4 South Map Attachments 1 Sampling Logs 2 Laboratory Report 3 Data Validation Report 4 Well Abandonment Logs Tables Table 1. Operable Unit 1 CVOC Concentrations 2023 Annual Groundwater Monitoring Report, Operable Units 1 and 4, Union Pacific Railroad, Ogden, Utah Well ID Date Be n z e n e Et h y l b e n z e n e Vi n y l c h l o r i d e Units µg/L µg/L µg/L MCL 5 700 2 09/30/19 <0.079 <0.12 <0.11 02/01/21 <0.0941 <0.137 <0.234 03/17/21 <0.0941 <0.137 <0.234 05/06/22 0.109 J <0.137 <0.234 10/19/23 0.238 J 0.235 J <0.234 Notes: Only compounds detected above the laboratory reporting limit are listed in the table. VOCs analyzed using EPA Method 8260 < = less than the reporting limit µg/L = microgram per liter EPA = U.S. Environmental Protection Agency ID = identification J = The analyte is an estimated value between the reporting limit and the method detection limit. MCL = maximum contaminant level (the maximum concentration of the contaminant allowable by the EPA in drinking water) UJ = Estimated detection limit. The result is estimated and may be a false negative due to related QC problems. Goode Lake Bold Type indicates the analyte detected at or above the MCL or Utah Department of Environmental Quality Initial Screening Level for total petroleum hydrocarbons. AX0228191105SLC PAGE 1 OF 1 Table 2. Operable Unit 4 North Fluid Level Measurements 09/30/19 7.86 4,278.48 06/29/20 8.01 4,278.33 09/29/20 7.66 4,278.68 03/15/21 8.58 4,277.76 09/14/21 7.86 4,278.48 05/02/22 7.66 4,278.68 10/06/23 8.02 4,278.32 09/30/19 10.82 4,278.49 06/29/20 Dry -- 09/29/20 11.21 4,278.10 03/15/21 Dry -- 09/14/21 Dry -- 05/02/22 10.52 4,278.79 10/06/23 Dry -- 09/30/19 13.29 4,278.39 06/29/20 13.92 4,277.76 09/29/20 13.58 4,278.10 03/15/21 13.72 4,277.96 09/14/21 13.63 4,278.05 05/02/22 13.61 4,278.07 10/06/23 13.77 4,277.91 Notes: Well ID amsl = above mean sea level ft = foot (feet) ID = identification 2023 Annual Groundwater Monitoring Report, Operable Units 1 and 4, Union Pacific Railroad, Ogden, Utah Reference Point (ft amsl) Depth to Watera (ft)Date 34-MW8 4,291.68 4,286.34 a Depth to groundwater from top of well casing or river surface from survey reference point. Comments Weber River 34-MW10 4,289.31 Groundwater Elevation (ft amsl) AX0228191105SLC\Table_2_2023OU4North_GW PAGE 1 OF 1 Table 3. Operable Unit 4 North MNA Parameters and Measured Field Parameters 2023 Annual Groundwater Monitoring Report, Operable Units 1 and 4, Union Pacific Railroad, Ogden, Utah Well ID Screen Interval (ft bgs - ft bgs)Date Su l f a t e Ch l o r i d e Al k a l i n i t y a s Ca C O 3 Ni t r a t e Me t h a n e Et h a n e Et h e n e pH Electrical Conductivity Ferrous Iron Dissolved Oxygen Oxidation- reduction Potential Units mg/L mg/L mg/L mg/L µg/L µg/L µg/L mS/cm mg/L mg/L mV 9/30/19 28.4 519 597 0.82 510 [J] 12.9 [J] <2.9 [J] 7.00 2.683 3.30+ 0.31 -141.8 9/29/20 9/14/21 5/5/22 29.9 488 608 0.315 230 <4.07 <4.26 6.68 2.586 2.5 0.52 -62.1 10/6/23 28.7 478 604 <0.05 477 <0.422 4.6 6.85 2.777 3.30+ 2.49 -91.4 9/30/19 23.8 519 547 0.79 270 [J] 7.7 [J] <2.9 [J] 6.89 2.566 3.30+ 0.38 -110.7 9/29/20 9/14/21 5/5/22 28.9 633 628 <0.050 446 <4.07 <4.26 6.74 3.312 3.5 0.34 -121.4 10/6/23 Notes: + = actual value exceeds upper limit of detection < = less than the reporting limit bgs = below ground surface CaCO3 = calcium carbonate ft = foot (feet) J = estimated concentration mg/L = milligram(s) per liter MNA = monitored natural attenuation mS/cm = milliSiemen(s) per centimeter NA = not analyzed No sample collected. Weber River water level is higher or equal to the 34-MW8 monitoring well water level. No sample collected. Weber River water level is higher or equal to the 34-MW8 monitoring well water level. No sample collected. Weber River water level is higher or equal to the 34-MW10 monitoring well water level. Well is dry. No sample collected. Well is dry. No sample collected. 4 - 1434-MW8 5 -1534-MW10 mV = millivolt ID = identification µg/L = microgram(s) per liter ES020112202827SLC\Table_3_2023OU4North_GWData_MNA_FP_v0 PAGE 1 OF 1 Table 4. Operable Unit 4 North CVOC Concentrations 2023 Annual Groundwater Monitoring Report, Operable Units 1 and 4, Union Pacific Railroad, Ogden, Utah Well ID Screen Interval (ft bgs - ft bgs)Date 1, 1 , 1 - T r i c h l o r o e t h a n e 1, 1 , 2 - T r i c h l o r o e t h a n e 1, 1 - D i c h l o r o e t h a n e 1, 1 - D i c h l o r o e t h e n e 1, 2 - D i c h l o r o e t h a n e 1, 4 - D i o x a n e ci s - 1 , 2 - D i c h l o r o e t h e n e tr a n s - 1 , 2 - D i c h l o r o e t h e n e Be n z e n e Ch l o r o e t h a n e ( E t h y l ch l o r i d e ) Ch l o r o m e t h a n e ( M e t h y l ch l o r i d e ) Et h y l b e n z e n e Tr i c h l o r o e t h e n e Te t r a c h l o r o e t h e n e Vi n y l c h l o r i d e Units µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L MCL 200 5 NE 7 5 NE 70 100 5 NE NE 700 5 5 2 09/30/19 <0.12 <0.10 18 <0.22 <0.14 NA 0.79 J <0.17 0.32 J 0.82 J <0.16 <0.12 <0.17 <0.22 5.2 09/29/20 09/14/21 05/05/22 <0.149 <0.158 0.182 J <0.188 <0.0819 <10.0 <0.0941 <0.192 <0.960 0.145 J <0.137 <0.300 <0.149 <0.190 <0.234 10/06/23 <0.149 <0.158 4.91 <0.188 <0.0819 <0.597 0.350 J <0.149 <0.0941 <0.192 <0.960 <0.137 <0.190 <0.300 <0.234 09/30/19 <0.12 <0.10 8.5 <0.22 <0.14 NA 0.70 J <0.17 <0.079 <0.42 <0.16 <0.12 <0.17 <0.22 4.0 09/29/20 09/14/21 05/05/22 <0.149 <0.158 <0.100 <0.188 <0.0819 <10.0 <0.0941 <0.192 <0.960 0.276 J <0.137 <0.300 <0.149 <0.190 <0.234 10/06/23 Notes: Bold Type indicates the analyte detected at or above the MCL < = less than the method detection limit, reported value is the method detection limit µg/L = microgram(s) per liter bgs = below ground surface ft = foot (feet) ID = identification J = This qualifier indicates that the analyte is an estimate value between the reporting limit and the method detection limit. MCL = maximum contaminant level NA = not analyzed NE = not established No sample collected. Weber River water level is higher or equal to the 34-MW8 monitoring well water level. No sample collected. Weber River water level is higher or equal to the 34-MW8 monitoring well water level. No sample collected. Weber River water level is higher or equal to the 34-MW10 monitoring well water level. Well is dry. No sample collected. Well is dry. No sample collected. 4 - 14 34-MW10 5 - 15 CVOC = chlorinated volatile organic compound 34-MW8 AX0228191105SLC PAGE 1 OF 1 Table 5. Monitoring Well Abandonment Activities 2023 Annual Groundwater Monitoring Report, Operable Units 1 and 4, Union Pacific Railroad, Ogden, Utah Sampling Frequency Well Replacement ID Operable Unit 133-MW1 5YR 9/19/2023 SU 2 14.23 Abandoned 33-MW633-MW1FP B 9/19/2023 SU 2 24.60 Abandoned 33-MP233-MW4 5YR 9/19/2023 SU 2 15.37 Abandoned 33-MW8 Operable Unit 4 NorthSPRR3-MW2 5YR 9/18/2023 FM 2 13.00 Abandoned SPRR3-MW3 Operable Unit 4 South30-B16(P)5YR MNA 9/19/2023 SU 2 13.00 Could Not Locate; Assumed Lost 30-MW6D Notes:5YR = 5-yearB = biennialbgs = below ground surfaceFM = flush mountft = foot (feet)ID = identificationin = inches MNA = monitored natural attenuationSU = stick up CommentsDate Abandoned Completion Type Diameter (in)Location ID Total Depth (ft bgs) AX0228191105SLC Page 1 Figures ST204 ST104 ST53 ST104 ST104 9 Coffer Dam G o o d e L a k e Ogden R i v e r 20th St 21st St 24th St Wa l l A v e W e b e r Ri ver 31st St §¨¦I-15 DOWNTOWN OGDEN 44 MILES TO SALT LAKE CITY 9 Buena Ventura Pond and Park FORMER PINTSCHGAS FACILITY \\Dc1vs01\gisproj\U\UPRR\UPRR_Ogden\UPRR_Ogden\MapFiles\2022\GMR\Figure1_SiteLocationMap.mxd AESPEJO 11/6/2023 12:45:46 0 1,000 2,000 Feet LEGEND COMMUTER LINE TRACK APPROXIMATE OGDEN RAILYARDBOUNDARY APPROXIMATE AREA OFINDUSTRIAL SEWER LINEREMEDIATION AND SOURCE AREASOIL REMOVAL APPROXIMATE OU1 SITE BOUNDARY APPROXIMATE OU4 NORTH PLUMEBOUNDARY APPROXIMATE OU4 SOUTH PLUMEBOUNDARY STATE ROUTE 1 inch = 1,000 feet TCE = TRICHLOROETHENE CIS-1, 2-DCE = CIS-1, 2-DICHLOROETHENEMAP EXTENT§¨¦15 §¨¦84 §¨¦15 SouthWeber Uintah WashingtonTerrace Riverdale SouthOgden Roy City WestHaven OgdenCity Marriott-SlatervilleCity FarrWestCity £¤89 MAP INDEX FIGURE 1SITE LOCATION MAP2023 ANNUAL GROUNDWATER MONITORING REPORT, OPERABLE UNITS 1 AND 4 UNION PACIFIC OGDEN RAILROAD FACILITY, OGDEN, UTAH ST204 Notes:Aerial Imagery is 2016 NAIP imagery A AA A AA A A A A A A A A A A A A A A A A AA A A A A A AA A GOODE LAKE OGDEN RIVER 21ST STREET OVERPASS 33-MW9 33-MW8 33-MW6 33-MW4AA 33-MW6FP 33-MW5FP 33-MW4FP 33-MW2FP 33-MW1FP 33-MW10FP 33-MP1 33-RW2 33-MP5 33-MP3 33-MP633-IW1 33-RW1 33-MP4 33-MP2 33-MW5 33-MW4 33-MW3 33-MW11 33-MW5A 33-MW12FP 33-MW11FP 33-MW2 33-MW1 SOURCES:1. THE FORRESTER GROUP, PILOT DNAPL RECOVERY SYSTEM OPERATIONAL REPORT, FEBUARY 2003 (FIGURE 2).2. THE FORRESTER GROUP, OGDEN FEASIBILITY STUDY, SEPTEMBER 2004 (FIGURE 3-4).3. AERIAL IMAGERY IS MICROSOFT BING IMAGERY. \\dc1vs01\GISProj\U\UPRR\UPRR_Ogden\UPRR_Ogden\MapFiles\2023\GMR\Figure2_OU1_Map.mxd AESPEJO 11/3/2023 14:31:25 FIGURE 2OPERABLE UNIT 1 MAP2023 ANNUAL GROUNDWATER MONITORING REPORT, OPERABLE UNITS 1 AND 4UNION PACIFIC OGDEN RAILROAD FACILITY, OGDEN, UTAH 0 200 400 Feet WELL SAMPLING AND GAUGING FREQUENCY A BIENNIAL A FIVE YEAR A WELL GAUGING ONLYFIVE YEAR FREQUENCY A NOT GAUGED OR SAMPLED A GOODE LAKE SURFACE SAMPLE LOCATION A ABANDONED APPROXIMATE EXTENTOF RESIDUAL DNAPL APPROXIMATE OGDEN RAILYARDBOUNDARY 1 inch = 200 feet LEGEND \\dc1vs01\GISProj\U\UPRR\UPRR_Ogden\UPRR_Ogden\MapFiles\2023\GMR\Figure3_OU4N_CVOC_Plume_Area.mxd AESPEJO 11/16/2023 09:32:23 !P WEBER RIVER 21st St 24th St 4274 4 2 8 0 4279 42784277 4275 WEBER RIVER GAUGE(4277.91) 34-MW10(Dry)(NS) 34-MW8(4278.32)(ND) 18-MW1 SPRR3-MW3 34-MW9 34-MW3 38-MW12 34-MW6 22a-MW6 34-MW2 34-MW1 22a-MW3 34-MW7D 38-MW9 38-MW5 38-MW3 35-MW2 35-MW1 34-OB -12 34-OB -17 SPRR3-MW2 34-B1W1 34-B2W2 34-SPMW-02 38-MW8 38-MW6 34-MW4 22a-MW1 34-OB -16 34-SPMW-03 42784277 4279 4 2 7 6 4280 4 2 7 5 4276 4 2 7 4 4281 4 2 8 1 (16) NotesPlume contours based on Spring 2022 results.MNA = Monitored natural attenuationMSL = Mean Sea LevelND = Not detectedNS = N ot sampledAerial Imagery is Microsoft Bing Imagery LEGEND WELL SAMPLING AND GAUGING FREQUENCY A ANNUAL A BIENN IAL A FIVE YEAR A WELL GAUGING ON LYFIVE YEAR FREQU ENCY A FIVE YEAR MN A A ABAND ONED !P RIVER GAUGE (NOT USED FOR POTEN TIOMETRIC C ONTOU R) GR OUNDWATER ELEVATION CONTOUR(FEET ABOVE MSL, SPRING 2022) GR OUNDWATER FLOW DIRECTION(SPRING 2022) VINYL CHLORIDE CONCENTRATION (μg/L, FALL 2023) GR OUNDWATER ELEVATION (FEET ABOVE MSL, FALL 2023) VINYL CHLORIDE CONCENTRATION(µg/L, SPR ING 2022) 4273 2 10 100 (4267.27) FIGURE 3OU4 NORTH CVOC PLUME AREA2023 ANNUAL G ROUND WATER MO NITORING REPORT, OPERABLE UNITS 1 AND 4UNION PACIFIC RAIL ROAD COMPANY, OG DEN, UT 1 inch = 500 feet 0 500250 Feet A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A A 22b-MW1A 30-MW1 22b-MW2D 30-MW6D 26-MW1 21-MW2 26-STMW1 21-MW1A 30-B7(P) 30-B16(P) 20-MW4 30-MW7 26-MW2 20-MW2 30-MW4A 30-MW3 4296 4 3 0 0 4 3 0 1 4298 4297 4 2 9 9 4 2 9 9 4297 4 3 0 0 4 3 0 1 4296 4298 \\dc1vs01\GISProj\U\UPRR\UPRR_Ogden\UPRR_Ogden\MapFiles\2023\GMR\Figure4_OU4S_Map.mxd AESPEJO 11/6/2023 12:40:30 FIGURE 4OU4 SOUTH MAP2023 GR OUNDWATER MON ITOR ING R EPO RT, OPERABLE UNITS 1 AND 4UNION PACIFIC RAIL ROAD COMPANY, OG DEN, UT LEGEND WELL SAMPLING AND GAUGING FREQUENCY A BIENNIAL A FIVE YEAR A FIVE YEAR GAUGE A FIVE YEAR MNA A ABAND ONED VINYL CHLORIDE CONCENTRATION 2 µg/L 10 µg/L GR OUNDWATER ELEVATION CONTOUR(FEET ABOVE MSL, SPRING 2022) GR OUNDWATER FLOW DIRECTION(SPRING 2022) NotesPlume contours based on Spring 2022 results.Aerial Imagery is Microsoft Bing Imagery. 0 500250 Feet1 inch = 500 feet 4301 Attachment 1 Sampling Logs Attachment 2 Laboratory Reports Attachment 3 Data Validation Report GHD | Union Pacific Railroad | 11183954-95-03-1990 | Data Verification Report 1 Data Verification Report November 16, 2023 To Terence Mares Project No. 11183954-95-03-1990 Copy to Jesse Orth, Julie Lidstone DVR No. N/A From Jeffrey Cloud/eew/1671 Contact No. 1 971 925 3756 Project Name Union Pacific Railroad (UPRR) Email Jeffrey.Cloud@ghd.com Subject Analytical Results and Data Verification of Report L1664159 Annual Sampling Event SP Yard Ogden, Utah October 2023 The services undertaken by GHD in connection with preparing this report were limited to those specifically detailed in the report and are subject to the scope limitations set out in the report. 1.Introduction This document details a data verification of analytical results for a water sample collected in support of the Annual Sampling Event at the SP Yard site in Ogden, Utah during October 2023. The sample was submitted to Pace National Center for Testing and Innovation, located in Mt. Juliet, Tennessee. A sample collection and analysis summary is presented in Table 1. A summary of the analytical methodology is presented in Table 2. The validated analytical results are summarized in Table 3. Standard GHD report deliverables were submitted by the laboratory. The analytical results and supporting quality assurance/quality control (QA/QC) data were assessed. Evaluation of the data was based on information obtained from the chain of custody form, finished report forms, method blank data, recovery data from surrogate spikes, laboratory control data and field QC data. The QA/QC criteria by which these data have been assessed are outlined in the analytical methods referenced in Table 2 and applicable guidance from the documents entitled: 1."National Functional Guidelines for Organic Superfund Methods Data Review", United States EnvironmentalProtection Agency (USEPA) 540-R-20-005, November 2020 2."National Functional Guidelines for Inorganic Superfund Methods Data Review", United States EnvironmentalProtection Agency (USEPA) 542-R-20-006, November 2020 These items will subsequently be referred to as the "Guidelines" in this report. GHD | Union Pacific Railroad | 11183954-95-03-1990 | Data Verification Report 2 2. Sample Holding Time and Preservation The sample holding time criteria and sample preservation requirements for the requested parameters are summarized in the methods. The sample chain of custody document and analytical report were used to determine sample holding times. The sample was prepared and analyzed within the required holding times. All sample containers were properly preserved, delivered on ice and stored by the laboratory at the required temperature (0-6°C). 3. Laboratory Method Blank Analyses Method blanks are prepared from a purified matrix and analyzed with investigative samples to determine the existence and magnitude of sample contamination introduced during the analytical procedures. For this study, laboratory method blanks were analyzed at a minimum frequency of one per analytical batch. All method blank results were non-detect, indicating that laboratory contamination was not a factor for this investigation. 4. Surrogate Spike Recoveries In accordance with the method employed, all samples, blanks, and QC samples analyzed for organics are spiked with surrogate compounds prior to sample analysis. Surrogate recoveries provide a means to evaluate the effects of laboratory performance on individual sample matrices. The sample submitted for volatile organic compound (VOC) and 1,4-dioxane analysis was spiked with the appropriate number of surrogate compounds prior to sample analysis. Surrogate recoveries were assessed against the control limits. All surrogate recoveries met the associated criteria. 5. Laboratory Control Sample Analyses Laboratory control samples (LCS)/laboratory control sample duplicates (LCSD) are prepared and analyzed as samples to assess the analytical efficiencies of the methods employed, independent of sample matrix effects. The relative percent difference (RPD) of the LCS/LCSD recoveries is used to evaluate analytical precision. For this study, LCS or LCS/LCSD were analyzed at a minimum frequency of one per analytical batch. 5.1 Organic Analyses The LCS/LCSD contained all analytes of interest. All LCS/LCSD recoveries and RPDs were within associated control limits, demonstrating acceptable analytical accuracy and precision. 5.2 Inorganic Analyses The LCS contained all analytes of interest. LCS recoveries were assessed per the "Guidelines". All LCS recoveries were within the control limits, demonstrating acceptable analytical accuracy. GHD | Union Pacific Railroad | 11183954-95-03-1990 | Data Verification Report 3 6. Field QA/QC Samples The field QA/QC consisted of one trip blank sample. To evaluate contamination from sample collection, transportation, storage, and analytical activities, one trip blank was submitted to the laboratory for analysis. All results were non-detect for the analytes of interest. 7.Analyte Reporting Data were reported down to the laboratory’s quantitation limit (QL), which is defined as the method detection limit (MDL)with sample-specific adjustments for dilutions, aliquot size, volumes, etc. One positive analyte detection lessthan the reporting limit (RL) but greater than the QL was reported as estimated (J) in Table 3. Non-detect results werepresented as non-detect at the QL in Table 3. 8.Conclusion Based on the assessment detailed in the foregoing, the summarized data are acceptable without qualification. Regards Jeffrey Cloud Data Management Team – Data Validator Page 1 of 1 Table 1 Sample Collection and Analysis Summary Annual Sampling Event Union Pacific Railroad (UPRR) - SP Yard Ogden, Utah October 2023 Analysis/Parameters Location Matrix Collection Date Collection Time An i o n s Di s s o l v e d G a s e s Al k a l i n i t y VO C s 1, 4 - D i o x a n e Comments (mm/dd/yyyy)(hr:min) 34-MW8 34-MW8 Water 10/06/2023 13:00 X X X X X TB-1 --Water 10/06/2023 --X Trip Blank Notes: VOCs - Volatile Organic Compounds "--"- Not Applicable Sample Identification GHD 11183954-MEM-1671-Tbls.xlsx Page 1 of 1 Table 2 Analytical Methods Annual Sampling Event Union Pacific Railroad (UPRR) - SP Yard Ogden, Utah October 2023 Parameter Method Matrix Volatile Organic Compounds (VOCs)SW-846 8260B(1)Water 1,4-Dioxane SW-846 8260B SIM(1)Water Dissolved Gases RSK-175(2)Water Alkalinity SM 2320B(3)Water Anions SW-846 9056A(1)Water EPA 353.2(4)Water Notes: (1)- SW-846 - "Test Methods for Evaluating Solid Waste, Physical/Chemical Methods", SW-846, Third Edition, 1986, with subsequent revisions (2)- EPA-RSK SOP 175 - EPA Internal Standard Operating Procedure #175 dated 8/11/94 by Bryan Newell at the USEPA R.S. Kerr Laboratory (3)- SM - "Standard Methods for the Examination of Water and Wastewater", 18th Edition, 1992, with subsequent revisions (4)- EPA - MCAWW - “Methods for Chemical Analysis of Water and Waste,” EPA-600/4-79-020, revised March 1983, with subsequent revisions SIM - Selective Ion Monitoring GHD 11183954-MEM-1671-Tbls.xlsx Table 3 Analytical Results Summary Annual Sampling Event Union Pacific Railroad (UPRR) - SP Yard Ogden, Utah October 2023 Page 1 of 1 Location ID:34-MW8 Sample Name:34-MW8 Sample Date:10/06/2023 Parameters Unit Volatile Organic Compounds 1,1,1-Trichloroethane µg/L <0.149 1,1,2-Trichloroethane µg/L <0.158 1,1-Dichloroethane µg/L 4.91 1,1-Dichloroethene µg/L <0.188 1,2-Dichloroethane µg/L <0.0819 Benzene µg/L <0.0941 Chloroethane µg/L <0.192 Chloromethane (Methyl chloride)µg/L <0.960 cis-1,2-Dichloroethene µg/L 0.350 J Ethylbenzene µg/L <0.137 Tetrachloroethene µg/L <0.300 trans-1,2-Dichloroethene µg/L <0.149 Trichloroethene µg/L <0.190 Vinyl chloride µg/L <0.234 Volatile Organic Compounds, SIM 1,4-Dioxane µg/L <0.597 Dissolved Gases Ethane µg/L 4.60 Ethene µg/L <0.422 Methane µg/L 477 General Chemistry Alkalinity, bicarbonate µg/L 604000 Alkalinity, carbonate µg/L <8450 Alkalinity, total (as CaCO3)µg/L 604000 Chloride µg/L 478000 Nitrite/Nitrate µg/L <50.0 Sulfate µg/L 28700 Notes: < - Not detected at the associated reporting limit J - Estimated concentration SIM - Selective Ion Monitoring GHD 11183954-MEM-1671-Tbls.xlsx Data Verification Report GHD | Union Pacific Railroad | 11183954-95-03-1990 | Data Verification Report 1 November 16, 2023 To Terence Mares Project No. 11183954-95-03-1990 Copy to Jesse Orth, Julie Lidstone DVR No. N/A From Jeffrey Cloud/eew/1673 Contact No. 1 971 925 3756 Project Name Union Pacific Railroad (UPRR) Email Jeffrey.Cloud@ghd.com Subject Analytical Results and Data Verification of Report L1668803 Annual Goode Lake Sampling Event SP Yard Ogden, Utah October 2023 The services undertaken by GHD in connection with preparing this report were limited to those specifically detailed in the report and are subject to the scope limitations set out in the report. 1. Introduction This document details a data verification of analytical results for a water sample collected in support of the Annual Goode Lake Sampling Event at the SP Yard site in Ogden, Utah during October 2023. The sample was submitted to Pace National Center for Testing and Innovation, located in Mt. Juliet, Tennessee. A sample collection and analysis summary is presented in Table 1. A summary of the analytical methodology is presented in Table 2. The validated analytical results are summarized in Table 3. Standard GHD report deliverables were submitted by the laboratory. The analytical results and supporting quality assurance/quality control (QA/QC) data were assessed. Evaluation of the data was based on information obtained from the chain of custody form, finished report forms, method blank data, recovery data from surrogate spikes, laboratory control data and field QC data. The QA/QC criteria by which these data have been assessed are outlined in the analytical method referenced in Table 2 and applicable guidance from the document entitled "National Functional Guidelines for Organic Superfund Methods Data Review", United States Environmental Protection Agency (USEPA) 540-R-20-005, November 2020. 2. Sample Holding Time and Preservation The sample holding time criterion and sample preservation requirements for the requested parameter are summarized in the method. The sample chain of custody document and analytical report were used to determine the sample holding time. The sample was analyzed within the required holding time. All sample containers were properly preserved, delivered on ice and stored by the laboratory at the required temperature (0-6°C). GHD | Union Pacific Railroad | 11183954-95-03-1990 | Data Verification Report 2 3. Laboratory Method Blank Analyses Method blanks are prepared from a purified matrix and analyzed with investigative samples to determine the existence and magnitude of sample contamination introduced during the analytical procedures. For this study, laboratory method blanks were analyzed at a minimum frequency of one per analytical batch. All method blank results were non-detect, indicating that laboratory contamination was not a factor for this investigation. 4. Surrogate Spike Recoveries In accordance with the method employed, all samples, blanks, and QC samples analyzed for organics are spiked with surrogate compounds prior to sample analysis. Surrogate recoveries provide a means to evaluate the effects of laboratory performance on individual sample matrices. The sample submitted for volatile organic compound (VOC) analysis was spiked with the appropriate number of surrogate compounds prior to sample analysis. Surrogate recoveries were assessed against the control limits. All surrogate recoveries met the associated criteria. 5. Laboratory Control Sample Analyses Laboratory control samples (LCS) are prepared and analyzed as samples to assess the analytical efficiencies of the method employed, independent of sample matrix effects. For this study, LCS were analyzed at a minimum frequency of one per analytical batch. The LCS contained all analytes of interest. All LCS recoveries were within associated control limits, demonstrating acceptable analytical accuracy with the exception of one high tetrachloroethene recovery. The associated sample result was non-detect and was not impacted. No qualification of the data was deemed necessary. 6. Field QA/QC Samples The field QA/QC consisted of one trip blank sample. To evaluate contamination from sample collection, transportation, storage, and analytical activities, one trip blank was submitted to the laboratory for analysis. All results were non-detect for the analytes of interest. 7. Analyte Reporting Data were reported down to the laboratory’s quantitation limit (QL), which is defined as the method detection limit (MDL) with sample-specific adjustments for dilutions, aliquot size, volumes, etc. Positive analyte detections less than the reporting limit (RL) but greater than the QL were reported as estimated (J) in Table 3. Non-detect results were presented as non-detect at the QL in Table 3. GHD | Union Pacific Railroad | 11183954-95-03-1990 | Data Verification Report 3 8.Conclusion Based on the assessment detailed in the foregoing, the summarized data are acceptable without qualification. Regards Jeffrey Cloud Data Management Team – Data Validator Page 1 of 1 Table 1 Sample Collection and Analysis Summary Annual Goode Lake Sampling Event Union Pacific Railroad (UPRR) - SP Yard Ogden, Utah October 2023 Analysis/Parameters Location Matrix Collection Date Collection Time VOCs Comments (mm/dd/yyyy)(hr:min) GOODE LAKE Goode Lake Water 10/19/2023 10:00 X TB-1 --Water 10/19/2023 --X Trip Blank Notes: VOCs - Volatile Organic Compounds "--"- Not Applicable Sample Identification GHD 11183954-MEM-1673-Tbls.xlsx Page 1 of 1 Table 2 Analytical Methods Annual Goode Lake Sampling Event Union Pacific Railroad (UPRR) - SP Yard Ogden, Utah October 2023 Parameter Method Matrix Volatile Organic Compounds (VOCs)SW-846 8260B(1)Water Notes: (1)- SW-846 - "Test Methods for Evaluating Solid Waste, Physical/Chemical Methods", SW-846, Third Edition, 1986, with subsequent revisions GHD 11183954-MEM-1673-Tbls.xlsx Table 3 Analytical Results Summary Annual Goode Lake Sampling Event Union Pacific Railroad (UPRR) - SP Yard Ogden, Utah October 2023 Page 1 of 1 Location ID:Goode Lake Sample Name:GOODE LAKE Sample Date:10/19/2023 Parameters Unit Volatile Organic Compounds 1,1,1-Trichloroethane µg/L <0.149 1,1,2-Trichloroethane µg/L <0.158 1,1-Dichloroethane µg/L <0.100 1,1-Dichloroethene µg/L <0.188 1,2-Dichloroethane µg/L <0.0819 Benzene µg/L 0.238 J Chloroethane µg/L <0.192 Chloromethane (Methyl chloride)µg/L <0.960 cis-1,2-Dichloroethene µg/L <0.126 Ethylbenzene µg/L 0.235 J Tetrachloroethene µg/L <0.300 trans-1,2-Dichloroethene µg/L <0.149 Trichloroethene µg/L <0.190 Vinyl chloride µg/L <0.234 Notes: < - Not detected at the associated reporting limit J - Estimated concentration GHD 11183954-MEM-1673-Tbls.xlsx Attachment 4 Well Abandonment Logs Date 9/18/2023 Weather Sunny Well Loc ID 30‐B16(P) Field Personnel Carol Gross Operable Unit 4 South Subcontractor RMEC Start Time 845 End Time Well Depth (ft) Casing Type PVC Water Level (ft) Casing Diamter (in) 2  Length of Casing Removed (ft) Length of Casing Left In Place (ft) Grout Volume Placed Type of Grout Existing (old) Surface  Completion: New Surface  Patch: Asphalt Asphalt Concrete Concrete Natural/Dirt X Natural/Dirt X Other: Other: Stick‐up X Bollards (Quantity) Flush‐Mount Notes:Could not locate well. Surveyor on‐site on 9/19/2023 to locate well. Durbano Metals moved debris and dug in location of the well coordinates. No PVC  or completion found.  Monitoring Well Abandonment Form Date 9/19/2023 Weather Sunny Well Loc ID 33‐MW1 Field Personnel Carol Gross Operable Unit 1 Subcontractor RMEC Start Time 1045 End Time 1600 Well Depth (ft) 14.23 Casing Type PVC Water Level (ft) 7.06 Casing Diamter (in) 2  Length of Casing Removed (ft) ~4.5 feet Length of Casing Left In Place (ft) ~13.7 feet Grout Volume Placed approximately 1.1 gallons plus bentonite chips Type of Grout Portland Cement 1/11 Existing (old) Surface  Completion: New Surface  Patch: Asphalt Asphalt Concrete Concrete Natural/Dirt X Natural/Dirt X Other: Other: Stick‐up X Bollards (Quantity) 2 Flush‐Mount Notes:Started removing bollards at 1045. Came back to site 1405 to abandon. Filled in the top  surface with native material. Monitoring Well Abandonment Form Date 9/19/2023 Weather Sunny Well Loc ID 33‐MW1FP Field Personnel Carol Gross Operable Unit 1 Subcontractor RMEC Start Time 1045 End Time 1600 Well Depth (ft) 24.60 Casing Type PVC Water Level (ft) 6.97 Casing Diamter (in) 2  Length of Casing Removed (ft) ~4.5 feet Length of Casing Left In Place (ft) ~20 feet Grout Volume Placed approximately 2.5 gallons plus bentonite chips Type of Grout Portland Cement 1/11 Existing (old) Surface  Completion: New Surface  Patch: Asphalt Asphalt Concrete Concrete Natural/Dirt X Natural/Dirt X Other: Other: Stick‐up X Bollards (Quantity) 2 Flush‐Mount Notes:Started removing bollards at 1045. Came back to site 1405 to abandon. Filled in the top  surface with native material. Monitoring Well Abandonment Form Date 9/19/2023 Weather Sunny Well Loc ID 33‐MW4 Field Personnel Carol Gross Operable Unit 1 Subcontractor RMEC Start Time 930 End Time 1030 Well Depth (ft) 15.37 Casing Type PVC Water Level (ft) 10.50 Casing Diamter (in) 2  Length of Casing Removed (ft) ~4.5 feet  Length of Casing Left In Place (ft) ~11 feet Grout Volume Placed approximately 1.00 gallons + bentonite Type of Grout Portland Cement 1/11 Existing (old) Surface  Completion: New Surface  Patch: Asphalt Asphalt Concrete Concrete Natural/Dirt X Natural/Dirt X Other: Other: Stick‐up X Bollards (Quantity) 2 Flush‐Mount Notes:Filled in the top surface with native material. Salvaged stick up completion and bollards.  Monitoring Well Abandonment Form Date 9/18/2023 Weather Sunny Well Loc ID SPRR3‐MW2 Field Personnel Carol Gross Operable Unit 4 North Subcontractor RMEC Start Time 745 End Time 850 Well Depth (ft) 13 Casing Type PVC Water Level (ft) NA ‐ well plugged Casing Diamter (in) 2  Length of Casing Removed (ft) 8 inches which was approximately 2 feet bgs Length of Casing Left In Place (ft) ~12 feet Grout Volume Placed approximately 1 gallon + bentonite Type of Grout Portland Cement 1/11 Existing (old) Surface  Completion: New Surface  Patch: Asphalt Asphalt Concrete Concrete Natural/Dirt X Natural/Dirt X Other: Other: Stick‐up Bollards (Quantity) Flush‐Mount X Notes:Filled in the top surface with native material. Monitoring Well Abandonment Form