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HomeMy WebLinkAboutDAQ-2024-0116361 DAQC-1141-24 Site ID 101817 (B4) MEMORANDUM TO: STACK TEST FILE – XCL ASSETCO, LLC – Zubiate III 22-4C-22 THROUGH: Rik Ombach, Minor Source Oil and Gas Compliance Section Manager FROM: Paul Bushman, Environmental Scientist DATE: November 13, 2024 SUBJECT: Source: One (1) Waukesha F3524GSI engine Contact: Lauren Brown: (713) 808-9406 Location: Duchesne County, UT Test Contractor: Oasis Emission Consultants, Inc. Permit/AO#: Permit by Rule Action Code: TR Subject: Review of stack test report dated August 26, 2024 On October 22, 2024, Utah Division of Air Quality (DAQ) received a test report for one (1) Waukesha F3524GSI engine at Zubiate III 22-4C-22, Duchesne County, Utah. Testing was performed August 19, 2024, to demonstrate compliance with the emission limits found in Utah Administrative Code R307-510 and 40 CFR Part 60, Subpart JJJJ. The calculated test results are: Source Test Date Pollutant Method Tester Results DAQ Results Limits Waukesha F3524GSI SN: 5283705603 August 19, 2024 NOx 320 0.57 g/bhp-hr 0.573 g/bhp-hr 1.0 g/bhp-hr CO 320 0.11 g/bhp-hr 0.112 g/bhp-hr 2.0 g/bhp-hr VOC 320 0.01 g/bhp-hr 0.010 g/bhp-hr 0.7 g/bhp-hr DEVIATIONS: None. CONCLUSION: The stack test report appears to be acceptable. RECOMMENDATION: The emissions from the Waukesha F3524GSI engine should be considered to have been in compliance with the emission limits of UAC R307-510 and 40 CFR Part 60, Subpart JJJJ during testing. ATTACHMENTS: DAQ stack test review excel spreadsheets, XCL AssetCo, LLC stack test report. Emissions XCL Resources Zubiate III 22-4C-22 Duchesne County Waukesha F3524GSI; SN: 5283705603 Test Date: 8/19/2024 Run #1 2 3 Average Start Time 12:27 13:27 14:27 Stop Time 13:27 14:27 15:27 Sample Duration (minutes)60 60 60 BHP Engine Load - Actual (bhp) 647 647 647 647 DS Stack Diameter (inches)10.0 10.0 10.0 10.0PAVG Average (Delta P)½ (" H2O)½0.7740 0.7850 0.7950 0.7847 CP Pitot Tube Constant (unitless)0.84 0.84 0.84 0.84 TS Stack Temperature (°F)597 600 600 599 Pbar Barometric Pressure (" Hg)25.17 25.17 25.18 25.17 Ps Stack Pressure ('' H2O)0.25 0.28 0.27 0.27 O2%vd O2 (%vd)0.0 0.0 0.0 0.0 CO2%vd CO2 (%vd)12.4 12.5 12.5 12.5 N2%vd N2 (%vd)87.6 87.5 87.5 87.5 dry NOX (ppmvd)132.6 150.6 161.5 148.2 dry CO (ppmvd) 47.5 46.3 48.4 47.4 wet NMEOC (ppmvw as C3H8)2.1 2.1 2.1 2.1 Run #1 2 3 Average Bws Measured Moisture Content (%/100)0.188 0.195 0.193 0.192 Bws Saturated Moisture Content (%/100)121.145 123.794 123.748 122.896 Bws Actual Moisture Content (%/100)0.188 0.195 0.193 0.192 MD Molecular Weight Dry (lb/lb-mole)29.98 30.00 30.00 29.99 MA Molecular Weight Wet (lb/lb-mole)27.73 27.66 27.69 27.69 VS Gas Velocity (ft/sec)68.4 69.5 70.4 69.4 FACFM Gas Flow (acfm)2238 2276 2303 2272 FDSCFM Gas Flow (dscfm)763 767 779 770 FWSCFM Gas Flow (wscfm)941 954 966 954 FKWSCFH Gas Flow (kwscfh)56 57 58 57 FKWSCFM Gas Flow (kwscfm)0.941 0.954 0.966 0.954 lb/hr Gas Flow (lb/hr) 4063 4110 4165 4112 Fo Fo (unitless)1.685 1.672 1.672 1.676 wet O2 (%vw)0.0 0.0 0.0 0.0 wet CO2 (%vw)10.1 10.1 10.1 10.1 wet NOX (ppmvw)107.648 121.194 130.379 119.740 15 NOX (ppmvd @ 15% O2)37.438 42.505 45.602 41.849 82.0 lb/hr NOX (lb/hr)0.725 0.827 0.901 0.818 g/bhp-hr NOX (g/bhp-hr)0.508 0.580 0.632 0.573 1.0 wet CO (ppmvw) 38.531 37.275 39.031 38.279 15 CO (ppmvd @ 15% O2)13.401 13.073 13.652 13.375 270.0 lb/hr CO (lb/hr) 0.158 0.155 0.164 0.159 g/bhp-hr CO (g/bhp-hr) 0.111 0.109 0.115 0.112 2.0 dry NMEOC (ppmvd as C3H8)2.560 2.600 2.570 2.577 dry NMEOC (ppmvd as C3H8)2.560 2.600 2.570 2.577 15 NMEOC (ppmvd as C3H8 @ 15% O2)0.723 0.734 0.726 0.727 60.0 lb/hr NMEOC (lb/hr as C3H8)0.013 0.014 0.014 0.014 g/bhp-hr NMEOC (g/bhp-hr as C3H8)0.009 0.010 0.010 0.010 0.7 Permit Limits Field Reference Method Data Reference Method Calculations Page 1 of 1 Source Test Report For XCL Resources Axia 2 Duchesne County, Utah Test Date: August 19, 2024 Report Date: August 26, 2024 Federal Regulation: EPA 40 CFR 60, Subpart JJJJ Engine: Waukesha F3524GSI SN: 5283705603 Unit ID: 76774 (101817) Prepared By: Oasis Emission Consultants, Inc. 2730 Commercial Way Rock Springs, WY 82901 August 26, 2024 Mr. Ryan Sokolowski XCL Resources Dear Mr. Sokolowski: Re: Engine Emission Testing For XCL Resources, Axia 2, Unit 76774 (101817), EPA 40 CFR 60, Subpart JJJJ. An air emissions test program was conducted on a Waukesha F3524GSI engine, operated by XCL Resources and designated as Unit 76774 (101817), located at the Axia 2 in Duchesne County, Utah. The purpose of the testing was to demonstrate compliance with the emissions limits contained in EPA 40 CFR 60, Subpart JJJJ, for oxides of nitrogen (NOx), carbon monoxide (CO) and volatile organic compounds (VOC). Oasis Emission Consultants, Inc. conducted the testing on August 19, 2024. EPA 40 CFR 60, Subpart JJJJ Emission Levels The average recorded levels were found to comply with emission levels stipulated in the permit, as shown in the attached report and summarized below. Emission Unit Avg NOx Permit NOx Avg CO Permit CO Avg NMNEHC* Permit VOC g/bhp-hr 0.57 1.0 0.11 2.0 0.01 0.7 *VOC levels reported as non-methane, non-ethane hydrocarbon on a propane basis (NMNEHC C3). Catalyst Parameters (Averaged Over 3 Test Runs) Inlet Temp (deg F) DP (in H2O) 613 3.2 Engine Load (Averaged Over 3 Test Runs) Rated BHP Operating BHP % Load 840 646.8 77.0 Testing Protocol The attached report was generated using an extractive FTIR system using methodologies as required by and in accordance with EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320 as outlined in the submitted Source Test Protocol. Quality Assurance Oasis has performed a full review of the raw data and calculated results in this report. Any errors we have encountered have been listed in the body of this report. After performing the review, we are confident that this engine has met all requirements. If you have any questions or require further information, please contact the undersigned at (307) 382-3297. Yours truly, Oasis Emission Consultants, Inc. _________________________ _______________________ Charles A. Chapman Cember Crawley Manager of Technical Services Environmental Scientist _________________________ Christopher N. Knott, P.Eng. Director, Engineering and Operations SOURCE EMISSION TEST REPORT FEDERAL REGULATION EPA 40 CFR 60, Subpart JJJJ Test Performed By: Oasis Emission Consultants, Inc. Test Company Contact: Chris Knott 2730 Commercial Way Rock Springs, WY 82901 307.382.3297 Owner/Operator: XCL Resources Owner/Operator Contact: Ryan Sokolowski Facility Name: Axia 2 Duchesne County, Utah Emission Source: Waukesha F3524GSI Unit 76774 (101817) Date of Test: August 19, 2024 Date of Report: August 26, 2024 TABLE OF CONTENTS 1.1 Introduction .......................................................................................................................... 1 2.1 Stack Sampling Location ..................................................................................................... 2 3.1 Discussion of NOx, CO and VOC Test Results ................................................................... 4 3.1.1 Source Test 1 ............................................................................................................................................ 4 3.1.2 Source Test 2 ............................................................................................................................................ 4 3.1.3 Source Test 3 ............................................................................................................................................ 4 4.1 Stack Sampling Methods and Procedures ............................................................................ 5 4.2 Equipment Utilization .......................................................................................................... 6 4.3 Measurement of VOC (NMNEHC C3) ............................................................................... 7 4.4 Process Parameters ............................................................................................................... 7 5.1 Quality Assurance ................................................................................................................ 8 List of Tables and Figures Figure 1 - Sample Port Location ............................................................................................................................. 2 Figure 2 - Sampling Train Schematic-Method 320 ................................................................................................. 6 Table 1 - Insertion Depths of Traverse Points for Stratification Test ..................................................................... 3 Table 2 - Location of Traverse Points in Circular Stacks ....................................................................................... 3 Table 3 - Test Matrix .............................................................................................................................................. 5 Table 4 - Concentrations and Interference .............................................................................................................. 6 APPENDIX A: NOx, CO and VOC Test Data APPENDIX B: Quality Assurance/Calibration Data APPENDIX C: Load Approximation APPENDIX D: Example Calculations and Summary APPENDIX E: Field Notes 1 1.1 Introduction An air emissions test program was conducted on a Waukesha F3524GSI engine, operated by XCL Resources and designated as Unit 76774 (101817), located at the Axia 2 in Duchesne County, Utah. The purpose of the testing was to demonstrate compliance with the emissions limits contained in EPA 40 CFR 60, Subpart JJJJ, for oxides of nitrogen (NOx), carbon monoxide (CO) and volatile organic compounds (VOC) defined as non-methane, non-ethane hydrocarbons, reported as propane (NMNEHC C3). The facility is currently located in Duchesne County, Utah. Three one hour test runs were performed on August 19, 2024 to analyze NOx, CO and VOC emission levels. Test runs were performed according to methodologies outlined by EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320 as outlined in the submitted Source Test Protocol. Each one hour test run consisted of 60 readings taken at one minute intervals. Process parameters were recorded during each test run in order to determine the load. Parameters include the engine panel load percent reading. The following key personnel were present during testing: Jordan Nix, OEC Branden A 2 2.1 Stack Sampling Location The facility is currently located in Duchesne County, Utah. Testing was conducted on the Waukesha F3524GSI engine. The sampling port for moisture, NOx, CO and VOC measurements was approximately 3.7 pipe diameters (37”) downstream from the nearest flow disturbance (Distance B) and 1.0 pipe diameters (10”) upstream from the nearest disturbance (Distance A), as seen in Figure 1. The stack sampling location was placed at approximately 50% insertion depth based on an O2 stratification check which demonstrated a non-stratified flow regime. The stratification was conducted according to EPA 40 CFR 75(A), §6.5.6.1 using 3 traverse points determined according to Table 1 below. In accordance with EPA 40 CFR 60(A), Method 1, a total of 16 traverse insertion depths (8 traverse points through each of the 2 ports) were determined according to Table 2 below in order to conduct Method 2. Figure 1 - Sample Port Location 10" A B Oxidation Catalyst 3 Table 1 - Insertion Depths of Traverse Points for Stratification Test Traverse Point Insertion Depth (Percent of Stack Diameter) 1 16.6 2 50.0 3 83.3 Table 2 - Location of Traverse Points in Circular Stacks 4 3.1 Discussion of NOx, CO and VOC Test Results Three, one hour test runs were performed on August 19, 2024 to analyze exhaust NOx, CO and VOC (NMNEHC C3) emission levels to demonstrate compliance with the emissions limits contained in EPA 40 CFR 60, Subpart JJJJ. Testing for NOx, CO and VOC were run concurrently with one another. Each test was performed at the maximum achievable load. Measured emissions were below permitted limits. Please refer to the Appendices for a listing of all raw data, calibration error response and calculations performed per EPA 40 CFR 60(A) requirements. 3.1.1 Source Test 1: Waukesha F3524GSI, NOx, CO and VOC The first test was performed from 12:27 to 13:26 for NOx, CO and VOC. Based on operating parameters recorded during testing, the load was approximated at 646.8 bhp, and the average NOx and CO levels were found to be 0.51 g/bhp-hr and 0.11 g/bhp-hr respectively, below limitations. The VOC level tested at 0.01 g/bhp- hr, which tested in compliance. 3.1.2 Source Test 2: Waukesha F3524GSI, NOx, CO and VOC The second test was performed from 13:27 to 14:26 for NOx, CO and VOC. Based on operating parameters recorded during testing, the load was approximated at 646.8 bhp, and the average NOx and CO levels were found to be 0.58 g/bhp-hr and 0.11 g/bhp-hr respectively, below limitations. The VOC level tested at 0.01 g/bhp- hr, which tested in compliance. 3.1.3 Source Test 3: Waukesha F3524GSI, NOx, CO and VOC The third test was performed from 14:27 to 15:27 for NOx, CO and VOC. Based on operating parameters recorded during testing, the load was approximated at 646.8 bhp, and the average NOx and CO levels were found to be 0.63 g/bhp-hr and 0.12 g/bhp-hr respectively, below limitations. The VOC level tested at 0.01 g/bhp- hr, which tested in compliance. Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) VOC (ppmvd) VOC (g/bhp-hr) O2 (%) 1 132.62 0.51 47.47 0.11 2.56 0.01 0.0 Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) VOC (ppmvd) VOC (g/bhp-hr) O2 (%) 2 150.57 0.58 46.31 0.11 2.60 0.01 0.0 Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) VOC (ppmvd) VOC (g/bhp-hr) O2 (%) 3 161.54 0.63 48.36 0.12 2.57 0.01 0.0 5 4.1 Stack Sampling Methods and Procedures Testing followed EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320, with no exceptions. Table 3 - Test Matrix Method Title Parameter Reference EPA 40 CFR 60 Appendix A, Method 1 Sample and Velocity Traverses for Stationary Sources Sampling Point Determination https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_1_3.pdf EPA 40 CFR 60 Appendix A, Method 2 Determination of Stack Gas Velocity and Volumetric Flow Rate Exhaust Effluent Flow https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_2.pdf EPA 40 CFR 60 Appendix A, Method 3 Gas Analysis for the Determination of Dry Molecular Weight O2, CO2, Dry Volumetric Flow Rate https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_3.pdf EPA 40 CFR 63 Appendix A, EPA Method 320 Vapor Phase Organic and Inorganic Emissions by Extractive FTIR Nitrogen Oxides, Carbon Monoxide, Non- Methane Non- Ethane Hydrocarbons on a Propane Basis https://www.epa.gov/ emc/method-320- vapor-phase-organic- and-inorganic- emissions-extractive- ftir United States. U.S. Environmental Protection Agency. “EMC Promulgated Test Methods.” Air Emission Measurement Center (EMC). 31 August 2023. Web. 18 March 2024. <https://www.epa.gov/emc/emc-promulgated-test-methods>. 6 4.2 Equipment Utilization The following equipment was used during the tests performed at this facility in conjunction with procedures outlined by EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320. • (1) MKS MultiGas 2030 FTIR Continuous Gas Analyzer (0.210 L/min sample flow, 0.014 atmosphere sample pressure, 1 atmosphere cell pressure, 191°C cell temperature) • (1) Laptop Computer for the FTIR Analyzer using MKS MG2000 Software • (1) 75ft or 100ft Heated Teflon Line w/ Heated Sample Probe and Spike Bypass Line • S-Type Pitot Tube c/w 20 ft. Heated Sample Line (coefficient 0.84) • (1) Fyrite O2/CO2 Analyzer • (5) EPA Protocol G1 Calibration Gas (NOx, CO, C3H8, C2H4 and NO2) The MKS Multigas 2030 FTIR Analyzer operated with a spectral resolution of 0.5 cm-1 and a scan time of 30 seconds. The FTIR spectrometer utilizes a multi-pass gas cell with a 5.11 meter effective pathlength. Figure 2 - Sampling Train Schematic-Method 320 Table 4 - Concentrations and Interference 7 The MKS 2030 software provides a Natural Gas Method that is designed to minimize all expected interferences by removing the regions in the quant region where they are most absorbed (i.e. picket fence approach). So, for example, all the water peaks that are greater than about 0.1 abs are removed from the quant region. Since the spectral noise measured (sample spectrum) is in the range of 0.001 absorbance, it is desirable to have any error within this range. The MKS software will match the water calibration spectrum to the sample spectrum at any 1 point in the spectrum to about 1% precision. So, 1% of 0.1 absorbance is 0.001 abs. This is why any peaks greater than this for interfering compounds are usually excluded so they do not interfere. To summarize, the MKS software and the method are designed to minimize any interferences by removing their largest interfering absorptions. 4.3 Measurement of VOC (NMNEHC C3) The algorithm currently used for NMNEHC C3 and developed for natural gas fired applications by Dr. Spartz and MKS instruments in accordance with EPA standards, is the following: (2.4*c8/(1+exp((2-c8)/0.2))+1.9*c11/(1+exp((2-c11)/0.2))+6*c12/(1+exp((0.5-c12) /0.2))+2.85*c13/(1+exp((2-c13)/0.2))+3*c14/(1+exp((1-c14)/0.2)))/3 c8= acetylene c11= ethylene c12= hexane c13= propylene c14= propane Note: The constants in front of each of the compounds listed represents the FID response factor when calibrated with Propane. As with any CEMS analyzer, the FTIR may demonstrate a negative zero bias. The “exp” functions listed in the algorithm above are intended to mathematically filter out any negative biases and set them to approach zero. 4.4 Process Parameters Process parameters were recorded during each test run in order to determine the load. Parameters include the engine panel load percent reading. Results are provided in Appendix C. 8 5.1 Quality Assurance The MKS Multigas 2030 FTIR Analyzer was used to measure NOx, CO and VOC on a dry basis. A pre Direct and System calibration measurement was made on compounds of NOx, CO, C3H8 and C2H4. In addition, post System calibrations were made on compounds of NOx, CO, C3H8 and C2H4. Compounds of CO2 and C3H8 were measured for the quality assurance spiking requirements. Levels for calibrations and zeroes must be within +/- 5% of the certified calibration gas or response to zero gas, respectively. CTS procedures were followed according to EPA requirements for both pre and post testing. Similarly, QA spiking procedures were followed. Analysis of the CO2 exhaust effluent was used to determine the dilution factor. Steady levels of the CO2 were observed and a sufficient duration of time was allowed to elapse for a representative average. The calibration gas was spiked into the effluent stream using a bypass line at approximately 10% of the sampling rate. The dilution factor was obtained from observation of the stack CO2 behavior using the following equation: CO2AVG – CO2SPIKE DF = ------------------------ CO2 AVG Where: CO2AVG = The average undiluted CO2 stack gas concentration of spike measurements CO2SPIKE = The average diluted CO2 stack gas concentration when spiked The sample recovery was then obtained from the following equation: % REC = (Spike MEAS – Stack MEAS)* (1 – DF) --------------------------------------------------------- CS * DF Where: Spike MEAS = The average diluted stack gas concentration when spiked Stack MEAS = The average undiluted stack gas concentration DF = Dilution factor CS = Certified concentration of calibration standards The Sample Recovery average level for C3H8 was found to be 88.3%, which was within the allowable tolerance of Method 320 (70% to 130%). A summary of all spiking procedures/results can be found in Appendix B. APPENDIX A NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 139.607509 0.499748 140.107257 48.831611 2.623627 12.542656 12:27:40 08/19/2024 2 172.408267 0.459477 172.867744 47.815898 2.115395 12.357769 12:28:40 08/19/2024 3 113.573985 0.433228 114.007213 49.5232 2.167357 13.006826 12:29:40 08/19/2024 4 138.786559 0.517208 139.303767 50.950034 1.168803 13.148172 12:30:40 08/19/2024 5 200.247675 0.56669 200.814365 46.853962 1.152728 13.579004 12:31:41 08/19/2024 6 124.131022 0.559835 124.690857 48.934376 2.718129 16.145394 12:32:41 08/19/2024 7 113.81569 0.852392 114.668082 47.684577 2.778889 17.940372 12:33:41 08/19/2024 8 133.562392 1.306205 134.868597 49.417672 2.565966 21.703526 12:34:41 08/19/2024 9 146.015675 1.71624 147.731915 46.69694 2.424070 22.243829 12:35:41 08/19/2024 10 132.640657 1.783596 134.424253 46.974801 2.599944 22.269732 12:36:41 08/19/2024 11 88.201284 1.558741 89.760025 48.84665 2.504726 21.519581 12:37:41 08/19/2024 12 66.373546 1.333597 67.707143 49.96598 2.158514 19.593197 12:38:42 08/19/2024 13 68.143188 1.180094 69.323282 54.516873 2.425511 18.821223 12:39:42 08/19/2024 14 71.777891 1.023028 72.800919 47.462869 3.024824 18.467024 12:40:42 08/19/2024 15 65.754557 1.180044 66.934601 48.101723 2.708443 18.725228 12:41:42 08/19/2024 16 70.139254 1.069051 71.208305 49.837902 2.902428 18.167387 12:42:42 08/19/2024 17 114.498548 0.961834 115.460382 44.167693 2.724578 17.514471 12:43:42 08/19/2024 18 247.799453 1.006615 248.806068 42.491271 2.716547 18.09718 12:44:42 08/19/2024 19 319.053433 1.298948 320.352381 42.982334 2.406450 18.964144 12:45:42 08/19/2024 20 109.123806 0.975248 110.099054 45.317514 3.235013 17.438401 12:46:43 08/19/2024 21 102.951094 0.999464 103.950558 46.151916 3.035719 18.210064 12:47:43 08/19/2024 22 161.096915 1.085064 162.181979 44.996931 2.731666 18.794434 12:48:43 08/19/2024 23 170.737166 1.255744 171.99291 44.272066 2.069407 20.535796 12:49:43 08/19/2024 24 151.458316 1.238075 152.696391 45.022921 2.722828 19.280522 12:50:43 08/19/2024 25 101.150013 1.415247 102.56526 48.152737 2.521662 22.105566 12:51:43 08/19/2024 26 74.504334 1.745771 76.250105 50.809745 2.565583 22.507394 12:52:43 08/19/2024 27 129.145449 1.122168 130.267617 48.999709 3.002811 19.606639 12:53:44 08/19/2024 28 119.782716 1.175849 120.958565 48.682673 2.333599 18.764695 12:54:44 08/19/2024 29 127.775991 1.169263 128.945254 47.739073 2.583671 19.199936 12:55:44 08/19/2024 30 127.848338 1.212314 129.060652 48.314849 2.575865 19.747502 12:56:44 08/19/2024 31 117.550054 1.097282 118.647336 47.9807 2.696577 19.445177 12:57:44 08/19/2024 32 173.112957 1.361723 174.47468 46.972929 2.783039 21.054174 12:58:44 08/19/2024 33 167.650953 1.411007 169.06196 44.736578 2.677284 19.847404 12:59:44 08/19/2024 34 137.634769 1.346731 138.9815 45.513935 2.563317 20.102577 13:00:44 08/19/2024 35 103.925182 1.194902 105.120084 47.855484 2.286745 19.63576 13:01:45 08/19/2024 36 224.843903 1.17226 226.016163 46.899839 2.256822 18.72037 13:02:45 08/19/2024 37 172.64078 1.119584 173.760364 46.794641 2.005371 18.826876 13:03:45 08/19/2024 38 135.767131 1.095531 136.862662 46.40496 2.316248 19.06323 13:04:45 08/19/2024 39 119.02224 1.249707 120.271947 48.607916 1.967097 19.16228 13:05:45 08/19/2024 40 150.021094 1.085949 151.107043 47.889244 3.659449 18.590803 13:06:45 08/19/2024 41 115.244157 1.073705 116.317862 48.645263 3.668867 18.711868 13:07:45 08/19/2024 42 127.15583 1.084038 128.239868 47.723106 2.654809 18.929043 13:08:46 08/19/2024 43 150.886804 1.222787 152.109591 47.222635 2.614929 19.564876 13:09:46 08/19/2024 44 123.933638 1.386418 125.320056 47.399618 2.697487 19.965986 13:10:46 08/19/2024 45 138.137455 1.129762 139.267217 46.142165 2.715644 19.59859 13:11:46 08/19/2024 46 117.768755 1.312865 119.08162 47.159513 3.108506 20.250487 13:12:46 08/19/2024 47 121.362068 1.134786 122.496854 45.893728 2.359849 18.931378 13:13:46 08/19/2024 48 100.930444 1.091401 102.021845 47.562862 2.695601 18.703822 13:14:46 08/19/2024 49 170.572288 1.102687 171.674975 46.137222 2.754598 18.929734 13:15:46 08/19/2024 50 124.186159 1.248345 125.434504 46.995921 2.464291 19.332222 13:16:47 08/19/2024 51 111.433195 1.128127 112.561322 48.873511 2.565008 19.432208 13:17:47 08/19/2024 52 134.729227 1.147838 135.877065 48.370954 2.511956 19.030057 13:18:47 08/19/2024 53 135.853285 1.29068 137.143965 47.335798 2.496407 19.419491 13:19:47 08/19/2024 54 109.094753 1.186703 110.281456 48.866169 2.690401 19.878406 13:20:47 08/19/2024 55 99.68786 1.188783 100.876643 48.066524 2.818393 19.740271 13:21:47 08/19/2024 56 154.200779 1.146154 155.346933 46.021391 2.480687 18.714868 13:22:47 08/19/2024 57 125.531485 1.060133 126.591618 46.869176 2.453774 18.458025 13:23:47 08/19/2024 58 93.115126 1.171404 94.28653 48.265475 2.883919 18.825827 13:24:48 08/19/2024 59 112.918449 1.116162 114.034611 47.463005 2.104906 18.730901 13:25:48 08/19/2024 60 117.731768 1.140907 118.872675 47.042487 2.354251 19.013003 13:26:48 08/19/2024 AVG 131.48 1.14 132.62 47.47 2.56 18.83 ppm@15% O2 37.44 13.40 0.72 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.51 0.72 0.11 0.16 0.01 0.01 76774 (101817) FTIR Measurements Calculated Emission Levels XCL Resources Axia 2 Run 1 Record Date EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 10 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 0.50 1057 0.25 0.707 Average O2 0.0 (% dry)A 2 1.05 0.49 0.700 Average CO2 12.4 (% dry)A 3 1.94 0.51 0.714 Average N2 + CO 87.6 (% dry)A 4 3.23 0.53 0.728 Dry Molecular Weight 29.98 lb/lbmol A 5 6.77 0.60 0.775 Wet Molecular Weight 27.73 lb/lbmol A 6 8.06 0.64 0.800 EPA REFERENCE METHOD 320 A 7 8.95 0.66 0.812 Barometric Pressure 25.17 in Hg A 8 9.50 0.61 0.781 Moisture Content 18.83 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 132.62 ppm A 11 Calculated NOx Mass Output 0.72 lbs/hr A 12 Calculated NOx Output 0.51 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 47.47 ppm A 15 Calculated CO Mass Output 0.16 lbs/hr A 16 Calculated CO Output 0.11 g/bhp-hr B 1 0.50 0.57 1057 0.25 0.755 EPA REFERENCE METHOD 320 B 2 1.05 0.54 0.735 Average Analyzer NMNEHC Level 2.56 ppm B 3 1.94 0.63 0.794 Calculated NMNEHC Mass Output 0.01 lbs/hr B 4 3.23 0.66 0.812 Calculated NMNEHC Output 0.01 g/bhp-hr B 5 6.77 0.64 0.800 LOAD APPROXIMATION B 6 8.06 0.68 0.825 Estimated Engine Load 646.8 BHP B 7 8.95 0.65 0.806 B 8 9.50 0.71 0.843 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 0.6 1057 0.3 0.774 Average Stack Gas Velocity 68.39 ft/sec Average Dry Flowrate 764.01 dscfm TEST RUN # 1 NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 146.670855 1.123276 147.794131 46.003166 2.517964 18.725152 13:27:48 08/19/2024 2 150.183414 1.080592 151.264006 46.256012 2.999579 18.703163 13:28:48 08/19/2024 3 149.361636 1.204248 150.565884 48.223322 2.172812 18.901969 13:29:48 08/19/2024 4 146.480677 1.232368 147.713045 47.326653 2.354674 20.341834 13:30:48 08/19/2024 5 147.522494 1.303164 148.825658 51.208636 2.757122 19.821225 13:31:49 08/19/2024 6 155.239794 1.675686 156.91548 45.829524 2.592058 20.830635 13:32:49 08/19/2024 7 184.345876 1.155428 185.501304 45.031274 2.169926 19.031826 13:33:49 08/19/2024 8 169.235858 1.052238 170.288096 45.106372 2.255046 19.14308 13:34:49 08/19/2024 9 130.153107 1.044819 131.197926 45.941126 2.456297 20.041555 13:35:49 08/19/2024 10 133.467623 1.187424 134.655047 46.781355 2.780602 19.977974 13:36:49 08/19/2024 11 133.498653 1.247586 134.746239 45.766373 2.935485 20.938281 13:37:49 08/19/2024 12 139.064566 1.036776 140.101342 46.866434 2.341545 18.675575 13:38:49 08/19/2024 13 142.179363 1.194543 143.373906 45.993091 2.782196 19.971205 13:39:50 08/19/2024 14 119.765794 0.96812 120.733914 45.946482 2.170753 19.046373 13:40:50 08/19/2024 15 108.263456 1.040581 109.304037 46.206092 2.744048 19.478904 13:41:50 08/19/2024 16 83.2181 0.813413 84.031513 49.602802 3.325431 18.498636 13:42:50 08/19/2024 17 116.637036 0.992818 117.629854 45.924956 3.055375 18.391199 13:43:50 08/19/2024 18 78.800162 1.024589 79.824751 46.791377 3.267777 18.83278 13:44:50 08/19/2024 19 66.29517 1.041143 67.336313 49.647748 2.485388 19.021063 13:45:50 08/19/2024 20 75.114762 0.981366 76.096128 48.22295 2.413559 18.502014 13:46:50 08/19/2024 21 82.431914 1.111482 83.543396 45.847609 2.530270 18.726382 13:47:51 08/19/2024 22 82.645555 1.070368 83.715923 43.953875 2.461643 18.907952 13:48:51 08/19/2024 23 107.497025 1.096013 108.593038 43.095394 2.576292 19.373293 13:49:51 08/19/2024 24 103.596304 1.046331 104.642635 43.169306 2.416754 18.694288 13:50:51 08/19/2024 25 158.017125 1.026907 159.044032 42.370491 2.790910 18.569672 13:51:51 08/19/2024 26 182.326553 1.069687 183.39624 42.857701 2.930325 18.366609 13:52:51 08/19/2024 27 163.976559 1.140982 165.117541 43.783747 2.645862 20.512237 13:53:51 08/19/2024 28 191.254045 1.353552 192.607597 43.096792 2.748254 20.119414 13:54:52 08/19/2024 29 211.038424 1.102428 212.140852 43.671036 2.541631 19.965818 13:55:52 08/19/2024 30 168.234627 1.16265 169.397277 46.451445 2.760693 19.419558 13:56:52 08/19/2024 31 171.759375 1.298061 173.057436 45.67913 2.746659 19.684244 13:57:52 08/19/2024 32 142.190443 1.166567 143.35701 46.498064 2.438181 19.230565 13:58:52 08/19/2024 33 130.726448 1.316754 132.043202 47.887385 2.932483 21.476736 13:59:52 08/19/2024 34 117.474443 1.418685 118.893128 48.046268 2.675280 21.466338 14:00:52 08/19/2024 35 152.208438 1.148755 153.357193 46.807906 2.907637 20.041004 14:01:52 08/19/2024 36 191.762648 1.154792 192.91744 45.018954 2.544337 19.863257 14:02:53 08/19/2024 37 232.303139 0.982727 233.285866 44.90862 2.407735 19.554322 14:03:53 08/19/2024 38 251.408212 0.985141 252.393353 43.471769 2.485115 19.106182 14:04:53 08/19/2024 39 115.705147 0.859724 116.564871 47.861071 2.819782 18.462937 14:05:53 08/19/2024 40 140.879859 0.922542 141.802401 46.161184 3.171252 18.709954 14:06:53 08/19/2024 41 126.866881 0.948891 127.815772 46.895269 2.714444 18.634076 14:07:53 08/19/2024 42 134.670242 1.269885 135.940127 46.661271 2.602649 19.997378 14:08:53 08/19/2024 43 210.625174 1.022628 211.647802 45.688427 2.541096 19.04758 14:09:54 08/19/2024 44 167.431673 1.190358 168.622031 47.440569 2.354600 19.047247 14:10:54 08/19/2024 45 160.728198 1.132266 161.860464 50.98057 2.415315 19.634742 14:11:54 08/19/2024 46 157.03874 1.144548 158.183288 47.930015 2.531421 19.235756 14:12:54 08/19/2024 47 167.183724 1.184589 168.368313 47.467119 2.867872 20.342807 14:13:54 08/19/2024 48 202.40902 1.162959 203.571979 45.597244 2.733142 19.78775 14:14:54 08/19/2024 49 169.00334 1.337958 170.341298 46.273159 1.742458 20.590032 14:15:54 08/19/2024 50 193.936596 1.162511 195.099107 45.763274 2.266509 19.022608 14:16:54 08/19/2024 51 193.377767 1.085294 194.463061 45.992211 2.581884 19.991114 14:17:55 08/19/2024 52 161.494577 1.089846 162.584423 47.382373 2.932428 19.578845 14:18:55 08/19/2024 53 143.201266 1.403552 144.604818 45.624672 2.632842 20.283986 14:19:55 08/19/2024 54 208.885394 1.386473 210.271867 45.466683 2.244357 20.754406 14:20:55 08/19/2024 55 123.164672 1.673496 124.838168 49.185497 2.333379 21.364475 14:21:55 08/19/2024 56 159.738231 1.245066 160.983297 47.156359 2.541326 20.303785 14:22:55 08/19/2024 57 146.695058 1.087407 147.782465 47.742648 3.199419 19.36138 14:23:55 08/19/2024 58 171.357622 1.103979 172.461601 46.341305 2.203142 18.908877 14:24:55 08/19/2024 59 110.427182 1.082083 111.509265 47.55901 2.174267 18.611091 14:25:56 08/19/2024 60 184.384754 1.198416 185.58317 46.250794 2.353724 19.048076 14:26:56 08/19/2024 AVG 149.43 1.15 150.57 46.31 2.60 19.51 ppm@15% O2 42.51 13.07 0.73 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.58 0.83 0.11 0.15 0.01 0.01 Calculated Emission Levels Record Date XCL Resources Axia 2 Run 2 76774 (101817) FTIR Measurements EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 10 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 0.48 1060 0.28 0.693 Average O2 0.0 (% dry)A 2 1.05 0.51 0.714 Average CO2 12.5 (% dry)A 3 1.94 0.53 0.728 Average N2 + CO 87.5 (% dry)A 4 3.23 0.64 0.800 Dry Molecular Weight 30.00 lb/lbmol A 5 6.77 0.67 0.819 Wet Molecular Weight 27.66 lb/lbmol A 6 8.06 0.61 0.781 EPA REFERENCE METHOD 320 A 7 8.95 0.69 0.831 Barometric Pressure 25.17 in Hg A 8 9.50 0.72 0.849 Moisture Content 19.51 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 150.57 ppm A 11 Calculated NOx Mass Output 0.83 lbs/hr A 12 Calculated NOx Output 0.58 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 46.31 ppm A 15 Calculated CO Mass Output 0.15 lbs/hr A 16 Calculated CO Output 0.11 g/bhp-hr B 1 0.50 0.56 1060 0.28 0.748 EPA REFERENCE METHOD 320 B 2 1.05 0.53 0.728 Average Analyzer NMNEHC Level 2.60 ppm B 3 1.94 0.55 0.742 Calculated NMNEHC Mass Output 0.01 lbs/hr B 4 3.23 0.63 0.794 Calculated NMNEHC Output 0.01 g/bhp-hr B 5 6.77 0.71 0.843 LOAD APPROXIMATION B 6 8.06 0.73 0.854 Estimated Engine Load 646.8 BHP B 7 8.95 0.70 0.837 B 8 9.50 0.64 0.800 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 0.6 1060 0.3 0.785 Average Stack Gas Velocity 69.53 ft/sec Average Dry Flowrate 768.01 dscfm TEST RUN # 2 NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 244.628872 0.954884 245.583756 45.523266 2.113838 18.49692 14:27:56 08/19/2024 2 122.217762 1.409756 123.627518 48.223097 2.205879 20.543018 14:28:56 08/19/2024 3 125.28801 1.405387 126.693397 46.47255 2.403044 20.349001 14:29:56 08/19/2024 4 183.62815 1.046531 184.674681 45.986758 1.779356 18.549316 14:30:56 08/19/2024 5 230.053853 1.069558 231.123411 45.418158 2.708782 18.403346 14:31:56 08/19/2024 6 164.718827 0.979601 165.698428 47.263523 2.944384 18.742748 14:32:56 08/19/2024 7 120.088057 1.038368 121.126425 49.091336 2.338887 19.091872 14:33:57 08/19/2024 8 155.058855 1.18296 156.241815 48.909904 2.959204 19.905187 14:34:57 08/19/2024 9 128.599396 1.192512 129.791908 50.056007 2.635560 20.116848 14:35:57 08/19/2024 10 130.33285 1.153169 131.486019 49.550623 2.402388 19.398226 14:36:57 08/19/2024 11 109.636437 1.333371 110.969808 50.361352 2.442032 20.232174 14:37:57 08/19/2024 12 80.96723 1.428476 82.395706 51.654676 2.513432 20.287546 14:38:57 08/19/2024 13 66.711731 1.455901 68.167632 54.567065 3.290289 20.382896 14:39:57 08/19/2024 14 107.731333 1.186346 108.917679 47.183462 2.392613 19.334074 14:40:58 08/19/2024 15 186.956506 0.99421 187.950716 45.19174 2.317774 17.611518 14:41:58 08/19/2024 16 214.870651 0.742406 215.613057 44.862019 2.651450 16.748882 14:42:58 08/19/2024 17 239.272171 0.677626 239.949797 46.225218 2.738717 17.182395 14:43:58 08/19/2024 18 174.147926 0.880984 175.02891 46.369687 2.563650 18.599892 14:44:58 08/19/2024 19 222.898892 1.28356 224.182452 45.774216 3.149166 19.934879 14:45:58 08/19/2024 20 141.430492 1.23228 142.662772 51.042061 2.599464 20.435912 14:46:58 08/19/2024 21 193.051118 1.308745 194.359863 47.131415 2.609211 20.508216 14:47:58 08/19/2024 22 260.794199 1.039272 261.833471 45.648436 2.610842 19.281892 14:48:59 08/19/2024 23 197.403536 0.902823 198.306359 47.259542 2.822022 18.178069 14:49:59 08/19/2024 24 185.281137 0.860791 186.141928 48.305871 2.724428 18.509638 14:50:59 08/19/2024 25 147.66182 0.927636 148.589456 47.708644 2.871439 18.377064 14:51:59 08/19/2024 26 130.841653 1.110122 131.951775 48.10855 2.445678 19.971571 14:52:59 08/19/2024 27 120.359393 1.522559 121.881952 48.557567 2.901284 21.36975 14:53:59 08/19/2024 28 120.519201 1.466294 121.985495 48.836787 2.577744 20.634217 14:54:59 08/19/2024 29 137.526101 1.31685 138.842951 49.026283 2.144934 19.796665 14:55:59 08/19/2024 30 195.59297 1.207399 196.800369 48.22966 2.511566 19.192014 14:57:00 08/19/2024 31 196.698311 1.094827 197.793138 46.302244 2.201711 17.985369 14:58:00 08/19/2024 32 185.47869 0.895474 186.374164 46.158364 2.176925 16.816775 14:59:00 08/19/2024 33 175.625053 0.756913 176.381966 46.512887 2.061412 16.242063 15:00:00 08/19/2024 34 177.388424 0.777614 178.166038 47.195629 2.318940 16.20841 15:01:00 08/19/2024 35 143.109225 0.768431 143.877656 47.563391 2.484243 16.059584 15:02:00 08/19/2024 36 126.280477 0.90272 127.183197 47.571051 2.758013 17.38474 15:03:00 08/19/2024 37 158.823771 1.081104 159.904875 58.75581 2.876530 18.592501 15:04:01 08/19/2024 38 193.868176 1.139196 195.007372 48.199804 2.566977 19.239957 15:05:01 08/19/2024 39 270.724086 1.200106 271.924192 47.325653 3.073900 20.053656 15:06:01 08/19/2024 40 150.595592 1.129025 151.724617 49.406495 2.755966 19.91815 15:07:01 08/19/2024 41 158.590469 1.15947 159.749939 49.53766 2.685229 20.032774 15:08:01 08/19/2024 42 174.779516 1.248762 176.028278 49.646939 2.223459 20.540425 15:09:01 08/19/2024 43 167.402214 1.040032 168.442246 51.844297 2.125075 18.820159 15:10:01 08/19/2024 44 152.199942 1.147933 153.347875 52.397817 2.961061 19.474649 15:11:01 08/19/2024 45 244.201757 1.393208 245.594965 50.251757 2.243389 20.250199 15:12:02 08/19/2024 46 140.957489 1.099121 142.05661 51.58819 2.672162 19.433841 15:13:02 08/19/2024 47 112.00664 1.172901 113.179541 54.841409 3.037073 19.702326 15:14:02 08/19/2024 48 178.016806 1.553101 179.569907 50.323374 2.392952 21.715377 15:15:02 08/19/2024 49 178.399467 1.764686 180.164153 48.208675 2.655996 22.451969 15:16:02 08/19/2024 50 135.119478 1.509261 136.628739 49.939268 2.519379 21.200014 15:17:02 08/19/2024 51 152.712775 1.151563 153.864338 47.719656 2.529967 19.596188 15:18:02 08/19/2024 52 118.37507 1.275225 119.650295 47.700616 2.248796 19.410874 15:19:03 08/19/2024 53 120.307158 1.003618 121.310776 47.8609 2.814213 18.630345 15:20:03 08/19/2024 54 113.580352 0.933248 114.5136 46.478762 2.471085 17.800123 15:21:03 08/19/2024 55 118.758033 0.933644 119.691677 45.896739 2.812800 17.666918 15:22:03 08/19/2024 56 111.225935 1.023679 112.249614 47.247538 2.790439 18.479513 15:23:03 08/19/2024 57 112.717505 1.226687 113.944192 47.519582 2.325362 19.339471 15:24:03 08/19/2024 58 108.491183 1.284644 109.775827 48.2315 2.740828 20.307862 15:25:03 08/19/2024 59 216.912871 1.645727 218.558598 43.99629 2.742081 21.897275 15:26:03 08/19/2024 60 191.649704 1.520345 193.170049 46.698617 2.474050 21.802906 15:27:04 08/19/2024 AVG 160.39 1.15 161.54 48.36 2.57 19.29 ppm@15% O2 45.60 13.65 0.73 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.63 0.90 0.12 0.16 0.01 0.01 FTIR Measurements 76774 (101817) Calculated Emission Levels XCL Resources Axia 2 Run 3 Record Date EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 10 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 0.44 1060 0.27 0.663 Average O2 0.0 (% dry)A 2 1.05 0.59 0.768 Average CO2 12.5 (% dry)A 3 1.94 0.63 0.794 Average N2 + CO 87.5 (% dry)A 4 3.23 0.64 0.800 Dry Molecular Weight 30.00 lb/lbmol A 5 6.77 0.68 0.825 Wet Molecular Weight 27.69 lb/lbmol A 6 8.06 0.72 0.849 EPA REFERENCE METHOD 320 A 7 8.95 0.74 0.860 Barometric Pressure 25.18 in Hg A 8 9.50 0.69 0.831 Moisture Content 19.29 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 161.54 ppm A 11 Calculated NOx Mass Output 0.90 lbs/hr A 12 Calculated NOx Output 0.63 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 48.36 ppm A 15 Calculated CO Mass Output 0.16 lbs/hr A 16 Calculated CO Output 0.12 g/bhp-hr B 1 0.50 0.58 1060 0.27 0.762 EPA REFERENCE METHOD 320 B 2 1.05 0.52 0.721 Average Analyzer NMNEHC Level 2.57 ppm B 3 1.94 0.69 0.831 Calculated NMNEHC Mass Output 0.01 lbs/hr B 4 3.23 0.61 0.781 Calculated NMNEHC Output 0.01 g/bhp-hr B 5 6.77 0.66 0.812 LOAD APPROXIMATION B 6 8.06 0.62 0.787 Estimated Engine Load 646.8 BHP B 7 8.95 0.71 0.843 B 8 9.50 0.64 0.800 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 0.6 1060 0.3 0.795 Average Stack Gas Velocity 70.40 ft/sec Average Dry Flowrate 780.15 dscfm TEST RUN # 3 APPENDIX B Date Time NO 191C span NO2 191C span H2O% (high) 191C Formaldehyde 191C Ethylene 191C TE span Propane 191C span Acetaldehyde 191C span CO ppm 191C (1of2) spanCO ppm Dry CO2% 191C NOx Wet NOx Dry NM NE HC C3 Temp ( C )Pressure (atm)8/19/2024 12:08:35 -0.160503 0.180858 0.001956 -0.144677 0.260847 0.845116 0.128725 0.12101 0.121012 0.005903 0.020355 0.020356 2.946047 190.984467 1.0030378/19/2024 12:08:43 -0.133159 0.004831 -0.002921 0.09284 0.319368 0.648774 0.682255 0.170476 0.170471 0.00691 -0.128327 -0.128323 1.860686 190.984467 1.0029188/19/2024 12:08:50 -0.273915 0.046081 -0.00776 -0.062819 -0.319721 1.225552 0.133433 -0.036125 -0.036122 0.003841 -0.227834 -0.227816 3.633879 191.016251 1.002946 8/19/2024 12:08:58 -0.123183 0.077031 -0.000985 0.058983 0.318256 1.143817 0.543583 0.243818 0.243815 0.006348 -0.046152 -0.046152 3.789615 191.058365 1.0029098/19/2024 12:09:35 0 0 0 0 0 0 0 0 0 0 0 0 0 191.06076 1.003091 8/19/2024 12:09:48 -0.04438 -0.011613 -0.004885 -0.042967 -0.114825 -0.057958 0.046075 0.076616 0.076613 0.004031 -0.055994 -0.055991 -0.000589 191.06076 1.0035448/19/2024 12:09:56 0.175543 -0.090367 -0.005132 -0.147907 0.525799 -0.075948 -0.248899 -0.076131 -0.076127 -0.00302 0.085176 0.085172 0.021363 191.06076 1.0030678/19/2024 12:10:03 0.069309 -0.034569 0.00435 -0.025705 0.272031 0.722905 0.103381 0.206431 0.20644 -0.011742 0.03474 0.034741 0.140386 191.06076 1.0030078/19/2024 12:10:11 0.098556 -0.053298 -0.001371 0.087022 0.0238 0.082727 -0.081665 0.064155 0.064154 -0.013057 0.045258 0.045257 0.011306 191.06076 1.0032338/19/2024 12:10:18 -0.136254 0.055263 -0.007998 -0.082864 0.037319 0.305809 0.164639 -0.184043 -0.184028 0.006385 -0.080991 -0.080984 0.004639 191.06076 1.0035748/19/2024 12:10:26 -0.199304 0.049378 0.000968 -0.077255 0.051975 -0.451361 -0.232513 -0.030199 -0.0302 -0.004365 -0.149926 -0.149927 0.022846 191.06076 1.0031478/19/2024 12:10:33 -0.060618 -0.029455 0.001485 -0.018221 0.009174 -0.13548 0.017901 0.255305 0.255308 -0.008032 -0.090073 -0.090074 0.002205 191.06076 1.002912 8/19/2024 12:10:41 -0.154795 0.011287 0.000822 -0.053517 -0.300092 -0.261014 0.143102 0.000157 0.000157 0.001665 -0.143508 -0.143509 0.011218 191.06076 1.0029038/19/2024 12:10:48 0.079124 0.028767 -0.006453 -0.176504 0.282516 0.445892 -0.01561 -0.050138 -0.050134 0.005302 0.107892 0.107885 0.017398 191.06076 1.003454 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/19/2024 12:11:07 306.452889 283.975306 271.049395 191.06076 1.003856 8/19/2024 12:14:29 62.170571 190.895447 1.0033578/19/2024 12:11:15 466.155311 460.020958 461.436965 191.06076 1.00305 8/19/2024 12:14:36 91.920619 190.895447 1.003351 8/19/2024 12:11:22 497.679723 499.288245 494.867419 191.06076 1.003104 8/19/2024 12:14:44 98.108224 190.895447 1.0035928/19/2024 12:11:30 504.845549 506.681068 500.77091 191.06076 1.003615 8/19/2024 12:14:52 99.232259 190.895447 1.0037988/19/2024 12:11:38 504.983949 508.143854 498.038916 191.06076 1.003441 8/19/2024 12:14:59 99.521003 190.895447 1.0030258/19/2024 12:11:45 507.142868 509.222599 499.215275 191.06076 1.002579 8/19/2024 12:15:07 99.952205 190.895447 1.0042838/19/2024 12:11:53 508.642405 511.318105 497.329752 191.06076 1.003296 8/19/2024 12:15:14 100.388002 190.895447 1.0031448/19/2024 12:12:00 508.360761 511.906226 503.099866 191.057571 1.003216 8/19/2024 12:15:22 100.215263 190.92804 1.0033348/19/2024 12:12:08 508.757734 512.183105 497.811918 191.054398 1.003425 8/19/2024 12:15:29 100.490154 190.965393 1.003658 8/19/2024 12:12:15 509.996917 512.822222 500.703738 191.03714 1.003391 8/19/2024 12:15:37 99.502873 190.965393 1.003265 Date Time NO2 191C span Temp ( C )Pressure (atm)8/19/2024 12:12:35 57.882814 190.990814 1.0033378/19/2024 12:12:43 122.480854 190.990814 1.0034148/19/2024 12:12:50 140.918747 190.990814 1.003273 8/19/2024 12:12:58 145.713967 190.988998 1.0040368/19/2024 12:13:05 147.813017 190.899429 1.0035678/19/2024 12:13:13 148.842854 190.895447 1.0030618/19/2024 12:13:20 150.080087 190.895447 1.0035118/19/2024 12:13:28 147.324794 190.895447 1.0036578/19/2024 12:13:35 148.396804 190.895447 1.0035178/19/2024 12:13:43 148.819247 190.895447 1.003669 8/19/2024 12:13:50 149.415024 190.895447 1.0030298/19/2024 12:13:58 149.096529 190.895447 1.003705 8/19/2024 12:14:06 146.707953 190.895447 1.00389 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/19/2024 12:15:57 1.254067 1.487949 0.264656 190.965393 0.988772 8/19/2024 12:17:25 60.698067 191.048035 1.003441 8/19/2024 12:16:05 201.729358 213.556756 169.993241 190.97084 1.006695 8/19/2024 12:17:32 92.904406 191.048035 1.0032568/19/2024 12:16:12 447.049977 448.629553 439.122597 191.011703 1.008023 8/19/2024 12:17:40 98.482875 191.048035 1.003907 8/19/2024 12:16:20 494.686903 497.051564 490.429002 191.048035 1.007921 8/19/2024 12:17:47 99.51103 191.048035 1.0033138/19/2024 12:16:27 505.040813 507.60391 496.504205 191.048035 1.007745 8/19/2024 12:17:55 99.578841 191.048035 1.0035578/19/2024 12:16:35 506.191173 510.059366 499.364207 191.048035 1.007791 8/19/2024 12:18:02 99.983123 191.048035 1.0033548/19/2024 12:16:42 508.969773 513.038922 501.751801 191.048035 1.006239 8/19/2024 12:18:10 100.153969 191.048035 1.0036238/19/2024 12:16:50 509.459435 512.431325 499.650195 191.048035 1.003354 8/19/2024 12:18:17 99.862139 191.048035 1.0032628/19/2024 12:16:57 509.403498 512.631833 499.244444 191.048035 1.003118 8/19/2024 12:18:25 100.169882 191.048035 1.0036478/19/2024 12:17:05 508.213906 512.878039 500.882197 191.048035 1.003454 8/19/2024 12:18:32 99.998793 191.048035 1.003618 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Ethylene 191C TE Temp ( C )Pressure (atm)8/19/2024 12:18:55 0.220573 0.624892 1.238706 5.326639 191.048035 1.003698/19/2024 12:19:02 0.380915 0.30351 0.343194 1.012807 191.048035 1.00307 8/19/2024 12:19:10 0.018812 -0.048594 0.928761 0.006903 191.048035 1.0032118/19/2024 12:19:17 0.102582 -0.073344 0.594454 -0.076986 191.048035 1.003313 8/19/2024 12:19:25 0.016089 0.099713 0.624375 0.062577 191.048035 1.0035118/19/2024 12:19:32 0.15607 -0.114982 0.47388 0.350683 191.048035 1.003588/19/2024 12:19:40 0.003115 0.088433 0.641412 0.206413 191.048035 1.0036378/19/2024 12:19:47 -0.127381 0.150343 0.537355 -0.169763 191.048035 1.003772 Raw Calibration Data BACKGROUND / PRE DIRECT ZERO PRE DIRECT CAL NO2 CAL PRE SYSTEM CAL PRE SYSTEM ZERO Date Time CO2% 191C Propane 191C span Temp ( C )Pressure (atm) 8/19/2024 12:23:35 10.964738 0.933811 190.944199 0.9873438/19/2024 12:23:42 10.950967 0.984134 190.965393 0.9877488/19/2024 12:23:50 10.941652 0.514253 190.965393 0.9871588/19/2024 12:24:28 10.9139 0.717054 190.966217 0.9874488/19/2024 12:24:35 10.48573 3.383337 191.022614 1.0005878/19/2024 12:24:43 4.455872 186.95051 191.048035 1.0149968/19/2024 12:24:50 1.020714 394.488816 191.048035 1.003645 8/19/2024 12:24:58 2.914969 293.947744 191.048035 1.0037128/19/2024 12:25:05 7.856568 116.803157 191.048035 1.0057928/19/2024 12:25:13 9.251227 67.01621 191.048035 1.0070188/19/2024 12:25:20 9.567076 56.874664 191.048035 1.0074018/19/2024 12:25:28 9.634822 54.525211 191.048035 1.0070058/19/2024 12:25:35 9.664864 53.671192 191.048035 1.0056488/19/2024 12:25:43 9.866144 46.896857 191.048035 1.002786 8/19/2024 12:26:05 10.021011 40.856442 191.048035 1.0031718/19/2024 12:26:13 10.022874 40.413364 191.048035 1.003012 8/19/2024 12:26:20 9.998249 39.841035 191.048035 1.003303 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/19/2024 15:38:44 304.735199 295.187599 267.663498 190.811737 1.004843 8/19/2024 15:37:11 63.250795 190.952667 0.9809 8/19/2024 15:38:51 464.392536 465.177603 459.602804 190.806442 1.007708 8/19/2024 15:37:19 91.388984 190.952667 1.0109898/19/2024 15:38:59 497.355854 501.990935 491.895703 190.806442 1.00686 8/19/2024 15:37:26 98.520571 191.044403 1.0118388/19/2024 15:39:07 505.983721 509.748053 497.817619 190.806442 1.006431 8/19/2024 15:37:34 99.614884 191.048035 1.013438/19/2024 15:39:14 505.836565 509.146247 496.584439 190.806442 1.006635 8/19/2024 15:37:41 99.699525 191.048035 1.0137248/19/2024 15:39:22 505.606148 509.069573 498.063398 190.806442 1.005508 8/19/2024 15:37:49 99.379853 191.014435 1.0126418/19/2024 15:39:29 505.168761 509.922153 499.489957 190.806442 1.005123 8/19/2024 15:37:57 98.969232 190.971741 1.0115738/19/2024 15:39:37 505.146605 509.460572 498.799133 190.806442 1.005547 8/19/2024 15:38:04 98.388288 190.971741 1.003173 8/19/2024 15:39:44 506.592146 510.935352 500.433677 190.806442 1.004736 8/19/2024 15:38:12 99.390628 190.971741 1.0030328/19/2024 15:39:52 506.203111 511.542402 497.34358 190.806442 1.003216 8/19/2024 15:38:19 99.208208 190.971741 1.004326 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/19/2024 15:37:26 0.058279 0.197645 -0.208899 191.044403 1.011838 8/19/2024 15:40:29 -0.980925 190.911804 1.0023588/19/2024 15:37:34 -0.042531 0.072876 0.02916 191.048035 1.01343 8/19/2024 15:40:36 -0.32177 190.984467 1.006087 8/19/2024 15:37:41 0.100926 0.089452 0.365888 191.048035 1.013724 8/19/2024 15:40:44 -0.79516 190.984467 1.0067128/19/2024 15:37:49 0.005784 0.039704 -0.786727 191.014435 1.012641 8/19/2024 15:40:51 -0.267377 191.048035 1.0082848/19/2024 15:37:57 -0.030777 -0.067514 -0.854135 190.971741 1.011573 8/19/2024 15:40:59 -0.81732 191.06076 1.0070338/19/2024 15:38:04 0.140435 -0.090799 -0.341621 190.971741 1.003173 8/19/2024 15:41:06 0.05618 191.06076 1.0042978/19/2024 15:38:12 -0.256063 -0.032908 -0.575641 190.971741 1.003032 8/19/2024 15:41:14 -0.214898 191.06076 1.0031598/19/2024 15:38:19 0.057964 0.140463 -0.282908 190.971741 1.004326 8/19/2024 15:41:21 -0.726279 191.06076 1.004375 POST SYSTEM ZERO SAMPLE SPIKE RECOVERY POST SYSTEM CAL PRE TEST 1 501.6 10.9 1.3 9.8 47.6 0.095 88.3% Sensor Analyzer Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Error (%)Error (%) NOx 512.8 512.4 0.0 0.08 -0.01 CO 510.0 507.5 0.0 0.49 0.01 Propane 500.7 501.6 0.0 -0.18 0.00 Ethylene 99.5 101.90 0.1 -2.35 0.06 Sensor System Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Recovery (%)Error (%) NOx 512.9 512.4 0.1 0.09 0.02 CO 508.2 507.5 0.1 0.14 0.03 Propane 500.9 501.6 0.7 -0.14 0.14 Ethylene*100.0 101.90 1.0 -1.87 0.97 Sensor System Cal Zero Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Recovery (%)Error (%)Drift Error (%)Drift Error (%) NOx 511.5 512.4 0.0 -0.17 0.01 0.26 0.02 CO 506.2 507.5 0.0 -0.26 0.00 0.40 0.03 Propane 497.3 501.6 -0.3 -0.85 -0.07 0.71 0.21 Ethylene*99.2 101.90 -0.6 -2.64 -0.62 0.78 1.59 *CTS Scans are conducted with Ethylene through the sample line. % Recovery Propane PRE DIRECT CAL FTIR QA/QC SUMMARY SAMPLE RECOVERY CALCULATIONS Period Spike #Concentration of Propane Cylinder Stack CO2 Concentration Stack Propane Concentration Stack + Spike CO2 Concentration Stack + Propane Concentration DF Calculated POST SYSTEM CAL PRE SYSTEM CAL XCL – Axia 2 8-19-24 XCL – Axia 2 8-19-24 XCL – Axia 2 8-19-24 Spectral Fit Run 1 Spectral Fit Run 2 Spectral Fit Run 3 Analysis Validation Report Sample Filename: C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000140.LAB Filename for noise: C:\OLT\Data\Golden Spectrum\New FTIR 09-13-23\NEW FTIR 09-13-23_000003.LAB Interferences Filenames: C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000071.LAB C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000072.LAB C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000073.LAB C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000074.LAB C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000075.LAB C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000076.LAB C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000077.LAB C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000078.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 93.2 4 -0.18 0.25 5.49 5.49 -2.14 --0-2795 1.04 Good NO2 191C 1.07 0.6 0.43 0.02 0.02 0.64 0.64 0.48 0.55 0.05 0.14 0-488 1.02 Close to DL N2O 191C 17.31 0.73 -0.02 0.02 0.83 0.83 -0.39 --0-200 -Good NH3 TE 191C 4.49 19.67 7.65 2.05 3.49 33.57 33.57 8.5 17.67 0.85 2.55 0-2995 -Close to DL H2O% (HIGH) 191C20.27 0.2 -0.01 0.01 0.32 0.32 -0.41 --0-40 -Good FORMALDEHYDE 191C-0.03 0.51 0.23 0.16 0.18 0.58 0.58 0.24 0.36 0.01 0.08 0-69 1.18 Close to DL FORMIC ACID 191C TE0.22 3.14 2.68 0.7 0.82 3.67 3.67 2.85 2.85 0.17 0.89 0-466 -Close to DL CH4 2900 CM-1 191C37.73 3.14 38.72 0.85 1.23 5.29 5.29 43.13 43.14 4.41 12.91 0-3143 0.98 Close to DL PROPANE 191C 0.98 0.46 0.62 0.11 0.13 0.55 0.55 1.25 1.25 0.63 0.21 0-4976 0.95 Close to DL PROPYLENE 191C TE-0.13 3.7 2.64 0.78 0.93 4.38 4.38 3.32 3.32 0.68 0.88 0-194 -Close to DL ETHANE 191C 0.93 1.14 1.26 0.26 0.4 1.78 1.78 1.62 1.62 0.36 0.42 0-1004 -Close to DL ETHYLENE 191C TE2.88 9.39 3.15 1.01 1.24 11.58 11.58 3.69 8.32 0.55 1.05 0-900 -Close to DL CO PPM 191C (1OF2)37.01 1.5 -0.15 0.33 3.12 3.12 -0.78 --0-5010 1.03 Good CO2% 191C 9.92 0.23 -0.01 0.01 0.32 0.32 -0.2 --0-23 -Good CO% 191C (2OF2)0 0 0 0 0 0 0 0 0 0 0 0-8 -Close to DL ACETALDEHYDE 191C-0.67 1.21 1.53 0.36 0.46 1.55 1.55 1.62 1.62 0.09 0.51 0-186 0.98 Close to DL ACETYLENE 191C0.16 2.15 0.54 0.36 0.48 2.84 2.84 0.56 1.8 0.02 0.18 0-1016 -Close to DL SO2 191C 5.69 5.84 2.93 0.24 0.29 7.12 7.12 3.5 5.47 0.57 0.98 0-964 1.02 Close to DL HEXANE 191C -0.12 0.31 0.22 0.06 0.09 0.42 0.42 0.23 0.25 0.02 0.07 0-1000 -Close to DL Analysis Validation Report Sample Filename: C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000200.LAB Filename for noise: C:\OLT\Data\Golden Spectrum\New FTIR 09-13-23\NEW FTIR 09-13-23_000003.LAB Interferences Filenames: C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000071.LAB C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000072.LAB C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000073.LAB C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000074.LAB C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000075.LAB C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000076.LAB C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000077.LAB C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000078.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 127.49 4.73 -0.18 0.25 6.48 6.48 -2.66 --0-2795 1.04 Good NO2 191C 0.92 0.5 0.43 0.02 0.02 0.53 0.53 0.48 0.48 0.05 0.14 0-488 1.02 Close to DL N2O 191C 18.57 0.97 -0.02 0.02 1.1 1.1 -0.54 --0-200 -Good NH3 TE 191C 6.1 19.91 7.65 2.05 3.49 33.99 33.99 8.5 17.86 0.85 2.55 0-2995 -Close to DL H2O% (HIGH) 191C19.24 0.22 -0.01 0.01 0.34 0.34 -0.38 --0-40 -Good FORMALDEHYDE 191C-0.02 0.51 0.23 0.16 0.18 0.58 0.58 0.24 0.36 0.01 0.08 0-69 1.18 Close to DL FORMIC ACID 191C TE0.7 3.16 2.68 0.7 0.82 3.7 3.7 2.85 2.85 0.17 0.89 0-466 -Close to DL CH4 2900 CM-1 191C32.36 3.14 38.72 0.85 1.23 5.3 5.3 43.13 43.14 4.41 12.91 0-3143 0.98 Close to DL PROPANE 191C 0.64 0.46 0.62 0.11 0.13 0.55 0.55 1.25 1.25 0.63 0.21 0-4976 0.95 Close to DL PROPYLENE 191C TE-0.21 3.85 2.64 0.78 0.93 4.55 4.55 3.32 3.32 0.68 0.88 0-194 -Close to DL ETHANE 191C 1.12 1.16 1.26 0.26 0.4 1.8 1.8 1.62 1.62 0.36 0.42 0-1004 -Close to DL ETHYLENE 191C TE3.11 9.39 3.15 1.01 1.24 11.59 11.59 3.69 8.31 0.55 1.05 0-900 -Close to DL CO PPM 191C (1OF2)38.48 1.95 -0.15 0.33 4.05 4.05 -1.01 --0-5010 1.03 Good CO2% 191C 10.08 0.23 -0.01 0.01 0.32 0.32 -0.2 --0-23 -Good CO% 191C (2OF2)0 0 0 0 0 0 0 0 0 0 0 0-8 -Close to DL ACETALDEHYDE 191C-0.99 1.1 1.53 0.36 0.46 1.41 1.41 1.62 1.62 0.09 0.51 0-186 0.98 Close to DL ACETYLENE 191C0.14 2.33 0.54 0.36 0.48 3.08 3.08 0.56 1.98 0.02 0.18 0-1016 -Close to DL SO2 191C 5.74 5.53 2.93 0.24 0.29 6.74 6.74 3.5 5.16 0.57 0.98 0-964 1.02 Close to DL HEXANE 191C -0.11 0.31 0.22 0.06 0.09 0.42 0.42 0.23 0.24 0.02 0.07 0-1000 -Close to DL Analysis Validation Report Sample Filename: C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000260.LAB Filename for noise: C:\OLT\Data\Golden Spectrum\New FTIR 09-13-23\NEW FTIR 09-13-23_000003.LAB Interferences Filenames: C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000071.LAB C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000072.LAB C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000073.LAB C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000074.LAB C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000075.LAB C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000076.LAB C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000077.LAB C:\OLT\Data\XCL\Axia 2 E1 08-19-24\AXIA 2 E1 08-19-24_000078.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 113.79 4.67 -0.18 0.25 6.4 6.4 -2.53 --0-2795 1.04 Good NO2 191C 0.89 0.52 0.43 0.02 0.02 0.55 0.55 0.48 0.48 0.05 0.14 0-488 1.02 Close to DL N2O 191C 16.48 0.9 -0.02 0.02 1.03 1.03 -0.51 --0-200 -Good NH3 TE 191C 7.03 22.58 7.65 2.05 3.49 38.55 38.55 8.5 20.51 0.85 2.55 0-2995 -Close to DL H2O% (HIGH) 191C19.43 0.26 -0.01 0.01 0.4 0.4 -0.39 --0-40 -Good FORMALDEHYDE 191C0.01 0.57 0.23 0.16 0.18 0.64 0.64 0.24 0.42 0.01 0.08 0-69 1.18 Close to DL FORMIC ACID 191C TE0.44 3.57 2.68 0.7 0.82 4.18 4.18 2.85 2.88 0.17 0.89 0-466 -Close to DL CH4 2900 CM-1 191C28.47 3.08 38.72 0.85 1.23 4.48 4.48 43.13 43.13 4.41 12.91 0-3143 0.98 Close to DL PROPANE 191C 0.48 0.51 0.62 0.11 0.13 0.62 0.62 1.25 1.25 0.63 0.21 0-4976 0.95 Close to DL PROPYLENE 191C TE-1.19 4.27 2.64 0.78 0.93 5.05 5.05 3.32 3.47 0.68 0.88 0-194 -Close to DL ETHANE 191C 1.1 1.27 1.26 0.26 0.4 1.98 1.98 1.62 1.62 0.36 0.42 0-1004 -Close to DL ETHYLENE 191C TE3.35 10.21 3.15 1.01 1.24 12.6 12.6 3.69 9.12 0.55 1.05 0-900 -Close to DL CO PPM 191C (1OF2)41.35 2.04 -0.15 0.33 4.24 4.24 -1.05 --0-5010 1.03 Good CO2% 191C 10.01 0.23 -0.01 0.01 0.32 0.32 -0.2 --0-23 -Good CO% 191C (2OF2)0 0 0 0 0 0 0 0 0 0 0 0-8 -Close to DL ACETALDEHYDE 191C-0.42 1.22 1.53 0.36 0.46 1.57 1.57 1.62 1.62 0.09 0.51 0-186 0.98 Close to DL ACETYLENE 191C0.19 2.56 0.54 0.36 0.48 3.38 3.38 0.56 2.2 0.02 0.18 0-1016 -Close to DL SO2 191C 6.04 5.67 2.93 0.24 0.29 6.91 6.91 3.5 5.29 0.57 0.98 0-964 1.02 Close to DL HEXANE 191C -0.01 0.35 0.22 0.06 0.09 0.47 0.47 0.23 0.28 0.02 0.07 0-1000 -Close to DL APPENDIX C Test Run Load %Site Rated Load, bhp Load Approx., bhp 1 77 840 646.8 2 77 840 646.8 3 77 840 646.8 Engine Load Approximation based on Panel Levels APPENDIX D Test Run Flowrate dscfm Approx. BHP Avg O2 % NOx ppmvd NOx g/bhp-hr NOx lbs/hr CO ppmvd CO g/bhp-hr CO lbs/hr NMNEHC ppmvd NMNEHC g/bhp-hr NMNEHC lbs/hr Moisture Content % 1 764.01 646.8 0.0 132.62 0.51 0.72 47.47 0.11 0.16 2.56 0.01 0.01 18.83 2 768.01 646.8 0.0 150.57 0.58 0.83 46.31 0.11 0.15 2.60 0.01 0.01 19.51 3 780.15 646.8 0.0 161.54 0.63 0.90 48.36 0.12 0.16 2.57 0.01 0.01 19.29 646.8 0.0 148.24 0.57 0.82 47.38 0.11 0.16 2.58 0.01 0.01 19.21 Summary Average Levels Example Calculations: XCL Resources, Axia 2, 76774 (101817) The following is a step-by-step calculation for the first test run conducted on the Axia 2 76774 (101817). Test Parameters  Stack Diameter = 10 inches  Traverse Points = 16  Ports = 2  Barometric Pressure = 25.17 in Hg  Average O2 = 0.0%  Average CO2 = 12.4%  Load Approximation = 646.8 bhp  Moisture Content = 18.83% EPA 40 CFR 60(A) Methods 1-3: Determination of Stack Gas Velocity and Flow Rate Dry Molecular Weight (lb/lbmol) = (0.44 * %CO2) + (0.32 * %O2) + ((0.28 * (%N2 + %CO)) Where: %CO2 – Carbon Dioxide Content Of The Gas = 12.4% %O2 – Oxygen Content Of The Gas = 0.0% %N2 – Nitrogen Content Of The Gas %CO – Carbon Monoxide Content Of The Gas (%N2 +%CO) = (100 - %O2 - %CO2) = (100 – 0.0 – 12.4) = 87.6% Dry = (0.44 * %CO2) + (0.32 * %O2) + ((0.28 * (%N2 + %CO)) = (0.44 * 12.4) + (0.32 * 0.0) + (0.28 * 87.6) = 29.98 lb/lbmol Wet Molecular Weight (lb/lbmol) = MD * (1-BWS) + (18) * BWS Where: MD – Molecular Weight Of The Dry Gas (lb/lbmol) = 29.98 lb/lbmol BWS – Moisture Content Of The Gas (%/100) = 18.83% = MD * (1-BWS) + (18) * BWS = 29.98 * (1 – (18.83/ 100)) + (18 * (18.83/ 100)) = 27.73 lb/lbmol Average Stack Gas Velocity (ft/sec) = Cp * (85.49) * ∆PAVG * (TS / (((PS / 13.6) + PB) * MA)) Where: CP – Pitot tube constant (unitless) = 0.84 ∆PAVG – Average square root of the stack gas pitot DP (inches water) = 0.774 in H2O TS – Average stack temperature (R) = 1057 R PB – Barometric pressure (in Hg) = 25.17 in Hg PS – Stack pressure relative to barometric pressure (inches water) = 0.3 in H2O MA – Molecular weight of the wet gas (lb/lbmol) = 27.73 lb/lbmol = Cp * (85.49) * ∆PAVG * (TS / (((PS / 13.6) + PB) * MA)) = 0.84 * (85.49) * 0.774 * ( 1057 / (((0.3/ 13.6) + 25.17) * 27.73)) = 68.39 ft/sec Average Dry Flowrate (dscfm) = 60 * (1-BWS) * VS *  * (((DS / 2) / 12))2)* TSTD / TS * (PB + (PS / 13.6)) / 29.92 Where: DS – Diameter of the stack (inches) = 10 inches BWS – Moisture content of the gas (%) = 18.83% TSTD – Standard temperature (528R) TS – Average stack temperature (R) = 1057 R PB – Barometric pressure (in Hg) = 25.17 in Hg PS – Stack pressure relative to barometric pressure (inches water) = 0.3 in H2O VS– Average Stack gas velocity (ft/sec) = 68.39 ft/sec = 60 * (1-BWS) * VS *  * (((DS / 2) / 12))2)* TSTD / TS * (PB + (PS / 13.6)) / 29.92 = 60 * (1 - (18.83/ 100)) * 68.39 *  * (((10 / 2) / 12))2) * 528 / 1057 * (25.17 + (0.3 / 13.6)) / 29.92 = 764.01 dscfm Conversion of Dry Flowrate to m3/hr = Q * 60 * 2.83168*10 -2 Where: Q – Volumetric Flowrate = 764.01 dscfm 2.83168*10 -2 – Conversion factor for cubic feet to cubic meter 60 – Minutes in an hour = Q * 60 * 2.83168*10 -2 = 764.01 *60 * 2.83168*10 -2 = 1298.06 m3/hr ASTM D 6348-03: Determination of NOx, CO and VOC Emissions From Stationary Sources NOx Emission Rate (g/Bhp-hr) = (Cd * 1.912*10 -3 * Q * T) / HP-hr Where: Cd – Measured NOx concentration in ppm = 132.62 ppm 1.92*10 -3 - Conversion constant for ppm to g/m3 NOx Q – Volumetric Flowrate = 1298.06 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 646.8 Bhp = (Cd * 1.912*10 -3 * Q * T) / HP-hr = (132.62 * 1.912*10 -3 * 1298.06 * 1) / 646.8 = 0.51 g/Bhp-hr NOx Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.51 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 646.8 Bhp = g/Bhp-hr / 454 * Bhp = 0.51 / 454 * 646.8 = 0.72 lbs/hr CO Emission Rate (g/Bhp-hr) = (Cd * 1.164*10 -3 * Q * T) / HP-hr Where: Cd – Measured CO concentration in ppm = 47.47 ppm 1.164*10 -3 - Conversion constant for ppm to g/m3 CO Q – Volumetric Flowrate = 1298.06 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 646.8 Bhp = (Cd * 1.164*10 -3 * Q * T) / HP-hr = (47.47 * 1.164*10 -3 * 1298.06 * 1) / 646.8 = 0.11 g/Bhp-hr CO Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.11 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 646.8 Bhp = g/Bhp-hr / 454 * Bhp = 0.11 / 454 * 646.8 = 0.16 lbs/hr VOC Emission Rate (g/Bhp-hr) = (Cd * 1.833*10 -3 * Q * T) / HP-hr Where: Cd – Measured VOC concentration in ppm = 2.56 ppm 1.833*10 -3 - Conversion constant for ppm to g/m3 VOC Q – Volumetric Flowrate = 1298.06 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 646.8 Bhp = (Cd * 1.833*10 -3 * Q * T) / HP-hr = (2.56 * 1.833*10 -3 * 1298.06 * 1) / 646.8 = 0.01 g/Bhp-hr VOC Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.01 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 646.8 Bhp = g/Bhp-hr / 454 * Bhp = 0.01 / 454 * 646.8 = 0.01 lbs/hr APPENDIX E ------ FTIR Engine Test Sheet Company Name Location / Unit 1.0. Y!7_,­ .sc fa e-E j Type of Test Completed Field Technician (5) Client Rep and/or State Rep .s x! hf A/C'{/ Jordan Nix -.,e:;{n~;;r ~II If Date f? ~/J cf /e '1 3,:>'1/'fNon-Resettable Run Time Hours WCl oteShu,Engine Make '"' ,,,,,., "," ......~",'"F35?,-4 (r5IErmine Model 1:)Z'~3 ~D J:)hrYs lOT EnQine SIN Verified: PI/!/ Port Distance A r Port Distance B .s;r "\1 ':'"''Exhaust Diameter (inches) 10" ConcentrationCylinder #Calibration Gas [I 512.4 CO (ppm CC725093NO (ppm 507.5 Propane CC725093 501.6 Methane (ppm CC725093 ippm 504.9 Ethvlene (ppm CC725093 CC275071 101.9 N02(ppm) CC496385 145.7 Acetaldehyde (ppm) 198.7CC431764 Stack Diagram "~m~",-.-.·'~,~ ...,'< ..... T A 1 t B ... tI ! 1 '[~~l' . _.."~.,- Test 1 Test 2 Test 3 Time of Reading /2.26 137...6 1'12-6 Zl)J!=7-?_t:; ,/T-2:-6, I~Atm Pressure (in Hg) Atm Temp CF) .g~ ~'t7? ~'7- IC':) =r-ID36 /00/0Engine RPM *Manifold Pres. "./.ace") or Boost(psi) or Boost (psia) 3Z-:,'T 3Z-,C::-32-/ v- j /1:6 119 Izc,Manifold Temo tF) . Psuction (psi) Stage 1 '3'-/ ,~6 3=r .....---Tsuction 'F Stage 1 Pdischar e (osi) Staqe 1 tZ--7-1Z-7 /Zb Psuction 'osi) stace 2 ~ -----.Tsuction 'F) StaQe 2 -'-1 U 4/1:; qlLPdlscharoe (psi) Staae 2 Psuction psi) Stage 3 r \Tsuction CF) Stage 3 Pdlscharqe (osi) Staae 3 Psuction (psi) Staqe 4 Tsuction CF) Stage 4 Pdischarge (psi) Staqe 4 Gas Throuahout (mmef/d) or ( Pre Cat Temp CF) c/1 b '~ Post Cat Temp CF) Cat Differential Pres. (" of H20) '5,,2 Humiditv% 02% C02 % Dry AFR Setting mV (Left Bank) , , II u'tau o /». ,7;; LOAD % tpanett-or (Estimated) 7L::? lenition Timing CF) 1-1--, 7~ AFR SettinQ mV (Rioht Bank) RevS • Some units show boost in inches of Hg. In this situation please indicate if it is positive (+) or negative(-). Eg: (+12") or (- 5") 9/17/2019 Worksheet: O2 Stratification Client:XCL Location:Axia 2 E1 Date:8/19/2024 PD:10 DD:37 YES Method 1 Criteria Met UD:10 YES Method 1 Criteria Met Port Point Insertion Depth Reading (inches)(%) A 1 1.66 0.00 A 2 5.00 0.00 A 3 8.33 0.00 A 4 A 5 A 6 A 7 A 8 A 9 A 10 A 11 A 12 Average 0.00 Notes: To demonstrate non-stratified flow and utilize one sampling location O2 may not deviate by more than +/- 0.3% of the average O2 concentration. EPA REFERENCE METHOD 3A (Determination Of Stratification) COMPANY NAME:XCL COMPANY LOCATION:Axia 2 E1 DATE:8/19/24 STACK DIAMETER (inches):10 TRAVERSE POINTS:16 2 TEST RUN #1 TEST RUN #2 TEST RUN #3 AVERAGE O2:0 AVERAGE O2:0 AVERAGE O2:0 AVERAGE CO2:12.4 AVERAGE CO2:12.5 AVERAGE CO2:12.5 BARO PRESSURE:25.17 BARO PRESSURE:25.17 BARO PRESSURE:25.18 Point Insertion DepthDP (H2O)Ts (deg R)Stat P (H2O)Point Insertion DepthDP (H2O)Ts (deg R)Stat P (H2O)Point Insertion DepthDP (H2O)Ts (deg R)Stat P (H2O) 1 0.5 0.5 597 0.25 1 0.5 0.48 600 0.28 1 0.5 0.44 600 0.27 2 1.05 0.49 2 1.05 0.51 2 1.05 0.59 3 1.94 0.51 3 1.94 0.53 3 1.94 0.63 4 3.23 0.53 4 3.23 0.64 4 3.23 0.64 5 6.77 0.6 5 6.77 0.67 5 6.77 0.68 6 8.06 0.64 6 8.06 0.61 6 8.06 0.72 7 8.95 0.66 7 8.95 0.69 7 8.95 0.74 8 9.5 0.61 8 9.5 0.72 8 9.5 0.69 9 9 9 10 10 10 11 11 11 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16 1 0.5 0.57 597 0.25 1 0.5 0.56 600 0.28 1 0.5 0.58 600 0.27 2 1.05 0.54 2 1.05 0.53 2 1.05 0.52 3 1.94 0.63 3 1.94 0.55 3 1.94 0.69 4 3.23 0.66 4 3.23 0.63 4 3.23 0.61 5 6.77 0.64 5 6.77 0.71 5 6.77 0.66 6 8.06 0.68 6 8.06 0.73 6 8.06 0.62 7 8.95 0.65 7 8.95 0.7 7 8.95 0.71 8 9.5 0.71 8 9.5 0.64 8 9.5 0.64 9 9 9 10 10 10 11 11 11 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16