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HomeMy WebLinkAboutDAQ-2024-0112431 DAQC-1086-24 Site ID 101073 (B4) MEMORANDUM TO: STACK TEST FILE – XCL ASSETCO, LLC – Shiner 30-3A-22 Pad THROUGH: Rik Ombach, Minor Source Oil and Gas Compliance Section Manager FROM: Paul Bushman, Environmental Scientist DATE: October 23, 2024 SUBJECT: Source: One (1) Waukesha L7044GSI engine Contact: Lauren Brown: (713) 808-9406 Location: Duchesne County, UT Test Contractor: Oasis Emission Consultants, Inc. Permit/AO#: Permit by Rule Action Code: TR Subject: Review of stack test report dated August 27, 2024 On October 22, 2024, Utah Division of Air Quality (DAQ) received a test report for one (1) Waukesha L7044GSI engine at Shiner 30-3A-22 Pad, Duchesne County, Utah. Testing was performed August 21, 2024, to demonstrate compliance with the emission limits found in Utah Administrative Code R307-510 and 40 CFR Part 60, Subpart JJJJ. The calculated test results are: Source Test Date Pollutant Method Tester Results DAQ Results Limits Waukesha L7044GSI SN: C-14141/11 August 21, 2024 NOx 320 0.04 g/bhp-hr 0.042 g/bhp-hr 1.0 g/bhp-hr CO 320 0.23 g/bhp-hr 0.227 g/bhp-hr 2.0 g/bhp-hr VOC 320 0.01 g/bhp-hr 0.007 g/bhp-hr 0.7 g/bhp-hr DEVIATIONS: None. CONCLUSION: The stack test report appears to be acceptable. RECOMMENDATION: The emissions from the Waukesha L7044GSI engine should be considered to have been in compliance with the emission limits of UAC R307-510 and 40 CFR Part 60, Subpart JJJJ during testing. ATTACHMENTS: DAQ stack test review excel spreadsheets, XCL AssetCo, LLC stack test report. Emissions XCL Resources Shiner 30-3A-11 Pad Duchesne County Waukesha L7044GSI; SN: C-14141/11 Test Date: 8/21/2024 Run #1 2 3 Average Start Time 7:58 8:58 9:58 Stop Time 8:58 9:58 10:58 Sample Duration (minutes)60 60 60 BHP Engine Load - Actual (bhp) 1159 1159 1159 1159 DS Stack Diameter (inches)8.0 8.0 8.0 8.0PAVG Average (Delta P)½ (" H2O)½1.0220 1.0250 1.0310 1.0260 CP Pitot Tube Constant (unitless)0.84 0.84 0.84 0.84 TS Stack Temperature (°F)972 973 974 973 Pbar Barometric Pressure (" Hg)24.71 24.71 24.71 24.71 Ps Stack Pressure ('' H2O)0.58 0.56 0.59 0.58 O2%vd O2 (%vd)0.0 0.0 0.0 0.0 CO2%vd CO2 (%vd)11.9 11.9 11.9 11.9 N2%vd N2 (%vd)88.1 88.1 88.1 88.1 dry NOX (ppmvd)27.5 27.4 26.9 27.3 dry CO (ppmvd) 246.1 243.5 239.1 242.9 wet NMEOC (ppmvw as C3H8)2.6 3.9 4.5 3.7 Run #1 2 3 Average Bws Measured Moisture Content (%/100)0.191 0.197 0.200 0.196 Bws Saturated Moisture Content (%/100)881.605 885.002 888.276 884.961 Bws Actual Moisture Content (%/100)0.191 0.197 0.200 0.196 MD Molecular Weight Dry (lb/lb-mole)29.90 29.90 29.90 29.90 MA Molecular Weight Wet (lb/lb-mole)27.64 27.56 27.53 27.58 VS Gas Velocity (ft/sec)106.2 106.7 107.4 106.8 FACFM Gas Flow (acfm)2224 2235 2250 2236 FDSCFM Gas Flow (dscfm)549 546 548 548 FWSCFM Gas Flow (wscfm)678 681 685 681 FKWSCFH Gas Flow (kwscfh)41 41 41 41 FKWSCFM Gas Flow (kwscfm)0.678 0.681 0.685 0.681 lb/hr Gas Flow (lb/hr) 2919 2923 2937 2926 Fo Fo (unitless)1.756 1.756 1.756 1.756 wet O2 (%vw)0.0 0.0 0.0 0.0 wet CO2 (%vw)9.6 9.6 9.5 9.6 wet NOX (ppmvw)22.229 22.034 21.501 21.922 15 NOX (ppmvd @ 15% O2)7.752 7.746 7.582 7.694 82.0 lb/hr NOX (lb/hr)0.108 0.107 0.105 0.107 g/bhp-hr NOX (g/bhp-hr)0.042 0.042 0.041 0.042 1.0 wet CO (ppmvw) 199.177 195.498 191.416 195.364 15 CO (ppmvd @ 15% O2)69.459 68.728 67.503 68.563 270.0 lb/hr CO (lb/hr) 0.588 0.580 0.571 0.580 g/bhp-hr CO (g/bhp-hr) 0.230 0.227 0.224 0.227 2.0 dry NMEOC (ppmvd as C3H8)3.180 4.870 5.670 4.573 dry NMEOC (ppmvd as C3H8)3.180 4.870 5.670 4.573 15 NMEOC (ppmvd as C3H8 @ 15% O2)0.898 1.375 1.601 1.291 60.0 lb/hr NMEOC (lb/hr as C3H8)0.012 0.018 0.021 0.017 g/bhp-hr NMEOC (g/bhp-hr as C3H8)0.005 0.007 0.008 0.007 0.7 Permit Limits Field Reference Method Data Reference Method Calculations Page 1 of 1 Source Test Report For XCL Resources Shiner #30-3A-22 Pad Duchesne County, Utah Test Date: August 21, 2024 Report Date: August 27, 2024 Federal Regulation: EPA 40 CFR 60, Subpart JJJJ Engine: Waukesha L7044GSI SN: C-14141/11 Unit ID: 77795 (101073) Prepared By: Oasis Emission Consultants, Inc. 2730 Commercial Way Rock Springs, WY 82901 August 27, 2024 Mr. Ryan Sokolowski XCL Resources Dear Mr. Sokolowski: Re: Engine Emission Testing For XCL Resources, Shiner #30-3A-22 Pad, Unit 77795 (101073), EPA 40 CFR 60, Subpart JJJJ. An air emissions test program was conducted on a Waukesha L7044GSI engine, operated by XCL Resources and designated as Unit 77795 (101073), located at the Shiner #30-3A-22 Pad in Duchesne County, Utah. The purpose of the testing was to demonstrate compliance with the emissions limits contained in EPA 40 CFR 60, Subpart JJJJ, for oxides of nitrogen (NOx), carbon monoxide (CO) and volatile organic compounds (VOC). Oasis Emission Consultants, Inc. conducted the testing on August 21, 2024. EPA 40 CFR 60, Subpart JJJJ Emission Levels The average recorded levels were found to comply with emission levels stipulated in the permit, as shown in the attached report and summarized below. Emission Unit Avg NOx Permit NOx Avg CO Permit CO Avg NMNEHC* Permit VOC g/bhp-hr 0.04 1.0 0.23 2.0 0.01 0.7 *VOC levels reported as non-methane, non-ethane hydrocarbon on a propane basis (NMNEHC C3). Catalyst Parameters (Averaged Over 3 Test Runs) Inlet Temp (deg F) DP (in H2O) 928 0.8 Engine Load (Averaged Over 3 Test Runs) Rated BHP Operating BHP % Load 1680 1159.2 69.0 Testing Protocol The attached report was generated using an extractive FTIR system using methodologies as required by and in accordance with EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320 as outlined in the submitted Source Test Protocol. Quality Assurance Oasis has performed a full review of the raw data and calculated results in this report. Any errors we have encountered have been listed in the body of this report. After performing the review, we are confident that this engine has met all requirements. If you have any questions or require further information, please contact the undersigned at (307) 382-3297. Yours truly, Oasis Emission Consultants, Inc. _________________________ _______________________ Charles A. Chapman Cember Crawley Manager of Technical Services Environmental Scientist _________________________ Christopher N. Knott, P.Eng. Director, Engineering and Operations SOURCE EMISSION TEST REPORT FEDERAL REGULATION EPA 40 CFR 60, Subpart JJJJ Test Performed By: Oasis Emission Consultants, Inc. Test Company Contact: Chris Knott 2730 Commercial Way Rock Springs, WY 82901 307.382.3297 Owner/Operator: XCL Resources Owner/Operator Contact: Ryan Sokolowski Facility Name: Shiner #30-3A-22 Pad Duchesne County, Utah Emission Source: Waukesha L7044GSI Unit 77795 (101073) Date of Test: August 21, 2024 Date of Report: August 27, 2024 TABLE OF CONTENTS 1.1 Introduction .......................................................................................................................... 1 2.1 Stack Sampling Location ..................................................................................................... 2 3.1 Discussion of NOx, CO and VOC Test Results ................................................................... 4 3.1.1 Source Test 1 ............................................................................................................................................ 4 3.1.2 Source Test 2 ............................................................................................................................................ 4 3.1.3 Source Test 3 ............................................................................................................................................ 4 4.1 Stack Sampling Methods and Procedures ............................................................................ 5 4.2 Equipment Utilization .......................................................................................................... 6 4.3 Measurement of VOC (NMNEHC C3) ............................................................................... 7 4.4 Process Parameters............................................................................................................... 7 5.1 Quality Assurance ................................................................................................................ 8 List of Tables and Figures Figure 1 - Sample Port Location ............................................................................................................................. 2 Figure 2 - Sampling Train Schematic-Method 320 ................................................................................................ 6 Table 1 - Insertion Depths of Traverse Points for Stratification Test ..................................................................... 3 Table 2 - Location of Traverse Points in Circular Stacks ....................................................................................... 3 Table 3 - Test Matrix .............................................................................................................................................. 5 Table 4 - Concentrations and Interference .............................................................................................................. 6 APPENDIX A: NOx, CO and VOC Test Data APPENDIX B: Quality Assurance/Calibration Data APPENDIX C: Load Approximation APPENDIX D: Example Calculations and Summary APPENDIX E: Field Notes 1 1.1 Introduction An air emissions test program was conducted on a Waukesha L7044GSI engine, operated by XCL Resources and designated as Unit 77795 (101073), located at the Shiner #30-3A-22 Pad in Duchesne County, Utah. The purpose of the testing was to demonstrate compliance with the emissions limits contained in EPA 40 CFR 60, Subpart JJJJ, for oxides of nitrogen (NOx), carbon monoxide (CO) and volatile organic compounds (VOC) defined as non- methane, non-ethane hydrocarbons, reported as propane (NMNEHC C3). The facility is currently located in Duchesne County, Utah. Three one hour test runs were performed on August 21, 2024 to analyze NOx, CO and VOC emission levels. Test runs were performed according to methodologies outlined by EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320 as outlined in the submitted Source Test Protocol. Each one hour test run consisted of 60 readings taken at one minute intervals. Process parameters were recorded during each test run in order to determine the load. Parameters include the engine panel load percent reading. The following key personnel were present during testing: Jordan Nix, OEC Branden A 2 2.1 Stack Sampling Location The facility is currently located in Duchesne County, Utah. Testing was conducted on the Waukesha L7044GSI engine. The sampling port for moisture, NOx, CO and VOC measurements was approximately 3.0 pipe diameters (24”) downstream from the nearest flow disturbance (Distance B) and 0.8 pipe diameters (6”) upstream from the nearest disturbance (Distance A), as seen in Figure 1. The stack sampling location was placed at approximately 50% insertion depth based on an O2 stratification check which demonstrated a non-stratified flow regime. The stratification was conducted according to EPA 40 CFR 75(A), §6.5.6.1 using 3 traverse points determined according to Table 1 below. In accordance with EPA 40 CFR 60(A), Method 1, a total of 16 traverse insertion depths (8 traverse points through each of the 2 ports) were determined according to Table 2 below in order to conduct Method 2. Figure 1 - Sample Port Location 8" A B 3 Table 1 - Insertion Depths of Traverse Points for Stratification Test Traverse Point Insertion Depth (Percent of Stack Diameter) 1 16.6 2 50.0 3 83.3 Table 2 - Location of Traverse Points in Circular Stacks 4 3.1 Discussion of NOx, CO and VOC Test Results Three, one hour test runs were performed on August 21, 2024 to analyze exhaust NOx, CO and VOC (NMNEHC C3) emission levels to demonstrate compliance with the emissions limits contained in EPA 40 CFR 60, Subpart JJJJ. Testing for NOx, CO and VOC were run concurrently with one another. Each test was performed at the maximum achievable load. Measured emissions were below permitted limits. Please refer to the Appendices for a listing of all raw data, calibration error response and calculations performed per EPA 40 CFR 60(A) requirements. 3.1.1 Source Test 1: Waukesha L7044GSI, NOx, CO and VOC The first test was performed from 7:58 to 8:57 for NOx, CO and VOC. Based on operating parameters recorded during testing, the load was approximated at 1159.2 bhp, and the average NOx and CO levels were found to be 0.04 g/bhp-hr and 0.23 g/bhp-hr respectively, below limitations. The VOC level tested at 0.00 g/bhp- hr, which tested in compliance. 3.1.2 Source Test 2: Waukesha L7044GSI, NOx, CO and VOC The second test was performed from 8:58 to 9:57 for NOx, CO and VOC. Based on operating parameters recorded during testing, the load was approximated at 1159.2 bhp, and the average NOx and CO levels were found to be 0.04 g/bhp-hr and 0.23 g/bhp-hr respectively, below limitations. The VOC level tested at 0.01 g/bhp- hr, which tested in compliance. 3.1.3 Source Test 3: Waukesha L7044GSI, NOx, CO and VOC The third test was performed from 9:58 to 10:57 for NOx, CO and VOC. Based on operating parameters recorded during testing, the load was approximated at 1159.2 bhp, and the average NOx and CO levels were found to be 0.04 g/bhp-hr and 0.22 g/bhp-hr respectively, below limitations. The VOC level tested at 0.01 g/bhp- hr, which tested in compliance. Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) VOC (ppmvd) VOC (g/bhp-hr) O2 (%) 1 27.46 0.04 246.05 0.23 3.18 0.00 0.0 Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) VOC (ppmvd) VOC (g/bhp-hr) O2 (%) 2 27.44 0.04 243.46 0.23 4.87 0.01 0.0 Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) VOC (ppmvd) VOC (g/bhp-hr) O2 (%) 3 26.86 0.04 239.12 0.22 5.67 0.01 0.0 5 4.1 Stack Sampling Methods and Procedures Testing followed EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320, with no exceptions. Table 3 - Test Matrix Method Title Parameter Reference EPA 40 CFR 60 Appendix A, Method 1 Sample and Velocity Traverses for Stationary Sources Sampling Point Determination https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_1_3.pdf EPA 40 CFR 60 Appendix A, Method 2 Determination of Stack Gas Velocity and Volumetric Flow Rate Exhaust Effluent Flow https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_2.pdf EPA 40 CFR 60 Appendix A, Method 3 Gas Analysis for the Determination of Dry Molecular Weight O2, CO2, Dry Volumetric Flow Rate https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_3.pdf EPA 40 CFR 63 Appendix A, EPA Method 320 Vapor Phase Organic and Inorganic Emissions by Extractive FTIR Nitrogen Oxides, Carbon Monoxide, Non- Methane Non- Ethane Hydrocarbons on a Propane Basis https://www.epa.gov/ emc/method-320- vapor-phase-organic- and-inorganic- emissions-extractive- ftir United States. U.S. Environmental Protection Agency. “EMC Promulgated Test Methods.” Air Emission Measurement Center (EMC). 31 August 2023. Web. 27 August 2024. <https://www.epa.gov/emc/emc-promulgated-test-methods>. 6 4.2 Equipment Utilization The following equipment was used during the tests performed at this facility in conjunction with procedures outlined by EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320. • (1) MKS MultiGas 2030 FTIR Continuous Gas Analyzer (0.210 L/min sample flow, 0.014 atmosphere sample pressure, 1 atmosphere cell pressure, 191°C cell temperature) • (1) Laptop Computer for the FTIR Analyzer using MKS MG2000 Software • (1) 75ft or 100ft Heated Teflon Line w/ Heated Sample Probe and Spike Bypass Line • S-Type Pitot Tube c/w 20 ft. Heated Sample Line (coefficient 0.84) • (1) Fyrite O2/CO2 Analyzer • (5) EPA Protocol G1 Calibration Gas (NOx, CO, C3H8, C2H4 and NO2) The MKS Multigas 2030 FTIR Analyzer operated with a spectral resolution of 0.5 cm-1 and a scan time of 30 seconds. The FTIR spectrometer utilizes a multi-pass gas cell with a 5.11 meter effective pathlength. Figure 2 - Sampling Train Schematic-Method 320 Table 4 - Concentrations and Interference 7 The MKS 2030 software provides a Natural Gas Method that is designed to minimize all expected interferences by removing the regions in the quant region where they are most absorbed (i.e. picket fence approach). So, for example, all the water peaks that are greater than about 0.1 abs are removed from the quant region. Since the spectral noise measured (sample spectrum) is in the range of 0.001 absorbance, it is desirable to have any error within this range. The MKS software will match the water calibration spectrum to the sample spectrum at any 1 point in the spectrum to about 1% precision. So, 1% of 0.1 absorbance is 0.001 abs. This is why any peaks greater than this for interfering compounds are usually excluded so they do not interfere. To summarize, the MKS software and the method are designed to minimize any interferences by removing their largest interfering absorptions. 4.3 Measurement of VOC (NMNEHC C3) The algorithm currently used for NMNEHC C3 and developed for natural gas fired applications by Dr. Spartz and MKS instruments in accordance with EPA standards, is the following: (2.4*c8/(1+exp((2-c8)/0.2))+1.9*c11/(1+exp((2-c11)/0.2))+6*c12/(1+exp((0.5-c12) /0.2))+2.85*c13/(1+exp((2-c13)/0.2))+3*c14/(1+exp((1-c14)/0.2)))/3 c8= acetylene c11= ethylene c12= hexane c13= propylene c14= propane Note: The constants in front of each of the compounds listed represents the FID response factor when calibrated with Propane. As with any CEMS analyzer, the FTIR may demonstrate a negative zero bias. The “exp” functions listed in the algorithm above are intended to mathematically filter out any negative biases and set them to approach zero. 4.4 Process Parameters Process parameters were recorded during each test run in order to determine the load. Parameters include the engine panel load percent reading. Results are provided in Appendix C. 8 5.1 Quality Assurance The MKS Multigas 2030 FTIR Analyzer was used to measure NOx, CO and VOC on a dry basis. A pre Direct and System calibration measurement was made on compounds of NOx, CO, C3H8 and C2H4. In addition, post System calibrations were made on compounds of NOx, CO, C3H8 and C2H4. Compounds of CO2 and C3H8 were measured for the quality assurance spiking requirements. Levels for calibrations and zeroes must be within +/- 5% of the certified calibration gas or response to zero gas, respectively. CTS procedures were followed according to EPA requirements for both pre and post testing. Similarly, QA spiking procedures were followed. Analysis of the CO2 exhaust effluent was used to determine the dilution factor. Steady levels of the CO2 were observed and a sufficient duration of time was allowed to elapse for a representative average. The calibration gas was spiked into the effluent stream using a bypass line at approximately 10% of the sampling rate. The dilution factor was obtained from observation of the stack CO2 behavior using the following equation: CO2AVG – CO2SPIKE DF = ------------------------ CO2 AVG Where: CO2AVG = The average undiluted CO2 stack gas concentration of spike measurements CO2SPIKE = The average diluted CO2 stack gas concentration when spiked The sample recovery was then obtained from the following equation: % REC = (Spike MEAS – Stack MEAS)* (1 – DF) --------------------------------------------------------- CS * DF Where: Spike MEAS = The average diluted stack gas concentration when spiked Stack MEAS = The average undiluted stack gas concentration DF = Dilution factor CS = Certified concentration of calibration standards The Sample Recovery average level for C3H8 was found to be 88.8%, which was within the allowable tolerance of Method 320 (70% to 130%). A summary of all spiking procedures/results can be found in Appendix B. APPENDIX A NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 25.613075 -0.121187 25.491888 222.098398 1.198146 6.556663 7:58:25 08/21/2024 2 27.524436 -0.03045 27.493986 275.089139 2.409283 8.944835 7:59:25 08/21/2024 3 27.462141 0.027802 27.489943 248.743673 2.834629 14.843689 8:00:25 08/21/2024 4 27.49294 0.287277 27.780217 227.536019 2.898398 18.800993 8:01:25 08/21/2024 5 27.620472 0.013373 27.633845 258.933497 3.574223 19.230181 8:02:25 08/21/2024 6 26.773911 0.476382 27.250293 201.661938 3.414929 23.253907 8:03:26 08/21/2024 7 27.986586 0.273816 28.260402 265.544768 3.202074 20.472949 8:04:26 08/21/2024 8 27.573248 0.442552 28.0158 246.238533 2.577042 16.996445 8:05:26 08/21/2024 9 28.254763 0.620597 28.87536 279.780095 2.980985 21.764027 8:06:26 08/21/2024 10 27.163094 0.406136 27.56923 255.619156 2.639619 19.794929 8:07:26 08/21/2024 11 26.794051 0.415064 27.209115 201.749 2.953069 18.881188 8:08:26 08/21/2024 12 26.725568 0.403798 27.129366 251.489916 2.593970 19.296984 8:09:26 08/21/2024 13 27.768657 0.276033 28.04469 258.437008 3.994604 18.207077 8:10:26 08/21/2024 14 27.524402 0.300004 27.824406 244.096684 3.559477 18.367785 8:11:27 08/21/2024 15 28.25378 0.37304 28.62682 292.395215 3.404646 19.495431 8:12:27 08/21/2024 16 27.979672 0.384038 28.36371 252.844352 2.834008 17.336637 8:13:27 08/21/2024 17 25.572961 0.378628 25.951589 204.955184 3.404387 18.964176 8:14:27 08/21/2024 18 27.449033 0.192354 27.641387 256.704959 2.449626 19.895783 8:15:27 08/21/2024 19 27.132187 0.366319 27.498506 239.664163 2.821995 18.389916 8:16:27 08/21/2024 20 26.411759 0.190063 26.601822 226.189719 3.689953 18.314538 8:17:27 08/21/2024 21 27.504905 -0.865609 26.639296 250.419512 3.244671 21.595425 8:18:27 08/21/2024 22 27.90688 0.484797 28.391677 252.51236 3.758303 17.04932 8:19:28 08/21/2024 23 26.705383 0.012193 26.717576 255.151291 2.886058 20.74387 8:20:28 08/21/2024 24 27.306517 0.243548 27.550065 248.981569 3.043091 20.903453 8:21:28 08/21/2024 25 26.665206 0.409752 27.074958 217.402498 3.239858 18.420943 8:22:28 08/21/2024 26 26.054059 0.510561 26.56462 209.193709 2.732191 21.490156 8:23:28 08/21/2024 27 26.754988 0.389074 27.144062 219.825641 2.818713 19.283147 8:24:28 08/21/2024 28 28.310703 0.557472 28.868175 283.293975 2.363083 22.399814 8:25:28 08/21/2024 29 26.88957 0.314846 27.204416 236.643636 2.676387 19.028794 8:26:29 08/21/2024 30 26.606486 0.350867 26.957353 231.209421 2.531182 18.857706 8:27:29 08/21/2024 31 27.572084 0.408301 27.980385 249.085276 3.166967 19.843427 8:28:29 08/21/2024 32 27.027476 0.462918 27.490394 213.338441 3.471419 22.293028 8:29:29 08/21/2024 33 25.652959 0.213454 25.866413 198.814773 3.337551 23.029229 8:30:29 08/21/2024 34 27.815936 0.43275 28.248686 278.993427 3.495100 18.227014 8:31:29 08/21/2024 35 29.045405 0.541761 29.587166 298.027883 3.754516 17.506498 8:32:29 08/21/2024 36 26.57081 0.212841 26.783651 234.779479 3.538538 20.772594 8:33:29 08/21/2024 37 26.4366 0.736796 27.173396 200.452711 2.875923 22.160855 8:34:30 08/21/2024 38 27.430116 0.520723 27.950839 284.085665 3.481903 16.983139 8:35:30 08/21/2024 39 27.740601 0.25728 27.997881 254.789754 3.369822 17.89803 8:36:30 08/21/2024 40 27.261903 0.223225 27.485128 252.739924 3.541043 18.723979 8:37:30 08/21/2024 41 28.816648 0.296852 29.1135 295.443999 3.247873 19.972983 8:38:30 08/21/2024 42 27.701174 0.369742 28.070916 257.355617 3.861101 18.256106 8:39:30 08/21/2024 43 27.079344 -0.456321 26.623023 259.429515 2.932375 20.299218 8:40:30 08/21/2024 44 27.002878 0.409191 27.412069 227.865918 3.410429 19.86194 8:41:30 08/21/2024 45 24.743187 0.551558 25.294745 188.694535 2.136510 15.796385 8:42:31 08/21/2024 46 27.328478 -0.153282 27.175196 258.682807 3.328872 18.374145 8:43:31 08/21/2024 47 27.674463 0.469964 28.144427 273.978327 4.146797 18.53157 8:44:31 08/21/2024 48 27.410456 0.199957 27.610413 266.113854 3.012317 19.921597 8:45:31 08/21/2024 49 25.582369 0.232347 25.814716 194.553511 4.051176 21.002786 8:46:31 08/21/2024 50 27.610692 0.388476 27.999168 294.985227 2.888100 18.082605 8:47:31 08/21/2024 51 27.486613 0.257986 27.744599 267.003548 3.204513 20.4487 8:48:31 08/21/2024 52 25.496173 0.379977 25.87615 210.252765 2.565377 20.816392 8:49:31 08/21/2024 53 26.286919 0.433507 26.720426 247.621002 3.115718 19.205336 8:50:32 08/21/2024 54 27.006005 0.440446 27.446451 236.894834 4.431898 18.408355 8:51:32 08/21/2024 55 27.201861 0.426657 27.628518 262.697868 3.958956 19.050371 8:52:32 08/21/2024 56 27.177597 0.123933 27.30153 236.297564 3.640678 20.388435 8:53:32 08/21/2024 57 27.892715 0.478902 28.371617 269.673982 4.922110 21.348914 8:54:32 08/21/2024 58 27.035903 0.568358 27.604261 246.818066 3.327316 18.855992 8:55:32 08/21/2024 59 26.500248 0.414528 26.914776 222.814978 3.237551 20.600114 8:56:32 08/21/2024 60 27.706212 0.615417 28.321629 266.130567 2.911525 18.666458 8:57:32 08/21/2024 AVG 27.15 0.31 27.46 246.05 3.18 19.05 ppm@15% O2 7.75 69.46 0.90 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.04 0.11 0.23 0.59 0.00 0.01 77795 (101073) FTIR Measurements Calculated Emission Levels XCL Resources Shiner #30-3A-22 Pad Run 1 Record Date EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 8 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 1.10 1432 0.58 1.049 Average O2 0.0 (% dry)A 2 0.84 1.12 1.058 Average CO2 11.9 (% dry)A 3 1.55 1.11 1.054 Average N2 + CO 88.1 (% dry)A 4 2.58 1.04 1.020 Dry Molecular Weight 29.90 lb/lbmol A 5 5.42 0.86 0.927 Wet Molecular Weight 27.64 lb/lbmol A 6 6.45 0.90 0.949 EPA REFERENCE METHOD 320 A 7 7.16 1.12 1.058 Barometric Pressure 24.71 in Hg A 8 7.50 1.11 1.054 Moisture Content 19.05 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 27.46 ppm A 11 Calculated NOx Mass Output 0.11 lbs/hr A 12 Calculated NOx Output 0.04 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 246.05 ppm A 15 Calculated CO Mass Output 0.59 lbs/hr A 16 Calculated CO Output 0.23 g/bhp-hr B 1 0.50 0.99 1432 0.58 0.995 EPA REFERENCE METHOD 320 B 2 0.84 1.07 1.034 Average Analyzer NMNEHC Level 3.18 ppm B 3 1.55 1.11 1.054 Calculated NMNEHC Mass Output 0.01 lbs/hr B 4 2.58 1.16 1.077 Calculated NMNEHC Output 0.00 g/bhp-hr B 5 5.42 1.10 1.049 LOAD APPROXIMATION B 6 6.45 0.98 0.990 Estimated Engine Load 1159.2 BHP B 7 7.16 0.95 0.975 B 8 7.50 1.01 1.005 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 1.0 1432 0.6 1.022 Average Stack Gas Velocity 106.15 ft/sec Average Dry Flowrate 548.99 dscfm TEST RUN # 1 NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 26.967272 0.372789 27.340061 242.571346 3.847706 19.092038 8:58:33 08/21/2024 2 26.645745 0.457231 27.102976 231.028492 3.383098 18.052186 8:59:33 08/21/2024 3 27.422321 0.32827 27.750591 248.998655 3.516836 18.938664 9:00:33 08/21/2024 4 25.787678 0.495676 26.283354 204.993311 3.011743 20.24454 9:01:33 08/21/2024 5 28.201437 0.56255 28.763987 292.841897 3.916836 20.846411 9:02:33 08/21/2024 6 29.060764 0.41853 29.479294 282.09872 4.194157 20.127492 9:03:33 08/21/2024 7 28.110599 0.466013 28.576612 284.990403 3.233654 19.47786 9:04:33 08/21/2024 8 26.682936 0.445974 27.12891 223.423253 3.030627 17.106708 9:05:34 08/21/2024 9 27.498734 0.328886 27.82762 267.338479 3.746974 17.933443 9:06:34 08/21/2024 10 27.047414 0.133231 27.180645 239.768228 4.004677 18.437741 9:07:34 08/21/2024 11 26.425974 -0.379352 26.046622 231.610148 5.099495 21.626957 9:08:34 08/21/2024 12 27.375727 0.468128 27.843855 245.805221 4.516323 17.851526 9:09:34 08/21/2024 13 26.982237 0.52272 27.504957 242.073801 3.404095 18.968581 9:10:34 08/21/2024 14 25.445412 0.589504 26.034916 196.703653 3.894590 21.7615 9:11:34 08/21/2024 15 26.83867 0.390533 27.229203 260.012645 4.978017 20.062228 9:12:34 08/21/2024 16 26.358296 0.54312 26.901416 205.036563 3.641671 18.400421 9:13:35 08/21/2024 17 26.581275 0.419055 27.00033 219.973426 3.340227 19.394291 9:14:35 08/21/2024 18 25.543875 0.544485 26.08836 210.624547 3.807657 19.45117 9:15:35 08/21/2024 19 26.865095 0.087599 26.952694 225.410563 4.108208 22.080881 9:16:35 08/21/2024 20 26.000759 0.537744 26.538503 212.330657 3.709507 18.211314 9:17:35 08/21/2024 21 26.479701 0.300017 26.779718 237.229882 4.868189 18.19816 9:18:35 08/21/2024 22 26.821454 0.39715 27.218604 237.045269 3.508817 17.462727 9:19:35 08/21/2024 23 26.153618 0.274247 26.427865 221.15705 4.748853 20.085571 9:20:35 08/21/2024 24 26.199332 0.06051 26.259842 231.242588 4.144755 23.133051 9:21:36 08/21/2024 25 26.79508 0.743119 27.538199 242.512241 7.136163 23.085815 9:22:36 08/21/2024 26 24.318054 0.759673 25.077727 172.815248 5.818459 20.873968 9:23:36 08/21/2024 27 25.120302 0.533741 25.654043 228.897458 4.016707 20.248437 9:24:36 08/21/2024 28 26.778356 0.816704 27.59506 257.259755 5.351312 20.124105 9:25:36 08/21/2024 29 26.99961 0.670671 27.670281 263.769226 3.539034 18.920423 9:26:36 08/21/2024 30 26.52558 0.628569 27.154149 222.864257 5.097032 18.726774 9:27:36 08/21/2024 31 27.029396 0.475151 27.504547 262.669736 3.486003 19.283169 9:28:36 08/21/2024 32 25.854769 0.504846 26.359615 198.508327 4.099859 20.017775 9:29:37 08/21/2024 33 25.794599 0.633486 26.428085 240.097894 4.773561 18.429405 9:30:37 08/21/2024 34 26.566906 0.169776 26.736682 232.756436 5.711768 20.044434 9:31:37 08/21/2024 35 26.315096 0.318223 26.633319 223.441341 7.756477 23.061263 9:32:37 08/21/2024 36 26.298989 0.430483 26.729472 210.760603 6.032476 20.660678 9:33:37 08/21/2024 37 25.842017 0.795667 26.637684 212.753904 6.568963 20.41822 9:34:37 08/21/2024 38 27.508846 0.760988 28.269834 258.23902 4.562144 18.954644 9:35:37 08/21/2024 39 26.888903 0.553623 27.442526 241.462714 3.438460 18.594148 9:36:37 08/21/2024 40 28.580888 0.506527 29.087415 296.547118 6.230270 17.927502 9:37:38 08/21/2024 41 27.146781 0.560065 27.706846 238.650621 6.867475 21.15544 9:38:38 08/21/2024 42 30.317352 0.395898 30.71325 378.309236 4.397136 16.903956 9:39:38 08/21/2024 43 26.64684 0.425155 27.071995 220.167302 4.871946 18.623097 9:40:38 08/21/2024 44 26.924114 0.548876 27.47299 236.435109 3.802146 19.864265 9:41:38 08/21/2024 45 26.889937 0.190097 27.080034 228.860945 5.888078 19.793959 9:42:38 08/21/2024 46 26.873933 0.957676 27.831609 224.14264 6.816075 22.952271 9:43:38 08/21/2024 47 28.078965 0.773175 28.85214 270.213297 8.099611 23.208286 9:44:38 08/21/2024 48 26.82229 0.651644 27.473934 227.432574 4.645289 19.84133 9:45:39 08/21/2024 49 26.810392 0.533587 27.343979 220.934755 5.637520 19.287935 9:46:39 08/21/2024 50 27.786753 0.634008 28.420761 278.16708 5.816685 22.118487 9:47:39 08/21/2024 51 28.749667 0.538398 29.288065 281.055435 8.374143 22.283747 9:48:39 08/21/2024 52 26.540159 0.708954 27.249113 232.467833 6.501837 19.756041 9:49:39 08/21/2024 53 28.94561 0.550985 29.496595 297.615244 5.122351 19.033734 9:50:39 08/21/2024 54 27.052653 0.5914 27.644053 250.414036 5.025825 18.161978 9:51:39 08/21/2024 55 27.6855 0.548447 28.233947 271.677178 6.513690 17.294919 9:52:40 08/21/2024 56 26.248121 0.460535 26.708656 222.266981 5.261235 17.511364 9:53:40 08/21/2024 57 27.110972 0.255384 27.366356 264.186262 5.922058 20.157826 9:54:40 08/21/2024 58 27.552812 0.681167 28.233979 237.867566 3.713138 20.241207 9:55:40 08/21/2024 59 27.845603 0.764342 28.609945 300.267145 6.689610 19.234217 9:56:40 08/21/2024 60 27.924752 0.637669 28.562421 266.939633 4.937142 18.476776 9:57:40 08/21/2024 AVG 26.94 0.49 27.44 243.46 4.87 19.70 ppm@15% O2 7.74 68.73 1.37 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.04 0.11 0.23 0.58 0.01 0.02 Calculated Emission Levels Record Date XCL Resources Shiner #30-3A-22 Pad Run 2 77795 (101073) FTIR Measurements EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 8 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 0.86 1433 0.56 0.927 Average O2 0.0 (% dry)A 2 0.84 1.08 1.039 Average CO2 11.9 (% dry)A 3 1.55 0.99 0.995 Average N2 + CO 88.1 (% dry)A 4 2.58 1.03 1.015 Dry Molecular Weight 29.90 lb/lbmol A 5 5.42 1.11 1.054 Wet Molecular Weight 27.56 lb/lbmol A 6 6.45 1.19 1.091 EPA REFERENCE METHOD 320 A 7 7.16 1.08 1.039 Barometric Pressure 24.71 in Hg A 8 7.50 1.06 1.030 Moisture Content 19.70 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 27.44 ppm A 11 Calculated NOx Mass Output 0.11 lbs/hr A 12 Calculated NOx Output 0.04 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 243.46 ppm A 15 Calculated CO Mass Output 0.58 lbs/hr A 16 Calculated CO Output 0.23 g/bhp-hr B 1 0.50 1.01 1433 0.56 1.005 EPA REFERENCE METHOD 320 B 2 0.84 1.13 1.063 Average Analyzer NMNEHC Level 4.87 ppm B 3 1.55 1.12 1.058 Calculated NMNEHC Mass Output 0.02 lbs/hr B 4 2.58 1.09 1.044 Calculated NMNEHC Output 0.01 g/bhp-hr B 5 5.42 0.98 0.990 LOAD APPROXIMATION B 6 6.45 1.08 1.039 Estimated Engine Load 1159.2 BHP B 7 7.16 1.05 1.025 B 8 7.50 0.98 0.990 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 1.1 1433 0.6 1.025 Average Stack Gas Velocity 106.71 ft/sec Average Dry Flowrate 547.01 dscfm TEST RUN # 2 NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C Time 1 26.311259 0.599093 26.910352 234.344962 5.913325 17.33593 9:58:40 08/21/2024 2 27.226673 0.661248 27.887921 276.355565 6.453049 20.929951 9:59:40 08/21/2024 3 26.705904 0.639702 27.345606 251.041148 4.807836 18.968701 10:00:41 08/21/2024 4 27.25393 0.555118 27.809048 264.782019 6.987946 18.173322 10:01:41 08/21/2024 5 27.416893 0.59887 28.015763 254.550505 5.348580 18.933568 10:02:41 08/21/2024 6 28.547761 0.491675 29.039436 309.194356 5.840576 18.133013 10:03:41 08/21/2024 7 27.320416 0.618845 27.939261 254.232935 5.292060 18.712466 10:04:41 08/21/2024 8 26.868162 0.659929 27.528091 256.067753 7.136468 21.245037 10:05:41 08/21/2024 9 27.199847 0.555246 27.755093 283.570925 6.850564 19.547155 10:06:41 08/21/2024 10 26.499212 0.561643 27.060855 224.610587 4.774513 22.694519 10:07:41 08/21/2024 11 25.225146 0.675848 25.900994 211.101785 4.500578 18.489617 10:08:42 08/21/2024 12 25.176796 0.509083 25.685879 216.472132 7.153927 21.796659 10:09:42 08/21/2024 13 24.432846 0.796981 25.229827 195.311201 7.055427 20.199975 10:10:42 08/21/2024 14 26.103555 0.769144 26.872699 266.401751 5.537948 19.873643 10:11:42 08/21/2024 15 25.856001 0.85812 26.714121 229.549481 5.461152 21.533303 10:12:42 08/21/2024 16 28.389732 0.679591 29.069323 329.230446 6.379383 20.847202 10:13:42 08/21/2024 17 25.172587 0.780932 25.953519 202.117581 7.346153 20.262268 10:14:42 08/21/2024 18 25.954859 0.647048 26.601907 266.704176 6.465390 18.764435 10:15:42 08/21/2024 19 27.974421 0.941769 28.91619 290.320915 4.703899 20.514634 10:16:43 08/21/2024 20 26.299843 1.363738 27.663581 216.582924 7.910874 23.268009 10:17:43 08/21/2024 21 24.879141 0.885911 25.765052 198.510165 6.144149 21.056458 10:18:43 08/21/2024 22 24.937812 0.843356 25.781168 214.899981 7.558155 21.189487 10:19:43 08/21/2024 23 25.422083 0.880497 26.30258 235.270955 7.566224 20.8633 10:20:43 08/21/2024 24 25.695354 0.771478 26.466832 227.83913 5.958065 19.893119 10:21:43 08/21/2024 25 25.570633 0.731279 26.301912 246.518828 3.955342 19.293272 10:22:43 08/21/2024 26 26.158006 0.784502 26.942508 256.201746 4.194185 19.656308 10:23:43 08/21/2024 27 25.295576 0.756214 26.05179 198.396461 3.753146 19.456142 10:24:44 08/21/2024 28 26.03989 0.742432 26.782322 242.23744 4.448727 20.851864 10:25:44 08/21/2024 29 25.501583 0.585716 26.087299 223.475611 5.294231 19.263861 10:26:44 08/21/2024 30 24.414569 0.825379 25.239948 197.143383 6.548784 20.807061 10:27:44 08/21/2024 31 24.584495 0.725212 25.309707 212.368058 6.397403 19.974523 10:28:44 08/21/2024 32 25.614686 0.777447 26.392133 220.080856 4.575280 19.258322 10:29:44 08/21/2024 33 24.721585 0.710204 25.431789 201.856553 3.408045 19.311225 10:30:44 08/21/2024 34 28.302388 0.765467 29.067855 358.783204 5.151733 19.038737 10:31:45 08/21/2024 35 27.828672 0.524406 28.353078 247.337125 5.458746 18.978957 10:32:45 08/21/2024 36 25.773833 0.602175 26.376008 235.48512 3.858093 18.92214 10:33:45 08/21/2024 37 25.503902 0.612329 26.116231 209.693198 4.620483 19.717638 10:34:45 08/21/2024 38 24.584062 0.792427 25.376489 196.960854 3.821333 20.138326 10:35:45 08/21/2024 39 24.833516 0.781633 25.615149 213.211856 6.403158 19.644431 10:36:45 08/21/2024 40 25.333762 0.927066 26.260828 222.565722 5.104141 21.248801 10:37:45 08/21/2024 41 24.955757 0.777617 25.733374 203.173688 5.278989 20.144916 10:38:45 08/21/2024 42 25.697887 0.865637 26.563524 232.855263 7.177584 20.416022 10:39:45 08/21/2024 43 25.857907 0.940484 26.798391 251.68741 6.311651 20.15049 10:40:46 08/21/2024 44 27.072247 0.918323 27.99057 250.905681 6.549396 20.866142 10:41:46 08/21/2024 45 26.191675 0.846052 27.037727 228.410896 6.307962 21.076959 10:42:46 08/21/2024 46 26.512331 0.84195 27.354281 251.33177 7.280658 20.857279 10:43:46 08/21/2024 47 25.530263 0.651031 26.181294 225.782591 4.157196 19.204099 10:44:46 08/21/2024 48 26.44589 0.609739 27.055629 226.529231 5.130913 19.173323 10:45:46 08/21/2024 49 25.879623 0.839046 26.718669 215.050215 4.833054 20.202847 10:46:46 08/21/2024 50 25.920548 0.809016 26.729564 239.502884 7.148408 20.556878 10:47:46 08/21/2024 51 25.776183 0.845863 26.622046 215.865768 6.454074 19.566407 10:48:47 08/21/2024 52 27.003996 0.825131 27.829127 280.623231 4.035137 20.270714 10:49:47 08/21/2024 53 25.571747 0.905329 26.477076 209.131285 5.890471 20.918731 10:50:47 08/21/2024 54 26.38566 0.623115 27.008775 248.196291 6.306943 20.201943 10:51:47 08/21/2024 55 26.996683 0.735432 27.732115 266.327501 6.604731 20.491375 10:52:47 08/21/2024 56 26.390638 0.776797 27.167435 245.321418 4.429331 18.975676 10:53:47 08/21/2024 57 26.018535 0.629294 26.647829 229.366131 4.067438 17.881831 10:54:47 08/21/2024 58 26.771916 0.646822 27.418738 257.683423 4.912028 17.923111 10:55:48 08/21/2024 59 26.509482 0.668896 27.178378 237.224151 6.530474 19.990092 10:56:48 08/21/2024 60 26.56359 0.600366 27.163956 241.025612 4.766138 19.044723 10:57:48 08/21/2024 AVG 26.12 0.74 26.86 239.12 5.67 19.95 ppm@15% O2 7.58 67.50 1.60 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.04 0.11 0.22 0.57 0.01 0.02 FTIR Measurements 77795 (101073) Calculated Emission Levels XCL Resources Shiner #30-3A-22 Pad Run 3 Record Date EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 8 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 0.94 1434 0.59 0.970 Average O2 0.0 (% dry)A 2 0.84 1.06 1.030 Average CO2 11.9 (% dry)A 3 1.55 1.12 1.058 Average N2 + CO 88.1 (% dry)A 4 2.58 1.16 1.077 Dry Molecular Weight 29.90 lb/lbmol A 5 5.42 1.08 1.039 Wet Molecular Weight 27.53 lb/lbmol A 6 6.45 1.03 1.015 EPA REFERENCE METHOD 320 A 7 7.16 0.99 0.995 Barometric Pressure 24.71 in Hg A 8 7.50 1.04 1.020 Moisture Content 19.95 %A 9 EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 26.86 ppm A 11 Calculated NOx Mass Output 0.11 lbs/hr A 12 Calculated NOx Output 0.04 g/bhp-hr A 13 EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 239.12 ppm A 15 Calculated CO Mass Output 0.57 lbs/hr A 16 Calculated CO Output 0.22 g/bhp-hr B 1 0.50 0.99 1434 0.59 0.995 EPA REFERENCE METHOD 320 B 2 0.84 1.05 1.025 Average Analyzer NMNEHC Level 5.67 ppm B 3 1.55 1.17 1.082 Calculated NMNEHC Mass Output 0.02 lbs/hr B 4 2.58 1.09 1.044 Calculated NMNEHC Output 0.01 g/bhp-hr B 5 5.42 1.15 1.072 LOAD APPROXIMATION B 6 6.45 1.11 1.054 Estimated Engine Load 1159.2 BHP B 7 7.16 1.03 1.015 B 8 7.50 1.02 1.010 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 1.1 1434 0.6 1.031 Average Stack Gas Velocity 107.42 ft/sec Average Dry Flowrate 548.66 dscfm TEST RUN # 3 APPENDIX B Date Time NO 191C span NO2 191C span H2O% (high) 191C Formaldehyde 191C Ethylene 191C TE span Propane 191C span Acetaldehyde 191C span CO ppm 191C (1of2) spanCO ppm Dry CO2% 191C NOx Wet NOx Dry NM NE HC C3 Temp ( C )Pressure (atm)8/21/2024 7:08:29 0.015155 0.039457 -0.014757 -0.28839 -0.554811 0.619838 -0.572999 -0.11333 -0.113313 -0.011 0.054611 0.054603 0.08247 191.1185 1.000618/21/2024 7:08:37 0.051738 0.018918 -0.012754 -0.159469 0.358876 0.150916 0.111045 0.134306 0.134289 -0.008073 0.070656 0.070647 0.00963 191.192459 0.999558/21/2024 7:08:44 0.194204 -0.028741 -0.012184 -0.00033 -0.372809 0.27877 -0.190973 -0.008588 -0.008586 -0.003549 0.165463 0.165443 0.012276 191.213348 0.99922 8/21/2024 7:08:52 0.110461 0.005091 -0.018992 -0.082995 -0.189582 0.213891 -1.214584 0.019536 0.019532 -0.011928 0.115552 0.11553 0.008129 191.213348 0.9987138/21/2024 7:09:30 0 0 0 0 0 0 0 0 0 0 0 0 0 191.213348 0.997262 8/21/2024 7:09:43 -0.075453 0.06773 -0.00166 0.089589 -0.233428 -0.915025 0.133375 -0.024787 -0.024787 -0.002025 -0.007723 -0.007723 0.015493 191.200104 0.9964798/21/2024 7:09:50 -0.153058 0.059454 0.008885 -0.26673 -0.579367 -0.484876 0.053826 -0.055161 -0.055166 0.009109 -0.093604 -0.093613 -0.009685 191.137054 0.9960868/21/2024 7:09:58 0.077469 0.013559 -0.001764 -0.076813 -0.681729 -0.332339 0.741279 -0.079921 -0.079919 0.008832 0.091027 0.091026 -0.003378 191.137054 0.9952028/21/2024 7:10:06 -0.082476 0.032896 -0.003359 -0.112143 -0.292657 -0.500163 -0.045355 -0.052117 -0.052115 0.000634 -0.04958 -0.049578 0.046934 191.137054 0.995198/21/2024 7:10:13 -0.242899 0.085425 0.005325 0.011102 -0.198352 0.360986 0.664404 0.159102 0.159111 -0.000708 -0.157474 -0.157483 0.016684 191.173386 0.993968/21/2024 7:10:21 -0.047996 0.072676 -0.000719 -0.275227 -0.334354 -0.496222 0.419521 0.131597 0.131596 -0.00284 0.02468 0.02468 0.002758 191.156128 0.9933268/21/2024 7:10:28 -0.343366 0.056208 0.000873 0.006209 -0.002394 -0.054641 0.166806 -0.173529 -0.17353 0.00158 -0.287158 -0.28716 -0.005072 191.156128 0.992687 8/21/2024 7:10:36 -0.226934 0.072766 -0.000693 -0.104924 0.418954 0.59617 -0.120072 -0.258038 -0.258037 0.007669 -0.154168 -0.154167 0.065532 191.149765 0.9922198/21/2024 7:10:43 0.051493 0.022423 0.002804 -0.117941 1.231966 0.708442 0.185089 -0.206178 -0.206184 0.007547 0.073916 0.073918 0.149552 191.083801 0.991656 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/21/2024 7:11:06 309.504149 294.702794 274.632217 191.085129 0.998865 8/21/2024 7:14:05 60.595867 191.041687 0.9904228/21/2024 7:11:14 470.015032 466.340508 467.228477 191.114349 0.999086 8/21/2024 7:14:13 91.502246 191.041687 0.990426 8/21/2024 7:11:21 501.636023 502.308676 495.569333 191.092545 0.998747 8/21/2024 7:14:20 97.640004 191.041687 0.9909698/21/2024 7:11:29 505.917293 508.256849 497.424 191.092545 0.998369 8/21/2024 7:14:28 100.019437 191.041687 0.9919588/21/2024 7:11:36 505.021864 509.206278 498.196217 191.092545 0.99863 8/21/2024 7:14:35 99.212276 191.065521 0.9898728/21/2024 7:11:44 504.111685 510.051803 500.41158 191.092545 0.997887 8/21/2024 7:14:43 99.184892 191.054398 0.9900228/21/2024 7:11:51 505.036288 509.702255 497.996331 191.048828 0.99733 8/21/2024 7:14:50 99.695034 191.054398 0.9903958/21/2024 7:11:59 505.532189 510.125327 499.577523 191.009888 0.99655 8/21/2024 7:14:58 99.246844 191.054398 0.9903018/21/2024 7:12:06 505.182731 510.569688 495.323633 191.009888 0.996705 8/21/2024 7:15:05 98.668318 191.054398 0.990252 8/21/2024 7:12:14 506.859871 510.515517 502.511199 191.009888 0.996542 8/21/2024 7:15:13 99.298281 191.054398 0.990903 Date Time NO2 191C span Temp ( C )Pressure (atm)8/21/2024 7:12:35 64.510607 191.105255 0.9891498/21/2024 7:12:43 126.588995 191.083466 0.9870888/21/2024 7:12:50 140.44282 191.029877 0.98683 8/21/2024 7:12:58 144.151967 191.028961 0.9872878/21/2024 7:13:05 145.282991 191.028961 0.9871858/21/2024 7:13:13 146.217373 191.028961 0.9871398/21/2024 7:13:20 146.527414 191.028961 0.986568/21/2024 7:13:28 146.79147 191.028961 0.9867978/21/2024 7:13:35 147.167863 191.09346 0.9856148/21/2024 7:13:43 147.181221 191.111618 0.985349 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/21/2024 7:15:36 0.222791 0.70725 0.679474 191.017838 0.97271 8/21/2024 7:17:06 58.361752 191.05069 1.0003478/21/2024 7:15:43 163.28471 177.299318 137.119494 191.073471 0.987357 8/21/2024 7:17:13 90.139341 191.009888 1.0053768/21/2024 7:15:51 431.749828 434.836414 425.799506 191.073471 0.987954 8/21/2024 7:17:21 96.629034 191.009888 1.0061658/21/2024 7:15:58 488.139401 493.32664 490.759865 191.073471 0.98788 8/21/2024 7:17:28 97.653658 191.009888 1.005658 8/21/2024 7:16:06 500.038759 505.764613 497.789281 191.064392 0.988175 8/21/2024 7:17:36 99.675225 191.009888 1.0047138/21/2024 7:16:13 502.200041 507.514469 496.114228 191.00444 0.987653 8/21/2024 7:17:44 99.544782 191.008072 1.004573 8/21/2024 7:16:21 503.869578 509.241511 500.80348 190.997177 0.987117 8/21/2024 7:17:51 98.976633 190.996262 1.0022388/21/2024 7:16:28 504.309757 510.268756 493.022219 190.997177 0.986872 8/21/2024 7:17:59 99.629481 191.055191 1.0001318/21/2024 7:16:36 503.836576 509.821445 498.496704 190.997177 0.985269 8/21/2024 7:18:06 98.987417 191.022614 0.9994568/21/2024 7:16:43 505.346842 510.417017 497.257302 191.067108 0.986833 8/21/2024 7:18:14 98.182434 191.022614 1.000187 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Ethylene 191C TE Temp ( C )Pressure (atm)8/21/2024 7:18:36 0.798141 0.855546 0.794286 6.088935 191.022614 1.0004058/21/2024 7:18:44 0.101613 0.144143 0.939204 1.535061 191.022614 1.0004198/21/2024 7:18:51 -0.227648 0.130397 0.129006 0.466876 191.047134 1.001268/21/2024 7:18:59 0.122365 0.109364 0.403185 0.334358 191.044861 0.9994648/21/2024 7:19:06 -0.091409 -0.096611 -0.123968 0.203954 191.041687 1.00081 8/21/2024 7:19:14 0.190908 0.101529 -0.003183 -0.474673 191.041687 1.0003688/21/2024 7:19:21 0.013843 0.049558 0.663964 -0.619818 191.041687 0.999587 8/21/2024 7:19:29 -0.066855 0.171677 0.991786 -0.471333 191.024429 1.000204 Raw Calibration Data BACKGROUND / PRE DIRECT ZERO PRE DIRECT CAL NO2 CAL PRE SYSTEM CAL PRE SYSTEM ZERO Date Time CO2% 191C Propane 191C span Temp ( C )Pressure (atm)8/21/2024 7:54:21 11.282078 0.626994 190.977036 0.9940898/21/2024 7:54:29 11.304146 0.258071 190.961746 0.9976378/21/2024 7:54:36 11.322815 0.465714 190.979919 0.9942568/21/2024 7:54:51 11.345993 0.49915 191.014908 0.9948158/21/2024 7:54:59 11.338554 0.492594 191.048035 0.995256 8/21/2024 7:55:06 8.385605 65.066725 191.048035 1.0028128/21/2024 7:55:14 2.233794 354.48689 191.038498 1.000593 8/21/2024 7:55:21 0.524447 451.671311 191.031693 0.9901348/21/2024 7:55:29 1.153143 416.830129 190.982651 0.989798/21/2024 7:55:36 7.043501 170.106741 190.965393 0.9920578/21/2024 7:55:44 9.504893 73.051203 190.965393 0.9943398/21/2024 7:55:51 10.131918 49.912609 190.965393 0.9954328/21/2024 7:55:59 10.251385 45.313026 190.965393 0.9948598/21/2024 7:56:29 10.316748 44.563214 190.965393 0.993887 8/21/2024 7:56:36 10.35207 45.410238 190.965393 0.993422 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/21/2024 11:07:18 314.4958 306.035525 281.717455 190.978104 1.002674 8/21/2024 11:05:46 62.776977 190.978104 0.9605318/21/2024 11:07:26 460.970803 461.942143 455.708607 190.978104 1.002642 8/21/2024 11:05:54 90.919861 190.978104 1.0055138/21/2024 11:07:34 492.054631 495.422594 484.903134 190.978104 1.002769 8/21/2024 11:06:01 96.463261 190.978104 1.005654 8/21/2024 11:07:41 499.925906 502.529894 490.980346 190.978104 1.002367 8/21/2024 11:06:09 98.459406 190.978104 1.0063358/21/2024 11:07:49 500.774726 505.782987 494.453958 190.978104 1.002553 8/21/2024 11:06:16 97.96954 190.978104 1.0055768/21/2024 11:07:56 502.534584 505.945189 494.309172 190.978104 1.003741 8/21/2024 11:06:24 98.406639 190.978104 1.0062918/21/2024 11:08:04 502.905991 505.961494 492.556447 190.95903 1.00302 8/21/2024 11:06:32 97.462368 190.978104 1.0069058/21/2024 11:08:11 503.129056 506.985589 494.569355 190.93042 1.003504 8/21/2024 11:06:39 98.977313 190.978104 1.0062258/21/2024 11:08:19 502.752046 505.361726 495.999154 190.897827 1.003324 8/21/2024 11:06:47 98.734258 190.978104 1.004658/21/2024 11:08:26 503.473761 505.091825 495.860152 190.896362 1.003468 8/21/2024 11:06:54 98.602025 190.978104 1.004868 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm)8/21/2024 11:06:01 0.134921 0.377446 0.122715 190.978104 1.005654 8/21/2024 11:09:06 -1.025137 190.990814 1.0056058/21/2024 11:06:09 -0.065101 0.324777 0.046927 190.978104 1.006335 8/21/2024 11:09:14 -1.348674 190.990814 1.0078258/21/2024 11:06:16 -0.107288 -0.174396 -0.307582 190.978104 1.005576 8/21/2024 11:09:21 0.098201 190.990814 1.0077518/21/2024 11:06:24 -0.212662 0.082041 -0.644499 190.978104 1.006291 8/21/2024 11:09:29 -0.628914 190.990814 1.007275 8/21/2024 11:06:32 0.104648 0.240797 -0.714745 190.978104 1.006905 8/21/2024 11:09:36 -0.60773 190.990814 1.0080698/21/2024 11:06:39 -0.094629 0.138113 -0.19125 190.978104 1.006225 8/21/2024 11:09:44 -0.832606 190.990814 1.0085398/21/2024 11:06:47 -0.108422 -0.172302 -0.823355 190.978104 1.00465 8/21/2024 11:09:51 -0.652841 190.990814 1.0084688/21/2024 11:06:54 0.000024 -0.075383 0.265454 190.978104 1.004868 8/21/2024 11:09:59 -0.205987 190.990814 1.007817 POST SYSTEM ZERO SAMPLE SPIKE RECOVERY POST SYSTEM CAL PRE TEST 1 501.6 11.3 0.5 10.3 46.3 0.093 88.8% Sensor Analyzer Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Error (%)Error (%) NOx 510.5 512.4 -0.1 -0.37 -0.02 CO 506.9 507.5 0.0 -0.13 -0.01 Propane 502.5 501.6 -0.2 0.18 -0.05 Ethylene 99.3 101.90 -0.2 -2.55 -0.23 Sensor System Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Recovery (%)Error (%) NOx 510.4 512.4 0.2 -0.39 0.04 CO 505.3 507.5 0.1 -0.42 0.03 Propane 497.3 501.6 0.4 -0.87 0.08 Ethylene*98.2 101.90 1.1 -3.65 1.06 Sensor System Cal Zero Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Recovery (%)Error (%)Drift Error (%)Drift Error (%) NOx 505.1 512.4 0.1 -1.43 0.02 1.04 0.01 CO 503.5 507.5 0.0 -0.79 -0.01 0.37 0.04 Propane 495.9 501.6 -0.4 -1.14 -0.07 0.28 0.15 Ethylene*98.6 101.90 -0.7 -3.24 -0.69 0.41 1.75 *CTS Scans are conducted with Ethylene through the sample line. % Recovery Propane PRE DIRECT CAL FTIR QA/QC SUMMARY SAMPLE RECOVERY CALCULATIONS Period Spike #Concentration of Propane Cylinder Stack CO2 Concentration Stack Propane Concentration Stack + Spike CO2 Concentration Stack + Propane Concentration DF Calculated POST SYSTEM CAL PRE SYSTEM CAL XCL - Shiner #30-3A-22 Pad 8-21-24 XCL - Shiner #30-3A-22 Pad 8-21-24 XCL - Shiner #30-3A-22 Pad 8-21-24 Spectral Fit Run 1 Spectral Fit Run 2 Spectral Fit Run 3 Analysis Validation Report Sample Filename: C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000140.LAB Filename for noise: C:\OLT\Data\Golden Spectrum\New FTIR 09-13-23\NEW FTIR 09-13-23_000003.LAB Interferences Filenames: C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000068.LAB C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000069.LAB C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000070.LAB C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000071.LAB C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000072.LAB C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000073.LAB C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000074.LAB C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000075.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 20.95 2.91 -0.18 0.25 3.98 3.98 -2.17 --0-2795 1.04 Good NO2 191C 0.2 0.58 0.27 0.02 0.02 0.61 0.61 0.28 0.56 0 0.09 0-488 1 Close to DL N2O 191C 2.54 0.33 3.65 0.02 0.02 0.38 0.38 4.09 4.09 0.45 1.22 0-200 -Close to DL NH3 TE 191C 390.78 34.92 214.68 2.05 3.49 57.44 57.44 241.23 241.36 26.55 71.56 0-2995 -Close to DL H2O% (HIGH) 191C20.45 0.22 -0.01 0.01 0.34 0.34 -0.41 --0-40 -Good FORMALDEHYDE 191C-0.15 0.63 0.39 0.16 0.18 0.71 0.71 0.41 0.47 0.02 0.13 0-69 1.18 Close to DL FORMIC ACID 191C TE-0.5 3.73 2.27 0.7 0.82 4.37 4.37 2.48 3.04 0.2 0.76 0-466 -Close to DL CH4 2900 CM-1 191C119.04 4.46 -0.85 1.23 8.45 8.45 -2.38 --0-3143 0.98 Good PROPANE 191C 0.94 0.57 1.27 0.11 0.13 0.68 0.68 1.72 1.72 0.45 0.42 0-4976 0.95 Close to DL PROPYLENE 191C TE1.59 4.41 3 0.78 0.93 5.21 5.21 4.3 4.3 1.3 1 0-194 -Close to DL ETHANE 191C 5.2 1.36 7.59 0.26 0.4 2.12 2.12 8.39 8.39 0.8 2.53 0-1004 -Close to DL ETHYLENE 191C TE3.16 10.78 2.74 1.01 1.24 13.3 13.3 3.08 9.7 0.35 0.91 0-900 -Close to DL CO PPM 191C (1OF2)221.17 6.12 -0.15 0.33 12.35 12.35 -4.42 --0-5010 1.03 Good CO2% 191C 9.53 0.21 -0.01 0.01 0.29 0.29 -0.19 --0-23 -Good CO% 191C (2OF2)0.02 0 -0 0 0 0 -0 --0-8 -Good ACETALDEHYDE 191C-0.06 1.46 0.94 0.36 0.46 1.88 1.88 1.03 1.11 0.09 0.31 0-186 0.98 Close to DL ACETYLENE 191C-0.29 3.99 1.35 0.36 0.48 5.27 5.27 1.38 3.63 0.03 0.45 0-1016 -Close to DL SO2 191C 5.14 5.3 1.44 0.24 0.29 6.46 6.46 1.86 4.94 0.42 0.48 0-964 1.02 Close to DL HEXANE 191C -0.18 0.37 0.2 0.06 0.09 0.5 0.5 0.25 0.3 0.06 0.07 0-1000 -Close to DL Analysis Validation Report Sample Filename: C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000200.LAB Filename for noise: C:\OLT\Data\Golden Spectrum\New FTIR 09-13-23\NEW FTIR 09-13-23_000003.LAB Interferences Filenames: C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000068.LAB C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000069.LAB C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000070.LAB C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000071.LAB C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000072.LAB C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000073.LAB C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000074.LAB C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000075.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 21.35 2.63 -0.18 0.25 3.59 3.59 -1.88 --0-2795 1.04 Good NO2 191C 0.42 0.73 0.27 0.02 0.02 0.77 0.77 0.28 0.7 0 0.09 0-488 1 Close to DL N2O 191C 2.9 0.35 3.65 0.02 0.02 0.4 0.4 4.09 4.09 0.45 1.22 0-200 -Close to DL NH3 TE 191C 368.52 38.73 214.68 2.05 3.49 63.7 63.7 241.23 241.35 26.55 71.56 0-2995 -Close to DL H2O% (HIGH) 191C22.28 0.24 -0.01 0.01 0.37 0.37 -0.45 --0-40 -Good FORMALDEHYDE 191C-0.2 0.59 0.39 0.16 0.18 0.66 0.66 0.41 0.43 0.02 0.13 0-69 1.18 Close to DL FORMIC ACID 191C TE0.17 3.56 2.27 0.7 0.82 4.17 4.17 2.48 2.88 0.2 0.76 0-466 -Close to DL CH4 2900 CM-1 191C120.36 4.42 -0.85 1.23 8.38 8.38 -2.41 --0-3143 0.98 Good PROPANE 191C 1.4 0.57 1.27 0.11 0.13 0.69 0.69 1.72 1.72 0.45 0.42 0-4976 0.95 Close to DL PROPYLENE 191C TE3.06 4.61 3 0.78 0.93 5.46 5.46 4.3 4.3 1.3 1 0-194 -Close to DL ETHANE 191C 5.54 1.4 7.59 0.26 0.4 2.19 2.19 8.39 8.39 0.8 2.53 0-1004 -Close to DL ETHYLENE 191C TE3.79 12.37 2.74 1.01 1.24 15.26 15.26 3.08 11.27 0.35 0.91 0-900 -Close to DL CO PPM 191C (1OF2)228.2 6.7 -0.15 0.33 13.54 13.54 -4.56 --0-5010 1.03 Good CO2% 191C 9.34 0.22 -0.01 0.01 0.3 0.3 -0.19 --0-23 -Good CO% 191C (2OF2)0.02 0 -0 0 0 0 -0 --0-8 -Good ACETALDEHYDE 191C-0.01 1.38 0.94 0.36 0.46 1.77 1.77 1.03 1.03 0.09 0.31 0-186 0.98 Close to DL ACETYLENE 191C-0.39 3.95 1.35 0.36 0.48 5.21 5.21 1.38 3.59 0.03 0.45 0-1016 -Close to DL SO2 191C 5.25 6.94 1.44 0.24 0.29 8.46 8.46 1.86 6.58 0.42 0.48 0-964 1.02 Close to DL HEXANE 191C -0.37 0.38 0.2 0.06 0.09 0.51 0.51 0.25 0.31 0.06 0.07 0-1000 -Close to DL Analysis Validation Report Sample Filename: C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000260.LAB Filename for noise: C:\OLT\Data\Golden Spectrum\New FTIR 09-13-23\NEW FTIR 09-13-23_000003.LAB Interferences Filenames: C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000068.LAB C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000069.LAB C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000070.LAB C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000071.LAB C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000072.LAB C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000073.LAB C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000074.LAB C:\OLT\Data\XCL\Shiner #30-3A-22 E2 08-21-24\SHINER #30-3A-22 E2 08-21-24_000075.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 20.22 3.3 -0.18 0.25 4.5 4.5 -2.56 --0-2795 1.04 Good NO2 191C 0.68 0.61 0.27 0.02 0.02 0.65 0.65 0.28 0.57 0 0.09 0-488 1 Close to DL N2O 191C 2.2 0.39 3.65 0.02 0.02 0.45 0.45 4.09 4.09 0.45 1.22 0-200 -Close to DL NH3 TE 191C 356.84 34.36 214.68 2.05 3.49 56.52 56.52 241.23 241.34 26.55 71.56 0-2995 -Close to DL H2O% (HIGH) 191C19.52 0.28 -0.01 0.01 0.43 0.43 -0.39 --0-40 -Good FORMALDEHYDE 191C-0.21 0.61 0.39 0.16 0.18 0.69 0.69 0.41 0.46 0.02 0.13 0-69 1.18 Close to DL FORMIC ACID 191C TE0 3.84 2.27 0.7 0.82 4.5 4.5 2.48 3.16 0.2 0.76 0-466 -Close to DL CH4 2900 CM-1 191C113.44 4.62 -0.85 1.23 8.75 8.75 -2.31 --0-3143 0.98 Good PROPANE 191C 1.09 0.59 1.27 0.11 0.13 0.71 0.71 1.72 1.72 0.45 0.42 0-4976 0.95 Close to DL PROPYLENE 191C TE2.3 4.75 3 0.78 0.93 5.62 5.62 4.3 4.3 1.3 1 0-194 -Close to DL ETHANE 191C 4.64 1.43 7.59 0.26 0.4 2.23 2.23 8.39 8.39 0.8 2.53 0-1004 -Close to DL ETHYLENE 191C TE3.05 11.59 2.74 1.01 1.24 14.3 14.3 3.08 10.51 0.35 0.91 0-900 -Close to DL CO PPM 191C (1OF2)179.56 4.93 -0.15 0.33 9.95 9.95 -3.59 --0-5010 1.03 Good CO2% 191C 9.64 0.22 -0.01 0.01 0.3 0.3 -0.19 --0-23 -Good CO% 191C (2OF2)0.02 0 -0 0 0 0 -0 --0-8 -Good ACETALDEHYDE 191C0.05 1.42 0.94 0.36 0.46 1.82 1.82 1.03 1.06 0.09 0.31 0-186 0.98 Close to DL ACETYLENE 191C -0.5 4 1.35 0.36 0.48 5.28 5.28 1.38 3.64 0.03 0.45 0-1016 -Close to DL SO2 191C 5.05 5.49 1.44 0.24 0.29 6.7 6.7 1.86 5.14 0.42 0.48 0-964 1.02 Close to DL HEXANE 191C -0.19 0.38 0.2 0.06 0.09 0.51 0.51 0.25 0.31 0.06 0.07 0-1000 -Close to DL APPENDIX C Test Run Load %Site Rated Load, bhp Load Approx., bhp 1 69 1680 1159.2 2 69 1680 1159.2 3 69 1680 1159.2 Engine Load Approximation based on Panel Levels APPENDIX D Test Run Flowrate dscfm Approx. BHP Avg O2 % NOx ppmvd NOx g/bhp-hr NOx lbs/hr CO ppmvd CO g/bhp-hr CO lbs/hr NMNEHC ppmvd NMNEHC g/bhp-hr NMNEHC lbs/hr Moisture Content % 1 548.99 1159.2 0.0 27.46 0.04 0.11 246.05 0.23 0.59 3.18 0.00 0.01 19.05 2 547.01 1159.2 0.0 27.44 0.04 0.11 243.46 0.23 0.58 4.87 0.01 0.02 19.70 3 548.66 1159.2 0.0 26.86 0.04 0.11 239.12 0.22 0.57 5.67 0.01 0.02 19.95 1159.2 0.0 27.25 0.04 0.11 242.88 0.23 0.58 4.58 0.01 0.02 19.57 Summary Average Levels Example Calculations: XCL Resources, Shiner #30-3A-22 Pad, 77795 (101073) The following is a step-by-step calculation for the first test run conducted on the Shiner #30-3A- 22 Pad 77795 (101073). Test Parameters • Stack Diameter = 8 inches • Traverse Points = 16 • Ports = 2 • Barometric Pressure = 24.71 in Hg • Average O2 = 0.0% • Average CO2 = 11.9% • Load Approximation = 1159.2 bhp • Moisture Content = 19.05% EPA 40 CFR 60(A) Methods 1-3: Determination of Stack Gas Velocity and Flow Rate Dry Molecular Weight (lb/lbmol) = (0.44 * %CO2) + (0.32 * %O2) + ((0.28 * (%N2 + %CO)) Where: %CO2 – Carbon Dioxide Content Of The Gas = 11.9% %O2 – Oxygen Content Of The Gas = 0.0% %N2 – Nitrogen Content Of The Gas %CO – Carbon Monoxide Content Of The Gas (%N2 +%CO) = (100 - %O2 - %CO2) = (100 – 0.0 – 11.9) = 88.1% Dry = (0.44 * %CO2) + (0.32 * %O2) + ((0.28 * (%N2 + %CO)) = (0.44 * 11.9) + (0.32 * 0.0) + (0.28 * 88.1) = 29.90 lb/lbmol Wet Molecular Weight (lb/lbmol) = MD * (1-BWS) + (18) * BWS Where: MD – Molecular Weight Of The Dry Gas (lb/lbmol) = 29.90 lb/lbmol BWS – Moisture Content Of The Gas (%/100) = 19.05% = MD * (1-BWS) + (18) * BWS = 29.90 * (1 – (19.05/ 100)) + (18 * (19.05/ 100)) = 27.64 lb/lbmol Average Stack Gas Velocity (ft/sec) = Cp * (85.49) * ∆PAVG * (TS / (((PS / 13.6) + PB) * MA)) Where: CP – Pitot tube constant (unitless) = 0.84 ∆PAVG – Average square root of the stack gas pitot DP (inches water) = 1.022 in H2O TS – Average stack temperature (R) = 1432 R PB – Barometric pressure (in Hg) = 24.71 in Hg PS – Stack pressure relative to barometric pressure (inches water) = 0.6 in H2O MA – Molecular weight of the wet gas (lb/lbmol) = 27.64 lb/lbmol = Cp * (85.49) * ∆PAVG * (TS / (((PS / 13.6) + PB) * MA)) = 0.84 * (85.49) * 1.022 * ( 1432 / (((0.6/ 13.6) + 24.71) * 27.64)) = 106.15 ft/sec Average Dry Flowrate (dscfm) = 60 * (1-BWS) * VS *  * (((DS / 2) / 12))2)* TSTD / TS * (PB + (PS / 13.6)) / 29.92 Where: DS – Diameter of the stack (inches) = 8 inches BWS – Moisture content of the gas (%) = 19.05% TSTD – Standard temperature (528R) TS – Average stack temperature (R) = 1432 R PB – Barometric pressure (in Hg) = 24.71 in Hg PS – Stack pressure relative to barometric pressure (inches water) = 0.6 in H2O VS– Average Stack gas velocity (ft/sec) = 106.15 ft/sec = 60 * (1-BWS) * VS *  * (((DS / 2) / 12))2)* TSTD / TS * (PB + (PS / 13.6)) / 29.92 = 60 * (1 - (19.05/ 100)) * 106.15 *  * (((8 / 2) / 12))2) * 528 / 1432 * (24.71 + (0.6 / 13.6)) / 29.92 = 548.99 dscfm Conversion of Dry Flowrate to m3/hr = Q * 60 * 2.83168*10 -2 Where: Q – Volumetric Flowrate = 548.99 dscfm 2.83168*10 -2 – Conversion factor for cubic feet to cubic meter 60 – Minutes in an hour = Q * 60 * 2.83168*10 -2 = 548.99 *60 * 2.83168*10 -2 = 932.732 m3/hr ASTM D 6348-03: Determination of NOx, CO and VOC Emissions From Stationary Sources NOx Emission Rate (g/Bhp-hr) = (Cd * 1.912*10 -3 * Q * T) / HP-hr Where: Cd – Measured NOx concentration in ppm = 27.46 ppm 1.92*10 -3 - Conversion constant for ppm to g/m3 NOx Q – Volumetric Flowrate = 932.732 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 1159.2 Bhp = (Cd * 1.912*10 -3 * Q * T) / HP-hr = (27.46 * 1.912*10 -3 * 932.732 * 1) / 1159.2 = 0.04 g/Bhp-hr NOx Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.04 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 1159.2 Bhp = g/Bhp-hr / 454 * Bhp = 0.04 / 454 * 1159.2 = 0.11 lbs/hr CO Emission Rate (g/Bhp-hr) = (Cd * 1.164*10 -3 * Q * T) / HP-hr Where: Cd – Measured CO concentration in ppm = 246.05 ppm 1.164*10 -3 - Conversion constant for ppm to g/m3 CO Q – Volumetric Flowrate = 932.732 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 1159.2 Bhp = (Cd * 1.164*10 -3 * Q * T) / HP-hr = (246.05 * 1.164*10 -3 * 932.732 * 1) / 1159.2 = 0.23 g/Bhp-hr CO Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.23 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 1159.2 Bhp = g/Bhp-hr / 454 * Bhp = 0.23 / 454 * 1159.2 = 0.59 lbs/hr VOC Emission Rate (g/Bhp-hr) = (Cd * 1.833*10 -3 * Q * T) / HP-hr Where: Cd – Measured VOC concentration in ppm = 3.18 ppm 1.833*10 -3 - Conversion constant for ppm to g/m3 VOC Q – Volumetric Flowrate = 932.732 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = 1159.2 Bhp = (Cd * 1.833*10 -3 * Q * T) / HP-hr = (3.18 * 1.833*10 -3 * 932.732 * 1) / 1159.2 = 0.00 g/Bhp-hr VOC Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.00 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = 1159.2 Bhp = g/Bhp-hr / 454 * Bhp = 0.00 / 454 * 1159.2 = 0.01 lbs/hr APPENDIX E FTIR Engine Test Sheet Company Name -v----z:L Location / Unit 1.0. 5J..,l'ner 4T.~ -1}19 ~Z-? F?­ Type of Test Comoleted s»:thY II/?// Field Technician (s) Jordan Nix 8rctnden A oS /'Z--I /Z"f Client Rep and/or State Reo Date L.. 704tJ o-sa:Engine Model ''''-'''-0.,6-/ £1/l-fI / IIEnaine SIN Verified: ~ h" ,"'''.-.-._._~.-.-Port Distance A l~. 2-1-{ I'Port Distance B "-,'"~'r .~Exhaust Diameter (inches) ...." ConcentrationCylinder #Calibration Gas [ -. 512.4 CC725093 CC725093NO (ppm 507.5 ppm 501.6 CC725093 CC725093 504.9 •t! t 1 N02 (ppm) Acetaldehyde (ppm) CO (ppm Propane Methane (ppm Ethvlene ppm CC275071 101.9 CC496385 145.7 CC431764 198.7 Stack Diagram rrz: ~9'Non-Resettable Run Time Hours tAl t(v/C-e~h~Engine Make ,~""~~~«~"«,,, ..««<­~"~-~""~,,,,,~--- *Manifold Pres. Vac(") or Boost(psi) or Boost ~ c: / I!.. T t A 1 B Time of Reading Atm Pressure (in Hg) Atm Temp CF) Enaine RPM Manifold Temp fF) Psuction (psi) Stage 1 Tsuction OF) Stage 1 Pdischarae (psi) Staae 1 Psuction (psi) Stage 2 Tsuction CF) Stage 2 Pdischarae (psi) Staae 2 Psuction (psi) Staae 3 Tsuction CF) Staae 3 Pdischan e (psi) Staae 3 Psuction psi) Staae 4 Tsuction OF) Stage 4 Pdischarge (psi) Stage 4 Gas Throunhput (mmcfrd) or I Pre Cat Temp CF) Post Cat Temp CF) Cat Differential Pres. (" of H2O) Humiditv% 02% C02 % Dry LOAD % ~PaRel) or (Estimated) Ignition Timing fF) AFR Setting mV (Left Bank) AFR SettinQ mV (Riqht Bank) ~vF7h ) L /f2.. Test 1 Test 2 Test 3 0:7~ '8 ()~~~ otj bCS tJ1, '1-/ z,tf, ?-) ZJ.f I' ti ?­t:.­::;--q., Cd;!? 103 1057..1 /032 /'31 1 / /'),0 ( /7. I F) I 1 / //:;"",1 II q­ (P>;?-/ Ill;/ /"2-0 z-Cf-7_'r" c-<-j-/17­-/1 h II-:J­--­---4 z e: LIZ 7­t-/29­ ~ -­--.--­-­/30':::J.­J~~ /3,<7'­ I ( J I b " fb '.I 16':;­ tj53 qz-q cI.it-'1 q~T_ Cf7--3 '9"7Y O·~ o.~ c;J,'9,--­-0(;I (,;J II. <r lilT /I,q ~q bCf - 6" .., -­- z...c ,':' / ez: t:;l--- Rev 8 * Some units show boost in inches of Hg. In this situation please indicate if it is positive (+) or negative(-). Eg: (+12") or (- 5'') 9/17/2019 Worksheet: O2 Stratification Client:XCL Location:Shiner #3o-3A-22 E2 Date:8/21/2024 PD:8 DD:24 YES Method 1 Criteria Met UD:6 YES Method 1 Criteria Met Port Point Insertion Depth Reading (inches)(%) A 1 1.33 0.00 A 2 4.00 0.00 A 3 6.66 0.00 A 4 A 5 A 6 A 7 A 8 A 9 A 10 A 11 A 12 Average 0.00 Notes: To demonstrate non-stratified flow and utilize one sampling location O2 may not deviate by more than +/- 0.3% of the average O2 concentration. EPA REFERENCE METHOD 3A (Determination Of Stratification) COMPANY NAME:XCL COMPANY LOCATION:Shiner #3o-3A-22 E2 DATE:8/21/24 STACK DIAMETER (inches):8 TRAVERSE POINTS:16 2 TEST RUN #1 TEST RUN #2 TEST RUN #3 AVERAGE O2:0 AVERAGE O2:0 AVERAGE O2:0 AVERAGE CO2:11.9 AVERAGE CO2:11.9 AVERAGE CO2:11.9 BARO PRESSURE:24.71 BARO PRESSURE:24.71 BARO PRESSURE:24.71 Point Insertion DepthDP (H2O)Ts (deg R)Stat P (H2O)Point Insertion DepthDP (H2O)Ts (deg R)Stat P (H2O)Point Insertion DepthDP (H2O)Ts (deg R)Stat P (H2O) 1 0.5 1.1 972 0.58 1 0.5 0.86 973 0.56 1 0.5 0.94 974 0.59 2 0.84 1.12 2 0.84 1.08 2 0.84 1.06 3 1.552 1.11 3 1.552 0.99 3 1.552 1.12 4 2.584 1.04 4 2.584 1.03 4 2.584 1.16 5 5.416 0.86 5 5.416 1.11 5 5.416 1.08 6 6.448 0.9 6 6.448 1.19 6 6.448 1.03 7 7.16 1.12 7 7.16 1.08 7 7.16 0.99 8 7.5 1.11 8 7.5 1.06 8 7.5 1.04 9 9 9 10 10 10 11 11 11 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16 1 0.5 0.99 972 0.58 1 0.5 1.01 973 0.56 1 0.5 0.99 974 0.59 2 0.84 1.07 2 0.84 1.13 2 0.84 1.05 3 1.552 1.11 3 1.552 1.12 3 1.552 1.17 4 2.584 1.16 4 2.584 1.09 4 2.584 1.09 5 5.416 1.1 5 5.416 0.98 5 5.416 1.15 6 6.448 0.98 6 6.448 1.08 6 6.448 1.11 7 7.16 0.95 7 7.16 1.05 7 7.16 1.03 8 7.5 1.01 8 7.5 0.98 8 7.5 1.02 9 9 9 10 10 10 11 11 11 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16