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HomeMy WebLinkAboutDAQ-2024-0120791 DAQC-CI108370001-24 Site ID 10837 (B1) MEMORANDUM TO: FILE – FLOWSERVE CORPORATION – Automatic Control Valves and Sub-component Manufacturer THROUGH: Chad Gilgen, Minor Source Compliance Section Manager FROM: Daniel Riddle, Environmental Scientist DATE: December 10, 2024 SUBJECT: FULL COMPLIANCE EVALUATION, Minor, Utah County INSPECTION DATE: November 8, 2024 SOURCE LOCATION: 1350 North Mountain Springs Parkway Springville, UT 84663 SOURCE CONTACTS: Brian Pike, Safety, Health, and ESA Manager 801-489-2489 bpike@flowserve.com OPERATING STATUS: Operating, however the paint booths, sand blasting, and generator were not in operation during the inspection. PROCESS DESCRIPTION: The source manufactures automatic control valves and valve subcomponents. The process begins with the machining down of the steel to the finishing of the valves. Two paint booths are present onsite and vented to the atmosphere. Also, some sandblasting operations occur which includes venting the exhaust through a baghouse. APPLICABLE REGULATIONS: Approval Order (AO) DAQE-AN108370002-14, dated September 22, 2014 MACT (Part 63) ZZZZ: National Emissions Standards for Hazardous Air Pollutants for Stationary Reciprocating Internal Combustion Engines, SOURCE EVALUATION: Name of Permittee: Permitted Location: Flowserve Corporation - Automatic Control Valves and Sub-component Manufacturer 1350 North Mountain Springs Parkway P.O. Box 220 1350 North Mountain Springs Parkway Springville, UT 846630903 Springville, UT 846630220 SIC Code: 3494: (Valves & Pipe Fittings, NEC) ) $ ' $ ' 2 Section I: GENERAL PROVISIONS I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101] I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401] I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1] I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8] I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307-401-4] I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107] I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150] Status: In Compliance. No limits set forth in this AO appear to have been exceeded. The source stated that there have been no modifications to the equipment or processes. The equipment appeared to be properly operated and maintained according to manufacturer recommendations. Records are kept as required and were made available after the inspection. No breakdowns have been reported since the previous inspection. An emissions inventory was submitted for 2023, and emissions data are reported below. Section II: SPECIAL PROVISIONS II.A The approved installations shall consist of the following equipment: II.A.1 Flowserve Corporation Automatic control valves and sub-component manufacturer II.A.2 Natural Gas-Fired Ovens Two (2) rated at 0.75 MMBtu/hr each II.A.3 Paint Booth One (1) Binks* Model CPFA-10-8-T-LH* (10'W x 8'H x 11'D) II.A.4 Paint Booth One (1) Blecker* paint booth, Model SPF-14-10-10* (14'W x 10'H x 10'D) II.A.5 Paint Booth - new equipment One (1) paint booth controlled with dry filter pads II.A.6 Anodizing Equipment Miscellaneous anodizing equipment 3 II.A.7 Sandblasting Operations Sandblasting booth and baghouse II.A.8 Welding Booth Miscellaneous welding equipment * Brand names and models are for information only Status: In Compliance. The equipment observed on site is consistent with that listed with two exceptions. The Binks paint booth has been removed and there is an existing 75 kW emergency generator that was discovered during an inspection in 2015. The generator operates on natural gas. The hour meter read at 676.1 hrs at the time of inspection. II.B Requirements and Limitations II.B.1 Site-Wide Requirements. II.B.1.a Visible emissions from any point or fugitive emission source associated with the installation or control facilities shall not exceed 10% opacity. [R307-401-8] II.B.1.a.1 Opacity observations of emissions from stationary sources shall be conducted in accordance with 40 CFR 60, Appendix A, Method 9. [R307-401-8] Status: In Compliance. No visible emissions were observed from any point at the time of inspection. Method 9 was utilized to verify opacity limits. See attached VEO form. II.B.2 Conditions on the New Paint Booth II.B.2.a Flowserve Corporation shall notify the Director in writing when the new paint booth listed in Condition #II.A has been installed and is operational. To ensure proper credit when notifying the Director, send your correspondence to the Director, attn: Compliance Section. If the installation has not been completed within 18 months from the date of this AO, the Director shall be notified in writing on the status of the installation. At that time, the Director shall require documentation of the continuous installation of the equipment and may revoke the AO. [R307-401-18] Status: In Compliance. Notification was made and is located in the source file. II.B.3 Conditions on All Paint Booths II.B.3.a The paint booths shall be equipped with Andrea exhaust filter media made of non-fire supporting paper paint arrestor filters or equivalent to control particulate emissions. All air exiting the booths shall pass through this control system before being vented to the atmosphere. [R307-401-8] Status: In Compliance. The paint booths were fully equipped with filters that appeared to be in good condition. Filters are changed as need, and monometers indicate air flow through the filters. II.B.3.b The owner/operator shall comply with applicable requirements and limitations in R307-350. [R307-350] Status: In Compliance. CARBOGUARD 893 Part A from Carboline is used to coat products. It has a VOC content of 195 g/L or 1.68 lb/gal, in compliance with the limits in Table 1 of this rule. A Klean-Strip paint thinner is used for solvent cleaning. It has a vapor pressure of 0.3 mm Hg at 20 degrees Celsius. See the attached SDS for more information. 4 II.B.4 VOC and HAP Limitations II.B.4.a The plant-wide emissions of VOCs and HAPs from the paint booths and associated operations shall not exceed: 10.00 tons per rolling 12-month period for VOCs including all HAPs below 254 pounds per rolling 12-month period for ethyl benzene 26 pounds per rolling 12-month period for formaldehyde 173 pounds per rolling 12-month period for methanol 101 pounds per rolling 12-month period for methyl isobutyl ketone 965 pounds per rolling 12-month period for toluene 1421 pounds per rolling 12-month period for xylene 1.47 tons per rolling 12-month period for total HAPs. [R307-401-8] II.B.4.a.1 Compliance with the limitations shall be determined on a rolling 12-month total. No later than 20 days after the end of each month, a new 12-month total shall be calculated using data from the previous 12 months. The records of consumption shall be kept on a monthly basis. [R307-401-8] II.B.4.a.2 The VOC and HAP emissions shall be determined by maintaining a record of VOC- and HAP-emitting materials used each month. The record shall include the following data for each material used: A. Name of the VOC- and HAP-emitting material, such as: paint, adhesive, solvent, thinner, reducers, etc. B. Density of each material used (pounds per gallon) C. Percent by weight of all VOC and HAP in each material used D. Gallons of each VOC- and HAP-emitting material used E. The amount of VOC and HAP emitted monthly by each material used shall be calculated by the following procedure: VOC = % VOC by Weight x [Density ( lb )] x Gal Consumed x 1 ton (100) (gal) 2000 lb HAP = % HAP by Weight x [Density ( lb )] x Gal Consumed x 1 ton (100) (gal) 2000 lb F. The amount of VOC or HAP emitted monthly from all materials used. G. The amount of VOCs or HAPs reclaimed for the month shall be similarly quantified and subtracted from the quantities calculated above to provide the monthly total VOC or HAP emissions. [R307-401-8] Status: In Compliance. Emissions appear to be calculated correctly. For the rolling 12-month period from October 2023 - September 2024, emissions are as follows: 0.4944 tons for VOCs 0 lbs for ethyl benzene 0 lbs for formaldehyde 0 lbs for methanol 0 lbs for methyl isobutyl ketone 0.01 lbs for toluene 970.78 lbs for xylene 0.49415 tons for all HAPS See the attached table for more information. 5 II.B.5 Conditions on the Sandblasting Operations. II.B.5.a The baghouse shall control process streams from the sandblasting operations. All exhaust air from the sandblasting operations shall be routed through the baghouse before being vented to the atmosphere. [R307-401-8] Status: In Compliance. The sandblasting operations are routed through the baghouse. II.B.5.b Sandblasting operations shall be limited to 3,000 hours per rolling 12-month period. [R307-401-8] II.B.5.b.1 To determine compliance with a rolling 12-month total, the owner/operator shall calculate a new 12-month total by the twentieth day of each month using data from the previous 12 months. Records of hours of operation shall be kept for all periods when the plant is in operation. The records of hours of operation shall be kept on a daily basis. Hours of operation shall be determined by supervisor monitoring and maintaining of an operations log. [R307-401-8] Status: In Compliance. For the rolling 12-month period from October 2023 - September 2024, sandblasting took place for a total of 214 hours. See the attached table for more information. Section III: APPLICABLE FEDERAL REQUIREMENTS In addition to the requirements of this AO, all applicable provisions of the following federal programs have been found to apply to this installation. This AO in no way releases the owner or operator from any liability for compliance with all other applicable federal, state, and local regulations including UAC R307. MACT (Part 63) ZZZZ: National Emissions Standards for Hazardous Air Pollutants for Stationary Reciprocating Internal Combustion Engines Status: In Compliance. There is an existing 75 kW emergency generator that was discovered during an inspection in 2015. The generator operates on natural gas. A Warning (DAQC-1568-15) was issued under the condition that the source would add it to the equipment list the next time a modification is made to the AO. The generator has been operated for a total of 15 hours in 2024. AREA SOURCE RULES EVALUATION: The following Area Source Rules were evaluated during this inspection: National Emission Standards for Hazardous Air Pollutants [R307-214] Status: In Compliance. Compliance with this area source rule is satisfied by compliance with Federal Requirement MACT (Part 63) Subpart ZZZZ. See Section III above for more information. PM10 Nonattainment and Maintenance Areas: Abrasive Blasting [R307-306] Status: In Compliance. Sandblasting is conducted in an enclosed room which vents through a baghouse. No visible emissions were observed at the time of inspection. Miscellaneous Metal Parts and Products Coatings [R307-350] Status: In Compliance. See status of condition II.B.3.b for more information. 6 EMISSION INVENTORY: Listed below are the Actual Emissions Inventory provided from Flowserve Corporation - Automatic Control Valves and Sub-component Manufacturer for the 2023 emissions reporting year. A comparison of the estimated total potential emissions (PTE) on AO: DAQE-AN108370002-14, dated September 22, 2014, is provided. PTE are supplied for supplemental purposes only. Criteria Pollutant PTE tons/yr Actuals tons/yr CO2 Equivalent 258.00 N/A Carbon Monoxide 0.03 0.00962 Nitrogen Oxides 0.25 0.002835 Particulate Matter - PM10 0.88 0.15534 Particulate Matter - PM2.5 0.88 0.00173 Sulfur Dioxide 0.00 0.00007 Volatile Organic Compounds 10.00 0.07621 Hazardous Air Pollutant PTE lbs/yr Actuals lbs/yr Ethyl Benzene (CAS #100414) 260 N/A Formaldehyde (CAS #50000) 20 N/A Methanol (CAS #67561) 180 N/A Methyl Isobutyl Ketone (Hexone) (CAS #108101) 100 N/A Toluene (CAS #108883) 960 N/A Xylenes (Isomers And Mixture) (CAS #1330207) 1420 N/A PREVIOUS ENFORCEMENT ACTIONS: No enforcement action within the past five years. COMPLIANCE STATUS & RECOMMENDATIONS: In regards to Approval Order (AO) DAQE-AN108370002-14, dated September 22, 2014, the overall status is: In Compliance. The facility appears to be well maintained and operated. Required records were current and made available during the inspection. HPV STATUS: Not Applicable. RECOMMENDATION FOR NEXT INSPECTION: Inspect as normal. NSR RECOMMENDATIONS: Add the pre-existing 75 kW generator to the equipment list with the next AO modification. ATTACHMENTS: VEO form, email correspondence, rolling 12s, generator usage, SDS Daniel Riddle <driddle@utah.gov> 10837 - Follow up to air quality inspection 8 messages Daniel Riddle <driddle@utah.gov>Fri, Nov 8, 2024 at 9:35 AM To: bpike@flowserve.com Brian, Thank you for meeting today for your air quality inspection. As discussed, here are the records I will require to complete my inspection report: From AO DAQE- AN108370002-14 (attached): Condition II.B.4.a - VOC and HAP emissions, itemized as required (Oct 23 - Sept 24) Condition II.B.5.b - hours of sandblasting operations (Oct 23 - Sept 24) 40 CFR Part 63 Subpart ZZZZ (https://www.ecfr.gov/current/title-40/chapter-I/subchapter-C/part-63/subpart-ZZZZ) hours of usage for maintenance of the 75 kW natural gas generator (Oct 23 - Sept 24) Additionally, for Condition II.B.3.b / UAC R307-350 (attached): 307-350-5 - For any products that would fall under Table 1, I need a copy of an SDS or EDS or TDS that shows the VOC content in the appropriate units and shows it is compliant with the limits 307-350-7 - If any solvent cleaning products are used (such as for cleaning paint brushes), I need an SDS or EDS or TDS for the product(s) that shows the VOC composite vapor pressure is no greater than 1 mmHG at 20 degrees Celsius Please provide these records by November 15, 2024. Let me know if you have any questions. Best, Daniel 2 attachments R307-350.pdf 99K 10837 AO.pdf 3512K Pike, Brian <BPike@flowserve.com>Tue, Nov 12, 2024 at 8:27 AM To: Daniel Riddle <driddle@utah.gov> Daniel, I have attached all the requested data we discussed. Please let me know if you need anything else. Thank You Brian Pike HSE Manager Flowserve Corporation 11/21/24, 9:57 AM State of Utah Mail - 10837 - Follow up to air quality inspection https://mail.google.com/mail/u/0/?ik=3e54b7a6bd&view=pt&search=all&permthid=thread-a:r8774165004592784359&simpl=msg-a:r-25473196991783…1/6 1350 N. Mountain Springs Pkwy Springville, Utah 84663 Office: (801) 489-2226 Cell: (385) 327-9637 Email: bpike@flowserve.com From: Daniel Riddle <driddle@utah.gov> Sent: Friday, November 8, 2024 9:35 AM To: Pike, Brian <BPike@flowserve.com> Subject: [External] 10837 - Follow up to air quality inspecon CAUTION: This email originated from outside of Flowserve. Do not click links or open attachments unless you can confirm the sender and know the content is safe. [Quoted text hidden] 4 attachments IMG_1458.jpeg 2892K Thinner SDS.pdf 404K Carboguard 893 SDS.pdf 416K VOC_HAPs_SandblastTotals.xlsx 22K Daniel Riddle <driddle@utah.gov>Tue, Nov 12, 2024 at 9:39 AM To: "Pike, Brian" <BPike@flowserve.com> 11/21/24, 9:57 AM State of Utah Mail - 10837 - Follow up to air quality inspection https://mail.google.com/mail/u/0/?ik=3e54b7a6bd&view=pt&search=all&permthid=thread-a:r8774165004592784359&simpl=msg-a:r-25473196991783…2/6 Thank you - I'll look it over and let you know if we need anything else. [Quoted text hidden] Daniel Riddle <driddle@utah.gov>Wed, Nov 20, 2024 at 2:56 PM To: "Pike, Brian" <BPike@flowserve.com> Brian, The thinner you are using may not be compliant with R307-350. The SDS you sent me shows a vapor pressure of 4.8 mmHg at 20 degrees Celsius. It also has a relatively high VOC content of 909 g/L. R307-350-7(2) states: I'm attaching a SDS for a similar compliant product. You can see that the vapor pressure is only 0.22 mmHg at room temperature. At this time, if you can commit to discontinuing this thinner and switching to a compliant thinner no later than November 2025, we can mark this as out of compliance with no action recommended. Please let me know if you have any questions. [Quoted text hidden] Paint-thinner-kleanstrip.pdf 24K Pike, Brian <BPike@flowserve.com>Wed, Nov 20, 2024 at 3:17 PM To: Daniel Riddle <driddle@utah.gov> Daniel, Thank You for bringing this to our attention, we have been using Klean Strip and I sent the old SDS (by Mistake)… We are using Klean Strip (See Pic Below). We will commit to continue to use as well. Thank You! 11/21/24, 9:57 AM State of Utah Mail - 10837 - Follow up to air quality inspection https://mail.google.com/mail/u/0/?ik=3e54b7a6bd&view=pt&search=all&permthid=thread-a:r8774165004592784359&simpl=msg-a:r-25473196991783…3/6 Brian Pike HSE Manager Flowserve Corporation 1350 N. Mountain Springs Pkwy Springville, Utah 84663 Office: (801) 489-2226 Cell: (385) 327-9637 Email: bpike@flowserve.com 11/21/24, 9:57 AM State of Utah Mail - 10837 - Follow up to air quality inspection https://mail.google.com/mail/u/0/?ik=3e54b7a6bd&view=pt&search=all&permthid=thread-a:r8774165004592784359&simpl=msg-a:r-25473196991783…4/6 From: Daniel Riddle <driddle@utah.gov> Sent: Wednesday, November 20, 2024 2:56 PM To: Pike, Brian <BPike@flowserve.com> Subject: [External] Re: [External] 10837 - Follow up to air quality inspecon CAUTION: This email originated from outside of Flowserve. Do not click links or open attachments unless you can confirm the sender and know the content is safe. Brian, The thinner you are using may not be compliant with R307-350. The SDS you sent me shows a vapor pressure of 4.8 mmHg at 20 degrees Celsius. It also has a relatively high VOC content of 909 g/L. R307-350-7(2) states: [Quoted text hidden] [Quoted text hidden] Daniel Riddle <driddle@utah.gov>Thu, Nov 21, 2024 at 8:32 AM To: "Pike, Brian" <BPike@flowserve.com> Thanks for correcting that - can you send me the SDS or EDS or TDS for Klean Strip Lacquer thinner to show that this product is compliant with the the 1mmHG at 20 degrees Celsius limit? [Quoted text hidden] Pike, Brian <BPike@flowserve.com>Thu, Nov 21, 2024 at 9:33 AM To: Daniel Riddle <driddle@utah.gov> Daniel, 11/21/24, 9:57 AM State of Utah Mail - 10837 - Follow up to air quality inspection https://mail.google.com/mail/u/0/?ik=3e54b7a6bd&view=pt&search=all&permthid=thread-a:r8774165004592784359&simpl=msg-a:r-25473196991783…5/6 Attached is the Thinner SDS. [Quoted text hidden] KleanStrip Thinner.pdf 127K Daniel Riddle <driddle@utah.gov>Thu, Nov 21, 2024 at 9:57 AM To: "Pike, Brian" <BPike@flowserve.com> Thank you for sending this! I'll let you know if I need anything else. [Quoted text hidden] 11/21/24, 9:57 AM State of Utah Mail - 10837 - Follow up to air quality inspection https://mail.google.com/mail/u/0/?ik=3e54b7a6bd&view=pt&search=all&permthid=thread-a:r8774165004592784359&simpl=msg-a:r-25473196991783…6/6 MONTH/YEAR VOC POUNDSTOLUENEXYLENETOTAL HAPs December 2023 77.41 0.00 77.41 77.41 January 2024 80.10 0.00 80.10 80.10 February 2024 77.99 0.00 77.99 77.99 March 2024 70.33 0.00 70.33 70.33 April 2024 106.13 0.00 106.13 106.13 May 2023 87.55 0.00 87.55 87.55 June 2024 71.73 0.00 71.73 71.73 July 2024 94.16 0.00 94.16 94.16 August 2024 74.38 0.01 74.38 74.39 September 2024 96.41 0.00 96.41 96.41 October 2023 72.83 0.00 72.83 72.83 November 2023 79.80 0.00 61.76 79.80December 2024 0.00 0.00 0.00 0.00 Total POUNDS 988.82 0.01 970.78 988.83 Total TONS 0.4944 988.83 Flowserve Springville VOC Rolling Totals with HAPs - Toluene & Xylene Permitted Plant-Wide 10 Tons VOCs Oven Hours X 0.75 = BTU X 0.14 = BTU X .0006 = Month Hours BTU's Total NOx lbs Total SOx lbs Jan- 24 27 20.25 2.940 0.0126Feb-24 20 15.00 2.100 0.0090Mar-23 34 25.50 3.570 0.0153Apr-24 32 24.00 3.360 0.0144May-24 22 16.50 2.310 0.0099Jun-24 17 12.75 1.785 0.0077 Jul-24 25 18.75 2.625 0.0113 Aug-24 28 21.00 2.940 0.0126 Sep-24 38 28.50 3.990 0.0171 Oct-23 24 18.00 2.520 0.0108 Nov-23 11 8.25 1.155 0.0050Dec-23 17 12.75 1.785 0.0077 TOTALS 295 221.25 31.080 0.133 Month Sandblast Hours Hours X 0.57 = lbs of PM10 Jan- 24 29 16.53 Feb-24 14 7.98 Mar-24 46 26.22 Apr-24 27 15.39 May-24 14 7.98 Jun-24 8 4.56 Jul-24 34 19.38 Aug-24 19 10.83 Sep-24 23 13.11 Oct-23 15 8.55 Nov-23 14 7.98 Dec-23 11 6.27TOTALS254144.78 NOx, SOx Rolling Totals OVEN ROLLING TOTALS PM10 Rolling Totals ANDBLAST ROLLING TOTAL Month Oven Start End Total Month Start End Total Jan-24 1 1781 1781 0 Jan-24 27 2 4220 4247 27 29Feb-24 1 1781 1781 0 Feb-24 20 2 4247 4267 20 14Mar-24 1 1781 1781 0 Mar-24 13 2 4267 4280 13 21 Apr-24 1 1781 1795 14 Apr-24 32 2 4280 4298 18 27 May-24 1 1795 1799 4 May-24 22 2 4298 4316 18 14 Jun-24 1 1799 1799 0 Jun-2417243164333178 Jul-24 1 1799 1799 0 Jul-24 27 2 4333 4360 27 19 Aug-24 1 1799 1799 0 Aug-24 28 2 4360 4388 28 19 Sep-24 1 1799 1800 1 Sep-24 38 2 4388 4425 37 23Oct-23 1 1781 1781 0 Oct-23 24 2 4168 4192 24 15Nov-23 1 1781 1781 0 Nov-23 11 2 4192 4203 11 14 Dec-23 1 1781 1781 0 Dec-23 17 2 4203 4220 17 11 276 214 OVEN & SANDBLAST USAGE Oven Useage Sandblast Useage 6945 6974 29 6974 6988 14 6988 7009 21 7009 7036 27 7036 7050 14 7050 7058 8 7058 7077 19 7077 7096 19 7096 7119 23 6905 6920 15 6920 6934 14 6934 6945 11 OVEN TOTALS SandBLAST TOTAL Date Printed: 05/11/2023 Product: 0988A1NL Safety Data Sheet Prepared in Accordance with HCS 29 C.F.R. 1910.1200 1. Identification of the Substance/Mixture and the Company/Undertaking 1.1 Product Identifier 0988A1NL Revision Date:12/05/2022 Supercedes Date:02/16/2022Product Name:CARBOGUARD 893 PART A Component of multicomponent industrialcoatings - Industrial use. 1.2 Relevant identified uses of the substance or mixture and usesadvised against 1.3 Details of the supplier of the safety data sheet Manufacturer:Carboline Global Inc. 2150 Schuetz Road St. Louis, MO USA 63146 Regulatory / Technical Information: Contact Carboline Technical Services at 1-800-848-4645 Schlereth, Ken - regulatory@carboline.comDatasheet Produced by: Emergency telephone number:1.4 CHEMTREC 1-800-424-9300 (Inside US)CHEMTREC +1 703 5273887 (Outside US) HEALTH - Pittsburgh Poison Control 1-412-681-6669 2. Hazard Identification 2.1 Classification of the substance or mixture Hazardous to the aquatic environment, Chronic, category 3 Carcinogenicity, category 1AEye Irritation, category 2 Flammable Liquid, category 2 Reproductive Toxicity, category 2 STOT, repeated exposure, category 1 Skin Irritation, category 2Skin Sensitizer, category 1 Page 1 / 11 Date Printed: 05/11/2023 Product: 0988A1NL 2.2 Label elements Symbol(s) of Product Signal Word Danger Named Chemicals on Label TOLUENE, MICROCRYSTALLINE SILICA, EPOXY RESIN, BISPHENOL A EPOXY RESIN HAZARD STATEMENTS H225 Highly flammable liquid and vapour.Flammable Liquid, category 2 H315 Causes skin irritation.Skin Irritation, category 2 H317 May cause an allergic skin reaction.Skin Sensitizer, category 1 H319 Causes serious eye irritation.Eye Irritation, category 2 H350-1A May cause cancer.Carcinogenicity, category 1A H361 Suspected of damaging fertility or the unborn child.Reproductive Toxicity, category 2 H372 Causes damage to organs through prolonged or repeated exposure.STOT, repeated exposure, category 1 H412 Harmful to aquatic life with long lasting effects.Hazardous to the aquatic environment, Chronic, category 3 PRECAUTION PHRASES P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking. P235 Keep cool. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash hands thoroughly after handling. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/ face protection. P284 Wear respiratory protection. P302+352 IF ON SKIN: Wash with plenty of soap and water. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do so.Continue rinsing. P308+313 IF exposed or concerned: Get medical advice/attention P314 Get medical advice/attention if you feel unwell. P333+313 If skin irritation or rash occurs: Get medical advice/attention. P403+233 Store in a well-ventilated place. Keep container tightlyclosed. 2.3 Other hazards No Information Results of PBT and vPvB assessment: The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII. 3. Composition/Information On Ingredients 3.2 Mixtures Page 2 / 11 Date Printed: 05/11/2023 Product: 0988A1NL Hazardous ingredients Name According to EEC EINEC No.CAS-No.%Classifications MICROCRYSTALLINE SILICA 238-878-4 14808-60-7 50 - <75 H350-372 Carc. 1A, STOT RE 1 TITANIUM DIOXIDE 236-675-5 13463-67-7 10 - <25 BISPHENOL A EPOXY RESIN 500-033-5 25068-38-6 10 - <25 H315-317-319-411 Aquatic Chronic 2, Eye Irrit. 2, Skin Irrit. 2, Skin Sens. 1 EPOXY RESIN 607-500-3 25036-25-3 2.5 - <10 H315-317-319 TOLUENE 203-625-9 108-88-3 2.5 - <10 H225-304-315-319-332-335-336 -361-370-412 Acute Tox. 4 Inhalation, Aquatic Chronic 3, Asp. Tox. 1, Eye Irrit. 2, Flam. Liq. 2, Repr. 2, Skin Irrit. 2, STOT SE1, STOT SE 3 NE, STOT SE 3 RTI CARBON BLACK 215-609-9 1333-86-4 2.5 - <10 METHYL ETHYL KETONE 201-159-0 78-93-3 1.0 - <2.5 H225-319-336 Eye Irrit. 2, Flam. Liq. 2, STOT SE 3 NE ISOPROPANOL 200-661-7 67-63-0 1.0 - <2.5 H225-319-336 Eye Irrit. 2, Flam. Liq. 2, STOT SE 3 NE META-XYLENE 203-576-3 108-38-3 1.0 - <2.5 H312-315-332 1-METHOXY-2- PROPANOL ACETATE 203-603-9 108-65-6 1.0 - <2.5 H226 Flam. Liq. 3 ETHYL BENZENE 202-849-4 100-41-4 0.1 - <1.0 H225-304-315-319-332-351-373 -412 Acute Tox. 4 Inhalation, Aquatic Chronic 3, Asp. Tox. 1, Carc. 2, Eye Irrit. 2, Flam. Liq. 2, Skin Irrit. 2, STOT RE 2 CAS-No.M-Factors 14808-60-7 0 13463-67-7 0 25068-38-6 0 25036-25-3 0 108-88-3 0 1333-86-4 0 78-93-3 0 67-63-0 0 108-38-3 0 108-65-6 0 100-41-4 0 Remarks:CAS No 13463-67-7: Note 10 CAS No. 25068-38-6 identified as CAS No. 1675-54-3, EC No. 216-823-5 under REACH Registration Additional Information:The text for GHS Hazard Statements shown above (if any) is given in Section 16. 4. First-aid Measures 4.1 Description of First Aid Measures AFTER INHALATION:Give oxygen or artificial respiration if needed. Remove person to fresh air. If signs/symptoms continue, get medical attention. AFTER SKIN CONTACT:In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. If skin irritation persists, call a physician. AFTER EYE CONTACT:Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Page 3 / 11 Date Printed: 05/11/2023 Product: 0988A1NL AFTER INGESTION:Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If swallowed, call a poison control centre or doctor immediately. 4.2 Most important symptoms and effects, both acute and delayed Harmful if swallowed. Irritating to eyes and skin. Risk of serious damage to the lungs (by aspiration). Vapours may cause drowsiness and dizziness. 4.3 Indication of any immediate medical attention and special treatment needed No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if available, can be found in section 11. When symptoms persist or in all cases of doubt seek medical advice. 5. Fire-fighting Measures 5.1 Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog UNUSUAL FIRE AND EXPLOSION HAZARDS:Flammable liquid. Vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures with air. Vapors may travel to areas away from work site before igniting/flashing back to vapor source. Provide adequate ventilation. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration higher than the occupational exposure limits. Keep away from heat/sparks/open flames/hot surfaces. -No smoking. Electrical installations / working materials must comply with the technological safety standards. Wear shoes with conductive soles. FOR SAFETY REASONS NOT TO BE USED:No Information 5.2 Special hazards arising from the substance or mixture No Information 5.3 Advice for firefighters SPECIAL FIREFIGHTING PROCEDURES: In the event of fire, wear self-contained breathing apparatus. Cool containers / tanks with water spray. Flammable. SPECIAL FIREFIGHTING PROTECTION EQUIPMENT: No Information 6. Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Evacuate personnel to safe areas. Remove all sources of ignition. To avoid ignition of vapours by static electricity discharge, all metal parts of the equipment must be grounded. Wear personal protective equipment. For personal protection see section 8. 6.2 Environmental precautions Do not allow material to contaminate ground water system. Prevent product from entering drains. 6.3 Methods and material for containment and cleaning up Prevent further leakage or spillage if safe to do so. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Reference to other sections6.4 No Information 7. Handling and Storage 7.1 Precautions for safe handling INSTRUCTIONS FOR SAFE HANDLING :Keep containers dry and tightly closed to avoid moisture absorption and contamination. Prepare the working solution as given on the label(s) and/or the user instructions. Do not breathe vapours or spray mist. Ensure all equipment is electrically grounded before beginning transfer operations. Do not use sparking tools. Page 4 / 11 Date Printed: 05/11/2023 Product: 0988A1NL Do not get in eyes, on skin, or on clothing. Use only with adequate ventilation/personal protection. Wash thoroughly after handling. PROTECTION AND HYGIENE MEASURES :Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. When using, do not eat, drink or smoke. 7.2 Conditions for safe storage, including any incompatibilities CONDITIONS TO AVOID:Heat, flames and sparks. STORAGE CONDITIONS:Keep container closed when not in use. Store in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. 7.3 Specific end use(s) No specific advice for end use available. 8. Exposure Controls/Personal Protection 8.1 Control parameters Ingredients with Occupational Exposure Limits (US) Name ACGIH TWA ACGIH STEL ACGIH CeilingCAS-No. MICROCRYSTALLINE SILICA 14808-60-7 0.025 MGM3 N/E N/E TITANIUM DIOXIDE 13463-67-7 10 mg/m3 N/E N/E BISPHENOL A EPOXY RESIN 25068-38-6 N/E N/E N/E EPOXY RESIN 25036-25-3 N/E N/E N/E TOLUENE 108-88-3 20 PPM N/E N/E CARBON BLACK 1333-86-4 3 MGM3 N/E N/E METHYL ETHYL KETONE 78-93-3 200 PPM 300 PPM N/E ISOPROPANOL 67-63-0 200 PPM 400 PPM N/E META-XYLENE 108-38-3 100 PPM 150 PPM N/E 1-METHOXY-2-PROPANOL ACETATE 108-65-6 N/E N/E N/E ETHYL BENZENE 100-41-4 20 PPM 125 ppm Name CAS-No.OSHA PEL OSHA STEL MICROCRYSTALLINE SILICA 14808-60-7 0.05 MGM3 N/E TITANIUM DIOXIDE 13463-67-7 15 MGM3 N/E BISPHENOL A EPOXY RESIN 25068-38-6 N/E N/E EPOXY RESIN 25036-25-3 N/E N/E TOLUENE 108-88-3 200 ppm 560 MGM3, 150 PPM CARBON BLACK 1333-86-4 3.5 MGM3 N/E METHYL ETHYL KETONE 78-93-3 590 MGM3, 200 PPM885 MGM3, 300 PPM ISOPROPANOL 67-63-0 980 MGM3, 400 PPM1225 MGM3, 500 PPM Page 5 / 11 Date Printed: 05/11/2023 Product: 0988A1NL META-XYLENE 108-38-3 100.00 PPM N/E 1-METHOXY-2-PROPANOL ACETATE 108-65-6 N/E N/E ETHYL BENZENE 100-41-4 435 MGM3, 100 PPM545 MGM3, 125 PPM FURTHER ADVICE:Refer to the regulatory exposure limits for the workforce enforced in each country. Some components may not have been classified under the EU CLP Regulation. 8.2 Exposure controls Personal Protection RESPIRATORY PROTECTION:In order to avoid inhalation of spray-mist and sanding dust, all spraying and sanding must be done wearing adequate respirator. Use only with ventilation to keep levels below exposure guidelines reported in this document. User should test and monitor exposure levels to ensure all personnel are below guidelines. If not sure, or not able to monitor, use State or federally approved supplied air respirator. For silica containing coatings in a liquid state, and/or if no exposure limits are established above, air-supplied respirators are generally not required. EYE PROTECTION:Safety glasses with side-shields. HAND PROTECTION:Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Impervious gloves. Request information on glove permeation properties from the glove supplier. Lightweight protective clothing OTHER PROTECTIVE EQUIPMENT:Ensure that eyewash stations and safety showers are close to the workstation location. ENGINEERING CONTROLS:Avoid contact with skin, eyes and clothing. Ensure adequate ventilation, especially in confined areas. 9. Physical and Chemical Properties 9.1 Information on basic physical and chemical properties Appearance:Viscous Liquid, Various Colors Physical State Liquid Odor Epoxy Odor threshold N/D pH N/D Melting point / freezing point (°C)N/D Boiling point/range (°C)173 F (78 C) - 500 F (260 C) Flash Point (°C)61F (16C) Evaporation rate Slower than Ether Not determinedFlammability (solid, gas) Upper/lower flammability or explosive limits 0.5 - 12.0 Vapour Pressure, mmHg N/D Vapour density Heavier than Air Relative density Not determined Solubility in / Miscibility with water N/D Partition coefficient: n-octanol/water Not determined Auto-ignition temperature (°C)Not determined Decomposition temperature (°C)Not determined Page 6 / 11 Date Printed: 05/11/2023 Product: 0988A1NL Viscosity Unknown Explosive properties Not determined Oxidising properties Not determined 9.2 Other information VOC Content g/l:195 app 1.56Specific Gravity (g/cm3) 10. Stability and Reactivity 10.1 Reactivity No reactivity hazards known under normal storage and use conditions. 10.2 Chemical stability Stable under normal conditions. 10.3 Possibility of hazardous reactions Hazardous polymerisation does not occur. 10.4 Conditions to avoid Heat, flames and sparks. 10.5 Incompatible materials Strong oxidizing agents. 10.6 Hazardous decomposition products Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense black smoke. Page 7 / 11 Date Printed: 05/11/2023 Product: 0988A1NL 11. Toxicological Information 11.1 Information on toxicological effects Acute Toxicity: Oral LD50:N/D Inhalation LC50:N/D Eye Irritation and Skin Irritation, category 2Irritation: UnknownCorrosivity: Skin Sensitizer, category 1Sensitization: UnknownRepeated dose toxicity: Carcinogenicity, category 1ACarcinogenicity: UnknownMutagenicity: Reproductive Toxicity, category 2Toxicity for reproduction: UnknownSTOT-single exposure: STOT, repeated exposure, category 1STOT-repeated exposure: UnknownAspiration hazard: If no information is available above under Acute Toxicity then the acute effects of this product have not been tested. Data on individual components are tabulated below: Chemical Name Oral LD50 Dermal LD50 Vapor LC50 Gas LC50 Dust/Mist LC50CAS-No. 14808-60-7 MICROCRYSTALLINE SILICA 22500 mg/kg Not Available Not Available 0.000 0.000 13463-67-7 TITANIUM DIOXIDE 25000 mg/kg, oral (rat)Not Available Not Available No Information No Information 25068-38-6 BISPHENOL A EPOXY RESIN 11400 mg/kg, rat, oral 23000 mg/kg, dermal, rabbit >20 mL/kg skin, sensitizer 25036-25-3 EPOXY RESIN >2000 mg/kg,oral, rat >2000 mg/kg,dermal, rat Not Available 0.000 0.000 108-88-3 TOLUENE 5000 mg/kg rat oral 12267 mg/kg, dermal, rabbit 8000 ppm/4 hrs, rat, inhalation 0.000 0.000 1333-86-4 CARBON BLACK 8000 mg/kg oral, rat Not Available Not Available 78-93-3 METHYL ETHYL KETONE 2194 mg/kgrat, oral Not Available 34.5 mg/L/ 4 hour rat,inhalation 0.000 0.000 67-63-0 ISOPROPANOL 4720 mg/kg rat, oral 12800 mg/kg, dermal, rabbit 22500ppm/8hrs rat, inhalation 0.000 0.000 108-38-3 META-XYLENE Not Available Not Available Not Available 0.000 0.000 Page 8 / 11 Date Printed: 05/11/2023 Product: 0988A1NL 108-65-6 1-METHOXY-2-PROPANOL ACETATE 8532 mg/kg, oral (rat)>5000 mg/kg 101 ppm/4 hr, rat, inh 0.000 0.000 100-41-4 ETHYL BENZENE 3500 mg/kg rat, oral >5000 mg/l, dermal rabbit 17.2 mg/L Inh, Rat, 4Hr 0.000 0.000 Additional Information: This product may contain Ethyl Benzene, which is listed by IARC as possibly carcinogenic to humans (Group 2B). This listing is based on inadequate evidence of carcinogenicity in humans and sufficient evidence in experimental animals. Constituents of this product may include crystalline silica which, if inhalable, may cause silicosis, a form or progressive pulmonary fibrosis. Inhalable crystalline silica is listed by IARC as a group 1 carcinogen (lung) based on sufficient evidence in occupationally exposed humans and sufficient evidence in animals. Crystalline silica is also listed by the NTP as a known human carcinogen. This classification isrelevant when exposed to Quartz (silicon dioxide) in dust or powder form only, including cured product that is subject to sanding, grinding, cutting, or other surface preparation activities. Constituents may also include abestiform or non-asbestiform tremolite or other silicates as impurities, and above dei minimus exposure to these impurities in inhalable form may be carcinogenic or cause other serious lung problems. 12. Ecological Information 12.1 Toxicity: EC50 48hr (Daphnia):Unknown UnknownIC50 72hr (Algae): UnknownLC50 96hr (fish): 12.2 Persistence and degradability:Unknown 12.3 Bioaccumulative potential:Unknown 12.4 Mobility in soil:Unknown 12.5 Results of PBT and vPvB assessment: The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII. 12.6 Other adverse effects:Unknown Chemical Name EC50 48hr IC50 72hr LC50 96hrCAS-No. 14808-60-7 MICROCRYSTALLINE SILICA No information No information No information 13463-67-7 TITANIUM DIOXIDE No information No information No information 25068-38-6 BISPHENOL A EPOXY RESIN 2.1 mg/l (daphnia)11 mg/l (algae)1.3 mg/l (fish) 25036-25-3 EPOXY RESIN No information No information No information 108-88-3 TOLUENE 6 mg/l (Daphnia magna)12.5 mg/L (Algae)5.8 mg/L (Fish) 1333-86-4 CARBON BLACK No information No information No information 78-93-3 METHYL ETHYL KETONE 308 mg/l (Daphnia magna)No information 2993 mg/l (Pimephales promelas) 67-63-0 ISOPROPANOL 13299 mg/l (Daphnia Magna) >1000 m/gL (desmodesmussubspicatus) 9640 mg/L (pimphales promelas) 108-38-3 META-XYLENE No information No information No information 108-65-6 1-METHOXY-2-PROPANOL ACETATE 408 mg/l (Daphnia Magna) >1000 mg/l (Green Algae)161 mg/l (Fathead Minnow) 100-41-4 ETHYL BENZENE 1.8 mg/l (Daphnia Magna)4.6 mg/l (Green Algae)4.2 mg/l (Rainbow Trout) 13. Disposal Considerations Page 9 / 11 Date Printed: 05/11/2023 Product: 0988A1NL 13.1 WASTE TREATMENT METHODS:Do not burn, or use a cutting torch on, the empty drum. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of in accordance with local regulations. Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. Transport Information 14.1 UN number UN1263 UN proper shipping name14.2 Paint N/ATechnical name 14.3 3Transport hazard class(es) N/ASubsidiary shipping hazard Packing group14.4 II 14.5 Marine Pollutant: Yes (Epoxy Resin)Environmental hazards Special precautions for user Unknown14.6 EmS-No.:F-E, S-E Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code14.7 Unknown 15. Regulatory Information 15.1 Safety, health and environmental regulations/legislation for the substance or mixture: U.S. Federal Regulations: As follows - CERCLA - Sara Hazard Category This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Flammable (gases, aerosols, liquids, or solids), Carcinogenicity, Reproductive toxicity, Skin Corrosion or Irritation, Respiratory or Skin Sensitization, Serious eye damage or eye irritation, Specific target organ toxicity (single or repeated exposure) Sara Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name CAS-No.% TOLUENE 108-88-3 4.48 META-XYLENE 108-38-3 1.43 ETHYL BENZENE 100-41-4 0.59 Toxic Substances Control Act: All components of this product are either listed on the TSCA Inventory or are exempt. This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: No TSCA 12(b) components exist in this product. U.S. State Regulations: As follows - New Jersey Right-to-Know: The following materials are non-hazardous, but are among the top five components in this product. Chemical Name CAS-No. Page 10 / 11 Date Printed: 05/11/2023 Product: 0988A1NL 1,2-BENZENEDICARBOXIOLIC ACID, DI-C9-11- BRANCHED AND LINEAR ALKYL ESTERS 68515-43-5 Pennsylvania Right-To-Know The following non-hazardous ingredients are present in the product at greater than 3%. Chemical Name CAS-No. 1,2-BENZENEDICARBOXIOLIC ACID, DI-C9-11-BRANCHED AND LINEAR ALKYL ESTERS 68515-43-5 IRON OXIDE 1309-37-1 YELLOW IRON OXIDE 51274-00-1 CALIFORNIA PROPOSITION 65 WARNING: Cancer and Reproductive Harm -- www.P65Warnings.ca.gov International Regulations: As follows - * Canadian DSL: All chemical ingredients included on inventory (DSL) 15.2 Chemical Safety Assessment: No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier. 16. Other Information Text for GHS Hazard Statements shown in Section 3 describing each ingredient: H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H315 Causes skin irritation.H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness.H350 May cause cancer. H351 Suspected of causing cancer. H361 Suspected of damaging fertility or the unborn child. H370 Causes damage to organs. H372 Causes damage to organs through prolonged or repeated exposure.H373 May cause damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. Reasons for revision No Information The information contained herein is, to the best of our knowledge and belief accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by use of this material. It is the responsibility of the user to comply with all applicable federal, state, and local laws and regulations. Page 11 / 11 08/09/2023Revision: 08/10/2023Printed: Page: 1 of 8 Klean Strip Paint Thinner SAFETY DATA SHEET 11/22/2022Supersedes Revision: Product Name: Company Name: Emergency Contact:(800)451-8346 Information:(800)398-3892 Intended Use: Web site address: Product Code: 1. PRODUCT AND COMPANY IDENTIFICATION Klean Strip Paint Thinner Paint, stain, and varnish thinning. CKPT94402, EKPT94401, GKPT94002, GKPT94002P, GKPT94400, QKPT94003, QKPT94203, QKPT943 2105 Channel Avenue Memphis, TN 38113 3E 24 Hour Emergency Contact W.M. Barr Customer Service www.wmbarr.com W. M. Barr 2. HAZARDS IDENTIFICATION Flammable Liquids, Category 3 Acute Toxicity: Inhalation, Category 4 Skin Corrosion/Irritation, Category 2 Serious Eye Damage/Eye Irritation, Category 2B Germ Cell Mutagenicity, Category 1B Toxic To Reproduction, Category 2 Specific Target Organ Toxicity (single exposure), Category 3 Specific Target Organ Toxicity (repeated exposure), Category 2 Aspiration Toxicity, Category 1 GHS Precautionary Phrases: GHS Hazard Phrases: DangerGHS Signal Word: P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P210 - Keep away from heat, hot surfaces, sparks, open flams and other ignition source. No smoking. P233 - Keep container tightly closed. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting/.../equipment. ... other specified by the manufacturer/supplier or the competent authority. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P260 - Do not breathe dust/fume/gas/mist/vapors/spray. P264 - Wash hands thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear protective gloves/protective clothing/eye protection/face protection. H226 - Flammable liquid and vapor. H304 - May be fatal if swallowed and enters airways. H315 - Causes skin irritation. H332 - Harmful if inhaled. H336 - May cause drowsiness or dizziness. H340 - May cause genetic defects . H361 - Suspected of damaging fertility or the unborn child . H373 - May cause damage to through prolonged or repeated exposure. Licensed to W.M. Barr and Company: MIRS SDS, (c) A V Systems, Inc.GHS format 08/09/2023Revision: 08/10/2023Printed: Page: 2 of 8 Klean Strip Paint Thinner SAFETY DATA SHEET 11/22/2022Supersedes Revision: GHS Response Phrases: GHS Storage and Disposal Phrases: P281 - Use personal protective equipment as required. P235 - Keep cool. P301+310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302+352 - IF ON SKIN: Wash with plenty of soap and water. P303+361+353 - IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P304+340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+351+338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+313 - IF exposed or concerned: Get medical attention/advice. P312 - Call a POISON CENTER or doctor/physician if you feel unwell. P314 - Get medical attention/advice if you feel unwell. P321 - Specific treatment see ... on this label. P331 - Do NOT induce vomiting. P332+313 - If skin irritation occurs, get medical advice/attention. P337+313 - If eye irritation persists, get medical advice/attention. P362 - Take off contaminated clothing and wash before re-use. P370 - In case of fire: P403 - Store in well-ventilated place. P405 - Store locked up. P501 - Dispose of contents/container according to local, state and federal regulations. This material is classified as hazardous under OSHA regulations.OSHA Regulatory Status: Medical Conditions Generally Aggravated By Exposure: Potential Health Effects (Acute and Chronic): Diseases of the skin, eyes, liver, kidneys central nervous system and respiratory system. Inhalation Acute Exposure Effects: May cause dizziness, headache, watering of eyes, eye irrtation, weakness, nausea, muscle twitches and depression of central nervous system. Severe over exposure may cause convulsions, unconsiousness and death. Intentional misuse of this product by deliberately concentrating and inhaling can be harmful or fatal. Inhalation of decomposition products may cause severe injury or death. Skin Contact Acute Exposure Effects: May cause skin irritation. Decomposition may produce carbon monoxide and carbon dioxide. May cause numbness in fingers and arms, drying of skin, and dermatitis. May cause increased severity of symptoms listed under inhalation. Eye Contact Acute Exposure Effects: This material is an eye irritant. May cause irritation, burns, conjunctivitis of eyes and corneal ulcerations of the eye. Vapors may irritate eyes. May cause jaundice, bone marrow damage, liver damage, anemia and skin irritation. Ingestion Acute Exposure Effects: Harmful or fatal if swallowed. May cause nausea; vomiting; weakness; muscle twitches; gastrointestinal irritation; diarrhea; unconsciousness; convulsions; and death. Chronic Exposure Effects: Reports have associated repeated and prolonged overexposure to solvents with neurological and other physiological damage. Prolonged or repeated contact may cause dermatitis. May cause jaundice, bone marrow damage, liver damage anemia and skin irritation. Licensed to W.M. Barr and Company: MIRS SDS, (c) A V Systems, Inc.GHS format 08/09/2023Revision: 08/10/2023Printed: Page: 3 of 8 Klean Strip Paint Thinner SAFETY DATA SHEET 11/22/2022Supersedes Revision: CAS # Hazardous Components (Chemical Name) 3. COMPOSITION/INFORMATION ON INGREDIENTS Concentration Stoddard solvent {Mineral spirits; Aliphatic Petroleum Distillates; White spirits} 8052-41-3 80.0 -100.0 % Benzene, Trimethyl- 25551-13-7 3.0 -7.0 % Additional Chemical Information Ingredients vary due to multiple blends and/or raw material suppliers. 4. FIRST AID MEASURES Emergency and First Aid Procedures: Note to Physician: Signs and Symptoms Of Exposure: Inhalation: If user experiences breathing difficulty, move to air free of vapors. Administer oxygen if breathing is difficult. Skin Contact Acute Exposure Effects: Skin Contact: Wash with soap and large quantities of water for at least 15 minutes. Seek medical attention if irritation from contact persists. Eye Contact: Flush with large quantities of water for at least 15 minutes and seek immediate medical attention. Ingestion: Do NOT induce vomiting. Call your poison control center, hospital emergency room, or physician immediately for instructions. If spontaneous vomiting is about to occur, place victim's head below knees. If victim is drowsy or unconscious, place on the left side with head down. Never give anything by mouth to an unconscious person. Get medical attention immediately. Call your local poison control center for further information. Inhalation: Inhalation overexposure can produce toxic effects. Monitor for respiratory distress. If cough or difficulty in breathing develops, evaluate for upper respiratory tract inflammation, bronchitis, and pneumonitis. Administer supplemental oxygen with assisted ventilation as required. Ingestion: If ingested, this material presents a significant aspiration and chemical pneumonitis hazard. Induction of emesis is not recommended. Consider activated charcoal and/or gastric lavage. If patient is obtunded, protect the airway by cuffed endotracheal intubation or by placement of the body in a Trendelenburg and left lateral decubitus position. ROUTE OF ENTRY: Inhalation, Skin/Dermal, Eye/Ocular, Ingestion/Oral. Licensed to W.M. Barr and Company: MIRS SDS, (c) A V Systems, Inc.GHS format 08/09/2023Revision: 08/10/2023Printed: Page: 4 of 8 Klean Strip Paint Thinner SAFETY DATA SHEET 11/22/2022Supersedes Revision: 5. FIRE FIGHTING MEASURES Flash Pt: Fire Fighting Instructions: Flammable Properties and Hazards: Autoignition Pt: Explosive Limits: Flammability Classification: Suitable Extinguishing Media: Hazardous Combustion Products: > 100.00 F Self-contained respiratory protection should be provided for fire fighters fighting fires in buildings or confined areas. Storage containers exposed to fire should be kept cool with water spray to prevent pressure build-up. Stay away from heads of containers that have been exposed to intense heat or flame. Combustible. Liquid. LEL: 0.5 UEL: 6 NFPA Class II Use carbon dioxide, dry powder, or foam. Carbon dioxide, Carbon monoxide, smoke, fumes and/or unburned hydrocarbons. 6. ACCIDENTAL RELEASE MEASURES Steps To Be Taken In Case Material Is Released Or Spilled: Methods for cleaning up. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Stay upwind, out of low areas, and ventilate closed spaces before entering. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Spills/Leaks: Take up with sand or other non-combustible absorbent material and place into containers for later disposal. Dike to collect large liquid spills. Dike far ahead of spill for later disposal. WASTE DISPOSAL Dispose in accordance with appliable local, state and federal regulations. A single exposure, when used as directed, is not likely to result in adverse skin effects. 7. HANDLING AND STORAGE Precautions To Be Taken in Handling: Precautions To Be Taken in Read carefully all cautions and directions on product label before use. Since empty container retains residue, follow all label warnings even after container is empty. Dispose of empty container according to all regulations. Do not reuse this container. Read carefully all cautions and directions on product label before use. Since empty container retains residue, follow all label warnings even after container is empty. Dispose of empty container according to all regulations. Do not reuse this container. according to local, state and federal regulations. Do not reuse this container. A static electrical charge can accumulate when this material is flowing through pipes, nozzles or filters, and when it is agitated. A static spark discharge can ignite accumulated vapors particularly during dry weather conditions. Always use proper bonding and grounding procedures. Keep container tightly closed when not in use. Store in a cool, dry place. Do not store Licensed to W.M. Barr and Company: MIRS SDS, (c) A V Systems, Inc.GHS format 08/09/2023Revision: 08/10/2023Printed: Page: 5 of 8 Klean Strip Paint Thinner SAFETY DATA SHEET 11/22/2022Supersedes Revision: Storing:near flames or at elevated temperatures. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Recommended Exposure LimitsCAS # Chemical Name Jurisdiction Notations ACGIH TLV8052-41-3 Stoddard solvent {Mineral spirits; Aliphatic Petroleum Distillates; White spirits} TLV: 100 ppm OSHA PELs PEL: 500 ppm ACGIH TLV25551-13-7 Benzene, Trimethyl-TLV: 25 ppm Respiratory Equipment (Specify Type): Eye Protection: Protective Gloves: Other Protective Clothing: Engineering Controls (Ventilation etc.): Work/Hygienic/Maintenance Practices: For OSHA controlled work place and other regular users. Use only with adequate ventilation under engineered air control systems designed to prevent exceeding appropriate TLV. For OSHA controlled workplace and other regular users - Use only with adequate ventilation under engineered air control systems designed to prevent exceeding appropriate TLV. For occasional use where engineered air control is not feasible, use properly maintained and properly fitted NIOSH approved respirator for organic solvent vapors. A dusk mask does not provide protection against vapors. A dust mask does not provide protection against vapors. Safety glasses, chemical goggles, or face shields are recommended to safeguard against potential eye contact, irritation, or injury. Contact lenses should not be worn while working with chemicals. Various application methods can dictate use of additional protective safety equipment, such as impermeable aprons, etc., to minimize exposure. Before reuse, thoroughly clean any clothing or protective equipment that has been contaminated by prior use. Discard any clothing or other protective equipment that cannot be decontaminated, such as gloves or shoes. Use only with adequate ventilation to prevent build-up of vapors. Open all windows and doors. use only with a cross ventilation of moving fresh air across the work area. If strong odor is noticed or you experience slight dizziness, headache, nausea, or eye-watering - STOP - ventilation is inadequate. Leave area immediately. A source of clean water should be available in the work area for flushing eyes and skin. Do not eat, drink, or smoke in the work area. Wash hands thoroughly after use and before eating, drinking, or smoking. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical States:[ ] Gas [ X ] Liquid [ ] Solid Appearance and Odor:Water white / Free and clear. Odor threshold not determined. pH:N.D. Melting Point:N.A. Boiling Point:318.00 F - 385.00 F Flash Pt:> 100.00 F Evaporation Rate:N.D. Flammability (solid, gas): Explosive Limits:LEL: 0.5 UEL: 6 Vapor Pressure (vs. Air or mm Hg): 0.3 MM HG at 68.0 F ND MM HG at 50.0 C Vapor Density (vs. Air = 1):5 Air = 1 Licensed to W.M. Barr and Company: MIRS SDS, (c) A V Systems, Inc.GHS format 08/09/2023Revision: 08/10/2023Printed: Page: 6 of 8 Klean Strip Paint Thinner SAFETY DATA SHEET 11/22/2022Supersedes Revision: Specific Gravity (Water = 1): 0.78 Solubility in Water:Slight Solubility Notes:Very slightly soluble in cold water. Saturated Vapor Concentration: N.D. Octanol/Water Partition Coefficient: ND Percent Volatile:100.0 % by weight. VOC / Volume:778.0000 G/L Autoignition Pt: Decomposition Temperature: N.D. Viscosity:N.D. a_fld_hdr[9]:ND = Not Determined. ND = Not Determined. Information with regard to primary physical hazard: 10. STABILITY AND REACTIVITY Conditions To Avoid - Instability: Stability: Incompatibility - Materials To Avoid: Hazardous Decomposition or Byproducts: Possibility of Hazardous Reactions: Conditions To Avoid - Hazardous Reactions: Unstable [ ] Stable [ X ] Incompatible with strong acids, alkaliles and oxidzers such as liquid chlorine and oxygen. Decomposition may produce carbon monoxide and carbon dioxide. Will occur [ ] Will not occur [ X ] Licensed to W.M. Barr and Company: MIRS SDS, (c) A V Systems, Inc.GHS format 08/09/2023Revision: 08/10/2023Printed: Page: 7 of 8 Klean Strip Paint Thinner SAFETY DATA SHEET 11/22/2022Supersedes Revision: CAS # Hazardous Components (Chemical Name) NTP 11. TOXICOLOGICAL INFORMATION Toxicological Information: IARC ACGIH OSHA This product has not been tested as a whole. Information below will be for individual ingredients. Refer to section 2 for acute and chronic health effects. CAS# 25551-13-7: Standard Draize Test, Skin, Species: Rabbit, 500.0 MG, 24 H, Moderate. Result: Kidney, Ureter, Bladder: Changes in liver weight. Endocrine: Changes in thymus weight. Immunological Including Allergic: Decreased immune response. - "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," , Institut Pro Vychovu Vedoucicn P, Marhold, J.V., Institut Pro Vychovu Vedoucicn, Pracovniku Chemickeho, Prumyclu Praha Czechoslovakia, Vol/p/yr: -,24, 1972 Standard Draize Test, Eyes, Species: Rabbit, 500.0 MG, 24 H, Mild. Result: Kidney, Ureter, Bladder: Changes in liver weight. Kidney, Ureter, Bladder: Changes in bladder weight. Nutritional and Gross Metabolic:Weight loss or decreased weight gain. - "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," , Institut Pro Vychovu Vedoucicn P, Marhold, J.V., Institut Pro Vychovu Vedoucicn, Pracovniku Chemickeho, Prumyclu Praha Czechoslovakia, Vol/p/yr: -,24, 1972 Stoddard solvent {Mineral spirits; Aliphatic Petroleum Distillates; White spirits} 8052-41-3 Benzene, Trimethyl- 25551-13-7 12. ECOLOGICAL INFORMATION Waste Disposal Method: 13. DISPOSAL CONSIDERATIONS Dispose in accordance with applicable local, state, and federal regulations. 14. TRANSPORT INFORMATION Flammable liquids, n.o.s. (Stoddard solvent, Benzene, Trimethyl-)DOT Proper Shipping Name: 3 FLAMMABLE LIQUIDDOT Hazard Class: UN1993UN/NA Number:IIIPacking Group: LAND TRANSPORT (US DOT): Additional Transport Information: The shipper / supplier may be able to apply one of the following exceptions if allowed under 49 CFR Regulations: Combustible Liquid, Consumer Commodity, Limited Quantity, Viscous Liquid, Does Not Sustain Combustion, or others, as allowed under 49 CFR Hazmat Regulations. Please consult 49 CFR Subchapter C to ensure that subsequent shipments comply with these exceptions. Please consult 49CFR Subchapter C to ensure that subsequent shipments comply with these exceptions. Licensed to W.M. Barr and Company: MIRS SDS, (c) A V Systems, Inc.GHS format 08/09/2023Revision: 08/10/2023Printed: Page: 8 of 8 Klean Strip Paint Thinner SAFETY DATA SHEET 11/22/2022Supersedes Revision: CAS # Hazardous Components (Chemical Name) 15. REGULATORY INFORMATION S. 302 (EHS) S. 304 RQ S. 313 (TRI) EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists Stoddard solvent {Mineral spirits; Aliphatic Petroleum Distillates; White spirits} No No No 8052-41-3 Benzene, Trimethyl- No No No 25551-13-7 CAS # Hazardous Components (Chemical Name) Other US EPA or State Lists Stoddard solvent {Mineral spirits; Aliphatic Petroleum Distillates; White spirits} TSCA: Inventory 8052-41-3 Benzene, Trimethyl- TSCA: Inventory 25551-13-7 Regulatory Information:This product is regulated by the United States Consumer Product Safety Commission and is subject to certain labeling requirements under the Federal Hazardous Substances Act. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS). The product label also includes other important information, including directions for use, and should always be read in its entirety prior to using the product. 16. OTHER INFORMATION Additional Information About This Product: Revision Date: Preparer Name: Previous revision:08/09/2023 11/22/2022 The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, state and local laws and regulations. Company Policy or Disclaimer: W.M. Barr and Company, Inc. (901)775-0100 Licensed to W.M. Barr and Company: MIRS SDS, (c) A V Systems, Inc.GHS format