HomeMy WebLinkAboutDERR-2024-011166
195 North 1950 West
Mailing Address: P.O. Box 144840 Salt Lake City, UT 84114-4840
Telephone (801) 536-4100 ) 359-8853 (801) 536-4284
www.deq.utah.gov
Printed on 100% recycled paper
State of Utah
SPENCER J. COX
Governor
DEIDRE HENDERSON
Lieutenant Governor
Department of
Environmental Quality
Kimberly D. Shelley
Executive Director
DIVISION OF ENVIRONMENTAL
RESPONSE AND REMEDIATION
Brent H. Everett
Director
ERRC-149-24
October 2, 2024
Athena Jones
US EPA Region 8
Mail Code 8EPR-SR
1595 Wynkoop Street
Denver, Colorado 80202-1129
Dear Ms. Jones:
Please find enclosed the Portland Cement Site Operable Unit 3 Annual Groundwater and
Surface Water Monitoring and Sampling Report for sampling completed during June 2023.
If you have any questions concerning this report, please contact me at 801-536-4100.
Sincerely,
Tony Howes, P.G.
Environmental Scientist
Division of Environmental Response and Remediation
TH/lg
Enclosure(s): OU3 Annual Groundwater and Surface Water Monitoring and Sampling Report
ecc: Paul Crosbie, Salt Lake County Health Department (letter only)
ANNUAL GROUNDWATER AND SURFACE WATER
MONITORING AND SAMPLING REPORT
Portland Cement OU3 Site
Salt Lake City, Utah
June 2023
TABLE OF CONTENTS 1.0 INTRODUCTION ......................................................................................................................................................... 1 2.0 PURPOSE AND OBJECTIVES ................................................................................................................................. 1 3.0 PROJECT MANAGEMENT ....................................................................................................................................... 1 4.0 SITE DESCRIPTION AND HISTORY .................................................................................................................... 1 5.0 FIELD ACTIVITIES .................................................................................................................................................... 3 5.1 Sample Collection and Analysis ...................................................................................................................... 3 5.2 Equipment Decontamination .......................................................................................................................... 3 5.3 Quality Control Samples .................................................................................................................................... 3 5.4 Deviations from Standard Sampling Activities ........................................................................................ 4 6.0 SUMMARY OF RESULTS ......................................................................................................................................... 4 6.1 Groundwater Level Monitoring Results ...................................................................................................... 4 6.2 Field Parameters .................................................................................................................................................. 5 6.3 Shallow Aquifer Analytical Results ............................................................................................................... 5 6.3.1 COC Concentrations in the Shallow Aquifer .................................................................................... 5 6.3.2 Metal Concentrations in ACL Compliance Wells ............................................................................ 6 6.4 Surface Water Analytical Results ................................................................................................................... 6 6.5 Intermediate Aquifer Analytical Results .................................................................................................... 6 7.0 CONTAMINANT TRENDS OVER TIME .............................................................................................................. 7 7.1 Shallow Aquifer Contaminant Trends ......................................................................................................... 7 7.2 Intermediate Aquifer Contaminant Trends ............................................................................................... 8 8.0 CONCLUSION .............................................................................................................................................................. 9 9.0 REFERENCES ............................................................................................................................................................ 10
LIST OF FIGURES, TABLES, AND APPENDICES
FIGURES: Figure 1: Site Location Figure 2: Groundwater Elevations in the Shallow and Intermediate Aquifers Figure 3: Total Metal Concentrations Detected in the Shallow Aquifer Figure 4: Dissolved Metal Concentrations Detected in the ACL Wells and City Drain Figure 5: Total Metal Concentrations Detected in the Intermediate Aquifer
TABLES:
Table 1: Field Duplicate Results Table 2: Groundwater Elevations Table 3: Summary of Final Water Quality Field Parameters Table 4: Shallow Aquifer Total Metals Concentrations Table 5: Comparison of ACL Monitoring Well Results to ACL Table 6: Surface Water Metal Concentrations Table 7: Intermediate Aquifer Total Metal Concentrations
APPENDICES: Appendix A: Water Quality Field Parameters Appendix B: Analytical Results Appendix C: Water Level Measurements Appendix D: Data Trends for Monitoring Wells
Annual Monitoring and Sampling Report June 2023 Portland Cement Site OU3 Page 1
1.0 INTRODUCTION This report was prepared by the Utah Department of Environmental Quality, Division of Environmental Response and Remediation (UDEQ/DERR) to summarize groundwater monitoring and sampling at the Portland Cement OU3 Site (Site) for June 2023. This sampling aims to determine the effectiveness of the selected remedy established in the Record of Decision (ROD) for Operable Unit Three (OU3). OU3 addressed contaminated groundwater in the shallow aquifer. The scope of this investigation included recording water level measurements and collecting groundwater and surface water samples for dissolved and total metal analysis. Activities associated with the June 2023 annual monitoring and sampling event took place from June 12 – June 20, 2023.
2.0 PURPOSE AND OBJECTIVES The purpose of groundwater and surface water monitoring is to provide information as to the concentrations and distribution of contaminants at the Site. As specified in the Portland Cement OU3 ROD, long-term monitoring will continue until cleanup goals are attained. The scope of the long-term monitoring program includes groundwater/surface water sampling and analytical data interpretation. The objectives of long-term monitoring are:
• To determine if contaminants are migrating off-site;
• To determine if contaminants are migrating to the intermediate aquifer;
• To determine the effectiveness of the selected remedy in reducing contaminants to their respective cleanup goals; and
• To determine if contaminant concentrations in the city drain exceed performance standards. These objectives are achieved by collecting, analyzing, and evaluating samples from monitoring wells and the city drain. Analytical results are compared to cleanup goals and previous analytical data.
3.0 PROJECT MANAGEMENT Field activities associated with the June 2023 groundwater monitoring and sampling event were conducted by Tony Howes the UDEQ/DERR Project Manager. Groundwater and surface water samples were shipped to Bonner Analytical Testing Company in Hattiesburg, Mississippi as specified by the EPA Contract Laboratory Program (CLP). Samples were also submitted under chain of custody to Chemtech-Ford Laboratories in Sandy, Utah for pH, total dissolved solids (TDS), and chromium-6 analysis.
4.0 SITE DESCRIPTION AND HISTORY The Site is located in Salt Lake City, Utah on the west side of Redwood Road (1700 West) at 1000 South, within a triangular area defined by Indiana Avenue, Redwood Road, and the Jordan River overflow canal (surplus canal). The approximately 70-acre site consists of three separate but adjacent properties known as the West Site, Site 2, and Site 3 (Figure 1).
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The disposal of cement kiln dust (CKD) and chromium-bearing bricks on the Site contaminated soils and groundwater with metals that leached from the waste materials. The CKD and contaminated surface soils were excavated and removed from the Site during the remedial action completed in 1997. The Site was backfilled with clean soil and regraded. Significant concentrations of contaminants remain in the shallow groundwater aquifer that lies beneath the Site. The groundwater aquifers of interest at the Site are the shallow aquifer and the intermediate aquifer. Both are located above the Salt Lake Valley Principal Aquifer which supplies a majority of the drinking water to the Salt Lake Valley. The shallow aquifer is unconfined, while the intermediate aquifer is confined between two continuous clay layers. The upper clay layer separates the shallow and intermediate aquifers and is approximately 10 feet thick. The shallow aquifer is comprised of silt and fine-grained sand from the water table down to the upper clay layer at approximately 25 to 30 feet below ground surface (bgs). The intermediate aquifer is comprised of poorly sorted, silty, fine-grained sand to well-sorted medium-grained sand and is typically 5 to 12 feet thick, at depths of 40 to 55 feet bgs. Flow between the two aquifers has historically been upward from the intermediate aquifer to the shallow aquifer. Groundwater flow in the shallow (contaminated) aquifer is complex due to interaction with local surface water and utility pathways. Primary areas of recharge are the unlined surplus canal along the southern boundary of the Site and underflow along the eastern site boundary. Shallow groundwater discharges to the city drain, an unlined stormwater ditch that bisects the Site and flows east to west. The Site is also bisected from north to south by a sanitary sewer. The sewer line bedding material acts as a conduit removing groundwater from the Site and routing it into the city drain. Together, these two features ensure that shallow groundwater beneath the Site is discharged into the city drain. The city drain, surplus canal, sanitary sewer, and a stormwater ditch on the west end of the Site serve as groundwater “boundaries” for the contaminated shallow aquifer. The effect of these groundwater “boundaries,” and the upward vertical gradient from the intermediate aquifer, is that groundwater contamination is contained largely within the Site borders and within the shallow aquifer. The water in the shallow aquifer has been impacted over the entire Site, with the highest degree of contamination occurring in locations formerly overlain by CKD wastes. The OU3 ROD established monitored natural attenuation (MNA) as the selected remedy to address the contaminated shallow aquifer. A network of groundwater monitoring wells (Figure 1) was constructed at the Site to monitor concentrations of contaminants in the shallow and intermediate aquifers to ensure the effectiveness of the MNA remedy. At the time the ROD was established, no elevated concentrations of monitored contaminants had been detected in groundwater outside the Site boundaries or in the intermediate aquifer. The Contaminants of Concern (COCs) for groundwater identified in the ROD are arsenic, cadmium, chromium, lead, manganese, molybdenum, and pH. Cleanup goals developed for the shallow aquifer are based on federal maximum contaminant levels (MCLs) and local background water quality for arsenic. Since the shallow aquifer discharges into the sanitary sewer and the city drain and eventually discharges into the Farmington Bay Waterfowl Management Area of the Great Salt Lake, alternate concentration limits (ACLs) were established for the groundwater wells located along the city drain and the sanitary sewer line to protect surface water. These ACLs were calculated by determining what concentrations of individual chemicals in groundwater would cause an exceedance of 125% of the Class IIID water standards for aquatic wildlife within the city drain at a designated point of compliance. The ACLs are applied only for the protection of the water in the city drain and are only
Annual Monitoring and Sampling Report June 2023 Portland Cement Site OU3 Page 3
enforced at the shallow aquifer wells along the city drain and sanitary sewer (i.e., PWEA, P2FA, P3CC, P3DA, and P3FA). These five wells are analyzed for both total and dissolved: aluminum, chromium 6, copper, iron, mercury, nickel, selenium, and zinc in addition to the groundwater COCs.
5.0 FIELD ACTIVITIES Samples were collected from nine shallow aquifer monitoring wells (PWEA, PWBA, P2FA, P2HA, P3BB, P3CC, P3DA, P3FA, and P3GB), three intermediate aquifer monitoring wells (PWS, P3EA, and P3O), and one surface water location (CDPOC). Depth to groundwater was measured at two additional shallow aquifer monitoring wells (P2EA and P2GA).
5.1 Sample Collection and Analysis Sampling activities were conducted according to procedures outlined in Section 4 of the Operations
and Maintenance (O&M) Monitoring Plan, Sampling and Analysis Plan (SAP). The depth to groundwater from the top of the well casing was measured with an electronic water level meter and recorded before well purging and sample collection. Monitoring wells were purged until water quality field parameters were within +/- 10% for at least two subsequent readings (Appendix A). Groundwater and surface water samples were collected in certified clean containers. Samples were collected with a low-flow peristaltic pump and disposable polyethylene tubing. All samples collected were analyzed for total metals, TDS, and pH. Samples collected from wells PWEA, P2FA, P3CC, P3DA, P3FA, and from the city drain (CDPOC) were also analyzed for dissolved metals and chromium 6. Dissolved metal samples were filtered in the field with a new, disposable 0.45-micron filter at each sampling location. Samples obtained for total and dissolved metal analysis were preserved in the field with nitric acid and placed on ice in an insulated cooler. Weather conditions obtained from the National Weather Service website (http://forecast.weather.gov/MapClick.php?lat=38.4494&lon=-112.2302#.WDXS-H04JfV) and recorded at the time of collecting the surface water sample (CDPOC) was overcast and 73° Fahrenheit. Analytical reports from Chemtech-Ford Laboratories and the EPA contract laboratory for the June 2023 annual groundwater monitoring and sampling event are provided in Appendix B.
5.2 Equipment Decontamination The water level meter was rinsed with de-ionized water between each monitoring well. Disposable polyethylene tubing was used at each monitoring well and surface water sample location; therefore, tubing decontamination was not required.
5.3 Quality Control Samples A groundwater field duplicate sample (PWAA) was collected in conjunction with sample PWEA. The Relative Percent Difference (RPD) between groundwater sample PWEA and its duplicate PWAA is summarized in Table 1. The total cadmium and zinc concentrations did not meet the quality assurance RPD criterion of less than or equal to 20 percent and were assigned a “J” qualifier as
Annual Monitoring and Sampling Report June 2023 Portland Cement Site OU3 Page 4
called for in the Portland Cement Site Quality Assurance Project Plan (URS, 1999). The remaining total and dissolved metal concentrations met the RPD criterion of less than or equal to 20 percent (Table 1). The RPD was not calculated for analytes with concentrations below the method detection limits. A surface water field duplicate sample (P3AA) was collected in conjunction with sample CDPOC. The RPD between surface water sample CDPOC and its duplicate (P3AA) are also summarized in Table 1. The dissolved copper concentration did not meet the quality assurance RPD criterion of less than or equal to 20 percent and was assigned a “J” qualifier as called for in the Portland Cement Site Quality Assurance Project Plan (URS, 1999). The remaining total and dissolved metal concentrations met the RPD criterion of less than or equal to 20 percent (Table 1). The RPD was not calculated for analytes with concentrations below the method detection limits.
5.4 Deviations from Standard Sampling Activities No samples or groundwater level measurements were collected from wells B6S, B7S, PWDA, PWKA, P2DA, B6I, PWT, or PWU due to damage or removal of the monitoring wells. No groundwater level measurements or samples were collected from monitoring wells P2BA, P2GA, and P2M. Monitoring wells P2BA, P2GA, and P2M were inaccessible due to site redevelopment construction activity and will be monitored or sampled during the next monitoring and sampling event. The absence of data from these sample locations does not affect the ability to meet the objectives of the annual monitoring and sampling event.
6.0 SUMMARY OF RESULTS
6.1 Groundwater Level Monitoring Results Depths to groundwater for the shallow and intermediate aquifers were recorded on a water level measurement form (Appendix C) and are summarized in Table 2. Groundwater elevations calculated for the shallow aquifer ranged from 4,218.51 feet above mean sea level (amsl) at P3CC to 4,223.58 feet amsl at P3FA. Groundwater elevations calculated for the intermediate aquifer ranged from 4,223.31 feet amsl at PWS to 4,224.89 feet amsl at P3EA (Table 2). Based on groundwater elevations for wells P2CA, P2HA, and P2FA, the horizontal groundwater flow direction in the shallow aquifer south of the city drain appears to flow away from the city drain which is not consistent with past trends. The well casing for P2CA, P2HA, and P2FA was modified to accommodate development and the established top-of-casing elevations are likely no longer valid; therefore, the horizontal groundwater flow direction in the shallow aquifer south of the city drain is likely inaccurate. The horizontal groundwater flow direction in the shallow aquifer north of the city drain is toward the city drain and is consistent with past trends. Groundwater elevations calculated for paired monitoring wells were higher for the intermediate aquifer monitoring wells than for the shallow aquifer monitoring wells (Figure 2). Based on this information, the vertical groundwater flow direction is upwards from the intermediate to the shallow aquifer and is consistent with past trends.
Annual Monitoring and Sampling Report June 2023 Portland Cement Site OU3 Page 5
6.2 Field Parameters A summary of the final field parameters recorded for the June 2023 monitoring and sampling event is provided in Table 3. Temperatures recorded for this monitoring event ranged from 12.61 degrees Celsius (°C) at PWEA to 20.79°C at PWS. Specific conductivity ranged from 0.434 microsiemens per centimeter (µS/cm) at PWS to 17.80 µS/cm at P2HA. The pH values recorded for this monitoring event ranged from 7.72 standard units at PWS to 9.65 standard units at PWEA. Turbidity values ranged from zero nephelometric turbidity unit (NTU) at monitoring wells PWEA PWBA P2FA, and P3FA to 107 NTU at P3DA. Dissolved oxygen levels ranged from 0.02 milligrams per liter (mg/L) at surface water sample location CDPOC to 19.95 mg/L at P3FA. Oxidation/reduction potential (ORP) values ranged from -415 millivolts (mV) at P3CC to 76 mV at surface water sample location CDPOC.
6.3 Shallow Aquifer Analytical Results The cleanup goals for the COCs in the shallow aquifer were derived from MCLs and local background water quality. For arsenic, the local background concentration exceeded the MCL therefore the attainment of the background concentration of 64 micrograms per liter (µg/L) was established as the cleanup goal. For the other contaminants, the attainment of concentrations below the MCLs was set as the cleanup goal. The cleanup goals for the shallow aquifer specified in the ROD are for concentrations of total metals in groundwater. ACLs are applied for the protection of the city drain where the groundwater discharges to the city drain and are only enforced at the shallow wells near the city drain and the sanitary sewer.
6.3.1 COC Concentrations in the Shallow Aquifer Groundwater samples collected from nine shallow aquifer monitoring wells in June 2023 were analyzed for total metals and compared to the groundwater cleanup goals (Table 4). Shallow monitoring well locations and detected concentrations are shown in Figure 3. TDS results measured in the shallow aquifer ranged from 1,340 mg/L at P3FA to 18,000 mg/L at P2HA. There are no cleanup goals for TDS. Values for pH in the shallow aquifer were above the cleanup goal of less than 8 standard units in all nine shallow aquifer monitoring wells sampled in June 2023. Values for pH ranged from 8.3 at P3BB to 10 at PWEA and P3CC. The total arsenic cleanup goal of 64 µg/L was exceeded in shallow monitoring wells PWEA, PWBA, P2FA, P2HA, P3CC, P3DA, and P3FA. Total arsenic concentrations detected in the shallow aquifer monitoring wells ranged from 12 µg/L in monitoring well P3GB to 1,100 µg/L in P3CC. Total cadmium concentrations in the shallow aquifer monitoring wells did not exceed the cleanup goal of 6.2 µg/L. Detected cadmium concentrations in the shallow aquifer monitoring wells ranged from 0.15 J µg/L in monitoring well PWBA to 0.69 J µg/L in monitoring well P2FA.
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Total chromium concentrations in the shallow aquifer monitoring wells did not exceed the cleanup goal of 100 µg/L. Detected chromium concentrations ranged from 0.55 J µg/L at P3GB to 7.9 µg/L at P2FA. Total lead concentrations in the shallow aquifer monitoring wells did not exceed the cleanup goal of 15 µg/L. Detected lead concentrations ranged from 0.24 J µg/L at PWEA to 3.8 µg/L at P3FA. Total manganese concentrations in the shallow aquifer monitoring wells did not exceed the cleanup goal of 440 µg/L. Detected manganese concentrations ranged from 6.8 µg/L at PWBA to 110 µg/L at P3BB. The total molybdenum cleanup goal of 182 µg/L was exceeded in shallow aquifer monitoring wells PWEA, PWBA, P2FA, P2HA, P3CC, P3DA, P3FA, and P3GB. Total molybdenum concentrations detected in the shallow aquifer monitoring wells ranged from 38 J+ µg/L in well P3BB to 60,000 J+ µg/L in P2FA.
6.3.2 Metal Concentrations in ACL Compliance Wells ACLs apply to dissolved metal concentrations and were established for the groundwater wells located along the city drain and the sanitary sewer line to protect surface water. Four ACL point of compliance wells were analyzed for dissolved metals and compared to the ACLs (Table 5). ACL point of compliance locations and detected concentrations are shown in Figure 4. Dissolved metal concentrations in the ACL point of compliance wells were all below the established ACLs.
6.4 Surface Water Analytical Results A surface water sample (CDPOC) was collected from the point of compliance (i.e. confluence of the city drain and the north-south trending stormwater ditch west of I-215; Figure 4) and analyzed for total and dissolved metals. The performance standards documented in the ROD for surface water at the Site require that dissolved metals not exceed 125% of Class IIID water quality standards. Metal concentrations in sample CDPOC were less than their established surface water performance standards (Table 6). However, the laboratory detection limit of 0.2 µg/L for dissolved mercury was greater than the established surface water performance standard of 0.01 µg/L, and the result may have exceeded the performance standard. Mercury is believed to not be a concern related to the Site since concentrations in the shallow aquifer were below the laboratory detection limit. In addition to metals analysis, surface water TDS and pH were also measured. TDS and pH levels were 1,770 mg/L and 8.1 standard units, respectively. There is no surface water performance standard for TDS. The pH value was within the surface water performance standard range of 8.13-11.25.
6.5 Intermediate Aquifer Analytical Results Groundwater samples collected from three intermediate aquifer monitoring wells were analyzed for total metals and compared to the groundwater cleanup goals. Total metal concentrations detected in these three monitoring wells are summarized in Table 7. Monitoring well locations and detected concentrations are shown in Figure 5.
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The pH values detected in monitoring wells P3EA and P3O exceeded the cleanup goal of 8 standard units. The pH values in wells P3EA and P3O were 8.8 and 8.2 standard units, respectively. With the exception of lead in monitoring well P3EA, total metal concentrations in the intermediate aquifer were less than the established cleanup goals. The lead concentration in well P3EA was 64 µg/L. Groundwater elevations have consistently demonstrated an upward flow from the intermediate to the shallow aquifer. Therefore, the pH and lead exceedance in the intermediate aquifer is likely not the result of downward flow from the contaminated shallow aquifer. If contaminants from the shallow aquifer near these wells are migrating to the intermediate aquifer, the transport mechanism is unclear.
7.0 CONTAMINANT TRENDS OVER TIME COC concentration trends for wells screened in the shallow and intermediate aquifers were evaluated with the Mann-Kendall non-parametric statistical test for trend. The evaluation of contaminant trends was completed with a free spreadsheet-based software tool obtained from GSI (GSI, 2012). The results of the GSI statistical trend evaluation are provided in Appendix D. Analytical data for groundwater samples collected from June 2015 to June 2023 were used to perform the statistical test for trends. Analytical data reported as non-detect were assigned a common value less than the smallest measured value in the data set as suggested in the EPA guidance document Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities Unified
Guidance (EPA, 2009). A confidence factor of 95% was used for the trend evaluation. Strong increasing or decreasing trends are indicated as having a confidence factor greater than 95% and trends indicated as either “probably decreasing” or “probably increasing” have a confidence factor between 90% and 95%. Confidence factors less than 90% were either indicated as “no trend” or “stable”.
7.1 Shallow Aquifer Contaminant Trends The following COC contaminant trends were observed in the shallow aquifer: pH levels have remained fairly constant throughout all sampling events. pH has consistently exceeded the cleanup goal of 8 standard units in all shallow monitoring wells. The Mann-Kendall statistical trend analysis found that pH was increasing in well P3CC, probably increasing in wells PWEA and P2FA, decreasing in wells P2BA and P3GB, stable in wells PWBA, P3FA, and P2HA, and no trends were observed in wells P3BB and P3DA. Arsenic concentrations have consistently remained above the 64 μg/L cleanup goal in wells PWEA, P2HA, P3CC, and P3FA. The Mann-Kendall statistical trend analysis found that arsenic concentrations were increasing in wells PWEA, PWBA, and P3CC, decreasing in wells P2BA, and P2HA, probably decreasing in well P3GB, stable in wells P2FA, P3BB, and P3FA, and no trend was observed in well P3DA. Cadmium concentrations have consistently been below the cleanup goal of 6.2 μg/L in the majority of wells throughout the Site. The Mann-Kendall statistical trend analysis found cadmium concentrations were probably increasing in well PWEA, decreasing in wells P3FA and P3GB, stable in wells P2BA and P3DA, and no trend in wells PWBA, P2FA, P2HA, P3BB, and P3CC
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Chromium concentrations have been consistently below the cleanup goal of 100 μg/L in the majority of wells throughout the Site. The Mann-Kendall statistical trend analysis found that chromium concentrations were increasing in well PWEA, probably increasing in well P3BB, decreasing in wells P2BA and P3FA, stable in well P3GB, and no trend in wells. PWBA, P2FA, P2HA, P3CC, and P3DA. With the exception of the June 2022 and 2023 monitoring and sampling events, lead concentrations have been consistently above the cleanup goal of 15 μg/L in well P3FA and below the cleanup goal in the remainder of the wells throughout the Site. The Mann-Kendall statistical trend analysis found that lead concentrations were probably increasing in well P2HA, decreasing in well P3FA, stable in wells PWBA and P2FA, and no trend in wells PWEA, P2BA, P3BB, P3CC, P3DA, and P3GB. With the exception of the June 2021, 2022, and 2023 monitoring and sampling events, Manganese concentrations have consistently been above the cleanup goal of 440 μg/L in well P3FA. Manganese concentrations in the remaining wells have consistently been below the cleanup goal. The Mann-Kendall statistical trend analysis found manganese concentrations were increasing in well P2HA, decreasing in well P3FA and no trends were observed in wells PWEA, PWBA P2BA, P2FA, P3BB, P3CC, P3DA, and P3GB. Molybdenum concentrations have consistently remained above the cleanup goal of 182 μg/L in wells PWEA, PWBA, P2FA, P2HA, P3CC, and P3FA, The Mann-Kendall statistical trend analysis found molybdenum concentrations were probably increasing in wells PWEA and P3CC, probably decreasing in well P3GB, stable in wells P2BA, P2HA, and P3FA, and no trend in wells PWBA, P2FA, P3BB, and P3DA.
7.2 Intermediate Aquifer Contaminant Trends The following COC contaminant trends were observed in the intermediate aquifer: The pH values have remained fairly constant in the intermediate aquifer since June 2015 and pH levels have remained either below or slightly above the cleanup goal of 8 standard units. The Mann-Kendall statistical trend analysis found that pH was increasing in well P3EA, decreasing in well P2M, no trend in well PWS, and stable in well P3O. With the exception of well P3O, total arsenic concentrations in the intermediate aquifer have consistently been below the cleanup goal of 64 μg/L since June 2015. The Mann-Kendall statistical trend analysis found arsenic levels in the intermediate monitoring wells were probably increasing in well PWS, decreasing in well P2M, no trend in well P3EA, and stable in well P3O. Total cadmium concentrations in the intermediate aquifer monitoring wells have consistently been less than the cleanup goal of 6.2 μg/L. The Mann-Kendall statistical trend analysis found no trend for cadmium levels in the intermediate monitoring wells PWS, P2M, P3EA, and P3O. Total chromium concentrations in the intermediate aquifer monitoring wells have consistently been less than the cleanup goal of 100 μg/L. The Mann-Kendall statistical trend analysis found chromium concentrations in the intermediate monitoring wells were decreasing in wells PWS and P2M, and no trend was observed in wells P3EA and P3O. With the exception of well P3EA, total lead concentrations in the intermediate aquifer monitoring wells have consistently been less than the cleanup goal of 15 μg/L. The lead concentrations in well
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P3EA for June 2018, 2021, and 2024 were 34.7 μg/L, 36 μg/L, and 64 μg/L, respectively. The Man-Kendall statistical trend analysis found lead concentrations in the intermediate monitoring wells were probably increasing in well P3EA, probably decreasing in well P2M, and no trend was observed in wells PWS and P3O. Manganese concentrations in the intermediate monitoring wells have consistently been less than the cleanup goal of 440 μg/L. The Mann-Kendall statistical trend analysis found manganese concentrations in the intermediate monitoring wells were probably increasing in well PWS, decreasing in well P2M and no trend was observed in wells P3EA and P3O. With the exception of well P3O, total molybdenum concentrations in the intermediate aquifer have consistently been less than the cleanup goal of 182 μg/L. The Mann-Kendall statistical trend analysis found molybdenum concentrations in the intermediate monitoring wells were decreasing in well P3O, stable in well PWS and P2M and no trend was observed in well P3EA.
8.0 CONCLUSION Based on the monitoring and sampling data for June 2023, the following conclusions can be made:
• The top-of-casing elevations for wells P2CA, P2HA, and P2FA need to be surveyed.
• Contaminants do not appear to be migrating off-site or to the intermediate aquifer.
• Dissolved metal concentrations in wells near the city drain did not exceed ACLs.
• Dissolved metal concentrations in the city drain did not exceed performance standards.
• Statistical evaluation of COC concentration trends in the intermediate aquifer found pH, levels were increasing in some wells.
• Statistical evaluation of COC concentration trends in the shallow aquifer found pH, arsenic, chromium, and manganese levels were increasing in some wells. DERR will continue to monitor the site in order to identify contaminant trends and assess the progress and validity of the monitored natural attenuation remedy. The next sampling event was completed in April 2024.
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9.0 REFERENCES GSI Environmental Inc. (GSI), 2012, GSI Mann-Kendall Toolkit for Constituent Trend Analysis Version 1, http://www.gsi-net.com/en/software/free-software/gsi-mann-kendall-toolkit.html. URS Greiner Woodward Clyde (URS), 1999, Final Operations and Maintenance and Monitoring Plan Sampling and Analysis Plan Quality Assurance Project Plan for the Portland Cement OU3 Site, Salt Lake City, Utah. United States Environmental Protection Agency (EPA), 2009, Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities Unified Guidance, U.S. Environmental Protection Agency, EPA/530/R-09-007.
FIGURES
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Site 3
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EXPLANATION
Portland Cement Site OU3
June 2023
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Site Loc ation
Figure 1Shallow Monitoring Well
#*City Drain Point Of Compliance
@A Intermediate Monitoring Wells
City Drain
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Indiana Avenue
Bending River Road
1040 South
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P2CA
4220.24
PWBA
4220.12
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P2HA
P2FA
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P3GB
4224.11
P3O
4219.48
P3DA
P2EA
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EXPLANATION
Portland Cement Site OU3
June 2023
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0 250 500 750 1,000125Feet
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City Drain
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Site Boundary
Groundwater Elevations in t he
Shallow and Intermediate Aquifers
Figure 2
Scale:1:4,500ÍShallow Aquifer Historical Gradient
Surplus Canal
§¨¦215
Redwood Road
Indiana Avenue
Bending River Road
1040 South
pH 1 0Arsenic600 μg/LCadmium0.5 2 J μg/LChromium1.3 J μg/LLead0.2 4 J μg/LManganese8.4 μg/LMolybdenum8700 J+ μg/L
PWEA
pH 9.6Arsenic91 μg/LCadmium0.15 J μg/LChromium2 μg/LManganese6.8 μg/LMolybdenum1500 J+ μg/L
PWBA
pH 9 .4Arsenic230 μg/LCadmium0.1 8 J μg/LChromium4.5 μg/LLead2.6 μg/LManganese57 μg/LMolybdenum15000 J+ μg/L
P2HA
pH 8.3Arsenic45 μg/LChromium1.1 J μg/LManganese110 μg/LMolybdenum38 J+ μg/L
P3BB
@A
pH 9.2Arsenic110 μg/LCadmium0.69 J μg/LChromium7.9 μg/LManganese27 μg/LMolybdenum60000 J+ μg/L
P2FA
pH 10Arsenic11 00 μg/LCadmium0.48 J μg/LChromium3.5 μg/LManganese23 μg/LMolybdenum31000 μg/L
P3 CC
pH 9 .2Arsenic190 μg/LChromium6.2 μg/LLead3 μg/LManganese39 μg/LMolybdenum810 J+ μg/L
P3DA
pH 8 .8Arsenic12 μg/LChromium0.5 5 J μg/LManganese17 μg/LMolybdenum290 J+ μg/L
P3GB
pH 9.2Arsenic220 μg/LChromium1.7 J μg/LLead3.8 μg/LManganese58 μg/LMolybdenum600 J+ μg/L
P3 FA
@A
@A
@A
@A
@A
@A
@A
@A
@A
EXPLANATION
Portland Cement Site OU3
June 2023
@A Shallow Monitoring Wells
City Drain
Sewer
Site Boundary
pH <8.00Arsenic64 µg/LCadmium6.2 µg/LChromium100 µg/LLead15 µg/LManganese440 µg/LMolybdenum182 µg/L
Cleanup Goals
Total Metal Concentrat ions
Detected in the Shallow Aquifer
Figure 3
0 250 500 750 1,000125Feet
®
1:4,500Scale:
#*
@A
@A
@A
@A
@A
Surplus Canal
§¨¦215
Indiana Avenue
Bending River Road
1040 South
pH 8.1Arsenic170 μg/LChromium0.6 J μg/LChromium VI 11 μg/LCopper2.9 J μg/LIron45 J μg/LLead0.19 J μg/LNickel5.7 μg/LSelenium1.8 J μg/LZinc8 μg/L
CDPOC
Ars e ni c 640 μg/LChromium1.4 J μg/LCopper1.7 J μg/LIron28 J μg/LNickel19 μg/LZinc0.7 J
PWEA
Ars e ni c 13 00 μg/LCadmium0.29 μg/LChromium3.7 μg/LChromium VI 78 μg/LCopper0.8 J μg/LIron37 J μg/LNickel7.4 μg/LSelenium3.9 J μg/LZinc0.73 J μg/L
P3 CC
Aluminum 12 J μg/LArsenic200 μg/LChromium0.51 J μg/LChromium VI 11 μg/LCopper0.44 J μg/LIron31 J μg/LNickel0.77 J μg/LZinc0.8 J μg/L
P3DA
Ars e nic 2 80 μg/LChromium0.3 3 J μg/LCopper0.8 5 J μg/LIron32 J μg/LNickel3 μg/LSelenium2.1 J μg/L
P3FA
Ars e ni c 9 7 μg/LCadmium0.6 5 μg/LChromium7.6 μg/LCopper1.8 J μg/LIron32 J μg/LNickel12 μg/LSelenium11 μg/LZinc0.8 J μg/L
P2 FA
EXPLANATION
Portland Cement Site OU3
June 2023
@A Shallow Monitoring Wells
#*City Drain Point Of Compliance
Sewer
Site Boundary
City Drain 0 250 500 750 1,000125Feet
®
1:4,500Scale:
Diss olved Metal Concentrations
Detected in the
ACL Wells and City Drain
Figure 4
pH 8 .1 3 - 1 1 .2 5Aluminum180.75 µg/LArsenic187.5 µg/LCadmium0.3 125 µg/LChromium92.5 µg/LChromium VI 1 3.75 µg/LCopper11.25 µg/LIron1250 µg/LLead3.1 3 µg/LMercury0.0 1 µg/LNickel65 µg/LSelenium5.7 5 µg/LSilver2 µg/LZinc150 µg/L
Surface WaterPerformance Standards Aluminum 4 502 .3 3 µg/LArsenic9832.6 8 µg/LCadmium139.08 µg/LChromium26339.8 1 µg/LChromium VI 5 69.26 µg/LCopper1564.5 µg/LIron25875.4 8 µg/LLead666.71 µg/LMercury0.6 2 µg/LNickel20667.9 4 µg/LSelenium258.75 µg/LSilver6.2 1 µg/LZinc13914.0 5 µg/L
GroundwaterACL Value
Surplus Canal
§¨¦215
Redwood Road
Indiana Avenue
Bending River Road
1040 South
pH 8 .2Arsenic31 μg/LChromium0.4 8 J μg/LManganese35 μg/LMolybdenum19 J+ μg/L
P3O
pH 7.8Arsenic38 μg/LCadmium2.4 J μg/LChromium0.94 J μg/LLead2.3 μg/LManganese62 μg/L
PWS
pH 8 .8Arsenic38 μg/LCadmium3.9 J μg/LChromium19 μg/LLead64 μg/LManganese430 μg/L
P3 EA
@A
@A
@A
EXPLANATION
Portland Cement Site OU3
June 2023
pH <8.00Arsenic64 µg/LCadmium6.2 µg/LChromium100 µg/LLead15 µg/LManganese440 µg/LMolybdenum182 µg/L
Cleanup Goals
@A Intermediate Monitoring Wells
City Drain
Sewer
Site Boundary 0 250 500 750 1,000125Feet
®
1:4,500Scale:
Total Metal Concentrations
Detected in the Intermediate Aquif er
Figure 5
TABLES
Table 1: Field Duplicate Results
Well ID PWEA PWAA¹CDPOC P3AA²
Sample Date 6/15/2022 6/15/2022 6/15/2022 6/15/2022
TDS mg/l @ 180C 9,220 8,830 4.32 1,770 1,660 6.41
pH standard units 10 10 0.00 8.1 8.1 0.00
Chromium VI < 10 < 10 NC 11 < 10 NC
Total Metals μg/l
Aluminum 20 U 20 U NC 37 41 10.26
Arsenic 600 630 4.88 180 180 0.00
Cadmium 0.52 0.71 30.89 0.2 U 0.2 U NC
Chromium 1.3 1.3 0.00 0.88 0.91 3.35
Copper 3.8 3.9 2.60 5.6 5.4 3.64
Iron 36 33 8.70 180 180 0.00
Lead 0.24 0.23 4.26 0.75 0.75 0.00
Manganese 8.4 8.5 1.18 760 760 0.00
Mercury NA NA NC 0.2 R 0.2 R NC
Molybdenum 8700 8500 2.33 440 440 0.00
Nickel 19 19 0.00 6.1 5.9 3.33
Selenium 5 U 1.6 NC 5 1.8 NC
Silver 1 UJ 1 UJ NC 1 UJ 1 UJ NC
Zinc 1.6 2.6 47.62 14 14 0.00
Dissolved Metals μg/l
Aluminum 20 U 20 U NC 20 U 20 U NC
Arsenic 640 650 1.55 170 170 0.00
Cadmium 0.2 U 0.2 U NC 0.2 U 0.2 U NC
Chromium 1.4 1.3 7.41 0.6 0.57 5.13
Copper 1.7 1.6 6.06 2.9 2.2 27.45
Iron 28 27 3.64 45 48 6.45
Lead 1 U 1 U NC 0.19 1 U NC
Manganese 8.2 8.3 1.21 730 740 1.36
Mercury 0.2 UJ 0.2 UJ NC 0.2 UJ 0.2 UJ NC
Molybdenum 9400 9300 1.07 420 430 2.35
Nickel 19 20 5.13 5.7 5.7 0.00
Selenium 5 U 2.6 NC 1.8 1.9 5.41
Silver 1 U 1 U NC 1 U 1 U NC
Zinc 0.7 5 U NC 8 7.6 5.13
¹Field Duplicate Sample of PWEA
²Field Duplicate Sample of CDPOC
< Measurement is below detection limit
U Undetected
R Rejected
UJ Undetected; the associated quantitation or reporting limit is considered to be an estimatedvalue.
NA Not Analyzed
NC Not Calculated
mg/l Milligrams per liter
µg/l Microgram per liter
Relative Percent
Difference
Relative Percent
Difference
Table 2: Groundwater Elevations
Well ID Northing*Easting*Top of Casing Elevation
(ft. amsl)
Screen Interval
(ft btoc)
Depth to Water
(ft btoc)
Groundwater
Elevation June
2023 (ft amsl)
PWEA 880166.13 1876367.68 4224.01 9.01 - 19.01 3.89 4220.12
PWBA 879561.32 1876767.30 4226.17 13.57 - 23.57 5.93 4220.24
P2BA¹878487.82 1877861.06 4226.65 10.65 - 20.65 NM NC
P2FA 879835.28 1877326.05 4227.75 12.75 - 22.75 6.37 4221.38
P2CA 878475.35 1877299.83 4226.31 13.81 - 23.81 5.96 4220.35
P2GA¹879046.76 1877716.67 4226.38 10.28 - 25.28 NM NC
P2HA 879156.93 1877388.40 4227.79 11.18 - 26.18 7.69 4220.1
P3CC 880037.80 1877335.80 4226.62 12.42 - 22.42 8.11 4218.51
P3DA 880444.80 1877307.50 4227.16 12.96 - 22.96 7.68 4219.48
P3FA 880821.03 1877274.47 4227.99 12.59 - 22.59 4.41 4223.58
P3GB 880630.22 1877703.28 4228.76 15.26 - 25.26 6.79 4221.97
P3BB 880012.76 1877910.67 4227.19 16.19 - 26.19 6.90 4220.29
PWS 879561.56 1876752.94 4226.78 36.88 - 46.88 3.47 4223.31
P2EA 878905.56 1877290.22 4227.78 36.48 - 46.48 3.27 4224.51
P2M¹878506.32 1877811.83 4227.04 34.44 - 44.44 NM NC
P3EA 880374.80 1877306.90 4227.23 36.63 - 46.63 2.34 4224.89
P3O 880643.12 1877767.30 4228.73 38.73 -48.73 4.62 4224.11
Note: Wells P2BA, P2GA, and P2M were inaccessible due to construction activity
NM Not Measured
NC Not Calculated
* UTM Coordinates
ft - feet
amsl - above mean sea level
btoc - below top of casing
¹ Monitoring Wells P2BA, P2GA, and P2M were inaccessible due to redevelopment construction activity
Intermediate Wells
Shallow Wells
Table 3: Summary of Final Water Quality Field Parameters
Location Date Recorded
Final
Temperature
(°C)
Final Specific
Conductance
(mS/cm)
Final pH
(standard units)
Final Turbidity
(NTU)
Final Dissolved
Oxygen (mg/L)
Final Oxidation
Reduction
Potential (mv)
Shallow Wells
PWEA 6/13/2023 12.61 9.63 9.65 0.0 0.61 -330
PWBA 6/13/2023 14.24 6.17 9.27 0.0 1.39 -350
P2BA¹NR NR NR NR NR NR NR
P2FA 6/16/2023 15.86 11.70 8.91 0.0 0.60 -322
P2HA 6/14/2023 17.46 17.80 9.02 21.5 0.72 -326
P3CC 6/16/2023 16.74 15.20 9.61 2.0 0.38 -415
P3DA 6/20/2023 15.75 2.27 8.90 107.0 0.53 -307
P3FA 6/16/2023 19.81 3.39 9.36 0.0 19.95 -109
P3GB 6/14/2023 15.22 2.54 8.37 1.7 6.50 -352
P3BB 6/20/2023 15.30 6.93 8.06 34.5 3.77 -310
Intermediate Wells
PWS 6/12/2023 20.79 0.434 7.72 51 2.40 -216
P2M¹NR NR NR NR NR NR NR
P3O 6/14/2023 14.91 0.681 7.90 0.9 3.04 -303
P3EA 6/20/2023 19.28 0.654 8.82 428 2.40 -205
Surface Water
CDPOC 6/12/2023 18.56 2.06 7.98 3.4 0.02 76
°C Degrees Celsius
mS/cm Millisiemens per centimeter
NTU Nephelometric Turbidity Unit
mg/L Milligrams per liter
mv Millivolts
NR Not Recorded
¹ Monitoring Wells P2BA and P2M were inaccessible due to redevelopment construction activity
Table 4: Shallow Aquifer Total Metals Concentrations
Well ID PWEA PWBA P2BA¹P2FA P2HA P3BB P3CC P3DA P3FA P3GB
Sample Date 6/13/2023 6/13/2023 NR 6/16/2023 6/14/2023 6/20/2023 6/16/2023 6/20/2023 6/20/2023 6/14/2023
TDS mg/l @ 180°C **9,220 5,250 NA 13,100 18,000 6,500 17,200 1,830 1,340 1,980
pH (Standard Units)<8.00 10.0 9.6 NA 9.2 9.4 8.3 10.0 9.2 9.2 8.8
Arsenic 64.0 600 91 NA 110 230 45 1100 190 220 12
Cadmium 6.20 0.52 J 0.15 J NA 0.69 J 0.18 J 0.2 U 0.48 J 0.2 U 0.2 U 0.2 U
Chromium 100.0 1.3 J 2 NA 7.9 4.5 1.1 J 3.5 6.2 1.7 J 0.55 J
Lead 15.0 0.24 J 1 U NA 1 U 2.6 1 U 1 U 3 3.8 1 U
Manganese 440.0 8.4 6.8 NA 27 57 110 23 39 58 17
Molybdenum 182.0 8700 J+1500 J+NA 60000 J+15000 J+38 J+31000 J+810 J+600 J+290 J+
¹ Monitoring Well P2BA was inaccessible due to redevelopment construction activity
NR Not Recorded
NA Not analyzed
** No value established
mg/l Milligrams per liter
µg/l Micrograms per liter
red values exceed cleanup goals
J Estimated positive result
J+ Estimated positive result biased high
U Undetected
Cleanup Goals
μg/l
Table 5: Comparison of ACL Monitoring Well Results to ACL
Well ID PWEA P2FA P3CC P3DA P3FA
Sample Date 6/13/2023 6/16/2023 6/16/2023 6/20/2023 6/20/2023
Dissolved Dissolved Dissolved Dissolved Dissolved
Aluminum 4502.33 20 U 20 U 20 U 12 J 20 U
Arsenic 9832.68 640 97 1300 200 280
Cadmium 139.08 0.2 U 0.65 0.29 0.2 U 0.2 U
Chromium 26339.81 1.4 J 7.6 3.7 0.51 J 0.33 J
Chromium VI 569.26 < 10 < 10 78 11 < 10
Copper 1564.50 1.7 J 1.8 J 0.8 J 0.44 J 0.85 J
Iron 25875.48 28 J 32 J 37 J 31 J 32 J
Lead 666.71 1 U 1 U 1 U 1 U 1 U
Mercury 0.62 0.2 UJ 0.2 UJ 0.2 UJ 0.2 UJ 0.2 UJ
Nickel 20667.94 19 12 7.4 0.77 J 3
Selenium 258.75 5 U 11 3.9 J 5 U 2.1 J
Silver 6.21 1 U 1 U 1 U 1 U 1 U
Zinc 13914.05 0.7 J 0.8 J 0.73 J 0.8 J 5 U
µg/l Micrograms per liter
< Measurement is below detection limit
J Estimated positive result
UJ Undetected; the associated quantitation or reporting limit is considered to be an estimatedvalue.
U Undetected
ACL Value
(μg/L)
Table 6: Surface Water Metal Concentrations
Location ID CDPOC CDPOC
Sample Date 6/12/2023 6/12/2023
Total Dissolved
TDS mg/L @ 180°C **1,770 NA
pH 8.13 - 11.25 8.1 NA
Aluminum 180.75 37 20 U
Arsenic 187.5 180 170
Cadmium 0.3125 0.2 U 0.2 U
Chromium 92.5 0.88 J 0.6 J
Chromium VI 13.75 NA 11
Copper 11.25 5.6 2.9 J
Iron 1250 180 J 45 J
Lead 3.13 0.75 J 0.19 J
Mercury 0.01 0.2 R 0.2 UJ
Nickel 65 6.1 5.7
Selenium 5.75 5 U 1.8 J
Silver 2 1 UJ 1 U
Zinc 150 14 8
mg/l Milligrams per liter
µg/l Micrograms per liter
** No value established
red values exceed cleanup goals
NA Not applicable
J Estimated positive result
U Undetected
UJ Undetected; the associated quantitation or reporting limit is considered to be an estimatedvalue.
R Rejected
Performance
Standards μg/l
Table 7: Intermediate Aquifer Total Metal Concentrations
Well ID PWS P2M¹P3EA P3O
Sample Date 6/12/2023 NR 6/20/2023 6/14/2023
TDS mg/l @ 180C **372 NA 488 520
pH (Standard Units)<8.00 7.8 NA 8.8 8.2
Arsenic 64 38 NA 38 31
Cadmium 6.2 2.4 J NA 3.9 J 0.2 U
Chromium 100 0.94 J NA 19 0.48 J
Lead 15 2.3 NA 64 1 U
Manganese 440 62 NA 430 35
Molybdenum 182 10 U NA 10 U 19 J+
¹ Monitoring Well P2M was inaccessible due to redevelopment construction activity
NR Not Recorded
NA Not analyzed
mg/l Milligrams per liter
µg/l Micrograms per liter
red values exceed clean-up goal
** No value established
J Estimated positive result
J+ Estimated positive result biased high
U - Undetected
Cleanup Goals
μg/l
Appendix A:
Water Quality Field Parameters
Appendix B:
Analytical Results
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 1 Thu, 13 Jul 2023 09:17:59
Sample Number: LCS01 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: pH: Sample Date: Sample Time:
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Spike 40 ug/L 40 1 YES S3VE
Antimony Spike 4.1 J+ug/L 4.1 1 YES S3VE
Arsenic Spike 2.1 ug/L 2.1 1 YES S3VE
Barium Spike 19 ug/L 19 1 YES S3VE
Beryllium Spike 1.9 ug/L 1.9 1 YES S3VE
Calcium Spike 920 ug/L 920 1 YES S3VE
Chromium Spike 3.8 ug/L 3.8 1 YES S3VE
Cobalt Spike 2.2 J+ug/L 2.2 1 YES S3VE
Copper Spike 4.3 ug/L 4.3 1 YES S3VE
Iron Spike 370 ug/L 370 1 YES S3VE
Lead Spike 1.9 ug/L 1.9 1 YES S3VE
Magnesium Spike 970 ug/L 970 1 YES S3VE
Manganese Spike 2.2 ug/L 2.2 1 YES S3VE
Nickel Spike 2.3 ug/L 2.3 1 YES S3VE
Potassium Spike 1000 J+ug/L 1000 1 YES S3VE
Selenium Spike 9.7 ug/L 9.7 1 YES S3VE
Silver Spike 1.8 ug/L 1.8 1 YES S3VE
Sodium Spike 1000 J+ug/L 1000 1 YES S3VE
Thallium Spike 1.9 ug/L 1.9 1 YES S3VE
Vanadium Spike 9.7 ug/L 9.7 1 YES S3VE
Zinc Spike 9.9 ug/L 9.9 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 2 Thu, 13 Jul 2023 09:17:59
Sample Number: LCS02 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: pH: Sample Date: Sample Time:
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Cadmium Spike 0.43 ug/L 0.43 1 YES S3VE
Molybdenum Spike 20 J+ug/L 20 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 3 Thu, 13 Jul 2023 09:17:59
Sample Number: MH0AF0 Method: Mercury by Cold Vapor Matrix: Water MA Number:
Sample Location: CDPOC-D pH: 1.Sample Date: 06/12/2023 Sample Time: 14:11:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Mercury Target 0.20 UJ ug/L 0.20 U 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 4 Thu, 13 Jul 2023 09:17:59
Sample Number: MH0AF0 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: CDPOC-D pH: 1.Sample Date: 06/12/2023 Sample Time: 14:11:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 20 U ug/L 20 U 1 YES S3VE
Antimony Target 2.5 J+ug/L 2.5 1 YES S3VE
Arsenic Target 170 ug/L 170 1 YES S3VE
Barium Target 77 ug/L 77 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 0.20 U ug/L 0.20 U 1 YES S3VE
Calcium Target 73000 ug/L 73000 1 YES S3VE
Chromium Target 0.60 J ug/L 0.60 J 1 YES S3VE
Cobalt Target 1.5 J+ug/L 1.5 1 YES S3VE
Copper Target 2.9 ug/L 2.9 1 YES S3VE
Iron Target 45 J ug/L 45 J 1 YES S3VE
Lead Target 0.19 J ug/L 0.19 J 1 YES S3VE
Magnesium Target 50000 ug/L 50000 1 YES S3VE
Manganese Target 730 ug/L 730 1 YES S3VE
Nickel Target 5.7 ug/L 5.7 1 YES S3VE
Potassium Target 81000 J+ug/L 81000 1 YES S3VE
Selenium Target 1.8 J ug/L 1.8 J 1 YES S3VE
Silver Target 1.0 U ug/L 1.0 U 1 YES S3VE
Sodium Target 440000 J+ug/L 440000 D 10 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 4.7 J ug/L 4.7 J 1 YES S3VE
Zinc Target 8.0 ug/L 8.0 1 YES S3VE
Molybdenum Target 420 J+ug/L 420 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 5 Thu, 13 Jul 2023 09:17:59
Sample Number: MH0AF2 Method: Mercury by Cold Vapor Matrix: Water MA Number:
Sample Location: P3AA-D pH: 1.Sample Date: 06/12/2023 Sample Time: 12:36:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Mercury Target 0.20 UJ ug/L 0.20 U 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 6 Thu, 13 Jul 2023 09:17:59
Sample Number: MH0AF2 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: P3AA-D pH: 1.Sample Date: 06/12/2023 Sample Time: 12:36:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 20 U ug/L 20 U 1 YES S3VE
Antimony Target 2.6 J+ug/L 2.6 1 YES S3VE
Arsenic Target 170 ug/L 170 1 YES S3VE
Barium Target 78 ug/L 78 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 0.20 U ug/L 0.20 U 1 YES S3VE
Calcium Target 74000 ug/L 74000 1 YES S3VE
Chromium Target 0.57 J ug/L 0.57 J 1 YES S3VE
Cobalt Target 1.5 J+ug/L 1.5 1 YES S3VE
Copper Target 2.2 ug/L 2.2 1 YES S3VE
Iron Target 48 J ug/L 48 J 1 YES S3VE
Lead Target 1.0 U ug/L 1.0 U 1 YES S3VE
Magnesium Target 51000 ug/L 51000 1 YES S3VE
Manganese Target 740 ug/L 740 1 YES S3VE
Nickel Target 5.7 ug/L 5.7 1 YES S3VE
Potassium Target 82000 J+ug/L 82000 1 YES S3VE
Selenium Target 1.9 J ug/L 1.9 J 1 YES S3VE
Silver Target 1.0 U ug/L 1.0 U 1 YES S3VE
Sodium Target 440000 J+ug/L 440000 D 10 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 4.8 J ug/L 4.8 J 1 YES S3VE
Zinc Target 7.6 ug/L 7.6 1 YES S3VE
Molybdenum Target 430 J+ug/L 430 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 7 Thu, 13 Jul 2023 09:17:59
Sample Number: MH0AF4 Method: Mercury by Cold Vapor Matrix: Water MA Number:
Sample Location: PWEA-D pH: 1.Sample Date: 06/13/2023 Sample Time: 14:42:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Mercury Target 0.20 UJ ug/L 0.20 U 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 8 Thu, 13 Jul 2023 09:17:59
Sample Number: MH0AF4 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: PWEA-D pH: 1.Sample Date: 06/13/2023 Sample Time: 14:42:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 20 U ug/L 20 U 1 YES S3VE
Antimony Target 2.0 U ug/L 0.40 J 1 YES S3VE
Arsenic Target 640 ug/L 640 1 YES S3VE
Barium Target 52 ug/L 52 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 0.20 U ug/L 0.20 U 1 YES S3VE
Calcium Target 1600 ug/L 1600 1 YES S3VE
Chromium Target 1.4 J ug/L 1.4 J 1 YES S3VE
Cobalt Target 1.0 U ug/L 0.97 J 1 YES S3VE
Copper Target 1.7 J ug/L 1.7 J 1 YES S3VE
Iron Target 28 J ug/L 28 J 1 YES S3VE
Lead Target 1.0 U ug/L 1.0 U 1 YES S3VE
Magnesium Target 1400 ug/L 1400 1 YES S3VE
Manganese Target 8.2 ug/L 8.2 1 YES S3VE
Nickel Target 19 ug/L 19 1 YES S3VE
Potassium Target 1500000 J+ug/L 1500000 D 50 YES S3VE
Selenium Target 5.0 U ug/L 5.0 U 1 YES S3VE
Silver Target 1.0 U ug/L 1.0 U 1 YES S3VE
Sodium Target 2500000 J+ug/L 2500000 D 50 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 13 ug/L 13 1 YES S3VE
Zinc Target 0.70 J ug/L 0.70 J 1 YES S3VE
Molybdenum Target 9400 J+ug/L 9400 D 10 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 9 Thu, 13 Jul 2023 09:17:59
Sample Number: MH0AF6 Method: Mercury by Cold Vapor Matrix: Water MA Number:
Sample Location: PWAA-D pH: 1.Sample Date: 06/13/2023 Sample Time: 14:45:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Mercury Target 0.20 UJ ug/L 0.20 U 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 10 Thu, 13 Jul 2023 09:17:59
Sample Number: MH0AF6 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: PWAA-D pH: 1.Sample Date: 06/13/2023 Sample Time: 14:45:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 20 U ug/L 20 U 1 YES S3VE
Antimony Target 2.0 U ug/L 0.41 J 1 YES S3VE
Arsenic Target 650 ug/L 650 1 YES S3VE
Barium Target 53 ug/L 53 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 0.20 U ug/L 0.20 U 1 YES S3VE
Calcium Target 1600 ug/L 1600 1 YES S3VE
Chromium Target 1.3 J ug/L 1.3 J 1 YES S3VE
Cobalt Target 1.0 J+ug/L 1.0 1 YES S3VE
Copper Target 1.6 J ug/L 1.6 J 1 YES S3VE
Iron Target 27 J ug/L 27 J 1 YES S3VE
Lead Target 1.0 U ug/L 1.0 U 1 YES S3VE
Magnesium Target 1400 ug/L 1400 1 YES S3VE
Manganese Target 8.3 ug/L 8.3 1 YES S3VE
Nickel Target 20 ug/L 20 1 YES S3VE
Potassium Target 1500000 J+ug/L 1500000 D 50 YES S3VE
Selenium Target 2.6 J ug/L 2.6 J 1 YES S3VE
Silver Target 1.0 U ug/L 1.0 U 1 YES S3VE
Sodium Target 2600000 J+ug/L 2600000 D 50 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 14 ug/L 14 1 YES S3VE
Zinc Target 5.0 U ug/L 5.0 U 1 YES S3VE
Molybdenum Target 9300 J+ug/L 9300 D 10 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 11 Thu, 13 Jul 2023 09:17:59
Sample Number: MH0AG3 Method: Mercury by Cold Vapor Matrix: Water MA Number:
Sample Location: P2FA-D pH: 1.Sample Date: 06/16/2023 Sample Time: 14:20:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Mercury Target 0.20 UJ ug/L 0.20 U 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 12 Thu, 13 Jul 2023 09:17:59
Sample Number: MH0AG3 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: P2FA-D pH: 1.Sample Date: 06/16/2023 Sample Time: 14:20:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 20 U ug/L 20 U 1 YES S3VE
Antimony Target 2.0 U ug/L 1.0 J 1 YES S3VE
Arsenic Target 97 ug/L 97 1 YES S3VE
Barium Target 68 ug/L 68 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 0.65 ug/L 0.65 1 YES S3VE
Calcium Target 3900 ug/L 3900 1 YES S3VE
Chromium Target 7.6 ug/L 7.6 1 YES S3VE
Cobalt Target 2.3 J+ug/L 2.3 1 YES S3VE
Copper Target 1.8 J ug/L 1.8 J 1 YES S3VE
Iron Target 32 J ug/L 32 J 1 YES S3VE
Lead Target 1.0 U ug/L 1.0 U 1 YES S3VE
Magnesium Target 21000 ug/L 21000 1 YES S3VE
Manganese Target 27 ug/L 27 1 YES S3VE
Nickel Target 12 ug/L 12 1 YES S3VE
Potassium Target 880000 J+ug/L 880000 D 50 YES S3VE
Selenium Target 11 ug/L 11 1 YES S3VE
Silver Target 1.0 U ug/L 1.0 U 1 YES S3VE
Sodium Target 4100000 J+ug/L 4100000 D 50 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 18 ug/L 18 1 YES S3VE
Zinc Target 0.80 J ug/L 0.80 J 1 YES S3VE
Molybdenum Target 64000 J+ug/L 64000 D 50 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 13 Thu, 13 Jul 2023 09:17:59
Sample Number: MH0AG5 Method: Mercury by Cold Vapor Matrix: Water MA Number:
Sample Location: P3CC-D pH: 1.Sample Date: 06/16/2023 Sample Time: 11:21:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Mercury Target 0.20 UJ ug/L 0.20 U 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 14 Thu, 13 Jul 2023 09:17:59
Sample Number: MH0AG5 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: P3CC-D pH: 1.Sample Date: 06/16/2023 Sample Time: 11:21:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 20 U ug/L 20 U 1 YES S3VE
Antimony Target 2.0 U ug/L 0.66 J 1 YES S3VE
Arsenic Target 1300 ug/L 1300 D 100 YES S3VE
Barium Target 280 ug/L 280 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 0.29 ug/L 0.29 1 YES S3VE
Calcium Target 7200 ug/L 7200 1 YES S3VE
Chromium Target 3.7 ug/L 3.7 1 YES S3VE
Cobalt Target 1.0 U ug/L 0.54 J 1 YES S3VE
Copper Target 0.80 J ug/L 0.80 J 1 YES S3VE
Iron Target 37 J ug/L 37 J 1 YES S3VE
Lead Target 1.0 U ug/L 1.0 U 1 YES S3VE
Magnesium Target 13000 ug/L 13000 1 YES S3VE
Manganese Target 22 ug/L 22 1 YES S3VE
Nickel Target 7.4 ug/L 7.4 1 YES S3VE
Potassium Target 2200000 J+ug/L 2200000 D 100 YES S3VE
Selenium Target 3.9 J ug/L 3.9 J 1 YES S3VE
Silver Target 1.0 U ug/L 1.0 U 1 YES S3VE
Sodium Target 4600000 J+ug/L 4600000 D 100 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 30 ug/L 30 1 YES S3VE
Zinc Target 0.73 J ug/L 0.73 J 1 YES S3VE
Molybdenum Target 32000 J+ug/L 32000 D 25 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 15 Thu, 13 Jul 2023 09:17:59
Sample Number: MH0AG8 Method: Mercury by Cold Vapor Matrix: Water MA Number:
Sample Location: P3DA-D pH: 1.Sample Date: 06/20/2023 Sample Time: 13:18:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Mercury Target 0.20 UJ ug/L 0.20 U 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 16 Thu, 13 Jul 2023 09:17:59
Sample Number: MH0AG8 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: P3DA-D pH: 1.Sample Date: 06/20/2023 Sample Time: 13:18:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 12 J ug/L 12 J 1 YES S3VE
Antimony Target 2.0 U ug/L 2.0 U 1 YES S3VE
Arsenic Target 200 ug/L 200 1 YES S3VE
Barium Target 160 ug/L 160 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 0.20 U ug/L 0.20 U 1 YES S3VE
Calcium Target 8400 ug/L 8400 1 YES S3VE
Chromium Target 0.51 J ug/L 0.51 J 1 YES S3VE
Cobalt Target 1.0 U ug/L 0.15 J 1 YES S3VE
Copper Target 0.44 J ug/L 0.44 J 1 YES S3VE
Iron Target 31 J ug/L 31 J 1 YES S3VE
Lead Target 1.0 U ug/L 1.0 U 1 YES S3VE
Magnesium Target 10000 ug/L 10000 1 YES S3VE
Manganese Target 13 ug/L 13 1 YES S3VE
Nickel Target 0.77 J ug/L 0.77 J 1 YES S3VE
Potassium Target 160000 J+ug/L 160000 D 10 YES S3VE
Selenium Target 5.0 U ug/L 5.0 U 1 YES S3VE
Silver Target 1.0 U ug/L 1.0 U 1 YES S3VE
Sodium Target 580000 J+ug/L 580000 D 10 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 5.3 ug/L 5.3 1 YES S3VE
Zinc Target 0.80 J ug/L 0.80 J 1 YES S3VE
Molybdenum Target 890 J+ug/L 890 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 17 Thu, 13 Jul 2023 09:17:59
Sample Number: MH0AH3 Method: Mercury by Cold Vapor Matrix: Water MA Number:
Sample Location: P3FA-D pH: 1.Sample Date: 06/20/2023 Sample Time: 11:14:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Mercury Target 0.20 UJ ug/L 0.20 U 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 18 Thu, 13 Jul 2023 09:17:59
Sample Number: MH0AH3 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: P3FA-D pH: 1.Sample Date: 06/20/2023 Sample Time: 11:14:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 20 U ug/L 20 U 1 YES S3VE
Antimony Target 2.0 U ug/L 0.65 J 1 YES S3VE
Arsenic Target 290 ug/L 290 1 YES S3VE
Barium Target 40 ug/L 40 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 0.20 U ug/L 0.20 U 1 YES S3VE
Calcium Target 4400 ug/L 4400 1 YES S3VE
Chromium Target 0.37 J ug/L 0.37 J 1 YES S3VE
Cobalt Target 1.0 U ug/L 0.46 J 1 YES S3VE
Copper Target 0.98 J ug/L 0.98 J 1 YES S3VE
Iron Target 30 J ug/L 30 J 1 YES S3VE
Lead Target 1.0 U ug/L 1.0 U 1 YES S3VE
Magnesium Target 7100 ug/L 7100 1 YES S3VE
Manganese Target 12 ug/L 12 1 YES S3VE
Nickel Target 3.3 ug/L 3.3 1 YES S3VE
Potassium Target 380000 J+ug/L 380000 D 5 YES S3VE
Selenium Target 2.1 J ug/L 2.1 J 1 YES S3VE
Silver Target 1.0 U ug/L 1.0 U 1 YES S3VE
Sodium Target 350000 J+ug/L 350000 D 5 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 22 ug/L 22 1 YES S3VE
Zinc Target 5.0 U ug/L 5.0 U 1 YES S3VE
Molybdenum Target 940 J+ug/L 940 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 19 Thu, 13 Jul 2023 09:17:59
Sample Number: MH0AH3D Method: Mercury by Cold Vapor Matrix: Water MA Number:
Sample Location: pH: 1.Sample Date: 06/20/2023 Sample Time: 11:14:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Mercury Target 0.20 UJ ug/L 0.20 U 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 20 Thu, 13 Jul 2023 09:17:59
Sample Number: MH0AH3D Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: pH: 1.Sample Date: 06/20/2023 Sample Time: 11:14:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 20 U ug/L 20 U 1 YES S3VE
Antimony Target 2.0 U ug/L 0.59 J 1 YES S3VE
Arsenic Target 280 ug/L 280 1 YES S3VE
Barium Target 39 ug/L 39 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 0.20 U ug/L 0.20 U 1 YES S3VE
Calcium Target 4400 ug/L 4400 1 YES S3VE
Chromium Target 0.33 J ug/L 0.33 J 1 YES S3VE
Cobalt Target 1.0 U ug/L 0.29 J 1 YES S3VE
Copper Target 0.85 J ug/L 0.85 J 1 YES S3VE
Iron Target 30 J ug/L 30 J 1 YES S3VE
Lead Target 1.0 U ug/L 1.0 U 1 YES S3VE
Magnesium Target 7000 ug/L 7000 1 YES S3VE
Manganese Target 12 ug/L 12 1 YES S3VE
Nickel Target 3.0 ug/L 3.0 1 YES S3VE
Potassium Target 380000 J+ug/L 380000 D 5 YES S3VE
Selenium Target 2.2 J ug/L 2.2 J 1 YES S3VE
Silver Target 1.0 U ug/L 1.0 U 1 YES S3VE
Sodium Target 340000 J+ug/L 340000 D 5 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 22 ug/L 22 1 YES S3VE
Zinc Target 5.0 U ug/L 5.0 U 1 YES S3VE
Molybdenum Target 930 J+ug/L 930 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 21 Thu, 13 Jul 2023 09:17:59
Sample Number: MH0AH3L Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: pH: 1.Sample Date: Sample Time:
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 100 U ug/L 100 U 5 YES S3VE
Antimony Target 10 U ug/L 10 U 5 YES S3VE
Arsenic Target 290 ug/L 290 5 YES S3VE
Barium Target 41 J ug/L 41 J 5 YES S3VE
Beryllium Target 5.0 U ug/L 5.0 U 5 YES S3VE
Cadmium Target 1.0 U ug/L 1.0 U 5 YES S3VE
Calcium Target 4500 ug/L 4500 5 YES S3VE
Chromium Target 10 U ug/L 10 U 5 YES S3VE
Cobalt Target 5.0 U ug/L 0.58 J 5 YES S3VE
Copper Target 1.1 J ug/L 1.1 J 5 YES S3VE
Iron Target 1000 U ug/L 1000 U 5 YES S3VE
Lead Target 5.0 U ug/L 5.0 U 5 YES S3VE
Magnesium Target 7300 ug/L 7300 5 YES S3VE
Manganese Target 12 ug/L 12 5 YES S3VE
Nickel Target 2.8 J ug/L 2.8 J 5 YES S3VE
Potassium Target 380000 J+ug/L 380000 D 25 YES S3VE
Selenium Target 25 U ug/L 25 U 5 YES S3VE
Silver Target 5.0 U ug/L 5.0 U 5 YES S3VE
Sodium Target 360000 J+ug/L 360000 D 25 YES S3VE
Thallium Target 5.0 U ug/L 5.0 U 5 YES S3VE
Vanadium Target 23 J ug/L 23 J 5 YES S3VE
Zinc Target 25 U ug/L 25 U 5 YES S3VE
Molybdenum Target 800 J+ug/L 800 5 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 22 Thu, 13 Jul 2023 09:17:59
Sample Number: MH0AH3S Method: Mercury by Cold Vapor Matrix: Water MA Number:
Sample Location: pH: 1.Sample Date: 06/20/2023 Sample Time: 11:14:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Mercury Spike 0.89 J-ug/L 0.89 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 23 Thu, 13 Jul 2023 09:17:59
Sample Number: MH0AH3S Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: pH: 1.Sample Date: 06/20/2023 Sample Time: 11:14:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Antimony Spike 110 J+ug/L 110 1 YES S3VE
Arsenic Spike 330 ug/L 330 1 YES S3VE
Barium Spike 2000 ug/L 2000 1 YES S3VE
Beryllium Spike 54 ug/L 54 1 YES S3VE
Cadmium Spike 48 ug/L 48 1 YES S3VE
Chromium Spike 180 ug/L 180 1 YES S3VE
Cobalt Spike 530 J+ug/L 530 1 YES S3VE
Copper Spike 260 ug/L 260 1 YES S3VE
Lead Spike 18 ug/L 18 1 YES S3VE
Manganese Spike 470 ug/L 470 1 YES S3VE
Nickel Spike 520 ug/L 520 1 YES S3VE
Selenium Spike 100 ug/L 100 1 YES S3VE
Silver Spike 38 ug/L 38 1 YES S3VE
Thallium Spike 45 ug/L 45 1 YES S3VE
Vanadium Spike 490 ug/L 490 1 YES S3VE
Zinc Spike 450 ug/L 450 1 YES S3VE
Molybdenum Spike 1000 J+ug/L 1000 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 24 Thu, 13 Jul 2023 09:17:59
Sample Number: PBW01 Method: Mercury by Cold Vapor Matrix: Water MA Number:
Sample Location: pH: Sample Date: Sample Time:
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Mercury Target 0.20 UJ ug/L 0.20 U 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 25 Thu, 13 Jul 2023 09:17:59
Sample Number: PBW01 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: pH: Sample Date: Sample Time:
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 20 U ug/L 20 U 1 YES S3VE
Antimony Target 2.0 U ug/L 2.0 U 1 YES S3VE
Arsenic Target 1.0 U ug/L 1.0 U 1 YES S3VE
Barium Target 10 U ug/L 10 U 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Calcium Target 500 U ug/L 500 U 1 YES S3VE
Chromium Target 2.0 U ug/L 2.0 U 1 YES S3VE
Cobalt Target 1.0 U ug/L 1.0 U 1 YES S3VE
Copper Target 2.0 U ug/L 2.0 U 1 YES S3VE
Iron Target 200 U ug/L 200 U 1 YES S3VE
Lead Target 1.0 U ug/L 1.0 U 1 YES S3VE
Magnesium Target 500 U ug/L 500 U 1 YES S3VE
Manganese Target 1.0 U ug/L 1.0 U 1 YES S3VE
Nickel Target 1.0 U ug/L 1.0 U 1 YES S3VE
Potassium Target 59 J ug/L 59 J 1 YES S3VE
Selenium Target 5.0 U ug/L 5.0 U 1 YES S3VE
Silver Target 1.0 U ug/L 1.0 U 1 YES S3VE
Sodium Target 48 J ug/L 48 J 1 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 5.0 U ug/L 5.0 U 1 YES S3VE
Zinc Target 5.0 U ug/L 5.0 U 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 26 Thu, 13 Jul 2023 09:17:59
Sample Number: PBW02 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: pH: Sample Date: Sample Time:
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Cadmium Target 0.20 U ug/L 0.20 U 1 YES S3VE
Molybdenum Target 0.12 J ug/L 0.12 J 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AF2 Lab Name: Bonner Analytical Testing Co.
Page 27 Thu, 13 Jul 2023 09:17:59
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 1 Thu, 13 Jul 2023 14:47:45
Sample Number: LCS01 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: pH: Sample Date: Sample Time:
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Spike 38 ug/L 38 1 YES S3VE
Antimony Spike 4.2 J+ug/L 4.2 1 YES S3VE
Arsenic Spike 2.0 ug/L 2.0 1 YES S3VE
Barium Spike 19 ug/L 19 1 YES S3VE
Beryllium Spike 2.0 ug/L 2.0 1 YES S3VE
Calcium Spike 930 ug/L 930 1 YES S3VE
Chromium Spike 4.0 ug/L 4.0 1 YES S3VE
Cobalt Spike 2.2 ug/L 2.2 1 YES S3VE
Copper Spike 4.3 ug/L 4.3 1 YES S3VE
Iron Spike 380 ug/L 380 1 YES S3VE
Lead Spike 2.0 ug/L 2.0 1 YES S3VE
Magnesium Spike 960 ug/L 960 1 YES S3VE
Manganese Spike 2.2 ug/L 2.2 1 YES S3VE
Nickel Spike 2.2 ug/L 2.2 1 YES S3VE
Potassium Spike 970 J+ug/L 970 1 YES S3VE
Selenium Spike 9.8 ug/L 9.8 1 YES S3VE
Silver Spike 1.9 ug/L 1.9 1 YES S3VE
Sodium Spike 1000 J+ug/L 1000 1 YES S3VE
Thallium Spike 1.9 ug/L 1.9 1 YES S3VE
Vanadium Spike 9.8 ug/L 9.8 1 YES S3VE
Zinc Spike 10 ug/L 10 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 2 Thu, 13 Jul 2023 14:47:45
Sample Number: LCS02 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: pH: Sample Date: Sample Time:
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Cadmium Spike 0.48 ug/L 0.48 1 YES S3VE
Molybdenum Spike 20 J+ug/L 20 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 3 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AE9 Method: Mercury by Cold Vapor Matrix: Water MA Number:
Sample Location: CDPOC pH: 1.Sample Date: 06/12/2023 Sample Time: 14:11:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Mercury Target 0.20 R ug/L 0.20 U 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 4 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AE9 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: CDPOC pH: 1.Sample Date: 06/12/2023 Sample Time: 14:11:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 37 ug/L 37 1 YES S3VE
Antimony Target 2.9 J+ug/L 2.9 1 YES S3VE
Arsenic Target 180 ug/L 180 1 YES S3VE
Barium Target 80 ug/L 80 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 0.20 U ug/L 0.20 U 1 YES S3VE
Calcium Target 73000 ug/L 73000 1 YES S3VE
Chromium Target 0.88 J ug/L 0.88 J 1 YES S3VE
Cobalt Target 1.5 ug/L 1.5 1 YES S3VE
Copper Target 5.6 ug/L 5.6 1 YES S3VE
Iron Target 180 J ug/L 180 J 1 YES S3VE
Lead Target 0.75 J ug/L 0.75 J 1 YES S3VE
Magnesium Target 51000 ug/L 51000 1 YES S3VE
Manganese Target 760 ug/L 760 1 YES S3VE
Nickel Target 6.1 ug/L 6.1 1 YES S3VE
Potassium Target 82000 J+ug/L 82000 1 YES S3VE
Selenium Target 5.0 U ug/L 5.0 U 1 YES S3VE
Silver Target 1.0 UJ ug/L 1.0 U*1 YES S3VE
Sodium Target 440000 J+ug/L 440000 D 5 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 4.9 J ug/L 4.9 J 1 YES S3VE
Zinc Target 14 ug/L 14 1 YES S3VE
Molybdenum Target 440 J+ug/L 440 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 5 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AF1 Method: Mercury by Cold Vapor Matrix: Water MA Number:
Sample Location: P3AA pH: 1.Sample Date: 06/12/2023 Sample Time: 12:36:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Mercury Target 0.20 R ug/L 0.20 U 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 6 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AF1 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: P3AA pH: 1.Sample Date: 06/12/2023 Sample Time: 12:36:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 41 ug/L 41 1 YES S3VE
Antimony Target 2.8 J+ug/L 2.8 1 YES S3VE
Arsenic Target 180 ug/L 180 1 YES S3VE
Barium Target 82 ug/L 82 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 0.20 U ug/L 0.20 U 1 YES S3VE
Calcium Target 74000 ug/L 74000 1 YES S3VE
Chromium Target 0.91 J ug/L 0.91 J 1 YES S3VE
Cobalt Target 1.5 ug/L 1.5 1 YES S3VE
Copper Target 5.4 ug/L 5.4 1 YES S3VE
Iron Target 180 J ug/L 180 J 1 YES S3VE
Lead Target 0.75 J ug/L 0.75 J 1 YES S3VE
Magnesium Target 50000 ug/L 50000 1 YES S3VE
Manganese Target 760 ug/L 760 1 YES S3VE
Nickel Target 5.9 ug/L 5.9 1 YES S3VE
Potassium Target 84000 J+ug/L 84000 1 YES S3VE
Selenium Target 1.8 J ug/L 1.8 J 1 YES S3VE
Silver Target 1.0 UJ ug/L 1.0 U*1 YES S3VE
Sodium Target 450000 J+ug/L 450000 D 5 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 5.1 ug/L 5.1 1 YES S3VE
Zinc Target 14 ug/L 14 1 YES S3VE
Molybdenum Target 440 J+ug/L 440 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 7 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AF3 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: PWEA pH: 1.Sample Date: 06/13/2023 Sample Time: 14:42:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 20 U ug/L 20 U 1 YES S3VE
Antimony Target 2.0 U ug/L 0.46 J 1 YES S3VE
Arsenic Target 600 ug/L 600 1 YES S3VE
Barium Target 52 ug/L 52 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 0.52 ug/L 0.52 1 YES S3VE
Calcium Target 1500 ug/L 1500 1 YES S3VE
Chromium Target 1.3 J ug/L 1.3 J 1 YES S3VE
Cobalt Target 0.94 J ug/L 0.94 J 1 YES S3VE
Copper Target 3.8 ug/L 3.8 1 YES S3VE
Iron Target 36 J ug/L 36 J 1 YES S3VE
Lead Target 0.24 J ug/L 0.24 J 1 YES S3VE
Magnesium Target 1400 ug/L 1400 1 YES S3VE
Manganese Target 8.4 ug/L 8.4 1 YES S3VE
Nickel Target 19 ug/L 19 1 YES S3VE
Potassium Target 1400000 J+ug/L 1400000 D 50 YES S3VE
Selenium Target 5.0 U ug/L 5.0 U 1 YES S3VE
Silver Target 1.0 UJ ug/L 1.0 U*1 YES S3VE
Sodium Target 2400000 J+ug/L 2400000 D 50 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 14 ug/L 14 1 YES S3VE
Zinc Target 1.6 J ug/L 1.6 J 1 YES S3VE
Molybdenum Target 8700 J+ug/L 8700 D 10 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 8 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AF5 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: PWAA pH: 1.Sample Date: 06/13/2023 Sample Time: 14:45:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 20 U ug/L 20 U 1 YES S3VE
Antimony Target 2.0 U ug/L 0.44 J 1 YES S3VE
Arsenic Target 630 ug/L 630 1 YES S3VE
Barium Target 54 ug/L 54 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 0.71 ug/L 0.71 1 YES S3VE
Calcium Target 1600 ug/L 1600 1 YES S3VE
Chromium Target 1.3 J ug/L 1.3 J 1 YES S3VE
Cobalt Target 1.0 ug/L 1.0 1 YES S3VE
Copper Target 3.9 ug/L 3.9 1 YES S3VE
Iron Target 33 J ug/L 33 J 1 YES S3VE
Lead Target 0.23 J ug/L 0.23 J 1 YES S3VE
Magnesium Target 1400 ug/L 1400 1 YES S3VE
Manganese Target 8.5 ug/L 8.5 1 YES S3VE
Nickel Target 19 ug/L 19 1 YES S3VE
Potassium Target 1400000 J+ug/L 1400000 D 50 YES S3VE
Selenium Target 1.6 J ug/L 1.6 J 1 YES S3VE
Silver Target 1.0 UJ ug/L 1.0 U*1 YES S3VE
Sodium Target 2400000 J+ug/L 2400000 D 50 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 14 ug/L 14 1 YES S3VE
Zinc Target 2.6 J ug/L 2.6 J 1 YES S3VE
Molybdenum Target 8500 J+ug/L 8500 D 10 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 9 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AF7 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: PWBA pH: 1.Sample Date: 06/13/2023 Sample Time: 12:08:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 20 U ug/L 20 U 1 YES S3VE
Antimony Target 2.0 U ug/L 2.0 U 1 YES S3VE
Arsenic Target 91 ug/L 91 1 YES S3VE
Barium Target 23 ug/L 23 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 0.15 J ug/L 0.15 J 1 YES S3VE
Calcium Target 1300 ug/L 1300 1 YES S3VE
Chromium Target 2.0 ug/L 2.0 1 YES S3VE
Cobalt Target 0.17 J ug/L 0.17 J 1 YES S3VE
Copper Target 0.27 J ug/L 0.27 J 1 YES S3VE
Iron Target 200 U ug/L 200 U 1 YES S3VE
Lead Target 1.0 U ug/L 1.0 U 1 YES S3VE
Magnesium Target 620 ug/L 620 1 YES S3VE
Manganese Target 6.8 ug/L 6.8 1 YES S3VE
Nickel Target 3.8 ug/L 3.8 1 YES S3VE
Potassium Target 800000 J+ug/L 800000 D 20 YES S3VE
Selenium Target 5.0 U ug/L 5.0 U 1 YES S3VE
Silver Target 1.0 UJ ug/L 1.0 U*1 YES S3VE
Sodium Target 1400000 J+ug/L 1400000 D 20 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 24 ug/L 24 1 YES S3VE
Zinc Target 5.0 U ug/L 5.0 U 1 YES S3VE
Molybdenum Target 1500 J+ug/L 1500 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 10 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AF8 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: PWS pH: 1.Sample Date: 06/12/2023 Sample Time: 13:36:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 610 ug/L 610 1 YES S3VE
Antimony Target 2.0 U ug/L 0.32 J 1 YES S3VE
Arsenic Target 38 ug/L 38 1 YES S3VE
Barium Target 150 ug/L 150 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 2.4 ug/L 2.4 1 YES S3VE
Calcium Target 20000 ug/L 20000 1 YES S3VE
Chromium Target 0.94 J ug/L 0.94 J 1 YES S3VE
Cobalt Target 0.63 J ug/L 0.63 J 1 YES S3VE
Copper Target 4.6 ug/L 4.6 1 YES S3VE
Iron Target 1500 ug/L 1500 1 YES S3VE
Lead Target 2.3 ug/L 2.3 1 YES S3VE
Magnesium Target 18000 ug/L 18000 1 YES S3VE
Manganese Target 62 ug/L 62 1 YES S3VE
Nickel Target 1.5 ug/L 1.5 1 YES S3VE
Potassium Target 25000 J+ug/L 25000 1 YES S3VE
Selenium Target 5.0 U ug/L 5.0 U 1 YES S3VE
Silver Target 1.0 UJ ug/L 1.0 U*1 YES S3VE
Sodium Target 77000 J+ug/L 77000 1 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 1.4 J ug/L 1.4 J 1 YES S3VE
Zinc Target 7.2 ug/L 7.2 1 YES S3VE
Molybdenum Target 10 U ug/L 0.65 J 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 11 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AG1 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: P2HA pH: 1.Sample Date: 06/14/2023 Sample Time: 11:45:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 510 ug/L 510 1 YES S3VE
Antimony Target 2.0 U ug/L 0.62 J 1 YES S3VE
Arsenic Target 230 ug/L 230 1 YES S3VE
Barium Target 260 ug/L 260 1 YES S3VE
Beryllium Target 2.0 U ug/L 2.0 UD 2 YES S3VE
Cadmium Target 0.18 J ug/L 0.18 J 1 YES S3VE
Calcium Target 21000 ug/L 21000 1 YES S3VE
Chromium Target 4.5 ug/L 4.5 1 YES S3VE
Cobalt Target 0.91 J ug/L 0.91 J 1 YES S3VE
Copper Target 25 ug/L 25 1 YES S3VE
Iron Target 510 ug/L 510 1 YES S3VE
Lead Target 2.6 ug/L 2.6 1 YES S3VE
Magnesium Target 35000 ug/L 35000 1 YES S3VE
Manganese Target 57 ug/L 57 1 YES S3VE
Nickel Target 6.5 ug/L 6.5 1 YES S3VE
Potassium Target 1900000 J+ug/L 1900000 D 100 YES S3VE
Selenium Target 2.0 J ug/L 2.0 J 1 YES S3VE
Silver Target 0.031 J ug/L 0.031 J*1 YES S3VE
Sodium Target 4700000 J+ug/L 4700000 D 100 YES S3VE
Thallium Target 0.14 J ug/L 0.14 J 1 YES S3VE
Vanadium Target 7.5 ug/L 7.5 1 YES S3VE
Zinc Target 48 ug/L 48 1 YES S3VE
Molybdenum Target 15000 J+ug/L 15000 D 10 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 12 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AG2 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: P2FA pH: 1.Sample Date: 06/16/2023 Sample Time: 14:20:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 20 U ug/L 20 U 1 YES S3VE
Antimony Target 2.0 U ug/L 0.98 J 1 YES S3VE
Arsenic Target 110 ug/L 110 1 YES S3VE
Barium Target 67 ug/L 67 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 0.69 ug/L 0.69 1 YES S3VE
Calcium Target 4000 ug/L 4000 1 YES S3VE
Chromium Target 7.9 ug/L 7.9 1 YES S3VE
Cobalt Target 2.0 ug/L 2.0 1 YES S3VE
Copper Target 2.4 ug/L 2.4 1 YES S3VE
Iron Target 68 J ug/L 68 J 1 YES S3VE
Lead Target 1.0 U ug/L 1.0 U 1 YES S3VE
Magnesium Target 21000 ug/L 21000 1 YES S3VE
Manganese Target 27 ug/L 27 1 YES S3VE
Nickel Target 12 ug/L 12 1 YES S3VE
Potassium Target 870000 J+ug/L 870000 D 100 YES S3VE
Selenium Target 11 ug/L 11 1 YES S3VE
Silver Target 0.042 J ug/L 0.042 J*1 YES S3VE
Sodium Target 3900000 J+ug/L 3900000 D 100 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 18 ug/L 18 1 YES S3VE
Zinc Target 0.70 J ug/L 0.70 J 1 YES S3VE
Molybdenum Target 60000 J+ug/L 60000 D 50 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 13 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AG4 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: P3CC pH: 1.Sample Date: 06/16/2023 Sample Time: 11:21:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 20 ug/L 20 1 YES S3VE
Antimony Target 2.0 U ug/L 0.62 J 1 YES S3VE
Arsenic Target 1100 ug/L 1100 D 100 YES S3VE
Barium Target 280 ug/L 280 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 0.48 ug/L 0.48 1 YES S3VE
Calcium Target 7600 ug/L 7600 1 YES S3VE
Chromium Target 3.5 ug/L 3.5 1 YES S3VE
Cobalt Target 0.53 J ug/L 0.53 J 1 YES S3VE
Copper Target 0.60 J ug/L 0.60 J 1 YES S3VE
Iron Target 62 J ug/L 62 J 1 YES S3VE
Lead Target 1.0 U ug/L 1.0 U 1 YES S3VE
Magnesium Target 14000 ug/L 14000 1 YES S3VE
Manganese Target 23 ug/L 23 1 YES S3VE
Nickel Target 7.4 ug/L 7.4 1 YES S3VE
Potassium Target 2100000 J+ug/L 2100000 D 100 YES S3VE
Selenium Target 4.2 J ug/L 4.2 J 1 YES S3VE
Silver Target 1.0 UJ ug/L 1.0 U*1 YES S3VE
Sodium Target 4300000 J+ug/L 4300000 D 100 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 31 ug/L 31 1 YES S3VE
Zinc Target 2.5 J ug/L 2.5 J 1 YES S3VE
Molybdenum Target 31000 J+ug/L 31000 D 25 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 14 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AG6 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: P3BB pH: 1.Sample Date: 06/20/2023 Sample Time: 10:36:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 10 J ug/L 10 J 1 YES S3VE
Antimony Target 2.0 U ug/L 2.0 U 1 YES S3VE
Arsenic Target 45 ug/L 45 1 YES S3VE
Barium Target 420 ug/L 420 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 0.20 U ug/L 0.20 U 1 YES S3VE
Calcium Target 29000 ug/L 29000 1 YES S3VE
Chromium Target 1.1 J ug/L 1.1 J 1 YES S3VE
Cobalt Target 0.15 J ug/L 0.15 J 1 YES S3VE
Copper Target 0.29 J ug/L 0.29 J 1 YES S3VE
Iron Target 200 ug/L 200 1 YES S3VE
Lead Target 1.0 U ug/L 1.0 U 1 YES S3VE
Magnesium Target 60000 ug/L 60000 1 YES S3VE
Manganese Target 110 ug/L 110 1 YES S3VE
Nickel Target 0.86 J ug/L 0.86 J 1 YES S3VE
Potassium Target 69000 J+ug/L 69000 1 YES S3VE
Selenium Target 5.0 U ug/L 5.0 U 1 YES S3VE
Silver Target 1.0 UJ ug/L 1.0 U*1 YES S3VE
Sodium Target 2400000 J+ug/L 2400000 D 50 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 5.6 ug/L 5.6 1 YES S3VE
Zinc Target 5.0 U ug/L 5.0 U 1 YES S3VE
Molybdenum Target 38 J+ug/L 38 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 15 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AG7 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: P3DA pH: 1.Sample Date: 06/20/2023 Sample Time: 13:18:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 880 ug/L 880 1 YES S3VE
Antimony Target 2.0 U ug/L 2.0 U 1 YES S3VE
Arsenic Target 190 ug/L 190 1 YES S3VE
Barium Target 180 ug/L 180 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 0.20 U ug/L 0.20 U 1 YES S3VE
Calcium Target 15000 ug/L 15000 1 YES S3VE
Chromium Target 6.2 ug/L 6.2 1 YES S3VE
Cobalt Target 0.58 J ug/L 0.58 J 1 YES S3VE
Copper Target 5.3 ug/L 5.3 1 YES S3VE
Iron Target 1000 ug/L 1000 1 YES S3VE
Lead Target 3.0 ug/L 3.0 1 YES S3VE
Magnesium Target 11000 ug/L 11000 1 YES S3VE
Manganese Target 39 ug/L 39 1 YES S3VE
Nickel Target 1.9 ug/L 1.9 1 YES S3VE
Potassium Target 150000 ug/L 150000 D 10 YES S3VE
Selenium Target 5.0 U ug/L 5.0 U 1 YES S3VE
Silver Target 1.0 UJ ug/L 1.0 U*1 YES S3VE
Sodium Target 570000 J+ug/L 570000 D 10 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 9.4 ug/L 9.4 1 YES S3VE
Zinc Target 7.5 ug/L 7.5 1 YES S3VE
Molybdenum Target 810 J+ug/L 810 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 16 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AG9 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: P3EA pH: 1.Sample Date: 06/20/2023 Sample Time: 15:19:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 12000 ug/L 12000 1 YES S3VE
Antimony Target 2.0 U ug/L 0.78 J 1 YES S3VE
Arsenic Target 38 ug/L 38 1 YES S3VE
Barium Target 250 ug/L 250 1 YES S3VE
Beryllium Target 0.82 J ug/L 0.82 J 1 YES S3VE
Cadmium Target 3.9 ug/L 3.9 1 YES S3VE
Calcium Target 120000 ug/L 120000 1 YES S3VE
Chromium Target 19 ug/L 19 1 YES S3VE
Cobalt Target 7.7 ug/L 7.7 1 YES S3VE
Copper Target 55 ug/L 55 1 YES S3VE
Iron Target 16000 ug/L 16000 1 YES S3VE
Lead Target 64 ug/L 64 1 YES S3VE
Magnesium Target 35000 ug/L 35000 1 YES S3VE
Manganese Target 430 ug/L 430 1 YES S3VE
Nickel Target 18 ug/L 18 1 YES S3VE
Potassium Target 37000 J+ug/L 37000 1 YES S3VE
Selenium Target 1.9 J ug/L 1.9 J 1 YES S3VE
Silver Target 0.37 J ug/L 0.37 J*1 YES S3VE
Sodium Target 120000 J+ug/L 120000 1 YES S3VE
Thallium Target 0.60 J ug/L 0.60 J 1 YES S3VE
Vanadium Target 21 ug/L 21 1 YES S3VE
Zinc Target 140 ug/L 140 1 YES S3VE
Molybdenum Target 10 U ug/L 3.3 J 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 17 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AH0 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: P3GB pH: 1.Sample Date: 06/14/2023 Sample Time: 13:40:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 15 J ug/L 15 J 1 YES S3VE
Antimony Target 2.0 U ug/L 2.0 U 1 YES S3VE
Arsenic Target 12 ug/L 12 1 YES S3VE
Barium Target 67 ug/L 67 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 0.20 U ug/L 0.20 U 1 YES S3VE
Calcium Target 8100 ug/L 8100 1 YES S3VE
Chromium Target 0.55 J ug/L 0.55 J 1 YES S3VE
Cobalt Target 0.082 J ug/L 0.082 J 1 YES S3VE
Copper Target 0.40 J ug/L 0.40 J 1 YES S3VE
Iron Target 52 J ug/L 52 J 1 YES S3VE
Lead Target 1.0 U ug/L 1.0 U 1 YES S3VE
Magnesium Target 15000 ug/L 15000 1 YES S3VE
Manganese Target 17 ug/L 17 1 YES S3VE
Nickel Target 0.34 J ug/L 0.34 J 1 YES S3VE
Potassium Target 120000 J+ug/L 120000 1 YES S3VE
Selenium Target 5.0 U ug/L 5.0 U 1 YES S3VE
Silver Target 1.0 UJ ug/L 1.0 U*1 YES S3VE
Sodium Target 670000 J+ug/L 670000 D 10 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 1.9 J ug/L 1.9 J 1 YES S3VE
Zinc Target 0.85 J ug/L 0.85 J 1 YES S3VE
Molybdenum Target 290 J+ug/L 290 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 18 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AH1 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: P3O pH: 1.Sample Date: 06/14/2023 Sample Time: 14:20:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 26 ug/L 26 1 YES S3VE
Antimony Target 2.0 U ug/L 2.0 U 1 YES S3VE
Arsenic Target 31 ug/L 31 1 YES S3VE
Barium Target 120 ug/L 120 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 0.20 U ug/L 0.20 U 1 YES S3VE
Calcium Target 14000 ug/L 14000 1 YES S3VE
Chromium Target 0.48 J ug/L 0.48 J 1 YES S3VE
Cobalt Target 0.065 J ug/L 0.065 J 1 YES S3VE
Copper Target 0.22 J ug/L 0.22 J 1 YES S3VE
Iron Target 84 J ug/L 84 J 1 YES S3VE
Lead Target 1.0 U ug/L 1.0 U 1 YES S3VE
Magnesium Target 18000 ug/L 18000 1 YES S3VE
Manganese Target 35 ug/L 35 1 YES S3VE
Nickel Target 1.0 U ug/L 1.0 U 1 YES S3VE
Potassium Target 64000 J+ug/L 64000 1 YES S3VE
Selenium Target 5.0 U ug/L 5.0 U 1 YES S3VE
Silver Target 1.0 UJ ug/L 1.0 U*1 YES S3VE
Sodium Target 110000 J+ug/L 110000 1 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 1.2 J ug/L 1.2 J 1 YES S3VE
Zinc Target 0.79 J ug/L 0.79 J 1 YES S3VE
Molybdenum Target 19 J+ug/L 19 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 19 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AH2 Method: Mercury by Cold Vapor Matrix: Water MA Number:
Sample Location: P3FA pH: 1.Sample Date: Sample Time:
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Mercury Target 0.20 U ug/L 0.20 U 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 20 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AH2 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: P3FA pH: 1.Sample Date: 06/20/2023 Sample Time: 11:14:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 1200 ug/L 1200 1 YES S3VE
Antimony Target 2.0 U ug/L 0.73 J 1 YES S3VE
Arsenic Target 220 ug/L 220 1 YES S3VE
Barium Target 53 ug/L 53 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 0.20 U ug/L 0.20 U 1 YES S3VE
Calcium Target 9700 ug/L 9700 1 YES S3VE
Chromium Target 1.7 J ug/L 1.7 J 1 YES S3VE
Cobalt Target 1.1 ug/L 1.1 1 YES S3VE
Copper Target 10 ug/L 10 1 YES S3VE
Iron Target 1800 ug/L 1800 1 YES S3VE
Lead Target 3.8 ug/L 3.8 1 YES S3VE
Magnesium Target 9000 ug/L 9000 1 YES S3VE
Manganese Target 59 ug/L 59 1 YES S3VE
Nickel Target 4.3 ug/L 4.3 1 YES S3VE
Potassium Target 280000 ug/L 280000 D 5 YES S3VE
Selenium Target 2.5 J ug/L 2.5 J 1 YES S3VE
Silver Target 1.0 UJ ug/L 1.0 U*1 YES S3VE
Sodium Target 300000 J+ug/L 300000 D 5 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 25 ug/L 25 1 YES S3VE
Zinc Target 9.4 ug/L 9.4 1 YES S3VE
Molybdenum Target 610 J+ug/L 610 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 21 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AH2A Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: pH: 1.Sample Date: 06/20/2023 Sample Time: 11:14:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Silver Spike 2.0 ug/L 2.0 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 22 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AH2D Method: Mercury by Cold Vapor Matrix: Water MA Number:
Sample Location: pH: 1.Sample Date: 06/20/2023 Sample Time: 11:14:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Mercury Target 0.20 U ug/L 0.20 U 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 23 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AH2D Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: pH: 1.Sample Date: 06/20/2023 Sample Time: 11:14:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 1200 ug/L 1200 1 YES S3VE
Antimony Target 2.0 U ug/L 0.70 J 1 YES S3VE
Arsenic Target 230 ug/L 230 1 YES S3VE
Barium Target 54 ug/L 54 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Cadmium Target 0.20 U ug/L 0.20 U 1 YES S3VE
Calcium Target 9900 ug/L 9900 1 YES S3VE
Chromium Target 1.7 J ug/L 1.7 J 1 YES S3VE
Cobalt Target 1.2 ug/L 1.2 1 YES S3VE
Copper Target 10 ug/L 10 1 YES S3VE
Iron Target 1800 ug/L 1800 1 YES S3VE
Lead Target 3.8 ug/L 3.8 1 YES S3VE
Magnesium Target 9100 ug/L 9100 1 YES S3VE
Manganese Target 58 ug/L 58 1 YES S3VE
Nickel Target 4.1 ug/L 4.1 1 YES S3VE
Potassium Target 290000 ug/L 290000 D 5 YES S3VE
Selenium Target 3.0 J ug/L 3.0 J 1 YES S3VE
Silver Target 0.032 J ug/L 0.032 J 1 YES S3VE
Sodium Target 320000 J+ug/L 320000 D 5 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 25 ug/L 25 1 YES S3VE
Zinc Target 8.7 ug/L 8.7 1 YES S3VE
Molybdenum Target 600 J+ug/L 600 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 24 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AH2L Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: pH: 1.Sample Date: Sample Time:
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 1300 ug/L 1300 5 YES S3VE
Antimony Target 10 U ug/L 10 U 5 YES S3VE
Arsenic Target 220 ug/L 220 5 YES S3VE
Barium Target 54 ug/L 54 5 YES S3VE
Beryllium Target 5.0 U ug/L 5.0 U 5 YES S3VE
Cadmium Target 1.0 U ug/L 1.0 U 5 YES S3VE
Calcium Target 10000 ug/L 10000 5 YES S3VE
Chromium Target 1.8 J ug/L 1.8 J 5 YES S3VE
Cobalt Target 1.2 J ug/L 1.2 J 5 YES S3VE
Copper Target 10 ug/L 10 5 YES S3VE
Iron Target 1800 ug/L 1800 5 YES S3VE
Lead Target 3.8 J ug/L 3.8 J 5 YES S3VE
Magnesium Target 9400 ug/L 9400 5 YES S3VE
Manganese Target 62 ug/L 62 5 YES S3VE
Nickel Target 4.7 J ug/L 4.7 J 5 YES S3VE
Potassium Target 290000 ug/L 290000 D 25 YES S3VE
Selenium Target 25 U ug/L 25 U 5 YES S3VE
Silver Target 5.0 U ug/L 5.0 U 5 YES S3VE
Sodium Target 330000 J+ug/L 330000 D 25 YES S3VE
Thallium Target 5.0 U ug/L 5.0 U 5 YES S3VE
Vanadium Target 26 ug/L 26 5 YES S3VE
Zinc Target 9.4 J ug/L 9.4 J 5 YES S3VE
Molybdenum Target 570 J+ug/L 570 5 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 25 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AH2S Method: Mercury by Cold Vapor Matrix: Water MA Number:
Sample Location: pH: 1.Sample Date: 06/20/2023 Sample Time: 11:14:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Mercury Spike 0.98 ug/L 0.98 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 26 Thu, 13 Jul 2023 14:47:45
Sample Number: MH0AH2S Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: pH: 1.Sample Date: 06/20/2023 Sample Time: 11:14:00
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Antimony Spike 110 J+ug/L 110 1 YES S3VE
Arsenic Spike 270 ug/L 270 1 YES S3VE
Barium Spike 2000 ug/L 2000 1 YES S3VE
Beryllium Spike 53 ug/L 53 1 YES S3VE
Cadmium Spike 48 ug/L 48 1 YES S3VE
Chromium Spike 180 ug/L 180 1 YES S3VE
Cobalt Spike 540 ug/L 540 1 YES S3VE
Copper Spike 280 ug/L 280 1 YES S3VE
Lead Spike 22 ug/L 22 1 YES S3VE
Manganese Spike 520 ug/L 520 1 YES S3VE
Nickel Spike 530 ug/L 530 1 YES S3VE
Selenium Spike 100 ug/L 100 1 YES S3VE
Silver Spike 35 ug/L 35 *1 YES S3VE
Thallium Spike 45 ug/L 45 1 YES S3VE
Vanadium Spike 500 ug/L 500 1 YES S3VE
Zinc Spike 460 ug/L 460 1 YES S3VE
Molybdenum Spike 700 J+ug/L 700 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 27 Thu, 13 Jul 2023 14:47:45
Sample Number: PBW01 Method: Mercury by Cold Vapor Matrix: Water MA Number:
Sample Location: pH: Sample Date: Sample Time:
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Mercury Target 0.20 U ug/L 0.20 U 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 28 Thu, 13 Jul 2023 14:47:45
Sample Number: PBW01 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: pH: Sample Date: Sample Time:
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Aluminum Target 20 U ug/L 20 U 1 YES S3VE
Antimony Target 2.0 U ug/L 2.0 U 1 YES S3VE
Arsenic Target 1.0 U ug/L 1.0 U 1 YES S3VE
Barium Target 10 U ug/L 10 U 1 YES S3VE
Beryllium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Calcium Target 500 U ug/L 500 U 1 YES S3VE
Chromium Target 2.0 U ug/L 2.0 U 1 YES S3VE
Cobalt Target 1.0 U ug/L 1.0 U 1 YES S3VE
Copper Target 2.0 U ug/L 2.0 U 1 YES S3VE
Iron Target 200 U ug/L 200 U 1 YES S3VE
Lead Target 1.0 U ug/L 1.0 U 1 YES S3VE
Magnesium Target 500 U ug/L 500 U 1 YES S3VE
Manganese Target 1.0 U ug/L 1.0 U 1 YES S3VE
Nickel Target 1.0 U ug/L 1.0 U 1 YES S3VE
Potassium Target 500 U ug/L 500 U 1 YES S3VE
Selenium Target 5.0 U ug/L 5.0 U 1 YES S3VE
Silver Target 1.0 U ug/L 1.0 U 1 YES S3VE
Sodium Target 500 U ug/L 500 U 1 YES S3VE
Thallium Target 1.0 U ug/L 1.0 U 1 YES S3VE
Vanadium Target 5.0 U ug/L 5.0 U 1 YES S3VE
Zinc Target 5.0 U ug/L 5.0 U 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 29 Thu, 13 Jul 2023 14:47:45
Sample Number: PBW02 Method: Metals by ICP-MS Matrix: Water MA Number: 3068.1
Sample Location: pH: Sample Date: Sample Time:
% Moisture: % Solids: 0.0
Analyte Name Analyte Type Validation Result Validation Flag Units Lab Result Lab Flag Dilution Factor Reportable Validation Level
Cadmium Target 0.20 U ug/L 0.20 U 1 YES S3VE
Molybdenum Target 10 U ug/L 10 U 1 YES S3VE
Sample Summary Report
Project Name: PORTLAND CEMENT (KILN DUST
2 & 3) Project
GroupID: 50855/68HERH20D0009/MH0AE9 Lab Name: Bonner Analytical Testing Co.
Page 30 Thu, 13 Jul 2023 14:47:45
The analyses presented on this report were performed in accordance with the
National Environmental Laboratory Accreditation Program (NELAP) unless
noted in the comments, flags, or case narrative. If the report is to be used for
regulatory compliance, it should be presented in its entirety, and not be
altered.
Client Service Contact: 801.262.7299
Attn: Utah Div. of Environmental Response & Remediation
195 N 1950 W
Salt Lake City, UT 84116
Work Order: 23F0917
Project: Portland Cement
6/20/2023
Approved By:
Reed Hendricks, Director of Operations
9632 South 500 West Sandy, Utah 84070
Serving the Intermountain West since 1953
801.262.7299 Main 866.792.0093 Fax www.ChemtechFord.com
Page 1 of 6
xx
Chemtech-Ford Laboratories
Serving the Intermountain West Since 1953
Certificate of Analysis
9632 South 500 West
Sandy, UT 84070
O:(801) 262-7299 F: (866) 792-0093
www.ChemtechFord.com
Utah Div. of Environmental Response & Remediation
195 N 1950 W
Salt Lake City, UT 84116
PO#:
Receipt:
Date Reported:
Project Name:
234-19
6/12/23 15:14 @ 14.1 °C
6/20/2023
Portland Cement
Sample ID: PWS
Lab ID: 23F0917-01Matrix: Water
Flag(s)Units
Analysis
Date/Time
Date Sampled: 6/12/23 13:36
Preparation
Date/Time
Sampled By: Client
Minimum
Reporting
Limit MethodResult
Inorganic
pH Units SPH6/13/23 12:596/13/23 12:080.1 SM 4500 H-B7.8pH
mg/L 6/13/236/13/2320SM 2540 C372Total Dissolved Solids (TDS)
Project Name: Portland Cement CtF WO#: 23F0917
www.ChemtechFord.com
Page 2 of 6Page 2 of 6
xx
Chemtech-Ford Laboratories
Serving the Intermountain West Since 1953
Certificate of Analysis
9632 South 500 West
Sandy, UT 84070
O:(801) 262-7299 F: (866) 792-0093
www.ChemtechFord.com
Utah Div. of Environmental Response & Remediation
195 N 1950 W
Salt Lake City, UT 84116
PO#:
Receipt:
Date Reported:
Project Name:
234-19
6/12/23 15:14 @ 14.1 °C
6/20/2023
Portland Cement
Sample ID: CDPOC
Lab ID: 23F0917-02Matrix: Water
Flag(s)Units
Analysis
Date/Time
Date Sampled: 6/12/23 14:11
Preparation
Date/Time
Sampled By: Client
Minimum
Reporting
Limit MethodResult
Inorganic
mg/L 6/12/236/12/230.010 SM 3500 Cr-B0.011Hexavalent Chromium
pH Units SPH6/13/23 13:006/13/23 12:080.1 SM 4500 H-B8.1pH
mg/L 6/13/236/13/2320SM 2540 C1770Total Dissolved Solids (TDS)
Project Name: Portland Cement CtF WO#: 23F0917
www.ChemtechFord.com
Page 3 of 6Page 3 of 6
xx
Chemtech-Ford Laboratories
Serving the Intermountain West Since 1953
Certificate of Analysis
9632 South 500 West
Sandy, UT 84070
O:(801) 262-7299 F: (866) 792-0093
www.ChemtechFord.com
Utah Div. of Environmental Response & Remediation
195 N 1950 W
Salt Lake City, UT 84116
PO#:
Receipt:
Date Reported:
Project Name:
234-19
6/12/23 15:14 @ 14.1 °C
6/20/2023
Portland Cement
Sample ID: P3AA
Lab ID: 23F0917-03Matrix: Water
Flag(s)Units
Analysis
Date/Time
Date Sampled: 6/12/23 12:36
Preparation
Date/Time
Sampled By: Client
Minimum
Reporting
Limit MethodResult
Inorganic
mg/L 6/12/236/12/230.010 SM 3500 Cr-B0.010Hexavalent Chromium
pH Units SPH6/13/23 13:016/13/23 12:080.1 SM 4500 H-B8.1pH
mg/L 6/13/236/13/2320SM 2540 C1660Total Dissolved Solids (TDS)
Project Name: Portland Cement CtF WO#: 23F0917
www.ChemtechFord.com
Page 4 of 6Page 4 of 6
xx
Chemtech-Ford Laboratories
Serving the Intermountain West Since 1953
Certificate of Analysis
9632 South 500 West
Sandy, UT 84070
O:(801) 262-7299 F: (866) 792-0093
www.ChemtechFord.com
Utah Div. of Environmental Response & Remediation
195 N 1950 W
Salt Lake City, UT 84116
PO#:
Receipt:
Date Reported:
Project Name:
234-19
6/12/23 15:14 @ 14.1 °C
6/20/2023
Portland Cement
Report Footnotes
Abbreviations
ND = Not detected at the corresponding Minimum Reporting Limit (MRL).
1 mg/L = one milligram per liter or 1 mg/kg = one milligram per kilogram = 1 part per million.
1 ug/L = one microgram per liter or 1 ug/kg = one microgram per kilogram = 1 part per billion.
1 ng/L = one nanogram per liter or 1 ng/kg = one nanogram per kilogram = 1 part per trillion.
On calculated parameters, there may be a slight difference between summing the rounded values shown on the report
vs the unrounded values used in the calculation.
Flag Descriptions
SPH = Sample submitted past method specified holding time.
Project Name: Portland Cement CtF WO#: 23F0917
www.ChemtechFord.com
Page 5 of 6Page 5 of 6
Page 6 of 6
The analyses presented on this report were performed in accordance with the
National Environmental Laboratory Accreditation Program (NELAP) unless
noted in the comments, flags, or case narrative. If the report is to be used for
regulatory compliance, it should be presented in its entirety, and not be
altered.
Client Service Contact: 801.262.7299
Attn: Utah Div. of Environmental Response & Remediation
195 N 1950 W
Salt Lake City, UT 84116
Work Order: 23F1075
Project: Portland Cement
6/20/2023
Approved By:
Reed Hendricks, Director of Operations
9632 South 500 West Sandy, Utah 84070
Serving the Intermountain West since 1953
801.262.7299 Main 866.792.0093 Fax www.ChemtechFord.com
Page 1 of 6
xx
Chemtech-Ford Laboratories
Serving the Intermountain West Since 1953
Certificate of Analysis
9632 South 500 West
Sandy, UT 84070
O:(801) 262-7299 F: (866) 792-0093
www.ChemtechFord.com
Utah Div. of Environmental Response & Remediation
195 N 1950 W
Salt Lake City, UT 84116
PO#:
Receipt:
Date Reported:
Project Name:
234-19
6/13/23 16:01 @ 13.1 °C
6/20/2023
Portland Cement
Sample ID: PWBA
Lab ID: 23F1075-01Matrix: Water
Flag(s)Units
Analysis
Date/Time
Date Sampled: 6/13/23 12:08
Preparation
Date/Time
Sampled By: Client
Minimum
Reporting
Limit MethodResult
Inorganic
pH Units SPH6/14/23 12:016/14/23 10:450.1 SM 4500 H-B9.6pH
mg/L 6/14/236/14/2320SM 2540 C5250Total Dissolved Solids (TDS)
Project Name: Portland Cement CtF WO#: 23F1075
www.ChemtechFord.com
Page 2 of 6Page 2 of 6
xx
Chemtech-Ford Laboratories
Serving the Intermountain West Since 1953
Certificate of Analysis
9632 South 500 West
Sandy, UT 84070
O:(801) 262-7299 F: (866) 792-0093
www.ChemtechFord.com
Utah Div. of Environmental Response & Remediation
195 N 1950 W
Salt Lake City, UT 84116
PO#:
Receipt:
Date Reported:
Project Name:
234-19
6/13/23 16:01 @ 13.1 °C
6/20/2023
Portland Cement
Sample ID: PWAA
Lab ID: 23F1075-02Matrix: Water
Flag(s)Units
Analysis
Date/Time
Date Sampled: 6/13/23 14:46
Preparation
Date/Time
Sampled By: Client
Minimum
Reporting
Limit MethodResult
Inorganic
mg/L 6/14/236/14/230.010 SM 3500 Cr-BNDHexavalent Chromium
pH Units SPH6/14/23 12:066/14/23 10:450.1 SM 4500 H-B10.0pH
mg/L 6/14/236/14/2350SM 2540 C8830Total Dissolved Solids (TDS)
Project Name: Portland Cement CtF WO#: 23F1075
www.ChemtechFord.com
Page 3 of 6Page 3 of 6
xx
Chemtech-Ford Laboratories
Serving the Intermountain West Since 1953
Certificate of Analysis
9632 South 500 West
Sandy, UT 84070
O:(801) 262-7299 F: (866) 792-0093
www.ChemtechFord.com
Utah Div. of Environmental Response & Remediation
195 N 1950 W
Salt Lake City, UT 84116
PO#:
Receipt:
Date Reported:
Project Name:
234-19
6/13/23 16:01 @ 13.1 °C
6/20/2023
Portland Cement
Sample ID: PWEA
Lab ID: 23F1075-03Matrix: Water
Flag(s)Units
Analysis
Date/Time
Date Sampled: 6/13/23 14:47
Preparation
Date/Time
Sampled By: Client
Minimum
Reporting
Limit MethodResult
Inorganic
mg/L 6/14/236/14/230.010 SM 3500 Cr-BNDHexavalent Chromium
pH Units SPH6/14/23 12:116/14/23 10:450.1 SM 4500 H-B10.0pH
mg/L 6/14/236/14/2350SM 2540 C9220Total Dissolved Solids (TDS)
Project Name: Portland Cement CtF WO#: 23F1075
www.ChemtechFord.com
Page 4 of 6Page 4 of 6
xx
Chemtech-Ford Laboratories
Serving the Intermountain West Since 1953
Certificate of Analysis
9632 South 500 West
Sandy, UT 84070
O:(801) 262-7299 F: (866) 792-0093
www.ChemtechFord.com
Utah Div. of Environmental Response & Remediation
195 N 1950 W
Salt Lake City, UT 84116
PO#:
Receipt:
Date Reported:
Project Name:
234-19
6/13/23 16:01 @ 13.1 °C
6/20/2023
Portland Cement
Report Footnotes
Abbreviations
ND = Not detected at the corresponding Minimum Reporting Limit (MRL).
1 mg/L = one milligram per liter or 1 mg/kg = one milligram per kilogram = 1 part per million.
1 ug/L = one microgram per liter or 1 ug/kg = one microgram per kilogram = 1 part per billion.
1 ng/L = one nanogram per liter or 1 ng/kg = one nanogram per kilogram = 1 part per trillion.
On calculated parameters, there may be a slight difference between summing the rounded values shown on the report
vs the unrounded values used in the calculation.
Flag Descriptions
SPH = Sample submitted past method specified holding time.
Project Name: Portland Cement CtF WO#: 23F1075
www.ChemtechFord.com
Page 5 of 6Page 5 of 6
Page 6 of 6
The analyses presented on this report were performed in accordance with the
National Environmental Laboratory Accreditation Program (NELAP) unless
noted in the comments, flags, or case narrative. If the report is to be used for
regulatory compliance, it should be presented in its entirety, and not be
altered.
Client Service Contact: 801.262.7299
Attn: Utah Div. of Environmental Response & Remediation
195 N 1950 W
Salt Lake City, UT 84116
Work Order: 23F1214
Project: Portland Cement
6/20/2023
Approved By:
Reed Hendricks, Director of Operations
9632 South 500 West Sandy, Utah 84070
Serving the Intermountain West since 1953
801.262.7299 Main 866.792.0093 Fax www.ChemtechFord.com
Page 1 of 6
xx
Chemtech-Ford Laboratories
Serving the Intermountain West Since 1953
Certificate of Analysis
9632 South 500 West
Sandy, UT 84070
O:(801) 262-7299 F: (866) 792-0093
www.ChemtechFord.com
Utah Div. of Environmental Response & Remediation
195 N 1950 W
Salt Lake City, UT 84116
PO#:
Receipt:
Date Reported:
Project Name:
234-19
6/14/23 15:28 @ 11.6 °C
6/20/2023
Portland Cement
Sample ID: P2HA
Lab ID: 23F1214-01Matrix: Water
Flag(s)Units
Analysis
Date/Time
Date Sampled: 6/14/23 11:45
Preparation
Date/Time
Sampled By: Client
Minimum
Reporting
Limit MethodResult
Inorganic
pH Units SPH6/15/23 15:276/15/23 14:400.1 SM 4500 H-B9.4pH
mg/L 6/14/236/14/23100SM 2540 C18000Total Dissolved Solids (TDS)
Project Name: Portland Cement CtF WO#: 23F1214
www.ChemtechFord.com
Page 2 of 6Page 2 of 6
xx
Chemtech-Ford Laboratories
Serving the Intermountain West Since 1953
Certificate of Analysis
9632 South 500 West
Sandy, UT 84070
O:(801) 262-7299 F: (866) 792-0093
www.ChemtechFord.com
Utah Div. of Environmental Response & Remediation
195 N 1950 W
Salt Lake City, UT 84116
PO#:
Receipt:
Date Reported:
Project Name:
234-19
6/14/23 15:28 @ 11.6 °C
6/20/2023
Portland Cement
Sample ID: P3GB
Lab ID: 23F1214-02Matrix: Water
Flag(s)Units
Analysis
Date/Time
Date Sampled: 6/14/23 13:40
Preparation
Date/Time
Sampled By: Client
Minimum
Reporting
Limit MethodResult
Inorganic
pH Units SPH6/15/23 15:286/15/23 14:400.1 SM 4500 H-B8.8pH
mg/L 6/14/236/14/2320SM 2540 C1980Total Dissolved Solids (TDS)
Project Name: Portland Cement CtF WO#: 23F1214
www.ChemtechFord.com
Page 3 of 6Page 3 of 6
xx
Chemtech-Ford Laboratories
Serving the Intermountain West Since 1953
Certificate of Analysis
9632 South 500 West
Sandy, UT 84070
O:(801) 262-7299 F: (866) 792-0093
www.ChemtechFord.com
Utah Div. of Environmental Response & Remediation
195 N 1950 W
Salt Lake City, UT 84116
PO#:
Receipt:
Date Reported:
Project Name:
234-19
6/14/23 15:28 @ 11.6 °C
6/20/2023
Portland Cement
Sample ID: P3O
Lab ID: 23F1214-03Matrix: Water
Flag(s)Units
Analysis
Date/Time
Date Sampled: 6/14/23 14:20
Preparation
Date/Time
Sampled By: Client
Minimum
Reporting
Limit MethodResult
Inorganic
pH Units SPH6/15/23 15:286/15/23 14:400.1 SM 4500 H-B8.2pH
mg/L 6/14/236/14/2320SM 2540 C520Total Dissolved Solids (TDS)
Project Name: Portland Cement CtF WO#: 23F1214
www.ChemtechFord.com
Page 4 of 6Page 4 of 6
xx
Chemtech-Ford Laboratories
Serving the Intermountain West Since 1953
Certificate of Analysis
9632 South 500 West
Sandy, UT 84070
O:(801) 262-7299 F: (866) 792-0093
www.ChemtechFord.com
Utah Div. of Environmental Response & Remediation
195 N 1950 W
Salt Lake City, UT 84116
PO#:
Receipt:
Date Reported:
Project Name:
234-19
6/14/23 15:28 @ 11.6 °C
6/20/2023
Portland Cement
Report Footnotes
Abbreviations
ND = Not detected at the corresponding Minimum Reporting Limit (MRL).
1 mg/L = one milligram per liter or 1 mg/kg = one milligram per kilogram = 1 part per million.
1 ug/L = one microgram per liter or 1 ug/kg = one microgram per kilogram = 1 part per billion.
1 ng/L = one nanogram per liter or 1 ng/kg = one nanogram per kilogram = 1 part per trillion.
On calculated parameters, there may be a slight difference between summing the rounded values shown on the report
vs the unrounded values used in the calculation.
Flag Descriptions
SPH = Sample submitted past method specified holding time.
Project Name: Portland Cement CtF WO#: 23F1214
www.ChemtechFord.com
Page 5 of 6Page 5 of 6
Page 6 of 6
The analyses presented on this report were performed in accordance with the
National Environmental Laboratory Accreditation Program (NELAP) unless
noted in the comments, flags, or case narrative. If the report is to be used for
regulatory compliance, it should be presented in its entirety, and not be
altered.
Client Service Contact: 801.262.7299
Attn: Environmental Response & Remediation
195 N 1950 W 1st Floor
Salt Lake City, UT 84070
Work Order: 23F1408
Project: Portland Cement
6/28/2023
Approved By:
Reed Hendricks, Director of Operations
9632 South 500 West Sandy, Utah 84070
Serving the Intermountain West since 1953
801.262.7299 Main 866.792.0093 Fax www.ChemtechFord.com
Page 1 of 5
xx
Chemtech-Ford Laboratories
Serving the Intermountain West Since 1953
Certificate of Analysis
9632 South 500 West
Sandy, UT 84070
O:(801) 262-7299 F: (866) 792-0093
www.ChemtechFord.com
Environmental Response & Remediation
195 N 1950 W 1st Floor
Salt Lake City, UT 84070
PO#:
Receipt:
Date Reported:
Project Name:
234-19
6/16/23 15:13 @ 8.3 °C
6/28/2023
Portland Cement
Sample ID: P3CC
Lab ID: 23F1408-01Matrix: Water
Flag(s)Units
Analysis
Date/Time
Date Sampled: 6/16/23 11:21
Preparation
Date/Time
Sampled By: Client
Minimum
Reporting
Limit MethodResult
Inorganic
mg/L 6/26/236/26/230.010 SM 3500 Cr-B0.078Hexavalent Chromium
pH Units SPH6/16/23 17:286/16/23 17:250.1 SM 4500 H-B10.0pH
mg/L 6/20/236/20/23500SM 2540 C17200Total Dissolved Solids (TDS)
Project Name: Portland Cement CtF WO#: 23F1408
www.ChemtechFord.com
Page 2 of 5Page 2 of 5
xx
Chemtech-Ford Laboratories
Serving the Intermountain West Since 1953
Certificate of Analysis
9632 South 500 West
Sandy, UT 84070
O:(801) 262-7299 F: (866) 792-0093
www.ChemtechFord.com
Environmental Response & Remediation
195 N 1950 W 1st Floor
Salt Lake City, UT 84070
PO#:
Receipt:
Date Reported:
Project Name:
234-19
6/16/23 15:13 @ 8.3 °C
6/28/2023
Portland Cement
Sample ID: P2FA
Lab ID: 23F1408-02Matrix: Water
Flag(s)Units
Analysis
Date/Time
Date Sampled: 6/16/23 14:20
Preparation
Date/Time
Sampled By: Client
Minimum
Reporting
Limit MethodResult
Inorganic
mg/L 6/26/236/26/230.010 SM 3500 Cr-BNDHexavalent Chromium
pH Units SPH6/16/23 17:296/16/23 17:250.1 SM 4500 H-B9.2pH
mg/L 6/20/236/20/23500SM 2540 C13100Total Dissolved Solids (TDS)
Project Name: Portland Cement CtF WO#: 23F1408
www.ChemtechFord.com
Page 3 of 5Page 3 of 5
xx
Chemtech-Ford Laboratories
Serving the Intermountain West Since 1953
Certificate of Analysis
9632 South 500 West
Sandy, UT 84070
O:(801) 262-7299 F: (866) 792-0093
www.ChemtechFord.com
Environmental Response & Remediation
195 N 1950 W 1st Floor
Salt Lake City, UT 84070
PO#:
Receipt:
Date Reported:
Project Name:
234-19
6/16/23 15:13 @ 8.3 °C
6/28/2023
Portland Cement
Report Footnotes
Abbreviations
ND = Not detected at the corresponding Minimum Reporting Limit (MRL).
1 mg/L = one milligram per liter or 1 mg/kg = one milligram per kilogram = 1 part per million.
1 ug/L = one microgram per liter or 1 ug/kg = one microgram per kilogram = 1 part per billion.
1 ng/L = one nanogram per liter or 1 ng/kg = one nanogram per kilogram = 1 part per trillion.
On calculated parameters, there may be a slight difference between summing the rounded values shown on the report
vs the unrounded values used in the calculation.
Flag Descriptions
SPH = Sample submitted past method specified holding time.
Project Name: Portland Cement CtF WO#: 23F1408
www.ChemtechFord.com
Page 4 of 5Page 4 of 5
Page 5 of 5
The analyses presented on this report were performed in accordance with the
National Environmental Laboratory Accreditation Program (NELAP) unless
noted in the comments, flags, or case narrative. If the report is to be used for
regulatory compliance, it should be presented in its entirety, and not be
altered.
Client Service Contact: 801.262.7299
Utah Department of Environmental Quality
Attn: Tony Howes
195 North 1950 West
Salt Lake City, UT 84116
Work Order: 23F1555
Project: Portland Cement Final Samples
6/28/2023
Approved By:
Dave Gayer, Laboratory Director
9632 South 500 West Sandy, Utah 84070
Serving the Intermountain West since 1953
801.262.7299 Main 866.792.0093 Fax www.ChemtechFord.com
Page 1 of 7
xx
Chemtech-Ford Laboratories
Serving the Intermountain West Since 1953
Certificate of Analysis
9632 South 500 West
Sandy, UT 84070
O:(801) 262-7299 F: (866) 792-0093
www.ChemtechFord.com
Utah Department of Environmental Quality
Tony Howes
195 North 1950 West
Salt Lake City, UT 84116
PO#:
Receipt:
Date Reported:
Project Name:
234-19
6/20/23 16:08 @ 14.1 °C
6/28/2023
Portland Cement Final Samples
Sample ID: P3BB
Lab ID: 23F1555-01Matrix: Water
Flag(s)Units
Analysis
Date/Time
Date Sampled: 6/20/23 10:36
Preparation
Date/Time
Sampled By: Client
Minimum
Reporting
Limit MethodResult
Inorganic
pH Units SPH6/21/23 12:366/21/23 11:280.1 SM 4500 H-B8.3pH
mg/L 6/21/236/21/2320SM 2540 C6500Total Dissolved Solids (TDS)
Project Name: Portland Cement Final Samples CtF WO#: 23F1555
www.ChemtechFord.com
Page 2 of 7Page 2 of 7
xx
Chemtech-Ford Laboratories
Serving the Intermountain West Since 1953
Certificate of Analysis
9632 South 500 West
Sandy, UT 84070
O:(801) 262-7299 F: (866) 792-0093
www.ChemtechFord.com
Utah Department of Environmental Quality
Tony Howes
195 North 1950 West
Salt Lake City, UT 84116
PO#:
Receipt:
Date Reported:
Project Name:
234-19
6/20/23 16:08 @ 14.1 °C
6/28/2023
Portland Cement Final Samples
Sample ID: P3FA
Lab ID: 23F1555-02Matrix: Water
Flag(s)Units
Analysis
Date/Time
Date Sampled: 6/20/23 11:14
Preparation
Date/Time
Sampled By: Client
Minimum
Reporting
Limit MethodResult
Inorganic
mg/L 6/26/236/26/230.010 SM 3500 Cr-BNDHexavalent Chromium
pH Units SPH6/21/23 12:376/21/23 11:280.1 SM 4500 H-B9.2pH
mg/L 6/21/236/21/2320SM 2540 C1340Total Dissolved Solids (TDS)
Project Name: Portland Cement Final Samples CtF WO#: 23F1555
www.ChemtechFord.com
Page 3 of 7Page 3 of 7
xx
Chemtech-Ford Laboratories
Serving the Intermountain West Since 1953
Certificate of Analysis
9632 South 500 West
Sandy, UT 84070
O:(801) 262-7299 F: (866) 792-0093
www.ChemtechFord.com
Utah Department of Environmental Quality
Tony Howes
195 North 1950 West
Salt Lake City, UT 84116
PO#:
Receipt:
Date Reported:
Project Name:
234-19
6/20/23 16:08 @ 14.1 °C
6/28/2023
Portland Cement Final Samples
Sample ID: P3DA
Lab ID: 23F1555-03Matrix: Water
Flag(s)Units
Analysis
Date/Time
Date Sampled: 6/20/23 13:18
Preparation
Date/Time
Sampled By: Client
Minimum
Reporting
Limit MethodResult
Inorganic
mg/L 6/26/236/26/230.010 SM 3500 Cr-B0.011Hexavalent Chromium
pH Units SPH6/21/23 12:376/21/23 11:280.1 SM 4500 H-B9.2pH
mg/L 6/21/236/21/2320SM 2540 C1830Total Dissolved Solids (TDS)
Project Name: Portland Cement Final Samples CtF WO#: 23F1555
www.ChemtechFord.com
Page 4 of 7Page 4 of 7
xx
Chemtech-Ford Laboratories
Serving the Intermountain West Since 1953
Certificate of Analysis
9632 South 500 West
Sandy, UT 84070
O:(801) 262-7299 F: (866) 792-0093
www.ChemtechFord.com
Utah Department of Environmental Quality
Tony Howes
195 North 1950 West
Salt Lake City, UT 84116
PO#:
Receipt:
Date Reported:
Project Name:
234-19
6/20/23 16:08 @ 14.1 °C
6/28/2023
Portland Cement Final Samples
Sample ID: P3EA
Lab ID: 23F1555-04Matrix: Water
Flag(s)Units
Analysis
Date/Time
Date Sampled: 6/20/23 15:19
Preparation
Date/Time
Sampled By: Client
Minimum
Reporting
Limit MethodResult
Inorganic
pH Units SPH6/21/23 12:386/21/23 11:280.1 SM 4500 H-B8.8pH
mg/L 6/21/236/21/2320SM 2540 C488Total Dissolved Solids (TDS)
Project Name: Portland Cement Final Samples CtF WO#: 23F1555
www.ChemtechFord.com
Page 5 of 7Page 5 of 7
xx
Chemtech-Ford Laboratories
Serving the Intermountain West Since 1953
Certificate of Analysis
9632 South 500 West
Sandy, UT 84070
O:(801) 262-7299 F: (866) 792-0093
www.ChemtechFord.com
Utah Department of Environmental Quality
Tony Howes
195 North 1950 West
Salt Lake City, UT 84116
PO#:
Receipt:
Date Reported:
Project Name:
234-19
6/20/23 16:08 @ 14.1 °C
6/28/2023
Portland Cement Final Samples
Report Footnotes
Abbreviations
ND = Not detected at the corresponding Minimum Reporting Limit (MRL).
1 mg/L = one milligram per liter or 1 mg/kg = one milligram per kilogram = 1 part per million.
1 ug/L = one microgram per liter or 1 ug/kg = one microgram per kilogram = 1 part per billion.
1 ng/L = one nanogram per liter or 1 ng/kg = one nanogram per kilogram = 1 part per trillion.
On calculated parameters, there may be a slight difference between summing the rounded values shown on the report
vs the unrounded values used in the calculation.
Flag Descriptions
SPH = Sample submitted past method specified holding time.
Project Name: Portland Cement Final Samples CtF WO#: 23F1555
www.ChemtechFord.com
Page 6 of 7Page 6 of 7
Page 7 of 7
Appendix C:
Water Level Measurements
Appendix D:
Data Trends for Monitoring Wells
Evaluation Date:Job ID:
Facility Name: Constituent:
Conducted By: Concentration Units:Standard Units
Sampling Point ID:PWEA PWBA P2BA P2FA P2HA Cleanup
Sampling Sampling
Event Date
1 Jun-15 9.69 9.69 8.51 8.59 9.98 8.00
2 Nov-15 9.62 9.77 8.71 8.67 9.20 8.00
3 Jun-16 9.83 9.92 8.60 8.78 10.20 8.00
4 Nov-16 9.94 9.88 8.70 8.95 9.54 8.00
5 May-17 9.66 9.70 8.39 9.22 9.80 8.00
6 Jun-18 9.70 9.61 8.33 8.75 9.30 8.00
7 Jun-19 9.62 9.66 8.29 8.97 9.36 8.00
8 Jun-21 9.89 9.72 8.32 9.22 9.38 8.00
9 Jun-22 10.20 10.00 8.30 0 9.30 8.00
10 Jun-23 10.00 9.60 0 9.20 9.40 8.00
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:0.02 0.01 0.35 0.35 0.04 0.00
Mann-Kendall Statistic (S):18 -7 -33 16 -10 0
Confidence Factor:93.4% 70.0% 99.9% 90.7% 78.4% 45.6%
Concentration Trend:Prob. Increasing Stable Decreasing Prob. Increasing Stable Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water , 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
GSI Environmental Inc., www.gsi-net.com
PH WEST SITE AND SITE 2 (SHALLOW) CONCENTRATION (Standard Units)
13-Aug-23
Portland Cement pH West Site and Site 2 (Shallow)
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
Tony Howes
6
6.5
7
7.5
8
8.5
9
9.5
10
10.5
11
12/14 05/16 09/17 02/19 06/20 10/21 03/23 07/24
Co
n
c
e
n
t
r
a
t
i
o
n
(
S
t
a
n
d
a
r
d
Un
i
t
s
)
Sampling Date
PWEA
PWBA
P2BA
P2FA
P2HA
Cleanup
Evaluation Date:Job ID:
Facility Name: Constituent:
Conducted By: Concentration Units:Standard Units
Sampling Point ID:P3BB P3CC P3DA P3FA P3GB Cleanup
Sampling Sampling
Event Date
1 Jun-15 8.19 9.44 8.54 9.98 9.17 8.00
2 Nov-15 8.28 9.63 8.57 8.82 8.91 8.00
3 Jun-16 8.30 9.85 8.59 10.10 9.21 8.00
4 Nov-16 NS 10.10 9.84 9.10 8.85 8.00
5 May-17 NS 9.98 9.78 10.10 8.48 8.00
6 Jun-18 8.14 NS 8.72 10.00 8.40 8.00
7 Jun-19 8.48 NS NS 9.77 8.63 8.00
8 Jun-21 8.99 9.99 8.51 9.99 8.63 8.00
9 Jun-22 8.40 10.00 9.30 9.90 8.30 8.00
10 Jun-23 8.30 10.00 9.20 9.20 8.80 8.00
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:0.03 0.02 0.06 0.05 0.04 0.00
Mann-Kendall Statistic (S):11 19 8 -4 -22 0
Confidence Factor:88.7% 98.9% 76.2% 60.3% 97.1% 45.6%
Concentration Trend:No Trend Increasing No Trend Stable Decreasing Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water , 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
GSI Environmental Inc., www.gsi-net.com
PH SITE 3 (SHALLOW) CONCENTRATION (Standard Units)
13-Aug-23
Portland Cement pH Site 3 (Shallow)
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
Tony Howes
7
7.5
8
8.5
9
9.5
10
10.5
11
12/14 05/16 09/17 02/19 06/20 10/21 03/23 07/24
Co
n
c
e
n
t
r
a
t
i
o
n
(
S
t
a
n
d
a
r
d
Un
i
t
s
)
Sampling Date
P3BB
P3CC
P3DA
P3FA
P3GB
Cleanup
Evaluation Date:Job ID:
Facility Name: Constituent:
Conducted By: Concentration Units:ug/L
Sampling Point ID:PWEA PWBA P2BA P2FA P2HA Cleanup
Sampling Sampling
Event Date
1 Jun-15 133 40 24.5 49.8 645 64
2 Nov-15 89.7 42.4 34.8 45.2 193 64
3 Jun-16 111 71.8 14.8 72 1020 64
4 Nov-16 151 41.4 37.7 86.7 253 64
5 May-17 83 74.5 7.5 287 461 64
6 Jun-18 86.9 168 29 57.7 274 64
7 Jun-19 161 70.1 7.5 70.6 252 64
8 Jun-21 430 73 7.3 35 250 64
9 Jun-22 360 110 8 0 190 64
10 Jun-23 600 91 0 110 230 64
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:0.81 0.49 0.78 0.96 0.71 0.00
Mann-Kendall Statistic (S):23 25 -24 -1 -23 0
Confidence Factor:97.7% 98.6% 98.2% 50.0% 97.7% 45.6%
Concentration Trend:Increasing Increasing Decreasing Stable Decreasing Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water , 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
GSI Environmental Inc., www.gsi-net.com
ARSENIC WEST SITE AND SITE 2 (SHALLOW) CONCENTRATION (ug/L)
13-Aug-23
Portland Cement Arsenic West Site and Site 2 (Shallow)
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
Tony Howes
1
10
100
1000
10000
12/14 05/16 09/17 02/19 06/20 10/21 03/23 07/24
Co
n
c
e
n
t
r
a
t
i
o
n
(
u
g
/
L
)
Sampling Date
PWEA
PWBA
P2BA
P2FA
P2HA
Cleanup
Evaluation Date:Job ID:
Facility Name: Constituent:
Conducted By: Concentration Units:ug/L
Sampling Point ID:P3BB P3CC P3DA P3FA P3GB Cleanup
Sampling Sampling
Event Date
1 Jun-15 53.9 198 58.4 1010 95.2 64
2 Nov-15 62.3 180 81.8 406 33.6 64
3 Jun-16 52.9 352 57.9 796 64.9 64
4 Nov-16 0 532 362 209 11.8 64
5 May-17 0 790 562 868 7.5 64
6 Jun-18 56.7 0 70.7 916 7.5 64
7 Jun-19 48.2 0 0 572 5.15 64
8 Jun-21 44
1000 110 780 13 64
9 Jun-22 61 1000 190 710 20 64
10 Jun-23 45 1100 190 220 12 64
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:0.55 0.83 1.02 0.44 1.11 0.00
Mann-Kendall Statistic (S):-6 21 10 -11 -16 0
Confidence Factor:66.8% 96.4% 78.4% 81.0% 90.7% 45.6%
Concentration Trend:Stable Increasing No Trend Stable Prob. Decreasing Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water , 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
GSI Environmental Inc., www.gsi-net.com
ARSENIC SITE 3 (SHALLOW) CONCENTRATION (ug/L)
13-Aug-23
Portland Cement Arsenic Site 3 (Shallow)
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
Tony Howes
1
10
100
1000
10000
12/14 05/16 09/17 02/19 06/20 10/21 03/23 07/24
Co
n
c
e
n
t
r
a
t
i
o
n
(
u
g
/
L
)
Sampling Date
P3BB
P3CC
P3DA
P3FA
P3GB
Cleanup
Evaluation Date:Job ID:
Facility Name: Constituent:
Conducted By: Concentration Units: ug/L
Sampling Point ID:PWEA PWBA P2BA P2FA P2HA Cleanup
Sampling Sampling
Event Date
1 Jun-15 0.30 0.30 0.30 0.30 0.30 6.2
2 Nov-15 0.30 0.30 0.30 0.30 0.30 6.2
3 Jun-16 0.30 0.30 0.30 3.18 4.47 6.2
4 Nov-16 0.30 0.30 0.30 0.30 0.30 6.2
5 May-17 0.30 0.30 0.30 0.30 0.30 6.2
6 Jun-18 0.30 0.30 0.30 0.30 0.30 6.2
7 Jun-19 0.30 0.30 0.30 0.30 0.30 6.2
8 Jun-21 2.7 0.37 0.30 7.4 4.5 6.2
9 Jun-22 2.1 0.56 0.30 0 1.4 6.2
10 Jun-23 0.52 0.3 0 0.69 0.30 6.2
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:1.20 0.25 0.35 1.78 1.40 0.00
Mann-Kendall Statistic (S):18 13 -9 2 6 0
Confidence Factor:93.4% 85.4% 75.8% 53.5% 66.8% 45.6%
Concentration Trend:Prob. Increasing No Trend Stable No Trend No Trend Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water , 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
GSI Environmental Inc., www.gsi-net.com
CADMIUM WEST SITE AND SITE 2 (SHALLOW) CONCENTRATION ( ug/L)
13-Aug-23
Portland Cement Cadmium West Site and Site 2 (Shallow)
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
Tony Howes
0.1
1
10
12/14 05/16 09/17 02/19 06/20 10/21 03/23 07/24
Co
n
c
e
n
t
r
a
t
i
o
n
(
u
g
/
L
)
Sampling Date
PWEA
PWBA
P2BA
P2FA
P2HA
Cleanup
Evaluation Date:Job ID:
Facility Name: Constituent:
Conducted By: Concentration Units:ug/L
Sampling Point ID:P3BB P3CC P3DA P3FA P3GB Cleanup
Sampling Sampling
Event Date
1 Jun-15 0.10 0.30 0.30 4.81 1.35 6.2
2 Nov-15 0.10 1.12 0.95 12.40 1.42 6.2
3 Jun-16 0.10 0.651 0.30 5.03 0.61 6.2
4 Nov-16 0 9.74 0.30 4.48 0.30 6.2
5 May-17 0 0.30 0.30 0.30 0.30 6.2
6 Jun-18 0.10 0 0.30 4.31 0.30 6.2
7 Jun-19 0.10 0 0 3.42 0.30 6.2
8 Jun-21 0.10 7.8 0.37 1.00 0.42 6.2
9 Jun-22 0.10 7.5 0.49 0.73 0.18 6.2
10 Jun-23 0.10 0.48 0.10 0.10 0.10 6.2
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:0.53 1.40 0.74 1.00 0.89 0.00
Mann-Kendall Statistic (S):4-1-5-33-290
Confidence Factor:60.3% 50.0% 63.6% 99.9% 99.5% 45.6%
Concentration Trend:No Trend No Trend Stable Decreasing Decreasing Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water , 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
GSI Environmental Inc., www.gsi-net.com
CADMIUM SITE 3 (SHALLOW) CONCENTRATION (ug/L)
13-Aug-23
Portland Cement Cadmium Site 3 (Shallow)
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
Tony Howes
0.1
1
10
100
12/14 05/16 09/17 02/19 06/20 10/21 03/23 07/24
Co
n
c
e
n
t
r
a
t
i
o
n
(
u
g
/
L
)
Sampling Date
P3BB
P3CC
P3DA
P3FA
P3GB
Cleanup
Evaluation Date:Job ID:
Facility Name: Constituent:
Conducted By: Concentration Units: ug/L
Sampling Point ID:PWEA PWBA P2BA P2FA P2HA Cleanup
Sampling Sampling
Event Date
1 Jun-15 1 1 1 14.1 1 100
2 Nov-15 1 5.1 1 10.6 5.2 100
3 Jun-16 1 5.48 1 17.4 1 100
4 Nov-16 11111100
5 May-17 1 1 1 160 1 100
6 Jun-18 11111100
7 Jun-1911111100
8 Jun-21 2.2 3.8 0.53 5.6 1.7 100
9 Jun-22 2.3 3.5 0.6 NA 2.2 100
10 Jun-23 1.3 2 0 7.9 4.5 100
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:0.41 0.73 0.42 2.11 0.81 0.00
Mann-Kendall Statistic (S):20 1 -22 -7 14 0
Confidence Factor:95.5% 50.0% 97.1% 72.8% 87.3% 45.6%
Concentration Trend:Increasing No Trend Decreasing No Trend No Trend Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water , 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
GSI Environmental Inc., www.gsi-net.com
CHROMIUM WEST SITE AND SITE 2 (SHALLOW) CONCENTRATION ( ug/L)
13-Aug-23
Portland Cement Chromium West Site and Site 2 (Shallow)
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
Tony Howes
0.1
1
10
100
1000
12/14 05/16 09/17 02/19 06/20 10/21 03/23 07/24
Co
n
c
e
n
t
r
a
t
i
o
n
(
u
g
/
L
)
Sampling Date
PWEA
PWBA
P2BA
P2FA
P2HA
Cleanup
Evaluation Date:Job ID:
Facility Name: Constituent:
Conducted By: Concentration Units:ug/L
Sampling Point ID:P3BB P3CC P3DA P3FA P3GB Cleanup
Sampling Sampling
Event Date
1 Jun-15 1
1 1 82.5 1 100
2 Nov-15 1
5.38 505 197 1 100
3 Jun-16 1
1 5.25 97.2 1 100
4 Nov-16 NS
1 1 83.7 1 100
5 May-17 NS
1111 100
6 Jun-18 1
NS 11.2 106 1 100
7 Jun-19 1
NS NS 41.4 1 100
8 Jun-21 1.9
4.3 6.7 16 0.85 100
9 Jun-22 1.5 4 1.2 4.7 1.1 100
10 Jun-23 1.1 3.5 6.2 1.7 0.55 100
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:0.28 0.69 2.79 0.99 0.16 0.00
Mann-Kendall Statistic (S):12 4 3 -23 -8 0
Confidence Factor:91.1% 64.0% 58.0% 97.7% 72.9% 45.6%
Concentration Trend:Prob. Increasing No Trend No Trend Decreasing Stable Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water , 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
GSI Environmental Inc., www.gsi-net.com
CHROMIUM SITE 3 (SHALLOW) CONCENTRATION (ug/L)
13-Aug-23
Portland Cement Chromium Site 3 (Shallow)
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
Tony Howes
0.1
1
10
100
1000
12/14 05/16 09/17 02/19 06/20 10/21 03/23 07/24
Co
n
c
e
n
t
r
a
t
i
o
n
(
u
g
/
L
)
Sampling Date
P3BB
P3CC
P3DA
P3FA
P3GB
Cleanup
Evaluation Date:Job ID:
Facility Name: Constituent:
Conducted By: Concentration Units: ug/L
Sampling Point ID:PWEA PWBA P2BA P2FA P2HA Cleanup
Sampling Sampling
Event Date
1 Jun-15 0.13 0.13 0.13 0.13 0.13 15
2 Nov-15 0.56 0.13 0.13 0.13 0.13 15
3 Jun-16 0.13 0.695 0.13 0.13 0.13 15
4 Nov-16 0.13 0.13 0.13 0.13 0.13 15
5 May-17 0.13 0.13 14 0.13 0.13 15
6 Jun-18 0.13 0.13 0.13 0.13 0.13 15
7 Jun-19 0.13 0.13 0.13 0.13 0.13 15
8 Jun-21 0.13 0.13 0.13 0.13 0.13 15
9 Jun-22 0.35 0.13 0.48 0 0.51 15
10 Jun-23 0.24 0.13 0 0.13 2.6 15
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:0.70 0.96 2.85 0.35 1.87 0.00
Mann-Kendall Statistic (S):6-5-2-7170
Confidence Factor:66.8% 63.6% 53.5% 70.0% 92.2% 45.6%
Concentration Trend:No Trend Stable No Trend Stable Prob. Increasing Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water , 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
GSI Environmental Inc., www.gsi-net.com
LEAD WEST SITE AND SITE 2 (SHALLOW) CONCENTRATION ( ug/L)
13-Aug-23
Portland Cement Lead West Site and Site 2 (Shallow)
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
Tony Howes
0.1
1
10
100
12/14 05/16 09/17 02/19 06/20 10/21 03/23 07/24
Co
n
c
e
n
t
r
a
t
i
o
n
(
u
g
/
L
)
Sampling Date
PWEA
PWBA
P2BA
P2FA
P2HA
Cleanup
Evaluation Date:Job ID:
Facility Name: Constituent:
Conducted By: Concentration Units:ug/L
Sampling Point ID:P3BB P3CC P3DA P3FA P3GB Cleanup
Sampling Sampling
Event Date
1 Jun-15 0.13 0.13 0.13
92.7 0.13 15
2 Nov-15 2.22 0.13 46.5
760 1.29 15
3 Jun-16 0.13 0.13 0.13
188 1.53 15
4 Nov-16 0 0.13 0.13
224 0.13 15
5 May-17 0 0.13 0.13
0.13 0.13 15
6 Jun-18 0.13 0 0.13
165 0.13 15
7 Jun-19 0.13 0 0
106 0.13 15
8 Jun-21 0.13 0.13 3
25 0.13 15
9 Jun-22 0.13 0.47 0.76 14 1 15
10 Jun-23 0.13 0.13 3 3.8 0.13 15
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:2.15 0.93 2.69 1.43 1.20 0.00
Mann-Kendall Statistic (S):-1 1 6 -23 -6 0
Confidence Factor:50.0% 50.0% 66.8% 97.7% 66.8% 45.6%
Concentration Trend:No Trend No Trend No Trend Decreasing No Trend Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water , 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
GSI Environmental Inc., www.gsi-net.com
LEAD SITE 3 (SHALLOW) CONCENTRATION (ug/L)
13-Aug-23
Portland Cement Lead Site 3 (Shallow)
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
Tony Howes
0.1
1
10
100
1000
12/14 05/16 09/17 02/19 06/20 10/21 03/23 07/24
Co
n
c
e
n
t
r
a
t
i
o
n
(
u
g
/
L
)
Sampling Date
P3BB
P3CC
P3DA
P3FA
P3GB
Cleanup
Evaluation Date:Job ID:
Facility Name: Constituent:
Conducted By: Concentration Units: ug/L
Sampling Point ID:PWEA PWBA P2BA P2FA P2HA Cleanup
Sampling Sampling
Event Date
1 Jun-15 5.96 1.1 14.6 7.14 1.1 440
2 Nov-15 1.1 1.1 1.1 1.1 1.1 440
3 Jun-16 6.19 25.1 10.4 1.1 11.1 440
4 Nov-16 1.1 1.1 1.1 1.1 1.1 440
5 May-17 1.1 1.1 1.1 1.1 1.1 440
6 Jun-18 1.1 51.3 15.7 1.1 1.1 440
7 Jun-19 1.1 1.1 33.7 12 1.1 440
8 Jun-21 9 7.6 34 36 20 440
9 Jun-22 9.2 7.8 24 0 24 440
10 Jun-23 8.4 6.8 0 27 57 440
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:0.83 1.55 0.98 1.45 1.52 0.00
Mann-Kendall Statistic (S):13 11 8 7 22 0
Confidence Factor:85.4% 81.0% 72.9% 70.0% 97.1% 45.6%
Concentration Trend:No Trend No Trend No Trend No Trend Increasing Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water , 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
GSI Environmental Inc., www.gsi-net.com
MANGANESE WEST SITE AND SITE 2 (SHALLOW) CONCENTRATION ( ug/L)
13-Aug-23
Portland Cement Manganese West Site and Site 2 (Shallow)
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
Tony Howes
1
10
100
1000
12/14 05/16 09/17 02/19 06/20 10/21 03/23 07/24
Co
n
c
e
n
t
r
a
t
i
o
n
(
u
g
/
L
)
Sampling Date
PWEA
PWBA
P2BA
P2FA
P2HA
Cleanup
Evaluation Date:Job ID:
Facility Name: Constituent:
Conducted By: Concentration Units:ug/L
Sampling Point ID:P3BB P3CC P3DA P3FA P3GB Cleanup
Sampling Sampling
Event Date
1 Jun-15 50.2 2.23 18.4 2650 7.04 440
2 Nov-15 70.1 1.1 1180 10600 38.1 440
3 Jun-16 39.8 1.1 19.1 3960 34 440
4 Nov-16 0 1.1 17.2 3620 25 440
5 May-17 0 1.1 1.1 20.6 1.1 440
6 Jun-18 39.1 0 28.7 3640 182 440
7 Jun-19 40.8 0 0 2070 12.3 440
8 Jun-21 130 29 48 320 16 440
9 Jun-22 160 29 23 89 13 440
10 Jun-23 110 23 39 58 17 440
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:0.84 1.45 2.67 1.19 1.54 0.00
Mann-Kendall Statistic (S):14 5 3 -25 -3 0
Confidence Factor:87.3% 63.6% 56.9% 98.6% 56.9% 45.6%
Concentration Trend:No Trend No Trend No Trend Decreasing No Trend Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water , 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
GSI Environmental Inc., www.gsi-net.com
MANGANESE SITE 3 (SHALLOW) CONCENTRATION (ug/L)
13-Aug-23
Portland Cement Manganese Site 3 (Shallow)
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
Tony Howes
1
10
100
1000
10000
100000
12/14 05/16 09/17 02/19 06/20 10/21 03/23 07/24
Co
n
c
e
n
t
r
a
t
i
o
n
(
u
g
/
L
)
Sampling Date
P3BB
P3CC
P3DA
P3FA
P3GB
Cleanup
Evaluation Date:Job ID:
Facility Name: Constituent:
Conducted By: Concentration Units: ug/L
Sampling Point ID:PWEA PWBA P2BA P2FA P2HA Cleanup
Sampling Sampling
Event Date
1 Jun-15 5950 1410 249 23600 17900 182
2 Nov-15 3720 1400 337 2120 9630 182
3 Jun-16 4950 2310 195 28100 32800 182
4 Nov-16 6050 1470 517 7470 8530 182
5 May-17 3150 1600 325 81200 14400 182
6 Jun-18 2830 4850 109 6770 21500 182
7 Jun-19 6170 2140 150 16800 20800 182
8 Jun-21 9600 1600 300 31000 8900 182
9 Jun-22 8000 2200 320 0 5100 182
10 Jun-23 8700 1500 0 60000 15000 182
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:0.39 0.51 0.58 1.03 0.53 0.00
Mann-Kendall Statistic (S):19 12 -13 5 -9 0
Confidence Factor:94.6% 83.2% 85.4% 63.6% 75.8% 45.6%
Concentration Trend:Prob. Increasing No Trend Stable No Trend Stable Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water , 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
GSI Environmental Inc., www.gsi-net.com
MOLYBDENUM WEST SITE AND SITE 2 (SHALLOW) CONCENTRATION ( ug/L)
13-Aug-23
Portland Cement Molybdenum West Site and Site 2 (Shallow)
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
Tony Howes
1
10
100
1000
10000
100000
12/14 05/16 09/17 02/19 06/20 10/21 03/23 07/24
Co
n
c
e
n
t
r
a
t
i
o
n
(
u
g
/
L
)
Sampling Date
PWEA
PWBA
P2BA
P2FA
P2HA
Cleanup
Evaluation Date:Job ID:
Facility Name: Constituent:
Conducted By: Concentration Units:ug/L
Sampling Point ID:P3BB P3CC P3DA P3FA P3GB Cleanup
Sampling Sampling
Event Date
1 Jun-15 101 4990 13 6850 10600 182
2 Nov-15 20.8 6420 9.12 312 4920 182
3 Jun-16 14.8 18400 39.9 5510 6690 182
4 Nov-16 0 25500 17400 416 265 182
5 May-17 0 24400 5400 7470 202 182
6 Jun-18 4.56 0 131 5150 886 182
7 Jun-19 4.56 0 0 2790 95.4 182
8 Jun-21 420 31000 1300 3200 1800 182
9 Jun-22 130 31000 1700 2600 610 182
10 Jun-23 38 31000 810 600 290 182
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:1.77 0.76 2.03 0.76 1.36 0.00
Mann-Kendall Statistic (S):5199-11-190
Confidence Factor:63.6% 94.6% 75.8% 81.0% 94.6% 45.6%
Concentration Trend:No Trend Prob. Increasing No Trend Stable Prob. Decreasing Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water , 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
GSI Environmental Inc., www.gsi-net.com
MOLYBDENUM SITE 3 (SHALLOW) CONCENTRATION (ug/L)
13-Aug-23
Portland Cement Molybdenum Site 3 (Shallow)
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
Tony Howes
1
10
100
1000
10000
100000
12/14 05/16 09/17 02/19 06/20 10/21 03/23 07/24
Co
n
c
e
n
t
r
a
t
i
o
n
(
u
g
/
L
)
Sampling Date
P3BB
P3CC
P3DA
P3FA
P3GB
Cleanup
Evaluation Date:Job ID:
Facility Name: Constituent:
Conducted By: Concentration Units:Standard Units
Sampling Point ID:PWS P2M P3EA P3O Cleanup Goal
Sampling Sampling
Event Date
1 Jun-15 7.77 8.02
7.96 8.2 8
2 Nov-15 8.04 8.02
7.98 8.22 8
3 Jun-16 7.77 7.89
7.99 8.58 8
4 Nov-16 8.02 7.97
8.04 8.38 8
5 May-17 7.61 7.8
7.93 8.16 8
6 Jun-18 7.74 7.80
8.31 08
7 Jun-19 7.94 7.87
0 8.44 8
8 Jun-21 8.13 7.91
8.48 8.17 8
9 Jun-22 7.8 0 10.7 7.4 8
10 Jun-23 7.808.88.28
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:0.02 0.53 0.37 0.35 0.00
Mann-Kendall Statistic (S):3 -28 23 -10 0
Confidence Factor:56.9% 99.4% 97.7% 78.4% 45.6%
Concentration Trend:No Trend Decreasing Increasing Stable Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water , 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
GSI Environmental Inc., www.gsi-net.com
PH INTERMEDIATE WELLS CONCENTRATION (Standard Units)
13-Aug-23
Portland Cement pH Intermediate Wells
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
Tony Howes
6
6.5
7
7.5
8
8.5
9
9.5
10
10.5
11
12/14 05/16 09/17 02/19 06/20 10/21 03/23 07/24
Co
n
c
e
n
t
r
a
t
i
o
n
(
S
t
a
n
d
a
r
d
Un
i
t
s
)
Sampling Date
PWS
P2M
P3EA
P3O
Cleanup Goal
Evaluation Date:Job ID:
Facility Name: Constituent:
Conducted By: Concentration Units:ug/L
Sampling Point ID:PWS P2M P3EA P3O Cleanup Goal
Sampling Sampling
Event Date
1 Jun-15 32.6 29.9 30.1 41 64
2 Nov-15 31.2 29.3 28.1 30.8 64
3 Jun-16 29.5 33.2 29.4 66.6 64
4 Nov-16 32 24.1 29.4 39.8 64
5 May-17 30.4 10.6 33.5 32.7 64
6 Jun-18 29.4 25.6 45 NS 64
7 Jun-19 35.5 24.8 NS 30.8 64
8 Jun-21 35 28 50 29 64
9 Jun-22 38 0 11 49 64
10 Jun-23 38 0 383164
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:0.10 0.60 0.34 0.31 0.00
Mann-Kendall Statistic (S):18 -24 11 -9 0
Confidence Factor:93.4% 98.2% 84.6% 79.2% 45.6%
Concentration Trend:Prob. Increasing Decreasing No Trend Stable Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water , 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
ARSENIC INTERMEDIATE WELLS CONCENTRATION (ug/L)
GSI Environmental Inc., www.gsi-net.com
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
13-Aug-23
Portland Cement Arsenic Intermediate Wells
Tony Howes
1
10
100
12/14 05/16 09/17 02/19 06/20 10/21 03/23 07/24
Co
n
c
e
n
t
r
a
t
i
o
n
(
u
g
/
L
)
Sampling Date
PWS
P2M
P3EA
P3O
Cleanup Goal
Evaluation Date:Job ID:
Facility Name: Constituent:
Conducted By: Concentration Units:ug/L
Sampling Point ID:PWS P2M P3EA P3O Cleanup Goal
Sampling Sampling
Event Date
1 Jun-15 0.1 0.1 0.1 0.1 6.2
2 Nov-15 0.1 0.1 0.1 0.1 6.2
3 Jun-16 0.1 1.94 0.1 0.1 6.2
4 Nov-16 0.1 0.1 0.1 0.1 6.2
5 May-17 0.1 0.1 0.1 0.1 6.2
6 Jun-18 0.1
0.1 0.106.2
7 Jun-19 0.1
0.1 00.16.2
8 Jun-21 0.1
0.34 3.6 0.2 6.2
9 Jun-22 0.1 0 0.1 0.1 6.2
10 Jun-23 2.4 0 3.9 0.1 6.2
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:2.20 2.04 1.89 0.47 0.00
Mann-Kendall Statistic (S):9 -13 10 3 0
Confidence Factor:75.8% 85.4% 78.4% 56.9% 45.6%
Concentration Trend:No Trend No Trend No Trend No Trend Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water , 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
CADMIUM INTERMEDIATE WELLS CONCENTRATION (ug/L)
GSI Environmental Inc., www.gsi-net.com
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
13-Aug-23
Portland Cement Cadmium Intermediate Wells
Tony Howes
0.1
1
10
12/14 05/16 09/17 02/19 06/20 10/21 03/23 07/24
Co
n
c
e
n
t
r
a
t
i
o
n
(
u
g
/
L
)
Sampling Date
PWS
P2M
P3EA
P3O
Cleanup Goal
Evaluation Date:Job ID:
Facility Name: Constituent:
Conducted By: Concentration Units:ug/L
Sampling Point ID:PWS P2M P3EA P3O Cleanup Goal
Sampling Sampling
Event Date
1 Jun-15 1111100
2 Nov-15 1111100
3 Jun-16 1 9.92 1 1 100
4 Nov-16 1 1 1 9.83 100
5 May-17 1111100
6 Jun-18 1 1 8.3 0 100
7 Jun-19 1 1 0 26.7 100
8 Jun-21 0.53 0.43 12 1.8 100
9 Jun-22 0.36 0 0.52 1.1 100
10 Jun-23 0.94 0 19 0.48 100
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:0.27 1.80 1.45 1.90 0.00
Mann-Kendall Statistic (S):-20-25910
Confidence Factor:95.5% 98.6% 75.8% 50.0% 45.6%
Concentration Trend:Decreasing Decreasing No Trend No Trend Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water , 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
CHROMIUM INTERMEDIATE WELLS CONCENTRATION (ug/L)
GSI Environmental Inc., www.gsi-net.com
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
13-Aug-23
Portland Cement Chromium Intermediate Wells
Tony Howes
0.1
1
10
100
12/14 05/16 09/17 02/19 06/20 10/21 03/23 07/24
Co
n
c
e
n
t
r
a
t
i
o
n
(
u
g
/
L
)
Sampling Date
PWS
P2M
P3EA
P3O
Cleanup Goal
Evaluation Date:Job ID:
Facility Name: Constituent:
Conducted By: Concentration Units:ug/L
Sampling Point ID:PWS P2M P3EA P3O Cleanup Goal
Sampling Sampling
Event Date
1 Jun-15 0.25 0.25 0.25 0.25 15
2 Nov-15 0.25 0.25 0.25 0.25 15
3 Jun-16 0.25 11.8 0.25 0.25 15
4 Nov-16 0.25 0.25 0.25 9.63 15
5 May-17 0.25 0.25 0.25 0.25 15
6 Jun-18 0.25 0.25 34.7 0 15
7 Jun-19 0.25 0.25 0 14.5 15
8 Jun-21 0.25 0.25 36 0.25 15
9 Jun-22 0.25 0 0.42 0.64 15
10 Jun-23 2.3 0 64 0.25 15
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:1.42 2.71 1.68 1.94 0.00
Mann-Kendall Statistic (S):9 -19 19 4 0
Confidence Factor:75.8% 94.6% 94.6% 60.3% 45.6%
Concentration Trend:No Trend Prob. Decreasing Prob. Increasing No Trend Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water , 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
LEAD INTERMEDIATE WELL CONCENTRATION (ug/L)
GSI Environmental Inc., www.gsi-net.com
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
13-Aug-23
Portland Cement Lead Intermediate Well
Tony Howes
0.1
1
10
100
12/14 05/16 09/17 02/19 06/20 10/21 03/23 07/24
Co
n
c
e
n
t
r
a
t
i
o
n
(
u
g
/
L
)
Sampling Date
PWS
P2M
P3EA
P3O
Cleanup Goal
Evaluation Date:Job ID:
Facility Name: Constituent:
Conducted By: Concentration Units:ug/L
Sampling Point ID:PWS P2M P3EA P3O Cleanup Goal
Sampling Sampling
Event Date
1 Jun-15 30.7 36.2 68.2 23.8 440
2 Nov-15 39.9 42.8 66.3 28.7 440
3 Jun-16 29.3 137 65.2 18.8 440
4 Nov-16 23.7 41.8 65.8 118 440
5 May-17 30 42.4 90.3 40.5 440
6 Jun-18 25.5 40.1 179 0 440
7 Jun-19 45.2 0.25 0 102 440
8 Jun-21 33 42 160 44 440
9 Jun-22 44 0 1.1 38 440
10 Jun-23 62 0 430 35 440
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:0.32 1.04 1.11 0.82 0.00
Mann-Kendall Statistic (S):17-22750
Confidence Factor:92.2% 97.1% 70.0% 63.6% 45.6%
Concentration Trend:Prob. Increasing Decreasing No Trend No Trend Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water , 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
MANGANESE INTERMEDIATE WELLS CONCENTRATION (ug/L)
GSI Environmental Inc., www.gsi-net.com
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
13-Aug-23
Portland Cement Manganese Intermediate Wells
Tony Howes
0.1
1
10
100
1000
12/14 05/16 09/17 02/19 06/20 10/21 03/23 07/24
Co
n
c
e
n
t
r
a
t
i
o
n
(
u
g
/
L
)
Sampling Date
PWS
P2M
P3EA
P3O
Cleanup Goal
Evaluation Date:Job ID:
Facility Name: Constituent:
Conducted By: Concentration Units:ug/L
Sampling Point ID:PWS P2M P3EA P3O Cleanup Goal
Sampling Sampling
Event Date
1 Jun-15 5 5 5 442 182
2 Nov-15 5 5 5 333 182
3 Jun-16 5 5 5.36 755 182
4 Nov-16 5 5 5 366 182
5 May-17 5 5 5 173 182
6 Jun-18 5 5 153 0 182
7 Jun-19 5 9.76 0 80.6 182
8 Jun-21 5 5 53
54 182
9 Jun-22 0.76 0 14 61 182
10 Jun-23 5 0 5 19 182
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:0.29 0.62 1.90 1.06 0.00
Mann-Kendall Statistic (S):-7 -11 5 -29 0
Confidence Factor:70.0% 81.0% 63.6% 99.5% 45.6%
Concentration Trend:Stable Stable No Trend Decreasing Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water , 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
MOLYBDENUM INTERMEDIATE WELLS CONCENTRATION (ug/L)
GSI Environmental Inc., www.gsi-net.com
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
13-Aug-23
Portland Cement Molybdenum Intermediate Wells
Tony Howes
0.1
1
10
100
1000
12/14 05/16 09/17 02/19 06/20 10/21 03/23 07/24
Co
n
c
e
n
t
r
a
t
i
o
n
(
u
g
/
L
)
Sampling Date
PWS
P2M
P3EA
P3O
Cleanup Goal