HomeMy WebLinkAboutDAQ-2024-0120791
DAQC-CI108370001-24
Site ID 10837 (B1)
MEMORANDUM
TO: FILE – FLOWSERVE CORPORATION – Automatic Control Valves and
Sub-component Manufacturer
THROUGH: Chad Gilgen, Minor Source Compliance Section Manager
FROM: Daniel Riddle, Environmental Scientist
DATE: December 10, 2024
SUBJECT: FULL COMPLIANCE EVALUATION, Minor, Utah County
INSPECTION DATE: November 8, 2024
SOURCE LOCATION: 1350 North Mountain Springs Parkway
Springville, UT 84663
SOURCE CONTACTS: Brian Pike, Safety, Health, and ESA Manager
801-489-2489 bpike@flowserve.com
OPERATING STATUS: Operating, however the paint booths, sand blasting, and
generator were not in operation during the inspection.
PROCESS DESCRIPTION: The source manufactures automatic control valves and valve
subcomponents. The process begins with the machining down of
the steel to the finishing of the valves. Two paint booths are
present onsite and vented to the atmosphere. Also, some
sandblasting operations occur which includes venting the
exhaust through a baghouse.
APPLICABLE REGULATIONS: Approval Order (AO) DAQE-AN108370002-14, dated
September 22, 2014
MACT (Part 63) ZZZZ: National Emissions Standards for
Hazardous Air Pollutants for Stationary Reciprocating Internal
Combustion Engines,
SOURCE EVALUATION:
Name of Permittee: Permitted Location:
Flowserve Corporation - Automatic Control
Valves and Sub-component Manufacturer
1350 North Mountain Springs Parkway
P.O. Box 220
1350 North Mountain Springs Parkway
Springville, UT 846630903 Springville, UT 846630220
SIC Code: 3494: (Valves & Pipe Fittings, NEC)
) $ ' $ '
2
Section I: GENERAL PROVISIONS
I.1 All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and 40 CFR. Unless noted otherwise, references cited in these AO conditions refer to those rules. [R307-101]
I.2 The limits set forth in this AO shall not be exceeded without prior approval. [R307-401]
I.3 Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved. [R307-401-1]
I.4 All records referenced in this AO or in other applicable rules, which are required to be kept by the owner/operator, shall be made available to the Director or Director's representative upon request, and the records shall include the two-year period prior to the date of the request. Unless otherwise specified in this AO or in other applicable state and federal rules, records shall be kept for a minimum of two (2) years. [R307-401-8]
I.5 At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Director which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on equipment authorized by this AO shall be recorded. [R307-401-4]
I.6 The owner/operator shall comply with UAC R307-107. General Requirements: Breakdowns. [R307-107]
I.7 The owner/operator shall comply with UAC R307-150 Series. Emission Inventories. [R307-150] Status: In Compliance. No limits set forth in this AO appear to have been exceeded. The source stated that there have been no modifications to the equipment or processes. The equipment appeared to be properly operated and maintained according to manufacturer recommendations. Records are kept as required and were made available after the inspection. No breakdowns have been reported since the previous inspection. An emissions inventory was submitted for 2023, and emissions data are reported below.
Section II: SPECIAL PROVISIONS
II.A The approved installations shall consist of the following equipment:
II.A.1 Flowserve Corporation Automatic control valves and sub-component manufacturer
II.A.2 Natural Gas-Fired Ovens Two (2) rated at 0.75 MMBtu/hr each
II.A.3 Paint Booth One (1) Binks* Model CPFA-10-8-T-LH* (10'W x 8'H x 11'D)
II.A.4 Paint Booth One (1) Blecker* paint booth, Model SPF-14-10-10* (14'W x 10'H x 10'D)
II.A.5 Paint Booth - new equipment One (1) paint booth controlled with dry filter pads
II.A.6 Anodizing Equipment Miscellaneous anodizing equipment
3
II.A.7 Sandblasting Operations Sandblasting booth and baghouse
II.A.8 Welding Booth Miscellaneous welding equipment * Brand names and models are for information only
Status: In Compliance. The equipment observed on site is consistent with that listed with two exceptions. The Binks paint booth has been removed and there is an existing 75 kW emergency generator that was discovered during an inspection in 2015. The generator operates on natural gas. The hour meter read at 676.1 hrs at the time of inspection.
II.B Requirements and Limitations
II.B.1 Site-Wide Requirements. II.B.1.a Visible emissions from any point or fugitive emission source associated with the installation or control facilities shall not exceed 10% opacity. [R307-401-8] II.B.1.a.1 Opacity observations of emissions from stationary sources shall be conducted in accordance with 40 CFR 60, Appendix A, Method 9. [R307-401-8] Status: In Compliance. No visible emissions were observed from any point at the time of inspection. Method 9 was utilized to verify opacity limits. See attached VEO form. II.B.2 Conditions on the New Paint Booth II.B.2.a Flowserve Corporation shall notify the Director in writing when the new paint booth listed in Condition #II.A has been installed and is operational. To ensure proper credit when notifying the Director, send your correspondence to the Director, attn: Compliance Section. If the installation has not been completed within 18 months from the date of this AO, the Director shall be notified in writing on the status of the installation. At that time, the Director shall require documentation of the continuous installation of the equipment and may revoke the AO. [R307-401-18] Status: In Compliance. Notification was made and is located in the source file. II.B.3 Conditions on All Paint Booths II.B.3.a The paint booths shall be equipped with Andrea exhaust filter media made of non-fire supporting paper paint arrestor filters or equivalent to control particulate emissions. All air exiting the booths shall pass through this control system before being vented to the atmosphere. [R307-401-8] Status: In Compliance. The paint booths were fully equipped with filters that appeared to be in good condition. Filters are changed as need, and monometers indicate air flow through the filters. II.B.3.b The owner/operator shall comply with applicable requirements and limitations in R307-350. [R307-350] Status: In Compliance. CARBOGUARD 893 Part A from Carboline is used to coat products. It has a VOC content of 195 g/L or 1.68 lb/gal, in compliance with the limits in Table 1 of this rule. A Klean-Strip paint thinner is used for solvent cleaning. It has a vapor pressure of 0.3 mm Hg at 20 degrees Celsius. See the attached SDS for more information.
4
II.B.4 VOC and HAP Limitations II.B.4.a The plant-wide emissions of VOCs and HAPs from the paint booths and associated operations shall not exceed: 10.00 tons per rolling 12-month period for VOCs including all HAPs below 254 pounds per rolling 12-month period for ethyl benzene 26 pounds per rolling 12-month period for formaldehyde 173 pounds per rolling 12-month period for methanol 101 pounds per rolling 12-month period for methyl isobutyl ketone 965 pounds per rolling 12-month period for toluene 1421 pounds per rolling 12-month period for xylene 1.47 tons per rolling 12-month period for total HAPs. [R307-401-8] II.B.4.a.1 Compliance with the limitations shall be determined on a rolling 12-month total. No later than 20 days after the end of each month, a new 12-month total shall be calculated using data from the previous 12 months. The records of consumption shall be kept on a monthly basis. [R307-401-8] II.B.4.a.2 The VOC and HAP emissions shall be determined by maintaining a record of VOC- and HAP-emitting materials used each month. The record shall include the following data for each material used: A. Name of the VOC- and HAP-emitting material, such as: paint, adhesive, solvent, thinner, reducers, etc. B. Density of each material used (pounds per gallon) C. Percent by weight of all VOC and HAP in each material used D. Gallons of each VOC- and HAP-emitting material used E. The amount of VOC and HAP emitted monthly by each material used shall be calculated by the following procedure: VOC = % VOC by Weight x [Density ( lb )] x Gal Consumed x 1 ton (100) (gal) 2000 lb HAP = % HAP by Weight x [Density ( lb )] x Gal Consumed x 1 ton (100) (gal) 2000 lb F. The amount of VOC or HAP emitted monthly from all materials used. G. The amount of VOCs or HAPs reclaimed for the month shall be similarly quantified and subtracted from the quantities calculated above to provide the monthly total VOC or HAP emissions. [R307-401-8] Status: In Compliance. Emissions appear to be calculated correctly. For the rolling 12-month period from October 2023 - September 2024, emissions are as follows: 0.4944 tons for VOCs 0 lbs for ethyl benzene 0 lbs for formaldehyde 0 lbs for methanol 0 lbs for methyl isobutyl ketone 0.01 lbs for toluene 970.78 lbs for xylene 0.49415 tons for all HAPS See the attached table for more information.
5
II.B.5 Conditions on the Sandblasting Operations. II.B.5.a The baghouse shall control process streams from the sandblasting operations. All exhaust air from the sandblasting operations shall be routed through the baghouse before being vented to the atmosphere. [R307-401-8] Status: In Compliance. The sandblasting operations are routed through the baghouse. II.B.5.b Sandblasting operations shall be limited to 3,000 hours per rolling 12-month period. [R307-401-8] II.B.5.b.1 To determine compliance with a rolling 12-month total, the owner/operator shall calculate a new 12-month total by the twentieth day of each month using data from the previous 12 months. Records of hours of operation shall be kept for all periods when the plant is in operation. The records of hours of operation shall be kept on a daily basis. Hours of operation shall be determined by supervisor monitoring and maintaining of an operations log. [R307-401-8] Status: In Compliance. For the rolling 12-month period from October 2023 - September 2024, sandblasting took place for a total of 214 hours. See the attached table for more information.
Section III: APPLICABLE FEDERAL REQUIREMENTS
In addition to the requirements of this AO, all applicable provisions of the following federal programs
have been found to apply to this installation. This AO in no way releases the owner or operator from any
liability for compliance with all other applicable federal, state, and local regulations including UAC
R307.
MACT (Part 63) ZZZZ: National Emissions Standards for Hazardous Air Pollutants for Stationary
Reciprocating Internal Combustion Engines
Status: In Compliance. There is an existing 75 kW emergency generator that was discovered during an
inspection in 2015. The generator operates on natural gas. A Warning (DAQC-1568-15) was issued
under the condition that the source would add it to the equipment list the next time a modification is
made to the AO. The generator has been operated for a total of 15 hours in 2024.
AREA SOURCE RULES EVALUATION:
The following Area Source Rules were evaluated during this inspection:
National Emission Standards for Hazardous Air Pollutants [R307-214]
Status: In Compliance. Compliance with this area source rule is satisfied by compliance with Federal
Requirement MACT (Part 63) Subpart ZZZZ. See Section III above for more information.
PM10 Nonattainment and Maintenance Areas: Abrasive Blasting [R307-306]
Status: In Compliance. Sandblasting is conducted in an enclosed room which vents through a
baghouse. No visible emissions were observed at the time of inspection.
Miscellaneous Metal Parts and Products Coatings [R307-350]
Status: In Compliance. See status of condition II.B.3.b for more information.
6
EMISSION INVENTORY:
Listed below are the Actual Emissions Inventory provided from Flowserve Corporation - Automatic
Control Valves and Sub-component Manufacturer for the 2023 emissions reporting year. A comparison of
the estimated total potential emissions (PTE) on AO: DAQE-AN108370002-14, dated September 22,
2014, is provided. PTE are supplied for supplemental purposes only.
Criteria Pollutant PTE tons/yr Actuals tons/yr
CO2 Equivalent 258.00 N/A
Carbon Monoxide 0.03 0.00962
Nitrogen Oxides 0.25 0.002835
Particulate Matter - PM10 0.88 0.15534
Particulate Matter - PM2.5 0.88 0.00173
Sulfur Dioxide 0.00 0.00007
Volatile Organic Compounds 10.00 0.07621
Hazardous Air Pollutant PTE lbs/yr Actuals lbs/yr
Ethyl Benzene (CAS #100414) 260 N/A
Formaldehyde (CAS #50000) 20 N/A
Methanol (CAS #67561) 180 N/A
Methyl Isobutyl Ketone (Hexone) (CAS #108101) 100 N/A
Toluene (CAS #108883) 960 N/A
Xylenes (Isomers And Mixture) (CAS #1330207) 1420 N/A
PREVIOUS ENFORCEMENT
ACTIONS: No enforcement action within the past five years.
COMPLIANCE STATUS &
RECOMMENDATIONS: In regards to Approval Order (AO) DAQE-AN108370002-14,
dated September 22, 2014, the overall status is: In Compliance.
The facility appears to be well maintained and operated.
Required records were current and made available during the
inspection.
HPV STATUS: Not Applicable.
RECOMMENDATION FOR
NEXT INSPECTION: Inspect as normal.
NSR RECOMMENDATIONS: Add the pre-existing 75 kW generator to the equipment list with
the next AO modification.
ATTACHMENTS: VEO form, email correspondence, rolling 12s, generator usage,
SDS
Daniel Riddle <driddle@utah.gov>
10837 - Follow up to air quality inspection
8 messages
Daniel Riddle <driddle@utah.gov>Fri, Nov 8, 2024 at 9:35 AM
To: bpike@flowserve.com
Brian,
Thank you for meeting today for your air quality inspection. As discussed, here are the records I will require to complete
my inspection report:
From AO DAQE- AN108370002-14 (attached):
Condition II.B.4.a - VOC and HAP emissions, itemized as required (Oct 23 - Sept 24)
Condition II.B.5.b - hours of sandblasting operations (Oct 23 - Sept 24)
40 CFR Part 63 Subpart ZZZZ (https://www.ecfr.gov/current/title-40/chapter-I/subchapter-C/part-63/subpart-ZZZZ)
hours of usage for maintenance of the 75 kW natural gas generator (Oct 23 - Sept 24)
Additionally, for Condition II.B.3.b / UAC R307-350 (attached):
307-350-5 - For any products that would fall under Table 1, I need a copy of an SDS or EDS or TDS that shows the VOC
content in the appropriate units and shows it is compliant with the limits
307-350-7 - If any solvent cleaning products are used (such as for cleaning paint brushes), I need an SDS or EDS or TDS
for the product(s) that shows the VOC composite vapor pressure is no greater than 1 mmHG at 20 degrees Celsius
Please provide these records by November 15, 2024. Let me know if you have any questions.
Best,
Daniel
2 attachments
R307-350.pdf
99K
10837 AO.pdf
3512K
Pike, Brian <BPike@flowserve.com>Tue, Nov 12, 2024 at 8:27 AM
To: Daniel Riddle <driddle@utah.gov>
Daniel,
I have attached all the requested data we discussed. Please let me know if you need anything else.
Thank You
Brian Pike
HSE Manager
Flowserve Corporation
11/21/24, 9:57 AM State of Utah Mail - 10837 - Follow up to air quality inspection
https://mail.google.com/mail/u/0/?ik=3e54b7a6bd&view=pt&search=all&permthid=thread-a:r8774165004592784359&simpl=msg-a:r-25473196991783…1/6
1350 N. Mountain Springs Pkwy
Springville, Utah 84663
Office: (801) 489-2226
Cell: (385) 327-9637
Email: bpike@flowserve.com
From: Daniel Riddle <driddle@utah.gov>
Sent: Friday, November 8, 2024 9:35 AM
To: Pike, Brian <BPike@flowserve.com>
Subject: [External] 10837 - Follow up to air quality inspec on
CAUTION: This email originated from outside of Flowserve. Do not click links or open attachments unless you can
confirm the sender and know the content is safe.
[Quoted text hidden]
4 attachments
IMG_1458.jpeg
2892K
Thinner SDS.pdf
404K
Carboguard 893 SDS.pdf
416K
VOC_HAPs_SandblastTotals.xlsx
22K
Daniel Riddle <driddle@utah.gov>Tue, Nov 12, 2024 at 9:39 AM
To: "Pike, Brian" <BPike@flowserve.com>
11/21/24, 9:57 AM State of Utah Mail - 10837 - Follow up to air quality inspection
https://mail.google.com/mail/u/0/?ik=3e54b7a6bd&view=pt&search=all&permthid=thread-a:r8774165004592784359&simpl=msg-a:r-25473196991783…2/6
Thank you - I'll look it over and let you know if we need anything else.
[Quoted text hidden]
Daniel Riddle <driddle@utah.gov>Wed, Nov 20, 2024 at 2:56 PM
To: "Pike, Brian" <BPike@flowserve.com>
Brian,
The thinner you are using may not be compliant with R307-350. The SDS you sent me shows a vapor pressure of 4.8
mmHg at 20 degrees Celsius. It also has a relatively high VOC content of 909 g/L. R307-350-7(2) states:
I'm attaching a SDS for a similar compliant product. You can see that the vapor pressure is only 0.22 mmHg at room
temperature.
At this time, if you can commit to discontinuing this thinner and switching to a compliant thinner no later than November
2025, we can mark this as out of compliance with no action recommended. Please let me know if you have any
questions.
[Quoted text hidden]
Paint-thinner-kleanstrip.pdf
24K
Pike, Brian <BPike@flowserve.com>Wed, Nov 20, 2024 at 3:17 PM
To: Daniel Riddle <driddle@utah.gov>
Daniel,
Thank You for bringing this to our attention, we have been using Klean Strip and I sent the old SDS (by
Mistake)… We are using Klean Strip (See Pic Below). We will commit to continue to use as well.
Thank You!
11/21/24, 9:57 AM State of Utah Mail - 10837 - Follow up to air quality inspection
https://mail.google.com/mail/u/0/?ik=3e54b7a6bd&view=pt&search=all&permthid=thread-a:r8774165004592784359&simpl=msg-a:r-25473196991783…3/6
Brian Pike
HSE Manager
Flowserve Corporation
1350 N. Mountain Springs Pkwy
Springville, Utah 84663
Office: (801) 489-2226
Cell: (385) 327-9637
Email: bpike@flowserve.com
11/21/24, 9:57 AM State of Utah Mail - 10837 - Follow up to air quality inspection
https://mail.google.com/mail/u/0/?ik=3e54b7a6bd&view=pt&search=all&permthid=thread-a:r8774165004592784359&simpl=msg-a:r-25473196991783…4/6
From: Daniel Riddle <driddle@utah.gov>
Sent: Wednesday, November 20, 2024 2:56 PM
To: Pike, Brian <BPike@flowserve.com>
Subject: [External] Re: [External] 10837 - Follow up to air quality inspec on
CAUTION: This email originated from outside of Flowserve. Do not click links or open attachments unless you can
confirm the sender and know the content is safe.
Brian,
The thinner you are using may not be compliant with R307-350. The SDS you sent me shows a vapor pressure of 4.8
mmHg at 20 degrees Celsius. It also has a relatively high VOC content of 909 g/L. R307-350-7(2) states:
[Quoted text hidden]
[Quoted text hidden]
Daniel Riddle <driddle@utah.gov>Thu, Nov 21, 2024 at 8:32 AM
To: "Pike, Brian" <BPike@flowserve.com>
Thanks for correcting that - can you send me the SDS or EDS or TDS for Klean Strip Lacquer thinner to show that this
product is compliant with the the 1mmHG at 20 degrees Celsius limit?
[Quoted text hidden]
Pike, Brian <BPike@flowserve.com>Thu, Nov 21, 2024 at 9:33 AM
To: Daniel Riddle <driddle@utah.gov>
Daniel,
11/21/24, 9:57 AM State of Utah Mail - 10837 - Follow up to air quality inspection
https://mail.google.com/mail/u/0/?ik=3e54b7a6bd&view=pt&search=all&permthid=thread-a:r8774165004592784359&simpl=msg-a:r-25473196991783…5/6
Attached is the Thinner SDS.
[Quoted text hidden]
KleanStrip Thinner.pdf
127K
Daniel Riddle <driddle@utah.gov>Thu, Nov 21, 2024 at 9:57 AM
To: "Pike, Brian" <BPike@flowserve.com>
Thank you for sending this! I'll let you know if I need anything else.
[Quoted text hidden]
11/21/24, 9:57 AM State of Utah Mail - 10837 - Follow up to air quality inspection
https://mail.google.com/mail/u/0/?ik=3e54b7a6bd&view=pt&search=all&permthid=thread-a:r8774165004592784359&simpl=msg-a:r-25473196991783…6/6
MONTH/YEAR VOC POUNDSTOLUENEXYLENETOTAL HAPs
December 2023 77.41 0.00 77.41 77.41
January 2024 80.10 0.00 80.10 80.10
February 2024 77.99 0.00 77.99 77.99
March 2024 70.33 0.00 70.33 70.33
April 2024 106.13 0.00 106.13 106.13
May 2023 87.55 0.00 87.55 87.55
June 2024 71.73 0.00 71.73 71.73
July 2024 94.16 0.00 94.16 94.16
August 2024 74.38 0.01 74.38 74.39
September 2024 96.41 0.00 96.41 96.41
October 2023 72.83 0.00 72.83 72.83
November 2023 79.80 0.00 61.76 79.80December 2024 0.00 0.00 0.00 0.00
Total POUNDS 988.82 0.01 970.78 988.83
Total TONS 0.4944 988.83
Flowserve Springville
VOC Rolling Totals with
HAPs - Toluene & Xylene
Permitted Plant-Wide 10 Tons VOCs
Oven
Hours X
0.75 =
BTU X 0.14
=
BTU X
.0006 =
Month Hours BTU's Total NOx
lbs
Total SOx
lbs
Jan- 24 27 20.25 2.940 0.0126Feb-24 20 15.00 2.100 0.0090Mar-23 34 25.50 3.570 0.0153Apr-24 32 24.00 3.360 0.0144May-24 22 16.50 2.310 0.0099Jun-24 17 12.75 1.785 0.0077
Jul-24 25 18.75 2.625 0.0113
Aug-24 28 21.00 2.940 0.0126
Sep-24 38 28.50 3.990 0.0171
Oct-23 24 18.00 2.520 0.0108
Nov-23 11 8.25 1.155 0.0050Dec-23 17 12.75 1.785 0.0077
TOTALS 295 221.25 31.080 0.133
Month Sandblast
Hours
Hours X
0.57 = lbs
of PM10
Jan- 24 29 16.53
Feb-24 14 7.98
Mar-24 46 26.22
Apr-24 27 15.39
May-24 14 7.98
Jun-24 8 4.56
Jul-24 34 19.38
Aug-24 19 10.83
Sep-24 23 13.11
Oct-23 15 8.55
Nov-23 14 7.98
Dec-23 11 6.27TOTALS254144.78
NOx, SOx Rolling Totals
OVEN ROLLING TOTALS
PM10 Rolling Totals
ANDBLAST ROLLING TOTAL
Month Oven Start End Total Month Start End Total
Jan-24 1 1781 1781 0 Jan-24
27 2 4220 4247 27 29Feb-24 1 1781 1781 0 Feb-24
20 2 4247 4267 20 14Mar-24 1 1781 1781 0 Mar-24
13 2 4267 4280 13 21
Apr-24 1 1781 1795 14 Apr-24
32 2 4280 4298 18 27
May-24 1 1795 1799 4 May-24
22 2 4298 4316 18 14
Jun-24 1 1799 1799 0 Jun-2417243164333178
Jul-24 1 1799 1799 0 Jul-24
27 2 4333 4360 27 19
Aug-24 1 1799 1799 0 Aug-24
28 2 4360 4388 28 19
Sep-24 1 1799 1800 1 Sep-24
38 2 4388 4425 37 23Oct-23 1 1781 1781 0 Oct-23
24 2 4168 4192 24 15Nov-23 1 1781 1781 0 Nov-23
11 2 4192 4203 11 14
Dec-23 1 1781 1781 0 Dec-23
17 2 4203 4220 17 11
276 214
OVEN & SANDBLAST USAGE
Oven Useage Sandblast Useage
6945 6974 29
6974 6988 14
6988 7009 21
7009 7036 27
7036 7050 14
7050 7058 8
7058 7077 19
7077 7096 19
7096 7119 23
6905 6920 15
6920 6934 14
6934 6945 11
OVEN TOTALS SandBLAST TOTAL
Date Printed: 05/11/2023 Product: 0988A1NL
Safety Data Sheet
Prepared in Accordance with HCS 29
C.F.R. 1910.1200
1. Identification of the Substance/Mixture and the Company/Undertaking
1.1 Product Identifier 0988A1NL Revision Date:12/05/2022
Supercedes Date:02/16/2022Product Name:CARBOGUARD 893
PART A
Component of
multicomponent industrialcoatings - Industrial use.
1.2 Relevant identified uses of the
substance or mixture and usesadvised against
1.3 Details of the supplier of the safety data sheet
Manufacturer:Carboline Global Inc.
2150 Schuetz Road
St. Louis, MO USA 63146
Regulatory / Technical Information:
Contact Carboline Technical Services at
1-800-848-4645
Schlereth, Ken - regulatory@carboline.comDatasheet Produced by:
Emergency telephone number:1.4 CHEMTREC 1-800-424-9300 (Inside US)CHEMTREC +1 703 5273887 (Outside US)
HEALTH - Pittsburgh Poison Control 1-412-681-6669
2. Hazard Identification
2.1 Classification of the substance or mixture
Hazardous to the aquatic environment, Chronic, category 3
Carcinogenicity, category 1AEye Irritation, category 2
Flammable Liquid, category 2
Reproductive Toxicity, category 2
STOT, repeated exposure, category 1
Skin Irritation, category 2Skin Sensitizer, category 1
Page 1 / 11
Date Printed: 05/11/2023 Product: 0988A1NL
2.2 Label elements
Symbol(s) of Product
Signal Word
Danger
Named Chemicals on Label
TOLUENE, MICROCRYSTALLINE SILICA, EPOXY RESIN, BISPHENOL A EPOXY RESIN
HAZARD STATEMENTS
H225 Highly flammable liquid and vapour.Flammable Liquid, category 2
H315 Causes skin irritation.Skin Irritation, category 2
H317 May cause an allergic skin reaction.Skin Sensitizer, category 1
H319 Causes serious eye irritation.Eye Irritation, category 2
H350-1A May cause cancer.Carcinogenicity, category 1A
H361 Suspected of damaging fertility or the unborn child.Reproductive Toxicity, category 2
H372 Causes damage to organs through prolonged or repeated
exposure.STOT, repeated exposure, category 1
H412 Harmful to aquatic life with long lasting effects.Hazardous to the aquatic environment,
Chronic, category 3
PRECAUTION PHRASES
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. – No
smoking.
P235 Keep cool.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/
face protection.
P284 Wear respiratory protection.
P302+352 IF ON SKIN: Wash with plenty of soap and water.
P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do so.Continue rinsing.
P308+313 IF exposed or concerned: Get medical advice/attention
P314 Get medical advice/attention if you feel unwell.
P333+313 If skin irritation or rash occurs: Get medical advice/attention.
P403+233 Store in a well-ventilated place. Keep container tightlyclosed.
2.3 Other hazards
No Information
Results of PBT and vPvB assessment:
The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.
3. Composition/Information On Ingredients
3.2 Mixtures
Page 2 / 11
Date Printed: 05/11/2023 Product: 0988A1NL
Hazardous ingredients
Name According to EEC EINEC No.CAS-No.%Classifications
MICROCRYSTALLINE
SILICA
238-878-4 14808-60-7 50 - <75 H350-372 Carc. 1A, STOT RE 1
TITANIUM DIOXIDE 236-675-5 13463-67-7 10 - <25
BISPHENOL A EPOXY
RESIN
500-033-5 25068-38-6 10 - <25 H315-317-319-411 Aquatic Chronic 2, Eye Irrit. 2,
Skin Irrit. 2, Skin Sens. 1
EPOXY RESIN 607-500-3 25036-25-3 2.5 - <10 H315-317-319
TOLUENE 203-625-9 108-88-3 2.5 - <10 H225-304-315-319-332-335-336
-361-370-412
Acute Tox. 4 Inhalation,
Aquatic Chronic 3, Asp. Tox.
1, Eye Irrit. 2, Flam. Liq. 2,
Repr. 2, Skin Irrit. 2, STOT SE1, STOT SE 3 NE, STOT SE 3
RTI
CARBON BLACK 215-609-9 1333-86-4 2.5 - <10
METHYL ETHYL
KETONE
201-159-0 78-93-3 1.0 - <2.5 H225-319-336 Eye Irrit. 2, Flam. Liq. 2, STOT
SE 3 NE
ISOPROPANOL 200-661-7 67-63-0 1.0 - <2.5 H225-319-336 Eye Irrit. 2, Flam. Liq. 2, STOT
SE 3 NE
META-XYLENE 203-576-3 108-38-3 1.0 - <2.5 H312-315-332
1-METHOXY-2-
PROPANOL ACETATE
203-603-9 108-65-6 1.0 - <2.5 H226 Flam. Liq. 3
ETHYL BENZENE 202-849-4 100-41-4 0.1 - <1.0 H225-304-315-319-332-351-373
-412
Acute Tox. 4 Inhalation,
Aquatic Chronic 3, Asp. Tox.
1, Carc. 2, Eye Irrit. 2, Flam.
Liq. 2, Skin Irrit. 2, STOT RE 2
CAS-No.M-Factors
14808-60-7 0
13463-67-7 0
25068-38-6 0
25036-25-3 0
108-88-3 0
1333-86-4 0
78-93-3 0
67-63-0 0
108-38-3 0
108-65-6 0
100-41-4 0
Remarks:CAS No 13463-67-7: Note 10
CAS No. 25068-38-6 identified as CAS No. 1675-54-3, EC No. 216-823-5 under REACH Registration
Additional Information:The text for GHS Hazard Statements shown above (if any) is given in Section 16.
4. First-aid Measures
4.1 Description of First Aid Measures
AFTER INHALATION:Give oxygen or artificial respiration if needed. Remove person to fresh air. If signs/symptoms
continue, get medical attention.
AFTER SKIN CONTACT:In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. If skin irritation persists, call a physician.
AFTER EYE CONTACT:Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Page 3 / 11
Date Printed: 05/11/2023 Product: 0988A1NL
AFTER INGESTION:Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If swallowed, call
a poison control centre or doctor immediately.
4.2 Most important symptoms and effects, both acute and delayed
Harmful if swallowed. Irritating to eyes and skin. Risk of serious damage to the lungs (by aspiration). Vapours may cause
drowsiness and dizziness.
4.3 Indication of any immediate medical attention and special treatment needed
No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if
available, can be found in section 11.
When symptoms persist or in all cases of doubt seek medical advice.
5. Fire-fighting Measures
5.1 Extinguishing Media:
Carbon Dioxide, Dry Chemical, Foam, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS:Flammable liquid. Vapours are heavier than air and may spread along
floors. Vapours may form explosive mixtures with air. Vapors may travel to areas away from work site before igniting/flashing
back to vapor source. Provide adequate ventilation. Prevent the creation of flammable or explosive concentrations of vapour
in air and avoid vapour concentration higher than the occupational exposure limits. Keep away from heat/sparks/open
flames/hot surfaces. -No smoking. Electrical installations / working materials must comply with the technological safety
standards. Wear shoes with conductive soles.
FOR SAFETY REASONS NOT TO BE USED:No Information
5.2 Special hazards arising from the substance or mixture
No Information
5.3 Advice for firefighters
SPECIAL FIREFIGHTING PROCEDURES: In the event of fire, wear self-contained breathing apparatus. Cool containers /
tanks with water spray. Flammable.
SPECIAL FIREFIGHTING PROTECTION EQUIPMENT: No Information
6. Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation. Evacuate personnel to safe areas. Remove all sources of ignition. To avoid ignition of vapours
by static electricity discharge, all metal parts of the equipment must be grounded. Wear personal protective equipment. For
personal protection see section 8.
6.2 Environmental precautions
Do not allow material to contaminate ground water system. Prevent product from entering drains.
6.3 Methods and material for containment and cleaning up
Prevent further leakage or spillage if safe to do so. Contain spillage, soak up with non-combustible absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations
(see section 13).
Reference to other sections6.4
No Information
7. Handling and Storage
7.1 Precautions for safe handling
INSTRUCTIONS FOR SAFE HANDLING :Keep containers dry and tightly closed to avoid moisture absorption and
contamination. Prepare the working solution as given on the label(s) and/or the user instructions. Do not breathe vapours or
spray mist. Ensure all equipment is electrically grounded before beginning transfer operations. Do not use sparking tools.
Page 4 / 11
Date Printed: 05/11/2023 Product: 0988A1NL
Do not get in eyes, on skin, or on clothing. Use only with adequate ventilation/personal protection. Wash thoroughly after
handling.
PROTECTION AND HYGIENE MEASURES :Handle in accordance with good industrial hygiene and safety practice. Wash
hands before breaks and at the end of workday. When using, do not eat, drink or smoke.
7.2 Conditions for safe storage, including any incompatibilities
CONDITIONS TO AVOID:Heat, flames and sparks.
STORAGE CONDITIONS:Keep container closed when not in use. Store in a dry, well ventilated place away from sources of
heat, ignition and direct sunlight.
7.3 Specific end use(s)
No specific advice for end use available.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Ingredients with Occupational Exposure Limits
(US)
Name ACGIH TWA ACGIH STEL ACGIH CeilingCAS-No.
MICROCRYSTALLINE SILICA 14808-60-7 0.025 MGM3 N/E N/E
TITANIUM DIOXIDE 13463-67-7 10 mg/m3 N/E N/E
BISPHENOL A EPOXY RESIN 25068-38-6 N/E N/E N/E
EPOXY RESIN 25036-25-3 N/E N/E N/E
TOLUENE 108-88-3 20 PPM N/E N/E
CARBON BLACK 1333-86-4 3 MGM3 N/E N/E
METHYL ETHYL KETONE 78-93-3 200 PPM 300 PPM N/E
ISOPROPANOL 67-63-0 200 PPM 400 PPM N/E
META-XYLENE 108-38-3 100 PPM 150 PPM N/E
1-METHOXY-2-PROPANOL ACETATE 108-65-6 N/E N/E N/E
ETHYL BENZENE 100-41-4 20 PPM 125 ppm
Name CAS-No.OSHA PEL OSHA STEL
MICROCRYSTALLINE SILICA 14808-60-7 0.05 MGM3 N/E
TITANIUM DIOXIDE 13463-67-7 15 MGM3 N/E
BISPHENOL A EPOXY RESIN 25068-38-6 N/E N/E
EPOXY RESIN 25036-25-3 N/E N/E
TOLUENE 108-88-3 200 ppm 560 MGM3, 150
PPM
CARBON BLACK 1333-86-4 3.5 MGM3 N/E
METHYL ETHYL KETONE 78-93-3 590 MGM3, 200 PPM885 MGM3, 300
PPM
ISOPROPANOL 67-63-0 980 MGM3, 400 PPM1225 MGM3,
500 PPM
Page 5 / 11
Date Printed: 05/11/2023 Product: 0988A1NL
META-XYLENE 108-38-3 100.00 PPM N/E
1-METHOXY-2-PROPANOL ACETATE 108-65-6 N/E N/E
ETHYL BENZENE 100-41-4 435 MGM3, 100 PPM545 MGM3, 125
PPM
FURTHER ADVICE:Refer to the regulatory exposure limits for the workforce enforced in each country. Some components may
not have been classified under the EU CLP Regulation.
8.2 Exposure controls
Personal Protection
RESPIRATORY PROTECTION:In order to avoid inhalation of spray-mist and sanding dust, all spraying and sanding must
be done wearing adequate respirator. Use only with ventilation to keep levels below exposure guidelines reported in this
document. User should test and monitor exposure levels to ensure all personnel are below guidelines. If not sure, or not able
to monitor, use State or federally approved supplied air respirator. For silica containing coatings in a liquid state, and/or if no
exposure limits are established above, air-supplied respirators are generally not required.
EYE PROTECTION:Safety glasses with side-shields.
HAND PROTECTION:Gloves should be discarded and replaced if there is any indication of degradation or chemical
breakthrough. Impervious gloves. Request information on glove permeation properties from the glove supplier. Lightweight
protective clothing
OTHER PROTECTIVE EQUIPMENT:Ensure that eyewash stations and safety showers are close to the workstation location.
ENGINEERING CONTROLS:Avoid contact with skin, eyes and clothing. Ensure adequate ventilation, especially in confined
areas.
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance:Viscous Liquid, Various Colors
Physical State Liquid
Odor Epoxy
Odor threshold N/D
pH N/D
Melting point / freezing point (°C)N/D
Boiling point/range (°C)173 F (78 C) - 500 F (260 C)
Flash Point (°C)61F (16C)
Evaporation rate Slower than Ether
Not determinedFlammability (solid, gas)
Upper/lower flammability or explosive
limits
0.5 - 12.0
Vapour Pressure, mmHg N/D
Vapour density Heavier than Air
Relative density Not determined
Solubility in / Miscibility with water N/D
Partition coefficient: n-octanol/water Not determined
Auto-ignition temperature (°C)Not determined
Decomposition temperature (°C)Not determined
Page 6 / 11
Date Printed: 05/11/2023 Product: 0988A1NL
Viscosity Unknown
Explosive properties Not determined
Oxidising properties Not determined
9.2 Other information
VOC Content g/l:195
app 1.56Specific Gravity (g/cm3)
10. Stability and Reactivity
10.1 Reactivity
No reactivity hazards known under normal storage and use conditions.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
Hazardous polymerisation does not occur.
10.4 Conditions to avoid
Heat, flames and sparks.
10.5 Incompatible materials
Strong oxidizing agents.
10.6 Hazardous decomposition products
Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense black smoke.
Page 7 / 11
Date Printed: 05/11/2023 Product: 0988A1NL
11. Toxicological Information
11.1 Information on toxicological effects
Acute Toxicity:
Oral LD50:N/D
Inhalation LC50:N/D
Eye Irritation and Skin Irritation, category 2Irritation:
UnknownCorrosivity:
Skin Sensitizer, category 1Sensitization:
UnknownRepeated dose toxicity:
Carcinogenicity, category 1ACarcinogenicity:
UnknownMutagenicity:
Reproductive Toxicity, category 2Toxicity for reproduction:
UnknownSTOT-single exposure:
STOT, repeated exposure, category 1STOT-repeated exposure:
UnknownAspiration hazard:
If no information is available above under Acute Toxicity then the acute effects of this product have not been tested.
Data on individual components are tabulated below:
Chemical Name Oral LD50 Dermal LD50 Vapor LC50 Gas LC50 Dust/Mist
LC50CAS-No.
14808-60-7 MICROCRYSTALLINE SILICA 22500 mg/kg Not Available Not Available 0.000 0.000
13463-67-7 TITANIUM DIOXIDE 25000 mg/kg,
oral (rat)Not Available Not Available No
Information
No
Information
25068-38-6 BISPHENOL A EPOXY RESIN 11400 mg/kg,
rat, oral
23000 mg/kg,
dermal, rabbit
>20 mL/kg
skin,
sensitizer
25036-25-3 EPOXY RESIN >2000 mg/kg,oral, rat >2000 mg/kg,dermal, rat Not Available 0.000 0.000
108-88-3 TOLUENE 5000 mg/kg
rat oral
12267 mg/kg,
dermal, rabbit
8000 ppm/4
hrs, rat,
inhalation
0.000 0.000
1333-86-4 CARBON BLACK 8000 mg/kg
oral, rat Not Available Not Available
78-93-3 METHYL ETHYL KETONE 2194 mg/kgrat, oral Not Available
34.5 mg/L/ 4
hour rat,inhalation 0.000 0.000
67-63-0 ISOPROPANOL 4720 mg/kg
rat, oral
12800 mg/kg,
dermal, rabbit
22500ppm/8hrs rat,
inhalation
0.000 0.000
108-38-3 META-XYLENE Not Available Not Available Not Available 0.000 0.000
Page 8 / 11
Date Printed: 05/11/2023 Product: 0988A1NL
108-65-6 1-METHOXY-2-PROPANOL
ACETATE
8532 mg/kg,
oral (rat)>5000 mg/kg 101 ppm/4 hr,
rat, inh 0.000 0.000
100-41-4 ETHYL BENZENE 3500 mg/kg
rat, oral
>5000 mg/l,
dermal rabbit
17.2 mg/L
Inh, Rat, 4Hr 0.000 0.000
Additional Information:
This product may contain Ethyl Benzene, which is listed by IARC as possibly carcinogenic to humans (Group 2B). This listing is
based on inadequate evidence of carcinogenicity in humans and sufficient evidence in experimental animals. Constituents of this
product may include crystalline silica which, if inhalable, may cause silicosis, a form or progressive pulmonary fibrosis. Inhalable
crystalline silica is listed by IARC as a group 1 carcinogen (lung) based on sufficient evidence in occupationally exposed humans and
sufficient evidence in animals. Crystalline silica is also listed by the NTP as a known human carcinogen. This classification isrelevant when exposed to Quartz (silicon dioxide) in dust or powder form only, including cured product that is subject to sanding,
grinding, cutting, or other surface preparation activities. Constituents may also include abestiform or non-asbestiform tremolite or
other silicates as impurities, and above dei minimus exposure to these impurities in inhalable form may be carcinogenic or cause
other serious lung problems.
12. Ecological Information
12.1 Toxicity:
EC50 48hr (Daphnia):Unknown
UnknownIC50 72hr (Algae):
UnknownLC50 96hr (fish):
12.2 Persistence and degradability:Unknown
12.3 Bioaccumulative potential:Unknown
12.4 Mobility in soil:Unknown
12.5 Results of PBT and vPvB
assessment:
The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.
12.6 Other adverse effects:Unknown
Chemical Name EC50 48hr IC50 72hr LC50 96hrCAS-No.
14808-60-7 MICROCRYSTALLINE SILICA No information No information No information
13463-67-7 TITANIUM DIOXIDE No information No information No information
25068-38-6 BISPHENOL A EPOXY RESIN 2.1 mg/l (daphnia)11 mg/l (algae)1.3 mg/l (fish)
25036-25-3 EPOXY RESIN No information No information No information
108-88-3 TOLUENE 6 mg/l (Daphnia magna)12.5 mg/L (Algae)5.8 mg/L (Fish)
1333-86-4 CARBON BLACK No information No information No information
78-93-3 METHYL ETHYL KETONE 308 mg/l (Daphnia
magna)No information 2993 mg/l (Pimephales
promelas)
67-63-0 ISOPROPANOL 13299 mg/l (Daphnia
Magna)
>1000 m/gL
(desmodesmussubspicatus)
9640 mg/L (pimphales
promelas)
108-38-3 META-XYLENE No information No information No information
108-65-6 1-METHOXY-2-PROPANOL ACETATE 408 mg/l (Daphnia
Magna)
>1000 mg/l (Green
Algae)161 mg/l (Fathead Minnow)
100-41-4 ETHYL BENZENE 1.8 mg/l (Daphnia
Magna)4.6 mg/l (Green Algae)4.2 mg/l (Rainbow Trout)
13. Disposal Considerations
Page 9 / 11
Date Printed: 05/11/2023 Product: 0988A1NL
13.1 WASTE TREATMENT METHODS:Do not burn, or use a cutting torch on, the empty drum. If recycling is not practicable,
dispose of in compliance with local regulations. Dispose of in accordance with local regulations. Empty containers should be
taken to an approved waste handling site for recycling or disposal.
14. Transport Information
14.1 UN number UN1263
UN proper shipping name14.2 Paint
N/ATechnical name
14.3 3Transport hazard class(es)
N/ASubsidiary shipping hazard
Packing group14.4 II
14.5 Marine Pollutant: Yes (Epoxy Resin)Environmental hazards
Special precautions for user Unknown14.6
EmS-No.:F-E, S-E
Transport in bulk according to Annex II
of MARPOL 73/78 and the IBC code14.7 Unknown
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation for the substance or mixture:
U.S. Federal Regulations: As follows -
CERCLA - Sara Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Flammable (gases, aerosols, liquids, or solids), Carcinogenicity, Reproductive toxicity, Skin Corrosion or Irritation, Respiratory
or Skin Sensitization, Serious eye damage or eye irritation, Specific target organ toxicity (single or repeated exposure)
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No.%
TOLUENE 108-88-3 4.48
META-XYLENE 108-38-3 1.43
ETHYL BENZENE 100-41-4 0.59
Toxic Substances Control Act:
All components of this product are either listed on the TSCA Inventory or are exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
No TSCA 12(b) components exist in this product.
U.S. State Regulations: As follows -
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product.
Chemical Name CAS-No.
Page 10 / 11
Date Printed: 05/11/2023 Product: 0988A1NL
1,2-BENZENEDICARBOXIOLIC ACID, DI-C9-11-
BRANCHED AND LINEAR ALKYL ESTERS 68515-43-5
Pennsylvania Right-To-Know
The following non-hazardous ingredients are present in the product at greater than 3%.
Chemical Name CAS-No.
1,2-BENZENEDICARBOXIOLIC ACID, DI-C9-11-BRANCHED AND LINEAR ALKYL ESTERS 68515-43-5
IRON OXIDE 1309-37-1
YELLOW IRON OXIDE 51274-00-1
CALIFORNIA PROPOSITION 65
WARNING: Cancer and Reproductive Harm -- www.P65Warnings.ca.gov
International Regulations: As follows -
* Canadian DSL:
All chemical ingredients included on inventory (DSL)
15.2 Chemical Safety Assessment:
No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.
16. Other Information
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.H350 May cause cancer.
H351 Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H370 Causes damage to organs.
H372 Causes damage to organs through prolonged or repeated exposure.H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
Reasons for revision
No Information
The information contained herein is, to the best of our knowledge and belief accurate. However,
since the conditions of handling and use are beyond our control, we make no guarantee of results,
and assume no liability for damages incurred by use of this material. It is the responsibility of
the user to comply with all applicable federal, state, and local laws and regulations.
Page 11 / 11
08/09/2023Revision:
08/10/2023Printed:
Page: 1 of 8
Klean Strip Paint Thinner
SAFETY DATA SHEET
11/22/2022Supersedes Revision:
Product Name:
Company Name:
Emergency Contact:(800)451-8346
Information:(800)398-3892
Intended Use:
Web site address:
Product Code:
1. PRODUCT AND COMPANY IDENTIFICATION
Klean Strip Paint Thinner
Paint, stain, and varnish thinning.
CKPT94402, EKPT94401, GKPT94002, GKPT94002P, GKPT94400, QKPT94003,
QKPT94203, QKPT943
2105 Channel Avenue
Memphis, TN 38113
3E 24 Hour Emergency Contact
W.M. Barr Customer Service
www.wmbarr.com
W. M. Barr
2. HAZARDS IDENTIFICATION
Flammable Liquids, Category 3
Acute Toxicity: Inhalation, Category 4
Skin Corrosion/Irritation, Category 2
Serious Eye Damage/Eye Irritation, Category 2B
Germ Cell Mutagenicity, Category 1B
Toxic To Reproduction, Category 2
Specific Target Organ Toxicity (single exposure), Category 3
Specific Target Organ Toxicity (repeated exposure), Category 2
Aspiration Toxicity, Category 1
GHS Precautionary Phrases:
GHS Hazard Phrases:
DangerGHS Signal Word:
P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P210 - Keep away from heat, hot surfaces, sparks, open flams and other ignition source.
No smoking.
P233 - Keep container tightly closed.
P240 - Ground/bond container and receiving equipment.
P241 - Use explosion-proof electrical/ventilating/lighting/.../equipment. ... other specified
by the manufacturer/supplier or the competent authority.
P242 - Use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P260 - Do not breathe dust/fume/gas/mist/vapors/spray.
P264 - Wash hands thoroughly after handling.
P271 - Use only outdoors or in a well-ventilated area.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
H226 - Flammable liquid and vapor.
H304 - May be fatal if swallowed and enters airways.
H315 - Causes skin irritation.
H332 - Harmful if inhaled.
H336 - May cause drowsiness or dizziness.
H340 - May cause genetic defects .
H361 - Suspected of damaging fertility or the unborn child .
H373 - May cause damage to through prolonged or repeated exposure.
Licensed to W.M. Barr and Company: MIRS SDS, (c) A V Systems, Inc.GHS format
08/09/2023Revision:
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Klean Strip Paint Thinner
SAFETY DATA SHEET
11/22/2022Supersedes Revision:
GHS Response Phrases:
GHS Storage and Disposal
Phrases:
P281 - Use personal protective equipment as required.
P235 - Keep cool.
P301+310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+352 - IF ON SKIN: Wash with plenty of soap and water.
P303+361+353 - IF ON SKIN (or hair): Remove/take off immediately all contaminated
clothing. Rinse skin with water/shower.
P304+340 - IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P305+351+338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+313 - IF exposed or concerned: Get medical attention/advice.
P312 - Call a POISON CENTER or doctor/physician if you feel unwell.
P314 - Get medical attention/advice if you feel unwell.
P321 - Specific treatment see ... on this label.
P331 - Do NOT induce vomiting.
P332+313 - If skin irritation occurs, get medical advice/attention.
P337+313 - If eye irritation persists, get medical advice/attention.
P362 - Take off contaminated clothing and wash before re-use.
P370 - In case of fire:
P403 - Store in well-ventilated place.
P405 - Store locked up.
P501 - Dispose of contents/container according to local, state and federal regulations.
This material is classified as hazardous under OSHA regulations.OSHA Regulatory Status:
Medical Conditions Generally
Aggravated By Exposure:
Potential Health Effects
(Acute and Chronic):
Diseases of the skin, eyes, liver, kidneys central nervous system and respiratory system.
Inhalation Acute Exposure Effects:
May cause dizziness, headache, watering of eyes, eye irrtation, weakness, nausea,
muscle twitches and depression of central nervous system. Severe over exposure may
cause convulsions, unconsiousness and death. Intentional misuse of this product by
deliberately concentrating and inhaling can be harmful or fatal. Inhalation of
decomposition products may cause severe injury or death.
Skin Contact Acute Exposure Effects:
May cause skin irritation. Decomposition may produce carbon monoxide and carbon
dioxide. May cause numbness in fingers and arms, drying of skin, and dermatitis. May
cause increased severity of symptoms listed under inhalation.
Eye Contact Acute Exposure Effects:
This material is an eye irritant. May cause irritation, burns, conjunctivitis of eyes and
corneal ulcerations of the eye. Vapors may irritate eyes. May cause jaundice, bone
marrow damage, liver damage, anemia and skin irritation.
Ingestion Acute Exposure Effects:
Harmful or fatal if swallowed. May cause nausea; vomiting; weakness; muscle twitches;
gastrointestinal irritation; diarrhea; unconsciousness; convulsions; and death.
Chronic Exposure Effects:
Reports have associated repeated and prolonged overexposure to solvents with
neurological and other physiological damage. Prolonged or repeated contact may cause
dermatitis. May cause jaundice, bone marrow damage, liver damage anemia and skin
irritation.
Licensed to W.M. Barr and Company: MIRS SDS, (c) A V Systems, Inc.GHS format
08/09/2023Revision:
08/10/2023Printed:
Page: 3 of 8
Klean Strip Paint Thinner
SAFETY DATA SHEET
11/22/2022Supersedes Revision:
CAS # Hazardous Components (Chemical Name)
3. COMPOSITION/INFORMATION ON INGREDIENTS
Concentration
Stoddard solvent {Mineral spirits; Aliphatic
Petroleum Distillates; White spirits}
8052-41-3 80.0 -100.0 %
Benzene, Trimethyl- 25551-13-7 3.0 -7.0 %
Additional Chemical
Information
Ingredients vary due to multiple blends and/or raw material suppliers.
4. FIRST AID MEASURES
Emergency and First Aid
Procedures:
Note to Physician:
Signs and Symptoms Of
Exposure:
Inhalation:
If user experiences breathing difficulty, move to air free of vapors. Administer oxygen if
breathing is difficult. Skin Contact Acute Exposure Effects:
Skin Contact:
Wash with soap and large quantities of water for at least 15 minutes. Seek medical
attention if irritation from contact persists.
Eye Contact:
Flush with large quantities of water for at least 15 minutes and seek immediate medical
attention.
Ingestion:
Do NOT induce vomiting. Call your poison control center, hospital emergency room, or
physician immediately for instructions.
If spontaneous vomiting is about to occur, place victim's head below knees. If victim is
drowsy or unconscious, place on the left side with head down. Never give anything by
mouth to an unconscious person. Get medical attention immediately.
Call your local poison control center for further information.
Inhalation: Inhalation overexposure can produce toxic effects. Monitor for respiratory
distress. If cough or difficulty in breathing develops, evaluate for upper respiratory tract
inflammation, bronchitis, and pneumonitis. Administer supplemental oxygen with
assisted ventilation as required.
Ingestion: If ingested, this material presents a significant aspiration and chemical
pneumonitis hazard. Induction of emesis is not recommended. Consider activated
charcoal and/or gastric lavage. If patient is obtunded, protect the airway by cuffed
endotracheal intubation or by placement of the body in a Trendelenburg and left lateral
decubitus position.
ROUTE OF ENTRY: Inhalation, Skin/Dermal, Eye/Ocular, Ingestion/Oral.
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5. FIRE FIGHTING MEASURES
Flash Pt:
Fire Fighting Instructions:
Flammable Properties and
Hazards:
Autoignition Pt:
Explosive Limits:
Flammability Classification:
Suitable Extinguishing Media:
Hazardous Combustion
Products:
> 100.00 F
Self-contained respiratory protection should be provided for fire fighters fighting fires in
buildings or confined areas. Storage containers exposed to fire should be kept cool with
water spray to prevent pressure build-up. Stay away from heads of containers that have
been exposed to intense heat or flame.
Combustible. Liquid.
LEL: 0.5 UEL: 6
NFPA Class II
Use carbon dioxide, dry powder, or foam.
Carbon dioxide, Carbon monoxide, smoke, fumes and/or unburned hydrocarbons.
6. ACCIDENTAL RELEASE MEASURES
Steps To Be Taken In Case
Material Is Released Or
Spilled:
Methods for cleaning up.
Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Stay
upwind, out of low areas, and ventilate closed spaces before entering. ELIMINATE all
ignition sources (no smoking, flares, sparks or flames in immediate area).
Spills/Leaks:
Take up with sand or other non-combustible absorbent material and place into
containers for later disposal.
Dike to collect large liquid spills.
Dike far ahead of spill for later disposal.
WASTE DISPOSAL
Dispose in accordance with appliable local, state and federal regulations.
A single exposure, when used as directed, is not likely to result in adverse skin effects.
7. HANDLING AND STORAGE
Precautions To Be Taken in
Handling:
Precautions To Be Taken in
Read carefully all cautions and directions on product label before use. Since empty
container retains residue, follow all label warnings even after container is empty.
Dispose of empty container according to all regulations. Do not reuse this container.
Read carefully all cautions and directions on product label before use. Since empty
container retains residue, follow all label warnings even after container is empty.
Dispose of empty container according to all regulations. Do not reuse this container.
according to local, state and federal regulations. Do not reuse this container.
A static electrical charge can accumulate when this material is flowing through pipes,
nozzles or filters, and when it is agitated. A static spark discharge can ignite
accumulated vapors particularly during dry weather conditions. Always use proper
bonding and grounding procedures.
Keep container tightly closed when not in use. Store in a cool, dry place. Do not store
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Storing:near flames or at elevated temperatures.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Recommended Exposure LimitsCAS # Chemical Name Jurisdiction Notations
ACGIH TLV8052-41-3 Stoddard solvent
{Mineral spirits; Aliphatic Petroleum
Distillates; White spirits}
TLV: 100 ppm
OSHA PELs PEL: 500 ppm
ACGIH TLV25551-13-7 Benzene, Trimethyl-TLV: 25 ppm
Respiratory Equipment
(Specify Type):
Eye Protection:
Protective Gloves:
Other Protective Clothing:
Engineering Controls
(Ventilation etc.):
Work/Hygienic/Maintenance
Practices:
For OSHA controlled work place and other regular users. Use only with adequate
ventilation under engineered air control systems designed to prevent exceeding
appropriate TLV. For OSHA controlled workplace and other regular users - Use only
with adequate ventilation under engineered air control systems designed to prevent
exceeding appropriate TLV. For occasional use where engineered air control is not
feasible, use properly maintained and properly fitted NIOSH approved respirator for
organic solvent vapors. A dusk mask does not provide protection against vapors. A dust
mask does not provide protection against vapors.
Safety glasses, chemical goggles, or face shields are recommended to safeguard
against potential eye contact, irritation, or injury. Contact lenses should not be worn
while working with chemicals.
Various application methods can dictate use of additional protective safety equipment,
such as impermeable aprons, etc., to minimize exposure. Before reuse, thoroughly clean
any clothing or protective equipment that has been contaminated by prior use. Discard
any clothing or other protective equipment that cannot be decontaminated, such as
gloves or shoes.
Use only with adequate ventilation to prevent build-up of vapors. Open all windows and
doors. use only with a cross ventilation of moving fresh air across the work area. If
strong odor is noticed or you experience slight dizziness, headache, nausea, or
eye-watering - STOP - ventilation is inadequate. Leave area immediately.
A source of clean water should be available in the work area for flushing eyes and skin.
Do not eat, drink, or smoke in the work area.
Wash hands thoroughly after use and before eating, drinking, or smoking.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical States:[ ] Gas [ X ] Liquid [ ] Solid
Appearance and Odor:Water white / Free and clear. Odor threshold not determined.
pH:N.D.
Melting Point:N.A.
Boiling Point:318.00 F - 385.00 F
Flash Pt:> 100.00 F
Evaporation Rate:N.D.
Flammability (solid, gas):
Explosive Limits:LEL: 0.5 UEL: 6
Vapor Pressure (vs. Air or
mm Hg):
0.3 MM HG at 68.0 F
ND MM HG at 50.0 C
Vapor Density (vs. Air = 1):5 Air = 1
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Specific Gravity (Water =
1):
0.78
Solubility in Water:Slight
Solubility Notes:Very slightly soluble in cold water.
Saturated Vapor
Concentration:
N.D.
Octanol/Water Partition
Coefficient:
ND
Percent Volatile:100.0 % by weight.
VOC / Volume:778.0000 G/L
Autoignition Pt:
Decomposition
Temperature:
N.D.
Viscosity:N.D.
a_fld_hdr[9]:ND = Not Determined.
ND = Not Determined.
Information with regard to
primary physical hazard:
10. STABILITY AND REACTIVITY
Conditions To Avoid -
Instability:
Stability:
Incompatibility - Materials To
Avoid:
Hazardous Decomposition or
Byproducts:
Possibility of Hazardous
Reactions:
Conditions To Avoid -
Hazardous Reactions:
Unstable [ ] Stable [ X ]
Incompatible with strong acids, alkaliles and oxidzers such as liquid chlorine and oxygen.
Decomposition may produce carbon monoxide and carbon dioxide.
Will occur [ ] Will not occur [ X ]
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CAS # Hazardous Components (Chemical Name) NTP
11. TOXICOLOGICAL INFORMATION
Toxicological Information:
IARC ACGIH OSHA
This product has not been tested as a whole. Information below will be for individual
ingredients. Refer to section 2 for acute and chronic health effects.
CAS# 25551-13-7:
Standard Draize Test, Skin, Species: Rabbit, 500.0 MG, 24 H, Moderate.
Result:
Kidney, Ureter, Bladder: Changes in liver weight.
Endocrine: Changes in thymus weight.
Immunological Including Allergic: Decreased immune response.
- "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," , Institut Pro Vychovu
Vedoucicn P, Marhold, J.V., Institut Pro Vychovu Vedoucicn, Pracovniku Chemickeho,
Prumyclu Praha Czechoslovakia, Vol/p/yr: -,24, 1972
Standard Draize Test, Eyes, Species: Rabbit, 500.0 MG, 24 H, Mild.
Result:
Kidney, Ureter, Bladder: Changes in liver weight.
Kidney, Ureter, Bladder: Changes in bladder weight.
Nutritional and Gross Metabolic:Weight loss or decreased weight gain.
- "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," , Institut Pro Vychovu
Vedoucicn P, Marhold, J.V., Institut Pro Vychovu Vedoucicn, Pracovniku Chemickeho,
Prumyclu Praha Czechoslovakia, Vol/p/yr: -,24, 1972
Stoddard solvent {Mineral spirits; Aliphatic Petroleum
Distillates; White spirits}
8052-41-3
Benzene, Trimethyl- 25551-13-7
12. ECOLOGICAL INFORMATION
Waste Disposal Method:
13. DISPOSAL CONSIDERATIONS
Dispose in accordance with applicable local, state, and federal regulations.
14. TRANSPORT INFORMATION
Flammable liquids, n.o.s. (Stoddard solvent, Benzene, Trimethyl-)DOT Proper Shipping Name:
3 FLAMMABLE LIQUIDDOT Hazard Class:
UN1993UN/NA Number:IIIPacking Group:
LAND TRANSPORT (US DOT):
Additional Transport
Information:
The shipper / supplier may be able to apply one of the following exceptions if allowed
under 49 CFR Regulations: Combustible Liquid, Consumer Commodity, Limited
Quantity, Viscous Liquid, Does Not Sustain Combustion, or others, as allowed under 49
CFR Hazmat Regulations. Please consult 49 CFR Subchapter C to ensure that
subsequent shipments comply with these exceptions. Please consult 49CFR Subchapter
C to ensure that subsequent shipments comply with these exceptions.
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CAS # Hazardous Components (Chemical Name)
15. REGULATORY INFORMATION
S. 302 (EHS) S. 304 RQ S. 313 (TRI)
EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists
Stoddard solvent {Mineral spirits; Aliphatic
Petroleum Distillates; White spirits}
No No No 8052-41-3
Benzene, Trimethyl- No No No 25551-13-7
CAS # Hazardous Components (Chemical Name) Other US EPA or State Lists
Stoddard solvent {Mineral spirits; Aliphatic
Petroleum Distillates; White spirits}
TSCA: Inventory 8052-41-3
Benzene, Trimethyl- TSCA: Inventory 25551-13-7
Regulatory Information:This product is regulated by the United States Consumer Product Safety Commission
and is subject to certain labeling requirements under the Federal Hazardous Substances
Act. These requirements differ from the classification criteria and hazard information
required for safety data sheets (SDS). The product label also includes other important
information, including directions for use, and should always be read in its entirety prior to
using the product.
16. OTHER INFORMATION
Additional Information About
This Product:
Revision Date:
Preparer Name:
Previous revision:08/09/2023 11/22/2022
The information contained herein is presented in good faith and believed to be accurate
as of the effective date shown above. This information is furnished without warranty of
any kind. Employers should use this information only as a supplement to other
information gathered by them and must make independent determination of suitability
and completeness of information from all sources to assure proper use of these
materials and the safety and health of employees. Any use of this data and information
must be determined by the user to be in accordance with applicable federal, state and
local laws and regulations.
Company Policy or
Disclaimer:
W.M. Barr and Company, Inc. (901)775-0100
Licensed to W.M. Barr and Company: MIRS SDS, (c) A V Systems, Inc.GHS format