DAQ-2024-012020

1

DAQC-1215-24
Site ID 10346 (B5)

MEMORANDUM

TO: CEM FILE – RIO TINTO KENNECOTT UTAH COPPER, LLC – Smelter Facility

THROUGH: Harold Burge, Major Source Compliance Section Manager

FROM: Rob Leishman, Environmental Scientist

DATE: December 8, 2024

SUBJECT: Source: Smelter Main Stack (SME 011) and Acid Plant Tail Gas
(SME011b)
Contact: Sean Daly – 801-569-6331
Location: Kennecott Smelter, Magna, UT
Test Contractor: Alliance Technical Group, LLC
FRS ID#: UT00000049003500030
Permit/AO#: Title V operating permit 35003004, dated September 18, 2020
Last Revised September 27, 2022
Approval Order (AO) DAQE-AN103460063-24, dated
October 29, 2024
Subject: Review of RA/PST Report dated July 18, 2024

On July 19, 2024, DAQ received a Relative Accuracy/Performance Specification Test (RA/PST)
report for the Kennecott Smelter and Acid Plant Tail Gas stacks in Magna, UT. Testing was performed on
May 29, 2024, and June 18, 2024, to determine the relative accuracy of the NOx, SO2, and Flow
monitoring systems. The DAQ-calculated test results are:

RA/PST EVALUATION:

Main Stack (SME011)
NSPS RATA - Test Date - 5/29/2024
Primary
Channel Manufacturer Serial No. Units CEM
Value
RM
Value
Relative
Accuracy Status
SO2 Thermo Scientific 43iQ 12127413439 ppm 30.967 29.251 10.0% Passed
lbs/hr 186.600 173.350 4.1% Passed
NOx Thermo Fisher 42iQLS 12127413438 ppm 5.668 5.717 2.7% Passed
lbs/hr 24.110 23.990 4.8% Passed
Volumetric Flow Rate dscfm 603928.0 591655.5 5.0% Passed
Stack Test Deviation Report
There were no deviations observed during testing.
Calibration gases were in date and met performance specifications.

1 8 2
2

Tail Gas (SME011b)
NSPS RATA - Test Date - 6/18/2024
Primary
Channel Manufacturer Serial No. Units CEM
Value
RM
Value
Relative
Accuracy Status
SO2 Uniserch Associates Inc.
DAS-AR2047-00-FC-SO2-B-P DAS22-001 ppm 55.11 39.293 6.7% Passed
Stack Test Deviation Report
There were no deviations observed during testing.
Calibration gases were in date and met performance specifications.

DEVIATIONS: No deviations were noted in this report.

CONCLUSION: Rio Tinto Kennecott Utah Copper, LLC operates the continuous
emissions monitor (CEM) on the SME011 and SME011b stacks
to measure NOx and SO2 emissions and stack flow. The CEM
was audited by the DAQ and found to meet quality assurance
requirements found in 40 CFR Part 60, Appendix B,
Performance Specification 1, and R307-170, Continuous
Emission Monitoring System Program. Quarterly cylinder gas
audits and an annual relative accuracy test audit were conducted
in accordance with the procedures outlined in UAC R307-170.

RECOMMENDATION: The Kennecott SME011 and SME011b CEM systems were
operating as required in R307-170 and 40 CFR 60.13 at the time
of this evaluation.

HPV: No.

ATTACHMENTS: RATA Review Spreadsheets.
RioTinto Rio Tinto Kennecott Utah Copper, LLC
4700 Daybreak Parkway
South Jordan, UT 84009 USA
Tel: [phone]
UTAH DEPAFTMENT OF
ET.IVIRONMENIAL OTJAUTY
JUL 1 I 2024
o,bl$80 FIIX'6#.,",
Mr. Bryce Bird, Director
Department of Environmental Quality
Division of Air Quality
P.O. Box 144820
Salt Lake City, Utah 84114-4820
Attn: Rob Leishman
Date
18 July 2024
Dear Mr. Bird:
RE: Relative Accuracy Test Audit (RATA) Reports
Main Stack NO,/SOz& Tail Gas SOz
Title V Operating Permit No. 3500030004
Kennecott Utah Copper - Smelter Facility
Kennecott Utah Copper, LLC is hereby submitting the attached Main Stack (SME
0'11) sulfur dioxide (SOz) and nitrogen oxides (NO-) and Tail Gas (SME 011b)
RATA report as required by Approval Order DAQE-AN103460061-22 and Title V
operating permit 3500030004. The testing was conducted on May 29,2024 (Main
Stack) and June 18,2024 (Tail Gas). Data collected during the audit indicates the
monitors are operating in compliance with applicable requirements.
Based on information and belief formed after reasonable inquiry, the statements
and information contained in this document are true, accurate and complete (R307-
415-5d).
Should you have any questions or need further information regarding this protocol,
please feel free to contact me or Sean Daly at 801 -569-6331 .
Simon Mallard
Acting General Manager, Metals
Rio Tinto Kenne@tt Utah Copper, LLC 4700 Daybreak Parkway, South Jordan, UT 84009
RioTinto Rlo Tlnto Kennecott Utah Coppor, LLC
4700 Daybreak Parkway
South Jordan, UT 84009 USA
Tel: [phone]
Mr. Bryce Bird, Director
Department of Environmental Quality
Division of Air Quality
P.O. Box 144820
Salt Lake City, Utah 84114-4820
Attn: Rob Leishman
I,TAH DEPARTMENT OF
ENVIRONMENTAL OIJAI,JTY
JUL 1 I 2024
Date
18 July 2024
b\q$'tr+yfl,Po,o.*
Dear Mr. Bird:
RE: Relative Accuracy Test Audit (RATA) Reports
Main Stack NO,/SOz & Tail Gas SOz
Title V Operating Permit No. 3500030004
Kennecott Utah Gopper - Smelter Facility
Kennecott Utah Copper, LLC is hereby submitting the attached Main Stack (SME
011) sulfur dioxide (SOz) and nitrogen oxides (NOx) and Tail Gas (SME 011b)
RATA report as required by Approval Order DAQE-AN103460061-22 and Title V
operating permit 3500030004. The testing was conducted on May 29,2024 (Main
Stack) and June 18,2024 (Tail Gas). Data collected during the audit indicates the
monitors are operating in compliance with applicable requirements.
Based on information and belief formed after reasonable inquiry, the statements
and information contained in this document are true, accurate and complete (R307-
415-5d).
Should you have any questions or need further information regarding this protocol,
please feelfree to contact me or Sean Daly at 801-569-6331.
Simon Mallard
Acting General Manager, Metals
Rio Tinto Konn6@tt Utsh Copper, LLC 4700 Daybrsak Parkwey, South Jordan, UT 84009
_I,TAH DEPARTMET.IT OFENVIRONMEMAL OUAIITY
r.,.li.'Allare,,#r ;-].t
De)r Vere4
OF AIR QUALITY
RATA Report
Rio Tinto Kennecott
4700 Daybreak Parkway
South Jordan, UT 84095
Source Tested: Main Stack SMEOl1
Test Date: May 29,2024
Proj ect No. AST- 2024-2322-00 I
Prepared By
Alliance Technical Group, LLC
3683 W 2270 S, Suite E
West Valley City, UT 84120
pd/lErrce
itc!NtoAt G R () ll t'Source Test Report
Tesl Prosram Summary
Regulatory Information
Permit Nos.
Regulatory Citation
Source Information
DAQE-AN103460061-22
Title v operating Permit 3500030004
40 CFR 60, Appendix B, PS 2 and 6
Source Name
Smelter Main Stack
Contact Information
Source ID
SMEOII
Target Parameters
VFR, SOz, NOx
Test Locotion
Kennecott Utah Copper, LLC
4700 Daybreak Parkway
South Jordan, UT 84009
Jenny Esker
j enny.esker@riotinto. com
(801) s69-6494
Sean Daly
sean.daly3 @riotinto.com
(801)204-2s63
Test Company
Alliance Technical Group, LLC
3683 W 2270 S, Suite E
West Valley City, UT 84120
Project Manager
Charles Horton
[e-mail]
(3s2) 663-7s68
Field Team Leader
Ryan Lyons
ryan. [e-mail]
(708)214-48s0
QA/QC Manager
Kathleen Shonk
[e-mail]
(8t2) 4s2-478s
Report Coordinator
Delaine Spangler
[e-mail]
Report Reviewer
Sarah Perry
sarah.perry@al I iancetg. com
RTK - Magna, UTAST-2024-2322-001 Page i
pdlldrpE)
Source Test Report
Certfication StatementTf CIINICAL GROUP
Alliance Technical Group, LLC (Alliance) has completed the source testing as described in this report. Results
apply only to the source(s) tested and operating condition(s) for the specific test date(s) and time(s) identified within
this report. All results are intended to be considered in their entirety, and Alliance is not responsible for use of less
than the complete test report without written consent. This report shall not be reproduced in full or in part without
written approval from the customer.
To the best of my knowledge and abilities, all information, facts and test data are correct. Data presented in this
report has been checked for completeness and is accurate, error-free and legible. Onsite testing was conducted in
accordance with approved internal Standard Operating Procedures. Any deviations or problems are detailed in the
relevant sections in the test report.
This report is only considered valid once an authorized representative of Alliance has signed in the space provided
below; any other version is considered draft. This document was prepared in portable document format (.pdf) and
contains pages as identified in the bottom footer of this document.
7t912024
Charles Horton QSTI
Alliance Technical Group, LLC
Date
RTK - Magna, UTAST-2024-2322-001 Page ii
pilt6rpe
IICIINICAL_ GROUP Source Test Report
Table of Contents
TABLE OF CONTENTS
L l Process/Control System Descriptions. ..................... l-l
1.4 Site-Specific Test Plan & Notification.................. ....................... l-l
3.1 U.S. EPA Reference Test Methods I and 2 - Sampling/Traverse Points and Volumetric Flow Rate ........ 3-l
3.2 U.S. EPA Reference Test Method 34 - Oxygen/Carbon Dioxide........ ............ 3- I
3.3 U.S. EPA Reference Test Method 4 - Moisture Content........ .....3-2
3.4 U.S. EPA Reference Test Method 6C - Sulfur Dioxide........ .......3-2
3.5 U.S. EPA Reference Test Method 7E - Nitrogen Oxides ............3-2
3.6 U.S. EPA Reference Test Method 205 - Gas Dilution System Certification. ........................3-2
3.7 Quality Assurance/Quality Control - U.S. EPA Reference Test Methods 3A,6C and7E.........................3-2
LIST OF TABLES
Table 2- I : Summary of Performance Specification Test Results ..............2-l
APPENDICES
Appendix A Sample Calculations
Appendix B Field Data
Appendix C Quality Assurance/Quality Control Data
Appendix D CEMS/CERMS Data
AST-2024-2322-001 RTK - Magna, UT Page iii
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Gn()itP Source Test Reporl
Introduction
1.0 Introduction
Alliance Technical Group, LLC (Alliance) was retained by Rio Tinto Kennecott (RTK) to conduct performance
specification (PS) testing at the Smelter facility located in Magna, Utah. Portions of the facility are subject to
provisions of the 40 CFR 60, Appendix B, PS 2 and 6, the Utah Department of Environmental Quality, Division of
Air Quality (UDAQ) Approval Order (AO) DAQE-AN103460061-22 and the Title V Operating Permit No.
350030004. Testing included conducting a relative accuracy test audit (RATA) to determine the relative accuracy
(RA) of the primary and redundant sulfur dioxide (SOz) and nitrogen oxides (NOx) continuous emissions
monitoring system (CEMS) and the volumetric flow rate (VFR) continuous emissions rate monitoring system
(CERMS) serving the Main Stack designated as SME0I l.
l.l Process/ControlSystemDescriptions
The smelter facility rehnes, and processes copper slurry concentrates for the production of copper anodes. Gases
from the acid plant, secondary gas system, rotary dryer, powerhouse superheater and the Foster Wheeler boiler,
matte grinding plant, anode area, and hydrometallurgical plant are ducted through a variety of environmental
controls to the smelter Main Stack SME0l l and vented to the atmosphere.
1.2 CEMS Descriptions
Parameter:
Make:
Model:
Serial No.
Span:
Nitrogen Oxides
NOx
Thermo Scientific
42iQLS
12127413438
0-100 / 0-10,000
43iQ
t2127413439
0-100 / 0-10,000
43iQ
121274t3439
0-100 / 0-10,000
Sulfur Dioxide
SOz- Low SOz- High
Thermo Scientific Thermo Scientific
Flow
Primary
CemtekrKVB-Enertec
Flow 100
0019
0-l" H2o
1.3 Project Team
Personnel involved in this project are identified in the following table.
Table l-l: Project Team
1.4 Site-Specific Test Plan & Notification
Testing was conducted in accordance with the Site-Specific Test Plan (SSTP) submitted to UDAQ by RTK.
RTK Personnel Sean Daly
Alliance Personnel
Ryan Lyons
SupilaniMailei
Finn Townsley
RTK - Magna, UTAST-2024-2322-00t Page I -l
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TECI,INICAL GROUP Source Test Report
Swwnary of Results
2.0 Summary of Results
Alliance conducted PS testing at the Smelter facility located in Magn4 Utah on May 29,2024. Testng included
conducting a RATA to determine the RA of the SOz and NOx CEMS and the VFR CERMS serving the Main Stack
designated as SMEOI l.
Table 2-l provides a summary of the emission testing results with comparisons to the applicable RA requirements.
Any difference between the summary results listed in the following table and the detailed results contained in
appendices is due to rounding for presentation.
Table 2-l: Summary of Performance Specification Test Results
Sulfur Dioxide Data
Concentration, ppmvw
Emission Rate, lb/hr
<20 o/o
<20 Yo
18.00 % t
12.92o/o l
Nitrogen Oxides Data
Concentration, ppmvw
Emission Rate, Ib/hr
<20 Yo
<20 o/o
6.15 0A I
4.88 o/o I
Volumetric Flow Rate
Flow Rate, scfrn (wet)
t Calculated using the mean reference mettrod.
RTK-Magn4 UTAST-2024-2322-Nt Page2-l
Volumetric Flow Rate t&2 Full Velocity Traverses
Oxygen / Carbon Dioxide 3A Instrumental Analysis
Moisture Content 4 Gravimetric Analysis
Sulfur Dioxide 6C lnstrumental Analysis
Nitrogen Oxides 7E lnstrumental Analysis
Gas Dilution System Certification 205
pill6rrpE)
Ito!l.JlCAl Gn()Ul)Source Test Report
Testing Methodologt
3.0 Testing Methodology
The emission testing program was conducted in accordance with the test methods listed in Table 3-1. Method
descriptions are provided below while quality assurance/quality control data is provided in Appendix C.
Table 3-l: Source Testing Methodology
3.1 U.S. EPA Reference Test Methods I and 2 - Sampling/Traverse Points and Volumetric Flow Rate
The sampling location and number of traverse (sampling) points were selected in accordance with U.S. EPA
Reference Test Method l. To determine the minimum number of traverse points, the upstream and downsffeam
distances were equated into equivalent diameters and compared to Figure I -2 in U.S. EPA Reference Test Method I .
Full velocity traverses were conducted in accordance with U.S. EPA Reference Test Method 2 to determine the
average stack gas velocity pressure, static pressure and temperature. The velocity and static pressure measurement
system consisted of a pitot tube and inclined manometer. The stack gas temperature was measured with a K-type
thermocouple and pyrometer.
Stack gas velocity pressure and temperature readings were recorded before and after each test run. The data
collected before and after each test run was averaged. The averages were utilized to calculate the volumetric flow
rate in accordance with U.S. EPA Reference Test Method 2.
Stack gas velocity pressure and temperature readings were recorded during each test run. The data collected was
utilized to calculate the volumetric flow rate for comparison to the continuous emission rate monitoring system
(CERMS). The relative accuracy of the CERMS was determined based on procedures found in 40 CFR 60,
Performance Specifi cation 6.
3.2 U.S. EPA Reference Test Method 3A - Oxygen/Carbon Dioxide
The oxygen (Oz) and carbon dioxide (COz) testing was conducted in accordance with U.S. EPA Reference Test
Method 3A,. Data was collected online and reported in one-minute averages. The sampling system consisted of a
stainless-steel probe, Teflon sample line(s), gas conditioning system and the identified gas analyzer. The gas
conditioning system was a non-contact condenser used to remove moisture from the stack gas. If an unheated
Teflon sample line was used, then a portable non-contact condenser was placed in the system directly after the
probe. Otherwise, a heated Teflon sample line was used. The quality control measures are described in Section 3.7.
AST-2024-2322-001 RTK * Magna, UT Page 3-l
AI
ir i.l l(Source Test Report
Tesling Methodologt
3.3 U.S. EPA Reference Test Method 4 - Moisture Content
The stack gas moisture content (BWS) was determined in accordance with U.S. EPA Reference Test Method 4. The
gas conditioning train consisted of a series of chilled impingers. Prior to testing, each impinger was filled with a
known quantiry of water or silica gel. Each impinger was analyzed gravimetrically before and after each test run on
the same balance to determine the amount of moisture condensed.
3.4 U.S. EPA Reference Test Method 6C - Sulfur Dioxide
The sulfur dioxide (SOz) testing was conducted in accordance with U.S. EPA Reference Test Method 6C. Data was
collected online and reported in one-minute averages. The sampling system consisted of a heated stainless steel
probe, Teflon sample line(s), gas conditioning system and the identified analyzer. The gas conditioning system was
a non-contact condenser used to remove moisfure from the source gas. If an unheated Teflon sample line was used,
then a portable non-contact condenser was placed in the system directly after the probe. Otherwise, a heated Teflon
sample line was used. The quality control measures are described in Section 3.7.
The relative accuracy of the SOz CEMS was determined based on procedures found in 40 CFR 60, Performance
Specification 2.
3.5 U.S. EPA Reference Test Method 7E - Nitrogen Oxides
The nitrogen oxides (NOx) testing was conducted in accordance with U.S. EPA Reference Test Method lE. Data
was collected online and repofted in one-minute averages. The sampling system consisted of a stainless-steel probe,
Teflon sample line(s), gas conditioning system and the identified gas analyzer. The gas conditioning system was a
non-contact condenser used to remove moisture from the stack gas. If an unheated Teflon sample line was used,
then a portable non-contact condenser was placed in the system directly after the probe. Otherwise, a heated Teflon
sample line was used. The quality control measures are described in Section 3.7.
The relative accuracy of the NOx CEMS was determined based on procedures found in 40 CFR 60, Performance
Specification 2.
3.6 U.S. EPA Reference Test Method 205 - Gas Dilution System Certification
A calibration gas dilution system field check was conducted in accordance with U.S. EPA Reference Method 205.
Multiple dilution rates and total gas flow rates were utilized to force the dilution system to perform two dilutions on
each mass flow controller. The diluted calibration gases were sent directly to the analyzer, and the analyzer response
recorded in an electronic field data sheet. The analyzer response agreed within 2% of the actual diluted gas
concentration. A second Protocol I calibration gas, with a cylinder concentration within l0% of one of the gas
divider settings described above, was inffoduced directly to the analyzer, and the analyzer response recorded in an
electronic field data sheet. The cylinder concentration and the analyzer response agreed within 2o/o. These steps
were repeated three (3) times. Copies of the Method 205 data can be found in the Quality Assurance/Quality
Control Appendix.
3.7 Quality Assurance/Quality Control - U.S. EPA Reference Test Methods 3A, 6C and 7E
Cylinder calibration gases used met EPA Protocol I (+l- 2%) standards. Copies of all calibration gas certificates can
be found in the Quality Assurance/Quality Control Appendix.
Low Level gas was introduced directly to the analyzer. After adjusting the analyzer to the Low-Level gas
concentration and once the analyzer reading was stable, the analyzer value was recorded. This process was repeated
FtalEe
(r; ilrI , r'
AST-2024-2322-001 RTK - Magna, UT Page 3-2
Source Tesl Report
Testing Methodologt
for the High-Level gas. For the Calibration Error Test, Low, Mid, and High Level calibration gases were
sequentially introduced directly to the analyzer. All values were within 2.0 percent of the Calibration Span or 0.5
ppmv lo/o absolute difference.
High or Mid-Level gas (whichever was closer to the stack gas concentration) was infroduced at the probe and the
time required for the analyzer reading to reach 95 percent or 0.5 ppmv/% (whichever was less restrictive) of the gas
concentration was recorded. The analyzer reading was observed until it reached a stable value, and this value was
recorded. Next, Low Level gas was introduced at the probe and the time required for the analyzer reading to
decrease to a value within 5.0 percent or 0.5 ppmv/% (whichever was less restrictive) was recorded. If the Low-
Level gas was zero gas, the response was 0.5 ppmvlo/o or 5.0 percent of the upscale gas concentration (whichever
was less restrictive). The analyzer reading was observed until it reached a stable value and this value was recorded.
The measurement system response time and initial system bias were determined from these data. The System Bias
was within 5.0 percent of the Calibration Span or 0.5 ppmv/% absolute difference.
High or Mid-Level gas (whichever was closer to the stack gas concentration) was introduced at the probe. After the
analyzet response was stable, the value was recorded. Next, Low Level gas was introduced at the probe, and the
analyzer value recorded once it reached a stable response. The System Bias was within 5.0 percent of the
Calibration Span or 0.5 ppmvloh absolute difference or the data was invalidated and the Calibration Error Test and
System Bias were repeated.
Drift between pre- and post-run System Bias was within 3 percent of the Calibration Span or 0.5 ppmv/7o absolute
difference. If the drift exceeded 3 percent or 0.5 ppmv/%, the Calibration Enor Test and System Bias were repeated.
To determine the number of sampling points, a gas stratification check was conducted prior to initiating testing. The
pollutant concentrations were measured at three points (16.7, 50.0 and 83.3 percent of the measurement line). Each
traverse point was sampled for a minimum of twice the system response time.
If the pollutant concentration at each traverse point did not differ more than 5 percent or 0.5 ppmv/0.3% (whichever
was less restrictive) of the average pollutant concentration, then single point sampling was conducted during the test
runs. Ifthe pollutant concentration did not meet these specifications but differed less than l0 percent or 1.0
ppmvl0.5%o from the average concentration, then three (3) point sampling was conducted (stacks less than 7.8 feet in
diameter - 16.7 , 50.0 and 83.3 percent of the measurement line; stacks greater than 7.8 feet in diameter - 0.4, 1.0,
and 2.0 meters fiom the stack wall). If the pollutant concentration differed by more than l0 percent or 1.0
ppmv/0.5% from the average concentration, then sampling was conducted at a minimum of twelve (12) traverse
points. Copies of stratification check data can be found in the Quality Assurance/Quality Control Appendix.
An NOz - NO converter check was performed on the analyzer prior to initiating testing. An approximately 50 ppm
n itrogen dioxide cylinder gas was introduced directly to the NOx analyzer and the instrument response was recorded
in an electronic data sheet. The instrument response was within +/- l0 percent of the cylinder concentration.
A Data Acquisition System with battery backup was used to record the instrument response in one (l) minute
averages. The data was continuously stored as a *.CSV file in Excel format on the hard drive of a computer. At the
completion of testing, the data was also saved to the Alliance server. All data was reviewed by the Field Team
Leader before leaving the facility. Once arriving at Alliance's office, all written and electronic data was
relinquished to the report coordinator and then a final review was performed by the Project Manager.
AST-2024-2322-001 RTK - Magna, UT Page 3-3
AllTalEEr Example Calculations
It r'llll ..Al (i[l()|l
Ircrtion Rio Tlrto fe""e"tt - tttlgt"' Uf
Sor""u
Proiect No. AST-202+2322
Run No.
Psrrmeter(s)
Meter Prqsurc (Pm), in. Eg
AHPm = Pb+-
wherc, 13 6
Pb 25.27 - b{omctric prcssuc, in. Hg
AH 1.000 = pressue diffcrential oforificc, in H2O
Pm 25.34 = in. Hg
Absolute Strck Gls Prqlure (Ps)' in. Eg
Ps. Ps = eU+fr
whcre.Pb 25.27 = baomctric prcssuc, in. Hg
Pg 0.02 = static pressuc, in. H2O
Ps 25.27 = in Hg
Stenderd Meter Volume (Vmrtd), dscf
l7.636xVmxPmxYVmtd-
where,
Y
Vm
Pm
Tm
Vmstd
Tm
1.003 = mctcr co[cction factor
@=retcrvolue,cf25.34 = absolutc mctcr prcssuc, in. Hg
__119J_- ab3olutc mctcr tcmpcratue, "R
__].,|..1Q[_=dscf
Stsndrrd Wet Volume (Vw!td), 3cf
Vwstd= 0.047l6xVlc
where,Vlc 48.6 = wcight ofHrO collcctc4 Ivwstd-......E--scf
Molsture Fraction (BWS$t), dime nsionlc$ (thmrctical .t sstursted cordition3)
106.3?-(+f:e)- BltrSsat =
-
where,-"""-' PSTs I 15.6 = stgck tempcratue, oF
Ps
--2I!-=
sbsolutc stack gs pressue, in. Hg
BWSsat __JL!29_ = dimeroiontcss
Moilaure FrEction (BWS), dlmensionless
VwstdBWS =where, (Vwstd * Vmstd)
Vwstd 2.292 = standtrd wct volme, scfVmstd 3l.0'14 = stmdtrd mcter volmc, dscf
BwS -- oG9- = dimcnsionless
Moisture Fr8ction (BWS), dimensionles
BWS = BWSmsd unless BWSsat < BWSmsd
wherc,
BWSsat_____]ll29_ - moistuc fraction (thcorctical at satuatcd conditions)
BWSmsd 0.069 - moistue fraction (mcsucd)
BWS 0.069
Molecuhr Weight (DRY) (Md), lbAb-mole
Md = (0.44 x o/oCO) + (0.32 x o/oO2) + (0.28 (100- o/oCO2 - o/oO2))
where,
CO, _;||_ = cubon dioxidc conccntration, o/o
O, ___-.'| i.]_ - oxygcn concentration, yo
Md 2A.76 = lb/lb mol
AlliErEet-i (:!ilta'n I rl Fl (') l, t'
Loetion Rio Tltrto Ken!@tt - Mrgrr' UT
Source M8in Strck - SME0I I
Project No.
Rua No.
Ps rrm et€ r(3)
Example Calculations
Moleculrr W€ight (WET) (Ms), lb/ltsmole
Ms = Md (1 - BWS) + 18.01s (BWS)
where,Md 28.76 = molcculu wcight (DRY), lb4b mol
Bws .@- moistue fraction, dimcnsionlcss
Ms 28.02 = lb/lb mol
AvcrE8e Veloclty (V!), ft^s
"..Vs = 85.49 x Cp x (APt/z)avg xwberel
Cp 0.84 = pitot tube coefficient
A p'o111]!_- averagc prc/post tcat vclocity hcad of stack gu, (in. H2O)r'
Ts ___l]J.l_ = avcmgc prc/post tcat absolule stack temperatuc, oR
Ps 25.2'1 = absolutc stack gu prcssuc, in. HgMs 28.02 = molcculu wcight of stack gu, lb/lb mol
vs ---7ill-= fl/scc
Avcrage Steck Grs Flow et Strck Cotrditions (Qe), rcfm
Qa=60xVsxAs
where,
V. ____?gl_ = stack gu vclocity, fusc
As ---€!L = cross-scctional rca of stack, ft2
Qa 768,938 - acfm
Averrgc Strck Grs Flow rt Strtrdrrd Conditlonr (Qs)r d$fm
Qsd = 17.636 x Qa x (l - BWS) x E!
Ts
whcre,Qa 768,938 = avcrage stack gas flow at siack mnditions, acfm
BWS 0.069 = moistue fraction, dimcroionlcss
P" J.U_- absolute stack gs prcssuc, in. HgTs 575.3 = avcragc pre/post tcst absolutc stack tempcratuc, oR
Qt@=at"m
Dry Gro Mcter Celibrrtion Check (Yqa), percent
Y-
Yoa =
where,Y 1.003 = metcrcorection facior, dimcnsionlcas
O_____gq_= m timc, min.
Vm _fg!99_ = total mctcr volme, dcf
Tm 549. I = absolutc m€tcr tcmpcratue, oR
AH@ _!.5!l_- orifice mctcr calibration ccfiicicnt, in. H2O
Pb 25.21 - baomctric prcssuc, in. Hg
o
Vm ***)
x 100
AH avg_!Q![= averagc prcssuc diffcrcntial of orifice, in H2O
Md 28.'11 - molcculr wcight (DRY), lblb mol
(A H)'o
-!$-=
avcragc sqwc root prcssuc difllrcntial of orifrcc, (in. H2O)ta
Yqa -12 =pcrccnt
plll6rEe Example Calculations
T f O ll l'J l ()n L (l fi r'ii [.'
Location: Rio T
Source:M
Project No.: AST-2024-2322
Run No. /Method Run I / Method 3,{
Or - Outlet Concentration (Cq), oh dry
Co,= (Cou.-co)* ( #"i
where,Cob. 16.28 : average analyzer value during test, oZ dry
Co-0'30-: average of pretest & posttest zero responses,o/o dry
CMA-T7:[tr= actual concentration of calibration gas,Yodry
CM
-TZIT-
: average of pretest & posttest calibration responses, 7o dry
Ca-T = Oz Concentration, To dry
COr - Outlet Concentration (C6s), o/o dry
cco,: (cou,-co)* ( d'l.h)
where,Cob, 0.69 : average analyzet value during test, 7o dry
Co-:0T-: average of pretest & posttest zero responses,%o dry
CMA-30-: actual concentration of calibration gas,o/o dry
CIVT: average of pretest & posttest calibration responses, 7o dry
Cco,T: CO: Concentration, o/o dry
pult6rlrce Example Calculations
I t: () tl l.l l (.) r'i L (1,::l ar l.r T'
Location: fuo Tinto Kennecott - Maena. UT
Source: Maln StacL - SMbU I I
Project No.: AST-2024-2322
Run No. /MethodRun I / Method 7E
NOx - Outlet Concentration (C616), ppmvd
cNo^ = ( Co6. - C6 ) x (,-" - a, lfu )
where,Cob, 6.27 : average analyzer value during test, ppmvd
Co
-0:0T-
: average of pretest & posttest zero responses, ppmvd
CMA-T5.TO-= actual concentration of calibration gas, ppmvd
CM-.T: average of pretest & posttest calibration responses, ppmvd
CNS*.........ffi: Nox Concentration, ppmvd
NOx - Outlet Concentration (Cp6*), ppmvw
where,
C*o,*= CNo*x(l-BWS)
CNo* 6.26 : NOx - Outlet Concentration, ppmvd
Bws
-6lE-
: moisture fraction, unitlessCp6**-T8-= ppmvw
NOx - Outlet Emission Rate (ERxe,), lb/hr
.L
,o.. - CNo, x MW x Qs x 60 fl x28.32 rnLr\NOx -
where,CNo" 6.26 : NOx - Outlet Concentration, ppmvd
MW 46.0055 : NOx molecular weight, g/g-mole
Qs 554,826 = stack gas volumetric flow rate at standard conditions, dscfrnERNo*-4.Tr: lb/hr
plll6rrrce Example Calculations
I t (tllt.t l(tAi (,ri()l)f'
Location: fuo T
Source:M
Project No.: AST-2024-2322
Run No. /-lVlethod Run I / Method 6C
SOz - Outlet Concentration (Cse), ppmvd
where,
cso, : ( Cou. - co ) * ( f_--.r)
Cou. 36.49 : average analyzer value during test, ppmvd
Co----lT-: average of pretest & posttest zero responses, ppmvd
CMA-T5IO-: actual concentration of calibration gas, ppmvd
CM-9-: average of pretest & posttest calibration responses, ppmvd
Cso, ----J-6-il : SOz C o nce ntration, ppmvd
SOr - Outlet Concentration (C.o*), ppmvw
Lso,* -C56,x(l-BWS)
where,Cso, 36.67 : SOz - Outlet Concentration, ppmvd
Bws
-b.069-:
moisture fraction, unitlessCso.*-T-:ppmvw
SO, - Outlet Emission Rate (ERse), lb/hr
oo- - Cso,xMWxQsx60# x28J:2h
-^SO, -
where,Cso. 36.67 : SOz - Outlet Concentration, ppmvd
Mw-4.066-: Soz molecular weight, g/g-mole
Qs 554,826 : stack gas volumetric flow rate at standard conditions, dscfrn
ERso,
pul6rlpE)SO2 Summary
It( lIt..j |.rAt rrF()lrl,
Locetion: Rio Tinto Kennecott - Magna, UT
Sorrcet
Project No. : AST -2024-2322
' Dclimitcr for us not ucd in RA calculations
Confi dcnce Coefficient, CC
aa = lto'gt r rollVn I
where,
h.ws L306 : degrees of freedom value
n 9 : number of runs selected for calculating the RA
Sd 2.026 : standard deviation ofdifferenceCC 1.557 : confidence coefficient
Relative Accuracy, RA
ld I + lcclM = 7ri;;7:x1oo
where,
d -3.40 = average difference of Reference Method and CEMSCC 1.557 : confidence coefticientRM 2h63 = reference method, ppmvw
RA l8J0 = relative accuracy,Yo
Run
No.Dete Time Reference Method
SO, Concentration
DDInVW
CEMS - Combined
S0r Concentration
DDMYW
Average
Difference
nDmvwStartEnd
I
2
3
4
5
6
7
8
9
l0
5t29t24
5t29t24
5/29124
5t29124
5t29t24
5t29t24
5t29t24
5t29124
5129t24
5t29124
0:05
l:33
l:54
2:51
3:12
3:33
4: l0
4:31
4:52
5:34
0:25
l:53
2:14
3:l I
3:32
3:53
4:30
4:51
5:12
5:54
34.t4
23.93
t6.l5
12.98
29.59
38.79
25.73
39.19
38.90
22.8t
42.89
28.90
18.24
13.21
32.38
44.90
28.25
44.96
43.44
24.42
4.97
-2.09
-0.23
-2.79
-6.1 l
-2.52
-5.77
4.54
-t.61
Average 27.s6 30.97 -3.403
Standard Deviation (Sd)2.026
Confi dence Coeffi cient (CC)1.557
Relative Accuracy (RA)tE%
Performance Required - Mean Reference Method RA < 20%
Performance Specifi cation Method PS2
Alt6rtrc--TECHNICAL GROUP
SO2 Summary
Locetion: Rio Tinto Kennecott - Mama- UT
Source: Main Stack - SME0I I
Project No.: AST-2024-2322
r Delimiter for ms not used in RA calculations
Confi dence Coeffi cient, CC
aa=ltogtrrollVn I
where,
hsts
-@-=
degrees of freedom value
n 9 = number of runs selected for calculating the RA
Sd 12.137 = standard deviation ofdifferenceCC 9.330 = confidence coefficient
Relative Accuracy, RA
ld l+ lcclM = 7r;ffix1oo
where,
d -13.09 = average difference of Reference Method and CEMS
CC 9.330 = confidence coefticient
RM 173.51 I = reference method, lb/hrRA 12.92 _= relative accuracy,Yo
Run
No.Dete Time Reference Method
SOr Emission Rate
lb/hr
CEMS
SOz Emission Rate
lb/hr
Average
Difference
Ib/hrStartEnd
I
2
J
4
5
6
7
8
9
l0
5t29t24
5t29t24
5t29/24
5D9n4
5t29/24
s/29124
5t29t24
5t29t24
st29l24
st29t24
0:05
l:33
l:54
2:51
3:12
3:33
4: l0
4:31
4:52
5:34
0:25
l:53
2:14
3:l I
3:32
3:53
4:30
4:51
5:12
5:54
203.t
142.4
98.6
8l.l
184.2
247.5
161.0
zst.6
248.6
146.6
249.7
173.7
109.2
83.2
203.4
276.2
t69.7
269.2
253.2
141.6
-3 1.3
- 10.6
-2.1
-19.2
-28.7
-8.7
-17.6
4.6
5.0
Averag(173.5 186.6 -13.089
Standard Deviation (Sd t2.137
Confi dence Coeffi cient (CC 9.330
Relative Accuracy (RA 12.92 Yo
Performance Required - Mean Reference Methor RA < 20%
Performance Specifi cation Methoc PS2
pul6rlpE)NOx Summary
T I ('iltiti)A[ (lnf)t]P
Location: Rio Tinto Kennecott - Maena. UT
Source: Main Stack - SMEOI I
ProjectNo.: AST-24144
* Delimiter for ms not used in RA calculations
Confi dence Coeffi cient, CC
.. : ltnZt ,. ,ollVn I
where,
to.e75 2.306 : degrees offreedom value
n 9 = number of runs selected for calculating the RASd 0.104 = standard deviation ofdif,lerenceCC 0.080 : confidence coeflicient
Relative Accuracy, RA
ld I + lcclRA : _____i__-x100
where,d -0.25 = average difference of Reference Method and CEMSCC 0J80 = confidence coefficientRM 5323 = reference method, ppmvw
RA 615 = relative accuracy,o/o
Run
No.Drte Time Reference Method
NOx Concentretion
DDMVW
CEMS
NOx Concentration
nnmvw
Average
Difference
NDM\ITYStartEnd
I
')
J
4
5
6
7
8
9
l0
st29/24
5t29t24
5t29t24
5t29t24
st29l24
5t29t24
st29l24
5t29t24
5/29t24
5t29124
0:05
l:33
l:54
2:5 |
3:12
3:33
4:10
4:31
4:52
5:34
0:25
l:53
2:14
3:l I
3:32
3:53
4:30
4:51
5:12
5:54
5.83
5.43
5.33
4.35
4.83
s.95
5.98
5.5'7
4.97
5. l0
6.t2
s.93
5.76
4.62
5.1 I
6. l9
6.30
5.76
5.06
5.22
-0.29
-0.43
-0.27
-0.28
-0.24
-0.32
-0. l9
-0.09
-0 12
Averagr 5.32 5.57 -0.248
Standard Deviation (Sdl 0.104
Confi dence Coefficient (CCl 0.080
Relative Accuracy (RAl 6.15 o/o
Performance Required - Mean Reference Method RAs20%
Performance Specifi cation Methoc PS2
pultErre
TECHNICAL GROUP
Location: Rio Tinto Kennecoft - Mama. UT
NOx Summary
Source: Main Stack - SME0I I
Proj ect No.: AST -2024-2322
Run
No.Date Time Reference Method
NOx Emission Rate
lb/hr
CEMS
NOx Emission Rate
lb/hr
Average
Difference
lb/hrStartEnd
I
2
3
4
5
6
7
8
9
l0
5t29t24
5t29t24
5t29t24
5/29/24
5129124
5t29t24
5t29124
5t29/24
5t29t24
5t29124
0:05
l:33
l:54
2:51
3:12
3:33
4:10
4:31
4:52
5:34
0:25
l:53
2:14
3:ll
3:32
3:53
4:30
4:51
5:12
5:54
24.9
23.2
23.3
19.5
21.6
27.3
26.9
25.7
22.8
23.5
25.7
25.7
24.9
2t.0
23.2
2',1 .4
27.2
24.7
21.2
21.8
-0.78
-1.53
-1.41
-1.59
-0.07
-0.33
0.91
1.55
t.73
Averagt 23.9 24.t -0. I 69
Standard Deviation (Sd L301
Confi dence Coefficient (CC'1.000
Relrtive Accuracy (RA 4.88 Y"
Performance Required - Mean Reference Metho<RA<20Yo
Performance Specifi cation Methor PS2
' Dclimiter for us not uscd in RA calculstions
Confidence Coeflicient, CC
cc = ltozt , sallVn I
where,
to.rrt _ Zil!_= degrees of fieedom value
n 9 : number of runs selected for calculating the RASd 1.301 : standard deviation ofdifference
CC 1.000 = confidence coeflicient
Relative Accuracy, RA
ld l+ lcclM = 7ri;;; xloo
where,d -0. I 7 = average difference of Reference Method and CEMSCC 1.000 = confidence coefficient
RM 23.941 = reference method, lb/hr
RA 4.88 = relative accuracy,oh
VFR Summary
Location:
Source:
Project No.:
Rio Tinto Kennecott -
Stack - SME0I I
AST-2024:2322
+ Dclimiter for ms not ucd in RA ca.lculations
Confidence Coeffi cient, CC
cc = ltolt , sallVn I
where,to.rr, 2.306 = degrees offreedom value
n 9 = number of runs selected for calculating the RA
Sd 22,869.17 = standard deviation of difference
CC 17,578.77 = confidence coefficient
Relative Accuracy, RA
ldl+lcclrut = -j;i--x100
where,d 16,140.00 = average difference of Reference Method and CEMS
CC 17,578.77 = confidence coefficient
RM 622,512.78 : reference method, scfrn-wet
RA 5.42 = relative acatracy,Vo
Run
No.Dete
Time Reference Method
Flow Rate
scfm-wet
CEMS
Flow Rate
scfm-wet
Average
Difference
scfm-wetStertEnd
I
2
3
4
5
6
7
8
9
l0
5129124
5129124
5/29t24
5n9t24
5129t24
5t29/24
5n9D4
5t29124
5129/24
5n9D4
0:05
l:33
l:54
2:51
3:12
3:33
4:10
4:31
4:52
5:34
0:25
l:53
2:14
3:l I
3:32
3:53
4:30
4:51
5:12
5:54
595,748
595,9 I 9
6IL,072
626,570
623,937
639,481
626,637
643,098
640, I 53
643,9t6
584,607
604,4t2
601,722
632,37'7
632,040
6t6,229
602,309
598,48 l
58s, I 78
582,409
I t,l4t
-8,493
9,350
-5,807
-8, I 03
23,252
24,328
44,6t7
54,975
Average 622.5t3 606.373 1 6.1 40
Standard Deviation (Sd'22,869
Confi dence Coefficient (CC'11578.772
Relstive Accuracy (RAl 5.42 0
Acceptability Criteria - Mean Reference Methoc s20%
Performance Specifi cation Methoc PS6
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T f (, lil'r r() n t (l n()t., P
Locrtlon Rlo Tltrto Konccon - M.gr.' UT
Sourcc Mdn St ck- SMEoII
Project No. AST-202+2322
Drtc OSlzglU
lraf, rll.tmlcE
DuctOrl.ntrdon: Vcnicd
Ducr Dcisn: --tEii-
Dkaocc from tr.r W.ll ao Outlldc of Pon: 296.00 ln
Ntpptc tragor: -----16- tn
Dcpth of Ducr: ----fi6- tn
crort scction.l Arcr of Du"t, --Jiif6-- ft'
No. ofT6t Pont: 4
otsrucc lr ----fr6l-ft
DLt.nc. A Duct Dim"t.^t ----lJl-(murr bG > oJ)
Dillucc B: 200.0 ft
Dktuc. B lruct Dimot ^,
-----i.l-(mur b. > 2)
Mldmum NuDbcr ofTravcNc Polnt!: 12
Acturl Nmbcr of T["cre Polot ,-----Jr-
Mdurcr (latdd ud Drtr): SPR 5D92024
Rcvld.r (lntdd ud Drk)t lrf 5n9Do24
LOCATION OF TRAVERSE POINTS
Nurld oJnM. polra N d furM.r
I
2
3
1
5
6
7
t
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2 3 ,156189101112
14.6
8J.4
6.1
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75.0
n1'
4.4
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29.6
70.4
t5.4
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32.3
67.7
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27.6
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11.4
85.4
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82.3
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B= 200ft.
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plll6rlpe
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Location Rio Tinto Kennecott - Magna, UT
Cyclonic Flow Check
Source Main Stack - SMEOll
Project No. AST-202 4-2322
Date 5129D4
Sample Point Angle (AP=0)
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III(
FraAI
II lll.llr,,r.r i,
Locrtion
Soure
Project No.
Prrrm.ter(t)
Consol. Uni$ / M.thod
Method 4 Data
lun
)il.
No.
,trlu!
;trn Tim.
!trd Tim.
lun Timc, min (0)
I
5t2qn4
VALID
10r05
t2 t2
60
M5-14
2
5t79/24
VALID
r2.5r
ti.5t
60
MJ.I4
3
5/29t24
VAIID
l4: l0
l5:10
60
l\,{-5- r 4
i{ctcr Corrcction Frctor (Y)
)rific. Crlibrrtion Vdu. (AH A)
t{u Vrcuum, in. Hg
I 003
l6Et
3
0 000
1.001
t.6ilj
0 000
t.001
I 6El
3
0 000
Vd.r Volumc, ft.3
0
5
l0
l5
zo
30
35
40
45
so
60
t20.225
t23.470
t26.774
829.994
833 t20
t36.32t
t39.453
t12 120
845.761
84t.894
t52.024
85i. rJ2
tJ8.294
85E 7lJ
861.970
t65.224
t6t.45 I
t7l 651
E74 &9
E7E. t02
tEl.354
tt45t7
tt7.7 l0
t90.965
t94 230
E91.414
897.650
900.930
904.tt5
907.420
9 l0 6E0
9t3 965
9t7.t50
920.420
923.745
926.960
930.135
933 J00
936.7t9
39 t3q
T.mp.raturc, "F
0
5
t0
l5
20
30
35
40
45
50
s5
60
Avcn8a Tamp.r.tur., oF (Tn)
Avcn8. T.mp.r.tur., oR (Tn)
Minimum Tamp.ratur., oF
Matartt
tttttt
tt
t9
90
90
9C)
9t
9t
9t
9l
t9
549tt
Probc Filtcr Vrcrum Imp. Etit
55
55
55
55
55
55
5-5
5_5
55
55
5-5
55
55
5,i
J!
Mct.r
ET
EE
tt
tt
8t
89
E9
89
89
89
89
89
89
89
54t
tt
Probc Filt.r tum Imp. Erit
49
49
46
46
46
46
46
49
49
49
49
49
49
48
46
Maa€r
E9
E9
t9
t9
{t9
90
90
90
90
90
90
90
90
90
549
t9
Probc Filts Vrcuum
l
3
3
l
l
l
3
3
l
3
3
3
l
3
3
Imp. Erit
-{0
-10
-s0
JO
50
,10
,sl
-51
5l
5l
JI
50
JI
50
50
lrrom.tric Pr6sur., ir. Hg (Pb)
uct.r Orific. Pr.!tur., in. WC (AH)
llct€r Prctturc, in. Ht (Pm)
irndrrd M..ar Voluma ft-3 lvmlt(
25 27
I 000
25.34
31.074
25.21
L000
25.i4
25.4i
1.000
75.52
32.t10
tnrlysir Typc
mping.r l, Pi./Port T6t, g
mping.r 1, Pr.fPo.t T6t, 8
mpinS.r 3, Pr.lPort T6t, t
mpint.r 4, Prc/Post Tcst, t
y'olum. Wrtcr Collcctcd, mL (Vl.)
;tsdrrd Wttcr Volumc, ftr (VP!td)
Uoirtur. Fnction Mcsur.d (BWS)
lB Mol.culrr W.itht, lbnb.mol. (dry) (Md)
\CM a.lihr.li^n ah..L V.tr,, ry^il
Crrvimetnc Grevimetric
H20
H20
Emp$
72t.9
701.9
635.2
7il.E
7| O
63t 7
24.9
9.1
35
H20
H20
E*ptr
753 E
7ll0
61t.7
775. r
713.9
639. I
21.3
t).4
??
H20
H20
E.pt-u
775.1
713.9
639. I
799.2
122.O
642._\qtr l
24.t
E.t
3.4
4t.6
2 292
0 069lt 7t
-t7
3 1.9
I 501
0 045
2t.71
o7
45.2
2.r32
0.0622til
Runl-RMData
Location: Rio Tinto Kennecott - Magna, UT
Source: Main Stack - SME0I I
Project No.: AST-2024-2322
Date; 5/29124
Time
Unit
Status
Uncorrected Run Average (Cour)
Cal Gas Concentration (Cyn)
Pretest System Zero Response
Posttest System Zero Response
Average Zero Response (Co)
Pretest System Cal Response
Posttest System Cal Response
Average Cal Response (Cnr)
Corrected Run Avera
l0:05
l0:06
l0:07
l0:08
l0:09
l0:10
l0:l I
l0:12
l0: l3
l0: l4
l0: l5
l0:16
l0: l7
l0: l8
l0: l9
l0:20
l0:21
l0:22
l0:23
l0:24
l0:25
Or - Outlet
o/o dry
Valid
t6.28
r2.00
0.01
0.00
0.00
t t.94
12.08
t2.01
16.33
16.32
16.3 I
16.30
16.30
t6.29
r 6.30
16.30
16.3 I
16.29
16.26
t6.29
16.26
16.27
16.26
t6.27
t6.25
16.25
16.26
t6.24
16.25
COz - Outlet
o/o dry
Valid
NOx - Outlet
ppmvd
Valid
6.27
15.00
0.08
0.08
0.08
14.84
t4.99
14.92
6.26
6.31
6.37
6.44
6.50
6.59
6.3s
6.t9
6.23
6.20
6.20
6.t7
6.14
6.t4
6.23
6.26
6.26
6.23
6.22
6.20
6.24
6.19
SOz - Outlet
ppmvd
Valid
36.49
15.00
0.04
0.01
0.03
14.96
t4.92
14.94
36.67
22.',l8
23.05
26.18
41.22
52.25
53.15
53.15
49.44
41.7',7
41.10
4t.04
37.18
32.34
29.98
31.66
32.t3
31.73
30.67
30.66
3 1.87
32.91
0.69
s.00
0.02
0.00
0.0 r
4.99
4.92
4.96
0.69
0.69
0.70
0.70
0.70
0.68
0.68
0.68
0.69
0.69
0.70
0.69
0.69
0.69
0.69
0.70
0.70
0.70
0.70
0.70
0.70
0.70
Run2-RMData
Rio Tinto Kennecott - Magna, UTLocation:
Source:
Project No.:
Main Stack - SME0I I
AST-2024-2322
Date: 5129124
Time
Unit
Status
Uncorrected Run Average (Cour)
Cal Gas Concentration (C*ra)
Pretest System Zero Response
Posttest System Zero Response
Average Zero Response (Co)
Pretest System Cal Response
Posttest System Cal Response
Average Cal Response (Cu)
Corrected Run A Corr
Or - Outlet COr - Outlet NOx - Outlet SOr - Outlet
o/o dry o/o dry ppmvd ppmvd
Valid Valid Valid Valid
12.00
0.01
0.00
0.00
1.94
12.08
t2.01
16.98
5.00
0.02
0.00
0.0 r
4.99
4.92
4.96
0.60
5.8s
1s.00
0.08
0.08
0.08
14.84
14.99
14.92
s.83
25.86
50.00
0.13
0.16
0.15
50.32
50.00
2s.70
I l:33
ll:34
I l:35
I l:36
I l:37
I l:38
I l:39
I l:40
I l:41
ll:42
l1:43
ll:44
I l:45
I l:46
I l:47
I l:48
ll:49
I l:50
I l:51
I l:52
I l:53
16.92
r6.95
16.97
16.98
r6.98
r7.01
17.01
17.02
r7.03
17.03
17.0 t
r7.00
16.99
17.05
17.03
17.04
17.01
16.98
16.98
16.98
16.98
0.63
0.63
0.62
0.62
0.62
0.61
0.6 r
0.60
0.60
0.6 r
0.6 r
0.61
0.60
0.58
0.58
0.58
0.s9
0.61
0.62
0.61
0.61
6. l0
6.02
s.93
5.85
5.93
s.87
5.90
5.89
5.87
s.84
s.94
6.03
5.16
5.64
5.62
5.75
5.68
5.73
s.84
5.84
5.78
68.49
67.50
62.07
40.73
28.1 1
21.99
18.08
16.63
15.65
15.24
15.27
15.38
15.99
16.40
17.t4
17.46
17.7 t
17.93
18.14
18.34
18.74
pllIATEE)Run3-RMData
Location:
Source:
Project No.:
Rio Tinto Kennecott - Magna, UT
Main Stack - SMEOI I
AST-2024-2322
Date: 5129124
Time
Unit
Status
Or - Outlet
o/o dry
Valid
CO, - Outlet
'/. dry
Valid
NOx - Outlet
ppmvd
Valid
SO: - Outlet
ppmvd
Valid
Uncorrected Run Average (Cou)
Cal Gas Concentration (Crur)
Pretest System Zero Response
Posttest System Zero Response
Average Zero Response (Co)
Pretest System Cal Response
Posttest System Cal Response
Average Cal Response (Cu)
16.96
12.00
0.01
0.00
0.00
I t.94
12.08
t2.01
r6.95
0.61
5.00
0.02
0.00
0.0 r
4.99
4.92
4.96
0.60
5.74
15.00
0.08
0.08
0.08
14.84
14.99
14.92
5.72
17.50
50.00
0.r3
0.l6
0.r5
s0.32
50.00
50.r6
17.35Corrected Run A
I l:54
I l:55
I l:56
I l:57
I l:58
I l:59
l2:00
l2:01
l2:02
l2:03
l2:04
l2:05
l2:06
l2:07
l2:08
l2:09
l2:10
l2:ll
l2:12
l2:13
12:14
t6.9'l
t6.97
16.96
16.98
16.98
16.99
16.99
17.00
r 7.00
16.99
r 6.98
t6.96
16.94
16.94
16.95
t6.92
16.93
16.91
16.91
16.93
r 6.98
0.61
0.61
0.60
0.60
0.6 r
0.60
0.60
0.60
0.61
0.6 r
0.61
0.6 r
0.61
0.6 r
0.61
0.61
0.61
0.61
0.61
0.61
0.60
5.78
5.77
5.76
5.60
5.6 r
s.60
5.62
s.66
s.68
5.82
5.81
5.85
5.85
5.84
5.8 r
5.80
5.79
5.7',7
5.79
5.'.t4
5.55
19.38
20.t9
20.53
20.66
21.28
20.89
20.88
19.40
17.60
16.87
16.28
15.91
15.54
15.24
15.14
15.13
15.31
15.12
15.21
15.3 I
15.61
Run4-RMData
Rio Tinto Kennecott - Magna, UTLocation:
Source:
Project No.:
Main Stack - SME0I I
AST-2024-2322
Date: 5129124
Time
Unit
Status
Uncorrected Run Average (Cou.)
Cal Gas Concentration (Cua)
Pretest System Zero Response
Posttest System Zero Response
Average Zero Response (Co)
Pretest System Cal Response
Posttest System Cal Response
Average Cal Response (Crtr)
Corrected Run A
l2:51
l2:52
12:53
l2:54
l2:55
l2:56
l2:57
l2:58
l2:59
I 3:00
l3:01
l3:02
I 3:03
l3:04
I 3:05
l3:06
I 3:07
I 3:08
l3:09
l3: l0
l3:l I
Or - Outlet
o/" dry
Valid
17.36
r 2.00
0.00
0.00
0.00
12.08
l r.98
t2.03
t'7.32
COz - Outlet
o/o dry
Valid
NOx - Outlet
ppmvd
Valid
4.62
15.00
0.08
0.09
0.09
14.99
15.02
15.0 I
4.56
SOr - Outlet
ppmvd
Valid
t3.74
s0.00
0.16
0.31
0.24
50.00
49.88
49.94
13.59
0.48
5.00
0.00
0.00
0.00
4.92
4.93
4.93
0.49
17.24
17.32
t'7.36
17.37
17.37
t7.36
17.38
17.37
t7.39
17.37
t7.37
17.37
t7.34
17.33
t7.37
t7.40
17.38
17.39
r 7.38
17.38
17.38
0.49
0.48
0.47
0.48
0.47
0.47
0.47
0.48
0.48
0.48
0.48
0.49
0.49
0.50
0.49
0.49
0.49
0.48
0.49
0.49
0.49
4.82
4.73
4.6t
4.67
4.58
4.41
4.44
4.47
4.57
4.s8
4.6t
4.63
4.66
4.63
4.55
4.46
4.5t
4.72
4.75
4.79
4.78
t5.27
15.09
14.56
14.34
14.00
14.06
13.91
13.64
13.77
13.86
r3.84
13.56
t3.52
t3.41
I 3.5s
l3.t l
t2.46
12.33
12.65
r 3.53
14.15
Run5-RMData
Location:
Source:
Project No.:
Rio Tinto Kennecott - Magna, UT
Main Stack - SME0I I
AST-2024-2322
Dilez 5129/24
Time
Unit
Status
Oz - Outlet
o/o dry
Valid
COr - Outlet
o/o dry
Valid
NOx - Outlet
ppmvd
Valid
SOz - Outlet
ppmvd
Valid
Uncorrected Run Average (Cou,)
Cal Gas Concentration (Crrra)
Pretest System Zero Response
Posttest System Zero Response
Average Zero Response (Co)
Pretest System Cal Response
Posttest System Cal Response
Average Cal Response (Cu)
t7.33
r 2.00
0.00
0.00
0.00
12.08
I 1.98
12.03
17.28
0.50
5.00
0.00
0.00
0.00
4.92
4.93
4.93
0.51
5.1 I
15.00
0.08
0.09
0.09
14.99
15.02
15.01
5.05
3 1.03
50.00
0. r6
0.31
0.24
50.00
49.88
49.94
30.98Corrected Run A
13:12
l3: l3
13:14
l3: l5
l3: l6
l3:17
l3: l8
l3: l9
l3:20
13:21
l3:22
l3:23
l3:24
l3:25
l3:26
l3:21
l3:28
13:29
I 3:30
13:31
l3:32
t7.37
t7.36
17.33
t7.34
17.34
17.35
17.36
17.35
17.33
17.35
t7.36
17.36
17.35
17.34
17.34
17.34
17.31
17.30
17.30
17.27
17.t3
0.49
0.49
0.50
0.50
0.49
0.48
0.48
0.49
0.50
0.50
0.49
0.50
0.50
0.51
0.50
0.s0
0.50
0.50
0.50
0.s0
0.55
4.89
4.84
4.94
4.90
6.26
6.93
6.43
4.99
4.78
4.80
4.76
4.76
4.73
4.81
4.82
4.82
4.84
4.96
s.05
4.96
5. l0
t4.63
r4.98
17.17
18.73
2l.36
22.11
22.3t
23.97
26.76
28.79
28.0s
29.46
30.08
29.80
29.15
31.46
32.41
39.35
53.69
65.83
7t.61
Run6-RMData
Location:
Source:
Project No.:
Rio Tinto Kennecott - Magna, UT
Main Stack - SME0I I
AST-2024-2322
Datez 5129124
Time
Unit
Status
Or - Outlet
o/o dry
Valid
COz - Outlet
o/o dry
Valid
NOx - Outlet
ppmvd
Valid
SOz - Outlet
ppmvd
Valid
Uncorrected Run Average (Cou,)
Cal Gas Concentration (Cr,a)
Pretest System Zero Response
Posttest System Zero Response
Average Zrro Response (Co)
Pretest System Cal Response
Posttest System Cal Response
Average Cal Response (Cru)
11.06
12.00
0.00
0.00
0.00
r 2.08
I 1.98
12.03
17.02
0.63
5.00
0.00
0.00
0.00
4.92
4.93
4.93
0.64
6.29
r 5.00
0.08
0.09
0.09
14.99
15.02
15.01
6.23
40.61
s0.00
0. l6
0.31
0.24
50.00
49.88
49.94
40.62Corrected Run A
I 3:33
l3:34
l3:35
l336
l3:37
l3:38
l3:39
l3:40
l3:41
l3:42
l3:43
l3:44
l3:45
l3:46
l3:47
l3:48
l3:49
l3:50
l3:51
l3:52
l3:53
17.07
17.05
17.05
17.04
17.05
17.05
t7.04
17.03
17.06
17.08
17.08
17.t0
17.09
17.06
17.08
17.07
17.07
17.06
17.06
17.06
t7.07
0.s8
0.60
0.62
0.64
0.64
0.64
0.64
0.63
0.63
0.63
0.63
0.62
0.63
0.64
0.64
0.64
0.63
0.62
0.62
0.62
0.61
5.66
5.97
6.r5
6. l5
6.t9
6.24
6.31
6.48
6.33
6.30
6.34
6.41
6.38
6.40
6.50
6.50
6.44
6.43
6.35
6.32
6.17
68.71
63.73
6s.2s
6s.37
65.74
64.51
62.83
64.71
42.88
29.03
23.48
21.37
20.57
20.16
21.57
24.17
25.35
25.56
25.55
25.98
26.33
Run7-RMData
Rio Tinto Kennecott - Magna. UTLocation:
Source:
Project No.:
Main Stack - SME0I I
AST-2024-2322
Date: 5129124
Time
Unit
Status
Uncorrected Run Average (Cour)
Cal Gas Concentration (CuJ
Pretest System Zero Response
Posttest System Zero Response
Average Zero Response (Co)
Pretest System Cal Response
Posttest System Cal Response
Average Cal Response (Cru)
Corrected Run A (Corr
Oz - Outlet
o/o dry
Valid
17.44
12.00
0.00
0.00
0.00
r 1.98
t t.96
I t.97
17.49
17.44
17.44
17.44
17.45
17.43
17.44
17.44
17.43
11.43
17.46
17.48
17.49
17.42
t7.44
17.44
t7.43
17.44
17.43
17.44
11.45
17.46
COz - Outlet
t/, dry
Valid
0.63
5.00
0.00
0.00
0.00
4.93
4.91
4.92
0.64
NOx - Outlet
ppmvd
Valid
6.40
15.00
0.09
0.00
0.05
15.02
14.98
15.00
6.38
SOz - Outlet
ppmvd
Valid
27.53
50.00
0.31
0.30
0.31
49.88
49.98
49.93
27.43
37.12
41.48
32.99
24.78
22.49
23.07
22.s8
23.57
23.97
22.96
22.80
22.25
21.04
20.28
20.54
21.7 |
21.78
21.12
27.75
44.62
59.29
l4: l0
14:l I
l4:12
l4: l3
l4:14
l4: l5
l4: l6
l4:17
l4: l8
l4:19
l4:20
l4:21
l4:22
l4:23
l4:24
l4:25
l4:26
l4:27
l4:28
l4:29
l4:30
0.63
0.63
0.62
0.62
0.62
0.62
0.62
0.63
0.63
0.63
0.63
0.62
0.62
0.63
0.63
0.63
0.63
0.63
0.62
0.62
0.62
6.10
6.t2
6.12
6.18
6.32
6.41
6.38
6.49
6.60
6.55
6.61
6.48
6.49
6.49
6.50
6.39
6.38
6.47
6.46
6.47
6.43
Run8-RMData
Rio Tinto Kennecott - Magna, UTLocation:
Source:
Project No.:
Main Stack - SME0ll
AST-2024-2322
Datez 5129/24
Time
Unit
Status
Uncorrected Run Average (Cour)
Cal Gas Concentration (Cr*rJ
Pretest System Zero Response
Posttest System Zero Response
Average Zero Response (Co)
Pretest System Cal Response
Posttest System Cal Response
Average Cal Response (Cnr)
Corrected Run A
Or - Outlet
oh dry
Valid
17.63
12.00
0.00
0.00
0.00
l r.98
I t.96
t.97
17.68
COr - Outlet
oh dry
Valid
NOx - Outlet
ppmvd
Valid
s.96
15.00
0.09
0.00
0,05
t5.02
14.98
t5.00
5.93
6.46
6.57
6.62
6.69
6.73
6.74
6.63
6.61
6.5',7
6.s6
6.24
5.91
s.56
s.26
5.29
5.41
5.07
s.06
5.02
s.06
5.1 I
SOz - Outlet
ppmvd
Valid
41.'77
50.00
0.3 r
0.30
0.31
49.88
49.98
49.93
41.78
66.58
64.91
62.17
58.87
56.14
53.85
54.8'7
53.97
50.58
50.24
42.65
24.96
18.47
15.54
16.32
26.40
28.88
30.26
32.27
34.05
35.21
0.6 t
s.00
0.00
0.00
0.00
4.93
4.91
4.92
0.62
l4:31
l432
l4:33
l4:34
l4:35
l4:36
l4:37
l4:38
l4:39
l4:40
l4:41
l4;42
l4:43
l4:44
l4:45
l4:46
l4:47
l4:48
l4:49
l4:50
l4:51
17.44
17.42
17.43
17.43
t7.42
17.45
17.52
r 7.50
17.47
17.52
17.52
17.47
17.58
17.78
17.90
17.95
t7.96
17.95
17.90
17.84
r 7.81
0.63
0.63
0.62
0.63
0.63
0.63
0.63
0.63
0.63
0.61
0.61
0.61
0.61
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60
FlaAI Run9-RMData
il
Location:
I I ii,,itt
Rio Tinto Kennecott - Maena. UT
Source: Main Stack - SMEOI I
Project N o.: AST -2024-2322
Datez 5129124
Time
Unit
Status
Uncorrected Run Average (Cou,)
Cal Gas Concentration (CrtrJ
Pretest System Zero Response
Posttest System Zero Response
Average Zero Response (Co)
Pretest System Cal Response
Posttest System Cal Response
Average Cal Response (Cu)
Corrected Run Average (Corr
Oz - Outlet
oh dry
Valid
17.58
12.00
0.00
0.00
0.00
I 1.98
I t.96
I1.97
t7.63
COz - Outlet
o/o dry
Valid
NOx - Outlet
ppmvd
Valid
5.32
15.00
0.09
0.00
0.05
15.02
14.98
15.00
5.29
s.00
5.12
5.14
5.20
5.22
5.25
s.38
5.36
s.44
5.45
5.45
5.40
5.32
5.24
5.27
5.38
5.38
s.36
5.40
5.48
5.56
SOz - Outlet
ppmvd
Valid
4t.47
50.00
0.3 r
0.30
0.3 r
49.88
49.98
49.93
4t.47
35.96
36.80
37.8s
38.4 r
40.42
43.88
45.99
45.44
4s.46
44.79
45.76
44.79
43.28
42.3t
4l .50
41.42
40.14
39.39
39.34
39.48
38.42
0.69
5.00
0.00
0.00
0.00
4.93
4.91
4.92
0.70
l4:52
l4:53
l4:54
l4:55
l4:56
l4:57
l4:58
l4:59
l5:00
l5:01
l5:02
I 5:03
l5:04
I 5:05
l5:06
l5:07
l5:08
l5:09
l5: l0
l5:l I
I 5:12
17.78
17.72
17.68
11.66
17.65
t7.61
17.59
11.59
17.56
17.56
17.52
17.52
17.52
t7.54
t7.52
17.53
17.54
r 7.55
17.55
r 7.55
t7.54
0.s9
0.60
0.62
0.63
0.64
0.66
0.68
0.69
0.70
0.70
0.72
0.72
0.72
0.72
0.73
0.73
0.73
0.72
0.72
0.72
0.72
Run 10 - RM Data
Rio Tinto Kennecott - Magna, UTLocation:
Source:
Project No.:
Main Stack - SME0I I
AST-2024-2322
Date; 5129124
Time
Unit
Status
Uncorrected Run Average (Cou.)
Cal Gas Concentration (Cm,l)
Pretest System Zero Response
Posttest System Zero Response
Average Zero Response (Co)
Pretest System Cal Response
Posttest System Cal Response
Average Cal Response (Crnr)
Corrected Run A
Or - Outlet
o/o dry
Valid
17.41
12.00
0.00
0.00
0.00
1.96
l 1.96
I 1.96
17.47
COr - Outlet
o/o dry
Valid
NOx - Outlet
ppmvd
Valid
5.43
rs.00
0.00
0.01
0.01
r4.98
t4.97
14.98
5.43
SOr - Outlet
ppmvd
Valid
24.44
50.00
0.30
0.34
0.32
49.98
49.87
49.93
24.32
0.74
5.00
0.00
0.00
0.00
4.91
4.92
4.92
0.76
l5:34
l5:35
l5:36
l5:37
l5:38
l5:39
l5:40
l5:41
l5:42
l5:43
l5:44
l5:45
l5:46
l5:47
l5:48
l5:49
l5:50
l5:51
l5:52
l5:53
l5:54
17.37
t7.36
17.35
17.37
t7.39
17.42
17.43
17.42
17.45
17.44
t7.44
t7.42
17.42
17.43
17.44
17.44
t7.46
17.45
17.44
t7.33
17.33
0.74
0.74
0.75
0.75
0.75
0.75
0.'7s
0.75
0.75
0.75
0.75
0.74
0.7 5
0.'74
0.74
0.73
0.73
0.72
0.74
0.76
0.75
5.33
5.33
s.40
5.41
5.47
5.53
5.59
5.63
5.55
5.57
5.56
5.56
5.57
5.56
5.50
5.36
5. l0
5.10
5.r8
5.32
5.35
16.17
r 6.91
17.76
18.82
t9.s4
20.58
21.31
22.70
23.98
24.39
25.50
27.92
29.46
29.78
29.67
29.32
29.38
28.94
27.61
27.20
26.38
A/lrerlrcE)
i- ' i r. {l:) ii'
Location Rio Tinto Kennecott - Magna, UT
QA Data
Source Main Stack - SME0I I
Proj ect N o. AST -2024 -2322
Parameter O, - Outlet CO: - Outlet NOx - Outlet SOr - Outlet
Make
Model
S/N
Oneratins Range
SERVOMEX
1440
1420013279
25
SERVOMEX
t440
t4ts0/3279
25
THERMO
42iQ
12327730521
50
THERMO
43i
r 336459886
50
THERMO
43i
I 336459886
100
Cylinder ID
Zero
Mid
Hish
NA
cc1s9630
cc759630
NA
cc759630
cc759630
NA
E80050386
EB0050386
NA
EB00s0386
E80050386
NA
E80087789
EB0087789
Cylinder Certifed Values
Zero
Mid
Hish
NA
23.95
23.95
NA
23.9
23.9
NA
50.0
50.0
NA
48. l
48. I
NA
497
497
Cylinder Expiration Date
Zero
Mid
Hish
NA
9ll913t
9ll913t
NA
9lt913t
9il9131
NA
7127129
1127129
NA
7127129
7127129
NA
8t23t3t
8/2313t
Tvoe of Samnle Line Heated S le Line
plll6lpe
I [ ( ] I I l'.1 I (
Location:
Source:
Project No.:
:/\I (irjar![]
Rio Tinto Kennecott - Magna, UT
Response Times
Main Stack - SME0I I
AST-2024-2322
seconds
Parameter Or - Outlet COr - Outlet NOx - Outlet SOr - Outlet
Zero
Low
Mid
Hish
45
NA
50
50
45
NA
50
50
50
NA
60
60
54
NA
60
60
Averase 48.3 48.3 56.7 58.0
FliTAIIEE),t:Calibration Data
Rio Tinto Kennecott - Magna, UTLocation:
Source:
Project No.:
Main Stack - SME0I I
AST-2024-2322
Date: 5129124
Parameter Or - Outlet COr - Outlet NOx - Outlet SOz - Outlet
Exoected Averase Concentration 17.00 5.00 10.00 15.00
Span Between
Low
High
Desired Snan
17.00
85.00
23.95
5.00
25.00
10.00
10.00
50.00
30.00
1s.00
75.00
30.00
Low Range Gas
Low
Hish
NA
NA
NA
NA
NA
NA
NA
NA
Mid Range Gas
Low
Hish
9.58
14.37
4.00
6.00
r 2.00
18.00
t2.00
18.00
High Range Gas
Low
Hish
NA
NA
NA
NA
NA
NA
NA
NA
Actual Concentration (% or ppm)
Zero
Low
Mid
Hieh
0.00
NA
r 2.00
23.9s
0.00
NA
5.00
10.00
0.00
NA
15.00
30.00
0.00
NA
15.00
30.00
Upscale Calibration Gas (Cnm)Mid Mid Mid Mid
Instrument Response (% or ppm)
Zero
Low
Mid
Hish
0.02
NA
12.05
23.94
0.01
NA
5.04
10.03
0.00
NA
14.87
30.02
0.00
NA
t4.99
30.1 3
Performance (7o of Span or Cal. Gas Conc.)
Zero
Low
Mid
Hish
0.08
NA
0.2t
0.04
0. r0
NA
0.40
0.30
0.00
NA
0.43
0.07
0.00
NA
0.03
0.43
Status
Zero
Low
Mid
Hieh
PASS
NA
PASS
PASS
PASS
NA
PASS
PASS
PASS
NA
PASS
PASS
PASS
NA
PASS
PASS
Fl Ttt,AI lEe Calibration Data
Rio Tinto Kennecott - Magna, UT
Main Stack - SME0I I
Location:
Source:
Project No.:
Date:
AST-2024-2322
5t29t24
Parameter Oz - Outlet COr - Outlet NOx - Outlet SOz - Outlet
Exoected Averase Concentration 16.28 0.69 6.27 50.00
Span Between
Low
High
Desired Snan
16.28
81.41
23.95
0.69
20.00
10.00
6.27
31.35
30.00
s0.00
250.00
r 00.00
Low Range Gas
Low
Hish
NA
NA
NA
NA
NA
NA
NA
NA
Mid Range Gas
Low
Hish
9.s8
14.37
4.00
6.00
12.00
r 8.00
40.00
60.00
High Range Gas
Low
Hish
NA
NA
NA
NA
NA
NA
NA
NA
Actual Concentration (%o or ppm)
Zero
Low
Mid
Hish
0.00
NA
12.00
23.95
0.00
NA
5.00
10.00
0.00
NA
15.00
30.00
0.00
NA
50.00
100.00
Upscale Calibration Gas (Cnra)Mid Mid Mid Mid
Instrument Response (7o or ppm)
Zero
Low
Mid
Hish
0.02
NA
t2.05
23.94
0.01
NA
5.04
10.03
0.00
NA
14.87
30.02
0.04
NA
50.05
100.28
Performance (7o of Span or Cal. Gas Conc.)
Zero
Low
Mid
Hish
0.08
NA
0.21
0.04
0.10
NA
0.40
0.30
0.00
NA
0.43
0.07
0.04
NA
0.05
0.28
Status
Zero
Low
Mid
Hish
PASS
NA
PASS
PASS
PASS
NA
PASS
PASS
PASS
NA
PASS
PASS
PASS
NA
PASS
PASS
FrerAIIEE):t':
Bias/Drift Determinations
Rio Tinto Kennecott - Magna, UTLocation:
Source:
Project No.:
Main Stack - SMEOI I
AST-2024-2322
Parameter O" - Outlet COr - Outlet NOx - Outlet SOr - Outlet
Run I
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest Svstem Uoscale Response
0.0 r
0.00
I t.94
12.08
0.02
0.00
4.99
4.92
0.08
0.08
14.84
t4.99
0.04
0.01
14.96
14.92
Run 2
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
0.01
0.00
1t.94
12.08
0.02
0.00
4.99
4.92
0.08
0.08
14.84
t4.99
0. l3
0. l6
50.32
50.00
Run 3
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
0.01
0.00
I 1.94
12.08
0.02
0.00
4.99
4.92
0.08
0.08
14.84
14.99
0. l3
0. l6
50.32
50.00
Run 4
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
0.00
0.00
r2.08
l r.98
0.00
0.00
4.92
4.93
0.08
0.09
14.99
15.02
0. l6
0.31
50.00
49.88
Run 5
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
0.00
0.00
r2.08
I 1.98
0.00
0.00
4.92
4.93
0.08
0.09
14.99
15.02
0. l6
0.31
50.00
49.88
Run 6
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
0.00
0.00
t 2.08
I 1.98
0.00
0.00
4.92
4.93
0.08
0.09
14.99
15.02
0. l6
0.31
50.00
49.88
Run 7
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
0.00
0.00
r r.98
I 1.96
0.00
0.00
4.93
4.9t
0.09
0.00
15.02
14.98
0.31
0.30
49.88
49.98
Run 8
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest Svstem Upscale ResDonse
0.00
0.00
I 1.98
I1.96
0.00
0.00
4.93
4.91
0.09
0.00
t 5.02
r4.98
0.3 r
0.30
49.88
49.98
Run 9
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
0.00
0.00
r r.98
I1.96
0.00
0.00
4.93
4.91
0.09
0.00
r 5.02
r 4.98
0.31
0.30
49.88
49.98
Run l0
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest Svstem Upscale ResDonse
0.00
0.00
r r.96
I 1.96
0.00
0.00
4.91
4.92
0.00
0.01
r4.98
14.9'l
0.30
0.34
49.98
49.87
Bias/Drift Determinations
Location: Rio Tinto Kennecott - Maena. UT
Source: Main Stack - SME0I I
Project No.: AST-2024-2322
Parameter Oz - Outlet CO, - Outlet NOx - Outlet SO" - Outlet
Run I Date 5n9n4
Span Value
Initial Instrument Zero Cal Response
Initial Instrument Upscale CaI Response
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
23.95
0.02
r 2.05
0.01
0.00
I 1.94
r 2.08
r0.00
0.01
5.04
0.02
0.00
4.99
4.92
30.00
0.00
14.87
0.08
0.08
14.84
t4.99
30.00
0.00
t4.99
0.04
0.0 r
14.96
t4.92
Bias (%)
Pretest Zero
Posttest Zero
Pretest Span
Posttest SDan
-0.06
-0.08
-0.46
0. l3
0.08
-0. l0
-0.50
-1.20
0.27
0.27
-0. l0
0.40
0.l3
0.03
-0. l0
-0.23
Drift (%)
Zero
Mid
-0.03
0.58
-0. l8
-0.70
0.00
0.50
-0. l0
-0.13
Run 2 Date 5129124
Span Value
lnstrument Zero Cal Response
lnstrument Upscale Cal Response
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
23.95
0.02
12.05
0.0 r
0.00
I t.94
12.08
r0.00
0.0 r
5.04
0.02
0.00
4.99
4.92
30.00
0.00
t4.87
0.08
0.08
14.84
14.99
r00.00
0.04
50.05
0. l3
0. l6
50.32
50.00
Bias (%)
Pretest Zero
Posttest Zero
Pretest Span
Posttest Soan
-0.06
-0.08
-0.46
0. l3
0.08
-0. l0
-0.50
-1.20
0.27
0.27
-0. l0
0.40
0.30
0.40
0.90
-0.17
Drift (%)
Zero
Mid
-0.03
0.58
-0. l8
-0.70
0.00
0.50
0.03
-0.32
Run 3 Date 5D9124
Span Value
Instrument Zero Cal Response
Instrument Upscale Cal Response
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
23.95
0.02
r 2.05
0.0 r
0.00
r 1.94
t 2.08
r 0.00
0.0 r
5.04
0.02
0.00
4.99
4.92
30.00
0.00
14.87
0.08
0.08
r 4.84
t4.99
100.00
0.04
50.05
0. l3
0. l6
50.32
50.00
3ias (%)
Jretest Zero
losttest Zero
?retest Span
Josttest Span
-0.06
-0.08
-0.46
0. l3
0.08
-0. r0
-0.50
-t.20
0.27
0.27
-0. l0
0.40
0.09
0.12
0.27
-0.0s
)rift (%)
Zero
\4id
-0.03
0.58
-0.r8
-0.70
0.00
0.50
0.03
-0.32
Bias/Drift Determinations
Location:
Source:
Project No.:
Main Stack - SME0I I
Rio f into Kennecott - Magna, UT
AST-2024-2322
Parameter Or - Outlet CO: - Outlet NOx - Outlet SO: - Outlet
Run 4 Date 5129124
Span Value
Instrument Zero Cal Response
Instrument Upscale Cal Response
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest Svstem Uoscale Response
23.95
0.02
12.05
0.00
0.00
12.08
I 1.98
10.00
0.0 r
5.04
0.00
0.00
4.92
4.93
30.00
0.00
14.87
0.08
0.09
14.99
15.02
r 00.00
0.04
50.05
0. l6
0.31
50.00
49.88
Bias (%)
Pretest Zero
Posttest Zero
Pretest Span
Posttest Soan
0.08
0.08
0.13
0.29
0. l0
0.r0
t.20
l. t0
0.27
0.30
0.40
0.50
0.12
0.2'7
0.05
0. l7
Drift (%)
Zero
Mid
0.00
-0.42
0.00
0. l0
0.03
0. l0
0. l5
-0.12
Run 5 Date Sl29l24
Span Value
Instrument Zero Cal Response
Instrument Upscale Cal Response
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
23.95
0.02
12.05
0.00
0.00
12.08
l r.98
10.00
0.0 r
5.04
0.00
0.00
4.92
4.93
30.00
0.00
t4.8'.7
0.08
0.09
14.99
15.02
100.00
0.04
50.05
0.r6
0.31
50.00
49.88
Bias (%)
Pretest Zero
Posttest Zero
Pretest Span
Posttest Span
0.08
0.08
0. l3
0.29
0. l0
0. l0
1.20
l.l0
0.27
0.30
0.40
0.s0
0. r2
0.27
0.05
0. l7
Drift (%)
Zero
Mid
0.00
-0.42
0.00
0. l0
0.03
0. l0
0.l5
-0.12
Run 6 Date 5129124
Span Value
Instrument Zero Cal Response
Instrument Upscale Cal Response
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
23.95
0.02
12.05
0.00
0.00
12.08
I 1.98
10.00
0.01
5.04
0.00
0.00
4.92
4.93
30.00
0.00
14.87
0.08
0.09
14.99
15.02
100.00
0.04
50.05
0.r6
0.31
50.00
49.88
Bias (%)
Pretest Zero
Posttest Zero
Pretest Span
Posttest Span
0.08
0.08
0.13
0.29
0.10
0. r0
1.20
l. l0
0.27
0.30
0.40
0.50
0.12
0.2'1
0.05
0.t'7
Drifi(%)
Zero
Mid
0.00
-0.42
0.00
0. l0
0.03
0. l0
0. l5
-0.12
AI FtarEe Bias/Drift Determinations
li !:
Location: Rio Tinto Kennecott - Maena- UT
Source: Main Stack - SME0I I
Project No.: AST-2024-2322
Parameter Oz - Outlet COz - Outlet NOx - Outlet SO" - Outlet
Run 7 Date 5129124
Span Value
Instrument Zero Cal Response
Instrument Upscale Cal Response
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest Svstem Uoscale Resoonse
23.95
0.02
12.05
0.00
0.00
I 1.98
I1.96
10.00
0.01
5.04
0.00
0.00
4.93
4.91
30.00
0.00
14.8'7
0.09
0.00
15.02
r 4.98
r 00.00
0.04
50.05
0.3 r
0.30
49.88
49.98
Bias (%)
Pretest Zero
Posttest Zero
Pretest Span
Posttest Snan
0.08
0.08
0.29
0.38
0.r0
0.r0
l.t0
1.30
0.30
0.00
0.50
0.37
0.27
0.26
0. l7
0.07
Drift(%)
Zero
Mid
0.00
-0.08
0.00
-0.20
-0.30
-0. r3
-0.01
0. l0
Run 8 Date 5129124
Span Value
Instrument Zero Cal Response
Instrument Upscale Cal Response
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
23.95
0.02
12.05
0.00
0.00
I 1.98
I r.96
10.00
0.01
5.04
0.00
0.00
4.93
4.91
30.00
0.00
t4.87
0.09
0.00
15.02
14.98
100.00
0.04
50.05
0.3 r
0.30
49.88
49.98
Bias (%)
Pretest Zero
Posttest Zero
Pretest Span
Posttest Span
0.08
0.08
0.29
0.38
0. l0
0. l0
l.l0
1.30
0.30
0.00
0.50
0.37
0.2'1
0.26
0. l7
0.07
Drift(%)
Zero
Mid
0.00
-0.08
0.00
-0.20
-0.30
-0. l3
-0.01
0. l0
Run 9 Date 5129124
Span Value
Instrument Zero Cal Response
Instrument Upscale Cal Response
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
23.95
0.02
12.05
0.00
0.00
r r.98
I1.96
r 0.00
0.0 r
5.04
0.00
0.00
4.93
4.9t
30.00
0.00
14.87
0.09
0.00
15.02
14.98
100.00
0.04
50.05
0.31
0.30
49.88
49.98
Bias (%)
Pretest Zero
Posttest Zero
Pretest Span
Posttest Span
0.08
0.08
0.29
0.38
0. l0
0. r0
l.l0
1.30
0.30
0.00
0.50
0.37
0.27
0.26
0.17
0.07
Drift(%)
Zero
Mid
0.00
-0.08
0.00
-0.20
-0.30
-0. l3
-0.0 r
0. l0
Bias/Drift Determinations
II .ll
Location:
Sou rce:
Project No.:
Main Stack - SMEOI I
Rio Tinto Kennecott - Magna, UT
AST-2024-2322
Parameter O, - Outlet COr - Outlet NOx - Outlet SOr - Outlet
Run l0 Date 5129124
Span Value
Instrument Zero Cal Response
Instnrment Upscale Cal Response
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
23.95
0.02
12.05
0.00
0.00
r r.96
I1.96
r 0.00
0.01
5.04
0.00
0.00
4.91
4.92
30.00
0.00
14.87
0.00
0.01
r4.98
14.97
100.00
0.04
50.05
0.30
0.34
49.98
49.8'1
Bias (%)
Pretest Zero
Posttest Zero
Pretest Span
Posttest Soan
0.08
0.08
0.38
0.38
0.r0
0.r0
r.30
t.20
0.00
0.03
0.3 7
0.33
0.26
0.30
0,07
0.18
Drift(%)
Zero
Mid
0.00
0.00
0.00
0. l0
0.03
-0.03
0.04
-0.1 1
&*P!il--.
Accreditatlon #82754
Red Ball Technical Gas Service
555 Craig Kennedy Way
Shreveport, A 71107
800-551 -8{ 50
PGVP Vendor lO # G12023
EPA PROTOGOL GAS CERTIFICATE OF ANALYSIS
Cylinder Number:
Product lD Number:
Cylinder Pressure:
coA #
Customer PO. NO.:
Customer:
1c759630
127907
r900 PslG
1c759630.20230830-0
Certificatlon Oate:
Expiration Oate:
MFG Facility:
Lot Number:
Tracking Number:
Prevlous Certirication Oates:
09121t2023
c9t19t2031
- Shreveport - LA
cc759630.20230830
1 01 309330
per the May 20 1 2 EP A 1 t aceabi lity P rotocol, Document EPA-500/R- 1 2/53 1,
G2.
Component ConcsntraUon Uncertalnty Analytlcal Prlnclpla Assayed On
cc737012
E80022021
cc737012.20230228
EB0022021.20140323
I 162980025 09t13DO23
017146467 09n1n023
SMART-CERT
This is to certify the gases referenced have been calibrated/tested, and verified to meet the defined specifications. This
calibration/test was performed using Gases or Scales that are traceable through National lnstitute of Standards and
Technology (NIST) to the lnternational System of Units (Sl). The basis of complrance stated is a comparison of the
measurement parameters to the specified or required calibration/testing process. The expanded uncertainties use a coverage
factor of k=2 to approximate the 95% confldence level of the measurement, unless otherwise noted. This calibration certificate
applies only to the item described and shall not be reproduced other than in full, without written approval from Red Ball
Technical Gas Services. lf not included, the uncertainty of calibrations are available upon request and were taken into account
when determining pass or fail.
4n-
,/-tn. &rrl
Timothy Davis
Analytical Chemist
Assay Laboratory: Red Ball TGS
Version 02-J, Revised on 2018-09-17
.r'{,t.r,?';.-i \v/ i-ni**z /^\:.2.r,,1.. s.
L#*PJ*f,--
Accreditation #62754
Red Ball Technical Gas Service
555 Craig Kennedy Way
Shreveport, A 71107
800-551 -81 50
PGVP Vendor lD * G12023
EPA PROTOGOL GAS CERTIFICATE OF ANALYSIS
Cylinder Number:
Product lD Number:
Cylinder Pressure:
coA #
Customer PO. NO.:
Customer:
:80087789
123897
9OO PSIG
:40087789.2023061 4-0
Certification Date:
Expiration Date:
MFG Facility:
Lot Number:
Tracking Number:
Previous Certifi cation Dates:
)8t25t2023
1Al?312031
:80087789 2O23O814
195287456
been certified per the May 2012 EPAT'ac,€ability Protocol, Document 12t531,
G1
I
Concentration Uncertalnty Analytical Prlnclple Assayed On
Analytical lnstrumentation
Princ ry
HoribaSO2 NDIR vtA-510 so2 G000G2A o8t17no23
SMART-CERT
This is to certify the gases referenced have been calibrated/tested, and verified to meet the defined specifications. This
calibration/test was performed using Gases or Scales that are traceable through National lnstitute of Standards and
Technology (NIST) to the lnternational System of Units (Sl). The basis of compliance stated is a comparison of the
measurement parameters to the specifled or required calibration/testing process. The expanded uncertainties use a coverage
factor of k=2 to approximate the 95% confldence level of the measurement, unless otheMise noted. This calibration certificate
applies only to the item described and shall not be reproduced other than in full, without written approval from Red Ball
Technical Gas Services. lf not included, the uncertainty of calibrations are available upon request and were taken into account
when determining pass or fail.
-/'7,4n
Timothy Davis
Analytical Chemist
Assay Laboratory. Red Ball TGS
Version 02-J, Revised on 2018-09-17
il;
Red Ball Technical Gas Service
555 Craig Kennedy Way
Shreveport, LA 71107
800-6513150
PGVP Vondor lD # G12021
EPA PROTOCOL GAS CERTIFICATE OF ANALYSIS
Cylinder Numben
Product lD Number:
Cyllnder Prassurc:
GOA#
Customer PO. NO.:
Cugtomcr:
Certification Date:
Explradon Oate:
ilFG F.cillty:
Lot Numbor:
Tracking Number:
Prevlous Certifi csdon Dat6:
)7n9no21
)7t27120.29
- Shi€vemrl - L.A
=80050386.20210706173562063
This otandard has per thc iiby 2012 EPA Traceabiliv
G2.
Do Not ljse This Below l0O
Compon.nt Concondon Unc.rtrlnty Analytical Principl.A3rlyad On
Carbon Monoxide 49.8 PPM *0.2 PPM mR 07mt2021
Nltric Oxide 50.0 PPM t0.4 PPM Chemiluminescence 07h4n021,07n9n021
Sulfur Dioxide 48.1 PPM 10.12 PPM ND|R 07n2DO21,07n6nO21
Total Oxides of Nitogen 50.1 PPM
Nitrogen Balance
Certified
Analydcal tC$urom.nt Datr Avlll.ble
043790 043790.2)'t60714 01/08/2025 GM|S
--- cc 51 _ __-eg!grrJg0le-__.*wg@9_ sR'r
@72t119 CC726ai9.2019GI2t 05,!5,2{rU GMIS
EBe553a5 EB@5536.2O20042,a 09/26n@a GMls
N2 SO2 67 PPM 0.097 1694.
__]2 _ ---- -. __ N9- =-. 59-EP!!i -_- _.- -,0.r2 - --SRrr:8E4[N2 CO 4.2PPM 0.25a
Anahdcsl lnstnrmentadon
s02
NO
co
so2
NO
NOn
Chaf,ilminarc.nca
FTlR
NOIR
Ch.milumlm3canca
Ho.ba
Thm
Ml€
Hqibs
Th.mo
vla510 so2
4AGHL
MKS 2031q'G2Er(VS13T
vrA-sro so2
42iO-HL
GOOGzA 06/r&|2@1
11g26,42f)7 07toct2ut1
017ra6487 07EDtm1
GomG2A O7rNz@1111:,fj(xn7 07ranfI21
SMART4ERT
This is h certity he gases refecncsd have bcen calibratcd/tcsbd, and ,,erified b mcet thc defined specifications. This
calibraton/tGt was perlonr€d using Gascs or Scales that are tsacesble through Nruonal lnsfitjE of Stardarus and
TGcinology (NIST) to the lnEmational SFtrm ol UnlB (Sl). The b€-ds of compliance stat€d is a compartson of lhe
measucment paftrmeters to the 3pecified or rcquircd calibration/tcsting procass. The cxpand.d unc.rtEinti6 use a covemge
factor of k=2 b approxirnate the 95% confidenca lcr/d of the mcasutemcr( unlelr otharwilr nobd. This calibration cerilficatc
applic! onty b the item described and thsu nd bc cproduc€d o0lcr than in ftill, without wrttten appro\ral florn Red Bsll
Tecrln'tc8l Gas Scrviccs. lf not indud€d, the uncerteinty of calibrstions are avallable upon request and wer! takcn inb account
when deErmining pass or f,ail.
W:A"ah
Jasmine Godfroy
Analydcrl Cheml$
Asay Laboratory Red Ball TGS
Vsrion 02-r- RGYi.ed 6 201&0$17
rll.l l{:At
Location:
Project No.:
(l fl () trl,
fuo Tinto Kennecott - Magna, UT
AST-2024-2322
NO2 Converter Check - Outlet#Analyzer Model ffiCylinder ID Number #Cvlinder Concentration. pDm
Pre-Test Date 5128124 Time 15:39
Pre.Test Concentration, ppm 43.12
Pre-Test Efficiency. 7o 90
Post-Test Date Time
Post-Testcor"enFr-tioo,pp,
Post-Test Efficiencv. 7o
*Required Efficiency is 2
Airgas
an Air Uquido company
Airgas Specialty Gases
Airgas USA LLC
525 North Industrial toop Road
Tooele, UT 84o74
Airgas.com
CERTIFICATE OF ANALYSIS
Grade of Products EPA PROTOCOL STAMARI)
Part Number:
Cylinder Number:
Laboratory:
PGVP Number:
Gas Code:
E03Nt94E15W0005
cc509482
124 -Tooele (SAP)- UT
872023
N02,02,BALN
Reference Number:
Cylinder Volume:
Cylinder Pressure:
Valve Outlet:
Certification Date:
153-402667045-1
145.0 CF
201s PSIG
660
Mar 20,2023
Expiration Date: Mar 20,2026
Certification performed in accordance with 'EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)" document EPA
600/R- 1 2/531 , using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical
uncertainty as stated below with a confidence level of 95%. There are no signiflcant impurities which affect the use of this calibration mixture. All concentrations are on a
mole/mole basis unless otherwise noted. The results relate only to the items tested. The report shall not be reproduced except in full without approval of the laboratory. Do
Not Use This Cylinder below 100 psig, i.e. 0.7
Triad Data Available Upon Request
Sianafrrre an fila
ANALYTICAL RE,SULTS
Actual Protocol Total Relative
NITROGEN D|OXIDE 50.00 PPM 47.80 PPM Gl +l-2.O% NlSTTraceable 03/1312023,0312012023
OXYGEN 5.000 % 5.004o/o Gl +l-0.7% NlSTTraceable 0311312023
NITROGEN Balance
CALIBRATION STANDARDS
Type Lot lD Cylinder No Concentration Uncertainty Expiration Date
GMIS
NTRM
't2397
14060629
ccs1 1 358
cc436987
59.32 PPM NITROGEN DIOXIDE/NITROGEN
4,794 % OXYGEN/NITROGEN
+l-'l .4Vo
0.4Yo
ANALYTICAL EQUIPMENT
Analytical Principle Last Multipoint Calibration
MKS FT|R NO2 018143349
Horiba MPA-510 W603MM58 02
FTIR
02 Par
Mar 09, 2023
Mar 09, 2023
Approved for Release Page 1 of 1
Locstion:
Source:
Proj€ct No.:
Rio Tinto Kemecon -
Date 5/28/24
Analyzer Make:
Aralyzer Model:
Analyzer SN:
Environics ID:
ComponenL/Balance Gas:
Cylinder Gas lD (Dilution):
Cylinder Gas Concentration (Dilution), 7o:
Cylinder Gas ID (Mid-Level)r
Cylinder Gas Concenration (Mid-Level), %:
SERVOMEX
1440
1420013219
a4t2
cc759630
23.95
all AST Environics Units have 2-
Method Criterir EPA
P, rsmcter o)_
MIK€
NIodel
S/N
Snqn
JEKVUMEA
t440
t4200132'19
23.95
'vlinder Numher lD
Lero
Mid
tlish
NA
RR043 I I
aa? (061n
Svlinder Certifi ed Vslues
Zero
Mid
[fioh
0.0
I t.00
23.9s
lnstrument ResDonsc (7o or ppm)
Leto
Mid
Hioh
U,U I
I 1.02
23.93
Salibration Ges Selection (70 of SDrn'l
Mid
Hish
4s.9
r00.0
:elibmtion Error Pcrformance (7" ofSDrnl
Gro
tltid
Hish
0.1
-0 I
Linearitv (7o of Ranse)
0.1
Target Mass Flow
Contollem
Tsrg€t
Dilution
to/^\
Target Flow
Rate
lnm
Trrget
Concentrstion
(o/^l
Actual
Concentrution
(o/"\
Analyzer
Concentretion
(o/^r
Anslyzer
Concentration
lo/"\
rnJCctrou J
Analyzer
Concentration
(o/"\
AVeragc
Analyzer
Conccntration
lo/"\
Difference
lo/"\
Averoge Error
( *.2./.)
l0L/l0L 800 5.0 t9.2 t9.2 t9.24 19.25 t9. l9 9.23 0.03 o.t"h
t0ul0L 50.0 5.0 )t)20 196 206 12 03 t2.02 0.02 0.to/"
l0L/tL 20.0 40 4.8 48 4 lt4 4'16 416 -0 ut -o.30/"
l0t-/ I L 10.0 4.0 2.4 z.4u 2.41)0.0 t tJ. J"/o
Average
Analyzer
Concentrstion
t o/^\
lnjection I
Erlor
( *.2yol
lnjection 2
Eror
( +2./ol
lnjection 3
Error
( *.2"/"t
t9 23 0.to/.0.toa -o.20
2.0)-0 \"/^0 4"/o O lo/"
4.79 I to/"-o.6.k -O.6Yo
241 -0.3v"0.6v"-o.3vd
Gas Calibration Dircct to
Afr*
s0i,rqc: ItsIrNG
Mass Flow Controller Calibration
Document lC 620.009
Revisior 22.0
Effective Dat€12/16/22
lssuing Department Tech Seruices Pao€1of1
Diludon S)rstem Make:
Dilution System Model:
Dilution System SA:
Calibration Equipment Make:
Calibration Equipment Model:
Calibration Equipment SA:
Flor Cell S/t,l:
Flow Cell S/N:
Calibration Gas:
Barometric Pressure, mmHg:
Ambient Temperature,'F:
Environics
4040
u12-02-21-2024
Alicat Scientific
M-1O5LPD/5MM.D/5M,
272121
272121
272120
Nitrogen
25.U1
u.4
M-1StPl'/-Dl5M
Mass Flow Controller lD
Size, ccm:
Make:
Model:
s/N:
#1
10,000
Environics
rFc 202
626687006
#2
10,000
E nvironics
Ftc 202
626687003
#3
1,000
Environics
FFC 202
626683003
Set Flow True Flow Difference
cdmin cdmin
Set Flow True Flow Difhrence
cdmin cqlmin
Set Flow True Flow Difference
cclmin cclmin
5%
10%
20%
30%
40o/o
50%
60%
70%
80%
90%
100%
500 493 1.4%
1,000 1,008 0.8%
2,000 2,039 2.0%
3,000 3,061 2.0%
4000 4,079 2.0%
5,000 s,093 1.9%
6,000 6,110 1.8%
7,000 7,134 1.9%
8,000 8,154 19%
9,000 9,183 2.0%
10,000 10,202 2.0%
500 491 1.8%
1,000 1,013 1.3%
2,000 2,041 2.1%
3,000 3,074 2.5%
4,000 4,105 2.6%
5,000 5,127 2.5%
6,000 6,143 2.4%
7,000 1,168 2.4%
8.000 8,175 2.2%
9,000 9,190 2.1%
'10,000 10,202 2.0%
50 49 2.2%
100 99 0.9%
200 200 0.0%
300 301 0.3%
400 402 0.6%
500 503 0.6%
600 605 0.8%
700 707 1.0%
800 809 1.2%
900 914 1.5%
1,000 1,019 1.9%
Note: The mass flow controller's calibration values are used by the dilution system's operating software to improve accuracy. These calibrations are not necessarily
indicative of the s!6tems overall performance. Performance is verified by conducting a Method 205 prior to each field use.
Calibration Performed By: .lFT
Date 2/21/2024
-i .\ /; "--.i_\>j:/_r.-ffi*; -/r:\:t /^\:',.11,1),1. "
&*gl+*."
Accreditation #62754
Red Ball Technical Gas Service
555 Craig Kennedy Way
Shreveport, LA 71107
800-551-8't 50
PGVP Vendor lD # G12023
EPA PROTOCOL GAS CERTIFIGATE OF ANALYSIS
Cylinder Number:
Product lD Number:
Cylinder Pressure:
coA #
Customer PO. NO.:
Gustomer:
RR0431
't25371
1900 PS|G
RR0431 1 .20230831 -0
Certification Date:
Expiration Date:
MFG Facility:
Lot Number:
Tracking Number:
Previous certifi cation oates:
)9t21t2023
)9t19t2031
- Shreveport - LA
{R0431 1.20230631
I 07549958
This calibration standard has been certified per the May 201 Proiocol, Document EPA-600/R-121531,
G1.
I
Gertifi ed Concentration(s)
ConcentraUonw
11.00%
Uncertainty
*OJ,^/,
10.03 %
Analytlcal Principle
rnR
MPA
Assayed On
Dioxide 0912112023
09t1812023xygen
itrogen Balance
Analytical Measurement Data Available Online.
Reference Standard(s)
cc737012 2023022A
EBOO2202',t.20180323
1162980025 09nAnO23
017146467 09/21t2023
SMART-CERT
This is to certify the gases referenced have been calibrated/tested, and verified to meet the defined specifications. This
calibration/test was performed using Gases or Scales that are traceable through National lnstitute of Standards and
Technology (NIST) to the lnternational System of Units (Sl). The basis of compliance stated is a comparison of the
measurement parameters to the specified or required calibration/testing process. The expanded uncertainties use a coverage
factor of k=2 to approximate the 95% confidence level of the measurement, unless otherwise noted. This calibration certificate
applies only to the item described and shall not be reproduced other than in full, without writlen approval from Red Ball
Technical Gas Services. lf not included, the uncertainty of calibrations are available upon request and were taken into accounl
when determining pass or fail.
fu-.tLrh
Jasmine Godfrey
Analytical Chemist
Assay Laboratory: Red Ball TGS
Ve.sion 02-J Revised on 2018-09-17
AfatpE)
LI
Locetion Rio Tinto Kennecott - Masna. UT
QA Data
Source Main Stack - SME0I I
Project No. AST-2024-2322
Parameter(s) VFR
Drt€Pitot ID Evidence of
drmcsp?
Evidence of
micolionmanf,
Calibration or
Renlir reouired?
5n9/24 RTK I no no no
Dete Probe or
Thermncnrrnle II)
Reference
Temn^ (oF)
Indicated
Temn /o[t Difference Criteria
5t29t24 RTK I 890 89.0 0.0%+ 1.5 % (absolute)
Field Balence Check
Date 0st29t24
Balance ID:SCALE.23
Certified Weight ID:SLC-I KG-I
Certified Weight (g):1000.0
Measured Weight (g):I 000. I
Weight Ditference (g):-0.1
Dete Barometric
Prasrrrrp
Evidence of Reading Verified Calibration or
Danoir ranrrirarl,Weather Station Location
st29/24 Weather Station NA NA NA SALT LAKE CITY, UT
Date Nleter Box ID Positive Pressure Leak Check
5t29124 M5 t4 Pass
Alianrce DGM Calibration-Orifi ces
Document l[:6?04$4
Revisior 24.0
Effective Dat€v31/24
lssuing Depanment Iech Services Paq€lotl
EouiDment Detall - Dry Gas Meter
Console lD: M5-14
Meter S/N: 8219521
Critical Orifice 5/N: SH 40-73
Calibration Detall
lnitial Barometric Pressure, in. Hg (PbL)
Final Barometric Pressure, in. Hg (Pbr)
Averaqe Barometric Pressure, in. Hg (Pb)
25 60
25.60
25 60
Critifcal Orifice lD (Y)
K' Factor, ft3.R'/2 / in. wc min (K')
Vacuum Pressure, in. Hg (Vp)
lnitial DGM volume, ft3 (Vm,)
Final DGM Volume, ft3 (VmF)
Total DGM Volume. ft3 (vm)
SH-73
0.7864
12.0
551.000
576.3 58
25.358
SH-73 SH-63
0.6007
165
601 900
623.468
19 568
SH-63 SH-55
0.4524
17.5
659 200
673.919
14.719
SH-55
07864 0 601 0.452
120
577 300
602120
25.420
16.5
623.900
643.491
19 591
17.5
674900
689.615
14.715
Ambient Temperature, "F (Ta)
lnitial DGM Temperature, 'F (Tmr)
Final DGM Temperature, 'F (Im,
Averaoe DGlv Temoerature. 'F (Tm)
68
68
69
69
72
72
73
73
73
73
74
74
75
75
75
75
76
76
76
76
76
76
Elapsed Time (O)
Meter Orifice Pressure, in. WC (AH)
Standard Meter volume, ft3 (Vmstd)
Standard Critical Orifice Volume, ft3 (Vcr)
Meter Correction Factor (Y)
-olerance
Orifice Calibration Value (AH @)
Tolerance
Orifice Cal Check
25.00
270
21.8483
21.9096
1 003
0.000
1704
0.023
25 00
2.70
21.7371
21.8270
1.004
0.001
1.704
0.023
25 00
160
16.6492
16 6571
1 000
0.003
1.725
0 044
25.00
160
16 6376
16.6415
1 000
0.003
1 725
0.044
25.00
0.85
12.4500
12.5214
1.006
0.003
1 612
0.068
25.00
085
12.4350
12.5097
1.006
0.003
1.614
0.067
031 055 0.55
Meter Correction Factor (Y)1.003
f,rifice Calibration Value (AH @)1.681
)ositive Pressure Leak Check Yes
Equipment Detail - Thermocouple Sensor
Reference Calibrator Make
Reference Calibrator Model
Reference Calibrator S/N
Calibration Detail
Practical Instrument Electronics
Piecal 5208
887216
Reference Temp.Display Temp.Accuracy Absolute
Difference
oF oR I K 7o oF
0
68
100
460
528
560
0
66
98
460
526
558
0.0
0.4
0.4
0
2
2
223
248
273
683
708
733
))1
248
273
683
708
733
0.0
0.0
0.0
0
0
0
300
400
500
600
700
800
900
1,000
1,100
1,200
760
860
960
1,060
'1,160
1,260
1,360
1,460
1,560
1,660
300
398
497
599
701
800
900
1,000
1,101
1,201
760
858
957
r,059
1,161
1,260
r,360
1,460
1,561
1,661
0.0
0.2
03
0.1
-0 1
0.0
0.0
0.0
-0 1
-0.1
0
2
3
1
i
0
0
0
1
'1
Personnel
Shamit Nakra
Calibration By
Calibration Date
Reviewed By
Xander Gray Krahn
5/16/2024
pllr6lpe
T t_() ll l! l()Al (l R() lr P
Location: Rio Tinto Kennecott - Mama. UT
Source: Main Stack - SME0I I
Project No. : AST-2024-2322
Date:512912024
Traverse Point Time o2
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16.36
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UlAH DFPARIMENT OF
ENVIRONMENTAL QUALITY
DIVISION OF AIR OI'ATITY
UTAH DEPABTIIFNT OF
ETWIFIONMENTAL OUALITY
t;r i
and Det''sgre4!ION OF AIR OUALIT,Alla
RATA Report
Rio Tinto Kennecott
4700 Daybreak Parkway
South Jordan, UT 84095
Source Tested: Acid Plant l'ail Gas SMEO1 lb
Test Date: June 18.2024
Proj ect No. AST- 2024-2322-002
Prepared By
Alliance Technical Group, LLC
3683 W 2270 S, Suite E
West Valley City, UT 84120
Resulatorv Information
pJ/IATEE)
TICIiNICAL GROI]t)Source Tesl Report
Test Program Summary
Permit Nos.
Regulatory Citation
Source Information
DAQE-AN103460061-22
Title V Operating Permit 3500030004
40 CFR 60, Appendix B, PS 2
Source Nqme
Acid Plant Tail Gas
Contact Information
Permit ID
SMEOI Ib
Source ID
TailGas
Target Parameter
SOz
Test Location
Kennecott Utah Copper, LLC
4700 Daybreak Parkway
South Jordan, UT 84009
Jenny Esker
j enny.esker@riotinto. com
(801) s69-6494
Sean Daly
[e-mail]
(801)204-2s63
Andrew Bellard
[e-mail]
Test Company
Alliance Technical Group, LLC
3683 W 2270 S, Suite E
West Valley City, UT 84120
Project Manager
Charles Horton
charles.horton@al liancetg.com
(3s2) 663-7s68
Field Team Leader
Alan Jensen
alan j ensen@all iancetg. com
[phone]
QA/QC Manager
Kathleen Shonk
katie. shonk@al liancetg.com
(812) 4s2-478s
Report Coordinator
Delaine Spangler
delaine. spangler@alliancetg. com
Report Reviewer
Sarah Perry
[e-mail]
AST-2024-2322-002 RTK - Magna, UT Page i
ltNtciAL GB()!l'Source Test Report
C ertification Staleme nt
Alliance Technical Group, LLC (Alliance) has completed the source testing as described in this report. Results
apply only to the source(s) tested and operating condition(s) for the specific test date(s) and time(s) identified within
this report. All results are intended to be considered in their entirety, and Alliance is not responsible for use of less
than the complete test report without written consent. This report shall not be reproduced in full or in part without
written approval from the customer.
To the best of my knowledge and abilities, all information, facts and test data are correct. Data presented in this
report has been checked for completeness and is accurate, error-free and legible. Onsite testing was conducted in
accordance with approved intemal Standard Operating Procedures. Any deviations or problems are detailed in the
relevant sections in the test report.
This report is only considered valid once an authorized representative of Alliance has signed in the space provided
below; any other version is considered draft. This document was prepared in portable document format (.pdf) and
contains pages as identified in the bottom footer of this document.
7t17t2024
Charles Horton QSTI
Alliance Technical Group, LLC
Date
AST-2024-2322-002 RTK - Magna, UT Page ii
(, I I l..l I (),\ l ( i ti () ,l Source Test Reporl
Table of Conlenls
TABLE OF CONTENTS
l.l Process/Control System Descriptions. ..................... 1-l
1.4 Site-Specific Test Plan & Notification.................. ....................... l-l
3.1 U.S. EPA Reference Test Methods 1 and2 - Sampling/Traverse Points and Volumetric Flow Rate........3-l
3.2 U.S. EPA Reference Test Method 3l3A- Oxygen/Carbon Dioxide... ..............3-l
3.3 U.S. EPA Reference Test Method 4 - Moisture Content........ .....3-l
3.4 U.S. EPA Reference Test Method 6C - Sulfur Dioxide........ ....... 3-1
3.5 U.S. EPA Reference Test Method 205 - Gas Dilution System Certification. ........................3-2
3.6 Quality Assurance/Quality Control - U.S. EPA Reference Test Method 3/3A ............ .........3-2
3.7 Quality Assurance/Quality Conhol - U.S. EPA Reference Test Method 6C................ .........3-2
LIST OF TABLES
Table 2-l: Summary of Performance Specification Test Results ..............2-l
APPENDICES
Appendix A Sample Calculations
Appendix B Field Data
Appendix C Quality Assurance/Quality Control Data
Appendix D CEMS Data
AST-2024-2322-002 RTK - Magna, UT Page iii
pdltdrpe
It i,tiNl()n t Gti()itP Source Test Reporl
Inlroduclion
1.0 I ntroduction
Alliance Technical Group, LLC (Alliance) was retained by Rio Tinto Kennecott (RTK) to conduct performance
specification (PS) testing at the Smelter facility located in Magna, Utah. Portions of the facility are subject to
provisions of the 40 CFR 60, Appendix B, PS 2, the Utah Department of Environmental Quality, Division of Air
Quality (UDAQ) Approval Order (AO) DAQE-AN103460061-22 and the Title V Operating Permit No.
3500030004. Testing included conducting a relative accuracy test audit (RATA) to determine the relative accuracy
(RA) of the sulfur dioxide (SOz) continuous emissions monitoring system (CEMS) serving the Acid Plant Tail Gas
exhaust stack designated as SME0I I b.
1.1 Process/ControlSystemDescriptions
The off gases from the flash smelting and converting furnaces are treated in the double contact acid plant. The acid
plant is equipped with a SOz CEMS and is designed to operate with a tail gas SO2 concentration of 200 parts per
million, dry volume basis (ppmvd) or less during steady state operations. The tail gas exhaust stack from the acid
plant is vented to the main stack.
1.2 CEMS Descriptions
Pollutant
Parameter: SOz
Make: Unisearch Associates Inc.
Model: DAS-AR2047-00-FC-S02-B-P
SerialNo.: DAS22-001
Span: 0- l50ppm/0- l,500ppm
1.3 Project Team
Personnel involved in this project are identified in the following table.
Table l-l: Project Team
RTK Personnel Sean Daly
Andy Bellard
Alliance Personnel Alan Jensen
1.4 Site-Specific Test Plan & Notification
Testing was conducted in accordance with the Site-Specific Test Plan (SSTP) submitted to UDAQ by RTK.
1.5 Test Program Notes
Reference Method time is one hour behind plant CEMS time due to time zone changes.
AST-2024-2322-002 RTK - Magna, UT Page l-l
TECtINICAL GROUP Source Tesl Reporl
Summary of Results
2.0 Summary of Results
Alliance conducted PS testing at the Smelter facility located in Magna, Utah on June 18, 2024. Testng conducting a
RATA to determine the RA of the SOz CEMS serving the Acid Plant Tail Gas exhaust stack desigrated as
sMEol lb.
Table 2-l provides a summary of the emission testing results with comparisons to the applicable RA requirements.
Any difference between the summary results listed in the following table and the detailed results contained in
appendices is due to rounding for presentation.
Table 2-1: Summary of Performance Specification Test Results
RTK- Magna, UT
Sulfur Dioxide Data
Concentration, ppmvw
I Calculated using the applicable source standard for the pollutant. See Appendix B for the applicable standard used.
AST-2024-2322-002 Page 2-l
Parameter U.S. EPA Reference
Test Methods Notes/Remarks
Volumetric FIow Rate 1,2 Full Velocity Traverses
Oxygen/Carbon Dioxide 3t3A Integrated Bag / Instrumental Analysis
Moisture Content 4 Gravimetric Analvsis
Sulfur Dioxide 6C Instrumental Analysis
Gas Dilution System Certification 205
t;. ..
lc/Aliatpe Source Test Report
7'e s t i n g lv'l e thod o I ogy
3.0 Testing Methodology
The emission testing program was conducted in accordance with the test methods listed in Table 3-1. Method
descriptions are provided below while quality assurance/quality control data is provided in Appendix C.
Table 3-l: Source Testing Methodology
3.1 U.S. EPA Reference Test Methods I and 2 - Sampling/Traverse Points and Volumetric Flow Rate
The sampling location and number of traverse (sampling) points were selected in accordance with U.S. EPA
Reference Test Method L To determine the minimum number of traverse points, the upstream and downstream
distances were equated into equivalent diameters and compared to Figure I -2 in U.S. IIPA Reference Test Method I .
Full velocity traverses were conducted in accordance with U.S. EPA Reference Test Method 2 to determine the
average stack gas velocity pressure, static pressure and temperature. The velocity and static pressure measurement
system consisted of a pitot tube and inclined manometer. The stack gas temperature was measured with a K{ype
thermocouple and pyronreter.
Stack gas velocity pressure and temperature readings were recorded during each test run. 'lhe data collected was
utilized to calculate the volumetric flow rate in accordance with U.S. EPA Reference Test Method 2.
3.2 U.S. EPA Reference Test Method 3/3A - Oxygen/Carbon Dioxide
The oxygen (O:) and carbon dioxide (COz) testing was conducted in accordance with U.S. EPA Reference Test
Method 3/3A. One (l) integrated Tedlar bag sample was collected during each test run. 'fhe bag samples were
analyzed on site with a gas analyzer. The remaining stack gas constituent was assumed to be nitrogen for the stack
gas molecular weight determination. The quality control measures are described in Section 3.6.
3.3 U.S. EPA Reference Test Method 4 - Moisture Content
l'he stack gas rnoisture content (BWS) was determined in accordance with U.S. EPA Reference Test Method 4. I'he
gas conditioning train consisted of a series of chilled impingers. Prior to testing, each impinger was filled with a
known quantity of water or silica gel. IJach impinger was analyzed gravintetrically before and after each test run on
the sarne balance to deterrnine the anrount of moisture condensed.
3.4 U.S. EPA Reference Test Method 6C - Sulfur Dioxide
I'he sullur dioxide (SO2) testing was conducted in accordance with U.S. EPA Reference Test Method 6C. Data was
collected online and reported in one-minute averages. The sampling systern consisted of a heated stainless steel
probe, T'eflon sarnple line(s), gas conditioning systern and the identified analyzer. 1-he gas conditioning system was
a non-contact condenser used to remove moisture from the source gas. If an unheated J'eflon sanrple line was used,
AS',I -2024-2322-002 I{1 K Magna. Ll l'
rla
i l'.,,'t
AI lEe
{i I
Source Tesl Report
Tesling Methodolop,
then a portable non-contact condenser was placed in the system directly after the probe. Otherwise, a heated Teflon
sample line was used. The quality control measures are described in Section 3.7.
The relative accuracy of the SOz CEMS was determined based on procedures found in 40 CFR 60, Performance
Specification 2.
3.5 U.S. EPA Reference Test Method 205 - Gas Dilution System Certification
A calibration gas dilution system field check was conducted in accordance with U.S. EPA Reference Method 205.
An initial three (3) point calibration was conducted, using individual Protocol I gases, on the analyzer used to
complete the dilution system field check. Multiple dilution rates and total gas flow rates were utilized to force the
dilution system to perform two dilutions on each mass flow controller. The diluted calibration gases was sent
directly to the analyzer, and the analyzer response recorded in an electronic field data sheet. A mid-level supply gas,
with a cylinder concentration within l0% of one of the gas divider settings described above, was introduced directly
to the analyzer, and the analyzer response recorded in an electronic field data sheet. The cylinder concentration and
the analyzer response agreed within 2Yo. These steps were repeated three (3) times. The average analyzer response
agreed within2Yo of the predicted gas concentration. No single injection differed more than 2%ofrom the average
instrument response for that dilution. Copies of the Method 205 data can be found in the Quality Assurance/Quality
Control Appendix.
3.6 Quality Assurance/Quality Control - U.S. EPA Reference Test Method 3/3A
Cylinder calibration gases used met EPA Protocol I (+l- 2%) standards. Copies of all calibration gas certificates can
be found in the Quality Assurance/Quality Control Appendix.
Low-Level gas was introduced directly to the analyzer. After adjusting the analyzer to the Low-Level gas
concentration and once the analyzer reading was stable, the analyzer value was recorded. This process was repeated
for the High-Level gas. For the Calibration Error Test, Low, Mid, and High-Level calibration gases were
sequentially introduced directly to the analyzer. All values were within 2.0 percent of the Calibration Span or 0.5o/o
absolute difference.
At the completion of testing, the data was also saved to the Alliance server. All data was reviewed by the Field
Team Leader before leaving the facility. Once arriving at Alliance's office, all written and electronic data was
relinquished to the report coordinator and then a final review was performed by the Project Manager.
3.7 Quality Assurance/Quality Control - U.S. EPA Reference Test Method 6C
Cyf inder calibration gases used met EPA Protocol | (+l- 2%) standards. Copies of all calibration gas certificates can
be found in the Quality Assurance/Quality Control Appendix.
Low Level gas was introduced directly to the analyzer. After adjusting the analyzer to the Low-Level gas
concentration and once the analyzer reading was stable, the analyzer value was recorded. This process was repeated
for the High-Level gas. For the Calibration Error Test, Low, Mid, and High Level calibration gases were
sequentially introduced directly to the analyzer. All values were within 2.0 percent of the Calibration Span or 0.5
ppmv lo/o abso lute d ifference.
High or Mid Level gas (whichever was closer to the stack gas concentration) was introduced at the probe and the
time required for the analyzer reading to reach 95 percent or 0.5 ppmv/% (whichever was less restrictive) of the gas
AS'l-2024-2322-002 RTK - Magna. tJT'Page 3-2
FIAAIlEE!
i ill(r 'I l,l I r. ,,1
Source Test Report
Testing Melhodologt
concentration was recorded. The analyzer reading was observed until it reached a stable value, and this value was
recorded. Next, Low Level gas was introduced at the probe and the time required for the analyzer. reading to
decrease to a value within 5.0 percent or 0.5 ppmv/% (whichever was less restrictive) was recorded. If the Low-
Level gas was zero gas, the response was 0.5 ppmvlo/o or 5.0 percent of the upscale gas concentration (whichever
was less restrictive). The analyzer reading was observed until it reached a stable value and this value was recorded.
The measurement system response time and initial system bias were determined fi'om these data. The System Bias
was within 5.0 percent of the Calibration Span or 0.5 ppmv/% absolute difference.
High or Mid Level gas (whichever was closer to the stack gas concentration) was introduced at the probe. After the
analyzer response was stable, the value was recorded. Next, Low Level gas was introduced at the probe, and the
analyzer value recorded once it reached a stable response. The System Bias was within 5.0 percent of the
Calibration Span or 0.5 ppmvlo/o absolute difference or the data was invalidated and the Calibration Error Test and
System Bias were repeated.
Drift between pre- and post-run System Bias was within 3 percent of the Calibration Span or 0.5 ppmv/7o absolute
difference. If the drift exceeded 3 percent or 0.5 ppmv/%, the Calibration Error Test and System Bias were repeated.
To determine the number of sampling points, a gas stratification check was conducted prior to initiating testing. The
pollutant concentrations were measured at three points (16.7,50.0 and 83.3 percent of the measurement line). Each
traverse point was sampled for a minimum of twice the system response time.
If the pollutant concentration at each traverse point did not differ more than 5 percent or 0.5 ppmv/O.3% (whichever
was less restrictive) of the average pollutant concentration, then single point sampling was conducted during the test
runs. If the pollutant concentration did not meet these specifications but differed less than l0 percent or 1.0
ppmvl}.5%o from the average concentration, then three (3) point sampling was conducted (stacks less than 7.8 feet in
diameter - 16.7,50.0 and 83.3 percent of the measurement line; stacks greater than 7.8 feet in diameter - 0.4, 1.0,
and 2.0 meters from the stack wall). If the pollutant concentration differed by more than l0 percent or 1.0
ppmvl}.5Yo from the average concentration, then sampling was conducted at a minimum of twelve (12) traverse
points. Copies of stratification check data can be found in the Quality Assurance/Quality Control Appendix.
A Data Acquisition System with battery backup was used to record the instrument response in one (l) minute
averages. The data was continuously stored as a +.CSV file in Excel format on the hard drive of a computer. At the
completion of testing, the data was also saved to the Alliance server. All data was reviewed by the Field Team
Leader before leaving the facility. Once arriving at Alliance's office, all written and electronic data was
relinquished to the report coordinator and then a final review was performed by the Project Manager.
AS1'-2024-2322-002 RT K Magna, U'[Page 3-3
AllTarEE)Example Calculations
i I I'ill.]1. ."\l rlll(rLll'
Location Rio Tinto Kennecott - M
Source Acid Plent Tail Gas -
Project No. AST -2024-2322
Run No. I
Parameter(s) BWS
Meter Pressure (Pm), in. Hg
Pm=
where,
AHPb + 136
Pb 25.72 = barometric pressure, in. Hg
aH-T3O-= pressure differential of orifice, in H2o
Pm 25.77 = in. Hg
Standrrd Meter Volume (Vmstd), dscf
17.636xVmxPmxYVmstd =Tm
where,Y 1.003 = meter correction factor
vm -J6.60:-= meter volume, cfpmT = absolute meter pressure, in. Hg
rm -.ffi = absolute meter temperature, oR
vmstdT?T7-=dscf
Standard Wet Volume (Vwstd), scf
where,
Vwstd= 0.04716xVlc
Vlc 13.9 = weight of H2O collected, gvwstd-6]6.il=scf
Moisture Fraction (BWS), dimensionless
Vwstd
where,
BWS = /\/*r.i +\/*r,l\
Vwstd 0.656 = standard wet volume, scfVmstd....ffi-= standard meter volume, dscf
Bws --:-o'- = dimensionless
Molecular Weight (DRY) (Md), lb/lb-mole
Md : (0.44 x o/oCO2) + (0.32 x o/oO2) + (0.28 (100 -where,
CO, .; = carbon dioxide concentration, o/o
02 - = oxygen concentration, To
Md lbilb mol
o/o CO2 - o/o O2))
AllTalEE)
Location Rio Tinto Kennecott -
Source Acid Plant
Project No. AST-2024-2322
Run No, I
Parameter(s) BWS
Example Calculations
Molecular Weight (WET) (Ms), Ib/lb-mole
Ms=
where,
Md (1 - BWS) + 18.01s (BWS)
Md molecular weight (DRY), lb/lb molBWS 0.d13-:moisturefraction,dimensionlessMsT:lb/lbmol
Dry Gas Meter Calibration Check (Yqa), percent
Yqa =
where,
x 100
Y 1.003 : meter correction factor, dimensionlessO 60 : run time, min.Vr-]qq!3-: total meter volume, dcf
Tm 539.1 : absolute meter temperature, oR
AH@ I .681 : orifice meter calibration coefficient, in. H2O
Pb L= barometric pressure, in. Hg
AH avg 0.650 : average pressure differential oforifice, in H2O
Md 28.82 = molecular weight (DRY), lb/lb mol
1a u;'' 0.806 = average square root pressure differential oforifice, (in. H2O)rD
Yqa -1.4 = percent
gltfurcp
TECI.t\ICAL GROUPLocation: Rio Tinto Kennecott - Magna, UT
Source: Acid Plant TailGas - SME0llb
Project No.: AST-2021-234
Run No. /Method Run I / Method 6C
SO: - Outlet Concentration (Cso)' ppmvd
Cso,:
where,
30.9
C*o \(C"-gr1
: average analyzer value during test, ppmvd
= average ofpretest & posttest zero responses, ppmvd
= actual concentration of calibration gas, ppmvd: average ofpretest & posttest calibration responses, ppmvd
= SOz Concentration, ppmvd
(Cou.-Co)*(
Cot,
C^0.1
Cve
CM
Cso,
50.0
49,2
31.0
SOu - Outlet Concentration (Cso,*), ppmvw
Cso,*:
Cso,
BWS
Cso,*
C56ox(l-BWS)
where,
3l.0 : SOz - Outlet Concentration, ppmvd: moisture fraction, unitless: ppmvw
0.025
30.0
A/tfuTtrCIINICAL GROUP
SO2 Summary
Location:
Source:
Project No.:
Rio Tinto Kennecott -
Acid Plant Tail Gas - SME0I lb
AST-2024-2322
Run
No.Dete Time Reference Method
SOr Concentration
ppmvw
CEMS
SOr Concentration
DDMVW
Average
Difference
DnmvwStertEnd
I
2
3
4
5
6
7
8
9
6/18t24
6/t8124
6fi8/24
6il8124
6n8/24
6n8124
6il8t24
6n8t24
6fi8124
2:40
3:01
3:22
4:00
4:21
4:42
5:20
5:41
6:02
3:21
3:42
4:20
4:41
5:02
5:40
6:01
6:22
30.00
33.00
34.00
41.00
39.00
37.00
41.00
46.00
43.00
45.00
49.00
5 1.00
58.00
s6.00
53.00
s9.00
64.00
6l .00
5
6
7
7
7
6
8
8
8
Averagt 38.22 55.1 1 -15 889
Standard Deviation (Sd 1.054
Apolicable Source Standard (AS'250
Confidence Coefficient (CC'0.810
Reletive Accuracy (RA'7.08 o/o
Performance Required - Applicable Source Standarr RAs l0%
Performance Specifi cation Methoc PS2
Confidence Coefficient, CC
cc : ltoIu, sallVn I
where ,
to.nrt _4_= degrees of freedom value
n 9 : number ofruns selected for calculating the RA
Sd---ll'54 = standard deviation of differenceCC-1310 = confidence coeflicient
Relative Accuracy, RA
I d l+ lcclRA = ;3i;;p x1oo
where,
d -16.89 = average difference of Reference Method and CEMS
CC O.8 l0 = confidence coefficient
AS 250.000 = applicable source standard, ppmvw
RA ---7I8 -= relative accuracy, Vo
pulrhre Emissions Calculations
Locstion fuo Tinto Kennccott - Magn4 UT
TECHNICAL GROUP Sourcc Acid Plmt T8il Ga - SMEOI lb
Projtrl No. AST -2024-2322
Rtrn t Runl Run2 Run3 Run4 Ruo5 Ruo6 RunT Run8 Rua9 Avcrese
)at€
itaa Timc
itoo Timc
6t18t24 6il4t24 6t18n4
12.40 13:01 11:22
- 13:21 13:42
6n8t24 6118124 6lt8/24
14:00 14:21 14:42
l4:2O 14:41 15:02
6lt8D4 6il8124 6lt8/24
15:20 15:41 16:O2
15:40 15:01 16:22
InDnt Drtt - Outlet
vtoisture Fmction- dimcmionless BWS 0.025 0.025 0.025 0.02t 0.021 0.021 0.018 0.018 0.0t8 0.021
Cdculated Datr - Outlct
iG Concentration, ppmvd
iO, Concentration- DDmw
cs
csI-
31.00 34.00 35.00
30.00 33.00 34.00
42.00 40.00 38.00 42.oo
4r.00 39.00 37.00 41.00
41.00 44.00 39.22
46.00 43.00 38.22
att6tre| [ r.] lt t.. 1,r1. I ()n()lr []
Loetlon Rlo Tinto KcnGott - M.fnr' UT
Method I Data
Sourcc Acid Plut Trll G.r - SMEolrb
Projlct No. ASf'2014-2322
Drtc 06/lt/24
ISr..! P.nm.a.r
II
'.arr ,{.&t 6 .e
1_,:t:'
t
CIRCULAR DUCT
LOCATION OF TRAVERSE POIN'TS
N!ilber oJ frNcfr. poh& oD a diaaEur
I
2
3
4
6
8
9
l0
ll
t2
3 ,a56769t011t2
t4.6
85.4
6.1
25.0
75.0,1'
4.4
t4.6
29.6
70.4
85.4,:u
32
10.5
19.4
32.3
67.7
t0.6
E9.-l,1'
-
- 26_ 8.2
- 14.6
- 22.6
-- 65.8
-- 77.4
-- 85.4
-- 918
-_-_nr_-o
2.1
6.1
I t.t
11.1
25.0
35.6
64.4
75.0
t2.3
88.2
93.3
91.9
tPcrceill o/stack d@frctetlroh insida u'all lo truvtsc pihl
Duct Orlcnt dotr: Horizontal
Dr"t Doigr, ---tiiti-
Dktrncc firm Far Wdl to OuBldG ofPorl: 68.00 ln
Itipplc bngtt: ----Tft- ln
D.pth ofDuct: 60.00 ln
cro!3 Scction.l 4rc. or or"t, ---lif,J- 1'
No. ofTst Port!: 2
olrtuc. ,tr ---l ojt- fi
Dtltmce A Duct Dim.t ., ----li-(murt b. > os)
Dtutucc B: 13 0 fi
Dlrarnc. B lruct ltlm.t.., ----If,-(mu.t b. > !)
MlnimuD Numbcr ofTr.vcEc Polnt!: I 6
Acod Nubcr of Tw.* Poios, ----]Z-
Mouer (Inltld Md Detc): AJE 6/1824
R.vldcr (lnlti.l sd Drtc)! AJE 6/18i24
Ihlu
Travcnc
Polnt
o/. ot
Dlmctcr
Dlrtmca from
out!ldc ofwdl
I
3
I
5
6
1
6
9
l0
ll
t2
3.2
r0.5
19.4
32.3
67.7
E0.6
89.5
96.t
1.92
6.30
I 1.64
t9.3E
40.62
48.36
53.70,T'
9 tslt6
t4 5/t6
l9 5/8
27 3/E
4E 5/E
56 3/8
6l I l/t6
66 t/t6
Stack Diagrm
A= 10ft
B= 13fl
Dcpth ofDuct = 60 in.
Cross Sectional Ar@ Drynrtrcam
Olsturbance
aooaaoao
uprtream
Dliturbenc.
AllErlpe Method 2Data
Location Rio Tinto Kennecott - Maeno. UT
Source Acid Plant Teil Gas - SME0Ilb
Project No. AST -2024-2322
Run No.
Date
Status
Stert Time
Stop Time
I
6lt8/24
VALID
l5:51
l5:56
,
6lt8l24
VALID
l5:57
l5:58
3
6n8124
VALID
l5:59
l6:00
02 Concentration, 7o
CO2 Concentration, 9/o
Molecular Weisht. Ib/lb-mole (dry)
(o2)
(c02)
(Md)
19.4
0.2
28.82
19.5
0.2
28.8 r
19.5
0.2
28.81
AI
II
rI T
ill.llr
Con!ola
Loc.tion
Source
Project No.
Prremet.r(!)
IJnirs / M.thod
Tinro Kdne.ofr -
Arid
Method 4 Data
lun No.
)rtc
itrtu!
itrn Timc
ind Tim.
lun Timc, min (0)
I
6/tEt24
VALID
l2:4n
I 3:40
60
2
dltn4
VALID
l4:00
t5 00
60
M5- 14
J
6il8t24
VALID
l5:20
l6:20
60
M5- t4
ilcter Corr.ction Frctor (Y)
)rificc Cdibretion Vrluc (AH 6)
tler Vecuum, in. Ilg
I 001
I 681
2
0 001
I 001
I 6Er
1.003
l.6El
fei.r Volum€, ft3
0
5
l0
l5
20
25
30
35
40
45
50
55
60
293.420
295.925
29t.430
300.940
30i.445
30J.950
30t.455
3 10.955
3 13.465
3 t5 970
3 tE 475
320 9E0
32i 4t3
t0 053
323.76t
326.165
32t.770
33 r.275
133 7t0
136.2t5
338 790
341 300
343.805
346.3 l0
34t u5
3Jl 320
3J3.t26
30 065
354.027
356.630
359.225
36t.E20
364 4lJ
367 010
169 600
112 t95
314 t90
377.3t5
379.9E0
3t2.575
3E5.167
3 t. 140
Tampcrrtura,
0
5
l0
l5
20
2li
30
J5
40
45
50
55
60
Av.rrtc T.mparrtura, oF (Tm)
Av.rrt T.mpcrrtur., oR (Tm)
Minimum Tcmptrrturc, "F
Mctar
't7
77
77
7t
79
79
79
t0
t0
8l
82
82.
t2
19
539
11
Probc Filt.r Vrc Imp. Erit
64
60
57
52
48
41
46
46
47
4E
49
.t9
5l
Mct.r
n0
8l
8l
8t
t2
t2
8l
83
84
8i
85
86
ti6
It3
5{3
80
86
ProbG Filt.r Vrcuum
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
7
Imp. Erit
6t
57
53
50
4t
47
4t
48
49
-51
52
5t
41
6t
Matar
t5
t5
t7
t7tttt
t8
tg
89
90
9t
9t
92
E8
548
t5
92
Probc Filt.r Vlcuum
2
2
2
2
7
2
2
7
2
2
2
2
2
2
7
)
Imp. Erit
62
59
55
53
52
_\2
52
5.1
54
5_t
_5j
_56
56
-55
52
(\)
Brromctric Prcllurc, in. H8 (Pb)
Illctcr Orificc Prcrsurc, in. WC (AH)
Mct.r Prcilurc, in. H8 (Pn)
,vi..,
25.t2
0 6-50
25.77
25.417
25 7t
0 650
25.16
25.70
0 6J0
25.75
Andy3is Typc
Impintcr 1, PrclPost Tcit, g
Impinger 2, Pr.JPost T6t, 8
lmpinBcr 3, Pr.JPost T.st, 8
lmpingcr,l, Pr./Post T.st, g
Volumc W.tcr Collcct.d, mL (Vlc)
Stendrrd Wrtcr Volumc, fti (Vwttd)
Moilturc Frcction M.sur.d (BWS)
CG Moleculrr W.ight, lb^Umol. (dry) (Md)
DCM Crlibrrtion Chcck Vdrc {Yod
Cmvimtric Gravimcuc
H20
H20
ErPE
Silie
774 6
15t.2
654.9
716 6
752 1
656 5
2.0
l5
l6
H20
H20
Enrpt)
7 t6.6
752 1
656.5
778. I
't53.7
657.Eqt! a
t.5
l0
l3
H20
H20
Enrpt\
77t. I
7-s3. ?
6-17.8
179.3
7-r{.9
657.3
t.
l.
{t
t3.9
0 656
0 025
2E.82
-t {
I 1.4
0.J38
0.021
2E.E I
-l t
I 0.3
0.4E6
0.01E
2E,tI
pultErre
TE(]HNI()AL CNOL' P
Runl-RMData
Location:
Source:
Project No.:
Rio Tinto Kennecott - Magna, UT
Acid Plant Tail Gas - SME0I lb
AST-2024-2322
Date: 6/18124
Time
Unit
Status
SOr - Outlel
ppmvd
Valid
Uncorrected Run Average (Cou.)
Cal Gas Concentration (Cr"ra)
Pretest System Zero Response
Posttest System Zero Response
Average Zero Response (Co)
Pretest System Cal Response
Posttest System Cal Response
Average Cal Response (Cna)
30.95
s0.00
0.06
0.07
0.07
49.s6
48.87
49.22
31.42Corrected Run A
l2:40
l2:41
12:42
12:43
l2:44
l2:45
l2:46
l2:47
l2:48
l2:49
l2:50
l2:51
l2:52
l2:53
12:54
12:55
12:56
12:57
l2:58
12:59
l3:00
24.74
25.84
26.45
27.30
28.27
28.80
29.44
30.21
30.90
31.32
3 1.80
32.38
32.83
33.17
33.48
33.46
33.71
33.85
34.00
34.1 0
33.83
Alt6rtreTECHNICAT CNOLI P
Run2-RMData
Location:
Source:
Project No.:
Rio Tinto Kennecott - Magna, UT
Acid Plant Tail Gas - SME011b
AST-2024-2322
Date: 6/18124
Time
Unit
Status
SOz - Outlet
ppmvd
Valid
Uncorrected Run Average (Cour)33.87
50.00
0.06
0.07
0.07
49.56
48.87
49.22
34.39
l3:01
13:02
I 3:03
l3:04
l3:05
l3:06
13:07
l3:08
13:09
13: l0
l3:ll
l3:12
l3:13
13:14
13: l5
l3: l6
l3:17
l3: l8
l3:19
13:20
l3:21
34.09
34.11
34.02
33.88
33.79
33.61
33.76
33.88
33.75
33.76
33.90
3). tz
33.90
34.09
33.88
33.88
33.87
33.83
33.92
33.83
33.86
Cal Gas Concentration (CrmJ
Pretest System Zero Response
Posttest System Zero Response
Average Zero Response (Co)
Pretest System Cal Response
Posttest System Cal Response
Average Cal Response (Cu)
pllt6rtrcp
TECHNICAL CNOt-'P
Run3-RMData
Location:
Source:
Project No.:
Rio Tinto Kennecott - Magna, UT
Acid Plant TailGas - SME0I lb
AST-2024-2322
Date: 6/18124
Time
Unit
Status
SOz - Outlet
ppmvd
Valid
Uncorrected Run Average (Cou.)
Cal Gas Concentration (CrrrJ
Pretest System Zero Response
Posttest System Zero Response
Average Zero Response (Co)
Pretest System Cal Response
Posttest System Cal Response
Average Cal Response (Cm)
34.82
50.00
0.06
0.07
0.07
49.s6
48.87
49.22
35.36Corrected Run A
13:22
13:23
l3:24
l3:25
l3:26
l3:27
l3:28
13:29
I 3:30
l3:31
l3:32
l3:33
l3:34
l3:35
l3:36
l3:37
l3:38
l3:39
l3:40
13:41
l3:42
33.83
33.67
33.80
33.10
33.89
34.05
34.03
34.16
34.04
34.09
34.12
34.30
34.s4
34.9s
35.27
35.51
35.86
36.25
36.57
37.05
37.53
pult6rre
TECHNICAL l]NOLJ P
Run4-RMData
Location:
Source:
Project No.: AST-2024-2322
Rio Tinto Kennecott - Mama, UT
Acid Plant Tail Gas - SME01 lb
Date: 6/18124
Time
Unit
Status
Uncorrected Run Average (Cou.)
Cal Gas Concentration (CrtrJ
Pretest System Zrro Response
Posttest System Zero Response
Average Zero Response (Co)
Pretest System Cal Response
Posttest System Cal Response
Average Cal Response (Cna)
Corrected Run A Cor
SOz - Outlet
ppmvd
Valid
41.08
50.00
0.07
0.05
0.06
48.87
48.78
48.83
42.06
l4:00
l4:01
l4:02
l4:03
l4:04
l4:05
l4:06
14:07
l4:08
14:09
l4:10
l4:l I
l4:12
l4:13
l4:14
I4:15
l4:16
l4:17
l4:18
l4:19
l4..20
39.64
39.66
39.81
40.0s
40.30
40.45
40.78
41.16
41.17
41.18
41.48
4t.69
41.70
41.71
41.83
42.01
41.76
41.86
41.69
41.59
41.10
pllt6rre
r EC tr N rcA L c n ot'Jo"u,,on:
RioTintoKennecott-Ma'rra,UT
Run5-RMData
Source: Acid Plant Tail Gas - SME0I lb
Project No.: AST-2024-2322
Datez 6ll8l24
Time
Unit
Status
Uncorrected Run Average (Cou,)
Cal Gas Concentration (CuJ
Pretest System Zero Response
Posttest System Zero Response
Average Zero Response (Co)
Pretest System Cal Response
Posttest System Cal Response
Average Cal Response (Cu)
Corrected Run Average (Corr
SOz - Outlet
ppmvd
Valid
39.06
50.00
0.07
0.05
0.06
48.87
48.78
48.83
39.98
l4:21
l4:22
l4:23
l4:24
l4:25
l4:26
l4:27
l4:28
l4:29
l4:30
l4:31
l4:32
l4:33
l4:34
l435
l4:36
l4:37
l4:38
l4:39
l4:40
l4:41
40.90
40.89
40.10
39.82
39.78
39.62
39.1 0
38.76
38.54
38.67
38.61
38.64
38.72
38.79
38.90
38.88
38.70
38.69
38.31
38.04
37.74
putt6rrpe
I ECHN icAt cBo.'Jo.r,,on,
Source:
Project No.:
Run6-RMData
Rio Tinto Kennecott - Magna, UT
Acid Plant Tail Gas - SME0I lb
AST-2024-2322
Date: 6l18/24
Time
Unit
Status
Uncorrected Run Average (Cour)
Cal Gas Concentration (Cr*l,r)
Pretest System Zero Response
Posttest System Zero Response
Average Zero Response (Co)
Pretest System Cal Response
Posttest System Cal Response
Average Cal Response (Cnr)
Corrected Run A
SOz - Outlet
ppmvd
Valid
36.65
50.00
0.07
0.05
0.06
48.87
48.78
48.83
37.52
l4:42
l4:43
l4:44
l4:45
l4:46
l4:47
14:48
14:49
l4:50
l4:51
l4:52
l4:53
l4:54
l4:55
l4:56
l4:57
l4:58
l4:59
15:00
l5:01
l5:02
37.48
37.24
37.07
36.99
36.87
36.76
36.89
36.69
36.82
36.90
36.69
36.s4
36.64
36.58
36.65
36.63
36.55
36.26
3s.94
35.80
35.72
pult6rre
rEC H N lcAL c not'Jo"r,,rn:
RioTintoKennecott-Magna,UT
RunT-RMData
Source: Acid Plant Tail Gas - SMEOI lb
Project No.: AST-2024-2322
Date: 6ll8l24
Time
Unit
Status
SOz - Outlet
ppmvd
Valid
Uncorrected Run Average (Cru.)
Cal Gas Concentration (Cr*r,l)
Pretest System Zero Response
Posttest System Zero Response
Average Zero Response (Co)
Pretest System Cal Response
Posttest System Cal Response
Average Cal Response (CM)
41.32
50.00
0.05
0.06
0.06
48.78
49.07
48.93
42.22Corrected Run A
l5:20
l5:21
l5:22
l5:23
l5:24
l5:25
l5:26
l5:27
l5:28
15:29
I 5:30
15:3 I
l5:32
15:33
l5:34
l5:35
15:36
l5:37
l5:38
I 5:39
l5:40
37.97
38,26
38.56
38.82
39.05
39.51
39.98
40.31
40.78
41.07
4t.59
41.84
42.08
42.52
42.83
43.18
43.32
43.42
44.18
44.26
44.18
plltErre
TECHNICAL CNOL' P
Run8-RMData
Location:
Source:
Project No.:
Rio Tinto Kennecott - Mama, UT
Acid Plant Tail Gas - SME011b
AST-2024-2322
Date: 6/18124
Time
Unit
Status
SOu - Outlet
ppmvd
Valid
Uncorrected Run Average (Cou.)
Cal Gas Concentration (CM,1)
Pretest System Zero Response
Posttest System Zero Response
Average Zero Response (Co)
Pretest System Cal Response
Posttest System Cal Response
Average Cal Response (Crrr)
45.68
50.00
0.05
0.06
0.06
48.78
49.07
48.93
46.68Corrected Run Average (Corr
15:41
l5:42
l5:43
l5:44
l5:45
l5:46
l5:47
l5:48
15:49
l5:50
l5:5 I
l5:52
I 5:53
l5:54
I 5:55
I 5:56
l5:57
I 5:58
I 5:59
l6:00
l6:01
44.40
44.70
45.00
4s.35
45.59
45.83
46.23
46.58
47.02
47.04
47.17
47.06
46.88
46.5r
46.07
45.53
45.20
44.75
44.61
44.08
43.73
pllt6rre
r E c H N rc A L c n o t'Jo"rrron,
Source:
Project No.:
Run9-RMData
Rio Tinto Kennecott - Magra, UT
Acid Plant Tail Gas - SMEOI lb
AST-2024-2322
Date: 6l18/24
Time
Unit
Status
SOr - Outlet
ppmvd
Valid
Uncorrected Run Average (Cou.)
Cal Gas Concentration (CuJ
Pretest System Zero Response
Posttest System Zero Response
Average Zero Response (Co)
Pretest System Cal Response
Posttest System Cal Response
Average Cal Response (Crrr)
42.78
50.00
0.0s
0.06
0.06
48.78
49.07
48.93
43.71Corrected Run A
l6:02
l6:03
l6:04
16:05
16:06
l6:07
16:08
l6:09
l6:10
l6:l I
l6:12
l6: l3
l6:14
l6: l5
l6:16
l6:17
l6; l8
l6:19
l6:20
l6:21
l6:22
43.56
43.28
43.17
43.07
42.83
42.52
42.47
42.31
42.37
42.17
42.57
42.36
42.08
42.36
42.21
42.69
42.87
43.1 1
43.33
43.34
43.63
AlAlEeIi
Method 3/3A Data
Rio Tinto Kennecott - Magna, UTLocation
Source
Project No.
Acid Plant Tail Gas - SMEOtlb
AST-2024-2322
02 Data C02 Data
Date/Time 6tr8t24 l5:40 Date/Time 6fi8t24 l5:40
Make/lVtodel/SN Servomex 1400 14204 Servomex 1440 l4l5c-2
Parameter Cylinder ID Cylinder
Concentration. o/"
Analyzer
Concentration. 7"Cylinder ID Cylinder
Conaentrqlion o/^
Analyzer
Cnncenfrqfinn o/^
Zero Gas Nitrogen 0.00 0.08 Nitrogen 0.00 0.06
High Range Gas E80069884 23.99 23.98 EB0069884 23.90 24.02
Mid Range Gas RR0425 I r0.99 r r.00 RR0425 r I t.l0 I1.03
Concentration Span, 7o 24.0 23.9
Accuracy 0.5 0.5
Run No.Run I Run 2 Run 3
Peremeter Or!:o Coaoh Or.Yo CO2Y,OtV" CO2YI
Date/Time 6n8t2024 l5:56 6il8t2024 I 5:58 6/t8t2024 l6:00
Analysis #I
Analysis #2
Analysis #3
Average
l9_42 o_24 19.53 0.21 t 9.54 0.20
t9.43 0.25 19.52 0.22 19.49 0.23
19.45 0.23 r9.50 0.20 19.47 0.21
t9.4 0.2 19.5 0.2 19.5 0.2
7'he remaining consistuenl is assuned to be nitrugen.
.*'t.ta r',7'r.
-s-\-!j2-r.-it**7,z=:.:2.,' '..s'PJII@hdBla
Accreditation #62754
Red Ball Technical Gas Service
555 Craig Kennedy Way
Shreveport, LA 71107
800-551 -81 50
PGVP Vendor lD # G'12024
EPA PROTOCOL GAS GERTIFICATE OF ANALYSIS
Cylinder Number:
Product lD Number:
Cylinder Pressure:
coA #
Customer PO. NO.:
Customer:
E80069884
127907
1900 PS|G
E80069884.20240320-0
Certification Date:
Expiration Date:
MFG Facility:
Lot Number:
Tracking Number:
Previous Certification Dates:
0410312024
0410112032
- Shreveport - LA
E 6UUOVdU4. ZU24UJZU
x44212711
has per 2 EPA Traceability Protocol, Document EPA-600/R-12/531 ,
G2.
Concentratlon Uncertalnty Analytical Prlnclple Assayed On
fij%
10.06 %
Analytical Measurement Data Available Online.
Reference Standard(s)
cc520205.202301 08
EB0022009.20201022
20.01 0/o
24 76 0/6
1162980025 03t18t2024
017146467 04t02t2024
SMART.CERT
This is to certify the gases referenced have been calibrated/tested, and verified to meet the defined speciflcations. This
calibration/test was performed using Gases or Scales that are traceable through National lnstitute of Standards and
Technology (NIST) to the lnternational System of Units (Sl). The basis of compliance stated is a comparison of the
measurement parameters to the specified or required calibration/testing process. The expanded uncertainties use a coverage
factor of k=2 to approximate the 95% confldence level of the measurement, unless otheMise noted. This calibration certiflcate
applies only to the item described and shall not be reproduced other than in full, without written approval from Red Ball
Technical Gas Services. lf not included, the uncertainty of calibrations are available upon request and were taken into account
when determining pass or fail.
Brittany Johnson
Analytical Chemist
Assay Laboratory: Red Ball TGS
Version 02-J, Revised on 201 8'09-'1 7
Red Ball Technical Gas Service
555 Craig Kennedy Way
Shreveport, LA 71107
800-551 -81 50
PGVP Vendor lD # G12023
EPA PROTOCOL GAS CERTIFICATE OF ANALYSIS
Cylinder Number:
Product lD Number:
Cylinder Pressure:
coA #
Customer PO. NO.:
Customer:
RR04251
125371
1900 PS|G
RR04251 .2023083 1 -0
Certlfication Date:
Expiration Oate:
MFG Facility:
Lot Number:
Tracking Number:
Previous Certification Dates:
)9t21t2023
)911912031
ft(u4z5 1 .2U23UU31
'1075497 18
This calibration standard has been per the May 2012
G1,
Certified C
Concentratlon Uncertalnty
rC-11 "/"
10.03 %
Analytical Prlnclplo
FTIR
MPA
Assayod On
ogn1l202g
09t18t2023
Carbon Dioxide
Oxygen
11.1To
10.99 %
Nitrogen Balance
Reference Standard(s)
QQ737012
EBOO22021
cc737012.20230228
EBOO22021.20180323
t't62980025 09t1812023
017146467 09t21D023
SMART-CERT
This is to certity the gases referenced have been calibrated/tested, and verified to meet the defined specifications. This
calibration/test was performed using Gases or Scales that are traceable through National lnstitute of Standards and
Technology (NIST) to the lnternational System of Units (Sl). The basis of compliance stated is a comparison of the
measurement parameters to the specified or required calibration/testing process. The expanded uncertainties use a coverage
factor of k=2 to approximate the 95% confldence level of the measurement, unless otherwise noted. This calibration certiflcate
applies only to the item described and shall not be reproduced other than in full, without written approval from Red Ball
Technical Gas Services. lf not included, the uncertainty of calibrations are available upon request and were taken into account
when determining pass or fail.
fu* /Lrh
Jasmine Godfrey
Analytical chemist
Assay Laboratory: Red Ball TGS
Version 02-J, Revised on 2018-09-17
pllt6r'ire QA Data
Location RioTintoK.@
Source
Project No. AST-202 4-2322
Parameter SOz - Outlet
Make
Model
S/N
Oneratins Ranse
Ametek
9900
zD-9900-s1302-l
100
Cylinder ID
7*ro
Mid
Hish
NA
EB0087789
EB0087789
Cylinder Certifed Values
Zero
Mid
Hish
NA
497
497
Cylinder Expiration Date
Zero
Mid
Hish
NA
8/23/31
8/23/31
Tvoe of Samnle Line Heated Sample Line
AT FIAlEE!Response Times
IL(;lll\l(-r i\l (.-i t]()1. l['
Location: No Tinto Kennecott - Maena. UT
Source: Acid Plant Tail Gas - SME0I lb
Project No.: AST-2042322
Zero
Low
Mid
Aver
A/l6rlEE)| :, _" I Calibration Data
Location: Rio Tinto Kennecott - Magna, UT
Source: Acid Plant Tail Gas - SME0I lb
Project No.: L{!a21422
Date: 6ll8l24
Parameter SOu - Outlet
Expected Average Concentration 50.00
Span Between
Low
High
Desired Snan
50.00
2s0.00
90.00
Low Range Gas
Low
Hieh
NA
NA
Mid Range Gas
Low
Hish
36.00
54.00
High Range Gas
Low
Hish
NA
NA
Actual Concentration (7o or ppm)
Zero
Low
Mid
Hiph
0.00
NA
50.00
90.00
Upscale Calibration Gas (CnrJ Mid
Instrument Response (7o or ppm)
Zero
Low
Mid
Hiph
0.26
NA
49.28
89.57
Performance (7o of Span or Cal. Gas Conc.)
Zero
Low
Mid
Hish
0.29
NA
0.80
0.48
Status
Zero
Low
Mid
Hish
PASS
NA
PASS
PASS
pulr6rrpe
l [ ( ] I I tJ I (
Bias/Drift Determinations
Location: Rio Tinto Kennecott - Magna UT
Source: Acid Plant Tail Gas - SME0I I b
Project No.: AST-2024-2322
Parameter SOu - Outlet
Run I Date 6118124
Span Value
Initial Instrument Zero Cal Response
Initial Instrument Upscale Cal Response
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
90.00
0.26
49.28
0.06
0.07
49.56
48.87
Bias (%)
Pretest Zero
Posttest Zero
Pretest Span
Posttest Span
-0.22
-0.2 r
0.31
-0.46
Drift (%)
Zero
Mid
0.01
-0.7'7
Run 2 Date 6118124
Span Value
Instrument Zero Cal Response
Instrument Upscale Cal Response
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
90.00
0.26
49.28
0.06
0.07
49.56
48.87
Bias (%)
Pretest Zero
Posttest Zero
Pretest Span
Posttest Span
-0.22
-0.2 r
0.3 r
-0.46
Drift (%)
Zero
Mid
0.01
-0.77
Run 3 Date 6118124
Span Value
Instrument Zero Cal Response
Instrument Upscale Cal Response
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
90.00
0.26
49.28
0.06
0.07
49.56
48.87
Bias (%)
Pretest Zero
Posttest Zero
Pretest Span
Posttest Span
-0.22
-0.21
0.3 r
-0.46
Drift (%)
Zero
Mid
0.0 r
-0.77
FtaAI Bias/Drift Determinations
l[ (:ltt,] lr
Location: Rio Tinto Kennecott - Magna" UT
Source: Acid Plant Tail Gas - SME0I lb
Project No.: AST-2024-2322
Peremcter SOr - Outlet
Run 4 Date 6ll8n4
Span Value
Instrument Zero Cal Response
Instrument Upscale Cal Response
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest Svstem Upscale Response
90.00
0.26
49.28
0.07
0.05
48.87
48.78
Bias (%)
Pretest Zero
Posttest Zero
Pretest Span
Posttest Soan
0.21
0.23
0.46
0.56
Drift(%)
Zero
Mid
-0.02
-0. l0
Run 5 Date 6ll8n4
Span Value
Instrument Zero Cal Response
Instrument Upscale Cal Response
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
90.00
0.26
49.28
0.07
0.05
48.87
48.78
Bias (%)
Pretest Zero
Posttest Zero
Pretest Span
Posttest Span
0.2t
0.23
0.46
0.56
Drift(%)
Zero
Mid
-0.02
-0.10
Run 6 Date 6ll8D4
Span Value
Instrument Zero Cal Response
Instrument Upscale Cal Response
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
90.00
0.26
49.28
0.07
0.05
48.87
48.78
Bias (%)
Pretest Zero
Posttest Zero
Pretest Span
Posttest Span
0.21
0.23
0.46
0.56
Drift (%)
Zero
Mid
-0.02
-0. l0
pllIAIEE)Bias/Drift Determinations
Location: Rio Tinto Kennecott - Mama UT
Source: Acid Plant Tail Gas - SME0I lb
Project No.: AST-2024-2322
Parameter SO: - Outlet
Run 7 Date 6l$n4
Span Value
Instrument Zero Cal Response
Instrument Upscale Cal Response
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
90.00
0.26
49.28
0.05
0.06
48.78
49.07
Bias (%)
Pretest Zero
Posttest Zero
Pretest Span
Posttest Span
0.23
0.22
0.56
0.23
Drift(%)
Zero
Mid
0.01
0.32
Run 8 Date 6118124
Span Value
Instrument Zero Cal Response
Instrument Upscale Cal Response
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
90.00
0.26
49.28
0.05
0.06
48.78
49.07
Bias (%)
Pretest Zero
Posttest Zero
Pretest Span
Posttest Soan
0.23
0.22
0.56
0.23
Drift(%)
Zero
Mid
0.01
0.32
Run 9 Date 6ll8n4
Span Value
Instrument Zero Cal Response
Instrument Upscale Cal Response
Pretest System Zero Response
Posttest System Zero Response
Pretest System Upscale Response
Posttest System Upscale Response
90.00
0.26
49.28
0.05
0.06
48.78
49.07
Bias (%)
Pretest Zero
Posttest Zero
Pretest Span
Posttest Span
0.23
0.22
0.56
0.23
Drift (7d
Zero
Mid
0.01
0.32
&*PJll-r.
Accreditation #62754
Red Ball Technical Gas Service
555 Craig Kennedy Way
Shroveport, LA 71107
800-551 -81 50
PGVP Vendor lD # G12023
EPA PROTOGOL GAS GERTIFIGATE OF ANALYSIS
Cylinder Number:
Product lD Number:
Cylinder Pressure:
coA #
Customer PO. NO.:
Customer:
:80087789
23497
'1900 PS|G
E80087789.202308 14-0
Certification Oate:
Expiration Date:
MFG Facility:
Lot Number:
Tracking Number:
Previous Certification Dates:
)8t25t2023
)Et2312031
- snreveoon - LA
E80087789.202308 1 4
J9528/45ti
This calibration standard has been certified per the May 2012 Protocol, Document EPA-600/R-12/531,
G1
SMART-CERT
This is to certify the gases referenced have been calibrated/tested, and verified to meet the defined speciflcations. This
calibration/test was performed using Gases or Scales that are traceable through National lnstitute of Standards and
Technology (NIST) to the lnternational System of Units (Sl). The basis of compliance stated is a comparison of the
measurement parameters to the specified or required calibration/testing process. The expanded uncertainties use a coverage
factor of k=2 to approximate the 95% confidence level of the measurement, unless otheMise noted. This calibration certificate
applies only to the item described and shall not be reproduced other than in full, without written approval from Red Ball
Technical Gas Services. lf not included, the uncertainty of calibrations are available upon request and were taken into account
when determining pass or fail.
4n-Zrt &ru
Ti,nothy Da.,'s
Analytical Chemist
Assay Laboratory: Red Ball TGS
Version 02-J. Revised on 2018-09-17
Certifi ed Concentration(s)
ConcentraUon Uncertalnty Analytlcal Prlnclple Assayed On
Dioxide 497 PPM T3 PPM NDIR 08n8n023,08125t2023
Balance
Analytical Measurement Data Available online.
vtA-510 so2 G000G2A 08t17t2023
A/IATEE!
UT
E0l tb
Drte 6ll8l24
Method (lrit€ria EPA
rrem€t€r 02
Makr
Ntodel
S/N
Spar
Seruomex
1400
14204
23 99
Cvlinde r Number [D'I*ro
Mid
Hish
NA
RR0425 I
E80069884
Cvlindcr Certilied values
Z,erc
Mid
Hioh
U,U
r0.99
23.99
lnstmm€nt RBDonse (-/o or ooml
Lero
Mid
IIish
t0.92
23 96
Celibration Gas ti€lection ('jlo ofsDitr)
Mid
Hioh
45.E
100 0
elrDrtnon l,rror rerormtnce -/o OI SDAnI
Zero
Mid
llioh
0.7
-0.3
-0. I
Lin€arity (7o of Rrnse)
-0.6
Analyzer Make:
Analyzer Model:
Analyzer SN:
Environics lD:
Conrponent/Balance Gas:
Cylinder Gas lD (Dilution):
Cylinder Gas Concentration (Dilution), 7o:
Cylinder Gas ID (Mid-Level):
Cylinder Gas Concentration (Mid-Level), 7o:
t4204
23.99
RR0425 I
l0 99
Anelyzer
Concentration
lo/"\
lnjection I
f,rror
( +zy"r
Injection 2
Error
( +7"/.r
Inj€ction 3
Errcr
l+2"/"1
t9.22 O. LYo O.OYo -O. lYo
I 1.99 0. lo/o -0.tvo 0.o"4
4.E I 0 10/"0 0o./.-02v"
2.43 o.5a O.5Yo -l.lYo
Mid-Level SuDDlv Gas Calibration Dircct to
Crlibration
Gas
Concentration
t o/^\
lnjection I
Analyzer
Concent!'ation
lo/^\
Injection 2
Analyzer
Concentration
to/^\
rnJectlon J
Anrlyzer
Conc€ntretion
I o/^\
Avcrage
Analyzer
Coocentration
lo/"\
Difference
I 6/^\
Averrge
Error
( +2%l
10.99 t.02 102 l0 98 I l.0l 0.02 0.20/o
A/tfutre
SOURCE TESTING
Mass Flow Controller Calibration
Note: Themassflowcontroller'scalibrationvaluesareusedbythedilutionsystem'soperatingsoftwaretoimproveaccuracy. Thesecalibrationsarenot
necessarilyindicativeofthesystemsoverallperformance. PerformanceisverifiedbyconductingaMethod205priortoeachfielduse.
Calibration Performed By Ryan Lyons
Dilution System Make:
Dilution System Model:
Dilution System S/N:
Catibration EquipmentMake: lAlicatScientific
Calibration Equipment Model: lM-10SLPD/5MM-D/5M, M-15LPM-D/51
CalibrationEquipmentS/N: 1L97206
FlowCell S/N: 1197206
Flow Cell S/N: |L972OB
Calibration Gas:
Barometric Pressure, mmHg: 125.5
Ambient Temperature, 'F: 167
Mass Flow Controller lD
Size, ccm:
Make:
Model:
s/N:
#1
10,000
Environics
4040
455242077
#2
10,000
E nvironics
4040
4552420L2
#3
1,000
Environics
4040
4ss238006
Set Flow True Flow Difference
cc/min cc/min
Set Flow True Flow Difference
cc/min cc/min
Set Flow True Flow Difference
cc/min cc/mln
5%
to%
20%
30%
40%
s0%
60/o
70%
80%
90%
LOO%
500 502 0.4%
1,000 r,o77 t.7%
2,000 2,051 2.9%
3,000 3,083 23%
4,000 4,706 2.7%
5,000 5,L22 2.4%
6,000 6,748 2.5%
7,OOO 7,164 2.3%
8,000 8,t82 2.3%
9,000 9,198 2.2%
10.000 to,22]- 2.2%
500 so2 0.4%
1,000 7,ot2 1.2%
2,OOO 2,040 2.O%
3,000 3,059 2.0%
4,000 4,078 2.O%
5,000 5,095 L.9%
6,000 6,LL4 L.9%
7,000 7,t34 t.9%
8,000 8,ts2 r.9%
9,000 9,173 t.9%
10.000 10,195 2.0%
50 49 2.4%
100 99 r.5%
200 199 0.7%
300 299 0.2%
400 400 0.7%
500 502 0.s%
600 604 0.6%
700 706 0.9%
800 810 1.3%
900 916 t8%
1,000 1,024 2.4%
oate 4/27/23
AIibIEE)
TI
QA Data
t. l a li ( rrl ,
Location Rio Tinto Kennecott - Magnr, UT
Source Acid Plant Tail Gas - SME0llb
Project No.AST-2024-2322
Perameter(s) BWS
Field Balance Check
Drte 06/18t24
Balance lD:Scale 76
Certified Weight ID:SLC.I KG-I
Certified Weight (g):1000.0
Measured Weight (g):999.8
Weight Difference (g):0.2
Drte Barometric
Praccrrrp
Evidence of
demape?Reading Verified Celibration or
Danoir ranrriarl')Weather Stetion Location
6il8/24 Weather Station NA NA NA Salt Lake Ciry, UT
Date Meter Box ID Positive Pressure Leek Check
6il8124 M5-14 Pass
DGM Calibration-Orifi ces
Document I 620 004
Revisior 24.A
Effective Dat(1/31/24
lssuing Depaftment fech Services Paq(1of1
Equipment Detail - Dry Gas Meter
Console lD M5-14
Meter S/N. 8219521
Critical Orifice S/N: SH 40-73
Calibratlon Detail
lnitial Barometric Pressure, in. Hg (Pbr)
Final Barometric Pressure, in. Hg (PbF)
Averaqe Barometric Pressure, in. Hg (Pb)
25 60
25 60
25.60
Critifcal Orifice lD (Y)
K' Factor, ft'.R'/'/ in. WC min (K')
Vacuum Pressure, in. Hg (Vp)
tnitial DGM volume, ftr (vm)
Final DGM Volume, ft3 (Vmr)
Total DGM Volume, ftr (Vm)
SH-73
0.7864
12.0
551.000
576.3 58
25 358
SH.73 5H-63
0.6007
165
603.900
623 468
19.568
sH-63 SH.55
0.4524
17.5
659.200
673.919
14 719
SH-55
0.7864 0 601 0.452
120
577.300
602.720
25 420
16.5
623 900
643.491
19 591
17.5
674900
689.61 5
14.715
Ambient Temperature, 'F (Ta)
lnltial DGM Temperature, "F (Tm)
Final DGM Temperature, 'F (TmF)
Averaoe DGM Temoerature, 'F ( Tm)
68
68
69
69
72
72
73
73
73
73
74
14
74
74
75
75
75
75
76
76
76
76
76
76
Elapsed Time (O)
Meter Orifice Pressure, in. WC (AH)
Standard Meter volume, ft3 (Vmstd)
Standard Critical Orifice Volume, ft3 (Vco
Meter Correction Factor (Y)
Tolerance
Orifice Calibration Value (AH @)
Tolerance
3r,fice Cal Check
25.00
2.70
21.8483
21.9096
1.003
0 000
1.704
0 023
25.00
270
21.7371
21.8270
'1.004
0.001
1.704
0.023
25 00
1.60
16.6492
16.6571
1 000
0.003
1 725
0.044
25 00
160
16.6376
16.6415
1.000
0 003
1.725
0.044
25.00
0.85
12 4500
12.5214
1 006
0.003
1.612
0.068
25.00
085
12 4350
12.5097
1 006
0 003
1.614
0.067
031 0.55 055
vleter Correction Factor (Y)1.003
friffce Calibration Value (AH @)1.681
)ositfue Pressure Leak Check Yes
Equipment Detail - Thermocouple Sensor
Reference Calibrator Make.
Reference Calibrator Model,
Reference Calibrator S/N.
Calibration Detail
Practical lnstrument Electronics
Piecal 5208
887216
Reference Temp.Display Temp.Accuracy Absolute
Difference
oF oR r K I
0
68
100
460
528
560
0
66
98
460
526
558
0.0
0.4
0.4
0
2
2
223
248
273
683
708
733
223
248
273
683
708
733
0.0
00
0.0
0
0
0
300
400
500
600
700
800
900
1,000
1,100
1,200
760
860
960
1,060
1,160
1,260
1,360
1,460
1,560
1,660
300
398
497
599
701
800
900
1,000
1,101
1,201
760
858
957
1,059
1,161
1,260
1,360
1,460
1,561
1,661
0.0
0.2
0.3
01
-0.1
0.0
0.0
0.0
-0.1
-0.1
0
2
3
1
1
0
0
0
1
1
Personnel
Shamit Nakra
Calibration By
Calibration Date
Reviewed By
Xander Gray Krahn
5/16/2024
AnArEer I () III'r I() n L t'tt!,I"r:
RioTintoKennecott-Mama.UT
Source: Acid Plant Tail Gas - SME0I lb
Project No.: AST -2024-2322
Date: 6118/2024
Traverse Point Time Sor
(nom)
A-I
2
J
l0:30
l0:34
10:38
43.25
44.99
45.1 I
44.5Average
Criteria Met Single Point
Company: Rio Tinto Kennecott
Plant:City,/St: Magna, UT
Source: DUCT
CEMTEK KVB-EnarI€c NoIDAHS@
Average Values Report
cenerated: 6/LB /2024 73:37
Version 48.0
Period Start: 6/18/2024 L2:40
Period End: 6/18/2024 13:00
Validation Type: 1/1 min
Averaging Period: l- min
Type: Block Avg
Average
D SO2
AverageD_IAir Aw€rage Averago
D_SO2PwrR D_SOr_1Rr
Period Start: PPDI, dogE t PPnd-----d671{7ZdZ4 a2-40 3e L2L.1s 0.L2 4'1
05/t8/2024 12-.4t
06/18/2024 L2:42
05/18/2024 L2:43
06/L8/2024 L2:44
05/L8/2024 t2t45
05/18/2024 t2t46
06/L8/2024 L2:4'1
06/1,8/2024 12148
06/18 /2024 1"2| 49
06/18 /2024 1.2|50
06/18 /2024 72-.5L
06/78/2024 72:52
06/18/2024 \2:53
06/78/2024 12:54
06/t8/2024 t2:55
05/18/2024 L2:56
06/LB /2024 12z5'7
06/L8/2024 12258
06/L8/2024 L2:59
06/18/2024 13:00
40
41-
4t
42
43
44
45
45
46
4'7
4'1
4'7
48
48
48
48
48
48
48
48
0.L2
0.12
0.72
0.12
0.12
0.11
0.11
0.12
0.11
0.L2
0.L2
0.L2
0.L2
0.L2
0.L20.t2
0.L2
4'7
4'7
4'7
4'7
4'7
4'7
4'7
4'7
41
41
41
47
4'7
4'l
4'1
47
L2L.54
t2t.5'7
L2t.'t 6
122.L'7
122.39
122.',7L
123.03
1.23.29
r23.49
r23.66
123.88
L24 .08
L24.34
124.6L
L24.84
r25.05
1.25.29
r25.38
725 .45
125.59
0.12 47
41
35
0.72
o.72
Final. Average*
Maxinunr
Minimumr
45 L23.6L o.L2 {6
48 125.59
06/1.8/2024 06/18/2024 06/18/2024 06/t8/2024
13:00
L21.54
I / 2024
L2|4t
13:00 72:59
06/18/2024 06/L8/2024 06/L8/2024 06/18/2024
L2t49 13:00
o _L2 41
0.11 35
l-3:00
39
/ 2024
L2:40
* Does not include Inval-id Averaging Periods ("N/A")
CEMrEK KvB-En€rtec NotDNIS@
Average Values Report
Generated: 6/L8/2024 L3t33
Version 48.0
Company: Rio Tinto Kennecott
Plant:
City,/St: Magna, UT
Source: DUCT
Period Start: 6/18/2024 13207
Period End: 6/18/2024 t3:21
Valj-dation Type: 1/1 min
Averaging Period: L min
Type: Bl-ock Avg
Average
D_S02
Av€rag€ Average Averag€
D_Teq)D SO2FwrR D SO2 1Hr
Period Start: ppmr degF t PPnd
06/18/202a 73:Q2
06/18/2024 73|03
06/t8/2024 73204
06/18/2024 73205
06/tB /2024 1.3:06
06/L8/2024 t3:0'1
05/L8/2024 L3:.08
06/L8/2024 t3:09
06/L8/2024 t3:t0
05/18/2024 L3zLt
06/18/2024 L3.t2
06/78 /2024 1,3:73
06/18/2024 t3:74
05/18/2024 1.3|15
06/78/2o24 13t76
06/t8/2024 t3tt'7
06/18/2A24 13'tL8
06/L8/2024 13:L9
06/L8/2024 t3:20
05/t8/2024 13:27
48
48
48
48
48
49
49
49
49
49
49
49
49
49
49
49
50
49
49
49
125.90
1rR O?
126.03
L26.08
L26.L2
126.18
725.25
125.32
126.32
t26.35
t26.39
t26.42
726.4'7
126.50
126.52
t26.5'7
t26.50
L26.65
t26.'71
L25.8t
0.12 350.t2 350.t2 35
0.L2
0.L2
0.L2
0.L2
0.L2
0.L2
0.12
0.12
0.L2
0.t2
0 -t2
0 -12
0.1.2
0 -12
0.t2
a.L2
0.L2
35
35
atr
35
35
35
35
35
35
35
35
35
35
35
35
35
35
E'ina1 Average*
Maxiuum*
49 125.33 o.t2
o.L2
35
3550 L26.47
05/L8/2024 06/t8/2024 06/Lg/2024 06/L8/2024
13:18 13 t27 73:21,
o.12
L3:21
35Miniuum*48 L25.7706/78/2024 06/18/2024 06/t8/2024 06/78/2024
13:06 l3:01 13:21 L3z2l
i Does not include Invalid Averaging Periods ("N/A")
""n.... ^::
CEMTEK KVB-EnerIac NotDAHS@
Average Values Report
cenerated: 5/78/2024 73244
Version 48.0
Company: Rio Tinto Kennecott
Plant:
City,/St : Magna, UT
Source: DUCT
Period Start: 6/L8/2024 1,3:22
Period Endt 6/18/2024 L3t42
Validation Type: 1/1 min
Averaging Perj-od: L min
Type: Block Avg
Average
D SO2
Averag6
D_Temp
Average Average
D_SO2PWrR D_SO2_1Hr
Period Start: ppEw degf * PPnd
06/L8/2024 1,3t23 s0 t25.'7 9
t26.80
726.84
1.26.88
L26.92
0. 11
0. 11
0.L2
0. r.2
0.L2
35
2R
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
35
06/L8/2024 1,3:24
06/18/2024 73t25
06/L8/2024 73226
06/rB /2024 13:2'7
05/L8/2A24 t3228
06/78/202a ]-3229
06/18/202a 73:30
06/78/2024 t3:31
06/78/2024 L3|32
06/18/2024 L3t33
06/L8/2024 13234
06/tB/2024 t3?35
06/t8/2024 13:36
06/t8/2024 7323'7
05/t8/2024 t3:38
06/t8/2024 t3:39
o6/18/2024 L3:40
05/18/2024 t3:4t
05/L8/2024 13:42
49to
50
50
50
50
50
s0
51
51
51
52
52
53
53
s3
54
54
55
126.98 0.11L2'7.06 o.LL
L2'7.79
L2't.24
L2"t.26
72'7.32
1.2'7.02
1.26.46
L25.92
125.5r
125.29
1.25.L2
124.96
724 .8 4
o.12
0.11
0.11
0.11
0.t2
0.t2
0.L2
0.120.t2
0.t2
0.12
0.11
]-24-'74 0.11
Fina1 Awerage* 51
Maxinurn* 55
126.38 0.L2
L27 .32 a.L2
35
35
05/L8/2024 06/78/2024 05/78/2024 06/L8/2024
13t42
l(ininu:o.* 49
13:33 13: 40L24.74 0.11
1,32 42
35
05/18/2024 06/18/2024 06/L8/2024 05/78/2024
1,3:25 1a. Aa 14. ,a L3: 42
* Does not incl-ude Invalid Averaging Periods ("tl/a",
Page
CEIITEK l(VB-Enertec NetDAHSO
Average Values Report
cenerated: 5/18/2024 75zll
Version 48.0
Company: Rio Tinto Kennecott
PIant:
City/St: Magna, UT
Source: DUCT
Period Start: 6/18/2024 t4:00
Period Eod. 6/L8/2O24 L4t20Validation Type: 1/1 min
Averaging Period: I min
Type: Block Avg
Average
D_SO2
Average
D_fo-F
Averag€ Av€rage
D SO2PwrR D SO2 1Hr
Period Start: ppnw d€gtr t PPnd
06/L8/2024 74:0L
06/18/2024 14:02
06/78/2024 14:03
06/\8/2024 L4:04
06/18/2024 L4205
06/r8/2024 14:06
06/La /2024 1.4:0't
06/t8/2024 t4t08
06/t8/2024 t4:09
05/18/2024 t4:L0
06/18/2024 t4l.lt
06/L8 /2024 L4:1'2
06/18/2024 14:13
06/18/2024 L4t74
06/18/2024 14:15
06/t8/2Q24 14:t6
06/L8/2024 t4:L]
06/L8/2024 742L8
06/L8/2024 74t19
06/18/2024 ]-4:20
5'7
57
5'7
EA
58
58
58
59
59
59
59
EO
s9
59
59
59qo
59
58
co
12? 'Ot23 .64
123.88
L24.L7
L24 .46
t24.64
t24.80
'J.2 4 . 95
125.15
12s.31
125.51
125 .60
L25 .69
r25 .8 4
L25.9',7
r,26. 15
L26.3L
L26.44
126.51
L26.56
0.l,L 51
0. 11 51
0.11
0. 11
0. L1
0.11
0.11
0.11
0.11
0.11
0.11
0.11
0.11
0.11
0. 11
0. 11
0. r.1
0. 11
0.11
0.11
51
51
51
51
51
51
51
51
51
51
51
E1
51
51
51
51
51
Final Average*
Maxinum*
5E
59
125. t5
L26.s6
o,11
0.11
51
51
06/L8/2024 06/L8/2024 06/L8/2024 05/18/2024
14:18
56
L4:20 L4:20 l4:20
Minimum*123.18 0.11 51
06/L8/2024 06/L8/2024 06/78/2024 05/t8/202414:00 14:00 L4:20 L4120
* Does not include Inval-id Averaging Periods ("N/A")
Page L of
Company: Rio Tinto Kennecott
PIant:
City/St: Magna, UT
Source: DUCT
CE!4TEK KvB-Enertec N€tDNIS@
Average Values Report
cenerated: 6/78/2O24 75275
Averag'e Aveaage Averaqe
D-T€frtr D SO2PrrrR D SO2 1Hf,
Version 48.0
Period Start: 5/18/2024 14z2]-
Period End: 6/18/2024 14:41
Validation Type: 1/1 min
Averaging Period: 1 mj-n
Type: Block Avg
Auerag€
D SO2
Period Start: ppmw degF t ppnd
06/18/2024 t4:22
05/18/2024 14:23
06/78/2024 74:.24
06/18/2024 14.25
06/L8/2024 14t26
05/18/2024 t4:2'7
05/18/2024 t4:28
06/L8/2024 t4:29
06/18/2024 L4:30
06/L8/2024 14t37
06/t8/202a L4:32
06/18/2024 t4|33
06/L8/2024 74.34
06/18/2024 14:35
06/L8/2024 L4:35
06/78/2024 1,4:3'l
06/78/2024 14t38
06/t8/2024 t4239
06/78/2024 14240
05/78/2024 L4:.4L
5'7
5'7
5'7
55
56
56
56
55
55
55
55
56
56
55
56
55
55
55
54
54
0.11
0. 11
0. 11
0.11
0. t1
0.1.2
0.12
0.t2
0.L20.t2
0.t2
U. LZ
0.72
0.L2
0.L2
0.72
0.12
0.L2
0.L2
0.L2
51
51
51
51
51
51
51
51
51
51
51
51
5I
51
51
51
51
51
51
t26.'72
t26.88
t2'7.05
L2'7 .27
t2'7 .31
t2'7 .40
72'7 .49
L21.56
t21.6).
r21.65
t2'7.'70
72'7 .'71
72'7.75
t21.82
L21.89
128.00
t28.75
128.15
L2'7 .61
127.10
Eina1 Average*
l.{a:rimr-:n*
Mininr.ro*
14 224
5r1
L27 .50
128.16
126.60
56
51
o.Lz 5to.L2 51
06/18/2024 06/78/2024 06/18/2024 05/t8/202414:38 14t47 14t47
06/18/2024 06/18/2024 06/18/2024 06/L8/2024
14:41 14:21, 14:26
* Does not include Invalid Averaging Periods ("N/A")
l4: 41
0.11 51
of 1Page 1
Company: Rio Tinto Kennecott
Plant:
City/St: Magna, UT
Source: DUCT
CEI.fTEK lfiIB-En€rtec NetDAHS@
Average values Report
Generated: 5/18 /2024 75 t13
Version 48.0
Period Start: 6/1,8/2024 14:.42
Period Endz 5/18/2024 t5:02Validation Type: 1/1 min
Averaging Period: I min
Type: Block Avg
Averag6
D SO2
Average
D_Tenr
Average Average
D SO2PwrR D SO2 1Hr
Period Start: ppuw desE. t ppnd
uo/
06/t8/2024 74t43
06/L8/2024 74244
06/L8/2024 14245
06/]-8/2024 74.46
06 / L8 / 2024 74 : 4-l
06/L8/2024 14248
06/L8/2024 14:49
06/L8/2024 ta:50
06/L8/2024 14:5L
06/78/2024 14:.52
06/18 /2024 74-.53
06/t8/2024 1,4:54
06/L8/2024 L4:55
06/r8/2024 14:55
06/L8/2Q24 L4:5'1
06/L8/2024 L4:58
05/L8/2024 t4t59
06/L8/2024 L5200
06/78/2024 15:01
06/18/2024 15:02
q?
53
53
53
53
53
53
53
Et
53
53
53
52
az
52
5L
5L
5l
0.t2
0.12
0.720.t2
0.72
0.12
0.72
0.12
0.L2
0.1.2
0.L2
U. LI
0.12
0.12
o.t2
0 .12
0.L2
0.L2
0.L2
5L
51
51
51
51
51
51
51
51
51
51
51
51
51
51
51
51
55
56
55
1.26.19
125.85
12s.53
125.22
12s.08
12s.01
t24 .95
724.89
r24.80
124.'1 5
125.09
t25 .0'7
t24 .93
t24.64
124 .44
724.2t
123.82
123.59
L23 .6LL23.'73 0.L2
FinaJ. Average*
Maximum*
53 1211 .85
5rt L26.65
06/78/2024 06/18/2024 06/L8/2024 A6/18/2024
L4:42
L23.59
15:02 15:02
o.L2 52
o.L2 56
o.12 51
L4:42
51Minimum*06/78/2024 06/18/2024 06/78/2024 06/t8/202415:02 1"5:00 15:02
* Does not include Invalid Averaging Periods ("N/A")
14:59
of1Page 1
CEIrTEK l(vB-Enertec NetD:AHSO
Average Values Report
Generated: 6/18 /2024 L5 :5L
Version 48.0
Company: Ri.o Tinto Kennecott
Plant:
City,/St : Magna, UT
Source: DUCT
Period Start: 6/18/2024 L5220
Period Endt 5/L8/2A24 L5:40
Validation Type: 1/1 min
Averaging Period: I min
Type: Block Avg
JLv6!ag€
D_S02
Av€rage
D_fery
Av€rage Average
D SO2PsrR D SO2 1Hr
Period Start: Ptor degE. t PPnd
06/78/2024 L5t2L
05/18/2024 L5:22
05/t8/2024 L5:23
05/18/2024 15:.24
06/L8/2024 75:.25
06/L8/2024 75|26
06/tB /2024 t5l.2'7
06/78/2024 L5.28
06/t8/2024 L5229
06/t8/2024 15;30
06/L8/2024 L5:31
06/78/2024 15232
05/t8/2024 15233
Q6/18/2024 75:.34
06/L8/2024 L5:.35
06/L8/2024 75|36
06/L8 /2024 15:3'7
06/L8/2024 15t38
06/L8/2024 L5:39
05/18/2A24 15:40
56
56
5'7
58
58
59
59
1.26.7 4
1.26.86
L21.02
r2"t.23
t2'7 .40
L2'7.55
L2'7 .62
L2'7 .5L
0.L2
0.L2
0.L20.t2
0.12
0.L2
0.L2
0.L2
55
55
55
55
55
56
56
55
55
56
56
55
55
56
56
55
55
56
56
56
L21.55 0-1260 72'7.5'760 72't .34
0.1.2
0 -t260 125 .8',7 0 .12
67 :-26.56 0.12
0.t261 1-25.9651 125.'7 4 0.12
6t
6t
125.82 0.12
125.89 0.L2
0.L2
0.t2
0.1.2
62 725.96
62
62
126.24
t26.40
MaxiEum*
MiniEue*
62 L27.62 0.L2 56
06/78/2024 05/t8/2024 06/18/2024 05/18/2024
L5:40 15:2'1 L5:40 15:40
5655 L25.14 0.L2
06/18/2024 06/18/2024 06/78/2024 06/18/2024
15:27 15:35 15:40 l5:40
* Does not include InvaLid Averaging Periods ("N/A")
t'n"
_' - :_t
CE!'ITEK KvB-Enert€c N€tDAIIS@
Average values Report
cenerated: 6/L8 /2024 16:.04
Version 48.0
Company: Rio Tinto Kennecott
Plant:
City/St: Magna, UT
Source: DUCT
Period Start: 6/L8/2024 L5z4L
Period Endt 6/L8/2024 16:01
Validation Type: 1/1 min
Averaging Period: 1 min
Type: Bfock Avg
Awerage
D SO2
Average Average Averag€
D_T€'F D_SO2PwrR D_SO2_1Hr
Period Start: ppmr degF t ppnd
06/18/2024 75:42
06/t8/2024 t5:43
05/18/2024 15:.44
06/L8/2024 75:45
06/t8/2024 15:46
06 / L8 / 2024 L5 : 4'7
05/78/2024 L5t48
05/18/2024 L5249
05/t8/2024 15:50
53
63
64
64
65
65
6s
6s
65
t25.11 0.12126.55 0.t2 56
56
56
56
56
56
56
55
55
56
56
55
55
56
56
56
56q6
59
tro
L26.49
L26.75
r2s.86
0.t2
0.L2
0.L2125.80 0.L2126.01 0.L2L25.26 0.L2
126 -s8 0 -72
06/L8/2024 L5.5L 55
06/L8/2024 t5-.52 55
t26.88
r2'7.30
L2"t.53
rz't.'l'1
U.IZ
0.t2
0.12
o.12
06/L8/2024 75:.53
06/L8/2024 15?54
06/L8/2024 t5:55
06/L8/2024 15t56
05/tB /2024 t5 z5'7
06/78/2024 t5:58
05/L8/2024 t5t59
06/L8/2024 16:00
65
64
64
53
53
63
bz
52
L21 .95 0.t2L28.t2 0.t2
128.24
128.33
128.31
L28 .40
0.12
0.L2
0.L2
0.t2
06/L8/2024 l6t0L 62 L28 .44 0.t2
Final Awerage* 64
Maximu!* 65
t27 .L7
L2A.A4
o.L2
o.12
56
59
06/L8/2024 06/1.8/2024 06/18/2024 06/t8/2024
15:53
Mininun* 62
1"6:01
125.80
l6: 01
o.L2
16:01
56
06/78/2024 06/L8/2024 06/\8/2024 06/L8/2024
15:01 L5t4'7 16:01
* Does not include Invalid Averaging Periods ("N/A")
15:59
Page 1 of
=-
CEMIEK Is/B-En€lt€c NetDiAHS@
Average Values Report
Generated: 5/78 /2024 16224
Version 48.0
Period Start: 6/78/2024 l-6:02
Period End': 5/18/2024 16t22Val-idation Type: L/l min
Averaging Period: 1 min
Type: Bl-ock Avg
Company: Rio Tinto Kennecott
PIant:
City,/St : Magna, UT
Source: DUCT
Averag6
D SO2 D-TOnrr
Average Av6rag6 Average
D_SO2PrrrR D_SO2_1Hr
Period Start: ppBL d.eSE t PPnd
05/I8/2024 16tA3
06/t8/2024 76:04
06/L8/2024 76:05
06/18/2024 76:06
06/L8/2024 76|01
06/L8/2024 t6:08
06/18/2024 t6:09
06/18 /2024 1.621.0
06/18/2024 L5zLl
05/L8/2024 L6tL2
06/L8 /2024 16:1,3
06/L8/2024 76214
06/t8 /2024 76|1.5
06/18/2024 76:t6
06/L8/2024 76:L]
06/78/2024 762L8
06/18/2024 16:19
06/tB /2024 1.6:20
06/18/2024 16:27
05/18/2024 t6:22
6t
6l
6L
5l
61
6t
67
60
50
OU
OU
60
6L
6L
61
6L
61
62
62
62
728 .45
128.51
128.s0
L28 .42
r.28.31
L28.20
r.28.13
r,28.03
L2't.8'7
L2'7 .'t3
LZ l.bu
L21.49
1.2'1 .36
t2't.23
t2'1 .08
L26.91
L25.15
L26.65
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0.t2 590.L2 590.72 59
59
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0.L2
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59
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0.72
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0.t2
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59
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Does not include Invalid Averaging Periods ("U/e"1
15:22
, illBttr"
Kennecott Main Stack SME011 RATA RM 1, 2, 3A, 6C, 7E, & 19 (Tested 5-29-2024)
Reference Methods 2, 3A, 6C, 7E, 10, & 19
Source Information
Company Name Kennecott Copper
Company Contact:Sean Daly
Contact Phone No.801-569-6331
Stack Designation:Main Stack
Test & Review Dates
Test Date:5/29/2024
Review Date: 12/6/2024
Observer:Not Observed
Reviewer:Rob Leishman
Emission Limits Emission Rates
SO2 NOX CO SO2 NOX CO
lbs./MMBtu
lbs./hr. 552.0 35.0 176.06 23.900
ppm
%O2 Correction as a whole #
Test Information
Stack I.D. inches
As ft^2 Y Dl H @ Cp Pbar Pq (static)
Ps
Stack Pressure
288.00 452.389 1.0030 1.681 0.84 25.27 0.02 25.271471
Contractor Information
Contact:Austin Keough
Contracting Company: Alliance Source Testing
Address: 2855S 500 W Sutie A, Salt Lake City, Utah 84115
Phone No.: [phone]
Project No.:

Division of Air Quality
Instrumental Reference Methods - Gaseous Measurements
Round
Method 19 - F factors for Coal, Oil, and Gas
Fd Fw Fc
dscf/MMBtu wscf/MMBtu scf/MMBtu Diluent
F factor used
O2
CO2
Anthracite 2
Bituminous 2
Lignite
Natural
Propane
Butane
10100
COAL
OIL
GAS
9780
9860
9190
8710
8710
8710
10540
10640
11950
320
10610
10200
10390
1970
1800
1910
1420
1040
1190
1250
Wet CEM
Correct For O2
CO2 Interference w/CO
Yes
Yes
Yes
Kennecott Main Stack SME011 RATA RM 1, 2, 3A, 6C, 7E, & 19 (Tested 5-29-2024)
Company Kennecott Copper
Point Source Main Stack
Test Date 5/29/24
Start
Time
End
Time Run
NOx
PPM
NOx
lb/hr
SO2 - low
PPM
SO2 - high
PPM
SO2 - Average
PPM
SO2
lb/hr Flow
scfm
Headers
Here
Headers
Here
Headers
Here
Headers
Here
10:05 10:26 1 6.12 25.67 42.9 39 42.89 249.7 584607
11:33 11:54 2 5.93 25.7 28.89 26 28.9 173.7 604412
11:54 12:15 3 5.76 24.87 18.24 16 18.24 109.2 601722
12:51 13:12 4 4.62 20.95 13.22 11 13.21 83.2 632377
13:12 13:33 5 5.11 23.18 32.38 29 32.38 203.4 632040
13:33 13:54 6 6.19 27.36 44.88 41 44.9 276.2 616229
14:10 14:31 7 6.3 27.19 28.26 26 28.25 169.7 602309
14:31 14:52 8 5.76 24.74 44.96 41 44.96 269.2 598481
14:52 15:13 9 5.06 21.24 43.44 40 43.44 253.2 585178
15:34 15:55 10 5.22 21.79 24.43 22 24.42 141.6 582409
11
12
13
14
15
16
Kennecott Main Stack SME011 RATA RM 1, 2, 3A, 6C, 7E, & 19 (Tested 5-29-2024)
Headers
Here
Kennecott Main Stack SME011 RATA RM 1, 2, 3A, 6C, 7E, & 19 (Tested 5-29-2024)
Division of Air Quality
NSPS Relative Accuracy Performance Specification Test - CEMS Certification
Kennecott Copper
Main Stack
SO2 Analyzer:Serial No.:
CO2 Analyzer:Serial No.:
Acquisition System:Serial No.:
Acquisition System: Serial No.:
Equivalent Emission Limit:552.00
Test Date SO2 Dry SO2 Dry SO2 Test Date % CO2 Dry
5/29/2024 RM CEMS Diff RM CEMS Diff RM CEMS Diff 5/29/2024 RM CEMS Diff
Run#Start
Time
End
Time ppm lbs./MMBtu lbs./hr. Run#
Start
Time End Time %c %c
1 10:05 10:26 36.2 42.89 200.44 249.7 1 10:05 10:26 0.7
2 11:33 11:54 Y 25.7 28.9 -3.19 Y 142.31 173.7 -31.4 2 11:33 11:54 0.6
3 11:54 12:15 Y 17.4 18.24 -0.84 Y 98.76 109.2 -10.4 3 11:54 12:15 0.6
4 12:51 13:12 Y 13.6 13.21 0.38 Y 81.07 83.2 -2.1 4 12:51 13:12 0.5
5 13:12 13:33 Y 31.0 32.38 -1.39 Y 184.12 203.4 -19.3 5 13:12 13:33 0.5
6 13:33 13:54 Y 40.7 44.9 -4.25 Y 247.56 276.2 -28.6 6 13:33 13:54 0.6
7 14:10 14:31 Y 27.4 28.25 -0.82 Y 160.76 169.7 -8.9 7 14:10 14:31 0.6
8 14:31 14:52 Y 41.7 44.96 -3.22 Y 251.05 269.2 -18.2 8 14:31 14:52 0.6
9 14:52 15:13 Y 41.4 43.44 -2.00 Y 248.11 253.2 -5.1 9 14:52 15:13 0.7
10 15:34 15:55 Y 24.3 24.42 -0.11 Y 146.44 141.6 4.8 10 15:34 15:55 0.8
11 11
12 12
13 13
14 14
15 15
16 16
Average = 29.3 30.97 1.72 173.4 186.600 13.247 Average =
Sd Standard Deviation = 1.56 Sd Standard Deviation = Sd Standard Deviation = 12.094 Sd Standard Deviation =
Confidence Coefficient = 1.20 Confidence Coefficient = Confidence Coefficient = 9.3 Confidence Coefficient =
RA - Relative Accuracy =10.00%RA RA RA - Relative Accuracy =
n = 9 0 9 n = 0 or RA of 1%
t0.975 = 2.306 2.306 t0.975 =
E.L. Relative Accuracy = 31% 4.08%
a For steam generators;b Average of three samples;0
c Make sure that RM and M data are on a consistent basis either wet or dry.
40 CFR 60 Performance Specification 2 For SO2 and NOx Continuous Emission Monitoring Systems
13.2 Relative accuracy Performance Specification. The RA of the CEMSS must be not greater than 20 percent when RM is used in the denominator of Eq. 2-6
(average emissions during test are greater than 50 percent of the emission standard)or 10 percent when the applicable emission standard is used in the
denominator of Eq. 2-6 (average emissions during test are less than 50 percent of the emission standard).
Up dated January 17, 2006
40 CFR 60 Performance Specification 3 For O2 and CO2 Continuous Emission Monitoring Systems
13.2 CEMS Relative Accuracy Perfromance Specification.
The RA of the CEMS must be no grater than 20 percent of the mean value of the reference method (RM) data. 1 percent O2 or CO2.
The results are also acceptable if the absolute value of the difference between the mean RM value and the mean CEMS value is less than or equal to 1.0 percent O2 (or CO2).
Up dated September 14, 2016
40 CFR 60 Performance Specification 6 For Continuous Emission Rate Monitoring Systems (CERMS)
13.2 CERMS Relative Accuracy. The RA of the CERMS shall be no greater than 20 percent of the mean value of the RM's test data in terms of the nits of the emission
standard, or 10 percent of the applicable standard, which err is greater.
Up dated January 17, 2006
Passed Passed
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Thermo Scientific 43iQ 12127413439
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Kennecott Main Stack SME011 RATA RM 1, 2, 3A, 6C, 7E, & 19 (Tested 5-29-2024)
Division of Air Quality
Relative Accuracy Test Audit of
Kennecott Copper
Main Stack
NOX Analyzer:Serial No.:
O2 Analyzer:Serial No.:
Acquisition System:Serial No.:
Acquisition System: Serial No.:
Equivalent Emission Limit:35.00
Date NOx Dry NOx Dry NOx Test Date % O2 Dry
5/29/2024 RM CEMS Diff RM CEMS Diff RM CEMS Diff 9/30/2014 RM CEMS Diff
Run#Start
Time
End
Time ppm lbs./MMBtu lbs./hr. Run#
Start
Time End Time %c %c
1 10:05 10:26 Y 6.3 6.12 0.2 Y 25.20 25.67 -0.47 1 10:05 10:26 16.3
2 11:33 11:54 Y 5.8 5.93 -0.1 23.10 25.7 2 11:33 11:54 16.9
3 11:54 12:15 Y 5.7 5.76 -0.1 Y 23.23 24.87 -1.64 3 11:54 12:15 16.8
4 12:51 13:12 Y 4.6 4.62 -0.1 Y 19.55 20.95 -1.40 4 12:51 13:12 17.3
5 13:12 13:33 Y 5.0 5.11 -0.1 Y 21.54 23.18 -1.64 5 13:12 13:33 17.4
6 13:33 13:54 Y 6.2 6.19 0.0 Y 27.27 27.36 -0.10 6 13:33 13:54 17.1
7 14:10 14:31 Y 6.4 6.3 0.1 Y 26.85 27.19 -0.34 7 14:10 14:31 17.5
8 14:31 14:52 Y 6.0 5.76 0.2 Y 25.80 24.74 1.06 8 14:31 14:52 17.7
9 14:52 15:13 5.3 5.06 Y 22.93 21.24 1.69 9 14:52 15:13 17.6
10 15:34 15:55 Y 5.4 5.22 0.2 Y 23.53 21.79 1.74 10 15:34 15:55 17.5
11 11
12 12
13 13
14 14
15 15
16 16
Average = 5.7 5.7 0.049 23.99 24.11 0.12 Average =
Sd Standard Deviation = 0.14 Sd Standard Deviation = Sd Standard Deviation = 1.348 Sd Standard Deviation =
Confidence Coefficient = 0.107 Confidence Coefficient = Confidence Coefficient = 1.036 Confidence Coefficient =
RA - Relative Accuracy =2.70%Relative Accuracy = Relative Accuracy =4.80%RA - Relative Accuracy =
n = 9 0 9 n = 0 or RA of 1%
t0.975 = 2.306 t0.975 = t0.975 = 2.306 t0.975 =
E.L. Relative Accuracy = EMRA EMRA 69%
a For steam generators;b Average of three samples;
c Make sure that RM and M data are on a consistent basis either wet or dry.
40 CFR 60 Performance Specification 2 For SO2 and NOx Continuous Emission Monitoring Systems
4. Performance and Equipment Specifications
4.3 Relative accuracy. The RA of the CEMSS shall be no grater than 20 percent of the mean value of the RM test data in terms of the
units of the emission standard or 10 percent of the applicable standard, whichever is greater
For SO2 emission standards between 0.30 and 0.20 lbs./MMBtu use 15 Percent of the applicable standard;
For SO2 emission standards below 0.20 lbs./MMBtu use 20 Percent of the emission standard;
40 CFR 60 Performance Specification 3 For O2 and CO2 Continuous Emission Monitoring Systems
12. Calculate the arithmetic difference between the RM and the CEMSS output for each run. The average of the nine (of more) data sets constitute the RA.
13.2 Relative accuracy. The RA of the CEMSS must be no grater than 1 percent O2 or CO2.
40 CFR 60 Performance Specification 6 For Continuous Emission Rate Monitoring Systems (CERMS)
13.2 CERMS Relative Accuracy. The RA of the CERMS shall be no greater than 20 percent of the mean value of the RM's test data in terms of the nits of the emission
standard, or 10 percent of the applicable standard, which err is greater.
Up dated January 17, 2006
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PassedPassed
12127413438Thermo Fisher 42iQLS
Kennecott Main Stack SME011 RATA RM 1, 2, 3A, 6C, 7E, & 19 (Tested 5-29-2024)
Division of Air Quality
Relative Accuracy Test Audit of
Kennecott Copper
Main Stack
CO Analyzer:Serial No.:
Acquisition System:
Acquisition System: Serial No.:
Equivalent Emission Limit:
Date CO Dry CO Dry CO
5/29/2024 RM CEMS Diff RM CEMS Diff RM CEMS Diff
Run#Start
Time
End
Time ppm lbs./MMBtu lbs./hr.
1 10:05 10:26
2 11:33 11:54
3 11:54 12:15
4 12:51 13:12
5 13:12 13:33
6 13:33 13:54
7 14:10 14:31
8 14:31 14:52
9 14:52 15:13
10 15:34 15:55
11
12
13
14
15
16
Average =
Sd Standard Deviation =
Confidence Coefficient =
RA - Relative Accuracy =
n = 0 0 0
t0.975 =
E.L. Relative Accuracy =
a For steam generators;b Average of three samples;
c Make sure that RM and M data are on a consistent basis either wet or dry.
40 CFR 60 Performance Specification 4 For Carbon Monoxide (CO) Continuous Emission Monitoring Systems
applicable emission standard is used to calculate RA.
40 CFR 60 Performance Specification 4A For Carbon Monoxide (CO) Continuous Emission Monitoring Systems
13.2 Relative accuracy. The RA of the CEMSS must be no greater than 10 percent when the average RM value is used to calculate RA, 5 percent when the applicable
emission standard is used to calculate RA, or within 5 ppmv when the RA is calculated as the absolute average difference between the RM and CEMSS plus the 2.5
percent confidence coefficient.
40 CFR 60 Performance Specification 6 For Continuous Emission Rate Monitoring Systems (CERMS)
13.2 CERMS Relative Accuracy. The RA of the CERMS shall be no greater than 20 percent of the mean value of the RM's test data in terms of the nits of the emission
standard, or 10 percent of the applicable standard, which err is greater.
Up dated January 17, 2006
13.2 Relative accuracy. The RA of the CEMSS must be no grater than 10 percent when the average of the RM value is used to calculate RA or 5 percent when the
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Kennecott Main Stack SME011 RATA RM 1, 2, 3A, 6C, 7E, & 19 (Tested 5-29-2024)
Test Overview
NSPS Relative Accuracy
Performance Specification Test -
CEMS Certification Kennecott Copper
Point Source Main Stack
Contact Phone No.Sean Daly
Stack Designation:Main Stack
Project No.:0
Run Run # 1 Run # 2 Run # 3 Run # 4 Run # 5 Run # 6 Run # 7 Run # 8 Run # 9 Run # 10 Run # 11 Run # 12
Test Date 5/29/2024 5/29/2024 5/29/2024 5/29/2024 5/29/2024 5/29/2024 5/29/2024 5/29/2024 5/29/2024 5/29/2024 5/29/2024 5/29/2024
Start Time 10:05 11:33 11:54 12:51 13:12 13:33 14:10 14:31 14:52 15:34
Stop Time 10:26 11:54 12:15 13:12 13:33 13:54 14:31 14:52 15:13 15:55
Run Time 0:21 0:21 0:21 0:21 0:21 0:21 0:21 0:21 0:21 0:21
Stack I.D. (inches)288.00 288.00 288.00 288.00 288.00 288.00 288.00 288.00 288.00 288.00 288.00 288.00
As ft^2 452.39 452.39 452.39 452.39 452.39 452.39 452.39 452.39 452.39 452.39 452.39 452.39
Cp (Pitot Tube Coefficient)0.84 0.84 0.84 0.84 0.84 0.84 0.84 0.84 0.84 0.84 0.84 0.84
Yd Meter Y Factor (unit less)1.0030 1.0030 1.0030 1.0030 1.0030 1.0030 1.0030 1.0030 1.0030 1.0030 1.0030 1.0030
Pbar Barometric Pressure ("Hg)25.27 25.27 25.27 25.27 25.27 25.27 25.27 25.27 25.27 25.27 25.27 25.27
Pq (Static Pressure)0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02
Ps (Pressure of the Stack)25.27 25.27 25.27 25.27 25.27 25.27 25.27 25.27 25.27 25.27 25.27 25.27
Ts Stack Temp Avg. oF 115.50 118.50 118.20 128.20 127.60 127.90 131.00 132.00 130.90 132.30
Tm Meter Temperature oF 89.00 89.00 89.00 88.00 88.00 88.00 89.00 89.00 89.00 89.00
CO2 (carbon dioxide)0.71 0.62 0.62 0.49 0.51 0.64 0.64 0.62 0.70 0.75
O2 (oxygen)16.25 16.88 16.84 17.31 17.35 17.08 17.47 17.68 17.63 17.46
Md Molecular Weight Dry 28.76 28.77 28.77 28.77 28.78 28.79 28.80 28.81 28.82 28.82 #VALUE!#VALUE!
Ms Molecular Weight Wet 28.02 28.03 28.03 28.28 28.29 28.30 28.12 28.13 28.14 28.14 #VALUE!#VALUE!
N2 (nitrogen)83.04 82.50 82.54 82.21 82.14 82.28 81.89 81.70 81.67 81.79 #VALUE!#VALUE!
Vm Sample Volume (cf)38.07 38.07 38.07 38.76 38.76 38.76 39.14 39.14 39.14 39.14 0.00 0.00
Vm std Standard Volume (dscf)31.00 31.00 31.00 31.62 31.62 31.62 31.87 31.87 31.87 31.87
Vlc Moisture (g)48.60 48.60 48.60 31.90 31.90 31.90 45.20 45.20 45.20 45.20
Vwstd Moisture Volume (scf)2.29 2.29 2.29 1.50 1.50 1.50 2.13 2.13 2.13 2.13
Bws Moisture Content (%100)6.87%6.87%6.87%4.53%4.53%4.53%6.26%6.26%6.26%6.26%
S Bws (saturation moisture)12.05%13.11%13.00%17.10%16.83%16.96%18.43%18.92%18.38%19.07%
AvgSqrtDlp √∆P 0.438 0.439 0.450 0.468 0.465 0.477 0.468 0.480 0.478 0.481
Vs. Gas Velocity (ft./sec)28.33 28.49 29.20 30.46 30.30 31.07 30.61 31.47 31.27 31.53
Qa (stack actual flow rate) acfm 768,971 773,314 792,586 826,786 822,443 843,344 830,858 854,201 848,772 855,830
Qs (stack std. flow rate) dscfm 554,946 555,186 569,317 598,446 595,911 610,743 587,734 603,226 600,508 604,070 #VALUE!#VALUE!
Qsd (stack std. flow rate) dscfh 33,296,740 33,311,145 34,159,007 35,906,790 35,754,651 36,644,559 35,264,028 36,193,544 36,030,473 36,244,183
Qw (stack flow rate) wscfm 35,753,589 35,769,057 36,679,479 37,611,727 37,452,364 38,384,527 37,617,874 38,609,434 38,435,478 38,663,453
Kennecott Main Stack SME011 RATA RM 1, 2, 3A, 6C, 7E, & 19 (Tested 5-29-2024)
Test Overview
NSPS Relative Accuracy
Performance Specification Test -
CEMS Certification Kennecott Copper
Point Source Main Stack
Contact Phone No.Sean Daly
Stack Designation:Main Stack
Project No.:0
Run Run # 1 Run # 2 Run # 3 Run # 4 Run # 5 Run # 6 Run # 7 Run # 8 Run # 9 Run # 10 Run # 11 Run # 12
Test Date 5/29/2024 5/29/2024 5/29/2024 5/29/2024 5/29/2024 5/29/2024 5/29/2024 5/29/2024 5/29/2024 5/29/2024 5/29/2024 5/29/2024
Heat Input - BTU/hr.
F factor - scf/MMBtu
Fuel Analysis - ft3/min 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0
Fuel Flow - ft3/min 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
Heat Input - BTU/hr.
SO2 Concentrations
Uncorrected 36.49 25.86 17.50 13.74 31.03 40.61 27.53 41.77 41.47 24.44
Dry Corrected 36.22 25.71 17.40 13.59 30.99 40.65 27.43 41.74 41.44 24.31
Wet Corrected
NOx Concentrations
Uncorrected 6.27 5.85 5.74 4.62 5.11 6.29 6.40 5.96 5.32 5.43
Dry Corrected 6.34 5.81 5.69 4.56 5.04 6.23 6.37 5.97 5.33 5.44
Wet Corrected
CO Concentrations
Uncorrected
Dry Corrected
Wet Corrected
CO2 Concentrations
Uncorrected 0.69 0.61 0.61 0.48 0.50 0.63 0.63 0.61 0.69 0.74
Dry Corrected 0.71 0.62 0.62 0.49 0.51 0.64 0.64 0.62 0.70 0.75
Wet Corrected
O2 Concentrations
Uncorrected 16.27 17.00 16.96 17.36 17.33 17.06 17.44 17.63 17.58 17.41
Dry Corrected 16.25 16.88 16.84 17.31 17.35 17.08 17.47 17.68 17.63 17.46
Wet Corrected
Kennecott Main Stack SME011 RATA RM 1, 2, 3A, 6C, 7E, & 19 (Tested 5-29-2024)
Division of Air Quality
NSPS Relative Accuracy Performance Specification Test - CEMS Certification
Kennecott Copper
Main Stack
Average Emission
Dry SO2 NOX CO
lbs./MMBtu Average % concentration
lbs./hr.176.06 23.90 CO2 O2
ppm or % 29.95 5.68 0.63 17.20
Run 1 Enter O2 or CO2
Dry SO2 NOX CO CO2 O2
Atomic Weight 64 46 28
lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d))
lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d)
lbs./cu.ft 6.020E-06 7.568E-07
lbs./hr.200.44 25.20 0.71 16.25
ppm or %36.22 6.34 0.69 16.27
Run 2
Dry SO2 NOX CO CO2 O2
Atomic Weight 64 46 28
lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d))
lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d)
lbs./cu.ft 4.272E-06 6.934E-07
lbs./hr.142.31 23.10 0.62 16.88
ppm or %25.71 5.81 0.69 17.00 Raw Value
Run 3
Dry SO2 NOX CO CO2 O2
Atomic Weight 64 46 28
lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d))
lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d)
lbs./cu.ft 2.891E-06 6.801E-07
lbs./hr.98.76 23.23 0.62 16.84
ppm or %17.40 5.69 0.61 16.96 Raw Value
Run 4
Dry SO2 NOX CO CO2 O2
Atomic Weight 64 46 28
lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d))
lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d)
lbs./cu.ft 2.258E-06 5.446E-07
lbs./hr.81.07 19.55 0.49 17.31
ppm or %13.59 4.56 0.48 17.36 Raw Value
Run 5
Dry SO2 NOX CO CO2 O2
Atomic Weight 64 46 28
lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d))
lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d)
lbs./cu.ft 5.150E-06 6.025E-07
lbs./hr.184.12 21.5423 0.51 17.35
ppm or %30.99 5.04 0.50 17.33 Raw Value
Corrected For Cal. Drift
Raw Value
Corrected For Cal. Drift
Corrected For Cal. Drift
Corrected For Cal. Drift
Corrected For Cal. Drift
O2
CO2
Clear
lbs./MMBTU
Kennecott Main Stack SME011 RATA RM 1, 2, 3A, 6C, 7E, & 19 (Tested 5-29-2024)
Division of Air Quality
NSPS Relative Accuracy Performance Specification Test - CEMS Certification
Kennecott Copper
Main Stack
O2
CO2
Clear
lbs./MMBTU
Run 6
Dry SO2 NOX CO CO2 O2
Atomic Weight 64 46 28
lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d))
lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d)
lbs./cu.ft 6.756E-06 7.441E-07
lbs./hr.247.56 27.2654 0.64 17.08
ppm or %40.65 6.23 0.63 17.06 Raw Value
Run 7
Dry SO2 NOX CO CO2 O2
Atomic Weight 64 46 28
lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d))
lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d)
lbs./cu.ft 4.559E-06 7.614E-07
lbs./hr.160.76 26.85 0.64 17.47
ppm or %27.43 6.37 0.63 17.44 Raw Value
Run 8
Dry SO2 NOX CO CO2 O2
Atomic Weight 64 46 28
lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d))
lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d)
lbs./cu.ft 6.936E-06 7.129E-07
lbs./hr.251.05 25.80 0.62 17.68
ppm or %41.74 5.97 0.61 17.63 Raw Value
Run 9
Dry SO2 NOX CO CO2 O2
Atomic Weight 64 46 28
lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d))
lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d)
lbs./cu.ft 6.886E-06 6.363E-07
lbs./hr.248.11 22.93 0.70 17.63
ppm or %41.44 5.33 0.69 17.58 Raw Value
Run 10
Dry SO2 NOX CO CO2 O2
Atomic Weight 64 46 28
lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d))
lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d)
lbs./cu.ft 4.040E-06 6.493E-07
lbs./hr.146.44 23.53 0.75 17.46
ppm or %24.31 5.44 0.74 17.41 Raw Value
Run 11
Dry SO2 NOX CO CO2 O2
Atomic Weight 64 46 28
lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d))
lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d)
lbs./cu.ft
lbs./hr.
ppm or %Raw Value
Corrected For Cal. Drift
Corrected For Cal. Drift
Corrected For Cal. Drift
Corrected For Cal. Drift
Corrected For Cal. Drift
Corrected For Cal. Drift
Kennecott Main Stack SME011 RATA RM 1, 2, 3A, 6C, 7E, & 19 (Tested 5-29-2024)
Calibration Error Test
Test Date May 29, 2024 O2
CS - Cal. Span 23.95
Units %
Cylinder No. Expiration
Date Cal. Gas CV- Certified
Concentration
CDir or CS -
Measured
Concentration
Difference
ACE Eq. 7E-1
Analyzer Cal.
Error
Status
Low-level 0.00 0.02 0.02 0.08% Passed Cal.
Mid-level 12.00 12.05 0.05 0.21% Passed Cal.
High-level 23.95 23.94 0.01 0.04% Passed Cal.
% of Span Sec. 8.2.1 Cal Gas Verification
0 to 20% of CS - Cal. Span Low-Level 0.00%
40 to 60% of Cal. Span Mid-level 50.10%
100% of Cal. Span High-level 100.00%
Test Date May 29, 2024 CO2
CS - Cal. Span 10.00
Units %
Cylinder
No.
Expiration
Date Cal. Gas CV- Certified
Concentration
CDir or CS -
Measured
Concentration
Difference
ACE Eq. 7E-1
Analyzer Cal.
Error
Status
Low-level 0.00 0.01 0.01 0.100% Passed Cal.
Mid-level 5.00 5.04 0.04 0.400% Passed Cal.
High-level 10.00 10.03 0.03 0.300% Passed Cal.
% of Span Sec. 8.2.1 Cal Gas Verification
0 to 20% of Cal. Span Low-Level 0.00%
40 to 60% of Cal. Span Mid-level 50.00%
100% of Cal. Span High-level 100.00%
Test Date May 29, 2024 SO2
CS - Cal. Span 100.00
Units ppm
Cylinder
No.
Expiration
Date Cal. Gas CV- Certified
Concentration
CDir or CS -
Measured
Concentration
Difference
ACE Eq. 7E-1
Analyzer Cal.
Error
Status
Low-level 0.00 0.04 0.04 0.040% Passed Cal.
Mid-level 50.00 50.05 0.05 0.050% Passed Cal.
High-level 100.00 100.28 0.28 0.280% Passed Cal.
% of Span Sec. 8.2.1 Cal Gas Verification
0 to 20% of Cal. Span Low-Level 0.00%
40 to 60% of Cal. Span Mid-level 50.00%
100% of Cal. Span High-level 100.00%
Test Date May 29, 2024 NOx
CS - Cal. Span 30.00
Units ppm
Cylinder
No.
Expiration
Date Cal. Gas CV- Certified
Concentration
CDir or CS -
Measured
Concentration
Difference
ACE Eq. 7E-1
Analyzer Cal.
Error
Status
Low-level 0.00 0.00 0.00 0.000% Passed Cal.
Mid-level 15.00 14.87 0.13 0.433% Passed Cal.
High-level 30.00 30.02 0.02 0.067% Passed Cal.
% of Span Sec. 8.2.1 Cal Gas Verification
0 to 20% of Cal. Span Low-Level 0.00%
40 to 60% of Cal. Span Mid-level 50.00%
100% of Cal. Span High-level 100.00%
Test Date CO
CS - Cal. Span
Units ppm
Cylinder
No.
Expiration
Date Cal. Gas CV- Certified
Concentration
CDir or CS -
Measured
Concentration
Difference
ACE Eq. 7E-1
Analyzer Cal.
Error
Status
Low-level
Mid-level
High-level
% of Span Sec. 8.2.1 Cal Gas Verification
0 to 20% of Cal. Span Low-Level
40 to 60% of Cal. Span Mid-level
100% of Cal. Span High-level
Kennecott Acid Plant Tailgas SME011b RATA RM 1, 2, 3A, 6C, & 19 (Tested 6-18-2024)
Reference Methods 2, 3A, 6C, 7E, 10, & 19
Source Information
Company Name Kennecott Copper
Company Contact:Jenny Esker
Contact Phone No.801-569-6494
Stack Designation:Tail Gas
Test & Review Dates
Test Date:6/18/2024
Review Date: 12/8/2024
Observer:Not Observed
Reviewer:Rob Leishman
Emission Limits Emission Rates
SO2 NOX CO SO2 NOX CO
lbs./MMBtu
lbs./hr.
ppm 250.0 39.293
%O2 Correction as a whole #
Test Information
Stack I.D. inches
As ft^2 Y Dl H @ Cp Pbar Pq (static)
Ps
Stack Pressure
76.00 31.503 1.0030 1.681 0.84 0
Contractor Information
Contact:Austin Keough
Contracting Company: Alliance Source Testing
Address: 2855S 500 W Sutie A, Salt Lake City, Utah 84115
Phone No.: [phone]
Project No.:

Division of Air Quality
Instrumental Reference Methods - Gaseous Measurements
Round
Method 19 - F factors for Coal, Oil, and Gas
Fd Fw Fc
dscf/MMBtu wscf/MMBtu scf/MMBtu Diluent
F factor used
O2
CO2
Anthracite 2
Bituminous 2
Lignite
Natural
Propane
Butane
10100
COAL
OIL
GAS
9780
9860
9190
8710
8710
8710
10540
10640
11950
320
10610
10200
10390
1970
1800
1910
1420
1040
1190
1250
Wet CEM
Correct For O2
CO2 Interference w/CO
Yes
Yes
Yes
Kennecott Acid Plant Tailgas SME011b RATA RM 1, 2, 3A, 6C, & 19 (Tested 6-18-2024)
Company Kennecott Copper
Point Source Tail Gas
Test Date 6/18/24
Start
Time
End
Time Run
SO2
PPM
Headers
Here
Headers
Here
Headers
Here
Headers
Here
Headers
Here
Headers
Here
Headers
Here
Headers
Here
Headers
Here
Headers
Here
Headers
Here
12:40 13:01 1 45
13:01 13:22 2 49
13:22 13:43 3 51
14:08 14:29 4 58
14:21 14:42 5 56
14:42 15:03 6 53
15:20 15:41 7 59
15:41 16:02 8 64
16:02 16:23 9 61
10
11
12
13
14
15
16
Kennecott Acid Plant Tailgas SME011b RATA RM 1, 2, 3A, 6C, & 19 (Tested 6-18-2024)
Division of Air Quality
NSPS Relative Accuracy Performance Specification Test - CEMS Certification
Kennecott Copper
Tail Gas
SO2 Analyzer:Serial No.:
CO2 Analyzer:Serial No.:
Acquisition System:Serial No.:
Acquisition System: Serial No.:
Equivalent Emission Limit:250
Test Date SO2 Dry SO2 Dry SO2 Test Date % CO2 Dry
6/18/2024 RM CEMS Diff RM CEMS Diff RM CEMS Diff 6/18/2024 RM CEMS Diff
Run#Start
Time
End
Time ppm lbs./MMBtu lbs./hr. Run#
Start
Time End Time %c %c
1 12:40 13:01 Y 31.4 45 -13.58 #VALUE! 1 12:40 13:01
2 13:01 13:22 Y 34.6 49 -14.37 #VALUE! 2 13:01 13:22
3 13:22 13:43 Y 35.6 51 -15.39 #VALUE! 3 13:22 13:43
4 14:08 14:29 Y 42.1 58 -15.94 #VALUE! 4 14:08 14:29
5 14:21 14:42 Y 40.0 56 -15.97 #VALUE! 5 14:21 14:42
6 14:42 15:03 Y 37.6 53 -15.45 #VALUE! 6 14:42 15:03
7 15:20 15:41 Y 42.2 59 -16.78 #VALUE! 7 15:20 15:41
8 15:41 16:02 Y 46.5 64 -17.46 #VALUE! 8 15:41 16:02
9 16:02 16:23 Y 43.6 61 -17.42 #VALUE! 9 16:02 16:23
10 10
11 11
12 12
13 13
14 14
15 15
16 16
Average = 39.3 55.11 15.82 Average =
Sd Standard Deviation = 1.31 Sd Standard Deviation = Sd Standard Deviation = Sd Standard Deviation =
Confidence Coefficient = 1.00 Confidence Coefficient = Confidence Coefficient = Confidence Coefficient =
RA - Relative Accuracy = RA RA RA - Relative Accuracy =
n = 9 0 0 n = 0 or RA of 1%
t0.975 = 2.306 t0.975 =
E.L. Relative Accuracy = 16% 6.73%
a For steam generators;b Average of three samples;0
c Make sure that RM and M data are on a consistent basis either wet or dry.
40 CFR 60 Performance Specification 2 For SO2 and NOx Continuous Emission Monitoring Systems
13.2 Relative accuracy Performance Specification. The RA of the CEMSS must be not greater than 20 percent when RM is used in the denominator of Eq. 2-6
(average emissions during test are greater than 50 percent of the emission standard)or 10 percent when the applicable emission standard is used in the
denominator of Eq. 2-6 (average emissions during test are less than 50 percent of the emission standard).
Up dated January 17, 2006
40 CFR 60 Performance Specification 3 For O2 and CO2 Continuous Emission Monitoring Systems
13.2 CEMS Relative Accuracy Perfromance Specification.
The RA of the CEMS must be no grater than 20 percent of the mean value of the reference method (RM) data. 1 percent O2 or CO2.
The results are also acceptable if the absolute value of the difference between the mean RM value and the mean CEMS value is less than or equal to 1.0 percent O2 (or CO2).
Up dated September 14, 2016
40 CFR 60 Performance Specification 6 For Continuous Emission Rate Monitoring Systems (CERMS)
13.2 CERMS Relative Accuracy. The RA of the CERMS shall be no greater than 20 percent of the mean value of the RM's test data in terms of the nits of the emission
standard, or 10 percent of the applicable standard, which err is greater.
Up dated January 17, 2006
Passed
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Ametek 400 7744
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Kennecott Acid Plant Tailgas SME011b RATA RM 1, 2, 3A, 6C, & 19 (Tested 6-18-2024)
Division of Air Quality
Relative Accuracy Test Audit of
Kennecott Copper
Tail Gas
NOX Analyzer:Serial No.:
O2 Analyzer:Serial No.:
Acquisition System:Serial No.:
Acquisition System: Serial No.:
Equivalent Emission Limit:
Date NOx Dry NOx Dry NOx Test Date % O2 Dry
6/18/2024 RM CEMS Diff RM CEMS Diff RM CEMS Diff 9/30/2014 RM CEMS Diff
Run#Start
Time
End
Time ppm lbs./MMBtu lbs./hr. Run#
Start
Time End Time %c %c
1 12:40 13:01 1 12:40 13:01
2 13:01 13:22 2 13:01 13:22
3 13:22 13:43 3 13:22 13:43
4 14:08 14:29 4 14:08 14:29
5 14:21 14:42 5 14:21 14:42
6 14:42 15:03 6 14:42 15:03
7 15:20 15:41 7 15:20 15:41
8 15:41 16:02 8 15:41 16:02
9 16:02 16:23 9 16:02 16:23
10 10
11 11
12 12
13 13
14 14
15 15
16 16
Average = Average =
Sd Standard Deviation = Sd Standard Deviation = Sd Standard Deviation = Sd Standard Deviation =
Confidence Coefficient = Confidence Coefficient = Confidence Coefficient = Confidence Coefficient =
RA - Relative Accuracy = Relative Accuracy = Relative Accuracy = RA - Relative Accuracy =
n = 0 0 0 n = 0 or RA of 1%
t0.975 = t0.975 = t0.975 = t0.975 =
E.L. Relative Accuracy = EMRA EMRA
a For steam generators;b Average of three samples;
c Make sure that RM and M data are on a consistent basis either wet or dry.
40 CFR 60 Performance Specification 2 For SO2 and NOx Continuous Emission Monitoring Systems
4. Performance and Equipment Specifications
4.3 Relative accuracy. The RA of the CEMSS shall be no grater than 20 percent of the mean value of the RM test data in terms of the
units of the emission standard or 10 percent of the applicable standard, whichever is greater
For SO2 emission standards between 0.30 and 0.20 lbs./MMBtu use 15 Percent of the applicable standard;
For SO2 emission standards below 0.20 lbs./MMBtu use 20 Percent of the emission standard;
40 CFR 60 Performance Specification 3 For O2 and CO2 Continuous Emission Monitoring Systems
12. Calculate the arithmetic difference between the RM and the CEMSS output for each run. The average of the nine (of more) data sets constitute the RA.
13.2 Relative accuracy. The RA of the CEMSS must be no grater than 1 percent O2 or CO2.
40 CFR 60 Performance Specification 6 For Continuous Emission Rate Monitoring Systems (CERMS)
13.2 CERMS Relative Accuracy. The RA of the CERMS shall be no greater than 20 percent of the mean value of the RM's test data in terms of the nits of the emission
standard, or 10 percent of the applicable standard, which err is greater.
Up dated January 17, 2006
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Kennecott Acid Plant Tailgas SME011b RATA RM 1, 2, 3A, 6C, & 19 (Tested 6-18-2024)
Division of Air Quality
Relative Accuracy Test Audit of
Kennecott Copper
Tail Gas
CO Analyzer:Serial No.:
Acquisition System:
Acquisition System: Serial No.:
Equivalent Emission Limit:
Date CO Dry CO Dry CO
6/18/2024 RM CEMS Diff RM CEMS Diff RM CEMS Diff
Run#Start
Time
End
Time ppm lbs./MMBtu lbs./hr.
1 12:40 13:01
2 13:01 13:22
3 13:22 13:43
4 14:08 14:29
5 14:21 14:42
6 14:42 15:03
7 15:20 15:41
8 15:41 16:02
9 16:02 16:23
10
11
12
13
14
15
16
Average =
Sd Standard Deviation =
Confidence Coefficient =
RA - Relative Accuracy =
n = 0 0 0
t0.975 =
E.L. Relative Accuracy =
a For steam generators;b Average of three samples;
c Make sure that RM and M data are on a consistent basis either wet or dry.
40 CFR 60 Performance Specification 4 For Carbon Monoxide (CO) Continuous Emission Monitoring Systems
applicable emission standard is used to calculate RA.
40 CFR 60 Performance Specification 4A For Carbon Monoxide (CO) Continuous Emission Monitoring Systems
13.2 Relative accuracy. The RA of the CEMSS must be no greater than 10 percent when the average RM value is used to calculate RA, 5 percent when the applicable
emission standard is used to calculate RA, or within 5 ppmv when the RA is calculated as the absolute average difference between the RM and CEMSS plus the 2.5
percent confidence coefficient.
40 CFR 60 Performance Specification 6 For Continuous Emission Rate Monitoring Systems (CERMS)
13.2 CERMS Relative Accuracy. The RA of the CERMS shall be no greater than 20 percent of the mean value of the RM's test data in terms of the nits of the emission
standard, or 10 percent of the applicable standard, which err is greater.
Up dated January 17, 2006
13.2 Relative accuracy. The RA of the CEMSS must be no grater than 10 percent when the average of the RM value is used to calculate RA or 5 percent when the
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Kennecott Acid Plant Tailgas SME011b RATA RM 1, 2, 3A, 6C, & 19 (Tested 6-18-2024)
Division of Air Quality
NSPS Relative Accuracy Performance Specification Test - CEMS Certification
Kennecott Copper
Tail Gas
Average Emission
Dry SO2 NOX CO
lbs./MMBtu Average % concentration
lbs./hr.CO2 O2
ppm or % 39.29
Run 1 Enter O2 or CO2
Dry SO2 NOX CO CO2 O2
Atomic Weight 64 46 28
lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d))
lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d)
lbs./cu.ft 5.222E-06
lbs./hr.
ppm or %31.42
Run 2
Dry SO2 NOX CO CO2 O2
Atomic Weight 64 46 28
lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d))
lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d)
lbs./cu.ft 5.755E-06
lbs./hr.
ppm or %34.63 Raw Value
Run 3
Dry SO2 NOX CO CO2 O2
Atomic Weight 64 46 28
lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d))
lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d)
lbs./cu.ft 5.917E-06
lbs./hr.
ppm or %35.61 Raw Value
Run 4
Dry SO2 NOX CO CO2 O2
Atomic Weight 64 46 28
lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d))
lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d)
lbs./cu.ft 6.990E-06
lbs./hr.
ppm or %42.06 Raw Value
Run 5
Dry SO2 NOX CO CO2 O2
Atomic Weight 64 46 28
lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d))
lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d)
lbs./cu.ft 6.652E-06
lbs./hr.
ppm or %40.03 Raw Value
Corrected For Cal. Drift
Raw Value
Corrected For Cal. Drift
Corrected For Cal. Drift
Corrected For Cal. Drift
Corrected For Cal. Drift
O2
CO2
Clear
lbs./MMBTU
Kennecott Acid Plant Tailgas SME011b RATA RM 1, 2, 3A, 6C, & 19 (Tested 6-18-2024)
Division of Air Quality
NSPS Relative Accuracy Performance Specification Test - CEMS Certification
Kennecott Copper
Tail Gas
O2
CO2
Clear
lbs./MMBTU
Run 6
Dry SO2 NOX CO CO2 O2
Atomic Weight 64 46 28
lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d))
lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d)
lbs./cu.ft 6.241E-06
lbs./hr.
ppm or %37.55 Raw Value
Run 7
Dry SO2 NOX CO CO2 O2
Atomic Weight 64 46 28
lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d))
lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d)
lbs./cu.ft 7.016E-06
lbs./hr.
ppm or %42.22 Raw Value
Run 8
Dry SO2 NOX CO CO2 O2
Atomic Weight 64 46 28
lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d))
lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d)
lbs./cu.ft 7.735E-06
lbs./hr.
ppm or %46.54 Raw Value
Run 9
Dry SO2 NOX CO CO2 O2
Atomic Weight 64 46 28
lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d))
lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d)
lbs./cu.ft 7.243E-06
lbs./hr.
ppm or %43.58 Raw Value
Run 10
Dry SO2 NOX CO CO2 O2
Atomic Weight 64 46 28
lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d))
lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d)
lbs./cu.ft
lbs./hr.
ppm or %Raw Value
Run 11
Dry SO2 NOX CO CO2 O2
Atomic Weight 64 46 28
lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d))
lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d)
lbs./cu.ft
lbs./hr.
ppm or %Raw Value
Corrected For Cal. Drift
Corrected For Cal. Drift
Corrected For Cal. Drift
Corrected For Cal. Drift
Corrected For Cal. Drift
Corrected For Cal. Drift
Kennecott Acid Plant Tailgas SME011b RATA RM 1, 2, 3A, 6C, & 19 (Tested 6-18-2024)
Calibration Error Test
Test Date O2
CS - Cal. Span
Units %
Cylinder No. Expiration
Date Cal. Gas CV- Certified
Concentration
CDir or CS -
Measured
Concentration
Difference
ACE Eq. 7E-1
Analyzer Cal.
Error
Status
Low-level
Mid-level
High-level
% of Span Sec. 8.2.1 Cal Gas Verification
0 to 20% of CS - Cal. Span Low-Level
40 to 60% of Cal. Span Mid-level
100% of Cal. Span High-level
Test Date CO2
CS - Cal. Span
Units %
Cylinder
No.
Expiration
Date Cal. Gas CV- Certified
Concentration
CDir or CS -
Measured
Concentration
Difference
ACE Eq. 7E-1
Analyzer Cal.
Error
Status
Low-level
Mid-level
High-level
% of Span Sec. 8.2.1 Cal Gas Verification
0 to 20% of Cal. Span Low-Level
40 to 60% of Cal. Span Mid-level
100% of Cal. Span High-level
Test Date June 18, 2024 SO2
CS - Cal. Span 90.00
Units ppm
Cylinder
No.
Expiration
Date Cal. Gas CV- Certified
Concentration
CDir or CS -
Measured
Concentration
Difference
ACE Eq. 7E-1
Analyzer Cal.
Error
Status
Low-level 0.00 0.26 0.26 0.289% Passed Cal.
Mid-level 50.00 49.28 0.72 0.800% Passed Cal.
High-level 90.00 89.57 0.43 0.478% Passed Cal.
% of Span Sec. 8.2.1 Cal Gas Verification
0 to 20% of Cal. Span Low-Level 0.00%
40 to 60% of Cal. Span Mid-level 55.56%
100% of Cal. Span High-level 100.00%
Test Date NOx
CS - Cal. Span
Units ppm
Cylinder
No.
Expiration
Date Cal. Gas CV- Certified
Concentration
CDir or CS -
Measured
Concentration
Difference
ACE Eq. 7E-1
Analyzer Cal.
Error
Status
Low-level
Mid-level
High-level
% of Span Sec. 8.2.1 Cal Gas Verification
0 to 20% of Cal. Span Low-Level
40 to 60% of Cal. Span Mid-level
100% of Cal. Span High-level
Test Date CO
CS - Cal. Span
Units ppm
Cylinder
No.
Expiration
Date Cal. Gas CV- Certified
Concentration
CDir or CS -
Measured
Concentration
Difference
ACE Eq. 7E-1
Analyzer Cal.
Error
Status
Low-level
Mid-level
High-level
% of Span Sec. 8.2.1 Cal Gas Verification
0 to 20% of Cal. Span Low-Level
40 to 60% of Cal. Span Mid-level
100% of Cal. Span High-level