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DSHW-2022-015233 - 0901a06881099da6
Deq submit <dwmrcsubmit@utah.gov> P3MMP and Other Document Submittal 1 message Darren Bauer <Darren.Bauer@tchem.com>Wed, Jun 8, 2022 at 9:42 AM To: Judith Moran <jmoran@utah.gov> Cc: "dwmrcsubmit@utah.gov" <dwmrcsubmit@utah.gov>, Deborah Ng <dng@utah.gov>, Connie Nakahara <cnakahara@agutah.gov>, "machlis.ben@dorsey.com" <machlis.ben@dorsey.com>, Steve Rynders <Steve.Rynders@tchem.com> Judy, Please see the attached and consider them to Thatcher final draft and submittal to DWMRC for review. These documents include: Response to various requests for information, clarification and comments made through written correspondence and the on-site meeting/discussion. Phase 3 Material Management Plan (P3MMP). Signature pages to both documents. If you requires a hard-copy document(s), please let me know and we will print them out and mail them to you. Thank you for your consideration. Darren Bauer Safety-Health-Environmental Thatcher Group, Inc. 801-924-3454 darren.bauer@tchem.com “ACTA NON VERBA” The information contained in this e-mail message, and any attachments to it, contain confidential, proprietary, privileged, or otherwise secret information. If you are not the intended recipient, or believe that you may have received this email or attachments in error, any dissemination, use, review, distribution, printing or copying of the information contained in this e- mail message and any attachments to it are strictly prohibited. If you have received this communication in error, please notify us by reply e-mail or telephone and immediately and permanently delete the message and any attachments. Please include in your notice that the message and any attachments have been deleted. Thank you. 2 attachments 2022-06-06_ ltr_fnl_dft_thatcher_resptocomments.pdf 1096K State of Utah Mail - P3MMP and Other Document Submittal 1/2 DSHW-2022-015233 2022-06-06_dft_pln_thatcher_p3_work_plan_no_markup-with_appendices.pdf 8821K State of Utah Mail - P3MMP and Other Document Submittal 2/2 1 THATCHER COMPANY Phone (801) 972-4587 P. O. Box 27407, Salt Lake City, UT 84127-0407 Fax (801) 972-4606 June 6, 2022 Utah DEQ Division of Waste Management and Radiation Control P.O. Box 144840 Salt Lake City, UT 84114-4880 Reference: Thatcher Phase 3 Materials Management Plan (to the P3MMP) – Response to Comments Dear Utah Division of Waste Management and Radiation Control: Thatcher Chemical has prepared this letter as a response to comments provided by the Utah Department of Environmental Quality Division of Waste Management and Radiation Control (DWMRC) to the P3MMP, in a letter dated February 23, 2022. On March 3, 2022, DWMRC, Thatcher Chemical, and Stantec personnel met at Thatcher Company offices in Salt Lake City to discuss the initial comment letter from DWMRC and outline a path forward. This letter presents each comment provided by DWMRC in the February 23rd letter, followed by Thatcher Company’s response in italicized, bolded text. A complete copy of the revised P3MMP is included as Attachment 1 and a redlined copy of the P3MMP showing revisions in track changes is included as Attachment 2. Discussion Items and General Comments from February 23rd DWMRC Letter 1. Please add Thatcher personnel, Craig Thatcher, Darrin Bauer, and team leaders to the signatory’s approvals. Thatcher Company Response: As discussed during the March 3rd meeting at Thatcher Company offices, Mr. Darrin Bauer has added Craig Thatcher, Chief Executive Officer and Steven Rynders, Chief Operations Officer for Thatcher Company to the signatory approvals list and created a distribution sign-off list. 2. The Division would like to discuss SharePoint Access. Thatcher Company Response: During the March 3rd meeting, Thatcher requested that DWMRC provide a list of documents and data to be uploaded to the SharePoint site in addition to a list of personnel that will require access to the site. Thatcher received the requested list of documents/ data from DWMRC staff member Judith Moran via email on March 10, 2022. Thatcher will use these lists to ensure that DWMRC staff have access to the requested documentation and data via a dedicated SharePoint site. Ms. Moran mentioned in her email that additional items may be added to the list she provided. Thatcher will address additional documentation, data, and personnel access requests by DWMRC as necessary. 2 3. Please reference the Utah Administrative Code instead of 40 CFR Thatcher Company Response: Henceforth, Thatcher will ensure that, in addition to Code of Federal Regulations, Utah Administrative Code references are included in all submitted documentation. 4. Please specify Utah Solid and Hazardous Waste Rules, (e.g., Universal Waste Rules R315-273 UAC), instead of generic narrative for Best Management Practices (BMP) Thatcher Company Response: Henceforth, Thatcher will remove documented references to “Best Management Practices” (BMP) and cite applicable Utah Administrative Code references in their place. 5. Please provide all documents, spreadsheets, and forms referenced in the Phase 3 Material Management Plan (e.g., the site-specific Health and Safety Plan, the SDS 100 percent composition spreadsheet). Thatcher Company Response: Enclosed with this letter, and in the P3MMP, are the following requested documents: • Hazardous Materials – Thatcher Standard Operating Procedure (SOP) Environmental Health and Safety (EHS-29) in Appendix A of the P3MMP • Clean Harbors site-specific health and safety plan included in Appendix E of the P3MMP • SDS 100 percent composition spreadsheet included with Appen dix G Area Disposition Review Form and Spreadsheet. Phase 3 Material Management Plan (P3MMP) 1. Identification of Baseline Containers in Phase 3 (P3MMP Section 8.0) a. According to the P3MMP, Thatcher identified approximately 650 “Phase 3 Containers” as part of the November 2019 Self Evaluation Report. Thatcher needs to provide evidence to demonstrate that each Phase 3 container was initially included in the November 26, 2019, Self-Evaluation Report. Thatcher Company Response: Thatcher agreed to complete a baseline preliminary inventory of Phase 3 containers. Thatcher’s Baseline preliminary inventory consists of the following. Baseline Preliminary Inventory Areas Figure and Spreadsheets • Areas Map – P3MMP Phase 3 Areas, Figure 3. • Areas Inventory – 14 - areas on Figure 3. • Trailer Inventory – Containers in trailers. • Disposition Inventory – Containers. Baseline preliminary inventory Phase 3 containers were numbered as follows Area (A), such as Area 1 (01), and container number (001) (e.g., A -01-001). Area containers were labeled with assigned numbers. If it was determined that container area numbers were assigned to containers with disposition numbers 3 or materials not within the Phase 3 pre-November 2019 timeline they were removed from the list; therefore, area numbers may not be consecutive. Thatcher’s pre-existing trailer inventories were used for the trailer container inventory; therefore, area numbers were not assigned and containers in trailers were not labeled with assigned numbers. Containers on the disposition inventory have assigned disposition numbers. Baseline inventory P3MMP Figure 3 and baseline preliminary inventory spreadsheets are included as Attachment 1 to this letter. Total number of containers is 2711 (area inventory, trailer inventory, and disposition inventory). b. For the Division to be able to evaluate the scope and timeliness of the characterization and management of Phase 3 containers, Thatcher must label each Phase 3 container with a consecutive number as part of the next weekly inspection. Thatcher Company Response: Please reference response to P3MMP Section 8.0 1.a. c. Thatcher must provide the Division with a specific accounting of each of the numbered containers by area (1-13) for a baseline inventory. Thatcher Company Response: Please reference response to P3MMP Section 8.0 1.a. 2. Phase 3 Accumulation Date (P3MMP Definitions) a. As specified in the SCO, if the Phase 3 accumulation date is unknown, the accumulation date is the unique date that Thatcher first identifies each Phase 3 container. To be clear, this is the first day that Thatcher or their representatives initiates the process to identify, screen, sample, or use generator knowledge to determine the status of a container. Thatcher Company Response: When starting Phase 3 container area review, upon entering a new area, a hazardous label will be initially placed on each container in the area, pending classification of the container contents. The date of the initial label placement on each container will signify the accumulation start date for al l containers in that area. This process is detailed in Section 8.6.3 of the P3MMP. For clarity, during the March 3rd meeting, Thatcher and DWMRC agreed that conducting the Baseline Inventory and assigning a unique tracking number to the Phase 3 Containers identified therein does not constitute initiation of the “process to identify, screen, sample, or use generator knowledge to determine the status of a container.” 3. Compliance Schedule (P3MMP Section 10.1): a. Area disposition review and container management sh ould not be constrained by the number of containers that will fit into the northwest storage area (NWSA) secondary containment. Additionally, two and a half years is not an acceptable timeframe to 4 manage the remaining containers identified in your November 26, 2019, Self- Evaluation Report. The Division would like to discuss methods to accelerate this timeline, such as concurrently evaluating disposition areas (1-13) while awaiting analytical results and profiling for other areas. (See page 3 of P3MMP and pa ge 22, section 10.1) Thatcher Company Response: P3MMP Section 11.1, Compliance Schedule, has been updated based on the number of containers identified from the baseline inventory. Thatcher and DWMRC agreed that the area within the NWSA can be used for storage of repackaged containers and this will make the schedule “reasonably aggressive”. 4. Waste Characterization Program (P3MMP Section 7.0) a. Generator Knowledge i. Because Safety Data Sheets (SDS) only identify constituents present at 1% or more, they cannot be used to rule out toxicity characteristics when making waste determinations, or for identifying underlying hazardous constituents to comply with land disposal restriction (LDR) requirements. Thatcher Company Response: During the March 3rd meeting, DWMRC agreed that SDS can be used for a product if Thatcher is the producer of the lot or batch of the product. SDSs will also be used for known commercial chemical products as detailed in Section 8.5.2.1 of the P3MMP. ii. Please provide an example of a Thatcher production record if Thatcher intends to use them to characterize waste. (Section 7.1.1) Thatcher Company Response: Thatcher agreed to provide DWMRC with an example of batch production record (BPR). However, Thatcher has updated its response as follows: Known non-CCP Phase 3 Hazardous Secondary Materials are not anticipated. If and when these types of materials are identified Thatcher will provide the proposed recycling scenario information (i.e., including a BPR) to DWMRC. iii. Thatcher stated “Through generator knowledge it was determined that pesticides, herbicides, and poly-chlorinated biphenyls (PCBs) are not currently and historically have not been used or stored on-site. Therefore, further evaluation and analyses for pesticides, herbicides, and PCBs are not included in the characterization program.” However, section 3.1.12 of the Solid and Hazardous Waste Management P lan states that “the facility only uses small amounts of these materials,” in reference to pesticides. Please explain how Thatcher can ensure there are no pesticides amongst the Phase 3 containers. Thatcher Company Response: Thatcher agreed to clarify; in current Section 7.1 of the P3MMP, that no TCLP D-listed pesticides were ever historically present on the current site. 5 b. Waste Analysis i. In accordance with R444-14 of the Utah Administrative Code, all laboratories who perform waste determination for compliance with DEQ/Utah Solid and Hazardous Waste Rules (including Thatcher), must be a Utah certified laboratory for the methods used. Please provide documentation showing that Thatcher is a Utah certified laboratory for the proposed methods or modify the plan to ensure this requirement is met. Thatcher Company Response: Please refer to response to the next comment. ii. The Plan indicates that the FTIR method will be used for determining if additional organic testing off-site is needed for volatiles and semi-volatile organics. However, the method has only been approved by EPA for semi- volatiles. Please clarify or modify the plan accordingly. Thatcher Company Response: During the March 3rd meeting, it was decided that DWMRC staff would reach out to Mr. Steve Rynders regarding the allowable use of FTIR testing to screen samples for the presence of organic matter in container samples. DWMRC and Thatcher agreed to remove FTIR references and analyze all samples for TCLP VOAs/Semi-VOAs at the off-site EPA and Utah State- certified lab. iii. The Division recommends field screenings action levels for pH be less than 5 or greater than 9 due to the uncertainty of field pH paper method results. Modify the plan accordingly. Thatcher Company Response: Thatcher agreed to clarify the plan so that it is clear that the field pH sampling is merely a screening tool and safety measure, with the actual sample pH being determined by the analyzing laboratory upon receipt of the sample. The field screening procedures are detailed in Appendix C of the P3MMP. iv. pH paper can only be used for aqueous samples. Method SW-846 9045D must be used for non-aqueous samples. Modify the plan accordingly. Thatcher Company Response: Please refer to response to the last comment above. v. Provide a list of sample preparation and cleanup methods. Thatcher Company Response: Thatcher agreed to include sample preparation and laboratory clean-up procedures in the Plan which is detailed in Section 3.2.1 of the WAP. vi. Include the number and type of quality control samples in the waste analysis plan. 6 Thatcher Company Response: Thatcher agreed to two sets of Quality Control samples MS/MSD per sample area of 50 containers as detailed in Section 3.2.1.2 of the WAP. vii. Specify project specific “Precision, Accuracy, Representativity, Comparability, Completeness, and Sensitivity (PARCCS)” for Phase 3 containers. The Division’s default for waste samples is: 1. Accuracy for MS/MSD and LCS/LCSD is 70-130% 2. Precision for MS/MSD and LCS/LCSD is %RSD <25% 3. Comparability between data sets/split samples 4. Completeness 100% 5. Sensitivity less than the regulatory or risk action levels Thatcher Company Response: Mr. Pat Noteboom of Chemtech-Ford Laboratories1, confirmed the default limits set by DWMRC as detailed in Section 3.2.1.2 of the WAP. 5. Phase 3 Material Inventory and Management (P3MMP Section 8.0) a. Management of Investigation-derived waste (IDW) and contaminated media and debris from spill cleanups must be managed as newly generated waste. Thatcher Company Response: During the March 3rd meeting, Thatcher agreed to add narrative to the Plan clarifying that spills and IDW will be managed as newly generated waste as detailed in Section 8.9 of the P3MMP. b. Explain in the P3MMP how peroxide formers and other chemicals that become more dangerous when they exceed their expiration date and/or as they degrade will be identified and managed. Thatcher Company Response: Incompatibles are discussed in the Solid and Hazardous Waste Management Plan (Appendix B), which is referenced within the P3MMP. Judith Moran stated in an email on March 3, 2022: “I see that you refer to the SHWMP in section 8.0, so it is probably not necessary to add language about incompatibles to the P3MMP.” c. The Solid and Hazardous Waste Management Plan addresses newly generated incompatible wastes in Section 5.6. The P3MMP must also address how potentially incompatible wastes will be identified so they are not improperly stored together. Thatcher Company Response: Please refer to response to the last comment above. 6. Legitimate Recycling (Section 4.3) 1 Formerly American West Analytical Laboratories, Inc. which was purchased by Chemtech-Ford Laboratories. 7 a. Include a description of the process Thatcher will use to demonstrate that each secondary material was legitimately recycled and the documentation that will be provided to the Division. Thatcher Company Response: During the March 3rd meeting, Thatcher agreed to clarify how they determine “Legitimate Recycling” in the Plan. However, Thatcher has updated its response as follows: Known non-CCP Phase 3 Hazardous Secondary Materials are not anticipated. If these types of material s are identified, during the implementation of Phase 3, Thatcher will provide the proposed recycling scenario information (i.e., including a BPR) to DWMRC for approval. 7. Spill Response (P3MMP Section 8.2) a. Contaminated environmental media, spill cleanup materials, PPE, and other contaminated debris/media are considered newly generated waste, therefore the accumulation start date and labeling requirements begin when the spill occurs. Please modify the plan accordingly. Thatcher Company Response: Thatcher agreed to clarify in the Plan that spills are newly generated waste as detailed in P3MMP Section 8.3. b. Consider replacing the word “immediately” with the word “promptly.” In either case, define “immediately” or “promptly” with regard to spill response in the P3MMP and relevant attachments and appendices. Thatcher Company Response: Thatcher agreed to include a definition of “immediate” in the Plan and clarified Thatcher’s response timing as detailed in P3MMP Definitions Section. 8. Container Management (P3MMP Section 8.5) a. Container labeling (Section 8.5.3): container labeling with an indication of the hazards should be done as soon as any hazard information is known rather than waiting until all characterization information is obtained. Modify the plan accordingly. Thatcher Company Response: Section 8.5.3 was updated to 8.6.3 and states, “once hazardous characterization information is obtained” and doesn’t state “waiting until all characterization information is obtained”. b. Container repacking (Section 8.5.4): clarify how Thatcher is addressing damaged/leaking containers located in areas without secondary containment and/or spill response materials. Thatcher Company Response: This is addressed in P3MMP Section 8.3 and 8.6.4 (Section 8.3 references Section 9.6.4). c. Empty Container Management (Section 8.5.6:) citation R315-261-7(b)(i) UAC is missing in this language, “(i) The wastes have been removed that can be removed using the practices commonly employed to remove materials from that type of container such as pouring, pumping, and aspirating, and”. To clarify, all material 8 that can be removed must be removed for the container to be considered empty and therefore not hazardous waste. Thatcher Company Response: Thatcher edited the RCRA definition of “empty” As detailed in Section 8.6.6. 9. Monthly Report (P3MMP Section 9.1) a. Please clarify what forms and reports will be provided to the Division in the monthly report for determining the status of containers, including containers processed through publicly owned treatment works (POTW). Thatcher Company Response: P3 materials will not be processed through the POTW and P3MMP has been edited to clarify this point, as detailed in P3MMP Section 10.1. b. Please provide weekly inspection reports with associated corrective actions taken. Thatcher Company Response: Thatcher will maintain all inspection reports and document corrective actions taken as a result of the inspections on the SharePoint site. The results of inspections will be detailed in monthly reports. 10. Responsibilities (P3MMP Section 5.0) a. Personnel performing each task needs clarification. Please provide an organization chart to identify Phase 3 personnel who are responsible for each task. If there is overlap in their responsibilities, please specify. Thatcher Company Response: During the March 3 rd meeting, Thatcher agreed to add personnel/ responsibilities to the P3MMP material management process flow diagram (Figure 4). 11. Appendix E a. Phase 3 Thatcher Area Disposition Review Form needs clarification (e.g., Yes No at the top of the page). Thatcher Company Response: Appendix E was updated to G – and form edited (e.g., “Labeled Yes (Y) or No (N) and description”). 12. Appendix I a. Clarification is needed on how this form is utilized in the process. Thatcher Company Response: This form is populated from other, existing spreadsheets. This spreadsheet is used to track Phase 3 container recycling (use or, reuse), or disposal determinations. 13. Waste Analysis and Designation Plan (Solid and Hazardous Waste Management Plan Section 3.0) 9 a. Please specify in each of the “Waste Handling” sections that the accumulation start date for all containers of hazardous waste is the date when waste first enters the container, not the container is full. Also, a hazardous waste label and accumulation start date must be on each container while awaiting analysis. Thatcher Company Response: The SHWMP is for newly generated wastes not Phase 3 wastes. The comment is for full satellite accumulation containers <55 gallons. Training is provided for containers >55 gallons (i.e., containers dated when waste is first placed into the container). SHWMP Example: “EPA hazardous waste markings including the accumulation start date when the drums are full.” Appendix C - Phase 3 Waste Analysis Plan (WAP) 14. Sampling (Phase 3 Waste Analysis Plan Section 2) a. Compositing samples, grouping containers for characterization (see WAP Section 2.2), and combining the contents of containers for repackaging is prohibited unless Thatcher has documentation that the waste is generated from the same batch with an identical lot/batch number. Thatcher Company Response: Thatcher determined that compositing samples, grouping containers and combining contents would not occur and edited the WAP as detailed in Sections 2.2 and 2.3 accordingly. b. Land Disposal Restriction requirements, including sampling and analytical requirements must be addressed in the WAP. Thatcher Company Response: Section 3.1 of the WAP was edited accordingly. c. Provide narrative for consistency in collection of quality control samples e.g., matrix spike/matrix spiked duplicates and field duplicates for Clean Harbors sampling plan and P3MMP. Thatcher Company Response: Section 3.2.1.2 of the WAP was edited to detail the laboratory quality control procedures. d. Clarify in the WAP, that when using a COLIWASA or bailer, the full column must be dispensed into a single container. Thatcher Company Response: Section 2.2 of the WAP was edited to clarify that the full column must be dispensed into the sample container. e. The container labeling described in the P3MMP, and the labeling described in Clean Harbors’ Sampling Procedures, Steps 3-12 of container staging (attachment 1 to the WAP) are not the same. Please update either the P3MMP or the attachment to the WAP to reconcile these inconsistencies. Thatcher Company Response: Thatcher updated Section 5.0 of the P3MMP as follows “Thatcher will inform Clean Harbors that the requirements of this plan take precedence over Clean Harbors standard operating procedures (e.g., container labeling).” 10 Thatcher Company sincerely appreciates this opportunity to formally respond to DWMRC comments and look forward to making continued progress by working together. Please contact Darrin Bauer directly with questions, concerns or further comment on the P3MMP. Certification, “I certify under penalty of law that this document and any and all attachments were prepared under my direction or supervision according to a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.” Sincerely, Craig Thatcher, Chief Executive Officer Thatcher Company, Inc. 1900 Fortune Road Salt Lake City, UT 84104 Attachments: Attachment 1 P3MMP Phase 3 Areas (Figure 3) and Baseline Inventory Spreadsheets Separate Files P3MMP P3MMP in track changes (redlined) Thatcher Phase 3 Materials Management Plan (to the P3MMP) – Response to Comments Attachment 1: P3MMP Phase 3 Areas (Figure 3) and Baseline Inventory Spreadsheets Figure 3 Baseline Preliminary Inventory Page 1 of 67 Disposition Spreadsheets Page 3 of 67 Disposition Spreadsheets Disposition ID Labeled As Quantity Remaining Container Size Unit of Measure 5254 Phosphoric acid 85%1 50 # 5252 Ferric chloride 1 260 G 5251 unknown 1 260 G 5244 IP-10 barrier npf 3 55 G 5242 DET-Laundry-Gem state 1 30 # 5241 Alumunum sulfate - liquid 1 55 G 5237 t-1010 g 1 5 G 5231 tdip 02 2 55 G 5228 t-san 1 4*1 G 5227 choice prox 2 55 G 5222 Choice 1002 16 55 G 5218 FP acid san 8 55 G 5217 tamcem 6rs 1 275 G 5214 Blue Dye 1 1 G 5213 t-1010 NPF 1 5 G 5209 t-floc b-135 1 275 G 5207 Tamcem 6rs 1 275 G 5204 MasterRoc sa 160 8 645 # 5202 TI-2906 1 3190 # 5199 Surfactant HF -100c 4 460 # 5190 Potassium Permanganate 2 162 KG 5185 Brady Laundry softner 1 5 G 5179 Purasoap NPF 15 15 G 5177 Ap liquid detergent 4 55 G 5175 RV antifreeze 2 2 1 G 5174 ap liquid det npf 1 1 G 5169 liquisize 2 15 G 5168 cairox potassium permangenate 1 55.125 # 5166 velocity-one 4 55 G 5165 liquid alkaline cleaner 1 55 G 5163 Pro Oxine 10 5 G 5159 Water sample from glendive 0 5 G 5158 Patent blue v 2111 1 55 # Page 4 of 67 Disposition Spreadsheets Disposition ID Labeled As Quantity Remaining Container Size Unit of Measure 5152 Acetic Acid 1 19 L 5149 T-san 2 55 G 5147 Nitric acid 42*be 1 600 # 5141 T-sure 1 55 G 5140 Reclaim water tank by scrubber 1 15 G 5139 Alum reactor 1 15 G 5137 Reclaim water tank nitric acid 1 15 G 5136 Frac F 1853 by magnatite area 1 15 G 5134 Poly tank by sulfuric acid 1 15 G 5127 sodium bisulfite 40% low ph 1 3000 # 5125 IP-10 Barrier NPF 1 275 G 5124 Isopropyl myristate 1 390 # 5122 Sodium Nitrate Waste Water 1 275 G 5117 T-Scav 9905 1 55.115 # 5115 Fresh EC NPF 2 275 G 5112 FP AcidSan acid sanitizer 1 55 G 5110 Sulfuric acid v/v PCGR 3 680 # 5102 Use in ferric sulfate batches 1 275 G 5099 U-2000 4 55 G 5094 Ferric sulafte solution 0 275 G 5087 SaniFresh 5 15 G 5074 UNKNOWN 3 275 G 5062 Teat Dip Base RWK 15 275 G 5057 T-sure NPF 1 55 G 5056 T-Sure NPF 1 55 G 5055 Sanifresh 1 55 G 5007 T-Cide 5243 4 2300 # 5333 T 1005NPF Concentrate 69 55 G 5101 Water Clarifier inc 4030 1 275 G 5392 Sodium Silicate-N 41Baume 3 55 G 5383 Prestige 1 55 G 5382 T-CHX 1 55 G Page 5 of 67 Disposition Spreadsheets Disposition ID Labeled As Quantity Remaining Container Size Unit of Measure 5381 Cloguard-A NPF 1 55 G 5376 Teat Dip emollient 1 275 G 5375 Oxydip Plus NPF 1 55 G 5373 T-Dip 02 2 275 G 5372 Cloguard-A barrier 3 275 G 5369 Cloguard-A 1 275 G 5362 Pace 383 1 500 # 5360 SPE0108 1 55 G 5357 Value HD chlorine CIP cleaner 6 15 G 5352 Sodium Metacilicate Pentahydrate 2 275 G 5346 Velocity Two 5 30 G 5341 Cloguard Activator 4 1 G 5340 Cloguard Activator 4 55 G 5339 T-Prox Part II Concentrate 2 55 G 5334 Cloguard EX NPF 8 55 G 5323 Value Chlorine Dioxide Concentrate Pt A 2 15 G 5322 Value Chlorine Dioxide 3 55 G 5319 Velocity One 4 55 G 5317 CloguardEX NpF 10 55 G 5316 Cloguard SF Activator 2 55 G 5299 Velocity Two 3 15 G 5295 T-CHX 1 15 G 5291 Cloguard H1 Pre Dip NPF 12 55 G 5289 1 275 G 5285 Cloguard H1 Barrier NPF 6 55 G 5283 Cloguard-B 4 55 G 5279 Cloguard SF O 9 55 G 5275 Defendal HD Ext Lifecool 50/50 1 55 G 5270 Cloguard SF Activator 8 55 G 5269 Acedic Acid 99.5% Glacial 1 275 G 5263 CDC-1000 Detergent 3 55 G 5260 Cloguard H1 Pre Dip HF 4 55 G 5258 Calcium Chloride Washout 1 275 G 5250 Master roc sa 160 1 260 G 5239 Potassium Silicate 1 55 G 5236 cloguard h1 pre dip 1 55 G 5230 cloguard h2 npf foam concetrate 1 30 G 5229 cloguard activator 1 4*1 G 5226 CLOGUARD-A BARRIER NPF 13 55 G Page 6 of 67 Disposition Spreadsheets Disposition ID Labeled As Quantity Remaining Container Size Unit of Measure 5223 Cloguard postdip h1 18 55 G 5210 t-floc 1420 1 2253 # 5206 MasterRoc sa 160 1 3150 # 5205 Enerscav a 2 600 # 5201 Meyco sa-167-na 1 3120 # 5198 Meyco SA 430 2 3120 # 5196 HCL hypochlorite tablets 1 50 # 5195 ERC calcium hypochlorite AST 1 55 # 5191 Sodium Nitrate TTA 25%5 50 # 5189 MasterRoc SA 430 4 5 G 5187 Liquid chlorinated cleaner 4 55 G 5184 peracetic acid 15%3 500 # 5172 clogaurd activator 4 1 G 5155 oxy dip plus 1 6*1 G 5146 TEP 52 1 650 # 5142 Phos. Acid 105% tech grade 2 30 G 5135 Premix Reactor 1 15 G 5132 Propylene glycol usp 38%3 460 # 5130 Scrubber Water 2 275 G 5109 Meyco sa 167 na 2 275 G 5100 CDC-1000 det. p-6871-2 1 55 G 5091 Meyco SA 430 1 275 G 5089 T-vet scrub 6 6*1 G 5071 Cloguard SF activator 2 55 G 5011 clogaurd H1 barrier NPF 8 55 G 5305 Ferrous Chloride 28-30%1 55 G 5277 Chlor-U-Foam 1 275 G 5200 Postdip ec npf 9 260 G 5105 Triple Value Post Dip 1%-10%4 260 G 5354 Select Iodine Concentate 1 275 G 5286 SD Provide 1 55 G 5266 Sodium Bisulfate 40%1 55 G 5265 Caustic Soda 25%1 55 G 5255 Velocity Two 11 55 G 5233 02 teat dip part 1 8 55 G Page 7 of 67 Disposition Spreadsheets Disposition ID Labeled As Quantity Remaining Container Size Unit of Measure 5219 sodium metasilicate pentahydrate 30%4 55 G 5180 Purasoap NPF 1 30 G 5167 O2 teat dip part 2 9 338 # 5121 excel final oxy 2 3 577 # 5096 Cloguard B 10 55 G 5095 Complete 3 55 G 5084 T-sure NPF 2 55 G 5077 Compliance GTO 3 15 G 5010 Future Cow ACT 1 55 G 5351 Chlor-u-foam 1 275 G 5350 T-Mulx SP AD-4-10N 4 55 G 5262 Chlor U Foam 2 55 G 5232 tdip 02 concentrate 2 275 G 5224 t-dip 02 4 260 G 5203 Sodium aluminate 39% solids 1 3000 # Total 531 Page 8 of 67 Trailer Spreadsheets - Area 12 Page 9 of 67 Labeled Yes Labeled No Container # of Containers for Project x 15G Drum 8 x 260G Tote 1 x 275G Tote 2 x 2250# Tote 2 x 330G Tote 1 x 2225# Tote 1 x 55G Drum 4 x 450# Drum 4 x 560# Drum 1 x 465# Drum 2 x 55G Drum 1 x 55G Drum 2 x 55G Drum 1 x 55G Drum 1 x 5G Pail 1 x 465# Drum 3 x 55G Steel drum 4 x 275 Tote 1 x 500# Drum 3 x 600# Drum 4 x 360# Drum 2 x 55G Drum 10 x 275G Tote 1 x 50# Pail 24 x 5G Pail 2 x 5G Pail 4 x 5G Pail 2 x 5G Pail 1 x 5G Pail 5 x 5G Pail 1 x 5G Pail 4 x 5G Pail 1 x 1G Jug 1 x 5G Pail 2 x 5G Pail 1 108 Trailer 53323 Page 10 of 67 Labeled Yes Labeled No Container # of Containers for Project x 110# Drum 3 x 5G Jug 20 x 55G Drum 1 x 55G Drum 4 x 55G Drum 2 x 15G Drum 1 x 15G Drum 1 x 55G Drum 3 x 340# Drum 1 x 275G Tote 2 x 55G Drum 2 x 50# Box 18 x 50# Box 50 x 55G Drum 1 x 465# Drum 4 x 55G Drum 3 x 275G Tote 7 x 20KG Drum 11 x 5G Jug 1 x 55G Drum 1 x 55G Drum 1 x 1 x 4 x 1 x 1 x 1 x 110# Drum 1 x 1 147 Trailer 532173 Page 11 of 67 Labeled Yes Labeled No Container # of Containers for Project x 100# Drum 7 x 100# Drum 5 x 225# Drum 2 x 3 x 100# Drum 5 x 100# Drum 10 x 100# Drum 10 x 100# Drum 5 x 400# Drum 2 x 400# Drum 1 x 100# Drum 7 x 90kg Drum 6 x 5g Jugs 11 x 440# Drum 4 x 450# Drum 4 x Med Fiber Drum 10 x Med Fiber Drum 2 x Med Fiber Drum 4 x Med Fiber Drum 10 x 100# Drum 10 x 90kg Drum 4 x 1G Jug 9 x 15G Drum 5 x 55G Drum 2 x 4x1 Case 1 x 15G Drum 2 x 275G Tote 1 x Lg Fiber Drum 4 x Box 7 x 400# Drum 1 x 400# Drum 1 x Med Fiber Drum 10 x Med Fiber Drum 1 x 260G Tote 1 x 15G Drum 1 x 15G Drum 1 x 15G Drum 1 x 15G Drum 1 x 15G Drum 1 x 275G Tote 2 174 Trailer 5316 Page 12 of 67 Labeled Yes Labeled No Container # of Containers for Project x 100# Fiber Drum 9 x 50# Box 7 x 575# Drum 3 x 260g Tote 1 x 585# Drum 8 x 5Gal Bucket 21 x 55g Drum 2 x 585# Drum 4 x 260g Tote 1 x 450# Drum 5 x 460# Drum 3 x 100# Drum 1 x 5g Drum 10 x 55g Drum 4 x Med Fiber Drum 1 x Large Fiber Drum 1 x Small Fiber Drum 2 x Boxes 4 x Containers 25 x 55g Drum 3 x 55g Drum 1 x 15g Drum 1 x 55g Drum 1 x 15g Drum 1 x Containers 9 x 5g Drum 20 x 270g Tote 1 x 55g Drum 3 x 55g Drum 1 x 275g Tote 3 156 Trailer 534325 Page 13 of 67 Labeled Yes Labeled No Container # of Containers for Project x 2300# Tote 1 x 275g Tote 1 x 2730# Tote 1 x 55g Drum 1 x 15g Drum 2 x 275g Tote 1 x 2300# Tote 1 x 275g Tote 1 x 275g Tote 1 x 2900# Tote 1 x 2800# Tote 1 x Large Fiber Drum 2 x Med Fiber Drum 1 x 55g Drum 1 x 55g Drum 1 x 55g Drum 2 x 55g Drum 4 x 15g Drum 5 x 40# Pail 1 x 5g Drum 2 x 55g Drum 8 x 275g Tote 2 x 2820# Tote 1 x 275g Tote 5 47 Trailer 53138 Page 14 of 67 Yes No Container # of Containers for Project x 475# Drum 4 x 90kg Drum 8 x 450# Drum 3 x Med Fiber Drum 1 x 50# Buckets 2 x 500# Drum 2 x 448# Drum 1 x 55g Drum 1 x 450# Drum 3 x 200# Fiber Drum 4 x 165kg Drum 4 x 680# Tote 1 x 450# Drum 4 x 450# Drum 3 x Large Fiber Drum 1 x Large Fiber Drum 1 x 55g Drum 1 x 55g Drum 1 x 15g Drum 1 x 55g Drum 2 x 5g Jugs 2 x Large Fiber Drum 1 x 25kg Drums 24 x 25kg Bags 24 x 50# Bags 4 x 25kg Bags 20 x 55g Drum 1 x 15g Drum 1 x 50g Jugs 2 x 15g Drum 1 x 5g Jugs 1 x 55g Drum 2 x 25# Pail 3 x 6x1 Boxes 2 x 6x1 Boxes 1 x 6x1 Boxes 5 x 6x1 Boxes 3 x 6x1 Boxes 2 x 6x1 Boxes 2 x 6x1 Boxes 1 x 1g Jugs 5 x 50# Box 1 x 6x1 Boxes 11 x 6x1 Boxes 1 x 1g Jugs 3 x 25# Boxes 39 Trailer 530417 Page 15 of 67 x 6x1 Boxes 1 211 Page 16 of 67 Labeled Yes Labeled No Container # of Containers for Project x 5g Jugs 48 x 6x1 Boxes 12 x 594# Drum 4 x 275g Tote 1 x 275g Tote 1 x 275g Tote 1 x 275g Tote 2 x 2200# Tote 1 x 165# Drum 1 x 30g Drum 4 x 4x1 Boxes 56 x 55g Drum 3 x 15g Drum 9 x 2000# Sack 2 x 25kg bags 40 x 2000# Sack 2 x 179.5kg Drum 4 x 422.5# Drum 4 x 475# Drum 4 x 174.5kg Drum 8 x 40# Pail 1 x 25kg Box 1 x 420# Drum 1 x 425# Drum 1 x 450# Drum 1 x 50# Drum 1 x 250# Drum 1 x 229kg Drum 1 x 443# Drum 1 x 475# Drum 1 x 50# Bag 1 x Fiber Drum 1 219 Trailer 53113 Page 17 of 67 Area Spreadsheets Page 19 of 67 4859-0509-4175\1 Phase 3 Material Management Plan Thatcher Company Inc. 1905 West Fortune Road, Salt Lake City, Utah June 06, 2022 Prepared for: Thatcher Company, Inc. 1905 West Fortune Road, Salt Lake City, Utah Prepared by: Stantec Consulting Services Inc. 2890 East Cottonwood Parkway Suite 300 Salt Lake City, Utah Phase 3 Material Management Plan June 2022 4859-0509-4175\1 This document entitled Phase 3 Material Management Plan was prepared by Stantec Consulting Services Inc. (“Stantec”) for the account of Thatcher Company, Inc. (Thatcher) and Thatcher Company, Inc. (the “Client”). Any reliance on this document by any third party is strictly prohibited . The material in it reflects Stantec’s professional judgment in light of the scope, schedule and other limitations stated in the docum ent and in the contract between Stantec and the Client. The opinions in the document are based on conditions and information existing at the time the document was published and do not take into account any subsequent changes. In preparing the document, Stantec did not verify information supplied to it by others. Any use which a third party makes of this document is the responsibility of such third party . Such third party agrees that Stantec shall not be responsible for costs or damages of any kind, if an y, suffered by it or any other third party as a result of decisions made or actions taken based on this document. Prepared by (signature) Rich Pratt Reviewed by (signature) Tom Fendler Approved by (signature) Craig Thatcher Chief Executive Officer Thatcher Company, Inc. Approved by (signature) Steven Rynders, PhD VP R&D/Technical Services Thatcher Company, Inc. Phase 3 Material Management Plan June 2022 i 4859-0509-4175\1 Table of Contents 1.0 EXECUTIVE SUMMARY ................................................................................................ 1 2.0 INTRODUCTION ............................................................................................................ 4 2.1 BACKGROUND .............................................................................................................. 4 2.2 FACILITY DESCRIPTION .............................................................................................. 4 2.3 EMERGENCY RESPONSE ............................................................................................ 6 2.3.1 Incident (i.e., Leaking Containers) Management Programs ............................ 6 3.0 PROJECT DESCRIPTION ............................................................................................. 7 3.1 PHASE 3 MATERIALS MANAGEMENT PURPOSE ....................................................... 7 3.2 PHASE 3 MATERIAL MANAGEMENT OBJECTIVES .................................................... 7 4.0 REGULATORY REQUIREMENTS ................................................................................. 8 4.1 LARGE QUANTITY GENERATOR MATERIAL MANAGEMENT STANDARDS ............. 8 4.2 MATERIAL ANALYSIS AND DESIGNATION STANDARDS ........................................... 8 4.3 LEGITIMATE RECYCLING EVALUATIONS ................................................................... 9 5.0 RESPONSIBILITIES .....................................................................................................10 5.1 THATCHER ...................................................................................................................10 5.2 FIELD SERVICES CONTRACTOR ...............................................................................10 5.3 ENVIRONMENTAL CONSULTANT ...............................................................................11 5.3.1 Electronic Files for DWMRC on SharePoint Site .......................................... 11 6.0 HEALTH AND SAFETY ................................................................................................12 6.1 CLEAN HARBORS MATERIAL MANAGEMENT HEALTH AND SAFETY .....................12 7.0 WASTE CHARACTERIZATION PROGRAM ................................................................12 7.1 APPLICATION OF GENERATOR KNOWLEDGE..........................................................12 7.1.1 Generator Knowledge Used for Characterization of Known Materials .......... 13 7.2 APPLICATION OF FIELD SCREENING AND ANALYSIS FOR MATERIAL CHARACTERIZATION ..................................................................................................13 8.0 PHASE 3 MATERIAL INVENTORY AND MANAGEMENT ...........................................15 8.1 PHASE 3 BASELINE PRELIMINARY INVENTORY ......................................................15 8.2 INSPECTIONS ..............................................................................................................15 8.3 MANAGEMENT OF “CONTAINERS NOT IN GOOD CONDITION” ...............................16 8.4 PHASE 3 CONTAINER AREA REVIEW AND MANAGEMENT DETERMINATIONS ......................................................................................................16 8.4.1 Area Disposition Review Forms and Spreadsheet ........................................ 17 8.5 DISPOSITION AND/OR DISPOSAL MATERIAL MANAGEMENT .................................17 8.5.1 Known Phase 3 Hazardous Secondary Materials Identified for Disposition ................................................................................................... 18 8.5.1.1 Known Material Identified for Disposition (Use or Reuse (Recycling)) .......... 18 Phase 3 Material Management Plan June 2022 ii 4859-0509-4175\1 8.5.2 Material Identified for Disposal ..................................................................... 20 8.5.2.1 Known Material Identified for Disposal ......................................................... 20 8.5.2.2 Unknown Material Identified for Disposal ..................................................... 20 8.5.3 Material Management Disposition Forms and Spreadsheets ........................ 20 8.5.3.1 Disposal Forms and Tracking Spreadsheets ................................................ 20 8.5.3.2 Disposition Tracking Spreadsheet ................................................................ 20 8.6 CONTAINER MANAGEMENT .......................................................................................20 8.6.1 Management of Containers Posing Imminent Threat .................................... 20 8.6.2 Management of Containers Spilled During Transport ................................... 20 8.6.3 Container Labeling ....................................................................................... 21 8.6.4 Container Repackaging ................................................................................ 21 8.6.5 Container handling ....................................................................................... 22 8.6.6 Empty Container Management ..................................................................... 22 8.7 WASTE STORAGE PROCEDURES .............................................................................22 8.8 WASTE DISPOSAL .......................................................................................................23 8.9 DECONTAMINATION PROCESS .................................................................................23 9.0 REPORTING .................................................................................................................23 9.1 MONTHLY REPORTING ...............................................................................................23 10.0 COMPLIANCE SCHEDULE ..........................................................................................24 10.1 COMPLIANCE SCHEDULE ..........................................................................................24 11.0 REFERENCES ..............................................................................................................26 LIST OF TABLES Table 1 Buildings and Activities Table 2 Field Screening, Sampling, and Analyses Steps Table 3 Area Containers Table 4 Disposition List Containers Figures Figure 1 Site Location Map Figure 2 Site Map Figure 3 Phase 3 Areas Figure 4 Material Management Process Flow Diagram Phase 3 Material Management Plan June 2022 iii 4859-0509-4175\1 Appendices Appendix A Thatcher Emergency Response Program (Hazardous Materials Emergency Action Plan EHS-13) and Standard Operating Procedure (SOP) Environmental Health and Safety (EHS-29) Appendix B Solid and Hazardous Waste Management Plan Appendix C Waste Analysis Plan Appendix D P3MMP Distribution List Appendix E Clean Harbors Health and Safety Plan Appendix F 90-Day Hazardous Waste Storage and Phase 3 Areas Inspection Forms Appendix G Area Disposition Review Form and Spreadsheet Appendix H Field Screening Form Appendix I Repackaging Form Appendix J Container Tracking and Disposal Spreadsheets Appendix K Disposition Tracking Spreadsheets Appendix L Monthly Report Phase 3 Material Management Plan June 2022 iv 4859-0509-4175\1 Abbreviations CCP Commercial Chemical Products CFR Code of Federal Regulation DOT Department of Transportation DWMRC Division of Waste Management and Radiation Control EHS Environmental Health and Safety EPA Environmental Protection Agency IDW Investigation-Derived Waste LQG Large Quantity Generator NWSA Northwest Storage Area P3MMP Phase 3 Material Management Plan PCBs Poly-chlorinated biphenyls PPM Parts Per Million POTW Publicly Owned Treatment Works RCRA Resource Conservation and Recovery Act SCO Stipulation and Consent Order SDS Safety Data Sheet SHWMP Solid and Hazardous Waste Management Plan SOP Standard Operating Procedure Stantec Stantec Consulting Services, Inc. TCLP Toxicity Characteristic Leaching Procedure Thatcher Thatcher Company, Inc. UDEQ Utah Department of Environmental Quality USHWA Utah Solid and Hazardous Waste Act VOA Volatile Organic Analysis WAP Waste Analysis Plan WICP Waste Inventory and Characterization Plan Phase 3 Material Management Plan June 2022 v 4859-0509-4175\1 Definitions Commercial Chemical Products (CCP): means both listed commercial chemical products as defined in 40 C.F.R. § 261.33 / R315-261-33 and non-listed commercial chemical products which EPA defines as including all types of unused commercial products, including off -specification species of the same, that exhibit a characteristic of hazardous waste. See 50 Fed. Reg. 14219 (April 11, 1985). Container not in Good Condition: includes leaking containers or containers with a structural integrity issue that may cause the loss of containment due to corrosion, d ents, etc. Container Repackage: Container repackaging includes overpacking and/or transfer of materials to a container in good condition. Discarded Material: means and includes any material that is (i) abandoned by disposal, accumulated or stored, but not recycled, before or in lieu of being abandoned by disposal, or sham recycled; (ii) accumulated or stored before recycling in manner constituting disposal or, unless it is a commercial chemical product, accumulated speculatively; or (iii) inherently waste-like.1 Discarded Spilled Material or Waste: means spilled or released Material or Waste not immediately recovered. Hazardous Secondary Materials released to the environment and not immediately recovered are Discarded Spilled Materials.2 Container Tracking and Disposal Spreadsheet: is the spreadsheet which will be used to (i) track area containers, (ii) record the characterization and disposal of containers that are determined to be waste. The container tracking and disposal spreadsheet will be used to record field screening data and laboratory analytical results which are the basis for characterizing and profiling waste material for disposal. Disposition: means the act of making Phase 3 determinations for either (i) use or reuse (recycling) “disposition”, or (ii) disposal. Hazardous Secondary Material: means a secondary material (e.g., spent material, by-product, or sludge) that, when discarded, would be identified as a hazardous waste pursuant to Utah Admin. Code R315 -261. Hazardous Waste: means when tested or classified based on generator’s knowledge, a solid waste that (i) is not excluded under Utah Admin. Code R315- 261-4; and (ii) is listed as a hazardous waste under Utah Admin. Code R315- 261-30 through 33, and/or exhibits any of the characteristics of a hazardous waste under Utah Admin. Code R315- 261-20 through 24. “Immediately” Related To Spill Response: means response measures are implemented without delay. 1 Utah Admin. Code R315-261-2(a)(2)(i). 2 Utah Admin. Code R315-260-43(a)(3). Phase 3 Material Management Plan June 2022 vi 4859-0509-4175\1 Newly Generated waste and Date: means any newly generated waste (e.g., investigation derived waste, spill cleanup, environmental media (from spill cleanup), and/or personal protection equipment). The container is dated with the date the material is accumulated. Non-Hazardous Material/Waste: means those materials which are not a listed hazardous waste and do not exhibit a characteristic of hazardous waste, either within containers not being discarded (non-hazardous material) or being discarded (non-hazardous waste). Non-Hazardous Secondary Material: means a secondary material that, when discarded, would not be identified as a hazardous waste pursuant to Utah Admin. Code R315-261. Material: means those substances discretely contained on-site, including active inventory, Hazardous Secondary Material, recyclable material, and wastes (hazardous, or non-hazardous solid waste). Phase 3 Accumulation Date: means the unique date that Thatcher first identifies each Phase 3 container (e.g., container area review date P3MMP Section 8.4). Phase 3 containers: means containers at the facility as of the date of the “Self-Disclosure Letter,” November 26, 2019, that contain material that is not raw material, process intermediates,3 or products (not including Thatcher’s active inventory CCP’s) and are being stored on-site for use or reuse (recycling) and, as described in the Self-Disclosure Letter, for which Thatcher may not have historically maintained sufficient information to document compliance with Resource Conservation and Recovery Act (RCRA) for the subset of these materials that would be hazardous waste if “discarded” (i.e., disposed). Phase 3 containers may include recyclable materials, non-hazardous material/solid waste, hazardous waste, universal waste, and/or used oil. Universal Waste: means hazardous waste (batteries, pesticides, mercury-containing equipment, lamps, aerosol cans, and antifreeze) managed under Utah Admin. Code R315-273 standards for universal waste management. 3 Materials generated from one process for another process. Phase 3 Material Management Plan June 2022 1 4859-0509-4175\1 1.0 EXECUTIVE SUMMARY Stantec Consulting Services Inc. (Stantec) conducted an environmental compliance audit in October 2019 at the Thatcher Company, Inc. (Thatcher) facility located at 1905 West Fortune Road, Salt Lake City, Utah (the Facility or Site, see Figures 1 and 2). The audit was conducted to evaluate the Facility’s compliance with state and federal solid and hazardous waste management requirements. Based upon the audit findings, Thatcher, through its legal counsel Dorsey & Whitney LLP, submitted a self -disclosure letter dated November 26, 2019 (the Disclosure Letter) to DWMRC, which identified instances of potential non- compliance regarding the manner in which materials are stored on-site. Thatcher then met with the regulatory agency to discuss the issues. A Waste Inventory and Characterization Plan dated March 11, 2020 (WICP) was submitted to the DWMRC which proposed to characterize and dispose of waste identified at the Facility in four phases: • Phase 1 – laboratory chemicals; • Phase 2 – an estimated 1,106 containers in the northwest storage area (NWSA) and an estimated 200 containers directly east of the NWSA fence line; • Phase 3 – an estimated 650 containers in various on-site storage areas; and • Phase 4 – material management for continuous operation. Thatcher completed Phase 1 of the project on April 10, 2020 and characterized/disposed of a total of 99 containers. Thatcher completed Phase 2 of the WICP on May 28, 2021 and characterized/disposed of 1,499 containers in and around the NWSA. Prior to pausing implementation of Phase 3 due to concerns raised by the DWMRC, Thatcher characterized/disposed of 55 containers. Thatcher will resume implementation of Phase 3 once it receives DWMRC approval of this Phase 3 Material Management Plan (P3MMP). A draft Stipulation and Consent Order (SCO) was agreed to between Thatcher and the DWMRC and was provided for public comment. The approved SCO (number 2102006) is dated December 9, 2021. By letter dated January 7, 2022, DWMRC granted Thatcher an extension t o January 21, 2022 to submit the plan and schedule required by paragraph 18.5 of the SCO. This P3MMP documents the plan and schedule required by paragraph 18.5 of the SCO. The primary objectives of P3MMP tasks to be completed at the Facility include: • Demonstrate Phase 3 container material management compliance pursuant to the Utah Solid and Hazardous Waste Act (the Act), Utah Code § 19-6-101, et seq., and the Utah Used Oil Management Act (the Used Oil Act), Utah Code § 19-6-701. • Maintain Phase 3 material management records for material handling (i.e., tracking material movement and management practices), disposal, or continued storage for use or reuse (recycling) with tracking to demonstrate compliance with RCRA legitimate recycling requirements. Phase 3 Material Management Plan June 2022 2 4859-0509-4175\1 • Review the facility and evaluate the disposition of all Phase 3 containers. • Ensure that all containers are in good condition with no leaks or defects (such as dents or corrosion) that may compromise the integrity of the container and confirm that the construction of all containers are compatible with the contents. Materials in Containers not in Good Condition and/or materials in containers not compatible with the contents will be repackaged. • Respond to leaks or spills immediately. • Label all unlabeled Phase 3 containers. • Make hazardous waste determinations pursuant to R315-262-11. • Ship Phase 3 hazardous material designated for disposal within 90 days of the Phase 3 Accumulation Date or request, in writing, an extension of the 90-day time limit demonstrating that the extension is necessary due to unforeseen, temporary, and uncontrollable circumstances . • Complete the project within a “reasonably aggressive” project schedule estimated timeline (see Section 10, Compliance Schedule). • Use best management practices in the management of non-hazardous solid waste, hazardous waste, universal waste, and/or used oil. • Provide monthly status update reports to the DWMRC of progress completing Phase 3 activities. Phase 3 materials in containers will be characterized following procedures set forth in Section 7, which builds on the experiences gained during implementation of Phases 1 and 2 of the project. Management options may include, as appropriate and in compliance with regulatory requirements and paragraph 18.3 of the SCO, use/reuse (recycling) in the production process, and/or disposal. Thatcher has contracted with Stantec to coordinate material analysis and characterization with Clean Harbors. The proposed characterization methods include field screening, on -site laboratory analyses (Thatcher), and off-site laboratory analysis, as detailed in the attached Waste Analysis Plan (WAP). The characterization program is based on field screening data and pH for the categories as described in the WAP and Container Tracking and Disposal Spreadsheets . When possible, generator knowledge will also be applied to characterize known materials. The characterization program is as follows. • Field screening to categorize materials (oils, water, solvents, other) for sampling. • Off-site lab pH confirmation. • Laboratory analysis as detailed in the attached WAP. • Category analyses as described in Table 2. Thatcher will continue to inspect the 90-day hazardous waste storage and Phase 3 areas on a weekly basis. Beginning on October 22, 2021, Thatcher observed all Phase 3 containers weekly to identify Containers not in Good Condition. Weekly area inspections have been documented by area managers and since initiating this inspection program four containers requiring repackaging have been identified and managed. Weekly area monitoring and inspections will continue through Phase 3. Containers found to be “Containers not in Good Condition” will be repackaged for storage on-site. Any container that is not in good condition which contains material that exhibits a characteristic of, or is a listed hazardous waste, and containers for which insufficient information is available to make a hazardous waste determination, shall not be recycled or reworked and must be managed for disposal. Phase 3 Material Management Plan June 2022 3 4859-0509-4175\1 Thatcher has designated 14 Phase 3 container management areas as shown on Figure 3. Thatcher completed a Baseline Preliminary Inventory; as directed by the DWMRC, to provide assurance that the total number of Phase 3 containers does not change as the project progresses. Material management decisions can proceed concurrent with the area disposition review and inventory. Management decisions will include use/reuse (recycling) in the production process, and/or disposal. A Facility -wide disposition area review will be completed to gather information needed to facilitate efficient management decisions. Each Phase 3 container will be assigned a tracking number. Once Phase 3 area disposition review is initiated, container management will be limited to the number of containers requiring disposal that will fit into the NWSA secondary containment. Thatcher will manage containers identified for disposition that will be left in the area or moved to another area for storage for use and tracked on the disposition spreadsheets. Once assigned a date, Thatcher intends to manage containers designated for disposal as non-hazardous, universal waste, and/or hazardous waste containers within the 90-day LQG storage time limit. Thatcher will prepare and submit P3MMP reports to the DWMRC on or before the 15th day of each month until P3MMMP is completed. The Phase 3 material management process will continue within 30 days of receipt of DWMRC approval of this P3MMP. Phase 3 Material Management Plan June 2022 4 4859-0509-4175\1 2.0 INTRODUCTION Stantec Consulting Services Inc. (Stantec) conducted an environmental compliance audit in October 2019 at the Thatcher Company, Inc. (Thatcher) facility located at 1905 West Fortune Road, Salt Lake City, Utah (the Facility or Site, see Figures 1 and 2). The audit was conducted to evaluate the Site’s compliance with state and federal solid and hazardous waste management requirements. Based upon the audit findings, Thatcher, through its legal counsel Dorsey & Whitney LLP, submitted a self-disclosure letter dated November 26, 2019 (the Disclosure Letter) to DWMRC, identifying instances of potential non -compliance in the manner in which materials are stored on-site. Thatcher then met with the regulatory agency to discuss the issues. 2.1 BACKGROUND A Waste Inventory and Characterization Plan dated March 11, 2020 (WICP) was submitted to the DWMRC which proposed to characterize and dispose of waste identified at the Facility in four phases: • Phase 1 – laboratory chemicals; • Phase 2 – an estimated 1,106 containers in the northwest storage area (NWSA) and an estimated 200 containers directly east of the NWSA fence line; • Phase 3 – an estimated 2,177 containers in various on-site storage areas (see Section 8.1); and • Phase 4 – material management for continuous operation. Thatcher completed Phase 1 of the project on April 10, 2020 and characterized/disposed of a total of 99 containers. Thatcher completed Phase 2 of the WICP on M ay 28, 2021 and characterized/disposed of 1,499 containers in and around the NWSA. Prior to pausing implementation of Phase 3 due to concerns raised by the DWMRC, Thatcher characterized/disposed of 70 containers. Thatcher will resume implementation of Phase 3 once it receives DWMRC approval of this Phase 3 Material Management Plan (P3MMP). 2.2 FACILITY DESCRIPTION The Site is comprised of several parcels totaling approximately 30 acres. The Site is loca ted within an industrial area of Salt Lake City and is zoned M-1 for Light Manufacturing use. The Site is bordered by Interstate-215 to the west, a large canal to the north, and California Avenue to the southeast. Fortune Road transects the southern portion of the Site. Railroad tracks cross the southern and western portions of the Site with railroad spurs entering the Site from the southeast and northwest corners o f the property. The Site is used for blending and repackaging of chemicals and consists of se veral buildings, material storage areas, truck trailers used for storage, a large warehouse, office buildings, an above ground storage tank farm, and wastewater treatment infrastructure. Thatcher uses over 30 chemicals (mostly inorganic basic Phase 3 Material Management Plan June 2022 5 4859-0509-4175\1 chemicals) to manufacture approximately 4,500 products for industries including agriculture, food and dairy, water treatment, waste-water treatment, laundry, pharmaceutical, construction, mining, precious metals, oil and gas, and power generation. The Site location is shown on Figure 1 and the Facility Map is included as Figure 2. Buildings and activities are listed in Table 1 below. Table 1 Buildings and Activities Building Activity 1 Main Warehouse (Process Support) 2a Aluminum Sulfate Production 2b Ferric and Ferrous Sulfate Production 2c Anhydrous Chlorine Repackaging 3a Various Production Chemicals 3b Warehouse Storage (Process Support) 3c Sodium Thiocyanate Production 3 Outside Various combinations of hydrochloric acid products 4 Sodium Carbonate (Soda Ash) mixtures (i.e., compounding) Production 5 Container Wash Area Water Treatment Containments 6 Food and Dairy - Oxidizer Repackaging and Various Production Chemicals 6A 6A - Warehouse 7 Pharmaceutical and Iodine Compounds Production 8 Batch processing from B12 Feed Sulfite to thiosulfate 9 Production Tanks for Repackaging Alcohols, Glycols, and Various Chemicals 9A Warehouse (Process Support) 10 Ammonia for Ammonium Hydroxide Organic Process: Paraformaldehyde (PFA) is reacted w/ MEA to produce monoethanolamine triazine (MEA-T) 11 Calcium Nitrates/Nitrites, Magnesium Nitrate, Sodium Nitrate 12 Sulfite Chemistry Area, Aluminum Chlorohydrate, Ammonium Bisulfite, Potassium Sulfite 13 No Assigned Building/Activity 14 Truck Shop (Process Support) 15 Equipment Storage 16 Maintenance Shop (Process Support) 17 Laboratory (Process Support) 18 No Assigned Building/Activity 19 Tank Farm Area Chemical products from vendors (raw materials) are stored on-site in railcars, tankers, tanks, and/or smaller containers (i.e., totes or drums) for producing Thatcher products (i.e., product component chemicals). Products are produced in designated process locations on-site. Excess product, off-specification (non- conforming chemicals), and/or return material authorized chemicals are used for rework as product component chemicals. Site secondary containment consists of containment for storage tanks (tank farm secondary containments), site containment for storage containers and process operations, and area sumps. The Site is self-contained and is sloped toward the center of the Site. Self-containment includes asphalt and/or concrete surfaces Phase 3 Material Management Plan June 2022 6 4859-0509-4175\1 where materials and stormwater flow into area storm drains/sumps. The flow from the storm drains/sumps is to the water treatment process in the Building-5 area where any pH adjustment, per the existing publicly owned treatment works (POTW) permit, is completed prior to discharge to POTW. Chemical production operations include raw materials storage with secondary containment, mixing and holding tanks, reaction vessels, piping and transfer equipment, scrubbers, boilers, cooling towers, chillers, dewatering filter presses, various water use treatment, and dust cartridge or bag collectors. 2.3 EMERGENCY RESPONSE Thatcher maintains emergency plans in accordance with regulatory requirements and for the purpose of contingency planning for the response in the event of an emergency. 2.3.1 Incident (i.e., Leaking Containers) Management Programs Thatcher conducts weekly area monitoring and inspections. Observations from inspections are recorded on inspection forms and historical inspection forms are archived at the Facility. Containers observed not to be in good condition are addressed as necessary. Thatcher employees respond to incidents according to the plan (see below) applicable to the materials released (i.e., hazardous waste and/or hazardous material), the materials Safety Data Sheet (SDS) and the training required to handle the material. The Facility maintains the following emergency response program plans: • Emergency Response Program (hazardous materials Emergency Action Plan EHS-13) Appendix A. • Preparedness and Prevention Plan for management of 90-day and satellite accumulation hazardous waste storage areas. • Contingency Plan (hazardous waste). These plans detail the emergency response and reporting necessary to meet regulatory requirements. Thatcher’s record keeping and reporting guidelines include the following: • Hazardous Materials – Thatcher Standard Operating Procedure (SOP) Environmental Health and Safety (EHS-29) Appendix A. • Hazardous Waste – Contingency Plan. Solid and Hazardous Waste Management Plan (SHWMP, Appendix B) Sections 9.0 Contingency Plan and Emergency Procedures and 9.8 Emergency Reporting Procedures. Thatcher will direct all reasonable measures necessary to ensure that fires, explosions, and releases of hazardous waste do not occur, recur, or spread. These measures may include: • Stopping, controlling, or containing the source of the release; • Containing the released materials to minimize spreading; • Eliminating or controlling health and safety hazards; • Collecting and containerizing released material; • Reporting hazardous waste releases as required by R315-263-30; and • Cleaning up and/or treating residual contamination in-place. Phase 3 Material Management Plan June 2022 7 4859-0509-4175\1 3.0 PROJECT DESCRIPTION Following DWMRC approval of this P3MMP, Thatcher will continue with Phase 3 activities. This plan details the methods and procedures to be followed to address Facility wide containers found outside of the lab (Phase 1) and beyond the NWSA (Phase 2). 3.1 PHASE 3 MATERIALS MANAGEMENT PURPOSE The purpose of Phase 3 of this project is to perform a facility-wide review, evaluate the status of all Phase 3 containers, identify available information regarding such containers, and make an appropriate management decision for each container (i.e., disposal or continued storage for use or reuse (recycling) with tracking to demonstrate compliance with Resource Conservation and Recovery Act (RCRA) legitimate recycling requirements in compliance with Paragraph 18.3 of the SCO). 3.2 PHASE 3 MATERIAL MANAGEMENT OBJECTIVES The primary objectives of P3MMP tasks to be completed at the Facility include: • Demonstrate Phase 3 container material management compliance pursuant to Utah Code § 19- 6-101, et seq., and the Used Oil Act, Utah Code § 19-6-701. • Maintain Phase 3 material management records for material handling (i.e., tracking material movement and management practices), disposal, or continued storage for use or reuse (recycling) with tracking to demonstrate compliance with RCRA legitimate recycling requirements and the provisions of the SCO. • Review of the Facility to evaluate the disposition of all Phase 3 containers. • Ensure that all containers are in good condition with no leaks or defects (such as dents or corrosion) that may compromise the integrity of the container and to confirm that the construction of all containers are compatible with the contents. Materials in Containers not in Good Condition and/or materials in containers not compatible with the contents will be repackaged. • Confirm that all materials containers have not exceeded their Department of Transportation expiration dates. • Respond to leaks or spills immediately. • Label all unlabeled Phase 3 containers. • Make hazardous waste determinations pursuant to R315-262-11. • Ship Phase 3 hazardous material designated for disposal within 90 days of the Phase 3 Accumulation Date or request, in writing, an extension of the 90-day time limit demonstrating that the extension is necessary due to unforeseen, temporary, and uncontrollable circumstances . • Complete the project within a “reasonably aggressive” project schedule estimated timeline. • Use best management practices in the management of non-hazardous solid waste and Utah Administrative Code for hazardous waste, universal waste, and/or used oil. • Provide monthly status update reports to the DWMRC of progress completing Phase 3 activities. Phase 3 Material Management Plan June 2022 8 4859-0509-4175\1 In addition to these objectives, a Waste Analysis Plan (WAP) is included in Appendix C, which details the process for collecting material samples from containers requiring characterization, recording field data, and performing laboratory analysis of material samples. 4.0 REGULATORY REQUIREMENTS UDEQ’s DWMRC regulates hazardous waste management. Thatcher’s P3MMP shall be executed in accordance with the SCO and Utah Admin. Code R315-261 through 268 and 273. 4.1 LARGE QUANTITY GENERATOR MATERIAL MANAGEMENT STANDARDS Thatcher’s SHWMP (Appendix B) provides for the Large Quantity Generator (LQG) material management standards and includes the following: 1. Introduction; 2. Description of generator status; 3. Waste analysis and designation with sampling and testing recommendations; 4. Waste container management; 5. Preparedness and Prevention Plan; 6. Satellite and universal waste accumulation areas; 7. Pre-transport and recordkeeping requirements; 8. Hazardous Waste Contingency Plan (required for an LQG); 9. Waste minimization guidelines; and 10. Personnel training. 4.2 MATERIAL ANALYSIS AND DESIGNATION STANDARDS Containers in Phase 3 storage areas will be characterized in accordance with RCRA, statutory standards and the regulations promulgated thereunder. Any business that generates a solid waste is required in accordance with Utah Admin. Code R315-262-11 to make a hazardous waste determination for that material. The generator is required to use the following steps to determine if the waste: • Is excluded from regulation under Utah Admin. Code R315-261-4; • Is listed as a hazardous waste under Utah Admin. Code R315-261-30 through 33; • When tested, exhibits any of the characteristics of a hazardous waste under Utah Admin. Code R315-261-20 through 24; and • Can be is classified under Utah Admin. Code R315-262-11 based on generator’s Phase 3 Material Management Plan June 2022 9 4859-0509-4175\1 knowledge of the hazard characteristic of the waste. Testing of process waste streams are generally referred to as “characteristic tests”. These analyses include ignitability (flash point 140 degrees Fahrenheit [˚F] or below), corrosivity (pH less than or equal to 2.0 or greater than or equal to 12.5), reactivity (unstable, water reactive, potentially explosive, can generate toxic gases, etc.), and toxicity as determined by Toxicity Characteristic Leaching Procedure (TCLP). If the waste is not excluded from regulation and is determined to be a hazardous waste, the generator must refer to Utah Admin. Code R315-261, 264, 265, 266, 268, and 273 for possible exclusions or restrictions pertaining to management of the specific waste. The Land Disposal Restrictions found in part 268 apply to all wastes intended for landfill disposal and incineration (ash residues from incineration are land disposed). Based on the characterization, an appropriate management method (use, recycling, and/or disposal) will be identified which complies with applicable legal requirements and is protective of human health and the environment. Thatcher’s SHWMP (Appendix B) includes a waste analysis and designation plan for Thatcher’s chemical manufacturing processes. The waste analysis and designation standards are the same for P3MMP. 4.3 LEGITIMATE RECYCLING EVALUATIONS Thatcher will evaluate the legitimacy of materials for use or reuse (recycling) pursuant to Utah Admin. Code R315-260-43. Disposition and disposal management methods are detailed in Section 8.5. The following factors will be used in this legitimacy analysis. 1. The Hazardous Secondary Material must provide a useful contribution to the recycling process or to a product or intermediate of the recycling process. The material provides a useful contribution if it: o Contributes a valuable ingredient to the product or intermediate; o Replaces a catalyst or carrier in the recycling process; o Is the source of a valuable constituent recovered in the recycling process; o Is recovered or regenerated by the recycling process; or o Is used as an effective substitute for a commercial product. 2. The recycling process must produce a valuable product or intermediate. The product or intermediate is valuable if it is: o Sold to a third party; or o Is used by the recycler or generator as an effective substitute for a commercial product or as an ingredient or intermediate in an industrial process. 3. The generator and the recycler must manage the Hazardous Secondary Material as a valuable commodity when it is in their control. Phase 3 Material Management Plan June 2022 10 4859-0509-4175\1 4. The product of the recycling process does not contain significant concentrations of hazardous constituents not found in analogous products, or at a significantly higher concentration than found in analogous products, and does not exhibit a characteristic of hazardous waste not exhibited by analogous products. This factor is not mandatory; it is not determinative of the analysis, but it must be considered in the analysis. 5.0 RESPONSIBILITIES The following subsections detail the responsibilities of the applicable parties associate d with implementation of this P3MMP. A P3MMP distribution list is included in Appendix D. These responsibilities are also included on Figure 4 Material Management Process Flow Diagram. Thatcher will inform Clean Harbors that the requirements of this plan t ake precedence over Clean Harbors’ standard operating procedures (e.g., container labeling). 5.1 THATCHER Thatcher will continue to act as the main point of contact and the lead on the project and will direct the contractors during the Phase 3 activities. Thatcher’s P3MMP responsibilities include: • Coordination with UDEQ DWMRC. • Section 6.0 Health and Safety. • Providing facility staff, contractors, and equipment as necessary. • Implementation and oversight. • Section 7.0 Waste Characterization Program. • Section 8.0 Material Inventory and Management. • Section 9.0 Reporting. • Section 10.0 Compliance Schedule. • Signatures for profiles, manifests/bill of lading, etc. 5.2 FIELD SERVICES CONTRACTOR A Field Services Contractor, Clean Harbors, was retained for field execution of Phase 1 and Phase 2 of the WICP. During Phase 3 of the project, Clean Harbors will complete or provide assistance for the following as directed by Thatcher: • Section 6.0 Health and Safety. • Adherence and execution. • Training project management and operations personnel (i.e., safety, foreman, etc.). Training may include the following: o 40-Hour Hazardous Waste Operations and Emergency Response (HAZWOPER) Training. Phase 3 Material Management Plan June 2022 11 4859-0509-4175\1 o Annual 8-Hour HAZWOPER Refresher [29 Code of Federal Regulations (C.F.R.) 1910.120(e)(8)]. o Department of Transportation (DOT). • Additional training beyond the abovementioned required trainings may include, but not be limited to: o First Aid/Cardiopulmonary Resuscitation (CPR) Training (minimum of one on-site); o HAZWOPER Supervisory 8-hour Training [29 C.F.R. 1910.120(e)(4)]; and o Additional training specific to the job being performed (e.g., Fall Protection, Lock Out/Tag Out, Hot Work, Confined Space, etc.). • Assisting with Section 7.0, the Waste Characterization Program. o Record keeping of sampling (i.e., related forms). • Assisting with Section 8.0 Material Inventory and Management. o Container handling and repackaging. • Assisting with Section 9.0 Reporting. • Profile approval and preparation of manifests/bill of lading, etc. 5.3 ENVIRONMENTAL CONSULTANT An environmental consultant, Stantec, has been hired by Thatcher to prepare this P3MMP. Stantec will periodically be on-site during implementation of this P3MMP to audit compliance with the plan and provide technical support. Stantec will complete or provide assistance for the following as directed by Thatcher: • Section 6.0 Health and Safety. • On-site area disposition review and inventory. • Section 7.0 Waste Characterization Program recordkeeping and profiling. • Section 8.0 Material Inventory and Management. • Section 9.0 Reporting. • Performance of P3MMP monthly inspections and record observations, as directed by Thatcher. • Assisting with record management. • As needed, provide technical support if advice is required to resolve field conditions which deviate from those anticipated in this P3MMP. 5.3.1 Electronic Files for DWMRC on SharePoint Site Stantec will provide DWMRC designated representative access to Thatcher’s DWMRC SharePoint data sharing site and upload electronic files for DWMRC. P3MMP files on the SharePoint site include the following: • P3MMP Forms and spreadsheets. • Hazardous waste manifest and Land Disposal Restriction (LDR) Forms. • Hazardous waste profiles. • Laboratory analytical reports • Section 9.1 Monthly Reporting items. Phase 3 Material Management Plan June 2022 12 4859-0509-4175\1 DWMRC requested bill of lading for recyclable materials shipped elsewhere. Thatcher will not ship P3 materials offsite for recycling opting to dispose of recyclable materials which cannot be used at the Facility. 6.0 HEALTH AND SAFETY Clean Harbors’ field staff will perform P3MMP field tasks under a Site-specific health and safety plan included in Appendix E which will include 1) task specific job hazard analysis; 2) hazard prevention and control; 3) personal protective equipment; 4) hazard communication; and 5) safety data sheets. Thatcher will perform tasks under Thatcher’s Health and Safety program. Stantec will perform tasks under Stantec’s hazard recognition and control program. Site-specific health and safety will meet the requirements of Occupational Health and Safety Administration (OSHA) regulations at 29 C.F.R. 1910.120. All field staff will have the appropriate level of Hazardous Waste Operator Training for the P3MMP tasks they perform. Thatcher will be responsible for health and safety oversight of all personnel at the Facility. 6.1 CLEAN HARBORS MATERIAL MANAGEMENT HEALTH AND SAFETY Clean Harbors will provide sampling, container handling, and material management (off-site disposal) support for the project. Clean Harbors will prepare job hazard analyses specific to each task which they will perform. The Health and Safety procedures are evergreen documents and will be updated daily during tailgate meetings as necessary to reflect changed conditions. Clean Harbors’ services may require the use of Level B (supplied air), C, and/or D personal protective equipment as deemed necessary by a competent person. 7.0 WASTE CHARACTERIZATION PROGRAM This section describes the processes which will be followed for Phase 3 characterization of known and unknown materials in containers. Standard material analysis and designation as described in Section 4.2 Material Analysis and Designation will be used. 7.1 APPLICATION OF GENERATOR KNOWLEDGE In 2019, Thatcher contracted with Stantec to provide regulatory support. A material inventory and characterization team evaluated site operations and available information on material in storage to evaluate the field monitoring, on-site, and off-site analyses necessary for material management under health, safety, and/or statutory standards. This team consisted of Thatcher staff who are knowledgeable of Facility processes and waste management practices, Stantec regulatory specialists, and Clean Harbors field service specialists. Clean Harbors’ High Hazard Group was consulted as part of this process. Phase 3 Material Management Plan June 2022 13 4859-0509-4175\1 The types of chemicals used for production, produced product chemicals, and chemicals returned from clients were evaluated. This evaluation included a preliminary review of the chemical production process and laboratory operations. The following conclusions were made from the preliminary review: • Hazardous waste was being generated at the laboratory. • Materials from the chemical production process exhibiting only the characteristic of corrosivity were neutralized and discharged under the discharge permit. • No other hazardous wastes from the chemical production process were identified. Through generator knowledge it was determined that pesticides and herbicides (i.e., TCLP D-list pesticides and herbicides) were not used, and poly-chlorinated biphenyls (PCBs) are not and historically have not been used or stored on-site. On February 12, 2020, Mr. Craig Thatcher was contacted and confirmed that pesticides and herbicides (i.e., TCLP D-list pesticides and herbicides) have not been on-site. Thatcher staff members Mr. Dave Lindsey, environmental health and safety, and Tim Lawton, process engineer, confirmed that PCBs were not on-site. Therefore, analyses for those analyte groups are not included in the characterization program. 7.1.1 Generator Knowledge Used for Characterization of Known Materials Generator knowledge used for characterization of known materials includes the following. • Container labels documented on P3MMP forms and/or spreadsheets. • SDS o If 100 percent of constituents are not identified, additional information will be obtained and tracked in a SDS 100 percent composition spreadsheet included with Appendix G Area Disposition Review Form and Spreadsheet. • If an SDS is not available for the material, a Thatcher production record may be used for Thatcher products. 7.2 APPLICATION OF FIELD SCREENING AND ANALYSIS FOR MATERIAL CHARACTERIZATION Materials in containers will be characterized under the standards described in Section 4.2 Material Analysis and Designation. Management options may include use/reuse (recycling) in the production process, and/or disposal. Thatcher has contracted with Stantec to coordinate material analysis and designation (characterization) with Clean Harbors based on Section 4.2 Material Analysis and Designation Standards. These standard characterization methods include field screening and off-site laboratory analyses as detailed in the WAP included in Appendix C. Phase 3 Material Management Plan June 2022 14 4859-0509-4175\1 The following is the characterization program developed by Thatcher’s project team. The characterization program will include field screening and analyses (off-site labs). The characterization program is based on field screening data and pH determinations for the categories as described in the WAP and Container Tracking and Disposal Spreadsheets. The characterization program is as follows: • Field screening. • Off-site lab pH confirmation. • Category evaluation as described in Table 2. Additional laboratory analysis will be performed as necessary, based upon field screening, to characterize Phase 3 material. The field screening, sampling, and analyses steps are detailed in Table 2. Table 2 Field Screening, Sampling, and Analyses Steps Step Descriptions Comments Field Screening Clean Harbors completes field screening, field screening forms, enters the data on the Container Tracking and Disposal Spreadsheet, and uploads field forms to the SharePoint site. Stantec completes a quality assurance review of the forms and data entry. Clean Harbors Sampling1 and Lab Analyses Off-site: Samples are obtained for – Analyses of: 1. pH, 2. TCLP RCRA 8 Metals and Underlying Hazardous Constituent (UHC) Nickel, 3. Flash Point, 4. TCLP VOAs/Semi-VOAs and UHC methanol (non-wastewater), and/or 5. UHC Total VOAs Methanol (wastewater) and Xylene 6. Total sulfide or cyanide if detected from field monitoring Yes (Y) or No (N) If field screening for sulfide or cyanide is negative, the samples are not analyzed for these parameters. 1Chemtech-Ford Laboratories (CTF) analyzes pH and enters data in the Container Tracking and Disposal Spreadsheets. Stantec completes a pH quality assurance review to ensure the corr ect category is designated for CTF analyses determinations (i.e., P3MMP spreadsheet auto populates with a “Y” (Yes) in the category column). This category is dependent on the following: • Off-site lab pH analyses. • Field screening parameters . Phase 3 Material Management Plan June 2022 15 4859-0509-4175\1 8.0 PHASE 3 MATERIAL INVENTORY AND MANAGEMENT Thatcher is prepared to initiate the Phase 3 Inventory and Management following DWMRC approval of the P3MMP. Container inspections have been completed weekly and a Baseline Preliminary Inventory was performed during the preparation of this P3MMP. A material inventory and management flow diagram is included in P3MMP Figure 4. This diagram summarizes the P3MMP decision making process for Phase 3 containers. 8.1 PHASE 3 BASELINE PRELIMINARY INVENTORY DWMRC informed Thatcher that a Phase 3 inventory was required prior to continuing Ph ase 3 to provide assurance that the total number of Phase 3 containers does not change as the project progresses. Phase 3 as initially started with Batch 1 and a total of 103 containers were inventoried, with 70 containers disposed, and 33 containers identified as commercial chemical product for recycling. Thatcher dispersed the 33 commercial chemical product containers to other areas . These containers are included in the Baseline preliminary inventory and Phase 3 continuation. The term “batch” was applied to the first area where container disposition management determinations were made prior to preparation of this plan. Baseline preliminary inventory of containers in Phase 3 areas 1 through 14 (Figure 3) were numbered as follows: Area (A), such as Area 1 (01), and container number (001) (e.g., A-01-001). Thatcher inspected the 14 areas and completed the area’s baseline preliminary inventory. During the area’s baseline preliminary inventory, labels were assigned to 1,003 containers and/or pallets (e.g., bags of same materials). If it was determined that container ar ea numbers were assigned to containers with disposition numbers or materials not within the Phase 3 pre-November 2019 timeline they were removed from the list; therefore, area numbers may not be consecutive. Thatcher’s pre-existing trailer inventories (area 12) were used for trailer container inventory (1,177 containers); therefore, area numbers were not assigned and containers in trailers were not labeled with assigned numbers. Containers on the disposition inventory (531 containers) have assigned disposition numbers. Total Phase 3 containers from the baseline inventory of the 14 areas (1,003), trailers (1,177), and disposition list (531) is 2,711. 8.2 INSPECTIONS The 90-day hazardous waste storage and Phase 3 areas are inspected on a weekly basis. Copies of blank inspection forms are included in Appendix F. Completed copies of 90-day storage area inspection forms are maintained by Thatcher. Phase 3 Material Management Plan June 2022 16 4859-0509-4175\1 8.3 MANAGEMENT OF “CONTAINERS NOT IN GOOD CONDITION” Beginning on October 22, 2021, Thatcher observed all Phase 3 containers weekly to identify Containers not in Good Condition. Weekly area inspections have been documented by area managers and since initiating this inspection program, four containers requiring repackaging have been identified and managed. Regular area monitoring and inspections are ongoing and will continue through Phase 3; examples include the following: • Weekly inspections of Phase 3 areas and maintenance of inspection records. • Thatcher conducts regular work area inspections and addresses Containers not in Good Condition as necessary. • Employees that identify Containers not in Good Condition during daily operations follow company container management and/or reporting guidelines (see Section 2.3 Emergency Response). • Thatcher employees respond to incidents according to the plan applicable to the materials released (i.e., hazardous waste and/or hazardous material) and training received. During inspections, containers found to be Containers not in Good Condition will be repackaged prior to moving the containers for storage in the NWSA and will be managed for disposal. Thatcher immediately addresses (i.e., repackages per Section 8.6.4 Container Repackaging) any containers that pose an imminent threat. Any spill or release of material (newly generated), including raw materials or product, will be immediately cleaned up. If a spill is detected that is not immediately cleaned up or is mixed with another material, soil, or precipitation/run-off, it is considered waste which will be containerized for management as newly generated. Any container that is not in good condition which contains material that exhibits a characteristic of, or is a listed hazardous waste, and containers for which insufficient information is available to make a hazardous waste determination, shall not be recycled or reworked and must be managed for disposal. Containers with newly generated waste will be dated with the date the material is first placed in the containers. 8.4 PHASE 3 CONTAINER AREA REVIEW AND MANAGEMENT DETERMINATIONS This section describes the processes which will be followed for the review of the Facility and inventory of material containers during Phase 3 of the project. Thatcher has designated 14 Phase 3 container management areas as shown on Figure 3. Material management decisions can proceed concurrent with the area disposition review. Management decisions for Phase 3 containers will include use/reuse (recycling) in the production process, and/or disposal. Facility-wide review will be completed to gather information needed to facilitate efficient management decisions. The container area disposition review Phase 3 Material Management Plan June 2022 17 4859-0509-4175\1 will include Area 1 through Area 14 as shown in Figure 3. Thatcher knowledgeable staff will work with Stantec to identify and track the containers with area disposition review forms and spreadsheets (see Section 8.4.1). Each Phase 3 container will be assigned a tracking number. Containers observed not to be in good condition will be immediately addressed as detailed in Section 8.2 Management of “Containers not in Good Condition”. Container disposal is detailed in Section 8.8, Disposal Forms and Tracking Spreadsheets, and the disposition process is detailed in Section 8.5.3. A material inventory and management flow diagram is included in P3MMP Figure 4. This diagram summarizes the P3MMP decision making process for Phase 3 containers. 8.4.1 Area Disposition Review Forms and Spreadsheet The Area Disposition Review Form will be used to track information collected during the disposition process (disposal or disposition) and is included in Appendix G. Disposal numbering started with Batch 1 containers 1511-1542. The term “batch” was applied to the first area where container disposition management determinations were made prior to preparation o f this plan. The container numbering used in the form and/or spreadsheets is as follows. • Consecutive “by area” tracking numbers will be assigned to Phase 3 containers managed for disposal or disposition. ▪ Phase 3 containers will be numbered as follows Area (A), such as Area 1 (01), and container number (001) (e.g., A-01-001). ▪ Disposition (recycling) containers will have “(R)” added to the end of the number (e.g., A-01-001 (R)). Some containers with materials intended for recycling may have an existing disposition number which has been tracked previously on a list maintained by Thatcher. These containers will be labeled as either “Phase 3 Recyclable Material – CCP” or “Phase 3 Recyclable Material, Non-CCP Pending Approval from the DWMRC” based on the contents of the container. These containers will be migrated to the disposition spreadsheet, will receive a disposition number (e.g., A-01-001 (R))) and will be labeled for hazard type in accordance with the Globally Harmonized System of classification and labeling of chemicals. The Area Disposition Review Spreadsheet included in Appendix G is used to track area disposition review determinations by each Area (disposal or disposition) for Phase 3 containers. A new Area Review Disposition Spreadsheet will be started when transitioning to a new Area. The Repackaging Form described in Section 8.5.3.1 will be used if containers require repacking for movement (i.e., Containers not in Good Condition). 8.5 DISPOSITION AND/OR DISPOSAL MATERIAL MANAGEMENT Area disposition review and container management will be limited to the number of containers requiring disposal that will fit into the NWSA secondary containment (i.e., phased approach with an estimated maximum of 50-containers in the NWSA at any one time). Thatcher knowledgeable staff will work with Stantec to identify and track the containers. Each container not identified as “active inventory” designated Phase 3 Material Management Plan June 2022 18 4859-0509-4175\1 for disposition or disposal will be assigned a tracking number as described in Section 8.4.1. Container condition and immediate action determinations will be addressed. Thatcher will manage containers identified for disposition that will be left in the area or moved to another area for storage for use and tracked on the disposition spreadsheets. Clean Harbors will contain and cleanup any leaking or spilled material identified during movement from the process or container storage area to the NWSA and will follow Thatcher emergency response plan requirements. Container trailers will be moved to the NWSA by Thatcher and unloaded by Clean Harbors and/or appropriately trained Thatcher staff. Clean Harbors and/or Thatcher will move repackaged containers pending disposal to the area directly outside of the NWSA east fence line. The NWSA secondary containment is lined with high density poly-ethylene sheeting (HDPE), is open sided, and has a roof that mostly covers the area. Storm water in the secondary containment is collected for management. The area directly outside of the NWSA east fence line will be utilized for storage of repackaged containers pending disposal which will provide room in the NWSA secondary containment to accelerate the project schedule. Secondary containment for this area consists of asphalt and concrete surfaces with storm water draining towards the facilities’ storm water treatment system. Once there is sufficient room in the NWSA secondary containment area, disposition review and container management will continue in order to meet “reasonably aggressive” project schedule objectives. When containers in the NWSA are characterized and repackaged/overpacked (as necessary) they can be moved t o the east of the NWSA fencing for temporary storage until a disposal shipment is arranged. Containers will be labeled as detailed in Section 8.6.3, Container Labeling. Once assigned a date, Thatcher intends to manage containers designated for disposal as universal waste, and/or hazardous waste containers within 90 days of the Phase 3 Accumulation Date. If hazardous waste containers will exceed the 90-day time limit, Thatcher will request in writing an extension of the 90-day limit, demonstrating that the extension is necessary due to unforeseen, temporary, and uncontrollable circumstances . Use or reuse (recycling) is summarized in Section 8.4.1. Used oil will be managed using Thatcher’s existing used oil management practices. Universal waste will be managed in accordance with the requirements of R315- 273. A flow diagram detailing the material management process is included as Figure 4. 8.5.1 Known Phase 3 Hazardous Secondary Materials Identified for Disposition Commercial Chemical Products are both listed commercial chemical products as defined in 40 C.F.R. § 261.33 / R315-261-33 and non-listed commercial chemical products which EPA defines as including all types of unused commercial products, including off-specification species of the same, that exhibit a characteristic of hazardous waste. See 50 Fed. Reg. 14219 (April 11, 1985). 8.5.1.1 Known Material Identified for Disposition (Use or Reuse (Recycling)) A “known material” identified for disposition is identified by label, SDS (Thatcher products or other CCPs), and/or Thatcher tracking number (e.g., lot number, product number, etc.). Known Phase Phase 3 Material Management Plan June 2022 19 4859-0509-4175\1 3 CCPs shall be evaluated for use or reuse (recycling) within one year of the material’s Phase 3 Accumulation Date. Hazardous CCP containers not used within the one-year time period will be transferred to the LQG storage area and disposed of within 90 days. Known non-CCP Phase 3 Hazardous Secondary Materials are not anticipated. If and when these types of materials are identified Thatcher will provide the proposed recycling scenario information to DWMRC. Non-CCP Phase 3 Hazardous Secondary Materials may only be recycled with the express written authorization of DWMRC. Any non-CCP Phase 3 Hazardous Secondary Material authorized for recycling, but not used within nine months of the Phase 3 Accumulation Date, will be transferred to the LQG storage area and disposed of within 90 days. Section 4.3 legitimate reuse/re-working scenarios will be provided for known non-CCP Hazardous Secondary Materials for DWMRC approval. While awaiting the DWMRC decision on the request to recycle non-CCP Phase 3 Hazardous Secondary Materials, the containers will receive a disposition number; however, the containers will be stored in the NWSA until approved for recycling. If the material is not approved for recycling, it will be managed as hazardous waste and managed in accordance with Section 8.5.3.1. Known non-CCP Phase 3 Hazardous Secondary Materials recycling s cenario information will include the following. • Hazardous determination (i.e., would exhibit hazardous waste characteristics or be a listed hazardous waste if disposed). • Non-CCP hazardous secondary material is designated by Thatcher’s technical services as “assigned in use” in the regular SharePoint disposition process. Thatcher Production Planning creates an inventory under generic item number Disposition Material (DISP MTRL) for approved rework disposition materials in the central Enterprise Resource Planning (ERP) system Infor/M3 (software), assigning the Disposition number (DXXXX) as the M3 Lot number. Production Planning and Technical Services will collaborate to add “DISP MTRL” item by Lot (Disposition number) into finished goods batches to the M3 Bill of Materials for that Manufacturing Order (MO). Through basic functionality of the M3 ERP system, Lot tracing will provide historical usage of these “DISP MTRL” items including the following data points: Lot number (Disposition number), Item, date used, qty used, operator name that reported production, finished product created, among others. This information is stored in the M3 database indefinitely and can be accessed at any time. Phase 3 Material Management Plan June 2022 20 4859-0509-4175\1 8.5.2 Material Identified for Disposal 8.5.2.1 Known Material Identified for Disposal A “known material” identified for disposal is identified by label, SDS (Thatcher products or other CCPs), and/or Thatcher tracking number (e.g., lot number, product number, etc.). If information is not conclusive for profiling the material for disposal, it will be managed as an unknown. 8.5.2.2 Unknown Material Identified for Disposal An “unknown material” will be evaluated for disposal using the characterization process as detailed in Section 7.0. 8.5.3 Material Management Disposition Forms and Spreadsheets 8.5.3.1 Disposal Forms and Tracking Spreadsheets Forms used to track container information include a Field Screening Form (Appendix H) and a Repackaging Form (Appendix I). The Container Tracking and Disposal Spreadsheets are included in Appendix J. This spreadsheet is used to track area containers, track sampling, characterization, profiling, and disposal information. Stantec will upload the spreadsheet to the Thatcher UDEQ DWMRC SharePoint site monthly when the monthly report is submitted. The process of field screening, sample collection and analysis, and material characterization is detailed in the WAP (Appendix C). 8.5.3.2 Disposition Tracking Spreadsheet The Disposition Tracking Spreadsheet is included in Appendix K. This spreadsheet is used to track Phase 3 container recycling (use, or reuse), or disposal determinations. 8.6 CONTAINER MANAGEMENT The procedures proposed to physically manage the Phase 3 containers are detailed below. 8.6.1 Management of Containers Posing Imminent Threat See Section 8.3 Management of Containers not in Good Condition. 8.6.2 Management of Containers Spilled During Transport See Section 8.3 Management of Containers not in Good Condition. Phase 3 Material Management Plan June 2022 21 4859-0509-4175\1 8.6.3 Container Labeling All containers will retain either the disposal number or the disposition (recycling) number assigned during the area disposition review process as detailed in section 8.4.1. If a container is repackaged or overpacked, the disposal or disposition number will be transferred to the new container. Containers with unknown contents which require disposal will be labeled “hazardous waste” and “on test” with the inventory date as the Phase 3 Accumulation Date, unless the actual accumulation date can be determined. If the actual accumulation date is known, the container will be labeled with both the actual accumulation date and the Phase 3 Accumulation Date. Containers requiring disposal with known contents will be labeled as either hazardous or non-hazardous waste. Containers designated for disposition (recycling or disposal) will be labeled with the Phase 3 Accumulation Date as the accumulation date unless a prior accumulation date can be determined, in which case both dates will be indicated on the label. In addition to the hazardous waste label, once hazardous characterization information is obtained, Department of Transportation (DOT) hazardous class labels will be applied to the containers for identifying hazardous characteristics (e.g., DOT corrosive hazard class for RCRA characteristic of corrosivity). Containers will also be labeled as described above when material is repackaged. 8.6.4 Container Repackaging Container repackaging includes overpacking and/or transfer of materials to a container in good condition by trained staff. Container condition will be inspected as described in Section 8.2. Containers will be closed except when removing or adding material. Containers will be repackaged in areas with secondary containment and will have spill response materials readily available. Temporary secondary containment will be established (e.g., plastic sheeting with berms) in areas without secondary containment for management of damaged/leaking containers. Containers will be overpacked by manual or mechanical means. Transfer of materials from one container to another will be by manual methods (e.g., containers emptied form one container to another using valves and funnels), or mechanical (pumps) means. Non-sparking tools will be used for containers with ignitable materials and bonding and grounding will be used when transferring material which could generate friction (e.g., pumping). Container tracking numbers will be transferred to the new container(s). If contents from large containers are repacked in smaller containers (e.g., 275-gallon tote to 55-gallon drums) an alphabetical character, (e.g., 1543A and 1543B etc.) will be added to the number. If same material from small containers are consolidated in larger containers (not bulked) (e.g., 5-gallon pails in 55-gallon drums), all small container numbers will be tracked on the new larger container. Phase 3 Material Management Plan June 2022 22 4859-0509-4175\1 8.6.5 Container handling Closed containers may be moved by manual (personnel and drum handling equipment) or mechanical (forklift, drum handling equipment, transport vehicles) means. Manual drum handling equipment includes cart, dolly, pallet, and/or pallet jack. Mechanical drum handling equipment includes drum mover attachment and lifting devices. Loads will be secured on transport vehicles when necessary. Containers designated for disposal will be moved to the NWSA secondary containment. Containers designated for disposition will remain in the area or be moved to another area for management. 8.6.6 Empty Container Management Containers will be emptied by using standard practices commonly employed for the material and container type (e.g., pouring, pumping, and aspirating) and in accordance with Utah Admin. Code R315-261-7: • No more than 2.5 centimeters (one inch) of residue remains on the bottom of the container or inner liner; • No more than 3 percent by weight of the total capacity of the container remains in the container or inner liner if the container is less than or equal to 110 gallons in size ; or • No more than 0.3 percent by weight of the total capacity of the container remains in the contain er or inner liner if the container is greater than 110 gallons in size. • Containers that have held acute hazardous wastes must be rinsed or cleaned per Utah Admin. Code R315-261-7(b). Acute hazardous waste constituents can be determined by comparing label/SDS constituents’ sole active ingredients, or hazardous waste from non-specific sources to acute hazardous waste listed in Utah Admin. Code R315-261-31 or 261-33(e). • Containers that have held acute hazardous waste will be rinsed with the appropriate reagen t before being discarded. RCRA-empty small containers are discarded in the trash or managed as scrap metal when empty. Large containers are recycled to the vendor, reused, managed as scrap metal, crushed, cut in half (plastic), and/or thrown in the trash. 8.7 WASTE STORAGE PROCEDURES Stantec, on behalf of Thatcher, developed a comprehensive SHWMP, dated August 31, 2020. The SHWMP (Appendix B) was prepared in accordance with Utah Admin. Code R315, 262 through 265. SHWMP Section 4.0 details preparedness and prevention for an LQG and describes practices for hazardous waste storage areas management. Thatcher intends to comply with all the LQG requirements for 90-day and satellite accumulation hazardous waste storage areas. This plan applies to the 90-day and satellite accumulation hazardous waste storage areas located at the Facility. The area directly outside of the NWSA east fence line will be utilized for storage of repackaged containers pending disposal which will provide room in the NWSA secondary containme nt to accelerate the project schedule. Phase 3 Material Management Plan June 2022 23 4859-0509-4175\1 8.8 WASTE DISPOSAL SHWMP Section 8.0 Pre-Transport Requirements and Record Keeping was prepared in compliance the requirements of the hazardous waste regulations detailed in Utah Admin. Code 262-20 through 27, 30 through 35, and 40 through 44 for a LQG. Thatcher intends to comply with all the LQG requirements for disposal in preparing hazardous waste for shipment off-site and for the proper maintenance of records regarding these shipments. 8.9 DECONTAMINATION PROCESS Newly generated investigation-derived wastes (IDW) generated during this work include used Personal Protection Equipment, used disposable sampling equipment, paper shipping waste, and decontamination materials. Potential characteristic or listed hazardous waste decontamination materials will be containerized, characterized, classified, and disposed of according to regulatory requirements. All containers of potentially hazardous waste IDW generated pursuant to the P3MMP will be labeled to identify their contents and left in safe locations at the site for eventual disposal (pending analyses). All IDW wastes that did not contact sample materials or other site wastes will be handled as solid waste. 9.0 REPORTING 9.1 MONTHLY REPORTING Thatcher will prepare and submit P3MMP reports to the DWMRC on or before the 15th day of each month until P3MMP is completed. Reports will include a written project description and the following. • Number of containers, by area, processed. • Number of containers moved to the NWSA. • Number of containers repackaged. • Number of containers sampled and characterized. • Number of containers disposed as hazardous waste and non-hazardous waste. • Number of containers retained for reuse, container number, date. • A copy of the inventory forms and spreadsheet created for the area. • Inspection forms with description of cleanup of any leak or spill material identified during the P3MMP process. The monthly report format is included in Appendix L. Phase 3 Material Management Plan June 2022 24 4859-0509-4175\1 10.0 COMPLIANCE SCHEDULE 10.1 COMPLIANCE SCHEDULE The Phase 3 material management process will continue within 30 days of receipt of DWMRC approval of this P3MMP. The schedule for completing Phase 3 of this project will be dictated by the storage capacity of the NWSA, which can accommodate containers as follows: • Secondary containment approximately 50 containers, and • Approximately 500 repackaged containers within the fenced area. Thatcher anticipates that the initial area disposition review process for each area will take several days (estimated 1.5-weeks) at the end of which a disposition management decision will have been made for each Phase 3 container in the area. Once the area disposition review has been completed, the containers will be processed in accordance with the disposition management decision made as detailed in Section 8.4. Materials in containers will be sampled and characterized under the standards described in Section 4.2 Material Analysis and Designation and Section 7.2 Application of Field screening and Analysis for material characterization (estimated 3-weeks). Management options may include use/reuse (recycling) in the production process and/or disposal. Materials in Containers not in Good Condition, in containers not compatible with the contents, or not meeting DOT standards will be repackaged. Containers will be labeled as described above when material is repackaged. Repackaging and preparation for shipment is estimated to require 4 weeks. Analyses data and material/waste profile submission will be completed (estimated 1.5 weeks). Profile approval is estimated at 2-weeks. Thatcher’s “reasonably aggressive” compliance is based on the following. Thatcher estimates 12 weeks (84 days)4 to process 50 containers for management in the NWSA, with an estimated 2,711 containers that must be processed for management. DWMRC informed Thatcher on March 3, 2022 (via email) that the NWSA area inside the fence line can be used for storage of repackaged containers. This will provide the capability to process an estimated 50 containers every week. Therefore, the estimated schedule for managing 2,711 containers is 1 year 3 months. Use or Reuse (Recycling) Schedule Hazardous CCP containers not used within the one-year period from the Phase 3 Accumulation Date will be transferred to the LQG storage area and disposed of within 90 days. For those Hazardous Secondary Materials which are not CCPs and which have been approved, in writing, for recycling by DWMRC must 4 This estimate includes six days of contingent time for unforeseen delay or unanticipated conditions. Phase 3 Material Management Plan June 2022 25 4859-0509-4175\1 be used within 9 months of the material’s Phase 3 Accumulation Date. If not used within 9 months, the containers will be transferred to the LQG storage area and disposed of within 90 days. Phase 3 Material Management Plan June 2022 26 4859-0509-4175\1 11.0 REFERENCES Stantec Consulting Services, Inc, Waste Inventory and Characterization Work Plan. March 20, 2021 Utah Division of Waste Management and Radiation Control, Stipulation and Consent Order No. 2102006. dated effective December 9, 2021 Utah Admin. Code R315-261 through 268 and 273. Department of Transportation labeling 49 CFR part 172. Occupational Safety and Health Administration standard 29 CFR 1910.1200. Thatcher Phase 3 Materials Management Plan (to the P3MMP) – Response to Comments Letter. June 03, 2022 FIGURES Step 2: P3MMP Section 8.2 Management of Containers Not in Good Condition - Evaluation (Thatcher and Stantec responsibility) Is container damaged/ leaking? Yes Take immediate action. 1. Address spill or release - Record keeping Section 2.3.1. 2. Repackage container - Record Keeping "Repackage Form". (Thatcher and/or Clean Harbors responsibility) Go to Step 5 for Disposal No Step 3: Section 8.4 Disposition (Step 4) or Disposal (Step 5) Material Management. 1. Use, reuse, or disposal - record keeping is the Material Management Disposition Forms and Spreadsheets (8.4.3.2). (Thatcher and Stantec responsibility) Is container a "known material CCP or non-CCP" - Record keeping is label, safety data sheet, and or Thatcher tracking number. (Thatcher and Stantec responsibility) Yes Step 4: Section 8.4.1 Known Commercial Chemical Products (CCP) and Non-CCP - Evaluate for use or reuse (recycling). Can material be used or reused? (Thatcher and Stantec responsibility) Yes Is container hazardous CCP or non-CCP? (Thatcher and Stantec responsibility) DWMRC approal for use is required for hazardous non-CCP. Yes Has container been used or reused (recycled) 1. CCP within one year? 2. Non-CCP within 9-months? (Thatcher and Stantec responsibility) Yes No further action required. No No go to Step 5 No No go to Step 5 Step 5: Section 8.4 Disposal and 8.4.2 Material Identified for Disposal 1. Known (8.4.2.1) or unknown material (8.4.2.2) identified for disposal. 1a. Evaluate/ characterize for disposal - Record keeping is the Disposal Forms and Tracking Spreadsheets Section 8.4.3.1. 2. Responsibilies a. Thatcher and/or Clean Harbors will move continers to the NWSA. b. Clean Harbors container handling, repackaging, sampling, and related forms. c. Thatcher and Stantec recordkeeping management. 1. Use or Reuse management tracked on Disposition spreadsheet. 2. Disposal go to Step 5. Step 1: P3MMP Section 8.3 - Project team select storage area for material management from the 13 designated storage areas. Inspect one storage area completely before moving on to additional storage area(s). Record keeping is the Area Disposition Review Form and Spreadsheet Section 8.3.1 (Thatcher and Stantec responsibility). Notes: 11. Phase 3 under the Stipulated Consent Order begins with disposal container #1543 and recycling #R001. 2. P3MMP Section 8.1 Inspections: Areas are inspected weekly by Thatcher. Record keeping is the weekly inspection forms. 3. Monthly Reports Section 9.1: Thatcher and Stantec responsibility. 4. Records will be maintained on SharePoint by Stantec. 1Consecutive tracking numbers will be assigned to Phase 3 containers managed for disposal starting at 1543 the next consecutive tracking number after Phase 3 Batch Area 1 (containers 1511-1542) and disposition starting at R001. The term “batch” was applied to the first area where container disposition management determinations were made prior to preparation of this plan. Containers identified as known with the same contents are assigned the tracking number and an alphabetical character, e.g., 1543A and 1543B etc. FIGURE 4 Thatcher P3MMP Material Management Process Flow Diagram APPENDIX A Thatcher Emergency Response Program (Hazardous Materials Emergency Action Plan EHS- 13) and Standard Operating Procedure (SOP) Environmental Health and Safety (EHS-29) EMERGENCY RESPONSE PROGRAM PAGE: 2 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 2.0 DEFINITIONS 2.1 California Code of Regulations (CCR)—the State of California code for regulatory compliance that are equivalent or more stringent than the comparable Federal (OSHA) regulation. 2.2 CAL/OSHA—state of California’s Occupational Safety and Health administration. California is one of many states with an OSHA approved State Plan. 2.3 Catastrophic Chemical Spill/Release—the emergency is beyond the ability of Thatcher HazMat personnel and will only be controlled with the assistance of outside agency intervention. The public will be affected. 2.4 CHEMTREC—The Chemical Transportation Emergency Center operated by the Chemical Manufacturers Association in Washington D.C. 2.4.1 For domestic shipping (within the U.S.) call: 1-800-424-9300, Customer Number: 22106 2.4.2 For Canada call Canutec (613-996-6666), Customer number: 22106 2.4.3 For international (outside of the U.S.) call: 703-527-3887, Customer number: 22106 2.5 CHLOREP—the basic description of the chlorine industry's response procedure as set forth in the document titled, "Chlorine Emergency Plan (CHLOREP)." 2.6 DOT—the United States Department of Transportation. 2.7 EMERGENCY—aAny incident involving a chemical which creates a potential or actual public hazard. 2.8 ERT (Emergency Response Team)—a team consisting of a team leader and one or more team assistants to handle the emergency. (HazMat team members are all 40 hour HAZWOPER trained.) 2.9 EPA—the United States Environmental Protection Agency. 2.10 HazMat Refresher—eight (8) hour Hazardous material training once a year known as HAZWOPER. 2.11 HAZWOPER—the required training course method for HazMat teams (29 CFR 1910.120). 2.12 International Fire Code (IFC)—Fire Code superseding 1997 Uniform Fire Code (UFC)—a new version of this regulation was release in January 2012 and every three years afterwards. 2.13 Major Chemical Spill/Release—there is a strong possibility the chemical will leave the property and a chance someone can be injured as a result of the incident. The public will be affected. 2.14 Minor Chemical Spill/Release—can be controlled by immediate personnel but a page is conveyed to the Thatcher HazMat Team. This will allow the team to prepare, in the event the condition becomes moderate. The public will not be affected. 2.15 Moderate Chemical Spill/Release—under the direction of the Plant Manager, the emergency can be controlled on property. Thatcher HazMat Team members are required to respond in order to contain the chemical, but injuries resulting from the incident are non-existent. The public will not be affected. 2.16 NAC—Nevada Administrative Code. 2.17 Notification—the NRC shall be notified immediately when an unauthorized discharge becomes reportable under state, federal, or local regulations. 2.18 NRC—National Response Center. The 800-424-8802 number may be called 24 hours a day and the operator will submit a report to the various agencies. Calls to the Fire Department, and State EPA will still need to be made. EMERGENCY RESPONSE PROGRAM PAGE: 3 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 2.19 OSHA—the Occupational Safety and Health Administration, as instituted by the OSH Act of 1970, which created the numerous federal laws which employers, must follow to ensure employee safety. 2.20 Release of Hazardous Materials—hazardous materials shall not be released into a sewer, storm drain, ditch, drainage canal, lake, river, or tidal waterway, or upon the ground, sidewalk, street and highway, or into the atmosphere. 3.0 EMERGENCY ACTION PLAN (EAP) VS EMERGENCY RESPONSE PLAN (ERP) 3.1 EAP—an emergency action plan (EAP) is a written document required by OSHA standards 29 CFR 1910.38(a). The purpose of an EAP is to simplify and organize employer and employee actions during workplace emergencies. Emergency Action Plans and proper employee training (ensuring employees understand their roles and responsibilities within the plan) will result in fewer and less severe employee injuries and less structural damage to the facility during emergencies. 3.2 The EAP is designed to be the pre-planning phase of an incident/accident; it is the steps taken by Thatcher Company to prepare for, and have a plan in place, to respond to all types of accidents/incidents. This planning may include, but is not limited to 3.2.1 Creating an Emergency services—call list, 3.2.2 Creating and coordinating with List of hospitals and doctors, 3.2.3 Creating an Employee Call List (important phone numbers) 29 CFR 1910.38(c)(6), 3.2.4 Designating HazMat Team responsibilities, 3.2.5 Determining evacuation routes and practicing evacuation drills, 3.2.6 Determining Shutdown procedures for those who will remain behind during an incident to properly shut down facility equipment and processes, and 3.2.7 Determining average employee responsibilities. 3.3 ERP—after an incident/accident has occurred, the first priority is always the preservation of life. The second priority is the stabilization of the incident/accident. The actions taken to make a situation better once the incident/accident has occurred are the response plan. The best way to handle these incidents is to plan, train, and have designated responsibilities for them. These responsibilities may be broken down into groups or individually and may include 3.3.1 Evacuating in an orderly manner to the primary or secondary evacuation point—as directed 3.3.2 Performing assigned task (HazMat Team members only) 3.4 Activation of the Emergency Response Plan (ERP) will be at the discretion of those involved in the incident (onsite personnel), anytime they feel outside help is needed 911 will be called. 3.5 As with all Thatcher Company Standard Operating Procedures (SOPs), this SOP must be updated, or reviewed/validated at least annually for applicability. A new revision number will indicate the SOP has been updated, or a separated review/validation sheet attached to the SOP will indicate the SOP has been reviewed/validated on the date indicated on the form. EMERGENCY RESPONSE PROGRAM PAGE: 4 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 4.0 PRE-EMERGENCY PLANNING AND COORDINATION WITH LOCAL FIRE DEPARTMENTS, EMERGENCY MEDICAL PERSONNEL, AND THE L.E.P.C. 4.1 Many State and local governments have programs in place to periodically complete local fire department’s pre-incident inspections. Such inspections have been done to familiarize the fire departments with the facility layout, its general operation, the different types of chemicals, and their location around the facility. Any local fire department wishing to do so has an open invitation for these inspections. Since Thatcher Company does not manage these entities we cannot assume when they will accept the offer to train onsite; however, we anticipate training to be offered at least annually. When training and coordination of this nature takes place, Thatcher Company Personnel will take minutes from these meetings and maintain a record of the fact emergency responders have seen this SOP and have knowledge of on-site capabilities and expectations. Minutes need not be recorded on any special form but must be attached at the end of this SOP. Topics of discussion, requirements, and recommendations from off-site emergency responders will also be recorded 4.2 These pre-incident inspections are an essential part of Thatcher Company’s emergency response plan. They allow Thatcher Company to work with fire fighters in an emergency to preserve life and property. Together we will be able to respond efficiently and effectively to emergencies and/or unauthorized releases (see EHS-29). 4.3 EMERGENCY RESPONSE: If OSHA considers a worksite response activity a "HAZWOPER Emergency Response," then employers with employees at the site performing emergency response must comply with HAZWOPER paragraph (q) and all other General Industry (29 CFR 1910) standards. The term "emergency response" has a very specific meaning and application under HAZWOPER. Employers often apply this term to any activity requiring immediate attention. However, under HAZWOPER this term applies specifically to response activities where there is an uncontrolled release of a hazardous substance, as defined by HAZWOPER in paragraph (a) (3), or where an uncontrolled release is likely. Thatcher Company HAZWOPER trained employees (HazMat Team) are also trained in First Aid and CPR; as such, they are the ONLY designated company personnel that can, and may, respond in an emergency situation— all non-HazMat employees will evacuate the facility and are NOT authorized to assist in any manner of medical duties. 4.4 In the event of an emergency or unauthorized release the Facility Incident Commander (FIC) will take charge of the situation. The FIC for Thatcher Company will be the senior HazMat (emergency response) team member onsite at the time of the incident. 4.5 Emergency Medical Teams—the medical facility handling any emergency situation for major injuries involving one or more people will be the hospital listed in EHS-13F6. Any medical teams responding to the facility will be advised of any potential hazards that still exist as well as decontamination procedures that need to be followed. 4.6 Local Emergency Planning Community (LEPC)—a copy of this emergency response plan, a map of the facility, and a copy of the hazardous materials inventory will be made available to the LEPC upon request. Check your local regulations on this matter, many areas require the LEPC be given this information, and other local groups such as the NDEP CAPP have access to this information. 4.7 A complete list of chemicals is available through the onsite Hazardous Materials Identification System (HMIS) and through Safety Data Sheets (SDS)—both are available upon request. 4.8 Important phone numbers and emergency numbers will be posted near all phones and on employee information boards—the forms that may be posted are the forms associated with this SOP (EHS-13F1, EHS-13F2, EHS-13F4, and EHS-13F6). EMERGENCY RESPONSE PROGRAM PAGE: 5 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 4.9 Employee responsibilities are broken down into two groups: first, those who are part of the HazMat (emergency response team) and secondly, everyone else. Only HazMat team members are permitted to respond to emergencies of any nature—all other employees evacuate to their designated evacuation locations as specified in the SOP. HazMat Team members (members listed in EHS-13F2) will act as incident command stricter as specified in section 11 of this SOP until such times as they are relieved by local, state, or other governmental authorities. 4.10 Based on the type and nature of the chemicals used onsite, it is extremely unlikely that any employee transported to an offsite emergency facility would be contaminated at a level high enough to warrant decontamination of anyone other than the affected individual. A SDS of the chemical of exposure will be made available to emergency responders upon request. 5.0 EMPLOYEE ALARM SYSTEM 5.1 General Alarm Requirements. An all employee alarm system will be designed according to the following: 5.1.1 Does the employee alarm system appear to provide warning for necessary emergency action as called for in the emergency action plan, or for reaction time for safe escape of employees from the work-place or the immediate work area, or both? 5.1.2 Is the employee alarm capable of being perceived above ambient noise or light levels by all employees in the affected portions of the work place? 5.1.3 Is the employee alarm distinctive and recognizable as a signal to evacuate the work area or to perform actions designated under the emergency action plan? 5.1.4 Where a communication system also serves as the employee alarm system, do all emergency messages have priority over all non-emergency messages? 5.1.5 Have procedures been established for sounding emergency alarms in the workplace? For those facilities with ten (10) or fewer employees in a particular workplace, direct voice communication is an acceptable procedure for sounding the alarm, provided all employees can hear the alarm. Such work-places need not have a back-up system. 5.2 In addition to the requirements 5.2.1 Employees are properly trained. 5.2.2 Emergency telephone numbers are posted 5.2.3 Alarm system is maintained by trained personnel 5.3 Annual Alarm system testing will be performed and documented to ensure the system is functioning and to find any areas of deficiency. 5.4 See EHS-13F13 for specific information on your facility’s alarm system and employee notification procedures 6.0 EVACUATION PLANS 6.1 Emergency evacuation escape route plans are posted in key areas throughout the buildings (usually near exit doors). All employees have been trained concerning these plans and should also be familiar with the evacuation plans for the other buildings within the company. 6.2 Employee responsibilities are broken down into two groups: first, those who are part of the HazMat (emergency response team) and secondly, everyone else. Only HazMat team members are permitted to respond to emergencies of any nature—all other employees evacuate to their designated evacuation locations as specified in the SOP. 6.3 All HazMat Team members are HAZWOPER trained to be able to respond to any release or other emergency; they know how to use common emergency equipment. EMERGENCY RESPONSE PROGRAM PAGE: 6 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 6.4 Employee Accountability Procedures after Evacuation 29 CFR 1910.38(c)(4). 6.4.1 In the event of an emergency, all occupants will promptly exit the building by the nearest exit. Once clear of the building, go to the designated evacuation location and immediately report to their supervisor. After evacuation, each supervisor (or designee) is responsible for accounting for each employee assigned to that supervisor by rallying at the designated evacuation location and conducting a head count. Each employee will be accounted for by name. 6.4.2 Each employee is responsible for reporting to his or her supervisor so an accurate head count can be made. 6.4.3 All supervisors are required to report their head count (by Name) to the Emergency Plan Coordinator or designee. 6.5 Designated Evacuation Locations 29 CFR 1910.38(c)(2) 6.5.1 Primary Location (EHS-13F9). 6.5.2 Secondary Location (EHS-13F10). 6.5.3 Rescue or medical duties procedure—only HazMat Team members or emergency personnel may be involved in medical and rescue activities. Other employees evacuate their building to the primary or secondary evacuation location and wait for the all clean before re-entering the facility. 6.5.4 Once the building is evacuated, no one is to re-enter the building for any reason. Rescue personnel (if designated and properly trained) are excluded from this rule. When the Fire Department or other responsible agency has notified us the building is safe for re-entry, then, and only then, will personnel return to their workstations. 6.5.5 Training for employees who assist in evacuation will be limited to the HazMat Team. Each HazMat Team member has been trained to assist in the safe and orderly emergency evacuation of employees according to the requirements set forth in 29 CFR 1910.38(c) (5). Additionally, all HazMat Team member have been trained to the requirements of 29 CFR 1910.120 (g) (HAZWOPER) and receive annual recertification on this training as required by the OSHA regulation. 6.5.6 Employee training is provided to all employees when (a) the plan is initiated, (b) when employee's required actions and responsibilities change, (c) there are any changes to the plan, and (d) initially for new employees. 6.5.7 This training may include 6.5.7.1 Proper use of fire extinguishers and their location 6.5.7.2 Evacuation routes 6.5.7.3 Building shutdown procedures 6.5.7.4 Emergency escape procedures 6.5.7.5 Procedures to account for employees 6.5.7.6 Major workplace fire hazards 6.5.7.7 Fire prevention practices 6.5.7.8 Closing doors behind you 6.5.7.9 Means of reporting fire and other emergencies 6.5.7.10 Names and titles of emergency plan and fire protection coordinators 6.5.7.11 Alarm systems EMERGENCY RESPONSE PROGRAM PAGE: 7 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 6.5.7.12 Proper housekeeping 6.5.7.13 Emergency and fire prevention plan availability 6.5.7.14 Hazard weather procedures 6.6 Annually this information may be reviewed during the bi-monthly safety meetings (i.e., refresher training). 6.7 Hazard Weather Emergency Plan—when a hazardous weather alert is announced all employees should immediately go to the closest tornado refuge area (where applicable). All employees should stay in the tornado refuge area until given the all clear sign. 7.0 AUTHORITY TO EVACUATE THE PLANT 7.1 Any emergency that requires a decision to evacuate the plant must be cleared with the company President. In his absence, the Plant Manager, Safety Manager, or the most senior manager on-site will determine if evacuation is required. The decision to evacuate will be communicated to senior management at the earliest convenience. 7.2 If an employee takes an emergency call from an off-site location, the following information needs to be recorded: 7.2.1 A phone number where the person calling may be reached 7.2.2 The name of a contact person 7.2.3 The Company name and address (if applicable) 7.2.4 A brief description of the emergency 7.2.5 The appropriate Thatcher Company personnel to respond 7.2.6 Appropriate non-Thatcher Emergency Response Personnel (If applicable) 7.3 If evacuation is required outside of Thatcher Company property, personnel (highest ranking person) will make an assignment to contact the adjacent businesses as listed in form EHS- 13F3. 8.0 EMERGENCY RECOGNITION 8.1 Thatcher Company believes providing employees with hazard recognition training that improves safety awareness is the best way to bring common sense safety to our workplace. 8.2 Emergency recognition training educates employees about ways to identify workplace hazards, recognize the harmful effects hazards can have on them, and learn how to minimize or eliminate hazards by practicing safe work behaviors. This may include, but is not limited to 8.2.1 Housekeeping hazards 8.2.2 Fire 8.2.3 Flammable gas release 8.2.4 Toxic gas release 8.2.5 Medical 8.2.6 Other 8.2.7 Earthquake 8.2.8 Flood 8.2.9 Hurricane or other serious storm 8.2.10 Others not specifically listed 8.3 This training is part of the new employee safety orientation and may include annual refresher training in the form of bi-monthly safety meetings. EMERGENCY RESPONSE PROGRAM PAGE: 8 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 9.0 REPORTING AN EMERGENCY 9.1 All emergencies will be reported according to EHS-29. Reporting emergencies may also include notifying others through manual pull box alarms, public address systems, radio, telephones, or verbally. 9.2 On-site HazMat team member, who are First Aid and CPR certified, will be contacted to assess if off-site emergency medical attention is needed. If off-site help is determined to be needed, then the appropriate person(s) will be contacted (EHS-13F6). 9.3 It is the responsibility of the FIC to inform offsite emergency responders if decontamination (decon 4 e) of employees is needed. 9.4 Fire 29 CFR 1910.38(c)(1). 9.4.1 All fires and emergencies will be reported by one of the following means. 9.4.1.1 Verbally to the FIC, if during standard work hours 9.4.1.2 By telephone, if after hours or on weekends 9.4.1.3 By the alarm system 24 hours a day 9.4.1.4 Public address system 9.4.1.5 The following numbers may be posted at all telephones having outside lines: 9.4.1.5.1 FIRE 9.4.1.5.2 POLICE or SHERIFF 9.4.1.5.3 AMBULANCE 9.4.1.5.4 COMPANY NAME AND ADDRESS/LOCATION 9.4.2 It is anticipated the Fire Department responding will be from the city or county facility nearest Thatcher Company property; however, this is only an assumption. Emergency dispatchers (911) are always free to call whichever agency they feel best suited for the task at hand. 9.5 Flammable Gas Release—will follow the guidelines set forth by the applicable Process Safety Management (PSM). At minimum, employees should notify their immediate supervisor through means such as a manual pull box alarms, public address systems, radio, or telephones. 9.6 Toxic Gas Release—will follow the guidelines set forth by the applicable PSM. At minimum, employees should notify their immediate supervisor through means such as a manual pull box alarms, public address systems, radio, or telephones. 9.7 Medical—will be reported according to the guidelines established in PS-11, employees should also follow the guidelines set form in EHS-19. At minimum, employees should notify their immediate supervisor through means such as a manual pull box alarms, public address systems, radio, or telephones. 9.8 Earthquake—at minimum, employees should notify their immediate supervisor through means such as a manual pull box alarms, public address systems, radio, or telephones. 9.9 Flood, where applicable—at minimum, employees should notify their immediate supervisor through means such as a manual pull box alarms, public address systems, radio, or telephones. 9.10 Hurricane or other Serious Storm, where applicable—at minimum, employees should notify their immediate supervisor through means such as a manual pull box alarms, public address systems, radio, or telephones. 9.11 Others not specifically listed—at minimum, employees should notify their immediate supervisor through means such as a manual pull box alarms, public address systems, radio, or telephones. EMERGENCY RESPONSE PROGRAM PAGE: 9 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 9.12 Employees should use EHS-26 as a reference. 10.0 COMMUNICATION 10.1 The Supervisor will be likely to know of an emergency first. The Supervisor will notify the entire facility through means such as a manual pull box alarms, public address systems, radio, telephones, or verbally. 10.2 When paging using the overhead phone system—three random phone keys will be pushed on the air to bring attention to the speaker. The person paging may state the chemical involved, type of release, the location, and the severity or other details of the incident. 10.2.1 The Supervisor may designate a representative to speak on the paging system, if the emergency requires his/her immediate attention. 10.3 For Laboratory and Office Staff Workers, press the “PAGE” button, press “00” for the entire plant, then three random phone keys on the air to bring attention to the speaker. 10.4 Severity of emergency—The Chemical Spill/Release shall be categorized by the following, if possible: Minor, Moderate, Major, or Catastrophic (Refer to 2.0 Definitions for details). 10.4.1 An example of a page: "HazMat team please report to the Alum area.” 10.4.2 In the event the PA system is not functioning, messengers must contact the HazMat Team physically or by use of a megaphone. The Area Manager where the incident is located will assign a messenger to summon the HazMat Team as needed. 10.5 Notifying required agencies. 10.5.1 A condition of Major or Catastrophic where the reportable quantity has been released requires a 911 call; a call must also be made to the NRC and SERC (EHS-13F4). 10.5.2 The fire department is required to be notified when a chemical is released into the environment (any RQ amount to ground). When a minor release has occurred, the non- emergency fire department phone number will be used (EHS-13F4). The following is an example of a required “Minor” release notification: "My name is (Designated Person), from Thatcher Company at (give your location). I am making a required Non- Emergency report for a chemical release. (Chemical Name) was released at (Time AM/PM) on the (e.g., west end of the plant). The release has been contained and does not require assistance from the Fire Department. There is no danger to employees or to the public. 10.6 The designated person who contacts 911 or communicates with the outside ERT will need to know the following information: 10.6.1 If anyone has been injured 10.6.2 The number of injured persons 10.6.3 The types of injuries 10.6.4 Name of the chemical 10.6.5 Source of the release, fire, or hazard 10.6.6 Immediate location of the release, fire, or hazard (Building #, address, etc.) 10.6.7 Current status of hazard 10.6.8 Possible hazards that may arise 10.6.9 Characteristics of the chemical (appearance, odors, etc.) 10.6.10 Evacuation information—how many and where have the evacuations been implemented 10.6.11 Quantity of spill—Do not guess! EMERGENCY RESPONSE PROGRAM PAGE: 10 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 10.7 The quantity of the release and other information given to the responding authorities must be correct and substantiated. Explain to the Fire Department or other involved agencies an evaluation is in process and a qualified chemist will inform you of the correct release quantity. 10.8 News Media 10.8.1 In the event of emergency, interested news personnel, (i.e., reporters, cameramen, news crews, etc.) are to be directed to the Thatcher Company President. The Company President may designate this duty of answering questions, and providing background to another individual. 10.8.2 To ensure the safety of the news media, no media personnel are allowed on the property until the Company President gives permission. 10.8.3 Once permission is granted, the Company President or his designated representative will accompany the media personnel during the entire time they are on-site. 10.8.4 No employee may talk to the media until after they have received permission to do so from the Company President. Violation of this principle may result in employee discipline as described in EHS-09. 11.0 INCIDENT COMMAND STRUCTURE (ICS) 11.1 The ICS used during an emergency may consist of the following: 11.1.1 The senior most HazMat Team member on-site will act as the FIC until such time as the local fire or police officials take over. Unless instructed otherwise the senior most HazMat Team member will remain on-site even after properly relieved to ensure there is a company representative on-site. 11.1.2 This person will also act as liaison between the company and offsite responders and will ensure that company communications are communicated to offsite emergency responders. 11.1.3 The FIC will be responsible for designating the roles of the other HazMat Team members based upon the nature and degree of the incident. 11.2 Site Control 11.2.1 The purpose of site control is to minimize potential contamination of workers, protect the public from the site's hazards, and prevent vandalism. Site control is especially important in emergency situations. 11.2.2 Several site control procedures can be implemented to reduce worker and public exposure to chemical, physical, biologic, and safety hazards. 11.2.2.1 Compile a site map 11.2.2.2 Prepare the site for subsequent activities 11.2.2.3 Establish work zones 11.2.2.4 Establish and strictly enforce decontamination procedures for both personnel and equipment 11.2.2.5 Establish site security measures 11.2.2.6 Set up communication networks 11.2.2.7 Enforce safe work practices 11.3 The degree of site control depends on site characteristics such as the site size, nature, and degree of the incident and the surrounding community. The appropriate sequence for implementing these measures should be determined on a site specific basis. In many cases, it will be necessary to implement several measures simultaneously. EMERGENCY RESPONSE PROGRAM PAGE: 11 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 11.4 Site Map 11.4.1 A site map showing topographic features, prevailing wind direction, drainage, location of buildings, Storage/Mix-tanks, and ponds is helpful in 11.4.1.1 Planning activities 11.4.1.2 Assigning personnel 11.4.1.3 Identifying access routes, evacuation routes, and problem areas 11.4.1.4 Identifying areas of the site that require use of personal protective equipment 11.4.1.5 Supplementing the daily safety and health briefings of the field teams 11.4.2 The map should be prepared prior to site entry and updated throughout the course of site operations to reflect 11.4.2.1 Accidents 11.4.2.2 Changes in site activities 11.4.2.3 Emergencies 11.4.2.4 Hazards not previously identified 11.4.2.5 New materials introduced on site 11.4.2.6 Vandalism 11.4.2.7 Weather conditions 11.4.3 Overlays can be used to help portray information without cluttering the map. 11.5 Site Work Zone 11.5.1 To reduce the accidental spread of hazardous substances by workers from the contaminated area to the clean area, zones should be delineated on the site where different types of operations will occur, and the flow of personnel among the zones should be controlled. 11.5.2 The establishment of work zones will help ensure that 11.5.2.1 personnel are properly protected against the hazards present where they are working, 11.5.2.2 work activities and contamination are confined to the appropriate areas, and 11.5.2.3 Personnel can be located and evacuated in an emergency. 11.5.3 Contaminated area within the facility should be divided into as many different zones as needed to meet operational and safety objectives. These zones may include 11.5.3.1 Exclusion Zone: the contaminated area 11.5.3.2 Contamination Reduction Zone (CRZ): the area where decontamination takes place 11.5.3.3 Support Zone: the uncontaminated area where workers should not be exposed to hazardous conditions 11.5.4 Outlining these three zones should be based on sampling and monitoring results and on an evaluation of potential routes and amount of contaminant dispersion in the event of a release. Movement of personnel and equipment among these zones should be minimized and restricted to specific access. 11.5.5 Control Points to prevent cross-contamination from contaminated areas to clean areas EMERGENCY RESPONSE PROGRAM PAGE: 12 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 should be established based on the degree and nature of the incident. 11.6 Exclusion Zone 11.6.1 The Exclusion Zone is the area where contamination does or could occur. The primary activities performed in the Exclusion Zone are 11.6.1.1 Site characterization, such as mapping, photographing, and sampling. 11.6.1.2 Installation of wells for groundwater monitoring. 11.6.1.3 Cleanup work, such as drum movement, drum staging, and materials bulking. 11.6.2 The outer boundary of the Exclusion Zone, called the Hotline, should be clearly marked by lines, placards, hazard tape and/or signs; or enclosed by physical barriers, such as chains, fences, or ropes. Access Control Points should be established at the periphery of the Exclusion Zone to regulate the flow of personnel and equipment into and out of the zone and to help verify proper procedures for entering and exiting are followed. If feasible, separate entrances and exits should be established to separate personnel and equipment movement into and out of the Exclusion Zone. 11.6.3 The Exclusion Zone can be subdivided into different areas of contamination based on the known or expected type and degree of hazard or on the incompatibility of waste streams. This allows more flexibility in safety requirements, operations, decontamination procedures, and use of resources. 11.6.4 The personnel working in the Exclusion Zone may include the Field Team Leader, the work parties, and specialized personnel such as heavy equipment operators. All personnel within the Exclusion Zone should wear the level of protection required by the Site Safety Plan. Within the zone, different levels of protection may be justified based on the degree of hazard presented. The level of personal protection required in each subarea should be specified. 11.6.5 The required level of protection in the Exclusion Zone may vary based on the degree and nature of the incident. For example, a worker who collects samples from open containers might require Level B protection, while one who performs walk-through ambient air monitoring might only need Level C protection. When appropriate, different levels of protection within the Exclusion Zone should be assigned to promote a more flexible, effective, and less costly operation, while still maintaining a high degree of safety. 11.7 Contamination Reduction Zone (CRZ) 11.7.1 The CRZ is the transition area between the contaminated area and the clean area. This zone is designed to reduce the probability the clean Support Zone will become contaminated or affected by other site hazards. 11.7.2 The distance between the Exclusion and Support Zones provided by the CRZ, together with decontamination of workers and equipment, limits the physical transfer of hazardous substances into clean areas. 11.7.3 The boundary between the CRZ and the Exclusion Zone is called the Hotline. The degree of contamination in the CRZ decreases as one moves from the Hotline to the Support Zone, due both to the distance and the decontamination procedures. 11.7.4 Decontamination procedures take place in a designated area within the CRZ called the Contamination Reduction Corridor (CRC). They begin at the Hotline. At least two lines of decontamination stations should be set up within the CRC: one for personnel and one for heavy equipment. A large operation may require more than two lines. Access into and out of the CRZ from the Exclusion Zone is through Access 11.8 Control Points: one each for personnel and equipment entrance, one each for personnel and EMERGENCY RESPONSE PROGRAM PAGE: 13 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 equipment exit, if feasible. EMERGENCY RESPONSE PROGRAM PAGE: 14 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 11.9 The boundary between the Support Zone and the CRZ, called the Contamination Control Line, separates the possibly low contamination area from the clean Support Zone. Access to the CRZ from the Support Zone is through two Access Control Points if feasible: one each for personnel and equipment. Personnel entering the CRZ should be required to wear the personal protective clothing and equipment prescribed for working in the CRZ. To reenter the Support Zone, workers should remove any protective clothing and equipment worn in the CRZ, and leave through the personnel exit Access Control Point. 11.10 The personnel stationed in the CRZ are usually the Site Safety Officer, a Personnel Decontamination Station (PDS) Operator, and the emergency response personnel. Additional personnel may assist the PDS Operator by conducting abbreviated decontamination procedures for sample containers. 11.11 The CRZ must be well designed to facilitate 11.11.1 Decontamination of equipment, PDS operators, personnel, and samples. 11.11.2 Emergency response: transport for injured personnel (safety harness, stretcher), first- aid equipment (such as bandages, blankets, eye wash, splints, and water), and containment equipment (absorbent, fire extinguisher). 11.11.3 Equipment resupply: air tank changes, personal protective clothing and equipment (such a booties and gloves), sampling equipment (such as bottles and glass rods), and tools. 11.11.4 Sample packaging and preparation for onsite or offsite laboratories. 11.11.5 Worker temporary rest area: toilet facilities, bench, chair, liquids, and shade. Water and other potable liquids should be clearly marked and stored properly to ensure all glasses and cups are clean. Wash facilities should be located near drinking facilities to allow employees to wash before drinking. Drinking, washing, and toilet facilities should be located in a safe area where protective clothing can be removed. Facilities should be cleaned and inspected regularly. 11.12 Appropriate protective measures should be taken by maintenance workers. 11.12.1 Drainage of water and other liquids that are used during decontamination. 11.12.2 Personnel within the CRZ should be required to maintain internal communications, line- of-sight contact with work parties, work party monitoring (e.g., for air time left, fatigue, heat stress, hypothermia), and site security. 11.13 Support Zone 11.13.1 The Support Zone is the location of the administrative and other support functions needed to keep the operations in the Exclusion and CRZ running smoothly. Any function that need not or cannot be performed in a hazardous or potentially hazardous area is performed here. The Command Post Supervisor should be present in the Support Zone. Other personnel present will depend on the functions being performed, and may include the Project Team Leader and field team members who are preparing to enter or who have returned from the Exclusion Zone. 11.13.2 Personnel may wear normal work clothes within this zone. Any potentially contaminated clothing, equipment, and samples must remain in the CRZ until decontaminated. 11.13.3 Support Zone personnel are responsible for alerting the proper agency in the event of an emergency. All emergency telephone numbers, change for the telephone (if necessary), evacuation route maps, and vehicle keys should be kept in the Support Zone. EMERGENCY RESPONSE PROGRAM PAGE: 15 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 11.13.4 Support facilities are located in the Support Zone. Consider the following factors when placing them. 11.13.4.1 Accessibility. Topography, open space available, locations of highways and railroad tracks, and ease of access for emergency vehicles. 11.13.4.2 Resources. Adequate roads, power lines, telephones, shelter, and water. 11.13.4.3 Visibility. Line-of-sight to all activities in the Exclusion Zone. 11.13.4.4 Wind direction. Upwind of the Exclusion Zone, if possible. 11.13.4.5 Distance. As far from the Exclusion Zone as practicable. 11.14 The buddy system WILL be used during all emergency responses—HazMat Team Members responding to the incident will work in pairs to mitigate the hazards involved. Specific roles may include 11.14.1 Decontamination 11.14.2 Investigation 11.14.3 Liaison Officer 11.14.4 Service 11.14.5 Safety Officer 11.14.6 Those performing the hazard mitigation (strike team) 11.15 Emergency Response Team Organization 11.15.1 A current flowchart for the facility can be found in EHS-13F5. 11.16 The exact number of emergency responders (HazMat Team) will depend on the nature, type, severity, and time of the incident. 12.0 MEDICAL AND FIRST AID 12.1 If an employee is injured, seek immediate medical attention by contacting your supervisor. 12.2 In non-emergency situations, the Supervisor must be notified immediately of an accident. In the event of a serious injury, the Supervisor is to be contacted after medical attention has been provided to the injured employee (i.e., 911 called). 12.2.1 The Supervisor and the injured employee must complete the "Accident Investigation" report (EHS-06). 12.2.2 A non-emergency accident requires the Supervisor or Safety Manager to be notified before a medical facility is visited. Workers Compensation has an approved Physician list that is located in this SOP and on the Safety Manager’s door. 12.2.3 The injured employee is required to take a post-accident drug screen within 24 hours of the injury. 12.3 Location of Emergency First Aid Kits 12.3.1 HazMat Team members are the only people authorized to administer first aid and use the first aid kits. First Aid kits are generally located in the HazMat closet, and/or the lab (if applicable). The HazMat first aid kits are under the supervision of the Safety Manger (See EHS-19). Please verify the location of your closest first-aid kit. 12.3.2 An additional general use first aid kit is located in the dispatch office under the supervision of the Plant Superintendent. This kit is for minor scrapes and cuts. (Branch locations may differ—verify where your nearest first-aid kit is located). EMERGENCY RESPONSE PROGRAM PAGE: 16 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 12.4 Chlorine Emergencies (see Pamphlet 63 from the Chlorine Institute: First Aid, Medical Management/Surveillance and Occupational Hygiene Monitoring Practices for Chlorine, Edition 8). 12.4.1 FIRST AID—first aid is the immediate temporary treatment given to an exposed individual. Prompt action is essential. Reassurance to the individual will help to alleviate anxiety. When indicated, medical assistance must be obtained as soon as possible. Never give anything by mouth to an unconscious or convulsing person. If chlorine has saturated an exposed individual’s clothes and/or skin, decontamination should be done by removing affected clothing and showering as appropriate. 12.4.2 Responders should take the necessary precautions to protect themselves from any exposure to chlorine while administering first aid and should move the victim from any contaminated area as quickly as possible. 12.4.3 INHALATION—an individual with chlorine inhalation exposure should be evaluated for adequate airway, breathing and circulation after the inhalation. If breathing has apparently ceased, the victim should be given cardiopulmonary resuscitation (CPR) immediately. If breathing has not ceased, the exposed individual should be placed in a comfortable position. The person should sit in an upright position with the head and trunk elevated to a 45-60 degree position (unless there is a medical contraindication). Slow, deep breathing should be encouraged. Vital signs (respiratory rate, pulse, and blood pressure) and oxygen saturation should be obtained if trained personnel and equipment are available. Suitable equipment for the administration of oxygen should be available either on site or at a nearby facility. Such equipment should be periodically tested. 12.4.4 Historically, oxygen therapy, specifically humidified oxygen, has been considered the primary treatment for chlorine inhalations. Humidified oxygen is preferred since the humidity soothes the irritation to the mucous membranes caused by the chlorine. Oxygen without the humidity can have a drying effect, thus potentially aggravating the irritant symptoms. However, if humidified oxygen is not available, oxygen without the humidity should not be withheld if oxygen therapy is indicated. With the advance in technology, equipment (pulse oximeter) is now available which can quickly measure the oxygen saturation in an indivi dual. This measurement may be helpful in deciding whether supplemental oxygen is needed after a chlorine inhalation. 12.4.5 Oxygen therapy may not be necessary for all cases of chlorine inhalation. However, in any case in which an individual with a chlorine inhalation continues to be symptomatic after leaving the area of exposure, oxygen therapy is recommended unless it can be determined it is not needed. The circumstances in which oxygen therapy is not needed should be defined in advance by a physician, based on the clinical findings and a case-by-case determination made by first aid providers specifically trained in this area. 12.4.6 ADMINISTRATION OF OXYGEN—oxygen should be administered by first aid providers trained in the use of the specific oxygen equipment under the guidance of a licensed health care professional. 12.4.7 If a pulse oximeter is not available, oxygen therapy is recommended for any individual who has inhaled chlorine and continues to be symptomatic after leaving the area of exposure. EMERGENCY RESPONSE PROGRAM PAGE: 17 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 12.4.8 If a pulse oximeter is available, the following findings comprise a base list of situations in which oxygen therapy is generally indicated to be given by first aid providers after a chlorine inhalation. Other criteria may be added to this list if specifically recommended by a physician: 12.4.8.1 Sustained pulse-oximetry readings <92%; or 12.4.8.2 The individual is in obvious respiratory distress (including, but not limited to rapid respirations, difficulty breathing, using accessory muscles for respiration, continuous uncontrollable coughing, wheezing); or 12.4.8.3 The exposed individual is having “symptoms of concern”, such as significant chest pain/tightness, extreme weakness, altered/declining mental status, or the individual is diaphoretic (clammy/pale/sweating not due to environmental conditions) etc., especially if these or other significant symptoms occur with an individual with a past history of cardiac problems or asthma; (NOTE: “symptoms of concern” generally do not include the typical upper respiratory tract irritation symptoms which occur with mild chlorine gas inhalations such as mild/moderate coughing, initial difficulty “catching one’s breath”, mild/moderate shortness of breath, irritated throat, runny nose, congestion, headache, and/or mild nausea). 12.4.9 NOTE: It is recommended a physician be consulted regarding any individual meeting one or more of the above criteria in order to determine whether further evaluation and/or treatment is indicated. 12.4.10 If oxygen therapy is indicated, it should be administered until the symptoms resolve. Whenever oxygen is discontinued after symptoms resolve, the individual should then be observed for 30–60 minutes while breathing room air. If significant symptoms do not resolve within 60 minutes of oxygen therapy, or symptoms return/worsen and/or the oxygen saturation (when pulse oximetry is available) falls below 92%, it is recommended oxygen therapy be restarted (if it had been discontinued) and further evaluation by a physician be provided. 12.5 Administration of Humidified Breathing Air—not all individuals who have inhaled chlorine require oxygen therapy. It is recommended the circumstances in which oxygen therapy is not needed should be defined in advance by a physician and a case-by-case determination made by first aid providers specifically trained in this area. 12.6 In situations where it has been determined oxygen therapy is not needed, but the individual with an inhalation exposure has irritant symptoms, humidified air may be provided for symptomatic care. While breathing humidified air, the individual should be closely monitored for 30–60 minutes. If the individual continues to show no signs or symptoms for which oxygen would be indicated, the humidified air can be stopped. Observation should continue for an additional 30 minutes while the individual is breathing room air so as to ensure there is no deterioration of the individual's condition. Oxygen therapy should be started at any time during the above process if symptoms worsen to the point oxygen is indicated (12.4.8). Further evaluation by a physician should be provided in any case in which oxygen therapy is provided. 12.7 Symptomatic care—other symptomatic care measures, such as cool compresses to the face and over-the-counter medications, may help to minimize symptoms. Over-the-counter medications which may be helpful include 12.7.1 Irritated/sore throat—throat lozenges 12.7.2 Dry cough—dextromethorphan, guaifenesin 12.7.3 Headaches—acetaminophen, aspirin, ibuprofen 12.7.4 Upset stomach—antacids EMERGENCY RESPONSE PROGRAM PAGE: 18 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 12.8 CONTACT WITH SKIN—if liquid chlorine has contaminated the skin or clothing, an emergency shower should be used immediately and contaminated clothing should be removed under the shower. Flush contaminated skin with copious amounts of tepid water for 15 minutes or longer. Thermal burns, due to the cold temperature of liquid chlorine, may be more damaging than any chemical reaction of chlorine and the skin. Exposure to gaseous chlorine can irritate the skin. Do not attempt chemical neutralization or apply any salves or ointments to damaged skin. Refer to a qualified health care provider if irritation persists after irrigation or if skin is broken or blistered. 12.9 CONTACT WITH THE EYES—if the eyes have been irritated due to exposure to chlorine, they should be flushed immediately with copious quantities of tepid water for at least 15 minutes. 12.9.1 Never attempt to neutralize with chemicals. 12.10 The eyelids should be held apart during this period to ensure contact of water with all accessible tissue of the eyes and lids. Medical assistance must be obtained as soon as possible. If such assistance is not immediately available, eye irrigation should be continued for a second 15-minute period. Nothing but water should be applied unless ordered by a qualified health care provider. 12.11 MEDICAL MANAGEMENT OF CHLORINE EXPOSURES (SUBSEQUENT TO FIRST AID)—the following information is intended for general guidance only. Final determination of specific medical intervention(s) should only be made by qualified medical personnel upon full consideration of each patient’s overall medical condition. The Institute recommends that any treatment be done in conjunction with a full medical assessment by qualified personnel. 12.12 GENERAL PRINCIPLES 12.12.1 All individuals who have developed symptoms as a result of an acute overexposure to chlorine gas by inhalation should be placed under the supervision of qualified health care personnel. 12.12.2 There is no known specific antidote for acute chlorine exposure. Prompt medical assessment and supportive measures are necessary to obtain good therapeutic results. 12.12.3 If the individual is unconscious, take steps necessary to protect the airway from obstruction. 12.12.4 Alleviate anxiety by communicating with the patient the various procedures undertaken and elicit his/her cooperation, especially in breathing exercises. 12.12.5 Position the patient with the head and trunk elevated to a 45-60° position (assuming there are no medical contraindications). 12.12.6 Encourage slow, regular respiration. 12.12.7 Oxygen therapy should be considered in all individuals who continue to be symptomatic after a chlorine inhalation. If after medical evaluation it is determined an individual does not need oxygen therapy, humidified air may be helpful an alleviating some of the residual irritant respiratory symptoms. 12.13 THERAPY FOR SPECIFIC PHYSIOLOGICAL DISTURBANCES 12.13.1 Pulmonary Edema—once pulmonary edema has developed from acute chlorine inhalation, the treatment is basically that of acute respiratory failure. This individual should be under the care of a health care professional familiar with this disease process in an intensive care setting. It should be noted there is inconclusive evidence regarding the use of corticosteroids to prevent or alleviate pulmonary edema after an acute chlorine inhalation. 12.13.2 Bronchospasm (Wheezing)—bronchodilators administered either by nebulization, or subcutaneously, may be beneficial if patient is having bronchospasm (wheezing). EMERGENCY RESPONSE PROGRAM PAGE: 19 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 12.13.3 Acute Anxiety—acute anxiety (fear and/or apprehension) by an employee exposed to chlorine may occur. Reassurance is best accomplished without the use of sedatives. Use of sedatives should only be considered by qualified medical personnel following medical assessment and only employed under close supervision of respiratory function to monitor progress. 12.13.4 Delayed Effects—after an acute exposure to chlorine, pulmonary function usually returns to pre-exposure levels in 7 to 14 days, and complete recovery usually occurs. Post-incident spirograms may be used for clinical follow-up. Cases of Reactive Airways Dysfunction Syndrome (RADS), a chemical irritant-induced asthma, have been reported after significant chlorine inhalation. 12.13.5 The inhalation of any irritating gas may lead to delayed reactions such as pulmonary edema. Since physical exercise appears to have some relation with the incidence of delayed reaction, it is recommended any patient who has had severe inhalation exposure should be kept at rest for a period of observation. During the period of observation, the avoidance of irritants (e.g., cigarette smoke, dust, etc.) is recommended. The length of observation will depend on the clinical assessment of the exposed individual. Observation may be required up to several days after exposure. Excitement, apprehension and/or emotional distress may persist for some period of time following a severe exposure. 13.0 FIRE SUPPRESSION PLAN (29 CFR 1910.157) 13.1 Responsibilities 13.1.1 Management is responsible for seeing fire-prevention procedures are established and enforced; fire suppression systems are inspected regularly and maintained; supervisors are trained to use fire extinguishers for incipient fires; and employees are trained to use evacuation routes and procedures. 13.1.2 Supervisors are responsible for monitoring the use of flammable materials; training employees in safe storage, use and handling of flammables; and ensuring storage areas for flammables are maintained properly. 13.1.3 Employees are responsible for following company procedures for the safe storage, use and handling of flammable materials, and reporting unsafe conditions to their immediate supervisor. 13.2 Definitions 13.2.1 Fires are classified according to the type of fuel or material. 13.2.1.1 Class A—wood, paper and cloth 13.2.1.2 Class B—flammable gases, liquids and greases 13.2.1.3 Class C—fires in live electrical equipment, or involving materials near electrically powered equipment 13.2.1.4 Class D—combustible metals such as magnesium, zirconium, potassium and sodium 13.3 Ignition Sources—eliminate all non-essential ignition sources where flammable materials are used or stored. For example 13.3.1 Keep sources of open flame (such as welding and cutting torches, furnaces, matches, and heaters) away from operations involving flammables. 13.3.2 Do not cut or weld equipment containing flammable liquids unless the equipment has been emptied and purged with a neutral gas such as nitrogen. EMERGENCY RESPONSE PROGRAM PAGE: 20 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 13.3.3 Prohibit chemical ignition sources (such as DC motors, switches, and circuit breakers) in areas where flammable materials are stored or handled. 13.3.4 Use only non-sparking tools in areas where flammables are stored or handled. 13.3.5 Eliminate the possibility of static sparks—caused by electron transfer between two contacting surfaces—in flammable storage or handling areas. 13.4 Incompatible Materials (See EHS-16 For More Information) 13.4.1 Store materials such as oxidizers and organic peroxides, which produce large amounts of oxygen when they decompose, in an area separate from flammable materials. 13.5 Fire Extinguishers 13.5.1 Portable fire extinguishers can be very effective for fighting fires in their incipient stages. A person who is well-trained in fire-extinguisher use can save both lives and property. Portable fire extinguishers must be available even when other firefighting measures are available. For extinguishers to be effective in a fire situation, proper selection, inspection, and maintenance are essential. 13.5.2 Fire Extinguishers are located throughout the facility for us in an emergency. 13.5.3 Make sure all fire extinguishers are placed in conspicuous locations, clearly visible, and easily accessible. 13.5.4 Keep all fire extinguishers fully charged and operable, and in their proper locations at all times. 13.6 Fire Safety Inspections And Housekeeping 13.6.1 Supervisors and safety committees are responsible for work site inspections to ensure compliance with the company Fire Safety Program. These inspections should address housekeeping issues, proper storage of chemicals, access to fire extinguishers, and emergency evacuation routes. 13.7 Emergency Exits 13.7.1 Every exit must be clearly visible, or the path to it conspicuously identified in such a manner that every occupant of the building will know the best way to get out of the building in a fire or other emergency. 13.7.2 Exits must never be obstructed. Any door or passageway that is not an exit or path to an exit must be identified with a sign that reads ‘Not An Exit’ or a sign that indicates its actual use, such as storage closet, etc. 13.7.3 All exit signs must either be self-illuminating, or illuminated by a reliable external light source. 13.8 Emergency Plan For Persons With Disabilities 13.8.1 First line supervisors are responsible for assisting persons with disabilities under their supervision, and must choose an alternate to assume responsibility in the supervisor’s absence. The supervisor, alternate and worker with the disability will be trained on available escape routes. A list of persons with disabilities must be kept on file in the (personnel, safety director’s office). Company visitors with disabilities will be assisted in the same manner as employees. EMERGENCY RESPONSE PROGRAM PAGE: 21 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 13.9 Fire Emergency Procedures 13.9.1 The person who discovers a fire should activate the nearest alarm, and notify his or her supervisor and other building occupants. 13.9.2 You should only attempt to fight a fire if 13.9.2.1 The fire department has been notified 13.9.2.2 The fire is small and confined to its point of origin 13.9.2.3 You have an escape route available and can fight the fire with your back to the exit If you cannot answer yes to all of these conditions; immediately leave the area! 13.9.3 Be sure you have a proper, fully functioning fire extinguisher, and are trained on how to use it before attempting to suppress a fire. 13.9.4 Leave your work area if you hear a fire alarm. Close all windows and doors, and turn off any sources of fuel or points of ignition when you leave; evacuate the building and move away from exits, and assemble in designated evacuation location in the company evacuation plan. Remain outside until a competent authority says it is safe to re-enter the building. 13.10 Fire Extinguisher Training 13.10.1 All new employees will receive orientation training on the proper use of fire extinguishers. This may include watching a video, a PowerPoint presentation or a verbal discussion. 13.10.2 Existing employees will be retrained annually on the safe use of fire extinguishers. This training will consist of identifying and familiarization with the PASS acronym 13.10.2.1 P – Pull the pin 13.10.2.2 A – Aim 13.10.2.3 S – Squeeze the trigger 13.10.2.4 S – Sweep side to side 14.0 EVACUATION PROCEDURES 14.1 After the announcement (page) has been made to evacuate the working areas of the plant, Supervisors will shut-down their operations. For areas with more involved shutdown procedures, the Supervisor will follow the emergency shut-down SOP specific to their area, if applicable. 14.2 The evacuation location will be determined by the HazMat team leadership. Once determined, the location will be paged to all employees. Evacuation routes of Thatcher buildings are as follows: 14.2.1 Primary evacuation location (EHS-13F9) 14.2.2 Secondary evacuation location (EHS-13F10) 14.3 Evacuation routes (preferred routes) 14.3.1 Each facility and building have specified unique (preferred) evacuation routes (map) and they can be found in the forms associated with this SOP (EHS-13F14). 14.4 Upon notification of an emergency requiring an evacuation, all personnel should use the nearest unobstructed exit and head to the primary evacuation location. 14.5 Supervisors will designate a roll call employee. This employee will gather the Area personnel in the designated area and take roll as the employees assemble. The HazMat Team will be notified of missing persons and enter into the plant for rescue after they have the appropriate EMERGENCY RESPONSE PROGRAM PAGE: 22 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 Personal Protective Equipment (PPE). 14.6 The role sheet, pen and clip board, required for taking roll, are stored in the HazMat closet or in the office. 14.6.1 Red Clip Boards are for day shift personnel (7:00 AM through 3:30 PM) 14.6.1.1 Every building has a designated person to take roll. 14.6.2 Blue Clip Boards are for swing shift personnel (3:30 PM through 7:00 AM)—Where applicable 14.6.2.1 Every building has a designated person to take roll (generally this will be the supervisor). 14.6.3 These sheets will be updated as required by the Safety Manager. 14.7 Any protective measures or containment efforts will be performed by the ERT. These operations will continue until the problem is corrected or until outside agencies mandate (acquire) control. 14.8 The Office/Dispatch check-in (Scale house) will be responsible for any common carriers which have signed in but have not yet entered into the facility. These drivers will be gathered in the same manner as the area personnel are gathered. 14.9 The common carriers that have entered the facility will be the responsibility of the Supervisor where he is loading; the Supervisor will include these drivers with their personnel. 14.10 All transportation vehicles will be checked for drivers in their sleeping berths. They will be informed of the emergency, evacuated, and accounted for. 14.11 Evacuation Plans—emergency evacuation escape route plans are posted in key areas throughout the facility. All employees shall be trained on primary and secondary evacuation routes and locations. 14.12 Employee Accountability—in the event of an evacuation, all occupants shall promptly exit the building via the nearest exit. Go to your designated evacuation location and report to your supervisor. A role call will be complete to account for all employees, contractors, and visitors. 14.13 Building Re-Entry—once evacuated, no one shall re-enter the building(s), with the exception of the HazMat (ERT) Team in searching for unaccounted personnel. Once the Fire Department or other responsible agency has notified us the building is safe to re-enter; only then, shall personnel be allowed to return to their areas of work. 14.14 Site Security and Control—in the case of an evacuation, site security shall be the responsibility of the senior most HazMat Team member on-site. Any person who is not directly related to the emergency at hand will not be allowed on Thatcher Company property for the duration of the incident. 14.15 Contractor Responsibility—in the event of evacuation, the manager or designee is responsible to account for all contractors on-site at that time. To accomplish this, contractors will sign-in and out according to EHS-14. Once accounted for, contractors will be informed of the nature of the incident and be instructed on when they may re-enter the facility. 15.0 LOCAL, STATE, AND NATIONAL EMERGENCY PHONE NUMBERS 15.1 A current list of these important phone numbers in maintained in EHS-13F4. 15.2 For chemical spills or releases involving quantities equal to or greater than reportable quantities, the Plant Manager, Technical Director, or Safety Manger will assign a person to immediately call the agencies listed in EHS-13F4. 15.2.1 The local Fire Department/Local Emergency Planning Committee (LEPC) EMERGENCY RESPONSE PROGRAM PAGE: 23 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 15.2.2 National Response Center (NRC) 15.2.2.1 The National Response Center (NRC) is the sole federal point of contact for RQ chemical spills and releases. The NRC operates 24 hours a day, 7 days a week, 365 days a year. A report will be generated and sent to the local Fire Department and EPA automatically. The Fire Department and EPA still require the notification from Thatcher Company even with the generated NRC report. 15.2.3 EPA Contact 15.2.3.1 This may be a state agency or to a local EPA office—check your area for applicability (EHS-13F4). 15.2.4 For accidental spill/release discharges into the sewer (POTW—Publically Owned Treatment Works), Where applicable. 15.2.4.1 Within five (5) days of a spill/release discharge, a designated Thatcher Company employee shall submit to the POTW manager a detailed written report describing the cause of the discharge and the measures to be taken to prevent future occurrences. 15.3 Qualified individuals in the lab and engineering departments will generate an estimate of the hazardous material quantity that was released into the environment. If the amount meets or exceeds the reportable quantity, the notification must be made to the proper authorities. 15.4 OSHA must be contacted by phone within 8-hours, if the following conditions are met. (Note: if the Area OSHA office cannot be contacted, the 1-800-321-OSHA may be called.) 15.4.1 Death of any employee. 15.4.2 Inpatient hospitalization of three or more employees (Federal OSHA). 15.4.3 Arizona—employers must report to ADOSH all workplace accidents involving a fatality, or involving the hospitalization of three or more employees. This report must be made within eight (8) hours following the incident. To report an incident to ADOSH, call (602) 542-5795 or toll-free at (855) 268-5251. If you call outside of regular business hours, please leave a message and someone will return your call as soon as possible. 15.4.4 California—CAL/OSHA must be contacted if one (1) person is hospitalized. (a) Every employer shall report immediately by telephone or telegraph to the nearest District Office of the Division of Occupational Safety and Health any serious injury or illness, or death, of an employee occurring in a place of employment or in connection with any employment. Immediately means as soon as practically possible but not longer than 8 hours after the employer knows or with diligent inquiry would have known of the death or serious injury or illness. If the employer can demonstrate exigent circumstances exist, the time frame for the report may be made no longer than 24 hours after the incident. Title 8, California Administrative Code. 15.4.5 Florida—follow Federal guidelines listed in 15.4. 15.4.6 Idaho—follow Federal guidelines listed in 15.4. 15.4.7 Montana—follow Federal guidelines listed in 15.4. 15.4.8 Nevada—employers must report to NVOSHA all workplace accidents involving a fatality of one or more employees, or involving hospitalization of three or more employees, within eight (8) hours after learning of the accident. To report an incident to NVOSHA, call (702) 486-9020 (Southern Nevada) or (775) 824-4600 (Northern Nevada). 15.4.9 New York—follow Federal guidelines listed in 15.4. 15.4.10 Utah—UOSH must be contacted if one (1) person is hospitalized. 15.4.11 Check local state regulation for federal OSHA variations. EMERGENCY RESPONSE PROGRAM PAGE: 24 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 16.0 PERSONNEL TRAINING 16.1 All employees will have sufficient training to recognize an emergency should it arise. Training through first responder level in accordance with OSHA standard 29 CFR 1910.12 (q) (6) (ii) shall be given to all employees. All production employees shall receive training through the hazardous materials specialist level, as defined by OSHA 29 CFR 1910.12 (q) (6) (iv). Through training and hands-on experience, employees will be taught how to recognize potential hazards and correct them (or at least minimize them) before they become emergencies. Engineering controls have also been put into place to help prevent emergencies from happening. Ongoing training may be given through bi-monthly meeting and semiannual drills. 16.2 All HazMat Team members have received training to the 40 hour HAZWOPER level (29 CFR 1910.120). All HazMat Team members also receive annual 8 hour refresher training as required by the OSHA standard. 16.3 In addition, facility personnel will have annual refresher training of the current Emergency Response Plan (ERP). 16.4 Only personnel with appropriate training will be allowed to respond to an emergency situation. All plant employees will receive annual training on this SOP during a safety meeting. This includes instructions of evacuation locations during an evacuation. Employees are trained on the hazards of Chlorine, Sulfur Dioxide, and Ammonia gases. Information concerning SDS, forms, placards, and safety are read and tested during this orientation meeting. 16.5 ERT (Emergency Response Team) members shall respond to chemical and other hazardous plant emergencies. Before an employee can become a first responder, they must have the 40- Hour HAZWOPER training followed by the annual 8-hour refresher courses to remain current. Annual CPR and 3-year first aid certifications are required. 16.6 Thatcher Transportation Drivers and HazMat team members will be trained in the use of Emergency Kits. Emergency Kits are designed to contain most leaks which may be encountered in compressed gas shipping containers. They are designated 16.6.1 Kit A—for 150 lb. cylinders 16.6.2 Kit B—for ton containers 16.6.3 Kit C—for tank cars, and tank trucks 16.7 All trucks transporting these gases will carry the kits necessary for their shipment. Drivers using any equipment, including the A, B, and C Kits, Fire Extinguishers, and respirators will be reported to the Safety Manager. An incident investigation will follow any use of emergency equipment. 16.8 The Supervisors are responsible of all safety equipment used in chemical gas leaks, spills, fires, and other emergencies. Area fire extinguishers are checked bi-monthly and recorded on the Safety Meeting notes 16.9 All employees will be trained on the facility evacuation plan during their new employee orientation and annually thereafter. If for any reason the specifics of the EAP changes, employees will receive training on these changes to the level of understanding. Additionally, if an employee’s position changes within Thatcher Company they will receive training which pertains to their new position. 16.10 At least once per year this plan will be tested in an evacuation drill. During these drill all alarms systems will be tested. EMERGENCY RESPONSE PROGRAM PAGE: 26 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 initial advice from pre-printed material to personnel at the scene. 19.2 Where expert advice or help at the scene appears necessary, CHEMTREC and CANUTEC operate as Emergency Dispatch Agencies. In such cases, the Emergency Dispatcher will enter the pertinent information on an appropriate dispatch report. This person will determine the preferable chemical emergency group using the Location Guide. 19.3 At times, Thatcher Company may send company personnel to help clean a spill—when this occurs, only personnel who have been HAZWOPER trained may be considered for offsite spill management. 20.0 SHUT DOWN CHECKLIST 20.1 Procedures to be followed by employees who remain to operate critical plant operations before they evacuate. 20.2 Employees may be required to operate fire extinguishers or shut down gas and/or electrical systems and other special equipment that could be damaged if left operating or create additional hazards to emergency responders (such as releasing hazardous materials) 29 CFR 1910.38(c)(3). 20.3 A full list of applicable equipment that may require lengthy shut-down procedures is maintained. EHS-13F12 lists building and equipment that must be shut down before evacuation and the person responsible for doing so. 21.0 CRITIQUE OF RESPONSE AND FOLLOW-UP 21.1 A critique of the response to the release will be performed no more than two weeks after the date of the incident. 21.2 The critique will involve a written statement from all of the personnel directly involved in the incident. 21.3 An analysis will be done on all other written reports to determine what could have been improved upon in the response and what can be done in the future to prevent a similar incident from happening again. 21.4 Additional training will be given in accordance with the results of the analysis to all of the personnel affected by the incident. 21.5 Any engineering controls that can further reduce the likelihood of a similar accident from happening again will be implemented. 21.6 A written record of incidents will be archived. 21.7 Any equipment deficiencies, such as a non-functioning alarm will be documented for repair. Employees will be notified the alarm system or other equipment is non-functioning and down for repair. 22.0 EMERGENCY PHONE NUMBERS 22.1 A current list of important phone numbers can be found in EHS-13F1. 22.2 A current list of the HazMat Emergency Response Team members and their phone numbers can be found in EHS-13F2. 23.0 MANAGEMENT PLAN, SITE CONTACTS AND DOCUMENT CONTROL 23.1 Covered in EHS-13F15. 24.0 MAXIMUM INVENTORIES OF HHCs 24.1 A current list of maximum possible inventories of all chemicals stored on-site is located in the Hazardous Materials Inventory Summary (HMIS) and is part of the Hazardous Materials Management Plan (HMMP). The HMMP is updated at least annually and submitted to any required local governing fire departments. It is the Plant Manager's responsibility to ensure EMERGENCY RESPONSE PROGRAM PAGE: 27 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 these limits are not exceeded. EMERGENCY RESPONSE PROGRAM PAGE: 28 of 28 (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 REVISION HISTORY Rev Date Author Section Affected Change Description 0 09/21/2015 D. Bauer All Initial release. This Document revised from SF-13. 1 APPROVALS S. Cockcroft All 24.0 Inventories Update code references. Add. EMERGENCY RESPONSE PROGRAM (Emergency Action Plan (EAP) and Fire Prevention Plan) SOP: EHS-13 REV: 1 REFERENCES LIST OF EMERGENCY RESOURCES (Standard Operating Procedures)—the following list contains Thatcher Company "Standard Operating Procedures” pertaining to different aspects of possible hazards and/or contain elements of safety. EHS-01 Lockout/Tagout Program EHS-02 (SF-02) Confined Space Entry EHS-08 (SF-08) Preparing and Suiting Up in a HazMat Situation Requiring Self-Containment EHS-09 (SF-09) Disciplining and Documenting Safety and Conduct Violations EHS-11 (SF-11) Hazard Communication EHS-12 (SF-12) Respiratory Protection EHS-14 Security Program EHS-16 (SF-16) Storage of Incompatibles EHS-19 (SF-19) Bloodborne Pathogen Program EHS-26 Employee Injury and Illness Plan (IIPP) EHS-29 (IH-01) Recording and Reporting Chemical Releases EHS-47 (SF-25) Emergency Shutdown Procedures for SO2 and Ammonia Processes EHS-49 (SF-18) Chlorine Room Emergency Shutdown Procedures EHS-52 (MC-26) Solid and Liquid Waste Handling Procedure EHS-70 (MBE-40) Reuse of DOT Packaging Containers EHS-72 (HM-126) Hazardous Material Training and Certification PS-01 Process Safety Management PS-11 (SF-06) Accident/Incident Investigation OSHA 29 CFR 1910 Nevada NAC Ref. 459 FORMS INDEX FORMS Forms listed as the generic numbering with site specific forms, using site annotation, being created where applicable. EHS-13F1 Emergency Phone Numbers EHS-13F2 HazMat Emergency Response Team Members EHS-13F3 Adjacent Business EHS-13F4 Local, State, and National Emergency Phone Numbers EHS-13F5 Emergency Response Team Organization Flow Chart EHS-13F6 List of Doctors EHS-13F7 Thatcher Company Map EHS-13F8 Thatcher Company Evacuation Check-In Sheet EHS-13F9 Primary Evacuation Location EHS-13F10 Secondary Evacuation Location EHS-13F11 Building Evacuation Exits, Extinguishers, SCBAs, Eyewash/Showers EHS-13F12 Shut Down Operations (List of Buildings and Equipment that Must Be Shut Down Before Evacuation and the Person Responsible for Doing So) EHS-13F13 Thatcher Company Alarm System Information EHS-13F14 Thatcher Company Evacuation Map (Preferred Routes) EHS-13F15 Management Plan, Site Contacts and Document Control EHS-13F16 Risk Assessment LOGS None RECORDING AND REPORTING CHEMICAL RELEASES PAGE: 2 of 4 SOP: EHS-29 REV: 01 2.0 DEFINITIONS 2.1 Catastrophic Release—a major uncontrolled emission, fire, or explosion involving one or more regulated substances that present imminent and substantial endangerment to public health and the environment. All chemical spills or releases that cannot be immediately contained and can have an unbridled effect upon coworkers, the public, and/or the environment. 2.2 Chemical Spill or Release—any gas, liquid, or solid chemical that has been released from normal packaging containment, allowing it to be unintentionally released to the floor, ground, drainage systems, or air. 2.3 Emergency Response Release—all chemical spill or release that will leave or have the potential to leave Thatcher property thereby affecting the public. 2.4 Reportable Release—all chemical spills or releases that meet or exceed the reportable quantity established by the Environmental Protection Agency (EPA). This includes chemical spills or releases that cannot be contained in the immediate area or pose other health risks to employees. 3.0 REGULATION REQUIREMENTS 3.1 Chemical spills and releases are regulated by several federal (including OSHA, EPA, DOT), state, and local agencies (including the fire department). Their goal is to ensure companies do not harm their employees, that employees do not carelessly hurt others, that the public is protected from unknown harm, and the environment is safeguarded. To ensure compliance, each spill or release must be carefully documented. All spills will be documented using the steps and forms found in the Incident Investigation program (PS-11F1, 3, and 4) ensuring the material and concentration of the chemical spilled or released is listed along with how it was recovered and cleaned up. 3.2 Under 40 CFR 302.4 and 40 CFR 355 the federal government requires immediate notification of a release for certain hazardous chemicals greater than the Reportable Quantity (RQ). Follow-up reports are also required by the EPA as knowledge is gained throughout the release, the Reportable Release Report (EHS-29-F2) will be used to record the contact information of the regulatory agencies contacted. 3.3 Under state and local regulations the Fire Department, LEPC, and SERC must be immediately notified upon a hazardous chemical release, except for amounts less than the reportable quantities (RQ). The Reportable Release Report (EHS-29F2) will be used to record the contact information of the regulatory agencies contacted. 3.4 The EHS Manager shall archive the Reportable Release Report (EHS-29F2) along with the Incident Investigation Reports (PS-11F1, 3 and 4) for at least 5 years. 4.0 REPORTING AND DOCUMENTING REPORTABLE RELEASES AT THATCHER COMPANY 4.1 All chemicals spills or releases will be reported as soon as they happen. 4.1.1 The EHS Manager will be notified immediately to initiate the investigation. 4.1.2 The Area Supervisor will notify personnel to initiate chemical spill/release containment and cleanup. 4.2 The EHS manager will ensure reportable spills have been thoroughly documented and investigated by area managers and personnel involved. Limits of chemical release for key materials handled by Thatcher personnel are noted in the Reportable Quantities (RQ) List (EHS-29F1). For other chemical spills, the EHS Manager will provide exposure limits upon request. All reportable releases must be recorded and corrected in accordance with 4.1. 4.2.1 In addition, the Area Supervisor must immediately notify the Operations Manager or the acting Operations Manager on duty. 4.2.2 The Operations Manager shall take all precautions to protect other plant workers and contain the chemical. RECORDING AND REPORTING CHEMICAL RELEASES PAGE: 3 of 4 SOP: EHS-29 REV: 01 4.2.3 After the safety of plant workers has been secured, the Operations Manager shall in turn notify the EHS Manager or the EHS VP. 4.2.4 Reportable releases or spills mandate notification of federal, state, or local agencies. The EHS Manager shall make the required notifications and prepare written information in accordance with appropriate government mandates. The Reportable Release Report (EHS-29F2) must be filled out as soon as possible, preferably during the release or directly after. 4.3 In case of an emergency response release the employee(s) at the release should do all they can to SAFELY terminate and contain the release. 4.3.1 They should simultaneously notify key individuals on the Emergency Response list, found in posted areas beginning with the Area Supervisor and then down the list as appropriate to include owners, the HAZMAT team and the EHS Manager. 4.3.2 The EHS Manager will notify the appropriate agencies and will contact immediate neighbors that may be affected. The Reportable Release Report (EHS-29F2) will be used to document the agencies contacted and information given. 4.3.3 Employees associated with the spill or release will be required to properly document events using the initial incident form (PS-11F1) as soon as the chemical spill or release is contained. 4.4 For a catastrophic release or for fire, Thatcher Employees should immediately call 911 to report the situation. They should also simultaneously perform all items in 4.3. 4.5 The Reportable Release Reports (EHS-29F2) will be filed by the EHS Manager. The EHS Manager will then send a copy to Senior Management. 5.0 MEDIA COMMUNICATIONS AND EXTERNAL INFORMATION RELEASE 5.1 Except for an emergency report to 911, employees are not authorized to communicate corporate information outside the company. Emergency communications will be coordinated by the Company President through the EHS VP or Director. RECORDING AND REPORTING CHEMICAL RELEASES PAGE: 4 of 4 SOP: EHS-29 REV: 01 REVISION HISTORY Rev Date Author Section Affected Change Description 0 06/09/2016 D. Bauer / D. Yocom All Initial release. Document revised from IH-01. 1 APPROVALS S. Poulos D. Lindsey 2.0 Definitions 3.0 Regulations 4.0 Reporting 5.0 Media Remove near miss. Clarification of use of forms. Clarification of use of forms and update position titles. Update position titles. RECORDING AND REPORTING CHEMICAL RELEASES SOP: EHS-29 REV: 01 REFERENCES 40 CFR 68.3, Definitions of releases. 40 CFR 302.4, Designation of hazardous substances. 40 CFR 355, Emergency planning and notification. FORMS INDEX Forms and Logs listed as the generic numbering with site specific forms, using site annotation, being created where applicable. FORMS EHS-29F1 Reportable Quantities EHS-29F2 Reportable Release Report LOGS None APPENDIX B Solid and Hazardous Waste Management Plan Sign-off Sheet This document entitled Thatcher Company, Inc., Solid and Hazardous Waste Management Plan was prepared by Stantec Consulting Services Inc. (“Stantec”) for the account of Dorsey & Whitney LLP (“Attorney”) and Thatcher Company Inc. (the “Client”). Any reliance on this document by any third party is strictly prohibited. The material in it reflects Stantec’s professional judgment in light of the scope, schedule and other limitations stated in the document and in the contract between Stantec and the Client. The opinions in the document are based on conditions and information existing at the time the document was published and do not take into account any subsequent changes. In preparing the document, Stantec did not verify information supplied to it by others. Any use which a third party makes of this document is the responsibility of such third party. Such third party agrees that Stantec shall not be responsible for costs or damages of any kind, if any, suffered by it or any other third party as a result of decisions made or actions taken based on this document. Prepared by (signature) Richard Pratt Reviewed by ________________________________________ (signature) Dan Heiser Reviewed by (signature) Jen Cole Thatcher Solid and Hazardous Waste Management Plan i Table of Contents LIST OF ACRONYMS AND ABBREVIATIONS ........................................................................... VIII 1.0 INTRODUCTION ............................................................................................................. 1 1.1 ENVIRONMENTAL PROTECTION AGENCY AND STATE HAZARDOUS WASTE MANAGEMENT REGULATIONS ..................................................................................... 2 2.0 FACILITY HAZARDOUS AND UNIVERSAL WASTE GENERATOR STATUS ......................... 4 2.1 FACILITY HAZARDOUS WASTE GENERATOR STATUS .................................................... 4 2.2 FACILITY UNIVERSAL WASTE GENERATOR (HANDLER) STATUS .................................... 5 3.0 WASTE ANALYSIS AND DESIGNATION PLAN ................................................................ 6 3.1 GENERAL ADMINISTRATIVE WASTES ............................................................................. 7 3.1.1 Office and Lunchroom Wastes .................................................................. 7 3.1.2 Janitorial Products Including Aerosols and Waste from Their Use ........... 7 3.1.3 Industrial Lamp Bulbs .................................................................................. 7 3.1.4 Aerosol Paints, Cleaners, Lubricants, and Vent Filters .............................. 9 3.1.5 Spray Foam Insulation Aerosol Cans ........................................................10 3.1.6 Ni-Cad, Mercury, and Dry Lead Batteries ................................................10 3.1.7 Sealed Gel Lead Acid Batteries ...............................................................11 3.1.8 Carbon and Alkaline Batteries ..................................................................11 3.1.9 Lithium Batteries .........................................................................................11 3.1.10 Used Floor Dry or Sweeping Compound..................................................12 3.1.11 General Administrative Maintenance Wastes ........................................13 3.1.12 Pesticides ....................................................................................................13 3.1.13 Painting Wastes ..........................................................................................14 3.1.14 Sanitary Wastewater and Sludge .............................................................14 3.1.15 Warehouse Wastes ....................................................................................15 3.1.16 Safety-Health-Environment Department Wastes ....................................15 3.1.17 Fire Extinguisher Powder ............................................................................15 3.1.18 Used Computer Parts .................................................................................15 3.1.19 Waste Electrical Components ..................................................................16 3.1.20 Bio-Hazard Waste .......................................................................................17 3.1.21 Empty Product Containers ........................................................................17 3.1.22 Unusable New Products ............................................................................18 3.1.23 Chlorinated Fluorocarbons/Refrigerant ...................................................18 3.1.24 Refrigeration Unit CFCs Oil Waste .............................................................18 3.1.25 Asbestos ......................................................................................................19 3.1.26 Non-leaking Light Ballasts and Small Capacitors ....................................19 3.1.27 Transformer Oil (No-PCB and PCB Oil)......................................................20 3.1.28 Mercury Waste ...........................................................................................20 3.2 VEHICLE, MOBILE EQUIPMENT, AND SHOP WASTE .....................................................21 Thatcher Solid and Hazardous Waste Management Plan ii 3.2.1 Used Oil and Used Oil Burner Ash .............................................................21 3.2.2 Used Oil, Air, Diesel Fuel, Gasoline, and Coolant Filters ..........................23 3.2.3 Used Grease ...............................................................................................23 3.2.4 Used Floor Dry .............................................................................................24 3.2.5 Used Rags, Wipes, Absorbent Pads, and Socks ......................................24 3.2.6 Used Engine Coolant (Glycol-Based Antifreeze) ....................................25 3.2.7 Water-Sediment/Sludges from Sumps ......................................................25 3.2.8 Aerosol Paints, Cleaners, Lubricants, and Vent Filters .............................26 3.2.9 Contaminated or Waste Diesel Fuel ........................................................26 3.2.10 Contaminated or Waste Gasoline and/or Kerosene ..............................26 3.2.11 Empty Product Containers ........................................................................27 3.2.12 Lead Acid Batteries ...................................................................................27 3.2.13 Scrap Metal Including Welding Rod and Cuttings .................................28 3.2.14 Compressed Gas Cylinders .......................................................................28 3.2.15 Cold Cutting Fluid ......................................................................................28 3.2.16 Machine Tool Fluids ....................................................................................29 3.2.17 Spent Solvent (Water and/or Hydrocarbon-Based), Sludge, and/or Filters from Parts Washers or Bulk Solvent Use ..............................29 3.2.18 Hot Water Parts Washer Spent Filters, Water, Sludge, and Skimmer Waste ...........................................................................................30 3.2.19 Used Desiccants .........................................................................................31 3.2.20 Ni-Cad, Mercury, Dry Lead Batteries, or Sealed Gel Lead Acid ............31 3.2.21 Lithium Batteries .........................................................................................32 3.2.22 Carbon and Alkaline Flashlight Batteries .................................................32 3.2.23 General Maintenance Wastes .................................................................32 3.2.24 Chlorinated Fluorocarbons/Refrigerant ...................................................32 3.2.25 Refrigeration Unit CFCs Oil Waste .............................................................32 3.2.26 Paint-Related Materials Including Blasting Grit .......................................32 3.2.27 Pressure Washing Wastes ..........................................................................32 3.2.28 Air Cooler Filters ..........................................................................................33 3.3 TIRE REPAIR (TRUCK SHOP) ..........................................................................................33 3.3.1 Tire Cleaner and Adhesive ........................................................................33 3.3.2 Tire and Wheel Balance Weights ..............................................................33 3.3.3 Tire Prep Solution ........................................................................................34 3.3.4 Tires ..............................................................................................................34 3.3.5 Used Floor Dry .............................................................................................34 3.3.6 Used Rags, Wipes, Absorbent Pads, and Socks ......................................34 3.3.7 Empty Product Containers ........................................................................34 3.4 EQUIPMENT PAINTING .................................................................................................34 3.4.1 Painting Wastes ..........................................................................................34 3.4.2 Used Blasting Grit and/or Paint Chips ......................................................35 3.4.3 Empty Product Containers ........................................................................35 3.4.4 Used Rags, Wipes, Drop Cloths, and Masking Material ..........................35 Thatcher Solid and Hazardous Waste Management Plan iii 3.4.5 Aerosol Paints, Cleaners, Lubricants, and Vent Filters .............................36 3.4.6 Lead Based Paint Removal Waste ...........................................................36 3.5 MAINTENANCE .............................................................................................................36 3.5.1 Used Lubricating and Hydraulic Oil ..........................................................36 3.5.2 Used Grease ...............................................................................................37 3.5.3 Used Rags, Wipes, Absorbent Pads, and Socks ......................................37 3.5.4 Waste Paints and Painting Wastes ...........................................................37 3.5.5 Sand Blast Grit ............................................................................................37 3.5.6 Scrap Metal Including Welding Rod and Cuttings .................................37 3.5.7 Spent Solvent (water and/or hydrocarbon-based), Sludge, and/or Filters from Parts Washers or Bulk Solvent Use ..............................37 3.5.8 Industrial Lamp Bulbs .................................................................................37 3.5.9 Aerosol Paints, Cleaners, Lubricants, and Vent Filters .............................37 3.5.10 Cold Cutting Fluid ......................................................................................37 3.5.11 Used Floor Dry .............................................................................................37 3.5.12 Ni-Cad Batteries .........................................................................................37 3.5.13 Lithium Batteries .........................................................................................38 3.5.14 Carbon and Alkaline Batteries ..................................................................38 3.5.15 Sump Cleanouts .........................................................................................38 3.5.16 Tank and Vessel Cleanouts .......................................................................39 3.5.17 Used Rags, Wipes, Absorbent Pads, and Socks with Spray Solvent Waste (Used on Instrumentation) ................................................40 3.5.18 Hot Water Parts Washer Spent Filters, Water, Sludge, and Skimmer Waste ...........................................................................................40 3.5.19 Machine Tool Fluids ....................................................................................40 3.5.20 Lead Acid Batteries ...................................................................................40 3.6 LABORATORY ...............................................................................................................40 3.6.1 Used or Stored Excess Samples .................................................................41 3.6.2 Oil and Gas Industry Samples ...................................................................41 3.6.3 High Performance Liquid Chromatography Waste ................................41 3.6.4 Silver Nitrate Solution from Chloride Argentometric Analysis .................42 3.6.5 Chloroform Surfactant Titration.................................................................42 3.6.6 Dilute Metal Solutions ................................................................................43 3.6.7 Hydranal Solutions......................................................................................43 3.6.8 Lab Sink Drains and Neutralization Tank Wastewater Discharge ...........43 3.6.9 Unused Laboratory Chemicals .................................................................44 3.6.10 Laboratory Chemicals Desiccant and/or Activated Carbon Off Gas Filters ....................................................................................................45 3.6.11 Makeup Air Filters .......................................................................................45 3.6.12 Water Purification Cartridges and Compressor Desiccant Filters ..........45 3.6.13 Miscellaneous Titration and/or pH Buffer Solutions .................................45 3.6.14 Contaminated Personal Protection Equipment (PPE), Floor Sweepings, and/or Trash ...........................................................................46 Thatcher Solid and Hazardous Waste Management Plan iv 3.6.15 Hood Scrubber Solution.............................................................................46 3.6.16 Empty Reagent Containers .......................................................................47 3.6.17 Equipment Bulbs ........................................................................................47 3.6.18 Compressed Gas Cylinders .......................................................................47 3.6.19 Used Oil .......................................................................................................47 3.7 FUELING FACILITIES .......................................................................................................47 3.7.1 Collected Oil/Grease and Small Spills ......................................................47 3.7.2 Collected Diesel Fuel and Small Spills ......................................................47 3.7.3 Contaminated or Waste Gasoline and Small Spills .................................48 3.7.4 Collected Used Engine Coolant (Glycol-Based Antifreeze) and small Spills ...................................................................................................48 3.7.5 Used Floor Dry .............................................................................................48 3.7.6 Used Rags, Wipes, Absorbent Pads, and Socks ......................................48 3.7.7 Fuel Filters ....................................................................................................48 3.7.8 Aerosol Paints, Cleaners, Lubricants, and Vent Filters .............................48 3.7.9 Oily Water, Used Oil, Sediment/Sludges from Sumps ..............................48 3.8 CHEMICAL MANUFACTURING ....................................................................................48 3.8.1 Scrubber Solutions ......................................................................................50 3.8.2 Filter Press Wash Water/Sludge or Used Filter Press Components ..........50 3.8.3 Filter Press Cake .........................................................................................51 3.8.4 Dust Collectors or Bag Filters .....................................................................51 3.8.5 Area Sumps ................................................................................................52 3.8.6 Boiler Blowdown .........................................................................................52 3.8.7 Boiler Chemical Cleaning .........................................................................53 3.8.8 Demineralization Water Treatment and Reverse Osmosis Filter Cleaning Wash Water ...............................................................................53 3.8.9 Reverse Osmosis Water Filters ...................................................................54 3.8.10 Heat Exchanger, Cooling Tower, Chillers and/or Strainers Pressure or Acid Wash Waste ....................................................................54 3.8.11 Sodium Hypochlorite Cooling Tower Bleed .............................................55 3.9 UTILITIES AND RAW MATERIALS ....................................................................................55 3.9.1 Area Sumps and Water Treatment Containments ..................................55 3.9.2 Container Wash Areas ..............................................................................56 3.9.3 Water Treatment Filter Press ......................................................................57 3.9.4 Water Treatment Filter Cake .....................................................................57 3.9.5 Oil Water Separators ..................................................................................57 3.9.6 Sodium Hydroxide Reagents Area Sumps ...............................................57 3.9.7 Antiscalant Area Sump .............................................................................58 3.9.8 Acid Area Sumps .......................................................................................58 3.9.9 Miscellaneous Reagent Area Sumps .......................................................58 3.9.10 Boiler Solution (Heat Transfer Solution) .....................................................58 3.10 SPILL CLEANUP .............................................................................................................59 3.10.1 Soils or Cleanup Material Contaminated with Oil and/or Grease ........59 Thatcher Solid and Hazardous Waste Management Plan v 3.10.2 Soils or Cleanup Materials Contaminated with Diesel Fuel ....................60 3.10.3 Soils or Cleanup Materials Contaminated with Gasoline and/or Kerosene .....................................................................................................60 3.10.4 Soils or Cleanup Materials Contaminated with Alcohol .........................61 3.10.5 Soils or Cleanup Materials Contaminated with Oxidizer ........................61 3.10.6 Soils or Cleanup Materials Contaminated with Engine Coolant or Heat Transfer Solution ............................................................................62 3.10.7 Soils or Cleanup Materials Contaminated with Used Non-Listed Solvent ........................................................................................................62 3.10.8 Soils or Cleanup Materials Contaminated with Used Paint Thinner or F-Listed Cleaning Solvent .........................................................62 3.10.9 Soils or Cleanup Materials Contaminated with Unused Paint, Blended Commercial Formulations, or Chemical Mixtures ....................63 3.10.10 Soils or Cleanup Materials Contaminated with Acid ..............................63 3.10.11 Soils or Cleanup Materials Contaminated with Caustics and/or Lime .............................................................................................................64 3.10.12 Soils or Cleanup Materials Contaminated with Antiscalant ...................64 3.10.13 Soils or Cleanup Materials Contaminated with a Pure Chemical .........64 4.0 ACCEPTABLE SOLID WASTE (TRASH) FOR OFF SITE DISPOSAL ................................... 66 4.1 GENERAL DESCRIPTION OF ACCEPTABLE SOLID WASTES..........................................66 4.2 FACILITY CONSTRUCTION WASTES ..............................................................................66 4.3 TRASH ...........................................................................................................................66 4.4 PROHIBITED AND HAZARDOUS WASTE .......................................................................66 5.0 CONTAINER MANAGEMENT PLAN ............................................................................. 68 5.1 TYPES OF CONTAINERS ................................................................................................68 5.1.1 Intermediate Bulk Containers (IBC) or Roll-Offs .......................................68 5.1.2 55-Gallon Open-Top Drums ......................................................................68 5.1.3 55-Gallon Closed-Top Drums ....................................................................69 5.1.4 Salvage Drums (Used for Overpacks) ......................................................69 5.1.5 Universal Waste Containers.......................................................................69 5.1.6 Totes and Tanks ..........................................................................................69 5.2 MANAGEMENT OF CONTAINERS ................................................................................70 5.3 CONTAINER INSPECTIONS ...........................................................................................71 5.4 STORAGE LIMITATIONS .................................................................................................71 5.5 IGNITABLE OR REACTIVE WASTES ................................................................................72 5.6 INCOMPATIBLE WASTES ...............................................................................................72 6.0 PREPAREDNESS AND PREVENTION PLAN .................................................................... 73 6.1 HAZARDOUS WASTE STORAGE AREAS MAINTENANCE AND NORMAL OPERATION PROCEDURES ..........................................................................................74 Thatcher Solid and Hazardous Waste Management Plan vi 6.2 REQUIRED EQUIPMENT FOR OPERATION OF THE HAZARDOUS WASTE STORAGE AREAS ..........................................................................................................76 6.3 ARRANGEMENTS WITH LOCAL AUTHORITIES ..............................................................79 7.0 HAZARDOUS WASTE SATELLITE AND UNIVERSAL WASTE ACCUMULATION AREAS .......................................................................................................................... 80 8.0 PRE-TRANSPORT REQUIREMENTS AND RECORD KEEPING.......................................... 82 8.1 EPISODIC GENERATION REQUIREMENTS AND RECORD KEEPING .............................83 9.0 CONTINGENCY PLAN AND EMERGENCY PROCEDURES ............................................ 85 9.1 EMERGENCY COORDINATORS ...................................................................................85 9.2 EMERGENCY COORDINATOR ACTIONS .....................................................................86 9.3 EMERGENCY RESPONSE EQUIPMENT AND MATERIALS ..............................................89 9.4 EMERGENCY SPILL RESPONSE ACTIONS .....................................................................90 9.4.1 Emergency Spill Response Actions ...........................................................90 9.4.2 Internal Emergency Reporting ..................................................................91 9.5 EMERGENCY FIRE RESPONSE ACTIONS ......................................................................91 9.6 EMERGENCY EXPLOSION RESPONSE ACTIONS ..........................................................93 9.7 EVACUATION PLANS....................................................................................................93 9.8 EMERGENCY REPORTING PROCEDURES ....................................................................93 9.9 MANAGEMENT OF WASTES PRODUCED DURING AN INCIDENT RESPONSE .............96 9.10 COORDINATION WITH LOCAL AUTHORITIES ...............................................................96 9.10.1 Emergency Response Agency Waiver ....................................................97 9.11 AMENDMENT OF CONTINGENCY PLAN .....................................................................97 9.12 CONTINGENCY PLAN QUICK REFERENCE GUIDE ......................................................98 9.12.1 Emergency Coordinator Contact List ......................................................98 9.12.2 Emergency Communications ...................................................................98 9.12.3 Hazardous Waste Information ..................................................................98 9.12.4 Hazardous Waste Exposure ..................................................................... 100 9.12.5 Facility and Street Maps .......................................................................... 100 9.12.6 Hazardous Waste Quick Reference Guide Updates ............................ 101 10.0 PERSONNEL TRAINING ...............................................................................................102 10.1 INTRODUCTION .......................................................................................................... 102 10.2 HAZARDOUS WASTE MANAGEMENT JOB DESCRIPTIONS ........................................ 102 10.2.1 90-day Hazardous Waste Storage Areas Operator .............................. 103 10.2.2 Hazardous Waste Satellite Accumulation Operator ............................. 103 10.2.3 Hazardous Waste Shipper ....................................................................... 103 10.2.4 Universal Waste Operator ....................................................................... 103 10.3 TRAINING RECORD KEEPING ..................................................................................... 104 11.0 WASTE MINIMIZATION GUIDELINES ...........................................................................105 Thatcher Solid and Hazardous Waste Management Plan vii 11.1 MANAGEMENT SUPPORT ........................................................................................... 105 11.2 WASTE GENERATION ACCOUNTING ........................................................................ 105 11.3 ECONOMIC BENEFITS OF WASTE REDUCTION .......................................................... 106 11.4 WASTE MINIMIZATION ASSESSMENTS ......................................................................... 106 11.5 TECHNICAL WASTE MINIMIZATION INFORMATION ................................................... 107 11.6 IMPLEMENTATION OF WASTE REDUCTION APPROACH ........................................... 107 LIST OF TABLES Table 2.1 - Small Quantity Universal Waste Handler .............................................................. 5 Table 3.1 Buildings and Activities ...........................................................................................48 Table 4.1 - Prohibited and Acceptable Waste List ...............................................................67 Table 6.1 - Hazardous Waste Storage Areas Phone Locations ...........................................77 Table 6.2 - Hazardous Waste Storage Areas Fire Extinguisher Locations ............................77 Table 6.3 - Hazardous Waste Storage Areas Spill Kit or Equipment Locations ...................78 Table 9.1 - Building 16 Hazardous Waste Information ..........................................................98 Table 9.2 - Laboratory Hazardous Waste Information .........................................................99 Table 9.3 - Process North West Storage Area Hazardous Waste Information .................. 100 LIST OF APPENDICES APPENDIX A EMERGENCY CONTACT LIST ..................................................................... A.1 APPENDIX B CONTINGENCY PLAN MAPS ..................................................................... B.1 APPENDIX C HAZARDOUS WASTE MANAGEMENT PERSONNEL JOB TITLES .................. C.1 Thatcher Solid and Hazardous Waste Management Plan viii List of Acronyms and Abbreviations CFC Chlorinated Fluorocarbons CESQG Conditionally Exempt Small Quantity Generator CFR Code of Federal Regulations CRT Cathode Ray Tubes ˚F Degrees Fahrenheit DOT Department of Transportation ENU Elementary Neutralization Unit EPA Environmental Protection Agency HID High-Intensity-Discharge HP High-Pressure IBC Intermediate Bulk Container kg Kilogram lbs Pounds LDR Land Disposal Restriction LQG Large Quantity Generator mg/L Milligrams Per Liter PCS Petroleum Contaminated Soil PPE Personal Protective Equipment PPM Parts Per Million RCRA Resource Conservation and Recovery Act SDS Safety Data Sheet SHWMP Solid and Hazardous Waste Management Plan SQG Small Quantity Generator TC Toxicity Characteristic TCLP Toxicity Characteristic Leaching Procedure TOX Total Organic Halogens TPH Total Petroleum Hydrocarbons TSCA Toxic Substances Control Act TSDF Treatment, Storage, and Disposal Facilities UHWM Uniform Hazardous Waste Manifest UAC Utah Administrative Code VSQG Very Small Quantity Generator Thatcher Solid and Hazardous Waste Management Plan ix INTRODUCTION August 2020 Thatcher Solid and Hazardous Waste Management Plan 1 1.0 INTRODUCTION This Solid and Hazardous Waste Management Plan (SHWMP) presents information on the generation, characterization, management, and disposal of the waste streams generated by Thatcher Company, Inc. (Thatcher). This document represents the chemical manufacturing and distribution facility plan for compliance with the federal and State of Utah solid and hazardous waste management regulations applicable to chemical facility activities. Thatcher produces a diversified range of products supporting industries such as oil/gas, water treatment, laundry, pharmaceutical, and food/dairy. These products include mainly inorganic chemical compounds, surfactants, concrete admixtures, disinfecting agents, soaps, and detergents. The Thatcher’s facility is located at 1905 Fortune Road, Salt Lake City, Utah. The complex nature of the hazardous waste regulations requires detailed planning, procedures, and documentation. This document is intended for use by facility personnel familiar with and responsible for the facility’s solid and hazardous waste management. The following is a summary of material management practices in this plan: • Acceptable non-hazardous solid wastes (trash) are disposed in trash containers on site and transported for disposal off site at permitted county landfills/transfer stations. Acceptable non-hazardous solid wastes with free liquids must be solidified/dried before disposing in the trash. • Hazardous wastes are disposed off site at permitted hazardous waste incineration and/or landfill disposal facilities. • Universal wastes are recycled off site at permitted universal waste handling facilities. • Designated non-hazardous wastes are disposed off site at approved facilities. • Used oil is recycled off site at approved facilities. • Used coolant (antifreeze) is recycled on site or off site at approved facilities. • Petroleum contaminated soils (PCS) are containerized and disposed of off site at approved facilities. • Recyclable materials may be recycled off site at approved facilities (e.g., electronics, cardboard, aluminum, paper, ink cartridges). • Sanitary wastewater is piped to the local Publicly Owned Treatment Works (POTW). INTRODUCTION August 2020 Thatcher Solid and Hazardous Waste Management Plan 2 • Materials meeting the wastewater discharge permit parameters are treated and discharge to the POTW under the permit number SLC-0001. • Contractor wastes will comply with the Utah Hazardous Waste Regulations. When needed, Thatcher will provide guidance to assist contractors in the proper management of waste generated from each project. Ultimately, contractors are responsible for the solid and hazardous wastes generated from contracted services as described in the contract general terms and conditions. Potential wastes will be identified prior to commencement of work. Acceptable non-hazardous solid wastes (trash) are disposed off-site in permitted landfills. Acceptable non-hazardous solid wastes with free liquids must be solidified/dried before disposing in the trash. Wastes may be approved by Thatcher for management with Thatcher materials or wastes (i.e., used oil, non-hazardous trash, and PCS). • Waste minimization is practiced at the Thatcher facility, and materials are recycled when possible and practical. Any business that generates a waste is required by Title 40 of the Code of Federal Regulations (CFR) Part 262.11 / Utah Administrative Code (UAC) R315-262-11 to determine if the waste is a hazardous waste. Laboratory analyses of various process and waste streams have been used to make the hazardous waste determinations for Thatcher, which are reported in this document. Additional process and waste stream sampling is completed on an as-needed basis. The original laboratory analytical results obtained from wastes sampled and analyzed for this plan are located in the records archive of Thatcher’s Environmental Health and Safety Department. Thatcher samples its waste streams as necessary to comply with the above regulations. Waste streams were reviewed, inventoried, and identified for sampling in this report. 1.1 ENVIRONMENTAL PROTECTION AGENCY AND STATE HAZARDOUS WASTE MANAGEMENT REGULATIONS Utah's authorized version of the 1976 Federal Resource Conservation and Recovery Act (RCRA) regulations are contained in the Utah Hazardous Waste Management Regulations. The regulations are enforced in Utah by the Department of Environmental Quality (UDEQ), Division of Waste Management and Radiation Control (DWMRC) located in Salt Lake City, Utah. The U.S. Environmental Protection Agency (EPA), through its Region Eight office in Denver, Colorado, has oversight and audit authority over the Utah program. Federal government control of hazardous waste is derived from authority granted by the Resource Conservation and Recovery Act (RCRA). The federal hazardous waste regulations applicable to waste generators are found in 40 CFR Parts 260, 261, 262, 265, 266, 268, 273, 279, and 280. The UDEQ, DWMRC regulations applicable to waste generators are found in Utah Administrative Code (UAC) R315 - 260, 261, 262, 265, 266, 268, 273, 279, and 280. INTRODUCTION August 2020 Thatcher Solid and Hazardous Waste Management Plan 3 40 CFR Part 262/UAC R315-262 requires a waste generator to characterize its waste products to determine if they are hazardous wastes. This requires a review of 40 CFR Part 261/UAC R315-261 to determine if the wastes are defined as solid wa stes (note: the regulatory definition of a solid waste includes liquids and compressed gasses) and 40 CFR 261 Subpart D /UAC R315-261-(30-33 and 35) to determine if the solid wastes are specifically listed as hazardous wastes. If the wastes are solid wastes and not specifically listed as hazardous wastes, the waste must then be reviewed according to the methods set forth in Subpart C of 40 CFR Part 261/UAC R315-261-(20- 24). This testing is generally referred to as the "characteristic tests" (see Section 3.0). FACILITY HAZARDOUS AND UNIVERSAL WASTE GENERATOR STATUS August 2020 Thatcher Solid and Hazardous Waste Management Plan 4 2.0 FACILITY HAZARDOUS AND UNIVERSAL WASTE GENERATOR STATUS 2.1 FACILITY HAZARDOUS WASTE GENERATOR STATUS Generators of hazardous wastes are classified and subsequently regulated dif ferently based on the quantity of wastes generated on a monthly basis. The economic, legal, and practical differences between generator classifications may be substantial. Generators are categorized according to the amount of hazardous waste and acutely hazardous waste the facility generates during a calendar month. The quantity limits apply to the total weight of hazardous and acute hazardous wastes generated from all sources on site and may also include some material designated for reuse or recycling unless specifically exempted, such as lead acid batteries. A fully regulated generator is a Large Quantity Generator (LQG) that generates more than 1,000 kilograms (kg) (2,200 pounds [lbs]) of hazardous waste, 1 kg (2.2 lbs) of acute hazardous waste, or 100 kg (220 lbs) of acute hazardous waste cleanup residue per calendar month. A Small Quantity Generator (SQG) generates between 100 kg and 1,000 kg (220 lbs and 2,200 lbs) of hazardous waste, 1 kg (2.2 lbs) of acute hazardous waste or 100 kg (220 lbs) of ac ute cleanup residue per calendar month. A Very Small Quantity Generator (VSQG) generates 100 kg or less (less than 220 lbs) of hazardous waste, 1 kg (2.2 lbs) of acute waste, or 100 kg (220 lbs) of acute cleanup residue per calendar month. LQGs and SQGs have varying restrictions on handling, accumulation, and disposal of hazardous wastes. They also have recordkeeping, reporting, employee training, emergency planning, and emergency procedures requirements. VSQGs have few restrictions on handling and disposal of hazardous waste. Based on inspections and internal accounting, Thatcher is classified as an LQG. LQGs must comply with parts of the federal and state hazardous waste regulations related to identification of their wastes, use of proper containers, appropriate storage conditions, accurate markings and labeling, use of hazardous waste manifests, emergency response, training, and proper disposal of the wastes. The facility has recently updated its generator status with UDEQ and is in the process of complying with all of these requirements. LQGs cannot store hazardous waste onsite for more than 90 days. This document describes the waste management activities at Thatcher and has been designed to comply with the hazardous waste management regulations applicable to LQGs. Thatcher has notified the EPA and the UDEQ regarding its waste generating activities and has been assigned the following EPA Identification Number: UTD041307356. August 2020 Thatcher Solid and Hazardous Waste Management Plan 5 2.2 FACILITY UNIVERSAL WASTE GENERATOR (HANDLER) STATUS Thatcher is a small quantity universal waste handler. A small quantity universal waste handler is defined as a facility that does not accumulate more than 5,000 kilogram of universal waste (batteries, pesticides, thermostats, lamps/bulbs, or mercury containing equipment calculated collectively) at any one time. Regulatory requirements for small quantity universal waste handlers are summarized in the following in table. Table 2.1 - Small Quantity Universal Waste Handler Record 40 CFR Regulatory Citation/UAC Small Quantity Handlers Retention Period Notification to EPA 273.12 and 32 / R315-273- 12and32 Not Required Not applicable Universal waste generator status 273.9 / R315- 273-9 11,000 lbs on site at any time At minimum, have a record of waste on site during calendar year; recommend three years Accumulation time limits 273.15 and 35 / R315-273-15 and 35 Method in place to demonstrate the waste has been accumulated no longer than 12 months At minimum, have a record while waste is on site; recommend three years Employee Training 273.16 and 36 / R315-273-16 and 36 Inform employees on proper handling and emergency procedures for the universal wastes on site No record required to be kept but recommend keeping with other employee waste training records Off-site shipments 273.19 and 39 / R315-273-19 and 39 Not required to keep records of shipments but recommend records be kept Recommend three years WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 6 3.0 WASTE ANALYSIS AND DESIGNATION PLAN This section describes the chemical manufacturing processes with the associated waste streams. Each waste stream is further detailed with its characteristics, classification, disposal requirements and analysis (as required). Where applicable, the waste handling and shipping information is also included. Solid waste (40 CFR 261.2 / R315-261-2) will be characterized in accordance with the Resource Conservation and Recovery Act (RCRA), the Utah Solid and Hazardous Waste Act (USHWA) statutory standards, the Environmental Protection Agency (EPA), and UDEQ DWMRC regulations promulgated thereunder. Any business that generates a solid waste is required by 40 CFR 262.11 / R315-262-11 to determine if that material designated for management as a hazardous waste. A hazardous waste is defined in 40 CFR Part 261 as part of waste analysis and designation. The generator is required to use the following steps to determine if the waste: • Is excluded from regulation under 40 CFR Part 261.4 / R315-261-4; • Is listed as a hazardous waste under Subpart D of 40 CFR Part 261 / R315-261; • When tested, exhibits any of the characteristics of a hazardous waste under Subpart C of 40 CFR 261 / UAC R315-261-(20-24); and • Can be is classified under Subpart C of 40 CFR 261 / UAC R315-261 based on generator’s knowledge of the hazard characteristic of the waste. Testing of process waste streams is generally referred to as “characteristic testing.” These analyses include: ignitability (flash point of 140 degrees Fahrenheit [˚F] or below), corrosivity (pH less than or equal to 2.0 or greater than or equal to 12.5), reactivity (unstable, water reactive, potentially explosive, can generate toxic gases, etc.); and Toxicity Characteristic (TC), Toxic Characteristic Leaching Procedure (TCLP) Toxicity (a waste extraction process used to evaluate waste content for 8 leachable metals, 25 organics, and selected pesticides and herbicides). If the waste is not excluded from regulation and is determined to be a hazardous waste, the generator must refer to 40 CFR parts 261, 264, 265, 266, 268, and 273 / R315 - 261, 264, 265, 266, 268, and 273 for possible exclusions or restrictions pertaining to management of the specific waste. The Land Disposal Restrictions found in part 268 apply to all hazardous wastes intended for landfill disposal and incineration (ash residues from incineration are land disposed). Based on the characterization, an appropriate management method (use, recycling, and/or disposal) will be identified which complies with applicable legal requirements and is protective of human health and the environment. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 7 Non-hazardous wastes generated at the facility are disposed off site in permitted or approved facilities. Hazardous wastes are stored at the designated LQG 90-day storage facility prior to disposal off site. Each waste stream is characterized to determine classification and appropriate management practice. The following sections document the waste analysis and designation efforts made by Thatcher operations on all process and waste streams typically produced at the property. 3.1 GENERAL ADMINISTRATIVE WASTES Description: There are various wastes that are generally produced in all working locations of the property including the administration buildings and the other chemical manufacturing areas. These common, general wastes are described in this section. 3.1.1 Office and Lunchroom Wastes Characteristics: Waste paper, metal, plastic, cardboard, wood, wrapping and packaging, waste copier toner, waste laser printer toner/developers, hardened white- out, hardened adhesives, food scraps and lunchroom trash. Classification: Typically, non-hazardous solid waste, however, non-empty containers of hazardous products may be hazardous wastes when disposed. Disposal: Non-hazardous trash is discarded in the trash. Non-empty containers should be disposed as required for the material characteristics. Analyses: Not required, use product labels and Safety Data Sheets (SDSs) for chemical products that are discarded. 3.1.2 Janitorial Products Including Aerosols and Waste from Their Use Characteristics: Many janitorial products contain chemicals that may be hazardous. In normal use, these products are either used consumptively or diluted in water. See Section 3.1.4 for characterization and handling of aerosols. Classification: Products used following instructions on labels do not constitute disposal, and wastes from normal use of products are typically diluted enough to not exhibit hazardous characteristics. Discarded, full-strength janitorial products may exhibit hazardous characteristics of ignitability (D001), corrosivity (D002), reactivity (D003), or TCLP toxicity (D004-D043). Disposal: Non-hazardous wastes can be thrown in the trash or the sanitary wastewater system as directed by the manufacturers' directions. Discarded, unused products should be characterized by review of product labeling or SDSs and containerized and disposed as appropriate. Analyses: Not required; constituents can be determined from SDSs. 3.1.3 Industrial Lamp Bulbs Characteristics: High-Pressure (HP) sodium High-Intensity-Discharge (HID), mercury vapor HID, metal halide HID bulbs, fluorescent tubes, Compact Fluorescent Lamps (CFL), Light-Emitting Diode (LED), and incandescent bulbs. It is WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 8 Thatcher policy to only use non-hazardous TCLP compliant HIDs or fluorescent bulbs. Classification: Some remnant “silver-tipped” fluorescent tubes/lamps on-site may have been some of the first tubes/lamps manufactured with mercury below the RCRA regulatory level and may be non-hazardous solid waste. Intact or broken fluorescent tubes/lamps with the silver ends are typically TCLP hazardous wastes for mercury (D009); HP sodium, mercury vapor, and metal halide are TCLP toxic for mercury (D009) and lead (D008); CFL’s may exceed the TCLP toxic level for mercury (D009); CFL’s and LED’s are TCLP toxic for lead (D008), if not managed as universal waste under 40 CFR Part 273 / R315-273. Contact the Safety-Health-Environment Department for classification of fluorescent tubes/lamps with silver ends. The “silver-tipped” fluorescent tubes marked “TCLP Compliant,” “green- tipped” fluorescent tubes, and incandescent bulbs are non-hazardous solid waste. Philips HID bulbs marked “Alto” and other manufactures HID bulbs marked “TCLP compliant” have passed a TCLP test and are non- hazardous. Tubes and bulbs crusher filters are TCLP toxic for mercury (D009). Disposal: Non-hazardous Waste Non-hazardous incandescent bulbs are placed in the trash and/or recycled. Hazardous Waste Hazardous waste bulbs/tubes and /or broken bulbs/tubes are accumulated in drums marked/labeled “Hazardous Waste Used Lamps” prior to off-site management at an approved disposal facility. Universal Waste Fluorescent tubes, HP sodium, mercury vapor, metal halide lamps, CFL’s, and LED’s are accumulated at the warehouse or other designated areas in containers marked/labeled “Universal Waste Used lamps” prior to off- site management at an approved universal waste management facility. Analyses: Not required, if constituents can definitely be determined from SDSs. If constituents cannot be determined from SDSs, apply generator knowledge, use previous characterization information, and/or sample and test for TCLP metals. Waste Handling: Hazardous Waste Broken bulbs/tubes hazardous wastes will be collected in drums having properly completed EPA hazardous waste markings including the accumulation start date when the drums are full. Containers are stored in a designated area within the hazardous waste storage area or other designated areas until they are shipped to a designated or a permitted Treatment, Storage, and Disposal Facility (TSDF). Universal Waste Universal wastes are accumulated in original packaging or in an approved container. Mark containers with a properly completed EPA universal waste marking (sticker) including the date the waste is first put in the container (accumulation start date). Containers are stored in a designated area until they are shipped to a designated Universal Waste WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 9 recycling facility (once per year). Universal waste cannot be stored on-site for greater than 12 months. Shipping: Container DOT Specification: Hazardous Waste UN/1A2. Universal Waste Original shipping container or other designation. Waste Code: Hazardous Waste: D008 and D009. Universal Waste: Does not apply to universal waste. Shipping Name: See waste profile. 3.1.4 Aerosol Paints, Cleaners, Lubricants, and Vent Filters Characteristics: Aerosol paints, cleaners, lubricants, and vent filters may contain listed chemicals. Additionally, material in aerosol cans may be ignitable (D001) and/or reactive (D003). Vent filters contain carbon and adsorbed vapors. It is company policy to minimize use of chlorinated and/or regulated aerosol solvents. Classification: Empty aerosol containers (approaching atmospheric pressure) are non- hazardous, solid waste. Unused, discarded products are hazardous if they contain a U- or P-listed chemical as the sole active ingredient or fail RCRA characteristics. Non-empty aerosols (empty of product but still containing propellant) may be hazardous due to characteristics of ignitability and/or reactivity. Spent vent filters are listed hazardous waste and/or exhibit hazardous waste characteristics. Disposal: Aerosol products are sprayed onto surfaces then allowed to dry or wiped- off with rags. Partially full potentially non-useable aerosol products are collected to determine if the products are still usable or if they are unusable or spent. All unusable or spent aerosol cans are emptied with a can puncturing device (the satellite accumulation container under these devices is under the management of a designated operator). Punctured empty cans are thrown in the trash or recycled as scrap metal. Spent vent filters are accumulated separately for disposal. Analyses: Apply generator knowledge, use previous characterization information, SDS, and/or sample and test aspirated liquids/solids for TCLP metals, F- and D-list total volatiles, F- and D-list total semi-volatiles, and ignitability. Waste Handling: Liquid hazardous wastes are collected in closed-top drums and spent vent filters are collected in open-top drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Drums containing flammable liquids must be grounded when adding or removing waste. Shipping: Container DOT Specification: Liquids UN/1A1 and vent filters UN/1A2 Waste Code(s): Varies with constituents. Shipping Name: See waste profiles. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 10 3.1.5 Spray Foam Insulation Aerosol Cans Characteristics: Insulating foam aerosol cans containing foam constituents. Additionally, material in aerosol cans may be ignitable (D001) and/or reactive (D003). Classification: RCRA-empty containers (approaching atmospheric pressure) are non- hazardous, solid waste. Non-empty aerosols (empty of product but still containing propellant) may be hazardous due to characteristics of ignitability and/or reactivity. Disposal: Aerosol products are used for their intended purpose. Partially full potentially non-useable aerosol products are collected to determine if the products are still usable or if they are unusable. All unusable insulating foam aerosol cans are accumulated for disposal. Analyses: Not required, constituents can be determined from SDS. Waste Handling: Insulating foam aerosol cans hazardous wastes are collected in open-top drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Shipping: Container DOT Specification: UN/1A2 Waste Code(s): Ignitability (D001) and reactivity (D003). Shipping Name: See waste profile. 3.1.6 Ni-Cad, Mercury, and Dry Lead Batteries Characteristics: NiCad batteries contain alkaline materials and cadmium. Dry lead (non- lead acid) and mercury batteries contain lead and mercury respectively. Classification: Recycled NiCad, dry lead, and mercury batteries are subject to the Universal Waste management standards located in 40 CFR Part 273 / R315-273. Discarded Ni-Cad batteries containing cadmium hazardous waste characteristic (D006), mercury batteries containing hazardous characteristic (D009), and dry lead batteries containing hazardous waste characteristic (D008) are regulated for hazardous waste characteristics, unless managed as universal wastes. Disposal: Accumulated and recycled as Universal Wastes. Analyses: Not required; constituents can be determined from SDSs. Waste Handling: Handle batteries carefully to prevent damage. All batteries are placed in plastic bags or terminals are taped to prevent terminals from contacting and to prevent short circuits. Used Ni-Cad and mercury batteries are collected and stored in plastic containers at designated locations on-site and managed as universal waste. Universal waste cannot be stored on- site for greater than 12 months. Universal Waste Batteries are collected in containers marked with the words "Universal Waste Used Batteries (Ni-Cad, Dry Lead, or Mercury Batteries Only)" or returned to the vendor for recycling. Shipping: Container DOT Specification: UN 1H2. Waste Code: Not applicable to Universal Waste. Varies with hazardous waste battery type: Ni-cad (D006), Mercury (D009) and Lead (D008). Shipping Name: See waste profile. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 11 3.1.7 Sealed Gel Lead Acid Batteries Characteristics: Sealed gel lead acid batteries contain lead and acid. Classification: Undamaged non-leaking batteries are recyclable materials under 40 CFR 261.6 / R315-261-6 or universal waste under 40 CFR Part 273 / R315-273. Damaged or leaking batteries are hazardous waste due to the characteristics of lead (D008) and corrosivity (D002). Disposal: Handle sealed gel lead acid batteries carefully to prevent damage and potential acid spills. All batteries are place in plastic bags or terminals are taped to prevent terminals from contacting and to prevent short circuits. Recycled Batteries Used batteries are stored in on-site specified locations (shops or warehouse yards) prior to being returned to vendors for recycling when a new battery is obtained. Universal Waste Batteries are handled as universal waste under 40 CFR Part 273 / R315-273 when a new battery is obtained. Used sealed gel lead acid batteries are collected and stored in a plastic container, at the warehouse. Hazardous Waste Damaged leaking batteries are containerized and disposed as hazardous waste. Each broken battery must be packaged in a separate plastic pail. Analyses: Not required; constituents can be determined from SDSs. Waste Handling: Hazardous Waste Hazardous waste damaged or leaking batteries are collected in separate plastic pails placed in plastic drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Universal Waste Universal waste batteries are collected on-site in containers marked with the words "Universal Waste Used Batteries (“Sealed Gel Lead Acid Batteries Only"). Mark the universal waste container with the date the waste is first put in the container. Universal waste cannot be stored on-site for greater than 12 months. Shipping: Container DOT Specification: UN/1H2. Waste Code: Not applicable to universal waste. D008 (10 lbs) and D002 (100 lbs) for hazardous waste. 3.1.8 Carbon and Alkaline Batteries Characteristics: Lamp and other miscellaneous batteries. Classification: Rayovac zinc-carbon and alkaline batteries SDSs indicates waste batteries are non-hazardous, solid wastes. Disposal: Batteries are discarded in the trash. Analyses: Not required; constituents can be determined from SDSs. 3.1.9 Lithium Batteries Characteristics: Spent lithium ion batteries contain reactive and ignitable lithium. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 12 Classification: Recycled lithium batteries are subject to the Universal Waste Management Standards located in 40 CFR Part 273 / R315-273. Discarded lithium batteries containing reactive lithium are regulated for hazardous waste characteristics of ignitability (D001) and reactivity (D003), unless managed as universal wastes. Disposal: Used lithium batteries are collected and stored in a plastic container, at the designated location on-site and managed as universal or hazardous waste. If disposed as a waste, they should be handled as hazardous waste. Handle lithium batteries carefully to prevent damage. All batteries are place in plastic bags or terminals are taped to prevent terminals from contacting and to prevent short circuits. Analyses: Not required; constituents can be determined from SDSs. Waste Handling: Hazardous Waste Hazardous wastes will be collected in drums having properly completed EPA hazardous waste markings including the accumulation start date when the drums are full. Containers are stored in a designated area within the hazardous waste storage area or other designated areas until they are shipped to a designated or a permitted Treatment, Storage, and Disposal Facility (TSDF). Universal Waste Universal waste batteries are collected in containers marked with the words "Universal Waste Used Batteries (Lithium Batteries Only)". Mark the container with the date the waste is first put in the container. Universal waste cannot be stored on-site for greater than 12 months. All batteries are place in plastic bags or terminals are taped to prevent terminals from contacting and to prevent short circuits. Shipping: Container DOT Specification: UN/1A2 or UN/1H2. Waste Code: D001 and D003 if disposed as hazardous waste. Not applicable to universal waste. Shipping Name: See waste profile. 3.1.10 Used Floor Dry or Sweeping Compound Characteristics: Varies with wastes absorbed. Material may contain oil, TCLP toxicity materials, or listed solvents or fuels. Listed solvents are typically not used at the mine. Classification: Normally non-hazardous solid waste; however, if contaminated with TCLP toxicity materials or listed solvents or other hazardous materials, the floor dry or sweeping compound may be regulated as a hazardous waste when discarded. Disposal: Non-draining (no free liquid) non-hazardous floor dry is routinely discarded in the trash; however, large quantities generated from a spill cleanup are containerized for characterization prior to disposal. Floor dry or sweeping compound known to be contaminated with listed solvents or other hazardous wastes should be segregated, containerized, and handled as hazardous waste. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 13 Analyses: Normally not required except for characterization of potentially contaminated floor dry. For spill cleanup waste characterization, review of SDSs and/or testing may be required to determine regulatory status. Waste Handling: Hazardous wastes are collected in open-top drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Shipping: Container DOT Specification: UN/1A2. Waste Code: Varies with waste analyses. Shipping Name: See waste profile. 3.1.11 General Administrative Maintenance Wastes Characteristics: Wastes produced from general maintenance of buildings including wood, air filters, glass, pieces of metal, masonry, fiberglass and foam insulation (except unused spray foam insulation aerosol cans), adhesives, yard care products, hardware, and packaging. Classification: Normally non-hazardous solid waste, however, if contaminated with F- listed solvents or other hazardous materials, the wastes may be regulated as a hazardous waste when discarded. Disposal: Routinely discarded in the trash, however, wastes known to be contaminated with F-listed solvents or other hazardous wastes should be segregated, containerized, and handled as hazardous waste. Analyses: Normally not required except for characterization of potentially contaminated wastes. For contaminated waste characterization, review of SDSs and/or testing may be required to determine regulatory status. 3.1.12 Pesticides Characteristics: Small amounts of waste insecticides, herbicides, or rodenticides remaining in RCRA empty containers. The facility only uses small amounts of these materials. Classification: Waste pesticides typically contain products that classify them as hazardous waste. These materials are regulated by the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA) and RCRA. Recalled pesticides and pesticides collected and managed as part of a waste pesticide collection program are subject to the universal waste management standards located in 40 CFR Part 273 / R315-273 if not handled as hazardous waste. Disposal: These products should be entirely used as intended whenever possible. Unused waste pesticides should be handled as hazardous wastes according to the manufacturers' recommendations. Pesticide containers should be RCRA empty (see Section 3.1.21.) before being disposed in the trash. Aerosol cans should be at atmospheric pressure when disposed. Analyses: Not required, use manufacturer labels or SDSs. Waste Handling: Hazardous wastes are collected in open-top lab pack drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Shipping: Container DOT Specification: Various use SDS. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 14 Waste Code: Various use SDS. Shipping Name: Various SDS. 3.1.13 Painting Wastes Characteristics: Waste paint, thinners, paint brushes or rollers, masking material, rags, wipes, and containers. Classification: Latex (water-based) paint wastes are typically non-hazardous, solid wastes. Oil-based painting related materials are typically hazardous wastes. Most oil-based product reducers or thinners are hazardous due to ignitability or listed solvent content. Spent reducers or thinners that contain 10 percent or more of F-listed solvent prior to use are F-list solvent hazardous waste. Oil-based paints may be hazardous due to ignitability (D001), TCLP characteristic for lead (D008) or chromium content (D007). Epoxy hardeners may be characteristic hazardous waste for corrosivity (D002). Disposal: Discard latex paints, containers, and painting wastes as solid wastes in the trash after allowed to dry. Other waste paints, reducers, and thinners that are either listed or have hazardous characteristics should be disposed as hazardous waste at a RCRA-permitted facility. Epoxies should be classified and disposed accordingly. Painting wastes (applicators, rags, masking material, and empty containers) produced in the use of oil- based paints may be hazardous if still wet when disposed. Analyses: Apply generator knowledge; use previous characterization information, SDS, and/or sample and test potentially hazardous painting wastes for TCLP metals, F- and D-list total volatiles, F- and D-list total semi-volatiles and ignitability. Waste Handling: Solid hazardous wastes will be collected in open-top drums (UN/1A2). Liquid hazardous wastes will be collected UN/1A1 drums. These drums will have properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Shipping: Container DOT Specification: UN/1A2 (solid) or UN/1A1 (liquid). Waste Code: Varies with waste constituents. Shipping Name: See waste profile. 3.1.14 Sanitary Wastewater and Sludge Characteristics: Wastewater/sludge from toilets, sinks, eye wash stations, and showers. Classification: Typically, non-hazardous. Listed hazardous wastes or materials that would be a characteristic hazardous waste may render wastewater/sludge hazardous and should not be disposed down toilets, sinks or showers. Disposal: Sanitary wastewater is discharged through piping to the local publicly owned treatment works. Analyses: Not required. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 15 3.1.15 Warehouse Wastes Characteristics: Unusable new products or materials that cannot be returned to the vendors. Classification: Inert parts and materials are typically non-hazardous solid waste. Chemical products may be non-hazardous solid waste but may also be listed hazardous wastes or characteristic hazardous wastes. Disposal: Non-hazardous solid wastes are thrown in the trash. Chemical products should be disposed according to typical operating practices or according to SDS recommendations. Analyses: Not required, follow label or SDS recommendations. 3.1.16 Safety-Health-Environment Department Wastes Characteristics: Empty calibration gas cylinders, empty vials that contained sam ple preservative chemicals, environmental analyses kits, and used Draeger type sample or smoke tubes. Classification: RCRA empty containers are solid waste. Used Draeger type sample or smoke tubes may be non-hazardous solid waste but may also be listed hazardous wastes or characteristic hazardous wastes. Disposal: Non-hazardous solid wastes are thrown in the trash. Chemical products should be disposed according to SDS recommendations. Analyses: Not required, follow label or SDS recommendations. 3.1.17 Fire Extinguisher Powder Characteristics: Dry-type fire extinguisher powder removed when servicing fire extinguishers. Classification: Non-hazardous material. Disposal: Recycled back into extinguishers. Analyses: Not required, follow SDSs for proper handling. 3.1.18 Used Computer Parts Characteristics: Cathode Ray Tubes (CRTs) monitors, used computers, and circuit boards (e-waste) contain TCLP metals. Electrical components include a variety of electrical and electronic components for example, instrumentation electronic components. Classification: Varies with type and construction of component. Typically electrical components are non-hazardous solid waste but could contain TCLP metals such as mercury, silver, or lead. Whole Used Circuit Boards The scrap metal exemption applies to whole used circuit boards that contain minor battery or mercury switch components and that are sent for continued use, reuse, or recovery under 40 CFR 261.6 (a)(3)(ii) / R315-261- 6, RCRA Hotline fax back (14155), and (May 26, 1998, 63 FR 28556). Used, Intact CRTs WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 16 Used intact CRT monitors are not solid waste unless they are disposed under 40 CFR 261.4 (a)(22) / R315-261-4. Used, Broken CRTs Used, broken CRT monitors are not solid waste provided that they meet the requirements of 40 CFR Part 261.39 / R315-261-39. Documentation must be on file from the recycling facility to show how recycling is accomplished. Hazardous Waste CRTs CRT monitors waste is hazardous waste for lead (D008) if not recycled. Disposal: Do not dispose recyclable e-waste in the trash. Material is accumulated in containers for off site recycling. E-waste known to be contaminated with hazardous wastes is segregated, containerized, and handled as hazardous waste if not recycled. Analysis Not required; constituents can be determined from SDSs. Waste Handling: Recyclable Material: Place used computer parts in cubic yard boxes on pallets and secure. Label the boxed as “Used computer monitors and electronic equipment.” Used, broken CRTs should be placed in boxes labeled, “Used cathode ray tube(s)-contains leaded glass” and do not mix with other glass materials.” Hazardous Waste: Hazardous wastes will be collected in DOT specification cubic yard boxes. These boxes will have properly completed EPA hazardous waste markings, including the accumulation date when the box contains more than 7.4 cu. ft. (estimated 55-gallons) of waste. Shipping: Container DOT Specification: Recyclable Material: Non-DOT specification containers may be used. Hazardous Waste: DOT specification cubic yard boxes. Waste Code: CRTs - Lead (D008) and other various waste codes with identified waste constituents. Shipping Name: See waste profile. 3.1.19 Waste Electrical Components Characteristics: Variety of unusable electrical and electronic components; for example, instrumentation electronic components. See Section 3.1.18 for used computer parts. Classification: Varies with type and construction of component. Typically, non- hazardous solid waste but could contain TCLP metals such as mercury, silver, or lead. The scrap metal exemption applies to whole used circuit boards that contain minor battery or mercury switch components and that are sent for continued use, reuse, or recovery under 40 CFR 261.6 (a)(3)(ii) / R315-261-6, RCRA Hotline fax back (14155), and (May 26, 1998, 63 FR 28556). Documentation must be on file from the recycling facility to show how recycling is accomplished. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 17 Disposal: Electrical components are accumulated for recycling or hazardous waste disposal at approved facilities. Larger items such as motors are stored for re-build, reuse, or resale. Analyses: Not required for hardware that does not contain potentially toxic metals. Components that are suspected of containing toxic metals should be tested for TCLP metals before disposing. 3.1.20 Biohazard Waste Characteristics: Biohazard waste from first aid operations and medical treatment. Biohazard wastes include first aid waste containing blood. Classification: Biohazard. Disposal: Disposed off site at an approved incineration facility. Do not burn biohazard waste on site or throw in the trash. Waste Handling: Sharps are contained in rigid engineer-controlled containers. Non-sharps biohazard wastes are contained in red biohazard bags. Sharps and non- sharps biohazard waste containers should be placed in fiber barrels or totes provided for these wastes. Biohazard containers are labeled with biohazard labels. Shipping: Container DOT Specification: UN/1G fiber drum or Non-DOT specification tote (provided by the disposal facility). Shipping Name: See waste profile. 3.1.21 Empty Product Containers Characteristics: Empty containers previously holding ignitable materials may contain explosive atmospheres. Use caution and ventilate. Classification: Containers are empty and exempt from regulation (40 CFR 261.7 / R315- 261-7) when: a. All products or waste have been removed that can be removed using the practices commonly employed to remove materials from that type of container, e.g., pouring, pumping, and aspirating, and b. No more than 2.5 centimeters (one inch) of residue remain on the bottom of the container or inner liner, or c. No more than 3 percent by weight of the total capacity of the container remains in the container or inner liner if the container is less than or equal to 110 gallons in size, or d. No more than 0.3 percent by weight of the total capacity of the container remains in the container or inner liner if the container is greater than 110 gallons in size. e. Containers that have held compressed gases are empty when the pressure in the container approaches atmospheric. f. Containers that have held acute hazardous wastes must be rinsed or cleaned per 261.7(b) / R315-261-7. Acute hazardous waste constituents can be determined by comparing label/SDS constituents’ sole active ingredients, or hazardous waste from non-specific sources to acute hazardous waste listed in 40 CFR 261.31, 261.32, or 261.33(e) / R315-261-(31-33). WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 18 Disposal: Small containers (<18 gallons) are discarded in the trash or managed as scrap metal when empty. Large containers (>18 gallons) are recycled to the vendor, reused, managed as scrap metal, crushed, cut in half (plastic), and/or thrown in the trash. Containers that have held acute hazardous waste will be rinsed with the appropriate reagent before being discarded. The rinse reagent will be used in the same process as the chemical if safe to do so or disposed. Analyses: Not required. 3.1.22 Unusable New Products Characteristics: Unusable new products or materials that cannot be returned to the vendors. Classification: Inert parts and materials are typically non-hazardous solid waste. Chemical products may be non-hazardous solid waste but may also be listed hazardous wastes or characteristic hazardous wastes. Disposal: Non-hazardous wastes are thrown in the trash. Chemical products should be disposed according to typical operating practices or according to SDS recommendations. Analyses: Not required, follow label or SDS recommendations. 3.1.23 Chlorinated Fluorocarbons/Refrigerant Characteristics: Chlorinated Fluorocarbons (CFCs)/Refrigerants that are removed from equipment air conditioning systems. See Section 3.2.25 for CFC contaminated oil. Classification: Excluded from regulation as solid waste under 40 CFR 261.2(e)(1)(ii) / R315- 261-2(e)(1)(ii) when recycled directly. Disposal: This recyclable material is handled by certified employees or contractors using a recovery unit. Analyses: Not required. 3.1.24 Refrigeration Unit CFCs Oil Waste Characteristic: Oil that comes in contact with CFCs during the normal use of the refrigeration unit. Classification: If total halogen is greater than 1,000 parts per million (ppm), then it is treated as a hazardous waste unless it is sent to b e reclaimed for CFCs, 40 CFR 279.10(b)(ii)(B) / R315-279-10. If total halogen is less than 1,000 ppm, then it can be managed as used oil. Disposal: CFC work is conducted by certified technicians who may add new oil, but they do not normally remove used oil. The facility has requested the contractor to provide paperwork if they remove used oil with CFCs. If greater than 1,000 ppm total halogen, ship to a facility that can reclaim CFC from used oil or ship off as hazardous waste. If less than 1,000 ppm total halogen, manage with used oil. Analysis: Chlor-D-Tect test for total halogen content. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 19 3.1.25 Asbestos Characteristics: Asbestos-containing waste containing greater than 1% by weight of friable asbestos. Classification: Solid waste requiring specialized handling practices under the Toxic Substances Control Act (TSCA). Only properly certified employees or contractors should handle asbestos. Disposal: Disposed of off site at an approved landfill. Analysis: Required to determine if suspect material is greater than 1% asbestos. A trained asbestos inspector, as defined by EPA, must determine if material is friable asbestos. Waste Handling: Handling or removal must be performed by trained and/or certified individuals (e.g., certified asbestos abatement technician). Double bagged and placed into a double lined container. Containers are labeled with one of the following warning labels: “Caution Contains Asbestos Fibers Avoid Opening or Breaking Container Breathing Asbestos Is Hazardous To Your Health”, “Caution Contains Asbestos Fibers Avoid Creating Dust May Cause Serious Bodily Harm”, or “Danger Contains Asbestos Fibers Avoid Creating Dust Cancer and Lung Disease Hazard.” Check with receiving facility to determine proper shipping papers needed for the facility (i.e. Clean Harbors requires a hazardous waste manifest). Shipping: Container: Double lined container. Waste Code: Not applicable. Shipping Name: See waste profile. 3.1.26 Non-leaking Light Ballasts and Small Capacitors Characteristics: Light ballasts and small capacitors removed from light fixtures. Classification: If ballast and capacitors are labeled as non-Poly Chlorinated Biphenyl (PCB), they are a non-hazardous solid waste. If the ballasts or capacitors are labeled as containing PCB or have no labeling, the facility is managing the waste as a Toxic Substances and Control Act (TSCA) waste. Disposal: Non-PCB ballasts and small capacitors can be thrown in the trash. PCB containing ballasts and small capacitors should be containerized for disposal at an approved TSCA facility. Analysis: Not required; use labels on ballasts and small capacitors. Waste Handling: TSCA PCB wastes are collected in open-top drums labeled with a PCB marking. PCBs or PCB Items designated for disposal must be disposed of within 1 year from the date it was determined to be a PCB waste and the decision was made to dispose of it. This is the date of removal from service and the point at which the 1-year time frame begins. Therefore, when the drum is full or after 9 months, whichever is first, the drum should be shipped for disposal to meet the 1-year disposal requirement. Waste must be shipped using a hazardous waste manifest. Shipping: Container DOT Specification: UN/1A2 (metal open-top drum). Waste Code: Not applicable to TSCA waste. Shipping Name: See waste profile. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 20 Reportable Quantity: PCBs (1 lb). 3.1.27 Transformer Oil (No-PCB and PCB Oil) Characteristics: Empty transformers, large capacitors, oil drained from transformers during maintenance, and leaking PCB light ballasts or small capacitors. PC B containing equipment has not been identified on site. However, PCB information is included if any PCB containing equipment is identified. Classification: Past analyses indicate oil to be No-PCB and PCB. Any oil containing any quantifiable level of PCBs (2 ppm) and oil-filled electrical equipment containing > 50 ppm PCBs is regulated under TSCA. The TSCA cleanup standards range from > 1 ppm in a residential or high occupancy area to < 25 ppm in a low occupancy area. Spill cleanups originating from PCBs < 50 ppm are regulated under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), Superfund Amendments and Reauthorization Act of 1986 (SARA) and State Department of Environmental Quality (DEQ) requirements. The CERCLA SARA and/or DEQ cleanup standards for PCBs are typically < 1 ppm. Therefore, empty electrical equipment previously containing any detectable amount of PCB should be managed at a company approved facility. Disposal: No-PCB large capacitors are recycled by an approved remanufacturer. Large capacitors, leaking light ballasts, and leaking small capacitors containing PCB are disposed at a TSCA facility. No-PCB oil is handled as used oil (see Section 3.2.1). PCB oil is disposed of as PCB at an approved facility. Empty equipment previously containing no-PCB and/or PCB < 50 ppm is recycled at an approved remanufacturing facility. Analyses: Not required unless the oil has not been previously analyzed or is contaminated during maintenance with solvent or other materials. Oil suspected of containing PCBs should be tested for PCBs before disposing. Waste Handling: Liquid TSCA PCB wastes are collected in closed-top drums. Large capacitors, leaking light ballasts, and leaking small capacitors containing PCB are collected in open top drums. PCBs or PCB Items designated for disposal must be disposed of within 1 year from the date it was determined to be a PCB waste and the decision was made to dispose of it. This is the date of removal from service and the point at which the 1- year time frame begins. Therefore, when the drum is full or after 9 months whichever is first the drum should be shipped for disposal to meet the 1- year disposal requirement. The TSCA waste must be shipped using a hazardous waste manifest. Shipping: Container DOT Specification: Liquids UN/1A1 (metal closed-top drum) and solids UN/1A2 (metal open-top drum) or 1H2 (plastic open-top drum). Waste Code: Not applicable to TSCA waste. Shipping Name: See waste profile. 3.1.28 Mercury Waste Characteristics: Mercury in instruments (i.e. switches and testing equipment), thermostats, and/or spills. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 21 Classification: Mercury thermostats and mercury containing equipment can be managed as universal waste under 40 CFR Part 273 / R315-273 or as waste mercury and contaminated debris D009 (mercury) hazardous waste if not managed as universal waste. Disposal: Universal Waste Managed as universal waste if not managed as hazardous waste. Hazardous Waste Managed as hazardous waste (D009) if not managed as universal waste. Analyses: Not required. Use generator knowledge as hazardous or universal waste (thermostats or mercury containing equipment). Waste Handling: Hazardous Waste Accumulated in open top drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Universal Waste Universal waste will be placed in an open top drum labeled as “Universal Waste - Mercury Thermostats or Mercury Containing Equipment.” Mark the container with the date the waste is first put in the container. Universal waste cannot be stored on site for greater than 12 months. Shipping: Container DOT Specification: UN/1A2 or 1H2 open-head drum. Waste Code: Varies with waste analyses. Shipping Name: See waste profile. 3.2 VEHICLE, MOBILE EQUIPMENT, AND SHOP WASTE Description: Fleet equipment is serviced in the field or in the truck shop. Major equipment repairs and preventative maintenance are completed at the Thatcher truck shop. Mobile lube and utility trucks provide field lubrication and maintenance services. 3.2.1 Used Oil and Used Oil Burner Ash Characteristics: Used lubricating oil and hydraulic oils, including brake and transmission fluid, generated from vehicle and machinery with minor amounts of fuel constituents and metals. It is facility policy to not mix used oil with solvents, coolants, or other waste materials. Analyses have indicated that the oil meets the criteria for specification used oil. Used oil burner ash may contain metals. Classification: Used Oil Non-hazardous solid waste unless contaminated with degreasing solvent or toxic metals. It is a facility policy that degreasing solvents are not to be mixed with used oil. In addition, only non-chlorinated degreasing solvents will be used. Wear of engine parts or hydraulic systems may contaminate oil with metals resulting in oil classification as off-specification oil, if recycled or as a hazardous waste, if disposed. Although used oil destined for disposal or recycling is not listed as a hazardous waste, the EPA has established standards for managing used oil (40 CFR Part 279). Used oil WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 22 burned for energy recovery under these rules must be analyzed to show if it meets used oil specifications. Used Oil Burner Ash Wear of engine parts or hydraulic systems may contaminate “used oil” with metals resulting in ash containing metals. Ash with metals below TCLP metals regulatory levels is non-hazardous solid waste and ach with metals exceeding TCLP metals is hazardous waste. Disposal: Used Oil Used oil generated in the maintenance of mobile equipment is vacuumed to the shop tank and/or collected in totes or drums and stored in aboveground storage tanks within secondary containment. Used oil from equipment that is maintained in the field is handled in a mobile tank that is then brought to the designated shop where the oil from the mobile tank is transferred to the stationary tank. Used oil is recycled off site at approved facilities. Used oil is tested on a routine basis prior to on site or off site recycling. A contractor picks up used oil for off site recycling for energy recovery. Used Oil Burner Ash Non-hazardous solid waste ash is thrown in the trash. Hazardous waste ash is accumulated in a satellite accumulation drum. Analyses: Used Oil Used oil shipped off site for recycling is tested for specifications (40 CFR 279.11 / R315-279-11). Used Oil Burner Ash Ash is analyzed for TCLP metals. Waste Handling: Used Oil Off Site Recycling The facility will not be a “Used Oil Marketer,” “Used Oil Processor/Re- Refiner,” or a “Used Oil Transporter.” The facility’s procedures for used oil management include the following: (1) We will not, nor will we allow any “hazardous waste” to be mixed with our used oil; (2) We will only use a pre-approved marketer/transporter having a valid EPA identification number to transport our used oil; (3) We will not direct shipments of used oil, and we will make no claim in regard to the used oil specification for used oil recycled off site; (4) We will require that the transporter analyze each shipment of used oil with Chlor-D-Tect ® test kits or the equivalent, to verify that the total organic halogens (TOX) concentration is below 1,000 ppm before transportation. The results of this analysis will be provided to, and retained by, the on site environmental personnel. If the analysis show TOX in excess of 1,000 ppm, a sample will be collected and tested for total volatiles and TCLP metals (standard turnaround) before the used oil is transported off site for disposal; and, (5) We will use generator knowledge and previous specification sample test results for used oil characterization. Used Oil Burner Ash Ash managed as hazardous wastes will be collected in open top drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Shipping: Used Oil Burner Ash WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 23 Hazardous Waste container DOT Specification: UN/1A2. Waste Codes: Varies with waste analyses. Shipping Name: See waste profile. 3.2.2 Used Oil, Air, Diesel Fuel, Gasoline, and Coolant Filters Characteristics: Used oil filters contain used oil, dirt, and metal particles. Used coolant filters contain coolant, dirt, and metal particles. Air filters contain dirt. Diesel fuel filters contain diesel fuel, dirt, and metal particles. Gasoline filters contain gasoline, dirt, and metal particles. Classification: Used coolant and air filters are non-hazardous solid wastes. Used oil filters are excluded from regulation as hazardous waste provided they are non- terne plated, have not been mixed with a listed hazardous waste, and have been punctured or dismantled, and gravity hot-drained (40 CFR 261.4 (b)(13) / R315-261-4 or crushed. Drained and/or crushed used diesel fuel (diesel fuel > 140˚F) filters are non-hazardous solid waste. Used gasoline/fuel filters are hazardous for ignitability (D001) and/or benzene (D018). Drain and accumulate liquids in proper containers. Drained fuel filter may be classified as scrap metal under 40 CFR 261.6 (a)(3)(ii) / R315- 261-6, under the June 3, 1998 RCRA online number: 14184 Regulatory Status of Spent Metal Filters Under RCRA. Disposal: Used oil filters are punctured on the filter dome end, then hot-drained for at least 24 hours and/or crushed. Diesel and coolant filters are drained and/or crushed. The diesel and used oil are combined with other used oil generated on site and coolant is combined with coolant. Coolant is collected in a separate bulk tank. Used oil and coolant filters that are drained and/or crushed, and air filters are thrown in the trash. Gasoline fuel filters are accumulated in hazardous waste containers or drained and managed as scrap metal. Gasoline is used or accumulated and managed under 3.2.10. Analyses: None required as long as the above procedures are followed. Waste Handling: Gasoline fuel filters managed as hazardous waste will be collected in open-head drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Shipping: Container DOT Specification: UN/1A1. Waste Codes: Gasoline fuel filters hazardous waste D001 and/or D018. Shipping Name: See waste profile. 3.2.3 Used Grease Characteristics: Vehicle and machinery greases that may contain regulated metals as part of their formulation and/or from wear of metal parts. Wear of mechanical parts on bearings may contaminate grease with metals. Use of fuel or solvent for clean-up may contaminate the grease. Analyses of this material have indicated that it is non-hazardous. Classification: Non-hazardous solid waste unless contaminated with metals or degreasing solvents. Metals in grease may produce a TCLP toxic WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 24 hazardous waste. Any degreasing solvents mixed with grease may produce an F-listed hazardous waste. Disposal: Non-hazardous greasy rags and floor dry are discarded in drums labeled trash. Larger quantities of used grease are disposed off site for recycling, fuel blending, or incineration depending on waste analyses. Analyses: Not required for unused or uncontaminated grease; constituents can be determined from SDSs. For grease containing degreasing solvent or spill cleanup waste, characterization review of SDS and/or testing may be required to determine regulatory status. Test for TCLP metals and F- and D-list total volatiles before shipping any previously uncharacterized grease off site for disposal. Waste Handling: Non-Hazardous Solid Waste: Used grease is collected in open top drums having properly completed markings. Hazardous Waste: Wastes are collected in open-top drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Shipping: Container DOT Specification: Non-Hazardous Solid Waste: Non-DOT specification containers may be used (i.e., the original grease shipping containers if in good condition) or DOT specification containers UN/1A2. Hazardous Waste: UN/1A2. Waste Code: Varies with hazardous waste analyses. Non-Hazardous Waste: Mark the container with the wording “Used Grease.” Hazardous Waste: Shipping Name: See waste profile. 3.2.4 Used Floor Dry Characterization and handling are the same as Section 3.1.10. 3.2.5 Used Rags, Wipes, Absorbent Pads, and Socks Characteristics: Varies with use and materials absorbed. May contain oil, solvents, fuels, and/or various substances. Classification: Typically, non-hazardous solid waste. If wet with non-listed solvent, fuel, used oil, or other regulated materials, the rags may be an ignitable (D001) hazardous waste when discarded. If contaminated with listed degreasing solvents, may be a (F002-F005) hazardous waste. Disposal: Routinely generated non-hazardous rags, wipes, absorbent pads, and socks that are not wet with oil, solvent, and/or fuel are discarded in the trash barrels. Wet non-hazardous oily rags are drained, and petroleum hydrocarbon products are accumulated with the used oil. Rags, wipes, WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 25 absorbent pads, and socks that are wet with ignitable liquids or are known to be contaminated with listed solvents or other hazardous materials should be segregated, containerized, and handled as hazardous waste. Analyses: Normally not required except for characterization of potentially contaminated rags. For spill cleanup, waste characterization review of SDS and/or testing may be required to determine regulatory status. Waste Handling: Hazardous wastes are collected in open-top drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Shipping: Container DOT Specification: UN/1A2. Waste Code: Varies with waste analyses. Shipping Name: See waste profile. 3.2.6 Used Engine Coolant (Glycol-Based Antifreeze) Characteristics: Ethylene glycol and water (50:50 mix) drained from mobile eq uipment may contain regulated metals and benzene. Ethylene glycol is toxic by ingestion. Analyses of this material have indicated it is non-hazardous. Classification: Non-hazardous solid waste unless contaminated with metals, fuels, solvents, or other maintenance wastes. TCLP metal analyses of used coolant from the facility were below hazardous waste regulatory levels. If TCLP metals exceed hazardous waste regulatory levels, antifreeze would be regulated as hazardous waste. Disposal: Typically used consumptively or reused. Accumulated coolant is collected in drums or tanks for recycling and recycled on site or off site (by an approved facility). The approved contractor routinely tests and evacuates the used antifreeze storage tank. Used coolant storage containers including drums and tanks must be marked with the words “Used Antifreeze.” Hazardous wastes should be segregated, containerized, and handled as hazardous waste. Analyses: Use coolant SDSs, apply generator knowledge, and/or sample initially (and any time the process changes). 3.2.7 Water-Sediment/Sludges from Sumps Characteristics: Water with dirt, detergent, and de minimis amounts of spilled fuel, coolant, oil, grease, and solvents. Classification: Typically, non-hazardous solid waste and used oil/grease. Sediment/Sludge may contain hydrocarbons, characteristic hazardous waste, and/or listed hazardous waste. Disposal: Water and sediment in sumps is removed by a contractor with a vacuum truck and managed according to classification. Absorbent booms may be used. Absorbent booms are managed under 3.2.5 Absorbent Pads. Petroleum Contaminated Soil (PCS) (non-hazardous) is containerized and disposed at off site approved facilities. Solids/sludges that are wet with ignitable liquids or are known to be contaminated with listed solvents or other hazardous materials are segregated, containerized, and handled as hazardous waste. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 26 Analyses: Not required for non-hazardous water and sediment. Apply generator knowledge; use previous characterization and/or SDS information for solids/sludge. Sample and test if necessary due to process or product changes. Sample and test sludge for total petroleum hydrocarbons (TPH), TCLP metals, total F- and D-list volatiles and/or semi-volatiles in order to characterize. For spill cleanup waste characterization, a review of SDS and/or testing may be required to determine regulatory status. 3.2.8 Aerosol Paints, Cleaners, Lubricants, and Vent Filters Characterization and handling are the same as Section 3.1.4. 3.2.9 Contaminated or Waste Diesel Fuel Characteristics: Diesel fuel resulting from servicing equipment and from spill cleanups. Classification: Flash point of diesel fuel used at the facility is typically above 140˚F which would not be RCRA ignitable. Diesel fuel mixed with used oil is regulated as used oil, provided the resultant mixture does not exhibit the characteristic of ignitability under 40 CFR Part 279.10 (b)(2)(iii) / R315-279- 10. Disposal: Non-hazardous waste diesel fuel is collected in drip buckets and combined in designated drums around the property. This is mixed with used oil for recycling or energy recovery. PCS (non-hazardous diesel- contaminated) is containerized and disposed at off site approved facilities. Floor dry contaminated with adsorbed (no free liquid) diesel fuel is thrown in the trash. Analyses: Not required unless diesel fuel with a lower flash point is purchased and disposed with used oil. Mixtures of diesel fuel and other materials to be disposed off site will be tested for ignitability. 3.2.10 Contaminated or Waste Gasoline and/or Kerosene Characteristics: Contaminated or off-specification waste gasoline from fueling vehicles or from spills. Contaminated or off specification kerosene from use for heating or from spills. Liquid waste must not be solidified for disposal. Classification: Possible hazardous waste due to characteristics of ignitability (D001) and, benzene (D018) if present in strong concentrations. Is exempt from regulation as a hazardous waste under the Mixture Rule (40 CFR Part 261.3 (a)(2)(iii) / R315-261-3) if small concentrations are mixed with motor oil, or other solid wastes and the resulting mixture no longer exhibits a characteristic of hazardous waste. Also exempt from regulation if used as a fuel such as burned for energy recovery. Disposal: Liquid gasoline and kerosene disposed as a hazardous waste is shipped as D001 and/or D018 hazardous waste if the discarded material exhibits the characteristics. Exempt if used as a fuel. PCS (non-hazardous soil contaminated with small amounts of gasoline) is containerized and disposed at off site approved facilities. Solids/sludges that are wet with WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 27 ignitable liquids are segregated, containerized, and handled as hazardous waste. Analyses: Apply generator knowledge; use previous characterization and/or SDS information. Mixtures of gasoline, kerosene, and other materials to be disposed off site will be tested for ignitability, TCLP benzene for solids and/or total benzene for liquids. Mixtures of gasoline, kerosene, and other materials that are recycled or used for energy recovery do not require testing. Waste Handling: Recyclable material or hazardous wastes will be collected in closed-top drums. Hazardous waste containers will have properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Drums containing flammable liquids must be grounded when adding or removing waste. Shipping: Container DOT Specification: UN/1A1 Waste Code: D001 and/or D018 for hazardous waste and none if used as a fuel. Shipping Name: See waste profile. 3.2.11 Empty Product Containers Characterization and handling are the same as Section 3.1.21. 3.2.12 Lead Acid Batteries Characteristics: Vehicle and equipment batteries containing acid and lead. Classification: Non-hazardous solid waste if recycled. Recycling requirements for lead- acid batteries are found in 40 CFR 261.6 (a)(2) and (a)(3) / R315-261-6. Damaged or leaking batteries are hazardous waste due to the characteristics of lead (D008) and corrosivity (D002). If not recycled under the recycling requirement above, recycled lead acid batteries are subject to the Universal Waste Management Standards located in 40 CFR Part 273 / R315-273. Disposal: Handle lead acid batteries carefully to prevent damage and potential acid spills. Damaged batteries may be costlier to recycle. Battery terminals should be protected to prevent short circuits. Recycled Batteries Used batteries are stored in on-site specified locations (shops or warehouse yards) prior to being returned to vendors for recycling when a new battery is obtained. Universal Waste If not recycled under the recycling requirement above batteries are handled as universal waste under 40 CFR Part 273 / R315-273 when a new battery is obtained. Used lead acid batteries are collected and stored at the warehouse. Hazardous Waste Damaged leaking batteries are containerized and disposed as hazardous waste. Each broken battery must be packaged in a separate plastic pail. Analyses: Not required; constituents can be determined from SDSs. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 28 Waste Handling: Hazardous Waste Hazardous waste damaged or leaking batteries are collected in separate plastic pails placed in plastic drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Universal Waste Universal waste batteries are collected in containers marked with the words "Universal Waste Used Batteries” (“Lead Acid Batteries Only"). Mark the universal waste container with the date the waste is first put in the container. Universal waste cannot be stored on-site for greater than 12 months. Shipping: Container DOT Specification: UN/1H2. Waste Code: Not applicable to universal waste. D008 (10 lbs) and D002 (100 lbs) for hazardous waste. Shipping Name: See waste profile. 3.2.13 Scrap Metal Including Welding Rod and Cuttings Characteristics: Pieces of metal scrap, used metal parts, and welding rod. Classification: Recyclable material 40 CFR 261.6 / R315-261-6. Disposal: Scrap metal is saved in recycling bins and/or specified locations and picked up by a recycling contractor. Contractors routinely remove scrap metal or used parts are returned to the vendor. Analyses: Not required for recycled scrap metal. 3.2.14 Compressed Gas Cylinders Characteristics: Typically, empty when disposed but may contain pressurized hazardous materials if not empty. Classification: Non-hazardous solid waste when empty. Reactive (D003) and/or ignitable (D001) hazardous waste if still pressurized. Waste codes may vary with constituents. Disposal: Compressed gas vendors pick up large empty cylinders and refill them for use. All gas cylinders not returned to vendors for use will be emptied to atmospheric pressure before being thrown in the trash or recycled for metal content (valves are removed or left open according to good management practice). Mark empty cylinders with an “empty” sticker and dispose in the trash (small disposable cylinders only) if empty. Non- empty cylinders are recycled or disposed off site at a permitted facility. Analyses: Not required; constituents can be determined from SDSs. 3.2.15 Cold Cutting Fluid Characteristics: Used cold cutting fluid and metals from metal cutting saws. It is a good management practice to not mix solvents, coolants, or other waste materials with cutting fluid. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 29 Classification: Non-hazardous solid waste unless contaminated with metals or degreasing solvents. Oil-based fluid is managed as used oil (see Section 3.2.1). Water-based fluid is typically non-hazardous solid waste but may be hazardous if heavily contaminated with listed solvents or regulated metals. Disposal: Typically used consumptively. Excess oil-based fluid is mixed with used oil for disposal (see Section 3.2.1). Acceptable non-hazardous solid wastes with free liquids must be solidified/dried before disposing in the trash. Hazardous waste water-based fluid is accumulated separately in drums for off site disposal at permitted facilities. Analyses: Not required for oil-based fluid unless there are process changes. Apply generator knowledge, use previous characterization information, and SDS for characterization of water-based fluid and/or sample and test for TCLP metals and volatile organics (if identified by generator knowledge) to verify characteristics. Once characterized, apply generator knowledge and sample to re-characterize any time the process changes. Waste Handling: Hazardous wastes are collected in closed-top drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Shipping: Container DOT Specification: UN/1A1 (metal closed-top drum). Waste Code: Varies with waste analyses. Shipping Name: See waste profile. 3.2.16 Machine Tool Fluids Characteristics: Machining fluids from cleaning out machine tool sumps. Classification: Machining fluids used at the facility typically are not hazardous wastes. Disposal: Typically, fluids are used consumptively but used oils removed from sumps would be handled as used oil. Analyses: Not required for oil-based fluid unless there are process changes. Apply generator knowledge, use previous characterization information, and SDS for characterization of water-based fluid and/or sample and test for TCLP metals and volatile organics (if identified by generator knowledge) to verify characteristics. Once characterized, apply generator knowledge and sample to re-characterize any time the process changes. 3.2.17 Spent Solvent (Water and/or Hydrocarbon-Based), Sludge, and/or Filters from Parts Washers or Bulk Solvent Use Characteristics: Water-based and/or hydrocarbon-based spent solvent, sludge and filters from bulk solvent use or parts washers. Typically spent solvents, sludge and filters contain dirt, oil, and grease. Unused and/or spent solvent has a flash point greater than 140˚F. Spent solvent, sludge and filters may also contain metals from parts cleaning. If sludge is separated for disposal, it will typically contain hydrocarbons. Do not mix F-listed solvent with solvent from parts washers. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 30 Classification: Accumulated spent solvent, sludge, and/or filters not exceeding hazardous waste regulatory limits are handled as non-hazardous solid waste. These may be hazardous if mixed with listed solvents and/or heavily contaminated with regulated metals. Accumulated spent solvent, sludge, and/or filters exceeding hazardous waste regulatory limits are handled as hazardous waste. If Safety Kleen solvent is being used, Safety Kleen may include the plant parts washers in their continued use program which is, when they service the washer, they reuse the solvent from our washer to clean their drums at their facilities becoming the end user. If Safety Kleen solvent exceeds hazardous waste reg ulatory limits and is not used in Safety Kleen’s continued use program it must be handled as hazardous waste. Disposal: Non-hazardous cartridge type filters are drained and managed the same as used oil filters (see Section 3.2.2) and non-hazardous cellulose filters are drained and thrown in the trash. Non-hazardous combustible spent solvent may be managed with used oil (see Section 3.2.1). Non- hazardous sludge is containerized and managed as non-hazardous solid waste for on or off site disposal. Spent solvent, sludge, and/or filters known to be contaminated with listed solvents or other hazardous wastes, are segregated, containerized, and handled as hazardous waste at permitted facilities. Spent Safety Kleen solvent may be used by Safety Kleen in their continued use program. Analyses: Not required for unused solvent constituents (may be obtained from SDS). Apply generator knowledge; use previous characterization information, and SDS for characterization of filters and used solvent and/or sample and test initially (and anytime the process changes) for TCLP metals and F- and D-list volatile organics (if identified by generator knowledge) to verify characteristics. Once characterized apply generator knowledge and sample and re-characterize any time the process changes. Waste Handling: Hazardous Waste Hazardous waste liquids are collected in closed top drums, and filters and/or sludges are collected in separate open head drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Safety Kleen Continued Use Program Liquids are collected in open and/or closed top drums having properly completed markings provided by Safety Kleen. Shipping: Container DOT Specification: UN/1A2. Waste Code: Varies with waste analyses. Shipping Name: See waste profile. 3.2.18 Hot Water Parts Washer Spent Filters, Water, Sludge, and Skimmer Waste Characteristics: "Hot water parts washer" filters, water, sludge, and skimmer waste which contains high pH detergent (before use) and may contain metals, oil, grease, and solvents from parts cleaning. Detergent solutions typically exhibit a neutral pH after use. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 31 Classification: Water, sludge, and skimmer (oil) waste are typically non-hazardous solid wastes but may be hazardous if heavily contaminated with regulated metals or listed solvents. Non-hazardous skimmer oil is managed as used oil. Non-hazardous filters are handled the same as used oil filters. Accumulated water, sludge, and/or filters exceeding hazardous waste regulatory limits are handled as hazardous waste. Disposal: Water and sludge are containerized, sampled, characterized, and classified for disposal. Non-hazardous water and/or sediment/sludge is transferred by a vacuum truck to the wash bay sump. Non-hazardous skimmer oil is managed with use oil (see Section 3.2.1). Non-hazardous cartridge type filters are drained and managed the same as used oil filters (see Section 3.2.2) and non-hazardous cellulose filters are drained and thrown in the trash. Hazardous waste water, sludge, and/or skimmer waste is accumulated separately in drums for off site disposal at permitted facilities. Analyses: Apply generator knowledge, use previous characterization information, and SDS for characterization of filters, water, sludge, and/or skimmer waste and/or sample and test for TCLP metals and volatile organics (if identified by generator knowledge) to verify characteristics. Once characterized apply generator knowledge and sample to re-characterize any time the process changes. Waste Handling: Hazardous wastes are collected in open-top drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Shipping: Container DOT Specification: UN/1A2. Waste Code: Varies with waste analyses. Shipping Name: See waste profile. 3.2.19 Used Desiccants Characteristics: Used desiccant from various air drying systems. Classification: Desiccant is typically non-hazardous solid waste. Disposal: Dry non-hazardous waste is thrown in the trash. Analyses: Not required for product; constituents can be determined from labels/SDSs. Apply generator knowledge; use previous characterization and/or SDS information. Sample and test if necessary due to process or product change. Not required except for characterization of potentially hazardous spent desiccant. Desiccant is typically tested for TCLP metals. Once characterized apply generator knowledge and sample to re- characterize any time the process changes. 3.2.20 Ni-Cad, Mercury, Dry Lead Batteries, or Sealed Gel Lead Acid Characterization and handling are the same as Section 3.1.6. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 32 3.2.21 Lithium Batteries Characterization and handling are the same as Section 3.1.9. 3.2.22 Carbon and Alkaline Flashlight Batteries Characterization and handling are the same as Section 3.1.8. 3.2.23 General Maintenance Wastes Characteristics: Waste paper, metal, plastic, cardboard, wood, wrapping and packaging, RCRA empty containers and aluminum cans. Classification: Typically, non-hazardous solid waste; however, non-empty containers of hazardous products may be hazardous wastes when disposed. Scrap metal is recyclable material under 40 CFR 261.6 (a)(3)(ii) / R315-261-6. Disposal: Non-hazardous wastes are thrown in the trash. Recyclable materials are accumulated for off site recycling. Non-empty containers (i.e., adhesive and oil etc.) will be disposed as required for the material characteristics. Analyses: Not required; use product labels and SDSs for chemical products that are discarded. 3.2.24 Chlorinated Fluorocarbons/Refrigerant Characterization and handling are the same as Section 3.1.23. 3.2.25 Refrigeration Unit CFCs Oil Waste Characterization and handling are the same as Section 3.1.24. 3.2.26 Paint-Related Materials Including Blasting Grit Characterization and handling are the same as Section 3.4. 3.2.27 Pressure Washing Wastes Characteristics: Pressure washing overspray, oil, grease, and metals (water & chemical additive; normally alkaline detergent). Undiluted product pH may be corrosive. Classification: Typically, non-hazardous solid waste but this wastewater may contain listed or characteristic hazards according to generator knowledge. The wastewater may be hazardous if heavily contaminated with regulated metals, listed cleaning solvents, and/or characteristic cleaning solvents. Unused, undiluted product additives or detergents may be hazardous waste if discarded. Disposal: Consult the SDS for disposal of unused or spilled pressure washing chemicals. PCS (non-hazardous) is containerized and disposed at off site WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 33 approved facilities. Wash water suspected of containing regulated metals, listed cleaning solvents, and/or characteristic cleaning solvents is containerized, sampled, and tested. Wash water failing for corrosivity only is neutralized in containers and disposed in the water management system. Hazardous waste wash water is disposed as hazardous waste off site. Acceptable non-hazardous solid wastes with free liquids must be solidified/dried before disposing in the trash. Analysis: A change in the detergent formulation or product used requires a rev iew of the SDS and pH testing. Not required except for characterization of potentially contaminated wash water. For wash water containing regulated metals, listed cleaning solvents, and/or characteristic cleaning solvent waste characterization review of generator knowledge, SDS and/or testing may be required to determine regulatory status. Test for pH and TCLP metals before disposing of any previously uncharacterized wash water. 3.2.28 Air Cooler Filters Characteristics: Air filters contain dust from filtering outside and work area air. Classification: Non-hazardous solid wastes. Disposal: Air filters are thrown in the trash. Analyses: None required. 3.3 TIRE REPAIR (TRUCK SHOP) Description: Tire repair is conducted at the facility and involves use of adhesives and solvents. Various wastes that are produced during tire repair are discussed below. 3.3.1 Tire Cleaner and Adhesive Characteristics: Unused cleaners and adhesives from tire maintenance may be ignitable and may contain toxic characteristic solvents. Used cleaners may contain listed solvents. Classification: Ignitable cleaners and/or cleaners containing toxic characteristic solvents would be hazardous waste when discarded. Cleaners that contain 10 percent or more of F-listed solvent when spent are F-list solvent hazardous waste. Review SDSs or labels for disposal requirements. Disposal: Products are typically used consumptively with no waste. Unused cleaners are typically hazardous due to ignitability or toxic characteristic solvent content. Unused materials or used cleaners known to be contaminated with listed solvents or other hazardous wastes should be segregated, containerized, and handled as hazardous waste. Analyses: Not required; constituents can be determined from SDSs. 3.3.2 Tire and Wheel Balance Weights Characteristics: Lead weights. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 34 Classification: Recyclable material. Lead weights are hazardous waste for TCLP lead (D008) if discarded. Disposal: Accumulated used weights are recycled for use as weights and are not disposed. Used weights are fully consumed. Analyses: Not required. 3.3.3 Tire Prep Solution Characteristics: Contains glycol and inert chemicals. Classification: Typically used consumptively with no waste. Non-hazardous solid waste, unless contaminated with listed solvents or other hazardous materials. Disposal: Spills of tire life are absorbed and thrown in the trash. Analyses: Not required; constituents can be determined from SDSs. 3.3.4 Tires Characteristics: Chemically inert. Classification: Non-hazardous solid waste. Disposal: Tires are managed and disposed of off site by contractors. Analyses: Not required. 3.3.5 Used Floor Dry Characterization and handling are the same as Section 3.1.10. 3.3.6 Used Rags, Wipes, Absorbent Pads, and Socks Characterization and handling are the same as Section 3.2.5. 3.3.7 Empty Product Containers Characterization and handling are the same as Section 3.1.21. 3.4 EQUIPMENT PAINTING Description: The facility will typically contract for sand blasting and painting of its larger equipment and may also conduct its own small sand blasting and spray-painting jobs. Equipment is cleaned and sand blasted to prepare it for painting. The painting process is completed at the equipment location. Various paints, thinners, reducers, and hardeners are used as required. Wastes consist of waste blasting grit, masking materials, empty paint cans, rags, wipes, spent thinner, and minor amounts of waste paints. 3.4.1 Painting Wastes Characterization and handling are the same as 3.1.13. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 35 3.4.2 Used Blasting Grit and/or Paint Chips Characteristics: Used sand blasting grit at outdoor painting areas may contain metals from the parts themselves and paint particles contained in the waste grit. Analyses of this material have indicated that it is non-hazardous. Classification: Typically, non-hazardous solid waste but may contain lead and cadmium from paint particles in the waste. If the concentration of these metals is high, the waste may fail TCLP metals and be a characteristic hazardous waste. Samples obtained in the past indicate that none of the TCLP regulatory levels for toxic metals were exceeded. Disposal: Used non-hazardous blasting grit is typically left on the ground in the sand blasting portion of the outdoor painting areas or it is collected by the contractor for disposal in the trash or off site disposal. Used grit exhibiting hazardous waste characteristics will be placed in drums and handled as hazardous waste for disposal. Analyses: Use paint SDSs, apply generator knowledge and/or sample initially (and any time the process changes). Test for TCLP metals if metal content of paint fraction or parts is uncertain. 3.4.3 Empty Product Containers Characterization and handling are the same as 3.1.21. 3.4.4 Used Rags, Wipes, Drop Cloths, and Masking Material Characteristics: Varies with use and materials absorbed. May be ignitable, contain solvents, or characteristic metals. Classification: Typically, non-hazardous solid waste, however, if waste is contaminated with a listed solvent, the waste may be a listed hazardous waste. If contaminated with paints, solvent blends, or other non-listed materials, the waste may be a characteristic hazardous waste when discarded. Waste that is wet with flammable paint or solvent when discarded may be ignitable (D001). Waste that contains a strong concentration of paint containing toxic metals such as cadmium or lead may be TCLP toxic for these metals. Disposal: Non-hazardous rags, wipes, drop cloths, and masking material can be thrown in the trash. Wastes known to be contaminated with listed or TCLP solvents or other hazardous wastes will be segregated, containerized, and handled as hazardous waste. Analyses: Normally not required except for characterization of potentially hazardous rags, wipes and masking material. Review of SDS and/or testing may be required to determine regulatory status. Waste Handling: Hazardous wastes are collected in open-top drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Shipping: Container DOT Specification: UN/1A2. Waste Code: Varies with waste analyses. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 36 Shipping Name: See waste profile. 3.4.5 Aerosol Paints, Cleaners, Lubricants, and Vent Filters Characterization and handling are the same as Section 3.1.4. 3.4.6 Lead Based Paint Removal Waste Characteristics: Varies with removal process and materials used. May be ignitable; and may contain solvents or characteristic metals in addition to lead (D008). Classification: Hazardous waste D008 (lead). If waste is contaminated with listed solvent, the waste is a listed hazardous waste. If contaminated with solvent blends, or other non-listed materials, the waste may be a characteristic hazardous waste when discarded. Waste that is wet with flammable paint removal solvent when discarded may be ignitable (D001). Waste that contains a strong concentration of paint containing other toxic metals such as cadmium may include additional TCLP toxic metals. Disposal: Lead based paint removal materials and paint chips are segregated, containerized, and handled as hazardous waste. Analyses: Review of SDS and/or testing may be required to determine regulatory status. Apply generator knowledge; use previous characterization and/or SDS information. Sample and test if necessary due to process or product change. Lead based paint waste is typically tested for TCLP metals. Sample and test for total F & D-list volatiles, total semi-volatiles and/or ignitability (if identified by generator knowledge). Once characterized apply generator knowledge and sample and re-characterize any time the process changes. Waste Handling: Lead based paint removal materials will be collected in drums having properly completed EPA hazardous waste markings including the accumulation start date when the drums are full and handled as follows: Shipping: Container DOT Specification: UN/1A2. Waste Code: Varies with waste analyses. Shipping Name: See waste profile. 3.5 MAINTENANCE Description: Maintenance of the chemical manufacturing equipment is conducted by the maintenance department (maintenance and electrical shops). Various wastes that are produced in these activities are discussed below. 3.5.1 Used Lubricating and Hydraulic Oil Characterization and handling are the same as Section 3.2.1, except that any drums of used oil from the field are brought to the work area designated used oil tank and transferred to it. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 37 3.5.2 Used Grease Characterization and handling are the same as Section 3.2.3. 3.5.3 Used Rags, Wipes, Absorbent Pads, and Socks Characterization and handling are the same as Section 3.2.5. 3.5.4 Waste Paints and Painting Wastes Characterization and handling are the same as Section 3.1.13. 3.5.5 Sand Blast Grit Characterization and handling are the same as Section 3.4.2. 3.5.6 Scrap Metal Including Welding Rod and Cuttings Characterization and handling are the same as Section 3.2.13. 3.5.7 Spent Solvent (water and/or hydrocarbon-based), Sludge, and/or Filters from Parts Washers or Bulk Solvent Use Characterization and handling are the same as Section 3.2.17. 3.5.8 Industrial Lamp Bulbs Characterization and handling are the same as Section 3.1.3. 3.5.9 Aerosol Paints, Cleaners, Lubricants, and Vent Filters Characterization and handling are the same as Section 3.1.4. 3.5.10 Cold Cutting Fluid Characterization and handling are the same as Section 3.2.15. 3.5.11 Used Floor Dry Characterization and handling are the same as Section 3.1.10. 3.5.12 Ni-Cad Batteries Characterization and handling are the same as Section 3.1.6. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 38 3.5.13 Lithium Batteries Characterization and handling are the same as Section 3.1.9. 3.5.14 Carbon and Alkaline Batteries Characterization and handling are the same as Section 3.1.8. 3.5.15 Sump Cleanouts Characteristics: Occasional cleanout of process and floor sumps. Characteristics depend on the location of the sump in the process and the presence of any spi lled chemicals in the sump contents. Typical characteristics associated with an area include floor wash water with de minimis amounts of spilled equipment (pumps, compressors etc.) lube oil and process chemicals. Classification: Recycled Sump cleanouts that are recycled to the process from which the material originated are excluded from RCRA solid waste under 40 CFR 261.4 (a)(8) / R315-261-4 (a)(8) and/or 40 CFR 261.2(e) / R315-261-2(e). Elementary Neutralization Units Elementary Neutralization Units (ENUs) are used for neutralizing wastes that are hazardous only because they exhibit the corrosivity characteristic (40 CFR 260.10 / R315-260-10). They are exempted from permitting under 40 CFR 270.1(c)(2)(v) / R315-270-1(c)(2)(v). The requirements for 40 CFR Parts 264 and 265 / R315-264 and 265 do not apply [40 CFR 264.1(g)(6) / R315- 264-1(g)(6) and 265.1(c)(10) / R315-265-1(c)(10)]. The hazardous waste corrosive characteristic is neutralized, and the waste classified as non- hazardous solid waste by generator knowledge. Other spilled material collected in sumps that is not recycled to the process circuit from which it originated, ENU neutralized for the characteristic of corrosivity only will be tested for hazardous waste characteristics before being recycled to the process, ENU neutralized, or disposed. Wastewater Permit Materials treated and discharged to the POTW under the wastewater discharge permit number SLC-0001 are excluded from regulation as a solid waste (therefore not a hazardous waste) under 40 CFR 261.4 (a)(1)(ii) / R315-261-4 (a)(1)(ii). Hazardous Waste Sump cleanouts containing characteristic and/or listed hazardous waste will be segregated, containerized, and handled as hazardous waste. Disposal: Recycled to the process. Wash water failing for corrosivity only is managed in an on site ENU. Treated waters are discharged under wastewater discharge permit SLC-0001. Sump cleanouts containing characteristic and/or listed hazardous waste will be segregated, containerized, and handled as hazardous waste. Analyses: Not required if material is recycled to the process from which the material originated. The pH is monitored to ensure the corrosivity is neutralized WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 39 when treating in an ENU. If the soil/sludge possibly contains metals and/or F-listed solvents, sample and test initially (and anytime the process changes) for TCLP metals and total F- and D-list volatile organics. 3.5.16 Tank and Vessel Cleanouts Characteristics: Occasional cleanout of process tanks and vessels. Characteristics depend on the location of the tank or vessel in the process and if any cleaning reagents or materials are added to the tank contents to conduct the cleanout. Classification: Recycled Tank cleanout materials that are not mixed with any ha zardous cleaning reagents and that are recycled to the process from which the material originated are excluded from RCRA solid waste under 40 CFR 261.4 (a)(8) / R315-261-4 (a)(8) and/or 40 CFR 261.2(e) / R315-261-2(e). Elementary Neutralization Units Elementary Neutralization Units (ENUs) are used for neutralizing wastes that are hazardous only because they exhibit the corrosivity characteristic (40 CFR 260.10 / R315-260-10). They are exempted from permitting under 40 CFR 270.1(c)(2)(v) / R315-270-1(c)(2)(v). The requirements for 40 CFR Parts 264 and 265 / R315-264 and 265 do not apply [40 CFR 264.1(g)(6) / R315- 264-1(g)(6) and 265.1(c)(10) / R315-265-1(c)(10)]. The hazardous waste corrosive characteristic is neutralized, and the waste classified as non- hazardous solid waste by generator knowledge. Other spilled material collected in sumps that is not recycled to the process circuit from which it originated, ENU neutralized for the characteristic of corrosivity only will be tested for hazardous waste characteristics before being recycled to the process, ENU neutralized, or disposed. Wastewater Permit Materials treated and discharged to the POTW under the wastewater discharge permit number SLC-0001 are excluded from regulation as a solid waste (therefore not a hazardous waste) under 40 CFR 261.4 (a)(1)(ii) / R315-261-4 (a)(1)(ii). Hazardous Waste Sump cleanouts containing characteristic and/or listed hazardous waste will be segregated, containerized, and handled as hazardous waste. Disposal: Recycled to the process. Wash water failing for corrosivity only is managed in an on site ENU. Treated waters are discharged under wastewater discharge permit SLC-0001. Sump cleanouts containing characteristic and/or listed hazardous waste will be segregated, containerized, and handled as hazardous waste. Analyses: Not required if material is recycled to the process from which the material originated. The pH is monitored to ensure the corrosivity is neutralized when treating in an ENU. If the soil/sludge possibly contains metals and/or F-listed solvents, sample and test initially (and anytime the process changes) for TCLP metals and total F- and D-list volatile organics. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 40 3.5.17 Used Rags, Wipes, Absorbent Pads, and Socks with Spray Solvent Waste (Used on Instrumentation) Characteristics: Waste rags, wipes, absorbent pads, and socks with solvent from using spray solvent on instruments. It is facility policy to only use non-chlorinated solvents. Small amounts of solvent used evaporate during use. Classification: Typically, non-hazardous solid waste. If wet with non-listed solvent, fuel, used oil, or other regulated materials, the rags may be an ignitable (D001) hazardous waste when discarded. If contaminated with listed degreasing solvents, may be a (F002-F005) hazardous waste. Disposal: Routinely generated non-hazardous rags, wipes, absorbent pads, and socks that are not wet with oil, solvent and/or fuel are thrown in the trash. Wet non-hazardous oily rags are drained and petroleum hydrocarbon products are accumulated with the used oil. Rags, wipes, absorbent pads, and socks that are wet with ignitable liquids or are known to be contaminated with listed solvents or other hazardous materials will be segregated, containerized, and handled as hazardous waste. Analyses: Normally not required except for characterization of potentially contaminated rags. For spill cleanup waste characterization review of SDS and/or testing may be required to determine regulatory status. Waste Handling: Hazardous wastes are collected in open-top drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Shipping: Container DOT Specification: UN/1A2. Waste Code: Varies with waste analyses. Shipping Name: See waste profile. 3.5.18 Hot Water Parts Washer Spent Filters, Water, Sludge, and Skimmer Waste Characterization and handling are the same as 3.2.18. 3.5.19 Machine Tool Fluids Characterization and handling are the same as 3.2.16. 3.5.20 Lead Acid Batteries Characterization and handling are the same as 3.2.12. 3.6 LABORATORY Description: The laboratory conducts testing for the entire operation. The laboratory contains facilities for sample preparation, assay, and wet chemistry testing. The laboratory waste streams produced within the facility are: WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 41 3.6.1 Used or Stored Excess Samples Characteristics: Excess process samples not analyzed or research and development samples which are recycled to the process as a component and samples placed into storage for future analyses. Classification: Samples placed into storage are not waste. Recycled samples are excluded from RCRA solid waste under 40 CFR 261.2(e)(1)(i) / R315-261- 2(e)(1)(i) because the material is recycled as a raw material. Disposal: Samples are used in the process or stored for analyses. Analyses: Not required unless changes in laboratory processes occur that may change the samples characteristics or if the samples are handled differently. 3.6.2 Oil and Gas Industry Samples Characteristics: Excess oil and gas industry samples containerized for sampling and classification for management. Samples consist of oil, organics, water, and/or metals. Classification: Managed as used oil, non-hazard solid waste, or hazardous waste based on generator knowledge or analyses. Disposal: Used Oil Characterization and handling same as Section 3.2.1. Non-hazardous Waste or Hazardous Waste Non-hazardous and hazardous wastes will be collected in drums having properly completed markings: 1) non-hazardous; or, 2) EPA hazardous waste markings including the accumulation start date when the satellite accumulation drums are full). Containers are stored in a designated area within the hazardous waste storage area or other designated areas until they are shipped to a designated or a permitted or approved non- hazardous waste facility or Treatment, Storage, and Disposal Facility (TSDF). Analyses: Sample and test initially (and anytime the process changes) for TCLP metals and total F- and D-list volatile and semi-volatile organics. 3.6.3 High Performance Liquid Chromatography Waste Characteristics: High Performance Liquid Chromatography solution (methanol and acetonitrile). Classification: Hazardous waste due to characteristic of ignitability (D001). Disposal: Liquid methanol and acetonitrile collected in a hazardous waste satellite accumulation container is disposed as a D001 hazardous waste. Analyses: Apply generator knowledge; use previous characterization and/or SDS information. Mixtures of methanol and other materials to be disposed off site will be tested for RCRA hazardous waste characteristics. Waste Handling: Hazardous wastes will be collected in closed-top drums. Hazardous waste containers will have properly completed EPA hazardous waste markings, WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 42 including the date when the drum becomes full or 55 gallons of the waste has accumulated. Drums containing flammable liquids must be grounded when adding or removing waste. Shipping: Container DOT Specification: UN/1A2 Waste Code: D001. Shipping Name: See waste profile. 3.6.4 Silver Nitrate Solution from Chloride Argentometric Analysis Characteristics: Silver nitrate solutions left over from chloride argentometric analysis. Classification: Silver nitrate solutions are hazardous waste for oxidizer (D001) and silver (D011). Disposal: Hazardous wastes are collected in a hazardous waste satellite accumulation container and disposed as a D001 and D011 hazardous waste. Analyses: Use SDSs, apply generator knowledge and/or sample initially (and any time the process changes). Test for TCLP metals if metals content of solution is uncertain and other applicable RCRA hazardous waste characteristics. Waste Handling: Hazardous wastes will be collected in closed-top drums. Hazardous waste containers will have properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Shipping: Containers: Hazardous wastes are collected in compatible UN/1H1 or 1A1 drums. Waste Code: Oxidizer (D001), silver (D011) and/or varies with waste analyses. Shipping Name: See waste profile. 3.6.5 Chloroform Surfactant Titration Characteristics: Chloroform solutions left over titration. Classification: Chloroform solutions are hazardous waste for chloroform (D022). Disposal: Hazardous wastes are collected in a hazardous waste satellite accumulation container and disposed as a D022 hazardous waste. Analyses: Use SDSs, apply generator knowledge and/or sample initially (and any time the process changes). Test for TCLP metals if metals content of solution is uncertain and other applicable RCRA hazardous waste characteristics. Waste Handling: Hazardous wastes will be collected in closed-top drums. Hazardous waste containers will have properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Shipping: Containers: Hazardous wastes are collected in compatible UN/1H1 or 1A1 drums. Waste Code: chloroform (D022) and/or varies with waste analyses. Shipping Name: See waste profile. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 43 3.6.6 Dilute Metal Solutions Characteristics: Dilute metal solutions not meeting wastewater discharge requirements. Classification: Non-hazardous solid waste dilute metal solutions not meeting the wastewater discharge requirements. Disposal: Non-hazardous solid wastes are collected in accumulation containers for off site management in an approved facility. Analyses: Use SDSs, apply generator knowledge and/or sample initially (and any time the process changes). Test for TCLP metals if metals content of solution is uncertain and other applicable RCRA hazardous waste characteristics. Waste Handling: Non-hazardous wastes will be collected in closed-top drums. Containers will have properly completed markings, including information identifying the contents. Shipping: Containers: Non-hazardous wastes are collected in compatible UN/1H1 or 1A1 drums. Waste Code: None, unless identified from analyses. Shipping Name: See waste profile. 3.6.7 Hydranal Solutions Characteristics: Hydranal solutions not meeting wastewater discharge requirements. Classification: Non-hazardous solid Hydranal solutions not meeting the wastewater discharge requirements. Disposal: Non-hazardous solid wastes are collected in accumulation containers for off site management in an approved facility. Analyses: Use SDSs, apply generator knowledge and/or sample initially (and any time the process changes). Test for TCLP metals if metals content of solution is uncertain and other applicable RCRA hazardous waste characteristics. Waste Handling: Non-hazardous wastes will be collected in closed-top drums. Containers will have properly completed markings, including information identifying the contents. Shipping: Containers: Non-hazardous wastes are collected in compatible UN/1H1 or 1A1 drums. Waste Code: None, unless identified from analyses. Shipping Name: See waste profile. 3.6.8 Lab Sink Drains and Neutralization Tank Wastewater Discharge Characteristics: Non-hazardous solid waste (i.e., liquid) and corrosive samples drain to the lab neutralization tank from the sinks. Samples must not contain listed hazardous waste or ignitable or oxidizer (D001), reactive (D003) or characteristic waste in excess of TCLP levels. Classification: Elementary Neutralization Units Elementary Neutralization Units (ENUs) are used for neutralizing wastes that are hazardous only because they exhibit the corrosivity characteristic (40 WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 44 CFR 260.10 / R315-260-10) (i.e., lab neutralization tank). They are exempted from permitting under 40 CFR 270.1(c)(2)(v) / R315-270- 1(c)(2)(v). The requirements for 40 CFR Parts 264 and 265 / R315-264 and 265 do not apply [40 CFR 264.1(g)(6) / R315-264-1(g)(6) and 265.1(c)(10) / R315-265-1(c)(10)]. The hazardous waste corrosive characteristic is neutralized, and the waste classified as non-hazardous solid waste by generator knowledge. Other material that is not ENU neutralized for the characteristic of corrosivity only will be tested for hazardous waste characteristics before being ENU neutralized (corrosivity D002 only) or disposed. Wastewater Permit Materials treated and discharged to the POTW under the wastewater discharge permit number SLC-0001 are excluded from regulation as a solid waste (therefore not a hazardous waste) under 40 CFR 261.4 (a)(1)(ii) / R315-261-4 (a)(1)(ii). Hazardous Waste Samples containing characteristic (excluding corrosivity D002 only) and/or listed hazardous waste will be segregated, containerized, and handled as hazardous waste. Disposal: Samples failing for corrosivity only are managed in an on site ENU. Treated waters are discharged under wastewater discharge permit SLC- 0001. Samples containing characteristic (excluding corrosivity D002 only) and/or listed hazardous waste will be segregated, containerized, and handled as hazardous waste. Analyses: The pH is monitored to ensure the corrosivity is neutralized when treating in an ENU. If the samples possibly contain characteristic (excluding corrosivity D002 only) and/or listed hazardous waste, sample and test initially (and anytime the process changes) for TCLP characteristics and /or total F- and D-list volatile or semi-volatile organics. Waste Handling: Hazardous wastes will be collected in closed-top drums. Hazardous waste containers will have properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Drums containing flammable liquids must be grounded when adding or removing waste. Shipping: Container DOT Specification: UN/1A1 or 1H1. Waste Code: Varies with waste analyses. Shipping Name: See waste profile. 3.6.9 Unused Laboratory Chemicals Characteristics: Laboratory chemicals that have not been utilized and are in their original containers. Classification: If disposed as waste, will determine if the chemical is a listed or a characteristic hazardous waste. Unused laboratory chemicals are hazardous if they contain a U- or P-listed chemical as the sole active ingredient or fail RCRA characteristics. Disposal: If disposed, dispose off-site at an appropriate facility. Analyses: Not required, determine material properties from SDSs. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 45 3.6.10 Laboratory Chemicals Desiccant and/or Activated Carbon Off Gas Filters Characteristics: Laboratory chemicals desiccant and/or activated carbon off gas filters are used on various laboratory chemicals. Desiccant and/or activated carbon filters may contain various laboratory chemical constituents. Classification: If disposed as waste, determine if the filter material is a listed or a characteristic hazardous waste. Desiccant and/or activated carbon filters are hazardous if they contain a U- or P-listed chemical as the sole active ingredient or fail RCRA characteristics. Disposal: Non-hazardous solid wastes are thrown in the trash. Hazardous wastes are segregated, containerized, and handled as hazardous waste. Analyses: Not required, if material properties are determined from SDSs. If the filter materials possibly contain metals and/or listed solvents, sample and test initially (and anytime the process changes) for TCLP metals and total F- and D-list volatile or semi-volatile organics. 3.6.11 Makeup Air Filters Characteristics: Air filters contain dust from filtering outside. Classification: Non-hazardous solid waste. Disposal: Air filters are thrown in the trash. Analyses: None required. 3.6.12 Water Purification Cartridges and Compressor Desiccant Filters Characteristics: Cartridges and desiccant filters. Classification: Non-hazardous solid waste. Disposal: Thrown in the trash. Analyses: Not required. 3.6.13 Miscellaneous Titration and/or pH Buffer Solutions Characteristics: Titration solutions contain various chemicals. Various pH buffer solutions are also used in the lab. Classification: Most of the solutions are non-hazardous solid wastes. If solutions are contaminated with TCLP Toxicity including metals (D009 mercury and D011 Silver), ignitable or oxidizer liquids (D001), or listed solvents the titration solutions may be regulated as a hazardous waste when discarded. Disposal: Non-hazardous solid waste solutions are poured into the sink drains. Titration solutions known to be contaminated with TCLP Toxicity including metals, ignitable liquid, or listed solvents or other hazardous wastes are segregated, containerized, and handled as hazardous waste. Analyses: Not required unless changes in laboratory processes occur that may change the solution characteristics or if the solution is handled differently. If disposed as waste, will determine if the material is a hazardous waste. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 46 Waste Handling: Hazardous wastes will be collected in closed-top drums. Hazardous waste containers will have properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Drums containing flammable liquids must be grounded when adding or removing waste. Shipping: Container DOT Specification: UN/1A1 or 1H1. Waste Code: Varies with waste analyses. Shipping Name: See waste profile. 3.6.14 Contaminated Personal Protection Equipment (PPE), Floor Sweepings, and/or Trash Characteristics: Contaminated PPE, floor sweepings, and/or trash. Classification: Typically, non-hazardous solid waste. If disposed as waste, determine if the material is contaminated with a listed or a characteristic hazardous waste. Disposal: Non-hazardous solid waste it thrown in the trash. Hazardous wastes are collected in a hazardous waste satellite accumulation container. Analyses: Sample and test contaminated material initially (and anytime the process changes) for TCLP metals and total F- and D-list volatile and semi-volatile organics. These analytes are determined from known contaminants. Waste Handling: Hazardous wastes are collected in open-top drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Shipping: Container DOT Specification: UN/1A2. Waste Code: Varies with waste analyses. Shipping Name: See waste profile. 3.6.15 Hood Scrubber Solution Characteristics: Caustic hood scrubber solution. Classification: Elementary Neutralization Units Elementary Neutralization Units (ENUs) are used for neutralizing wastes that are hazardous only because they exhibit the corrosivity characteristic (40 CFR 260.10 / R315-260-10) (i.e., lab neutralization tank). They are exempted from permitting under 40 CFR 270.1(c)(2)(v) / R315-270- 1(c)(2)(v). The requirements for 40 CFR Parts 264 and 265 / R315-264 and 265 do not apply [40 CFR 264.1(g)(6) / R315-264-1(g)(6) and 265.1(c)(10) / R315-265-1(c)(10)]. The hazardous waste corrosive characteristic is neutralized, and the waste classified as non-hazardous solid waste by generator knowledge. Wastewater Permit Materials treated and discharged to the POTW under the wastewater discharge permit number SLC-0001 are excluded from regulation as a solid waste (therefore not a hazardous waste) under 40 CFR 261.4 (a)(1)(ii) / R315-261-4 (a)(1)(ii). WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 47 Disposal: Caustic hood scrubber solutions failing for corrosivity only is managed in an on site ENU. Treated waters are discharged under wastewater discharge permit SLC-0001. Analyses: The pH is monitored to ensure the corrosivity is neutralized when treating in an ENU. 3.6.16 Empty Reagent Containers Characterization and handling same as Section 3.1.21. 3.6.17 Equipment Bulbs Characterization and handling same as 3.1.3. 3.6.18 Compressed Gas Cylinders Characterization and handling same as Section 3.2.14. 3.6.19 Used Oil Characterization and handling same as Section 3.2.1. 3.7 FUELING FACILITIES Description: The processing operations at the facility require diesel fuel, gasoline, oils, greases, antifreezes, and/or solvents for equipment operation and maintenance. Fueling facilities consist of storage/dispensing facilities for fuels, lubricants, and coolant (glycol-based antifreeze). Typical waste streams from these facilities are described below: 3.7.1 Collected Oil/Grease and Small Spills This Includes used lubricating grease, oil and hydraulic oils, including brake and transmission fluid, generated from vehicle and machinery with minor amounts of fuel constituents and metals. It is facility policy to not mix used oil with solvents, coolants or other waste materials. Analyses have indicated that the oil meets the criteria for specification used oil. Collected oil characterization and handling are the same as 3.2.1. Collected grease characterization and handling are the same as 3.2.3. Small spills characterization and handling are the same as 3.14.1. 3.7.2 Collected Diesel Fuel and Small Spills Diesel fuel collected within secondary containment features. The SDS flash point is reported to be above 140˚F. Collected diesel characterization and handling are the same as 3.2.9. Small spills characterization and handling are the same as 3.14.2. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 48 3.7.3 Contaminated or Waste Gasoline and Small Spills Collected gasoline characterization and handling are the same as 3.2.10. Small spills characterization and handling are the same as 3.14.3. 3.7.4 Collected Used Engine Coolant (Glycol-Based Antifreeze) and small Spills Spilled, engine coolant (antifreeze) collected within secondary containment features. Collected coolant characterization and handling are the same as 3.2.6. Small spills characterization and handling are the same as 3.14.4. 3.7.5 Used Floor Dry Characterization and handling are the same as Section 3.1.10. 3.7.6 Used Rags, Wipes, Absorbent Pads, and Socks Characterization and handling are the same as Section 3.2.5. 3.7.7 Fuel Filters Characterization and handling are the same as Section 3.2.2. 3.7.8 Aerosol Paints, Cleaners, Lubricants, and Vent Filters Characterization and handling are the same as Section 3.1.4. 3.7.9 Oily Water, Used Oil, Sediment/Sludges from Sumps Characterization and handling are the same as Section 3.2.7. 3.8 CHEMICAL MANUFACTURING Description: Chemical manufacturing facility activities include various activities for production of a diversified range of products. Buildings and activities are listed in Table 3.1 below. Table 3.1 Buildings and Activities Building Activity 1 Main Warehouse (Process Support) 2a Aluminum Sulfate Production 2b Ferric and Ferrous Sulfate Production 2c Anhydrous Chlorine Repackaging 3a Various Production Chemicals 3b Warehouse Storage (Process Support) WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 49 Building Activity 3c Sodium Isocyanate Production 3 Outside Various combinations of hydrochloric acid products 4 Sodium Carbonate (Soda Ash) mixtures (i.e., compounding) Production 5 Oxidizer Repackaging Container Wash Area Water Treatment Containments 6 Food and Dairy - Various Production Chemicals 7 Pharmaceutical and Iodine Compounds Production 8 Batch processing from B12 Feed Sulfite to thiosulfate 9 Production Tanks for Repackaging Alcohols, Glycols, and Various Chemicals 9A Warehouse (Process Support) 10 Ammonia for Ammonium Hydroxide Organic Process: Paraformaldehyde (PFA) is reacted w/ MEA to produce monoethanolamine triazine (MEA-T) 11 Calcium Nitrates/Nitrites, Magnesium Nitrate, Sodium Nitrate 12 Sulfite Chemistry Area, Aluminum Chlorate, Ammonium Bisulfite, Potassium Sulfite 14 Truck Shop (Process Support) 15 None 16 Maintenance Shop (Process Support) 17 Laboratory (Process Support) 18 None 19 Tank Farm Area Chemicals from vendors (raw materials) are stored on-site in railcars, tankers, tanks, and/or smaller containers (i.e., totes or drums) for producing Thatcher products (i.e., product component chemicals). Products are produced in designated process locations on-site. Excess product, off-specification (non-conforming chemicals), and/or return material authorized chemicals are used for rework as product component chemicals. Site secondary containment consists of containment for storage tanks (tank farm secondary containments) and site containment (for storage containers and process operations) and area sumps. The Site is reportedly self-contained and is sloped toward the center of the Site. Self- containment includes asphalt and/or concrete surfaces where materials would flow into area sumps. Chemical production operations include raw materials storage with secondary containment, mixing and holding tanks, reaction vessels, piping and transfer equipment, scrubbers, boilers, cooling towers, chillers, dewatering filter presses, various water use treatment, and dust cartridge or bag collectors. Typical waste streams from these facilities are described below: WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 50 3.8.1 Scrubber Solutions Characteristics: Acids or alkaline materials are neutralized. Buildings: B2a, B2b, B2c, B3a, B10, and B11. Classification: Elementary Neutralization Units Elementary Neutralization Units (ENUs) are used for neutralizing wastes that are hazardous only because they exhibit the corrosivity characteristic (40 CFR 260.10 / R315-260-10). They are exempted from permitting under 40 CFR 270.1(c)(2)(v) / R315-270-1(c)(2)(v). The requirements for 40 CFR Parts 264 and 265 / R315-264 and 265 do not apply [40 CFR 264.1(g)(6) / R315- 264-1(g)(6) and 265.1(c)(10) / R315-265-1(c)(10)]. The hazardous waste corrosive characteristic is neutralized, and the waste classified as non- hazardous solid waste by generator knowledge. Wastewater Permit Materials treated and discharged to the POTW under the wastewater discharge permit number SLC-0001 are excluded from regulation as a solid waste (therefore not a hazardous waste) under 40 CFR 261.4 (a)(1)(ii) / R315-261-4 (a)(1)(ii). Disposal: Recycled to the process. Wash water failing for corrosivity only is managed in an on site ENU. Treated waters are discharged under wastewater discharge permit SLC-0001 Analyses: The pH is monitored to ensure the corrosivity is neutralized. 3.8.2 Filter Press Wash Water/Sludge or Used Filter Press Components Characteristics: Process sediment and solutions from processes. Filter press plates/cloth may be rinsed and/or washed. Buildings: B2a, B2b, B2c, B3a, B5, B8, and B11. Classification: Wash water and sediment from filter press plates/cloth may contain corrosive liquid or non-hazardous solid waste. Recycled Solutions are managed as products or returned to the process. Solutions returned to the process are excluded from regulation as a solid waste under 40 CFR 261.4 (a)(8) / R315-261-4 (a)(8) when recycled to the process or under 40 CFR 261.2(e)(1)(i) / R315-261-2(e)(1)(i) because the material is recycled as a raw material into the process. Elementary Neutralization Units Elementary Neutralization Units (ENUs) are used for neutralizing wastes that are hazardous only because they exhibit the corrosivity characteristic (40 CFR 260.10 / R315-260-10). They are exempted from permitting under 40 CFR 270.1(c)(2)(v) / R315-270-1(c)(2)(v). The requirements for 40 CFR Parts 264 and 265 / R315-264 and 265 do not apply [40 CFR 264.1(g)(6) / R315- 264-1(g)(6) and 265.1(c)(10) / R315-265-1(c)(10)]. The hazardous waste corrosive characteristic is neutralized, and the waste classified as non- hazardous solid waste by generator knowledge. Wastewater Permit Materials treated and discharged to the POTW under the wastewater discharge permit number SLC-0001 are excluded from regulation as a WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 51 solid waste (therefore not a hazardous waste) under 40 CFR 261.4 (a)(1)(ii) / R315-261-4 (a)(1)(ii). Disposal: Solutions are recycled to the process. Wash water and sediment flows to the area sump. Wash water failing for corrosivity only is managed in an on site ENU. Treated waters are discharged under wastewater discharge permit SLC-0001. Sludge is disposed in roll-offs and an approved and permitted disposal or agriculture facility. Unusable filter press components may be rinsed before they are thrown in the trash. Analyses: The pH is monitored to ensure the corrosivity is neutralized when treating in an ENU. Sediment has been sampled, analyzed, and classified as non- hazardous solid waste. 3.8.3 Filter Press Cake Characteristics: Process sediment from the processes. Buildings: B2a, B2b, B2c, B3a, B5, B8, and B11. Classification: Filter press cake is a non-hazardous solid waste per generator knowledge. Disposal: Sediment is disposed in roll-offs at an approved and permitted disposal or agriculture facility. Analyses: Sediment has been sampled, analyzed, and classified as non-hazardous solid waste. 3.8.4 Dust Collectors or Bag Filters Characteristics: Dust, cartridges, and/or bags from the various processes. Buildings: B2c, B3a, B3c, B4, B6, B7, and B11. Classification: Recycled Dust returned to the process is excluded from regulation as a solid waste under 40 CFR 261.2(e) / R315-261-2(e). Non-hazardous Solid Waste Cartridges and bags may be rinsed and managed as non-hazardous solid waste by generator knowledge. Hazardous Waste Cartridges and bags that contain characteristic and/or listed hazardous waste will be segregated, containerized, and handled as hazardous waste. Disposal: Dust is returned to the process for use. Non-hazardous solid waste cartridges and bags are thrown in the trash. Cartridges and bags that contain characteristic and/or listed hazardous waste will be segregated, containerized, and handled as hazardous waste. Analyses: Not required if material is recycled to the process from which the material originated. If the cartridges and/or bags possibly contain metals and/or F- listed solvents, sample and test initially (and anytime the process changes) for TCLP metals and total F- and D-list volatile organics. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 52 3.8.5 Area Sumps Characteristics: Characteristics depend on the location of the sump in the process and the presence of any spilled chemicals in the sump contents. Typical characteristics associated with an area include floor wash water with de minimis amounts of spilled equipment (pumps, compressors etc.) lube oil and process chemicals. Classification: Recycled Sump cleanouts that are recycled to the process from which the material originated are excluded from RCRA solid waste under 40 CFR 261.4 (a)(8) / R315-261-4 (a)(8) and/or 40 CFR 261.2(e) / R315-261-2(e). Elementary Neutralization Units Elementary Neutralization Units (ENUs) are used for neutralizing wastes that are hazardous only because they exhibit the corrosivity characteristic (40 CFR 260.10 / R315-260-10). They are exempted from permitting under 40 CFR 270.1(c)(2)(v) / R315-270-1(c)(2)(v). The requirements for 40 CFR Parts 264 and 265 / R315-264 and 265 do not apply [40 CFR 264.1(g)(6) / R315- 264-1(g)(6) and 265.1(c)(10) / R315-265-1(c)(10)]. The hazardous waste corrosive characteristic is neutralized, and the waste classified as non- hazardous solid waste by generator knowledge. Spilled Material Other spilled material collected in sumps that is not recycled to the process circuit from which it originated, ENU neutralized for the characteristic of corrosivity only will be tested for hazardous waste characteristics before being recycled to the process, ENU neutralized, or disposed. Hazardous Waste Sump cleanouts containing characteristic and/or listed hazardous waste will be segregated, containerized, and handled as hazardous waste. Wastewater Permit Materials treated and discharged to the POTW under the wastewater discharge permit number SLC-0001 are excluded from regulation as a solid waste (therefore not a hazardous waste) under 40 CFR 261.4 (a)(1)(ii) / R315-261-4 (a)(1)(ii). Disposal: Recycled to the process. Wash water failing for corrosivity only is managed in an on site ENU. Treated waters are discharged under wastewater discharge permit SLC-0001. Sump cleanouts containing characteristic and/or listed hazardous waste will be segregated, containerized, and handled as hazardous waste. Analyses: Not required if material is recycled to the process from which the material originated. The pH is monitored to ensure the corrosivity is neutralized when treating in an ENU. If the soil/sludge possibly contains metals and/or F-listed solvents, sample and test initially (and anytime the process changes) for TCLP metals and total F- and D-list volatile organics. 3.8.6 Boiler Blowdown Characteristics: Boiler water and scale. Scale from intake water may contain metals. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 53 Buildings: B11 and B7. Classification: Non-hazardous solid waste. Disposal: Water flows to the area sump which is pumped to the water treatment. Wastewater Permit Materials treated and discharged to the POTW under the wastewater discharge permit number SLC-0001 are excluded from regulation as a solid waste (therefore not a hazardous waste) under 40 CFR 261.4 (a)(1)(ii) / R315-261-4 (a)(1)(ii). Analyses: Not required. 3.8.7 Boiler Chemical Cleaning Characteristics: Water, cleaning chemicals, and scale. Scale from intake water may contain metals. Classification: The wastewater may be hazardous if heavily contaminated with regulated metals, listed cleaning solvents, and/or characteristic cleaning solvents. Cleaning waste must be sampled and tested for classification. Disposal: Non-hazardous wash water is disposed in the area sump. Wash water failing for corrosivity only is managed in an on site ENU. Hazardous waste wastewater is disposed of as hazardous waste off site. Analyses: For wash water containing regulated metals, listed cleaning solvents, and/or characteristic cleaning solvent waste, characterization review of generator knowledge, SDS, and/or testing may be required to determine regulatory status. Test for pH and TCLP metals before disposing. 3.8.8 Demineralization Water Treatment and Reverse Osmosis Filter Cleaning Wash Water Characteristics: Anion, cation, and/or mixed bed resin used in demineralizer vessels that has been exhausted and can no longer be regenerated in an efficient manner. Resin or reverse osmosis filter cleaning chemicals and/or backwash water. Sodium chloride (salt) may be used to regenerate the resin. Rinsed filters. Classification: Non-hazardous Solid Waste Brine, wash water and/or scale is typically non-hazardous solid waste but this wastewater and/or scale may contain listed or characteristic hazardous waste according to generator knowledge. Elementary Neutralization Units Elementary Neutralization Units (ENUs) are used for neutralizing wastes that are hazardous only because they exhibit the corrosivity characteristic (40 CFR 260.10 / R315-260-10). They are exempted from permitting under 40 CFR 270.1(c)(2)(v) / R315-270-1(c)(2)(v). The requirements for 40 CFR Parts 264 and 265 / R315-264 and 265 do not apply [40 CFR 264.1(g)(6) / R315- 264-1(g)(6) and 265.1(c)(10) / R315-265-1(c)(10)]. The hazardous waste corrosive characteristic is neutralized, and the waste classified as non- hazardous solid waste by generator knowledge. Hazardous Waste WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 54 The wastewater or sludge may be hazardous if heavily contaminated with regulated metals, listed cleaning solvents, and/or characteristic cleaning solvents. Wastewater Permit Materials treated and discharged to the POTW under the wastewater discharge permit number SLC-0001 are excluded from regulation as a solid waste (therefore not a hazardous waste) under 40 CFR 261.4 (a)(1)(ii) / R315-261-4 (a)(1)(ii). Disposal: Wash water and sediment flows to the area sump. Wash water failing for corrosivity only is managed in an on site ENU. Treated waters are discharged under wastewater discharge permit SLC-0001. Used resins are disposed of off site at approved facilities or managed by vendors. Sludge containing characteristic and/or listed hazardous waste will be segregated, containerized, and handled as hazardous waste. Analyses: The pH is monitored to ensure the corrosivity is neutralized when treating in an ENU. If the used resin and/or sediment possibly contains metals and/or F-listed solvents, sample and test initially (and anytime the process changes) for TCLP metals and total F- and D-list volatile organics. 3.8.9 Reverse Osmosis Water Filters Characteristics: Rinsed cartridges filters. Classification: Non-hazardous solid waste. Disposal: Thrown in the trash. Analyses: Not required. 3.8.10 Heat Exchanger, Cooling Tower, Chillers and/or Strainers Pressure or Acid Wash Waste Characteristics: Wash water and/or acid wash water. Heat exchanger, cooling tower, and/or chillers are closed loop water systems. Building B12 cooling tower process chemical bleed. Classification: Building 12 Cooling Tower Bleed Is managed under the wastewater permit. Non-hazardous Solid Waste Wash water and system water is typically non-hazardous solid waste. Elementary Neutralization Units Elementary Neutralization Units (ENUs) are used for neutralizing wastes that are hazardous only because they exhibit the corrosivity characteristic (40 CFR 260.10 / R315-260-10). They are exempted from permitting under 40 CFR 270.1(c)(2)(v) / R315-270-1(c)(2)(v). The requirements for 40 CFR Parts 264 and 265 / R315-264 and 265 do not apply [40 CFR 264.1(g)(6) / R315- 264-1(g)(6) and 265.1(c)(10) / R315-265-1(c)(10)]. The hazardous waste corrosive characteristic is neutralized, and the waste classified as non- hazardous solid waste by generator knowledge. Wastewater Permit WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 55 Materials treated and discharged to the POTW under the wastewater discharge permit number SLC-0001 are excluded from regulation as a solid waste (therefore not a hazardous waste) under 40 CFR 261.4 (a)(1)(ii) / R315-261-4 (a)(1)(ii). Hazardous Waste The wash water and/or acid wastewater may be hazardous if heavily contaminated with regulated metals, listed cleaning solvents, and/or characteristic cleaning solvents. Disposal: Wash water and sediment flows to the area sump. Wash water failing for corrosivity only is managed in an on site ENU. Treated waters are discharged under wastewater discharge permit SLC-0001. Wash water and/or sludge containing characteristic and/or listed hazardous waste will be segregated, containerized, and handled as hazardous waste. Analyses: The pH is monitored to ensure the corrosivity is neutralized when treating in an ENU. If the wash water and/or sediment possibly contains metals and/or F-listed solvents, sample, and test initially (and anytime the process changes) for TCLP metals and total F- and D-list volatile organics. 3.8.11 Sodium Hypochlorite Cooling Tower Bleed Characteristics: Water, chlorine, and sodium hydroxide solutions from building 2C sodium hypochlorite cooling tower bleed. Classification: Recycled Materials that are recycled to the process from which the material originated are excluded from RCRA solid waste under 40 CFR 261.4 (a)(8) / R315-261-4 (a)(8) and/or 40 CFR 261.2(e) / R315-261-2(e). Disposal: Recycled to the process. Analyses: Not required if material is recycled to the process from which the material originated 3.9 UTILITIES AND RAW MATERIALS Description: Chemical manufacturing facility activities include various activities for production of a diversified range of products. Chemicals from vendors (raw materials) are stored and unloaded on-site. Containers include railcars, tankers, tanks, and/or smaller containers (i.e., totes or drums) for producing Thatcher products (i.e., product component chemicals). Site secondary containment consists of containment for storage tanks (tank farm secondary containments) and site containment (for storage containers and process operations) and area sumps. The Site is reportedly self-contained and is sloped toward the center of the Site or area sumps. Self- containment includes asphalt and/or concrete surfaces where materials and stormwater would flow into area sumps. Typical waste streams from these facilities are described below: 3.9.1 Area Sumps and Water Treatment Containments Characteristics: Characteristics depend on the location of the sumps in the process (i.e., raw material storage areas, tank farms and/or general area sumps), the presence of any spilled chemicals in the sump contents, and/or materials WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 56 in the water treatment containments. Typical characteristics associated with an area include stormwater, floor or area wash water, and/or process water with de minimis amounts of spilled equipment (pumps, compressors etc.) lube oil and process chemicals. Classification: Storm Water Non-hazardous Solid Waste Storm water used in the process is non-hazardous solid waste unless it contains characteristic and/or listed hazardous waste. Elementary Neutralization Units Elementary Neutralization Units (ENUs) are used for neutralizing wastes that are hazardous only because they exhibit the corrosivity characteristic (40 CFR 260.10 / R315-260-10). They are exempted from permitting under 40 CFR 270.1(c)(2)(v) / R315-270-1(c)(2)(v). The requirements for 40 CFR Parts 264 and 265 / R315-264 and 265 do not apply [40 CFR 264.1(g)(6) / R315- 264-1(g)(6) and 265.1(c)(10) / R315-265-1(c)(10)]. The hazardous waste corrosive characteristic is neutralized, and the waste classified as non- hazardous solid waste by generator knowledge. Wastewater Permit Materials treated and discharged to the POTW under the wastewater discharge permit number SLC-0001 are excluded from regulation as a solid waste (therefore not a hazardous waste) under 40 CFR 261.4 (a)(1)(ii) / R315-261-4 (a)(1)(ii). Hazardous Waste Sump or containment cleanouts containing characteristic and/or listed hazardous waste will be segregated, containerized, and handled as hazardous waste. Disposal: Wash water failing for corrosivity only is managed in an on site ENU. Treated waters are discharged under wastewater discharge permit SLC- 0001. Sump cleanouts containing characteristic and/or listed hazardous waste will be segregated, containerized, and handled as hazardous waste. Analyses: Not required if material is recycled to the process from which the material originated. The pH is monitored to ensure the corrosivity is neutralized when treating in an ENU. If the soil/sludge possibly contains metals and/or F-listed solvents, sample and test initially (and anytime the process changes) for TCLP metals and total F- and D-list volatile organics. 3.9.2 Container Wash Areas Characteristics: Characteristics depend on the container contents. Container wash includes Building 5 and 6 (containers) and B2c (cylinders). Classification: Elementary Neutralization Units Elementary Neutralization Units (ENUs) are used for neutralizing wastes that are hazardous only because they exhibit the corrosivity characteristic (40 CFR 260.10 / R315-260-10). They are exempted from permitting under 40 CFR 270.1(c)(2)(v) / R315-270-1(c)(2)(v). The requirements for 40 CFR Parts 264 and 265 / R315-264 and 265 do not apply [40 CFR 264.1(g)(6) / R315- 264-1(g)(6) and 265.1(c)(10) / R315-265-1(c)(10)]. The hazardous waste WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 57 corrosive characteristic is neutralized, and the waste classified as non- hazardous solid waste by generator knowledge. Wastewater Permit Materials treated and discharged to the POTW under the wastewater discharge permit number SLC-0001 are excluded from regulation as a solid waste (therefore not a hazardous waste) under 40 CFR 261.4 (a)(1)(ii) / R315-261-4 (a)(1)(ii). Hazardous Waste Sump cleanouts containing characteristic and/or listed hazardous waste will be segregated, containerized, and handled as hazardous waste. Disposal: Wash water failing for corrosivity only is managed in an on site ENU. Treated waters are discharged under wastewater discharge permit SLC- 0001. Sump cleanouts containing characteristic and/or listed hazardous waste will be segregated, containerized, and handled as hazardous waste. Analyses: Not required if material is recycled to the process from which the material originated. The pH is monitored to ensure the corrosivity is neutralized when treating in an ENU. If the soil/sludge possibly contains metals and/or F-listed solvents, sample and test initially (and anytime the process 3.9.3 Water Treatment Filter Press Characterization and handling are the same as Section 3.8.2. 3.9.4 Water Treatment Filter Cake Characterization and handling are the same as Section 3.8.3. 3.9.5 Oil Water Separators Characterization and handling are the same as Section 3.7.9. Buildings: B7 and B16. 3.9.6 Sodium Hydroxide Reagents Area Sumps Characteristics: Storm water and area wash water with de minimis amounts of spilled liquid sodium hydroxide, hydraulic oil, and lubricating oil. Classification: Water with de minimis amounts of reagents is non-hazardous solid waste, not regulated as a solid waste under 40 CFR 261.2(e)(1)(i) and (ii) / R315- 261-2(e)(1)(i) and (ii) when recycled to the process, and/or excluded from regulation as a solid waste under 40 CFR 261.4 (a)(8) / R315-261-4 (a)(8) when recycled to the process. Disposal: Recycled to the process. Analyses: Not required for water with de minimis amounts of reagents. For spill cleanup waste characterization, a review of SDS and/or testing may be required to determine regulatory status. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 58 3.9.7 Antiscalant Area Sump Characteristics: Storm water and area wash water with de minimis amounts of spilled antiscalant, hydraulic oil, and lubricating oil. Classification: Water with de minimis amounts of reagents is non-hazardous solid waste and excluded from regulation as a solid waste under 40 CFR 261.4 (a)(8) / R315-261-4 (a)(8). Disposal: Recycled to the process. Analyses: Not required. 3.9.8 Acid Area Sumps Characteristics: Storm water and area wash water with de minimis amounts of spilled hydrochloric acid, nitric acid, acetic acid, phosphoric acid, antiscalant, hydraulic oil, and lubricating oil. Classification: Water with de minimis amounts of reagents is non-hazardous solid waste. Disposal: Recycled to the process. Analyses: Not required for water with de minimis amounts of reagents. For spill cleanup waste characterization, a review of SDS and/or testing may be required to determine regulatory status. 3.9.9 Miscellaneous Reagent Area Sumps Characteristics: Storm water and area wash water with de minimis amounts of spilled reagents, hydraulic oil, and lubricating oil. Classification: Water with de minimis amounts of reagents is non-hazardous solid waste. If RCRA listed reagents are used, they must be reviewed on a case-by- case basis; see Section 3.14. Disposal: Reviewed and determined on a case-by-case basis. Analyses: Not required for water with de minimis amounts of reagents. For spill cleanup waste characterization, a review of SDS and/or testing may be required to determine regulatory status. 3.9.10 Boiler Solution (Heat Transfer Solution) Characteristics: Propylene glycol heat transfer solution used in various boilers may contain regulated metals. Propylene glycol is toxic by ingestion. Classification: Non-hazardous solid waste unless contaminated with metals. If solutions are heavily contaminated with metals and metals exceed the TCLP metals regulatory levels, solutions would be regulated as hazardous waste. Disposal: Typically used consumptively or reused. Accumulated heat transfer solution is collected in drums or tanks for recycling and recycled on site or off site (by an approved facility). The approved contractor routinely tests and evacuates the used antifreeze storage tank. Used heat transfer solution storage containers including drums and tanks must be marked with the words “Used Antifreeze.” Hazardous wastes should be segregated, containerized, and handled as hazardous waste. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 59 Analyses: Use heat transfer solution SDSs, apply generator knowledge and/or sample initially (and any time the process changes). 3.10 SPILL CLEANUP Description: The cleanup of spilled materials produces waste streams consisting of the spilled materials and soil or cleanup waste (adsorbents, rags, wash water, etc.) contaminated with the spilled materials. Spilled material that is containerized and used for its intended purpose is not a hazardous waste. According to the mixture rule, 40 CFR 261.3(a) / R315-261-3(a), contaminated soil or cleanup waste resulting from the spill of a listed hazardous waste which is listed as a toxic (T) or acute hazardous waste (H) [40 CFR 261.30/ R315-261-30] is itself a hazardous waste. Listed hazardous waste includes commonly encountered F-list (F001-F005) spent solvents. F-list only applies to solvent used for their solvent properties that dissolve or mobilize other constituents. The F-list spent solvent must contain at least 10% of one or more of the F-list solvents before use. Contaminated soil or cleanup waste resulting from the spill of a characteristic hazardous waste, whether listed or not, would itself be a hazardous waste only if the soil or cleanup material also exhibited the hazardous characteristic. The applicable hazardous characteristics are: ignitability (I), corrosivity (C), reactivity (R), or toxicity characteristic (E) [40 CFR 261.20 - .24/ R315-261-20-24]. However, disposal of these materials will need to comply with the applicable land disposal restriction (LDR) regulations [LDR regulations are found in 40 CFR Part 268/ R315-268]. Hazardous waste cleanup wastes are containerized and handled as hazardous wastes. Petroleum contaminated soils are containerized and disposed of off site at approved facilities. The following spill waste streams may potentially be produced at the facility: 3.10.1 Soils or Cleanup Material Contaminated with Oil and/or Grease Characteristics: Lubricating oil, hydraulic oil, used oil, grease and/or soil and cleanup material. Classification: Normally non-hazardous solid waste, however, if the oil/grease was previously contaminated with F-listed solvents and/or heavily contaminated with metals, the mixture would be regulated as an F-listed and/or characteristic hazardous waste when discarded. Disposal: Petroleum contaminated soils is containerized and disposed at off site approved facilities. Non-draining absorbent cleanup material is routinely discarded in the trash; however, large quantities generated from a spill cleanup are containerized for characterization prior to disposal. Soil contaminated with solvents or other hazardous materials will be segregated, sampled, and containerized for testing before being sent to a permitted facility. Analyses: Apply generator knowledge; use previous characterization and/or SDS information. Sample and test if necessary due to process or product changes. Sample and test for TCLP metals, F- and D-list total volatiles and F- and D-list semi-volatiles in order to characterize. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 60 3.10.2 Soils or Cleanup Materials Contaminated with Diesel Fuel Characteristics: Diesel fuel contaminated soil or cleanup materials. Classification: Flash point is typically above 140˚F for diesel fuel used at the facility, which would not be RCRA ignitable. Disposal: Petroleum contaminated soils is containerized and disposed at off site approved facilities. Floor dry contaminated with adsorbed (no free liquid) diesel fuel is thrown in the trash. Analyses: Not required unless wet with lower flash point (<140˚F) diesel fuel. Mixtures of lower flash point (<140˚F) diesel fuel and other materials will be tested for ignitability. 3.10.3 Soils or Cleanup Materials Contaminated with Gasoline and/or Kerosene Characteristics: Contaminated or off-specification waste gasoline from fueling vehicles or from spills. In addition, contaminated water and/or spills from the gasoline storage tank and fuel pump. Contaminated or off specification kerosene from use for heating or from spills. Liquid waste must not be solidified for disposal. Classification: Possible hazardous waste due to characteristics of ignitability (D001) and benzene (D018) if present in strong concentrations. Exempt from regulation if used as a fuel (such as burned for energy recovery). Disposal: Small quantities of gasoline or kerosene (1%) may be mixed with used oil for recycling or energy recovery. Liquid ga soline and kerosene disposed as a hazardous waste is shipped as D001 and/or D018 hazardous waste if the discarded material exhibits the characteristics. Exempt if used as a fuel. Non-hazardous soil contaminated with small amounts of gasoline or kerosene is containerized and disposed at off site approved facilities. Solids/sludges that are wet with ignitable liquids are segregated, containerized, and handled as hazardous waste. Analyses: Apply generator knowledge; use previous characterization and/or SDS information. Mixtures of gasoline, kerosene, and other materials to be disposed off site will be tested for ignitability, TCLP benzene for solids and/or total benzene for liquids. Mixtures of gasoline, kerosene, and other materials that are recycled or used for energy recovery do not require testing. Waste Handling: Recyclable material or hazardous wastes will be collected in open-top drums. Hazardous waste containers will have properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Drums containing flammable liquids must be grounded when adding or removing waste. Shipping: Container DOT Specification: UN/1A2 Waste Code: D001 and/or D018 for hazardous waste and none if used as a fuel. Shipping Name: See waste profile. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 61 3.10.4 Soils or Cleanup Materials Contaminated with Alcohol Characteristics: Contaminated or off-specification waste alcohol from spills. Liquid waste must not be solidified for disposal. Classification: Possible hazardous waste due to characteristics of ignitability (D001) or unused commercial chemical product sole active ingredient methanol (U154) if present in strong concentrations. Disposal: Liquid alcohol disposed as a hazardous waste is shipped as D001 or methanol (U154) hazardous waste if the discarded material exhibits the characteristics. Solids/sludges that are wet with ignitable liquids are segregated, containerized, and handled as hazardous waste. Analyses: Apply generator knowledge; use previous characterization and/or SDS information. Mixtures of alcohol and other materials to be disposed off site will be tested for ignitability. Waste Handling: Hazardous wastes will be collected in closed-top drums. Hazardous waste containers will have properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Drums containing flammable liquids must be grounded when adding or removing waste. Shipping: Container DOT Specification: UN/1A2 Waste Code: D001 or methanol (U154). Shipping Name: See waste profile. 3.10.5 Soils or Cleanup Materials Contaminated with Oxidizer Characteristics: Contaminated or off-specification waste oxidizer from spills. Liquid waste must not be solidified for disposal. Classification: Possible hazardous waste due to characteristics of oxidizer (D001) if present in strong concentrations. Disposal: Liquid oxidizer disposed as a hazardous waste is shipped as D001 hazardous waste if the discarded material exhibits the characteristic. Solids/sludges that are wet with oxidizer liquids are segregated, containerized, and handled as hazardous waste. Analyses: Apply generator knowledge; use previous characterization and/or SDS information. Mixtures of oxidizer and other materials to be disposed off site will be tested for oxidizer. Waste Handling: Hazardous wastes will be collected in closed-top drums. Hazardous waste containers will have properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Drums containing flammable liquids must be grounded when adding or removing waste. Shipping: Container DOT Specification: UN/1A2, or 1H2. Waste Code: D001. Shipping Name: See waste profile. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 62 3.10.6 Soils or Cleanup Materials Contaminated with Engine Coolant or Heat Transfer Solution Characteristics: Glycol-based engine coolant, glycol-based heat transfer solution (boiler propylene glycol) and/or water from closed loop cooling systems equipment, boilers, soil, and cleanup materials. Cleanup materials may contain regulated metals and/or benzene. Ethylene and/or propylene glycol is toxic by ingestion. Classification: Non-hazardous solid waste unless contaminated with metals, fuels, solvents, or other maintenance wastes the mixture may be regulated as a characteristic hazardous waste when discarded. Disposal: Non-hazardous, non-draining materials are thrown in the trash. Glycol- based coolant or heat transfer solution, known to be contaminated with metals, fuels, solvents, or other maintenance wastes, is segregated, containerized, sampled, and tested for classification. Hazardous wastes are containerized and handled as hazardous waste. Analyses: Not required except for characterization of potentially contaminated glycol-based coolant or heat transfer solution. For spill cleanup waste characterization, a review of the SDS and/or testing may be required to determine regulatory status. 3.10.7 Soils or Cleanup Materials Contaminated with Used Non-Listed Solvent Characteristics: Used, spilled cleaning solvent mixed with soil or cleanup materials. Classification: Typically, non-hazardous unless there is sufficient metal content in the spilled solvent to fail TCLP toxicity for metals or if an F-listed solvent has been mixed with the solvent. Disposal: Acceptable non-hazardous solid wastes with free liquids must be solidified/dried before disposing in the trash. Soil contaminated with listed solvents or other hazardous materials will be segregated, sampled, and containerized for testing before being sent to a RCRA-permitted facility. Analyses: Sample and test for TCLP metals, flash point, and volatile organics. Waste Handling: Hazardous wastes will be collected in open-top drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Shipping: Container DOT Specification: UN/1A2. Waste Code: Varies with waste constituents. Shipping Name: See waste profile. 3.10.8 Soils or Cleanup Materials Contaminated with Used Paint Thinner or F-Listed Cleaning Solvent Characteristics: Used thinner or F-listed solvent mixed with soil or cleanup materials. Classification: Most of these products will fall under one of the F-listed solvents (F001- F005) when spent and discarded. Used solvent may also contain enough metals to fail TCLP toxicity for metals and/or flash point. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 63 Disposal: Hazardous waste must be disposed at a RCRA-permitted facility. Analyses: Sample and test for TCLP metals, flash point, and volatile organics. Waste Handling: Hazardous wastes will be collected in open-top drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Shipping: Container DOT Specification: UN/1A2. Waste Code: Varies with waste constituents. Shipping Name: See waste profile. 3.10.9 Soils or Cleanup Materials Contaminated with Unused Paint, Blended Commercial Formulations, or Chemical Mixtures Characteristics: Paint, commercial products, or chemical products consisting of blends of chemicals mixed with soil or cleanup materials. Commercial formulations may be characteristic hazardous waste (e.g. a commercial formulation of paint thinner may be hazardous due to ignitability and/or toxicity characteristics). Classification: Typically, non-hazardous but may be hazardous by characteristic depending on the chemical properties of the spilled material. Review the SDS for the spilled material to see if it would be a hazardous waste under any of the characteristics. If the concentration of a characteristic hazardous waste is high enough in the soil or cleanup materials, the mixture may exhibit the hazardous characteristic and be a hazardous waste. Disposal: Acceptable non-hazardous solid wastes with free liquids must be solidified/dried before disposing in the trash. Mixtures exhibiting a hazardous waste characteristic are disposed as hazardous waste. Analyses: Not typically required if information on hazardous waste characteristics can be obtained from SDSs. If SDS information indicates that the contaminated soil may exhibit a hazardous characteristic, analyze the mixture for that characteristic. Waste Handling: Hazardous wastes will be collected in open-top drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Shipping: Container DOT Specification: UN/1A2. Waste Code: Varies with waste constituents. Shipping Name: See waste profile. 3.10.10 Soils or Cleanup Materials Contaminated with Acid Characteristics: Acid mixed with soil or cleanup materials. Classification: Typically, not a hazardous waste at low acid concentrations. Recycled reagents are excluded from regulation as a solid waste under 40 CFR 261.2(e)(1)(ii) / R315-261-2(e)(1)(ii). May be a corrosive hazardous waste (D002) if saturated with acid and the mixture has a pH less than 2.0. Non- hazardous solid waste after being neutralized according to SDS recommendations. WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 64 Disposal: Containerize liquid waste for use or disposal. Treat spills according to directions in SDS. Dispose of non-liquid non-hazardous waste in the trash. Analyses: Mixtures of acid and other materials that are recycled do not require testing. Sample and test pH on free liquid waste if disposed. Waste Handling: Hazardous wastes will be collected in open-top drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Shipping: Container DOT Specification: UN/1H2. Waste Code: D002 for hazardous waste. Shipping Name: See waste profile. 3.10.11 Soils or Cleanup Materials Contaminated with Caustics and/or Lime Characteristics: Caustic (sodium hydroxide), antiscalant (sodium hydroxide mixture), Trasar Trac 101 (sodium nitrate used in the boiler), and/or lime reagents mixed with soil or cleanup materials. Classification: Typically, not a hazardous waste at low caustic/alkaline concentrations. Recycled reagents are excluded from regulation as a solid waste under 40 CFR 261.2(e)(1)(ii) / R315-261-2(e)(1)(ii). May be a corrosive hazardous waste (D002) if saturated with caustic and the mixture has a pH greater than 12.5. Non-hazardous solid waste after being neutralized according to SDS recommendations. Disposal: Containerize liquid waste for use or disposal. Treat spills according to directions in SDS. Dispose of non-liquid non-hazardous waste in the trash. Analyses: Mixtures of caustic materials and other materials that are recycled do not require testing. Sample and test pH on free liquid waste if disposed. Waste Handling: Hazardous wastes will be collected in open-top drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Shipping: Container DOT Specification: UN/1H2. Waste Code: D002 for hazardous waste. Shipping Name: See waste profile. 3.10.12 Soils or Cleanup Materials Contaminated with Antiscalant Characteristics: Antiscalant (without acid or caustic constituents) mixed with soil or cleanup materials. Classification: Non-hazardous solid waste. Disposal: Recycled to the process. Analyses: Not required. 3.10.13 Soils or Cleanup Materials Contaminated with a Pure Chemical Characteristics: Any pure chemical or a commercial formulation with one essentially pure form chemical sole-active ingredient mixed with soil or cleanup materials. Classification: May be a listed hazardous waste or be hazardous by characteristic depending on the chemical properties of the spilled material. Review the WASTE ANALYSIS AND DESIGNATION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 65 SDS of the spilled material to see if it would be a hazardous waste under any of the characteristics or listed hazardous waste constituents. Review the hazardous waste listings in 40 CFR 261.33/ R315-261-33 to see if the chemical is listed. If the spilled chemical is listed as a hazardous waste in 40 CFR 261.33/ R315-261-33, the mixture is also hazardous, unless it is listed only for the characteristics of ignitability (I), corrosivity (C), or reactivity (R), then the resulting mixture is hazardous only if it exhibits the characteristic. Mixtures listed for other than characteristics of I, C, or R are hazardous waste bearing the P or U hazardous waste number of the chemical. Disposal: Acceptable non-hazardous solid wastes with free liquids must be solidified/dried before disposing in the trash. Dispose of in a hazardous waste disposal facility for mixtures with a listed hazardous waste or mixtures exhibiting a hazardous waste characteristic. Analyses: Not typically required if information on hazardous waste characteristics can be obtained from SDSs. If SDS information indicates that the contaminated soil may exhibit a hazardous characteristic, analyze the mixture for that characteristic. Waste Handling: Hazardous wastes will be collected in open-top drums having properly completed EPA hazardous waste markings, including the date when the drum becomes full or 55 gallons of the waste has accumulated. Shipping: Container DOT Specification: UN/1A2. Waste Code: Varies with constituents. Shipping Name: See waste profile. ACCEPTABLE Solid WASTE (Trash) for off site disposal August 2020 Thatcher Solid and Hazardous Waste Management Plan 66 4.0 ACCEPTABLE SOLID WASTE (TRASH) FOR OFF SITE DISPOSAL 4.1 GENERAL DESCRIPTION OF ACCEPTABLE SOLID WASTES All waste to be placed in the trash containers will be incidental to the industrial operation (see Table 1). Examples of acceptable wastes include: • Untreated wood wastes • Paper products • Drained and crushed oil filters • Empty containers (x 3 rinse) crushed or cut • Five-gallon empty containers or smaller with lids off • Office and lunch room wastes • Uncontaminated piping and liner material Acceptable non-hazardous solid wastes (trash) are disposed in trash containers on site and transported for disposal off site at permitted county landfills. Acceptable non-hazardous solid wastes with free liquids must be solidified/dried before disposing in the trash. 4.2 FACILITY CONSTRUCTION WASTES The construction of new facilities at the facility will generate some wastes. These wastes will include wood, paper, and other non-salvageable metal products. The disposal of these wastes will continue intermittently for the life of the facility site. 4.3 TRASH The disposal of domestic waste will be minimal since no on site housing exists or is planned. Therefore, the amount of domestic waste to be disposed will be generated by the employees only during their working hours. 4.4 PROHIBITED AND HAZARDOUS WASTE The following materials cannot be disposed in the off site landfill (see Table 1): • Hazardous waste • Batteries • Liquid wastes • Unpunctured aerosol cans • Undrained oil filters • Drums which are not empty and crushed • Household hazardous wastes • Highly putrescible wastes, including dead animals ACCEPTABLE Solid WASTE (Trash) for off site disposal August 2020 Thatcher Solid and Hazardous Waste Management Plan 67 • Spent cleaning solvents • Household wastes brought on site by employees Table 4.1 - Prohibited and Acceptable Waste List Prohibited Wastes Acceptable Wastes Hazardous Wastes Paper Products Liquids (Oil/Paint/Solvents/Antifreeze) Untreated Wood Pallets/Crates/Scrap Unpunctured Aerosol Cans Scrap Metal/Plastic Batteries Empty Cloth/Plastic Bags Drums (Undrained/Uncrushed/Uncut) Empty Cut-in-Half Plastic Drums or Crushed Steel Drums Undrained Oil Filters Empty Metal/Plastic Buckets/Cans/Bottles (Lids off) Contaminated Piping and Liner Office Wastes Contaminated Soils (Lead/Hydrocarbons) Lunch Room Wastes Dead Animals Oily Rags/Gloves Spill Cleanup Materials (PPE/Soil/Debris) Clean Piping/Liner Materials Sludges (Sewage/Sumps) Unsalvageable Parts Grease (All types) Drained and Crushed Filters Transformers/Capacitors Clean Construction (Concrete/Wood) Explosives Medical Wastes Large Used Tires Lamps CONTAINER MANAGEMENT PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 68 5.0 CONTAINER MANAGEMENT PLAN This Container Management Plan has been prepared in compliance with the requirements of the federal hazardous waste regulation found in 40 CFR Part 262.15 / R315-262-15 and/or 262.17 / R315-262-17, and Company guidelines. This plan applies to all containers used to hold hazardous materials/wastes, non-hazardous materials/wastes, and universal wastes generated at the facility. Containers shall be in good condition with no leaks, dents, corrosion, or any other defect that may compromise the integrity of the container. Container construction will be compatible with the contents. 5.1 TYPES OF CONTAINERS The following descriptions are for approved types of containers to be used for accumulation and temporary storage of hazardous wastes and hazardous materials. The Safety-Health- Environment Department shall review and approve any containers not listed below to be used for hazardous materials/wastes, non-hazardous materials/wastes, and universal wastes. 5.1.1 Intermediate Bulk Containers (IBC) or Roll-Offs Roll-off containers are used to contain bulk quantities of non-liquid hazardous waste and non- hazardous waste. IBC containers used to contain liquids, shall meet Department of Transportation (DOT) United Nations (UN) specifications. Roll-offs will meet DOT non-sift proof requirements. The construction material for the bulk containers will be compatible with the characteristics of the wastes to be contained. This should be determined in consultation with the Safety-Health-Environment Department. All bulk containers will be in good condition with no damage or corrosion that would impair the ability of the bulk containers to contain the wastes. The tops of roll-offs should incorporate a flexible sealing gasket or tarp in good condition. 5.1.2 55-Gallon Open-Top Drums These containers are used to contain non-bulk quantities of non-liquid hazardous waste and non-hazardous waste. Wastes shall be placed into clean, 55-gallon, open-top type drums meeting DOT UN specification (e.g. steel drums 1A2/Y250 and plastic drums 1H2). The construction material for the drums shall be compatible with the characteristics of the wastes to be contained. This should be determined in consultation with the Safety-Health-Environment Department. All drums shall be in good condition with no damage or corrosion that would impair the ability of the drum to contain the wastes. The tops should incorporate a flexible sealing gasket in good condition. The sealing rings should fit the drums and be able to seal the drums tightly. Drums with side bungs should not be used. CONTAINER MANAGEMENT PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 69 5.1.3 55-Gallon Closed-Top Drums These containers are used to contain non-bulk quantities of liquid hazardous waste and non- hazardous waste. Wastes shall be placed into clean, 55-gallon closed-top type drums meeting DOT UN specification (e.g. 1A1/Y1.4/250). All drums shall be in good condition with no damage or corrosion that would impair the ability of the drum to contain the wastes. The construction material for the drums shall be compatible with the characteristics of the wastes to be contained. This should be determined in consultation with the Safety-Health-Environment Department. The tops should incorporate threaded bungs in good condition. The bungs should fit the drums and be able to seal the drums tightly. Sufficient headspace (about 3 inches) should be left in the container to provide for liquid expansion and contraction. 5.1.4 Salvage Drums (Used for Overpacks) These containers are used for managing leaking or off-specification containers. Steel drums shall meet DOT UN specification 1A2. Plastic drums shall meet DOT UN specification 1H2. The construction material for the drums shall be compatible with the characteristics of the wastes to be contained. This should be determined in consultation with the Safety-Health-Environment Department. All drums shall be in good condition with no damage or corrosion that would impair the ability of the drum to contain the wastes. The tops should incorporate a flexible sealing gasket in good condition. The sealing rings should fit the drums and be able to seal the drums tightly. Drums with side bungs should not be used. 5.1.5 Universal Waste Containers These containers are used to contain universal wastes (e.g. "Batteries", "Lamps", or "mercury containing equipment"). Universal wastes shall be contained in containers or packages that are structurally sound, adequate to prevent breakage, and compatible with the contents. This should be determined in consultati on with the Safety-Health-Environment Department. All containers shall be in good condition with no damage or corrosion that would impair the ability of the container to contain the wastes. 5.1.6 Totes and Tanks These containers are used to contain used oil and/or coolant (i.e., antifreeze). The construction material for the containers shall be compatible with the characteristics of the wastes to be contained. This should be determined in consultation with the Safety-Health-Environment Department. All containers shall be in good condition with no damage or corrosion that would impair the ability of the container to contain the wastes. Liquid waste shall be added with a funnel to prevent spillage. CONTAINER MANAGEMENT PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 70 5.2 MANAGEMENT OF CONTAINERS a. All containers of hazardous materials/wastes, non-hazardous materials/wastes, and universal wastes shall be closed during all times when wastes are not being added or removed from the containers. IBCs shall be closed per container specific DOT closure instructions. Roll-offs shall be closed by closing the door or covering the opening with a tarp. Open top drums shall be closed by placing the lid and sealing ring on the drum. The sealing ring bolt must face down and should be tightened sufficiently so that the contents of the drum will not spill if the drum were to tip over. Only non-liquid wastes shall be placed in open-top drums. All liquids shall be placed in closed-top drums with bungs. Drums shall have their bungs turned in tight except when wastes are being added or removed. Liquid waste shall be added with a funnel to prevent spillage. b. All containers holding flammable wastes such as paints, paint-related material, and solvents shall be grounded with a grounding wire attached to bare metal on the drum before opening the container top to minimize the potential for sparking when adding waste. c. Only non-sparking bung wrenches and funnels shall be used for drums holding flammable wastes. d. Containers of hazardous materials/wastes, non-hazardous materials/wastes, and universal wastes shall be handled carefully to prevent damaging the containers. Full containers shall not be stacked or stored on their sides. Any damage caused to a container of hazardous waste and/or universal waste shall immediately be reported to management and an evaluation shall be made as to whether the container should be overpacked or if the contents of the container should be transferred to a good container. Any spilled hazardous waste should be immediately contained to minimize contamination. Hazardous Waste Container Inspection Records shall be completed on a weekly basis for all containers of hazardous waste in designated 90-day hazardous waste storage areas. e. Properly completed labels identifying the container contents shall be placed on the upper 1/3 of each drum or container when the first waste is placed inside. Deteriorated non-legible labels will be replaced. f. Containers of unidentified waste that have not yet been characterized shall be marked as determined by the Safety-Health-Environment Department. g. Containers of hazardous waste shall be marked with a "Hazardous Waste" marking that complies with 40 CFR 262.15 / R315-262-15. The accumulation start date shall be filled in with the date and proper hazardous waste codes entered on the marking when the first waste is added to the container, except for satellite accumulation container situations. CONTAINER MANAGEMENT PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 71 The date is added to the container marking the day the satellite accumulation container becomes full. The manifest document number shall be completed at the time the container is shipped off site for disposal. h. Containers of hazardous waste shall be marked with “hazard communication labels” (e.g., hazard statement or pictogram consistent with the Occupational Safety and Health Administration Hazard Communication Standard at 29 CFR 1910.1200 or DOT hazard class label(s)) identifying the hazardous waste characteristics (i.e., ignitable, corrosive, reactive, toxic). i. Containers of incompatible hazard classes shall be separated by physical barriers or enough distance to separate potential spills and prevent mixing of incompatible materials. j. Any drum to be disposed or reused should first be drained of all free liquid. All empty drums should have bungs/lids on and should be stored on their sides. Drum to be used for handling other non-hazardous wastes/materials or returned to vendors for refund should be placed in designated areas. Drums that are damaged or are otherwise intended to be disposed should be placed in the designated area prior to crushing before being thrown in the trash. Drums may be managed as scrap metal. 5.3 CONTAINER INSPECTIONS a. All containers of hazardous waste in designated 90-day hazardous waste storage areas and/or designated hazardous waste satellite accumulation area shall be inspected at least weekly, looking for proper labels, leaks, and deterioration caused by corrosion or other factors. Hazardous Waste Container Inspection Records shall be completed on a weekly basis for all containers of hazardous waste. b. Containers shall be placed in designated satellite accumulation areas or the hazardous waste storage area with sufficient space separating each container so that the inspector can observe the top and all sides of each container of hazardous waste. All containers shall be oriented such that all hazardous waste labels can be readily observed without turning the containers. c. Records of the inspections shall be maintained by the Safety-Health-Environment Department. 5.4 STORAGE LIMITATIONS Large Quantity Generators will not store hazardous waste onsite for more than 90 days, while Small Quantity Generators will store hazardous waste on site for no more than 180 days (or 270 days if the facility is 200 miles or more from the TSDF). Very Small Quantity Generators and Small CONTAINER MANAGEMENT PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 72 Quantity Generators will not store greater than 6,000 kg (13,200 lbs. or about 26 full drums) of hazardous waste onsite. 5.5 IGNITABLE OR REACTIVE WASTES a. 40 CFR 262.17(a)(1)(vi)(A) / R315-262-17(a)(1)(vi)(A) requires that ignitable or reactive wastes should not be stored any closer than 50 feet from the property fence line. b. Flammable and reactive wastes will be separated and protected from ignition sources including smoking areas. “No Smoking” signs will be posted in the storage areas. 5.6 INCOMPATIBLE WASTES a. Incompatible wastes (e.g., acids and bases, or organics and corrosives), shall not be placed in the same containers. When there is any doubt as to the compatibility of a waste to be added to a container, do not add the waste until after checking with the Safety-Health-Environment Department. b. Only new, reconditioned, or clean drums or containers shall be used for storage of hazardous waste. In no case shall a drum or container that previously held an incompatible material be used for storage of hazardous waste without first being thoroughly cleaned and rinsate properly disposed. Contact the Safety-Health- Environment Department for proper decontamination procedures. c. Containers of hazardous waste that are incompatible with other hazard wastes being stored nearby shall be separated by physical barriers (i.e., containment pallets) or enough distance to separate potential leaking container spills and prevent mixing of incompatible materials. PREPAREDNESS AND PREVENTION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 73 6.0 PREPAREDNESS AND PREVENTION PLAN This Preparedness and Prevention Plan has been prepared in compliance with the requirements of the federal hazardous waste regulations found in 40 CFR Part 262 Subpart M (262.250-265) / R315-262-250-265 Preparedness and prevention for an LQG and Company management practice. Thatcher Company, Inc. (Thatcher) intends to comply with all the LQG requirements for 90-day and satellite accumulation hazardous waste storage areas. This plan applies to the 90-day and satellite accumulation hazardous waste storage areas located at the facility: 90-Day Hazardous Waste Storage Areas • The temporary 90-day hazardous waste storage area (drums and containers) located in the north west storage area (NWSA), which also provides storage for non-hazardous waste; and, • The 90-day Lab hazardous waste storage area located outside on the east side of Building 16 (maintenance shop) directly across from the west side of the lab. • Other temporary 90-day hazardous waste storage areas may be established on a case- by-case basis. Satellite Accumulation Hazardous Waste Storage Areas • The Lab storage area is located outside on the east side of the Building 16; and, 1. • Building 16 aerosol puncturing area located on the north side of the Building. The location of Hazardous Waste Generation and Satellite Accumulation Areas are sh own on Figure 1. A boundary fence restricts access to most of the site including the NWSA. The NW SA and lab storage areas also have separate fences to restrict access to the storage containers. Building 16 satellite accumulation container is maintained in the Building until full and then moved to the lab storage area. Containers are stored on containment pallets in the lab area and/or on the ground in the NWSA. Access to the 90-day hazardous waste storage areas is limited to authorized personnel. Signage with wording identifying the appropriate health and safety warnings (i.e. No Smoking) will be posted around the 90-day hazardous waste storage area locations. Drums are to be placed in these designated areas on wooden or containment pallets. Containment pallets will be used to separate incompatible materials. Empty drums will be stored on their sides in designated areas. PREPAREDNESS AND PREVENTION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 74 6.1 HAZARDOUS WASTE STORAGE AREAS MAINTENANCE AND NORMAL OPERATION PROCEDURES The hazardous waste storage areas will be maintained and operated such as to minimize the possibility of fire, explosion, or any other release of hazardous waste to the air, soil, or surface water which could threaten human health or the environment. This will be accomplished in the following ways: a. To access the 90-day drum/container hazardous waste area, Thatcher personnel will be given authorization from the Safety-Health-Environment Department and have a portable radio and/or cellular phone on their persons. b. All employees working in the hazardous waste storage areas shall be trained in the proper handling of the wastes, appropriate personal protection measures, and appropriate emergency response measures, relevant to their normal working responsibilities. c. All containers of hazardous waste shall be stored only in the designated area or drum/container handling facility, which incorporate spill control measures. d. All containers of hazardous waste shall be: 1. Properly labeled and marked with the words "HAZARDOUS WASTE", wording identifying the contents, and labels identifying the hazardous waste characteristics (e.g., ignitable, corrosive, reactive, toxic). 2. Placed on pallets and oriented so that their labels and markings are readily visible to allow inspections of the containers and their labels. 3. Placed with sufficient aisle space and with aisle space maintained between lines of drums in the drum/container handling facility such as to allow the unobstructed movement of containers, spill control materials, and fire control equipment; and 4. Each drum shall have a unique number identification to facilitate the recording of inspection information. e. All hazardous waste containers shall be of appropriate type and quality and shall be tightly closed except for when wastes are being added or removed. f. All workers shall extinguish any smoking materials or other open flames before entering the drum/container handling facility. PREPAREDNESS AND PREVENTION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 75 g. Containers of flammable hazardous waste shall be grounded with grounding wires before being opened to add or remove wastes. h. A grounding strap shall be attached to any drum containing flammable wastes before opening. i. Wastes shall be carried through the workplace to the hazardous waste storage container in closed cans, buckets, or drums that are marked as to their contents and which would prevent a spill if tipped or dropped. j. Wastes shall be handled carefully when being transferred to the roll off and/or storage drums/containers. Liquid wastes will always be added using the funnels or other appropriate method. k. Containers shall be handled carefully to prevent damage to them. Any damaged container shall be evaluated as to its ability to satisfactorily contain the wastes and the wastes shall be transferred to a new container if necessary. Alternatively, damaged drums will be overpacked into open-top salvage drums. l. Spill containment and cleanup materials shall be available at the waste storage areas and/or warehouse areas and shall be used whenever there is a spill of hazardous waste. m. Inspections of the 90-day hazardous waste storage areas shall be conducted weekly and following any emergency response. Equipment shall be tested and maintained. These inspections shall include observations and a record of the status of at least the following: 1. Condition of all containers including their closure condition, labels, and any damage or signs of corrosion or leakage. Items to be inspected will include the number of containers in storage, how long they have been in storage, and any observations of any problems or abnormal conditions with containers or other storage area characteristics, noting which drum(s) had the problem(s). 2. Condition and availability of all tools, emergency response materials, including monthly fire extinguisher inspections, and communications equipment. 3. Condition and completeness of all container labeling an d marking. Particular attention will apply to the accumulation dates and amounts of hazardous waste stored. 4. The inspector will also note if there are any hazardous waste containers that have been in storage for an extended time period (approaching the 90-day limit). PREPAREDNESS AND PREVENTION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 76 n. Hazardous Waste Container Inspection Records shall be completed on a weekly basis for all containers of hazardous waste. The written record of each inspection shall be promptly delivered to the Safety-Health-Environment Department following each weekly inspection. Inspection records shall be maintained by the Safety-Health-Environment Department for a period of at least three years. Any abnormal conditions shall be reported to the Safety-Health-Environment Department Vice President (VP) or their designee in a timely manner. Any inspections noting leakage or p otential leakage of hazardous waste, or any other conditions that may result in danger to personnel or the environment, shall be reported to the Safety-Health-Environment Department immediately. The Safety-Health-Environment Department shall also note from the inspection reports if storage times and/or amounts are nearing the allowable limits and make the proper arrangements to dispose of the waste before these limits are exceeded. 6.2 REQUIRED EQUIPMENT FOR OPERATION OF THE HAZARDOUS WASTE STORAGE AREAS The following materials and equipment are used in the hazardous waste storage areas; unless none of the hazards posed by waste handled at the storage area could require a particular kind of equipment: a. 90-Day and Satellite Accumulation Hazardous Waste Storage Areas (drums and containers). b. Portable radios or telephones in proper working order which can be used to report emergencies and allow the workers at the storage area to receive immediate emergency instruction. [262.252(a)(b), 262.254(b), and 262.261(e) / R315-262-(252(a)(b), 254(b), and 261(e)] 1. Emergency Communications - The following emergency communications method is used for a hazardous waste emergency. a) The supervisor or manager responsible for the area will notify the Emergency Coordinator. See Appendix A Emergency Coordinators – Contact List. b) In the event of an imminent or actual emergency, the Area Supervisor will notify all personnel and the Safety-Health-Environment Manager on site by: 1) Paging using the overhead phone system—three random phone keys will be pushed on the air to bring attention to the speaker. The person paging may state the chemical involved, type of release, the location, and the severity or other details of the incident. PREPAREDNESS AND PREVENTION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 77 i. The Supervisor may designate a representative to speak on the paging system, if the emergency requires his/her immediate attention. 2) For Laboratory and Office Staff Workers, press the “PAGE” button, press “00” for the entire plant, then three random phone keys on the air to bring attention to the speaker. c) After the announcement (page) has been made to evacuate the working areas of the plant, Supervisors will shut-down their operations. For areas with more involved shutdown procedures, the Supervisor will follow the emergency shut-down SOP specific to their area, if applicable. d) The evacuation location will be determined by the HazMat team leadership. Once determined, the location will be paged to all employees. e) In the event that a partial or site wide evacuation is required, the evacuation location will be determined by the HazMat team leadership. Once determined, the location will be paged to all employees. The “Page” will be accompanied by the order to evacuate as outlined in Section 2.7 Evacuation Plans. Table 6.1 - Hazardous Waste Storage Areas Phone Locations Hazardous Waste Storage Area (90- Day NWSA) Hazardous Waste Storage Area (90-Day Lab) Lab Satellite Accumulation Storage Area Maintenance Satellite Accumulation Storage Area Building 6 Building 17 Building 17 Building 16 c. Fire extinguishers, in working order and/or other fire equipment where available. These are to extinguish fires involving the types of wastes stored in the area. [40 CFR 262.252(c) and 262.261(e) / R315-(252(c), 261(e))] Table 6.2 - Hazardous Waste Storage Areas Fire Extinguisher Locations Hazardous Waste Storage Area (90- Day NWSA) Hazardous Waste Storage Area (90-Day Lab) Lab Satellite Accumulation Storage Area Maintenance Satellite Accumulation Storage Area Immediate Area Within Building-17 Within Building-17 Within Building-16 PREPAREDNESS AND PREVENTION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 78 d. If large volumes of water are required to respond to a fire, this is available through the site fire hydrants shown on Figure 1. [40 CFR 262.252(d) / R315-262-252(d)] e. A labeled spill kit with response materials for the containment, absorption and cleanup of wastes that are stored in the areas. The spill response materials also include suitable personal protective equipment sufficient for two workers to re spond to a significant spill of the type of hazardous waste stored in the facility. [40 CFR 262.252(c) / /R315-262- 252(c)] Table 6.3 - Hazardous Waste Storage Areas Spill Kit or Equipment Locations Hazardous Waste Storage Area (90- Day NWSA) Hazardous Waste Storage Area (90-Day Lab) Lab Satellite Accumulation Storage Area Maintenance Satellite Accumulation Storage Area Immediate Area Within Building-17 Within Building-17 Within Building -16 f. Mobile equipment is available throughout the facility. g. Additional PPE and chemical protective clothing are readily available at maintenance stores. h. Decontamination equipment is available on site and at maintenance stores. i. Grounding straps and connectors to allow grounding of a container of flammable waste before opening. [40 CFR 262.252(c) and 262.261(e) / R315-262-(252(c) and 261(e))] j. Sufficient lighting to allow safe working conditions at all times wastes are being handled in the waste storage area. If artificial lighting is not available, wastes will only be handled in the storage area during daylight hours. k. Appropriate tools for handling the containers of waste including non-sparking wrenches and a non-sparking funnel. [40 CFR 262.252(c) / R315-262-252(c)] l. At least one empty 55-gallon drum of the appropriate type (open head or bung) ready to receive each type of waste stored in the area, and one empty, salvage drum to be used to contain a leaking 55-gallon drum. [40 CFR 262.252(c) / R315-262-252(c)] m. All facility communications or alarm systems, fire protection equipment, spill control equipment, and decontamination equipment, where required, will be tested , and maintained as necessary to assure its proper operation in time of emergency [40 CFR 262.253 / R315-262-253]. 1. The communications equipment (handheld radios and cell phones) are tested routinely through constant use at the property. Fire extinguishers are inspected and tested regularly by the Environmental Safety and Health Department. Spill control equipment at the hazardous waste storage facilities does not require PREPAREDNESS AND PREVENTION PLAN August 2020 Thatcher Solid and Hazardous Waste Management Plan 79 testing but is maintained as necessary to be ready for use in an emergency. 2. Notify all personnel on site by Paging using the overhead phone system. 3. There are not any alarms related to hazardous waste generation or storage on- site. 6.3 ARRANGEMENTS WITH LOCAL AUTHORITIES See 9.0 Contingency Plan and Emergency Procedures Section 9.10 Coordination with Local Authorities. HAZARDOUS WASTE SATELLITE AND UNIVERSAL WASTE ACCUMULATION AREAS August 2020 Thatcher Solid and Hazardous Waste Management Plan 80 7.0 HAZARDOUS WASTE SATELLITE AND UNIVERSAL WASTE ACCUMULATION AREAS In concert with the federal hazardous waste regulations in 40 CFR Parts 262.15 / R315-262-15 and 273 / R315-273, Thatcher has established one or more "satellite accumulation and/or universal waste areas" at its facilities. These are intended to gradually accumulate hazardous wastes and/or universal wastes in containers. Hazardous waste is accumulated in satellite accumulation containers until they are full, at which time the containers are transferred to the hazardous waste storage area. Universal wastes are accumulated in containers for no longer than one year. The operation of the hazardous waste satellite accumulation and/or universal wastes accumulation areas will be as follows: a. Employees working with the hazardous and/or universal wastes will be trained in the proper handling of the wastes and appropriate emergency response measures relevant to their normal working responsibilities. b. All satellite accumulation drums will be marked with the words "HAZARDOUS WASTE", wording identifying the contents, and “hazard communication labels” (e.g., hazard statement or pictogram consistent with the Occupational Safety and Health Administration Hazard Communication Standard at 29 CFR 1910.1200 or DOT hazard class label(s)) identifying the hazardous waste characteristics (i.e., ignitable, corrosive, reactive, toxic). c. All universal waste accumulation containers will be marked with the words "Universal Waste" and the date the waste is first put in the containers. In addition, the container shall be marked to identify the contents (e.g., "Batteries"). d. All accumulation containers will be located at or near the point of generation of the wastes and will be under the control of the operator. e. The accumulation containers will be located to be readily inspected on all sides and to allow room for spill control and fire response (See section 5.3 for container inspection procedures). f. All accumulation containers will be oriented so that their labels and markings are readily visible for inspection. g. All accumulation containers will be closed except when wastes are being added or removed. h. Grounding straps will be connected to any accumulation drum containing flammable wastes before opening. i. Wastes will be handled carefully when being transferred to the accumulation drums or containers. Liquid wastes should always be added using funnels. Any spillage will be immediately cleaned up. HAZARDOUS WASTE SATELLITE AND UNIVERSAL WASTE ACCUMULATION AREAS August 2020 Thatcher Solid and Hazardous Waste Management Plan 81 j. When a 55-gallon or less hazardous waste satellite accumulation container is full, it should be labeled with the appropriate EPA and/or DOT markings and labels. The accumulation date on the EPA hazardous waste label (required on satellite accumulation drums) should be filled in with the date that the drum became full. k. Full satellite accumulation drums will be transferred to a hazardous waste storage area within three days of becoming full. l. Universal wastes are accumulated on-site for no longer than one year at which time the containers are shipped to the universal waste management facility. m. All outdoor accumulation drums may be placed on individual spill containment pallets to control any spills or leakage. PRE-TRANSPORT REQUIREMENTS AND RECORD KEEPING August 2020 Thatcher Solid and Hazardous Waste Management Plan 82 8.0 PRE-TRANSPORT REQUIREMENTS AND RECORD KEEPING In compliance with 40 CFR 262 Subparts B, C, and D / R315-262-(20-27, 30-35, and 40-44), and Company guidelines, the following requirements will be followed in preparing hazardous waste for shipment off site and for the proper maintenance of records regarding these shipments. a. Hazardous wastes will only be disposed in properly permitted, off site treatment, storage, and disposal facilities (TSDF) that have been audited and approved by the Thatcher. b. Chemical waste profiles, and profile samples as required for initial approval, will be provided to the TSDF in advance of shipping the hazardous waste. The waste will not be shipped until the TSDF replies with an approval. c. Wastes will be packaged, labeled, and marked in compliance with applicable DOT regulations and the requirements of the TSDF prior to shipping. d. A Uniform Hazardous Waste Manifests (UHWM) prepared by hazardous waste disposal vendors will be reviewed by the Safety-Health-Environment Department prior to the shipping date. e. The UHWM will be signed by the DOT 49 CFR trained Safety-Health-Environment Department personnel and the transporter when the waste is shipped. The generator copy of the UHWM will then be retained by the Safety-Health-Environment Department and the rest of the copies will be given to the transporter. f. The waste containers will be inspected to check for proper, non-leaking condition of the containers, that all covers, bungs, and/or gaskets are tight and sealed, and that all required markings and labels are present. g. Prior to the shipment date, the appropriate, DOT-approved placards for the waste shipment will be obtained to be offered to the transporter if the transporter does not provide them. h. Care will be taken to store hazardous waste on site for no more than 90-days for a LQG. i. Copies of each manifest will be retained in facility records for at least 3 years. j. Copies of all waste analyses or other determinations will be retained in facility records for at least 3 years. k. If a signed copy of a manifest is not received by an LQG, from a TSDF within 35 days of shipping the waste, determine the status by contacting the transporter or TSDF. If a signed copy of the manifest is not received from a TSDF within 45 days of shipping the waste, a copy of the manifest with an explanation letter that the mine has not received confirmation of delivery shall be sent to UDEQ. PRE-TRANSPORT REQUIREMENTS AND RECORD KEEPING August 2020 Thatcher Solid and Hazardous Waste Management Plan 83 l. Biennial Reports shall be prepared and submitted by March 1 of each even numbered year in compliance with instructions provided for the report form and UDEQ. Copies of the Biennial Report shall be retained in mine records for at least 3 years. m. Determine if the hazardous wastes are restricted from land disposal (40 CFR Part 268 / R315-268). For each shipment of restricted hazardous wastes that do not meet treatment standards, a written notification shall be made to the treatment and/or disposal facility. For each shipment of restricted hazardous wastes that can be land disposed without further treatment, a written notification and certification that the waste meets treatment standards shall be made to the treatment and/or disposal facility (see 40 CFR Part 268.7 / R315-268-7 for notification/certification content requirements). n. Determine the underlying hazardous constituents (as defined in 40 CFR Part 268.2 / R315- 268-2) for all wastes exhibiting the characteristic of ignitability (D001) (other than high TOC ignitable liquids), corrosivity (D002), reactivity (D003), and/or TCLP toxicity (D004- D043). The disposal facility shall be notified of all underlying hazardous constituents for these wastes. o. Copies of all notices, certifications, demonstrations, waste analyses, and other documents pursuant to the land disposal restrictions (40 CFR Part 268/ R315-268) shall be retained for at least 3 years. 8.1 EPISODIC GENERATION REQUIREMENTS AND RECORD KEEPING In compliance with 40 CFR 262 Subpart L/ R315-262-(30-33), the following requirements will be followed for VSQG and SQG hazardous waste episodic generation. a. Episodic generation applies to planned or unplanned activities that do not normally occur during generation operations (i.e., maintenance or spills). b. Episodic generation is limited to one episodic event per year unless a petition is granted for additional events. EPA-approved episodic events do not count toward the facility’s generator status. c. A notification form (EPA using the RCRA Subtitle C Site Identification Form (8700-12)) must be submitted to UDEQ/DSHW: 1) 30-days prior to a planned event; and 2) within 72-hours by phone, via fax, or email for unplanned events. Notification must include: the start date and end date of the episodic event and the reason(s) for the event, types and estimated quantities of hazardous wastes expected to be generated as a result of the episodic event, and identify a facility contact and emergency coordinator with 24-hour telephone access to discuss the notification submittal or respond to emergency. d. Generated hazardous waste must be transported off-site within 60-days of generation. e. A VSQG must obtain an EPA identification number if it doesn’t have one. PRE-TRANSPORT REQUIREMENTS AND RECORD KEEPING August 2020 Thatcher Solid and Hazardous Waste Management Plan 84 f. Hazardous waste containers must be marked “Episodic Hazardous Waste” and the date the waste was placed in the container, in addition to the standard hazardous waste container marking requirements. g. Records must be kept for 3 years and record keeping must include: 1) beginning and end dates of the episodic event; 2) description of the episodic event, types, and quantities of hazardous waste generated; 3) transporter name(s), description of management and name of the hazardous waste disposal facility; and 4) approval letter for petitioned additional episodic event. Contingency plan and Emergency Procedures August 2020 Thatcher Solid and Hazardous Waste Management Plan 85 9.0 CONTINGENCY PLAN AND EMERGENCY PROCEDURES In compliance with 40 CFR Part 262 Subpart M (262.260-265) / R315-262-(260-265) Contingency Plan and Emergency Procedures and company policy, Thatcher Company, Inc. (Thatcher) has developed the following Contingency Plan and Emergency Proc edures for any accidents involving hazardous waste at its facilities. This portion of the plan is designed to minimize hazards to human health or the environment from fires, explosions or any unplanned sudden or non- sudden release of hazardous waste or hazardous waste constituents to air, soil or surface water. The Thatcher facilities have this Contingency Plan (hazardous waste) and an Emergency Response Program (hazardous materials Emergency Action Plan and Emergency Response Plan) in place. Thatcher employees respond to incidents according to the plan applicable to the materials released (i.e., hazardous waste and/or hazardous material) and training received. 9.1 EMERGENCY COORDINATORS a. An Emergency Coordinator chain-of-responsibility has been created at the facility to coordinate all emergency response measures related to hazardous waste. The persons listed are qualified to act as Emergency Coordinators with the knowledge, responsibility, and authority for coordinating emergency response measures to be tak en in the event of an emergency involving hazardous wastes. This employee must be either present at the facilities or on call (and able to report to the facility within a short per iod of time) with the responsibility for coordinating all emergency response measures. The Emergency Coordinator and/or Alternate will be thoroughly familiar with the contents of this contingency plan. This person must have the authority to commit the re sources needed to carry out the contingency plan. The Emergency Coordinator and/or Alternates are listed in Appendix A - Emergency Coordinators Contact List.. *The supervisor or manager responsible for the area will notify the Emergency Coordinator. b. For emergencies involving hazardous waste, if the key individuals named above ar e not immediately available or are in route to the facility, the following procedure will be used. 1. The first member of the Thatcher HazMat Emergency Response Team (HERT) to arrive at the scene of an incident involving hazardous waste will communicate with security and will help restrict access to the area of the incident until a more senior member of the HERT or one of the persons named above arrives at the scene of the incident. c. The Emergency Coordinator and the alternate Emergency Coordinators are qualified to act in this capacity due to their thorough familiarity with the following: Contingency plan and Emergency Procedures August 2020 Thatcher Solid and Hazardous Waste Management Plan 86 1. Types of hazardous waste operations and activities at the facility; 2. Locations and characteristics of all hazardous wastes handled; 3. Locations of all records regarding hazardous wastes within the facility; 4. Layout of the facility, including all emergency equipment, manpower, and levels of response training; 5. Appropriate evacuation procedures; 6. Safe and appropriate emergency response procedures; 7. Proper handling of hazardous wastes produced in response actions; and, 8. Selection and implementation of the proper decontamination procedures and solutions used in response to hazardous conditions. 9.2 EMERGENCY COORDINATOR ACTIONS a. If there is an imminent or actual emergency involving hazardous waste at the facility, the Emergency Coordinator (or alternate) will: 1. Respond immediately when called out. 2. Activate emergency communications to notify all personnel in affected areas if not already completed. a) Paging using the overhead phone system—three random phone keys will be pushed on the air to bring attention to the speaker. The person paging may state the chemical involved, type of release, the location, and the severity or other details of the incident. b) The Supervisor may designate a representative to speak on the paging system if the emergency requires his/her immediate attention. c) For Laboratory and Office Staff Workers, press the “PAGE” button, press “00” for the entire plant, then three random phone keys on the air to bring attention to the speaker. d) There are not any alarms related to hazardous waste generation or storage on-site. 3. The Emergency Coordinator must decide if a situation is controllable by plant personnel, onsite emergency response team, or if outside response is required and will determine the need to implement provisions of the plan. Contingency plan and Emergency Procedures August 2020 Thatcher Solid and Hazardous Waste Management Plan 87 4. Confirm that facility staff has begun the appropriate emergency response actions, if not, assist in coordinating the appropriate response. 5. Establish security at the immediate location of the incident to prevent the entry of unauthorized persons into the affected area. 6. Determine the character, source, amount, and extent of any released hazardous waste or hazardous waste constituents by: a) Observing from a safe distance the physical character of the released waste or hazardous material (vapor, liquid, solid), b) Weather patterns and wind direction at the time of the release. c) Determining the source of the release through inspection or from firsthand reports of observers, d) Estimate the amount of material released by noting the size of the container or tank and the location of the release point on the container or tank, and e) Noting the lateral extent of the obvious contamination by actual presence of the material or from indirect evidence (smoke, stains, wet ted surfaces etc.). 7. Assess the possible hazards to human health and the environment that may result from the release, fire or explosion including identification of: a) Toxic or irritating vapors, smoke or fumes, b) Toxic and/or corrosive liquids or solids, c) Oxidizing materials, d) Potential fuels, e) Incompatible materials or chemicals, and f) Soil and/or water contamination. These hazard assessments will be conducted through identifying the materials released by their locations within the facility or reading markings, labels, and/or truck placards and then determining their hazardous characteristics by reviewing DOT Emergency Response Guide (ERG) and/or SDS information, using health and safety monitoring equipment, and/or using generator knowledge. SDSs are available on Thatcher’s Thatchernet system and provide information for the main hazardous chemicals and hazardous constituents of the waste streams produced at the facility. Characterization analyses, waste profiles, and manifests for hazardous waste streams produced at the available from the Safety-Health- Environment Department. 8. Determine the need for the evacuation of persons not required for immediate response actions and initiate any appropriate evacuation procedures. Evacuation directions should consider possible effects of downwind transport of airborne contaminants and downhill transport of liquids on persons exposed during the evacuation. Should evacuation be necessary employees should Contingency plan and Emergency Procedures August 2020 Thatcher Solid and Hazardous Waste Management Plan 88 gather at designated assembly points unless instructed otherwise, and supervisors will conduct an accounting of their respective personnel. 9. Notify appropriate state or local agencies with designated response roles if needed. The Emergency Coordinator will designate a point-of contact to help communicate with local, county, and state authorities if needed. 10. If the Emergency Coordinator determines that the incident could affect human health or the environment outside the facility the emergency coordinator must report findings. See section 2.8 Emergency Reporting Procedures, Number 1- Reportable Incident Determination. 11. Determine if shutdown of certain processes or operations is necessary to reduce hazards of release. a) If the facility stops operations in response to a fire, explosion or release, the emergency coordinator must monitor for leaks, pressure buildup, gas generation, or ruptures in valves, pipes, or other equipment wherever appropriate; and, 12. Direct all reasonable measures necessary to ensure that fires, explosions, and releases of hazardous waste do not occur, recur, or spread. These measures may include: a) Stopping, controlling, or containing the source of the release, b) Containing the released materials to minimize spreading, c) Eliminating or controlling health and safety hazards, d) Collecting and containerizing released material, and e) Cleaning up and/or treating residual contamination in-place. 13. Provide for the proper handling of any hazardous wastes produced during the incident itself and during any response actions taken. 14. Prevent placing any incompatible wastes or hazardous materials in contact with the released waste. 15. Initiate internal reporting and notifications to outside agencies as required. 16. Ensure that emergency response equipment and materials are returned to readiness and are in proper working condition after the response action and that decontamination of the equipment has been completed, if necessary. 17. Record the time, date, of samples obtained and by whom, in addition to details of any incident that requires implementing the Contingency Plan and any internal and external notifications given. Contingency plan and Emergency Procedures August 2020 Thatcher Solid and Hazardous Waste Management Plan 89 18. Thatcher must notify Utah Department of Environmental Quality (UDEQ) that Thatcher facilities are in compliance with the following if the Contingen cy Plan has been implemented: a) The Emergency Coordinator ensured that incompatible waste recovered from released material was not treated, stored, or disposed of improperly. b) Cleanup was complete; and, c) Response equipment was returned to service for use before operations were resumed in affected areas. 19. The contingency plan must be reviewed, and immediately amended, if necessary, whenever: a) Applicable regulations are revised. b) The plan fails in an emergency. c) The facility changes in its design, construction, op eration, maintenance, or other circumstances – in a way that materially increases the potential for incidents. d) The list of emergency coordinators changes; and, e) The list of emergency equipment changes. b. Following any hazardous waste emergency response action, the Emergency Coordinator will conduct such investigations or evaluations as may be necessary to determine the causes of the incident and how to prevent future incidents; assess the effectiveness of the response actions and how they may be improved; and, determine if any changes to the facility's emergency response procedures can be made to improve the quality of the facility's emergency preparedness. 9.3 EMERGENCY RESPONSE EQUIPMENT AND MATERIALS Emergency response equipment is available in the immediate work area to the employees who have been trained in the response actions required for a release of hazardous waste and/or hazardous material. The HazMat Emergency Response Team will be mobilized for response as required. a. The equipment and material to be used to respond to an incident involving hazardous waste is in work areas, designated hazardous waste storage areas, and/or warehouse. This equipment and material include the following: 1. Dry chemical fire extinguishers - to extinguish chemical fires 2. Splash goggles - to protect eyes from liquids and solids 3. Butyl or neoprene gloves - to protect hands from solids and liquids 4. Neoprene boots - to protect feet from solids and liquids 5. SCBA - to protect against inhalation of extremely hazardous substances 6. Shovel - to build containment features and clean up solid material Contingency plan and Emergency Procedures August 2020 Thatcher Solid and Hazardous Waste Management Plan 90 7. Broom - to clean up solid material 8. Duct tape - to seal PPE, tailor or repair PPE, hold plastic sheeting, provide temporary repairs of containers or equipment b. Other items available for incident response, but located in the warehouse and or near the hazardous waste storage areas include: 1. Overpack drum - used to overpack another drum or contain spill cleanup wastes 2. Tyvek and Saranex suits - for protection against hazardous solids (Tyvek) or liquids (Saranex) 3. Paper towels - to help clean up liquids and assist with decontamination 4. Plastic garbage bags - to contain spent spill cleanup materials 5. Noncombustible absorbent material - to clean up spills of liquids 6. Face shields - to provide full-face splash protection 7. Plastic sheeting - to control evaporation of volatile chemicals, cover contaminated surfaces, build decontamination areas, and protect clean surfaces from contamination c. Other spill response equipment and materials are available in other locations at the facility to respond to spills of petroleum and chemicals. Emergency Spill Kits are provided at locations throughout the facility for use by all emp loyees and contractors. 9.4 EMERGENCY SPILL RESPONSE ACTIONS 9.4.1 Emergency Spill Response Actions a. In the event of a spill of hazardous waste or hazardous material, the hazardous spill response and clean-up measures described in Thatcher’s Emergency Response Program will be followed. b. As a general rule, Thatcher employees only respond to very minor incidents if trained and safe to do so, such as small incidental releases where the substance can be controlled at the time of the release by employees in the immediate release area. 1. For small spills involving a container, the employees may be instructed to either transfer the material to an approved container or overpack the container. 2. The HazMat Emergency Response Team will respond to incidents involving spills of hazardous waste, fires, explosions, or any other incidents involving hazardous waste. Contingency plan and Emergency Procedures August 2020 Thatcher Solid and Hazardous Waste Management Plan 91 3. The first member of the HazMat Emergency Response Team to arrive at the scene of an incident, involving hazardous waste will communicate with security and will help restrict access to the area of the incident until a more senior member of the HazMat Emergency Response Team or one of the emergency coordinators arrives at the scene of the incident. 9.4.2 Internal Emergency Reporting a. The Thatcher employee that first notices the spill or discharge shall notify the supervisor or manager. b. The Thatcher employee, supervisor, and/or manager shall: 1. Page using the overhead phone system—three random phone keys will be pushed on the air to bring attention to the speaker. The person paging may state the chemical involved, type of release, the location, and the severity or other details of the incident. a) The Supervisor may designate a representative to speak on the paging system if the emergency requires his/her immediate attention. 2. For Laboratory and Office Staff Workers, press the “PAGE” button, press “00” for the entire plant, then three random phone keys on the air to bring attention to the speaker. c. The following information must be provided to the Emergency Coordinator: 1. Name and location of the employee notifying the Emergency Coordinator, 2. The nature of the incident, 3. Any actions being taken by persons already on the scene of the incident, and 4. Any recommendations for further actions. 9.5 EMERGENCY FIRE RESPONSE ACTIONS a. Personnel encountering a fire in their immediate workplace should: 1. Walk, do not run, to the nearest exit away from the fire. 2. Stay low and crawl in areas filled with smoke; and 3. Use handrails on stairways. Contingency plan and Emergency Procedures August 2020 Thatcher Solid and Hazardous Waste Management Plan 92 b. In the event of a fire involving hazardous waste, the following response actions shall be followed by the person discovering the fire: 1. Call for the response of all emergency personnel needed, and request radio silence when necessary. 2. Notify other workers in the area and sound the fire alarm. 3. Notify the supervisor or manager by radio or phone and describe the location of the fire and state your name. 4. Direct others away from the fire, and report to the posted evacuation assembly point when necessary. 5. Confine the fire - close all doors and windows. 6. If the fire is small, and the person has had fire response training, an appropriate fire extinguisher should be used only if the fire can be extinguished safely, and there is an open exit available to escape if necessary. 7. If the fire is too large, evacuate the area and allow the Emergency Response Team to respond. c. Persons who find themselves in an area involved in a fire should aid emergency response crews by: 1. Providing unobstructed access to and from the scene for emergency personnel and equipment. 2. Providing any additional support requested by emergency personnel. 3. Shut-down equipment near the emergency site. 4. Account for personnel. 5. Remain calm and keep talking and noise to a minimum. 6. Listen for evacuation instructions. 7. Report to a safe area away from the fire and remain there for instructions; and 8. Do not return to the fire area until directed by personnel in charge. d. The HazMat Emergency Response Team Incident Commander will coordinate the on-site and/or off-site response to the fire according to Thatcher procedures. e. The Supervisor will notify the Emergency Coordinator to assist with the fire response, should hazardous substances be involved. f. The Emergency Coordinator will determine if the fire involved hazardous waste or hazardous materials that could release hazardous waste constituents. If so, the procedures in this Contingency Plan will be followed. Contingency plan and Emergency Procedures August 2020 Thatcher Solid and Hazardous Waste Management Plan 93 9.6 EMERGENCY EXPLOSION RESPONSE ACTIONS a. The fire response actions of Section 9.5 of this document should be followed in the event of an explosion. b. If an explosion has not occurred, but an emergency incident has the potential to develop into an explosion, the person in charge of responding to the incident shall: 1. Evacuate all employees to a safe location; and 2. Re-evaluate the necessary response actions considering the potential risk to the health and safety of personnel and to facilities. 9.7 EVACUATION PLANS Evacuation plans (EHS 13F11) have been developed for each building at the facility. When instructed, personnel should walk, not run, to the nearest safe exit in their work area and assemble at the posted designated evacuation assembly point as indicated in the evacuation plans, unless otherwise instructed. Emergency evacuation escape route plans are posted in key areas throughout the buildings (usually near exit doors). All employees have been trained concerning these plans and should also be familiar with the evacuation plans for the other buildings within the company. Only HazMat team members are permitted to respond to emergencies of any nature, all other employees evacuate to their designated evacuation locations as specified in the SOP. 9.8 EMERGENCY REPORTING PROCEDURES To ensure that emergencies involving hazardous waste are properly handled and reported, the following emergency reporting procedures shall be followed. a. Persons who discover a release or potential release of hazardous waste should immediately notify their immediate Supervisor or Manager. The immediate Supervisor or Manager will immediately notify the Emergency Coordinator on-site or on call and provide the following information: 1. Name and phone number of individual reporting. 2. Time and date of spill. 3. Location of spill - as specific as possible. 4. Description of the material and the amount of material spilled (if known). 5. Cause of spill. 6. Emergency action taken to minimize the threat to human health and the environment Contingency plan and Emergency Procedures August 2020 Thatcher Solid and Hazardous Waste Management Plan 94 7. Note if the released material is confined within property boundaries a nd/or if it has reached a waterway, drainage, or pond. 8. Note the number of human and/or animal injuries/fatalities. b. The Emergency Coordinator will determine if there has been a reportable incident, spill, or discharge and complete applicable reporting. 1. In general, a reportable spill includes: a) Hazardous chemicals equal to or in excess of the Federal “Reportable Quantity” (RQ) under CERCLA and/or the Extremel y Hazardous Substances (EHS) RQ under EPCRA. 1) CERCLA RQs are determined from 40 CFR 302.4 Appendix B CERCLA RQ list. 2) EPCRA RQs are determined from 40 CFR Part 355 Appendix A. b) One kilogram (2.2 lbs.) of acutely toxic hazardous waste (“P”-listed or “F”- listed with hazard code “H”) or 100 kilograms (220 lbs.) of hazardous waste or any non-permitted release that could threaten human health or the environment must be reported to UDEQ. Only Thatcher’s Plant Manager, Technical Director, Safety Manager or Emergency Coordinator will assign a person to verbally notify the appropriate agencies, if any of the above reporting requirements are met. If any of the above reporting requirements are met, go to Number 2 below and follow the reporting requirements. 2. Reportable incident verbal notification: a) Immediate notification requirements for reportable release that equal s or exceeds the CERCLA RQ and/or EPCRA EHS RQ: 1) Facilities must immediately notify the National Response Center (NRC), UDEQ, Salt Lake City Fire Department, which acts as the Local Emergency Planning Committee (LEPC), and Utah Department of Public Safety below. b) One kilogram (2.2 lbs.) of acutely toxic hazardous waste (“P”-listed or “F”- listed with hazard code “H”) or 100 kilograms (220 lbs.) of hazardous waste or any non-permitted release that could threaten human health or the environment must be reported to UDEQ: Contingency plan and Emergency Procedures August 2020 Thatcher Solid and Hazardous Waste Management Plan 95 1) Facilities must as soon as possible, but not later than the end of the first working day after the release, notify the UDEQ and provide immediate notification to the Salt Lake City Fire Department (LEPC) below. 3. Dial “8” to get an outside telephone line from onsite. a) National Response Center 1-800-424-8802 b) Utah Department of Environmental Quality 1-801-536-4123 The State Emergency Response Commission (SERC) and other UDEQ agencies are notified by UDEQ. c) Salt Lake City Fire Department (LEPC) Emergency 911 d) Salt Lake City Fire Department (LEPC) Non-Emergency 1-801-596-5254 e) Utah Department of Public Safety 1-801-538-3702 4. The Emergency Coordinator shall provide the following information when reporting a spill/release: a) Company’s Name, phone number, address of the facility and hazardous waste generator Identification Number: UTD041307356. b) Name, title, and phone number of individual reporting. c) Time, date, and type of incident (e.g., release, fire). d) Name and quantity of materials involved. e) Location of spill - as specific as possible including township and range, section, and county in addition to the specific location on the site. f) Description of the material and the amount of material spilled. g) Cause of spill. h) Emergency action taken to minimize the threat to human health and the environment. i) Description of any injuries or fatalities. j) Evacuations necessary. k) Environmental media the material was released to, if any; and l) Clean up procedures taken. 5. Within 15 days of the spill, a written report will be prepared and submitted by the emergency coordinator to the Division of Solid and Hazardous Waste, Utah State Department of Environmental Quality that includes the above information. In addition, the report must provide information on: a) The extent of injuries, if any. b) An assessment of actual or potential hazards to human health or the environment, where this is applicable; and Contingency plan and Emergency Procedures August 2020 Thatcher Solid and Hazardous Waste Management Plan 96 c) The estimated quantity and disposition of recovered material that resulted from the incident. 6. The Emergency Coordinator shall determine if the incident requires the assistance of an experienced hazardous waste spill response contractor. 9.9 MANAGEMENT OF WASTES PRODUCED DURING AN INCIDENT RESPONSE The wastes produced in a cleanup or response to an emergency incident involving hazardous wastes or hazardous materials may themselves be hazardous wastes. For example, floor dry used to absorb a spill of a listed solvent would be a hazardous waste mixture having the same hazardous waste code as the spilled material. Waste is characterized, classified, and managed at permitted or approved facilities. 9.10 COORDINATION WITH LOCAL AUTHORITIES In compliance with federal hazardous waste regulations at 40 CFR 262.256 and 265.52(c), a copy of the Hazardous Waste Contingency Plan and Hazardous Waste Preparedness and Prevention Plan and an invitation to visit the facility has been sent to the local entities and authorities listed in the section below that may be involved in an emergency situation. Thatcher will coordinate with the following agencies to familiarize agency personnel with the types of hazardous waste handled in the waste storage areas and the potential need for their services. Thatcher has coordinated with the following local emergency response agencies to familiarize them with the potential need for their services in the future to respond to a hazardous waste incident: • Salt Lake City Fire Department (LEPC) • Salt Lake City Police Department The following medical facilities will be notified of the hazards associated with various emergency situations at the facilities and will be provided a copy of the Contingency Plan and Hazardous Waste Preparedness and Prevention Plan. • Intermountain Medical Center, 5121 Cottonwood St, Murray, UT, 1-801-507-6600 Personnel from the hospital and local ambulance services will be advised of materials handled at the facility, the likely hazards involved. Safety Data Sheets and other technical references pertaining to hazardous materials are available from facility for use by hospital personnel. Contingency plan and Emergency Procedures August 2020 Thatcher Solid and Hazardous Waste Management Plan 97 The facility has contacted local police, fire, emergency response teams and hospitals and provided them with copies of or portions of the Thatcher facilities Contingency Plan and Hazardous Waste Preparedness and Prevention Plan and relevant background information in an effort to familiarize them with the layout of the facilities, the properties of the hazardous wastes handled at the facility, the associated hazards, entrances to and roads within the facility, evacuation assembly areas. These local authorities are invited to visit the facility if they should so desire. The arrangements with local authorities discussed above include provisions for designating one authority as the primary emergency authority. If an emergency arises at Thatcher, which cannot be controlled by plant personnel, the HazMat Emergency Response Coordinator (HERC) will notify the appropriate authorities. If a spill of hazardous material or hazardous waste cannot be contained, controlled, and cleaned up by facility personnel or local authorities, the HazMat Emergency Response Coordinator will call in a professional cleanup contractor. Copies of letters sent to the Emergency Response agencies requesting their coordination in response assistance to emergency situations are in the environmental files. 9.10.1 Emergency Response Agency Waiver Thatcher has not applied for the waiver described below. A facility possessing 24-hour response capabilities may seek a waiver from the authority having jurisdiction (AHJ) over the fire code within the facility's state or locality as far as needing to make arrangements with the local fire department as well as any other organization necessary to respond to an emergency, provided that the waiver is documented in the operating record. 9.11 AMENDMENT OF CONTINGENCY PLAN The Contingency Plan will be reviewed and amended according to the following. a. Regulations are revised. b. The plan fails in an emergency. c. The emergency equipment list changes. d. The emergency coordinator list changes. e. The facility changes in a way that materially increases the potential for fires, explosions, or releases of hazardous waste or hazardous waste constituents, or changes the response necessary in an emergency as follows: Contingency plan and Emergency Procedures August 2020 Thatcher Solid and Hazardous Waste Management Plan 98 1. Design or construction. 2. Operation, maintenance, or other circumstances. 9.12 CONTINGENCY PLAN QUICK REFERENCE GUIDE This Contingency Plan Quick Reference Guide was developed per 40 CFR Part 262.262(b). 9.12.1 Emergency Coordinator Contact List Emergency coordinator and alternates 7/24-hour emergency telephone number(s) are in Appendix A. 9.12.2 Emergency Communications Activate emergency communications to notify all personnel in effected areas if not already completed. a. Paging using the overhead phone system—three random phone keys will be pushed on the air to bring attention to the speaker. The person paging may state the chemical involved, type of release, the location, and the severity or other details of the incident. b. The Supervisor may designate a representative to speak on the paging system, if the emergency requires his/her immediate attention. c. For Laboratory and Office Staff Workers, press the “PAGE” button, press “00” for the entire plant, then three random phone keys on the air to bring attention to the speaker. d. There are not any alarms related to hazardous waste generation or storage on-site. 9.12.3 Hazardous Waste Information The following hazardous waste information tables include locations, general types/name s, and estimated maximum amount present at any one time. Table 9.1 - Building 16 Hazardous Waste Information Hazardous Waste Descriptions Hazard Estimated Maximum Amount Location Generated Location Accumulated Aerosol Aspirator -Ignitable -TCLP RCRA 8 metals -TCLP volatiles or semi-volatiles 55-gallons Building 16 Laboratory 90- Day Storage Contingency plan and Emergency Procedures August 2020 Thatcher Solid and Hazardous Waste Management Plan 99 Table 9.2 - Laboratory Hazardous Waste Information Hazardous Waste Descriptions Hazard Estimated Maximum Amount Location Generated Location Accumulated Mixed Organic Waste -Ignitable -TCLP RCRA 8 metals -TCLP volatiles or semi-volatiles 55-gallons Laboratory- Building 17 Laboratory Satellite Accumulation Area Full containers are stored in the Laboratory 90- Day Storage Area Methanol/Acetonitrile -Ignitable 55-gallons Laboratory- Building 17 Silver Nitrate -Corrosive Alkaline -Silver 55-gallons Laboratory- Building 17 Chloroform -Toxic 55-gallons Laboratory- Building 17 Dilute Heavy Metal Solutions -TCLP RCRA 8 metals 55-gallons Laboratory- Building 17 Hydrazine Waste 55-gallons Laboratory- Building 17 Expired Analytical Reagents -Ignitable -Corrosive Acid or Alkaline -TCLP RCRA 8 metals -TCLP volatiles or semi-volatiles 55-gallons Laboratory- Building 17 Research and Development Accumulation -Ignitable -Corrosive Acid or Alkaline -TCLP RCRA 8 metals -TCLP volatiles or semi-volatiles 55-gallons Laboratory- Building 17 Contingency plan and Emergency Procedures August 2020 Thatcher Solid and Hazardous Waste Management Plan 100 Table 9.3 - Process North West Storage Area Hazardous Waste Information Hazardous Waste Descriptions Hazard Estimated Maximum Amount Location Generated Location Accumulated Process Waste Category 1 pH <2 or >12.5 (inorganic or organic. -Ignitable -Corrosive Acid or Alkaline -TCLP RCRA 8 metals -TCLP volatiles or semi- volatiles 200 containers (55 to 275 gallons each) Process North West Storage Area Process Waste Category 2: pH: >2 or <12.5 (Inorganic) -TCLP RCRA 8 metals 400 containers (55 to 275 gallons each) Process Waste Category 3: pH: >2 or <12.5 (Organic) -Ignitable -TCLP RCRA 8 metals -TCLP volatiles or semi- volatiles 400 containers (55 to 275 gallons each) Process Waste Category 4: Oxidizer, Peroxide, Fluoride, Iodine, Bromine, Chlorine, Ammonia (Inorganic or Organic) -Ignitable -Corrosive Acid or Alkaline -TCLP RCRA 8 metals -TCLP volatiles or semi- volatiles 40 containers (55 to 275 gallons each) Process Waste Category 5: Oil < or >1000 ppm Halogenated Hydrocarbons. -Ignitable -TCLP RCRA 8 metals -TCLP volatiles or semi- volatiles 10 containers (55 to 275 gallons each) 9.12.4 Hazardous Waste Exposure Exposure to these hazardous wastes does not require unique or special treatment by medical staff. 9.12.5 Facility and Street Maps A facility map and a street map are included with the following information in Appendix B. Contingency plan and Emergency Procedures August 2020 Thatcher Solid and Hazardous Waste Management Plan 101 a. Facility map access routes to: 1. Hazardous waste generation and accumulation locations; and, 2. Fire water supply locations (i.e., fire hydrant and flow rate). b. Street map in relation to the following to understa nd the best route to the facility and evacuate citizens and workers: 1. Surrounding businesses. 2. Schools; and, 3. Residential areas 9.12.6 Hazardous Waste Quick Reference Guide Updates The Hazardous Waste Quick Reference Guide must be updated whenever the contingency plan is amended. Amended documents must be submitted to the local emergency responders identified in Section 9.10 Coordination with Local Authorities PERSONNEL TRAINING August 2020 Thatcher Solid and Hazardous Waste Management Plan 102 10.0 PERSONNEL TRAINING 10.1 INTRODUCTION This section on training management details how the facility manages hazardous materials/wastes, non-hazardous materials/wastes, and universal wastes training requirements and training courses at the facility. It has been prepared in compliance with the requirements of the federal hazardous waste regulation found in 40 CFR 262.17(a)(7) / R315-262-17(a)(7) LQG Personnel Training and 273.16 / R315-273-16 universal waste small quantity handlers training. The facility has instituted a personnel training program for those individuals whose job descriptions require they handle or manage hazardous or universal waste(s), or who work at the 90-day hazardous waste storage areas. This training is offered to new hires within six months of their initial employment at the facility, and annually thereafter to all applicable personnel. The training summarizes the RCRA and DOT regulations, focusing in detail on areas directly related to hazardous waste management and spill response measures at the facility. A representative of the Safety-Health-Environment Department trained in hazardous waste management procedures directs the training. The type and quantity of training given to each employee is relevant to the employee’s hazardous waste management tasks commonly part of his/her employment position. Training may be provided in separate areas as required (i.e., laboratory waste management). 10.2 HAZARDOUS WASTE MANAGEMENT JOB DESCRIPTIONS a. Employees’ names, general job titles, and hazardous waste management job titles/descriptions are found in Appendix C. Supervisors, crew shifter, and/or other names not listed in Appendix C are part of the facility operating records. b. The following job descriptions are for the Facility’s employees who share in the responsibility of managing the hazardous waste or are likely to handle hazardous waste in an emergency situation at the facility site. The training requirements for these individuals are also listed. A detailed list consisting of each employee name, job title, and hazardous waste or hazardous materials job description/training is included in Appendix C Hazardous Waste Management Personnel Job Titles. Training records are kept in the Safety-Health-Environment Department Files. c. As required in 40 CFR 262.17/ R315-262-17, 273.16/ R315-273-16 and/or 49 CFR 172.704, initial training will include a class overview of RCRA and/or DOT requirements and this manual. Yearly refresher training will include any changes or updates to this manual, improvements to the RCRA management system, and a review of RCRA and/or DOT requirements. Safety-Health-Environment Department personnel will predominantly teach the initial training and yearly refresher courses. PERSONNEL TRAINING August 2020 Thatcher Solid and Hazardous Waste Management Plan 103 d. Operators will also receive training regarding response as described in the Spill Prevention, Control, and Countermeasures Plan, Emergency Response Plan, Hazardous Waste Contingency Plan, Emergency Preparedness and Prevention Plan and/or Emergency responder training, in accordance with applicable OSHA regulations, sufficient to enable the person to direct the evacuation, and/or appropriate response resulting from an environmental emergency incident. e. Required requisite skills, education, and qualifications required include classroom and on- the-job training as follows: 1. 90-day Hazardous Waste Storage Areas Operator – 90-day storage hazardous waste storage areas shipper, DOT Hazardous Materials Operator, and DOT/RCRA/Emergency Response training; 2. Hazardous Waste Operator – Shipper, DOT Hazardous Materials Operator, DOT/RCRA/Emergency Response training; and, 3. Satellite Accumulation and Universal Waste Operator – RCRA/Emergency Response Training. 10.2.1 90-day Hazardous Waste Storage Areas Operator Operators are in charge of ensuring the 90-day hazardous waste storage areas compliance with this manual, training regulations, and emergency response duties. The operators respond to emergency incidents according to the level of training received. The 90-day Hazardous Waste Operator must ensure that the 90-day hazardous waste storage areas drum storage or bulk storage containers are shipped off-site within each 90-day period, and that weekly inspections are completed and documented. 10.2.2 Hazardous Waste Satellite Accumulation Operator Operators overseeing an area that includes a hazardous waste satellite accumulation container are responsible for complying with Section 7.0 (Hazardous Waste Satellite and Universal Waste Accumulation Areas) of this manual [40 CFR 262.15 / R315-262-15] and emergency response duties. The operators respond to emergency incidents according to the level of training received. 10.2.3 Hazardous Waste Shipper Individuals who have shipping responsibilities for hazardous wastes. As required in 49 CFR 172.704, initial training will include a class overview of DOT requirements, this manual, and emergency response duties. The emergency response trained operators respond to emergency incidents according to the level of training received. 10.2.4 Universal Waste Operator Operators overseeing an area that includes a universal waste container are responsible for complying with section 7.0 (Hazardous Waste Satellite and Universal Waste Accumulation Areas) of this manual, and emergency response duties. The operators respond to emergency incidents PERSONNEL TRAINING August 2020 Thatcher Solid and Hazardous Waste Management Plan 104 according to the level of training received. As required in both 40 CFR 262.17(a)(7) / R315-262- 17(a)(7) and 40 CFR 273.16 / R315-276-16, initial training will include a class overview of the Universal Waste requirements under RCRA and this manual. 10.3 TRAINING RECORD KEEPING All hazardous waste training records will be kept for the life of the facility. These records are kept in the Safety-Health-Environment Department files. WASTE MINIMIZATION GUIDELINES August 2020 Thatcher Solid and Hazardous Waste Management Plan 105 11.0 WASTE MINIMIZATION GUIDELINES The facility is committed to preventing or reducing pollution by avoiding unnecessary generation of wastes and by participating in recycling efforts. The facility has implemented a waste minimization program that addresses waste minimization efforts and opportunities for used oil, non-hazardous petroleum related wastes, hazardous materials/wastes, non-hazardous materials/wastes, universal wastes, and other solid wastes. Waste minimization is achieved through source reduction and environmentally sound recycling. Environmentally sound recycling includes use, reuse, or reclamation. The facility has implemented these techniques to reduce the quantities of wastes. Examples of the facility’s current waste minimization efforts include the following: a. Source reduction through efficient and evolving operating practices, solvent substitution, and inventory control of paints and solvents; b. Environmentally sound recycling of aluminum, paper, cardboard, solvents, used oil, antifreeze, lead acid batteries, fire extinguisher powder, scrap metal, e-waste, fuels, and/or Chlorinated Fluorocarbons (CFCs)/Refrigerants and; c. Product substitution of materials that may potentially generate a hazardous waste to products that are environmentally sound, such as the elimination of chlorinated solvents in all facilities; and, d. Recycling of Universal Wastes, off site at permitted universal waste handling facilities. 11.1 MANAGEMENT SUPPORT Minimizing the amount of hazardous waste generated is a crucial component of any effective waste management program. The facility has an ongoing program of waste minimization. Facility management will continue to support waste minimization efforts through one or more of the following methods: a. Issuing a formal written statement encouraging waste minimization, b. Setting waste reduction goals, c. Using preferred alternative products identified by the New Product Review form; d. Making a commitment to implement waste minimization recommendations, e. Designating waste minimization coordinator(s), f. Publishing waste reduction success stories, g. Implementing and employee incentive program, and/or h. Training employees to recognize waste reduction opportunities. 11.2 WASTE GENERATION ACCOUNTING The facility maintains a waste management system to track the types and quantities of wastes produced as well as the types and amounts of hazardous constituents in wastes, including the rates and dates they are generated. The data accumulated in this accounting system supports WASTE MINIMIZATION GUIDELINES August 2020 Thatcher Solid and Hazardous Waste Management Plan 106 the facility's waste reduction efforts by providing information needed to identify waste minimization opportunities. The waste management system also provides the data required to describe the facility's waste minimization efforts; and results for LQG Biennial Reporting if required in the future. A Biennial Report that is required for an LQG by regulation is required to be submitted to ADEQ by March 1 of each even numbered year. 11.3 ECONOMIC BENEFITS OF WASTE REDUCTION Reducing the quantity and toxicity of wastes makes good economic sense due to the high cost of hazardous waste management and disposal. Significant cost savings can include: • Reduced testing, transportation, and disposal costs, • Reduced regulatory compliance costs, • Reduced future liability costs, and • Increased worker safety. In many cases, implementation of proper waste management practices can significantly reduce disposal costs. For example, a 55-gallon drum of waste oil can be recycled for less than $50. However, if a chlorinated solvent were added to this drum, the waste may be re-classified as a hazardous waste, increasing the disposal cost to as much as $800. The facility will periodically determine the true costs associated with waste management and cleanup, including the costs of regulatory compliance, paperwork and reporting, costs of materials found in the waste stream, employee exposure and health care, transportation, treatment, storage, disposal costs, and liability insurance. This will enable the facility to identify where the greatest waste-reduction cost savings opportunities exist. 11.4 WASTE MINIMIZATION ASSESSMENTS The facility will periodically conduct waste minimization assessments in order to identify where materials can be prevented from becoming a waste or where new waste minimization approaches can be effectively applied to a waste stream. Specific waste minimization approaches to be considered for application include: source reduction, recycle/reuse, and treatment. Some waste reduction examples include: a. Input Changes (raw product substitution) - Example: Use of non-toxic grease instead of grease containing toxic metals or volatile organic solvents. Also, replacing chlorinated degreasing solvents with non-chlorinated solvents. b. Operation Improvements - Examples: Chemical and/or physical property testing to extend the useful life of a product such as motor oil or antifreeze. WASTE MINIMIZATION GUIDELINES August 2020 Thatcher Solid and Hazardous Waste Management Plan 107 c. Maintenance Process Changes - Example: Oil or coolant reuse - During maintenance and repair activities that require oil or coolant removal but not change-out, save the material for reintroduction. d. Administrative Controls - Example: Inventory control procedures and policies to ensure products are used before new products are purchased and that damaged product containers are properly repackaged and labeled for use. e. Recycle/Reuse - Example: Recycling of solvents, used oil, antifreeze, lead acid batteries, fire extinguisher powder, scrap metal, e-waste, fuels, and/or CFCs/Refrigerants. 11.5 TECHNICAL WASTE MINIMIZATION INFORMATION The facility exchanges technical waste minimization information and success stories with other company facilities. The facility also seeks out waste reduction information from other companies, technical publications, trade or professional associations, consultants, universities, or governmental agencies. 11.6 IMPLEMENTATION OF WASTE REDUCTION APPROACH The facility strives to implement waste reduction approaches identified by waste minimization assessments. Implemented waste reduction approaches are periodically evaluated by facility personnel using one or more of the following criteria: a. Waste reduction effectiveness, b. Economic cost including effects on production and product quality, c. Barriers or obstacles to implementation, and d. Environmental impact and regulatory requirements. APPENDIX A August 2020 Thatcher Solid and Hazardous Waste Management Plan A.1 Appendix A EMERGENCY CONTACT LIST Primary Emergency Coordinator Emergency Phone Number Darren Bauer – VP Safety-Health-Environment Department 801-888-6047 Alternates Dave Johnson – Environmental Engineer 775-250-2930 Brandon Lowery – Safety-Health-Environment Department TECHNICIAN 435-237-7245 APPENDIX B August 2020 Thatcher Solid and Hazardous Waste Management Plan B.1 Appendix B CONTINGENCY PLAN MAPS APPENDIX C August 2020 Thatcher Solid and Hazardous Waste Management Plan C.1 Appendix C HAZARDOUS WASTE MANAGEMENT PERSONNEL JOB TITLES General Job Title 1Name Hazardous Waste Management Personnel Job Titles VP Safety-Health- Environment Departmentt Darren Bauer 90-day Hazardous Waste Storage Areas Operators and/or Emergency Responders DOT Hazardous Materials/Wastes Shipper/Operator Satellite 40 CFR 262. 15 / R315-262.15, Universal Waste40 CFR 273.16 / R315-273-16, and Hazardous Materials and Non- Hazardous Materials/Wastes Management Training Environmental Engineer Dave Johnson 90-day Hazardous Waste Storage Areas Operators and/or Emergency Responders DOT Hazardous Materials/Wastes Shipper/Operator Satellite 40 CFR 262. 15 / R315-262.15, Universal Waste40 CFR 273.16 / R315-273-16, and Hazardous Materials and Non- Hazardous Materials/Wastes Management Training Safety-Health- Environment Department TECHNICIAN Brandon Lowery 90-day Hazardous Waste Storage Areas Operators and/or Emergency Responders DOT Hazardous Materials/Wastes Shipper/Operator Satellite 40 CFR 262. 15 / R315-262.15, Universal Waste40 CFR 273.16 / R315-273-16, and Hazardous Materials and Non- Hazardous Materials/Wastes Management Training Lab Supervisor Management Satellite 40 CFR 262. 15 / R315-262.15, Universal Waste40 CFR 273.16 / R315-273-16, and Hazardous Materials and Non- Hazardous Materials/Wastes Management Training Lab Technicians Lab Technicians Satellite 40 CFR 262. 15 / R315-262.15, Universal Waste40 CFR 273.16 / R315-273-16, and Hazardous Materials and Non- Hazardous Materials/Wastes Management Training Maintenance Shop Management Satellite 40 CFR 262. 15 / R315-262.15, Universal Waste40 CFR 273.16 / R315-273-16, and Hazardous Materials and Non- Hazardous Materials/Wastes Management Training Truck Shop Management Satellite 40 CFR 262. 15 / R315-262.15, Universal Waste40 CFR 273.16 / R315-273-16, and Hazardous Materials and Non- Hazardous Materials/Wastes Management Training 1Names not listed above are part of the facility operating records. APPENDIX C Waste Analysis Plan 4867-8198-7593\1 PHASE 3 WASTE ANALYSIS PLAN June 2022 Prepared for: THATCHER COMPANY, INC. Prepared by: STANTEC CONSULTING SERVICES INC. 2890 East Cottonwood Parkway, Suite 300 Salt Lake City, UT 84121 Project Number: 203722428 Phase 3 Waste Analysis Plan i 4867-8198-7593\1 Table of Contents 1 INTRODUCTION ......................................................................................................... 1 2 FIELD SCREENING AND SAMPLING ........................................................................ 1 2.1 Air Monitoring ................................................................................................................................ 1 2.2 Liquid Sampling............................................................................................................................. 1 2.3 Solid(s) Sampling .......................................................................................................................... 3 2.4 Sample Identification and Custody ............................................................................................... 4 2.5 Field Screening ............................................................................................................................. 4 3 LABORATORY ANALYSIS ........................................................................................ 6 3.1 Material Category Determination .................................................................................................. 8 3.2 OFF-SITE LABORATORIES ......................................................................................................... 9 3.2.1 CTF ................................................................................................................................ 9 3.2.2 ALLIANCE TECHNOLOGIES ..................................................................................... 11 4 CONCLUSION ...........................................................................................................12 List of Tables Table 2.1 Sample Bottles for Liquids ........................................................................................................ 2 Table 2.2 Sample Bottles for Solids .......................................................................................................... 4 Table 2.3 Field Screening Methods ........................................................................................................... 5 Table 3.1 Field Screening Data Purpose ................................................................................................... 7 Table 3.2 Potential Waste Categories and Laboratory Analysis ............................................................ 8 Table 3.3 CTF Analytical Methods ............................................................................................................. 9 Table 3.4 CTF PARCCS ............................................................................................................................. 11 List of Attachments Attachment 1 Clean Harbors Sampling Procedures Attachment 2 Chain-of-Custody (COC) Attachment 3 Field Screening Strip Instructions Attachment 4 Chemtech-Ford Quality Manual Attachment 5 Alliance QAPP PHASE 3 WASTE ANALYSIS PLAN Introduction Phase 3 Waste Analysis Plan 1 4867-8198-7593\1 1 Introduction This Phase 3 Waste Analysis Plan (P3WAP) has been prepared in accordance with Stipulation and Consent Order number 2102006. This P3WAP details the procedures for field screening, sampling, and laboratory analysis of Phase 3 materials at the Thatcher Company, Inc. (Thatcher) facility located at 1905 West Fortune Road, Salt Lake City, Utah (the Facility). This P3WAP will be used to characterize unknown materials at the facility for off-site disposal. 2 Field Screening and Sampling Prior to beginning Phases 1 and 2 of the Waste Inventory and Characterization Process (WICP) as described in the WICP plan, Thatcher’s project team evaluated known chemicals which may be present at each building based upon the raw materials and products used at the facility to manufacture goods for sale. Known chemicals were used to identify chemicals used and potential exposure hazards to personnel during the process of characterizing and disposing of unknown material. Based upon the known chemicals and potential exposure hazards, a field monitoring and screening procedure was developed as detailed below. Generator knowledge evaluations are detailed in the Phase 3 Material Management Plan (P3MMP). Generator knowledge will be an important tool for identifying materials that are labeled and known to the project team. Containers of known material will also be evaluated if the contents display properties which differ from the Safety Data Sheet (SDS) suggesting that the material has been mixed with an unknown material. 2.1 Air Monitoring Air monitoring will be necessary prior to accessing containers with unknown materials in order to evaluate personnel risks of exposure. While wearing the appropriate PPE, as detailed in a Site Specific Health and Safety Plan, the technician will monitor valves, caps, and/or a slightly open (i.e., cracked) lid using a four- gas meter. If readings are observed to be within acceptable limits, the technician will proceed with opening the container for sampling and will measure the air quality inside the container. If the air measurements are not within acceptable limits, the technician will allow the container to vent until acceptable air measurements are obtained. Measurements from inside the container will be tracked on the Thatcher Field Characterization Sheet and will be used for the sample characterization purposes. The Thatcher Field Characterization Sheet is included in Appendix E of the P3MMP. Air monitoring measurements will include oxygen (O2), lower explosive limit (LEL), carbon monoxide (CO), and hydrogen sulfide (H 2S), and will be recorded on a Field Screening Form which is included as an appendix to the P3MMP. 2.2 Liquid Sampling Liquid and solid material samples will be collected once air monitoring is completed. Liquid samples are typically collected from the opened container using either a composite liquid waste sampler (coliwasa), standard drum thief, or a bailer. These sampling tools are preferred because they can collect sample PHASE 3 WASTE ANALYSIS PLAN Field Screening and Sampling Phase 3 Waste Analysis Plan 3 4867-8198-7593\1 UHC Total VOAs Methanol(wastewater) and Xylene Three (3) 40 ml vials Two (2) 40 ml vials Glass Glass Hydrochloric Acid None Total Sulfide or Cyanide If Detected from Field Monitoring 8 oz 16 oz Plastic Plastic Sodium Hydroxide and Zinc Acetate Sodium Hydroxide A detailed description of Clean Harbors ’ liquid and solid sampling procedures is included as Attachment 1. 2.3 Solid(s) Sampling Solid(s) samples will be collected using hand shovels, spoons, hand augers, or a bucket. All reusable equipment will be decontaminated prior to use as described in the P3MMP. Solid(s) sampling tools will be used to collect solid material from multiple locations within the container. If the solid material appears to be heterogeneous, the sample bottles will be filled using multiple grab aliquots which are approximately equivalent to that material’s proportional content of the container. Sample bottles required for solid samples are included in Table 2.2 below. PHASE 3 WASTE ANALYSIS PLAN Laboratory Analysis Phase 3 Waste Analysis Plan 10 4867-8198-7593\1 Total Cyanide SM 4500(CN)CE Total Sulfide SM 4500(S2)D Ammonia E350.1 Nitrate as N E353.2 SW-846 = US Environmental Protection Agency, Test Methods for Evaluating Solid Waste, Update VII TCLP = toxicity leaching characteristic procedure SM = Standard Methods 1Wastewater/Nonwastewater Definition: Wastewater (WW): Wastes that contain less than 1% by weight total organic carbon (TOC) and less than 1% by weight total suspended solids (TSS). 3.2.1.1 CTF Sample Dilution CTF informed Thatcher of the following: • Complex sample matrices (e.g., oils, paints, soaps, alcohols, waxes etc.) necessitate dilution before VOA/Semi-VOA analyses. • Dilutions raise the Minimum Reporting Limit (MRL/ Practical Quantitation Limits (PQL)) These types of materials may also damage analyses equipment delaying analyses. When the MRL is greater than the TCLP VOA/Semi-VOA regulatory level Thatcher assigns the hazardous waste code (i.e., designates the material hazardous waste). 3.2.1.2 CTF QC Procedures All samples will be submitted for analysis with Level 2+ quality control which includes reporting of: • Surrogate recoveries; • Method blanks 1:20 samples; • Laboratory control samples1:20; and • Matrix spike and matrix spike duplicates 1:20 samples. Precision, accuracy, representativeness, comparability, completeness, and sensitivity (PARCCS) parameters are listed in Table 3.4. PHASE 3 WASTE ANALYSIS PLAN Conclusion Phase 3 Waste Analysis Plan 12 4867-8198-7593\1 Samples will also be evaluated for their elemental composition which will be used to assist wit h the speciation of the type of oxidizer that is present. Solid samples will be analyzed for the presence of elemental ions using inductively coupled plasma optical emission spectroscopy which reports results in units of milligrams per kilogram. Liquid sa mples will be evaluated for elemental ions using energy dispersive x-ray spectroscopy, x-ray diffraction. A copy of Alliance’s QAPP is included as Attachment 5. 4 Conclusion This P3WAP details the procedures for field screening, sampling and laboratory analysis of Phase 3 materials at the Thatcher Facility. If material characterization procedures deviate from the processes described in this WAP, the DWMRC will be informed of the new procedure and the reason for the variance. Variances may be necessary in instances where an unanticipated material category is encountered. PHASE 3 WASTE ANALYSIS PLAN Phase 3 Waste Analysis Plan 4867-8198-7593\1 Attachment 1 Clean Harbors Sampling Procedures SAMPLING PROCEDURES COLLECTION EQUIPMENT A variety of equipment should be available from a secure storage site for use by the CHES FS PERSONNEL, as suggested below. Much of the equipment should be of the disposable type to minimize cleaning, for QA and safety reasons. Additional items may be added as needed. Solids Collection. Items for collecting samples of solids: • Hand Shovels – Steel, stainless steel & plastic • Stainless Steel / Plastic - Scoop / Spoon • Hand Auger • Stainless Steel / Plastic – Pan / Bucket Liquid Collection. Items for collecting samples of liquids: • Sample Rods and Contaminated Liquid Waste Samplers (Coliwasa) - disposable plastic • Pipettes and Droppers - disposable plastic • Bailers - disposable plastic and Teflon • Stainless Steel or Polypropylene Dipper Sample Jars and Containers: An assortment should be readily available. To eliminate possible contamination or reaction of future samples, new sample containers should be used each time, and each should be used only once. New containers may be used out-of-box for information and disposal sampling activities. Glass containers should have Plastic or Teflon-lined lids. Recommended sample containers to secure include: At each container, the CHES FS team will perform various field tests and gather all the bottles needed to support Stantec FTIR and AWAL. • Solids / Soils: four 4oz jars plus one tall 16 oz jar • Liquid/Part Liquid: one 4oz jar, one 250 mL plastic, one 16 oz tall glass, one 1L plastic, one 1L amber, three unpreserved VOC vials. SAMPLING PROCEDURES This section describes how to collect various types of samples, CHES may alter these procedures, as appropriate, on a case-by-case basis. • Consult (SEE ATTACHED) JHA for KNOWN and UNKNOWN Sampling steps and Safety Procedures. • Before commencing collection of samples, thoroughly evaluate the site Pre-sampling staging area, sampling area and disposal staging area. Checking for any leakers, labels that may be peeling off containers and to develop the sampling plan for the day’s activities. SAMPLING PROCEDURES SAMPLING PROCEDURES (Cont.) • Record pertinent observations in Supervisor / Foreman field notes. Include a sketch, when appropriate. • Prepare all sampling equipment and sample containers properly prior to staging containers in the Sampling / Repack Secondary containment. If possibly sample in the staging area and following the day’s sampling plan discussed during the Safety Tail gate meeting at the beginning of the shift following the pre-work inspection. • Have absorbents handy to control spills. • Place containers for receiving samples on a flat, stable surface. • Collect samples and securely close containers as quickly as feasible. • Where possible, record field observations at a safe on-site location rather than from the sampling point itself. • Due to potentially hazardous samples, be sure to clean the outside of the sampling containers prior to packaging them for transportation. • Label all sample containers with the date, time, sample ID and collector's initials that will match the COC. • Complete all chain-of-custody documents and record information in the field notes (JOB STATEMENT DAILY). • Sampling equipment that is reused should be decontaminated between samples. High or Low pH sampling devices to be reused MUST only be reused on like pH or chemical compounds. Drum or Container Sampling 1. Approach and open the drum or container only if it is possible to do so safely. Prior to opening the container use a 4/5 gas PID meter to monitor the valve, lid, caps, etc… if all readings are safe, proceed with opening the container for sampling, once open use 4/5 gas PID to get reading of the contents of the drum and document on the Thatcher Field Characterization Sheet. KNOWN CHEMICAL (PPE): If the Container is a Known chemical but still requires sampling, review the SDS for Hazards and Proper PPE (Suggested PPE QC Tyvek Suits, FFAPR with GME P100 cartridges, Nitrile Inner Gloves, Neoprene Outer Gloves, Steel Toe Chemical Boots ALL Seams fully Taped Up. UNKNOWN CHEMICAL (PPE): If the Container is an Unknown chemical Minimum Suggested PPE SL Tyvek Suits, Full Face Suppled Air Mask with SAR Bottle or SCBA, Nitrile Inner Gloves, Neoprene Outer Gloves, Steel Toe Chemical Boots ALL Seams fully Taped Up. SAMPLING PROCEDURES Drum or Container Sampling (Cont.) 2. Select the sample container that is appropriate for the type of sample you will be obtaining. If Liquid use one 4oz jar, one 250 mL plastic, one 16 oz tall glass, one 1L plastic, one 1L amber, three unpreserved VOC vials, Volatile Organic Compounds (VOCs) are to be a parameter, use (3) three unpreserved VOC vials, especially if the material is aqueous or of other nature that would allow easy volatilization. If the material is VOC Solids or contaminated soil, use an four 4oz jars plus one tall 16 oz jar with a Teflon-lined cap or Plastic Lid. 3. Select the appropriate sample rod or coliwasa for the chemical to be sampled. Slowly insert a sample rod or coliwasa into the drum / container. Go to the bottom of the drum in order to obtain a representative sample of all the layers that may be present. 4. If viscous materials are encountered, be careful about the possible breaking of the sampling Rod, More than one attempt may be needed to retrieve a sample of all layers. 5. Using a gloved hand, cap the end of the rod with a thumb; then quickly withdraw the rod from the drum. 6. Place the bottom end of the rod into a sample container and slowly release the thumb control to allow the material in the sample rod to flow smoothly into the sample container. Put the sample container nearby or atop the drum to lessen the chance of spillage. 7. Repeat the procedure until the desired amount of sample has been obtained. If VOCs are a parameter, fill the sample container completely to the top to minimize volatilization of the sample. 8. Place the rod back into the Drum / Container momentarily and close the sample container immediately. 9. Dispose of the rod, • If acceptable to the disposal facility, break the rod and leave it in the drum; Or • Package it with other debris from the site, such as used PPE; *** Bag PPE and sampling devices and place into a designated Drum, Flex Bin (Cubic Yard Box) or Roll Off Box for Proper disposal. *** 10. Close the Drum / Container. 11. Label the sample container and the drum / container in a manner that allows them to be referenced to each other. (i.e. Date, Time, Sample ID#) This is to be written with a Pint Marker on the TOP and Side of each Drum / Container, also Place a Hazardous waste label on the Drum / Container as “PENDING ANALYSIS” and a On Test Sticker Placed on the Drum / Container. SAMPLING PROCEDURES Drum or Container Sampling (Cont.) 12. Place the sample container in a shipping container (e.g., a cooler) for transportation along with a COC Chain Of Custody. 13. Repeat this procedure for each drum / container to be sampled. OTHER SAMPLING CONSIDERATIONS VOC Vials Samples that are to be tested for VOCs are to be collected in VOC vials to minimize loss of volatile compounds. This is especially true with aqueous samples or other materials that may allow for easy loss of VOCs. To properly fill a VOC vial: • The vial should be completely filled to prevent any volatilization. • Extreme caution must be taken when filling the vial to avoid agitation or turbulence that may allow the loss of VOCs. • Gently pour the sample down the side of the vial to fill. • Invert the vial and tap it gently to look for air bubbles. If bubbles are observed, repeat the procedure. NOTE: If the material to be sampled has significant vapor pressure, such as a concentrated solvent, a VOC vial is not recommended for use. Remember to only fill the sample container to approximately 90% full. Cooling The most common preservative measure for emergency response sampling is to cool the samples with ice packs or cold packs. • Never use ice to cool materials that are known or suspected to be water reactive. • Whenever possible, dilute aqueous samples should be cooled, especially in preparation for low- or medium- level organic analysis and low-level inorganic analysis. • VOC vials of dilute aqueous samples should also contain an appropriate preservative. • All cyanide samples must be shipped on ice. SAMPLING PROCEDURES Cooling (Cont.) • Concentrated waste samples generally do not need to be preserved, but it is nevertheless good practice to cool them. Field Testing: • pH Test (0-14) - pH paper / Strips are used to estimate the pH of aqueous samples (and of water test mixtures). • Oxidizer Risk / Test - Spilfyter Chemical Classifier Strip to be used Light – Dark Blue= Present White= Not Present • Flouride Risk / Test - Spilfyter Chemical Classifier Strip to be used Yellow= Present Pink= Not Present • Petroleum Product, Organic Solvent Risk / Test – Dark Blue= Present Light Blue= Not Present • Iodine, Brome, Chlorine Risk – Violet= Present Peach= Not Present • Peroxide Risk / Test – Quantofix (91312) Test Strip 1-100 mg/L H2O2 • Cyanide Risk / Test – Quantofix Vile / Strip (91318) Test Kit 1-30 mg/L CN • Ammonium Risk / Test – Quantofix Vile / Strip (91315) Test Kit 10-400 mg/L NH4 • 4 / 5 Gas Meter - ALTAIR® 5X Multigas Detector (O2, CO, H2S, LEL) PID Varies on Meter we assign (VOC, CN, SO2) Lab Analysis – AWAL - American West Analytical Laboratories: • pH (ALL SAMPLES) • Cat 1 Corr Inorg: TCLP Dlist Metals • Cat 1 Corr Org: Flash, TCLP Dlist (Met, SVOC, VOC) • Cat 2 non Corr Inorg TCLP Dlist Metals • Cat 3 non Corr Org: Flash, TCLP( Met, SVOC, VOC) • Cat 4 Oxdz Etc Org: Flash, TCLP (Met, SVOC, VOC) • Cat 4 Oxdizer Etc. Inorg: TCLP Dlist Metals • Cat 5 Halo HC Flash, TCLP Dlist (Met, SVOC, VOC) • Cyanide • Sulfide SAMPLING PROCEDURES Cleaning Procedures Clean Harbors normally acquires sample containers as needed from a contract laboratory that pre- cleans them. All cleaning should be done outdoors in a well-ventilated area with in our containment work area, using Level D protection at a minimum. After cleaning an item, handle and store it in a manner that prevents contamination. Items should be wrapped in new aluminum foil or in a new sealable plastic bag (i.e. Drum, bucket poly liner taped. Glass Items 1. Wash with detergent (i.e. Dawn dish soap) and rinse with tap water. 2. Rinse with tap water. 3. Air or Rag dry 4. Package to prevent contamination. Stainless Steel Equipment 1. Wash with detergent (i.e. Dawn dish soap) and rinse with tap water. 2. Rinse with tap water. 3. Air or Rag dry 4. Package to prevent contamination. Plastic or Teflon 1. Wash with detergent (i.e. Dawn dish soap) and rinse with tap water. 2. Rinse with tap water. 3. Air or Rag dry 4. Package to prevent contamination. Note: Plastic pipettes or droppers should not be cleaned due to the difficulty of cleaning and drying them. Use only as new in box. Soil or Sludge Sampling: The type of soil / sludge sampling CHES will normally need to obtain is a surface grab sample at a spill site, a composite sample of a soil pile, or confirmation sampling in an excavation. (rarely need to obtain deep soil corings; so that aspect will not be discussed.) 1. Sample container with a sufficiently wide mouth to facilitate filling. It must be made of glass and have a Teflon or aluminum-foil seal. 2. Use a clean Plastic / Teflon, stainless-steel scoop, spoon, or auger to gather the desired sample. SAMPLING PROCEDURES Soil or Sludge Sampling Cont.: 3. If the area is large or not visibly homogeneous, composite several samples within the contaminated area. 4. The sample should be as free as possible of twigs, rocks, or other debris. 5. Sludges should be allowed to settle and liquid rise to the top to be strip test if needed a small amount of distilled water will be added and mixed into get a enough liquid produced to conduct the onsite strip testing. 5. If VOCs are intended to be a parameter, it is important to minimize their volatilization. Avoid unnecessarily agitating or disturbing the soil sample. To minimize headspace volatilization, fill the sample container as completely as possible. 6. Close, seal, and label the sample container. 7. Place it in a shipping container for transportation. Ice is not generally required for soil samples, but ice may be used at the discretion of the sampler. However, to preserve their integrity all cyanide and VOC samples must be cooled. Composite Solid Sampling: The aim of this procedure is to composite random samples of solids (e.g., soil, debris, hazardous materials, scale, powder or fluff) drawn from containers that may or may have NOT been previously liquid. 1. Survey the container. 2. Sample container with a sufficiently wide mouth to facilitate filling. It must be made of glass and have a Teflon or aluminum-foil seal. 3. Use a clean Plastic / Teflon, stainless-steel scoop, spoon, or auger to gather the desired sample. 4. Solids should be put into a small test container (Glass or Plastic), a small amount of distilled water will be added and mixed into get enough liquid produced to conduct the onsite strip testing. 5. The field-testing results will be Noted on the Field Characterization Sheet. 6. Pull sample and pack into sampling containers with NO head space, label and place the containers in ice chest for lab analysis, add samples container count and sample ID# to the COC – Chain of Custody. SAMPLING PROCEDURES Container Management (Staging, repacking, over packing): 1. Inspect container (POLY Containers) for UN rating and expiration dates. Like all plastic packages, their UN approval expires after 5 years so the date of manufacture is important to check. Note that in the case of Nitric acid (>55%) and Hydrofluoric acid (>75%) the approval only lasts 2 years Inspect Container (STEEL DRUMS): It is important to know that once a certified UN steel drum is manufactured, it can be invalidated, but it never expires! What is critical is that the certification test report is valid when the drums are manufactured. Though certification on the steel drum does not expire, it can be deemed noncompliant if the components used in the drum are not as those specified in the Closure Instructions from the original steel drum manufacturer, or the most recent re-manufacturer. ALL CONTAINERS: Steel Drums, Poly Drums and Totes need to be inspected for expiration dates (EXPIRED), dents, dings, gouges, cracking, rusting, missing seals, caps or bungs will require the contents to be Repacked or Over Packed. Dirty exterior of a container will require to be Cleaned, repacked or over packed. OVER DRUMS: Overdrums or Salvage Drums are used to contain drums that for various reasons are unsuitable to move. This can include drums that are out of date, leaking or in bad condition (dented, rusted etc). IBC’S IBCs (Intermediate Bulk Containers) are a larger scale alternative to drums. They are typically used for customers who produce large quantities of a waste stream. Composite IBC’s are the most commonly used type of IBC. They are a plastic inner receptacle in a metal cage outer. They fulfil a similar role to tight-head drums and are used for a broad range of waste streams e.g., solvents and acids. •The CHES will fills them through the cap at the top and discharges the contents through the drip cap at the bottom •IBC’s need to be tested every two and a half years to maintain their UN approval. •An example of a UN code found on an IBC is shown in Example 2 below. SAMPLING PROCEDURES SAMPLING PROCEDURES CONTAINER STAGING / REPACKING: 1. New set of containers are staged in rows that can be accessed by all sides for sampling and inspection. 2. NO more than 50 containers in the staging area at one given time. 3. Once the container has been inspected, sampled it will have a Hazardous Waste Label and a “On Test label placed on the container “Pending analysis” 4. The container will have a Sample ID issued which will be unique to any other container. 5. The crew will place on a CHES Inventory form weather it is to be shipped or if it is to be Repacked or Over Packed. SAMPLING PROCEDURES CONTAINER STAGING / REPACKING Cont.: 6. The Container will be taken into the Over Pack / Repack Secondary Containment and Repacked or Over Packed. Most drums will be over packed and Most Totes (IBC’s) will be Repacked. IBC’s that are Repacked based on the consistency of the material in the tote (i.e. Full Free Flowing liquids will be pumped or drained into another IBC). (IBC’s that are Approx. ½ full or Less will be repacked into drums, IBC’s with solids will be repacked into drums and they will retain the Sample ID number assigned to the Original container, but a “S” will be added to the End for Heavy Sludge or Solids). 7. The repacked container will be updated on the CHES internal inventory sheet as to what size container / containers and quantity of containers the original Sample ID Number was repacked into. NOTE: All Repacking operations will be conducted in Level C (Unless the Chemical SDS or Field testing and Monitoring require upgraded PPE. 8. Once the container is repacked or Over packed it will be staged in the Last section of the containment Staged for disposal. 9. Once the results are back from the Lab, Stantec will then Assign the Container Sample ID a Waste Profile number. 10. Once a waste profile number has been assigned to the container or containers the waste will be scheduled for disposal, a manifest and labels will be printed. 11. The Crew will then Place the labels on the containers based on the Container size & profile number. 12. Inventory will be rechecked and confirmed then a truck will be scheduled to perform the T&D to remove the waste from the Site. EMPTY CONTAINER MANAGEMENT: 1. Empty containers from repack operations to be to RCRA empty standard with NO free liquids. 2. Drums and totes to be crushed or cut to minimize void space. 3. Crushed and Cut Drums and Totes to be placed into lined roll off container or containers with absorbent spread on the bottom. 4. Crushed and Cut Drums and Totes to be disposed of on a Debris waste profile, the bin will be the same used for PPE, Plastic, Sampling devices, etc… PHASE 3 WASTE ANALYSIS PLAN Phase 3 Waste Analysis Plan 4867-8198-7593\1 Attachment 2 Chain-of-Custody CONTACT: PROJECT: PO Number: INVOICE EMAIL ADDRESS: 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. Bottle type Lot # QC levels definition: QC1: none QC2: Batch QC, random sample QC3: 25% surcharge. Narrative plus Batch QC, your sample selected QC4: 40% surcharge. Add raw data COMPANY: CHAIN OF CUSTODY - SAMPLE SUBMITTAL FORM * Expedited turnaround subject to additional charge UPS HP C Headspace Present (VOC) PHONE #: ADDRESS: Sample condition CITY/STATE/ZIP: EMAIL: TESTS REQUESTED Special Instructions: Received by: [signature] Customer Courier Sampled by: [print] Correct Containers Sufficient Sample Volume TIME Received on Ice Payment Terms are net 30 days OAC. 1.5% interest charge per month (18% per annum). Client agress to pay collection costs and attorney's fees. Sampled by: [signature] Received by: [signature] Relinquished by: [signature] Delivery Method Date/Time Date/Time Date/TimeRelinquished by: [signature] Relinquished by: [signature] RUSH Due Date*: CLIENT SAMPLE INFORMATIONLab Use Only MATRIX USPS Received within Holding Time Chemtech-Ford Courier DATE FedExTemperature Blank temperature range of 0-6 C° may be rejected. ON ICE NOT ON ICE Temp (C°): Samples received outside the EPA recommended E. C o l i / C o l i f o r m ( A b s e n t / P r e s e n t ) Custody Seal Container Intact COC/Labels Agree Walk-in Date/Time Date/Time LOCATION / IDENTIFICATION Received by: [signature] QC Level 1 2 3 4 E. C o l i / C o l i f o r m ( E n u m e r a t e d ) Date/Time Chemtech-Ford Laboratories 9632 South 500 West Sandy, UT 84070 Phone: 801-262-7299 www.chemtechford.com PHASE 3 WASTE ANALYSIS PLAN Phase 3 Waste Analysis Plan 4867-8198-7593\1 Attachment 3 Field Screening Strip Instructions PHASE 3 WASTE ANALYSIS PLAN Phase 3 Waste Analysis Plan 4867-8198-7593\1 Attachment 4 CTF Quality Manual Quality Manual This Quality Manual meets the requirements of ISO 17025, ISO 9001, and TNI. This Quality Manual is confidential and assigned as outlined below. Original Document: Quality Manager Controlled Copy Uncontrolled Copy All employees have access to a controlled version through Quality Manager, or through the Chemtech-Ford intranet. Printed copies are not considered controlled documents. Companies whose Quality Systems are defined by this document are: Chemtech-Ford Laboratories 9632 South 500 West Sandy, UT 84070 801.262.7299 Timpview Analytical Laboratories 1384 West 130 South Orem, UT 84058 801.229.2272 This Quality Manual has been approved for use by affiliate laboratories of Chemtech- Ford, Inc. PHASE 3 WASTE ANALYSIS PLAN Phase 3 Waste Analysis Plan 4867-8198-7593\1 Attachment 5 Alliance QAPP Information for Work Plan / R20210400 Prepared for: Stantec Salt Lake City, UT November 18, 2021 www.alliancetechgroup.com info@alliancetechgroup.com 732.355.1234 (ph) www.alliancetechgroup.com 9 Deer Park Drive ~ Suite B Monmouth Jct., NJ 08852 info@alliancetechgroup.com CONFIDENTIAL - R20210400 QAPP DOCUMENTATION.DOCX - THE ANALYTICAL DATA IN THIS REPORT ARE TO BE USED FOR EXPLORATORY AND DEVELOPMENT STUDIES ONLY AND ARE NOT INTENDED FOR PRODUCT RELEASE PG 2 Summary Alliance Technologies is an FDA and DEA-registered laboratory. The lab was asked to perform the following testing on a varity of samples provided by Stantec: • ICP-OES • Active Oxygen • EDX analysis to determine approxiamte elemental composition • X-Ray Diffraction (XRD) on solid samples for phase analysis In-house methods were used for all sample analysis and are described in the Experimental section. Experimental Analysis of Samples for Active Oxygen: Since the samples had an unknown amount of Active Oxygen, the samples were “screened” by creating a 10% solution of the sample. Approximately 1g of each sample was placed in a 15 mL centrifuge tube and diluted to 10mL with DI water. The solutions were then shaken to mix and allowed to sit at room temperazture overnight. The next day, 1mL of the sample solutions was placed in a 15 mL centrifuge tube along with 1.0 mL 50% KI and 1.0 mL of starch indicator. If the color of the solution did not change to a darker shade of purple/black; the solution was not titrated and determined to have low/no Active Oxygen. If the color of the solution changed, 0.5 mL increments of 0.1N sodium thiosulfate was added until the solution was colorless. For samples low in Active Oxygen, 5mL of the sample solution was placed into a 150mL beaker along with 1.0 mL of 50% KI and 1.0 mL of starch indicator. The solution was diluted to ~60mL with DI water. The solution was titrated with 0.025N sodium thiosulfate until the solution became colorless. www.alliancetechgroup.com 9 Deer Park Drive ~ Suite B Monmouth Jct., NJ 08852 info@alliancetechgroup.com CONFIDENTIAL - R20210400 QAPP DOCUMENTATION.DOCX - THE ANALYTICAL DATA IN THIS REPORT ARE TO BE USED FOR EXPLORATORY AND DEVELOPMENT STUDIES ONLY AND ARE NOT INTENDED FOR PRODUCT RELEASE PG 3 The final Active Oxygen was calculated from the amount of thiosulfate required to reach the endpoint in the titration. ICP-OES analysis: The samples were weighed into 15 place Teflon microwave digestion vessels. To each tube, 8 mL of nitric acid was added. The samples were then digested using a Milestone Ultrawave. Once the samples cooled, they were quantitatively transferred to 50 mL ICP tubes and diluted to 25 mL using DI water. The solutions were then analyzed on an Agilent 710 ICP-OES which was calibrated using a multi-point calibration curve created from NIST-traceable standards. XRD Analysis: The solid samples were ground into a fine powder using a mortar and pestle. The powder was backfilled into the sample holder to allow for random orientation . Optimized diffraction data was collected using a Philips PW1830 diffractometer system XRD patterns were collected on a Philips PW1830 diffractometer system operating with the following parameters: 45kV Voltage and 35mA Current Quality Control The following documents are being supplied for a description of the Quality system used at Alliance Technologies: • 1M-04 Policy Manual – Describes the overall quality management system and quality policy • GE003-08 – Documentation and Data Handling © Alliance Technologies, LLC 2021 - Reproduction of this report in its entirety is permitted. No portions of this report may be reproduced, transmitted, or removed without the written permission of Alliance Technologies. All Rights Reserved. APPENDIX D P3MMP Distribution List Phase 3 Material Management Plan Distribution List Area Print Name Signature APPENDIX E Clean Harbors Health and Safety Plan HEALTH AND SAFETY PLAN Phase III Material Management Plan Thatcher Group, Inc. 1905 Fortune Road Salt Lake City, UT 84104 March 2022 Prepared by: Michael E. Sanders Operations Manager Clean Harbors Sanders.michaele@cleanharbors.com 801-673-5373 Page i Table of Contents 1. Scope of Work……………………………………………………………………………………..…1 1.1. General…………………………………………………………………………………………..1 1.2. Scope and Applicability of the Health and Safety Plan……………………………………..1 2. Site Description……………………………………………………………………………………….1 3. Roles and Responsibilities…………………………………………………………………………..2 3.1. Responsibilities of Foreman/Supervisor……………………………………………………...2 3.2. Responsibilities of Health and Safety…………………………………………………………2 3.3. Responsibilities of Onsite Personnel……………………………………………………........3 4. Training and Medical Monitoring Requirements…………………………………………………..3 4.1. Training…………………………………………………………………………………………..3 4.2. Medical Monitoring Program…………………………………………………………………...4 5. Description of Field Work……………………………………………………………………………4 6. Physical Hazards……………………………………………………………………………………..4 6.1. Weather…………………………………………………………………………………………..4 7. Personal Protective Equipment……………………………………………………………………..5 7.1. Selection of Personal Protective Equipment…………………………………………………5 8. Illumination…………………………………………………………………………………………….5 9. Meteorological Monitoring…………………………………………………………………………...6 10. Standard Safe Work Practices……………………………………………………………………...6 10.1. General Rules of Conduct……………………………………………………………...6 10.2. Injury/Illness Reporting…………………………………………………………………7 11. Confined Spaces……………………………………………………………………………………..7 12. Air Monitoring…………………………………………………………………………………………7 13. Work Area Access……………………………………………………………………………………7 14. Decontamination……………………………………………………………………………………...7 15. Sanitation……………………………………………………………………………………………...8 16. Emergency Supplies…………………………………………………………………………………8 17. Emergency Information………………………………………………………………………………8 17.1. Site Resources…………………………………………………………………………..9 17.2. Emergency Procedures………………………………………………………………...9 18. Directions to Medical Facilities…………………………………………………………………….10 19. Authorized Changes to the Health and Safety Plan…………………………………………….10 Attachment A: Facility Map Attachment B: Plan Acceptance Form Attachment C: Directions to Rocky Mountain Care Clinic Attachment D: Directions to University of Utah Hospital Attachment E: Employee Acknowledgement Page 1 1.0 Scope of Work 1.1 General This HASP describes the procedures and protective measures that will support the work being performed at the site. All Occupational Safety and Health Administration (OSHA) Regulation requirements will be followed. The purpose of this HASP is to provide site-specific safety information and procedures, overview of site hazards, chemicals of concern, action levels, initial levels of personal protective equipment to be used for various site activities, decontamination procedures, and emergency resources and information. In this document, Clean Harbors will establish procedures designed to meet the following goals: 1. Staff: A team consisting of 1 x Foreman/Supervisor, 1 x Operator and 2 x Technicians providing support up to 40 hours/week, for the tasks outlined in the “Description of Field Work” section of this document. 2. Incorporate Clean Harbors Online Services system capabilities for visibility into waste volume tracking, generating regulatory reporting data and compliance inspections. 3. Provide Transportation and Disposal pricing for all waste streams. 4. Prepare and coordinate shipments of all waste streams into designated facilities. Develop a partnership/program that is flexible enough to allow for contraction or expansion of duties that mirrors Thatcher’s business fluctuations. 1.2 Scope and Applicability of the Health and Safety Plan The provisions of this HASP are for all personnel working on site, who shall read this plan and sign the accompanying plan acceptance form (Attachment A) before starting site activities. In addition, personnel will operate in accordance with the most current requirements of Title 29 Code of Federal Regulations, Section 1910.120 (29 CFR 1910.120), Standards for Hazardous Waste Operations and Emergency Response (HAZWOPER). These regulations include the following provisions for employees: training, CFR 29 1910.120 (e); medical surveillance, CFR 29 1910.120(f); and personal protective equipment (PPE), CFR 29 1910.120(g). Clean Harbors personnel are responsible for operating in accordance with all applicable regulations of the company and Federal/State guidelines. If there are any questions, please contact the Site Foreman/Supervisor or Health & Safety. 2.0 Site Description Thatcher is in Salt Lake City, UT the facility produces various chemicals for commercial sale. The area in which Clean Harbors will be conducting sampling and repacking is in the Northwest corner of the plant. This area is barricaded off from the rest of the plant and only designated personnel have access. Page 2 3.0 Roles and Responsibilities The Foreman/Supervisor is the primary entity to conduct the work at the Site. If personnel involved in removal action activities believe that the removal action process is being conducted in a manner inconsistent with the work plan or HASP, or in any other inconsistent manner, all activities must cease. 3.1 Responsibilities of Foreman/Supervisor The Site Foreman/Supervisor will direct the activities. The Foreman/Supervisor has the primary responsibility for ensuring that all personnel are aware of: Names of personnel and alternates responsible for site safety and health. Safety, health, and other hazards present onsite. Use of personal protective equipment (PPE) and ensuring that the equipment is available and in good working condition. Work practices by which the employee can reduce risks from hazards. Safe use of engineering controls and equipment onsite. Medical surveillance requirements, including recognition of symptoms which might indicate exposure to hazards. Site control measures, decontamination procedures, site standard operating procedures, and the contingency plan and responses to emergencies including the necessary PPE. The Foreman/Supervisor is also responsible for ensuring that all employees have received at least 40 hours of health and safety instruction (off-Site), and three days of actual field experience under the direct supervision of a trained experienced supervisor. Workers who may be exposed to unique or special hazards shall be provided additional training. The Foreman/Supervisor also monitors the performance of personnel to ensure that mandatory health and safety procedures are being performed and corrects any practices that do not comply with the HASP. Copies of the health and safety training certificates must be available for review by the Foreman/Supervisor. If unforeseen site conditions or emergencies occur, the Foreman/Supervisor shall ensure that the medical surveillance program is implemented as required by CFR 29 1910.120. Additional responsibilities may include: Consulting with the H & S and/or personnel. Preparation and submittal of any and all project reports – includes progress, accident, incident, contractual, etc. Monitoring personnel decontamination to ensure that all personnel are complying with the established decontamination procedures. 3.2 Responsibilities of Health & Safety The responsibilities of H & S include: Ensures that a copy of the HASP is maintained on-Site during all field activities. Advise the team on all health and safety-related matters involved onsite. Page 3 Follow the safety program in the field, including the proper use of personal protective and site monitoring equipment. Ensure that field personnel observe the appropriate work zones and decontamination procedures. Report any safety violations to the Foreman/Supervisor and local Management. Conduct safety briefings during field activities. H & S will approve this HASP and will address any changes that need to be made to this HASP. H & S will also be a part of the morning tool box talk with the crew each day. 3.3 Responsibilities of onsite personnel The responsibilities of onsite personnel include: All personnel going onsite must be thoroughly briefed on anticipated hazards and trained on equipment to be worn, safety procedures to be followed, emergency procedures, and communications. All personnel should avoid obvious vapor exposure, e.g., presence of strong and irritating or nauseating odors. Personnel shall be familiar with the physical characteristics of site conditions including: o Wind direction in relation to contamination zones o Accessibility to associates, equipment and vehicles o Communication o Operation zones o Site access o Nearest water sources o Rally and/or Assembly Areas (in the event of an evacuation) The number of personnel and equipment in the contamination area must be kept to a minimum, consistent with effective site operations. Procedures for leaving a contaminated area must be planned and implemented before going onsite in accordance with the HASP. All visitors to the job site must comply with the HASP procedures. Personal protection equipment may be modified for visitors depending on the situation. Modifications must be approved by the H & S. 4.0 Training and Medical Monitoring Requirements 4.1 Training Only authorized personnel with at least 40 hours of hazardous waste health and safety training (e.g. HAZWOPPER) meeting the requirements of OSHA (CFR 29 1910.120). As applicable, all personnel shall have the required annual HAZWOPER refresher training. All Site personnel will document training. Site-specific training in the use of equipment, as well as safety precautions, will be provided during the pre-field safety meeting. The training will be repeated for any worker not present for the initial training. H & S will be a part of daily, pre-shift tool box talks, which cover the Clean Harbors Hazardous Work Permit. Safety meetings will be conducted monthly at the Clean Harbors Facility to review various topics throughout the year. Written attendance and meeting records of all safety meetings will be maintained at the local branch. Page 4 4.2 Medical Monitoring Program General Provisions All personnel who enter hazardous waste/spill sites or have potential for exposure to hazardous materials therein must participate in a Medical Monitoring Program. The program is conducted by a medical professional. The purpose of the program is to identify any pre-existing illnesses or problems that would put an employee at unusual risk from certain exposures or inhibit the use of respirators, and to monitor and evaluate exposure-related events where workers are involved in handling hazardous materials. Foreman/Supervisor may consult with the Health and Safety Officer concerning the scope of work and known or anticipated chemical hazards associated with the project. 5.0 Description of Field Work Waste Handling Waste Collection of Phase III materials brought to repack area Sampling of Unknown Waste Streams Waste Identification/Characterization Pump/Transfer of Waste into proper shipping containers as needed Reports/Administrative/Shipment Paperwork Manifesting, Generation and Record Keeping of all Shipment Paperwork Profile Management, Completion and Recertification Chain of Custody for Samples/Analytical Waste Minimization, Recycling and Volume Reduction Waste Stream Volume Reporting Procurement Supply Management (Waste Containers, PPE, Sampling) 6.0 Physical Hazards Personnel should be aware of and act to minimize dangers associated with physical hazards typically encountered during onsite activities. These hazards include material handling, slippery surfaces, lifting and drum handling. Personnel will walk at all times. Running should be avoided as it greatly increases the probability of slips, trips, and falls. 6.1 Weather During extreme weather conditions, the Foreman/Supervisor shall use his best judgment and has the authority to stop fieldwork or dismiss workers for the day. Examples of conditions that may warrant work stoppage include tornado warnings, high winds, hail, flooding, snow, cold temps, and ice storms. Page 5 7.0 Personal Protective Equipment The level of employee protection for the work to be completed during site activities was determined by researching site conditions, reviewing planned activities, and identifying Site- specific physical and chemical hazards. 7.1 Selection of Personal Protective Equipment It is important that specified PPE protect against known and suspected Site hazards. Protective equipment is selected based on the types, concentrations, and routes of personal exposure that may be encountered. In situations where the types of materials and possibilities of contact are unknown or the hazards are not clearly identifiable, a more subjective determination must be made of the PPE required, and greater emphasis is placed in experience and sound safety practices. As discussed above, PPE for site workers will be based on Site history and on the activities to be performed there. The minimum level of PPE for set up/tare down, forklift operation and trailer loading will be Level D. Level D consists of the following: Work Uniform Inner gloves of Nitrile Outer gloves Cut/Impact Resistant Leather Gloves Safety glasses Hard Hat Steel Toe Leather Boots The minimum level of PPE during repacking, characterization and sampling procedures will be Level C. Level C consists of the following: Poly-coated Tychem suit w/hood and booties Inner gloves of Nitrile Outer gloves, chemical resistant Head/eye protection of full-face respirator with lined air Steel-toed rubber boots 8.0 Illumination Nighttime work activities are not anticipated. If nighttime (or low illumination levels) work is planned, adequate illumination will be provided to allow for full illumination in the work area. Page 6 9.0 Meteorological Monitoring Onsite ambient weather conditions (temperature, wind speed and direction, and relative humidity) may be monitored each day by the following methods; real-time internet weather locations and the National Weather Service (if a local station can provide data relevant to the Site). Real time internet weather information will be monitored at www.intellicast.com/LocalWeather/World/UnitedStates Or with an appropriate weather app on the Foreman/Supervisors phone. 10.0 Standard Safe Work Practices Standard safe work practices required onsite include: Eating, drinking, chewing gum or tobacco, smoking, or any other activity that increases the probability of hand-to-mouth transfer and ingestion of material is prohibited in any area designated as contaminated. Hands and face must be thoroughly washed upon leaving the work area. Whenever decontamination procedures for outer garments are in effect, the entire body should be thoroughly washed as soon as practical after leaving the contamination reduction zone. Contact with contaminated surfaces should be avoided. Whenever possible, do not walk through puddles, leachate, or discolored surfaces or lean, sit, or place equipment on drums, containers, or soil suspected of being contaminated. Medicine and alcohol can exacerbate the effects from exposure to toxic chemicals. Prescribed drugs shall not be taken by personnel on cleanup or response operations where the potential for absorption, inhalation, or ingestion of toxic substances exists, unless specifically approved by a qualified physician. Consumption of alcoholic beverages is prohibited. 10.1 General Rules of Conduct The following general rules of conduct are required for anyone working on this project: Alcohol, firearms, narcotics, and other contraband items are not permitted on the premises. Any violation of local, state, or federal laws, or conduct outside the generally accepted moral standards of the community is prohibited. Willfully damaging or destroying property, or removing records is forbidden. Misappropriation or unauthorized alteration of any record is forbidden. Gambling in any form, selling tickets or articles, taking orders, soliciting subscriptions, taking up collections, etc., is forbidden. Compliance with posted signs and notices is required. Boisterousness and noisy or offensive work habits, abusive language, or any oral, written, symbolic, or other communication that tends to disrupt work or morale of others is forbidden. Fighting or threatening bodily harm to another is forbidden. Defacing any property is forbidden. Page 7 Wearing shorts of any type and/or offensive logos, pictures, or phrases on clothing is forbidden. Shirts, shoes, and pants, slacks, or coverall-type garments will be worn at all times. People operating motor vehicles will obey all traffic regulations. 10.2 Injury/Illness Reporting Clean Harbors will report any and all incidents to the appropriate Thatcher contact and local Management. Appropriate actions will then be taken to ensure the employee or equipment is taken care of immediately. A report will be generated and can be made available to Thatcher upon request. An investigation of the incident will take place when it is warranted in a timely manner. Once an investigation is completed, any and all mitigation procedures or retraining will be implemented and relayed to the Thatcher contact. 11.0 Confined Spaces No confined space entry is anticipated. 12.0 Air Monitoring Air monitoring will be conducted during all characterization, sampling, transfer and repacking procedures. 13.0 Work Area Access Site visitors to the work area will be restricted to times when characterization, sampling, transfer and repacking procedures are not taking place. If conversations need to be conducted during these times, they can either be done outside of the work area, or work will be shut down and containers sealed closed prior to access to the site. If H & S believes that personnel are in danger or others may be in danger because of activities being conducted, he/she has the authority to immediately suspend work and may instruct personnel to evacuate the area. Examples of situations when this may happen are: Severe weather conditions such as thunder or lightening. Extreme winds. Site conditions have changed, for whatever reason, such that the HASP does not adequately address the current situation. Safety precautions being used are inadequate for the situation. Personnel including the contractor, subcontractors, or visitors, are or may be exposed to an immediate health hazard. 14.0 Decontamination All personnel that come into contact with potentially contaminated soil or water will be decontaminated to avoid cross contamination. Disposable equipment intended for one-time use will not be decontaminated but will be packaged for appropriate disposal. Decontamination will occur prior to and after each designated use of a piece of equipment or truck. Decontamination procedures, based on Level C protection, will consist of the following: Brushing off heavily soiled boot covers and PPE. Rinsing off all PPE while still on person in potable water rinse. Disposing of gloves and other disposable PPE in a designated container. Page 8 Washing hands and face. Washing with non-phosphate detergent and potable water wash, using a brush if necessary. Equipment will be decontaminated in the pre-designated area on plastic sheeting or other appropriate barrier or method, and clean bulky equipment will be stored on plastic sheeting in uncontaminated areas. 15.0 Sanitation Temporary sanitary facilities will be established or identified at the site for the duration of the work and will be serviced at regular intervals. Workers will complete the following personal hygiene procedures before leaving the work site: Toilet and hand washing facilities will be located on site or an alternate sanitary facility and their specific location identified prior to beginning work activities. Potable drinking water will be on site for use by site personnel. Personal protective equipment shall be kept clean and in good repair. Safety devices, including protective clothing worn by the employee, shall not be interchanged among the employees until properly cleaned. All equipment leaving the site will be free of gross hazardous and non-hazardous waste (i.e. mud and/or soil). Eating, drinking, chewing gum or tobacco, and smoking - are prohibited within the work area. Sitting or kneeling should be avoided in areas of known or suspected areas of contamination. Hands and face should be thoroughly washed when leaving the work area. Defective PPE should be repaired or replaced immediately. 16.0 Emergency Supplies The following emergency and first-aid items will be at the site in a designated area during all activities: A physician-approved, industrial first-aid kit with eyewash kit, one-way air valves for CPR, latex gloves, and safety glasses. A 10lb (min.) ABC-type fire extinguisher. Technicians will be trained and informed on the proper use of fire extinguishers. Potable water for drinking and washing. A spill-control kit containing absorbent materials and neutralizing agents. A plumbed eye and deluge shower is on site next to the entrance to the work area. Communications equipment immediately available to all employees. If cell phone coverage is available, at least one cell phone will be onsite. Page 9 17.0 Emergency Information All hazardous waste site activities present a risk to onsite personnel. During routine operations, risk is minimized by establishing good work practices, staying alert and using proper PPE. Unpredictable events such as physical injury, chemical exposure, or fire may occur and must be anticipated. During the site briefing that will be held, workers will be reminded of the provisions of the emergency response plan, communications systems, and evacuation routes. Thatcher Emergency Contacts Darren Bauer HR/EHS 801-888-6047 Dave Johnson 775-250-2930 Brandon Lowery 435-237-7245 Dave Lindsey EHS Manager 801-673-5532 Onsite Clean Harbor Emergency Contacts TBD TBD TBD Michael Sanders Operations Manager (801) 673-5373 Tim Armentrout Health and Safety Manager (303) 906-6731 If emergency contacts are not available, contact: Ambulance Emergency Dispatch 911 Fire Fire Department 911 Police Police Department 911 17.1 Site Resources First-aid equipment, telephones, restroom facilities, and water are available. Clean Harbors personnel working onsite communication and first-aid equipment available at the work area at all times. 17.2 Emergency Procedures All personnel with current First Aid and CPR training will be identified during morning tool box talks. Emergency procedures are to be followed if any of the following situations develop onsite: Any member of the field crew is involved in an accident or experiences any adverse effects or symptoms of exposure while onsite. A condition is discovered that suggests the existence of a situation more hazardous than anticipated. The following emergency procedures should be followed: Site work area entrance and exit routes will be planned and emergency escape routes lined out. If any member of the field team experiences any effects or symptoms of exposure while on the scene, the entire field crew will immediately halt work and act according. Page 10 For applicable site activities, wind indicators visible to all onsite personnel will be provided by Foreman/Supervisor to indicate possible routes for upwind escape. Identifying any conditions that would suggest a situation more hazardous than anticipated will result in the suspension of work until the situation has been evaluated appropriate mitigating steps have been relayed to the field team. If an accident occurs, the Foreman/Supervisor is to contact local Management and assist in complete an accident report form for submittal to the appropriate company official. If a member of the field crew suffers a personal injury, the Foreman/Supervisor will initiate Injury and Illness procedures. If a member of the field crew suffers a chemical exposure, the affected areas should be flushed immediately with copious amounts of clean water via the onsite safety eyewash/shower. While employee is being flushed in safety eyewash/shower, the Foreman/Supervisor will initiate Injury and Illness procedures. 18.0 Directions to Hospital The closest medical facilities: Rocky Mountain Care Clinic 1820 South 4088 West Salt Lake City, UT 84104 801-975-7799 801-746-4014 After Hours University of Utah Hospital 50 Medical Drive North Salt Lake City, UT 84132 801-581-2121 19.0 Authorized Changes to the Health and Safety Plan Any changes to this Health and Safety Plan must be approved in writing by the Health and Safety Manager and Operations Manager. The documentation will become part of the HASP. Page 11 ATTACHMENT A Facility Map with Evacuation Routes Page 12 ATTACHMENT B PLAN ACCEPATANCE FORM Health and Safety Plan INSTRUCTIONS: This form is to be completed by each person working or visiting at the project work site during the proposed activities. Project: Phase III Material Management Plan I represent that I have read and understand the contents of the above plan and agree to perform my work in accordance with it. Signed: Print Name: Company: Date: Page 13 ATTACHMENT C DIRECTIONS TO ROCKY MOUNTAIN CARE CLINIC FROM SITE: Page 14 ATTACHMENT D DIRECTIONS TO UNIVERSITY OF UTAH HOSPITAL APPENDIX F 90-Day Hazardous Waste Storage and Phase 3 Areas Inspection Forms APPENDIX G Area Disposition Review Form and Spreadsheet Phase 3 Thatcher Area Disposition Review Form Container identification number: Inventory Area: GPS: Container Condition and Immediate Action Determination: Labeled Yes (Y) or No (N) and description: Not Labeled Y or N and description: Container Location Description: Container Information: Size Type Color Quantity Material Generation Source: Date of transfer from area to NWSA or disposition area: Comments: Review Form Date (Accumulation Date): 1Disposition (Recycle or Disposal) Label Date if Different form above: 1Containers will be labeled with the inventory date as the Phase 3 Accumulation Date, unless the actual accumulation date can be determined. If the actual accumulation date is known, the container will be labeled with both the actual accumulation date and the Phase 3 Accumulation Date. Spreadsheet Items To-Be-Determined: SDS, Hazard Determination, Hazardous Characteristics, CCP and Secondary Material Determinations, Repack and Comments (Include: legitimate use/re-use/re-working scenario and DWMRC approval date) Page _______ of _______ Phase 3 AREA DISPOSITION REVIEW SPREADSHEET Area Disposition Review Spreadsheet The Phase 3 area disposition review spreadsheet was prepared for tracking container information as follows in Table 1. Table 1 Area Disposition Review Spreadsheet Column Description A Introduction top of worksheet A Location A Area location/GPS A Inventory date Data Entry A Description B Labeled C Unlabeled D SDS E Non-hazardous (NH) or Hazardous (H) F Hazardous Characteristics G Hazardous Determination a. Generator Knowledge b. Analyses H Container size, type, and color I Quantity J - M Columns J through M Header - Disposition J CCP Date K CCP Tracking No. (Lot or Assigned) L Secondary Material Date M Secondary Material Tracking No. N & O Columns N and O Header - Dispose N Disposal Label Date O Disposal No. P Repack Q Comment Include: legitimate use/re-use/re-working scenario and DWMRC approval date WICP #SDS Composition %Solid Liquid pH Flash Point Specific Gravity Density DOT Comments 1531 SDS Ammonium Phosphate 100 x 8 1.62 NA 1524 SDS Calcium Polysulfide Calcium Polysulfide 30 red 11.3-11.5 1.28 NA Water 70 1517 SDS (4)Excel Final Oxy Sulfuric Acid 40-50 red 0.75 1.71 8 NA1760, Compounds, cleaning liquid, 8, PGII Hydrogen Peroxide 5.0-10 Methanesulphonic Acid 5.0-10 ATMP Acid .Aminotris(methylenephosphonic acid), [Bis(phosphonomethyl)amino]m ethylphosphonic acid <1 Water 40-60 It is necessary to have 100% composition and document some general information for profiling the materail. Some previous P3 Batch 1 examples are provided below. APPENDIX H Field Screening Form Phase 3 Field Screening Form THATCHER COMPANY Nothwest Storage Area Date Container ID# Material Amount Liq (L) Solid (S) Sludge (SL) Material Color pH O2 %CO % H2S %VOC (ppm)LEL %HCN (PPM) Iodine, Bromine, Chlorine Oxidizer Fluoride Water Miscibility/Temp after test Y or N Y or N Y or N Contains Cyanide Contains Sulfide Ammonia Unif orm Ununiform % Free Liquids % Settled Solids % Total Suspende d Solids Phases Top %/Color Phases Middle %/Color Phases Bottom %/Color Y or N Y or N Y or N Material is compatible with container type: Y or N 1Wastewater/Nonwastewater Definition: Wastewater (WW): Wastes that contain less than 1% by weight total organic carbon (TOC) and less than 1% by weight total suspended solids (TSS). Specific Gravity/Density: < 0.8 (Gasoline), 0.8-1.0 (Ethanol), 1.0 (Water), 1.0-1.2 (Antifreeze), >1.2 (Methylene Chloride) Contents Description Comments (include container label description): Other Comments: Field Monitoring Comments: Peroxide: 0, 0-2, 2-5, 5-10, >10 or ppm ______ Viscosity (Centipoise): 1-100 (Water), 101-500 (Motor Oil), 501-10,000 (Molasses), > 10,000 Physical State: Solid without Free Liquid, Powder, Monolithic Solid, Liquid with No Solids, Liquid/Solid Mixture, Sludge, Gas/Aerosol Halogenated Hydrocarbon (PPM) (e.g., oils (Chlor- Dtect)) Container Information [Type (metal (M), plastic (P), fiber board (F) or other] Labeled Yes (Y) or No (N) If yes enter information in Comments Section Size: Color: Type: Field Monitoring: Circle Y (yes), N (no) or enter monitoring data. Weather Conditions and Temperature 1Underlying Hazardous Constituent UHC: Circle Wastewater/Nonwastewater Determination Wastewater Nonwastewater Page ___ of ___ APPENDIX I Repackaging Form Phase 3 Container Repackaging Form Date:Container identification number: Container Location: Was the container number updated? If yes, list the updated number: Container Information: Size Type Color Comments: Phase 3 Container Repackaging Form Date:Container identification number: Container Location: Was the container number updated? If yes, list the updated number: Container Information: Size Type Color Comments: Note: Form is set up for two containers per page. APPENDIX J Container Tracking and Disposal Spreadsheets P3MMP Container Tracking and Disposal Spreadsheets The WICP spreadsheets have been updated for P3 MMP container tracking, accumulation date, sample analyses tracking, characterization/classification (by analyses or Safety Data Sheet), recycling designation, and disposal tracking. The P3MMP Container Tracking and Disposal Spreadsheets workbook contains the following worksheets. Table 1 Worksheet 1 • Worksheet 1. Container Tracking, Material Screening, Category Designation Table 2 Worksheets 2 Through 5 • Worksheet 2. Category 1 pH: <2 or >12.5 (Corrosives) • Worksheet 3. Category 2 pH: >2 or <12.5 • Worksheet 4. Category 3 Oxidizer, Peroxide, Fluoride, Iodine, Bromine, Chlorine, Ammonia • Worksheet 5. Category 4: Oil < or >10003 ppm Halogenated Hydrocarbons Table 3 Worksheets 6 Through 9 • Worksheet 6. Peroxide Liquids • Worksheet 7. Peroxide Solids • Worksheet 8. Ammonia Solids • Worksheet 9. Oxidizer Solids Table 1 P3MMP Disposal Spreadsheets (Worksheet 1) Worksheet 1 Column Headers Row 2 Descriptions Row 3 A through D Header: Column A: Container Tracking and/or Sample Number, and Description Column B: Analyze (A), Safety Data Sheet (S), or Recycle (R Column C: 1Accumulation Date Column D: Container Description - For unidentified material include a general description and for material identified by Safety Data Sheet (SDS) include product name. A Phase 3 containers will be numbered as follows Area (A), Area 1 (01), and container number (001) (e.g., A-01-001). Container identification number is used to track the container management and/or sampling/analyses, SDS, and/or recycling data. Containers designated for recycling are tracked on the disposition spreadsheet. B • “A” is entered for unidentified materials that required analyses. • “S” is entered for known materials identified by product name and SDS. • “R” is entered for materials designated for recycling. C Containers will be labeled with the inventory date as the Phase 3 Accumulation Date unless the actual accumulation date can be determined. If the actual ac cumulation date is known, the container will be labeled with both the actual accumulation date and the Phase 3 Accumulation Date. D Container Description - For unknown material a general description is included and for material identified by Safety Data Sheet (SDS) the product name is included. E through G Header CTF Lab Data E CTF Lab ID# F CTF Lab Data Entry Personnel (Initial) Worksheet 1 Column Headers Row 2 Descriptions Row 3 G Lab pH • The category is assigned based on the lab pH. H through N Header: Field Screening Data (Clean Harbors enters screening data and Stantec completes QA) Field screening data is used to make category determinations. H Wastewater/Nonwastewater Determination: Wastewater (WW): Wastes that contain less than 1% by weight total organic carbon (TOC) and less than 1% by weight total suspended solids (TSS). Lab will make methanol analyses determination: TCLP UHC methanol (nonwastewater) or UHC Total VOAs Methanol (wastewater). I Field pH If lab pH changes the field screening category, field pH shall be replaced wit h lab pH (red text). This column links to the category equation and must be update for applying the correct category. J Oxidizer, Peroxide, Fluoride, Iodine, Bromine, Chlorine, Ammonia Yes (Y) or No (N) K Oil >1000 ppm HH. Yes (Y) or No (N) < 1000 ppm Halogenated Hydrocarbons is managed as used oil L Cyanide? Yes(Y) or No (N) M Sulfide? Yes(Y) or No (N) N VOC (ppm) Columns O through R Header: Category Determinations Yes (Y) or No (N) O Category 1: pH: <2 or >12.5 (Corrosives) P Category 2: pH: >2 or <12.5 Q Category 3: Oxidizer, Peroxide, Fluoride, Iodine, Bromine, Chlorine, Ammonia R Category 4: Oil < or >1000 ppm Halogenated Hydrocarbons. Columns S through U Header: Characterization\Classification, Review\Determination, and Date. S Hazardous Waste (HW)) T Non-Hazardous (NH) U Date Column V Header: Disposal Profile Number V Green highlight is approved profile and un-highlighted is not approved. Column W Header: Phase 3 Shipment W Shipment Number and Manifest Number/Date Containers are tracked by shipment, manifest, and profile numbers. The manifest line items correlate to profile numbers assigned to the containers. The P3MMP worksheets 2 through 5 are field screening and/or analyses data spreadsheets Table 2. Spreadsheets are set up for analyses data entry. Stantec reviews the analyses and determines if the material is a characteristic or listed hazardous waste and/or non-hazardous material. This information is used to determine if there is an existing disposal profile of if a new profile is necessary. Disposal profiles numbers are entered at the bottom of the worksheet for each container. The profile number is transferred to worksheet 1 by Stantec after the profile is approved by the disposal facility. Table 2 P3MMP Disposal Spreadsheets (Worksheets 2 Through 5 Analyses) Worksheets 2 through 5 Category pH Flash Point (less than or greater than 1400F TCLP RCRA 8 Metals and UHC Nickel TCLP Volatile and Semi- Volatile and UHC methanol (nonwastewater) UHC Total VOAs Methanol (wastewater) and Xylene Halogen ated Oil Content < or >1000 ppm 2 Category 1 pH <2 or >12.5 (Corrosives) -Acid pH <2 -Basic pH >12.5 Yes Yes Yes Yes No 3 Category 2 pH >2 or <12.5 >2 or <12.5 Yes Yes Yes Yes No 4 Category 4 Oxidizer, Peroxide, Fluoride, Iodine, Bromine, Chlorine, Ammonia -Acid pH <2 -Basic pH >12.5 ->2 or <12.5 Yes Yes Yes Yes No 5 Category 5: Oil < or >10003 ppm Halogenated Hydrocarbons. -Acid pH <2 -Basic pH >12.5 ->2 or <12.5 Yes Yes Yes or No1 Yes or No1 Yes 1Yes if Halogenated Oil Content >1000 ppm The P3MMP worksheet 4 is Category 3 field monitoring and additional parameter worksheets 6 through 9 analyses data spreadsheets Table 3. Category 4 Worksheet 4 Field Monitoring and additional Category 4 field screening parameters (worksheets 6 through 9) identified by the characterization team are listed in the following table. Unknown materials identified as containing oxidizers, peroxides, and/or ammonia will be analyzed for additional characterization parameters, determinations, profiling, and disposal. Table 3 Disposal Spreadsheets (Worksheets 6 through 9) Category 4 Worksheet 4 Field Monitoring Additional Parameters Worksheets 6 through 9 Comments Oxidizer and Peroxide Worksheet 6 Peroxide Liquids Active Oxygen (AO)1 and/or Inductively Coupled Plasma (ICP) ICP is used to identify material components for disposal profile if AO is >10 ppm. Worksheet 7 Peroxide Solids AO1, X-Ray Diffraction (XRD) Qualitative analysis, Energy Dispersive X-Ray (EDX) analysis XRD Qualitative and EDX analyses are used to identify material components for disposal profile. Worksheet 8 Ammonia Solids AO1, EDX, Ammonia mg/kg, Total Nitrate as N mg/L Ammonia and nitrate concentrations were evaluated to determine oxidizing potential Worksheet 9 Oxidizer Solids AO1, XRD Qualitative, and EDX Fluoride NA Iodine NA Bromine NA Chlorine NA Ammonia See Worksheet 8 above 1AO <10 ppm is not considered to have oxidizing potential. AO >10 ppm is managed as an oxidizer. Materials with active oxygen was < 10 containing other oxidizing potential constituents (e.g., nitrate compounds) were identified as oxidizers. An oxidizer yes or no column was added for making the oxidizer determinations. CTF Lab pH Disposal Profile Number Phase3: Shipment Container Tracking and/or Sample Number Analyze (A), SDS (S), or Recycle (R)1Accumulaiton Date Container Description CTF Lab ID# CTF Lab Data Entry Personnel (Initial)Lab pH 2Wastewater? Yes (Y) or No (N)Field pH Oxidizer, Peroxide, Fluoride, Iodine, Bromine, Chlorine, Ammonia Yes (Y) or No (N) Oil >1000 ppm HH. Yes (Y) or No (N) Cyanide? Yes(Y) or No (N) Sulfide? Yes(Y) or No (N) VOC (ppm)2. Cat 1 pH <2 or >12.5 (Corrosives) 3. Category 2: pH: >2 or <12.5 4. Cat 3: Oxidizer, Peroxide, Fluoride, Iodine, Bromine, Chlorine, Ammonia 5. Category 4: Oil < or >1000 ppm Halogenated Hydrocarbons Hazardous Waste (HW)) Non-Hazardous (NH) Date Green highlight is approved profile and un- highlighted is not approved. Shipment Number and Manifest Number/Date A-01-001 N N N N A-01-002 N N N N A-01-003 N N N N A-01-004 N N N N A-01-005 N N N N 1. Container and Analyses Tracking Characterization\Classification, Review\Determination, and Date. Notes 1. Phase 3 containers will be numbered as follows Area (A), Area 1 (01), and container number (001) (e.g., A-01-001) column A. 2. Stantec and Thatcher determine if containers require analyses (A), are characterized by safety data sheets (S), or are recyclable (R) in column B. 3. Clean Harbors enters the accumulation date column C, container description column D, and field monitoring data is entered in columns H-N. 4. Lab enters lab ID# column E, data entry personnel initial entry column F, and analyzes\enters pH in column H. 5. Data auto populates in the Category columns for identifying remaining off-site analyses. 6. Off-site analyses is entered in Category worksheets (i.e., xls lab data). 7. Characterization\Classification Review\Determination (Hazardous Waste (HW) or Non-Hazardous (NH)) and Date. 8. Disposal Profile Number - Green highlight is approved profile and un-highlighted is not approved. 9. Phase 3 Shipment - Shipment Number and Manifest Number/Date 1Containers will be labeled with the inventory date as the Phase 3 Accumulation Date unless the actual accumulation date can be determined. If the actual accumulation date is known, the container will be labeled with both the actual accumulation date and the Phase 3 Accumulation Date. Category Determinations Category 1 pH <2 or >12.5 (Corrosives), Category 2 pH >2 and <12.5, Category 3 Oxidizer, Peroxide, Fluoride, Iodine, Bromine, Chlorine, Ammonia Analyses: 1. pH, 2. TCLP RCRA 8 Metals and UHC Nickel, 3. Flash Point, 4. TCLP VOAs/Semi-VOAs, UHC methanol (nonwastewater), 5. UHC Total VOAs Methanol (wastewater) and Xylene, 6. Total sulfide or cyanide if detected from field monitoring Yes (Y) or No (N) Category 4 Oil < or >1000 ppm Halogenated Hydrocarbons Analyses: 1. TCLP RCRA 8 Metals and UHC Nickel, 2. Flash Point, 3. TCLP VOAs/Semi-VOAs UHC methanol (nonwastewater), 4. UHC Total VOAs Methanol (wastewater) and Xylene. Column A: Container Tracking and/or Sample Number Column B: Analyze (A), Safety Data Sheet (S), or Recycle (R Column C: 1Accumulation Date Column D: Container Description - For unknown material include a general description and for material identified by Safety Data Sheet (SDS) include product name.CTF Lab Data Field Screening Data (Clean Harbors enters screening data and Stantec completes QA) 2Wastewater/Nonwastewater Definition: Wastewater (WW): Wastes that contain less than 1% by weight total organic carbon (TOC) and less than 1% by weight total suspended solids (TSS). Lab methanol analyses determination: TCLP UHC methanol (nonwastewater) or UHC Total VOAs Methanol (wastewater). 2. Cat 1-<2 or >12.5 Corrosive A-01-001 A-01-002 A-01-003 Analyses RCRA Waste Code Reg Limit Off-site Lab 1. pH <2 (Corrosive Acid)D002 2. pH >12.5 (Corrosive Base)D002 4. Flash Point (less than or greater than 140 d D001 140 A-01-001 A-01-002 A-01-003 Reg Level Reg Level Reg Level 1. TCLP Analyses - RCRA 8 Metals RCRA Waste Code Reg Limit a. Arsenic (ppm; mg/L)D004 5.0 b. Barium (ppm; mg/L)D005 100.0 c. Cadmium (ppm; mg/L)D006 1.0 d. Chromium (ppm; mg/L)D007 5.0 e. Lead (ppm; mg/L)D008 5.0 f. Mercury (ppm; mg/L)D009 0.2 g. Selenium (ppm; mg/L)D010 1.0 h. Silver (ppm; mg/L)D011 5.0 I. UHC Nickel UHC 11.0 2. Total sulfide or cyanide if detected from field monitoring* a. Cyanide (ppm; mg/L) b. Sulfide (ppm; mg/L) *Note: If cyanide or sulfide are present in a sample container, a D003 waste code determination will be necessary. Sample/ Container Number: Sample/ Container Number: 2. Cat 1-<2 or >12.5 Organic A-01-001 A-01-002 A-01-003 1. TCLP Analyses - Volatile Constituent for Organic Samples and UHC Methanol (Nonwastewater) RCRA TC Waste Code TCLP Limit Reg Level Reg Level Reg Level Benzene D018 0.5 Carbon Tetrachloride D019 0.5 Chlorobenzene D021 100 Chloroform D022 6 1,2-Dichloroethane D028 0.5 1,1-Dichloroethylene D029 0.7 Methyl Ethyl Ketone (2-Butanone)D035 200 Tetrachloroethylene (Perchloroethylene)D039 0.7 Trichloroethylene D040 0.5 Vinyl Chloride D043 0.2 1P or 1,4-Dichlorobenzene D027 7.5 Methanol (UHC Nonwastewater)UHC 0.75 1. UHC Total VOAs Methanol (wastewater) and Xylene Mg/L Methanol (wastewater)UHC 5.6 Xylene (Nonwastewater)UHC 30 Xylene (wastewater)UHC 0.32 1543 1544 1545 1. TCLP Analyses - Semi-Volatile Constituent for Organic Samples RCRA TC Waste Code TCLP Level Reg Level Reg Level Reg Level O-Cresol (2-Methylphenol)D023 200 M-Cresol (3&4-Methylphenol)D024 200 P-Cresol (3&4-Methylphenol)D025 200 Cresol (*Total O-M-P Cresol D026 200 2,4-Dinitrotoluene D030 0.13 Hexachlorobenzene D032 0.13 Hexachloro-1,3-Butadiene D033 0.5 Hexachloroethane D034 3 Nitrobenzene D036 2 Pentachlorophenol D037 100 Pyridine D038 5 2,4,5-Trichlorophenol D041 400 2,4,6-Trichlorophenol D042 2 Sample/ Container Number: Sample/ Container Number: 3. Cat 2 pH>2or<12.5 1540 1541 A-01-001 A-01-002 Analyses RCRA Waste Code Off-site Lab 1. pH >2 and <12.5 4.5 3 2. Flash Point (less than or greater than 140 deg F)D001 140 >158 >158 1540 1541 A-01-001 A-01-002 Reg Level Reg Level Reg Level Reg Level 1. TCLP Analyses - RCRA 8 Metals RCRA Waste Code Reg Limit a. Arsenic (ppm; mg/L)D004 5.0 < 0.200 < 0.200 b. Barium (ppm; mg/L)D005 100.0 < 3.00 < 3.00 c. Cadmium (ppm; mg/L)D006 1.0 < 0.0350 < 0.0350 d. Chromium (ppm; mg/L)D007 5.0 < 2.00 < 2.00 e. Lead (ppm; mg/L)D008 5.0 < 2.00 < 2.00 f. Mercury (ppm; mg/L)D009 0.2 < 0.100 < 0.0100 g. Selenium (ppm; mg/L)D010 1.0 < 0.100 < 0.100 h. Silver (ppm; mg/L)D011 5.0 < 0.100 < 0.100 i. UHC Nickel UHC 11.0 2. Total sulfide or cyanide if detected from field monitoring* a. Cyanide (ppm; mg/L) b. Sulfide (ppm; mg/L) *Note: If cyanide or sulfide are present in a sample container, a D003 waste code determination will be necessary. 1540 1541 A-01-001 A-01-002 1. TCLP Analyses - Volatile Constituent for Organic Samples and UHC Methanol (Nonwastewater) RCRA TC Waste Code TCLP Limit Reg Level Reg Level Reg Level Reg Level Benzene D018 0.5 < 10.0 < 1.00 Carbon Tetrachloride D019 0.5 < 20.0 < 2.00 Chlorobenzene D021 100 < 20.0 < 2.00 Chloroform D022 6 < 20.0 < 2.00 1,2-Dichloroethane D028 0.5 < 20.0 < 2.00 1,1-Dichloroethylene D029 0.7 < 20.0 < 2.00 Methyl Ethyl Ketone (2-Butanone)D035 200 < 100 < 10.0 Tetrachloroethylene (Perchloroethylene)D039 0.7 < 20.0 < 2.00 Trichloroethylene D040 0.5 < 20.0 < 2.00 Vinyl Chloride D043 0.2 < 10.0 < 1.00 1P or 1,4-Dichlorobenzene D027 7.5 < 20.0 < 2.00 Methanol (UHC Nonwastewater)UHC 0.75 1. UHC Total VOAs Methanol (wastewater) and Xylene Mg/L Methanol (wastewater)UHC 5.6 Xylene (Nonwastewater)UHC 30 Xylene (wastewater)UHC 0.32 Sample/ Container Number: Sample/ Container Number: Sample/ Container Number: 3. Cat 3 pH>2or<12.5 Organic 1540 1541 A-01-001 A-01-002 1. TCLP Analyses - Semi-Volatile Constituent for Organic Samples RCRA TC Waste Code TCLP Level Reg Level Reg Level Reg Level Reg Level O-Cresol (2-Methylphenol)D023 200 < 10.0 < 10.0 M-Cresol (3&4-Methylphenol)D024 200 < 10.0 < 10.0 P-Cresol (3&4-Methylphenol)D025 200 < 10.0 < 10.0 Cresol (*Total O-M-P Cresol D026 200 2,4-Dinitrotoluene D030 0.13 < 10.0 < 10.0 Hexachlorobenzene D032 0.13 < 10.0 < 10.0 Hexachloro-1,3-Butadiene D033 0.5 < 10.0 < 10.0 Hexachloroethane D034 3 < 10.0 < 10.0 Nitrobenzene D036 2 < 10.0 < 10.0 Pentachlorophenol D037 100 < 10.0 < 10.0 Pyridine D038 5 < 10.0 < 10.0 2,4,5-Trichlorophenol D041 400 < 10.0 < 10.0 2,4,6-Trichlorophenol D042 2 < 10.0 < 10.0 Sample/ Container Number: 4. Cat 3 Oxidizers Etc 1542 A-01-001 A-01-002 Analyses RCRA Waste Code Off-site Lab 1. pH <2 (Corrosive Acid)D002 < 1.00 2. pH >12.5 (Corrosive Base)D002 < 1.00 3. pH >2 and <12.5 < 1.00 4. Characterization of Sample Container*: a. Oxidizer Y/N b. Peroxide Y/N c. Fluoride Y/N d. Iodine Y/N e. Bromine Y/N f. Chlorine Y/N g. Ammonia Y/N Y 5. Flash Point (less than or greater than 140 deg F)D001 140 N/A *Note: If sample contains any material type described by a - g, above, then a waste code determination will be necessary. 1542 A-01-001 A-01-002 Reg Level Reg Level Reg Level 1. TCLP Analyses - RCRA 8 Metals RCRA Waste Code Reg Limit a. Arsenic (ppm; mg/L)D004 5.0 < 0.200 b. Barium (ppm; mg/L)D005 100.0 < 3.00 c. Cadmium (ppm; mg/L)D006 1.0 < 0.0350 d. Chromium (ppm; mg/L)D007 5.0 26.50 e. Lead (ppm; mg/L)D008 5.0 < 2.00 f. Mercury (ppm; mg/L)D009 0.2 0.02 g. Selenium (ppm; mg/L)D010 1.0 < 0.100 h. Silver (ppm; mg/L)D011 5.0 < 0.100 i. UHC Nickel UHC 11.0 2. Total sulfide or cyanide if detected from field monitoring* a. Cyanide (ppm; mg/L) b. Sulfide (ppm; mg/L) *Note: If cyanide or sulfide are present in a sample container, a D003 waste code determination will be necessary. Sample/ Container Number: Sample/ Container Number: Regulatory Analyses - Enter Sam 4. Cat 4 Oxidizers Etc Organic 1542 A-01-001 A-01-002 1. TCLP Analyses - Volatile Constituent for Organic Samples and UHC Methanol (Nonwastewater) RCRA TC Waste Code TCLP Limit Reg Level Reg Level Reg Level Benzene D018 0.5 < 1.00 Carbon Tetrachloride D019 0.5 < 2.00 Chlorobenzene D021 100 < 2.00 Chloroform D022 6 < 2.00 1,2-Dichloroethane D028 0.5 < 2.00 1,1-Dichloroethylene D029 0.7 < 2.00 Methyl Ethyl Ketone (2-Butanone)D035 200 < 10.0 Tetrachloroethylene (Perchloroethylene)D039 0.7 < 2.00 Trichloroethylene D040 0.5 < 2.00 Vinyl Chloride D043 0.2 < 1.00 1P or 1,4-Dichlorobenzene D027 7.5 < 2.00 Methanol (UHC Nonwastewater)UHC 0.75 1. UHC Total VOAs Methanol (wastewater) and Xylene Mg/L Methanol (wastewater)UHC 5.6 Xylene (Nonwastewater)UHC 30 Xylene (wastewater)UHC 0.32 1542 A-01-001 A-01-002 1. TCLP Analyses - Semi-Volatile Constituent for Organic Samples RCRA TC Waste Code TCLP Level Reg Level Reg Level Reg Level O-Cresol (2-Methylphenol)D023 200 < 40.0 M-Cresol (3&4-Methylphenol)D024 200 < 40.0 P-Cresol (3&4-Methylphenol)D025 200 < 40.0 Cresol (*Total O-M-P Cresol D026 200 2,4-Dinitrotoluene D030 0.13 < 40.0 Hexachlorobenzene D032 0.13 < 40.0 Hexachloro-1,3-Butadiene D033 0.5 < 40.0 Hexachloroethane D034 3 < 40.0 Nitrobenzene D036 2 < 40.0 Pentachlorophenol D037 100 < 40.0 Pyridine D038 5 < 40.0 2,4,5-Trichlorophenol D041 400 < 40.0 2,4,6-Trichlorophenol D042 2 < 40.0 1. Ammonia and Nitrate Analyses RCRA Waste Code Reporting Limit (ppm) a. Ammonia as N b. Nitrate/Nitrite as N Sample/ Container Number: Regulatory Analyses - Enter Sam Regulatory Analyses - Enter Sam Sample/ Container Number: 5. Cat 4 Oil Halogenated HCs A-01-001 A-01-002 Analyses RCRA Waste Code Reg Limit Off-site Lab 1. pH <2 (Corrosive Acid)D002 Y/N 2. pH >12.5 (Corrosive Base)D002 Y/N 3. pH >2 and <12.5 Y/N 4. Halogenated Oil Content >1000 ppm 1000 5. Flash Point (less than or greater than 140 deg F)D001 140 A-01-001 A-01-002 Reg Level Reg Level 1. TCLP Analyses - RCRA 8 Metals RCRA Waste Code Reg Limit a. Arsenic (ppm; mg/L)D004 5.0 b. Barium (ppm; mg/L)D005 100.0 c. Cadmium (ppm; mg/L)D006 1.0 d. Chromium (ppm; mg/L)D007 5.0 e. Lead (ppm; mg/L)D008 5.0 f. Mercury (ppm; mg/L)D009 0.2 g. Selenium (ppm; mg/L)D010 1.0 h. Silver (ppm; mg/L)D011 5.0 i. UHC Nickel UHC 11.0 A-01-001 A-01-002 1. TCLP Analyses - Volatile Constituent for Organic Samples and UHC Methanol (Nonwastewater) RCRA TC Waste Code TCLP Limit Reg Level Reg Level Benzene D018 0.5 Carbon Tetrachloride D019 0.5 Chlorobenzene D021 100 Chloroform D022 6 1,2-Dichloroethane D028 0.5 1,1-Dichloroethylene D029 0.7 Methyl Ethyl Ketone (2-Butanone)D035 200 Tetrachloroethylene (Perchloroethylene)D039 0.7 Trichloroethylene D040 0.5 Vinyl Chloride D043 0.2 Methanol (UHC Nonwastewater)UHC 0.75 1. UHC Total VOAs Methanol (wastewater) and Xylene Mg/L Methanol (wastewater)UHC 5.6 Xylene (Nonwastewater)UHC 30 Xylene (wastewater)UHC 0.32 Sample/ Container Number: Sample/ Container Number: Sample/ Container Number: 5. Cat 5 Oil Halogenated HCs A-01-001 A-01-002 1. TCLP Analyses - Semi-Volatile Constituent for Organic Samples RCRA TC Waste Code TCLP Level Reg Level Reg Level O-Cresol (2-Methylphenol)D023 200 M-Cresol (3&4-Methylphenol)D024 200 P-Cresol (3&4-Methylphenol)D025 200 Cresol (*Total O-M-P Cresol (Cresylic Acid) D026 200 1P or 1,4-Dichlorobenzene D027 7.5 2,4-Dinitrotoluene D030 0.13 Hexachlorobenzene D032 0.13 Hexachloro-1,3-Butadiene D033 0.5 Hexachloroethane D034 3 Nitrobenzene D036 2 Pentachlorophenol D037 100 Pyridine D038 5 2,4,5-Trichlorophenol D041 400 2,4,6-Trichlorophenol D032 2 Sample/ Container Number: 6. Peroxide Liquids Sample/ Container Number: pH Active Oxygen (ppm) Oxidizer (Y/N) ICP Analyses < D.L.mg/Kg Ag (Silver)NA Al (Aluminum) As (Arsenic) Au (Gold) B (Boron) Ba (Barium) Be (Beryllium) Bi (Bismuth) Ca (Calcium) Cd (Cadmium) Co (Cobalt) Cr Cu (Copper) Fe (Iron) Ga (Gallium) Hg (Mercury) K (Potassium) Li (Lithium) Mg (Magnesium) Mn (Manganese) Mo (Molybdenum) Na (Sodium) Ni (Nickel) P (Phosphorus) Pb (Lead) Pd (Palladium) Pt (Platinum) S (Sulfur) Sb (Antimony) Se (Selenium) Si (Silicon) Sn (Tin) Sr (Strontium) Th (Thorium) Ti (Titanium) Tl (Thallium) U (Uranium) V (Vanadium) W (Tungsten) Zn (Zinc) Zr (Zirconium) 7. PeroxideSolids Sample/ Container Number: pH Active Oxygen (ppm) XRD Qualitative Oxidizer (Y/N) EDX Analyses %%% Al (Aluminum) C (Carbon) Ca (Calcium) Cl (Chorine) Cu (Copper) Fe (Iron) I (Iodine) K (Potassium) Mg (Magnesium) N (Nitrogen) Na (Sodium) O (Oxygen) P (Phosphorus) S (Sulfur) Si (Silicon) Ti (Titanium) Note: "-" indicates that the lab analysis sheet did not provide a value for the analyte. 8. AmmoniaSolids Sample/ Container Number: pH Active Oxygen (ppm) Ammonia (mg/Kg) Total Nitrate as N (mg/L) XRD Qualitative Oxidizer (Y/N) EDX Analyses %% Al (Aluminum) C (Carbon) Ca (Calcium) Cl (Chorine) Fe (Iron) K (Potassium) Mg (Magnesium) Na (Sodium) O (Oxygen) P (Phosphorus) S (Sulfur) Si (Silicon) Ti (Titanium) Note: "-" indicates that the lab analysis sheet did not provide a value for the analyte. 9. Oxidizer Solids Sample/ Container Number: pH Active Oxygen (ppm) XRD Qualitative Oxidizer (Y/N) EDX Analyses %%%%% Al (Aluminum) C (Carbon) Ca (Calcium) Cl (Chlorine) Fe (Iron) I (Iodine) K (Potassium) Mg (Magnesium) Na (Sodium) O (Oxygen) S (Sulfur) Si (Silicon) Note: "-" indicates that the lab analysis sheet did not provide a value for the analyte. 1. 698 requires review with Thatcher to determine identification (i.e., lab and or process knowlegde). APPENDIX K Disposition Tracking Spreadsheets PHASE 3 DISPOSITION SPREADSHEET Thatcher’s disposition spreadsheets have been updated for P3MMP container use or reuse (recycling) or disposal tracking as follows in Table 1. Table 1 Disposition Spreadsheet Worksheet Column Description A "Disposition ID" is used for tracking each container. -Each container is labeled with the tracking number. B "Branch Location" UT C “Date container added to the system” -This date will auto populate for tracking P3 CCPs and secondary material (not CCP). D "Flow Status " Management Status: -Assigned In Use -Complete -Okay to Sell "As Is" -Pending -Samples Needed -Waiting on Final Assignment -Waiting on Lab Results E “Labeled As” F “Safety Data Sheet (SDS) Y (Yes) N (No)” If column E has a product name an SDS is typically available. G “Product Number (PNUM)” H “Quantity” I “Quantity Used” J “Quantity Remaining” K “Location In Warehouse” L “Batch # (Batch Lot #) to Use In” M, N, and O M.“Container Size” N.“Unit of Measure” O.“Container Type” (e.g., tote, drum) P “Liquid, Solid, or Sludge (Semi-solid material)” Q “Control Equipment Sludge” RCRA defined "sludge" (i.e., air pollution control or other pollution control whether it is a solid, semi-solid, or liquid) R “Lot #” -Lot # that this batch originated from S “Reason for Disposition” T “Commercial Chemical Product: Yes (Y) No (N)” Examples of CCPs include: -Excess material from processing. -Returned materials. -Off-spec materials (those which would have otherwise been a CCP if they had met specifications) U “Final Disposition Determination Date of CPP” V “Secondary Material: Yes (Y) No (N)” Examples of secondary materials include: -Scrubber Material -Baghouse Material -Rinse Water W “Final Disposition Date of Secondary Material” X “Non-Hazardous, Hazardous Determinations” Y “Comments” Z “Created By” AA “Lab Tests Completed By” AB “Lab Recommendation Notes” AC “Lab Assignment” AD “Products to Use in Rework” AE “Retest Date” AF “Disposal Determination Date (Generation Date)” AG “Tech Services VP Decision” AH “Tech Services VP Notes” AI “Item Type (Program Auto Generated Column)” AJ “Path (Program Auto Generated Column)” Phase 3 Thatcher Disposition Spreadsheet Disposition ID Branch Location Date Container Added to System Flow Status Labeled As Safety Data Sheet (SDS) Y (Yes) N (No)PNUM Quantity Quantity Used Quantity Remaining Location in Warehouse Batch# to Use In Phase 3 Thatcher Disposition Spreadsheet Container Size Unit of Measure Container Type Liquid, Solid, or Sludge (Semi-solid material) Air Pollution Control Equipment Sludge (solid, semi- solid, or liquid)Lot# Reason for Disposition Commercial Chemical Product (CPP): Yes (Y) or No (N) Final Disposition Determination Date of CPP Secondary Material: Yes (Y) or No (N) Phase 3 Thatcher Disposition Spreadsheet Final Disposition Date of Secondary Material Non-Hazardous, Hazardous Determinations Comments Created By Lab Tests Completed By Lab Recommendation Notes Lab Assignment Products to use in Rework Retest Date Phase 3 Thatcher Disposition Spreadsheet Disposal Determination Date (Generation Date) Tech Services VP Decision Tech Services VP Notes Item Type Path APPENDIX L Monthly Report Thatcher P3MMP Monthly Report Date: Area Date Number of Containers Processed Number of Containers Repackaged Trailer Number 0 0 P3MMP monthly reports will include the following on the SharePoint site. 1. Written Projec Description. 2. A copy of the inventory forms and spreadsheet created for the area. 3. Description of cleanup of any leak or spill material identified during the P3MICMP process. Items 1 and 2 will be included in the written project description on Thatchers letterhead with the certification. Thatcher P3MMP Monthly Report Area Disposition Review Monthly Data Totals = From Area Date Number of Containers Moved to NWSA Number of Containers Repackaged Number of Containers Sampled and Characterized Number of Hazardous Waste Containers Disposed Number of Non- Hazardous Waste Containers Disposed 0 0 0 0 0 Thatcher P3MMP Monthly Report NWSA Monthly Data Totals = Date of Retained Container Container Number Number of Containers Retained for Reuse 0Totals = Thatcher P3MMP Monthly Report Use/Reuse (Recycling) Monthly Data