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HomeMy WebLinkAboutDRC-2008-002321 - 0901a0688081d041State of Utah JON M. HUNTSMAN, JR. Governor GARY HERBERT Lieutenant Governor Certified Mail Department of Environmental Quality Richard W. Sprott Executive Direaor DIVISION OF RADIATION CONTROL Dane L. Finerfrock Director October 9, 2008 rotatposrase&Fe* l$ I rrtI, Eo lfl E,ITITr\- EE,trtrI tr rjlrlEf rLtrIE,rL [q.!;fl :rif ^:tilTrii{j*tiffi T*.#if.*f iii;mr;r ffi,H$;rt:,$ffi ffi ',iai',^, (Return Receipt Requested)Stra?'Afi:'N6::--- o, po e[i'ill" sia;,'27iF;,i Mr. David C. Frydenlund Vice hesident and General Counsel Denison Mines (USA) CorP. (DUSA) 1050 Seventeenth St. Suite 950 Denver, Colorado, 80265 2od Quarter, 2008 DUSA Groundwater Monitoring Report: Ground Water Quality Discharge Permit UGW370004: DRC Findings, Notice of Enforcement Discretion, and Request For Information. Dear Mr. Frydenlund: On Septemb er 2,2008,the Utah Division of Radiation Control (DRC) received the 2"d Quarter (April - June) 2008 Groundwater Monitoring Report (2'd Quarter 2008 Report). After review of the 2od Quarter 200d Report for the Denison Mines (USA) Corp. (DUSA) White Mesa Uranium Mill near Blanding, Utah, the following issues were identified: Additional Monitoring Not Reported as Required In Tab B of the 2nd Quarter 2008 Report, it shows that DUSA collected a groundwater sample from monitoring well MW-4 on May 27 ,2OOB at 15:05. Included in Tab G of the 2'd Quarter 2008 Report, Chain of Custody forms sent to Energy Labs and American West Analytical Labs requested analysis of samples from will MW4. No results of these analyses were included in the 2no Quarter 2008Report'.-." Since MW-4 is a chloroform investigation well, the 2'd Quarter 2008 Chloroform Monitoring Report (2'o Quarter Chloroform Report) was also reviewed to see if the resu_lts were included in that report' The MW- dsamples collected on iuluy 27 ,2008 were not included in the 2'd Quarter Chloroform Report. Although MW-4 was not required to be sampled under the Permit, additional monitoring is required to be submitted under Part II.F of the Permit, as follows: ADDTT17NAL MONTO1ryG By THE PERMITTEE. lf the permittee monitors any pollutant more frequently than required. by this permit, using approved test procedures as specified in this permit, the results of this monitoring shali be included in the calculation and reporting of the data submitted. Such increased frequency skall also be indicated. 168 North 1950 West'Salt I-ake City' UT Mailing Address: P.O. Box 144850 ' Salt I-ake City, UT 84114-4850 Telephone (801 ) 536-4250' Fax (80 l -533-4097' T.D.D. (801 ) 536-441 4 \!wre.deq.utah.gov Printed on 100% recYcled PaPer r Complete items 1, 2, and 3. Also complete item 4 if Restricted Delivery is desired.r Print your name and address on the reverse so that we can return the card to you.r Attach this card to the back of the mailpiece, or on the front if space permits. 1. Article Addrcssed to:D. 'ls delivery address different fiom item lf YES, enter delivery address below: E Agent B Addressee 4. Restricted OelVen/? (m' Fae) E ye (lnnsfer from sellca laf€ll)l ?EE? E?1I] EBEE ?11t] 585? 2. &ticle Number PS Form 381 1, feOruary zOoa Domestlc Retum Receipt 1@59SO2-fvl-.|54O ; UrurrEo SrRres Posrn SeRvrce ilil1 First-Class Mail Postage & Fees Paid USPS Permit No. G-10 ' Sender: Please print your name, address, and ZIP+4 in this box ' D EPT O F ENV' f, O N M EN rAf.. A U A L ITYo,tltstoM OF n,AptaTtav ctiwrnatt68 Atf?Pilt 'tsfil WEST :, - - PO Bo.X t448fi .;- IALT L.AKE ctw ur euwq&b^ o\-.U1o - ^r, r,Y"':i'l 99'', ' '.d ii,,i,,l''l,,,li,,,li,l,,l,i'll,,i,,l,l,li',,,i'i,ii,,,il,,,l Mr. Frydenlund October 9, 2008 Page 2 Notice of Enforcement Discretion Although it appears that DUSA has inappropriately withheld the results of the groundwatff samples in well I\rIW-4 collected on May 27,2008, the Executive Secretary has determined to use enforcement discretion in this matter, based on: 1. DUSA will provide documentation that it canceled the analysis for the MW4 groundwater sample collected on May 27,2008, ot 2. DUSA will remit the MW-4 results for the groundwater sample collected on May 27 ,2008 within l0 calendar days ofreceipt ofthis letter. Samples Received by Laboratory at Temperature Greater than Approved Temperature (4"C) Improper sample preservation was provided during the April, May, and June 2008 groundwater monitoring evdnts, in that, groundwater samples were received by the analytical laboratory at temperatures greater than the 4"C for VOCs. As stated in Section 9.3(d) of the QAP, non-conformance is defined when a satnple temperature is exceeded for a constituent. These temperature exceedances are in violation of Sections 9.3(d) and 10.1(a) of the QAP, and Parts LE.1(a) and tr.A of the Permit. This is a continuing violation, previously cited in the January 11, February 28, April 1, and August 4, 2008 DRC NOVs. On July 3, 2008 DUSA notified the DRC (by phone) that two sets of samples were received and accepted by its analytical laboratory at temperatures greater than the maximum allowed temperature of 4'C for .VOCs. These two sets of samples were received at 5'C and 6oC for the April and May, 2008 accelerated monitoring events, respectively. In a July 7 , 2008 Notice Pursuant to R3 17-6-6. 13, DUSA argued that Affirmative Defense set out in Part LG.3(c) of the Permit should be applicable to these temperature exceedances for the following reasons: 1. DUSA submittpd verbal notification of the temperature exceedances on July 3, 2008 and written notification on July 7,2008 according to UAC-R317-6-6.13 2. The failure was not intentional or caused by Permitee negligence, either in action or in failure to act, The Permittee has taken adequate measures to meet Permit conditions in a timely matter or has submitted to the Executive Secretary, for the Executive Secretary's approval, and adequate plan and schedule for meeting Permit conditions, and Provisions of UAC l9-5-l}7 have not been violated. The DRC advised in an August 1, 2008 letter that DUSA had met three of the four items needed to meet Affirmative Defense. Although, DUSA described in great detail the steps they have or will take to fix the sample temperatue problems, DUSA failed to provide the DRC with a schedule or date when it would be back in compliance. Without a schedule by which compliance will be regained, DUSA failed to meet the terms of Affirmative Defense. Although, DUSA failed to meet all the criteria for Affirmative Defense in the July 7, 2008 submittal, the DRC concluded that DUSA still could submit a date whereby compliance for future samples will be regained. In a September 4, 2008 submittal, DUSA determined that the root cause of past temperature problems were not solely due to the failure to use "5-day" coolers, as originally proposed by DUSA, but was due to a number of factors: J. 4. Mr. Frydenlund October 9,2008 Page 3 o Failure to use regular ice, rather than "blue ice" o Failure to ensure that there is a proper ratio of ice to sample volume o Failure to collect samples on a schedule that minimizes sample transit time from the Mill to the analytical laboratory r Failure to use "5-day coolers" in all circumstances o Failure to schedule sampling events and identify sample temperature problems early enough in the sampling period to allow re-sampling during the period, if necessary As a result of this analysis, DUSA claims it has changed its sampling practices, effective August 1, 2008, as follows: . "5-day" coolers will be used in all circumstances to transport groundwater samples o DUSA will use regular ice as a coolant o Ensure there is a proper ratio of ice to sample volume in each cooler o Collect samples early in the week, so that the samples will be received by the analytical laboratory on a business day and will not sit in transit over the weekend o Collect samples as early in each sampling period as is reasonably practicable, in order to allow for re-sampling during the period if necessary. Contact the analytical laboratory upon scheduled receipt of the samples to ensure that they have been received by the lab within the requisite temperature range If samples are not received by the analytical laboratory within the required temperature range, the samples will be re-collected during the same period and the new samples will be submitted to the analytical laboratory for analysis Notice of Enforcement Discretion The Executive Secretary has decided to use enforcement discretion in this matter, in that the April, May, and June 2008 samples received by the analytical laboratory were above the requisite temperature but were collected prior to the DUSA commitment that all future groundwater samples, starting on August 1, 2008 will be received by the analytical laboratory at or below sample temperature requirements. As a result, the DRC will not pursue enforcement for the April - June temperature problems at this time, but will give DUSA the benefit of doubt that it has "solved" the temperature problem. Please ensure that compliance is achieved and maintained so as to avoid escalated enforcement action in the future. Thank you for your cooperation in this matter. If you have any questions or comments regarding this letter, please contact Phil Goble at (801) 5364044. Sincerely, UTAH WATER QUALITY BOARD Dane L. Finerftdck DLF/PRG:prg State of Utah JON M. HUNTSMAN, JR. Govemor GARY HERBERT Lieutenant Governor IDepartment ot Environmental Quality Richard W. Sprott Executive Director DIVISION OF RADIATION CONTROL Dane L. Finerfrock Director MEMORANDUM DATE: SUBJECT:August 29,2008 DUSA 2'd Quarter, 2008 Routine Groundwater Monitoring Report Groundwater Discharge Permit (Permit) UG370004 Denison Mines (USA) Corp. (DUSA) White Mesa Mill, Blanding, Utah This is a summary of the 2nd Quarter (April - June) 2008 sampling event and all accelerated monitoring events during the 2nd Quarter as documented in the August 29,2008 DUSA Report, cited above. After review of this report, DRC staff findings are as follows: 1) The DUSA 2'd Quarter 2008 Groundwater Monitoring Report (2nd Quarter 2008 Report) was received by the DRC by its respective due date (September 1, 2008). 2) DUSA samples received by the analytical laboratory for the April, May, and June, 2008 monitoring events failed to meet sample preservation requirements, in that they arrived above the approved temperature for VOCs. 3) DUSA failed to submit results for additional monitoring it conducted, as required by the Permit. 4) Certain QA/QC sample data problems are apparent. 5) Summary of the apparent violations is also provided below. 1.0 Accelerated Monitoring and POC Wells Exceeding GWCL When a monitoring well has a pollutant that exceeds a GWCL set forth in Table 2 of the Permit it is in Probable Out of Compliance (POOC) status. DUSA is then required to immediately initiate accelerated sampling of that pollutant (see Permit, Part I.G.1). When monitoring wells have parameters that have exceeded the GWCL two or more consecutive times they may be: in Out of Compliance (OOC) status if the contaminant concentration also exceeds the mean and second standard deviation, or statistically significantly higher as determined by some EPA guidance (see Permit, Part I.G.2). However, in a NOV dated August24,2006, the DRC decided a parameter had to exceed the Ground Water Quality Standard (GWQS) set forth in Table 2 of the Permit for two or more consecutive times to be in OOC status. This process will continue until the Background Groundwater Quality Reports submitted on December 29,2006 and May 31,2007) has been approved by the DRC. In the tables listed below are monitoring wells with parameters currently in POOC (normal font) or OOC (in bold and italics) status. 168 North 1950 West. Salt l,ake City, UT Mailing Address: P.O. Box 1,t4850 . Salt Lake City. UT 84114-4850 Telephone (801 ) 536-4250 . Fax (80 l -533-4097 . T.D.D. (801 ) 536-44 I 4 www.deq.utah. gov Printed on 1007o recycled paper I LorenMorton 4# phir Gobre re6 October 6, 2008 Page2 Wells Monitored Accelerated to Monthly Monitori Well Class *Position Parameter Date of First Exceedance of GWOS/GWCL Date Accelerated Monitoring First Reouired MW-14 Class III water D4A manganese uranium March 2005 March 2005 April2005 Anril2005 Ivtw-26 Class III water CF-P, C-2 chloroform dichloromethane manganese uranium March 2005 June 2005 March 2005 March 2005 April2005 July 2005 April2005 April2005 MW-32 Class III water c-2 cadmium+ gross alpha+ iron manganese nickel March 2005 March 2007 March 2005 March 2005 March 2005 April2005 April2007 April2005 April2005 April2005 *D=Down-gradient; U=Up-gradient; C=Cross-gradient; CF-P=chloroformpumpingwell;1,2,3,4A= Cell # + = Well/parameters not in excess of their respective GWCL in 2"d Quarter, 2008 Wells Monitored Semi-annually Accelerated to Quarterly Monitoring Well Class *Position Parameter Date of First Exceedance of GWQS/GWCL Date Accelerated Monitoring First Required MW-1 Class II water u-1 manganese+ THF+ 4" Quarter 2005 2'd Quarter 2005 1" Quarter 2006 3'd Quarter 2005 MW-3 Class III water D-4A manganese selenium thallium+ TTIF+ uranium 4* Quarter 2005 2'd Quarter 2006 3'd Quarter 2005 3'd Quarter 2006 3'd Ouarter 2005 1" Quarter 2006 3'd Quarter 2006 4fr Quarter 2005 4fr Quarter 2006 4ft Ouarter 2005 MW-5 Class II water D-3 fluoride+ manganese THF+ 2"'Quarter 2005 2'd Quarter 2@5 4ft Ouarter 2005 3'" Quarter 2005 3'd Quarter 2005 l't Ouarter 2006 MW-12 Class III water D-3 THF+ uranium 2"o Quarter 2005 2nd Ouarter 2005 3" Quarter 2005 3'd Ouarter 2005 MW-15 Class III water D-4A selenium uranium 2'" Quarter 2005 2'd Ouarter 2005 3'" Quarter 2005 3'd Ouarter 2005 MW-17 Class III water C-4A uramum 2"" Ouarter 2005 3'" Ouarter 2005 MW-18 Class II water u-l manganese+ thallium uranium 4"'Quarter 2007 2'd Quarter 2005 2nd ouarter 2oo5 1" Quarter 2008 3'd Quarter 2005 3'd Ouarter 2005 MW-19 Class II water u-l fluoride selenium+ thallium+ uranium+ 4"'Quarter 2005 2'd Quarter 2005 4e Quarter 2005 2nd Ouarter 2005 l" Quarter 2006 3'd Quarter 2005 l't Quarter 2006 3'd Ouarter 2005 * D = Down-gradient; U = Up-gradient; C = Cross-gradient; 1,2,3,4A = Cell # + = Well/parameters not in excess of their respective GWCL in 2"d Quarter, 2008 Page 3 Some of the parameters listed were not found to be in excess of their respective GWCL during the 2n Quarter,2008 monitoring events. The following wells have parameters currently in POOC or OOC status that did not exceed theiriespective GWCL (last time parameter above GWCL in parenthesis) during the 2"d Quarter, 2008 sampling events: o MW-l: Manganese (1" Qtr 2007) andTHF (4m Qtr 2007) o MW-3: TIIF (3'd Qtr 2006) and Thallium (3'd Qtr 2oo7) o MW-5: TI{F (4d'Qtr 2005) and Fluoride (1" Qtr 2008) o MW-12: TIIF (l't Qtr 2007) o MW-l8: Manganese (4n'Qtr 2007)o MW-19: Selenium (1't Qtr 2006),Thallium (1$ Qtr 2008), and Uranium (4h Qtr 2007) o MW-32: Cadmium (July 2007) and Gross Alpha (February 2008) 2.0 Samples Received by Laboratory at Temperature Greater than Approved Temperature Improper sample preservation was provided during the April, May, and June 2008 groundwater monitoring events, in that, groundwater samples were received by the analytical laboratory at temperatures greater than the 4'C for VOCs. For details see Table 1, below. As stated in Section 9.3(d) of the QAP, non- conformance is defined when a sample temperature is exceeded for a constituent. These temperature exceedances are in violation of Sections 9.3(d) and 10.1(a) of the QAP, and Parts I.E.1(a) and II.A of the Permit. This is a continuing violation, previously cited in the January 11, February 28, April l, and August 4,2008 DRC NOVS Laboratoable l. Groundwater Sam ture Arrival At Sampling Event (Date Collected) Date and Temp ('C) of Samples Received bv Laboratory Samples Where Temperature Reouirements were Exceeded April29, 2008 (5t2t2008) 5 MW-26, MW-60 May 13-14,2008 6,n6t200$ 6 MW-26, MW-60 June 16-18,2008 (2nd Quarter) (6t20t2w8) 6.5 MW-5, MW-11, MW-12, MW-14, MW- 1 5, MW-20, MW -22, IvrW-75 On July 3, 2008 DUSA notified the DRC (by phone) that two sets of samples were received and accepted by its analytical laboratory at temperatures greater than the maximum allowed temperature of 4oC for VOCs. These two sets of samples were received at 5"C and 6oC for the April and May, 2008 accelerated monitoring events, respectively. In a July 7 ,2008 Notice Pursuant to R317-6-6.13, DUSA argued that Affirmative Defense set out in Part I.G.3(c) of the Permit should be applicable to these temperature exceedances for the following reasons: L DUSA submitted verbal notification of the temperature exceedances on July 3, 2008 and written notification on July 7 , 2008 according to UAC-R3 17 -6-6.13 The failure was not intentional or caused by Permitee negligence, either in action or in failure to act, The Permittee has taken adequate measures to meet Permit conditions in a timely matter or has submitted to the Executive Secretary, for the Executive Secretary's approval, and adequate plan and schedule for meeting Permit conditions, and Provisions of UAC 19-5-107 have not been violated. The DRC advised in an August l, 2008 letter that DUSA had met three of the four items needed to meet Affirmative Defense. Although, DUSA described in great detail the steps they have or will take to fix the sample temperature problems, DUSA failed to provide the DRC with a schedule or date when it would be 2. 4. Page 4 back in compliance. Without a schedule by which compliance will be regained, DUSA fails to meet the terms of Affirmative Defense. Although, DUSA failed to meet all the criteria for Affirmative Defense in the July 7,2008 submittal, the DRC concluded that DUSA still could submit a date whereby compliance for future samples will be regained. In a Septemb er 4,2008 submittal, DUSA determined that the root cause of past temperature problems were not solely due to the failure to use "5-day" coolers, as originally proposed by DUSA, but was due to a number of factors: a a a Failure to use regular ice, rather than "blue ice" Failure to ensure that there is a proper ratio of ice to sample volume Failure to collect samples on a schedule that minimizes sample transit time from the Mill to the analytical laboratory Failure to use "5-day coolers" in all circumstances Failure to schedule sampling events and identify sample temperature problems early enough in the sampling period to allow re-sampling during the period, if necessary a a As a result of this analysis, DUSA claims it has changed its sampling practices, effective August 1, 2008, as follows: a a a a o'5-day" coolers will be used in all circumstances to transport groundwater samples DUSA will use regular ice as a coolant Ensure there is a proper ratio of ice to sample volume in each cooler Collect samples early in the week, so that the samples will be received by the analytical laboratory on a business day and will not sit in transit over the weekend Collect samples as early in each sampling period as is reasonably practicable, in order to allow for re-sampling during the period if necessary. Contact the analytical laboratory upon scheduled receipt of the samples to ensure that they have been received by the lab within the requisite temperature range If samples are not received by the analytical laboratory within the required temperature range, the samples will be re-collected during the same period and the new samples will be submitted to the analytical laboratory for analysis DUSA claims it has implemented these new practices effective August 1, 2008. Therefore, it is recommended that the DRC not pursue a Notice of Violation for the April - June temperature problems at this time, but give DUSA the benefit of doubt that it has "solved" the temperature problem. However, if DUSA fails to submit groundwater samples to the analytical laboratory less than the requisite temperature, the Executive Secretary should pursue other enforcement options. 3.0 Additional Monitoring Not Reported as Required In Tab B of the 2od Quarter 2008 Report, a field worksheet shows that DUSA collected a groundwater sample from monitoring well MW-4 on May 27,2008 at 15:05. Included in Tab G of the 2'd Quarter 2008 Report, MW-4 also appears on both Chain of Custody forms sent to Energy Labs and American West Analytical Labs requesting analysis. No results of these analyses were included in the 2'd Quarter 2008 Report. Since MW4 is a chloroform investigation well, the 2nd Quarter 2008 Chloroform Monitoring Report (2nd Quarter Chloroform Report) was also reviewed to see if the results were included in that report. The MW-4 samples collected on May 27,2008 were not included in the 2nd Quarter Chloroform Report. Although MW-4 was not required to be sampled under the Permit, additional monitoring is required to be submitted under Part II.F of the Permit, as follows: Page 5 ADDITI1NALM)NIT1RING By rHE PERMITw. If the permittee monitors any pollutant more frequently than required by this permit, using approved test procedures as specified in this permit, the results of this monitoring, shall be included in the calculation and reporting of the data submitted. Such increased frequency shall also be indicated. Although it appears that DUSA has inappropriately withheld the results of the groundwater samples in well MW-4 collected on May 27,2008, DRC staff recommends that the Executive Secretary use enforcement discretion in this matter, based on: l. Allow DUSA to provide documentation that it canceled the analysis for the MW4 groundwater sample collected on May 27,2008, or 2. Allow DUSA to provide the MW-4 results for the groundwater sample collected on May 27,2008 within 10 calendar days of receipt of a Notice of Enforcement Discretion Letter. 4.0 Previous Monitoring Events QA/QC Sdmple Data Problems QA/QC problems found in the l't Quarter, 2008 groundwater monitoring events showed a number of issues in non-compliance with the DUSA QAP (for details see July 23,2008 DRC Memo). These antecedent problems included: During the January and February 2008 sampling events, TIIF was not analyzed for monitoring well MW-26 as required. This was a violation of Part I.E.1(dX2) and Part I.G.l(b)of the Permit. During the March 2008 monitoring event, DUSA failed to meet sample preservation requirements, in that they arrived at the analytical laboratory above the maximum temperature of 4oC for several constituents (sea 8/4/08 DRC NOV). These sample temperature exceedances were a violation of Section 9.3(d) of the QAP and Part I.E.4(a) of the Permit (see August 4,2008 DRC NOV, Violation No. 1). During the February and March,2007 monitoring events, Relative Percent Difference (RPD) was greater than 20Vo in original sample compared to the duplicate sample for several constituents. These QA/QC problems were in violation of Section 9.1.4(a) of the QAP. The DRC policy when dealing with RPD is as followed (see 1/10/08 DRC Letter, p.2 and 4): When DUSA submits an original and duplicate sample to the DRC for reporting purposes, the DRC will use the sample with the highest concentration submitted to determine compliance. Starting with the submittal of the 4ft Quarter 2007 Groundwater Report, DUSA will be required to provide documentation for each RPD calculation used during its review of analytical reports in a spreadsheet to be included in each groundwater report submitted to the DRC. 5.0 2nd Quarter 200S QA/QC Sample Data Problems The following are QA/QC problems that occurred in the monitoring events during the 2nd Quarter, 2008. The issues listed below are in non-compliance with the QAP and details can be found in Table 4 attached to this memo. May 14, 2008 Accelerated Monitoring Event (Table 4) o The field blank (MW-60) had detectable concentrations of chloroform. o The field blank (MW-60) was also analyzed for heavy metals, VOCs, and gross alpha. According to the QAP, DUSA is not required to collect a field blank. However, if DUSA wants to collect a 1) 2) Page 6 field blank for in house QA/QC, the DRC has no problem with it as long as they don't use the field blank results to flag or disqualify the groundwater sample results. 2nd Ouarter 2008. Sampling Date: May 27 - June 18. 2008 (Table 4) o The field blank (IvtW-60) had detectable concentrations of nitrate + nitrite (as N), chloroform, fluoride, chloride, TDS, bicarbonate, sodium, potassium, magnesium, and calcium. o The field blank (MW-60) was also analyzed for nutrients, heavy metals, gross alpha, VOCs, and inorganics. According to the QAP, DUSA is not required to collect a field blank. However, if DUSA wants to collect a field blank for in house QA/QC, the DRC has no problem with it as long as they don't use the field blank results to flag or disqualify the groundwater sample results. o Relative Percent Difference was greater than207o in original sample (MW-5, 84 pglL) compared to duplicate sample (MW-75, 58 pglL) for iron (36.62Vo), see Table 4. This is in violation of Section 9.1.4(a) of the QAP. When DUSA submits an original and duplicate sample to the DRC for reporting purposes, the DRC will use the sample with the highest concentration submitted to determine compliance. However, both samples were below the GWCL for iron (2,750 ttglL). It doesn't appear that DUSA is using the presence of detectable concentrations in the field and equipment rinse blanks in the 2nd Quarter, 2008 groundwater report to flag or disqualify the groundwater sample results. Furthermore, the approved QAP is currently silent on how field blanks results should have a bearing on groundwater sample interpretation. 6.0 Apparent Violations 1. DUSA groundwater samples for VOCs from 12 wells received by the analytical laboratory for the April, May, and June, 2008 monitoring events failed to meet sample preservation requirements, in that they arrived at the laboratory at a temperature above the maximum allowed temperature of 4oC . Therefore samples collected during these sampling events are not representative of the monitored activity conducted for the April - June sampling events. These temperature exceedances are in violation of Part I.E.4(a) and Part II.A of the Permit. This is a continuing violation cited previously in a January 11, February 28, April 1, and August 4,2008 DRC NOVs. 2. DUSA collected a groundwater sample from MW-4 on May 27,2008 that was not required under the Permit. Although, MW-4 is a chloroform investigation well, the results were not included in the 2nd Quarter 2008 report. Failing to submit results for this additional monitoring is in violation of Part II.F of the Permit. APPENDIX 1 QA/QC Tables TABLE 2 MONITOB WELLS WITH CONTAMINANT(S) WITH GROSS ALPHA COUNTING VARIANCE EXCEEDING 20% (pci/L) ivell )ontaminant(s) Groundwater Gradient Belationship to Tailing Cells1st Qtr 2008 Jan - March Concentration + Error Term Counling Variance 2nd Otr 2008 April - June Concentration + Error Term Counting Variance r'lw-l 1.2 kl-0.4\1.6 33o/"Jp qradient ol the site. /w-2 1 4 (+l-0.4)1.8 28.5"/"Directly southwest of the southwest corner and down gradient of Tailing Cell 1. /lw-3 1.1 Gl-O.4\36.3"/")own oradient of all the tailino cells 1 1 (+/-O.4)1.5 36.30/.)own oradient of all the tailino cells /lw-5 1 2 Ut-O 4\'1.6 33.0"/")own oradient ot Tailino Cell 3. /lw-1 1 0.9 (+/- 0.3)1.2 33"/"1.2 (+/-0.5)1.7 42%)irectly down gradient ol Tailing Cell 3 /tw-12 1.2 Gl-0.4\1.6 33o/")own oradienl of Tailino Cell 3 /lw-14 1.3 (+t 0.4)1.7 30.7%1.1 (+/{.a)36.3% firectlv down oradient ol Tailinq Cell 4A. /lw-15 1.1 (+/-0.a)1.5 36.3%)irectly near ihe southwest corner and lown oradient of Tailino Cell 4A ilw-17 0.9 (+/- 0.3)1.2 33o/o )irectly south of and down gradient o, railind aall 1A 1.2 /+t-O.4\1.6 3304 Jo oradient of the site /lw-19 1.3 (+r0.4)17 28.5o/o )irectly northeast and up gradient ol mill iite. ./lw-20-2.1 (+/-0.5)2.6 23.8o/o fown oradient of all the tailino cells ilw-23'1.9 (+t0.s)2.4 26.3"/"firectly on the southwest corner and Jown oradient ot Tailino Cell 3. 'AW-24',0.2 (+/- 0.3)0.5 150"/o 0.9 (+r 0.s)1.2 33o/"firectly on the southwest corner and lown oredient of Tailino Cell 1 '/lW-25"1.9 (+/- 0.4)2.3 21vo 1.4 (+/-0.5)'1.9 35.7"/"firectly on the southeast corner and )ross oradient of Tailino Cell 3. '/lw-26 2.3 (+/- 0.6)2.9 26"/"2.9 (+/-0.6)3,5 20.6%Easi and cross gradieni olTailing Cell 2. NIW-26 is a pumping well. Pumping from this well will capture some groundwater under the eastside of Tailino Cell 2 'AW-27',2.0 (+l- O.4\2.4 20o/o 1.9 (+10.5)2.4 26.3"/"\,lear the northeast corner and rnoredienl ol Tailino Cell I ow-zd'1.2 (+l- O.5\1.7 41.6"/o 1.3 (+r0.4)1.7 28.5"/"Directly on ihe north side and up gradient of Tailing Cell 2, and directly on the south side and down gradient of Tailino Cell 1. /lw-29'2.1 (+/- 0.5)2.6 23.8"/"1 (+l-o.a)I_5 36.3%Directly on the south side and upgradien o, Tailing Cell 3, and directly on the south side and down gradient of Tailing noll , /lw-30-1.0 (+l 0.3)1.3 30o/"0.8 (+/- 0.3)1.1 3 /.5-/o Directly on the north side and upgradient of Tailing Cell 3, and directly on the south side and down gradient ol Tailing Cell2. /lw-31'1.7 (+l= 0.4)2.1 23.5o/o 1.3 (+/-0.4)1.7 28.5"/"Directly on the north side and upgradient of Tailing Cell 3, and directly on the south side and down gradient of Tailing .:all , ilw-32 2.8 (+/- 0.6)3.4 21.4vo 3.5 (+r0.6)4.1 17-10/.Directly near the southeast corner and cross gradient of Tailing Cell 2 and directly near the northeast corner and up oredient ol Tailino Cell 3 t = Unregulated well Blank cells = gross alpha concentration below laboratory detection limit (>1.0 pCi/L). Therefore, no counting variance reported oPooo 39 o,o ocof N :>i@cromQo =et o ac oI =o:. o 3aE f iB5"E$ei'i la: g sE g; ;9€:eq9= i i =gs-gs ;$+EsiT*F: 'Eege i$EBgt$i5ss-g H' gi+ t-;io iFE=sffgF€FEssgEgggE E: : S-FA3 q=EE=6 2 E 33J =o B +za z ils il ! b i"gte.t=."e-:i-l88E.ABds.gdEgdd..i T-oIE ?YEr3i 5',D 5.d, iEe8t:rtEEt; INEritE36 AAAA A^A^iiii -N+Noo66 dodo Eli -al _5>a6 :qii)r3i l5E-!.6,ii-Ai*cel3!6'i! t!f,g,TT; 6 bbbb bob()b tEl$ ffih l4l E q_oa9 -?fori85b $ sn I !t1r1l;tot ri Ii;tXIE!:l $!it {r ?xil t !II :b9996a4 ---i -Nilooo,60dc iaEags$s3833aa$889t is.t F$l E tEt ffi _- --i- i$it50 00 AAAA A^A^ 6bbb bobc ho+f f Nr / oooolNot re83i \AAAAA.iNaiii isii)oooooo oo6<r*iSEAtxAA-SlrAB$tEi .OarrNA A,oioJ66frto!LNob rBESa ': iiii jN jri )o oooo oo6<,a$$EA$us5'sleAu$fi$i 'i' ooooo66a 9999 999!8888888t ) i gtipp 999 S,9 I 999tep:338i8888888H88888e BE b lo P itHiPatar-aoo6qb l;$:!iiNiaii.sifiooooooo oo60 i3flAEa$S.E-:1$36$$Ei .t isfiisu:;D{qPi A A A^ n-i:i:Nin i*:afi3g83E"Elaa6$iEi )F TooNPNPS;SBETEEE ,op9a3ei8:ooooooo(88EBB8Ei)9 )969P9999959p9pp69F18a8888888h88888b8E ,I,f 383aj8il,!o6!tuot !\BSr \ A AA.iNiiir +t-i isgaEag$38E3aa3sgEi 383i:8ijobool{ot ilss;'i iiii as-ioo 606<ia*AeAgssE'EIAAAAGEe 3S.E rSplJr:6!;38stsbBE t388e )999999999!1888888 8888 EIE EEEEgEEEEEEIEi o ooo 39 o to toocof N o6t!;Lc)o ooafo{o =o, 0,6 m f iB YE g t il!;; E'B 8 E }!i+; g 56 ai iA=ee=eE:s B# 5 Esi!*FE =gggg ''E*Fru;5rr g g=+ t $*Ee$''s s s 5E s E:i:D!ii 1aD: z 3 da Ib 'E':i"E*B'*.ie s!.Ee d a. e *"!'$Ae."e ^=iPl' I5'E^ +B I at i 0I 3 A AA A^4,bbbb bobc I ;E iE bbbb b6ba 6b :I _69 d,6$ttub!o qi."ttIlIE'.il!ui5 9:cll ;TE EAr rrr gEl 3,i It] bbbabob(6r.gi5 A A A A^A/-iii iNii -o9N'e;ts f:l:l l;altrhl! la :l^*l -o9l{*.*3N -91'i$ 3s I ae.,[[til*'l;o a +t I3q i Eq irtl fglie IEA i EIIia IT _3i T I .8I I II g i jrif,qae:iSti;\ A At::43:3:B:!:aA38sg*sta:asi*Eti rNtB J+rr rsri6b66 606<0 D@N o a 6 6 -)l€ 5 b N ! t x hs 3 !rf NJrJr JIrirbbbbbb b6b<r*fr38a$*.$ESsarsNif ,l rl! BI:t:1d :l^ril lqG N + N ! ^)bo o b 6 5 b aiN-+f - f If ^oo oooc ii-AEs$*=E"a3sta$ig! ) p6 p I $ rg I b )oooo3BBBsBB Ei3Eii >9i9999. 1695999N99Psi8888889S8S838h888E roo r - 6 5 / 'bo o i o A t r ss 3 i iiNJJna itii iar$a3;sa$el0aa*8E9 9Sot l! :l-lil 3gg e s B a looo f L 5 f i l8- o:! Bo b;iiNiiii iSii i*I3E:rsaEe:ss:*E89 )lr: o o l.;aB e E s i E ):9 9l .. ga 8l r999999 999S )99999d,999:999p999S,o5000aoooooo60066c ssd e d H S I iEea;AA -A A A^Ar ob-bbbb bobc iaBAEs$$sgii"lsaa$EEi As 3t; g: g 81ii! b \ 6 J a i ^A,3b-bbbb bobc iatAEata*au3saaeEEi r::9,l) 9l <rki ts h I i E ! iBB 8 i )99P999999S3888888 8888 999P99P9pi9888888888i8 ltrrr*E APPENDIX2 Monitor Well Concentration Tables for: MW-l, MW-2, MW-3, MW-5, MW-l1, MW-12, MW-14, MW-15, MW-17, MW-18, MW-19, MW-20, and MW-22 through MW-32 MW-1 Concentrations in bold exceed the GWQS Concenlrations shaded in yellow exceed the GWCL (a) = Quarterly accelerated monitoring evenl. The gross alpha counting vadance exceeded 20% Nol Sampled during 2nd Ouarler (June) 2007. This well was sampled in July 2007 as part ol a hydrogeologic study per{ormed by the University ol Utah. This study required undisiurbed water in this well lor at least 2 months prior to sampling. Contaminant GWOS GWCL (Class ll)(")1 st qtr. 2oo7 Jan - March 311612007 2nd qtr. 2007 April - June (")3rd qtr. 2oo7 July - Sept. 813012007 4th qtr. 2007 Oct. - Dec. 10/31t2007 (")1st qtr. 2oot Jan - March 311912008 2nd qtr. 2008 April - June 614t2008 Parameters Listed in Table 2 Nutrients (mo/L) \mmonie /as N)25 6.25 o.27 0.09 {itrate + Nitrite (as N)10 2.5 <0.1 o.42 Heaw Metals (zoll) \ rscnic 50 12.5 <5.0 <5.0 leryllium 4 1 <0.50 <0.50 --admirrm 5 1.25 <0.50 <0.50 ]hromium t00 25 <25 <25 lobalt 730 182.5 <10 <10 looper 1,300 325 <10 <10 ron 11,000 2,750 <30 88 -ead '15 3.75 <1.0 <1.0 Vlanoanese 800 200 229 30 '15 10 66 Vlercurv 2 0.5 <0.50 <0.50 vlolybdenum 40 10 <10 <10 tlickel 100 25 <20 <20 ielenium 50 12.5 <5.0 <5.0 iilver 100 25 <10 <10 fhallium 2 0.5 <0.50 <0.50 ln 17,000 4,250 <1 00 <1 00 Jranium 30 7.5 0.94 1.08 /anadium 60 15 <15 <15 ainc 5.000 1.2s0 <10 <10 Flediolnninc lnCi/l \ iross Alpha 15 3.75 1.2 (+/-0.6)1.2 G^O.4\ VOC {zoll) \cetone 700 175 <20 <20 <20 <20 Jenzene 5 1.25 <1.0 <1 .0 <1 .0 <1.0 2-Butanone (MEK)4,000 1,000 <20 <20 <20 <20 )arbon Tetrachloride 5 1.25 <1.0 <1 .0 0 ,0 )hloroform 70 17.5 <1.0 <1.0 0 .0 lhloromethane 30 7.5 <1.0 <1.0 .0 .0 )ichloromethane 5 1.25 <1.0 <1.0 .0 0 tlaphthalene 100 25 <1.0 <1.0 .0 .0 fetrahvdroluran (THF)46 11.5 14 15 16 <2.O 2.6 [oluene 1,000 250 <l.0 <1 .0 <1.0 .0 (vlenes(total)10.000 2,s00 <1 .0 <1 .0 <1.0 0 Others ;ield DH (S.U.)6.5 - 8.t 7.79 7.48;luoride (mq/l)4 1 0.3 0.3 lhloride (mo/l)17 15 iullate (mq/l)753 726 tDS (mo/l)1.390 1,220 ieneral lnoroanics Listed in Part l.1.(cl(2)liil larbonate (mo/l)<1.0 <l.0 licarbonate (mq/l)300 286 iodium (mo/l)171 174)otassium (mg/l)4.2 6.92 lesium (mq/l)64.2 59.5 )alcium (mo/l)176 164 total anions (meo/L)21.1 20.3 Total cations (meo/L)21.7 20.8 MW-2 'The gross alpha counting variance exceeded 2070 Nol Sampled during 2nd Quarter (June) 2007. This wellwas sarpled in July 2OO7 as part ol a hydrogeologic study pedored by the Univereity of Utah. This study required mdisturbed water in this rell for at le6t 2 mths prior to sartsing. Contaminant GWOS UWUL (Class lll) MW-2 (Semi-Annual Monitorino) 2nd qtr. 2005 April - June 612112005 4th qtr. 2005 Oct. - Dec. 1211412005 2nd qtr. 2006 April - June 612012006 4th qtr. 2006 Oct. - Dec. 1012412006 zndqt.2OO7 April - June 4rh qtr. 2007 Oct. - Dec. '1o12312007 2ndqtr.2008 April - June Al llrnnq Parameters Listed in Table Nutrients (md/L) \mmonia (as N)25 lz_c <0.05 0.08 o.12 <0.05 <o.05 <0.05 !rlrate + Nrlnle (as Nl lo <ol <o1 t)1 <0.1 <0.1 <0.1 Heaw Metals (uoll) \rsenic 50 25 <5.0 <5.0 <5.0 <5.O <5.0 <5o lervllium 4 2 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 ;admium <0 50 <0 50 o85 <0.50 <C 50 <0.50 lhromium 100 50 <25 <25 <25 <25 <25 <25 lobalt 730 365 <10 <10 <10 <10 <'10 <lu looper 1 300 650 <t()<lo <10 <10 <10 <10 ron 1 t.000 5.500 <30 <30 <30 <llt)<:{( )<30 -ead l5 8 <1.0 < 1.0 <1.0 <1.0 <1.0 <1.O vlanoanese 800 400 10 <1o <10 <10 <10 <10 vlercurv 2 1 <0.50 <0.50 <0.50 <o 50 <o 50 <0.50 vlolvbdenum 40 20 <10 <10 <10 <'10 <10 <'l o {ickel 100 50 <20 <20 <20 <20 <20 <20 lelenium 50 25 7 18.5 7.7 143 8.1 <5.0 iilver 100 50 <10 <10 <10 <10 <10 <10 fhallium 1 <o 50 <o 50 <0.50 <0.50 <0.50 <0.50 l-in 17.000 8.500 <1 00 <.I U{J <ltrt)00 Jranium 30 15 6.25 13.9 12 12.2 10.3 8.68 /anadium 60 30 <15 <15 <15 <t5 <15 <15 Zinc 5.000 2,500 12 <10 11 <10 14 <10 Radiolooics foCi/L) iross Aloha 15 7.5 <1.0 <1.0 <1.0 17 Gl-O1 13 -o 5\1 4 (+l-O 4\ VOC holl 't \cetone 700 350 <20 <20 <20 <20 <20 <20 Senzene 2.5 <1.0 <'1.0 <1.0 <1.O <1 0 0 2-Butanone (MEK)4,000 2,000 <20 <20 <20 <20 <20 <20 larbon T6trachloride 5 2.5 <'l.0 0 <1 0 <1 (l .0 0 )hlorolorm 70 35 <1.0 0 <1.0 <1.0 .0 o lhloromethene 30 15 35 o <1.0 2.1 .0 0 )ichloromethane 5 2.5 <1.0 0 <1.0 <1 0 ()0 {aphthalene 100 50 <1.0 0 <1.0 <1.0 .o <1 0 Tetrahvdrofuran (THF)46 23 <1 0 o <1.0 <10 <2.O Toluene 1.000 500 <1.O 0 <1.0 <1 0 o <1.0(vlcnes{totall to ooo s ooo 1tl o < 1.0 <1.0 <1 0 Others :ield oH (S.U.)6.5 - 8.5 7.42 7.99 7.64 7.17 741 732:kroride (mcr-/l\4 2 o4 0.3 0.3 o.2 0.3 0.3 lhloride (mc/l)7 7 I 7 )ulfate (mo/l)1 850 '1920 1.880 1.970 '1.990 2.OOO TDS fmo/l\3060 31 00 3 060 3,550 3.1 00 3.030 General lnoroanics Listed in Part 1.E.1.(c)(2)( larbonate (mq/l)<1.0 <1.0 < 1.0 <1.0 <1.0 <1.O licarbonate fmo/l'l 373 409 383 294 396 373 lodium (mc/l)473 483 470 447 460 530rotassium (mo/l)9.7 10 11.4 1 1.5 10.5 10.2 Ulaonesium (mc/l)44.7 92 99 103 100 95 lalcium (mc/l)313 329 315 355 326 Tolal anions (meo/L\44.8 46.8 45.6 46.1 48,1 4A fotal cations (meo/L)43.4 lts3 M6 477 45.3 4 .4 MW-3 Concentrations in bold exceed the GWQS Concentrations shaded exceed lhe GWCL (a) = Quarlerly accelerated monitoring event Not Sampled duriru 2nd Quarler (June) 2007. This well was sampled in July 2007 as part of a hydrogeologic sludy porform€d by the University ot Utah. This study required undisturbed wai6r in thiswell tor at leasi 2 monihs prior to sampling. Contaminant GWOS GWCL (Class lll)(')1 st qtr. 2oo7 Jan - March 311612007 2nd qtr. 2007 April - June (")3rd qtr. 2oo7 July - Sept. 812912007 4th qtr. 2007 Oct. - Dec. 1n,|a112on7 (")1 st qtr. 2oo8 Jan - March allql)o A 2nd qtr. 2008 April - June 512Al20,0,a Parameters Listed in Table 2 Nutrients (mc/L) \mmonia (as N)25 12.5 0.07 <0.05 Nilrate + Nitrite (as N)10 5 0.1 0.18 Heaw Metals (uo/L) Arsenic 50 25 <5.0 <5.0 3eryllium 4 2 <0.50 <0.50 ladmium 5 2.5 0.98 o.52 lhromium 100 50 <25 <25 lobalt 730 365 <10 <'10 lopper 1 300 650 <10 <10 lron 11.000 5.500 <30 <30 -ead 15 7.5 <1 .0 <l.0 Vanoanese 800 400 848 199 t-950 1-330 810 Mercury 2 1 <0.50 <0.50 Molvbdenum 40 20 <10 <10 !ickel 100 50 21 <20 3elenium 50 25 20.1 33.6 8.9 13.8 20.1 Silver '100 50 <10 <10 Thallium 2 1 0.99 ,.1S 1 _15 0.9 0.86 Tin 17.000 8.500 <1 00 <1 00 Jranium 30 15 30,2 17.4 39:4 35.6 31.3 y'anadium 60 30 <15 <15 7-inc 5.000 2.500 13 19 Radioloqics (pCi/L) iross Alpha 15 7.5 <1.0 1.1 (+10.4) VOC (uo/L) \cetone 700 350 <20 <20 <20 <20 Senzene 5 2.5 <1 .0 <1 .0 <1.0 <1 .0 2-Butanone (MEK)4.000 2.000 <20 <20 <20 <20 larbon Tetrachloride 5 2.5 <1.0 <1 .0 <1 .0 <1 .0 lhloroform 70 35 <1.0 <1 .O <1 .0 <1 .0 lhloromethane 30 15 <1.0 <1.0 <1 .0 <1.0 fichloromethane 5 2.5 <1.0 <1.0 <1 .0 <1.0 tlaphthalene 100 50 <1.0 <'1.0 <1 .0 <1 .0 fetrahvdrofuran (THF)46 23 11 <10 <10 6.5 <2.O foluene 1.000 500 <1.0 <1 .0 <1.0 <1 .0 (vlenes(total)10.000 5.000 <l.0 <1 .0 <-l.o <1 .0 Others:ield DH (S.U.)6.5 - 8.5 6.95 6.71:luoride (mo/l)4 2 o.4 0.5 lhloride (mc/l)63 64 iulfate (mc/l)3.120 3.340 l-DS (mc/l)5.150 4.800 eneral lnoroanics Listed in Part 1.E.1.(c)(2)(ii) larbonate (mo/l)<1 .0 <1 .0 licarbonate (mc/l)516 364 iodium (mc/l)804 846rotassium (mo/l)23.3 22.2 Vlaonesium (mc/l)246 247 lalcium (mc/l)482 488 fotal anions (meo/L)75.3 77.3 fotal cations (meo/L)80 82 MW-3A Concentrations in bold exceed the GWOS Concentrations shaded exceed the GWCL Not Sampled during 2nd Quarter (June) 2007. This wsll was sampled in July 2007 as part of a hydrogeologic study performed by the University of Ulah. This study required undisturbed water in these wells for al least 2 months prior to sampling. Not Sanpl€d durirq ttE 3rd Ouarter 2007 ard l sl QrBrler 20OB rnonitoring events as required Contaminant GWOS UWUL (Class lll)1st qtr. 2007 Jan - March 311412007 2ndqtr.2007 April - June 3rd qtr. 2007 July - Sept. 4th qtr. 2007 Oct. - Dec. 1013112007 1 st qtr. 2008 Jan - March 2nd qtr. 2008 April - June 5t28t2008 Paramelers Listed in able Nutrients (mo/L) \mmonia (as N)25 12.5 <0.05 <0.05 <0.05 {itrate + Nitrite (as N)'lo 5 0.9 1.2 0.91 Heaw Metals (uq/L) \rsenic 50 25 <5.0 <5.0 <5.0 leryllium 4 2 <0.50 1.32 o.77 ladmirrm 5 2.5 1.76 1.23 0.76 )hromium 100 50 <25 <25 <25 )obalt 730 365 <10 <10 <10 lopoer 1.300 650 <10 <10 <10 ron 'I 1.000 5.500 <30 <30 <30 -ead 15 7.5 <1 .0 <1 .0 <1 .0 Vlanqanese 800 400 253 142 64 Vlercury 2 1 <0.50 <0.50 <0.50 vlolvbdenum 40 20 <10 <10 <10 {ickel 100 50 26 <20 <20 ielenium 50 25 74 73.9 73.4 iilvcr 100 50 <10 <10 <10 l-hallium 2 1 o.74 1.0'l 0.9 tin 17.000 8.500 <1 00 <1 00 <1 00 Jranium 30 15 21 "9 22.9 22.4 /anadium 60 30 <15 <15 <t5 linc 5.000 2.s00 65 40 34 Radiolooics (DCi/L) iross Aloha 15 7.5 <1 .0 <1 .0 1 (+l-O.4\ VOC (uo/L) \cetone 700 350 <20 <20 <20 Jenzene 5 2"5 < 1.0 <1.0 <1 .0 l-Butanone (MEK)4.000 2,000 <20 <20 <20 ,-arbon Tetrachloride 5 2.5 <1 .0 0 <1.0 lhloroform 70 35 <1 .0 0 <1.0 lhloromethane 30 15 <1 .0 0 <1.0 Jichloromethane 5 2.5 .0 0 <1.0 \aDhthalene 100 50 .0 0 1.0 Tetrahvdrofuran (THF)46 23 0 <10 <2.0 Toluene 1,000 500 .0 <1.0 <1 .0(vlenes(total)'t0.000 5.000 .o <1.0 <1 .0 Others:ield oH (S.U.)6.5 - 8.5 7.02 6.92 7.30:luoride (mg/l)4 1.2 1.4 1 lhloride (mq/l)oz 60 61 3ulfate (mo/l)3,810 3.470 3,550 IDS (mq/l)5.770 5.490 5.070 ieneral lnorqanics Listed in Part .E.1.(cX2Xii) larbonate (mq/l)<1 .0 <1.0 <1.0 licarbonate (mq/l)381 324 384 3odium (mq/l)754 741 827)otassium (mq/l)26.9 29.3 28.6 Maonesium (mo/l)303 310 306 lalcium (mo/l)478 479 496 fotal anions (meq/L)87.4 79.4 81.9 otal cations (meo/L)82.8 82.4 86.6 Nole MW-5 Concentrations shaded exceed the GWCL (a) = Quarterly accelerated monitoring event Noi Sampled during 2nd Ouarter (June) 2007. This well was sampled in July 2OO7 as part o, a hydrogeologic study performed by the University of Ulah. This study required undisturbed waler in ihis well tor al least 2 months prior lo sampling. Contaminant GWOS GWCL (Class ll)(")1sl qtr. 2oo7 Jan - March 311512007 zndqlr.2007 April - June (')3rd qtr. 2oo7 July - Sept. 812812007 4th qtr. 2007 Oct. - Dec. 1012912007 (')1st qtr. 2oo8 Jan - March 311812008 2nd qtr. 2008 April - June 61181200a Parameters Listed in Table 2 Nutrients (mc/L) \mmonia (as N)25 6.25 0.43 0.51 !itrate + Nitrite (as N)10 2.5 <o.1 <0.05 Heaw Metals (uc/L) \rsenic 50 12.s <5.0 <5.0 3ervllium 4 1 <0.50 <0.50 ladmium 5 1.25 <0.50 <0.50 lhromium 100 25 <25 <25 loball 730 182.5 <10 <10 lopper 1.300 325 <10 <10 ron 11.000 2,750 <30 84 -ead 15 3.7s <l.0 <1 .0 Manqanese 800 200 281 134 142 203 258 Vlercury 2 0.5 <0.50 <0.50 Molvbdenum 40 10 <10 <10 ',lickel 100 25 <20 <20 Selenium 50 12.5 <5.0 <5.0 Silver 100 25 <10 <10 hallium 2 0.5 <0.50 <0.50 Iin 17.000 4 25o.<1 00 <1 00 Jranium 30 7.5 0.61 <0.30 /anadium 60 15 <15 <15 7-inc 5.000 1.250 <10 <10 Radiolooics (oCi/L) iross Alpha 15 3.75 <1 .0 1.2 GLl.41 VOC (uc/L) \cetone 700 175 <20 <20 <20 <20 3enzene 5 1.25 <1.0 <1 .0 <1 .0 <'1.0 2-Butanone (MEK)4.000 1,000 <20 20 <20 <20 larbon Tetrachloride 5 1.25 <1 .0 <1 .0 0 <1 .0 )hloroform 70 17.5 <1 .0 <1 .0 0 <1 .0 lhloromethane 30 7.5 <1 .0 <1 .0 0 <1 .0 )ichloromethane 5 1.25 <1 .0 <1_0 0 <1 .0 {aphthalene 100 25 <1 .0 <'l _0 0 <1.0 etrahvdrofuran (THF)46 11.5 <10 <10 10 9.2 10 [oluene 1.000 250 <1.0 <1.O 1.4 <1.0 (vlenes(total)10.000 2.500 <1 .0 <1.0 <1 .O <1.0 Others:ield oH (S.U.)6.5 - 8.5 8.09 7.65:luoride (mo/l)4 1 1.1 1.2 t 1 0.9 )hloride (mc/l)50 50 iulfate (mc/l)1,130 1 090 IDS (mc/l)1,880 1 900 ieneral lnorqanics Listed in Part 1.E.1.(cx2l ( ii) larbonate (mc/l)<'1.0 <1.0 licarbonate (mc/l)378 357 iodium (mc/l)476 503)otassium (mc/l)8.4 7.5 vlaonesium (mcr/l)eoe 38 ,'alcium (mc/l)138 135 lotal anions (meo/L)31 .3 30 lotal cations {meo/L)31 .1 32 MW-11 (a) = Monthly accelerated monitoring evenl* The gross alpha counting variance exceeded 207. Not Sampled during znd Ouarter (Juno) 2007. This well was sampled in July 2OO7 as parl ol a hydrogeologic study perrormed by the University ot Utah. This sludy required undisturbed waler in this well lor al least 2 months prior lo sampling. Contaminant GWOS UWUL (Class ll)1st qtr. 2007 Jan - March 3l't512007 Zndqlr.2007 April - June 3rd qtr. 2007 July - Sept. 812112007 4th qtr. 2007 Oct. - Dec. 1o-1ao12n,o,7 1 st qtr. 2008 Jan - March al1Rl2qn,R 2nd qtr. 2008 April - June A/ t A/2r|rlA Parameters Listed in Table 2 Nutrients (mq/L) \mmonia (as N)25 6.25 0.66 0.64 0.65 0.59 0.63 {itrate + Nitrite (as N)10 2.5 <0.1 <0.1 <0.1 <0.1 <0.05 Heaw Metals (ucr/L) \rsenic 50 12.5 <5.0 <5.0 <5.0 <5.0 <5.0 lervllium 4 1 <0.50 <0.50 <0.50 <0.50 <0.50 )admium 5 1.25 <0.50 <0.50 <0.50 <0.50 <0.50 lhromium 100 25 <25 <25 <25 <25 <25 lobalt 730 182.5 <10 <10 <10 <10 <10 loooer 1.300 325 <10 <'10 <10 <10 <10 ron 11.000 2.750 30 13s 141 206 112 -ead 15 3.75 <1.0 <1 .O <1.0 <1 .0 <1 .0 Vlanqanese 800 200 107 72 80 70 74 VIercury 2 0.5 <0.50 <0.50 <0.50 <0.50 <0.50 14olybdenum 40 10 <10 <10 <10 <10 <10 {ickel 100 25 <20 <20 <20 <20 <20 lelenium 50 12.5 <5.O <5.0 <5.0 <5.0 <5.0 lilver 100 25 <'10 <10 <10 <10 <10 fhallium 2 0.5 <0.50 <0.50 <0.50 <0.50 <0.50 lin 17.000 4.250 <'100 <100 <1 00 <1 00 < 100 Jranium 30 7.5 1.04 <0.30 <0.30 <0.30 <0.30 /anadium 60 15 <15 <'15 <15 <15 <15 7-inc 5.000 1.250 <10 <10 <'10 <to <10 Radiolooics (oCi/L) fross Aloha 15 3.75 <1 .0 <1 .0 .0.9 (+/- 0.3)1.2 (+10.5) VOC (uo/L) \cetone 700 175 <20 <20 <20 <20 <20 Senzene 5 1.25 <1 .0 <1 .0 <1 .0 <1.0 <1.0 l-Butanone (MEK)4,000 1.000 <20 <20 <20 <20 <20 larbon Tetrachloride 5 1.25 .0 <1.0 0 <1.0 <1 .0 lhloroform 70 17.5 .0 <1 .0 0 <1 .0 <1 .0 lhloromethane 30 7.5 .0 <1.0 0 <1 .0 <1 .0 )ichloromethane 5 1.25 .0 <1 .0 0 <'l .0 <1 .0 {aohthalene '100 25 .0 <1.0 0 <'l .0 <1 .0 fetrahvdrofuran (THF)46 11.5 <10 <10 <10 <2.0 <2.0 foluene 1.000 250 <1.0 <1.0 <1.0 <1 .0 <1 .0 (vlenes(total)10.o00 2.500 <1 .0 <1.0 <'l .o <1 .0 <1 .O Others:ield pH (S.U.)6.5 - 8.5 6.94 8.08 8.08 7.91 7.87:luoride (mo/l)4 1 0.6 0.7 0.5 0.6 0.5 lhloride (mo/l)31 30 ,a 29 30 Sulfate (mo/l)1,120 1,060 1,020 1.040 't o50 IDS (mc/l)2.O40 1,800 1.770 '| ,750 1.790 ieneral lnoroanics Listed in Part l-E.1.(c){2)(ii) larbonate (mq/l)<1 .0 <1.0 <l.0 3 <1.0 3icarbonate (mq/l)375 383 378 380 356 iodium (mo/l)571 568 580 606 632)otassium (mq/l)7.6 6.2 7.5 6 6.1 vlaqnesium (mq/l)22.1 10.9 11.1 10 10.7 lalcium (mo/l)69.2 39.2 40.3 38.1 40.8 [otal anions (meq/L)30.4 29.2 28.3 28.9 28.5 fotal cations (meq/L)30.4 27.8 28.4 29.3 30.6 MW-12 Concentralions shaded exceed the GWCL (a) = Quarierly accelerated moniloring event Not Sampted during 2nd Ouarter (June) 2007. This well was sampled in July 2007 as parl ol a hydrogeologic sludy perlormed by lhe University of Utah. This study required undisiurbed water in this well tor at least 2 monlhs prior lo sampling. Contaminant GWOS GWCL (Class lll) MW-1 2 (Semi-Annual Monitorino) (")1st qtr. 2oo7 Jan - March ?,l17lrno7 2nd qtr. 2007 April - June (")3rd qtr. 2oo7 July - Sept. 812812007 4th qtr. 2007 Oct. - Dec. 1012312007 (")1st qtr. 2oo8 Jan - March 311812008 2nd qtr. 2008 April - June 611712008 Parameters Listed in Table 2 Nutrients (mo/L) \mmonia (as N)25 12.5 <0.05 <0.05 {itrate + Nitrite (as N)10 5 <0.1 0.1 Heaw Metals (uq/L) \rsenic 50 25 <5.0 <5.0 lervllium 4 2 <0.50 <0.50 ladmium 5 2.5 <0.50 <0.50 )hromium 100 50 <25 <25 ,-obalt 730 365 <10 <t0 )oooer 1.300 650 i10 <10 ron 't 1.000 5.500 68 <30 -ead 15 7.5 <1.0 <1.0 Ulanganese 800 400 279 57 60 29 32 Ulercury 2 1 <0.50 <0.50 Jlolybdenum 40 20 <10 <10 {ickel 100 50 <20 <20 lelenium 50 25 10.7 7.9 Silver 100 50 <10 <10 Ihallium 2 1 <0.50 <0.50 Iin 17,000 8,500 <1 00 <1 00 Jranium 30 15 19.4 8.68 19.2 16.8 16.7y'anadium 60 30 <15 <15 7-inc 5.000 2.500 10 <10 Radiolooics (oCi/L) 3ross Aloha 15 7.5 <1 .0 1.2 (+l-O.4\ VOC (ucr/L) qcetone 700 350 <20 <20 <20 <20 3enzene 5 2.5 <1 .0 <1.0 <1 .0 <1 .0 2-Butanone (MEK)4,000 2,000 <20 <20 <20 <20 larbon Tetrachloride 5 2.5 <1 .0 <1 .0 <-1.0 <1 .0 lhloroform 70 35 <1 .0 <1 .0 <1 .0 <1 .0 lhloromelhane 30 15 <1 .0 <1 .0 <1 .0 <1 .O )ichloromethane 5 2.5 <1.0 <1 .0 <1 .0 <'l.o \aphthalene 100 50 <1.0 <1 .0 <1 .0 <1 .0 Ietrahvdrofuran (THF)46 23 3A <10 <10 <2.O 3 foluene 1,000 500 <'1.0 <1 .0 <1.0 <1 .0 (vlenes(total)10,000 5,000 <1 _O <1 .0 <1.0 <l.o Others :ield pH (S.U.)6.5 - 8.5 7.30 7.08:luoride (mq/l)4 2 o.2 0.3 lhloride (mq/l)58 54 3ulfate (mq/l)2.290 2,270 IDS (mq/l)3.800 3,530 Seneral lnoroanics Listed in Part .E.1.(cX2):ii) larbonate (mq/l)<1 .0 <1 .O licarbonate (mq/l)439 200 iodium (mq/l)282 300)otassium (mq/l)13.2 13 Vlaonesium (mo/l)224 207 )alcium (mq/l)524 525 fotal anions (meq/L)56.5 55.3 fotal cations (meo/L)57.2 56.6 MW.14 Contaminant GWOS GWCL (Class lll) VIW-1 4 (Quarterlv Monitorino) January (")Monthly Accl. '1129/20,0,a February (")Monthly Accl. 212n,120/0,a 1st qtr. 2008 Jan - March 3t19t200,4 April (u)Monthly Accl.Llrolti 9 May (u)Monthly Accl. E|1 AID^ A 2nd qtr. 2008 April - June 6t18t2008 rarameters Listed in Table 2 Nutrients (mc/L) Ammonie les N\25 12.5 o.12 <0.05 {itrale + Nitrite (as N)'to 5 <oI <o 05 Heaw Metals (uo/L) \rsenrc,50 25 <5.0 <5.0 lervllium 4 2 <0.50 <0.50 ladmium 5 2.5 0.99 0.91 )hromium 100 50 <20 <20 lobalt 730 365 <10 <10 0pDer 1,300 650 <10 <10 ron 1 1.000 5.500 <30 <30 -ead '15 7.5 2,2tn 2:080 <1.0 2,161)2,420 <1.O vlanoanese 800 400 2.,280 2.29,, vlercurv 2 I <0.50 <0.50 vlolvbdenum 40 20 <lo <10 {ickel 100 50 <20 <20 ielenium 50 25 <5.0 <5.0 iilver 100 50 <10 <10 I-hallium 2 I <0.50 <0.50 l-in 17,000 8,500 65.1 il.1 <100 6,;8 62.6 <100 Jranium 30 15 65.8 61.5 60 30 <15 <15 1C 5 000 2 500 <lo 14 Radiolooics (oCi/L) iross Aloha 't5 7.5 1.3 (+/- 0.4)'l. l (+/- 0.4) VOC (uo/L) \cetone 700 350 <20 <20 lenzene 5 2.5 <1.0 <1.0 2.Butanone (MEK)4 000 2,000 <20 <20 )arbon Tetrachloride 5 2.5 <1.0 .0 lhlorolorm 70 35 <1.0 .o lhloromethane 30 l5 <1.0 .0 )ichloromethane 5 2.5 <1.0 .0 {aphthalene 100 50 <1.0 .0 [etrahvdrofuran (THF)46 23 <2.O <2.O foluene 1.000 500 <1.0 <1.0 (vlenes(total)10 000 ooo <1 0 <1 0 Olhers:ield oH (s.u.)Aq.RE 7.72 6.88:luoride (mq/l)4 2 o.2 o.2 )hloride (mo/l)20 18 iullate (ms/l)2.27o 2,200 fDS (mo/l)3.420 3,620 ieneral lnoroanics Listed in Part E.1.(cX2Xii) larbonate (mo/l)<1.0 <1.0 licarbonate (mc/l)473 440 iodium (mq/l)332 359 )otassium (mo/l)11.1 12.2 vlaonesium (mc/l)155 152 ]alcium (mq/l)500 527 fotal anions (mec/L)55.7 53.6 total cations (meo/L)52.6 54.7 Concentrations in bold exceed the GWQS Concentrations shaded exceed the GWCL (a) = Quarterly accelerated rnonitoring event ' The gross alpha counting variance erceeded20k Not Sarrpled during 2nd Quarter (Jun€) 2007. This well was sampled in July 2007 as part of a hydrogeologic stldy pedonrEd by the University of Utah. This study required undisturbed water in this well lor at least 2 rmntl'ls prior to saffpling. Nd sarg€tq4ine lr$ $sy 2007"?pcqryfl$&$#rih{iq e€rit as ro$rlrEd "i" ' i nW ,u MW-15 Concentrations in bold exceed the GWOS Concentralions shaded exceed the GWCL (a) = Quarterly accelerated monitoring eveni Not Sampled during 2nd Ouarter (June) 2007. This well was sampled in July 2OO7 as parl of a hydrogeologic strdy perlormed by the University of Utah. This sludy required undisturbed wate. in this well ,or at least 2 monlhs prior to sampling- Contaminant GWOS GWCL (Class lll)(")1st qtr. 2oo7 Jan - March 311512007 2nd qtr. 2007 April - June (")3rd qtr. 2oo7 July - Sept. 812912007 4th qtr. 2007 July - Sept. 1012912007 (")1st qtr.2oo8 Jan - March 311112008 2nd qtr. 2008 April - June 6/1 8/2008 Parameters Listed in Table 2 Nutrients (mo/L) \mmonia (as N)25 12.5 <0.05 <0.05 ,,litrate + Nitrite (as N)10 5 0.1 0.15 Heaw Metals (ucr/L) \rsenic 50 25 <5.0 <5.0 lervllium 4 2 <0.50 <0.50 )admium 5 2.5 <0.50 <0.50 lhromium 100 50 <25 <25 lobalt 730 365 <10 <10 loooer '1.300 650 <10 <10 ron 11,000 5,500 <30 <30 -ead 15 7.5 <1.0 <1 .0 Vanoanese 800 400 <10 <10 VIercury 2 1 <0.50 <0.50 Vlolybdenum 40 20 <10 <10 \,lickel 100 50 <20 <20 3elenium 50 25 89.6 94 94 t13 1$ 3ilver 100 50 <10 <10 fhallium 2 1 <0.50 <0.50 lrn 17,000 8,500 <1 00 <1 00 Jranium 30 15 46.5 28-6 51 48,3 lB;9 y'anadium 60 30 <15 <15 7-inc 5.000 2.500 <10 <10 Radiolooics (oCi/L) iross Alpha 15 7.5 <1.0 .'1.1 (+/- 0.4) VOC (uo/L) qcetone 700 350 <20 <20 3enzene 5 2.5 <1 .0 <1 .0 2-Butanone (MEK)4.000 2.000 <20 <20 larbon Tetrachloride 5 2.5 <1 .0 <1.0 lhloroform 70 35 <1 .0 <1.0 lhloromethane 30 't5 <1.0 <1.0 )ichloromethane 5 2.5 <1.0 <1 .0tlaphthalene10050<1 .0 <1 .0 [etrahvdrofuran (THF)46 23 <1 .0 <2.0 foluene 1.000 500 <1 .0 <1.0 (vlenes(total)10.000 5.000 <l.o <1.0 Others:ield pH (S.U.)6.5 - 8.5 7.21 6.99:luoride (mo/l)4 2 0.2 0.2 )hloride (mo/l)Jb 37 iulfate (mc/l)2.340 2.400 l-DS (mo/l)3,660 3.680 ieneral lnoroanics Listed in Part 1.E.1.(c)(2)) larbonate (mc/l)<1 .0 <1 .0 licarbonate (moil)454 415 lodium (mc/l)457 520)otassium (mc/l)10.6 10.4 vlaonesium (mc/l)165 't 58 )alcium (mc/l)440 444 [otal anions (meo/L)57.2 57.9 lotal cations (meo/L)55.7 58.1 MW-17 Contaminanl GWOS GWCL (Class lll)(")1st qtr. 2oo7 Jan - March 311612007 zndqr2007 April - June 6/2012007 (")3rd qtr. 2oo7 July - Sept. 812912007 4th qtr. 2007 Oct. - Dec. 1012912007 (")1 st qtr. 2oo8 Jan - March 3t1212008 2nd qtr. 2008 April - June 512812008 Parameters Listed in Table 2 Nutrients (mc/L) \mmonia (as N)25 12.5 <0.05 <0.05 <0.05 {itrate + Nitrite (as N)10 5 0.3 0_4 0.5 Heaw Metals (uo/L) \rsenic 50 25 <5.0 <5.0 <5.0 lervllium 4 2 <0.50 <0.50 <0.50 ladmium 5 2.5 <0.50 <0.50 <0.50 lhromium 100 50 <25 <25 <25 lobalt 730 365 <10 <10 <10 )opper 1,300 650 <10 <10 <10 ron 11,000 5,500 <30 <30 <30 -ead 15 7.5 <1.0 <1.0 <l.0 r'lanqanese 800 400 91 73 108 r'lercury 2 <0.50 <0.50 <0.50 i/lolYbdenum 40 20 <10 <10 <10 {ickel 100 50 <20 <20 <20 ielenium 50 25 <5.0 5.4 7.8 lilver 100 50 <10 <10 <10 l-hallium 2 <0.50 <0.50 <0.50 <0.50 <0.50 tn 17,000 8,500 <1 00 <1 00 < 100 Jranium 30 15 x,4 't8.2 20.1 31 28.3 29_4 /anadium 60 30 <15 <15 <15 Iinc 5.000 2.500 <10 <10 <10 Radiolooics (oCi/L) iross Aloha 15 7.5 <1 .0 <l.0 -0.9 (+/. 0.3) VOC (uo/L) \cetone 700 350 <20 <20 <20 Jenzene 5 2.5 <1 .0 <1.0 <1.O l-Butanone (MEK)4,000 2,000 <20 <20 <20 )arbon Tetrachloride 5 2.5 .0 <1 .0 <1.0 )hloroform 70 35 0 <1 .0 <1 .0 )hloromethane 30 15 .0 <1.0 <1 .0 )ichloromethane 5 2.5 .0 <1.0 <1 .0 'laphthalene 100 50 .0 <1.0 <1 .0 fetrahvdrofuran (THF)46 23 <10 <10 <2.O [oluene 1,000 500 <1 .0 <1.0 <'l.0(vlenes(total)10.ooo 5,000 <1 .0 <1 .0 <1.0 Others :ield pH (S.U.)6.5 - 8.5 7.24 7.O7 7.29:luoride (mq/l)4 2 o.4 0.3 0.3 lhloride (mo/l)29 28 32 iulfate (mo/l)2.560 2.510 2,54A rDS (mq/l)4.160 3.980 4,030 Seneral lnorqanics Listed in Part E.1.(c)(2)(ii) larbonate (mq/l)<l.0 <1 .0 <1 .0 ficarbonate (mo/l)515 521 474 iodium (mq/l)637 624 648rotassium (mq/l)14.3 't3 12.4 Vlaqnesium (mq/l)198 188 188 lalcium (mo/l)381 371 386 [otal anions (mec/L)62.7 61.7 b t.b fotal cations (meo/L)63.4 61 .5 oJ,z Concentrations in bold exceed the GWQS Concenlrations shaded exceed the GWCL (a) = Quarterly accelerated moniloring eveni. The gross alpha counling variance exceeded 2O"/o MW-18 Concentrations in bold exceed the GWOS Concenlrations shaded exceed the GWCL (a) = Quarterly accelerated monitoring event* The gross alpha counting variance exceeded 207" Not Sampled during 2nd Ouarler (June) 2007. This well was sampled in July 2007 as parl of a hydrogeologic study performed by the University of Uiah. This study required undisturbed water in this well for at leasl 2 months prior to samplirE. Contaminant GWOS GWCL (Class ll (")1 st qtr. 2oo7 Jan - March 311612007 2nd qir. 2007 April - June (")3rd qtr. 2oo7 July - Sept. 812912007 4th qtr. 2007 Oct. - Dec. 1013012007 (")1 st qtr. 2oo8 Jan - March 3t1',U2008 2nd qtr. 2008 April - June 61412008 Parameters Listed in Table 2 Nutrients (mo/L) \mmonia (as N)25 6.25 0.17 <0.05 {itrate + Nitflte (as N}'t0 2.5 <0-1 <0.05 Heaw Metals (uq/L) \rsenic 50 12.5 <5.0 <5.0 leryllium 4 1 <0.50 <0.50 ladmium 5 1.25 <0.50 <0.50 lhromium 100 25 <25 <25 )obalt 730 182.5 <10 <10 lopper 1.300 325 <10 <10 ron 11.000 2.750 509 314 -ead 15 3.75 <1 .0 <1.0 vlanqanese 800 200 219 154 .119 Vlercury 2 0.5 <0.50 <0.50 vlolvbdenum 40 't0 <10 <10 {ickel 100 25 <20 <20 lelenium 50 12.5 <5.0 <5.0 iilver 100 25 <10 <10 l-hallium 2 0.5 1.85 0.96 o.89 1.11 1.34 l-in 17.000 4.250 <100 <'100 Jranium 30 7.5 46.9 36.t5 39.2 42.4 /M-8 /anadium 60 15 <'15 <15 Zinc 5.000 'I .250 19 <10 Radiolooics (DCi/L) iross AlDha 15 3.75 'I .7 (+/-0.6)*1 .2 (+l- O.4\ VOC (ucr/L) \cetone 700 175 <20 <20 lenzene 5 1.25 <1.0 <1 .0 |Butanone (MEK)4.000 1.000 <20 <20 )arbon Tetrachloride 5 1.25 <1.0 <1 .0 lhloroform 70 17.5 <1.0 <1 .0 lhloromethane 30 7.5 <1.0 <1 .0 )ichloromethane 5 1.25 <1 .0 <1 .0 tlaohthalene 't 00 25 <1 .0 <1 .0 letrahvdrofuran (THF)46 '1 1.5 <1 .0 <2.0 foluene 1.000 250 <1 .0 <1 .0 (vlenes(total)'10.000 2.500 <1 .0 <1 .O Others :ield pH (S.U.)6.5 - 8.5 7.03 7.05:luoride (mq/l)4 1 0.2 0.2 )hloride (mq/l)48 55 iulfate (mq/l)1,700 1,870 l-DS (mo/l)2,840 3,100 ]eneral lnoroanics Listed in Part l.E.'l .{c)(2 ( ii) larbonate (mo/l)<1 .0 <l.0 licarbonate (mq/l)429 423 iodium (ms/l)196 193)otassium (mq/l)9.5 9.6 vlaqnesium (mq/l)104 126 )alcium (mq/l)501 546 fotal anions (meq/L)43.9 47.5 fotal cations (meq/L)42.3 46.2 MW-19 Concenlrations shaded exceed the GWCL (a) = Quarterly accelerated monitoring event Not Sampled during 2nd Quarter (June) 2007. This well was sampled in July 2007 as pafl ot a hydrogeologic study performed by lh€ Univarsity of Utah. This study roquirad undisturbod water in this well tor at least 2 rrcnths prior to sampling. Contaminant GWQS (iWUL (Class ll (")1st qtr. 2oo7 Jan - March 311912007 2nd qtr. 2007 April - June (")3rd qtr. 2oo7 July - Sept. 813012007 4th qtr. 2007 Oct. - Dec. 1013012007 (")1st qtr. 2oo8 Jan - March 311112008 2nd qtr. 2008 April - June 61412008 Parameters Listed in Table 2 Nutrients (mo/L) \mmonia (as N)25 6.25 0.25 <0.05 <0.05 lttrate + Nttnte (as N)10 2.5 2 2.4 2.44 Heaw Metals (uo/L) \rsenic 50 12.5 <5.0 <5.0 <5.0 lervllium 4 1 <0.50 <0.50 <0.50 )admium 5 1.25 <0.50 <0.50 <0.50 lhromium 100 25 <25 <25 <25 )obalt 730 182.5 <10 <10 <10 loooer 1.300 325 <10 <10 <10 ron 11.000 2.750 <30 <30 <30 -ead 15 3.75 < l.0 <1 .0 <'l "0 Vlanoanese 800 200 13 <10 <10 Vlercurv 2 0.5 <o.50 <0.50 <0.50 Vlolvbdenum 40 10 <10 <10 <10 {ickel 100 25 <20 <20 <20 ielenium 50 12.5 11.1 1't.9 10.8 '10.6 10.2 lilver 100 25 <'10 <10 <10 l-hallium 2 0.5 <0.50 0.s3 0.52 o.52 <0.50 lin 17,000 4,250 <1 00 <100 <'100 Jranium 30 7.5 9.37 7.76 7.53 7.32 6.76 /anadium 60 15 <15 <15 <15 Zinc s.000 1.250 <10 <10 <10 Radiolooics (oCi/L) iross Aloha 15 3.75 1 (+l-.4\<1 .0 1.3 (+l 0.4) VOC (ucr/L) \cetone 700 175 <20 <20 <20 Jenzene 5 1.25 <1.0 <1 .0 <'1.0 IButanone (MEK)4,000 1,000 <20 <20 <20 larbon Tetrachloride 5 1.25 .0 .0 <l.0 lhloroform 70 17.5 .0 .0 <1 .0 ]hloromethane 30 7.5 .0 .0 <1 .0 )ichloromethane 5 1.25 .0 .0 <1 .0 'laphthalene 100 25 .0 .0 <1 .0 etrahvdrofuran ( lHl-)46 11.5 <10 0 <2.0 [oluene 1,000 250 <1 .0 .0 <1 .0 (vlenes(total)10.ooo 2,500 o .0 <1.0 Others :ield pH (S.U.)6.5 - 8.5 7.33 7.54 7.63 :luoride (mq/l)4 1 1'4 1.3 1.1 1.1 1.1 lhloride (mq/l)36 26 28 iulfate (mc/l)1,020 509 507 I-DS (mc/l)1,730 982 977 ieneral lnorqanics Listed in Part E.1.(cX2Xii) larbonate (mq/l)<1 .0 <1 .0 <1 .0 licarbonate (mq/l)298 270 257 iodium (mq/l)410 121 113 rotassium (mq/l)6 5 4.32 ,/aonesidm lmo/l)31 46.5 46.2 ,=alcium (mo/l)101 140 140 [otal anions (meo/L)27.3 16 15.8 Total cations (meo/L)25.6 16.2 15.8 Contaminanl GWQS GWCL (Class ll) MW-20 (Ouarterlv Monitorino) lst qtr. 2008 Jan - March 2nd qtr.2008 April - June 61171200a Parameters Listed in Table 2 Nutrients (mc/L) \mmonia (as N)25 6.25 0.69 \itrate + Nitrite (as N)10 2.5 2.52 Heaw Metals (ucr/L) qrsenic 50 12.5 <5.0 ervllium 4 1 <0.50 ladmium 5 1.25 <0.50 lhromium 100 25 <25 lobalt 730 182.s <10 lopper 1,300 325 <10 ron 11,000 2,750 <50 -ead 15 3.75 <1 .0 Manoanese 800 200 77 Vlercury 2 0.5 <0.50 Vlolvbdenum 40 10 <10 tlickel 100 25 <20 Selenium 50 12.5 <5.0 Silver 100 25 <10 fhallium 2 0.5 0.54 fin 17,000 4.250 <1 00 Jranium 30 7.5 34;6 y'anadium 60 15 <15 Zinc 5,000 1 25|J 41 Radioloqics (oCi/L) 3ross Alpha 15 3.75 I " .4.W11:11 .2.1 (+/- 0.5) VOC (uo/L) \cetone 700 175 <20 Jenzene 5 '1.25 <1 .0 2-Butanone (MEK)4.000 1.000 <20 larbon Tetrachloride 5 't.25 <1 .0 lhlorolorm 70 17.5 <1 .0 lhloromethane 30 7.5 <'l .0 )ichloromethane 5 1.25 <1.0 ,,laphthalene 100 25 <1.0 [etrahvdrofuran (THF)46 11.5 <2.0 foluene 1 0()()250 <1.0 (vlenes(total)10.000 2.500 <1.0 Others:ield oH (S.U.)6.5 - 8.f 7.35 :luoride (mc/l)4 1 0.2 lhloride (mc/l)67 iulfate (mc/l)3.880 IDS (mo/l)5.570 ieneral lnoroanics Listed in Part E.1.(cX2Xii) larbonate (mc/l)<1 .0 licarbonate (mo/l)384 iodium (mo/l)1.480 )otassium (mc/l)i1;1;:::::;;;;:1;;:;;l;1,:;,:;:;;;;1,1;61.9 vlaonesium (mc/l)108 lalcium (mc/l)395 lotal anions (meoil)89.1 fotal cations (meo/L)94.4 Concentrations shaded exceed the GWCL. MW-20 ffirs {*twMW Contaminant GWQS GWCL (Class lll, MW-22 (Quarterlv Monitorino) 1 st qtr. 2008 Jan - March 2nd qtr. 2008 April - June 611712008 Parameters Listed in f ah/'e 2 Nutrients (mo/L) Ammonia (as N)25 12.5 0.36 \itrate + Nitrite (as N)10 5 3.50 Heaw Metals (uo/L) Arsenic 50 25 <5.0 3ervllium 4 2 2,27 Sadmium 5 2.5 Y2;7 lhromium 100 50 <25 ohell 730 365 266 )oDDer 1.300 650 14 lron 11,000 5,500 <50 -ead 15 7.5 <1.0 Manqanese 800 400 gl.1@ Mercury 2 1 <0.50 Volybdenum 40 20 188 \ickel 100 50 118 3elenium 50 25 13.2 Silver 100 50 <10 fhallium 2 1 1.15 Tin 17,000 8,500 <100 Jranium 30 15 52.4y'anadium 60 30 <15 Tinc 5,000 2.500 ;:::a:.:;;b 458 Fladinlnninc /nf:i/l I Sross Aloha 15 7.5 '5.4 (+/- 0.8) VOC (uq/L) qcetone 700 350 <20 3enzene 5 2.5 <1.0 2-Butanone (MEK)4,000 2,000 <20 larbon Tetrachloride 5 2.5 <1 .0 lhloroform 70 35 <1 .0 lhloromethane 30 15 <1 .0 Jichloromethane 5 2.5 <1.0 tJaphthalene 100 50 <1 .0 Ietrahvdrofuran (THFI 46 23 <2.O Ioluene 1_OOO 500 <1.0 (vlenes(total)10,000 5,000 <1 .0 Others :ield pH (S.U.)6.5 - 8.s 6.2:luoride (mq/l)4 2 2:$ lhloride (mc/l)64 iulfate (mq/l)5.130 rDS (mq/l)7.1 10 Seneral lnorqanics Listed in Part E.1.(cX2'( ii) larbonate (mqil) - :::::::.:ai ::::] i';1?@ ffi ...::;;ti::+;iifiM <1 .0 licarbonate (mq/l)436 iodium (mo/l)260rotassium (mc/l)26.2 Maonesium (mq/l)975 lalcium (mo/l)483 fotal anions (meqiL)'t 16 fotal cations (meo/L)116 MW-22 Concenlrations shaded exceed the GWCL.:i{rit!. . ,,,,,,,,,,,,, .....,,,.-..-,-i MW-23 Contaminant GWOS GWCL TBA 1 st qtr. 2007 Jan - March 3114120r)7 2nd qtr. 2007 April - June 612012007 (")3rd qtr. 2oo7 July - Sept. 812712007 4th qtr. 2007 Oct. - Dec. 1012312007 (t)1 st qtr. 2oo8 Jan - March 2llAlrnnq 2nd qtr. 2008 April - June 6/9/2008 Parameters Listed in Table 2 Nutrients {mo/L) qmmonta (as N),R 0.06 <0.05 <0.05 <0.05 <0.05 0.16 \tlrate + Nttrite (as Nl 10 0.6 0.3 0.3 0.3 0.3 0.2 Heaw Metals (uq/L) qrsenic s0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 3ervllium 4 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 ladmium 5 <0.60 <0.50 <0.50 <0.50 <0.50 <0.50 lhromium 100 <20 <20 <25 <25 <25 <25 lobalt 730 <10 <10 <10 <10 <10 <'10 looper 1.300 <10 <10 <10 <10 <10 <10 ron 11.000 <30 <30 <30 <30 <30 <30 -ead .15 <'1.0 <1.0 <1 .0 <1.0 <1.0 <1.0 Manqanese 800 281 274 472 337 372 289 Mercury 2 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Molvbdenum 40 <10 <10 <10 <'lo <10 <10 ttickel 100 20 20 21 <20 29 29 ielenium 50 <5.0 5.2 5.2 <5.O <5.0 <5.0 iilver 100 <10 <10 <10 <10 <10 <10 fhallium 2 <0.50 0.98 1.48 1.24 1.27 1.06 l-in 17.000 <1 00 <1 00 <1 00 <'100 <1 00 <100 Jranium 30 22.1 21.1 20.7 19.6 21.2 18.6 /anadium 60 <20 <15 <15 <'15 <15 <15 Zinc 5.000 30 31 46 41 33 29 Radiolooics (oCi/L) iross Alpha 15 <1 .0 1.3 (0.4+/-)"2.1 (o.7+l-\1.3 (0.5+/-)2.6 (0.5+/-)1.9 (+l 0.5) VOC (ucr/L) \cetone 700 <20 <20 <20 <20 <20 <20 lenzene 5 <l.0 <1.0 <1 .0 <1 .O <1 .0 <1.0 l-Butanone (MEK)4,000 <20 <20 <20 <20 <20 <24 )arbon Tetrachloride 5 <1 .0 .0 <1 .0 <1 .0 <1.0 <1 .0 )hloroform 70 <'l .0 .0 <1 .0 <1 .0 <1 .0 <1 .0 lhloromethane 30 <1.0 .0 <1.0 <1 .0 <1 .0 <1.0 )ichloromethane 5 <1 .0 .0 <1.0 <'l .0 <1-0 <1.0 {aphthalene 100 <'l .0 <1.0 <1 .0 <1.0 <1.0 <1 .0 tetrahvdrofuran (THF)46 <10 <10 <10 <10 <2.O <2.O toluene 1.000 <1 .0 <1 .0 <1 .0 <1 .0 <l.0 <1 .0(vlenes(total)10.000 <1 .0 <1 .0 <1 .0 <l.o <1 .O <1.0 Others;ield DH (S.U.)6.5 - 8.5 7.23 6.97 7.',!1 6.94 7.49 7.05:luoride (mq/l)4 o.4 0.3 0.3 0.2 0.2 o.2 lhloride (mo/l)o 6 I 7 7 6 iulfate (mq/l)2.340 2.320 2,460 2,310 2.410 2.180 l-DS (mo/l)3.640 3.630 3.670 3,520 3,550 3.540 Seneral Inorganics Listed in Part E.1.(cX 2Xii) larbonate (mc/l)<1 .0 <1 .0 <1.0 <1 .0 <'l .0 <1 .0 licarbonate (mcr/l)298 281 250 162 275 306 iodium (mo/l)377 378 345 343 384 400rotassium (mq/l)11.2 11.9 10.6 11.1 10.9 10.4 vlaqnesium (mo/l)154 164 161 164 146 't 59 lalcium (mq/l)454 47s 472 475 444 494 fotal anions (meq/L)53.8 53.2 55.5 51.1 55 [otal calions Imeo/l )52 54 52 52.4 51.2 The gross alpha counting variance exceeded 207". MW-24 Contaminant GWOS UWUL TBA 1st qtr. 2007 Jan - March 311612007 2ndqlr.2007 April - June 612012007 (")3rd qtr. 2oo7 July - Sept. 812812007 4th qtr. 2007 Oct. - Dec. 1012312007 (")1 st qtr. 2oo8 Jan - March 311212008 2nd qtr. 2008 April - June 5lro't2n,o,R Parameters Listed in Table 2 Nulrients (mc/L) \mmonia (as N)25 2.72 1.78 1.28 0.86 5.58 0.32 tlitrate + Nitrite (as N)10 <0.1 <0.1 <0.1 <0.1 <0.1 0.12 Heaw Metals (uo/L) \rsenic 50 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 leryllium 4 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 )admium 5 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 )hromium 100 <25 <25 <25 <25 <25 <25 )obalt 730 <10 <10 <10 <10 <10 <10 )oooer 1.300 <10 <10 <10 <10 <10 <10 ron 11.000 't 01 2,110 2,140 2.320 3.580 2.740 -ead '15 <1 .0 <1 .0 <1 .0 <1 .0 <1 .0 <'l .0 Vlanoanese 800 2_s40 2,tfro 1,670 2.770 1',664 2-330 Vlercury 2 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 vlolvbdenum 40 <10 <10 <10 <10 <10 <'10 {ickel 100 <20 <20 <20 <20 <20 <20 Selenium 50 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Silver 100 <10 <10 <10 <10 <10 <10 Ihallium 2 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Iin 17.000 <1 00 <1 00 <100 <100 <1 00 <1 00 Jranium 30 2.13 1.46 2.11 1.78 0.84 o.77y'anadium 60 <15 <15 <15 <15 <15 <15 7-inc 5.000 <,,10 <10 11 <10 <10 17 Radiolooics (DCi/L) Sross AlDha 15 <1.0 <1 .0 -1 .2 (0.6+/-)<1.0 -0.2 (0.3+/-).0.9 (+/- 0.3) VOC (ucr/L) qcetone 700 <20 <20 <20 <20 <20 <20 3enzene 5 <1.0 <1.0 <l.0 <1 .0 <1.0 <1.0 2-Butanone (MEK)4.000 <20 <20 <20 <20 <20 <20 larbon Tetrachloride 5 <1 .0 <1 .0 <l.0 <1 .0 <1.0 .0 lhloroform 70 <1 .0 <1 .0 <1 .0 <1 ,0 <'1 .0 0 lhloromethane 30 <1 .0 <1 .0 <1.0 <1.0 <'l .0 0 )ichloromethane 5 <1 .0 <1 .0 <1.0 <1.0 <1 .0 .0 t,laohthalene 100 <1.0 <1 .0 <1.0 <'1 .0 <1 .0 .0 [eirahydrofuran (THF)46 <10 <10 <10 <10 <2.0 <2.0 Ioluene 1,000 <1.0 <1.0 <1 .0 <'l .0 <1.0 <1 .0(vlenes(lotal)10.000 <1 .O <1.0 <1 .0 <1 .0 <1.0 .o Others:ield oH (S.U.)6.5 - 8.5 7.'t6 6.90 6.91 6.97 6.91 7 4:luoride (mq/l)4 0.2 o.2 0.2 0.1 o.2 0.1 lhloride (mq/l)45 44 45 45 44 45 iulfate (mq/l)2.520 2.680 2.720 2,620 2,560 2.770 IDS (mq/l)4.140 4.160 4.280 4.180 4,090 4 030 ieneral lnorqanics Listed in Part E.1.(cX2Xii) larbonate (mq/l)<1 .0 <1 .0 <1 .0 <1 .0 <1.0 <1.0 licarbonate (mo/l)387 295 31 1 300 520 188 iodium (mo/l)425 454 427 495 469 502)otassium (mq/l)13.6 14.8 12.6 14.5 12.9 12.7 vlaonesium (mo/l)178 181 147 183 167 186 lalcium (mo/l)478 496 504 509 462 500 fotal anions (meq/L)60.2 61 .9 62.9 60.7 63.1 OZ [otal cations (meq/L)57.8 60.1 59.7 62.7 58.2 62.4 Concentrations shaded excsed the GWCLt The gross alpha counling variance exceeded 207o MW.25 Contaminant GWOS GWCL TBA 1 st qtr. 2007 Jan - March a/lal2o/n7 2nd qtr. 2007 April - June Al2nlrinT (")3rd qtr. 2oo7 July - Sept. a12712007 4th qtr. 2007 Oct. - Dec. 1012512007 1st qtr. 2008 Jan - March 311812008 2nd qtr. 2008 April - June 6112t2008 Parameters Listed in Table 2 Nutrients (mo/L) \mmonia (as N)25 0.5 0.49 0.55 0.54 0.49 0.67 \,litrate + Nitrite (as N)10 <0.1 <0.1 <0.1 <0.1 <1 .0 <0.1 Heaw Metals (uc/L) \rsenic 50 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Servllium 4 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 ladmium 5 1.44 1.39 1.44 1.37 1.23 1 .19 lhromium 't 00 <25 <25 <25 <25 <25 <25 lobalt 730 10 10 12 10 't0 10 ;oPPer 't.300 <10 <10 <10 <10 <10 <10 ron 11,000 <30 <30 <30 <30 <30 <30 -ead 15 <1 .0 <1 .0 <1 .0 <1 .0 <1 .0 <1.0 Vlanqanese 800 1,75[1.610 1,7tto t.6va 7,61{J t.670 Vlercury 2 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Vlolybdenum 40 10 10 11 11 11 11 tlickel 100 <20 <20 <20 <20 <20 <20 ielenium 50 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 iilver 100 <10 <10 <10 <10 <10 <10 Ihallium 2 1.05 1.03 1.04 0.98 0.9s 0.93 lin 17,000 <1 00 <1 00 <1 00 <1 00 <1 00 <'100 Jranium 30 6.01 5.86 6.27 6.02 5.94 6.08 y'anadium 60 <15 <'15 <15 <15 <15 52 7-inc 5,000 <10 <10 <10 11 <10 <10 Radioloqics (pCi/L) Sross Alpha 15 <1.0 1.0 (0.4+/-)1.2 (0.6+/-)<1 .0 1.9 (0.4+l)*1 .4(+/- 0.5) VOC (uc/L) \cetone 700 <20 <20 <20 <20 <20 <20 Jenzene 5 <1.0 <1 .0 <1 .0 <1 .0 <1.0 <1 .0 2-Butanone (MEK)4.000 <20 <20 <20 <20 <20 <20 larbon Tetrachloride 5 <1 .0 <1.0 <1 .0 <1.0 <1 .0 <1.0 lhloroform 70 <1 .0 <1.0 <1 .0 <1.0 <1 .0 <1 .0 lhloromethane 30 <1 .0 <.1.0 <1.0 <1.0 <1 .0 <1.0 )ichloromethane 5 <1 .0 <1.0 <1.0 <1.0 <'l .0 <1 .0 tlaphthalene 100 <1 .0 <1.0 <1.0 <1 .0 <1 .0 <1 .0 tetrahvdrofuran (THF)46 <10 <10 <10 <'10 <2.O <2.0 foluene 1.000 <1 .0 <1 .0 <1.0 <1 .0 <1.0 <t.o (vlenes(total)10.000 <1 .0 <1 .0 <1 .0 <1 .0 <1.0 <1.O Others:ield oH (S.U.)6.5 - 8.5 7.22 7.O5 6.8s 7.30 7.69 7.30:luoride (mc/l)4 o.4 o.4 0.4 0.3 0.3 0.3 lhloride (mc/l)32 31 33 32 32 25 iulfate (mo/l)1.750 1.740 1.850 1.710 1,750 1 ,610 IDS (mc/l)2.970 2.900 2.810 2.750 2.710 2,770 ieneral lnoroanics Listed in Part E.1.(cX 2Xii) larbonate (mc/l)<1.0 <1 .0 <1.0 <l.0 <'l .0 <1.0 licarbonate (mc/l)390 403 412 410 4't5 381 iodium (mc/l)289 269 274 272 306 306rotassium (mo/l)10.1 9.9 9.52 10_1 9.8 9.48 vlaonesium (mc/l)135 140 136 115 120 130 lalcium (mc/l)386 39s 390 392 3s3 383 fotal anions (mec/L)43.7 43.7 46.1 43.3 44.1 40.4 fotal cations (meo/L)43.3 43.4 42.9 4't.3 41.2 43.4 Concenlrations shaded exceed the GWCL MW-26 Contaminant GWQS GWCL (Class lll)January (")Monthly Accl. 1l2ql2o,o,R February(')Monthly Accl. 2l2nl200R 1st qtr. 2008 Jan - March al1rl2o,o,A April (")Monthly Accl. al2ql2qnA May (")Monthly Accl. 5114t2008 2nd qtr. 2008 April - Juneql2Tlri A Parameters Listed in Table 2 Nutrients (mo/L) Ammonia (as N)25 12.s 0.16 0.22 \itrate + Nitrite (as N)10 5 2.7 0.34 Heaw Metals (ucr/L) Arsenic 50 25 <5.0 <5.0 3ervllium 4 2 <0.50 <0.50 iadmirrm 5 2.5 <0.50 <0.50 lhromium 100 50 <25 <25 lobalt 730 365 <10 <10 lopper 1,300 650 <10 <10 lron 11,000 5,500 668 1 .100 -ead 15 7.5 <1.0 <'1.0 Manqanese 800 400 853 1,330 1,390 1,010 t,170 1,130 Mercurv 2 1 <0.50 <0.50 ulolvbdenum 40 20 <10 <10 \ickel 100 50 <20 <20 ialaniilm 50 25 <5.0 <5.0 lilver 100 50 <10 <10 thallium 2 1 <0.50 <0.50 l-in 17.000 8.500 <1 00 < 100 Jranium 30 15 20-1 59-2 46.3 17.2 20.7 21.7 /anadium 60 30 <15 <15 Iinc 5,000 2,500 <10 <10 Radioloqics (pCi/L) iross Alpha 15 7.5 2.3 (0.6+/-)"2.9 (0.6+l) VOC (uc/L) \celone 700 350 <20 <20 <20 <20 <20 <20 Jenzene 5 2.5 <1.0 <1 .0 <1 .0 <1 .0 <1.0 <1 .0 l-Butanone (MEK)4,000 2,000 <20 <20 <20 <20 <20 <20 larbon Tetrachloride 5 2.5 <1.0 <1 .0 <1.0 <1 .0 <1.0 <1 .0 lhloroform 70 35 uro 584 13AO 1,6Ut 1,2@ 2,iln lhloromethane 30 15 <1.0 <1 .0 <1.0 <1.0 <1 .0 <1.0 )ichloromethane 5 2.5 15 15 66 47 33 110 rlaohlhalene 100 50 <1.0 <1 .0 <1.0 <1.0 <1 .0 <'1.0 letrahydrofuran (THF)46 23 NOV NOV <2.0 <2.0 <2.O <2.0 [oluene 1,000 500 <1 .0 <1 .0 <'1.0 <1 .0 <1 .0 <1.0 (vlenes(total)10,000 5.OOO <1-O <l.o <'l _o <1 .O <1 .0 <1_O Olhers :ield pH (S.U.)6.5 - 8.5 6.99 7.18 :luoride (mc/l)4 2 0.3 0.2 lhloride (moil)69 56 iulfate (mo/l)r.850 2.0't0 I-DS (mc/l)3.110 1.630 ieneral lnorqanics Listed in Part .E.1.(cX2) larbonate (mq/l)<1.0 <1 .0 licarbonate (mq/l)390 380 iodium (mq/l)194 228rotassium (mq/l)11.1 10.4 vlaonesium (mo/l)154 166 lalcium (mc/l)492 48B total anions (mec/L)47 49.6 total cations (meo/L)46.1 48.2 Concentrations in bold exceed the GWOS Concenirations shaded exceed ihe GWCL (a) = Monthly accelerated monitoring event. The gross alpha counting variance exceeded 20% MW-27 Concentrations shaded exceed the GWCL. The gross alpha counting variance exceeded 20%. Noi Sampled during 2nd Quarter (June) 2007. This well was sampled in July 2007 as part of a tlydrogeologic study performed by ihe University ot Utah. This study required undisturbed waier in this well for at least 2 months prior to sampling. Contaminant GWOS GWUL TBA 1 st qtr. 2007 Jan - March 311412007 Zndqlr.2007 April - June (")3rd qtr. 2oo7 July - Sept. 812812007 4th qtr. 2007 Oct. - Dec. 1012212007 1 st qtr. 2008 Jan - March 3l't712008 2nd qtr. 2008 April - June 61212008 Parameters Listed in Table 2 Nr rtrianle /mn/l \ \mmonia (as N)25 <0.05 <0.05 <0.05 <0.05 <0.05 tlitrate + Nitrite (as N)'10 5 5.2 5.2 5.4 6.26 Heaw Metals (uqil) \rsenic 50 <5.0 <5.0 <5.0 <5.0 <5.0 Seryllium 4 <0.50 <0.50 <0.50 <0.50 <0.50 ladmium 5 <0.50 <0.50 <0.50 <0.50 <0.50 lhromium 100 <25 <25 <25 <25 <25 lobalt 730 <10 <10 <10 <10 <10 lopper 1.300 <10 <10 <10 <10 <10 ron 11.000 <30 <30 <30 264 <30 -ead 15 <1 .0 <1.0 <1 .0 <1.0 <1.0 Vlanoanese 800 <10 <10 <10 <10 <10 Vlercurv 2 <0.50 <0.50 <0.50 <0.50 <0.50 vlolvbdenum 40 <10 <10 <10 <10 <10 tlickel 100 <20 <20 <20 <20 <20 ielenium 50 10.9 10.1 10.6 8.5 10.1 3ilver 100 <10 <10 <10 <10 <'10 fhallium 2 <0.50 <0.50 <0.50 <0.50 <0.50 l-in '17,000 <100 <'100 <1 00 <1 00 <1 00 Jranium 30 29.s s2 32.2 30.2 31.2 /anadium 60 <15 <15 <15 <15 <15 Zinc 5,000 <10 <10 <10 <10 <10 Radiolooics (oCi/L) Sross Alpha 15 <1 .0 1.4 (0.6+/-)-1 .0 (0.5+/-).2.0 @.4+l-\-1 .9 (0.5+/-) VOC (uq/L) \cetone 700 <20 <20 <20 <20 <20 Jenzene 5 <1 .0 <1 .0 <1 .0 <1 .0 <1 .0 2-Butanone (MEK)4 000 <20 <20 <20 <20 <20 larbon Tetrachloride 5 <1 .0 0 <1 .0 <1.0 <1 .0 lhloroform 70 <1.0 0 <1 .0 <1.0 <1 .0 lhloromelhane 30 <1.0 .0 <1 .0 <'1.0 <1 .0 )ichloromethane 5 <'1.0 0 <1 .0 <1.0 <1 .0 ,,laphthalene 100 <1.0 .0 <1 .0 <l.0 <l.0 [etrahydrofuran (THF)46 <10 <10 <10 <2.O <2.0 [oluene 1,000 <1.0 <1.0 <1 .0 <.1 .0 <1.0 (vlenes(total)10.000 <1 .O <1 _O <1-O <l.o <1.0 Others :ield pH (S.U.)6.5 - 8.5 7.64 7.50 7.44 8.10 7.55 :luoride (mo/l),4 0.8 0.8 0.7 0.8 0.8 lhloride (mq/l)Jt)35 37 37 39 iulfate (mc/l)420 452 406 428 453 I-DS (mc/l)1.050 1,040 1 .010 1,050 1,030 ieneral lnorqanics Listed in Part .E 1.(cX2)(ii) larbonate (mq/l)<1 .0 <1 .0 <'1 .0 <1 .0 <1 .0 Sicarbonate (mq/l)429 450 448 456 424 iodium (mc/l)78.9 74.5 74.'.|71 75.5 )otassium (mq/l)4.5 4.36 4.3 4.6 4.36 vlaonesium (mq/l)73.3 76 73.2 66.7 77.3 lalcium (mq/l)188 176 170 156 177 total anions (meq/L)17.2 18.2 17.2 17.9 18 total cations (meoil)18 18.4 17.8 16.5 18.6 MW-28 Contaminant GWQS GWCL TBA 1 st qtr. 2007 Jan - March l,l1qlroo7 2nd qtr.2007 April - June Rl20l2io7 (")3rd qtr. 2oo7 July - Sept. A12P-12o,n-7 4th qtr. 2007 Oct. - Dec. lnl2al2no7 'lst qtr. 2008 Jan - March 3t1212008 2nd qtr. 2008 April - June 6/3/2008 Parameters Listed in Table 2 Nutrients (mo/L) \mmonia (as N)25 0.11 0.09 <0.05 <0.05 <0.05 <0.05 tlitrate + Nitrite (as N)'t0 0.2 0.2 o.2 o.2 0.1 0.18 Heaw Metals (ucr/L) \rsenic 50 12.1 15 18.6 17.9 15.4 15.1 lervllium 4 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 )admium 5 1.84 3.27 3.34 3.36 3.4 3.22 lhr6miilm 100 <25 <25 <25 <25 <25 <25 lobalt 730 28 32 29 31 29 22 lopper 1.300 <10 <10 <10 <10 <10 <10 ron 11.O00 277 206 43 43 46 46 -ead l5 <1 .0 <1 .0 <1.0 <1.0 <1 .0 <1.0 Vlanganese 800 1.590 1-450 1.520,,1-/tat,.1-5/16 ,.s60 Vlercury 2 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 vlolybdenum 40 <'10 <'10 <10 <10 <10 <10 {ickel 100 32 30 26 29 23 26 ielenium 50 <5.0 5.5 5.3 5 <5.0 <5.0 iilver 100 <10 <10 <10 <10 <10 <10 lhallium 2 0.85 0.74 0.88 0.9 0.84 o.82 lin 17.000 <1 00 <1 00 <1 00 <100 <1 00 < ,l00 Jranium 30 2.69 4.56 3.67 3.4 3.'17 3.46 /anadium 60 <15 <15 <15 <15 <15 <15 Zinc s.000 32 37 80 48 34 38 Radiolooics (oCi/L) iross Aloha 15 -1 .5 (0.5+l "1.2 (O.4+l-\1.5 (0.6+/-)1.2 (0.5+l)1.2 (0.5+/-)1.3 (0.4+/-) VOC {uo/L) \cetone 700 <20 <20 <20 <20 <20 <20 Jenzene 5 <1 .0 <1 .0 <'l .0 <1 .0 <1 .0 <'l .0 2-Butanone (MEK)4.000 <20 <20 <20 <20 <20 <20 larbon Tetrachloride 5 .0 <1 .0 <1 .0 <1 .0 <1 .0 .0 lhlorotorm 70 0 <1 .0 <1 .0 <1 .0 <1 .0 0 lhloromethane 30 0 <1 .0 <1 .0 <1 .0 <1 .0 0 )ichloromethane 5 0 <1 .0 <1 .0 <l.0 <1 .0 0 tlaohthalene 100 0 <1 .0 <1 .0 <1 .0 <1.0 0 fetrahvdrofuran (THF)46 <10 <10 <10 <10 <2.0 <2.0 [oluene 'I .000 <1 .0 <1 .0 <1 .0 <1 .0 <1 .0 <1 .0 (vlenes(total)10.000 <1 .0 <1 .0 <1 .0 <1 .0 <1 .0 <1 .0 Others :ield oH (S.U,)6.5 - 8.5 6.65 6.64 .,e 97 a.4u .6.88 E Zt. :luoride (mc/l)4 0.6 0.6 0.7 0.6 0.6 0.6 lhloride (mo/l)97 94 95 99 99 103 iulfaie (mc/l)2.340 2.360 2.440 2.370 2.310 2.360 fDS (mcr/l)3.800 3.770 3.700 3.600 3.640 3.580 feneral lnoroanics Listed in Part E.'1.(c)(2Xii) larbonate (mc/l)<1 .0 <1.0 <1 .0 <1 .0 <1 .0 <1 .0 licarbonate (mq/l)139 't51 161 162 159 149 3odium (mcr/l)332 251 266 282 292 303 rotassium (mqil)'14.3 12.4 11.1 1',t.4 11.4 11.1 Maqnesium (mg/l)192 188 180 184 160 167 lalcium (mo/l)5'19 521 s30 s38 490 5'14 [otal anions (meq/L)53.9 54.3 56.1 54.8 53.5 54.5 f^tal ^ali^nc /men/l \56.7 54.6 53.2 54.6 50.8 52.9 Concentraiions shaded exceed the GWCL. The gross alpha counting variance exceeded 20%. MW-29 Concentrations shadod exceed the GWCLt The gross alpha counting variance exceeded 20%. Not Sampled during 2nd Quarter (June) 2007. This well was sampled in July 2OO7 as part of a hydrogeologic strdy perfornEd by the Universiiy of Uiah. This study reguired undisturbed water in this well tor al leasl 2 monlhs prior to sampling. Contaminant GWOS GWCL TBA 1 st qtr. 2007 Jan - March 2l't6.l2n,n7 2ndqlr.2007 April - June (")3rd qtr. 2oo7 July - Sept. 812212007 4th qtr. 2007 Oct. - Dec. 1012412007 1 st qtr. 2008 Jan - March 3/1 9/2008 2nd qtr. 2008 April - June 61312008 Parameters Listed in Table 2 Nutrients (mc/L) A.mm^nia las N)25 0.84 0.83 0.79 0.8 0.53 rlitrate + Nitrite (as N)10 <0.1 <0.1 <0.1 <o.1 <o.05 Heaw Metals (uc/L) qrsenic 50 <5.0 <5.0 <5.0 <5.0 <5.0 Seryllium 4 <0.50 <0.50 <0.50 <0.50 <0.50 ladmium 5 <0.50 <0.50 <0.50 <0.50 <0.50 lhromium 100 <25 <25 <25 <25 <25 lobalt 730 <10 <10 <10 <10 <10 lopper 1,300 <10 <10 <10 <10 <10 ron 11,000 1.500 1.200 1.110 1 3aO 1,400 -ead 15 <-1.0 <1 .0 <1.0 <1 .0 <1 .0 Manoanese 800 5,@A 4.790 4.9ij0 4;830 5.260 Vlercury 2 <0.50 <0.50 <0.50 <0.50 <0.50 Volvbdenum 40 <10 <10 <10 <10 <10 Nickel 100 <20 <20 <20 <20 <20 Selenium 50 <5.0 <5.0 <5.0 <5.0 <5.0 Silver 100 <10 <10 <10 <10 <10 lhallium 2 <o.50 <o.50 <0.50 <0.50 <0.50 l-in 17,000 <'100 <1 00 <100 <1 00 <t00 Jranium 30 11.2 11.9 11.1 11.1 10.3 /anadium 60 <15 <15 <15 <15 <15 Iinc 5.000 13 13 15 21 22 Radiolooics (oCi/L) iross Alpha 15 1 (0.5+/-)1.1 (0.5+/-)<1.0 -2.1 (0.5+/-)1 1 (0.4+/-) VOC (uc/L) \cetone 700 <20 <20 <20 <20 <20 Jenzene 5 <1 .0 <1 .0 <1_0 <1 .0 <1 .0 2-Butanone (MEK)4.000 <20 <20 <20 <20 <20 )arbon Tetrachloride q <1 .0 <1 .O <1_0 <1 .0 <1 .0 lhloroform 70 <1 .0 <1.0 <1.0 <'l .0 <'l .0 ,-hloromethane 30 <1 .0 <'1.0 <1.0 <1 .0 <1 .0 )ichloromethane 5 <1.0 <'l _0 <1 .0 <1 .0 <1 .0 {aphthalene 100 <1 .0 <'l .0 <1 .0 <l.0 <1 .0 etrahvdroluran (THF)46 <10 <10 <10 <2.O <2.O foluene 1.000 <1.0 <1 .0 <1 .0 <1 .0 <1 .0 (vlenes(total)10.000 <1_O <'l -o <1 .0 <1 .0 <1 .0 Others;ield oH (S.U.)6.5 - 8.5 6.63 7.03 6.87 7 _46 6.98 :luoride (mc/l)4 0.9 1 0.8 0.8 0.8 lhloride (mo/l)39 37 37 39 38 lulfate (mc/l)2.780 2.790 2,790 2,840 2,840 fDS (mo/l)4.520 4,400 4 370 4,430 4.190 Seneral lnoroanics Listed in Part E.1.(c)2)(ii) larbonate (mo/l)<'1.0 <1.0 <'1.0 <'l .o <1 .0 licarbonate (mc/l)323 340 338 345 321 Sodium (mc/l)433 440 425 466 486 )otassium (mo/l)'t7.3 16.4 17.3 17.2 16.8 Maonesium (mcr/l)236 234 240 206 218 )alcium (mq/l)505 493 510 461 470 [otal anions (meq/L)64.4 64.7 64.6 65.9 65.5 [nlal nalinnq Imen/l \64.4 63.8 64.5 61 .1 bJ MW-30 Concentralions shaded exceed the GWCL. The gross alpha counting variance exceeded 207". Not Sampled during 2nd Ouarter (Jun€) 2007. This well was samplad in July 2OO7 as part of a hydrogeologic study porformed by the University ot Utah. This study required undislurbed water in this well ,or al least 2 monlhs prior to sampling. Conlaminant GWOS GWCL TBA 1 st qtr. 2007 Jan - March 311512007 2nd qtr. 2007 April - June (')3rd qtr. 2oo7 July - Sept. 812212007 4th qtr. 2007 Oct. - Dec. 1012412007 1st qtr. 2008 Jan - March 311912008 2nd qtr. 2008 April - June 61312008 Parameters Listed in Table 2 Nutrients (mc/L) \mmonia (as N)25 <0.05 0.08 <0.05 <0.05 <0.05 tlitrate + Nitrile (as N)10 14.4 14:6 14.9 14-8 ,8-7 Heaw Metals (uo/L) \rsenic 50 <5.0 <5.0 <5.0 <5.0 <5.0 lervllium 4 <0.50 <0.50 <0.50 <0.50 <0.50 ladmium 5 <0.50 <0.50 <0.50 <0.50 <0.50 lhromium 100 <25 <25 <25 <25 <25 lobalt 730 <10 <'10 <10 <10 <10 lopper 'I .300 <10 <'10 <10 <10 <10 ron 11.000 58 127 125 141 135 -ead 15 <1 .0 <1 .0 <l.0 <1.0 <1 .0 Manqanese 800 21 46 54 45 49 Mercury 2 <0.50 <0.50 <0.50 <0.50 <0.50 Molybdenum 40 <'10 <10 <10 <10 <10 \,lickel 100 <20 <20 <20 <20 <20 Selenium 50 31 .2 30.4 29.8 30.5 30,5 Silver 100 <10 <10 <10 <10 <10 Ihallium 2 <0.50 <0.50 <0.50 <0.50 <0.50 Iin 17.000 <100 <1 00 <1 00 <1 00 <1 00 Jranium 30 6.99 7.09 6.88 6.79 6.86 y'anadium 60 <15 <15 <15 <15 <15 linc 5.000 <10 <10 <10 <10 <10 Radiolooics (oCi/L) iross Aloha 15 <1.0 <1 .0 <l.0 1.0 (0.3+/-).0.8 (0.3+l) VOC (uc/L) \cetone 700 <20 <20 <20 <20 <20 lenzene 5 <1.0 <1 .0 <1 .0 <1 .0 <1.0 2-Butanone (MEK)4.000 <20 <20 <20 <20 <20 larbon Tetrachloride 5 <1.0 <1 .0 <1 .0 <1 .0 <1 .0 lhloroform 70 <1.0 <1 .0 <1 .0 <1"0 <1 .0 )hloromethane 30 <1 .0 <1 .0 <1 .0 <1 .0 <1 .0 )ichloromethane 5 <1 .0 <1 .0 <1 .0 <1 .0 <1.0 {aphthalene 100 <1 .0 <1 .0 <1 .0 <1.0 <1 .0 letrahvdrofuran (THF)46 <10 <10 <10 <2.0 <2.O foluene 1.000 <1 .0 <1 .0 <1 .0 <1 .0 <1 .0 (vlenes(total)10.o00 <1 .0 <1 .0 <1 .0 <1 .O <.1.0 Others :ield pH (S.U.)i.5 - a.l 6.85 7.16 7.43 7.90 7.51 :luoride (mq/l)4 0.4 0.4 0.3 0.4 0.4 )hloride (mq/l)125 126 122 118 12s iulfate (mo/l)838 852 871 853 842 IDS (mc/l)1.690 1.700 1.660 1 ,610 1.500 General lnoroanics Listed in Part 1.E.1.(c)(2)(ii) larbonate (ms/l)<1.0 <1.0 <l.0 <1 .0 <1.0 licarbonate (mq/l)190 193 197 197 r80 iodium (mc/l)102 108 110 108 109 )otassium (mq/l)8.2 7.3 8.1 7.8 7.29 Vlaonesium (mc/l)73.7 72.3 72.9 68.9 71.3 lalcium (mq/l)288 286 294 270 274 folal anions (meq/L)25.1 25.5 2s.9 25.4 25.4 fotal cations (meq/L)2s.1 25.1 25.7 24.1 24.7 MW-31 Concentralions shaded exceed lhe GWCL- The gross alpha counling variance exceeded 20%. Not Samplod during znd Ouarler (Jurle) 2007. This well was sampled in July 2007 as part of a hydrogeologic study pertormed by lhe Univorsity of Utah. This siudy rcquired urdislurbed water in lhis well tor al least 2 months prior to sampllng. Contaminant GWQS GWCL TBA 1st qtr. 2007 Jan - March 311512007 zndqtr.2007 April - June (")3rd qtr. 2oo7 July - Sept. a12712007 4th qtr. 2007 Oct. - Dec. 1012412007 1 st qtr. 2008 Jan - March 1/1 q/2nnA 2nd qtr.2008 April - June 6/3/2008 Parameters Listed in Table Nutrients (mc/L) \mmonia (as N)25 <0.05 <0.05 <0.05 <0.05 <0.05 {itrate + Nitrite (as N)10 22 23.3 .24.6 25 29.3 Heaw Metals (ucr/L) \rsenic 50 <5.0 <5.0 <5.0 <5.0 <5.0 leryllium 4 <0.50 <0.50 <0.50 <0.50 <0.50 ladmium 5 <0.50 <0.50 <0.50 <0.50 <0.50 )hromium 100 <25 <25 <25 <25 <25 lobalt 730 <10 <'10 <10 <10 <10 lopper 1,300 <10 <10 <10 <'10 <10 ron 11,000 <30 <30 <30 <30 <30 -ead 15 <1 .0 <1 .0 <1.0 <1 .0 <1.0 Vlanqanese 800 <10 <10 <10 <10 <10 Vlercury 2 <0.50 <0.50 <0.50 <0.50 <0.50 vlolybdenum 40 <10 <10 <10 <10 <10 {ickel r00 <20 <20 <20 <20 <20 ielenium 50 59.2 60.8 56.6 54.4 55,3 iilver 100 <10 <10 <10 <'10 <10 l-hallium 2 <0.50 <0.50 <0.50 <0.50 <0.50 l-in 17,000 <1 00 < 100 <1 00 <1 00 <100 Jranium 30 7.60 7.18 7.2 7.O2 6.95 /anadium 60 <'15 <'15 <15 <15 <15 linc 5,000 <10 <10 10 <10 <10 Radioloqics (pCiil) iross Alpha 15 <1 .O .1.4 (0.6+/-)<1 .0 1.7 (O.4+l-\1.3 (0.4+/-) VOC (uc/L) \cetone 700 <20 <20 <20 <20 <20 Jenzene 5 <1 .0 <1 .0 <1 .0 <1 .0 <1 .0 2-Butanone (MEK)4,000 <20 <20 <20 <20 <20 larbon Tetrachloride 5 <1 .0 .0 <1 .0 <1 .0 <1.0 lhloroform 70 <1 .0 .0 <1.0 <1.0 <'1.0 )hloromethane 30 <l.0 .0 <1 .0 <1-0 <1 .0 )ichloromethane 5 <1 .0 .0 <1 .0 <1.0 <1 .0 {aphthalene 100 <1 .0 .0 <1 .0 <1.O <1 .0 letrahvdrofuran (THF)46 <'10 0 <10 <2.O <2.0 foluene 1,000 <1 .0 <1-0 <1 .O <1_O <l.0 (vlenes(total)10.o00 <1 .0 <1 .O <1 .0 <'l.o <1 .0 Others :ield pH (S.U.)6.5 - 8.5 6.79 7_29 7.62 7.98 7.65 :luoride (mo/l)4 0.9 1 0.8 0.9 0.9 lhloride (mo/l)132 136 122 124 128 iulfate (mq/l)516 s32 497 521 514 I-DS (mq/l)1.24O 1.240 1 _150 1.220 1.180 ieneral lnorqanics Listed in Part E.1.(cX2)(ii) larbonate (mq/l)<1 .0 <1.0 <1 .0 <1 .0 <1 .0 licarbonate (mq/l)210 210 209 212 197 lodium (mq/l)94.6 93.1 93.3 91 93.7 )otassium (mq/l)b.b 6.23 6.4 6.2 5.96 Vlaqnesium (mq/l)86.1 B5.B 83.8 78.2 80.8 lalcium (mq/l)17'l 178 172 161 163 I-otal anions (meo/L)19.5 20.1 19 19.7 19.7 fotal cations (meo/L)19.9 20.1 19.7 18.6 19 MW-32 Contaminant GWQS UWUL (Class lll)January (")Monthly Accl. 112912008 February (")Monlhly Accl 21201200a 1 st qtr. 2008 Jan - March ?l1rlroo9, .April (")Monthly Accl. atralro A May (")Monthly Accl. E.11il2n,o,q 2nd qtr. 200t Jan - March alql2nnR Parameters Listed in Table 2 Nutrients lmo/L) \mmonia (as N)25 12.5 0.62 0.5 litrate + Nitrite (as N)10 5 <0.1 <0.05 Heaw Metals (ucr/L) \rsenic 50 25 <5.0 <5.0 leryllium 4 2 <0.50 <0.50 ladmirrm 5 2.5 1.32 <0.50 1.9 3 2.08 2.21 lhromium 100 50 <25 <25 lobalt 730 365 51 42 lopper 1,300 650 <'10 <10 ron 1.1,000 5,500 7,920 7;890 s.370 9,040 9,410 8,650 -ead 15 7.5 <1 .0 <1.0 Manqanese 800 400 4,950 s,010 5,660 5,500 5.810 5,4U' VIercury 2 1 <0.50 <0.50 Vlolvbdenum 40 20 11 10 rlickel 100 50 62 59 59 61 64 62 Selenium 50 25 <5.0 <5.0 Silver 100 50 <10 <10 fhallium 2 1 <0.50 <0.50 fin 17.000 8.500 <1 00 <1 00 Jranium 30 15 3.01 3.05 /anadium 60 30 <15 <15 Iinc 5.000 2.500 149 12s Radiolooics (oCiil) iross Alpha 15 7.5 5.3 (0.9+/-)9,2 fi.2+l-l -2.8 (0.6+/-)3.4 (0.6+l)4.0 (0.8+/-)3.5 (0.6+/-) VOC (uq/L) \celone 700 350 <20 <20 Jenzene 5 2.5 <1.0 <1.0 lButanone (MEK)4,000 2,000 <20 <20 larbon Tetrachloride 5 2.5 <1 .0 <'1.0 lhloroform 70 35 <1.0 <1.0 )hloromethane 30 15 <1.0 <1.0 )ichloromethane 5 2.5 <1 .0 <1.0 {aphthalene 100 50 <1.0 <1 .0 I-etrahydrofuran (THF)46 23 <2.0 <2.O [oluene 1.000 500 <1.0 <1 .0 (vlenes(total)'t 0.000 5.O00 <1.0 <1 .0 Others :ield pH (S.U.)6.5 - 8.5 6.89 6.59 :luoride (mg/l)4 2 o.2 o.2 )hloride (mq/l)30 32 iulfate (mo/l)2.420 2.430 l-DS (mo/l)3.800 3.550 ]eneral lnoroanics Listed in Part .E.1.(c)(2) larbonate (mq/l)<1 .0 <1 .0 licarbonate (mo/l)43s 407 iodium (mq/l)233 232 rotassium (mc/l)14.9 14.6 vlaonesium /mo/l)234 234 )alcium (mq/l)526 529 [otal anions (meq/L)58.4 58.1 fotal cations (meo/L)56.7 56.2 Concentrations in bold exceed the GWQS Concentrations shaded exceed the GWCL (a) = Monthly accelerated moniloring eveni. The gross alpha counting variance exceeded 20% ATTACHMENT 1 Documentation of Additional Sampling of MW-4 During the 2"d Quarter, 2008 t I I I I T I : I I t I I I I I t I I Mill - GmundwaterDischarge Penuit Groundwfier Monitoring Quality Assurance Plan (QAP) Date: 2.25 -Ul Revision: 2 Page ztO of 4I AXTACIIMENTl WIIITE MFSA I'RANI{'M MILL Locarion (well name). A{.\0 L\ Nau,re and initiats TH - Date andTime forPurging g / *l /of and Sampling(if different)- pHBuffer 7.0 1.O Welt purging Equip Used: y'pu*p or -bailer Well Pump (if other than f**rDGroOAhS 'Lo"tt)' Sampling gysnt (rroonrl \,O*\ar kev. Well Sampled in SamplingEvent-$r^J}6 pHBuffer4.o q.q- SpecificConductance-it{ -uMHoS/cm WettDep*t 143'6 -- Depth to Water Before Purgin CasingVolume (V)4'Yllcll: , (.653h) 3" Well: (36?h) Conduchnce (avg)- Well WaterTemP. (avg)-RedoxPotential (Eh)--'furbidity Weatler Cond. a l car 4 5,^,.n *b Ext'l Amb. Temp.(prior to sampling evsn0-ag'oc (,- t ft ".--lS Gal.Purged- Conductaoce l* Li l Temperatue rt.53 Redox Potential Ctrl-}jU-- rwbidiry [,3l Tipe:--.=---.*-Gal,Purged -. ,. Conductance- Redox Porential (Eh)- TurbiditY "r - p TemperaEue- Time:- Gal. Purged Conductance- Time:- Gal. Purged- ('nnrlur:tance Redox Potential (Ett)- Redox Potential (Eh)- l. Paged,l of 4l [&ll - Grousdwater Diseharge Permit Groundwater Moritoring Quality Assurarce Plan (QAP) TurbiditY Datg 11.17.06 Revision: I l' I I I I I I I ; I I I I ; ; I ; ; ! Turbidity -.-' Volume of Water Purged When Field Parametefs are Measured -----==-:- PumpiEg Rafe Calculation FlowRate (Q), ing1m.Time to evacuate hpo casing volumes (2V) T=2VlQ= Numberof casingvolurues evacuated (if other fimn two) If woll evacuated to drlmess, uumberof gallons evacuated '--------:--:=- Nameof CertifiedAnalyticatLaboptory if OtherThatBn*gyLrfr, Qq'c.'5t rf-*JOf\ to*l'lo &UJL Tvneof $ample $arnole T.akep (dIEISI SriiiuiJeYo,tume flnilleate if other X'ilhred (circle) Precervstive Added (circle) 'thtiit as specified helnwl vo(b Y) N 3x40ml Y HCX, ff) N Nufrients N l00ml Yffi/HrSgr Gl N HeawMetals N 250hl Y)N HNO' (ts) N All Othcr Non- Radiolosics g)N 250ml g/N NoPreservative Addsd GrossAtplu (r) N 1-000ml Y C{l E,SO. ^ fY) N Other(speciff)UN Sauplevolume YA[,qU Ifa preservative is use4 SpecifyTlpe and Quantity of Preservative: I ,5f FEf {,t3i,?Ef,Giti!f;,;'f i;!t:tr!i#!':UWA":;?,*#;.trf :t:i,#f !#' I T I I ANALYTICAL SUMMARY REPORT July 07, 2008 Denison Mines (USA) Corp 6425 S Hwy 191 Blanding, UT 84511 Workorder No.: C08051285 Quote lD: C1640 - POC Wells / Monthly Groundwater Sampling Project Name: 2nd Quarter Semi-Annual Groundwater Energy Laboratories, lnc. received the following 9 samples from Denison Mines (USA) Corp on 5/30/2008 for analysis. I Sample lD Client Sample lD Collect Date Receive Date Matrix c08051285-001 MW 3 i 05/28/08 08:30 05/30/08 Aqueous Metals by ICP/ICPMS, Dissolved Alkalinity QA Calculations Chloride Fluoride Nitrogen, Ammonia Nitrogen, Nitrate + Nitrite pH Gross Alpha minus Rn222 and Uranium Solids, Total Dissolved Sulfate SW8260B VOCs, Standard List : c08051285-002 MW3A 1 05/28/08 09:35 05/30/08 Aqueous Same As Above c08051285-003 MW26 - 05127108 14:20 05/30i08 Aqueous Same As Above c08051285-004 MW4 - 05127t08 15:05 05/30/08 Aqueous SameAsAbove c0805128+005 MW70 y\ oslzatoa 14:40 oE/30/08 Aqueous Same As Above c0805'128$006 MW 60 ) 05/28/08 10:32 05/30/08 Aqueous Same As Above c08051285-007 MW24 .- 05/29/08 07:15 05/30/08 Aqueous Same As Above c08051285-008 MW 17 C08051285-009 Trip Blank 05/28/08 14:40 05/30/08 Aqueous SameAsAbove 05/29/08 0O:00 05/30/08 Aqueous SW8260B VOCs, Standard Lisl I : I I I I I I I I T F As appropriate, any exceptions or problems with the analyses are noted in the Laboratory Analytical Report, the QA/QC Summary Report, orthe Case Nanative. lf you have any questions regarding these tests results, please call. ReportApproved By: d^* rK ill%.. ;J oIl otfl oEEl-oOH EE E,ZsEaEOPrI=JY ETEortrE IE: .E$ .)g IEHC8<a!r5s'EL.! tE Eb >Et, =,o=flL.,, ErtoJgoE lLooE trF EU OH IHH F oLz_r Etsa6c ifr> ,q J) o5o f o L t(t- EL,I P; ,q; t P -.nI >Fd_ h'a Hdu2a \j. 6 3 3o \b J( c ... z -Lrdt5:g) tE *l E;E l*t aE r ls] TE fi I€ EEE IE {, uvDpunoEurnlHsnu aat c6 54f--, {l{1, -*t-3t-t 7a gtTI \a S.ND R<5rc(, Eb-Ed rst|lo ABsseotg X uone|a6sn sprtos/sUoS repM 4Y Fg g 1g 1y1y:ed,{1e1dueg E o o o-t,ED c-oE oot '-:. J -i-1 0 YP opP <iEi, Jcu Crlt.0 < l!E otr 8H nE-9 ()'6S< ,&H E 6T cp{uip.,xIlfi<cCdo-a 6 EEI!, otri Cc./l'e q) C) EE;E 6#=ut Eo Eo,Eo o6boE6! o oE Ee€v6oa o-!6 b --ec^h .EEi! E9.o-€a;E€E =roo-t> OGtoEEet!=*; E*EEo-aro€g0tr3f>t!a!lE6 E< o!io=EA9A.Et Oo.€gJT B;LOOlEt)utE^o IEEllol= otE>l€ Et;e,I o.9lorlE_l-IEI6l6t-l6lolaJIElsl6 lsloI!t: IElot; I DENISOJ}## ilIINES CHAIN OF CUSTODY Samples Shipped to: American West Analytical Labs 463 West 3600 South Chain of Custodylsampling Analysis Request ?,lboy.- Name ,,//?t Elws. emperature Failu From: To: CC: Date: Subject: Dane, Loren Morton Dane Finerfrock David Frydenlund; Dean Henderson; Phillip Goble; Steve Landau Blt9l2008 4:32 PM Denison Mines: Verbal Notice for VOC Temperature Failures in June Sampling Event Dave Frydenlund and Steve Landau just called to report that some quarterly THF samples collected on 6/18/08 were sent to AWAL here in SLC. Upon arrival at AWAL they were found to be between 1 and 5 C. Of course some of those samples were greater than the 4 C required by the QAP. Dave and Steve were calling to provide verbal notice of the non- compliance under the Permit. Dave also said he has been doing some research and has found that the EPA SW-846 method for VOCs now only requires the sample to arrive at the lab under 6 C. Dave explained that DUSA is planning on asking for a QAP change to get those 2 extra degrees. I told DUSA that they are welcome to ask for a QAP change at anytime, just send in a written request with a redline / strikeout version of the currently approved QAP. Dave also said they have made several changes of late to improve their ability to comply with the sample temperature requirements, these included: 1, Using regular ice, instead of Blue Ice to cool the samples (Blue Ice was used previously) 2. Do sampling earlier in the quarter - so as to allow more time for re-sampling (if needed), 3. Do sampling earlier in the week, and use overnight shipping to get the samples to the lab on a business day - so they don't set on a loading dock, un-refrigerated, over the weekend. 4. DUSA calls the lab early on - to confirm the sample temperature on arrival at the lab. Dave repoded he will send in a written notice about this problem - as the Permit requires - within 5 days. On a different note, DUSA got our 8/U08 Notice of Agency Findings letter - regarding the VOC'sample temperature problems for the April and May, 2008 samples (in response to lhe 717 108 DUSA written notice and claim of affirmative defense). Dave said he understood why he didn't meet the affirmative defense criteria, and that the DRC was leaving the door open for them to qualify for it on those April and May samples. He said he would soon provide a new letter that would outline what they have already done to solve the temperature problem. Presumably, it would include the 4 points above. Dave recognized that DUSA's earlier conclusion that the lack of 5-day coolers was the entire root cause, and that there were other factors that needed to be fixed (hence the 4 points made above). Dave repofted that sample temperature results from July have been better. I told Dave that we would have to see the written reports to confirm all that, but that I was encouraged to hear about these recent improvembnts. Also, Dave acknowledged receipt of the 8/4/08 DRC NOV regarding the sample temperature problems for the March, 2008 sampling event. He acknowledged that issuance of NOV meant it was too late for affirmative defense for those samples. I reiterated the wording in the NOV, that we are not currently considering a monetary penalty for the March, 2008 sampling event, provided the problem is fixed in a timely manner. If you have questions about this phone call, please let me know. Loren JoNM.,rlro*,r* Govemor GARY HERBERT Lieutenant Govemor State of Utah Department of Environmental Quality Richard W. Sprott Executive Director DTVISION OFRADIATION CONTROL Dane L. Finerfrock Director I Augus "ommm Mr. David C Frydenlund Vice President and General Counsel Denison Mines (USA) Corp. (DUSA) 1050 Seventeenth St. Suite 950 Denver, Colorado, 80265 SUBJECT: "J:'::: re BeceiprFee th$@ 1_"1,1!1r"yolr": I I Fq;{SUBJECT:JULYT.200SOUSAARGUMENTSFOR', Ul'AFFTRMATvE DErervse neGeioiNo iirriieiqrune \<ji-l --o EOtftf t3 (FEIEIEt Ef July 7,2008 DUSA Arguments for Affirmati { Exceedances, April und Muy, 2008 Accelera t Denison Mines (USA) Corp. (DUSA) White Notice of Agency Findings EXCEEOANCES. APRIL AND MAY, 2OO8 ACCELERATEOGRoUNDWATERMoNIToRING EVENT, DENISoN IMINES (USA) CORP. (DUSAI WHTTE MESA U&qNTUM I MILL NEAR BLANDING. UTAH: NOTICE oF AGENCY FlNDINGS/PG DAVIO FRYDENLUND DENISON MINES (USA} CORPORATION INOEPENDANCE PLAZA STE 950 1O5O 17TH ST DENVER CO 80255 EIEtEr\- Dear Mr. Frydenlund On July 3,2W8 DUSA notified (by phone) the DRC that two sets of samples were received and accepted by its analytical laboratory at temperatures greater than the maximum allowed temperature of 4"C for VOCs. These two sets of samples were received at 5oC and 6oC for the April and May, 2008 accelerated monitoring events, respectively. It appears that these temperature exceedances are violations of Part I.E.1(a), Part tr.A of the Permit, and Table 1 and Section 9.3(d) of the approved DUSA QAP. DUSA written notification of the temperature exceedances was provided to the DRC by e-mail on July 7,2008.In the July 7, 2008 notice DUSA argues that Affirmative Defense set out in Part I.G.3(c) of the Permit should be applicable to these temperature exceedances for the following reasons: DUSA submitted verbal notification of the temperature exceedances on July 3,2008 and written notification on July 7 ,2008 according to UAC-R3 17 -6-6.13 The failure was not intentional or caused by Permitee negligence, either in action or in failure to act, The Permittee has taken adequate measures to meet Permit conditions in a timely matter or has submitted to the Executive Secretary, for the Executive Secretary's approval, and adequate plan and schedule for meeting Permit conditions, and Provisions of UAC 19-5-107 have not been violated. 168 North 1950 West . FO Box 1,14850. Satt take City, [.rT 841l4-4E50. phone (801) 5364250. fax (801) 533-4OC7 T.D.D. (801) 5364414. www.deq.utah.gov Prinled on 100% recvcled paper t. 2. 3. 4. o.9 oo cl c =oE ctttro3 o:o !E(E.c c.opq (l, tn o o oE cotloo E Eoo UIq ult!oq{zlGlfl ulltrl fo o SENDER:r Comolete iterns 1 and/or 2 for additional services.r Complete items 3, 4a, and 4b.r Print your name and address on the reverse of this form so that we can return thiscard to vou.r Attach this form to the front of the mailpiece, or on the back if space ooes nol oermit..W(ite "Return Receipt Requested"on the mailpiece belDw the article number.r The Return Receipt will show to whom the article was delivered and the date SUBJECT: JULY 7.2008 DUSA ARGUMENTS FOR AFFIRMATIVE DEFENSE REGARDING TEMPERAruRE EXCEEDANCES. APRIL AND MAY,2OO8 ACCELEMTED GROUND WATER MONITORING EVENT, DENISON MINES (USA) CORP. (OUSAI WHITE MESA UMNIUM MILL NEAR BrANDING. UTAH: NOTICE OF AGENCYrwoney'fr,bofik onvro rnvdEriiur'ro DENISON MINES (USA} CORPORATION INDEPENDANCE PLAZA STE 950 1050 17TH ST DENVER CO 80265 4a. Article Number Service ype I also wish to receive the following services (for an extra fee): 1. E Addressee's Address 2. I Restricted Delivery Consult Dostmaster for fee. D Registered E Exuess Mail'JaLl Retufir Receiotfor Merchandise lQertifiedLl lnsured E coo 0 6 2001 B. Addressee's Address (Only if requested aflftfgn/pdard) Radialion Contot PS Form 1jDecember1994 1o2ses-e8-B-022e DOmeStiC RetUrn ReCeipt Urureo SrnrEs Posrt SeRvtce First-Class Mail Postage & Fees Paid USPS Permit No. G-10 UTAH DEPARTMENT OF ENVIRONMENTAL QUALIry DIVISION OF RADIATION CONTROL P O BOX 144850 SALT LAKE CIry UT 84114-4850 o Print your name, address, andZlP Code in this box o 1- fli,,: If you have any questions or corrments regarding this letter, please contact Phil Goble at (801) 536- 4044. UTAH WATER QUALITY BOARD DLF/PRG:prg cc: M.M. Hubbell, Utah Attorney General's Office F:/DUSA/2,d Q'IR 2008 CW Sampling File: DRC Findings of April & May Temp Exceedances.doc From: To: CC: Date: Subject: Attachments: Steve Landau <Slandau@denisonmines.com> Phillip Goble <PGOBLE @ utah.gov> Loren Morton <LMORTON@utah.gov>, David Frydenlund <DFrydenlund@denisonmi... 10/13120082:47 PM MW-4 Results MW 4 5-27-08.pdf Hello Phil.....here are the results for MW-4 sampled on 5-27-08 Regards Steve Steve Landau Manager, Environmental Affairs t: (303) 389-4132 I f: (303) 389-4125 1050 17th Street, Suite 950, Denver, CO 80265 DENISON MINES (USA) CORP www.denisonmines.comchttp://wtlw.denisonm ines.com/> This e-mail is intended for exclusive use the person(s) mentioned as the recipient(s). This message and any attached files with it are confidential and may contain privileged or proprietary information. lf you are not the intended recipient(s) please delete this message and notify the sender. You may not use, distribute print or copy this message if you are not the intended recipient(s). ,*rrnrrnrOr),rr, tNC. .zssssattCreekHrghway(8260rr,r, ,)o , Casper; wY82602 Toll Free 888.235.0515 , 307.235.0515 ' Fax 307.234. 1639 ' casper@anergylab.com ' www.energylab.con Client: Project: Lab lD: Client Sample lD LABORATORY ANALYTIGAL REPORT Denison Mines (USA) Corp 2nd Quarter Semi-Annual Groundwater c0805128$004 MW4 Report Date: 07/07/08 Collection Date: 05/27108 15:05 DateReceived: 05/30/08 Matrix: Aqueous Amlyses Result Units Qualiflers RL MCUQCL Method Analysis Date / By MAJOR IONS Carbonate as CO3 Bicarbonate as HCO3 Calcium Chloride Fluoride Magnesium Nitrogon, Ammonia as N Nitrogen, Nitrate+Nikite as N Potassium Sodium Sulfate PHYSICAL PROPERTIES pH Solids, Total Dissolved TDS @ 180 C METALS. DISSOLVED Arsenic Beryllium Cadmium Chromium Cobalt Copper lron Lead Manganese Mercury Molybdenum Nickel Selenium Silver Thallium Tin Urenium Vanadium Zinc RADIONUCLIDES - DISSOLVED Gross Alpha minus Rn & U Gross Alpha minus Rn & U Precision (t) Gross Alpha minus Rn & U MDC ND mg/L 330 mg/L258 mg/L 44 mgiL 0.4 mg/L 114 rng/LND mg/L 6.50 mg/L 6.64 mg/L 82.6 mg/L 832 mg/L 7.2O s.u. 1550 mg/L ND ug/L ND ug/LND ug/LND ug/L ND ug/L ND ugiL ND ug/LND ug/LND ug/LND ug/L ND ug/LND ug/L46.4 ug/LND ugll ND ug/L ND ug/L 9.10 ug/LND ug/L ND ug/L 0.E 0.3 0.3 A232A B 42324 B 8200.7 44500-Cl B A4500-F C E200.7 E350.1 E353,2 E200.7 E200.7 A4500-so4 E 8200.8 E200.8 E200.8 E200.8 E200.8 E200.8 8200.7 8200.8 E200.8 E200.8 E200.8 E200.8 E2OO,E E200.8 E200.8 E200.8 8200.8 E200.8 E200.8 E900.1 E900.1 E900.1 1 1 0.52 1 0.1 0.50 0.05 0.05 0.50 3.8 10 0.01 10 5.U 0.50 0.50 25 10 10 30 1.0 10 0.50 10 20 5.0 10 0.s0 100 0.30 15 10 A4500-H B 0s/30/08 16.21 t ih A2540 C 06/02/08 09:19 /dd 06i03/08 14:37 I tjl 06/03/08 14:37 I \l 06/16/08 16:05 / cp 06/06/08 15:33 / ljl 06/04/08 13:51 / ljl 06/15/08 l6:05 / cp 06/05/08 08:28 / eli-b 06/10/08 10:54 i eli-b 06/'i6/08 16:05 / cp 06/16/08 16:05 / cp 06/03/08 16:47 / sp 06/1 1/08 06:54 / sml 06/1 ,/08 06:54 / sml 06/11/08 06:54 / sml 06/11/08 06:54 / sml 06/11/08 06:54 / sml 06/11/08 06:54 / sml 06/09108 2A:29 I cp 06/11108 06:54 / sml 06/11/08 06:54 / sml 06/11/08 06:54 / sml 06/'11l08 06:54 / sml 06/11/08 06:54 / sml 06/1 1/08 06:54 / sml 06/11/08 06:54 / sml 06/1 1/08 06:54 i sml 06/1 1/08 06:54 / sml 06/11/08 06:54 / sml 06/11/08 06:54 / sml 06/1 1/08 06:54 / sml 06/18/08 12'.13 I cN'l 06/18/08 12.13 / crw 06/18/08 12:13 / cnar pCiiL pCiiL pCi/L R€port RL - Analyte reporting limit. Definitions: eCL - euality control timit. MDC - Minimum detectable concentration MCL - Maximum contaminant level. ND - Not detecled at the reporting limit. D - RL increased due to sample matrix interference mIIW ,*rru, *rot,rt tcc. . 23ss salt creek Highway (8260,, , ,.o. ,)u, ' caspet; vw 82602 Toll Free 888.235.0515 . 307.235.0515 . Fax 307.234.1639 ' casper@energylab,com ' wwwenergylab,com Client: Project: Lab lD: Client Sample lD LABORATORY ANALYTICAL REPORT Denison Mines (USA) Corp 2nd Quarter Semi-Annual G roundwater c08051285-004 MW4 Report Date: 07/07/08 Collection Date: 05127108 15:05 DateReceived: 05/30/08 Matrix: Aqueous Analyses Result Units Qualifiers RL MCUQCL Method Analysis Date / By DATA QUALITY NC Balance (t 5) Anions Cations Solids, Total Dissolved Calculated TDS Balance (0.80 - 1,20) VOLATILE ORGANIC COMPOUNDS Acetone Benzena Carbon tetrachloride Chloroform Chloromethane Methyl ethyl ketone Methylene chloride Naphthalene Toluene xylenes, Total Sun: 1,2-Dichlorobenzene-d4 Su rr: Dibromofluoromethane Surr: p-Bromofl uorobenzene Surr: Toluens-dB 3.07 24.5 26.0 1540 1.01 ND ND 't.9 2500 NO ND ND ND ND ND 108 110 102 96.0 % meq/L meq/L mg/L Calculation Calculation Calculation Calculation Calculation 06/1 9/08 09:55 / sw 0611 9/08 09:55 / sw 06/1 9/08 09:55 / sw 06/,19/08 09:55 / sw 06/19/08 09:55 i sw SW826OB 06/06/08 03:44 / dkh SW8260B 06/06/08 03:44 / dkh SW8260B 06/06/08 03:44 / dkh SW8260B 06/06/08 04:23 / dkh SW8260B 06/06/08 03:44 / dkh SW8260B 06i06/08 03:44 / dkh SW8260B 06/06/08 03:44 / dkh SW8260B 06/06/08 03:44 / dkh SW8260B 06/06/08 03:44 / dkh SW8260B 06/06/08 03:44 / dkh SW8260B 06/06/08 03:44 / dkh SW8260B 06/06/08 03:zl4 / dkh SW8260B 06/06/08 03:44 / dkh SW8260B 06/06/CB 03:44 / dkh ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L %REC %REC %REC %REC 20 1.0 1.0 100 1.0 20 10 10 1,0 1.0 B0-1 20 70-1 30 80-1 20 80-1 20 Report RL ' Analyte reporting limit. Definitions: eCL - euality control limit. MDC - Minimum detectable concentration MCL - Maximum contaminant level. ND - Not detected at the reporting limit. D - RL increased due to sample matrix interference. ) soJ)/ INES Denison Mines (USA) Corp. 1 050 1 7th Street, Suite 950 Denver, CO 80265 USA Tel : 303 628-7798 Fax : 303 389.4125 www.denisonmines.com DENT September 4,2OOB VIA PDF AND FEDERAL EXPRESS ItliI r- \':i\( Mr. Dane L. Finerfrock Executive Secretary Utah Radiation Control Board State of Utah Department of Environmental Quality 168 North 1950 West Salt Lake City, UT B4'114-4850 Dear Mr. Re: July 7 2OOg DUSA Arguments for Affirmative Defense Regarding Temperature Exceedances, April and May,2008 Accelerated Groundwater Monitoring Event, Denison Mines (USA) Corp. (DUSA) White Mesa Uranium Mill(the "Mill") near Blanding, Utah: Notice of Agency Findings Reference is made to your letter dated August 1, 2008, which DUSA received on August 6, 2008, in which you provided DUSA with notice of agency findings relating to DUSA's July 7, 2007 written notice pursuant to R313- 6-6.13. ln its letter, DUSA asserted that the Affirmative Defense set out in Part LG.3(c) of the Mill's Groundwater Discharge Permit should be applicable to two sets of groundwater samples that were received and accepted by the Mill's contract analytical laboratory at temperatures greater than the maximum allowed temperature of 4'C for the April and May 2008 accelerated monitoring events. DUSA also advised in that letter that it was undergoing a number of experimental efforts involving ratio of ice to sample volumes, transportation logistics and sample collection timing, in order to better define the root cause and to allow DUSA to prevent re- occurrences of the problem. DUSA stated in the notice letter that it would provide the Executive Secretary with a follow up letter after completion of this review. ln your August 1, 2008 letter you advised that, in its July 7 submittal, DUSA had met three of the four items needed to meet the Affirmative Defense requirements under UAC R317-6-6.16(cX3); however DUSA failed to satisfy the fourth requirement because it did not provide the Executive Secretary with a schedule or date when DUSA would be back in compliance. ln your letter you also stated that although DUSA failed to meet all the criteria for the Affirmative Defense in its July 7,2OOB submittal, DUSA can still submit a date whereby compliance for future samples will be regained, and thereby satisfy the final item needed to meet the Affirmative Defense. Please accept this letter as the follow up letter referred to in DUSA's July 7 submittal, and as DUSA's submittal of a date whereby compliance for future samples will be regained, as required in order to meet the Affirmative Permit. Follow Up to July 7,2OO8 DUSA Notice Since the July 7, 2008 notice to the Executive Secretary, DUSA has: canvassed another Utah permittee, that is subject to similar groundwater monitoring requirements as well as the 4'C sample temperature requirement, to determine the methods it uses for the transportation of samples to its contract analytical laboratory; performed a number of experiments relating to the ratio of ice to sample volume, the type of ice to be used, and the effectiveness and timing of refrigeration at the Mill prior to packing samples into the coolers; and reviewed the logistics of transportation of samples from the Millto the analytical laboratory and timing and handling of samples upon receipt by the analytical laboratory, to ensure that samples are taken and sent to the analytical laboratory on a schedule that minimizes the time between shipment to and receipt by the analytical laboratory. Based on this review, DUSA has determined that the root cause of the past failures to satisfy the sample temperature requirement was not due solely to the failure to use "S-day'' coolers, as originally proposed by DUSA, but due to a combination of the following factors: failure to use regular ice, rather than "blue ice" (i.e., blue plastic ice blocks that are re-frozen prior to each re-use) to coolthe samples during transit. The analytical laboratory and the other permittee have advised DUSA that they have seen better success in meeting the sample temperature requirement when regular ice rather than blue ice is used. The Mill has used blue ice as the coolant in its sample coolers for the last several years; failure to ensure that there is a proper ratio of ice to sample volume. Mill personnel have conducted a number of experiments to arrive at an acceptable ratio of ice to sample volume. ln the past, Mill personnel have not been systematic on this point; failure to collect samples on a schedule that minimizes sample transit time between the Mill and the analytical laboratory. ln the past, samples have been collected and sent to the analytical laboratory at various times during the week. ln some cases this has resulted in the samples sitting in transit over the weekend; failure to use "S-day'' coolers in all circumstances. While it is evident from recent failures to satisfy the sample temperature requirements that the use of such coolers does not guarantee success, DUSA has concluded that the better insulated coolers will provide a better chance of success, given that the factors set out above are also satisfied; and failure of DUSA to schedule sampling events and identify sample temperature problems early enough in the sampling period to allow re-sampling during the period, if necessary. As a result of this analysis, DUSA has changed its practices, effective August 1, 2008, as follows: a a a it will continue to use S-day coolers. Mill stafl have been advised that S-day coolers are to be used in all circumstances for water samples; it will use regular ice as a coolant; it will ensure that there is a proper ratio of ice to sample volume in each cooler; it will collect samples early enough in the week, so that they will be received by the analytical laboratory on a business day and will not sit in transit over the weekend;. it will collect samples as early in each sampling period as is reasonably practicable, in order to allow for re-sampling during the period if necessary; Defense requirement. ,no"ila R317-6-6.16(c)(3) and Part 1.g.3(c) o,JM,,,'" Groundwater Discharge oENrsoJr/ ,UIINES it will contact the analytical laboratory upon scheduled receipt of the samples to ensure that they have been received by the analytical laboratory within the required temperature range; and lf samples are not received at the analytical laboratory within the required temperature range, the samples will be re-taken during the period and new samples will be submitted to the analytical laboratory for analysis. The loregoing are revised practices that the Mill intends to follow in order to ensure that the sample temperature requirements are satisfied. These may be fine{uned as the Mill gains more experience with them. However, the key feature is that samples will be taken early enough in each sample period to allow for re-sampling if necessary. Date Whereby Compliance for Future Samples will be Regained Some but not all of the foregoing revised practices were instituted commencing July 1, 2008. No samples for July, 2008 exceeded the 4"C requirement upon receipt at the analytical laboratory. The remainder of the foregoing practices were instituted effective August 1, 2008. As a result, DUSA hereby advises that, for the purposes of the Affirmative Defense under UAC R317-6-6.16(c)(3) and Part 1.9.3(c) of the Mill's Groundwater Discharge Permit that were asserted by DUSA in its July 7,2OOe notice to you, compliance for future samples will be regained effective as of July 1, 2008. It should also be noted that the two sets of samples referred to in the July 7 notice (April and May accelerated samples from MW-14, MW-26 and MW-32) were received at 5'C for April and 6'C for May. We understand that current NELAC standards and the current version of EPA SW-846 both now require that those samples be received by the laboratory at 6"C or less, not at 4'C or less. DUSA intends to make a submission to the Executive Secretary to change the Mill's Groundwater Sampling Quality Assurance Plan to reflect these new standards. lf you have any questions or require any further information, please contact the undersigned. Yours very truly, Derutsott Ron F. Hochstein Harold R. Roberts Steven D. Landau David E. Turk DENISOJ)// Vice President, Regulatory Affairs and Counsel ,UIINES DENI5OND/ II,IINES ) / Denison Mines (USA) Corp. 1050 17th Street, Suite 950 Denver, CO 80265 USA Tel: 303 628-7798 Fax: 303 389.4125 www.denisonmines.com August 29,2008 VIA FEDERAL EXPRESS Mr. Dane L. Finerfrock Executive Secretary Utah Radiation Control Board State of Utah Department of Environmental Quality 168 North 1950 West salt Lake city, uT 84114-4850 Dear Mr. Finerfrock: Transmittal of 2nd Quarter 2008 Routine Groundwater Monitoring Report and Routine DMT Performance Standard Monitoring Report For the White Mesa Uranium Mill Enclosed are two copies of the White Mesa Uranium Mill Groundwater Monitoring Report for the 2nd Quarter of 2008, as required under Parts I.F.1 and 2 of State of Utah Groundwater Discharge Permit No. UGW370004. Please note that the results for this quarters sampling do not indicate any exceedances of GWCL's for new parameters or locations that have not previously exceeded their respective concentration limits. If you should have any questions regarding these reports, please contact me. Yours very truly,4zLDrNsox MrNBs (USA) Conp. Steven D. Landau Manager, Environmental Affairs Ron F. Hochstein Harold Roberts (w/o enclosure) David Frydenlund David Turk SMNffiffiffiM fi,IINffi$ Oonison Miner {U$A) Gorp. 1050 l?th Str66t, Suito s50 Donvsr, GO 80265 USA Tol :303 8281798 Fax :303 383412$ www.dsnigonmines.com August 22,2008 VIA PDI.- AND FEDERAL EXPRESS Dane L. Finerfrock, Executive Secretary Utah Radiation Control Board Utah Department of Envirorunental Quality 168 North 1950 Wesi P.O. Box 144810 Salt Lake City, tJT 84114-4810 Dear Mr. Finerfi'ock: Re: State of Utah Ground Water Discharge Permit No. UW370004 White Mesa Uranium Mill - Notice Pursuant to R313-6-6.13 Please take notice purcuant to R3l3-6-6.13 that upon receipt of electronic data on August 18,2008 Denison Mines (USA) Cotp. (DUSA) discovered that one of the tbur sets of samples sent to Amedcan West Analytical Laboratories (AWAL) for tetrahydrofuran (THF) analysis was received at 50 C which exceeds the 4o C temperature specification cited in the Ground Water Monitoring Quality Assurance Plan (QAP) for the White Mesa Mili. tnitial notice of this instances of'non-compliance with the QAP was given to the Executive Secretary by telephone on August 19, 2008 (within 24 hours of the discovery). DUSA believes that the affirmative defense set out in Part I.G.3.c) of the Mill's State of Utah Groundwater Discharge Permit (the Permit) should be applicable to this non-compliance situatitx, for the firllowing reasons : the failure was not intentional or caused by DUSA's negligence, DUSA has taken adequate measures to meet pennit conditions in a timely manner or has submitted to the Executive Secretaly, for the Executive Secretary's approval, an adequate plan and schedule for meeting permit conditions, as detailed below; and the provisions of UCA 19-5-107 have nr:t been violated. The following information is relevant: -Ilhe Mill's QA Manager received electronic data relating to samples sent to AWAL fbr 3"1 Quarter, 2008 THF analyses on August 18, 2008. Upon review of the chain of custody information it was I a discovered that one of the four sets of samples sent to AWAL was received by the laboratory at 5o C. The QA Manager imrrediately contaoted AWAL and the Mill Radiation Safety Officer (RSO) about fhis matter, since prior communication between the Mil1's sampling technician and AWAI, had indicated that these samples had been received within the temperaturc specification. The AWAL Director reporled to the QA rnanager that the samples were within the temperature speoification listed for organic analyses under NEI,AC and the EPA SW-846 guidance. More specifically, these references specify that samples received for volatile and semi-volatile analyses are acceptable at temperatures equal to or less than 6o C. According to the Mili RSO, r,vhen the Mill's sarnpling technician asked the laboratory whether the samples were within the ternperature specification he assumed that when the laboratory reported that the samples were cornpliant with the temperature specification that AWAL understood hc was referring to the 4o C requirement in the DUSA QAP.'fhis assumption was based on prior contact by Denison with AWAI- about previous temperature concerns and the belief that the laboratory was fuliy aware of this particular specification in Denison's QAP. Unfortunately, the infbrmation about Denison's particular requirement went unnoticed by AWAL personnel receiving the sarnples and they assumed that the over-riding NELAC and SW-846 guidance applied to these samples. Accordingly, this miscommunication resulted in a failure to reject the samples and subsequent re-sampling. DUSA believes that the affinnative def'ense in Part LG.3.c) of the Pennit shoultl be applicable to this sample temperature n<ln-compliance situation. 'fhe failure to discover the sample temperature exceedance upon anival at the laboratory, and oonsequent inability to re-sample, was the result of miscommunication and was unintentional. Appropriate corective illeasures had been taken by Denison in response to a prior root-cause analyses related to ternperatule concems. These actions included delivery of the samples in 5-day soolers to assure sample receipt at orbclow the 4o C QAP requircment and a follow-up contact with the laboratory after sarnple shipment to determine whether sarnple temperatures on an'ival were compliant. These rlcasul'os were aimed at assuring better sample transport temperature control and to provide an opportunity tbr re-sample should in-transit temperature control failure occur. Unfbrtunately, the miscommunication between the laboratory personnel and Denison's technician, coupled with the laboratory's application of standard laboratory practices in lieu of Denison's rnore restrictive requirement, led to the non-compliant sample receipt tcmperalure. During our telephone convorsation with Mr. I",oren Mofien on August 19, 2008 f)enison related to Mr. Morten the disparity between sample temperature requirements in the QAP and the seemingly over- riding requirements of NELAC and the SW-846 guidance. Civen that the curent NELAC and SW- 846 sample temperature requirements differ liom those r:ited in tlie QAP, Denison inftrrmed Mr. Morton that a revision to the QAP in this regard would be proposed in order to correct the temperature requirement in the QAP, maintaining consistency with nationally accepted laboratory practices. That revision to the QAP will be forwarded to the UDEQ for its consideration by September 15, 2008. However, until such time that the Executive Secretary approves l)enison's request for modification of the QAP, Denison will retain the 4u C requirement. Regarding the status and schedule tbr cornpliance with the sample receipt temperature requirement, Denison has irnplemented further corrective actions and, as a result, has been compliant since July, 2008. More specifically, subsequent to the use of 5-day coolers, and in response to further difficulties in rneeting the temperature specification after that change, an adclitional root-cause evah.ration was conducted (as summarizecl in our july 3, 2008 email to you) and, in response, further conective measures were identiflecl and implemented. These measures included: l) the use of wet ice placed in zip-lock hags and on top of the samples during transpott (in lieu of blue ice mingled with the sarnples), 2) ad.iusted the volume of ice relative to the volume of samples, 3) adjusted sample shiprnent dates to ffi\ilm doEtvrs&r{ wJl;iMIh{ns assure overnight delivery during weekdays in order to avoid lengthy transit times or delivery on weekends and, 4) the collection of samples early in the month so that sufficient time would be available fbr re-sampling should a temperature failure occur. These corrective measures were implemented in July, 2008, after the receipt by the laboratory of these June sample sets which are the subject of this notice. Results to date since these additionai measures have been taken have been successful in keeping sample temperatures at 4" C or less. DTJSA appreciates your oonsideration of this matter and if you should have any questions please contact me or David Frydenlund. Yr:urs truIy, /1f/gdfr;&L' H Steven D. Landau Manager, Environmental Affairs Ron F. Hochstein Harold R. Roberts David C. Frydenlund David E. Turk OSN'$&NryM#MINS$ il6 DENI o soJ)/ INES Denbon f,inrr (USA) Corp. l0t0 17th St r..t, Suib 950 Denvrr, CO 80265 usA Tel :303 62&7798 Fer : 303 38$4125 August 6, 2008 SENT VIA ELECTRONIC MAIL AI\D FEDERAL EXPRESS Dane L. Finerfrock, Executive Secretary Utah Radiation Control Board Utah Department of Environmental Quality 168 North 1950 West P.O. Box 144810 Salt Lake city, uT 84114-4810 ;-, > :?- . State of Utah Ground Water Discharge Permit No. UW370004 (the 6G\IFDP") White Mesa Uranium Mill - Notice Pursuant to Part I.G.l(a) Dear Mr. Finerfrock: The White Mesa uranium mill (the "Mill") completed its 2'd quarter, 2008 groundwater sampling under the GWDP during the period of May 27 tltrough June 18, 2008. Samples were collected on May 27, 28 & 29 and June 3, 4, 5,9, 12, 16, 1 7 & 1 8. The final analytical results of these samplings were received by Denison in four data sets dated July 7 , 2008, July 17, 2008 (two sets) and Jily 27 , 2008. Under the GWDP it is intended that background groundwater quality will be determined on a well-by-well basis, as defined by the mean plus second standard deviation concentration. The Mill is currently in the process of working with the Utah Division of Radiation Control to establish background (including the mean plus standard deviation) for all of the constituents being sampled under the GWDP. Until background is established, the GWDP requires that constituent concentrations in each monitoring well shall not exceed the Groundwater Control Limits ("GWCLs") set out in Table 2 of the GWDP. Pursuant to Part I.G.l.a) of the GWDP, please take notice that the concentrations of the following constituents in the following monitoring wells sampled for the 2nd Quarter, 2008 exceeded their respective GWCLs in Table 2 of the Permit: Table I - GWCL Exceedances for the Quarterly and Semi-Annual Sampling Monitoring Well (Water Class) Constituent GWCL (us/L) Sample Result (ug/L) MW-3 (Class III) Manganese 400 810 Uranium l5 31.3 Selenium 25 73.4 /rl Ir,: l.'. \I t.tir'' -,, '\ir: .i:\\ \(-' Monitoring Well (lVefer Cless) Constituent GWCL lnoll ) Sample Result (ug/L) MW-s (Class II) Mansanese 200 2s8 MW-12 (Class III) Uranium 15 16.7 MW-14 (Class III) Uranium t5 6r.3 Manganese 400 2.290 MW-15 (Class III) Selenium 25 r06 Uranium t5 43.9 MW-17 (Class III) Uranium l5 29.4 MW-18 (Class II) Uranium 7.5 44.8 Thallium 0.5 t.34 MW-19 (Class II) Flouride r.0 l.l MW-26 (Class III) Mansanese 400 I.130 Uranium 15 2t.7 Chloroform 35 2.000 Dichlormethane 2.5 110 MW-32 (Class III) Manganese 400 5,400 Nickel 50 62 Iron 5.500 8.650 Unless the compliance status for any constituents in any wells is determined otherwise by the Executive Secretary, the Mill will, pursuant to Part I.G.l.b)l) of the Permit, commence or continue, as the case may be, accelerated sampling of each of the foregoing constituents in its respective well on a monthly or quarterly basis, as applicable, and as set forth below. No new accelerated monitoring requirements were added on the basis of this 2nd Quarter, 2008 sampling period. Table 2 - Accelerated Monitoring Requirements as of August 6, 2008 Monitoring Well (Water Class)Constituent Normal tr'requency of Samnlinp Accelerated Frequency of Samolins Commencement of Accelerated Monitorine MW-1 (Class II) Tetrahydrofuran Semi-Annual Ouarterly 4- Ouarter 2005 Manganese Semi-Annual Ouarterly l"'Ouarter 2006 MW-3 (Cless III) Manganese Semi-Annual Ouarterly l"'Ouarter 2006 Selinium Semi-Annual Quarterly 3'" Ouarter 2006 Thallium Semi-Annual Ouarterly 4- Ouarter 2005 Uranium Semi-Annual Quarterly 4n Ouarter 2005 Tetrahvdrofuran Semi-Annual Ouarterly 3* Ouarter 2006 MW-5 (Class II) Manganese Semi-Annual Ouarterly 4'" Ouarter 2005 OENISOJ)//,utNEs Monitoring \ilell (Water Class) v Constituent Normal Frequency of Samolins Acce-I-erated Frequency of Ssmnlino Commencement of Accelerated Monitorins MW-5 Contd.Fluoride Semi-Annual Ouarterly 4* Ouarter 2005 Tetrahydrofuran Semi-Annual Quarterlv ls Ouarter 2006 MW-12 (Class III) Uranium Semi-Annual Quarterly 4'" Ouarter 2005 Tetrahvdrofuran Semi-Annual Ouarterly 4'Ouarter 2005 MW-14 (Class III) Mansanese Quarterly Monthly June 2005 Uranium Ouarterly Monthlv June 2005 MW-15 (Class III) Selenium Semi-Annual Ouarterly 4'" Ouarter 2005 Uranium Semi-Annual Quarterlv 4- Ouarter 2005 MW-17 (Class III) Uranium Semi-Annual Quarterlv 4'" Ouarter 2005 Thalium Semi-Annual Ouarterlv 1" Ouarter 2006 MW-l8 (Class II) Thallium Semi-Annual Ouarterly 4'o Ouarter 2005 Uranium Semi-Annual Quarterly 4* Ouarter 2005 Manganese Semi-Annual Ouarterlv Januarv.2008 MW-19 (Class IT) Fluoride Semi-Annual Quarterly l" Ouarter 2006 Selenium Semi-Annual Ouarterly 4" Ouarter 2005 Thallium Semi-Annual Quarterly 1" Ouarter 2006 Uranium Semi-Annual Ouarterly 4'" Ouarter 2005 MW-26 (Class III) Manganese Quarterly Monthly June 2005 Uranium Ouarterly Monthlv June 2005 Chloroform Quarterly Monthly June 2005 Dichloromethane Ouarterly Monthlv September 2005 MW-32 (Class III) Cadmium Ouarterlv Monthly June 2005 Iron Quarterly Monthlv June 2005 Mansanese Ouarterlv Monthly June 2005 Nickel Quarterly Monthly June 2005 Gross Aloha Ouarterlv Monthly March2007 If you have any questions or require any further information, please contact the undersigned. Yours truly,% ZDenison Mines (USA) Corp. Steven D. Landau Manager, Environmental Affairs DENlsOJ)II MINES Ron Hochstein Harold Roberts David Frydenlund David Turk OENISOJ)II DENISOJ)// MINES Denbon tlines (USA) Corp. 1050 17th Str.et, Suite 95{, Dcnvcr, CO 80265 USA Tol : 303 628-7798 Far : 303 389.f125 July 7, 2008 VIA PDF AND FEDERAL EXPRESS Dane L. Finerfrock, Executive Secretary Utah Radiation Control Board Utah Department of Environmental Quality 168 North 1950 West P.O. Box 144810 Salt Lake City, UT 84114-4810 Dear Mr. Finerfrock: State of Utah Ground Water Discharge Permit No. UW370004 White Mesa Uranium Mill - Notice Pursuant to R313-6-6.13 Please take notice pursuant to R313-6-6.13 that Denison Mines (USA) Corp. (DUSA) initiated a follow-up telephone call with its contract analytical laboratory on July 2,2008 to determine whether the tempirature of samples delivered for the second quarter of 2008 had met the 40 C temperature specification. As a result of the call, DUSA discovered two instances where samples were received at the White Mesa Mill's (the Mill's) contract analytical laboratory above the 4o C specification, as detailed below. Initial notice of these instances of non-compliance was given to the Executive Secretary by telephone on July 3, 2008 (within 24 hours of the discovery). DUSA believes that the affirmative defense set out in Part I.G.3.c) of the Mill's State of Utah Groundwater Discharge Permit (the Permit) should be applicable to these non-compliance situations, for the following reasons: o the failure was not intentional or caused by DUSA's negligence, o DUSA has taken adequate measures to meet permit conditions in a timely malrner or has submitted to the Executive Secretary, for the Executive Secretary's approval, an adequate plan and schedule for meeting permit conditions, as detailed below; and o the provisions of UCA 19-5-107 have not been violated. The following information is relevant: The Mill's QA Manager noted in his follow-up conversation with the Mill's contract analytical laboratory on July 2,2008 that two sets of samples received and accepted by the laboratory for the '., JUL Re: o second quarter of 2008 were above 4o C (but on ice) at the time of delivery to the lab. These two sets (April and May accelerated samples from MW-l4,MW-26 and MW-32) were received at 5 o C for April and 6 o C for May and were outside of the temperature specification at 4o C, as required by Part I.E.4(b), Part II.A of the Permit, and Table 1 and Section 9.3(d) of the approved DUSA QAP. All other samples sent to the laboratory in the second quarter of 2008 were within the 4o C requirement. The samples sent to the laboratory were sent in 5-day coolers, as the use of these coolers had shown demonstrated success subsequent to Denison's February 21,2008 correspondence with UDEQ, where the coolers had been proposed for use in sample transport. DUSA believes that the affirmative defense in Part I.G.3.c) of the Permit should be applicable to these sample temperature non-compliance situations. The exceedance of temperature was unintentional and not caused by DUSA's negligence. Mill personnel were following the procedures reported to UDEQ on February 21,2008 and June 3, 2008 to avoid future sample temperature problems and the situation had improved. With the exception of these two sets of samples, all samples sent to the laboratory in 5- day coolers since February 21, 2008 have arrived at the laboratory at less than 4o C. The fact that these two sets of samples did not meet the temperature specification, has prompted DUSA to further study the matter to determine what further steps are required in order to ensure that the temperature specification will be satisfied in all cases in the future. DUSA will also move up its sample dates to as close to the beginning of each sample period as practicable, in order to allow for re-sampling within the period, should the temperature specification prove to be violated in the future. As an initial step, Mill personnel have been instructed to continue to use 5-day coolers for all future sample shipments and are currently conducting a test run to lower further the temperature of samples during transport. The test will include increasing coolant volume and/or decreasing the number of samples per cooler. The test will not include actual samples. Once the test run is complete (and successful), and actual samples have been sent to the laboratory, sample receipt temperature will be confirmed by the laboratory and if the receipt temperature remains unacceptable a re-sample of the affected water samples will be collected. DUSA is also reviewing transportation times and logistics from the Mill to the laboratory, to ensure that the time between sample collection and receipt at the laboratory is kept to a minimum, and is also considering other methods of cooling and transporting samples to the laboratory that are available or that are being used successfully by other similar facilities. DUSA will provide a follow up letter to the Executive Secretary after its completion of this review. DUSA appreciates your consideration of this matter and if you should have any questions please contact me or David Frydenlund. Manager, Environmental Affairs cc: Ron F. Hochstein Harold R. Roberts David C. Frydenlund David E. Turk DENI5OJ)I/ MINES