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DAQ-2024-011638
1 DAQC-1144-24 Site ID 101073 (B4) MEMORANDUM TO: STACK TEST FILE – XCL ASSETCO, LLC – Shiner 30-3A-22 Pad THROUGH: Rik Ombach, Minor Source Oil and Gas Compliance Section Manager FROM: Paul Bushman, Environmental Scientist DATE: November 13, 2024 SUBJECT: Source: One (1) Waukesha F3524GSI engine Contact: Lauren Brown: (713) 808-9406 Location: Duchesne County, UT Test Contractor: Oasis Emission Consultants, Inc. Permit/AO#: Permit by Rule Action Code: TR Subject: Review of stack test report dated August 26, 2024 On October 22, 2024, Utah Division of Air Quality (DAQ) received a test report for one (1) Waukesha F3524GSI engine at Shiner 30-3A-22 Pad, Duchesne County, Utah. Testing was performed August 19, 2024, to demonstrate compliance with the emission limits found in Utah Administrative Code R307-510 and 40 CFR Part 60, Subpart JJJJ. The calculated test results are: Source Test Date Pollutant Method Tester Results DAQ Results Limits Waukesha F3524GSI SN: WAU-1661569 August 19, 2024 NOx 320 0.12 g/bhp-hr 0.117 g/bhp-hr 1.0 g/bhp-hr CO 320 0.07 g/bhp-hr 0.065 g/bhp-hr 2.0 g/bhp-hr VOC 320 0.01 g/bhp-hr 0.007 g/bhp-hr 0.7 g/bhp-hr DEVIATIONS: None. CONCLUSION: The stack test report appears to be acceptable. RECOMMENDATION: The emissions from the Waukesha F3524GSI engine should be considered to have been in compliance with the emission limits of UAC R307-510 and 40 CFR Part 60, Subpart JJJJ during testing. ATTACHMENTS: DAQ stack test review excel spreadsheets, XCL AssetCo, LLC stack test report. Emissions XCL Resources Shiner 30-3A-22 Pad Duchesne County Waukesha F3524GSI; SN: WAU-1661569 Test Date: 8/19/2024 Run #1 2 3 Average Start Time 16:52 17:52 18:52 Stop Time 17:52 18:52 19:52 Sample Duration (minutes)60 60 60 BHP Engine Load - Actual (bhp) 874 882 874 876 DS Stack Diameter (inches)8.0 8.0 8.0 8.0PAVG Average (Delta P)½ (" H2O)½0.8300 0.8540 0.8270 0.8370 CP Pitot Tube Constant (unitless)0.84 0.84 0.84 0.84 TS Stack Temperature (°F)754 764 768 762 Pbar Barometric Pressure (" Hg)24.72 24.71 24.72 24.72 Ps Stack Pressure ('' H2O)0.29 0.31 0.29 0.30 O2%vd O2 (%vd)1.0 1.0 1.0 1.0 CO2%vd CO2 (%vd)11.3 11.3 11.3 11.3 N2%vd N2 (%vd)87.7 87.7 87.7 87.7 dry NOX (ppmvd)64.5 55.0 75.8 65.1 dry CO (ppmvd) 84.4 38.9 54.7 59.3 wet NMEOC (ppmvw as C3H8)3.8 3.2 2.4 3.1 Run #1 2 3 Average Bws Measured Moisture Content (%/100)0.194 0.190 0.186 0.190 Bws Saturated Moisture Content (%/100)329.328 347.518 354.808 343.884 Bws Actual Moisture Content (%/100)0.194 0.190 0.186 0.190 MD Molecular Weight Dry (lb/lb-mole)29.85 29.85 29.85 29.85 MA Molecular Weight Wet (lb/lb-mole)27.55 27.60 27.64 27.60 VS Gas Velocity (ft/sec)79.5 82.1 79.6 80.4 FACFM Gas Flow (acfm)1666 1720 1667 1684 FDSCFM Gas Flow (dscfm)483 496 482 487 FWSCFM Gas Flow (wscfm)599 613 592 602 FKWSCFH Gas Flow (kwscfh)36 37 36 36 FKWSCFM Gas Flow (kwscfm)0.599 0.613 0.592 0.602 lb/hr Gas Flow (lb/hr) 2570 2636 2550 2585 Fo Fo (unitless)1.761 1.761 1.761 1.761 wet O2 (%vw)0.8 0.8 0.8 0.8 wet CO2 (%vw)9.1 9.2 9.2 9.2 wet NOX (ppmvw)51.960 44.593 61.703 52.752 15 NOX (ppmvd @ 15% O2)19.108 16.318 22.485 19.304 82.0 lb/hr NOX (lb/hr)0.223 0.196 0.262 0.227 g/bhp-hr NOX (g/bhp-hr)0.116 0.101 0.136 0.117 1.0 wet CO (ppmvw) 68.003 31.476 44.512 47.997 15 CO (ppmvd @ 15% O2)25.008 11.518 16.221 17.582 270.0 lb/hr CO (lb/hr) 0.177 0.084 0.115 0.125 g/bhp-hr CO (g/bhp-hr) 0.092 0.043 0.060 0.065 2.0 dry NMEOC (ppmvd as C3H8)4.680 3.910 2.920 3.837 dry NMEOC (ppmvd as C3H8)4.680 3.910 2.920 3.837 15 NMEOC (ppmvd as C3H8 @ 15% O2)1.388 1.159 0.866 1.138 60.0 lb/hr NMEOC (lb/hr as C3H8)0.015 0.013 0.010 0.013 g/bhp-hr NMEOC (g/bhp-hr as C3H8)0.008 0.007 0.005 0.007 0.7 Permit Limits Field Reference Method Data Reference Method Calculations Page 1 of 1 Source Test Report For XCL Resources Shiner #30-3A-22 Pad Duchesne County, Utah Test Date: August 19, 2024 Report Date: August 26, 2024 Federal Regulation: EPA 40 CFR 60, Subpart JJJJ Engine: Waukesha F3524GSI SN: WAU-1661569 Unit ID: 804058 (101073) Prepared By: Oasis Emission Consultants, Inc. 2730 Commercial Way Rock Springs, WY 82901 August 26, 2024 Mr. Ryan Sokolowski XCL Resources Dear Mr. Sokolowski: Re: Engine Emission Testing For XCL Resources, Shiner #30-3A-22 Pad, Unit 804058 (101073), EPA 40 CFR 60, Subpart JJJJ. An air emissions test program was conducted on a Waukesha F3524GSI engine, operated by XCL Resources and designated as Unit 804058 (101073), located at the Shiner #30-3A-22 Pad in Duchesne County, Utah. The purpose of the testing was to demonstrate compliance with the emissions limits contained in EPA 40 CFR 60, Subpart JJJJ, for oxides of nitrogen (NOx), carbon monoxide (CO) and volatile organic compounds (VOC). Oasis Emission Consultants, Inc. conducted the testing on August 19, 2024. EPA 40 CFR 60, Subpart JJJJ Emission Levels The average recorded levels were found to comply with emission levels stipulated in the permit, as shown in the attached report and summarized below. Emission Unit Avg NOx Permit NOx Avg CO Permit CO Avg NMNEHC* Permit VOC g/bhp-hr 0.12 1.0 0.07 2.0 0.01 0.7 *VOC levels reported as non-methane, non-ethane hydrocarbon on a propane basis (NMNEHC C3). Catalyst Parameters (Averaged Over 3 Test Runs) Inlet Temp (deg F) DP (in H2O) 763 0.6 Engine Load (Averaged Over 3 Test Runs) Rated BHP Operating BHP % Load 840 876.4 104.3 Testing Protocol The attached report was generated using an extractive FTIR system using methodologies as required by and in accordance with EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320 as outlined in the submitted Source Test Protocol. Quality Assurance Oasis has performed a full review of the raw data and calculated results in this report. Any errors we have encountered have been listed in the body of this report. After performing the review, we are confident that this engine has met all requirements. If you have any questions or require further information, please contact the undersigned at (307) 382-3297. Yours truly, Oasis Emission Consultants, Inc. _________________________ _______________________ Charles A. Chapman Cember Crawley Manager of Technical Services Environmental Scientist _________________________ Christopher N. Knott, P.Eng. Director, Engineering and Operations SOURCE EMISSION TEST REPORT FEDERAL REGULATION EPA 40 CFR 60, Subpart JJJJ Test Performed By: Oasis Emission Consultants, Inc. Test Company Contact: Chris Knott 2730 Commercial Way Rock Springs, WY 82901 307.382.3297 Owner/Operator: XCL Resources Owner/Operator Contact: Ryan Sokolowski Facility Name: Shiner #30-3A-22 Pad Duchesne County, Utah Emission Source: Waukesha F3524GSI Unit 804058 (101073) Date of Test: August 19, 2024 Date of Report: August 26, 2024 TABLE OF CONTENTS 1.1 Introduction .......................................................................................................................... 1 2.1 Stack Sampling Location ..................................................................................................... 2 3.1 Discussion of NOx, CO and VOC Test Results ................................................................... 4 3.1.1 Source Test 1 ............................................................................................................................................ 4 3.1.2 Source Test 2 ............................................................................................................................................ 4 3.1.3 Source Test 3 ............................................................................................................................................ 4 4.1 Stack Sampling Methods and Procedures ............................................................................ 5 4.2 Equipment Utilization .......................................................................................................... 6 4.3 Measurement of VOC (NMNEHC C3) ............................................................................... 7 4.4 Process Parameters ............................................................................................................... 7 5.1 Quality Assurance ................................................................................................................ 8 List of Tables and Figures Figure 1 - Sample Port Location ............................................................................................................................. 2 Figure 2 - Sampling Train Schematic-Method 320 ................................................................................................. 6 Table 1 - Insertion Depths of Traverse Points for Stratification Test ..................................................................... 3 Table 2 - Location of Traverse Points in Circular Stacks ....................................................................................... 3 Table 3 - Test Matrix .............................................................................................................................................. 5 Table 4 - Concentrations and Interference .............................................................................................................. 6 APPENDIX A: NOx, CO and VOC Test Data APPENDIX B: Quality Assurance/Calibration Data APPENDIX C: Load Approximation APPENDIX D: Example Calculations and Summary APPENDIX E: Field Notes 1 1.1 Introduction An air emissions test program was conducted on a Waukesha F3524GSI engine, operated by XCL Resources and designated as Unit 804058 (101073), located at the Shiner #30-3A-22 Pad in Duchesne County, Utah. The purpose of the testing was to demonstrate compliance with the emissions limits contained in EPA 40 CFR 60, Subpart JJJJ, for oxides of nitrogen (NOx), carbon monoxide (CO) and volatile organic compounds (VOC) defined as non- methane, non-ethane hydrocarbons, reported as propane (NMNEHC C3). The facility is currently located in Duchesne County, Utah. Three one hour test runs were performed on August 19, 2024 to analyze NOx, CO and VOC emission levels. Test runs were performed according to methodologies outlined by EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320 as outlined in the submitted Source Test Protocol. Each one hour test run consisted of 60 readings taken at one minute intervals. Process parameters were recorded during each test run in order to determine the load. Parameters include the engine panel load percent reading. The following key personnel were present during testing: Jordan Nix, OEC Branden A 2 2.1 Stack Sampling Location The facility is currently located in Duchesne County, Utah. Testing was conducted on the Waukesha F3524GSI engine. The sampling port for moisture, NOx, CO and VOC measurements was approximately 3.5 pipe diameters (28”) downstream from the nearest flow disturbance (Distance B) and 2.6 pipe diameters (21”) upstream from the nearest disturbance (Distance A), as seen in Figure 1. The stack sampling location was placed at approximately 50% insertion depth based on an O2 stratification check which demonstrated a non-stratified flow regime. The stratification was conducted according to EPA 40 CFR 75(A), §6.5.6.1 using 3 traverse points determined according to Table 1 below. In accordance with EPA 40 CFR 60(A), Method 1, a total of 16 traverse insertion depths (8 traverse points through each of the 2 ports) were determined according to Table 2 below in order to conduct Method 2. Figure 1 - Sample Port Location 8" A B 3 Table 1 - Insertion Depths of Traverse Points for Stratification Test Traverse Point Insertion Depth (Percent of Stack Diameter) 1 16.6 2 50.0 3 83.3 Table 2 - Location of Traverse Points in Circular Stacks 4 3.1 Discussion of NOx, CO and VOC Test Results Three, one hour test runs were performed on August 19, 2024 to analyze exhaust NOx, CO and VOC (NMNEHC C3) emission levels to demonstrate compliance with the emissions limits contained in EPA 40 CFR 60, Subpart JJJJ. Testing for NOx, CO and VOC were run concurrently with one another. Each test was performed at the maximum achievable load. Measured emissions were below permitted limits. Please refer to the Appendices for a listing of all raw data, calibration error response and calculations performed per EPA 40 CFR 60(A) requirements. 3.1.1 Source Test 1: Waukesha F3524GSI, NOx, CO and VOC The first test was performed from 16:52 to 17:51 for NOx, CO and VOC. Based on operating parameters recorded during testing, the load was approximated at 873.6 bhp, and the average NOx and CO levels were found to be 0.12 g/bhp-hr and 0.09 g/bhp-hr respectively, below limitations. The VOC level tested at 0.01 g/bhp- hr, which tested in compliance. 3.1.2 Source Test 2: Waukesha F3524GSI, NOx, CO and VOC The second test was performed from 17:52 to 18:51 for NOx, CO and VOC. Based on operating parameters recorded during testing, the load was approximated at 882.0 bhp, and the average NOx and CO levels were found to be 0.10 g/bhp-hr and 0.04 g/bhp-hr respectively, below limitations. The VOC level tested at 0.01 g/bhp- hr, which tested in compliance. 3.1.3 Source Test 3: Waukesha F3524GSI, NOx, CO and VOC The third test was performed from 18:52 to 19:51 for NOx, CO and VOC. Based on operating parameters recorded during testing, the load was approximated at 873.6 bhp, and the average NOx and CO levels were found to be 0.14 g/bhp-hr and 0.06 g/bhp-hr respectively, below limitations. The VOC level tested at 0.01 g/bhp- hr, which tested in compliance. Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) VOC (ppmvd) VOC (g/bhp-hr) O2 (%) 1 64.45 0.12 84.35 0.09 4.68 0.01 1.0 Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) VOC (ppmvd) VOC (g/bhp-hr) O2 (%) 2 55.04 0.10 38.85 0.04 3.91 0.01 1.0 Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) VOC (ppmvd) VOC (g/bhp-hr) O2 (%) 3 75.84 0.14 54.71 0.06 2.92 0.01 1.0 5 4.1 Stack Sampling Methods and Procedures Testing followed EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320, with no exceptions. Table 3 - Test Matrix Method Title Parameter Reference EPA 40 CFR 60 Appendix A, Method 1 Sample and Velocity Traverses for Stationary Sources Sampling Point Determination https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_1_3.pdf EPA 40 CFR 60 Appendix A, Method 2 Determination of Stack Gas Velocity and Volumetric Flow Rate Exhaust Effluent Flow https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_2.pdf EPA 40 CFR 60 Appendix A, Method 3 Gas Analysis for the Determination of Dry Molecular Weight O2, CO2, Dry Volumetric Flow Rate https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_3.pdf EPA 40 CFR 63 Appendix A, EPA Method 320 Vapor Phase Organic and Inorganic Emissions by Extractive FTIR Nitrogen Oxides, Carbon Monoxide, Non- Methane Non- Ethane Hydrocarbons on a Propane Basis https://www.epa.gov/ emc/method-320- vapor-phase-organic- and-inorganic- emissions-extractive- ftir United States. U.S. Environmental Protection Agency. “EMC Promulgated Test Methods.” Air Emission Measurement Center (EMC). 31 August 2023. Web. 26 August 2024. <https://www.epa.gov/emc/emc-promulgated-test-methods>. 6 4.2 Equipment Utilization The following equipment was used during the tests performed at this facility in conjunction with procedures outlined by EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320. • (1) MKS MultiGas 2030 FTIR Continuous Gas Analyzer (0.210 L/min sample flow, 0.014 atmosphere sample pressure, 1 atmosphere cell pressure, 191°C cell temperature) • (1) Laptop Computer for the FTIR Analyzer using MKS MG2000 Software • (1) 75ft or 100ft Heated Teflon Line w/ Heated Sample Probe and Spike Bypass Line • S-Type Pitot Tube c/w 20 ft. Heated Sample Line (coefficient 0.84) • (1) Fyrite O2/CO2 Analyzer • (5) EPA Protocol G1 Calibration Gas (NOx, CO, C3H8, C2H4 and NO2) The MKS Multigas 2030 FTIR Analyzer operated with a spectral resolution of 0.5 cm-1 and a scan time of 30 seconds. The FTIR spectrometer utilizes a multi-pass gas cell with a 5.11 meter effective pathlength. Figure 2 - Sampling Train Schematic-Method 320 Table 4 - Concentrations and Interference 7 The MKS 2030 software provides a Natural Gas Method that is designed to minimize all expected interferences by removing the regions in the quant region where they are most absorbed (i.e. picket fence approach). So, for example, all the water peaks that are greater than about 0.1 abs are removed from the quant region. Since the spectral noise measured (sample spectrum) is in the range of 0.001 absorbance, it is desirable to have any error within this range. The MKS software will match the water calibration spectrum to the sample spectrum at any 1 point in the spectrum to about 1% precision. So, 1% of 0.1 absorbance is 0.001 abs. This is why any peaks greater than this for interfering compounds are usually excluded so they do not interfere. To summarize, the MKS software and the method are designed to minimize any interferences by removing their largest interfering absorptions. 4.3 Measurement of VOC (NMNEHC C3) The algorithm currently used for NMNEHC C3 and developed for natural gas fired applications by Dr. Spartz and MKS instruments in accordance with EPA standards, is the following: (2.4*c8/(1+exp((2-c8)/0.2))+1.9*c11/(1+exp((2-c11)/0.2))+6*c12/(1+exp((0.5-c12) /0.2))+2.85*c13/(1+exp((2-c13)/0.2))+3*c14/(1+exp((1-c14)/0.2)))/3 c8= acetylene c11= ethylene c12= hexane c13= propylene c14= propane Note: The constants in front of each of the compounds listed represents the FID response factor when calibrated with Propane. As with any CEMS analyzer, the FTIR may demonstrate a negative zero bias. The “exp” functions listed in the algorithm above are intended to mathematically filter out any negative biases and set them to approach zero. 4.4 Process Parameters Process parameters were recorded during each test run in order to determine the load. Parameters include the engine panel load percent reading. Results are provided in Appendix C. 8 5.1 Quality Assurance The MKS Multigas 2030 FTIR Analyzer was used to measure NOx, CO and VOC on a dry basis. A pre Direct and System calibration measurement was made on compounds of NOx, CO, C3H8 and C2H4. In addition, post System calibrations were made on compounds of NOx, CO, C3H8 and C2H4. Compounds of CO2 and C3H8 were measured for the quality assurance spiking requirements. Levels for calibrations and zeroes must be within +/- 5% of the certified calibration gas or response to zero gas, respectively. CTS procedures were followed according to EPA requirements for both pre and post testing. Similarly, QA spiking procedures were followed. Analysis of the CO2 exhaust effluent was used to determine the dilution factor. Steady levels of the CO2 were observed and a sufficient duration of time was allowed to elapse for a representative average. The calibration gas was spiked into the effluent stream using a bypass line at approximately 10% of the sampling rate. The dilution factor was obtained from observation of the stack CO2 behavior using the following equation: CO2AVG – CO2SPIKE DF = ------------------------ CO2 AVG Where: CO2AVG = The average undiluted CO2 stack gas concentration of spike measurements CO2SPIKE = The average diluted CO2 stack gas concentration when spiked The sample recovery was then obtained from the following equation: % REC = (Spike MEAS – Stack MEAS)* (1 – DF) --------------------------------------------------------- CS * DF Where: Spike MEAS = The average diluted stack gas concentration when spiked Stack MEAS = The average undiluted stack gas concentration DF = Dilution factor CS = Certified concentration of calibration standards The Sample Recovery average level for C3H8 was found to be 76.9%, which was within the allowable tolerance of Method 320 (70% to 130%). A summary of all spiking procedures/results can be found in Appendix B. APPENDIX A NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 59.532401 1.026815 60.559216 791.584299 6.175138 21.089568 16:52:35 08/19/2024 2 53.611948 0.787176 54.399124 600.252551 4.262954 19.057611 16:53:35 08/19/2024 3 47.486789 0.826153 48.312942 417.294916 5.648211 20.206394 16:54:35 08/19/2024 4 46.983067 1.01934 48.002407 404.651563 5.371528 20.873545 16:55:35 08/19/2024 5 44.083948 0.876749 44.960697 276.808681 4.543257 18.7472 16:56:35 08/19/2024 6 42.721378 0.972551 43.693929 168.891953 6.192902 21.617183 16:57:36 08/19/2024 7 39.981501 0.618912 40.600413 115.004043 4.794211 18.097776 16:58:36 08/19/2024 8 40.843313 0.977647 41.82096 102.127751 4.878243 19.666127 16:59:36 08/19/2024 9 39.976233 0.888705 40.864938 92.609897 5.256154 19.3131 17:00:36 08/19/2024 10 44.060489 0.803784 44.864273 49.740563 5.068075 18.14566 17:01:36 08/19/2024 11 42.337873 0.737534 43.075407 44.878558 3.642838 17.95261 17:02:36 08/19/2024 12 45.542724 0.833741 46.376465 42.596094 4.926396 18.554042 17:03:36 08/19/2024 13 47.026404 1.059789 48.086193 40.211768 5.683822 21.130698 17:04:37 08/19/2024 14 50.246546 0.987189 51.233735 39.286472 4.530110 19.987246 17:05:37 08/19/2024 15 61.111083 0.816337 61.92742 36.552316 4.165295 19.055142 17:06:37 08/19/2024 16 54.557629 0.731767 55.289396 37.269905 5.000579 18.545596 17:07:37 08/19/2024 17 93.870367 0.755593 94.62596 36.485744 5.312898 18.740764 17:08:37 08/19/2024 18 154.783074 0.541838 155.324912 35.043638 5.137425 20.849328 17:09:37 08/19/2024 19 40.505518 0.670194 41.175712 41.55186 3.431985 17.076217 17:10:37 08/19/2024 20 55.286553 0.638475 55.925028 41.113158 4.896313 16.75993 17:11:37 08/19/2024 21 114.102621 0.655948 114.758569 35.731256 4.927057 17.623161 17:12:37 08/19/2024 22 78.811671 0.762912 79.574583 36.593956 5.026150 18.770177 17:13:38 08/19/2024 23 141.547798 0.541336 142.089134 33.005757 4.907384 16.792703 17:14:38 08/19/2024 24 108.35924 0.823651 109.182891 34.700187 5.128816 20.048409 17:15:38 08/19/2024 25 79.821442 0.821904 80.643346 34.296422 3.570586 18.492405 17:16:38 08/19/2024 26 51.287193 0.844273 52.131466 39.158304 5.341053 21.095019 17:17:38 08/19/2024 27 52.621272 0.95868 53.579952 37.198085 3.652443 19.868581 17:18:38 08/19/2024 28 52.635411 0.921941 53.557352 36.959625 4.707765 20.023128 17:19:38 08/19/2024 29 66.736798 0.913468 67.650266 35.424912 4.211873 19.684011 17:20:39 08/19/2024 30 84.624209 1.294229 85.918438 37.38488 6.730596 22.685219 17:21:39 08/19/2024 31 78.992909 0.880315 79.873224 34.837546 4.417175 19.811264 17:22:39 08/19/2024 32 43.53391 0.904325 44.438235 40.662109 5.376380 18.856069 17:23:39 08/19/2024 33 73.860339 0.831688 74.692027 35.382885 5.025223 18.529409 17:24:39 08/19/2024 34 41.568999 0.896002 42.465001 47.373876 4.820201 19.317677 17:25:39 08/19/2024 35 49.192299 0.872088 50.064387 38.205891 4.960100 19.126556 17:26:39 08/19/2024 36 46.13228 1.011964 47.144244 40.652573 5.282424 19.859615 17:27:39 08/19/2024 37 38.784207 1.157237 39.941444 44.688575 5.697107 20.505767 17:28:40 08/19/2024 38 42.728316 1.076455 43.804771 45.382443 5.491845 20.369216 17:29:40 08/19/2024 39 41.578816 1.111215 42.690031 72.108435 5.214569 19.356763 17:30:40 08/19/2024 40 47.084912 0.838164 47.923076 43.296859 3.873505 18.660893 17:31:40 08/19/2024 41 124.351764 0.914165 125.265929 45.744668 5.157951 18.96485 17:32:40 08/19/2024 42 69.66738 0.716089 70.383469 46.46445 4.058674 17.842619 17:33:40 08/19/2024 43 159.896474 0.71043 160.606904 38.263468 4.644997 17.4374 17:34:40 08/19/2024 44 97.183634 0.609113 97.792747 96.833425 5.500419 16.856919 17:35:40 08/19/2024 45 87.507025 0.775551 88.282576 34.14253 3.477763 18.219899 17:36:41 08/19/2024 46 88.020309 0.927458 88.947767 33.25759 4.099683 19.052705 17:37:41 08/19/2024 47 47.902789 0.987821 48.89061 38.158677 3.758508 19.711175 17:38:41 08/19/2024 48 40.385936 1.011444 41.39738 45.855151 2.518973 18.69965 17:39:41 08/19/2024 49 46.678349 0.957303 47.635652 41.799444 3.124564 19.775297 17:40:41 08/19/2024 50 41.943691 0.999071 42.942762 40.4352 4.973491 21.265752 17:41:41 08/19/2024 51 54.190757 1.095891 55.286648 35.734876 6.081230 20.369338 17:42:42 08/19/2024 52 62.001049 1.267834 63.268883 35.210481 6.207614 20.916294 17:43:41 08/19/2024 53 56.730266 1.1188 57.849066 35.677215 5.438157 20.781575 17:44:42 08/19/2024 54 48.997217 1.304154 50.301371 36.787054 5.276085 21.38748 17:45:42 08/19/2024 55 65.101202 0.964878 66.06608 35.418458 5.095599 20.737421 17:46:42 08/19/2024 56 55.595638 0.961105 56.556743 46.160192 3.186422 19.35866 17:47:42 08/19/2024 57 50.411676 0.908317 51.319993 45.235507 2.829399 19.08678 17:48:42 08/19/2024 58 74.726612 0.907011 75.633623 35.258225 3.735196 19.524586 17:49:42 08/19/2024 59 50.02975 0.816712 50.846462 38.539948 2.171473 18.721578 17:50:42 08/19/2024 60 53.448045 1.08494 54.532985 38.935987 2.460478 19.17249 17:51:43 08/19/2024 AVG 63.56 0.90 64.45 84.35 4.68 19.38 ppm@15% O2 19.11 25.01 1.39 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.12 0.22 0.09 0.18 0.01 0.02 804058 (101073) FTIR Measurements Calculated Emission Levels XCL Resources Shiner #30-3A-22 Pad Run 1 Record Date EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 8 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 0.51 1214 0.29 0.714 Average O2 1.0 (% dry)A 2 0.84 0.60 0.775 Average CO2 11.3 (% dry)A 3 1.55 0.63 0.794 Average N2 + CO 87.7 (% dry)A 4 2.58 0.66 0.812 Dry Molecular Weight 29.85 lb/lbmol A 5 5.42 0.71 0.843 Wet Molecular Weight 27.55 lb/lbmol A 6 6.45 0.77 0.877 EPA REFERENCE METHOD 320 A 7 7.16 0.80 0.894 Barometric Pressure 24.72 in Hg A 8 7.50 0.73 0.854 Moisture Content 19.38 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 64.45 ppm A 11 Calculated NOx Mass Output 0.22 lbs/hr A 12 Calculated NOx Output 0.12 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 84.35 ppm A 15 Calculated CO Mass Output 0.18 lbs/hr A 16 Calculated CO Output 0.09 g/bhp-hr B 1 0.50 0.62 1214 0.29 0.787 EPA REFERENCE METHOD 320 B 2 0.84 0.58 0.762 Average Analyzer NMNEHC Level 4.68 ppm B 3 1.55 0.65 0.806 Calculated NMNEHC Mass Output 0.02 lbs/hr B 4 2.58 0.79 0.889 Calculated NMNEHC Output 0.01 g/bhp-hr B 5 5.42 0.76 0.872 LOAD APPROXIMATION B 6 6.45 0.81 0.900 Estimated Engine Load 873.6 BHP B 7 7.16 0.75 0.866 B 8 7.50 0.70 0.837 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 0.7 1214 0.3 0.830 Average Stack Gas Velocity 79.56 ft/sec Average Dry Flowrate 483.11 dscfm TEST RUN # 1 NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 41.857584 0.898113 42.755697 50.455784 3.287216 18.879905 17:52:43 08/19/2024 2 42.464436 0.858465 43.322901 40.313517 2.823360 18.848285 17:53:43 08/19/2024 3 43.137329 0.881098 44.018427 43.553663 4.322871 19.091751 17:54:43 08/19/2024 4 65.774974 0.876416 66.65139 35.582755 3.234627 18.490817 17:55:43 08/19/2024 5 46.413707 0.851301 47.265008 40.2179 4.434250 18.364037 17:56:43 08/19/2024 6 75.40616 0.74909 76.15525 34.299347 4.111961 17.82444 17:57:43 08/19/2024 7 52.20465 0.78457 52.98922 39.248949 3.380393 18.713715 17:58:43 08/19/2024 8 43.217768 0.783954 44.001722 43.011996 3.287898 17.602041 17:59:44 08/19/2024 9 47.744049 0.725612 48.469661 38.892996 4.668144 17.756615 18:00:44 08/19/2024 10 42.137351 0.917507 43.054858 39.500763 2.985592 19.369147 18:01:44 08/19/2024 11 48.220918 0.852973 49.073891 36.96108 3.256352 19.682149 18:02:44 08/19/2024 12 44.639324 0.85769 45.497014 43.821284 3.710774 19.329416 18:03:44 08/19/2024 13 59.36506 0.876254 60.241314 35.805294 4.569228 19.248329 18:04:44 08/19/2024 14 59.995183 0.796268 60.791451 35.284035 4.317975 18.272362 18:05:44 08/19/2024 15 43.160009 0.750641 43.91065 38.463932 5.021570 17.578021 18:06:44 08/19/2024 16 50.186307 0.812762 50.999069 37.944216 5.041449 18.728789 18:07:45 08/19/2024 17 66.45305 0.657885 67.110935 34.829224 5.061757 18.507761 18:08:45 08/19/2024 18 54.799233 0.876343 55.675576 36.58928 5.009995 18.883616 18:09:45 08/19/2024 19 48.026805 0.973629 49.000434 42.348878 4.742550 20.486461 18:10:45 08/19/2024 20 57.096962 0.780881 57.877843 36.508699 4.199016 18.483056 18:11:45 08/19/2024 21 50.94767 0.730214 51.677884 39.57931 5.682108 18.570115 18:12:45 08/19/2024 22 48.263215 0.672616 48.935831 39.009049 5.272028 18.218995 18:13:45 08/19/2024 23 56.716637 0.893828 57.610465 36.896782 4.596543 19.052733 18:14:46 08/19/2024 24 77.181911 0.854659 78.03657 35.405047 3.752796 18.703494 18:15:46 08/19/2024 25 59.474447 0.786828 60.261275 35.691257 4.926100 18.278753 18:16:46 08/19/2024 26 62.653779 0.863469 63.517248 36.191815 5.025412 18.774619 18:17:46 08/19/2024 27 53.95529 0.926316 54.881606 38.792567 4.258203 18.694106 18:18:46 08/19/2024 28 52.052088 1.014366 53.066454 38.119432 5.473004 19.551096 18:19:46 08/19/2024 29 51.905168 1.075035 52.980203 37.066399 5.583707 19.67591 18:20:46 08/19/2024 30 59.78801 1.335735 61.123745 36.073966 7.274255 22.086487 18:21:46 08/19/2024 31 61.111075 0.827543 61.938618 35.530586 5.645550 18.5463 18:22:47 08/19/2024 32 50.925731 0.746169 51.6719 36.918919 3.961175 17.96849 18:23:47 08/19/2024 33 53.060518 0.77608 53.836598 37.463055 5.702339 18.510863 18:24:47 08/19/2024 34 50.47872 1.005099 51.483819 43.447067 6.489613 20.318569 18:25:47 08/19/2024 35 44.473035 0.746796 45.219831 46.242471 4.627638 18.687755 18:26:47 08/19/2024 36 41.115843 0.605549 41.721392 43.15631 4.928043 18.905237 18:27:47 08/19/2024 37 44.43587 0.764833 45.200703 41.197067 4.148862 19.559519 18:28:47 08/19/2024 38 59.196004 0.662105 59.858109 36.249713 3.088190 19.003334 18:29:47 08/19/2024 39 53.041174 0.859048 53.900222 39.965024 4.429079 19.983229 18:30:48 08/19/2024 40 44.67231 0.730537 45.402847 43.133972 2.799804 18.088832 18:31:48 08/19/2024 41 48.90248 0.746498 49.648978 40.301221 3.653273 19.001339 18:32:48 08/19/2024 42 47.816269 0.747182 48.563451 39.675702 2.831954 18.416609 18:33:48 08/19/2024 43 53.237879 0.645111 53.88299 39.080325 2.538459 17.909016 18:34:48 08/19/2024 44 84.576713 1.126014 85.702727 35.099016 4.852464 21.885298 18:35:48 08/19/2024 45 63.483954 0.848831 64.332785 34.743689 3.935683 20.510511 18:36:48 08/19/2024 46 63.749097 0.880391 64.629488 35.98982 2.678316 19.111023 18:37:48 08/19/2024 47 57.911264 0.929872 58.841136 36.459847 2.483982 19.094648 18:38:49 08/19/2024 48 48.147602 0.896137 49.043739 39.279374 2.299712 19.305561 18:39:49 08/19/2024 49 46.42013 0.868133 47.288263 41.386903 2.419313 19.442208 18:40:49 08/19/2024 50 48.000064 1.099743 49.099807 41.947265 2.455358 19.842031 18:41:49 08/19/2024 51 43.302773 0.787098 44.089871 44.497495 2.816283 18.538935 18:42:49 08/19/2024 52 49.097467 0.923782 50.021249 40.276572 2.427137 18.262187 18:43:49 08/19/2024 53 56.172681 0.951167 57.123848 37.376655 2.458047 19.226827 18:44:49 08/19/2024 54 70.435351 0.812148 71.247499 35.568414 1.559588 18.858772 18:45:50 08/19/2024 55 53.33242 0.908431 54.240851 36.773634 2.784313 19.062667 18:46:50 08/19/2024 56 57.496323 0.719881 58.216204 36.638389 2.365253 18.04999 18:47:50 08/19/2024 57 47.515481 0.82171 48.337191 38.193972 2.582287 18.553029 18:48:50 08/19/2024 58 64.614624 1.032591 65.647215 34.547272 3.740951 20.025561 18:49:50 08/19/2024 59 89.358482 0.987352 90.345834 34.55946 2.208145 19.000136 18:50:50 08/19/2024 60 50.078498 1.126024 51.204522 48.581955 2.392375 19.683739 18:51:50 08/19/2024 AVG 54.19 0.85 55.04 38.85 3.91 18.98 ppm@15% O2 16.32 11.52 1.16 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.10 0.20 0.04 0.08 0.01 0.01 Calculated Emission Levels Record Date XCL Resources Shiner #30-3A-22 Pad Run 2 804058 (101073) FTIR Measurements EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 8 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 0.62 1224 0.31 0.787 Average O2 1.0 (% dry)A 2 0.84 0.66 0.812 Average CO2 11.3 (% dry)A 3 1.55 0.68 0.825 Average N2 + CO 87.7 (% dry)A 4 2.58 0.76 0.872 Dry Molecular Weight 29.85 lb/lbmol A 5 5.42 0.79 0.889 Wet Molecular Weight 27.60 lb/lbmol A 6 6.45 0.86 0.927 EPA REFERENCE METHOD 320 A 7 7.16 0.81 0.900 Barometric Pressure 24.71 in Hg A 8 7.50 0.75 0.866 Moisture Content 18.98 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 55.04 ppm A 11 Calculated NOx Mass Output 0.20 lbs/hr A 12 Calculated NOx Output 0.10 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 38.85 ppm A 15 Calculated CO Mass Output 0.08 lbs/hr A 16 Calculated CO Output 0.04 g/bhp-hr B 1 0.50 0.58 1224 0.31 0.762 EPA REFERENCE METHOD 320 B 2 0.84 0.63 0.794 Average Analyzer NMNEHC Level 3.91 ppm B 3 1.55 0.69 0.831 Calculated NMNEHC Mass Output 0.01 lbs/hr B 4 2.58 0.77 0.877 Calculated NMNEHC Output 0.01 g/bhp-hr B 5 5.42 0.88 0.938 LOAD APPROXIMATION B 6 6.45 0.74 0.860 Estimated Engine Load 882.0 BHP B 7 7.16 0.79 0.889 B 8 7.50 0.69 0.831 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 0.7 1224 0.3 0.854 Average Stack Gas Velocity 82.10 ft/sec Average Dry Flowrate 496.72 dscfm TEST RUN # 2 NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 60.2555 0.960885 61.216385 38.032095 2.584075 19.613685 18:52:50 08/19/2024 2 49.970252 0.735533 50.705785 42.808666 2.386527 18.396754 18:53:51 08/19/2024 3 41.120647 0.819955 41.940602 45.806436 2.264653 18.054686 18:54:51 08/19/2024 4 58.117567 0.739863 58.85743 36.571494 3.018564 18.398713 18:55:51 08/19/2024 5 44.158128 1.038339 45.196467 41.128193 2.321712 19.377899 18:56:51 08/19/2024 6 41.513942 0.733929 42.247871 44.264808 2.591854 18.759615 18:57:51 08/19/2024 7 42.83206 1.051824 43.883884 50.724755 2.811168 20.451691 18:58:51 08/19/2024 8 66.205101 0.684745 66.889846 37.163772 2.840670 17.876415 18:59:51 08/19/2024 9 55.804715 1.141506 56.946221 41.948243 3.329474 20.23097 19:00:52 08/19/2024 10 41.366847 0.723706 42.090553 42.175955 2.692490 17.681851 19:01:52 08/19/2024 11 53.626532 0.735004 54.361536 38.281126 5.333268 20.519409 19:02:52 08/19/2024 12 49.796565 0.766074 50.562639 39.068356 2.656409 18.231437 19:03:52 08/19/2024 13 55.213258 0.656889 55.870147 37.080284 2.648970 17.368266 19:04:52 08/19/2024 14 49.131385 0.828617 49.960002 38.60695 2.253407 19.050799 19:05:52 08/19/2024 15 51.155263 0.508705 51.663968 38.344676 2.334530 16.152865 19:06:52 08/19/2024 16 50.072032 0.50354 50.575572 39.605184 3.217349 16.189444 19:07:52 08/19/2024 17 61.089041 0.79131 61.880351 35.643845 3.466534 18.93003 19:08:53 08/19/2024 18 58.715094 0.945044 59.660138 35.702573 3.565577 20.014021 19:09:53 08/19/2024 19 52.193266 0.944907 53.138173 38.014977 3.339203 19.166849 19:10:53 08/19/2024 20 43.200336 0.769015 43.969351 42.228151 3.198524 18.528871 19:11:53 08/19/2024 21 59.849219 0.677734 60.526953 37.771583 2.841038 17.979967 19:12:53 08/19/2024 22 51.210872 0.858592 52.069464 37.332761 3.192956 18.594659 19:13:53 08/19/2024 23 53.170028 0.800771 53.970799 37.932177 4.545981 17.279602 19:14:53 08/19/2024 24 52.607651 0.954966 53.562617 36.298002 4.317891 20.063046 19:15:53 08/19/2024 25 51.126435 0.885896 52.012331 41.122549 3.659621 18.421273 19:16:54 08/19/2024 26 71.24912 0.891662 72.140782 34.821917 4.386354 20.077872 19:17:54 08/19/2024 27 53.124139 0.940955 54.065094 39.184168 3.275829 18.516065 19:18:54 08/19/2024 28 45.43184 0.975471 46.407311 54.678118 2.676397 19.09494 19:19:54 08/19/2024 29 90.423737 1.068951 91.492688 68.660807 2.682322 18.902742 19:20:54 08/19/2024 30 367.905274 0.893317 368.798591 88.967777 2.975685 18.14323 19:21:54 08/19/2024 31 338.425202 0.896967 339.322169 157.765415 3.172877 18.335468 19:22:54 08/19/2024 32 296.717228 0.796069 297.513297 42.642791 2.710183 17.243742 19:23:54 08/19/2024 33 65.446563 0.834432 66.280995 58.548777 3.009729 18.886767 19:24:55 08/19/2024 34 55.199345 0.914079 56.113424 36.582679 3.867552 21.154192 19:25:55 08/19/2024 35 98.261906 0.921009 99.182915 37.808597 2.445532 18.920502 19:26:55 08/19/2024 36 49.601802 0.770459 50.372261 38.119889 2.625443 17.694305 19:27:55 08/19/2024 37 46.277968 0.876784 47.154752 43.325243 3.134789 18.721167 19:28:55 08/19/2024 38 67.565853 0.923311 68.489164 36.518531 3.270968 20.072634 19:29:55 08/19/2024 39 62.651975 0.685097 63.337072 35.873994 2.602273 18.658908 19:30:55 08/19/2024 40 71.206169 1.005101 72.21127 38.07041 2.700655 18.792092 19:31:55 08/19/2024 41 74.583153 0.715604 75.298757 34.420083 2.449218 17.528094 19:32:56 08/19/2024 42 57.632833 0.796321 58.429154 35.889575 2.600473 17.532554 19:33:56 08/19/2024 43 47.654239 0.867362 48.521601 37.724691 2.893699 19.937993 19:34:56 08/19/2024 44 46.180188 0.902912 47.0831 39.351093 2.371415 18.545784 19:35:56 08/19/2024 45 140.529569 0.917122 141.446691 52.687213 2.631684 19.900106 19:36:56 08/19/2024 46 74.43427 0.958203 75.392473 274.724449 2.954028 20.43632 19:37:56 08/19/2024 47 281.423128 0.898547 282.321675 501.171382 2.571601 19.026447 19:38:56 08/19/2024 48 62.268428 0.837224 63.105652 73.331797 2.618655 19.130967 19:39:57 08/19/2024 49 50.644771 0.949194 51.593965 39.738948 2.261866 20.112539 19:40:57 08/19/2024 50 73.738693 0.98124 74.719933 36.083807 2.520119 19.394366 19:41:57 08/19/2024 51 53.357499 0.825863 54.183362 35.502653 2.679878 18.812359 19:42:57 08/19/2024 52 55.791707 0.769875 56.561582 34.783649 2.717020 18.023176 19:43:57 08/19/2024 53 51.823778 0.74484 52.568618 35.191838 2.625271 17.459564 19:44:57 08/19/2024 54 52.639377 0.746813 53.38619 35.150898 2.915739 18.144435 19:45:57 08/19/2024 55 59.010781 0.756645 59.767426 34.79138 2.848342 17.014449 19:46:57 08/19/2024 56 49.731824 0.574361 50.306185 34.722853 2.245834 16.605583 19:47:58 08/19/2024 57 51.253382 0.595996 51.849378 34.570642 2.180846 16.112547 19:48:58 08/19/2024 58 46.206666 0.796512 47.003178 35.700996 2.673444 19.395546 19:49:58 08/19/2024 59 48.776258 0.681912 49.45817 35.913683 2.457439 18.359481 19:50:58 08/19/2024 60 50.030804 0.784032 50.814836 36.033045 2.836674 18.283905 19:51:58 08/19/2024 AVG 75.01 0.83 75.84 54.71 2.92 18.64 ppm@15% O2 22.49 16.22 0.86 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.14 0.26 0.06 0.11 0.01 0.01 FTIR Measurements 804058 (101073) Calculated Emission Levels XCL Resources Shiner #30-3A-22 Pad Run 3 Record Date EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 8 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 0.55 1228 0.29 0.742 Average O2 1.0 (% dry)A 2 0.84 0.61 0.781 Average CO2 11.3 (% dry)A 3 1.55 0.64 0.800 Average N2 + CO 87.7 (% dry)A 4 2.58 0.69 0.831 Dry Molecular Weight 29.85 lb/lbmol A 5 5.42 0.73 0.854 Wet Molecular Weight 27.64 lb/lbmol A 6 6.45 0.76 0.872 EPA REFERENCE METHOD 320 A 7 7.16 0.71 0.843 Barometric Pressure 24.72 in Hg A 8 7.50 0.66 0.812 Moisture Content 18.64 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 75.84 ppm A 11 Calculated NOx Mass Output 0.26 lbs/hr A 12 Calculated NOx Output 0.14 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 54.71 ppm A 15 Calculated CO Mass Output 0.11 lbs/hr A 16 Calculated CO Output 0.06 g/bhp-hr B 1 0.50 0.58 1228 0.29 0.762 EPA REFERENCE METHOD 320 B 2 0.84 0.66 0.812 Average Analyzer NMNEHC Level 2.92 ppm B 3 1.55 0.61 0.781 Calculated NMNEHC Mass Output 0.01 lbs/hr B 4 2.58 0.75 0.866 Calculated NMNEHC Output 0.01 g/bhp-hr B 5 5.42 0.78 0.883 LOAD APPROXIMATION B 6 6.45 0.82 0.906 Estimated Engine Load 873.6 BHP B 7 7.16 0.73 0.854 B 8 7.50 0.70 0.837 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 0.7 1228 0.3 0.827 Average Stack Gas Velocity 79.60 ft/sec Average Dry Flowrate 482.29 dscfm TEST RUN # 3 APPENDIX B Date Time NO 191C span NO2 191C span H2O% (high) 191C Formaldehyde 191C Ethylene 191C TE span Propane 191C span Acetaldehyde 191C span CO ppm 191C (1of2) spanCO ppm Dry CO2% 191C NOx Wet NOx Dry NM NE HC C3 Temp ( C )Pressure (atm)8/19/2024 16:06:04 -0.118814 -0.055702 -0.014631 0.162426 0.568447 -0.047025 0.273427 -0.149301 -0.149279 0.000331 -0.174516 -0.17449 0.024962 191.041809 0.9686638/19/2024 16:06:12 0.055805 0.030559 -0.016655 0.063512 0.218843 -0.23978 0.703403 0.093941 0.093925 0.013378 0.086364 0.086349 0.021781 191.073471 0.9679348/19/2024 16:06:19 0.007525 -0.021764 -0.012368 -0.136411 -0.413605 0.274537 -0.583726 -0.147271 -0.147252 0.010662 -0.01424 -0.014238 0.014446 191.073471 0.968023 8/19/2024 16:06:27 -0.04455 0.041117 -0.008717 0.093655 -0.362911 -0.509013 -0.211059 -0.032646 -0.032643 0.008003 -0.003433 -0.003433 0.000386 191.073471 0.9681838/19/2024 16:07:04 0 0 0 0 0 0 0 0 0 0 0 0 0 191.073471 0.968364 8/19/2024 16:07:17 -0.11807 0.052847 -0.004035 0.070675 -0.643903 -0.043817 -0.176451 0.085679 0.085676 0.001716 -0.065222 -0.06522 0.019148 191.073471 0.9682498/19/2024 16:07:25 -0.139693 -0.018363 -0.003789 0.123653 -0.634868 -0.312547 0.115805 0.13021 0.130205 0.000411 -0.158055 -0.158049 0.359237 191.073471 0.9682388/19/2024 16:07:32 0.086422 -0.040902 0.000833 0.030518 0.576178 0.004078 -0.270142 0.018135 0.018135 -0.000366 0.045521 0.045521 0.004082 191.073471 0.9679678/19/2024 16:07:40 -0.045079 0.031742 -0.009756 -0.056328 0.223224 -0.44425 -0.062802 0.060709 0.060703 0.004987 -0.013337 -0.013336 0.025686 191.073471 0.9676188/19/2024 16:07:47 -0.108719 -0.036015 -0.002925 0.063598 0.711955 0.421007 -0.143267 0.249774 0.249767 0.001696 -0.144734 -0.14473 0.024892 191.073471 0.96818/19/2024 16:07:55 0.046472 -0.029486 -0.003808 -0.020332 0.675833 -0.509152 0.301475 -0.089753 -0.089749 0.005927 0.016986 0.016985 0.029318 191.073471 0.9678368/19/2024 16:08:02 0.056166 -0.004162 -0.001193 0.061413 -0.219021 -0.072869 -0.053947 -0.012432 -0.012432 -0.003676 0.052004 0.052004 0.001777 191.073471 0.967836 8/19/2024 16:08:10 0.093696 -0.013818 0.000979 0.062015 0.241869 -0.205547 -0.647368 0.026291 0.026292 -0.006635 0.079878 0.079879 2.56184 191.073471 0.9682788/19/2024 16:08:17 0.236901 -0.006329 -0.006073 -0.03568 -0.284083 -0.102076 -0.127618 0.087345 0.08734 0.005476 0.230572 0.230558 0.001277 191.073471 0.968008 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/19/2024 16:08:39 322.802405 324.561184 291.002712 191.05069 1.001667 8/19/2024 16:11:45 59.996397 191.00354 1.0041328/19/2024 16:08:46 467.140001 470.433151 461.995577 190.978104 1.009245 8/19/2024 16:11:52 91.351397 191.00354 1.004097 8/19/2024 16:08:54 498.547041 502.616286 493.413748 190.978104 1.009509 8/19/2024 16:12:00 97.569669 191.00354 1.003798/19/2024 16:09:02 504.888136 509.074558 498.382169 190.978104 1.009411 8/19/2024 16:12:07 99.036355 191.00354 1.0037388/19/2024 16:09:09 505.931494 511.020425 498.184902 190.978104 1.00962 8/19/2024 16:12:15 99.651488 191.00354 1.0043178/19/2024 16:09:17 506.593293 510.835679 499.138332 190.978104 1.009744 8/19/2024 16:12:22 99.533857 191.00354 1.0039338/19/2024 16:09:24 506.744859 510.933906 499.031702 190.978104 1.006365 8/19/2024 16:12:30 99.224217 191.00354 1.0041028/19/2024 16:09:32 505.823435 511.002471 497.589482 190.953461 1.003785 8/19/2024 16:12:37 98.965141 191.010681 1.0040098/19/2024 16:09:39 506.292232 511.308747 499.039199 190.882736 1.004306 8/19/2024 16:12:45 99.997387 191.018982 1.00387 8/19/2024 16:09:47 507.33173 511.869172 497.884267 190.882736 1.00428 8/19/2024 16:12:52 99.755146 191.026245 1.003901 Date Time NO2 191C span Temp ( C )Pressure (atm)8/19/2024 16:10:12 67.499916 190.840347 1.0036778/19/2024 16:10:19 121.748398 190.787369 1.0047328/19/2024 16:10:27 137.392751 190.788162 1.004041 8/19/2024 16:10:34 141.707423 190.8564 1.0041088/19/2024 16:10:42 143.461071 190.866837 1.0044158/19/2024 16:10:49 144.599418 190.936325 1.0039458/19/2024 16:10:57 145.079753 190.930878 1.0041778/19/2024 16:11:04 145.142709 190.91362 1.0043728/19/2024 16:11:12 145.949729 190.927246 1.0040598/19/2024 16:11:19 146.369694 190.927246 1.004062 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/19/2024 16:13:12 0.7735 1.441521 -0.05189 191.053864 0.996111 8/19/2024 16:14:40 62.603309 190.971741 1.0031738/19/2024 16:13:20 140.84802 154.842273 119.300748 191.079834 1.005146 8/19/2024 16:14:48 91.769601 190.971741 1.0043178/19/2024 16:13:27 424.68379 426.27506 412.116964 191.039871 1.001334 8/19/2024 16:14:55 97.689502 191.014435 1.0043698/19/2024 16:13:35 486.924897 491.906625 483.922782 190.990814 1.001958 8/19/2024 16:15:03 99.027015 191.054398 1.004102 8/19/2024 16:13:43 501.383206 506.39369 495.483057 190.990814 1.002866 8/19/2024 16:15:10 98.885634 191.054398 1.0041058/19/2024 16:13:50 503.62051 508.914856 496.437837 190.990814 1.002576 8/19/2024 16:15:18 99.830314 191.004333 1.004272 8/19/2024 16:13:57 507.535533 511.44985 499.440102 190.990814 1.00251 8/19/2024 16:15:25 99.858689 190.95903 1.0043468/19/2024 16:14:05 506.654938 511.514417 498.078926 190.990814 1.003175 8/19/2024 16:15:33 99.931967 191.006256 1.004518/19/2024 16:14:12 506.657493 510.986965 499.942389 190.99173 1.002705 8/19/2024 16:15:40 99.38204 191.035324 1.00448/19/2024 16:14:20 507.192445 510.616816 497.030183 191.009888 1.003024 8/19/2024 16:15:48 98.914587 191.035324 1.004099 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Ethylene 191C TE Temp ( C )Pressure (atm)8/19/2024 16:16:10 0.477268 0.831731 0.888839 6.414436 190.968109 1.0014958/19/2024 16:16:18 0.192691 0.639013 0.145281 1.209779 191.022614 1.0015218/19/2024 16:16:25 0.18134 0.187407 -0.155894 0.781108 191.022614 1.0020498/19/2024 16:16:33 0.138905 0.226287 -0.130064 0.697508 191.022614 1.0019438/19/2024 16:16:40 0.282903 0.103984 0.299622 0.056442 191.022614 1.001475 8/19/2024 16:16:48 -0.072814 0.068048 0.769899 -0.283084 191.022614 1.0021098/19/2024 16:16:56 0.091191 0.132081 -0.153317 -0.247402 191.022614 1.001931 8/19/2024 16:17:03 0.122254 0.062585 -0.385987 -0.115947 191.022614 1.001937 Raw Calibration Data BACKGROUND / PRE DIRECT ZERO PRE DIRECT CAL NO2 CAL PRE SYSTEM CAL PRE SYSTEM ZERO Date Time CO2% 191C Propane 191C span Temp ( C )Pressure (atm) 8/19/2024 16:40:41 10.352002 -1.21317 191.022614 0.9977128/19/2024 16:40:48 10.329741 -0.904682 191.022614 0.9973688/19/2024 16:40:56 10.348185 -1.103695 191.022614 0.9974148/19/2024 16:43:26 10.283731 -0.29732 191.022614 0.9971768/19/2024 16:43:34 10.111449 0.026446 191.022614 1.0025358/19/2024 16:43:41 5.027232 155.2273 191.022614 1.0070688/19/2024 16:43:49 1.528287 371.197783 191.022614 0.99396 8/19/2024 16:43:56 5.185134 206.753721 191.022614 0.9945028/19/2024 16:44:04 8.192102 87.724673 191.022614 0.9968488/19/2024 16:44:11 8.980044 56.809433 191.022614 0.9974578/19/2024 16:44:19 9.165419 50.383584 191.022614 0.997668/19/2024 16:44:26 9.187802 48.462305 191.022614 0.9977618/19/2024 16:44:34 9.286512 43.710353 191.022614 0.9979238/19/2024 16:44:41 9.339646 40.962465 191.022614 0.998171 8/19/2024 16:44:56 9.255954 39.488568 191.022614 0.9955468/19/2024 16:45:04 9.147679 38.448517 191.022614 0.995546 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/19/2024 20:03:25 301.73999 294.433885 267.287255 190.908173 1.005032 8/19/2024 20:01:56 64.969444 190.993469 0.9502068/19/2024 20:03:33 462.88031 462.122925 456.586821 190.908173 1.004538 8/19/2024 20:02:03 90.82851 190.990814 1.006365 8/19/2024 20:03:40 494.462677 496.82486 488.127844 190.908173 1.005347 8/19/2024 20:02:11 96.582597 190.990814 1.0079318/19/2024 20:03:48 502.124276 504.530121 492.59526 190.908173 1.005032 8/19/2024 20:02:18 97.722928 190.990814 1.0081388/19/2024 20:03:55 501.808224 506.911976 489.419207 190.908173 1.00492 8/19/2024 20:02:26 98.46944 190.990814 1.0090478/19/2024 20:04:03 504.02114 507.556331 493.158916 190.908173 1.005795 8/19/2024 20:02:33 98.936555 190.990814 1.0089088/19/2024 20:04:10 504.049307 507.40699 490.112697 190.908173 1.005218 8/19/2024 20:02:41 98.68733 190.974472 1.0079898/19/2024 20:04:18 504.196675 507.340969 491.471765 190.908173 1.004689 8/19/2024 20:02:48 98.327165 190.932693 1.0080588/19/2024 20:04:25 503.620259 505.845307 492.253041 190.908173 1.004492 8/19/2024 20:02:56 98.938138 190.908173 1.008431 8/19/2024 20:04:33 504.085125 506.33198 491.690333 190.908173 1.005333 8/19/2024 20:03:03 99.235326 190.908173 1.007515 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/19/2024 20:02:11 0.404945 0.549183 -0.180508 190.990814 1.007931 8/19/2024 20:05:09 -1.037583 190.908173 0.992098/19/2024 20:02:18 0.036589 0.123806 -1.418764 190.990814 1.008138 8/19/2024 20:05:16 -0.186733 190.908173 0.9908888/19/2024 20:02:26 -0.131599 0.215095 -0.898432 190.990814 1.009047 8/19/2024 20:05:24 -0.229093 190.908173 0.992065 8/19/2024 20:02:33 0.095555 0.351181 -0.407156 190.990814 1.008908 8/19/2024 20:05:31 -0.435903 190.908173 0.9923288/19/2024 20:02:41 -0.084662 0.178502 -0.714547 190.974472 1.007989 8/19/2024 20:05:39 -0.699604 190.943924 0.9919528/19/2024 20:02:48 -0.010796 0.090954 -0.587952 190.932693 1.008058 8/19/2024 20:05:46 -0.263728 190.984467 0.9923248/19/2024 20:02:56 0.047202 0.435099 -0.359496 190.908173 1.008431 8/19/2024 20:05:54 -0.034352 190.984467 0.9917448/19/2024 20:03:03 0.117976 0.247881 -1.425961 190.908173 1.007515 8/19/2024 20:06:01 -0.836123 190.984467 0.992279 POST SYSTEM ZERO SAMPLE SPIKE RECOVERY POST SYSTEM CAL PRE TEST 1 501.6 10.3 -0.6 9.2 42.2 0.100 76.9% Sensor Analyzer Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Error (%)Error (%) NOx 511.9 512.4 0.0 -0.10 0.00 CO 507.3 507.5 0.1 -0.03 0.01 Propane 497.9 501.6 -0.1 -0.74 -0.03 Ethylene 99.8 101.90 0.1 -2.10 0.11 Sensor System Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Recovery (%)Error (%) NOx 510.6 512.4 0.3 -0.35 0.06 CO 507.2 507.5 0.2 -0.06 0.04 Propane 497.0 501.6 0.2 -0.91 0.05 Ethylene*98.9 101.90 1.2 -2.93 1.21 Sensor System Cal Zero Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Recovery (%)Error (%)Drift Error (%)Drift Error (%) NOx 506.3 512.4 0.3 -1.18 0.05 0.84 0.01 CO 504.1 507.5 0.1 -0.67 0.01 0.61 0.03 Propane 491.7 501.6 -0.7 -1.98 -0.13 1.06 0.18 Ethylene*99.2 101.90 -0.5 -2.61 -0.51 0.31 1.72 *CTS Scans are conducted with Ethylene through the sample line. Stack Propane Concentration Stack + Spike CO2 Concentration Stack + Propane Concentration DF Calculated POST SYSTEM CAL PRE SYSTEM CAL % Recovery Propane PRE DIRECT CAL FTIR QA/QC SUMMARY SAMPLE RECOVERY CALCULATIONS Period Spike #Concentration of Propane Cylinder Stack CO2 Concentration XCL - Shiner #30-3A-22 Pad 8-19-24 XCL - Shiner #30-3A-22 Pad 8-19-24 XCL - Shiner #30-3A-22 Pad 8-19-24 Spectral Fit Run 1 Spectral Fit Run 2 Spectral Fit Run 3 Analysis Validation Report Sample Filename: C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000140.LAB Filename for noise: C:\OLT\Data\Golden Spectrum\New FTIR 09-13-23\NEW FTIR 09-13-23_000003.LAB Interferences Filenames: C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000068.LAB C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000069.LAB C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000070.LAB C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000071.LAB C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000072.LAB C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000073.LAB C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000074.LAB C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000075.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 32.09 2.48 -0.18 0.25 3.38 3.38 -1.5 --0-2795 1.04 Good NO2 191C 0.8 0.42 0.26 0.02 0.02 0.45 0.45 0.31 0.38 0.05 0.09 0-488 1.02 Close to DL N2O 191C 1.47 0.39 3.02 0.02 0.02 0.45 0.45 3.35 3.35 0.33 1.01 0-200 -Close to DL NH3 TE 191C 9.82 22.86 20.94 2.05 3.49 39.03 39.03 23.91 23.91 2.97 6.98 0-2995 -Close to DL H2O% (HIGH) 191C21.26 0.22 -0.01 0.01 0.35 0.35 -0.43 --0-40 -Good FORMALDEHYDE 191C0.06 0.52 0.23 0.16 0.18 0.59 0.59 0.32 0.37 0.09 0.08 0-69 1.18 Close to DL FORMIC ACID 191C TE0.29 3.28 2.32 0.7 0.82 3.85 3.85 2.74 2.74 0.42 0.77 0-466 -Close to DL CH4 2900 CM-1 191C64.24 3.61 -0.85 1.23 6.69 6.69 -1.57 --0-3143 0.98 Good PROPANE 191C 0.47 0.48 1.72 0.11 0.13 0.58 0.58 1.82 1.82 0.1 0.57 0-4976 0.95 Close to DL PROPYLENE 191C TE1.69 4.03 5.62 0.78 0.93 4.77 4.77 6.76 6.76 1.14 1.87 0-194 -Close to DL ETHANE 191C 1.42 1.2 4.4 0.26 0.4 1.86 1.86 4.94 4.94 0.54 1.47 0-1004 -Close to DL ETHYLENE 191C TE3.46 9.36 3.26 1.01 1.24 11.55 11.55 3.9 8.27 0.63 1.09 0-900 -Close to DL CO PPM 191C (1OF2)32.02 1.81 -0.15 0.33 3.86 3.86 -0.95 --0-5010 1.03 Good CO2% 191C 8.87 0.22 -0.01 0.01 0.31 0.31 -0.18 --0-23 -Good CO% 191C (2OF2)0 0 -0 0 0 0 -0 --0-8 -Check it! ACETALDEHYDE 191C-0.6 1.2 1.82 0.36 0.46 1.54 1.54 2.28 2.28 0.47 0.61 0-186 0.98 Close to DL ACETYLENE 191C 0.1 2.23 0.53 0.36 0.48 2.94 2.94 0.62 1.88 0.1 0.18 0-1016 -Close to DL SO2 191C 5.78 6.66 1.86 0.24 0.29 8.12 8.12 2.38 6.28 0.53 0.62 0-964 1.02 Close to DL HEXANE 191C -0.09 0.33 2.55 0.06 0.09 0.44 0.44 2.92 2.92 0.37 0.85 0-1000 -Close to DL Analysis Validation Report Sample Filename: C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000200.LAB Filename for noise: C:\OLT\Data\Golden Spectrum\New FTIR 09-13-23\NEW FTIR 09-13-23_000003.LAB Interferences Filenames: C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000068.LAB C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000069.LAB C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000070.LAB C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000071.LAB C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000072.LAB C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000073.LAB C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000074.LAB C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000075.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 37.04 3.11 -0.18 0.25 4.24 4.24 -1.98 --0-2795 1.04 Good NO2 191C 0.92 0.49 0.26 0.02 0.02 0.52 0.52 0.31 0.44 0.05 0.09 0-488 1.02 Close to DL N2O 191C 1.71 0.3 3.02 0.02 0.02 0.34 0.34 3.35 3.35 0.33 1.01 0-200 -Close to DL NH3 TE 191C 4.16 16.01 20.94 2.05 3.49 27.32 27.32 23.91 23.91 2.97 6.98 0-2995 -Close to DL H2O% (HIGH) 191C19.88 0.22 -0.01 0.01 0.33 0.33 -0.4 --0-40 -Good FORMALDEHYDE 191C0.07 0.53 0.23 0.16 0.18 0.6 0.6 0.32 0.38 0.09 0.08 0-69 1.18 Close to DL FORMIC ACID 191C TE0.2 3.24 2.32 0.7 0.82 3.79 3.79 2.74 2.74 0.42 0.77 0-466 -Close to DL CH4 2900 CM-1 191C63.3 3.54 -0.85 1.23 6.55 6.55 -1.53 --0-3143 0.98 Good PROPANE 191C 0.45 0.47 1.72 0.11 0.13 0.56 0.56 1.82 1.82 0.1 0.57 0-4976 0.95 Close to DL PROPYLENE 191C TE1.98 3.86 5.62 0.78 0.93 4.57 4.57 6.76 6.76 1.14 1.87 0-194 -Close to DL ETHANE 191C 1.35 1.19 4.4 0.26 0.4 1.85 1.85 4.94 4.94 0.54 1.47 0-1004 -Close to DL ETHYLENE 191C TE2.73 9.27 3.26 1.01 1.24 11.43 11.43 3.9 8.2 0.63 1.09 0-900 -Close to DL CO PPM 191C (1OF2)33.14 1.4 -0.15 0.33 2.99 2.99 -0.71 --0-5010 1.03 Good CO2% 191C 9.12 0.21 -0.01 0.01 0.29 0.29 -0.18 --0-23 -Good CO% 191C (2OF2)0 0 -0 0 0 0 -0 --0-8 -Check it! ACETALDEHYDE 191C-0.72 1.14 1.82 0.36 0.46 1.47 1.47 2.28 2.28 0.47 0.61 0-186 0.98 Close to DL ACETYLENE 191C0.03 1.93 0.53 0.36 0.48 2.55 2.55 0.62 1.59 0.1 0.18 0-1016 -Close to DL SO2 191C 4.81 5.49 1.86 0.24 0.29 6.69 6.69 2.38 5.15 0.53 0.62 0-964 1.02 Close to DL HEXANE 191C -0.08 0.32 2.55 0.06 0.09 0.44 0.44 2.92 2.92 0.37 0.85 0-1000 -Close to DL Analysis Validation Report Sample Filename: C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000260.LAB Filename for noise: C:\OLT\Data\Golden Spectrum\New FTIR 09-13-23\NEW FTIR 09-13-23_000003.LAB Interferences Filenames: C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000068.LAB C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000069.LAB C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000070.LAB C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000071.LAB C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000072.LAB C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000073.LAB C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000074.LAB C:\OLT\Data\XCL\Shiner pad #30-3A-22 E1 08-19-24\SHINER PAD #30-3A-22 E1 08-19-24_000075.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 58.49 3.35 -0.18 0.25 4.55 4.55 -1.85 --0-2795 1.04 Good NO2 191C 0.79 0.46 0.26 0.02 0.02 0.48 0.48 0.31 0.41 0.05 0.09 0-488 1.02 Close to DL N2O 191C 2.45 0.35 3.02 0.02 0.02 0.4 0.4 3.35 3.35 0.33 1.01 0-200 -Close to DL NH3 TE 191C 24.89 22.2 20.94 2.05 3.49 37.88 37.88 23.91 23.91 2.97 6.98 0-2995 -Close to DL H2O% (HIGH) 191C19.39 0.28 -0.01 0.01 0.44 0.44 -0.39 --0-40 -Good FORMALDEHYDE 191C0.07 0.74 0.23 0.16 0.18 0.83 0.83 0.32 0.58 0.09 0.08 0-69 1.18 Close to DL FORMIC ACID 191C TE0.39 4.46 2.32 0.7 0.82 5.22 5.22 2.74 3.77 0.42 0.77 0-466 -Close to DL CH4 2900 CM-1 191C54.29 5.07 -0.85 1.23 9.39 9.39 -2.87 --0-3143 0.98 Good PROPANE 191C -0.21 0.67 1.72 0.11 0.13 0.8 0.8 1.82 1.82 0.1 0.57 0-4976 0.95 Close to DL PROPYLENE 191C TE0.74 5.37 5.62 0.78 0.93 6.35 6.35 6.76 6.76 1.14 1.87 0-194 -Close to DL ETHANE 191C 1.64 1.65 4.4 0.26 0.4 2.57 2.57 4.94 4.94 0.54 1.47 0-1004 -Close to DL ETHYLENE 191C TE3.23 11.73 3.26 1.01 1.24 14.47 14.47 3.9 10.65 0.63 1.09 0-900 -Close to DL CO PPM 191C (1OF2)28.96 1.66 -0.15 0.33 3.53 3.53 -0.86 --0-5010 1.03 Good CO2% 191C 9.02 0.21 -0.01 0.01 0.29 0.29 -0.18 --0-23 -Good CO% 191C (2OF2)0 0 -0 0 0 0 -0 --0-8 -Check it! ACETALDEHYDE 191C-0.07 1.55 1.82 0.36 0.46 1.98 1.98 2.28 2.28 0.47 0.61 0-186 0.98 Close to DL ACETYLENE 191C-0.13 2.55 0.53 0.36 0.48 3.36 3.36 0.62 2.2 0.1 0.18 0-1016 -Close to DL SO2 191C 5.3 5.36 1.86 0.24 0.29 6.53 6.53 2.38 5 0.53 0.62 0-964 1.02 Close to DL HEXANE 191C -0.08 0.44 2.55 0.06 0.09 0.6 0.6 2.92 2.92 0.37 0.85 0-1000 -Close to DL APPENDIX C Test Run Load %Site Rated Load, bhp Load Approx., bhp 1 104 840 873.6 2 105 840 882.0 3 104 840 873.6 Engine Load Approximation based on Panel Levels APPENDIX D Test Run Flowrate dscfm Approx. BHP Avg O2 % NOx ppmvd NOx g/bhp-hr NOx lbs/hr CO ppmvd CO g/bhp-hr CO lbs/hr NMNEHC ppmvd NMNEHC g/bhp-hr NMNEHC lbs/hr Moisture Content % 1 483.11 873.6 1.0 64.45 0.12 0.22 84.35 0.09 0.18 4.68 0.01 0.02 19.38 2 496.82 882.0 1.0 55.04 0.10 0.20 38.85 0.04 0.08 3.91 0.01 0.01 18.98 3 482.29 873.6 1.0 75.84 0.14 0.26 54.71 0.06 0.11 2.92 0.01 0.01 18.64 876.4 1.0 65.11 0.12 0.23 59.30 0.07 0.13 3.84 0.01 0.01 19.00 Summary Average Levels Example Calculations: XCL Resources, Shiner #30-3A-22 Pad, 804058 (101073) The following is a step-by-step calculation for the first test run conducted on the Shiner #30-3A- 22 Pad 804058 (101073). Test Parameters Stack Diameter = 8 inches Traverse Points = 16 Ports = 2 Barometric Pressure = 24.72 in Hg Average O2 = 1.0% Average CO2 = 11.3% Load Approximation = 873.6 bhp Moisture Content = 19.38% EPA 40 CFR 60(A) Methods 1-3: Determination of Stack Gas Velocity and Flow Rate Dry Molecular Weight (lb/lbmol) = (0.44 * %CO2) + (0.32 * %O2) + ((0.28 * (%N2 + %CO)) Where: %CO2 – Carbon Dioxide Content Of The Gas = 11.3% %O2 – Oxygen Content Of The Gas = 1.0% %N2 – Nitrogen Content Of The Gas %CO – Carbon Monoxide Content Of The Gas (%N2 +%CO) = (100 - %O2 - %CO2) = (100 – 1.0 – 11.3) = 87.7% Dry = (0.44 * %CO2) + (0.32 * %O2) + ((0.28 * (%N2 + %CO)) = (0.44 * 11.3) + (0.32 * 1.0) + (0.28 * 87.7) = 29.85 lb/lbmol Wet Molecular Weight (lb/lbmol) = MD * (1-BWS) + (18) * BWS Where: MD – Molecular Weight Of The Dry Gas (lb/lbmol) = 29.85 lb/lbmol BWS – Moisture Content Of The Gas (%/100) = 19.38% = MD * (1-BWS) + (18) * BWS = 29.85 * (1 – (19.38/ 100)) + (18 * (19.38/ 100)) = 27.55 lb/lbmol Average Stack Gas Velocity (ft/sec) = Cp * (85.49) * ∆PAVG * (TS / (((PS / 13.6) + PB) * MA)) Where: CP – Pitot tube constant (unitless) = 0.84 ∆PAVG – Average square root of the stack gas pitot DP (inches water) = 0.830 in H2O TS – Average stack temperature (R) = 1214 R PB – Barometric pressure (in Hg) = 24.72 in Hg PS – Stack pressure relative to barometric pressure (inches water) = 0.3 in H2O MA – Molecular weight of the wet gas (lb/lbmol) = 27.55 lb/lbmol = Cp * (85.49) * ∆PAVG * (TS / (((PS / 13.6) + PB) * MA)) = 0.84 * (85.49) * 0.830 * ( 1214 / (((0.3/ 13.6) + 24.72) * 27.55)) = 79.56 ft/sec Average Dry Flowrate (dscfm) = 60 * (1-BWS) * VS * * (((DS / 2) / 12))2)* TSTD / TS * (PB + (PS / 13.6)) / 29.92 Where: DS – Diameter of the stack (inches) = 8 inches BWS – Moisture content of the gas (%) = 19.38% TSTD – Standard temperature (528R) TS – Average stack temperature (R) = 1214 R PB – Barometric pressure (in Hg) = 24.72 in Hg PS – Stack pressure relative to barometric pressure (inches water) = 0.3 in H2O VS– Average Stack gas velocity (ft/sec) = 79.56 ft/sec = 60 * (1-BWS) * VS * * (((DS / 2) / 12))2)* TSTD / TS * (PB + (PS / 13.6)) / 29.92 = 60 * (1 - (19.38/ 100)) * 79.56 * * (((8 / 2) / 12))2) * 528 / 1214 * (24.72 + (0.3 / 13.6)) / 29.92 = 483.11 dscfm Conversion of Dry Flowrate to m3/hr = Q * 60 * 2.83168*10 -2 Where: Q – Volumetric Flowrate = 483.11 dscfm 2.83168*10 -2 – Conversion factor for cubic feet to cubic meter 60 – Minutes in an hour = Q * 60 * 2.83168*10 -2 = 483.11 *60 * 2.83168*10 -2 = 820.808 m3/hr ASTM D 6348-03: Determination of NOx, CO and VOC Emissions From Stationary Sources NOx Emission Rate (g/Bhp-hr) = (Cd * 1.912*10 -3 * Q * T) / HP-hr Where: Cd – Measured NOx concentration in ppm = 64.45 ppm 1.92*10 -3 - Conversion constant for ppm to g/m3 NOx Q – Volumetric Flowrate = 820.808 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 873.6 Bhp = (Cd * 1.912*10 -3 * Q * T) / HP-hr = (64.45 * 1.912*10 -3 * 820.808 * 1) / 873.6 = 0.12 g/Bhp-hr NOx Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.12 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 873.6 Bhp = g/Bhp-hr / 454 * Bhp = 0.12 / 454 * 873.6 = 0.22 lbs/hr CO Emission Rate (g/Bhp-hr) = (Cd * 1.164*10 -3 * Q * T) / HP-hr Where: Cd – Measured CO concentration in ppm = 84.35 ppm 1.164*10 -3 - Conversion constant for ppm to g/m3 CO Q – Volumetric Flowrate = 820.808 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 873.6 Bhp = (Cd * 1.164*10 -3 * Q * T) / HP-hr = (84.35 * 1.164*10 -3 * 820.808 * 1) / 873.6 = 0.09 g/Bhp-hr CO Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.09 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 873.6 Bhp = g/Bhp-hr / 454 * Bhp = 0.09 / 454 * 873.6 = 0.18 lbs/hr VOC Emission Rate (g/Bhp-hr) = (Cd * 1.833*10 -3 * Q * T) / HP-hr Where: Cd – Measured VOC concentration in ppm = 4.68 ppm 1.833*10 -3 - Conversion constant for ppm to g/m3 VOC Q – Volumetric Flowrate = 820.808 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 873.6 Bhp = (Cd * 1.833*10 -3 * Q * T) / HP-hr = (4.68 * 1.833*10 -3 * 820.808 * 1) / 873.6 = 0.01 g/Bhp-hr VOC Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.01 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 873.6 Bhp = g/Bhp-hr / 454 * Bhp = 0.01 / 454 * 873.6 = 0.02 lbs/hr APPENDIX E FTIR Engine Test Sheet Company l\Iame 'Lt-L Location / Unit 1.0. t::;},,}'npI PC/c/ ,?X IfJr /1/~/; Jordan Nix 12. (",.,~ _IAll? If rJ~ //4/2-4 uZi'/ -,2',14 --7~ 7J Type of Test Completed Field Technician (5) Client Rep and/or State Rep Date { e-.1'45Non-Resettable Run Time Hours IAJctJ;bsho,EnQine Make ' """,_..">~"~~N~"'.'·".'·'"Enqine Model F <? F; z:« 1r5I w.lir/ -hGf, /f)£,qEnaine SIN Verified: "/1,4/, 'IIPort Distance A /' , " Z-~Port Distance B '~'v. t. 1/Exhaust Diameter (inches) Calibration Gas Cylinder # Concentration NO (ppm) 512.4 CO (ppm CC725093 507.5 Propane CC725093 501.6 Methane CC725093ppm CC725093 504.9 Ethvlene (ppm ppm 101.9CC275071 l ~ 145.7 Acetaldehyde (ppm) CC4963851\102 (ppm) 198.7CC431764 Stack Diagram ,'...... <,•• ... T ,r T t A 1 B Time of Readinq Atm Pressure (in Hg) Atm Temp CF) Engine RPM *Manifold Pres. Vac("}-er Boost(psi) or Boost (psia), Manifold Temo tF) Psuction (psi) Staqe 1 Tsuction ('F) staae 1 Pdischarqe (psi) Staae 1 Psuction (psi) Staqe 2 Tsuction CF) Stage 2 Pdischarqe (nsi) StaQe 2 Psuction [psi) Stage 3 Tsuction OF) Stage 3 Pdischaroe (osl) Staae 3 Psuction (psi) Stage 4 Tsuction OF) Stage 4 Pdischarge (psi) StaQe 4 Gas Throuahout (mmcf/dl or ( Test 1 /6 t; J /3 z J/3:+ -" Test 2 /I (, q., .----' Test 3 fCZ?) /16 Z /5 ? Pre Cat Temp CF) Post Cat Temp CF) Cat Differential Pres. (" of H20) Humidity% 02% C02 % Dry LOAD % 1PafteItor (Estimated) Ignition Timing ('F) AFR Setting mV (Left Bank) AFR Settina mV (Riaht Bank) 17.{JI.u :5'10 1.0 lot:) /.0 lOy Rev 8 • Some units show boost in inches of Hg. In this situation please indicate if it is positive (+) or negative(-). Eg: (+12") or (- 5'') 9/17/2019 Worksheet: O2 Stratification Client:XCL Location:Shiner pad #30-3A-22 E1 Date:8/19/2024 PD:8 DD:28 YES Method 1 Criteria Met UD:21 YES Method 1 Criteria Met Port Point Insertion Depth Reading (inches)(%) A 1 1.33 1.00 A 2 4.00 1.00 A 3 6.66 1.00 A 4 A 5 A 6 A 7 A 8 A 9 A 10 A 11 A 12 Average 1.00 Notes: To demonstrate non-stratified flow and utilize one sampling location O2 may not deviate by more than +/- 0.3% of the average O2 concentration. EPA REFERENCE METHOD 3A (Determination Of Stratification) COMPANY NAME:XCL COMPANY LOCATION:Shiner pad #30-3A-22 E1 DATE:8/19/24 STACK DIAMETER (inches):8 TRAVERSE POINTS:16 2 TEST RUN #1 TEST RUN #2 TEST RUN #3 AVERAGE O2:1 AVERAGE O2:1 AVERAGE O2:1 AVERAGE CO2:11.3 AVERAGE CO2:11.3 AVERAGE CO2:11.3 BARO PRESSURE:24.72 BARO PRESSURE:24.71 BARO PRESSURE:24.72 Point Insertion DepthDP (H2O)Ts (deg R)Stat P (H2O)Point Insertion DepthDP (H2O)Ts (deg R)Stat P (H2O)Point Insertion DepthDP (H2O)Ts (deg R)Stat P (H2O) 1 0.5 0.51 754 0.29 1 0.5 0.62 764 0.31 1 0.5 0.55 768 0.29 2 0.84 0.6 2 0.84 0.66 2 0.84 0.61 3 1.552 0.63 3 1.552 0.68 3 1.552 0.64 4 2.584 0.66 4 2.584 0.76 4 2.584 0.69 5 5.416 0.71 5 5.416 0.79 5 5.416 0.73 6 6.448 0.77 6 6.448 0.86 6 6.448 0.76 7 7.16 0.8 7 7.16 0.81 7 7.16 0.71 8 7.5 0.73 8 7.5 0.75 8 7.5 0.66 9 9 9 10 10 10 11 11 11 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16 1 0.5 0.62 754 0.29 1 0.5 0.58 764 0.31 1 0.5 0.58 768 0.29 2 0.84 0.58 2 0.84 0.63 2 0.84 0.66 3 1.552 0.65 3 1.552 0.69 3 1.552 0.61 4 2.584 0.79 4 2.584 0.77 4 2.584 0.75 5 5.416 0.76 5 5.416 0.88 5 5.416 0.78 6 6.448 0.81 6 6.448 0.74 6 6.448 0.82 7 7.16 0.75 7 7.16 0.79 7 7.16 0.73 8 7.5 0.7 8 7.5 0.69 8 7.5 0.7 9 9 9 10 10 10 11 11 11 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16