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DAQ-2024-011523
1 DAQC-1124-24 Site ID 10123 (B5) MEMORANDUM TO: FILE – HF SINCLAIR WOODS CROSS REFINING, LLC THROUGH: Harold Burge, Major Source Compliance Section Manager FROM: Rob Leishman, Environmental Scientist DATE: November 7, 2024 SUBJECT: Holly Refining and Marketing (Holly Refinery), Major, SIP, Title V, MACT, Davis County FRS # UT00000049001100013 INSPECTION TYPE: State Electronic Data Report (SEDR) Review REVIEW DATE: November 7, 2024 SOURCE LOCATION: West Bountiful/Davis County SOURCE CONTACT: Matt Howes - 801-397-7412 APPLICABLE REGULATIONS: Title V operating permit 1100013001, dated May 3, 2024 Last Revised May 3, 2024 November 15, 2023 – DAQE-AN1012300587-23 – Approval Order November 18, 2013 – DAQE-AN101230041-13 – Approval Order SOURCE INSPECTION EVALUATION: With the exception of sources that only monitor for opacity, quarterly report memoranda will only address the findings of the quarterly report. Approval Order and Title V permit conditions addressing continuous emission monitoring requirements will be addressed in Holly Refinery’s relative accuracy performance specification test review memorandum. SEDR Review: Third Quarter 2024 % Monitor Availability (MA) Performance Test Dates (N/A to Opacity) Summary of Excess Emissions During Point Source Operation Point Source Op. hrs. Channel MA CGA Lin RATA Point Source Channel Hrs. Limitation Amine Plant 2208 H2S 100% 09/09/24 04/30/24 Amine Plant H2S 17.00 160 ppm - 3- hour RA U4 FCCU 2208 CO 99% 09/18/24 05/01/24 Amine Plant H2S 0.00 60 ppm - 365- day RA U4 FCCU 2208 CO2 99% 09/18/24 05/01/24 Sulfur Recovery Unit SO2 0.00 100 ppm - 12- hour RA 1 8 2 2 Third Quarter 2024 % Monitor Availability (MA) Performance Test Dates (N/A to Opacity) Summary of Excess Emissions During Point Source Operation Point Source Op. hrs. Channel MA CGA Lin RATA Point Source Channel Hrs. Limitation U4 FCCU 2208 NOx 99% 09/18/24 05/01/24 U4 FCCU CO 9.00 500 ppm - hourly U4 FCCU 2208 SO2 99% 09/18/24 05/01/24 U4 FCCU NOx 0.00 40 ppm - 7- day RA U4 FCCU 2208 O2 99% 09/18/24 05/01/24 U4 FCCU NOx 0.00 22.5 ppm - 365-day RA U4 FCCU 2208 Particulate 100% U4 FCCU SO2 0.00 50 ppm - 7- day RA U4 FCCU 2208 Particulate 100% U4 FCCU SO2 0.00 25 ppm - 365- day RA Sulfur Recovery Unit 2208 SO2 99% 09/18/24 05/01/24 U4 FCCU Particulate 0.00 9.2 in H2O - hourly Sulfur Recovery Unit 2208 O2 99% 09/18/24 05/01/24 U4 FCCU Particulate 0.00 66 psi - hourly Crude Unit 2208 O2 100% 05/16/24 08/14/24 Crude Unit O2 0.00 5 ppm - hourly North Flare 2208 H2S 100% 09/11/24 03/26/24 North Flare H2S 34.00 162 ppm - 3- hour RA North Flare 2208 TRS 100% 09/18/24 South Flare H2S 0.00 162 ppm - 3- hour RA South Flare 2208 H2S 100% 09/11/24 03/27/24 U25 FCCU CO 127.00 500 ppm - hourly South Flare 2208 TRS 100% 09/19/24 U25 FCCU NOx 0.00 80 ppm - 7- day RA U25 FCCU 2208 CO 100% 06/20/24 08/14/24 U25 FCCU NOx 0.00 40 ppm - 365- day RA U25 FCCU 2208 CO2 100% 06/20/24 08/14/24 U25 FCCU SO2 0.00 50 ppm - 7- day RA U25 FCCU 2208 NOx 100% 06/20/24 09/10/24 U25 FCCU SO2 0.00 25 ppm - 365- day RA U25 FCCU 2208 SO2 100% 06/20/24 08/14/24 U25 FCCU Particulate 0.00 15.2 in H2O - 3-hour RA U25 FCCU 2208 O2 100% 06/20/24 08/14/24 U25 FCCU Particulate 0.00 0.21 GPM/MSCFH - 3-hour RA U25 FCCU 2208 Particulate 100% U25 FCCU 2208 Particulate 100% Excess Emission Report - Hourly Summary Point Source Channel Startup & Shutdown Control Equipment Problems Process Problems Other Known Causes Unknown Causes Emission Limit Amine Plant H2S 0 0 17 0 0 160 ppm - 3-hour RA Amine Plant H2S 0 0 0 0 0 60 ppm - 365-day RA 3 Excess Emission Report - Hourly Summary Point Source Channel Startup & Shutdown Control Equipment Problems Process Problems Other Known Causes Unknown Causes Emission Limit Sulfur Recovery Unit SO2 0 0 0 0 0 100 ppm - 12-hour RA U4 FCCU CO 4 0 9 0 0 500 ppm - hourly U4 FCCU NOx 0 0 0 0 0 40 ppm - 7-day RA U4 FCCU NOx 0 0 0 0 0 22.5 ppm - 365-day RA U4 FCCU SO2 0 0 0 0 0 50 ppm - 7-day RA U4 FCCU SO2 0 0 0 0 0 25 ppm - 365-day RA U4 FCCU Particulate 5 0 0 0 0 9.2 in H2O - hourly U4 FCCU Particulate 6 0 0 0 0 66 psi - hourly Crude Unit O2 0 0 0 0 0 5 ppm - hourly North Flare H2S 21 1 26 7 0 162 ppm - 3-hour RA South Flare H2S 1 0 0 0 0 162 ppm - 3-hour RA U25 FCCU CO 0 0 127 0 0 500 ppm - hourly U25 FCCU NOx 0 0 0 0 0 80 ppm - 7-day RA U25 FCCU NOx 0 0 0 0 0 40 ppm - 365-day RA U25 FCCU SO2 0 0 0 0 0 50 ppm - 7-day RA U25 FCCU SO2 0 0 0 0 0 25 ppm - 365-day RA U25 FCCU Particulate 0 0 0 0 0 15.2 in H2O - 3-hour RA U25 FCCU Particulate 0 0 0 0 0 0.21 GPM/MSCFH - 3-hour RA CMS Performance Summary - Hourly Summary Point Source Channel Monitor Malfunction Non-monitor Malfunction QA Calibrations Other Known Causes Unknown Causes Amine Plant H2S 0 0 0 0 0 U4 FCCU CO 0 21 0 0 0 U4 FCCU CO2 0 21 0 0 0 U4 FCCU NOx 0 21 0 0 0 U4 FCCU SO2 0 21 0 0 0 U4 FCCU O2 0 21 0 0 0 U4 FCCU Particulate 0 0 0 0 0 U4 FCCU Particulate 0 0 0 0 0 Sulfur Recovery Unit SO2 0 21 0 0 0 Sulfur Recovery Unit O2 0 21 0 0 0 Crude Unit O2 0 0 0 0 0 North Flare H2S 0 0 2 0 0 4 CMS Performance Summary - Hourly Summary Point Source Channel Monitor Malfunction Non-monitor Malfunction QA Calibrations Other Known Causes Unknown Causes North Flare TRS 0 0 0 0 0 South Flare H2S 0 0 0 0 0 South Flare TRS 0 11 0 0 0 U25 FCCU CO 0 0 4 0 0 U25 FCCU CO2 0 0 2 0 0 U25 FCCU NOx 0 0 4 0 0 U25 FCCU SO2 0 0 4 0 0 U25 FCCU O2 0 0 4 0 0 U25 FCCU Particulate 0 0 0 0 0 U25 FCCU Particulate 0 0 0 0 0 Pollutant Concentration Exceeded Span of CEM Monitor Outage During Point Source Operation Alternate Sampling CEM Modifications 0 Hours 178 Hours 0 Hours 0 Events SOURCE INSPECTION SUMMARY EVALUATION: HF Sinclair Woods Cross Refining, LLC maintains its CEMS as required in R307-170 and 40 CFR 60.13. CURRENT RECOMMENDATIONS: All deviations appear to be a result of breakdown or process related problems that do not warrant issuing a violation. HF Sinclair Woods Cross Refining, LLC was in compliance during this reporting period. No further enforcement action is recommended. HF Sinclair Woods Cross Refining, LLC’s NSPS monitoring system meets the performance standards of 40 CFR 60, Appendix B Performance Specifications. HPV: No RECOMMENDATION FOR NEXT INSPECTION: Check DAS for daily zero and span drift. Check the QC program to ensure that monitor drift is being tracked and that the source can identify excessive drift. ATTACHMENTS: Excel spreadsheet review HF Sinclair Refinery EER 3Q2024 Point Source Information Late Expired Cal. Gas Valid Cal. Gas Days Yes No 1 Type Code 100 (Company Information)Type Code Company Manager Company Name AIRS # Phone Number Environmental Contact 1 100 Dustin Simmonds 01100013 (801) 397-7412 Matt Howes 1 100 0 0 0 0 1 Type Code 110 (Point Source Identification)Type Code Point Source Quarter 1 - 4 Year Point Source Operating Hrs. in Quarter 1 110 3 2024 2208 1 110 3 2024 2208 1 110 3 2024 2208 1 110 3 2024 2208 1 110 3 2024 2208 1 110 3 2024 2208 1 110 3 2024 2208 1 110 0 0 0 1 Type Code 200 (Monitor Identification)Type Code Point Source Channel Manufacturer Model No. Monitor SN Low Span High Span Installation Date Monitor Location 1 200 H2S Siemens 3004945670 10 - 300 4/1/2021 Fuel Line 1 200 O2 Ametek Thermox WDG-IV 10208656 - 20 8/17/2015 Stack 1 200 H2S Extrel Max 300-RTG 62582 - 300 11/8/2018 Flare Line 1 200 TRS Thermo Scientific Sola II SL-09960914 2000 30 11/11/2015 Flare Line 1 200 H2S Extrel Max 300-RTG 62585 - 300 11/8/2018 Flare Line 1 200 TRS Thermo Scientific Sola II SL-09970914 2000 30 11/11/2015 Flare Line 1 200 O2 Ametek 9900RM 9900-S1616-1 - 20 2/7/2023 Stack 1 200 SO2 Teledyne Monitor Labs T100H 467 - 200 5/30/2021 Stack 1 200 CO SICK MCS100E 15062323 - 1000 6/1/2016 Stack 1 200 CO2 SICK MCS100E 15062323 - 20 6/1/2016 Stack 1 200 NOx SICK MCS100E 15062323 - 200 6/1/2016 Stack 1 200 O2 SICK MCS100E 15062323 - 20 6/1/2016 Stack 1 200 Particulate Rosemount 3051CG4A22A1AS1M5K5Q4Q83051CG4A22A1AS1M5K5Q4Q8- - 6/1/2016 Stack 1 200 Particulate Flexim/SICK Maihak US-7407/SIC 199 F704/15062323 - - 9/20/2017 Stack 1 200 SO2 SICK MCS100E 15062323 - 200 6/1/2016 Stack 1 200 CO Teledyne Monitor Labs T300 5404 - 1000 5/30/2021 Stack 1 200 CO2 Teledyne Monitor Labs T300 5404 - 0.2 5/30/2021 Stack 1 200 NOx Ametek 9900RM 9900-S1616-1 - 200 2/7/2023 Stack 1 200 O2 Ametek 9900RM 9900-S1616-1 - 20 2/7/2023 Stack 1 200 Particulate Rosemount 3051CG2A22A1AS1E5M5Q4Q82278010 - - 10/27/2012 Stack 1 200 Particulate Rosemount 3051TG3A2B21AS1E5M5Q4Q82278290 - - 10/27/2012 Stack 1 200 SO2 Teledyne Monitor Labs T100H 467 - 200 5/30/2021 Stack 1 200 0 0 0 0 0 0 1/0/1900 0 1 Type Code310 (Excess Emissions) SUMMARY REPORT Type Code Channel Total Hours of Excess Emissions Excess Emissions - % of Total Operating Hours RC 701 Hours - start up/Shutdown RC 702 Hours- Control Equipment Problems RC 703 Hours - Process Problems RC 704, 706, 707 Hours -Other Known Causes RC 705 Hours - Unknown Causes Emission Limitation Emission Limitation Units Emission Limitation Averaging Period 1 TRUE 310 H2S 17 0.77% 0 0 17 0 0 160 ppm 3-hour RA 1 TRUE 310 H2S 0 0.00% 0 0 0 0 0 60 ppm 365-day RA 1 TRUE 310 SO2 0 0.00% 0 0 0 0 0 100 ppm 12-hour RA 1 TRUE 310 CO 13 0.59% 4 0 9 0 0 500 ppm hourly 1 TRUE 310 NOx 0 0.00% 0 0 0 0 0 40 ppm 7-day RA 1 TRUE 310 NOx 0 0.00% 0 0 0 0 0 22.5 ppm 365-day RA 1 TRUE 310 SO2 0 0.00% 0 0 0 0 0 50 ppm 7-day RA 1 TRUE 310 SO2 0 0.00% 0 0 0 0 0 25 ppm 365-day RA 1 TRUE 310 Particulate 5 0.23% 5 0 0 0 0 9.2 in H2O hourly 1 TRUE 310 Particulate 6 0.27% 6 0 0 0 0 66 psi hourly 1 TRUE 310 O2 0 0.00% 0 0 0 0 0 5 ppm hourly 1 TRUE 310 H2S 55 2.49% 21 1 26 7 0 162 ppm 3-hour RA 1 TRUE 310 H2S 1 0.05% 1 0 0 0 0 162 ppm 3-hour RA 1 TRUE 310 CO 127 5.75% 0 0 127 0 0 500 ppm hourly 1 TRUE 310 NOx 0 0.00% 0 0 0 0 0 80 ppm 7-day RA 1 TRUE 310 NOx 0 0.00% 0 0 0 0 0 40 ppm 365-day RA 1 TRUE 310 SO2 0 0.00% 0 0 0 0 0 50 ppm 7-day RA 1 TRUE 310 SO2 0 0.00% 0 0 0 0 0 25 ppm 365-day RA 1 TRUE 310 Particulate 0 0.00% 0 0 0 0 0 15.2 in H2O 3-hour RA 1 TRUE 310 Particulate 0 0.00% 0 0 0 0 0 0.21 GPM/MSCFH3-hour RA 1 310 0 0 0 0 0 0 0 0 0 South Flare U25 FCCU U25 FCCU U25 FCCU U25 FCCU U25 FCCU U25 FCCU U25 FCCU 0 HF Sinclair Woods Cross Refining LLC 0 Amine Plant Crude Unit North Flare North Flare South Flare South Flare Sulfur Recovery Unit Sulfur Recovery Unit U25 FCCU U25 FCCU U25 FCCU U4 FCCU U4 FCCU U4 FCCU U4 FCCU U4 FCCU Amine Plant Amine Plant U4 FCCU 0 U4 FCCU Sulfur Recovery Unit U4 FCCU U4 FCCU Crude Unit North Flare U4 FCCU U4 FCCU U4 FCCU U4 FCCU Amine Plant Crude Unit North Flare South Flare Sulfur Recovery Unit U25 FCCU U4 FCCU 0 U25 FCCU U25 FCCU U25 FCCU U25 FCCU U4 FCCU Point Source HF Sinclair Refinery EER 3Q2024 1 Type Code 300 (CMS Performance Summary) Type Code Channel Point Source Operating Hours Downtime - % of Total Operating Hours Total CMS Downtime RC 721 Hours - Monitor Malfunction RC 722 Hours - Non-monitor Malfunction RC 723 Hours - QA Calibrations RC 724 Hours - Other Known Causes RC 725 Hours - Unknown Causes 1 TRUE 300 H2S 2208 0.00% 0 0 0 0 0 0 1 TRUE 300 CO 2208 0.95% 20.98333333 0 20.98333333 0 0 0 1 TRUE 300 CO2 2208 0.95% 20.98333333 0 20.98333333 0 0 0 1 TRUE 300 NOx 2208 0.95% 20.98333333 0 20.98333333 0 0 0 1 TRUE 300 SO2 2208 0.95% 20.98333333 0 20.98333333 0 0 0 1 TRUE 300 O2 2208 0.95% 20.98333333 0 20.98333333 0 0 0 1 TRUE 300 Particulate 2208 0.00% 0 0 0 0 0 0 1 TRUE 300 Particulate 2208 0.00% 0 0 0 0 0 0 1 TRUE 300 SO2 2208 0.95% 20.98333333 0 20.98333333 0 0 0 1 TRUE 300 O2 2208 0.95% 20.98333333 0 20.98333333 0 0 0 1 TRUE 300 O2 2208 0.00% 0 0 0 0 0 0 1 TRUE 300 H2S 2208 0.09% 2 0 0 2 0 0 1 TRUE 300 TRS 2208 0.00% 0 0 0 0 0 0 1 TRUE 300 H2S 2208 0.00% 0 0 0 0 0 0 1 TRUE 300 TRS 2208 0.50% 10.98333333 0 10.98333333 0 0 0 1 TRUE 300 CO 2208 0.18% 4 0 0 4 0 0 1 TRUE 300 CO2 2208 0.09% 2 0 0 2 0 0 1 TRUE 300 NOx 2208 0.18% 4 0 0 4 0 0 1 TRUE 300 SO2 2208 0.18% 4 0 0 4 0 0 1 TRUE 300 O2 2208 0.18% 4 0 0 4 0 0 1 TRUE 300 Particulate 2208 0.00% 0 0 0 0 0 0 1 TRUE 300 Particulate 2208 0.00% 0 0 0 0 0 0 1 300 0 0 0 0 0 0 1 Type Code 250 (Performance Specification RATA Results) Type Code Channel Date of Most Current RATA Date of Preceding RATA Months Between RATA's Units of Measurement CEM Value Reference Method Value Relative accuracy Pass/ Fail 1 361 Days 250 H2S 04/30/24 05/05/23 12 ppm 18.2 19.7 180.00% pass 1 363 Days 250 CO 05/01/24 05/04/23 12 ppm 95.89 95.34 200.00% pass 1 363 Days 250 CO2 05/01/24 05/04/23 12 ppm 14.9 15.23 240.00% pass 1 363 Days 250 NOx 05/01/24 05/04/23 12 ppm 13.72 19.44 860.00% pass 1 363 Days 250 SO2 05/01/24 05/04/23 12 ppm 0.044 0.017 20.00% pass 1 363 Days 250 O2 05/01/24 05/04/23 12 0 1.86 2.69 80.00% pass 1 363 Days 250 SO2 05/01/24 05/04/23 12 ppm 0.044 0.017 20.00% pass 1 363 Days 250 O2 05/01/24 05/04/23 12 0 1.86 2.69 80.00% pass 1 355 Days 250 O2 08/14/24 08/25/23 12 ppm 3.2 3.5 830.00% pass 1 379 Days 250 H2S 03/26/24 03/13/23 12 ppm 2.27 0 300.00% pass 1 369 Days 250 H2S 03/27/24 03/24/23 12 ppm 0.46 0 20.00% pass 1 356 Days 250 CO 08/14/24 08/24/23 12 ppm 128.1 141.3 410.00% pass 1 356 Days 250 CO2 08/14/24 08/24/23 12 0 13.3 15 1320.00% pass 1 383 Days 250 NOx 09/10/24 08/24/23 13 ppm 17.4 20.7 560.00% pass 1 356 Days 250 SO2 08/14/24 08/24/23 12 ppm 1.6 0 320.00% pass 1 356 Days 250 O2 08/14/24 08/24/23 12 0 2 2 570.00% pass 1 0 Days 250 0 01/00/00 01/00/00 0 0 0 0 0.00% 0 U4 FCCU U4 FCCU Amine Plant U25 FCCU U25 FCCU U25 FCCU U25 FCCU North Flare Sulfur Recovery Unit Sulfur Recovery Unit Crude Unit North Flare South Flare South Flare U25 FCCU U25 FCCU U25 FCCU U25 FCCU U25 FCCU Sulfur Recovery Unit Sulfur Recovery Unit Crude Unit North Flare South Flare U4 FCCU U4 FCCU U4 FCCU U4 FCCU U4 FCCU Amine Plant U4 FCCU U4 FCCU U25 FCCU U25 FCCU Point Source Point Source 0 U25 FCCU 0 U4 FCCU U4 FCCU U4 FCCU HF Sinclair Refinery EER 3Q2024 1 Type Code 260 (CGA Results)Type Code Channel Date Audit Point No. Cylinder ID Cylinder Expiration Date Type of Certification Units of Measurement CEM Value Cylinder Value Precision %Pass/ Fail Range - High or Low 1 Valid Cal. Gas 260 H2S 09/09/24 1 CC358743 04/19/25 EPA Traceability Protocolppm 56.6 59.9 550.00% pass low 1 Valid Cal. Gas 260 H2S 09/09/24 2 CC18730 02/28/27 EPA Traceability Protocolppm 178.8 183.6 260.00% pass high 1 Valid Cal. Gas 260 O2 05/16/24 1 EB0095843 11/25/27 EPA Traceability Protocol% 3.9 4 310.00% pass low 1 Valid Cal. Gas 260 O2 05/16/24 2 CC484626 02/26/27 EPA Traceability Protocol% 9.6 10.1 450.00% pass high 1 Valid Cal. Gas 260 H2S 09/11/24 1 CC216113 11/29/25 EPA Traceability Protocolppm 59.3 59.5 30.00% pass low 1 Valid Cal. Gas 260 H2S 09/11/24 2 CC504017 04/20/25 EPA Traceability Protocolppm 165.6 177.7 680.00% pass high 1 Valid Cal. Gas 260 TRS 09/18/24 1 CC10516 12/28/25 EPA Traceability Protocolppm 423.7 406.1 430.00% pass low 1 Valid Cal. Gas 260 TRS 09/18/24 2 CC456684 08/02/25 EPA Traceability Protocolppm 1293.7 1192 850.00% pass high 1 Valid Cal. Gas 260 TRS 09/18/24 1 SG9146387BAL 09/23/24 Primary Standard ppm 61611.7 59970 270.00% pass low 1 Valid Cal. Gas 260 TRS 09/18/24 2 CC55059 05/17/26 Certified Standard-SPECppm 186013.7 180100 330.00% pass high 1 Valid Cal. Gas 260 H2S 09/11/24 1 CC216113 11/29/25 EPA Traceability Protocolppm 56.8 59.5 460.00% pass low 1 Valid Cal. Gas 260 H2S 09/11/24 2 CC504017 04/20/25 EPA Traceability Protocolppm 170.9 177.7 380.00% pass high 1 Valid Cal. Gas 260 TRS 09/19/24 1 CC10516 12/28/25 EPA Traceability Protocolppm 427.7 406.1 530.00% pass low 1 Valid Cal. Gas 260 TRS 09/19/24 2 CC456684 08/02/25 EPA Traceability Protocolppm 1283.7 1200 700.00% pass high 1 Valid Cal. Gas 260 TRS 09/19/24 1 SG9146387BAL 09/23/24 Primary Standard ppm 53517.3 59970 1080.00% pass low 1 Valid Cal. Gas 260 TRS 9/19/24 2 CC55059 5/17/26 Certified Standard-SPECppm 199,076 180,100 11 pass high 1 Valid Cal. Gas 260 O2 9/18/24 1 CC509215 1/18/25 EPA Traceability Protocol% 5 5 1 pass low 1 Valid Cal. Gas 260 O2 9/18/24 2 EB0140936 9/29/24 EPA Traceability Protocol% 11 11 3 pass high 1 Valid Cal. Gas 260 SO2 9/18/24 1 CC470425 4/12/29 EPA Traceability Protocolppm 53 50 4 pass low 1 Valid Cal. Gas 260 SO2 9/18/24 2 CC476299 5/16/30 EPA Traceability Protocolppm 112 110 2 pass high 1 Valid Cal. Gas 260 CO 6/20/24 1 CC470425 4/12/29 EPA Traceability Protocolppm 247 249 1 pass low 1 Valid Cal. Gas 260 CO 6/20/24 2 CC476299 5/16/30 EPA Traceability Protocolppm 537 554 3 pass high 1 Valid Cal. Gas 260 CO2 6/20/24 1 CC511443 9/28/24 EPA Traceability Protocol% 6 6 5 pass low 1 Valid Cal. Gas 260 CO2 6/20/24 2 CC255701 6/22/24 EPA Traceability Protocol% 13 12 8 pass high 1 Valid Cal. Gas 260 NOx 6/20/24 1 CC470425 4/12/29 EPA Traceability Protocolppm 50 51 1 pass low 1 Valid Cal. Gas 260 NOx 6/20/24 2 CC476299 5/16/30 EPA Traceability Protocolppm 107 111 4 pass high 1 Valid Cal. Gas 260 O2 6/20/24 1 CC511443 9/28/24 EPA Traceability Protocol% 5 5 2 pass low 1 Valid Cal. Gas 260 O2 6/20/24 2 CC500960 9/9/24 EPA Traceability Protocol% 11 11 0 pass high 1 Valid Cal. Gas 260 SO2 6/20/24 1 CC470425 4/12/29 EPA Traceability Protocolppm 51 50 1 pass low 1 Valid Cal. Gas 260 SO2 6/20/24 2 CC315186 5/28/27 EPA Traceability Protocolppm 113 118 4 pass high 1 Valid Cal. Gas 260 CO 9/18/24 1 CC470425 4/12/29 EPA Traceability Protocolppm 255 249 2 pass low 1 Valid Cal. Gas 260 CO 9/18/24 2 CC476299 5/16/30 EPA Traceability Protocolppm 564 554 2 pass high 1 Valid Cal. Gas 260 CO2 9/18/24 1 CC511443 9/28/24 EPA Traceability Protocol% 6 6 0 pass low 1 Valid Cal. Gas 260 CO2 9/18/24 2 CC277518 10/6/24 EPA Traceability Protocol% 12 12 0 pass high 1 Valid Cal. Gas 260 NOx 9/18/24 1 CC470425 4/12/29 EPA Traceability Protocolppm 52 51 1 pass low 1 Valid Cal. Gas 260 NOx 9/18/24 2 CC476299 5/16/30 EPA Traceability Protocolppm 111 111 0 pass high 1 Valid Cal. Gas 260 O2 9/18/24 1 CC509215 1/18/25 EPA Traceability Protocol% 5 5 1 pass low 1 Valid Cal. Gas 260 O2 9/18/24 2 EB0140936 9/29/24 EPA Traceability Protocol% 11 11 3 pass high 1 Valid Cal. Gas 260 SO2 9/18/24 1 CC470425 4/12/29 EPA Traceability Protocolppm 53 50 4 pass low 1 Valid Cal. Gas 260 SO2 9/18/24 2 CC476299 5/16/30 EPA Traceability Protocolppm 112 110 2 pass high 1 260 0 1/0/00 0 0 1/0/00 0 0 0 0 0 0 0 1 Type Code 270 (Linearity Test Results)Type Code Channel Date Audit Point No. Cylinder ID Cylinder Expiration Date Type of Certification Units of Measurement CEM Value Cylinder Value Precision %Pass/ Fail Range - High or Low 1 270 0 01/00/00 0 0 01/00/00 0 0 0 0 0.00% 0 0 1 Type Code 210 (Pollutant Concentration Exceeded Span of CEM) Type Code Channel Start Date Start Time End Date End Time Hours 1 0 0 0 1/0/00 0:00 1/0/00 0:00 1 1 None Reported 1 0 TC 220 Hours 177.62 TC 220 Hours 0.00 TC 230 Hours 0.00 Events 0.00 Hours 0.00 Events 0.00 0.00 1 177.87 TC 300 Hours 0.25 FALSE U25 FCCU U25 FCCU U25 FCCU U4 FCCU 0 0 0 U4 FCCU U4 FCCU U4 FCCU U4 FCCU U4 FCCU U4 FCCU U4 FCCU U4 FCCU U4 FCCU Crude Unit Crude Unit U25 FCCU U25 FCCU South Flare North Flare North Flare North Flare North Flare North Flare Sulfur Recovery Unit U25 FCCU U25 FCCU South Flare U25 FCCU U25 FCCU U25 FCCU Type Code 210 (Pollutant Concentration Exceeded Span of CEM) Type Code 220 (Monitor Outage During Point Source Operation) Type Code 230 (Manual Sample - Alternate Sampling During Monitor Outage) Type Code 240 (CEM Modifications) Type Code 530 (Excess Emissions During Emergency Conditions) Type Code 550 (Changes in Operation in Control Equipment When CEM Data Not Available) Type Code 500 (Boiler Operating Days w/o 18 Hours of Data) Type Code 450 (Data Excluded) Point Source Point Source Point Source Yes North Flare South Flare South Flare South Flare South Flare Sulfur Recovery Unit Sulfur Recovery Unit Sulfur Recovery Unit Amine Plant Amine Plant None Reported None Reported None Reported None Reported None Reported None Reported HF Sinclair Refinery EER 3Q2024 Relative Accuracy Overview Point Source Channel Date of Most Current RATA Date of Preceding RATA Months Between RATA's Units Measured CEM Value Reference Method Value Relative Accuracy Pass/ Fail Amine Plant H2S 04/30/24 05/05/23 12 ppm 18.2 19.70 1.80 pass U4 FCCU CO 05/01/24 05/04/23 12 ppm 95.89 95.34 2.00 pass U4 FCCU CO2 05/01/24 05/04/23 12 ppm 14.9 15.23 2.40 pass U4 FCCU NOx 05/01/24 05/04/23 12 ppm 13.72 19.44 8.60 pass U4 FCCU SO2 05/01/24 05/04/23 12 ppm 0.044 0.02 0.20 pass U4 FCCU O2 05/01/24 05/04/23 12 1.86 2.69 0.80 pass Sulfur Recovery Unit SO2 05/01/24 05/04/23 12 ppm 0.044 0.02 0.20 pass Sulfur Recovery Unit O2 05/01/24 05/04/23 12 1.86 2.69 0.80 pass Crude Unit O2 08/14/24 08/25/23 12 ppm 3.2 3.50 8.30 pass North Flare H2S 03/26/24 03/13/23 12 ppm 2.27 0.00 3.00 pass South Flare H2S 03/27/24 03/24/23 12 ppm 0.46 0.00 0.20 pass U25 FCCU CO 08/14/24 08/24/23 12 ppm 128.1 141.30 4.10 pass U25 FCCU CO2 08/14/24 08/24/23 12 13.3 15.00 13.20 pass U25 FCCU NOx 09/10/24 08/24/23 13 ppm 17.4 20.70 5.60 pass U25 FCCU SO2 08/14/24 08/24/23 12 ppm 1.6 0.00 3.20 pass U25 FCCU O2 08/14/24 08/24/23 12 2 2.00 5.70 pass * NSPS CGA Third 2024 Audit Gas Ranges Audit Gas Ranges AP1 Low AP2 Low AP1 High AP2 High Amine Plant H2S 9/9/24 300 59.9 60 to 90 Amine Plant H2S 9/9/24 300 183.6 150 to 180 Crude Unit O2 5/16/24 20 4 4 to 6 Crude Unit O2 5/16/24 20 10.1 8 to 12 North Flare H2S 9/11/24 300 59.5 60 to 90 North Flare H2S 9/11/24 300 177.7 150 to 180 North Flare TRS 9/18/24 2000 406.1 400 to 600 North Flare TRS 9/18/24 2000 1192 1000 to 1200 North Flare TRS 9/18/24 300000 59970 60000 to 90000 North Flare TRS 9/18/24 300000 180100 150000 to 180000 South Flare H2S 9/11/24 300 59.5 60 to 90 South Flare H2S 9/11/24 300 177.7 150 to 180 South Flare TRS 9/19/24 2000 406.1 400 to 600 South Flare TRS 9/19/24 2000 1200 1000 to 1200 South Flare TRS 9/19/24 300000 59970 60000 to 90000 South Flare TRS 9/19/24 300000 180100 150000 to 180000 Sulfur Recovery Unit O2 9/18/24 20 4.9 4 to 6 Sulfur Recovery Unit O2 9/18/24 20 11.1 8 to 12 Sulfur Recovery Unit SO2 9/18/24 200 50.4 40 to 60 Sulfur Recovery Unit SO2 9/18/24 200 110.3 100 to 120 U25 FCCU CO 6/20/24 1000 249 200 to 300 U25 FCCU CO 6/20/24 1000 553.5 500 to 600 U25 FCCU CO2 6/20/24 20 6 5 to 8 U25 FCCU CO2 6/20/24 20 12 10 to 14 U25 FCCU NOx 6/20/24 200 50.9 40 to 60 U25 FCCU NOx 6/20/24 200 111.2 100 to 120 U25 FCCU O2 6/20/24 20 5.1 4 to 6 U25 FCCU O2 6/20/24 20 11 8 to 12 U25 FCCU SO2 6/20/24 200 50.4 40 to 60 U25 FCCU SO2 6/20/24 200 118 100 to 120 U4 FCCU CO 9/18/24 1000 249 200 to 300 U4 FCCU CO 9/18/24 1000 553.5 500 to 600 U4 FCCU CO2 9/18/24 20 6 5 to 8 U4 FCCU CO2 9/18/24 20 11.9 10 to 14 U4 FCCU NOx 9/18/24 200 50.9 40 to 60 U4 FCCU NOx 9/18/24 200 111.2 100 to 120 U4 FCCU O2 9/18/24 20 4.9 4 to 6 U4 FCCU O2 9/18/24 20 11.1 8 to 12 U4 FCCU SO2 9/18/24 200 50.4 40 to 60 U4 FCCU SO2 9/18/24 200 110.3 100 to 120 High Span Audit Gas UsedPoint Source Channel Audit Date Low Span Audit Gas Used HF Sinclair Refinery EER 3Q2024 Monitoring Information TC 210, 230, & 240 Type Code 210 (Pollutant Concentration Exceeded Span of CEM) - 500 (All) * Sum of Hours Column Labels Row Labels (blank) Grand Total (blank)0 0 Grand Total 0 0 * Type Code 230 (Manual Sample - Alternate Sampling During Monitor Outage) - 500 (All) * Sum of Hours Column Labels Row Labels (blank) Grand Total (blank)0 0 Grand Total 0 0 * Type Code 240 (CEM Modifications) - 100 (All) * Count of Channel Column Labels Row Labels (blank) Grand Total (blank) (blank) Grand Total HF Sinclair Refinery EER 3Q2024 Type Code 220 (Monitor Outage During Point Source Operation) - 600 (All) * Sum of Hours Column Labels Row Labels 722 723 Grand Total U4 FCCU O2 Broken part on calibration gas system. part replaced 20.98 20.98 CO Broken part on calibration gas system. part replaced 20.98 20.98 CO2 Broken part on calibration gas system. part replaced 20.98 20.98 NOx Broken part on calibration gas system. part replaced 20.98 20.98 SO2 Broken part on calibration gas system. part replaced 20.98 20.98 Sulfur Recovery Unit O2 Broken part on calibration gas system. part replaced 20.98 20.98 SO2 Broken part on calibration gas system. part replaced 20.98 20.98 U25 FCCU O2 QA Calibrations performed 3.95 3.95 CO QA Calibrations performed 3.95 3.95 CO2 QA Calibrations performed 1.97 1.97 NOx QA Calibrations performed 3.95 3.95 SO2 QA Calibrations performed 3.95 3.95 North Flare H2S QA Calibrations performed 1.98 1.98 South Flare TRS Sample System Contaminated. System Cleaned Out 10.98 10.98 Grand Total 157.87 19.75 177.62 HF Sinclair Refinery EER 3Q2024 SO2 * SO2 Type Code 410 (SO2) - 6000 (All) SO2 * SO2 Count of Magnitude of Emissions Column Labels SO2 Row Labels (blank)Grand Total SO2 0SO2U4 FCCU 1 1 SO2 Sulfur Recovery Unit 1 1 SO2 U25 FCCU 1 1 SO2 Grand Total 3 3 NOx *NOx Type Code 420 (NOx) - 6000 (All) NOx *NOx Count of Magnitude of Emissions Column Labels NOx Row Labels (blank)Grand Total NOx U4 FCCU NOx 0 1 1 NOx U25 FCCU NOx 0 1 1 NOx Grand Total 2 2 H2S/TRS * H2S/TRS Type Code 430 (H2S) - 6000 (All) H2S/TRS *H2S/TRS Count of Magnitude of Emissions Column Labels H2S/TRS Row Labels (blank)701 702 703 704 Grand Total H2S/TRS Amine Plant H2S/TRS Unit 17 Thermal reactor shutdown, worked on bringing unit 17 back online 17 17 H2S/TRS North Flare H2S/TRS Start up/Shut down 3 3 H2S/TRS ARN issues led to flare seal drums liberating H2S 10 10 H2S/TRS Process control problems led to variations causing upset. Attempted to line out process variations 1 1 H2S/TRS Compressor overwhelmed causing unit upset 4 4 H2S/TRS Process Interlock of the FCCU, Attempted restart of unit 12 12 H2S/TRS External power outage.18 18 H2S/TRS Equipment taken offline for repairs, worked to bring back online 7 7 H2S/TRS South FlareH2S/TRS External power outage.1 1 H2S/TRS Grand Total 22 1 43 7 73 CO * CO Type Code 440 (CO) - 6000 (All) CO * CO Count of Magnitude of Emissions Column Labels CO Row Labels (blank)701 703 Grand Total CO U4 FCCU CO Process startup/shutdown in other units causing upset 2 2 CO Unit 17 Thermal reactor shutdown, worked on bringing unit 17 back online 1 1 CO Process Interlock of the FCCU, Attempted restart of unit 8 8 CO #N/A 1 1 CO External power outage.1 1 CO U25 FCCU CO Process Interlock of the FCCU, Attempted restart of unit 127 127 CO Grand Total 4 136 140 VOC/THC * VOC/THC Type Code 460 (VOC/THC) - 6000 (All) VOC/THC * VOC/THC Count of Magnitude of Emissions Column Labels VOC/THC Row Labels Grand Total VOC/THC Grand Total O2 * O2 Type Code 470 (TRS as O2) - 6000 (All) O2 * O2 Count of Magnitude of Emissions Column Labels O2 Row Labels (blank)Grand Total O2 Crude Unit O2 0 1 1 O2 Grand Total 1 1 P.M.* P.M.Type Code 490 Particulate (PM) - 6000 (All) P.M.* P.M.Count of Magnitude of Emissions Column Labels P.M.Row Labels 701 Grand Total P.M.External power outage.11 11 P.M.U4 FCCU 11 11 P.M.Grand Total 11 11 HF Sinclair Refinery EER 3Q2024 Type Code 500 Before February 28, 2005 (Boiler Operating Days w/o 18 Hours of Data) After February 28, 2005 (90% Operating Hours For each 30 BOD) - 500 (All) * Count of Channel Column Labels Row Labels Grand Total Grand Total * Type Code 510 (F-factor, Equations & Conversion Factors) - 500 (All) Count of F-factor Column Labels Row Labels Grand Total Grand Total * Type Code 520 (Minimum Data Not Obtained <22/30 BODs) - 500 (All) Count of Channel Column Labels Row Labels Grand Total Grand Total * Type Code 530 (Excess Emissions During Emergency Conditions) - 500 (All) Count of Date Column Labels Row Labels Grand Total Grand Total * Type Code 540 (Fuel Pre-treatment Credit SO2) - 500 (All) Count of Date Column Labels Row Labels Grand Total Grand Total * TypeCode 550 (Changes in Operation in Control Equipment When CEM Data Not Available) - 500 (All) Column Labels Row Labels Grand Total Grand Total