DAQ-2024-010902

1

DAQC-1003-24
Site ID 11841 (B4)

MEMORANDUM

TO: STACK TEST FILE – PEPPERIDGE FARM, INC. – Process Line No. 3 and No. 10

THROUGH: Harold Burge, Major Source Compliance Section Manager

FROM: Robert Sirrine, Environmental Scientist

DATE: September 24, 2024

SUBJECT: Location: 901 North 200 West, Richmond, Cache County, UT
Contact: Jeancarlo Hale, 435-750-8402
Tester: Alliance Technical Group, Tobias Hubbard 605-645-8562
Source: Lines No. 3 and No. 10 Catalytic Oxidizers
FRS ID#: UT0000004900500093
Permit #: DAQE-AN118410010-24, dated July 26, 2024
Action Code: TR
Subject: Review of stack test report received August 16, 2024

On August 16, 2024, the DAQ received an emissions test report for Pepperidge Farm’s process lines No. 3 and
No. 10 catalytic oxidizers located in Richmond, Cache County, UT. Testing was performed June 12, 2024, to
determine compliance with Permit Condition II.B.2.a for VOC emissions. The DAQ calculated test results are:

Source Test Date RM/Pollutant DAQ Result Source Result Limit

Line #3 6/12/24 25A/NMNEHC 0.63 lbs/hr^ 0.63 lbs/hr^ 1.50 lbs/hr*

Line #10 6/12/24 25A/NMNEHC 0.74 lbs/hr^ 0.74 lbs/hr^ 4.85 lbs/hr*

*AO DAQE-AN118410009-23, dated July 20, 2023, VOC emission limits for Lines #3 and #10 are shown
above since that AO was in affect at the time of testing. The limits for the current AO listed above as
Permit # are 0.95 lbs/hr and 3.25 lbs/hr respectively.

^ NMNEHC as propane

DEVIATIONS: The source was a minor source, and then a major, and back to minor
causing confusion of how to submit the test report which was
submitted four days late. No action recommended.

CONCLUSION: The emissions test report appears to be acceptable.

RECOMMENDATION: Lines #3 and #10 catalytic oxidizers should be considered to have
been in compliance at the time of testing. No further action needed.

ATTACHMENT: Stack testing reports for Lines #3 and #10 received August 16, 2024,
DAQ generated Excel spreadsheets

Source Test Report

Pepperidge Farm Incorporated
Commercial Bakery
901 North 200 West
Richmond, UT 84333

Sources Tested: Process Line No. 3 and No. 10
Test Date: June 12, 2024

Project No. AST-2024-2320

Prepared By
Alliance Technical Group, LLC
3683 W 2270 S, Suite E
West Valley City, UT 84120

Source Test Report
Test Program Summary

AST-2024-2320 Pepperidge – Richmond, UT Page i

Regulatory Information

Permit No. DAQE-AN118410008-18

Source Information

Source Name Target Parameters
Process Line No. 3 VOC Process Line No. 10

Contact Information

Test Location Test Company Analytical Laboratory
Pepperidge Farm Incorporated
Commercial Bakery
901 North 200 West
Richmond, UT 84333

Jeancarlo Hale
[e-mail]
[phone]

Alliance Technical Group, LLC
3683 W 2270 S, Suite E
West Valley City, UT 84120

Project Manager
Charles Horton
[e-mail]
[phone]

Field Team Leader
Ryan Lyons
[e-mail]
[phone]

QA/QC Manager
Kathleen Shonk
[e-mail]
[phone]

Report Coordinator
Delaine Spangler
[e-mail]

Report Reviewer
Sarah Perry
[e-mail]

Alliance Technical Group, LLC
5530 Marshall Street
Arvada, CO 80002
James Davidson
[e-mail]
[phone]
2 of 161
Source Test Report
Certification Statement
AST-2024-2320 Pepperidge – Richmond, UT Page ii
Alliance Technical Group, LLC (Alliance) has completed the source testing as described in this report. Results
apply only to the source(s) tested and operating condition(s) for the specific test date(s) and time(s) identified within
this report. All results are intended to be considered in their entirety, and Alliance is not responsible for use of less
than the complete test report without written consent. This report shall not be reproduced in full or in part without
written approval from the customer.
To the best of my knowledge and abilities, all information, facts and test data are correct. Data presented in this
report has been checked for completeness and is accurate, error-free and legible. Onsite testing was conducted in
accordance with approved internal Standard Operating Procedures. Any deviations or problems are detailed in the
relevant sections in the test report.
This report is only considered valid once an authorized representative of Alliance has signed in the space provided
below; any other version is considered draft. This document was prepared in portable document format (.pdf) and
contains pages as identified in the bottom footer of this document.
Charles Horton, QSTI
Alliance Technical Group, LLC
Date
8/12/2024
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Source Test Report
Table of Contents
AST-2024-2320 Pepperidge – Richmond, UT Page iii
TABLE OF CONTENTS
1.0 Introduction ................................................................................................................................................. 1-1
1.1 Process/Control System Descriptions .......................................................................................................... 1-1
1.2 Project Team ............................................................................................................................................... 1-1
1.3 Site Specific Test Plan & Notification ........................................................................................................ 1-1
2.0 Summary of Results .................................................................................................................................... 2-1
3.0 Testing Methodology .................................................................................................................................. 3-1
3.1 U.S. EPA Reference Test Methods 1 and 2 – Sampling/Traverse Points and Volumetric Flow Rate ........ 3-1
3.2 U.S. EPA Reference Test Method 3A – Oxygen/Carbon Dioxide .............................................................. 3-1
3.3 U.S. EPA Reference Test Method 4 – Moisture Content ............................................................................ 3-1
3.4 U.S. EPA Reference Test Method 25A – Volatile Organic Compounds .................................................... 3-1
3.5 U.S. EPA Reference Test Method 205 – Gas Dilution System Certification .............................................. 3-2
3.6 Quality Assurance/Quality Control – U.S. EPA Reference Test Method 3A.............................................. 3-2
3.7 Quality Assurance/Quality Control – U.S. EPA Reference Test Method 25A ............................................ 3-3
LIST OF TABLES
Table 1-1: Project Team ........................................................................................................................................... 1-1
Table 2-1: Summary of Results – Process Line No. 3 ............................................................................................... 2-1
Table 2-2: Summary of Results – Process Line No. 10 ............................................................................................. 2-1
Table 3-1: Source Testing Methodology .................................................................................................................. 3-1
APPENDICES
Appendix A Sample Calculations
Appendix B Field Data
Appendix C Laboratory Data
Appendix D Quality Assurance/Quality Control Data
Appendix E Process Operating/Control System Data
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Introduction
5 of 161

Source Test Report
Introduction

AST-2024-2320 Pepperidge – Richmond, UT Page 1-1

1.0 Introduction
Alliance Technical Group, LLC (Alliance) was retained by Pepperidge Farm Incorporated (Pepperidge) to conduct
compliance testing at the Richmond, Utah facility. Portions of the facility are subject to provisions of the Utah
Department of Environmental Quality, Division of Air Quality (UDAQ) Permit No. DAQE-AN118410008-18.
Testing was conducted to determine the emission rate of volatile organic compounds (VOC) from the Catalytic
Oxidizers installed on Process Line No. 3 and No. 10.
1.1 Process/Control System Descriptions
Pepperidge Farm Inc. owns and operates a commercial baking plant in Richmond, Utah. The plant operates Process
Line No. 3 and Process Line No. 10. Process line No. 3 is a Natural Gas/Propane Fired Oven with a maximum
rating of 5.2 MMBtu/hr; emissions are controlled with a radio frequency dryer to remove excess moisture from the
product line. Process Line No. 10 is a Natural Gas/Propane Fired Oven with a maximum rating of 12.5 MMBtu/hr;
emissions are controlled by a 1.6 MMBtu/hr Catalytic Oxidizer for VOC (ethanol) destruction.
1.2 Project Team
Personnel involved in this project are identified in the following table.

Table 1-1: Project Team

Pepperidge Personnel Jeancarlo Hale
Alliance Personnel
Ryan Lyons
Mitchell Manwaring
Samantha Waters
1.3 Site Specific Test Plan & Notification
Testing was conducted in accordance with the Site Specific Test Plan (SSTP) submitted to UDAQ by Alliance on
April 17, 2024.

6 of 161

Summary of Results

7 of 161

Source Test Report
Summary of Results

AST-2024-2320 Pepperidge – Richmond, UT Page 2-1

2.0 Summary of Results
Alliance conducted compliance testing at the Pepperidge Farm facility in Richmond, UT on June 12, 2024. Testing
consisted of determining the emission rate of VOC from the Catalytic Oxidizers installed on Process Line No. 3 and
No. 10.

Tables 2-1 and 2-1 provide summaries of the emission testing results with comparisons to the applicable permit
limits. Any difference between the summary results listed in the following tables and the detailed results contained
in appendices is due to rounding for presentation.

Table 2-1: Summary of Results – Process Line No. 3

Run Number Run 1 Run 2 Run 3 Average
Date 6/12/24 6/12/24 6/12/24 --
Non-Methane Ethane Hydrocarbon Data
Concentration, ppmvd 333.49 226.33 196.61 252.14
Concentration, lb/hr 1.93 1.36 1.18 1.49
Permit Limit, lb, hr -- -- -- 1.5
Percent of Limit, % -- -- -- 99

Table 2-2: Summary of Results – Process Line No. 10

Run Number Run 1 Run 2 Run 3 Average
Date 6/12/24 6/12/24 6/12/24 --
Non-Methane Ethane Hydrocarbon Data
Concentration, ppmvd 303.85 0.00 0.00 101.28
Concentration, lb/hr 6.75 0.00 0.00 2.25
Permit Limit, lb, hr -- -- -- 4.85
Percent of Limit, % -- -- -- 46

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Testing Methodology

9 of 161

Source Test Report
Testing Methodology

AST-2024-2320 Pepperidge – Richmond, UT Page 3-1

3.0 Testing Methodology
The emission testing program was conducted in accordance with the test methods listed in Table 3-1. Method
descriptions are provided below while quality assurance/quality control data is provided in Appendix D.

Table 3-1: Source Testing Methodology

Parameter U.S. EPA Reference
Test Methods Notes/Remarks
Volumetric Flow Rate 1 & 2 Full Velocity Traverses
Oxygen / Carbon Dioxide 3A Instrumental Analysis
Moisture Content 4 Gravimetric Analysis
Volatile Organic Compounds 25A ---
Gas Dilution System Certification 205 ---
3.1 U.S. EPA Reference Test Methods 1 and 2 – Sampling/Traverse Points and Volumetric Flow Rate
The sampling location and number of traverse (sampling) points were selected in accordance with U.S. EPA
Reference Test Method 1. To determine the minimum number of traverse points, the upstream and downstream
distances were equated into equivalent diameters and compared to Figure 1-2 in U.S. EPA Reference Test Method 1.

Full velocity traverses were conducted in accordance with U.S. EPA Reference Test Method 2 to determine the
average stack gas velocity pressure, static pressure and temperature. The velocity and static pressure measurement
system consisted of a pitot tube and inclined manometer. The stack gas temperature was measured with a K-type
thermocouple and pyrometer.

Stack gas velocity pressure and temperature readings were recorded during each test run. The data collected was
utilized to calculate the volumetric flow rate in accordance with U.S. EPA Reference Test Method 2.
3.2 U.S. EPA Reference Test Method 3A – Oxygen/Carbon Dioxide
The oxygen (O2) and carbon dioxide (CO2) testing was conducted in accordance with U.S. EPA Reference Test
Method 3A. Data was collected online and reported in one-minute averages. The sampling system consisted of a
stainless-steel probe, Teflon sample line(s), gas conditioning system and the identified gas analyzer. The gas
conditioning system was a non-contact condenser used to remove moisture from the stack gas. If an unheated
Teflon sample line was used, then a portable non-contact condenser was placed in the system directly after the
probe. Otherwise, a heated Teflon sample line was used. The quality control measures are described in Section 3.6.
3.3 U.S. EPA Reference Test Method 4 – Moisture Content
The stack gas moisture content (BWS) was determined in accordance with U.S. EPA Reference Test Method 4. The
gas conditioning train consisted of a series of chilled impingers. Prior to testing, each impinger was filled with a
known quantity of water or silica gel. Each impinger was analyzed gravimetrically before and after each test run on
the same balance to determine the amount of moisture condensed.
3.4 U.S. EPA Reference Test Method 25A – Volatile Organic Compounds
The volatile organic compounds (VOC) testing was conducted in accordance with U.S. EPA Reference Test Method
25A. Data was collected online and reported in one-minute averages. The sampling system consisted of a stainless-steel
10 of 161

Source Test Report
Testing Methodology

AST-2024-2320 Pepperidge – Richmond, UT Page 3-2

probe, heated Teflon sample line(s) and the identified gas analyzer. The quality control measures are described in
Section 3.7.
3.5 U.S. EPA Reference Test Method 205 – Gas Dilution System Certification
A calibration gas dilution system field check was conducted in accordance with U.S. EPA Reference Method 205.
An initial three (3) point calibration was conducted, using individual Protocol 1 gases, on the analyzer used to
complete the dilution system field check. Multiple dilution rates and total gas flow rates were utilized to force the
dilution system to perform two dilutions on each mass flow controller. The diluted calibration gases was sent
directly to the analyzer, and the analyzer response recorded in an electronic field data sheet. A mid-level supply gas,
with a cylinder concentration within 10% of one of the gas divider settings described above, was introduced directly
to the analyzer, and the analyzer response recorded in an electronic field data sheet. The cylinder concentration and
the analyzer response agreed within 2%. These steps were repeated three (3) times. The average analyzer response
agreed within 2% of the predicted gas concentration. No single injection differed more than 2% from the average
instrument response for that dilution. Copies of the Method 205 data can be found in the Quality Assurance/Quality
Control Appendix.
3.6 Quality Assurance/Quality Control – U.S. EPA Reference Test Method 3A
Cylinder calibration gases used met EPA Protocol 1 (+/- 2%) standards. Copies of all calibration gas certificates can
be found in the Quality Assurance/Quality Control Appendix.

Low Level gas was introduced directly to the analyzer. After adjusting the analyzer to the Low-Level gas
concentration and once the analyzer reading was stable, the analyzer value was recorded. This process was repeated
for the High-Level gas. For the Calibration Error Test, Low, Mid, and High Level calibration gases were
sequentially introduced directly to the analyzer. All values were within 2.0 percent of the Calibration Span or 0.5%
absolute difference.

High or Mid-Level gas (whichever was closer to the stack gas concentration) was introduced at the probe and the
time required for the analyzer reading to reach 95 percent or 0.5% (whichever was less restrictive) of the gas
concentration was recorded. The analyzer reading was observed until it reached a stable value, and this value was
recorded. Next, Low Level gas was introduced at the probe and the time required for the analyzer reading to
decrease to a value within 5.0 percent or 0.5% (whichever was less restrictive) was recorded. If the Low-Level gas
was zero gas, the response was 0.5% or 5.0 percent of the upscale gas concentration (whichever was less restrictive).
The analyzer reading was observed until it reached a stable value and this value was recorded. The measurement
system response time and initial system bias were determined from these data. The System Bias was within 5.0
percent of the Calibration Span or 0.5% absolute difference.

High or Mid-Level gas (whichever was closer to the stack gas concentration) was introduced at the probe. After the
analyzer response was stable, the value was recorded. Next, Low Level gas was introduced at the probe, and the
analyzer value recorded once it reached a stable response. The System Bias was within 5.0 percent of the
Calibration Span or 0.5% absolute difference or the data was invalidated and the Calibration Error Test and System
Bias were repeated.

Drift between pre- and post-run System Bias was within 3 percent of the Calibration Span or 0.5% absolute
difference. If the drift exceeded 3 percent or 0.5%, the Calibration Error Test and System Bias were repeated.

11 of 161

Source Test Report
Testing Methodology

AST-2024-2320 Pepperidge – Richmond, UT Page 3-3

To determine the number of sampling points, a gas stratification check was conducted prior to initiating testing. The
pollutant concentrations were measured at twelve traverse points (as described in Method 1). Each traverse point
was sampled for a minimum of twice the system response time.

If the diluent concentration at each traverse point did not differ more than 5 percent or 0.3% (whichever was less
restrictive) of the average pollutant concentration, then single point sampling was conducted during the test runs. If
the pollutant concentration did not meet these specifications but differed less than 10 percent or 0.5% from the
average concentration, then three (3) point sampling was conducted (stacks less than 7.8 feet in diameter - 16.7, 50.0
and 83.3 percent of the measurement line; stacks greater than 7.8 feet in diameter – 0.4, 1.0, and 2.0 meters from the
stack wall). If the pollutant concentration differed by more than 10 percent or 0.5% from the average concentration,
then sampling was conducted at a minimum of twelve (12) traverse points. Copies of stratification check data can
be found in the Quality Assurance/Quality Control Appendix.

A Data Acquisition System with battery backup was used to record the instrument response in one (1) minute
averages. The data was continuously stored as a *.CSV file in Excel format on the hard drive of a computer. At the
completion of testing, the data was also saved to the Alliance server. All data was reviewed by the Field Team
Leader before leaving the facility. Once arriving at Alliance’s office, all written and electronic data was
relinquished to the report coordinator and then a final review was performed by the Project Manager.
3.7 Quality Assurance/Quality Control – U.S. EPA Reference Test Method 25A
Cylinder calibration gases used met EPA Protocol 1 (+/- 2%) standards. Copies of all calibration gas certificates can
be found in the Quality Assurance/Quality Control Appendix.

Within two (2) hours prior to testing, zero gas was introduced through the sampling system to the analyzer. After
adjusting the analyzer to the Zero gas concentration and once the analyzer reading was stable, the analyzer value
was recorded. This process was repeated for the High-Level gas, and the time required for the analyzer reading to
reach 95 percent of the gas concentration was recorded to determine the response time. Next, Low and Mid-Level
gases were introduced through the sampling system to the analyzer, and the response was recorded when it was
stable. All values were less than +/- 5 percent of the calibration gas concentrations.

Mid-Level gas was introduced through the sampling system. After the analyzer response was stable, the value was
recorded. Next, Zero gas was introduced through the sampling system, and the analyzer value recorded once it
reached a stable response. The Analyzer Drift was less than +/- 3 percent of the span value.

A Data Acquisition System with battery backup was used to record the instrument response in one (1) minute
averages. The data was continuously stored as a *.CSV file in Excel format on the hard drive of a computer. At the
completion of testing, the data was also saved to the Alliance server. All data was reviewed by the Field Team
Leader before leaving the facility. Once arriving at Alliance’s office, all written and electronic data was
relinquished to the report coordinator and then a final review was performed by the Project Manager.

12 of 161

Appendix A

13 of 161
Example Calculations
Location
Source
Project No.
Run No.
Parameter(s)
Meter Pressure (Pm), in. Hg
where,
Pb 25.45 = barometric pressure, in. Hg
ΔH 1.000 = pressure differential of orifice, in H2O
Pm 25.52 = in. Hg
Absolute Stack Gas Pressure (Ps), in. Hg
where,
Pb 25.45 = barometric pressure, in. Hg
Pg 0.07 = static pressure, in. H2O
Ps 25.46 = in. Hg
Standard Meter Volume (Vmstd), dscf
where,
Y 1.005 = meter correction factor
Vm 38.138 = meter volume, cf
Pm 25.52 = absolute meter pressure, in. Hg
Tm 532.6 = absolute meter temperature, °R
Vmstd 32.394 = dscf
Standard Wet Volume (Vwstd), scf
where,
Vlc 210.2 = weight of H2O collected, g
Vwstd 9.913 = scf
Moisture Fraction (BWSsat), dimensionless (theoretical at saturated conditions)
where,
Ts 268.0 = stack temperature, °F
Ps 25.5 = absolute stack gas pressure, in. Hg
BWSsat 1.000 = dimensionless
Moisture Fraction (BWS), dimensionless
where,
Vwstd 9.913 = standard wet volume, scf
Vmstd 32.394 = standard meter volume, dscf
BWS 0.234 = dimensionless
Moisture Fraction (BWS), dimensionless
where,
BWSsat 1.000 = moisture fraction (theoretical at saturated conditions)
BWSmsd 0.234 = moisture fraction (measured)
BWS 0.234
Molecular Weight (DRY) (Md), lb/lb-mole
where,
CO2 3.9 = carbon dioxide concentration, %
O2 12.0 = oxygen concentration, %
Md 29.10 = lb/lb mol
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 3
AST-2024-2320
1
VFR
Vwstd = 0.04716 x Vlc
Vmstd =17.636 x Vm x Pm x Y
Tm
BWS ൌ Vwstd
ሺVwstd ൅ Vmstdሻ
Md ൌ ሺ0.44 ൈ % COଶሻ ൅ ሺ0.32 ൈ % O2ሻ ൅ ሺ0.28 ሺ100 െ % COଶ െ % O2ሻሻ
BWS ൌ BWSmsd unless BWSsat ൏ BWSmsd
BWSsat ൌ 10଺.ଷ଻ି ଶ,଼ଶ଻
୘ୱାଷ଺ହ
Ps
Ps ൌ Pb ൅ Pg
13.6
Pm ൌ Pb ൅ Δ H
13.6
14 of 161
Example Calculations
Location
Source
Project No.
Run No.
Parameter(s)
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 3
AST-2024-2320
1
VFR
Molecular Weight (WET) (Ms), lb/lb-mole
where,
Md 29.10 = molecular weight (DRY), lb/lb mol
BWS 0.234 = moisture fraction, dimensionless
Ms 26.50 = lb/lb mol
Average Velocity (Vs), ft/sec
where,
Cp 0.84 = pitot tube coefficient
Δ P1/2 0.228 = average pre/post test velocity head of stack gas, (in. H2O)1/2
Ts 727.7 = average pre/post test absolute stack temperature, °R
Ps 25.46 = absolute stack gas pressure, in. Hg
Ms 26.50 = molecular weight of stack gas, lb/lb mol
Vs 17.0 = ft/sec
Average Stack Gas Flow at Stack Conditions (Qa), acfm
where,
Vs 17.0 = stack gas velocity, ft/sec
As 1.67 = cross-sectional area of stack, ft
2
Qa 1,708 = acfm
Average Stack Gas Flow at Standard Conditions (Qs), dscfm
Ps
Ts
where,
Qa 1,708 = average stack gas flow at stack conditions, acfm
BWS 0.234 = moisture fraction, dimensionless
Ps 25.46 = absolute stack gas pressure, in. Hg
Ts 727.7 = average pre/post test absolute stack temperature, °R
Qs 807 = dscfm
Dry Gas Meter Calibration Check (Yqa), percent
where,
Y 1.005 = meter correction factor, dimensionless
Θ 60 = run time, min.
Vm 38.138 = total meter volume, dcf
Tm 532.6 = absolute meter temperature, °R
ΔH@ 1.595 = orifice meter calibration coefficient, in. H2O
Pb 25.45 = barometric pressure, in. Hg
ΔH avg 1.000 = average pressure differential of orifice, in H2O
Md 29.10 = molecular weight (DRY), lb/lb mol
(Δ H)1/2 1.000 = average square root pressure differential of orifice, (in. H2O)1/2
Yqa -1.0 = percent
Qsd = 17.636 x Qa x (1 - BWS) x
Ms ൌ Md ሺ1 െ BWSሻ ൅ 18.015 ሺBWSሻ
Vs ൌ 85.49 ൈ Cp ൈ ሺΔ P ଵ/ଶ ሻ avg ൈ Ts
Ps x Ms
Qa ൌ 60 ൈ Vs ൈ As
Yqa ൌ
Y െ Θ
Vm 0.0319 ൈ Tm ൈ 29
ΔH@ ൈ Pb ൅ Δ Havg.
13.6 ൈ Md
ΔH avg.
Y ൈ 100
15 of 161
Location:
Source:
Project No.:
Run No. /Method
O₂ - Outlet Concentration (C O₂), % dry
CMA
( CM - C0 )
where,
Cobs 11.95 = average analyzer value during test, % dry
Co 0.00 = average of pretest & posttest zero responses, % dry
CMA 12.00 = actual concentration of calibration gas, % dry
CM 11.99 = average of pretest & posttest calibration responses, % dry
CO₂11.96 = O₂ Concentration, % dry
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 3
AST-2024-2320
Run 1 / Method 3A
CO₂ = ( Cobs - C0 ) x

CO₂ - Outlet Concentration (C CO₂), % dry
C M A ( CM - C 0 )
where,
Cobs 3.91
Co 0.01
CMA 5.00
CM 5.01
CCO₂3.90
= average analyzer value during test, % dry
= average of pretest & posttest zero responses, % dry
= actual concentration of calibration gas, % dry
= average of pretest & posttest calibration responses, % dry
= CO₂ Concentration, % dry
CCO₂ = ( Cobs - C0 ) x
Example Calculations
16 of 161
Example Calculations
Location:
Source:
Project No.:
Run No. /Method
THC - Outlet Concentration (as C3H8) (CTHC), ppmvd
CTHCw
1 - BWS
where,
CTHCw 814.0 = THC - Outlet Concentration (as C3H8), ppmvw
BWS 0.234 = moisture fraction, unitless
CTHC 1062.7 = ppmvd
THC - Outlet Emission Rate (as C3H8) (ERTHC), lb/hr
where,
CTHC 1062.7 = THC - Outlet Concentration (as C3H8), ppmvd
MW 44.1 = THC molecular weight, g/g-mole
Qs 807 = stack gas volumetric flow rate at standard conditions, dscfm
ERTHC 5.9 = lb/hr
THC - Outlet Concentration (CTHCc), ppmvd as Ethanol
CTHC
RF
where,
CTHC 1062.68 = THC - Outlet Concentration, ppmvd
RF 0.34 = Response Factor, dimensionless
CTHCc 3106.53 = ppmvd
THC - Outlet Emission Rate (ERTHC), lb/hr as Ethanol
where,
CTHCc 3106.5 = THC - Outlet Concentration, ppmvd as Ethanol
MW 46.0684 = THC molecular weight, g/g-mole
Qs 807 = stack gas volumetric flow rate at standard conditions, dscfm
ERTHC 18.0 = lb/hr
NMEHC Concentration (as C3H8) (CNMEHC), ppmvd
where,
CTHC 1062.68 = THC Concentration (as C3H8), ppmvd
CCH4 893.33 = CH4 Concentration (as C3H8), ppmvd
CC2H6 55.27 = C2H6 Concentration (as C3H8), ppmvd
CNMEHC 114.08 = ppmvd
NMEHC Emission Rate (as C3H8) (ERNMEHC), lb/hr
where,
CNMEHC 114.08 = NMEHC Concentration (as C3H8), ppmvd
MW 44.1 = NMEHC molecular weight, g/g-mole
Qs 807 = stack gas volumetric flow rate at standard conditions, dscfm
ERNMEHC 0.63 = lb/hr
ERNMEHC =CNMEHC x MW x Qs x 60 x 28.32
24.04 x 1.0E06 x 454
CNMEHC =CTHC - CCH4 - CC2H6
CTHCc =
ERTHC =CTHC x MW x Qs x 60 x 28.32
x 1.0E06 x 454
ERTHC =CTHC x MW x Qs x 60 x 28.32
24.04 x 1.0E06 x 454
CTHC =
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 3
AST-2024-2320
Run 1 / Method 25A
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17 of 161
Location
Source(s)
Project No.
Date(s)
Where,
CTSavg 104.05 = average of all CTS calibration gas readings, ppm
CTScyl 108 = CTS bottle certified gas value, ppm
CTSR 96.3% = CTS recovery value, %
Spike Dilution Factor (DF), %
Where,
SF6dir 4.28 = average of direct tracer gas value readings
SF6nat 0.01 = average of native tracer gas value readings
SF6spike 0.174241 = average of dynamic spike tracer gas value readings
DF 3.84% = spike dilution factor, %
Calculated Spike (Spikecalc), ppm
Where,
DF 3.84% = spike dilution factor, %
Analytedir 94.20 = average of direct analyte gas values, ppm
Analyte nat 1.43 = average of native analyte gas values, ppm
Spikecalc 4.99 = calculated spike, ppm value, ppm
Spike Recovery Value (SpikeR), %
Where,
Spikecalc 4.99 = calculated spike, ppm value, ppm
Analytespike 4.49 = average of spiked analyte gas values, ppm
SpikeR 89.89% = spike recovery value, %
Pepperidge Farm, Richmond, UT
Unit 3
AST-2024-2320
6/11/2024
CTS Recovery Value (CTSR), %
𝐶𝑇𝑆௔௩௚
𝐶𝑇𝑆௖௬௟
ൈ 100
𝑆𝐹6௦௣௜௞௘ െ𝑆𝐹6௡௔௧
𝑆𝐹6ௗ௜௥
ൈ 100
𝐷𝐹 ൈ 𝐴𝑛𝑎𝑙𝑦𝑡𝑒𝑑𝑖𝑟൅ሺ𝐴𝑛𝑎𝑙𝑦𝑡𝑒௡௔௧ ൈ 1 െ𝐷𝐹 ሻ
𝐴𝑛𝑎𝑙𝑦𝑡𝑒௦௣௜௞௘
𝑆𝑝𝑖𝑘𝑒௖௔௟௖
ൈ 100
18 of 161
Appendix B
19 of 161
Process Line No. 3
20 of 161
Emissions Calculations
Location
Source
Project No.
Run Number Run 1 Run 2 Run 3 Average
Date 6/12/24 6/12/24 6/12/24 --
Start Time 9:00 11:10 12:40 --
Stop Time 10:00 12:09 13:39 --
Response Factor, dimensionless RF
0.34 0.34 0.34 0.34
Moisture Fraction, dimensionless BWS 0.234 0.215 0.220 0.223
Volumetric Flow Rate (M1-4), dscfm Qs 807 840 836 828
O₂ Concentration, % dry CO₂11.96 13.66 13.58 13.07
CO₂ Concentration, % dry CCO₂3.90 3.98 3.95 3.94
THC (as C₃H₈) Concentration, ppmvd CTHC 1062.68 912.42 876.39 950.50
THC (as C₃H₈) Concentration, ppmvw CTHCw 814.01 716.25 683.58 737.95
THC (as C₃H₈) Emission Rate, lb/hr ERTHC 5.9 5.3 5.0 5.4
THC (as Ethanol) Concentration, ppmvd CTHCcc 3106.53 2667.28 2561.95 2778.59
THC (as Ethanol) Concentration, lb/hr ERTHCc 18.00 16.08 15.38 16.49
CH4 Concentration, ppmvd CCH4 2680.00 2362.00 2291.00 2444.33
CH4 Concentration (as C₃H₈), ppmvd CCH4 as propane 893.33 787.33 763.67 814.78
C2H6 Concentration, ppmvd CC2H6 82.90 71.50 68.20 74.20
C2H6 Concentration (as C₃H₈), ppmvd CC2H6 as propane 55.27 47.67 45.47 49.47
NMEHC (as C₃H₈) Concentration, ppmvd CNMEHC 114.08 77.42 67.26 86.25
NMEHC (as C₃H₈) Emission Rate, lb/hr ERNMEHC 0.63 0.45 0.39 0.49
NMEHC (as Ethanol) Concentration, ppmvd CNMEHCc 333.49 226.33 196.61 252.14
NMEHC (as Ethanol) Concentration, lb/hr EFNMEHCc 1.93 1.36 1.18 1.49
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 3
AST-2024-2320
Source Data
Input Data - Outlet
Calculated Data - Outlet
21 of 161
Method 1 Data
Location
Source
Project No.
Date
Vertical
Circular
23.50 in
6.00 in
17.50 in
1.67 ft2
2
1
6.1 ft
4.2 (must be > 0.5)
3.3 ft
2.3 (must be > 2)
16
16
Measurer (Initial and Date):SRW 6/11/24
Reviewer (Initial and Date):MDM 6/11/24
2345 6 789101112
1 14.6 -- 6.7 --4.4 -- 3.2 -- 2.6 -- 2.1 1 3.2 0.56 6 9/16
2 85.4 -- 25.0 -- 14.6 -- 10.5 -- 8.2 -- 6.7 2 10.5 1.84 7 13/16
3 -- -- 75.0 -- 29.6 -- 19.4 -- 14.6 -- 11.8 3 19.4 3.40 9 3/8
4 -- -- 93.3 -- 70.4 -- 32.3 -- 22.6 -- 17.7 4 32.3 5.65 11 5/8
5 -- -- -- -- 85.4 -- 67.7 -- 34.2 -- 25.0 5 67.7 11.85 17 7/8
6 -- -- -- -- 95.6 -- 80.6 -- 65.8 -- 35.6 6 80.6 14.11 20 1/8
7 -- -- -- ------ 89.5 -- 77.4 -- 64.4 7 89.5 15.66 21 11/16
8 -- -- -- ------ 96.8 -- 85.4 -- 75.0 8 96.8 16.94 22 15/16
9 -- -- -- ------ -- -- 91.8 -- 82.3 9 -- -- --
10 -- -- -- ------ -- -- 97.4 -- 88.2 10 -- -- --
11 -- -- -- ------ -- -- -- -- 93.3 11 -- -- --
12 -- -- -- ------ -- -- -- -- 97.9 12 -- -- --
*Percent of stack diameter from inside wall to traverse point.
A = 6.08333333333333 ft.
B = 3.33333333333333 ft.
Depth of Duct = 17.5 in.
Cross Sectional Area of Duct:
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 3
AST-2024-2320
06/11/24
Stack Parameters
Duct Orientation:
Duct Design:
Distance from Far Wall to Outside of Port:
Nipple Length:
Depth of Duct:
No. of Test Ports:
Number of Readings per Point:
Distance A:
Distance A Duct Diameters:
Distance B:
Distance B Duct Diameters:
Minimum Number of Traverse Points:
Actual Number of Traverse Points:
CIRCULAR DUCT
Number of traverse points on a diameter
Stack Diagram
Cross Sectional Area
LOCATION OF TRAVERSE POINTS
Traverse
Point
% of
Diameter
Distance
from inside
wall
Distance
from
outside of
port
Upstream
Disturbance
Downstream
Disturbance
B
A
22 of 161
Cyclonic Flow Check
Location
Source
Project No.
Date
Sample Point Angle (ΔP=0)
1 15
2 15
3 10
4 10
5 10
6 5
7 10
8 15
9 15
10 10
11 10
12 10
13 15
14 10
15 10
16 15
Average 11.6
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 3
AST-2024-2320
6/12/24
23 of 161
Field Data
Method 2 Data
Location
Source
Project No.
Δ P
(in. WC)
Ts
(°F)
Δ P
(in. WC)
Ts
(°F)
Δ P
(in. WC)
Ts
(°F)
0.05 268 0.06 249 0.05 248
0.06 268 0.07 249 0.06 248
0.07 268 0.06 249 0.06 248
0.06 268 0.06 249 0.07 248
0.05 268 0.06 249 0.06 248
0.05 268 0.05 249 0.05 248
0.03 268 0.03 249 0.04 248
0.04 268 0.02 249 0.03 248
0.06 268 0.07 249 0.05 248
0.07 268 0.08 249 0.06 248
0.07 268 0.06 249 0.07 248
0.07 268 0.06 249 0.07 248
0.06 268 0.06 249 0.06 248
0.04 268 0.06 249 0.06 248
0.04 268 0.04 249 0.04 248
0.03 268 0.03 249 0.03 248
Average
Square Root of ΔP, (in. WC)1/2 (ΔP)1/2 0.230
Average ΔP, in. WC (ΔP)0.05
Pitot Tube Coefficient (Cp)0.840
Barometric Pressure, in. Hg (Pb)25.45
Static Pressure, in. WC (Pg)0.05
Stack Pressure, in. Hg (Ps)25.45
Average Temperature, °F (Ts)255.0
Average Temperature, °R (Ts)714.7
Measured Moisture Fraction (BWSmsd)0.223
Moisture Fraction @ Saturation (BWSsat)1.000
Moisture Fraction (BWS)0.223
O2 Concentration, % (O2)13.07
CO2 Concentration, % (CO2)3.82
Molecular Weight, lb/lb-mole (dry) (Md)29.13
Molecular Weight, lb/lb-mole (wet) (Ms)26.65
Velocity, ft/sec (Vs)16.9
VFR at stack conditions, acfm (Qa)1,696
VFR at standard conditions, scfh (Qsw)63,912
VFR at standard conditions, scfm (Qsw)1,065
VFR at standard conditions, dscfm (Qsd)827
8
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 3
AST-2024-2320
Run No.1 2 3
Status VALID VALID VALID
Date 6/12/24 6/12/24 6/12/24
Stop Time 9:18 11:29 13:37
Start Time 9:10 11:18 13:20
Traverse Point
A1
2
3
4
Leak Check Pass Pass Pass
3
4
5
6
7
5
6
7
8
B1
2
0.840 0.840 0.840
0.05 0.05 0.05
0.228 0.230 0.230
0.07 0.04 0.03
25.45 25.45 25.45
268.0 249.0 248.0
25.46 25.45 25.45
0.234 0.215 0.220
727.7 708.7 707.7
29.10 29.18 29.12
11.96 13.66 13.58
3.90 3.98 3.59
17.0 16.9 16.9
26.50 26.78 26.68
1,708 1,689 1,690
1,053 1,070 1,072
63,207 64,202 64,327
807 840 836
1.0001.0001.000
0.2200.2150.234
24 of 161
Method 4 Data
Location
Source
Project No.
Parameter(s)
Console Units / Method ft3 M4
Run No.
Date
Status
Start Time
End Time
Run Time, min (θ)
Meter ID
Meter Correction Factor (Y)
Orifice Calibration Value (ΔH @)
Max Vacuum, in. Hg
Post Leak Check, ft3/min (at max vac.)
Meter Volume, ft3
Total Meter Volume, ft3 (Vm)
Meter Probe Filter Vacuum Imp. Exit Meter Probe Filter Vacuum Imp. Exit Meter Probe Filter Vacuum Imp. Exit
67 -- -- 1 58 85 -- -- 2 58 100 -- -- 1 61
70 -- -- 1 52 90 -- -- 2 53 101 -- -- 1 58
69 -- -- 1 48 92 -- -- 2 51 101 -- -- 1 57
70 -- -- 1 47 92 -- -- 2 52 102 -- -- 1 56
72 -- -- 1 47 94 -- -- 2 52 102 -- -- 1 56
74 -- -- 1 48 95 -- -- 2 52 102 -- -- 1 56
74 -- -- 1 48 98 -- -- 2 52 102 -- -- 1 55
74 -- -- 1 48 100 -- -- 2 53 102 -- -- 1 54
75 -- -- 1 49 100 -- -- 2 53 102 -- -- 1 54
75 -- -- 1 49 101 -- -- 2 53 102 -- -- 1 54
76 -- -- 1 50 101 -- -- 2 53 102 -- -- 1 54
76 -- -- 1 50 102 -- -- 2 53 102 -- -- 1 55
76 -- -- 1 50 102 -- -- 2 53 102 -- -- 1 55
Average Temperature, °F (Tm)73 -- -- 1 50 96 -- -- 2 53 102 -- -- 1 56
Average Temperature, °R (Tm)533 -- -- -- -- 556 -- -- -- -- 561 -- -- -- --
Minimum Temperature, °F 67 -- -- 1 47 85 -- -- 2 51 100 -- -- 1 54
Maximum Temperature, °F 76 -- -- 1 58 102 -- -- 2 58 102 -- -- 1 61
Barometric Pressure, in. Hg (Pb)
Meter Orifice Pressure , in. WC (ΔH)
Meter Pressure, in. Hg (Pm)
Standard Meter Volume, ft3 (Vmstd)
Analysis Type
Impinger 1, Pre/Post Test, g 750.7 857.9 107.2 857.9 958.0 100.1 682.3 794.6 112.3
Impinger 2, Pre/Post Test, g 701.2 771.9 70.7 771.9 798.1 26.2 678.1 700.5 22.4
Impinger 3, Pre/Post Test, g 636.7 652.3 15.6 652.3 695.3 43.0 699.3 745.5 46.2
Impinger 4, Pre/Post Test, g 916.8 933.5 16.7 933.5 946.3 12.8 915.5 924.9 9.4
Volume Water Collected, mL (Vlc)
Standard Water Volume, ft3 (Vwstd)
Moisture Fraction Measured (BWS)
Gas Molecular Weight, lb/lb-mole (dry) (Md)
DGM Calibration Check Value (Yqa)
Temperature, °F
0
5
30
35
60
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 3
AST-2024-2320
VFR
1
VALID
6/12/24
9:00
10:00
60
MB 702
1.005
1.595
VALID
12:40
13:40
60
MB 702
1.005
1.595
1
0.000
29.18
-2.2
190.3
8.975
0.220
0.0
29.12
H2O
H2O
Empty
H2O
Empty
25.45
1.000
25.45
1.000
2
6/12/24
3
6/12/24
VALID
11:10
12:10
60
MB 702
1.005
1.595
2
0.000
223.944
227.100
230.400
233.700
236.900
240.000
243.400
246.700
250.100
253.300
256.700
260.100
263.445
213.800
217.200
220.400
223.608
185.170
188.200
191.400
194.500
197.700
201.100
204.200
207.400
210.500
38.138 38.438 39.501
H2O
182.1
8.588
0.215
29.10
-1.0
25.52
31.276
25.52
31.833
Gravimetric Gravimetric
Silica Silica Silica
25.45
210.2
9.913
0.234
1.000
25.52
32.394
H2O
H2O
Empty
Gravimetric
1
0.000
146.732
149.900
153.000
156.200
159.200
162.300
165.400
168.500
171.600
174.800
178.400
181.700
184.87060
0
5
10
15
20
25
10
15
20
25
40
45
50
55
30
35
40
45
50
55
25 of 161
Run 1 - RM Data
Location:
Source:
Project No.:
Date:
Time O₂ - Outlet CO₂ - Outlet THC - Outlet
Unit % dry % dry ppmvw
Status Valid Valid Valid
Uncorrected Run Average (Cobs)11.95 3.91 814.01
Cal Gas Concentration (CMA)12.00 5.00 1000.00
Pretest System Zero Response 0.00 0.01 4.09
Posttest System Zero Response 0.00 0.00 0.00
Average Zero Response (Co)0.00 0.01 2.05
Pretest System Cal Response 12.01 4.95 996.44
Posttest System Cal Response 11.97 5.07 1002.33
Average Cal Response (CM)11.99 5.01 999.39
Corrected Run Average (Corr)11.96 3.90 NA
9:00 11.88 3.91 759.73
9:01 11.91 3.88 756.74
9:02 11.92 3.88 759.92
9:03 11.91 3.90 775.87
9:04 11.86 3.92 784.71
9:05 11.91 3.88 792.26
9:06 11.92 3.91 804.29
9:07 11.88 3.96 803.92
9:08 11.98 3.89 792.21
9:09 11.97 3.89 791.50
9:10 11.96 3.90 792.72
9:11 11.92 3.94 803.10
9:12 11.95 3.91 799.17
9:13 11.92 3.94 788.25
9:14 11.95 3.90 790.64
9:15 11.98 3.89 805.74
9:16 11.87 3.96 821.92
9:17 11.91 3.94 807.68
9:18 11.91 3.92 818.34
9:19 11.94 3.90 817.71
9:20 11.87 3.95 822.98
9:21 11.97 3.90 801.58
9:22 11.96 3.89 811.28
9:23 11.90 3.94 821.15
9:24 11.94 3.92 807.69
9:25 11.96 3.91 817.54
9:26 11.97 3.89 812.79
9:27 11.90 3.95 823.09
9:28 11.98 3.90 808.13
9:29 11.90 3.95 833.16
9:30 11.91 3.96 809.19
9:31 11.94 3.92 805.12
9:32 11.96 3.91 822.14
9:33 11.90 3.96 816.95
9:34 11.91 3.94 825.73
9:35 11.99 3.88 810.21
9:36 11.98 3.89 827.63
9:37 11.95 3.92 813.44
9:38 12.01 3.87 813.35
9:39 12.00 3.88 820.48
9:40 11.94 3.92 826.66
9:41 11.90 3.94 827.56
9:42 11.96 3.90 818.49
9:43 11.97 3.90 814.24
9:44 11.99 3.87 812.84
9:45 11.98 3.88 831.65
9:46 12.00 3.87 822.52
9:47 12.00 3.86 819.86
9:48 12.03 3.84 822.45
9:49 12.02 3.84 840.75
9:50 11.96 3.90 851.25
9:51 11.94 3.92 828.68
9:52 11.95 3.91 836.43
9:53 12.00 3.86 839.58
9:54 11.96 3.91 839.84
9:55 11.93 3.92 842.46
9:56 11.95 3.90 846.19
9:57 11.91 3.93 842.58
9:58 12.00 3.86 817.37
9:59 11.99 3.87 849.36
10:00 11.96 3.89 834.02
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 3
AST-2024-2320
6/12/24
26 of 161
Run 2 - RM Data
Location:
Source:
Project No.:
Date:
Time O₂ - Outlet CO₂ - Outlet THC - Outlet
Unit % dry % dry ppmvw
Status Valid Valid Valid
Uncorrected Run Average (Cobs)13.74 4.03 716.25
Cal Gas Concentration (CMA)12.00 5.00 1000.00
Pretest System Zero Response 0.00 0.00 0.00
Posttest System Zero Response 0.02 0.00 0.00
Average Zero Response (Co)0.01 0.00 0.00
Pretest System Cal Response 11.97 5.07 1002.33
Posttest System Cal Response 12.18 5.04 1001.51
Average Cal Response (CM)12.08 5.06 1001.92
Corrected Run Average (Corr)13.66 3.98 NA
11:10 13.70 4.13 728.41
11:11 13.59 4.15 747.02
11:12 13.57 4.14 735.53
11:13 13.64 4.10 716.40
11:14 13.70 4.07 705.72
11:15 13.74 4.05 706.59
11:16 13.75 4.04 701.44
11:17 13.77 4.03 703.01
11:18 13.80 4.01 707.18
11:19 13.80 4.00 704.61
11:20 13.78 4.01 695.47
11:21 13.79 4.00 704.75
11:22 13.83 3.98 705.78
11:23 13.74 4.04 709.89
11:24 13.79 4.00 727.16
11:25 13.76 4.01 744.51
11:26 13.74 4.03 732.57
11:27 13.73 4.03 743.12
11:28 13.74 4.02 749.34
11:29 13.72 4.04 744.07
11:30 13.69 4.06 742.60
11:31 13.69 4.06 752.98
11:32 13.72 4.04 736.46
11:33 13.72 4.04 731.83
11:34 13.64 4.08 748.74
11:35 13.69 4.05 744.31
11:36 13.67 4.07 731.13
11:37 13.71 4.04 717.22
11:38 13.76 4.01 730.04
11:39 13.76 4.00 742.87
11:40 13.72 4.02 734.96
11:41 13.72 4.03 747.33
11:42 13.73 4.02 737.28
11:43 13.74 4.02 717.05
11:44 13.75 4.00 723.45
11:45 13.79 3.97 729.39
11:46 13.75 4.00 721.52
11:47 13.74 4.01 705.14
11:48 13.77 3.99 710.08
11:49 13.75 4.00 705.50
11:50 13.71 4.03 709.95
11:51 13.76 3.99 689.37
11:52 13.74 4.01 712.10
11:53 13.72 4.02 696.55
11:54 13.72 4.02 710.70
11:55 13.71 4.03 702.58
11:56 13.74 4.01 697.06
11:57 13.74 4.00 682.10
11:58 13.76 3.99 685.66
11:59 13.72 4.01 707.68
12:00 13.71 4.02 691.37
12:01 13.73 4.01 696.77
12:02 13.72 4.01 709.93
12:03 13.69 4.03 701.41
12:04 13.77 4.01 686.50
12:05 13.96 3.97 685.93
12:06 13.97 4.02 696.44
12:07 13.96 4.01 692.71
12:08 13.94 4.00 693.63
12:09 13.73 4.02 704.23
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 3
AST-2024-2320
6/12/24
27 of 161
Run 3 - RM Data
Location:
Source:
Project No.:
Date:
Time O₂ - Outlet CO₂ - Outlet THC - Outlet
Unit % dry % dry ppmvw
Status Valid Valid Valid
Uncorrected Run Average (Cobs)13.74 3.97 683.58
Cal Gas Concentration (CMA)12.00 5.00 1000.00
Pretest System Zero Response 0.02 0.00 0.00
Posttest System Zero Response 0.13 0.00 0.00
Average Zero Response (Co)0.08 0.00 0.00
Pretest System Cal Response 12.18 5.04 1001.51
Posttest System Cal Response 12.11 5.02 995.77
Average Cal Response (CM)12.15 5.03 998.64
Corrected Run Average (Corr)13.58 3.95 NA
12:40 13.78 3.98 698.37
12:41 13.77 3.98 698.11
12:42 13.75 4.00 698.88
12:43 13.74 3.99 696.53
12:44 13.71 4.01 683.18
12:45 13.74 3.99 684.22
12:46 13.73 4.01 695.74
12:47 13.71 4.02 693.06
12:48 13.69 4.02 711.02
12:49 13.72 4.01 700.03
12:50 13.72 4.01 692.80
12:51 13.74 3.99 679.57
12:52 13.78 3.96 675.03
12:53 13.80 3.96 689.00
12:54 13.74 3.98 694.02
12:55 13.67 4.01 702.24
12:56 13.69 4.00 695.65
12:57 13.67 4.01 672.93
12:58 13.74 3.96 682.11
12:59 13.73 3.97 686.02
13:00 13.70 3.99 690.12
13:01 13.66 4.01 694.81
13:02 13.70 3.98 685.84
13:03 13.73 3.96 684.96
13:04 13.73 3.97 689.40
13:05 13.78 3.92 689.30
13:06 13.77 3.93 680.09
13:07 13.75 3.94 680.01
13:08 13.75 3.94 685.00
13:09 13.71 3.98 677.03
13:10 13.74 3.95 675.02
13:11 13.76 3.94 668.73
13:12 13.78 3.94 676.47
13:13 13.73 3.98 679.15
13:14 13.73 3.97 676.40
13:15 13.72 3.97 683.38
13:16 13.77 3.95 679.63
13:17 13.74 3.97 672.54
13:18 13.74 3.97 675.84
13:19 13.71 3.99 685.02
13:20 13.73 3.96 687.85
13:21 13.73 3.97 685.05
13:22 13.73 3.96 683.14
13:23 13.74 3.96 682.81
13:24 13.72 3.97 670.30
13:25 13.75 3.96 671.96
13:26 13.71 3.99 680.73
13:27 13.68 4.00 683.44
13:28 13.74 3.96 685.82
13:29 13.73 3.97 689.42
13:30 13.72 3.97 687.69
13:31 13.69 3.99 672.57
13:32 13.80 3.92 665.50
13:33 13.77 3.93 674.01
13:34 13.77 3.93 672.83
13:35 13.78 3.92 685.34
13:36 13.74 3.96 682.73
13:37 13.74 3.95 676.03
13:38 13.80 3.92 657.24
13:39 13.79 3.92 663.35
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 3
AST-2024-2320
6/12/24
28 of 161
Process Line No. 10
29 of 161
Emissions Calculations
Location
Source
Project No.
Run Number Run 1 Run 2 Run 3 Average
Date 6/12/24 6/12/24 6/12/24 --
Start Time 15:25 16:58 18:30 --
Stop Time 16:24 17:57 19:29 --
Response Factor, dimensionless RF
0.34 0.34 0.34 0.34
Moisture Fraction, dimensionless BWS 0.296 0.270 0.258 0.275
Volumetric Flow Rate (M1-4), dscfm Qs 3,096 3,192 3,349 3,212
O₂ Concentration, % dry CO₂10.59 11.57 10.63 10.93
CO₂ Concentration, % dry CCO₂5.72 5.17 4.81 5.24
THC (as C₃H₈) Concentration, ppmvd CTHC 1447.61 1307.81 2036.78 1597.40
THC (as C₃H₈) Concentration, ppmvw CTHCw 1019.12 954.70 1511.29 1161.70
THC (as C₃H₈) Emission Rate, lb/hr ERTHC 30.8 28.7 46.9 35.5
THC (as Ethanol) Concentration, ppmvd CTHCcc 4231.79 3823.12 5954.12 4669.68
THC (as Ethanol) Concentration, lb/hr ERTHCc 94.1 87.6 143.1 108.3
CH4 Concentration, ppmvd CCH4 3795.00 4316.00 6604.00 4905.00
CH4 Concentration (as C₃H₈), ppmvd CCH4 as propane 1265.00 1438.67 2201.33 1635.00
C2H6 Concentration, ppmvd CC2H6 118.00 139.00 199.00 152.00
C2H6 Concentration (as C₃H₈), ppmvd CC2H6 as propane 78.67 92.67 132.67 101.33
NMEHC (as C₃H₈) Concentration, ppmvd CNMEHC 103.94 0.00 0.00 34.65
NMEHC (as C₃H₈) Emission Rate, lb/hr ERNMEHC 2.21 0.00 0.00 0.74
NMEHC (as Ethanol) Concentration, ppmvd CNMEHCc 303.85 0.00 0.00 101.28
NMEHC (as Ethanol) Concentration, lb/hr EFNMEHCc 6.75 0.00 0.00 2.25
*Underlined values are negative due to subtraction and have been corrected to zero.
Input Data - Outlet
Calculated Data - Outlet
Source Data
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 10
AST-2024-2320
30 of 161
Method 1 Data
Location
Source
Project No.
Date
Vertical
Circular
28.00 in
1.50 in
26.50 in
3.83 ft2
2
1
3.0 ft
1.4 (must be > 0.5)
10.8 ft
4.9 (must be > 2)
16
16
Measurer (Initial and Date):SRW 6/12/24
Reviewer (Initial and Date):MDM 6/12/24
2345 6 789101112
1 14.6 -- 6.7 --4.4 -- 3.2 -- 2.6 -- 2.1 1 3.2 1.00 2 1/2
2 85.4 -- 25.0 -- 14.6 -- 10.5 -- 8.2 -- 6.7 2 10.5 2.78 4 5/16
3 -- -- 75.0 -- 29.6 -- 19.4 -- 14.6 -- 11.8 3 19.4 5.14 6 5/8
4 -- -- 93.3 -- 70.4 -- 32.3 -- 22.6 -- 17.7 4 32.3 8.56 10 1/16
5 -- -- -- -- 85.4 -- 67.7 -- 34.2 -- 25.0 5 67.7 17.94 19 7/16
6 -- -- -- -- 95.6 -- 80.6 -- 65.8 -- 35.6 6 80.6 21.36 22 7/8
7 -- -- -- ------ 89.5 -- 77.4 -- 64.4 7 89.5 23.72 25 3/16
8 -- -- -- ------ 96.8 -- 85.4 -- 75.0 8 96.8 25.50 27
9 -- -- -- ------ -- -- 91.8 -- 82.3 9 -- -- --
10 -- -- -- ------ -- -- 97.4 -- 88.2 10 -- -- --
11 -- -- -- ------ -- -- -- -- 93.3 11 -- -- --
12 -- -- -- ------ -- -- -- -- 97.9 12 -- -- --
*Percent of stack diameter from inside wall to traverse point.
A = 3 ft.
B = 10.8 ft.
Depth of Duct = 26.5 in.
Cross Sectional Area of Duct:
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 10
AST-2024-2320
06/12/24
Stack Parameters
Duct Orientation:
Duct Design:
Distance from Far Wall to Outside of Port:
Nipple Length:
Depth of Duct:
No. of Test Ports:
Number of Readings per Point:
Distance A:
Distance A Duct Diameters:
Distance B:
Distance B Duct Diameters:
Minimum Number of Traverse Points:
Actual Number of Traverse Points:
CIRCULAR DUCT
Number of traverse points on a diameter
Stack Diagram
Cross Sectional Area
LOCATION OF TRAVERSE POINTS
Traverse
Point
% of
Diameter
Distance
from inside
wall
Distance
from
outside of
port
Upstream
Disturbance
Downstream
Disturbance
B
A
31 of 161
Cyclonic Flow Check
Location
Source
Project No.
Date
Sample Point Angle (ΔP=0)
1 10
2 15
3 17
4 17
5 15
6 15
7 10
8 18
9 20
10 20
11 15
12 15
13 15
14 18
15 18
16 18
Average 16.0
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 10
AST-2024-2320
6/12/24
32 of 161
Field Data
Method 2 Data
Location
Source
Project No.
Δ P
(in. WC)
Ts
(°F)
Δ P
(in. WC)
Ts
(°F)
Δ P
(in. WC)
Ts
(°F)
0.25 635 0.22 638 0.29 648
0.24 635 0.26 638 0.22 648
0.22 635 0.27 638 0.20 648
0.27 635 0.30 638 0.28 648
0.29 635 0.21 638 0.27 648
0.27 635 0.22 638 0.28 648
0.27 635 0.25 638 0.28 648
0.28 635 0.28 638 0.29 648
0.20 635 0.24 638 0.28 648
0.22 635 0.22 638 0.27 648
0.23 635 0.26 638 0.27 648
0.26 635 0.28 638 0.28 648
0.28 635 0.26 638 0.30 648
0.28 635 0.28 638 0.30 648
0.27 635 0.28 638 0.30 648
0.26 635 0.27 638 0.31 648
Average
Square Root of ΔP, (in. WC)1/2 (ΔP)1/2 0.512
Average ΔP, in. WC (ΔP)0.26
Pitot Tube Coefficient (Cp)0.840
Barometric Pressure, in. Hg (Pb)25.45
Static Pressure, in. WC (Pg)0.03
Stack Pressure, in. Hg (Ps)25.45
Average Temperature, °F (Ts)640.5
Average Temperature, °R (Ts)1100.1
Measured Moisture Fraction (BWSmsd)0.275
Moisture Fraction @ Saturation (BWSsat)1.000
Moisture Fraction (BWS)0.275
O2 Concentration, % (O2)10.93
CO2 Concentration, % (CO2)5.23
Molecular Weight, lb/lb-mole (dry) (Md)29.27
Molecular Weight, lb/lb-mole (wet) (Ms)26.18
Velocity, ft/sec (Vs)47.2
VFR at stack conditions, acfm (Qa)10,852
VFR at standard conditions, scfh (Qsw)265,656
VFR at standard conditions, scfm (Qsw)4,428
VFR at standard conditions, dscfm (Qsd)3,212
8
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 10
AST-2024-2320
Run No.1 2 3
Status VALID VALID VALID
Date 6/12/24 6/12/24 6/12/24
Stop Time 15:51 17:55 19:02
Start Time 15:40 17:40 18:50
Traverse Point
A1
2
3
4
Leak Check Pass Pass Pass
3
4
5
6
7
5
6
7
8
B1
2
0.840 0.840 0.840
0.26 0.26 0.28
0.505 0.506 0.525
0.02 0.04 0.02
25.45 25.45 25.45
634.6 638.4 648.4
25.45 25.45 25.45
0.296 0.270 0.258
1094.3 1098.1 1108.1
29.34 29.29 29.19
10.59 11.57 10.63
5.72 5.17 4.81
46.6 46.5 48.5
25.99 26.24 26.31
10,718 10,697 11,142
4,396 4,373 4,514
263,787 262,362 270,818
3,096 3,192 3,349
1.0001.0001.000
0.2580.2700.296
33 of 161
Method 4 Data
Location
Source
Project No.
Parameter(s)
Console Units / Method ft3 M4
Run No.
Date
Status
Start Time
End Time
Run Time, min (θ)
Meter ID
Meter Correction Factor (Y)
Orifice Calibration Value (ΔH @)
Max Vacuum, in. Hg
Post Leak Check, ft3/min (at max vac.)
Meter Volume, ft3
Total Meter Volume, ft3 (Vm)
Meter Probe Filter Vacuum Imp. Exit Meter Probe Filter Vacuum Imp. Exit Meter Probe Filter Vacuum Imp. Exit
100 -- -- 2 59 100 -- -- 2 60 100 -- -- 2 57
101 -- -- 2 57 101 -- -- 2 52 102 -- -- 2 54
101 -- -- 2 52 101 -- -- 2 49 102 -- -- 2 54
102 -- -- 2 48 101 -- -- 2 50 102 -- -- 2 52
102 -- -- 2 48 102 -- -- 2 51 103 -- -- 2 51
102 -- -- 2 49 102 -- -- 2 51 103 -- -- 2 51
102 -- -- 2 50 102 -- -- 2 51 103 -- -- 2 51
102 -- -- 2 50 102 -- -- 2 52 103 -- -- 2 51
102 -- -- 2 51 102 -- -- 2 52 103 -- -- 2 51
102 -- -- 2 52 103 -- -- 2 52 103 -- -- 2 52
102 -- -- 2 52 103 -- -- 2 52 103 -- -- 2 52
102 -- -- 2 52 103 -- -- 2 53 103 -- -- 2 52
102 -- -- 2 52 103 -- -- 2 53 103 -- -- 2 52
Average Temperature, °F (Tm)102 -- -- 2 52 102 -- -- 2 52 103 -- -- 2 52
Average Temperature, °R (Tm)561 -- -- -- -- 562 -- -- -- -- 562 -- -- -- --
Minimum Temperature, °F 100 -- -- 2 48 100 -- -- 2 49 100 -- -- 2 51
Maximum Temperature, °F 102 -- -- 2 59 103 -- -- 2 60 103 -- -- 2 57
Barometric Pressure, in. Hg (Pb)
Meter Orifice Pressure , in. WC (ΔH)
Meter Pressure, in. Hg (Pm)
Standard Meter Volume, ft3 (Vmstd)
Analysis Type
Impinger 1, Pre/Post Test, g 707.6 939.2 231.6 768.8 941.0 172.2 722.6 935.3 212.7
Impinger 2, Pre/Post Test, g 700.5 737.7 37.2 737.7 838.7 101.0 729.8 767.1 37.3
Impinger 3, Pre/Post Test, g 645.5 650.8 5.3 650.8 655.1 4.3 655.1 660.6 5.5
Impinger 4, Pre/Post Test, g 924.9 933.1 8.2 934.8 947.5 12.7 947.5 958.8 11.3
Volume Water Collected, mL (Vlc)
Standard Water Volume, ft3 (Vwstd)
Moisture Fraction Measured (BWS)
Gas Molecular Weight, lb/lb-mole (dry) (Md)
DGM Calibration Check Value (Yqa)
Temperature, °F
0
5
30
35
60
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 10
AST-2024-2320
VFR
1
VALID
6/12/24
15:35
16:35
60
MB 702
1.005
1.595
VALID
18:30
19:30
60
MB 702
1.005
1.595
2
0.000
29.29
3.2
266.8
12.582
0.258
0.9
29.19
H2O
H2O
Empty
H2O
Empty
29.45
1.100
29.45
1.100
2
6/12/24
3
6/12/24
VALID
16:58
17:58
60
MB 702
1.005
1.595
2
0.000
343.112
346.700
349.900
353.100
356.600
359.700
363.100
366.300
369.600
371.800
375.000
378.300
381.970
332.700
335.900
339.100
342.815
303.136
306.400
309.700
312.900
316.200
319.600
322.900
326.100
329.500
39.328 39.679 38.858
H2O
290.2
13.686
0.270
29.34
-0.1
29.53
36.981
29.53
36.176
Gravimetric Gravimetric
Silica Silica Silica
25.45
282.3
13.313
0.296
1.000
25.52
31.693
H2O
H2O
Empty
Gravimetric
2
0.000
263.648
267.000
270.200
273.600
276.800
280.100
283.300
286.500
289.700
293.000
296.200
299.600
302.97660
0
5
10
15
20
25
10
15
20
25
40
45
50
55
30
35
40
45
50
55
34 of 161
Run 1 - RM Data
Location:
Source:
Project No.:
Date:
Time O₂ - Outlet CO₂ - Outlet THC - Outlet
Unit % dry % dry ppmvw
Status Valid Valid Valid
Uncorrected Run Average (Cobs)10.64 5.72 1019.12
Cal Gas Concentration (CMA)12.00 5.00 1000.00
Pretest System Zero Response 0.13 0.00 0.00
Posttest System Zero Response 0.01 0.00 0.00
Average Zero Response (Co)0.07 0.00 0.00
Pretest System Cal Response 12.11 5.02 995.77
Posttest System Cal Response 11.98 4.97 1009.57
Average Cal Response (CM)12.05 5.00 1002.67
Corrected Run Average (Corr)10.59 5.72 NA
15:25 10.74 5.72 1,051.78
15:26 10.95 5.62 987.86
15:27 10.85 5.65 1,013.80
15:28 10.93 5.60 999.72
15:29 10.61 5.81 1,076.06
15:30 10.42 5.88 1,118.42
15:31 10.56 5.78 1,027.74
15:32 10.68 5.72 1,015.74
15:33 10.69 5.70 969.48
15:34 10.79 5.63 984.32
15:35 10.66 5.71 1,088.24
15:36 10.71 5.68 1,022.57
15:37 10.68 5.69 1,008.60
15:38 10.54 5.78 1,036.10
15:39 10.72 5.67 977.12
15:40 10.45 5.85 1,101.24
15:41 10.62 5.74 1,031.62
15:42 10.82 5.60 963.05
15:43 10.65 5.72 1,047.49
15:44 10.91 5.54 911.25
15:45 10.74 5.64 1,042.82
15:46 10.73 5.67 1,034.43
15:47 10.71 5.66 1,003.89
15:48 10.57 5.76 1,024.56
15:49 10.59 5.75 1,052.45
15:50 10.41 5.87 1,160.05
15:51 10.67 5.69 1,016.95
15:52 10.72 5.66 1,012.49
15:53 10.62 5.73 1,042.46
15:54 10.76 5.63 984.94
15:55 10.41 5.86 1,090.23
15:56 10.60 5.73 968.93
15:57 10.63 5.71 1,032.54
15:58 10.56 5.78 1,034.08
15:59 10.83 5.58 935.86
16:00 10.65 5.69 1,011.34
16:01 10.67 5.70 980.02
16:02 10.65 5.70 991.29
16:03 10.63 5.70 985.85
16:04 10.63 5.73 1,032.20
16:05 10.50 5.80 1,024.78
16:06 10.52 5.78 1,036.39
16:07 10.50 5.79 1,034.34
16:08 10.80 5.60 937.24
16:09 10.57 5.75 1,058.70
16:10 10.49 5.79 1,026.97
16:11 10.54 5.77 988.78
16:12 10.44 5.84 1,050.15
16:13 10.56 5.75 981.54
16:14 10.66 5.70 1,000.13
16:15 10.63 5.70 981.02
16:16 10.87 5.54 916.02
16:17 10.52 5.77 1,083.44
16:18 10.52 5.79 1,030.44
16:19 10.62 5.71 978.32
16:20 10.41 5.84 1,081.17
16:21 10.53 5.78 1,051.07
16:22 10.55 5.76 1,023.36
16:23 10.80 5.60 933.73
16:24 10.59 5.72 1,059.83
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 10
AST-2024-2320
6/12/24
35 of 161
Run 2 - RM Data
Location:
Source:
Project No.:
Date:
Time O₂ - Outlet CO₂ - Outlet THC - Outlet
Unit % dry % dry ppmvw
Status Valid Valid Valid
Uncorrected Run Average (Cobs)11.56 5.12 954.70
Cal Gas Concentration (CMA)12.00 5.00 1000.00
Pretest System Zero Response 0.01 0.00 0.00
Posttest System Zero Response 0.00 0.00 0.00
Average Zero Response (Co)0.01 0.00 0.00
Pretest System Cal Response 11.98 4.97 1009.57
Posttest System Cal Response 12.00 4.93 1002.09
Average Cal Response (CM)11.99 4.95 1005.83
Corrected Run Average (Corr)11.57 5.17 NA
16:58 10.67 5.21 967.74
16:59 11.25 5.10 909.88
17:00 11.48 5.02 899.95
17:01 11.59 5.02 903.18
17:02 11.70 5.01 879.34
17:03 11.53 5.13 912.48
17:04 11.61 5.07 882.11
17:05 11.46 5.17 967.95
17:06 11.32 5.24 974.77
17:07 11.59 5.11 905.61
17:08 11.70 5.03 895.18
17:09 11.68 5.06 922.41
17:10 11.66 5.06 900.36
17:11 11.50 5.18 933.55
17:12 11.49 5.15 924.28
17:13 11.38 5.23 967.09
17:14 11.62 5.10 891.01
17:15 11.81 4.97 880.82
17:16 11.65 5.10 944.12
17:17 11.87 4.93 848.64
17:18 11.56 5.14 979.22
17:19 11.60 5.13 921.61
17:20 11.43 5.19 929.66
17:21 11.52 5.15 902.46
17:22 11.50 5.16 911.22
17:23 11.61 5.08 922.28
17:24 11.65 5.09 954.75
17:25 11.69 5.05 937.89
17:26 11.54 5.13 970.21
17:27 11.48 5.17 978.80
17:28 11.46 5.19 982.76
17:29 11.50 5.19 993.22
17:30 11.42 5.21 980.21
17:31 11.60 5.12 960.45
17:32 11.59 5.12 978.78
17:33 11.82 4.97 899.70
17:34 11.71 5.07 987.66
17:35 11.79 5.01 931.59
17:36 11.62 5.08 1,008.76
17:37 11.37 5.25 1,058.63
17:38 11.52 5.16 989.34
17:39 11.51 5.15 1,001.36
17:40 11.59 5.09 971.21
17:41 11.66 5.06 947.73
17:42 11.63 5.07 957.78
17:43 11.57 5.13 978.78
17:44 11.37 5.21 1,013.95
17:45 11.39 5.22 1,016.08
17:46 11.46 5.19 989.39
17:47 11.58 5.12 985.22
17:48 11.59 5.10 980.36
17:49 11.64 5.10 976.26
17:50 11.69 5.06 956.84
17:51 11.67 5.06 990.00
17:52 11.46 5.10 1,040.55
17:53 11.60 5.16 971.81
17:54 11.50 5.27 1,022.67
17:55 11.45 5.31 1,065.14
17:56 11.62 5.20 989.80
17:57 11.85 5.05 937.51
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 10
AST-2024-2320
6/12/24
36 of 161
Run 3 - RM Data
Location:
Source:
Project No.:
Date:
Time O₂ - Outlet CO₂ - Outlet THC - Outlet
Unit % dry % dry ppmvw
Status Valid Valid Valid
Uncorrected Run Average (Cobs)10.60 4.73 1511.29
Cal Gas Concentration (CMA)12.00 5.00 1000.00
Pretest System Zero Response 0.00 0.00 0.00
Posttest System Zero Response 0.00 0.00 0.00
Average Zero Response (Co)0.00 0.00 0.00
Pretest System Cal Response 12.00 4.93 1002.09
Posttest System Cal Response 11.94 4.91 993.64
Average Cal Response (CM)11.97 4.92 997.87
Corrected Run Average (Corr)10.63 4.81 NA
18:30 10.65 4.67 1,435.94
18:31 10.61 4.69 1,512.97
18:32 10.69 4.67 1,556.06
18:33 10.57 4.72 1,567.75
18:34 10.48 4.79 1,436.57
18:35 10.84 4.56 1,390.94
18:36 10.53 4.78 1,353.54
18:37 10.59 4.74 1,380.46
18:38 10.58 4.72 1,490.39
18:39 10.52 4.79 1,323.58
18:40 10.86 4.56 1,270.41
18:41 10.46 4.84 1,344.19
18:42 10.57 4.75 1,409.32
18:43 10.59 4.74 1,359.50
18:44 10.75 4.63 1,268.84
18:45 10.57 4.74 1,446.51
18:46 10.49 4.78 1,570.75
18:47 10.37 4.86 1,519.63
18:48 10.63 4.69 1,520.87
18:49 10.57 4.73 1,579.89
18:50 10.61 4.71 1,618.37
18:51 10.64 4.70 1,655.34
18:52 10.43 4.85 1,503.10
18:53 10.69 4.68 1,436.20
18:54 10.63 4.71 1,358.18
18:55 10.80 4.61 1,330.31
18:56 10.62 4.73 1,538.54
18:57 10.58 4.74 1,585.35
18:58 10.72 4.65 1,624.64
18:59 10.51 4.79 1,703.16
19:00 10.41 4.85 1,599.29
19:01 10.53 4.79 1,422.06
19:02 10.89 4.55 1,450.93
19:03 10.51 4.82 1,451.86
19:04 10.39 4.88 1,402.58
19:05 10.56 4.76 1,474.89
19:06 10.52 4.78 1,540.04
19:07 10.58 4.77 1,481.31
19:08 10.55 4.78 1,546.42
19:09 10.54 4.76 1,666.94
19:10 10.69 4.67 1,685.25
19:11 10.52 4.78 1,703.18
19:12 10.49 4.82 1,516.83
19:13 10.78 4.62 1,500.34
19:14 10.78 4.62 1,525.14
19:15 10.51 4.83 1,507.03
19:16 10.80 4.59 1,463.71
19:17 10.67 4.69 1,646.68
19:18 10.61 4.73 1,705.55
19:19 10.48 4.81 1,660.43
19:20 10.61 4.72 1,608.10
19:21 10.74 4.65 1,512.51
19:22 10.53 4.81 1,420.43
19:23 10.61 4.74 1,555.78
19:24 10.54 4.77 1,646.91
19:25 10.41 4.88 1,606.18
19:26 10.68 4.70 1,489.14
19:27 10.71 4.68 1,485.80
19:28 10.60 4.74 1,601.52
19:29 10.56 4.77 1,709.48
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 10
AST-2024-2320
6/12/24
37 of 161

Appendix C

38 of 161
Project No.AST-2024-2320
Analytical Laboratory Report
www.alliancetg.com
Alliance Technical Group, LLC
Analytical Servives
5530 Marshall St.
Arvada, CO 80002
[phone]
Pepperidge Farm
901 North 200 West
Richmond, UT 84333
1 of 93
39 of 161
James Davidson Date
Quality Assurance Associate
Certification Statement
Alliance Source Testing, LLC (AST) has completed the analysis as described in this report.
Results apply only to the source(s) tested and operating condition(s) for the specific test
date(s) and time(s) identified within this report. All results are intended to be considered in
their entirety, and AST is not responsible for use of less than the complete test report without
written consent. This report shall not be reproduced in full or in part without written approval
from the customer.
To the best of my knowledge and abilities, all information, facts and test data are correct.
Data presented in this report has been checked for completeness and is accurate, error-free
and legible. Any deviations or problems are detailed in the relevant sections on the test
report.
This document was prepared in portable document format (.pdf) and contains pages as
identified in the bottom footer of this document.
Validation Signature
The analytical data and all QC contained within this report was reviewed and validated by
the following individual.
2 of 93
Digitally signed by James Davidson
DN: C=US, CN=James Davidson, E=[e-mail]
Reason: I attest to the accuracy and integrity of this document
Location: your signing location here
Date: 2024.06.28 13:05:21-05'00'
Foxit PDF Editor Version: 11.2.10
James Davidson
40 of 161
Project Narrative
Analytical Method:Method 18—Measurement of Gaseous Organic Compound Emissions by Gas
Chromatography
Calibration:Three certified calibration standards containing each analyte of interest were
analyzed, each in triplicate agreement of 5% of their mean, to produce a regression
line of concentration versus area count.
Sample Analysis:The retention times of the analytes in the calibration standards were used to identify
peaks in the sample chromatograms. The area counts of the peaks in the sample
chromatograms were multiplied by the slope of the appropriate calibration line to
determine the concentration of target analytes in the samples.
MDL:The Minimum Detection Level (MDL) is 0.02 (C1) and 0.05 (C2) ppm per fraction. If the
measured result for a fraction is less than the MDL, the MDL was used in ensuing
calculations.
Custody:The samples were received by Carson Williamson on 6/17/2024 in Arvada, CO. The
samples were received in good condition with proper Chain-of-Custody
documentation. No apparent container problems were noted upon receipt. Prior to
analysis, the samples were kept secure with access limited to authorized personnel of
AST.
Number of Samples:12
Labeling: Acceptable
Analyst:Carson Williamson-Laboratory Analyst I
Equipment:Agilent 8890 GC-FID System S/N: US2131A004; Column: Restek MXT-1 S/N:1646930
QC Notes:The samples met the minimum criteria established by the relevant method.
Reporting Notes:M18-Line No.3 Stack-Run 1 was received nearly flat.
3 of 93
41 of 161
Location
Source
Project No.
Method
Analyst
Analysis Date
Instrument
Analyte
Lower Curve Limit ppm
Upper Curve Limit ppm J - Estimated Value, Value less than the lowest standard
Limit of Detection ppm E - Estimated Value, Value greater than the highest standard
Lab ID Field ID Ret. Time #1
(min.)
Ret. Time #2
(min.)
Ret. Time #3
(min.)%RD Dilution
Factor Recovery Eff.Measured
Conc. (ppm)
D44949 M18-Line No.3 Primary-Run 1 4.72 4.72 4.72 2,680 2,677 2,678 2,678 0.07 1 1.00 2678 2,680
D44950 M18-Line No.3 Primary-Run 2 4.72 4.72 4.72 2,360 2,363 2,359 2,360 0.10 1 1.00 2360 2,362
D44951 M18-Line No.3 Primary-Run 3 4.72 4.72 4.72 2,290 2,288 2,289 2,289 0.07 1 1.00 2289 2,291
D44955 M18-Line No.10 Primary-Run 1 4.72 4.72 4.72 3,811 3,812 3,816 3,813 0.08 1 1.00 3813 3,795
D44956 M18-Line No.10 Primary-Run 2 4.72 4.72 4.72 4,337 4,334 4,339 4,337 0.07 1 1.00 4337 4,316
D44957 M18-Line No.10 Primary-Run 3 x2 dilution 4.72 4.72 4.72 3,321 3,316 3,317 3,318 0.09 2 1.00 6636 6,604
D44952 M18-Line No.3 Stack-Run 1 4.72 4.72 4.72 703 696 689 696 0.99 1 0.99 696 703
D44953 M18-Line No.3 Stack-Run 2 4.72 4.72 4.72 2,826 2,825 2,827 2,826 0.03 1 0.99 2826 2,853
D44954 M18-Line No.3 Stack-Run 3 4.72 4.72 4.72 2,313 2,312 2,312 2,312 0.03 1 0.99 2312 2,334
D44958 M18-Line No.10 Stack-Run 1 4.72 4.72 4.72 3,656 3,655 3,654 3,655 0.03 1 1.00 3655 3,639
D44959 M18-Line No.10 Stack-Run 2 4.72 4.72 4.72 4,342 4,346 4,353 4,347 0.14 1 1.00 4347 4,328
D44960 M18-Line No.10 Stack-Run 3 4.72 4.72 4.72 4,108 4,112 4,122 4,114 0.19 1 1.00 4114 4,096
Carson Williamson-Laboratory Analyst I
0.02
4799
0.422
Methane
Agilent 8890 GC-FID System S/N: US2131A004; Column: Restek MXT-1 S/N:1646930
Sample #3
(ppm)
Sample #2
(ppm)
Sample #1
(ppm)
Average
(ppm)
Adjusted Conc.
(ppm)
ND - Non Detect
Pepperidge Farm
Line No.3 Primary, Line No.3 Stack, Line No.10 Primary, Line No.10 Stack
AST-2024-2320
EPA Method 18: Determination of Gaseous Organic Compounds using Gas Chromatography
6/17/2024, 6/18/2024
4 of 93
42

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16
1
Location
Source
Project No.
Method
Analyst
Analysis Date
Instrument
Analyte
Lower Curve Limit ppm
Upper Curve Limit ppm J - Estimated Value, Value less than the lowest standard
Limit of Detection ppm E - Estimated Value, Value greater than the highest standard
Lab ID Field ID Ret. Time #1
(min.)
Ret. Time #2
(min.)
Ret. Time #3
(min.)%RD Dilution
Factor Recovery Eff.Measured
Conc. (ppm)
D44949 M18-Line No.3 Primary-Run 1 4.96 4.96 4.96 83.6 81.6 83.0 82.7 1.40 1 1.00 83 82.9
D44950 M18-Line No.3 Primary-Run 2 4.96 4.96 4.96 71.3 71.6 71.2 71.3 0.30 1 1.00 71.3 71.5
D44951 M18-Line No.3 Primary-Run 3 4.96 4.96 4.96 68.0 68.1 68.0 68.0 0.05 1 1.00 68.0 68.2
D44955 M18-Line No.10 Primary-Run 1 4.96 4.96 4.96 116 116 116 116 0.16 1 0.98 116 118
D44956 M18-Line No.10 Primary-Run 2 4.96 4.96 4.96 136 136 137 136 0.09 1 0.98 136 139
D44957 M18-Line No.10 Primary-Run 3 x2 dilution 4.96 4.96 4.96 97.7 97.5 97.4 97.6 0.15 2 0.98 195 199
D44952 M18-Line No.3 Stack-Run 1 4.96 4.96 4.96 34.6 34.4 34.1 34.4 0.76 1 0.98 34.4 35.1
D44953 M18-Line No.3 Stack-Run 2 4.96 4.96 4.96 87.6 87.6 87.5 87.6 0.11 1 0.98 87.6 89.5
D44954 M18-Line No.3 Stack-Run 3 4.96 4.96 4.96 69.1 69.1 69.1 69.1 0.04 1 0.98 69.1 70.7
D44958 M18-Line No.10 Stack-Run 1 4.96 4.96 4.96 117 117 117 117 0.10 1 0.97 117 120
D44959 M18-Line No.10 Stack-Run 2 4.96 4.96 4.96 137 137 137 137 0.20 1 0.97 137 141
D44960 M18-Line No.10 Stack-Run 3 4.96 4.96 4.96 132 132 133 132 0.24 1 0.97 132 136
0.503
Ethane
Agilent 8890 GC-FID System S/N: US2131A004; Column: Restek MXT-1 S/N:1646930
6/17/2024, 6/18/2024
Carson Williamson-Laboratory Analyst I
Pepperidge Farm
Line No.3 Primary, Line No.3 Stack, Line No.10 Primary, Line No.10 Stack
AST-2024-2320
EPA Method 18: Determination of Gaseous Organic Compounds using Gas Chromatography
Adjusted Conc.
(ppm)
ND - Non Detect
Sample #1
(ppm)
Sample #2
(ppm)
Sample #3
(ppm)
Average
(ppm)
0.05
4813
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43

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16
1
Location
Source
Project No.
Method
Cpd Inj. 1 Inj. 2 Inj. 3
ID RT AC ppm RT AC ppm RT AC ppm RT AC ppm
Methane 4.72 1883 2680 4.72 1880 2677 4.72 1881 2678 4.72 1881 2678
Ethane 4.96 107 83.6 4.96 104 81.6 4.96 106 83.0 4.96 106 82.7
Cpd Inj. 1 Inj. 2 Inj. 3
ID RT AC ppm RT AC ppm RT AC ppm RT AC ppm
Methane 4.72 1657 2360 4.72 1660 2363 4.72 1657 2359 4.72 1658 2360
Ethane 4.96 91.0 71.3 4.96 91.3 71.6 4.96 90.8 71.2 4.96 91.0 71.3
Cpd Inj. 1 Inj. 2 Inj. 3
ID RT AC ppm RT AC ppm RT AC ppm RT AC ppm
Methane 4.72 1609 2290 4.72 1607 2288 4.72 1608 2289 4.72 1608 2289
Ethane 4.96 86.8 68.0 4.96 86.9 68.1 4.96 86.8 68.0 4.96 86.8 68.0
Cpd Inj. 1 Inj. 2 Inj. 3
ID RT AC ppm RT AC ppm RT AC ppm RT AC ppm
Methane 4.72 2677 3811 4.72 2678 3812 4.72 2681 3816 4.72 2678 3813
Ethane 4.96 148 116 4.96 148 116 4.96 148 116 4.96 148 116
Cpd Inj. 1 Inj. 2 Inj. 3
ID RT AC ppm RT AC ppm RT AC ppm RT AC ppm
Methane 4.72 3047 4337 4.72 3044 4334 4.72 3048 4339 4.72 3046 4337
Ethane 4.96 174 136 4.96 174 136 4.96 174 137 4.96 174 136
Cpd Inj. 1 Inj. 2 Inj. 3
ID RT AC ppm RT AC ppm RT AC ppm RT AC ppm
Methane 4.72 2333 3321 4.72 2329 3316 4.72 2330 3317 4.72 2331 3318
Ethane 4.96 125 98 4.96 124 98 4.96 124 97 4.96 124 98
Cpd Inj. 1 Inj. 2 Inj. 3
ID RT AC ppm RT AC ppm RT AC ppm RT AC ppm
Methane 4.72 494 703 4.72 489 696 4.72 484 689 4.72 489 696
Ethane 4.96 44.1 34.6 4.96 43.9 34.4 4.96 43.5 34.1 4.96 43.8 34.4
Cpd Inj. 1 Inj. 2 Inj. 3
ID RT AC ppm RT AC ppm RT AC ppm RT AC ppm
Methane 4.72 1985 2826 4.72 1985 2825 4.72 1986 2827 4.72 1985 2826
Ethane 4.96 112 87.6 4.96 112 87.6 4.96 112 87.5 4.96 112 87.6
Cpd Inj. 1 Inj. 2 Inj. 3
ID RT AC ppm RT AC ppm RT AC ppm RT AC ppm
Methane 4.72 1625 2313 4.72 1624 2312 4.72 1624 2312 4.72 1624 2312
Ethane 4.96 88.2 69.1 4.96 88.1 69.1 4.96 88.2 69.1 4.96 88.2 69.1
Cpd Inj. 1 Inj. 2 Inj. 3
ID RT AC ppm RT AC ppm RT AC ppm RT AC ppm
Methane 4.72 2568 3656 4.72 2568 3655 4.72 2567 3654 4.72 2567 3655
Ethane 4.96 149 117 4.96 149 117 4.96 149 117 4.96 149 117
Cpd Inj. 1 Inj. 2 Inj. 3
ID RT AC ppm RT AC ppm RT AC ppm RT AC ppm
Methane 4.72 3050 4342 4.72 3053 4346 4.72 3058 4353 4.72 3053 4347
Ethane 4.96 175 137 4.96 175 137 4.96 175 137 4.96 175 137
Cpd Inj. 1 Inj. 2 Inj. 3
ID RT AC ppm RT AC ppm RT AC ppm RT AC ppm
Methane 4.72 2886 4108 4.72 2889 4112 4.72 2895 4122 4.72 2890 4114
Ethane 4.96 168 132 4.96 169 132 4.96 169 133 4.96 169 132
EPA Method 18: Determination of Gaseous Organic Compounds using Gas Chromatography
Pepperidge Farm
AST-2024-2320
Line No.3 Primary, Line No.3 Stack, Line No.10 Primary, Line No.10 Stack
Average
Average
M18-Line No.10 Stack-Run 3
M18-Line No.10 Stack-Run 2
Average
Average
M18-Line No.10 Primary-Run 3 x2 dilution
M18-Line No.3 Stack-Run 1
M18-Line No.3 Stack-Run 2
Average
Average
Average
M18-Line No.3 Stack-Run 3
M18-Line No.10 Stack-Run 1
Average
Average
Average
M18-Line No.10 Primary-Run 1
M18-Line No.10 Primary-Run 2
M18-Line No.3 Primary-Run 3
Average
Average
Sample Analysis
M18-Line No.3 Primary-Run 1
M18-Line No.3 Primary-Run 2
6 of 93
44 of 161
Location
Source
Project No.
Method
Cpd Conc.
ID (ppm)RT AC RT AC RT AC RT AC OK?
Methane 4799 4.72 3397 4.72 3368 4.72 3387 4.72 3384 Y
Ethane 4813 4.96 6189 4.96 6135 4.96 6171 4.96 6165 Y
Cpd Conc.
ID (ppm)RT AC RT AC RT AC RT AC OK?
Methane 2010 4.72 1387 4.72 1381 4.72 1372 4.72 1380 Y
Ethane 2008 4.96 2517 4.96 2507 4.96 2491 4.96 2505 Y
Cpd Conc.
ID (ppm)RT AC RT AC RT AC RT AC OK?
Methane 0.422 4.72 0.300 4.72 0.300 4.72 0.294 4.72 0.298 Y
Ethane 0.503 4.96 0.643 4.96 0.640 4.96 0.642 4.96 0.642 Y
Inj. 1 Inj. 2 Inj. 3
Low-Level Calibration Standard
Inj. 1 Inj. 2 Inj. 3
Average
Average
Line No.3 Primary, Line No.3 Stack, Line No.10 Primary, Line No.10 Stack
Pepperidge Farm
Initial Three-Point Calibration
High Level Calibration Standard
Mid-Level Calibration Standard
EPA Method 18: Determination of Gaseous Organic Compounds using Gas Chromatography
AST-2024-2320
Inj. 3Inj. 2Inj. 1 Average
7 of 93
45 of 161
Location
Source
Project No.
Method
Certified Average ppm from Certified Average ppm from
ppm AC curve ppm AC curve
4799 3384 R2 M 4818 4813 6165 R2 M 4831
2010 1380 1965 2008 2505 1963
0.422 0.298 0.424 0.503 0.642 0.5030.7841.0001.4241.000
Linear Regression Calculations
Statistics Statistics
EPA Method 18: Determination of Gaseous Organic Compounds using Gas Chromatography
AST-2024-2320
Line No.3 Primary, Line No.3 Stack, Line No.10 Primary, Line No.10 Stack
Pepperidge Farm
Linear Regression Linear Regression
Methane Ethane
0
1000
2000
3000
4000
5000
6000
0 1000 2000 3000 4000 5000 6000 7000
pp
m
Area Counts
Methane
Ethane
Linear (Methane)
Linear (Ethane)
8 of 93
46 of 161
Location
Source
Project No.
Method
Analysis Date
Cpd Conc.
ID (ppm)RT AC RT AC RT AC RT AC ppm
Methane 0.000 n/a 0.000 n/a 0.000 0.000
Ethane 0.000 n/a 0.000 n/a 0.000 0.000
Cpd Conc.
ID (ppm)RT AC RT AC RT AC RT AC ppm
Methane 2010 4.72 1310 4.72 1310 4.72 1310 4.72 1310 1865
Ethane 2008 4.96 2370 4.96 2371 4.96 2370 4.96 2370 1857
Cpd Conc.
ID (ppm)RT AC RT AC RT AC RT AC ppm
Methane 2010 4.72 1341 4.72 1340 4.72 1341 4.72 1341 1909
Ethane 2008 4.96 2430 4.96 2430 4.96 2432 4.96 2431 1905
Initial CCV
Nitrogen Blank
Pepperidge Farm
Line No.3 Primary, Line No.3 Stack, Line No.10 Primary, Line No.10 Stack
AST-2024-2320
EPA Method 18: Determination of Gaseous Organic Compounds using Gas Chromatography
Inj. 1 Inj. 2
6/17/2024
Average
Average
Inj. 3
Inj. 1 Inj. 2 Inj. 3
Inj. 1 Inj. 2 Inj. 3 Average
Post CCV
9 of 93
47 of 161
Location
Source
Project No.
Method
Analysis Date
Cpd Conc.
ID (ppm)RT AC RT AC RT AC RT AC ppm
Methane 2093 4.72 1469 4.72 1468 4.72 1470 4.72 1469 2091
Ethane 66.1 4.96 84.1 4.96 84.1 4.96 84.0 4.96 84.1 65.9
Cpd Conc.
ID (ppm)RT AC RT AC RT AC RT AC ppm
Methane 0.00 n/a 0 n/a 0.000 0.000
Ethane 0.00 n/a 0 n/a 0.000 0.000
Cpd Conc.
ID (ppm)RT AC RT AC RT AC RT AC ppm
Methane 2010 4.72 1369 4.72 1367 4.72 1366 4.72 1367 1946
Ethane 2008 4.96 2487 4.96 2485 4.96 2483 4.96 2485 1947
Cpd Conc.
ID (ppm)RT AC RT AC RT AC RT AC ppm
Methane 2010 4.72 1373 4.72 1373 4.72 1374 4.72 1373 1955
Ethane 2008 4.96 2495 4.96 2497 4.96 2498 4.96 2497 1956
Cpd Conc.
ID (ppm)RT AC RT AC RT AC RT AC ppm
Methane 2167 4.72 1508 4.72 1507 4.72 1508 4.72 1508 2147
Ethane 68.5 4.96 85.5 4.96 85.2 4.96 85.7 4.96 85.5 67.0
Cpd Conc.
ID (ppm)RT AC RT AC RT AC RT AC ppm
Methane 3173 4.72 2239 4.72 2240 4.72 2241 4.72 2240 3189
Ethane 105 4.96 132 4.96 132 4.96 132 4.96 132 104
Cpd Conc.
ID (ppm)RT AC RT AC RT AC RT AC ppm
Methane 3178 4.72 2243 4.72 2239 4.72 2244 4.72 2242 3192
Ethane 106 4.96 132 4.96 132 4.96 131 4.96 132 103
Post CCV
1L-M18-Line No.3 Stack-Run 2 : 1L-1500 ppm C1; 50 ppm C2 Cal Standard
Inj. 1 Inj. 2 Inj. 3 Average
Initial CCV
Inj. 1 Inj. 2 Inj. 3 Average
Inj. 1 Inj. 2 Inj. 3 Average
Pepperidge Farm
Line No.3 Primary, Line No.3 Stack, Line No.10 Primary, Line No.10 Stack
AST-2024-2320
EPA Method 18: Determination of Gaseous Organic Compounds using Gas Chromatography
Quality Assurance
1L-M18-Line No.3 Primary-Run 1 : 1L-1500 ppm C1; 50 ppm C2 Cal Standard
Inj. 1 Inj. 2 Inj. 3 Average
Nitrogen Blank
6/18/2024
Inj. 1 Inj. 2 Inj. 3 Average
1L-M18-Line No.10 Primary-Run 2: 1L-2010 ppm C1; 75 ppm C2 Cal Standard
Inj. 1 Inj. 2 Inj. 3 Average
1L-M18-Line No.10 Stack-Run 2: 1L-2010 ppm C1; 75 ppm C2 Cal Standard
Inj. 1 Inj. 2 Inj. 3 Average
10 of 93
48 of 161
Location
Source
Project No.
Method
Analyst
Instrument
Cylinder ID:
Cert. Concentration:Spike Prepared (Date/Time):6/18/2024 9:00
Cylinder Expiration:Spiked Sample Run Time (Date/Time):6/18/2024 16:12
Analyte: METHANE
Avg. Sample Conc.
(ppm)
Sample Volume
added to Recovery
Spike (l)
Conc. of spike
standard
(ppm)
2678 1.0 1508
Recovery Spike Result
(ppm)
Percent Recovery
(%)
Recovery
Efficiency
2091 100%1.00
Cylinder ID:
Cert. Concentration:Spike Prepared (Date/Time):6/18/2024 9:05
Cylinder Expiration:Spiked Sample Run Time (Date/Time):6/18/2024 17:13
Analyte: ETHANE
Avg. Sample Conc.
(ppm)
Sample Volume
added to Recovery
Spike (l)
Conc. of spike
standard
(ppm)
82.7 1.0 49.4
Recovery Spike Result
(ppm)
Percent Recovery
(%)
Recovery
Efficiency
65.9 100%1.00
Cylinder ID:
Cert. Concentration:Spike Prepared (Date/Time):6/18/2024 9:10
Cylinder Expiration:Spiked Sample Run Time (Date/Time):6/18/2024 18:13
Analyte:METHANE
Avg. Sample Conc.
(ppm)
Sample Volume
added to Recovery
Spike (l)
Conc. of spike
standard
(ppm)
2826 1.0 1508
Recovery Spike Result
(ppm)
Percent Recovery
(%)
Recovery
Efficiency
2147 99%0.99
Cylinder ID:
Cert. Concentration:Spike Prepared (Date/Time):6/18/2024 9:15
Cylinder Expiration:Spiked Sample Run Time (Date/Time):6/18/2024 19:13
Analyte:ETHANE
Avg. Sample Conc.
(ppm)
Sample Volume
added to Recovery
Spike (l)
Conc. of spike
standard
(ppm)
87.6 1.0 49.4
Recovery Spike Result
(ppm)
Percent Recovery
(%)
Recovery
Efficiency
67.0 98%0.98
1L-M18-Line No.3 Stack-Run 2 : 1L- 50
ppm C2 Cal Standard M18-Line No.3 Stack-Run 2
Sample Volume of spike
standards added to Recovery
Spike (l)
Theoretical Conc. of
Recovery Spike (ppm)
1.0 68.5
ALM035146
49.43 ppm
9/27/2026
Recovery Spike ID Sample ID
1L-M18-Line No.3 Stack-Run 2 : 1L-
1500 ppm C1 Cal Standard M18-Line No.3 Stack-Run 2
Sample Volume of spike
standards added to Recovery
Theoretical Conc. of
Recovery Spike (ppm)
1.0 2167
S990494A
2010 ppm
5/31/2031
Recovery Spike ID Sample ID
AST-2024-2320
Line No.3 Primary, Line No.3 Stack, Line No.10 Primary, Line No.10 Stack
Pepperidge Farm
S990494A
Carson Williamson-Laboratory Analyst I
Agilent 8890 GC-FID System S/N: US2131A004; Column: Restek MXT-1 S/N:1646930
EPA Method 18: Spike Recovery
9/27/2026
Recovery Spike ID Sample ID
2010 ppm
5/31/2031
Recovery Spike ID Sample ID
1L-M18-Line No.3 Primary-Run 1 : 1L-
1500 ppm C1 Cal Standard M18-Line No.3 Primary-Run 1
Sample Volume of spike
standards added to Recovery
Spike (l)
Theoretical Conc. of
Recovery Spike (ppm)
1.0 2093
ALM035146
49.43 ppm
Sample Volume of spike
standards added to Recovery
Spike (l)
Theoretical Conc. of
Recovery Spike (ppm)
1.0 66.1
1L-M18-Line No.3 Primary-Run 1 : 1L-50
ppm C2 Cal Standard M18-Line No.3 Primary-Run 1
11 of 93
49 of 161
Location
Source
Project No.
Method
Analyst
Instrument
Cylinder ID:
Cert. Concentration:Spike Prepared (Date/Time):6/18/2024 9:20
Cylinder Expiration:Spiked Sample Run Time (Date/Time):6/18/2024 20:13
Analyte:METHANE
Avg. Sample Conc.
(ppm)
Sample Volume
added to Recovery
Spike (l)
Conc. of spike
standard
(ppm)
4337 1.0 2010
Recovery Spike Result
(ppm)
Percent Recovery
(%)
Recovery
Efficiency
3189 100%1.00
Cylinder ID:
Cert. Concentration:Spike Prepared (Date/Time):6/18/2024 9:25
Cylinder Expiration:Spiked Sample Run Time (Date/Time):6/18/2024 21:13
Analyte:ETHANE
Avg. Sample Conc.
(ppm)
Sample Volume
added to Recovery
Spike (l)
Conc. of spike
standard
(ppm)
136 1.0 74.6
Recovery Spike Result
(ppm)
Percent Recovery
(%)
Recovery
Efficiency
104 98%0.98
Cylinder ID:
Cert. Concentration:Spike Prepared (Date/Time):6/18/2024 3:30
Cylinder Expiration:Spiked Sample Run Time (Date/Time):6/18/2024 22:13
Analyte:METHANE
Avg. Sample Conc.
(ppm)
Sample Volume
added to Recovery
Spike (l)
Conc. of spike
standard
(ppm)
4347 1.0 2010
Recovery Spike Result
(ppm)
Percent Recovery
(%)
Recovery
Efficiency
3192 100%1.00
Cylinder ID:
Cert. Concentration:Spike Prepared (Date/Time):6/18/2024 3:30
Cylinder Expiration:Spiked Sample Run Time (Date/Time):6/18/2024 11:13
Analyte:ETHANE
Avg. Sample Conc.
(ppm)
Sample Volume
added to Recovery
Spike (l)
Conc. of spike
standard
(ppm)
137 1.0 74.6
Recovery Spike Result
(ppm)
Percent Recovery
(%)
Recovery
Efficiency
103 97%0.97
Agilent 8890 GC-FID System S/N: US2131A004; Column: Restek MXT-1 S/N:1646930
Pepperidge Farm
Line No.3 Primary, Line No.3 Stack, Line No.10 Primary, Line No.10 Stack
AST-2024-2320
EPA Method 18: Spike Recovery
Carson Williamson-Laboratory Analyst I
1L-M18-Line No.10 Stack-Run 2: 1L-75
ppm C2 Cal Standard M18-Line No.10 Stack-Run 2
Sample Volume of spike
standards added to Recovery
Spike (l)
Theoretical Conc. of
Recovery Spike (ppm)
1.0 106
EB0123059
99.45 ppm
10/11/2026
Recovery Spike ID Sample ID
1L-M18-Line No.10 Stack-Run 2: 1L-
2010 ppm C1 Cal Standard M18-Line No.10 Stack-Run 2
Sample Volume of spike
standards added to Recovery
Spike (l)
Theoretical Conc. of
Recovery Spike (ppm)
1.0 3178
S990494A
2010 ppm
5/31/2031
Recovery Spike ID Sample ID
1L-M18-Line No.10 Primary-Run 2: 1L-
75 ppm C2 Cal Standard M18-Line No.10 Primary-Run 2
Sample Volume of spike
standards added to Recovery
Spike (l)
Theoretical Conc. of
Recovery Spike (ppm)
1.0 105
EB0123059
99.45 ppm
10/11/2026
Recovery Spike ID Sample ID
1L-M18-Line No.10 Primary-Run 2: 1L-
2010 ppm C1 Cal Standard M18-Line No.10 Primary-Run 2
Sample Volume of spike
standards added to Recovery
Theoretical Conc. of
Recovery Spike (ppm)
1.0 3173
S990494A
2010 ppm
5/31/2031
Recovery Spike ID Sample ID
12 of 93
50 of 161
13 of 93
51 of 161
=====================================================================
Acq. Operator : SYSTEM Seq. Line : 30
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 7 (F)
Injection Date : 6/17/2024 5:24:33 PM Inj : 1
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
FID1 A, Front Signal (AST-2024-2...2330 061724 2024-06-17 13-01-42\F-030-7-M18-Line No.3 Primary-Run 1.D)
4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.721 MF 1882.61243 1.41692 2667.50255 Methane
4.957 MF 106.67425 7.79958e-1 83.20138 Ethane
Totals : 2750.70394
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...30 061724 2024-06-17 13-01-42\F-030-7-M18-Line No.3 Primary-Run 1.D
Sample Name: M18-Line No.3 Primary-Run 1
W8250 AST 6/19/2024 9:09:54 AM SYSTEM Page 1 of 2
14 of 93
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Acq. Operator : SYSTEM Seq. Line : 31
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 7 (F)
Injection Date : 6/17/2024 5:39:51 PM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
FID1 A, Front Signal (AST-2024-2...2330 061724 2024-06-17 13-01-42\F-031-7-M18-Line No.3 Primary-Run 1.D)
4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.721 MF 1880.44971 1.41692 2664.43829 Methane
4.957 FM 104.07088 7.79939e-1 81.16891 Ethane
Totals : 2745.60720
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...30 061724 2024-06-17 13-01-42\F-031-7-M18-Line No.3 Primary-Run 1.D
Sample Name: M18-Line No.3 Primary-Run 1
W8250 AST 6/19/2024 9:10:44 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 32
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 7 (F)
Injection Date : 6/17/2024 5:55:13 PM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
FID1 A, Front Signal (AST-2024-2...2330 061724 2024-06-17 13-01-42\F-032-7-M18-Line No.3 Primary-Run 1.D)
4.
7
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1

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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.721 MF 1880.87903 1.41692 2665.04658 Methane
4.957 MF 105.88948 7.79952e-1 82.58871 Ethane
Totals : 2747.63529
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...30 061724 2024-06-17 13-01-42\F-032-7-M18-Line No.3 Primary-Run 1.D
Sample Name: M18-Line No.3 Primary-Run 1
W8250 AST 6/19/2024 9:40:18 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 34
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 8 (F)
Injection Date : 6/17/2024 6:25:57 PM Inj : 1
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
FID1 A, Front Signal (AST-2024-2...2330 061724 2024-06-17 13-01-42\F-034-8-M18-Line No.3 Primary-Run 2.D)
4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.721 MF 1657.47595 1.41692 2348.51672 Methane
4.957 MF 90.98076 7.79828e-1 70.94932 Ethane
Totals : 2419.46603
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...30 061724 2024-06-17 13-01-42\F-034-8-M18-Line No.3 Primary-Run 2.D
Sample Name: M18-Line No.3 Primary-Run 2
W8250 AST 6/19/2024 9:40:39 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 35
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 8 (F)
Injection Date : 6/17/2024 6:41:17 PM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
FID1 A, Front Signal (AST-2024-2...2330 061724 2024-06-17 13-01-42\F-035-8-M18-Line No.3 Primary-Run 2.D)
4.
7
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.721 MF 1659.64343 1.41692 2351.58772 Methane
4.957 MF 91.31939 7.79831e-1 71.21369 Ethane
Totals : 2422.80141
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...30 061724 2024-06-17 13-01-42\F-035-8-M18-Line No.3 Primary-Run 2.D
Sample Name: M18-Line No.3 Primary-Run 2
W8250 AST 6/19/2024 9:41:35 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 36
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 8 (F)
Injection Date : 6/17/2024 6:56:39 PM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
FID1 A, Front Signal (AST-2024-2...2330 061724 2024-06-17 13-01-42\F-036-8-M18-Line No.3 Primary-Run 2.D)
4.
7
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1

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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.721 MF 1656.74939 1.41692 2347.48728 Methane
4.957 MF 90.82964 7.79826e-1 70.83133 Ethane
Totals : 2418.31862
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...30 061724 2024-06-17 13-01-42\F-036-8-M18-Line No.3 Primary-Run 2.D
Sample Name: M18-Line No.3 Primary-Run 2
W8250 AST 6/19/2024 9:42:02 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 38
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 9 (F)
Injection Date : 6/17/2024 7:27:21 PM Inj : 1
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
FID1 A, Front Signal (AST-2024-2...2330 061724 2024-06-17 13-01-42\F-038-9-M18-Line No.3 Primary-Run 3.D)
4.
7
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.721 MF 1608.87854 1.41693 2279.66121 Methane
4.957 MF 86.79668 7.79785e-1 67.68276 Ethane
Totals : 2347.34397
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...30 061724 2024-06-17 13-01-42\F-038-9-M18-Line No.3 Primary-Run 3.D
Sample Name: M18-Line No.3 Primary-Run 3
W8250 AST 6/19/2024 9:42:23 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 39
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 9 (F)
Injection Date : 6/17/2024 7:42:41 PM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
FID1 A, Front Signal (AST-2024-2...2330 061724 2024-06-17 13-01-42\F-039-9-M18-Line No.3 Primary-Run 3.D)
4.
7
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1

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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.721 MF 1606.93921 1.41693 2276.91346 Methane
4.957 MF 86.86655 7.79786e-1 67.73732 Ethane
Totals : 2344.65077
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...30 061724 2024-06-17 13-01-42\F-039-9-M18-Line No.3 Primary-Run 3.D
Sample Name: M18-Line No.3 Primary-Run 3
W8250 AST 6/19/2024 9:45:05 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 40
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 9 (F)
Injection Date : 6/17/2024 7:58:00 PM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
FID1 A, Front Signal (AST-2024-2...2330 061724 2024-06-17 13-01-42\F-040-9-M18-Line No.3 Primary-Run 3.D)
4.
7
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.721 MF 1607.59399 1.41693 2277.84119 Methane
4.957 MF 86.81474 7.79785e-1 67.69687 Ethane
Totals : 2345.53806
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...30 061724 2024-06-17 13-01-42\F-040-9-M18-Line No.3 Primary-Run 3.D
Sample Name: M18-Line No.3 Primary-Run 3
W8250 AST 6/19/2024 9:45:29 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 54
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 13 (F)
Injection Date : 6/17/2024 11:31:29 PM Inj : 1
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Backup
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
50
100
150
200
250
FID1 A, Front Signal (AST-2024-2...,2330 061724 2024-06-17 13-01-42\F-054-13-M18-Line No.3 Stack-Run 1.D)
4.
7
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.722 FM 493.77234 1.41708 699.71693 Methane
4.959 MF 44.13106 7.78891e-1 34.37328 Ethane
Totals : 734.09021
Data File C:\Users\P...330 061724 2024-06-17 13-01-42\F-054-13-M18-Line No.3 Stack-Run 1.D
Sample Name: M18-Line No.3 Stack-Run 1
W8250 AST 6/19/2024 9:52:13 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 55
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 13 (F)
Injection Date : 6/17/2024 11:46:38 PM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Backup
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
50
100
150
200
250
FID1 A, Front Signal (AST-2024-2...,2330 061724 2024-06-17 13-01-42\F-055-13-M18-Line No.3 Stack-Run 1.D)
4.
7
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.722 FM 489.18640 1.41709 693.21932 Methane
4.959 MM 43.89326 7.78881e-1 34.18762 Ethane
Totals : 727.40694
Data File C:\Users\P...330 061724 2024-06-17 13-01-42\F-055-13-M18-Line No.3 Stack-Run 1.D
Sample Name: M18-Line No.3 Stack-Run 1
W8250 AST 6/19/2024 9:52:51 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 56
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 13 (F)
Injection Date : 6/18/2024 12:01:49 AM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Backup
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
50
100
150
200
250
FID1 A, Front Signal (AST-2024-2...,2330 061724 2024-06-17 13-01-42\F-056-13-M18-Line No.3 Stack-Run 1.D)
4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.722 FM 484.22318 1.41709 686.18715 Methane
4.959 MF 43.51014 7.78865e-1 33.88852 Ethane
Totals : 720.07566
Data File C:\Users\P...330 061724 2024-06-17 13-01-42\F-056-13-M18-Line No.3 Stack-Run 1.D
Sample Name: M18-Line No.3 Stack-Run 1
W8250 AST 6/19/2024 9:53:19 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 57
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 14 (F)
Injection Date : 6/18/2024 12:16:58 AM Inj : 1
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Backup
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
FID1 A, Front Signal (AST-2024-2...,2330 061724 2024-06-17 13-01-42\F-057-14-M18-Line No.3 Stack-Run 2.D)
4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.722 FM 1984.88599 1.41691 2812.40940 Methane
4.959 MF 111.79294 7.79992e-1 87.19760 Ethane
Totals : 2899.60700
Data File C:\Users\P...330 061724 2024-06-17 13-01-42\F-057-14-M18-Line No.3 Stack-Run 2.D
Sample Name: M18-Line No.3 Stack-Run 2
W8250 AST 6/19/2024 9:54:04 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 58
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 14 (F)
Injection Date : 6/18/2024 12:32:07 AM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Backup
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
FID1 A, Front Signal (AST-2024-2...,2330 061724 2024-06-17 13-01-42\F-058-14-M18-Line No.3 Stack-Run 2.D)
4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.722 MF 1984.73438 1.41691 2812.19459 Methane
4.959 MF 111.81675 7.79992e-1 87.21619 Ethane
Totals : 2899.41078
Data File C:\Users\P...330 061724 2024-06-17 13-01-42\F-058-14-M18-Line No.3 Stack-Run 2.D
Sample Name: M18-Line No.3 Stack-Run 2
W8250 AST 6/19/2024 9:54:34 AM SYSTEM Page 1 of 2
27 of 93
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Acq. Operator : SYSTEM Seq. Line : 59
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 14 (F)
Injection Date : 6/18/2024 12:47:16 AM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Backup
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
FID1 A, Front Signal (AST-2024-2...,2330 061724 2024-06-17 13-01-42\F-059-14-M18-Line No.3 Stack-Run 2.D)
4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 FM 1985.82104 1.41691 2813.73425 Methane
4.959 MF 111.62429 7.79991e-1 87.06593 Ethane
Totals : 2900.80018
Data File C:\Users\P...330 061724 2024-06-17 13-01-42\F-059-14-M18-Line No.3 Stack-Run 2.D
Sample Name: M18-Line No.3 Stack-Run 2
W8250 AST 6/19/2024 9:54:58 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 61
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 15 (F)
Injection Date : 6/18/2024 1:17:32 AM Inj : 1
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Backup
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
FID1 A, Front Signal (AST-2024-2...,2330 061724 2024-06-17 13-01-42\F-061-15-M18-Line No.3 Stack-Run 3.D)
4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 MF 1624.75208 1.41692 2302.15171 Methane
4.959 MF 88.20089 7.79800e-1 68.77904 Ethane
Totals : 2370.93076
Data File C:\Users\P...330 061724 2024-06-17 13-01-42\F-061-15-M18-Line No.3 Stack-Run 3.D
Sample Name: M18-Line No.3 Stack-Run 3
W8250 AST 6/19/2024 9:55:23 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 62
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 15 (F)
Injection Date : 6/18/2024 1:32:37 AM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Backup
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
FID1 A, Front Signal (AST-2024-2...,2330 061724 2024-06-17 13-01-42\F-062-15-M18-Line No.3 Stack-Run 3.D)
4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 MF 1623.72021 1.41692 2300.68972 Methane
4.959 MF 88.12581 7.79799e-1 68.72043 Ethane
Totals : 2369.41015
Data File C:\Users\P...330 061724 2024-06-17 13-01-42\F-062-15-M18-Line No.3 Stack-Run 3.D
Sample Name: M18-Line No.3 Stack-Run 3
W8250 AST 6/19/2024 9:55:43 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 63
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 15 (F)
Injection Date : 6/18/2024 1:47:42 AM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Backup
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
100
200
300
400
500
600
700
800
FID1 A, Front Signal (AST-2024-2...,2330 061724 2024-06-17 13-01-42\F-063-15-M18-Line No.3 Stack-Run 3.D)
4.
7
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 MF 1624.30042 1.41692 2301.51178 Methane
4.959 MF 88.16790 7.79800e-1 68.75329 Ethane
Totals : 2370.26507
Data File C:\Users\P...330 061724 2024-06-17 13-01-42\F-063-15-M18-Line No.3 Stack-Run 3.D
Sample Name: M18-Line No.3 Stack-Run 3
W8250 AST 6/19/2024 9:56:03 AM SYSTEM Page 1 of 2
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=====================================================================
Acq. Operator : SYSTEM Seq. Line : 42
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 10 (F)
Injection Date : 6/17/2024 8:28:39 PM Inj : 1
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
1400
FID1 A, Front Signal (AST-2024-2...30 061724 2024-06-17 13-01-42\F-042-10-M18-Line No.10 Primary-Run 1.D)
4.
7
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.721 MF 2676.88696 1.41690 3792.87475 Methane
4.957 MF 147.63614 7.80166e-1 115.18075 Ethane
Totals : 3908.05550
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P... 061724 2024-06-17 13-01-42\F-042-10-M18-Line No.10 Primary-Run 1.D
Sample Name: M18-Line No.10 Primary-Run 1
W8250 AST 6/19/2024 9:46:10 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 43
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 10 (F)
Injection Date : 6/17/2024 8:43:58 PM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
1400
FID1 A, Front Signal (AST-2024-2...30 061724 2024-06-17 13-01-42\F-043-10-M18-Line No.10 Primary-Run 1.D)
4.
7
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.721 MF 2677.85205 1.41690 3794.24214 Methane
4.957 MF 147.60300 7.80166e-1 115.15488 Ethane
Totals : 3909.39701
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P... 061724 2024-06-17 13-01-42\F-043-10-M18-Line No.10 Primary-Run 1.D
Sample Name: M18-Line No.10 Primary-Run 1
W8250 AST 6/19/2024 9:46:44 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 44
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 10 (F)
Injection Date : 6/17/2024 8:59:14 PM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
1400
FID1 A, Front Signal (AST-2024-2...30 061724 2024-06-17 13-01-42\F-044-10-M18-Line No.10 Primary-Run 1.D)
4.
7
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1

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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.721 MF 2680.63159 1.41690 3798.18034 Methane
4.957 MF 147.97395 7.80168e-1 115.44449 Ethane
Totals : 3913.62483
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P... 061724 2024-06-17 13-01-42\F-044-10-M18-Line No.10 Primary-Run 1.D
Sample Name: M18-Line No.10 Primary-Run 1
W8250 AST 6/19/2024 9:47:06 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 46
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 11 (F)
Injection Date : 6/17/2024 9:29:45 PM Inj : 1
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
250
500
750
1000
1250
1500
FID1 A, Front Signal (AST-2024-2...30 061724 2024-06-17 13-01-42\F-046-11-M18-Line No.10 Primary-Run 2.D)
4.
7
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.721 MF 3046.62817 1.41689 4316.74459 Methane
4.958 MF 174.10159 7.80249e-1 135.84260 Ethane
Totals : 4452.58719
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P... 061724 2024-06-17 13-01-42\F-046-11-M18-Line No.10 Primary-Run 2.D
Sample Name: M18-Line No.10 Primary-Run 2
W8250 AST 6/19/2024 9:48:11 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 47
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 11 (F)
Injection Date : 6/17/2024 9:45:00 PM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
250
500
750
1000
1250
1500
FID1 A, Front Signal (AST-2024-2...30 061724 2024-06-17 13-01-42\F-047-11-M18-Line No.10 Primary-Run 2.D)
4.
7
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.722 MF 3044.16211 1.41689 4313.25053 Methane
4.958 MF 173.91794 7.80249e-1 135.69922 Ethane
Totals : 4448.94975
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P... 061724 2024-06-17 13-01-42\F-047-11-M18-Line No.10 Primary-Run 2.D
Sample Name: M18-Line No.10 Primary-Run 2
W8250 AST 6/19/2024 9:48:59 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 48
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 11 (F)
Injection Date : 6/17/2024 10:00:13 PM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
250
500
750
1000
1250
1500
FID1 A, Front Signal (AST-2024-2...30 061724 2024-06-17 13-01-42\F-048-11-M18-Line No.10 Primary-Run 2.D)
4.
7
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2

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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.722 MF 3048.25977 1.41689 4319.05632 Methane
4.958 MF 174.18994 7.80249e-1 135.91158 Ethane
Totals : 4454.96789
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P... 061724 2024-06-17 13-01-42\F-048-11-M18-Line No.10 Primary-Run 2.D
Sample Name: M18-Line No.10 Primary-Run 2
W8250 AST 6/19/2024 9:49:21 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 8
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 3 (F)
Injection Date : 6/18/2024 1:42:14 PM Inj : 1
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
FID1 A, Front Signal (AST-2024-2... 061824 2024-06-18 11-56-36\F-008-3-M18-Line No.10 Primary-Run 3 x2.D)
4.
7
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3

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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 FM 2332.83301 1.41690 3305.40003 Methane
4.959 MF 124.66424 7.80066e-1 97.24635 Ethane
Totals : 3402.64638
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...61824 2024-06-18 11-56-36\F-008-3-M18-Line No.10 Primary-Run 3 x2.D
Sample Name: M18-Line No.10 Primary-Run 3 x2
W8250 AST 6/19/2024 10:03:59 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 9
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 3 (F)
Injection Date : 6/18/2024 1:57:14 PM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
FID1 A, Front Signal (AST-2024-2... 061824 2024-06-18 11-56-36\F-009-3-M18-Line No.10 Primary-Run 3 x2.D)
4.
7
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3

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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 MF 2329.47925 1.41690 3300.64824 Methane
4.959 MF 124.43896 7.80065e-1 97.07047 Ethane
Totals : 3397.71871
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...61824 2024-06-18 11-56-36\F-009-3-M18-Line No.10 Primary-Run 3 x2.D
Sample Name: M18-Line No.10 Primary-Run 3 x2
W8250 AST 6/19/2024 10:04:29 AM SYSTEM Page 1 of 2
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=====================================================================
Acq. Operator : SYSTEM Seq. Line : 10
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 3 (F)
Injection Date : 6/18/2024 2:12:17 PM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
FID1 A, Front Signal (AST-2024-2... 061824 2024-06-18 11-56-36\F-010-3-M18-Line No.10 Primary-Run 3 x2.D)
4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 MF 2330.15479 1.41690 3301.60538 Methane
4.959 MF 124.34669 7.80065e-1 96.99844 Ethane
Totals : 3398.60382
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...61824 2024-06-18 11-56-36\F-010-3-M18-Line No.10 Primary-Run 3 x2.D
Sample Name: M18-Line No.10 Primary-Run 3 x2
W8250 AST 6/19/2024 10:04:53 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 12
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 4 (F)
Injection Date : 6/18/2024 2:42:19 PM Inj : 1
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
1400
FID1 A, Front Signal (AST-2024-2320 061824 2024-06-18 11-56-36\F-012-4-M18-Line No.10 Stack-Run 1.D)
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 MF 2568.16895 1.41690 3638.83703 Methane
4.959 MF 149.11908 7.80172e-1 116.33850 Ethane
Totals : 3755.17553
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...320 061824 2024-06-18 11-56-36\F-012-4-M18-Line No.10 Stack-Run 1.D
Sample Name: M18-Line No.10 Stack-Run 1
W8250 AST 6/19/2024 10:07:29 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 13
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 4 (F)
Injection Date : 6/18/2024 2:57:23 PM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
1400
FID1 A, Front Signal (AST-2024-2320 061824 2024-06-18 11-56-36\F-013-4-M18-Line No.10 Stack-Run 1.D)
4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 MF 2567.51245 1.41690 3637.90687 Methane
4.959 MF 149.32860 7.80173e-1 116.50207 Ethane
Totals : 3754.40895
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...320 061824 2024-06-18 11-56-36\F-013-4-M18-Line No.10 Stack-Run 1.D
Sample Name: M18-Line No.10 Stack-Run 1
W8250 AST 6/19/2024 10:08:20 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 14
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 4 (F)
Injection Date : 6/18/2024 3:12:27 PM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
1400
FID1 A, Front Signal (AST-2024-2320 061824 2024-06-18 11-56-36\F-014-4-M18-Line No.10 Stack-Run 1.D)
4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.722 MF 2566.73853 1.41690 3636.81033 Methane
4.958 MF 149.37363 7.80173e-1 116.53723 Ethane
Totals : 3753.34756
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...320 061824 2024-06-18 11-56-36\F-014-4-M18-Line No.10 Stack-Run 1.D
Sample Name: M18-Line No.10 Stack-Run 1
W8250 AST 6/19/2024 10:11:21 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 68
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 3 (F)
Injection Date : 6/18/2024 3:03:12 AM Inj : 1
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Backup
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
250
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1000
1250
1500
FID1 A, Front Signal (AST-2024-2...,2330 061724 2024-06-17 13-01-42\F-068-3-M18-Line No.10 Stack-Run 2.D)
4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 MF 3049.93945 1.41689 4321.43619 Methane
4.959 MF 174.84749 7.80251e-1 136.42493 Ethane
Totals : 4457.86112
Data File C:\Users\P...330 061724 2024-06-17 13-01-42\F-068-3-M18-Line No.10 Stack-Run 2.D
Sample Name: M18-Line No.10 Stack-Run 2
W8250 AST 6/19/2024 9:56:54 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 69
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 3 (F)
Injection Date : 6/18/2024 3:18:15 AM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Backup
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
250
500
750
1000
1250
1500
FID1 A, Front Signal (AST-2024-2...,2330 061724 2024-06-17 13-01-42\F-069-3-M18-Line No.10 Stack-Run 2.D)
4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 MF 3052.54395 1.41689 4325.12638 Methane
4.959 MF 174.99529 7.80251e-1 136.54032 Ethane
Totals : 4461.66670
Data File C:\Users\P...330 061724 2024-06-17 13-01-42\F-069-3-M18-Line No.10 Stack-Run 2.D
Sample Name: M18-Line No.10 Stack-Run 2
W8250 AST 6/19/2024 9:57:32 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 70
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 3 (F)
Injection Date : 6/18/2024 3:33:20 AM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Backup
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
250
500
750
1000
1250
1500
FID1 A, Front Signal (AST-2024-2...,2330 061724 2024-06-17 13-01-42\F-070-3-M18-Line No.10 Stack-Run 2.D)
4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 MF 3057.83618 1.41689 4332.62472 Methane
4.959 MF 175.44611 7.80253e-1 136.89228 Ethane
Totals : 4469.51699
Data File C:\Users\P...330 061724 2024-06-17 13-01-42\F-070-3-M18-Line No.10 Stack-Run 2.D
Sample Name: M18-Line No.10 Stack-Run 2
W8250 AST 6/19/2024 9:57:55 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 72
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 4 (F)
Injection Date : 6/18/2024 4:03:26 AM Inj : 1
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Backup
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
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1600
FID1 A, Front Signal (AST-2024-2...,2330 061724 2024-06-17 13-01-42\F-072-4-M18-Line No.10 Stack-Run 3.D)
4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 MF 2885.69189 1.41689 4088.72115 Methane
4.959 MF 168.41164 7.80233e-1 131.40039 Ethane
Totals : 4220.12154
Data File C:\Users\P...330 061724 2024-06-17 13-01-42\F-072-4-M18-Line No.10 Stack-Run 3.D
Sample Name: M18-Line No.10 Stack-Run 3
W8250 AST 6/19/2024 9:58:17 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 73
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 4 (F)
Injection Date : 6/18/2024 4:18:30 AM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Backup
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
1400
1600
FID1 A, Front Signal (AST-2024-2...,2330 061724 2024-06-17 13-01-42\F-073-4-M18-Line No.10 Stack-Run 3.D)
4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 MF 2888.54565 1.41689 4092.76451 Methane
4.959 MF 168.64777 7.80234e-1 131.58474 Ethane
Totals : 4224.34926
Data File C:\Users\P...330 061724 2024-06-17 13-01-42\F-073-4-M18-Line No.10 Stack-Run 3.D
Sample Name: M18-Line No.10 Stack-Run 3
W8250 AST 6/19/2024 9:58:39 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 74
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 4 (F)
Injection Date : 6/18/2024 4:33:33 AM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Backup
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
1400
1600
FID1 A, Front Signal (AST-2024-2...,2330 061724 2024-06-17 13-01-42\F-074-4-M18-Line No.10 Stack-Run 3.D)
4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 MF 2895.21680 1.41689 4102.21656 Methane
4.959 MF 169.14386 7.80236e-1 131.97205 Ethane
Totals : 4234.18861
Data File C:\Users\P...330 061724 2024-06-17 13-01-42\F-074-4-M18-Line No.10 Stack-Run 3.D
Sample Name: M18-Line No.10 Stack-Run 3
W8250 AST 6/19/2024 9:59:00 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 18
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 5 (F)
Injection Date : 6/18/2024 4:12:56 PM Inj : 1
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
100
200
300
400
500
600
700
800
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-018-5-M18-Line No.3 Primary-Run 1 C1 S.D)
4.
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External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.722 FM 1468.54150 1.41693 2080.82392 Methane
4.960 - - - Ethane
Totals : 2080.82392
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-018-5-M18-Line No.3 Primary-Run 1 C1 S.D
Sample Name: M18-Line No.3 Primary-Run 1 C1 Spk
W8250 AST 6/19/2024 10:17:22 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 19
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 5 (F)
Injection Date : 6/18/2024 4:27:59 PM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
100
200
300
400
500
600
700
800
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-019-5-M18-Line No.3 Primary-Run 1 C1 S.D)
4.
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External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.722 FM 1468.41321 1.41693 2080.64214 Methane
4.960 - - - Ethane
Totals : 2080.64214
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-019-5-M18-Line No.3 Primary-Run 1 C1 S.D
Sample Name: M18-Line No.3 Primary-Run 1 C1 Spk
W8250 AST 6/19/2024 10:19:20 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 20
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 5 (F)
Injection Date : 6/18/2024 4:43:02 PM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
100
200
300
400
500
600
700
800
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-020-5-M18-Line No.3 Primary-Run 1 C1 S.D)
4.
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External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.722 MF 1469.73206 1.41693 2082.51076 Methane
4.960 - - - Ethane
Totals : 2082.51076
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-020-5-M18-Line No.3 Primary-Run 1 C1 S.D
Sample Name: M18-Line No.3 Primary-Run 1 C1 Spk
W8250 AST 6/19/2024 10:20:15 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 22
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 6 (F)
Injection Date : 6/18/2024 5:13:10 PM Inj : 1
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
100
200
300
400
500
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-022-6-M18-Line No.3 Primary-Run 1 C2 S.D)
4.
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External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.720 - - - Methane
4.958 MM 84.07617 7.79755e-1 65.55884 Ethane
Totals : 65.55884
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-022-6-M18-Line No.3 Primary-Run 1 C2 S.D
Sample Name: M18-Line No.3 Primary-Run 1 C2 Spk
W8250 AST 6/19/2024 10:22:48 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 23
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 6 (F)
Injection Date : 6/18/2024 5:28:16 PM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
100
200
300
400
500
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-023-6-M18-Line No.3 Primary-Run 1 C2 S.D)
4.
9
5
8

-

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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.720 - - - Methane
4.958 MM 84.13277 7.79756e-1 65.60302 Ethane
Totals : 65.60302
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-023-6-M18-Line No.3 Primary-Run 1 C2 S.D
Sample Name: M18-Line No.3 Primary-Run 1 C2 Spk
W8250 AST 6/19/2024 10:24:20 AM SYSTEM Page 1 of 2
54 of 93
92 of 161
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Acq. Operator : SYSTEM Seq. Line : 24
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 6 (F)
Injection Date : 6/18/2024 5:43:19 PM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
100
200
300
400
500
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-024-6-M18-Line No.3 Primary-Run 1 C2 S.D)
4.
9
5
8

-

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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.720 - - - Methane
4.958 MM 84.02712 7.79755e-1 65.52054 Ethane
Totals : 65.52054
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-024-6-M18-Line No.3 Primary-Run 1 C2 S.D
Sample Name: M18-Line No.3 Primary-Run 1 C2 Spk
W8250 AST 6/19/2024 11:41:07 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 26
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 7 (F)
Injection Date : 6/18/2024 6:13:24 PM Inj : 1
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
100
200
300
400
500
600
700
800
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-026-7-M18-Line No.3 Stack-Run 2 C1 Spk.D)
4.
7
2
2

-

M
e
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a
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.722 FM 1508.31445 1.41693 2137.17644 Methane
4.960 - - - Ethane
Totals : 2137.17644
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-026-7-M18-Line No.3 Stack-Run 2 C1 Spk.D
Sample Name: M18-Line No.3 Stack-Run 2 C1 Spk
W8250 AST 6/19/2024 10:29:48 AM SYSTEM Page 1 of 2
56 of 93
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Acq. Operator : SYSTEM Seq. Line : 27
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 7 (F)
Injection Date : 6/18/2024 6:28:26 PM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
100
200
300
400
500
600
700
800
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-027-7-M18-Line No.3 Stack-Run 2 C1 Spk.D)
4.
7
2
2

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M
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.722 FM 1507.19421 1.41693 2135.58922 Methane
4.960 - - - Ethane
Totals : 2135.58922
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-027-7-M18-Line No.3 Stack-Run 2 C1 Spk.D
Sample Name: M18-Line No.3 Stack-Run 2 C1 Spk
W8250 AST 6/19/2024 10:30:12 AM SYSTEM Page 1 of 2
57 of 93
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Acq. Operator : SYSTEM Seq. Line : 28
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 7 (F)
Injection Date : 6/18/2024 6:43:28 PM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
100
200
300
400
500
600
700
800
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-028-7-M18-Line No.3 Stack-Run 2 C1 Spk.D)
4.
7
2
2

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M
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.722 FM 1507.99231 1.41693 2136.72001 Methane
4.960 - - - Ethane
Totals : 2136.72001
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-028-7-M18-Line No.3 Stack-Run 2 C1 Spk.D
Sample Name: M18-Line No.3 Stack-Run 2 C1 Spk
W8250 AST 6/19/2024 10:31:44 AM SYSTEM Page 1 of 2
58 of 93
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=====================================================================
Acq. Operator : SYSTEM Seq. Line : 30
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 8 (F)
Injection Date : 6/18/2024 7:13:31 PM Inj : 1
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
100
200
300
400
500
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-030-8-M18-Line No.3 Stack-Run 2 C2 Spk.D)
4.
9
5
9

-

E
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.720 - - - Methane
4.959 MM 85.54790 7.79772e-1 66.70783 Ethane
Totals : 66.70783
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-030-8-M18-Line No.3 Stack-Run 2 C2 Spk.D
Sample Name: M18-Line No.3 Stack-Run 2 C2 Spk
W8250 AST 6/19/2024 10:34:22 AM SYSTEM Page 1 of 2
59 of 93
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=====================================================================
Acq. Operator : SYSTEM Seq. Line : 31
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 8 (F)
Injection Date : 6/18/2024 7:28:35 PM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
100
200
300
400
500
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-031-8-M18-Line No.3 Stack-Run 2 C2 Spk.D)
4.
9
5
8

-

E
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.720 - - - Methane
4.958 MM 85.22459 7.79768e-1 66.45542 Ethane
Totals : 66.45542
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-031-8-M18-Line No.3 Stack-Run 2 C2 Spk.D
Sample Name: M18-Line No.3 Stack-Run 2 C2 Spk
W8250 AST 6/19/2024 10:39:39 AM SYSTEM Page 1 of 2
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=====================================================================
Acq. Operator : SYSTEM Seq. Line : 32
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 8 (F)
Injection Date : 6/18/2024 7:43:36 PM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
100
200
300
400
500
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-032-8-M18-Line No.3 Stack-Run 2 C2 Spk.D)
4.
9
5
8

-

E
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a
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.720 - - - Methane
4.958 MM 85.66287 7.79773e-1 66.79759 Ethane
Totals : 66.79759
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-032-8-M18-Line No.3 Stack-Run 2 C2 Spk.D
Sample Name: M18-Line No.3 Stack-Run 2 C2 Spk
W8250 AST 6/19/2024 10:40:40 AM SYSTEM Page 1 of 2
61 of 93
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=====================================================================
Acq. Operator : SYSTEM Seq. Line : 34
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 9 (F)
Injection Date : 6/18/2024 8:13:37 PM Inj : 1
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-034-9-M18-Line No.10 Primary-Run 2 C1 .D)
4.
7
2
3

-

M
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 MF 2238.72876 1.41691 3172.06792 Methane
4.960 - - - Ethane
Totals : 3172.06792
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-034-9-M18-Line No.10 Primary-Run 2 C1 .D
Sample Name: M18-Line No.10 Primary-Run 2 C1 Spk
W8250 AST 6/19/2024 11:02:36 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 35
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 9 (F)
Injection Date : 6/18/2024 8:28:37 PM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-035-9-M18-Line No.10 Primary-Run 2 C1 .D)
4.
7
2
3

-

M
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 MF 2240.41528 1.41691 3174.45747 Methane
4.960 - - - Ethane
Totals : 3174.45747
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-035-9-M18-Line No.10 Primary-Run 2 C1 .D
Sample Name: M18-Line No.10 Primary-Run 2 C1 Spk
W8250 AST 6/19/2024 11:03:45 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 36
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 9 (F)
Injection Date : 6/18/2024 8:43:37 PM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-036-9-M18-Line No.10 Primary-Run 2 C1 .D)
4.
7
2
3

-

M
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 MF 2240.66675 1.41691 3174.81376 Methane
4.960 - - - Ethane
Totals : 3174.81376
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-036-9-M18-Line No.10 Primary-Run 2 C1 .D
Sample Name: M18-Line No.10 Primary-Run 2 C1 Spk
W8250 AST 6/19/2024 11:04:13 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 38
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 10 (F)
Injection Date : 6/18/2024 9:13:36 PM Inj : 1
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-038-10-M18-Line No.10 Primary-Run 2 C2.D)
4.
9
5
9

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E
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a
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.720 - - - Methane
4.959 MM 132.11131 7.80102e-1 103.06036 Ethane
Totals : 103.06036
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-038-10-M18-Line No.10 Primary-Run 2 C2.D
Sample Name: M18-Line No.10 Primary-Run 2 C2 Spk
W8250 AST 6/19/2024 11:04:42 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 39
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 10 (F)
Injection Date : 6/18/2024 9:28:36 PM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-039-10-M18-Line No.10 Primary-Run 2 C2.D)
4.
9
5
9

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E
t
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a
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.720 - - - Methane
4.959 MM 132.49916 7.80104e-1 103.36316 Ethane
Totals : 103.36316
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-039-10-M18-Line No.10 Primary-Run 2 C2.D
Sample Name: M18-Line No.10 Primary-Run 2 C2 Spk
W8250 AST 6/19/2024 11:05:10 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 40
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 10 (F)
Injection Date : 6/18/2024 9:43:35 PM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-040-10-M18-Line No.10 Primary-Run 2 C2.D)
4.
9
5
9

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E
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.720 - - - Methane
4.959 MM 132.29082 7.80103e-1 103.20050 Ethane
Totals : 103.20050
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-040-10-M18-Line No.10 Primary-Run 2 C2.D
Sample Name: M18-Line No.10 Primary-Run 2 C2 Spk
W8250 AST 6/19/2024 11:06:07 AM SYSTEM Page 1 of 2
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=====================================================================
Acq. Operator : SYSTEM Seq. Line : 42
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 11 (F)
Injection Date : 6/18/2024 10:13:33 PM Inj : 1
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-042-11-M18-Line No.10 Stack-Run 2 C1 S.D)
4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 MF 2243.47144 1.41691 3178.78760 Methane
4.960 - - - Ethane
Totals : 3178.78760
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-042-11-M18-Line No.10 Stack-Run 2 C1 S.D
Sample Name: M18-Line No.10 Stack-Run 2 C1 Spk
W8250 AST 6/19/2024 11:13:03 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 43
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 11 (F)
Injection Date : 6/18/2024 10:28:31 PM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-043-11-M18-Line No.10 Stack-Run 2 C1 S.D)
4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 MF 2239.45215 1.41691 3173.09285 Methane
4.960 - - - Ethane
Totals : 3173.09285
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-043-11-M18-Line No.10 Stack-Run 2 C1 S.D
Sample Name: M18-Line No.10 Stack-Run 2 C1 Spk
W8250 AST 6/19/2024 11:13:40 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 44
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 11 (F)
Injection Date : 6/18/2024 10:43:32 PM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-044-11-M18-Line No.10 Stack-Run 2 C1 S.D)
4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 MF 2243.77026 1.41691 3179.21100 Methane
4.960 - - - Ethane
Totals : 3179.21100
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-044-11-M18-Line No.10 Stack-Run 2 C1 S.D
Sample Name: M18-Line No.10 Stack-Run 2 C1 Spk
W8250 AST 6/19/2024 11:14:22 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 46
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 12 (F)
Injection Date : 6/18/2024 11:13:30 PM Inj : 1
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-046-12-M18-Line No.10 Stack-Run 2 C2 S.D)
4.
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External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.720 - - - Methane
4.959 MM 131.56506 7.80100e-1 102.63390 Ethane
Totals : 102.63390
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-046-12-M18-Line No.10 Stack-Run 2 C2 S.D
Sample Name: M18-Line No.10 Stack-Run 2 C2 Spk
W8250 AST 6/19/2024 11:14:51 AM SYSTEM Page 1 of 2
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=====================================================================
Acq. Operator : SYSTEM Seq. Line : 47
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 12 (F)
Injection Date : 6/18/2024 11:28:29 PM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-047-12-M18-Line No.10 Stack-Run 2 C2 S.D)
4.
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External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.720 - - - Methane
4.959 MM 131.82281 7.80101e-1 102.83513 Ethane
Totals : 102.83513
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-047-12-M18-Line No.10 Stack-Run 2 C2 S.D
Sample Name: M18-Line No.10 Stack-Run 2 C2 Spk
W8250 AST 6/19/2024 11:15:19 AM SYSTEM Page 1 of 2
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=====================================================================
Acq. Operator : SYSTEM Seq. Line : 48
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 12 (F)
Injection Date : 6/18/2024 11:43:26 PM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Sample Info : AST-2024-2320
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
FID1 A, Front Signal (AST-2024-2...061824 2024-06-18 11-56-36\F-048-12-M18-Line No.10 Stack-Run 2 C2 S.D)
4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.720 - - - Methane
4.959 MM 131.29060 7.80099e-1 102.41962 Ethane
Totals : 102.41962
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...1824 2024-06-18 11-56-36\F-048-12-M18-Line No.10 Stack-Run 2 C2 S.D
Sample Name: M18-Line No.10 Stack-Run 2 C2 Spk
W8250 AST 6/19/2024 11:15:40 AM SYSTEM Page 1 of 2
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=====================================================================
Acq. Operator : SYSTEM Seq. Line : 25
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 1 (F)
Injection Date : 6/17/2024 4:46:54 PM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Additional Info : Peak(s) manually integrated
min3456789101112
pA
4
5
6
7
8
9
10
11
12
FID1 A, Front Signal (AST-2024-2320,2330 061724 2024-06-17 13-01-42\F-025-1-N2 Blank.D)
=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.720 - - - Methane
4.960 - - - Ethane
Totals : 0.00000
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...ta\AST-2024-2320,2330 061724 2024-06-17 13-01-42\F-025-1-N2 Blank.D
Sample Name: N2 Blank
W8250 AST 6/19/2024 9:07:40 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 3
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 1 (F)
Injection Date : 6/18/2024 12:27:12 PM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Additional Info : Peak(s) manually integrated
min3456789101112
pA
4
4.2
4.4
4.6
4.8
5
5.2
5.4
FID1 A, Front Signal (AST-2024-2320 061824 2024-06-18 11-56-36\F-003-1-N2 Blank.D)
=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.720 - - - Methane
4.960 - - - Ethane
Totals : 0.00000
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...\1\Data\AST-2024-2320 061824 2024-06-18 11-56-36\F-003-1-N2 Blank.D
Sample Name: N2 Blank
W8250 AST 6/19/2024 10:01:42 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 26
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 6 (F)
Injection Date : 6/17/2024 5:01:16 PM Inj : 1
Inj Volume : 10 µl
Acq. Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B 4MinC1C2_TAS.M
Last changed : 6/5/2024 9:06:50 AM by SYSTEM
Analysis Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B 4MinC1C2_TAS.M (Sequence Method)
Last changed : 6/18/2024 9:38:16 AM by SYSTEM
Additional Info : Peak(s) manually integrated
min12345
pA
0
200
400
600
800
1000
FID1 A, Front Signal (AST-2024-2320,2330 061724 2024-06-17 13-01-42\F-026-6-CCVi 2000ppm.D)
4.
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2
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 6/5/2024 9:06:38 AM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.720 FM 1309.59204 1.41814 1857.18990 Methane
4.882 - - - Ethylene
4.955 MF 2369.62427 7.80700e-1 1849.96578 Ethane
Totals : 3707.15569
Data File C:\Users\P...ST-2024-2320,2330 061724 2024-06-17 13-01-42\F-026-6-CCVi 2000ppm.D
Sample Name: CCVi 2000ppm
W8250 AST 6/19/2024 9:08:29 AM SYSTEM Page 1 of 2
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=====================================================================
Acq. Operator : SYSTEM Seq. Line : 27
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 6 (F)
Injection Date : 6/17/2024 5:07:03 PM Inj : 2
Inj Volume : 10 µl
Acq. Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B 4MinC1C2_TAS.M
Last changed : 6/5/2024 9:06:50 AM by SYSTEM
Analysis Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B 4MinC1C2_TAS.M (Sequence Method)
Last changed : 6/18/2024 9:38:16 AM by SYSTEM
Additional Info : Peak(s) manually integrated
min12345
pA
0
200
400
600
800
1000
FID1 A, Front Signal (AST-2024-2320,2330 061724 2024-06-17 13-01-42\F-027-6-CCVi 2000ppm.D)
4.
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2
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 6/5/2024 9:06:38 AM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.720 FM 1310.16748 1.41814 1858.00596 Methane
4.882 - - - Ethylene
4.956 MF 2370.56079 7.80700e-1 1850.69692 Ethane
Totals : 3708.70288
Data File C:\Users\P...ST-2024-2320,2330 061724 2024-06-17 13-01-42\F-027-6-CCVi 2000ppm.D
Sample Name: CCVi 2000ppm
W8250 AST 6/19/2024 9:09:06 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 28
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 6 (F)
Injection Date : 6/17/2024 5:12:51 PM Inj : 3
Inj Volume : 10 µl
Acq. Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B 4MinC1C2_TAS.M
Last changed : 6/5/2024 9:06:50 AM by SYSTEM
Analysis Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B 4MinC1C2_TAS.M (Sequence Method)
Last changed : 6/18/2024 9:38:16 AM by SYSTEM
Additional Info : Peak(s) manually integrated
min12345
pA
0
200
400
600
800
1000
FID1 A, Front Signal (AST-2024-2320,2330 061724 2024-06-17 13-01-42\F-028-6-CCVi 2000ppm.D)
4.
7
2
0

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M
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6

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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 6/5/2024 9:06:38 AM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.720 FM 1309.65430 1.41814 1857.27819 Methane
4.882 - - - Ethylene
4.956 MF 2369.72559 7.80700e-1 1850.04488 Ethane
Totals : 3707.32307
Data File C:\Users\P...ST-2024-2320,2330 061724 2024-06-17 13-01-42\F-028-6-CCVi 2000ppm.D
Sample Name: CCVi 2000ppm
W8250 AST 6/19/2024 9:09:25 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 4
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 2 (F)
Injection Date : 6/18/2024 12:42:12 PM Inj : 1
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
FID1 A, Front Signal (AST-2024-2320 061824 2024-06-18 11-56-36\F-004-2-CCVi 2000ppm.D)
4.
7
2
3

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M
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 MF 1368.53516 1.41694 1939.12938 Methane
4.959 FM 2487.13208 7.80678e-1 1941.64912 Ethane
Totals : 3880.77850
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...ata\AST-2024-2320 061824 2024-06-18 11-56-36\F-004-2-CCVi 2000ppm.D
Sample Name: CCVi 2000ppm
W8250 AST 6/19/2024 10:02:14 AM SYSTEM Page 1 of 2
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=====================================================================
Acq. Operator : SYSTEM Seq. Line : 5
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 2 (F)
Injection Date : 6/18/2024 12:57:12 PM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
FID1 A, Front Signal (AST-2024-2320 061824 2024-06-18 11-56-36\F-005-2-CCVi 2000ppm.D)
4.
7
2
3

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4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 MF 1366.94812 1.41694 1936.88078 Methane
4.959 FM 2484.84717 7.80678e-1 1939.86527 Ethane
Totals : 3876.74605
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...ata\AST-2024-2320 061824 2024-06-18 11-56-36\F-005-2-CCVi 2000ppm.D
Sample Name: CCVi 2000ppm
W8250 AST 6/19/2024 10:03:08 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 6
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 2 (F)
Injection Date : 6/18/2024 1:12:14 PM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
FID1 A, Front Signal (AST-2024-2320 061824 2024-06-18 11-56-36\F-006-2-CCVi 2000ppm.D)
4.
7
2
3

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4.
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 MF 1366.13989 1.41694 1935.73564 Methane
4.959 FM 2483.39233 7.80678e-1 1938.72946 Ethane
Totals : 3874.46510
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...ata\AST-2024-2320 061824 2024-06-18 11-56-36\F-006-2-CCVi 2000ppm.D
Sample Name: CCVi 2000ppm
W8250 AST 6/19/2024 10:03:36 AM SYSTEM Page 1 of 2
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=====================================================================
Acq. Operator : SYSTEM Seq. Line : 76
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 6 (F)
Injection Date : 6/18/2024 5:02:40 AM Inj : 1
Inj Volume : 10 µl
Acq. Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B 4MinC1C2_TAS.M
Last changed : 6/5/2024 9:06:50 AM by SYSTEM
Analysis Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B 4MinC1C2_TAS.M (Sequence Method)
Last changed : 6/18/2024 9:38:16 AM by SYSTEM
Additional Info : Peak(s) manually integrated
min12345
pA
0
200
400
600
800
1000
FID1 A, Front Signal (AST-2024-2320,2330 061724 2024-06-17 13-01-42\F-076-6-CCVf 2000ppm.D)
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External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 6/5/2024 9:06:38 AM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.722 FM 1340.83313 1.41814 1901.49428 Methane
4.882 - - - Ethylene
4.957 MF 2430.12402 7.80700e-1 1897.19769 Ethane
Totals : 3798.69197
Data File C:\Users\P...ST-2024-2320,2330 061724 2024-06-17 13-01-42\F-076-6-CCVf 2000ppm.D
Sample Name: CCVf 2000ppm
W8250 AST 6/19/2024 9:59:24 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 77
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 6 (F)
Injection Date : 6/18/2024 5:08:28 AM Inj : 2
Inj Volume : 10 µl
Acq. Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B 4MinC1C2_TAS.M
Last changed : 6/5/2024 9:06:50 AM by SYSTEM
Analysis Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B 4MinC1C2_TAS.M (Sequence Method)
Last changed : 6/18/2024 9:38:16 AM by SYSTEM
Additional Info : Peak(s) manually integrated
min12345
pA
0
200
400
600
800
1000
FID1 A, Front Signal (AST-2024-2320,2330 061724 2024-06-17 13-01-42\F-077-6-CCVf 2000ppm.D)
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External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 6/5/2024 9:06:38 AM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.722 FM 1340.36975 1.41814 1900.83714 Methane
4.882 - - - Ethylene
4.958 MF 2430.16455 7.80700e-1 1897.22933 Ethane
Totals : 3798.06647
Data File C:\Users\P...ST-2024-2320,2330 061724 2024-06-17 13-01-42\F-077-6-CCVf 2000ppm.D
Sample Name: CCVf 2000ppm
W8250 AST 6/19/2024 9:59:47 AM SYSTEM Page 1 of 2
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Acq. Operator : SYSTEM Seq. Line : 78
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 6 (F)
Injection Date : 6/18/2024 5:14:15 AM Inj : 3
Inj Volume : 10 µl
Acq. Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B 4MinC1C2_TAS.M
Last changed : 6/5/2024 9:06:50 AM by SYSTEM
Analysis Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320,2330 061724 2024
-06-17 13-01-42\FID B 4MinC1C2_TAS.M (Sequence Method)
Last changed : 6/18/2024 9:38:16 AM by SYSTEM
Additional Info : Peak(s) manually integrated
min12345
pA
0
200
400
600
800
1000
FID1 A, Front Signal (AST-2024-2320,2330 061724 2024-06-17 13-01-42\F-078-6-CCVf 2000ppm.D)
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 6/5/2024 9:06:38 AM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 FM 1341.12585 1.41814 1901.90940 Methane
4.882 - - - Ethylene
4.958 MF 2431.59106 7.80700e-1 1898.34301 Ethane
Totals : 3800.25241
Data File C:\Users\P...ST-2024-2320,2330 061724 2024-06-17 13-01-42\F-078-6-CCVf 2000ppm.D
Sample Name: CCVf 2000ppm
W8250 AST 6/19/2024 10:00:08 AM SYSTEM Page 1 of 2
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=====================================================================
Acq. Operator : SYSTEM Seq. Line : 50
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 2 (F)
Injection Date : 6/19/2024 12:13:21 AM Inj : 1
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
FID1 A, Front Signal (AST-2024-2320 061824 2024-06-18 11-56-36\F-050-2-CCVf 2000ppm.D)
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 FM 1372.84473 1.41694 1945.23542 Methane
4.959 MF 2495.39282 7.80678e-1 1948.09837 Ethane
Totals : 3893.33379
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...ata\AST-2024-2320 061824 2024-06-18 11-56-36\F-050-2-CCVf 2000ppm.D
Sample Name: CCVf 2000ppm
W8250 AST 6/19/2024 11:36:44 AM SYSTEM Page 1 of 2
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=====================================================================
Acq. Operator : SYSTEM Seq. Line : 51
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 2 (F)
Injection Date : 6/19/2024 12:28:20 AM Inj : 2
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
FID1 A, Front Signal (AST-2024-2320 061824 2024-06-18 11-56-36\F-051-2-CCVf 2000ppm.D)
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 FM 1373.45532 1.41694 1946.10054 Methane
4.959 MF 2496.92529 7.80678e-1 1949.29478 Ethane
Totals : 3895.39533
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...ata\AST-2024-2320 061824 2024-06-18 11-56-36\F-051-2-CCVf 2000ppm.D
Sample Name: CCVf 2000ppm
W8250 AST 6/19/2024 11:37:06 AM SYSTEM Page 1 of 2
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=====================================================================
Acq. Operator : SYSTEM Seq. Line : 52
Sample Operator : SYSTEM
Acq. Instrument : W8250 AST Location : 2 (F)
Injection Date : 6/19/2024 12:43:19 AM Inj : 3
Inj Volume : 10 µl
Method : C:\Users\Public\Documents\ChemStation\1\Data\AST-2024-2320 061824 2024-06-
18 11-56-36\FID B, C1C2_TAS.M (Sequence Method)
Last changed : 5/30/2024 3:24:54 PM by SYSTEM
Additional Info : Peak(s) manually integrated
min3456789101112
pA
0
200
400
600
800
1000
1200
FID1 A, Front Signal (AST-2024-2320 061824 2024-06-18 11-56-36\F-052-2-CCVf 2000ppm.D)
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=====================================================================
External Standard Report
=====================================================================
Sorted By : Signal
Calib. Data Modified : 5/30/2024 3:21:53 PM
Multiplier : 1.0000
Dilution : 1.0000
Do not use Multiplier & Dilution Factor with ISTDs
Signal 1: FID1 A, Front Signal
RetTime Type Area Amt/Area Amount Grp Name
[min] [pA*s] [ppm]
-------|------|----------|----------|----------|--|------------------
4.723 FM 1373.81677 1.41694 1946.61267 Methane
4.959 MF 2497.50830 7.80678e-1 1949.74994 Ethane
Totals : 3896.36261
Uncalibrated peaks RF : 1.00000
Data File C:\Users\P...ata\AST-2024-2320 061824 2024-06-18 11-56-36\F-052-2-CCVf 2000ppm.D
Sample Name: CCVf 2000ppm
W8250 AST 6/19/2024 11:37:24 AM SYSTEM Page 1 of 2
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Appendix D

131 of 161
QA Data
Location
Source
Project No.
O₂ - Outlet CO₂ - Outlet THC - Outlet
Make SERVOMEX SERVOMEX VIG
Model 1440 1440 20/2
S/N 14200/3279 14150/3279 8840524
Operating Range 25 25 10000
Cylinder ID
Zero NA NA NA
Mid CC764364 CC764364 EB0078090
High CC764364 CC764364 EB0078090
Cylinder Certifed Values
Zero NA NA NA
Mid 23.98 23.9 8560
High 23.98 23.9 8560
Cylinder Expiration Date
Zero NA NA NA
Mid 9/19/31 9/19/31 10/2/31
High 9/19/31 9/19/31 10/2/31
Type of Sample Line Heated Sample Line
Parameter
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 3
AST-2024-2320
132 of 161
Response Times
Location:
Source:
Project No.:
O₂ - Outlet CO₂ - Outlet THC - Outlet
Zero 30 30 65
Low NA NA 70
Mid 50 50 72
High 52 52 74
Average 44.0 44.0 70.3
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 3
AST-2024-2320
Parameter
Response Times, seconds
133 of 161
Calibration Data
Location:
Source:
Project No.:
Date:
O₂ - Outlet CO₂ - Outlet THC - Outlet
Expected Average Concentration 14.00 5.00 1000.00
Span Between
Low 14.00 5.00 1500.00
High 70.00 25.00 2500.00
Desired Span 23.98 10.00 2000.00
Low Range Gas
Low NA NA 500.00
High NA NA 700.00
Mid Range Gas
Low 9.59 4.00 900.00
High 14.39 6.00 1100.00
High Range Gas
Low NA NA 1600.00
High NA NA 1800.00
Actual Concentration (% or ppm)
Zero 0.00 0.00 0.00
Low NA NA 700.00
Mid 12.00 5.00 1000.00
High 23.98 10.00 1700.00
Response Time (seconds)44.00 44.00 70.25
Upscale Calibration Gas (CMA)Mid Mid Mid
Instrument Response (% or ppm)
Zero 0.00 0.00 4.09
Low NA NA 696.88
Mid 11.95 5.04 996.44
High 23.97 10.00 1697.41
Performance (% of Span or Cal. Gas Conc.)
Zero 0.00 0.00 0.00
Low NA NA -0.64
Mid 0.21 0.40 -0.37
High 0.04 0.00 0.00
Status
Zero PASS PASS PASS
Low NA NA PASS
Mid PASS PASS PASS
High PASS PASS PASS
Process Line No. 3
Pepperidge Farm Incorporated - Richmond, UT
Parameter
6/12/24
AST-2024-2320
134 of 161
Bias/Drift Determinations
Location:
Source:
Project No.:
O₂ - Outlet CO₂ - Outlet THC - Outlet
Pretest System Zero Response 0.00 0.01 4.09
Posttest System Zero Response 0.00 0.00 0.00
Pretest System Upscale Response 12.01 4.95 996.44
Posttest System Upscale Response 11.97 5.07 1,002.33
Pretest System Zero Response 0.00 0.00 0.00
Posttest System Zero Response 0.02 0.00 0.00
Pretest System Upscale Response 11.97 5.07 1,002.33
Posttest System Upscale Response 12.18 5.04 1,001.51
Pretest System Zero Response 0.02 0.00 0.00
Posttest System Zero Response 0.13 0.00 0.00
Pretest System Upscale Response 12.18 5.04 1,001.51
Posttest System Upscale Response 12.11 5.02 995.77
Run 2
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 3
AST-2024-2320
Parameter
Run 1
Run 3
135 of 161
Bias/Drift Determinations
Location:
Source:
Project No.:
O₂ - Outlet CO₂ - Outlet THC - Outlet
Run 1 Date 6/12/24
Span Value 23.98 10.00 2,000.00
Initial Instrument Zero Cal Response 0.00 0.00 4.09
Initial Instrument Upscale Cal Response 11.95 5.04 996.44
Pretest System Zero Response 0.00 0.01 4.09
Posttest System Zero Response 0.00 0.00 0.00
Pretest System Upscale Response 12.01 4.95 996.44
Posttest System Upscale Response 11.97 5.07 1,002.33
Bias (%)
Pretest Zero 0.00 0.10 NA
Posttest Zero 0.00 0.00 NA
Pretest Span 0.25 -0.90 NA
Posttest Span 0.08 0.30 NA
Drift (%)
Zero 0.00 -0.10 -0.20
Mid -0.17 1.20 0.29
Run 2 Date 6/12/24
Span Value 23.98 10.00 2,000.00
Instrument Zero Cal Response 0.00 0.00 4.09
Instrument Upscale Cal Response 11.95 5.04 996.44
Pretest System Zero Response 0.00 0.00 0.00
Posttest System Zero Response 0.02 0.00 0.00
Pretest System Upscale Response 11.97 5.07 1,002.33
Posttest System Upscale Response 12.18 5.04 1,001.51
Bias (%)
Pretest Zero 0.00 0.00 NA
Posttest Zero 0.08 0.00 NA
Pretest Span 0.08 0.30 NA
Posttest Span 0.96 0.00 NA
Drift (%)
Zero 0.08 0.00 0.00
Mid 0.88 -0.30 -0.04
Run 3 Date 6/12/24
Span Value 23.98 10.00 2,000.00
Instrument Zero Cal Response 0.00 0.00 4.09
Instrument Upscale Cal Response 11.95 5.04 996.44
Pretest System Zero Response 0.02 0.00 0.00
Posttest System Zero Response 0.13 0.00 0.00
Pretest System Upscale Response 12.18 5.04 1,001.51
Posttest System Upscale Response 12.11 5.02 995.77
Bias (%)
Pretest Zero 0.08 0.00 NA
Posttest Zero 0.54 0.00 NA
Pretest Span 0.96 0.00 NA
Posttest Span 0.67 -0.20 NA
Drift (%)
Zero 0.46 0.00 0.00
Mid -0.29 -0.20 -0.29
Parameter
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 3
AST-2024-2320
136 of 161
QA Data
Location
Source
Project No.
O₂ - Outlet CO₂ - Outlet THC - Outlet
Make SERVOMEX SERVOMEX VIG
Model 1440 1440 20/2
S/N 14200/3279 14150/3279 8840524
Operating Range 25 25 10000
Cylinder ID
Zero NA NA NA
Mid CC764364 CC764364 EB0078090
High CC764364 CC764364 EB0078090
Cylinder Certifed Values
Zero NA NA NA
Mid 23.98 23.9 8560
High 23.98 23.9 8560
Cylinder Expiration Date
Zero NA NA NA
Mid 9/19/31 9/19/31 10/2/31
High 9/19/31 9/19/31 10/2/31
Type of Sample Line Heated Sample Line
Parameter
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 10
AST-2024-2320
137 of 161
Response Times
Location:
Source:
Project No.:
O₂ - Outlet CO₂ - Outlet THC - Outlet
Zero 30 30 65
Low NA NA 70
Mid 50 50 72
High 52 52 74
Average 44.0 44.0 70.3
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 10
AST-2024-2320
Parameter
Response Times, seconds
138 of 161
Calibration Data
Location:
Source:
Project No.:
Date:
O₂ - Outlet CO₂ - Outlet THC - Outlet
Expected Average Concentration 14.00 5.00 1000.00
Span Between
Low 14.00 5.00 1500.00
High 70.00 25.00 2500.00
Desired Span 23.98 10.00 2000.00
Low Range Gas
Low NA NA 500.00
High NA NA 700.00
Mid Range Gas
Low 9.59 4.00 900.00
High 14.39 6.00 1100.00
High Range Gas
Low NA NA 1600.00
High NA NA 1800.00
Actual Concentration (% or ppm)
Zero 0.00 0.00 0.00
Low NA NA 700.00
Mid 12.00 5.00 1000.00
High 23.98 10.00 1700.00
Response Time (seconds)44.00 44.00 70.25
Upscale Calibration Gas (CMA)Mid Mid Mid
Instrument Response (% or ppm)
Zero 0.00 0.00 4.09
Low NA NA 696.88
Mid 11.95 5.04 996.44
High 23.97 10.00 1697.41
Performance (% of Span or Cal. Gas Conc.)
Zero 0.00 0.00 0.00
Low NA NA -0.64
Mid 0.21 0.40 -0.37
High 0.04 0.00 0.00
Status
Zero PASS PASS PASS
Low NA NA PASS
Mid PASS PASS PASS
High PASS PASS PASS
Process Line No. 10
Pepperidge Farm Incorporated - Richmond, UT
Parameter
6/12/24
AST-2024-2320
139 of 161
Bias/Drift Determinations
Location:
Source:
Project No.:
O₂ - Outlet CO₂ - Outlet THC - Outlet
Pretest System Zero Response 0.13 0.00 0.00
Posttest System Zero Response 0.01 0.00 0.00
Pretest System Upscale Response 12.11 5.02 995.77
Posttest System Upscale Response 11.98 4.97 1,009.57
Pretest System Zero Response 0.01 0.00 0.00
Posttest System Zero Response 0.00 0.00 0.00
Pretest System Upscale Response 11.98 4.97 1,009.57
Posttest System Upscale Response 12.00 4.93 1,002.09
Pretest System Zero Response 0.00 0.00 0.00
Posttest System Zero Response 0.00 0.00 0.00
Pretest System Upscale Response 12.00 4.93 1,002.09
Posttest System Upscale Response 11.94 4.91 993.64
Run 2
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 10
AST-2024-2320
Parameter
Run 1
Run 3
140 of 161
Bias/Drift Determinations
Location:
Source:
Project No.:
O₂ - Outlet CO₂ - Outlet THC - Outlet
Run 1 Date 6/12/24
Span Value 23.98 10.00 2,000.00
Initial Instrument Zero Cal Response 0.00 0.00 4.09
Initial Instrument Upscale Cal Response 11.95 5.04 996.44
Pretest System Zero Response 0.13 0.00 0.00
Posttest System Zero Response 0.01 0.00 0.00
Pretest System Upscale Response 12.11 5.02 995.77
Posttest System Upscale Response 11.98 4.97 1,009.57
Bias (%)
Pretest Zero 0.54 0.00 NA
Posttest Zero 0.04 0.00 NA
Pretest Span 0.67 -0.20 NA
Posttest Span 0.13 -0.70 NA
Drift (%)
Zero -0.50 0.00 0.00
Mid -0.54 -0.50 0.69
Run 2 Date 6/12/24
Span Value 23.98 10.00 2,000.00
Instrument Zero Cal Response 0.00 0.00 4.09
Instrument Upscale Cal Response 11.95 5.04 996.44
Pretest System Zero Response 0.01 0.00 0.00
Posttest System Zero Response 0.00 0.00 0.00
Pretest System Upscale Response 11.98 4.97 1,009.57
Posttest System Upscale Response 12.00 4.93 1,002.09
Bias (%)
Pretest Zero 0.04 0.00 NA
Posttest Zero 0.00 0.00 NA
Pretest Span 0.13 -0.70 NA
Posttest Span 0.21 -1.10 NA
Drift (%)
Zero -0.04 0.00 0.00
Mid 0.08 -0.40 -0.37
Run 3 Date 6/12/24
Span Value 23.98 10.00 2,000.00
Instrument Zero Cal Response 0.00 0.00 4.09
Instrument Upscale Cal Response 11.95 5.04 996.44
Pretest System Zero Response 0.00 0.00 0.00
Posttest System Zero Response 0.00 0.00 0.00
Pretest System Upscale Response 12.00 4.93 1,002.09
Posttest System Upscale Response 11.94 4.91 993.64
Bias (%)
Pretest Zero 0.00 0.00 NA
Posttest Zero 0.00 0.00 NA
Pretest Span 0.21 -1.10 NA
Posttest Span -0.04 -1.30 NA
Drift (%)
Zero 0.00 0.00 0.00
Mid -0.25 -0.20 -0.42
Parameter
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 10
AST-2024-2320
141 of 161
Balance
Red Ball Technical Gas Service
555 Craig Kennedy Way
Shreveport, LA 71107
800-551-8150
Accreditation #62754 PGVP Vendor ID # G12023
EPA PROTOCOL GAS CERTIFICATE OF ANALYSIS
Cylinder Number:CC764364 Certification Date:09/21/2023
Product ID Number:127907 Expiration Date:09/19/2031
Cylinder Pressure:1900 PSIG MFG Facility: - Shreveport - LA
COA #CC764364.20230830-0 Lot Number:CC764364.20230830
Customer PO. NO.:Tracking Number:108811898
Customer:Previous Certification Dates:
This calibration standard has been certified per the May 2012 EPA Traceability Protocol, Document EPA-600/R-12/531,
using procedure G2.
Do Not Use This Cylinder Below 100 psig (0.7 Megapascal).
Certified Concentration(s)
Component Concentration Uncertainty Analytical Principle Assayed On
Carbon Dioxide 23.9 %±0.2 %FTIR 09/21/2023
Oxygen 23.98 %±0.04 %MPA 09/14/2023
Nitrogen
Analytical Measurement Data Available Online.
Reference Standard(s)
Serial Number Lot Expiration Type Balance Component Concentration Uncertainty(%)NIST Reference
CC737012 CC737012.20230228 07/09/2031 GMIS N2 O2 20 %0.112 SRM 2659a
EB0022021 EB0022021.20180323 07/15/2026 GMIS N2 CO2 14.9 %0.777 101001
Analytical Instrumentation SMART-CERT
Component Principle Make MPC Date
O2 MPA Thermo 09/13/2023
CO2 FTIR MKS 09/21/2023
Serial
1162980025
017146467
This is to certify the gases referenced have been calibrated/tested, and verified to meet the defined specifications. This
calibration/test was performed using Gases or Scales that are traceable through National Institute of Standards and
Technology (NIST) to the International System of Units (SI). The basis of compliance stated is a comparison of the
measurement parameters to the specified or required calibration/testing process. The expanded uncertainties use a coverage
factor of k=2 to approximate the 95% confidence level of the measurement, unless otherwise noted. This calibration certificate
applies only to the item described and shall not be reproduced other than in full, without written approval from Red Ball
Technical Gas Services. If not included, the uncertainty of calibrations are available upon request and were taken into account
when determining pass or fail.
Timothy Davis
Analytical Chemist
Assay Laboratory: Red Ball TGS
Version 02-J, Revised on 2018-09-17
Model
410i
MKS 2031DJG2EKVS13T
142 of 161
Balance
Red Ball Technical Gas Service
555 Craig Kennedy Way
Shreveport, LA 71107
800-551-8150
Accreditation #62754 PGVP Vendor ID # G12023
EPA PROTOCOL GAS CERTIFICATE OF ANALYSIS
Cylinder Number:EB0078090 Certification Date:10/04/2023
Product ID Number:125959 Expiration Date:10/02/2031
Cylinder Pressure:1900 PSIG MFG Facility: - Shreveport - LA
COA #EB0078090.20230913-0 Lot Number:EB0078090.20230913
Customer PO. NO.:Tracking Number:084269001
Customer:Previous Certification Dates:
This calibration standard has been certified per the May 2012 EPA Traceability Protocol, Document EPA-600/R-12/531,
using procedure G2.
Do Not Use This Cylinder Below 100 psig (0.7 Megapascal).
Certified Concentration(s)
Component Concentration Uncertainty Analytical Principle Assayed On
Propane 8560 PPM ±80 PPM FTIR 10/04/2023
Nitrogen
Analytical Measurement Data Available Online.
Reference Standard(s)
Serial Number Lot Expiration Type Balance Component Concentration Uncertainty(%)NIST Reference
EB0064251 EB0064251.201610114g 05/17/2024 GMIS N2 C3H8 1495 PPM 0.603 2647a
Analytical Instrumentation SMART-CERT
Component Principle Make MPC Date
C3H8 FTIR MKS 10/03/2023
Serial
017146467
This is to certify the gases referenced have been calibrated/tested, and verified to meet the defined specifications. This
calibration/test was performed using Gases or Scales that are traceable through National Institute of Standards and
Technology (NIST) to the International System of Units (SI). The basis of compliance stated is a comparison of the
measurement parameters to the specified or required calibration/testing process. The expanded uncertainties use a coverage
factor of k=2 to approximate the 95% confidence level of the measurement, unless otherwise noted. This calibration certificate
applies only to the item described and shall not be reproduced other than in full, without written approval from Red Ball
Technical Gas Services. If not included, the uncertainty of calibrations are available upon request and were taken into account
when determining pass or fail.
Aaron Varelas
Analytical Chemist
Assay Laboratory: Red Ball TGS
Version 02-J, Revised on 2018-09-17
Model
MKS 2031DJG2EKVS13T
143 of 161
Location:
Source:
Project No.:
Date
EPA
O2
SERVOMEX
1440
14200/3279
25.0
Cylinder Number ID
Zero NA
Mid RR04311
High CC764364
Cylinder Certified Values
Zero 0.0
Mid 11
High 23.98
Instrument Response (% or ppm)
Zero 0.0
Mid 11.1
High 24.0
Calibration Gas Selection (% of Span)
Mid 44.0
High 95.9
Calibration Error Performance (% of Span)
Zero 0.0
Mid 0.4
High -0.1
Linearity (% of Range)
0.4
(%) lpm (%) (%) (%) (%) (%) (%) (%)( ± 2 %)
10L/5L 80.0 5.0 19.2 19.2 19.2 19.2 19.2 19.20 0.00 0.0%
10L/5L 50.0 5.0 12.0 12.0 12.1 12.1 12.1 12.08 0.08 0.7%
10L/1L 20.0 4.0 4.8 4.8 4.8 4.8 4.8 4.80 0.00 -0.1%
10L/1L 10.0 4.0 2.4 2.4 2.4 2.4 2.4 2.39 -0.01 -0.3%
(%)( ± 2 %)( ± 2 %)( ± 2 %)
19.20 0.1% -0.1% 0.1%
12.08 0.1% -0.3% 0.1%
4.80 0.3% -0.6% 0.3%
2.39 -0.1% 1.1% -1.0%
Mid-Level Supply Gas Calibration Direct to Analyzer
Calibration Injection 1 Injection 2 Injection 3 Average
Gas Analyzer Analyzer Analyzer Analyzer
Concentration Concentration Concentration Concentration Concentration
(%) (%) (%) (%) (%) (%)( ± 2 %)
11.00 11.0 11.0 11.0 10.95 -0.05 -0.5%
Average
Analyzer
Concentration
Injection 1
Error
Injection 2
Error
Injection 3
Error
Difference
Average
Error
*Not all AST Environics Units have 2-10L Mass Flow Controllers. For these units the 90% @ 7lpm and 80% @ 7lpm injections will not be conducted.
Cylinder Gas ID (Mid-Level): RR04311
Cylinder Gas Concentration (Mid-Level), %: 11
Target Mass Flow
Contollers
Target
Dilution
Target Flow
Rate
Target
Concentration
Actual
Concentration
Injection 1
Analyzer
Concentration
Injection 2
Analyzer
Concentration
Injection 3
Analyzer
Concentration
Average
Analyzer
Concentration Difference Average Error
Component/Balance Gas: O2/N2
Cylinder Gas ID (Dilution): CC764364
Cylinder Gas Concentration (Dilution), %: 23.98
Analyzer Model: 1440
Analyzer SN: 14200/3279
Environics ID: 8412
Analyzer Make: SERVOMEX
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 3
AST-2024-2320
6/10/24
Parameter
Make
Model
S/N
Span
Method Criteria
144 of 161
Issuing Department
Dilution System Make:
Dilution System Model:
Dilution System S/N:
Calibration Equipment Make:
Calibration Equipment Model:
Calibration Equipment S/N:
Flow Cell S/N:
Flow Cell S/N:
Calibration Gas:
Barometric Pressure, mmHg:
Ambient Temperature, °F:
Mass Flow Controller ID
Size, ccm:
Make:
Model:
S/N:
Set Flow True Flow Difference Set Flow True Flow Difference Set Flow True Flow Difference
cc/min cc/min cc/min cc/min cc/min cc/min
5%500 493 1.4%500 491 1.8%50 49 2.2%
10%1,000 1,008 0.8%1,000 1,013 1.3%100 99 0.9%
20%2,000 2,039 2.0%2,000 2,041 2.1%200 200 0.0%
30%3,000 3,061 2.0%3,000 3,074 2.5%300 301 0.3%
40%4,000 4,079 2.0%4,000 4,105 2.6%400 402 0.6%
50%5,000 5,093 1.9%5,000 5,127 2.5%500 503 0.6%
60%6,000 6,110 1.8%6,000 6,143 2.4%600 605 0.8%
70%7,000 7,134 1.9%7,000 7,168 2.4%700 707 1.0%
80%8,000 8,154 1.9%8,000 8,175 2.2%800 809 1.2%
90%9,000 9,183 2.0%9,000 9,190 2.1%900 914 1.5%
100%10,000 10,202 2.0%10,000 10,202 2.0%1,000 1,019 1.9%
Date:
Environics
FFC 202
10,000
# 2 # 3
Environics
1,000
Environics
FFC 202 FFC 202
#1
10,000
Environics
25.641
64.4
4040
272120
Nitrogen
Calibration Performed By:JFT
2/21/2024
626687006
Note: The mass flow controller's calibration values are used by the dilution system's operating software to improve accuracy. These calibrations are not necessarily
indicative of the systems overall performance. Performance is verified by conducting a Method 205 prior to each field use.
626687003 626683003
8412-02-21-2024
Alicat Scientific
M-10SLPD/5MM-D/5M, M-1SLPM-D/5M
272121
272121
620.009
22.0
12/16/22
1 of 1
Mass Flow Controller Calibration
Tech Services
Document ID
Revision
Effective Date
Page
145 of 161
Balance
Red Ball Technical Gas Service
555 Craig Kennedy Way
Shreveport, LA 71107
800-551-8150
Accreditation #62754 PGVP Vendor ID # G12023
EPA PROTOCOL GAS CERTIFICATE OF ANALYSIS
Cylinder Number:RR04311 Certification Date:09/21/2023
Product ID Number:125371 Expiration Date:09/19/2031
Cylinder Pressure:1900 PSIG MFG Facility: - Shreveport - LA
COA #RR04311.20230831-0 Lot Number:RR04311.20230831
Customer PO. NO.:Tracking Number:107549958
Customer:Previous Certification Dates:
This calibration standard has been certified per the May 2012 EPA Traceability Protocol, Document EPA-600/R-12/531,
using procedure G1.
Do Not Use This Cylinder Below 100 psig (0.7 Megapascal).
Certified Concentration(s)
Component Concentration Uncertainty Analytical Principle Assayed On
Carbon Dioxide 10.9 %±0.11 %FTIR 09/21/2023
Oxygen 11.00 %±0.03 %MPA 09/18/2023
Nitrogen
Analytical Measurement Data Available Online.
Reference Standard(s)
Serial Number Lot Expiration Type Balance Component Concentration Uncertainty(%)NIST Reference
CC737012 CC737012.20230228 07/09/2031 GMIS N2 O2 20 %0.112 SRM 2659a
EB0022021 EB0022021.20180323 07/15/2026 GMIS N2 CO2 14.9 %0.777 101001
Analytical Instrumentation SMART-CERT
Component Principle Make MPC Date
O2 MPA Thermo 09/18/2023
CO2 FTIR MKS 09/21/2023
Serial
1162980025
017146467
This is to certify the gases referenced have been calibrated/tested, and verified to meet the defined specifications. This
calibration/test was performed using Gases or Scales that are traceable through National Institute of Standards and
Technology (NIST) to the International System of Units (SI). The basis of compliance stated is a comparison of the
measurement parameters to the specified or required calibration/testing process. The expanded uncertainties use a coverage
factor of k=2 to approximate the 95% confidence level of the measurement, unless otherwise noted. This calibration certificate
applies only to the item described and shall not be reproduced other than in full, without written approval from Red Ball
Technical Gas Services. If not included, the uncertainty of calibrations are available upon request and were taken into account
when determining pass or fail.
Jasmine Godfrey
Analytical Chemist
Assay Laboratory: Red Ball TGS
Version 02-J, Revised on 2018-09-17
Model
410i
MKS 2031DJG2EKVS13T
146 of 161
Location Pepperidge Farm Incorporated - Richmond, UT
Source Process Line No. 3
Project No.AST-2024-2320
Date 6/12/24
Analyzer VIG 20/2
Serial Number 8840524
Parameter Ethanol
Certified Concentration, ppm 102.9
Analyzer Response 1, ppm 35.2
Average Response, ppm 35.20
Response Factor 0.34
147 of 161
Location Pepperidge Farm Incorporated - Richmond, UT
Source Process Line No. 10
Project No.AST-2024-2320
Date 6/12/24
Analyzer VIG 20/2
Serial Number 8840524
Parameter Ethanol
Certified Concentration, ppm 102.9
Analyzer Response 1, ppm 35.2
Average Response, ppm 35.20
Response Factor 0.34
148 of 161
QA Data
Location
Source
Project No.
Parameter(s)
Date Pitot ID
Evidence of
damage?
Evidence of
mis-alignment?
Calibration or
Repair required?
6/12/24 P-807 no no no
Date Probe or
Thermocouple ID
Reference
Temp. (°F)
Indicated
Temp. (°F)Difference Criteria
6/12/24 P-807 70.0 70.0 0.0%
Date 06/12/24
Balance ID:5A2873330
Certified Weight ID:SLC-1KG-1
Certified Weight (g):1000.0
Measured Weight (g):999.8
Weight Difference (g):0.2--------
Date Barometric Pressure Evidence of
damage?Reading Verified Calibration or
Repair required?
6/12/24 Weather Station NA NA NA
6/12/24 MB 702
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 3
AST-2024-2320
VFR
± 1.5 % (absolute)
Field Balance Check
Pass
Weather Station Location
Richmond, UT
Date Meter Box ID Positive Pressure Leak Check
149 of 161
QA Data
Location
Source
Project No.
Parameter(s)
Date Pitot ID
Evidence of
damage?
Evidence of
mis-alignment?
Calibration or
Repair required?
6/12/24 P-807 no no no
Date Probe or
Thermocouple ID
Reference
Temp. (°F)
Indicated
Temp. (°F)Difference Criteria
6/12/24 P-807 70.0 70.0 0.0%
Date 06/12/24
Balance ID:5A2873330
Certified Weight ID:SLC-1KG-1
Certified Weight (g):1000.0
Measured Weight (g):999.8
Weight Difference (g):0.2--------
Date Barometric Pressure Evidence of
damage?Reading Verified Calibration or
Repair required?
6/12/24 Weather Station NA NA NA
6/12/24 MB 702
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 10
AST-2024-2320
VFR
± 1.5 % (absolute)
Field Balance Check
Pass
Weather Station Location
Richmond, UT
Date Meter Box ID Positive Pressure Leak Check
150 of 161
Document ID 620.004
Revision 24.0
Effective Date 1/31/24
Issuing Department Page 1 of 1
Console ID:
Meter S/N:
Critical Orifice S/N:
(PbI)
(PbF)
(Pb)
(Y)SH-73 SH-73 SH-63 SH-63 SH-55 SH-55
(K')0.7864 0.7864 0.6007 0.601 0.4524 0.452
(VP)11.0 11.0 14.0 14.0 15.5 15.5
Initial DGM Volume, ft3 (VmI)655.700 685.400 714.800 734.700 765.400 783.400
Final DGM Volume, ft3 (VmF)681.015 710.623 734.195 758.011 783.018 812.805
Total DGM Volume, ft3 (Vm)25.315 25.223 19.395 23.311 17.618 29.405
Ambient Temperature, °F (Ta)68 67 69 70 71 71
Initial DGM Temperature, °F (TmI)68 67 69 70 71 71
Final DGM Temperature, °F (TmF)70 68 70 71 71 71
Average DGM Temperature, °F ( Tm)69 68 70 71 71 71
Elapsed Time (Θ)25.00 25.00 25.00 30.00 30.00 50.00
Meter Orifice Pressure, in. WC (ΔH)2.50 2.50 1.50 1.50 0.84 0.84
Standard Meter volume, ft3 (Vmstd)21.7825 21.7651 16.6253 19.9443 15.0309 25.0871
Standard Critical Orifice Volume, ft3 (Vcr)21.9139 21.9347 16.7233 20.0490 15.0851 25.1418
Meter Correction Factor (Y)1.006 1.008 1.006 1.005 1.004 1.002
Tolerance --0.001 0.003 0.001 0.000 0.002 0.003
Orifice Calibration Value (ΔH @)1.575 1.576 1.616 1.616 1.594 1.594
Tolerance --0.021 0.019 0.021 0.021 0.001 0.001
Orifice Cal Check --
Meter Correction Factor (Y)
Orifice Calibration Value (ΔH @)
Accuracy Absolute
Difference
oF oR oF oR %oF
0 460 0 460 0.0 0
68 528 66 526 0.4 2
100 560 98 558 0.4 2
223 683 223 683 0.0 0
248 708 248 708 0.0 0
273 733 273 733 0.0 0
300 760 300 760 0.0 0
400 860 398 858 0.2 2
500 960 497 957 0.3 3
600 1,060 599 1,059 0.1 1
700 1,160 701 1,161 -0.1 1
800 1,260 800 1,260 0.0 0
900 1,360 900 1,360 0.0 0
1,000 1,460 1,000 1,460 0.0 0
1,100 1,560 1,100 1,560 0.0 0
1,200 1,660 1,200 1,660 0.0 0
Calibration Date:
Yes
0.40 0.27 0.40
DGM Calibration-Orifices
Tech Services
25.60
25.61
25.61
K' Factor, ft3·R1/2 / in. WC·min
Piecal 520B
Vacuum Pressure, in. Hg
Initial Barometric Pressure, in. Hg
Final Barometric Pressure, in. Hg
Average Barometric Pressure, in. Hg
Critifcal Orifice ID
Calibration Detail
MB-702
805126
SH 40-73
Positive Pressure Leak Check
Equipment Detail - Dry Gas Meter
1.005
1.595
Personnel
Reference Calibrator Make:
Reference Calibrator Model:
Reference Calibrator S/N:
Calibration Detail
Equipment Detail - Thermocouple Sensor
Reference Temp.Display Temp.
Practical Instrument Electronics
887216
Charles HortonReviewed By:
Xander Gray KrahnCalibration By:
5/9/2024
151 of 161
Location
Source(s)
Project No.
Date(s)
Ethylene Cylinder ID
Concentration (ppmv)
Instrument Outlet
CTS 1 104.13 CTS 7 104.08 AVERAGE 104.05 Greatest Deviation from average
CTS 2 105.15 CTS 8 103.90 MAX 105.15 1.06%
CTS 3 103.31 CTS 9 103.43 deviation 1.10
CTS 4 104.88 CTS 10 -- MIN 103.11 Agreement with Assumed Pathlength
CTS 5 103.11 CTS 11 -- deviation 0.94 96.35%
CTS 6 104.49 CTS 12 --within 5% no correction required
CTS 1 CTS 7
Date Time File Temperature (CPressure Ethylene Date Time File Temperature (CPressure Ethylene
6/11/24 9:30:15 MKS 14 DYNO 2024_000745.LAB 192.1 0.923 104.28 6/12/24 16:53:14 MKS 14 DYNO 2024_001497.LAB 191.8 1.317 103.76
6/11/24 9:31:17 MKS 14 DYNO 2024_000746.LAB 192.1 0.926 104.11 6/12/24 16:54:17 MKS 14 DYNO 2024_001498.LAB 191.8 1.317 104.34
6/11/24 9:32:20 MKS 14 DYNO 2024_000747.LAB 192.1 0.927 104.00 6/12/24 16:55:19 MKS 14 DYNO 2024_001499.LAB 191.8 1.317 104.15
CTS 2 CTS 8
Date Time File Temperature (CPressure Ethylene Date Time File Temperature (CPressure Ethylene
6/11/24 11:46:52 MKS 14 DYNO 2024_000874.LAB 192.1 1.317 105.17 6/12/24 18:22:36 MKS 14 DYNO 2024_001581.LAB 191.8 1.316 103.61
6/11/24 11:47:54 MKS 14 DYNO 2024_000875.LAB 192.1 1.317 105.22 6/12/24 18:23:39 MKS 14 DYNO 2024_001582.LAB 191.8 1.317 103.86
6/11/24 11:48:57 MKS 14 DYNO 2024_000876.LAB 192.1 1.317 105.08 6/12/24 18:24:42 MKS 14 DYNO 2024_001583.LAB 191.8 1.317 104.24
CTS 3 CTS 9
Date Time File Temperature (CPressure Ethylene Date Time File Temperature (CPressure Ethylene
6/12/24 8:40:03 MKS 14 DYNO 2024_001032.LAB 192.2 1.272 103.11 6/12/24 19:52:16 MKS 14 DYNO 2024_001665.LAB 192.0 0.883 103.10
6/12/24 8:41:05 MKS 14 DYNO 2024_001033.LAB 192.2 1.272 103.40 6/12/24 19:53:19 MKS 14 DYNO 2024_001666.LAB 192.0 0.871 103.72
6/12/24 8:42:08 MKS 14 DYNO 2024_001034.LAB 192.2 1.272 103.42 6/12/24 19:54:22 MKS 14 DYNO 2024_001667.LAB 192.0 0.871 103.46
CTS 4 CTS 10
Date Time File Temperature (CPressure Ethylene Date Time File Temperature (CPressure Ethylene
6/12/24 10:31:29 MKS 14 DYNO 2024_001136.LAB 192.1 1.317 104.72
6/12/24 10:32:32 MKS 14 DYNO 2024_001137.LAB 192.1 1.317 104.83
6/12/24 10:33:35 MKS 14 DYNO 2024_001138.LAB 192.1 1.317 105.08
CTS 5 CTS 11
Date Time File Temperature (CPressure Ethylene Date Time File Temperature (CPressure Ethylene
6/12/24 12:30:06 MKS 14 DYNO 2024_001248.LAB 192.0 1.303 103.08
6/12/24 12:31:09 MKS 14 DYNO 2024_001249.LAB 192.0 1.303 103.02
6/12/24 12:32:11 MKS 14 DYNO 2024_001250.LAB 192.0 1.303 103.23
CTS 6 CTS 12
Date Time File Temperature (CPressure Ethylene Date Time File Temperature (CPressure Ethylene
6/12/24 14:10:49 MKS 14 DYNO 2024_001343.LAB 192.0 1.317 104.53
6/12/24 14:11:52 MKS 14 DYNO 2024_001344.LAB 192.0 1.317 104.35
6/12/24 14:12:54 MKS 14 DYNO 2024_001345.LAB 192.0 1.317 104.58
MKS 14 (Serial #184146639)
Pepperidge Farm, Richmond, UT
Unit 3
AST-2024-2320
6/11/2024
108.0
EB0049666
152 of 161
This is to certify the gases referenced have been calibrated/tested, and verified to meet the defined specifications. This
calibration/test was performed using Gases or Scales that are traceable through National Institute of Standards and
Technology (NIST) to the International System of Units (SI). The basis of compliance stated is a comparison of the
measurement parameters to the specified or required calibration/testing process. The expanded uncertainties use a
coverage factor of k=2 to approximate the 95% confidence level of the measurement, unless otherwise noted. This
calibration certificate applies only to the item described and shall not be reproduced other than in full, without written approval
from Red Ball Technical Gas Services. If not included, the uncertainty of calibrations are available upon request and were
taken into account when determining pass or fail.
Timothy Davis
Analytical Chemist
Assay Laboratory: Red Ball TGS
Version 02-G, Revised on 2017-07-02
MPC Date
C2H4 FTIR MKS MKS 2031DJG2EKVS13T 017146467
Analytical Instrumentation SMART-CERT
Component Principle Make Model Serial
1005 PPM 2 4034426CC734580CC73458007/26/2024 PS N2 C2H4
Reference Standard(s)
Serial Number Lot Expiration Type Balance Component Concentration Uncertainty(%)NIST Reference
Nitrogen
Analytical Measurement Data Available Online.
Balance
Ethylene
Certified Concentration(s)
Component Concentration Uncertainty Analytical Principle
108 PPM ± 2% NIST FTIR
Customer:Previous Certification Dates:
Do Not Use This Cylinder Below 100 psig (0.7 Megapascal).
This mixture is for laboratory use only, not for drug, household or other use.
This mixture is certified in Mole % to be within ±2% of the actual number reported with a confidence of 95%.
This mixture was manufactured by scale; weights traceable to N.I.S.T. Certificate #822/266926-02.
COA #EB0049666.20240219-0 Lot Number:EB0049666.20240219
Customer PO. NO.:Tracking Number:073562373
Product ID Number:124838 Expiration Date:02/20/2032
Cylinder Pressure:1900 PSIG MFG Facility: - Shreveport - LA
CERTIFIED GAS CERTIFICATE OF ANALYSIS
Cylinder Number:EB0049666 Certification Date:02/22/2024
Red Ball Technical Gas Service
555 Craig Kennedy Way
Shreveport, LA 71107
800-551-8150
Accreditation #62754 PGVP Vendor ID # G12024
153 of 161
Location
Source
Project No.
Date
EB0038762 Component
93 Acetaldehyde
EB0038762 Component
4.57 SF6
Instrument ID Outlet
Direct Spike Values
Date Time File Temperature (C) Pressure Spike (ppm) Tracer (ppm)
06/11/24 9:53:15 MKS 14 DYNO 202 192.2 0.906 95.10 4.245
06/11/24 9:54:18 MKS 14 DYNO 202 192.2 0.913 94.14 4.202
06/11/24 9:55:20 MKS 14 DYNO 202 192.2 0.914 94.27 4.224
06/11/24 9:56:23 MKS 14 DYNO 202 192.2 0.914 93.91 4.370
06/11/24 9:57:26 MKS 14 DYNO 202 192.2 0.914 94.37 4.319
06/11/24 9:58:29 MKS 14 DYNO 202 192.2 0.914 93.66 4.263
06/11/24 9:59:31 MKS 14 DYNO 202 192.2 0.914 93.97 4.311
Average 94.20 4.276
Native Values
Date Time File Temperature (C) Pressure Spike (ppm) Tracer (ppm)
06/11/24 10:23:34 MKS 14 DYNO 202 192.2 1.179 1.63 0.010
06/11/24 10:24:37 MKS 14 DYNO 202 192.1 1.175 2.35 0.010
06/11/24 10:25:40 MKS 14 DYNO 202 192.1 1.000 1.89 0.010
06/11/24 10:26:43 MKS 14 DYNO 202 192.2 1.063 1.35 0.010
06/11/24 10:27:46 MKS 14 DYNO 202 192.2 0.876 1.51 0.010
06/11/24 10:28:48 MKS 14 DYNO 202 192.1 0.881 0.40 0.010
06/11/24 10:29:51 MKS 14 DYNO 202 192.1 1.030 0.84 0.010
Average 1.43 0.010
Spiked values
Date Time File Temperature (C) Pressure Spike (ppm) Tracer (ppm)
06/11/24 10:34:02 MKS 14 DYNO 202 192.1 1.168 5.01 0.175
06/11/24 10:35:05 MKS 14 DYNO 202 192.1 1.088 4.90 0.178
06/11/24 10:36:07 MKS 14 DYNO 202 192.2 1.081 4.04 0.170
06/11/24 10:37:10 MKS 14 DYNO 202 192.1 1.081 4.09 0.161
06/11/24 10:38:13 MKS 14 DYNO 202 192.1 1.059 4.54 0.183
06/11/24 10:39:16 MKS 14 DYNO 202 192.1 1.095 4.29 0.187
06/11/24 10:40:18 MKS 14 DYNO 202 192.1 1.097 4.52 0.166
Average 4.49 0.174
Dilution Factor
3.8%
Calculated Spike
4.99
Spike Recovery
89.89%
MKS 14 (Serial #184146639)
Tracer Cylinder ID
Tracer Gas concentration
Spike Gas concentration
Pepperidge Farm, Richmond, UT
Unit 3
AST-2024-2320
6/11/2024
Spike Cylinder ID
154 of 161
4.57 PPM ± 2% NIST FTIR
This is to certify the gases referenced have been calibrated/tested, and verified to meet the defined specifications. This
calibration/test was performed using Gases or Scales that are traceable through National Institute of Standards and
Technology (NIST) to the International System of Units (SI). The basis of compliance stated is a comparison of the
measurement parameters to the specified or required calibration/testing process. The expanded uncertainties use a
coverage factor of k=2 to approximate the 95% confidence level of the measurement, unless otherwise noted. This
calibration certificate applies only to the item described and shall not be reproduced other than in full, without written approval
from Red Ball Technical Gas Services. If not included, the uncertainty of calibrations are available upon request and were
taken into account when determining pass or fail.
Anthony Cyr
Assistant Operations Manager
Assay Laboratory: Red Ball TGS
Version 02-G, Revised on 2017-07-02
MKS MKS 2031DJG2EKVS13T 017146467
MPC Date
SF6 FTIR MKS MKS 2031DJG2EKVS13T 017146467
C2H4O FTIR
Analytical Instrumentation SMART-CERT
Component Principle Make Model Serial
2 4011772
9.97 PPM 5 4011772
CC742079 CC742079 07/27/2023 PS N2 C2H4O 98.1 PPM
CC518670 CC518670 07/27/2023 PS N2 SF6
Reference Standard(s)
Serial Number Lot Expiration Type Balance Component Concentration Uncertainty(%)NIST Reference
Nitrogen
Analytical Measurement Data Available Online.
Balance
Acetaldehyde
Sulfur Hexafluoride
Certified Concentration(s)
Component Concentration Uncertainty Analytical Principle
93.0 PPM ± 2% NIST FTIR
Customer:Previous Certification Dates:
Do Not Use This Cylinder Below 100 psig (0.7 Megapascal).
This mixture is for laboratory use only, not for drug, household or other use.
This mixture is certified in Mole % to be within ±2% of the actual number reported with a confidence of 95%.
This mixture was manufactured by scale; weights traceable to N.I.S.T. Certificate #822/266926-02.
COA #EB0038762.20230306-0 Lot Number:EB0038762.20230306
Customer PO. NO.:Tracking Number:065156566
Product ID Number:125303 Expiration Date:03/14/2025
Cylinder Pressure:1900 PSIG MFG Facility: - Shreveport - LA
CERTIFIED GAS CERTIFICATE OF ANALYSIS
Cylinder Number:EB0038762 Certification Date:03/15/2023
Red Ball Technical Gas Service
555 Craig Kennedy Way
Shreveport, LA 71107
800-551-8150
Accreditation #62754 PGVP Vendor ID # G12023
155 of 161
Location:
Source:
Project No.:
Date:
Time O2 CO2
(%) (%)
A-1 8:46 11.83 3.86
2 8:49 11.91 3.86
3 8:52 11.86 3.90
11.9 3.9
Single Point Single Point
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 3
AST-2024-2320
6/12/2024
Average
Criteria Met
Traverse Point
156 of 161
Location:
Source:
Project No.:
Date:
Time O2 CO2
(%) (%)
A-1 15:03 10.69 5.73
2 15:06 10.45 5.30
3 15:09 10.95 5.59
10.7 5.5
Single Point Single Point
Pepperidge Farm Incorporated - Richmond, UT
Process Line No. 10
AST-2024-2320
6/12/2024
Average
Criteria Met
Traverse Point
157 of 161

Appendix E

158 of 161
Time Production Rate (lbs/hr) Residence Time (minutes) Catalyst Inlet Temp (F) Catalyst Outlet Temp (F) Temp Rise Across Catalyst (F)
9:00 2971 2.52 626 775 149
9:15 2971 2.52 625 781 156
9:30 2971 2.52 626 781 155
9:45 2971 2.52 625 778 153
10:00 2962 2.62 624 777 153
11:10 2989 2.54 625 773 148
11:25 2989 2.54 624 772 148
11:40 2980 2.54 626 772 146
11:55 2989 2.54 625 766 141
12:10 2989 2.54 625 766 141
12:40 2989 2.56 624 767 143
12:55 2989 2.56 626 763 137
1:10 2989 2.56 627 763 136
1:25 2980 2.56 624 763 139
1:40 2989 2.56 624 761 137
Line 3 Oxidizer Data
15
9

of

16
1
Time Production Rate (lbs/hr) Residence Time (minutes) Catalyst Inlet Temp (F) Catalyst Outlet Temp (F) Temp Rise Across Catalyst (F)
15:25 8725 2.8 698 841 143
15:40 8725 2.8 704 841 137
15:55 8725 2.8 701 842 141
16:10 8725 2.8 701 837 136
16:25 8725 2.8 697 845 148
16:58 8725 2.8 699 839 140
17:13 8725 2.8 695 841 146
17:28 8725 2.8 697 847 150
17:43 8725 2.8 695 845 150
17:58 8725 2.8 703 857 154
18:30 8725 2.8 691 876 185
18:45 8725 2.8 709 875 166
19:00 8725 2.8 690 880 190
19:15 8725 2.8 710 878 168
19:30 8725 2.8 709 870 161
Line 10 Oxidizer Data
16
0

of

16
1
Last Page of Report
161 of 161
Pepperidge Farms RM 25 A VOC 2024 revb
Reference Methods 25 A & B
Compromis
Source Information
Company Name Pepperidge Farms Line 3
Company Contact:Jeancarlo Hale
Contact Phone No.435-750-8402
Point Source:Pepperidge Farms
Test & Review Dates
Test Date:6/12/2024 Tabs Are Shown
Review Date:9/25/2024
Observer:none
Reviewer:Robert Sirrine
Emission Limits Emission Rates
VOC VOC
350.0 86.25
1.50 0.49
%O2 Correction as a who
Test Information
Equivalent
Diameter (in.)Y Dl H @ Cp Pbar Pq (static)
Ps
Stack Pressure
17.5 1.0050 1.595 0.84 25.45 0.07 25.45
Contractor Information
Contact:Austin Keough
Contracting CompanyAlliance Source Testing
Address: 2855S 500 W Sutie A, Salt Lake City, Utah 84115
Phone No.: [phone] Btu/hr Selected
Project No.:
8710

Division of Air Quality
Instrumental Reference Methods - Gaseous Measurements
ppm
Method 19 - F factors for Coal, Oil, and Gas
Fd Fw Fc
dscf/MMBtu wscf/MMBtu scf/MMBtu
F factor used
O2
CO2
Anthracite 2
Bituminous 2
Lignite
Natural
Propane
Butane
10100
COAL
OIL
GAS
9780
9860
9190
8710
8710
8710
10540
10640
11950
320
10610
10200
10390
1970
1800
1910
1420
1040
1190
1250
Wet CEM
Correct For O2
Yes
Yes
State of Utah CalError Page 1
VOC K3
(Propane)O2
Span Value 1,700.00 Span Value 23.98
Units ppm Units %
Cylinder No.
Expiration
Date Cylinder Value: Response Difference CAL. ERROR Status Cylinder No.
Expiration
Date
Cylinder
Value:
Response Difference
CAL. ERROR Status
Zero Gas 0.00 4.09 4.09 0.24%Passed Cal.Zero Gas 0.00 0.00 0.00 0.00%Passed Cal.
Low-level Cal. Gas 700.00 696.88 3.12 0.18%Passed Cal.Mid-level Cal. Gas 12.00 11.95 0.05 0.21%Passed Cal.
Mid-level Cal. Gas 1,000.00 996.44 3.56 0.21%Passed Cal.High-level Cal. Gas 23.98 23.97 0.01 0.04%Passed Cal.
High-level Cal. Gas 1,700.00 1,697.41 2.59 0.15%Passed Cal.
<0.25% of span value Zero Gas 0.00%
<0.10% of span value Zero Gas 0.00%40 to 60% of span value Low-level Cal. Gas 50.0%
25 to 35% of span value Low-level Cal. Gas 41.18%80 to 100% of span value Mid-level Cal. Gas 100.00%
45 to 55% of span value Mid-level Cal. Gas 58.82%
80 to 90% of span value High-level Cal. Gas 100.00%
VOC K4
(Butane)CO2
Span Value Span Value 10
Units ppm Units %
Cylinder No.
Expiration
Date Cylinder Value: Response Difference CAL. ERROR Status Cylinder No.
Expiration
Date
Cylinder
Value:Response Difference CAL. ERROR Status
Zero Gas Zero Gas 0.000 0.000 0.00 0.00%Passed Cal.
Low-level Cal. Gas Mid-level Cal. Gas 5.000 5.040 0.04 0.40%Passed Cal.
Mid-level Cal. Gas High-level Cal. Gas 10.000 10.000 0.00 0.00% Passed Cal.
High-level Cal. Gas
<0.25% of span value Zero Gas 0.00%
<0.10% of span value Zero Gas 40 to 60% of span value Low-level Cal. Gas 50.0%
25 to 35% of span value Low-level Cal. Gas 80 to 100% of span value Mid-level Cal. Gas 100.00%
45 to 55% of span value Mid-level Cal. Gas
80 to 90% of span value High-level Cal. Gas
0.00
VOC K2 (Ethane)
0.00
Span Value 0.00
Units ppm
Cylinder No.
Expiration
Date Cylinder Value: Response Difference CAL. ERROR Status
Zero Gas
Low-level Cal. Gas
Mid-level Cal. Gas
High-level Cal. Gas
<0.10% of span value Zero Gas
25 to 35% of span value Low-level Cal. Gas
45 to 55% of span value Mid-level Cal. Gas
80 to 90% of span value High-level Cal. Gas
Page 1
Pepperidge Farms RM 25 A VOC 2024 revb
Division of Air Quality
NSPS Relative Accuracy Performance Specification Test - CEMS Certification
Pepperidge Farms Line 3
Pepperidge Farms
Average Emission
Dry
VOC
(Propane)
VOC
(Butane)
VOC
(Ethane)Average % concentration
lbs./hr. 0.49 CO2 O2
ppm 86.25 3.82 13.07
Run 1
Dry
VOC
(Propane)
VOC
(Butane)
VOC
(Ethane)
Molecular Weight 44.1 58.1 30.1
Qs dscf min 8.053E+02 CO2 O2
ppm 114.08 3.90 11.96
lbs/hr 0.6307 3.91 11.95
Run 2
Dry
VOC
(Propane)
VOC
(Butane)
VOC
(Ethane)
Molecular Weight 44.1 58.1 30.1
Qs dscf min 8.401E+02 CO2 O2
ppm 77.42 3.98 13.68
lbs/hr 0.45 4.02 13.72
Run 3
Dry
VOC
(Propane)
VOC
(Butane)
VOC
(Ethane)
Molecular Weight 44.1 58.1 30.1
Qs dscf min 8.370E+02 CO2 O2
ppm 67.26 3.59 13.60
lbs/hr 0.3865 3.60 13.71
Corrected Value
Raw Value
mg/Liter of gasoline
Corrected Value
Raw Value
Corrected Value
Raw Value
Wet CEM
Yes
Correct For O2
Yes
Pepperidge Farms RM 25 A VOC 2024 revb
Division of Air Quality Stack Test Review of
Pepperidge Farms Line 3
VOC K3
(Propane)
VOC K4
(Butane)
VOC K2
(Ethane)CO2 O2 Pepperidge Farms
CS Calibration Span 1700.00 10.00 23.98
Units ppm ppm ppm % %
CV - Cylinder Value: VOC VOC VOC
CO2 O2
Zero Gas 0.00 0.00 0.00
Low-Level 700.00 5.00 12.00
Mid-Level 1000.00 5.00 12.00
High-Level 1700.00 10.00 23.98
Zero Gas 0.00% 0.00% 0.00%
Low Level Cal Gas 41.18%
Mid leverl Cal. Gas 58.82% 50.00% 50.04%
High Level Cal. Gas 100.00% 100.00% 100.00%
Cdir - Enter Actual Up-scale Cylinder Value Used To Correct Emission Concentration.
CDir CMA 1000.00 5.00 12.00
Calibration Error Test
Cs - Measured Concentration VOC VOC VOC CO2 O2
Zero Gas 4.09 0.00 0.00
Low-Level 696.88 5.04 11.95
Mid-Level 996.44 5.04 11.95
High-Level 1697.41 10.00 23.97
Enter Up-scale Analyzer Response to be used during testing.
996.44 5.04 11.95
ABS Difference:
Zero Gas 4.09 0.00 0.00
Low level Cal. Gas 3.12
Mid level Cal. Gas 3.56 0.04 0.05
High level Cal. Gas 2.59 0.00 0.01
Pre-Test Sampling SystemDrift
Initial Values VOC VOC VOC CO2 O2
CO - Low-Level 4.09 0.01 0.00 System Bias.
SBi - Zero Drift 0.00% TRUE TRUE 0.10% 0.00%± 5% of Span
Difference 0 TRUE TRUE 0.01 0
Pass or Failed Invalid Run Passed Cal. Passed Cal. Passed Cal.
CM - Up-scale Gas 996.44 4.95 12.01
SBi - Up-Scale Drift 0.00% TRUE TRUE 0.90% 0.25%
Difference 0.00 TRUE TRUE 0.09 0.06
Pass or Failed Invalid Run Passed Cal. Passed Cal. Passed Cal.
Raw Test Data Time Start Stop
Test Date:6/12/2024 VOC VOC VOC VOC
(Propane) (Butane) (Ethane)CO2 O2 VOC
Enter THC= 814.01 3.91 11.95 VOC
CO2/O2
Post-Test System Drift =(Cs - Cdir)/CS x 100
Final Values VOC VOC VOC CO2 O2
CO - Low-Level 0.00 0.00 0.00 System Bias.
SBi - Zero Bias 0.24% TRUE TRUE 0.00% 0.00%± 5% of Span
Difference 4.1 TRUE TRUE 0.0 0.0
Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal.
CM - Up-scale Gas 1002.33 5.07 11.97
SBi - Up-Scale Bias 0.35% TRUE TRUE 0.30% 0.08%
Difference 5.9 TRUE TRUE 0.0 0.0
Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal.
Calibration Error % of Span - D=ABS(SBf - SBi)
Low-Level Cal Error 0.24% TRUE TRUE 0.10% 0.00% Drift
Difference 4.1 TRUE TRUE 0.0 0.0 3% of Span
Pass or Re-Calibrate Pass Pass Pass
Up-scale Cal. Error 0.35% TRUE TRUE 0.60% 0.17%
Difference 5.9 TRUE TRUE 0.1 0.0
Pass or Re-Calibrate Pass Pass Pass
<0.10% of the Span Value - O2 0 to 20%
25 to 35% of the Span Value
45 to 55% of the span value - O2 40% to 60%
80 to 90% of the span value - O2 100%
NOTE
These cells scans for the appropriate
CMA and Cir. gas after the Cm - Up-
scale gas is entered.
If this scan is incorrect change the
Cma and Cdir to the correct gas value.
Failed Bias Dialog
Failed Drift Dialog
CO Calibration Gas
Failed Bias Dialog
Pepperidge Farms RM 25 A VOC 2024 revb
Division of Air Quality Stack Test Review of
Pepperidge Farms Line 3
VOC K3
(Propane)
VOC K4
(Butane)
VOC K2
(Ethane)CO2 O2 Pepperidge Farms
CS Calibration Span 1700.00 10.00 23.98
Units ppm ppm ppm % % Unprotected
CV - Cylinder Value: VOC VOC VOC CO2 O2
Zero Gas 0.00 0.00 0.00
Low-Level 700.00 5.00 12.00
Mid-Level 1000.00 5.00 12.00
High-Level 1700.00 10.00 23.98
Zero Gas 0.00% 0.00% 0.00%
Low Level Cal Gas 41.18%
Mid leverl Cal. Gas 58.82% 50.00% 50.04%
High Level Cal. Gas 100.00% 100.00% 100.00%
Cdir - Enter Actual Up-scale Cylinder Value Used To Correct Emission Concentration.
CDir CMA 1000.00 5.00 12.00
Calibration Error Test
Cs - Measured Concentration VOC VOC VOC
CO2 O2
Zero Gas 4.09 0.00 0.00
Low-Level 696.88 5.04 11.95
Mid-Level 996.44 5.04 11.95
High-Level 1697.41 10.00 23.97
Enter Up-scale Analyzer Response to be used during testing.
996.44 5.04 11.95
ABS Difference:
Zero Gas 4.09 0.00 0.00
Low level Cal. Gas 3.12
Mid level Cal. Gas 3.56 0.04 0.05
High level Cal. Gas 2.59 0.00 0.01
Pre-Test Sampling SystemDrift
Initial Values VOC VOC VOC
CO2 O2
CO - Low-Level 0.00 0.00 0.00 System Bias.
SBi - Zero Drift 0.24% TRUE TRUE 0.00% 0.00%± 5% of Span
Difference 4.09 TRUE TRUE 0 0
Pass or Failed Invalid Run Passed Cal. Passed Cal. Passed Cal.
CM - Up-scale Gas 1002.33 5.07 11.97
SBi - Up-Scale Drift 0.35% TRUE TRUE 0.30% 0.08%
Difference 5.89 TRUE TRUE 0.03 0.02
Pass or Failed Invalid Run Passed Cal. Passed Cal. Passed Cal.
Raw Test Data Time Start Stop
Test Date:6/12/2024 VOC VOC VOC VOC
(Propane) (Butane) (Ethane)
CO2 O2 VOC
Enter THC= 716.25 4.02 13.72 VOC
CO2/O2
Post-Test System Drift =(Cs - Cdir)/CS x 100
Final Values VOC VOC VOC
CO2 O2
CO - Low-Level 0.00 0.00 0.02 System Bias.
SBi - Zero Bias 0.24% TRUE TRUE 0.00% 0.08%± 5% of Span
Difference 4.1 TRUE TRUE 0.0 0.0
Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal.
CM - Up-scale Gas 1001.51 5.02 12.11
SBi - Up-Scale Bias 0.30% TRUE TRUE 0.20% 0.67%
Difference 5.1 TRUE TRUE 0.0 0.2
Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal.
Calibration Error % of Span - D=ABS(SBf - SBi)
Low-Level Cal Error 0.00% TRUE TRUE 0.00% 0.08% Drift
Difference 0.0 TRUE TRUE 0.0 0.0 3% of Span
Pass or Re-Calibrate Pass Pass Pass
Up-scale Cal. Error 0.05% TRUE TRUE 0.10% 0.58%
Difference 0.8 TRUE TRUE 0.1 0.1
Pass or Re-Calibrate Pass Pass Pass
<0.10% of the Span Value - O2 0 to 20%
25 to 35% of the Span Value
45 to 55% of the span value - O2 40% to 60%
80 to 90% of the span value - O2 100%
Failed Bias Dialog
Failed Drift Dialog
Failed Bias Dialog
Pepperidge Farms RM 25 A VOC 2024 revb
Division of Air Quality Stack Test Review of
Pepperidge Farms Line 3
VOC K3
(Propane)
VOC K4
(Butane)
VOC K2
(Ethane)CO2 O2 Pepperidge Farms
CS Calibration Span 1700.00 10.00 23.98
Units ppm ppm ppm % % Unprotected
CV - Cylinder Value: VOC VOC VOC CO2 O2
Zero Gas 0.00 0.00 0.00
Low-Level 700.00 5.00 12.00
Mid-Level 1000.00 5.00 12.00
High-Level 1700.00 10.00 23.98
Zero Gas 0.00% 0.00% 0.00%
Low Level Cal Gas 41.18%
Mid leverl Cal. Gas 58.82% 50.00% 50.04%
High Level Cal. Gas 100.00% 100.00% 100.00%
Cdir - Enter Actual Up-scale Cylinder Value Used To Correct Emission Concentration.
CDir CMA 1000.00 5.00 12.00
Calibration Error Test
Cs - Measured Concentration VOC VOC VOC
CO2 O2
Zero Gas 4.09 0.00 0.00
Low-Level 696.88 5.04 11.95
Mid-Level 996.44 5.04 11.95
High-Level 1697.41 10.00 23.97
Enter Up-scale Analyzer Response to be used during testing.
996.44 5.04 11.95
ABS Difference:
Zero Gas 4.09 0.00 0.00
Low level Cal. Gas 3.12
Mid level Cal. Gas 3.56 0.04 0.05
High level Cal. Gas 2.59 0.00 0.01
Pre-Test Sampling SystemDrift
Initial Values VOC VOC VOC
CO2 O2
CO - Low-Level 0.00 0.00 0.02 System Bias.
SBi - Zero Drift 0.24% TRUE TRUE 0.00% 0.08%± 5% of Span
Difference 4.09 TRUE TRUE 0 0.02
Pass or Failed Invalid Run Passed Cal. Passed Cal. Passed Cal.
CM - Up-scale Gas 1001.51 5.02 12.11
SBi - Up-Scale Drift 0.30% TRUE TRUE 0.20% 0.67%
Difference 5.07 TRUE TRUE 0.02 0.16
Pass or Failed Invalid Run Passed Cal. Passed Cal. Passed Cal.
Raw Test Data Time Start Stop
Test Date:6/12/2024 VOC VOC VOC VOC
(Propane) (Butane) (Ethane)
CO2 O2 VOC
Enter THC= 683.58 3.60 13.71 VOC
CO2/O2
Post-Test System Drift =(Cs - Cdir)/CS x 100
Final Values VOC VOC VOC
CO2 O2
CO - Low-Level 0.00 0.00 0.13 System Bias.
SBi - Zero Bias 0.24% TRUE TRUE 0.00% 0.54%± 5% of Span
Difference 4.1 TRUE TRUE 0.0 0.1
Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal.
CM - Up-scale Gas 995.77 5.02 12.11
SBi - Up-Scale Bias 0.04% TRUE TRUE 0.20% 0.67%
Difference 0.7 TRUE TRUE 0.0 0.2
Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal.
Calibration Error % of Span - D=ABS(SBf - SBi)
Low-Level Cal Error 0.00% TRUE TRUE 0.00% 0.46% Drift
Difference 0.0 TRUE TRUE 0.0 0.1 3% of Span
Pass or Re-Calibrate Pass Pass Pass
Up-scale Cal. Error 0.26% TRUE TRUE 0.00% 0.00%
Difference 5.7 TRUE TRUE 0.0 0.0
Pass or Re-Calibrate Pass Pass Pass
<0.10% of the Span Value - O2 0 to 20%
25 to 35% of the Span Value
45 to 55% of the span value - O2 40% to 60%
80 to 90% of the span value - O2 100%
Failed Bias Dialog
Failed Drift Dialog
Failed Bias Dialog
Pepperidge Farms line 10 RM 25A VOC 2024 rev
Reference Methods 25 A & B
Compromis
Source Information
Company Name Pepperidge Farms Line 10
Company Contact:Jeancarlo Hale
Contact Phone No.435-750-8402
Point Source:Pepperidge Farms
Test & Review Dates
Test Date:6/12/2024 Tabs Are Shown
Review Date:9/30/2024
Observer:none
Reviewer:Robert Sirrine
Emission Limits
VOC
350.0 34.6
4.85 0.74
%O2 Correction as a who
Test Information
Equivalent
Diameter (in.)Y Dl H @ Cp Pq (static)
Ps
Stack Pressure
26.5 1.0050 1.595 0.84 0.02 25.45
Contractor Information
Contact:Austin Keough
Contracting CompanyAlliance Source Testing
Address: 2855S 500 W Sutie A, Salt Lake City, Utah 84115
Phone No.: [phone] Btu/hr Selected
Project No.:
8710

Division of Air Quality
Instrumental Reference Methods - Gaseous Measurements
ppm
Method 19 - F factors for Coal, Oil, and Gas
Fd Fw Fc
dscf/MMBtu wscf/MMBtu scf/MMBtu
F factor used
O2
CO2
Anthracite 2
Bituminous 2
Lignite
Natural
Propane
Butane
10100
COAL
OIL
GAS
9780
9860
9190
8710
8710
8710
10540
10640
11950
320
10610
10200
10390
1970
1800
1910
1420
1040
1190
1250
Wet
Corr
Y
Y
State of Utah CalError Page 1
VOC K3
(Propane)O2
Span Value 2,000.00 Span Value 23.98
Units ppm Units %
Cylinder No.
Expiration
Date Cylinder Value: Response Difference CAL. ERROR Status Cylinder No.
Expiration
Date
Cylinder
Value:
Response Difference
CAL. ERROR Status
Zero Gas 0.00 4.09 4.09 0.20%Passed Cal.Zero Gas 0.00 0.00 0.00 0.00%Passed Cal.
Low-level Cal. Gas 700.00 696.88 3.12 0.16%Passed Cal.Mid-level Cal. Gas 12.00 11.95 0.05 0.21%Passed Cal.
Mid-level Cal. Gas 1,000.00 996.44 3.56 0.18%Passed Cal.High-level Cal. Gas 23.98 23.97 0.01 0.04%Passed Cal.
High-level Cal. Gas 1,700.00 1,697.41 2.59 0.13%Passed Cal.
<0.25% of span value Zero Gas 0.00%
<0.10% of span value Zero Gas 0.00%40 to 60% of span value Low-level Cal. Gas 50.0%
25 to 35% of span value Low-level Cal. Gas 35.00%80 to 100% of span value Mid-level Cal. Gas 100.00%
45 to 55% of span value Mid-level Cal. Gas 50.00%
80 to 90% of span value High-level Cal. Gas 85.00%
VOC K4
(Butane)CO2
Span Value Span Value 10
Units ppm Units %
Cylinder No.
Expiration
Date Cylinder Value: Response Difference CAL. ERROR Status Cylinder No.
Expiration
Date
Cylinder
Value:Response Difference CAL. ERROR Status
Zero Gas Zero Gas 0.000 0.000 0.00 0.00%Passed Cal.
Low-level Cal. Gas Mid-level Cal. Gas 5.000 5.040 0.04 0.40%Passed Cal.
Mid-level Cal. Gas High-level Cal. Gas 10.000 10.000 0.00 0.00% Passed Cal.
High-level Cal. Gas
<0.25% of span value Zero Gas 0.00%
<0.10% of span value Zero Gas 40 to 60% of span value Low-level Cal. Gas 50.0%
25 to 35% of span value Low-level Cal. Gas 80 to 100% of span value Mid-level Cal. Gas 100.00%
45 to 55% of span value Mid-level Cal. Gas
80 to 90% of span value High-level Cal. Gas
0.00
VOC K2 (Ethane)
0.00
Span Value 0.00
Units ppm
Cylinder No.
Expiration
Date Cylinder Value: Response Difference CAL. ERROR Status
Zero Gas
Low-level Cal. Gas
Mid-level Cal. Gas
High-level Cal. Gas
<0.10% of span value Zero Gas
25 to 35% of span value Low-level Cal. Gas
45 to 55% of span value Mid-level Cal. Gas
80 to 90% of span value High-level Cal. Gas
Page 1
Pepperidge Farms line 10 RM 25A VOC 2024 rev
Division of Air Quality
NSPS Relative Accuracy Performance Specification Test - CEMS Certification
Pepperidge Farms Line 10
Pepperidge Farms
Average Emission
Dry
VOC
(Propane)
VOC
(Butane)
VOC
(Ethane)Average % concentration
lbs./hr. 0.74 CO2 O2
ppm 34.55 5.24 10.92
Run 1
Dry
VOC
(Propane)
VOC
(Butane)
VOC
(Ethane)
Molecular Weight 44.1 58.1 30.1
Qs dscf min 3.098E+03 CO2 O2
ppm 103.66 5.73 10.59
lbs/hr 2.21 5.72 10.64
Run 2
Dry
VOC
(Propane)
VOC
(Butane)
VOC
(Ethane)
Molecular Weight 44.1 58.1 30.1
Qs dscf min 3.082E+03 CO2 O2
ppm 0.00 5.18 11.57
lbs/hr 0.00 5.12 11.56
Run 3
Dry
VOC
(Propane)
VOC
(Butane)
VOC
(Ethane)
Molecular Weight 44.1 58.1 30.1
Qs dscf min 3.241E+03 CO2 O2
ppm 0.00 4.82 10.63
lbs/hr 0 4.73 10.60
Corrected Value
Raw Value
mg/Liter of gasoline
Corrected Value
Raw Value
Corrected Value
Raw Value
Wet CEM
Yes
Correct For O2
Yes
Pepperidge Farms line 10 RM 25A VOC 2024 rev
Division of Air Quality Stack Test Review of
Pepperidge Farms Line 10
VOC K3
(Propane)
VOC K4
(Butane)
VOC K2
(Ethane)CO2 O2 Pepperidge Farms
CS Calibration Span 2000.00 10.00 23.98
Units ppm ppm ppm % %
CV - Cylinder Value: VOC VOC VOC
CO2 O2
Zero Gas 0.00 0.00 0.00
Low-Level 700.00 5.00 12.00
Mid-Level 1000.00 5.00 12.00
High-Level 1700.00 10.00 23.98
Zero Gas 0.00% 0.00% 0.00%
Low Level Cal Gas 35.00%
Mid leverl Cal. Gas 50.00% 50.00% 50.04%
High Level Cal. Gas 85.00% 100.00% 100.00%
Cdir - Enter Actual Up-scale Cylinder Value Used To Correct Emission Concentration.
CDir CMA 1000.00 5.00 12.00
Calibration Error Test
Cs - Measured Concentration VOC VOC VOC CO2 O2
Zero Gas 4.09 0.00 0.00
Low-Level 696.88 5.04 11.95
Mid-Level 996.44 5.04 11.95
High-Level 1697.41 10.00 23.97
Enter Up-scale Analyzer Response to be used during testing.
996.44 5.04 11.95
ABS Difference:
Zero Gas 4.09 0.00 0.00
Low level Cal. Gas 3.12
Mid level Cal. Gas 3.56 0.04 0.05
High level Cal. Gas 2.59 0.00 0.01
Pre-Test Sampling SystemDrift
Initial Values VOC VOC VOC CO2 O2
CO - Low-Level 0.00 0.00 0.13 System Bias.
SBi - Zero Drift 0.20% TRUE TRUE 0.00% 0.54%± 5% of Span
Difference 4.09 TRUE TRUE 0 0.13
Pass or Failed Invalid Run Passed Cal. Passed Cal. Passed Cal.
CM - Up-scale Gas 995.77 5.02 12.11
SBi - Up-Scale Drift 0.03% TRUE TRUE 0.20% 0.67%
Difference 0.67 TRUE TRUE 0.02 0.16
Pass or Failed Invalid Run Passed Cal. Passed Cal. Passed Cal.
Raw Test Data Time Start Stop
Test Date:6/12/2024 VOC VOC VOC VOC
(Propane) (Butane) (Ethane)CO2 O2 VOC
Enter THC= 103.94 5.72 10.64 VOC
CO2/O2
Post-Test System Drift =(Cs - Cdir)/CS x 100
Final Values VOC VOC VOC CO2 O2
CO - Low-Level 0.00 0.00 0.01 System Bias.
SBi - Zero Bias 0.20% TRUE TRUE 0.00% 0.04%± 5% of Span
Difference 4.1 TRUE TRUE 0.0 0.0
Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal.
CM - Up-scale Gas 1009.57 4.97 11.98
SBi - Up-Scale Bias 0.66% TRUE TRUE 0.70% 0.13%
Difference 13.1 TRUE TRUE 0.1 0.0
Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal.
Calibration Error % of Span - D=ABS(SBf - SBi)
Low-Level Cal Error 0.00% TRUE TRUE 0.00% 0.50% Drift
Difference 0.0 TRUE TRUE 0.0 0.1 3% of Span
Pass or Re-Calibrate Pass Pass Pass
Up-scale Cal. Error 0.62% TRUE TRUE 0.50% 0.54%
Difference 13.8 TRUE TRUE 0.0 0.1
Pass or Re-Calibrate Pass Pass Pass
<0.10% of the Span Value - O2 0 to 20%
25 to 35% of the Span Value
45 to 55% of the span value - O2 40% to 60%
80 to 90% of the span value - O2 100%
NOTE
These cells scans for the appropriate
CMA and Cir. gas after the Cm - Up-
scale gas is entered.
If this scan is incorrect change the
Cma and Cdir to the correct gas value.
Failed Bias Dialog
Failed Drift Dialog
CO Calibration Gas
Failed Bias Dialog
Pepperidge Farms line 10 RM 25A VOC 2024 rev
Division of Air Quality Stack Test Review of
Pepperidge Farms Line 10
VOC K3
(Propane)
VOC K4
(Butane)
VOC K2
(Ethane)CO2 O2 Pepperidge Farms
CS Calibration Span 2000.00 10.00 23.98
Units ppm ppm ppm % % Unprotected
CV - Cylinder Value: VOC VOC VOC CO2 O2
Zero Gas 0.00 0.00 0.00
Low-Level 700.00 5.00 12.00
Mid-Level 1000.00 5.00 12.00
High-Level 1700.00 10.00 23.98
Zero Gas 0.00% 0.00% 0.00%
Low Level Cal Gas 35.00%
Mid leverl Cal. Gas 50.00% 50.00% 50.04%
High Level Cal. Gas 85.00% 100.00% 100.00%
Cdir - Enter Actual Up-scale Cylinder Value Used To Correct Emission Concentration.
CDir CMA 1000.00 5.00 12.00
Calibration Error Test
Cs - Measured Concentration VOC VOC VOC
CO2 O2
Zero Gas 4.09 0.00 0.00
Low-Level 696.88 5.04 11.95
Mid-Level 996.44 5.04 11.95
High-Level 1697.41 10.00 23.97
Enter Up-scale Analyzer Response to be used during testing.
996.44 5.04 11.95
ABS Difference:
Zero Gas 4.09 0.00 0.00
Low level Cal. Gas 3.12
Mid level Cal. Gas 3.56 0.04 0.05
High level Cal. Gas 2.59 0.00 0.01
Pre-Test Sampling SystemDrift
Initial Values VOC VOC VOC
CO2 O2
CO - Low-Level 0.00 0.00 0.01 System Bias.
SBi - Zero Drift 0.20% TRUE TRUE 0.00% 0.04%± 5% of Span
Difference 4.09 TRUE TRUE 0 0.01
Pass or Failed Invalid Run Passed Cal. Passed Cal. Passed Cal.
CM - Up-scale Gas 1009.57 4.97 11.98
SBi - Up-Scale Drift 0.66% TRUE TRUE 0.70% 0.13%
Difference 13.13 TRUE TRUE 0.07 0.03
Pass or Failed Invalid Run Passed Cal. Passed Cal. Passed Cal.
Raw Test Data Time Start Stop
Test Date:6/12/2024 VOC VOC VOC VOC
(Propane) (Butane) (Ethane)
CO2 O2 VOC
Enter THC= 0.00 5.12 11.56 VOC
CO2/O2
Post-Test System Drift =(Cs - Cdir)/CS x 100
Final Values VOC VOC VOC
CO2 O2
CO - Low-Level 0.00 0.00 0.00 System Bias.
SBi - Zero Bias 0.20% TRUE TRUE 0.00% 0.00%± 5% of Span
Difference 4.1 TRUE TRUE 0.0 0.0
Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal.
CM - Up-scale Gas 1002.09 4.91 12.00
SBi - Up-Scale Bias 0.28% TRUE TRUE 1.30% 0.21%
Difference 5.6 TRUE TRUE 0.1 0.1
Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal.
Calibration Error % of Span - D=ABS(SBf - SBi)
Low-Level Cal Error 0.00% TRUE TRUE 0.00% 0.04% Drift
Difference 0.0 TRUE TRUE 0.0 0.0 3% of Span
Pass or Re-Calibrate Pass Pass Pass
Up-scale Cal. Error 0.37% TRUE TRUE 0.60% 0.08%
Difference 7.5 TRUE TRUE 0.1 0.0
Pass or Re-Calibrate Pass Pass Pass
<0.10% of the Span Value - O2 0 to 20%
25 to 35% of the Span Value
45 to 55% of the span value - O2 40% to 60%
80 to 90% of the span value - O2 100%
Failed Bias Dialog
Failed Drift Dialog
Failed Bias Dialog
Pepperidge Farms line 10 RM 25A VOC 2024 rev
Division of Air Quality Stack Test Review of
Pepperidge Farms Line 10
VOC K3
(Propane)
VOC K4
(Butane)
VOC K2
(Ethane)CO2 O2 Pepperidge Farms
CS Calibration Span 2000.00 10.00 23.98
Units ppm ppm ppm % % Unprotected
CV - Cylinder Value: VOC VOC VOC CO2 O2
Zero Gas 0.00 0.00 0.00
Low-Level 700.00 5.00 12.00
Mid-Level 1000.00 5.00 12.00
High-Level 1700.00 10.00 23.98
Zero Gas 0.00% 0.00% 0.00%
Low Level Cal Gas 35.00%
Mid leverl Cal. Gas 50.00% 50.00% 50.04%
High Level Cal. Gas 85.00% 100.00% 100.00%
Cdir - Enter Actual Up-scale Cylinder Value Used To Correct Emission Concentration.
CDir CMA 1000.00 5.00 12.00
Calibration Error Test
Cs - Measured Concentration VOC VOC VOC
CO2 O2
Zero Gas 4.09 0.00 0.00
Low-Level 696.88 5.04 11.95
Mid-Level 996.44 5.04 11.95
High-Level 1697.41 10.00 23.97
Enter Up-scale Analyzer Response to be used during testing.
996.44 5.04 11.95
ABS Difference:
Zero Gas 4.09 0.00 0.00
Low level Cal. Gas 3.12
Mid level Cal. Gas 3.56 0.04 0.05
High level Cal. Gas 2.59 0.00 0.01
Pre-Test Sampling SystemDrift
Initial Values VOC VOC VOC
CO2 O2
CO - Low-Level 0.00 0.00 0.00 System Bias.
SBi - Zero Drift 0.20% TRUE TRUE 0.00% 0.00%± 5% of Span
Difference 4.09 TRUE TRUE 0 0
Pass or Failed Invalid Run Passed Cal. Passed Cal. Passed Cal.
CM - Up-scale Gas 1002.09 4.91 12.00
SBi - Up-Scale Drift 0.28% TRUE TRUE 1.30% 0.21%
Difference 5.65 TRUE TRUE 0.13 0.05
Pass or Failed Invalid Run Passed Cal. Passed Cal. Passed Cal.
Raw Test Data Time Start Stop
Test Date:6/12/2024 VOC VOC VOC VOC
(Propane) (Butane) (Ethane)
CO2 O2 VOC
Enter THC= 0.00 4.73 10.60 VOC
CO2/O2
Post-Test System Drift =(Cs - Cdir)/CS x 100
Final Values VOC VOC VOC
CO2 O2
CO - Low-Level 0.00 0.00 0.00 System Bias.
SBi - Zero Bias 0.20% TRUE TRUE 0.00% 0.00%± 5% of Span
Difference 4.1 TRUE TRUE 0.0 0.0
Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal.
CM - Up-scale Gas 993.64 4.91 11.94
SBi - Up-Scale Bias 0.14% TRUE TRUE 1.30% 0.04%
Difference 2.8 TRUE TRUE 0.1 0.0
Pass or Invalid Run Passed Cal. Passed Cal. Passed Cal.
Calibration Error % of Span - D=ABS(SBf - SBi)
Low-Level Cal Error 0.00% TRUE TRUE 0.00% 0.00% Drift
Difference 0.0 TRUE TRUE 0.0 0.0 3% of Span
Pass or Re-Calibrate Pass Pass Pass
Up-scale Cal. Error 0.14% TRUE TRUE 0.00% 0.17%
Difference 8.5 TRUE TRUE 0.0 0.1
Pass or Re-Calibrate Pass Pass Pass
<0.10% of the Span Value - O2 0 to 20%
25 to 35% of the Span Value
45 to 55% of the span value - O2 40% to 60%
80 to 90% of the span value - O2 100%
Failed Bias Dialog
Failed Drift Dialog
Failed Bias Dialog