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DAQ-2024-011270
1 DAQC-1094-24 Site ID 11679 (B4) MEMORANDUM TO: STACK TEST FILE – SCOUT ENERGY MANAGEMENT, LLC – Ashley Compressor Station – Duchesne County THROUGH: Rik Ombach, Minor Source Oil and Gas Compliance Section Manager FROM: Kyle Greenberg, Environmental Scientist DATE: October 24, 2024 SUBJECT: Sources: One (1) 1,255 hp Compressor Engine; Caterpillar G3516TALE SN: 4EK02753 and One (1) 1,380 hp Compressor Engine; Caterpillar 3516TALE SN: JEF01561 Contact: Abby Molyneaux: 972-325-1170 Location: Remote location in Duchesne County, UT Test Contractor: Great Plains Analytical Services, Inc. Permit/AO#: DAQE-AN116790009-15, dated February 9, 2015 Action Code: TR Subject: Review of Stack Test Report dated August 21, 2024 On August 21, 2024, DAQ received test reports for One (1) 1,255 hp Compressor Engine; Caterpillar G3516TALE SN: 4EK02753 and One (1) 1,380 hp Compressor Engine; Caterpillar 3516TALE SN: JEF01561 at the Ashley Compressor Station. Testing was performed on July 31, 2024, to demonstrate compliance with the emission limits found in condition II.B.4 of DAQE-AN116790009-15 and 40 CFR Part 60 Subpart JJJJ. The calculated test results are: Source Test Date Test Methods Pollutants Tester Results DAQ Results Limits 1,255 hp Compressor Engine; Caterpillar G3516TALE SN: 4EK02753 7/31/24 ASTM D6348-03 NOx 2.249 lbs/hr 0.828 g/hp-hr 2.238 lbs/hr 0.824 g/hp-hr 4.15lbs/hr 1.0 g/hp-hr CO 2.641 lbs/hr 0.973 g/hp-hr 2.630 lbs/hr 0.969 g/hp-hr 5.26 lbs/hr 2.0 g/hp-hr VOC 0.360 g/hp-hr 0.358 g/hp-hr 0.7 g/hp-hr 1,380 hp Compressor Engine; Caterpillar 3516TALE SN: JEF01561 7/31/24 ASTM D6348-03 NOx 0.824 lbs/hr 0.301 g/hp-hr 0.815 lbs/hr 0.298 g/hp-hr 3.04 lbs/hr 1.0 g/hp-hr CO 0.030 lbs/hr 0.011 g/hp-hr 0.029 lbs/hr 0.011 g/hp-hr 0.85 lbs/hr 2.0 g/hp-hr VOC 0.333 lbs/hr 0.122 g/hp-hr 0.330 lbs/hr 0.121 g/hp-hr 2.1 lbs/hr 0.7 g/hp-hr 2 DEVIATIONS: None. CONCLUSION: The stack test report appears to be acceptable. RECOMMENDATION: It is recommended the emissions from the compressor engines be considered in compliance with the emission limits found in condition II.B.4 of DAQE-AN116790009-15 and 40 CFR Part 60 Subpart JJJJ during the time of testing. HPV: Not Applicable. ATTACHMENTS: DAQ excel spreadsheets; Scout Energy stack test report. Emissions Scout Energy Management, LLC Ashley Compressor Station Duchesne County, Utah Unit 1; Caterpillar G3516TALE; SN: 4EK02753 Test Date: 7/31/24 Run # 1 2 3 Average Start Time 9:43 10:56 12:07 Stop Time 10:43 11:56 13:07 Sample Duration (minutes) 60 60 60 BHP Engine Load - Actual (bhp) 1228 1233 1233 1231 DS Stack Diameter (inches) 12.0 12.0 12.0 12.0 PAVG Average (Delta P)½ (" H2O)½0.8870 0.8730 0.8878 0.8826 CP Pitot Tube Constant (unitless) 0.99 0.99 0.99 0.99 TS Stack Temperature (°F) 671 678 681 676 Pbar Barometric Pressure (mbar) 818 819 819 819 Pbar Barometric Pressure (" Hg) 24.16 24.19 24.18 24.18 Ps Stack Pressure ('' H2O)0.06 0.06 0.06 0.06 O2%vd O2 (%vd)9.5 9.4 9.4 9.4 CO2%vd CO2 (%vd)5.2 5.3 5.3 5.3 N2%vd N2 (%vd)85.3 85.3 85.3 85.3 dry NOX (ppmvd)183.2 201.7 209.7 198.2 dry CO (ppmvd) 370.8 385.4 391.4 382.5 wet TVOC (ppmvw as C3H8)82.6 83.0 84.7 83.4 Run # 1 2 3 Average Bws Measured Moisture Content (%/100) 0.070 0.072 0.073 0.071 Bws Saturated Moisture Content (%/100) 206.976 216.041 220.146 214.388 Bws Actual Moisture Content (%/100) 0.070 0.072 0.073 0.071 MD Molecular Weight Dry (lb/lb-mole) 29.22 29.22 29.22 29.22 MA Molecular Weight Wet (lb/lb-mole) 28.43 28.42 28.40 28.42 VS Gas Velocity (ft/sec) 96.3 95.0 96.8 96.1 FACFM Gas Flow (acfm) 4538 4479 4563 4526 FDSCFM Gas Flow (dscfm) 1591 1560 1582 1578 FWSCFM Gas Flow (wscfm) 1712 1681 1707 1700 FKWSCFH Gas Flow (kwscfh) 103 101 102 102 FKWSCFM Gas Flow (kwscfm) 2 2 2 2 lb/hr Gas Flow (lb/hr) 7580 7438 7552 7523 Fo Fo (unitless)2.181 2.179 2.175 2.179 wet O2 (%vw)8.9 8.7 8.7 8.8 wet CO2 (%vw)4.9 4.9 4.9 4.9 wet NOX (ppmvw)170.414 187.259 194.430 184.034 15 NOX (ppmvd @ 15% O2)94.943 103.597 107.727 102.089 lb/hr NOX (lb/hr)2.087 2.252 2.375 2.238 4.15 g/bhp-hr NOX (g/bhp-hr)0.771 0.828 0.874 0.824 1.00 wet CO (ppmvw) 344.904 357.872 362.885 355.220 15 CO (ppmvd @ 15% O2)192.158 197.985 201.062 197.068 lb/hr CO (lb/hr) 2.572 2.620 2.698 2.630 5.26 g/bhp-hr CO (g/bhp-hr) 0.950 0.964 0.993 0.969 2.0 dry NMEOC (ppmvd as C3H8)88.759 89.358 91.387 89.835 15 NMEOC (ppmvd as C3H8 @ 15% O2)45.999 45.901 46.943 46.281 lb/hr NMEOC (lb/hr as C3H8)0.969 0.956 0.991 0.972 g/bhp-hr NMEOC (g/bhp-hr as C3H8)0.358 0.352 0.365 0.358 0.7 Permit Limits Field Reference Method Data Reference Method Calculations Page 1 of 5 Linearity Scout Energy Management, LLC Ashley Compressor Station Duchesne County, Utah Unit 1; Caterpillar G3516TALE; SN: 4EK02753 Test Date: 7/31/24 O2 21.0 10.62 0.0 10.6 Linearity Bias (Zero) 0.0 Linearity Bias (Span) 10.7 % 0.00 10.62 20.98 0.0 10.7 21.2 0.0 0.0 0.2 0.0 0.00% 0.19% 0.91% Span Bias Max Calibration Error Bias Check (Zero) Bias Check (Span) 2 3 4 Results 3 Zero Bias 4 Difference 1 4 Response 1 2 Gas Concentration 1 2 3 Linearity Information Gas Span Gas Value/Range Bias Gas Value Page 2 of 5 Run 1 Scout Energy Management, LLC Ashley Compressor Station Duchesne County, Utah Unit 1; Caterpillar G3516TALE; SN: 4EK02753 Test Date: 7/31/24 O2 21.0 10.62 0.0 10.6 0.0 10.4 0.0% 1.4% 0.0% 1.2% Corrected O2 % 9.5 Run Length (Minutes) Uncorrected O2 % 60 9.4 Post Test Calibration Calibration Information Instrument Range Span Gas Value Gas Calibration Pretest Calibration Zero% Span% Zero% Span% Absolute Bias (Zero) Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Results Page 3 of 5 Run 2 Scout Energy Management, LLC Ashley Compressor Station Duchesne County, Utah Unit 1; Caterpillar G3516TALE; SN: 4EK02753 Test Date: 7/31/24 O2 21.0 10.62 0.0 10.6 0.0 10.4 0.0% 1.4% 0.0% 1.2% Corrected O2 % 9.4 Run Length (Minutes) Uncorrected O2 % 60 9.3 Calibration Information Results Absolute Bias (Zero) Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Span% Span% Gas Instrument Range Post Test Calibration Zero% Span Gas Value Calibration Pretest Calibration Zero% Page 4 of 5 Run 3 Scout Energy Management, LLC Ashley Compressor Station Duchesne County, Utah Unit 1; Caterpillar G3516TALE; SN: 4EK02753 Test Date: 7/31/24 O2 21.0 10.62 0.0 10.6 0.0 10.4 0.0% 1.4% 0.0% 1.2% Corrected O2 % 9.4 Run Length (Minutes) Uncorrected O2 % 60 9.3 Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Calibration Information Span Gas Value Calibration Pretest Calibration Gas Post Test Calibration Instrument Range Zero% Results Absolute Bias (Zero) Span% Span% Zero% Page 5 of 5 Emissions Scout Energy Management, LLC Ashley Compressor Station Duchesne County, Utah Unit 3; Caterpillar G3516TALE; SN: JEF01561 Test Date: 7/31/24 Run # 1 2 3 Average Start Time 14:21 15:41 16:50 Stop Time 15:21 16:41 17:50 Sample Duration (minutes) 60 60 60 BHP Engine Load - Actual (bhp) 1232 1288 1204 1241 DS Stack Diameter (inches) 13.0 13.0 13.0 13.0 PAVG Average (Delta P)½ (" H2O)½0.6410 0.6317 0.6806 0.6511 CP Pitot Tube Constant (unitless) 0.99 0.99 0.99 0.99 TS Stack Temperature (°F) 711 716 723 716 Pbar Barometric Pressure (mbar) 817 817 816 817 Pbar Barometric Pressure (" Hg) 24.13 24.12 24.10 24.11 Ps Stack Pressure ('' H2O)0.42 0.41 0.47 0.43 O2%vd O2 (%vd)8.8 8.9 8.8 8.8 CO2%vd CO2 (%vd)5.2 5.3 5.3 5.3 N2%vd N2 (%vd)85.9 85.9 85.9 85.9 dry NOX (ppmvd)84.6 86.0 83.8 84.8 dry CO (ppmvd) 4.8 5.2 5.1 5.0 wet NMNEOC (ppmvw as C3H8)33.4 33.3 33.0 33.3 Run # 1 2 3 Average Bws Measured Moisture Content (%/100) 0.071 0.072 0.070 0.071 Bws Saturated Moisture Content (%/100) 263.820 271.647 283.029 272.832 Bws Actual Moisture Content (%/100) 0.071 0.072 0.070 0.071 MD Molecular Weight Dry (lb/lb-mole) 29.19 29.20 29.20 29.19 MA Molecular Weight Wet (lb/lb-mole) 28.40 28.40 28.42 28.40 VS Gas Velocity (ft/sec) 70.9 70.0 75.6 72.2 FACFM Gas Flow (acfm) 3920 3871 4183 3991 FDSCFM Gas Flow (dscfm) 1325 1302 1400 1343 FWSCFM Gas Flow (wscfm) 1427 1403 1506 1446 FKWSCFH Gas Flow (kwscfh) 86 84 90 87 FKWSCFM Gas Flow (kwscfm) 1 1 2 1 lb/hr Gas Flow (lb/hr) 6312 6206 6666 6395 Fo Fo (unitless)2.312 2.282 2.287 2.294 wet O2 (%vw)8.2 8.2 8.2 8.2 wet CO2 (%vw)4.8 4.9 4.9 4.9 wet NOX (ppmvw)78.591 79.858 77.987 78.812 15 NOX (ppmvd @ 15% O2)41.361 42.207 40.965 41.511 lb/hr NOX (lb/hr)0.803 0.802 0.841 0.815 3.04 g/bhp-hr NOX (g/bhp-hr)0.296 0.282 0.317 0.298 1.00 wet CO (ppmvw) 4.492 4.785 4.770 4.683 15 CO (ppmvd @ 15% O2)2.364 2.529 2.506 2.466 lb/hr CO (lb/hr) 0.028 0.029 0.031 0.029 0.85 g/bhp-hr CO (g/bhp-hr) 0.010 0.010 0.012 0.011 2.0 dry NMEOC (ppmvd as C3H8)36.002 35.903 35.485 35.797 15 NMEOC (ppmvd as C3H8 @ 15% O2)17.604 17.615 17.337 17.519 lb/hr NMEOC (lb/hr as C3H8)0.327 0.321 0.341 0.330 2.13 g/bhp-hr NMEOC (g/bhp-hr as C3H8)0.121 0.113 0.128 0.121 0.7 Permit Limits Field Reference Method Data Reference Method Calculations Page 1 of 5 Linearity Scout Energy Management, LLC Ashley Compressor Station Duchesne County, Utah Unit 3; Caterpillar G3516TALE; SN: JEF01561 Test Date: 7/31/24 O2 21.0 10.62 0.0 10.6 Linearity Bias (Zero) 0.0 Linearity Bias (Span) 10.7 % 0.00 10.62 20.98 0.0 10.7 21.2 0.0 0.0 0.2 0.0 0.00% 0.19% 0.91% Gas Concentration 1 2 3 Linearity Information Gas Span Gas Value/Range Bias Gas Value 4 Difference 1 4 Response 1 2 Span Bias Max Calibration Error Bias Check (Zero) Bias Check (Span) 2 3 4 Results 3 Zero Bias Page 2 of 5 Run 1 Scout Energy Management, LLC Ashley Compressor Station Duchesne County, Utah Unit 3; Caterpillar G3516TALE; SN: JEF01561 Test Date: 7/31/24 O2 21.0 10.62 0.0 10.6 0.0 10.3 0.0% 1.9% 0.0% 1.7% Corrected O2 % 8.8 Run Length (Minutes) Uncorrected O2 % 60 8.7 Zero% Span% Absolute Bias (Zero) Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Results Post Test Calibration Calibration Information Instrument Range Span Gas Value Gas Calibration Pretest Calibration Zero% Span% Page 3 of 5 Run 2 Scout Energy Management, LLC Ashley Compressor Station Duchesne County, Utah Unit 3; Caterpillar G3516TALE; SN: JEF01561 Test Date: 7/31/24 O2 21.0 10.62 0.0 10.6 0.0 10.3 0.0% 1.9% 0.0% 1.7% Corrected O2 % 8.9 Run Length (Minutes) Uncorrected O2 % 60 8.7 Gas Instrument Range Post Test Calibration Zero% Span Gas Value Calibration Pretest Calibration Zero% Calibration Information Results Absolute Bias (Zero) Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Span% Span% Page 4 of 5 Run 3 Scout Energy Management, LLC Ashley Compressor Station Duchesne County, Utah Unit 3; Caterpillar G3516TALE; SN: JEF01561 Test Date: 7/31/24 O2 21.0 10.62 0.0 10.6 0.0 10.3 0.0% 1.9% 0.0% 1.7% Corrected O2 % 8.8 Run Length (Minutes) Uncorrected O2 % 60 8.7 Post Test Calibration Instrument Range Zero% Results Absolute Bias (Zero) Span% Span% Zero% Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Calibration Information Span Gas Value Calibration Pretest Calibration Gas Page 5 of 5 303 West 3rd Street ● Elk City, Oklahoma 73644 ● 580-225-0403 GAS Inc. www.gasinc.us Utah Department of Environmental Quality State Office Building – Air Quality Division 195 North 1950 West Salt Lake City, Utah 84114 RE: Scout Energy Management, LLC 40 CFR Part 60 Subpart JJJJ – Test Report To Whom It May Concern, Please find enclosed the performance tesVng reports for 40 CFR Part 60, Subpart JJJJ on behalf of Scout Energy Management, LLC. Please see below for the informaVon perVnent to the tesVng. The tesVng took place the week of July 29, 2024. Facility Unit # Serial # Loca1on Ashley Compressor StaVon Unit 1 4EK02753 Duchesne County, Utah Ashley Compressor StaVon JEF01561 Duchesne County, Utah For informaVon regarding the performance test, you can contact me by email at jmorgan@gasinc.us or by phone at 580-225-0403. For informaVon regarding engine or locaVon informaVon, please contact Chris Breitling by email at chris.breitling@scoutep.com or by phone at (469) 485-3418. Regards, Jordan Morgan Client Analyst GAS Inc. ,49& [ "#$#%& )D( )*)+ Performance Test Report Test Type: Annual Test Date: 7/31/2024 Caterpillar G3516TALE Lean Burn (4 Cycle) 303 W. 3rd St Elk City , OK 73644(580) 225-0403 Test Started:Test Completed:09:43 AM 01:22 PM Source: Unit Number: Unit 1 Serial Number: 4EK02753 Engine Hours:75386.7 Permit #: #DAQE-ANl 1679008-13 Location: Duchesne County, Utah Prepared on Behalf of: Scout Energy Management, LLC Ashley Compressor Station 40 CFR Part 60 Subpart JJJJ CO NOx NMNEHC 3.940 4.150 2.641 2.249 382.419 198.199 89.834 2.000 1.000 0.700 0.973 0.828 0.360 Pass Pass Pass Pass Pass Federal State Federal State Federal Results lb/hr Results ppmvd Permit lb/hr Results g/hp-hr Permit g/hp-hr PASS ALL Index Tables Figures Appendices Table 5.1 (Run Summaries)................................................................ Table 6.1 (Volumetric Flow Rate Data)............................................... Table 6.2 (Stack Gas Measurements)................................................. Table 8.1 (Oxygen Calibration)........................................................... Annex Table 1.2.1 (Certified Calibration Bottle Concentrations)......... Annex Table 1.2.2 (Measurement System Capabilities)..................... Annex Table 1.3.1 (Test Specific Target Analytes)............................. Annex Table 4.1 (Measure System Capabilities)................................ Figure 6.1 (Location of Traverse Points per Method 1)....................... Annex Figure 1.4.1 (Sampling Train).................................................. Annex Figure 1.4.2 (Sampling Points)................................................. Annex Figure 1.4.3 (Sampling Port Locations).................................... Certified Calibration Bottle Certificates................................................ Tri Probe Certification via GD-031...................................................... GAS ALT 141_FTIR EPA.................................................................... Tester Qualifications (resume)............................................................ Raw Data............................................................................................ 27 Key Personnel.............................................................................1.0 3 Sampling System........................................................................2.0 3 Methods Used.............................................................................3.0 3 Test Summaries..........................................................................4.0 5 Run Summaries..........................................................................5.0 6 6 Volumetric Flow Rate Data.........................................................6.0 7 7 7 7 Calculations................................................................................7.0 8 9 12 12 13 15 13 14 14 20 25 28 29 Oxygen Calibration.....................................................................9 Engine Parameter Data Sheet....................................................10 QA/QC Results............................................................................11 Signature Page...........................................................................12.0 Appendices.................................................................................13.0 Bottle Certs.................................................................................2014.0 Tri Probe Certification via GD-031..............................................2515.0 GAS ALT 141_FTIR EPA............................................................16.0 Tester Qualifications (resume)....................................................2817.0 D6348 Annexes..........................................................................1211.0 18 19 26 8.0 9.0 10.0 Raw Data....................................................................................2918.0 1.0 Key Personnel GAS, Inc. Scout Energy Management, LLC 2.0 Sampling System The sampling system used consisted of a Stainless steel probe, heated Teflon line, gas conditioning system, and a Gasmet model DX4000 FTIR analyzer. The gas conditioning system used was a Gasmet Personal Sampling System with a Zirconium Oxide oxygen sensor. 3.0 Methods Used This extractive FTIR based field test method is used to quantify gas phase concentrations of multiple target analytes (CO, NOX, CH2O, & VOC's) from stationary source effluent. Because an FTIR analyzer is potentially capable of analyzing hundreds of compounds, this test method is not analyte or source specific. The analytes, detection levels, and data quality objectives are expected to change for any particular testing situation. It is the responsibility of the tester to define the target analytes, the associated detection limits for those analytes in the particular source effluent, and the required data quality objectives for each specific test program. Provisions are included in this test method that require the tester to determine critical sampling system and instrument operational parameters, and for the conduct of QA/QC procedures. Testers following this test method will generate data that will allow an independent observer to verify the valid collection, identification, and quantification of the subject target analytes. EPA Method 1 & 1A EPA Method 2 & 2C EPA Method 3A The purpose of the method is to provide guidance for the selection of sampling ports and traverse points at which sampling for air pollutants will be performed pursuant to regulations set forth in this part. This method is applicable for the determination of the average velocity and the volumetric flow rate of a gas stream. The average gas velocity in a stack is determined from the gas density and from measurement of the average velocity head with a standard pitot tube. Velocity readings are taken from each stack at 16 separate traverse points (Table 6.1) and used to determine the engines mass emissions rate, calculated utilizing the formulas seen in section 7.0 of this report. This is a procedure for measuring oxygen (O2) and carbon dioxide (CO2) in stationary source emissions using a continuous instrumental analyzer. Quality assurance and quality control requirements are included to assure that the tester collects data of known quality. Documentation to these specific requirements for equipment, supplies, sample collection and analysis, calculations, and data analysis will be included. ASTM D6348-03 Jason Bird 3 Danny Cupp Gas, Inc. 4.0 Test Summary T e s t S u m m a r y Site Verification Photos Gas, Inc. Unit Unit 1 with a serial number of 4EK02753 which is a Caterpillar G3516TALE engine located at Ashley Compressor Station and operated by Scout Energy Management, LLC was tested for emissions of: Carbon Monoxide, Oxides of Nitrogen, and Volatile Organic Compounds. The test was conducted on 7/31/2024 by Danny Cupp with Great Plains Analytical Services, Inc. All quality assurance and quality control tests were within acceptable tolerances. The engine is a natural gas fired Lean Burn (4 Cycle) engine rated at 1255 brake horse power (BHP) at 1400 RPM. The engine was operating at 1231 BHP and 1374 RPM which is 98.12% of maximum engine load during the test. The test HP calculation can be found on page 8. The engine was running at the maximum load available at the test site. This test will satisfy the testing requirements for 40 CFR Part 60 Subpart JJJJ. Unit Unit 1 is authorized to operate under permit #DAQE-ANl 1679008-13. 4 4.0 Test Summary Engine/Compressor Specs Ashley Compressor StationLocation Unit 1Unit ID Make Caterpillar Site Elevation ft.5404.11 Model G3516TALE Atmospheric Pressure psi.12.12 Serial Number 4EK02753 Stack Diameter in.12 mfg. rated hp 1255 No 1400 Date of Manufacture Engine/Compressor Operation Run 2 Run 3 3 Run AveragesRun 1 Test Horsepower 1228 1233 1233 1231 1370 1375 1376 1374 Percent Load % Intake Manifold Pressure (hg) 97.86%98.21%98.29%98.12% 22.15 22.15 23.17 22.49 Intake Manifold Temperature (F)116.60 117.70 118.20 117.50 Ambient Conditions Ambient Temperature Dry (F)67.00 80.00 83.00 76.67 Exhaust Flow Data Q Stack (dscfh) Q Stack (dscm/hr) 95788.52 94052.89 95316.14 95052.52 2712.40 2663.26 2699.03 2691.56 Moisture Fraction Bws Fuel Consumption (Btu/h[-hr) 0.07 0.07 0.07 0.07 0 0 0 0 Fuel Flow (dscfh) Fuel (btu/scf)1020 1020 1020 1020 O2 F factor 8710.0 8710 8710 8710 Results Method 3A Corrected O2% Dry Moisture %6.98%7.15%7.29%7.14% T e s t S u m m a r y mfg. rated rpm Test RPM 9.51%9.41%9.41%9.44% Permitted Standards Results 5 Catalyst 0.9960.969 Run 1 Run 2 Run 3 3 Run Average Pass Permits 09:43 AM 10:56 AM 12:07 PM 7/31/2024 CO (g/hp-hr)0.953 0.9732.000 Pass StateFederal CO (ppmvw)344.897 357.890 362.532 355.106 CO (ppmvd)370.785 385.430 391.041 382.419 CO (mol wt) 28.01 CO (ppmvd) @15% O2 192.100 197.902 200.801 196.935 Fail CO (ppbvd) @15% O2 192099.856 197902.311 200801.456 196934.541 Fail 2.7082.634CO (lbs/hr)2.581 2.6413.940 Pass NOx (g/hp-hr)0.774 0.833 0.877 0.8281.000 Pass NOx (ppmvw)170.410 187.268 194.429 184.035 NOx (ppmvd)183.201 201.679 209.718 198.199 NOx (mol wt) 46.01 82.564 82.969 84.725 83.419NMNEHC (ppmvw) 88.761 89.354 91.387 89.834NMNEHC (ppmvd) NOx (ppbvd) @15% O2 94914.388 103553.667 107691.254 102053.103 Fail NOx (ppmvd) @15% O2 94.914 103.554 107.691 102.053 Fail NMNEHC (mol wt) 44.10 45986.354 45879.404 46927.728 46264.495 FailNMNEHC (ppbvd) @15% O2 0.359 0.354 0.367 0.3600.700 PassNMNEHC (g/hp-hr) 45.986 45.879 46.928 46.264 FailNMNEHC (ppmvd) @15% O2 NOx (lbs/hr)2.095 2.264 2.386 2.2494.150 Pass Gas, Inc. 5.0 Run Summaries Summary Source Run 1 R u n Table 5.1 Run Summaries S u m m a r i e s 6 0.00Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture % 344.90 0.00 108.42 0.00 61.99 0.00 170.41 0.64 82.56 0.19% 8.73% 0.00% 6.98% NMNEHC 338.86 103.90 60.01 163.91 84.52 8.81%6.97% 369.78 148.78 66.77 215.55 86.03 8.05%6.39% 350.94 112.94 63.97 176.91 80.61 8.64%6.99% 0.00 0.00 0.00 0.00 0.78 0.00%0-.0% Avg. Wet NO2NO Summary Source Run 2 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 0.00 0.00 0.00 0.00 0.78 0.00%0-.0% 357.05 116.08 67.89 183.97 82.31 8.60%7.05% 354.98 131.43 67.65 199.08 90.13 8.11%7.05% 358.73 119.45 71.12 190.57 83.63 8.63%7.24% 0.00 0.00 0.00 0.00 0.87 0.17%0.00% Avg. Wet 357.89 117.77 69.50 187.27 82.97 8.62%7.15% NO2NO Summary Source Run 3 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 361.13 122.18 72.76 194.95 85.18 8.59%7.28% 367.32 130.08 77.85 207.93 93.18 7.98%6.42% 363.94 120.05 73.86 193.91 84.27 8.62%7.31% 0.44 0.00 0.00 0.00 0.20 0.14%0-.0% 0.00 0.00 0.00 0.00 0.87 0.17%0.00% Avg. Wet 362.53 121.12 73.31 194.43 84.72 8.61%7.29% NO2NO Gas, Inc. 6.0 Volumetric Flow Rate Data Volumetric Flow Rate Data .99 Stack diameter = Table 6.1. Data used for volumetric flow rate (Method 2) 12 inches or:1 feet. or:.79 Square Feet Run 1 Average Pitot Tube Coefficient Cp(std)= H2O CO2 O2 CO Molecular Weight Stack Gas dry basis (Md) Molecular Weight Stack Gas wet basis (Ms) Stack Static Pressure (Pg) Stack Static Pressure (Pg) Atmospheric Pressure at Location (Pbar) Atmospheric Pressure at Location (Pbar) Absolute Stack Pressure (Ps) Stack Temperature Stack Temperature Stack Temperature Stack Gas Velocity Stack Flow Rate Q Stack Gas Wet Volmetric Flow Rate Stack Gas Dry Volumetric Flow Rate Sample after Back Purge: Within 5% of Last Δpstd reading: Stack Diameter (inches) Inches upstream from disturbance Inches downstream from disturbance scf/hr 0.65 Yes 12.00 300.00 31.00 scf/hr cfs ft/sec Deg R Deg F Deg C "Hg "Hg MBAR "Hg "H20 g/g mole g/g mole ppmd %d %d %d 6.98 29.19 0.79 Inches 2 6 10 Vo l u m e t r i c F l o w Ra tes Pitot readings are taken for Method 2 calculations using measuring points outlined in Method 1 Figure 6.1 16 Traverse Points Were Used Emissions Sampling Points - 3 point long line sampling probe First Sampling Point Taken @ 16.7% of Stack Diameter Second Sampling Point Taken @ 50% of Stack Diameter Third Sampling Point Taken @ 83.3% of Stack Diameter 5.22 8.73 344.90 818.32 0.06 24.17 24.23 670.50 1130.17 354.72 28.41 96.27 75.61 102978.48 95788.52 Run 2 7.15 29.20 0.77 5.27 8.62 357.89 819.00 0.06 24.19 24.25 677.50 1137.17 358.61 28.40 95.21 74.78 101290.61 94052.89 Run 3 7.29 29.20 0.79 5.28 8.61 362.53 818.78 0.06 24.18 24.24 680.50 1140.17 360.28 28.38 96.91 76.12 102811.62 95316.14 7.14 29.20 0.78 5.25 8.66 355.11 818.70 0.06 24.18 24.24 676.17 1135.84 357.87 28.40 96.14 75.50 102362.26 95054.28 *The exhaust stack did not present cyclonic flow conditions at the sampling location due to the absence of cyclones, inertial demisters, venturi scrubbers, or tangential inlets. * Cyclonic Flow Check (Pass/Fail): PASS Δpstd (in) H2O 0.68 Exhaust Temp F 670.00 Pitot Tube Sampling Points (Velocity) 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 Δpstd Average= Run 1 Table 6.2. Stack gas pressure readings measured with a standard pitot tube use for Volumetric Flow Rate 0.75 0.80 0.77 669.00 668.00 667.00 0.76 0.88 0.92 666.00 665.00 664.00 0.87 0.75 0.82 663.00 671.00 672.00 0.80 673.00 0.76 0.79 0.84 674.00 675.00 676.00 0.70 0.72 0.79 677.00 678.00 670.50 Δpstd = Velocity head measured by the standard pitot tube, (in.) H2O.Run 3 Δpstd (in) H2O 0.83 Exhaust Temp F 681.00 0.89 0.87 0.79 682.00 683.00 684.00 0.77 0.60 0.81 685.00 686.00 687.00 0.83 0.86 0.80 688.00 680.00 679.00 0.93 678.00 0.92 0.77 0.68 677.00 676.00 675.00 0.66 0.65 674.00 673.00 680.500.79 Run 2 Δpstd (in) H2O 0.80 Exhaust Temp F 677.00 0.77 0.78 0.75 676.00 675.00 674.00 0.89 0.65 0.63 673.00 672.00 671.00 0.50 0.67 0.88 670.00 678.00 679.00 0.89 680.00 0.92 0.77 0.73 681.00 682.00 683.00 0.80 0.83 684.00 685.00 0.77 677.50 7 Gas, Inc. 7.0 Calculations Method 2: Determination of Stack Gas Velocity and Volumetric Flow Rate *Note- Use of this method negates the need for any fuel related numbers for emissions calculations Nomenclature Δp(avg) = Velocity head of stack gas, mm H2O (in. H2O).Ps = Absolute stack pressure (Pbar+ Pg), mm Hg (in Hg) 3600 = Conversion Factor, sec/hr. A = Cross-sectional area of stack, m2 (ft2). Bws = Water vapor in the gas stream (from ASTM D6348) Kp = Velocity equation constant. Md = Molecular weight of stack gas, dry basis, g/g-mole (lb./lb.-mole). Ms = Molecular weight of stack gas, wet basis, g/g-mole (lb./lb. -mole). Pstd = Standard absolute pressure, 760 mm Hg (29.92 in. Hg). Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (dscf/hr.). Ts(abs) = Absolute stack temperature, °K (°R). = 460 + Ts for English units. Tstd = Standard absolute temperature, 293°K (528 °R). Vs = Average stack gas velocity, m/sec (ft./sec). *(Observed from Method 3 12.3) Dry Molecular Weight. Equation 3-1 Md = .44(.052)+.32(.095)+.28(.819+.034) = 29.194 LB/LB-MOLEMd = .44(%CO2)+.32(%O2)+.28(%N2+%CO) 12.5 Molecular Weight of Stack Gas. Equation 2-6 Ms = 29.194(1 -.06982)+.18.0(.06982) = 28.412 LB/LB-MOLEMs = Md(1-Bws)+18.0(Bws) 12.6 Average Stack Gas Velocity. Equation 2-7 Vs = 85.49*.99*√.79*√(1130.17/(24.23*28.412)) = 96.28 FT/SECVs = Kp*Cp(std)*√Δpavg*√(Ts(abs)/(Ps*Ms)) 12.7 Average Stack Gas Volumetric Flow Rate. Equation 2-8 Qsd = 3600(1-.07)96.275*.785((528*24.23)/ (1130.17*29.92)) = 95788.52 DSCF/HRQsd = 3600(1-Bws)Vs*A((Tstd*Ps)/(Ts(abs)*Pstd)) *Standard conversion from feet to meters Q = 95788.522/35.315 = 2712.403 DSCM/HRQ = Qsd/35.315 Emission Rates (Examples use CO Run 1) Nomenclature CO corrected @ 15% O2 453.6= Conversion factor lb. to gram HP= Engines rated Horsepower A = Cross-sectional area of stack, m2 (ft2). BHP/HR. = Brake work of the engine, horsepower-hour (HP-HR.). BTU/HP-HR. = Brake Specific Fuel Consumption (HHV) ER = Emission rate of (CO) in g/HP-hr. F(d )= Volumes of combustion components per unit of heat content, scm/J (scf/million Btu). Q = Stack gas volumetric flow rate, in standard cubic meters per hour, dry basis LB/HR.= Emission rate of (CO) in LB/HR. Mfg.= Manufacturer Exhaust flow rate at 100% (ft3/min) O2 = Concentration of oxygen on a dry basis, percent. ppm= Parts Per Million (CO) ppm@15% O2= PPM corrected to 15% O2 Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (DSCF/HR.). Run Time = Run Time in Minutes TPY= Tons per Year Mol wt.= Mol Weight of CO (28.01) Vs = Average stack gas velocity, m/sec (ft./sec). ppm @ 15% O2 = 370.785*(20.9-15)/(20.9-9.5%)) = 191.897 PPM @ 15% O2ppm @ 15% O2 = PPM*((20.9-15%O2)/(20.9-O2)) G/HP HR from 40 CFR Part 60 Subpart JJJJ (370.785*(1.164*10^-3)*2712.403*(Run Time/60))/1228.107 = .953 G/HP-HRg/hp-hr = (PPM*(1.164*10^-3)*Q*(Run Time/60))/BHP/HR LB/HR from Grams LB/HR = .953*1/453.6*1228.107 = 2.581 LB/HRlb/hr = ER*1/453.6*BHP-HR TPY TPY = 2.581*4.38 = 11.305 TPYTPY = LB/HR. *4.38 Horsepower HP Provided On Site Wet to Dry PPM 370.78 = 344.8965*(1/(1-.07))ppm wet * (1/(1-H2O) = ppm dry 8 Cp(std) = Standard pitot tube coefficient; use 0.99 Gas, Inc. 8.1 Calibration error test; how do I confirm my analyzer calibration is correct? After the tester has assembled, prepared and calibrated the sampling system and analyzer, they conduct a 3-point analyzer calibration error test before the first run and again after any failed system bias test or failed drift test. They then introduce the low-, mid-, and high-level calibration gases sequentially in direct calibration mode. At each calibration gas level (low, mid, and high) the calibration error must be within ± 2.0 percent of the calibration span. 8.0 Oxygen Calibration 8.2 Initial system bias and system calibration error checks. Before sampling begins, it is determined whether the high- level or mid-level calibration gas best approximates the emissions and it is used as the upscale gas. The upscale gas is introduced at the probe upstream of all sample- conditioning components in system calibration mode. 8.3 Post-run system bias check and drift assessment - confirming that each sample collected is valid. Sampling may be performed for multiple runs before performing the post-run bias or system calibration error check provided this test is passed at the conclusion of the group of runs. A failed final test in this case will invalidate all runs subsequent to the last passed test. (1) Next, zero gas is introduced as described above. The response must be within 0.5 percent of the upscale gas concentration. (2) Low-level gas reading is observed until it has reached a final, stable value and the results are recorded. The measurement system will be operated at the normal sampling rate during all system bias checks. (3) If the initial system bias specification is not met, corrective action is taken. The applicable calibration error test from Section 8.2.3 of EPA Method 7E is repeated along with the initial system bias check until acceptable results are achieved, after which sampling will begin. The pre- and post-run system bias must be within ± 5.0 percent of the calibration span for the low-level and upscale calibration gases. (1) If the post-run system bias check is not passed, then the run is invalid. The problem is then diagnosed and fixed, then another calibration error test and system bias is passed before repeating the run. (2) After each run, the low-level and upscale drift is calculated, using Equation 7E–4 in Section 12.5 from EPA Method 7E. If the post-run low- and upscale bias checks are passed, but the low-or upscale drift exceeds the specification in Section 13.3, the run data are valid, but a 3-point calibration error test and a system bias check must be performed and passed prior to additional testing. Table 8.1 Oxygen Calibration EPA Method 3A QA Worksheet (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Certified Gas Concentraion Low-Level (%) 0.00% Certified Gas Concentraion Mid-Level (%) Certified Gas Concentraion High-Level (%) (DIRECT) Analyzer Calibration Error (≤ 2%) Certified Concentration Value (%) Direct Calibration Response (%) Absolute Difference (%) Analyzer Calibration Error (%)Analyzer Direct Calibration Response Certified bottle value % 0.00% 0.00% 0.00% Zero Gas % Mid-Level Gas % High-Level Gas % Bias Pre Initial Value Bias Post Inital Values System Calibrations Response Pre (%) 0.00% System Bias (% of Span) Pre System Calibration Response Post (%) System Bias (% of Span) Post Drift (% of Span) 0.00%0.00%0.00%0.00% (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Avg. Gas Concentration (Run 1) Avg. Gas Concentration (Run 2) Avg. Gas Concentration (Run 3) Effluent Gas (Cgas) Run 1 Effluent Gas (Cgas) Run 2 Effluent Gas (Cgas) Run 3 Linearity Check 0.00%0.00%0.00% Method 7E 3.4 To the extent practicable, the measured emissions should be between 20 to 100 percent of the selected calibration span. This may not be practicable in some cases of low concentration measurements or testing for compliance with an emission limit when emissions are substantially less than the limit. 7E 8.5: Note: that you may risk sampling for multiple runs before performing the post-run bias provided you pass this test at the conclusion of the group of runs Upscale Gas Analyzer Calibration Response (%) Zero Gas Upscale Gas EPA Method 3A QA Worksheet Zero Gas Mid-Level Gas High-Level Gas 100% Nitrogen O2 QA/QC Zero Gas %0.00% Mid-Level Gas % High-Level Gas % System Calibration Response Pre (%) System Calibration Response Post (%) Zero Gas % Upscale Cal Zero Gas % Upscale Cal Upscale Used Upscale Used 10.65% 21.17% 10.61% 10.35% 10.62% 10.62% 10.35%10.61% 10.65% 21.17% 10.62% 20.98% 10.62% 20.98% 10.62%20.98% 0.00% 10.62% 20.98% 0.03% 0.19% 0.14% 0.92% 10.62% Span Zero Offset 0.00% 20.98 0.00% 10.65%0.19%1.42%0.01% 9.39% 9.29% 9.29% 9.51% 9.41% 9.41% 9 Gas, Inc. 897.0 896.0 896.3 19.0 20.0 19.3 9.0 Engine Parameter Data Sheet Company Site Elevation (ft) Facility Unit ID Date Make Scout Energy Management, LLC Ashley Compressor Station 7/31/2024 5404.11 Unit 1 Caterpillar Model Serial Number G3516TALE 4EK02753 Technician Danny Cupp Run Start Times 09:43 AM 10:56 AM 12:07 PM 01:22 PM Run 1 Run 2 Run 3 Completed Engine Parameter Data Run 1 Engine Speed (RPM)1370.0 1375.0 1376.0 1373.7 Engine Hours 75383.7 75384.7 75385.7 75386.7 Intake Manifold Pressure (psi)23.0 23.0 23.5 23.2 Intake Manifold Temp °F 116.6 117.7 118.2 117.5 Engine Load (BHP)1228.1 1232.6 1233.5 1231.4 Ambient Temp °F 67.0 80.0 83.0 76.7 Humidity %263.0 15.0 15.0 97.7 Dew Point °F 31.0 30.0 3.0 21.3 N/A 0.0 0.0 No N/A N/A N/A N/A N/A N/A N/A N/A# of Catalyst Installed Catalyst Manufacturer Catalyst (Yes or No) AFR Setting (Target Left Bank) AFR Setting (Target Right Bank) AFR Manufacturer/Type 0.0 0.0 0.0 0.0 0.0 0.0 N/A N/A N/A 10 Run 3 AverageRun 2 19.0 896.0Discharge Pressure (psi) Suction Pressure (psi) Catalyst Pressure Drop H2O Catalyst Outlet Temp °F Catalyst Inlet Temp °F Gas, Inc. 10.0 QA/QC Results Average:Carbon monoxide CO Gas, Inc. 0.00 R e s u l t s Average:Nitrogen monoxide NO 0.00 Average:Nitrogen dioxide NO2 0.00 Average:NOx 0.00 Average:VOC 0.37 Average:Oxygen 0.16 Pre-test Baseline Results Time: Q A / Q C Value:CTS Bottle Concentration 100.00 Value:CTS Compound Concentration Avg 99.69 Tolerance 2.00% Difference between measured and expected 0.31% CTS Direct to Analyzer Time: Average:Carbon monoxide CO 0.00 Average:Nitrogen monoxide NO 0.00 Average:Nitrogen dioxide NO2 0.26 Average:NOx 0.26 Average:VOC 0.52 Average:Oxygen 0.11 Pre-test System Zero Time: Mechanical Response Time 45 seconds Value:CTS Bottle Concentration 100.00 Value:CTS Compound Concentration Avg 99.51 Tolerance 5.00% Difference between measured and expected 0.49% Pre-test System CTS & Mechanical Response Time 7 secondsEquilibration Response Time Value:Spike Reported 253.90 Value:Spike Expected 257.20 System (Equilibration) Response Time Target (Spike) 45 secondsSystem Zero Response Time 45 secondsSystem Response Time System (Zero) Response Time 11 11.0 D6348 Annexes 1-8 D6348 Annexes 1. Test Plan Requirements Annex 1.2 The test quality objectives completed for the emissions test are demonstrated throughout Annexes 1, 2, 3, 4, 5, 6, 7 & 8 as layed out per ASTM D6348-03. All reference methods, pre-test and post test procedures were within acceptable limits. Data generated during the pre-test and post-test procedures are summarized below in order of the distinctive Annex. Three 60 minute test runs were performed. The final analyte concentrations are the average of each test run. Data was taken at 60 second intervals. Each 60 second measurement was the average of 600 scans. Propane is used as the surrogate compound for the Annex 5 Spiking Technique due to Propane being the VOC that is most commonly found in the combustion process of natural gas. Additionally, the molecular weight of Propane coincides with with molecular weight of VOC's per the EPA. Annex Table 1.2.1 Certified Calibration Bottle Concentrations Bottle Expiration NO2 Ethylene SF6 O2 (%) CC507057 4/29/2027 99.08 10.62% CC262147 11/29/2031 100.00 CC421882 10/10/2030 20.98% Cylinder # CC42028 Expiration: 12-11-2031 Propane CO NO SF6 Bottle Value 257.20 501.00 246.20 10.07 Analyzer System Response 253.90 494.10 247.81 10.05 Percent Difference 1.28%1.38%0.65%0.22% Annex Table 1.2.2 Measurement System Capabilities SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 99.691 4.985 Spike Direct Propane 254.616 Mechanical Response Time SF6 10.073 CO 492.636 NO 249.253 Ethylene 99.508 4 seconds Analyzer Response Propane 253.899 SF6 10.048 CO 494.102 NO 247.805 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 254.371 CO 482.087 NO 234.061 7 seconds 14 seconds 7.17% 7.41% 7.70% 82.75% 98.25% 98.90% 10.030 12 Gas, Inc. Annex 1.3 Compounds Infrared Analysis Region (cm-1) Expected Concentration Range Measurement System Achievable Minimum Detectable Concentrations Required Measurement System Accuracy and Precision for Test Application CO 2000-2200 0-1200 ppm NO 1875-2138 NO2 2700-2950 VOC 2600-3200 910-1150 2550-2950 CH2O 2550-2850 Interfering Compounds * CO is analyzed in a separate analysis region than CO2 and H2O CO2 Water Vapor 926-1150 3200-3401 Annex Table 1.3.1 Test Specific Target Analytes and Data Quality Objectives 0.16267 ppm 4 ppm 0-1000 ppm 0.4007 ppm 2 ppm 0-100 ppm 0.4899 ppm 2 ppm 0-100 ppm 1.8520 ppm Total VOC's 1 ppm per VOC 0-100 ppm 0.7878 ppm 1 ppm 0-10% 0-22% 0% 0.20% n/a n/a * VOCs compiled of Acetaldehyde, Ethylene, Hexane, and Propane. Annex 1.4 Figure Annex 1.4.1 Sampling Train The testing instrumentation is housed in an enclosed vehicle which is located approximately 45 feet from the source. A heated sample line (sixty feet in length) is attached to the inlet of analyzer system and the source effluent discharges through the FTIR outlet. 13 Gas, Inc. Sampling Point Locations in Inches 16.7%2.004 50%6.000 83.3%9.996 Figure Annex 1.4.3 Sample Port Location Figure Annex 1.4.2 Sampling Points Interior Stack Diameter (inches): Inches Upstream: Inches Downstream: 12 300 31 14 Stack Gas Dry Volumetric Flow Rate (scf/hr): 95054.28 H2O%d @ Sampling Point:7.14 CO2%d @ Sampling Point:5.25 Pressure @ Sampling Point (Pg "H2O):0.78 Temperature @ Sampling Point (Deg F):676.17 Gas, Inc. D6348 Annex 2. Determination of FTIR Measurement System Minimum Detectable Concentrations (MDC#1) Target Analyte Results (ppm) CO 0.1627 NO 0.4007 NO2 0.4899 Ethylene 0.3782 Propane 0.4351 Hexane 0.2233 Acetaldehyde 0.8152 Formaldehyde 0.7878 D6348 Annex 3. FTIR Reference Spectra Calibration Transfer Standard Expected Measured Path Length Validated Ethylene 100 99.69 4.985 Passed D6348 Annex 4. Required Pre-Test Procedures Annex Table 1.2.2 Measurement System Capabilities 15 SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 99.691 4.985 Spike Direct Propane 254.616 Mechanical Response Time SF6 10.073 CO 492.636 NO 249.253 Ethylene 99.508 4 seconds Analyzer Response Propane 253.899 SF6 10.048 CO 494.102 NO 247.805 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 254.371 CO 482.087 NO 234.061 7 seconds 14 seconds 7.17% 7.41% 7.70% 82.75% 98.25% 98.90% 10.030 Gas, Inc. D6348 Annex 5. Analyte Spiking Technique Propane Spike Direct SF6 CO NO 257.200 10.070 501.000 246.200 254.616 10.073 492.636 249.253 1.00% 0.03% 1.67% 1.24% +/- 2% +/- 2% +/- 2% +/- 2% Pass Pass Pass Pass Parameter Gas Concentration Measured % Difference Specification Validated 32.247 0.000 Spike Average 40.031 0.722 Dilution Factor 7.168% Expected 48.376 % Recovery 82.750% Specification 70-130% <10% Spike Run 1 via the System Source Output Propane SF6 D6348 Annex 6. Determination of System Performance Parameters Noise Equivalent Absorbance (NEA) RMS High RMS Mid RMS Low Line Position: Demonstrating the peak positions align correctly (Manual Comparison +/- 20%) 0.000 Spike Average 0.746 Dilution Factor 7.406% Expected % Recovery Specification 70-130% <10% Spike Run 2 via the System Source Output Propane SF6 0.000 Spike Average 0.776 Dilution Factor 7.704% Expected % Recovery Specification 70-130% <10% Spike Run 3 via the System Source Output Propane SF6 27.570 44.755 45.251 98.900% 0.003863 0.014019 0.018149 26.057 42.430 43.185 98.250% Line Position Difference:Resolution Difference to Reference1.55%Pass Pass4.24% 16 Gas, Inc. Resolution The Gasmet GICCOR (Genzel Interferometer with Cube Corner Retroreflectors) interferometer is specially designed for maximum optical throughput and maximum signal to noise ratio of 7.72 (cm-1) remaining stable with any vibration and temperature changes. D6348 Annex 7. Preparation of Analytical Quantification Algorithm The analytical accuracy of the quantification algorithm is satisfied via the results from Annex 5 per Annex 7.6 Regression Slope:-9.25935765 Pass Line Position Difference:Resolution Difference to Reference 4.24% D6348 Annex 8. Post Test Quality Assurance/Quality Control Procedures CTS Bottle Concentration: CTS Sample Concentration Average: Difference between measured and expected: Tolerance: 100.00 103.09 3.00% 5.00% POST CTS System Check: Run 1 Points 1 & 2 on CO/NO/Propane Run 2 Points 1 & 2 on CO/NO/Propane Run 3 Points 1 & 2 on CO/NO/Propane Run Data Validation - Automated vs Manual Reading Validated Comments All within 20% All within 20% All within 20% Passed Passed Passed Demonstrates no interferences observed. Demonstrates no interferences observed. Demonstrates no interferences observed. 17 Gas, Inc. Detector Linearity The Gasmet DX4000 is a low resolution spectrometer where the aperture is fixed to a maximum angle setting and the detector linearity was tested with an alternate approach. A three point linearity of the CTS gas was performed and validated. 12.0 Signature Page Job/File Name: We certify that based on review of test data, knowledge of those individuals directly responsible for conducting this test, we believe the submitted information to be accurate and complete. Scout Energy Management, LLC; Ashley Compressor Station; Unit 1; JJJJ 18 Company: Print Name: Signature: Title: Phone Number: Date: Company:G.A.S. Inc.Date: Print Name: Title: 7/31/2024 Emissions Specialist Company:G.A.S. Inc.Date: Print Name: Title: Signature: Phone Number: Travis Hartley Director of Stack Testing 580-225-0403 7/31/2024 Danny Cupp Gas, Inc. Appendices Gas, Inc. Gas, Inc. Spike (5 Gas) Gas, Inc. 9% O2/NO2 Gas, Inc. Ethylene Only Gas, Inc. BIP Gas, Inc. CERTIcICATE Oc ANALYSIS Grade of Product: EPA PROTOCOL STANaARa Part Number:E02NI79E15A00B1 Reference Number:54-402564012-1 Cylinder Number:CC421882 Cylinder Volume:146.0 CF Laboratory:124 - Chicago (SAP) - IL Cylinder Pressure:2015 PSIG PGVP Number:B12022 Valve Outlet:590 Gas Code:O2,BALN Certification Date:Oct 10, 2022 Expiration Date:Oct 10, 2030 Certification performed in accordance with “EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)” document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. The results relate only to the items tested. The report shall not be reproduced except in full without approval of the laboratory. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. ANALYTICAL RESULTS Component Requested Actual Protocol Total Relative AssayConcentrationConcentrationMethodUncertaintyDates OXYGEN 21.00 %20.98 %G1 +/- 0.4% NIST Traceable 10/10/2022 NITROGEN Balance CALIBRATION STANaARaS Type Lot ID Cylinder No Concentration Uncertainty Expiration Date NTRM 150104-18 K026588 22.454 % OXYGEN/NITROGEN +/- 0.2%Mar 08, 2027 ANALYTICAL EnUIPMENT Instrument/Make/Model Analytical Principle Last Multipoint Calibration O2-1 HORIBA MPA-510 3VUYL9NR Paramagnetic Sep 14, 2022 Triad Data Available Upon Request Airgas Specialty Gases Airgas USA LLC12722 S. Wentworth Ave. Chicago, IL 60628 Airgas.com Signature on file Approved for Release Page 1 of 1 ㈱┠伲 Tri Probe Certification ” ‡ ƒ – Ž ƒ ‹ • • • ƒ Ž › – ‹ … ƒ Ž ‡ ” ˜ ‹ … ‡ • ͵Ͳ͵͵ǡǡ͵ͶͶ ȋͷͺͲȌʹʹͷǦͲͶͲ͵ ǣȋͷͺͲȌʹʹͷǦʹͳʹ &(57,),&$7(2)$1$/<6,6 *UDGHRI3URGXFW&(57,),('67$1'$5'352%( 3DUW1XPEHU65HIHUHQFH 1XPEHU /DERUDWRU\*$6,1&6WDFN'LDPHWHU $QDO\VLV'DWH7DUJHW)ORZ 5DWH /PLQ /271XPEHU 61 $ $6 1XPEHURI 3RLQWV 3URGXFWSHUIRUPDQFHYHULILHGE\GLUHFWFRPSDULVRQWRFDOLEUDWLRQVWDQGDUGVWUDFHDEOHWR1,67 7KHSUREHOLVWHGRQWKLVIRUPPHHWVWKHPXOWLSRLQWWUDYHUVHUHTXLUHPHQWRI(3$0HWKRGH VHFWLRQDVVKRZQLQWKHDFFRPSDQ\LQJGDWD0HWKRGHVHFWLRQVWDWHVWKDWWKHPXOWLSRLQW WUDYHUVHUHTXLUHPHQWFDQEHVDWLVILHGE\VDPSOLQJYLD³DPXOWLKROHSUREHGHVLJQHGWRVDPSOHDW WKHSUHVFULEHGSRLQWVZLWKDIORZSHUFHQWRIPHDQIORZUDWH´ $1$/<7,&$/5(68/76 ZƵŶηdŽƚĂů&ůŽǁ ;>ͬŵͿ DĞĂƐƵƌĞĚ&ůŽǁ WŽƌƚ;>ͬŵͿ ;ĞůƚĂƋϭͿ DĞĂƐƵƌĞĚ&ůŽǁ WŽƌƚ;>ͬŵͿ ;ĞůƚĂƋϮͿ DĞĂƐƵƌĞĚ&ůŽǁ WŽƌƚ;>ͬŵͿ ;ĞůƚĂƋϯͿ 0HDQ3UREH 3RUW6DPSOHG )ORZ/P 5XQ/30 䧮 䧮 䧮 5XQ/30 䧮 䧮 䧮 &DOLEUDWLRQFRQGXFWHGLQDFFRUGDQFHZLWK(PLVVLRQ0HDVXUHPHQW&HQWHU*XLGHOLQH'RFXPHQW±(0&*' 1RWHV BBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBB $SSURYHGIRU5HOHDVH'DWH 2/17/2022 Probe size: 12S Mr. Jordan Williamson CEO GAS Inc. 303 W. 3rd Street Elk City, OK 73644 Dear Mr. Williamson: We are writing in response to your letter received on September 17, 2020, in which you request the approval of alternative testing procedures. The EPA’s Office of Air Quality Planning and Standards (OAQPS) is the delegated authority for consideration of major alternatives to test methods and procedures as set forth in 40 CFR parts 60 and 63 under which your request must be addressed. GAS Inc. is requesting a change to one of the test methods, ASTM D6348-03, used for conducting performance tests to determine compliance under 40 CFR part 60, Subpart JJJJ – Standards of Performance for Stationary Spark Ignition Internal Combustion Engines (Subpart JJJJ) and 40 CFR part 63, Subpart ZZZZ – National Emissions Standards for Hazardous Air Pollutants for Performance for Stationary Reciprocating Internal Combustion Engines (Subpart ZZZZ). The change being requested will be used to check detector linearity of the Fourier Transform Infrared (FTIR) instrumentation used to conduct this method. Specifically, you are requesting that the procedures of section 8.3.3 of Method 320 (40 CFR part 60, Appendix A), another FTIR-based method allowed under Subparts JJJJ and ZZZZ, be used in lieu of section A6.4.1 of ASTM D6348-03 when conducting testing using ASTM D6348-03 under 40 CFR part 60, Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. In your request, you state that this alternative linearity check procedure will produce consistent results when utilizing either Method 320 or ASTM D6348-03. Additionally, some FTIR instrumentation does not allow for reducing the size of the aperture in the instrument and, thus, it would not be feasible to properly conduct the entirety of the ASTM D6348-03 method in its current form using such an instrument. Based on our understanding of FTIR instrument principles and recognition that the requested alternative determination of detector linearity is both technically sound and contained within Method 320, we are approving the requested change. We believe that this alternative is acceptable for use for use in testing all engines subject to 40 CFR part 60 Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. Also, we will post this letter as ALT-141 on EPA’s website (at www.epa.gov/emc/broadly-applicable-approved-alternative- testmethods) to announce that our approval of this alternative test method is broadly applicable to engines for the purposes of meeting Subparts JJJJ and ZZZZ. March 15, 2021 Sincerely, Steffan M. Johnson, Group Leader Measurement Technology Group If you should have any questions or require further information regarding this approval, please contact David Nash of my staff at 919-541-9425 or email at nash.dave@epa.gov. cc: Sara Ayers, EPA/OECA/OC/MAMPD, (ayres.sara@epa.gov) Melanie King, EPA/OAR/OAQPS/SPPD, (king.melanie@epa.gov) James Leather, EPA Region 6, (leather.james@epa.gov) David Nash, EPA/OAR/OAQPS/AQAD, (nash.dave@epa.gov) Heather Sessing, Oklahoma DEQ, (Heather.sessing@deq.ok.gov) Danny Cupp GAS, Inc. Type of Sources Tested: info@gasinc.us Stationary Internal Combustion Engines • 4 Stroke Rich Burn Engines • 2 Stroke & 4 Stroke Lean Burn Engines Stationary Natural Gas Fired Generators Stationary Propane Fired Generators Gas Fired Boilers Qualifications: Trained, studied, and fully demonstrates compliance for emissions testing via data collection outlined in the following Reference Methods: • EPA Method 1 & 1A – Sampling & Traverse Points • EPA Method 2 & 2C – Velocity & Volumetric Flow Rate of a Gas Stream • EPA Method 3A – Oxygen • EPA Method 7E – NOX • EPA Method 10 – Carbon Monoxide • EPA Method 25A – Volatile Organic Compounds • ASTM D6348 – Extractive Fourier Transform Infrared Spectroscopy Conducts emissions testing on a weekly basis including, but not limited to, the following test types: Initial Compliance, Biennial Compliance, Semiannual Compliance & Quarterly Compliance. All tests performed are in accordance to any and all Federal & State requirements as applicable (i.e. JJJJ, ZZZZ, 106.512, 117, PEA, etc.). Performed testing in Colorado, Utah, Wyoming, North Dakota, Montana, Kansas, New Mexico, Oklahoma, Texas, Louisiana (land and off-shore), Arkansas, Ohio, Pennsylvania, West Virginia, New York, Kentucky, & Mississippi. • Quarterly Performance Reviews covering ongoing changes with Federal Regulations, State Compliance guidelines, & site-specific safety certifications. Types of Analyzers: • Gasmet DX4000 FTIR • Gasmet Portable Sampling Unit with Zirconium Oxide O2 Sensory • Testo 350 • Flame Ionization Detector 580-225-0403 Gas, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 1 Minute Average Data Sheet Scout Energy Management, LLCClient: Ashley Compressor Station Unit Number:Unit 1 Make:Caterpillar Location:G3516TALEModel: 4EK02753Serial Number: RAW Result Data Stability 7/31/2024 05:41 0.0000.0003.310 0.014 1.3211.095 0.000 0.000 0.0000.0002.457 0.968 0.0160.000 0.000 850.01.130.703 0.013 0.00 0.14 179.0 Pre Test Baseline Direct 7/31/2024 05:49 0.0000.000-1.282 0.000 0.0000.000 0.111 0.000 0.0000.0000.377 0.000 0.2690.000 0.000 850.00.530.393 0.000 0.00 0.15 179.0 7/31/2024 05:50 0.0000.000-1.289 0.000 0.0000.000 0.103 0.000 0.0000.1870.000 0.000 0.0000.000 0.000 850.00.450.676 0.000 0.00 0.18 179.0 7/31/2024 05:50 0.0000.000-1.350 0.001 0.0000.000 0.119 0.072 0.0000.4590.000 0.000 0.0000.000 0.009 850.00.130.166 0.000 0.00 0.16 180.0 CTS Direct 7/31/2024 05:57 0.0000.000-1.542 0.029 0.3660.000 0.000 0.000 0.7170.3120.000 99.727 0.0000.115 0.000 851.066.680.283 0.000 0.00 0.26 180.0 7/31/2024 05:57 0.4210.000-1.557 0.024 0.0000.000 0.000 0.000 0.3460.4620.000 99.244 0.0000.555 0.000 851.066.170.000 0.000 0.42 0.25 180.0 7/31/2024 05:57 0.0000.000-1.560 0.017 0.0000.000 0.000 0.000 0.0000.0000.000 100.103 0.0000.000 0.000 851.066.840.151 0.000 0.00 0.29 180.0 High O2 Direct 7/31/2024 06:00 0.0000.000-1.595 0.013 1.2770.000 0.000 0.106 0.0000.1470.000 0.000 0.2920.000 0.000 851.00.500.305 0.000 0.00 21.12 180.0 7/31/2024 06:01 0.0000.000-1.556 0.022 0.3510.000 0.000 0.365 0.5320.2280.000 0.000 0.0000.000 0.000 851.00.360.537 0.000 0.00 21.20 180.0 7/31/2024 06:01 0.0800.000-1.570 0.000 0.4570.000 0.000 0.210 0.2410.2260.000 0.000 0.0000.000 0.000 851.00.180.277 0.000 0.08 21.20 180.0 NO2/Mid O2 Direct 7/31/2024 06:08 99.1010.000-1.575 0.000 1.5770.000 0.797 0.000 1.3750.1260.000 0.000 0.0000.000 0.000 851.00.390.583 0.000 99.10 10.66 180.0 7/31/2024 06:09 97.7420.000-1.581 0.000 0.0930.000 0.763 0.000 1.0460.5300.000 0.000 0.0310.000 0.000 851.00.030.000 0.000 97.74 10.64 180.0 7/31/2024 06:09 100.2100.000-1.590 0.000 1.5170.000 0.818 0.000 1.7850.0060.000 0.000 0.0000.087 0.000 851.00.000.003 0.000 100.21 10.65 180.0 Spike Direct 7/31/2024 06:16 0.000248.999-1.576 4.633 0.329494.461 0.711 1.345 2.0210.4900.000 1.893 255.3760.000 0.000 851.0259.814.755 10.086 249.00 0.18 180.0 7/31/2024 06:16 0.000249.280-1.574 4.556 2.761491.784 0.747 1.328 3.3530.7560.000 1.827 254.0230.000 0.000 851.0257.563.484 10.078 249.28 0.20 180.0 7/31/2024 06:17 0.000249.479-1.589 4.604 2.728491.662 0.803 1.639 3.7250.2030.277 1.932 254.4480.000 0.000 851.0258.994.874 10.055 249.48 0.22 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline System 7/31/2024 06:20 0.0000.000-0.031 0.002 0.0000.000 0.002 0.126 0.0000.0000.000 0.000 0.3950.065 0.000 851.01.010.925 0.000 0.00 0.13 180.0 7/31/2024 06:20 0.0000.000-0.031 0.025 0.0000.000 0.000 0.024 0.9430.0090.000 0.000 0.0000.000 0.000 850.00.450.681 0.000 0.00 0.20 179.0 7/31/2024 06:20 0.7800.000-0.032 0.020 0.0000.000 0.000 0.000 0.6550.0000.000 0.000 0.0000.000 0.000 850.00.100.145 0.000 0.78 0.00 179.0 CTS System with Response Time 7/31/2024 06:22 0.0000.000-0.032 0.020 0.0000.000 0.000 0.073 0.1720.0040.000 98.782 0.0000.017 0.037 849.066.330.598 0.000 0.00 0.64 180.0 7/31/2024 06:23 0.0000.000-0.031 0.016 0.1090.000 0.000 0.037 0.0000.0000.000 99.462 0.2390.000 0.000 849.066.600.069 0.000 0.00 1.21 180.0 7/31/2024 06:23 0.0000.000-0.031 0.000 0.0000.000 0.014 0.296 0.0000.0000.000 100.280 0.1940.000 0.000 850.067.050.000 0.000 0.00 1.22 180.0 NO2/Mid O2 System with Response Time 7/31/2024 06:25 98.7031.051-0.031 0.000 1.8240.000 0.828 0.000 1.0780.0000.000 0.000 0.0000.000 0.000 849.00.280.422 0.000 99.75 10.59 180.0 7/31/2024 06:25 97.3901.690-0.032 0.020 1.2020.000 0.790 0.101 1.9630.2200.000 0.000 0.0000.000 0.000 848.00.580.871 0.000 99.08 10.62 180.0 7/31/2024 06:26 99.6980.865-0.032 0.016 1.2630.000 0.802 0.000 0.9280.0000.000 0.000 0.0870.000 0.000 848.00.290.307 0.000 100.56 10.62 179.0 Spike System with Response Time 7/31/2024 06:28 0.000245.949-0.032 4.614 1.414495.191 0.959 1.614 2.5420.1700.000 2.099 254.2470.000 0.000 846.0257.642.985 10.024 245.95 0.02 180.0 7/31/2024 06:28 0.000249.707-0.032 4.616 2.282493.192 0.919 1.757 3.4390.1240.000 1.893 253.2480.000 0.000 844.0256.492.963 10.066 249.71 0.02 180.0 7/31/2024 06:29 0.000247.760-0.032 4.608 2.891493.922 0.917 1.276 2.3940.3870.000 2.012 254.2020.015 0.000 843.0258.173.940 10.055 247.76 0.16 180.0 Baseline System with Response Time 7/31/2024 06:32 0.0000.000-0.032 0.003 0.0430.000 0.039 0.000 0.7860.0220.000 0.000 0.0000.128 0.019 848.00.550.764 0.000 0.00 0.19 180.0 7/31/2024 06:32 0.0000.000-0.032 0.011 0.1410.000 0.000 0.248 1.0540.0000.000 0.000 0.1650.000 0.000 848.00.871.050 0.000 0.00 0.24 180.0 7/31/2024 06:33 0.0000.000-0.032 0.000 0.3480.000 0.002 0.050 0.1180.0000.000 0.000 0.1060.000 0.075 847.00.510.382 0.000 0.00 0.14 180.0 Run 1 - A 30minute/60min 7/31/2024 09:43 48.22762.5247.531 4.995 869.257308.879 0.000 0.000 57.5030.00014.906 60.532 37.4850.000 3.756 818.088.494.704 0.000 110.75 8.98 180.0 7/31/2024 09:44 51.07963.7386.158 5.014 866.837315.384 0.000 0.000 61.4720.0007.247 61.573 39.1020.000 3.446 818.090.545.240 0.000 114.82 9.00 180.0 7/31/2024 09:45 58.22664.0476.121 4.997 875.596314.105 0.000 0.000 63.4910.0007.103 61.369 39.1810.000 3.431 818.090.134.765 0.000 122.27 8.99 179.0 7/31/2024 09:46 55.29863.9726.175 5.040 872.869315.645 0.000 0.000 63.0680.0006.604 61.447 39.1670.000 3.517 818.090.244.612 0.000 119.27 8.95 180.0 7/31/2024 09:47 56.00767.2956.164 4.996 877.438317.569 0.000 0.000 64.3680.0007.263 61.942 40.5140.000 3.647 818.092.334.833 0.000 123.30 8.98 180.0 7/31/2024 09:48 54.49163.9126.192 5.007 885.573314.011 0.000 0.000 65.5630.0007.232 61.969 40.8360.000 3.608 818.092.594.837 0.000 118.40 9.02 179.0 7/31/2024 09:49 60.22865.1786.197 5.071 888.296314.880 0.000 0.000 65.4720.0006.030 61.696 40.1920.000 3.693 818.092.085.051 0.000 125.41 8.85 180.0 7/31/2024 09:50 62.16867.6366.186 5.026 894.411318.221 0.000 0.000 68.2890.0007.403 61.855 40.8630.000 3.544 818.092.535.011 0.000 129.80 9.02 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 7/31/2024 09:51 55.57566.4066.210 5.034 895.394316.521 0.000 0.000 69.1000.0007.082 61.735 42.6830.000 3.422 818.093.924.847 0.000 121.98 9.05 180.0 7/31/2024 09:52 54.00566.8526.193 5.061 894.330317.021 0.000 0.000 67.8370.0007.237 62.046 42.9290.000 3.608 818.095.025.263 0.000 120.86 8.97 180.0 7/31/2024 09:53 54.99262.9706.192 5.041 899.839315.545 0.000 0.000 69.6860.0007.698 62.150 43.1760.000 3.558 818.094.994.896 0.000 117.96 9.02 180.0 7/31/2024 09:55 51.78758.7006.215 5.059 896.812313.489 0.000 0.000 66.8560.0006.885 61.508 41.1400.000 3.822 818.092.904.669 0.000 110.49 9.05 180.0 7/31/2024 09:56 47.03258.5577.133 5.079 885.448303.494 0.000 0.000 63.3160.0007.208 60.241 40.4110.000 3.560 818.090.994.943 0.000 105.59 8.96 180.0 7/31/2024 09:57 47.06861.6508.633 5.038 875.623300.222 0.000 0.000 58.9130.00012.608 59.526 38.0120.000 3.723 818.088.214.602 0.000 108.72 8.84 180.0 7/31/2024 09:58 58.18491.6247.323 5.143 790.949328.600 0.000 0.000 42.4760.0005.225 63.747 29.7550.000 3.436 818.082.905.657 0.000 149.81 8.61 180.0 7/31/2024 09:59 63.075149.2717.678 5.287 738.320359.519 0.000 0.000 31.0050.00010.117 64.564 24.1130.000 3.446 818.078.035.975 0.000 212.35 8.56 179.0 7/31/2024 10:00 78.008169.8716.736 5.323 733.983391.568 0.000 0.000 49.1330.0003.967 65.322 21.9390.000 1.457 818.071.053.976 0.000 247.88 8.69 180.0 7/31/2024 10:01 69.981167.8466.675 5.310 738.679395.597 0.000 0.000 30.7320.0007.852 65.120 24.1860.000 3.341 818.078.476.285 0.000 237.83 8.58 180.0 7/31/2024 10:02 82.036167.1616.735 5.277 737.144394.576 0.000 0.000 47.3260.0005.384 64.961 22.2490.000 1.603 818.071.514.113 0.000 249.20 8.60 179.0 7/31/2024 10:03 70.203173.2568.241 5.367 744.118365.538 0.000 0.000 30.1780.00011.435 63.186 23.7940.000 3.567 818.077.206.225 0.000 243.46 8.61 180.0 7/31/2024 10:04 68.008166.5717.055 5.318 736.383392.768 0.000 0.000 31.7380.0008.986 64.984 24.1610.000 3.519 818.078.776.370 0.000 234.58 8.62 180.0 7/31/2024 10:05 69.652167.1777.857 5.363 744.238365.485 0.000 0.000 30.8380.00011.338 63.945 23.5680.000 3.508 818.077.175.932 0.000 236.83 8.65 180.0 7/31/2024 10:06 70.659168.7656.756 5.318 737.647395.152 0.000 0.000 31.3710.0008.783 65.136 23.2020.000 3.587 818.077.595.677 0.000 239.42 8.62 180.0 7/31/2024 10:07 67.123125.0496.784 5.242 768.825354.262 0.000 0.000 36.5890.0009.160 64.961 26.2260.000 3.665 818.080.886.026 0.000 192.17 8.77 180.0 7/31/2024 10:08 53.39681.5517.396 5.117 823.984324.230 0.000 0.000 49.6250.00011.855 63.463 31.5040.000 3.493 818.084.054.869 0.000 134.95 8.79 180.0 7/31/2024 10:09 57.68992.3956.722 5.205 790.889334.084 0.000 0.000 42.8660.0007.990 64.412 28.2100.000 3.661 818.081.935.176 0.000 150.08 8.85 179.0 7/31/2024 10:10 50.616115.7598.376 5.288 788.618331.102 0.000 0.000 38.1540.00010.914 62.175 25.3550.000 3.875 818.077.955.089 0.000 166.37 8.78 180.0 7/31/2024 10:11 59.980124.1596.508 5.159 766.596347.187 0.000 0.000 38.2240.0008.721 64.866 26.2110.000 3.653 818.080.806.051 0.000 184.14 8.67 180.0 7/31/2024 10:12 66.394126.5297.118 5.285 761.580353.874 0.000 0.000 35.0020.0008.294 63.882 24.2230.000 3.560 818.077.865.896 0.000 192.92 8.71 179.0 7/31/2024 10:13 59.208136.5009.941 5.308 771.794347.133 0.000 0.000 33.2180.00018.993 61.154 23.0140.000 3.770 818.074.514.779 0.000 195.71 8.72 180.0 60.013103.8976.973 5.159 818.382338.855 0.000 0.000 50.1140.0008.717 62.849 32.2470.000 3.449 818.0084.5215.212 0.000 163.911 8.817 179.8Avg. Spike 1 7/31/2024 10:18 66.773148.7766.387 5.238 708.559369.781 0.000 0.000 44.8230.0005.921 59.379 40.0310.000 1.810 818.086.034.182 0.722 215.55 8.05 180.0 Run 1 - B 30minute/60min 7/31/2024 10:20 58.41897.8236.413 5.194 805.011339.427 0.000 0.000 46.1640.0007.998 66.093 29.0530.000 3.790 818.084.525.736 0.000 156.24 8.74 180.0 7/31/2024 10:21 58.52189.4686.444 5.213 795.166337.606 0.000 0.000 44.0770.0007.418 66.006 28.7240.000 3.676 818.083.865.661 0.000 147.99 8.66 180.0 7/31/2024 10:22 60.149102.1006.447 5.293 791.598350.415 0.000 0.000 42.2490.0007.109 67.128 26.2710.000 3.428 818.081.916.045 0.000 162.25 8.60 180.0 7/31/2024 10:23 63.784115.7336.458 5.353 789.086354.963 0.000 0.000 40.7470.0007.221 66.819 25.2650.000 3.558 818.080.645.572 0.000 179.52 8.62 180.0 7/31/2024 10:24 64.058119.6226.526 5.309 779.602357.354 0.000 0.000 39.8970.0007.260 67.265 25.9580.000 3.684 819.082.145.953 0.000 183.68 8.72 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 7/31/2024 10:25 62.228117.0986.477 5.270 780.612355.042 0.000 0.000 39.5990.0008.492 67.352 26.0100.000 3.576 818.082.366.434 0.000 179.33 8.70 179.0 7/31/2024 10:26 63.967114.5436.460 5.262 783.081357.508 0.000 0.000 40.7420.0007.830 67.227 26.0170.000 3.654 819.082.466.478 0.000 178.51 8.71 180.0 7/31/2024 10:27 59.735120.5339.817 5.328 790.630321.102 0.000 0.000 34.9600.00016.671 62.113 24.9820.000 4.062 819.078.085.341 0.000 180.27 8.54 180.0 7/31/2024 10:28 63.001115.6587.384 5.311 780.194349.252 0.000 0.000 37.4850.00013.712 65.333 25.0400.000 3.723 819.079.735.534 0.000 178.66 8.53 180.0 7/31/2024 10:29 60.505118.3868.648 5.375 787.644343.321 0.000 0.000 36.4530.00012.066 63.368 25.2380.000 3.843 819.078.705.288 0.000 178.89 8.54 180.0 7/31/2024 10:30 61.500117.1796.474 5.255 776.163357.955 0.000 0.000 40.3000.0008.259 66.857 26.4910.000 3.516 818.081.925.730 0.000 178.68 8.60 180.0 7/31/2024 10:31 69.359115.4636.422 5.275 781.337355.640 0.000 0.000 38.6410.0007.938 66.528 25.9670.000 3.593 818.081.666.224 0.000 184.82 8.69 180.0 7/31/2024 10:32 66.909114.3616.422 5.276 776.934355.019 0.000 0.000 38.5390.0007.503 65.871 25.9360.000 3.522 818.080.625.591 0.000 181.27 8.72 180.0 7/31/2024 10:34 62.311117.8148.040 5.324 785.556342.239 0.000 0.000 37.0510.0009.950 63.237 25.1360.000 3.757 819.078.926.161 0.000 180.12 8.59 180.0 7/31/2024 10:35 60.755112.5177.936 5.273 787.095350.857 0.000 0.000 36.1660.00015.492 64.439 24.9490.000 3.800 818.079.375.789 0.000 173.27 8.65 180.0 7/31/2024 10:36 62.595118.6676.463 5.282 775.925356.949 0.000 0.000 38.7530.0007.901 65.769 25.5000.000 3.606 819.080.295.595 0.000 181.26 8.61 180.0 7/31/2024 10:37 64.779114.7746.516 5.289 778.458356.264 0.000 0.000 38.5150.0008.668 66.250 25.6240.000 3.578 818.080.615.496 0.000 179.55 8.57 180.0 7/31/2024 10:38 69.182116.6916.492 5.263 781.451355.449 0.000 0.000 39.4580.0007.858 65.611 25.4970.000 3.556 819.080.235.815 0.000 185.87 8.59 180.0 7/31/2024 10:39 63.798113.7796.454 5.258 786.036353.431 0.000 0.000 38.2560.0007.258 65.105 25.2580.000 3.505 819.079.645.954 0.000 177.58 8.72 180.0 7/31/2024 10:40 65.035112.3336.474 5.239 785.690356.542 0.000 0.000 38.9710.0008.074 65.241 25.6070.000 3.545 819.080.216.024 0.000 177.37 8.69 180.0 7/31/2024 10:41 63.437116.6447.527 5.299 787.864344.895 0.000 0.000 38.1180.0008.536 63.778 25.7300.000 3.690 818.079.325.533 0.000 180.08 8.73 179.0 7/31/2024 10:42 64.118111.8959.654 5.217 789.486339.555 0.000 0.000 35.0640.00019.929 62.454 24.5410.000 3.991 819.077.635.211 0.000 176.01 8.60 180.0 7/31/2024 10:43 68.048110.8186.706 5.234 785.913355.629 0.000 0.000 39.2460.00010.921 65.222 26.4610.000 3.471 819.080.625.606 0.000 178.87 8.65 180.0 7/31/2024 10:44 67.605113.6656.526 5.255 788.029353.941 0.000 0.000 39.1160.0008.319 65.456 25.6690.000 3.533 819.080.295.879 0.000 181.27 8.61 180.0 7/31/2024 10:45 66.201111.1206.461 5.232 779.229356.730 0.000 0.000 39.1970.0008.210 65.572 25.6520.000 3.479 819.080.155.727 0.000 177.32 8.71 180.0 7/31/2024 10:46 65.572112.1617.299 5.265 777.939350.690 0.000 0.000 37.4860.0009.097 64.404 25.4680.000 3.726 819.079.435.365 0.000 177.73 8.68 179.0 7/31/2024 10:47 63.798113.2166.487 5.259 777.605353.316 0.000 0.000 38.8690.0007.830 65.433 26.1200.000 3.420 819.080.385.694 0.000 177.01 8.69 180.0 7/31/2024 10:48 68.031111.7936.538 5.215 781.242357.293 0.000 0.000 39.6530.0008.871 65.850 26.2410.000 3.565 819.081.245.952 0.000 179.82 8.70 180.0 7/31/2024 10:49 62.986109.7907.180 5.277 784.789352.392 0.000 0.000 39.9110.0009.725 64.997 25.9520.000 3.679 819.080.535.836 0.000 172.78 8.65 179.0 7/31/2024 10:50 68.640112.5816.579 5.285 786.496357.366 0.000 0.000 40.6080.0008.441 65.800 25.8720.000 3.610 819.080.755.681 0.000 181.22 8.64 180.0 63.968112.9416.991 5.273 784.529350.938 0.000 0.000 39.1430.0009.485 65.419 25.8740.000 3.638 818.6380.6075.764 0.000 176.908 8.648 179.9Avg. 61.990108.4196.982 5.216 801.456344.897 0.000 0.000 44.6280.0009.101 64.134 29.0610.000 3.544 818.3282.5645.488 0.000 170.409 8.733 179.8Run 1 Avg: Baseline 1 7/31/2024 10:53 0.0000.000-0.010 0.000 0.0390.000 0.124 0.000 0.1310.0021.351 0.000 0.3650.000 0.038 819.00.780.515 0.000 0.00 0.00 180.0 Run 2 - A 30minute/60min 7/31/2024 10:56 71.291115.0876.047 5.259 779.124355.863 0.000 0.000 40.9330.0006.562 65.871 25.4350.000 3.701 819.080.455.551 0.000 186.38 8.64 180.0 7/31/2024 10:57 70.290117.6496.367 5.277 780.998357.598 0.000 0.000 41.8340.0007.709 66.861 26.1180.000 3.659 819.081.615.397 0.000 187.94 8.59 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 7/31/2024 10:58 67.389115.8026.507 5.285 790.021359.548 0.000 0.000 42.2730.0008.751 66.633 26.1360.000 3.599 819.081.575.718 0.000 183.19 8.62 180.0 7/31/2024 10:59 67.396112.0356.563 5.255 784.314356.629 0.000 0.000 41.1620.0008.530 66.250 26.1450.000 3.605 819.081.576.070 0.000 179.43 8.55 178.0 7/31/2024 11:00 66.145114.9606.610 5.308 789.292354.969 0.000 0.000 40.7690.0008.169 66.025 25.3390.000 3.731 819.080.655.746 0.000 181.11 8.60 180.0 7/31/2024 11:01 66.909113.4006.671 5.283 793.775360.333 0.000 0.000 43.6420.0008.430 66.573 25.8100.000 3.778 819.081.505.619 0.000 180.31 8.60 180.0 7/31/2024 11:02 67.268115.9366.702 5.302 793.057361.592 0.000 0.000 41.4610.0009.221 67.340 26.2360.000 3.878 819.082.885.994 0.000 183.20 8.58 180.0 7/31/2024 11:03 67.695116.2026.731 5.338 792.543360.997 0.000 0.000 42.0980.0009.260 67.163 26.1290.000 3.866 819.082.565.890 0.000 183.90 8.57 180.0 7/31/2024 11:04 64.183114.2346.754 5.311 796.722360.158 0.000 0.000 42.9180.0008.928 67.426 26.6260.000 3.764 819.082.865.633 0.000 178.42 8.59 180.0 7/31/2024 11:05 66.625117.9866.771 5.314 794.728360.512 0.000 0.000 41.4320.0008.912 67.299 25.5760.000 3.831 819.081.935.730 0.000 184.61 8.60 180.0 7/31/2024 11:06 64.441116.45912.136 5.064 804.633326.157 0.000 0.000 38.4730.00027.419 60.530 23.7350.000 4.527 819.076.254.667 0.000 180.90 8.55 180.0 7/31/2024 11:07 66.508118.2236.867 5.273 790.683360.217 0.000 0.000 41.9920.00010.164 67.289 25.3960.000 3.951 819.082.015.783 0.000 184.73 8.69 180.0 7/31/2024 11:08 68.216118.5606.854 5.238 782.238358.648 0.000 0.000 41.4490.0009.405 67.617 26.3450.000 3.775 819.083.216.356 0.000 186.78 8.61 180.0 7/31/2024 11:09 62.326115.10210.009 5.303 791.131339.360 0.000 0.000 38.6430.00017.466 63.340 24.8450.000 4.298 819.078.934.896 0.000 177.43 8.61 179.0 7/31/2024 11:10 69.225117.1756.884 5.299 782.029354.088 0.000 0.000 41.8780.0006.663 66.804 24.9350.000 3.974 819.081.095.498 0.000 186.40 8.52 180.0 7/31/2024 11:12 70.929116.0986.821 5.247 792.181357.427 0.000 0.000 41.0670.00010.078 67.293 25.2930.000 3.983 819.082.146.031 0.000 187.03 8.60 180.0 7/31/2024 11:13 67.426118.3726.829 5.230 778.042357.975 0.000 0.000 41.5730.00010.152 67.516 25.3830.000 4.027 819.081.985.296 0.000 185.80 8.56 179.0 7/31/2024 11:14 69.398119.3666.849 5.268 779.305360.391 0.000 0.000 43.1460.00010.179 67.731 26.7810.000 3.711 819.083.396.052 0.000 188.76 8.61 180.0 7/31/2024 11:15 68.207116.5296.785 5.241 782.777359.008 0.000 0.000 41.7080.0009.914 67.516 26.0090.000 4.141 819.083.025.576 0.000 184.74 8.64 180.0 7/31/2024 11:16 71.802115.8496.764 5.247 783.303357.195 0.000 0.000 42.4180.0009.888 67.397 26.0090.000 4.052 819.083.005.935 0.000 187.65 8.61 180.0 7/31/2024 11:17 68.292114.5886.772 5.222 783.803358.339 0.000 0.000 42.4180.0005.758 67.745 26.3350.000 3.816 819.083.216.109 0.000 182.88 8.61 179.0 7/31/2024 11:18 71.146115.0476.790 5.256 780.496356.564 0.000 0.000 41.7120.0005.861 67.322 26.1310.000 3.926 819.082.815.920 0.000 186.19 8.75 180.0 7/31/2024 11:19 70.250117.8036.814 5.262 782.921358.595 0.000 0.000 42.9120.0009.470 67.875 25.7850.000 4.018 819.083.236.233 0.000 188.05 8.65 180.0 7/31/2024 11:20 68.116115.1226.836 5.237 778.013360.097 0.000 0.000 42.6150.0006.099 68.113 27.1530.000 3.809 819.083.965.672 0.000 183.24 8.63 180.0 7/31/2024 11:21 68.506115.9716.798 5.254 782.627358.010 0.000 0.000 42.3970.00010.041 67.806 26.2310.000 3.814 819.082.755.522 0.000 184.48 8.65 179.0 7/31/2024 11:22 65.962116.2586.848 5.266 773.062360.154 0.000 0.000 41.6510.00010.111 67.851 27.2720.000 3.941 819.084.686.439 0.000 182.22 8.56 180.0 7/31/2024 11:23 69.503116.8686.851 5.248 784.766361.417 0.000 0.000 42.6980.00010.070 67.215 26.7030.000 4.196 819.083.375.196 0.000 186.37 8.63 179.0 7/31/2024 11:24 65.987114.9307.375 5.311 788.058359.435 0.000 0.000 41.7840.00010.397 67.107 27.4040.000 4.037 819.084.135.867 0.000 180.92 8.54 180.0 7/31/2024 11:25 64.623112.8376.934 5.263 782.926361.434 0.000 0.000 42.2000.00010.415 68.373 27.6610.000 3.813 819.084.956.116 0.000 177.46 8.65 180.0 7/31/2024 11:26 70.581117.9756.887 5.246 786.072358.865 0.000 0.000 43.4630.00010.809 67.981 26.7640.000 3.913 819.083.705.676 0.000 188.56 8.63 179.0 67.888116.0817.048 5.264 786.121357.053 0.000 0.000 41.8240.0009.828 66.929 26.0570.000 3.904 819.0082.3135.740 0.000 183.969 8.608 179.7Avg. Spike 2 7/31/2024 11:29 67.652131.4257.047 5.242 719.920354.981 0.000 0.000 49.4180.0007.189 60.332 42.4300.000 2.408 819.090.133.991 0.746 199.08 8.11 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Run 2 - B 30minute/60min 7/31/2024 11:31 72.051118.8136.811 5.243 773.559361.200 0.000 0.000 40.5520.0005.755 67.986 26.7500.000 4.125 819.084.356.039 0.000 190.86 8.70 180.0 7/31/2024 11:32 66.949119.7298.097 5.276 775.641352.303 0.000 0.000 39.0380.0009.783 66.333 25.6120.000 4.396 819.082.285.484 0.000 186.68 8.63 180.0 7/31/2024 11:33 73.566118.1346.899 5.207 774.690356.533 0.000 0.000 40.1320.0006.549 67.518 26.2450.000 4.168 819.083.515.876 0.000 191.70 8.62 179.0 7/31/2024 11:34 64.771119.0568.855 5.333 788.312343.662 0.000 0.000 37.4220.00015.001 64.843 25.6370.000 4.409 819.081.415.590 0.000 183.83 8.62 180.0 7/31/2024 11:35 74.390117.9657.238 5.225 771.327359.341 0.000 0.000 40.2840.0009.912 67.052 26.2530.000 4.144 819.083.286.047 0.000 192.35 8.66 180.0 7/31/2024 11:36 70.416117.5956.877 5.243 772.328357.020 0.000 0.000 40.3210.0006.491 67.342 26.3780.000 4.176 819.083.746.174 0.000 188.01 8.61 180.0 7/31/2024 11:37 70.472117.1126.938 5.242 772.229357.799 0.000 0.000 39.4950.00010.256 67.420 26.6220.000 4.046 819.083.625.934 0.000 187.58 8.66 180.0 7/31/2024 11:38 67.349118.5126.935 5.255 782.853361.087 0.000 0.000 40.5860.0006.772 67.323 26.7560.000 3.852 819.083.716.554 0.000 185.86 8.60 180.0 7/31/2024 11:39 69.731116.8036.893 5.257 781.633356.748 0.000 0.000 40.2450.00010.250 67.055 26.1640.000 3.918 819.082.796.126 0.000 186.53 8.58 180.0 7/31/2024 11:40 74.770119.3496.840 5.257 767.748360.409 0.000 0.000 39.7790.0006.242 67.367 26.4710.000 4.191 819.083.976.306 0.000 194.12 8.60 180.0 7/31/2024 11:41 66.463118.12710.815 5.469 779.512336.851 0.000 0.000 34.8480.00019.714 61.872 25.7570.000 4.837 819.079.103.635 0.000 184.59 8.63 180.0 7/31/2024 11:42 70.950120.2246.975 5.255 774.175359.782 0.000 0.000 39.1470.0006.794 67.059 26.8520.000 4.201 819.083.895.888 0.000 191.17 8.61 180.0 7/31/2024 11:43 70.113119.6577.701 5.373 776.680357.642 0.000 0.000 38.0840.0006.944 65.678 26.1660.000 4.280 819.082.375.782 0.000 189.77 8.60 180.0 7/31/2024 11:44 72.175117.7317.008 5.269 775.312358.564 0.000 0.000 40.8480.00010.590 67.012 26.7880.000 3.938 819.083.516.258 0.000 189.91 8.63 180.0 7/31/2024 11:45 71.458123.3116.964 5.214 763.902362.599 0.000 0.000 38.4300.0006.585 67.622 26.8400.000 4.255 819.084.806.549 0.000 194.77 8.69 180.0 7/31/2024 11:46 68.479121.1766.918 5.285 771.366361.607 0.000 0.000 39.7140.0006.449 67.369 26.7040.000 4.070 819.083.856.142 0.000 189.66 8.64 180.0 7/31/2024 11:47 74.396121.2236.918 5.288 768.773358.132 0.000 0.000 40.2100.00010.381 67.223 26.0130.000 4.172 819.083.326.211 0.000 195.62 8.70 180.0 7/31/2024 11:48 70.575120.4856.983 5.252 772.077361.428 0.000 0.000 39.5390.0006.453 67.456 27.1240.000 3.990 819.084.176.145 0.000 191.06 8.69 180.0 7/31/2024 11:49 73.386118.9157.008 5.260 781.805358.426 0.000 0.000 39.5340.0006.347 67.122 26.2160.000 4.101 819.083.216.054 0.000 192.30 8.63 180.0 7/31/2024 11:50 69.891121.8586.946 5.264 764.719358.442 0.000 0.000 38.6910.00010.950 66.836 26.3740.000 3.930 819.083.126.485 0.000 191.75 8.64 180.0 7/31/2024 11:52 68.802120.3716.957 5.247 763.293363.435 0.000 0.000 38.2920.0007.448 67.411 26.9030.000 4.096 819.083.855.711 0.000 189.17 8.69 179.0 7/31/2024 11:53 70.593119.3356.930 5.280 768.958359.610 0.000 0.000 37.9630.0007.041 67.379 26.7490.000 4.072 819.083.765.922 0.000 189.93 8.73 180.0 7/31/2024 11:54 70.952119.0586.957 5.260 766.524361.977 0.000 0.000 38.8440.0006.728 67.277 27.2630.000 4.021 819.084.566.604 0.000 190.01 8.70 180.0 7/31/2024 11:55 74.400115.6886.968 5.222 773.021361.858 0.000 0.000 38.7650.0007.051 67.685 27.6730.000 4.007 819.084.986.255 0.000 190.09 8.52 179.0 7/31/2024 11:56 73.112120.4116.957 5.284 771.744363.458 0.000 0.000 39.5090.0006.847 67.794 27.0110.000 3.963 819.084.306.250 0.000 193.52 8.57 180.0 7/31/2024 11:57 74.212121.8246.946 5.277 767.575365.280 0.000 0.000 39.3570.0006.352 68.365 27.2760.000 4.112 819.085.166.127 0.000 196.04 8.63 180.0 7/31/2024 11:58 71.901120.3996.953 5.283 767.042363.262 0.000 0.000 39.0570.0006.021 67.981 27.3410.000 3.957 819.084.696.171 0.000 192.30 8.57 180.0 7/31/2024 11:59 73.642119.8876.968 5.271 766.534365.759 0.000 0.000 38.1570.0007.072 68.067 27.6250.000 3.954 819.085.226.455 0.000 193.53 8.66 180.0 7/31/2024 12:00 74.483119.9516.974 5.276 762.948363.422 0.000 0.000 39.3760.0006.576 67.479 27.6140.000 4.008 819.084.826.307 0.000 194.43 8.71 180.0 7/31/2024 12:01 69.065120.8098.069 5.291 776.447354.155 0.000 0.000 38.9380.0008.470 66.255 27.2520.000 3.934 819.083.426.193 0.000 189.87 8.62 180.0 71.117119.4507.243 5.272 772.424358.726 0.000 0.000 39.1720.0008.261 67.039 26.6810.000 4.111 819.0083.6256.042 0.000 190.567 8.638 179.9Avg. 69.502117.7667.145 5.268 779.273357.889 0.000 0.000 40.4980.0009.044 66.984 26.3690.000 4.008 819.0082.9695.891 0.000 187.268 8.623 179.8Run 2 Avg: GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline 2 7/31/2024 12:04 0.0000.000-0.002 0.113 0.0000.000 0.010 0.307 0.0300.1362.845 0.000 0.2870.000 0.035 819.00.870.774 0.000 0.00 0.17 180.0 Run 3 - A 30minute/60min 7/31/2024 12:07 72.176119.9826.522 5.248 756.004360.927 0.000 0.000 37.9780.0005.022 68.108 27.1810.000 4.024 819.085.096.680 0.000 192.16 8.54 180.0 7/31/2024 12:08 72.835119.1256.731 5.295 763.356362.579 0.000 0.000 39.9680.0005.395 68.290 27.3640.000 4.003 819.084.956.077 0.000 191.96 8.51 180.0 7/31/2024 12:09 72.928118.6396.828 5.259 768.217360.404 0.000 0.000 38.8630.0005.624 68.677 28.2520.000 3.894 819.086.557.078 0.000 191.57 8.54 180.0 7/31/2024 12:10 72.991119.8406.882 5.278 762.506362.414 0.000 0.000 37.9500.0005.322 68.063 27.4560.000 4.064 819.085.206.363 0.000 192.83 8.45 179.0 7/31/2024 12:11 73.383120.5646.874 5.273 766.986362.410 0.000 0.000 38.9680.0005.767 67.860 27.0790.000 3.992 819.084.586.415 0.000 193.95 8.52 180.0 7/31/2024 12:12 72.375123.2606.922 5.272 768.394363.833 0.000 0.000 37.6460.0006.290 68.454 26.7950.000 4.028 819.084.606.165 0.000 195.63 8.57 180.0 7/31/2024 12:13 75.749122.8106.934 5.285 761.991362.937 0.000 0.000 37.7700.0005.915 68.625 26.8460.000 4.151 819.084.645.609 0.000 198.56 8.67 180.0 7/31/2024 12:14 73.657121.1666.911 5.245 764.442359.264 0.000 0.000 37.4810.0006.652 68.077 26.9130.000 4.226 819.084.846.134 0.000 194.82 8.57 180.0 7/31/2024 12:15 72.053121.0096.903 5.247 757.697362.317 0.000 0.000 39.6740.0006.583 67.969 27.2750.000 4.077 819.084.876.190 0.000 193.06 8.69 179.0 7/31/2024 12:16 74.380120.6736.926 5.261 763.105359.725 0.000 0.000 37.0190.0005.982 67.629 27.1100.000 4.066 819.084.416.115 0.000 195.05 8.62 180.0 7/31/2024 12:17 73.439122.1336.888 5.254 761.522359.119 0.000 0.000 39.2700.0006.236 67.594 27.3050.000 3.858 819.084.596.752 0.000 195.57 8.67 180.0 7/31/2024 12:18 77.075124.2246.890 5.222 755.402361.372 0.000 0.000 38.6590.0006.183 68.028 27.5490.000 3.958 819.085.196.563 0.000 201.30 8.64 180.0 7/31/2024 12:19 72.578122.1776.908 5.218 765.602360.892 0.000 0.000 37.9750.0006.934 68.455 27.5710.000 4.006 819.085.726.741 0.000 194.75 8.76 180.0 7/31/2024 12:20 64.982119.6399.392 5.289 771.079351.358 0.000 0.000 35.3100.00014.039 65.541 26.4840.000 4.355 819.082.755.785 0.000 184.62 8.62 180.0 7/31/2024 12:21 71.522122.1257.221 5.261 762.674360.282 0.000 0.000 36.2710.0009.195 67.704 27.5050.000 4.057 819.084.856.141 0.000 193.65 8.69 180.0 7/31/2024 12:22 72.908123.2267.502 5.272 762.102359.705 0.000 0.000 36.8430.0005.937 67.517 27.5490.000 3.917 819.084.596.296 0.000 196.13 8.64 180.0 7/31/2024 12:23 68.867124.6809.062 5.255 774.976354.781 0.000 0.000 35.7750.00016.947 66.560 27.3790.000 4.278 819.084.235.882 0.000 193.55 8.58 180.0 7/31/2024 12:24 77.377122.8127.731 5.329 764.123360.981 0.000 0.000 37.2630.0008.172 67.918 28.2520.000 4.099 819.085.916.262 0.000 200.19 8.60 180.0 7/31/2024 12:25 77.681121.5727.054 5.248 761.228366.170 0.000 0.000 37.7990.0006.854 68.289 28.3220.000 4.078 819.086.586.855 0.000 199.25 8.56 179.0 7/31/2024 12:26 69.087123.4117.059 5.312 772.533361.835 0.000 0.000 38.1420.0006.870 68.585 28.2300.000 3.815 819.085.866.409 0.000 192.50 8.60 180.0 7/31/2024 12:27 70.386124.0947.383 5.301 770.650363.405 0.000 0.000 38.5290.0007.576 68.286 27.8970.000 3.977 819.085.386.006 0.000 194.48 8.58 180.0 7/31/2024 12:28 70.713123.9797.738 5.357 774.519364.914 0.000 0.000 37.4110.0006.779 67.983 27.4920.000 4.193 819.085.155.920 0.000 194.69 8.57 180.0 7/31/2024 12:30 71.203124.0898.123 5.375 772.544360.503 0.000 0.000 38.3820.0008.745 67.465 28.0860.000 4.050 819.085.196.033 0.000 195.29 8.58 180.0 7/31/2024 12:31 70.809123.7007.131 5.294 756.092365.068 0.000 0.000 37.8930.0008.095 68.912 28.2040.000 4.199 819.086.776.341 0.000 194.51 8.51 180.0 7/31/2024 12:32 71.454123.2647.101 5.305 763.842364.103 0.000 0.000 37.7380.0007.234 68.771 27.8490.000 4.099 819.086.456.827 0.000 194.72 8.48 180.0 7/31/2024 12:33 70.548125.4657.954 5.437 762.548360.109 0.000 0.000 37.1190.0005.851 66.948 27.5720.000 4.055 819.084.135.722 0.000 196.01 8.52 180.0 7/31/2024 12:34 72.886124.8537.619 5.321 754.823360.503 0.000 0.000 35.3540.0009.311 67.508 26.8420.000 4.102 819.083.925.797 0.000 197.74 8.64 180.0 7/31/2024 12:35 79.228124.9987.056 5.246 754.389362.092 0.000 0.000 36.9260.0007.619 68.923 28.5040.000 3.978 819.086.966.818 0.000 204.23 8.57 180.0 7/31/2024 12:36 77.973122.5377.044 5.241 756.939363.535 0.000 0.000 37.2390.0007.141 68.663 28.5430.000 4.013 819.086.766.623 0.000 200.51 8.71 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 7/31/2024 12:37 69.673115.4717.005 5.188 747.114356.250 0.000 0.000 35.0010.0006.935 67.201 27.6870.000 4.021 819.084.776.359 0.000 185.14 8.57 180.0 72.764122.1847.276 5.280 763.247361.126 0.000 0.000 37.6070.0007.374 67.953 27.5700.000 4.054 819.0085.1836.299 0.000 194.947 8.592 179.9Avg. Spike 3 7/31/2024 12:39 77.853130.0816.415 5.180 703.128367.317 0.000 0.000 45.5300.0009.272 62.105 44.7550.000 2.050 819.093.184.379 0.776 207.93 7.98 180.0 Run 3 - B 30minute/60min 7/31/2024 12:41 74.298122.3946.962 5.286 764.550366.404 0.000 0.000 37.5700.0007.001 68.733 27.8130.000 4.097 819.086.026.280 0.000 196.69 8.59 180.0 7/31/2024 12:42 75.588122.9427.015 5.281 759.103365.233 0.000 0.000 37.3370.0007.352 68.635 28.2820.000 3.781 819.086.166.829 0.000 198.53 8.60 180.0 7/31/2024 12:43 75.992125.2677.019 5.255 757.992365.131 0.000 0.000 36.1930.0006.724 68.345 27.6500.000 4.031 819.085.566.416 0.000 201.26 8.62 180.0 7/31/2024 12:44 73.083122.2057.003 5.226 759.514363.088 0.000 0.000 35.9930.0006.803 68.166 26.9230.000 4.117 819.085.106.746 0.000 195.29 8.69 179.0 7/31/2024 12:45 71.151121.3887.045 5.296 763.088363.666 0.000 0.000 36.5260.0006.397 68.141 27.1360.000 4.000 819.084.626.081 0.000 192.54 8.76 180.0 7/31/2024 12:46 75.250122.1897.064 5.275 764.984364.869 0.000 0.000 35.7350.0006.518 68.279 27.5370.000 3.987 819.085.356.477 0.000 197.44 8.58 180.0 7/31/2024 12:47 73.174122.9827.073 5.279 759.806365.600 0.000 0.000 35.8750.0006.662 68.814 27.9450.000 4.109 819.086.256.317 0.000 196.16 8.57 180.0 7/31/2024 12:48 77.433125.8177.058 5.279 769.500368.696 0.000 0.000 36.6070.0006.612 68.658 27.5490.000 3.907 819.085.386.358 0.000 203.25 8.55 180.0 7/31/2024 12:49 73.276126.2297.079 5.288 773.752365.942 0.000 0.000 35.9550.0006.936 68.080 27.0000.000 4.094 819.085.136.822 0.000 199.51 8.60 180.0 7/31/2024 12:50 69.415125.6949.655 5.433 771.398346.965 0.000 0.000 33.3940.00011.425 63.775 26.0140.000 4.407 819.080.534.768 0.000 195.11 8.58 180.0 7/31/2024 12:51 68.863124.2588.576 5.293 769.853357.916 0.000 0.000 35.6740.00017.466 66.338 26.9990.000 4.278 819.083.585.691 0.000 193.12 8.56 180.0 7/31/2024 12:52 72.065120.5607.292 5.292 759.551363.322 0.000 0.000 34.9370.0006.449 67.450 27.2070.000 4.182 819.084.566.027 0.000 192.63 8.60 180.0 7/31/2024 12:53 75.824120.3247.394 5.263 766.144362.552 0.000 0.000 35.2360.0009.542 67.336 26.9480.000 4.153 819.084.145.987 0.000 196.15 8.55 180.0 7/31/2024 12:54 74.047120.6757.520 5.319 769.767362.560 0.000 0.000 33.9950.0008.067 66.523 26.9650.000 4.262 819.084.146.443 0.000 194.72 8.66 180.0 7/31/2024 12:55 73.450115.3587.094 5.254 773.207362.315 0.000 0.000 36.4830.0007.536 66.538 27.0640.000 3.972 819.083.936.840 0.000 188.81 8.70 180.0 7/31/2024 12:56 72.112120.1577.102 5.239 771.638361.661 0.000 0.000 34.8150.0007.726 67.221 26.7570.000 4.126 818.084.196.541 0.000 192.27 8.59 180.0 7/31/2024 12:57 71.852119.5427.054 5.259 762.781364.142 0.000 0.000 35.1230.0007.613 66.725 26.9390.000 4.272 818.084.226.373 0.000 191.39 8.60 179.0 7/31/2024 12:58 70.354118.2087.079 5.253 767.528365.889 0.000 0.000 35.3440.0007.143 66.603 26.8280.000 4.231 818.084.036.503 0.000 188.56 8.65 180.0 7/31/2024 12:59 69.623121.0037.757 5.320 769.623362.182 0.000 0.000 34.3680.0007.665 65.970 27.5570.000 4.016 818.083.475.849 0.000 190.63 8.66 180.0 7/31/2024 13:00 73.347112.8497.076 5.229 763.825363.154 0.000 0.000 34.4110.0007.660 65.788 26.6800.000 4.245 819.082.715.515 0.000 186.20 8.69 180.0 7/31/2024 13:01 73.567113.5017.090 5.214 767.381364.702 0.000 0.000 35.3810.0007.963 66.635 27.6580.000 3.954 819.083.755.637 0.000 187.07 8.69 180.0 7/31/2024 13:02 78.922119.1287.083 5.244 759.963366.318 0.000 0.000 34.2730.0007.654 66.989 26.8380.000 4.272 818.083.525.211 0.000 198.05 8.62 180.0 7/31/2024 13:03 76.003116.7897.060 5.291 757.340365.413 0.000 0.000 34.9560.0007.583 66.933 27.8830.000 4.108 818.084.375.465 0.000 192.79 8.70 180.0 7/31/2024 13:04 77.806121.2317.048 5.271 773.688367.111 0.000 0.000 35.2020.0007.611 67.247 27.3740.000 3.988 818.083.815.445 0.000 199.04 8.63 180.0 7/31/2024 13:05 73.616116.8507.035 5.288 772.120369.287 0.000 0.000 36.0250.0007.102 66.882 27.7390.000 4.015 818.084.295.904 0.000 190.47 8.64 180.0 7/31/2024 13:06 75.995112.6927.055 5.240 768.039368.347 0.000 0.000 35.9810.0007.892 66.368 28.2270.000 3.996 818.084.566.146 0.000 188.69 8.65 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 7/31/2024 13:07 77.970120.5917.031 5.247 758.021365.221 0.000 0.000 34.4480.0006.767 67.378 27.2550.000 4.255 818.084.375.527 0.000 198.56 8.66 180.0 7/31/2024 13:09 70.524119.7768.030 5.425 763.863359.560 0.000 0.000 34.0480.0005.113 64.690 26.8400.000 4.362 818.081.944.870 0.000 190.30 8.62 180.0 7/31/2024 13:10 73.981111.9677.753 5.225 773.055364.079 0.000 0.000 35.6130.00012.131 66.477 28.0720.000 4.079 818.084.185.438 0.000 185.95 8.62 180.0 7/31/2024 13:11 77.304118.8057.055 5.263 765.721366.811 0.000 0.000 36.3340.0006.885 67.276 27.1830.000 4.153 818.084.125.660 0.000 196.11 8.64 180.0 73.863120.0467.305 5.278 765.893363.938 0.000 0.000 35.4610.0007.867 67.100 27.2950.000 4.115 818.5784.2666.006 0.000 193.910 8.629 179.9Avg. 73.313121.1157.291 5.279 764.570362.532 0.000 0.000 36.5340.0007.620 67.527 27.4330.000 4.085 818.7884.7246.152 0.000 194.429 8.611 179.9Run 3 Avg: Baseline 3 7/31/2024 13:14 0.0000.000-0.022 0.072 0.0000.443 0.055 0.008 0.0000.0050.000 0.000 0.0000.000 0.099 818.00.200.000 0.000 0.00 0.14 180.0 Post CTS 7/31/2024 13:16 0.0000.000-0.028 0.092 0.2940.000 0.026 0.000 1.6970.0000.000 102.408 0.0000.000 0.056 818.068.780.582 0.000 0.00 0.18 180.0 7/31/2024 13:16 0.0000.000-0.027 0.067 0.1790.000 0.020 0.000 1.3601.5440.000 103.084 0.0000.000 0.000 818.068.730.000 0.000 0.00 0.21 180.0 7/31/2024 13:17 0.0000.000-0.028 0.055 0.0000.000 0.093 0.152 0.0730.1640.000 103.777 0.1770.225 0.097 818.069.870.463 0.000 0.00 0.07 180.0 Post NO2/Mid O2 7/31/2024 13:19 97.6280.000-0.025 0.081 3.9922.105 0.793 0.000 0.9510.0000.472 0.000 0.0000.000 0.041 818.00.831.125 0.000 97.63 10.24 180.0 7/31/2024 13:19 100.3860.000-0.027 0.073 3.0800.540 0.703 0.000 1.2920.7082.456 0.000 0.0000.000 0.023 818.00.080.049 0.000 100.39 10.38 180.0 7/31/2024 13:19 98.0410.000-0.027 0.090 1.4860.738 0.963 0.000 0.0000.3090.000 0.014 0.0000.000 0.274 818.00.980.637 0.000 98.04 10.44 180.0 Post 5-Gas 7/31/2024 13:22 0.000233.850-0.029 4.633 0.000482.249 0.895 1.929 2.5360.0000.000 2.161 254.6160.000 0.000 818.0257.752.539 10.034 233.85 0.02 180.0 7/31/2024 13:22 0.000234.545-0.030 4.575 0.000478.508 0.886 1.702 2.2680.0001.926 2.038 254.0200.903 0.000 818.0257.242.791 10.026 234.55 0.15 180.0 7/31/2024 13:22 0.000234.846-0.029 4.594 1.232483.181 0.979 1.485 3.8540.0004.645 2.008 254.4490.000 0.000 818.0258.173.576 10.042 234.85 0.22 180.0 7/31/2024 13:22 0.000232.051-0.028 4.708 2.021481.247 1.086 1.535 2.4860.0003.837 2.073 255.2800.000 0.000 818.0259.844.762 10.030 232.05 0.21 180.0 7/31/2024 13:22 0.000236.465-0.029 4.545 1.497483.473 0.941 1.958 2.0431.4753.933 2.054 253.7360.000 0.079 818.0256.942.514 10.020 236.46 0.02 180.0 7/31/2024 13:22 0.000232.608-0.029 4.630 1.991483.863 0.986 1.405 1.8680.5361.453 2.095 254.1270.537 0.000 818.0258.364.249 10.026 232.61 0.21 180.0 End of Test Purge 7/31/2024 13:24 0.0000.000-0.030 0.074 0.0002.390 0.000 0.027 0.6070.0000.157 0.000 1.7230.000 0.276 818.02.650.558 0.030 0.00 0.17 180.0 7/31/2024 13:24 0.1730.000-0.030 0.082 0.2430.846 0.021 0.000 0.0000.0000.000 0.000 1.3540.000 0.000 818.02.301.417 0.000 0.17 0.22 180.0 7/31/2024 13:24 1.1650.000-0.031 0.082 0.0000.957 0.015 0.234 0.3390.9790.000 0.000 0.1040.000 0.000 818.00.470.547 0.000 1.16 0.19 180.0 7/31/2024 13:25 0.0000.000-0.031 0.063 0.0000.429 0.000 0.159 0.0001.7182.165 0.000 1.0560.000 0.000 818.01.330.414 0.000 0.00 0.17 180.0 7/31/2024 13:25 0.0000.000-0.031 0.090 0.8670.000 0.080 0.006 1.6400.0052.441 0.000 0.0000.000 0.035 818.00.070.000 0.000 0.00 0.20 180.0 7/31/2024 13:25 0.0000.000-0.030 0.042 0.0000.231 0.000 0.000 0.0250.0001.483 0.000 0.0000.000 0.469 818.01.611.001 0.000 0.00 0.15 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 7/31/2024 13:25 1.8410.000-0.030 0.048 0.0000.276 0.000 0.000 0.0000.0002.670 0.000 0.0000.877 0.000 818.00.130.189 0.000 1.84 0.15 180.0 7/31/2024 13:25 0.0000.000-0.031 0.026 0.8840.024 0.023 0.031 0.0000.8660.913 0.000 0.5740.000 0.000 818.01.321.126 0.000 0.00 0.15 180.0 7/31/2024 13:25 0.0000.000-0.030 0.071 0.0000.000 0.085 0.000 0.0000.0000.000 0.000 0.0301.459 0.193 818.01.010.895 0.000 0.00 0.00 180.0 GAS, Inc. 303 W. 3rd St Elk City , OK 73644(580) 225-0403 Test Started:Test Completed:02:21 PM 06:31 PM Permit #: #DAQE-ANl 1679008-13 Location: Duchesne County, Utah Prepared on Behalf of: Scout Energy Management, LLC Ashley Compressor Station CO NOx NMNEHC 0.850 3.040 2.130 0.030 0.824 0.333 5.040 84.821 35.796 2.000 1.000 0.700 0.011 0.301 0.122 Pass Pass Pass Pass Pass Pass Federal State Federal State Federal State Results lb/hr Results ppmvd Permit lb/hr Results g/hp-hr Permit g/hp-hr PASS ALL 40 CFR Part 60 Subpart JJJJ Performance Test Report Test Type: Initial Test Date: 7/31/2024 DOM: 3/1/12 Source: Caterpillar 3516TALE Lean Burn (4 Cycle) Unit Number: Unit #3 Serial Number: JEF01561 Engine Hours: 39742.3 Index Tables Figures Appendices Table 5.1 (Run Summaries)................................................................ Table 6.1 (Volumetric Flow Rate Data)............................................... Table 6.2 (Stack Gas Measurements)................................................. Table 8.1 (Oxygen Calibration)........................................................... Annex Table 1.2.1 (Certified Calibration Bottle Concentrations)......... Annex Table 1.2.2 (Measurement System Capabilities)..................... Annex Table 1.3.1 (Test Specific Target Analytes)............................. Annex Table 4.1 (Measure System Capabilities)................................ Figure 6.1 (Location of Traverse Points per Method 1)....................... Annex Figure 1.4.1 (Sampling Train).................................................. Annex Figure 1.4.2 (Sampling Points)................................................. Annex Figure 1.4.3 (Sampling Port Locations).................................... Certified Calibration Bottle Certificates................................................ Tri Probe Certification via GD-031...................................................... GAS ALT 141_FTIR EPA.................................................................... Tester Qualifications (resume)............................................................ Raw Data............................................................................................ 27 Key Personnel.............................................................................1.0 3 Sampling System........................................................................2.0 3 Methods Used.............................................................................3.0 3 Test Summaries..........................................................................4.0 5 Run Summaries..........................................................................5.0 6 6 Volumetric Flow Rate Data.........................................................6.0 7 7 7 7 Calculations................................................................................7.0 8 9 12 12 13 15 13 14 14 20 25 28 29 Oxygen Calibration.....................................................................9 Engine Parameter Data Sheet....................................................10 QA/QC Results............................................................................11 Signature Page...........................................................................12.0 Appendices.................................................................................13.0 Bottle Certs.................................................................................2014.0 Tri Probe Certification via GD-031..............................................2515.0 GAS ALT 141_FTIR EPA............................................................16.0 Tester Qualifications (resume)....................................................2817.0 D6348 Annexes..........................................................................1211.0 18 19 26 8.0 9.0 10.0 Raw Data....................................................................................2918.0 1.0 Key Personnel GAS, Inc. Scout Energy Management, LLC 2.0 Sampling System The sampling system used consisted of a Stainless steel probe, heated Teflon line, gas conditioning system, and a Gasmet model DX4000 FTIR analyzer. The gas conditioning system used was a Gasmet Personal Sampling System with a Zirconium Oxide oxygen sensor. 3.0 Methods Used This extractive FTIR based field test method is used to quantify gas phase concentrations of multiple target analytes (CO, NOX, CH2O, & VOC's) from stationary source effluent. Because an FTIR analyzer is potentially capable of analyzing hundreds of compounds, this test method is not analyte or source specific. The analytes, detection levels, and data quality objectives are expected to change for any particular testing situation. It is the responsibility of the tester to define the target analytes, the associated detection limits for those analytes in the particular source effluent, and the required data quality objectives for each specific test program. Provisions are included in this test method that require the tester to determine critical sampling system and instrument operational parameters, and for the conduct of QA/QC procedures. Testers following this test method will generate data that will allow an independent observer to verify the valid collection, identification, and quantification of the subject target analytes. EPA Method 1 & 1A EPA Method 2 & 2C EPA Method 3A The purpose of the method is to provide guidance for the selection of sampling ports and traverse points at which sampling for air pollutants will be performed pursuant to regulations set forth in this part. This method is applicable for the determination of the average velocity and the volumetric flow rate of a gas stream. The average gas velocity in a stack is determined from the gas density and from measurement of the average velocity head with a standard pitot tube. Velocity readings are taken from each stack at 16 separate traverse points (Table 6.1) and used to determine the engines mass emissions rate, calculated utilizing the formulas seen in section 7.0 of this report. This is a procedure for measuring oxygen (O2) and carbon dioxide (CO2) in stationary source emissions using a continuous instrumental analyzer. Quality assurance and quality control requirements are included to assure that the tester collects data of known quality. Documentation to these specific requirements for equipment, supplies, sample collection and analysis, calculations, and data analysis will be included. ASTM D6348-03 Tyson Clegg 3 Danny Cupp Gas, Inc. 4.0 Test Summary t S u m m a r y Site Verification Photos Gas, Inc. The engine is a natural gas fired Lean Burn (4 Cycle) engine rated at 1311 brake horse power (BHP) at 1400 RPM. The engine was operating at 1241 BHP and 1344 RPM which is 94.69% of maximum engine load during the test. The test HP calculation can be found on page 8. The engine was running at the maximum load available at the test site. This test will satisfy the testing requirements for 40 CFR Part 60 Subpart JJJJ. Unit Unit #5 is authorized to operate under permit #DAQE-ANl 1679008-13. 4 Unit Unit #3 with a serial number of JEF01561 which is a Caterpillar 3516TALE engine located at Ashley Compressor Station and operated by Scout Energy Management, LLC was tested for emissions of: T Carbon Monoxide, Oxides of Nitrogen, and Volatile Organic Compounds. The test was conducted on 7/31/2024 by Danny Cupp with Great Plains Analytical Services, Inc. All quality assurance and quality e control tests were within acceptable tolerances. s 4.0 Test Summary Engine/Compressor Specs Ashley Compressor StationLocation Unit ID Make Caterpillar Site Elevation ft.6168.58 Model 3516TALE Atmospheric Pressure psi.11.86 Serial Number JEF01561 Stack Diameter in.13 mfg. rated hp 1311 Yes 1400 Date of Manufacture 3/1/2012 Engine/Compressor Operation Run 2 Run 3 3 Run AveragesRun 1 Test Horsepower 1232 1288 1204 1241 1348 1345 1339 1344 Percent Load % Intake Manifold Pressure (hg) 93.97%98.25%91.84%94.69% 54.04 53.22 52.00 53.09 Intake Manifold Temperature (F)148.10 147.60 147.00 147.57 Ambient Conditions Ambient Temperature Dry (F)89.00 92.00 93.00 91.33 Exhaust Flow Data Q Stack (dscfh) Q Stack (dscm/hr) 80349.42 79084.93 84675.26 81369.87 2275.22 2239.42 2397.71 2304.12 Moisture Fraction Bws Fuel Consumption (Btu/h[-hr) 0.07 0.07 0.07 0.07 0 0 0 0 Fuel Flow (dscfh) Fuel (btu/scf)1020 1020 1020 1020 O2 F factor 8710.0 8710 8710 8710 Results Method 3A Corrected O2% Dry Moisture %7.09%7.17%6.99%7.08% T e s t S u m m a r y mfg. rated rpm Test RPM 8.83%8.87%8.82%8.84% Permitted Standards Results 5 Catalyst 0.0120.010 Run 1 Run 2 Run 3 3 Run Average Pass Permits 02:21 PM 03:41 PM 04:50 PM 7/31/2024 CO (g/hp-hr)0.010 0.0112.000 Pass StateFederal CO (ppmvw)4.493 4.786 4.771 4.683 CO (ppmvd)4.835 5.155 5.129 5.040 CO (mol wt) 28.01 CO (ppmvd) @15% O2 2.364 2.529 2.506 2.466 Fail CO (ppbvd) @15% O2 2363.878 2529.288 2505.633 2466.267 Fail 0.0320.030CO (lbs/hr)0.028 0.0300.850 Pass NOx (g/hp-hr)0.299 0.286 0.319 0.3011.000 Pass NOx (ppmvw)78.593 79.855 77.991 78.813 NOx (ppmvd)84.588 86.026 83.848 84.821 NOx (mol wt) 46.01 33.449 33.329 33.005 33.261NMNEHC (ppmvw) 36.001 35.904 35.484 35.796NMNEHC (ppmvd) NOx (ppbvd) @15% O2 41354.061 42205.889 40959.308 41506.420 Fail NOx (ppmvd) @15% O2 41.354 42.206 40.959 41.506 Fail NMNEHC (mol wt) 44.10 17600.305 17615.429 17333.564 17516.433 FailNMNEHC (ppbvd) @15% O2 0.122 0.114 0.130 0.1220.700 PassNMNEHC (g/hp-hr) 0.331 0.325 0.344 0.3332.130 PassNMNEHC (lbs/hr) 17.600 17.615 17.334 17.516 FailNMNEHC (ppmvd) @15% O2 NOx (lbs/hr)0.811 0.812 0.847 0.8243.040 Pass Gas, Inc. Unit #3 5.0 Run Summaries Summary Source Run 1 R u n Table 5.1 Run Summaries S u m m a r i e s 6 0.00Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture % 4.49 0.00 78.49 0.00 0.11 0.00 78.59 0.64 33.45 0.19% 8.06% 0.00% 7.09% NMNEHC 4.19 77.77 0.21 77.98 32.90 7.99%7.01% 42.87 92.54 0.00 92.53 55.54 7.51%5.64% 4.80 79.20 0.00 79.20 34.00 8.12%7.17% 0.00 0.00 0.00 0.00 0.22 0.17%0-.0% Avg. Wet NO2NO Summary Source Run 2 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 0.00 0.00 0.00 0.00 0.22 0.17%0-.0% 4.67 78.92 0.04 78.95 33.25 8.10%7.10% 41.57 93.72 0.00 93.72 52.69 7.48%6.08% 4.90 80.76 0.00 80.76 33.41 8.08%7.25% 0.00 0.00 0.96 0.96 0.09 0.16%0.19% Avg. Wet 4.79 79.84 0.02 79.86 33.33 8.09%7.17% NO2NO Summary Source Run 3 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 4.21 79.36 0.34 79.69 32.81 8.12%7.03% 41.32 91.36 0.00 91.36 53.16 7.57%5.87% 5.33 76.28 0.01 76.29 33.20 8.00%6.94% 0.00 0.00 0.97 0.97 0.14 0.12%0.00% 0.00 0.00 0.96 0.96 0.09 0.16%0.19% Avg. Wet 4.77 77.82 0.18 77.99 33.01 8.06%6.99% NO2NO Gas, Inc. 6.0 Volumetric Flow Rate Data Volumetric Flow Rate Data .99 Stack diameter = Table 6.1. Data used for volumetric flow rate (Method 2) 13 inches or:1.08 feet. or:.92 Square Feet Run 1 Average Pitot Tube Coefficient Cp(std)= H2O CO2 O2 CO Molecular Weight Stack Gas dry basis (Md) Molecular Weight Stack Gas wet basis (Ms) Stack Static Pressure (Pg) Stack Static Pressure (Pg) Atmospheric Pressure at Location (Pbar) Atmospheric Pressure at Location (Pbar) Absolute Stack Pressure (Ps) Stack Temperature Stack Temperature Stack Temperature Stack Gas Velocity Stack Flow Rate Q Stack Gas Wet Volmetric Flow Rate Stack Gas Dry Volumetric Flow Rate Sample after Back Purge: Within 5% of Last Δpstd reading: Stack Diameter (inches) Inches upstream from disturbance Inches downstream from disturbance scf/hr 0.58 Yes 13.00 300.00 31.00 scf/hr cfs ft/sec Deg R Deg F Deg C "Hg "Hg MBAR "Hg "H20 g/g mole g/g mole ppmd %d %d %d 7.09 29.19 0.42 Inches 2.17 6.5 10.83 Vo l u m e t r i c F l o w Ra tes Pitot readings are taken for Method 2 calculations using measuring points outlined in Method 1 Figure 6.1 16 Traverse Points Were Used Emissions Sampling Points - 3 point long line sampling probe First Sampling Point Taken @ 16.7% of Stack Diameter Second Sampling Point Taken @ 50% of Stack Diameter Third Sampling Point Taken @ 83.3% of Stack Diameter 5.43 8.06 4.49 817.00 0.03 24.13 24.16 710.50 1170.17 376.94 28.40 71.52 65.93 86479.05 80349.41 Run 2 7.17 29.19 0.41 5.43 8.10 4.79 816.85 0.03 24.13 24.16 715.50 1175.17 379.72 28.39 70.78 65.24 85196.04 79084.93 Run 3 6.99 29.18 0.47 5.39 8.06 4.77 816.00 0.03 24.10 24.14 722.50 1182.17 383.61 28.40 76.14 70.19 91034.48 84675.26 7.08 29.19 0.43 5.42 8.07 4.68 816.62 0.03 24.12 24.15 716.17 1175.84 380.09 28.40 72.84 67.14 87615.84 81410.74 *The exhaust stack did not present cyclonic flow conditions at the sampling location due to the absence of cyclones, inertial demisters, venturi scrubbers, or tangential inlets. * Cyclonic Flow Check (Pass/Fail): PASS Δpstd (in) H2O 0.32 Exhaust Temp F 710.00 Pitot Tube Sampling Points (Velocity) 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 Δpstd Average= Run 1 Table 6.2. Stack gas pressure readings measured with a standard pitot tube use for Volumetric Flow Rate 0.41 0.50 0.35 709.00 708.00 707.00 0.42 0.39 0.46 706.00 705.00 704.00 0.47 0.38 0.25 703.00 711.00 712.00 0.30 713.00 0.23 0.53 0.59 714.00 715.00 716.00 0.44 0.66 0.42 717.00 718.00 710.50 Δpstd = Velocity head measured by the standard pitot tube, (in.) H2O.Run 3 Δpstd (in) H2O 0.50 Exhaust Temp F 722.00 0.53 0.61 0.55 721.00 720.00 719.00 0.45 0.41 0.39 718.00 717.00 716.00 0.29 0.27 0.36 715.00 723.00 724.00 0.39 725.00 0.52 0.58 0.51 726.00 727.00 728.00 0.57 0.58 729.00 730.00 722.500.47 Run 2 Δpstd (in) H2O 0.23 Exhaust Temp F 715.00 0.34 0.45 0.50 714.00 713.00 712.00 0.31 0.30 0.26 711.00 710.00 709.00 0.21 0.38 0.46 708.00 716.00 717.00 0.42 718.00 0.49 0.50 0.51 719.00 720.00 721.00 0.59 0.58 722.00 723.00 0.41 715.50 7 Gas, Inc. 7.0 Calculations Method 2: Determination of Stack Gas Velocity and Volumetric Flow Rate *Note- Use of this method negates the need for any fuel related numbers for emissions calculations Nomenclature Δp(avg) = Velocity head of stack gas, mm H2O (in. H2O).Ps = Absolute stack pressure (Pbar+ Pg), mm Hg (in Hg) 3600 = Conversion Factor, sec/hr. A = Cross-sectional area of stack, m2 (ft2). Bws = Water vapor in the gas stream (from ASTM D6348) Kp = Velocity equation constant. Md = Molecular weight of stack gas, dry basis, g/g-mole (lb./lb.-mole). Ms = Molecular weight of stack gas, wet basis, g/g-mole (lb./lb. -mole). Pstd = Standard absolute pressure, 760 mm Hg (29.92 in. Hg). Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (dscf/hr.). Ts(abs) = Absolute stack temperature, °K (°R). = 460 + Ts for English units. Tstd = Standard absolute temperature, 293°K (528 °R). Vs = Average stack gas velocity, m/sec (ft./sec). *(Observed from Method 3 12.3) Dry Molecular Weight. Equation 3-1 Md = .44(.054)+.32(.088)+.28(.858+0) = 29.191 LB/LB-MOLEMd = .44(%CO2)+.32(%O2)+.28(%N2+%CO) 12.5 Molecular Weight of Stack Gas. Equation 2-6 Ms = 29.191(1 -.07088)+.18.0(.07088) = 28.398 LB/LB-MOLEMs = Md(1-Bws)+18.0(Bws) 12.6 Average Stack Gas Velocity. Equation 2-7 Vs = 85.49*.99*√.42*√(1170.17/(24.16*28.398)) = 71.52 FT/SECVs = Kp*Cp(std)*√Δpavg*√(Ts(abs)/(Ps*Ms)) 12.7 Average Stack Gas Volumetric Flow Rate. Equation 2-8 Qsd = 3600(1-.071)71.523*.922((528*24.16)/ (1170.17*29.92)) = 80349.42 DSCF/HRQsd = 3600(1-Bws)Vs*A((Tstd*Ps)/(Ts(abs)*Pstd)) *Standard conversion from feet to meters Q = 80349.415/35.315 = 2275.221 DSCM/HRQ = Qsd/35.315 Emission Rates (Examples use CO Run 1) Nomenclature CO corrected @ 15% O2 453.6= Conversion factor lb. to gram HP= Engines rated Horsepower A = Cross-sectional area of stack, m2 (ft2). BHP/HR. = Brake work of the engine, horsepower-hour (HP-HR.). BTU/HP-HR. = Brake Specific Fuel Consumption (HHV) ER = Emission rate of (CO) in g/HP-hr. F(d )= Volumes of combustion components per unit of heat content, scm/J (scf/million Btu). Q = Stack gas volumetric flow rate, in standard cubic meters per hour, dry basis LB/HR.= Emission rate of (CO) in LB/HR. Mfg.= Manufacturer Exhaust flow rate at 100% (ft3/min) O2 = Concentration of oxygen on a dry basis, percent. ppm= Parts Per Million (CO) ppm@15% O2= PPM corrected to 15% O2 Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (DSCF/HR.). Run Time = Run Time in Minutes TPY= Tons per Year Mol wt.= Mol Weight of CO (28.01) Vs = Average stack gas velocity, m/sec (ft./sec). ppm @ 15% O2 = 4.835*(20.9-15)/(20.9-8.8%)) = 2.358 PPM @ 15% O2ppm @ 15% O2 = PPM*((20.9-15%O2)/(20.9-O2)) G/HP HR from 40 CFR Part 60 Subpart JJJJ (4.835*(1.164*10^-3)*2275.221*(Run Time/60))/1232 = .01 G/HP-HRg/hp-hr = (PPM*(1.164*10^-3)*Q*(Run Time/60))/BHP/HR LB/HR from Grams LB/HR = .01*1/453.6*1232 = .028 LB/HRlb/hr = ER*1/453.6*BHP-HR TPY TPY = .028*4.38 = .123 TPYTPY = LB/HR. *4.38 Horsepower HP Provided On Site Wet to Dry PPM 4.84 = 4.4925*(1/(1-.07))ppm wet * (1/(1-H2O) = ppm dry 8 Cp(std) = Standard pitot tube coefficient; use 0.99 Gas, Inc. 8.1 Calibration error test; how do I confirm my analyzer calibration is correct? After the tester has assembled, prepared and calibrated the sampling system and analyzer, they conduct a 3-point analyzer calibration error test before the first run and again after any failed system bias test or failed drift test. They then introduce the low-, mid-, and high-level calibration gases sequentially in direct calibration mode. At each calibration gas level (low, mid, and high) the calibration error must be within ± 2.0 percent of the calibration span. 8.0 Oxygen Calibration 8.2 Initial system bias and system calibration error checks. Before sampling begins, it is determined whether the high- level or mid-level calibration gas best approximates the emissions and it is used as the upscale gas. The upscale gas is introduced at the probe upstream of all sample- conditioning components in system calibration mode. 8.3 Post-run system bias check and drift assessment - confirming that each sample collected is valid. Sampling may be performed for multiple runs before performing the post-run bias or system calibration error check provided this test is passed at the conclusion of the group of runs. A failed final test in this case will invalidate all runs subsequent to the last passed test. (1) Next, zero gas is introduced as described above. The response must be within 0.5 percent of the upscale gas concentration. (2) Low-level gas reading is observed until it has reached a final, stable value and the results are recorded. The measurement system will be operated at the normal sampling rate during all system bias checks. (3) If the initial system bias specification is not met, corrective action is taken. The applicable calibration error test from Section 8.2.3 of EPA Method 7E is repeated along with the initial system bias check until acceptable results are achieved, after which sampling will begin. The pre- and post-run system bias must be within ± 5.0 percent of the calibration span for the low-level and upscale calibration gases. (1) If the post-run system bias check is not passed, then the run is invalid. The problem is then diagnosed and fixed, then another calibration error test and system bias is passed before repeating the run. (2) After each run, the low-level and upscale drift is calculated, using Equation 7E–4 in Section 12.5 from EPA Method 7E. If the post-run low- and upscale bias checks are passed, but the low-or upscale drift exceeds the specification in Section 13.3, the run data are valid, but a 3-point calibration error test and a system bias check must be performed and passed prior to additional testing. Table 8.1 Oxygen Calibration EPA Method 3A QA Worksheet (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Certified Gas Concentraion Low-Level (%) 0.00% Certified Gas Concentraion Mid-Level (%) Certified Gas Concentraion High-Level (%) (DIRECT) Analyzer Calibration Error (≤ 2%) Certified Concentration Value (%) Direct Calibration Response (%) Absolute Difference (%) Analyzer Calibration Error (%)Analyzer Direct Calibration Response Certified bottle value % 0.00% 0.00% 0.00% Zero Gas % Mid-Level Gas % High-Level Gas % Bias Pre Initial Value Bias Post Inital Values System Calibrations Response Pre (%) 0.00% System Bias (% of Span) Pre System Calibration Response Post (%) System Bias (% of Span) Post Drift (% of Span) 0.00%0.00%0.00%0.00% (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Avg. Gas Concentration (Run 1) Avg. Gas Concentration (Run 2) Avg. Gas Concentration (Run 3) Effluent Gas (Cgas) Run 1 Effluent Gas (Cgas) Run 2 Effluent Gas (Cgas) Run 3 Linearity Check 0.00%0.00%0.00% Method 7E 3.4 To the extent practicable, the measured emissions should be between 20 to 100 percent of the selected calibration span. This may not be practicable in some cases of low concentration measurements or testing for compliance with an emission limit when emissions are substantially less than the limit. 7E 8.5: Note: that you may risk sampling for multiple runs before performing the post-run bias provided you pass this test at the conclusion of the group of runs Upscale Gas Analyzer Calibration Response (%) Zero Gas Upscale Gas EPA Method 3A QA Worksheet Zero Gas Mid-Level Gas High-Level Gas 100% Nitrogen O2 QA/QC Zero Gas %0.00% Mid-Level Gas % High-Level Gas % System Calibration Response Pre (%) System Calibration Response Post (%) Zero Gas % Upscale Cal Zero Gas % Upscale Cal Upscale Used Upscale Used 10.65% 21.17% 10.61% 10.26% 10.62% 10.62% 10.26%10.61% 10.65% 21.17% 10.62% 20.98% 10.62% 20.98% 10.62%20.98% 0.00% 10.62% 20.98% 0.03% 0.19% 0.14% 0.92% 10.62% Span Zero Offset 0.00% 20.98 0.00% 10.65%0.19%1.84%0.02% 8.68% 8.72% 8.67% 8.83% 8.87% 8.82% 9 Gas, Inc. 884.0 882.0 882.7 17.8 17.2 17.3 9.0 Engine Parameter Data Sheet Company Site Elevation (ft) Facility Unit ID Date Make Scout Energy Management, LLC Ashley Compressor Station 7/31/2024 6168.58 Caterpillar Model Serial Number 3516TALE JEF01561 Technician Danny Cupp Run Start Times 02:21 PM 03:41 PM 04:50 PM 06:31 PM Run 1 Run 2 Run 3 Completed Engine Parameter Data Run 1 Engine Speed (RPM)1347.5 1345.1 1339.0 1343.9 Engine Hours 39739.3 39740.3 39741.3 39742.3 Intake Manifold Pressure (psi)38.4 38.0 37.4 37.9 Intake Manifold Temp °F 148.1 147.6 147.0 147.6 Engine Load (BHP)1232.0 1288.0 1204.0 1241.3 Ambient Temp °F 89.0 92.0 93.0 91.3 Humidity %11.0 10.0 9.0 10.0 Dew Point °F 27.0 27.0 25.0 26.3 Caterpillar 0.0 0.0 Yes N/A N/A N/A N/A 2 2 2 2# of Catalyst Installed Catalyst Manufacturer Catalyst (Yes or No) AFR Setting (Target Left Bank) AFR Setting (Target Right Bank) AFR Manufacturer/Type 0.0 0.0 0.0 0.0 0.0 0.0 Caterpillar Caterpillar Caterpillar 10 Run 3 AverageRun 2 17.0 882.0Discharge Pressure (psi) Suction Pressure (psi) Catalyst Pressure Drop H2O Catalyst Outlet Temp °F Catalyst Inlet Temp °F Gas, Inc. Unit #3 10.0 QA/QC Results Average:Carbon monoxide CO Gas, Inc. 0.00 R e s u l t s Average:Nitrogen monoxide NO 0.00 Average:Nitrogen dioxide NO2 0.00 Average:NOx 0.00 Average:VOC 0.37 Average:Oxygen 0.16 Pre-test Baseline Results Time: Q A / Q C Value:CTS Bottle Concentration 100.00 Value:CTS Compound Concentration Avg 99.69 Tolerance 2.00% Difference between measured and expected 0.31% CTS Direct to Analyzer Time: Average:Carbon monoxide CO 0.00 Average:Nitrogen monoxide NO 0.00 Average:Nitrogen dioxide NO2 0.26 Average:NOx 0.26 Average:VOC 0.52 Average:Oxygen 0.11 Pre-test System Zero Time: Mechanical Response Time 45 seconds Value:CTS Bottle Concentration 100.00 Value:CTS Compound Concentration Avg 99.51 Tolerance 5.00% Difference between measured and expected 0.49% Pre-test System CTS & Mechanical Response Time 7 secondsEquilibration Response Time Value:Spike Reported 253.90 Value:Spike Expected 257.20 System (Equilibration) Response Time Target (Spike) 45 secondsSystem Zero Response Time 45 secondsSystem Response Time System (Zero) Response Time 11 11.0 D6348 Annexes 1-8 D6348 Annexes 1. Test Plan Requirements Annex 1.2 The test quality objectives completed for the emissions test are demonstrated throughout Annexes 1, 2, 3, 4, 5, 6, 7 & 8 as layed out per ASTM D6348-03. All reference methods, pre-test and post test procedures were within acceptable limits. Data generated during the pre-test and post-test procedures are summarized below in order of the distinctive Annex. Three 60 minute test runs were performed. The final analyte concentrations are the average of each test run. Data was taken at 60 second intervals. Each 60 second measurement was the average of 600 scans. Propane is used as the surrogate compound for the Annex 5 Spiking Technique due to Propane being the VOC that is most commonly found in the combustion process of natural gas. Additionally, the molecular weight of Propane coincides with with molecular weight of VOC's per the EPA. Annex Table 1.2.1 Certified Calibration Bottle Concentrations Bottle Expiration NO2 Ethylene SF6 O2 (%) CC507057 4/29/2027 99.08 10.62% CC262147 11/29/2031 100.00 CC421882 10/10/2030 20.98% Cylinder # CC42028 Expiration: 12-11-2031 Propane CO NO SF6 Bottle Value 257.20 501.00 246.20 10.07 Analyzer System Response 253.90 494.10 247.81 10.05 Percent Difference 1.28%1.38%0.65%0.22% Annex Table 1.2.2 Measurement System Capabilities SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 99.691 4.985 Spike Direct Propane 254.616 Mechanical Response Time SF6 10.073 CO 492.636 NO 249.253 Ethylene 99.508 4 seconds Analyzer Response Propane 253.899 SF6 10.048 CO 494.102 NO 247.805 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 255.593 CO 482.308 NO 238.729 7 seconds 14 seconds 7.89% 7.62% 7.59% 102.80% 99.72% 102.18% 10.038 12 Gas, Inc. Annex 1.3 Compounds Infrared Analysis Region (cm-1) Expected Concentration Range Measurement System Achievable Minimum Detectable Concentrations Required Measurement System Accuracy and Precision for Test Application CO 2000-2200 0-1200 ppm NO 1875-2138 NO2 2700-2950 VOC 2600-3200 910-1150 2550-2950 CH2O 2550-2850 Interfering Compounds * CO is analyzed in a separate analysis region than CO2 and H2O CO2 Water Vapor 926-1150 3200-3401 Annex Table 1.3.1 Test Specific Target Analytes and Data Quality Objectives 0.16267 ppm 4 ppm 0-1000 ppm 0.4007 ppm 2 ppm 0-100 ppm 0.4899 ppm 2 ppm 0-100 ppm 1.8520 ppm Total VOC's 1 ppm per VOC 0-100 ppm 0.7878 ppm 1 ppm 0-10% 0-22% 0% 0.20% n/a n/a * VOCs compiled of Acetaldehyde, Ethylene, Hexane, and Propane. Annex 1.4 Figure Annex 1.4.1 Sampling Train The testing instrumentation is housed in an enclosed vehicle which is located approximately 45 feet from the source. A heated sample line (sixty feet in length) is attached to the inlet of analyzer system and the source effluent discharges through the FTIR outlet. 13 Gas, Inc. Sampling Point Locations in Inches 16.7%2.171 50%6.500 83.3%10.829 Figure Annex 1.4.3 Sample Port Location Figure Annex 1.4.2 Sampling Points Interior Stack Diameter (inches): Inches Upstream: Inches Downstream: 13 300 31 14 Stack Gas Dry Volumetric Flow Rate (scf/hr): 81410.74 H2O%d @ Sampling Point:7.08 CO2%d @ Sampling Point:5.42 Pressure @ Sampling Point (Pg "H2O):0.43 Temperature @ Sampling Point (Deg F):716.17 Gas, Inc. D6348 Annex 2. Determination of FTIR Measurement System Minimum Detectable Concentrations (MDC#1) Target Analyte Results (ppm) CO 0.1627 NO 0.4007 NO2 0.4899 Ethylene 0.3782 Propane 0.4351 Hexane 0.2233 Acetaldehyde 0.8152 Formaldehyde 0.7878 D6348 Annex 3. FTIR Reference Spectra Calibration Transfer Standard Expected Measured Path Length Validated Ethylene 100 99.69 4.985 Passed D6348 Annex 4. Required Pre-Test Procedures Annex Table 1.2.2 Measurement System Capabilities 15 SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 99.691 4.985 Spike Direct Propane 254.616 Mechanical Response Time SF6 10.073 CO 492.636 NO 249.253 Ethylene 99.508 4 seconds Analyzer Response Propane 253.899 SF6 10.048 CO 494.102 NO 247.805 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 255.593 CO 482.308 NO 238.729 7 seconds 14 seconds 7.89% 7.62% 7.59% 102.80% 99.72% 102.18% 10.038 Gas, Inc. D6348 Annex 5. Analyte Spiking Technique Propane Spike Direct SF6 CO NO 257.200 10.070 501.000 246.200 254.616 10.073 492.636 249.253 1.00% 0.03% 1.67% 1.24% +/- 2% +/- 2% +/- 2% +/- 2% Pass Pass Pass Pass Parameter Gas Concentration Measured % Difference Specification Validated 22.691 0.005 Spike Average 42.348 0.795 Dilution Factor 7.892% Expected 41.194 % Recovery 102.800% Specification 70-130% <10% Spike Run 1 via the System Source Output Propane SF6 D6348 Annex 6. Determination of System Performance Parameters Noise Equivalent Absorbance (NEA) RMS High RMS Mid RMS Low Line Position: Demonstrating the peak positions align correctly (Manual Comparison +/- 20%) 0.000 Spike Average 0.768 Dilution Factor 7.624% Expected % Recovery Specification 70-130% <10% Spike Run 2 via the System Source Output Propane SF6 0.000 Spike Average 0.765 Dilution Factor 7.595% Expected % Recovery Specification 70-130% <10% Spike Run 3 via the System Source Output Propane SF6 22.027 40.747 39.877 102.180% 0.003863 0.014019 0.018149 22.387 40.167 40.280 99.720% Line Position Difference:Resolution Difference to Reference1.55%Pass Pass4.24% 16 Gas, Inc. Resolution The Gasmet GICCOR (Genzel Interferometer with Cube Corner Retroreflectors) interferometer is specially designed for maximum optical throughput and maximum signal to noise ratio of 7.72 (cm-1) remaining stable with any vibration and temperature changes. D6348 Annex 7. Preparation of Analytical Quantification Algorithm The analytical accuracy of the quantification algorithm is satisfied via the results from Annex 5 per Annex 7.6 Regression Slope:-9.25935765 Pass Line Position Difference:Resolution Difference to Reference 4.24% D6348 Annex 8. Post Test Quality Assurance/Quality Control Procedures CTS Bottle Concentration: CTS Sample Concentration Average: Difference between measured and expected: Tolerance: 100.00 100.95 0.94% 5.00% POST CTS System Check: Run 1 Points 1 & 2 on CO/NO/Propane Run 2 Points 1 & 2 on CO/NO/Propane Run 3 Points 1 & 2 on CO/NO/Propane Run Data Validation - Automated vs Manual Reading Validated Comments All within 20% All within 20% All within 20% Passed Passed Passed Demonstrates no interferences observed. Demonstrates no interferences observed. Demonstrates no interferences observed. 17 Gas, Inc. Detector Linearity The Gasmet DX4000 is a low resolution spectrometer where the aperture is fixed to a maximum angle setting and the detector linearity was tested with an alternate approach. A three point linearity of the CTS gas was performed and validated. We certify that based on review of test data, knowledge of those individuals directly responsible for conducting this test, we believe the submitted information to be accurate and complete. 18 Company: Print Name: Signature: Title: Phone Number: Date: Company:G.A.S. Inc.Date: Print Name: Title: 7/31/2024 Emissions Specialist Company:G.A.S. Inc.Date: Print Name: Title: Signature: Phone Number: Travis Hartley Director of Stack Testing 580-225-0403 7/31/2024 Danny Cupp Gas, Inc. 12.0 Signature Page Job/File Name: Scout Energy Management, LLC; Ashley Compressor Station; Unit #3; JJJJ Appendices Gas, Inc. Gas, Inc. Spike (5 Gas) Gas, Inc. 9% O2/NO2 Gas, Inc. Ethylene Only Gas, Inc. BIP Gas, Inc. CERTIcICATE Oc ANALYSIS Grade of Product: EPA PROTOCOL STANaARa Part Number:E02NI79E15A00B1 Reference Number:54-402564012-1 Cylinder Number:CC421882 Cylinder Volume:146.0 CF Laboratory:124 - Chicago (SAP) - IL Cylinder Pressure:2015 PSIG PGVP Number:B12022 Valve Outlet:590 Gas Code:O2,BALN Certification Date:Oct 10, 2022 Expiration Date:Oct 10, 2030 Certification performed in accordance with “EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)” document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. The results relate only to the items tested. The report shall not be reproduced except in full without approval of the laboratory. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. ANALYTICAL RESULTS Component Requested Actual Protocol Total Relative AssayConcentrationConcentrationMethodUncertaintyDates OXYGEN 21.00 %20.98 %G1 +/- 0.4% NIST Traceable 10/10/2022 NITROGEN Balance CALIBRATION STANaARaS Type Lot ID Cylinder No Concentration Uncertainty Expiration Date NTRM 150104-18 K026588 22.454 % OXYGEN/NITROGEN +/- 0.2%Mar 08, 2027 ANALYTICAL EnUIPMENT Instrument/Make/Model Analytical Principle Last Multipoint Calibration O2-1 HORIBA MPA-510 3VUYL9NR Paramagnetic Sep 14, 2022 Triad Data Available Upon Request Airgas Specialty Gases Airgas USA LLC12722 S. Wentworth Ave. Chicago, IL 60628 Airgas.com Signature on file Approved for Release Page 1 of 1 ㈱┠伲 Tri Probe Certification ” ‡ ƒ – Ž ƒ ‹ • • • ƒ Ž › – ‹ … ƒ Ž ‡ ” ˜ ‹ … ‡ • ͵Ͳ͵͵ǡǡ͵ͶͶ ȋͷͺͲȌʹʹͷǦͲͶͲ͵ ǣȋͷͺͲȌʹʹͷǦʹͳʹ &(57,),&$7(2)$1$/<6,6 *UDGHRI3URGXFW&(57,),('67$1'$5'352%( 3DUW1XPEHU65HIHUHQFH 1XPEHU /DERUDWRU\*$6,1&6WDFN'LDPHWHU $QDO\VLV'DWH7DUJHW)ORZ 5DWH /PLQ /271XPEHU 61 $ $6 1XPEHURI 3RLQWV 3URGXFWSHUIRUPDQFHYHULILHGE\GLUHFWFRPSDULVRQWRFDOLEUDWLRQVWDQGDUGVWUDFHDEOHWR1,67 7KHSUREHOLVWHGRQWKLVIRUPPHHWVWKHPXOWLSRLQWWUDYHUVHUHTXLUHPHQWRI(3$0HWKRGH VHFWLRQDVVKRZQLQWKHDFFRPSDQ\LQJGDWD0HWKRGHVHFWLRQVWDWHVWKDWWKHPXOWLSRLQW WUDYHUVHUHTXLUHPHQWFDQEHVDWLVILHGE\VDPSOLQJYLD³DPXOWLKROHSUREHGHVLJQHGWRVDPSOHDW WKHSUHVFULEHGSRLQWVZLWKDIORZSHUFHQWRIPHDQIORZUDWH´ $1$/<7,&$/5(68/76 ZƵŶηdŽƚĂů&ůŽǁ ;>ͬŵͿ DĞĂƐƵƌĞĚ&ůŽǁ WŽƌƚ;>ͬŵͿ ;ĞůƚĂƋϭͿ DĞĂƐƵƌĞĚ&ůŽǁ WŽƌƚ;>ͬŵͿ ;ĞůƚĂƋϮͿ DĞĂƐƵƌĞĚ&ůŽǁ WŽƌƚ;>ͬŵͿ ;ĞůƚĂƋϯͿ 0HDQ3UREH 3RUW6DPSOHG )ORZ/P 5XQ/30 䧮 䧮 䧮 5XQ/30 䧮 䧮 䧮 &DOLEUDWLRQFRQGXFWHGLQDFFRUGDQFHZLWK(PLVVLRQ0HDVXUHPHQW&HQWHU*XLGHOLQH'RFXPHQW±(0&*' 1RWHV BBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBB $SSURYHGIRU5HOHDVH'DWH 2/17/2022 Probe size: 13S Mr. Jordan Williamson CEO GAS Inc. 303 W. 3rd Street Elk City, OK 73644 Dear Mr. Williamson: We are writing in response to your letter received on September 17, 2020, in which you request the approval of alternative testing procedures. The EPA’s Office of Air Quality Planning and Standards (OAQPS) is the delegated authority for consideration of major alternatives to test methods and procedures as set forth in 40 CFR parts 60 and 63 under which your request must be addressed. GAS Inc. is requesting a change to one of the test methods, ASTM D6348-03, used for conducting performance tests to determine compliance under 40 CFR part 60, Subpart JJJJ – Standards of Performance for Stationary Spark Ignition Internal Combustion Engines (Subpart JJJJ) and 40 CFR part 63, Subpart ZZZZ – National Emissions Standards for Hazardous Air Pollutants for Performance for Stationary Reciprocating Internal Combustion Engines (Subpart ZZZZ). The change being requested will be used to check detector linearity of the Fourier Transform Infrared (FTIR) instrumentation used to conduct this method. Specifically, you are requesting that the procedures of section 8.3.3 of Method 320 (40 CFR part 60, Appendix A), another FTIR-based method allowed under Subparts JJJJ and ZZZZ, be used in lieu of section A6.4.1 of ASTM D6348-03 when conducting testing using ASTM D6348-03 under 40 CFR part 60, Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. In your request, you state that this alternative linearity check procedure will produce consistent results when utilizing either Method 320 or ASTM D6348-03. Additionally, some FTIR instrumentation does not allow for reducing the size of the aperture in the instrument and, thus, it would not be feasible to properly conduct the entirety of the ASTM D6348-03 method in its current form using such an instrument. Based on our understanding of FTIR instrument principles and recognition that the requested alternative determination of detector linearity is both technically sound and contained within Method 320, we are approving the requested change. We believe that this alternative is acceptable for use for use in testing all engines subject to 40 CFR part 60 Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. Also, we will post this letter as ALT-141 on EPA’s website (at www.epa.gov/emc/broadly-applicable-approved-alternative- testmethods) to announce that our approval of this alternative test method is broadly applicable to engines for the purposes of meeting Subparts JJJJ and ZZZZ. March 15, 2021 Sincerely, Steffan M. Johnson, Group Leader Measurement Technology Group If you should have any questions or require further information regarding this approval, please contact David Nash of my staff at 919-541-9425 or email at nash.dave@epa.gov. cc: Sara Ayers, EPA/OECA/OC/MAMPD, (ayres.sara@epa.gov) Melanie King, EPA/OAR/OAQPS/SPPD, (king.melanie@epa.gov) James Leather, EPA Region 6, (leather.james@epa.gov) David Nash, EPA/OAR/OAQPS/AQAD, (nash.dave@epa.gov) Heather Sessing, Oklahoma DEQ, (Heather.sessing@deq.ok.gov) Danny Cupp GAS, Inc. Type of Sources Tested: info@gasinc.us Stationary Internal Combustion Engines • 4 Stroke Rich Burn Engines • 2 Stroke & 4 Stroke Lean Burn Engines Stationary Natural Gas Fired Generators Stationary Propane Fired Generators Gas Fired Boilers Qualifications: Trained, studied, and fully demonstrates compliance for emissions testing via data collection outlined in the following Reference Methods: • EPA Method 1 & 1A – Sampling & Traverse Points • EPA Method 2 & 2C – Velocity & Volumetric Flow Rate of a Gas Stream • EPA Method 3A – Oxygen • EPA Method 7E – NOX • EPA Method 10 – Carbon Monoxide • EPA Method 25A – Volatile Organic Compounds • ASTM D6348 – Extractive Fourier Transform Infrared Spectroscopy Conducts emissions testing on a weekly basis including, but not limited to, the following test types: Initial Compliance, Biennial Compliance, Semiannual Compliance & Quarterly Compliance. All tests performed are in accordance to any and all Federal & State requirements as applicable (i.e. JJJJ, ZZZZ, 106.512, 117, PEA, etc.). Performed testing in Colorado, Utah, Wyoming, North Dakota, Montana, Kansas, New Mexico, Oklahoma, Texas, Louisiana (land and off-shore), Arkansas, Ohio, Pennsylvania, West Virginia, New York, Kentucky, & Mississippi. • Quarterly Performance Reviews covering ongoing changes with Federal Regulations, State Compliance guidelines, & site-specific safety certifications. Types of Analyzers: • Gasmet DX4000 FTIR • Gasmet Portable Sampling Unit with Zirconium Oxide O2 Sensory • Testo 350 • Flame Ionization Detector 580-225-0403 Gas, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 1 Minute Average Data Sheet Scout Energy Management, LLCClient: Ashley Compressor Station Unit Number: Make:Caterpillar Location:3516TALEModel: JEF01561Serial Number: RAW Result Data Stability 7/31/2024 05:41 0.0000.0003.310 0.014 1.3211.095 0.000 0.000 0.0000.0002.457 0.968 0.0160.000 0.000 850.01.130.703 0.013 0.00 0.14 179.0 Pre Test Baseline Direct 7/31/2024 05:49 0.0000.000-1.282 0.000 0.0000.000 0.111 0.000 0.0000.0000.377 0.000 0.2690.000 0.000 850.00.530.393 0.000 0.00 0.15 179.0 7/31/2024 05:50 0.0000.000-1.289 0.000 0.0000.000 0.103 0.000 0.0000.1870.000 0.000 0.0000.000 0.000 850.00.450.676 0.000 0.00 0.18 179.0 7/31/2024 05:50 0.0000.000-1.350 0.001 0.0000.000 0.119 0.072 0.0000.4590.000 0.000 0.0000.000 0.009 850.00.130.166 0.000 0.00 0.16 180.0 CTS Direct 7/31/2024 05:57 0.0000.000-1.542 0.029 0.3660.000 0.000 0.000 0.7170.3120.000 99.727 0.0000.115 0.000 851.066.680.283 0.000 0.00 0.26 180.0 7/31/2024 05:57 0.4210.000-1.557 0.024 0.0000.000 0.000 0.000 0.3460.4620.000 99.244 0.0000.555 0.000 851.066.170.000 0.000 0.42 0.25 180.0 7/31/2024 05:57 0.0000.000-1.560 0.017 0.0000.000 0.000 0.000 0.0000.0000.000 100.103 0.0000.000 0.000 851.066.840.151 0.000 0.00 0.29 180.0 High O2 Direct 7/31/2024 06:00 0.0000.000-1.595 0.013 1.2770.000 0.000 0.106 0.0000.1470.000 0.000 0.2920.000 0.000 851.00.500.305 0.000 0.00 21.12 180.0 7/31/2024 06:01 0.0000.000-1.556 0.022 0.3510.000 0.000 0.365 0.5320.2280.000 0.000 0.0000.000 0.000 851.00.360.537 0.000 0.00 21.20 180.0 7/31/2024 06:01 0.0800.000-1.570 0.000 0.4570.000 0.000 0.210 0.2410.2260.000 0.000 0.0000.000 0.000 851.00.180.277 0.000 0.08 21.20 180.0 NO2/Mid O2 Direct 7/31/2024 06:08 99.1010.000-1.575 0.000 1.5770.000 0.797 0.000 1.3750.1260.000 0.000 0.0000.000 0.000 851.00.390.583 0.000 99.10 10.66 180.0 7/31/2024 06:09 97.7420.000-1.581 0.000 0.0930.000 0.763 0.000 1.0460.5300.000 0.000 0.0310.000 0.000 851.00.030.000 0.000 97.74 10.64 180.0 7/31/2024 06:09 100.2100.000-1.590 0.000 1.5170.000 0.818 0.000 1.7850.0060.000 0.000 0.0000.087 0.000 851.00.000.003 0.000 100.21 10.65 180.0 Spike Direct 7/31/2024 06:16 0.000248.999-1.576 4.633 0.329494.461 0.711 1.345 2.0210.4900.000 1.893 255.3760.000 0.000 851.0259.814.755 10.086 249.00 0.18 180.0 7/31/2024 06:16 0.000249.280-1.574 4.556 2.761491.784 0.747 1.328 3.3530.7560.000 1.827 254.0230.000 0.000 851.0257.563.484 10.078 249.28 0.20 180.0 7/31/2024 06:17 0.000249.479-1.589 4.604 2.728491.662 0.803 1.639 3.7250.2030.277 1.932 254.4480.000 0.000 851.0258.994.874 10.055 249.48 0.22 180.0 GAS, Inc. Unit #3 Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline System 7/31/2024 06:20 0.0000.000-0.031 0.002 0.0000.000 0.002 0.126 0.0000.0000.000 0.000 0.3950.065 0.000 851.01.010.925 0.000 0.00 0.13 180.0 7/31/2024 06:20 0.0000.000-0.031 0.025 0.0000.000 0.000 0.024 0.9430.0090.000 0.000 0.0000.000 0.000 850.00.450.681 0.000 0.00 0.20 179.0 7/31/2024 06:20 0.7800.000-0.032 0.020 0.0000.000 0.000 0.000 0.6550.0000.000 0.000 0.0000.000 0.000 850.00.100.145 0.000 0.78 0.00 179.0 CTS System with Response Time 7/31/2024 06:22 0.0000.000-0.032 0.020 0.0000.000 0.000 0.073 0.1720.0040.000 98.782 0.0000.017 0.037 849.066.330.598 0.000 0.00 0.64 180.0 7/31/2024 06:23 0.0000.000-0.031 0.016 0.1090.000 0.000 0.037 0.0000.0000.000 99.462 0.2390.000 0.000 849.066.600.069 0.000 0.00 1.21 180.0 7/31/2024 06:23 0.0000.000-0.031 0.000 0.0000.000 0.014 0.296 0.0000.0000.000 100.280 0.1940.000 0.000 850.067.050.000 0.000 0.00 1.22 180.0 NO2/Mid O2 System with Response Time 7/31/2024 06:25 98.7031.051-0.031 0.000 1.8240.000 0.828 0.000 1.0780.0000.000 0.000 0.0000.000 0.000 849.00.280.422 0.000 99.75 10.59 180.0 7/31/2024 06:25 97.3901.690-0.032 0.020 1.2020.000 0.790 0.101 1.9630.2200.000 0.000 0.0000.000 0.000 848.00.580.871 0.000 99.08 10.62 180.0 7/31/2024 06:26 99.6980.865-0.032 0.016 1.2630.000 0.802 0.000 0.9280.0000.000 0.000 0.0870.000 0.000 848.00.290.307 0.000 100.56 10.62 179.0 Spike System with Response Time 7/31/2024 06:28 0.000245.949-0.032 4.614 1.414495.191 0.959 1.614 2.5420.1700.000 2.099 254.2470.000 0.000 846.0257.642.985 10.024 245.95 0.02 180.0 7/31/2024 06:28 0.000249.707-0.032 4.616 2.282493.192 0.919 1.757 3.4390.1240.000 1.893 253.2480.000 0.000 844.0256.492.963 10.066 249.71 0.02 180.0 7/31/2024 06:29 0.000247.760-0.032 4.608 2.891493.922 0.917 1.276 2.3940.3870.000 2.012 254.2020.015 0.000 843.0258.173.940 10.055 247.76 0.16 180.0 Baseline System with Response Time 7/31/2024 06:32 0.0000.000-0.032 0.003 0.0430.000 0.039 0.000 0.7860.0220.000 0.000 0.0000.128 0.019 848.00.550.764 0.000 0.00 0.19 180.0 7/31/2024 06:32 0.0000.000-0.032 0.011 0.1410.000 0.000 0.248 1.0540.0000.000 0.000 0.1650.000 0.000 848.00.871.050 0.000 0.00 0.24 180.0 7/31/2024 06:33 0.0000.000-0.032 0.000 0.3480.000 0.002 0.050 0.1180.0000.000 0.000 0.1060.000 0.075 847.00.510.382 0.000 0.00 0.14 180.0 Run 1 - A 30minute/60min 7/31/2024 14:21 6.18459.5383.346 4.485 577.3184.530 0.000 0.000 45.5930.0006.705 2.888 18.5380.000 1.483 817.023.760.492 0.000 65.72 8.01 180.0 7/31/2024 14:22 0.00073.9905.168 5.526 780.6966.582 0.000 0.000 52.5600.0009.074 4.187 22.3230.000 2.627 817.032.463.141 0.000 73.99 8.12 180.0 7/31/2024 14:23 0.00073.8355.627 5.516 781.6275.793 0.000 0.000 51.3160.0009.186 4.645 23.3570.000 2.610 817.033.873.289 0.000 73.84 8.08 180.0 7/31/2024 14:24 0.00077.8705.877 5.555 772.6115.912 0.000 0.000 50.1040.0008.520 4.333 22.1570.000 2.715 817.031.972.245 0.000 77.87 8.07 180.0 7/31/2024 14:25 0.00076.5246.059 5.507 776.8345.597 0.000 0.000 50.4570.0008.959 4.529 22.4010.000 2.705 817.032.762.896 0.000 76.52 8.04 180.0 7/31/2024 14:26 0.00076.4996.163 5.498 777.9745.375 0.000 0.000 50.9620.0009.496 4.658 22.9940.000 2.611 817.033.393.099 0.000 76.50 8.11 180.0 7/31/2024 14:27 0.00076.5896.262 5.485 782.3435.126 0.000 0.000 51.3430.0009.457 4.359 22.1720.000 2.843 817.033.213.675 0.000 76.59 8.03 180.0 7/31/2024 14:28 0.00076.4656.341 5.493 786.6735.169 0.000 0.000 51.9030.0009.094 4.507 22.3870.000 2.626 817.032.512.803 0.000 76.47 8.07 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 7/31/2024 14:30 0.00078.2056.424 5.497 781.3765.716 0.000 0.000 50.7850.0009.110 4.658 22.0270.000 2.704 817.032.272.587 0.000 78.20 8.10 180.0 7/31/2024 14:31 0.19976.6686.471 5.476 784.8494.902 0.000 0.000 52.4580.0009.270 4.436 23.2770.000 2.643 817.033.543.025 0.000 76.87 8.06 180.0 7/31/2024 14:32 0.00075.5526.478 5.461 788.8684.930 0.000 0.000 52.5620.0009.462 4.593 23.2040.000 2.680 817.033.402.666 0.000 75.55 8.10 180.0 7/31/2024 14:33 0.02276.6096.547 5.474 790.9294.993 0.000 0.000 51.4710.0009.445 4.597 23.3080.000 2.459 817.033.343.070 0.000 76.63 8.06 180.0 7/31/2024 14:34 0.00082.70310.000 5.241 788.2520.000 0.000 0.000 48.6340.00011.143 4.028 22.2920.000 2.908 817.032.873.118 0.000 82.70 8.11 180.0 7/31/2024 14:35 0.00079.4307.701 5.443 794.6244.233 0.000 0.000 51.4710.00010.411 4.697 22.4130.000 2.586 817.032.833.163 0.000 79.43 8.09 180.0 7/31/2024 14:36 0.00081.2998.095 5.427 788.1312.779 0.000 0.000 50.5330.00010.627 4.330 22.0480.000 2.786 817.032.633.181 0.000 81.30 8.12 180.0 7/31/2024 14:37 0.00078.2457.590 5.410 788.8282.467 0.000 0.000 51.2760.00010.118 4.077 23.0500.000 2.738 817.033.483.350 0.000 78.24 8.17 179.0 7/31/2024 14:38 0.00077.7558.441 5.341 791.4911.504 0.000 0.333 49.3160.00011.883 3.956 22.7760.000 2.857 817.033.313.275 0.000 77.76 8.13 180.0 7/31/2024 14:39 0.00077.4536.985 5.438 783.2164.587 0.000 0.000 50.4530.00010.239 4.476 22.9710.000 2.793 817.033.733.281 0.000 77.45 8.08 180.0 7/31/2024 14:40 0.00079.4246.829 5.461 782.5515.164 0.000 0.000 49.9410.0009.773 4.439 22.1330.000 2.741 817.032.422.766 0.000 79.42 8.12 180.0 7/31/2024 14:41 0.00081.8507.767 5.407 784.8552.406 0.000 0.000 49.5530.0009.224 3.913 22.8360.000 2.793 817.033.153.187 0.000 81.85 8.12 180.0 7/31/2024 14:42 0.00081.5058.108 5.420 781.0652.463 0.000 0.935 48.4180.00010.156 3.827 22.4180.000 2.878 817.032.542.724 0.000 81.50 8.10 180.0 7/31/2024 14:43 0.00080.2718.003 5.394 784.3892.315 0.000 0.555 49.1460.0009.512 3.666 22.6190.000 2.978 817.032.892.810 0.000 80.27 8.19 180.0 7/31/2024 14:44 0.00079.8068.036 5.381 786.7492.170 0.000 0.661 49.1520.0009.843 3.887 22.8830.000 2.853 817.033.032.772 0.000 79.81 8.19 180.0 7/31/2024 14:45 0.00080.0737.478 5.435 787.8083.377 0.000 0.299 50.2080.00010.477 3.897 22.2250.000 2.833 817.032.402.871 0.000 80.07 8.08 180.0 7/31/2024 14:46 0.00079.5407.115 5.415 782.1763.851 0.000 0.000 50.7460.00010.173 4.088 22.9730.000 2.749 817.033.543.512 0.000 79.54 8.09 180.0 7/31/2024 14:47 0.00080.6438.564 5.358 774.3731.079 0.000 0.843 48.7590.00010.103 3.758 23.1820.000 2.851 817.033.543.233 0.000 80.64 8.10 179.0 7/31/2024 14:48 0.00079.4277.001 5.453 779.8654.937 0.000 0.240 51.3610.00011.008 4.152 23.1560.000 2.742 817.033.433.030 0.000 79.43 8.11 180.0 7/31/2024 14:49 0.00078.8857.242 5.431 780.4984.620 0.000 0.000 49.6880.0009.677 4.242 23.2260.000 2.622 817.033.323.027 0.000 78.89 8.12 180.0 7/31/2024 14:50 0.00077.6086.747 5.461 784.7985.177 0.000 0.000 50.7840.0009.691 4.659 22.7390.000 2.864 817.033.442.796 0.000 77.61 8.14 180.0 7/31/2024 14:51 0.00078.8617.831 5.233 752.0187.943 0.000 0.066 47.2780.00011.057 4.681 26.6520.000 2.854 817.037.953.712 0.135 78.86 5.06 180.0 0.21477.7717.010 5.404 775.9264.190 0.000 0.131 50.2740.0009.763 4.239 22.6910.000 2.704 817.0032.8992.960 0.005 77.984 7.999 179.9Avg. Spike 1 7/31/2024 15:04 0.00092.5355.636 5.421 713.88042.868 0.000 0.000 42.2540.0009.314 6.302 42.3480.000 3.047 817.055.544.339 0.795 92.53 7.51 180.0 Run 1 - B 30minute/60min 7/31/2024 15:06 0.00083.9115.960 5.495 745.15618.071 0.000 0.000 47.1060.0008.462 5.262 28.5850.000 3.030 817.040.453.440 0.247 83.91 8.04 180.0 7/31/2024 15:07 0.00077.5776.274 5.493 770.3795.802 0.000 0.000 50.0040.0008.953 4.805 23.3910.000 2.715 817.034.073.072 0.000 77.58 8.12 180.0 7/31/2024 15:09 0.00079.3316.386 5.527 766.0915.954 0.000 0.000 49.8430.0008.444 4.252 22.9560.000 2.659 817.033.052.905 0.000 79.33 8.08 180.0 7/31/2024 15:10 0.00081.2337.879 5.448 769.7152.562 0.000 0.253 49.6530.00010.096 3.961 23.3530.000 2.643 817.033.303.032 0.000 81.23 8.21 180.0 7/31/2024 15:11 0.00082.66511.413 5.230 757.0310.000 0.000 1.630 45.9730.00012.530 3.225 23.5030.000 3.174 817.034.093.132 0.000 82.67 8.21 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 7/31/2024 15:12 0.00078.8247.491 5.408 769.9952.867 0.000 1.588 49.8900.00010.852 4.158 23.4580.000 2.846 817.033.983.093 0.000 78.82 8.12 180.0 7/31/2024 15:13 0.00079.5277.722 5.447 771.4922.517 0.000 1.805 50.0610.00010.221 3.939 23.6860.000 2.704 817.033.893.256 0.000 79.53 8.18 180.0 7/31/2024 15:14 0.00078.2966.432 5.499 766.4935.626 0.000 0.000 50.1260.0009.701 4.457 22.8420.000 2.817 817.033.282.754 0.000 78.30 8.22 180.0 7/31/2024 15:15 0.00077.0836.421 5.460 765.3835.234 0.000 0.000 50.5320.0009.107 4.585 24.2570.000 2.512 817.034.553.312 0.000 77.08 8.15 180.0 7/31/2024 15:16 0.00078.4096.439 5.494 763.5845.565 0.000 0.000 50.1480.0009.424 4.810 23.4280.000 2.693 817.034.203.263 0.000 78.41 8.10 179.0 7/31/2024 15:17 0.00077.9196.442 5.528 763.9705.789 0.000 0.000 49.3680.0008.743 4.566 23.2970.000 2.904 817.034.032.817 0.000 77.92 8.20 180.0 7/31/2024 15:18 0.00077.7416.446 5.508 768.2775.157 0.000 0.000 50.8870.0009.350 4.696 23.3650.000 2.842 817.034.092.872 0.000 77.74 8.10 180.0 7/31/2024 15:19 0.00080.6176.992 5.514 765.9423.448 0.000 0.000 49.9090.0008.020 4.256 22.9780.000 2.773 817.033.703.505 0.000 80.62 8.13 180.0 7/31/2024 15:20 0.00081.96011.844 5.223 757.3720.000 0.000 0.577 46.2220.00012.794 3.593 22.1590.000 3.169 817.033.273.560 0.000 81.96 8.05 180.0 7/31/2024 15:21 0.00078.9396.999 5.431 757.7904.414 0.000 0.740 49.4630.00010.703 4.431 23.9410.000 2.758 817.034.272.796 0.000 78.94 8.09 179.0 7/31/2024 15:22 0.00080.7767.563 5.472 767.5302.922 0.000 0.589 48.4130.0008.740 4.107 23.5620.000 2.676 817.033.552.850 0.000 80.78 8.11 180.0 7/31/2024 15:23 0.00079.2496.467 5.498 766.5765.428 0.000 0.000 50.6460.0009.449 4.593 23.1640.000 2.709 817.033.422.658 0.000 79.25 8.11 180.0 7/31/2024 15:24 0.00079.1606.403 5.497 768.3415.741 0.000 0.000 50.3590.0008.970 4.561 23.1700.000 2.550 817.033.613.443 0.000 79.16 8.12 180.0 7/31/2024 15:25 0.00077.5146.433 5.473 761.9135.465 0.000 0.000 50.6680.0009.340 4.914 23.3030.000 2.758 817.034.263.255 0.000 77.51 8.16 180.0 7/31/2024 15:26 0.00076.3116.420 5.491 759.3125.837 0.000 0.000 50.4550.0009.155 4.746 24.0660.000 2.594 817.034.332.863 0.000 76.31 8.12 179.0 7/31/2024 15:27 0.00076.9186.407 5.522 764.8225.781 0.000 0.000 49.4890.0008.815 4.630 23.5590.000 2.601 817.033.542.543 0.000 76.92 8.02 180.0 7/31/2024 15:28 0.00076.4956.419 5.481 763.6095.592 0.000 0.000 50.6390.0009.291 4.601 23.1720.000 2.845 817.033.792.798 0.000 76.50 8.16 180.0 7/31/2024 15:29 0.00077.0066.450 5.482 765.2675.707 0.000 0.000 50.6170.0008.949 4.774 23.3280.000 2.673 817.033.722.794 0.000 77.01 8.18 179.0 7/31/2024 15:30 0.00077.3646.765 5.479 772.4755.171 0.000 0.000 50.5080.0009.249 4.647 23.3850.000 2.678 817.033.332.240 0.000 77.36 8.10 180.0 7/31/2024 15:31 0.00078.2276.914 5.468 763.8284.970 0.000 0.000 49.1180.0009.491 4.278 22.9920.000 2.827 817.033.633.194 0.000 78.23 8.07 180.0 7/31/2024 15:32 0.00078.9466.469 5.465 766.0975.707 0.000 0.000 50.1760.0008.912 4.815 22.9460.000 2.699 817.033.492.905 0.000 78.95 8.18 180.0 7/31/2024 15:33 0.00081.4548.882 5.353 768.5490.490 0.000 0.000 48.9220.0008.962 4.251 23.1240.000 2.677 817.033.663.518 0.000 81.45 8.24 180.0 7/31/2024 15:34 0.00086.9969.028 5.350 768.2730.352 0.000 0.000 46.9450.0007.860 3.980 22.5780.000 2.956 817.033.533.579 0.000 87.00 8.04 180.0 7/31/2024 15:35 0.00076.7286.650 5.437 767.2005.311 0.000 0.000 49.5640.00010.552 4.433 23.5530.000 2.685 817.033.812.895 0.000 76.73 8.15 180.0 7/31/2024 15:36 0.00078.8356.575 5.464 763.9476.355 0.000 0.000 49.5510.0008.964 4.858 23.5140.000 2.678 817.034.092.966 0.000 78.83 8.10 179.0 0.00079.2007.166 5.455 764.8804.795 0.000 0.239 49.5090.0009.470 4.439 23.4870.000 2.762 817.0033.9993.044 0.008 79.201 8.129 179.8Avg. 0.10778.4867.088 5.429 770.4034.492 0.000 0.185 49.8910.0009.617 4.339 23.0890.000 2.733 817.0033.4493.002 0.006 78.593 8.064 179.9Run 1 Avg: Baseline 1 7/31/2024 15:39 0.0000.000-0.009 0.094 0.0000.004 0.067 0.156 0.0000.0000.284 0.000 0.0000.000 0.108 817.00.220.000 0.000 0.00 0.17 180.0 Run 2 - A 30minute/60min 7/31/2024 15:41 0.00071.1194.239 5.381 736.5946.534 0.000 0.000 47.2750.0008.665 4.478 23.1840.000 3.017 817.034.463.381 0.000 71.12 8.00 179.0 7/31/2024 15:42 0.00076.0955.631 5.546 765.0106.909 0.000 0.000 49.7910.0008.398 4.630 23.6250.000 2.674 817.034.002.918 0.000 76.10 8.08 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 7/31/2024 15:43 0.00075.9426.093 5.480 765.0156.192 0.000 0.000 50.5190.0008.724 4.993 23.0210.000 2.842 817.034.163.195 0.000 75.94 8.15 180.0 7/31/2024 15:44 0.00074.0726.326 5.433 763.6286.174 0.000 0.000 48.8860.0009.831 4.517 23.5250.000 2.923 817.034.473.137 0.000 74.07 8.02 179.0 7/31/2024 15:45 1.10876.8216.434 5.507 775.8486.196 0.000 0.000 42.9730.0008.961 4.702 23.1460.000 3.014 817.034.222.867 0.000 77.93 8.12 180.0 7/31/2024 15:46 0.00076.6486.439 5.476 770.3015.681 0.000 0.000 49.9170.0009.221 4.738 23.0110.000 2.716 817.033.743.212 0.000 76.65 8.10 179.0 7/31/2024 15:48 0.00077.9046.464 5.464 773.8385.583 0.000 0.000 49.9640.0009.388 4.727 22.4990.000 2.850 817.033.182.741 0.000 77.90 8.09 180.0 7/31/2024 15:49 0.00078.3636.507 5.474 768.1775.645 0.000 0.000 49.2860.0009.298 4.482 22.5270.000 2.896 817.033.212.851 0.000 78.36 8.13 180.0 7/31/2024 15:50 0.00084.4099.676 5.260 771.5040.000 0.000 0.000 47.4270.0008.646 4.082 22.6020.000 2.936 817.033.333.197 0.000 84.41 8.09 179.0 7/31/2024 15:51 0.00078.5327.262 5.441 771.8194.955 0.000 0.000 49.3420.0009.735 4.253 22.0390.000 2.815 817.032.583.111 0.000 78.53 8.11 180.0 7/31/2024 15:52 0.00079.2457.291 5.448 773.8314.050 0.000 0.000 48.5910.0009.611 4.474 22.2820.000 2.872 817.033.002.991 0.000 79.25 8.01 180.0 7/31/2024 15:53 0.00080.8788.412 5.355 766.9323.121 0.000 0.000 46.9080.00010.187 4.237 21.7500.000 3.044 817.032.813.216 0.000 80.88 8.14 179.0 7/31/2024 15:54 0.00078.6107.216 5.437 767.4344.233 0.000 0.000 47.4390.00010.376 4.683 22.5910.000 3.104 817.034.073.226 0.000 78.61 8.12 180.0 7/31/2024 15:55 0.00079.5867.384 5.436 766.0274.376 0.000 0.000 48.1960.0009.888 4.650 22.5120.000 2.801 817.033.433.320 0.000 79.59 8.17 179.0 7/31/2024 15:56 0.00079.3227.135 5.470 769.0705.757 0.000 0.000 48.0550.0009.516 4.804 22.2700.000 2.869 817.032.792.367 0.000 79.32 8.17 180.0 7/31/2024 15:57 0.00078.1446.681 5.458 776.0165.951 0.000 0.000 49.6460.0009.383 4.639 22.3390.000 2.834 817.033.052.928 0.000 78.14 8.15 180.0 7/31/2024 15:58 0.00078.0497.782 5.368 776.1293.892 0.000 0.000 48.8450.0009.892 4.231 21.9970.000 3.064 817.033.213.400 0.000 78.05 8.06 180.0 7/31/2024 15:59 0.00081.1117.522 5.415 766.4754.103 0.000 0.000 48.2370.0009.351 4.621 21.8800.000 3.021 817.033.073.097 0.000 81.11 8.12 180.0 7/31/2024 16:00 0.00078.5476.654 5.429 767.0886.076 0.000 0.000 49.2290.00010.035 4.772 22.0840.000 2.825 817.032.772.786 0.000 78.55 8.20 179.0 7/31/2024 16:01 0.00082.3588.462 5.393 770.7122.670 0.000 0.077 46.3830.0009.737 3.834 21.7530.000 3.026 817.032.042.519 0.000 82.36 8.15 180.0 7/31/2024 16:02 0.00080.3578.300 5.393 771.0583.447 0.000 0.112 47.5580.00010.984 4.401 21.9020.000 2.944 817.032.492.643 0.000 80.36 8.17 180.0 7/31/2024 16:03 0.00078.0876.607 5.435 765.5236.117 0.000 0.000 47.9610.0009.512 4.575 22.0250.000 3.028 817.032.862.586 0.000 78.09 8.03 179.0 7/31/2024 16:04 0.00080.9428.291 5.353 770.8352.329 0.000 0.093 47.7060.00011.779 4.330 22.3710.000 2.888 817.033.233.297 0.000 80.94 8.10 180.0 7/31/2024 16:05 0.00078.5246.552 5.419 762.7294.683 0.000 0.000 48.5030.0009.554 4.701 21.9970.000 3.053 817.033.222.968 0.000 78.52 8.17 179.0 7/31/2024 16:06 0.00079.1276.497 5.497 767.1105.942 0.000 0.000 48.2040.0009.362 4.552 22.4020.000 2.796 817.033.022.992 0.000 79.13 8.08 180.0 7/31/2024 16:07 0.00078.0626.733 5.469 772.3245.405 0.000 0.000 48.2590.0009.726 4.675 22.2760.000 2.844 817.033.123.053 0.000 78.06 8.17 180.0 7/31/2024 16:08 0.00081.1117.773 5.418 770.5002.419 0.000 0.000 47.8080.0008.754 4.677 22.0600.000 2.933 817.033.012.951 0.000 81.11 8.07 180.0 7/31/2024 16:09 0.00086.6789.380 5.294 773.5400.040 0.000 0.504 47.0310.00011.988 4.146 21.3200.000 3.164 817.032.663.365 0.000 86.68 8.05 180.0 7/31/2024 16:10 0.00079.6586.557 5.488 768.0895.936 0.000 0.000 48.5440.0009.670 4.399 21.8960.000 2.876 817.032.633.069 0.000 79.66 8.08 180.0 7/31/2024 16:11 0.00079.2036.567 5.469 771.0405.808 0.000 0.000 48.6030.0009.532 4.548 22.7290.000 2.697 817.033.593.655 0.000 79.20 8.16 180.0 0.03778.9177.096 5.430 768.4734.674 0.000 0.026 48.2360.0009.657 4.518 22.3870.000 2.912 817.0033.2473.035 0.000 78.954 8.109 179.7Avg. Spike 2 7/31/2024 16:14 0.00093.7186.081 5.448 711.82941.569 0.000 0.000 41.2420.0008.789 5.995 40.1670.000 3.168 817.052.693.284 0.768 93.72 7.48 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Run 2 - B 30minute/60min 7/31/2024 16:16 0.00088.6119.496 5.276 743.4748.310 0.000 0.188 42.5140.00010.935 4.604 27.2350.000 3.365 817.039.313.417 0.173 88.61 8.14 179.0 7/31/2024 16:17 0.00078.7967.103 5.409 771.0534.120 0.000 0.000 49.1050.00011.131 4.378 22.3820.000 2.988 817.033.653.557 0.000 78.80 8.13 180.0 7/31/2024 16:18 0.00079.2096.514 5.441 765.1505.523 0.000 0.000 47.8950.00010.170 4.678 22.4850.000 2.845 817.033.543.365 0.000 79.21 8.18 179.0 7/31/2024 16:19 0.00079.8606.549 5.476 773.7176.020 0.000 0.000 48.7890.0009.511 4.592 21.6800.000 2.968 817.032.793.167 0.000 79.86 8.11 180.0 7/31/2024 16:20 0.00080.5146.696 5.463 766.3375.535 0.000 0.000 47.2210.00010.008 4.684 21.7550.000 2.977 817.032.903.108 0.000 80.51 8.06 180.0 7/31/2024 16:21 0.00080.7506.814 5.421 763.7524.481 0.000 0.000 46.1820.0009.256 4.476 21.6820.000 3.213 817.033.283.286 0.000 80.75 8.18 180.0 7/31/2024 16:22 0.00079.4316.619 5.445 764.6345.825 0.000 0.000 46.6480.0009.786 4.625 22.0330.000 2.981 817.033.383.447 0.000 79.43 8.14 180.0 7/31/2024 16:23 0.00079.6416.597 5.489 764.4845.716 0.000 0.000 47.7400.0009.647 4.676 21.8660.000 2.968 817.032.632.573 0.000 79.64 8.06 180.0 7/31/2024 16:24 0.00079.5386.603 5.490 767.4005.745 0.000 0.000 47.4350.0009.740 4.576 21.6940.000 2.937 817.032.332.564 0.000 79.54 8.10 180.0 7/31/2024 16:26 0.00079.5736.620 5.487 769.2105.772 0.000 0.000 47.9710.00010.025 4.684 21.5390.000 2.878 817.032.312.837 0.000 79.57 8.21 180.0 7/31/2024 16:27 0.00083.24012.258 5.165 761.1610.000 0.000 0.233 43.1310.00014.297 3.729 20.8970.000 3.339 817.032.373.456 0.000 83.24 8.08 180.0 7/31/2024 16:28 0.00080.7236.967 5.434 764.0813.973 0.000 0.000 47.0370.00010.838 4.704 21.9590.000 3.182 817.033.483.029 0.000 80.72 8.07 180.0 7/31/2024 16:29 0.00079.6626.970 5.450 763.9715.203 0.000 0.000 47.4100.00010.776 4.751 21.8820.000 2.964 817.033.053.113 0.000 79.66 8.12 180.0 7/31/2024 16:30 0.00083.9559.062 5.353 770.6190.499 0.000 0.399 45.6800.00013.033 3.891 21.9140.000 3.042 817.033.033.652 0.000 83.96 8.13 180.0 7/31/2024 16:31 0.00079.0136.626 5.471 769.7025.598 0.000 0.000 48.4940.00010.718 4.869 22.0660.000 2.880 817.033.103.046 0.000 79.01 8.17 180.0 7/31/2024 16:32 0.00083.0788.319 5.361 765.1142.031 0.000 0.501 46.0460.00011.973 4.134 21.6230.000 3.226 817.033.043.313 0.000 83.08 8.23 180.0 7/31/2024 16:33 0.00081.3736.817 5.422 763.0074.400 0.000 0.000 47.6070.0009.597 4.373 22.2750.000 2.947 817.033.233.225 0.000 81.37 8.15 180.0 7/31/2024 16:34 0.00078.9476.651 5.477 764.8505.804 0.000 0.000 48.6420.0009.880 4.586 22.5730.000 2.828 817.033.593.458 0.000 78.95 8.12 180.0 7/31/2024 16:35 0.00080.8396.623 5.494 770.7125.808 0.000 0.000 47.8040.0009.716 4.749 22.2350.000 2.842 817.033.093.000 0.000 80.84 8.09 180.0 7/31/2024 16:36 0.00079.6416.620 5.430 761.8564.702 0.000 0.000 47.9710.0009.214 4.763 22.3020.000 2.954 817.033.142.636 0.000 79.64 8.08 179.0 7/31/2024 16:37 0.00078.6016.652 5.480 769.2825.574 0.000 0.000 48.3190.0009.946 4.778 22.5780.000 2.821 817.033.222.716 0.000 78.60 8.15 179.0 7/31/2024 16:38 0.00081.9296.674 5.523 762.8016.001 0.000 0.000 47.9820.0009.430 4.627 21.9220.000 2.808 816.032.202.371 0.000 81.93 8.11 180.0 7/31/2024 16:39 0.00079.2256.670 5.494 768.2905.958 0.000 0.000 48.8330.00010.046 4.569 22.6100.000 2.963 816.033.703.174 0.000 79.23 8.14 180.0 7/31/2024 16:40 0.00079.6036.645 5.517 769.3315.933 0.000 0.000 48.6120.00010.464 4.610 22.7720.000 2.941 816.033.612.817 0.000 79.60 8.10 180.0 7/31/2024 16:41 0.00079.8676.645 5.460 766.4354.521 0.000 0.000 47.8790.0009.620 4.747 22.5250.000 2.968 816.033.452.739 0.000 79.87 8.15 180.0 7/31/2024 16:42 0.00085.85010.933 5.232 759.7280.000 0.000 0.000 44.7810.00010.408 3.893 21.3000.000 3.386 816.032.693.026 0.000 85.85 8.11 179.0 7/31/2024 16:43 0.00081.1656.663 5.507 768.4295.834 0.000 0.000 48.9460.0009.150 4.592 22.1020.000 2.857 816.032.782.861 0.000 81.16 8.14 180.0 7/31/2024 16:44 0.00080.9536.543 5.495 759.0235.833 0.000 0.000 48.2650.0009.528 4.868 22.4560.000 2.853 816.033.473.098 0.000 80.95 8.11 180.0 7/31/2024 16:45 0.00079.2617.010 5.445 758.2665.346 0.000 0.000 48.1840.0009.832 4.851 22.5920.000 2.965 816.033.813.074 0.000 79.26 8.05 180.0 7/31/2024 16:46 0.00079.8396.550 5.366 746.5876.839 0.000 0.000 46.7770.0009.681 4.760 24.1760.000 3.110 816.036.153.864 0.049 79.84 6.86 180.0 0.00080.7567.250 5.432 764.4154.897 0.000 0.044 47.3300.00010.279 4.561 22.3040.000 3.000 816.7033.4113.100 0.007 80.756 8.082 179.8Avg. 0.01879.8377.173 5.431 766.4444.785 0.000 0.035 47.7830.0009.968 4.539 22.3450.000 2.956 816.8533.3293.067 0.004 79.855 8.096 179.8Run 2 Avg: GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline 2 7/31/2024 16:48 0.9570.0000.185 0.047 3.4840.000 0.000 0.443 0.4820.0000.640 0.000 0.0000.000 0.047 816.00.090.000 0.000 0.96 0.16 180.0 Run 3 - A 30minute/60min 7/31/2024 16:50 10.09763.7143.095 4.514 569.5804.348 0.000 0.000 44.3530.0005.081 3.602 17.3470.000 1.520 816.023.511.080 0.000 73.81 7.90 180.0 7/31/2024 16:51 0.00076.8355.559 5.514 755.5097.032 0.000 0.000 48.1920.0009.343 4.808 22.8710.000 3.071 816.034.263.069 0.000 76.83 8.06 180.0 7/31/2024 16:52 0.00076.4976.045 5.459 758.4736.021 0.000 0.000 48.8320.0009.032 4.763 22.8880.000 2.904 816.033.792.878 0.000 76.50 8.15 179.0 7/31/2024 16:53 0.00077.8836.240 5.467 760.7896.228 0.000 0.000 47.8990.0008.897 4.728 22.4580.000 2.941 816.033.262.651 0.000 77.88 8.17 180.0 7/31/2024 16:54 0.00078.2686.352 5.476 761.9356.179 0.000 0.000 48.4790.0008.829 4.665 22.4780.000 2.806 816.033.223.036 0.000 78.27 8.09 180.0 7/31/2024 16:55 0.00078.6546.373 5.461 753.1725.854 0.000 0.000 48.4390.0009.936 4.914 22.4500.000 3.053 816.033.632.693 0.000 78.65 8.17 180.0 7/31/2024 16:56 0.00078.1386.453 5.452 764.5325.863 0.000 0.000 48.1440.0009.711 4.704 22.6820.000 2.932 816.033.943.381 0.000 78.14 8.11 180.0 7/31/2024 16:57 0.00078.3116.451 5.490 764.8215.913 0.000 0.000 47.4670.0009.586 4.695 22.1890.000 3.157 816.034.093.687 0.000 78.31 8.17 180.0 7/31/2024 16:58 0.00080.5506.457 5.496 771.1536.481 0.000 0.000 48.2010.0008.487 4.332 22.0310.000 2.854 816.032.633.002 0.000 80.55 8.19 180.0 7/31/2024 16:59 0.00090.1529.528 5.304 769.5270.000 0.000 0.000 45.3190.0008.036 3.851 21.5220.000 3.220 816.032.813.421 0.000 90.15 8.16 180.0 7/31/2024 17:00 0.00083.4107.601 5.379 769.0823.768 0.000 0.000 47.6890.0008.829 4.303 21.6300.000 2.888 816.032.483.302 0.000 83.41 8.18 179.0 7/31/2024 17:01 0.00082.2237.517 5.401 757.6234.362 0.000 0.000 46.3280.0009.444 4.655 21.4780.000 3.234 816.033.163.172 0.000 82.22 8.17 180.0 7/31/2024 17:02 0.00080.2966.647 5.459 764.4745.892 0.000 0.000 47.8410.0009.715 4.842 22.3630.000 2.962 816.033.903.582 0.000 80.30 8.15 180.0 7/31/2024 17:03 0.00080.7216.928 5.476 766.7005.279 0.000 0.000 46.3730.0009.210 4.621 21.9500.000 2.937 816.032.712.706 0.000 80.72 8.17 180.0 7/31/2024 17:05 0.00082.4688.134 5.388 777.0972.247 0.000 0.000 47.9550.0009.345 4.395 21.8280.000 2.670 816.032.213.166 0.000 82.47 8.13 180.0 7/31/2024 17:06 0.00080.2447.352 5.414 766.5603.010 0.000 0.000 48.4740.0009.532 4.342 21.8540.000 2.890 816.032.593.085 0.000 80.24 8.12 180.0 7/31/2024 17:07 0.00082.1167.611 5.418 766.4022.724 0.000 0.000 46.8810.00010.808 4.530 22.0560.000 2.857 816.033.173.574 0.000 82.12 8.11 180.0 7/31/2024 17:08 0.00078.2406.746 5.460 776.9875.311 0.000 0.000 49.7740.0009.414 4.491 22.6520.000 2.640 816.032.983.084 0.000 78.24 8.11 180.0 7/31/2024 17:09 0.00079.6947.122 5.445 768.5813.627 0.000 0.000 48.3200.0009.847 4.374 22.1460.000 2.771 816.032.813.308 0.000 79.69 8.05 179.0 7/31/2024 17:10 0.00077.9727.142 5.477 776.8625.117 0.000 0.000 49.0030.00010.102 4.509 22.0810.000 2.735 816.032.803.369 0.000 77.97 8.20 180.0 7/31/2024 17:11 0.00082.4549.272 5.350 767.6810.643 0.000 0.000 45.8720.0009.926 3.957 21.3420.000 3.089 816.032.443.416 0.000 82.45 8.12 180.0 7/31/2024 17:12 0.00077.7026.622 5.474 761.9965.470 0.000 0.000 46.9100.0009.961 4.449 22.3340.000 2.821 816.033.413.704 0.000 77.70 8.10 180.0 7/31/2024 17:13 0.00077.9036.942 5.406 764.3893.665 0.000 0.000 47.6970.0009.879 4.501 22.1010.000 2.966 816.033.333.440 0.000 77.90 8.15 180.0 7/31/2024 17:14 0.00076.5466.441 5.460 768.9655.292 0.000 0.000 48.5140.0009.714 4.698 22.5240.000 2.694 816.033.002.932 0.000 76.55 8.13 179.0 7/31/2024 17:15 0.00076.6286.505 5.452 773.0105.324 0.000 0.000 48.8720.0009.782 4.487 22.5000.000 2.619 816.032.692.944 0.000 76.63 8.12 180.0 7/31/2024 17:16 0.00083.6769.104 5.303 769.6140.144 0.000 0.000 46.8180.0009.847 4.136 22.1820.000 2.934 816.033.453.961 0.000 83.68 8.10 179.0 7/31/2024 17:17 0.00077.6147.002 5.473 779.9394.648 0.000 0.000 47.8340.00010.356 4.632 21.9120.000 2.662 816.032.343.024 0.000 77.61 8.10 180.0 7/31/2024 17:18 0.00086.6088.370 5.386 768.1260.346 0.000 0.060 45.7900.00010.710 3.938 22.1470.000 2.752 816.032.493.324 0.000 86.61 8.14 180.0 7/31/2024 17:19 0.00077.9778.333 5.379 767.2182.084 0.000 0.539 45.5610.00011.009 4.480 22.5080.000 2.919 816.033.863.790 0.000 77.98 8.14 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 7/31/2024 17:20 0.00077.1756.878 5.429 771.7603.422 0.000 0.000 48.2980.00010.472 4.825 22.3070.000 2.762 816.033.433.578 0.000 77.18 8.04 180.0 0.33779.3567.027 5.402 760.4194.210 0.000 0.020 47.5380.0009.495 4.474 22.0270.000 2.842 816.0032.8133.179 0.000 79.692 8.123 179.8Avg. Spike 3 7/31/2024 17:23 0.00091.3635.869 5.413 710.34041.321 0.000 0.000 40.5510.0009.088 6.507 40.7470.000 2.852 816.053.163.557 0.765 91.36 7.57 180.0 Run 3 - B 30minute/60min 7/31/2024 17:25 0.00079.5336.061 5.499 753.00917.139 0.000 0.000 46.9050.0008.813 5.061 28.2850.000 2.913 816.039.553.095 0.230 79.53 8.08 180.0 7/31/2024 17:26 0.00076.3846.311 5.504 773.9395.985 0.000 0.000 48.9470.0009.229 4.713 22.5370.000 2.690 816.032.892.746 0.000 76.38 8.22 180.0 7/31/2024 17:27 0.00075.8416.372 5.542 778.3326.293 0.000 0.000 49.6750.0009.089 4.721 22.4140.000 2.607 816.032.692.871 0.000 75.84 8.15 180.0 7/31/2024 17:28 0.00076.1386.398 5.504 776.8705.914 0.000 0.000 49.3250.0009.322 4.657 22.6860.000 2.578 816.032.762.715 0.000 76.14 8.14 180.0 7/31/2024 17:29 0.00086.1029.732 5.275 767.1180.000 0.000 0.266 45.1780.00011.600 3.844 22.2420.000 2.858 816.032.933.616 0.000 86.10 8.12 180.0 7/31/2024 17:30 0.00077.7707.610 5.395 772.1213.373 0.000 0.228 46.9940.00011.585 4.181 22.3260.000 2.826 816.032.953.283 0.000 77.77 8.21 180.0 7/31/2024 17:31 0.00075.4786.371 5.443 770.7096.130 0.000 0.000 48.0190.0009.094 4.755 22.2190.000 2.657 816.032.432.589 0.000 75.48 8.19 179.0 7/31/2024 17:32 0.00076.1936.512 5.446 763.8056.119 0.000 0.000 47.5500.0009.179 4.639 22.2890.000 2.767 816.032.762.772 0.000 76.19 8.19 180.0 7/31/2024 17:33 0.00075.4616.376 5.418 771.3625.453 0.000 0.000 48.8100.0008.593 4.684 22.8220.000 2.665 816.033.102.744 0.000 75.46 8.24 180.0 7/31/2024 17:34 0.00074.6076.354 5.431 763.0446.234 0.000 0.000 47.1830.0008.914 4.622 22.5550.000 2.751 816.032.932.694 0.000 74.61 8.25 179.0 7/31/2024 17:35 0.00076.0866.469 5.486 766.4636.195 0.000 0.000 47.3070.0008.237 4.787 22.2350.000 2.698 816.032.582.635 0.000 76.09 8.12 180.0 7/31/2024 17:36 0.00084.1989.421 5.231 764.0970.000 0.000 0.297 44.5900.00011.563 4.228 22.2590.000 2.916 816.033.023.157 0.000 84.20 8.19 180.0 7/31/2024 17:37 0.00073.5166.309 5.429 766.5066.276 0.000 0.000 48.1780.0009.584 4.866 23.1700.000 2.752 816.034.143.329 0.000 73.52 8.26 180.0 7/31/2024 17:38 0.00075.0936.539 5.416 773.4114.197 0.000 0.000 49.0420.0008.984 4.576 23.3060.000 2.412 816.033.062.815 0.000 75.09 8.26 180.0 7/31/2024 17:39 0.00077.7747.807 5.309 770.1292.835 0.000 0.518 46.4300.00010.464 4.454 22.9080.000 2.757 816.033.653.395 0.000 77.77 8.11 179.0 7/31/2024 17:40 0.00075.1846.327 5.476 759.7806.449 0.000 0.000 48.3170.0008.723 4.820 22.9570.000 2.828 816.033.843.016 0.000 75.18 8.30 180.0 7/31/2024 17:41 0.00074.1836.323 5.478 765.5126.585 0.000 0.000 48.4240.0008.562 4.679 22.9350.000 2.858 816.033.963.279 0.000 74.18 8.20 180.0 7/31/2024 17:42 0.00073.1016.390 5.428 769.7765.965 0.000 0.000 49.3350.00010.057 4.795 23.3580.000 2.717 816.033.892.846 0.000 73.10 8.22 180.0 7/31/2024 17:44 0.00074.9176.413 5.419 768.4034.810 0.000 0.000 48.7870.0009.400 4.853 23.2040.000 2.769 816.034.343.539 0.000 74.92 8.17 180.0 7/31/2024 17:45 0.00073.9146.385 5.441 768.2196.241 0.000 0.000 48.2050.0009.970 4.573 22.6020.000 2.703 816.033.243.276 0.000 73.91 8.16 178.0 7/31/2024 17:46 0.00085.51910.984 5.276 763.7430.000 0.000 0.305 44.4160.0009.749 3.170 21.6310.000 2.926 816.031.783.270 0.000 85.52 8.18 180.0 7/31/2024 17:47 0.00076.2206.671 5.414 769.6085.633 0.000 0.095 48.9100.00011.550 4.285 23.3330.000 2.580 816.033.503.227 0.000 76.22 8.13 180.0 7/31/2024 17:48 0.00073.7156.405 5.424 758.9175.566 0.000 0.000 48.7470.0009.404 4.729 23.3630.000 2.699 816.033.672.634 0.000 73.72 8.18 179.0 7/31/2024 17:49 0.00074.9916.419 5.469 766.6816.000 0.000 0.000 49.8760.0009.317 4.731 22.8410.000 2.674 816.033.252.862 0.000 74.99 8.18 180.0 7/31/2024 17:50 0.00074.4996.404 5.448 774.9515.865 0.000 0.000 50.1640.0009.607 4.774 23.0420.000 2.679 816.033.482.848 0.000 74.50 8.20 180.0 7/31/2024 17:51 0.00077.8927.500 5.431 771.8743.600 0.000 0.000 48.3080.0008.669 4.423 22.4470.000 2.633 816.032.713.080 0.000 77.89 8.16 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 7/31/2024 17:52 0.00076.9236.589 5.463 764.8395.669 0.000 0.000 48.8720.0009.309 4.882 22.3060.000 2.749 816.032.702.462 0.000 76.92 8.20 180.0 7/31/2024 17:53 0.00075.9746.901 5.392 763.6874.296 0.000 0.000 47.7730.0009.435 4.376 22.8330.000 3.003 816.033.462.556 0.000 75.97 8.23 180.0 7/31/2024 17:54 0.00075.3716.477 5.389 771.9014.559 0.000 0.000 49.7390.0009.740 4.689 23.0630.000 2.751 816.033.813.175 0.000 75.37 8.19 180.0 7/31/2024 17:55 0.41665.7117.503 3.925 539.6676.572 0.000 0.000 37.6430.0004.834 3.593 20.7490.000 1.477 816.026.831.099 0.186 66.13 2.73 179.0 0.01476.2766.944 5.373 760.2825.332 0.000 0.057 47.7220.0009.419 4.539 22.8310.000 2.696 816.0033.1972.921 0.014 76.290 8.005 179.8Avg. 0.17577.8166.986 5.388 760.3514.771 0.000 0.038 47.6300.0009.457 4.506 22.4290.000 2.769 816.0033.0053.050 0.007 77.991 8.064 179.8Run 3 Avg: Baseline 3 7/31/2024 17:57 0.9660.000-0.001 0.071 2.0640.000 0.000 0.513 0.2990.3002.311 0.000 0.0000.000 0.072 816.00.140.000 0.000 0.97 0.12 180.0 Post CTS 7/31/2024 18:24 0.0000.000-0.032 0.056 2.2620.000 0.000 0.058 1.0980.4320.000 100.238 0.0000.395 0.101 817.067.030.000 0.000 0.00 0.29 180.0 7/31/2024 18:24 0.0000.000-0.030 0.092 1.2870.000 0.000 0.000 1.3200.0480.000 100.631 0.5590.463 0.221 817.068.090.000 0.000 0.00 0.07 180.0 7/31/2024 18:25 5.1840.000-0.031 0.053 2.0750.000 0.000 0.000 2.2010.0260.000 101.358 0.0000.022 0.000 817.067.580.000 0.000 5.18 0.19 180.0 7/31/2024 18:25 0.0000.000-0.031 0.046 0.1840.000 0.000 0.000 0.4971.7050.000 101.583 0.3670.856 0.033 817.068.160.000 0.000 0.00 0.26 180.0 Post NO2/Mid O2 7/31/2024 18:26 103.7930.430-0.032 0.032 0.0000.000 0.669 0.030 0.0000.0000.000 0.000 0.2520.047 0.000 819.00.630.563 0.000 104.22 10.24 180.0 7/31/2024 18:26 98.2120.000-0.030 0.044 0.0000.000 0.708 0.000 0.2230.0001.917 0.000 0.0000.000 0.000 819.00.000.000 0.000 98.21 10.24 179.0 7/31/2024 18:26 97.9090.933-0.031 0.000 0.0000.505 0.845 0.424 0.0000.0021.754 0.000 0.0000.839 0.045 819.00.090.000 0.000 98.84 10.31 179.0 Post 5-Gas 7/31/2024 18:31 0.000238.764-0.031 4.578 0.000480.550 0.896 1.233 0.7180.0002.056 2.044 255.2580.000 0.000 825.0257.611.480 10.028 238.76 0.02 180.0 7/31/2024 18:31 0.000240.061-0.031 4.585 0.667481.100 0.867 1.705 2.2341.6101.327 2.034 255.0050.000 0.000 825.0258.352.985 10.054 240.06 0.02 180.0 7/31/2024 18:31 0.000235.819-0.031 4.557 0.326481.458 1.048 1.190 0.9210.1851.231 1.938 254.7920.000 0.012 825.0257.231.680 10.071 235.82 0.02 180.0 7/31/2024 18:31 0.000240.854-0.031 4.601 1.736484.264 0.850 1.652 0.4760.0830.583 2.372 256.8910.000 0.000 825.0259.541.604 10.001 240.85 0.16 180.0 7/31/2024 18:31 0.000238.448-0.031 4.523 0.000485.430 0.770 1.130 0.0000.0441.773 2.039 256.4870.756 0.000 826.0260.083.345 10.035 238.45 0.15 179.0 7/31/2024 18:31 0.000238.430-0.031 4.537 0.000481.043 0.819 1.403 0.0000.0501.705 2.074 255.1260.000 0.000 826.0257.401.331 10.036 238.43 0.19 179.0 End of Test Purge 7/31/2024 18:33 0.0000.000-0.032 0.049 0.4710.000 0.035 0.000 0.1260.5561.803 0.000 0.0000.565 0.120 828.00.240.000 0.000 0.00 0.17 180.0 7/31/2024 18:34 0.3250.000-0.031 0.022 0.0000.073 0.027 0.000 0.2800.0080.604 0.000 0.0000.000 0.313 828.00.630.000 0.000 0.32 0.13 180.0 7/31/2024 18:34 0.0000.000-0.031 0.020 0.9600.000 0.000 0.000 0.0000.2310.035 0.000 0.3181.222 0.182 828.00.680.000 0.000 0.00 0.24 180.0 7/31/2024 18:34 0.3720.000-0.031 0.045 0.1100.000 0.016 0.000 0.2900.0151.544 0.000 0.3290.000 0.121 828.00.730.243 0.000 0.37 0.14 180.0 7/31/2024 18:34 0.3210.000-0.031 0.035 0.5530.000 0.000 0.000 0.0000.0000.047 0.000 0.2020.000 0.000 828.00.200.000 0.000 0.32 0.00 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 7/31/2024 18:34 0.0000.000-0.032 0.026 0.9250.000 0.000 0.305 0.0000.7930.000 0.000 1.1110.000 0.143 829.01.400.000 0.000 0.00 0.12 180.0 7/31/2024 18:34 1.0290.000-0.031 0.040 0.4250.000 0.000 0.188 0.7970.1220.000 0.000 0.0000.213 0.063 830.00.130.000 0.000 1.03 0.13 179.0 7/31/2024 18:34 1.9120.000-0.032 0.018 0.0000.000 0.013 0.000 0.7550.0621.563 0.000 0.5810.000 0.000 831.00.580.000 0.000 1.91 0.13 179.0 GAS, Inc. 303 W. 3rd St Elk City , OK 73644(580) 225-0403 Test Started:Test Completed:02:21 PM 06:31 PM Permit #: #DAQE-ANl 1679008-13 Location: Duchesne County, Utah Prepared on Behalf of: Scout Energy Management, LLC Ashley Compressor Station CO NOx NMNEHC 0.850 3.040 2.130 0.030 0.824 0.333 5.040 84.821 35.796 2.000 1.000 0.700 0.011 0.301 0.122 Pass Pass Pass Pass Pass Pass Federal State Federal State Federal State Results lb/hr Results ppmvd Permit lb/hr Results g/hp-hr Permit g/hp-hr PASS ALL 40 CFR Part 60 Subpart JJJJ Performance Test Report Test Type: Initial Test Date: 7/31/2024 DOM: 3/1/12 Source: Caterpillar 3516TALE Lean Burn (4 Cycle) Unit Number: Unit #3 Serial Number: JEF01561 Engine Hours: 39742.3 Index Tables Figures Appendices Table 5.1 (Run Summaries)................................................................ Table 6.1 (Volumetric Flow Rate Data)............................................... Table 6.2 (Stack Gas Measurements)................................................. Table 8.1 (Oxygen Calibration)........................................................... Annex Table 1.2.1 (Certified Calibration Bottle Concentrations)......... Annex Table 1.2.2 (Measurement System Capabilities)..................... Annex Table 1.3.1 (Test Specific Target Analytes)............................. Annex Table 4.1 (Measure System Capabilities)................................ Figure 6.1 (Location of Traverse Points per Method 1)....................... Annex Figure 1.4.1 (Sampling Train).................................................. Annex Figure 1.4.2 (Sampling Points)................................................. Annex Figure 1.4.3 (Sampling Port Locations).................................... Certified Calibration Bottle Certificates................................................ Tri Probe Certification via GD-031...................................................... GAS ALT 141_FTIR EPA.................................................................... Tester Qualifications (resume)............................................................ Raw Data............................................................................................ 27 Key Personnel.............................................................................1.0 3 Sampling System........................................................................2.0 3 Methods Used.............................................................................3.0 3 Test Summaries..........................................................................4.0 5 Run Summaries..........................................................................5.0 6 6 Volumetric Flow Rate Data.........................................................6.0 7 7 7 7 Calculations................................................................................7.0 8 9 12 12 13 15 13 14 14 20 25 28 29 Oxygen Calibration.....................................................................9 Engine Parameter Data Sheet....................................................10 QA/QC Results............................................................................11 Signature Page...........................................................................12.0 Appendices.................................................................................13.0 Bottle Certs.................................................................................2014.0 Tri Probe Certification via GD-031..............................................2515.0 GAS ALT 141_FTIR EPA............................................................16.0 Tester Qualifications (resume)....................................................2817.0 D6348 Annexes..........................................................................1211.0 18 19 26 8.0 9.0 10.0 Raw Data....................................................................................2918.0 1.0 Key Personnel GAS, Inc. Scout Energy Management, LLC 2.0 Sampling System The sampling system used consisted of a Stainless steel probe, heated Teflon line, gas conditioning system, and a Gasmet model DX4000 FTIR analyzer. The gas conditioning system used was a Gasmet Personal Sampling System with a Zirconium Oxide oxygen sensor. 3.0 Methods Used This extractive FTIR based field test method is used to quantify gas phase concentrations of multiple target analytes (CO, NOX, CH2O, & VOC's) from stationary source effluent. Because an FTIR analyzer is potentially capable of analyzing hundreds of compounds, this test method is not analyte or source specific. The analytes, detection levels, and data quality objectives are expected to change for any particular testing situation. It is the responsibility of the tester to define the target analytes, the associated detection limits for those analytes in the particular source effluent, and the required data quality objectives for each specific test program. Provisions are included in this test method that require the tester to determine critical sampling system and instrument operational parameters, and for the conduct of QA/QC procedures. Testers following this test method will generate data that will allow an independent observer to verify the valid collection, identification, and quantification of the subject target analytes. EPA Method 1 & 1A EPA Method 2 & 2C EPA Method 3A The purpose of the method is to provide guidance for the selection of sampling ports and traverse points at which sampling for air pollutants will be performed pursuant to regulations set forth in this part. This method is applicable for the determination of the average velocity and the volumetric flow rate of a gas stream. The average gas velocity in a stack is determined from the gas density and from measurement of the average velocity head with a standard pitot tube. Velocity readings are taken from each stack at 16 separate traverse points (Table 6.1) and used to determine the engines mass emissions rate, calculated utilizing the formulas seen in section 7.0 of this report. This is a procedure for measuring oxygen (O2) and carbon dioxide (CO2) in stationary source emissions using a continuous instrumental analyzer. Quality assurance and quality control requirements are included to assure that the tester collects data of known quality. Documentation to these specific requirements for equipment, supplies, sample collection and analysis, calculations, and data analysis will be included. ASTM D6348-03 Tyson Clegg 3 Danny Cupp Gas, Inc. 4.0 Test Summary t S u m m a r y Site Verification Photos Gas, Inc. The engine is a natural gas fired Lean Burn (4 Cycle) engine rated at 1311 brake horse power (BHP) at 1400 RPM. The engine was operating at 1241 BHP and 1344 RPM which is 94.69% of maximum engine load during the test. The test HP calculation can be found on page 8. The engine was running at the maximum load available at the test site. This test will satisfy the testing requirements for 40 CFR Part 60 Subpart JJJJ. Unit Unit #5 is authorized to operate under permit #DAQE-ANl 1679008-13. 4 Unit Unit #3 with a serial number of JEF01561 which is a Caterpillar 3516TALE engine located at Ashley Compressor Station and operated by Scout Energy Management, LLC was tested for emissions of: T Carbon Monoxide, Oxides of Nitrogen, and Volatile Organic Compounds. The test was conducted on 7/31/2024 by Danny Cupp with Great Plains Analytical Services, Inc. All quality assurance and quality e control tests were within acceptable tolerances. s 4.0 Test Summary Engine/Compressor Specs Ashley Compressor StationLocation Unit ID Make Caterpillar Site Elevation ft.6168.58 Model 3516TALE Atmospheric Pressure psi.11.86 Serial Number JEF01561 Stack Diameter in.13 mfg. rated hp 1311 Yes 1400 Date of Manufacture 3/1/2012 Engine/Compressor Operation Run 2 Run 3 3 Run AveragesRun 1 Test Horsepower 1232 1288 1204 1241 1348 1345 1339 1344 Percent Load % Intake Manifold Pressure (hg) 93.97%98.25%91.84%94.69% 54.04 53.22 52.00 53.09 Intake Manifold Temperature (F)148.10 147.60 147.00 147.57 Ambient Conditions Ambient Temperature Dry (F)89.00 92.00 93.00 91.33 Exhaust Flow Data Q Stack (dscfh) Q Stack (dscm/hr) 80349.42 79084.93 84675.26 81369.87 2275.22 2239.42 2397.71 2304.12 Moisture Fraction Bws Fuel Consumption (Btu/h[-hr) 0.07 0.07 0.07 0.07 0 0 0 0 Fuel Flow (dscfh) Fuel (btu/scf)1020 1020 1020 1020 O2 F factor 8710.0 8710 8710 8710 Results Method 3A Corrected O2% Dry Moisture %7.09%7.17%6.99%7.08% T e s t S u m m a r y mfg. rated rpm Test RPM 8.83%8.87%8.82%8.84% Permitted Standards Results 5 Catalyst 0.0120.010 Run 1 Run 2 Run 3 3 Run Average Pass Permits 02:21 PM 03:41 PM 04:50 PM 7/31/2024 CO (g/hp-hr)0.010 0.0112.000 Pass StateFederal CO (ppmvw)4.493 4.786 4.771 4.683 CO (ppmvd)4.835 5.155 5.129 5.040 CO (mol wt) 28.01 CO (ppmvd) @15% O2 2.364 2.529 2.506 2.466 Fail CO (ppbvd) @15% O2 2363.878 2529.288 2505.633 2466.267 Fail 0.0320.030CO (lbs/hr)0.028 0.0300.850 Pass NOx (g/hp-hr)0.299 0.286 0.319 0.3011.000 Pass NOx (ppmvw)78.593 79.855 77.991 78.813 NOx (ppmvd)84.588 86.026 83.848 84.821 NOx (mol wt) 46.01 33.449 33.329 33.005 33.261NMNEHC (ppmvw) 36.001 35.904 35.484 35.796NMNEHC (ppmvd) NOx (ppbvd) @15% O2 41354.061 42205.889 40959.308 41506.420 Fail NOx (ppmvd) @15% O2 41.354 42.206 40.959 41.506 Fail NMNEHC (mol wt) 44.10 17600.305 17615.429 17333.564 17516.433 FailNMNEHC (ppbvd) @15% O2 0.122 0.114 0.130 0.1220.700 PassNMNEHC (g/hp-hr) 0.331 0.325 0.344 0.3332.130 PassNMNEHC (lbs/hr) 17.600 17.615 17.334 17.516 FailNMNEHC (ppmvd) @15% O2 NOx (lbs/hr)0.811 0.812 0.847 0.8243.040 Pass Gas, Inc. Unit #3 5.0 Run Summaries Summary Source Run 1 R u n Table 5.1 Run Summaries S u m m a r i e s 6 0.00Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture % 4.49 0.00 78.49 0.00 0.11 0.00 78.59 0.64 33.45 0.19% 8.06% 0.00% 7.09% NMNEHC 4.19 77.77 0.21 77.98 32.90 7.99%7.01% 42.87 92.54 0.00 92.53 55.54 7.51%5.64% 4.80 79.20 0.00 79.20 34.00 8.12%7.17% 0.00 0.00 0.00 0.00 0.22 0.17%0-.0% Avg. Wet NO2NO Summary Source Run 2 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 0.00 0.00 0.00 0.00 0.22 0.17%0-.0% 4.67 78.92 0.04 78.95 33.25 8.10%7.10% 41.57 93.72 0.00 93.72 52.69 7.48%6.08% 4.90 80.76 0.00 80.76 33.41 8.08%7.25% 0.00 0.00 0.96 0.96 0.09 0.16%0.19% Avg. Wet 4.79 79.84 0.02 79.86 33.33 8.09%7.17% NO2NO Summary Source Run 3 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 4.21 79.36 0.34 79.69 32.81 8.12%7.03% 41.32 91.36 0.00 91.36 53.16 7.57%5.87% 5.33 76.28 0.01 76.29 33.20 8.00%6.94% 0.00 0.00 0.97 0.97 0.14 0.12%0.00% 0.00 0.00 0.96 0.96 0.09 0.16%0.19% Avg. Wet 4.77 77.82 0.18 77.99 33.01 8.06%6.99% NO2NO Gas, Inc. 6.0 Volumetric Flow Rate Data Volumetric Flow Rate Data .99 Stack diameter = Table 6.1. Data used for volumetric flow rate (Method 2) 13 inches or:1.08 feet. or:.92 Square Feet Run 1 Average Pitot Tube Coefficient Cp(std)= H2O CO2 O2 CO Molecular Weight Stack Gas dry basis (Md) Molecular Weight Stack Gas wet basis (Ms) Stack Static Pressure (Pg) Stack Static Pressure (Pg) Atmospheric Pressure at Location (Pbar) Atmospheric Pressure at Location (Pbar) Absolute Stack Pressure (Ps) Stack Temperature Stack Temperature Stack Temperature Stack Gas Velocity Stack Flow Rate Q Stack Gas Wet Volmetric Flow Rate Stack Gas Dry Volumetric Flow Rate Sample after Back Purge: Within 5% of Last Δpstd reading: Stack Diameter (inches) Inches upstream from disturbance Inches downstream from disturbance scf/hr 0.58 Yes 13.00 300.00 31.00 scf/hr cfs ft/sec Deg R Deg F Deg C "Hg "Hg MBAR "Hg "H20 g/g mole g/g mole ppmd %d %d %d 7.09 29.19 0.42 Inches 2.17 6.5 10.83 Vo l u m e t r i c F l o w Ra tes Pitot readings are taken for Method 2 calculations using measuring points outlined in Method 1 Figure 6.1 16 Traverse Points Were Used Emissions Sampling Points - 3 point long line sampling probe First Sampling Point Taken @ 16.7% of Stack Diameter Second Sampling Point Taken @ 50% of Stack Diameter Third Sampling Point Taken @ 83.3% of Stack Diameter 5.43 8.06 4.49 817.00 0.03 24.13 24.16 710.50 1170.17 376.94 28.40 71.52 65.93 86479.05 80349.41 Run 2 7.17 29.19 0.41 5.43 8.10 4.79 816.85 0.03 24.13 24.16 715.50 1175.17 379.72 28.39 70.78 65.24 85196.04 79084.93 Run 3 6.99 29.18 0.47 5.39 8.06 4.77 816.00 0.03 24.10 24.14 722.50 1182.17 383.61 28.40 76.14 70.19 91034.48 84675.26 7.08 29.19 0.43 5.42 8.07 4.68 816.62 0.03 24.12 24.15 716.17 1175.84 380.09 28.40 72.84 67.14 87615.84 81410.74 *The exhaust stack did not present cyclonic flow conditions at the sampling location due to the absence of cyclones, inertial demisters, venturi scrubbers, or tangential inlets. * Cyclonic Flow Check (Pass/Fail): PASS Δpstd (in) H2O 0.32 Exhaust Temp F 710.00 Pitot Tube Sampling Points (Velocity) 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 Δpstd Average= Run 1 Table 6.2. Stack gas pressure readings measured with a standard pitot tube use for Volumetric Flow Rate 0.41 0.50 0.35 709.00 708.00 707.00 0.42 0.39 0.46 706.00 705.00 704.00 0.47 0.38 0.25 703.00 711.00 712.00 0.30 713.00 0.23 0.53 0.59 714.00 715.00 716.00 0.44 0.66 0.42 717.00 718.00 710.50 Δpstd = Velocity head measured by the standard pitot tube, (in.) H2O.Run 3 Δpstd (in) H2O 0.50 Exhaust Temp F 722.00 0.53 0.61 0.55 721.00 720.00 719.00 0.45 0.41 0.39 718.00 717.00 716.00 0.29 0.27 0.36 715.00 723.00 724.00 0.39 725.00 0.52 0.58 0.51 726.00 727.00 728.00 0.57 0.58 729.00 730.00 722.500.47 Run 2 Δpstd (in) H2O 0.23 Exhaust Temp F 715.00 0.34 0.45 0.50 714.00 713.00 712.00 0.31 0.30 0.26 711.00 710.00 709.00 0.21 0.38 0.46 708.00 716.00 717.00 0.42 718.00 0.49 0.50 0.51 719.00 720.00 721.00 0.59 0.58 722.00 723.00 0.41 715.50 7 Gas, Inc. 7.0 Calculations Method 2: Determination of Stack Gas Velocity and Volumetric Flow Rate *Note- Use of this method negates the need for any fuel related numbers for emissions calculations Nomenclature Δp(avg) = Velocity head of stack gas, mm H2O (in. H2O).Ps = Absolute stack pressure (Pbar+ Pg), mm Hg (in Hg) 3600 = Conversion Factor, sec/hr. A = Cross-sectional area of stack, m2 (ft2). Bws = Water vapor in the gas stream (from ASTM D6348) Kp = Velocity equation constant. Md = Molecular weight of stack gas, dry basis, g/g-mole (lb./lb.-mole). Ms = Molecular weight of stack gas, wet basis, g/g-mole (lb./lb. -mole). Pstd = Standard absolute pressure, 760 mm Hg (29.92 in. Hg). Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (dscf/hr.). Ts(abs) = Absolute stack temperature, °K (°R). = 460 + Ts for English units. Tstd = Standard absolute temperature, 293°K (528 °R). Vs = Average stack gas velocity, m/sec (ft./sec). *(Observed from Method 3 12.3) Dry Molecular Weight. Equation 3-1 Md = .44(.054)+.32(.088)+.28(.858+0) = 29.191 LB/LB-MOLEMd = .44(%CO2)+.32(%O2)+.28(%N2+%CO) 12.5 Molecular Weight of Stack Gas. Equation 2-6 Ms = 29.191(1 -.07088)+.18.0(.07088) = 28.398 LB/LB-MOLEMs = Md(1-Bws)+18.0(Bws) 12.6 Average Stack Gas Velocity. Equation 2-7 Vs = 85.49*.99*√.42*√(1170.17/(24.16*28.398)) = 71.52 FT/SECVs = Kp*Cp(std)*√Δpavg*√(Ts(abs)/(Ps*Ms)) 12.7 Average Stack Gas Volumetric Flow Rate. Equation 2-8 Qsd = 3600(1-.071)71.523*.922((528*24.16)/ (1170.17*29.92)) = 80349.42 DSCF/HRQsd = 3600(1-Bws)Vs*A((Tstd*Ps)/(Ts(abs)*Pstd)) *Standard conversion from feet to meters Q = 80349.415/35.315 = 2275.221 DSCM/HRQ = Qsd/35.315 Emission Rates (Examples use CO Run 1) Nomenclature CO corrected @ 15% O2 453.6= Conversion factor lb. to gram HP= Engines rated Horsepower A = Cross-sectional area of stack, m2 (ft2). BHP/HR. = Brake work of the engine, horsepower-hour (HP-HR.). BTU/HP-HR. = Brake Specific Fuel Consumption (HHV) ER = Emission rate of (CO) in g/HP-hr. F(d )= Volumes of combustion components per unit of heat content, scm/J (scf/million Btu). Q = Stack gas volumetric flow rate, in standard cubic meters per hour, dry basis LB/HR.= Emission rate of (CO) in LB/HR. Mfg.= Manufacturer Exhaust flow rate at 100% (ft3/min) O2 = Concentration of oxygen on a dry basis, percent. ppm= Parts Per Million (CO) ppm@15% O2= PPM corrected to 15% O2 Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (DSCF/HR.). Run Time = Run Time in Minutes TPY= Tons per Year Mol wt.= Mol Weight of CO (28.01) Vs = Average stack gas velocity, m/sec (ft./sec). ppm @ 15% O2 = 4.835*(20.9-15)/(20.9-8.8%)) = 2.358 PPM @ 15% O2ppm @ 15% O2 = PPM*((20.9-15%O2)/(20.9-O2)) G/HP HR from 40 CFR Part 60 Subpart JJJJ (4.835*(1.164*10^-3)*2275.221*(Run Time/60))/1232 = .01 G/HP-HRg/hp-hr = (PPM*(1.164*10^-3)*Q*(Run Time/60))/BHP/HR LB/HR from Grams LB/HR = .01*1/453.6*1232 = .028 LB/HRlb/hr = ER*1/453.6*BHP-HR TPY TPY = .028*4.38 = .123 TPYTPY = LB/HR. *4.38 Horsepower HP Provided On Site Wet to Dry PPM 4.84 = 4.4925*(1/(1-.07))ppm wet * (1/(1-H2O) = ppm dry 8 Cp(std) = Standard pitot tube coefficient; use 0.99 Gas, Inc. 8.1 Calibration error test; how do I confirm my analyzer calibration is correct? After the tester has assembled, prepared and calibrated the sampling system and analyzer, they conduct a 3-point analyzer calibration error test before the first run and again after any failed system bias test or failed drift test. They then introduce the low-, mid-, and high-level calibration gases sequentially in direct calibration mode. At each calibration gas level (low, mid, and high) the calibration error must be within ± 2.0 percent of the calibration span. 8.0 Oxygen Calibration 8.2 Initial system bias and system calibration error checks. Before sampling begins, it is determined whether the high- level or mid-level calibration gas best approximates the emissions and it is used as the upscale gas. The upscale gas is introduced at the probe upstream of all sample- conditioning components in system calibration mode. 8.3 Post-run system bias check and drift assessment - confirming that each sample collected is valid. Sampling may be performed for multiple runs before performing the post-run bias or system calibration error check provided this test is passed at the conclusion of the group of runs. A failed final test in this case will invalidate all runs subsequent to the last passed test. (1) Next, zero gas is introduced as described above. The response must be within 0.5 percent of the upscale gas concentration. (2) Low-level gas reading is observed until it has reached a final, stable value and the results are recorded. The measurement system will be operated at the normal sampling rate during all system bias checks. (3) If the initial system bias specification is not met, corrective action is taken. The applicable calibration error test from Section 8.2.3 of EPA Method 7E is repeated along with the initial system bias check until acceptable results are achieved, after which sampling will begin. The pre- and post-run system bias must be within ± 5.0 percent of the calibration span for the low-level and upscale calibration gases. (1) If the post-run system bias check is not passed, then the run is invalid. The problem is then diagnosed and fixed, then another calibration error test and system bias is passed before repeating the run. (2) After each run, the low-level and upscale drift is calculated, using Equation 7E–4 in Section 12.5 from EPA Method 7E. If the post-run low- and upscale bias checks are passed, but the low-or upscale drift exceeds the specification in Section 13.3, the run data are valid, but a 3-point calibration error test and a system bias check must be performed and passed prior to additional testing. Table 8.1 Oxygen Calibration EPA Method 3A QA Worksheet (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Certified Gas Concentraion Low-Level (%) 0.00% Certified Gas Concentraion Mid-Level (%) Certified Gas Concentraion High-Level (%) (DIRECT) Analyzer Calibration Error (≤ 2%) Certified Concentration Value (%) Direct Calibration Response (%) Absolute Difference (%) Analyzer Calibration Error (%)Analyzer Direct Calibration Response Certified bottle value % 0.00% 0.00% 0.00% Zero Gas % Mid-Level Gas % High-Level Gas % Bias Pre Initial Value Bias Post Inital Values System Calibrations Response Pre (%) 0.00% System Bias (% of Span) Pre System Calibration Response Post (%) System Bias (% of Span) Post Drift (% of Span) 0.00%0.00%0.00%0.00% (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Avg. Gas Concentration (Run 1) Avg. Gas Concentration (Run 2) Avg. Gas Concentration (Run 3) Effluent Gas (Cgas) Run 1 Effluent Gas (Cgas) Run 2 Effluent Gas (Cgas) Run 3 Linearity Check 0.00%0.00%0.00% Method 7E 3.4 To the extent practicable, the measured emissions should be between 20 to 100 percent of the selected calibration span. This may not be practicable in some cases of low concentration measurements or testing for compliance with an emission limit when emissions are substantially less than the limit. 7E 8.5: Note: that you may risk sampling for multiple runs before performing the post-run bias provided you pass this test at the conclusion of the group of runs Upscale Gas Analyzer Calibration Response (%) Zero Gas Upscale Gas EPA Method 3A QA Worksheet Zero Gas Mid-Level Gas High-Level Gas 100% Nitrogen O2 QA/QC Zero Gas %0.00% Mid-Level Gas % High-Level Gas % System Calibration Response Pre (%) System Calibration Response Post (%) Zero Gas % Upscale Cal Zero Gas % Upscale Cal Upscale Used Upscale Used 10.65% 21.17% 10.61% 10.26% 10.62% 10.62% 10.26%10.61% 10.65% 21.17% 10.62% 20.98% 10.62% 20.98% 10.62%20.98% 0.00% 10.62% 20.98% 0.03% 0.19% 0.14% 0.92% 10.62% Span Zero Offset 0.00% 20.98 0.00% 10.65%0.19%1.84%0.02% 8.68% 8.72% 8.67% 8.83% 8.87% 8.82% 9 Gas, Inc. 884.0 882.0 882.7 17.8 17.2 17.3 9.0 Engine Parameter Data Sheet Company Site Elevation (ft) Facility Unit ID Date Make Scout Energy Management, LLC Ashley Compressor Station 7/31/2024 6168.58 Caterpillar Model Serial Number 3516TALE JEF01561 Technician Danny Cupp Run Start Times 02:21 PM 03:41 PM 04:50 PM 06:31 PM Run 1 Run 2 Run 3 Completed Engine Parameter Data Run 1 Engine Speed (RPM)1347.5 1345.1 1339.0 1343.9 Engine Hours 39739.3 39740.3 39741.3 39742.3 Intake Manifold Pressure (psi)38.4 38.0 37.4 37.9 Intake Manifold Temp °F 148.1 147.6 147.0 147.6 Engine Load (BHP)1232.0 1288.0 1204.0 1241.3 Ambient Temp °F 89.0 92.0 93.0 91.3 Humidity %11.0 10.0 9.0 10.0 Dew Point °F 27.0 27.0 25.0 26.3 Caterpillar 0.0 0.0 Yes N/A N/A N/A N/A 2 2 2 2# of Catalyst Installed Catalyst Manufacturer Catalyst (Yes or No) AFR Setting (Target Left Bank) AFR Setting (Target Right Bank) AFR Manufacturer/Type 0.0 0.0 0.0 0.0 0.0 0.0 Caterpillar Caterpillar Caterpillar 10 Run 3 AverageRun 2 17.0 882.0Discharge Pressure (psi) Suction Pressure (psi) Catalyst Pressure Drop H2O Catalyst Outlet Temp °F Catalyst Inlet Temp °F Gas, Inc. Unit #3 10.0 QA/QC Results Average:Carbon monoxide CO Gas, Inc. 0.00 R e s u l t s Average:Nitrogen monoxide NO 0.00 Average:Nitrogen dioxide NO2 0.00 Average:NOx 0.00 Average:VOC 0.37 Average:Oxygen 0.16 Pre-test Baseline Results Time: Q A / Q C Value:CTS Bottle Concentration 100.00 Value:CTS Compound Concentration Avg 99.69 Tolerance 2.00% Difference between measured and expected 0.31% CTS Direct to Analyzer Time: Average:Carbon monoxide CO 0.00 Average:Nitrogen monoxide NO 0.00 Average:Nitrogen dioxide NO2 0.26 Average:NOx 0.26 Average:VOC 0.52 Average:Oxygen 0.11 Pre-test System Zero Time: Mechanical Response Time 45 seconds Value:CTS Bottle Concentration 100.00 Value:CTS Compound Concentration Avg 99.51 Tolerance 5.00% Difference between measured and expected 0.49% Pre-test System CTS & Mechanical Response Time 7 secondsEquilibration Response Time Value:Spike Reported 253.90 Value:Spike Expected 257.20 System (Equilibration) Response Time Target (Spike) 45 secondsSystem Zero Response Time 45 secondsSystem Response Time System (Zero) Response Time 11 11.0 D6348 Annexes 1-8 D6348 Annexes 1. Test Plan Requirements Annex 1.2 The test quality objectives completed for the emissions test are demonstrated throughout Annexes 1, 2, 3, 4, 5, 6, 7 & 8 as layed out per ASTM D6348-03. All reference methods, pre-test and post test procedures were within acceptable limits. Data generated during the pre-test and post-test procedures are summarized below in order of the distinctive Annex. Three 60 minute test runs were performed. The final analyte concentrations are the average of each test run. Data was taken at 60 second intervals. Each 60 second measurement was the average of 600 scans. Propane is used as the surrogate compound for the Annex 5 Spiking Technique due to Propane being the VOC that is most commonly found in the combustion process of natural gas. Additionally, the molecular weight of Propane coincides with with molecular weight of VOC's per the EPA. Annex Table 1.2.1 Certified Calibration Bottle Concentrations Bottle Expiration NO2 Ethylene SF6 O2 (%) CC507057 4/29/2027 99.08 10.62% CC262147 11/29/2031 100.00 CC421882 10/10/2030 20.98% Cylinder # CC42028 Expiration: 12-11-2031 Propane CO NO SF6 Bottle Value 257.20 501.00 246.20 10.07 Analyzer System Response 253.90 494.10 247.81 10.05 Percent Difference 1.28%1.38%0.65%0.22% Annex Table 1.2.2 Measurement System Capabilities SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 99.691 4.985 Spike Direct Propane 254.616 Mechanical Response Time SF6 10.073 CO 492.636 NO 249.253 Ethylene 99.508 4 seconds Analyzer Response Propane 253.899 SF6 10.048 CO 494.102 NO 247.805 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 255.593 CO 482.308 NO 238.729 7 seconds 14 seconds 7.89% 7.62% 7.59% 102.80% 99.72% 102.18% 10.038 12 Gas, Inc. Annex 1.3 Compounds Infrared Analysis Region (cm-1) Expected Concentration Range Measurement System Achievable Minimum Detectable Concentrations Required Measurement System Accuracy and Precision for Test Application CO 2000-2200 0-1200 ppm NO 1875-2138 NO2 2700-2950 VOC 2600-3200 910-1150 2550-2950 CH2O 2550-2850 Interfering Compounds * CO is analyzed in a separate analysis region than CO2 and H2O CO2 Water Vapor 926-1150 3200-3401 Annex Table 1.3.1 Test Specific Target Analytes and Data Quality Objectives 0.16267 ppm 4 ppm 0-1000 ppm 0.4007 ppm 2 ppm 0-100 ppm 0.4899 ppm 2 ppm 0-100 ppm 1.8520 ppm Total VOC's 1 ppm per VOC 0-100 ppm 0.7878 ppm 1 ppm 0-10% 0-22% 0% 0.20% n/a n/a * VOCs compiled of Acetaldehyde, Ethylene, Hexane, and Propane. Annex 1.4 Figure Annex 1.4.1 Sampling Train The testing instrumentation is housed in an enclosed vehicle which is located approximately 45 feet from the source. A heated sample line (sixty feet in length) is attached to the inlet of analyzer system and the source effluent discharges through the FTIR outlet. 13 Gas, Inc. Sampling Point Locations in Inches 16.7%2.171 50%6.500 83.3%10.829 Figure Annex 1.4.3 Sample Port Location Figure Annex 1.4.2 Sampling Points Interior Stack Diameter (inches): Inches Upstream: Inches Downstream: 13 300 31 14 Stack Gas Dry Volumetric Flow Rate (scf/hr): 81410.74 H2O%d @ Sampling Point:7.08 CO2%d @ Sampling Point:5.42 Pressure @ Sampling Point (Pg "H2O):0.43 Temperature @ Sampling Point (Deg F):716.17 Gas, Inc. D6348 Annex 2. Determination of FTIR Measurement System Minimum Detectable Concentrations (MDC#1) Target Analyte Results (ppm) CO 0.1627 NO 0.4007 NO2 0.4899 Ethylene 0.3782 Propane 0.4351 Hexane 0.2233 Acetaldehyde 0.8152 Formaldehyde 0.7878 D6348 Annex 3. FTIR Reference Spectra Calibration Transfer Standard Expected Measured Path Length Validated Ethylene 100 99.69 4.985 Passed D6348 Annex 4. Required Pre-Test Procedures Annex Table 1.2.2 Measurement System Capabilities 15 SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 99.691 4.985 Spike Direct Propane 254.616 Mechanical Response Time SF6 10.073 CO 492.636 NO 249.253 Ethylene 99.508 4 seconds Analyzer Response Propane 253.899 SF6 10.048 CO 494.102 NO 247.805 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 255.593 CO 482.308 NO 238.729 7 seconds 14 seconds 7.89% 7.62% 7.59% 102.80% 99.72% 102.18% 10.038 Gas, Inc. D6348 Annex 5. Analyte Spiking Technique Propane Spike Direct SF6 CO NO 257.200 10.070 501.000 246.200 254.616 10.073 492.636 249.253 1.00% 0.03% 1.67% 1.24% +/- 2% +/- 2% +/- 2% +/- 2% Pass Pass Pass Pass Parameter Gas Concentration Measured % Difference Specification Validated 22.691 0.005 Spike Average 42.348 0.795 Dilution Factor 7.892% Expected 41.194 % Recovery 102.800% Specification 70-130% <10% Spike Run 1 via the System Source Output Propane SF6 D6348 Annex 6. Determination of System Performance Parameters Noise Equivalent Absorbance (NEA) RMS High RMS Mid RMS Low Line Position: Demonstrating the peak positions align correctly (Manual Comparison +/- 20%) 0.000 Spike Average 0.768 Dilution Factor 7.624% Expected % Recovery Specification 70-130% <10% Spike Run 2 via the System Source Output Propane SF6 0.000 Spike Average 0.765 Dilution Factor 7.595% Expected % Recovery Specification 70-130% <10% Spike Run 3 via the System Source Output Propane SF6 22.027 40.747 39.877 102.180% 0.003863 0.014019 0.018149 22.387 40.167 40.280 99.720% Line Position Difference:Resolution Difference to Reference1.55%Pass Pass4.24% 16 Gas, Inc. Resolution The Gasmet GICCOR (Genzel Interferometer with Cube Corner Retroreflectors) interferometer is specially designed for maximum optical throughput and maximum signal to noise ratio of 7.72 (cm-1) remaining stable with any vibration and temperature changes. D6348 Annex 7. Preparation of Analytical Quantification Algorithm The analytical accuracy of the quantification algorithm is satisfied via the results from Annex 5 per Annex 7.6 Regression Slope:-9.25935765 Pass Line Position Difference:Resolution Difference to Reference 4.24% D6348 Annex 8. Post Test Quality Assurance/Quality Control Procedures CTS Bottle Concentration: CTS Sample Concentration Average: Difference between measured and expected: Tolerance: 100.00 100.95 0.94% 5.00% POST CTS System Check: Run 1 Points 1 & 2 on CO/NO/Propane Run 2 Points 1 & 2 on CO/NO/Propane Run 3 Points 1 & 2 on CO/NO/Propane Run Data Validation - Automated vs Manual Reading Validated Comments All within 20% All within 20% All within 20% Passed Passed Passed Demonstrates no interferences observed. Demonstrates no interferences observed. Demonstrates no interferences observed. 17 Gas, Inc. Detector Linearity The Gasmet DX4000 is a low resolution spectrometer where the aperture is fixed to a maximum angle setting and the detector linearity was tested with an alternate approach. A three point linearity of the CTS gas was performed and validated. We certify that based on review of test data, knowledge of those individuals directly responsible for conducting this test, we believe the submitted information to be accurate and complete. 18 Company: Print Name: Signature: Title: Phone Number: Date: Company:G.A.S. Inc.Date: Print Name: Title: 7/31/2024 Emissions Specialist Company:G.A.S. Inc.Date: Print Name: Title: Signature: Phone Number: Travis Hartley Director of Stack Testing 580-225-0403 7/31/2024 Danny Cupp Gas, Inc. 12.0 Signature Page Job/File Name: Scout Energy Management, LLC; Ashley Compressor Station; Unit #3; JJJJ Appendices Gas, Inc. Gas, Inc. Spike (5 Gas) Gas, Inc. 9% O2/NO2 Gas, Inc. Ethylene Only Gas, Inc. BIP Gas, Inc. CERTIcICATE Oc ANALYSIS Grade of Product: EPA PROTOCOL STANaARa Part Number:E02NI79E15A00B1 Reference Number:54-402564012-1 Cylinder Number:CC421882 Cylinder Volume:146.0 CF Laboratory:124 - Chicago (SAP) - IL Cylinder Pressure:2015 PSIG PGVP Number:B12022 Valve Outlet:590 Gas Code:O2,BALN Certification Date:Oct 10, 2022 Expiration Date:Oct 10, 2030 Certification performed in accordance with “EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)” document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. The results relate only to the items tested. The report shall not be reproduced except in full without approval of the laboratory. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. ANALYTICAL RESULTS Component Requested Actual Protocol Total Relative AssayConcentrationConcentrationMethodUncertaintyDates OXYGEN 21.00 %20.98 %G1 +/- 0.4% NIST Traceable 10/10/2022 NITROGEN Balance CALIBRATION STANaARaS Type Lot ID Cylinder No Concentration Uncertainty Expiration Date NTRM 150104-18 K026588 22.454 % OXYGEN/NITROGEN +/- 0.2%Mar 08, 2027 ANALYTICAL EnUIPMENT Instrument/Make/Model Analytical Principle Last Multipoint Calibration O2-1 HORIBA MPA-510 3VUYL9NR Paramagnetic Sep 14, 2022 Triad Data Available Upon Request Airgas Specialty Gases Airgas USA LLC12722 S. Wentworth Ave. Chicago, IL 60628 Airgas.com Signature on file Approved for Release Page 1 of 1 ㈱┠伲 Tri Probe Certification ” ‡ ƒ – Ž ƒ ‹ • • • ƒ Ž › – ‹ … ƒ Ž ‡ ” ˜ ‹ … ‡ • ͵Ͳ͵͵ǡǡ͵ͶͶ ȋͷͺͲȌʹʹͷǦͲͶͲ͵ ǣȋͷͺͲȌʹʹͷǦʹͳʹ &(57,),&$7(2)$1$/<6,6 *UDGHRI3URGXFW&(57,),('67$1'$5'352%( 3DUW1XPEHU65HIHUHQFH 1XPEHU /DERUDWRU\*$6,1&6WDFN'LDPHWHU $QDO\VLV'DWH7DUJHW)ORZ 5DWH /PLQ /271XPEHU 61 $ $6 1XPEHURI 3RLQWV 3URGXFWSHUIRUPDQFHYHULILHGE\GLUHFWFRPSDULVRQWRFDOLEUDWLRQVWDQGDUGVWUDFHDEOHWR1,67 7KHSUREHOLVWHGRQWKLVIRUPPHHWVWKHPXOWLSRLQWWUDYHUVHUHTXLUHPHQWRI(3$0HWKRGH VHFWLRQDVVKRZQLQWKHDFFRPSDQ\LQJGDWD0HWKRGHVHFWLRQVWDWHVWKDWWKHPXOWLSRLQW WUDYHUVHUHTXLUHPHQWFDQEHVDWLVILHGE\VDPSOLQJYLD³DPXOWLKROHSUREHGHVLJQHGWRVDPSOHDW WKHSUHVFULEHGSRLQWVZLWKDIORZSHUFHQWRIPHDQIORZUDWH´ $1$/<7,&$/5(68/76 ZƵŶηdŽƚĂů&ůŽǁ ;>ͬŵͿ DĞĂƐƵƌĞĚ&ůŽǁ WŽƌƚ;>ͬŵͿ ;ĞůƚĂƋϭͿ DĞĂƐƵƌĞĚ&ůŽǁ WŽƌƚ;>ͬŵͿ ;ĞůƚĂƋϮͿ DĞĂƐƵƌĞĚ&ůŽǁ WŽƌƚ;>ͬŵͿ ;ĞůƚĂƋϯͿ 0HDQ3UREH 3RUW6DPSOHG )ORZ/P 5XQ/30 䧮 䧮 䧮 5XQ/30 䧮 䧮 䧮 &DOLEUDWLRQFRQGXFWHGLQDFFRUGDQFHZLWK(PLVVLRQ0HDVXUHPHQW&HQWHU*XLGHOLQH'RFXPHQW±(0&*' 1RWHV BBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBBB $SSURYHGIRU5HOHDVH'DWH 2/17/2022 Probe size: 13S Mr. Jordan Williamson CEO GAS Inc. 303 W. 3rd Street Elk City, OK 73644 Dear Mr. Williamson: We are writing in response to your letter received on September 17, 2020, in which you request the approval of alternative testing procedures. The EPA’s Office of Air Quality Planning and Standards (OAQPS) is the delegated authority for consideration of major alternatives to test methods and procedures as set forth in 40 CFR parts 60 and 63 under which your request must be addressed. GAS Inc. is requesting a change to one of the test methods, ASTM D6348-03, used for conducting performance tests to determine compliance under 40 CFR part 60, Subpart JJJJ – Standards of Performance for Stationary Spark Ignition Internal Combustion Engines (Subpart JJJJ) and 40 CFR part 63, Subpart ZZZZ – National Emissions Standards for Hazardous Air Pollutants for Performance for Stationary Reciprocating Internal Combustion Engines (Subpart ZZZZ). The change being requested will be used to check detector linearity of the Fourier Transform Infrared (FTIR) instrumentation used to conduct this method. Specifically, you are requesting that the procedures of section 8.3.3 of Method 320 (40 CFR part 60, Appendix A), another FTIR-based method allowed under Subparts JJJJ and ZZZZ, be used in lieu of section A6.4.1 of ASTM D6348-03 when conducting testing using ASTM D6348-03 under 40 CFR part 60, Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. In your request, you state that this alternative linearity check procedure will produce consistent results when utilizing either Method 320 or ASTM D6348-03. Additionally, some FTIR instrumentation does not allow for reducing the size of the aperture in the instrument and, thus, it would not be feasible to properly conduct the entirety of the ASTM D6348-03 method in its current form using such an instrument. Based on our understanding of FTIR instrument principles and recognition that the requested alternative determination of detector linearity is both technically sound and contained within Method 320, we are approving the requested change. We believe that this alternative is acceptable for use for use in testing all engines subject to 40 CFR part 60 Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. Also, we will post this letter as ALT-141 on EPA’s website (at www.epa.gov/emc/broadly-applicable-approved-alternative- testmethods) to announce that our approval of this alternative test method is broadly applicable to engines for the purposes of meeting Subparts JJJJ and ZZZZ. March 15, 2021 Sincerely, Steffan M. Johnson, Group Leader Measurement Technology Group If you should have any questions or require further information regarding this approval, please contact David Nash of my staff at 919-541-9425 or email at nash.dave@epa.gov. cc: Sara Ayers, EPA/OECA/OC/MAMPD, (ayres.sara@epa.gov) Melanie King, EPA/OAR/OAQPS/SPPD, (king.melanie@epa.gov) James Leather, EPA Region 6, (leather.james@epa.gov) David Nash, EPA/OAR/OAQPS/AQAD, (nash.dave@epa.gov) Heather Sessing, Oklahoma DEQ, (Heather.sessing@deq.ok.gov) Danny Cupp GAS, Inc. Type of Sources Tested: info@gasinc.us Stationary Internal Combustion Engines • 4 Stroke Rich Burn Engines • 2 Stroke & 4 Stroke Lean Burn Engines Stationary Natural Gas Fired Generators Stationary Propane Fired Generators Gas Fired Boilers Qualifications: Trained, studied, and fully demonstrates compliance for emissions testing via data collection outlined in the following Reference Methods: • EPA Method 1 & 1A – Sampling & Traverse Points • EPA Method 2 & 2C – Velocity & Volumetric Flow Rate of a Gas Stream • EPA Method 3A – Oxygen • EPA Method 7E – NOX • EPA Method 10 – Carbon Monoxide • EPA Method 25A – Volatile Organic Compounds • ASTM D6348 – Extractive Fourier Transform Infrared Spectroscopy Conducts emissions testing on a weekly basis including, but not limited to, the following test types: Initial Compliance, Biennial Compliance, Semiannual Compliance & Quarterly Compliance. All tests performed are in accordance to any and all Federal & State requirements as applicable (i.e. JJJJ, ZZZZ, 106.512, 117, PEA, etc.). Performed testing in Colorado, Utah, Wyoming, North Dakota, Montana, Kansas, New Mexico, Oklahoma, Texas, Louisiana (land and off-shore), Arkansas, Ohio, Pennsylvania, West Virginia, New York, Kentucky, & Mississippi. • Quarterly Performance Reviews covering ongoing changes with Federal Regulations, State Compliance guidelines, & site-specific safety certifications. Types of Analyzers: • Gasmet DX4000 FTIR • Gasmet Portable Sampling Unit with Zirconium Oxide O2 Sensory • Testo 350 • Flame Ionization Detector 580-225-0403 Gas, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 1 Minute Average Data Sheet Scout Energy Management, LLCClient: Ashley Compressor Station Unit Number: Make:Caterpillar Location:3516TALEModel: JEF01561Serial Number: RAW Result Data Stability 7/31/2024 05:41 0.0000.0003.310 0.014 1.3211.095 0.000 0.000 0.0000.0002.457 0.968 0.0160.000 0.000 850.01.130.703 0.013 0.00 0.14 179.0 Pre Test Baseline Direct 7/31/2024 05:49 0.0000.000-1.282 0.000 0.0000.000 0.111 0.000 0.0000.0000.377 0.000 0.2690.000 0.000 850.00.530.393 0.000 0.00 0.15 179.0 7/31/2024 05:50 0.0000.000-1.289 0.000 0.0000.000 0.103 0.000 0.0000.1870.000 0.000 0.0000.000 0.000 850.00.450.676 0.000 0.00 0.18 179.0 7/31/2024 05:50 0.0000.000-1.350 0.001 0.0000.000 0.119 0.072 0.0000.4590.000 0.000 0.0000.000 0.009 850.00.130.166 0.000 0.00 0.16 180.0 CTS Direct 7/31/2024 05:57 0.0000.000-1.542 0.029 0.3660.000 0.000 0.000 0.7170.3120.000 99.727 0.0000.115 0.000 851.066.680.283 0.000 0.00 0.26 180.0 7/31/2024 05:57 0.4210.000-1.557 0.024 0.0000.000 0.000 0.000 0.3460.4620.000 99.244 0.0000.555 0.000 851.066.170.000 0.000 0.42 0.25 180.0 7/31/2024 05:57 0.0000.000-1.560 0.017 0.0000.000 0.000 0.000 0.0000.0000.000 100.103 0.0000.000 0.000 851.066.840.151 0.000 0.00 0.29 180.0 High O2 Direct 7/31/2024 06:00 0.0000.000-1.595 0.013 1.2770.000 0.000 0.106 0.0000.1470.000 0.000 0.2920.000 0.000 851.00.500.305 0.000 0.00 21.12 180.0 7/31/2024 06:01 0.0000.000-1.556 0.022 0.3510.000 0.000 0.365 0.5320.2280.000 0.000 0.0000.000 0.000 851.00.360.537 0.000 0.00 21.20 180.0 7/31/2024 06:01 0.0800.000-1.570 0.000 0.4570.000 0.000 0.210 0.2410.2260.000 0.000 0.0000.000 0.000 851.00.180.277 0.000 0.08 21.20 180.0 NO2/Mid O2 Direct 7/31/2024 06:08 99.1010.000-1.575 0.000 1.5770.000 0.797 0.000 1.3750.1260.000 0.000 0.0000.000 0.000 851.00.390.583 0.000 99.10 10.66 180.0 7/31/2024 06:09 97.7420.000-1.581 0.000 0.0930.000 0.763 0.000 1.0460.5300.000 0.000 0.0310.000 0.000 851.00.030.000 0.000 97.74 10.64 180.0 7/31/2024 06:09 100.2100.000-1.590 0.000 1.5170.000 0.818 0.000 1.7850.0060.000 0.000 0.0000.087 0.000 851.00.000.003 0.000 100.21 10.65 180.0 Spike Direct 7/31/2024 06:16 0.000248.999-1.576 4.633 0.329494.461 0.711 1.345 2.0210.4900.000 1.893 255.3760.000 0.000 851.0259.814.755 10.086 249.00 0.18 180.0 7/31/2024 06:16 0.000249.280-1.574 4.556 2.761491.784 0.747 1.328 3.3530.7560.000 1.827 254.0230.000 0.000 851.0257.563.484 10.078 249.28 0.20 180.0 7/31/2024 06:17 0.000249.479-1.589 4.604 2.728491.662 0.803 1.639 3.7250.2030.277 1.932 254.4480.000 0.000 851.0258.994.874 10.055 249.48 0.22 180.0 GAS, Inc. Unit #3 Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline System 7/31/2024 06:20 0.0000.000-0.031 0.002 0.0000.000 0.002 0.126 0.0000.0000.000 0.000 0.3950.065 0.000 851.01.010.925 0.000 0.00 0.13 180.0 7/31/2024 06:20 0.0000.000-0.031 0.025 0.0000.000 0.000 0.024 0.9430.0090.000 0.000 0.0000.000 0.000 850.00.450.681 0.000 0.00 0.20 179.0 7/31/2024 06:20 0.7800.000-0.032 0.020 0.0000.000 0.000 0.000 0.6550.0000.000 0.000 0.0000.000 0.000 850.00.100.145 0.000 0.78 0.00 179.0 CTS System with Response Time 7/31/2024 06:22 0.0000.000-0.032 0.020 0.0000.000 0.000 0.073 0.1720.0040.000 98.782 0.0000.017 0.037 849.066.330.598 0.000 0.00 0.64 180.0 7/31/2024 06:23 0.0000.000-0.031 0.016 0.1090.000 0.000 0.037 0.0000.0000.000 99.462 0.2390.000 0.000 849.066.600.069 0.000 0.00 1.21 180.0 7/31/2024 06:23 0.0000.000-0.031 0.000 0.0000.000 0.014 0.296 0.0000.0000.000 100.280 0.1940.000 0.000 850.067.050.000 0.000 0.00 1.22 180.0 NO2/Mid O2 System with Response Time 7/31/2024 06:25 98.7031.051-0.031 0.000 1.8240.000 0.828 0.000 1.0780.0000.000 0.000 0.0000.000 0.000 849.00.280.422 0.000 99.75 10.59 180.0 7/31/2024 06:25 97.3901.690-0.032 0.020 1.2020.000 0.790 0.101 1.9630.2200.000 0.000 0.0000.000 0.000 848.00.580.871 0.000 99.08 10.62 180.0 7/31/2024 06:26 99.6980.865-0.032 0.016 1.2630.000 0.802 0.000 0.9280.0000.000 0.000 0.0870.000 0.000 848.00.290.307 0.000 100.56 10.62 179.0 Spike System with Response Time 7/31/2024 06:28 0.000245.949-0.032 4.614 1.414495.191 0.959 1.614 2.5420.1700.000 2.099 254.2470.000 0.000 846.0257.642.985 10.024 245.95 0.02 180.0 7/31/2024 06:28 0.000249.707-0.032 4.616 2.282493.192 0.919 1.757 3.4390.1240.000 1.893 253.2480.000 0.000 844.0256.492.963 10.066 249.71 0.02 180.0 7/31/2024 06:29 0.000247.760-0.032 4.608 2.891493.922 0.917 1.276 2.3940.3870.000 2.012 254.2020.015 0.000 843.0258.173.940 10.055 247.76 0.16 180.0 Baseline System with Response Time 7/31/2024 06:32 0.0000.000-0.032 0.003 0.0430.000 0.039 0.000 0.7860.0220.000 0.000 0.0000.128 0.019 848.00.550.764 0.000 0.00 0.19 180.0 7/31/2024 06:32 0.0000.000-0.032 0.011 0.1410.000 0.000 0.248 1.0540.0000.000 0.000 0.1650.000 0.000 848.00.871.050 0.000 0.00 0.24 180.0 7/31/2024 06:33 0.0000.000-0.032 0.000 0.3480.000 0.002 0.050 0.1180.0000.000 0.000 0.1060.000 0.075 847.00.510.382 0.000 0.00 0.14 180.0 Run 1 - A 30minute/60min 7/31/2024 14:21 6.18459.5383.346 4.485 577.3184.530 0.000 0.000 45.5930.0006.705 2.888 18.5380.000 1.483 817.023.760.492 0.000 65.72 8.01 180.0 7/31/2024 14:22 0.00073.9905.168 5.526 780.6966.582 0.000 0.000 52.5600.0009.074 4.187 22.3230.000 2.627 817.032.463.141 0.000 73.99 8.12 180.0 7/31/2024 14:23 0.00073.8355.627 5.516 781.6275.793 0.000 0.000 51.3160.0009.186 4.645 23.3570.000 2.610 817.033.873.289 0.000 73.84 8.08 180.0 7/31/2024 14:24 0.00077.8705.877 5.555 772.6115.912 0.000 0.000 50.1040.0008.520 4.333 22.1570.000 2.715 817.031.972.245 0.000 77.87 8.07 180.0 7/31/2024 14:25 0.00076.5246.059 5.507 776.8345.597 0.000 0.000 50.4570.0008.959 4.529 22.4010.000 2.705 817.032.762.896 0.000 76.52 8.04 180.0 7/31/2024 14:26 0.00076.4996.163 5.498 777.9745.375 0.000 0.000 50.9620.0009.496 4.658 22.9940.000 2.611 817.033.393.099 0.000 76.50 8.11 180.0 7/31/2024 14:27 0.00076.5896.262 5.485 782.3435.126 0.000 0.000 51.3430.0009.457 4.359 22.1720.000 2.843 817.033.213.675 0.000 76.59 8.03 180.0 7/31/2024 14:28 0.00076.4656.341 5.493 786.6735.169 0.000 0.000 51.9030.0009.094 4.507 22.3870.000 2.626 817.032.512.803 0.000 76.47 8.07 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 7/31/2024 14:30 0.00078.2056.424 5.497 781.3765.716 0.000 0.000 50.7850.0009.110 4.658 22.0270.000 2.704 817.032.272.587 0.000 78.20 8.10 180.0 7/31/2024 14:31 0.19976.6686.471 5.476 784.8494.902 0.000 0.000 52.4580.0009.270 4.436 23.2770.000 2.643 817.033.543.025 0.000 76.87 8.06 180.0 7/31/2024 14:32 0.00075.5526.478 5.461 788.8684.930 0.000 0.000 52.5620.0009.462 4.593 23.2040.000 2.680 817.033.402.666 0.000 75.55 8.10 180.0 7/31/2024 14:33 0.02276.6096.547 5.474 790.9294.993 0.000 0.000 51.4710.0009.445 4.597 23.3080.000 2.459 817.033.343.070 0.000 76.63 8.06 180.0 7/31/2024 14:34 0.00082.70310.000 5.241 788.2520.000 0.000 0.000 48.6340.00011.143 4.028 22.2920.000 2.908 817.032.873.118 0.000 82.70 8.11 180.0 7/31/2024 14:35 0.00079.4307.701 5.443 794.6244.233 0.000 0.000 51.4710.00010.411 4.697 22.4130.000 2.586 817.032.833.163 0.000 79.43 8.09 180.0 7/31/2024 14:36 0.00081.2998.095 5.427 788.1312.779 0.000 0.000 50.5330.00010.627 4.330 22.0480.000 2.786 817.032.633.181 0.000 81.30 8.12 180.0 7/31/2024 14:37 0.00078.2457.590 5.410 788.8282.467 0.000 0.000 51.2760.00010.118 4.077 23.0500.000 2.738 817.033.483.350 0.000 78.24 8.17 179.0 7/31/2024 14:38 0.00077.7558.441 5.341 791.4911.504 0.000 0.333 49.3160.00011.883 3.956 22.7760.000 2.857 817.033.313.275 0.000 77.76 8.13 180.0 7/31/2024 14:39 0.00077.4536.985 5.438 783.2164.587 0.000 0.000 50.4530.00010.239 4.476 22.9710.000 2.793 817.033.733.281 0.000 77.45 8.08 180.0 7/31/2024 14:40 0.00079.4246.829 5.461 782.5515.164 0.000 0.000 49.9410.0009.773 4.439 22.1330.000 2.741 817.032.422.766 0.000 79.42 8.12 180.0 7/31/2024 14:41 0.00081.8507.767 5.407 784.8552.406 0.000 0.000 49.5530.0009.224 3.913 22.8360.000 2.793 817.033.153.187 0.000 81.85 8.12 180.0 7/31/2024 14:42 0.00081.5058.108 5.420 781.0652.463 0.000 0.935 48.4180.00010.156 3.827 22.4180.000 2.878 817.032.542.724 0.000 81.50 8.10 180.0 7/31/2024 14:43 0.00080.2718.003 5.394 784.3892.315 0.000 0.555 49.1460.0009.512 3.666 22.6190.000 2.978 817.032.892.810 0.000 80.27 8.19 180.0 7/31/2024 14:44 0.00079.8068.036 5.381 786.7492.170 0.000 0.661 49.1520.0009.843 3.887 22.8830.000 2.853 817.033.032.772 0.000 79.81 8.19 180.0 7/31/2024 14:45 0.00080.0737.478 5.435 787.8083.377 0.000 0.299 50.2080.00010.477 3.897 22.2250.000 2.833 817.032.402.871 0.000 80.07 8.08 180.0 7/31/2024 14:46 0.00079.5407.115 5.415 782.1763.851 0.000 0.000 50.7460.00010.173 4.088 22.9730.000 2.749 817.033.543.512 0.000 79.54 8.09 180.0 7/31/2024 14:47 0.00080.6438.564 5.358 774.3731.079 0.000 0.843 48.7590.00010.103 3.758 23.1820.000 2.851 817.033.543.233 0.000 80.64 8.10 179.0 7/31/2024 14:48 0.00079.4277.001 5.453 779.8654.937 0.000 0.240 51.3610.00011.008 4.152 23.1560.000 2.742 817.033.433.030 0.000 79.43 8.11 180.0 7/31/2024 14:49 0.00078.8857.242 5.431 780.4984.620 0.000 0.000 49.6880.0009.677 4.242 23.2260.000 2.622 817.033.323.027 0.000 78.89 8.12 180.0 7/31/2024 14:50 0.00077.6086.747 5.461 784.7985.177 0.000 0.000 50.7840.0009.691 4.659 22.7390.000 2.864 817.033.442.796 0.000 77.61 8.14 180.0 7/31/2024 14:51 0.00078.8617.831 5.233 752.0187.943 0.000 0.066 47.2780.00011.057 4.681 26.6520.000 2.854 817.037.953.712 0.135 78.86 5.06 180.0 0.21477.7717.010 5.404 775.9264.190 0.000 0.131 50.2740.0009.763 4.239 22.6910.000 2.704 817.0032.8992.960 0.005 77.984 7.999 179.9Avg. Spike 1 7/31/2024 15:04 0.00092.5355.636 5.421 713.88042.868 0.000 0.000 42.2540.0009.314 6.302 42.3480.000 3.047 817.055.544.339 0.795 92.53 7.51 180.0 Run 1 - B 30minute/60min 7/31/2024 15:06 0.00083.9115.960 5.495 745.15618.071 0.000 0.000 47.1060.0008.462 5.262 28.5850.000 3.030 817.040.453.440 0.247 83.91 8.04 180.0 7/31/2024 15:07 0.00077.5776.274 5.493 770.3795.802 0.000 0.000 50.0040.0008.953 4.805 23.3910.000 2.715 817.034.073.072 0.000 77.58 8.12 180.0 7/31/2024 15:09 0.00079.3316.386 5.527 766.0915.954 0.000 0.000 49.8430.0008.444 4.252 22.9560.000 2.659 817.033.052.905 0.000 79.33 8.08 180.0 7/31/2024 15:10 0.00081.2337.879 5.448 769.7152.562 0.000 0.253 49.6530.00010.096 3.961 23.3530.000 2.643 817.033.303.032 0.000 81.23 8.21 180.0 7/31/2024 15:11 0.00082.66511.413 5.230 757.0310.000 0.000 1.630 45.9730.00012.530 3.225 23.5030.000 3.174 817.034.093.132 0.000 82.67 8.21 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 7/31/2024 15:12 0.00078.8247.491 5.408 769.9952.867 0.000 1.588 49.8900.00010.852 4.158 23.4580.000 2.846 817.033.983.093 0.000 78.82 8.12 180.0 7/31/2024 15:13 0.00079.5277.722 5.447 771.4922.517 0.000 1.805 50.0610.00010.221 3.939 23.6860.000 2.704 817.033.893.256 0.000 79.53 8.18 180.0 7/31/2024 15:14 0.00078.2966.432 5.499 766.4935.626 0.000 0.000 50.1260.0009.701 4.457 22.8420.000 2.817 817.033.282.754 0.000 78.30 8.22 180.0 7/31/2024 15:15 0.00077.0836.421 5.460 765.3835.234 0.000 0.000 50.5320.0009.107 4.585 24.2570.000 2.512 817.034.553.312 0.000 77.08 8.15 180.0 7/31/2024 15:16 0.00078.4096.439 5.494 763.5845.565 0.000 0.000 50.1480.0009.424 4.810 23.4280.000 2.693 817.034.203.263 0.000 78.41 8.10 179.0 7/31/2024 15:17 0.00077.9196.442 5.528 763.9705.789 0.000 0.000 49.3680.0008.743 4.566 23.2970.000 2.904 817.034.032.817 0.000 77.92 8.20 180.0 7/31/2024 15:18 0.00077.7416.446 5.508 768.2775.157 0.000 0.000 50.8870.0009.350 4.696 23.3650.000 2.842 817.034.092.872 0.000 77.74 8.10 180.0 7/31/2024 15:19 0.00080.6176.992 5.514 765.9423.448 0.000 0.000 49.9090.0008.020 4.256 22.9780.000 2.773 817.033.703.505 0.000 80.62 8.13 180.0 7/31/2024 15:20 0.00081.96011.844 5.223 757.3720.000 0.000 0.577 46.2220.00012.794 3.593 22.1590.000 3.169 817.033.273.560 0.000 81.96 8.05 180.0 7/31/2024 15:21 0.00078.9396.999 5.431 757.7904.414 0.000 0.740 49.4630.00010.703 4.431 23.9410.000 2.758 817.034.272.796 0.000 78.94 8.09 179.0 7/31/2024 15:22 0.00080.7767.563 5.472 767.5302.922 0.000 0.589 48.4130.0008.740 4.107 23.5620.000 2.676 817.033.552.850 0.000 80.78 8.11 180.0 7/31/2024 15:23 0.00079.2496.467 5.498 766.5765.428 0.000 0.000 50.6460.0009.449 4.593 23.1640.000 2.709 817.033.422.658 0.000 79.25 8.11 180.0 7/31/2024 15:24 0.00079.1606.403 5.497 768.3415.741 0.000 0.000 50.3590.0008.970 4.561 23.1700.000 2.550 817.033.613.443 0.000 79.16 8.12 180.0 7/31/2024 15:25 0.00077.5146.433 5.473 761.9135.465 0.000 0.000 50.6680.0009.340 4.914 23.3030.000 2.758 817.034.263.255 0.000 77.51 8.16 180.0 7/31/2024 15:26 0.00076.3116.420 5.491 759.3125.837 0.000 0.000 50.4550.0009.155 4.746 24.0660.000 2.594 817.034.332.863 0.000 76.31 8.12 179.0 7/31/2024 15:27 0.00076.9186.407 5.522 764.8225.781 0.000 0.000 49.4890.0008.815 4.630 23.5590.000 2.601 817.033.542.543 0.000 76.92 8.02 180.0 7/31/2024 15:28 0.00076.4956.419 5.481 763.6095.592 0.000 0.000 50.6390.0009.291 4.601 23.1720.000 2.845 817.033.792.798 0.000 76.50 8.16 180.0 7/31/2024 15:29 0.00077.0066.450 5.482 765.2675.707 0.000 0.000 50.6170.0008.949 4.774 23.3280.000 2.673 817.033.722.794 0.000 77.01 8.18 179.0 7/31/2024 15:30 0.00077.3646.765 5.479 772.4755.171 0.000 0.000 50.5080.0009.249 4.647 23.3850.000 2.678 817.033.332.240 0.000 77.36 8.10 180.0 7/31/2024 15:31 0.00078.2276.914 5.468 763.8284.970 0.000 0.000 49.1180.0009.491 4.278 22.9920.000 2.827 817.033.633.194 0.000 78.23 8.07 180.0 7/31/2024 15:32 0.00078.9466.469 5.465 766.0975.707 0.000 0.000 50.1760.0008.912 4.815 22.9460.000 2.699 817.033.492.905 0.000 78.95 8.18 180.0 7/31/2024 15:33 0.00081.4548.882 5.353 768.5490.490 0.000 0.000 48.9220.0008.962 4.251 23.1240.000 2.677 817.033.663.518 0.000 81.45 8.24 180.0 7/31/2024 15:34 0.00086.9969.028 5.350 768.2730.352 0.000 0.000 46.9450.0007.860 3.980 22.5780.000 2.956 817.033.533.579 0.000 87.00 8.04 180.0 7/31/2024 15:35 0.00076.7286.650 5.437 767.2005.311 0.000 0.000 49.5640.00010.552 4.433 23.5530.000 2.685 817.033.812.895 0.000 76.73 8.15 180.0 7/31/2024 15:36 0.00078.8356.575 5.464 763.9476.355 0.000 0.000 49.5510.0008.964 4.858 23.5140.000 2.678 817.034.092.966 0.000 78.83 8.10 179.0 0.00079.2007.166 5.455 764.8804.795 0.000 0.239 49.5090.0009.470 4.439 23.4870.000 2.762 817.0033.9993.044 0.008 79.201 8.129 179.8Avg. 0.10778.4867.088 5.429 770.4034.492 0.000 0.185 49.8910.0009.617 4.339 23.0890.000 2.733 817.0033.4493.002 0.006 78.593 8.064 179.9Run 1 Avg: Baseline 1 7/31/2024 15:39 0.0000.000-0.009 0.094 0.0000.004 0.067 0.156 0.0000.0000.284 0.000 0.0000.000 0.108 817.00.220.000 0.000 0.00 0.17 180.0 Run 2 - A 30minute/60min 7/31/2024 15:41 0.00071.1194.239 5.381 736.5946.534 0.000 0.000 47.2750.0008.665 4.478 23.1840.000 3.017 817.034.463.381 0.000 71.12 8.00 179.0 7/31/2024 15:42 0.00076.0955.631 5.546 765.0106.909 0.000 0.000 49.7910.0008.398 4.630 23.6250.000 2.674 817.034.002.918 0.000 76.10 8.08 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 7/31/2024 15:43 0.00075.9426.093 5.480 765.0156.192 0.000 0.000 50.5190.0008.724 4.993 23.0210.000 2.842 817.034.163.195 0.000 75.94 8.15 180.0 7/31/2024 15:44 0.00074.0726.326 5.433 763.6286.174 0.000 0.000 48.8860.0009.831 4.517 23.5250.000 2.923 817.034.473.137 0.000 74.07 8.02 179.0 7/31/2024 15:45 1.10876.8216.434 5.507 775.8486.196 0.000 0.000 42.9730.0008.961 4.702 23.1460.000 3.014 817.034.222.867 0.000 77.93 8.12 180.0 7/31/2024 15:46 0.00076.6486.439 5.476 770.3015.681 0.000 0.000 49.9170.0009.221 4.738 23.0110.000 2.716 817.033.743.212 0.000 76.65 8.10 179.0 7/31/2024 15:48 0.00077.9046.464 5.464 773.8385.583 0.000 0.000 49.9640.0009.388 4.727 22.4990.000 2.850 817.033.182.741 0.000 77.90 8.09 180.0 7/31/2024 15:49 0.00078.3636.507 5.474 768.1775.645 0.000 0.000 49.2860.0009.298 4.482 22.5270.000 2.896 817.033.212.851 0.000 78.36 8.13 180.0 7/31/2024 15:50 0.00084.4099.676 5.260 771.5040.000 0.000 0.000 47.4270.0008.646 4.082 22.6020.000 2.936 817.033.333.197 0.000 84.41 8.09 179.0 7/31/2024 15:51 0.00078.5327.262 5.441 771.8194.955 0.000 0.000 49.3420.0009.735 4.253 22.0390.000 2.815 817.032.583.111 0.000 78.53 8.11 180.0 7/31/2024 15:52 0.00079.2457.291 5.448 773.8314.050 0.000 0.000 48.5910.0009.611 4.474 22.2820.000 2.872 817.033.002.991 0.000 79.25 8.01 180.0 7/31/2024 15:53 0.00080.8788.412 5.355 766.9323.121 0.000 0.000 46.9080.00010.187 4.237 21.7500.000 3.044 817.032.813.216 0.000 80.88 8.14 179.0 7/31/2024 15:54 0.00078.6107.216 5.437 767.4344.233 0.000 0.000 47.4390.00010.376 4.683 22.5910.000 3.104 817.034.073.226 0.000 78.61 8.12 180.0 7/31/2024 15:55 0.00079.5867.384 5.436 766.0274.376 0.000 0.000 48.1960.0009.888 4.650 22.5120.000 2.801 817.033.433.320 0.000 79.59 8.17 179.0 7/31/2024 15:56 0.00079.3227.135 5.470 769.0705.757 0.000 0.000 48.0550.0009.516 4.804 22.2700.000 2.869 817.032.792.367 0.000 79.32 8.17 180.0 7/31/2024 15:57 0.00078.1446.681 5.458 776.0165.951 0.000 0.000 49.6460.0009.383 4.639 22.3390.000 2.834 817.033.052.928 0.000 78.14 8.15 180.0 7/31/2024 15:58 0.00078.0497.782 5.368 776.1293.892 0.000 0.000 48.8450.0009.892 4.231 21.9970.000 3.064 817.033.213.400 0.000 78.05 8.06 180.0 7/31/2024 15:59 0.00081.1117.522 5.415 766.4754.103 0.000 0.000 48.2370.0009.351 4.621 21.8800.000 3.021 817.033.073.097 0.000 81.11 8.12 180.0 7/31/2024 16:00 0.00078.5476.654 5.429 767.0886.076 0.000 0.000 49.2290.00010.035 4.772 22.0840.000 2.825 817.032.772.786 0.000 78.55 8.20 179.0 7/31/2024 16:01 0.00082.3588.462 5.393 770.7122.670 0.000 0.077 46.3830.0009.737 3.834 21.7530.000 3.026 817.032.042.519 0.000 82.36 8.15 180.0 7/31/2024 16:02 0.00080.3578.300 5.393 771.0583.447 0.000 0.112 47.5580.00010.984 4.401 21.9020.000 2.944 817.032.492.643 0.000 80.36 8.17 180.0 7/31/2024 16:03 0.00078.0876.607 5.435 765.5236.117 0.000 0.000 47.9610.0009.512 4.575 22.0250.000 3.028 817.032.862.586 0.000 78.09 8.03 179.0 7/31/2024 16:04 0.00080.9428.291 5.353 770.8352.329 0.000 0.093 47.7060.00011.779 4.330 22.3710.000 2.888 817.033.233.297 0.000 80.94 8.10 180.0 7/31/2024 16:05 0.00078.5246.552 5.419 762.7294.683 0.000 0.000 48.5030.0009.554 4.701 21.9970.000 3.053 817.033.222.968 0.000 78.52 8.17 179.0 7/31/2024 16:06 0.00079.1276.497 5.497 767.1105.942 0.000 0.000 48.2040.0009.362 4.552 22.4020.000 2.796 817.033.022.992 0.000 79.13 8.08 180.0 7/31/2024 16:07 0.00078.0626.733 5.469 772.3245.405 0.000 0.000 48.2590.0009.726 4.675 22.2760.000 2.844 817.033.123.053 0.000 78.06 8.17 180.0 7/31/2024 16:08 0.00081.1117.773 5.418 770.5002.419 0.000 0.000 47.8080.0008.754 4.677 22.0600.000 2.933 817.033.012.951 0.000 81.11 8.07 180.0 7/31/2024 16:09 0.00086.6789.380 5.294 773.5400.040 0.000 0.504 47.0310.00011.988 4.146 21.3200.000 3.164 817.032.663.365 0.000 86.68 8.05 180.0 7/31/2024 16:10 0.00079.6586.557 5.488 768.0895.936 0.000 0.000 48.5440.0009.670 4.399 21.8960.000 2.876 817.032.633.069 0.000 79.66 8.08 180.0 7/31/2024 16:11 0.00079.2036.567 5.469 771.0405.808 0.000 0.000 48.6030.0009.532 4.548 22.7290.000 2.697 817.033.593.655 0.000 79.20 8.16 180.0 0.03778.9177.096 5.430 768.4734.674 0.000 0.026 48.2360.0009.657 4.518 22.3870.000 2.912 817.0033.2473.035 0.000 78.954 8.109 179.7Avg. Spike 2 7/31/2024 16:14 0.00093.7186.081 5.448 711.82941.569 0.000 0.000 41.2420.0008.789 5.995 40.1670.000 3.168 817.052.693.284 0.768 93.72 7.48 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Run 2 - B 30minute/60min 7/31/2024 16:16 0.00088.6119.496 5.276 743.4748.310 0.000 0.188 42.5140.00010.935 4.604 27.2350.000 3.365 817.039.313.417 0.173 88.61 8.14 179.0 7/31/2024 16:17 0.00078.7967.103 5.409 771.0534.120 0.000 0.000 49.1050.00011.131 4.378 22.3820.000 2.988 817.033.653.557 0.000 78.80 8.13 180.0 7/31/2024 16:18 0.00079.2096.514 5.441 765.1505.523 0.000 0.000 47.8950.00010.170 4.678 22.4850.000 2.845 817.033.543.365 0.000 79.21 8.18 179.0 7/31/2024 16:19 0.00079.8606.549 5.476 773.7176.020 0.000 0.000 48.7890.0009.511 4.592 21.6800.000 2.968 817.032.793.167 0.000 79.86 8.11 180.0 7/31/2024 16:20 0.00080.5146.696 5.463 766.3375.535 0.000 0.000 47.2210.00010.008 4.684 21.7550.000 2.977 817.032.903.108 0.000 80.51 8.06 180.0 7/31/2024 16:21 0.00080.7506.814 5.421 763.7524.481 0.000 0.000 46.1820.0009.256 4.476 21.6820.000 3.213 817.033.283.286 0.000 80.75 8.18 180.0 7/31/2024 16:22 0.00079.4316.619 5.445 764.6345.825 0.000 0.000 46.6480.0009.786 4.625 22.0330.000 2.981 817.033.383.447 0.000 79.43 8.14 180.0 7/31/2024 16:23 0.00079.6416.597 5.489 764.4845.716 0.000 0.000 47.7400.0009.647 4.676 21.8660.000 2.968 817.032.632.573 0.000 79.64 8.06 180.0 7/31/2024 16:24 0.00079.5386.603 5.490 767.4005.745 0.000 0.000 47.4350.0009.740 4.576 21.6940.000 2.937 817.032.332.564 0.000 79.54 8.10 180.0 7/31/2024 16:26 0.00079.5736.620 5.487 769.2105.772 0.000 0.000 47.9710.00010.025 4.684 21.5390.000 2.878 817.032.312.837 0.000 79.57 8.21 180.0 7/31/2024 16:27 0.00083.24012.258 5.165 761.1610.000 0.000 0.233 43.1310.00014.297 3.729 20.8970.000 3.339 817.032.373.456 0.000 83.24 8.08 180.0 7/31/2024 16:28 0.00080.7236.967 5.434 764.0813.973 0.000 0.000 47.0370.00010.838 4.704 21.9590.000 3.182 817.033.483.029 0.000 80.72 8.07 180.0 7/31/2024 16:29 0.00079.6626.970 5.450 763.9715.203 0.000 0.000 47.4100.00010.776 4.751 21.8820.000 2.964 817.033.053.113 0.000 79.66 8.12 180.0 7/31/2024 16:30 0.00083.9559.062 5.353 770.6190.499 0.000 0.399 45.6800.00013.033 3.891 21.9140.000 3.042 817.033.033.652 0.000 83.96 8.13 180.0 7/31/2024 16:31 0.00079.0136.626 5.471 769.7025.598 0.000 0.000 48.4940.00010.718 4.869 22.0660.000 2.880 817.033.103.046 0.000 79.01 8.17 180.0 7/31/2024 16:32 0.00083.0788.319 5.361 765.1142.031 0.000 0.501 46.0460.00011.973 4.134 21.6230.000 3.226 817.033.043.313 0.000 83.08 8.23 180.0 7/31/2024 16:33 0.00081.3736.817 5.422 763.0074.400 0.000 0.000 47.6070.0009.597 4.373 22.2750.000 2.947 817.033.233.225 0.000 81.37 8.15 180.0 7/31/2024 16:34 0.00078.9476.651 5.477 764.8505.804 0.000 0.000 48.6420.0009.880 4.586 22.5730.000 2.828 817.033.593.458 0.000 78.95 8.12 180.0 7/31/2024 16:35 0.00080.8396.623 5.494 770.7125.808 0.000 0.000 47.8040.0009.716 4.749 22.2350.000 2.842 817.033.093.000 0.000 80.84 8.09 180.0 7/31/2024 16:36 0.00079.6416.620 5.430 761.8564.702 0.000 0.000 47.9710.0009.214 4.763 22.3020.000 2.954 817.033.142.636 0.000 79.64 8.08 179.0 7/31/2024 16:37 0.00078.6016.652 5.480 769.2825.574 0.000 0.000 48.3190.0009.946 4.778 22.5780.000 2.821 817.033.222.716 0.000 78.60 8.15 179.0 7/31/2024 16:38 0.00081.9296.674 5.523 762.8016.001 0.000 0.000 47.9820.0009.430 4.627 21.9220.000 2.808 816.032.202.371 0.000 81.93 8.11 180.0 7/31/2024 16:39 0.00079.2256.670 5.494 768.2905.958 0.000 0.000 48.8330.00010.046 4.569 22.6100.000 2.963 816.033.703.174 0.000 79.23 8.14 180.0 7/31/2024 16:40 0.00079.6036.645 5.517 769.3315.933 0.000 0.000 48.6120.00010.464 4.610 22.7720.000 2.941 816.033.612.817 0.000 79.60 8.10 180.0 7/31/2024 16:41 0.00079.8676.645 5.460 766.4354.521 0.000 0.000 47.8790.0009.620 4.747 22.5250.000 2.968 816.033.452.739 0.000 79.87 8.15 180.0 7/31/2024 16:42 0.00085.85010.933 5.232 759.7280.000 0.000 0.000 44.7810.00010.408 3.893 21.3000.000 3.386 816.032.693.026 0.000 85.85 8.11 179.0 7/31/2024 16:43 0.00081.1656.663 5.507 768.4295.834 0.000 0.000 48.9460.0009.150 4.592 22.1020.000 2.857 816.032.782.861 0.000 81.16 8.14 180.0 7/31/2024 16:44 0.00080.9536.543 5.495 759.0235.833 0.000 0.000 48.2650.0009.528 4.868 22.4560.000 2.853 816.033.473.098 0.000 80.95 8.11 180.0 7/31/2024 16:45 0.00079.2617.010 5.445 758.2665.346 0.000 0.000 48.1840.0009.832 4.851 22.5920.000 2.965 816.033.813.074 0.000 79.26 8.05 180.0 7/31/2024 16:46 0.00079.8396.550 5.366 746.5876.839 0.000 0.000 46.7770.0009.681 4.760 24.1760.000 3.110 816.036.153.864 0.049 79.84 6.86 180.0 0.00080.7567.250 5.432 764.4154.897 0.000 0.044 47.3300.00010.279 4.561 22.3040.000 3.000 816.7033.4113.100 0.007 80.756 8.082 179.8Avg. 0.01879.8377.173 5.431 766.4444.785 0.000 0.035 47.7830.0009.968 4.539 22.3450.000 2.956 816.8533.3293.067 0.004 79.855 8.096 179.8Run 2 Avg: GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline 2 7/31/2024 16:48 0.9570.0000.185 0.047 3.4840.000 0.000 0.443 0.4820.0000.640 0.000 0.0000.000 0.047 816.00.090.000 0.000 0.96 0.16 180.0 Run 3 - A 30minute/60min 7/31/2024 16:50 10.09763.7143.095 4.514 569.5804.348 0.000 0.000 44.3530.0005.081 3.602 17.3470.000 1.520 816.023.511.080 0.000 73.81 7.90 180.0 7/31/2024 16:51 0.00076.8355.559 5.514 755.5097.032 0.000 0.000 48.1920.0009.343 4.808 22.8710.000 3.071 816.034.263.069 0.000 76.83 8.06 180.0 7/31/2024 16:52 0.00076.4976.045 5.459 758.4736.021 0.000 0.000 48.8320.0009.032 4.763 22.8880.000 2.904 816.033.792.878 0.000 76.50 8.15 179.0 7/31/2024 16:53 0.00077.8836.240 5.467 760.7896.228 0.000 0.000 47.8990.0008.897 4.728 22.4580.000 2.941 816.033.262.651 0.000 77.88 8.17 180.0 7/31/2024 16:54 0.00078.2686.352 5.476 761.9356.179 0.000 0.000 48.4790.0008.829 4.665 22.4780.000 2.806 816.033.223.036 0.000 78.27 8.09 180.0 7/31/2024 16:55 0.00078.6546.373 5.461 753.1725.854 0.000 0.000 48.4390.0009.936 4.914 22.4500.000 3.053 816.033.632.693 0.000 78.65 8.17 180.0 7/31/2024 16:56 0.00078.1386.453 5.452 764.5325.863 0.000 0.000 48.1440.0009.711 4.704 22.6820.000 2.932 816.033.943.381 0.000 78.14 8.11 180.0 7/31/2024 16:57 0.00078.3116.451 5.490 764.8215.913 0.000 0.000 47.4670.0009.586 4.695 22.1890.000 3.157 816.034.093.687 0.000 78.31 8.17 180.0 7/31/2024 16:58 0.00080.5506.457 5.496 771.1536.481 0.000 0.000 48.2010.0008.487 4.332 22.0310.000 2.854 816.032.633.002 0.000 80.55 8.19 180.0 7/31/2024 16:59 0.00090.1529.528 5.304 769.5270.000 0.000 0.000 45.3190.0008.036 3.851 21.5220.000 3.220 816.032.813.421 0.000 90.15 8.16 180.0 7/31/2024 17:00 0.00083.4107.601 5.379 769.0823.768 0.000 0.000 47.6890.0008.829 4.303 21.6300.000 2.888 816.032.483.302 0.000 83.41 8.18 179.0 7/31/2024 17:01 0.00082.2237.517 5.401 757.6234.362 0.000 0.000 46.3280.0009.444 4.655 21.4780.000 3.234 816.033.163.172 0.000 82.22 8.17 180.0 7/31/2024 17:02 0.00080.2966.647 5.459 764.4745.892 0.000 0.000 47.8410.0009.715 4.842 22.3630.000 2.962 816.033.903.582 0.000 80.30 8.15 180.0 7/31/2024 17:03 0.00080.7216.928 5.476 766.7005.279 0.000 0.000 46.3730.0009.210 4.621 21.9500.000 2.937 816.032.712.706 0.000 80.72 8.17 180.0 7/31/2024 17:05 0.00082.4688.134 5.388 777.0972.247 0.000 0.000 47.9550.0009.345 4.395 21.8280.000 2.670 816.032.213.166 0.000 82.47 8.13 180.0 7/31/2024 17:06 0.00080.2447.352 5.414 766.5603.010 0.000 0.000 48.4740.0009.532 4.342 21.8540.000 2.890 816.032.593.085 0.000 80.24 8.12 180.0 7/31/2024 17:07 0.00082.1167.611 5.418 766.4022.724 0.000 0.000 46.8810.00010.808 4.530 22.0560.000 2.857 816.033.173.574 0.000 82.12 8.11 180.0 7/31/2024 17:08 0.00078.2406.746 5.460 776.9875.311 0.000 0.000 49.7740.0009.414 4.491 22.6520.000 2.640 816.032.983.084 0.000 78.24 8.11 180.0 7/31/2024 17:09 0.00079.6947.122 5.445 768.5813.627 0.000 0.000 48.3200.0009.847 4.374 22.1460.000 2.771 816.032.813.308 0.000 79.69 8.05 179.0 7/31/2024 17:10 0.00077.9727.142 5.477 776.8625.117 0.000 0.000 49.0030.00010.102 4.509 22.0810.000 2.735 816.032.803.369 0.000 77.97 8.20 180.0 7/31/2024 17:11 0.00082.4549.272 5.350 767.6810.643 0.000 0.000 45.8720.0009.926 3.957 21.3420.000 3.089 816.032.443.416 0.000 82.45 8.12 180.0 7/31/2024 17:12 0.00077.7026.622 5.474 761.9965.470 0.000 0.000 46.9100.0009.961 4.449 22.3340.000 2.821 816.033.413.704 0.000 77.70 8.10 180.0 7/31/2024 17:13 0.00077.9036.942 5.406 764.3893.665 0.000 0.000 47.6970.0009.879 4.501 22.1010.000 2.966 816.033.333.440 0.000 77.90 8.15 180.0 7/31/2024 17:14 0.00076.5466.441 5.460 768.9655.292 0.000 0.000 48.5140.0009.714 4.698 22.5240.000 2.694 816.033.002.932 0.000 76.55 8.13 179.0 7/31/2024 17:15 0.00076.6286.505 5.452 773.0105.324 0.000 0.000 48.8720.0009.782 4.487 22.5000.000 2.619 816.032.692.944 0.000 76.63 8.12 180.0 7/31/2024 17:16 0.00083.6769.104 5.303 769.6140.144 0.000 0.000 46.8180.0009.847 4.136 22.1820.000 2.934 816.033.453.961 0.000 83.68 8.10 179.0 7/31/2024 17:17 0.00077.6147.002 5.473 779.9394.648 0.000 0.000 47.8340.00010.356 4.632 21.9120.000 2.662 816.032.343.024 0.000 77.61 8.10 180.0 7/31/2024 17:18 0.00086.6088.370 5.386 768.1260.346 0.000 0.060 45.7900.00010.710 3.938 22.1470.000 2.752 816.032.493.324 0.000 86.61 8.14 180.0 7/31/2024 17:19 0.00077.9778.333 5.379 767.2182.084 0.000 0.539 45.5610.00011.009 4.480 22.5080.000 2.919 816.033.863.790 0.000 77.98 8.14 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 7/31/2024 17:20 0.00077.1756.878 5.429 771.7603.422 0.000 0.000 48.2980.00010.472 4.825 22.3070.000 2.762 816.033.433.578 0.000 77.18 8.04 180.0 0.33779.3567.027 5.402 760.4194.210 0.000 0.020 47.5380.0009.495 4.474 22.0270.000 2.842 816.0032.8133.179 0.000 79.692 8.123 179.8Avg. Spike 3 7/31/2024 17:23 0.00091.3635.869 5.413 710.34041.321 0.000 0.000 40.5510.0009.088 6.507 40.7470.000 2.852 816.053.163.557 0.765 91.36 7.57 180.0 Run 3 - B 30minute/60min 7/31/2024 17:25 0.00079.5336.061 5.499 753.00917.139 0.000 0.000 46.9050.0008.813 5.061 28.2850.000 2.913 816.039.553.095 0.230 79.53 8.08 180.0 7/31/2024 17:26 0.00076.3846.311 5.504 773.9395.985 0.000 0.000 48.9470.0009.229 4.713 22.5370.000 2.690 816.032.892.746 0.000 76.38 8.22 180.0 7/31/2024 17:27 0.00075.8416.372 5.542 778.3326.293 0.000 0.000 49.6750.0009.089 4.721 22.4140.000 2.607 816.032.692.871 0.000 75.84 8.15 180.0 7/31/2024 17:28 0.00076.1386.398 5.504 776.8705.914 0.000 0.000 49.3250.0009.322 4.657 22.6860.000 2.578 816.032.762.715 0.000 76.14 8.14 180.0 7/31/2024 17:29 0.00086.1029.732 5.275 767.1180.000 0.000 0.266 45.1780.00011.600 3.844 22.2420.000 2.858 816.032.933.616 0.000 86.10 8.12 180.0 7/31/2024 17:30 0.00077.7707.610 5.395 772.1213.373 0.000 0.228 46.9940.00011.585 4.181 22.3260.000 2.826 816.032.953.283 0.000 77.77 8.21 180.0 7/31/2024 17:31 0.00075.4786.371 5.443 770.7096.130 0.000 0.000 48.0190.0009.094 4.755 22.2190.000 2.657 816.032.432.589 0.000 75.48 8.19 179.0 7/31/2024 17:32 0.00076.1936.512 5.446 763.8056.119 0.000 0.000 47.5500.0009.179 4.639 22.2890.000 2.767 816.032.762.772 0.000 76.19 8.19 180.0 7/31/2024 17:33 0.00075.4616.376 5.418 771.3625.453 0.000 0.000 48.8100.0008.593 4.684 22.8220.000 2.665 816.033.102.744 0.000 75.46 8.24 180.0 7/31/2024 17:34 0.00074.6076.354 5.431 763.0446.234 0.000 0.000 47.1830.0008.914 4.622 22.5550.000 2.751 816.032.932.694 0.000 74.61 8.25 179.0 7/31/2024 17:35 0.00076.0866.469 5.486 766.4636.195 0.000 0.000 47.3070.0008.237 4.787 22.2350.000 2.698 816.032.582.635 0.000 76.09 8.12 180.0 7/31/2024 17:36 0.00084.1989.421 5.231 764.0970.000 0.000 0.297 44.5900.00011.563 4.228 22.2590.000 2.916 816.033.023.157 0.000 84.20 8.19 180.0 7/31/2024 17:37 0.00073.5166.309 5.429 766.5066.276 0.000 0.000 48.1780.0009.584 4.866 23.1700.000 2.752 816.034.143.329 0.000 73.52 8.26 180.0 7/31/2024 17:38 0.00075.0936.539 5.416 773.4114.197 0.000 0.000 49.0420.0008.984 4.576 23.3060.000 2.412 816.033.062.815 0.000 75.09 8.26 180.0 7/31/2024 17:39 0.00077.7747.807 5.309 770.1292.835 0.000 0.518 46.4300.00010.464 4.454 22.9080.000 2.757 816.033.653.395 0.000 77.77 8.11 179.0 7/31/2024 17:40 0.00075.1846.327 5.476 759.7806.449 0.000 0.000 48.3170.0008.723 4.820 22.9570.000 2.828 816.033.843.016 0.000 75.18 8.30 180.0 7/31/2024 17:41 0.00074.1836.323 5.478 765.5126.585 0.000 0.000 48.4240.0008.562 4.679 22.9350.000 2.858 816.033.963.279 0.000 74.18 8.20 180.0 7/31/2024 17:42 0.00073.1016.390 5.428 769.7765.965 0.000 0.000 49.3350.00010.057 4.795 23.3580.000 2.717 816.033.892.846 0.000 73.10 8.22 180.0 7/31/2024 17:44 0.00074.9176.413 5.419 768.4034.810 0.000 0.000 48.7870.0009.400 4.853 23.2040.000 2.769 816.034.343.539 0.000 74.92 8.17 180.0 7/31/2024 17:45 0.00073.9146.385 5.441 768.2196.241 0.000 0.000 48.2050.0009.970 4.573 22.6020.000 2.703 816.033.243.276 0.000 73.91 8.16 178.0 7/31/2024 17:46 0.00085.51910.984 5.276 763.7430.000 0.000 0.305 44.4160.0009.749 3.170 21.6310.000 2.926 816.031.783.270 0.000 85.52 8.18 180.0 7/31/2024 17:47 0.00076.2206.671 5.414 769.6085.633 0.000 0.095 48.9100.00011.550 4.285 23.3330.000 2.580 816.033.503.227 0.000 76.22 8.13 180.0 7/31/2024 17:48 0.00073.7156.405 5.424 758.9175.566 0.000 0.000 48.7470.0009.404 4.729 23.3630.000 2.699 816.033.672.634 0.000 73.72 8.18 179.0 7/31/2024 17:49 0.00074.9916.419 5.469 766.6816.000 0.000 0.000 49.8760.0009.317 4.731 22.8410.000 2.674 816.033.252.862 0.000 74.99 8.18 180.0 7/31/2024 17:50 0.00074.4996.404 5.448 774.9515.865 0.000 0.000 50.1640.0009.607 4.774 23.0420.000 2.679 816.033.482.848 0.000 74.50 8.20 180.0 7/31/2024 17:51 0.00077.8927.500 5.431 771.8743.600 0.000 0.000 48.3080.0008.669 4.423 22.4470.000 2.633 816.032.713.080 0.000 77.89 8.16 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 7/31/2024 17:52 0.00076.9236.589 5.463 764.8395.669 0.000 0.000 48.8720.0009.309 4.882 22.3060.000 2.749 816.032.702.462 0.000 76.92 8.20 180.0 7/31/2024 17:53 0.00075.9746.901 5.392 763.6874.296 0.000 0.000 47.7730.0009.435 4.376 22.8330.000 3.003 816.033.462.556 0.000 75.97 8.23 180.0 7/31/2024 17:54 0.00075.3716.477 5.389 771.9014.559 0.000 0.000 49.7390.0009.740 4.689 23.0630.000 2.751 816.033.813.175 0.000 75.37 8.19 180.0 7/31/2024 17:55 0.41665.7117.503 3.925 539.6676.572 0.000 0.000 37.6430.0004.834 3.593 20.7490.000 1.477 816.026.831.099 0.186 66.13 2.73 179.0 0.01476.2766.944 5.373 760.2825.332 0.000 0.057 47.7220.0009.419 4.539 22.8310.000 2.696 816.0033.1972.921 0.014 76.290 8.005 179.8Avg. 0.17577.8166.986 5.388 760.3514.771 0.000 0.038 47.6300.0009.457 4.506 22.4290.000 2.769 816.0033.0053.050 0.007 77.991 8.064 179.8Run 3 Avg: Baseline 3 7/31/2024 17:57 0.9660.000-0.001 0.071 2.0640.000 0.000 0.513 0.2990.3002.311 0.000 0.0000.000 0.072 816.00.140.000 0.000 0.97 0.12 180.0 Post CTS 7/31/2024 18:24 0.0000.000-0.032 0.056 2.2620.000 0.000 0.058 1.0980.4320.000 100.238 0.0000.395 0.101 817.067.030.000 0.000 0.00 0.29 180.0 7/31/2024 18:24 0.0000.000-0.030 0.092 1.2870.000 0.000 0.000 1.3200.0480.000 100.631 0.5590.463 0.221 817.068.090.000 0.000 0.00 0.07 180.0 7/31/2024 18:25 5.1840.000-0.031 0.053 2.0750.000 0.000 0.000 2.2010.0260.000 101.358 0.0000.022 0.000 817.067.580.000 0.000 5.18 0.19 180.0 7/31/2024 18:25 0.0000.000-0.031 0.046 0.1840.000 0.000 0.000 0.4971.7050.000 101.583 0.3670.856 0.033 817.068.160.000 0.000 0.00 0.26 180.0 Post NO2/Mid O2 7/31/2024 18:26 103.7930.430-0.032 0.032 0.0000.000 0.669 0.030 0.0000.0000.000 0.000 0.2520.047 0.000 819.00.630.563 0.000 104.22 10.24 180.0 7/31/2024 18:26 98.2120.000-0.030 0.044 0.0000.000 0.708 0.000 0.2230.0001.917 0.000 0.0000.000 0.000 819.00.000.000 0.000 98.21 10.24 179.0 7/31/2024 18:26 97.9090.933-0.031 0.000 0.0000.505 0.845 0.424 0.0000.0021.754 0.000 0.0000.839 0.045 819.00.090.000 0.000 98.84 10.31 179.0 Post 5-Gas 7/31/2024 18:31 0.000238.764-0.031 4.578 0.000480.550 0.896 1.233 0.7180.0002.056 2.044 255.2580.000 0.000 825.0257.611.480 10.028 238.76 0.02 180.0 7/31/2024 18:31 0.000240.061-0.031 4.585 0.667481.100 0.867 1.705 2.2341.6101.327 2.034 255.0050.000 0.000 825.0258.352.985 10.054 240.06 0.02 180.0 7/31/2024 18:31 0.000235.819-0.031 4.557 0.326481.458 1.048 1.190 0.9210.1851.231 1.938 254.7920.000 0.012 825.0257.231.680 10.071 235.82 0.02 180.0 7/31/2024 18:31 0.000240.854-0.031 4.601 1.736484.264 0.850 1.652 0.4760.0830.583 2.372 256.8910.000 0.000 825.0259.541.604 10.001 240.85 0.16 180.0 7/31/2024 18:31 0.000238.448-0.031 4.523 0.000485.430 0.770 1.130 0.0000.0441.773 2.039 256.4870.756 0.000 826.0260.083.345 10.035 238.45 0.15 179.0 7/31/2024 18:31 0.000238.430-0.031 4.537 0.000481.043 0.819 1.403 0.0000.0501.705 2.074 255.1260.000 0.000 826.0257.401.331 10.036 238.43 0.19 179.0 End of Test Purge 7/31/2024 18:33 0.0000.000-0.032 0.049 0.4710.000 0.035 0.000 0.1260.5561.803 0.000 0.0000.565 0.120 828.00.240.000 0.000 0.00 0.17 180.0 7/31/2024 18:34 0.3250.000-0.031 0.022 0.0000.073 0.027 0.000 0.2800.0080.604 0.000 0.0000.000 0.313 828.00.630.000 0.000 0.32 0.13 180.0 7/31/2024 18:34 0.0000.000-0.031 0.020 0.9600.000 0.000 0.000 0.0000.2310.035 0.000 0.3181.222 0.182 828.00.680.000 0.000 0.00 0.24 180.0 7/31/2024 18:34 0.3720.000-0.031 0.045 0.1100.000 0.016 0.000 0.2900.0151.544 0.000 0.3290.000 0.121 828.00.730.243 0.000 0.37 0.14 180.0 7/31/2024 18:34 0.3210.000-0.031 0.035 0.5530.000 0.000 0.000 0.0000.0000.047 0.000 0.2020.000 0.000 828.00.200.000 0.000 0.32 0.00 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 7/31/2024 18:34 0.0000.000-0.032 0.026 0.9250.000 0.000 0.305 0.0000.7930.000 0.000 1.1110.000 0.143 829.01.400.000 0.000 0.00 0.12 180.0 7/31/2024 18:34 1.0290.000-0.031 0.040 0.4250.000 0.000 0.188 0.7970.1220.000 0.000 0.0000.213 0.063 830.00.130.000 0.000 1.03 0.13 179.0 7/31/2024 18:34 1.9120.000-0.032 0.018 0.0000.000 0.013 0.000 0.7550.0621.563 0.000 0.5810.000 0.000 831.00.580.000 0.000 1.91 0.13 179.0 GAS, Inc.