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DAQ-2024-011244
1 DAQC-1087-24 Site ID 101764 (B4) MEMORANDUM TO: STACK TEST FILE – XCL ASSETCO, LLC – Myrin Ranch II 32-4B-23 THROUGH: Rik Ombach, Minor Source Oil and Gas Compliance Section Manager FROM: Paul Bushman, Environmental Scientist DATE: October 23, 2024 SUBJECT: Source: One (1) Waukesha L7044GSI engine Contact: Lauren Brown: (713) 808-9406 Location: Duchesne County, UT Test Contractor: Oasis Emission Consultants, Inc. Permit/AO#: Permit by Rule Action Code: TR Subject: Review of stack test report dated August 27, 2024 On October 22, 2024, Utah Division of Air Quality (DAQ) received a test report for one (1) Waukesha L7044GSI engine at Myrin Ranch II 32-4B-23, Duchesne County, Utah. Testing was performed August 21, 2024, to demonstrate compliance with the emission limits found in Utah Administrative Code R307-510 and 40 CFR Part 60, Subpart JJJJ. The calculated test results are: Source Test Date Pollutant Method Tester Results DAQ Results Limits Waukesha L7044GSI SN: 5283701555 August 21, 2024 NOx 320 0.09 g/bhp-hr 0.087 g/bhp-hr 1.0 g/bhp-hr CO 320 0.09 g/bhp-hr 0.092 g/bhp-hr 2.0 g/bhp-hr VOC 320 0.01 g/bhp-hr 0.012 g/bhp-hr 0.7 g/bhp-hr DEVIATIONS: None. CONCLUSION: The stack test report appears to be acceptable. RECOMMENDATION: The emissions from the Waukesha L7044GSI engine should be considered to have been in compliance with the emission limits of UAC R307-510 and 40 CFR Part 60, Subpart JJJJ during testing. ATTACHMENTS: DAQ stack test review excel spreadsheets, XCL AssetCo, LLC stack test report. Emissions XCL Resources Myrin Ranch II 32-4B-23 Duchesne County Waukesha L7044GSI; SN:5283701555 Test Date: 8/21/2024 Run #1 2 3 Average Start Time 11:58 12:58 13:58 Stop Time 12:58 13:58 14:58 Sample Duration (minutes)60 60 60 BHP Engine Load - Actual (bhp) 1680 1680 1680 1680 DS Stack Diameter (inches)12.0 12.0 12.0 12.0PAVG Average (Delta P)½ (" H2O)½1.3960 1.3550 1.4010 1.3840 CP Pitot Tube Constant (unitless)0.84 0.84 0.84 0.84 TS Stack Temperature (°F)763 764 766 765 Pbar Barometric Pressure (" Hg)24.68 24.67 24.67 24.67 Ps Stack Pressure ('' H2O)0.75 0.73 0.75 0.74 O2%vd O2 (%vd)0.0 0.0 0.0 0.0 CO2%vd CO2 (%vd)12.4 12.4 12.4 12.4 N2%vd N2 (%vd)87.6 87.6 87.6 87.6 dry NOX (ppmvd)25.3 24.5 24.6 24.8 dry CO (ppmvd) 41.5 41.5 47.2 43.4 wet NMEOC (ppmvw as C3H8)1.9 2.9 4.1 3.0 Run #1 2 3 Average Bws Measured Moisture Content (%/100)0.188 0.189 0.188 0.188 Bws Saturated Moisture Content (%/100)345.649 347.646 351.320 348.205 Bws Actual Moisture Content (%/100)0.188 0.189 0.188 0.188 MD Molecular Weight Dry (lb/lb-mole)29.98 29.98 29.98 29.98 MA Molecular Weight Wet (lb/lb-mole)27.74 27.72 27.74 27.73 VS Gas Velocity (ft/sec)133.9 130.0 134.5 132.8 FACFM Gas Flow (acfm)6308 6128 6340 6259 FDSCFM Gas Flow (dscfm)1828 1770 1831 1810 FWSCFM Gas Flow (wscfm)2251 2184 2256 2230 FKWSCFH Gas Flow (kwscfh)135 131 135 134 FKWSCFM Gas Flow (kwscfm)2.251 2.184 2.256 2.230 lb/hr Gas Flow (lb/hr) 9722 9428 9743 9631 Fo Fo (unitless)1.685 1.685 1.685 1.685 wet O2 (%vw)0.0 0.0 0.0 0.0 wet CO2 (%vw)10.1 10.1 10.1 10.1 wet NOX (ppmvw)20.556 19.872 19.953 20.127 15 NOX (ppmvd @ 15% O2)7.142 6.916 6.933 6.997 82.0 lb/hr NOX (lb/hr)0.331 0.310 0.322 0.321 g/bhp-hr NOX (g/bhp-hr)0.089 0.084 0.087 0.087 1.0 wet CO (ppmvw) 33.735 33.653 38.353 35.247 15 CO (ppmvd @ 15% O2)11.721 11.712 13.327 12.254 270.0 lb/hr CO (lb/hr) 0.331 0.320 0.377 0.343 g/bhp-hr CO (g/bhp-hr) 0.089 0.086 0.102 0.092 2.0 dry NMEOC (ppmvd as C3H8)2.360 3.540 5.100 3.667 dry NMEOC (ppmvd as C3H8)2.360 3.540 5.100 3.667 15 NMEOC (ppmvd as C3H8 @ 15% O2)0.666 0.999 1.440 1.035 60.0 lb/hr NMEOC (lb/hr as C3H8)0.030 0.043 0.064 0.046 g/bhp-hr NMEOC (g/bhp-hr as C3H8)0.008 0.012 0.017 0.012 0.7 Permit Limits Field Reference Method Data Reference Method Calculations Page 1 of 1 Source Test Report For XCL Resources Gilbert/Myrin 2 Duchesne County, Utah Test Date: August 21, 2024 Report Date: August 27, 2024 Federal Regulation: EPA 40 CFR 60, Subpart JJJJ Engine: Waukesha L7044GSI SN: 5283701555 Unit ID: AG18227 (101764) Prepared By: Oasis Emission Consultants, Inc. 2730 Commercial Way Rock Springs, WY 82901 August 27, 2024 Mr. Ryan Sokolowski XCL Resources Dear Mr. Sokolowski: Re: Engine Emission Testing For XCL Resources, Gilbert/Myrin 2, Unit AG18227 (101764), EPA 40 CFR 60, Subpart JJJJ. An air emissions test program was conducted on a Waukesha L7044GSI engine, operated by XCL Resources and designated as Unit AG18227 (101764), located at the Gilbert/Myrin 2 in Duchesne County, Utah. The purpose of the testing was to demonstrate compliance with the emissions limits contained in EPA 40 CFR 60, Subpart JJJJ, for oxides of nitrogen (NOx), carbon monoxide (CO) and volatile organic compounds (VOC). Oasis Emission Consultants, Inc. conducted the testing on August 21, 2024. EPA 40 CFR 60, Subpart JJJJ Emission Levels The average recorded levels were found to comply with emission levels stipulated in the permit, as shown in the attached report and summarized below. Emission Unit Avg NOx Permit NOx Avg CO Permit CO Avg NMNEHC* Permit VOC g/bhp-hr 0.09 1.0 0.09 2.0 0.01 0.7 *VOC levels reported as non-methane, non-ethane hydrocarbon on a propane basis (NMNEHC C3). Catalyst Parameters (Averaged Over 3 Test Runs) Inlet Temp (deg F) DP (in H2O) 724 3.4 Engine Load (Averaged Over 3 Test Runs) Rated BHP Operating BHP % Load 1680 1680.0 100.0 Testing Protocol The attached report was generated using an extractive FTIR system using methodologies as required by and in accordance with EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320 as outlined in the submitted Source Test Protocol. Quality Assurance Oasis has performed a full review of the raw data and calculated results in this report. Any errors we have encountered have been listed in the body of this report. After performing the review, we are confident that this engine has met all requirements. If you have any questions or require further information, please contact the undersigned at (307) 382-3297. Yours truly, Oasis Emission Consultants, Inc. _________________________ _______________________ Charles A. Chapman Cember Crawley Manager of Technical Services Environmental Scientist _________________________ Christopher N. Knott, P.Eng. Director, Engineering and Operations SOURCE EMISSION TEST REPORT FEDERAL REGULATION EPA 40 CFR 60, Subpart JJJJ Test Performed By: Oasis Emission Consultants, Inc. Test Company Contact: Chris Knott 2730 Commercial Way Rock Springs, WY 82901 307.382.3297 Owner/Operator: XCL Resources Owner/Operator Contact: Ryan Sokolowski Facility Name: Gilbert/Myrin 2 Duchesne County, Utah Emission Source: Waukesha L7044GSI Unit AG18227 (101764) Date of Test: August 21, 2024 Date of Report: August 27, 2024 TABLE OF CONTENTS 1.1 Introduction .......................................................................................................................... 1 1.2 Deviation .............................................................................................................................. 1 2.1 Stack Sampling Location ..................................................................................................... 2 3.1 Discussion of NOx, CO and VOC Test Results ................................................................... 4 3.1.1 Source Test 1 ............................................................................................................................................ 4 3.1.2 Source Test 2 ............................................................................................................................................ 4 3.1.3 Source Test 3 ............................................................................................................................................ 4 4.1 Stack Sampling Methods and Procedures ............................................................................ 5 4.2 Equipment Utilization .......................................................................................................... 6 4.3 Measurement of VOC (NMNEHC C3) ............................................................................... 7 4.4 Process Parameters............................................................................................................... 7 5.1 Quality Assurance ................................................................................................................ 8 List of Tables and Figures Figure 1 - Sample Port Location ............................................................................................................................. 2 Figure 2 - Sampling Train Schematic-Method 320 ................................................................................................ 6 Table 1 - Insertion Depths of Traverse Points for Stratification Test ..................................................................... 3 Table 2 - Location of Traverse Points in Circular Stacks ....................................................................................... 3 Table 3 - Test Matrix .............................................................................................................................................. 5 Table 4 - Concentrations and Interference .............................................................................................................. 6 APPENDIX A: NOx, CO and VOC Test Data APPENDIX B: Quality Assurance/Calibration Data APPENDIX C: Load Approximation APPENDIX D: Example Calculations and Summary APPENDIX E: Field Notes 1 1.1 Introduction An air emissions test program was conducted on a Waukesha L7044GSI engine, operated by XCL Resources and designated as Unit AG18227 (101764), located at the Gilbert/Myrin 2 in Duchesne County, Utah. The purpose of the testing was to demonstrate compliance with the emissions limits contained in EPA 40 CFR 60, Subpart JJJJ, for oxides of nitrogen (NOx), carbon monoxide (CO) and volatile organic compounds (VOC) defined as non-methane, non- ethane hydrocarbons, reported as propane (NMNEHC C3). The facility is currently located in Duchesne County, Utah. Three one hour test runs were performed on August 21, 2024 to analyze NOx, CO and VOC emission levels. Test runs were performed according to methodologies outlined by EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320 as outlined in the submitted Source Test Protocol. Each one hour test run consisted of 60 readings taken at one minute intervals. Process parameters were recorded during each test run in order to determine the load. Parameters include the engine panel load percent reading. The following key personnel were present during testing: Jordan Nix, OEC Branden A 1.2 Deviation The serial number was found to differ from that which was provided in the testing protocol. 2 2.1 Stack Sampling Location The facility is currently located in Duchesne County, Utah. Testing was conducted on the Waukesha L7044GSI engine. The sampling port for moisture, NOx, CO and VOC measurements was approximately 2.7 pipe diameters (32”) downstream from the nearest flow disturbance (Distance B) and 1.2 pipe diameters (14”) upstream from the nearest disturbance (Distance A), as seen in Figure 1. The stack sampling location was placed at approximately 50% insertion depth based on an O2 stratification check which demonstrated a non-stratified flow regime. The stratification was conducted according to EPA 40 CFR 75(A), §6.5.6.1 using 3 traverse points determined according to Table 1 below. In accordance with EPA 40 CFR 60(A), Method 1, a total of 16 traverse insertion depths (8 traverse points through each of the 2 ports) were determined according to Table 2 below in order to conduct Method 2. Figure 1 - Sample Port Location 12" A B 3 Table 1 - Insertion Depths of Traverse Points for Stratification Test Traverse Point Insertion Depth (Percent of Stack Diameter) 1 16.6 2 50.0 3 83.3 Table 2 - Location of Traverse Points in Circular Stacks 4 3.1 Discussion of NOx, CO and VOC Test Results Three, one hour test runs were performed on August 21, 2024 to analyze exhaust NOx, CO and VOC (NMNEHC C3) emission levels to demonstrate compliance with the emissions limits contained in EPA 40 CFR 60, Subpart JJJJ. Testing for NOx, CO and VOC were run concurrently with one another. Each test was performed at the maximum achievable load. Measured emissions were below permitted limits. Please refer to the Appendices for a listing of all raw data, calibration error response and calculations performed per EPA 40 CFR 60(A) requirements. 3.1.1 Source Test 1: Waukesha L7044GSI, NOx, CO and VOC The first test was performed from 11:58 to 12:57 for NOx, CO and VOC. Based on operating parameters recorded during testing, the load was approximated at 1680.0 bhp, and the average NOx and CO levels were found to be 0.09 g/bhp-hr and 0.09 g/bhp-hr respectively, below limitations. The VOC level tested at 0.01 g/bhp- hr, which tested in compliance. 3.1.2 Source Test 2: Waukesha L7044GSI, NOx, CO and VOC The second test was performed from 12:58 to 13:57 for NOx, CO and VOC. Based on operating parameters recorded during testing, the load was approximated at 1680.0 bhp, and the average NOx and CO levels were found to be 0.08 g/bhp-hr and 0.09 g/bhp-hr respectively, below limitations. The VOC level tested at 0.01 g/bhp- hr, which tested in compliance. 3.1.3 Source Test 3: Waukesha L7044GSI, NOx, CO and VOC The third test was performed from 13:58 to 14:57 for NOx, CO and VOC. Based on operating parameters recorded during testing, the load was approximated at 1680.0 bhp, and the average NOx and CO levels were found to be 0.09 g/bhp-hr and 0.10 g/bhp-hr respectively, below limitations. The VOC level tested at 0.02 g/bhp- hr, which tested in compliance. Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) VOC (ppmvd) VOC (g/bhp-hr) O2 (%) 1 25.30 0.09 41.52 0.09 2.36 0.01 0.0 Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) VOC (ppmvd) VOC (g/bhp-hr) O2 (%) 2 24.50 0.08 41.49 0.09 3.54 0.01 0.0 Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) VOC (ppmvd) VOC (g/bhp-hr) O2 (%) 3 24.56 0.09 47.21 0.10 5.10 0.02 0.0 5 4.1 Stack Sampling Methods and Procedures Testing followed EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320, with no exceptions. Table 3 - Test Matrix Method Title Parameter Reference EPA 40 CFR 60 Appendix A, Method 1 Sample and Velocity Traverses for Stationary Sources Sampling Point Determination https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_1_3.pdf EPA 40 CFR 60 Appendix A, Method 2 Determination of Stack Gas Velocity and Volumetric Flow Rate Exhaust Effluent Flow https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_2.pdf EPA 40 CFR 60 Appendix A, Method 3 Gas Analysis for the Determination of Dry Molecular Weight O2, CO2, Dry Volumetric Flow Rate https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_3.pdf EPA 40 CFR 63 Appendix A, EPA Method 320 Vapor Phase Organic and Inorganic Emissions by Extractive FTIR Nitrogen Oxides, Carbon Monoxide, Non- Methane Non- Ethane Hydrocarbons on a Propane Basis https://www.epa.gov/ emc/method-320- vapor-phase-organic- and-inorganic- emissions-extractive- ftir United States. U.S. Environmental Protection Agency. “EMC Promulgated Test Methods.” Air Emission Measurement Center (EMC). 31 August 2023. Web. 27 August 2024. <https://www.epa.gov/emc/emc-promulgated-test-methods>. 6 4.2 Equipment Utilization The following equipment was used during the tests performed at this facility in conjunction with procedures outlined by EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320. • (1) MKS MultiGas 2030 FTIR Continuous Gas Analyzer (0.210 L/min sample flow, 0.014 atmosphere sample pressure, 1 atmosphere cell pressure, 191°C cell temperature) • (1) Laptop Computer for the FTIR Analyzer using MKS MG2000 Software • (1) 75ft or 100ft Heated Teflon Line w/ Heated Sample Probe and Spike Bypass Line • S-Type Pitot Tube c/w 20 ft. Heated Sample Line (coefficient 0.84) • (1) Fyrite O2/CO2 Analyzer • (5) EPA Protocol G1 Calibration Gas (NOx, CO, C3H8, C2H4 and NO2) The MKS Multigas 2030 FTIR Analyzer operated with a spectral resolution of 0.5 cm-1 and a scan time of 30 seconds. The FTIR spectrometer utilizes a multi-pass gas cell with a 5.11 meter effective pathlength. Figure 2 - Sampling Train Schematic-Method 320 Table 4 - Concentrations and Interference 7 The MKS 2030 software provides a Natural Gas Method that is designed to minimize all expected interferences by removing the regions in the quant region where they are most absorbed (i.e. picket fence approach). So, for example, all the water peaks that are greater than about 0.1 abs are removed from the quant region. Since the spectral noise measured (sample spectrum) is in the range of 0.001 absorbance, it is desirable to have any error within this range. The MKS software will match the water calibration spectrum to the sample spectrum at any 1 point in the spectrum to about 1% precision. So, 1% of 0.1 absorbance is 0.001 abs. This is why any peaks greater than this for interfering compounds are usually excluded so they do not interfere. To summarize, the MKS software and the method are designed to minimize any interferences by removing their largest interfering absorptions. 4.3 Measurement of VOC (NMNEHC C3) The algorithm currently used for NMNEHC C3 and developed for natural gas fired applications by Dr. Spartz and MKS instruments in accordance with EPA standards, is the following: (2.4*c8/(1+exp((2-c8)/0.2))+1.9*c11/(1+exp((2-c11)/0.2))+6*c12/(1+exp((0.5-c12) /0.2))+2.85*c13/(1+exp((2-c13)/0.2))+3*c14/(1+exp((1-c14)/0.2)))/3 c8= acetylene c11= ethylene c12= hexane c13= propylene c14= propane Note: The constants in front of each of the compounds listed represents the FID response factor when calibrated with Propane. As with any CEMS analyzer, the FTIR may demonstrate a negative zero bias. The “exp” functions listed in the algorithm above are intended to mathematically filter out any negative biases and set them to approach zero. 4.4 Process Parameters Process parameters were recorded during each test run in order to determine the load. Parameters include the engine panel load percent reading. Results are provided in Appendix C. 8 5.1 Quality Assurance The MKS Multigas 2030 FTIR Analyzer was used to measure NOx, CO and VOC on a dry basis. A pre Direct and System calibration measurement was made on compounds of NOx, CO, C3H8 and C2H4. In addition, post System calibrations were made on compounds of NOx, CO, C3H8 and C2H4. Compounds of CO2 and C3H8 were measured for the quality assurance spiking requirements. Levels for calibrations and zeroes must be within +/- 5% of the certified calibration gas or response to zero gas, respectively. CTS procedures were followed according to EPA requirements for both pre and post testing. Similarly, QA spiking procedures were followed. Analysis of the CO2 exhaust effluent was used to determine the dilution factor. Steady levels of the CO2 were observed and a sufficient duration of time was allowed to elapse for a representative average. The calibration gas was spiked into the effluent stream using a bypass line at approximately 10% of the sampling rate. The dilution factor was obtained from observation of the stack CO2 behavior using the following equation: CO2AVG – CO2SPIKE DF = ------------------------ CO2 AVG Where: CO2AVG = The average undiluted CO2 stack gas concentration of spike measurements CO2SPIKE = The average diluted CO2 stack gas concentration when spiked The sample recovery was then obtained from the following equation: % REC = (Spike MEAS – Stack MEAS)* (1 – DF) --------------------------------------------------------- CS * DF Where: Spike MEAS = The average diluted stack gas concentration when spiked Stack MEAS = The average undiluted stack gas concentration DF = Dilution factor CS = Certified concentration of calibration standards The Sample Recovery average level for C3H8 was found to be 83.0%, which was within the allowable tolerance of Method 320 (70% to 130%). A summary of all spiking procedures/results can be found in Appendix B. APPENDIX A NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 23.066228 0.391568 23.457796 41.754724 1.753129 14.660578 11:58:18 08/21/2024 2 23.296925 0.554666 23.851591 40.842509 1.668966 15.425719 11:59:19 08/21/2024 3 23.153377 0.597671 23.751048 41.027095 2.208290 17.830046 12:00:19 08/21/2024 4 24.167774 0.667874 24.835648 40.661035 2.278803 18.593151 12:01:19 08/21/2024 5 23.041512 0.568525 23.610037 40.759836 1.712621 17.305285 12:02:19 08/21/2024 6 22.099433 0.370562 22.469995 41.850052 2.202798 19.409214 12:03:19 08/21/2024 7 22.834316 0.941221 23.775537 42.294529 2.542643 20.569305 12:04:19 08/21/2024 8 22.288538 0.894753 23.183291 44.439676 2.816924 19.051762 12:05:19 08/21/2024 9 22.810067 0.701755 23.511822 42.046062 2.421607 17.979203 12:06:19 08/21/2024 10 23.154322 0.751111 23.905433 41.624379 2.149364 19.875075 12:07:20 08/21/2024 11 25.390063 0.813154 26.203217 40.50186 1.887414 18.804905 12:08:20 08/21/2024 12 22.406088 0.565391 22.971479 41.73368 2.585339 18.067098 12:09:20 08/21/2024 13 22.524093 0.528429 23.052522 46.357544 1.720112 16.341179 12:10:20 08/21/2024 14 25.579434 0.586611 26.166045 43.370269 2.117964 20.940255 12:11:20 08/21/2024 15 61.461988 0.849296 62.311284 38.090819 2.158229 20.235475 12:12:20 08/21/2024 16 23.312678 0.932692 24.24537 39.518439 1.657302 20.333332 12:13:20 08/21/2024 17 24.048756 1.052822 25.101578 39.509947 2.963726 21.431038 12:14:20 08/21/2024 18 23.724068 0.874023 24.598091 40.110136 1.488392 21.407387 12:15:21 08/21/2024 19 22.366431 1.02787 23.394301 40.784599 2.093221 20.033179 12:16:21 08/21/2024 20 23.711708 0.885728 24.597436 40.890287 1.803814 19.62158 12:17:21 08/21/2024 21 23.801774 1.028486 24.83026 41.867445 2.689875 22.172859 12:18:21 08/21/2024 22 23.244436 1.224998 24.469434 41.781787 4.003978 21.622775 12:19:21 08/21/2024 23 23.315903 0.85365 24.169553 41.283952 3.949959 19.25554 12:20:21 08/21/2024 24 22.677399 0.813247 23.490646 42.394098 2.105896 18.604256 12:21:21 08/21/2024 25 23.202296 0.729332 23.931628 42.94332 2.518564 18.792922 12:22:21 08/21/2024 26 22.305331 0.709961 23.015292 43.348355 2.525564 17.903281 12:23:22 08/21/2024 27 24.882327 0.637373 25.5197 41.043795 2.535153 17.62771 12:24:22 08/21/2024 28 24.954219 0.608176 25.562395 40.370134 1.596719 17.011072 12:25:22 08/21/2024 29 23.000344 0.570591 23.570935 40.382993 2.191444 16.893658 12:26:22 08/21/2024 30 22.856236 0.548508 23.404744 41.322062 1.295609 16.603876 12:27:22 08/21/2024 31 22.721339 0.552562 23.273901 40.652933 2.117267 17.233656 12:28:22 08/21/2024 32 22.103478 0.511008 22.614486 41.038197 1.986808 17.095522 12:29:22 08/21/2024 33 22.417804 0.650389 23.068193 41.209489 1.385452 19.615491 12:30:22 08/21/2024 34 22.464253 0.869199 23.333452 41.734619 2.790962 21.15071 12:31:23 08/21/2024 35 22.029091 0.583271 22.612362 41.04096 2.560035 17.87737 12:32:23 08/21/2024 36 21.618538 0.606692 22.22523 42.890081 1.928626 17.210482 12:33:23 08/21/2024 37 22.540758 0.638577 23.179335 41.075082 2.856775 18.915777 12:34:23 08/21/2024 38 21.594522 0.460595 22.055117 41.780939 1.355966 16.856762 12:35:23 08/21/2024 39 22.34354 0.509177 22.852717 41.524013 2.611501 18.717827 12:36:23 08/21/2024 40 22.903141 1.136939 24.04008 40.236353 2.897484 21.549582 12:37:23 08/21/2024 41 21.638541 0.678248 22.316789 41.668527 3.052014 19.573466 12:38:23 08/21/2024 42 22.581962 0.864888 23.44685 47.25239 2.305602 19.6507 12:39:24 08/21/2024 43 22.710953 0.702061 23.413014 41.646566 2.590907 18.445182 12:40:24 08/21/2024 44 22.301736 0.554248 22.855984 41.553976 2.046283 17.596522 12:41:24 08/21/2024 45 22.036251 0.611536 22.647787 41.835394 2.158375 17.742521 12:42:24 08/21/2024 46 22.106205 0.575626 22.681831 41.719828 2.778845 18.64058 12:43:24 08/21/2024 47 22.107983 0.808953 22.916936 45.269945 2.441822 19.803387 12:44:24 08/21/2024 48 22.79558 0.605784 23.401364 52.888082 2.677950 17.160013 12:45:24 08/21/2024 49 34.580207 0.632607 35.212814 41.079313 3.110307 18.828497 12:46:24 08/21/2024 50 68.620074 0.570221 69.190295 37.352722 2.389618 19.89005 12:47:25 08/21/2024 51 27.463702 0.70836 28.172062 38.118667 1.735312 18.768899 12:48:25 08/21/2024 52 22.566194 0.513533 23.079727 39.08724 2.265391 16.91663 12:49:25 08/21/2024 53 21.722195 1.041291 22.763486 40.675502 4.377199 22.155141 12:50:25 08/21/2024 54 21.597188 0.831023 22.428211 40.776302 2.666350 19.01218 12:51:25 08/21/2024 55 23.213792 0.629285 23.843077 40.580112 2.145283 18.739667 12:52:25 08/21/2024 56 26.460258 0.849461 27.309719 39.918637 2.562118 20.652373 12:53:25 08/21/2024 57 21.851378 0.785971 22.637349 40.270245 3.694692 18.805653 12:54:26 08/21/2024 58 22.770538 0.713871 23.484409 40.618306 2.001021 18.534422 12:55:26 08/21/2024 59 22.539643 0.556568 23.096211 40.64401 2.394312 17.104568 12:56:26 08/21/2024 60 22.639742 0.491384 23.131126 40.397016 1.936871 16.454275 12:57:26 08/21/2024 AVG 24.60 0.71 25.30 41.52 2.36 18.75 ppm@15% O2 7.14 11.72 0.67 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.09 0.33 0.09 0.33 0.01 0.03 AG18227 (101764) FTIR Measurements Calculated Emission Levels XCL Resources Gilbert/Myrin 2 Run 1 Record Date EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 12 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 1.53 1223 0.75 1.237 Average O2 0.0 (% dry)A 2 1.26 1.84 1.356 Average CO2 12.4 (% dry)A 3 2.33 1.88 1.371 Average N2 + CO 87.6 (% dry)A 4 3.88 1.98 1.407 Dry Molecular Weight 29.98 lb/lbmol A 5 8.12 2.09 1.446 Wet Molecular Weight 27.74 lb/lbmol A 6 9.67 2.11 1.453 EPA REFERENCE METHOD 320 A 7 10.74 2.07 1.439 Barometric Pressure 24.68 in Hg A 8 11.50 2.00 1.414 Moisture Content 18.75 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 25.30 ppm A 11 Calculated NOx Mass Output 0.33 lbs/hr A 12 Calculated NOx Output 0.09 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 41.52 ppm A 15 Calculated CO Mass Output 0.33 lbs/hr A 16 Calculated CO Output 0.09 g/bhp-hr B 1 0.50 1.98 1223 0.75 1.407 EPA REFERENCE METHOD 320 B 2 1.26 1.88 1.371 Average Analyzer NMNEHC Level 2.36 ppm B 3 2.33 1.85 1.360 Calculated NMNEHC Mass Output 0.03 lbs/hr B 4 3.88 1.97 1.404 Calculated NMNEHC Output 0.01 g/bhp-hr B 5 8.12 2.07 1.439 LOAD APPROXIMATION B 6 9.67 2.02 1.421 Estimated Engine Load 1680.0 BHP B 7 10.74 1.98 1.407 B 8 11.50 1.95 1.396 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 2.0 1223 0.8 1.396 Average Stack Gas Velocity 133.80 ft/sec Average Dry Flowrate 1828.42 dscfm TEST RUN # 1 NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 22.274381 0.521848 22.796229 40.964699 2.380548 17.803564 12:58:26 08/21/2024 2 21.856259 0.65285 22.509109 41.436745 2.170169 19.457572 12:59:26 08/21/2024 3 22.006586 0.682111 22.688697 42.358126 2.588661 18.337242 13:00:26 08/21/2024 4 22.731412 0.625355 23.356767 40.934168 2.822763 17.553941 13:01:26 08/21/2024 5 22.078603 0.800681 22.879284 41.602182 2.423289 20.189255 13:02:27 08/21/2024 6 22.410688 0.701892 23.11258 41.106511 2.308132 17.93312 13:03:27 08/21/2024 7 22.480071 0.674673 23.154744 40.910421 3.367131 19.921559 13:04:27 08/21/2024 8 22.473304 0.786226 23.25953 42.056647 2.003117 19.446683 13:05:27 08/21/2024 9 22.753688 1.007912 23.7616 48.379587 4.095270 20.209313 13:06:27 08/21/2024 10 24.5961 0.761616 25.357716 41.882338 3.067040 18.673703 13:07:27 08/21/2024 11 24.727411 0.800391 25.527802 41.147493 2.908751 18.828429 13:08:27 08/21/2024 12 22.54341 0.890093 23.433503 42.631623 3.061620 21.674863 13:09:27 08/21/2024 13 22.798604 0.931929 23.730533 42.032486 4.150784 21.948643 13:10:28 08/21/2024 14 22.107219 0.966611 23.07383 42.178737 2.172341 19.036136 13:11:28 08/21/2024 15 22.675278 0.776167 23.451445 42.64995 2.046952 18.384268 13:12:28 08/21/2024 16 22.555372 0.79439 23.349762 43.178239 2.595483 20.180248 13:13:28 08/21/2024 17 22.789396 1.095763 23.885159 42.207306 3.895202 20.938419 13:14:28 08/21/2024 18 22.86602 1.081998 23.948018 43.150905 3.854213 21.128966 13:15:28 08/21/2024 19 25.008882 0.690179 25.699061 41.776685 2.643541 18.459555 13:16:28 08/21/2024 20 22.412976 0.687195 23.100171 42.65478 3.176115 17.884562 13:17:28 08/21/2024 21 22.530783 0.627619 23.158402 42.214299 2.674905 17.259445 13:18:29 08/21/2024 22 22.625906 0.545695 23.171601 42.636632 2.465530 16.985867 13:19:29 08/21/2024 23 22.843983 0.58204 23.426023 42.418948 3.498046 18.636563 13:20:29 08/21/2024 24 25.133228 0.897816 26.031044 40.401461 3.799663 20.217173 13:21:29 08/21/2024 25 30.791529 0.54564 31.337169 39.491436 3.484121 18.641807 13:22:29 08/21/2024 26 27.22382 0.612094 27.835914 40.066221 2.543766 18.969221 13:23:29 08/21/2024 27 35.405642 0.497508 35.90315 38.721309 1.965101 15.955694 13:24:29 08/21/2024 28 23.581899 0.52152 24.103419 39.088549 3.055830 16.30261 13:25:29 08/21/2024 29 22.536902 0.569035 23.105937 39.851206 2.760708 18.880771 13:26:30 08/21/2024 30 22.424007 0.88037 23.304377 41.240296 4.739663 20.368589 13:27:30 08/21/2024 31 23.214678 0.7179 23.932578 40.097332 5.353232 19.255189 13:28:30 08/21/2024 32 22.789145 0.626313 23.415458 40.546635 5.132403 17.163889 13:29:30 08/21/2024 33 22.331226 0.903355 23.234581 41.673844 3.892182 19.610824 13:30:30 08/21/2024 34 22.279496 0.876069 23.155565 42.764373 3.959490 18.356948 13:31:30 08/21/2024 35 22.317255 0.993083 23.310338 42.675237 5.155183 21.097917 13:32:30 08/21/2024 36 22.02805 0.832422 22.860472 44.111176 4.774109 17.440515 13:33:30 08/21/2024 37 22.278878 0.829444 23.108322 42.813629 3.403590 17.444586 13:34:31 08/21/2024 38 22.42635 0.744411 23.170761 43.820447 5.121799 18.288039 13:35:31 08/21/2024 39 23.429913 0.75531 24.185223 41.562844 4.960988 18.130943 13:36:31 08/21/2024 40 23.862161 0.751289 24.61345 40.906658 3.309767 17.620277 13:37:31 08/21/2024 41 38.586034 0.925324 39.511358 38.237232 2.171068 19.315131 13:38:31 08/21/2024 42 22.724212 1.194213 23.918425 39.351741 4.526229 20.658162 13:39:31 08/21/2024 43 22.390008 0.751615 23.141623 40.457819 3.594557 17.911637 13:40:31 08/21/2024 44 21.828356 0.697315 22.525671 40.915508 3.225584 17.170207 13:41:32 08/21/2024 45 21.958729 0.59995 22.558679 41.043349 4.752450 16.542592 13:42:32 08/21/2024 46 21.993768 0.976214 22.969982 41.494574 5.477723 20.560771 13:43:32 08/21/2024 47 22.285426 1.252205 23.537631 42.237145 5.613098 21.208558 13:44:32 08/21/2024 48 21.898829 1.016304 22.915133 41.808567 5.547132 18.9272 13:45:32 08/21/2024 49 22.258072 0.688293 22.946365 41.626875 3.954053 17.636684 13:46:32 08/21/2024 50 22.244024 0.856827 23.100851 42.682686 2.851985 17.800842 13:47:32 08/21/2024 51 22.979148 0.940733 23.919881 41.594036 4.693341 19.927655 13:48:32 08/21/2024 52 23.559878 0.9502 24.510078 41.009093 4.340875 20.138948 13:49:33 08/21/2024 53 23.015136 0.828647 23.843783 40.911293 4.617128 18.520045 13:50:33 08/21/2024 54 23.334491 0.858393 24.192884 40.744586 3.245884 19.132879 13:51:33 08/21/2024 55 22.894604 0.964076 23.85868 42.102054 3.318692 19.656201 13:52:33 08/21/2024 56 23.766595 0.959092 24.725687 42.3031 2.297501 19.044507 13:53:33 08/21/2024 57 26.532096 0.742873 27.274969 39.811135 3.614534 17.193165 13:54:33 08/21/2024 58 28.047567 0.932373 28.97994 39.450457 2.599014 18.686872 13:55:33 08/21/2024 59 23.249072 0.861098 24.11017 40.142588 3.251755 18.021601 13:56:33 08/21/2024 60 28.222984 0.999866 29.22285 39.002595 4.773639 20.462719 13:57:34 08/21/2024 AVG 23.70 0.80 24.50 41.49 3.54 18.89 ppm@15% O2 6.92 11.71 1.00 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.08 0.31 0.09 0.32 0.01 0.04 Calculated Emission Levels Record Date XCL Resources Gilbert/Myrin 2 Run 2 AG18227 (101764) FTIR Measurements EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 12 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 1.59 1224 0.73 1.261 Average O2 0.0 (% dry)A 2 1.26 1.55 1.245 Average CO2 12.4 (% dry)A 3 2.33 1.60 1.265 Average N2 + CO 87.6 (% dry)A 4 3.88 1.84 1.356 Dry Molecular Weight 29.98 lb/lbmol A 5 8.12 1.95 1.396 Wet Molecular Weight 27.72 lb/lbmol A 6 9.67 1.87 1.367 EPA REFERENCE METHOD 320 A 7 10.74 1.82 1.349 Barometric Pressure 24.67 in Hg A 8 11.50 1.97 1.404 Moisture Content 18.89 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 24.50 ppm A 11 Calculated NOx Mass Output 0.31 lbs/hr A 12 Calculated NOx Output 0.08 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 41.49 ppm A 15 Calculated CO Mass Output 0.32 lbs/hr A 16 Calculated CO Output 0.09 g/bhp-hr B 1 0.50 1.56 1224 0.73 1.249 EPA REFERENCE METHOD 320 B 2 1.26 1.76 1.327 Average Analyzer NMNEHC Level 3.54 ppm B 3 2.33 1.89 1.375 Calculated NMNEHC Mass Output 0.04 lbs/hr B 4 3.88 2.09 1.446 Calculated NMNEHC Output 0.01 g/bhp-hr B 5 8.12 1.99 1.411 LOAD APPROXIMATION B 6 9.67 2.04 1.428 Estimated Engine Load 1680.0 BHP B 7 10.74 2.01 1.418 B 8 11.50 1.92 1.386 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 1.8 1224 0.7 1.355 Average Stack Gas Velocity 130.05 ft/sec Average Dry Flowrate 1771.96 dscfm TEST RUN # 2 NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 22.4657 0.96879 23.43449 40.323395 4.915373 20.055235 13:58:34 08/21/2024 2 22.239701 1.038501 23.278202 41.008576 4.503450 18.873881 13:59:34 08/21/2024 3 24.198286 0.86244 25.060726 41.867442 2.870673 18.456533 14:00:34 08/21/2024 4 22.718642 0.957661 23.676303 40.817964 2.780410 18.571217 14:01:34 08/21/2024 5 29.402976 0.769418 30.172394 39.262045 2.736175 17.944944 14:02:34 08/21/2024 6 23.872686 0.823191 24.695877 40.813934 3.323867 17.736107 14:03:34 08/21/2024 7 22.283641 0.73821 23.021851 42.159507 2.597792 17.295124 14:04:34 08/21/2024 8 22.311951 1.014007 23.325958 41.388368 5.263701 20.575607 14:05:35 08/21/2024 9 22.660107 1.202692 23.862799 41.183544 5.157861 20.673821 14:06:35 08/21/2024 10 22.626748 1.137865 23.764613 40.986608 3.901691 19.817461 14:07:35 08/21/2024 11 24.574705 0.89468 25.469385 40.348304 3.987012 18.759666 14:08:35 08/21/2024 12 23.517979 0.61335 24.131329 39.774402 2.161047 16.473485 14:09:35 08/21/2024 13 21.986921 0.583111 22.570032 41.506001 3.737158 15.854679 14:10:35 08/21/2024 14 22.856742 0.68408 23.540822 40.994064 3.766050 17.856195 14:11:35 08/21/2024 15 23.133774 0.672407 23.806181 40.310774 4.911260 20.402555 14:12:36 08/21/2024 16 22.747466 1.06947 23.816936 41.346495 5.269570 19.447236 14:13:36 08/21/2024 17 22.700872 0.938416 23.639288 43.776821 3.932790 18.059051 14:14:36 08/21/2024 18 23.145532 1.136942 24.282474 43.187397 5.321981 20.700047 14:15:36 08/21/2024 19 23.374067 1.156952 24.531019 42.889114 5.940223 20.495323 14:16:36 08/21/2024 20 22.778688 1.302121 24.080809 42.831837 5.356580 19.845624 14:17:36 08/21/2024 21 22.896259 1.208967 24.105226 43.567156 5.661499 20.539413 14:18:36 08/21/2024 22 23.31422 0.958571 24.272791 43.646022 3.575793 18.556961 14:19:36 08/21/2024 23 22.848531 1.093117 23.941648 44.249016 4.738485 18.929727 14:20:37 08/21/2024 24 22.936161 0.853546 23.789707 43.938598 5.481300 18.296622 14:21:37 08/21/2024 25 23.121585 1.102627 24.224212 44.677691 5.260522 18.800383 14:22:37 08/21/2024 26 22.886221 1.003363 23.889584 44.668775 5.375561 17.756195 14:23:37 08/21/2024 27 23.672828 1.043299 24.716127 43.545054 3.916204 19.506849 14:24:37 08/21/2024 28 24.020337 0.952891 24.973228 43.456011 5.387380 18.393298 14:25:37 08/21/2024 29 23.460003 0.836019 24.296022 43.609225 5.334036 17.485277 14:26:37 08/21/2024 30 23.428764 1.001781 24.430545 43.727941 5.365580 18.218682 14:27:37 08/21/2024 31 23.336898 1.037089 24.373987 44.71897 5.811507 18.498419 14:28:38 08/21/2024 32 23.632747 0.815562 24.448309 44.682101 5.691514 17.472296 14:29:38 08/21/2024 33 23.216577 0.876004 24.092581 44.125949 5.516864 17.18609 14:30:38 08/21/2024 34 23.491221 1.035826 24.527047 44.399952 3.960982 18.744596 14:31:38 08/21/2024 35 23.538974 1.046041 24.585015 47.267657 5.176205 18.280295 14:32:38 08/21/2024 36 23.977381 1.053345 25.030726 50.545232 6.126597 18.483363 14:33:38 08/21/2024 37 24.767448 0.911868 25.679316 67.394349 6.190290 18.599415 14:34:38 08/21/2024 38 24.677264 1.028296 25.70556 57.114039 6.418463 18.833987 14:35:38 08/21/2024 39 23.890996 0.897105 24.788101 53.715255 6.197984 18.244474 14:36:39 08/21/2024 40 24.411881 0.994546 25.406427 59.282546 6.049146 18.306043 14:37:39 08/21/2024 41 24.679637 0.970053 25.64969 45.825578 5.786963 18.547838 14:38:39 08/21/2024 42 23.777141 1.117224 24.894365 43.255988 6.062660 20.02565 14:39:39 08/21/2024 43 23.091805 1.084991 24.176796 45.42361 5.372495 18.74442 14:40:39 08/21/2024 44 23.62935 1.377336 25.006686 47.613387 5.377763 20.611615 14:41:39 08/21/2024 45 23.544482 1.196185 24.740667 51.223864 6.252900 19.299117 14:42:39 08/21/2024 46 23.669717 1.019702 24.689419 47.29776 5.654881 19.082715 14:43:39 08/21/2024 47 23.373441 1.127193 24.500634 45.60179 5.318905 19.303216 14:44:40 08/21/2024 48 23.319136 1.092979 24.412115 46.907332 5.365180 19.33529 14:45:40 08/21/2024 49 23.498184 0.995052 24.493236 47.030054 6.216413 18.572454 14:46:40 08/21/2024 50 23.583673 0.996213 24.579886 49.492996 6.429234 18.80536 14:47:40 08/21/2024 51 23.492037 0.983385 24.475422 47.740281 5.184621 18.337772 14:48:40 08/21/2024 52 23.941173 0.989243 24.930416 56.998778 6.143323 19.064887 14:49:40 08/21/2024 53 24.842152 1.261648 26.1038 69.037864 5.632560 20.821682 14:50:40 08/21/2024 54 24.554418 1.149927 25.704345 62.543549 5.457644 19.352321 14:51:41 08/21/2024 55 24.019876 0.95908 24.978956 55.651972 5.782676 18.464487 14:52:41 08/21/2024 56 23.743069 0.821944 24.565013 54.130676 6.411840 17.758422 14:53:41 08/21/2024 57 24.049109 0.895829 24.944938 56.058952 5.965588 17.728437 14:54:41 08/21/2024 58 24.148075 0.967238 25.115313 60.517168 5.519470 18.132937 14:55:41 08/21/2024 59 24.690203 1.023422 25.713625 66.659997 6.612452 18.368147 14:56:41 08/21/2024 60 23.769712 0.976276 24.745988 54.520273 5.587740 18.065392 14:57:41 08/21/2024 AVG 23.58 0.99 24.56 47.21 5.10 18.76 ppm@15% O2 6.93 13.33 1.44 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.09 0.32 0.10 0.38 0.02 0.06 FTIR Measurements AG18227 (101764) Calculated Emission Levels XCL Resources Gilbert/Myrin 2 Run 3 Record Date EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 12 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 1.88 1226 0.75 1.371 Average O2 0.0 (% dry)A 2 1.26 2.03 1.425 Average CO2 12.4 (% dry)A 3 2.33 2.02 1.421 Average N2 + CO 87.6 (% dry)A 4 3.88 1.97 1.404 Dry Molecular Weight 29.98 lb/lbmol A 5 8.12 1.85 1.360 Wet Molecular Weight 27.74 lb/lbmol A 6 9.67 1.98 1.407 EPA REFERENCE METHOD 320 A 7 10.74 2.06 1.435 Barometric Pressure 24.67 in Hg A 8 11.50 1.84 1.356 Moisture Content 18.76 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 24.56 ppm A 11 Calculated NOx Mass Output 0.32 lbs/hr A 12 Calculated NOx Output 0.09 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 47.21 ppm A 15 Calculated CO Mass Output 0.38 lbs/hr A 16 Calculated CO Output 0.10 g/bhp-hr B 1 0.50 1.75 1226 0.75 1.323 EPA REFERENCE METHOD 320 B 2 1.26 1.99 1.411 Average Analyzer NMNEHC Level 5.10 ppm B 3 2.33 1.89 1.375 Calculated NMNEHC Mass Output 0.06 lbs/hr B 4 3.88 2.08 1.442 Calculated NMNEHC Output 0.02 g/bhp-hr B 5 8.12 2.12 1.456 LOAD APPROXIMATION B 6 9.67 2.06 1.435 Estimated Engine Load 1680.0 BHP B 7 10.74 1.93 1.389 B 8 11.50 1.96 1.400 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 2.0 1226 0.8 1.401 Average Stack Gas Velocity 134.49 ft/sec Average Dry Flowrate 1832.44 dscfm TEST RUN # 3 APPENDIX B Date Time NO 191C span NO2 191C span H2O% (high) 191C Formaldehyde 191C Ethylene 191C TE span Propane 191C span Acetaldehyde 191C span CO ppm 191C (1of2) spanCO ppm Dry CO2% 191C NOx Wet NOx Dry NM NE HC C3 Temp ( C )Pressure (atm)8/21/2024 11:34:11 -0.037229 0.047172 0.007474 -0.107194 0.24907 0.042153 -0.050165 -0.065403 -0.065408 0.018543 0.009944 0.009944 0.039144 190.927246 0.9974138/21/2024 11:34:18 0.074622 0.136601 0.005466 -0.210338 -0.200232 0.270038 0.947749 0.121688 0.121695 0.015776 0.211223 0.211235 0.005977 190.927246 1.0001758/21/2024 11:34:26 0.024638 0.043081 0.007444 0.00104 0.048478 0.570603 0.850333 0.008733 0.008734 0.006076 0.067719 0.067724 0.09331 190.927246 0.999945 8/21/2024 11:34:33 -0.327638 0.059339 0.008699 -0.158711 -0.014915 0.089233 0.599133 -0.247979 -0.248001 0.010926 -0.268299 -0.268322 0.316897 190.927246 1.0005178/21/2024 11:35:15 0 0 0 0 0 0 0 0 0 0 0 0 0 190.927246 1.000114 8/21/2024 11:35:28 -0.189668 -0.115894 -0.005578 -0.152496 -0.179545 0.057898 -0.065512 0.035319 0.035317 0.002697 -0.305562 -0.305545 0.031041 190.927246 0.9999398/21/2024 11:35:36 -0.194331 -0.058186 -0.00392 -0.116061 -0.732247 0.429678 0.137792 0.152063 0.152057 0.002357 -0.252517 -0.252507 0.046426 190.927246 0.9999928/21/2024 11:35:43 0.190138 -0.114618 -0.005512 -0.193855 -0.558773 0.027539 -0.312572 0.137454 0.137446 0.000775 0.07552 0.075516 0.02295 190.927246 0.9998178/21/2024 11:35:51 -0.24143 0.002364 -0.002768 -0.222569 0.030645 -0.911375 -0.450381 0.009934 0.009934 0.019729 -0.239065 -0.239059 0.028809 190.927246 1.0004718/21/2024 11:35:58 0.155394 0.01554 -0.001494 -0.091483 0.196086 0.349545 0.207808 0.125705 0.125703 -0.00141 0.170934 0.170932 0.00936 190.927246 0.9999358/21/2024 11:36:06 0.107365 -0.06644 -0.002875 -0.089893 -0.401774 0.43477 -0.382913 0.054378 0.054376 -0.011156 0.040925 0.040924 0.020503 190.927246 1.0005838/21/2024 11:36:13 0.077687 -0.059415 -0.004359 -0.23772 0.914433 -0.053626 0.32484 -0.134433 -0.134427 -0.004349 0.018272 0.018271 -0.005322 190.927246 0.999714 8/21/2024 11:36:21 -0.054084 -0.063947 0.000858 -0.249059 0.008912 -0.475804 -0.573307 0.110557 0.110558 0.001555 -0.118031 -0.118032 0.030429 190.927246 0.9999668/21/2024 11:36:28 -0.081255 0.021997 -0.000429 0.050371 -0.457336 0.484815 0.267618 -0.188429 -0.188428 -0.001729 -0.059258 -0.059258 0.057928 190.927246 1.000491 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/21/2024 11:36:48 284.912831 286.39403 253.4102 190.927246 0.998508 8/21/2024 11:40:03 52.599575 190.95903 0.9984888/21/2024 11:36:56 446.602485 448.136149 438.241185 190.932693 0.999648 8/21/2024 11:40:11 86.101214 190.95903 0.999591 8/21/2024 11:37:03 485.377078 489.289127 481.72509 191.022614 1.000356 8/21/2024 11:40:18 95.899655 190.95903 0.9992158/21/2024 11:37:11 494.123196 500.491573 489.429754 191.022614 0.999829 8/21/2024 11:40:26 97.454304 190.95903 0.9993158/21/2024 11:37:18 499.103861 504.296865 493.352994 191.022614 0.99993 8/21/2024 11:40:33 98.452889 190.95903 0.9993368/21/2024 11:37:26 500.552014 504.798385 496.842793 191.022614 0.999886 8/21/2024 11:40:41 99.061635 190.95903 0.9993788/21/2024 11:37:34 501.874699 506.156332 492.923798 191.022614 1.000098 8/21/2024 11:40:48 99.908037 190.95903 0.9992648/21/2024 11:37:41 501.001271 506.89384 494.403705 191.022614 1.000299 8/21/2024 11:40:56 98.879784 190.95903 0.998738/21/2024 11:37:49 501.860112 506.911076 498.553957 191.022614 1.000104 8/21/2024 11:41:03 99.158892 190.95903 0.998327 8/21/2024 11:37:56 501.29733 507.111012 494.959289 191.022614 1.000571 8/21/2024 11:41:11 99.736807 190.95903 0.998893 Date Time NO2 191C span Temp ( C )Pressure (atm)8/21/2024 11:38:18 50.867502 191.117447 1.0045988/21/2024 11:38:26 110.124998 191.040771 1.0059928/21/2024 11:38:33 129.940113 191.035324 1.005092 8/21/2024 11:38:41 135.216844 191.035324 1.005558/21/2024 11:38:48 137.98695 191.035324 1.0061538/21/2024 11:38:56 139.390596 191.034409 1.0064438/21/2024 11:39:03 140.242597 191.00444 1.0063288/21/2024 11:39:11 140.855774 190.95903 1.0061368/21/2024 11:39:18 141.405702 190.95903 1.0062258/21/2024 11:39:26 142.067814 190.95903 1.006101 8/21/2024 11:39:33 142.191347 190.95903 1.0056978/21/2024 11:39:41 142.940981 190.95903 1.006415 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/21/2024 11:41:32 25.251458 29.224012 19.635738 190.95903 0.989165 8/21/2024 11:43:02 55.323926 190.95903 0.9973778/21/2024 11:41:39 305.113194 309.038113 273.825959 190.95903 0.997597 8/21/2024 11:43:09 86.725079 190.95903 0.997884 8/21/2024 11:41:47 450.743272 452.114907 443.439302 190.95903 0.998007 8/21/2024 11:43:17 95.697194 190.95903 0.9988858/21/2024 11:41:54 487.60038 491.145088 486.056781 190.95903 0.998678 8/21/2024 11:43:24 98.032802 190.95903 0.99846 8/21/2024 11:42:02 499.535656 503.676328 493.388841 190.95903 0.998405 8/21/2024 11:43:32 99.450401 190.959824 0.9985158/21/2024 11:42:09 503.063261 507.422173 493.961394 190.95903 0.998483 8/21/2024 11:43:39 98.778376 191.007172 0.9987938/21/2024 11:42:17 504.028603 508.295193 497.220494 190.95903 0.998759 8/21/2024 11:43:47 98.89642 191.042587 0.9982638/21/2024 11:42:24 506.778452 510.876288 499.453702 190.95903 0.998458 8/21/2024 11:43:55 99.93983 191.124329 0.9977228/21/2024 11:42:32 504.981758 508.991028 497.242885 190.95903 0.998399 8/21/2024 11:44:02 99.047262 191.124329 0.9989378/21/2024 11:42:39 504.162495 508.77946 498.130912 190.95903 0.998724 8/21/2024 11:44:10 98.780037 191.124329 0.998668 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Ethylene 191C TE Temp ( C )Pressure (atm)8/21/2024 11:44:32 0.873371 0.50061 0.536575 9.639554 191.124329 0.996968/21/2024 11:44:40 0.428794 0.317234 0.020758 2.198312 191.124329 0.9988/21/2024 11:44:47 0.212943 0.151983 0.371138 0.569792 191.124329 0.997884 8/21/2024 11:44:55 0.191538 -0.138432 -0.155917 -0.231164 191.124329 0.997998/21/2024 11:45:02 0.185265 -0.042524 0.291986 -0.101427 191.124329 0.997703 8/21/2024 11:45:10 0.183822 0.041546 0.36903 0.654562 191.124329 0.9979788/21/2024 11:45:17 0.312338 0.014606 -0.267363 -0.095701 191.124329 0.9975688/21/2024 11:45:25 -0.009926 -0.082227 0.08272 0.231366 191.124329 0.998019 Raw Calibration Data BACKGROUND / PRE DIRECT ZERO PRE DIRECT CAL NO2 CAL PRE SYSTEM CAL PRE SYSTEM ZERO Date Time CO2% 191C Propane 191C span Temp ( C )Pressure (atm)8/21/2024 11:51:11 11.157593 0.340928 190.895447 0.9709738/21/2024 11:51:19 11.169195 0.659709 190.895447 0.9710348/21/2024 11:51:26 11.137902 0.724552 190.895447 0.9712878/21/2024 11:54:04 11.114772 0.374441 191.002106 0.9717098/21/2024 11:54:12 10.986927 0.676463 191.079834 0.97541 8/21/2024 11:54:19 5.877376 130.329242 191.079834 0.9816818/21/2024 11:54:27 1.604139 367.490348 191.079834 0.975047 8/21/2024 11:54:34 0.64906 422.045934 191.079834 0.9693178/21/2024 11:54:42 4.923127 235.316111 191.079834 0.970558/21/2024 11:54:49 8.563075 99.795339 191.079834 0.9726158/21/2024 11:54:57 9.589174 59.964688 191.079834 0.9730598/21/2024 11:55:04 9.876302 51.08338 191.079834 0.9733728/21/2024 11:55:12 9.993723 47.285912 191.079834 0.973968/21/2024 11:55:19 10.008185 46.515836 191.079834 0.973418 8/21/2024 11:55:27 9.994473 46.727565 191.065964 0.9731828/21/2024 11:55:34 9.968851 48.049623 191.054398 0.973689 8/21/2024 11:55:42 9.952428 46.422941 191.054398 0.9727288/21/2024 11:55:49 9.96274 44.904083 191.054398 0.9719788/21/2024 11:55:57 10.025937 43.793077 191.054398 0.9740098/21/2024 11:56:27 9.62298 36.025937 191.006119 1.0078388/21/2024 11:56:35 9.769471 35.820398 190.971741 1.0069588/21/2024 11:56:42 9.627131 36.324243 190.971741 1.0026488/21/2024 11:56:50 9.862806 36.347855 190.971741 1.005812 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/21/2024 15:09:49 249.042694 245.830344 213.306422 191.048035 1.0132 8/21/2024 15:08:20 58.967673 191.048035 0.9450088/21/2024 15:09:56 439.499302 437.419903 427.909103 191.048035 1.013788 8/21/2024 15:08:28 87.703959 191.048035 1.020213 8/21/2024 15:10:04 488.31296 488.645678 481.432938 191.038956 1.013783 8/21/2024 15:08:35 94.794431 191.048035 1.0248458/21/2024 15:10:11 500.885231 504.21609 492.372698 190.98764 1.013297 8/21/2024 15:08:43 97.639668 191.048035 1.024587 8/21/2024 15:10:19 504.659623 507.893225 495.398311 190.971741 1.012859 8/21/2024 15:08:50 98.092921 191.048035 1.0246698/21/2024 15:10:26 507.873904 510.139375 495.507512 190.971741 1.013063 8/21/2024 15:08:58 98.149614 191.048035 1.0243618/21/2024 15:10:34 508.496099 509.939871 496.635258 190.971741 1.013235 8/21/2024 15:09:05 99.491141 191.048035 1.0176148/21/2024 15:10:42 508.092989 510.751158 497.08282 190.93837 1.013041 8/21/2024 15:09:13 98.245708 191.048035 1.0156968/21/2024 15:10:49 507.572456 511.230053 495.90231 190.895447 1.01267 8/21/2024 15:09:20 98.386461 191.048035 1.0151328/21/2024 15:10:57 507.989926 511.620389 498.607623 190.895447 1.012376 8/21/2024 15:09:28 98.842381 191.048035 1.014881 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/21/2024 15:08:35 0.312532 0.325222 0.90926 191.048035 1.024845 8/21/2024 15:11:33 0.296808 190.895447 1.0180538/21/2024 15:08:43 0.364196 0.035138 0.234221 191.048035 1.024587 8/21/2024 15:11:41 -0.909427 190.895447 1.0180588/21/2024 15:08:50 0.063147 0.0401 -0.046621 191.048035 1.024669 8/21/2024 15:11:48 -0.573781 190.895447 1.017368 8/21/2024 15:08:58 0.07227 0.070924 0.67187 191.048035 1.024361 8/21/2024 15:11:56 0.000556 190.895447 1.0172228/21/2024 15:09:05 0.088957 -0.316603 0.243633 191.048035 1.017614 8/21/2024 15:12:03 -0.778725 190.895447 1.017199 8/21/2024 15:09:13 0.083993 -0.101002 -0.64494 191.048035 1.015696 8/21/2024 15:12:11 -0.207926 190.895447 1.0171378/21/2024 15:09:20 -0.049358 0.051755 0.263178 191.048035 1.015132 8/21/2024 15:12:18 -0.703325 190.895447 1.0171418/21/2024 15:09:28 0.210544 -0.077159 0.348329 191.048035 1.014881 8/21/2024 15:12:26 -0.238878 190.895447 1.016895 POST SYSTEM ZERO SAMPLE SPIKE RECOVERY POST SYSTEM CAL PRE TEST 1 501.6 11.1 0.6 10.0 46.5 0.099 83.0% Sensor Analyzer Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Error (%)Error (%) NOx 507.1 512.4 -0.1 -1.03 -0.01 CO 501.3 507.5 0.1 -1.22 0.01 Propane 495.0 501.6 0.0 -1.32 0.00 Ethylene 99.7 101.90 -0.1 -2.12 -0.09 Sensor System Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Recovery (%)Error (%) NOx 508.8 512.4 0.1 -0.71 0.02 CO 504.2 507.5 0.3 -0.66 0.07 Propane 498.1 501.6 0.2 -0.69 0.03 Ethylene*98.8 101.90 1.8 -3.06 1.77 Sensor System Cal Zero Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Recovery (%)Error (%)Drift Error (%)Drift Error (%) NOx 511.6 512.4 0.0 -0.15 0.00 0.55 0.02 CO 508.0 507.5 0.1 0.10 0.03 0.75 0.04 Propane 498.6 501.6 0.2 -0.60 0.05 0.10 0.01 Ethylene*98.8 101.90 -0.4 -3.00 -0.39 0.06 2.16 *CTS Scans are conducted with Ethylene through the sample line. Stack Propane Concentration Stack + Spike CO2 Concentration Stack + Propane Concentration DF Calculated POST SYSTEM CAL PRE SYSTEM CAL % Recovery Propane PRE DIRECT CAL FTIR QA/QC SUMMARY SAMPLE RECOVERY CALCULATIONS Period Spike #Concentration of Propane Cylinder Stack CO2 Concentration XCL – Gilbert/Myrin 2 8-21-24 XCL – Gilbert/Myrin 2 8-21-24 XCL – Gilbert/Myrin 2 8-21-24 Spectral Fit Run 1 Spectral Fit Run 2 Spectral Fit Run 3 Analysis Validation Report Sample Filename: C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000150.LAB Filename for noise: C:\OLT\Data\Golden Spectrum\New FTIR 09-13-23\NEW FTIR 09-13-23_000003.LAB Interferences Filenames: C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000070.LAB C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000071.LAB C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000072.LAB C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000073.LAB C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000074.LAB C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000075.LAB C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000076.LAB C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000077.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 21.46 2.58 -0.18 0.25 3.52 3.52 -1.82 --0-2795 1.04 Good NO2 191C 0.58 0.39 0.25 0.02 0.02 0.42 0.42 0.26 0.36 0.01 0.08 0-488 1 Close to DL N2O 191C 1.31 0.36 3.06 0.02 0.02 0.42 0.42 3.42 3.42 0.37 1.02 0-200 -Close to DL NH3 TE 191C 6.24 20.83 9.32 2.05 3.49 35.55 35.55 10.87 18.77 1.55 3.11 0-2995 -Close to DL H2O% (HIGH) 191C18.77 0.24 -0.01 0.01 0.37 0.37 -0.38 --0-40 -Good FORMALDEHYDE 191C-0.18 0.54 0.34 0.16 0.18 0.61 0.61 0.54 0.54 0.2 0.11 0-69 1.18 Close to DL FORMIC ACID 191C TE0.75 3.29 2.15 0.7 0.82 3.86 3.86 2.37 2.59 0.23 0.72 0-466 -Close to DL CH4 2900 CM-1 191C5.21 2.64 21.82 0.85 1.23 3.84 3.84 24.4 24.4 2.58 7.27 0-3143 0.98 Close to DL PROPANE 191C 0.47 0.5 0.75 0.11 0.13 0.6 0.6 0.88 0.88 0.13 0.25 0-4976 0.95 Close to DL PROPYLENE 191C TE1.07 3.69 4.05 0.78 0.93 4.36 4.36 4.33 4.33 0.28 1.35 0-194 -Close to DL ETHANE 191C 0.26 1.14 0.84 0.26 0.4 1.77 1.77 0.87 0.88 0.04 0.28 0-1004 -Close to DL ETHYLENE 191C TE2.43 9.32 2.64 1.01 1.24 11.5 11.5 3.25 8.26 0.61 0.88 0-900 -Close to DL CO PPM 191C (1OF2)30.78 1.77 -0.15 0.33 3.77 3.77 -0.93 --0-5010 1.03 Good CO2% 191C 10.09 0.24 -0.01 0.01 0.33 0.33 -0.2 --0-23 -Good CO% 191C (2OF2)0 0 0 0 0 0 0 0 0 0 0 0-8 -Close to DL ACETALDEHYDE 191C-0.7 1.23 1.46 0.36 0.46 1.58 1.58 1.64 1.64 0.18 0.49 0-186 0.98 Close to DL ACETYLENE 191C-0.39 2.53 0.67 0.36 0.48 3.33 3.33 0.94 2.17 0.27 0.22 0-1016 -Close to DL SO2 191C 5.98 5.25 2 0.24 0.29 6.4 6.4 2.48 4.87 0.48 0.67 0-964 1.02 Close to DL HEXANE 191C -0.06 0.31 0.23 0.06 0.09 0.41 0.41 0.35 0.35 0.11 0.08 0-1000 -Close to DL Analysis Validation Report Sample Filename: C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000210.LAB Filename for noise: C:\OLT\Data\Golden Spectrum\New FTIR 09-13-23\NEW FTIR 09-13-23_000003.LAB Interferences Filenames: C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000070.LAB C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000071.LAB C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000072.LAB C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000073.LAB C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000074.LAB C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000075.LAB C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000076.LAB C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000077.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 17.58 2.08 -0.18 0.25 2.84 2.84 -1.44 --0-2795 1.04 Good NO2 191C 0.75 0.44 0.25 0.02 0.02 0.46 0.46 0.26 0.4 0.01 0.08 0-488 1 Close to DL N2O 191C 3.98 0.35 3.06 0.02 0.02 0.4 0.4 3.42 3.42 0.37 1.02 0-200 -Close to DL NH3 TE 191C 3.45 20.14 9.32 2.05 3.49 34.38 34.38 10.87 18.17 1.55 3.11 0-2995 -Close to DL H2O% (HIGH) 191C19.93 0.21 -0.01 0.01 0.33 0.33 -0.4 --0-40 -Good FORMALDEHYDE 191C-0.17 0.59 0.34 0.16 0.18 0.66 0.66 0.54 0.54 0.2 0.11 0-69 1.18 Close to DL FORMIC ACID 191C TE0.02 3.65 2.15 0.7 0.82 4.28 4.28 2.37 2.98 0.23 0.72 0-466 -Close to DL CH4 2900 CM-1 191C27.53 3.28 21.82 0.85 1.23 4.76 4.76 24.4 24.41 2.58 7.27 0-3143 0.98 Close to DL PROPANE 191C 0.63 0.53 0.75 0.11 0.13 0.63 0.63 0.88 0.88 0.13 0.25 0-4976 0.95 Close to DL PROPYLENE 191C TE2.61 3.99 4.05 0.78 0.93 4.72 4.72 4.33 4.33 0.28 1.35 0-194 -Close to DL ETHANE 191C 0.41 1.29 0.84 0.26 0.4 2.01 2.01 0.87 1.03 0.04 0.28 0-1004 -Close to DL ETHYLENE 191C TE2.38 9.18 2.64 1.01 1.24 11.33 11.33 3.25 8.13 0.61 0.88 0-900 -Close to DL CO PPM 191C (1OF2)33.08 1.4 -0.15 0.33 2.98 2.98 -0.71 --0-5010 1.03 Good CO2% 191C 9.98 0.23 -0.01 0.01 0.32 0.32 -0.2 --0-23 -Good CO% 191C (2OF2)0 0 0 0 0 0 0 0 0 0 0 0-8 -Close to DL ACETALDEHYDE 191C-0.55 1.3 1.46 0.36 0.46 1.66 1.66 1.64 1.64 0.18 0.49 0-186 0.98 Close to DL ACETYLENE 191C-0.32 2.36 0.67 0.36 0.48 3.12 3.12 0.94 2.01 0.27 0.22 0-1016 -Close to DL SO2 191C 5.97 5.63 2 0.24 0.29 6.86 6.86 2.48 5.25 0.48 0.67 0-964 1.02 Close to DL HEXANE 191C -0.18 0.34 0.23 0.06 0.09 0.46 0.46 0.35 0.35 0.11 0.08 0-1000 -Close to DL Analysis Validation Report Sample Filename: C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000270.LAB Filename for noise: C:\OLT\Data\Golden Spectrum\New FTIR 09-13-23\NEW FTIR 09-13-23_000003.LAB Interferences Filenames: C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000070.LAB C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000071.LAB C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000072.LAB C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000073.LAB C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000074.LAB C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000075.LAB C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000076.LAB C:\OLT\Data\XCL\Gilbert-Myrin 2 E2 08-21-24\GILBERT-MYRIN 2 E2 08-21-24_000077.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 18.41 2.68 -0.18 0.25 3.66 3.66 -2 --0-2795 1.04 Good NO2 191C 0.8 0.48 0.25 0.02 0.02 0.51 0.51 0.26 0.44 0.01 0.08 0-488 1 Close to DL N2O 191C 5.41 0.47 3.06 0.02 0.02 0.54 0.54 3.42 3.42 0.37 1.02 0-200 -Close to DL NH3 TE 191C 4.73 20.73 9.32 2.05 3.49 35.39 35.39 10.87 18.72 1.55 3.11 0-2995 -Close to DL H2O% (HIGH) 191C18.34 0.27 -0.01 0.01 0.43 0.43 -0.37 --0-40 -Good FORMALDEHYDE 191C-0.18 0.62 0.34 0.16 0.18 0.7 0.7 0.54 0.54 0.2 0.11 0-69 1.18 Close to DL FORMIC ACID 191C TE0.42 3.6 2.15 0.7 0.82 4.21 4.21 2.37 2.91 0.23 0.72 0-466 -Close to DL CH4 2900 CM-1 191C43.18 3.48 21.82 0.85 1.23 5.86 5.86 24.4 24.42 2.58 7.27 0-3143 0.98 Close to DL PROPANE 191C 0.69 0.54 0.75 0.11 0.13 0.64 0.64 0.88 0.88 0.13 0.25 0-4976 0.95 Close to DL PROPYLENE 191C TE2.66 4.09 4.05 0.78 0.93 4.84 4.84 4.33 4.33 0.28 1.35 0-194 -Close to DL ETHANE 191C 0.9 1.29 0.84 0.26 0.4 2.01 2.01 0.87 1.02 0.04 0.28 0-1004 -Close to DL ETHYLENE 191C TE2.73 9.81 2.64 1.01 1.24 12.1 12.1 3.25 8.74 0.61 0.88 0-900 -Close to DL CO PPM 191C (1OF2)38.77 1.8 -0.15 0.33 3.73 3.73 -0.92 --0-5010 1.03 Good CO2% 191C 10.11 0.24 -0.01 0.01 0.33 0.33 -0.2 --0-23 -Good CO% 191C (2OF2)0 0 0 0 0 0 0 0 0 0 0 0-8 -Close to DL ACETALDEHYDE 191C-0.63 1.35 1.46 0.36 0.46 1.73 1.73 1.64 1.64 0.18 0.49 0-186 0.98 Close to DL ACETYLENE 191C-0.53 2.55 0.67 0.36 0.48 3.37 3.37 0.94 2.19 0.27 0.22 0-1016 -Close to DL SO2 191C 6.25 5.4 2 0.24 0.29 6.59 6.59 2.48 5.02 0.48 0.67 0-964 1.02 Close to DL HEXANE 191C -0.12 0.34 0.23 0.06 0.09 0.46 0.46 0.35 0.35 0.11 0.08 0-1000 -Close to DL APPENDIX C Test Run Load %Site Rated Load, bhp Load Approx., bhp 1 100 1680 1680.0 2 100 1680 1680.0 3 100 1680 1680.0 Engine Load Approximation based on Panel Levels APPENDIX D Test Run Flowrate dscfm Approx. BHP Avg O2 % NOx ppmvd NOx g/bhp-hr NOx lbs/hr CO ppmvd CO g/bhp-hr CO lbs/hr NMNEHC ppmvd NMNEHC g/bhp-hr NMNEHC lbs/hr Moisture Content % 1 1828.42 1680.0 0.0 25.30 0.09 0.33 41.52 0.09 0.33 2.36 0.01 0.03 18.75 2 1771.96 1680.0 0.0 24.50 0.08 0.31 41.49 0.09 0.32 3.54 0.01 0.04 18.89 3 1832.44 1680.0 0.0 24.56 0.09 0.32 47.21 0.10 0.38 5.10 0.02 0.06 18.76 1680.0 0.0 24.79 0.09 0.32 43.41 0.09 0.34 3.66 0.01 0.05 18.80 Summary Average Levels Example Calculations: XCL Resources, Gilbert/Myrin 2, AG18227 (101764) The following is a step-by-step calculation for the first test run conducted on the Gilbert/Myrin 2 AG18227 (101764). Test Parameters • Stack Diameter = 12 inches • Traverse Points = 16 • Ports = 2 • Barometric Pressure = 24.68 in Hg • Average O2 = 0.0% • Average CO2 = 12.4% • Load Approximation = 1680.0 bhp • Moisture Content = 18.75% EPA 40 CFR 60(A) Methods 1-3: Determination of Stack Gas Velocity and Flow Rate Dry Molecular Weight (lb/lbmol) = (0.44 * %CO2) + (0.32 * %O2) + ((0.28 * (%N2 + %CO)) Where: %CO2 – Carbon Dioxide Content Of The Gas = 12.4% %O2 – Oxygen Content Of The Gas = 0.0% %N2 – Nitrogen Content Of The Gas %CO – Carbon Monoxide Content Of The Gas (%N2 +%CO) = (100 - %O2 - %CO2) = (100 – 0.0 – 12.4) = 87.6% Dry = (0.44 * %CO2) + (0.32 * %O2) + ((0.28 * (%N2 + %CO)) = (0.44 * 12.4) + (0.32 * 0.0) + (0.28 * 87.6) = 29.98 lb/lbmol Wet Molecular Weight (lb/lbmol) = MD * (1-BWS) + (18) * BWS Where: MD – Molecular Weight Of The Dry Gas (lb/lbmol) = 29.98 lb/lbmol BWS – Moisture Content Of The Gas (%/100) = 18.75% = MD * (1-BWS) + (18) * BWS = 29.98 * (1 – (18.75/ 100)) + (18 * (18.75/ 100)) = 27.74 lb/lbmol Average Stack Gas Velocity (ft/sec) = Cp * (85.49) * ∆PAVG * (TS / (((PS / 13.6) + PB) * MA)) Where: CP – Pitot tube constant (unitless) = 0.84 ∆PAVG – Average square root of the stack gas pitot DP (inches water) = 1.396 in H2O TS – Average stack temperature (R) = 1223 R PB – Barometric pressure (in Hg) = 24.68 in Hg PS – Stack pressure relative to barometric pressure (inches water) = 0.8 in H2O MA – Molecular weight of the wet gas (lb/lbmol) = 27.74 lb/lbmol = Cp * (85.49) * ∆PAVG * (TS / (((PS / 13.6) + PB) * MA)) = 0.84 * (85.49) * 1.396 * ( 1223 / (((0.8/ 13.6) + 24.68) * 27.74)) = 133.80 ft/sec Average Dry Flowrate (dscfm) = 60 * (1-BWS) * VS * * (((DS / 2) / 12))2)* TSTD / TS * (PB + (PS / 13.6)) / 29.92 Where: DS – Diameter of the stack (inches) = 12 inches BWS – Moisture content of the gas (%) = 18.75% TSTD – Standard temperature (528R) TS – Average stack temperature (R) = 1223 R PB – Barometric pressure (in Hg) = 24.68 in Hg PS – Stack pressure relative to barometric pressure (inches water) = 0.8 in H2O VS– Average Stack gas velocity (ft/sec) = 133.80 ft/sec = 60 * (1-BWS) * VS * * (((DS / 2) / 12))2)* TSTD / TS * (PB + (PS / 13.6)) / 29.92 = 60 * (1 - (18.75/ 100)) * 133.80 * * (((12 / 2) / 12))2) * 528 / 1223 * (24.68 + (0.8 / 13.6)) / 29.92 = 1828.42 dscfm Conversion of Dry Flowrate to m3/hr = Q * 60 * 2.83168*10 -2 Where: Q – Volumetric Flowrate = 1828.42 dscfm 2.83168*10 -2 – Conversion factor for cubic feet to cubic meter 60 – Minutes in an hour = Q * 60 * 2.83168*10 -2 = 1828.42 *60 * 2.83168*10 -2 = 3106.5 m3/hr ASTM D 6348-03: Determination of NOx, CO and VOC Emissions From Stationary Sources NOx Emission Rate (g/Bhp-hr) = (Cd * 1.912*10 -3 * Q * T) / HP-hr Where: Cd – Measured NOx concentration in ppm = 25.30 ppm 1.92*10 -3 - Conversion constant for ppm to g/m3 NOx Q – Volumetric Flowrate = 3106.5 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 1680.0 Bhp = (Cd * 1.912*10 -3 * Q * T) / HP-hr = (25.30 * 1.912*10 -3 * 3106.5 * 1) / 1680.0 = 0.09 g/Bhp-hr NOx Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.09 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 1680.0 Bhp = g/Bhp-hr / 454 * Bhp = 0.09 / 454 * 1680.0 = 0.33 lbs/hr CO Emission Rate (g/Bhp-hr) = (Cd * 1.164*10 -3 * Q * T) / HP-hr Where: Cd – Measured CO concentration in ppm = 41.52 ppm 1.164*10 -3 - Conversion constant for ppm to g/m3 CO Q – Volumetric Flowrate = 3106.5 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 1680.0 Bhp = (Cd * 1.164*10 -3 * Q * T) / HP-hr = (41.52 * 1.164*10 -3 * 3106.5 * 1) / 1680.0 = 0.09 g/Bhp-hr CO Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.09 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 1680.0 Bhp = g/Bhp-hr / 454 * Bhp = 0.09 / 454 * 1680.0 = 0.33 lbs/hr VOC Emission Rate (g/Bhp-hr) = (Cd * 1.833*10 -3 * Q * T) / HP-hr Where: Cd – Measured VOC concentration in ppm = 2.36 ppm 1.833*10 -3 - Conversion constant for ppm to g/m3 VOC Q – Volumetric Flowrate = 3106.5 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 1680.0 Bhp = (Cd * 1.833*10 -3 * Q * T) / HP-hr = (2.36 * 1.833*10 -3 * 3106.5 * 1) / 1680.0 = 0.01 g/Bhp-hr VOC Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.01 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 1680.0 Bhp = g/Bhp-hr / 454 * Bhp = 0.01 / 454 * 1680.0 = 0.03 lbs/hr APPENDIX E FTIR Engine Test Sheet Company Name Location I Unit 1.0. /yi Jher-/--1IfJ v7"n 7~F 2 Type of Test Completed Field Technician (s) Client Rep and/or State Rep Date Jordan Nix o Cjf/2-IIZJ1 Non-Resettable Run Time Hours 1/1-5 Stack Diagram T A t B 1 504.9 198.7 145.7 512.4 501.6 101.9 507.5 Concentration 1)zC; s sot hI)h I If II 37" Cvtinder# I z...11 CC496385 CC275071 CC431764 CC725093 CC725093 CC725093 CC725093Methane (ppm) Acetaldehyde (ppm) N02 (ppm) Propane ppm) CO (ppm Calibration Gas NO (ppm Exhaust Diameter (inches) Ethylene (ppm) Engine Model Engine Make Test 1 Test 2 Test 3 Time of Reading . 1/6 s Iit-"-ii/3!J .~ Atm Pressure (in Hg) z: lr,693 z,,1(,6~ Zt;; 67' Atm Temp CF) .gz.. --q,1./ 99 Engine RPM 1132//""5 z./1 "3('5 , *Manifold Pres. ~r Boost(psi) or Boost (psia) -. 3!.r; 9"i 4~7i 39,'7f Manifold Temo fF) -. I.T., ~ 1"3 y..::13'¥ Psuction (psi) Stage 1 '1~b t1G L/,c,. Tsuction CF) Stage 1 ------...- Pdischarae (psi) Staae 1 JAr:: In t: / r» 71 Psuction (psi) Stage 2 ----Tsuction CF) Stage 2 ~ --Pdischar e (osi) Staae 2 111(-, WIIJ.-"1/:::;:- Psuction (psi) Stage 3 --_. -Tsuction 'F) Stage 3 -'------Pdischarue (psi) Staae 3 , Z-.n 1 IZ-c'7 I £-'/')(7 Psuction psi) Stage 4 Tsuction OF) Stage 4 Pdischarqe (psi) Stage 4 Gas Throuuhout (mmcf/d) or ( ) Pre Cat Temp CF) fZ7 rc-Z?::77? , 2-b Post Cat Temp CF) 71-, ~;;a ~6it 7L6t; Cat Differential Pres. (" of H2O) ~ft; 3.'1 S.{ Humidity% --- 02% I? 6 C!> C02 % Dry 17 I-f /2. '1 I~''t LOAD % (PaMlfor (Estimated) \A/ C{ V t:.-.. '00 /00 ICO Ignition Timing CF) /3,<.( I ..... AFR Setting mV (Left Bank) rte or-f. «rroi-I-.-... AFR Settina mV (Riaht Bank) P'~+-o 2o. 6ljLj'// -/ Rev 8 • Some units show boost in inches of Hg. In this situation please indicate if it is positive (+) or negative(-). Eg: (+12") or (- 5") 9/17/2019 Worksheet: O2 Stratification Client:XCL Location:Gilbert-Myrin 2 E2 Date:8/21/2024 PD:12 DD:32 YES Method 1 Criteria Met UD:14 YES Method 1 Criteria Met Port Point Insertion Depth Reading (inches)(%) A 1 1.99 0.00 A 2 6.00 0.00 A 3 10.00 0.00 A 4 A 5 A 6 A 7 A 8 A 9 A 10 A 11 A 12 Average 0.00 Notes: To demonstrate non-stratified flow and utilize one sampling location O2 may not deviate by more than +/- 0.3% of the average O2 concentration. EPA REFERENCE METHOD 3A (Determination Of Stratification) COMPANY NAME:XCL COMPANY LOCATION:Gilbert-Myrin 2 E2 DATE:8/21/24 STACK DIAMETER (inches):12 TRAVERSE POINTS:16 2 TEST RUN #1 TEST RUN #2 TEST RUN #3 AVERAGE O2:0 AVERAGE O2:0 AVERAGE O2:0 AVERAGE CO2:12.4 AVERAGE CO2:12.4 AVERAGE CO2:12.4 BARO PRESSURE:24.68 BARO PRESSURE:24.67 BARO PRESSURE:24.67 Point Insertion DepthDP (H2O)Ts (deg R)Stat P (H2O)Point Insertion DepthDP (H2O)Ts (deg R)Stat P (H2O)Point Insertion DepthDP (H2O)Ts (deg R)Stat P (H2O) 1 0.5 1.53 763 0.75 1 0.5 1.59 764 0.73 1 0.5 1.88 766 0.75 2 1.26 1.84 2 1.26 1.55 2 1.26 2.03 3 2.328 1.88 3 2.328 1.6 3 2.328 2.02 4 3.876 1.98 4 3.876 1.84 4 3.876 1.97 5 8.124 2.09 5 8.124 1.95 5 8.124 1.85 6 9.672 2.11 6 9.672 1.87 6 9.672 1.98 7 10.74 2.07 7 10.74 1.82 7 10.74 2.06 8 11.5 2 8 11.5 1.97 8 11.5 1.84 9 9 9 10 10 10 11 11 11 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16 1 0.5 1.98 763 0.75 1 0.5 1.56 764 0.73 1 0.5 1.75 766 0.75 2 1.26 1.88 2 1.26 1.76 2 1.26 1.99 3 2.328 1.85 3 2.328 1.89 3 2.328 1.89 4 3.876 1.97 4 3.876 2.09 4 3.876 2.08 5 8.124 2.07 5 8.124 1.99 5 8.124 2.12 6 9.672 2.02 6 9.672 2.04 6 9.672 2.06 7 10.74 1.98 7 10.74 2.01 7 10.74 1.93 8 11.5 1.95 8 11.5 1.92 8 11.5 1.96 9 9 9 10 10 10 11 11 11 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16