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HomeMy WebLinkAboutDAQ-2024-011476 1 DAQC-1112-24 Site ID 10346 (B5) MEMORANDUM TO: FILE – KENNECOTT UTAH COPPER CORPORATION THROUGH: Harold Burge, Major Source Compliance Section Manager FROM: Rob Leishman, Environmental Scientist DATE: November 1, 2024 SUBJECT: Kennecott Utah Copper Corporation (Kennecott), Major, SIP, Title V, Salt Lake County, FRS # UT00000049003500030 INSPECTION TYPE: State Electronic Data Report (SEDR) Review REVIEW DATE: November 1, 2024 SOURCE LOCATION: Magna, Salt Lake County SOURCE CONTACT: Austin Keough – 801-569-6331 APPLICABLE REGULATIONS: Title V Operating Permit Permit Number: 3500030004 Date of Permit: September 18, 2020 Date of Last Revision: September 27, 2022 SOURCE INSPECTION EVALUATION: With the exception of sources that only monitor for opacity, quarterly report memoranda will only address the findings of the quarterly report. Approval Order and Title V permit conditions addressing continuous emission monitoring requirements will be addressed in Kennecott’s relative accuracy performance specification test review memorandum. SOURCE REVIEW EVALUATION: Third Quarter 2024 % Monitor Availability (MA) Performance Test Dates (N/A to Opacity) Summary of Excess Emissions During Point Source Operation Point Source Op. hrs. Channel MA CGA Lin RATA Point Source Channel Hrs. Limitation Conc Dryer 1300 Opacity 99% Conc Dryer Opacity 16.80 15 % - 6 min avg Main Stack 2208 NOx 95% 08/28/24 05/29/24 Main Stack Opacity 19.80 20 % - 6 min avg Main Stack 2208 Opacity 100% Tail Gas Opacity 0.00 15 % - 6 min avg 1 8 2 2 Third Quarter 2024 % Monitor Availability (MA) Performance Test Dates (N/A to Opacity) Summary of Excess Emissions During Point Source Operation Point Source Op. hrs. Channel MA CGA Lin RATA Point Source Channel Hrs. Limitation Main Stack 2208 SO2 98% 08/28/24 05/29/24 Main Stack SO2 0.00 552 lb/hr - 3 HR RAvg Tail Gas 1710 Opacity 100% Main Stack SO2 0.00 422 lb/hr - 24 HR BAvg Tail Gas 1710 SO2 95% 08/28/24 06/18/24 Tail Gas SO2 0.00 250 ppm - 6 HR BAvg Tail Gas SO2 0.00 170 ppm - 24 HR BAvg Main Stack NOx 0.00 35 lb/hr - Ann Avg Main Stack NOx 0.00 154 lb/hr - 24HR BAvg Excess Emission Report - Hourly Summary Point Source Channel Startup & Shutdown Control Equipment Problems Process Problems Other Known Causes Unknown Causes Emission Limit Conc Dryer Opacity 0 16.8 0 0 0 15 % - 6 min avg Main Stack Opacity 1.4 18.6 1.1 0.1 0 20 % - 6 min avg Tail Gas Opacity 1.7 0 0 0 0 15 % - 6 min avg Main Stack SO2 6 0 0 0 0 552 lb/hr - 3 HR RAvg Main Stack SO2 0 0 0 0 0 422 lb/hr - 24 HR BAvg Tail Gas SO2 0 0 0 0 0 250 ppm - 6 HR BAvg Tail Gas SO2 0 0 0 0 0 170 ppm - 24 HR BAvg Main Stack NOx 0 0 0 0 0 35 lb/hr - Ann Avg Main Stack NOx 0 0 0 0 0 154 lb/hr - 24HR BAvg CMS Performance Summary - Hourly Summary Point Source Channel Monitor Malfunction Non-monitor Malfunction QA Calibrations Other Known Causes Unknown Causes Conc Dryer Opacity 0 0 15 0 0 Main Stack NOx 48 59 3 0 0 Main Stack Opacity 0 0 1 0 0 Main Stack SO2 0 32 15 3 0 Tail Gas Opacity 0 0 1 0 0 Tail Gas SO2 0 0 85 0 0 3 Type Code 280 (COMS Attenuator Filters) Procedure 3 Point Source & Location Attenuator I.D. Attenuator Certification Date Certified Attenuator Opacity OPLR, SECR, or PLCF, Corrected Opacity Value Range Low, Mid, & High Certification 1-year or 5- year Conc Dryer - Duct S11843 10/23/23 8.27 0.00 0 low 1 Conc Dryer - Duct S11834 10/23/23 16.43 0.00 0 mid 1 Conc Dryer - Duct S11812 10/23/23 25.20 0.00 0 high 1 Tail Gas - Duct S12476 10/23/23 8.38 0.00 0 low 1 Tail Gas - Duct S12485 10/23/23 16.91 0.00 0 mid 1 Tail Gas - Duct S12494 10/23/23 24.86 0.00 0 high 1 Type Code 281 (Procedure 3 - COMS Filter Audit Calibration Error) Point Source Location Audit Date Opacity Monitor Response (Average of 5) Mean Difference Calibration Error (≤ 3%) Low Mid High Conc Dryer Duct 8/29/24 10 1.260 1.410 Conc Dryer Duct 8/29/24 18 1.340 1.480 Conc Dryer Duct 8/29/24 27 1.930 2.080 Tail Gas Duct 8/29/24 9 0.130 0.150 Tail Gas Duct 8/29/24 17 0.350 0.540 Tail Gas Duct 8/29/24 26 1.070 1.100 Type Code 282 (Annual Zero Alignment Audit) Procedure 3 Point Source Location Audit Date Alternative Zero Alignment (Yes or No) COM Clear Condition Zero Response (CCZR) COM Simulated Zero Response (CSZR) Zero Alignment Error Difference (CCZR)- (CSZR) Adjustment to COM Simulated Zero Response (CSZR) (Yes or No) Conc Dryer Duct 8/29/23 Yes 0.00 0.21 0 No Tail Gas Duct 8/29/23 Yes 0.38 0.11 0 No Pollutant Concentration Exceeded Span of CEM Monitor Outage During Point Source Operation Alternate Sampling CEM Modifications 0 Hours 262 Hours 0 Hours 0 Events 4 SOURCE INSPECTION SUMMARY EVALUATION: Kennecott maintains its CEMS as required in R307-170 and 40 CFR 60.13 CURRENT RECOMMENDATIONS: All deviations appear to be a result of breakdown or process related problems that do not warrant issuing a violation. Periods of excess emissions that were recorded by the CMS in service on each point source during this reporting period are summarized in the SEDR and described in Pivot Table 400 “Excess Emissions Review.” Kennecott was in compliance during this reporting period. No further enforcement action is recommended. Kennecott’s NSPS monitoring system meets the performance standards of 40 CFR 60, Appendix B Performance Specifications. HIGH PRIORITY VIOLATOR (HPV): No. RECOMMENDATION FOR NEXT INSPECTION: Check DAS for daily zero and span drift. Check the QC program to ensure that monitor drift is being tracked and that the source can identify excessive drift. ATTACHMENTS: Excel spreadsheet review. Kennecott EER 3Q2024 Point Source Information Late Expired Cal. Gas Valid Cal. Gas Days Yes No 1 Type Code 100 (Company Information)Type Code Company Manager Company Name AIRS # Phone Number Environmental Contact1 100 Simon Mallard 03500030 801-569-6331 Cassady Kristensen 1 100 0 0 0 0 1 Type Code 110(Point Source Identification)Type Code Point Source Quarter1 - 4 Year Point Source Operating Hrs. in Quarter 1 110 3 2024 1300.7 1 110 3 2024 2208 1 110 3 2024 2208 1 110 3 2024 2208 1 110 3 2024 1710 1 110 3 2024 1710 1 110 3 2024 1710 1 110 0 0 0 1 Type Code 200 (Monitor Identification)Type Code Point Source Channel Manufacturer Model No. Monitor SN Low Span High Span Installation Date Monitor Location 1 200 Opacity Teledyne Monitor Labs IncLightHawk 560ES 5602949 0 100 5/18/2018 Duct 1 200 NOx Thermo 42iQ 12127413438 0 100 3/23/2022 Stack 1 200 Opacity Teledyne Monitor Labs Inc.LightHawk 560ES 5603123 0 100 7/11/2019 Stack 1 200 SO2 Thermo Scientific 43iQ 12127413439 0 100 3/23/2022 Stack 1 200 SO2 Thermo Scientific 43iQ 12127413439 0 10000 3/23/2022 Stack 1 200 Opacity Teledyne Monitor Labs IncLightHawk 560ES 5603122 0 100 7/17/2019 Duct 1 200 SO2 Unisearch DOAS AR2047 DAS22-001 0 150 8/3/2022 Duct 1 200 SO2 Unisearch DOAS AR2047 DAS22-001 0 1500 8/3/2022 Duct 1 200 0 0 0 0 0 0 1/0/1900 0 1 Type Code310 (Excess Emissions) SUMMARY REPORT Type Code Channel Total Hours of Excess Emissions Excess Emissions - % of Total Operating Hours RC 701 Hours - start up/Shutdown RC 702 Hours- Control Equipment Problems RC 703 Hours -Process Problems RC 704, 706, 707 Hours -Other Known Causes RC 705 Hours - Unknown Causes Emission Limitation Emission Limitation Units Emission Limitation Averaging Period1 TRUE 310 Opacity 16.8 1.29% 0 16.8 0 0 0 15 % 6 min avg 1 TRUE 310 Opacity 21.2 0.96% 1.4 18.6 1.1 0.1 0 20 % 6 min avg 1 TRUE 310 Opacity 1.7 0.10% 1.7 0 0 0 0 15 % 6 min avg 1 TRUE 310 SO2 6 0.27% 6 0 0 0 0 552 lb/hr 3 HR RAvg 1 TRUE 310 SO2 0 0.00% 0 0 0 0 0 422 lb/hr 24 HR BAvg 1 TRUE 310 SO2 0 0.00% 0 0 0 0 0 250 ppm 6 HR BAvg 1 TRUE 310 SO2 0 0.00% 0 0 0 0 0 170 ppm 24 HR BAvg 1 TRUE 310 NOx 0 0.00% 0 0 0 0 0 35 lb/hr Ann Avg 1 TRUE 310 NOx 0 0.00% 0 0 0 0 0 154 lb/hr 24HR BAvg 1 310 0 0 0 0 0 0 0 0 0 1 Type Code 300 (CMS Performance Summary) Type Code Channel Point Source Operating Hours Downtime - % of Total Operating Hours Total CMS Downtime RC 721 Hours - Monitor Malfunction RC 722 Hours - Non-monitor Malfunction RC 723 Hours - QA Calibrations RC 724 Hours - Other Known Causes RC 725 Hours - Unknown Causes1 TRUE 300 Opacity 1300.7 1.17% 15.2 0 0 15.2 0 0 1 TRUE 300 NOx 2208 4.98% 110 48 59 3 0 0 1 TRUE 300 Opacity 2208 0.05% 1 0 0 1 0 0 1 TRUE 300 SO2 2208 2.26% 50 0 32 15 3 0 1 TRUE 300 Opacity 1710 0.06% 1 0 0 1 0 0 1 TRUE 300 SO2 1710 4.97% 85 0 0 85 0 0 1 300 0 0 0 0 0 0 1 Type Code 250 (Performance Specification RATA Results) Type Code Channel Date of Most Current RATA Date of Preceding RATA Months Between RATA's Units of Measurement CEM Value Reference Method Value Relative accuracy Pass/ Fail 1 265 Days 250 SO2 06/18/24 09/27/23 9 ppmvd 55.11 38.22 708.00% Pass 1 244 Days 250 NOx 05/29/24 09/28/23 8 lb/hr 24.1 23.9 488.00% Pass 1 244 Days 250 SO2 05/29/24 09/28/23 8 lb/hr 186.6 173.5 1292.00% Pass 1 244 Days 250 SO2 05/29/24 09/28/23 8 lb/hr 186.6 173.5 1292.00% Pass 1 0 Days 250 0 01/00/00 01/00/00 0 0 0 0 0.00% 0 1 Type Code 260(CGA Results)Type Code Channel Date Audit Point No. Cylinder ID Cylinder Expiration Date Type of Certification Units ofMeasurement CEM Value Cylinder Value Precision%Pass/ Fail Range - High or Low1 Valid Cal. Gas 260 NOx 08/28/24 1 CC741696 06/13/25 P1 ppmv 24.9 26.1 -460.00% Pass Low 1 Valid Cal. Gas 260 NOx 08/28/24 2 EB0042599 06/13/30 P1 ppmv 53.94 56.06 -378.00% Pass Low 1 Valid Cal. Gas 260 SO2 08/28/24 1 CC741696 06/13/25 P1 ppmv 24.79 24.91 -48.00% Pass Low 1 Valid Cal. Gas 260 SO2 08/28/24 2 EB0042599 06/13/30 P1 ppmv 59.12 55.38 675.00% Pass Low 1 Valid Cal. Gas 260 SO2 08/28/24 1 EB0095882 01/03/30 P1 ppmv 2530.33 2504 105.00% Pass High 1 Valid Cal. Gas 260 SO2 08/28/24 2 ALM025983 01/24/30 P1 ppmv 5606.67 5499 196.00% Pass High 1 Valid Cal. Gas 260 SO2 08/28/24 1 CC284500 06/13/30 P1 ppmv 31.87 30.9 313.00% Pass Low 1 Valid Cal. Gas 260 SO2 08/28/24 2 SG9170530BAL 01/03/31 P1 ppmv 67.43 70.5 -435.00% Pass Low 1 Valid Cal. Gas 260 SO2 08/28/24 1 CC20272 06/13/30 P1 ppmv 280.67 313 -1033.00% Pass High 1 Valid Cal. Gas 260 SO2 08/28/24 2 ALM057503 01/05/31 P1 ppmv 619.33 681.3 -910.00% Pass High 1 260 0 01/00/00 0 0 01/00/00 0 0 0 0 0.00% 0 0 1 Type Code 270 (Linearity Test Results)Type Code Channel Date Audit Point No. Cylinder ID Cylinder Expiration Date Type of Certification Units ofMeasurement CEM Value Cylinder Value Precision%Pass/ Fail Range - High or Low1 270 0 01/00/00 0 0 01/00/00 0 0 0 0 0.00% 0 0 1 Type Code 210(Pollutant ConcentrationExceeded Span of CEM) Type Code Channel Start Date Start Time End Date End Time Hours 1 0 0 0 1/0/00 0:00 1/0/00 0:00 1 1 None Reported 1 0 TC 220 Hours 262.20 TC 220 Hours 0.00 TC 230 Hours 0.00 Events 0.00 Hours 0.00 Events 0.00 0.00 1 262.20 TC 300 Hours 0.00 TRUE None Reported None Reported None Reported None Reported None Reported None Reported Point Source Point Source Point Source Point Source Point Source Point Source Yes Tail Gas 0 Conc Dryer Main Stack Main Stack Main Stack Tail Gas Tail Gas Tail Gas 0 Main Stack Main Stack Tail Gas Main Stack Main Stack Main Stack Tail Gas Tail Gas 0 Conc Dryer Main Stack Main Stack Type Code 550(Changes in Operation in Control Equipment When CEM Data Not Available) Type Code 500 (Boiler Operating Days w/o 18 Hours of Data) Kennecott Copper 0 Type Code 450(Data Excluded) Conc Dryer Main Stack Main Stack Main Stack Main Stack Tail Gas Tail Gas Tail Gas 0 Tail Gas Tail Gas Main Stack Main Stack 0 Conc Dryer Main Stack Type Code 210 (Pollutant Concentration Exceeded Span of CEM) Type Code 220 (Monitor Outage During Point Source Operation) Type Code 230(Manual Sample - AlternateSampling During MonitorOutage) Type Code 240(CEM Modifications) Type Code 530 (Excess Emissions During Emergency Conditions) Main Stack Main Stack Main Stack 0 Tail Gas Main Stack Main Stack Main Stack Main Stack Tail Gas Tail Gas Tail Gas 0 0 Kennecott EER 3Q2024 Relative Accuracy Overview Point Source Channel Date of Most Current RATA Date of Preceding RATA Months Between RATA's Units Measured CEM Value Reference Method Value Relative Accuracy Pass/ Fail Tail Gas SO2 06/18/24 09/27/23 9 ppmvd 55.11 38.22 708.00% Pass Main Stack NOx 05/29/24 09/28/23 8 lb/hr 24.1 23.90 488.00% Pass Main Stack SO2 05/29/24 09/28/23 8 lb/hr 186.6 173.50 1292.00% Pass Main Stack SO2 05/29/24 09/28/23 8 lb/hr 186.6 173.50 1292.00% Pass * NSPS CGA Third 2024 Audit Gas Ranges Audit Gas Ranges AP1 Low AP2 Low AP1 High AP2 High Main Stack NOx 8/28/24 100 26.1 20 to 30 Main Stack NOx 8/28/24 100 56.06 50 to 60 Main Stack SO2 8/28/24 100 24.91 20 to 30 Main Stack SO2 8/28/24 100 55.38 50 to 60 Main Stack SO2 8/28/24 10000 2504 2000 to 3000 Main Stack SO2 8/28/24 10000 5499 5000 to 6000 Tail Gas SO2 8/28/24 150 30.9 30 to 45 Tail Gas SO2 8/28/24 150 70.5 75 to 90 Tail Gas SO2 8/28/24 1500 313 300 to 450 Tail Gas SO2 8/28/24 1500 681.3 750 to 900 * Type Code 280 (COMS Attenuator Filters) Procedure 3 Point Source Location Attenuator I.D. Attenuator Certification Date Certified Attenuator Opacity OPLR, SECR, or PLCF, Corrected Opacity Value Range Low, Mid, & High Certification 1-year or 5-year Conc Dryer Duct S11843 10/23/23 8 0 0 low 1 Conc Dryer Duct S11834 10/23/23 16 0 0 mid 1 Conc Dryer Duct S11812 10/23/23 25 0 0 high 1 Tail Gas Duct S12476 10/23/23 8.38 0 0 low 1 Tail Gas Duct S12485 10/23/23 16.91 0 0 mid 1 Tail Gas Duct S12494 10/23/23 24.86 0 0 high 1 * Opacity Monitor Response (Average of 5) Low Range Mid Range High Range Conc Dryer Duct 8/29/24 10 1.260 0.060 0.140 1.410 Conc Dryer Duct 8/29/24 18 1.340 0.060 0.140 1.480 Conc Dryer Duct 8/29/24 27 1.930 0.060 0.140 2.080 Tail Gas Duct 8/29/24 9 0.130 0.010 0.020 0.150 Tail Gas Duct 8/29/24 17 0.350 0.080 0.190 0.540 Tail Gas Duct 8/29/24 26 1.070 0.010 0.030 1.100 * Point Source Location Audit Date Alternitive Zero Alignment (Yes or No) COM Clear Condition Zero Response (CCZR) COM Simulated Zero Response (CSZR) Zero Alignment Error Difference (CCZR)-(CSZR) Adjustment to COM Simulated Zero Response (CSZR) (Yes or No) Conc Dryer Duct 8/29/23 Yes 0.000 0.210 0.210 No Tail Gas Duct 8/29/23 Yes 0.380 0.110 0.270 No Type Code 282 (Procedure 3 - Annual Zero Alignment Audit) Point Source Location Audit Date Mean Difference Standard Deviation Confidence Coefficient Calibration Error (≤ 3%) Type Code 281 (Procedure 3 - COMS Filter Audit Calibration Error) Point Source Channel Audit Date Low Span Audit Gas Used High Span Audit Gas Used Kennecott EER 3Q2024 Monitoring Information TC 210, 230, & 240 Type Code 210 (Pollutant Concentration Exceeded Span of CEM) - 500 (All) * Sum of Hours Column Labels Row Labels (blank) Grand Total (blank)0 0 Grand Total 0 0 * Type Code 230 (Manual Sample - Alternate Sampling During Monitor Outage) - 500 (All) * Sum of Hours Column Labels Row Labels (blank) Grand Total (blank)0 0 Grand Total 0 0 * Type Code 240 (CEM Modifications) - 100 (All) * Count of Channel Column Labels Row Labels (blank) Grand Total (blank) (blank) Grand Total Kennecott EER 3Q2024 Type Code 220 (Monitor Outage During Point Source Operation) - 600 (All) * Sum of Hours Column Labels Row Labels 723 722 724 721 Grand Total Conc Dryer Opacity Calibration 10.8 10.8 Other QA 3.1 3.1 Opacity Audit 1.3 1.3 Main Stack Opacity Opacity Audit 1.0 1.0 SO2 Bad Calibration 12.0 12.0 Sample Train Problem 32.0 32.0 Maintenance 3.0 3.0 Calibration Gas Audit 3.0 3.0 NOx Sample Train Problem 59.0 59.0 Calibration Gas Audit 3.0 3.0 Instrument Malfunction 48.0 48.0 Tail Gas Opacity Opacity Audit 1.0 1.0 SO2 Calibration 72.0 72.0 Bad Calibration 11.0 11.0 Calibration Gas Audit 2.0 2.0 Grand Total 120.2 91.0 3.0 48.0 262.2 Kennecott EER 3Q2024 Opy * Opy Count of Magnitude of Emissions Column Labels Opy Row Labels 701 702 703 704 Grand Total Opy Conc Dryer 168 168 Opy Baghouse Problem 168 168 Opy Main Stack 14 186 11 1 212 Opy Secondary Gas System Trip - During Maintenance 11 11 Opy Shutdown - Residual process gas while offline 11 11 Opy Secondary Gas System Trip 186 186 Opy 82 Offline - Stopped Fan 1 1 Opy Startup - Acid Plant Converter Temperatures Low 3 3 Opy Tail Gas 17 17 Opy Startup - Acid Plant Converter Temperatures Low 13 13 Opy Acid Plant Trip - Compressors 4 4 Opy Grand Total 31 354 11 1 397 SO2 * SO2 Type Code 410 (SO2) - 6000 (All) SO2 * SO2 Count of Magnitude of Emissions Column Labels SO2 Row Labels 701 Grand Total SO2 FCG Trip SO2 Main Stack 3 3 SO2 Shutdown - FSF diversion to SGS during controlled shutdown SO2 Main Stack 3 3 SO2 Grand Total 6 6 NOx * NOx Type Code 420 (NOx) - 6000 (All) NOx * NOx Count of Magnitude of Emissions Column Labels NOx Row Labels Grand Total NOx Grand Total NOx d * NOx d Type Code 421 (Daily NOx Emissions) - 500 (All) NOx d * NOx d Count of Reason Code Column Labels NOx d Row Labels Grand Total NOx d Grand Total Kennecott EER 3Q2024 Type Code 500 Before February 28, 2005 (Boiler Operating Days w/o 18 Hours of Data) After February 28, 2005 (90% Operating Hours For each 30 BOD) - 500 (All) * Count of Channel Column Labels Row Labels Grand Total Grand Total * Type Code 510 (F-factor, Equations & Conversion Factors) - 500 (All) Count of F-factor Column Labels Row Labels Grand Total Grand Total * Type Code 520 (Minimum Data Not Obtained <22/30 BODs) - 500 (All) Count of Channel Column Labels Row Labels Grand Total Grand Total * Type Code 530 (Excess Emissions During Emergency Conditions) - 500 (All) Count of Date Column Labels Row Labels Grand Total Grand Total * Type Code 540 (Fuel Pre-treatment Credit SO2) - 500 (All) Count of Date Column Labels Row Labels Grand Total Grand Total * TypeCode 550 (Changes in Operation in Control Equipment When CEM Data Not Available) - 500 (All) Column Labels Row Labels Grand Total Grand Total