Loading...
HomeMy WebLinkAboutDRC-2009-006626 - 0901a06880151202J:)i>C. - J-LC<( CO ^i^^/. Page 1 of 1 Sonja Robinson - Revised minutes for March 31, 2009 meeting between Denison Mines, DRC, and MWH concerning White Mesa ICTM From: "Douglas Oliver Jr." <Douglas.S.01iver@us.mwhglobal.com> To: Loren Morton <LMORTON@utah.gov> Date: 11/18/2009 12:40 PM Subject: Revised minutes for March 31, 2009 meeting between Denison Mines, DRC, and MWH concerning White Mesa ICTM CC: Thomas Rushing ii <TRUSHING@utah.gov>, David Frydenlund <DFr}'denlund@denisonmines.com>, Harold Roberts <HRobens@denisonmines.com> Attachments: Minutes for 31 Mar09 meeting revised 18Nov09.docx; Minutes for 31 Mar09 meetingrevised 18Nov09 redlined version.docx Loren, At Dave Frydenlund's request, I am sending you the revised minutes for the March 31, 2009 meeting between Denison Mines, DRC, and MWH concerning the White Mesa Infiltration and Contaminant Transport Model (ICTM). Draft minutes were originally submitted to the DRC on April 23, 2009. The attached revised minutes reflect changes that were made in response to DRC's comments sent to Denison on April 28, 2009 by Tom Rushing. I have included both a final copy and a redlined version of the minutes so you can readily see the changes we made. Ifyou have any questions or comments, please contact Dave Frydenlund. Thanks, Doug Douglass. Oliver, P.G. Principal Hydrogeologist MWH Americas, Inc. 10619 South Jordan Gateway, Ste. 100 SaltLakeCity, UT 84095 email: douRlas.ollver(S>mwhelobal.com Phone: 801-617-3224 Fax; 801-617-4224 This e-ma>l is intended for exclusive use the person(s) mentioned as the recipient(s). This message and any attached files with it are confidential and may contain privileged or propneiary informaiion If you are not the intended recipient(s) please delete thrs message and notify the sender. Vou may not use. distribute prim or copy this message if you are nol the intended fecipient{s). file:/.C:\Documents and Settings\Sdrobinson\Local Settings\Temp\XPgrpwise\4B05259BE... 12/9/2009 1 MINUTES FROM MEETING WITH UTAH DIVISION OF RADIATION CONTROL (DRC) TO DISCUSS COMMENTS ON THE WHITE MESA INFILTRATION AND CONTAMINANT TRANSPORT MODELING REPORT Date: March 31, 2009 Time: l:00-6:00pm MDT Location: Utah DRC Office (168 North, 1950 West, Salt Lake City, Utah) Attendees: Utah DRC: Loren Morton and Thomas Rushing Denison Mines (USA) Corp: Harold Roberts and Dave Frydenlund MWH Americas: Doug Oliver, Ryan Jakubowski and Phil Crouse The purpose of the meeting was to discuss the DRC's comments (dated February 2, 2009) on the Infiltration and Contaminant Transport Modeling (ICTM) Report that was prepared by MWH for Denison and submitted to the DRC in November 2007. These minutes are intended to summarize the primary discussions and key decisions made during the meeting. The order of items presented in this summary is not necessarily in the order discussed at the meeting. DISCUSSION ITEMS Background MWH presented an overview of the project including: • Site description • Project background / permit requirements • Timeline • Modeling overview Many of the DRC's comments were discussed during this presentation. Key Issues Based on their review of the ICTM Report, the DRC identified the following list of "key" issues: 1. Vegetation details to support the proposed evapotranspiration (ET) cover. 2. Sorption and retardation of contaminants of concern. 3. Source term concentrations for tailings fluids. 4. Modeling of potential leakage through liners. 2 5. Coupling of models and how output from one model is input into the next model. 6. Effects of storm intensity, ponding, and 2-D effects of runon/runoff on infiltration through the ET cover. 7. Cell 1. Primary matters discussed and decisions made regarding these key issues are presented below. ET Cover Design and Vegetation The cover design as presented in the ICTM Report was preliminary and conceptual in nature. The ET concept was adopted because it is more effective than the conventional cover proposed in the reclamation plan. The Ground Water Discharge Permit specifically allowed for design changes to improve cover performance. After the modeling is completed, the cover design and reclamation plan can be revised, but the modeling should come first. The cover can be engineered to meet the required performance standards. The ICTM will be based on site-specific data where possible, and will rely on literature values where necessary (Note: since the time of this meeting, additional site-specific data have been collected). The DRC will review all final engineering designs and materials specifications to ensure conformance with the modeled performance capabilities. The DRC would like the report to include additional details concerning the vegetation such as the proposed seed mix (plant species). Details that need to be justified and supported for the modeling include rooting depth and root density distribution, percent cover, vegetation density and LAI (leaf area index). Other considerations include soil properties (e.g., soil types, salinity, organic content), longevity and competition with woody species. A sensitivity analysis should be performed on vegetation parameters to evaluate the effects these have on the model results. The DRC raised the need for cited references from botanists and range scientists and the sensitivity analysis needs to simulate long-term vegetation establishment (Note: the September 2, 2009 meeting involved extensive discussion concerning long-term vegetation establishment, which will be incorporated in the revised ICTM report). Sorption and Retardation The results of the materials testing (soil-water characteristic curves) need to be discussed in more detail in the Report. Specifically, the Report needs to describe the samples that were used and why these sample locations were selected and what they represent in the model. During the meeting, MWH presented a simplified cross section showing the sample locations relative to the tailings cells. This figure will be added to the ICTM Report. In regard to sorption and retardation, MWH provided DRC with the NRC/USGS reference NUREG/CR-6820 (Davis and Curtis, 2003) which describes the approach used to calculate sorption and retardation for the uranium mill tailings site at Naturita. The NRC/USGS reference also describes a methodology used to measure the mass of HFO (hydrous ferric oxide). We incorporated a similar approach for White Mesa. The 3 amount of ANP (acid neutralizing potential) and methodology used to measure the ANP were discussed. The DRC was concerned that there was not enough ANP and HFO data to adequately represent the distribution in the vadose zone. Furthermore, the DRC thought that the ANP values (which are relatively low), don't appear to match the geochemical modeling that shows significant acid neutralization. During the meeting it was noted that MWH will look into this. Following the meeting we noted that this discrepancy may be explained by the normalization procedure incorporated as part of the PHREEQC modeling. Options to consider include: • collecting more HFO and ANP data to better represent vadose zone materials, or • doing a sensitivity analysis (reduce sorption by one or more orders of magnitude) to evaluate the effects of this uncertainty/variability on the model results. The geochemical modeling used to calculate the sorption coefficients needs to be described more clearly in the Report (details were provided in Appendix B). The Report needs to state the prerequisite geochemical conditions necessary for sorption onto HFO (e.g., pH ranges and resulting effects on sorption). Tom suggested collecting samples and doing batch sorption tests with tailings fluids to corroborate values calculated with HFO data (Note: This was discussed in more detail in the September 2, 2009 meeting). Source Term Chemistry The source term concentrations for tailings fluids used in the model were discussed. The DRC would like a statistical analysis performed on the data. Denison collected and analyzed tailings fluids in 2007 and 2008 to address questions regarding mill process water (DRC has not received this data because the data were collected for internal purposes). Data from the University of Utah study were not used in this modeling effort because the University of Utah study was not published until 2008, while the ICTM report was submitted in 2007. A sensitivity analysis will be performed with different source terms to evaluate the effects of source concentrations on the overall predictions. Modeling of Potential Leakage Through Liner MWH discussed the approach used to model potential leakage through the liner. MWH described the pseudo layer that was required in HYDRUS in order to simulate leakage through the HDPE and PVC liners. The Giroud and Bonaparte method was used to calculate leakage for a given head through the liner. The hydraulic conductivity was adjusted in the pseudo layer until the flux was matched using the same head as was used in the Giroud and Bonaparte calculations. These calculations need to be included in the report (appendix). Given that the model considers the PVC and HDPE liners to be thin 4 for modeling purposes (30 mil and 60 mil, respectively) and have extremely low hydraulic conductivity, the large contrasts in hydraulic conductivity over short distances, would cause the model to be unstable and the solution would not converge. As a result, a thicker layer (“pseudo layer”) with higher hydraulic conductivity was assumed. The layer thickness used was 30 cm, but this was arbitrary. This layer could be any thickness, but there is a corresponding hydraulic conductivity that is required for a given thickness to match the calculated flux for a given head. As the thickness of the pseudo layer is increased, the corresponding hydraulic conductivity must be increased to match the flux for a given head on the liner. This layer was assumed to include no sorption so as not to retard contaminants. (Note: As discussed in the September 2, 2009 meeting, we decided to model leakage through the liners differently, and as a result, this pseudo layer is no longer in the model). Coupling of Models MWH presented an overview of the modeling approach and linkage of models. The DRC would like to see the modeling approach streamlined/simplified, if possible. This would make it easier for DRC to explain to the public that the model results are conservative, protective, and robust. A flow chart will be added to the Report to clarify the purpose of each model and how the inputs and outputs are related/coupled. Different models were required because there is no single model that can simulate all required processes. Furthermore, the different time- scales that act on different parts of the system resulted in much greater efficiency by modeling the distinct parts of the system separately (e.g., cover model requires extremely short time steps while the vadose zone model has longer time steps). Models that were used simply to develop initial conditions (e.g., initial soil moisture distribution of the tailings and bedrock vadose zone) will be moved to the appendices of the report to improve readability. The report should clearly state how the output of one model is used as the input to the next. Another way to simplify the modeling would be to assume steady-state (average) flux rates into the tailings as input into the lower HYDRUS model of the tailings/cell liner/bedrock vadose zone. The sensitivity analysis needs to be expanded to determine the parameters that are most sensitive. This work should be documented in the appendices to keep the body of the report streamlined. Effects of Storm Intensity, Ponding, and Runon/Runoff The effects of storm intensity, ponding, and 2-D/3-D effects of runon/runoff on infiltration were discussed. The Report must explain why a 1-D model is sufficient rather than a 2-D or 3-D model. A series of sensitivity runs were discussed to evaluate storm intensity and ponding. To test storm intensity, a short period of time should be modeled with hourly (or less) precipitation and compared to the same precipitation entered as a daily value (as we have it 5 modeled). The water content and flux at specific nodes in the profile can be used to compare the results. To evaluate ponding, a similar analysis can be performed. The results of these sensitivity tests should be documented and included in the appendices. Cell 1 Currently the plan is to place D&D materials from the decommissioning of the mill in Cell 1. However, these materials could be placed in Cell 4A or 4B. Prior to placing the D&D materials, the liner and any contaminated underlay (foundation) material from Cell 1 would be removed and placed in Cell 4A or 4B. A rad survey (with field instrumentation and lab data for correlation) would be completed and any contamination remaining would be remediated with the end goal being clean closure (soil cleanup standard based on radium-226 and natural uranium). The Cell 1 area would be opened to the west for surface water drainage. Then the 10-acre area on the southern side of Cell 1, adjacent to the Cell 2 berm, would be lined with compacted clay. The D&D materials (dry) would be placed on the clay liner and covered with an ET cover (extension of the cap that will extend across the other cells). This needs to be included in the ICTM Report and can be modeled by simulating Cell 1 with relatively dry tailings and a clay liner. We could assume that the material would behave as a high permeability porous media (e.g., sand) at a concentration equivalent to the values used for the tailings. We could vary the initial moisture content (i.e., -500 cm to -5,000 cm) as part of the sensitivity analysis. Because the purpose of this model is to evaluate the effectiveness of the cover for the closure period, the current pond in Cell 1 will not be simulated. Other Items Discussed The operational phase was not included in the HYDRUS simulations because the purpose of the infiltration and contaminant transport modeling was to evaluate the effectiveness of the cover. However, including the operational phase in the modeling was discussed. The operational phase includes the period that the cells were in operation prior to closure, which is assumed to run from 1980 (startup of Cell 2) through 2016 (completion of Cell 4B filling). This may affect water and contaminant fluxes through the vadose zone and to groundwater. After the operational period, an additional 200 years will be simulated following closure of the cells. The slimes drains in Cells 2 and 3 are "burrito drains", meaning sand has been placed in an envelope over the drains, rather than in a continuous layer across the bottom of the tailing cells. The 1-ft thick sand layer in the MODFLOW model did not extend across the entire tailing cell area, but did cover the entire 400 ft by 600 ft drain area. The MODFLOW model will be modified to simulate the drain system more accurately. PATH FORWARD We agreed that the path forward would involve preparing these minutes summarizing the meeting (issues discussed and path forward/actions) and a draft response to the DRC's comments. For comments that require additional work, the draft response can simply include a statement as to how we will address the comment. 6 MWH will submit meeting minutes and a draft response to Denison in one week, then Denison will submit these to DRC on April 23 (which date was later extended to April 30 for the draft response). We will have conference calls to discuss any items that are not clear in our responses, rather than going back and forth with formal letters. Once DRC agrees on our responses, we can revise the responses and submit a final response. The ICTM Report will then be revised in accordance with the final response. 1 MINUTES FROM MEETING WITH UTAH DIVISION OF RADIATION CONTROL (DRC) TO DISCUSS COMMENTS ON THE WHITE MESA INFILTRATION AND CONTAMINANT TRANSPORT MODELING REPORT Date: March 31, 2009 Time: l:00-6:00pm MDT Location: Utah DRC Office (168 North, 1950 West, Salt Lake City, Utah) Attendees: Utah DRC: Loren Morton and Thomas Rushing Denison Mines (USA) Corp: Harold Roberts and Dave Frydenlund MWH Americas: Doug Oliver, Ryan Jakubowski and Phil Crouse The purpose of the meeting was to discuss the DRC's comments (dated February 2, 2009) on the Infiltration and Contaminant Transport Modeling (ICTM) Report that was prepared by MWH for Denison and submitted to the DRC in November 2007. These minutes are intended to summarize the primary discussions and key decisions made during the meeting. The order of items presented in this summary is not necessarily in the order discussed at the meeting. DISCUSSION ITEMS Background MWH presented an overview of the project including: • Site description • Project background / permit requirements • Timeline • Modeling overview Many of the DRC's comments were discussed during this presentation. Key Issues Based on their review of the ICTM Report, the DRC identified the following list of "key" issues: 1. Vegetation details to support the proposed evapotranspiration (ET) cover. 2. Sorption and retardation of contaminants of concern. 3. Source term concentrations for tailings fluids. 4. Modeling of potential leakage through liners. 2 5. Coupling of models and how output from one model is input into the next model. 6. Effects of storm intensity, ponding, and 2-D effects of runon/runoff on infiltration through the ET cover. 7. Cell 1. Primary matters discussed and decisions made regarding these key issues are presented below. ET Cover Design and Vegetation The cover design as presented in the ICTM Report was preliminary and conceptual in nature. The ET concept was adopted because it is more effective than the conventional cover proposed in the reclamation plan. The Ground Water Discharge Permit specifically allowed for design changes to improve cover performance. After the modeling is completed, the cover design and reclamation plan can be revised, but the modeling should come first. The cover can be engineered to meet the required performance standards. The ICTM will be based on site-specific data where possible, and will rely on literature values where necessary (Note: since the time of this meeting, additional site-specific data have been collected). The DRC will review all final engineering designs and materials specifications to ensure conformance with the modeled performance capabilities. The DRC would like the report to include additional details concerning the vegetation such as the proposed seed mix (plant species). Details that need to be justified and supported for the modeling include rooting depth and root density distribution, percent cover, vegetation density and LAI (leaf area index). Other considerations include soil properties (e.g., soil types, salinity, organic content), longevity and competition with woody species. A sensitivity analysis should be performed on vegetation parameters to evaluate the effects these have on the model results. The DRC raised the need for cited references from botanists and range scientists and the sensitivity analysis needs to simulate long-term vegetation establishment (Note: the September 2, 2009 meeting involved extensive discussion concerning long-term vegetation establishment, which will be incorporated in the revised ICTM report). Sorption and Retardation The results of the materials testing (soil-water characteristic curves) need to be discussed in more detail in the Report. Specifically, the Report needs to describe the samples that were used and why these sample locations were selected and what they represent in the model. During the meeting, MWH presented a simplified cross section showing the sample locations relative to the tailings cells. This figure will be added to the ICTM Report. In regard to sorption and retardation, MWH provided DRC with the NRC/USGS reference NUREG/CR-6820 (Davis and Curtis, 2003) which describes the approach used to calculate sorption and retardation for the uranium mill tailings site at Naturita. The NRC/USGS reference also describes a methodology used to measure the mass of HFO (hydrous ferric oxide). We incorporated a similar approach for White Mesa. The 3 amount of ANP (acid neutralizing potential) and methodology used to measure the ANP were discussed. The DRC was concerned that there was not enough ANP and HFO data to adequately represent the distribution in the vadose zone. Furthermore, the DRC thought that the ANP values (which are relatively low), don't appear to match the geochemical modeling that shows significant acid neutralization. During the meeting it was noted that MWH will look into this. Following the meeting we noted that this discrepancy may be explained by the normalization procedure incorporated as part of the PHREEQC modeling. Options to consider include: • collecting more HFO and ANP data to better represent vadose zone materials, or • doing a sensitivity analysis (reduce sorption by one or more orders of magnitude) to evaluate the effects of this uncertainty/variability on the model results. The geochemical modeling used to calculate the sorption coefficients needs to be described more clearly in the Report (details were provided in Appendix B). The Report needs to state the prerequisite geochemical conditions necessary for sorption onto HFO (e.g., pH ranges and resulting effects on sorption). Tom suggested collecting samples and doing batch sorption tests with tailings fluids to corroborate values calculated with HFO data (Note: This was discussed in more detail in the September 2, 2009 meeting). Source Term Chemistry The source term concentrations for tailings fluids used in the model were discussed. The DRC would like a statistical analysis performed on the data. Denison collected and analyzed tailings fluids in 2007 and 2008 to address questions regarding mill process water (DRC has not received this data because the data were collected for internal purposes). Data from the University of Utah study were not used in this modeling effort because the University of Utah study was not published until 2008, while the ICTM report was submitted in 2007. A sensitivity analysis will be performed with different source terms to evaluate the effects of source concentrations on the overall predictions. Modeling of Potential Leakage Through Liner MWH discussed the approach used to model potential leakage through the liner. MWH described the pseudo layer that was required in HYDRUS in order to simulate leakage through the HDPE and PVC liners. The Giroud and Bonaparte method was used to calculate leakage for a given head through the liner. The hydraulic conductivity was adjusted in the pseudo layer until the flux was matched using the same head as was used in the Giroud and Bonaparte calculations. These calculations need to be included in the report (appendix). Given that the model considers the PVC and HDPE liners to be thin 4 for modeling purposes (30 mil and 60 mil, respectively) and have extremely low hydraulic conductivity, the large contrasts in hydraulic conductivity over short distances, would cause the model to be unstable and the solution would not converge. As a result, a thicker layer (“pseudo layer”) with higher hydraulic conductivity was assumed. The layer thickness used was 30 cm, but this was arbitrary. This layer could be any thickness, but there is a corresponding hydraulic conductivity that is required for a given thickness to match the calculated flux for a given head. As the thickness of the pseudo layer is increased, the corresponding hydraulic conductivity must be increased to match the flux for a given head on the liner. This layer was assumed to include no sorption so as not to retard contaminants. (Note: As discussed in the September 2, 2009 meeting, we decided to model leakage through the liners differently, and as a result, this pseudo layer is no longer in the model). Coupling of Models MWH presented an overview of the modeling approach and linkage of models. The DRC would like to see the modeling approach streamlined/simplified, if possible. This would make it easier for DRC to explain to the public that the model results are conservative, protective, and robust. A flow chart will be added to the Report to clarify the purpose of each model and how the inputs and outputs are related/coupled. Different models were required because there is no single model that can simulate all required processes. Furthermore, the different time- scales that act on different parts of the system resulted in much greater efficiency by modeling the distinct parts of the system separately (e.g., cover model requires extremely short time steps while the vadose zone model has longer time steps). Models that were used simply to develop initial conditions (e.g., initial soil moisture distribution of the tailings and bedrock vadose zone) will be moved to the appendices of the report to improve readability. The report should clearly state how the output of one model is used as the input to the next. Another way to simplify the modeling would be to assume steady-state (average) flux rates into the tailings as input into the lower HYDRUS model of the tailings/cell liner/bedrock vadose zone. The sensitivity analysis needs to be expanded to determine the parameters that are most sensitive. This work should be documented in the appendices to keep the body of the report streamlined. Effects of Storm Intensity, Ponding, and Runon/Runoff The effects of storm intensity, ponding, and 2-D/3-D effects of runon/runoff on infiltration were discussed. The Report must explain why a 1-D model is sufficient rather than a 2-D or 3-D model. A series of sensitivity runs were discussed to evaluate storm intensity and ponding. To test storm intensity, a short period of time should be modeled with hourly (or less) precipitation and compared to the same precipitation entered as a daily value (as we have it 5 modeled). The water content and flux at specific nodes in the profile can be used to compare the results. To evaluate ponding, a similar analysis can be performed. The results of these sensitivity tests should be documented and included in the appendices. Cell 1 Currently the plan is to place D&D materials from the decommissioning of the mill in Cell 1. However, these materials could be placed in Cell 4A or 4B. Prior to placing the D&D materials, the liner and any contaminated underlay (foundation) material from Cell 1 would be removed and placed in Cell 4A or 4B. A rad survey (with field instrumentation and lab data for correlation) would be completed and any contamination remaining would be remediated with the end goal being clean closure (soil cleanup standard based on radium-226 and natural uranium). The Cell 1 area would be opened to the west for surface water drainage. Then the 10-acre area on the southern side of Cell 1, adjacent to the Cell 2 berm, would be lined with compacted clay. The D&D materials (dry) would be placed on the clay liner and covered with an ET cover (extension of the cap that will extend across the other cells). This needs to be included in the ICTM Report and can be modeled by simulating Cell 1 with relatively dry tailings and a clay liner. We could assume that the material would behave as a high permeability porous media (e.g., sand) at a concentration equivalent to the values used for the tailings. We could vary the initial moisture content (i.e., -500 cm to -5,000 cm) as part of the sensitivity analysis. Because the purpose of this model is to evaluate the effectiveness of the cover for the closure period, the current pond in Cell 1 will not be simulated. Other Items Discussed The operational phase was not included in the HYDRUS simulations because the purpose of the infiltration and contaminant transport modeling was to evaluate the effectiveness of the cover. However, including the operational phase in the modeling was discussed. The operational phase includes the period that the cells were in operation prior to closure, which is assumed to run from 1980 (startup of Cell 2) through 2016 (completion of Cell 4B filling). This may affect water and contaminant fluxes through the vadose zone and to groundwater. After the operational period, an additional 200 years will be simulated following closure of the cells. The slimes drains in Cells 2 and 3 are "burrito drains", meaning sand has been placed in an envelope over the drains, rather than in a continuous layer across the bottom of the tailing cells. The 1-ft thick sand layer in the MODFLOW model did not extend across the entire tailing cell area, but did cover the entire 400 ft by 600 ft drain area. The MODFLOW model will be modified to simulate the drain system more accurately. PATH FORWARD We agreed that the path forward would involve preparing these minutes summarizing the meeting (issues discussed and path forward/actions) and a draft response to the DRC's comments. For comments that require additional work, the draft response can simply include a statement as to how we will address the comment. Deleted: This will be addressed in the response. 6 MWH will submit meeting minutes and a draft response to Denison in one week, then Denison will submit these to DRC on April 23 (which date was later extended to April 30 for the draft response). We will have conference calls to discuss any items that are not clear in our responses, rather than going back and forth with formal letters. Once DRC agrees on our responses, we can revise the responses and submit a final response. The ICTM Report will then be revised in accordance with the final response.