HomeMy WebLinkAboutDAQ-2024-0120341
DAQC-1231-24
Site ID 16121 (B4)
MEMORANDUM
TO: STACK TEST FILE – CRUSOE ENERGY SYSTEMS – Duchesne Data Center
Power Station
THROUGH: Harold Burge, Major Source Compliance Section Manager
FROM: Robert Sirrine, Environmental Scientist
DATE: December 12, 2024
SUBJECT: Location: 1 mile Northeast of Upalco, Duchesne County, UT
Contact: Ken Parker: 720-495-3656, Pinyon ES-Kaitlin Meszaros: 631-245-0308
Tester: Great Plains Analytical Services (GAS), Macie McClellan: 580-225-0403
Source: Engines 1251, 1254, 1283, 1318, 1362
FRS Site ID#: UT0000004901300215
Permit #: AO DAQE-AN161210003-24, dated September 18, 2024
Action Code: 3A
Subject: Review of stack test report received November 5, 2024
On November 5, 2024, the DAQ received stack test reports for emissions testing of the Crusoe Energy
Systems – Duchesne Data Center Power Plant’s, Waukesha 2,500 hp Generator Engine Units 1251, 1254,
1283, 1318, and 1362, located 1 mile Northeast of Upalco, Duchesne County, UT. Testing was performed
October 7-11, 2024, to determine compliance with AO Condition II.B.2.a and NSPS 40 CFR 60, Subpart
JJJJ for NOx, CO, and VOC emissions. The DAQ calculated results are:
Source Test Date RM/Pollutant DAQ Result Tester Result Limit
GE 1251 10/08/24 */NOX 0.14 lb/hr 0.14 lb/hr 0.83 lb/hr
0.03 g/BHP-Hr 0.03 g/BHP-Hr 0.15 g/BHP-Hr
*/CO 0.31 lb/hr 0.31 lb/hr 1.65 lb/hr
0.07 g/BHP-Hr 0.07 g/BHP-Hr 0.30 g/BHP-Hr
*/VOC 0.02 lb/hr 0.02 lb/hr 0.17 lb/hr
0.00 g/BHP-Hr 0.00 g/BHP-Hr 0.03 g/BHP-Hr
GE 1254 10/10/24 */NOX 0.25 lb/hr 0.25 lb/hr 0.83 lb/hr
0.05 g/BHP-Hr 0.05 g/BHP-Hr 0.15 g/BHP-Hr
*/CO 0.18 lb/hr 0.19 lb/hr 1.65 lb/hr
0.04 g/BHP-Hr 0.04 g/BHP-Hr 0.30 g/BHP-Hr
*/VOC 0.06 lb/hr 0.06 lb/hr 0.17 lb/hr
0.01 g/BHP-Hr 0.01 g/BHP-Hr 0.03 g/BHP-Hr
* - / $ - - $ )
2
GE 1283 10/07/24 */NOX 0.025 lb/hr 0.025 lb/hr 0.83 lb/hr
0.005 g/BHP-Hr 0.005 g/BHP-Hr 0.15 g/BHP-Hr
*/CO 0.745 lb/hr 0.745 lb/hr 1.65 lb/hr
0.15 g/BHP-Hr 0.15 g/BHP-Hr 0.30 g/BHP-Hr
*/VOC 0.01 lb/hr 0.01 lb/hr 0.17 lb/hr
0.00 g/BHP-Hr 0.00 g/BHP-Hr 0.03 g/BHP-Hr
GE 1318 10/09/24 */NOX 0.10 lb/hr 0.10 lb/hr 0.83 lb/hr
0.02 g/BHP-Hr 0.02 g/BHP-Hr 0.15 g/BHP-Hr
*/CO 0.45 lb/hr 0.45 lb/hr 1.65 lb/hr
0.10 g/BHP-Hr 0.10 g/BHP-Hr 0.30 g/BHP-Hr
*/VOC 0.06 lb/hr 0.06 lb/hr 0.17 lb/hr
0.01 g/BHP-Hr 0.01 g/BHP-Hr 0.03 g/BHP-Hr
GE 1362 10/11/24 */NOX 0.124 lb/hr 0.124 lb/hr 0.83 lb/hr
0.03 g/BHP-Hr 0.03 g/BHP-Hr 0.15 g/BHP-Hr
*/CO 0.40 lb/hr 0.40 lb/hr 1.65 lb/hr
0.087 g/BHP-Hr 0.085 g/BHP-Hr 0.3 g/BHP-Hr
*/VOC 0.046 lb/hr 0.046 lb/hr 0.17 lb/hr
0.01 g/BHP-Hr 0.01 g/BHP-Hr 0.03 g/BHP-Hr
*ASTM D6348-03
DEVIATIONS: No deviations were noted. Testing for NOx is required within
one year of the previous test, but testing VOC and CO emissions
is required every three years. All engines were tested last year
for NOx, CO, and VOC emissions.
CONCLUSION: The stack test reports for the listed engine appear to be
acceptable.
RECOMMENDATION: Generator Engines 1251, 1254, 1283, 1318, and 1362 should be
considered to have been in compliance with the NOx, CO, and
VOC applicable emissions limits at the time of testing.
HPV: No.
ATTACHMENT: Crusoe Energy Systems emissions testing reports received
November 5, 2024.
DAQ generated Excel spreadsheets.
40 CFR Part 60 Subpart JJJJ
Performance Test Report
Test Type: Annual
Test Date: 1O|U2O24
Source:
Waukesha 9394 GSI
Rich Burn (4 Cycle)
Unit Number: 1251
Serial Number: 1457259
Engine Hours:30750
Location:
Duchesne Data Center Power Station
Duchesne County, Utah
DEPANTMENT OF
ENVIIIONMENTAL OUATITY
Nov - 5 2024
D]VISION OF AIB QUAL]TY
Test Started: 08:53 AM Test Completed: 12:56 PM
#As.
Prepared on Behalf of:
Crusoe Energy Systems, lnc.
303 W. 3rd St (580) 225-0403 Elk City , OK73644
!ndex
1.0 Key Personnel.... ............. 3
2.0 Sampling System..... ....... 3
3.0 Methods Used........ .. ......................... 3
4.0 Test Summaries.. ....."... . 5
5.0 Run Summaries.. . 6
6.0 Volumetric Flow Rate Data.... ............. 7
7.0 Calculations............. .......8
8.0 Orygen Calibration... ...... 9
9.0 Engine Parameter Data Sheet.. . ....... 10
10.0 QA/QC Results... . .. . .. .11
11.0 D6348 Annexes...... 12
12.0 Signature Page........ ....... 18
13.0 Appendices.............. ..... 19
14.0 Bottle Certs........... .......... 20
15.0 Tri Probe Certification via GD-031 ......25
'16.0 GAS ALT 141_FT|R EPA........ ............26
17.0 Tester Qualifications (resume)... ......... 28
18 0 Raw Data
i";i.=
2e
Table 5.1 (Run Summaries)............. ........... 6
Table 6.1 (Volumetric Flow Rate Data)........... ................ 7
Table 6.2 (Stack Gas Measurements)....... ......................7
Table 8.1 (Oxygen Calibration).. ................. I
Annex Table 1.2.1 (Certified Calibration Bottle Concentrations)......... 12
Annex Table 1.2.2 (Measurement System Capabilities)..................... 12
Annex Table 1 .3. 1 (Test Specific Target Analytes)............................. 1 3
Annex Table 4.1 (Measure System Capabilities) ........... 15
Figures
Figure 6.1 (Location of Traverse Points per Method 1)..
Annex Figure 1.4.1 (Sampling Train)....
Annex Figure 1.4.2 (Sampling Points)..
Annex Figure 1.4.3 (Sampling Port Locations)...
Appendices
Certified Calibration Bottle Certificates...........
Tri Probe Certification via GD-031
GAS ALT 141-FTIR EPA.........
Tester Qualifications (resume)...
7
13
14
14
20
25
27
28
29Raw Data.
1.0 Key Personnel
GAS
Crusoe Energy Systems, lnc.
Lewis Shirley
Alex Nelson
2.0 Sampling System
The sampling system used consisted of a Stainless steel probe, heated Teflon line, gas conditioning
system, and a Gasmet model DX4000 FTIR analyzer. The gas conditioning system used was a Gasmet
Personal Sampling System with a Zirconium Oxide oxygen sensor.
3.0 Methods Used
ASTM D6348.03
This extractive FTIR based field test method is used to quantify gas phase concentrations of multiple target
analytes (CO, NOX, CH2O, & VOC's) from stationary source effluent. Because an FTIR analyzer is
potentially capable of analyzing hundreds of compounds, this test method is not analyte or source specific.
The analytes, detection levels, and data quality objectives are expected to change for any particular testing
situation. lt is the responsibility of the tester to define the target analytes, the associated detection limits for
those analytes in the particular source effluent, and the required data quality objectives for each specific
test program. Provisions are included in this test method that require the tester to determine critical
sampling system and instrument operational parameters, and for the conduct of QA/QC procedures.
Testers following this test method will generate data that will allow an independent observer to verify the
valid collection, identification, and quantification of the subject target analytes.
EPA Method 1 & 1A
The purpose of the method is to provide guidance for the selection of sampling ports and traverse points at
which sampling for air pollutants will be performed pursuant to regulations set forth in this part.
EPA Meth od 2 & 2C
This method is applicable for the determination of the average velocity and the volumetric flow rate of a gas
stream. The average gas velocity in a stack is determined from the gas density and from measurement of
the average velocity head with a standard pitot tube. Velocity readings are taken from each stack at 16
separate traverse points (Table 6.1) and used to determine the engines mass emissions rate, calculated
utilizing the formulas seen in section 7.0 of this report.
EPA Method 3A
This is a procedure for measuring oxygen (O2) and carbon dioxide (CO2) in stationary source emissions
using a continuous instrumental analyzer. Quality assurance and quality control requirements are included
to assure that the tester collects data of known quality. Documentation to these specific requirements for
equipment, supplies, sample collection and analysis, calculations, and data analysis will be included.
GAS
4.0 Test Summary
Unit 1251 with a serial number of 1457259 which is a Waukesha 9394 GSI engine located at Duchesne
Data Center Power Station and operated by Crusoe Energy Systems, lnc. was tested for emissions of.
Carbon Monoxide, Oxides of Nitrogen, and Volatile Organic Compounds. The test was conducted on
101812024 by Lewis Shirley with Great Plains Analytical Services, lnc. All quality assurance and quality
control tests were within acceptable tolerances.
The engine is a natural gas fired Rich Burn (4 Cycle) engine rated at 2500 brake horse power (BHP) at
1200 RPM. The engine was operating at 2185 BHP and 1200 RPM which is 87,38% of maximum engine
load during the test. The test HP calculation can be found on page 8. The engine was running at the
maximum load available at the test site.
This test will satisfy the testing requirements for 40 CFR Part 60 Subpart JJJJ.
Site Verification Photos
GAS
Duchesne Data Center Power Station
GAS
5.0 Run Summaries
Table 5.1 Run Summaries
GAS
6.0 Volumetric Flow Rate Data 7
Table 6.1. Data used for volumetric f Iow rate (Method 2)
Pitot Tube Coetfacaent Cp(std)= 99
Stack diameter = 20 lncnes or:167 reet, or:214 Square Feel
t12(.J Yod 18.35 18 37 18 22 18 31
c{0-)2 "/od 9.62 962 9.67 954
Q2 "/od 0.24 0.22 0.35 0.27
CO oomd 30.97 28.75 21.52 27.08
Molecular Weiqht Stack Gas dry basis (Md o/o mole 29 55 29 s5 29.56 29.55
Molecular Werqht Stack Gas wet basrs (Ms)q/q mole 2t.43 27 43 27 46 27.44
Stack Statrc Pressure (Pq "H20 0.18 0.41 u.'29 U3U
Stack Static Pressure (Pq "Hq 0.01 0.03 0.02 0.02
Atmosoheric Pressure at Location (Pbar MBAR 829.00 828.82 828.00 828 61
Atmosohenc Pressure at Locatron (Pbar "Hq 24.49 24 48 24 46 24.47
Absolute stack Pressure (Ps "Hq 24.54 24.51 24.44 24 50
stack Iemperature Deq L;490.66 501.74 496 81 496 4U
Stack Temperature Deq F 915 19 935.1 3 9:26.25 9:z5.52
Stack Temperature Deq R 1374.86 1394.80 1385.92 1 385.1 I
Stack Gas Velocitv fUsec 51.36 78.24 65.80 65.99
Stack Flow Rate Q cfs 112 05 170.69 143.56 143.97
Stack Gas Wet Volmetric Flow Rate sct/hr 126445 02 't 90555 0C 161078.76 161747.00
Stack Gas Dry Volumetric Flow Flate sct/hr 103565 79 1 55552.98 13't726.'t8 132123.84
mrssrons liamolrno HornIS - 3 00rnl lonq lrne sampllnq proD€lnches
First Samolino Poinl aken @ 16.7% of Stacl Diameter 3.34
Second Samplinq Point Taken @ 50% of Stack Diameter 10
tntro Samoilno Hotnl aKen (g ui 5-lo OI SIEICK Ulameler 16.66
samole afier Back Puroe:u.25
Within 5% of Last Apstd readinq:Yes
measured with a standard tube use for Volumetric Flow Rate
Figure 6.1
16 Traverse Points Were Used
Table 6.2. Stack gas pressure read
Aostd = Velocitv head measured bv the' standard pitot tube, (in.) H2O'
Stack Diameter (inches)20 00
lnches upstream from dtsturbance 4.UU
lnches downstream trom drsturbance 30.oo
Pitot readings are taken for Method 2 calculations using measuring points outlined in Method 1
'The exhaust stack did not presont cyclonic flow conditions at the sampling location due to the
absence of cyclones, inertial demisters, venturi scrubbers, or tangential inleB.
-- _. '_- ;
A*gs
zil I
d.ro --t' l I I I r ! !I
ri'
67 ao 6q.a9 5q"96 8h
GAS
32
I
7.0 Calculations
Method 2: Determination of Stack Gas Velocitv and Volumetric Flow Rate
*Note- Use of this method neqates the need for anv fuel related numbers for emissions calculations
Ap(avg) = Velocity head of stack gas, mm H2O (in H2O)
3600 = Conversion Factor, sec/hr.
A = Cross-sectional area of stack, n2 (ft2)
Bws = Water vapor in the gas stream (from ASTM D6348)
Cp(std) = Standard pitot tube coefficient; use 0 99
Kp = Velocity equation constant.
Md = Molecular weight of stack gas, dry basis, g/g-mole (lb./lb.-mole).
Ms = Molecular weight of stack gas, wet basis, g/g-mole (lb./lb. -mole).
Ps = Absolute stack pressure (Pbar+ Pg), mm Hg (in Hg)
Pstd = Standard absolute pressure, 760 mm Hg (29 92 in. Hg)
Qsd = Dry volumetric stack gas flow rate corrected to
standard conditions, dscm/hr. (dscf/hr.).
Ts(abs) = Absolute stack temperature, oK ('Fl). = 460 + Ts for
English units.
Tstd = Standard absolute temperature, 293"K (528 'R).
Vs = Average stack gas velocity, m/sec (ft./sec).
Md = .44(o/oCO2l+.32(kO2)+.28(%N2+%CO)Md = .44(.096)+.32(.003)+.28(.898+.003) = 29.55 LB/LB-MOLE
Ms = Md(1 -Bws)+18.0(Bws)Ms = 29 ss(1 -.183s3)+.18.0(.1 8353) = 27.431 LBiLB-MOLE
vs = 85.49'.99'l r a'y'1r sza.esTs/(24.s'27 .4sr )) = 51 .36 FT/sEcVs = Kp'Cp(srd)'y'apavg-y'1Ts1abs)/(Ps'Ms))
Qsd = 3600(1 -Bws)Vs'A((Tstd'Ps)/(Ts(abs)'Pstd))Qsd = 3600(1 - 1 84)51 36'2 1 82((528'24.5\t (1374 8575'29 920 = 1 0356s.79 DSCF/HR
Q = Qsd/35.315 Q = 103565.789/35.315 =2932.629 OSCM/HR
Emission Rates (Examoles use CO Run 1)
453.6= Conversion factor lb. to gram HP= Engines rated Horsepower
A = Cross-sectional area of stack, m2 (ft2). Mfg = ysnulscturer Exhaust flow rate at 100% (ft3/min)
BHP/HR. = Brake work of the engine, horsepower-hour (HP-HR ) 02 = Concentration of oxygen on a dry basis, percent.
BTU/HP-HR. = Brake Specific Fuel Consumption (HHV) ppm= Parts Per Million (CO)
ER = Emission rate of (CO) in g/HP-hr. ppm@15% 02= PPM corrected lo 15o/o 02
F(d )= yslumas of combustion components per unit of heat Qsd = Dry volumetric stack gas flow rate corrected
content, scm/J (scf/million Btu). to standard conditions, dscm/hr. (DSCF/}1R.)
Q = Stack gas volumetric flow rate, in standard cubic meters Run Time = Run Time in Minutes
per hour, dry basis Tpy= Tons per year
LB/HR = Emission rate of (Co) in LB/HR. Vs = Average stack gas velocity, m/sec (ft./sec).
Mol wt.= Mol Weight of CO (28.01)
ppm @ 15o/o 02 = PPM'((20 9-15/002)/(20 9-O2))ppm @ 15% 02 = 37 925t 120.9-1 5)(20.9-.3'l")) = 10 862 PPM @ 15/" 02
g/hp-hr = (PPM'(1 .164'1 0^-3)'Q-(Run Time/60))/BHP/HR (37.925'(1 . 1 64- 1 0^-3)'2932.629.(Run Time/60))/21 84.s6 = 059 G/HP-HR
lb/hr = ER'1/453.6'BHP-HR LB/HR = .059.1/453.6'2184.56 = 285 LB/tlR
li
TPY = 1-9fi19 -4 3t TPY = .285-4.38 = 1 248 TPY
KW.1 34022088 I 1 630' 1 .34022088
ppm wel'(1(1-H2O) = ppm dry 37 93 = 30.965-(1(1- 18))
GAS
98.0 Oxygen Calibration
8.1 Calibration error test; how do I confirm my analyzer calibration is correct? After the tester has assembled, prepared and calibrated the
sampling system and analyzer, they conduct a 3-point analyzer calibration error test before the first run and again after any failed system bias test or
failed drift test. They then introduce the low-, mid-, and high-level calibration gases sequentially in direct calibration mode. Al each calibration gas level
(low. mid, and high) the calibration error must be within I 2.0 percent of lhe calibration span.
8.2 lnitial system bias and system calibration error checks. Before sampling begins, it is determined whether the high- level or mid-level
calibration gas best approximates the emissions and it is used as the upscale gas. The upscale gas is introduced at the probe upstream of all sample-
conditioning components in system calibration mode.
(1) Next, zero gas is introduced as described above. The response must be within 0.5 percent ofthe upscale gas concentration.
(2) Low-level gas reading is observed until it has reached a final, stable value and the results are recorded. The measurement system will be
operated al the normal sampling rate during all system bias checks.
(3) lftheinitial systembiasspecificationisnotmet,correctiveactionistaken. TheapplicablecalibralionerrortestfromSectionS.2.3ofEPA
Method 7E is repeated along with the initial syslem bias check until acceptable results are achieved, afterwhich sampling will begin. The pre-
and post-run system bias must be within t 5.0 percent of the calibration span forthe low-level and upscale calibration gases.
8.3 Post-run system bias check and drift assessment - confirming that each sample collected is valid. Sampling may be performed for multiple
runs before performing the post-run bias or system calibration error check provided this test is passed at the conclusion of the group of runs. A failed
final tesl in this case will invalidate all runs subsequent to the last passed test.
(1) lfthe post-run system bias check is not passed, then the run is invalid. The problem is then diagnosed and fixed, then another calibration
error test and system bias is passed before repeating the run.
(2)Aftereachrun,thelow-level andupscaledriftiscalculated,usingEquation7E4inSeclion125fromEPAMethod7E lfthepost-runlow-
and upscale bras checks are passed, but the low-or upscale drifl exceeds the specification in Section 13.3, the run data are valid, but a 3-point
calibration error tesl and a system bias check must be performed and passed prior to additional testing.
Table 8.'l Oxygen Calibration
Method 7E 3.4 1o the extent practicable, lhe measured emissions should be between
20 to 100 percenl of the selected calibration span. This may not be practicable in some
cases of low concentration measurements or testing for compliance with an emission
limit when emissions are substantially less than the limit.
EPA Method 3A QA Worksheet
Gertifled Gas Concentrelon I Certlfled Ge3 Concentralon I Certlfied Ga! Co
Low-Level (%) I Mid-Leyol (%l I High-Leve
o oo.,
ncontraion
7E 8 5: Note: that you may
risk sampling for multiple
runs before performing the
poslrun bias provided you
pass this test at the
conclusion of the group of
runs
(DIRECT) Analyzer Calibiation Error (5 2%)
Check
Certified
Concentration
Value (70)
Direct
Calibralion
Resporce (o/o)
Absolute
Difference (o/o)
Analyzer
Calibration
Enor (o/o)
Zero Gas o/o 0.00%0.00%0.00%0.00o/o
Mid-Level Gas %
High-Level Gas %
10.620/o
21 .120/o
10.81Yo
21.O70/o
o.190/o
0.05%
0.90%
0.250/o
(SYSTEM) Calibration Bias Checks (s 5%) and Orift Ghecks (s 3%)Upscale Gas 10.620/o
Zero Offset 0.00%
Bias Pre lnitial Value Bias Posl lniial Valueg
Span 21.12
AnalYzer
Calibration
Response (%)
Zero Gas o.oo%
System
Celibrations
Response Pre
eh)
System Bias (ol
of Span) Pre
System
Calibration
Response Post(Yol
System Bias (%
of Span) Post
Drift (o/o of
Span)
0.00% 0.00%0.00%0.00%0 00o/o
Upscale Gas 10.81%10.65%0.740/o 10.53%1.340/o 0.l'to/o
(SYSTEM) Calibration Bias Checks (s 5%) and Drift Checks (s 3%)
Avo. Gas Concentration (Run 1)0.30% Effiuent Gas (Csas) Run 1 0.30%
Avg. Gas Concentration (Run 2)0.27% Emuent Gas (Cgas) Run 2 0.27o/o
Avg, Gas Concentration (Run 3) 0.43Y0 Emuent Gas (Cgas) Run 3 O.43o/o
EPA Method 3A QA Worksheet
Zero Gas 100% Nitrogen
Mid-Level Gas 10.620/o
Hiqh-Level Gas 21 .120/o
Zero Gas o/o
Mid-Level Gas %
High-Level Gas %
System
Calibration
Response Pre
("/"1I."*I
I ro osv" I
System
Calibration
Response Post
("/"1I ..*^ I
J ro sgv" I
10.81o/o
GAS
Company urusoe Enerqy systems, lnc
Facility Duchesne Data oenter Power statton
Date 10tEt2024
site Etevailon (ft)1776 32
unit lD 1251
Make Waukesha
Model 9394 GSt
Serial Number 1457259
Technician Lewls Shtrley
9.0 Engine Parameter Data Sheet
AS
Anal yl t co I Scrr rcr.s. Irr<'
Completed
Run Start Times UU:5i' AM 1O:15 AM 1:29 AM 12:56 PM
EnElne Hours 30747 30748 30749 30750
Enqine Parameter Data
Bun 1 Flun 2 Flun 3 Averaoe
Enqine Speed (RPM)1 199.0 1200.0 1200.0 1't99.7
lntake Manifold Pressure (psi)65.O t5.7 13.4 t1.4
lntake Manilold Temp "F 122.4 124.5 124.2 123.1
Engtne Load {EHP):z1tJ4.6 2184.6 2144.6 2144.6
Ambient Temp "F 63.O 63.0 b/.u b4.3
Humidaty 70 23.O 29.0 24.U 25.3
Dew Point "F 25.O 29.0 29.O 2t.l
AFR Manufacturer/Tvpe Waukesha Waukesha Waukesha Waukesha
AFR Settino (Taroet Riqht Bankl 63.8 64.4 60.8 63.0
AFR Setting (Target Left Bank)65.0 64.5 b].4 b5.o
suction Pressure (psi)1630.0 1674.0 1590.O 1631 .3
DascharEe Pressure (psi)r 630.0 1674.O 1590.0 I b3t .3
catalyst (Yes or No)Yes
Catalvst Manufacturer Miratech Miratech Miratech Miratech
# ot Catalvst Installed 1 1 1
Catalyst lnlet Temp'F lo8o.o 1081 .O 1EO.O 13.t
Catalyst Outlet Temp "F 1 10E.0 1 109.0 108.0 108.3
catalyst Pressure Drop H2O 5.6 5.r 5.6 5.6
10.0 OA/OC Results
esponse tme
Spike Reported
Spike Expected
Value: 252.61
Value: 252.40
Nitrogen monoxide NO
Nitrogen dioxide NO2
NOx
VOC
Oxygen
Average:0.00
Average:0.73
Average:0.73
Average:0.38
Average:0.06
CTS Compound Concentration Avg
Tolerance
Difference between measured and expected
Value: 98.47
2.00%
1.82Y"
Nitrogen monoxide NO
Nitrogen dioxide N02
NOx
voc
Oxygen
Average:30.73
Average: 16.22
Average: 1.35
Average: 17.57
Average: 16.45
Average:0.21
CTS Bottle Concentration
CTS Compound Concentration Avg
Tolerance
Difference between measured and expected
Value: 100.30
Value: 97.93
5.00%
2.37To
System Response Time
Gas, lnc.
12
11.0 D6348 Annexes 1-8
The test quality objectives completed for the emissions test are demonstrated throughout Annexes 1,2,3,
4, 5, 6, 7 & 8 as layed out per ASTM D6348-03. All reference methods, pre{est and post test procedures
were within acceptable limits. Data generated during the pre-test and post-test procedures are
summarized below in order of the distinctive Annex.
Three 60 minute test runs were performed. The final analyte concentrations are the average of each test
run. Data was taken at 60 second intervals. Each 60 second measurement was the average of 600 scans.
Propane is used as the surrogate compound for the Annex 5 Spiking Technique due to Propane being the
VOC that is most commonly found in the combustion process of natural gas. Additionally, the molecular
weight of Propane coincides with with molecular weight of VOC's per the EPA.
Annex Table 1.2.1 Certif ied Calibration Bottle Concentrationg
Bottle Expiration N02 Ethylene SF6 A2 f/ol
cc506322 9t17t2o27 99.95 1U.62-/o
12tO1t2025 100 30
cc405148 4t1512032 21 'l2o/"
Cylinder # ALM-063647 Expiration: 5-03-2032
Propane GO NO SF6
Botfle value 252.40 501 70 23t.5U 10.20
Analvzer Svstem Besponse 252.61 501.56 23tl.U4 10 18
Percent Ditference 0.08%0.03"/o 0.23"/"U.'l 9"/o
Annex Table 1.2.2 Measurement System Capabilities
GAS
Annex Table 1.3.1 Test Specific Target Analytes and Data Quality Objectives
Compounds
lnfrared
Analysis Region(cm-l)
Expected
Concentration
Range
Measuremenr
System
Achievable
Minimum
Detectable
Concentrations
Hequrreq
Measurement
System
Accuracy and
Precision forfest Aoolication
CO 2000-2200 0-1200 oDm O 'l 5257 oom 4 oom
NO 1 875-21 38 0-1000 oom 0.4007 oom 2 oDm
N()2 2too-2950 0-100 ppm u.46VV OOm 2 ppm
VOC
2600-3200
0-100 ppm 1.8520 ppm Tota
VOC's I ppm perVOC910-1 150
2550-2950
CH2O 2550-2850 0-100 oom u. /6/6 oDm 1 oDm
lnterfering
Compounds
- CO is analyzed in a separate analysis region than CO2 and H2O
co2 926-1 150 O-1Oo/"OYo nla
Water Vapor 3200-3401 o-22%U.20"/o nla
'VOCs compiled of Acetaldehyde, Ethylene, Hexane, and Propane.
1.4
02
SENSOR
PROBE
-r1
FLOW
MTR,
VENT
Figure Annex 1.4.1 Sampling Train
The testing instrumentation is housed in an enclosed vehicle which is located approximately 45 feet from the source. A
heated sample line (sixty feet in length) is attached to the inlet of analyzer system and the source effluent discharges
through the FTIR outlet.
0t
l
H
GAS
STACK
GAS
14
u
UJ
IIJ
=govo
o
lnches
Upstream:
4
TRI.PROBE SAMPLE POINT LOCATIONS
AS PERCENTAGE OF STACK DIAMETER
Figure Annex 1.4.2 Sampling Points
lnterior Stack Diameter (inches):
lnches
Downstream:
30
SAMPLE PORT LOCATION DETERMINED
BY DISTAT.ICE FROM DISTURBANCE
Figure Annex 1.4.3 Sample Port Location
Sampling Point Locations
in lnches
lO.l-/o 3.340
sOYo 10.000
U3.l57o 16.660
tu,
u,
=soIsq
ai(D
&
UJFut
=oIsou)
GAS
Target Analyte Results (ppm)
CO u.162t
NO U.4UU/
NO2 0.489S
tthvlene 0.3782
ProDane u.4J5r
Hexane U.ZZ3;
Acetaldenvde 0.815'
Formaldenvde 0.787t
N T;A III :7'I,1 S f y l'-l (rvr;,t",')'f,,, / 'i : 1
,tlNTiAMDCT+I:,- rrt s
L<'t,tt
caltbratron Transler standard Expected Measured Path Lenqth Validated
tthvlene UU.J 96 4t 4.909 PASSCO
est
Annex Table 1.2.2 Measurement System Capabilities
Parameter
Measured Gas concentration(oom'l Path Length EquilrDrauon
Time Dilution Factor 7" Recovery
Path Lenoth Ethvlene 98 473 4 909
Spike Direct
Propane 252 521
SF6 10 160
(io 499.12E
NO 238 180
Mechanical
Response Time Ethylene 97.928 17 seconds
Analyzer
Response
Propane 252 608
10 secondsSF610 181
CO 501 562
NO 238 036
Analyte Spike
Recovery Propane & SF6
8 83%9U.b3"/o
6. /U"/o 101 80%
9 26"/o 101 90%
Svstem zero Nitroqen 18 seconds
Post Spike
System
Propane 255 615
CO 485 299
NO 237 994
SI-6 I U.1 65
GAS
Paramelor G88 Goncentrailon Meaaurecl 7o Difterence speciflcation velldated
Spike Direct
Propane 252.4(JU 252 521 o.o5"/o +l- 2o/"PaSS
SF6 10.200 10.t60 0.39%+l'2/o PASS
CO 501.700 499.1 28 Q.51"/o +l- 2o/o PaSS
NO Z3I.5UU 256. I 6U O.29"/o +h 2"/o PASS
splke Hun 1 vla lhe syStem
Source Output Spike Averaqe Dilution Factor Expected 70 Recovery specifacation
Propane 0.026 22.226 22.31 99.63U"/o 7O-'13O"/"
SF6 0.000 0.897 8.829"/"<1Oo/o
splke Run z vla the syStsm
Source Output Spike Averaqe Dilution Factor Expected 70 Recovery Specificataon
Propane U.U24 22.31t 2't.g6u 101.800%7O-'l3Oo/o
SF6 0 001 0.884 8.701"/"<1Oo/"
SDlke Run 3 vla the Svstem
Source Output Spike Average Dilution Factor Expected o/o Recoverv Specilication
Propane 0.529 24.306 23.E52 I U l .VUU-/o 70-'130/"
st--6 U.UUU u.v4l 9.ZOZ-/o <11)"/o
Noise Equivalent Absorbance (NEA)
BMS High 0 003623
FMS Mid 0.00'1664
FIMS Low 0.055207
s
Line Position
00 - \-'.'/ \,-/ -.r/
2092 2069 2046 2023 1999 1976 1953 1930 1907 1884 1861 1837 1814
Pass
GAS
02
01
00
01
03
02
01
-ul
@ o.ooo/o Pass
The Gasmet GICCOR (Genzel lnterferometer with Cube Corner Betroreflectors) interferometer is specially
designed for maximum optical throughput and maximum signal to noise ratio of 7.72 (cm-1) remaining
stable with any vibration and temperature changes.
is a low resolution spectrometer where the aperture is fixed to a maximum angle
setting and the detector linearity was tested with an alternate approach. A three point linerarity of th-e CTS
gas was performed and validated.
Linea rity
3'1.9923
22.9923
13 9923
4 9923
-4.0077
-13.0077
-22.0077
-31.0077
-40.0077
31 9923
22.9923
1 3 9923
4 9923
-4.0077
-13.0077
-22.0077
-31.0077
-40.0077687 679 672 664 656 648 641 633 625 618 610 602695
.001923824 Pass
The analytical accuracy of the quantification algorithm is satisfied via the results from Annex 5 per Annex
7.6
POST CTS Syrtom Cheok:
u tu trollte uoncenlralton:100 30
u tu uamote uoncenlralton Averaoe:96.71
urnerence oetween measureo ano expecleo:3.71o/"
Tolerance:5.00"/"
Run Dtta valldailon - Automatad v3 Manual Roadllu Yalldfied Gommantr
Hun 1 Potnts 1 & 2 0n UO/NO/Prooane All wrthrn 2070 Passed uemonslrales no rnlenerences oDserveo
Flun 2 Pornts 1 & 2 on CO/NO/Prooane All within 20%Passed uemon$rales no rnlenerences ooserveo
HUn 3 POTnIS r & Z On UU/NU/HrOpane Allwithin 20% Passed Demonstrates no interferences observed.
GAS
12.0 Signature Page
Job/File Name: Crusoe Energy Systems, lnc.; Duchesne Data Center Power Station; 1251;JJJJ
Emissions Specialist
We certify that based on review of test data, knowledge of those individuals directly responsible for
conducting this test, we believe the submitted information to be accurate and complete.
Company: G.A.S. lnc.
Print Name: Lewis Shirley
Title: Emissions Specialist
Date:101812024
Company:
Print Name:
Signature:
Title:
Phone Number:
Date:
Company:
Print Name:
Title:
Signature:
G.A.S. lnc.
Travis Hartley
Director of Stack Testing
'T-4>-
Date: 1Ol8l2O24
PhoneNumber: 580-225-0403
GAS
Appendices
oidlnflo! adod lBoEl( fit.ialnlr llai
r\ :500 fl'u
ItRt( (N[)l :jil0 PP\t
IN\NI :iU il I'P\I
\RJtr)\ \l(N(r\il[ qr]i, Ir\l
\|il]()\ l)k,\ll[ 5 rrxr
ITR(LI \ ttriaxe
:.r'$ lt'\l
.I'i fl'\t
::: r ll'\l
5r,l 1 I'Jr\l
{..ry: ,
-llr.\lsl lr.,(!bk -lrlf\l\lSl lrx.rhk rU:6:11:l(l5tr,i:l':l
.lrr' \lSI IE(fjl.lc -:1)IPI'|\l\l lh.rhlc l$-'hllrll(,5U.llo:{
- Ir n . \lsl tE..rhlc - i tlf iq \lS I trlonlc ltr :q :l,:{
. lr o", \lsl llr.t.$L. - .l :fPrl \15 I Trx.,hlr 1,5 tll llrll
,o'".\lsl lrJ.c.rhk -0il".\l\l Irruhlr rcl^lir.l{
litua$
il fuLqic€ aofiEr\
Grade of Product: EPA PROTOCOL STANDARD
Cuslomer: GREAT PIAINSANAYTICAL SERVICE.
Spike (5 Gas)
.tlrtrr sp(hll! (;rsi
..\rr8r! trSA Lt.CIl:l: S Udx$'{th {\(.
( hr(rgo.lt. dk'lx
,\rrlns r(xrl
CERTIFICATE OF ANALYSIS
Parl Number
Cylinder Number
Laboratory:
PGVP Number
Gas Code:
E05Nr94E15AC014
ALM{63647
124 - Chicago (SAP) - lL
812024
CO.C02,NO.NOX PFN BALN
Retererc No: 54-403018922-1
Cylinder \blume: 147 0
Cyinds Pressurs; 2015
Valv€ Outlet 660
CertifEticn Oate. May 03.202t1
Exdratbn Dsb: llay 03, 2032
Csttlcdbn t8ilcmod lo &cqdrn@ wtth'EPATra6aUlrty Prct@ltq Asey and Cstitkebn ol Oasos Calbraton Sien6flds ([4sy 20121'dMot EPA 6O/R-
12,!31, uslu tlE as$y procadres llsbd. Andyllql ltethodjlogy dce! nol r€quf€ 6r€dDn lq ilaly{El hlerrss@ T}ls cylln&r h€3 a tolal sa]ylcal u@dalrly as
Blsled b6t* flth 6 6de@ b€lol95% Ther€ arc no aglln€d rtrrputo€s whkh ,led tha tr d thrs €lbr8tlon mlrluE Al @rcrlratms ,e on a fiEle{rcle hsrsnl6 otrrsw* rcled The resuis retd€ oriy b the ltsnE lesled lhe repod snall rct be reproo@d ox@pt in tutl wih@t +provar d tre ramralcry Do Nd Us Thts
Cy'rnder mlo 100 Pslg I e 0 7 rcgop3$ds
ANALyTICAL RESt'I.T!;
Ati(AL\"n('AL f Qt:t Pt\t f, :\'t
!,il.r r\ill \t PllrllllJl
('-r slt.\il \s t I lR.\It.\l.l \rr1-u'
InR
\l)u
fTI R
I ltR
rnR
I fir tlriiund ( rllbrrri.,n
\!r 1'l l/r:r
I,k r rS.0 \l f:lr tr):l:
Vr ({ l,:J
Ur\ lr: :tl:J
lh\ rl: :ll:lr.,\idr rsilr ..\t l':010:l:
tr,'kl Ili{}.\t l': l}11:lr ol :0:l
\0r-E P.A A\At-)',I'!cAt. R[st t-Ts
lrhd l).tr.tr rll.ble tipoo llcqu(!t
Mixture contains nominal 1oppm Sullur F{exafluoride as a lraer cmlnnent Aclual tosted value rnduded with rn th6 onginal Cortiflcte ol Analysis
Contacl tl"E Airgas laboratory tl a reprint rs required SF6 @ 10.20 PPM
Signature on Frle
ApproYed tor Release pagc I of 2
CAI-I BR,,TI'IOI S'TA \DARDS
lR\l lrxxi':-r l
lRll Iio{)5.i 1
Ik\t lnw{rl
hLSR\l \fR\l PR\l..rR(,\!tr',rd!.,h{(Frnl\ilr.lir.1.e l,'rlt{A{lSurdl rtrrlr.!r\,\$dn.nDad,{rlEini\.b
(rlv (d(iarfli)l
((:al5n) :JelPr\t\lIRl(trrttiiffi
lll0li:qp -rir,5m\l\lrRl( {)\ll)l \lIR(x,l\
((51[11, lnelll'\l\lIR(x,l\l)lrt\jt)l \llRrrrl\
I)olirrn, tj (,t lr'\l \lrR(x,l \ I)l()\ll)l \lR
l,i 0:r9'\ :1 1 i Pt\l fRol\\l \lR
r(15ler: r!tqfl\l(aRl(r\\l)\ouDl,\llRr,(,lN
r (fiiol_ "t\q,. ( \Rllr\l)l(,\ll)l \tlRr{,1\
t Dftmldr frE hr(
;lfls tf,}\!r:H:o::{
,\l i lll(
,\ll\ !,1(txn'1jlU
-lrJ'.. hn lr.:llrl
.!t. (\rtq.ll):n
_ I 0, Ich Ir j0ln
'15. I.l.ltllr:l
- r, 5', \br l'. :l):'
, ii r, tL,r 05 :0:'
{i d Ur! ir ll,:(
Ill{H
GAS
Airgas
aa Ar Lrq,,de comFa\
9% OZ|NOZ
AirB!. Sp<.ialt) (ia$r
Airlidr t's.\ l,l,('
6:.to L uit6l t)n\r
l)urhitrr. \_('3--ril
,\ir 8r'.\r,n
CERTI FICATE OF ANALYSIS
Grade of Product: EPA PROTOCOL STANDARD
Part Number: E03N189E15W0020
CylinderNumber: CC506322
Laboratory: 124 - Durham (SAP) - NC
PGVP Number: 822024
Gas Code; NO2.O2.BALN
Reference Number: 1 22-403138917 -1
Cylinder Volume: 145.3 CF
Cylinder Pressure: 2015 PSIG
Valve Oullel: 660
Certification Date: Sep 17, 2024
Exfiration Date: Seo ll.ZOZ7
Cd6(don pglormql n acordarce Hth €PA Trs6$lily Pr6cd lor A*y od Cdildon ol GasG Cdbr&n Sbrirds (l,by 2012)' Ocffit EPA
60CyR.l253l. uenglE aaay pl@ODa l6bd A@[tcd M€thddooy &6 naa.oqura @trffi br sdyElnto.ld6@. Thr €ytfi6 l5s at&l-dylsl
urcsfudy6sblodbd@whacsrhdoccleolol$lt TheGarenoslgnrEidmBrlFiSdalhcthugolth6caltatsmqfuro AlMafrr&oseaons
mdfrDb bs66 ud6! olhsso rctod Th€ ordb re bb 6ly b he ilffir le*d The reprl sh.llnd be r$dEd er@f, n full*ihout ef@al d tt* l$ddry. Oo
Td.d Dala AYClrbl. Upon Rcquast
Approved for Release Pig" t ol I
Abl U56th,3Cyln6.bbw 1m psg ro 07 mcoeMb
Cofiponrnl
ANALYTICAL R"ESULTS
Requartod Actual Protocol Totd R.hliv!Concentr*lon Concdrtratlon llGthod t nc.rtaintv A3ray
Dda3
NTTROGEN DTOXOE 100 0 PPM 99.95 PPM G1 '- 1 3% N|ST Treeabre 09/10/2024. O9,r7im21OXYGEN 10.60'$ 1062q" G1 .i-04%NlSTIraeaHe 0€'lO:D24NITROGEN Bdae
CALIBRATION S'TAN DARDS
Typo Lol lO Cylinder No ConHtrelion Uncrrtdnty Erpirstion Daia
GN.ilS 1534002024601 CC500952 100 4 PP[! NTTROGEN DTOX|DE/N|TROGEN May 0l 2O?7
Nd 21. :O24
P$OA m27
Mz'2 m28
PRM C2392001 04 or5:J54d S 80 PPM N|IROG€N DIOX|DE/A|R
GMrS 1534002024505 CC507606 9964 PPM NITROGEN DTOXIDE"'A|R
NTRM 100106 K02r587 9967%OXYGEN',NTTROGEN
Ilr SRM NTRM PRM or RGM @d ele 6 od! n rcltrcrr b lE GMIS u*d n rk ars! md mr d ol rh tr
10%
0 39'"
lnitrumenUMako/f,lodel
ANAI.I"TICAL EQUIPM ENT
Analytic.l Prlnciplo Lrst i/tultlpoint Calibration
MKS F TtR t'toz 0181765E3
SEmem Oxymat 61 M3299 02
FTIR
PamemUc
Sep 12 2024
Sep 04 2024
GAS
Airgas
Ethylene Only
Airgas Specialty Gases
Airgas USA LLC
r2722 S. wentworth Ave.
Chicago, lL 6o628
Airg,&s.com
CERTIFICATE OF ANALYSIS
Grade of Product: PRIMARY STANDARD
GREAT PLAINS ANALYTICAL SERVICE,Customer:
Parl Number:
Cylinder Number
Laboratory:
Analysis Date:
Lot Number:
XO2NI99P1 sACVH8
cc325720
124 - Chicago (SAP) - lL
Dec 01. 2022
54-402603460-1
Expiration Date: Dec 01,2025
Reference Number: 54-402603460-1
Cylinder Volume: 144.0 CF
Cylinder Pressure: 2015 PSIG
Valve Outlet: 350
Primary Standard Gas Mixtures are traceable to N.LS.T. weights and/or N.I.S,T. Gas Mixture reference materials.
Component
ANALYTICAL RESI.TLTS
Req Conc Actual Concentration
(Mole %)
Analytical
Uncertainty
ETHYLENE
NITROGEN
100.0 PPM
Balane
1OO,O PPM
Approved for Releas€Pag3loll
GAS
Alrgffi
s Ai Lifuldc @drotly
BIP
Alrru SpGddty (;ur
Ai8as t:S{ LlrCqlo utritd Drhe
lhrham. :{C 2r:r!:t
AirS!t.trfr
CERTIFICATE OF BATCH AIYALYSE
Grade of Product: CEM-CAL ZERO
Pan Number:
Cylhder Analyzed:
Laboratry:
Analysb Oale:
Nr c2300
APROINCSG869299A
'124 - Durlurn (SAP) . NC
Feb22,2024
Re{erence Number: 122-40298018&1
Cylnder Volume: 304.0 CF
Cylirder Prcssrm: 26u10 PSIG
Vdw Outlel: 580
Componant
ATIALYTICAL RESULTS
Rcqmrbd
Purfty
C.rtfiod
Cdtcmtratlon
NTROGEN
NOr
so2
THC
CARBON MONOXIOE
CARBON DIOXIDE
99.9995 Yo
0.1 PPM
O.,I PPM
0.1 PPM
0.5 PPM
t.O PPM
<LDL
<LDL
<LDL
99.9995 %
O.O2 PPM
O.O7 PPM
O.O3 PPM
0.1 PPM
O.t PPM
F.rnilr.nt Noti:Alrge3 ccrtitlcs thst thc contenls o, Oris cylind.r mc€i th€ roquirerncflts ot 40 CFR
72.?
Cyllnd.rt ln Brtcfi:
196944Y,409@0, 5867137Y, APRONCSG869290A. CO15440. F1023530, FLr4 18. F19579. Tm236H,
T002408, T I 700 18.. T597209. T987073. TWB35S593Y
lnprrhies \rerified agsinst anaMical st€ndsrds trseable lo NIST by wsighl and/o. end!.sis
Approved for Releare P.g. I ol I
GAS
Airgas
a^ A, Lra,aa compa\
21% 02
AirgEi slr('ielt) (;eer
Airtirs t s.\ l,l.('
ir5 S()dh lrttlu\triill Lx,tt R1,il(l'lixx.lr. t l t{{(t-l
trlln\.1rrtr
CERTIFICATE OF ANALYSIS
Grade of Product: EPA PROTOCOL STANDARI)
Part Number: E02N179E15A0081
CylilrderNumber: CC406148Laboralory. 124 - Tooele (SAP) - UT
PGVP Number: 872024
Gas Code: O2.BALN
Cdficrion p6lormqJ h seordaEe sih'EPA frae*lrty
Tri.d Orlr Avihbla Upon R.quost
Approved for ReleaBe
Reference Numb€r: 153-403018921-1
Cylnder Volume. 146.0 CF
Cylinder Pressure: 2015 PSIG
Valve OuUet: 590
Certification Dat€: A,pr 15. 2f24
Date:
50OR.1253,. ugng lha a3!y p@(fu@i l6bd. A@tttcC M€$oddqy ab6 n.l rqure @reto lor sd'.i@l ntodsoco. Thr cylds B a ltul Ddy'Hl
uEGfudy 6 sbkd bd@ wth a cqrfuaco lBcl d 5A T Ec are no 3enlEad mprlcc SEh dlat h us ol lh6 ElEe[fr mqlro AI M@drdor6 ao on a
md*rob bss6 ud6! othtrec mtql Tho esdts r.bE 6t b he Cmr kid Th€ (elod shallnd b. rpd@d er@d n lullwtbd Srr@al oa t|. l-odsy. Oo
PagE I ol I
Conponanl Rcquostod
Concontrdion
ANALYTICAL R.ESULTS
Aciuel ProtocolConentrdlon [tlcthod
Totd RGletlv!
Uncartsinty
Aisry
Datca
oxYGEN 21.m%MTROGEN Bdarce
21 12 "/o G'f .i 0 5'lo NISI TEede O4!1UN24
CALI B RAT ION S'T'AN DARD.STypo Lot lD Cylinder No ConcGntratlon l,rnc6rtslnty Explrtion Oata
I{IRM 09061434 CC-282452 22.53 % OXYGEN/I{TROGEN 0.4%May 13 2025
lnctrumcnUHd(c/Modcl
ANALYTICAL EQUIPMENT
Analyiicd Princlplc Lat multipolnt Callbration
l-bnba MPA-s10 W6O3tltM58 02 O2 PnamamlE IOIXON)AD( 03 2024
GAS
#Rs
Part Number:
Laboratory:
Analysis Date:
LOT Number:
SN:
CERTIFICATE OF ANALYSIS
Grade of Product: CERTIFIED STANDARD-PROBE
Mcasured Flow Measured Flow Measured Flow Mean Probc
Port A (Vml Port B (Uml Port C (Vm) Port Sampled
lDelta o1l lDelta o2l lDclta o3l Flow (L/m)
Great Plains Analydcal Servlces
303 w 3d st
Elk ciry oK,73644
(580J 225-0403 Fax: (580)225 -2672
Tri Probe Certification
18S
GAS INC
3t3t2022
A
22A't8S
Reference 22
Number:
Stack Diameter:
Target Flow
Rate:
Number of
Points:
'18"
3Umin
3
Product performance verified by direct comparison to calibration standards traceable to N.I.S.T.
*The probe listed on this form meets the multipoint traverse requirement of EPA Method 7e,
section 8.4 as shown in the accompanying data. Method 7e. section 8.4 states that the multipoint
traverse requirement can be satisfied by sampling via "a multi-hole probe designed to sample at
the prescribed points with a flow +/- l0 percent ofmean flow rate".
ANALYTICAL RESULTS
Total Flow
(Uml
Run I
Run 2
2 LPM
4 LPM
o ?20
(tt 54A)
t.{l
(7 el L)
0 (r50 {) 620 0 (*3
(-2ola) (-653A)
130({} 5l a)l2l t 3t
(-7 40l\)
rCalibration conducted in accordance with Emission Measurement Center Guideline Document - EMC GD.03l
3/312022
DateApproved for Release
Probe size: 18S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
RESEARCH TRIANGLE PARK NC ?7711
March 15.2021
,.rrti ,t
A;l , t.t\ rAt I I I i,t ,1l{f ,Jlf ir .
AlJt :AlJi ni.l ,,
Mr. Jordan Williarnson
CEO
GAS Inc.
303 W. 3ra Street
Elk City, OK73644
Dear Mr. Williamson:
We are writing in response to your letter received on September 17,2020, in which you request the approval
of alternative testing procedures. The EPA's Office of Air Quality Planning and Standards (OAQPS) is the
delegated authority for consideration of major alternatives to test methods and procedures as set fofth in 40
CFR parts 60 and 63 under which your request must be addressed. GAS Inc. is requesting a change to one of
the test methods. ASTM D6348-03, used for conducting performance tests to determine compliance under
40 CFR part 60. Subpart JJJJ - Standards of Performance for Stationary Spark Ignition Internal Combustion
Engines (Subpart JJJJ) and 40 CFR parl 63. Subpart ZZZZ - National Emissions Standards for Hazardous
Air Pollutants for Performance for Stationary Reciprocating Internal Combustion Engines (Subpart ZZZZ).
The change being requested will be used to check detector linearity of the Fourier Transform Infrared (FTIR)
instrumentation used to conduct this method. Specifically. you are requesting that the procedures of section
8.3.3 of Method 320 (40 CFR part 60, Appendix A), another FTIR-based method allowed under Subparts
JJJJ and ZZZZ, be used in lieu of section A6.4.1of ASTM D6348-03 when conducting testing using ASTM
D6348-03 under 40 CFR part 60, Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ.
In your request. you state that this alternative linearity check procedure will produce consistent results when
utilizing either Method 320 or ASTM D6348-03. Additionally, some FTIR instrumentation does not allow
for reducing the size of the aperture in the instrument and, thus. it would not be feasible to properly conduct
the entirety of the ASTM D6348-03 method in its current form using such an instrument.
Based on our understanding of FTIR instrument principles and recognition that the requested alternative
determination of detector linearity is both technically sound and contained within Method 320, we are
approving the requested change. We believe that this altemative is acceptable for use for use in testing all
engines subject to 40 CFR part 60 Subpart JJJJ and 40 CFR parl63, Subpart ZZZZ. Also. we will post this
letter as ALT-l4l on EPA's website (alvlnu.epa.gov/emc/broadly-applicable-approted-allernative-
teslmethods) to announce that our approval of this alternative test method is broadly applicable to engines for
the purposes of meeting Subparts JJJJ and ZZZZ.
If you should have any questions or require further information regarding this approval, please contact David
Nash of my staffat 919-541-9425 or email at nash.dave@epa.gov.
Sincerely,
STEFFAN STEFFAN JOHNSON
Digitally slgned by
JoHNSON rffrHil'
Steffan M. Johnson, Group Leader
Measurement Technology Group
Sara Ayers, EPA/OECA/OC/MAMPD, (ayres.sara@epa.gov)
Melanie King, EPA/OAR/OAQPS/SPPD, (king.melanie@epa.gov)
James Leather, EPA Region 6, (leatherjames@epa.gov)
David Nash, EPA/OAR/OAQPSiAQAD, (nash.dave@epa.gov)
cc:
Lewis Shirley
Emissions Specialist
GAS
580-225-0403
info@gasinc.us
Type of Sources Tested:
Stationary lnternal Combustion Engines. 4 Stroke Rich Burn Engines. 2 Stroke & 4 Stroke Lean Burn Engines
Stationary Natural Gas Fired Generators
Stationary Propane Fired Generators
Gas Fired Boilers
Types of Analyzers:. Gasmet DX4000 FTIR. Gasmet Portable Sampling Unit with Zirconium Oxide 02 Sensory. Testo 350. Flame lonization Detector
Qualifications:
Trained, studied, and fully demonstrates compliance for emissions testing via data collection outlined in the
following Reference Methods:. EPA Method 1 & 1A - Sampling & Traverse Points. EPA Method 2 &2C - Velocity & Volumetric Flow Rate of a Gas Stream. EPA Method 3A - Oxygen. EPA Method 7E - NOX. EPA Method 10 - Carbon Monoxide. EPA Method 25A- Volatile Organic Compounds. ASTM D6348 - Extractive Fourier Transform lnfrared Spectroscopy
Conducts emissions testing on a weekly basis including, but not limited to, the following test types: lnitial
Compliance, Biennial Compliance, Semiannual Compliance & Quarterly Compliance. Alltests performed
are in accordance to any and all Federal & State requirements as applicable (i.e. JJJJ, ZZZZ, 106.51 2, 117,
PEA, etc.). Performed testing in Colorado, Utah, Wyoming, North Dakota, Montana, Kansas, New Mexico,
Oklahoma, Texas, Louisiana (land and off-shore), Arkansas, Ohio, Pennsylvania, West Virginia, New York,
Kentucky, & Mississippi.
. Quarterly Performance Reviews covering ongoing changes with Federal Regulations, State
Compliance guidelines, & site-specific safety certifications.
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40 CFR Part 60 Subpart JJJJ
Performance Test Report
Test Type: Annual
Test Date: 1U1O2.O24
Source:
Waukesha 9394GSl
Rich Burn (4 Cycle)
Unit Numberz 1254
Serial Number: 1453999
Engine Hours: 32320
Location:
Duchesne Data Center Power Station
Duchesne County, Utah
Prepared on Behall of:
Crusoe Energy Systems, lnc.
+As"
oepnnrneNT-b?-
ENVI'-IONMEN TAL OUALITY
N0r/ - 5 2024
DtvtstoN OF AtB ot,At try
303 W. 3rd St (580) 225-0403 Elk City , OK 73644
lndex
1.0 Key Personnel.... ..... .. .. . 3
2.0 Sampling System..... ....... 3
3.0 Methods Used...... ..... . 3
4.0 Test Summaries.. . 5
5.0 Run Summaries.. . 6
6.0 Volumetric Flow Rate Data.... ............. 7
7.0Calculations........... ..8
8.0 Oxygen Calibration... ...... I
9.0 Engine Parameter Data Sheet.. .......... 10
10.0 QA/QC Results... ........ 11
11.0 D6348Annexes... . ....... 12
12.0 Signature Page....... ....... 18
13.0 Appendices.............. ....... 19
14.0 Bottle Certs........... . 20
15.0 Tri Probe Certification via GD-031 . . 25
16.0 GAS ALT 141_FT|R EPA........ ............26
17.0 Tester Qualifications (resume)... ......... 28
18 0 Raw Data
iaUl;;
.... . 2e
Table 5.1 (Run Summaries)
Table 6.1 (Volumetric Flow Rate Data)........... ................ 7
Table 6.2 (Stack Gas Measurements)....... ......................7
Table 8.1 (Oxygen Calibration). .................. I
Annex Table 1.2.1 (Certified Calibration Bottle Concentrations)......... 12
Annex Table 1.2.2 (Measurement System Capabilities)..................... 12
AnnexTable 1.3.1 (TestSpecificTargetAnalytes)............................. 13
Annex Table 4.1 (Measure System Capabilities) ............ 15
Figures
Figure 6.1 (Location of Traverse Points per Method 1) . .. . .. .. 7
Annex Figure 1.4.1 (Sampling Train).... ...... 13
Annex Figure 1.4.2 (Sampling Points).. .......14
Annex Figure 1.4.3 (Sampling Port Locations)... ............. 14
Appendices
Certified Calibration Bottle Certificates...........
Tri Probe Certification via GD-031
GAS ALT 141 FTIR EPA.
20
25
27
Tester Qualifi cations (resume)..................... 28
Raw Data..29
3
1.0 Key Personnel
GAS, lnc.
Crusoe Energy Systems, lnc.
Lewis Shirley
Alex Nelson
2.0 Sampling System
The sampling system used consisted of a Stainless steel probe, heated Teflon line, gas conditioning
system, and a Gasmet model DX4000 FTIR analyzer. The gas conditioning system used was a Gasmet
Personal Sampling System with a Zirconium Oxide oxygen sensor.
3.0 Methods Used
ASTM D6348.03
This extractive FTIR based field test method is used to quantify gas phase concentrations of multiple target
analytes (CO, NOX, CH2O, & VOC's) from stationary source effluent. Because an FTIR analyzer is
potentially capable of analyzing hundreds of compounds, this test method is not analyte or source specific.
The analytes, detection levels, and data quality objectives are expected to change for any particular testing
situation. lt is the responsibility of the tester to define the target analytes, the associated detection limits foi
those analytes in the particular source effluent, and the required data quality objectives for each specific
test program. Provisions are included in this test method that require the tester to determine critical
sampling system and instrument operational parameters, and for the conduct of QA/QC procedures.
Testers following this test method will generate data that will allow an independent observer to verify the
valid collection, identification, and quantification of the subject target analytes.
EPAMethodl&1A
The purpose of the method is to provide guidance for the selection of sampling ports and traverse points at
which sampling for air pollutants will be performed pursuant to regulations set forth in this part.
EPAMethod2&2C
This method is applicable for the determination of the average velocity and the volumetric flow rate of a gas
stream. The average gas veloci$ in a stack is determined from the gas density and from measurement of
the average velocity head with a standard pitot tube. Velocity readings are taken from each stack at 16
separate traverse points (Table 6.1) and used to determine the engines mass emissions rate, calculated
utilizing the formulas seen in section 7.0 ol this report.
EPA Method 3A
This is a procedure for measuring oxygen (O2) and carbon dioxide (CO2) in stationary source emissions
using a continuous instrumental analyzer. Quality assurance and quality control requirements are included
to assure that the tester collects data of known quality. Documentation to these specific requirements for
equipment, supplies, sample collection and analysis, calculations, and data analysis will be included.
Gas, lnc.
4.0 Test Summary
Unit 1254 with a serial number of 1453999 which is a Waukesha 9394GSl engine located at Duchesne
Data Center Power Station and operated by Crusoe Energy Systems, !nc. was tested for emissions of:
Carbon Monoxide, Oxides of Nitrogen, and Volatile Organic Compounds. The test was conducted on
1011012024 by Lewis Shirley with Great Plains Analytical Services, lnc. All quality assurance and quality
control tests were within acceptable tolerances.
The engine is a natural gas fired Rich Burn (4 Cycle) engine rated at 2500 brake horse power (BHP) at
1200 RPM. The engine was operating at 2244BHP and 1200 RPM which is 89.74% of maximum engine
load during the test. The test HP calculation can be found on page 8. The engine was running at the
maximum load available at the test site.
This test will satisfy the testing requirements for 40 CFR Part 60 Subpart JJJJ.
Site Verification Photos
P 3 J9-r,l
Gas, lnc.
Location Ouchesne Daia Center Power Stalion Unit lD 't2*
MAKE Waukesha Site Elevation ft.5784.73
Model 9394GSl Atmospheric Pressure psi.11.42
Serial Number 1453999 Stack Diameter in 20
mfo. rated ho 2500 Catalyst Yes
mfo. raled rDm 1200 Date of Manufacture
Test Horseoower 2244 22M 2244 2244
IESt HPM 1200 1 200 1 199 12o,0
Percent Load "/o U9.14-/o 69.14"/o lJ9.14-/o A9.l4Yo
lntake Manitold Pressure (hg)105.63 105.02 1867.r+0 692.64
lniake Manifold Temoerature (F)125.20 124.OO 63.30 10,4.17
Ambient Temperature Drv (F)43.00 5t.00 60.00 51.33
O Stack (dscfh)204731.35 179572.84 180495.95 188267.O4
O Stack (dscm/hr)5797.29 5U64.US 5111.06 5331 .O8
Moisture Fraction Bws 0.18 0.18 0.18 0.18
Method 3A Corrected O2o/" DN o.22"/o O.28"/o 0.600/o 0.377"
Moisture 7o 17.74o/"17.854/o 18.244/o 1.94"/o
5
5.0 Run Summaries
Table 5.1 Run Summaries
Gas, lnc.
6.0 Volumetric Flow Rate Data 7
Table 6.2. Stack gas pressure use lor Volumetrlc Flow Rate
Aostd = Velocitv head measured bv the' standard pitot tube, (in.) H2O.-
SamDte aner t acK ruroe.I.UJ
Wilhin 5ol" ol Last Apstd readino:YES
Flgure 6.1
16 Traverse Points Were UsedStack Diameter (inches)20.00
lnches upstream from disturbance 4.@
lnches downstream from dislurbance 30.00
Pitot readings are taken for Method 2 calculations using measuring points outlined in Method 1
'The exhaust stack dld not present cyclonlc llow condltlons at the sampllng locatlon due to the
absence of cyclones, lnertlal demlsters, venturl scrubbers, or tangentla! lnlets.
;A*_-!,..i z(
L
'f l'-
t:6a
-1\so\
Table 6.1. Data used for volumetric flow rate (Method 2)
Pitot Tube Coefflcient Cp(std)= .99
Stack diameter = 20 linches or:1.67 r€el. or:2.14 Square Feet
H20 o/od '17.74 17.85 18.24 17.94
COz I o/od 9.42 9.47 9.59 9.49
OZ I "/od o.18 0.23 0.50 0.30
CO I ppmd 5.49 9.04 19.'t2 11.21
Molecular Weioht Stack Gas drv basis (Md) I q/o mole 29.51 29.52 29.55 29.53
Molecular Weioht Stack Gas wet basis (Ms)o/o mole 27.47 27.47 27 _45 27.46
stack static Pressure (Pq) I 'H20 0.70 0.54 0.55 0.59
Stack Static Pressure (Po) I "Hq 0.05 0.04 0.o4 0.04
Atmosoheric Pressure at Location Pbar MBAFI 831.00 832.00 831 .1 8 831.39
Atmosoheric Pressure at Location Pbar "Hq 24.il 24.57 24.55 24.56
Absolute Stack Pressure (Ps)"Hg 24.60 24_61 24.59 24.60
Stack Temperature I Deq C 495.56 498.26 498.85 497.56
Stack Temperature I L,eq F 924.00 928.88 .94 927.
Stack Temperature I Deo R 1383.67 1384.55 1389.61 1347.27
Stack Gas Velocity I fvsec 101.01 88.98 90.01 93.50
Siack Flow Rate Q I cfs 220.34 194.12 196.38 204.00
stack Gas wet volmetric Flow Hate I scf/hr | 248868.101 218ffi3.381 220769.77 229807.20
Stack Gas Dry Volumetric Flow Rate I scl/hr | 204731.341 179572.841 180496.94 144570.98
ffi lono line samolino orobe lnches
First Samolino Point Taken @ 16.7"/" ol Stack Diameter 3.34
Second SamDlino Point Taken @ 50% of Stack Diameter 10
Third Samolinq Point Taken @ 83.3olo ol Stack Diameter 16.66
nqs measured with a standard D
FIUN ln LJN
aoatd ilnt H2():xnaust lomo r ato nztt txnauat I emo Fl aoato llnt Hzo EXnauSl I emo t
Pitot Tube Samolino Points (Velocitv)
1 0.40 925.00 o.62 930.00 0.65 931.00
2 o.38 923.00 0.83 927.0O 1.04 929.00
3 v.'lz 923.OO 1.O3 92E.O0 1.O2 92E.OO
4 v.4l 924.OO o.90 9:,U.UU o.86 930.00
5 0.97 923.00 o.32 929.(ru o.22 930.00
6 1.30 924.OO 0.37 929.00 0.29 929.00
7 1.22 924.OO o.27 930.00 0.55 931.OO
8 1.17 925.00 0.16 927.0O 0.s0 929.00
9 1.25 923.00 0.41 9Z9.UU 0.34 929.00
t0 1.26 923.OO o.44 92E.OO o.51 931.OO
11 1.29 926.00 o.75 930.OO o.22 93r.OO
12 0.34 925.0O o.47 929.00 0.36 931.00
13 0.35 925.00 o.28 9Z9.UU 0.60 929.00
14 o.22 923.OO 0.40 930.00 o.42 931.00
15 0.13 924.00 (,.43 928.00 0.18 930.00
16 0.26 924.OO 0.93 929.00 1.03 930.00
Aoslcl Averaoe=o.t{)924.OO 0.54 928.88 0.55 929.94
Gas, lnc.
7.0 Calculations
Method 2: Determination ol Stack Gas VelociW and Volumetric Flow Rate
.Note- Use of this method neqates the need for anv fuel related numbers for emissions calculations
Ap(avg) - Velocity head of stack gas, mm H2O (in. H2O).
3600 = Conversion Faclor. sec/hr.
A = Cross-sectional area of stack, m2 (ftZ).
Bws = Waler vapor in the gas slream (from ASTM D6348)
Cp(std) = Standard pitot tube coetficient; use 0.99
Kp = Velocity equation constant.
Md = Molecular weight of stack gas, dry basis, g/g-mole (lb./lb.-mole).
Ms = Molecular weight of stack gas, wet basis, g/g-mole (lb./lb. -mole).
Ps = Absolute stack pressure (Pbar+ Pg), mm Hg (in Hg)
Pstd = Standard absolute pressure, 760 mm Hg (29.92 in. Hg).
Osd = Dry volumetric stack gas flow rate corrected to
standard conditions, dscm/hr. (dscl/hr.).
Ts(abs) = Absolute stack temperature, oK ('R). = 460 + Ts for
English units.
Tstd = Standard absolute temperature, 293'K (528'R).
Vs = Average stack gas velocity, m/sec (ft./sec).
Md = . 44 ( o/oCO 2l + . 32 (o/oO2l +.28("/oN 2 +o/oCO )Md = .44(.094)+.32(.002)+.28(.903+.001 ) = 29. 51 4 LB/LB-MOLE
Vs = Kp'Cp(stct1'y'apavg'y'1rs1abs)/(Ps'Ms))vs = 85.49'.99 "/.t "/ ('t S$.At I e4.6' 27 . 47 2)) = 1 o 1 .O r FTIS EC
Qsd = 3600( 1 -Bws)Vs'A((Tstd'Ps)/(Ts(abs)' Pstd))Osd = 36OO(1-.177)101.014'2.182((528'24.6y (1388.67'29.92\l =204731.35 DSCF/HR
Q = Osd/35.315 A = 204731 .345/35.31 5 - 5797 .291 DSCM/HR
Emission Rates (Examples use CO Run 1)
453.6= Conversion factor lb. to gram HP= Engines rated Horsepower
A = Cross-sectional area of stack, m2 (ft2). Mfg.= ysnul.cturer Exhaust flow rate al 1O0o/o (ft3/min)
BHP/HR. = Brake work ol the engine, horsepower-hour (HP-HR.). 02 = Concentration of oxygen on a dry basis, percent.
BTU/HP-HR. = Brake Specific Fuel Consumplion (HHV) ppm= Parts Per Million (CO)
ER = Emission rate ol (CO) in g/HP-hr. ppm@15% 02= PPM corrected lo 15o/"02
F(d 1= y61ur.s of combustion components per unit of heat Qsd = Dry volumetric stack gas flow rate corrected
contenl, scm/J (scf/million Btu). to standard conditions, dscm/hr. (DSCF/HR.).
Q = Stack gas volumetric llow rate, in standard cubic meters Run Time = Run Time in Minutes
per hour, dry basis Tpy= Tons per year
LB/HR'= Emission rate ol (co) in LB/HR' vs = Average stack gas velocity, m/sec (fl./sec).
Molwl.= MolWeight ol CO (28.01)
ppm @ 15o/o 02 = PPM'((20.9-15%O2y(20.9-O2))ppm @ 1 5olo 02 = 6.667'(20.9-1 5ll(20.9-.P/")) = 1 .9 PPM @ 1 5o/" 02
g/hp-hr = (PPM'(1. 1 64'1 0L3)'Q'(Run Time/60))/BHP/HR (6.667'( 1 . 1 64' 1 0^-3)'5797.29 1'(Run Time/60)112243.53 = .02 G/HP-HR
lb/hr = ER'1/453.6'BHP-HR LB/HR = .02'1t453.6'2243.53 = .099 LB/HR
TPY = LB/HR. '4.38 TPY = .099'4.38 = .434 TPY
KW'1.34022088 1674'1.34022088
ppm wel' (1(1-H2O) - ppm dry 6.67 = 5.as5'11 (1 -.18))
Gas, lnc.
8.0 Oxygen Callbration 9
8.1 Calibration error tost; how do I confirm my analyzer calibration is correct? After the tester has assembled, prepared and calibrated the
sampling system and analyzer. they conduct a 3-point analyzer ca[bration error test before the first run and again after any failed system bias test or
failed drifi test. They then introduce the low-, mid-, and high-level calibration gases sequentially in direct calibration mode. At each calibratron gas level
(low. mid. and high) the calibration error must be within 1 2 0 percent of the calabration span.
8.2 lnitial systsm bias and system calibration error checks. Before sampling begins. it is determined whether the high- level or mid-level
calibration gas best approximates the emissions and it rs used as the upscale gas. The upscale gas rs introduced at the probe upstream of all sample-
conditroning components in system calibration mode.
( 1 ) Next. zero gas rs introduced as described above. The response must be within 0.5 percent of the upscale gas concentration.
(2) Low-level gas reading is observed until it has reached a final, stable value and the results are recorded. The measurement system will be
operated at the normal sampling rate during all system bias checks.
(3) lf the inrtral system bias specification is not met, corrective action is taken. The applicable calibration error test from Section 8.2.3 of EPA
Method 7E is repeated along with the initial system bias check until acceptable results are achieved. after which sampling will begin. The pre-
and post-run system bias musl be within t 5.0 percent of the calibration span for the low-level and upsc€le calibration gases.
8.3 Post-run system blas check and drift assessment - confirming that each sample collected is valid. Sampling may be performed for multlple
runs before performing the post-run bias or system calibration enor check provided this test is passed at the conclusion of the group of runs. A failed
final test in this case will invalidate all runs subsequent to the last passed test.
(1 ) lf the poslrun system bias check is not passed. then the run is invalid. The problem is then diagnosed and fixed, then another calibration
error tesl and system bras is passed before repeating the run.
(2)Aftereach run, the low-level and upscale dnftiscalculated, using Equation 7E4rn Section 12.5from EPAMethod 7E. lf the posLrun low-
and upscale bias checks are passed, but the low-or upscale drift exceeds the specification rn Section 13.3. the run data are valid. but a 3-point
calibration error tesl and a syslem bias check must be performed and passed prior to additional testing.
Table 8.1 Oxygen Callbration
Method 7E 3.4 To the extent practicable, the measured emissions should be between
20 to 100 per€nt of the selected calibration span. This may not be practicable in some
c€ses of low concentration measurements or testing for compliance with an emission
limit when emissions are substantially less than the limit.
EPA Method 3A QA Worfsheet
Cerdfrod Ger Concrntn-on I Ccrtlfr.d G.. Conc.nErl,on I C.ftmcd C,a! Co
Low.Lcvel (16) | Hld-Levol (%) I Hlgh{cvt
too",
(DIRECT) Analy:er Calibratlon Enor (s 2%)
Check
ncantralon
7E 8.5: Note: that you may
risk sampling for multiple
runs before performing the
post-run bias provided you
pass this test at the
conclusion of the group of
runs
Cenifi.d
Conceofatioa
Value (%)
Dir6ct
Crlibrltion
Rerponso (%)
Absolute
Difierencc (%)
Analper
Cdib.ltioflEnor(%)
Zero Gas Yo 0.00o/o 0.00o/o 0.00% 0.00%
Mid-Level Gas 9o
High-Level Gas %
10.62Yo
21 120/"
10.78o/o
21.450h
0.16%
0.33%
0 76%
1 .580/.
(SYSTEH) Calibration Blas Check3 (l 5%) and orift Check! (5 3%l Uprcale Ges 10.62%
Zero Offs6t 0.0O%
Biac Pre lnitial Veluc Bi!3 Post lnitd ValuerSpan 21.12
Analfzer
Calibration
Response (o/o)
Zero Gas 0.0oyo
SFt m
Calibratione
Respome Pre
(Yo)
;y3r.m Bi.! (9(
of Spen) Pre
SlctemCslibnrirn
R.3pon!. Po.t
(%)
lpbm Bia (i
ot Sp!n) Po.i fi{t(%of
Spen)
0.00%o oo'/.0.0oo/o 0.00%0.000/"
Upscale Gas 10.781o 10.690/o 0.44%10.67%0.52%0.000/o
(SYSTEm) Calibratlon Blas Checke (l 5'/6) and Drift Checks (S 3'A)
Avo. Gcs Concentatirn (Run 1 0.22Yo Efruent Gas (Coa3) Run 1 0.227o
Avg. Gas Concenfatbn (Run 2)o.28Yo Eflluent Gas (C,gar) Run 2 0.280h
Avg. Gas Concentsrfon (Run 3)0.61%Effuant Gas (Cgrs) Run 3 0.60%
EPA Method 3A CIA Worksheet
Zero Gas 100% Nfuogen
Mid-Level Gas lO.62Yo
High-Level Gas 21.120/"
Zero Gas %
Mid-Level Gas o/o
High-Level Gas o/o
zero Grs % l-16%-l Uprcate Uced
Upscare car l-,osr"/-] 10.62olo
zero cas e; I fi;fl Upscate Urod
Upscarecar fro6?%_l fi.62o/,
Gas, lnc.
Company Crusoe Enerov Svstems. lnc.
Facilfty Duchesne Data Center Power Station
Date 101't012024
sate Etevation (ft)5788.73
Unlt lD 1zil
Make Waukesha
Mode!9394GSr
sefla! Number 1 453999
Techniclan Lewis ShirleV
9.0 Engine Parameter Data Sheet
AS
Completed
Run Start Times 07:36 AM 09:03 AM 10:14 AM 11:49 AM
Englne Hours 32317 32318 3231 I 32320
Engine Parameter Data
tlun I Run 2 Run 3 Averaqe
Enslne Speed (RPM)1200_0 1200.0 1199.0 1 199.7
lntake Manitold Pressure (psil o3.t 63.4 929.0 J52.U
lntake Manatold Temp "F 125.2 124.O 63.3 1o4.2
Enqins Load (BHP):2243.5 2243.5 2243.5 2243.5
Amblent TemD "F zt{|.0 51.0 60.0 51.3
Humldltv %52.0 42.O 29.0 41.0
Dew Polnt "F 27.O 28.0 2A.O 27.7
AFR Manutacturer/Type waul(esha waukesha waukesha waul(esha
Suctlon Pressure N/A N/A N/A N/A
Dlscharqe Pressure N/A N/A N/A N/A
uatatYst lYes or NC Yes
Catalyst Manulacturer Mtratsch Miratech Mrratech Mtratech
# ol Catalyst lnstalled 1 1
Catalyst lnlet Temo "F 1 101.0 1101 .0 1087.0 1096.3
Calalyst Outlet TemD "l-1123-O 1121.O 't't 14.0 1 1 19.3
Catalysi Pressure Drop H2O 6.0 6.O b.u 6
11
10.0 OA/QC Besults
mZero Response Time
System Response Time 45 seconds
Nitrogen monoxide NO
Nitrogen dioxide NO2
NOx
voc
Oxygen
Average:0.24
Average:0.00
Average:0.24
Average:0.23
Average:0.03
CTS Bottle Concentration
CTS Compound Concentration Avg
Tolerance
Ditference between measured and expected
Value: 100.30
Value:99.84
2.OO/"
0.467"
Nitrogen monoxide NO
Nitrogen dioxide NO2
NOx
VOC
Oxygen
Average:0.04
Average:0.59
Average:0.00
Average:0.60
Average:0.50
Average:0.12
CTS Bottle Concentration
CTS Compound Concentration Avg
Tolerance
Difference between measured and expected
Value: 100.30
Value:98.61
5.00%
1.68%
Equilibration Response Time
Spike Reported
Spike Expected
45 seconcls
Value: 248.44
Value: 252.40
Gas, lnc.
12
1 1 .0 D6348 Annexes 1-8
1. Test
nex
The test quality objectives completed for the emissions test are demonstrated throughout Annexes 1,2,3,
4, 5, 6, 7 & B as layed out per ASTM D6348-03. All reference methods, pre-test and post test procedures
were within acceptable limits. Data generated during the pre-test and post-test procedures are
summarized below in order of the distinctive Annex.
Three 60 minute test runs were performed. The final analyte concentrations are the average of each test
run. Data was taken at 60 second intervals. Each 60 second measurement was the average of 600 scans.
Propane is used as the surrogate compound for the Annex 5 Spiking Technique due to Propane being the
VOC that is most commonly found in the combustion process ol natural gas. Additionally, the molecular
weight of Propane coincides with with molecular weight of VOC's per the EPA.
Annex Table 1.2.1 Certified Calibration Bottle Concentrations
Bottle Expiration N02 Ethvlene SF6 02 ("/ol
cc506322 9t1712027 99.95 'r 0 62"6
12t1t2025 100.30
cc406148 4t15t2032 21 .12",o
Cylinder # ALM-063647 Expiration: 5-03-2032
Propane co NO SF6
Bottle Value 252.40 501.70 237.50 10.20
Analvzer Svslem Hesoonse 248.44 505.39 237.61 10.27
Hercenl utnerence 1 .57q"o.7 40.,"o.040'"o.71"/"
Annex Table 1.2.2 Measurement System Capabilities
|Jarameler
Measured Gas Concentration(opm)Path Length EquIrDraIton
Time Dilution Factor o/o Recovery
Path Lenoth Ethylene 99.841 4 977
Spike Drrect
Hropane 250.748
SF6 10 349
CO 509.787
NO 240.030
Mechanical
Response Time Elhylene 98.61 1 40 seconds
Analyzer
Response
Prooane 248.441
16 secondsSF610.272
CO s05.388
NU 237 605
Analyte Spike
Recovery Propane & SF6
8.07";91 .36"rir
7.3O"1"U9.59"/o
8.1 3"."92.bYYo
System Zero Nitroqen 27 seconds
Posl Spike
System
Propane 247.4'16
CO 509.647
NO 236.173
SI-6 10.217
Gas. lnc.
Annex Table 1.3.1 Test Specific Target Analytes and Data Quality Objectives
Compounds
lnfrared
Analysls Reglon
(cm-1)
Erpected
Concentratlon
Range
MeaSurement
System
Achlevable
Mlnlmum
tletectableConcentretlons
rlequrreg
Measurement
SystemAccuracy and
Preclslon for
Test Aoolicatlon
co 2000-2200 0-1200 oom O.16267 oom 4 pom
NO lE75-2't3E o-1000 pom 0.4007 ppm 2 ppm
N02 2700-2950 O-1OO oom 0.4899 Dom 2ggm
VOC
2600-3200
0-100 ppm 1.8520 ppm Total
VOC'S 1 ppmperVOC91 0-1 1 50
2550-2950
CH2O 2550-2850 0-100 oom 0.7878 ppm 1 ppm
lnterlering
Gompounds ' CO is analyzed in a separate analysis region than CO2 and H2O
coz 926-1 1 50 O-1Oo/"O"/o nla
Water VaDor 3200-3401 O-22o/o Q.200/"nla
' VOCs compiled of Acetaldehyde, Ethylene, Hexane, and Propane.
c2
SENSOR
PSS PROB€E;Tt
L
G^SffiI
FTIR
PA\IEL
Ftow
HTR.
'/Ef\T
Figure Annex 1.4.1 Sampling Traln
The testing instrumentation is housed in an enclosed vehicle which is located approximately 45 feet from the source. A
heated sample line (sixty feet in length) is attached to the inlet of analyzer system and the source effluent discharges
through the FTIR outlet.
It
lt
GAS
S?ACX
Gas, lnc.
14
Sampllng Point Locations
ln lnches
'16.7o/o 3.lrrto
5O"/o ro.qx)
83.3%16.6tr
trUJF
Tso
!3.a
?lr,
d.
uJt-utt
o
E
at
lnches
Upstream:
4
lncies
Downstream:
30
TRI-PROBE SAMPLE POINT LOCATIONS
AS PERCENTAGE OF STACK DIAMETER
Flgure Annex 1.4.2 Sampllng Polnts
lnterior Stack Diameter (inches):
SAIPLE PORT LOCAITON OETERMINED
BY USTAiICE FROI,I USTI'REANCE
Flgure Annex 1.4.3 Sample Port Locatlon
Pressure (9 liamollno Polnt (Po'HzU 0.59
I emDerature (9 Samollno Point (Deo F 927.6
stacl( Gas Drv volumetnc Flow Bate IUUb/U.9U
Hzoo/d @ SamDlino Point: 17.94
CO2o/"d @ Samolino Poini:.4
Gas, lnc.
Target Analyte Resutts (ppm)
CO 0.1621
NO U.4UUr
NO2 0.489S
Ethvlene u.3 /62
Propane 0.4351
Hexane 0.223i
Acetaldehvde 0.815'
Formaldehvde u. lalt
N ri rt, ;;: '. n/ ,: z ,*:, r ( N r;,r"1 )
ll y N.,. z rrrri
"tt
"'t lllll"l' t )\
,rt
'^i l: A l-llt s - L'' "' I'' "'
RI;l: ttt 1.,,-t!,'rtl s
trlIt t-' t-', ,rl.\
Ll DC'II
caltbratron I ranster Stanoard Exoected Measured Path Lenqth Validated
Ethylene 100.3 99.64 4.977 PASSEd
Annex Table 1.2.2 Measurement System Capabilities
Farameler
Measured Gas uoncenlratron(nnml Path Length tsqullrDratron
Time Dilution Factor o/o Recovery
Path I enoth thvlene 99.841 4.977
Sprke Direct
Prooane 250 788
SF6 10.349
CO 509.787
NO 240 030
Mechanical
Response Time Ethylene 98.611 40 seconds
Analyzer
Response
Propane 1248.441
16 secondsSF610.272
CO 505.388
NO 237.605
Analyte Spike
Recovery Propane & SF6
8.O70,"91 .360,a
/ .JU"/o 6U.59"rc
8.13"i,92-b9"/o
System Zero Nrlroqen 27 seconds
Post Spike
System
Propane 247.416
CO 509 647
NO 236.173
SF6 10.217
Gas, lnc.
Paramgter Gas ConcentraUon Measured 7" Diflerence Soecificatlon valldatod
Spike Direcl
Propane 252.400 250.788 0.64o/"+l- 2o/"Pass
SF6 10.200 10.349 1.46"/o 'tl'Z'/o PASS
CO 5U1 . /UU 509.787 1.61o/"+l- 2o/"f,ass
NO 237.500 240.030 1.070k +l- 2o/"PaSS
Spike Run 1 vaa the System
Source Outout Soike Averaoe Dilution Factor Exoected 7o Recoverv SDecification
Propane 0.001 18.609 20.369 91.3600/o 7O-13O7o
SF6 0.000 0.835 8.068%<'lOo/o
spake Run 2 vla the system
source uulput SDake Averaqe Dilution Factor Expected 70 Recoverv SDecification
Prooane 0.000 16.508 18.425 89.5900/"70-130e'.
SF6 0.001 0.755 7.295o/"<'lQo/"
Soike Run 3 via the Svstem
source outout spike Averaqe Dalution Factor Expected 70 FleGOvery specitication
Propane U.UUU 19.020 20.520 92.690o/o 7O'13O"/o
SF6 o.oo1 o.841 8.1260/"<l U-lo
Noise Equivalent Absorbance (NEA)
RMS High 0.005s06
RMS Mid 0.002723
RMS Low 0.004269
Position: Demonstrating the peak positions a nual
Lrrre Posrtron
Line Position Ditference:Resolution Difference to Relerencel 2.06q"0.00o,o Pass
Gas, lnc.
Pass
The Gasmet GICCOR (Genzel lnterferometer with Cube Corner Retroreflectors) interferometer is specially
designed for maximum opticalthroughput and maximum signalto noise ratio of 7.72 (cm-1) remaining
stable with any vibration and temperature changes.
The DX4000 is a low resolution spectrometer where the aperture is fixed to a
setting and the detector linearity was tested with an alternate approach. A three point linerarity of the CTS
gas was performed and validated.
Lin ea rity
31 9945
22 9945
1 3 9945
4 9945
4 0055
1 3 0055
22 0055
-31 0055
,40 0055695 687
31 9945
22 9945
1 3 9945
4 9945
-4 0055
1 3 0055
-22 0055
-31 0055
-40 0055679 672 664 656 648 641 633 625 61 8 6 I 0 602
.002336901 Pass
The analytical accuracy of the quantification algorithm is satisfied via the results from Annex 5 per Annex
7.6
FgsTgTs gytEm Gnecr:
u t 5 t ome uoncenlralton:100.30
u | 5 lramDre uoncentra[on Averaqe:98.79
Dillerence between measured and exDected:1.53o/o
lolerance:5.(X)7o
Fun m Ydl6uoD - AnilclrtEd Yt Ertd Erdlm yalEalDal Gorrllmils
F{Un I FOtnIS I A ZOn ULr/NU/rrOOane All within 20%PaSSed uemonstrales no rntenerenoes obs€rvecl.
HUn Z HOTnIS 'l 6 Z On UU/NU/HrOpane Allwithin 20% Passed ugmonstrates no tnterferenoes observed-
Run 3 Points 1 & 2 on CONO/Prooane All within 20olo Passed uemonsrrares no rnrenerenoes ooserveo.
Gas, lnc.
18
12.0 Signature Page
Job/File Name: Crusoe Energy Systems, lnc.; Duchesne Data Center Power Station; 1254;JJJJ
We certify that based on review of test data, knowledge of those individuals directly responsible for
conducting this test, we believe the submitted information to be accurate and complete.
Company: G.A.S. lnc.
Print Name: Lewis Shirley
Title: Emissions Specialist
Date:10/1012024
Company:
Print Name:
Signature:
Title:
Phone Number:
Date:
Company: G.A.S. tnc.
Print Name: Travis Hartley
Title: Director of Stack Testing
Signature:' =\-)- -
Phone Number: 580-225-0403
Date: 'f OhOPO?4
Gas, lnc.
Appendices
r lLo.dc.rron
Spike (5 Gas)
ttlrr tFa.l, (.8
trer.t t\ll(
l -'-:: \ tlilt,rti {.r
( ir.r.ll dl,:\
\ rtr. i .n
CE RTI FICATE OF ANALYSIS
Gmdc of Pmducl: EPA PROT(IOL STAIDARDCr.*,r Ge€.^l R.AraEArrllYIEA -RVrcEPnlfnDr
Cla.qr rfr.r$..L&rEy
FOVP |Ulocr
G.a Co(b
EOl,lr9aC lSAC,r.rl'u06r.,l?a Or.e3lslPr lti r2of.co co: rro rlor PPx 0Atx
R.hm lao traoltlg? !
Cr5rlf \blr. 147 0
Cthd; Prrrrrc 2Ot5Vr. Orf. oao
C..rt Et O- Un Ol 2qa
Cryrrbn Or-: by0l 2Ol0
C.lt- t-d - ...,ffi - {X la.dl }oad t, tq d C./ra.ab d b. C-.b 5A tt- lgl: O*ea ltlaaOfr:tr( cre t'trtprao^r.-{ Arutn(tfa.n6aod^{rrae@dqirEt r'rt .re rs$..!a.ualcr-taff+tritxda- H -t a(aru.(a ts oat \ ttanar0naqrrt{ta.tfrirldnr - dtra'J.ra..rd.l, Arqaa&ra roa@mm,lo frGC ftEarcorrt bt\ahE ?bildrtd !.'lr&d..lqrtolr ..hr afrydht&*.t Oold r t\.CFCtu'I9{ . l!-.tt.l.
r\ rt.t rl( rt. t[st I ni
( .u-tttat r)\ sr.r\D.rltlxi
r\.rl.l I r AL LQt t?ttL\ I
a
r -r,tt \: ?], .r.'{.'I Itl
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r -r,)c \( l-\' 't:r.'
.[r! $ ?.' n-. '
\rr\{.7r r\rt.l n( rt. tl.lrt t.ri
lrt a lX. lr-* t,- LlGa
'iora (rtllr ^rml lqaa t t )btis{a r a lrr c6rpt{ A.td tFla(, v-, rr6.cd -\n G. rgl,rJ Ca,DtkI d ArJyta
Codrct frr &grr t d.El I . !9nd i ?rqurrd SrO O tO l0 FPff
SrgTtarrt o t-
Af+.c- b, Xbb.r.p.r1r' I .rl !
--
haE l-lba.l-D l_l-.- gb
'\ :!,'fru
llh.,\ll{ :!,',Pv
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\lDr\:rr\Ii
llra.t\ tlb,
t-D
,vrl lt \ .lr\.:'s 're.' tv \tIIt r,\tX \rtir,t \
1.,,(R\:lli 'r\i{ \ ll(r t\
a rr tV \lllr..t \ trt'\l{ \.larr,t \
I, t!\1llt.,t\ ;txn:{ \t
'ai I t! Erra\\r \l
Vlr a',\4 (.s
lrrl ).-r'
ll \l r(.1.{' 6 rtVrrr-ar\Ury,\:N\.tarrl\
\llll .rt: ita u' '..r'.r raar\:|X,\ttl \tltrri\
:\ !lV \ llU ft\t .i t!.V..x r\.r -,d\ .,r E-..,. i r.Ui od,r t r,., d rr r-., I -.i
Gas, Inc.
9o/o O2|NO2
llrpH
$6rr r7<iJ6 I'rr
^,,, I rr-! 11,.,
Il..l,rr' \r j rr
CE RTI FICATE O F AhIALYSIS
Gra& of Product: EPA PROT(rcOL STANDARI)
Prf t{tre
C)aofir NumD..
tSorrtay
PGVPT\aune
C'.t Codc
E03r{6* t 5Wm?0
cc!o6322
lza .Drrtsn (SAP) , HC
8,7,021
N@ O? a&H
R.b.fica ia.rrbo,
Cylrxlr Vdvmc
CytrOr Ptl+lrn
V.|v, O\.r0ol
C.rt,Ldff Dlr
t22.aol13{t9r7 I
r.3 3 CF
20't3 PsrG
660
SGg I 7 202a
@)l !n)l rq In .* Fa.. [X hli, t&ai .. d ry re b ,qE Elc. lE :il,t - .td 8a.{-t. *l l-- - a rr&i.Er,, *t 7b .rt qrr d rga6 r.i arbr h,r r.E,**, Ev. a G.d,-^.r r..
@- --,.* .a-, rl rr. *A r-a,A t. h la H- ?E.?@ B€ b q&d.'t. V {t., *ra, ts a{arr :r'
OI.
fr r @e -a ll^',rldl hcdts b- dcrbs dtuE C@
ttl- Oaa Av-lda t Fi f.q.,..a
lb.maiL
Ao9?or.d rd R.L...
.brrl:.-EatA
tlrlrl
Caatloarrl
.,L\AI,ITICAL ru)suI,TSt.qtrr.a &nd tEEoa toaal.Lr.Grtc.ol,do.r Concanlrdlqt t(,ra thcrfaail,Aaa?o-
rar96ttc>a{Of IOOiPPM e! ,sPrtl ar . 'l\N5r',.d ,)]:r.!i{ }]llIJra()ry(It r0(,: \ ,.Ju - . r:a\\rs"'-d iJr.{rrt.\r
|. recx,f I Nuo
C.{t. I B RAT lo.r- SiT.{JL lrAl txif[' Ldl D Crlrxtr rao Corrrlrto'r t,nc-r.5t, trt rdf,r lb.
Elr C:' lqlr{, ! t).(ta! !\l{xl2Q.'ain r{-J4 r?rt
i]I) . q{r u rl{xa fa o.or cl }a !x(,xl )alt !0 t'lar rJ tr<)Q li OOrOt 1,.
r.) 6a ppu.a :E-x{ li oror()( ^.a{95r\()frdl.h.ILtx;lra
(LS !5}{XUrJ.r{lr (.arD.a
L)! $raa
u- 0l lcl,ttr I ! lu.'a
A{':r I.Ir'f
w ti f.titx:L, !rft(n I I'1L
ln * XIU aq!:,U,'ft&-. r.rrt d-.UEh*6d.hr-rrdarldolrt ra.-
fr.rn r.tuladloa.a
,Lt At-tTtcAt- E QU I Plt LYT
A^#c, Attprr L-t lrn .a.ra C.{Hroo
l.s , rl'l t(.)i i'r i! ti.Ll
3-6C,ffiral ut?go{'
,.Q J.0 ! 2 2r?a
3- I}. 20Ja
Gas, lnc.
AIrgas
F A, L4d cswr)
Ethylene Only
AlrFs Spccidty Gre
Airf,rs USA LLC
12722 s. wentslrth Ave.
Ori68o, lL 6{r62aAiF.(u
CERTIFICATE OF AI{ALYSIS
Grade of Product: PRIMARY STAIYDARD
GREAT PLAINS ANALYTICAL SERVICE.Cuslomer:
Part Number:
Cylinder Number:
Laboratory:
Analysis Dat6:
Lot Numb€r:
x02Nt99P1sACVH8
cc325720
124 - Chicago (SAP) - lL
Dec01,2022
54.40260346&1
Erplratlon Dete: Dec 01,2025
Roference Number: 54-402603460-1
Cylinder Volume: 144.0 CF
Cylindor Pressure: 2015 PSIG
Valve Out€t: 35O
Primary Standard C,as Mixtures are traceable to N.I.S.T. weighB and/or N.I.S.T. Gas Mixtrre reference maErials.
Component
ANALYTICAL RESI.'LTS
Reg Conc Actual Concentratlon
(moh%)
Analytlcal
Uncertainty
ETHYLENE
NITROGEN
100.0 PPM
Balanca
'r00.0 PPM +h 1Yo
Approved for Roloato P.g l ott
Gas, lnc.
llrpm
BIP
firtr. rt-iart {;-.!c.. t \\ tlr
6..' I t{d ltF.
'Jl:,"::t' '- "
CERTIFICATE OF BATCH ANALYSIS
Grede of Pr.oduct: CEM-CAL ZERO
Prl t{r,rrot
Cra.rd.. Aalyrad
L.D?BYAnCnr Oalc
Nt CzrX)
APROr{CS6Ct92sA
t2a . hrh'n iSAP) . NC
Fcb 22. 20?.
RC''.EOHt,nO., !22{02tml8&r
Cy'rrdcr Vcturr I)a 0 CF
Cylrr6ct Prr*rlr eAaO PSIGvd€ Ov0Gl 540
Csrrgo.r.rl
AI{ALYTICAL R,ESULTS
f.ql.radhrf,duCoc.al,rbo
NrfftOG€N ee 9,e$ t
tlOr
so2
rHc
CARSOil MOirOxlO€
cARm{oroxro€
0 r PPlt0rPPH
O t PPIJ|
O5PPil
't 0 PPH
.LOt
<LDL
<I,DL
9e 906.[
O@ PPU
O 07 PPU
OB PPU
OTPPU
o r PPlt
hnanorf taar:>r cc6a?r l'rl lho coEtr ol |frr cy'rt! tral fr. rrqurrt .a r o{ aO CtRtt)
CrhahLtsh.
rga}a.v .og!o 566,t]rY APkollcsca€2gga coltaao lro2$}0 rLr.te rL t9 rorua,{lm2{l t t ,m tC ller2oa l9e IO rl lVl,8lCS193Y
IrIlnDa ffftod .ort n)y'ol rt rOrdr ?E&. b talsl Dy 69rr Jrd,s r^tta.
ArlFdtoRrloro lr,rJr
Gas, lnc.
IIIgH
21o/o 02
Ltrrr t;rl.rlt l.€.
l,trrt\\l:.
',j', \ah lrl,Fl,,rl 1..r. X
l,r.! I I il,' I
U, !' 'a
CE,RTI I{CATE O }' AIYALYSIS
Gradc of Pnoduct: EPA PROTOCOLSTANDARI)
PlrNurto. Eo2t{lHl5AOOB!
Cyrochrl{umDor CC4O6tra0lSorrldy 'lza - To6lG 19Py . uI
PGVP ltua'ba gl?0zl
Crr Cde OA EAtN
Rolacrrc ilrnba I 53.aOJ0lE92'l . !
Cykxhr VcAnc ta6 0 CF
Cykxhr Pic,t6rrt 2015 PSIG
Valvc Ouicl 5q)
C.rlrtc.t,qr Dic fu, 15 ?02f
It)a '.!lrt ,qlt-.-44..nE ht&ahtni-ds ffi tsrAr1dac.. lt.re -.r&a@,^#r-*l-r- ai.rb.E,r$\ rbaa{q,Ed..<rtdarr.iftlh,-irta.p*i-Vr I *rrl'b..r,..
ai|ll^a i{,a.a-- il tk -'o.Et,rl t' h la Hl lk trg, 8v E ry&d.it. \. -w ryrr., h a{ar, i,
OI.
hlrrtfr n Effi. 6 lt^'!}gtr ,tGd b bn d AtaD d bEu Cr b'tr nl, ltdlta
blnh.CEhrtrr- .0:
t.ld O.r. Arald. t ?€a R.qrr-a
,go,a'.. ld R.L...bt, lJl
Co.wo.ril fu{lr.a.dCcElrtalSn
.{:! ALlTtcAl- RDst' l.Ts
Actd hoaocolCdrcarEflqi lor.ra loaa Li{r
Uncaafal.lr
Ax?Otrr
OrYCf \ ;r'I \
|.:*{x,t .i 6*rr r
(.! l\ l{sl ',^.- I r9L.,.
c.{l-l B lLA't' loN !fl '.,L\ l).rt lxr
lfr Lal O Cfana., t.c Ctiorn.da.i flra-td.lr, Err..iia,r OaX
hrE {rulal U-.lrau l,l 5J a OIY(*-bUIR(Xi[}r C a\L- I I :O.5
Irfn,trdJlrf .,Ioad
AN Al.tTlCAl- [:QU I P]t ]:Yt
rartdca ttrcla.t-t LF.r C.lbll5.r
li-. l*4.6 r) tl\lIrLr| ()l Ol F..tDrljt Ao i'] ix.Ua
Gas, lnc.
Gas
Great Plelns Anal5dcal Servles
303 w 3d st
Elk City, OK 73544
(580)225-0403 Fax: (5AO)225 -2612
CERTIFICATE OF ANALYSE
Gnde of Product CERTIFIED STANDARIIPROBE
Part Number:
Laboratory:
Analysis Date:
LOT Number:
SN:
201
GAS INC.
3t3t2022
A
22^.20L
Reference 22
Number:
Stack Diameter'. 20'
Target Flow 3Umin
Rate:
Numberof 3
Points:
Product performance verified by direct comparison to calibration standards traceable to N.I.S.T.
rThe probe listed on this form meets the multipoint traverse requirement of EPA Method 7e,
section 8.4 as shown in the accompanying data. Method 7e, section 8.4 states that the multipoint
traverse requiremenl can be satisfied by sampling via "a multi-hole probe designed to sample at
the prescribed points with a flow +/- l0 percent of mean flow rate".
ANALYTICAL RESULTS
Tot.l Flow
lVml
Mcesurcd Flor llcrured How Mcerurcd Flow Mern Probc
Port A (Vml Port B (Vml Port C lvml Port Srmpl€d
lDolte all lDclte o2l lDclte oll F-lo* tl -/mI
Rul
Run :
] LPM
4 LPM
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rCalibration conducted in accordance with Emission Measurement Ccnter Guidcline Document - EMC GIXl3l
3/312022
Date
Notes:
Approved for Release
UNIIED STATTS ETTVIRONMENTAL PROTECTION AGENCY
ili'iEAtir_Fr 'IllAtJ(]LE r AIrK tia :'7711
if
March 15,2021
.1 it
Mr. Jordan Williamson
CEO
GAS [nc.
303 W. 3ra Street
Elk City, OK73644
Dear Mr. Williarnson:
We are writing in response to your letter received on September 17.2020, in which you request the approval
of alternative testing procedures. The EPA's Oflice of Air Quality Planning and Standards (OAQPS) is the
delegated authority tbr consideration of major alternatives to test methods and procedures as set fbrth in 40
CFR parts 60 and 6-l under which your request must be addressed. GAS Inc. is requesting a change to one of
the test methods, ASTM D6348-03. used for conducting performance tests to determine compliance under
40 CFR part 60, Subpart JJJJ - Standards of Pertbrmance for Stationary Spark Ignition Internal Combustion
Engines (Subpart JJJJ) and 40 CFR part 63, Subpart ZZZZ - National Emissions Standards tbr Hazardous
Air Pollutants for Perfbrmance for Stationary Reciprocating Internal Combustion Engines (Subpart ZZZZ).
The change being requested will be used to check detector linearity of the Fourier Transform Infrared (FTIR)
instrumentation used to conduct this method. Specifically, you are requesting that the procedures of section
8.3.3 of Method 320 (40 CFR part 60, Appendix A), another FTIR-based method allowed under Subparts
JJJJ and ZZZZ, be used in lieu of section 46.4.1 of ASTM D6348-03 when conducting testing using ASTM
D6348-03 under 40 CFR part 60, Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ.
In your request, you state that this alternative linearity check procedure will produce consistent results when
utilizing either Method 320 or ASTM D6348-03. Additionally, some FTIR instrumentation does not allow
fbr reducing the size of the aperture in the instrument and, thus, it would not be feasible to properly conduct
the entirety of the ASTM D6348-03 method in its current form using such an instrument.
Based on our understanding of FTIR instrument principles and recognition that the requested alternative
detennination of detector linearity is both technically sound and contained within Method 320, we are
approving the requested change. We believe that this altemative is acceptable for use for use in testing all
engines subiect to 40 CFR part 60 Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. Also, we will post this
letter as ALT-l4l on EPA's website (at rnnr'.epa.gor/emc/broadly-applicable-approved-altentatire-
lestmethods) to announce that our approval of this alternative test method is broadly applicable to engines lbr
the purposes of meeting Subparts JJJJ and ZZZZ.
a't
ndUzr'.\l(4I
If you should have any questions or require further infonnation regarding this approval, please contact David
Nash of my staffat 919-541-9425 or email at nash.da'r,e@epa.got'.
Sincerely,
STEFFAN Dldtally slgrEd by
STEFFAN ntI\fsof.l
JoHNsoN Hir$iJ'
Steffan M. Johnson, Group Leader
Measurement Technology Group
Sara Ayers, EPA/OECA/OCi\{AMPD, (ayres. sara@ epa. gov)
Melanie King, EPA/OAR/OAQPS/SPPD, (king. melanie@epa. gov)
James Leather, EPA Region 6, (leatherjames@epa.gov)
David Nash, EPA/OAR/OAQPS/AQAD, (nash.dave@epa.gov)
Lewis Shirley
GAS, lnc.
580-225-0403
info@gasinc.us
Type of Sources Tested:
Stationary lnternal Combustion Engines. 4 Stroke Flich Burn Engines. 2 Stroke & 4 Stroke Lean Burn Engines
Stationary Natural Gas Fired Generators
Stationary Propane Fired Generators
Gas Fired Boilers
Types of Analyzers:. Gasmet DX4000 FTIR. Gasmet Portable Sampling Unit with Zirconium Oxide 02 Sensory. Testo 350. Flame lonization Detector
Qualifications:
Trained, studied, and fully demonstrates compliance for emissions testing via data collection outlined in the
following Reference Methods:. EPA Method 1 & 1A - Sampling & Traverse Points. EPA Method 2 &2C - Velocity & Volumetric Flow Bate of a Gas Stream. EPA Method 3A - Oxygen. EPA Method 7E - NOX. EPA Method 10 - Carbon Monoxide. EPA Method 25A - Volatile Organic Compounds. ASTM D6348 - Extractive Fourier Transform lnfrared Spectroscopy
Conducts emissions testing on a weekly basis including, but not limited to, the following test types: lnitial
Compliance, BiennialCompliance, SemiannualCompliance & Quarterly Compliance. Alltests performed
are in accordance to any and all Federal & State requirements as applicable (i.e. JJJJ,7777, 106.51 2, 117,
PEA, etc.). Performed testing in Colorado, Utah, Wyoming, North Dakota, Montana, Kansas, New Mexico,
Oklahoma, Texas, Louisiana (land and off-shore), Arkansas, Ohio, Pennsylvania, West Virginia, New York,
Kentucky, & Mississippi.
. Quarterly Performance Reviews covering ongoing changes with Federal Regulations, State
Compliance guidelines, & site-specific safety certifications.
Gas, lnc.
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40 CFR Part 60 Subpart JJJJ
Performance Test Report
Test Type: Annual
Test Date: 1OnnO24
Source:
Waukesha 9394 GSI
Rich Burn (4 Cycle)
Unit Number: 1283
Serial Number: 1469776
Engine Hours:27123
D[t,AtI rM[N I
ENVIHONMEN IAL
Nf)V -5 |
rx.----_--t
Location:
Duchesne Data Center Power Station
Duchesne County, Utah
Prepared on Behall of:
Crusoe Energy Systems, !nc.
+As.
303 W. 3rd St (580) 225-0403 Elk City , OK73644
lndex
1.0 Key Personnel....
2.0 Sampling System.....
3.0 Methods Used.... .
4.0 Test Summaries..
5.0 Run Summaries..
6.0 Volumetric Flow Rate Data....
7.0 Calculations.............
8.0 Oxygen Calibration...
9.0 Engine Parameter Data Sheet..
10.0 QA/QC Results........
1 1.0 D6348 Annexes......
12.0 Signature Page.......
1 3.0 Appendices..............
14.0 Bottle Certs......... .
15.0 Tri Probe Certification via GD-031
16.0 GAS ALT 141-FTIR EPA........
1 7.0 Tester Qualifications (resume)...
'18.0 Raw Data............
i"Ol;;
Appendices
Certifi ed Calibration Bottle Certift cates...........
TriProbe Certification via GD-031
GAS ALT 141_FTIR EPA.............
Tester Qualifications (resume)...
Raw Data....
Table 5.1 (Run Summaries)........... ............. 6
Table 6.'f (Volumetric Flow Rate Data)........... ................ 7
Table 6.2 (Stack Gas Measurements)....... ......................7
Table 8.1 (Oxygen Calibration). .................. 9
Annex Table 1.2.1 (Certified Calibration Boftle Concentrations)......... 12
Annex Table 1.2.2 (Measurement System Capabilities)..................... 12
Annex Table 1.3.1 (Test Specific Target Analytes)............................. 13
Annex Table 4.1 (Measure System Capabilities) ......,..... 15
Figures
Figure 6.1 (Location of Traverse Points per Method 1). . . ...... ... . .. 7
Annex Figure 1.4.1 (Sampling Train).... ...... 13
Annex Figure 1.4.2 (Sampling Points).. ....... 14
Annex Figure 1.4.3 (Sampling Port Locations)... ............. 14
3
3
3
5
6
7
I
9
10
11
'12
18
19
20
25
26
28
29
20
25
27
28
29
3
1.0 Key Personnel
GAS, lnc.
Crusoe Energy Systems, lnc.
Lewis Shirley
Alex Nelson
2.0 Sampling System
The sampling system used consisted of a Stainless steel probe, heated Teflon line, gas conditioning
system, and a Gasmet model DX4000 FTIR analyzer. The gas conditioning system used was a Gasmet
Personal Sampling System with a Zirconium Oxide oxygen sensor.
3.0 Methods Used
ASTM D6348.03
This extractive FTIR based field test method is used to quantify gas phase concentrations of multiple target
analytes (CO, NOX, CH2O, & VOC's)from stationary source effluent. Because an FTIR analyzer is
potentially capable of analyzing hundreds of compounds, this test method is not analyte or source specific.
The analytes, detection levels, and data quality objectives are expected to change for any particular testing
situation. lt is the responsibility of the tester to define the target analytes, the associated detection limits for
those analytes in the particular source etfluent, and the required data quality objectives for each specific
test program. Provisions are included in this test method that require the tester to determine critical
sampling system and instrument operational parameters, and for the conduct ol QA/QC procedures.
Testers following this test method will generate data that will allow an independent observer to verity the
valid collection, identification, and quantification of the subject target analytes.
EPA Method 1 & 1A
The purpose of the method is to provide guidance for the selection of sampling ports and traverse points at
which sampling for air pollutants will be performed pursuant to regulations set forth in this part.
EPAMethod2&2C
This method is applicable for the determination of the average velocity and the volumetric flow rate of a gas
stream. The average gas velocity in a stack is determined from the gas density and from measurement of
the average velocity head with a standard pitot tube. Velocity readings are taken from each stack at 16
separate traverse points (Table 6.1) and used to determine the engines mass emissions rate, calculated
utilizing the formulas seen in section 7.O ol this report.
EPA Method 3A
This is a procedure for measuring oxygen (O2) and carbon dioxide (CO2) in stationary source emissions
using a continuous instrumental analyzer. Quality assurance and quality control requirements are included
to assure that the tester collects data of known quality. Documentation to these specific requirements for
equipment, supplies, sample collection and analysis, calculations, and data analysis will be included.
Gas, lnc.
4.0 Test Summary
Unit 1283 with a serial number of 1469776 which is a Waukesha 9394 GSI engine located at Duchesne
Data Center Power Station and operated by Crusoe Energy Systems, lnc. was tested for emissions of:
Carbon Monoxide, Oxides of Nitrogen, and Volatile Organic Compounds. The test was conducted on
101712024 by Lewis Shirley with Great Plains Analytical Services, lnc. All quality assurance and quality
control tests were within acceptable tolerances.
The engine is a natural gas fired Rich Burn (4 Cycle) engine rated at 2500 brake horse power (BHP) at
1200 RPM. The engine was operating at2200 BHP and 1199 RPM which is 88.00% of maximum engine
load during the test. The test HP calculation can be found on page 8. The engine was running at the
maximum load available at the test site.
This test will satisfy the testing requirements for 40 CFR Part 60 Subpaft JJJJ.
Site Verification Photos
Gas. lnc.
4.0 Test
Gas, lnc.
5.0 Run Summaries
Table 5.1 Run Summaries
Gas, lnc.
Table 6.1. Data used for volumetric flow rate (Method 2)
Pltot Iube (;oenlctenl (.;OISldl= .1,9
Stack diameter = 24 rncnes or:'eel. or:3.14 Sauare Feet
H20 o/od 17.39 17.77 17.81 17.66
co2 "/od 9.59 9.72 9.73 9.68
02 o/od o.25 0.14 0.29 0.23
CO oDmo 32.45 34.54 30.89 32.63
Molecular Weight Stack Gas dry basis (Md)q/q mole 29.55 29.56 29.57 29.56
Molecular Weiqht Stack Gas wet basis (Ms)o/o mole 27.54 27.5'l 27.51 27.52
Stack Static Pressure (Pq)"H20 u.3c 0.59 0.64 0.54
Stack Static Pressure (Pq)"Ho 0.03 0.04 0.05 0.04
Atmosoheric Pressure at Location (Pbar)MBAR 832.1 5 832.68 832.00 832.28
Atmosoheric Pressure at Location (Pbar)"Hq 24.58 24.59 24.57 24.58
Absolute Stack Pressure (Ps)"Hg 24.61 24.U 24.62 24.62
stack lemperalure Deq U 447.74 496.15 497.81 493.90
Slack Temoerature Deq F 909.94 925.06 928.06 921 .O2
Slack Temo€rature Deo R 1369.61 1384.73 1387.73 1380.69
Slack Gas Velocity fvsec 75.56 92.63 95.87 88.78
Stack Flow Bate Q cls 237.39 291.01 304.32 278.92
Stack Gas Wet Vohetnc Flow Hate scl/hr 270957.61 328931.97 343013.90 3't 5991 .1 4
Stack Gas Dry Volumetnc Flow Flate scl/hr 22828.68 z/o4tj9.'24 281925.55 260191 .32
missions Samolino Points - 3 ooint lono line samDlinq orob€lnches
First Samolino Point aken @ 1 7% of Stack Diameter 4.01
Second Samolino Point Taken @ 50"/" of Sta(rk Diameter 12
Third Samplinq Point Taken @ 83.3olo ol Slack Diameter 19.99
6.0 Volumetric Flow Rate Data
Table 6.2. Stack gas pressure measured with a standard tube use Flow Rate
Aostd = Velocitv head measured bv the' standard pitot tube, (in.) H2o.'
Samote aner EacK Huroe.u.bb
Within 5olo ol Last Aostd readino:YES
Flgure 6.1
16 Traverse Points Were UsedStack Diameter (inches)24.OO
lnches upstream from disturbance 6.00
lnches downstream from disturbance 24.O/J
Pitot readings are taken for Method 2 calculations using measuring points outlined in Method
'The exhaust stack dld not prosont cyclonlc flow condltlons at the sampllng locatlon duo to tho
absence of cyclones, lnertlal demlsters, venturl scrubbers, or tangentlal lnlets.
ir
ir'e
96 6'.
un F.un 2 un
aoatd flnt H2 I [emo l aDstd flnt H2(, Exnausl IemD I apsro (rn) ti auSt TemD f
Pitot Tube Samolino Points (Velocitv)
1 o.46 vt I .tx,u.b/926.OO 0.78 929.00
2 0.30 909.fi)U.9U 924.00 0.83 927.OO
3 o.17 910.0O o.42 925.00 o.49 928.O0
4 o.28 910.00 u.5u 924.00 0.94 928.00
5 0.33 91 1.00 0.50 926.00 1.18 928.O0
6 0.38 91 l.OO o.40 925.OO o.7a 929.OO
7 o.51 909.0O o.21 YZ4.tJt)o.32 929.OO
I 0.63 909.(x)0.or 926.00 o.M 92t.OO
I 0.33 910.00 12 926.00 U.Z}4 928.OO
10 o.4E 909.0O o.E9 925.00 o.77 929.00
11 0.39 911.OO o.43 925.00 0.56 928.00
12 0.30 909.00 0.60 9Z4.UU 0.48 929.00
13 0.27 909.00 0.54 926.00 0.39 927.0O
14 0.40 911.00 0.39 924.00 0.68 92t.OO
15 0.26 910.00 o.62 926.O0 o.49 92E.OO
l6 o.a2 910.OO o.58 9Z5.UU o.66 92E.OO
AOSIO Avefaoe=o.39 909.94 o.59 925.06 o.64 92E.06
Gas, lnc.
I
7.0 Calculations
Method 2: Determination of Stack Gas Velocity and Volumetric Flow Rate
.Note- Use of this method neqates the need for anv fuel related numbers for emissions calculations
Ap(avg) = Velocity head of stack gas, mm H2O (in. H2O).
3600 = Conversion Factor, sec/hr.
A = Cross-seclional area of stack, m2 (ft2).
Bws = Waler vapor in the gas stream (from ASTM D6348)
Cp(std) = Standard pitot tube coetticient; use 0.99
Kp = Velocity equation constant.
Md = Molecular weight of stack gas, dry basis, g/g-mole (lb./lb.-mole).
Ms = Molecular weight of stack gas, wet basis, g/g-mole (lb./lb. -mole).
Ps = Absolute stack pressure (Pbar+ Pg), mm Hg (in Hg)
Pstd = Standard absolute pressure, 760 mm Hg (29.92 in. Hg).
Osd = Dry volumetric stack gas tlow rate corrected to
standard conditions, dscm/hr. (dscfftr.).
Ts(abs) = Absolute stack temperature, "K ('R). = 460 + Ts for
English units.
Tstd = Standard absolute temperature, 293"K (528 'R).
Vs = Average stack gas velocity, m/sec (ft./sec).
M d = . 44 ( o,{,C O 2l + .32 (ohO 2\ + .28 ( o;i, N2 +o/.C O )Md = .44(.096)+.32(.003)+.28(.898+.0o3) = 29.546 LB/LB-MOLE
Ms = Md(1 -Bws)+18.0(Bws)Ms = 29.546(1 - 17394)+.18.0(.17394) = 27.538 LB/IB-MOLE
vs = Kp'cp(std)'y'apavg'V(Ts(abs)/( Ps'Ms))vs = 85.49'.gg'y'ss'y'1 r eos.ooT st i.24.61' 27.s38)) = 75.56 FT/SEC
Qsd = 3600(1-Bws)Vs'A((Tstd'Ps)/(Ts(abs)'Pstd))(Jso = Jour(r-.r /41lJ.)uj J.r4z((Jzu zc.orr/ (rJov.ou/5'"9.!,2)) = zzJ616.o5
DSCF/HB
O = Osd/35.315 O =223828.648/35.315 = 6338.062 DSCM/FIR
Emission Rates (Examples use CO Run 1)
453.6= Conversion factor lb. to gram HP= Engines rated Horsepower
A = Cross-sectional area of stack, m2 (ft21. Mfg.= y3nul"clurer Exhaust flow rate at 100% (ft3/min)
BHP/HR. = Brake work of the engine, horsepower-hour (HP-HB.). 02 = Concentralion of oxygen on a dry basis, percent.
BTU/HP-HR. = Brake Specilic Fuel Consumption (HHV) ppm= Parts Per Million (CO)
EB = Emisslon rate ol (CO) in g/HP-hr. ppm@l5ol" 02= PPM corrected to 15% 02
F(d )= Vglurngs ol combustion components per unit ol heat Qsd = DU volumetric stack gas llow rate corrected
conlent, scm/J (scf/million Btu). to standard conditions, dscm/hr. (DSCF/HH.).
O = Stack gas volumetric flow rate, in standard cubic meters Run Time = Bun Time in Minutes
per hour, dry basis Tpy= Tons per year
LB/HR.= Emission rate ol (Co) in LB/HB. Vs = Average stack gas velocity, m/sec (ft./sec).
Mol wl.= MolWeight of CO (28.01)
ppm @ 15% 02 = PPM'((20.9-15'/"O2X20.9-O2))ppm @ 15"/" 02=39.288'(.20.9-15y(20.9-.3o/oll=11.252 PPM @ 15o/"02
g/hp-hr = (PPM' ( t . 1 64' 1 0L3)'Q' (Bun Time/60))rBHPrtlR (39.288'( 1 . 1 64' 1 0^-3)'6338.062'(Run Time/60)) l22OO = . 1 32 G/HP-HR
lbft r = ER' 1 /453.6'BHP-HFl LB/HR = .132'11453.6'2200 = .639 LB/HR
TPY = LB/HR. '4.38 TPY = .639'4.38 = 2.799 TPY
HP Provided On Site
ppm wet'(1(1-H2O) = ppm dry 39.29 = 32.4s45'( 1(1 -. 1 7))
Gas,lnc.
8.0 Oxygen Callbratlon I
8.'l Calibration error test; how do I conflrm my analyzer calibration is correct? After the tester has assembled. prepared and calibrated the
sampling system and analyzer. they conduct a 3-point analyzer calibration error test before the first run and again after any failed system bias test or
farled drifi test. They then rntroduce the low-. mid-. and high-level calibration gases sequentially in direct calibration mode. At each calibration gas level
(low. mid, and high) the calibration error must be within t 2.0 percent of the calibration span
8.2 lnltial system blas and system calibration error checks. Before sampling begins. it is determined whether the high- level or mid-level
calibration gas best approximates the emrssions and it is used as the upscale gas. The upscale gas rs introduced at the probe upstream of all sample-
conditioning components in system calibration mode
(1 ) Next, zero gas is introduced as described above. The response must be within 0.5 percent of the upscale gas concentration.
(2) Low-level gas reading is observed until it has reached a final, stable value and the results are recorded. The measurement system will be
operated at the normal sampling rate during all system bias checks.
(3) lf the initial system bias specification is not met. corrective action is taken. The applcable calibration error test from Section 8.2.3 of EPA
Method 7E is repeated along with the initial system bias check until acceptable results are achieved. after which sampling will begin. The pre-
and post-run system bras must be within t 5.0 percent of the calibration span for the low-level and upscale calibratron gases.
8.3 Post-run system bias check and drift assessment - confirming that sach samplo collected is valid. Sampling may be performed for multiple
runs before performing the poslrun bias or system calibration error check provided this test is passed at the conclusion of the group of runs. A failed
final test in this case will invalidate all runs subsequent to the last passed test.
(1) lf the post-run system bias check is not passed, then the run is invalid. The problem is then diagnosed and fixed. then another calibration
error test and system bias is passed before repeating the run.
(2) After each run, the low-level and upscale drift is calculated, using Equation 7E4 in Section l2 5 from EPA Method 7E. lf the post-run low-
and upscale bias checks are passed. but the low-or upscale drifl exceeds the specrfication in Section 13.3. the run data are valid. but a 3-point
calibration error test and a system bias check must be performed and passed prior to additional testing
Table 8.1 Oxygen Calibration
Method 7E 3.4 To the extent practicable, the measured emissrons should be between
20 to 100 percent of the selected calibration span. This may not be practicable in some
cases of low concentration measurements or testing for compliance with an emission
limit when emissions are substantially less than the limit.
EPA Method 3A OA Worksheet
Certificd Ger Concentrelon I Ccrtlfied Gs3 Co.rc.ntreion I Certlfied Gar CoLow.Lcwl (ti) I rrld.L v.l (96! | Xbh-Lcvt
"*",
nGentrdon
7E 8.5: Note: that you may
risk sampling for multiple
runs before performing the
post-run bias provided you
pass this test at the
conclusion of the group of
runs
(OIRECT) Analytor Calibratlon Error (5 2%)
Linearity Check
Certified
Concentration
Value (7o)
Dir.clCrlibration
R6lpon3o (9
Absolute An!lfzor
CalibrationEror (%)
Zero Gas o/o 0.00%0.00% 0.00%0.00%
Mid-Level Gas %
High-Level Gas %
't0.620/0
21.12/.
10.82o/o
21.38v.
0.20%
0.260/"
0.93%
1.23o/o
(SYSTEtr) Calibratlon Bla3 Check! (S 5%! and Orift Checks (s 3%)Upsclle Gr3 10.62%
Zero Offs€t 0.00%
Bi!3 Pre lnitial Value Bias Poet lnital ValuecSpan 21.12
AnElyzer
Calibration
Response (o/o)
Zero Gas 0.0oo/o
Sy3tem
Calibrati:ns
Responre Pre
(%)
iystem Birc (91
of Spen) Pre
Syetemtulibr.tirn
Response Post
lY.l
Sysbrn Bb3 (9(
of Sg!n) Port Drill (7o of
Spen)
0.00%0 00%0.00%0.00%0.00'/"
Upscale Gas 10.820/.1 1.000/"0.870/.10.92%0.49%0.000/.
(SYSTEM) Calibration Bias Checks (S 5%) and Drift Check3 (J 3%)
Avo. Gas Concsnfrtion (Run 1 0.30% Eflluant Gas (CE 3) Run 1 O.E9o
Avg. Gas Coneenbation (Run 2)0.179o Eflluent Gas (Cgor) Run 2 0.16%
Avg. Gs Concantsation (Run 3)0.357o Effiuent Gas (Cgas) Run 3 o.u%
EPA lJlethod 34 QA Worksheet
Zero Gas 100o/o Nitrogen
Mid-Level Gas 10.620/.
High-Level Gas 21.12./"
Zero Gas o/u
Mid-Level Gas %
High-Level Gas o/o
Gas, lnc.
company urusoe Enerqv SYSrems, rnc.
Faclllty Duchesne Data Cenler Power Station
Date 10nDo24
Slte Elevetion (n)1776.10
Unlt lD 1 283
Make Waukesha
MOdEI 9394 GSr
Serlal Number 1469776
Technaclen Lewis Shirley
9.0 Engine Parameter Data Sheet
AS
Completed
Gas, lnc.
Run Start Tlmes 07:57 AM 09:23 AM 1O:50 AM 12:21 PM
Englne Hours 27120 27121 27122 27123
11
10.0 OA/OC Results
System Zero Response Time
System Response Time
83 seconds
83 seconds
Carbon monoxide CO
Nitrogen monoxide NO
Nitrogen dioxide N02
NOx
voc
Oxygen
Average:0.13
Average:0.00
Average:0.68
Average:0.68
Average:0.42
Average:0.12
CTS Bottle Concentration
CTS Compound Concentration Avg
Tolerance
Difference between measured and expected
Value: 100.30
Value:98.59
2.OO/"
1.71"/"
Nitrogen monoxide NO
Nitrogen dioxide NO2
NOx
voc
Oxygen
Average:0.15
Average:0.00
Average:0.23
Average:0.23
Average:0.14
Average:0.09
Mechanical Response Time
CTS Bottle Concentration
CTS Compound Concentration Avg
Tolerance
Difference between measured and expected
Value: 100.30
Value: 102.41
5.00o/"
2.10"/"
Equilibration Response Time
Spike Reported
Spike Expected
Value:249.85
Value:252.40
Gas, lnc.
12
11.0 D6348 Annexes 1-8
The test quality objectives completed for the emissions test are demonstrated throughout Annexes 1,2,3,
4, 5, 6, 7 & 8 as layed out per ASTM D6348-03. All reference methods, pre-tesl and post test procedures
were within acceptable limits. Data generated during the pre-test and post-test procedures are
summarized below in order of the distinctive Annex.
Three 60 minute test runs were performed. The final analyte concentralions are the average of each test
run. Data was taken at 60 second intervals. Each 60 second measurement was the average of 600 scans.
Propane rs used as the surrogate compound for the Annex 5 Spiking Technique due to Propane being the
VOC that is most commonly found in the combustion process of natural gas. Additionally, the molecular
weight of Propane coincides with with molecular weight of VOC's per the EPA.
Annex Table 1.2.1 Certified Calibration Bottle Concentrations
1.2
Bottle Expiration N()2 Ethylene SF6 o2l"h)
cc506322 9t17t2027 99.95 10.62"'o
121t2025 100.30
cc406148 4t15t2032 21 .129/"
Cylinder # ALM-063647 Expiration: 5-03-2032
Propane CO NO SF6
Elottle Value 252.40 501 70 z3 / .51)10.20
Analvzer Svstem l-{esponse 249.85 487.75 235.46 10 30
Percent Difference I.01"/o 2.78,,"0.86",/o 0.990./o
Annex Table 1.2.2 Measurement System Capabilities
Paramelel
Measured Gas uoncentralron(oom)Path Length Equlllorallon
Time Dilution Factor 7o Recovery
Path Lenqth Ethvlene 98.589 4.915
Spike Direcl
Propane 249.871
SF6 10.367
L,;U +9v.t'JU
NO zsb.z13
Mechanical
Besponse Time Ethylene 102.409 8 seconds
Analyzer
Response
Propane 249.848
'10 secondsSF610.301
(rO 46t /51
NO 235.4b2
Analyte Spike
Recovery Propane & SF6
O.169/"0.00"/o
7.85"/"90.260/.
7.634/"69. /5Y',o
Svstem Zero Nitrooen 83 seconds
Post Spike
System
Propane zqd.rqv
CO 5U4.JJZ
NO 234./26
SF6 10.222
Gas, lnc.
Annex Table 1.3.1 Test Specific Target Analytes and Data Ouality Objectives
VOCs compiled ol Acetaldehyde, Ethylene, Hexane, and Propane.
Compounds
lnfrared
Analysls Region
(cm-1)
Erpected
Concentration
Range
MeaSurement
System
Achlevable
Mlnimum
Detectableeannenirrlidna
Hequrreo
Measurement
System
Accuracy and
Preclslon for
Tesi Aoollcatlon
CO 2000-2200 O-12)O oom 0.'16267 oom 4 oom
NO 1 875-21 3E o-1u)o ppm u.4uu/ oom 2 ppm
N02 2700-2550 O-1OO Dom 0.4E99 ppm 2oom
VOC
2600-3200
0-100 ppm 1.8520 ppm Total
VOC's 1 ppm per VOC910-1 't50
2550-2950
CH2O 2550-2850 0-100 ppm 0.7678 DOm 1 ppm
lnterlering
Compounds ' CO is analyzed in a separate analysis region than CO2 and H2O
coz 926-1 1 50 0-10"/o Oo/o nla
Waler Vapor 3200-340',t O-22/"o.200/"nla
PSS PROBE{..;=fx't
rQ'
c2
SENSOR L
GASf\if I
FTIR
Flow
lffR.
VENT
Figure Annex 1.4.1 Sampllng Train
The testing instrumentation is housed in an enclosed vehicle which is located approximately 45 feet from the source. A
heated sample line (sixty feet in length) is attached to the inlet of analyzer system and the source effluent discharges
through the FTIR outlet.
eI
l
U
GAS
lf.I
CONTROT
PA\EL
Gas, lnc.
14
TRI-PRO8E SAMPLE POINT LOCATIONS
AS PERCENTAGE OF STACK DIAMETER
Flgure Annex 1.4.2 Sampllng Polnts
lnterior Stack Diameter (inches):
lnches
Upstream:
6
lnches
Downstream:
24
SAT#LE PORT LOCATION OETERMINED
BY DISTAT.ICE FROM DISTURBANCE
Flgure Anner 1.4.3 Sample Port Locatlon
Sampling Polnt Locatlons
in lnches
16.7o/o 4.OO8
50o/o 12.OOO
83.3olo 19.9924
UJtsu,I
o
It
E
Gas, lnc.
Target Analyte Results (ppm)
CO o.1621
NO U.4UUr
NO2 0.489S
EthVlene u.3/42
Propane U.4J5
Hexane U.ZZJ:
Acetaldehvde 0.815i
Formaldehvde 0.787f
trtNlitl,-rlt s l't
nrtLI
i,),
\ ll Z--t I
t' , 1.rv ra"i )
trlR t-'t:,,rl.\
trlD(:ltl
ttl,\' li;l r-rn {,rtt] t: t:,'rtl s
'''' , ( tt t" 0 ",' )'
- L'"'t I'r " l
1., ut!
Calibration Transfer Standard Expected Measured Path Lenqth Validated
Ethvlene 100.3 96.59 4.915 Passed
est
Annex Table 1.2.2 Measurement System Capabilities
Parameter
Measured Gas GOnCentralron
{noml Path Length trqurrDraUon
Time Dilution Faclor o/o Recovery
Path Lenoth Ethylene 98 589 4.915
Spike Direct
Propane 249.871
SF6 10.367
CO 499.830
NO 236.213
Mechanrcal
Besponse Time Ethylene 102.409 B seconds
Analyzer
Flesponse
Propane 249.444
10 secondsSF610.301
CO 487 751
NO 235.462
Analyte Spike
Recovery Propane & SF6
0. 16e,b 0.0096
7.85"k 9U.Zb"ro
7.63"i,89.75"/o
System Zero Nrtroqen 83 seconds
Post Spike
Syslem
Propane 244.540
CO 504.332
NO 234. /26
SF6 10.222
Gas. lnc.
Perameter Gas Concentrataon Measured 96 Difference SDocitlcatlon Valadated
Spike Direct
Propane 252.400 249.471 'I .OOozL +l- 2o/"PASS
SF6 10.200 10.367 1.640k +l- 2/o Pass
CO 501.700 499.830 0.37%+/- 2o/"Pass
NO 237.500 236.213 o.54"h +l- 2o/o Pass
Soilte Run 1 via the Svstem
Source Output Spike Average Dilution Factor Erpected o/o Recovery Speclfication
Propane U.UU1 U.UUU o.404 U.UUU"/o 7O-13O"/o
SF6 U.UUI o 017 o.164%<1Oo/"
Spike Run 2 vla tho Sysiem
Source Output spike Averaqe Ditution Factor Expected 70 ReCOvery specilication
Propane U.UUU 17.883 19.813 90.260"/o 7O'13Oo/"
SF6 U.UUd o.814 l -tl5i1"/o <1 O7o
SDake Run 3 via the System
Source Output Spake Averaqe Dilutaon Factol Exoected o/o Flecovery Speclfication
Propane 0.000 17.285 19.258 89.7500k 70-130n"
SF6 0.009 0.791 7.6300/"<1Oo/"
Noise Equivalent Absorbance (NEA)
RMS High 0.003264
RMS Mid 0.001518
FIMS Low 0.000917
Line
I lre Posltron
pass
Gas, lnc.
0.00o4 Pass
The Gasmet GICCOR (Genzel lnterferometer with Cube Corner Retroreflectors) interferometer is specially
designed for maximum optical throughput and maximum signal to noise ratio of 7.72 (cm-1) remaining
stable with any vibration and temperature changes.
DX4000 is a low resolution spectrometer where the aperture is fixed to a maximum angle
setting and the detector linearity was testeid with an alternate appr6ach. A three point linerarity of thie CTS
gas was perlormed and validated.
Linea rity
3r 9943
22 9943
r 3 9943
4 9943
4 0057
r 3 0057
22 0057
3 r 0057
40 0057695 687 679 672
-.001315582 Pass
The analytical accuracy of the quantification algorithm is satisfied via the results from Annex 5 per Annex
7.6
664 656 648 64 1 633
31 9943
22 9943
1 3 9943
4 9943
4 0057
r 3 0057
22 0057
31 0057
40 0057625 618 610 602
F05TCT5 SvdomGnedcut5 t ome uoncenlralon:100.30
u l5 Sample uoncenlralDn Averaqe:101.77
Ditlerence between measured and exDected:1.45/"
Tolerance:5.OO7o
Hun Odr Ydldilon - Arnarmd lr Erud rutm val5eru qornmm0a
HUn 'l HOTnIS I & Z On Uu/N9/r'ropane All within 20%PASSed Demonstrates no interferences observed.
Run 2 Points 1 & 2 on CO/NO/Prooane All within 20olo Passed Demonstrales no interlerences observed.
Run 3 Poinls 1 & 2 on CONO/Prooane Allwithin 20% Passed Demonstrates no anterlerenoes observed.
Gas, lnc.
18
12.0 Signature Page
Job/File Name: Crusoe Energy Systems, lnc.; Duchesne Data Center Power Station; 1283;JJJJ
We certify that based on review of test data, knowledge of those individuals directly responsible for
conducting this test, we believe the submitted information to be accurate and complete.
Company: G.A.S. lnc.
Print Name: Lewis Shirley
Title: Emissions Specialist
Date:101712024
Company:
Print Name:
Signature:
Title:
Phone Number:
Date:
Company: G.A.S. lnc.
Print Name: Travis Hartley
Title: Director of Stack Testing
Signature:' _-lt)
Phone Number: 580-225-0403
Date: 10n12024
Gas, lnc.
Appendices
r f,rincarifr
Spike (5 Gas)
ItE. SF-t (.n
trr..( lrrtll
l:--': ] rrfr.,rrh \.r
( f,r.t,ll dt,lt
\ 4r" 'm
CE RTI TICATE OT ANALYSIS
Grrdc Of PTOdUCI: IPA PROT(TOL STA:{DARD
Ceic GRI I R.AaSArallVtlCAl -R1rtEP,{ iarnE
Cfa.tr )fr.?$f,
L&er
PovP rutaGr Cod.
EOt arcaE t3acorara.uo!atl?a. O\..eptSlP, tL
8r202aco coz rao tox PPn 8^lx
R.|..re Xo 3a$Irtltrz I
Ctfxt \Dlr. lll O
Crbdrr Asur lO!5
vi. O,I fltO
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Ethylene Only
Alrtu SpGddty CG6
Air6u USA Ll{'
12722 S. l4'enthrrih Air.
Chicato, IL 60628turtr.M
CERTIFICATE OF AIVALYSIS
Grade of Product: PRIMARY STAIYDARI)
GREAT PLAINS ANALYTICAL SERVICE.Cuslomer:
Part Numb€r:
Cylind€r Number
Laboratory:
Analysis Date:
Lot Numb€r:
x02Nl99P1sACVH8
cc325720
124 - Chicago (SAP) - lL
Oec01,2022
54402603460-t
Erplratlon Date: Ilec 01, 2025
ReferenceNumber: 54-40260346G1
Cylinder Volume: 144.0 CF
Cylinder Pressure: 2015 PSIG
Valv€ Ouuet: 350
Primary Standard C:as Mixtures are traceable to N.I.S.T. weights ard/or N.I.S.T. Gas MixtJre referene materials.
Component
ANALYTICAL RESI.'LTS
Req Conc Actual Concentratlon
(xob%)
Analytical
Uncertalnty
ETHYLENE
NITROGEN
1OO,O PPM
Balance
100.0 PPM +l- 1Yo
Approved for Releare P.g. I of I
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Part Number:
Laboratory:
Analysis Date:
LOT Number:
SN:
CERTIFICATE OF ANALYSIS
Gnde of Product CERTIFIED STANDARI>'PROBE
Mersucd Flos Mcrured Fbw Me.ruGd Flor Mern Probe
Pdt A lvml Port B lvm) Port C lVml Pon $mp!€d
(Dclta ofl lDclta o2l lltclte o3l Flow (lJm)
Grcat Plains Aralldcal Scrvlces
303 w 3d st
Elk ciry, oK 73644
(S80)225-0403 Fax: {580)225 -2612
24L
GAS INC.
3t3t2022
A
22^.24L
Reference 22
Number:
Stack Diameter: 24"
Target Flow 3Umin
Rate:
Number of 3
Points:
Product performance verified by direct comparison to calibration standards traceable to N.|.S.T.*The probe listed on this form meets the multipoint traverse requirement of EPA Method 7e,
section 8.4 as shown in the accompanying data. Method 7e, section 8.4 states that the multipoint
traverse requirement can be satislied by sampling via "a multi-hole probe designed to sample at
the prescribed points with a flow +/- l0 percent of mean flow rate".
ANALYTICAL RESULTS
Tot l Flow
lVm)
Rul
Run l
2 LPM
.I LPM
0.71o
It.ma)
I .19
(5.574 r
0.660
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tCalibration conductcd in accordancc u'ith Emission Measurcmcnt Ccntcr Guidelinc Documcnt - EMC GD.03l
31312022
Date
Notes:
Approved for Release
UNITED SIATES ENVIRONMENTAL PROTECTION AGENCY
n['.F ilIi( tr I IilAt.t{-rl E r Atji( ti(_ .,;;1 :
March 15,2021
Mr. Jordan Williamson
CEO
GAS [nc.
303 W. 3La Street
Elk City, OK73644
Dear Mr. Williarnson:
We are writing in response to your letter received on September 17, 2020, in which you request the approval
of alternative testing procedures. The EPA's Office of Air Quality Planning and Standards (OAQPS) is the
delegated authority fbr consideration of major altematives to test methods and procedures as set lbrth in 40
CFR parts 60 and 63 under u,hich your request must be addressed. GAS Inc. is requesting a change to one of
the test methods, ASTM D6348-03. used for conducting perfbrmance tests to determine compliance under
40 CFR part 60, Subpart JJJJ - Standards of Pertbrmance for Stationary Spark Ignition Internal Combustion
Engines (Subpart JJJJ) and 40 CFR part 63, Subpart ZZZZ - National Emissions Standards for Hazardous
Air Pollutants for Performance fbr Stationary Reciprocating Internal Cornbustion Engines (Subpart ZZZZ).
The change being requested will be used to check detector linearity of the Fourier Transform Infrared (FTIR)
instrumentation used to conduct this method. Specifically, you are requesting that the procedures of section
8.3.3 of Method 320 (40 CFR part 60, Appendix A), another FTIR-based method allowed under Subparts
JJJJ and ZZZZ, be used in lieu of section A6.4.1of ASTM D6348-03 when conducting testing using ASTM
D6348-03 under 40 CFR part 60, Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ.
In your request, you state that this alternative linearity check procedure will produce consistent results when
utilizing either Method 320 or ASTM D6348-03. Additionally, some FTIR instrumentation does not allow
fbr reducing the size of the aperture in the instrument and, thus, it w,ould not be feasible to properly conduct
the entirety of the ASTM D6348-03 method in its current form using such an instrument.
Based on our understanding of FTIR instrument principles and recognition that the requested alternative
determination of detector linearity is both technically sound and contained within Method 320, we are
approving the requested change. We believe that this alternative is acceptable for use tbr use in testing all
engines subject to 40 CFR part 60 Subpart JJJJ and 40 CFR part 63. Subpart ZZZZ. Also, we will post this
letter as ALT-l4l on EPA's website (at u'r.rv'.epa.gor/entc/broodly-applicable-approt'ed-qltentatit'e-
testmethods) to announce that otu approval of this altemative test method is broadly applicable to engines tbr
the purposes of rneeting Subparts JJJJ and ZZZZ.
alr,!7rNl(,
If you should have any questions or require further information regarding this approval, please contact David
Nash of my staffat 919-541-9425 or email at nash.date@epa.got,.
Sincerely,
STEFFAN HH^T,?[^1H-
JoHNSON HirffiJ'
Steffan M. Johnson, Group Leader
Measurement Technology Group
Sara Ayers, EPA/OECA/OCA{AMPD, (ayres. sara@epa. gov)
Melanie King, EPA/OAR/OAQPS/SPPD, (king.melanie@epa. gov)
James Leather, EPA Region 6, (leatherjames@epa.gov)
David Nash, EPA/OAR/OAQPS/AQAD, (nash.dave@epa.gov)
Lewis Shirley
GAS, lnc.
580-225-0403
info@gasinc.us
Type of Sources Tested:
Stationary lnternal Combustion Engines. 4 Stroke Rich Burn Engines. 2 Stroke & 4 Stroke Lean Burn Engines
Stationary Natural Gas Fired Generators
Stationary Propane Fired Generators
Gas Fired Boilers
Types of Analyzers:. Gasmet DX4000 FTIR. Gasmet Portable Sampling Unit with Zirconium Oxide 02 Sensory. Testo 350. Flame lonization Detector
Qualifications:
Trained, studied, and fully demonstrates compliance for emissions testing via data collection outlined in the
following Reference Methods:. EPA Method 1 & 1A - Sampling & Traverse Points. EPA Method 2 &2C - Velocity & Volumetric Flow Rate of a Gas Stream. EPA Method 3A - Oxygen. EPA Method 7E - NOX. EPA Method 10 - Carbon Monoxide. EPA Method 25A- Volatile Organic Compounds. ASTM D6348 - Extractive Fourier Transform lnfrared Spectroscopy
Conducts emissions testing on a weekly basis including, but not limited to, the following test types: lnitial
Compliance, BiennialCompliance, SemiannualCompliance & Quarterly Compliance. Alltests performed
are in accordance to any and all Federal & State requirements as applicable (i.e. JJJJ, ZZZ/ 106.512, 1 17,
PEA, etc.). Performed testing in Colorado, Utah, Wyoming, North Dakota, Montana, Kansas, New Mexico,
Oklahoma, Texas, Louisiana (land and off-shore), Arkansas, Ohio, Pennsylvania, West Virginia, New York,
Kentucky, & Mississippi.
. Quarterly Performance Reviews covering ongoing changes with Federal Regulations, State
Compliance guidelines, & site-specific safety certifications.
Gas, lnc.
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/t0 CFR Part 60 Subpart JJJJ
Performance Test Report
Test Type: Annual
Test Date: 1Ugn024
Source:
Waukesha 9394 GSI
Rich Burn (4 Cycle)
Unit Number: 1318
Serial Number: 1632554
Engine Hours: 16230
Locatlon:
Duchesne Data Center Power Station
Duchesne County, Utah
Prepared on Behalf of:
Crusoe Energy Systems, lnc.
+As"
DEPATITMENTJF-
ENVIHONMENIAL QUALITY
NO\/ - 5 2024
DIVISION OF AIB OUALITY
303 W. 3rd St (580) 225-0403 Elk City , OK 73644
Index
1.0 Key Personnel..
2.0 Sampling System.....
3.0 Methods Used..... ..
4.0 Test Summaries.
5.0 Run Summaries..
6.0 Volumetric Flow Rate Data....
7.0 Calculatlons.............
8,0 Oxygen Calibration...
9.0 Engine Parameter Data Sheet..
10.0 QA/QC Results........
1 1.0 D6348 Annexes. ....
12.0 Signature Page.......
'l 3.0 Appendices..............
14.0 Bottle Certs...........
15.0 Tri Probe Certification via GD-031
.I6.0 GAS ALT 141_FTIR EPA........
17.0 Tester Qualifications (resume)...
18.0 Raw Data
Tables
Table 5.1 (Run Summaries).............
Table 6.1 (Volumetnc Flow Rate Data)...........
Table 6.2 (Stack Gas Measurements).......
Table 8.1 (Oxygen Calibration)..
Annex Table 1 .2. 1 (Certified Calibration Bottle Concentrations).........
Annex Table 1 2.2 (Measurement System Capabilities)
Annex Table 1.3.1 (Test Specific Target Analytes).....
Annex Table 4.'l (Measure System Capabilities)
3
3
3
5
6
7
8
9
10
11
12
18
19
20
25
26
28
29
6
7
7
I
12
12
13
15
Figures
Figure 6.1 (Location of Traverse Points per Method 1) . .. . ... 7
Annex Figure'1.4.1 (Sampling Train).... ...... 13
Annex Figure 1.4.2 (Sampling Points).. ....... 14
Annex Figure 1.4.3 (Sampling Port Locations)... ............. 14
Appendices
Certified Calibration Bottle Certificates........... ......... ..... .20
Tri Probe Certification via GD-031 25
GAS ALT 141_FT|R EPA........ .... ............... 27
Tester Qualiflcations (resume)... ................. 2B
Raw Data.... 29
3
1.0 Key Personnel
GAS, lnc.
Crusoe Energy Systems, lnc.
Lewis Shirley
Alex Nelson
2.0 Sampling System
The sampling system used consisted of a Stainless steelprobe, heated Teflon line, gas conditioning
system, and a Gasmet model DX4000 FTIR analyzer. The gas conditioning system used was a Gasmet
Personal Sampling System with a Zirconium Oxide oxygen sensor.
3.0 Methods Used
ASTM D6348-03
This extractive FTIR based field test method is used to quantify gas phase concentrations ol multiple target
analytes (CO, NOX, CH2O, & VOC's)from stationary source effluent. Because an FTIR analyzer is
potentially capable of analyzing hundreds of compounds, this test method is not analyte or source specific.
The analytes, detection levels, and data quality objectives are expected to change for any particular testing
situation. lt is the responsibili$ of the tester to define the target analytes, the associated detection limits for
those analytes in the particular source effluent, and the required data quality objectives for each specific
test program. Provisions are included in this test method that require the tester to determine critical
sampling system and instrument operational parameters, and for the conduct of QA/QC procedures.
Testers following this test method will generate data that will allow an independent observer to verify the
valid collection, identification, and quantification of the subject target analytes.
EPAMethodl&14
The purpose of the method is to provide guidance for the selection of sampling ports and traverse points at
which sampling for air pollutants will be performed pursuant to regulations set forth in this part.
EPAMethod2&2C
This method is applicable for the determination of the average velocity and the volumetric flow rate of a gas
stream. The average gas velocity in a stack is determined from the gas density and from measurement of
the average velocity head with a standard pitot tube. Velocity readings are taken from each stack at 16
separate traverse points (Table 6.1) and used to determine the engines mass emissions rate, calculated
utilizing the formulas seen in section 7.0 of this report.
EPA Method 3A
This is a procedure for measuring oxygen (O2) and carbon dioxide (CO2) in stationary source emissions
using a continuous instrumental analyzer. Quality assurance and quality control requirements are included
to assure that the tester collects data of known quality. Documentation to these specific requirements for
equipment, supplies, sample collection and analysis, calculations, and data analysis will be included.
Gas, lnc.
4.0 Test Summary
Unit 1318 with a serial number of 1632554 which is a Waukesha 9394 GSI engine located at Duchesne
Data Center Power Station and operated by Crusoe Energy Systems, lnc. was tested for emissions of:
Carbon Monoxide, Oxides of Nitrogen, and Volatile Organic Compounds. The test was conducted on
101912024 by Lewis Shirley with Great Plains Analytical Services, lnc. All quality assurance and quality
control tests were within acceptable tolerances.
The engine is a natural gas fired Rich Burn (4 Cycle) engine rated at 2500 brake horse power (BHP) at'1200 RPM. The engine was operating at 21'15 BHP and 1200 RPM which is 84.59o/o of maximum engine
load during the test. The test HP calculation can be found on page 8. The engine was running at the
maximum load available at the test site.
This test will satisfy the testing requirements for 40 CFR Part 60 Subpart JJJJ.
Site Verification Photos
Gas, lnc.
4.0 Test
Gas, lnc.
5.0 Run Summaries
Table 5.1 Run Summaries
Gas, lnc.
6.0 Volumetric Flow Bate Data 7
Table 6.1. Data used for volumetric flow rate (Method 2)
Pltol TuDe Coenlclent CD(Stdl= .99
Stack diameter = 20 rnchBs or:1.67 reet. or:2.18 Souare Feet
t12l)"/&18.23 18.39 18.48 18.37
coz o/od 9.64 9.67 9.64 9.66
02 1od o.14 o.12 0.16 0.14
CO oomd 35.67 35.11 31.70 34.1 6
Molecular Weioht Stack Gas drv basis (Md)o/o mole 29.55 29.55 29.56 29.55
Molecular Weioht Stack Gas wet basrs (Ms o/q mole 27.44 27.43 27.42 27.43
Stack Static Pressure (F "H20 o.28 0.48 0.36 o.37
Stack Static Pressure (Po)"Ho 0.02 0.04 0.03 0.03
Atmosoheric Pressure at Location (Pbar)MBAB 829.53 830.52 830.25 830.13
Atmosoheric Pressure at Location (Pbar)"Hg 24.50 24.53 24.52 24.52
Absolute Stack Pressure (Ps)"Hs 24.52 24.57 24.55 24.55
stack Temoerature Dea C 447 71 ru5.52 196.'22 489.82
Stack Temoeralure Deo F 909.88 905.94 925.19 913.67
Stack Temoerature Deo R 1369.55 1365.61 1384.86 1373.34
Stack Gas Velocity tusec 63.81 43.21 73.28 73.88
Stack Flow Rate Q cls 139.22 181.53 159.87 161 17
stack Gas wet vohetnc l-low Hate sct/hr 158381.4€ 2074r',8.49 180038.28 183007.40
Stack Gas Dry Volumelric Flow Rate scf/hr 129502.99 169303.90 1467&.51 149393.51
Emissions Samolino Points - 3 ooint lono line samolino orobe lnches
First Samolino Point aken @ 16.7a/o ol Stack Diameter 3.34
Second Samplinq Point Taken @ 5O7" of Stack Diameter 10
Ihird Samplanq Point aken @ E3.37o of Stac Daameter 16.66
Table 6.2. Stack gas pressure measured with a standard tube use for Volumetrlc Flow Rate
Aostd = Velocitv head measured bv the' standard pitot tube, (in.) H2o.'
Samote aner BacK F,uroe:o.16
Within 5olo ol Last Aostd readinq:YES
Flgure 6.1
'16 Traverse Points Were UsedStack Diameter (inches)20.00
Inches upstream lrom disturbance 4.OO
lnches downstream lrom disturbance 30.oo
Pitot readings are taken for Method 2 calculations using measuring points outlined in Method
'The exhaust stack dld not present cyclonlc llow condltlons at the sampllng locatlon due to the
absence of cyclones, lnertlal demlsters, venturl scrubbers, or tangentlal lnlots.
f:!.t
96 6\
Gas, lnc.
7.0 Calculations
Method 2: Determination ol Stack Gas Velocitv and Volumetric Flow Rate
.Note- Use of this method neqates the need for anv fuel related numbers for emissions calculations
Ap(avg) - Velocig head of stack gas, mm H2O (in. H2O).
3600 = Conversion Factor, sec/hr.
A = Cross-sectional area of stack, m2 (ft2).
Bws = Waler vapor in the gas stream (from ASTM D6348)
Cp(std) = Standard pilot tube coefficient; use 0.99
Kp = Velocity equation constant.
Md = Molecular weight ol stack gas, dry basis, g/g-mole (lb./lb.-mole).
Ms = Molecular weight ol stack gas, wet basis, g/g-mole (lb./lb. -mole).
Ps = Absolute stack pressure (Pbar+ Pg), mm Hg (in Hg)
Pstd = Standard absolute pressure, 760 mm Hg (29.92 in. Hg).
Qsd = Dry volumetric stack gas llow rate corrected to
standard conditions, dscm/hr. (dscf/hr.).
Ts(abs) = Absolute stack temperature, oK ("R). = 460 + Ts for
English units.
Tsld = Standard absolute temperature, 293'K (528'R).
Vs = Average stack gas velocity, m/sec (ft./sec).
Md = .44(/.CO2\+.32(/"O21+.28("/oN2+"/oCO)Md = .44(.096)+.32(.002)+.28(.898+.004) = 29.il9 LB/LB-MOLE
Ms = Md( r -Bws)+1 8.O(Bws)Ms = 29.549(1 -.18234)+.18.0(.18234) =27.443 LB/LB-MOLE
vs = Kp'cp(std;'y'apavg'y'1rs1abs)/(Ps' Ms))vs = 85.49'.99'y'.2e'y'1 r sos.sa st (24.s2' 27.443)) = 6s.8 r FTlsEc
Qsd = 3600( 1 -Bws)Vs'A((Tstd'Ps)/(Ts(abs)'Pstd) )= 36OO( I -. 1 82)63 .A1 4' 2.1 82((528' 24. 52y ( 1 369. 145'29. 92) ) = 1 29502.99
O = Osd/35.315 o = 129502.993A5.315 = 3667.082 DSCM/HR
Emission Rates (Examples use CO Run I
453.6= Conversion factor lb. to gram HP= Engines rated Horsepower
A = Cross-sectional area ol stack, m2 (ftz). Mfg.= ysnulsclurer Exhaust flow rate at '100% (tt3/min)
BHP/HR. = Brake work of the engine, horsepower-hour (HP-HR.). 02 = Concentration of oxygen on a dry basis, percent.
BTU/HP-HR. = Brake Specific Fuel Consumption (HHV) ppm= Parts Per Million (CO)
ER = Emission rate ot (CO) in g/HP-hr. ppm@15o/" 02= PPM corrected lo'lsoh 02
F(d )= Volumes ol combustion components per unit of heat Qsd = DU volumelric stack gas flow rate correcled
content, scm/J (scf/million Btu). to standard conditions, dscm/hr. (DSCF/HR.).
O = Stack gas volumetric flow rate, in standard cubic meters Run Time = Run Time in Minutes
per hour, dry basis Tpy= Tons per year
LB/HR.= Emission rate of (Co) in LB/HR. Vs = Average slack gas velocity, m/sec (ft./sec).
Molwt.= MolWeight ol CO (28.01)
ppm @ 15ol" 02 = PPM'((20.9-15%O2y(20.9-O2))ppm @ 15o/" 02 = 43.627'(20.9-15y(20.9-.2o/.)) = 12.435 PPM @ 15o/o 02
g/hp-hr = (PPM'( 1. 1 64' 1 0r3)'Q'(Run Time/60))/BHP/HR (4i,.627'( 1 . 1 64' 1 0^-3)'3667.082'(Run Time/60)) t21 1 4.ffi9 = .088 GAIP-HR
tb/hr = ER'1 /453.5'BHP-HR LB/HR = .088'1/453.6'21 14.869 - .411 LB/HR
TPY = .41 l'4.38 = 1.8 TPY
1578'1.34022088
ppm wet' (1(1-H2O) - ppm dry 43.63 = 35.672'(1 (1 -. 1 8))
8.0 Oxygen Calibration 9
8.1 Calibration error test; how do I confirm my analyzer calibration is correct? After the tester has assembled. prepared and calibrated the
samphng system and analyzer. they conduct a 3-point analyzer calibration error test before the first run and again after any farled system bras test or
farled drift test. They then rntroduce the low-. mid-. and high-level calibration gases sequentially in direct calibration mode. At each calibration gas level
(low. mid. and highl the calibration error must be within I 2 0 percent of the calibration span.
8.2 lnitial system bias and system calibration error checks. Before samplrng begins. it is determined whether the hagh- level or mrd-level
calibration gas best approximates the emissions and it rs used as the upscale gas. The upscale gas is introduced at the probe upstream of all sample-
condrtioning components in system calrbration mode
( 1 ) Next, zero gas rs introduced as described above. The response must be within 0.5 percent of the upscale gas conceniration.
(2) Low-level gas reading is observed until it has reached a final. stable value and the results are recorded. The measurement system will be
operated at the normal sampling rate during all system bias checks.
(3) lf the initial system bias specification is not met, corrective action is taken. The applicable calibration error test from Section 8.2.3 of EPA
Method 7E is repeated along with the initial system bias check until acceptable results are achieved. after which sampling will begin. The pre-
and post-run system bias must be within t 5.0 percent of the calibration span for the low-level and upscale calibration gases.
8.3 Post-run syst€m bias check and drift assessment - confirming that each sample collectsd is valid. Sampling may be performed for multrple
runs before performing the post-run bias or system calibratron enor check provided this test is passed at the conclusion of the group of runs. A failed
final test an this case will invalidate all runs subsequent to the last passed test.
(1) lf the post-run system bias check is not passed, then the run is invalid. The problem rs then diagnosed and fixed, then another calibration
error test and system bias is passed before repeating the run.
(2)Aftereach run. the low-level and upscale drifl iscalculated. using Equation 7E4tn Section'l2.5from EPAMethod 7E. lf the postrun low-
and upscale bias checks are passed. but the low-or upscale drift exceeds the specificahon In Sectron 13.3. the run data are valid, but a 3-point
calibratron error test and a system bias check must be performed and passed prior to additional testrng
Table 8.1 Oxygen Calibration
Method 7E 3.4 To the extent practicable. the measured emissions should be between
20 to 100 percent of the selected calibration span. This may not be practicable in some
cases of low concentration measurements or testing for compliance with an emission
limit when emissions are substantially less than the limit.
EPA Method 3A QA Worksheet
Ccrtificd Gls Conc.ntraion I Cotilfied Ger Conontralon I Cert'ified Crac Co
Low.Lewl (%) I mld{ewl (%, I xtgtr{.evr
o ao.,
(OIRECT) Analy:e. Calibratlon Error (5 2'lo)
Chmk
ncantralon
7E 8.5: Note: that you may
risk sampling for multiple
runs before performing the
post-run bias provided you
pass this test at the
conclusion of the group of
rUNS
Certified
Concentration
Value (%)
Direct
C.libration
Relponso (%)
Abdute
Difierence (o/o
Analper
CrlibGtion
Enor (%)
Zero Gas o/o 0 00% 0.00%0.000/"0.00%
Mid-Level Gas %
High-Level Gas %
10.62%
21.120/.
10.63%
21 180/"
0 010/.
o 060/.
0 05%
0.270/"
(SYSTEM) Cslibration Blas Chocks (s 5%) and Drift Chsck3 (s 37.)UPsclle Gr3 10.62%
Zero Offs€t 0.000/"
Biac Pre lniti.lValue Bi.s P6t lnital ValuesSpan 21.12
Analfzsr
Calibration
Response (%)
Zero Gas 0.00%
Sy3tem
C!librutio.r3
Reoponse Pre
(%)
Sy3tem Bir3 (9(
of Span) Pre
System
Calibration
Ro3ponse P6l(%)
j).rtem Bias (ol
of Sprn) Po3I
Drill (% of
Span)
0.00% 0.00%0 000/"0 00%0 00%
Upscala Gas 10.6370 10.uo/.0 98%'to 7 10/"0.38%0.01%
(SYSTEM) Calibration Bias Checks (5 5%) and Orift Checks (s 3'6)
Avg. Gas Concsntration (Run 1)o.17yo Effuent Gas (Coas) Run I O.17o/o
Avg. Gas Concentration (Run 2)o.150/"Eflluent Gas (Cgar) Run 2 o.1syo
Avg. Gas Concentsation (Run 3) 0.19% Effiuent Gas (CA!s) Run 3 o.19%
Gas, lnc.
EPA Method 3A CIA Worksheot
Zero Gas 100% Nitrogen
Mid-Level Gas 10_62./.
High-Level Gas 21.12./.
Zero Gas %
Mid-Level Gas %
High-Level Gas %
ZeroGas% I ooo% IUpscateUsed
upscate cat f1m4",b I 1o.o2e,
Zero Gas % I ooo".,"
_l
Upscate Used
upscar€ cat I -x. 1 fi62e.
@mpany urusoe Enerov \ivstems, lnc.
Facilltv Duchesne Data Center Power Station
Date 1o,t9t2024
Slte Elevataon (ft)1775.96
Unat lD l3'tE
Mal(6 Waukesha
Model 9394 GSr
Serlal Number 1632554
Technaclan Lewis Shirlev
9.0 Engine Parameter Data Sheet
AS
Completed
Gas, lnc.
Run Start Tlmes 07:34 AM 08:57 AM 10:'18 AM 11:42 AM
Englne Hours 16227 16228 16.229 1 6230
Englne Parameter Data
BUN 1 Run 2 Bun 3 Averaoe
Enolne Specd (RPM)1199.0 1200.0 12()O.O 1 't99.7
htake i,lanlfold Pressure (Dsi)73.6 @.2 61.0 64.9
lntake Manltold Temp "F 120.4 121.5 124.O 122.0
Englne Load (BHP)2114.9 2114.9 2114.9 2114.9
Amblent Temp "F 46.O 52.O OU.U cz.l
Humldity 70 22.O 22.O 34.O 26.u
Dew Point'F 29.O 29.O 3Z.U JU.U
AFR Manulactu rerlTy]re Waukesha Waukesha Waukesha Waukesha
Suc{lon Pressure N/A N/A N/A N/A
Dlscharge Preasure N/A N/A N/A N/A
qataHst (Yea or Nc YES
Gatalyst Manulacturer Maratech Maratech Miratech Miratech
# ot Catalyst lnstalled 1 1 1 1
Catalvst lnlet Temo "F 118't.0 1074.O 't078.0 1111.0
Catalyst Outlet Temp'l-1103.0 1092.0 1099.0 1098.0
cataryst Pressure Drop H2(,5.b 5.2 5.6 5.5
11
10.0 OA/QC Results
Response Time
System Response Time 45 seconds
Nitrogen monoxide NO
Nitrogen dioxide NO2
NOx
voc
Oxygen
Average:0.00
Average:0.03
Average:0.03
Average:0.03
Average:0.04
CTS Compound Concentration Avg
Tolerance
Difference between measured and expected
Value: 100.30
Value: 101.46
2.007"
1 .1 6olo
Nitrogen monoxide NO
Nitrogen dioxide N02
NOx
VOC
Oxygen
Average:0.00
Average:0.39
Average:0.38
Average:0.11
CTS Bottle Concentration
CTS Compound Concentration Avg
Tolerance
Difference between measured and expected
Value:100.30
Value: 101.61
5.00%
1.31o/"
Equilibration Response Time
Spike Reported
Spike Expected
S
Value:255.51
Value:252.40
Gas, lnc.
12
11.0 D6348 Annexes 1-8
. Test
The test quality objectives completed for the emissions test are demonstrated throughout Annexes 1 ,2,3,
4, 5, 6, 7 & B as layed out per ASTM D6348-03. All reference methods, pre-test and post test procedures
were within acceptable limits. Data generated during the pre-test and post-test procedures are
summarized below in order of the distinctive Annex.
Three 60 minute test runs were performed. The final analyte concentrations are the average of each test
run. Data was taken at 60 second intervals. Each 60 second measurement was the average of 600 scans.
Propane is used as the surrogate compound for the Annex 5 Spiking Technique due to Propane being the
VOC that is most commonly found in the combustion process of natural gas. Additionally, the molecular
weight of Propane coincides with with molecular weight of VOC's per the EPA.
1
Annex Table 1.2.1 Certified Calibration Bottle Concentrations
Bottle Expirataon N()2 Ethylene SF6 02 (/"1
cc506322 9t17 t2027 99.95 10 62e'"
12/1/2025 100.30
cc406148 4t15t2032 21 .120.6
Cylinder # ALM-063647 Expiration: 5-03-2032
Propane CO NO SF6
Botlle Value 252.41J 501 70 23/.51J 10 20
Analyzer System Response 255.51 509.53 240.18 10.44
Percent Diflerence 1.23k 1.56q,.1 .1 3"6 2.35,L
Annex Table 1.2.2 Measurement System Capabilities
raramerer
Measured Gas concentratl0n(ppm)Path Length Equillorauon
Time Dilution Factor 7" Becovery
Path Lenoth Ethvlene 101 .464 5.058
Spike Direct
Prooane 251 771
SF6 10.357
CO lgJ. /6J
NO 23/.62/
Mechanical
Response Time Elhylene 101 609 t7 seconds
Analyzer
Response
Prooane 255.508
l7 secondsSI-6 I U.44U
CO 5U9_53U
NO 240,175
Analyte Spike
Recovery Propane & SF6
7.93,6 97.72o/"
8.92e,"95.12,b
7.48"1o 98.870,{,
System Zero Nrtroqen 17 seconcls
Posl Spike
System
Propane 252.O31
CO 499.038
NO 236.258
SF6 10 316
Gas, lnc.
1.3
13
'VOCs compiled of Acetaldehyde, Ethylene, Hexane, and Propane.
PSS PROB€F--l'*q, r-_
o2
SENSOR L
Frow
I,ITR.et
l
U
GASVENI
Figure Annex 1.4.1 Sampting Train
The testing instrumentation is housed in an enclosed vehicle which is located approximately 45 feet from the source. A
heated sample line (sixty feet in length) is attached to the inlet of analyzer system and the source effluent discharges
through the FTIR outlet.
Annex Table 1.3.1 Test Specific Target Analytes and Data Quality Objectives
Compounds
!nfrared
Analysis Reglon
(cm-1)
Expected
Concentratlon
Range
,yleaSuremenr
System
Achievable
Mlnlmum
Ileiectable
Concentrailons
Hequrreq
Measurement
System
Accuracy and
Preclslon forfest Aoollcatlon
CO 2@O-2200 0-1200 Dom 0.16267 Dom 4 oom
NO 1875-2138 0-10O0 oDm 0.4007 DDm 2 oDm
NO2 2700-2950 0-100 ppm 0.2899 oom 2oom
VOC
26U)-3200
0-100 ppm 1.8520 ppm Tota
VOC's 1 ppmperVOC91 0-1 1 50
2550-2950
CH2O 2550-2850 O-1OO oom 0.787E oom 1 oom
lnterfering
Compounds 'CO is analyzed in a separate analysis region than CO2 and HZO
coz 926-1 1 50 0-10%Oo/o nla
Water Vaoor 3200-3401 O-22o/o O.N"/"nla
S?ACX
Gas, lnc.
14
TRI.PROBE SAMPLE POINT LOCATIONS
AS PERCENTAGE OF STACK DIAMETER
Flgure Annex 1.4.2 Sampllng Polnts
lnterior Stack Diameter (inches):
lnches
Upstream:
4
!nches
Downstream:
30
SAFLE PORT LOCAIrcN OETERMINED
BY USTAIICE FROT4 USTUREANCE
Flgure Annex 1.4.3 Sample Port Locatlon
Sampling Point Locations
in lnches
16.7o/o 3.340
5Oo/o tu.u{.ru
83.3olo 16.550
El!F
T
5
tI.,)
?,o
g.
Hutt
o
3I
E
Gas, lnc.
Target Analyte Results (ppm)
CO o.1621
NO U.4UU r
NO2 0.489!
trInvrene u.3 / 62
Prooane o.4:t51
Hexane U.ZZJi
Acelaldehyde 0.8152
Formaldehvde 0.787t
tttNIitll-,ll s l't N,
nttLl:
.,i; X ,* '''r ( rr ,- t-",' ).
,rt,\'/:'A (-t,,t Lr,,,r-rn s -Iit:l: "t 1.,,-t,
,',,1 \'
r (N t;'7"1')
lrlR l; l-'t t tl.\
trlD(:$l
Calibration Transfer Standard Expected Measured Path Lenqth Validated
Ethvlene 100.3 1U't.46 5.058 PASSEd
Annex Table 1.2.2 Measurement System Capabilities
Parameter
Measured Gas concenlratron(oom)Path Length Equrllbratron
Time Dilution Factor "/" Recovery
Path Lenoth EthVlene 101 .464 5.0s8
Spike Direct
Propane 251 .771
SF6 10.357
CO 493.783
NO 237.827
Mechanical
Response Time Ethylene 101 609 1 7 seconds
Analyzer
Response
Propane z55.5UU
1 7 secondsSF610 440
CO 509.530
NO 240.175
Analyte Spike
Recovery Propane & SF6
7.93e,"9t /2".o
d.YZ",/o 95.1 ZYlo
7.48"',o 9U.6 /Yo
Svstem Zero Nitroeen 1 7 seconds
Post Spike
System
Prooane 252 031
CO 499.038
NO 236.258
SF6 10.316
Gas, lnc.
Paramoter Gas concentrauon Mea6ured 96 Dlfl€rence sBectflcataon Valldated
Spike Direcl
Propane 252.4UU 251 .771 O.25o/"tl- 2o/"HASS
SF6 10.200 10.357 'l .54o/"+l- 2o/"HASS
CO 501.700 493.783 1.580,',"+l- 2o/o Pass
NO 237.500 237.827 o.14h +l'2o/"Pass
Soike Run 1 via the Svstem
Source Output Solke Averaoe Dilution Factor Erpected o/" Recoverv Specification
Propane 1.3:/4 20.749 21.234 97.7207o 70-130%
SF6 0.004 o a21 I .921"/o (l UY/o
Splke Run 2 vla tha System
Source Output Spake Averaqe Dilution Factor Expected 7" Recovery Specification
Prooane 't 215 22.4b9 23.621 95.12O"/o /o-130"k
SF6 0.009 o.!,:z4 6.922'/c <107o
Soike Run 3 via the Svstem
Source Outpul Spike Averaqe Dilution Factor Expected 70 Recovery specification
Prooane 0.430 19.059 19.277 98.87Oo/o /U-13(J"/a
SI-6 0.006 0.775 7.483o/"<1Oo/"
Noise Equivalent Absorbance (NEA)
RMS High 0.002084
RMS Mid 0.001318
RMS Low 0.049510
ng (Manual Comparison +l- 2Oo/o
Iine Posrtron
to Reterence I 2.93n"0.0096 Pass
Gas, lnc.
Pass
The Gasmet GICCOR (Genzel lnterferometer with Cube Corner Retroreflectors) interferometer is specially
designed for maximum opticalthroughput and maximum signalto noise ratio of 7.72 (cm-l) remaining
stable with any vibration and temperature changes.
The Gasmet DX4000 is a low resolution spectrometer where the aperture is fixed to a maximum angle
setting and the detector linearity was tested with an alternate approach. A three point linerarity of ttie CTS
gas was performed and validated.
Linea rity
32 0324
23 0324
14 0324
5 0324
3 9676
12 9676
21 9676
30 9676
39 9676
695 687 679 672 664 656 648 641
32 0324
23 0324
14 0324
5 0324
3 9676
12 967(
21 967(
30 967(
39 967(633 625 618 610 602
-.OO1241n9 Pass
The analytical accuracy of the quantification algorithm is satisfied via the results from Annex 5 per Annex
7.6
POST gTS Svrbm Gh€cX:
CTS Bottle Concentration:loo.30
u I :' liamote uonoenlratbn Averaoe:99.47
Difference between measured and exDected:0.840/"
Tolerance:5.00o/"
Run Oitr Ydlddon - arcmod u3 Erud ECTIIO ydEeDd Gommrnta
Run 1 Points 1 & 2on CO/NO/Prooane All within 20olo Passed Demonstrates no inlerferences observed.
Run 2 Points 1 & 2 on CO/NO/Propane All within 2(P/o Passed Demonstrates no interferenc€s observed.
Run 3 Points 1 & 2 on CO/NO/Prooane Allwithin 20%Passed L'emonstrates no interlerences observed.
Gas, lnc.
18
12.0 Signature Page
Job/File Name: Crusoe Energy Systems, lnc.; Duchesne Data Center Power Station; 1318;JJJJ
We certify that based on review of test data, knowledge of those individuals directly responsible for
conducting this test, we believe the submitted information to be accurate and complete.
Company: G.A.S. lnc.
Print Name: Lewis Shirley
Title: Emissions Specialist
Dale:101912024
Company:
Print Name:
Signature:
Title:
Phone Number:
Date:
Company: G.A.S. Inc.
Print Name: Travis Hartley
Title: Director of Stack Testing
Signature:':j\.,-
Phone Number: 580-225-0403
Date:101912024
Gas, lnc.
Appendices
Gas, lnc.
m
r 9L4nrrtat
GNdC Of PTOdUCT: f,PA PROT(TOL STA:iDARD
Cr.*m GRC I Ft.AftSAnllYtlCAt -FVrcEP,hrt co!,llca€ rtl@r.
C)..t ffrrntil lUOCfa,L-ottsy
PO\IP lrrno<G6Cd.Crtreur Do tLy 0l 2Aa
Eryrea Oil: llrl 0t. lOlC
C.Ira FH - ...,e. - Ita lc.€ ioad U A.'r E Cd..ao ol h. C.--. lhA (tl F :t &lea ai aoit:aJl 69lra .r D.qdr.r '.3 &arfo farfrcilne, C.r d rEE @rt@ io dr(a,trwa ,\r (l-{i t{i r l!t, Fitr fi6.,r tI.,- m -r a iqclrE. rd o,Yr\ naEr.{n&d rsraar ffi .tdn! - dtra ca.a6d.tr la(m6-r. -FrrE m,B ft a ,d lt 6rr € dr b h h E tia rQq{ E d h n.,€{-.q.irt n i, drE, aor'r C h r&ft Oo B u- l\.OrrtE'Op{ . 3!rg4-r.
r\ rl_l rt( rt. ltrt I fr
( .rtrt&rt tr)\ sl,r\o.rtrlxi
Spike (5 Gas)
tlrta. tF{t (.n
Ir'.rt \\tl(
ll-ll \ llcr,rtlt t.<
( ll.a,ll dt!'\
\ r.trr { .o
Cf, RTI FICATE OF ANALYSIS
i?a. Orc.{olSlP) lt
8r2q.?.co co2 iao tor PPit g^tx
R.brretao !aaol)ltg22 t
C).trdr \bfr. lat O
Cfrd.. A-.u! 2Ol5
vd. Ofi. 6110
t\ rr.l I t( .rt. f.qt t?rtf\ I
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t tla
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lldra (orarla nrMa lqraa t^r, }|t-rria s a !., (crnp'!r, &tort ha<t vlr,td.O{ d\a [r4 rg^a Citfk- s, A^rtra
Crra.(t fh. &9D lrao.rEy , I rgnr{ i rt{urrd StC O t0 20 P?ll
3.grr-,rro o f N
Ao0rc.a b, ,b5...palc I ot I
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:--llv \lltl ,'4.\1 .,. l,rl ..irr^(..di.'rE-..iitr.iaisd.. lr,-\dr<,5,21-'.-
Gas, lnc.
9o/o O2|NO2
lltpH
Utgrr rgriJly f .rr
^1,r1r{-! lir,,
llrrl,{h \( r_ r r
CE,RTI FICATE O F ANALYSIS
Gra& of Product! EPA PROT(rcOL STANDARI)
Prf NunEr
Cro(b, Numo..
L&orXfft
PGVP l*sn$c,
C.r Codc
Eo3r{lErr5wm20
cc306322
'12{ . Dursn iSAP).}lC
8.7202.
HO2 02 BArit
RalrGnc, tlrrt .
Cyt76a. Vd\rmc
CylnOc Ptcttrn
Valv! OiJ6o(
Catlrlcrbot Olc
!22.a<3t9t7 r
r.3 3 CF
20!5 PsrG
660
Sca 17 ?02i1
Ortr:
6U6,e a .,l@ 6 tl^ t.rsi hd E b- d blad d bt{ Cffi M'tbr nll }r at^(r)a'.'att eqtb qF-r.nE hGak Ar 6d I d b-E dG. lict,e s.t4-G.a.rdr - 5 1-r - a (oirr. *,r al r,s ."< r{ra.d rsi.. rr^ &r ts - r' N,t-, rvr a .aadr-n -. ir aG.-E.eraff r< rr.+A tit,rlt.ha-tEl lE,.@.8{b@d.idnVdW .cr. rts &-, ab
brlih.clei-bb,Iq . o'
fi- O.ra Avtlda t Oqr ta.i.d
,t,f,o,'. lorR.Lr.lDtlJt
[T{ALTTICAL NTSI'LTS
l.A.id &nd ,roaocoa toL l.Llv.CEEantnc. Co,rcailrllcr 5rd Urc-faina,
rarPCJCt\f>lrJOf lUoaFPl/| og.,5Pl\l G! . .1\hl5r r,r-6- :rrr:rIJ:{ :O,II. ,I
(Iy(fr. ruar-1 \ 1(r L-! 6. . Ca\Ns".rd lx..rjlfa
rar9cJct\r>lrjof !u0aFPu 99.4
C.tl-l BIA'tl()N ST/LqS l)AnlXi
Ld D Crrlrdi Xo C-lrrtrrlb,r
rlLs rlHxr2lrf.{)r (-c!p1f ,c(.9ttuvlracx,a.lrtxorctra'tr-Y.{N
t]! tt.,aa gt t0 ,,su r. lrao<llr o(cuct Arr(jr!as rl}{x.P{.{flra t\y'.bt'i lan.pl,ufrtia(-xlx0ror({ ^xr t !Yr 7 9,I[ r \ Onil ]auil{(J(;l \
It :x Xlry lry .,u,,-d a-. )ot, dE!.Eh'x6d.h.r-t rd&rrdorr! rar-
I ri\5 or lfrri(! j I :'(r?a
t, Ja IUf
AN ALITICAL tiQU I Plt l:YT
An rE tn*aL
r,ts r rP rcl cr ir
Gas, lnc.
Alrgas
Customer:
Part Numbsr:
Cylindsr Number:
Laboratory:
Analysis Oate:
Lot Numb€r:
Ethylene Only
AlryEspccldtyca€
Air8sUS LLC
r2722 S. Wentworth Al'e.
C'hi6go, IL 60628
Ai4s.m
CERTIFICATE OFANALYSE
Grade of Product: PRIMARY STANDARI)
GREAT PLAINS ANALYTICAL SERVICE-
x02Nt99P1sACVH8
cc325720
124 - Chicago (SAP) - lL
Dec01.2022
5440260346G1
Erplrrtbn Drt : Doc 0t,2025
Referenoe Number: 54.40260346G1
Cylinder Volume: 144.0 CF
CyliM€r Pressure: 2015 PSIG
Valve Ouflot: 350
Primary Standard Gas Mixtures are traceabh to N.I.S.T. weights and/or N.I.S.T. Gas MixtJre reference materials.
Component
ANALYTICAL RESI.]LTS
Roq Conc Actual Concentratlon
(xoh%)
Analytlcal
Uncertalnty
ETHYLENE
NITROGEN
100.0 PPM
8€18ncs
r00.0 PPM rl- 1Yo
Approved for Releare P.g. I ot I
Gas, lnc.
llpH
BIP
$.trr rt-iatf l;Er![.. t \{ tlr
6r., I d^, Irr.r
'i':1"':" '""
CERTTFICATE OF BATCH AT{ALYSE
Grade of Prcduct: CEM-CAL 2ZERO
Prf Nunoa.
Crhd.r A^dyt (,
Ldorlcy
AnCno Dic
Nr czm
APROtNCSGC692g)A
t2a . Arhrn (SAP) . NC
F.b22 2o2a
RC..crE. r{L,rt , !22{0AO0l8.Gt
Cy'rrdGr Vclrrr I)a 0 CF
Cy'rrrCcr Prrrrrr 26aO PSIG
Valv! Grrcl 3t0
Cdtleo.raarl
AI{ALYTICAL R-ESULTS
Lqra.ad?trf,CrtardCdrcaintbrt
HIYROGEN
llOr
so2
rr{c
C nEOil MOI'aOXIO€
cARAOil OTOXTO€
99999:t I
0rPPH
0 r PPtt
orPPil
O 5 PPf,I
r0PPH
99 99rt !a.LDl. 0 @ PFU
<r DrL 0 07 PPL<LDI O 6 PPII< orPPf,t< otPPu
Frnmrrf faofr:Ar!.r cc6hr tri tl! coEir ot itrr cy'ndd fi64 l,! .tqJmdr o{ a0 Cf R
tl2
Clfr.-{r h lsoi
r919a.v .omo 5061 r try aPRotrcs6eelr,9^ co rtaao, r026]0 t L 1. ra rL91 f9 t(x)2])G.r
lmz.oa ttrmrt t9120,9 lgalorl rwBl3$193y
,rtunD6 siod aorll D)rlol rlrcrdr rrSa b l.lsl Dy 6rf rtd,c a.g}6a
Afio,r. taRaL-.b?ldt
Gas, lnc,
IITPH
21o/o 02
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'r--, \ ah l.rl,6r,',1 1,.r, t
1,,.! tlia.,_l
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CERTI FICATE OF AITALYSIS
Grade of Produc{3 EPA PROTOCOLS'fANDARI)
PllNunbor E02t{l79ElslOOBt
CyrodcrNumocr CC4O6!a6Lilorddr 12{ - lo6ac rSjlPr -UI
PGVP iaura.r fl72021
Cor Cdc 02 BALN
Rafaerro |trnla I 53 a&n tE92l . t
Cykxhr Vd,rnc 146 0 CF
Cykxhr Pr66ut 20t5 PSIG
Vllvo Ouicl 59
Cdtrtcrt'c1 Ote Apr 15 ?0211
nr)t !.)ar' -.N lb -A F&-. nE hwa hr€r t. d g ffi E .qd 6l.ci h.r,& s rro, 4!..dr- i,ll'lfrl--< a,.r*,.*tra\ rb..r!rya..nnOdarrri-tFrrilF.&*r'-Vr ar*.?i'tu.r.(-.,..,..('|l|Faux,.*,a@rr- lr.*4,-t,rit,ha6tat lt.,.dF€bv&d...rrr,\.iu, lFr. ,h a.tart a^,
Otl.
rnk.Blfr r&d@ -n ll^'rffi hdbbad6tau dbe,{Ctu 'M trn!, affl
Irt- O.i. AvaLa. t Do.r l.qu-l
AOerG,.a lo. R.Li.h, lc, I
Ca.l!a.td i.qu.i.aC{tcrtalon
..Ll Al.lTtcAL Rf,St' t.TS
Achd hoaoaolCqlca.rtiba tnroa toua nalrfrncit kar ADt,Orr-
(lrY6f \ l1(f \
ia re(Xrt \ 8..[.
5\N5l r.ro& I1S.{,j.
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hrru m6lay cL.!.i.9,1 Ll 5l l ortG{-brarRGj{h c a\llr tl I)5
fita^rrd/I-.rlo.rd
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&rrrrkdhrcTa.L^rl lfrpo.lra C.lb.aldl
ri*. tPA 6 r,l VglllLtla OJ ()2 Pr@ lt)llUltr Ad itl :,,Ua
Gas, lnc.
GAS
Part Number:
Laboratory:
Analysis Date:
LOT Number:
SN:
CERTIFICATE OF ANALYSIS
Grede of Prcduct CERTIFIED STANDARD"PROBE
Meaiurtd Flou iiaasurcd Flow Mcesured Flow Meeo Probe
Pon A (Vml Porr B (Vml Port C (Vm) Pora S.Dplcd
(Dclte oll lDclta o2l (Dclte o3l Flow ([-/m)
Gr€at Plelns An lldcal Servles
303 W 3d st
Elk City, OK 736.+4
(580)225-0403 Fax: (580)225-2612
20L
GAS INC.
31312022
A
22420L
Reference
Number:
Stack Diameter:
Target Flow
Rate:
Number of
PoinE:
22
20"
3Umin
3
hoduct performance verilied by direct comparison to calibration standards traceable to N.I.S.T.
*The probe listed on this form meets the multipoint traverse requirement of EPA Method 7e,
section 8.4 as shown in the accompanying data. Method 7e, section 8.4 states that the multipoint
traverse requirement can be satisfied by sampling via "a multi-hole probe designed to sample at
the prescribed poins with a flow +/- l0 percent of mean flow rate".
ANALYTICAL RESULTS
Tot lFlow
(Vml
Rul
R6l
] LPM
4 LPM
0.6t0
(7.94A',
r..15
(7.l.lA r
o.610
(.1.59l\)
l.:l(.:.lta )
0.590 0.610
({.t54 )
t.to t.:6
(-1.76.A )
'Calibration conducled in accordancc with Emission Measuremenl Ccnter Guidcline Document - EMC GD03l
31312022
DateApproved for Release
UNITED SIATTS ENVIRONIIENTAL PROTECTION AGENCY
f lf '.EAtir'_ F lnlAtr(-iuE I Al.:K fi(_ .,i:r'j
I
Mr. Jordan Williarnson
CEO
GAS Inc.
303 W. 3ra Street
Elk City, OK73644
Dear Mr. Williamson:
We are rvriting in response to your letter received on September 17,2020, in which you request the approval
of alternative testing procedures. The EPA's Office of Air Quality Planning and Standards (OAQPS) is the
delegated authority lbr consideration of major altematives to test methods and procedures as set lbrth in 40
CFR parts 60 and 63 under u'hich your request must be addressed. GAS Inc. is requesting a change to one of
the test methods, ASTM D6348-03. used for conducting performance tests to determine compliance under
40 CFR part 60, Subpart JJJJ - Standards of Performance for Stationary Spark Ignition Internal Combustion
Engines (Subpart JJJJ) and 40 CFR part 63, Subpart ZZZZ - National Emissions Standards fbr Hazardous
Air Pollutants tbr Pertbrmance for Stationary Reciprocating Internal Combustion Engines (Subpart ZZZZ).
The change being requested will be used to check detector linearity of the Fourier Transform Infrared (FTIR)
instnrmentation used to conduct this method. Specifically, you are requesting that the procedures of section
8.3.3 of Method 320 (40 CFR part 60, Appendix A), another FTIR-based method allowed under Subparts
JJJJ and ZZZZ, be used in lieu of section A6.4.1 of ASTM D6348-03 rvhen conducting testing using ASTM
D6348-03 under 40 CFR part 60, Subpart JJJJ and 40 CFR part 63. Subpart ZZZZ.
In your request, you state that this alternative linearity check procedure will produce consistent results when
utilizing either Method 320 or ASTM D6348-03. Additionally, some FTIR instrumentation does not allow
tbr reducing the size of the aperrure in the instrument and, thus, it would not be feasible to properly conduct
the entirety of the ASTM D6348-03 method in its current form using such an instrument.
Based on our understanding of FTIR instrument principles and recognition that the requested altemative
determination of detector linearity is both technically sound and contained within Method 320, we are
approving the requested change. We believe that this altemative is acceptable fbr use tbr use in testing all
engines subiect to 40 CFR part 60 Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. Also, we will post this
letter as ALT-l4l on EPA's website (at u:.r:l'.epo.gor/emc/broadly-applicable-approred-altentatite-
testntethods) to announce that our approval of this alternative test method is broadly applicable to engines lbr
the purposes of meeting Subparts JJJJ and ZZZZ.
rastz\)16
a
March 15, 2021
If you should have any questions or require further information regarding this approval, please contact David
Nash of my staffat 919-541-9425 or email at nash.dat,e@epa.got'.
Sincerely,
STEFFAN Hr^i,?*?-
JOHNSON ffirffiJ'
Steffan M. Johnson, Group Leader
Measurement Technology Group
cc:
Sara Ayers, EPA/OECA/OC/IvIAMPD, (ayres.sara@epa.gov)
Melanie King, EPA/OAR/OAQPS/SPPD, (king.melanie@epa. gov)
James Leather, EPA Region 6, (leatherjames@epa.gov)
David Nash, EPA/OAR/OAQPS/AQAD, (nash.dave@epa.gov)
Lewis Shirley
GAS, lnc.
580-225-0403
info@gasinc.us
Type of Sources Tested:
Stationary lnternal Combustion Engines. 4 Stroke Rich Burn Engines. 2 Stroke & 4 Stroke Lean Burn Engines
Stationary Natural Gas Fired Generators
Stationary Propane Fired Generators
Gas Fired Boilers
Types of Analyzers:. Gasmet DX4000 FTIR. Gasmet Portable Sampling Unit with Zirconium Oxide 02 Sensory. Testo 350. Flame lonization Detector
Qualifications:
Trained, studied, and fully demonstrates compliance for emissions testing via data collection outlined in the
following Reference Methods:. EPA Method 1 & 1A - Sampling & Traverse Points. EPA Method 2 &2C - Velocity & Volumetric Flow Rate of a Gas Stream. EPA Method 3A - Oxygen. EPA Method 7E - NOX. EPA Method 10 - Carbon Monoxide. EPA Method 25A- Volatile Organic Compounds. ASTM D6348 - Extractive Fourier Transform lnfrared Spectroscopy
Conducts emissions testing on a weekly basis including, but not limited to, the following test types: lnitial
Compliance, Biennial Compliance, SemiannualCompliance & Quarterly Compliance. Alltests performed
are in accordance to any and all Federal & State requirements as applicable (i.e. JJJJ,77zZ, 106.512, 117,
PEA, etc.). Performed testing in Colorado, Utah, Wyoming, North Dakota, Montana, Kansas, New Mexico,
Oklahoma, Texas, Louisiana (land and off-shore), Arkansas, Ohio, Pennsylvania, West Virginia, New York,
Kentucky, & Mississippi.
. Quarterly Performance Reviews covering ongoing changes with Federal Regulations, State
Compliance guidelines, & site-specific safety certifications.
Gas, lnc.
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40 CFR Part 60 Subpart JJJJ
Performance Test Report
Test Type: Annua!
Test Date: 1U1112024
Source:
Waukesha 9394 GSI
Rich Burn (4 Cycle)
Unit Number: 1362
Serial Number: 1650569
Engine Hours: 1 1665
Location:
Duchesne Data Center Power Station
Duchesne County, Utah
Prepared on Behalf of:
Crusoe Energy Systems, lnc.
+As.
DfpAnrMENiiE--
ENVtRONMEr.rral eUnlfV
No\/ - 5 2024
DIVISION OF AIR OUAI.ITY
303 W. 3rd St (580) 225-0403 Elk City , OK73644
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
10.0
11.0
12.0
13.0
14.0
15.0
16.0
17.0
I
o
10
11
12
18
19
20
25
26
28
Calculations
Orygen Calibration...
Engine Parameter Data Sheet..
QtuQC Results........
D6348 Annexes......
Signature Pa9e............
Appendices.
Bottle Certs.
Tri Probe Certification via GD-031
GAS ALT 141-FTIR EPA.............
Tester Qualifications (resume)...
18 0 Raw Data
i;;t;;
.......... 2e
Table 5.1 (Run Summaries)............. ........... 6
Table 6.1 (Volumetric Flow Rate Data)........... ................ 7
Table 6.2 (Stack Gas Measurements)....... ......................7
Table 8.1 (Oxygen Calibration).. ................. 9
Annex Table 1.2.1 (Certified Calibration Bottle Concentrations)......... 12
Annex Table 1.2.2 (Measurement System Capabilities)..................... 12
Annex Table 1.3.'1 (Test Specific Target Analytes)............................. 13
Annex Table 4.1 (Measure System Capabilities) ............ 15
Figures
Figure 6.1 (Location of Traverse Points per Method 1). .... . .... . 7
Annex Figure 1.4.1 (Sampling Train)..., .. ... 13
Annex Figure 1.4.2 (Sampling Points).. ....... 14
Annex Figure 1.4.3 (Sampling Port Locations)... ............. 14
Appendices
Certified Calibration Bottle Certificates........... .................20
Tri Probe Certification via GD-031 .............. 25
GAS ALT 141_FTIR EPA............. ............... 27
Tester Qualifications (resume)... ................. 28
Raw Data.... ........ 29
1.0 Key Personnel
GAS, lnc.
Crusoe Energy Systems, lnc.
Lewis Shirley
JD Herbert
2.0 Sampling System
The sampling system used consisted of a Stainless steel probe, heated Teflon line, gas conditioning
system, and a Gasmet model DX4000 FTIR analyzer. The gas conditioning system used was a Gasmet
Personal Sampling System with a Zirconium Oxide oxygen sensor.
3.0 Methods Used
ASTM D6348-03
This extractive FTIR based field test method is used to quantify gas phase concentrations of multiple target
analytes (CO, NOX, CH2O, & VOC's) from stationary source effluent. Because an FTIR analyzer is
potentially capable of analyzing hundreds of compounds, this test method is not analyte or source specific.
The analytes, detection levels, and data quality objectives are expected to change for any particular testing
situation. lt is the responsibility of the tester to define the target analytes, the associated detection limits for
those analytes in the particular source effluent, and the required data quality objectives for each specific
test program. Provisions are included in this test method that require the tester to determine critical
sampling system and instrument operational parameters, and for the conduct of QAiQC procedures.
Testers following this test method will generate data that will allow an independent observer to verify the
valid collection, identification, and quantification of the subject target analytes.
EPA Method 1 & 1A
The purpose of the method is to provide guidance for the selection of sampling ports and traverse points at
which sampling for air pollutants will be performed pursuant to regulations set forth in this part.
EPAMethod2&2C
This method is applicable for the determination of the average velocity and the volumetric flow rate of a gas
stream. The average gas velocity in a stack is determined from the gas density and from measurement of
the average velocity head with a standard pitot tube. Velocity readings are taken from each stack at 16
separate traverse points (Table 6.1) and used to determine the engines mass emissions rate, calculated
utilizing the formulas seen in section 7.0 of this report.
EPA Method 3A
This is a procedure for measuring oxygen (O2) and carbon dioxide (CO2) in stationary source emissions
using a continuous instrumental analyzer. Quality assurance and quality control requirements are included
to assure that the tester collects data of known quality. Documentation to these specific requirements for
equipment, supplies, sample collection and analysis, calculations, and data analysis will be included.
Gas, lnc.
4.0 Test Summary
Unit 1362 with a serial number of 1650569 which is a Waukesha 9394 GSI engine located at Duchesne
Data Center Power Station and operated by Crusoe Energy Systems, lnc. was tested for emissions of:
Carbon Monoxide, Oxides of Nitrogen, and Volatile Organic Compounds. The test was conducted on
1011112024 by Lewis Shirley with Great Plains Analytical Services, lnc. All quality assurance and quality
control tests were within acceptable tolerances.
The engine is a natural gas fired Rich Burn (4 Cycle) engine rated at 2500 brake horse power (BHP) at
1200 RPM. The engine was operating at 2110 BHP and 1200 RPM which is 84.38% of maximum engine
load during the test. The test HP calculation can be found on page 8. The engine was running at the
maximum load available at the test site.
This test will satisfy the testing requirements for 40 CFR Part 60 Subpart JJJJ.
Site Verification Photos
Gas, lnc.
Location Duchesne Data Center Power Station Unat lD 1 362
Mal(e Waukesha S te Elevation ft 5831 48
Model 9394 GSI Atmospheric Pressure psi 11.82
Serial Number 1 650569 stact( urameter rn,20
mfo. rated ho 2500 Gatalyst YES
mtq. rateo rpm 1 200 Date of Manufacture
Test Horsepower 2110 2110 2110 2110
TeSt FIPM 199 1200 1200 1200
Percent load"/"U4.36-/o 64.36"/o 84.38"/o 44.34"/o
lntake Manifold Pressure (hq)101.15 100 74 98 10 100.o0
lntake Manifold Temperature 1 't9.50 't20.60 123.80 121.30
Ambient Temperature Dry 49.00 b4.UU O I.UU c4.b /
O Stack (dscfh)1 54393.1 1 157571.29 125965.42 145976.61
Q Stack (dscm/hO 4371.89 4461.88 3566.91 4133 55
Moisture Fraction Bws 0.18 0.18 0.18 0.18
Method 3A Corrected O2o/o DN U.5670 2.52"/o .77o/"1.620/"
Morsture 9/o 1 1.62"/o 17.E1"/o 17.BE"/o l.ll-/o
4.0 Test 5
Gas, lnc.
6
5.0 Run Summaries
Table 5.1 Run Summaries
Gas, lnc.
Table 6.1. Data used for volumetric flow rate (Method 2)
Pitot Tube Coefficient Co(std)= .99
SracK otamerer = zu nches or:1.67 reet, or;2.'.t8 Square Feet
Hz.o o/od '17.62 17 8'l 17.88 17.77
c02 %d 9.41 9.49 9.48 9.46
o2 %d 045 2.O8 1.46 1.34
UU ppmd 32.45 37.05 22.68 30 73
Molecular Weiqht Stack Gas drv basrs (Md q/q mole 29 53 29.60 29.58 29.57
Molecular Weiqht Stack Gas wet basis (Ms q/q mole 27.49 27.54 27.51 27.51
Stack Static Pressure (Pq 'H20 0.40 0.42 0.27 036
stack stattc Pressure (Pg "Hq 0.03 0.03 o02 003
Atmosoheric Pressure at Locatron (Pbar MtsAH 83'l 07 632 UU 632 UU 831 59
Atmosoheric Pressure at Location (Pbar "Hq 24 55 24.57 24.57 24.56
Absolute Stack Pressure (Ps "Hq 24.58 24.60 24.59 24.59
Stack TemDerature Deq C 498 96 503 99 503.99 502.31
stact( lemperature ueq F 930.1 3 939 1I 939 1I 935 17
stack lemperature UEq H 1389 80 1398.86 1398.86 1395.84
Stack Gas Velocrty rusec 76.47 78.64 62.95 t3.uz
Stack Flow Bate Q cfs 166.83 171.56 137.33 159.3'l
Stack Gas Wet Volmetric Flow Rate scl/nr 187408.94 191705.4C 153382.55 178308.34
Stack Gas Dry Volumetric Flow Rate scf/hr 'I 54393 1 1 157571 29 125965.42 1 46630 38
tmtsstons samoltno Potnts - 3 00rnt lono ltne samoltno orob€lnches
First Samplrnq Pornt aken @ 16.7"/o ot Stack Drameter 334
Second Samolinq Point Taken @ 5O"/o of Stack Diameter 10
Third SamDlino Point Taken @ 83.3% of Stack Diameter 16.66
6.0 Volumetric Flow Rate Data 7
Table 6.2. Stack g?s pressure red
Aostd = Velocitv head measured bv the' standard p'itot tube, (in.) H2o '
s measured with a standard tube use for Volumetric Flow Rate
Figure 6.1
16 Traverse Points Were UsedStack Drameter (rnches)20.00
lnches upstream from disturbance 10.00
lnches downstream from disturbance 30 00
Pitot readings are taken for Method 2 calculations using measuring points outlined in Method 1
*The exhaust stack did not present cyclonic flow conditions at the sampling location due to the
absence of cyclones, inertial domisters, venturi scrubbers, or tangential inlets.
i*{c
- 6'1
!6 a'.
HUN I HUn Z HUN 3
apsro llnt Hzu Exnausr lemp r apsro iln, nzu =XnaUSI lemp I apsro ilnt nzu =xnausr temp I
Pitot Tube Samolinq Points (Velocitv)i.f ,Ii: ij,,i i i,iFii.l;iliiii
1 o.97 93't.UU 0.48 94U UU u2u 94U UU
2 0.88 930.00 0.35 939 00 u.z1 936.UU
3 0.34 929.00 0.36 940.00 0.26 938.00
4 u.to 929 00 o.21 VJ6.UU u.rc vsv.uu
5 o.24 930.00 038 956,UU o21 g4U.UU
6 o.29 931 00 0.40 940 00 u36 939 UU
7 0.35 931.00 0.50 940 00 0.34 940 00
8 0.17 930 00 065 939.00 0.30 939 00
I 0.53 930 00 036 939 00 0.'t5 94U UU
10 0.31 931.00 029 940.00 o.27 940 00
1 0.31 929.00 0.35 940.00 033 VJV,UU
12 o.40 v;zv.uu U.4U v5v.uu u.3t VJ6.UU
13 o.23 V5U.UU u.4t V5U.UU o.34 v56.UU
14 o31 95t.UU u.45 940.OO 0.36 939.UU
15 o51 930 00 u.55 938.00 o.15 94U-UU
16 0.35 931.00 u.55 939.00 o.28 940 00
Aostd Averaoe=040 930 13 0.42 939.1 I 0.27 939 19
Sample after Back Purqe 0.28
Wtthtn 57o ot LaSt ADstd readlnq:YES
Gas, lnc.
7.0 Calculations
Method 2: Determination of Stack Gas Velocitv and Volumetric Flow Rate
.Note- Use of this method neqates the need for anv fuel related numbers for emissions calculations
Ap(avg) = Velocity head of stack gas, mm H2O (in. H2O)
3600 = Conversion Factor, sec/hr.
A = Cross-sectional area of stack, m2 (ft2)
Bws = Water vapor in the gas stream (from ASTM D6348)
Cp(std) = Standard pitot tube coefficient; use 0.99
Kp = Velocity equation constant.
Md = Molecular weight of stack gas, dry basis, g/g-mole (lb./b.-mole).
Ms = Molecular weight of stack gas, wet basis, g/g-mole (lb /lb. -mole).
Ps = Absolute stack pressure (Pbar+ Pg), mm Hg (in Hg)
Pstd = Standard absolute pressure, 760 mm Hg (29.92 in. Hg).
Qsd = Dry volumetric stack gas flow rate corrected to
standard conditions, dscm/hr. (dscf/hr.).
Ts(abs) = Absolute stack temperature, oK ('R) = 460 + Ts for
English units.
Tstd = Standard absolute temperature, 293'K (528 "R).
Vs = Average stack gas velocity, m/sec (ft./sec).
Md = 44(%CO2l+.32(/"02) +.28(%N2+%CO)Md = 44(. 094)+. 32(.006)+. 28(.897+.003) = 29.525 LB/LB-MOLE
Ms = 29.s25(1 -.17617)+.18.0( .17617) = 27 495 LB/LB-MOLEMs = Md(1 -Bws)+1 8.0(Bws)
[s = Kp'Cp(std)-y'apavg.y'(Ts(abs)/( Ps' Ms))vs = 85.49'.99.1+.y'1r S8S.ZS5t(24.s8.27.49s)) = 76.47 FTISEC
= 3600(1-.176)76 .467'2.182((528'24 s8)/ (1389 795'29.92)) = 1 54333 1 1 DSCFQsd = 3600( l -Bws)Vs-A((Tstd.Ps)/(Ts(abs)-Pstd))
Q = Qsd/35.315 Q = 154393.109/35.315 = 4371 .885 DSCM/l-lFl
Emission Rates (Examples use CO Run 1
453.6= Conversion factor lb. to gram HP- Engines rated Horsepower
A = Cross-sectional area of stack, m2 (ft2). Mfg = yanrlrcturer Exhaust flow rate at 100% (ft3/min)
BHP/HR. = Brake work of the engine, horsepower-hour (HP-HFI.). 02 = Concentration of oxygen on a dry basis, percent.
BTU/HP-HB. = Brake Specific Fuel Consumption (HHV) ppm= Parts Per Million (CO)
ER = Emission rate of (CO) in g/1-iP-hr. ppm@'l 5% 02= PPM corrected lo 15"h 02
F(d )= ys;um.s of combustion components per unit of heat Qsd = Dry volumetric stack gas flow rate corrected
content, scm/J (scf/million Btu). to standard conditions, dscm/hr. (DSCF/HB )
Q = Stack gas volumetric flow rate, in standard cubic meters Run Time = Run Time in Minutes
per hour, dry basis Tpy= Tons per year
LB/HR = Emission rate of (Co) in LB/HR. Vs = Average stack gas velocity, m/sec (ft./sec).
Mol wt.= Mol Weight of CO (28 01)
ppm @ 15olo 02 = PPM.((20 9-15/"02)l(20 9-O2))ppm @ 15% 02 = 39.385.(20.9-1 5y(20.9-.6"/")\ = 11 447 PPM @ 15/" 02
g/trp-hr = (PPM'(1.1 64',1 0^-3)'Q'(Run Time/60))/BHP/1-rR (39.385-(1.164'1 0^-3)-4371.885'(Run Time/60))/2109.s08 = .095 G/l-lP-HR
lb/hr = ER'1 /453.6'BHP-HR LB/HR = .095'1 /453.6.21 09.508 = .442 LBlllR
TPY = LB/HR. -4.38 TPY = .442'4.38 = 1 936 TPY
1574'1.34022088
39.38 = 32.446s'(1 (1 -.1 8))ppm wet - (1(1-H2O) = ppm dry
Gas, lnc.
8.0 Oxygen Calibration 9
8.1 Calibration error test; how do I confirm my analyzer calibration is correct? After the tester has assembled, prepared and calibrated the
sampling system and analyzer, they conduct a 3-point analyzer calibration error test before the firsl run and again afler any failed system bias test or
failed drift test. They lhen introduce the low-, mid-, and highJevel calibration gases sequentially in direct calibration mode. At each calibration gas level
(low, mid, and high) the calibration error musl be wilhin i 2.0 percent of the calibraiion span.
8.2 lnitial system bias and system calibration error checks. Before sampling begins, it is determined whether the high- level or mid-level
calibration gas best approximates the emissions and it is used as the upscale gas. The upscale gas is introduced at the probe upstream of all sample-
conditioning components in system calibralion mode.
(1) Next, zero gas is introduced as described above. The response must be within 0.5 percent ofthe upscale gas concentralion.
(2) Low-level gas reading is observed until it has reached a final, stable value and the results are recorded. The measurement system will be
operated at ihe normal sampling rate during all system bias checks.
(3) lf the initial system bias specification is not met, corrective action is taken. The applicable calibration error test from Section 8.2.3 of EPA
Method 7E is repeated along with the initial system bias check until acceptable results are achieved, afterwhich sampling will begin. The pre-
and post-run system bias must bewithin t 5.0 percenl of the calibration span forthe low-level and upscale calibration gases.
8.3 Post-run system bias check and drift assessment - confirming that each sample collected is valid. Sampling may be performed for multiple
runs before performing the post-run bias or system calibration error check provided this test is passed at the conclusion of the group of runs. A failed
final test in this case will invalidate all runs subsequent to the last passed test.
(1) lf the pos!run system bias check is not passed, then the run is invalid. The problem is lhen diagnosed and fixed, then another calibration
error test and system bias is passed before repeating the run.
(2) After each run, the lowJevel and upscale drift is calculated, using Equation 7E4 in Section 12.5 from EPA Method 7E. lf the post-run low-
and upscale bias checks are passed, but the low-or upscale drift exceeds the specification in Section 13.3, the run data are valid, but a 3-point
calibration enor test and a system bias check must be performed and passed prior to additional testing.
Table 8.1 Oxygen Calibration
Method 7E 3.4 To the extent practicable, the measured emissions should be between
20 to 100 percent of the selected calibration span. This may not be practicable in some
cases of low concenlralion measurements or testing for compliance with an emission
limit when emissions are substantially less than the limit.
EPA Method 3A CIA Worksheet
Cortllled Gr! Concent eion I Certr'fled Gat Concentr.lon I Cenmed Ga! C(Low.hvrl ('6) I t{ld{.evel (%) I Hbh.L.v.
""r",(DIRECT) Analyzor Calibrafion Error (S 2%)
Check 7E 8.5: Nole: that you may
risk sampling for multiple
runs before performing the
postrun bias provided you
pass this test at the
conclusion of the group of
runs
Certifiedn^ffilEti6h Dir€d
Calib'rationR6ponse (%)
Absolute
OifferDnco (%)
Analyzer
Calibralion
Enor (%)Valuc (%)
Zero Gas %0.00% 0.00%0.000/o 0.QQo/o
Mid-Level Gas o/o
High-Level Gas %
10.62%
21.'.120/o
10.65%
20.79o/o
0 03%
0.33o/o
0.160/o
1 .550/o
(SYSTEM) Calibration Bias Checks (s 5%) and Drift Checks (s 3%)Upscalc Gaa 1o.B2%
Zero Oflset 0.000/o
Bies Pre lnitiel Value Bias Post lnital Value8Span 21.12
Analyzer
Calibration
Response (%)
Zero Gas 0.000/o
Systom
Calibfauong
Rcaponso Pre
Vrl
SysEm Biar (ol
of Span) Pre
Syst6m
Calibration
R€sponse Post
(%)
iysbm Bias (%
of Span) Post
Dritt (0/6 of
Span)
0.00%0.000/o 0.00o/o 0.000/o 0.00o/o
Upscale Gas 10.650/o 10.79o/o 0.630/o 10.560/o 0.44o/o 0 01%
(SYSTEM) Calibration Bia3 Checks (s 5%) and Drift Checks (s 3%)
Avo. Gas Concentration (Run'l)0.56% Emuent Gas (Coas) Run 1 0.587o
Avg. Gas Concentration (Run 2)2.9%Effiuent Gas (Cgas) Run 2 2.520h
Avg. Gas Conc€ntration (Run 3)1.78Vo Emuent Gas (Cgas) Run 3 1.77%
EPA Method 3A QA Worksheet
Zero Gas 100o/o Nitrogen
Mid-Level Gas 10.620/o
High-Level Gas 2',|'t20/o
Zero Gaso/o
Mid-Level Gas o/o
High-Level Gas o/o
zero Gas y" l-;A-l upscatr used
upscare car I ,o?g"zo I io.62o/o
zero Gas % I o;A-l upscat. us€d
upscate cat l-l0 s6%.-.| 1062o/o
Gas, lnc.
Companv Crusoe Enerov Svstems. lnc
Facillty Duchesne Data Center Power Station
Date 10.111t2024
slte Etevation (ft)563't.46
unit lD 1362
Make Waukesha
Model 9394 GSr
Seraal Number 1 650569
Technlcian Lewis Shirley
9.0 Engine Parameter Data Sheet
AS
Completed
Gas, lnc.
Run Start Times U/.46 AM o9:o4 AM IU:IC AM :36 AM
EnElne Hours 1 662 1 663 1 664 1 665
EnElne Parameter Data
Flun 1 HUn Z Bun 3 Averaqe
Enqine SDeed (RPM)1199.0 1200.0 1200.0 1 199.7
lntake Manifold Preesure (psi)bt.5 b t.u 6U.O 60.9
lntake Manifold Temp "F 19.5 I zu.b 123.6 121.3
Enqine Load (EHP)z-l u9.5 2109.5 2109.5 2109.5
Ambient Temp "F 49.U 54.U 61.0 54.t
Humidity 70 36.0 32.U 25.O 31.0
Dew Point "F 23.0 24.t)25.O 24.O
AFR Manufacturer/Tvoe Waukesha Waukesha Waukesha Waukesha
suction Pressure o.0 0.0 U.U U.U
Dlscharqe Presaure 0.0 0.0 U.U 0.o
Gatalyst (Yes or No Yes
Catalvst Manufacturer Miratech Miratech Miratech Miratech
# ot Catalyst Installed ,|1 1
cataryEt lnlet Temp "F I U6t.U 1080.o I U/b.U I U/V.U
Catalyst Outlet Temp "F 1098.0 1098.O 1090.o I U95.3
Catalvst Pressure Drop H2O -6.0 -6.0 -tj.U -6
11
10.0 QA/QC Results
Nitrogen monoxide NO
Nitrogen dioxide N02
NOx
VOC
Oxygen
Average:0.00
Average:0.13
Average: 0.16
Average:0.30
Average: 0.18
Average: 0.11
CTS Bottle Concentration
CTS Compound Concentration Avg
Tolerance
Difference between measured and expected
Value: 100.30
Value:99.99
2.00%
o.31%
Nitrogen monoxide NO
Nitrogen dioxide NO2
NOx
VOC
Oxygen
Average:0.65
Average:0.00
Average.0.65
Average:0.62
Average.0.13
CTS Bottle Concentration
CTS Compound Concentration Avg
Tolerance
Difference between measured and expected
Value: 100.30
Value: 96.94
5.00%
3.35%
Equilibration Response Time
Spike Reported
Spike Expected
I seconds
Value: 249.55
Value: 252.40
System Response Time
Gas, lnc.
12
11.0 D6348 Annexes 1-8
The test quality objectives completed for the emissions test are demonstrated throughout Annexes 1,2,3,
4, 5, 6, 7 & 8 as layed out per ASTM D6348-03. All reference methods, pre-test and post test procedures
were within acceptable limits. Data generated during the pre-test and post-test procedures are
summarized below in order of the distinctive Annex.
Three 60 minute test runs were performed. The final analyte concentrations are the average of each test
run. Data was taken at 60 second intervals. Each 60 second measurement was the average of 600 scans.
Propane is used as the surrogate compound for the Annex 5 Spiking Technique due to Propane being the
VOC that is most commonly found in the combustion process of natural gas. Additionally, the molecular
weight of Propane coincides with with molecular weight of VOC's per the EPA.
Annex Table 1.2.1 Certif ied Calibration Bottle Concentratione
Eottle Expiration NO2 Ethylene SF6 92 l'/ol
cc506322 9t1712027 uu qh 10.62"/"
12t1t2025 100.30
cc406148 4t15t2032 21 .12"/o
Cylinder # ALM-063647 Expiration: 5-03-2032
Propane GO NO sF6
tsonte vatue 252.4U 5U't. /U 237.50 10.20
Analvzer Svstem Besoonse 249.55 494.O2 235.66 10.'t 3
Percent Difference 1.13h 1.53o/"O.77o/"O.70"/"
Annex Table 1.2.2 Measurement System Capabilities
Gas, lnc.
Annex Table 1.3.1 Test Specific Target Analytes and Data Quality Objectives
. VOCs compiled of Acetaldehyde, Ethylene, Hexane, and Propane.
02
SENSOR
PSS PROBEITT*[[t
{iAS[{I
FTIR
PATEL I
ry
GT.S
FI OW
ITTR.stt EhT
Figure Annex 1.4.1 Sampling Train
The testing instrumentation is housed in an enclosed vehicle which is located approximately 45 feet from the source. A
heated sample line (sixty feet in length) is attached to the inlet of analyzer system and the source effluent discharges
through the FTIR outlet.
Compounds
lnfrared
Analysis Region(cm-l)
Expected
Concentration
Range
Measuremenr
System
Achievable
Minimum
Detectable
Concentrations
Hequrreq
Measurement
System
Accuracy and
Precision forfest Aoolication
CO 2000-2200 0-'1200 oom 0.16267 DDm 4 Dom
NO 1 875-21 38 0-1000 ppm 0.4007 Dom 2 DDm
N(J2 2too-2950 0-'t00 ppm u.4uvv oom 2 ppm
VOC
2600-3200
0-100 ppm 1 8520 ppm Total
VOC's 1 ppm per VOC91 0-1 1 50
2550-2950
H20 2550-2850 0-100 oom 0.7878 oom 1 oom
lnterlering
Compounds " CO is analyzed in a separate analysis region than CO2 and H2O
a02 926-1 1 50 O-1Oo/"OY"nla
Water Vapor 3200-3401 0-22%0.20"/"nla
S?ACX
DA-A
Gas, lnc.
Sampling Point Locations
in lnches
16.7"h 3.34U
5Oo/o 10.oo0
83.3olo 1
ElrilF
HEo
bfr.)
t6
(
HtrJI<fo
!
u!
E
TRI-PROBE SAMPLE POINT LOCATONS
AS PERCENTAGE OF STACK DIAMETER
Figure Annex 1.4.2 Sampling Points
lnterior Stack Diameter (inches): 20
lnches
Upstream:
10
lnches
Downstream:
30
SAI{PLE PORT LOCATION DETERMINED
gY DISTAhICE FROft{ BSTL'RBANCE
Figure Annex 1.4.3 Sample Port Location
Gas, lnc.
Target Analyte Results (ppm)
CO o.1621
NO 0.4007
N(.)2 0.489S
tlnvtene u.3 /62
Propane 0.435'r
Hexane U.223i
Acetaldehvde 0.8152
Formaldenvde 0.787t
N Ii;l
R t; t-'
I
\
j r i*:'r (N t;A"i')
.,i,: X ,* "' r ( rr ,-' ,-'",' )'
N li;l 't' /'LrDcrt I t''rt|II-! - 1'l':L I:'-::t
Iit.'t; 'tt I.,.tt,-rrt \'
,rl
l rrt.\
Annex 3.
Calibration Transfer Standard Expected Measureo Path Lenqth vaIoaleo
Ethvlene 100.3 99.99 4.985 PaSSed
4.est
Annex Table 1.2.2 Measurement System Capabilities
Parameter
Measured Gas Goncentratron{ooml Path Length Equilrorauon
Time Dilution Factor 7o Recovery
Path Lenqth Ethvlene 99 992 4 985
Sprke Direcl
Propane 252 638
SF6 lU 34t'
(,(-)509 301
NO 242 046
Mechanical
Hesponse Time Ethylene 96 945 20 seconds
Analyzer
Response
Prooane 249 554
8 secondsSF610.1 29
CO 494 022
NO 235 660
Analyte Spike
Recovery Propane & SF6
9 19"/"95 08%
I 36%94 45"/"
8 97"/"98.44"/"
SVSICM ZETO Nrtroqen 2 seconds
Post Spike
System
Hropane 246 AA4
CO 501 172
NO 232 993
SF6 10 020
Gas, Inc.
Parameter Gaa concentration Meaaurod 70 Dlffsrence Speclflcatlon Valldated
Spike Direct
Propane z52.4UU 252.63tl 0.09%+l- 2o/o PaSS
SF6 10 200 10 346 1.43%+l- 2/"Pass
CO 501.700 509.301 1.52/"*l'Z-/o Pass
NO 23/.501)zcz.o40 1.91"/o 1l'2"/o PASS
Splks Run 1 vla the System
Source Outpul Spike Average Dalution Factor Expected 70 HeCOvery specilication
Propane U.ddU 22.340 23 495 95.080%7O'13O"/o
SF6 o ool o.951 9.192"/o <1Oo/"
Splke Run 2 vla the System
Source Output splke AveraEe Dalution Factor Expected 70 ReCOvery Specilicataon
Propane U.UUU 22.314 23 625 94.45U'/o 7O-13Oo/"
SF6 o.oo1 u.9b6 9.356"/o <1Oo/"
Splke Run 3 vla the System
Source Output Spike Averaqe Dilution Factor Expected 70 Hecovery SDecilication
Hropane U.UUU 22.286 22.640 98.44Qo/o 7O-13Oo/"
SF6 U UUz 0 92tl 6.9/U"/o <10"/o
Noise Equivalent Absorbance (NEA)
RMS High 0.003129
RMS Mid 0.002253
RMS Low 0.007873
v
03
02
01
00
01
Line Position
2 069 2046 2023 r999 I 976 1 95i 1 930
Gas, lnc.
@ o.ooo/o Pass
The Gasmet GICCOR (Genzel lnterferometer with Cube Corner Retroreflectors) interferometer is specially
designed for maximum opticalthroughput and maximum signalto noise ratio of 7.72 (cm-1) remaining
stabte with any vibration and temperature changes.
is a low spectrometer aperture to a maximum ang
setting and the detector linearity was tested with an alternate approach. A three point linerarity of the CTS
gas was performed and validated.
Linea rity
32 0032
23 0032
14 0032
5 0032
-3 9968
1 2 9968
21 9968
30 9968
39 9968695 687 679 672 664 656 648 641
32 0032
23.0032
14 0032
5 0032
-3 9968
-12 996r
-21 996{
-30 996{
-39 9961633 625 61 8 61 0 602
.003652352 Pass
The analytical accuracy of the quantification algorithm is satisfied via the results from Annex 5 per Annex
7.6
POST CTS Svatem Check:
CTS Bottle Concentratron:I UU.3U
u t5 :iamote uoncenlralton Averaoe:96.51
urnerence Detween measureo ano exoecleo:3.92"/o
Tolerance:5.00"/"
Fun Data Valldauon - Automated v3 Manual Hgadlnq valkhted commentS
Run 1 Points 1 & 2 on CO/NO/Propane All within 20%Passed Demonstrates no rntefierences observecl_
Run 2 Points 1 & 2 on CO/NO/Propane All withrn 20%Passecl uemonsrrales no rnlenerences oDServeo.
Run 3 Points 1 & 2 on CO/NO/Propane Allwithin 20%Passecl uemonslrales no rnlenerences oDserveo.
Gas, lnc.
12.0 Signature Page
Job/File Name: Crusoe Energy Systems, lnc.; Duchesne Data Center Power Station; 1362; JJJJ
We certify that based on review of test data, knowledge of those individuals directly responsible for
conducting this test, we believe the submitted information to be accurate and complete.
Company: G.A.S. lnc.
Print Name: Lewis Shirley
Title: Emissions Specialist
Date:1011112024
Company:
Print Name:
Signature:
Title:
Phone Number:
Date:
Company:
Print Name:
Title:
Signature:
Phone Number:
G.A.S. lnc.
Travis Hartley
Director of Stack Testing
-i---'*b -
580-225-0403
Date: 1011112024
Gas, lnc.
Appendices
Spike (5 Gas)
tlrr.r:\D(Lll, (i.rt
.triFrt'1.\llr
l: i:: I lllhr r'lh l\i
( htr.lr(ll ..h:x
{ rrErr r.nt
CERTITrcATE OTANALYSIS
Grrde oJ Pnrducl: EPA PROTOCOL STAIIDARD
C!.{amr G,{.8AI FrArrEABAIYI lc^t EC{V€EFrf taxtr
CFr{.r l*lr6a
LlMtSry
P(IYP ltturio.r6dC{d.'
coar{rDa€ rr^coralltr{6toatll'{ ' c,x.eeE IS.AP, lL
e120lrco co, iao Hox PPr{ EAIH
RrFml1lo 9r"a{ttolln3.t
C'lnd!. \DUr !{? D
Crb.do Frnru'r ,Dt5
\hrG otdr( fdo
CollicoEa0t Urrm lq}ll
EryIftn Olb: tlry 0t 2OIl
crttt-rr Fhrd n' rffi. - t4 t.rr-uDlote nr raq -ac.rihau ol6-s (ltr&,, s.da il.t iYrll'di6d t.fra6l{.!:6tf rS0lllrtrtrala.trttttta A/crt.aLdrc(b.)Ot<rdl!'n(6(lgrrJld,llaall,rtym f.lrorrltiEralut tatttfir}raf nrlai Eaix rl t (turra.fa td st ltt tre n ry rrra(e'l rrt|qrlr iath atdthr r d tE (at dsl d.i[ Aa qaTBabrr a F t N/Dnr ittsmfl-r,frti.drrtarffi(bhhEFn.rirddrdEahqrutrd.Drpl.rlrrteltFrddr.lJUGyOgltavrflrClrharbrr rtjr.{ r. O!n fir.Jt
.rs At.t-Tt( .tL nt:5t l Tlt
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V. r,: ,!lr
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sa)\-f,tA,t\,tl,t-n( AL nr:!il l.Ts
Iti.a lht.lrrl* f rd ll{Ea
Ulrara c(rtm. .rmrre t*(a $rur 'tirriryl|a i a t dt t ct !arv-{ Aa.tutl b.td rta rE ,*0 .nra tr rrrrrr\.l Ctfirll{& rrl Ad;tlr
Cnfxl hr lrsrl I rtp,t:ril,! ( 7 irnrd I rGerrld 3f 0 & 10:0 FFtl
lllnahlrr m tl
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:q..rrtu .:r'rrtg ,,r .'r.\7t'lt,r,r- .:.1?u\llrl...r't r4lflr;r,.,,r.\):r
lrl "\ll'l :q.6F\, :r" lru ,,r 'F-\isI I,r,.. ;'^lfrl\D[ l,r.t. rs-'4.r,:.'',rr:,:.
\\l l\.r'rrH l1l.r?1, r,r ,n.\arl lr..r& llf71l\lll Jr.dr l{}r-\r.'r
\nltA ll'tu|\l;l lr.urlv '{. 'PtU r,r r}'.\61 Lr,rr} ' lfP\r\l}I i./*r '.nh' :,r:.
lllt^ l*Allr t,,,:'. ,.1 r ''-\hr l',,'r! !r'.\l!t l,.,Jlr ru) .r,lr
l- ll,
lr \,!:r:rt.'u
ldl-
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:.rr. ttr \ilXh (l(rl (..lllr.t \
I rr, ItV :,Jilr.\,t \ ;rf r'lt{ \rlIq,l I
r r FU\rtltrr,l\flla^:rl tlt
.'. i I tll Lr rI\\l I l
ar I r |f\l | \rjir\ u^tltlul $lt.rJ r
' a.r', I \lEl\(rI r\lll !llll r.i \
i:
I lert i -atD rlt !v J,-a
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l, tl l.h' I
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!)*M'rlttl lltt -rtt.Alrr.drr-..,,l. r,ru.r.si!h t.tl6vd,r&.rrr rJrlo,.tu.d,'i
Gas, lnc.
9% O2|NO2
llrtrr !tr-l.lt) tlE.trrrr I \{ lll'
h1I I -J6! liill
itrrlirltr \t.'__lI
U,r.. . (
CERTI FICATE O F ANALYSIS
Grade of Pruduct: EPA PROTOC{)L S'IANDARI)
Plt tlu;brr
Cy'hder NumDer
Lfiorstry
PGI'P t{uro.(
Gar Corb
EO3rlr8Sl5Wm20
cc3063?-2
12{ - Otrrsn (SAP} - r{C
BZ2o21
N@.02,8Ar"H
Rabnncr l'Lmbor. t 22i03l3t$r7, !
CylndrVrldme tf53CF
Cylrx,rr Prc++rrc 20tt PSl6
Vska Ov0ol 660
CGrblc.too DaE S*p t7 ?O?l
Oa.:
l-qdCdAtD.orhre :ErXlrr'&fffOX Ul)l s.rtlb -q 9rBd.. nE kfurbdogr bd A.', :da t -rrElnr(rn.r hr,1fr* t rhddrdisffr - rs! ffi r. a (dl-{.bt d t!\ ?ta.,rratt (an rtrrih -r, Jrr.J h irta i.alr*s ftLo a /-G.rl,ffi tt c a&aYr.lrBr,-tsxx tbMratl,rf r.ir,ftHr, !.a.rpirrlrr^chrlF!tu.ia*lrnlr.G,!, Ivf,rtE{uaE t}rHhln^Cfilh:S.3'. 0, mr.d
riaat oaa Aval5a lr1lIt n eorat
Apprffod lor R.l..a.tri'tCl
I\\ALITICAL RIISULTSR.eorid a.hd Proaocoa falfulttvr
ratffIrErtlgroE lDoC,F*U glr%tfi',t a\ ..- I !\;trtsl 7,t$6 {r,.1O.!i.r.)r .J}1r:It,it
DTYCE\ 10€4\ l0fj\ r:1 '..1:a'rlrl!?'r{tt tfl0rc:{
HtftooEt Ere
CALI BN^TION $TAN DANDS
Ld lO Cytlxlr to Corrltrnolr Uncrrdnt7 kpar.Dflr ht
Gavss rll.o0tQi{rxtt (ttln'n l0(1 .&tu|,iqu.itHchcucf 'rarr.t)ax .l
}{ilr CJ'&riNt tr Lr!!-r.raa r, 0l p(+r M tllfxari O{(]XCL AJr{rJwg rLwj{r?olaioo OC1r\lr,:r! q9ti.ppurllrr(rifHOr()rrif'^tg
}l1.lr, lE,rDE Xl*r'ttatt cltt\Qnrd|airfRDctti
Its 9t hlafl laly r.lel rl-.{ !i. r arlr r,rdilu L tr /iU6 [d n h lar -d tur ti ol tD tarr
I U\
:r ,1
U't 0I 1!?,ivi ;I r lrlla
A{t L ,a.IJt
ur r? iflill
ANALT'nC'AL LQU r Pil H:Yl'
Gas, lnc.
Alruas
Ethylene Only
AirSas Specirlt! csse6
Airgas USA LLC
12722 S. Wents.orih Ave.
Chi@go, IL 60628
Airys.com
CERTIFICATE OF ANALYSIS
Grade of Product: PRIMARY STANDARD
GREAT PLAINS ANALYTICAL SERVICE,Customer:
Part Number:
Cylinder Number
Laboratory.
Analysis Date:
Lot Number:
x02Nt99P1 5ACVH8
cc325720
124 - Chicago (SAP) - lL
Oec 01 , 2022
54-402603460-1
Expiration Date: Dec 01,2025
Reference Number:
Cylinder Volume:
Cylinder Pressure:
Valve Outlet:
54-402603460-1
144.0 CF
2015 PS|G
Primary Standard Gas Mixtures are traceable to N.I.S.T. weights and/or N.I.S.T. Gas Mixture reference materials.
Component Req Conc
ANALYTICAL RESULTS
Actual Concentration
(Mole %l
Analytical
Uncertainty
ETHYLENE
NITROGEN
100.0 PPM
Balance
1OO,O PPM +l- 1o/"
Approved for Release Pagel dl
Gas, lnc.
rhIG
r il lrl.4a ,;@ae
BIP
llrtrr ttEl.ltt (:8.
$[rr I \A lll'
b?[ I rdnJ lhlr]
litrh.!tr \t'rt:l
bp.,.fr
CERTIFICATT OT BATCH ANALYSE
Grrde of Product: CEM-CALZEIIO
Pst Nu,r$c{
Clfnd.r Ardyrtd
L*orarry.Andnr Oats
Hrczm
APRolNCSGAESzggA
t2a . Drhflr ISAP). NC
F6D 12. z0ar
Rols.|x,t l$unb€r 122{0AC0l8,ltl
Cy'trdG, Vdrrtta. 3Oa 0 CF
Cy'rrdct hrrrlrr:. 2840 PSlg
V.les (},nbl 3O0
Coilronfil
AITIALYTICAL RESULTS
l.qilrylRry C.rtt aConcdr.tbo
illrRoGEr{
NOr
so2rHc
crasoil NoraoxrDE
crF60ri oroxlo€
9$ Sd3.r
D 1Fru
O T PPf,I
0 I PlPu
0.3 PPM
I D PPf,I
s 9016 *<tDT O fi PP1M(Ltlt 007PP$
<LDL O OO PFII< OTPPM( oIPPM
hffif t{da.!Arg!r rc'taor $f lh. ciltdr ol llrr cr'thdd macl fr. trqJtm.rtr ol aO CtR
r?]qiad..r 5 Stien:
193$&lV /.(lffi,5G671ltY
^PR()aNCS6660I99A
COt!4{0, 1103!610, f lellG FLgt}$, lu)Isf*l
rm2ain. ttlcou ?frl'tog. 198)10 t3 TwB}ts19!y
trqxrnbH \frrttld o0anrl ,r.ltlf,rl rlIltilrrr t!<!d. E NBI tv rs(fi arxl,(, rnltr!
A,P.oitrx! lorRrlor tr!' l.a I
Gas, lnc.
21% 02
llrtrr tEl.tl, (lE.
tnifi L \\ IJI
'>jj l\rh lel'trtrr.l 1...1' 8..,rrI'irli tIitrr'r
CE,RTI FICATE OF ANALYSIS
Grade of Prcducts EPA PROTOCOL S'IANDARI)
ftrt Hurflbcr
Cy'a(,or Nunoor
LSorsttry
PGV? tturnbor
Cgr Codo
Eoa'll7*15^OOBr
cc{06rtE
t24 - ?omlc ISAPt . Ul
r,7vfi4
02,BALN
Rofotcoco Mrmbol l53 aO3Ot89?1.1
Cy!.xh, Vc.rme la6 0 Cf
Ct'tsroar PrGJ6l,E ?015 PSIO
Vnlvo Ou!:( 590
Ccrlfrtabo(l Dill, Apt !5, 2S?'{
ird-r r St fr d. a (fflt{.51d 9!\ f !a..rra4rrra( &r{ar r.^ fut H drra d&tr et'e .. /-*ii,&6 aa s al#aHr.e'I6ft-r'lI th*[,*h,rq!rn.,frHj ?!bFr4ria..d].,phdaathldfirlrBrhdtE{dan l.}r
fi- OL /lvtld. lreql E err..l
Aggrorrd lor Rdcor hFrCt
C..rvGrrrl n.qu.{.{tC{lc titlbn
r\\AL1'IICAL RIXULTS
Achld ProtocolCrtcaolraLn bl'roa loael Fdraln
t nc.d.hiy AarryOtt ]
ot \'r-t l t G) a
U:nCxjE { !&rrr
or .C5\hSIr!rrrt ltn5--rl.\a
CAll EIIATION STAN D.,UTIEfpr L.a O Clrari!.r il. Carcrri.aDoo lhcrl.lnly Errt aL.l DrL
Xrfi$ m6l{fa Ct':l:.a, l, $ a Crycf.trtlltl(|G€r\ C a.r,M.r I I ;0.13
hrtnmdJltdXodd
,rNALt-nc,tL t:QU I Plt ElTt
ArrrrrEaltt4h Irtln Fdil ce$brha
tt.l;. UP,r{, fO rttarlu,tar{ Ol rliF 'r1@( tDluJV ^ar 0I ]Xia
Gas, lnc.
Ges
Great Plains Analytical Services
303 w 3" st
Elk City, OK,73644
(580)225-0403 F ax: (580)225 -2672
CERTIFICATE OF ANALYSIS
Grade of Product: CERTIFIED STANDARD-PROBE
Part Number:
Laboratory:
Analysis Date:
LOT Number:
SN:
201
GAS INC.
3t3t2022
A
22420L
Reference 22
Number:
Stack Diameter: 20"
Target Flow 3Umin
Rate:
Number of 3
Points:
Product performance verified by direct comparison to calibration standards traceable to N.l.S.T.
*The probe listed on this form meets the multipoint traverse requirement of EPA Method 7e,
section 8.4 as shown in the accompanying data. Method 7e. section 8.4 states that the multipoint
traverse requirement can be satisfied by sampling via "a multi-hole probe designed to sample at
the prescribed points with a flow +/- l 0 percent of mean flow rate".
ANALYTICAL RESULTS
Total Flow
(t/ml
Measured Flow Measured Flow Measured Flow Mean Pmbe
Port A (Vml Port B (Vml Port c (t/m) Porr Srmpled
lDelta o1l (Delta o2l lDalta o3l Flos (L/m)
Run I
Run 2
2 LPM
4 LPM
0 680
(7 s4A )
ll5
(7 r4A)
0 620
(-r sea)
123
(-2 18A)
0 590
(-6 35A)
120
(4 ?6A)
0 610
'I 26
rCalibration conducted in accordance with Emission Measurement Center Guideline Document - EMC GD-031
3/3/2022
DateApproved for Release
t-UI{ITEO STATES ENVIBONMENTAL PROTECTION AGEHCY
fiE-\EAHLH ilttAN,Si-E r'AItH N(_- ;)7711
March 15"2021
;l I i
,r\lir ;r!1, l. i r r.lil,rllrr
lrll ,.,,u. J.t,..
Mr. Jordan Williamson
CEO
GAS lnc.
303 W. 3ra Street
Elk City, OK 73644
Dear Mr. Williamson:
We are writing in response to your letter received on September 17.2020, in which you request the approval
of alternative testing procedures. The EPA's Office of Air Quality Planning and Standards (OAQPS) is the
delegated authority for consideration of major alternatives to test methods and procedures as set forth in 40
CFR parts 60 and 63 under which your request must be addressed. GAS Inc. is requesting a change to one of
the test methods, ASTM D6348-03, used for conducting performance tests to determine compliance under
40 CFR part 60, Subpart JJJJ - Standards of Performance for Stationary Spark lgnition Internal Combustion
Engines (Subpart JJJJ) and 40 CFR part 63, Subpart ZZZZ - National Emissions Standards for Hazardous
Air Pollutants for Performance for Stationary Reciprocating Internal Combustion Engines (Subpart ZZZZ).
The change being requested will be used to check detector linearity of the Fourier Transfbrm Infrared (FTIR)
instrumentation used to conduct this method. Specifically. you are requesting that the procedures of section
8.3.3 of Method 320 (40 CFR part 60, Appendix A). another FTIR-based method allowed under Subparts
JJJJ and ZZZZ. be used in lieu of section A6.4.1of ASTM D6348-03 when conducting testing using ASTM
D6348-03 under 40 CFR part 60. Subpart JJJJ and 40 CFR part 63. Subpart ZZZZ.
In your request. you state that this alternative linearity check procedure will produce consistent results when
utilizing either Method 320 or ASTM D6348-03. Additionally. some FTIR instrumentation does not allow
for reducing the size of the aperture in the instrument and. thus. it would not be feasible to properly conduct
the entirety of the ASTM D6348-03 method in its current form using such an instrument.
Based on our understanding of FTIR instrument principles and recognition that the requested alternative
determination of detector linearity is both technically sound and contained within Method 320, we are
approving the requested change. We believe that this altemative is acceptable for use for use in testing all
engines subject to 40 CFR part 60 Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. Also, we will post this
letter as ALT- l4l on EPA's website (al u,ww.epa.gov/emc/broadly-applicable-approved-alternative-
lestmethods) to announce that our approval of this alternative test method is broadly applicable to engines for
the purposes of meeting Subparts JJJJ and ZZZZ.
If you should have any questions or require further information regarding this approval, please contact David
Nash of my staffat 919-541-9425 or email at nash.dave@epa.gov.
Sincerely,
STEFFAN Digttally slgrnd by
srEFFAil
'or{h$ofriJOHNSON ffi,'#lf.lJ'
Steffan M. Johnson, Group Leader
Measurement Technology Group
Sara Ayers, EPA/OECA/OC/MA MPD, (ayres. sara@epa. gov)
Melanie King, EPA/OAR/OAQPS/SPPD, (king.melanie@epa.gov)
James Leather, EPA Region 6, (leatherjames@epa.gov)
David Nash, EPA/OAR/OAQPS/AQAD, (nash.dave@epa.gov)
Lewis Shirley
GAS, lnc.
580-225-0403
info@gasinc.us
Type of Sources Tested:
Stationary lnternal Combustion Engines. 4 Stroke Rich Burn Engines. 2 Stroke & 4 Stroke Lean Burn Engines
Stationary Natural Gas Fired Generators
Stationary Propane Fired Generators
Gas Fired Boilers
Types of Analyzers:. Gasmet DX4000 FTIR. Gasmet Portable Sampling Unit with Zirconium Oxide 02 Sensory. Testo 350. Flame lonization Detector
Qualitications:
Trained, studied, and fully demonstrates compliance for emissions testing via data collection outlined in the
following Reference Methods:. EPA Method 1 & 1A - Sampling & Traverse Points. EPA Method 2 &2C - Velocity & Volumetric Flow Rate of a Gas Stream. EPA Method 3A - Oxygen. EPA MEthOd 7E - NOX. EPA Method 10 - Carbon Monoxide. EPA Method 25A- Volatile Organic Compounds. ASTM D6348 - Extractive Fourier Transform lnfrared Spectroscopy
Conducts emissions testing on a weekly basis including, but not limited to, the following test types: lnitial
Compliance, Biennial Compliance, Semiannual Compliance & Quafterly Compliance. Alltests performed
are in accordance to any and all Federal & State requirements as applicable (i.e. JJJJ, ZZZZ, 106.512, 117,
PEA, etc.). Performed testing in Colorado, Utah, Wyoming, North Dakota, Montana, Kansas, New Mexico,
Oklahoma, Texas, Louisiana (land and off-shore), Arkansas, Ohio, Pennsylvania, West Virginia, New York,
Kentucky, & Mississippi.
. Quarterly Performance Beviews covering ongoing changes with Federal Regulations, State
Compliance guidelines, & site-specific safety certifications.
Gas, lnc.
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Run NOx ppm %O2 PPM @ 15% O2 PPM @ ISO lb/MMBtu lb/hr g/hp-hr
1 10.077 0.30 2.89 0.05 0.00000 0.12467 0.02588
2 10.042 0.27 2.87 0.04 0.00000 0.18660 0.03874
3 7.380 0.43 2.13 0.03 0.00000 0.11617 0.02412
AVG 9.166 0.33 2.63 0.04 0.00000 0.14248 0.02958
Run CO ppm %O2 PPM @ 15% O2 PPM @ ISO lb/MMBtu lb/hr g/hp-hr
1 37.925 0.30 10.86 #DIV/0!0.00000 0.28564 0.05930
2 35.214 0.27 10.07 #DIV/0!0.00000 0.39836 0.08270
3 26.309 0.43 7.58 #DIV/0!0.00000 0.25211 0.05234
AVG 33.149 0.33 9.51 #DIV/0!0.00000 0.3120 0.06478
Run VOC ppm %O2 PPM @ 15% O2 PPM @ ISO lb/MMBtu lb/hr g/hp-hr
1 1.00 0.30 0.29 #DIV/0!0.00000 0.01188 0.00247
2 1.15 0.27 0.33 #DIV/0!0.00000 0.02045 0.00424
3 1.23 0.43 0.36 #DIV/0!0.00000 0.01859 0.00386
AVG 1.13 0.33 0.32 #DIV/0!0.00000 0.0170 0.00352
Run HCOH ppm %O2 PPM @ 15% O2 PPM @ ISO lb/MMBtu lb/hr g/hp-hr
1 0.00 #DIV/0!0.00000 0.0000 0.00000
2 0.00 #DIV/0!0.00000 0.0000 0.00000
3 0.00 #DIV/0!0.00000 0.0000 0.00000
AVG #DIV/0!#DIV/0!0.0000 #DIV/0!0.00000 0.0000 0.00000
Operating Parameter R1 R2 R3 AVG.
Engine Load %87.38 87.38 87.38 87.38
Fuel Feed Rate (SCF/hr):#DIV/0!
F-Factor;#DIV/0!
Engine HP 2185.00 2185.00 2185.00 2185.00
BSFC (BTU/BHP-hr):#DIV/0!
Q Stack dscf/hr 103565.79 155552.98 131767.18 130295.32
HHV #DIV/0!
Ambient Temperature (F):#DIV/0!
Analyte High Recovery +- 10% Gas Value System Response % Recovery Pre Direct Response % Recovery Post System Reponse % Recovery
NOx #DIV/0!#DIV/0!#DIV/0!
NO2 99.95 0.00 0.00 0.00
NO 237.50 238.04 100.23 238.18 100.29 237.99 100.21
CO 501.70 501.56 99.97 499.13 99.49 485.30 96.73
Ethylene (CTS)100.30 97.93 97.64 98.47 98.18 96.71 96.42
Oxygen 10.62 10.65 100.28 10.81 101.79 10.53 99.15
SF6 10.20 10.18 99.80 10.16 99.61 10.19 99.85
Propane 252.40 252.61 100.08 252.52 100.05 255.62 101.27
Baseline Baseline R1 Baseline R2 Baseline R3
CO 0.0800 0.2300 0.000
NO 0.0000 0.0000 0.000
NO2 0.7100 0.5300 1.270
NOx 0.7100 0.5300 1.270
NMNEHC 0.3100 0.1900 0.120
Oxygen 0.0000 0.0000 0.000
Analyte Cal Gas Value Stack gas measured Stack + Spike measured Spike % Recovery Dilution Factor +=10% Spike Value
SF6 run 1 10.200 0.0000 0.897 99.59 0.0883 0.9007
SF6 run 2 10.200 0.0010 0.884 99.50 0.0870 0.8874
SF6 run 3 10.200 0.0000 0.941 99.63 0.0926 0.9445
Propane spike run 1 252.400 0.0260 22.228 99.62 0.0883 22.2869
Propane spike run 2 252.400 0.0240 22.377 101.79 0.0870 21.9588
Propane spike run 3 252.400 0.5290 24.306 101.69 0.0926 23.3722
Analyte CO NO NO2 Form CO2 VOC
MDC 0.1627 0.4007 0.4899 0.7878 0.0000 1.8520
Calibration Transfer Standard (CTS)
Spiked amout should be < 10% of the Certified gas concentration. The DF should be < 0.100
Spiked amout should be +-50% of the Stack analyte gas concentration
Sample Spike Recovery (70%-130%)
Test Results CO
Sample Spike MDC
Crusoe Energy - Duchesne Data Center; Engine GE-1251 Stack Test Date 10/08/24, Reviewed 12/10/24 by Robert Sirrine
Analyte/Spike %Recovery, Error & Drift
System Zero Background Check Pretest
Test Results NOx
Test Parameters Generator #1
Test Results VOC
Test Results HCOH
Run NOx ppm %O2 PPM @ 15% O2 PPM @ ISO lb/MMBtu lb/hr g/hp-hr
1 7.608 0.22 2.17 0.03 0.00000 0.18607 0.03761
2 9.457 0.28 2.71 0.04 0.00000 0.20287 0.04101
3 16.526 0.60 4.80 0.07 0.00000 0.35634 0.07203
AVG 11.197 0.37 3.23 0.04 0.00000 0.24843 0.05022
Run CO ppm %O2 PPM @ 15% O2 PPM @ ISO lb/MMBtu lb/hr g/hp-hr
1 6.667 0.22 1.90 #DIV/0!0.00000 0.09927 0.02006
2 11.009 0.28 3.15 #DIV/0!0.00000 0.14377 0.02906
3 23.380 0.60 6.80 #DIV/0!0.00000 0.30690 0.06204
AVG 13.685 0.37 3.95 #DIV/0!0.00000 0.1833 0.03705
Run VOC ppm %O2 PPM @ 15% O2 PPM @ ISO lb/MMBtu lb/hr g/hp-hr
1 3.311 0.22 0.94 #DIV/0!0.00000 0.07762 0.01569
2 2.965 0.28 0.85 #DIV/0!0.00000 0.06096 0.01232
3 2.351 0.60 0.68 #DIV/0!0.00000 0.04859 0.00982
AVG 2.88 0.37 0.83 #DIV/0!0.00000 0.0624 0.01261
Run HCOH ppm %O2 PPM @ 15% O2 PPM @ ISO lb/MMBtu lb/hr g/hp-hr
1 0.00 #DIV/0!0.00000 0.0000 0.00000
2 0.00 #DIV/0!0.00000 0.0000 0.00000
3 0.00 #DIV/0!0.00000 0.0000 0.00000
AVG #DIV/0!#DIV/0!0.0000 #DIV/0!0.00000 0.0000 0.00000
Operating Parameter R1 R2 R3 AVG.
Engine Load %89.74 89.74 89.74 89.74
Fuel Feed Rate (SCF/hr):#DIV/0!
F-Factor;#DIV/0!
Engine HP 2244.00 2244.00 2244.00 2244.00
BSFC (BTU/BHP-hr):#DIV/0!
Q Stack dscf/hr 204731.35 179572.84 180496.95 188267.05
HHV #DIV/0!
Ambient Temperature (F):#DIV/0!
Analyte High Recovery +- 10% Gas Value System Response % Recovery Pre Direct Response % Recovery Post System Reponse % Recovery
NOx #DIV/0!#DIV/0!#DIV/0!
NO2 99.95 0.00 0.00 0.00
NO 237.50 237.61 100.05 240.03 101.07 236.17 99.44
CO 501.70 505.39 100.74 509.79 101.61 509.65 101.58
Ethylene (CTS)100.30 98.61 98.32 99.84 99.54 98.79 98.49
Oxygen 10.62 10.69 100.66 10.78 101.51 10.67 100.47
SF6 10.20 10.27 100.69 10.35 101.46 10.22 100.17
Propane 252.40 248.44 98.43 250.79 99.36 247.42 98.03
Baseline Baseline R1 Baseline R2 Baseline R3
CO 0.3700 0.1400 0.000
NO 0.8200 0.6800 0.800
NO2 0.0000 0.0000 0.000
NOx 0.8200 0.6800 0.800
NMNEHC 0.5600 0.8700 0.850
Oxygen 0.0400 0.1500 0.000
Analyte Cal Gas Value Stack gas measured Stack + Spike measured Spike % Recovery Dilution Factor +=10% Spike Value
SF6 run 1 10.200 0.0000 0.835 101.44 0.0807 0.8231
SF6 run 2 10.200 0.0010 0.755 101.26 0.0730 0.7446
SF6 run 3 10.200 0.0010 0.841 101.29 0.0813 0.8293
Propane spike run 1 252.400 0.0010 18.609 91.36 0.0807 20.3687
Propane spike run 2 252.400 0.0000 16.508 89.59 0.0730 18.4252
Propane spike run 3 252.400 0.0000 19.020 92.69 0.0813 20.5201
Analyte CO NO NO2 Form CO2 VOC
MDC 0.1627 0.4007 0.4899 0.7878 0.0000 1.8520
Calibration Transfer Standard (CTS)
Spiked amout should be < 10% of the Certified gas concentration. The DF should be < 0.100
Spiked amout should be +-50% of the Stack analyte gas concentration
Sample Spike Recovery (70%-130%)
Test Results CO
Sample Spike MDC
Crusoe Energy - Duchesne Data Center; Engine GE-1254 Stack Test Date 10/10/24, Reviewed 12/12/24 by Robert Sirrine
Analyte/Spike %Recovery, Error & Drift
System Zero Background Check Pretest
Test Results NOx
Test Parameters Generator #1
Test Results VOC
Test Results HCOH
Run NOx ppm %O2 PPM @ 15% O2 PPM @ ISO lb/MMBtu lb/hr g/hp-hr
1 1.057 0.29 0.30 0.00 0.00000 0.02826 0.00583
2 0.212 0.16 0.06 0.00 0.00000 0.00685 0.00138
3 1.138 0.34 0.33 0.00 0.00000 0.03833 0.00809
AVG 0.802 0.26 0.23 0.00 0.00000 0.02448 0.00510
Run CO ppm %O2 PPM @ 15% O2 PPM @ ISO lb/MMBtu lb/hr g/hp-hr
1 39.288 0.29 11.25 #DIV/0!0.00000 0.63953 0.13186
2 42.005 0.16 11.95 #DIV/0!0.00000 0.82623 0.16656
3 37.578 0.34 10.78 #DIV/0!0.00000 0.77046 0.16255
AVG 39.624 0.26 11.33 #DIV/0!0.00000 0.7454 0.15366
Run VOC ppm %O2 PPM @ 15% O2 PPM @ ISO lb/MMBtu lb/hr g/hp-hr
1 0.25 0.29 0.07 #DIV/0!0.00000 0.00633 0.00131
2 0.35 0.16 0.10 #DIV/0!0.00000 0.01084 0.00219
3 0.36 0.34 0.10 #DIV/0!0.00000 0.01175 0.00248
AVG 0.32 0.26 0.09 #DIV/0!0.00000 0.0096 0.00199
Run HCOH ppm %O2 PPM @ 15% O2 PPM @ ISO lb/MMBtu lb/hr g/hp-hr
1 0.00 #DIV/0!0.00000 0.0000 0.00000
2 0.00 #DIV/0!0.00000 0.0000 0.00000
3 0.00 #DIV/0!0.00000 0.0000 0.00000
AVG #DIV/0!#DIV/0!0.0000 #DIV/0!0.00000 0.0000 0.00000
Operating Parameter R1 R2 R3 AVG.
Engine Load %88.00 90.00 86.00 88.00
Fuel Feed Rate (SCF/hr):#DIV/0!
F-Factor;#DIV/0!
Engine HP 2200.00 2250.00 2150.00 2200.00
BSFC (BTU/BHP-hr):#DIV/0!
Q Stack dscf/hr 223828.65 270469.25 281926.55 258741.48
HHV #DIV/0!
Ambient Temperature (F):#DIV/0!
Analyte High Recovery +- 10% Gas Value System Response % Recovery Pre Direct Response % Recovery Post System Reponse % Recovery
NOx #DIV/0!#DIV/0!#DIV/0!
NO2 99.95 0.00 0.00 0.00
NO 237.50 235.46 99.14 236.21 99.46 234.73 98.83
CO 501.70 487.75 97.22 499.83 99.63 504.33 100.52
Ethylene (CTS)100.30 102.41 102.10 98.59 98.30 101.77 101.47
Oxygen 10.62 11.00 103.58 10.82 101.88 10.92 102.82
SF6 10.20 10.30 100.98 10.37 101.64 10.22 100.22
Propane 252.40 249.85 98.99 249.87 99.00 248.54 98.47
Baseline Baseline R1 Baseline R2 Baseline R3
CO 0.4200 0.2700 0.070
NO 0.4600 0.0000 0.000
NO2 0.0000 0.0600 0.060
NOx 0.4600 0.0600 0.060
NMNEHC 0.2700 0.1800 0.190
Oxygen 0.0400 0.1800 0.000
Analyte Cal Gas Value Stack gas measured Stack + Spike measured Spike % Recovery Dilution Factor +=10% Spike Value
SF6 run 1 10.200 0.0010 0.017 10.35 0.0160 0.1632
SF6 run 2 10.200 0.0080 0.814 100.66 0.0785 0.8007
SF6 run 3 10.200 0.0090 0.791 100.48 0.0763 0.7783
Propane spike run 1 252.400 0.0010 0.000 0.00 0.0160 4.0384
Propane spike run 2 252.400 0.0000 17.883 90.26 0.0785 19.8134
Propane spike run 3 252.400 0.0000 17.285 89.75 0.0763 19.2581
Analyte CO NO NO2 Form CO2 VOC
MDC 0.1627 0.4007 0.4899 0.7878 0.0000 1.8520
Calibration Transfer Standard (CTS)
Spiked amout should be < 10% of the Certified gas concentration. The DF should be < 0.100
Spiked amout should be +-50% of the Stack analyte gas concentration
Sample Spike Recovery (70%-130%)
Test Results CO
Sample Spike MDC
Crusoe Energy - Duchesne Data Center; Engine GE-1283 Stack Test Date 10/07/24, Reviewed 12/11/24 by Robert Sirrine
Analyte/Spike %Recovery, Error & Drift
System Zero Background Check Pretest
Test Results NOx
Test Parameters Generator #1
Test Results VOC
Test Results HCOH
Run NOx ppm %O2 PPM @ 15% O2 PPM @ ISO lb/MMBtu lb/hr g/hp-hr
1 6.338 0.17 1.80 0.03 0.00000 0.09805 0.02103
2 6.230 0.15 1.77 0.03 0.00000 0.12600 0.02702
3 4.978 0.19 1.42 0.02 0.00000 0.08728 0.01872
AVG 5.849 0.17 1.66 0.03 0.00000 0.10378 0.02226
Run CO ppm %O2 PPM @ 15% O2 PPM @ ISO lb/MMBtu lb/hr g/hp-hr
1 43.627 0.17 12.42 #DIV/0!0.00000 0.41088 0.08812
2 43.017 0.15 12.23 #DIV/0!0.00000 0.52965 0.11359
3 38.887 0.19 11.08 #DIV/0!0.00000 0.41506 0.08901
AVG 41.844 0.17 11.91 #DIV/0!0.00000 0.4519 0.09691
Run VOC ppm %O2 PPM @ 15% O2 PPM @ ISO lb/MMBtu lb/hr g/hp-hr
1 3.33 0.17 0.95 #DIV/0!0.00000 0.04930 0.01057
2 3.39 0.15 0.96 #DIV/0!0.00000 0.06562 0.01407
3 3.11 0.19 0.89 #DIV/0!0.00000 0.05226 0.01121
AVG 3.27 0.17 0.93 #DIV/0!0.00000 0.0557 0.01195
Run HCOH ppm %O2 PPM @ 15% O2 PPM @ ISO lb/MMBtu lb/hr g/hp-hr
1 0.00 #DIV/0!0.00000 0.0000 0.00000
2 0.00 #DIV/0!0.00000 0.0000 0.00000
3 0.00 #DIV/0!0.00000 0.0000 0.00000
AVG #DIV/0!#DIV/0!0.0000 #DIV/0!0.00000 0.0000 0.00000
Operating Parameter R1 R2 R3 AVG.
Engine Load %84.59 84.59 84.59 84.59
Fuel Feed Rate (SCF/hr):#DIV/0!
F-Factor;#DIV/0!
Engine HP 2115.00 2115.00 2115.00 2115.00
BSFC (BTU/BHP-hr):#DIV/0!
Q Stack dscf/hr 129502.99 169303.90 146764.51 148523.80
HHV #DIV/0!
Ambient Temperature (F):#DIV/0!
Analyte High Recovery +- 10% Gas Value System Response % Recovery Pre Direct Response % Recovery Post System Reponse % Recovery
NOx #DIV/0!#DIV/0!#DIV/0!
NO2 99.95 0.00 0.00 0.00
NO 237.50 240.18 101.13 237.83 100.14 236.26 99.48
CO 501.70 509.53 101.56 493.78 98.42 499.04 99.47
Ethylene (CTS)100.30 101.61 101.31 101.46 101.16 99.47 99.17
Oxygen 10.62 10.84 102.07 10.63 100.09 10.71 100.85
SF6 10.20 10.44 102.35 10.36 101.54 10.32 101.14
Propane 252.40 255.51 101.23 251.77 99.75 252.02 99.85
Baseline Baseline R1 Baseline R2 Baseline R3
CO 0.4200 0.0000 0.210
NO 0.7300 0.6300 0.710
NO2 0.0000 0.0000 0.000
NOx 0.7200 0.6300 0.710
NMNEHC 0.4400 0.3100 0.240
Oxygen 0.1600 0.0900 0.000
Analyte Cal Gas Value Stack gas measured Stack + Spike measured Spike % Recovery Dilution Factor +=10% Spike Value
SF6 run 1 10.200 0.0040 0.821 101.00 0.0793 0.8089
SF6 run 2 10.200 0.0090 0.924 100.56 0.0892 0.9098
SF6 run 3 10.200 0.0060 0.775 100.79 0.0748 0.7630
Propane spike run 1 252.400 1.3240 20.749 97.23 0.0793 20.0153
Propane spike run 2 252.400 1.2150 22.469 94.69 0.0892 22.5141
Propane spike run 3 252.400 0.4300 19.059 98.70 0.0748 18.8795
Analyte CO NO NO2 Form CO2 VOC
MDC 0.1627 0.4007 0.4899 0.7878 0.0000 1.8520
Calibration Transfer Standard (CTS)
Spiked amout should be < 10% of the Certified gas concentration. The DF should be < 0.100
Spiked amout should be +-50% of the Stack analyte gas concentration
Sample Spike Recovery (70%-130%)
Test Results CO
Sample Spike MDC
Crusoe Energy - Duchesne Data Center; Engine GE-1318 Stack Test Date 10/09/24, Reviewed 12/12/24 by Robert Sirrine
Analyte/Spike %Recovery, Error & Drift
System Zero Background Check Pretest
Test Results NOx
Test Parameters Generator #1
Test Results VOC
Test Results HCOH
Run NOx ppm %O2 PPM @ 15% O2 PPM @ ISO lb/MMBtu lb/hr g/hp-hr
1 6.976 0.56 2.02 0.03 0.00000 0.12866 0.02766
2 7.581 2.52 2.43 0.04 0.00000 0.14270 0.03068
3 6.740 1.77 2.08 0.03 0.00000 0.10142 0.02180
AVG 7.099 1.62 2.18 0.03 0.00000 0.12426 0.02671
Run CO ppm %O2 PPM @ 15% O2 PPM @ ISO lb/MMBtu lb/hr g/hp-hr
1 39.385 0.56 11.42 #DIV/0!0.00000 0.44222 0.09507
2 45.078 2.52 14.47 #DIV/0!0.00000 0.51656 0.11105
3 27.618 1.77 8.52 #DIV/0!0.00000 0.25300 0.05439
AVG 37.360 1.62 11.47 #DIV/0!0.00000 0.4039 0.08683
Run VOC ppm %O2 PPM @ 15% O2 PPM @ ISO lb/MMBtu lb/hr g/hp-hr
1 3.09 0.56 0.90 #DIV/0!0.00000 0.05468 0.01175
2 3.16 2.52 1.01 #DIV/0!0.00000 0.05694 0.01224
3 2.02 1.77 0.62 #DIV/0!0.00000 0.02916 0.00627
AVG 2.76 1.62 0.84 #DIV/0!0.00000 0.0469 0.01009
Run HCOH ppm %O2 PPM @ 15% O2 PPM @ ISO lb/MMBtu lb/hr g/hp-hr
1 0.00 #DIV/0!0.00000 0.0000 0.00000
2 0.00 #DIV/0!0.00000 0.0000 0.00000
3 0.00 #DIV/0!0.00000 0.0000 0.00000
AVG #DIV/0!#DIV/0!0.0000 #DIV/0!0.00000 0.0000 0.00000
Operating Parameter R1 R2 R3 AVG.
Engine Load %84.35 84.38 84.38 84.37
Fuel Feed Rate (SCF/hr):#DIV/0!
F-Factor;#DIV/0!
Engine HP 2110.00 2110.00 2110.00 2110.00
BSFC (BTU/BHP-hr):#DIV/0!
Q Stack dscf/hr 154393.11 157571.29 125965.42 145976.61
HHV #DIV/0!
Ambient Temperature (F):#DIV/0!
Analyte High Recovery +- 10% Gas Value System Response % Recovery Pre Direct Response % Recovery Post System Reponse % Recovery
NOx #DIV/0!#DIV/0!#DIV/0!
NO2 99.95 0.00 0.00 0.00
NO 237.50 235.66 99.23 242.05 101.91 232.99 98.10
CO 501.70 494.02 98.47 509.30 101.52 501.17 99.89
Ethylene (CTS)100.30 96.94 96.65 99.99 99.69 0.00
Oxygen 10.62 10.79 101.60 10.65 100.28 10.56 99.44
SF6 10.20 1013.00 9931.37 10.35 101.43 10.02 98.24
Propane 252.40 249.55 98.87 252.64 100.09 246.88 97.81
Baseline Baseline R1 Baseline R2 Baseline R3
CO 0.0650 0.1250 0.085
NO 0.9700 0.7300 0.670
NO2 0.0000 0.0000 0.000
NOx 0.0970 0.7300 0.670
NMNEHC 0.9400 1.0400 0.650
Oxygen 0.0500 0.0700 0.125
Analyte Cal Gas Value Stack gas measured Stack + Spike measured Spike % Recovery Dilution Factor +=10% Spike Value
SF6 run 1 10.200 0.0010 0.951 101.34 0.0919 0.9374
SF6 run 2 10.200 0.0010 0.968 101.28 0.0936 0.9547
SF6 run 3 10.200 0.0020 0.928 101.21 0.0897 0.9149
Propane spike run 1 252.400 0.3300 22.340 94.96 0.0919 23.1956
Propane spike run 2 252.400 0.0000 22.314 94.45 0.0936 23.6246
Propane spike run 3 252.400 0.0000 22.286 98.44 0.0897 22.6403
Analyte CO NO NO2 Form CO2 VOC
MDC 0.1627 0.4007 0.4899 0.7878 0.0000 1.8520
Calibration Transfer Standard (CTS)
Spiked amout should be < 10% of the Certified gas concentration. The DF should be < 0.100
Spiked amout should be +-50% of the Stack analyte gas concentration
Sample Spike Recovery (70%-130%)
Test Results CO
Sample Spike MDC
Crusoe Energy - Duchesne Data Center; Engine GE-1362 Stack Test Date 10/11/24, Reviewed 12/11/24 by Robert Sirrine
Analyte/Spike %Recovery, Error & Drift
System Zero Background Check Pretest
Test Results NOx
Test Parameters Generator #1
Test Results VOC
Test Results HCOH