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HomeMy WebLinkAboutDAQ-2024-011520 1 DAQC-1108-24 Site ID 10119 (B5) MEMORANDUM TO: FILE – CHEVRON PRODUCTS COMPANY – Salt Lake Refinery THROUGH: Harold Burge, Major Source Compliance Section Manager FROM: Rob Leishman, Environmental Scientist DATE: October 30, 2024 SUBJECT: Chevron Products Company (Chevron), Major, NSPS, Title V, MACT, Davis County – FRS # UT00000049001100003 INSPECTION TYPE: State Electronic Data Report (SEDR) Review REVIEW DATE: October 30, 2024 SOURCE LOCATION: North Salt Lake/Davis County SOURCE CONTACT: Tony Pollock – 801-539-7162 APPLICABLE REGULATIONS: Approval Order (AO) dated August 24, 2022, DAQE-AN101190106-22 SOURCE REVIEW EVALUATION: With the exception of sources that only monitor for opacity, quarterly report memoranda will only address the findings of the quarterly report. Approval Order and Title V permit conditions addressing continuous emission monitoring requirements will be addressed in Chevron’s relative accuracy performance specification test review memorandum. SEDR REVIEW: Third Quarter 2024 % Monitor Availability (MA) Performance Test Dates (N/A to Opacity) Summary of Excess Emissions During Point Source Operation Point Source Op. hrs. Channel MA CGA Lin RATA Point Source Channel Hrs. Limitation Boiler #7 1695 NOx 98% 08/28/24 08/27/24 FCC Regenerator Vent Opacity 0.00 30 % - 6min Boiler #7 1695 O2 98% 08/28/24 08/27/24 FCC Regenerator Vent Opacity 0.00 20 % - 3hrRA 1 8 2 2 Third Quarter 2024 % Monitor Availability (MA) Performance Test Dates (N/A to Opacity) Summary of Excess Emissions During Point Source Operation Point Source Op. hrs. Channel MA CGA Lin RATA Point Source Channel Hrs. Limitation FCC Regenerator Vent 2208 Opacity 100% FCC Regenerator Vent SO2 0.00 50 ppm - 7dRA FCC Regenerator Vent 2208 CO 98% 08/08/24 08/26/24 FCC Regenerator Vent SO2 0.00 25 ppm - 365dRA FCC Regenerator Vent 2208 NOx 98% 08/08/24 08/26/24 FCC Regenerator Vent NOx 0.00 106 ppm - 7dRA FCC Regenerator Vent 2208 SO2 98% 08/08/24 08/26/24 FCC Regenerator Vent NOx 0.00 80 ppm - 7dRA FCC Regenerator Vent 2208 CO2 98% 08/08/24 08/26/24 FCC Regenerator Vent CO 0.00 500 ppm - hour FCC Regenerator Vent 2208 O2 98% 08/08/24 08/26/24 Flare #1 H2S 3.00 162 ppm - 3hrRA Flare #1 2208 H2S 97% 08/12/24 09/21/20 Flare #2 H2S 55.00 162 ppm - 3hrRA Flare #1 2208 TRS 100% 08/12/24 Flare #3 H2S 0.00 162 ppm - 3hrRA Flare #2 2208 H2S 97% 08/07/24 09/22/20 Fuel Gas Mix Point H2S 0.00 162 ppm - 3hrRA Flare #2 2208 TRS 98% 08/07/24 Fuel Gas Mix Point H2S 0.00 60 ppm - 365dRA Flare #3 2208 H2S 98% 08/13/24 08/20/24 SRU Tailgas Incinerator 1 SO2 10.00 250 ppm - 12hrRA Flare #3 2208 TRS 98% 08/13/24 SRU Tailgas Incinerator 2 SO2 0.00 250 ppm - 12hrRA Fuel Gas Mix Point 2208 H2S 95% 08/06/24 08/19/24 SRU Tailgas Incinerator 1 2208 SO2 100% 08/06/24 08/21/24 SRU Tailgas Incinerator 1 2208 O2 100% 08/08/24 08/21/24 SRU Tailgas Incinerator 2 2208 SO2 99% 08/07/24 08/22/24 SRU Tailgas Incinerator 2 2208 O2 99% 08/07/24 08/22/24 Excess Emission Report - Hourly Summary Point Source Channel Startup & Shutdown Control Equipment Problems Process Problems Other Known Causes Unknown Causes Emission Limit FCC Regenerator Vent Opacity 0 0 0 0 0 30 % - 6min FCC Regenerator Vent Opacity 0 0 0 0 0 20 % - 3hrRA FCC Regenerator Vent SO2 0 0 0 0 0 50 ppm - 7dRA 3 Excess Emission Report - Hourly Summary Point Source Channel Startup & Shutdown Control Equipment Problems Process Problems Other Known Causes Unknown Causes Emission Limit FCC Regenerator Vent SO2 0 0 0 0 0 25 ppm - 365dRA FCC Regenerator Vent NOx 0 0 0 0 0 106 ppm - 7dRA FCC Regenerator Vent NOx 0 0 0 0 0 80 ppm - 7dRA FCC Regenerator Vent CO 0 0 0 0 0 500 ppm - hour Flare #1 H2S 0 3 0 0 0 162 ppm - 3hrRA Flare #2 H2S 0 22 2 31 0 162 ppm - 3hrRA Flare #3 H2S 0 0 0 0 0 162 ppm - 3hrRA Fuel Gas Mix Point H2S 0 0 0 0 0 162 ppm - 3hrRA Fuel Gas Mix Point H2S 0 0 0 0 0 60 ppm - 365dRA SRU Tailgas Incinerator 1 SO2 0 10 0 0 0 250 ppm - 12hrRA SRU Tailgas Incinerator 2 SO2 0 0 0 0 0 250 ppm - 12hrRA CMS Performance Summary - Hourly Summary Point Source Channel Monitor Malfunction Non-monitor Malfunction QA Calibrations Other Known Causes Unknown Causes Boiler #7 NOx 34 0 1 1 0 Boiler #7 O2 34 0 1 1 0 FCC Regenerator Vent Opacity 0 0 0 2 0 FCC Regenerator Vent CO 1 0 47 5 0 FCC Regenerator Vent NOx 1 0 47 5 0 FCC Regenerator Vent SO2 1 0 47 5 0 FCC Regenerator Vent CO2 1 0 47 5 0 FCC Regenerator Vent O2 1 0 47 5 0 Flare #1 H2S 40 0 24 3 0 Flare #1 TRS 0 1 0 3 0 Flare #2 H2S 0 0 29 27 0 Flare #2 TRS 36 0 0 2 0 Flare #3 H2S 0 17 22 4 0 Flare #3 TRS 33 17 0 3 0 Fuel Gas Mix Point H2S 30 55 28 1 0 SRU Tailgas Incinerator 1 SO2 1 0 0 1 0 SRU Tailgas Incinerator 1 O2 1 0 0 1 0 SRU Tailgas Incinerator 2 SO2 26 0 0 1 0 SRU Tailgas Incinerator 2 O2 26 0 0 1 0 4 Type Code 280 (COMS Attenuator Filters) Procedure 3 Point Source & Location Attenuator I.D. Attenuator Certification Date Certified Attenuator Opacity OPLR, SECR, or PLCF Corrected Opacity Value Range Low, Mid, & High Certification 1-year or 5-year FCC Regenerator Vent Flue Gas Duct DHT200 /14108330 3/4/24 12.90 0.90 21.68 Low 1 Year FCC Regenerator Vent Flue Gas Duct DHT200 /14108330 3/4/24 24.60 0.90 39.4 Mid 1 Year FCC Regenerator Vent Flue Gas Duct DHT200 /14108330 3/4/24 36.80 0.90 55.33 High 1 Year Type Code 281 (Procedure 3 - COMS Filter Audit Calibration Error) Point Source Location Audit Date Opacity Monitor Response (Average of 5) Mean Difference Calibration Error (≤ 3%) Low Mid High FCC Regenerator Vent Flue Gas Duct 8/7/24 7 0.005 1.149 FCC Regenerator Vent Flue Gas Duct 8/7/24 7 0.002 0.750 FCC Regenerator Vent Flue Gas Duct 8/7/24 7 -0.009 1.761 Pollutant Concentration Exceeded Span of CEM Monitor Outage During Point Source Operation Alternate Sampling CEM Modifications 34 Hours 763 Hours 0 Hours 0 Events SOURCE INSPECTION SUMMARY EVALUATION: Chevron maintains its CEMS as required in R307-170 and 40 CFR 60.13. CURRENT RECOMMENDATIONS: All deviations appear to be a result of breakdown or process related problems that do not warrant issuing a violation. Chevron was in compliance during this reporting period. No further enforcement actions should be taken. Chevron’s NSPS monitoring system meets the performance standards of 40 CFR 60, Appendix B Performance Specifications. HIGH PRIORITY VIOLATOR (HPV): No RECOMMENDATION FOR NEXT INSPECTION: Check DAS for daily zero and span drift. Check the QC program to ensure that monitor drift is being tracked and that the source can identify excessive drift. ATTACHMENTS: Excel spreadsheet review Ms. Serena Yau Chevron Salt Lake Refinery 685 South Chevron Way North Salt Lake, Utah 84054 Dear Ms. Yau: I am writing in response to your letter to EPA Region 8, dated October 27, 2020, in which you seek an alternative test method for use on Flare1 and Flare 2 at Chevron’s Salt Lake Refinery (Salt Lake) located in Salt Lake City, Davis County, Utah. It is our understanding that this facility is subject to 40 CFR part 60, Subpart Ja, Standards of Performance for Petroleum Refineries for Which Construction, Reconstruction, or Modification Commenced After May 14, 2007 (Subpart Ja). The Office of Air Quality Planning and Standards (OAQPS), as the delegated authority, must make the determination on any major alternatives to test methods and procedures required under 40 CFR parts 59, 60, 61, 63 and 65. Your proposed test method alternatives and our approval decisions are discussed below. According to the information provided, Flare 1 and Flare 2 at Salt Lake are subject to section 60.107a(a)(2) of Subpart Ja, which requires that a hydrogen sulfide (H2S) continuous monitoring system (CEMS) be used to comply with the emission limits found in section 60.103a(h) of Subpart Ja. Section 60.107a(a)(2) of Subpart Ja also requires an H2S CEMS be installed, operated and maintained according to 40 CFR part 60, appendix B, Performance Specification 7 (PS-7), and the use of Method 11, 15, or 15A of Appendix A-5 to 40 CFR part 60 or Method 16 of Appendix A-6 to 40 CFR part 60 for conducting the relative accuracy test. Following section 60.107a(a)(2), you are required to comply with the applicable quality assurance procedures in Appendix F to 40 CFR part 60, specifically Procedure 1 (40 CFR 60, Appendix F), which requires the annual relative accuracy test of each H2S CEMS. Based on the information you provided, Flare 1 and Flare 2 are both equipped with a flare vapor recovery (FVR) system. These FVR systems employ a water seal to prevent flaring, unless there is sufficient pressure on the seal for flare gas to break through. The vapors that do not break through the water seal are compressed and recovered. The FVR system prevents flaring the vast majority of the time. The H2S CEMS are located downstream of these water seals which means that when these water seals are intact, which is typical, there is no flare gas being sampled by the H2S CEMS. This intermittent flaring makes conducting a relative accuracy test on an H2S CEMS on Flare 1 and Flare 2 difficult. As a result of the difficulty associated with conducting a relative 1/12/2021 2 accuracy test on these H2S CEMSs, you seek to use the alternative relative accuracy procedure provided in section 16.2 of 40 CFR part 60, Appendix B, Performance Specification 2 (PS-2) and referenced as an alternative to the relative accuracy test in sections 60.107a(e)(1)(ii) and (2)(ii) of Subpart Ja. The alternative procedure requested allows for the completion of the alternative relative accuracy procedures found in section 16.0 of PS-2 in lieu of the relative accuracy test procedures for an H2S CEMS specified in PS-7. We have reviewed your request and the associated rule language and recognize that it can be difficult to perform relative accuracy tests of the H2S CEMSs installed on these units that do not consistently combust flare gas. Based on the information contained in your request on the intermittent flare gas flows, we approve the use of the alternative testing approach found in section 16.0 of PS-2, which allows cylinder gases to be used as an alternative to the relative accuracy test for H2S CEMSs, with the following caveats for each test: • This alternative test method is only approved for use on the two H2S CEMSs installed on Flare 1 and Flare 2 at Chevron’s Salt Lake Refinery. • The alternative relative accuracy procedures approved herein are an alternative to the relative accuracy test required by PS-7 and Procedure 1. • When conducting the alternative relative accuracy test, you must follow the procedures for performing the alternative relative accuracy test described in section 16.2 of PS-2 and meet the criteria specified in section 16.3 of PS-2. • The gas quality for the cylinder gases used to conduct the alternative relative accuracy tests must meet the Protocol Gas requirements defined in section 16.2.4 of PS-2, to an accuracy of at least 3 percent, or the cylinder gas material must be vendor certified as traceable to a NIST standard at 3 percent accuracy if Protocol Gases are not available at the concentration necessary for the alternative relative accuracy test. • The alternative relative accuracy procedures must be performed periodically as defined in section 60.107a(a)(1)(v) of Subpart Ja. • A copy of this approval letter must be included in the report detailing the results of the alternative relative accuracy procedures. If you have any questions regarding this determination, please contact Kim Garnett at 919-541- 1158 or garnett.kim@epa.gov. Sincerely, Steffan M. Johnson, Leader Measurement Technology Group STEFFAN JOHNSON Digitally signed by STEFFAN JOHNSON Date: 2021.01.12 08:43:07 -05'00' 3 cc: Rachel Agnew, Chevron (rachelagnew@chevron.com) Kim Garnett, EPA/OAQPS/AQAD (garnett.kim@epa.gov) Jeremy Marsigli, Utah DEQ (jmarsigli@utah.gov) Laurie Ostrand, EPA R8 (ostrand.laurie@epa.gov) Brenda Shine, EPA/OAQPS/SPPD (shine.brenda@epa.gov) Chevron Refinery EER 3Q2024 Point Source Information Late Expired Cal. Gas Valid Cal. Gas Days Yes No 1 Type Code 100(Company Information)Type Code Company Manager Company Name AIRS # Phone Number Environmental Contact 1 100 Troy Tortorich 01100003 (801) 539-7162 Tony Pollock 1 100 0 0 0 0 1 Type Code 110 (Point Source Identification)Type Code Point Source Quarter 1 - 4 Year Point Source Operating Hrs. in Quarter1 110 3 2024 1695 1 110 3 2024 2208 1 110 3 2024 2208 1 110 3 2024 2208 1 110 3 2024 2208 1 110 3 2024 2208 1 110 3 2024 2208 1 110 3 2024 2208 1 110 0 0 0 1 Type Code 200 (Monitor Identification)Type Code Point Source Channel Manufacturer Model No. Monitor SN Low Span High Span Installation Date Monitor Location 1 200 NOx Ametek Western Research9900 ZE-9900-10941-10 500 8/17/2018 F11007 1 200 O2 Ametek Western Research9900 ZE-9900-10941-10 21 8/17/2018 F11007 1 200 CO Siemens Ultramat 6 J6-783 0 1000 4/16/2020 K3223 1 200 CO2 Siemens Ultramat 6/Oxymat 6J7-447 0 25 4/16/2020 K3223 1 200 NOx Ametek Western Research9900 ZW-9900-S1334-10 200 4/16/2020 K3223 1 200 O2 Siemens Ultramat 6/Oxymat 6J7-447 0 10 4/16/2020 K3223 1 200 Opacity Sick/Maihak DHT200 0 100 10/5/2013 K3223 1 200 SO2 Siemens Ultramat 6E J6-783 0 200 4/16/2020 K3223 1 200 H2S Siemens Maxum Edition II #300194969000100 300 2/3/2010 V75220 1 200 TRS Atom FGA-100 140011 0 250000 11/5/2015 V75220 1 200 H2S Siemens Maxum Edition II #300194969000200 300 11/5/2010 V75120 1 200 TRS Atom FGA-100 140012 0 250000 11/4/2015 V75120 1 200 H2S Siemens Maxum Edition II #3001946900020 0 300 11/6/2019 D35014 1 200 TRS Atom FGA-100 18002 0 250000 11/6/2019 D35014 1 200 H2S Siemens Maxum Edition II #30019536380010ump 300 12/6/2009 V-113 1 200 O2 Ametek Ametek 9900 ZW-9900-S1332-10 21 9/1/2021 F-6550 1 200 SO2 Ametek Ametek 9900 ZW-9900-S1332-10 500 9/1/2021 F-6550 1 200 O2 Ametek Ametek 9000 AV9000WM-10235-1A0 21 12/16/2010 F-68250 1 200 SO2 Ametek Ametek 9000 AV9000WM-10235-1A0 500 12/16/2010 F-68250 1 200 0 0 0 0 0 0 1/0/1900 0 1 Type Code310 (Excess Emissions)SUMMARY REPORT Type Code Channel Total Hours of Excess Emissions Excess Emissions - % of Total Operating Hours RC 701 Hours - start up/Shutdown RC 702 Hours- Control Equipment Problems RC 703 Hours -Process Problems RC 704, 706, 707 Hours -Other Known Causes RC 705 Hours - Unknown Causes Emission Limitation Emission Limitation Units Emission Limitation Averaging Period1 TRUE 310 Opacity 0 0.00% 0 0 0 0 0 30 % 6min 1 TRUE 310 Opacity 0 0.00% 0 0 0 0 0 20 % 3hrRA 1 TRUE 310 SO2 0 0.00% 0 0 0 0 0 50 ppm 7dRA 1 TRUE 310 SO2 0 0.00% 0 0 0 0 0 25 ppm 365dRA 1 TRUE 310 NOx 0 0.00% 0 0 0 0 0 106 ppm 7dRA 1 TRUE 310 NOx 0 0.00% 0 0 0 0 0 80 ppm 7dRA 1 TRUE 310 CO 0 0.00% 0 0 0 0 0 500 ppm hour 1 TRUE 310 H2S 3 0.14% 0 3 0 0 0 162 ppm 3hrRA 1 TRUE 310 H2S 55 2.49% 0 22 2 31 0 162 ppm 3hrRA 1 TRUE 310 H2S 0 0.00% 0 0 0 0 0 162 ppm 3hrRA 1 TRUE 310 H2S 0 0.00% 0 0 0 0 0 162 ppm 3hrRA 1 TRUE 310 H2S 0 0.00% 0 0 0 0 0 60 ppm 365dRA 1 TRUE 310 SO2 10 0.45% 0 10 0 0 0 250 ppm 12hrRA 1 TRUE 310 SO2 0 0.00% 0 0 0 0 0 250 ppm 12hrRA 1 310 0 0 0 0 0 0 0 0 0 1 Type Code 300 (CMS Performance Summary) Type Code Channel Point Source Operating Hours Downtime - % of Total Operating Hours Total CMS Downtime RC 721 Hours - Monitor Malfunction RC 722 Hours - Non-monitor Malfunction RC 723 Hours - QA Calibrations RC 724 Hours - Other Known Causes RC 725 Hours - Unknown Causes 1 TRUE 300 NOx 1695 2.06% 35 33.5 0 0.5 1 0 1 TRUE 300 O2 1695 2.06% 35 33.5 0 0.5 1 0 1 TRUE 300 Opacity 2208 0.09% 1.9 0 0 0.3 1.6 0 1 TRUE 300 CO 2208 2.36% 52 0.75 0 46.5 4.75 0 1 TRUE 300 NOx 2208 2.36% 52 0.75 0 46.5 4.75 0 1 TRUE 300 SO2 2208 2.36% 52 0.75 0 46.5 4.75 0 1 TRUE 300 CO2 2208 2.36% 52 0.75 0 46.5 4.75 0 1 TRUE 300 O2 2208 2.36% 52 0.75 0 46.5 4.75 0 1 TRUE 300 H2S 2208 3.00% 66.25 39.75 0 24 2.5 0 1 TRUE 300 TRS 2208 0.16% 3.5 0 1 0 2.5 0 1 TRUE 300 H2S 2208 2.54% 56 0 0 29 27 0 1 TRUE 300 TRS 2208 1.71% 37.75 36.25 0 0 1.5 0 1 TRUE 300 H2S 2208 1.96% 43.25 0.25 17.25 22 3.75 0 1 TRUE 300 TRS 2208 2.41% 53.25 33 17.25 0 3 0 1 TRUE 300 H2S 2208 5.17% 114.25 30.25 55.25 27.75 1 0 1 TRUE 300 SO2 2208 0.09% 2 1 0 0 1 0 1 TRUE 300 O2 2208 0.07% 1.5 1 0 0 0.5 0 1 TRUE 300 SO2 2208 1.21% 26.75 25.75 0 0 1 0 1 TRUE 300 O2 2208 1.21% 26.75 25.75 0 0 1 0 1 300 0 0 0 0 0 0 Flare #3 Flare #1 Flare #1 Flare #2 Flare #2 Flare #3 Fuel Gas Mix Point SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 2 SRU Tailgas Incinerator 2 0 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 2 0 Chevron Products Co. 0 Boiler #7 Boiler #7 FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent Flare #1 Flare #1 Flare #2 FCC Regenerator Vent FCC Regenerator Vent Flare #1 Flare #2 Flare #3 FCC Regenerator Vent FCC Regenerator Vent Flare #2 Flare #3 Flare #3 Fuel Gas Mix Point SRU Tailgas Incinerator 1 FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent Fuel Gas Mix Point Fuel Gas Mix Point Boiler #7 Boiler #7 FCC Regenerator Vent SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 2 Boiler #7 FCC Regenerator Vent Flare #1 Flare #2 Flare #3 Fuel Gas Mix Point SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 2 0 SRU Tailgas Incinerator 2 0 Point Source Point Source Chevron Refinery EER 3Q2024 1 Type Code 250 (Performance SpecificationRATA Results)Type Code Channel Date of Most Current RATA Date of Preceding RATA Months Between RATA's Units of Measurement CEM Value Reference Method Value Relative accuracy Pass/ Fail 1 377 Days 250 NOx 08/27/24 08/16/23 12 ppm 0.081 0.072 0.01% P 1 377 Days 250 O2 08/27/24 08/16/23 12 0 3.8 3.8 1.80% P 1 378 Days 250 SO2 08/26/24 08/14/23 12 ppm 5.6 1.5 9.02% P 1 378 Days 250 NOx 08/26/24 08/14/23 12 ppm 9.6 1.5 1.24% P 1 378 Days 250 CO 08/26/24 08/14/23 12 ppm 95.4 93.5 0.62% P 1 378 Days 250 CO2 08/26/24 08/14/23 12 ppm 17.7 18 1.94% P 1 378 Days 250 O2 08/26/24 08/14/23 12 0 2 2 1.79% P 1 0 Days 250 H2S 09/21/20 09/21/20 12 ppm 8.9 5.81 3.30% P 1 0 Days 250 H2S 09/22/20 09/22/20 12 ppm 8.29 5.39 2.93% P 1 362 Days 250 H2S 08/20/24 08/24/23 12 ppm 0 0.07 0.10% P 1 360 Days 250 H2S 08/19/24 08/25/23 12 ppm 0.12 0.1 0.16% P 1 372 Days 250 SO2 08/21/24 08/15/23 12 ppm 65.1 74.1 13.66% P 1 372 Days 250 SO2 08/21/24 08/15/23 12 lb./hr. 1.5 1.7 15.74% P 1 372 Days 250 O2 08/21/24 08/15/23 12 0 3.7 3.8 1.33% P 1 367 Days 250 SO2 08/22/24 08/21/23 12 ppm 139.1 165.2 18.03% P 1 367 Days 250 SO2 08/22/24 08/21/23 12 lb./hr. 2.2 3.3 5.41% P 1 367 Days 250 O2 08/22/24 08/21/23 12 0 8.4 8.4 1.21% P 1 0 Days 250 0 01/00/00 01/00/00 0 0 0 0 0.00% 0 1 Type Code 260 (CGA Results)Type Code Channel Date Audit Point No. Cylinder ID Cylinder Expiration Date Type of Certification Units of Measurement CEM Value Cylinder Value Precision %Pass/ Fail Range - High or Low 1 Valid Cal. Gas 260 NOx 08/28/24 1 CC63048 06/02/31 EPA Traceability Protocol (Sept. 1997)ppm 136.1 135.4 52.00% P Low 1 Valid Cal. Gas 260 NOx 08/28/24 2 CC3688 06/02/31 EPA Traceability Protocol (Sept. 1997)ppm 280.2 276.1 148.00% P High 1 Valid Cal. Gas 260 O2 08/28/24 1 EB0027762 06/02/31 EPA Traceability Protocol (Sept. 1997)ppm 5 5 -79.00% P High 1 Valid Cal. Gas 260 O2 08/28/24 2 CC316355 05/01/26 EPA Traceability Protocol (Sept. 1997)ppm 8.1 8 112.00% P High 1 Valid Cal. Gas 260 CO 08/08/24 1 CC96320 06/02/31 EPA Traceability Protocol (Sept. 1997)ppm 237.1 249.9 -513.00% P Low 1 Valid Cal. Gas 260 CO 08/08/24 2 EB0157339 08/02/31 EPA Traceability Protocol (Sept. 1997)ppm 522.4 552.2 -540.00% P High 1 Valid Cal. Gas 260 CO2 08/08/24 1 CC200802 03/20/31 EPA Traceability Protocol (Sept. 1997)ppm 6.5 6.5 -107.00% P Low 1 Valid Cal. Gas 260 CO2 08/08/24 2 CC487479 03/02/31 EPA Traceability Protocol (Sept. 1997)ppm 14 14 14.00% P High 1 Valid Cal. Gas 260 NOx 08/08/24 1 CC320573 01/03/31 EPA Traceability Protocol (Sept. 1997)ppm 56.7 55.5 218.00% P Low 1 Valid Cal. Gas 260 NOx 08/08/24 2 CC262317 05/23/30 EPA Traceability Protocol (Sept. 1997)ppm 111.3 111.1 21.00% P High 1 Valid Cal. Gas 260 O2 08/08/24 1 EB0123082 05/31/31 EPA Traceability Protocol (Sept. 1997)% 5.1 5 220.00% P Low 1 Valid Cal. Gas 260 O2 08/08/24 2 EB0141908 05/31/31 EPA Traceability Protocol (Sept. 1997)% 8.2 8.1 149.00% P High 1 Valid Cal. Gas 260 SO2 08/08/24 1 CC733445 08/22/30 EPA Traceability Protocol (Sept. 1997)ppm 54.3 55.08 -143.00% P Low 1 Valid Cal. Gas 260 SO2 08/08/24 2 SG912106BAL 08/29/30 EPA Traceability Protocol (Sept. 1997)ppm 108.5 110.3 -163.00% P High 1 Valid Cal. Gas 260 H2S 08/12/24 1 CC160176 04/04/27 EPA PROTOCOL II GASppm 79.4 71.44 1114.00% P Low 1 Valid Cal. Gas 260 H2S 8/12/24 2 CC18776 10/19/26 EPA PROTOCOL II GASppm 166 159 4 P High 1 Valid Cal. Gas 260 TRS 8/12/24 1 CC97784 12/16/24 EPA PROTOCOL II GASppm 12,147 12,526 -3 P Low 1 Valid Cal. Gas 260 TRS 8/12/24 2 EB0140133 9/21/25 EPA PROTOCOL II GASppm 25,951 27,571 -6 P High 1 Valid Cal. Gas 260 H2S 8/7/24 1 ALM040013 6/30/26 EPA PROTOCOL II GASppm 75 70 7 P Low 1 Valid Cal. Gas 260 H2S 8/7/24 2 CC906612 6/9/26 EPA PROTOCOL II GASppm 167 159 5 P High 1 Valid Cal. Gas 260 TRS 8/7/24 1 CC341983 12/4/26 EPA PROTOCOL II GASppm 12,610 12,657 0 P Low 1 Valid Cal. Gas 260 TRS 8/7/24 2 EB0155296 4/13/26 EPA PROTOCOL II GASppm 27,212 27,525 -1 P High 1 Valid Cal. Gas 260 H2S 8/13/24 1 CC148981 5/28/26 EPA PROTOCOL II GASppm 69 70 -2 P Low 1 Valid Cal. Gas 260 H2S 8/13/24 2 CC475553 4/8/27 EPA PROTOCOL II GASppm 152 163 -7 P High 1 Valid Cal. Gas 260 TRS 8/13/24 1 CC231302 4/26/25 EPA PROTOCOL II GASppm 2,394 2,491 -4 P Low 1 Valid Cal. Gas 260 TRS 8/13/24 2 CC260070 4/12/25 EPA PROTOCOL II GASppm 5,244 5,553 -6 P High 1 Valid Cal. Gas 260 H2S 8/6/24 1 ALM044045 3/8/27 EPA Traceability Protocol (Sept. 1997)ppm 71 71 0 P Low 1 Valid Cal. Gas 260 H2S 8/6/24 2 CC429272 4/5/27 EPA Traceability Protocol (Sept. 1997)ppm 168 162 4 P High 1 Valid Cal. Gas 260 O2 8/8/24 1 ALM054666 4/26/27 EPA Traceability Protocol (Sept. 1997)ppm 5 5 -5 P Low 1 Valid Cal. Gas 260 O2 8/8/24 2 ALM020453 12/12/30 EPA Traceability Protocol (Sept. 1997)ppm 8 8 -3 P High 1 Valid Cal. Gas 260 SO2 8/6/24 1 CC107467 8/29/30 EPA Traceability Protocol (Sept. 1997)ppm 126 126 0 P Low 1 Valid Cal. Gas 260 SO2 8/6/24 2 EB0134129 11/22/29 EPA Traceability Protocol (Sept. 1997)ppm 252 252 0 P High 1 Valid Cal. Gas 260 O2 8/7/24 1 EB0105270 5/31/30 EPA Traceability Protocol (Sept. 1997)ppm 5 5 0 P Low 1 Valid Cal. Gas 260 O2 8/7/24 2 CC741651 8/23/29 EPA Traceability Protocol (Sept. 1997)ppm 8 8 0 P High 1 Valid Cal. Gas 260 SO2 8/7/24 1 CC356043 11/1/30 EPA Traceability Protocol (Sept. 1997)ppm 121 123 -2 P Low 1 Valid Cal. Gas 260 SO2 8/7/24 2 ALM047181 2/1/27 EPA Traceability Protocol (Sept. 1997)ppm 241 250 -4 P High 1 260 0 1/0/00 0 0 1/0/00 0 0 0 0 0 0 0 1 Type Code 270(Linearity Test Results)Type Code Channel Date Audit Point No. Cylinder ID Cylinder Expiration Date Type of Certification Units ofMeasurement CEM Value Cylinder Value Precision%Pass/ Fail Range - High or Low 1 270 0 01/00/00 0 0 01/00/00 0 0 0 0 0.00% 0 00 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 2 SRU Tailgas Incinerator 2 SRU Tailgas Incinerator 2 SRU Tailgas Incinerator 2 0 Flare #3 Flare #3 Fuel Gas Mix Point Fuel Gas Mix Point SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 Boiler #7 Boiler #7 Flare #3 Flare #3 FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent Flare #2 Flare #2 Flare #2 Flare #1 Boiler #7 FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent Boiler #7 0 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 2 SRU Tailgas Incinerator 2 FCC Regenerator Vent Flare #1 Flare #2 Flare #3 Fuel Gas Mix Point Boiler #7 Boiler #7 SRU Tailgas Incinerator 2 Point Source Point Source Point Source FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent FCC Regenerator Vent Flare #1 Flare #1 Flare #1 Flare #2 Chevron Refinery EER 3Q2024 1 Type Code 210 (Pollutant ConcentrationExceeded Span of CEM)Type Code Channel Start Date Start Time End Date End Time Hours 1 34 210 H2S 7/3/24 10:12 7/3/24 10:16 0.07 1 34 210 H2S 7/3/24 10:20 7/3/24 10:24 0.07 1 69 210 H2S 7/3/24 10:37 7/3/24 10:46 0.15 1 TRUE 210 H2S 8/8/24 14:38 8/8/24 14:41 0.05 1 210 H2S 8/12/24 10:54 8/12/24 11:03 0.15 1 210 H2S 8/18/24 19:46 8/18/24 19:51 0.08 1 210 H2S 9/17/24 11:17 9/17/24 11:38 0.35 1 210 H2S 9/17/24 11:42 9/17/24 11:51 0.15 1 210 H2S 9/17/24 11:59 9/17/24 12:03 0.07 1 210 H2S 9/17/24 12:12 9/17/24 12:30 0.30 1 210 H2S 9/17/24 12:33 9/17/24 12:47 0.23 1 210 H2S 9/17/24 13:18 9/17/24 13:22 0.07 1 210 H2S 9/17/24 13:26 9/17/24 13:39 0.22 1 210 H2S 9/17/24 13:47 9/17/24 13:56 0.15 1 210 H2S 9/17/24 14:05 9/17/24 14:22 0.28 1 210 H2S 7/3/24 9:58 7/3/24 10:02 0.07 1 210 H2S 7/3/24 10:24 7/3/24 10:32 0.13 1 210 H2S 7/3/24 10:43 7/3/24 10:46 0.05 1 210 H2S 7/16/24 19:09 7/16/24 19:12 0.05 1 210 H2S 7/16/24 19:16 7/16/24 19:35 0.32 1 210 H2S 7/16/24 19:46 7/16/24 20:20 0.57 1 210 H2S 7/16/24 20:23 7/16/24 20:27 0.07 1 210 H2S 7/26/24 20:52 7/26/24 20:56 0.07 1 210 H2S 7/26/24 20:58 7/26/24 21:03 0.08 1 210 H2S 7/26/24 21:07 7/26/24 21:18 0.18 1 210 H2S 7/26/24 21:21 7/26/24 21:25 0.07 1 210 H2S 7/26/24 21:32 7/26/24 21:52 0.33 1 210 H2S 8/18/24 19:39 8/18/24 19:47 0.13 1 210 H2S 8/18/24 19:50 8/18/24 19:53 0.05 1 210 H2S 8/18/24 19:58 8/18/24 20:09 0.18 1 210 H2S 8/18/24 20:20 8/18/24 20:47 0.45 1 210 H2S 8/18/24 20:50 8/18/24 21:38 0.80 1 210 H2S 8/18/24 21:57 8/18/24 22:02 0.08 1 210 H2S 8/18/24 22:21 8/18/24 22:24 0.05 1 210 H2S 8/18/24 22:27 8/18/24 22:54 0.45 1 210 H2S 8/18/24 22:58 8/18/24 23:24 0.43 1 210 H2S 8/19/24 3:24 8/19/24 3:35 0.18 1 210 H2S 8/19/24 3:50 8/19/24 4:02 0.20 1 210 H2S 8/19/24 4:40 8/19/24 4:47 0.12 1 210 H2S 9/8/24 23:41 9/8/24 23:44 0.05 1 210 H2S 9/8/24 23:52 9/8/24 23:59 0.12 1 210 H2S 9/9/24 0:03 9/9/24 0:11 0.13 1 210 H2S 9/9/24 0:18 9/9/24 1:04 0.77 1 210 H2S 9/9/24 7:21 9/9/24 9:14 1.88 1 210 H2S 9/17/24 11:29 9/17/24 11:37 0.13 1 210 H2S 9/17/24 11:44 9/17/24 11:48 0.07 1 210 H2S 9/17/24 12:03 9/17/24 12:15 0.20 1 210 H2S 9/17/24 12:21 9/17/24 12:37 0.27 1 210 H2S 9/17/24 12:41 9/17/24 13:15 0.57 1 210 H2S 9/17/24 13:18 9/17/24 13:22 0.07 1 210 H2S 9/17/24 13:26 9/17/24 13:30 0.07 1 210 H2S 9/17/24 13:37 9/17/24 13:45 0.13 1 210 H2S 9/17/24 13:48 9/17/24 13:52 0.07 1 210 H2S 9/17/24 13:56 9/17/24 14:04 0.13 1 210 H2S 9/17/24 14:07 9/17/24 14:34 0.45 1 210 H2S 9/17/24 14:52 9/17/24 15:29 0.62 1 210 H2S 9/17/24 16:11 9/17/24 16:41 0.50 1 210 H2S 9/17/24 17:30 9/17/24 17:34 0.07 1 210 H2S 9/17/24 17:45 9/17/24 19:11 1.43 1 210 H2S 9/17/24 19:22 9/17/24 19:30 0.13 1 210 H2S 9/17/24 19:37 9/17/24 20:56 1.32 1 210 H2S 9/17/24 21:11 9/17/24 21:19 0.13 1 210 H2S 9/17/24 21:25 9/17/24 21:41 0.27 1 210 H2S 9/19/24 9:34 9/19/24 9:49 0.25 1 210 H2S 9/19/24 9:56 9/19/24 10:01 0.08 1 210 H2S 9/19/24 10:08 9/19/24 10:34 0.43 1 210 H2S 9/19/24 12:56 9/19/24 13:01 0.08 1 210 H2S 9/19/24 13:12 9/19/24 13:15 0.05 1 210 H2S 9/19/24 13:19 9/19/24 13:38 0.32 1 210 H2S 9/19/24 13:41 9/19/24 14:49 1.13 1 210 H2S 9/19/24 15:08 9/19/24 17:53 2.75 1 210 H2S 9/23/24 7:47 9/23/24 7:54 0.12 1 210 H2S 9/23/24 7:59 9/23/24 8:10 0.18 1 210 H2S 9/23/24 8:12 9/23/24 8:20 0.13 1 210 H2S 9/23/24 8:24 9/23/24 8:32 0.13 1 210 H2S 9/23/24 8:47 9/23/24 8:50 0.05 1 210 H2S 9/23/24 9:01 9/23/24 9:13 0.20 1 210 H2S 9/23/24 9:16 9/23/24 9:21 0.08 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #1 Flare #1 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #1 Flare #1 Flare #1 Flare #1 Flare #1 Flare #1 Flare #1 Flare #1 Flare #1 Flare #1 Flare #1 Flare #1 Flare #1 Point Source Chevron Refinery EER 3Q2024 1 210 H2S 9/23/24 9:31 9/23/24 9:43 0.20 1 210 H2S 9/23/24 9:47 9/23/24 9:50 0.05 1 210 H2S 9/23/24 9:54 9/23/24 10:01 0.12 1 210 H2S 9/23/24 10:05 9/23/24 10:09 0.07 1 210 H2S 9/23/24 10:12 9/23/24 10:21 0.15 1 210 H2S 9/23/24 10:28 9/23/24 10:36 0.13 1 210 H2S 9/23/24 10:47 9/23/24 10:54 0.12 1 210 H2S 9/23/24 11:05 9/23/24 11:12 0.12 1 210 H2S 9/23/24 11:25 9/23/24 11:31 0.10 1 210 H2S 9/23/24 11:36 9/23/24 11:47 0.18 1 210 H2S 9/23/24 11:50 9/23/24 11:54 0.07 1 210 H2S 9/23/24 12:05 9/23/24 12:12 0.12 1 210 H2S 9/23/24 12:20 9/23/24 12:31 0.18 1 210 H2S 9/23/24 12:47 9/23/24 13:21 0.57 1 210 H2S 9/23/24 14:05 9/23/24 15:21 1.27 1 210 H2S 9/23/24 15:28 9/23/24 15:36 0.13 1 210 H2S 9/23/24 15:39 9/23/24 15:47 0.13 1 210 H2S 9/23/24 20:28 9/23/24 20:47 0.32 1 210 H2S 9/23/24 22:05 9/23/24 22:32 0.45 1 210 H2S 9/24/24 4:31 9/24/24 5:17 0.77 1 210 H2S 7/23/24 11:18 7/23/24 11:23 0.08 1 210 H2S 7/23/24 11:27 7/23/24 11:40 0.22 1 210 H2S 7/23/24 13:11 7/23/24 13:19 0.13 1 210 H2S 7/23/24 13:32 7/23/24 13:36 0.07 1 210 H2S 7/23/24 14:58 7/23/24 15:03 0.08 1 210 H2S 7/23/24 15:20 7/23/24 15:29 0.15 1 210 H2S 7/23/24 19:34 7/23/24 19:43 0.15 1 210 SO2 7/24/24 11:03 7/24/24 11:51 0.80 1 210 SO2 7/24/24 11:53 7/24/24 11:58 0.08 1 210 SO2 9/24/24 14:53 9/24/24 14:59 0.10 1 210 SO2 9/24/24 15:02 9/24/24 15:07 0.08 1 210 SO2 9/24/24 15:44 9/24/24 15:59 0.25 1 210 SO2 9/24/24 16:01 9/24/24 19:41 3.67 1 210 SO2 9/26/24 12:39 9/26/24 12:46 0.12 1 210 SO2 9/27/24 7:31 9/27/24 7:35 0.07 1 210 0 1/0/00 0:00 1/0/00 0:00 1 1 Yes 1 34.48 TC 220 Hours 763.15 TC 220 Hours 0.00 TC 230 Hours 0.00 Events 0.00 Hours 0.00 Events 0.00 0.00 1 763.15 TC 300 Hours 0.00 TRUE SRU Tailgas Incinerator 2 0 Flare #3 Flare #3 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 1 SRU Tailgas Incinerator 2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #3 Flare #3 Flare #3 Flare #3 Flare #3 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Flare #2 Type Code 210 (Pollutant Concentration Exceeded Span of CEM) Type Code 220 (Monitor Outage During Point Source Operation) Type Code 230 (Manual Sample - AlternateSampling During Monitor Outage) Type Code 240(CEM Modifications) Type Code 530 (Excess Emissions During Emergency Conditions) Type Code 450(Data Excluded) Type Code 550 (Changes in Operation in Control Equipment When CEM Data Not Available) Type Code 500 (Boiler Operating Days w/o 18 Hours of Data) Yes None Reported None Reported None Reported None Reported None Reported None Reported Chevron Refinery EER 3Q2024 Relative Accuracy Overview Point Source Channel Date of Most Current RATA Date of Preceding RATA Months Between RATA's Units Measured CEM Value Reference Method Value Relative Accuracy Pass/ Fail 2024 Boiler #7 NOx 08/27/24 08/16/23 12 ppm 0.081 0.07 0.01% P Boiler #7 O2 08/27/24 08/16/23 12 3.8 3.80 1.80% P FCC Regenerator Vent SO2 08/26/24 08/14/23 12 ppm 5.6 1.50 9.02% P FCC Regenerator Vent NOx 08/26/24 08/14/23 12 ppm 9.6 1.50 1.24% P FCC Regenerator Vent CO 08/26/24 08/14/23 12 ppm 95.4 93.50 0.62% P FCC Regenerator Vent CO2 08/26/24 08/14/23 12 ppm 17.7 18.00 1.94% P FCC Regenerator Vent O2 08/26/24 08/14/23 12 2 2.00 1.79% P Flare #1 H2S 09/21/20 09/21/20 12 ppm 8.9 5.81 3.30% P Flare #2 H2S 09/22/20 09/22/20 12 ppm 8.29 5.39 2.93% P Flare #3 H2S 08/20/24 08/24/23 12 ppm 0 0.07 0.10% P Fuel Gas Mix Point H2S 08/19/24 08/25/23 12 ppm 0.12 0.10 0.16% P SRU Tailgas Incinerator 1 SO2 08/21/24 08/15/23 12 ppm 65.1 74.10 13.66% P SRU Tailgas Incinerator 1 SO2 08/21/24 08/15/23 12 lb./hr. 1.5 1.70 15.74% P SRU Tailgas Incinerator 1 O2 08/21/24 08/15/23 12 3.7 3.80 1.33% P SRU Tailgas Incinerator 2 SO2 08/22/24 08/21/23 12 ppm 139.1 165.20 18.03% P SRU Tailgas Incinerator 2 SO2 08/22/24 08/21/23 12 lb./hr. 2.2 3.30 5.41% P SRU Tailgas Incinerator 2 O2 08/22/24 08/21/23 12 8.4 8.40 1.21% P * NSPS CGA Third 2024 Audit Gas Ranges Audit Gas Ranges AP1 Low AP2 Low AP1 High AP2 High Boiler #7 NOx 8/28/24 500 135.4 100 to 150 Boiler #7 NOx 8/28/24 500 276.1 250 to 300 Boiler #7 O2 8/28/24 21 5 4 to 6 Boiler #7 O2 8/28/24 21 8 8 to 12 FCC Regenerator Vent CO 8/8/24 1000 249.9 200 to 300 FCC Regenerator Vent CO 8/8/24 1000 552.2 500 to 600 FCC Regenerator Vent CO2 8/8/24 25 6.5 5 to 8 FCC Regenerator Vent CO2 8/8/24 25 14 10 to 14 FCC Regenerator Vent NOx 8/8/24 200 55.5 40 to 60 FCC Regenerator Vent NOx 8/8/24 200 111.1 100 to 120 FCC Regenerator Vent O2 8/8/24 10 5 4 to 6 FCC Regenerator Vent O2 8/8/24 10 8.1 8 to 12 FCC Regenerator Vent SO2 8/8/24 200 55.08 40 to 60 FCC Regenerator Vent SO2 8/8/24 200 110.3 100 to 120 Flare #1 H2S 8/12/24 300 71.44 60 to 90 Flare #1 H2S 8/12/24 300 159.3 150 to 180 Flare #1 TRS 8/12/24 250000 12526 50000 to 75000 Flare #1 TRS 8/12/24 250000 27571 125000 to 150000 Flare #2 H2S 8/7/24 300 69.7 60 to 90 Flare #2 H2S 8/7/24 300 158.8 150 to 180 Flare #2 TRS 8/7/24 250000 12657 50000 to 75000 Flare #2 TRS 8/7/24 250000 27525 125000 to 150000 Flare #3 H2S 8/13/24 300 70.46 60 to 90 Flare #3 H2S 8/13/24 300 163 150 to 180 Flare #3 TRS 8/13/24 250000 2491 50000 to 75000 Flare #3 TRS 8/13/24 250000 5553 125000 to 150000 Fuel Gas Mix Point H2S 8/6/24 300 70.76 60 to 90 Fuel Gas Mix Point H2S 8/6/24 300 161.6 150 to 180 SRU Tailgas Incinerator 1 O2 8/8/24 21 5.09 4 to 6 SRU Tailgas Incinerator 1 O2 8/8/24 21 8.04 8 to 12 SRU Tailgas Incinerator 1 SO2 8/6/24 500 125.7 100 to 150 SRU Tailgas Incinerator 1 SO2 8/6/24 500 251.6 250 to 300 SRU Tailgas Incinerator 2 O2 8/7/24 21 5.04 4 to 6 SRU Tailgas Incinerator 2 O2 8/7/24 21 7.97 8 to 12 SRU Tailgas Incinerator 2 SO2 8/7/24 500 123.2 100 to 150 SRU Tailgas Incinerator 2 SO2 8/7/24 500 249.5 250 to 300 * Type Code 280 (COMS Attenuator Filters) Procedure 3 Point Source Location Attenuator I.D. Attenuator Certification Date Certified Attenuator Opacity OPLR, SECR, or PLCF, Corrected Opacity Value Range Low, Mid, & High Certification 1-year or 5-year FCC Regenerator Vent Flue Gas Duct DHT200 /14108330 3/4/24 13 0.8996 21.68 Low 1 Year FCC Regenerator Vent Flue Gas Duct DHT200 /14108330 3/4/24 25 0.8996 39.4 Mid 1 Year FCC Regenerator Vent Flue Gas Duct DHT200 /14108330 3/4/24 37 0.8996 55.33 High 1 Year * Opacity Monitor Response (Average of 5) Low Range Mid Range High Range FCC Regenerator Vent Flue Gas Duct 8/7/24 7 0.005 0.005 0.007 1.149 FCC Regenerator Vent Flue Gas Duct 8/7/24 7 0.002 0.002 0.005 0.750 FCC Regenerator Vent Flue Gas Duct 8/7/24 7 -0.009 -0.009 0.008 1.761 Audit Gas Used High Span Audit Gas UsedPoint Source Channel Audit Date Low Span Point Source Location Audit Date Mean Difference Standard Deviation Confidence Coefficient Calibration Error (≤ 3%) Type Code 281 (Procedure 3 - COMS Filter Audit Calibration Error) Chevron Refinery EER 3Q2024 Monitoring Information TC 210, 230, & 240 Type Code 210 (Pollutant Concentration Exceeded Span of CEM) - 500 (All) * Sum of Hours Column Labels Row Labels (blank) H2S SO2 Grand Total (blank)0 0 Flare #1 2.52 2.52 Flare #2 25.92 25.92 Flare #3 0.88 0.88 SRU Tailgas Incinerator 1 4.98 4.98 SRU Tailgas Incinerator 2 0.18 0.18 Grand Total 0 29.32 5.17 34.48 * Type Code 230 (Manual Sample - Alternate Sampling During Monitor Outage) - 500 (All) * Sum of Hours Column Labels Row Labels (blank) Grand Total (blank)0 0 Grand Total 0 0 * Type Code 240 (CEM Modifications) - 100 (All) * Count of Channel Column Labels Row Labels (blank) Grand Total (blank) (blank) Grand Total Chevron Refinery EER 3Q2024 Type Code 220 (Monitor Outage During Point Source Operation) - 600 (All) * Sum of Hours Column Labels Row Labels 723 724 721 722 Grand Total FCC Regenerator Vent Opacity Performed mechanical centering on Opacity. 0.3 0.3 Performed quarterly audit.1.6 1.6 CO Performed quarterly audit.3.75 3.75 Daily Validations 46.5 46.5 Misc. calibration drift. Recalibrated and revalidated. 0.75 0.75 Replaced ammonia scrubber media and rebuilt sample pump, Cleaned Probe. 1 1 CO2 Performed quarterly audit.3.75 3.75 Daily Validations 46.5 46.5 Misc. calibration drift. Recalibrated and revalidated. 0.75 0.75 Replaced ammonia scrubber media and rebuilt sample pump, Cleaned Probe. 1 1 NOx Performed quarterly audit.3.75 3.75 Daily Validations 46.5 46.5 Misc. calibration drift. Recalibrated and revalidated. 0.75 0.75 Replaced ammonia scrubber media and rebuilt sample pump, Cleaned Probe. 1 1 SO2 Performed quarterly audit.3.75 3.75 Daily Validations 46.5 46.5 Misc. calibration drift. Recalibrated and revalidated. 0.75 0.75 Replaced ammonia scrubber media and rebuilt sample pump, Cleaned Probe. 1 1 O2 Performed quarterly audit.3.75 3.75 Daily Validations 46.5 46.5 Misc. calibration drift. Recalibrated and revalidated. 0.75 0.75 Replaced ammonia scrubber media and rebuilt sample pump, Cleaned Probe. 1 1 Flare #1 H2S Performed quarterly audit.2.5 2.5 Daily Validations 24.00 24 Misc. calibration drift. Recalibrated and revalidated. 0.5 0.5 Performed complete sample system PM. Changed filters, replaced nafion drier, rebuilt vacuum pump and replaced output presure transmitter on 8/8, next day the system failed validation. Recalibrated and revalidated. System passed without further issue. 33.75 33.75 Calibration drift. Cal gas regulator not controlling. Replaced regulators that had been previously ordered. Calibrated and revalidated. 5.5 5.5 TRS Performed quarterly audit.2.5 2.5 Technician replaced calibration gas bottle, and attempted a calibration and validation. The wrong calibration gas value was entered which caused a calibration drift as the technician was checking. The technician then entered the correct cal gas value recalibrated and revalidated the system. 1 1 Flare #2 H2S Performed quarterly audit.1.5 1.5 Daily Validations 23.00 23 Performed PM. Nafion Drier was not heating up properly, and found a leak in it as well. Replaced the Nafion Drier, it's thermocouple and replaced all sample system filters. 6 6 Analyzer technicians inadvertantly left validation bottle closed after performing CGA previous day. Technicians opened valve and revalidated CEMS. 25.5 25.5 TRS Performed quarterly audit.1.5 1.5 Analyzer team were notified of a failed validation. The team responded and replaced the thermostat, and analyzer furnace. Then the team calibrated and revalidated the analyzer. No further issues. 36.25 36.25 Chevron Refinery EER 3Q2024 Sum of Hours Column Labels Row Labels 723 724 721 722 Grand Total Flare #3 H2S Performed quarterly audit.3.5 3.5 Daily Validations 22.00 22 Technicians opened the GC doors during checks, which dropped the GC temperature slightly. This enabled the warning bit, but analyzer was still sampling. No down time. 0.25 0.25 #N/A 0.25 0.25 At 3:00PM on 9/18 the CEMS went into fault status on low valve air. Technicians caught the status failure during next morning validation checks. Replaced the low zero grade air bottles, recalibrated and revalidated. 17.25 17.25 TRS Performed quarterly audit.3 3 At 3:00PM on 9/18 the CEMS went into fault status on low valve air. Technicians caught the status failure during next morning validation checks. Replaced the low zero grade air bottles, recalibrated and revalidated. 17.25 17.25 During routine PM the zero calibration would not stabilize. Upon investigation the technician found a pitted valve body which was allowing span calibration gas to contaminate the zero gas. Through the course of time the technician replaced the excimer, detector and valve body. We have not had any issues since. 33 33 Fuel Gas Mix Point H2S Performed quarterly audit.0.5 0.5 Daily Validations 27.75 27.75 Calibration drift. Technicians searched for leaks and found a leaking sample filter. Tightened filter. Recalibrated and revalidated. 30.25 30.25 Technicians had to change the cal gas value in the software. Then they reran the validation. 0.5 0.5 H2 bottle developed a leak and caused a cal drift. Technicians replaced the bottle and reran the daily validation. 29 29 Valve gas bottle developed a leak and caused a cal drift. Technicians replaced the bottle and reran the daily validation. 26.25 26.25 SRU Tailgas Incinerator 1 SO2 Performed quarterly audit.1 1 Misc. calibration drift. Recalibrated and revalidated. 1 1 O2 Performed quarterly audit.0.5 0.5 Misc. calibration drift. Recalibrated and revalidated. 1 1 SRU Tailgas Incinerator 2 SO2 Performed quarterly audit.1 1 No validation occurred on on 9/19. On 9/20 technicians responded to a cal drift and found that the SO2 span gas regulator had been turned completely down.They increased the regulator for better flow and initiated the daily validation. No further issues. 25.75 25.75 O2 Performed quarterly audit.1 1 No validation occurred on on 9/19. On 9/20 technicians responded to a cal drift and found that the SO2 span gas regulator had been turned completely down.They increased the regulator for better flow and initiated the daily validation. No further issues. 25.75 25.75 Boiler #7 NOx Performed quarterly audit.2 2 Misc. calibration drift. Recalibrated and revalidated. 7.5 7.5 O2 not reading corrrectly, found broken calibration gas tube and repaired it. Calibrated and revalidated. 6.5 6.5 Technicians verified CEMS integrity for RATA. No issues were found. 1 1 Cal drift. Found low sample flow on analyzer. Replaced filter and performed calibration and revalidated. 53 53 Grand Total 336.55 72.1 263.75 90.75 763.15 Chevron Refinery EER 3Q2024 Opy *Opy Count of Magnitude of Emissions Column Labels Opy Row Labels Grand Total Opy Grand Total SO2 * SO2 Type Code 410 (SO2) - 6000 (All) SO2 *SO2 Count of Magnitude of Emissions Column LabelsSO2Row Labels 702 Grand Total SO2 The SRU1 unit shut down on low combustion air. This was due to the combustion air valve closing inadvertently while preparing for maintenance. Operations team safely reopened the valve, followed written procedures and started the plant back up. The refinery does not have a history of emissions associated with this cause. SO2 SRU Tailgas Incinerator 1 10 10SO2Grand Total 10 10 NOx * NOx Type Code 420 (NOx) - 6000 (All) NOx *NOx Count of Magnitude of Emissions Column LabelsNOxRow Labels Grand Total NOx Grand Total H2S/TRS * H2S/TRS Type Code 430 (H2S) - 6000 (All) H2S/TRS *H2S/TRS Count of Magnitude of Emissions Column Labels H2S/TRS Row Labels 702 703 704 Grand Total H2S/TRS Flare #1 H2S/TRS During a rain storm a level instrument had a false high level indication. This caused 66LC304 to open which blew Hydrogen to V106. The sudden increase in pressure opened 66PC409C to flare #1 and flare #2. This overwhelmed the flare vapor recovery systems which breached through the water seal drum causing excess H2S over the 3 hour limit. Operations investigated the instrument and rammed the leads to clear the false high level reading. The H2S soon fell below exceedance levels. The refinery does not have a history of emissions associated with this cause. 3 3 H2S/TRS Flare #2 H2S/TRS During a rain storm a level instrument had a false high level indication. This caused 66LC304 to open which blew Hydrogen to V106. The sudden increase in pressure opened 66PC409C to flare #1 and flare #2. This overwhelmed the flare vapor recovery systems which breached through the water seal drum causing excess H2S over the 3 hour limit. Operations investigated the instrument and rammed the leads to clear the false high level reading. The H2S soon fell below exceedance levels. The refinery does not have a history of emissions associated with this cause. 10 10 H2S/TRS The Coker B valve opened to relief due to a missed permissive signal. Which put H2S in to the relief system. We had a new UO on the console that was not yet aware of the permissive that was needed to avoid this scenario. Chevron provided additional coaching and training to the new unit operator on how to avoid this scenario in the future. The refinery does not have a history of emissions associated with this cause. 3 3 H2S/TRS While unloading a railcar in LPG. The blend pump cavitated. During this cavitation, operations were also venting a blend pump. The combination of the blend pump and the cavitating railcar pump overwhelmed and briefly breached the seals at flare #2. This caused an H2S 3 hour limit exceedance. Operations reacted quickly to sweep the flare with sweet gas and eliminate the exceedance. The refinery does not have a history of exceedances associated with this cause. 2 2 H2S/TRS Heavy rain caused the instrumentation on the VGO compressor to read a false high signal. This false high caused the SIS systems to open a control valve causing excess H2S to vent to relief, breaching the seal. Once the UO noticed the false level, he switched to a redundant level for control. This switching to another instrument not effected by the rain allowed the control valve to operate as designed. This eliminated the excess H2S at flare #2. The refinery does not have a history of emissions associated with this cause. 9 9 H2S/TRS There was simultaneous work going on at the FCC and jet plant. The automatic dump valve at the FCC opened on V32107. Around the same time the clay treater at the jet plant was being steamed to relief. This caused excess light hydrocarbon to vaporize from the steam and flow to spike at the flare. During the increase in flow, the flare#2 water seal was breached resulting in an exceedance in H2S. Operations saw the alarm and safely used sweet gas to sweep the flare eliminating the exceedance. The refinery does not have a history of emissions associated with this cause. 8 8 H2S/TRS Maintenance was working on level instrumentation on V66104. SIS instruments were placed in bypass, but the controller was not placed in manual. When 66LI316 instruments saw a high level, the dump valve opened sending pressure to relief. During that time, we exceeded our 3 hour H2S limit. Once this was noted, operations worked to quickly and safely place 66LC316 in manual and then closed position. This eliminated excess H2S from breaching the water seal at flare#2. The refinery does not have a history of emissions associated with this cause. 9 9 H2S/TRS Electricity supply to the refinery was temporarily interrupted causing several unit shut downs and also resulted in the loss of third party H2 supply for an extended period of time. This resulted in a Flare #2 3-hour H2S limit exceedance. Refinery personnel followed procedures to begin starting equipment that had shut down from the loss of power. Units were brought to a safe position and feed introduced. The refinery does not have a history of emissions associated with this cause. 14 14 Chevron Refinery EER 3Q2024 H2S/TRS Grand Total 25 2 31 58 CO * CO Type Code 440(CO) - 6000 (All) CO * CO Count of Magnitude of Emissions Column Labels CO Row Labels Grand TotalCOGrand Total VOC/THC *VOC/THC Type Code 460 (VOC/THC) - 6000 (All)VOC/THC *VOC/THC Count of Magnitude of Emissions Column Labels VOC/THC Row Labels Grand Total VOC/THC Grand Total O2 * O2 Type Code 470(TRS as O2) - 6000 (All) O2 * O2 Count of Magnitude of Emissions Column Labels O2 Row Labels Grand Total O2 Grand Total Chevron Refinery EER 3Q2024 Type Code 500 Before February 28, 2005 (Boiler Operating Days w/o 18 Hours of Data) After February 28, 2005 (90% Operating Hours For each 30 BOD) - 500 (All) * Count of Channel Column Labels Row Labels Grand Total Grand Total * Type Code 510 (F-factor, Equations & Conversion Factors) - 500 (All) Count of F-factor Column Labels Row Labels Grand Total Grand Total * Type Code 520 (Minimum Data Not Obtained <22/30 BODs) - 500 (All) Count of Channel Column Labels Row Labels Grand Total Grand Total * Type Code 530 (Excess Emissions During Emergency Conditions) - 500 (All) Count of Date Column Labels Row Labels Grand Total Grand Total * Type Code 540 (Fuel Pre-treatment Credit SO2) - 500 (All) Count of Date Column Labels Row Labels Grand Total Grand Total * TypeCode 550 (Changes in Operation in Control Equipment When CEM Data Not Available) - 500 (All) Column Labels Row Labels Grand Total Grand Total