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DAQ-2024-011276
1 DAQC-1096-24 Site ID 15830 (B4) MEMORANDUM TO: STACK TEST FILE – XCL ASSETCO, LLC – Crozier 2-1A-32 THROUGH: Rik Ombach, Minor Source Oil and Gas Compliance Section Manager FROM: Paul Bushman, Environmental Scientist DATE: October 25, 2024 SUBJECT: Source: One (1) Caterpillar G3516Plus engine Contact: Lauren Brown: (713) 808-9406 Location: Duchesne County, UT Test Contractor: Oasis Emission Consultants, Inc. Permit/AO#: Permit by Rule Action Code: TR Subject: Review of stack test report dated August 23, 2024 On October 22, 2024, Utah Division of Air Quality (DAQ) received a test report for one (1) Caterpillar G3516Plus engine at Crozier 2-1A-32, Duchesne County, UT. Testing was performed August 20, 2024, to demonstrate compliance with the emission limits found in Utah Administrative Code R307-510 and 40 CFR Part 60, Subpart JJJJ. The calculated test results are: Source Test Date Pollutant Method Tester Results DAQ Results Limits Caterpillar G3516Plus SN: N6C/WPW000447 August 20, 2024 NOx 320 0.51 g/bhp-hr 0.512 g/bhp-hr 1.0 g/bhp-hr CO 320 0.15 g/bhp-hr 0.145 g/bhp-hr 2.0 g/bhp-hr VOC 320 0.16 g/bhp-hr 0.158 g/bhp-hr 0.7 g/bhp-hr DEVIATIONS: None. CONCLUSION: The stack test report appears to be acceptable. RECOMMENDATION: The emissions from the Caterpillar G3516Plus engine should be considered to have been in compliance with the emission limits of UAC R307-510 and 40 CFR Part 60, Subpart JJJJ during testing. ATTACHMENTS: DAQ stack test review excel spreadsheets, XCL AssetCo, LLC stack test report. Emissions XCL Resources Crozier 2-1A-32 Duchesne County Caterpillar G3516Plus; SN: N6C/WPW00447 Test Date: 8/20/2024 Run #1 2 3 Average Start Time 9:35 10:36 11:38 Stop Time 10:35 11:36 12:38 Sample Duration (minutes)60 60 60 BHP Engine Load - Actual (bhp) 1309 1309 1309 1309 DS Stack Diameter (inches)12.0 12.0 12.0 12.0PAVG Average (Delta P)½ (" H2O)½1.9410 1.9500 1.9590 1.9500 CP Pitot Tube Constant (unitless)0.84 0.84 0.84 0.84 TS Stack Temperature (°F)931 935 932 933 Pbar Barometric Pressure (" Hg)24.97 24.97 24.97 24.97 Ps Stack Pressure ('' H2O)1.47 1.48 1.50 1.48 O2%vd O2 (%vd)8.5 8.5 8.5 8.5 CO2%vd CO2 (%vd)7.5 7.5 7.5 7.5 N2%vd N2 (%vd)84.0 84.0 84.0 84.0 dry NOX (ppmvd)79.7 80.3 80.9 80.3 dry CO (ppmvd) 37.3 37.3 37.4 37.3 wet NMEOC (ppmvw as C3H8)22.5 22.5 22.8 22.6 Run #1 2 3 Average Bws Measured Moisture Content (%/100)0.129 0.130 0.128 0.129 Bws Saturated Moisture Content (%/100)741.329 753.319 744.256 746.302 Bws Actual Moisture Content (%/100)0.129 0.130 0.128 0.129 MD Molecular Weight Dry (lb/lb-mole)29.54 29.54 29.54 29.54 MA Molecular Weight Wet (lb/lb-mole)28.05 28.05 28.06 28.05 VS Gas Velocity (ft/sec)196.0 197.2 197.9 197.0 FACFM Gas Flow (acfm)9237 9294 9325 9285 FDSCFM Gas Flow (dscfm)2557 2564 2582 2568 FWSCFM Gas Flow (wscfm)2938 2948 2964 2950 FKWSCFH Gas Flow (kwscfh)176 177 178 177 FKWSCFM Gas Flow (kwscfm)2.938 2.948 2.964 2.950 lb/hr Gas Flow (lb/hr) 12835 12875 12952 12887 Fo Fo (unitless)1.653 1.653 1.653 1.653 wet O2 (%vw)7.4 7.4 7.4 7.4 wet CO2 (%vw)6.5 6.5 6.5 6.5 wet NOX (ppmvw)69.446 69.876 70.539 69.953 15 NOX (ppmvd @ 15% O2)37.941 38.198 38.507 38.215 82.0 lb/hr NOX (lb/hr)1.460 1.474 1.496 1.476 g/bhp-hr NOX (g/bhp-hr)0.506 0.511 0.518 0.512 1.0 wet CO (ppmvw) 32.502 32.483 32.589 32.525 15 CO (ppmvd @ 15% O2)17.757 17.757 17.790 17.768 270.0 lb/hr CO (lb/hr) 0.416 0.417 0.421 0.418 g/bhp-hr CO (g/bhp-hr) 0.144 0.145 0.146 0.145 2.0 dry NMEOC (ppmvd as C3H8)25.860 25.850 26.140 25.950 dry NMEOC (ppmvd as C3H8)25.860 25.850 26.140 25.950 15 NMEOC (ppmvd as C3H8 @ 15% O2)12.304 12.300 12.438 12.347 60.0 lb/hr NMEOC (lb/hr as C3H8)0.454 0.455 0.463 0.457 g/bhp-hr NMEOC (g/bhp-hr as C3H8)0.157 0.158 0.160 0.158 0.7 Permit Limits Field Reference Method Data Reference Method Calculations Page 1 of 1 Source Test Report For XCL Resources Crozier #2-1A-32 Duchesne County, Utah Test Date: August 20, 2024 Report Date: August 23, 2024 Federal Regulation: EPA 40 CFR 60, Subpart JJJJ Engine: Caterpillar G3516Plus SN: N6C/WPW00447 Unit ID: E170346 (15830) Prepared By: Oasis Emission Consultants, Inc. 2730 Commercial Way Rock Springs, WY 82901 August 23, 2024 Mr. Ryan Sokolowski XCL Resources Dear Mr. Sokolowski: Re: Engine Emission Testing For XCL Resources, Crozier #2-1A-32, Unit E170346 (15830), EPA 40 CFR 60, Subpart JJJJ. An air emissions test program was conducted on a Caterpillar G3516Plus engine, operated by XCL Resources and designated as Unit E170346 (15830), located at the Crozier #2-1A-32 in Duchesne County, Utah. The purpose of the testing was to demonstrate compliance with the emissions limits contained in EPA 40 CFR 60, Subpart JJJJ, for oxides of nitrogen (NOx), carbon monoxide (CO) and volatile organic compounds (VOC). Oasis Emission Consultants, Inc. conducted the testing on August 20, 2024. EPA 40 CFR 60, Subpart JJJJ Emission Levels The average recorded levels were found to comply with emission levels stipulated in the permit, as shown in the attached report and summarized below. Emission Unit Avg NOx Permit NOx Avg CO Permit CO Avg NMNEHC* Permit VOC g/bhp-hr 0.51 1.0 0.15 2.0 0.16 0.7 *VOC levels reported as non-methane, non-ethane hydrocarbon on a propane basis (NMNEHC C3). Catalyst Parameters (Averaged Over 3 Test Runs) Inlet Temp (deg F) DP (in H2O) 904 1.6 Engine Load (Averaged Over 3 Test Runs) Rated BHP Operating BHP % Load 1340 1309.0 97.7 Testing Protocol The attached report was generated using an extractive FTIR system using methodologies as required by and in accordance with EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320 as outlined in the submitted Source Test Protocol. Quality Assurance Oasis has performed a full review of the raw data and calculated results in this report. Any errors we have encountered have been listed in the body of this report. After performing the review, we are confident that this engine has met all requirements. If you have any questions or require further information, please contact the undersigned at (307) 382-3297. Yours truly, Oasis Emission Consultants, Inc. _________________________ _______________________ Charles A. Chapman Cember Crawley Manager of Technical Services Environmental Scientist _________________________ Christopher N. Knott, P.Eng. Director, Engineering and Operations SOURCE EMISSION TEST REPORT FEDERAL REGULATION EPA 40 CFR 60, Subpart JJJJ Test Performed By: Oasis Emission Consultants, Inc. Test Company Contact: Chris Knott 2730 Commercial Way Rock Springs, WY 82901 307.382.3297 Owner/Operator: XCL Resources Owner/Operator Contact: Ryan Sokolowski Facility Name: Crozier #2-1A-32 Duchesne County, Utah Emission Source: Caterpillar G3516Plus Unit E170346 (15830) Date of Test: August 20, 2024 Date of Report: August 23, 2024 TABLE OF CONTENTS 1.1 Introduction .......................................................................................................................... 1 2.1 Stack Sampling Location ..................................................................................................... 2 3.1 Discussion of NOx, CO and VOC Test Results ................................................................... 4 3.1.1 Source Test 1 ............................................................................................................................................ 4 3.1.2 Source Test 2 ............................................................................................................................................ 4 3.1.3 Source Test 3 ............................................................................................................................................ 4 4.1 Stack Sampling Methods and Procedures ............................................................................ 5 4.2 Equipment Utilization .......................................................................................................... 6 4.3 Measurement of VOC (NMNEHC C3) ............................................................................... 7 4.4 Process Parameters............................................................................................................... 7 5.1 Quality Assurance ................................................................................................................ 8 List of Tables and Figures Figure 1 - Sample Port Location ............................................................................................................................. 2 Figure 2 - Sampling Train Schematic-Method 320 ................................................................................................ 6 Table 1 - Insertion Depths of Traverse Points for Stratification Test ..................................................................... 3 Table 2 - Location of Traverse Points in Circular Stacks ....................................................................................... 3 Table 3 - Test Matrix .............................................................................................................................................. 5 Table 4 - Concentrations and Interference .............................................................................................................. 6 APPENDIX A: NOx, CO and VOC Test Data APPENDIX B: Quality Assurance/Calibration Data APPENDIX C: Load Approximation APPENDIX D: Example Calculations and Summary APPENDIX E: Field Notes 1 1.1 Introduction An air emissions test program was conducted on a Caterpillar G3516Plus engine, operated by XCL Resources and designated as Unit E170346 (15830), located at the Crozier #2-1A-32 in Duchesne County, Utah. The purpose of the testing was to demonstrate compliance with the emissions limits contained in EPA 40 CFR 60, Subpart JJJJ, for oxides of nitrogen (NOx), carbon monoxide (CO) and volatile organic compounds (VOC) defined as non-methane, non- ethane hydrocarbons, reported as propane (NMNEHC C3). The facility is currently located in Duchesne County, Utah. Three one hour test runs were performed on August 20, 2024 to analyze NOx, CO and VOC emission levels. Test runs were performed according to methodologies outlined by EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320 as outlined in the submitted Source Test Protocol. Each one hour test run consisted of 60 readings taken at one minute intervals. Process parameters were recorded during each test run in order to determine the load. Parameters include the engine RPM, intake manifold temperature and pressure, and the site elevation. The following key personnel were present during testing: David Martinez, OEC Brandon, XCL 2 2.1 Stack Sampling Location The facility is currently located in Duchesne County, Utah. Testing was conducted on the Caterpillar G3516Plus engine. The sampling port for moisture, NOx, CO and VOC measurements was approximately 2.5 pipe diameters (30”) downstream from the nearest flow disturbance (Distance B) and 1.0 pipe diameters (12”) upstream from the nearest disturbance (Distance A), as seen in Figure 1. The stack sampling location was placed at approximately 50% insertion depth based on an O2 stratification check which demonstrated a non-stratified flow regime. The stratification was conducted according to EPA 40 CFR 75(A), §6.5.6.1 using 3 traverse points determined according to Table 1 below. In accordance with EPA 40 CFR 60(A), Method 1, a total of 16 traverse insertion depths (8 traverse points through each of the 2 ports) were determined according to Table 2 below in order to conduct Method 2. Figure 1 - Sample Port Location 12" A B Oxidation Catalyst 3 Table 1 - Insertion Depths of Traverse Points for Stratification Test Traverse Point Insertion Depth (Percent of Stack Diameter) 1 16.6 2 50.0 3 83.3 Table 2 - Location of Traverse Points in Circular Stacks 4 3.1 Discussion of NOx, CO and VOC Test Results Three, one hour test runs were performed on August 20, 2024 to analyze exhaust NOx, CO and VOC (NMNEHC C3) emission levels to demonstrate compliance with the emissions limits contained in EPA 40 CFR 60, Subpart JJJJ. Testing for NOx, CO and VOC were run concurrently with one another. Each test was performed at the maximum achievable load. Measured emissions were below permitted limits. Please refer to the Appendices for a listing of all raw data, calibration error response and calculations performed per EPA 40 CFR 60(A) requirements. 3.1.1 Source Test 1: Caterpillar G3516Plus, NOx, CO and VOC The first test was performed from 9:35 to 10:34 for NOx, CO and VOC. Based on operating parameters recorded during testing, the load was approximated at 1309.0 bhp, and the average NOx and CO levels were found to be 0.51 g/bhp-hr and 0.14 g/bhp-hr respectively, below limitations. The VOC level tested at 0.16 g/bhp- hr, which tested in compliance. 3.1.2 Source Test 2: Caterpillar G3516Plus, NOx, CO and VOC The second test was performed from 10:36 to 11:36 for NOx, CO and VOC. Based on operating parameters recorded during testing, the load was approximated at 1309.0 bhp, and the average NOx and CO levels were found to be 0.51 g/bhp-hr and 0.14 g/bhp-hr respectively, below limitations. The VOC level tested at 0.16 g/bhp- hr, which tested in compliance. 3.1.3 Source Test 3: Caterpillar G3516Plus, NOx, CO and VOC The third test was performed from 11:38 to 12:37 for NOx, CO and VOC. Based on operating parameters recorded during testing, the load was approximated at 1309.0 bhp, and the average NOx and CO levels were found to be 0.52 g/bhp-hr and 0.15 g/bhp-hr respectively, below limitations. The VOC level tested at 0.16 g/bhp- hr, which tested in compliance. Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) VOC (ppmvd) VOC (g/bhp-hr) O2 (%) 1 79.74 0.51 37.32 0.14 25.86 0.16 8.5 Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) VOC (ppmvd) VOC (g/bhp-hr) O2 (%) 2 80.28 0.51 37.32 0.14 25.82 0.16 8.5 Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) VOC (ppmvd) VOC (g/bhp-hr) O2 (%) 3 80.93 0.52 37.39 0.15 26.14 0.16 8.5 5 4.1 Stack Sampling Methods and Procedures Testing followed EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320, with no exceptions. Table 3 - Test Matrix Method Title Parameter Reference EPA 40 CFR 60 Appendix A, Method 1 Sample and Velocity Traverses for Stationary Sources Sampling Point Determination https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_1_3.pdf EPA 40 CFR 60 Appendix A, Method 2 Determination of Stack Gas Velocity and Volumetric Flow Rate Exhaust Effluent Flow https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_2.pdf EPA 40 CFR 60 Appendix A, Method 3 Gas Analysis for the Determination of Dry Molecular Weight O2, CO2, Dry Volumetric Flow Rate https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_3.pdf EPA 40 CFR 63 Appendix A, EPA Method 320 Vapor Phase Organic and Inorganic Emissions by Extractive FTIR Nitrogen Oxides, Carbon Monoxide, Non- Methane Non- Ethane Hydrocarbons on a Propane Basis https://www.epa.gov/ emc/method-320- vapor-phase-organic- and-inorganic- emissions-extractive- ftir United States. U.S. Environmental Protection Agency. “EMC Promulgated Test Methods.” Air Emission Measurement Center (EMC). 31 August 2023. Web. 18 March 2024. <https://www.epa.gov/emc/emc-promulgated-test-methods>. 6 4.2 Equipment Utilization The following equipment was used during the tests performed at this facility in conjunction with procedures outlined by EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320. • (1) MKS MultiGas 2030 FTIR Continuous Gas Analyzer (0.210 L/min sample flow, 0.014 atmosphere sample pressure, 1 atmosphere cell pressure, 191°C cell temperature) • (1) Laptop Computer for the FTIR Analyzer using MKS MG2000 Software • (1) 75ft or 100ft Heated Teflon Line w/ Heated Sample Probe and Spike Bypass Line • S-Type Pitot Tube c/w 20 ft. Heated Sample Line (coefficient 0.84) • (1) Fyrite O2/CO2 Analyzer • (5) EPA Protocol G1 Calibration Gas (NOx, CO, C3H8, C2H4 and NO2) The MKS Multigas 2030 FTIR Analyzer operated with a spectral resolution of 0.5 cm-1 and a scan time of 30 seconds. The FTIR spectrometer utilizes a multi-pass gas cell with a 5.11 meter effective pathlength. Figure 2 - Sampling Train Schematic-Method 320 Table 4 - Concentrations and Interference 7 The MKS 2030 software provides a Natural Gas Method that is designed to minimize all expected interferences by removing the regions in the quant region where they are most absorbed (i.e. picket fence approach). So, for example, all the water peaks that are greater than about 0.1 abs are removed from the quant region. Since the spectral noise measured (sample spectrum) is in the range of 0.001 absorbance, it is desirable to have any error within this range. The MKS software will match the water calibration spectrum to the sample spectrum at any 1 point in the spectrum to about 1% precision. So, 1% of 0.1 absorbance is 0.001 abs. This is why any peaks greater than this for interfering compounds are usually excluded so they do not interfere. To summarize, the MKS software and the method are designed to minimize any interferences by removing their largest interfering absorptions. 4.3 Measurement of VOC (NMNEHC C3) The algorithm currently used for NMNEHC C3 and developed for natural gas fired applications by Dr. Spartz and MKS instruments in accordance with EPA standards, is the following: (2.4*c8/(1+exp((2-c8)/0.2))+1.9*c11/(1+exp((2-c11)/0.2))+6*c12/(1+exp((0.5-c12) /0.2))+2.85*c13/(1+exp((2-c13)/0.2))+3*c14/(1+exp((1-c14)/0.2)))/3 c8= acetylene c11= ethylene c12= hexane c13= propylene c14= propane Note: The constants in front of each of the compounds listed represents the FID response factor when calibrated with Propane. As with any CEMS analyzer, the FTIR may demonstrate a negative zero bias. The “exp” functions listed in the algorithm above are intended to mathematically filter out any negative biases and set them to approach zero. 4.4 Process Parameters Process parameters were recorded during each test run in order to determine the load. Parameters include the engine RPM, intake manifold temperature and pressure, and the site elevation. Results are provided in Appendix C. 8 5.1 Quality Assurance The MKS Multigas 2030 FTIR Analyzer was used to measure NOx, CO and VOC on a dry basis. A pre Direct and System calibration measurement was made on compounds of NOx, CO, C3H8 and C2H4. In addition, post System calibrations were made on compounds of NOx, CO, C3H8 and C2H4. Compounds of CO2 and C3H8 were measured for the quality assurance spiking requirements. Levels for calibrations and zeroes must be within +/- 5% of the certified calibration gas or response to zero gas, respectively. CTS procedures were followed according to EPA requirements for both pre and post testing. Similarly, QA spiking procedures were followed. Analysis of the CO2 exhaust effluent was used to determine the dilution factor. Steady levels of the CO2 were observed and a sufficient duration of time was allowed to elapse for a representative average. The calibration gas was spiked into the effluent stream using a bypass line at approximately 10% of the sampling rate. The dilution factor was obtained from observation of the stack CO2 behavior using the following equation: CO2AVG – CO2SPIKE DF = ------------------------ CO2 AVG Where: CO2AVG = The average undiluted CO2 stack gas concentration of spike measurements CO2SPIKE = The average diluted CO2 stack gas concentration when spiked The sample recovery was then obtained from the following equation: % REC = (Spike MEAS – Stack MEAS)* (1 – DF) --------------------------------------------------------- CS * DF Where: Spike MEAS = The average diluted stack gas concentration when spiked Stack MEAS = The average undiluted stack gas concentration DF = Dilution factor CS = Certified concentration of calibration standards The Sample Recovery average level for C3H8 was found to be 86.5%, which was within the allowable tolerance of Method 320 (70% to 130%). A summary of all spiking procedures/results can be found in Appendix B. APPENDIX A NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 74.690087 4.084149 78.774236 37.764174 26.764526 12.766118 9:35:46 08/20/2024 2 74.608984 4.226231 78.835215 37.372758 25.531752 13.027449 9:36:46 08/20/2024 3 78.09744 4.643727 82.741167 37.460167 25.308459 13.020963 9:37:47 08/20/2024 4 76.991707 4.573643 81.56535 37.211684 25.455855 13.06855 9:38:47 08/20/2024 5 77.082688 4.682174 81.764862 37.370054 25.499199 13.43193 9:39:47 08/20/2024 6 74.392056 4.552213 78.944269 37.105849 25.887185 13.479228 9:40:47 08/20/2024 7 75.73219 4.643234 80.375424 37.164931 25.745735 13.197677 9:41:47 08/20/2024 8 74.592511 4.590218 79.182729 37.101805 25.862555 13.09397 9:42:47 08/20/2024 9 74.243163 4.576922 78.820085 37.098102 26.056090 13.162565 9:43:47 08/20/2024 10 75.350185 4.763506 80.113691 37.155749 25.986003 13.18471 9:44:48 08/20/2024 11 74.055354 4.744645 78.799999 36.975512 26.328713 13.87237 9:45:48 08/20/2024 12 74.632784 4.725279 79.358063 37.177522 26.024757 13.411411 9:46:48 08/20/2024 13 78.242786 5.082562 83.325348 37.108957 25.724748 13.198411 9:47:48 08/20/2024 14 75.629811 4.791144 80.420955 37.090242 26.797566 12.698824 9:48:48 08/20/2024 15 73.077272 4.500802 77.578074 37.212677 27.019251 12.312144 9:49:48 08/20/2024 16 73.786028 4.552629 78.338657 37.34207 26.664732 12.265843 9:50:49 08/20/2024 17 73.454369 4.479118 77.933487 37.265922 26.689588 12.359187 9:51:49 08/20/2024 18 76.011272 4.848744 80.860016 37.515619 26.123771 12.472057 9:52:49 08/20/2024 19 74.567177 4.793959 79.361136 37.457598 26.052213 12.783062 9:53:49 08/20/2024 20 75.425915 4.884297 80.310212 37.594168 26.128333 12.998119 9:54:49 08/20/2024 21 73.765151 4.683889 78.44904 37.273249 25.653831 13.478685 9:55:49 08/20/2024 22 70.999043 4.35813 75.357173 37.355399 25.882537 12.906246 9:56:49 08/20/2024 23 73.594268 4.753319 78.347587 37.32368 25.918219 12.900867 9:57:50 08/20/2024 24 75.053222 4.939964 79.993186 37.441276 25.707727 12.789573 9:58:50 08/20/2024 25 74.985009 4.964488 79.949497 37.129279 25.824926 12.57002 9:59:50 08/20/2024 26 74.751022 4.967149 79.718171 37.262182 25.913527 12.766137 10:00:50 08/20/2024 27 74.539007 4.909735 79.448742 37.266017 25.679857 12.842744 10:01:50 08/20/2024 28 75.377146 4.924416 80.301562 37.520027 26.135140 12.918662 10:02:50 08/20/2024 29 75.63804 4.94615 80.58419 37.633369 26.112679 13.186709 10:03:51 08/20/2024 30 73.230439 4.633191 77.86363 37.269994 25.756235 12.941117 10:04:51 08/20/2024 31 75.61215 4.9039 80.51605 37.497363 26.165976 13.015892 10:05:51 08/20/2024 32 75.358035 4.978009 80.336044 37.464546 25.998033 12.698003 10:06:51 08/20/2024 33 72.392006 4.708091 77.100097 37.231098 26.602382 12.696992 10:07:51 08/20/2024 34 73.609812 4.924128 78.53394 36.979556 25.566773 12.492126 10:08:51 08/20/2024 35 76.44225 5.252342 81.694592 37.331184 25.656900 12.585591 10:09:51 08/20/2024 36 74.850664 5.148629 79.999293 37.360715 25.806238 12.570417 10:10:52 08/20/2024 37 74.953677 5.189278 80.142955 37.287138 25.666990 13.739824 10:11:52 08/20/2024 38 73.713115 5.09416 78.807275 36.99498 25.591371 12.967434 10:12:52 08/20/2024 39 74.937184 5.155965 80.093149 37.373639 26.126070 12.739262 10:13:52 08/20/2024 40 73.442873 4.945254 78.388127 37.267252 26.302805 12.739555 10:14:52 08/20/2024 41 74.034146 4.982339 79.016485 37.263855 26.218255 12.643096 10:15:52 08/20/2024 42 74.219778 4.942133 79.161911 37.395448 26.032086 12.518215 10:16:53 08/20/2024 43 73.718638 4.777308 78.495946 37.342502 26.222181 12.396504 10:17:53 08/20/2024 44 71.557888 4.593685 76.151573 37.088485 26.533783 12.236068 10:18:53 08/20/2024 45 73.618345 4.776237 78.394582 37.424097 26.126498 12.908949 10:19:53 08/20/2024 46 74.160874 4.830047 78.990921 37.358989 26.072546 13.015406 10:20:53 08/20/2024 47 74.165853 4.804179 78.970032 37.304596 26.025483 12.662437 10:21:53 08/20/2024 48 74.409869 4.895604 79.305473 37.364852 25.085951 13.500826 10:22:53 08/20/2024 49 75.74881 5.002652 80.751462 37.418569 24.774231 13.30366 10:23:54 08/20/2024 50 75.361293 4.974913 80.336206 37.589791 25.666044 13.064478 10:24:54 08/20/2024 51 74.34653 4.877633 79.224163 37.44512 25.718348 12.432159 10:25:54 08/20/2024 52 75.287521 4.925136 80.212657 37.259638 24.869217 13.357519 10:26:54 08/20/2024 53 75.401966 5.029984 80.43195 37.350236 24.752286 13.098818 10:27:54 08/20/2024 54 75.505591 5.022276 80.527867 37.245202 25.112984 13.422613 10:28:54 08/20/2024 55 77.892833 5.279136 83.171969 37.599382 25.689144 12.906474 10:29:54 08/20/2024 56 76.901144 5.103291 82.004435 37.484417 25.594182 12.517361 10:30:55 08/20/2024 57 74.99156 4.908733 79.900293 37.436767 25.750457 12.603845 10:31:54 08/20/2024 58 77.56884 5.159677 82.728517 37.468991 25.413821 13.075023 10:32:54 08/20/2024 59 77.775817 5.32828 83.104097 37.299374 24.650226 12.890574 10:33:54 08/20/2024 60 75.499959 5.175505 80.675464 37.424602 25.798224 12.791146 10:34:54 08/20/2024 AVG 74.90 4.84 79.74 37.32 25.86 12.91 ppm@15% O2 37.94 17.76 12.31 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.51 1.46 0.14 0.42 0.16 0.45 E170346 (15830) FTIR Measurements Calculated Emission Levels XCL Resources Crozier #2-1A-32 Run 1 Record Date EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 12 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 3.68 1391 1.47 1.918 Average O2 8.5 (% dry)A 2 1.26 3.72 1.929 Average CO2 7.5 (% dry)A 3 2.33 3.76 1.939 Average N2 + CO 84.0 (% dry)A 4 3.88 3.81 1.952 Dry Molecular Weight 29.54 lb/lbmol A 5 8.12 3.88 1.970 Wet Molecular Weight 28.05 lb/lbmol A 6 9.67 3.80 1.949 EPA REFERENCE METHOD 320 A 7 10.74 3.74 1.934 Barometric Pressure 24.97 in Hg A 8 11.50 3.70 1.924 Moisture Content 12.91 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 79.74 ppm A 11 Calculated NOx Mass Output 1.46 lbs/hr A 12 Calculated NOx Output 0.51 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 37.32 ppm A 15 Calculated CO Mass Output 0.42 lbs/hr A 16 Calculated CO Output 0.14 g/bhp-hr B 1 0.50 3.69 1391 1.47 1.921 EPA REFERENCE METHOD 320 B 2 1.26 3.72 1.929 Average Analyzer NMNEHC Level 25.86 ppm B 3 2.33 3.75 1.936 Calculated NMNEHC Mass Output 0.45 lbs/hr B 4 3.88 3.81 1.952 Calculated NMNEHC Output 0.16 g/bhp-hr B 5 8.12 3.89 1.972 LOAD APPROXIMATION B 6 9.67 3.83 1.957 Estimated Engine Load 1309.0 BHP B 7 10.74 3.79 1.947 B 8 11.50 3.74 1.934 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 3.8 1391 1.5 1.941 Average Stack Gas Velocity 196.05 ft/sec Average Dry Flowrate 2559.80 dscfm TEST RUN # 1 NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 77.470603 5.505515 82.976118 37.433989 24.262950 13.602789 10:36:54 08/20/2024 2 75.378115 5.294588 80.672703 37.377986 25.153171 13.241277 10:37:55 08/20/2024 3 73.387216 5.06226 78.449476 37.456243 25.343433 13.589467 10:38:55 08/20/2024 4 75.181629 5.14253 80.324159 37.547551 26.124433 13.100438 10:39:55 08/20/2024 5 75.90786 5.415332 81.323192 37.378019 25.873336 12.822342 10:40:55 08/20/2024 6 75.679117 5.431058 81.110175 37.118161 25.264899 12.651235 10:41:55 08/20/2024 7 74.468413 5.337016 79.805429 37.364076 25.876876 12.722823 10:42:55 08/20/2024 8 73.025819 5.138259 78.164078 37.367918 26.217863 12.630119 10:43:56 08/20/2024 9 73.976028 5.126498 79.102526 37.204541 26.007293 12.608344 10:44:56 08/20/2024 10 73.671993 5.138318 78.810311 37.158551 25.971202 12.597215 10:45:56 08/20/2024 11 74.981938 5.321239 80.303177 37.430943 25.466960 12.534594 10:46:56 08/20/2024 12 75.550522 5.384756 80.935278 37.663992 25.632782 12.749293 10:47:56 08/20/2024 13 73.337061 5.136934 78.473995 37.179697 25.363624 13.332822 10:48:56 08/20/2024 14 74.177474 5.106826 79.2843 37.238197 25.107204 13.169446 10:49:56 08/20/2024 15 75.38999 4.861785 80.251775 37.233994 25.677150 12.88849 10:50:57 08/20/2024 16 73.355217 5.05166 78.406877 37.25154 26.050260 12.755739 10:51:57 08/20/2024 17 74.713009 5.085115 79.798124 37.094427 25.170791 13.312317 10:52:57 08/20/2024 18 75.781842 5.160027 80.941869 37.290318 25.320518 15.043084 10:53:57 08/20/2024 19 77.84524 5.431979 83.277219 37.667832 24.729819 13.536928 10:54:57 08/20/2024 20 76.817484 5.369161 82.186645 37.475449 24.980579 12.915148 10:55:57 08/20/2024 21 75.001872 5.18185 80.183722 37.314951 25.563801 12.760429 10:56:57 08/20/2024 22 76.725147 5.433578 82.158725 37.571876 25.198176 12.829719 10:57:58 08/20/2024 23 76.030537 5.452363 81.4829 37.50675 25.551238 12.7364 10:58:58 08/20/2024 24 75.473075 5.378209 80.851284 37.414513 25.394963 12.612576 10:59:58 08/20/2024 25 79.593585 5.916355 85.50994 37.40114 24.524975 13.175613 11:00:58 08/20/2024 26 76.84331 5.458857 82.302167 37.311536 25.496330 12.93066 11:01:58 08/20/2024 27 75.834307 5.368656 81.202963 37.367982 25.964409 12.736209 11:02:58 08/20/2024 28 75.571898 5.388898 80.960796 37.262084 26.260855 12.738484 11:03:58 08/20/2024 29 74.680509 5.246561 79.92707 37.328557 26.147220 12.702835 11:04:59 08/20/2024 30 74.604331 5.270799 79.87513 37.321221 25.123194 13.284664 11:05:59 08/20/2024 31 77.705878 5.76263 83.468508 37.413487 25.060743 12.909036 11:06:59 08/20/2024 32 74.229378 5.299153 79.528531 37.40361 25.909428 12.856662 11:07:59 08/20/2024 33 73.108591 5.019681 78.128272 37.334283 25.886136 12.720845 11:08:59 08/20/2024 34 72.938536 4.996624 77.93516 37.381558 25.907448 12.700634 11:09:59 08/20/2024 35 75.571481 5.411465 80.982946 37.389969 25.587743 12.640746 11:11:00 08/20/2024 36 75.585477 5.418726 81.004203 37.333284 26.235869 12.5831 11:12:00 08/20/2024 37 74.703468 5.264156 79.967624 37.284001 26.141505 12.810821 11:13:00 08/20/2024 38 75.147819 5.240168 80.387987 37.460179 26.648228 13.272482 11:14:00 08/20/2024 39 74.708644 5.320292 80.028936 37.249488 26.219242 12.730381 11:15:00 08/20/2024 40 78.489267 5.776248 84.265515 37.436225 25.361195 12.611918 11:16:00 08/20/2024 41 75.746879 5.433428 81.180307 37.057478 26.027639 12.659909 11:17:00 08/20/2024 42 74.461334 5.230362 79.691696 37.061463 26.083017 13.177775 11:18:01 08/20/2024 43 72.559999 5.054762 77.614761 36.982676 26.296053 12.870743 11:19:01 08/20/2024 44 72.992452 5.00029 77.992742 37.199153 26.960481 12.67608 11:20:01 08/20/2024 45 74.714715 5.17413 79.888845 37.419058 26.595718 12.653207 11:21:01 08/20/2024 46 76.204975 5.313642 81.518617 37.288488 26.164006 15.103609 11:22:01 08/20/2024 47 74.57065 5.25109 79.82174 37.220756 25.695906 14.011678 11:23:01 08/20/2024 48 75.827432 5.482364 81.309796 37.253803 25.274720 13.609692 11:24:01 08/20/2024 49 73.828633 5.23973 79.068363 37.1757 25.547758 13.016574 11:25:02 08/20/2024 50 75.360655 5.36877 80.729425 37.278184 26.277920 12.748148 11:26:02 08/20/2024 51 74.717168 5.293566 80.010734 37.21316 26.265935 12.661625 11:27:02 08/20/2024 52 75.131151 5.413779 80.54493 37.310708 26.281439 12.668546 11:28:02 08/20/2024 53 75.860884 5.448448 81.309332 37.447709 26.267873 12.735034 11:29:02 08/20/2024 54 74.62567 5.286535 79.912205 37.43856 26.596283 12.719072 11:30:03 08/20/2024 55 73.213039 5.193908 78.406947 37.363082 26.753237 12.602749 11:31:03 08/20/2024 56 72.361369 5.122547 77.483916 37.141979 26.822105 12.571675 11:32:03 08/20/2024 57 72.689592 5.123959 77.813551 37.232737 26.508277 12.754183 11:33:03 08/20/2024 58 72.955571 5.163462 78.119033 37.31733 26.555597 12.766146 11:34:03 08/20/2024 59 74.650673 5.312075 79.962748 37.226212 26.108404 12.609035 11:35:03 08/20/2024 60 74.13585 5.307519 79.443369 37.329291 26.053814 12.649319 11:36:03 08/20/2024 AVG 74.99 5.29 80.28 37.32 25.82 12.96 ppm@15% O2 38.20 17.76 12.28 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.51 1.47 0.14 0.42 0.16 0.45 Calculated Emission Levels Record Date XCL Resources Crozier #2-1A-32 Run 2 E170346 (15830) FTIR Measurements EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 12 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 3.71 1395 1.48 1.926 Average O2 8.5 (% dry)A 2 1.26 3.75 1.936 Average CO2 7.5 (% dry)A 3 2.33 3.78 1.944 Average N2 + CO 84.0 (% dry)A 4 3.88 3.83 1.957 Dry Molecular Weight 29.54 lb/lbmol A 5 8.12 3.89 1.972 Wet Molecular Weight 28.04 lb/lbmol A 6 9.67 3.85 1.962 EPA REFERENCE METHOD 320 A 7 10.74 3.82 1.954 Barometric Pressure 24.97 in Hg A 8 11.50 3.77 1.942 Moisture Content 12.96 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 80.28 ppm A 11 Calculated NOx Mass Output 1.47 lbs/hr A 12 Calculated NOx Output 0.51 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 37.32 ppm A 15 Calculated CO Mass Output 0.42 lbs/hr A 16 Calculated CO Output 0.14 g/bhp-hr B 1 0.50 3.70 1395 1.48 1.924 EPA REFERENCE METHOD 320 B 2 1.26 3.74 1.934 Average Analyzer NMNEHC Level 25.82 ppm B 3 2.33 3.77 1.942 Calculated NMNEHC Mass Output 0.45 lbs/hr B 4 3.88 3.82 1.954 Calculated NMNEHC Output 0.16 g/bhp-hr B 5 8.12 3.91 1.977 LOAD APPROXIMATION B 6 9.67 3.87 1.967 Estimated Engine Load 1309.0 BHP B 7 10.74 3.84 1.960 B 8 11.50 3.81 1.952 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 3.8 1395 1.5 1.950 Average Stack Gas Velocity 197.24 ft/sec Average Dry Flowrate 2566.70 dscfm TEST RUN # 2 NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 74.627174 5.357371 79.984545 37.19698 25.876702 12.717298 11:38:04 08/20/2024 2 72.257954 5.053522 77.311476 36.931975 25.802707 13.092375 11:39:04 08/20/2024 3 75.735116 5.349299 81.084415 37.288908 26.117354 12.714843 11:40:04 08/20/2024 4 75.109738 5.319483 80.429221 37.211906 25.961572 12.611221 11:41:04 08/20/2024 5 75.948997 5.532082 81.481079 37.310638 25.656400 12.621025 11:42:04 08/20/2024 6 80.571807 6.104694 86.676501 37.493577 25.183307 12.613146 11:43:04 08/20/2024 7 76.200645 5.645049 81.845694 37.164387 26.037400 12.615593 11:44:05 08/20/2024 8 74.74619 5.294161 80.040351 37.233607 26.599510 12.742415 11:45:05 08/20/2024 9 74.253404 5.212352 79.465756 37.289107 26.809735 12.814022 11:46:05 08/20/2024 10 74.321903 5.178701 79.500604 37.294424 25.852625 13.110882 11:47:05 08/20/2024 11 77.282313 5.581702 82.864015 37.373061 25.489793 15.345436 11:48:05 08/20/2024 12 77.49349 5.678078 83.171568 37.551318 25.211538 13.460727 11:49:05 08/20/2024 13 77.602918 5.680996 83.283914 37.511777 26.307150 12.903352 11:50:05 08/20/2024 14 76.273039 5.481404 81.754443 37.430062 26.430925 12.880813 11:51:06 08/20/2024 15 75.452222 5.359831 80.812053 37.538104 26.306747 12.966655 11:52:06 08/20/2024 16 78.292783 5.695369 83.988152 37.601122 25.571563 12.803375 11:53:06 08/20/2024 17 78.455003 5.754688 84.209691 37.710654 25.836462 12.657164 11:54:06 08/20/2024 18 77.612824 5.612985 83.225809 37.588187 25.990970 12.532148 11:55:06 08/20/2024 19 74.663718 5.260291 79.924009 37.606217 26.496357 12.555426 11:56:06 08/20/2024 20 73.600729 5.078507 78.679236 37.424134 26.641560 12.577548 11:57:07 08/20/2024 21 75.248874 5.371959 80.620833 37.308997 26.319719 12.506796 11:58:07 08/20/2024 22 75.196751 5.334085 80.530836 37.657007 26.501245 12.552937 11:59:07 08/20/2024 23 75.71406 5.4476 81.16166 37.703846 26.291004 12.59406 12:00:07 08/20/2024 24 74.844608 5.354659 80.199267 37.660831 26.306802 12.550672 12:01:07 08/20/2024 25 75.1244 5.394392 80.518792 37.757336 26.554468 12.945624 12:02:07 08/20/2024 26 77.366576 5.615242 82.981818 37.816001 25.895574 12.686701 12:03:07 08/20/2024 27 76.427011 5.522927 81.949938 37.567734 26.323615 12.69449 12:04:08 08/20/2024 28 73.74677 5.257732 79.004502 37.370502 26.308511 12.695967 12:05:08 08/20/2024 29 71.612862 4.960997 76.573859 37.441509 27.006660 12.6955 12:06:08 08/20/2024 30 70.218691 4.748089 74.96678 37.23066 27.271994 13.142897 12:07:08 08/20/2024 31 72.009816 4.976621 76.986437 37.46688 26.349153 13.003777 12:08:08 08/20/2024 32 74.013224 5.223394 79.236618 37.5805 25.671246 12.868476 12:09:08 08/20/2024 33 73.907262 5.265583 79.172845 37.44557 26.180440 12.83585 12:10:08 08/20/2024 34 73.190111 5.128482 78.318593 37.330952 26.578050 12.781828 12:11:09 08/20/2024 35 71.983274 4.962204 76.945478 37.494939 27.002190 12.928714 12:12:09 08/20/2024 36 75.791304 5.476411 81.267715 37.399647 25.629338 12.719557 12:13:09 08/20/2024 37 77.570363 5.710029 83.280392 37.408378 25.600621 12.583465 12:14:09 08/20/2024 38 79.069615 5.908725 84.97834 37.491787 25.615101 12.555319 12:15:09 08/20/2024 39 77.646627 5.772231 83.418858 37.36755 25.875488 12.618902 12:16:09 08/20/2024 40 76.275072 5.598158 81.87323 37.508233 26.411740 12.62442 12:17:09 08/20/2024 41 74.890491 5.43979 80.330281 37.354528 26.719242 12.599672 12:18:10 08/20/2024 42 75.051435 5.509972 80.561407 37.011769 26.425210 12.538957 12:19:10 08/20/2024 43 74.776228 5.441037 80.217265 37.141327 26.476248 12.571623 12:20:10 08/20/2024 44 74.524988 5.42543 79.950418 37.196344 26.435742 12.587473 12:21:10 08/20/2024 45 72.048303 5.038776 77.087079 37.102317 26.232395 13.75288 12:22:10 08/20/2024 46 77.002744 5.711045 82.713789 37.396161 25.164969 14.640719 12:23:10 08/20/2024 47 79.244102 6.056429 85.300531 37.35416 24.569426 13.031489 12:24:11 08/20/2024 48 76.053884 5.671103 81.724987 37.266474 25.898626 12.661021 12:25:11 08/20/2024 49 74.931056 5.486119 80.417175 37.134719 25.927832 12.655376 12:26:11 08/20/2024 50 73.308717 5.32917 78.637887 37.206294 26.355006 12.670693 12:27:11 08/20/2024 51 74.327639 5.337356 79.664995 37.198776 26.235428 12.789414 12:28:11 08/20/2024 52 75.770871 5.407668 81.178539 37.321957 26.352332 12.81875 12:29:11 08/20/2024 53 77.399899 5.627473 83.027372 37.499583 25.994770 12.772671 12:30:11 08/20/2024 54 76.962742 5.664243 82.626985 37.303378 26.160598 12.841468 12:31:12 08/20/2024 55 75.726234 5.498112 81.224346 37.204982 26.454894 12.89136 12:32:12 08/20/2024 56 76.29434 5.530815 81.825155 37.195936 26.229238 12.863756 12:33:12 08/20/2024 57 76.10657 5.387951 81.494521 37.446309 26.517411 12.830374 12:34:12 08/20/2024 58 75.190062 5.311918 80.50198 37.33367 26.362258 12.73237 12:35:12 08/20/2024 59 76.48263 5.444733 81.927363 37.492204 25.793041 12.705801 12:36:12 08/20/2024 60 76.211669 5.417231 81.6289 37.313122 26.054655 12.673216 12:37:12 08/20/2024 AVG 75.50 5.43 80.93 37.39 26.14 12.84 ppm@15% O2 38.51 17.79 12.44 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.52 1.50 0.15 0.42 0.16 0.46 FTIR Measurements E170346 (15830) Calculated Emission Levels XCL Resources Crozier #2-1A-32 Run 3 Record Date EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 12 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 3.74 1392 1.50 1.934 Average O2 8.5 (% dry)A 2 1.26 3.77 1.942 Average CO2 7.5 (% dry)A 3 2.33 3.79 1.947 Average N2 + CO 84.0 (% dry)A 4 3.88 3.84 1.960 Dry Molecular Weight 29.54 lb/lbmol A 5 8.12 3.89 1.972 Wet Molecular Weight 28.06 lb/lbmol A 6 9.67 3.86 1.965 EPA REFERENCE METHOD 320 A 7 10.74 3.84 1.960 Barometric Pressure 24.97 in Hg A 8 11.50 3.82 1.954 Moisture Content 12.84 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 80.93 ppm A 11 Calculated NOx Mass Output 1.50 lbs/hr A 12 Calculated NOx Output 0.52 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 37.39 ppm A 15 Calculated CO Mass Output 0.42 lbs/hr A 16 Calculated CO Output 0.15 g/bhp-hr B 1 0.50 3.76 1392 1.50 1.939 EPA REFERENCE METHOD 320 B 2 1.26 3.80 1.949 Average Analyzer NMNEHC Level 26.14 ppm B 3 2.33 3.84 1.960 Calculated NMNEHC Mass Output 0.46 lbs/hr B 4 3.88 3.88 1.970 Calculated NMNEHC Output 0.16 g/bhp-hr B 5 8.12 3.93 1.982 LOAD APPROXIMATION B 6 9.67 3.90 1.975 Estimated Engine Load 1309.0 BHP B 7 10.74 3.88 1.970 B 8 11.50 3.85 1.962 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 3.8 1392 1.5 1.959 Average Stack Gas Velocity 197.83 ft/sec Average Dry Flowrate 2583.51 dscfm TEST RUN # 3 APPENDIX B Date Time NO 191C span NO2 191C span H2O% (high) 191C Formaldehyde 191C Ethylene 191C TE span Propane 191C span Acetaldehyde 191C span CO ppm 191C (1of2) spanCO ppm Dry CO2% 191C NOx Wet NOx Dry NM NE HC C3 Temp ( C )Pressure (atm)8/20/2024 9:13:45 -0.097806 -0.002362 0.00558 0.016895 0.396347 -0.357861 0.236533 0.039691 0.039693 -0.003081 -0.100168 -0.100173 0.004593 191.016251 1.0628688/20/2024 9:13:52 0.041462 -0.019805 0.003764 -0.00101 0.035456 -0.003842 0.193304 0.05924 0.059242 -0.003322 0.021657 0.021658 0.010666 191.016251 1.0649828/20/2024 9:14:00 0.066059 -0.119794 0.000438 0.030825 0.431063 0.192686 0.416775 -0.023073 -0.023073 0.004883 -0.053735 -0.053736 0.006328 191.016251 1.040785 8/20/2024 9:14:07 -0.071966 -0.008698 0.004086 0.025764 0.679162 0.301239 0.420139 -0.017857 -0.017858 0.00038 -0.080664 -0.080667 0.006006 191.008987 1.0093468/20/2024 9:14:45 0 0 0 0 0 0 0 0 0 0 0 0 0 190.939957 1.016932 8/20/2024 9:14:59 0.024643 0.033816 -0.001284 -0.092055 0.221403 -0.277487 -0.251059 0.009915 0.009914 -0.001544 0.058459 0.058458 -0.001662 190.980759 1.0211718/20/2024 9:15:06 -0.150054 0.031214 -0.002651 -0.005501 0.094154 -0.528129 0.059123 0.011247 0.011246 0.004749 -0.11884 -0.118837 0.013361 191.035324 1.0182048/20/2024 9:15:14 -0.017569 -0.009342 0.001509 0.078361 0.278685 0.199455 -0.140856 -0.027422 -0.027422 -0.000159 -0.026911 -0.026911 0.006043 191.035324 1.0227618/20/2024 9:15:21 -0.056719 0.005163 -0.000913 -0.003267 0.46832 0.008928 -0.153855 0.034409 0.034409 0.008466 -0.051556 -0.051555 0.010237 191.034531 1.0218768/20/2024 9:15:29 -0.000818 0.028905 0.001643 -0.022902 0.085612 -0.319415 -0.178351 -0.023504 -0.023505 -0.00075 0.028087 0.028088 0.00025 191.006256 1.0121148/20/2024 9:15:36 -0.0852 0.006695 -0.003934 0.059021 0.0849 -0.09761 -0.120951 -0.056489 -0.056487 0.003412 -0.078505 -0.078502 0.006048 190.953583 1.0080628/20/2024 9:15:44 -0.102694 0.005054 -0.001521 -0.010152 0.441042 -0.048508 0.119672 0.007315 0.007315 0.004461 -0.09764 -0.097638 -0.000686 190.952667 1.015777 8/20/2024 9:15:51 -0.08257 0.001324 0.000276 0.035738 0.17429 -0.224633 -0.042618 -0.029919 -0.029919 0.010366 -0.081246 -0.081246 0.003836 190.952667 1.0002978/20/2024 9:15:59 -0.015095 -0.009003 -0.002746 0.102018 -0.216593 0.011537 0.317615 -0.02673 -0.02673 -0.001233 -0.024098 -0.024098 0.004028 190.952667 1.006828 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/20/2024 9:19:07 496.901005 509.330411 493.852478 191.061279 1.014014 8/20/2024 9:22:29 98.848511 191.016251 1.0068838/20/2024 9:19:14 505.201018 517.687402 502.462885 191.009888 1.008472 8/20/2024 9:22:36 98.289673 191.016251 1.017053 8/20/2024 9:19:22 503.889755 516.940418 501.442541 190.984467 1.008277 8/20/2024 9:22:44 98.779241 191.016251 1.0151868/20/2024 9:19:29 504.174968 516.968146 502.482211 190.984467 1.00495 8/20/2024 9:22:51 99.61024 191.016251 1.0098668/20/2024 9:19:37 505.22452 518.133055 504.886397 190.984467 1.00182 8/20/2024 9:22:59 98.595582 191.016251 1.0150778/20/2024 9:19:44 501.552084 514.168059 498.435559 190.982651 1.018178 8/20/2024 9:23:06 98.441094 191.013519 1.0191878/20/2024 9:19:52 499.169812 512.645658 497.922096 190.977188 1.01124 8/20/2024 9:23:14 99.449841 190.998077 1.0109998/20/2024 9:19:59 497.158612 510.531661 496.287208 190.950287 1.014234 8/20/2024 9:23:21 99.87769 190.955856 1.0051388/20/2024 9:20:07 505.354337 518.792416 506.348014 190.915436 0.998593 8/20/2024 9:23:29 99.04492 190.939957 1.014237 8/20/2024 9:20:14 499.609831 513.052212 500.023837 190.908173 1.013852 8/20/2024 9:23:36 100.223363 190.939957 1.006233 Date Time NO2 191C span Temp ( C )Pressure (atm)8/20/2024 9:20:50 141.304252 191.00354 1.0072118/20/2024 9:20:58 144.241166 191.00354 1.001098/20/2024 9:21:05 143.901239 191.00354 1.010006 8/20/2024 9:21:13 144.052047 191.00354 1.0106318/20/2024 9:21:20 146.030949 191.00354 1.0011258/20/2024 9:21:28 145.907215 191.00354 1.0043648/20/2024 9:21:35 147.799893 191.00354 0.9953188/20/2024 9:21:43 146.043227 190.998993 1.0096058/20/2024 9:21:50 145.461986 191.064392 1.0129638/20/2024 9:21:58 147.118202 191.054398 0.999124 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/20/2024 9:24:05 242.897427 284.536428 215.023299 191.028961 0.988301 8/20/2024 9:25:41 47.915781 190.952667 0.9895318/20/2024 9:24:12 434.854944 454.104831 429.919591 191.028961 1.000656 8/20/2024 9:25:49 97.281189 190.952667 0.9955398/20/2024 9:24:20 500.139869 513.059541 497.879844 191.028961 1.00618 8/20/2024 9:25:56 94.452109 190.952667 0.998148/20/2024 9:24:27 501.404915 514.361815 500.823671 191.028961 1.009854 8/20/2024 9:26:04 93.549909 190.978104 0.988423 8/20/2024 9:24:35 498.108587 511.716371 497.110968 191.028961 1.016595 8/20/2024 9:26:11 98.710747 191.033508 0.9878498/20/2024 9:24:42 503.548539 515.876365 501.631675 191.018066 1.010224 8/20/2024 9:26:19 98.650054 191.048035 0.988936 8/20/2024 9:24:50 505.835842 518.992406 505.517214 190.957443 1.003487 8/20/2024 9:26:27 100.662606 191.048035 0.9784568/20/2024 9:24:57 502.375635 515.166277 503.378731 190.952667 1.010003 8/20/2024 9:26:34 99.973926 191.048035 0.9821568/20/2024 9:25:05 506.910842 519.641365 507.090937 190.952667 1.001489 8/20/2024 9:26:42 99.037483 191.048035 0.9932358/20/2024 9:25:12 502.273423 515.1527 503.808467 190.952667 1.009074 8/20/2024 9:26:49 100.709898 191.047134 0.980902 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Ethylene 191C TE Temp ( C )Pressure (atm)8/20/2024 9:27:12 0.065216 0.00487 -0.166264 0.138735 190.965393 0.995928/20/2024 9:27:19 0.028027 -0.02531 -0.032311 0.1449 190.965393 1.0080828/20/2024 9:27:27 0.06229 0.168767 0.003159 0.191359 190.965393 1.0074728/20/2024 9:27:34 0.055672 0.041522 -0.318545 0.017343 190.965393 1.011658/20/2024 9:27:42 0.098184 -0.044913 -0.348985 -0.019551 190.965393 1.016709 8/20/2024 9:27:49 0.08688 0.119537 -0.330735 -0.016211 190.965393 1.0239018/20/2024 9:27:57 0.034959 0.025954 -0.011602 0.391597 190.965393 1.019629 8/20/2024 9:28:04 0.106128 0.092281 -0.074698 0.622331 190.965393 1.021023 Raw Calibration Data BACKGROUND / PRE DIRECT ZERO PRE DIRECT CAL NO2 CAL PRE SYSTEM CAL PRE SYSTEM ZERO Date Time CO2% 191C Propane 191C span Temp ( C )Pressure (atm)8/20/2024 9:30:54 6.687515 15.079002 190.997177 0.9977118/20/2024 9:31:01 6.701306 15.136873 190.997177 0.9970228/20/2024 9:31:09 6.668727 14.892286 190.997177 1.0013878/20/2024 9:31:16 6.649035 14.758155 190.989914 0.9980518/20/2024 9:31:24 6.684902 14.600127 190.944717 0.997797 8/20/2024 9:32:17 6.656542 15.10525 190.93544 0.9967338/20/2024 9:32:24 4.33115 58.564225 191.016251 1.015837 8/20/2024 9:32:32 3.438666 225.434797 191.016251 1.0078358/20/2024 9:32:39 3.525064 227.514395 191.016251 1.0074758/20/2024 9:32:47 5.811519 73.386166 191.016251 1.0016488/20/2024 9:32:54 6.161678 53.552959 191.016251 0.99928/20/2024 9:33:02 6.11836 54.950923 191.016251 1.0026388/20/2024 9:33:09 5.952194 63.687997 191.016251 1.006268/20/2024 9:33:17 6.008086 63.261522 191.016251 1.000963 8/20/2024 9:33:24 6.036228 60.085077 191.016251 1.00168/20/2024 9:33:54 6.031384 60.012398 191.016617 0.998945 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/20/2024 12:49:22 497.378394 510.779532 496.787935 190.984467 1.009347 8/20/2024 12:47:44 99.000564 191.064468 1.0101358/20/2024 12:49:30 506.029602 517.11537 502.823864 190.986282 1.018054 8/20/2024 12:47:52 99.723794 191.026245 1.009599 8/20/2024 12:49:37 507.718275 518.221392 503.559023 191.076202 1.032358 8/20/2024 12:47:59 98.770499 190.984467 1.0063038/20/2024 12:49:45 508.473707 518.706341 505.185722 191.079834 1.034931 8/20/2024 12:48:07 99.247157 190.984467 1.0173288/20/2024 12:49:52 507.511425 518.434767 505.466155 191.079834 1.028374 8/20/2024 12:48:14 98.97554 190.984467 1.0135978/20/2024 12:50:00 507.3476 518.597044 506.922777 191.079834 1.027327 8/20/2024 12:48:22 100.751809 190.984467 1.0009428/20/2024 12:50:07 507.344697 518.731052 505.313613 191.075851 1.026187 8/20/2024 12:48:29 98.960405 190.984467 1.0135038/20/2024 12:50:15 504.121255 516.316491 506.587904 191.048035 1.017266 8/20/2024 12:48:37 99.93711 190.984467 1.0023228/20/2024 12:50:22 504.149268 516.244648 505.355327 191.00354 1.016417 8/20/2024 12:48:44 98.493988 190.984467 1.013196 8/20/2024 12:50:30 501.52782 514.910385 505.76621 191.00354 1.010557 8/20/2024 12:48:52 98.727034 190.984467 1.014577 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/20/2024 12:47:59 -0.151104 -0.115031 -0.234533 190.984467 1.006303 8/20/2024 12:51:16 -0.271132 190.998993 1.0078818/20/2024 12:48:07 -0.146633 -0.089611 -0.336462 190.984467 1.017328 8/20/2024 12:51:23 -0.295041 190.997177 1.0117248/20/2024 12:48:14 -0.14059 -0.081248 -0.237514 190.984467 1.013597 8/20/2024 12:51:31 -0.272851 190.981277 1.006659 8/20/2024 12:48:22 -0.093199 -0.029864 -0.455356 190.984467 1.000942 8/20/2024 12:51:38 -0.559317 190.939041 1.0120318/20/2024 12:48:29 -0.068537 0.046544 -0.13233 190.984467 1.013503 8/20/2024 12:51:46 -0.383514 190.920883 1.0078788/20/2024 12:48:37 -0.108609 -0.023739 -0.391875 190.984467 1.002322 8/20/2024 12:51:53 -0.229959 190.920883 1.0050638/20/2024 12:48:44 -0.192963 0.00362 -0.204068 190.984467 1.013196 8/20/2024 12:52:01 -0.23684 190.920883 1.0083088/20/2024 12:48:52 -0.183008 0.085465 -0.246937 190.984467 1.014577 8/20/2024 12:52:08 -0.288614 190.920883 1.018519 POST SYSTEM ZERO SAMPLE SPIKE RECOVERY POST SYSTEM CAL PRE TEST 1 497.5 6.7 14.9 6.1 59.3 0.093 86.5% Sensor Analyzer Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Error (%)Error (%) NOx 513.1 514.5 0.0 -0.28 -0.01 CO 499.6 501.8 0.0 -0.44 0.00 Propane 500.0 497.5 -0.2 0.51 -0.03 Ethylene 100.2 99.76 0.2 0.46 0.23 Sensor System Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Recovery (%)Error (%) NOx 515.2 514.5 0.0 0.13 0.01 CO 502.3 501.8 0.1 0.09 0.01 Propane 503.8 497.5 -0.2 1.27 -0.03 Ethylene*100.7 99.76 0.1 0.95 0.12 Sensor System Cal Zero Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Recovery (%)Error (%)Drift Error (%)Drift Error (%) NOx 514.9 514.5 0.0 0.08 -0.01 0.05 0.02 CO 501.5 501.8 -0.1 -0.05 -0.03 0.15 0.04 Propane 505.8 497.5 -0.3 1.66 -0.06 0.39 0.02 Ethylene*98.7 99.76 -0.4 -1.04 -0.36 1.99 0.48 *CTS Scans are conducted with Ethylene through the sample line. % Recovery Propane PRE DIRECT CAL FTIR QA/QC SUMMARY SAMPLE RECOVERY CALCULATIONS Period Spike #Concentration of Propane Cylinder Stack CO2 Concentration Stack Propane Concentration Stack + Spike CO2 Concentration Stack + Propane Concentration DF Calculated POST SYSTEM CAL PRE SYSTEM CAL XCL – Crozier #2-1A-32 8-20-24 XCL – Crozier #2-1A-32 8-20-24 XCL – Crozier #2-1A-32 8-20-24 Spectral Fit Run 1 Spectral Fit Run 2 Spectral Fit Run 3 Analysis Validation Report Sample Filename: C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000142.LAB Filename for noise: C:\OLT\Data\Golden Spectrum 10-31-23\GOLDEN SPECTRUM 10-31-23_000004.LAB Interferences Filenames: C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000068.LAB C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000069.LAB C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000070.LAB C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000071.LAB C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000072.LAB C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000073.LAB C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000074.LAB C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000075.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 64.64 2.04 -0.24 0.32 2.77 2.77 -1.29 --0-2795 1.03 Good NO2 191C 4.27 0.33 -0.03 0.03 0.35 0.35 -0.2 --0-488 1.01 Good N2O 191C -0.02 0.24 0.07 0.03 0.03 0.28 0.28 0.08 0.22 0.01 0.02 0-200 -Close to DL NH3 TE 191C -5.5 27.96 3.03 4.14 7.06 47.74 47.74 3.55 23.89 0.52 1.01 0-2995 -Close to DL H2O% (HIGH) 191C13.36 0.26 -0.02 0.03 0.41 0.41 -0.27 --0-40 -Good FORMALDEHYDE 191C11.78 0.73 -0.24 0.27 0.84 0.84 -0.27 --0-69 -Good FORMIC ACID 191C TE0.81 6.58 0.95 1.56 1.83 7.71 7.71 0.96 5.06 0.02 0.32 0-466 -Close to DL CH4 2900 CM-1 191C431.46 9.75 -1.64 2.38 19.62 19.62 -8.63 --0-3143 0.97 Good PROPANE 191C 14.32 0.84 -0.22 0.27 1.01 1.01 -0.35 --0-4976 0.95 Good PROPYLENE 191C TE0.54 7.4 0.94 1.57 1.86 8.75 8.75 1.63 5.83 0.69 0.31 0-194 -Close to DL ETHANE 191C 36.17 1.9 -0.55 0.85 2.97 2.97 -0.78 --0-1004 -Good ETHYLENE 191C TE8.36 14.86 9.27 2.07 2.55 18.33 18.33 10.55 12.61 1.28 3.09 0-900 -Close to DL CO PPM 191C (1OF2)32.22 1.22 -0.25 0.55 2.6 2.6 -0.64 --0-5010 1.01 Good CO2% 191C 6.54 0.14 -0.01 0.02 0.19 0.19 -0.13 --0-23 -Good CO% 191C (2OF2)0 0 0 0 0 0 0 0 0 0 0 0-8 -Close to DL ACETALDEHYDE 191C-0.39 1.64 0.87 0.63 0.81 2.11 2.11 0.88 1.02 0.01 0.29 0-186 1 Close to DL ACETYLENE 191C0.01 2.76 0.27 0.79 1.05 3.64 3.64 0.27 2.01 0.01 0.09 0-1016 -Close to DL SO2 191C 2.7 3.35 1.78 0.26 0.32 4.09 4.09 2.15 3.05 0.38 0.59 0-964 1.02 Close to DL HEXANE 191C 1.06 0.57 1.21 0.13 0.18 0.77 0.77 1.38 1.38 0.17 0.4 0-1000 -Close to DL Analysis Validation Report Sample Filename: C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000203.LAB Filename for noise: C:\OLT\Data\Golden Spectrum 10-31-23\GOLDEN SPECTRUM 10-31-23_000004.LAB Interferences Filenames: C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000068.LAB C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000069.LAB C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000070.LAB C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000071.LAB C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000072.LAB C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000073.LAB C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000074.LAB C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000075.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 65.04 2.06 -0.24 0.32 2.8 2.8 -1.3 --0-2795 1.03 Good NO2 191C 4.71 0.38 -0.03 0.03 0.4 0.4 -0.24 --0-488 1.01 Good N2O 191C 0.01 0.26 0.07 0.03 0.03 0.29 0.29 0.08 0.23 0.01 0.02 0-200 -Close to DL NH3 TE 191C -6.22 25.94 3.03 4.14 7.06 44.27 44.27 3.55 21.83 0.52 1.01 0-2995 -Close to DL H2O% (HIGH) 191C12.65 0.26 -0.02 0.03 0.42 0.42 -0.25 --0-40 -Good FORMALDEHYDE 191C11.87 0.74 -0.24 0.27 0.85 0.85 -0.28 --0-69 -Good FORMIC ACID 191C TE1.05 6.59 0.95 1.56 1.83 7.72 7.72 0.96 5.06 0.02 0.32 0-466 -Close to DL CH4 2900 CM-1 191C428.15 9.92 -1.64 2.38 19.97 19.97 -8.56 --0-3143 0.97 Good PROPANE 191C 14.96 0.85 -0.22 0.27 1.02 1.02 -0.35 --0-4976 0.95 Good PROPYLENE 191C TE0.63 7.53 0.94 1.57 1.86 8.9 8.9 1.63 5.96 0.69 0.31 0-194 -Close to DL ETHANE 191C 36.82 1.97 -0.55 0.85 3.07 3.07 -0.81 --0-1004 -Good ETHYLENE 191C TE9.59 14.81 9.27 2.07 2.55 18.27 18.27 10.55 12.52 1.28 3.09 0-900 -Close to DL CO PPM 191C (1OF2)32.54 1.31 -0.25 0.55 2.79 2.79 -0.66 --0-5010 1.01 Good CO2% 191C 6.58 0.14 -0.01 0.02 0.2 0.2 -0.13 --0-23 -Good CO% 191C (2OF2)0 0 0 0 0 0 0 0 0 0 0 0-8 -Close to DL ACETALDEHYDE 191C-0.19 1.7 0.87 0.63 0.81 2.18 2.18 0.88 1.07 0.01 0.29 0-186 1 Close to DL ACETYLENE 191C0.19 2.77 0.27 0.79 1.05 3.66 3.66 0.27 2.01 0.01 0.09 0-1016 -Close to DL SO2 191C 2.69 3.1 1.78 0.26 0.32 3.78 3.78 2.15 2.8 0.38 0.59 0-964 1.02 Close to DL HEXANE 191C 1.1 0.57 1.21 0.13 0.18 0.77 0.77 1.38 1.38 0.17 0.4 0-1000 -Close to DL Analysis Validation Report Sample Filename: C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000264.LAB Filename for noise: C:\OLT\Data\Golden Spectrum 10-31-23\GOLDEN SPECTRUM 10-31-23_000004.LAB Interferences Filenames: C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000068.LAB C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000069.LAB C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000070.LAB C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000071.LAB C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000072.LAB C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000073.LAB C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000074.LAB C:\OLT\Data\XCL Resources\Crozier 0447 8-20-24\XCL CROZIER 0447 8-20-24_000075.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 65.49 1.99 -0.24 0.32 2.7 2.7 -1.31 --0-2795 1.03 Good NO2 191C 4.7 0.36 -0.03 0.03 0.38 0.38 -0.22 --0-488 1.01 Good N2O 191C 0.02 0.24 0.07 0.03 0.03 0.27 0.27 0.08 0.22 0.01 0.02 0-200 -Close to DL NH3 TE 191C -6.08 25 3.03 4.14 7.06 42.68 42.68 3.55 20.91 0.52 1.01 0-2995 -Close to DL H2O% (HIGH) 191C12.8 0.25 -0.02 0.03 0.4 0.4 -0.26 --0-40 -Good FORMALDEHYDE 191C11.85 0.74 -0.24 0.27 0.85 0.85 -0.28 --0-69 -Good FORMIC ACID 191C TE0.99 6.62 0.95 1.56 1.83 7.75 7.75 0.96 5.09 0.02 0.32 0-466 -Close to DL CH4 2900 CM-1 191C429.01 9.71 -1.64 2.38 19.55 19.55 -8.58 --0-3143 0.97 Good PROPANE 191C 14.82 0.85 -0.22 0.27 1.01 1.01 -0.35 --0-4976 0.95 Good PROPYLENE 191C TE0.81 7.48 0.94 1.57 1.86 8.85 8.85 1.63 5.91 0.69 0.31 0-194 -Close to DL ETHANE 191C 37.26 1.97 -0.55 0.85 3.07 3.07 -0.81 --0-1004 -Good ETHYLENE 191C TE9.74 14.52 9.27 2.07 2.55 17.91 17.91 10.55 12.22 1.28 3.09 0-900 -Close to DL CO PPM 191C (1OF2)32.5 1.27 -0.25 0.55 2.7 2.7 -0.65 --0-5010 1.01 Good CO2% 191C 6.58 0.14 -0.01 0.02 0.19 0.19 -0.13 --0-23 -Good CO% 191C (2OF2)0 0 0 0 0 0 0 0 0 0 0 0-8 -Close to DL ACETALDEHYDE 191C-0.32 1.71 0.87 0.63 0.81 2.19 2.19 0.88 1.08 0.01 0.29 0-186 1 Close to DL ACETYLENE 191C0.26 2.68 0.27 0.79 1.05 3.54 3.54 0.27 1.93 0.01 0.09 0-1016 -Close to DL SO2 191C 2.68 3.16 1.78 0.26 0.32 3.85 3.85 2.15 2.86 0.38 0.59 0-964 1.02 Close to DL HEXANE 191C 1.12 0.57 1.21 0.13 0.18 0.77 0.77 1.38 1.38 0.17 0.4 0-1000 -Close to DL EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 12 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 3.74 1392 1.50 1.934 Average O2 8.5 (% dry)A 2 1.05 3.77 1.942 Average CO2 7.5 (% dry)A 3 1.94 3.79 1.947 Average N2 + CO 84.0 (% dry)A 4 3.23 3.84 1.960 Dry Molecular Weight 29.54 lb/lbmol A 5 6.77 3.89 1.972 Wet Molecular Weight 28.06 lb/lbmol A 6 8.06 3.86 1.965 EPA REFERENCE METHOD 320 A 7 8.95 3.84 1.960 Barometric Pressure 24.97 in Hg A 8 9.50 3.82 1.954 Moisture Content 12.84 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 80.93 ppm A 11 Calculated NOx Mass Output 1.50 lbs/hr A 12 Calculated NOx Output 0.52 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 37.39 ppm A 15 Calculated CO Mass Output 0.42 lbs/hr A 16 Calculated CO Output 0.15 g/bhp-hr B 1 0.50 3.76 1392 1.50 1.939 EPA REFERENCE METHOD 320 B 2 1.05 3.80 1.949 Average Analyzer NMNEHC Level 26.14 ppm B 3 1.94 3.84 1.960 Calculated NMNEHC Mass Output 0.46 lbs/hr B 4 3.23 3.88 1.970 Calculated NMNEHC Output 0.16 g/bhp-hr B 5 6.77 3.93 1.982 LOAD APPROXIMATION B 6 8.06 3.90 1.975 Estimated Engine Load 1309.0 BHP B 7 8.95 3.88 1.970 B 8 9.50 3.85 1.962 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 3.8 1392 1.5 1.959 Average Stack Gas Velocity 197.83 ft/sec Average Dry Flowrate 2583.51 dscfm TEST RUN # 3 APPENDIX C LOW NOX UPGRADE CONTINUOUS HPG IMPCO WITH AIR FUEL RATIO CONTROL Field Gas 40.0-45.0 62.1 1027 5819 80 1340 bhp@1400rpm RATING STRATEGY: RATING LEVEL: FUEL SYSTEM: SITE CONDITIONS: FUEL: FUEL PRESSURE RANGE(psig): (See note 1) FUEL METHANE NUMBER: FUEL LHV (Btu/scf): ALTITUDE(ft): INLET AIR TEMPERATURE(°F): STANDARD RATED POWER: ENGINE SPEED (rpm):1368 COMPRESSION RATIO:8 AFTERCOOLER TYPE:SCAC AFTERCOOLER - STAGE 2 INLET (°F):130 AFTERCOOLER - STAGE 1 INLET (°F):201 JACKET WATER OUTLET (°F):210 ASPIRATION:TA COOLING SYSTEM:JW+OC+1AC, 2AC CONTROL SYSTEM:ADEM3 EXHAUST MANIFOLD:ASWC COMBUSTION:LOW EMISSION NOx EMISSION LEVEL (g/bhp-hr NOx):1.0 SET POINT TIMING:27 RATING NOTES LOAD 100%100%75%51% ENGINE POWER (WITHOUT FAN)(2)bhp 1309 1309 982 670 INLET AIR TEMPERATURE °F 80 80 80 80 MAXIMUM RATING SITE RATING AT MAXIMUM INLET AIR TEMPERATURE ENGINE DATA FUEL CONSUMPTION (LHV)(3)Btu/bhp-hr 8156 8156 8529 9100 FUEL CONSUMPTION (HHV)(3)Btu/bhp-hr 9012 9012 9424 10055 AIR FLOW (@inlet air temp, 14.7 psia)(WET)(4)(5)ft3/min 3029 3029 2332 1741 AIR FLOW (WET)(4)(5)lb/hr 13358 13358 10284 7676 FUEL FLOW (60°F, 14.7 psia)scfm 173 173 136 99 INLET MANIFOLD PRESSURE (6)psi(abs)34.2 34.2 28.3 21.6 EXHAUST TEMPERATURE - ENGINE OUTLET (7)°F 992 992 999 1001 EXHAUST GAS FLOW (@engine outlet temp, 14.5 psia)(WET)(5)(8)ft3/min 8799 8799 6812 5083 EXHAUST GAS MASS FLOW (WET)(5)(8)lb/hr 13872 13872 10687 7970 EMISSIONS DATA - ENGINE OUT NOx (as NO2)(9)(10)g/bhp-hr 1.00 1.00 1.00 1.00 CO (9)(10)g/bhp-hr 3.58 3.58 3.84 4.26 THC (mol. wt. of 15.84)(9)(10)g/bhp-hr 3.01 3.01 3.46 3.69 NMHC (mol. wt. of 15.84)(9)(10)g/bhp-hr 0.78 0.78 0.90 0.96 NMNEHC (VOCs) (mol. wt. of 15.84)(9)(10)(11)g/bhp-hr 0.53 0.53 0.60 0.64 HCHO (Formaldehyde)(9)(10)g/bhp-hr 0.41 0.41 0.27 0.35 CO2 (9)(10)g/bhp-hr 544 544 587 656 EXHAUST OXYGEN (9)(12)% DRY 8.0 8.0 7.8 7.6 HEAT REJECTION HEAT REJ. TO JACKET WATER (JW)(13)Btu/min 40938 40938 35115 27375 HEAT REJ. TO ATMOSPHERE (13)Btu/min 5192 5192 4327 3502 HEAT REJ. TO LUBE OIL (OC)(13)Btu/min 6105 6105 5237 4083 HEAT REJ. TO A/C - STAGE 1 (1AC)(13)(14)Btu/min 10658 10658 6126 2672 HEAT REJ. TO A/C - STAGE 2 (2AC)(13)(14)Btu/min 4125 4125 3391 2480 COOLING SYSTEM SIZING CRITERIA TOTAL JACKET WATER CIRCUIT (JW+OC+1AC)(14)(15)Btu/min 63550 TOTAL AFTERCOOLER CIRCUIT (2AC)(14)(15)Btu/min 4331 A cooling system safety factor of 0% has been added to the cooling system sizing criteria. CONDITIONS AND DEFINITIONS Engine rating obtained and presented in accordance with ISO 3046/1, adjusted for fuel, site altitude and site inlet air temperature. 100% rating at maximum inlet air temperature is the maximum engine capability for the specified fuel at site altitude and maximum site inlet air temperature. Maximum rating is the maximum capability at the specified aftercooler inlet temperature for the specified fuel at site altitude and reduced inlet air temperature. Refer to product O&M manual for details on additional lower load capability. No overload permitted at rating shown. For notes information consult page three. GAS COMPRESSION APPLICATION Page 1 of 4Data generated by GERP Web Version 2.11.0.24 Ref. Dta Set DM9401-06-001, Printed 23Aug2024 GAS ENGINE SITE SPECIFIC TECHNICAL DATAG3516XCL - Crozier #2-1A-32 APPENDIX D Test Run Flowrate dscfm Approx. BHP Avg O2 % NOx ppmvd NOx g/bhp-hr NOx lbs/hr CO ppmvd CO g/bhp-hr CO lbs/hr NMNEHC ppmvd NMNEHC g/bhp-hr NMNEHC lbs/hr Moisture Content % 1 2559.80 1309.0 8.5 79.74 0.51 1.46 37.32 0.14 0.42 25.86 0.16 0.45 12.91 2 2566.70 1309.0 8.5 80.28 0.51 1.47 37.32 0.14 0.42 25.82 0.16 0.45 12.96 3 2583.51 1309.0 8.5 80.93 0.52 1.50 37.39 0.15 0.42 26.14 0.16 0.46 12.84 1309.0 8.5 80.32 0.51 1.48 37.34 0.15 0.42 25.94 0.16 0.46 12.90 Summary Average Levels Example Calculations: XCL Resources, Crozier #2-1A-32, E170346 (15830) The following is a step-by-step calculation for the first test run conducted on the Crozier #2-1A- 32 E170346 (15830). Test Parameters • Stack Diameter = 12 inches • Traverse Points = 16 • Ports = 2 • Barometric Pressure = 24.97 in Hg • Average O2 = 8.5% • Average CO2 = 7.5% • Load Approximation = 1309.0 bhp • Moisture Content = 12.91% EPA 40 CFR 60(A) Methods 1-3: Determination of Stack Gas Velocity and Flow Rate Dry Molecular Weight (lb/lbmol) = (0.44 * %CO2) + (0.32 * %O2) + ((0.28 * (%N2 + %CO)) Where: %CO2 – Carbon Dioxide Content Of The Gas = 7.5% %O2 – Oxygen Content Of The Gas = 8.5% %N2 – Nitrogen Content Of The Gas %CO – Carbon Monoxide Content Of The Gas (%N2 +%CO) = (100 - %O2 - %CO2) = (100 – 8.5 – 7.5) = 84.0% Dry = (0.44 * %CO2) + (0.32 * %O2) + ((0.28 * (%N2 + %CO)) = (0.44 * 7.5) + (0.32 * 8.5) + (0.28 * 84.0) = 29.54 lb/lbmol Wet Molecular Weight (lb/lbmol) = MD * (1-BWS) + (18) * BWS Where: MD – Molecular Weight Of The Dry Gas (lb/lbmol) = 29.54 lb/lbmol BWS – Moisture Content Of The Gas (%/100) = 12.91% = MD * (1-BWS) + (18) * BWS = 29.54 * (1 – (12.91/ 100)) + (18 * (12.91/ 100)) = 28.05 lb/lbmol Average Stack Gas Velocity (ft/sec) = Cp * (85.49) * ∆PAVG * (TS / (((PS / 13.6) + PB) * MA)) Where: CP – Pitot tube constant (unitless) = 0.84 ∆PAVG – Average square root of the stack gas pitot DP (inches water) = 1.941 in H2O TS – Average stack temperature (R) = 1391 R PB – Barometric pressure (in Hg) = 24.97 in Hg PS – Stack pressure relative to barometric pressure (inches water) = 1.5 in H2O MA – Molecular weight of the wet gas (lb/lbmol) = 28.05 lb/lbmol = Cp * (85.49) * ∆PAVG * (TS / (((PS / 13.6) + PB) * MA)) = 0.84 * (85.49) * 1.941 * ( 1391 / (((1.5/ 13.6) + 24.97) * 28.05)) = 196.05 ft/sec Average Dry Flowrate (dscfm) = 60 * (1-BWS) * VS * * (((DS / 2) / 12))2)* TSTD / TS * (PB + (PS / 13.6)) / 29.92 Where: DS – Diameter of the stack (inches) = 12 inches BWS – Moisture content of the gas (%) = 12.91% TSTD – Standard temperature (528R) TS – Average stack temperature (R) = 1391 R PB – Barometric pressure (in Hg) = 24.97 in Hg PS – Stack pressure relative to barometric pressure (inches water) = 1.5 in H2O VS– Average Stack gas velocity (ft/sec) = 196.05 ft/sec = 60 * (1-BWS) * VS * * (((DS / 2) / 12))2)* TSTD / TS * (PB + (PS / 13.6)) / 29.92 = 60 * (1 - (12.91/ 100)) * 196.05 * * (((12 / 2) / 12))2) * 528 / 1391 * (24.97 + (1.5 / 13.6)) / 29.92 = 2559.80 dscfm Conversion of Dry Flowrate to m3/hr = Q * 60 * 2.83168*10 -2 Where: Q – Volumetric Flowrate = 2559.80 dscfm 2.83168*10 -2 – Conversion factor for cubic feet to cubic meter 60 – Minutes in an hour = Q * 60 * 2.83168*10 -2 = 2559.80 *60 * 2.83168*10 -2 = 4349.11 m3/hr ASTM D 6348-03: Determination of NOx, CO and VOC Emissions From Stationary Sources NOx Emission Rate (g/Bhp-hr) = (Cd * 1.912*10 -3 * Q * T) / HP-hr Where: Cd – Measured NOx concentration in ppm = 79.74 ppm 1.92*10 -3 - Conversion constant for ppm to g/m3 NOx Q – Volumetric Flowrate = 4349.11 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 1309.0 Bhp = (Cd * 1.912*10 -3 * Q * T) / HP-hr = (79.74 * 1.912*10 -3 * 4349.11 * 1) / 1309.0 = 0.51 g/Bhp-hr NOx Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.51 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 1309.0 Bhp = g/Bhp-hr / 454 * Bhp = 0.51 / 454 * 1309.0 = 1.46 lbs/hr CO Emission Rate (g/Bhp-hr) = (Cd * 1.164*10 -3 * Q * T) / HP-hr Where: Cd – Measured CO concentration in ppm = 37.32 ppm 1.164*10 -3 - Conversion constant for ppm to g/m3 CO Q – Volumetric Flowrate = 4349.11 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 1309.0 Bhp = (Cd * 1.164*10 -3 * Q * T) / HP-hr = (37.32 * 1.164*10 -3 * 4349.11 * 1) / 1309.0 = 0.14 g/Bhp-hr CO Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.14 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 1309.0 Bhp = g/Bhp-hr / 454 * Bhp = 0.14 / 454 * 1309.0 = 0.42 lbs/hr VOC Emission Rate (g/Bhp-hr) = (Cd * 1.833*10 -3 * Q * T) / HP-hr Where: Cd – Measured VOC concentration in ppm = 25.86 ppm 1.833*10 -3 - Conversion constant for ppm to g/m3 VOC Q – Volumetric Flowrate = 4349.11 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 1309.0 Bhp = (Cd * 1.833*10 -3 * Q * T) / HP-hr = (25.86 * 1.833*10 -3 * 4349.11 * 1) / 1309.0 = 0.16 g/Bhp-hr VOC Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.16 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 1309.0 Bhp = g/Bhp-hr / 454 * Bhp = 0.16 / 454 * 1309.0 = 0.45 lbs/hr APPENDIX E FTIR Engine Test Sheet Company Name vn. Location / Unit 1.0. err>~ ;JZ-T =tt=;;.. -1A -:-~ A Type of Test Completed 3x1hr /1/;:1/ David Martinez Field Technician (5) Client Rep and/or State Rep BrqnJ,,,,.. -.rcf Date 'i'-d.-O...~"I Stack Diagram EnQine Make Non-Resettable Run Time Hours LA r ! Engine Model Enaine SIN Port Distance A I~ 'I 4; l t."I I [~~] Port Distance 8 Exhaust Diameter (inches) Calibration Gas NO (ppm CO (ppm Propane (ppm) N02 (ppm) Ethvlene (ppm Methane (ppm Acetaldehvde (ppm) I~ ,I Cylinder # CC745222: CC450607 ND46380 CC51 0760 CC127876 CC471136 XC0155878 Concentration 514.5 501.8 497.5 144 99.97 494.5 199.1 Test 1 Test 2 Test 3 q: vs ID,'3.{; II:~ )Time of Reading Atm Pressure (in Hg) ?t. '1.&\ ") ),'1.1,7 -I ~t> ~5Atm Temp CF) Engine RPM veto I.5Jb *Manifold Pres. Vae(n) or ,Boost(~) or Boost (psia) ~k~ 3fi",6 \'?-.~.\ I~Y,S\~\Manifold Temo CF) Psuction (psi) StaQe 1 3'1 ~<t -..Tsuction CF) Staue 1 Pdischarae (osi) Staae 1 ( ~qtl lSO Psuction psi) Stage 2 Tsuction 'F) Stage 2 Pdischarae (osi) Staae 2 l. /1, ) l \;l~ ~~ 'Jay Psuction 'psi) Stage 3 , I Tsuction OF) staoe 3 I Pdischar e (psi) Staae 3 \~h " \~£o Psuction psi) Staqe 4 ! { Tsuction OF) StaQe 4 J Pdischarge (psi) Stage 4 T f Gas Throuahout Immef/d} or I } \ I Pre Cat Temp CF) a()7"J ~b3 Post Cat Temp CF) .~, Y1~t; 93~ Cat Differential Pres. (n of H2O) \, {; ,. It Humiditv% --02% ~,.') C£.S g.5 C02 % Dry 7,'\ I ~~ I.S LOAD % (Panel) or (Estimated) ..----_.. lonition Tlminq CF AFR SettinQ mV II ~ft R:rnk\ 1-h~,----)o,j --Rev 8 • Some units show boost in inches of Hg. In this situation please indicate if it is positive (+) or negative(-). Eg: (+12'1 or (- 5") AFR Settin "ank) 9/17/2019 Worksheet: O2 Stratification Client:XCL Location:Crozier #2-1A-32 Date:8/20/2024 PD:12 DD:30 YES Method 1 Criteria Met UD:12 YES Method 1 Criteria Met Port Point Insertion Depth Reading (inches)(%) A 1 1.99 8.50 A 2 6.00 8.50 A 3 10.00 8.50 A 4 A 5 A 6 A 7 A 8 A 9 A 10 A 11 A 12 Average 8.50 Notes: To demonstrate non-stratified flow and utilize one sampling location O2 may not deviate by more than +/- 0.3% of the average O2 concentration. EPA REFERENCE METHOD 3A (Determination Of Stratification) COMPANY NAME:XCL COMPANY LOCATION:Crozier #2-1A-32 DATE:8/20/24 STACK DIAMETER (inches):12 TRAVERSE POINTS:16 2 TEST RUN #1 TEST RUN #2 TEST RUN #3 AVERAGE O2:8.5 AVERAGE O2:8.5 AVERAGE O2:8.5 AVERAGE CO2:7.5 AVERAGE CO2:7.5 AVERAGE CO2:7.5 BARO PRESSURE:24.97 BARO PRESSURE:24.97 BARO PRESSURE:24.97 Point Insertion DepthDP (H2O)Ts (deg R)Stat P (H2O)Point Insertion DepthDP (H2O)Ts (deg R)Stat P (H2O)Point Insertion DepthDP (H2O)Ts (deg R)Stat P (H2O) 1 0.5 3.68 931 1.47 1 0.5 3.71 935 1.48 1 0.5 3.74 932 1.5 2 1.26 3.72 2 1.26 3.75 2 1.26 3.77 3 2.328 3.76 3 2.328 3.78 3 2.328 3.79 4 3.876 3.81 4 3.876 3.83 4 3.876 3.84 5 8.124 3.88 5 8.124 3.89 5 8.124 3.89 6 9.672 3.8 6 9.672 3.85 6 9.672 3.86 7 10.74 3.74 7 10.74 3.82 7 10.74 3.84 8 11.5 3.7 8 11.5 3.77 8 11.5 3.82 9 9 9 10 10 10 11 11 11 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16 1 0.5 3.69 931 1.47 1 0.5 3.7 935 1.48 1 0.5 3.76 932 1.5 2 1.26 3.72 2 1.26 3.74 2 1.26 3.8 3 2.328 3.75 3 2.328 3.77 3 2.328 3.84 4 3.876 3.81 4 3.876 3.82 4 3.876 3.88 5 8.124 3.89 5 8.124 3.91 5 8.124 3.93 6 9.672 3.83 6 9.672 3.87 6 9.672 3.9 7 10.74 3.79 7 10.74 3.84 7 10.74 3.88 8 11.5 3.74 8 11.5 3.81 8 11.5 3.85 9 9 9 10 10 10 11 11 11 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16