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HomeMy WebLinkAboutDAQ-2024-011550,.tttF$nctur Director, Air Enforcement Division Office of Civil Enforcement U.S. Environmental Protection Agency Mail Code 2242-A 1200 Pennsylvania Avenue, N.W. Washington, DC 20460-0001 Executive Secretary, Utah Air Quality Board Division of Air Quality 195 North 1950 West P.O. Box 144820 Salt Lake City, UT 841l6-4820 , l, July 3l ,2023 CERTIFIED MAIL: 7022 0410 0002 3551 6417 _UTAH DEPARruENT OFENVIRONMENTAL QUAUTY AllG _ 3 2023 IIIVI.SION OF AIR QUALITY RE: Semiannual Progress Report Consent Decree Entered July 2, 2008 in the U.S. District for the District of Utah United States of America, State of Utah v. Holly Refining & Marketing Company - Woods Cross Dear Director and Executive Secretary: In accordance with Paragraphs 135, 147, and 149 of the subject consent decree, this submittal provides the progress report for the Woods Cross Refinery for the semi-annual period from January I through June 30,2023. ln accordance with Paragraph 149d, the following certification is provided: I certi$ under penalty of law that this information was prepared under my direction or supervision by personnel qualified to properly gather and evaluate the information submitted. Based on my directions and after reasonable inquiry of the person(s) directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. In accordance with Paragraph 261, copies of this report are also provided to EPA Region 8 and other required government representatives. Sincerely,#4aJbff Danielson Vice President and Refinery Manager HF Sinclair Woods Cross Refining LLC 1070 W 500 S, Wesl Bountiful UT 84087 801 -299-6600 | HFSinclair.com REVIEWEDInitials: Date: Nov 14, 2024Compliance Status:OKFile #: 10123 (B2) Comment: FFY 2023 tl I hly 31,2023 Director, Air Enforcement Division, et. al. Page2 ci Director, Air Enforcement Division Air Program Director Office of Civil Enforcement OIfice of Enforcement, Compliance & Environmental Justice c/o Matrix New World Engineering Inc. Environmental Protection Agency, Region 8 26 Columbia Tumpike,2d Floor 1595 Wynkoop Sheet FlorhamPark,NJ 07932 Denver, CO 80202-ll}9 Megan J. Houdeshel T. Jones Dorsey & Whitney LLP R. Bagherianlll S, Maiu Street, Suite 2100 E. Benson (4) File 2.6.3.1.149 salt Lake ciqy, uT 84lll-2176 ec: csullivan@matrixneworld.com foley.patrick@epa. eov gallaeher.bob@epamail. epa. sov T. Go Progress Report on the Implementation of the Requirements of Part V (Affirmative Relief/Environmental Projects) CD tI Reouirement Status/Comment Section V.A. NOx Emissions Reductions from the FCCU t2 Submit detailed design for NOx Control Svstem bv l2l3lll0.Complete. Design sent I l/15/10. l3 Install and begin operation of NOx Control Svstem bv l2l3lll2.Complete. Operation began l0 I 27 I 12. t4 Commence I S-month interim demonstration period to determine interim FCCU NOx limit bv 411109. Data collection for NOx emissions from the FCC began 4lll09 and was completed 6130110. 15 Report results of interim NOx demonstration bv 90 davs followine period.Complete. Interim report sent 9129110. t6 Propose and comply with 7-day and 365- day interim NOx limits. Complete. Interim NOx limits proposed in interim report of 180 ppm 7-day average and I l0 oom 365-dav averase. t7 Comply with or dispute EPA-established interim NOx limits within 90 days of receipt. EPA-established limits received and complied with until final limits were set. 19 Commence I S-month demonstration period upon startup of NOx Control System to determine final FCCU NOx limit. Complete. Final demonstration period concluded on3130114. 20 Report results of final NOx demonstration bv 90 davs followins oeriod.Complete. Final report sent 517 I 14. 2t Propose and comply with 7-day and 365- day final NOx limits. Complete. Final NOx limits proposed in final report of 80 ppm 7-day average and 40 ppm 365-dav averase and monitorins. 22 Comply with or dispute EPA-established final NOx limits within 90 days of receipt. Final limits submitted to EPA on 5l7ll4. EPA established final NOx limits, received llll7l20, of 40 ppm 7-day average and22.5 ppm 365-day average. We are complying with those limits. 23 Use NOx and Oz CEMS to monitor FCCU performance bv 4lll09. Complete. NOx and Oz CEMS installed and collecting emissions data 4l I 109. Section V.B. SOz Emissions Reductions from the FCCU 25 Install and begin operation of a Wet Gas Scrubber at the FCCU by l2l3lll2 and meet25 ppm (365-day) and 50 ppm (7- dav) bv 6130113. Complete. Wet Gas Scrubber installed l0l27l12. We are complying with these limits. 26 Commence I S-month interim demonstration period to determine interim FCCU SOz limit bv 4lll09. Complete. Data collection for SOz emissions from the FCC began 4lll09 and was comoleted 6130110. 27 Report results of interim SOz demonstration by 90 days following period.Complete. Interim report sent 9129110. CD TI Reouirement Status/Comment 28 Propose and comply with 7-day and 365- day interim SOz limits. Complete. Interim SOz limits proposed in interim report of 160 ppm 7-day average and 50 ppm 365-dav averase. 29 Comply with or dispute EPA-established interim SOz limits within 90 days of receipt. EPA-established limits received, and complied with those limits until the lower limits became effective. 3l Use SOz and Oz CEMS to monitor FCCU oerformance bv 4lll09. Complete. SOz and Oz CEMS installed and collectins emissions data 4l I 109. Section V.C. PM Emissions Reductions from the FCC 32 Comply with limit of 1.0 pounds PM per 1000 pounds coke bumed for FCCU by 6130113. Complete. PM performance testing completed on l2l20l12. Report sent to EPA 1123113. JJ Install and begin operation of a Wet Gas Scrubber at the FCCU by l2l31ll2. Comply with limit of 0.5 pounds PM per 1000 pounds coke burned for FCCU by 6130fi3. Complete. PM performance testing completed on 12120112. Report sent to EPA ll23l13. 35 Perform PM test on FCCU by l0/31/13 and annually thereafter by l0/31. Submit results in next semiannual report. Initial PM performance testing completed on l2l20l12. Results sent to EPA under separate cover letter ll23l13. First annual PM test completed l0l22ll3. Second annual PM test completed l0l2ll4. Third annual PM test completed l0l22l15. Fourth annual PM test completed l2l7l16. Fifth annual PM test completed 10125117. Sixth annual PM test completed l0ll9ll8. Seventh annual PM test completed 9l4ll9. Eighth PM test completed 7114122. Request to reduce testing frequency was submitted to USEPA 6126118. Request for triennial testins sranted 9l6l19. Section V.D. CO Emissions Reductions from the FCCI 36 Comply with 500 ppm CO (l-hour) at FCCU bv l2l3ll09.Complete. Monitoring CO emissions. 37 Option to comply with 100 ppm CO (365- dav) at FCCU.Option is not currently under consideration. 39 Use CO and Oz CEMS to monitor FCCU oerformance bv 12131 109. Complete. CO and Oz CEMS installed and collectins emissions data 41 1 109. Section V.E. NSPS Aoolicabilitv of the FCCU Catalvsl Resenerator 4t FCCU subject to NSPS for CO by 12131109, and for SOz and PM by 6130113. CO limit complete, 500 ppm CO (l-hour) at FCCU. Wet Gas Scrubber installed and now comnlvins with SOr and PM NSPS limits. 43 Install and operate a COMS on the FCCU by l2l31l12 or comply with fl44. Complete. Altemate Monitoring Plan (AMP) request sent to EPA4ll2ll2. Revised AMP request sent to EPA9127ll2. AMP approval received 10/24112. CD tI Requirement Status/Comment 44 Request an AMP for monitoring opacity from the FCCU or comply with fl43. Complete. Altemate Monitoring Plan (AMP) request sent to EPA4ll2l12. Revised AMP request sent to EPA9127ll2. Section V.F. NOx Emissions Reductions from Heaters and Boilers 46a Install Next Generation ULNBs or alternative NOx Control Technology on 6H 1, or convert the Clark compressor driver to electric, or replace the Clark compressor with an electric-driven compressor bv l2l3ll09. Complete. Clark compressor was replaced by electric driven compressor I lK2. Installation was complete lll17l09. 46a Install Next Generation ULNBs or alternative NOx Control Technology on 8Hl bv l2l3ll09. Complete. Installed by 919108. 46a Install Next Generation ULNBs or alternative NOx Control Technology on 12Hl bv l2l3ll09. Complete. Installed by 917108. 46a Install Next Generation ULNBs or alternative NOx Control Technology on #5 Boiler bv l2l3ll09. Complete. Selective Catalytic Reduction (SCR) alternative NOx Control Technology was installed on #5 Boiler on 12130109. 46a Install Next Generation ULNBs or alternative NOx Control Technology on the CO Boiler by l2l3ll12 if disengaged from FCCT]. Complete. CO Boiler disengaged from FCCU 10126112. CO Boiler shut down permanently. 46a Install Next Generation ULNBs or alternative NOx Control Technology on Boiler #8bv 12l3lll2. Complete. Boiler shutdown on l2l3lll2 and restarted lll0ll3 with Selective Catalytic Reduction (SCR) installed. 46a Install Next Generation ULNBs or alternative NOx Control Technology on 4H1 by l2l31ll2 if heat input capacity is raised above 40 mmBTU/hr. Heat input capacity is at or below 40 mmBTU/hr. 46b(l) Install and operate NOx and Oz CEMS on heaters/boilers over 100 mmBTU/hr by date of NOx Control Technology installation, and use to monitor emissions by 6 months later. No heaters or boilers have heat input capacities over 100 mm BTU/hr (HHV). 46b(2) Conduct performance tests on heaters/boilers equal to or less than 100 mmBTU/tr by 60 days after installation of NOx Control Technology. Complete. Performance test on SHl completed 1019108. Performance test on 12Hl completed l0/13/08. Performance test on #5 Boiler completed 2l9ll0 and retested 3125110. Performance test on #8 Boiler completed 4122n3. 46c Submit permit revision to State proposing NOx emission limits (3-hour) for any NOx Control Technology within 120 days of start-up. Complete. Notice of Intent for a change in permit conditions for NOx limits on 8Hl and l2Hl submitted,12123108. Norice of Intent for a change in permit conditions for NOx limits on #5 Boiler submitted 4129110. CD 'II Resuirement Status/Comment 46d Submit annual NOx Control Technology progress report by l2l31 beginning in 2008. iirst report submitted l2ll5l08. Subsequent mnual reports submitted: l2l2l 109, l2l22l 10, t2l22l I t, 12121 I 12, t2l3t I 13, t2l30l 14, l2l29 l t5, t2l28l t 6, t2l27 l t7, t2l3 U t8, l2l 30 I 19, t2t 30 120, 12128 t2021, and t213012022. Section V.G. SOz Emissions Reductions from and NSPS Applicabilitv to Heaters and Boilers 48 All heaters and boilers are subject to NSPS Subpart J. Complete. Prior to Consent Decree, fuel gas for all heaters and boilers being monitored by CEM, with quarterly reporting as required by State of Utah. 49 May use alternative monitoring method immediatelv upon submittal of AMP. Complete. 2 AMPs submitted June 24,2009. (AMPs were subsequently rescinded.) 50 No liquid fossil fuel over 0.050/o Sulfur by weight shall be burned in any fuel gas combustion device. Complete. None used. Internal memo sent detailing limit. Copy and responses filed. Section V.H. NSPS Applicabilitv to the Sulfur Plant 52 NSPS shall apply if SRU exceeds 20 LTPD. Complete. Maximum SRU capacity is l0 LTPD. Daily HzS feed shown in Attachment A. 52a Install and commence operation of SOz CEMS at SRU bv 712108. Complete. CEMS installed and operational prior to 712108. 52a Demonstrate daily 95% recovery (30 day) for SRU using measured HzS in feed and SOz emissions from CEMS. The calculation of95% recovery from the sulfur recovery unit has become impractical due to the treatment of off gas from the sulfur recovery unit by a fluidized catalytic cracking unit's wet gas scrubber. A detailed summary of these chanses was submitted on 619116. 52a Determine HzS in SRU feed quarterly for 4 quarters and semiannually thereafter. Sampling and analysis completed 9122108, tol 1 6108, 21 6109, 5 I 5 109, 7 129 109, tol 12109, I 122/ 10, 8125 I t0, 0t 126l I t, 7 l28l I t, 2l2gl 12, 7 I I I I 12, 2l4l 13, 7 l2l 13, 21 181 I 4, 7 I 51 14, I l2l I I 5, 7 17 I I 5, and 219 I 1 6. Sampling has been discontinued. The SRU off gas is treated by a fluidized catalytic cracking unit's wet gas scrubber. 52b,c Complete SRP Optimization Study, implement recommendations, and submit study report within I year after 712108. Complete. Optimization Study was completed and report submitted 6126109. Schedule of implementation for the report's recommendations was included in the report that was submitted. CD TI Requirement Status/Comment 52d Submit test protocol to EPA Region 8 and State to perform 95o/o recovery efficiency and emission limit test at least 30 days before test. Conduct test within 6 months after completion of SRP Optimization Studv. SRP Optimization Study completed 612612009. Test protocol was submitted 1112312009. Testing performed 1212312009, SRU achieved 95.2% recovery and0.42 tons per day (830 lbs) SO2. 52e Submit a semiannual report covering SRU recovery, emissions, operating parameters, and daily feed. The calculation of 95% recovery from the sulfur recovery unit has become impractical due to the treatment of off-gas from the sulfur recovery unit by a fluidized catalytic cracking unit's wet gas scrubber. A detailed summary of these chanses was submitted on 619116. 52f Submit Plan for Maintenance and Operation of SRP within 270 days from 712108. Complete. Plan submitted 3 12612009, 52h Submit schedule to comply with NSPS within 120 days of SRU exceeding 20 LTPD input. Maximum SRU capacity has not increased beyond l0 LTPD. 54 All sulfur pit emissions routed to incinerator. Complete. Commenced prior to Consent Decree. Section V.L NSPS Applicabilitv to Flarins Devices 56,56a North flare and South flare subject to NSPS as of date of entry, eliminate all routinely- generated gas. Complete. Subject to NSPS prior to Consent Decree, no routinely-generated gas sent to flare. As of November I1,2015, all streams going to the flares are being monitored for compliance with the NSPS Ja standard, and are renorted in the ouarterlv CEMs reDorts. 56,56a South flare subject to NSPS 6130109, eliminate all routinely-generated gas. Complete. Study completed on routinely- generated gas sources and rerouting completed. Alternative Monitoring Plans submitted for 2 streams. (AMPs were subsequently rescinded.) 56,56a Propane flare subject to NSPS l2l3ll09, eliminate all routinely-generated gas. Complete. New propane flare installed 1111712009. The propane flare and associated storage pit were decommissioned in December of20l3. 56b Conduct performance tests for each flare within 180 days after bringing into compliance with NSPS. Performance tests for both North and South Flares conducted December 10, 2008. Performance test for the propane pit flare conducted March 25, 2010. 57a Comply with 162 ppm HzS limit in fuel gas-Complete. Ongoing prior to Consent Decree. Section V.J. Control of Acid Gas Flarins Incidents 59 Submit reports for Acid Gas Flaring Incidents no later than 45 days after incident. No Acid Gas flaring events occurred in period. CD !I Requirement Status/Comment Section V.K. Control of Hydrocarbon Flarine lncidents 68 Submit reports for Hydrocarbon Flaring Incidents in semiannual progress reports. Report for the incident on 413123 was completed 5117123. Report submitted on 713,/2023. Section V.L. CERCLA/EPCRA 69 Report any previously unreported SOz releases bv 6130109. No previously unreported SOz releases were identified. Section V.M. Benzene Waste Operations NESHAPS Prosram Enhancements 72 If TAB exceeds l0 Mg/yr, utilize the 6BQ comoliance ootion.TAB remains under 10 Mg/yr. 73 Complete review and verification of refinery's TAB and compliance by 270 davs after date ofentrv. Complete. Sampling plan, review and verification were completed 3/1 8/09. 74, l03a Submit report to the EPA and State by 60 days after review and verification.Complete. Report submitted 5120109. 75 Conduct additional sampling and submit results to EPA within 60 days after receivins request from EPA. EPA requested no additional sampling. 7\ l03b Revise report and resubmit within 120 days after comoletion of samolinp.Original report deemed final. 76 If revised report indicates initial report was unsatisfactory, resubmit report to State within 120 days after completing revised reDort. Original report deemed satisfactory. 11 I 03c If revised report indicates TAB over 10 Mglyr, submit plan within 180 days to ensure future compliance or to comply with 680 within 2 vears. No action required. The BWON Compliance Review and Verification Report did not indicate that the TAB exceeds 10 Mg/year. 79, 103d If actions are required under !l 77, submit certification of compliance within 30 days after completion of actions. No action required. Neither the BWON Compliance Review and Verification Report nor current sampling pursuant to Paragraph 94 indicate that the TAB exceeds l0 Ms/vear. 80 Develop program within 60 days from date of entry to annually review process/project information to ensure all new benzene waste streams are included in inventory. Complete. A task to complete an annual review was added to the automated environmental tracking system. Inventory reviewed on l2l3o/09, 12127/10, l2/30lll, 12127 I t2, t2l t9 I 13, t2l 101 14, t2l30l 1 5, t2t28t 16, 12t22t2017, 31241 18, t2l2t I tg, 121 201 19, t2l t7 120, 12t 30 t21, 12t30 t22, and r212U23. 82,84 Conduct audits ofall laboratories used for benzene waste analysis within 270 days after date of entry, new labs before use, and everv two vears. Laboratory audit completed 3/l ll1l,3l8l13, 3 I 181 t5, 31 1 61 17, 3128t 19, 3 t22t2t, and 312812023. CD !I Requirement Status/Comment 86 Review spi more than waste, and ls to determine if they generate 0 lbs ofaqueous benzene nclude in TAB. Environmental Procedure 5.02 incorporates review requirements. 87 Develop and begin annual training for all employees asked to draw benzene waste samples, complete first within calendar year. lnitial training completed 05 I 0 | I 09. Contract personnel were initially used to collect samples. Additional training completed annually. The latest training was completed on 12130122. 89 Ensure contractor employees hired to perform training are adequately trained. Completed for contract employees by 12115108, 1218109, and I 1/05/10. Contractors no lonser used. 90, l03e Submit waste/slop/off-spec oil management schematics Complete. Sent to State and EPA 8/21108. 93, l03f Submit quarterly/annual sampling plans to EPA and State by 60 days after revised report is finalized or original report is acceoted. Original report accepted. Sampling plan sent on 7l2l12. 95 Implement the sampling plan in the first full quarter after submittal. Complete. Sampling plan has been implemented. The sampling plan is more stringent than the CD in requiring quarterly sampling for waste streams > 0.05 Mg/yr benzene. 96, l03f If changes affect the validity of the sampling plan, submit revised plan within 90 davs. A revised sampling plan was submitted to EPA on 5125123. 97 Submit quarterly and annual projected TAB with semiannual reoort. The quarterly and annual projected TAB is included in Attachment B. 98 Implement corrective measures if quarterly TAB > 2.5Ms or annual TAB > l0 Ms.No excesses during this period. 99 Provide reasons why causes of excess quarterly or annual TAB will not recur.No excesses during this period. 100, l03g Submit compliance assurance plan if quarterly TAB > 2.5 Mg or annual TAB > 10 Ms. No excesses during this period. 101 Contract 3'd party to conduct TAB study and compliance review if quarterly TAB > 2.5 Mg or annual TAB > 10 Mg. Submit results to EPA and State within 30 days and imolement. No excesses during this period. l04a Submit sampling results and TABs with the semiannual reDort. Sampling results and TABs are included in Attachment B. l04b Submit description of training conducted with the semiannual report. Retraining completed for 2022 by attending a third party consult training course and via review of physical material based on existing computer-based trainins. CD qI Requirement Status/Comment l04c Submit a summary of lab audits conducted with the semiannual report. Identification of the laboratory audited, a description of the methods used in the audit, and the results ofthe audit are provided as Attachment C. 105 Requests to modiff the frequency of reportins under fll04. No request has been made to modiff the frequencv of reuortins. Section V.N. Leak Detection and Repair ("LDAR") Program Enhancements 109 Develop and maintain a written LDAR program within 120 days of date of entry Complete. Submitted with Semi-Annual Report dated 1128109. I 10, I 35a Submit LDAR program to EPA and State in first semiannual report. Complete. Submitted with Semi-Annual Report dated 1128109. 111a Train employees newly assigned to LDAR responsibilities before beginning LDAR work. Computer-based training is required for all newly involved employees. 11lb Provide annual training for all employees with specific LDAR responsibilities as primary job function beginning within I vear of 712108. Computer-based training program is required for all employees with specific LDAR responsibilities as their primary job function. lllc Provide training every 3 years for all operations and maintenance employees beginning within I year of 712108. Computer-based training program established training for 146 employees and completed 612109. Computer-based training for I 60 employees completed l2l2ll1l. Computer- based training for 218 employees completed l2l3ll13. Training for 173 employees completed l2l3l I 15. Training for 207 employees completed l2l3ll18. Training for 158 employees completed 21112022. l1 ld Maintain records of annual training as in fl I I lb for contract LDAR oersonnel.Maintained under file number 2.6.3. I 13, tt4 Conduct 3'o party audit of LDAR compliance every 4 years, beginning within 12 months of date of entry. 3'o par{ audit conducted by ERM and report submitted 6122109. l13 Submit LDAR compliance certification to EPA. LDAR compliance certification submitted 11512010. 11s Conduct an internal or 3'd party audit of the LDAR program every 4 years, beginning within 2 years after the initial 3'd party audit. 3'o party audit conducted 4/18111,4/8113, 4/ 13 I I 5, 5 I I 61 17, 4l I I I 19, 4 122121, and 5 I 4123. 116 LDAR audits are to be conducted in the same calendar quarter. All future LDAR audits will be conducted the second calendar quarter ofthe vear. 10 CD qi Requirement Status/Comment tt7 Implement steps necessary to correct areas of non-compliance identified in the Consent Decree required LDAR audits. All corrective actions identified in the first LDAR Audit conducted 5126-5129109 are complete. Corrective actions for the second and third audits are complete. Corrective actions for the fourth audit are complete. Corrective actions for the fifth audit are complete. Corrective actions for the sixth audit are complete. Corrective actions for the seventh audit are estimated to be completed by 81312023. 120 Utilize internal leak definition of 500 ppm for valves, except pressure reliefdevices, bv llll09. Complete. 121 Utilize internal leak definition of 2,000 oom for DumDs bv 7llll0.Complete. 122 Speciff in report whether applicable regulatory leak definition or lower internal leak definitions are being used for leak rates. Applicable regulatory leak definition is used for reporting leak rates. t24 Make initial attempt at repair on non- control valves with reading over 200 ppm and remonitor. Complete. 125 Monitor pumps in light service monthly beeinnine 7llll0.Complete. 126 Monitor valves, other than difficult to monitor valves. ouarterlv beeinnins 1lll09.Complete. t27 Keeo LDAR data in electronic database.Complete. 128 Use dataloggers/electronic data collection for LDAR.Complete. t29 Develop and implement a LDAR QA/QC procedure within 90 days after date of entry. Complete. 130 All LDAR equipment calibrations to be conducted per Method 27, and records maintained for life of Consent Decree. As specified in procedures, see Semi-Annual Report dated 1128109, Attachment B. 131 Drift assessments performed at minimum at the end of each shift, with remonitoring if nesative drift exceeds l0%. Complete. l32a Sign offby responsible person for delay of repair, and continued monitoring of eouioment. Complete. t32b Employ "drill and tap" for valves leaking over 10,000 ppm that cannot otherwise be reDaired. As required, and as specified in procedures, see Semi-Annual Report dated 1128109, Attachment B. 77 CD qI Reouirement Status/Comment t34 Repair or replace non-control valves that are chronic leakers at next process unit turnaround. As required, and as specified in procedures, see Semi-Annual Report dated 1128109, Attachment B. I 35a Provide LDAR program information in the first semiannual report.Complete. I 35b Provide description ofaudit report for each audit conducted in the prior year in the semiannual report (July 3l report only). Identification of the auditor, a summary of the audit results, and the status of Holly's actions related to the audit are provided as Attachment D. 136 Provide information on training and on LDAR monitoring and repairs in the resular NESHAPS reoorts. Included in Semiannual MACT reports beginning January 2009. Section V.O. Incorporation of Consent Decree Requirements into Federally Enforceable Permits l37a Submit permit revision for immediate Consent Decree requirements within 90 days of date of entry. Notice of Intent for a change in Approval Order (AO) conditions to incorporate Consent Decree requirements submitted 9119108. AO # DAOE-ANO 101230027 -09 received I I 12109. t37b Submit permit revision for other Consent Decree requirements within 90 days of effective date. Notice of Intent for a change in Approval Order (AO) conditions for NOx limits on 8Hl and l2Hl submitted 12123108. Ao # DAQE- ANOl 01 230027 -09 received I I 12109. Notice of Intent for a change in AO conditions for CO limit on FCCU submitted 3129110. AO # DAQE-ANO 101230032-10 received 8123/ 10. Notice of Intent for a change in AO conditions for #5 Boiler NOx limit submitted 4129110. AO # DAQE-AN0l 01230036-1 0 received 11117110. Notice of lntent for a change in AO conditions for interim NOx and SOz limits on FCCU submitted lll30ll0. Ao # DAQE- ANol 01230038-10 received l2l 161 10. Notice of Intent for a change in AO conditions for final SOz limits on FCCU submitted 5123112. Notice of Intent for a change in AO conditions for interim NOx limits on FCCU submitted 31231t3. AO # DAQE-AN101230041-13 received I l/18/13. AO # DAQE- AN101230052-20 received 10/8/20. AO # DAQE-AN I 01230053-22 received 9 I I 122 (no CD requirements to be implemented in this AO). AO # DAQE-AN1012300''-23 received 619123 (no additional CD requirements to be implemented in this AO). 72 CDqI Reouirement Status/Comment Section V.H. NSPS ApplicabiliW to the Sulfir Plant 52e Submit a semiannual report covering SRU recovery, emissions, operating parameters, and daily feed. The calculation of95% recovery from the sulfur recovery unit has become impractical due to the treatment of off gas from the sulfur recovery unit by a fluidized catalytic cracking unit's wet gas scrubber. A detailed summary of these changes was submitted on 619116. Summary of the Emissions Data Required by the Reporting Requirements of Part V (Affirmative Relief/Environmental Projects) Description of Any Problems Anticipated with Respect to Meeting the Requirements of Part V (Affirmative Relief/Environmental Projects) None for this report. Progress Report on the Implementation of the Requirements of Part VII (State Supplemental Environmental Project) Any Additional Matters to be Brought to the Attention of EPA and the State None for this report. CD tI Requirement Status/Comment Section VII. State Supplemental Environmental Proiec l45a Contribute $ 130,000 for purchase of mobile command post, which shall be acquired within 1 vear of date of entry. Complete. Delivery of mobile command post 418109. Public presentation 5 I 19109. l45b Submit a cost report and certification in the semiannual report upon completion of nroiect. Complete. Submitted with Semi-Annual Report dated 7 129 109, Attachment D. 147 Provide a progress report for the SEP in each semiannual report. Complete. Submitted with Semi-Annual Report dated 7 129 I 09. Attachment D. 13 CD tI Reouirement Status/Comment Section X. Reoortins and Recordkeeoins. !1149b. Emissions Data t49b Estimation of NOx emissions for each heater and boiler greater than 40 mmBtu/hr. 6Hl; 21.74 tpy, SHl; 9.89 gy, l2Hl;7 .12 tpy, 20H2;5.75 tpy, #5 Boiler; 0.14 py, #6 Boiler; 0.0 tpy (decommissioned in 2012), #8 Boiler; 2.30 fpy, #9 Boiler; 0.63 tpy, #10 Boiler; 1.38 tpy, #l I Boiler; 0.65 tpy. All NOx emissions for 8Hl, l2Hl,#5 Boiler, #8 Boiler, #9 Boiler, #10 Boiler, and #l I Boiler were estimated using stack testing results. All NOx emissions for 6Hl and20HZ were estimated using emission factors. t49b Estimate of NOx emissions as a sum for all heaters and boilers less than 40 mmBtu/hr. Estimated NOx emissions for all heaters and boilers less than 40 mmBtu/hr for the 2022 reportins vear:42.73 tpv (emission factors). r49b Estimate of SOz, CO and PM emissions as a sum for all heaters and boilers. Estimated emission for the 2022 reporting year are as follows: SOz; 10.09 tpy (CEMS), CO; 137.96 tpy (emission factor), PM (PMl0); 6.45 tpy (emission factor & stack testing), (PM2.5); 0.98 tov (emission factor & stack testins). t49b Estimate of SOz emissions from all Sulfur Recovery Plants. Estimated SOz emissions for the 2022 reporting year from all Sulfur Recovery Plants is 0 py (All SRU emissions are routed to a FCCU WGS). l49b SOz emissions from all acid gas flaring incidents bv flare. Reporting year 2022 had no acid gas flaring incidents. t49b NOx, SOz, PM, and CO emissions as a sum at each refinery for all other emissions units for which emissions information is required to be included in the facilities' AEI not identified above. Estimated emission for all other emissions units for the 2022 reporting year are as follows: NO*; 23.28 tpy, SOz; 3.19 tpy, CO; 123.18 tpy, PM (PM l0); 12.06 tpy, (PM2.5); 2.41 tpy. Summary of Annual Emissions Data for the Prior Calendar Year Exceedances of Emission Limits CD TI Limit Exceedances Section X. Reportins and Recordkeeoine. 1ll49c. Exceedances of Emission Limits t6 Interim NOx 7-day rolling average, corrected to 0oZ oxvsen. from FCCU No longer applicable. Complying with final limits. 16 Interim NOx 365-day rolling average, corrected to 0o% oxveen. from FCCU No longer applicable. Complying with final limits. 14 CD!I Limit Exceedances 2t Final NOx 7-day rolling average, corrected to 0oZ oxygen, from FCCU tQ2023: No Emission Limit exceedances. Total downtime of the CEM was 0.00% of the calendar quarter, as detailed in quarterly report submitted 4127123. 2Q2023: No Emission Limit exceedances. Total downtime of the CEM was 0.00% of the calendar quarter, as detailed in quarterly report submitted 7125123. 21 Final NOx 365-day rolling ayerage, corrected to |Yo oxygen, from FCCU tQ2023: No Emission Limit exceedances. Total downtime of the CEM was 0.00% of the calendar quarter, as detailed in quarterly report submitted 4127123. 2Q 2023: No Emission Limit exceedances. Total downtime of the CEM was 0.00% of the calendar quarter, as detailed in quarterly report submitted 7125123. 25 Final SOz 7-day rolling average, corrected to 0% oxygen, from FCCU lQ2023: No Emission Limit exceedances. Total downtime of the CEM was 0.00% of the calendar quarter, as detailed in quarterly report submitted 4127123. 2Q2023: No Emission Limit exceedances. Total downtime of the CEM was 0.00% of the calendar quarter, as detailed in quarterly report submitted 7125123. 25 Final SOz 365-day rolling average, corrected to 0% oxygen, from FCCU tQ2023: No Emission Limit exceedances. Total downtime of the CEM was 0.00% of the calendar quarter, as detailed in quarterly report submitted 4127123. 2Q2023: No Emission Limit exceedances. Total downtime of the CEM was 0.00% of the calendar quarter, as detailed in quarterly report submitted 7125123. 28 Interim SOz 7-day rolling average, corrected to 0olo oxygen. from FCCU No longer applicable. Complying with final limits. 28 Interim SOz 365-day rolling average, corrected to 0olo oxygen, from FCCU No longer applicable. Complying with final limits. 32 1.0 pounds PM per 1000 pounds of coke burned from FCCU Not applicable. Holly is subject to stricter limit of0.5 pounds PM per 1000pounds ofcoke burned from FCCU. 15 CDtt Limit Exceedances JJ 0.5 pounds PM per 1000 pounds ofcoke burned from FCCU lQ 2023: Emission Limit exceeded 1,25o/, of the calendar quarter. Total downtime of the CEM was 0.00% of the calendar quarter, as detailed in quarterly report submitted 4127123. 2Q2023: Emission Limit exceeded0.650/o of the calendar quarter. Total downtime of the CEM was 0.00% of the calendar quarter, as detailed in quarterly report submitted 7 I 25 I 23. 36 500 ppmvd CO l-hour average at0o/o oxygen, from FCCU tQ2023: Emission Limit exceeded0.65oh of the calendar quarter. Total downtime of the CEM was 0.00% of the calendar quarter, as detailed in quarterly report submitted 4127123. 2Q2023: Emission Limit exceeded 0.55% of the calendar quarter. Total downtime of the CEM was 0.00% of the calendar quarter, as detailed in quarterly report submitted 7 I 25 I 23 . 37 100 ppmvd CO 365-day average at0%o oxygen, from FCCU Not applicable. 46c NOx 3-hour rolline average. from 8H1 Not applicable. 46c NOx 3-hour rollins averase. from l2Hl Not aoolicable. 46c NOx 3-hour rolling average, from #5 Boiler Not applicable. 46c NOx 3-hour rolling average, from CO Boiler Not applicable. 46c NOx 3-hour rolling average, from #8 Boiler Not applicable. 46c NOx 3-hour rolling average, from FCCU Feed Heater Not applicable. 48 162ppm HzS 3-hour average, in fuel gas lQ2023: Emission Limit exceeded 0.05% of the calendar quarter. Total downtime of the CEM was 0.00% of the calendar quarter, as detailed in quarterly report submi tted, 4 1 27 1 23 . 2Q2023: Emission Limit exceeded 0.60% of the calendar quarter. Total downtime of the CEM was 0.00% of the calendar quarter, as detailed in quarterly report submitted 7 125 I 23 . 52a L6 tons per day sulfur, from SRP Emissions are combined with one of two FCCU wet gas scrubber stacks. A detailed summary of these changes was submitted on 619116. The limit at each FCCU wet gas scrubber is 0.05 tons per day for the combined SRU tail gas and regenerator scrubbed flue gas streams. 59 500 pounds SOz in a 24-hour period from acid gas flaring No incidents in period. L6 cDqt Limit Exceedances 68 500 pounds SOz in a24-hour period from hydrocarbon gas flaring Report for the incident on4/3123 was completed 5117123. Report submitted on 713U2023. Stack Tests - Emissions Monitored through Stack Testing 32,33 PM from FCCU Complete. PM performance testing completed onl2l20ll2. Report sent to EPAll23ll3. 46c NOx from 8Hl Complete. Stack test report submitted l2l15/08 to EPA and State of Utah in accordance with fl46d. 46c NOx from l2Hl Complete. Stack test report submitted l2ll5l08 to EPA and State of Utah in accordance with fl46d. 46c NOx from #5 Boiler Complete. Stack Testing completed 2l9ll0 and retested 3125110. Stack test report submitted 4l29ll0 with Notice of Intent. 46c NOx from CO Boiler Not applicable. 46c NOx from #8 Boiler Complete. Performance test completed on 4/22113. 46c NOx from FCCU Feed Heater Not applicable. t7 Attachment A SRP Summary Report SRP Summary Report no longer included per notification submitted to the Unhed State EPA ffice of Gvil Enforcement on June 9, 2016 detailing the charge in reportingfor the Sulfur Recovery Unit AUG .3 2OE DIVISION OF AIR OUALITY Attachment B TAB Analysis Reports BWON Samplsd Warte Str.m3 and R$ult 202ttdtutu H B. 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E Et e i I ,a E I , I tE , Attachment C Summary of BWON Lab Audit Teleplrone. +1 80'l 589 2632 www erm.com 12 April2023 AlVargas HollyFrontier Woods Cross Refining '1070 West 500 South West Bountiful, UT 84087 Reference: 06851 53 Subject: Benzene Waste Operations NESHAP (BWON) Third-Party Laboratory Audit Report Audit of the Chemtech-Ford (Chemtech) Laboratory, Salt Lake City, Utah Dear Al: This report documents the third-party audit of facility operations at the Chemtech-Ford (Chemtech) Laboratory in Salt Lake City, Utah, which the HollyFrontier (Holly) Woods Cross Refinery in Salt Lake City uses for analysis of benzene waste samples. Environmental Resources Management, lnc. (ERM) performed the audit on Tuesday, 28 March 2023,in accordance with the requirements of Holly Refining's Consent Decree (CD) with the United States Department of Justice. Callee Butcher of ERM served as the auditor. ERM performed an audit of Chemtech's laboratory and analytical services, including facility safety and chemical hygiene, quality assurance/quality controlsystems, certifications, employee training, sample traceability and reproducibility, sample receiving, data collection and reporting, subcontracting, vendor qualification, document management and retention, and corporate policies and procedures. The audit was based on a physical survey of the laboratory and examination of a sample of laboratory reports, manuals, policies and procedures, administrative and/or operating records, and interviews with key personnel. The following key staff were interviewed for the audit and facilitated onsite information gathering activities necessary to complete the audit: r Jenn Osborn, Director of Quality r Madeline Voloshin, Team Lead r Andrew Royer, Section Manager The compliance audit reviewed facility activities against applicable BWON requirements in Title 40 of the Code of Federal Regulations (40 CFR 61), Subpart FF; the CD; record retention requirements; and requirements associated with the National Environmental Laboratory Accreditation Conference (NELAC) Standard (United States Environmental Protection Agency lus EPAy600/R-04/003). FACILITY OVERVIEW AND DESCRIPTION The Chemtech Salt Lake City site is a contract-environmental laboratory site. The laboratory is located at 9632 South 500 West, Sandy, Utah 84070, and provides environmentalanalytical services for private and public sector clients under Standard lndustrial Classifications Codes (SlC) Code 8734. The laboratory conducts routine analyses of benzene waste samples from the Holly Refinery under Standard Methods 8021 and 8260C, and USEPA Method 624. The laboratory is [roo* - I srir" tooo I satt rare ciry, Utah 84r 1'1 ERM 12 April 2023 Reference: 0685 1 53 Page 2 o{ 2 accredited by the NELAC, which administers the National Laboratory Accreditation Program and is sponsored by the USEPA. The Chemtech facility includes one two-story building that houses analytical laboratories, offices, records, and supply storage. The laboratory was audited in October 2O22by the Utah Environmental Laboratory Certification Program (ELAP). All issues were resolved and corrective actions were documented and delivered to ELAP. FINDINGS For the purposes of this audit, a finding is defined as a departure from, or exception to, an existing applicable statute, regulation, permit, company standard, or policy that can be confirmed by the audit team. ERM identified no findings related to BWON sample analysis. The laboratory was identified as having sufficient systems in place for sample receiving, storage, analysis, and data collection/reporting related to BWON samples. The auditor did not identify any issues related to safety, chemical hygiene, quality assurance/quality control systems, or hazardous waste management. LIMITATIONS This assessment represents ERM's professional interpretation and judgment of existing conditions at Chemtech based on review of available records, facility inspections, and verbal interviews with site personnel, lt is ERM's intent that the findings presented herein be used as guidance only; ERM makes no guarantees, expressed or implied. Regulatory interpretation given in this report is provided by a technical expert and not an attorney-at-law. ERM appreciates the opportunity to assist Holly Refining with this important project. Please contact Callee Butcher at (801 ) 589-2632 or Wes Leavitt at (720) 938-051 5 if you have any questions. Sincerely, O.ur.ffidD Callee Butcher Consultant Director Project Manager V)*'fu Wes Leavitt, CIH Partner Attachment D LDAR Audit Summary FINAL Third-Party LDAR Audit Report HF Sinclair Woods Cross Refining LLC West Bountiful, Utah ,.tttF$nctor Emission Monitoring Service, Inc. Baton Rouge Office 450 Laurel Street, Suite 2010 Baton Rouge, LA 70801 luly2023 pdlahrpe lECriNtcAi clF()r.lP TABLE OF CONTENTS 1. INTRODUCTION 2. AUDIT METHODOLOGY 1-1 2-1 2-l 2-l 2. 1. Compliance Document Review Methodolory.... 2.2. LDAR Technician Observation 2.3. Field Review 2.4. Comparative Monitoring Methodology 2,4,1. Comparative Monitoring Leak Percentage........ 2.4.2. Historic Average Leak Percentaqe.................................. 2.4.2.2. Pumps 2.4.3. Comparative Monitoring Leak Ratio.................... 3. AUDIT RESULTS 3.1. Comparative Monitoring and Statistical Analysis Results 3.2. Program Strengths APPENDIX A: FINDINGS 3-1 HF Sinclair Woods Cross Refining [,LC LDAR Audit 2-3 2-3 2-3 ) -t" ',,,'...,,,.',.2.4 2-5 3-1 athtre Table 3-L. Comparative Monitoring Component Counts Table 3-2. Valve Comparative Monitoring Results Table 3-3. Pump Comparative Monitoring Results LIST OF TABLES tlF Sinclair Wootjs Cross Refining Ll,C l,l)AR ArrditAI6rrce 1: INTRODU-CT|ON Alliance Technical Group (ATG) conducted a third-party leak detection and repair (LDAR) audit at the HF Sinclair Woods Cross Refining LLC IHF Sinclair) petroleum refinery located in West Bountiful, Utah (the Woods Cross Refinery) in accordance with Paragraph 112 through 116 of the facility's Consent Decree. The audit included on- site activities and off-site database analysis. The site visit was conducted May 1, 2023 through May 4,2023. The audit scope consisted of the following key items: ) Compliance with LDAR requirements under the facility's Consent Decree;> Compliance with applicable LDAR regulations;o Utah Administrative Code R307-326-9; o 40 CFR 60, Subpart GGGa (NSPS GGGa); o 40 CFR 60, Subpart Wa (NSPS Wa), as referenced in NSPS GGGa;o 40 CFR 63, Subpart CC (MACT CC); and> Compliance with United States Environmental Protection Agency's (US EPA) Method 21. In accordance with Paragraph 112 of the Consent Decree, the specific tasks listed below were completed: ) Comparative monitoring for valves and pumps; ) Records review to ensure monitoring and repairs were completed in the required periods; > Field auditing to ensure affected equipment has been identified and included in the facility's LDAR program; ) Review of data management procedures; and> Observation of the LDAR technicians' calibration and monitoring techniques. ATG's LDAR audit methodology and results of the LDAR audit are discussed in the following sections of this report. all?atre HF' Sirrclair Woods Cross Refining l,LC LDAR Audit 1-1 2: AUDTT METHO-DOLOGY All items reviewed can be categorized as follows: review of compliance documents, LDAR technician observations, field review, and comparative monitoring. 2.1 . COMPLIANCE DOCUMENT REVIEW METHODOLOGY ATG provided an initial request for records to HF Sinclair on April 3,2023. The request included compliance records for the time period of April L,2027 through March 3L,2023. Provided documents were reviewed for compliance with the facility's Consent Decree, applicable LDAR regulations, and Method 2L. Method 21 monitoring and visual inspection data was requested and provided for the aforementioned time period. Data was analyzed to confirm that required monitoring/inspection frequencies and repair deadlines were met and that all required recordkeeping information was properly included. Evaluations were made on data collected by each LDAR technician to identify any anomalies that could indicate potential non-compliance or non- conformance with industry standards. Calibration records were reviewed for compliance with Method 21 to ensure proper calibration procedure. Delay of repair (DOR) records were reviewed to confirm proper documentation was maintained. Management of change (MOC) records were reviewed and discussed with facility personnel to ensure the MOC program adequately captures the addition and/or removal of LDAR equipment. In addition, the following records were reviewed to assess compliance with applicable Consent Decree requirements: > The written refinery-wide LDAR program; > Training records; > Initial attempt at repair of valves greater than 200 ppm;> Electronic storing and reporting of LDAR data;> QA/QCofLDARdata;> Calibration drift assessments;> DOR sign-offs; > Drill-and-taprecords;) Chronic leaker repair records;> Semiannual NSPS reports; and) Consent Decree reports. 2.2. LDAR TECHNICIAN OBSERVATIONS ATG performed LDAR technician observations to confirm compliance with 40 CFR 60, Appendix A-7, Method 21. Specifically, the following activities were observed: > Calibration techniques used by the monitoring personnel, including the precision test, daily calibration, calibration drift assessment, response time tests, verification of acceptable instruments and proper utilization of calibration gases. ) Monitoring techniques used by the monitoring personnel, including sample collection procedures (during which factors such as probe position and collection duration are considered), equipment operation, and on-site equipment maintenance. HF- Sinclail Woods Cross Refining LLC LDAR Audit EAliarrce 2-1 In addition, ATG discussed numerous aspects of Method 21 with the LDAR technicians to ensure methodologies utilized at the Woods Cross Refinery are compliant with regulatory requirements. 2.3. FIELD REVIEW During the audit, ATG performed unit walkthroughs and field review to identi$r potential non-compliance items throughout the Woods Cross Refinery. Specifically, ATG focused on the following: ) Open-ended valves or lines;> LDAR tagging (i.e., LDAR component identification); ) Leaker tags [i.e., leaking component identification);> Accessibility of components for monitoring;> Difficult-to-monitorandunsafe-to-monitordesignations;> Sampling connection system compliance; and> Pressure relief device compliance. The field review focused on component identification, tagging data management procedures, MOC procedures for tagging of new components, and LDAR work practices in the selected process units. ATG extracted a random assortment of components from the facility's LDAR database and verified that the components were correctly characterized in the database, As part of the random field review, ATG also examined select components included in the LDAR program to assess the quality of the MOC process. As part of this review, components listed as difficult-to-monitor were reviewed to determine the accuracy of the difficult-to-monitor designation. Additionally, ATG verified a subset of the pressure relief devices provided in the LDAR database were accurately tagged in the field. In order to evaluate best-in-class methods for tagging, ATG compiled a list of active leaking components, including components on delay of repair, and verified that each such component had a current leak tag with the proper information clearly displayed. In addition to current leaking components, ATG also verified that previously leaking valves were still tagged if subsequent monthly follow-up monitoring events had not yet been completed. In addition to reviewing the LDAR plan and procedures for leak repair when detected during Method 21 monitoring, ATG interviewed multiple operations and maintenance personnel to better understand the work practices in place for leak detection by audio, visual, olfactory (AVO) methods and what procedures are in place for repairing AVO leaks once they are detected. ATG also discussed field sampling procedures with operations and maintenance personnel and observed the sampling process to verifu that open-ended lines were not generated during routine sampling procedures. 2.4. COMPARATIVE MONITORING METHODOLOGY ATG performed comparative monitoring for a semirandomly selected subset of valves in gas/vapor and light liquid service and pumps in light liquid service in three (3) process units at the Woods Cross Refinery. ATG's monitoring results were then compared to the Woods Cross Refinery monitoring results obtained during the four complete quarters immediately preceding the audit (i.e., second quarter 2022 through first quarter 2023), as prescribed in Paragraph 1 L2 ofthe Consent Decree. The comparative monitoring leak percentage, historic average leak percentage, and comparative monitoring leak ratio were calculated as outlined below. HF Sinclail Woods Cross }lefining l,l,C LDAR Autlitall?atre 2.4.1. Comparative Monitoring Leak Percentage In accordance with Paragraph 112.a of the Consent Decree, the Comparative Monitoring Leak Percentage is calculated for valves and pumps by comparing the number of leaking components found during the audit to the total number of components monitored during the audit for each process unit included in the comparative monitoring analysis. Note that only a subset of components was monitored for this analysis. Therefore, 95%o confidence intervals are calculated in order to estimate the range in which the actual leak rate for valves should fall, based on the fact that the comparative monitoring tested only a sub-sample of components for only a single point in time. The 950/o confidence intervals are estimated using the definition of a normal confidence interval, defined in Equation 1. Where: CI=X= rd/2, n-1 Sn= n= Equation 1. Conlidence Intervals CI=X*totz,r-t!1n Confidence Interval The estimated sample average value The 97.5th percentile from the Student-t distribution with n-1 degrees of freedom Standard deviation for audit leak rates Sample size It should be noted that the 950/o confidence intervals for pumps is typically much larger than those for valves. Because there are so few pumps in each process unit, the audit leak percentage will necessarily be less statistically significant than the leak percentage for valves. 2.4.2. Historic Average Leak Percentage This section describes the calculation methodology for each type of subject equipment (i.e., valves and pumps) in accordance with Paragraph tLZ,b of the Consent Decree. Because the Consent Decree does not define a specific methodology to determine Ieak percentage, the leak percentage is calculated as specified in NSPS Wa. 2.4.2.1. Volves The Historic Average Leak Percentage for valves is calculated as specified in NSPS Wa. Calculations were performed based on monitoring data provided by HF Sinclair. Data from the four (4) quarterly monitoring periods immediately preceding the audit (i.e., second quarter 2022 through first quarter 2023) was used for this analysis. Based on Paragraph 120 of the facility's Consent Decree, the leak definition is a Method 21 reading of 500 ppm or greater. Equation 2. Percent Leaker Calculation for Valves o/oVy 100 Where: Percentage of leaking valves HI; Sinclair Woods Cross Ref ining l,l,C I.DAR Audit =(h)" Alflarce o/oVu 'z-3 Vr. Vr Number of valves found leaking Total number of valves monitored in the monitoring period The total number of valves monitored during a period, Vr, is determined by summing the total number of unique valves monitored. If a valve is monitored more than once during a period, it is still only counted once for the purposes of Vr. If a valve is found to be leaking one or more times during a monitoring period, regardless of how many times it was monitored, the valve is still only counted once for Vr, as well as once for Vr.. 2.4.2.2. Pumps Since pump percent leaker calculations are not defined under NSPS Wa, ATG has elected to utilize an analogous methodology as prescribed for valves. Calculations were performed based on monitoring data provided by HF Sinclair. Data from the four complete quarters immediately preceding the audit (i.e., April 2022 through March 2023) was used for this analysis. Based on Paragraph 121 of the facility's Consent Decree, the leak definition is a Method 21 reading of 2,000 ppm or greater. Equation 3. Percent Leaker Calculation for Pumps o/oP7=(&)"roo Where: Percentage of leaking pumps Number of pumps found leaking Total number of pumps monitored in the monitoring period The total number of pumps monitored during a period, Pr, is determined by summing the total number of unique pumps monitored. If a pump is monitored more than once during a period, it is still only counted once for the purposes of Pr. If a pump is found to be leaking one or more times during a monitoring period, regardless of how many times it was monitored, the pump is still only counted once for Pr, as well as once for Pr.. 2.4.3. Comparative Monitoring Leak Ratio The Comparative Monitoring Leak Ratio is used to assess the accuracy of the facility's historic monitoring results based on results of comparative monitoring conducted during the audit. In accordance with Paragraph 712.c of the Consent Decree, this ratio is calculated by dividing the Audit Leak Percentage by the Historic Average Leak Percentage, both described above. In accordance with Paragraph 117 of the Consent Decree, a Comparative Monitoring Leak Ratio greater than or equal to 3.0 shall be deemed an area of non-compliance and cause for corrective action. In addition to calculating the Comparative Monitoring Leak Ratio, the range of possible Comparative Monitoring Leak Ratios given the 950/o confidence intervals were also calculated based on the audit leak percentage. This calculation is performed to give a complete range of possibilities for the Comparative Monitoring Leak Ratio given the number of components monitored during the audit. o/oPt = Pl= Pr= HF Sinclair Woocis Cross Refining LLC LDAR AuditAl6rrce 2-4 Z. q.q. Chi-square Statistic An additional statistical test called the Chi-Square was performed; this test indicates a percent probability that two data sets are in strong agreement. The Chi-Square Statistic is intended to compare two sets of data with no assumption that one set of data is the standard to which the other is to be compared. However, for this audit, the historic site data is compared to the audit data, which is assumed to be the standard for comparison. Because the audit was performed to confirm the rigor of previous monitoring, HF Sinclair is concerned only with audit data that shows a higher leak rate than historic monitoring. If the historic leak percentage for a component in a process unit is higher than or equal to the audit leak percentage, the Chi-square Statistic is set to 7000/0, indicating that the historic data shows extremely rigorous monitoring as compared to the audit data. However, if audit data shows a higher leak percentage than historic data, the Chi-Square Statistic shows how closely the audit and site data correlate; a percentage closer to 100olo indicates a stronger agreement. It should be noted t}ta! similar to confidence intervals, the Chi-Square Statistic is more statistically significant with a higher amount of data points. at6tre HF Sinclair Woods Cross Refining LLC LDAR Audit 2-5 3. AUDIT RESULTS The table provided in Appendix A presents the potential compliance deviations (i.e., findings) noted during the audit. 3.1. COMPARATIVE MONITORING AND STATISTICAL ANALYSIS RESULTS Three (3) process units were selected for comparative monitoring at the Woods Cross Refinery: ) 08-Crude; > L9-LCOIDHT;and> 26-Poly. These three (3) units were chosen to represent process units across all spectrums of percent leakers: high, medium, and low. These units were also chosen because they were operating at the time of the audit and were not used for the comparative monitoring analysis performed during the previous audit. ATG semi-randomly monitored a minimum of 25o/o of the valves and pumps for each selected process unit in accordance with Paragraph 772 of the Consent Decree. To ensure randomness when monitoring in each selected unit, ATG monitoring technicians did not utilize a pre-set route from the facility's database. Rather, components were randomly selected for monitoring at the time of the comparative monitoring analysis based on the knowledge and experience of the monitoring personnel. In this way, personnel walked throughout each unit monitoring a randomly selected subset of components in a given process area. After monitoring personnel randomly selected components for monitoring in a process area, personnel proceeded to move across the process unit, ensuring a subset of components throughout each area within the unit were included in the comparative monitoring analysis. A mixture of easily accessible components and components on towers and up platforms were monitored to ensure a representative sample based on each unit's configuration, Component population counts, 250lo thresholds, and number of components selected for comparative monitoring are provided in Table 3-1 below. 1. There are 5 pumps in light liquid service in O8-Crude; however, only 3 were in service at the time of the audit. 2. No pumps in light liquid service operated in the 19-LCO/DHT unit. 3. All pumps in light liquid service in the 26-Poly follow the dual mechanical seal compliance option. Comparative monitoring results are provided in Table 3-2 and 3-3 below. IIF Sinclair Woods Cross Refining LLC I.DAR Audit Table 3-1, Comparative Monitoring Component Counts Unit Valve Analysis Pump Analysis1,2,3 Pouulation 2So/o Audited Population 2So/o Audited 0B-Crude 809 203 204 3 t 3 19-LCO/DHT 954 239 240 N/A N/A N/A 26-Polv 7283 327 332 N/A N/A N/A Al6rrce 3-1 Table 3-2. Valve Comparative Monitoring Results Unit Valve Leak Percentage Confidence Interyal I Comparative Monitoring Leak Ratio chi- Square Value 2HistoricAuditLow Hieh 08-Crude 0.22o/o 0.000/o 0.0070 L.79o/o 0.00 100.000/o 19.LCO/DHT 0.690/o 0.42o/o 0.07o/o 2.30o/o 0.60 100.00%o 26-Polv 0.940/o 0.30o/o 0.0lo/o \.670/o 0.32 100.00%o 1. Confidence intervals are set at 95ol0. 2. Chi-Square values are set to 100o/o ifthe historic leak percentage is higher than the audit leak percentage. Table 3-3. Pump Comparative Monitoring Results 1. Confidence intervals are set at 95ol0. 2. Chi-Square values are set to 100% if the historic leak percentage is higher than the audit leak percentage. 3. No pumps subject to periodic (i.e., monthly) Method 21 monitoring are operated in the 19-LCO/DHT or 26-Poly units. As prescribed in Paragraph lL7 of the Consent Decree, a Comparative Monitoring Leak Ratio of 3.0 or higher shall be deemed an area of non-compliance and cause for corrective action. As such, the results provided in Table 3-1 and 3-2 suggest compliant Method 21 monitoring for the Woods Cross Refinery, as all ratios are below the 3.0 action level. 3.2. PROGRAM STRENGTHS Overall, the Woods Cross Refinery LDAR program had multiple strengths worthy of mention. Specifically, ATG observed the following program strengths: > LDAR tagging and component identification for normal-to-monitor components, as well as detailed and accurate location descriptions within the database, ensure components are accurately accounted for and monitored efficiently;> All personnel groups work effectively to minimize open-ended lines, as observed from zero missing caps/plugs on drain and bleeder valves;> Effective communication between personnel groups, including the LDAR Coordinator, LDAR Contractor Personnel, Operations, and Maintenance, results in high-quality LDAR program management; and> The HF Sinclair LDAR Coordinator and LDAR Contractor Personnel (Operations Manager, Site Supervisor, and LDAR Technicians) are extremely knowledgeable and confident with their roles and responsibilities at the facility. llF- Sinclair Wootls Closs Ilefining LLC LDAR Audit Unit Pump Leak Percentage Confidence Interyal r Comparative Monitoring Leak Ratio chi- Square Value 2Historic Audit Low Hish 08-Crude 0.007o 0.000/o 0.0070 70.760/o 0.00 100.00%o 19-LCO/DHT3 N/A N/A N/A N/A N/A N/A 26-Polv3 N/A N/A N/A N/A N/A N/A AI6rrce 3-2 APPENDIX A: FnNDINGS ffi AUG - 3 2023 F OJJ E d eO E\ FEE;+4 n=5n + ,ag .=d oE 3, = a-?EE 6E,F:E .9€>! da o's ia +4 ;! 09:2a^ d ;,:u*d oE 3, =-- E:.8AE.J eE! 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Flaring Incident Report Brief Description of Incident: SO2 Release After Multiple Units Shutdown lncident End Date: 410412023 Incident Type: tr Acid Gas (report due 45 days after end of event) EI Hydrocarbon (report due in next quarterly NSPS, semiannual CD and MACT reports) M Excess Volume (report due in next semiannual MACT report) EI Excess HzS (report due in next quarterly CEMS report) CD '1159. Report due: 511912023 (45-dav\,7131/2023 (Semiannual CD and MACT reoorts) CD fl59.a. Start dates and times (list all if multiple releases are related to a sinsle event) Start Date Start Time End Date End Time 4/3/23 8:20 am 4/4123 3:28 am CD fl59.b. Emission Calculations for SOz from Flarins (round to one decimal point): Constants:8.44x I 0-5 : lbmole HzS/37 9 scf HzS][64 lbs SOz/lbmole H:S] [ton/2000 lbs] 0. I 69 : [bmole HzS/379 scf HzS]F .0 lbmole SOz/l lbmole HzSl[6a lb Sor/lb mole SOz] FR: Avg. flow rate to flare durins incident (scftr)l19.863.6 TD: Total duration of incident (hours)19.I ConcHzS : Avg. conc. of HzS in gas flared (vol. fraction. scf HzS/scf eas)0.003 Tons of SOu: [FRllTDllConcHrSlt8.44 x l0{l 0.7 ER: Emission rate (lbs SOz/trour): [FRllConcHzSl[0.169]69.2 Root Cause Analvsis (CD tl59.d. and Subnart Ja) Details of lncident: Following an external power outage which upset most of the plant's units, off gases overwhelmed the Flare Gas Recovery Unit. This resulted in both an exceedance of the flare gas flow threshold for the interconnected flare system, as well as a release of SOz in excess of 500lbs. Sequence of events in reverse order Result..Relief eas containinq SO2 was sent to the flare. ..caused bv..Multiple internal process units lost power and shut down. ..caused by..The substation faulted, intemrpting downstream power. ..caused bv..A fault cascaded through substation's re-closers. ...caused by..The bouncins lines contacted each other. ...caused bv..Heavy snow dislodged from lines at the external Parrish substation. Root Cause(s): Heavy snow caused an upset at the external Rocky Mountain Power operated substation. Pase 2 of3 art Flaring Incident Report Force majeure? tr No El Yes Significant contributing causes: Heavy snowfall caused a service intemrption at the Parrish substation. Corrective action required? tr Yes MNo If no, explain basis for conclusion: Power intemrption was caused by an extemal force. CD fl59.e. Alternative measures available to reduce the likelihood of a recurrence: Measure I N/A Measure 2:N/A Measure 3:N/A Measure I Probable effectiveness: Estimated cost: Should an outside consultant be retained to assist in the analysis of alternatives? tr Yes trNo Evaluation of possible changes: Design: Operation: Maintenance: Status: tr Completed tr Schedule for implementation:Commencement: Completion: Measure 2 Probable effectiveness: Estimated cost: Should an outside consultant be retained to assist in the analysis of alternatives? tr Yes trNo Evaluation of possible changes: Desien: N/A Operation: Procedures and training will need to be developed. Maintenance: Procedures and trainine will need to be develooed. Status: tr Completed tr Schedule for implementation:Commencement: Completion: Measure 3 Probable effectiveness : Estimated cost: Should an outside consultant be retained to assist in the analysis of alternatives? tr Yes trNo Evaluation of possible chanqes: Design: Operation: Maintenance: Flaring Incident Report trC leted tr Schedule for implementation: CD fl59.f. Statement Identifuing Grounds for Stipulated Penalties fl62. Grounds for stipulated penalties due to root cause tr None tr Careless operation tr Failure to follow written procedures tr Equipment failure due to failure to operate and maintain equipment in accordance with good engineering practice. Defenses tr Force Maieure tr Startup/Shutdownfupset fl63. Grounds for stipulated penalties due to frequency tr None tr SOz emissions > 20.0 pounds/hour for 3 consecutive hours or more and tr Failure to act in accordance with PMO Plan tr Took no action to limit duration or quantity ofSOz ! Total of Acid Gas Flaring Incidents in rolline l2-month oeriod >5 fN/A) Defenses E Force Maieure tr Malfunction tr Startup/Shutdownfuoset fl64. Grounds for stipulated penalties due to cause recuffence tr First time tr Root cause was sudden, infrequent, and not reasonably preventable tr Root cause was sudden, infrequent. and reasonablv preventable tr Recurrence: Root cause was result of previously-identified root cause tr Malfunction E Recurrence. agreed-upon malfunction E Recurrence, corrective action plan not yet completed E Recurrence, root cause investisation still underwav Clarification on first time or recrurence: Defenses tr Force Majeure tr Malfunction tr Startup/Shutdown/Upset tr Corrective action being developed tr Root cause of investigation pending CD fl59.e. WilyDid investisation take lonser than 45 davs? D No tr Yes lf yes, when will investigation be complete and report sent to EPA? CD fl59.h. Will corrective action take > 45 days? tr No tr Yes (followup report to EPA w/in 30 days)