Loading...
HomeMy WebLinkAboutDAQ-2024-0118871 DAQC-1181-24 Site ID 10008 (B4) MEMORANDUM TO: STACK TEST FILE – NUCOR STEEL – Utah THROUGH: Harold Burge, Major Source Compliance Section Manager FROM: Paul Morris, Environmental Scientist DATE: November 20, 2024 SUBJECT: Contact: Doug Jones – 435-458-2415 Location: West Cemetery Road, Plymouth, Box Elder County, Utah Tester: Alliance Technical Group Sources: Reheat Furnace #1 FRS ID #: UT0000004900300002 Permit: Title V operating permit #300002004 dated May 23, 2022 Date of Last Revision: September 12, 2024 Action Code: TR Subject: Review of Stack Test Report dated November 5, 2024 On November 13, 2024, the Utah Division of Air Quality (DAQ) received a stack test report for the Reheat Furnace (RH) #1 located at Nucor Steel’s steel mill in Plymouth, Utah. Testing was performed on September 26, 2024, to demonstrate compliance with the NOX emission limits found in Permit Condition II.B.5.b. The DAQ-calculated test result is: Source Test Date RM/Pollutant DAQ Result Test Result Limit RH #1 9/26/2024 7E/NOX 14.3 lbs/hr 14.3 lbs/hr 15.0 lbs/hr DEVIATIONS: None noted. CONCLUSION: The submitted test reports appear to be acceptable. RECOMMENDATION: The NOX emissions appear to have been in compliance with the applicable limits at the time of testing. No further action is necessary. HPV: No. ATTACHMENTS: Nucor Steel stack test reports received November 13, 2024 DAQ generated excel test review spreadsheets 6 , 3 ].IIJEEFT BAR M'LL GROUP PTYMOUTH DIVlSION November 5,2024 Utah Division of Air Quality Bryce Bird - Executive Director 1950 West 150 North PO Box 144820 Salt Lake City, Utah 84114-4820 Re: 2024Reheat Furnace #1 Testing Dear Mr. Bird: Attached is a copy of the report for the compliance testing conducted at Nucor Steel - Utah for Billet Reheat Furnace #l as required by the Title V Operating Permit #300002004. If you have any questions please do not hesitate to contact our Environmental Department Manager, Doug Jones, at 435-458-2415. Based on information and belief formed after reasonable inquiry, the statements and information in the General Manager - Plymouth Bar Mill Division attachments DEPAT]TMENT OF ENVIIIONMENIAL OUALITY NOv 1 3 2024 DIVISION OF AIR OUALTTY document are true, accurate, and complete. PO BOX 1OO PLYMOUIH, UTAH 8433IJ PHONE 435 458 ]]OO FAX 4]5 45E 231]9 WWW,NSUTAH.COM DtTNIITMt.NT OF Allarrce Source Test Report Nucor Steel-Utah West Cemetery Road Plymouth, UT 84330 Source Tested: Reheat Furnace #l Test Date: September 26,2024 Project No. AST-2024-31 3 6-007 Prepared By Alliance Technical Group, LLC 3683 W 2270 S, Suite E West Valley City, UT 84120 ENVIHONMENIAL OUALTTY All6noe i-t. ollNlc)At Gnorit)Source Te$ Rqon Test Propram Summary Regulatory Information Permit Nos. Source Information Utah Department of Environmental Quality, Division of Air Quality Approval Order DAQE- AN100080048-21-20Issued on October 28,2021; Title V Permit No. 300002004 revised May 23, 2022; and Utah State Implementation Plan (Sections IX.H.l l&12) Source Name Reheat Fumace #l Contact Information Source ID Unit #13 Target Parameter NOx Test Location Nucor Steel-Utah West Cemetery Rd. Plymouth, Utah Doug Jones P.O. Box 100 Plymouth, I..If 84330-0 I 00 Doug.Jones@nucor.com (43s) 4s8-24ts Kyndal Bair P.O. Box 100 Plymouth, UT 84330 kyndal.bair@nucor.com (43s) 4s8-2300 Test Company Alliance Technical Group, LLC 3683 W 2270 S, Suite E West Valley City, Lrf 84120 Project Manager Chartes Horton charles.horton@alliancetg.com (3s2) 663-7s68 Field Team Leader Alan Jensen alan j ensen@alliancetg.com (847)220-3949 QA/QC Manager Kathleen Shonk katie. shonk@lliancetg.com (812) 4s2478s Report Coordinator Michael Meadows michael.meadows@alliancetg.com Report Reviewer Rich Trzupek rich.rzupek@alliancetg. com (847)809-78il Nucor - Plymouth, UT 2 of5l AST-2024-3 I 3 6-007 Page i pulhrrce Source Test Report Certif catio n St ate me ntI t o lll.lIclAt GIl()l,l l) Alliance Technical Group, LLC (Alliance) has completed the source testing as described in this report. Results apply only to the source(s) tested and operating condition(s) for the specific test date(s) and time(s) identified within this report. All results are intended to be considered in their entirety, and Alliance is not responsible for use of less than the complete test report without written consent. This report shall not be reproduced in full or in part without written approval from the customer. To the best of my knowledge and abilities, all information, facts, and test data are correct. Data presented in this report has been checked for completeness and is accurate, error-free, and legible. Onsite testing was conducted in accordance with approved internal Standard Operating Procedures. Any deviations or problems are detailed in the relevant sections in the test report. This report is only considered valid once an authorized representative of Alliance has signed in the space provided below; any other version is considered draft. This document was prepared in portable document format (.pdf) and contains pages as identified in the bottom footer of this document. tl 'i:."/-/,//./- t013012024 Charles Horton, QSTI Alliance Technical Group, LLC Date Nucor - Plymouth, UT 3 of5l AST-2024-3 I 3 5-007 Page ii pJ/lArEe Itcill'll()Al GBOUT-'Source Tesl Reporl Table of Contents TABLE OF'CONTENTS LI Source and Control System Descriptions. ........... I-I 1.3 Site-Specific Test Plan &Notification................... ................... l-l 3.1 U.S. EPA Reference Test Methods 1 ar,d2 - Sampling/Traverse Points and Volumetric Flow Rate ........ 3-1 3.2 U.S. EPA Reference Test Method 3A - Oxygen/Carbon Dioxide......... ......... 3-1 3.3 U.S. EPA Reference Test Method 4 - Moisture Content......... ....................... 3-1 3.4 U.S. EPA Reference Test Method 7E - Nitrogen Oxides ......... 3-1 3.5 U.S. EPA Reference Test Method 205 - Gas Dilution System Certification. .......................3-2 3.6 Quality Assurance/Quality Conrol - U.S. EPA Reference Test Methods 3,A' and 7E................................3-2 LIST OT'TABLES APPEI\tDICES Appendix A Sample Calculations Appendix B Field Data Appendix C Quality Assurance/Quality Control Data Appendix D Process Operating/Control System Data Nucor - Plymouth, UT 4 of 5l AST-2024-3 r 3 6-007 Page iii 5 of5l pul6rpe Tt ()ilrJICAr (jfl(l(ltl Source Test Report Introduction 1.0 Introduction Alliance Technical Group, LLC (Alliance) was retained by Nucor Steel-Utah (Nucor) to conduct compliance testing at the Plymouth, Utah facility. Portions of the facility are subject to provisions of the Utah Department of Environmental quality, Division of Air Quality (UDAQ) Approval Order (AOP) DAQE-AN100080048-21-20; Title V Permit No.300002004; and the Utah State Implementation Plan (SIP) Sections X.H.ll and 12. Testing was conducted to determine the emission rate of niftogen oxides (NOx) at the exhaust of Reheat Fumace #l (R-F#l). 1.1 Source and Control System Descriptions The Reheat Furnace #2 is used to heat the steel billets prior to hot rolling them into marketable shapes. The fumace is equipped with natural gas fired boilers. 1.2 Project Team Personnel involved in this project are identified in the following table. Table 1-1: Project Team Nucor Personnel Kyndal Bair Alliance Personnel Alan Jensen Mitchell Manwaring 1.3 Site-Specific Test Plan & Notification Testing was conducted in accordance with the Site-Specific Test Plan (SSTP) submitted to UDAQ by Alliance on Jvne28,2024. Nucor - Plymouth, UT 6 of5l AST-2024-3 I 36-007 Page l-l Alt6rrcbTECHNICAL GROUP Swrce T*t Report Summan ofResulu 2.0 Summery of Results Alliance conducted compliance testing at the Nucor facility in Plymouth, Utah on September 26,2024, Testing consisted of determining the emission rate of NOx at the exhaust of RF#l. Table 2-l provides a summary of the ernission testing results with comparisons to the applicable UDAQ permit limit. Any difference between the summary of results listed in the following table and the detailed results contained in the appendices is due to rounding for presentation. Table 2-1: Summary of Results * Note: A product change during Run 3 ternporarily halted production, causing a one hour and fifty minute delay thirty nine minutes into the run. Six minutes after resuming, the facility experienced a 'cobble'production intemrption resulting in a thirty two minute delay. Testing resumed * 20:48 and was unintemrpted through the remainder of the run. Concenfation, ppmvd Emission Rate, lb/br Emission limit,lb/hr Percent of Limit, % 3l.9 14.3 15.0 95 30.9 t4.t 30.2 13.3 34.6 15.4 Nucor - Plymouth, UT 8 of5l AST-2024-3 136007 Page 2-1 9 ofSl Aftlpe Source Tesl Report Testing Methodologt 3.0 Testing Methodology The emission testing program was conducted in accordance with the test methods listed in Table 3-1. Method descriptions are provided below while quality assurance/quality control data is provided in Appendix C. Table 3-1: Source Testing Methodology Parameter U.S. EPA Reference Test Methods Notes/Remarks Volumetric Flow Rate t&2 Full Velocity Traverses Oxygen / Carbon Dioxide 3A Instrumental Analysis Moisture Content 4 Gravimetric Analysis Nitrogen Oxides 7E Instrumental Analysis Gas Dilution System Certification 205 3.1 U.S. EPA Reference Test Methods I and 2 - Sampling/Traverse Points and Volumetric Flow Rate The sampling location and number of traverse (sampling) points were selected in accordance with U.S. EPA Reference Test Method 1. To determine the minimum number of traverse points, the upstream and downstream distances were equated into equivalent diameters and compared to Figure l -2 in U.S. EPA Reference Test Method l. Full velocity traverses were conducted in accordance with U.S. EPA Reference Test Method 2 to determine the average stack gas velocity pressure, static pressure and temperafure. The velocity and static pressure measurement system consisted of a pitot tube and inclined manometer. The stack gas temperature was measured with a K-type thermocouple and pyrometer. Stack gas velocity pressure and temperature readings were recorded during each test run. The data collected was utilized to calculate the volumetric flow rate in accordance with U.S. EPA Reference Test Method 2. 3.2 U.S. EPA Reference Test Method 3A - Oxygen/Carbon Dioxide The oxygen (Oz) and carbon dioxide (CO2) testing was conducted in accordance with U.S. EPA Reference Test Method 3A. Data was collected online and reported in one-minute averages. The sampling system consisted of a stainless-steel probe, Teflon sample line(s), gas conditioning system and the identified gas analyzer. The gas conditioning system was a non-contact condenser used to remove moisture from the stack gas. If an unheated Teflon sample line was used, then a portable non-contact condenser was placed in the system directly after the probe. Otherwise, a heated Teflon sample line was used. The quality control measures are described in Section 3.6. 3.3 U.S. EPA Reference Test Method 4 - Moisture Content The stack gas moisture content (BWS) was determined in accordance with U.S. EPA Reference Test Method 4. The gas conditioning train consisted of a series of chilled impingers. Prior to testing, each impinger was filled with a known quantity of water or silica gel. Each impinger was analyzed gravimetrically before and after each test run on the same balance to determine the amount of moisture condensed. 3.4 U.S. EPA Reference Test Method 7E - Nitrogen Oxides The nitrogen oxides (NOx) testing was conducted in accordance with U.S. EPA Reference Test Method 7E. Data was collected online and reported in one-minute averages. The sampling system consisted of a stainless-steel probe, Nucor - Plymouth, UT l0 of 5l AST-2024-3 I 36-007 Page 3-l pill6rrpE) II rtllt.JtCn I Gn()|t)Source Test Reporl Testing Methodologt Teflon sample line(s), gas conditioning system and the identihed gas analyzer. The gas conditioning system was a non-contact condenser used to remove moisture from the stack gas. If an unheated Teflon sample line was used, then a portable non-contact condenser was placed in the system directly after the probe. Otherwise, a heated Teflon sample line was used. The quality control measures are described in Section 3.6. 3.5 U.S. EPA Reference Test Method 205 - Gas Dilution System Certification A calibration gas dilution system field check was conducted in accordance with U.S. EPA Reference Method 205. Multiple dilution rates and total gas flow rates were utilized to force the dilution system to perform two dilutions on each mass flow confioller. The diluted calibration gases were sent directly to the analyzer, and the analyzer response recorded in an elecfionic field data sheet. The analyzer response agreed within 2o/o of the actual diluted gas concentration. A second Protocol I calibration gas, with a cylinder concentration within l0% of one of the gas divider settings described above, was infioduced directly to the analyzer, and the analyzer response recorded in an electronic field data sheet. The cylinder concentration and the analyzer response agreed vvithirr 2Yo. These steps were repeated three (3) times. Copies of the Method 205 data can be found in the Quality Assurance/Quality Control Appendix. 3.6 Quality Assurance/Quality Control - U.S. EPA Reference Test Methods 34 and 7E Cylinder calibration gases used met EPA Protocol | (+l- 2%) standards. Copies of all calibration gas certificates can be found in the Quality Asswance/Quality Control Appendix. Low Level gas was introduced directly to the analyzer. After adjusting the analyzer to the Low-Level gas concentration and once the analyzer reading was stable, the analyzer value was recorded. This process was repeated for the High-Level gas. For the Calibration Error Test, Low, Mid, and High-Level calibration gases were sequentially introduced directly to the analyzer. All values were within 2.0 percent of the Calibration Span or 0.5 ppmv lo/o absolute difference. High or Mid-Level gas (whichever was closer to the stack gas concentration) was introduced at the probe and the time required for the analyzer reading to reach 95 percent or 0.5 ppmv/% (whichever was less restrictive) of the gas concentration was recorded. The analyzer reading was observed until it reached a stable value, and this value was recorded. Next, Low-Level gas was introduced at the probe and the time required for the analyzer reading to decrease to a value within 5.0 percent or 0.5 ppmv/% (whichever was less restrictive) was recorded. If the Low- Level gas was zero gas, the response was 0.5 ppmvlYo or 5.0 percent of the upscale gas concentration (whichever was less reskictive). The analyzer reading was observed until it reached a stable value, and this value was recorded. The measurement system response time and initial system bias were determined from these data. The System Bias was within 5.0 percent of the Calibration Span or 0.5 ppmv/% absolute difference. High or Mid-Level gas (whichever was closer to the stack gas concentration) was introduced at the probe. After the analyzer response was stable, the value was recorded. Next, Low-Level gas was introduced at the probe, and the analyzer value recorded once it reached a stable response. The System Bias was within 5.0 percent of the Calibration Span or 0.5 ppmv/%o absolute difference or the data was invalidated, and the Calibration Error Test and System Bias were repeated. Drift between pre- and post-run System Bias was within 3 percent of the Calibration Span or 0.5 ppmvl%o absolute difference. If the drift exceeded 3 percent or 0.5 ppmv/%, the Calibration Error Test and System Bias were repeated. AST-2024-3 136-007 Nucor - Plymouth, UT I I of 5l Page 3-2 pill6rrpE) TIOllt{tCAi i; r'1 r) tj [)Source Test Report Testins Methodolosy To determine the number of sampling points, a gas stratification check was conducted prior to initiating testing. The pollutant concentrations were measured at three points (16.7, 50.0 and 83.3 percent of the measurement line). Each haverse point was sampled for a minimum of twice the system response time. The pollutant concentration at each kaverse point did not differ more than 5 percent or 0.5 ppmv/0.3% (whichever was less restrictive) of the average pollutant concentration, therefore, single point sampling was conducted during the test runs. Copies of stratification check data can be found in the Quality Assurance/Quality Control Appendix. An NOz - NO converter check was performed on the analyzer at the completion of testing. An approximately 50 ppm nitrogen dioxide cylinder gas was introduced directly to the NOx analyzer and the instrument response was recorded in an electronic data sheet. The instrument response was within +/- l0 percent of the cylinder concentration. A Data Acquisition System with battery backup was used to record the instrument response in one (l) minute averages. The data was continuously stored as a *.CSV file in Excel format on the hard drive of a computer. At the completion of testing, the data was also saved to the Alliance server. All data was reviewed by the Field Team Leader before leaving the facility. Once arriving at Alliance's office, all written and electronic data was relinquished to the report coordinator and then a final review was performed by the Project Manager. Nucor - Plymouth, UT l2 of5l AST-2024-3 I 36-007 Page 3-3 l3 of5l A/l6r1rcc)Tf ()t1 Nton L (.iR()tiP Location: Nucor Steel - Plvmouth. UT Source: Reheat Furnace #l Project No.: A'5T-2024-3136 Run No. /'lVlethod Run I / Method 3A Or - Outlet Concentration (Co), Yo drl co= (co6,_cs)x (dFqr) where, Cou.A=ayerage analyzervalue duringtest, % dry Co 0.2 = average ofpretest & posttest zero responses, 0/o dry CN!,{ I1.0 = actual concentration of calibration gas,yo &y CM 10.9 = average ofpretest & posttest calibration responses, o/o dry Co, 12.8 : Oz ConcenEation, o/o dry 14 of5l plll6rrrcE) Tf(;IINICAL (}NOL]P Location: Nucor Steel - Plymoutb" UT Source: Reheat Furnace #l Project No.: AST-2024-3136 Run No. /Illethod Run I / Method 3A COr - Outlet Concentration (CcoJ, o/, ilrl cco= (cop.-ce)x ( dkJ) where, Cobs 4.9 = average analyzer value during test" % dry Co 0.0 = average ofpretest & posttest zero responses,o/o dry CMA 10.9 =actualconcentrationofcalibrationgas,Yodry CM I I .0 = average ofpretest & posttest calibration responses, yo dry Cco, 4.8 = COz Concentration,%o dry l5 of5l AliatpE) lli\ll, .'.t rl[],llll, Location: Nucor Steel - Plymouth, UT Source: Reheat Furnace #l Project No.: 45T-2024-3136 Run No. /Method Run 1 / Method 7E NOx - Outlet Concentration (CxoJ, ppmvd cNo": (co6,-c6)x (#.") where, 30.4Cob, co 0.0 : average analyzer value during test, ppmvd = average ofpretest & posttest zero responses, ppmvd CMA 50.0 : actual concentration of calibration gas, ppmvd CM 49.3 = average of pretest & posttest calibration responses, ppmvd CNo* 30.9 : NOx Concentration, ppmvd NOx - Outlet Emission Rate (ERno,), lb/hr L DD - C-",-MW-qt-60j:Ml1l(rr^- : - ---NUx 24.04 *;b x 1.0806 x453.592 !- where, CNo* MW 46.0055 30.9 : NOx - Outlet Concentration, ppmvd = NOx molecular weight, g/g-mole: stack gas volumetric flowrate at standard conditions, dscftn = lb/hr Qs 63,865 ERNo,t4.l l6 of5l pull6rr.leE) TET)IlNICAI Example Calculations (_l f i () Llt, IfldoD NEcor Stcl - Plmuth. LIT SoECG Rrb6t F!mc. #l RmNG I PmDtcr(t) VFR Mctcr Priluc CE),lL Eg AHpm = pb*m wbsq P\L- bmrctricpww, in. Hg AH__!1[-F6re difE@tid oforificc, in H2O P'..4-io'Hg Abelltc Strcl Gu Prouc (Pr), ln E3 Psps = pb+* wherc' hL= berccricprcom,ia.Hg Pg 0.30 - rtaticPre, ir. H2O Pr 25.46 = in. Hg Studrrd Mltcr Vdm (vBtd), drcf Vrotd=17.636xVmxPoxY rhqq Y 0.99t - Etr oGtic frctor v.-lElE6-= retcr wlrre, cf Pm 25 .51 = rbrclutc trrts pHrw, ia. Hg t.l]f[= rbstue Gta t@pc.turc,'R Vrotd 30.736 = &cf StrDd$d WctVduD oxnd), rcf ri.rC, Vwrtd= 0.(X7l6xVlc vk 72.5 = wight of HO collcto4 8 v*"d-........F=*f Mobtuc Fncdon (BW$rt), dlrululBr (tt6ndql rt [trttcd coldltloD) ,oesz-(ffi)BWSsat = - rhcrq PS Tr 709.9 = rtrck tctrpcfltuE, aF Pr -2l:- = .brclutc rtrck gu pruuc, ia- Hg BWSrt 1.000 -dimriolor Mobtuc Frrcdol (BWSI dluulodu VwstdBWS =(Vwstd * Vmstd)whcrq Vwrtd_!!]!- rtsdtd wet rclle, rcf vmtd 30.736 - ltu&rd trtEwltm, &cf BwS 0.100 -dimimbrs Motturc trn.do! (BWS), dlE uloddr BWS = BWSmsd unless BWSsat < BWSmsd Bwsnt I .000 = miutEr fretion (thoraicd at strEtcd cotrditi@) BWSmd 0.100 - mirtw fractior (rottd) BWS 0.100 Molcshr WdSLt (I,RY) (Md), lMb.mlc y6 = (0.,t4 x %COz) + (0.32 x VoO2) + (0.28(100- %COz - %O2)) rbrg cqg- ottoo dioxidc mmtratioa' % Q tZ.g - orygcn orcatrrtioo,'/o Md 29.28 = lb/lb rcl Tm l7 of5l FlaAI Example Calculations {-, li ( ) iJ Ir IcrdoD Nrcor Stcl - Pvmrth, UT Soucc Rrhcrt Fmcc fl ProJcc't No. AST-2024-3136 RuNo. I Puretcr(r) VFR Molcculrr Wclght (WEB (Mr), lbnb.Dle Ms = Md (1 - BWS) + 18.015 (BWS) whcr!, Md, 29-2t = ml*rdu wcight (DRY),lb/lb ml BWS__ 0.100 _= mfuturc frsction, dircNimlBs Ms 2E.16 = IbAb ml AvcnSc Vclelty (Vt), firEc = 85.49 x Cp x (A P 1/2) avg x Cp 0.t4 = pitot tubc c@fficicnl o at"E= svmge pr€/post test vclmity hcsd of stact gu, (in. Hzo)ra Tr -L!.lE:-= svmge pE/post icst absoluic stsct tctrp@hr, oR Ps 25.46 = 8bslute st8ck gB pH!w, in. Hg Mt__[!j-= mlcular rcight of stack gas,lb4b molVs 48.4 = fl/scc Arcngc Strck Gu Flow rt Strcl CoDdltlou (Qr), rcfu Qa=60xVsxAs xhcrq Vs 48.4 = stact ga rclocity, fl/se Ar-A;;-= coss-utimal re of strct, ft2 Q"__-Lg@_=*tu AvcrrSc Sttcl G$ now rt StrDdrrd Condlttou (Qr), rtrcfu Qsd= l7.636xQax(l -BWS)x whcrg Qs 184,E40 = 8veEge stscl ga flow st strck @nditioB, rctn BWS1[![= misluc firction, dircnsionlqs Pr -41L_ = rbmlutc stscL Sss prcssuc, in. Hg Tr -ll]8l = 8v@gc prr/poEt tcct sbrolutc stEat tcdpcEturc, "R Q1$![=dscftn Dry Gs MA.r CdlbntloD Chck (Yqr), pcrccrt Yqa = xhcrC' Y1!|!!-= *tcr coE*tiod frctor, dimsnsimlcss O 60 = M timc, min.vtA= total rctqvolw' dcf T-__13!L_= rbrclutc Etcr tcmFntus,'R All@ I .E24 = uificc rctcr calibmtiotr cocffcimt, in. H2O Pb L= barcrctric prc$uc, in. Hg AH avg 1.000 = avcngc pwre diffcmtial of cificc, in HrO Md 29.2t = rulculr wcight (DRY), lb/lb nol (A tI;'' ----Iffi- = &vcngc squsc rcot prcssw differcntial of orificc, (in. H2O)ra Yqa 0J =p€rcctrt Vs whEg E! Ts x 100 l8 of 5l 19 of5l Emissions CalculationsAI Ii Nucor Steel - Plymouth, UTLocation Source Project No. Reheat Fumace #l AST-2024-3t36 Run Number Runl Run2 Run3 Averaqe Date Start Time Stop Time 9t26t24 9/26t24 9t26t24 15:45 17:03 18: 19 16:49 I 8:02 2l :00 Input Data - Outlet Volumetric Flow Rate (Ml-4), dscfrn Qs 63,865 61,536 62,216 62,539 Calculated Data - Outlet Oz Concentration. % drv co. 12.76 12.52 I L5l 12.27 CO: Concentration, Yo drv cco, 4.84 4.97 5.48 5.10 NOx Concentration, ppmvd NOx Emission Rate, lb/hr CNo, ER*o' 30.9 t4.l 30.2 13.3 34.6 15.4 31.9 t4.3 20 of5l plltdrpe f L(;llNl()n L OR'.)l.)P Runl-RMData I^idotr: NMr Stlcl - PlmutL UT SouE: Rch6tFtlrc#l ProJct NG: AST-202+3 I 36 Dtlct 9fl6l24 TIr Utrlt (}r-(MGt COr-(MGt NOr-(MGt%dry %dry ppwd UmratrdR0Avcntc (Cr) Cd Gu ConGDErdo! (Cn) Prlt n Syn.E Z.ro RspoG P6tt6t SytcEz.ro Rcynu AYcrrgc Z.ro RsDou (Co) Prctst SyrtGD Crl Rspo[c P0tt6tS!trtGDCd RsDou Avcngc Cd RGrDu. (Cr) n.a l 1.00 0.16 0.14 0.15 10.94 t0.90 10.92 12.76 4.90 10.90 0.01 0.02 0.02 ll.0l I 1.02 I 1.02 4.84 30.45 50.@ 0.0E 0.01 0.05 48.70 49.92 49.26 30.89 l5:45 l5:46 l5:41 15;4E l5:49 l5:50 l5:5 I l5:52 l5:53 l5:54 l5:55 l5:56 l5:57 l5:5t l5:59 l6:00 l6:01 16i02 l6:03 l6:O4 l6:05 l6:06 l6:A 16:0t l6:09 l6:10 l6:l I l6:12 l6:13 l6:14 l6:15 l6: l6 l6t17 l6;lt l6: l9 l6:20 l6:21 l6:22 16t23 l6:U l6:25 16t26 l6:27 l6:28 l6:29 l6:30 l6:31 l6:37 l5:3t l6:39 l6:40 16:41 l6:42 l6:43 16i44 l6:45 l6:46 l6:47 l6:4t l5:49 t2.49 12.50 12.57 12.69 12.t0 t2.t9 t2.97 12.9 12.90 t2.u 12.79 12.80 12.t2 t2.t5 12.79 12.il 12.il t2.77 12.70 12.69 12.6 t2.& 12.il t2.fi 12.53 t2.52 12.50 12.57 t2.65 t2.il 12.6r t2.79 t2.E6 t2.u 12.77 12.67 12.69 t2.63 t2.57 t2.v t2.49 12.36 12.39 12.43 12.44 12.53 t2.fi t2.52 t2.55 12.55 12.47 t2.43 t2.45 12.47 12.51 12.50 12.51 t2.59 12.72 t2.n 4.99 4.99 4.94 4.t6 4.80 4.73 4.67 4.70 4.74 4.71 4.t3 4.80 4.t0 4.1t 4.81 4.19 4.79 4.t2 4.EE 4.t7 4.E9 4.90 4.93 4.92 4.97 4.9t 5.00 4.93 4.90 4.9r 4.93 4.81 4.19 4.79 4.t5 4.t9 4.t9 4.92 4.96 4.97 5.02 5.08 5.05 5.03 5.02 4.96 4.93 4.97 4.96 4.96 5.01 5.03 5.02 5.00 4.91 5.00 4.97 4.91 4.E6 4.U 32.U 31.t3 31.69 31.50 30.13 29.t5 29.05 29.49 30.36 30.y 3t.2t 30.77 29.t0 30.74 30.50 30.79 30.69 30.1t 30.71 3r.05 30.9t 30.33 30.06 30.25 r0.41 30.51 30.2t 29.9t 29.86 29.4 29.47 2t.80 2t.43 29.23 2t.96 29.06 2t.91 29.U 30.02 29.t5 30.12 30.35 30.33 30.t2 31.52 31.33 3 t.07 30.E8 30.72 31. l0 3 t.07 31.61 31.6t 31.39 3 1.20 31.03 31.3t 3 1.34 30.64 30.o7 2l of5l () fl () rJ n Run2-RMData Icrdon: Souccl ProJcct No.: Dttc: Tlr Uilt t2.39 5.05 Or - Osdct '/.dry r 1.00 0.14 0.14 0.14 10.90 10.91 t0.9t 12.83 12.72 12.66 t2.& 12.57 12.5t 12.54 t2.49 12.4 12.44 t2.43 t2.43 t2.36 12.29 12.28 t2.36 t2.37 12.37 12.36 t2.35 12.36 t2.33 t2.32 r2.35 t2.39 t2.v t2.3t t2.r2 t2.35 t2.v t2.33 t2.16 t2.3't t2.15 t2.36 12.3E t2.35 12.34 t2.34 t2.31 t2.32 12.35 t2.32 t2.36 t2.45 t2.55 12.3E t2.14 t2.29 12.38 t2.32 t2.35 t2.35 12.30 12.12 t2.33 12.30 t2.3t t2.44 t2.52 COr-Oldcr NOr-Mct%dty pprydValid Valid Uncorcctcd Ru AvcnSc (C.L) Crl Grt CoecffrdoD (CH^) Prctctt SyrtcD Zcro RspoEr Porttcrt SyrtcE Zcro RBpoDE Avcrrgc Z.ro R.rpm (Co) Prctlrt SyttcE Crl RBpoBG Porttart SyrtlE Crl Rrryouc Avrrr8r Cd Rrrpou (CrJ l7:03 17:04 l7:05 l7:06 l7:07 l7:08 17:09 l?: l0 l7:l I l7:12 l7:13 l7:14 l7:15 17:16 LTtL'l l7:18 17:19 17:20 17:21 17:22 17t23 11:24 17:25 17i26 11:27 17t2t l'l:29 l7:30 l7:31 l7:32 l'l:33 l7:34 l7:35 17:36 17:37 I 7:38 l7:39 l7:40 l7:41 l'1i42 17i43 l'l:44 l7:45 11:46 l7t4'7 l7:48 l7:49 17:50 l7:51 17:52 17:53 l7:54 l7:55 17:56 l7:57 l7:58 l'1159 l8:00 I E:01 lE:02 10.90 0.02 0.01 0.02 I 1.02 I r.0t r 1.05 4.19 4.88 4.89 4.93 4.94 4.95 4.97 5.00 5.01 5.03 5.03 5.03 5.09 5.1 t 5.1 I 5.06 5.06 5.05 5.0't 5.0t 5.0t 5.07 5.10 5.08 5.05 5.09 5.10 5.0E 5.05 5.07 5.09 5.06 5.06 5.07 5.06 5.06 5.07 5.08 5.08 5.09 5.1 I 5.07 5.09 5.07 5.00 4.95 5.O7 5.09 5. l0 5.07 5. l0 5.07 5.08 5.1 I 5.1 t 5.09 5.08 5.10 5.01 4.97 50.00 0.0r 0.0t 0.0r 49.E2 49.16 49.19 29.73 29.9t 29.97 30.02 30.06 30.30 30.39 30.33 30.23 30.1 3 30.25 29.99 29.92 29.95 30.22 30.55 30.62 30.66 30.26 30.09 30.11 30.29 30.34 29.98 29.95 30.39 30.24 29;t5 29.6 29.93 30.30 29.74 29.56 29.9 29.n 30.13 30.17 29.88 29.95 ,0.r7 30.61 30.23 30. l9 30.u 29.9E 29.8t 30.42 30.21 ,0.52 30.09 30.51 30.36 30.05 30.34 30.14 30.05 29.95 29.U 29.94 2t.Et 22 of 5l pllt6rpe l'EOit Ntc; n L GH()uP Run3-RMData IdrdoD:@SE!:!!E SoEcc: RrhBtFtIrc#l Projct N0:AST-2024-3 136 Drtct 9t26f4 TIB UDlt It:19 It:20 l8:21 It:22 It:23 It:24 l8:25 It:26 l8:21 l8:28 l8:29 l8:30 It:3 I It:32 It:33 It:34 l8:35 l8:36 It:37 It:3t It:39 It;40 It:41 It:42 It:43 It:,14 It:45 I t:,16 It:47 l8:48 It:49 l8:50 18:51 1t:52 It:53 It:54 l8:55 It:56 It:57 It:5t 20:10 20:l I 20:12 20:13 20:14 20:15 20:16 20:4E 20149 20:50 20:51 20:52 20:53 20:54 20:55 20:56 20i57 20:5t 20:59 2l:00 0.14 0.r6 0.15 10.9t to.c2 10.y2 5.59 10.90 0.01 0.04 0.03 I l.0t l1.09 4.9 5.00 5.08 5.04 5.07 5.07 5.05 5.09 5.O7 5.08 5.0t 5.09 5.04 5.01 4.n 4.97 4.96 4.96 4.97 4.98 5.04 5.06 s.09 5.00 5.02 5.06 5.06 5.08 5.06 5.04 5.07 5.07 5.0t 5.06 5.06 5.0t 5.t I 5.0t 5.03 4.74 s.93 6.05 6.lt 6.2E 6.4t 6.59 6.12 7.30 7.0t 6.m 6.75 6.72 6.62 6.& 6.6t 6.7t 6.E6 6.9E 't.u 't.t6 t429 50.00 0.01 0.02 0.02 49;t6 49.6 49.61 34.s6 31.15 !1.27 3t.50 3t.2E 31.59 3l.96 31.57 rt.26 31.52 3t.u 31.03 30.il 3 1.54 31.45 30.18 29.t6 30.05 29.93 29.v 30.11 30.90 30.99 30.t4 30.30 29.95 29.81 30.19 30.06 30.t2 30.u 30,0E 29.92 30.05 30.15 29.9r 29.76 30.13 30.49 31.5t 30.63 38.00 37.t! ,7.99 38.00 39.06 3t.t0 39.27 5t.26 45.05 42.4t 41.74 4l.ll N.2t 41.49 41.57 4.20 43.09 4r.47 44.t0 46.11 Or-(mct CG-(MGa NOx-Oudcl '/tdr! %dry ppwd UmrBtrdRu Avcngc (C.L) Crl G$ Com.ntrrdoD (Cu) PrGt rt S)!t.E Z.m R6p0r. P6tt6t Syrtcn Z.n R6poE Av.r{c z.rc Bspos (Co) Prctcrt Syttcm Cd R6po[c Porttat Sy*cm Crl RBpouc Av.nic Cd Rspoe (Cx) t2.49 12.4t 12.y t2,37 t2.y t2.36 t2.36 t2.31 t2.y t2.30 t2.31 t2.v t2.35 t2.4t t2.53 12.53 t2.54 12.54 12.55 12.51 12.4 12.3t t2.33 12.45 t2.4 t2.37 t2.37 t2.y 12.3t t2.42 12.31 t2.37 t2.35 t2.3E t2.39 t2.3s 12.31 t2.r2 t2.39 l2.Et 10.59 10.40 t0.u 10.10 9.90 9.6'l 9.43 E.47 t.t4 9.07 9.2t 9.33 9.46 9.46 9.43 9.25 9.19 t.99 8.t9 8.77 23 of 5l AI F'TA Method L Data li :l l{ Ifirdor Nrer Stel - nyu SomG nahcrt lrruc ,l Prcl.ct No. ASr-202+3136 D.L 09n$A Dud OrLildoE: Vcnial Ds D6Er Circulr Dltue lho6 F.r Will lo Odld. ot Pod: I I 3 .00 h Nlppl. laodb: 5.00 h Dcp6ofDrd: 10t.00 L Cru Sedord An. ollrcctr 53.52 ftr No. of Td Potu: 2 NEDb6 of R..dlntt D.r Polii: I DlrLe A: 9.0 n Dlfitra A Dld Dho.t.rr: I .0 (Dd b. > 09 obum a:----t;-n Dl.tu B D6 Dt E.tcr,t 3.0 (Dal b.> 2) Mlntb@ N@bcr of Trrvrda Polnt: 15 A.bl N@b.r otTnv.ru Pold: 16 M.umr 0dthl tod D.n1,ffiillEdf- RdLfrr ontthl rnd Drk|, NEgn6n4 LOCATTON OF TRAVERITE FOINTS Nu,,, oIM pola ot.til.te I 3 1 r 6 1 t 9 l0 ll 1 I 0 tn tt t2 'P.rcat o[tbct dlMcbt Irun lEid. wU b tMd. potat Tnvana Pota '/. ol Irr4td Dl6B.ftob odld. ofd I 3 1 5 6 7 t 9 l0 ll t2 ,.2 10.5 19.4 32.3 67.1 t0.6 89.5 :' 3.44 1 t.34 20.95 34.tt 73.12 t7.05 96.66,:" t 7lt5 t6 5/16 25 t5/16 39 7n 7E llt 92 1t16 lot I ln6 t*,'" Sek Di.gnm A-9tr B- 27fr. DcFhofDd= l0tir CiltSdtimlk Down,leam Dlnurb.ne aaaoaaaa Upstrarfr Dliurbance 24 of 5l Cyclonic Flow Check Tf ()til.lt( n L (tili)llP Location Nucor Steel - Plymouth, UT Source Reheat Furnace #1 ProJect No. A5T-2024-3136 D*e 9126124 Sample Polnt Angle (AP=0) I 2 3 4 5 6 7 8 9 10 1l t2 l3 l4 l5 l6 Average 4.5 25 of5l Fra I AI tl (:il1)rr Locrtiotr Nucor Steel - Plymouth. UT Field Data Method 2Data Source Reheat Furnace #l Project No. AST-2024-3136 I 9126124 VALID I 5:50 l6:00 Pass 2 9t26t24 VALID 17:15 17:25 Pass 3 9t26t24 VALID l8:23 l8:33 Pass AI 2 3 4 5 6 7 t BI 2 3 4 5 6 7 E 0.20 0.22 0.29 0.37 0.39 0.33 0.35 0. l5 0.23 0.28 0.36 0.40 0.34 0.30 0.20 0.15 708 708 709 710 7to 7tt 7t2 712 709 709 709 7t0 710 7t0 7t0 7tt 0.20 0.24 0.29 0.34 0.40 0.29 0.20 0.1 8 0.20 0.27 0.32 0.39 0.30 0.24 0.19 0.16 709 709 709 710 710 710 7tt 712 7t0 709 7t0 7tt 7ll 7t2 713 7t2 0.r9 0.23 0.27 0.3s 0.38 0.36 0.?l 0.17 0.24 0.28 0.32 0.40 0.33 0.25 o.2t 0.18 7t0 ?10 7tt 7tt 7tt 7tl 7tl 7t0 7t0 7t0 7tt 710 7t0 7lt 7t2 7tl Squ.re Root of AP, (ln. WC)rn (AP)t" Average AP, ln. WC (AP) Pltot Tube Coefftclent (Cp) Barometric Pressure, ln, Hg (Pb) Statlc Pressure, in, WC (Pg) Stack Pressure, ln. Hg (Ps) Averege Tempersture, oF (rg) Average Tempenture, "R CIO MeasuredMoistureFrsction @WSmsd) Moisture Fraction @ Saturatlon @WSsat) Moisture Fractlon (BWS) O2Concentratlon,7o (O2) CO2 Concentration, To (CO2) Molecular Weight, lbflb-mole (dry) (Md) MolecularWelght,lbilb-mole(wet) (Mr) Velocity, fUsec (Vs) VFR st strck conditions, rcfm (Qa) VFR et strndrrd conditions, scIL (Qsw) VFR rt rtrndard conditions, scfm (Qsw) VFR rt st ndrrd conditions. dscfm 0.528 0.29 0.840 25.44 0.30 25.46 709.9 I 169.5 0.1 00 1.000 0.100 12.76 4.84 29.28 28.t6 48.4 I 84,840 4,258, l 86 70,970 0.508 0.26 0.840 25.44 0.28 25.46 710.5 n70.2 0.099 1.000 0.099 12.52 4.97 29.30 28.1 8 46.6 t77,897 4,095,8 l 3 68,264 0.518 0.27 0.840 25.M 0.29 25.46 710.6 I 170.3 0.1 07 1.000 0.1 07 I l.5l 5.48 29.34 28.1 3 47.5 l8l,494 4, l 78,306 69,638 0.518 0.27 0.840 25.44 0.29 25.46 710.3 l 170.0 0.1 02 1.000 0.1 02 12.3 5.1 29.3t 28.16 47.5 I 81,41 I 4,t77,435 69,624 62.539 26 of5l FTA lo No. )d. lhtu imTlD. tDd Th. fu Th., d (0) lld* ID I 9t26t24 VALID l5:45 l6:,19 60 9D6n4 VALID l7:01 It:02 60 M5-9 3 9D6n4 VALTD l8:19 2l:00 60 M5-9 {&r Corrt do! F6r (Y) )ruc C.IbntbD V.h. (AH @) {u V*!rq h Et 0.98 t.824 3 0.002 0.99t tu 3 0.m2 0.998 t.t24 3 nml {rbt Volor, ll3 0 s t0 r! 20 ,s 3o 35 a0 45 50 55 60 1...1 M.6r Vdnm nl 935.444 938.440 94r.5r5 944.510 947.605 950.665 953.&0 956.670 959.740 962.7N 965.735 96t.695 97 1.634 9?1.t06 n4.165 977.715 9t0.$5 9t3.il0 916.800 9E9.795 992.7t0 995.765 99t.760 1001.750 1004.715 1007.759 t.003 10.9t5 14.000 17.0r0 19.970 n.985 26.005 29.0r0 32.020 35.035 3t.050 4 1.040 44.029 16.m5 f.q.ffiq 0 5 t0 l5 20 2' 30 t3 .0 a3 50 5! 60 P.mg. T.q.ntEg oF (ID) [.r{. T.q.ffiq 'R (fE) ,llDlEu l.q.ntEg oF M# 69 70 70 70 70 10 69 69 69 6t 68 68 6t 69 529 68 Prob.Illb,M lq.Edl 66 4t 41 47 47 4t 4t 49 49 50 5l 5t 53 50 47 Matar 6t 6t 6t 69 69 69 69 69 6t 66 6t 67 67 6t 528 67 69 Prob.rua6 lDp.8d 60 52 50 50 50 5l 5l s2 52 s3 54 5' 56 J] JO M.t r 70 70 70 7t 1t 72 72 72 1t 7t 7l 1t 531 70 12 Prcb.IIlt.r !m lEp. Ed @ 51 54 54 55 55 56 51 58 59 60 6l 63 5t 54u Broctdc PtdE lE gi 0t) }l.td Orlie P@ur, lE WC (AIO lldo Praoq b. Et (tu) thidrd M.hr Vol@ m (VEtd) 25.44 1.000 25.5t 25.44 1.000 25.51 25.44 t.0m 25.St lulydr Typ. lrybg.r l! Pn/P6t T6t, t hryl4c. 2, PrdP6i f 6t t lqlEg.r 3, hdPo.t f dt, i'ql!t.r,a, Pt./Pd ldt, f /olnD We ColL.t 4 EL (vL) lhrdrd Wd.. Volrq ff ry*to [obtu. Fr-do! M6u.d (BWS) iu MoLahr w.kha, rylbDh (dry) (MO mM Cdbh&D CH Vin fYdr) H20 H20 E rpty 725.0 701.2 641.6 941.1 775.t 7ll.t 645.1 949.4 50.t 9.9 3.7 8.1 H20 H20 E +ty Silio 115.t 7l t.l u5.3 949.4 il9.3 123.4 650.2 959.6 43.5 t2.3 4.9 t0.2 H20 H20 Brryty Silir 716.4 723.4 650.2 919.6 7t2.6 731.3 655.5 91t.1 46.2 13.9 5.3 r t.7 12.5 3.419 0.100 29.2a 0.5 10.9 3.344 0.099 29.30 -ol 11.1 3.636 0.t07 29.y AI Method 4 Data 27 of51 pJ/l6rrEE) Il r.lil.l alr',l r',[-i 11' Locatlon Nucor Steel - Plymouth, UT Source Reheat Furnoce #l Project No. AST-2024-3136 Parameter(s) VFR QA Data Dete Pitot ID Evldence of drmrqe? Evldence of mls-qliqnment? Calibradon or Renelr rmuired? 9126124 P-710-2 no DO no Date Probe or Reference Temo. (oFl Indlcated Tcmn loFl Dlfference Crlterie 9t26t24 P-'n0-2 66.0 66.0 0.0%+ 1.5 % (absolute) field Belence Check Drte 09t26t24 Balance ID SCALETS Certified Weight ID slc-l KG.l Certified Weight (g)r 1000.0 Measured Weight (g)999.8 Weight Difference (g);0.2 Date Beromeh:lc Pressurr Evldence of Reeding Verlfied Celibradon or anolr ranrrlrodl Weether Steflon Locstion 9t26D4 Weather Station NA NA NA l.ogan-Cache Airport, UT Dete Meter Bor II)Posldve Pressure Leek Check 9t26t24 M5-9 Pass 29 of 5l DGM Calibration-Orifi ces Document lC 620.004 Revisior 24.O Effective Dal(1/31/24 lssuinq Department Iech Services Paq(l of '1 Equipment Detail - Dry Gas Meter Console lD: M5-09 Meter S/N: 23075443 Critical Orifice S/N: SH 40-73 Calibration Detail nitial Barometric Pressure, in. Hg (Pb) Final Barometric Pressure, in. Hg (PbF) Averaqe Barometric Pressure, in. Hq (Pb) 6025. 25.60 25.60 Critifcal Orifice lD (Y) K' Factor, ft3 R'2 / in. wc.min (K) Vacuum Pressure, in. Hg (Vp) Initial DGM Volume, ft3 (vmr) Final DGM Volume, ft3 (Vmr) Total DGM volume. ft3 (Vm) SH.73 0.786/ 14.0 743.500 758.981 '15.481 sH-73 sH-63 0 6007 160 775.200 787.081 11.881 sH-63 sH-55 0.4524 18.0 799.900 808.842 8.942 SH.55 0.786l 0.601 0.452 14.0 759.300 774.766 15.466 16.0 787 300 799.195 11 895 18.0 809.000 817.958 8 958 Ambient Temperature, 'F Oa) lnitial DGM Temperature, 'F Omr) Final DGM Temperature, 'F Omr) Averaqe DGM Temperature,'F ( Tm) 82 82 82 82 83 83 OJ o2 83 o) 6J 83 83 83 84 84 84 84 84 g4 u 84 84u Elapsed Time (O) Meter Orifice Pressure, in. WC (AH) Standard Meter volume, ftr (Vmstd) Standard Critical Orifice Volume, ft3 (Vcr) Meter Corredion Fador m Tolerance Orifce Calibration Value (AH @) Tolerance Orrfice Cal Check 15.00 2.90 13.0134 12.9748 0.997 0.001 1.833 0.009 15.00 2.90 12.9768 12.9628 0.999 0.001 1.833 0.009 15.00 1.70 9.9347 9.9018 0.997 0.001 1.835 0.011 'r5.00 1.70 9.9373 9.9018 0.996 0 002 'r.833 0.010 15.00 0.95 7.M74 7.4504 1.000 0.002 1.804 0.020 15.00 0.95 7.4607 7.4504 0.999 0.001 '1.804 0.020 0.15 0.29 0.30 Veter Correction Factor ff)0.998 Jrifice Calibration Value (AH @)1.824 )ositive Pressure Leak Check Yes Equipment Detail - Thermocouple Sensor Reference Calibrator Make. Reference Calibrator Model: Reference Calibrator S/N: Calibration Detail Practical lnstrument Electronics Piecal 5208 887216 Reference Temp.Display Temp Accuracy Absolute Difference oF oR oF oR %r 0 68 100 460 528 s60 1 67 99 461 527 559 -0.2 0.2 0.2 223 248 273 683 708 733 224 249 274 684 709 734 -0.1 -0.1 -0.1 300 400 500 600 700 800 900 1,000 1,100 1,200 760 860 960 1,060 1,160 1,260 1,360 1,460 1,560 1,660 301 399 498 599 701 800 900 1,001 1,101 1,201 761 859 958 '1,059 1,161 1,260 1,360 1,461 1,561 1,661 -0.1 0.1 0.2 0.1 -0.1 0.0 0.0 -0.1 -0.1 -0.1 1 1 2 1 1 0 0 1 1 1 Personnel Charles R Horton 30 of5l Calibration By: Calibration Date. Reviewed By: Xander G Krahn 7/12/2024 pul6rrpE) r i: ( ) rilo!.ldol, il)"J,s,.ti-Fi,ti&l []T Sourc.: Rchat Fljme #l P rcJect No.: AS-T-2Q?41116 Dttc 9121124 Amlyzer Matc: Analyzer Modcl: Analyzo SN: Eovirouics ID: Componmy'Baluce Gu: Cylinda Gu ID @ilution): Cylindc Gu Coneuu-atio @itution), %: Cytinda Gry ID (Mid-Lrvcl): Cylindr Gu Concmration (Mid-loel), %: t00269 8029 2f .99 RRO253E .Not all AST Environics Units h8w 2-l0L MBs injectiom will not be mnducted ilcthod Crltcrh EPAttructar02 Mekt Mod. s/rr Sorr Swomex 4900 100269,{n lvllnd.r NMbcr ID 7*Jo Mld rldh NA RR02538 E80059884 lYlltrd.r Certlfi ed v.Iu6 72to Mld Hloh 0.00 I 1.00 23.99 l./. Ttto Mtd Elsh 0.00 I 1.02 ,1 09 Crllbrrtlon Grr Sclcttlon (7. of Sou) Mtd Hloh 44.Ootn Cillbnflon Enor Pcrfomrnc. (7. of SD.n) 78rc Mtd Hloh 0.0 0.1 0.0 Lharltv (7r of ReDcG) ol T.r8ct Mu FIow Trrgct Dllutlon t./-\ Trr3.t Flow Rrtr Trrget Concntndon t./-l Acturl Conccntrrdon (./-l lnJedon I Aml!'rcr ConeDtntloB InJcctlou 2 Andyzcr Concctrtntlon Inl6don 3Aill!"ar Concentradon Avcngc Atrd)"zcr Conceutrrtlotr Dlfiercnca Avengc Enor ( *2%\ l0ul0L 80.0 50 192 192 19.28 19.20 19.20 19.21 0.03 o.t% I OI-/lOL 50.0 5_0 12.0 t2.0 12.1 I l2.ll t2. l0 0l o 90/" IOUlL 20.0 40 48 48 /t 85 4.86 4.85 4.86 0.06 1.20/" IOUIL 00 4.0 2.4 2.4 2.41 2.42 2.41 2.42 0.02 0.E% AYerrge Aarlyzr CoBcctrtrrdon l./-\ Iujedon t Enor ( + 2./.r I4cctlon 2 Enor ( *2.Ar InJcctton 3Eror ( *2./.\ t9.23 o 70/"4 to/"-o to/" l2.t I o.oo/"o.0v.-0_to/. 4.86 .0.t%0.r%0.r% 74)-o 10/"off/"0.40/" 3l of5l anlflirrce SOL,,RCE TESTING Mass Flow Controller Calibration Note: The mass flow controller's calibration values are used by the dilution system's operating software to improve accuracy. These calibrations are not necessarily indicative of the systems overall performance. Performance is verified by conducting a Method 205 prior to each field use. Calibration Performed By JFT Dilutlon System Makei Dllutlon System Modeli Dilutlon System S/N: Callbratlon Equlpment Make: Calibratlon Equlpment Model: Callbratlon Equlpment S/N: Flow Cell S/N: Flow Cell S/N: Callbratlon Gas: Barometrlc Pressure, mmHt: Amblent Temperature,'F: 4040 8029 Alicat Scientific M-10SLPD/SM M-D/sM, M-15LPM-D/s 27212O;272721 272120 27212L Nitrogen 25.559 70.7 Mass Flow Controller lD Slze, ccml Make: Model: S/N: f1 10,000 Environics 4040 455242003 #2 10,000 Environics 4040 453242004 #3 1,000 Environics 4040 453242N2 Set Flow True Flow Dlfference cc/mln cc/mln Set Flow True Flow Dlfference cc/mln cc/mln Set Flow True Flow Dlfference cc/mln cc/mln 5% to% 20% 30% 40% 50% 60% 70% 80% 90% too% 500 489 2.2% 1,000 987 7.3% 2,000 1,970 t.s% 3,000 2,98s 0.s% 4,000 4,oL4 0.4% 5,000 5,034 o.7% 6,000 6,053 0s% 7,ffiO 7,084 t.2% 8,000 8,119 7.s% 9,000 9,1s6 L.7% 10,000 Lo,202 2.o% 500 454 9.2% 1,000 959 4.t% 2,000 1,989 0.5% 3,000 3,003 0.r% 4,000 4,0L4 0.4% 5,000 5,033 0.7% 6,000 6,055 0.9% 7,000 7,093 7.3% 8,000 8,723 7.5% 9,000 9,160 7.8% 10,000 10,196 2.O% 50 47 6.0% 100 97 3.0% 200 196 2.O% 300 298 0.7% 400 400 0.0% 500 502 0.4% 600 602 0.3% 700 706 0.9% 800 810 7.3% 900 914 L.6% 1,000 1,020 2.o% Date 4/L9124 32 of5l pl/l6rrpE) T E (l tl f\l I ()i\l (l B () tl t) Location: Nucor Steel - Plvmouth. UT Proj ect No.: AST-2024 -3 136 N02 Converter Check - Outlet#Analyzer Model Serial Number 12327730521 Cylinder ID Number CC770751 Cylinder Exp. Date 4/16/27 Cvlinder Concentretion- DDm 49.7 Pre-Test Date 9/26124 Time 14:36 Pre-Test Concentration, ppm 46.08 Pre-Test Efliciencv. 7o 93 Post-Test Date 9126124 Time Post-Test Concentration, ppm Post-Test Elfi ciencv. 7" 2l:13 93 46.30 *Required Eficiency is > 90 %. 33 of5l PJI/terhdluba Accredltrton #627t{ Rod Ball Technical Gas Service 555 Craig Kennedy Way Shreveport, LA 7't107 800-551{150 PGVP Vendor lD # G12021 EPA PROTOCOL GAS CERTIFICATE OF ANALYSIS Cy'lnder Number: Produc{ lD Number: Cyllnder Prosaure: coA# Customer PO. NO.: Curtomer: )cttol51 124t31 IU5U PSIG )c770751.202402124 Cortlficatlon Date: Explraflon Date: MFG Faclllty: Lol Number: Tracklng Number: Prevlous Cerllf, cafl on Dates: 04t't6t2024 c4t16t2027 cc770751.20240212 108893218 has been per the May Traceability G2. SMART.CERT Certified Concentration(s) Goncontra0on Uncortelnty Anrlytlcel Ptlnclplo Asrayed On o2n6l2o24. o4n6t20247 PPM to.s PPM FTIR Balance Analytcal f,leasurement Data Avallable Onllne. 29,22 PPM 94,5 PPM 53.3 PPM MKS 2O3,1DJG2E}OS13T MKS M31GPPP1A5ZK1)O( 017146467 0',119t2024 11242A2U 0{,11512024 This is to certiry the gases referenced have been calibrated/test€d, and verified to meet th€ defined specifications. This calibration/test was porformed using Gases or Scales that are trac€able through National lnstitute of Standards and Technology (NIST) to the lntemational Slatem of Units (Sl). The basis of complianc€ stated is a comparison of the measurement parameters to the specified or required calibrationnosting pmcess. The expanded uncertainti6s use a coverage factor of k=2 to approximate the 95% confidence level of the measurement, unless otherwise notad. This calibration certificate applies only to the itom described and shall not be reproduced other than in full, without witten approval from Red Ball Technical Gas Sorvicas. lf not included, tho uncertainty of calibrations are available upon request and werB laken inlo account when detormining pass or fail. -4 /1 ,414 M; Tlmothy Davlc Analytlcal Chemlst Assay Laboratory: Red Ball TGS Vmlon 02J, Revkod s 2018{917 34 of5l pd/l6rrrcE)QA Data Tf ()t-r t,.l l(tAl, (lRr.rItlr Location Nucor Steel - Plymouth, UT Source Reheat Fumace #l Project No. AST-2024-3136 Parameter Or - Outlet COr - Outlet NOx - Ouflet Make Model SAI Oneretins Rense Servomex 4900 100269 25 Servomex 4900 100269 100 Thermo 42iQ 12327730521 200 Cylinder ID 7*ro Mid Hish NA RR02538 EB0069884 NA RR02s38 EB0069884 NA EB00l 1606 88001 1606 Cylinder Certifed Values 7*ro Mid Hish NA I1.00 23.99 NA 10.9 23.9 NA 501 501 Cylinder Expiration Date 7*ro Mid Hish NA 9n9t3r 4/t/32 NA 9/19131 41U32 NA 9t16/31 9lt613t fvoe of Samole Line Heated Line 35 of5l pllIATEE) T []() ll f.l I ()A t (, R(.)ll I' Location: Nucor Steel - Plymouth, UT Response Times Source: Reheat Furnace #l Project No.: 4$2Q24:1116 seconds Parameter Or - Outlet C()" - flnflet NOx - Outlet 7*ro Low Mid Average 30 NA 30 30 NA 30 60 NA 60 30.0 30.0 60.0 36 of5l pul6rpEr Calibration Data Location: Nucor Steel - Plymouth, UT Source: Reheat Fumace #l Project No.: AST-2024-3 136 Date:9/26/24 Parameter O: - Outlet COr - Outlet NOx - Outlet Emected Averase Concentration 13.50 5.00 20.00 Span Between Low High Desired Soen 13.s0 67.50 23.99 5.00 25.00 23.90 20.00 r00.00 r00.00 Low Range Gas Low Hish NA NA NA NA NA NA Mid Range Gas Low Hish 9.60 r4.39 9.56 14.34 40.00 60.00 High Range Gas Low Hish NA NA NA NA NA NA Actual Concentration (7o or ppm) 7*ro Low Mid Hish 0.00 NA l 1.00 23.99 0.00 NA 10.90 23.90 0.00 NA 50.00 100.00 Resoonse Time (seconds)30.00 30.00 60.00 Uoscele Calibration Gas (C-^)Mid Mid Mid Instrument Response (7o or ppm) 7*ro Low Mid Hish 0.00 NA 11.00 23.99 -0.01 NA 11.22 23.90 0.02 NA 50.06 99.92 Performance (7o of Span or Cal. Gas Conc.) 7*ro Low Mid Hieh 0.00 NA 0.00 0.00 0.04 NA 1.34 0.00 0.02 NA 0.06 0.08 Status Tnro Low Mid Hish PASS NA PASS PASS PASS NA PASS PASS PASS NA PASS PASS 37 of5l Bias/Drift Determinations rl l1l,'l' "\l Location: Nucor Steel - Plymouth. UT Source: Reheat Furnace #l Project No.: AST-2024-3 136 Parameter Or - Outlet COr - Outlet NOx - Outlet Run I Pretest System Zero Response Posttest System Zero Response Pretest System Upscale Response Posttest System Upscale Response 0.16 0.14 10.94 10.90 0.01 0.02 r l.0l I 1.02 0.08 0.01 48.70 49.82 Run 2 Pretest System Zero Response Posttest System Zero Response Pretest System Upscale Response Posttest Svstem Uoscale Resoonse 0. l4 0. l4 10.90 10.91 0.02 0.01 1r.02 I 1.08 0.01 0.0r 49.82 49.76 Run 3 Pretest System Zero Response Posttest System Zero Response Pretest System Upscale Response Posttest System Upscale Response 0.l4 0.16 10.91 t0.92 0.01 0.04 I 1.08 11.09 0.01 0.02 49.76 49.46 38 of5l pul6rtpE) I r' i rl | ( i\ 1- rI Ft''i:;r*,NucorSteel-plymouth.ur Bias/Drift Determinations Source: Reheat Furnace #l Project No.: AST-2024-3136 Parsmeter O, - Outlet COr - Outlet NOr - Outlet Run 1 Date 9126124 Span Value nitial Instument 7*.ro Cal Response bitial Insfument Upscale Cal Response lretest System Zero Response losttest System Zero Response lretest System Upscale Response ,nsffesl Svsfm I Inscale Resnonse 23.99 0.00 I 1.00 0.r6 0.14 10.94 10.90 23.90 -0.01 11.22 0.01 0.02 I 1.0r I 1.02 100.00 0.02 50.06 0.08 0.0t 48.70 49.82 Sias (%) lretest Zero losttest Zero lretest Span )6stfesf Snan 0.67 0.58 -0.25 -0.42 0.08 0.13 -0.88 -0.84 0.06 -0.0t - 1.36 -0.24 )rift(%) 7*ro \,lid -0.08 -0.17 0.04 0.04 -0.07 t.t2 Run 2 Date 9126124 Span Value lnstrument Zero Cal Response lnstrument Upscale Cal Response Pretest System Zero Response Posttest Systern Zero Response Pretest Systern Upscale Response Posttest Svstern Upscale ResDonse 23.99 0.00 I 1.00 0.14 0.14 10.90 10.91 23.90 -0.0t 11.22 0.02 0.0r 11.02 I 1.08 100.00 0.02 50.06 0.01 0.01 49.82 49.76 Bias (%) Pret€st Zero Posttest Zero Pretest Span Posttest Soan 0.58 0.58 -0.42 -0.38 0. l3 0.08 -0.84 -0.59 -0.01 -0.01 -0.24 -0.30 Drift(%) Tnro Mid 0.00 0.04 -0.04 0_25 0.00 -0.06 Run 3 Drte 9126124 Span Value lnstrument Zero Cal Response lrlstrument Upscale Cal Response Pretest System Zero Response Posttest Systern Zero Response Pretest System Upscale Response Posttest Systern UDscale ResDonse 23.99 0.00 I 1.00 0.14 0.16 10.91 10.92 23.90 -0.01 11.22 0.01 0.04 I1.08 I 1.09 100.00 0.02 50.06 0.01 0.02 49.76 49.46 Bias (%) Pretest Zero Posttest Zero Pretest Span Posttest Span 0.58 0.67 -0.38 -0.33 0.08 0.21 -0.59 -0.s4 -0.01 0.00 -0.30 -0.60 Drift(%) Trro Mid 0.08 0.04 0. l3 0.04 0.01 -0.30 39 of5l &*f,g!$-.. Accrcdltaton #82754 Red Ball Technical Gas Service 555 Craig Kennedy Way Shroveport, A 71107 800€51€150 PGVP Vendor lD * G12023 EPA PROTOCOL GAS CERTIFICATE OF ANALYSIS Cy'lnder Number: Product lD Number: C)dlndor Pres3ure: coA# Customor PO. NO.: Customer: 1R02538 253t1 9OO PSIG <ROz536.20230U31 { Cortlflceton Date: Explratlon Date: UFG Feclllty: Lot Number: Tracklng Numbor: Provlou3 Certlllcatlon Dates : J9t2112023 lgn 9/2031 RR02538.20230831 103925725 calibration standard has been certified por tho May 2012 EPA Traceability Protocol, Document G1. -t SMART.CERT Conc.nlraton Uncertalnty An.lttlc.l Prlnclple A$ayed On f0.11 o/o 10.03 % 1162980025 09118t2023 o17',116467 09n1t2023 This is to cedty the gases referenced hav€ b6en calibratod/tested, and verified lo meet the defined spocifications. This calibration/test was p€rformed using Gases or Scales that are trac€able through National lnstituto of Standards and Technology (NIST) to the lntemational S)rstem of Units (Sl). The basis of compliance stated is a comparison of the measuremenl param€lers to tho sp€cified or requirBd calibratjon/testing prooess. The expanded uncertainties use a coveragg fador ol k=2 to approxlmate the 95% confidence level of tha measurement, unless othoMise not6d. This calibration certificate applies only to the item described and Ehall not be reproduced other than in full, without witten approval from R€d Ball Technical Gas Services. lf not included, the uncertainty of calibEtions are available upon r€quest and were taken into account when determining pass or fail. fr".*- /Lrh Jacmlne Godfiey Analwcal Chomllt Assay Laboratory: Red Ball TGS VoBion 02J, RevlEed o 2018{917 40 of5l &*,PJll,-.- Accredltatlon ,162754 Red Ball Technical Gas Service 555 Craig Kennedy Way Shreveport, LA 71107 800-551{150 PGVP Vendor lO # G12021 EPA PROTOCOL GAS CERTIFICATE OF ANALYSIS Cy'indor Number: Product lD Number: Gy'inder Pressuro: coA# Customer PO. NO.: Customer: E80069884 127907 1900 PS|G E80069884.20240320-0 Certlffcatlon Date: Expiratlon Date: MFG Facllity: Lot Number: Tracklng Number: Provlous Corlifr catlon Datss: )4to312024 )4to112032 snrevenon - I a :80069884.20240320 )8/.212711 standard been certified per the May 201 2 EPA Tracoability Protocol, Document EPA-600i R-1 2y531 , G2. SMART.CERT Concentraflon Uncertalnty Analytlcal Prlnclple A!3ayod On tO.1 o/o i0.06 % 20.01 ./. 24.76 0/; Analytical Instrumentation ilPC Dato 02 co2 MPA FTIR Tholm MKS 4t0i MKS 2O31DJG2EIO/SI3T 1162980025 03118,2024 017146467 U|O2J2024 This is to certify tho gases referenced hav6 been calibrated/tested, and verified to me6t the defined specifications. This calibration/test was performed using Gases or Scales that are traceable through National lnstitute of Standards and Technology (NIST) to the lntemational S)6tem of Units (Sl). The basis of compliance stated is a comparison of th6 measurement parameters to lhe specified or required calibration/testing process. The expanded uncertainties use a @verage factor of k=2 to approimate the 95% confidence level of the measurement, unless otheruise noted. This calibration certificale applies only to the item described and shall not be roproduced other than in full, without written approval from Red Ball Technical Gas Services. lf not included, the uncertainty of calibrations are available upon request and were taken into account when determining pass or fail. 4l of5l ?Jlrf.-rhhdE.ba Accredltaton ,lE275rl Red Ball Technical Gas Service 555 Craig Kennedy Way Shreveport, A 71107 800€5t{150 PGVP Vondor lD * G12023 EPA PROTOCOL GAS GERTIFICATE OF ANALYSIS Cyllndor Number: Product lD Numbor: C9lndor Pregsure: coA# Cultomer PO. NO.: Customsr: :B(rulltifii 24235 9OO PSIG :8001 1606.20230906-0 Certlficaton Dale: Explraton Oato: ilFG Faclllty: Lot Number: Tracklng Numbor: Pravlou! Gerflfl caton Oatos: )9t14t2o23 J9/16/2031 - shrevsmrt - 1A E8001 1606.20230906 )25274839 standard per t, Gl. SMART.cERT Concsnba0on Uncertrlnty Anll!illcll Prlnclple At.ayed On otal Oxides of Nitrogen 503 PPM il1-M-50 EB0059947.202301 1 7 sx32691.202301 1 7 996.7 PPM 280 PPM 279.8 PPM This is to certify the gases referenced hav€ been calibrated/t€sted, and verilied to m6et the defined specifications. This calibration/test was p€rformed using Gasas or Scales that are traceablo through National lnstitute of Standards and Technology (NIST) to the lnternational S)rstem of Units (Sl). Th€ basis of complianc€ stiated is a comparison of the measur€ment parameters to the sp€cified or requirod calibration/testing procsss. The oxpanded uncertainties use a cov€rags faclor of k=2 to approximate the 95% confidence level of the measurement, unless othenvise notgd. This calibration csrtificate appli€s only to the item de8cribed and shall not b€ reproduced other than in full, without writton apprcval from R6d Ball Technical Ges Sorvices. lf not included, the uncertainty of calibrations are available upon r€quest and w6re traken into account when detBrmining pass or fail. ,/atat thrrhu Aaron Varelag Anelytlcal Chemlst Assay Laboratory: Red Ball TGS Vffilon 02J, R6vbod m 2018-0$'17 42 of 5'l pllIATEE) 1f ()ilNt()AL (iR()l.iP Location: Nucor Steel - Pl.mouth" UT Source: Reheat Fumace #l Project No.: AST-2024-3135 Dile:912612024 Traverse Polnt Time o2 (V"l Coz (oal NOr (nnm) A-l 2 3 l4:50 l4:52 l4:54 l s.3 15. I 14.8 15.0 3.1 3.2 3.4 3.2 24.7 26.4 25.7 25.6Averaqe Criteria Met Single Point Single Pornt Sinele Point 43 of5l dd d d d d d d d d d d i d i d d d d d i d d d d H H d d H d H d d d d d H d d d i i F-IE, - - - 6 o 6 @ @ @ @ @ G @ @ @ @ @@ @ @ @ @ @ @ @ @@ @@ @ @ @ @ @ @ @ @@ @ @ @@ @ @ @ @ @ @@ @ @ @ @@ @ @@ F - - - o o o o o o o (q o o o o o o o O o o O o o O o O O O O (, (, O O (, O (, c) O ., (' O c) (, O (, (, , O c, C, O (' (, c) (, C, (? :s s 3 3 s S 3 ; 3 3 S S S $ S $ S S S $ S S S S S S S S S S S S S S $ S S S S 3 S S 3 S S 3 3 S S S S S S 3 S S 3 d I ed - F oo N Fo o N @ o ? o N F O O O N @ O { O N F O O @ F @ O { O N F O O O N @ O { O N F O O € F @ O S O N F O O o; F o 6 6 0 0 0 0 0 0 6 0 0 0 0 0 @ @ 6 @ 6 0 @ o @ t s t s N F N F N t s t s N @ O @ @ @ @ @ @ @ @ O O 6 0 0 0 @ 4 0 0 3 -I o @ 6 6 @ @ @ F ts N F F F F F ts ts N N N N N N N ts ts F F ts }- ts ts I. - F N N N N ts F F F F F N N ts N ts N ts F ts ts ts N N FF F F+o 6 0 6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 -6 6 6 6 o - - - o o - - - 6 o 6 o o 6 o - 6 o 6 . a 6 ( i ) ( r ) o o O o o o o o O o O O O O O O O O O O O O O O O O O O o =6 6 6 6 6 d @ @ @ @ 8 8 8 t 8 8 8 8 8 8 8 8 8 S 8 8 8 8 8 t 8 8 8 8 8 t t t 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 t @6 0 0 0 0 0 0 0 0 0 c' 8 s s s s s s 8 s S E S t t t t t E t t t t t t t t t t t t S t S E S t S t t t t t t t t t t t t t t t t t t t t :N N N N N N N NN N N N ( \ l N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N dt2. . I : S P : P 9 - * o a 6 io r o o p = S P : I I F 3 9R e N & N &S N R &8 E$ S S $ - ro t oo N -. P : S P e6ztrdf.n ' o o o @ 6 6 @ @ o @ @ @ @b o @ @ @ o @ o @ o o o@ @ o @ o @ o@ o o D o @ o @ o@ @ a @ @ @@ @@ @ D@ @ D@ a z a s s + s q $ $ q s s rt t !t I + tt { * { s t t 3 Q t t t I s t I t q s s t s t i { t + s { * { ? t !t 3 { $ t = $ t =od I&6o;' -* * Y: E r t = t = = = E = E = t E : : : = = = : : : : : E E = = z = : E = E = = = z = = = = f =E = = E = E = = = = f < 66 6 0 6 0 0 D O 6 6 0 6 0 0 0 6 0 0 D D O O 6 0 6 0 6 0 0 6 @ D @ O 6 0 0 0 0 0 @ o o 6 0 0 0 0 0 0 0 6 0 0 4 0 qN N N N N N N N T T N T N T T T T N N T t s N N N N N N N T T T N T T T F N N T N T T T T T T T T T N T T N T T N T oo o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o e o o o o o o o q. i i i i x i x i x x x x x x i i i x x x i x i i i i i x x t i x i x i x i x x x x i x x x x x x i x x t x x i x x c< < < < r < < < { < < n < < < r n ! { { { $ { < $ < q 3 { t ! s $ 9 { t t $ s < ! t < { ! { t { t 9 s t { v s { s or I L r r E r r L r I r d^N N N F t s F F N F @ @ @ @ @ @ O @ @ @ @ O @ 6 @ O @ @ O @ @ @ @ @ @ @ @ @ @ O @ @ @ @ @ O O O O O O O O O O O O O = N .\ N i\ N ts ts ts F ts N F N ts ts F F ts ts N N N ts ts ts ts N N F N N N ts N ts N F N F N N ts N F N N N N ts N N ts N F N F N ^I F N FF F ts N ts F N N F N ts N N NN N N F N N N FN N F N N N N ts F N N NN ts N ts N N N N NN Nt s N ts N N F N N N Fq i r r9 r s $ q s I t n t s ? 3 $ t t $ t I { t t q { $ t s r I q $ t s 9{ I { s r s I $ s s v $t s r 99 I r + U9+ o o N 6 o o F N o t o @ N @ o o F N o t 6 @ F @ o o F N o s o @ F @ o o - N o t b @ F @ o o F N o t o @ N @ o o 4 ( NF L N N 6o @@ 6@ @@ @ @ O O OO OO OO OO O O O OO O OO OO F F - - F F N N NN NN N NN N O !! r r $ $ s r q $ v $ s t $ t s t t t s $ s q q t t t o@ oo o o o 0 0 6 60 Q oo 6 0 0 6 0 6 Q 66 0 n oo o oo Jd d 6 d d d d d d d d 6 d 6 6 6 0 6 6 0 0 0 6 0 0 0 @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ qo o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o a o u< + + r < < r $ r + c + + r t n n v 9 t t { t $ Q n 9 t 9 s 9 $ 9 $ i t s 9 t $ s v s 9 9 $ t s q s t 9 s v t s * @N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N -r o o o o o o o o o o o o o o o o o o o o o o o o a oo o o o o o o o o o o o o o o o o o o o o o oo o o o o o o o tF F F o ftsf; - - * dd i i H i i I&@U:tr(,GIoIo&EFodIoEI: : : = = E = = : : : : = t E E = E E - = E T E E E E : : : E = t : : E = t E : t : = E E E - t E : = : = E = E E Fr c d d d o d d d 4 c a e d d d d o o 4 c do dc o do c c G4 e c c oc a4 e4 d rq 4 d d a4 dG c da 4 dc 4 d d@ 6 6 0 d N o s s o @ N o H H N o < 6 @ @ N 6 0 0 d d N O t @ @ N F @ O O H N N 0 ! @ @ r r @ O O H N O O t O @ uo O O o { l q< << { i t o o @ o O O 6 O @ @ @ o O O O O O o o O O O O O H d i d H d d d d d d d N N N N A q f l N tr c i s r i . r c i $ F i c i c i c i c i r i 6 d 6 d 6 d i , i i , i c i c i & i F i & i a i c i i i c i { { t < c t t { { r { < {. i d t r i r g { { t t t t t e t t g s {s ' i€ ! 3 s s v ! s q q s l ! r r s 3 9 q t ! q ! s { ! { 9 s s { ! { ! { { ! { 9 t ! { t { ! { t n q *, d N d d d d d d N d d N d d d N d N N N N N N N N N N d d N N N N N d N N N N N d N N d N N N d d d N N d N N N N i6 6 6 6 6 6 6 6 0 0 0 0 d O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O ]- . - N d N * . d N i N N N d N d N N N N N N N N N N N N N N N N N N N N N N N f l NN N N q N N N N N d N N N N N -a a a a b a b b b D D a a a D a a D a a B D D a a D a a a D a a D D a a a D a a D a a a a a D a a a a a a a a B a -. R N N d d d d N N N N d N N N N N N N N N N ( N N N N d N N N N ( N N N N N N N ( d N N N N N N N N N N N N N N N t ot oi ot ot ot ot ot ot d o 6 d d 6 6 d o o o o 6 o o o o o 6 o o o o o o 6 o o o o o o o o o o o o o o o o o o o o o o o 6 ,H u E -otr3r O O O (O @ O @ @ @ (O @ @ @ @ @ @ @ O @ @ @ @ @ @ A @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ e F () O .t c) A' A' (' O (' c) c) c) C' O (, (, () O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O 6 jS s s $ s s $ s s s s $ 3 s s s s $ s s s 3 s 3 3 3 3 3 3 s 3 3 s 3 3 3 $ s s s s x s s s s s s $ $ 3 s s s 3 s s 6G,6^O N O O * O N r O O 6 t s @ D { O N F o o @ t s @ o s oN F O o @ N @ o $ o N F o o @ t s @ D t o N r o o @ F @ 6 t o N = S V t = * { { S + OO O O O O OO O O N N N N N N N N N N F F O O OA O O O O O O O O O O OO O O .IN N N N t s N N N t s N N N N N N t s N N F t s t s t s t s t s N N N N N N N F t s t s t s N N t s t s N t s t s N t s t s N t s t s F @ @ @ @ @ @ @ @ rF ' F -o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o -i o e o (o o o c) o c) o o .q (t o (, .r ) o o (r ) o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o = o @ (o @ @ @ (o @ @ (o @ .D (o o @ @ o @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ o @ @ @ @ @ @ o @ @ @ o @ @ @ @ G @ r. o oo o o oo o o o oo o o o oo o o o o o o o o o o o o o o o o o o o o o o o o oo o o o o o oo o o oo o o o *' t t tt E tt t t t tt t tt t 3t E t t t t t 3 3 t E t t t 8 8 t 3 8 33 3 tE tt t 8 33 E tE t t 8t t t t }N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N PGa d r d d d i d d d i d i d d d d d d i d i i d i i H H i d H H d i H i i d i i d i i l i H I t66t? : P P: 3P Re S RX R& N Rf t - c o $ o @ N - - I : S P : I I : P I R e N R & RR N & R SE S E S B F N o !' o @ I&6zotrdfo,r ' @ @ @@ @ @ @o @ @@ h @ @@ @ @@ @ o 6 o @ @ @ @ @ o o @ o 6 @ @ @ @ o o @ o o @ o @ o o @ @ @ o @ @ o@ o @ @ 2V V S S S S S S S S S S S S S S S S S S T S S v s s s V s V r S S V s 9 S 9 3 S S 3 S S S 9 S = S S 9 3 V V S 9 S =oEIEE= = = - z E E E E f EE = E = E E E E : = E = = = E = = = = = f E= E = = E = f == f :: t = = E = E = = = = E = Ft O 4 AG 4 dA q O G rG C O d 4 4 eA C O d d d C d d C d d C d d 4 O O O 4 C C A4 e 4 O C C A CA A d dd r d d dN d N o n { o @ t s o o o i N o o < o @ o o d d N o{ 6 @ N N o o o i N N o ! 6 @ N N @ o o i N o o t @ F o o d N o uN o e o o o o o o o E ? I I l l 1 1 i 9 1 9 y t y ? { ? ! ? y ? y ? y ? { l ! ? y ? y ? 9 9 9 e 9 ? 9 9 9 C 9 e n n r : i : 1 : 1 : 1 : 1 9 ! ! ! 9 ! ! ! ! ! E s { ii { t < t' { ii { t { iJ { q { {' { i' s q < s r r I r M <. o 6 o o o o @ 6 o (i 6 6 6 6 o o 6 6 o o o ri (i o i- 3 r { { r I { { { { ! { t { { { I I { r { s s $ q r { $ I r $ ! r s ! { { { { { { { t I { I I I q I t s I !t < t { -I N N NN N N N N N NN N N N N N N NN N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N NN N N N Je O O O O O O O O O C O O O O O O O O O O O O O O O O O O O O O o o o o O O O O O O O O O O O O O O O O O O O O O JN N N N N N N N N N N d N N N N N A N q N N q N N N N N d d N N N N N N N N N N N N N N N N N N N N N N N N N N N =a a a D b D b b B b D a a D b b D b D A A A D A A A A B B A D A A A B A A D A A A B A A A A A A A D a A D a A A A -, f t d NA N dd d N N fl N N R N N ft dC N N N d N d N N N N N N N N N N N N N N N NN N N N N N N NN N N NN N N N to o 6 o 6 6 o 6 6 6 6 O O O O O O O O O 6 O O O 6 6 O O O O o O O O O O O O O O O O O O O O O O O O O O O O 6 O O 6ohr - r Y= t = = E = = = = E E = = = E E f Et : E t : E E E : t : = : t = E = = = : : r = = E f :E = t : : E f =E = E = =6 6 0 6 0 6 @ O O O 6 6 0 @ 6 6 6 0 6 0 6 6 0 6 0 6 D O @ D 6 6 0 6 0 6 0 0 0 0 0 0 @ O O 6 6 0 @ 6 @ O O O @ O O 9r r r N r F F r N r r r r r r N r r N N r r t s N r r r N r N N N r r r N r r r r r r r r r r N r r r r N N N N r N QO O O O O O O O O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Fii t x x x x x x x x x t x x i i x x x x x i x x x i x x x x x x x x x i x x i i i i x i x x i i x i i t x i i i c. s I < ! q s I s ! I { s ! I < $ $ < s v $ ! q { { ! s s s { { ! q ! s ! { { ! { < t { t ( ! { ! { s { I n I q ! ! 6r r [ c [ L [ r r r L [ L L I L E L L I ^ oo o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o =F t s N N t s F t s N t s t s N F N N N F @ @ @ @ O @ @ @ @ @ O @ @ @ O @ @ @ @ @ @ @ @ O @ @ @ @ @ O O @ @ @ @ @ @ @ @ @ @ .I F F N N F N t s t s N F N F N N N F N t s N N N t s F N t s N F N t s F F N N N N F t s t s t s t s N F F N t s N N N t s N F t s N N F N F =F F FF * $ s t { t t s $ t $ t $ t t * t t $ t t $ v $ I s s t s s + t t t t t $ S I I s t $ t $ $ { I I S I $ $ \t I $ $ 9- o o t o @ N @ O O F N o t o @ N o o o F N o r o @ N @ o o - N o t o @ t s @ o o F N o t @ @ N @ o o F N o t @ @ N ao o o 6 0 0 0 0 0 i { { r t r $ r r < 6 0 0 0 6 0 6 0 0 0 @ @ @ @ o @ o @ o @ N t s N N t s F t s N F N o o € o o o @ @ P a o o o o 6 o o o lJ ) lr ) rD rO u) lo rJ ) lr ra ' l ) o o o o o O O o 6 o o rD o o a o O O O o o o @ O O h o o o o o o n O o o o o :? . @ @ @ @ O O O @ @ @ @ @ @ @ @ @ @ @ 6 @ O O @ O O @ @ O 6 @ O O @ @ @ @ @ € O O 6 O O @ @ @ @ 6 O O @ O @ O O @ O qo o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o rv s s s s s s s s v v s v v s v s v s s s s v v s s s s s v s s s s s s s s q v s @, N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N -, o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o tF F F 6 UEF,o6-q6GU:F,oEIoIG uH u E -oie s s s B s s B s B E E E E E B s r E E r r E g g E E E E s B s B s H E g s H g s s E t t s H s B s B s B E E E E ES S H J S S t S S S S t t t S $ $ $ $ S s $ S S $ 3 S S $ S $ S S S S S S S S S S S S S S S S s S S S s s s s s s EIG- Fo 6 6 N @ o + o N ? o o o t s @ 6 q m N F O O O N O O t O N F O O € F @ o { O N F O O @ N @ o t o N F o o @ N @ o 6 6 aE 6 .6 io 6 6 d ct 6 @ 6 F N l. N ts ts N N N N @ @ O O 6 (O @ @ @ @ lo O o 6 lo 6 O 6 O O * t !t rt S t t q S { o o o o o -' ct 6 6 6 a6 6 6 6 @ @ @ 6 @ @ @ @ @ @ @ O @ O @ (D @ O @ @ @ @ @ (O @ @ @ (O (o @ @ @ O @ O @ O @ @ @ @ @ @ @ @ @ @ @ @ FF F F u{ o o oo o 60 0 0 0 0 0 0 0 00 0 0 00 0 0 0 0 0 00 0 0 0 0 0 0 00 00 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 0 i - - - - - o o - 6 - 6 - 6 O 6 - (. (i {i O (i (. (i (i (. (' o (o o o o s, o o o .r ) o o 6 (, A .? !' (D (, (! (D (? .? .? (! ., (! o o o o ;9 9 9 8 8 8 9 8 8 8 8 8 r 8 8 8 8 8 8 8 8 8 8 8 8 8 8 t 8 t t 8 t t 8 8 t 8 8 8 8 8 8 8 8 8 s 8 8 8 8 8 8 r r 8 8 e' S * E = = = = t E = 8 8 3 8 8 8 8 8 8 8 8 8 8 8 8 3 t 8 3 t t t t t t 8 t t t t t t t t t t t B t t t E t 3 3 8 8 : N N N N N N N N N dI il N N 61 6T 6r N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N Pf; -** H d d d d d H i i H d d d d d i d d d i i d d d d i d d d H d d d d d d d i i d i d d i d d i i d d d d i d edEr6TI r o o P = S P : I I : P PR F N tl X R R h R& 3 E SE $ 3 -. o rt o @r o o p = S P : P P: P P Re N & N R E N R 6'@zotrElo.n ' o o 66 6 @ o @ @ @ @@ @ @@ b @ o @ o @@ @@ @ @ n @ o o@ @ o @ @ @@ @ @ @@ @ @@ h o o @ @ @ e a @ @ @ @ o > it + < < i - a + < t a a + + + * $ r < { * + + i i + $ r r s t <f ? !a + 3 * !t ? { + r r { q r $ v v v s v $ s s v s =oEIG6r:trotIo6I d=trUo4To6E : := = -E = - E = = =- f t = : E = : E : = =: : - = = E= =E E E EE E E E: E =- - = t z : =: E E E = = = = F, d d d E d a d d a a d o c G 4 c a c G A A r o a G G A 4 e d d o l d G o c d o d G a o a 4 0 G o d d o d d d d d d s' N R E R N R & s s E g E S g S S D t E g S S g g $ g S e S $ 9 8 6 $ 3 3 3 B E D 3 E B t 5 s 3 3 3 3 8 5 3 8 P e P tr (i o 6 o a 6 o o o o o o o 6 o 6 6 o a o o o @ 6 6 a a @ a a o a o @ o o 6 @ o Q 6 o o @ @ @ @ @ @ @ @@ @ @ @ @ @ iG € n { E ! ! r n < ! s r r ! < s { v s s ! s r { q ! l ! ! r < ! { 1 3 ! n < q { s ! t ! { ! s ! ! t i s *,d d d d dd d d d d d d d N N d N N d N d d d Nd d d d N N N N N NN dd N N d N NN N N N N N N N N N N N N N N -'5 66 6 56 6 6 6 66 66 6 66 0 00 0 0 6 d OO O O O6 00 0 6 0 0 6 00 0 0 0 00 0 0 0 0 0 00 0 0 0 0 0 0 0 ]- F d N f l 6N N N N N N d d N N N N N N N d N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N = :d ii it :t it i, D ;t b it b D b a B a b a b b B a b b b a b D a a a a a B a D D D a a D a a a a a a a a B D B a a a B a -.d d dd d d d d d d N N d N N N N N N N N N d N dd N N N N N N N N N N NN N NN N N N N N N N N N N N N N N N N :t ot o, ot ot ot o, gt ot o 6 6 6 6 6 6 o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o doha e * n n d t d i i d H d i i d d d i H d i H i i d i i n i d i d d d d i d d d i d d i d Yr r r E r f :f f :E = = = = = E = z E z = = : f f =: t : E E = E : = E = = = E = E E = E = = E E E E = = Z E = <6 6 6 0 b 6 6 6 0 6 6 6 0 0 0 6 0 6 0 0 0 0 0 0 4 6 0 @ o o o o o o o o @ o o Q o o o @ 6 6 0 6 0 6 0 6 0 6 6 6 0 oi E N N N N N N N N N N t s N r F r r r r r t s r r r N r r r r r r r r r r r r N r r r r r N r r r F r r r r r F F F o a, ar o o o o o o o o o 6 0 0 a o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o 0 q i i i x i i x x x x i x i x x x i x x x x i x i x x x x i i x x i x x x i x x * x x i x >i i >{ x >a >{ x x x x x x x a. - - d t - { < d < s < { < {{ I I q ! q $ s t s $s ! { s t ! I s ! t s s { t r I q { I I < t s s a { ! q { I I s or d E E L r E r r I r I E G E E [ [ r r r r I r r r I r Gd FT N N N N N N N N N N N N N N N N N N N N N N N N N ( ! N { =@ @ o @ 6 0 @ @ @ @ @ @ o o @ @ @ @ € @ o o @ @ @ o @ @ @ @ a € @ € @ o o @ @ 6 0 0 0 6 @ @ o o o o o o o 6 @ @ o IN N N N t s F N N N N N N N N t s F N N N N t s N N F N t s F N t s N N F F t s F F F N t s N F F N t s t s t s N N t s N N N F N N F t s !F r r 9 r r s r r r r t t t t { t t t $ $ t s t $ s t s v s * t s { + $ * $ * { t t q i t i 9 t t t t t t t t n t t 9o o o F N o r o @ t s @ o o F N o t a @ N a o a F N o s o @ N @ o o r N o s o @ t s @ o o F N o t e @ N @ o o F N o t z 6 6 6 o d 6 6 o 6 o O O O O O O O O O O O O F F N N N N N N N N N N O O O O O OO O O O t + t t t !! o o o o o o o o o o o o @ o @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ o @ @ @ @ o @ o @ @ @ @ @ @ @ @ @ @ @ @ @ @ ?@ o @ @ @ o @ o € @ @ o o o @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ o @ @ o @ @ o o @ @ o o o o @ @ @ @ @ @ @ o o @ o o @ @ q6 0 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 u+ + + a + + - r n r < r $ t t t q t t t i t S i ? t a t t $ $ t { t 3 + + * { + t $ t * $ $ t f at+ + n $ q i t @N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N ,r o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o aF F F ll - - - o o o o o o 18 r 3 3 3 S 3 3 3 fr o o o o o o o o o @@ @ @ @ @ @ o @ @ @ @ @ @ o @ @ o @ @ @ o @ @ o o @ @ @ @ @ @ @ @ @ @ @ @ @ o @ @ @ o @ @ o @ oo o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o 6 6 0 0 0 0 0 0 0 0 0 0 0 3S 3 3 S S S $ S 3 S $ S S S S S S S S T S S S S S S S S S S S S S S S S S $ S S $ S 3 S S S 3 t oN F OO @ N O @ O N T O O O N @ O i O N F O O @ t s O O i o N r o O @ t s @ t O N F O O O N n t @ O t O N F O O @ @ @ @ @ @ @ @o o 6 a o o o lo o o @@ @ @ @@ @ o o @ @ @ o oo @ @@ @ @ @ @ @o @@ o o 60 0 0 0 6 0 b o 6 0 0 oo o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o d) o o o o o o o o o o o at o o o (a o (a (a o o (a (a o o o o o o o o o o o o o o o @@ @ @ @ @ @ @ @ @ @ @ o @ 6 @ @ @ @ @ @ 6 @ O @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ O @ @ @ @ @ @ @ @ G oo o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o 8S s r s 8 t t t t t t t t t t t t t t t t t t t t t t S t r S E S S t S S t t t S t t t t t t S t t t t t t t S NN N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N R 3 E S 3 3 3 3 r N o + 6 @ F @ o F N o rr D o F o o P = S P S p P : P P R F N & N R R N R R B E - N o !r 6 o F 6 o @@ o o @ @ @ 6 @ @ @ @ o @ @ b @ @ @ @ t s N @ @ @ @ @ @ @ @ 6 @ @ @ @ t s @ @ @ @ N N @ @ @ @ @ @ O t t t o o o $ o ss i s v s $ t s v v s s s s t q s t t s s s q s v q s q s q + v v v s t s t v s q s s q s s s O O O o o o o O o : E = = E E E = - E :E E : : = :E :E : I = : E = = = : : : : = :E :E : = = = = : = T : E = E = E E E : = E = = E E = E co o o d d d d d 4 0 0 d o r c o r c d o 4 4 0 a [ [ G c o c c G A c c 4 4 c G 4 q d c e d c c o a e 4 G 4 0 a 4 36 6 6 N 6 6 6 H N N O < O @ N 6 0 d N N O { 6 @ N N 6 0 0 d N N O < 6 @ N N @ 6 6 d N O O i 6 6 0 @ O O d N 0 t Hd d i d n i N N d d q ! q ! i i ! . ! c ! ! , t ! ? 9 ? c ? s ? e s ? g ? e s ? s ? s ? s ? l 9 l t s t a * a i s l y ? y . t p y ? { l e , n s y ? e 9 ? 9 9 9 e e 6i d 6 r b @ { b 6 6 6 d d ( b n i . b ( b 6 r b r b , i d 6 r b G r b 6 ( b ( b , i d . b G r b r b 6 6 . i r 6 ( b , 6 r b r b 6 ( b r i t ( i t 6 ( b 6 ( b , i d d d r F r N 6 ! t d 6 d 6 d 6 ! t v q q n < < t { ! { { { ! { t { { e { s a t I I t I 3 t I { { { t ! t s { ! { t g { { { { { { { { { { { { t { \t t Nd N d d d d d d d N d d N N d N N N d N N N N N N d N N N d d N N N N N N N d d N N d N d d N N N N d N N N N N oo o o o o 6 6 0 0 0 0 0 0 6 0 0 6 0 0 0 0 0 0 6 0 0 0 6 0 0 0 0 0 0 6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 NN N d N N N i d N N N N d N N N N N N N N N N d d d N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N a a D D D D it b i, i, b b b b D b a b b b a b a a b b a it b b b b b i, a D a b b D D a a b a a B a a a D a B a a a D Nd N N N N N N N N N f t d- d N i l N d d N N R N N R N N N N d d N ' i R N N ' N f t dN N f t NN N A N N A f f NN A N oo d o i 6 0 t o t o t o t q t o s t o t q t 0 t o t q t s t o o t q t o r 6 q ' q ' q t q ' o o t q t q t o o 6 0 o ' 0 0 0 0 0 6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 iH i i + + + + s s + s + EE E = = : : : = = E E E = = E = = = E = E E = : r E = = = = = = = = E = E E E E E E = E E E E 6 6 6 6 6 6 6 6 6 o6 6 o 6 o o o o D o o 6 o o 6 o o o o 6 4 4 o o @ o o @ o o o o 4 o o O 4 4 o o Q @ 4 A e Q P N N N N N N f f f r: F N F N N N F N N F F E F T N F t s . F E F T : T : T : T : T : T : E E T F E F E T : F T : T : . E E E F : | : : E E L E t > ' O i ' i ' O O b ' O ? ' i ! o o o o o o o o o o o o o o o o o o 6 o o o o o o o o o o o o o o o o o o o o o o o o o sl l? sl sl >{ i i >< x >l x i x x x x x x x x i i x x x x i x x x i x i i i x i * x x x x x i x x x x x x i x i x x x x x x x x 6 rj 6 6 o o o o o f, f, Ef , f; f, f, f, f f, f; f, f f, f; f, f; f f f, xf , f, f, f 33 t X t f ; f; 3f f, f, f, f f, f, f f f, f; f, f; f xi s d r t r r n r s NN N N N N N N @ @ @ @ @ @ @ @ @ 6 Q O O h O O 6 0 0 0 0 0 0 6 0 0 0 6 0 0 0 0 0 0 A O @ O O A F t s t s N N N t s N N @@ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ o @ @ o @ @ @ o o @ @ @ o @ @ @ @ o o @ @ @ @ @ @ o @ @ @ @ o @ @ @ @ @ @ @ @ @ ts N N F N N F F N N F F N F N F F F T N t s F F t s F N t s N N t s N N N N F N N t s F F t s N t s N F N N F F F t s t s N N N t s N s$ 3 t $ s t S i t t $ $ t 9 $ { q t t 9 s r s $ s $ $ $ t s q $ q s $ $ r $ s s s $ r v t t t 9 v $ $ 9 t t v t 6@ N 6 o o r N o t 6 @ N 6 O 6 F N O + 6 @ N 6 O O F N O t 6 @ N @ O O T N O < O @ N @ O O F N O S O @ t s @ O O F t + t !i + rD O 0 @ 1.. ) 0 ra O @ li. , @ @ @ @ (6 @ (o @ @ @ N N ts N N N ts l- F F @ @ @ @ (O O O @ @ @ O O O O O O O O O O O O (6 6 (o 6 (O @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ O O @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ O O @ @ @ @ @ @ @ @ @ @ O @ @ @ N N @@ @ @ @ @ @ @ o @ @ @ @ @ @ o @ @ @ @ @ @ @ @ @ @ € @ @ @ @ @ @ o @ @ @ o o o @ @ @ @ @ @ o o @ @ o o @ o @ @ @ oo o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o a o o o o o o a o o o o o o o o o o o o o o o o o 9S S $ i t q n 3 { t 3 s t $ 9 $ q s $ t $ t $ t s s t $ s $ $ 9 t $ t s s t s s $ t $ t * i t t t { t $ 9 t * $ NN N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N oo o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o FItr3p'6E@o;,at6lF66tfz_l6ztr)oI (,z=ot IE6:FroIoqo_l=F,&-o,E6=F,E I=_l6o;,ofooecIoGdo;,(zlo@,G6 ,H u E 60 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 s* s 3 s 3 s 3 3 8 3 S 3 t 3 f i Et E t 3 t t 3 r r 3 3 r 3 3 t 3 3 3 3 3 3 r S t S S 3 S r S 3 3 3 3 3 d d5 6 F, ct ct o at o o .' t o o c, o o o at (r ' o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o oo o o o St s E s oo ( , o o N6 6 + o N F o O O N O O A O N F O O € t s O @ $ O N F O O O F @ O S O N F O O @ F O O V O N - O O @ t s @ O t O N F bE h E h h h h E E E E E S 3 E 3 E 3 E E 8 B 3 E E E 3 3 3 3 S 3 S S 3 3 3 3 3 3 3 3 3 3 3 3 3 S S S S S S S S $ oo o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o Q o Q Q o o o o o o o o o o o o o o - 6 - - 6 - o 6 5 6 - 6 - o 6 6 .n o 6 6 6 (- 6 6 6 .q (O o o o o o o o o o o O o o o o o o o o o o o o o o o o o o o ar i ir t ir i a6 ar i a6 i6 a6 i6 di 6 6 aa @ (t @ @ @ @ @ Ct @ @ @ o @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ @ 56 5 5 5 5 5 6 6 6 5 6 6 o 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 o o o o o o o o o o o o o o o o o o o tt 8 8 8 8 8 8 8 8 r 8 8 r 8 8 8 8 8 8 r 8 8 8 8 8 3 t 3 3 s 3 8 3 8 3 r r r r 3 8 8 8 8 3 8 8 8 3 8 3 8 3 3 8 3 N N NN N N N N 6T 6 l N6 l 6 | N NN N NN N NN N NN NN N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N iH d d d d d d d @ @ o H d d d d i i H d i d d d d d d i d d i d n i i H i d i d d i i d i d i i o F N oi o@ N oo o FN & X R& N RR B S - or or o @s o o p : S P : P P : P P R e N & X R R N R R 3 ; g 3 3 3 FF F F F F N tE E E E S E S E - - o E S 3 E t t E E t E t E 3 3 t E 3 S t S H r S t S S 3 E 3 S 3 3 3 r 3 3 3 3 3 3 3 3 E 3 3 E= = : t - : = = E = - - = f , :: = - : : = E : - = t t = E E E = E = = = E = E E E E E = = : E Z : E = E : : E E ad 4 o a d E E G C C d & c o G A f AC A A A f 44 A A d d d d d d d d d d o d o d o o c a d d d d d c c d d d d 6N 6 6 O d d O { O O O N 6 O @ F O O O d N { A @ F O O O H N N 0 S 6 @ r @ O O d N O S O @ t s @ @ O O d N O I O @ 6b 6 5 - d il i i a e n { a ( a I { { o6 o 66 D6 6 6 O O O O O O O O O O O d H H N N N N N N N @- o o @ o @ o @ o @ @ @ @ a @ @ o o o @ o @ o @ @ @ o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o €3 E n < < < ? = < < q t { s { ! s < < ! v Q l s s s s s 9 < s s s ! l ! l l 9 { ! 1 9 ! { l { ! v s s s dd d d d d d d d d N N N N N d N N N d d N d d d d d N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N d6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 0 0 0 0 0 6 0 0 6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 dd N N d d f t id d ( d N N N N N N N d N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N b il a it b a b a a a a a a D a a a D a a a a a a a a a a a a a D a B D a b D a ts a a a D a a B D B a a D a a a B a Nd 6 d N d f t df l fl NN N N N d N N d d N N N N N N N N d N N N d N N N N N N N N N N N N N N N N N N N N N N N N ab b b b b a a ; b b b b b B t s ; b ; B a a a a b b b a a a a ; ; ; ; ; b ; ; ; a ; a b b b ; b b ; b ; b 6 ; ; ; did d H i d n d n i d d d d d d i i d d d d d d d d i H tE E E > E = f E= = E E = = E = E = = = E = t Z > = l = E = = = t = = = = = E = E = = E = f =Z E = E = E Z = : o@ o @ o o o o 6 6 Q @ o o o o o o o 6 o 6 o o @ o @ o 6 6 o o o 6 o 6 6 o o 6 6 o o 6 o Q Q 6 6 o 6 o 6 6 o @ Q F F N F F r ts r N r r r r ts r N r r r r r r r r r r r r r F r r r r r r r r r N N N F l: r a: F F r r F r a: F r: F r: oo o o o o o o o 6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6 0 0 0 0 0 0 0 0 0 ix i x > { i > { > { > i i > { > l > { > a > { > { x i x x i x i x x i > { i > a > a x x > i i l l x x > { > l l X x i > { x { > l > t x r > l x > { i > { X ki ri ir i 6 6 6 6 6 o 6 o 4 6 o o 6 o 6 6 o o 6 o 6 o o o o o 4 o o @ o o @ o 6 o o o 6 6 o o 6 o 6 6 o @ 6 @ o 6 o @ Fia i a i d d c i c i d d a i d o i a i d r i r i c i d e i c i r i c r d d c r c i c t c i a i r i a i c i a t F i a i a i a i c i a i F i c i c i d c i c i e i c i c i d c i c t e i c i d d c i c i r d d d ( d E [ [ u r u r u r L L r [ [ L r L u I r r G r I u I r r L r uL r r r r L L I L r L r I u I r ts t s N N N N t s t s N t s t s N N N t s F t s N N F t s N O O @ O @ @ @ O @ @ @ @ O O @ @ @ @ O @ @ @ @ @ O @ @ @ @ @ @ @ @ @ O 6@ @ @ @ @ @ O 6 @ @ @ @ @ @ @ @ O O O € O 6 0 @ O O O @ O @ @ @ @ O @ @ O @ @ @ @ € @ O @ @ @ @ @ @ @ @ @ @ @ 6 NN N N t s N F F N t s t s t s N N F N t s t s N F t s N F N N F t s N N F F N N N N t s t s N N N F N t s F N t s N t s t s N t s t s t s N F N N n t t t $ { I { t i s Q I n q { I $ \t \t { $ t $ I + t $ t t t t t i { t { i ? ( ? t t q $ $ $ t $ t I t q t t s s No ? 6 @ t s o o o F N O n O @ F @ O O F N O t 0 @ F @ O O F N O S e @ N @ O O F N O + O @ N O O O F N O T O @ N @ oo O O 6o OO F FN N N N NN NN N N OO O O O O OO OO t I t $ $ t i t $ 3 OO O OO OA o 6 NN F N t s N N t s F F N N t s N N N t s N N N N N F t s N N F N N t s N t s N N N N N F t s t s N F F N t s N N N N N N N F F t s N F @@ € @ @ @ @ @ @ o @ @ @ @ @ @ @ @ o 6 @ @ @ @ @ @ o o o @ @ o o o 6 0 @ o @ o @ @ o @ o @ @ o @ @ @ e @ @ @ @ @ oo o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o rr $ $ { r 3 r t + $ { 3 $ t t $ $ $ $ t t t q s t $ 9 t t v t s t { { t s { t t a Q { n t S t t S t t t t ! { i NN N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N oo o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o a o o II=,FU!6E66;aI G6fF I 6d4@=fzIG6zoFslaI (,zoGn'6r=F,rotI(- ,9.oG,o:F,uo4aoI&oUtF,EFzUI=_ld6()looECoEdo-ldGUozUfoUIE@ Eoi, - - - Et t s ja , F d anl6-o o 6 ro o 6 u{ o o o ;B g g 48 8 8 >N N N oltstii d i tsGu@I?8 - o -td6zotrfrf69r n s IoGa6qEEUoG{(,6,EarEF,uoeio,eIrE= - = Fr d L C d'N 6 6 ts d i & i & i 6. 8 N N JO O O =. R R R 5; A A adctI, - - * tr t - - RR R R =o o 6 :l ra ra ra du ? u ? u l a' f l P P Ec^€ o o =6 @ 6 .I F t s t s 85 5 5 u9o o - -6 6 6 =F t s F d8 8 8 AN N T -, o o o 3- - - UTAH DEPARTMENTENI-RONMENIAL QuALlry DIVISION OFATR OUALITY 5l of5l Nucor Reheat 1 Nox 2024 Reference Methods 2, 3A, 6C, 7E, 10, & 19 Source Information Company Name Nucor Steel Company Contact:Doug Jones Contact Phone No.(435) 458-2415 Stack Designation:Reheat Furnace #l Test & Review Dates Test Date:9/26/2024 & Review Date: 11/20/2024 Observer:Unobserved Reviewer:Paul Morris Emission Limits Emission Rates SO2 NOX CO SO2 NOX CO lbs./MMBtu lbs./hr. 15.0 14.316 ppm Percent %O2 Correction as a whole # Test Information Heat Input Stack I.D. inches As ft^2 Y Dl H @ Cp Pbar Pq (static) fuel flow rate (Btu/hr.) Heat Input (Btu/hr.) 108.00 63.617 0.9980 1.824 0.84 25.44 0.29 Contractor Information Contact: Charles Horton Contracting Company: Alliance Technical Group, LLC Address: 3683 W 2270 S, Suite E West Valley City, UT 84120 Phone No.: (464) 352-7568 Project No.: Round Division of Air Quality Instrumental Reference Methods - Gaseous Measurements Method 19 - F factors for Coal, Oil, and Gas Fd Fw Fc scf/MMBtu scf/MMBtu scf/MMBtu Diluent F factor used O2 CO2 Anthrocite 2 Bituminous 2 Lignite Natural Propane Butane 10100 COAL OIL GAS 9780 9860 9190 8710 8710 8710 10540 10640 11950 320 10610 10200 10390 1970 1800 1910 1420 1040 1190 1250 Wet CEM Correct For O2 CO2 Interference w/CO Yes Yes Yes Nucor Reheat 1 Nox 2024 Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Nucor Steel Reheat Furnace #l Average Emission Dry SO2 NOX CO lbs./MMbtu Average % concentration lbs./hr.14.32 CO2 O2 ppm or % 31.89 5.10 12.26 Run 1 Enter O2 or CO2 Dry SO2 NOX CO CO2 O2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 3.690E-06 lbs./hr.14.16 4.84 12.76 ppm or %30.89 4.90 12.64 Run 2 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 3.611E-06 lbs./hr.13.35 4.97 12.52 ppm or %30.23 4.90 12.39 Raw Value Run 3 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 4.128E-06 lbs./hr.15.43 5.48 11.52 ppm or %34.56 5.59 11.42 Raw Value Run 4 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft lbs./hr. ppm or %Raw Value Run 5 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft lbs./hr. ppm or %Raw Value C For Cal Drift Raw Value C For Cal Drift C For Cal Drift C For Cal Drift C For Cal Drift O2 CO2 Clear lbs./MMBTU Nucor Reheat 1 Nox 2024 Calibration Error Test Test Date September 26, 2024 O2 CS - Cal. Span 23.99 Units % Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 0.00 0.00 0.00% Passed Cal. RR02538 09/19/31 Mid-level 11.00 11.00 0.00 0.00% Passed Cal. EB0069884 04/01/32 High-level 23.99 23.99 0.00 0.00% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of CS - Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 45.85% 100% of Cal. Span High-level 100.00% Test Date September 26, 2024 CO2 CS - Cal. Span 23.90 Units % Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 -0.01 0.01 0.042% Passed Cal. RR02538 09/19/31 Mid-level 10.90 11.22 0.32 1.339% Passed Cal. EB0069884 04/01/32 High-level 23.90 23.90 0.00 0.000% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 45.61% 100% of Cal. Span High-level 100.00% Test Date SO2 CS - Cal. Span Units ppm Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level Mid-level High-level % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 40 to 60% of Cal. Span Mid-level 100% of Cal. Span High-level Test Date September 26, 2024 NOx CS - Cal. Span 100.00 Units ppm Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 0.02 0.02 0.020% Passed Cal. EB0011606 09/16/31 Mid-level 50.00 50.06 0.06 0.060% Passed Cal. High-level 100.00 99.92 0.08 0.080% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 50.00% 100% of Cal. Span High-level 100.00% Test Date CO CS - Cal. Span Units ppm Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level Mid-level High-level % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 40 to 60% of Cal. Span Mid-level 100% of Cal. Span High-level Valid Cal Gas Valid Cal Gas Valid Cal Gas Valid Cal Gas Valid Cal Gas Nucor Reheat 1 Nox 2024 Division of Air Quality Stack Test Review ofNucor Steel SO2 NOX CO CO2 O2 Reheat Furnace #l CS Calibration Span 100.00 23.90 23.99 Units ppm ppm ppm % % Unprotected CV - Cylinder Value: SO2 NOX CO CO2 O2Low-Level 0.00 0.00 0.00 Mid-Level 50.00 10.90 11.00 High-Level 100.00 23.90 23.99 0 to 20% of Cal. Span 0.00% 0.00% 0.00% 40 to 60% of Cal. Span 50.0% 45.6% 45.9% 100% of Cal. Span 100.0% 100.0% 100.0% Cdir - Enter Actual Up-scale Cylinder Value Used To Correct Emission Concentration. CDir CMA 50.00 10.90 11.00 Calibration Error Test Cs - Measured Concentration SO2 NOX CO CO2 O2 Low-Level 0.02 -0.01 0.00 Mid-Level 50.06 11.22 11.00High-Level 99.92 23.90 23.99 Enter Up-scale Analyzer Response to be used during testing. ACE Eq. 7E-1 50.06 11.22 11.00 Low-Level 0.02% 0.04% 0.00% ppmdv Difference 0.02 0.01 0 Status Passed Cal. Passed Cal.Passed Cal. Mid-Level 0.06% 1.34% 0.00% ppmdv Difference 0.06 0.32 0 Status Passed Cal. Passed Cal.Passed Cal. High-Level 0.08% 0.00% 0.00% ppmdv Difference 0.08 0 0 Status Passed Cal. Passed Cal.Passed Cal. Pre-Test Sampling System Bias Initial Values SO2 NOX CO CO2 O2 CO - Low-Level 0.08 0.01 0.16 System Bias. SBi - Zero Bias TRUE 0.06% TRUE 0.08% 0.67%± 5% of Span Difference TRUE 0.06 TRUE 0.02 0.16 Pass or Failed Invalid Run Passed Cal. Passed Cal. Passed Cal. CM - Up-scale Gas 48.70 11.01 10.94 SBi - Up-Scale Bias TRUE 1.36% TRUE 0.88% 0.25% Difference TRUE 1.36 TRUE 0.21 0.06 Pass or Failed Invalid Run Passed Cal. Passed Cal. Passed Cal. Raw Test Data Time Start Stop Test Date:9/26/2024 SO2 SO2 NOX CO CO2 O2 NOX30.5 4.9 12.6 CO 0.0% 30.5% 0.0% 20.5% 52.7% CO2/O2 Post-Test System Bias 7E-2 SB=(Cs - Cdir)/CS x 100 Final Values SO2 NOX CO CO2 O2 CO - Low-Level 0.01 0.02 0.14 System Bias. SBi - Zero Bias TRUE 0.01% TRUE 0.13% 0.58%± 5% of Span Difference TRUE 0.0 TRUE 0.0 0.1 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. CM - Up-scale Gas 49.82 11.02 10.90 SBi - Up-Scale Bias TRUE 0.24% TRUE 0.84% 0.42% Difference TRUE 0.2 TRUE 0.2 0.1 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. Calibration Drift % of Span - D=ABS(SBf - SBi) Low-Level Drift TRUE 0.05% TRUE 0.04% 0.08% Drift Difference TRUE 0.1 TRUE 0.0 0.0 3% of Span Pass or Re-Calibrate Pass Pass Pass Up-scale Gas Drift TRUE 1.12% TRUE 0.04% 0.17% Difference TRUE 1.1 TRUE 0.0 0.0 Pass or Re-Calibrate Pass Pass Pass Reheat Furnace #l Flow & Moisture As ft^2 Pbar Pq (static) Ps Avg Ts F CO2 - FCO2 O2 N2+C Md Ms 63.617 25.44 0.29 25.46 710 4.84 12.76 82.40 29.28 28.17 Y Cp Vm cf Vlc AVG Tm F Vm std Vw std Bws S Bws 268.7255 0.9980 0.84 36.190 72.50 60 31.170 3.413 0.0987 0.9990 0.999 Load - Megawatts Avg. √∆P's Vs (ft/sec.)Qsw scfh wet Qa acfm Qsd dscfh Heat InputBtu/hr Low Mid High 0.5279 48.420 4,259,075 184,820 3,838,794.00 Enert > #1 - Times Date Point No.∆P √∆P ts F tm F (in) tm F (out) Final Vf Initial Vi 1 0.20 0.447 708 69 66 776 725 50.820.22 0.469 708 70 48 711 701 9.9 3 0.29 0.539 709 70 47 645 642 3.7 4 0.37 0.608 710 70 47 949 941 8.1 5 0.39 0.624 710 70 47 6 0.33 0.574 711 70 48 7 0.35 0.592 712 69 48 8 0.15 0.387 712 69 49 9 0.23 0.480 709 69 49 10 0.28 0.529 709 68 50 11 0.36 0.600 709 68 51 12 0.40 0.632 710 68 51 13 0.34 0.583 710 68 53 14 0.30 0.548 710 15 0.20 0.447 710 16 0.15 0.387 711 17 18 1920 21 22 23 24 Failed Bias Dialog Failed Drift Dialog Failed Cal Error Dialog CO Calibration Gas Failed Bias Dialog Nucor Reheat 1 Nox 2024 Division of Air Quality Stack Test Review ofNucor Steel SO2 NOX CO CO2 O2 Reheat Furnace #l CS Calibration Span 100.00 23.90 23.99 Units ppm ppm ppm % % CV - Cylinder Value:SO2 NOX CO CO2 O2Low-Level 0.00 0.00 0.00Mid-Level 50.00 10.90 11.00 High-Level 100.00 23.90 23.99 0 to 20% of Cal. Span 0.00% 0.00% 0.00% 40 to 60% of Cal. Span 50.0% 45.6% 45.9%100% of Cal. Span 100.0% 100.0% 100.0% Cdir - Enter Actual Up-scale Cylinder Value Used To Correct Emission Concentration. CMA 50.00 10.90 11.00 Calibration Error Test Measured Concentration SO2 NOX CO CO2 O2Low-Level 0.02 -0.01 0.00 Mid-Level 50.06 11.22 11.00 High-Level 99.92 23.90 23.99 Enter Up-scale Analyzer Response to be used during testing. ACE Eq. 7E-1 50.06 11.22 11.00 Low-Level 0.02% 0.04% 0.00% ppmdv Difference 0.02 0.01 0 Status Passed Cal. Passed Cal.Passed Cal. Mid-Level 0.06% 1.34% 0.00% ppmdv Difference 0.06 0.32 0 Status Passed Cal. Passed Cal.Passed Cal. High-Level 0.08% 0.00% 0.00% ppmdv Difference 0.08 0 0 Status Passed Cal. Passed Cal.Passed Cal. Pre-Test Sampling System Bias Initial Values SO2 NOX CO CO2 O2 CO - Low-Level 0.01 0.02 0.14 System Bias. SBi - Zero Bias TRUE 0.01% TRUE 0.13% 0.58%± 5% of Span Difference TRUE 0.01 TRUE 0.03 0.14 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. CM - Up-scale Gas 49.82 11.02 10.90 SBi - Up-Scale Bias TRUE 0.24% TRUE 0.84% 0.42% Difference TRUE 0.24 TRUE 0.2 0.1 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. Raw Test Data Time Start Stop Test Date:9/26/2024 SO2 SO2 NOX CO CO2 O2 NOX 30.1 5.1 12.4 CO 0.0% 30.1% 0.0% 21.1% 51.6% CO2/O2 Post-Test System Bias 7E-2 SB=(Cs - Cdir)/CS x 100 Final Values SO2 NOX CO CO2 O2 CO - Low-Level 0.01 0.01 0.14 System Bias. SBi - Zero Bias TRUE 0.01% TRUE 0.08% 0.58%± 5% of Span Difference TRUE 0.0 TRUE 0.0 0.1 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. CM - Up-scale Gas 49.76 11.08 10.91 SBi - Up-Scale Bias TRUE 0.30% TRUE 0.59% 0.38% Difference TRUE 0.3 TRUE 0.1 0.1 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. Calibration Drift % of Span - D=ABS(SBf - SBi) Low-Level Drift TRUE 0.00% TRUE 0.04% 0.00% Response Spec. Difference TRUE 0.0 TRUE 0.0 0.0 3% of Span Pass or Re-Calibrate Pass Pass Pass Up-scale Gas Drift TRUE 0.06% TRUE 0.25% 0.04% Difference TRUE 0.1 TRUE 0.1 0.0 Pass or Re-Calibrate Pass Pass Pass Reheat Furnace #l Flow & Moisture As ft^2 Pbar Pq (static) Ps Avg Ts F CO2 - FCO2 O2 N2+C Md Ms 63.62 25.44 0.29 25.46 711 4.97 12.52 82.51 29.30 28.20 Y Cp Vm cf Vlc AVG Tm F Vm std Vw std Bws S Bws 269.7301 0.9980 0.84 35.953 70.90 61 30.936 3.337 0.0974 0.9990 0.999 Load - Megawatts Avg. √∆P's Vs Qsw scfh wet Qa acfm Qsd dscfh Heat Input Btu/hr Low Mid High 0.5083 46.60 4,096,798 177,873 3,697,883.39 Enert > #1 - Times Date Point No.∆P √∆P ts F tm F (in) tm F (out) Final Vf Initial Vi 1 0.20 0.447 709 68 60 819 776 43.5 2 0.24 0.490 709 68 52 723 711 12.3 3 0.29 0.539 709 68 50 650 645 4.940.34 0.583 710 69 50 960 949 10.2 5 0.40 0.632 710 69 50 6 0.29 0.539 710 69 51 7 0.20 0.447 711 69 51 8 0.18 0.424 712 69 52 9 0.20 0.447 710 68 52 10 0.27 0.520 709 68 53 11 0.32 0.566 710 68 54 12 0.39 0.624 711 67 55 13 0.30 0.548 711 67 56 14 0.24 0.490 712 15 0.19 0.436 713 16 0.16 0.400 712 17 1819 20 21 22 23 24 Failed Bias Dialog Failed Drift Dialog Failed Cal Error Dialog Failed Bias Dialog Nucor Reheat 1 Nox 2024 Division of Air Quality Stack Test Review ofNucor Steel SO2 NOX CO CO2 O2 Reheat Furnace #l CS Calibration Span 100.00 23.90 23.99 Units ppm ppm ppm % % CV - Cylinder Value:SO2 NOX CO CO2 O2Low-Level 0.00 0.00 0.00Mid-Level 50.00 10.90 11.00 High-Level 100.00 23.90 23.99 0 to 20% of Cal. Span 0.00% 0.00% 0.00% 40 to 60% of Cal. Span 50.0% 45.6% 45.9%100% of Cal. Span 100.0% 100.0% 100.0% Cdir - Enter Actual Up-scale Cylinder Value Used To Correct Emission Concentration. CMA 50.00 10.90 11.00 Calibration Error Test Measured Concentration SO2 NOX CO CO2 O2Low-Level 0.02 -0.01 0.00 Mid-Level 50.06 11.22 11.00 High-Level 99.92 23.90 23.99 Enter Up-scale Analyzer Response to be used during testing. ACE Eq. 7E-1 50.06 11.22 11.00 Low-Level 0.02% 0.04% 0.00% ppmv Difference 0.02 0.01 0 Status Passed Cal. Passed Cal.Passed Cal. Mid-Level 0.06% 1.34% 0.00% ppmv Difference 0.06 0.32 0 Status Passed Cal. Passed Cal.Passed Cal. High-Level 0.08% 0.00% 0.00% ppmv Difference 0.08 0 0 Status Passed Cal. Passed Cal.Passed Cal. Pre-Test Sampling System Bias Initial Values SO2 NOX CO CO2 O2 CO - Low-Level 0.01 0.01 0.14 System Bias. SBi - Zero Bias TRUE 0.01% TRUE 0.08% 0.58%± 5% of Span Difference TRUE 0.01 TRUE 0.02 0.14 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. CM - Up-scale Gas 49.76 11.08 10.91 SBi - Up-Scale Bias TRUE 0.30% TRUE 0.59% 0.38% Difference TRUE 0.3 TRUE 0.14 0.09 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. Raw Test Data Time Start Stop Test Date:9/26/2024 SO2 SO2 NOX CO CO2 O2 NOX 34.3 5.6 11.4 CO 0.0% 34.3% 0.0% 23.4% 47.6% CO2/O2 Post-Test System Bias 7E-2 SB=(Cs - Cdir)/CS x 100 Final Values SO2 NOX CO CO2 O2 CO - Low-Level 0.02 0.04 0.16 System Bias. SBi - Zero Bias TRUE 0.00% TRUE 0.21% 0.67%± 5% of Span Difference TRUE 0.0 TRUE 0.1 0.2 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. CM - Up-scale Gas 49.46 11.09 10.92 SBi - Up-Scale Bias TRUE 0.60% TRUE 0.54% 0.33% Difference TRUE 0.6 TRUE 0.1 0.1 Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal. Calibration Drift % of Span - D=ABS(SBf - SBi) Low-Level Drift TRUE 0.01% TRUE 0.13% 0.08% Response Spec. Difference TRUE 0.0 TRUE 0.0 0.0 3% of Span Pass or Re-Calibrate Pass Pass Pass Up-scale Gas Drift TRUE 0.30% TRUE 0.04% 0.04% Difference TRUE 0.3 TRUE 0.0 0.0 Pass or Re-Calibrate Pass Pass Pass Reheat Furnace #l Flow & Moisture As ft^2 Pbar Pq (static) Ps Avg Ts F CO2 - FCO2 O2 N2+C Md Ms 63.62 25.44 0.29 25.46 711 5.48 11.52 83.00 29.34 28.14 Y Cp Vm cf Vlc AVG Tm F Vm std Vw std Bws S Bws 269.9313 0.9980 0.84 36.026 77.10 65 30.760 3.629 0.1055 0.9990 0.999 Load - Megawatts Avg. √∆P's Vs Qsw scfh wet Qa acfm Qsd dscfh Heat Input Btu/hr Low Mid High 0.5179 47.54 4,178,991 181,461 3,737,979.80 Enert > #1 - Times Date Point No.∆P √∆P ts F tm F (in) tm F (out) Final Vf Initial Vi 1 0.19 0.436 710 70 64 783 736 46.2 2 0.23 0.480 710 70 57 737 723 13.9 3 0.27 0.520 711 70 54 656 650 5.340.35 0.592 711 71 54 971 960 11.7 5 0.38 0.616 711 71 55 6 0.36 0.600 711 72 55 7 0.21 0.458 711 72 56 8 0.17 0.412 710 72 57 9 0.24 0.490 710 72 58 10 0.28 0.529 710 72 59 11 0.32 0.566 711 71 60 12 0.40 0.632 710 71 61 13 0.33 0.574 710 71 63 14 0.25 0.500 711 15 0.21 0.458 712160.18 0.424 711 17 1819 20 21 22 23 24 Failed Bias Dialog Failed Cal Error Dialog Failed Drift Dialog Failed Bias Dialog