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HomeMy WebLinkAboutDRC-2012-001699 - 0901a068802f7a6f012-00 1699 Denison Mines (USA) Corp 105017th Street, Suite 950 Denver, CO 80265 USA Tel 303 628-7798 Fax 303 389-4125 www denisonmines com DENISO MINES July 27, 2012 VIA PDF AND FEDEX Rusty Lundberg, Co-Executive Secretary Utah Water Quality Board Utah Department of Environmental Quality 195 North 1950 West P O Box 144850 Salt Lake City, UT 84114-4850 Re: State of Utah Ground Water Discharge Permit No. UGW370004 White Mesa Uranium Mill - Notice Pursuant to Part I.G.I (a) Dear Mr Lundberg The White Mesa Mill (the "Mill") performed second quarter ("Q2") groundwater monitoring during the period from April 1, to June 30, 2012 under the July 14, 2011 version of the Mill's Groundwater Discharge Penrnt (the "GWDP") All analytical data needed for comparison to the GWCLs were received during the period ending July 18, 2012 Pursuant to Part IG 1 a) of the GWDP, (July 14, 2011) please take notice that the concentrations of specific constituents in the monitoring wells highlighted in yellow and bold italics in the columns for this quarter in the attached Table 1, exceeded their respective GWCLs For ease of review. Table 1 has been formatted to simplify the tracking of any continued exceedances from one monitoring period to the next by charting ongoing monitoring of the same well in the same row, and by highlighting exceedances (in color and bold italics) Part IG 1 c) of the GWDP states "that the Permittee shall prepare and submit within 30 calendar days to the Executive Secretary a plan and a time schedule for assessment of the sources, extent and potential dispersion of the contamination, and an evaluation of potential remedial action to restore and maintain groundwater quality to ensure that Permit limits will not be exceeded at the compliance monitoring point and that DMT or BAT will be reestablished " The summary below relating to Q2 2012 exceedances includes, for each exceedance, a brief discussion of whether such a plan and schedule is or is not required or appropriate at this time in light of other actions currently being undertaken by Denison, as determined by Utah Department of Environmental Quality (UDEQ) Staff and as stated in teleconferences with Denison on Apnl 27 and May 2, 2011 Based on the assessments noted below relating to the Q2 exceedances, a plan and N \Notices\GW Exceedence notices\2012 Exceedance Notices\Notice_of_Exceedance_GW_Q2 2012 08_20 docx Letter to Mr Rusty Lundberg July 27, 2012 Page 2 schedule for the Q2 2012 exceedances will not be required for the following reasons A Plan and Time Schedule will not be prepared for monitoring wells with two successive exceedances in Q2 2012 if successive exceedances were reported in a previous quarter and were included in the Plans and Schedules subnutted June 13, 2011, September 7, 2011 and amended April 13, 2012 A Plan and Time Schedule will not be submitted because the assessment processes and schedule have not changed since these previous subnussions Additionally, a Plan and Time Schedule will not be prepared for successive exceedances of nitrate + nitrite, chloride, chloroform, methylene chloride and pH because these constituents have been the subject of ongoing investigations at the Mill as discussed below Under the July 14, 2011 revision of the GWDP, GWCLs have been detemuned on a well-by- well basis to reflect background groundwater quality, as defined by the mean plus second standard deviation concentration, or the equivalent Accordingly, the GWDP requires that constituent concentrations in each monitoring well shall not exceed the GWCLs set out in Table 2 of the GWDP It should be noted that, because the GWCLs have been set at the mean plus second standard deviation, or the equivalent, un-impacted groundwater would normally be expected to exceed the GWCLs approximately 2 5% of the time Therefore, exceedances are expected in approximately 2 5% of all sample results, and do not necessarily represent impacts to groundwater from Mill operations The following are items of note relevant to all exceedance data presented herein 1 Nitrate + nitrite and chloride in monitoring wells at the site have been the subject of ongoing investigations at the Mill Based on the results of the previous investigations Denison and the Executive Secretary acknowledge that it has not been possible to date to determine the source(s), cause(s), attribution, magnitudes of contribution, and proportion(s) of the local nitrate + nitrite and chloride in groundwater Denison submitted a Corrective Action Plan ("CAP") for nitrate + nitrite and chloride in groundwater The CAP is currently undergoing a public comment period Based on information provided by UDEQ in teleconferences on April 27, and May 2, 2011, due to the ongoing activities and actions, the 30-day plan and schedule for assessment is not required for nitrate + nitrite and chloride exceedances at this time 2 As discussed in previous quarterly groundwater sampling reports, the background levels and GWCLs for pH were established based on eight or more quarters of laboratory data, which are historically higher than field data due to effects from the evolution of carbon dioxide, and subsequent increase in pH from field to lab Denison's letter to the Co- Executive Secretary of the Utah Water Quality Board dated January 31, 2011 proposed the recalculation of the GWCLs for field pH Following the statistical evaluation of pH data by Denison's geochenucal consultant, INTERA, Inc , Denison compared the Mill's most recent groundwater pH data from the Q2 of 2011, including accelerated sampling results as recent as June 2011, and noted that all of the June 2011 groundwater results, and many of the other results from Q2, were already outside the revised GWCLs that were to be proposed in the June 30, 2011 letter By the letter dated June 30, 2011, DENISO MINES N \NoUces\GW Exceedence notices\2012 Exceedance NoUces\Nonce_of_Exceedance_GW_Q2 2012 08_20 docx Letter to Mr Rusty Lundberg July 27, 2012 Page 3 Denison proposed to submit to DRC a Work Plan and Schedule to complete investigations to address the site-wide pH issue, following a meeting with DRC, to discuss Denison's findings to date and to agree upon the steps and milestone dates to be incorporated in the Work Plan and Schedule Pursuant to teleconferences with DRC on December 5, and December 19, 2011, Denison submitted the Work Plan and Schedule on January 20, 2012 and a revised plan based on DRC comments on April 13, 2012 The Work Plan and Time Schedule was approved by DRC Based on the approved Work Plan and Time Schedule, Denison and DRC entered into a Stipulated Consent Agreement ("SCA") dated July 12, 2012 Due to the current commitment and on-going study to evaluate site field pH conditions in the SCA, the 30-day plan and schedule for assessment IS not required for field pH exceedances 1.0 Exceedances in Required Quarterly Sampling Wells 1.1 Quarterly Wells with Two Successive Exceedances As indicated in the attached Table 1, the analytes discussed below exceeded their respective GWCLs for two successive sampling periods in Q2 2012 However, the 30-day plan and schedule contemplated in Part IG 1 c) of the GWDP will not be required for these particular consecutive exceedances which occurred in Q2 of 2012, for the reasons stated below One time exceedances and non-successive exceedances are noted on Table 1, but not listed below Consecutive exceedances which occurred in previous reporting periods are discussed in the respective 30-day plans and schedules for those quarters MW-26 • Nitrate + nitrite concentration exceeded its GWCL in all sampling events during Q2 2012 As mentioned above, nitrate + nitrite concentrations are currently under re- evaluation, and a plan to address this consecutive exceedance is not necessary and is not being submitted • Chloroform in MW-26 has exceeded its GWCL for all of the monitoring periods for Q2 2012 MW-26 IS used as a pumping well for the ongoing chloroform capture program and IS expected to yield increased concentrations of chloroform • Methylene chloride in MW-26 exceeded its GWCL all of the monitoring periods for Q2 2012 MW-26 is used as a pumping well for the ongoing chloroform capture program and IS expected to yield increased concentrations of methylene chloride MW-26 Note: As stated in the September 2009 Statement of Basis (page 23) m support of the January 20, 2010 revisions to the GWDP, "[i]t should be noted that, because MW-26 is a pumping well for chloroform removal, concentrations of all constituents in that well are subject to potential vanation over time as a result of the pumping activity This will be taken into account by the Executive Secretary in detenmning compliance for this well" Based on information provided by UDEQ m teleconferences on April 27, and May 2, 2011, due to the DENISO MINES N \Notices\GW Exceedence noUces\2012 Exceedance Notices\Notice_of_Exceedance_GW_Q2 2012 08_20 docx Letter to Mr Rusty Lundberg July 27, 2012 Page 4 current pumping status as part of the chloroform investigation program, the 30-day plan and schedule for assessment is not required at this time for exceedances of chloroform and methylene chloride in MW-26 • Chloride concentration exceeded its GWCL in all of the monitoring periods for Q2 2012 As mentioned above, chloride concentrations are currently under re-evaluation and a plan to address this consecutive exceedance is not necessary and is not being submitted MW-30 • Nitrate + nitrite concentration exceeded its GWCL in all sampling events during Q2 2012 and during previous quarters As mentioned above, nitrate + nitrite concentrations are currently under re-evaluation, and a plan to address this consecutive exceedance is not necessary and is not being submitted MW-31 Nitrate + nitrite concentration exceeded its GWCL in all sampling events during Q2 2012 and during previous quarters As mentioned above, nitrate + nitrite concentrations are currently under re-evaluation, and a plan to address this consecutive exceedance is not necessary and is not being subnutted Chloride concentration exceeded its GWCL in the April monthly and the Q2 (May 2012) sampling events As mentioned above, chloride concentrations are currently under re- evaluation, and a plan to address this consecutive exceedance is not necessary and is not being submitted TDS concentration exceeded its GWCL in all of the monitoring periods for Q2 2012 As noted above, a separate Plan and Time Schedule has not been submitted for this exceedance The successive TDS exceedances reported in Ql 2012 were added to, and addressed in conjunction, with the sulfate exceedances as described in the June 13, 2011 Plan and Time Schedule The rationale for addressing the TDS and sulfate together is based on the connection of sulfate to TDS, that is, sulfate is a component of TDS The time schedule for the assessment of TDS will be the same as that for sulfate MW-35 Manganese concentration exceeded the GWCL in MW-35 in all of the Q2 sampling events The consecutive manganese exceedances noted in MW-35 were previously discussed in the Plan and Time Schedule Under Part IG4 (d), submitted to UDEQ on September 7, 2011 as revised on April 13, 2012 An additional plan or schedule to address the Q2 exceedances is not necessary and is not being subnutted because the assessment processes and schedule have not changed since the September 7, 2011 and April 13, 2012 submissions It should be noted that background has not yet been established for MW-35 and that the interim GWCLs for MW-35 have been set at a fraction of the Groundwater Quality Standards pending the determination of background DENISO MINES N \Notices\GW Exceedence nonces\2012 Exceedance NoUces\Nonce_of_Exceedance_GW_Q2 2012 08_20 docx Letter to Mr Rusty Lundberg July 27, 2012 Page 5 Therefore, exceedances of the interim GWCLs do not necessarily represent impacts to groundwater from Mill activities • Uranium concentration exceeded the GWCL in MW-35 in all of the Q2 sampling events The consecutive uranium exceedances noted in MW-35 were previously discussed in the Plan and Time Schedule Under Part IG4 (d), submitted to UDEQ on September 7, 2011 as revised on April 13, 2012 An additional plan or schedule to address the Q2 exceedances is not necessary and is not being submitted because the assessment processes and schedule have not changed since the September 7, 2011 and April 13, 2012 submissions It should be noted that background has not yet been established for MW-35 and that the interim GWCLs for MW-35 have been set at a fraction of the Groundwater Quality Standards pending the determination of background Therefore, exceedances of the interim GWCLs do not necessarily represent impacts to groundwater from Mill activities • Gross alpha concentration exceeded the GWCL in MW-35 in all of the Q2 sampling events An additional plan or schedule to address the Q2 exceedances is not necessary and is not being submitted because the background has not yet been established for MW- 35, and the interim GWCLs for MW-35 have been set at a fraction of the Groundwater Quality Standards pending the determination of background Therefore, exceedances of the interim GWCLs do not necessarily represent impacts to groundwater from Mill activities • Thallium concentration exceeded the GWCL in MW-35 in the April monthly and the Q2 (May) sampling events An additional plan or schedule to address the these exceedances IS not necessary and is not being submitted because the background has not yet been established for MW-35, and the interim GWCLs for MW-35 have been set at a fraction of the Groundwater Quality Standards pending the determination of background Therefore, exceedances of the interim GWCLs do not necessarily represent impacts to groundwater from Mill activities 1.2 Quarterly Wells with New Exceedances Reported in Q2 New exceedances for the Q2 2012 quarterly well sampling program are listed below This exceedance will result in an accelerated sampling frequency from quarterly to monthly It is important to note that the well listed below will only be sampled during the monthly events for those constituents which exceeded the GWCLs The well listed below will be sampled for all constituents listed in the GWDP during the quarterly events as that is the regularly scheduled sampling for the quarterly wells • Manganese in MW-14 exceeded the GWCL in the May (Q2) sampling event DENISO MINES N \Notices\GW Exceedence notices\2012 Exceedance Notices\Notice_of_Exceedance_GW_Q2 2012 08_20 docx Letter to Mr Rusty Lundberg July 27, 2012 Page 6 Relative to accelerated reporting requirements, based on phone conversations with UDEQ on April 5, 2010, that reporting of exceedances is required to be completed within 30 days of receipt of the last data package for a quarterly monitoring event Similarly, accelerated monitoring is required to commence the month following the submission of the Exceedance Notice for a specified quarter for wells that are being accelerated from quarterly to monthly and the quarter following the submission of the Exceedance Notice for wells that are being accelerated from senuannually to quarterly Per teleconferences with UDEQ, Denison proposed modified language for the GWDP, Part 1 G 1 on May 25, 2012, to document DRC concurrence with the accelerated reporting and monitoring agreements resulting from the April 5, 2012 teleconference 2.0 Exceedances in Semiannual Sampling Wells Accelerated to Quarterly 2.1 Semi-annual Wells with Two Successive Exceedances As indicated in the attached Table 1, the analytes discussed below exceeded their respective GWCLs for two successive sampling periods (Ql and Q2) MW-3 Selenium has exceeded the GWCL for both the Ql sampling event and the Q2 sampling event The consecutive selenium exceedances noted in MW-3 were previously discussed in the Plan and Time Schedule Under Part 104 (d), submitted to UDEQ on June 13, 2011 as revised on April 13, 2012 An additional plan or schedule to address the Q2 exceedances is not necessary and is not being subnutted because the assessment processes and schedule have not changed since the June 13, 2011 and April 13, 2012 submissions Fluoride has exceeded the GWCL for both the Q1 sampling event and the Q2 sampling event The consecutive selenium exceedances noted in MW-3 were previously discussed in the Plan and Time Schedule Under Part 104 (d), subnutted to UDEQ on June 13, 2011 as revised on April 13, 2012 An additional plan or schedule to address the Q2 exceedances is not necessary and is not being submitted because the assessment processes and schedule have not changed since the June 13, 2011 and April 13, 2012 submissions MW-18 Thallium has exceeded the GWCL for both the Ql sampling event and the Q2 sampling event The consecutive thallium exceedances noted in MW-18 were previously discussed in the Plan and Time Schedule Under Part 104 (d), submitted to UDEQ on June 13, 2011 as revised on April 13, 2012 An additional plan or schedule to address the Q2 exceedances is not necessary and is not being submitted because the assessment processes and schedule have not changed since the June 13, 2011 and April 13, 2012 submissions DENISO MINES N \Notices\GW Exceedence notices\2012 Exceedance NoUces\Notice_of_Exceedance_GW_Q2 2012 08_20 docx Letter to Mr Rusty Lundberg July 27, 2012 Page 7 • TDS has exceeded the GWCL for both the Ql sampling event and the Q2 sampling event The consecutive TDS exceedances noted in MW-18 were previously discussed in the Plan and Time Schedule Under Part 104 (d), subnutted to UDEQ on June 13, 2011 as revised on April 13, 2012 An additional plan or schedule to address the Q2 exceedances is not necessary and is not being submitted because the assessment processes and schedule have not changed since the June 13, 2011 and April 13, 2012 submissions MW-19 Nitrate + Nitrite have exceeded the GWCL for both the Ql sampling event and the Q2 sampling event and during previous quarters As mentioned above, nitrate + nitrite concentrations are currently under re-evaluation, and a plan to address this consecutive exceedance is not necessary and is not being subnutted MW-24 Field pH has been slightly outside (slightly lower than) the GWCL for both the Ql sampling event and the Q2 sampling event As mentioned above, site-wide pH issues and trends are currently included in a separate study, and a plan and schedule to address this consecutive exceedance is not necessary and is not being subnutted MW-27 Nitrate + Nitrite have exceeded the GWCL for both the Ql sampling event and the Q2 sampling event and durmg previous quarters As mentioned above, nitrate + nitrite concentrations are currently under re-evaluation, and a plan to address this consecutive exceedance is not necessary and is not being subnutted Chloride has exceeded the GWCL for both the Ql sampling event and the Q2 sampling event and during previous quarters As mentioned above, chloride concentrations are currently under re-evaluation, and a plan to address this consecutive exceedance is not necessary and is not being subnutted TDS has exceeded the GWCL for both the Ql sampling event and the Q2 sampling event The consecutive TDS exceedances noted in MW-27 were previously discussed in the Plan and Time Schedule Under Part 104 (d), subnutted to UDEQ on June 13, 2011 as revised on Apnl 13, 2012 An additional plan or schedule to address the Q2 exceedances is not necessary and is not being submitted because the assessment processes and schedule have not changed since the June 13, 2011 and April 13, 2012 subnussions MW-28 Chloride has exceeded the GWCL for both the Ql sampling event and the Q2 sampling event and during previous quarters As mentioned above, chloride concentrations are DENISO MINES N \Notices\GW Exceedence notices\2012 Exceedance Nouces\Notice_of_Exceedance_GW_Q2 2012 08_20 docx Mi Letter to Mr Rusty Lundberg July 27, 2012 Page 8 currently under re-evaluation, and a plan to address this consecutive exceedance is not necessary and is not being submitted 2.1 Semi-annual Wells with New Exceedances Reported in Q2 New exceedances for the Q2 2012 semi-annual well sampling program are listed below These exceedances will result in an accelerated sampling frequency from semi-annually to quarterly It IS important to note that the well listed below will only be sampled during the quarterly events for those constituents which exceeded the GWCLs The well listed below will be sampled for all constituents listed m the GWDP during the semi-annual events (Q2 and Q4) as that is the regularly scheduled sampling for the semi-annual wells • Selenium in MW-15 exceeded the GWCL in the May (Q2) sampling event • Manganese in MW-28 exceeded the GWCL in the May (Q2) sampling event • Manganese in MW-29 exceeded the GWCL in the May (Q2) sampling event • TDS in MW-29 exceeded the GWCL in the May (Q2) sampling event If you have any questions or require any further information, please contact the undersigned Yours truly. Jo Ann Tischler Director, Compliance and Pemutting cc David Frydenlund Harold Roberts David Turk DENISO MINES N \Notices\GW Exceedence notices\2012 Exceedance Notices\Notice_of_Exceedance_GW_Q2 2012 08_20 docx Jiii Ql 2010 Results Q2 2010 Results 03 2010 Results Q4 2010 Results Monitonng WeU (Water Class) Constituent Exceeding GWCL GWCL m July 14,2011 GWDP Ql 2010 Sample Date Ql 2010 Result Q2 2010 Sample Date Q2 2010 Result May 2010 Monthly Sample Date May 2010 Monthly Result June 2010 Monthly Sample Oate June 2010 Monthly Result July 2010 Monthly Sample Date July 2010 Monthly Result August 2010 Monthly Sample Date August 2010 Monthly Result Q3 2010 Sample Date Q3 2010 Result October 2010 Monthly Sample Date October 2010 Monthly Result Q4 2010 Sample Date Q4 2010 Result December 2010 Monthly Sample Date December 2010 Monthly Result Required Quarterly Sampling WeUs MW-11 (Class U) Manganese (ug/L) 131 29 2/10/10 134 4/28/10 137 5/24/10 122 6/16/10 99 7/20/10 123 8/25/10 138 9/8/10 128 141 133 12/15/10 158 MW-11 (Class U) Tetrahydrofuran (ug/L) 115 2/10/10 12 4/28/10 52 5/24/10 <1 0 6/16/10 <1 0 7/27/10 2 17 8/25/10 <1 0 9/8/10 <1 0 10/20/10 <10 11/11/10 <1 0 12/15/10 <1 0 MW-14 (Class m) Manganese (ug/L) 2230 30 2060 2070 NA NA NA NA 1920 10/20/10 NA 1980 12/15/10 NA MW-14 (Class m) Field pH (S U ) 65-85 2/2/10 6 45 4/21/10 629 5/21/10 6 36 6/16/10 645 7/20/10 7 19 8/25/10 648 9/8/10 651 10/20/10 6 60 11/10/10 6 37 12/15/10 6 47 MW-25 (Class UI) Field pH (S U ) 65-85 2/26/2010 6 53 4/28/2010 72 NS NA NS NA NS NA NS NA 9/8/2010 6 58 NS NA 11/10/10 6 36 NS NA MW-25 (Class UI) Uranium 65 5 93 6 43 NS NA NS NA NS NA NS NA 9/8/2010 6 57 NS NA 5 89 NS NA MW-26 (Class III) Nitfate + Nitrite (as N) (mgA.) 0 62 13 2 03 04 06 06 9/26/10 07 10/20/10 04 11/15/10 02 12/15/10 04 MW-26 (Class III) Uranium (ug/L) 41 8 2/2/10 58 7 66 7 37 4 36 6 34 4 718 9/26/10 72 7 10/20/10 37 5 11/15/10 30 4 12/15/10 29 6 MW-26 (Class III) Chloroform (ug/L) 70 2/2/10 700 1700 800 940 900 2800 9/26/10 2100 10/20/10 1000 11/15/10 1900 12/15/10 1400 MW-26 (Class III) Chloride (mg/L) 58 31 2/2/10 72 57 80 47 52 49 9/26/10 64 10/20/10 52 11/15/10 48 12/15/10 52 MW-26 (Class III) Field pH (S U ) 6 74 - 8 5 2/2/10 6 59 4/22/10 7 18 5/21/10 636 t)/16/10 6 98 7/21/10 6 45 8/16/10 639 9/26/10 6 60 10/20/10 6 61 11/15/10 6 49 12/15/10 6 45 MW-26 (Class III) Dichloromethane (Methylene Chloride) (UgA.) 5 2/2/10 1 4/22/10 99 5/21/10 NR t)/16/10 22 7/21/10 12 8/16/10 24 9/26/10 45 10/20/10 55 11/15/10 16 12/15/10 1 2 MW-26 (Class III) TDS (mg/L) 3284 19 2/2/10 3100 4/22/10 3280 5/21/10 NS t)/16/10 NS 7/21/10 NS 8/16/10 NS 9/26/10 3440 10/20/10 NS 11/15/10 3140 12/15/10 NS MW-26 (Class III) Gross Alpha minus Rn & U (pCi/L) 4 69 2/2/10 24 4/22/10 06 5/21/10 NS t)/16/10 NS 7/21/10 NS 8/16/10 NS 9/26/10 25 10/20/10 NS 11/15/10 64 12/15/10 NS MW-30 (Class n) Nitrate + Nitrite (as N) (mgA.) 25 2/9/10 161 4/27/10 15 8 5/21/10 17 6/15/10 15 3 7/21/10 16 8/24/10 16 9/14/10 15 10/19/10 IS 11/9/10 15 12/14/10 16 MW-30 (Class n) Chlonde (mg/L) 128 2/9/10 127 4/27/10 97 5/21/10 NS 6/15/10 NS NS NS NS NS 9/14/10 111 10/19/10 NS 11/9/10 126 12/14/10 NS MW-30 (Class n) Field pH (S U ) 65-85 2/9/10 681 4/27/10 6 55 5/21/10 6 62 6/15/10 7 47 7/21/2010 6 82 8/24/10 6 73 9/14/10 6 80 10/19/10 6 77 11/9/10 6 75 12/14/10 6 65 MW-30 (Class n) Uranium (ug/L) 8 32 2/9/10 6 82 4/27/10 6 82 5/21/10 NS 6/15/10 NS NS NS NS NS 9/14/10 7 10 10/19/10 NS 11/9/10 6 64 12/14/10 NS MW-30 (Class n) Selenium (ug/L) 34 2/9/10 32 4/27/10 35 J 5/21/10 NS 6/15/10 NS 7/27/10 33 5 8/24/10 35 6 9/14/10 32 6 10/19/10 32 4 11/9/10 32 2 12/14/10 30 5 MW-31 (Class in) Nitrate + Nitrite (as N) (mgA,) 5 2/9/10 21 7 4/20/10 22 5 5/21/10 23 6/15/10 21 1 7/21/10 20 8/24/10 22 9/13/10 21 10/19/10 20 11/9/10 20 12/14/10 20 MW-31 (Class in) TDS (mg/L) 1320 2/9/10 1150 4/20/10 1220 NS NA NS NA NS NA NS NA 9/13/10 1330 NS NA 11/9/10 1320 12/14/10 NS MW-31 (Class in) Chloride (mg/L) 143 2/9/10 128 4/20/10 128 NS NA NS NA NS NA NS NA 9/13/10 139 NS NA 11/9/10 138 12/14/10 NS MW-31 (Class in) Field pH (S U ) 65-85 2/9/10 6 96 4/20/10 7 38 5/21/10 6 95 6/15/10 701 7/21/10 78 8/24/10 7 1 9/13/10 7 66 10/19/10 6 92 11/9/10 6 98 12/14/10 6 95 MW-31 (Class in) Sulfate (mg/L) 532 2/9/10 507 4/20/10 522 NS NA NS NA NS NA NS NA 9/13/10 527 NS NA 11/9/10 539 12/14/10 NS MW-35 (Class n) Manganese (ug/L) 200 NS NA NS NA NS NA NS NA NS NA NS NA NS NA NS NA 11/30/10 698 NS NA MW-35 (Class n) Thalbum (ug/l) 05 NS NA NS NA NS NA NS NA NS NA NS NA NS NA NS NA 11/30/10 1 14 NS NA MW-35 (Class n) Gross Alpha minus Rn & U (pCiA.) 3 75 NS NA NS NA NS NA NS NA NS NA NS NA NS NA NS NA 11/30/10 26 NS NA MW-35 (Class n) Selenium (ug/L) 125 NS NA NS NA NS NA NS NA NS NA NS NA NS NA NS NA 11/30/10 ND NS NA MW-35 (Class n) Uranium (ug/L) 75 NS NA NS NA NS NA NS NA NS NA NS NA NS NA NS NA 11/30/10 272 NS NA Required Semi-Annual Sampbng Wells MW-2 (Class m) Gross Alpha minus Rn & U (oCi/L) 32 NS NA 1 2 NS NA NS NA NS NA NS NA NS NA NS NA 35 NS NA MW-3 (Class UI) Selenium (ug/L) 37 NS NA 5/3/10 372 NS NA NS NA NS NA NS NA 9/20/10 35 5 NS NA 11/19/10 38 8 NS NA MW-3 (Class UI) Field pH (S U ) 65-85 NS NA 5/3/10 6 14(625) NS NA NS NA NS NA NS NA 9/20/10 6 39 NS NA 11/19/10 6 35 NS NA MW-3 (Class UI) Fluoride (Mg/L) 0 68 NS NA 5/3/10 0 71 NS NA NS NA NS NA NS NA 9/20/10 0 63 NS NA 11/19/10 0 77 NS NA MW-3A (Class no Field pH (S U ) 65-85 NS NA 5/4/10 6 23(624) NS NA NS NA NS NA NS NA 9/21/10 6 42 NS NA 11/22/10 621 NS NA MW-3A (Class no Sulfate (mg/L) 3640 NS NA 5/4/10 3680 NS NA NS NA NS NA NS NA 9/21/10 3630 NS NA 11/22/10 3850 NS NA MW-3A (Class no TDS (mgA,) 5805 NS NA 5860 NS NA NS NA NS NA NS NA 5470 NS NA 11/22/10 5330 NS NA MW-3A (Class no Selenium (ug/L) 89 NS NA 81 4 NS NA NS NA NS NA NS NA NS NS NA 948 NS NA MW-5 (Class n) Uranium (ug/L) 75 NS NA 4/26/10 0 39 NS NA NS NA NS NA NS NA NS NA NS NA 11/11/10 116 NS NA MW-12 (Class Field pH (S U ) 65-85 NS NA 7 16 NS NA NS NA NS NA NS NA 6 62 NS NA 647 NS NA m) Selenium (ug/L) 25 NS NA 4/27/10 25 7 NS NA NS NA NS NA NS NA 9/20/10 319 NS NA 11/19/10 27 6 NS NA MW-15 (Class Selenium (ug/L) 128 7 NS NA 100 NS NA NS NA NS NA NS NA NA NS NA 99 5 NS NA ID) Iron (ug/L) 81 7 NS NA 4/z ll lU ND NS NA NS NA NS NA NS NA NS NA NS NA 11/11/10 ND NS NA MW-18 (Class Thalbum (ug/l) 1 95 NS NA 3 73 NS NA NS NA NS NA NS NA 364 NS NA 3 57 NS NA HI) Sulfate (mg/L) 1938 9 NS NA 5/4/10 1950 NS NA NS NA NS NA NS NA 9/15/10 1930 NS NA 11/18/10 1910 NS NA Field pH (S U ) 6 25-8 5 NS NA 62 NS NA NS NA NS NA NS NA 7 23 NS NA 6 37 NS NA TDS (mg/L) 3198 77 NS NA 3280 NS NA NS NA NS NA NS NA 3190 NS NA 3030 NS NA Ql 2010 Results Q2 2010 Results Q3 2010 Results Q4 2010 Results Momtonng Well (Water Class) Constituent Exceeding GWCL GWCL in Current GWDP Ql Sample Date Ql Result Q2 Sample Date Q2 Result May Monthly Sample Date May Monthly Result June Monthly Sample Date June Monthly Result July Monthly Sample Date July Monthly Result August Monthly Sample Date August Monthly Result Q3 Sample Date Q3 Result October Monthly Sample Date October Monthly Result Q4 Sample Date Q4 Result December Monthly Sample Date December Monthly Result Required Semi-Annual Sampling Wells, conUnued MW-19 (Class ni) Field pH (S U ) 6 78-8 5 NS NA 5/4/10 6 61 (6 66) NS NA NS NA NS NA NS NA 9/15/10 6 93 NS NA 11/18/10 68 NS NA MW-19 (Class ni) Niu-ate + Nitfite (as N) (mgA.) 2 83 NS NA 5/4/10 26 NS NA NS NA NS NA NS NA 9/15/10 NS NA NA 11/18/10 24 NS NA MW-23 (Class ni) Field pH (S U ) 65-85 NS NA 4/22/10 6 18 NS NA NS NA NS NA NS NA 9/14/10 7 05 NS NA 11/22/10 6.44 NS NA MW-23 (Class ni) Manganese (ug/L) 550 NS NA 4/22/10 184 NS NA NS NA NS NA NS NA 9/14/10 NS NS NA 11/22/10 65 NS NA MW-24 (Class ni) Cadmium (ug/L) 25 NS NA 5/6/10 428 NS NA NS NA NS NA NS NA 9/21/10 506 NS NA 11/17/10 3 22 NS NA MW-24 (Class ni) Thallium (ug/L) 1 NS NA 5/6/10 13 NS NA NS NA NS NA NS NA 9/21/10 157 NS NA 11/17/10 109 NS NA MW-24 (Class ni) Field pH (S U ) 65-85 NS NA 5/6/10 5 91 (5 78) NS NA NS NA NS NA NS NA 9/21/10 6 64 NS NA 11/17/10 61 NS NA MW-27 (Class m) Nitrate+ Niu-ite (as N) (mgA.) 56 NS NA 5/3/10 58 NS NA NS NA NS NA NS NA 9/14/10 59 NS NA 11/12/10 57 NS NA MW-27 (Class m) Chloride (mg/L) 38 NS NA 5/3/10 42 NS NA NS NA NS NA NS NA 9/14/10 42 NS NA 11/12/10 45 NS NA MW-27 (Class m) Sulfate (mg/L) 462 NS NA 5/3/10 469 NS NA NS NA NS NA NS NA 9/14/10 461 NS NA 11/12/10 452 NS NA MW-27 (Class m) Field pH (S U ) 6 5-8 5 NS NA 5/3/10 6 78 NS NA NS NA NS NA NS NA 9/14/10 7 68 NS NA 11/12/10 6 89 NS NA MW-27 (Class m) TDS (mgA.) 1075 NS NA 5/3/10 1160 NS NA NS NA NS NA NS NA 9/14/10 1060 NS NA 11/12/10 1110 NS NA MW-27 (Class m) Gross Alpha minus Rn & U (pCi/L) 2 NS NA 5/3/10 1 6 NS NA NS NA NS NA NS NA 9/14/10 NA NS NA 11/12/10 24 NS NA MW-28 (Class m Chlonde (mg/L) 105 NS NA 4/19/10 108 NS NA NS NA NS NA NS NA 9/14/10 106 NS NA 11/12/10 107 NS NA MW-28 (Class m Manganese (ug/L) 1837 NS NA 4/19/10 1550 NS NA NS NA NS NA NS NA 9/14/10 NA NS NA 11/12/10 1510 NS NA MW-28 (Class m Field pH (S U ) 6 1-85 NS NA 4/19/10 5 67 NS NA NS NA NS NA NS NA 9/14/10 5 91 NS NA 11/12/10 5 72 NS NA MW-29 (Class ni) Iron (ug/L) 1869 NS NA 4/27/10 1630 NS NA NS NA NS NA NS NA NS NA NS NA 11/9/10 1490 NS NA MW-29 (Class ni) Manganese (ug/L) 5624 NS NA 4/27/10 4820 NS NA NS NA NS NA NS NA NS NA NS NA 11/9/10 4890 NS NA MW-29 (Class ni) TDS (mg/L) 4400 NS NA 4/27/10 4400 NS NA NS NA NS NA NS NA NS NA NS NA 11/9/10 4390 NS NA MW-29 (Class ni) Field pH (S U ) 6 46 - 8 5 NS NA 4/27/10 6 82 NS NA NS NA NS NA NS NA NS NA NS NA 11/9/10 617 NS NA MW-32 (Class UI) Gross Alpha minus Rn & U (pCi/L) 3 33 NS NA 4/20/10 45 NS NA NS NA NS NA NS NA 9/13/10 29 NS NA 11/10/10 88 NS NA MW-32 (Class UI) Field pH (S U ) 64-85 NS NA 4/20/10 6 03 NS NA NS NA NS NA NS NA 9/13/10 6 33 NS NA 11/10/10 6 05 NS NA Notes — GWCL values are taken from February 15, 2011 version of GWDP NS = Not Requu-ed and Not Sampled NR = Required and Not Reported NA = Not Apphcable Exceedances are shown in yellow Values in () parentheses are the field pH measurements for the resampled analyses Pursuant to the October 26 2011 DRC letter gross alpha monitoring ui MW-26 returned to the routine frquency of quarterly These samples were inadvertantly collected and are for informauon only Table 1 - GWCL Exceedances for Second Quarter 2012 under the July 14,2011 GWDP Ql 2011 Results Q2 2011 Results Q3 2011 Results Q4 2011 Results Monitonng Well (Water Class) Constituent Exceeding GWCL GWCL m July 14,2011 GWDP January 2011 Monthly Sample Date January 2011 Monthly Sample Result Ql 2011 Sample Date Q12011 Result March 2011 Monthly Sample Date March 2011 Monthly Result Q2 2011 Sample Date Q2 2011 Result May 2011 Monthly Sample Date May 2011 Monthly Result June 2011 Monthly Sample Date June 2011 Monthly Result July 2011 Monthly Sample Date July 2011 Monthly Result Q3 2011 Sample Date Q3 2011 Result September 2011 Monthly Sample Date September 2011 Monthly Result Q4 2011 Sample Date Q4 2011 Result November 2011 Monthly Sample Date November 2011 Monthly Result December 2011 Monthly Sample Date December 2011 Monthly Result Required Quarterly Sampling Wells MW-11 (Class 0) Manganese (ug/L) 131 29 121 145 68 148 170 6/15/2011 121 151 8/3/2011 118 106 112 105 100 MW-11 (Class 0) Tetrahydrofuran (ug/L) 115 1/11/11 <1 0 2/2/11 <\ 0 3/15/11 <1 0 4/4/2011 <1 0 5/10/2011 <1 0 6/20/2011 <1 0 7/6/2011 <1 0 8/30/11 <1 0 9/7/2011 <1 0 10/4/2011 <1 0 11/9/2011 <1 0 12/14/2011 <1 0 MW-14 (Class m) Manganese (ug/L) 2230 30 NA 2020 NA 2140 NA NA NA 1990 NA 1960 NA 12/12/2011 NA MW-14 (Class m) Field pH (S U ) 65-85 1/11/11 6 37 2/7/11 6 22 3/14/11 6 76 4/4/2011 6 63 5/10/2011 637 6/15/2011 5 83 7/5/2011 64 8/3/2011 623 (6 41) 9/8/2011 6 50 10/4/2011 6 71 (6 82) 11/9/2011 6 63 12/12/2011 6 84 MW-25 (Class UI) Field pH (S U ) 65-85 1/11/11 644 2/2/11 6 66 3/15/11 6 79 4/4/2011 67 5/11/2011 61 6/20/2011 5 77 7/6/2011 629 8/3/2011 8/30/11 6 42 (6 54) 9/7/2011 6 54 10/4/2011 66 11/9/2011 651 1212/2011 6 87 MW-25 (Class UI) Uranium 65 1/11/11 702 4 77 6.8 5 56 6 72 6/20/2011 7 06 6 74 8/3/2011 6 37 9/7/2011 5 96 10/4/2011 5 27 11/9/2011 6 56 1212/2011 6 1 MW-26 (Class UI) Nitrate + Nitrite (as N) (mgA.) 0 62 1/12/11 02 0 25 06 08 04 03 09 06 24 10/12/2011 09 11/9/2011 13 12/14/2011 25 MW-26 (Class UI) Uranium (ug/L) 41 8 1/12/11 32 2/16/11 69 3 3/15/11 31 8 4/1/2011 602 5/10/2011 574 6/20/2011 185 7/6/2011 57 1 8/3/2011 8/30/11 19 0 9/7/2011 56 1 10/12/2011 5«9 11/9/2011 55 6 12/14/2011 57 MW-26 (Class UI) Chloroform (ug/L) 70 1/12/11 800 2/16/11 730 3/15/11 1200 4/1/2011 390 5/10/2011 7900 6/20/2011 730 7/6/2011 300 8/3/2011 8/30/11 1000 9/7/2011 1300 10/12/2011 440 11/9/2011 1200 12/14/2011 1400 MW-26 (Class UI) Chlonde (mg/L) 58 31 1/12/11 52 2/16/11 59 3/15/11 64 4/1/2011 64 5/10/2011 54 6/20/2011 39 7/6/2011 64 8/3/2011 8/30/11 60 9/7/2011 66 10/12/2011 61 11/9/2011 55 12/14/2011 62 MW-26 (Class UI) Field pH (S U ) 6 74 - 8 5 1/12/11 6 83 2/16/11 6 06 3/15/11 6 89 4/1/2011 6 22 5/10/2011 643 6/20/2011 6 52 7/6/2011 6 35 8/3/2011 8/30/11 6 07 (658) 9/7/2011 6 71 10/12/2011 6 82 11/9/2011 6 75 12/14/2011 7 1 MW-26 (Class UI) Dichloromethane (Mediylene Chloride) (UgA.) 5 1/12/11 <1 0 2/16/11 10 3/15/11 14 4/1/2011 3 1 5/10/2011 20 6/20/2011 7 7/6/2011 24 8/3/2011 8/30/11 10 9/7/2011 79 10/12/2011 26 11/9/2011 89 12/14/2011 11 MW-26 (Class UI) TDS (mgA.) 3284 19 1/12/11 3100 2/16/11 3270 3/15/11 3140 4/1/2011 3310 5/10/2011 3140 6/20/2011 3020 7/6/2011 3270 8/3/2011 8/30/11 3190 9/7/2011 3200 10/12/2011 3190 11/9/2011 3220 12/14/2011 3160 MW-26 (Class UI) Gross Alpha minus Rn & U (pCiA.) 4 69 1/12/11 NS 2/16/11 3 3/15/11 27 4/1/2011 33 5/10/2011 39 6/20/2011 43 7/6/2011 28 8/3/2011 8/30/11 27 9/7/2011 25 10/12/2011 22 11/9/2011 NS 12/14/2011 NS MW-30 (Class II) Nitrate + Nitrite (as N) (mgA.) 25 1/10/11 15 2/1/11 16 3/14/11 17 4/11/2011 16 5/10/2011 16 6/20/2011 17 7/5/2011 17 8/3/2011 14 9/7/2011 16 10/4/2011 16 11/8/2011 16 12/12/2011 16 MW-30 (Class II) Chlonde (mg/L) 128 1/10/11 NS 2/1/11 134 3/14/11 NS 4/11/2011 134 5/10/2011 128 6/20/2011 127 7/5/2011 127 8/3/2011 126 9/7/2011 145 10/4/2011 129 11/8/2011 122 12/12/2011 124 MW-30 (Class II) Field pH (S U ) 65-85 1/10/11 6 65 2/1/11 6 96 3/14/11 7 10 4/11/2011 6 83 5/10/2011 67 6/20/2011 5 66 7/5/2011 6 65 8/3/2011 661 9/7/2011 6 80 10/4/2011 6 96 (6 73) 11/8/2011 6 83 12/12/2011 7 14 MW-30 (Class II) Uranium (ug/L) 8 32 1/10/11 NS 2/1/11 5 97 3/14/11 NS 4/11/2011 6 49 5/10/2011 NS 6/20/2011 NS 7/5/2011 NS 8/3/2011 8 9/7/2011 NS 10/4/2011 983 11/8/2011 NS 12/12/2011 NS MW-30 (Class II) Selenium (ug/L) 34 1/10/11 362 2/1/11 34 7 3/14/11 34 4/11/2011 444 5/10/2011 38 3 6/20/2011 38 7 7/5/2011 32 4 8/3/2011 J9 7 9/7/2011 32 4 10/4/2011 36 6 11/8/2011 368 12/12/2011 38 MW-31 (Class ni) Nitrate + Nitnte (as N) (mgA.) 5 1/10/11 19 2/1/11 21 3/14/11 22 4/1/2011 21 5/10/2011 20 6/20/2011 22 7/5/2011 22 8/2/2011 20 9/6/2011 21 10/3/2011 21 11/8/2011 21 12/12/2011 21 MW-31 (Class ni) TDS (mg/L) 1320 1/10/11 1240 2/1/11 1220 3/14/11 1250 4/1/2011 1370 5/10/2011 1290 6/20/2011 1330 7/5/2011 1280 8/2/2011 1300 9/6/2011 1300 10/3/2011 1320 11/8/2011 1290 12/12/2011 1330 MW-31 (Class ni) Chlonde (mgA.) 143 1/10/11 NS 2/1/11 145 3/14/11 NS 4/1/2011 143 5/10/2011 143 6/20/2011 145 7/5/2011 148 8/2/2011 148 9/6/2011 148 10/3/2011 145 11/8/2011 145 12/12/2011 148 MW-31 (Class ni) Field pH (S U ) 65-85 1/10/11 6 65 2/1/11 721 3/14/11 7 43 4/1/2011 7 01 5/10/2011 6 73 6/20/2011 616 7/5/2011 6 64 8/2/2011 6 67 9/6/2011 7 03 10/3/2011 7 28 (7 34) 11/8/2011 701 12/12/2011 7 46 MW-31 (Class ni) Sulfate (mg/L) 532 1/10/11 NS 2/1/11 538 3/14/11 531 4/1/2011 503 5/10/2011 512 6/20/2011 540 7/5/2011 532 8/2/2011 537 9/6/2011 541 10/3/2011 559 11/8/2011 552 12/12/2011 530 MW-35 (Class U) Manganese (ug/L) 200 NS NA 2/15/11 248 NS NA 6/7/2011 369 NS NA NS NA 7/20/11 348 8/30/2011 267 9/7/11 270 10/3/11 27/ 11/8/2011 283 12/14/11 247 MW-35 (Class U) Thalbum (ugA) 05 NS NA 2/15/11 <0 50 NS NA 6/7/2011 <0 50 NS NA NS NA 7/20/11 NS 8/30/2011 052 9/7/11 NS 10/3/11 0 57 11/8/2011 <050 12/14/11 0 63 MW-35 (Class U) Gross Alpha minus Rn & U (pCiA.) 3 75 NS NA 2/15/11 26 NS NA 6/7/2011 37 NS NA NS NA 7/20/11 NS 8/30/2011 45 9/7/11 NS 10/3/11 44 11/8/2011 47 12/14/11 42 MW-35 (Class U) Selenium (ug/L) 12 5 NS NA 2/15/11 ND NS NA 6/7/2011 ND NS NA NS NA 7/20/11 NA 8/30/2011 93 9/7/11 NA 10/3/11 105 11/8/2011 NA 12/14/11 NA MW-35 (Class U) Uranium (ug/L) 75 NS NA 2/15/11 12 7 NS NA 6/7/2011 21 7 NS NA NS NA 7/20/11 242 8/30/2011 183 9/7/11 22 3 10/3/11 201 11/8/2011 24 12/14/11 23 6 Required Semi-Annual Sampling Wells MW-2 (Class in) Gross Alpha minus Rn & U (pCi/L) 32 NS NA 1 1 NS NA 4/12/2011 1 2 NS NA NS NA NS NA 8/8/2011 05 NS NA 10/5/2011 1 3 NS NA NS NA MW-3 (Class in) Selenium (ug/L) 37 NS NA 2/15/11 405 NS NA 4/13/2011 45 4 NS NA NS NA NS NA 8/10/2011 46 NS NA 10/10/2011 467 NS NA NS NA MW-3 (Class in) Field pH (S U ) 65-85 NS NA 2/15/11 6 09 NS NA 4/13/2011 646 NS NA NS NA NS NA 8/10/2011 6 32 NS NA 10/10/2011 6 53 (6 83) NS NA NS NA MW-3 (Class in) Fluonde (Mg/L) 0 68 NS NA 2/15/11 069 NS NA 0 68 NS NA NS NA NS NA 8/10/2011 0 96 NS NA 10/10/2011 0 9/ NS NA NS NA MW 3A (Class IU) Field pH (S U ) 65-85 NS NA 6 05 NS NA 6 58 NS NA NS NA NS NA 619 NS NA 6 5 (6 92) NS NA NS NA MW 3A (Class IU) Sulfate (mg/L) 3640 NS NA 2/16/11 3730 NS NA 4/13/2011 3350 NS NA NS NA NS NA 8/11/2011 3560 NS NA 10/11/2011 5750 NS NA NS NA MW 3A (Class IU) TDS (mg/L) 5805 NS NA 5770 NS NA 5720 NS NA NS NA NS NA 5810 NS NA 5630 NS NA NS NA MW 3A (Class IU) Selenium (ug/L) 89 NS NA 99 NS NA 85 8 NS NA NS NA NS NA 88 5 NS NA 95 NS NA NS NA MW-5 (Class n) Uranium (ug/L) 75 NS NA 2/14/11 295 NS NA 4/12/2011 7 16 NS NA NS NA NS NA 8/9/2011 05 NS NA 10/10/2011 4 52 NS NA NS NA MW-12 (Class ni) Field pH (S U ) 65-85 NS NA 643 NS NA A IC I'^fW 1 6 67 NS NA NS NA NS NA 6 13 NS NA 1 A/£ /OA 1 1 6 7 (6 97) NS NA NS NA MW-12 (Class ni) Selenium (ug/L) 25 NS NA 2/15/11 39 NS NA 4/5/zUl 1 21 7 NS NA NS NA NS NA 8/9/2011 25 4 NS NA lU/6/2011 55* NS NA NS NA MW-15 Selenium (ug/L) 128 7 NS NA NA NS NA A11 'y /^A1 1 116 NS NA NS NA NS NA NS NA NS NA 1 A/1 A/OA 1 1 112 NS NA NS NA (Class UI) b-on (ug/L) 81 7 NS NA NS NA NS NA 4/lZ/iUl 1 <0 50 NS NA NS NA NS NA NS NA NS NA lU/lO/zUl 1 137 NS NA NS NA MW-18 Thallium (ug/l) 1 95 NS NA 3 49 NS NA 3 74 NS NA NS NA NS NA 40 339 NS NA 3 83 NS NA NS NA (Class IU) Sulfate (mg/L) 1938 9 NS NA 2/15/11 1770 NS NA 4/6/2011 1780 NS NA NS NA NS NA 8/10/2011 1910 NS NA 10/11/2011 2020 NS NA NS NA Field pH (S U ) 6 25-8 5 NS NA 6 27 NS NA 671 NS NA NS NA NS NA 9/21/11 5 95 NS NA 6 55 (6 63) NS NA NS NA TDS (mg/L) 3198 77 NS NA 3250 NS NA 5250 NS NA NS NA NS NA 3190 NS NA 5220 NS NA NS NA Ql 2011 Results Q2 2011 Results Q3 2011 Results Q4 2011 Results Monitonng Well (Water Class) Constituent Exceeding GWCL GWCLui Current GWDP January 2011 Monthly Sample Date January 2011 Monthly Sample Result Ql 2011 Sample Date Ql 2011 Result March 2011 Monthly Sample Date March 2011 Monthly Result Q2 2011 Sample Date Q2 2011 Result May 2011 Monthly Sample Date May 2011 Monthly Result June 2011 Monthly Sample Date June 2011 Monthly Result July 2011 Monthly Sample Date July 2011 Monthly Result Q3 2011 Sample Date Q32011 Result September 2011 Monthly Sample Date September 2011 Monthly Result Q4 20n Sample Date Q4 2011 Result November 2011 Monthly Sample Date November 2011 Monthly Result December 2011 Monthly Sample Date December 2011 Monthly Result Required Semi-Annual Sampling Wells, continued MW-19 (Class ni) Field pH (S U ) 6 78-8 5 NS NA 2/21/2011 6 78 NS NA 4/5/2011 7 03 NS NA NS NA NS NA 7/20/3011 6 65 NS NA 10/12/2011 6 88 (7 02) NS NA NS NA MW-19 (Class ni) Nitrate + Nitrite (as N) (mgA.) 2 83 NS NA 2/21/2011 NS NS NA 4/5/2011 26 NS NA NS NA NS NA 7/20/3011 NS NS NA 10/12/2011 40 NS NA NS NA MW-23 (Class IU) Field pH (S U ) 65-85 NS NA 2/9/2011 6.13 NS NA 4/5/2011 7 14 NS NA NS NA NS NA 8/4/2011 6 38 NS NA 10/6/2011 6 56 (6 77) NS NA NS NA MW-23 (Class IU) Manganese (ug/L) 550 NS NA 2/9/2011 NS NS NA 4/5/2011 32 NS NA NS NA NS NA 8/4/2011 NS NS NA 10/6/2011 55/ NS NA NS NA MW-24 (Class ni) Cadmium (ug/L) 25 NS NA 2/10/2011 2 78 NS NA 4/5/2011 2 61 NS NA NS NA NS NA 8/4/2011 1 46 NS NA 10/11/2011 1 78 NS NA NS NA MW-24 (Class ni) Thallium (ug/L) 1 NS NA 2/10/2011 142 NS NA 4/5/2011 107 NS NA NS NA NS NA 8/4/2011 <0 50 NS NA 10/11/2011 0 62 NS NA NS NA MW-24 (Class ni) Field pH (S U ) 65-85 NS NA 2/10/2011 5 75 NS NA 4/5/2011 612 NS NA NS NA NS NA 8/4/2011 6 45 NS NA 10/11/2011 644 NS NA NS NA MW-27 (Class m) Nitrate + Nitrite (as N) (mgA.) 56 NS NA 2/9/2011 6 NS NA 4/5/2011 64 NS NA NS NA NS NA 8/8/2011 6 NS NA 10/5/2011 63 NS NA NS NA MW-27 (Class m) Chloride (mg/L) 38 NS NA 2/9/2011 46 NS NA 4/5/2011 43 NS NA NS NA NS NA 8/8/2011 43 NS NA 10/5/2011 44 NS NA NS NA MW-27 (Class m) Sulfate (mg/L) 462 NS NA 2/9/2011 455 NS NA 4/5/2011 442 NS NA NS NA NS NA 8/8/2011 424 NS NA 10/5/2011 456 NS NA NS NA MW-27 (Class m) Field pH (S U ) 6 5-8 5 NS NA 2/9/2011 671 NS NA 4/5/2011 6 79 NS NA NS NA NS NA 8/8/2011 6 39 NS NA 10/5/2011 7 17 (7 24) NS NA NS NA MW-27 (Class m) TDS (mgA.) 1075 NS NA 2/9/2011 1090 NS NA 4/5/2011 1190 NS NA NS NA NS NA 8/8/2011 1090 NS NA 10/5/2011 1110 NS NA NS NA MW-27 (Class m) Gross Alpha minus Rn & U (pCi/L) 2 NS NA 2/9/2011 07 NS NA 4/5/2011 1 1 NS NA NS NA NS NA 8/8/2011 08 NS NA 10/5/2011 1 5 NS NA NS NA MW-28 (Class ni) Chlonde (mg/L) 105 NS NA 2/14/2011 114 NS NA 4/11/2011 109 NS NA NS NA NS NA 8/8/2011 105 NS NA 10/5/2011 143 NS NA NS NA MW-28 (Class ni) Manganese (ug/L) 1837 NS NA 2/14/2011 NA NS NA 4/11/2011 1690 NS NA NS NA NS NA 8/8/2011 NA NS NA 10/5/2011 1540 NS NA NS NA MW-28 (Class ni) Field pH (S U ) 6 1-85 NS NA 2/14/2011 5 69 NS NA 4/11/2011 6 01 NS NA NS NA NS NA 8/8/2011 5 7« NS NA 10/5/2011 507(6 M) NS NA NS NA MW-29 (Class III) Iron (ug/L) 1869 NS NA NS NA NS NA 4/18/2011 3010 NS NA NS NA NS NA 8/9/2011 1080 NS NA 10/5/2011 1220 NS NA NS NA MW-29 (Class III) Manganese (ug/L) 5624 NS NA NS NA NS NA 4/18/2011 4900 NS NA NS NA NS NA 8/9/2011 NA NS NA 10/5/2011 4800 NS NA NS NA MW-29 (Class III) IDS (mg/L) 4400 NS NA NS NA NS NA 4/18/2011 4080 NS NA NS NA NS NA 8/9/2011 NA NS NA 10/5/2011 4280 NS NA NS NA MW-29 (Class III) Field pH (S U ) 6 46 - 8 5 NS NA NS NA NS NA 4/18/2011 645 NS NA NS NA NS NA 8/9/2011 620 NS NA 10/5/2011 6 52 NS NA NS NA MW-32 (Class IU) Gross Alpha minus Rn & U (pCiA.) 3 33 NS NA 2/9/2011 1 5 NS NA 4/1/2011 46 NS NA NS NA NS NA 8/2/2011 8/30/11 1 9 NS NA 10/3/2011 57 NS NA NS NA MW-32 (Class IU) Field pH (S U ) 64-85 NS NA 2/9/2011 5 99 NS NA 4/1/2011 614 NS NA NS NA NS NA 8/2/2011 8/30/11 610 (620) NS NA 10/3/2011 6 35 NS NA NS NA Notes GWCL values are taken from July 14, 2011 version of GWDP NS = Not Requu-ed and Not Sampled NR = Required and Not Reported NA = Not Applicable Exceedances are shown in yellow Values m () parentheses are the field pH measurements for the resampled analyses Pursuant to the October 26 2011 DRC letter gross alpha monitoring m MW-26 returned to the routine frquency of quarterly These samples were inadvertantly coUected and are for information only Table 1 - GWCL Exceedances for Second Quarter 2012 under the July 14,2011 GWDP Ql 2012 Results Q2 2012 Results Monitonng Well (Water Class) Constituent Exceeding GWCL GWCL m July 14, 2011 GWDP January 2012 Monthly Sample Date January 2012 Monthly Result Ql 2012 Sample Date Ql 2012 Result March 2012 Monthly Sample Date March 2012 Monthly Result Apnl 2012 Monthly Sample Date April 2012 Monthly Result Q2 2012 Sample Date Q2 2012 Result June 2012 Monthly Sample Date June 2012 Monthly Result Sample Frequency Required Quarterly Sampling Wells MW-11 (Class 11) Manganese (ug/L) 131 29 102 154 121 /52 127 6/19/2012 122 1 Quarterly MW-11 (Class 11) Tetrahydrofuran 115 1/26/2012 <1 0 2/13/2012 251 3/13/2012 <1 0 4/10/2012 <1 0 5/8/2012 <1 0 6/19/2012 122 Quarterly MW-14 (Class ni) Manganese (ug/L) 2230 30 NA 1790 NA NA 2560 6/19/2012 NA Quarterly MW-14 (Class ni) Field pH (S U ) 65-85 1/24/2012 6 36 2/21/2012 6 57 3/14/2012 651 4/12/2012 6 97 5/9/2012 6 73 6/19/2012 6 90 Quarterly MW-25 (Class IU) Field pH (S U ) 65-85 1/25/2012 6 63 2/14/2012 6 83 3/14/2012 6 55 4/9/2012 6 58 5/2/2012 6 73 6/18/2012 6 99 Quarterly MW-25 (Class IU) Uranium 65 66 65 6 95 6 52 5/2/2012 5 90 6/18/2012 76 Quarterly MW-26 (Class UI) Nitrate + Nitrite (as N) (mgA.) 0 62 19 2/15/2012 12 5 34 29 6/19/2012 25 Quarterly MW-26 (Class UI) Uranium (ug/L) 41 8 646 2/21/2012 594 31 2 4/11/2012 42 2 5/7/2012 6/26/2012 18 2 6/19/2012 66 0 Quarterly MW-26 (Class UI) Chloroform (ug/L) 70 1900 2/15/2012 3300 2900 4/11/2012 2900 5/7/2012 6/26/2012 1700 6/19/2012 2400 Quarterly MW-26 (Class UI) Chloride (mg/L) 58 31 1/25/2012 68 2/15/2012 40 3/14/2012 74 4/11/2012 82 5/7/2012 6/26/2012 74 6/19/2012 85 Quarterly MW-26 (Class UI) Field pH (S U ) 6 74 - 8 5 1/25/2012 6 59 2/15/2012 2/21/2012 3/8/2012 6 72 (6 91) (6 71) 3/14/2012 6 39 4/11/2012 6 88 5/7/2012 6/26/2012 7 00(7 01) 6/19/2012 7 00 Quarterly MW-26 (Class UI) Dichloromethane (Methylene Chlonde) (UgA.) 5 1/25/2012 13 2/15/2012 24 3/14/2012 27 4/11/2012 20 5/7/2012 6/26/2012 10 6/19/2012 16 Quarterly MW-26 (Class UI) TDS (mg/L) 3284 19 1/25/2012 3250 2/15/2012 3150 3/14/2012 3220 4/11/2012 3140 5/7/2012 6/26/2012 3240 6/19/2012 3200 Quarterly MW-26 (Class UI) Gross Alpha minus Rn & U (pCi/L) 4 69 NS NA 2/21/2012 1 5 3/14/2012 4 4/11/2012 23 5/7/2012 6/26/2012 3 1 6/19/2012 NA Quarterly MW-30 (Class U) Nitrate + Nitrite (as N) (mgA.) 25 1/24/2012 17 2/14/2012 17 3/14/2012 18 4/10/2012 17 5/2/2012 16 6/18/2012 /5 0 Quarterly MW-30 (Class U) Chloride (mgA.) 128 1/24/2012 124 2/14/2012 126 3/14/2012 128 4/10/2012 128 5/2/2012 124 6/18/2012 131 (Quarterly MW-30 (Class U) Field pH (S U ) 65-85 1/24/2012 6 52 2/14/2012 7 12 3/14/2012 6 86 4/10/2012 7 66 5/2/2012 6 95 6/18/2012 7 10 Quarterly MW-30 (Class U) Uranium (ug/L) 8 32 NS NA 2/14/2012 7 42 3/14/2012 8 38 4/10/2012 7 84 5/2/2012 681 6/18/2012 78 Quarterly MW-30 (Class U) Selenium (ug/L) 34 1/24/2012 33 3 2/14/2012 55 3/14/2012 395 4/10/2012 59/ 5/2/2012 32 3 6/18/2012 57 Quarterly MW-31 (Class ni) Nitrate + Nitnte (as N) (mgA.) 5 1/24/2012 21 2/13/2012 21 3/13/2012 22 4/9/2012 21 5/2/2012 20 6/18/2012 6/29/2012 216 Quarterly MW-31 (Class ni) TDS (mg/L) 1320 1/24/2012 1360 2/13/2012 1240 3/13/2012 1400 4/9/2012 1380 5/2/2012 1410 6/18/2012 6/29/2012 1460 Quarterly MW-31 (Class ni) Chlonde (mg/L) 143 1/24/2012 155 2/13/2012 /50 3/13/2012 152 4/9/2012 160 5/2/2012 151 6/18/2012 6/29/2012 138 Quarterly MW-31 (Class ni) Field pH (S U ) 65-85 1/24/2012 6 78 2/13/2012 7 37 3/13/2012 7 13 4/9/2012 7 14 5/2/2012 7 19 6/18/2012 6/29/2012 7 28 7 63 Quarterly MW-31 (Class ni) Sulfate (mg/L) 532 1/24/2012 559 2/13/2012 55« 3/13/2012 517 4/9/2012 547 5/2/2012 532 6/18/2012 6/29/2012 497 Quarterly MW-35 (Class U) Manganese (ug/L) 200 1/24/2012 264 2/14/12 255 3/13/12 269 4/10/2012 277 5/2/2012 25« 6/19/2012 304 (Quarterly MW-35 (Class U) Thalbum (ugA) 05 1/24/2012 <050 2/14/12 0 65 3/13/12 0 71 4/10/2012 059 5/2/2012 066 6/19/2012 <0 50 Quarterly MW-35 (Class U) Gross Alpha minus Rn & U (pCi/L) 3 75 1/24/2012 65 2/14/12 41 3/13/12 62 4/10/2012 41 5/2/2012 45 6/19/2012 49 Quarterly MW-35 (Class U) Selenium (ug/L) 125 NS NA 2/14/12 19 7 NS NA 4/10/2012 NS 5/2/2012 114 6/19/2012 70 Quarterly MW-35 (Class U) Uranium (ug/L) 75 1/24/2012 161 2/14/12 24 7 3/13/12 24 9 4/10/2012 22 4 5/2/2012 22 2 6/19/2012 22 5 Quarterly Required Semi-Annual Sampling Wells MW-2 (Class UI) Gross Alpha minus Rn & U (pCi/L) 32 NS NA 2/22/2012 06 NS NA NS NA 5/9/2012 06 NS NA Semi-Annually MW-3 (Class IU) Selenium (ug/L) 37 NS NA 2/29/2012 431 NS NA NS NA 5/14/2012 52 « NS NA Semi-Annually MW-3 (Class IU) Field pH (S U ) 6 5-85 NS NA 2/29/2012 6 63 NS NA NS NA 5/14/2012 6 67 NS NA Semi-AnnuaUy MW-3 (Class IU) Fluonde (Mg/L) 0 68 NS NA 2/29/2012 0 86 NS NA NS NA 5/14/2012 104 NS NA Semi-Annually MW-3A (Class UI) Field pH (S U ) 65-85 NS NA 646 NS NA NS NA 5/15/2012 6 68 NS NA Semi-Annually MW-3A (Class UI) Sulfate (mg/L) 3640 NS NA 3/1/2012 3020 NS NA NS NA 5/15/2012 3220 NS NA Semi-Annually MW-3A (Class UI) TDS (mg/L) 5805 NS NA 5690 NS NA NS NA 5/15/2012 5730 NS NA Semi-Annually MW-3A (Class UI) Selenium (ug/L) 89 NS NA 65 8 NS NA NS NA 85 1 NS NA Semi-Annually MW-5 (Class n) Uranium (ug/L) 75 NS NA 2/28/2012 18 6 NS NA NS NA 5/9/2012 1 23 NS NA Semi-Annually Field pH (S U ) 65-85 NS NA 681 NS NA NS NA C / 1 A/OA 1 O 691 NS NA Semi-Annually MW-12 (Class 10) Selenium (ug/L) 25 NS NA 2/29/2012 272 NS NA NS NA 5/IU/2012 196 NS NA Semi-Annually K4\l/ 1 C ITr\ Selenium (ug/L) 128 7 NS NA o/oo /OA 1 O NA NS NA NS NA c /QA)A 1 O /52 NS NA Semi-Annually MW-IS (Class lU) b-on (ug/L) 81 7 NS NA 2/22/2012 <30 NS NA NS NA 5/y/2U12 <30 NS NA Semi-Annually Thalbum (ugA) 1 95 NS NA 5 65 NS NA NS NA 5 5/ NS NA Semi-Annually MW-18 (Class ni) Sulfate (mg/L) 19389 NS NA 2/27/2012 1920 NS NA NS NA 4/30/2012 1790 NS NA Semi-Annually Field pH (S U ) 6 25-8 S NS NA 66 NS NA NS NA 6 59 NS NA Semi-Annually TDS (mg/L) 3198 77 NS NA 5250 NS NA NS NA 52«0 NS NA Semi-Annually Ql 2012 Results | Monitonng Well (Water Class) Constituent Exceeding GWCL GWCL in Current GWDP January 2012 Monthly Sample Date January 2012 Monthly Result Ql 2012 Sample Date Ql 2012 Result March 2012 Monthly Sample Date March 2012 Monthly Result Apnl 2012 Monthly Sample Date Apnl 2012 Monthly Result Q2 2012 Sample Date Q2 2012 Result June 2012 Monthly Sample Date June 2012 Monthly Result Sample Frequency Required Senu-Annual Sampling Wells, contmued MW-19 (Class UI) Field pH (S U ) 6 78-8 5 NS NA 2/28/2012 6 83 NS NA NS NA 5/16/2012 6 86 NS NA Semi-Annually MW-19 (Class UI) Nitrate + Nitrite (as N) (mgA.) 2 83 NS NA 2/28/2012 59 NS NA NS NA 5/16/2012 5 7 NS NA Semi-Annually MW-23 (Class UI) Field pH (S U ) 65-85 NS NA 2/20/2012 661 NS NA NS NA 5/16/2012 6 74 NS NA Semi-Annually MW-23 (Class UI) Manganese (ug/L) 550 NS NA 2/20/2012 51 NS NA NS NA 5/16/2012 49 NS NA Semi-Annually MW-24 (Class HI) Cadmium (ug/L) 25 NS NA 2/23/2012 2 25 NS NA NS NA 5/10/2012 2 01 NS NA Semi-Annually MW-24 (Class HI) Thalbum (ug/L) 1 NS NA 2/23/2012 0 96 NS NA NS NA 5/10/2012 0 74 NS NA Semi-Annually MW-24 (Class HI) Field pH (S U ) 65-85 NS NA 2/23/2012 6 05 NS NA NS NA 5/10/2012 6 2/ NS NA Semi-Annually MW-27 (Class UI) Nitrate + Nitrite (as N) (mgA.) 56 NS NA 2/28/2012 6.4 NS NA NS NA 5/1/2012 62 NS NA Semi-/\nnually MW-27 (Class UI) Chlonde (mg/L) 38 NS NA 2/28/2012 45 NS NA NS NA 5/1/2012 46 NS NA Semi-Annually MW-27 (Class UI) Sulfate (mg/L) 462 NS NA 2/28/2012 451 NS NA NS NA 5/1/2012 446 NS NA Semi-Annually MW-27 (Class UI) Field pH (S U ) 6 5-8 5 NS NA 2/28/2012 7 24 NS NA NS NA 5/1/2012 7 03 NS NA Semi-Annually MW-27 (Class UI) TDS (mgA.) 1075 NS NA 2/28/2012 1140 NS NA NS NA 5/1/2012 1170 NS NA Semi-Annually MW-27 (Class UI) Gross Alpha minus Rn & U (pCi/L) 2 NS NA 2/28/2012 23 NS NA NS NA 5/1/2012 08 NS NA Semi-Annually MW-28 (Class UI) Chloride (mg/L) 105 NS NA 2/28/2012 109 NS NA NS NA 5/8/2012 114 NS NA Semi-Annually MW-28 (Class UI) Manganese (ug/L) 1837 NS NA 2/28/2012 NA NS NA NS NA 5/8/2012 1850 NS NA Semi-Annually MW-28 (Class UI) Field pH (S U) 6 1-85 NS NA 2/28/2012 6 22 NS NA NS NA 5/8/2012 6 15 NS NA Semi-/^nually MW-29 (Class UI) Iron (ug/L) 1869 NS NA 2/22/2012 1310 NS NA NS NA 5/8/2012 1400 NS NA Semi-Annually MW-29 (Class UI) Manganese (ug/L) 5624 NS NA 2/22/2012 NA NS NA NS NA 5/8/2012 6/40 NS NA Semi-Annually MW-29 (Class UI) TDS (mg/L) 4400 NS NA 2/22/2012 NA NS NA NS NA 5/8/2012 4600 NS NA Semi-Annually MW-29 (Class UI) Field pH (S U ) 6 46 - 8 5 NS NA 2/22/2012 7 12 NS NA NS NA 5/8/2012 6 47 NS NA Semi-Annually MW-32 (Class UI) Gross Alpha mmus Rn & U (pCiA.) 3 33 NS NA 2/21/2012 1 8 NS NA NS NA 4/30/2012 24 NS NA Semi-Annually MW-32 (Class UI) Field pH (S U ) 64-85 NS NA 2/21/2012 6 57 NS NA NS NA 4/30/2012 640 NS NA Semi-Annually Notes GWCL values are taken from February 15, 2011 version of GWDP NS = Not Requu-ed and Not Sampled NR = Required and Not Reported NA = Not Applicable Exceedances are shown in yellow Values in () parentheses are the field pH measurements for the resampled analyses Pursuant to the October 26 2011 DRC letter gross alpha monitonng m MW-26 retumed to the rouune frquency of quarterly These samples were inadvertantly collected and are for information only