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HomeMy WebLinkAboutDRC-2011-007854 - 0901a068802b1561State of Utah GARYR HERBERT Governor GREG BELL Lieutenant Governor TO FROM Department of Environmental Quality Amanda Smith Executive Director DPv'ISlON OF RADIATION CONTROL Rusty Lundberg Director Phil Goble DATE Dean Henderson August 31 2011 SUBJECT Comparing the Uranium Concentration Results Between USGS Seeps and Springs Samples and DUSA Seeps and Spnngs Samples in the Vicinity of the White Mesa Mill near Blanding Utah The USGS did a report called Assessment of Potential Uranium Emissions from a Uranium Mill on Water Sediments and Plants Located near the Ute Mountain Ute Reservation Utah (hereafter Report) In one section of this Report the USGS summarized m a graph total uranium distnbution in water from wells and springs that they sampled in the area surrounding the DUSA White Mesa Mill The springs that the USGS sampled included Entrance Westwater Cottonwood and Ruin which are spnngs that DUSA samplings To compare results DUSA uranium sample results are hand marked in red on a copy of the graph that the USGS used to summanze their uranium results (see Attachment 1) In comparing results it should be noted that the USGS analyzed for total uranium and DUSA has analyzed for dissolved uranium It appears results are similar between Rum (DUSA 8 11 pg/1 and USGS 10 pg/1) and Cottonwood spnngs (DUSA 4 - 8 pg/1 and USGS 10 pg/1) The DUSA results for the Westwater Spnng are 15 and 46 \igl\ where the USGS results are lower ranging between 2 to 11 pg/1 The DUSA results for the Entrance Sprmg are 15 2 and 17 8 pg/1 where the USGS results are higher ranging between 25 to 55 |Lig/l (see DUSA seeps and spnngs sample results m tables 1 5 m Attachment 2) The possible reasons for the different sample results are 1) dissolved (DUSA) vs total (USGS) uranium analysis 2) sampling procedures and 3) different laboratones 195 North 1950 West Salt Lake City UT Mailing Address PO Box 144850 Salt Lake City UT 84114 4850 Telephone (801) 536 4250 Fax (801) 533 4097 TDD (801)536 4414 wwwd q 1 h n Pr ted o 1009' y led p p Page 2 Attachment 1 USGS Uranium Distribution m Water Graph USGS Uliiiiuifi science for a changing world jort Iir Water V'/-. Oasis-Sprmg JA- : ;*4 a Bayless Well . r;-/.i,;;-^:^-, ,-^^.^?'tVman Weil I Mill Spring CowlGsimp Spring WM West Well .^f^^- . Entrance-;S^pring;jp^ ' South.MiflsSe^ .]| Pohd A ^A^.: AA'-^-Mi'-' -'-"- -ff^^lj ; WM East \Ai[eff - i^i /ri/J'^Anasazi'PohftFs-.!^^ North QQ Lii CL CO < Q. < O 70 60 50 40 30 20 10 0 South EPA Drinking Water MCL 4 . 4 4 A ^ .4 £ 4^ 4^ <^ ^\<r ^ 4 Page 3 f V Attachment 2 DUSA Sample Results Tables for Seeps and Springs Table 1 Summary of Seeps and Sprmgs Analytical Data 2010 Cottonwood Contaminant GWCL Canyon Spnng Enterance Spt •mg Rum Spnngs Westwater Spring Parameters Listed m Table 2 July? 2010 July 6 2010 July? 2010 Julys 2010 Nutrients (mg/L) Ammonia (as N) 25 <0 05 <0 05 <0 05 0 05 Nitrate + Nitnte (as N) 10 <01 1 1 7 <01 Heavy Metals (pg/L) Arsenic 50 <5 <5 <5 <5 Beryllium 4 <0 5 <0 5 <0 5 <0 5 Cadmium 5 <0 5 <0 5 <0 5 <0 5 Chromium 100 <25 <25 <25 <25 Cobalt 730 <10 <10 <10 <10 Copper 1 300 <10 <10 <10 <10 Iron 11 000 <30 <30 <30 56 Lead 15 <1 <1 <1 <1 Manganese 800 <10 11 <10 87 Mercury 2 <0 5 <0 5 <0 5 <0 5 Molybdenum 40 <10 <10 17 29 Nickel 100 <20 <20 <20 <20 Selenium 50 <5 92 10 <5 Silver 100 <10 <10 <10 <10 Thallium 2 <0 5 <0 5 <0 5 <0 5 Tin 17 000 <100 <100 <100 <100 Uranium 30 8 24 178 8 47 46 6 Vanadium 60 <15 <15 <15 <15 Zinc 5 000 <10 <10 <10 <10 Radiologics (pCi/L) Gross Alpha 15 <0 2 <0 5 <0 2 <0 3 VOC ((jg/L) Acetone 700 <20 <20 <20 <20 Benzene 5 <1 0 <1 0 <1 0 <1 0 2 Butanone (MEK) 4 000 <20 <20 <20 <20 Carbon Tetrachlonde 5 <1 0 <1 0 <1 0 <1 0 Chloroform 70 <1 0 <1 0 <1 0 <1 0 Chloromethane 30 <1 0 <1 0 <1 0 <1 0 Dichloromethane 5 <1 0 <1 0 <1 0 <1 0 Naphthalene 100 <1 0 <1 0 <1 0 <1 0 ^Tetrahydrofuran (THF) 46 <1 0 <1 0 <1 0 <1 0 Toluene 1 000 <1 0 <1 0 <1 0 <1 0 Xylenes (total) 10 000 <1 0 <1 0 <1 0 <1 0 Others Field pH (S U ) 65 85 7 47 7 56 7 51 7 38 Fluoride (mg/L) 4 0 38 0 73 0 53 06 Chloride (mg/L) NG 112 63 23 40 Sulfate (mg/L) NG 389 179 447 607 TDS (mg/L) NG 900 661 1 010 1 270 General Inorganics Listed m Part 1 E 1 (c)(2)(ii) Carbonate (mg/L) NG <1 <1 <1 <1 Bicarbonate (mg/L) NG 340 332 254 450 Sodium (mg/L) NG 214 62 7 93 4 160 Potassium (mg/L) NG 5 77 2 74 3 07 6 57 Magnesium (mg/L) NG 24 8 28 9 29 7 44 7 Calcium (mg/L) NG 92 2 96 5 136 179 Total anions (meq/L) NG 167 103 157 22 3 Total cations (meq/L) NG 156 9 47 148 21 8 1 THF sampled on November 3 2010 NG = No GWCL Shaded = exceeded GWCL Table 2 Contaminant GWCL Sampling Event Parameters Listed in Table 2 ^ 7/25/1977 Ml/10/1977 7/9/2009 July? 2010 Nutrients (mg/L) Ammonia (as N) 25 -013 <01 <0 05 <0 05 Nitrate + Nitrite (as N) 10 0 06 0 26 01 <0 1 Heavy Metals (pg/L) Arsenic 50 ^<10 NA <0 05 <5 Beryllium 4 NA NA 01 <0 5 Cadmium 5 ^4 '2 <0 5 <0 5 Chromium 100 "^20 ^<10 <25 <25 Cobalt 730 NA NA <10 <10 Copper 1 300 ^5 ^<5 <10 <10 Iron 11 000 3 200 110 <30 <30 Lead 15 ^30 •^<50 <1 <1 Manganese 800 1100 60 <10 <10 Mercury 2 ^2 <0 5 <0 5 Molybdenum 40 <10 NA <10 <10 Nickel 100 NA NA <20 <20 Selenium 50 140 NA <5 <5 Sliver 100 4 NA <10 <10 Thallium 2 NA NA <0 5 <0 5 Tin 17 000 NA NA <100 <100 Uranium 30 4 NA 8 42 8 24 Vanadium 60 6 <10 <15 <15 Zinc 5 000 60 150 <10 <10 Radiologics (pCi/L) Gross Alpha 15 10 2±3 1 NA <0 8 02 VOC (ug/L) Acetone 700 NA NA <20 <20 Benzene 5 NA NA <1 0 <1 0 2 Butanone (MEK) 4 000 NA NA <20 <20 Carbon Tetrachloride 5 NA NA <1 0 <1 0 Chloroform 70 NA NA <1 0 <1 0 Chloromethane 30 NA NA <1 0 <1 0 Dichloromethane 5 NA NA <1 0 <1 0 Naphthalene 100 NA NA <1 0 <1 0 Tetrahydrofuran (THF) 46 NA NA <1 0 ^<10 Toluene 1 000 NA NA <1 0 <1 0 Xylenes (total) 10 000 NA NA <1 0 <1 0 Others Field pH (S U ) 65 85 70 81 73 7 47 Fluonde (mg/L) 4 1 05 04 0 38 Chloride (mg/L) NG 1 71 124 112 Sulfate (mg/L) NG 333 243 383 389 TDS (mg/L) NG 1270 780 1 010 900 General Inorganics Listed in Part 1 E 1 (c)(2)(ii) Carbonate (mg/L) NG 0 0 <1 <1 Bicarbonate (mg/L) NG NA NA 316 340 Sodium (mg/L) NG 400 115 205 214 Potassium (mg/L) NG 66 43 57 5 77 Magnesium (mg/L) NG 19 28 25 24 8 Calcium (mg/L) NG 58 133 90 3 92 2 Totai anions (meq/L) NG NA NA 167 22 3 Total cations (meq/L) NG NA NA 156 21 8 1 Dames and Moore January 30 1978 2 THF sampled on November 3 2010 NG = No GWCL T - indicates metals analyzed as totals Environmental Report White Mesa Uraium Project San Juan County Utah Energy Fuels Inc Table 3 Contaminant GWCL Monitonng Events Parameters Listed in Table 2 Julys 2009 July 6, 2010 Nutnents (mg/L) Ammonia (as N) 25 0 28 <0 05 Nitrate + Nitnte (as N) 10 1 4 1 Heavy Metals (pg/ L) Arsenic 50 <5 <5 Beryllium 4 <0 5 <0 5 Cadmium 5 <0 5 <0 5 Chromium 100 <25 <25 Cobalt 730 <10 <10 Copper 1 300 <10 <10 Iron 11 000 <30 <30 Lead 15 <1 <1 Manganese 800 54 11 Mercury 2 <0 5 <0 5 Molybdenum 40 <10 <10 Nickel 100 <20 <20 Selenium 50 12 1 92 Silver 100 <10 <10 Thallium 2 <0 5 <0 5 Tin 17 000 <100 <100 Uranium 30 152 178 Vanadium 60 <15 <15 Zinc 5 000 <10 <10 Radiologics (pCi/ L) Gross Alpha 15 <0 8 <0 5 VOC (pg/L) Acetone 700 <20 <20 Benzene 5 <1 0 <1 0 2 Butanone (MEK) 4 000 <20 <20 Carbon Tetrachlonde 5 <1 0 <1 0 Chloroform 70 <1 0 <1 0 Chloromethane 30 <1 0 <1 0 Dichloromethane 5 <1 0 <1 0 Naphthalene 100 <1 0 <1 0 Tetrahydrofuran (THF) 46 <1 0 ^<10 Toluene 1 000 <1 0 <1 0 Xylenes (total) 10 000 <1 0 <1 0 Others Field pH (S U ) 65 85 7 64 7 56 Fluonde (mg/L) 4 07 0 73 Chlonde (mg/L) NG 60 63 Sulfate (mg/L) NG 178 179 TDS (mg/L) NG 605 661 General inorganics Listed in Part 1 E 1 (c)(2)(ii) Carbonate (mg/L) NG <1 <1 Bicarbonate (mg/L) NG 292 332 Sodium (mg/L) NG 61 4 62 7 Potassium (mg/L) NG 24 2 74 Magnesium (mg/L) NG 26 6 28 9 Calcium (mg/L) NG 90 8 96 5 Total anions (meq/L) NG 103 103 Total cations (meq/L) NG 9 47 9 47 NG = No GWCL 1 THF sampled on November 3 2010 Table 4 Historic Ruin Spring Concentrations Contammant Sampling Events Parameters Listed in Table 2 GWCL 7/25/1977 3/28/2003 6/5/2003 8/29/2003 11/11/2003 3/15/2004 4/20/2004 8/13/2004 9/27/2004 7/9/2009 7/7/10 Nutrients (mg/L) Ammonia (as N) 25 0 1 0 05 1 5 0 05 0 05 0 05 06 0 05 0 06 0 09 0 05 Nitrate + Nitnte (as N) 10 2 77 1 6 0 05 1 4 1 4 1 7 1 8 1 34 1 7 1 4 1 7 Heavy Metals (pgA.) Arsenic 50 NA 1 1 1 1 1 1 1 1 5 5 Beryllium 4 NA 10 <10 10 10 10 10 <10 10 05 05 Cadmium 5 4 5 5 5 5 5 5 <5 5 05 <0 5 Ch omium 100 100 50 50 50 50 50 50 50 50 <25 25 Cobalt 730 NA NA NA NA NA NA NA NA NA 10 10 Copper 1 300 5 10 10 82 10 10 10 10 10 10 10 Iron 11000 20 50 50 50 50 50 50 <50 <50 30 30 Lead 15 50 50 50 50 50 50 50 <50 50 <1 <1 Manganese 800 5 10 10 <10 10 10 10 <10 10 10 <10 Mercury 2 5 1 1 1 1 <1 1 1 1 05 05 Molybdenum 40 NA 100 100 <100 <100 100 100 100 100 17 17 Nckel 100 NA 50 50 50 <50 50 50 <50 50 20 <20 Selenium 50 NA 13 12 12 12 12 12 12 12 122 10 SIver 100 NA 1 1 <1 1 1 1 1 1 10 10 Thall um 2 NA 1 <1 1 1 1 <1 1 1 05 05 Tin 17 000 NA NA NA NA NA NA NA NA NA 100 <100 Uran um 30 NA 9 11 10 10 11 11 9 10 9 11 8 47 Vanadium 60 10 100 100 100 100 100 100 <100 100 15 15 Znc 5 000 15 14 10 10 10 10 10 <10 10 10 10 Radiologics (pCi/L) Gross Alpha 15|NA NA NA NA 10 <1 0 10 14 10 1 08 03 VOC (pg/L) Acetone 700 NA NA NA NA NA NA NA NA NA 20 <20 Benzene 5 NA NA NA NA NA NA NA NA NA 1 0 1 0 2 Butanone (MEK) 4 000 NA NA NA NA NA NA NA NA NA 20 <20 Carbon Tetrachlor de 5 NA NA NA NA NA NA NA NA NA <1 0 1 0 Chloroform 70 NA NA NA NA NA NA NA NA NA 1 0 1 0 Chloromethane 30 NA NA NA NA NA NA NA NA NA 1 0 1 0 Dichloromethane 5 NA NA NA NA NA NA NA NA NA 1 0 1 0 Naphthale e 100 NA NA NA NA NA NA NA NA NA 1 0 1 0 Tetrahydrofuran (THF) 46 NA NA NA NA NA NA NA NA NA 1 0 1 0 Toluene 1 000 NA NA NA NA NA NA NA NA NA 1 0 1 0 Xylenes (total) 10 000 NA NA NA NA NA NA NA NA NA 1 0 1 0 Others FeldpH (SU) 65 85 78 NA NA 7 91 7 98 NA NA NA NA 7 45 7 51 Fluoride (mg/L) 4 06 NA NA 06 05 05 06 06 06 05 0 53 Chlo Ide (mg/L) NG 25 28 1 21 5 27 4 28 29 3 28 5 26 25 28 23 Sulfate (mg/L) NG 472 503 501 495 506 539 468 544 613 528 447 TDS (mg/L) NG 975 NA NA 1040 1000 1050 1110 1050 1070 1 010 1 010 General Inorganics Listed in Part 1E 1 (c)(2)( ) Carbonate (mg/L) NG 0 NA 1 1 1 1 1 1 1 1 B carbonate (mg/L) NG NA NA NA 239 241 235 232 238 223 233 254 Sodium (mg/L) NG 200 110 105 103 113 104 110 113 116 104 93 4 Potass um (mg/L) NG 28 26 33 33 39 34 36 4 37 33 3 07 Magnesium (mg/L) NG 265 34 8 34 2 31 7 342 35 8 35 1 37 1 38 6 32 3 29 7 Calc um (mg/L) NG 375 153 156 149 158 158 162 176 186 151 136 Total an o s (meq/L) NG NA NA NA NA NA NA NA NA NA 15 7 157 Total cat ons (meq/L) NG NA NA NA NA NA NA NA NA NA 148 14 8 1Dm dMneJ ry30 1978 E m t IR p rtWht M U mP 1 ts J C ty Ut h E rgyF 1 1 2 THFsampl d N NA N 1 ly d NG N GWCL T d t th m tal mb 3 2010 lyzed t t I Table 5 Contaminant GWCL Monitoring Event Parameters Listed in Table 2 November 18, 2009 Julys 2010 N utrients (mg/L) Ammonia (as N) 25 <0 05 0 05 Nitrate + Nitrite (as N) 10 08 <01 Heavy Metals (pg/L) Arsenic 50 <5 <5 Beryllium 4 <0 5 <0 5 Cadmium 5 <0 5 <0 5 Chromium 100 <25 <25 Cobalt 730 <10 <10 Copper 1 300 <10 <10 Iron 11 000 <30 56 Lead 15 <1 <1 Manganese 800 37 87 Mercury 2 <0 5 <0 5 Molybdenum Nickel 40 100 <10 <20 <20 29 Selenium 50 <5 <5 Silver 100 <10 <10 Thallium 2 <0 5 <0 5 Tin 17 000 <100 <100 Uranium 30 15 1 46 6 Vanadium 60 <15 <15 Zmc 5 000 <10 <10 Radiologics (pCi/L) Gross Alpha 15 <0 6 <0 3 VOC (pg/L) Acetone 700 <20 <20 Benzene 5 <1 0 <1 0 2 Butanone (MEK) 4 000 <20 <20 Carbon Tetrachlonde 5 <1 0 <1 0 Chloroform 70 <1 0 <1 0 Chloromethane 30 <1 0 <1 0 Dichloromethane 5 <1 0 <1 0 Naphthalene 100 <1 0 <1 0 Tetrahydrofuran (THF) Toluene 46 1 000 <1 0 <1 0 '<^o <1 0 Xylenes (total) 10 000 <1 0 <1 0 Others Field pH (S U ) 65 85 8 01 7 38 Fluonde (mg/L) 4 07 06 Chloride (mg/L) NG 41 40 Sulfate (mg/L) NG 646 607 TDS (mg/L) NG 1 370 1 270 General Inorganics Listed in Part 1 E 1 (c)(2)(ii) Carbonate (mg/L) NG <5 <1 Bicarbonate (mg/L) NG 465 450 Sodium (mg/L) NG 195 160 Potassium (mg/L) NG 24 6 57 Magnesium (mg/L) Calcium (mg/L) NG NG 26 6 191 44 7 179 Total anions (meq/L) Total cations (meq/L) NG NG 22 3 21 8 22 3 21 8 1 THF sampled on November 3 2010 NG = No GWQS Shaded = exceeded GWCL