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Home My WebLink AboutDAQ-2024-0108841 DAQC-1025-24 Site ID 10096 (B5) MEMORANDUM TO: CEM FILE – SUNNYSIDE COGENERATION ASSOCIATES THROUGH: Harold Burge, Major Source Compliance Section Manager FROM: Rob Leishman, Environmental Scientist DATE: October 7, 2024 SUBJECT: Source: Unit 1 – Fluidized Bed Combustion Boiler Contact: Rusty Netz – 435-888-4476x107 Location: East Carbon, Carbon County, UT Test Contractor: Montrose Air Quality Services FRS ID#: UT00000049000700030 Permit/AO#: Title V operating permit 700030005 dated March 8, 2023 Subject: Review of NOX and SO2 RA/PST and CO Performance test Report dated June 24, 2024 On June 26, 2024, Utah Division of Air Quality (DAQ) received a Relative Accuracy/Performance Specification Test (RA/PST) report for the Sunnyside Unit 1 in East Carbon, Utah. Testing was performed on May 23, 2024, to determine the relative accuracy of the O2, CO2, NOX, and SO2 monitoring systems. A performance test was done concurrently to demonstrate compliance with the CO emission limits listed in the Title V operating permit. The DAQ-calculated test results are: PERFORMANCE TEST EVALUATION: Source Test Date Test Method Pollutant Result Limit Unit #1 5/23/2024 RM10 CO 0.013 lb/MMBtu 0.085 lb/MMBtu RA/PST EVALUATION: Unit No. 1 NSPS RATA - Test Date - 5/23/2024 Primary Channel Manufacturer Serial No. Units CEM Value RM Value Relative Accuracy Status SO2 Eco Chem - MC3 425 ppm 82.544 86.884 3.3% Passed lbs/MMBtu 0.190 0.190 1.2% Passed lbs/hr 117.689 141.810 6.3% Passed CO2 % 13.930 14.060 1.5% Passed NOx Eco Chem - MC3 425 ppm 166.833 165.820 0.8% Passed lbs/MMBtu 0.271 0.254 7.5% Passed O2 Eco Chem - MC3 425 % 5.880 5.660 4.7% Passed Volumetric Flow Rate scfm 174601.022 178600.422 2.5% Passed Stack Test Deviation Report There were no deviations observed during testing. Calibration gases were in date and met performance specifications. 1 8 2 2 DEVIATIONS: No deviations were noted in this report. CONCLUSION: Sunnyside Cogeneration Associates operates the continuous emissions monitor (CEM) systems on the Unit 1 stack to measure O2, CO2, NOX, and SO2 emissions. The CEM was audited by the DAQ and found to meet quality assurance requirements found in 40 CFR Part 60, Appendix B, Performance Specification 1, and R307-170, Continuous Emission Monitoring System Program. Quarterly cylinder gas audits and an annual relative accuracy test audit were conducted in accordance with the procedures outlined in UAC R307-170. Sunnyside Cogeneration Associates also demonstrated compliance with the CO emission limits listed in the Title V operating permit. RECOMMENDATION: The Sunnyside Cogeneration Associates Unit 1 CEM system was operating as required in R307-170 and 40 CFR 60.13 at the time of this evaluation. HPV: No. ATTACHMENTS: RATA Review Spreadsheets. Sunnyside Cogeneration Associates P.O. Box l-59 . Sunnyside, Utah 84539 . (435) 888-4476 . Fax (435) 888-2538 I:une 24,2024 UTAH DEPABTMENT OF EWIRONMENTAL OUAUTY Rob Leishman Division of Air Quality 195 North 1950 West Salt Lake city, Lltah 84116 Re: Sunnyside Cogeneration Associates (SCA) JUN 2 6 ?1,?4 DlvlsloN oF AIR QUA!-l-r' Relative Accuracy Test Audit (RATA) CO Compliance'l'ests Title V Permit Number # 700030005 Dear Mr. Leishman: 'l'he following reports summarize tlie results fronr the CEM RAT.A and CO compliance tests conducted at the SCA facility on lvlay 23,2024. The rersi:lis are used to determine complianoe with the facilifz's Air permit. The testing procedul'es adhered to all applicable EP;\ Methods. Division Policies. Utah Air Corrservation Rules, and nrethods approved by the Executi'r,: Secretary. I acknowledge under penalties ol'law that all informatiotr contained in the year 2024, CEIvI RAI A and CO test reports, to the best of my knowledge. is truthful and accurate, and is r'r complete record of all monitoring related events vrhich occurred ciuring the compliance tests. If you have an-l questions or if furtlrer clarification is lrcccierl, please contact RusW Netz or myself at (435) 888-4476. 'ihanl,^ You. 4r.*l /4q4,> Edlvard McCourt Agent for Sunnyside Cogeneratirin Associates Rusty Netz Plant File Source Test Repoft for 2O24 RATA Testing Relative Accuracy Test Audits and Compliance Testing Unit EU#1 Sunnyside Cogeneration Associates Sunnyside, Utah Prepared For: Sunnyside Cogeneration Associates 1 Power Plant Road Sunnyside, Utah 84539 Prepared By: Montrose Air Quality Services, LLC 6823 South 3600 West Spanish Fork, Utah 84660 For Submission To: Utah Division of Air Quality 195 North 1950 West Salt Lake City, Utah 84116 Docu ment N um ber: GPOS 1AS-O4 I 7 57 -RT -1600 Test Date: May 23, 2024 Submitta! Date: June 7, 2024 E[txo&d.vCatr.nlorM MgNT+PIT srAe Review and Ceftification All work, calculations, and other activities and tasks performed and presented in this document were carried out by me or under my direction and supervision. I hereby certify that, to the best of my knowledge, Montrose operated in conformance with the requirements of the Montrose Quality Management System and ASTM D7035-04 during this test project. Signature z ---V Date:June 7, 2O24 Name: Cheyney Guymon Title:Project Manager I have reviewed, technically and editorially, details, calculations, results, conclusions, and other appropriate written materials contained herein. I hereby certify that, to the best of my knowledge, the presented material is authentic, accurate, and conforms to the requirements of the Montrose Quality Management System and ASTM D7036-04. T I t I I I I I I I t I I I T I I t t Signature= /)l*A A....*.L Name: Joby Dunmire June7,2024 QA/QC Specialist 2 of 22O GP08 1AS-04 17s7-RT- 1600 ) I I I Table of Contents I Section Paoe I 1.0 Introduction........ .....................5 1.1 Summary of Test Program .............5 L.2 Key Personnel......... .....................7 2.0 Plant and Sampling Location Descriptions.............. ..................9 2.7 Process Description, Operation, and Control Equipment.............. .......9 2.2 Flue Gas Sampling Locations.. ........9 2.3 Operating Conditions and Process Data ..............9 3.0 Sampling and Analytical Procedures ............10 3.1 Test Methods..,......... ...................10 3.1.1 EPA Method 2.............. ......10 3.1.2 EPA Method 4............ ........12 3.1.4 EPA Methods 3A, 6C, 7E, and 10............ ..............74 3.2 Process Test Methods............ ......16 4.0 Test Discussion and Resu1ts.............. .....16 4.1 Field Test Deviations and Exceptions.......... ...................16 4.2 Presentation of Resu1ts..........,... ........16 5.0 Internal QA/QC Activities ......L7 5.1 QA/QC Audits....... .,....L7 5.2 QA/QC Discussion .......L7 5.3 Quality Statement ......L7 List of Appendices A Field Data and Calculations ........ ........18 A.1 Sampling Location ......19 A.2 RATA Results ............ .................21 I I I I I I I I I A.2.1 Unit 1.,............ .................22 A.3 Unit 1 Field Data ..............32 A.3.1 Flow Data .,...... .................33 A.3.2 InstrumentalTest Method Data......... ...................56 A.4 Example Calculations............. ......59 Facility Process Data......... .................81 B.1 Unit 1 .......82 Quality Assurance/Quality Control .....105 C.1 Units and Abbreviations........... ................. 105 C.2 ManualTest Method QA/QC Data......... ....... 114 C.3 Instrumental Test Method QA/QC Data......... .............. L27 I I I I I 3 of 22O GP08 1AS-041757-RT- 1600 C.4 Calibration Gas Ceftificates......... ..............206 C.5 Accreditation Information/Certiflcations..... .................216 List of Tables Table 1-1 Summary of Test Program ............ ...............5 Table 1-2 Summary of RATA Results - Sunnyside Unit 1............. ...................5 Table 1-3 Summary of Emission Limits ..,,.,,,7 Table 1-4 Test Personnel and Observers........... ............8 Table 2-1 Sampling Locations............ .........9 List of Figures Figure 3-1 EPA Method 2 Sampling Train ....... .............11 Figure 3-2 EPA Method 4 Sampling Train........ .....,.......13 Figure 3-3 EPA Methods 3A, 6C, 7E, and 10 Sampling Train...... .....15 4 of 22O GP08 1AS-041757-RT- 1600 I I I I I I I I I I I I I I I I I I T 1,O Introduction 1,1 Summary of Test Program Sunnyside Cogeneration Associates contracted Montrose Air Quality Seruices, LLC (Montrose) to perform a testing program at Sunnyside Power Plant located near Sunnyside, Utah. Testing was conducted in accordance with the testing requirements of Utah Department of Environmental Quality (UDEQ) Operating Permit 700030002 and (as applicabte) 40 CFR Parts 60 and 75. The specific objectives were to: . Perform annual Relative Accuracy Test Audits (MTAs) on the Continuous Emission Monitoring Systems (CEMS) installed on Unit EU#1 . Peform annual carbon monoxide (CO) compliance testing on the exhaust stack of Unit EU#1 . Conduct the test program with a focus on safety Montrose peformed the tests to measure the emission parameters listed in Table 1-1. Table 1-1 Summary of Test Program To simplify this repoft, a list of Units and Abbreviations is included in Appendix C.1. Throughout this report, chemical nomenclature, acronyms, and reporting units are not defined. Please refer to the list for specific details. 5 ot 220 GP08 1AS-041757-RT- 1600 This repoft presents the test results and supporting data, descriptions of the testing procedures, descriptions of the facility and sampling locations, and a summary of the quality assurance procedures used by Montrose. The average emission test results are summarized and compared to their respective performance specifications in Table 1-2. Detailed results for individual test runs and all supporting data can be found in the appendices. The testing was conducted by the Montrose personnel listed in Table 1-3. The tests were conducted according to the test plan (protocol) that was submitted to and approved by UDEQ. Table 1-2 Summary of RATA Results - Sunnyside Unit 1, May 23,2024 Part 5O Volumetric Flow dscfh App. B Sect. 2.3.1.2 Annual: S 7.5olo of RM L.4o/o Oxygen (Or) o/o volume dry App. B Sect. 2.3.1.2 Annual: *. O.7o/o Oz O.2oh Oz Garbon Dloxlde (COz) o/o volume dry App. B Sect. 2.3.1.2 Annual: *, O.7o/o COz O.196 COz Sulfur Dioxide (SOz) ppmvd App. B Sect. 2.3.1.2 Annual: + 12 ppm SOz 5.2 ppm SOz lblmmBtu PS-2 3 20.0olo of RM 3.3%, lb/hr PS-6 S 20.0olo of RM 8.3o,h Nitrogen Oxides (NOx as NOz) ppmvd PS-2 3 20.0olo of RM O.89/o Part 75 Nitrogen Oxides (NOx as NOz) lblmmBtu App. B Sect. 2.3.1.2 Annual: < 7.5olo of RM 7.30/b I I I I I T T I I I I I I I I T I I I6 of 22O GP08 1AS-041 757-RT- 1600 I I I I I I I I I I I I I I I I I I The applicable permit limits are presented in Table 1-3. Table 1-3 Summary of Emlssion Limits L.2 Key Personnel A list of project participants is included below: Facility Information Source Location:Sunnyside Cogeneration Associates Sunnyside Power Plant 1 Power Plant Road Sunnyside, Utah 84539 Rusty Netz Environmental Advisor Su nnyside Cogeneration Associates (43s) 888-4476x107 rusnetz@hotmail.com Utah Depaftment of Air Quality Rob Leishman (801) s36-4438 Rleishman@utah.gov Project Contact: Role: Company: Telephone: Email: Agency fnformation Regulatory Agency: Agency Contact: Telephone: Email: Testing Company Information Testing Firm: Montrose Air Quality Services, LLC Contact: CheyneyGuymon Title: Client Project Manager Telephone: (801)645-2353 Email: ChGuymon@montrose-env.com GP08 1AS-041757- RT- 1600 Test personnel and observers are summarized in Table 1-4. Table 1-4 Test Personnel and Obserwers Project Manager Qualified Individual (QI) Trailer operator Sample train operator Calculations and report preparation GP08 1AS-041757-RT-1600 t I I T 2.O Plant and Sampling Location Descriptions 2.L Process Description, Operation, and Control I Equipment The Sunnyside Cogeneration Facility is a steam-electric generating power plant located in Sunnyside, Carbon County, Utah. The plant consists of a circulating fluidized bed (CFB) combustion boiler designated EU #1, an emergency backup diesel-fired pump, diesel storage tanks, coal handling equipment, ash handling equipment and limestone handling equipment. EU #1 has a rating of 7OO MMBtu/hrand is equipped with limestone injection and a baghouse for control of emissions. The EU #1 is fueled by coal refuse from the Sunnyside and Star Point Refuse Piles. The flylbottom ash generated from the coal combustion is disposed of in an on-site landfill or used for beneficial applications. 2.2 Flue Gas Sampling Locations Information regarding the sampling locations is presented in Table 2-1. Table 2-1 Sampling Locations T I I T I T I The sample location was verified in the field to conform to EPA Method 1. Acceptable cyclonicflow conditions were confirmed priorto testing using EPA Method 1, Section 11.4. See Appendix A.1 for more information. 2.3 Operating Conditions and Process Data Emission tests were performed while the source/units and air pollution control devices were operating at the conditions required by the relevant performance specifications. The units were tested when operating within the load levels required by 40 CFR Part 75. Plant personnel were responsible for establishing the test conditions and collecting all applicable unit-operating data. The process data that was provided is presented in Appendix B. Data collected includes the following parameters: . Unit Load (MW) . Relevant CEMS Parameters T I I T t I I 9 of 22O GP08 1AS-041757-RT- 1600 2.4 CEMS Description The boiler EU #1 CEMS analyzers are presented in Table 2-2. Table 2-2 CEMS Information t I T I I T t I T I I I I t I T I I 3.O Sampling and Analytical Procedures 3.1 Test Methods The test methods for this test program have been presented in Table 1-1. Additional information regarding specific applications or modifications to standard procedures is presented below. 3.1.1 EPA Method 2, Determination of Gas Velocity and Volumetric Flow Rate (Type S Pitot Tube) EPA Method 2 is used to measure the gas velocity using an S-type pitot tube connected to a pressure measurement device, and to measure the gas temperature using a calibrated thermocouple connected to a thermocouple indicator. Typically, Type S (Stausscheibe) pitot tubes conforming to the geometric specifications in the test method are used, along with an inclined manometer. The measurements are made at traverse points specified by EPA Method 1. The molecular weight of the gas stream is determined from independent measurements of Oz, COz, and moisture. The stack gas volumetric flow rate is calculated using the measured average velocity head, the area of the duct at the measurement plane, the measured average temperature, the measured duct static pressure, the molecular weight of the gas stream, and the measured moisture. Pertinent information regarding the performance of the method is presented below: . Method Options: o S-type pitot tube coefficient is 0.84 o Method Exceptions: o None The typical sampling system is detailed in Figure 3-1. t l 70 of 220 GP08 1AS-041757-RT- 1600 Figure 3-1 EPA Method 2 Sampling Train GP08 1AS-041757-RT- 1600 3.1.2 EPA Method 4, Determination of Moisture Content in Stack Gas EPA Method 4 is a manual, non-isokinetic method used to measure the moisture content of gas streams. Gas is sampled at a constant sampling rate through a probe and impinger train. Moisture is removed using a series of pre-weighed impingers containing methodology- specific liquids and silica gel immersed in an ice water bath. The impingers are weighed after each run to determine the percent moisture. Pertinent information regarding the peformance of the method is presented below: o Method Options: o None o Method Exceptions: o Alt-009 was used for post-test meter calibration The typical sampling system is detailed in Figure 3-2. t I I I I I t I I I I I t t I I t I T12 of 22O GP08 1AS-041757-RT-1600 I I I I t I I I I t T I I I I I I I I Figure 3-2 EPA Method 4 Sampling Train (slaNad tpl . VACUUMq- L|NE THERM@OtJPLESIi BY.PASS VALVE (ttredpd ) VACUUM GAUGE MANOi,IETER ------+ 13 of 22O GP08 1AS-041757-RT- 1500 I I I3.1.4 EPA Methods 3A, 6C, 7E, and 1O, Determination of Oxyg€llr Carbon Dioxide, Sulfur Dioxide, Nitrogen Oxides, and Carbon Monoxide Concentrations in Emissions from Stationary Sources (Instrumental Analyzer Procedures) Concentrations of Oz, COz, SOz, NOx, and CO are measured simultaneously using EPA Methods 3A, 6C, 7E, and 10, which are instrumental test methods. Conditioned gas is sent to a series of analyzers to measure the gaseous emission concentrations. The performance requirements of the method must be met to validate the data. Pertinent information regarding the pefformance of the method is presented below: o Method Options: o A nondispersive infrared analyzer is used to measure COz o An ultraviolet absorption analyzer is used to measure SOz o A chemiluminescent analyzer is used to measure NOx o A gas filter correlation nondispersive infrared analyzer is used to measure co o NO and NOz are measured separately and summed to repoft NOx emissions o The alternative NOx converter efficiency test described in EPA Method 7E Section 16.2 may be used (bag procedure) o Gas stratification testing was peformed across a grid of 12 points determined using EPA Method 1 in accordance with 40 CFR Part 50, Appendix B, PS2 58.1.3.2 and 40 CFR Paft 75, Appendix A, $6.5.6.1. Stratification testing was performed for two minutes per traverse point in accordance with 40 CFR Paft 75, Appendix A, $5.5.6.1(c). As diluent and pollutant concentrations are within LOo/o of their mean concentrations, RATA testing was performed at three points located 0.4 meter, 1.0 meter and 2.0 meters from the stack wall, as required by 40 CFR Part 60, Appendix B, PS2 58.1.3.2 and 40 CFR Paft 75, Appendix A, $6.5.6.1(a). The typical sampling system is detailed in Figure 3-3. I I T I I I I I I I I I T I T IL4 of 22O GP08 1AS-041757-RT- 1600 I I t I I I I I I I t I T I I t I I t Figure 3-3 EPA Methods 3A, 6C, 7E, and 1O Sampling Train E)fiaug / Calibration Gas SIGNAL !------ SIGNAL SAMPLE FROE E)fiau$ Sample / Calbmtion Gas ^*l #! .&A\GR' iOT&ETIRSWTHFbwcdrR4VAES ?SROTSETIF WTH TL*COTTR4 gPu'flow+s' ROIXET!iSWTH [1ilcffn4 vaws q ANALYZER MASS FLOIVCONTRO-LER/ CAUMATIOI.I GAS MANIFOLD t5 of 22O GP081AS-041757-RT- 1500 3.2 Process Test Methods The test plan did not require that process samples be collected during this test program; therefore, no process sample data are presented in this test report. 4.O Test Discussion and Results 4.L Field Test Deviations and Exceptions No deviations or exceptions from the test plan or test methods were identified by the project manager during this test program. 4.2 Presentation of Results The average results are compared to the applicable performance specifications and permit limits in Tables 1-2 and 1-3. Emissions are reported in units consistent with those in the applicable pefformance specifications. Additional information is included in the appendices as presented in the Table of Contents. I I I I I T I I I I T I t I I I I I IL6 of 22O GP08 1AS-0417s7-RT-1500 I I I I I I I I I 5.O Internal QA/QC Activities 5.1 QA/QC Audits The meter boxes and sampling trains used during sampling performed within the requirements of their respective methods. All post-test leak checks, minimum metered volumes, and minimum sample durations met the applicable QA/QC criteria, except where noted in Section 5.2. Alternative Method Alt-009 was used for post-test meter calibration. EPA Method 3A, 5C, 7E, and 10 calibration audits were all within the measurement system performance specifications for the calibration drift checks, system calibration bias checks, and calibration error checks, except where noted in Section 5.2. The NOz to NO converter efficiency check of the analyzer was conducted per the procedures in EPA Method 7E, Section 8,2.4. The conversion efficiency met the criteria, except where noted in Section 5.2. 5.2 QA/QC Discussion All QA/QC criteria were met during this test program. 5.3 Quality Statement Montrose is qualified to conduct this test program and has established a quality management system that led to accreditation with ASTM Standard D7O36-O4 (Standard Practice for Competence of Air Emission Testing Bodies). Montrose pafticipates in annual functional assessments for conformance with D7O35-A4 which are conducted by the American Association for Laboratory Accreditation (A2LA). All testing performed by Montrose is supervised on site by at least one Qualified Individual (QI) as defined in D7036-04 Section 8.3.2. Data quality objectives for estimating measurement uncertainty within the documented limits in the test methods are met by using approved test protocols for each project as defined in D7036-04 Sections 7.2.t and 12.10. Additional quality assurance information is included in the report appendices. The content of this report is modeled after the EPA Emission Measurement Center Guideline Document (GD-043). L7 of 22O GP08 lAS-041757-RT- 1500 I I I I I I t T T I Appendix A Field Data and Calculations cP08 1AS-041757-RT- 1600 Appendix A.1 Sampling Location L9 of 220 GP08 1AS-041757-RT- 1600 EU T1 Stack Drrwlng & Trrv.Ea Point lrortlon T I I I I I I I I Cln t Coepn ClyrStlac: &lrmydd. Sane: Eult Job No. PROJgl767 Dllc: SlXUbA lrptn By Ch.yrxy Guymo.l I I I I I I I I GPoslAS-0417s7-Rr-1600 I I of TItram: v.lodty d hlqrLtr:Pqr TYP. gdrAru, Ft': t{mb.rof M: t neafto,M,lncftc: Totd l,lun${ ot Tltnm Polnt3: 6 6GGtt a 6.@ 12UFrilm F om Flow Ixrfinb.no lA): 104.0 tNcHES ln ld. St d( lnch€ Outla(l. lgpplo lrchdPolnt ilo. ,,LqINCHES 1 2 3 1 6 3 tLa 10.4 147 fr.l 28.9 35.9 71.1 71.'l !a.r 02.3 93.6 'tozc ' Adju.t d polnb dm.tr > 2.' no poant doar thJt t.O lrch ' Adr6t d pollrn dmd S 2f no polni clorr Orn o.5 ln rt Stek Di.rrt rr b.tw.O l2-Z lnci.t mlnlmrm Poarlt3 ft I ; a polnt p.r port |tttr E, 2 dlliltm domdrull fld uFtmcdt dabDt rr{cHE9 -C'E 20 of 220 ) Appendix A.2 RATA Results Appendix A.2.L Unit 1 22 of 22O cP08 1AS-041757-RT- 1600 I I Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah M660 801-794-2950I I RATA Sheet Company: Sunnyaide Source: EU #1 Date: 512312024 Monitor: Flow - P63 scfh I T Reference RelativeMethod Method Run # (scfh) (scfh) Diff Diff. Sqd.I 173,275 174,y4 -1,069 11427612 173,797 175,181 -1,384 1915456 3 172,336 174,724 -2,388 57025/4*4 172,409 175,1y -2,725 7425625*5 171,071 174,325 -3,2il 10588516 6 173,335 175,316 -1,981 39243617 172,437 174,il1 -2,104 4426816g 172,002 174,472 -2,470 6100900*9 172,423 175,414 -2,991 894608110 171,U4 174,236 -2,392 57216il11 172,453 174,536 -2,083 4338889 12 172,005 174,001 -1,996 3984016 Ave 172,609 174,595 -1,985 * Not used in calculations Standard Deviation 472.68 Relative Accuracy 1.36 % Confidence Coefficient 363.34 (of RM Test Data) T I I t I t I I I I T t I 23 of 22O GP08 1AS-041757- RT- 1500 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 RATA Sheet T I I I I T I I I I I I t T I I I I I Company: Sunnpide Source: EU #1 Dale: 512312024 % Reference Method Run # dv(%)*1 5.62 5.73 5.74 5.75 5.76 5.77 5.78 5.7I 5.710 5.7 Relative Method dv(%) 5.8 5.9 5.9 5.9 5.9 5.9 5.9 5.9 5.9 5.9 Abs. Diff 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Diff. Sqd. 0.0400 0.0400 0.0400 0.0400 0.0400 0.0400 0.0400 0.0400 0.0400 0.0400 Ave 5.7 * Not used in calculations StandardDeviation 0.000 ConfidenceCoefficient 0.000 0.25.9 Absolute Difference (of RM Test Data) O.2O olo 24 of 22O GP08 1AS-041 757-RT- 1 600 0.11 0.08 I I I t I I I I I I I I I I I I I I I Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 RATASheet Company: Sunnyside Source: EU #1 Date: 512312024 Standard Deviation Confidence Coefficient Reference Method Run # (%) 1 14.02 14.03 13.94 13.95 14.1*6 14.37 14.18 14.1 I 14.110 14.2 Ave 14.0 ' Not used in calculations co2 % Relative Method (Y,) 14.0 13.9 13.9 13.9 13.9 14.0 14.0 13.9 13.9 13.9 Abs. Diff 0.00000 0.10000 0.00000 0.00000 0.20000 0.30000 0.10000 0.20000 0.20000 0.30000 Diff. Sqd. 0.00000 0.01000 0.00000 0.00000 0.04000 0.09000 0.01000 0.04000 0.04000 0.09000 13.9 0.1 Absolute Dlfference 0.12 (of RM Test Data) 25 of 22O GP08 1AS-04 1 757-RT- 1 500 t I I I I I T t I I I t I I t I T I T lbs/hr Run # 1 2 3 4 5 6 7 *8 I 10 Montrose Air Quality Seruices, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 RATA Sheet Monitor:Company: Sunnyside Source: EU #1 Date: 512312024 Standard Deviation Confidence Coefficient Reference Method (lbs/hr) 143,907 149,673 151,658 149,823 142,938 149,296 152,257 156,431 156,551 153,657 Relative Method (lbs/hr) 143,912 143,770 143,666 142,943 142,947 142,638 '141,285 142,779 143,035 142,803 Abs. Diff 5 5,903 7,992 6,880 8 6,658 10,972 13,652 13,515 10,855 Diff. Sqd. 25 34845604 63877797 47338669 68 44322592 120393929 186367186 182663629 117823176 149,973 143,000 6,977 4,653 3,577 Relatlve Accuracy 7.04 % (of Reference Method) 26 of 22O GP08 1AS-041 757-RT- 1600 I I I I I I I I I I t I t I I I I I I Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 RATASheet Company: Sunnyside Source: EU #1 Dale: 512312024 Monitor:SO2 ppmvd Reference Method Run # (ppmvd) 1 69.12 U.73 94.14 91.45 U.7 '6 93.47 88.48 88.4I 90.010 93.3 Relative Method (ppmvd) 71.9 78.2 88.0 85.4 84.7 85.5 82.4 81.9 83.4 87.0 Abs. Diff 2.8 6.5 6.1 6.0 0.0 7.9 6.0 6.4 6.6 6.3 Diff. Sqd. 7.6176 41.9904 37.0881 35.7604 0.0009 61.9369 36.4816 41.6025 43.6921 40.1956 87.1 82.5 5.2 31.60 * Not used in calculations Standard Deviation 2.27 ConfidenceCoefficient 1.75 Relative Accuracy (of RM Test Data) 5.20 o/o 27 of 22O GP08 1AS-041757- RT- 1600 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 T I I I I I l I I I I I I I I I I I I RATA Sheet Company: Sunnyside Source: EU #1 Date: 512312024 Monitor: SO2 lbs/mmbtu Reference Relative Method Method Run# (lb/mmbtu)(lb/mmbtu)*1 0.148 0.1622 0.181 0.1763 0.202 0.1984 0.196 0.1935 0j79 0.1916 0.195 0.1937 0.187 0.186I 0.188 0.185I 0.190 0.18810 0.197 0.196 Abs. Diff 0.014 0.005 0.004 0.003 0.012 0.002 0.001 0.003 0.002 0.001 Diff. Sqd. 0.0002 0.0000 0.0000 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.191 0.190 0.004 'Not used in calculations StandardDeviation 0.003 ConfidenceCoefficient 0.003 Relative Accuracy (of RM Test Data) 3.29 % 28 of 22O GP08 1AS-041757-RT- 1600 I I I I t I I I I I t I I I I I I I I Montrose Air Quality Services, LLG. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 RATASheet Company: Sunnyside Source: EU #1 Dafe: 512312024 Monitor: SO2 lb/hr Reference Relative Method Method Run # (lb/hfl flb/hfl Abs. Diff Diff. Sqd. 1 98.6 102.4 3.8 14.13762 120.5 111.7 8.8 76s1293 133.3 125.6 7.7 59.294 129.1 121.8 7.3 53.72895 120.3 120.7 0.4 0j76416 133.2 121.9 1 1.3 127 .2384 7 125.7 117.3 8.4 69.7225 8 126.2 116.8 9.4 87.60969 130.4 119.1 11.3 128.142410 13s.0 123.8 11.2 125.8884 Ave 124.3 117.7 7.6 * Not used in calculations Standard Deviation 3.5't Relatlve Accuracy 8.26 o/o Confidence Coefficient 2.70 (of RM Test Data) 29 of 22O GP08 1AS-041757- RT- 1600 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 RATASheet t I I I I I t t T t I I I I t I T I I 1.2 Company: Sunnyside Source: EU #1 Date: 512312024 Standard Deviation Confidence Coefficient NOx ppmvd Run # 1 2 3 4 5 6 7*8 I 10 Reference Method (ppm) 165.4 167.2 163.9 162.8 164.2 167.1 169.3 167.3 167.1 165.3 Relative Method (ppm) 166.1 168.2 165.0 164.3 165.6 167.5 170.5 169.0 167.7 166.6 Abs. Diff 0.7 1.0 1.1 '1.5 1.4 0.4 1.2 1.7 0.6 1.3 Diff. Sqd. 0.49 1 1.1881 2.2801 2.01il 0.16 1.3924 2.8224 0.3249 1.69 165.8 166.8 1.0 * Not used in calculations 0.39 0.30 Relative Accuracy (of RM Test Data) 0.79 Yo 30 of 220 GP08 1AS-04 1757- RT- 1600 I I t I I t I I I I I I I I I I I I I Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 RATA Sheet Company: Sunnpide Source: EU #1 Date: 512312024 Monitor: NOx lb/mmbtu Reference Relative Method Method Run # (lb/mmbtu) (lb/mmbtu) Abs. Diff Diff. Sqd.1 0.254 0.268 0.014 0.00022 0.257 0.273 0.016 0.00033 0.253 0.268 0.015 0.00024 0.251 0.266 0.015 0.00025 0.250 0.269 0.019 0.0004*6 0.251 0.271 0.020 0.00047 0.257 0.276 0.019 0.00048 0.256 0.274 0.018 0.00039 0.2il 0.272 0.018 0.000310 0.251 0.270 0.019 0.0004 Ave 0.2U 0.271 0.017 * Not used in calculations Standard Deviation 0.0020 Relatlve Accuracy 7.31 % Confidence Coefficient 0.0015 (of RM Test Data) 37 of 220 GP08 1AS-04 1757-RT- 1 500 Appendix A.3 Unit 1 Field Data 32 of 220 GP081AS-041757-RT- 1500 Appendix A.3,1 Flow Data 33 of 22O GP08 1AS-041757-RT- 1600 MoNTROSE AIR QUALITY SERVTCES, LLC. 6823 South 3600 West Spanish Forh UT 84660 Cvclonlc FIow Determlnation ratrm EV v I o," Skzf o,{ BrnPrcr* t"Iflrp) 6'fl Pr,o,r\,,G) b'B ('91) StrdcPrts.("IIro)L strc*orncudur-14-l Pltot Tuber Po *t e,- / B--lZ-1 34 of 22O GP08 1AS-041757-RT- 1 600 I I I I vetocitv sheet t '1]Hili'=#'n' #'l 512312024 I ^P Sqrt AP rs (in. H2O) (in. H2O) oF 1 1.3 1.14 298 I Z iZ ili 3ZZ war Errects 14 1.5 1.22 298 0 101 inI 3 l:l l:31 i'i t ,:ffil ::, 7 1.5 1.22 298 Ps -0.75 in. H2OI 3 l:? l:33 i'i 'r: ii:12 'l;iZ 10 1.5 1.22 298 Mw(wet) 29.320'l lb/lb-mole I 11 1.6 1.26 298 Bws 0.0915 I 12 1.5 1.22 2gB Vs = 94.9944 ft/sec Qs "ta = 1.0397E+07 scf/hr t ,$fii: '3111','JH scr/min I average = 1.s92 1.2604 297.83 oF RUN#I: 9.4595E+06 DSCFH Ts7.Bg oR 1.o41zE+07 scFH Montrose Air Quality Seruices, LLG. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 35 of 220 GP08 1AS-041757- RT- 1600 I I I I I T I Montrose Ar Quality Services, LLG. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 Velocitv Sheet Sunnyside EU #1 (105s-1ose) #2 I I I I I t I I I I I I I I T t t I t 5t23t2024 1 2 3 4 5 6 7 8 I 10 11 12 AP Sqrt AP (in. H2o) (in. H2O) 1.18 1.30 1.26 1.26 1.U 1.30 1.22 1.26 1.26 1.30 1.22 1.22 Ts OF 298 298 298 298 298 297 298 298 298 298 298 297 297.89 0F 757.83 0R WallEffects 0 A ce Ps Pu., P3 Mw(wet) Bws Vs= 1101 in 55.64 fr2 0.8400 6-8 -0.75 in. H2O 23.52 in. Hg 23.46 in. Hg 29.3201 lb/lb-mole 0.0915 95.2808 fUsec 1.4 1.7 1.6 1.6 1.8 1.7 1.5 1.6 1.6 1.7 1.5 1.5 average =1.600 1.264.2 Qs.to = 1.M28E+07 scfhr Qs.ta = 1.73797E+05 scf/min DSCFH = 9.4737E+06 RUN #2: 9.4339E+06 DSCFH 1.0384E+07 SCFH 36 of 22O GP08 1AS-04 1 757-RT- 1600 tn fr2 ftlsec scfhr scf/min oF oR I I t I I I I I t I I t I I I I I I t Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 Velocitv Sheet Sunnyside EU #1 (r110-1114) #t 5123t2024 AP (in. H2o)1 1.52 1.63 1.84 1.4 5 1.5 6 1.7 7 1.4 8 1.6 I 1.7 10 1.8 1',| 1.612 1.3 Sqrt AP (in. H2o) 1.22 '1,26 1.U 1.18 1.22 1.30 1.18 1.26 1.30 1.U 1.26 1.',t4 Ts OF 298 298 297 298 298 298 298 297 297 298 298 298 Wall Effects 0 A ce Ps Pb., Pr Mw(wet) Bws Vs= Qs "to = Qs.ta = DSCFH = 1 101 55.64 0.8400 -0.75 23.52 23.46 29.3201 0.0915 94.4692 1.0340E+07 1.72336E+05 9.3940E+06 average =1.575 1.2535 297.75 757.75 RUN #3: 9.3960E+06 DSCFH 1.0U2E+07 SCFH 6-B in. H2O in. Hg in. Hg lb/lb-mole 37 of 220 GP08 1AS-041 757-RT- 1600 Montrose Ar Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 Velocitv Sheet Sunnyside EU #1 11120-11241u t I I I I T I I I I I I I I I I I I I oF oR 5123t2024 1 2 3 4 5 6 7 I 9 10 11 12 AP (in. H2o) 1.3 1.6 1.7 1.6 1.4 1.7 1.6 1.5 1.6 1.6 1.7 1.6 Sqrt AP (in. H2o) 1.14 1.26 1.30 1.26 1.18 1.30 1.26 1.22 1.26 1.26 1.30 1.26 WallEffects 0 A cp Ps Pt., P. Mw(wet) Bws Vs= Ts OF 297 298 298 298 298 297 298 298 298 298 298 298 1101 in 55.64 ftz 0.8400 6-8 -0.75 in. H2O 23.52 in. Hg 23.46 in. Hg 29.3201 lMb-mole 0.0915 94.5196 fr/sec average =1.575 1.2541 297.83 757.83 Qs *o = '1.0345E+07 scf/hr Qs.ta = 1.72409E+05 scf/min DSCFH = 9.3980E+06 RUN ll4: 9.3698E+06 DSCFH 1.0304E+07 SCFH 38 of 22O GP08 1AS-04 1757-RT- 1600 I I I I t I t I I I I I I I I I I I I Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 Velocitv Sheet Sunnyside EU #1 (1130-1134) #5 5t23t2024 AP (in. H2o)1 1.42 1.63 1.64 1.7 5 1.5 6 1.4 7 1.6 8 1.6 9 1.5 10 1.411 1.612 1.7 average =1.550 Sort AP (in. H2o) 1.18 1.26 1.26 1.30 1.22 1.18 1.26 1.26 1.22 1.18 1.26 1.30 Ts OF 297 298 298 297 297 298 298 298 298 298 298 298 WallEffects 0 A ce Ps Pt", P! Mw(wet) Bws Vs= QB "ta = Gls ,ta = DSGFH = 1 101 55.64 0.8400 -0.75 23.52 23.46 29.3201 0.0899 93.7759 1.0264E+07 1.71071E+05 9.3415E+06 6-B in. H2O in. Hg in. Hg lb/lb-mole in fi2 ft/sec scf/hr scf/min 1.2443 297.75 757.75 RUN #5: 9.4033E+06 DSCFH 1.0332E+07 SCFH oF oR GP08 1AS-041757-RT- 1600 Montrose Air Quality Seruices, LLC. 6823 South 3600 West Spanish Fork, Utah 84663 801-794-2951 Velocitv Sheet Sunnyside EU #1 (1140-114{1 #6 t I I I t I I I I I t I I I T I I I I 5t23t2024 AP (in. H2o)1 1.42 1.63 1.74 1.5 5 1.6 6 1.7 7 1.8 8 1.4 I 1.6 10 1.711 1.512 1.6 Ts OF 296 298 298 298 297 298 297 298 298 298 298 298 297.67 0F 757.67 0R Wall Effects 0 A ce Ps Pt", P. Mw(wet) Bws Vs= 1101 in 55.64 ftz 0.8400 6-8 -0.75 in. H2O 23.52 in. Hg 23.46 in. Hg 29.3201 lb/lb-mole 0.0899 95.0066 ft/sec Sqrt AP (in. H2O) 1.18 1.26 1.30 1.22 1.26 1.30 1.U 1.18 1.26 1.30 1.22 1.26 average =1.592 1.2607 Qs .ta = 1.0400E+07 scf/hr Qs au = 1.73335E+05 scf/min DSCFH = 9.4652E+06 RUN #6: 9.4406E+06 DSCFH 1.0373E+07 SCFH 40 of 22O GP08 1AS-041757-RT- 1600 I I I I I I I I I I I I I I I I I t I Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 Velocitv Sheet Sunnyside EU #1 (1150-11s4) #7 5t23t2024 AP (in. H2o) 1 1.32 1.63 1.54 1.7 5 1.6 6 1.7 7 1.7 I 1.5 I 1.6 10 1.511 1.512 1.7 Sqrt AP (in. H2o) 1.14 1.26 1.22 1.30 1.26 1.30 1.30 1.22 1.26 1.22 1.22 1.30 Ts OF 296 298 298 297 298 298 298 297 298 298 298 297 WallEffects 0 A ce Ps Pu, P" Mw(wet) Bws Vs= Qs.ta = Qs rto = DSCFH = RUN #7: 1101 in 55.64 ftz 0.8400 6-8 -0.75 in. H2O 23.52 in. Hg 23.46 in. Hg 29.3201 lb/lb-mole 0.0899 94.5040 fi/sec 1.0346E+07 scf/hr 1.72437E+05 scf/min 9.4161E+06 9.4042E+06 DSCFH 1.0333E+07 SCFH average =1.575 1.2541 297.58 0F 757.58 0R 4t of 22O GP08 1AS-041757-RT- 1500 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 80't-794-2950 Velocitv Sheet Sunnyside ('t200-12041 #8 t I I I I I I t I I t I I I I I I T I 512312024 AP (in. H2O)1 1.42 1.6 3 1.74 1.5 5 1.6 6 1.6 7 1.7 8 1.5 I 1.4 10 1.611 1.712 1.5 Ts OF 297 297 298 298 298 297 298 298 298 297 298 298 297.67 'F 757.67 oR WallEffects s A cP Ps Pb", Pr Mw(wet) Bws Vs= 1101 in 55.64 frz 0.8400 6-8 -0.75 in. H2O 23.52 in. Hg 23.46 in. Hg 29.3201 lb/lb-mole 0.0899 94.2756 fUsec Sqrt AP (in. H2O) 1.18 1.26 1.30 1.22 1.26 1.26 1.30 1.22 1.'t8 1.26 1.30 1.22 average =1.567 1.2510 Qs "to = 1.O32OE+07 scfhr Qs.ta = 1.72002E+05 scf/min DSCFH = 9.3923E+06 RUN #8: 9.4514E+06 DSCFH 1.0333E+07 SCFH 42 of 220 GP08 1AS-041757-RT- 1 500 I I t t I t I I I t I I I I I I I I I Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 Velocity Sheet Sunnpide EU #1 11210-12141 #9 512312024 AP (in. H2o)1 1.32 1.73 1.54 1.6 5 1.6 6 1.5 7 1.7 8 1.6 I 1.7 10 1.511 1.612 1.6 Sort AP (in. H2O) 1.14 1.30 1.22 1.26 1.26 1.22 1.30 1.26 1.30 1.22 1.26 1.26 Ts OF 298 298 298 298 297 297 298 298 298 298 298 298 Wall Effects 0 A cP Ps Pb., P3 Mw(wet) Bws Vs= Qs "to = Qsra= DSCFH = 1 101 55.64 0.8400 -0.75 23.52 23.46 29.3201 0.0807 94.5272 1.0345E+07 1.72423E+05 9.5105E+06 in fr2 6-B in. H2O in. Hg in. Hg lb/lb-mole ftlsec scf/hr scf/min average =1.575 1.2il2 297.83 757.83 oF oR RUN #9: 9.4945E+06 DSCFH 1.0328E+07 SCFH 43 of 220 GP08 1AS-04 1 757-RT- 1 600 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 Velocitv Sheet Sunnyaide EU #1 (134s-1349) #'t0 I I I 512312024 AP (in. H2o)1 1.42 1.63 1.54 1.7 5 1.6 6 1.5 7 1.4 8 1.7 I 1.6 10 "t.7 11 1.512 1.6 Sort AP (in. H2o) 1.18 1.26 1.22 1.30 1.26 1.22 1.18 1.30 1.26 1.30 1.22 1.26 Ts OF 298 298 297 298 296 298 298 298 298 298 297 298 WallEffects 0 A cP Ps Po., Pr Mw(wet) Bws Vs= Qs.u = Qs rta = DSCFH = RUN #10: 1101 in 55.64 ft2 0.8400 6-8 -0.75 in. H2O 23.52 in. Hg 23.46 in. Hg 29.3739 lb/lb-mole 0.0807 94.1892 ft/sec 1.0311E+07 scf/hr 1.718UE+05 scf/min 9.4786E+06 9.4786E+06 DSCFH 1.031'lE+07 SCFH average =1.567 1.2510 297.67 oF 757.67 0R I I I t I I44 of 22O GP08 1AS-041 757-RT- 1600 I I I t I I I I t T I T I I I t I I I Montrose Air Quality Services, LLG. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 Velocitv Sheet Phoenix Cement (13ss-1359) #11 5t23t2024 AP (in. H2o)1 1.32 1.73 1.64 1.5 5 1.6 6 1.7 7 1.4 I 1.6 I 1.7 10 1.711 1.512 1.6 Sort AP (in. H2o) 1.14 1.30 1.26 1.22 1.26 1.30 1.18 1.26 1.30 1.30 1.22 1.26 Ts OF 298 298 298 297 298 298 298 298 298 298 298 298 WallEffects 0 A cP Ps Pl". P" Mw(wet) Bws Vs= Qs "ro = Qs.ta = DSGFH = 1 101 55.64 0.8411 -0.75 23.52 23.46 29.3739 0.0807 94.5543 1.0347E+07 1.72453E+05 9.5122E+06 in ft2 6-B in. H2O in. Hg in. Hg lb/lb-mole frlsec scf/hr scf/min average =1.575 1.2il0 297.92 757.92 oF ,R RUN #11: 9.4998E+06 DSCFH 1.03ME+07 SCFH 45 of 220 GP08 1AS-041757-RT- 1 600 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 Velocitv Sheet Phoenix Cement (1405-1409) #12 I I I I I I I I I I t I I I I I I t I oF oR 5123t2024 AP (in. H2O)1 1.42 1.73 1.64 1.5 5 1.7 6 1.5 7 1.3 8 1.6 I 1.6 10 1.711 1.512 1.7 Sqrt AP (in. H2O) 1.18 1.30 1.26 1.22 1.30 1.22 1.14 1.26 1.26 1.30 1.22 1.30 Ts OF 298 297 297 298 298 298 298 298 297 298 298 298 Wal! Effects 0 A ce Ps Pb", P. Mw(wet) Bws Vs= GIS .to = Qs.to = DSCFH = 1101 in 55.64 ftz 0.8411 6-8 -0.75 in. H2O 23.52 in. Hg 23.46 in. Hg 29.3739 lb/lb-mole 0.0807 94.2876 fUsec 1.0320E+07 scf/hr 1.72005E+05 scf/min 9.4874E+06 average = 1.57 1.2506 297.75 757.75 RUN #12: 9.4874E+06 DSCFH 1.0320E+07 SCFH 46 of 22O GP08 1AS-041757-RT- 1600 t I I I I I I I I I I t I I I I I I I TEST RESULTS Svmbol vm Vmsta Vme v*o vw Bws Description Volume of Gas Sampled by Dry Gas Meter Dry Gas Volume at Standard Conditions Volume of Gas per Minute @ Dry Condtions Vdume of Water Vapor in the Gas Sample Total Moisture Collected in lmpingers and Silica Gel. Water Vapor in the Gas Stream, Proportion by Volume Units dcf dscf dscf/min scf g Value 80.7590 65.7229 0.il77 6.6180 140.6 0.0915 EPAMethod4 RUN#1 Pagelof3 47 of 22O GP081AS-041757-RT- 1500 Svmbol 1V. 2 Vr.to 3 Vre4 v"€"" 5V* 6 Bws TEST RESULTS Description Volume of Gas Sampled by Dry Gas Meter Dry Gas Volume at Standard Conditions Volume of Gas per Minute @ Dry Condtions Volume of Water Vapor in the Gas Sample Total Moisture Collected in lmpingers and Silica Gel. Water Vapor in the Gas Stream, Proportion by Volume EPA Method 4 RUN #2 Page2of 3 Units dcf dscf dsc'f/min scf s Value 80.3400 64.914/. 0.5410 6.4'156 136.3 0.0899 I I I I I I I I I I I I I I t I t I I48 of 22O GP08 1AS-041 757-RT- 1600 I I I I I T I I I I T t t I I I I I I TEST RESULTS Svmbol vm Vmstd V.e V*"" v* Bws Descriotion Volume of Gas Sampled by Dry Gas Meter Dry Gas Volume at Standard Conditions Volume of Gas per Minute @ Dry Condtions Volume of Water Vapor in the Gas Sample Total Moisture Collected in lmpingers and Silica Gel. Water Vapor in the Gas Stream, Proportion by Volume Units dcf dscf dscf/min scf s Value 39.4790 33.4083 0.5568 2.9325 62.3 0.0807 EPA Method 4 RUN #3 Page3of 3 49 of 22O GP08 1AS-041757-RT- 1600 tIIEI ooloIFd.Ir\tnNFI$oIoFt ott(\lGI tfN o og - oo o ^ EE 9 -o Fo= hlr , - ^ # gf f L EoFoJ 9G - ^ -e & f i L qE oF o.g o - o. t r .= oo o o o o o o o o o C, = F r- 6'oOP O* 76 - i (o d ) d r ( r ( o m o o o o o E& < , E -; ; ; ; - - ; - - ; 16 cI o oo oE E * tf tO ( D 1 o l r ) F O ) ! r O ( , G. E iJ @F F (O ( O NO N r \ l \ G) OE . 0 o <o < o < r i d d @ d d d c , d >: E E o€E - . = - i q f r E q E e E I q i E o= > o -q a o o @ o o N o o N r i 63 (o F c. , r N (" ) !r * 'I t @ (o F- ts El XE I . @ c o N N N N t s N @ N N t s ;i o - r ! L g) o o o o o o ) c D cD o cD o) 6E i/ NN N N N N N N N N N N oFEf !$ e e ss s s t s s s t B E E 6'FIf EE E r ., s r < r ( o r \ F @ @ @ @ @ @ E Ed a rr : (' to r o () ro t o to rr : r' ) ur rr , oF q, g) F' 6 E- c . , r < e s r o @ N c o o r P = S (! (L .!c @a Sl( \ l N N ( r O t \ f t f t t | r ) r O rt lo rf , L) rn ro | o r o r o | o r, lr ) Oc \ l F OO O - r tt t r i t t $ t t { \ i t t ! t NN N C { ( \ I N ( \ I S T S ' N N t- ( O s s N @ s r O F vs s s s Y v Y s s v SI N O I N N 6 I G T N N ( \ I N III FI i! l Er r#r tIIIIIII 6IE oo r c. r I . * f or <o c . r I . * o.gOa a a ( o ( o ( o @ ( o ( o @ @ @ @ .c m t t O O F N ( r t ( , O - N O +O O O FF - 6 { $l N N a? rJ )(o(o E5,o(! !ooco. = 5F o ooroF{IFd.INrnF{\rc)IaF{@oo-(,oN(\oF{lr l NN N O O O S t t S S S a6 6 6 6 0 6 1 6 l O r O r r , r J ) r , ) o( ( ) G r ( o N t \ N ( o @ o a \ 6 =g S S S S S V Y V S S N( \ I N N N C { N N N S I N N @6 @ o ) N r O @ - C D @ S l I } c< v s s s s r o s s s s NA U N N N N N N N N N N c,) IE ** * * I . * * I $ r G r N o.sE- - - EN O ! t l 0 O - N d , t L ) O - C a -d ) F r ( v ) ( , ) t $ t t t t $ l o 6 o &F F F oo o o o o o o o o o o c a c a? o ? c ? a? d? d ? o ? a? a? o + !l F t (\ l !t 6, t (o tf , (o ( , .a f \ t \ @ N r \ F t \ ( o @ o 6 t @@ ( l ) ( o ( o ( o @ ( o @ c r ( o G ) =6 O O - O N O O F t t^ e q c ! o l q a ' : c q q r r a? o- @ ( , o( o ( r o N o o N ! f o Fm O t d r t < l r ) ( r ) ( O F o @N N l s c O t O @ N l \ @ @ N oo o o o o ) o r o ) o ) ( D d r d ) NN N N N N N N $ I ( \ I N C I NN O N N N N ( r ) ( v ) ( ' ) T $ hr . ( ) c ) c r ( C ) ( o ( o c r ( o @ @ @ N6 f ) t t (I , C) N N N t \ 1 \ @ @ 6 6 U1 lO O r. ) r f ' t{ ) tJ ) rr ) |r ) tt ) CDtrE- s r c a t t l ( } ( o N @ o ) o F N d- -- -- a E 6d - oF o ^ CX E [ L 'a x - P e- EE 9 -6 ' FEf *E r s EoFEf cE - ^ EE . E t rE oF cD.E o ; oE .= EF g osp 3 o 9- 6 E. E < .P ^- = o rO c= o oo oE E * 3€ 5 3 >t E E lt1r lt Eff(,6JOoco- t (J FoEE . be J g> gJ t6B E. . ' U'E oFE= E ae -E oFEf 6E o it e E >E o oF o_ocEOEo . tIIIIIItIIIIIIIIttI II oolrHl =EIIIII oilIIIIIIIII ror)r\{N(Dr)sl F) O (O F, G , r l t t (, lO 1O 66 6 h b 1 r ) 1 6 r n b 6 6 lr , l O ( O f \ ( O @ ( O f \ q ] N q ) !t $ t t t S ! t t i \ t t NN N N SI $l N N N G I GI O@ $ h ? @ t O + 6 F sY v Y s s v s s s s NN N N N N N ( \ N N C I o -!6d - o( E o ^ od = i - EE U -o Fol ou = l - Fg f i t EoFo=e6 - ^ E B. E t qE oF o-E. . I I * * * i i N $ l o r ocSc o c o o s ) o ( . : < o ( o @ < o < o ( r o E (O r i !i lO t{ ) O O - - N N FJ C) * 6r r ) rO n |I ) (O ( O @ (O ( O ( O (O (o EffoGJO8. E 6F 66 0 0 0 6 h 6 6 6 b b a? c? o? o ? a ? c ? c o? o ? o ? a? a? OI r ) O f \ 6 O ) ( O O ( O l \ O ) l r ) d? a q q c ! c ! o ! c ? c ! q c Y c ! (o ( o ( ' , d) (') ( ' ) c) (') ( , ( r ) ( o (o E" 's o ,= oc .= oo9 l e -o F- a E" E < . P dE I= o oo oE E * 38 5 3 >: E E o)cE- r u < ' l t f I O ( O N @ O ) O r N o -- -- o lrILII oEPEE r ' s> Ef YGE g. J oE oFE .zxG - E E€ c{,FIf bE 6 6Q = > E- o oF o_OEEOEo . t- E P E f r q E ; i E A f r $ ,, - r j @ p p p p & R R S t s g @@ @ @ N N @ @ N @ O @ o) o) (D o) (D cD o) o) (D cD d) o) (\ I N N N N ( \ I N 6 I N N ( \ I O I NN O N N C ) d ) ( ' ) d ) lr ) lr ) lD @ G) (o G) (o ( o (D (o (o to t o @ @ € @ c o o r P c D o o ro ro lo ro r l ) ro rr , rf ) vj rf ) rr ) |l, I I I I Montrose Air Quality Services, LLG. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 Moisture Data EPA Method 4 I company: cosen Run Number: 1 t Sampling Location: EU #1 Date:512312024 I lmpinser 1 703.4 lmpinger 2 713 809.9 712.2 605.3 83s.8 Moisture Collected lnitialWeight FinalWeight Weight Gain 106O s -0.8 g 13.5 g 21.4 g TotalGain (V*) = 140.6 g GP08 1AS-041 757-RT- 1500 I tmpinser 3 5e1.8 I lmpinser 4 814.4 I I I I I I I I I s3or22o Montrose Air Quality Services, LLG. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 Moisture Data EPA Method 4 I I I I Company: Cogen Run Number: 2 Sampling Location: EU #1 Date:512312024 I I I I I lmpinger 1 lmpinger 2 lmpinger 3 lmpinger 4 lnitialWeight 708.2 Moisture Collected FinalWeight 687 Weight Gain -21.2 687.6 791.1 103.5 608.1 640.8 32.7 825.1 21.3 TotalGain (V*) =136.3 I I I t I t I I I I54 of 220 GP08 1AS-041757-RT- 1600 Montrose Air Quality Services, LLC. 6823 South 3600 West Spanish Fork, Utah 84660 801-794-2950 Moisture Data EPA Method 4 Company: Cogen Run Number: 3 Sampling Location:EU #1 Date:512312024 lmpinger 1 lmpinger 2 lmpinger 3 lmpinger 4 lnitialWeight 708 712.2 595.2 780.1 Moisture Collected FinalWeight 720 791.4 Weight Gain 12 12.2 11.3 TotalGain (V*) =62.3 55 of 22O GP08 1AS-041757-RT- 1600 Appendix A.3.2 Instrumental Test Method Data GP08 1AS-041757-RT- 1600 EE E E T E E E E E !o ! ! o o ! o ! a EE E E E E E E E E EE E E E E E E E E 33 3 i ! ! i i 3 i e2 e z e z , e z e E E t E E E E e e 2 d !! D ! a n a D a a !4 6 0 0 0 0 0 0 D EE E E E E E E E E E E E E E E E E E E EE E E E E E E E E E E E E E E E E E E ;; E E E E E = ; i il i i i i B i i i N6 N 6 + F 6 @ N N 3 E N 3 3 E E R 8 E d6 N N 6 N 6 6 o o 6@ O @ N O < - N F aN N a O F F O t O FF n T Q N O O O O 66 6 6 + O 6 6 6 6 ON N N N N N N N N dN N N N N N N N N dd d d c i d d c i c i d Cq q q C q g q q c oo o o o o o o o o ao a 3 6 ' 6 ' s 6 ' a ' a ++ + + + + * + + F < c c c c c c c c * ,l 5 t f t t t l c dd d t d d d d d a vvv v v v Y v v E oo o o o o o o o : oo o ( ) o o o o o E !. r C | q a q q 6 ! q O- t s 6 N F O F + N @F @ @ @ t s F N F t s rN O i 6 @ F 6 0 0 +* * * + + t * * r E c c c + tt f i t f r f J E dt d d t d 0 L e E a vvv v v v v v v E x x x x x x x x x - oo o o o o o o o x zz z z z z z z z 9 BE S E B T B E T E EE E E E E E E E E bb E E E E T E E E 88 8 8 8 8 8 8 8 8 6d 6 6 G 6 6 0 6 0 85 5 5 E 5 5 5 E 5 t6 ! t E ! ! ! t t EE E E E E E E E E dd d o a d d o a d da d a d d d o d o a. ! q e . ! I a ? a ? r a ? 6ts O N i N 6 N N 6 6@ @ @ 6 @ @ @ @ @ EE ! ! ! ! ! ! ! E EE E E E E E E E T a4 0 a a q a o o e oo d o o o o o o o €x E @ 6 6 r F 6 @ 6 N o 98 i su a e s E E b b E E O E ls c al d )Fr n E$ * * 8 S + * * P :E i c i c c - l c c c * 69 ? , r r = r r r =, c e 9 n t t d t d E d d j = o == = = = = = = = E -Y r e oo o o o o o o o t ! 22 Z Z 2 Z Z Z Z \ ) z IIItIIIItIIIIIIIIIt oo\oF{IFd.INrnNFl$oIaF{@oo- (J 6N O O O 6 6 r O 6 FN @ O N F 6 6 N O NF F 6 O 6 6 N O @ -6 0 6 N 6 d 6 6 6 I ': ., 1 .: ': ' : .: . : . : . : oo o o o o o o o o -N o i 6 @ N 6 O O ++ + + + + + + + - c c c c c c c c c s ,r r r J i J r l c dd e . d t E E c . E a vv v v v E OO O O O O O O O T oo o o a o o o o S -c a c 6 ' 6 ' a e e e ao 6 ' e 6 ' 6 ' c 6 ' 6 ' a +U { + t + * + + - +* * * * * * * * F E a a a ; i c c c * c E c c c c c c c * 3r f J f r : i l c f , r t r r r = r c dt d d t d . d d t a d d d . t d t t d d 2 vvv v v v v v v E vvv v v v v v v E x x x x x x x x x - oo o o o o o o o : , oo o o o 9 o o o A 66 6 6 5 6 5 6 5 O zz z z z z z z z 9 -- - - - o z 55 6 f f f f 5 6 f !!! ! o ! ! a ! ! fs f s s f f 6 s f 5f s 5 f 5 5 f 6 5 6! - ! 6 6 n O 6 6 a!- 4 0 0 4 E D E -N O O 6 6 6 @ N N da e r q r q r a q io o o o 6 6 @ o 6 =N O N N O N N O 6 -N O t 6 @ F O O o t+ + + + + + + + F tr c tr c c c c c c * )= ) a f r - r r c nd d d d d d d d 1 -Y - v ! E NN N N N Q N N N V oo o o o o o o o c ! @a a a a a @ a @ 9 a oNNsoNtn EE ! E ! E E ! E E E E E E E E E E E E 66 6 6 6 6 6 0 0 6 0 6 6 6 0 6 6 0 6 6 ET T E E E E E E E E E E E E E E E E E SS E E E E E E E E EE E S E E E S S E oo o o o o o o o o o o o o o o o o o o 60 6 A A 6 0 6 A 6 6 A A A A .E .s . E S. g g. ! !. E . 9 .E -E -g .E .g .E .! .E .! .g gg 9 g g g 9 9 g g g g g 9 9 9 9 g g ! - tt t t l l a l t l i l l l t l t l l l EE E E E E E E E E E E E E E E E E E E od o o d o d d d o d d a d d d d d d d da d d a a d a a d d a d d d d a d a d T3 B E B 3 R 3 8 3 aa a a a a a a a a oo o 6 0 0 0 0 0 0 EE E E E E E S E E oo o o o o o o o o 66 6 6 0 6 6 0 0 0 66 d d 6 6 d d 6 d 66 6 6 6 A ! ! ! 6 it t l l l l a l l EE E E E E E E E E dd a d a d d d o o da d a d a a d d a qo ? q o l A ' : . : c ? q q O-6 E O N n N O N o6 t + i o 6 0 0 0 Cq u ? q : q u ? * q \ q N@ 6 0 F 6 0 0 N 6 @N 6 6 F O O O O 6 =o a e 6 6 ' c a a 6 ++ & * * { + + + ? c c c c c c c c c * Jf J = r r f > f c tc . t d d d E d d - vv v v v E NN N N N N N N N V oo o o o o o o o ! ! a@ a a a o o o o S 66 E 6 O O ?N O n 6 @ N @ O O &t { * + + + t + F ** * t * t * * * - cc c c c c c E c * cc c c c c c c c * Sr r f , t r t J c 5f r f , f f r r E dd d d d d t d & 1 EE t r d t r t e . t r t r a vvv v v v v v v E vvv v v v v v v E x x x x x x x x xv oo o o o o o o o : oo o o o o o o o x 65 5 6 5 5 5 5 5 Q zz z z z z z z z 9 - o R8 8 3 3 8 8 8 3 8 E E E R 8 R R 3 R T EE E E E E E E E E E E E E E E E E E E EE E E E E E h E E h E h E E h b E b E 88 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 @@ 6 6 6 6 0 6 0 0 6 0 0 0 0 0 0 @ o o GG @ O 6 0 0 6 0 0 6 d d d 6 d 6 6 6 d ge g e g s e o s s eo e g e g o g S e EE E E E E E E E E E E E E E E E E E E do o o o o o o o o o d d o o o o o o o dd d o o d d d d d d o o d d o d d a d ': \ r a \ a 9 a q a ? 6G + F - O 6 6 O 6 @6 6 0 6 0 6 6 6 0 FN O + b O N 6 O O ++ + + + + & + + F E < c c c c c c c * fr - r r - ! t r c tt d e d n d d t r a vv v v v E NN N N N N N N N - oo o o o o o o o e ! aa a @ @ 6 a a a o @ ao 6 ' e 6' 6 ' t 6 ' 6 4 +& + + & + + + + F c c c t c c c c c * tit f f S f t l c dd d d d & c . E d a vv v v v v v v v E oo o o o o o o o : () o o o o o o o o E ao e c 6 ' a s 6 ' e a &+ * + { + + + + - c c c c c c c c c t Sr f r ! t r r t c dd d t d d d d d a vvv v v v v v v E x x x x x x x x x v oo o o o o o o o x zz z z zz z z z9 @O N O N N F N N N d; d i d i d i d ; d ; d i 6 i d i d ; N< N O O N F N N N NN N N N N N N N N qq a q u ? a q a q a ? {o o o o o o o o o qq c q a a c ? a c ! q lo o o o o o o o o q@ Ex E E$ : a d r ) li gEt , (, eEE)al,Eoa!EUIoaaao tt t t t t ! E ! EE E E E E E E E da o a a d d a a do d o d d o d d q. ! o l q . : a q o l a oo o r o 6 6 0 0 60 6 6 0 0 6 6 0 EE E E E E EE E E E E E E E E E oo o o o o o o o o o oo a o e e e o q e q ?a a G 6 ' 6 ' C a 6 ' 6 e O 6. e 6' A ' C a 6. 6 *+ * * * * * + * F + * + * * * * * + - c c c c E c c c c * c c c c c c c c c * ,tr f , r r r r c I f I f f f t , f c td d d d d d d d l dd d t d t t d n a vv v v v v v v v E vvv v v E oo o o o o o o o : . $ N N N N N N N N - 66 6 6 6 6 6 6 6 9 o o o o o o o o o 9! -- - - - o o o o o o a o o @ 3 It ooIl NlnHl sEIIIIt EE = E E E E E E E 60 0 6 6 0 0 6 6 6 4€ € e € 9 € € € € o) o ) @ @ G t ( ' ) r \ t \ N @ co N d ) r ( ) N o A l l f ) ( o ( Y ) N- (O - 6 _ N- O- t- a o) - rr , - lO - rO ( D O ) F t ( \ l F ( , r ( r ) lo r o s t s l r o r o r o r o l o 1 r ) FN ( " ) . t f l . c ) G ) N @ C r r O It : $ h { t + { t : t t * t l t : t t - c c c E c c c c c * J= 5 = = f J f r c tt t t t t t t t a vv v o a N( \ l ( \ t G t N ( \ l O t N ( \ t - oo o o o o o o o 9 ! oo o o o o o o ( ) S o) o It -e :l t 3CLA NV r. t N68 FN C D t l a r ( O F O + l t :+ t rE :t t : t t +t +t ct r c t r c c c c :, J 3 3 f 3 t 3 tt r x . x , & x . t t N( \ t N C \ t N C \ l ( \ t ( \ t oo o o o o o o oo o o o o o o EE E E E E E E E E dr ( b 6 ) ( l ) d r 6 r d i 0 r o o oo o o o o o o o o od , o d , o o d ) 6 r d ) o EE T E E T E E E E oo o o o o o o o o oo o o o o o o o o oo o o o o o o o . n .g . o . o . g . ( ! .( ! .o .G .o .g ll . o - o - o - o - o - o - o - o - o SS ; e ; S ; s } e } e } s ; s } e EE E t ' E ' ! ' E ' E ' ! ' E ' oo o o o d r o o o o oc r o o o o o o o o oo o o o o o o @ o ts t s E E t s T t s E T E oo o o o o o o o o oo o o o o o o o o oo . A o o o o o o o (E O O 6 ( E ( E O O ( o ( E EE E E E 5 5 5 5 E !E ' E E E E ! E D E ss s s s s s s s s qq o ? o ? - c ? r r r ( \ l tt ( A ( ' ) $ $ l } $ ! t t FN ( t + l r ) ( E ) ? \ a O C D O It t t * l { t l t * t l t l t l t e c c c c c c c c c * ff f f = = f = l c tt t t t r t & . d d a vv v E NN N N 6 1 ( \ I N N ( \ I V oo o o o o o o o q ! oo o o o ( - ) o o o ! ? (- ) =c a e 6 ' 6 ' s a 6 ' a It + + +t *t {t :t t : l t rt t - c E c c c c c c c * f= f l = a a a 3 c nd . d . d t t x . t t a vv v E GI N C . I N N N N N N - oo o o o o o o o 9 ! (J EE t ' E E ' E ! ' ' C ' ! ' ! ' ;e ; e } e I e i s t s e } < } e ; e } e O) O ) O ) O F ( A O { O F - c. i c ' i c . i + + + + + + { FN ( 7 r \ t l . ) ( E ) l \ O C D O + + :t t + rt t {t l t :l t : l t F c c c c c c c c c * J= f = = = = f 5 c dt t t d . t t d t a v+ v v v v v v v E NN ( \ t N ( \ 1 (\ , l S l N N v oo o o o o o o o E oo o o C ) o o o o ! 2 (J E :E ' !' E ' ! ' E ' :E ' !' :E ' E' (b ( D ( l ) ( D ( b 0 d ) ( , ) d ) 6 oo o o o o o o o o oo o r o d r o o 6 r o o EE E E E E E E E E oo o o o o o o o o oo o o o o o o o o 60 0 0 0 0 0 0 0 0 G( o ( g G t O . ! ( E C , ( E G on o o 6 5 n 6 - o 6 It l t l l t l t t ss s s s s s s s s \\ \ \ q q o t o g q q N( \ ( \ l N ( \ l c ) C ' \ l N ( , ) ( , ) EE ' E E E ' E E E ! ' E oo o o ( D 6 i 6 ) o o o oo o o o o o o o o oo o 6 ) 6 ( l ) 6 ) d ) 6 ) 0 , EE E E E E E E E E oo o o o o o o o o oo o o o o o o o o oo o . r o o o o o o G( ! C r ( u ( O G O G ( E O l) -o -o rl -o lr l t -o rt -o tr r t l t t r t t ss s s s s s s s s sx E Fc \ t N N c . , t N C \ l N c \ t N 3E ? dd r i d d d r j d r j d E& = (/ ) l 5 ) r r r =o 6 . G 6 ' 6 ' C A 6 ' a =- l l H * l t * t * * t l t l t l t l t - E8 5 E = E s s s E E s: i 9 t t t t t t t r t t a = o vv v t E x $ r N $ r N N ( \ 1 ( \ l N N - v oo o o o o o o o S EE ' ! ' E ! E E I ' E I ' ss s : s s s s s s s €* E '6 ii l @ o) co co o, @. o q) q) co -S J J d' r i d d d r i r i d r i r i = ei - = N, E (/ ) G l ;; ; fs . 0 $ 0 0 s 0 0 e E- g E c c c c c e c e c * rt - E ? = = f f r r r 3 r c F E ss s s s s s s s e ji NN N N ( \ t ( \ t ( \ l N ( \ l v v oo o o o o o o o S oNNo@tn IItITIItI q\ \ \ \ \ \ \ \ \ 1r , 1' ) lr ) r o lr t ro L' ro ro rr ) >LoEEJU'Io6,9cUJanooot!(, MONTROSE AIR QUALITY SERVICES, LLC. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 Plant Source Date Run Sunnyaide Unit EU #1 05123124 Run #1 Rata I I Date and Time 512312410:36 512312410:37 512312410:38 512312410:39 512312410:40 512312410:41 512312410:42 512312410:43 512312410:4 512312410:45 512312410:46 512312410:47 512312410:48 512312410:49 512312410:50 512312410:5'l 512312410:52 512312410:53 512312410:54 512312410:55 512312410:56 Average: NO, (opm) co (ppm) 13.9 13.9 13.9 14.1 14.0 13.8 '14.2 14.1 14.0 14.1 14.0 14.0 14.4 '14.2 14.0 14.3 14.0 13.8 13.9 14.1 13.9 14.0 so2 (ppm) 75.0 71.7 74.3 70.5 69.3 71.5 66.3 76.3 62.3 il.3 63.7 64.6 s9.7 66.3 66.4 66.3 71.0 76.4 75.9 65.8 68.4 68.8 02 cozgn ge) I I 169.3 165.6 162.8 161.5 169.6 164.5 163.3 162.7 168.8 164.5 166.4 164.1 167.4 163.8 165.6 163.8 168.6 166.4 162.1 170.2 170.4 165.8 5.9 5.7 5.9 5.7 5.7 5.8 5.8 5.6 5.9 5.8 5.8 5.8 5.9 5.7 5.8 5.7 5.7 5.8 5.7 5.9 5.9 5.8 13.9 14.0 13.9 14.',| 14.1 13.9 14.0 14.1 13.9 14.0 14.0 14.0 13.8 14.0 13.9 14.0 14.0 13.9 13.9 13.8 13.8 13.9I I I 59 of 220 GP08 1AS-041757- RT- 1600 MONTROSE AIR QUALITY SERVICES, LLC. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 Plant Source Date Run Sunnyside Unit EU #1 05123t24 Run #2 Rata I Date and Time 512312411:10 512312411:11 512312411:12 512312411:13 512312411:14 512312411:15 512312411:16 512312411:17 512312411:18 512312411:19 512312411:20 512312411:21 512312411:22 512312411:23 512312411:24 512312411:25 512312411:26 512312411:27 512312411:28 512312411:29 512312411:30 Average: NO, CO SO2 02 COz(ppm) (ppm) (ppm) t%) Un I I169.9 167.8 168.1 166.6 166.0 170.7 171.7 17',t.0 161.4 169.1 169.0 163.9 168.5 165.0 170.4 163.1 168.1 167.2 169.0 166.0 166.1 167.6 13.5 13.6 13.5 13.5 13.6 13.7 13.5 13.6 13.8 13.7 13.5 13.7 13.6 13.2 13.7 13.4 13.4 13.5 13.4 13.4 13.6 13.5 79.1 83.6 84.9 92.5 83.5 79.5 73.2 66.2 87.3 68.4 80.0 90.5 83.4 100.2 69.6 81.9 85.9 80.9 77.6 88.7 77.4 81.6 5.9 5.9 5.8 5.7 5.7 5.9 5.9 5.9 5.6 6.0 5.8 5.7 5.9 5.7 6.0 5.9 5.8 5.9 5.9 5.8 5.8 5.8 13.7 13.9 14.0 14.1 14.0 13.9 13.9 13.9 14.1 13.8 13.9 14.1 13.9 14.1 13.8 13.9 14.0 13.9 13.9 14.0 13.9 13.9 t I I I I I I60 of 220 GP08 1AS-041757-RT- 1600 MONTROSE AIR QUALITY SERVICES, LLG. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 t Plant Source Date Run Sunnytside Unit EU #1 05t23124 Run #3 Rata Date and Time 512312411:43 512312411:44 512312411:45 512312411:46 512312411:47 512312411:48 512312411:49 512312411:50 512312411:51 512312411:52 512312411:53 51231241l:il 512312411:55 512312411:56 512312411:57 512312411:58 512312411:59 512312412:00 512312412:01 512312412:02 512312412:03 Average: NOr (ppm) co (ppm) 13.1 13.5 13.2 13.2 13.6 13.6 13.5 13.4 13.6 13.5 't3.3 13.2 13.5 13.2 13.1 13.3 13.2 13.0 13.3 13.5 13.',| 13.3 so2 (opm) 95.7 89.9 93.2 87.9 92.1 9s.5 108.8 98.5 85.7 62.8 83.8 82.6 92.3 93.6 91.6 94.8 97.0 107.6 102.8 99.9 101.9 93.2 o2 tZt) 5.8 5.9 5.9 5.9 5.8 5.8 5.7 5.8 5.9 6.1 5.9 5.9 5.8 5.8 5.9 5.8 5.7 5.9 5.7 5.9 5.9 coz gd I I I 165.8 165.5 167.5 166.1 163.6 163.8 162.0 165.9 166.3 170.0 167.8 164.0 161.0 163.1 165.3 162.4 163.1 161.6 161.9 163.2 164.1 164.5 13.8 13.8 13.8 13.9 13.9 13.9 14.1 14.0 13.9 13.7 13.9 13.9 13.9 13.9 13.9 14.0 14.1 13.9 14.0 13.9 13.9 13.9 I 6L of 22O GP08 1AS-041757- RT- 1 600 MONTROSE AIR QUALITY SERVICES, LLC. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 Plant Source Date Run Sunnpide Unit EU #1 05123t24 Run #4 Rata Date and Time 512312412:16 512312412:'17 512312412:18 512312412:19 512312412:20 512312412:21 512312412:22 512312412:23 512312412:24 512312412:25 512312412:26 512312412:27 512312412:28 512312412:29 512312412:30 512312412:31 512312412:32 512312412:33 512312412:34 512312412:35 512312412:36 Average: NO, CO SO2 02 COz(ppm) (ppm) (oom) {%l Un 164.5 163.5 168.0 158.9 163.8 160.6 165.3 160.8 164.5 164..2 162.9 161.4 1&4.9 163.6 162.6 165.6 166.2 160.0 165.9 163.7 159.8 163.4 13.7 13.5 13.4 13.5 13.6 13.5 13.5 13.5 13.7 13.4 13.4 13.5 13.5 13.2 13.5 13.6 13.4 13.5 13.6 13.4 13.5 13.5 77.5 87.1 89.1 92.3 85.0 103.2 91.8 91.8 91.9 89.1 92.3 90.2 92.9 93.8 90.4 92.2 93.8 100.7 78.0 88.0 98.6 90.9 5.9 6.0 5.9 5.8 6.0 5.7 5.8 5.8 5.9 5.8 5.8 5.8 5.9 5.9 5.9 5.8 5.8 5.7 6.0 5.8 5.7 5.8 13.8 13.8 13.9 14.0 13.8 14.1 14.0 14.0 13.9 14.0 14.0 14.0 13.9 13.9 13.9 14.0 14.0 14.1 13.9 14.0 14.1 14.0 I I I62 of 22O GP08 1AS-041757-RT- 1600 MONTROSE AIR QUALITY SERVICES, LLC. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 NO, CO SO2 02 COz(ppm) (ppm) (pom) t%) Un I I I Plant Source Date Run Sunnyside Unit EU #1 05123124 Run #5 Rata Date and Time 512312413:21 512312413:22 512312413:23 512312413.,24 512312413:25 512312413:26 5123124'13:27 512312413:28 512312413:29 512312413:30 512312413:31 512312413:32 512312413:33 512312413:3tt 512312413:35 512312413:36 512312413:37 512312413:38 512312413:39 512312413:40 512312413:41 Average: 162.8 165.6 167.1 160.6 170.6 165.8 159.5 166.4 168.1 160.8 1il.3 169.2 't64.3 1M.7 165.2 't67.7 168.0 160.2 163.3 162.6 161.6 164..7 13.5 13.4 13.5 13.6 13.6 13.5 13.5 13.7 13.4 13.4 13.4 13.4 13.2 13.4 13.5 13.3 13.2 13.5 13.5 13.3 13.5 13.4 5.9 6.0 5.9 5.9 6.0 5.9 5.8 5.9 5.8 5.9 5.9 5.9 5.8 5.9 6.0 6.0 6.0 5.8 5.9 5.7 5.9 5.9 14.0 14.0 14.1 14.1 14.0 14.1 14.2 14.1 14.2 14.2 14.2 14.2 14.2 14.1 14.'.| 14.1 14.1 14.3 14.2 't4.3 14.3 14.1 88.5 83.9 80.9 80.8 74.0 80.1 87.9 87.4 90.2 91.7 86.1 82.5 93.6 80.8 77.2 76.9 80.2 89.0 82.6 92.5 89.4 84.6 GP08 1AS-041757-RT- 1 600 MONTROSE AIR QUALITY SERVICES, LLC. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 Plant: Sunnyside Source : Unit EU #1 Date: 05123124 Run : Run #6 Rata Date and Time 512312413:56 512312413:57 512312413:58 512312413:59 5123124'14:00 512312414:01 512312414:02 512312414:03 512312414:04 512312414:O5 512312414:06 512312414:07 512312414:08 512312414:09 512312414:10 512312414:11 512312414:12 512312414:13 512312414:14 512312414:15 512312414:16 Average: NO, CO SO2 02 COz(ppm) (ppm) (pom) {yn gn 169.9 170.0 166.2 164.8 173.6 168.4 163.8 168.'l 165.3 170.2 165.9 172.9 1il.s 165.9 161.5 164.7 163.4 171.1 173.1 168.0 166.8 167.5 13.5 13.2 13.2 13.s 13.4 13.2 13.4 13.4 13.3 13.4 '13.2 13.3 13.4 13.7 13.5 13.4 13.5 13.6 13.1 13.0 13.3 13.4 92.8 97.6 94.0 u.1 87.4 96.5 98.8 97.0 94.7 87.8 98.0 84.6 91.0 90.0 't07.7 101.6 108.3 91.8 89.1 80.4 82.9 93.1 5.9 5.9 5.8 5.9 5.9 5.7 5.9 5.8 5.7 6.0 5.7 6.0 6.0 5.8 5.6 5.7 5.7 5.9 6.0 6.0 5.9 5.8 14.2 14.3 14.3 14.3 14.2 14.5 14.3 14.4 14.4 14.2 14.4 14.2 14.2 't4.3 14.5 14.4 14.5 14.3 't4.2 14.2 14.2 14.3 I t I64 of 220 GP08 1AS-04 1 7s7-RT- 1600 MONTROSE AR QUALITY SERVICES, LLC. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 Plant Source Date Run Sunnyside Unit EU #1 05123124 Run #7 Rata Date and Time 512312414:32 512312414:33 512312414:?4 512312414:35 512312414:36 512312414:37 512312414:38 512312414:39 512312414:40 512312414:41 512312414:42 512312414:43 512312414:44 512312414:45 512312414:46 512312414:47 512312414:48 512312414:49 512312414:50 512312414:51 512312414:52 NO, CO SO2 02 COz(ppm) (ppm) (ppm) gn $) 168.7 166.1 174.4 17',t.9 168.1 172.3 170.9 't62.7 174.3 165.9 169.2 170.8 170.1 172.3 168.0 172.3 171.4 171.1 167.8 173.1 164.5 169.8 13.2 13.4 13.3 13.1 13.4 13.1 13.1 13.3 13.4 13.2 13.3 13.5 13.3 13.3 13.5 13.5 13.3 13.3 13.5 13.4 13.2 13.3 98.6 104.0 86.5 95.1 89.5 92.7 85.2 95.4 81.6 96.1 109.4 62.9 84.0 80.7 76.'.| 87.3 90.1 85.4 82.4 89.1 85.1 88.4 5.8 5.8 5.9 5.8 5.7 5.8 5.9 5.7 5.9 5.7 5.6 6.2 5.8 5.8 6.0 5.9 5.8 5.9 5.8 5.9 5.9 5.8 14.1 14.2 14.1 14.2 14.3 14.2 14.2 14.4 14.2 14.4 14.4 13.9 14.2 14.2 14.0 14.1 14.1 14.1 14.2 14.1 14.1 14.2 65 of 22O GP08 1AS-041757- RT- 1500 MONTROSE AIR QUALITY SERVICES, LLC. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 I IPlant: Sunnyside Source : Unit EU #1 Date: 05123124 Run : Run #8 Rata Date and Time 512312415:05 512312415:06 512312415:07 512312415:OB 512312415:09 512312415:10 512312415:11 512312415:12 512312415:13 512312415:14 512312415:15 512312415:16 512312415:17 512312415:18 512312415:19 512312415:20 512312415:21 512312415:22 512312415:23 512312415:24 512312415:25 Average: cozgnNO, CO SO2(ppm) (pom) (ppm) 165.8 1il.1 167.3 170.6 169.3 170.7 168.2 165.8 166.0 163.3 172.7 170.3 168.6 169.4 166.6 1U.1 167.3 168.4 170.2 168.4 166.8 167.8 13.2 13.4 13.3 13.3 13.4 13.5 13.3 13.4 13.6 13.4 13.4 13.3 13.4 13.3 13.3 13.5 13.4 13.5 13.5 13.4 13.1 13.4 o2 {vn 5.8 5.8 5.8 5.8 6.0 6.0 5.8 5.8 5.9 5.8 5.9 6.1 6.0 6.0 5.8 6.2 5.8 5.7 5.8 6.0 5.8 14.0 14.1 '14.1 14.1 14.0 14.0 14.1 14.1 14.0 14.2 14.0 13.9 13.9 14.0 14.1 13.8 14.1 14.2 14.1 13.9 14.1 14.0 99.0 90.8 97.2 91.5 85.3 80.7 g',t.7 93.0 87.7 101.2 88.6 74.0 75.5 89.0 96.8 81.5 84.1 92.4 80.4 82.6 96.6 88.6 I66 of 220 GP08 1AS-04 1757-RT- 1600 I I I MONTROSE AIR QUALITY SERVICES, LLC. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 I I Plant Source Date Run Sunnyside Unit EU #1 05t23t24 Run #9 Rata I Date and Time 512312415:38 512312415:39 512312415:40 512312415:41 512312415:42 512312415:43 512312415:44 512312415:45 512312415:46 5123124'15:47 512312415:48 512312415:49 512312415:50 512312415:51 512312415:52 512312415:53 512312415:54 512312415:55 512312415:56 512312415:57 512312415:58 Average: NO, CO SO2 02 COz(ppm) (ppm) (ppm) Un Ue) I 169.il 168.89 167.29 170.15 172.36 167.57 166.52 173.05 165.32 165.68 168.77 171.40 't68.74 164.97 164.65 164.81 166.76 170.17 167.33 166.08 160.68 167.7 13.21 13.09 13.20 13.36 13.09 13.22 13.35 13.12 13.14 13.46 13.34 13.28 13.02 13.46 13.31 12.80 13.39 13.35 13.09 13.04 13.36 13.2 105.81 101.75 100.55 81.74 88.09 83.02 84.96 77.14 95.56 87.56 85.15 83.03 84.89 91.58 100.97 92.20 81.53 85.53 86.46 95.41 102.20 90.2 5.79 s.81 5.86 5.91 5.89 5.86 5.90 6.06 5.79 5.88 5.89 5.88 5.97 5.89 5.76 5.76 5.95 5.91 5.91 5.85 5.73 5.9 14.04 14.05 14.05 14.01 14.04 14.07 14.02 13.90 14.13 14.05 14.06 14.07 13.99 't4.04 14.18 14.14 13.99 14.04 14.03 14.08 14.18 14.1 I I T I T I I I I I T I 67 of 22O GP08 1AS-041757-RT- 1 500 MONTROSE AR QUALITY SERVICES, LLC. 6823 South 3600 West 801-266-711 1 Spanish Fork, Utah 84660 I I t Plant Source Date Run Sunnpide Unit EU #1 05123124 Run #10 Rata Date and Time 512312416:12 512312416:13 512312416:14 512312416:15 512312416:16 512312416:17 512312416:18 512312416:19 512312416:20 512312416:21 512312416:22 512312416:23 512312416:24 512312416:25 512312416:26 512312416:27 5123124'16:28 512312416:29 512312416:30 512312416:31 512312416:32 Average: so2 02 coz(pom) tYel Un Nor (ppm) 163.3 166.0 166.0 166.7 169.4 170.2 165.3 163.5 167.4 163.9 167.8 169.6 165.0 161.1 164.8 169.3 166.6 162.7 167.7 164.6 162.3 165.9 co (ppm) 13.3 13.2 13.1 13.2 13.3 13.2 13.3 13.4 13.3 13.2 13.1 13.1 13.2 13.4 13.4 13.2 13.1 13.1 13.2 13.3 13.3 13.2 108.7 102.5 102.0 91.6 81.2 81.3 90.3 89.7 94.1 101.3 81.2 81.0 104.0 90.7 105.9 97.6 97.9 96.8 86.4 90.7 86.4 93.4 14.2 14.2 't4.1 14.1 13.9 14.0 14.1 14.1 14.1 14.2 13.9 14.0 14.2 14.1 14.1 14.2 14.0 14.1 14.1 14.0 14.0 14.1 5.7 5.7 5.8 5.8 6.0 6.0 5.8 5.8 5.8 5.7 6.0 5.9 5.8 5.8 5.8 5.8 5.9 5.8 5.8 5.9 5.9 5.8 I I I I I I I I T I T I T68 of 220 GP08 1AS-04 1757-RT- 1600 Appendix A.4 Example Calculations SAMPLE CALCULATIONS Sunnyside Cogeneration Associates, Unit EU#l RATA Compliance, PROJ-041757 t I I I I t I I I I I I t t I I T I T MOISTURE AND VOLUMETRIC FLOW RATE CALCULATION These results may differ slightly from the resu/fs presented in the report. Differences can be attributed to significant digit rcund-oft discrepancias, but should not be apparent until >3 significant figures. Value Symbol Definition 23.52 Po",Atmospheric Pressure, inches Mercury 459.67 459.67 Conversion factor, converting degrees Fahrenheit to degrees Rankine 68 Tc Gas Volume Correction Temperature, degrees Fahrenheit 29.92 Psto Standard Absolute Pressure, inches Mercury 80.759 V,Total metered volume, uncorrected, cubic feet 1.006 Y Meter Conection Factor, unitless 1.3 AHavs Delta H, sample rate average, inches H2O '13.6 13.6 Specific gravity of Mercury, unitless 55 T,Meter Tem perature, average, degrees Fahren heit -0.75 Pr Stack Gas Static Pressure, inches H2O 140.6 w"fVater caught, grams 1.04716 0.04716 Constant, cubic feet per milliliter 30.46 MWo Manually entered dry molecular weight, pounds per pound-mole 13.93 Coz Stack Gas Carbon Dioxide, Percent, by volume ).M MWcoz [4olecular Weight of CO2 divided by 100, pounds per pound-mole 5.8 o2 Stack Gas Orygen, Percent, by volume ).32 MWoz Molecular Weight of 02 divided by 100, pounds per pound-mole 30.27 N2 Stack nitrogen, percent by differencei N2 = 100 - 02 - CO2 - CH4 J.28 MWNz Molecular Weight of N2 divided by 100, pounds per pound-mole 1.18 MlWxzo Molecular Weight of water divided by 100, pounds per pound-mole 8s.49 Kp Constant 85.49 feet per second [ (pound per pound-mole) x (inches Mercury) / (degrees Rankine) x (inches water)l % 0.84 ce Pitot Tube Coefficient, unifless 1.2604 vaParE Square Root of Delta P, average 298 [8 Average Stack Gas Temperature, degrees Fahrenheit 101 ID lnside Stack Diameter, inches 24 24 12 inches per foot, multiplied by 2 3.14159 Pi Pi 1M 144 Conversion factor, converting square feet to square inches 0.7811 c.7854 Constant, representing Pi divided by 4 60 60 Seconds per minute or minutes per hour 3s.31 35.31 Cubic feet per cubic meter 60 Time Sample duration, minutes 70 of 22O GP08 1AS-041 757-RT- 1600 Vsc =V,*= V*= I I I SAMPLE CALCULATIONS I Sunnyside Cogeneration Associates, Unit EU#l RATA Comptiance, PROJ-041757 I Run I MolsruRE AND voLUMETRIc FLow RATE cALcuLATloN I iletered votume (v-r-.rl I vm.d, = Drysas*''i:;:#H,TJ::1::Y';iil.".**,ffi;l:liffi::1H':cubicreet - l,vm(std) - (459.67+68)/29.92x80.759x1.006x(23.520+(1.3113.6))/(54.88+459.67) r Vm(stdr = 65.76 ft3I- Stack Pressure (P.l I p. = stack pressu;;11]*tl,iiH rvrercury P,= 23.520+(-0.75l13.6) I P" = 23.46s inches Hg Moleture Volume (V-.) Volume of water vapor condensed, conected to standard conditions, standard cubic feet W" x 0.04716 140.6 x 0.04716 6.631 scf Measured Moisture (B*l I Measured stack gas moisture, percent I B*. = V"o/ (Vr"+ V',66y) x 100 B'o = 6.631 /(6.631 +65.760)x1oo I B,," = 9.160 % Saturated Moisture (B*) I Saturated stack gas moisture, percent I B*, = (100 / P")x l0^ (6.6911 - 13144 / (T. + 390.86))) B*" = (100 / 23.465) x'10^(6.6911 - (31441 (297.83 + 390.86))) I B*" = 1oo% (stack temP >212F) Molsture used In Calculatlons (B*) I * = -"^-r'rx t tulations'Percent I Drv MolecularWeiqht (MW,) MWa = Dry mo'ecu'aiH:X,;f::l:i:,r:ll'f"ifl ?i;xtfi^?li) + (cH1 x MW66a)r I MWo = (13.93 x 0.44)+ (5.8x 0.32) + (8o.zr x 0.28) + (0x 0.16)r MWa = 30.461 lbflb-mole I These rcsufts may differ slightty tromtl,o /€su/fs prosen tect in the rcport. Differences can be attibuted to significant diglt roundaff discrepancies, but should not be apparent until >3 significant figures. I 7L or 220 GposlAs-0417s7-Rr-1600 MOISTURE AND VOLUMETRIC FLOW RATE CALCULATION Wet Molecular Weiqht (MW-) Wet molecular weight of stack gas, pounds per pound-mole MW* = (MWxzoxBr)+(((100-B*")xMWd)/100) MW* = (0.18x9.160)+(((100-9.160)x30.a6)/100) MW,, - 29.319 lb/lb-mole Stack Gas Velocitv (V-) Average stack gas velocity, feet per second K, x G, x {4P,,, x { ;9. + 459.67) / (P, x Mw*)l 85.49 x 0.84 x 1.2604x r/11ZSZ.aS + 459.67) I (23.465x 29.319)l 94.975 fUsec Cross Sectional Area (CSA) Gircular Stack Circular stack cross sectional area, square feet I t I I I I I t I T I t I T t I T I T Qaa = Qso = Qso = SAMPLE CALCULATIONS Sunnyside Gogeneration Associates, Unit EU#l RATA Compliance, PROJ-041757 (lD l24l^2xPl (101 124) 2x3.14159 55.638 f( v" v" vs CSA = CSA = CSA = Averaoe Stack Gas Volumetrlc Flow Rate (acfm) Average, actual stack gas flow rate, actual cubic feet per minute acfm = acfm = acfm = scfm = scfm = scfm = Averaqe Stack Gas Volumetric Flow Rate (scfm) Average actual stack gas flow rate conected to standard conditions, standard cubic feet per minute V.xGSAx60 94.975x55.638x60 317,053.1 acfm acfm x (459.67 + T") / Pj16 x Pj / (T. + 459.67) 317,053.1 x (459.67 + 68) / 29.92x23.4651 (297.83 + 459.67) 173,209.1 scfm Averaqe Stack Gas Drv Volumetric Flow Rate (Q-,) Average standard stack gas flow rate corrected for moisture, dry standard cubic feet per minute (100-B*")/100xscfm (100 - 9.160) / 100 x173,209.1 157,343.1 dscfm Ihese resu/ts m ay ditrer slightly from the resu/ls presenfe d in the rcpod. Differences can be attributed to significant digit round-off discrepancies, but should not be apparcnt until >3 signiticant figures. 72 of 22O GP08 1AS-041757-RT- 1 600 lI I I I I I I I I t t I T I I I I t I SA]TIPLE CALCUIITIONS Sunnyllde Cogonoratlon Assoclates, Unlt Eurr'l RATA Compllance, PROJ{41757 AVERAGE STACK GAS CALCULATIONS CORRECTED FOR SYSTEiI BIAS VI,A USEPA 7E Averaoe Gas Effluent Calculation Conected for Svstem Bias Check. C...: USEPA 7E Run I Coo = (C.,r' Co) x [C'./ (C.'Co)] Oo Concontration ln Stack Ga! (percent) Ceuo = (5.800-0.15)x[10.070/(10.25-0.15)] Ceero = 5.633 Yo CO.Concentrallon ln Stack Gas (percent) cgoo . (13.900-0.1)x[11.97/(11.9s0-0.1)] Cs..o = 13.940 Yo NO- Concontratlon ln Stack Gas (parts per mllllon bv volumo. drv) csuo = (165.800 - 0.25) x 1247 I (247 .450 - O.25)) Csa.D = '165.416 ppmvd CO Concontratlon ln Stack Ga! (parts oer mllllon bv volume. drv) Cgoo = (14.000-0.1)x [25.3/(25.300-0.1)] Ce".o = 13.955 ppmvd SO. Concontratlon ln Stack Gas (parb por mllllon bv volume. drv) Csro = (68.800-0.15)x[99.8/(99.300-0.15)] Cc-o = 69.1 Those rasults may dillu sligh1y ftom the frsufs prsented ln the Epott. Difamces can be attibutott to slgnfcent digit rundaf drlscrpancleq but should not bo appaont until >3 sonifrc,,na figures. Symbol Dofinition Average gas concentration from anallzar, parts per million by volume or psrc€nt volume Actual concentration of the upscale calibration gas (SV), parts per million by volume or percent ,olume Average of the initial (Zi) and final (Zf) calibration bias check results for the zero gas, parts per million by volum€ or porrcsnt volume c.Average of the initlal (Si) and final (Sf) calibration bias check results for the upscale calibration gas, parts per million by volume or percent volume co.Average gas €ffluent concentration conected for system bias check, parls per million by volume cr p€rcenl volume Cguw Avorage gas effluent concentration conected for system bias check, parts per mlllion by volume cr peroent volume Gas Componenl o2 o/cvd Coz o/o vd Nox 6Dmvd co oomvd Soz oomvd THC DOmW CHr DOmt,W 5.8 13.9 't65.8 't4.0 68.8 N/A N/A z€ro initial (Zi)0.1 0.2 0.3 0.1 o.2 N/A tvA zsro linal (Zf)0.2 0.0 o.2 0.1 0.1 N/A t{/A co 0.2 0.'r 0.3 0.1 0.2 #Dtv/0!#Dtv/01 upscals initial (Si)10.3 12.O 247.2 25.4 100.4 N/A N/A upscale final (S0 10.2 11.9 247.7 25.2 94.2 N/A N/A cm 10.3 12.O 247.5 25.3 99.3 #Dtv/0! #Dlv/o! upscalo valuo (SV)10.07 11.97 247 2s.3 99.8 N/A N/A 73 of 220 GP08 1AS-04 1757-RT- 1 600 SAMPLE CALCULATIONS Sunnyside Cogeneration Associates, Unit EU#l RATA Compliance, PROJ-041757 EPA METHOD 7E CALIBRATION CALCUI-ATIONS I I I I I I I I I I I I I I I I T I I Choose Parameter: Analyzer Callbratlon Error - Mld-Leve! Absolute Difference AGE.il(dlrf) = ACE-y1661 = ACE-y16161 = Percent of Span AGE.1, = ACE-M = ACE-M = I corn-r'r 'Gv-u I l(101.3 - 101.e)l 0.60 Choose Parameter Above I (Corn-u - Cv* ) l/ CS x 100 l(101.3 - 101.9)l t 247 x 100 0.24 percent of span I Gorn+'cv+ I l(247.1 - 247)l 0.10 Choose Parameter Above Analvzer Callbratlon Error - HIqh-Level Absolute Difference ACEa11661 = ACE-616161 = ACE-H16ffi) = Percent of Span ACE-H = ACE-H = ACE-H = I (Corn+ - Cv-r ) | / CS x 100 l(247.1 - 247)l I 247 x 100 0.04 percent of span These results may ditrer slightly from the resu/fs presented in the report. Difierances can be attributed to significant digit roundoff discrepancies, but should not be apparent until >3 significant figures. Value Symbol Definition 0.00 Cv-r-Low-levd gas cylinder value, parts per million by volume or percent volume 101.9 Cv-u Mid-level gas cylinder value, parts per million by volume or percent volume 247 Cv-r-r High-level gas cylinder value, parts per million by volume or percent volume 0.00 Corn-l Measured concentration of low-level calibration gas in direct calibration mode, parts per million bv volume or Dercent volume 101.3 Corn-u Measured concentration of mid-level calibration gas in direct calibration mode, parts per million by volume or percent volume 247.'.|Corn-x Measured concentration of high-level calibration gas in direct calibration mode, parts per million by volume or Dercent volume 247.0 CS Calibration span, parts per million by volume or percent volume Choose:Upscale gas range used for bias/drift check 0.3 Cs int,"r.lnitial measured concentration of low-level calibration gas in system calibration mode, oarts oer million bv volume or oercent volume 247.2 Cs initi"ru lnitial measured concentration of upscale calibration gas in system calibration mod6, parts per million by volume or percent volume 0.2 Csnnaru Final measured concentration of lowievel calibration gas in system calibration mode, parts per million by volume or percent volume 247.7 Cs nnalu Final measured concentration of upscale calibration gas in system calibration mode, oarts oer million bv volume or oercent volume 74 of 220 GP08 1AS-04 1 757- RT- 1600 I I I SAMPLE CALCULATIONS Sunnyside Gogeneration Associates, Unit EU#l RATA Compliance, PROJ-041757 EPA METHOD 7E CALIBRATION CALCULATIONS - Runl I tnfiialsvstem Btas - Low-Level Absolute Difference I t"r*'"""= csrnru"r+'Con.lISB6ru"rl(oin = 0.3-0 I SBinru"r(am = 0.30 choose Parameter Above t SBinru"u-ranl = o.3o Choose Parameter Above I Perecnt_sISpan I sB"** = (Cst,,61+'Cq3J / cs SBinru"u = (0.3 - 0) 1247 x100 f SBinru'u = 0.12 Percent of sPan I SBrnru"u = 0.12 Choose ParameterAbove I lnitialSvstem Bias - Upscale I Abrotrt"-Diff"r"n"" SBInrurl-u(atq = CS tnnt"l-u 'Gon-x I SBrnu"ru(o,D = (247.2 - 247.1) t SB"rr-rto,o = 0'10 Choose Parameter Above SBrnru"ru(oiD = 0.10 choose Parameter Above I Percentofspan SB6ru.1u = (CS tnru"t-tl 'CD1p{{} / CS I SBrnru.ru - (247.2 - 241.1) I 247 x 1oo I SBrnnuru = 0.04 Percent of sPan SBinurl-u = 0.04 Choose Parameter Above t FtnatSvstem Blas - Low-Levet Absolute Difference I SBnn1+(do = Csnn11'Con.l I sBnna,.(din) = 0.2 - o SBnnaurarn = O'20 Choose Parameter Above I sB*r*r*nr = 0.20 choose parameter Above Percent ofjpan I s# (Gsmru- - cDR.J/ csr sBnnarr - (0.2 - o) t 247 x 1oo - SBnnru- = 0'08 Percent of sPan I SBnnarr = 0'08 Choose Parameter Above I lhese resu/ts m ay differ stightly ftom therosults presente d in the rcporl. Differences can be aftibuted to signiftcant digit rcund-ofi discrcpancies, but should not be apparcnt until >3 significant figwes. I 75 or 2zo cp081AS-0417s7-Rr-1600 SAMPLE CALCULATIONS Sunnyside Cogeneration Associates, Unit EU#l RATA Gompliance, PROJ-041 757 EPA METHOD 7E CALIBRATION CALCUI.ATIONS I I IFinal Svstem Bias - Uoscale Absolute Difference SBnnat-u(riltf) = SBnnaru(ttrtr) = SBnnaru(drtr) = SBnnaru(drtr) = Percent of Soan SBnnat-u = SBnnaru = SBnnant = SBnnau.t = Drift - Low-Level Absolute Difference Drift116161 = Drift-116161 = Drift-116;61 = Percent of Span Drift-. = Drift-r = Drift-r = Drift - Upscale Absolute Difference Drifta116161 = DrifLul6i0 = Driftu16tn) = Percent of Span Drift., = Drift, = DrifLu = CS nner-u 'Corn-n 247.7 -247.1 0.60 Choose Parameter Above 0.60 Choose Parameter Above (cs nn"r-u - CDIR.H) / cs (247.7 - 247.1) I 247 x 100 0.24 percent of span 0.24 Choose ParameterAbove ISB nnrr{on? ' SBrnnr.r-r-(orDl 10.20 - 0.301 0.10 Choose Parameter Above lSBnn.r+ 'SBrnnr.r+l 10.08 - 0.121 0.04 percent of span ISB nn*u(ar1 ' SBrnmnl(aml 10.60 - 0.101 0.50 Choose Parameter Above ISB nnrr.11 ' SBrnru"r.ul 10.24 - 0.041 0.20 percent of span I I I I I I I I I I I Ihese resu/fs may differ slightly from fhe resu/fs presented in the repod. Differences can be attributed to signiftcant digit rcund<ff discrepancies, but should not be apparent until >3 signifrcant tigures. T I I I T76 of 220 GP08 1AS-041757-RT- 1600 t I T I I I I I I I t I I I I I T I I SunnysldG cotcncratlon Assocletat Unh EUfl RATA compllancc, PRoJ{41757 slltl2o24 nun rl ssmplc Calculadons EPA Mcthod 6C: DGt rmlntdon ot sulfur Dloilde Emisdons from statlonary Sources (lnstrumcnLl An.lyrcr Procedurel (/o cFR P.rt 60, Appcndlx A{l (C--cJxc-. (C" - Co) = (68.8 - (0.15)) x 99.8 (100.15 - (0.1s)) = 58.5 ppmvd (Eq.7E-sb) cd= (cJ (Mw)@ = 1.14E{5 lb/scl (cd) (F.) (100) (COr%vd) = (1.1aE-05) (1800) (100) (14.0) = 0,145 lb/mmBtu (Eq. 19-7) VarLblG valucc-58.8 \voraoe Unadiusted Ga8 Concontratlon DDMVdq0.2 \voraoo Pr€y'Post Zoro Gas ResDongs ppmvd 99.8 :oncantratlon of Upscale Callbratlon Gas ppm c-100.2 verege Pro/Post Upscalo Gas Roponso opmvd c*68.s \voraoe Gas Concontration Adlu8ted br Bias pomvd MW 64.06 \,!olmlerWeioht lb-mole 385.3 385.3 /olume of One Pound of ldeel Gas at Stendard Conditions scfllFmole F.1800 : Fac-tor from EPA Msihod 19 scflmmBtu Ca 1.14E-05 ,ollutant Con6nlraton, Dry Basl8 oound/drv standard cublc foot CO" %vd 14.0 , Concentrauon drv volume oercent F..0.146 :ml8sion Rate pounds per milllon British thermal units 77 of 22O GP08 1AS-041757- RT- 1600 I t I I I I t I I I I I t I T I T Sunnyslde Unlt EU fl 5lL6l2023 Run S1 Sample C.lculatlons EPA Method 7E: Detcrmlnatlon of Nltrogen Oxld6 Embilons from Statlonary Sourc.t (lnstrumentel Analyrer Proceduref (trc cFR Pert 60, A9pendlx A-41 (CO2%vd) = (2.54E-01) (14) (100) (14.0) = 0.291lb/mmBtu (Eq. 19-7) I I Varlablc Valu!).flnluon c.-t65.8 vsrage UnadJust€d Ga8 Concentration ppmvd c^0.3 ryeraoe Pre/Post Zoro Ga8 Rosoonse oDmvd c-,247.1 :oncsntration of Upscalo Calibratlon Gas oDmc-247.5 \v6rag6 Pro/Post Upscale Gas Reponso ppmvd c-.r65.5 Neraoo Gas Concontration Adiustod br Bias ppmvd MW 46.01 tlol€cular Wdght lb/lFmole 3E5.3 385.3 y'olume of One Pound of ldeal Gas at Standard Conditions scfllb-mole F.1800 : Fac,tor from EPA Method 19 scflmmBtu cd 1.98E-05 rollutant Concontration, Dry Basis pounds per standard cubic foot CO, o/ovd 14.0 lO, Concentratlon drv volume Dercent F..0.zil :mlsslon Rate pounds per million British thermal units 78 of 22O GP08 1AS-04 1 757- RT- 1600 Sunny3ldc Unh EU 11 s/1612023 Run fll Samplc Calculatlon3 EPA Method 10: Dctermln.tlon of Csrbon Monoxlde Emlsslons from St tlonaty Sourcas (lnnrumcnt l Analyrer Proccdurel (/o cFR Part 60, Appendh A-41 Varlablc Yalua )eflnldon c.-14.O \veraoo Unadlusted Gas Concontration Domvdq0.'r Woraoo Pr6/Post Zero GaB RosDonse ppmvd c-25.3 loncentraton of Upscalo Calibration Gas ppm c-25.6 \vorago Prs/Post Upscalo Gag Reponso DDmvd 13.8 ryoraoe Gas Concentration Adiustod for Bias D9mVd MW 28.01 tlolecular Woight lb/lb-mole 385.3 385.3 /olum6 of Ons Pound of ldeal Ges at Stendard Conditions scfllb-.mole F.1800 = Fac,ior from EPA Method 19 scflmmBtu Ca 1.008-06 )ollutant Conc€ntration, Dry Basls pounds per standard cubic foot CO, Tovd 't4.o , Concantration drv volume oercent F.-0.013 :mission Rats pounds per million British thermal units cd= (C*) (Mw) ("rl (r"":, (COr%vd) = (1.00E-06) (1800) (100) (14.0) = 0.013 tb/mmBtu (Eq. 1*7) Sunnyside Unit EU fl slt6l2o23 Relative Accuracy Test Audit Sample Calculations NO, (lb/mmBtu) Run # RM CEM Abs. Diff t t I I I I I I I I t I I I I I T I I d2 o.271 nla nla 1 2 3 4 5 6 7 8I 10 11 12 0.2il 0.268 0.257 0.273 0.253 0.268 0.251 0.2660.250 0.269 0.257 0.256 0.zilo:.' 0.276 0.274 0.272t:, 0.014 0.016 0.015 0.0't5 0.019 0.0'19 0.018 0.018 o'rn 0.00020 0.00026 0.00023 0.00023 0.00036 0.00036 0.00032 0.00032 0.00036 Average Sum Sum2 o.254 nla nla 0.017 0.153 0.0234 0.00029 0.00263 nla cc=-(@- Vn = (2.306) (0.002) 3 = 0.002 RA= ld l+ lccl RM = 0.017 + 0.002 c.254 = 7.396 (100) (100) Variables Id'0.00263 Sum of the Squared Ditferences tldil'0.0234 Square of the Summed Differences n I Number of Test Runs sd 0.002 Standard Deviation of Differences b.ogzs 2.306 T-value from PS2, Table 2-'1 cc 0.002 2.5% Confidence Coefficient tdt 0.017 Absolute Averaoe Difference I CCI 0.002 \bsolute Confi dence Coefficient RM 0.254 Averaoe RM Value RA 7.3o/o R.elative Accuracy 80 of 220 GP08 1AS-041757- RT- 1600 Appendix B Facility Process Data 8l of 22O GP081AS-041757-RT- 1600 Appendix 8.1 Unit 1 82 of 22O GP08 1AS-041757-RT- 1600 ooroF{IFdINt,NFIsfoIor{@oo-ooNNono@ Eb.A=Eoo-o1r 'o6zzl cu > io -t:. : t =o ;i l-- o 1'gEc L e=o?ao lr ll a= -6.9 ci f; : - i 6 ig E on i ll n (J * E o= oLcooO E*Eo o=x) lU O o lr I E II J F tN 6, 8 IE E != c x 5g E '= a [ o i. o ;r , E r= & N E [ 6 3 E S b E I F E g I S ] E E R I I Eg F d FF F F F ; F Fe F C t ci c i c i o c i ci o c i o o ci ci o o o o o ct o o o ci c i o c , ao l a q q l r : q1 . : c ! o r e q q q q \ a o 6 r6 N n - - s 6 e E s i s E d a : J t ; fr s d s s s E sE l E ' - - -r - OF O O FF ri r i @ c i aN N F F 6 6 N n 6 6 F 6 O O F t s @ @ O O O O F O @ F @ FF NF 6 6 @ N 6 6 N 6 N N t s , @ @ O F @ @ F F @A F O N N N N N N N N N N N N N N N N N N N N N N N N N N @ oo o cr c i c r o c i c i o c i o o o ci o o o o o o c t o c i u t .q a ? o ! c ! - Aa ? n a l r q . q l - q q q c ? a r o N@ o o r I 6 6 6 o o o n a o o u i * d 6 (i i o o o q B E 8 3 B ** O i O O O O F @ @ F F O F O 6 @ @ t O t N O O F A Ii p p p r s x N r i r p s E E b E e p p R E EE P f l ** -. q c q q u l q C q r q q a q q \ q \ \ q r o FN o o F ? o6 6 o N o n 6 r r o r N ! d d F a i d o c i ci o i o o N N .D (D @ 6 @ @ (o 6 @ O lo O @ (o (o . O @ O O @ F @O t s C o o o o N e @ N o N o t o @ i Q q E A q q ! a? q q \ =I : .i d ; c i a i . i 6 i ; o t d . i a i G i d r i s i 6 ; a i o o i ; oic i o r o NN 8 E R: 8 S F g S P 9 F T S E 8 E P R 8 3 ST F 8 ci d d { d o d d { d d * o ? r t ! d d d d o ' d o o r t F F F F F N ts t s F t s F F F N t s F F F t s F F FF t s t s . F FF - @ . o o O F O O r O - O O O O r O O O o O O - F ii a + + + a $ + n $ i { r { + Y i i s i i ci + d + r NN - -- - K $5 E E € € E rE ! E f r E ' oEof DgEE ol \ q \ e ol 0c \ o! !: o l 0q q. q q e e q q I I @o o o o o o 6 0 0 0 0 0 0 0 0 0 0 0 @ o @N o O O F N O i O O N @ O O F N O ! O O oo o o + 1 9 t { 3 9 ? + t a o o o o o o 88 B 8 e S 8 e 8 8 8 8 8 8 8 8 g e B e e sv l ! = ! ! !! q ! ! ! i f !r ! 3 v g dN N N N N N N N N N N N N N N N N N N N BB a a a B a a B a a a a a a a a ; a a ; dN N N N N N N N N N N N N N N N N N N N ts B B E B B t s B B t s B t s B E t s t s B B E B A ,H E= frO)o fi B o( \ lA tc (o : iE x. 0 s 5' E \g P - r. \ O F- ! - ;H = E E H Ef l g g s t o E- e ' d. = a E= $? =L E a .. F :E ' u. 9 (E o ) o- u Loo-o, t -. ()(: IIIIIIIIIIIIIIIIIII IT oo+l h;r sEIII b E E E P P E F i E E E P F H E E E E i F S EI P P F& oo c i o c t o o o c i c i o o c i o o o o o o o o oo c i d oo r @ o o N N n F g o o o \ o N q o a q .: o 9 q q : I ; ! E i E : E E I E E s N i E I E S i g : g :e E 3 *' 6i OF ? @ FF ri d c i a i NN 6 o N o N o o 6 6 O 6 @ O F = O O O + N - O@ O @ FF F F N F t s t s t s N 6 t s F 6 6 F F N @ F F t s F NO F N N N i! N i Y i v i ! . ! N N 6 . N N 6 I d . N N N 6I N N N N N N N t s oo oo c i o o o ci c r . c i o o o o o o c i o c i o ci c i c i d q q q q , : 1 a q q .! 1 c! - I q : - .: c? o F N 6 @ 6 rF 6- 6 6 6 6 6 D 6 6 6 h 6 o o o o o o r i d rt i d c i N N 66 1 6 o 1 6 6 r l ' D o o D 1 l l o 6 o o 6 o o o o oD o D -. O (o O O - () - N O F A O N N N O I F O @ D NN t s Q Fi :; ; ; " i ; ;; ; *c t c , c i - a o ; d d @ o o dd ! 6 i N N @r a F 6 a d F F ( 6 F N F 6 6 o F o O F t s 6 O Fo o B .. qe ? e q q q ( | c ? q . : N ! N r N t ? N N o o Nt s N o - F 8 E E E E q i ; E E E E E E E E E E E E P EE i f r . * o- O O O F F O O t O O I @ O O o, o , o O O O O O O a - @ FF ni J + s i ; ; ; - ; ; + d ; ; c i + d d + + dd e 6 i N N - -- - t ( OO O @ O O O O N F N O O @ e O O O O @ O ct ri s i d ri ai d r i d c , 6 d d u i o d d u i ri d ri II o:l @ I trio :, E ..JioIAo=c L ?==r !oo il l la) tIIIIItt a@.9 dE6 E e3 . B 6' , > ou ; ll t t o E o=oLcooO tl *Eo o= xJ II J O c o rn Y t UJ F t .E * FL O .= r! EE I l 6E E I. - C '= ( ! O := o ;, , E r. r - E & q, : q, : \ q a q tq : c? . : E c o! c q -q q t o oo @ N == o + N o o o F F o o <i oi o r i d i o - - o u i + o c i - 6 sa I S I E B F 8I g E I E I5 I 5 5 P R I E P: 5 P ui + i r i a r d t + r t d c t : d a t d r i i r t d d d v t i { r r d d i E i N N L N N t s N t s N t s N F F N N t s t s ts ts t s t s t s - -- - 3 - $E 5 E fl * € 9= } P : 9 P : P 9 R F N R X 8 8 N R I o o ci d o ci o <i o o ci o ci c, o o o o o i I IE E H f E t - BE EC r < - ? l r t l I t n t { t ! ! r ! s I t E= d d N N d N N N N N N N N N N N N N N N N 6! a A a ts a a a a a B a a B a a a a ts d d d <p dN N N N N N N N N N N N N N N N N N N it i , i , ;l i t B B B B B ; B a B A nr n B A B B <t o 6 C , 6 6 6 6 6 o o O ('O O O O oo o o $E = z2fa - :l -, LF i^ aO =E8go)oA (Q - daoqU' J ac c9 l oEa- =5 rFao dl ==5t s zJF^FO fr 3 N^89 (o o - () o -=- x^9= ' ocge , 3€9g ltvoOo9o& 0)6:,Eo0LrJoozz:)o IP .n t*H '6 4O 6 t ^ s E8 G: ;- E 6g E TE ,1 E E- ! - ;H = E E H O) P : . e ci E Eq S S ; H o € 0' 8. E a E= fr f = r( , t r ) o' = @ .. FE r- O (E ( l ) ao - EoCLot .t+s.)AZ oo(oF{IFdINtlNFI+oIVI F{@od(,oNNotn@ bb0lEo-d,uleU'zzf, EA Io EE {. s=o ,t o E'gEG L tA€hao il l lU' ) -o .9 rc i Ft E =o a =o _ 6 oa i ll rl O. o o: oL tr O l! ( J tt rEo o= xJ Lt J O cn uu P I. I J F !tN -6 eg $ ,= l ! ! Et r X b€ E EE 6 5. 9 rr l l l uE p E E F } E E E fi P S P E F H H H F 3 fr E i ES f r P EF ac ; d o c ; o d d o o c i c r o c i o o o c i o o o oo o i @ o o b o F N o o o ts Q I o o o q q u! t: q q q q q == H e N g s N b r e $ d P P I N N S E S E B 8S I E "' - -x - 6N F N F- ri 6 i c i d NN N N fr R x $ F H & R $ E \ H { & & & e $ { E && f r f r 5F a; i i c i d d d d o o o o o o o o o o o o o oo d d NO @ F FF rir d o i NN o6 0 0 a o o - o o o @ i N o ry q r q q r r a q q ry qq c l q 55 s ts r I I E E E I E N I I 5 E I t E E E E 83 E i "" j oo N N N o o Nt 6 o o o @ @ ( 9 q ! o l Q q 3 qq q a ? = = a g a a E s sr s d e at E I E [i u a a g I E6 R 8 *- - -- - : - ot s O N l ! N ! O N F O F 6 o o F ! t a O l l no O P r i H n HE RE i gi E Ef ; k $ fi . { p . i $ fl g u. i . $ . p . ' * A+ + r t { d { + a i d i @ o rt d i o !o ! tt d t ir r ' d t : i FT . T i F F F . i F t . F F F F F t s F F N F t s F Fh F E I - -- - ; - O@ O O -F dd + 6 i dN -- - R 9r E 9 t 9 s f f 6 $ E S 8 f r h f r A E E E o oo o o o o oo o oc i o c, o ci ". . i * EE E E E i E " " " " " " ": " ". : : ": " " =. " " EE s s s s s s s s s s s s s s s $ s s s s s Ei NN N N N N N N N N N N N N N N N N N N N T 8t s t s 8 t s t s t s t s t s 9 t s t s t s t s 8 t s 8 t s t s 8 t s ol ot q q, o q of \ q I q o o o o o o o o o o o ri ut o d d d d r i o c t o ri d d ri d d d d d o e r q q a I q. ! q o i o o q ! ! 1 q ! r y , N o Ii gE E 3 3 E EE E E TB 3 3 E 8E E3 8 o o o Q o! o q Q q q q q o! ol ol q q o! ol q ol n, o o a, ri F, * i fi i ri d i d ! i ct d i + r d ! i t i ri I $= eF s AE E fi B (t r 6 l od ,fr $g (! : -t r ^ d 6 EE NE o $E E E; o 6= d s' E O) R . . e ci E E q gF ; E o # o- ts . 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(+ t !l ooEl hHl :El 5 : T 8 f , E E 8 B F E P 8 8 8 9 8 8 S B E E t E } EE R N f l F F N - e N N N N N N - r F F- N I o. o o o o c i o oo o . c r o o d o c i o o o o o oo d * o @ o O - F O F ! .o o N N I N N @ e o F N O? @ r F- S E E r : I : E e p s E l r r p g s I : 3 Es s g *' .. i ON F N ?F dd c i a i NN oN O F FF d+ r i d NN o6 6 6 O{A O FF ts n t s c i NN oF o ( @.- I a c? Q q . ! q q I q \ .! C ol o l q q q o l r t @o N F == g E E E a Bg , u u u g a E I s b E I E B I E i g E - ' - -- - ; Oo F @ er ci d + 6 i NN -- - & t t: o l q - o! . q q \ o! q q C q q C ol q o! C q o6 o o o o o o o o @ 6 o o b o o o o o @ IIIt oil Ol IItIIIItI a,IbsUJeU'zzlU' OO @ O ?F ts o t s @ N N NN N O oo o d 60 0 F o @ o t s o @ o o F o o o q @ o N t s 60 @ t s N F t s @ @ @ F F F @ O t s F O @ F @ NN N N N N N N N N N N N N N N f l NN N N ci c i o c , o o o o o ci c i c i o o o o o o o d o EIo :EE. eeo rl I3.= cL 6E =Goo il l la) -o.9 << , F; E =0 J r r :o b Eo > ou i Il tt o. 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F 'c t ij oc'E (o o Eo - LIou IIIItIIItIIIIIIIIl. n l> * . 6F N O t o. o o 6 0 oo o o 6 nt a t l NN N N N al a a a NN N N N ts 5 8 8 t s I !l oo\o+l EHl sEIIIII Rgl gr ItIITTtII oar ,E&l!o</ )zzfU) -@.9 . o FU E Et 8 oa i ll tt o. E EE e. o oO !l *Eo 9E UJ O cD lr u B II J F ? !tN o, i 61 9 H ,= t! Et r X 6€ E '= a E o i= o ;, E r. r - E p cio pE tu i=o :l rt' o E'o.= CL 6a :. EU' O il I l a) oF o o 0 0 ui - - o i F6 O t s oo o 6 pT P g ?F F 6EE E E E E E ET -F qt c c r : oN o F F E 5 =. 8 - 8. lt o o l ts t s F F F O? N O l Qi i ? l oo o o o i? i ! i NN N N N bl n r a A N, N N N N ts 8 t s 8 t s 3f ; = rlrtP a$*H (, (v ) *a Eg fr e g eE ;g = E E g or P : . e ii E SE E F B E a $= fr ? 5 8, E a .. F TE ooE( L Egod. _9)5 ooroF{IFd.Ir\ ttF{\roIoH@oCL(9 t IIItIIIt E EB ON c, (V ) I e! 6 ' it R6 c: ;- E E gE ;E o $E E E; o 5I c e' E o) R . . e 6E HE E F B E a E= fr ? 5 8. E a .. F +j B L (E ( D tr ( L tIou. oNNooiO't d'dt5EItr . loozzf E t, io pB (! =?o :I,t o !toEG L '5 l = aD 1e €E U' O Il lo) o .9 dFu - E -5 8 8 od i ll tt O. (D(r ,rii tNasoiiEb6,oEBt 6 o: (, Lcoo( J t! sEo 9E rr J O [i l II J Fo og .= rE Hg g. E '= r! 5. nl ! r. r - !E ci t s c i o i il 5 8 F E. g E f rE E E i E u ac ? \ \ q Ots r F N Es S E E d. r ' r i + o ts F F t s t s - b 8 6 s E i l x d r - o 6 0 0 0 E EE 6 n l = Cr -i l +r r l s &N N N N N ea a a a NN N N N 8t s t s t s t s r,t II ooro+l hHl sEIIIIIItIIIITTt t oNNooo olr taEoUJ(f6zzf cq , !o EE r! =ZO -l llatto.E cL 6a :( ! .D O il l la) -o.9 . o E; . E ET B oi ; ll tt o. sP!te(t,so8to6(,EBt 5 o: (,Lroo( , !, -Eo 9E u, l o lt Iut l-o o9 .= ( E x. E '= ( E5= tt ll u- E g EE .g r! fr u c o ) =* = 6E e e' E ? H5 E Ef ; Hf , c s ;E ET = EE U, UF L; O LLff , $t \a \ u ? 60 E8 8 E i( , i c ) SP p N !E E f * E E EEE€ .q q a a \ 58 8 8 8 N! a u t u ) i rt i c t d i d Ft s t s N F ia l ! l NN N N N ae a ; a NN N N N 88 t s t s t s eo)V O- N O ? 60 0 6 0 .H f = oo\oF{IFd.Itr lNFI$oI(/) F{@oo-(9oNNsoFIoFI Eo.A:,EoIuloozzf EO io EEZ6 tr o !,oEE L aa€E@o Il t@) -@.9 . o Fa . E Et $ on i ll uOt TPtlNgt$oEEo6oEId o 8= EOoO !sEo 9E UI O ll i l I. I I F o o9 .= ( ! ECEE '= G5. ul l tr E 33 3 3 ' " 58 $ t gg E $ $E E E E E f gE f, E -F o! q q . ' ! q ?N N O O 6t s F t s N ('o a o ( r ) +c t d d o Nt s F F F $O - N O i OF I A - ;; a r ; ; 5F 5 o d rl r ! i TN N N R N Be a a i r NN N N N BE E t s t s i SB .a N _ E gc tU a ?+ E ad = 6 :( ' = (U E < 6E ? HE E EE Ef l g g : E 9 H€ EE < E HE a ii F .i . j o LL#f , eot IIIIIIIIIIttIIIIIIl' i tIIItII oN:TI ITtIIIIIt E ooroil IFdIlnFItoIoF. l@oo- (9 bofE&lr loozz:)o@d.E6bTEts(!lr ,clE6eboEIE. C'o E1 0 (ll = -c . o :IloEoEo . n' E =( Eoo il l l .h 3 oEr E8 . E9 oi ; ll rt O. 6 8E EOoO !l sEo9= II J O ll I u. t Fo or 9 .= ( EEf '= (! 5= Il luE an q a (, o @t s o N oio 6 dc i d j Ft s t s t s *E 5 E E* E IE E H E E ' 85 tEdEgo -F qq c ! q c ! J'O 6 6 F 8N S g $ dc i r t i r i ts t s t s t s N 90 @ N O O ^9 { a i { ! X lE - .\ i . , i . i c i . i 5F 5 o -G *r r r l TN N N N N el i a a NN N N N DE D B E IS a$*H (. ) 6tt c, 6 i ^ .3 P. E Eg € YE O EE E E; o b= o . 3 ' E o) P: . e i. i E St E E B E a 3= $? E I'' E J O. = a .. F EEEbEo . tstr Ozl s b ooroF{IFdIttF{$oI@F{@oo- (9 bc,E$UJoo22f EU ' !o EE .! ==6 ;r o_o Nt\bo EP --3FE3 lo l P€Eoo Il l@) ociEoolf l tfPts$oiiEb6oEIr o.E rEI E9 . oa i ll tt O* o 8E c. o oOEa9E ru O Il l II J F0, og .= . EHg s. ! '= G5= tt ll rr - E 'q q r ? I o', , 3F E $ EE E E E E $ IE63 c6 !, q \ q q -O N O O 88 3 e F dr i d 6 r t Nt s F t s t s oo F o o 66 6 0 0 c, i , d . i . i ci di tit i i NN N N N BA A a A NN N N N 0t s t s t s t s E $. = .B E= ES EN e9(E N o aY l fi $8 <o : s. 2 6 gE YE o $E = E; o 6= a s' E o) P : . e di E $ EE F B E a 3= $? 5 8. E a .. F aE L (E O tr ( L LI& Il, .i I IIIIItIItIItIIII I !l ooID+l hHl sEIIIII oNNosfo o6Jto&lrJoU)zzf EO !o =EZO rA 1'g.E cL 6z :. !ao il t t .t ) ) e@E; Fr . E Et $ ol i ; ll rt o. lOIu)\tc!G)soE.Eo6oEIt IIIIItIII o 8= cocO t*Eo 9E l! O Ii l II J Fo (r 9 .= ( Eb* '= o5= tt ll r. u E (DoP a+*HE$ s o ) -c - l 6 EE TE ? H= E E€ Ol P . . e EE $i E F B E e E= $? E lr ) t r d :F ,EooE( L Eoo-oE. E[ E g "' gE E E EE f EE !T \q c ? e a Ft s @ O O 6F O O F 6- O N o oo 6 t o ts ts N t s , t s gE E f l g o, o o o o g 8= EF 5 o6 l3 t t l NN N N N ee a l a NN N N N BN ' A B B oo 6 0 0 +2x Appendix C Quality Assurance/Quality Control GP08 1AS-041757- RT- 1600 Appendix C.1 Units and Abbreviations GP08 1AS-041757-RT- 1600 I I 6.i\ l*?.N,T+g,S.H I I @Xo/oo,2 lccl tdtoc oF oR 'Hzo 13.6 AH AP 0 pg Pa tu acfm A" A Btu B* c" Caw Cor, cf or ft3 ctn Cc"" cM cm or m' cMA co cp c, CS cs a D dcf dcm Dn D" dscf dscfm dscm Fd fpm fps ft f( UNITS OF MEASUREMENT corrected to X% orygen (conected for dilution air) absolute value of the confidence coefficient absolute value of the mean differences degrees Celsius degrees Fahrenheit degrees Rankine inches of water column specific gravity of mercury pressure drop across orifice meter, inches H2O velocity head of stack gas, inches H2O total sampling time, minutes microgram density of acetone, mg/ml density of water, 0.9982 g/ml or 0.002201 lb/ml actual cubic feet of gas per minute at stack conditions cross-sectional area of nozzle, f cross-section al area of stack, square feet (f) British thermal unit proportion by volume of water vapor in gas stream particulate matter concentration in stack gas, gr/acf average unadjusted gas concentration, ppmv measured concentration of calibration gas, ppmv cubic feet cubic feet per minute average gas concentration adjusted for bias, ppmv average of initial and final system bias check responses from upscale calibration gas, ppmv cubic meters actual concentration of the upscale calibration gas, ppmv average of initial and final system bias check responses from low-level calibration gas, ppmv pitot tube coefficient particulate mafter concentration in stack gas, gr/dscf calibration span, % or ppmv measured concentration of calibration gas, ppmv manufactured certified concentration of calibration gas, ppmv drift assessment, % of span dry cubic feet dry cubic meters diameter of nozzle, inches diameter of stack, inches dry standard cubic feet dry standard cubic feet per minute dry standard cubic meters F-factor, dscf/MMBtu of heat input feet per minute feet per second feet square feet gram gallons grains (7000 grains per pound) T I I I T I I t T I I I t I I s gal gr 7O7 of 22O GP08 1AS-04 1 757-RT- 1 600 64\ l,l?N,T+gLE- gr/dscf hr I in k K K3 & kg 1(, kwscfh I lb/hr lb/MMBtu lpm m M m3 ma Md meq mg Mg min ml or mL mm MM MMBtu/hr mn mol mol. wt. or MW Ms I\,TVV n ng nm Nm3 DI bar ps Ps Pm ppb ppbv ppbvd ppm ppmv ppmvd ppmvw Ps psi psia psig UNITS OF MEASUREMENT grains per dry standard cubic feet hour percent of isokinetic sampling inch kilo or thousand (metric units, multiply by 103) kelvin (temperature) conversion factor 0.0154 gr/mg conversion factor 0.002668 ((in. Hgxft3)[((mt)("n)) kilogram pitot tube constant (85.49 fUsec) thousand wet standard cubic feet per hour liters pounds per hour pounds per million Btu liters per minute meter or milli thousand (English units) or mega (million, metric units) cubic meters mass of residue of acetone after evaporation, mg molecular weight of stack gas; dry basis, lb/lb-mole milliequivalent milligram megagram (106 grams) minute milliliter millimeter million (English units) million Btu per hour total amount of particulate matter collected, mg mole molecular weight molecular weight of stack gas; wet basis, lb/lb-mole molecular weight or megawatt number of data points nanogram nanometer normal cubic meter barometric pressure, inches Hg picogram stack static pressure, inches H2O barometric pressure of dry gas meter, inches Hg parts per billion parts per billion, by volume parts per billion by volume, dry basis parts per million parts per million, by volume parts per million by volume, dry basis parts per million by volume, wet basis absolute stack gas pressure, inches Hg pounds per square inch pounds per square inch absolute pounds per square inch gauge I I I I I I I I I I I I t I T t I I I108 of 220 GP08 1AS-0417s7- RT- 1500 I I I I I I I I I I I I t t I I I T I M l'l?,N,T+g,s.H P., Q" Q" Qat R S4n"r SBr scf scfh scfm scm scmh sec sf, sq. ft., or d std t T o.gzs T" Tm ton or t tph or tons/hr tpy or tons/yr T" T*a V vs V"* Vt" V, V51aa) v* vn vs Vvq*d) V*i("ta) Vms(std) W w8 Wrrp Wss UNITS OF MEASUREMENT standard absolute pressure, 29.92 inches Hg volumetric flow rate, actual conditions, acfm volumetric flow rate, standard conditions, scfm volumetric flow rate, dry standard conditions, dscfm ideal gas constant 21.85 ((in. Hg) (ft3)(f R) (lbmole)) post-run system bias check, % of span pre-run system bias check, % of span standard cubic feet standard cubic feet per hour standard cubic feet per minute standard cubic meters standard cubic meters per hour second square feet standard metric ton (1000 kg) t-value absolute average ambient temperature, oR (+459.67 for English) absolute average dry gas meter temperature, oR (+459.67 for English) ton = 2000 pounds tons per hour tons per year absolute average stack gas meter temperature, oR (+459.67 for English) absolute temperature at standard conditions volt volume of acetone blank, ml volume of acetone used in wash, ml total volume H2O collected in impingers and silica gel, grams volume of gas sampled through dry gas meter, ft3 volume of gas measured by the dry gas meter, conected to standard conditions, dscf stack gas volume sampled, acf volume collected at stack conditions through nozzle, acl average stack gas velocity, feet per second volume of water vapor condensed, conected to standard conditions, scf volume of water vapor in gas sampled ftom impingers, scf volume of water vapor in gas sampled from silica gel, scf watt weight of residue in acetone wash, mg total weight of impingers, grams total weight of silica gel, grams dry gas meter calibration factor, dimensionless GP08 1AS-041757-RT- 1 600 64\ l+?N,I+gp.H AAS ACDP ACE AD ADL AETB AS ASTM BACT BDL BHP BIF BLS cc CD CE CEM CEMS CERMS CET CFR CGA CHNOS CNCG co coc COMS CPM CPMS CT CTM cro CVAAS De DE Dioxins DLL DNCG ECD EIT ELCD EMPC EPA EPRI ES ESP EU FCCU FGD FI FIA FID FPD FPM ABBREVIATIONS atomic absorption spectroscopy air contiaminant discharge permit analyzer calibration enor, percent of span absolute difference above detection limit Air Emissions Testing Body applicable standard (emission limit) American Society For Testing And Materials best achievable control technology below detection limit brake horsepower boiler and industrial fumace black liquor solids confidence coefficient calibration drift calibration error continuous emissions monitor continuous emissions monitoring system continuous emissions rate monitoring system calibration enor test Code of Federal Regulations cylinder gas audit elemental analysis for determination of C, H, N, O, and S content in fuels concentrated non-condensable gas catalytic oxidizer chain of custody continuous opacity monitoring system condensable particulate matter continuous parameter monitoring system combustion turbine conditional test method catalytic thermal oxidizer cold vapor atomic absorption spectroscopy equivalent diameter destruction efficiency polychlorinated dibenzo-p-dioins (PCDDS) detection level limited dilute non-condensable gas electron capture detector Engineer ln Training electrolytic conductivity detector (hall detector) estimated maximum possible concentration US Environmental Protection Agency Electric Power Research lnstitute emission standard (applicable limit) electrostatic precipitator emission unit fluid catalytic cracking unit fl ue gas desulfurization flame ionization fl ame ionization analyzer flame ionization detector flame photometric detector filterable particulate matter I I I I I I I I I T I t I I I I I I T110 of 220 GP08 1AS-041757-RT- 1600 FTIR FTPB FTRB I I I I I I I I T I I I t I I I I 6.i\ lf?N,T+gL"E' Furans GC GC/MS GFAAS GFC GHG HAP HC HHV HPLC HRGC/HRMS HRSG tc ICAP ICPCR ICP-MS IR rso KW LFG LHV LPG MACT MDI MDL MNOC MRL MS NA NCASI NCG ND NDIR NESHAP NG NIOSH NIST NMC NMOC Ntt/MOC NPD NSPS OSHA PAH PCB PCWP PE PFAS PI PID PM ABBREVIATIONS Fourier-transform infrared spectroscopy field train proof blank field train recovery blank polych lorinated dibenzofurans (PCDFS) gas chromatography gas chromatography/mass spectroscopy graphite fumace atomic absorption spectroscopy gas filter conelation greenhouse gas hazardous air pollutant hydrocarbons higher heating value high performance liquid chromatography high-resolution gas chromatography/high-resolution mass spectroscopy heat recovery steam generator ion chromatography inductively-coupled argon plasma emission spectroscopy ion chromatography with a post-column reactor inductively coupled plasma-mass spectroscopy infrared radiation I ntemational Standards Organization kilowatts landfill gas lower heating value liquified petroleum gas maximum achievable control technology methylene diphenyl diisocyanate method detection limit maximum normal operating conditions method reporting limit mass spectrometry not applicable or not available National Council For Air And Steam lmprovement non-condensable gases not detected non-dispersive infrared National Emissions Standards For Hazardous Air Pollutants natural gas National lnstitute For Occupational Safety And Health National lnstitute Of Standards And Technology non-methane cutter non-methane organic compounds non-methane volatile organic compounds nitrogen phosphorus detector New Source Performance Standards Occupational Safety And Health Administration polycyclic aromatic hydrocarbons polychlorinated biphenyl compounds plyrvood and composite wood products Professional Engineer per- and polyfluoroalkyl substances (PFAS) photoionization photoionization detector particulate matter ttL of 22O GP08 1AS-04 1 757-RT- 1 600 6.1\lt?N,T+gp.I PMro PMz.s POM PS PSD PSEL PST PTE PTM oA/oc QI QSTI RA RAA RACT RATA RCTO RICE RM RTO SAM SCD SCR SD Sem|-VOST SRM TAP TBD TCA TCD TGNENMOC TGNMOC TGOC THC Ttc TO TO TPM TSP TTE ULSD UV VE voc VOST WC WWTP ABBREVIATIONS particulate matter less than 10 microns in aerodynamic diameter particulate matter less than 2.5 microns in aerodynamic diameter polycyclic organic matter performance specifi cation particle size distribution plant site emission limits performance specifi cation test permanent total enclosure performance test method quality assurance and quality control Qualified lndividual Qualified Source Testing lndividual relative accuracy relative accuracy audit reasonably available control technology relative accuracy test audit rotary concentrator thermal oxidizer stationary reciprocating internal combustion engine reference method regenerative thermal oxidizer sulfuric acid mist sulfu r chemiluminescent detector selective catalytic reduction system standard deviation semi-volatile organic compounds sample train standard reference material toxic air pollutant to be determined thermal cond u ctivity analyzet thermal conductivity detector total gaseous non-ethane non-methane organic compounds total gaseous non-methane organic compounds total gaseous organic compounds total hydrocarbons tentatively identifi ed compound thermal oxidizer toxic organic (as in EPA Method TO-15) total particulate matter total suspended particulate matter temporary total enclosure ultra-low sulfur diesel ultraviolet radiation range visible emissions volatile organic compounds volatile organic sample train water column waste water treatment plant I t I I I I I I I I I I I I I I t I Itt2 of 22O GP08 1AS-041 757-RT- 1600 I I t I t I I I t I I I I I I I I I I 64\ l+?N,T+glI CHEMICAL NOMENCLATURE Ag silver As arsenic Se Soz Sos SO, TCDD TCDF TGOC THC TI TRS Zn selenium sulfur dioxide sulfur trioxide sulfur oxides tetrachlorodi benzodioxin tetrachlorodi benzofuran total gaseous organic concentration total hydrocarbons thallium total reduced sulfur compounds zinc Ba barium Be beryllium C carbonCd cadmiumCdS cadmium sulfide CH2O formaldehyde CH3CHO acetaldehyde CH3OH methanol CHr methane C2H4O ethylene oxide CzHe ethane CaH4O acrolein CaH6O propionaldehyde CgHs propane C6H5OH phenol Clz chlorine ClO2 chlorine dioxide CO carbon monoxideCo cobalt COz carbon dioxide Cr chromiumCu copperEtO ethylene oxideEIOH ethyl alcohol (ethanol) H2 Hzo hydrogen water HzOz hydrogen peroxide HzS hydrogen sulfide H2SO4 sulfuric acid HCI hydrogen chlorideHg mercuryIPA isopropyl alcoholMDI methylene diphenyl diisocyanate MeCl2 methylene chlorideMEK methyl ethyl ketone MeOH methanolMn manganese nitrogen ammonia nickel nitric oxide nitrogen dioxide nitrogen oides orygenP phosphorus Pb leadPCDD polychlorinated dibenze'p-diofnsPCDF polychlorinated dibenzoturans N2 NHs Ni NO Noz Not o2 antimony tt3 of 22O GP08 1AS-041757-RT- 1 500 Appendix C.2 Manual Test Method QA/ QC Data cP08 1AS-041757-RT- 1600 I I I t I I I I I I I t I I I t t I I At-009Runl Run2 Run3 Average: Apex xc-522 512312024 Cogen Sunnyaide EU #1 At-009 Post Meter Cal. % Dlfference, Callbratlon muet be wlthln 5o/o ol orglnal Y Factor Average GP08 1AS-041757-RT- 1600 Montrose Atr Quality Services 6823 South 3600 West Spanish Fork, Utah 84660 (801) 7e4-2s50 (801) 266-7111 Meter Box Calibration Data Form (English Units) I I I I I T I t I I I I I I I I T I I Date 1t5t2024 Average Yi 1.006 Orfice Manometer Setting AH 0.50 1.00 1.50 2.OO 3.00 4.00 Barometric Pressure 25.78 Meter Box Number APEX XC-522 DGM No. 20227130 Average AH Calibrated By Std Meter Yi1.695 JA 0.99497 lnlet (Td i) "F 59 65 66 71 71 78 77 81 76 79 78 82 Average (Td) "F 60.50 65.00 69.50 74.00 74.75 76.75 Yi '1.004 1.011 1.010 1.007 1.004 '1.004 Average Yi 1.006 Std Test Meter (Vs) Ft3 5.002 5.001 10.005 10.004 10.004 10.009 Dry Gas Meter Ouflet (Td o) "F 58 60 61 62 62 67 67 71 71 73 72 75 Dry Gas Meter (vd)Ft3 4.938 4.928 9.903 9.959 9.933 9.924 Std Test Meter (Ts) "F 62 62 62 64 64 66 66 68 68 70 70 71 Time A Minutes 11.53 8.15 't3.53 11.58 9.22 8.00 AH/13.6 0.M 0,07 0.11 0.15 0.22 0.29 Std Test Meter Average Temp. 62.00 63,00 65.00 67.00 69.00 70.50 AH 1.7',!1 1.701 1.757 1.715 1.639 1.648 Average AH 1.695 GP08 1AS-041757-RT- 1600Lt6 of 220 242 71 71 245 71 33 72 237 71 72 248 71u 72 246 72 70 245 71 33 72 251 71 72 244 73 34 72 I I I I I I I I I I t I I I I I I I I Montrose Air Quality Services 6823 South 3600 West Spanish Fork, Utah 84660 (801) 794-29s0 (801) 266-7111 Sample Box Temperature Sensor Calibration Form Sample Box Number: lmpinger Boxes (Cal) Dale:'11812024 Calibrated By: CG Barometric Pressure: 25.55 Reference: Digi-Sense 20250-92 SN:210429562 Reference Point Number 1APEX 1#1{(xc522) 3 4 4 5 5 1APEX 1 #2A(XC522-10) 3 4 4 5 5 1APEX 1 #3A(XC522-14) 3 4 4 5 5 1ES1 #1A (C-5000) 3 4 4 5 5 a Type of calibration system used. Reference Thermocouple Thermometer Potentiometer Temperature "F Temperature'F 241 71 72 244 70 33 71 238 70 72 248 72u 71 245 73 71 245 72 34 72 251 72 72 242 72 33 71 Source a (specify) Probe on Probe off CPM Oven on Oven off lmpinger ice lmpinger amb. Probe on Probe off CPM Oven on Oven off !mpinger ice lmpinger amb. Probe on Probe off CPM Oven on Oven off lmpinger ice lmpinger amb. Probe on Probe off CPM Oven on Oven off lmpinger ice lmpinger amb. Temperature Difference b o/o -0.14 0.00 0.19 -0.19 -0.14 0.00 -0.19 0.14 -0.19 0.00 0.19 0.00 0.00 -0.19 -o.14 0.19 0.19 0.19 0.00 0.20 0.00 0.00 0.19 0.00 -0,19 -0.28 -0.20 -0.19 b (reference temp. 'F + 460) - (test thermometer temp. 'F + 460) reference temperature "F + 460 lL7 of 22O * 100< 1.5olo GP08 1AS-041757- RT- 1600 Montrose Air Quality Services 6823 South 3600 West Spanish Fork, Utah 84660 (801) 7%-2950 (801) 2667111 Sample Box Temperafure Sensor Calibration Form Sample Box Number: Probes (Cal) Date:11812024 Callbrated By: CG Baromebic Pressure: 25.55 Reference: Digi-Sense 20250-92 SN:210429562 Reference Point Source a Reference Thermocouple TemperatureNumber (specity) Thermometer Potentiometer Difference b Temperature "F Temperature oF %a) lce Water 35 36 -0.20 4' - A b) Hot Water 161 161 0.00c) Boiling Water 220 222 -0.29d) Warm Oil 249 251 -0.28e) Hot Oil 349 350 -0.12 0 Boiling Oil 461 462 -0.11 I t T t I I I t I I I I I I I I T t I 36 161 220 252 353 462 37 160 219 251 351 460 35 159 219 255 353 465 35 160 219 253 353 462 36 159 218 251 351 460 a) 4',- B b) c) d) e) 0 a)4'-C b) c) d) e) f) a)4'-D b) c) d) e) 0 lce Water Hot Water Boiling Water Warm Oil Hot Oil Boiling Oil lce Water Hot Water Boiling Water Warm Oil Hot Oil Boiling Oil lce Water Hot Water Boiling Water Warm Oil Hot Oil Boiling Oil 36 158 217 255 351 463 -0.20 0.16 0.29 0.00 0.25 0.22 -0.20 0.00 -0.29 -0.28 4.12 -0.11 -0.20 -0.16 -0.15 0.00 0.00 0.00 a Type of calibration system used. b (reference temp. "F + 460) - (testthermometer temp. 'F + 460) * 100< 1.57o reference tempbrafure "F + 460 118 pf 220 GP08 1AS-04 1757-RT- 1600 41 145 232 260 353 463 41 145 230 256 353 459 40 144 233 259 352 461 41 145 231 255 354 458 a) b) c) d) e) 0 a) b) c) d) e) 0 I I I I I I I t I I T I I I I I t I I Montrose Air Quality Servtces 6823 South 3600 West Spanish Fork, Utah 84660 (801) 794-2950 (801) 266-7111 Sample Box Temperature Sensor Calibration Form Sample Box Number: Probes (Cal) Date:11912024 Calibrated By: CG - Afi Barometric Pressure: 25.5 Reference: Digi-Sense 20250-92 SN:210429562 Reference Point Source a Reference ThermocoupleNumber (specify) Thermometer Potentiometer Temperature'F Temperature oF a) 6'- B b) c) d) e) 0 a) 7'-C b) c) d) e) 0 7'-D 7',-E lce Water Hot Water Boiling Water Warm Oil Hot Oil Boiling Oil fce Water 42 42 Hot Water 139 14O Boiling Water 227 226 Warm Oil 260 260 Hot Oil 346 345 Boiling Oil 453 455 lce Water Hot Water Boiling Water Warm Oil Hot Oil Boiling Oil lce Water Hot Water Boiling Water Warm Oil Hot Oil Boiling Oil Temperature Difference b o/o -0.20 -0.17 -0.15 -0.14 -0.25 0.11 0.00 -o.17 0.15 0.00 0.12 -0.22 -0.20 -o.17 0.14 -0.14 -0.12 -0,22 0.00 0.00 0.14 -0.14 0.12 -0.11 41 '|'37 226 259 344 451 42 138 227 260 346 450 a Type of calibration system used. b (reference temp. 'F + 460) - (test thermometer temp. 'F + 460) ' 100< 1.5o/o reference temperature "F + 460 tL9 of 220 GP08 1AS-041 757-RT- 1600 Pltot Tubo Callbntlon Data Sheet Prob.,Pttot lD tlo: 4'A-TP4' No PDt rEior q Ohltal ArE[r Fhdar l0: lb.snng TrF lD: CdpilD; Crlibilt m partdmld urkE tha proc.dms ot EPA M.thod 2. S.cdm 10.1 Allgnment rnd Tublng Dlmenslons -ft=", W$-" D D.tc Lldh.Or0 bnl pg.tton ld frrrr&ilil q nd Bre: %r*- D.gil lndkatrg hd Po.5d tq llLfii.f,lg 0. Pars PaSs ParE Ps3 Pagc Pss Pa$ Pars P!sE Pars OaIm Lrdkadnf LEl poaloon d rloiileg I mn calcuLune Z Aslambly lntor-Componont 8plclng Roqulrrmonts Onlcl TC mly Sclback TC mly Paar Pu Ps$Otlsct TC mly Putomled By: eFpond By: Si$!tr6: Signatlro: Oato: _ h.: - ot/ot 2a 01/oM21 o. (-l0o<c,< +l0o)32 d. a -10' < G< +10")3.1 R. a-\e ? It. a +5-l o.1 o" (-5" < B.< +5")ta t.1I0.5 A o Ba50 ,=Atmr {t ()-125')0.0170 F A hn O (t O.(Itlzs')0.@77 o (0.187t'< o,< 0.375')0.3740 P. I1.05t} < P. < 1.50)0..130o P. (t.os[} < P. < t.5til o 4250 I P^- Pr I s 0.0625 o.m60 I t I I t I I I I I I t I I I I I I IL20 of 220 GP08 1AS-04 1 757-RT- 1600 I I I I I I I I I I I I I I I I I I I Pltot Tube Callbratlon Data Shoot ft*ebr a Odd And. Fh&( lD: M{tqhg Tlp.lO: Cdp..lt} Calbrdon p.riomrd 6irl0 tlx p.oc..nrar ol EPA llL0pd 2, S.cdon 10.1 ffiY AlEnment lrd Tublttg Dlmenrlonr Pax Prs Prs! Paar Prtr Paar P!!a Patt Para Parr O.0o hirlc*rr ldl po.lll6 tor dffiarl.re rlrf,n 6kod.te z. A..embly lnt r4omponont Sprclng R.qultuncntt Otl.lTC orly Sotb.d( TC mly Paar Pas Patr Oftd TC only P.rbflncd By: lpprovrd By: Si{fdm: Slgrdw.: Oat: _0ion2a olwa 3.O a- r -lr < a. alrl t_9 B, (-5'< B, < +5"1 0.0 lt' (-t' < lJr < +r-l t-3 o7 e t.6 A 0.8(x)0 z:Atmr (t U.IZU')o mga aAh6e lr O&t125'l o.uDtq 0.1875" < q< 0.376')o.37@ P^ ('t.060 < P^ < 1.68)0.3s08 P. (1.06q < Pr < 1.5q)0.{m I P^- Pr I s 0.0625 {.@@ A B A i, a> 3 tr'l ).0.376 (, D- a> l.5l 2.W /l>3d.}3 3t5 t > o75,,I 45() t2l of 22O GP08 1AS-041 757-RT- 1600 Montrose Air Quality Servlges Cerdflcsto of Balance Calabradon Addrussr 6823 South 36fi) West (xty/stat3lAp: Spanlsh foa., Ubh 84560 Manufachrrun Model: Serlal ttumbon ldentlf,caUon: l.ocailon: Next Callbradon:71412024 RsfcrcneWelghts Cal ld: Nornlnrt Mrr lndlcldon ErrEr1 1 o.(xno 20 19.9999 {.0001 50 49.999!t {.0001 100 99.9998 -0.0m2 2@ 199.9998 -0.0002 Gomments: CerdflcateNo.: l|+ztlEI.#l Gallb. Date: t'l4lzou Tectrnlclan: CheYnryGtrYmon Norntrrrl Mrrr lndlcrtUon Ernor 1 1 0.fiD0 20 19.9999 -1E04 50 49.9999 -0.0001 1oo 99.9998 -O.(n02 2c,0 199.9998 {.(xxr2 Sartarlus Analytlcal 8a110530706E71 AETffi SmallTraller I t I I I I I I I I I t I I I I I I t Perdnert lnfbrmaUon: The artlfact descrlbed hereln has been cattbrated uslng standards traceble to NIST. Thls ls to cerdfy the data reported hercln ls true and conect as the date callbrated. The procedure used to callbrate the prtffact meets the requlrements to meet MAQS Shndards' AuftorLGd Slgnatnu: L22 of 22O GP08 1AS-041757-RT- 1600 I I I I I I I I I I I I I I I I I I I Montrose AIr QualitY Serulces Certmlte of Balancs Galabratlon Addmss: 6823 South 3500 West dty/StatelZp: Spanlsh Fork, Utah 84650 Manufacfitrcr: Model: Sorlaltlumben ldentlficadon: Loczdon: Shlmadzu Top loader D4d6TfiAEr #2439 AETfiz SmallTraller cErtlflcate No.: tl+2@4fi2 Gllb. Date: tl4l2@4 Tedtnlclan: ChsYnaYGuYmon Next Callbretlon:il412o?A Rsftttn€ WelglrG cal ld: Nomltul Marc tndldon Errpr 1 1.00 0.00 2020 0 50 49-98 -o.02 100 99.97 -0.03 2@ t99.97 -o.03 Gomments: Nomlnal rr,llaa lndlcrtlon Error 11.@020 19.99 {.01 s0 49.98 -o.02 1oo 99.98 -o.02 2@ 199.97 -o.o3 Perdnem lnformadon: The ar6fact descrlbed hereln has begn callbrated uslng standards traceble to NIST. Thls ls to certlfy the data reported hereln d true and comct as the date callbrated. The procedure used to caltbrate the arttfact meets the requlrements to meet MAOS Standards' Autfrorlzed Slgniltre: 723 of 220 GP08 1AS-041757-RT- 1 500 Montrose Air QualltY Services Cortmcats of Balance GahbraUon Addrues: 6823 South 3600 West CU/Stab/Zlp: Spanlsh Fork, Utah 84660 Manufacturpr: Model: Serlal ilumben ldertlficdon: Locadon: OHAUS Top Loader 8350103094 AET#5 Gooseneck IIext Callbradon:il4l2ou ReftrpnceWelgtbCal ld: Nomlna! f$ac' tndlcrllon Error 110 2020 0 50500 1oo 99.9 'o.1 2(x) 199.9 '0.1 Commants: certtflcateNo.: il+zo?A*s Callh. Date: {412024 Technlclan: CheYneYGrrymon Nomlnal M.ra lndlc.don Elror tt0202O0 so 49.9 '0.1 1@ 1U, 0 200 199.9 -o.1 Perdnent lnfurmadon: The ardfact descrlbed heretn has been callbrated uslng standards traceble to NIST' Thls ls to effi the data rcported hereln ls we and conect as the date callbrated. The procedure used to catlbrate the artlfact meets the requlrements to meet MAQS Standards' tu$odzod $gna|rrtu: t I I I I I I T I I t I I I T I T I IL24 of 220 GP08 1AS-041757-RT- 1600 I I I I I I I I I t T t I t I T t I I @rdflffi of Balance Calabredon Addruss: 6823 South 36m West OtylstaoI[p: Spanlsh Fork, t tah 84560 Montrose Air Quality Services Cerdf,cate No.: Cellb. Dete! Technlclan: Manufafiren Model: Sedal Numbcn tdentlllcadon: Locdons NextGllbraton: R€fErcncs Welghts Cal ld: OHAUS Analytlcal 8329582368 AET#6 Gooseneck lndlcdfon 1, 20 49.9998 99.9998 1!'9.9998 tl+zwr*6 1.141?fiu CheyneVGuYmon Nomlnsl M... 1 20 50 100 200 Gommsrts: il412024 Elror 0.fino 0 -o.0m2 -0.(m2 -0.fi)02 Nomlnel Mag 1 20 50 100 200 lndlcrtlon 0.9999 20 49.9998 99.9997 199.9998 Error {.0001 0 -o.0002 -0.0m3 -0.0q)2 Perdnent Informstlon: The artlfact descrlbed hercln has been callbrated uslng standards traceble to NIST. Thls ls to certlfythe data reported hereln ls tnte and conect as the date callbrated. The pmcadure 16ed to callbrate the artlfact meets the requlrements to meet MAQS Standards' Au$odzsd Slgnaturc: 125 of 220 GP081AS-04 1757-RT- 1 600 Tl4l4tu Error 0.fiDo 0.0m -0.0001 0 -0.0001 ilomlnal Merg 1 20 50 1ff) 200 I I I I I I I I T T T I T T I I T I I Montrcse Alr Quallty Servlces Certncate of Balane Calabrafl on Addrsss: 68Zl South 3600west Oty/Sffie/ap: Spanlsh Forlc tftah 84660 Manufacufl€n Modsl; Ser{al l{umban ldentlf,cadm: locatlon: Flrstaden HC21/104N 94L MAq}1 Laboratory NoG Callbradon: Rsforsncs Welgtrts Cal td: Nomlnal Marc lndlcatlon 1120 20 50 49.9999 100 1(x) 200 199.9999 Commrts: Perdnent lnfonnadon: The artifact descrlbed hereln has been catlbrated uslng standards traccble to NIST. Thls is to ceffi the daE reported hereln ls pue and conect as the date callbrated. The proedure used to callbrate dre arUdct meets the reOulrerypnts to meet MAQS Standards' Auftortsod SlgnaEtu: Certlf,cateNo.: ll+20?4ffi Callb. Date: U4l2g24 Technldan: CheYneYGtrynon lndlcrdon EFor 1 0.0000 20 0.00(n 500 99.9999 -0.0001 2(n 0 L26 of 220 GP08 1AS-041757-RT- 1600 Appendix C.3 Instrumental Test Method QA/QC Data JUN 2 6 2024 _DlVtsrOtt OF AtR OUALtTy MONTROSE AIR QUALIW SERVICES, LLC. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 Plant: Sunnyside Source : Unit EU #1 Date: 05123124 Run : Stratification t I I I I I I I I I I I T I T I T I I Date and Time 51231249:15 51231249:16 51231249:'17 5123124 9:18 5123124 9:19 51231249:20 5123124 9:21 51231249.,22 51231249',23 51231249.,24 51231249:25 51231249:26 51231249:27 51231249:28 51231249,,29 51231249:30 51231249:31 51231249:32 51231249:33 51231249:!l 51231249:35 51231249:36 51231249:37 51231249:38 51231249:39 51231249:4O 51231249:41 02 cozt%) M NOr (ppm) Average Value Observed Min Value Observed Max Value Observed 95% of Average 105% of Average Single Point Criteria Met? 90% ofAverage 110% of Average 3-point Criteria Met? 150.1 1s1.8 151.1 1il.7 148.8 156.0 150.7 149.5 1il.4 149.8 150.4 149.3 153.9 151.9 1s1.0 151.1 153.0 150.9 148.7 152.5 138.8 164.5 147.5 150.9 151.7 14r'.7 162.'.| 152.0 144.7 164.5 144.4 159.6 No (Max Value Exceeded) 136.8 167.2 Yes '|.4.3 14.3 14.3 14.3 14.3 14.2 10.9 14.2 14.2 '|.4.4 14.3 14.3 14.2 11.5 14.2 14.2 14.2 14.1 '14.3 14.1 11.9 13.9 14.3 14.3 14.2 14.3 13.8 14.2 13.8 14.4 13.5 14.9 Yes 12.8 15.6 Yes GP08 1AS-04 1757-RT- 1600 5.8 5.8 5.9 5.8 5.8 6.0 10.1 s.8 5.9 5.7 5.8 5.8 5.9 9.8 5.9 5.8 5.9 6.0 5.7 6.0 10.2 6.2 5.8 5.8 5.9 5.7 6.2 5.9 5.7 6.2 5.6 6.2 Yes 5.3 6.4 Yes L28 of 22O I I I I I I T I I I I I T I I I I I t Company Source Date Sample Gas Span Cylinder Value (ppm) 0 10.07 20.45 lnitlalBlas Anallger Response (ppm) 0 10.2 Analwer Callbratlon Sunnyside Unit EU #1 5t23t2024 02 20.45 Syatem Response (ppm) 0.1 10.3 Post-test #'l Bias Analper Response System Response(ppm) (ppm)0 0.210.2 10.2 Post-test f2 Bias Analyzer Response Sptem Response(ppm) (ppm)o 0.210.2 10.2 Post-test #3 Bias Anallzer Response System Response (ppm) 0 10.2 (ppm) 0.2 10.2 Anallzer Response (ppm) 0 10.2 20.5 Absolute Difference (ppm) 0.0 0.1 0.1 Difference (% of span) 0.00 0.64 0.24 Drift (% of span) 0.49 0.49 Drift (% of span) 0.00 0.00 Drift (% of span) 0.00 0.00 System Bias (% of span) 0.49 0.49 System Bias (% of span) 0.98 0.00 Slatem Bias (% of span) 0.98 0.00 System Bias (% of span) 0.98 0.00 t29 of 22O GP08 1AS-041757-RT- 1600 Post-test ll4 Bias Anallzer Response System Response I I I I I I I I I I I T I t t I T I I Analper Response System Response (ppm) 0 10.2 Post-test #5 Bias (ppm) 0 10.2 Post-test #6 Bias (ppm) 0 10.2 Post-test #7 Bias (ppm) 0 10.2 Post-test #8 Bias (ppm) 0 10.2 Post-test #9 Bias (ppm) 0 10.2 (ppm) 0.2 10.2 (ppm) 0.2 10.2 (ppm) 0.2 10.2 (ppm) 0.2 10.2 (ppm) 0.2 10.2 (ppm) 0.2 10.2 System Bias (% of span) 0.98 0.00 System Bias (% of span) 0.98 0.00 System Bias (% of span) 0.98 0.00 System Bias (% of span) 0.98 0.00 Syatem Bias (% of span) 0.98 0.00 System Bias (% of span) 0.98 0.00 Drift (% of span) 0.00 0.00 Drift (% of span) 0.00 0.00 Drift (% of span) 0.00 0.00 Drift (% of span) 0.00 0.00 Drift (% of span) 0.00 0.00 Drift (% of span) 0.00 0.00 Analyzer Response System Response Analper Response System Response Analper Response System Response Analyzer Response System Response 130 of 220 GP08 1AS-04 1757-RT- 1600 Post-test #10 Bias Analyzer Response System Response(ppm) (ppm)o 0.210.2 10.2 Post-test #ll Blas Anallzer Response System Response(ppm) (ppm) 0 10.2 System Bias (% of span) 0.98 0.00 Drift (% of span) 0.00 0.00 Sptem Bias (% of span) 0.00 49.88 Drift (% of span) 0.98 49.88 t3t of 220 GP08 1AS-04 1757-RT- 1 500 Company Source Date Sample Gas Span Cylinder Value (ppm) 0 11.97 22.79 lnltialBias Anallzer Response (ppm) 0 11.8 Analrzer Calibration Sunnyside Unit EU #1 5t23t2024 co2 22.79 I I I t I I I I I I I T T I T System Response (ppm) 0.2 12 Post-test #1 Bias Anallzer Response System Response(ppm) (ppm)0011.8 11.9 Post-test #2 Bias Analyzer Response System Response(ppm) (ppm) 0011.8 11.9 Post-test *3 Bias Analper Response System Response(ppm) (ppm) 001'1.8 12 Analper Response (ppm) 0 11.8 22.9 Absolute Difference (ppm) 0.0 0.2 0.1 System Bias (% of span) 0.88 0.88 System Bias (% of span) 0.00 0.44 System Bias (% of span) 0.00 0.44 System Bias (% of span) 0.00 0.88 Difference (% of span) 0.00 0.75 0^48 Drift (% of span) 0.88 0.44 Drift (% of span) 0.00 0.00 Drift (% of span) 0.00 0.44 I t t IL32 of 22O GP08 1AS-04 1 757-RT- 1600 I I I t t I I I t I I I I I I t I T I Post-test *l Bias Analper Response System Response Sptem Bias (% of span) 0.00 0.88 Drift (% of span) 0.00 0.00 (ppm) 0 1 1.8 Post-test #5 BIas (ppm) 0 12 Analger Response Sptem Response Sptem Bias (% of span) 0.44 0.88 Drift (% of span) 0.44 0.00 (ppm) 0 11.8 Post-test #6 Bias (ppm) 0.1 12 Ana[zer Response System Response Sptem Bias (% of span) 0.44 0.88 Drift (% of span) 0.00 0.00 (ppm) 0 1 1.8 Post-test #7 Bias (ppm) 0.'1 12 Analyzer Response System Response Syatem Bias (% of span) 0.00 0.88 Drift (% of span) 0.44 0.00 (ppm) 0 11.8 Post-test #8 Blas (ppm) 0 12 Anal)zer Response System Response Synstem Bias (% of span) 0.00 0.44 Drift (% of span) 0.00 0.44 (ppm) 0 11.8 Post-test #9 Blas (ppm) 0 11.9 Analyzer Response Sptem Response Sptem Bias (% of span) 0.00 0.44 Drift (% of span) 0.00 0.00 (ppm) 0 1 1.8 (ppm) 0 11.9 t33 of 22O GP08 1AS-041757-RT- 1600 Post.test #10 Bias Analper Response System Response(ppm) (ppm)00 11.8 1 1.9 Post-test #ll Blas Analyzer Response Sptem Response(ppm) (ppm) 0 11.8 Syatem Bias (% of span) 0.00 0.44 Syatem Bias (% of span) 0.00 51.78 Drift (% of span) 0.00 0.00 Drift (% of span) 0.00 52.22 I I I I I I I I t I IL34 ot 220 GP08 1AS-041757-RT-1600 I I I T I T I I I I T t t I I T I I t Gompany Source Date Sample Gas Span Cylinder Value (ppm) 0 99.8 238 lnltial Bias Analper Response (ppm) 0.1 99.9 Analwer Callbration Sunnllside Unit EU #1 5t2312024 so2 238 System Response (ppm) 0.2 100.4 Post-test #1 Bias Analyzer Response System Response(ppm) (ppm)0.1 0.199.9 98.2 Post-test #2 Bias Analper Response System Response(ppm) (ppm)0.1 0.599.9 98.8 Post-test #3 Blas Anallzer Response System Response (ppm) 0.1 99.9 (ppm) 0.7 98.9 Anallzer Response (ppm) 0.1 99.9 238.7 Absolute Difference (ppm) 0.1 0.1 0.7 System Bias (% of span) 0.04 0.21 System Bias (% of span) 0.00 0.71 System Bias (% of span) 0.17 0.46 Sptem Bias (% of span) 0.25 0.42 Difference (% of span) 0.04 0.04 0.29 Drift (% of span) 0.04 0.92 Drift (% of span) 0.17 0.25 Drift (% of span) 0.08 0.04 t35 of 220 GP08 1AS-041757- RT- 1600 Post-test #4 Bias Anallzer Response (ppm) 0.1 99.9 Post-test #5 Blas Analyzer Response (ppm) 0.1 99.9 Post-test #6 Blas Analyzer Response (ppm) 0.1 99.9 Post-test #7 Bias Analyzer Response (ppm) 0.1 99.9 Post-test #8 Bias Analyzer Response (ppm) 0.1 99.9 Post-test #9 Bias Analyzer Response (ppm) 0.1 99.9 System Response (ppm) 0.8 99.6 System Response (ppm) 0.8 99.5 System Response (ppm) 0.6 99.5 Sptem Response (ppm) 0.8 99.9 System Response (ppm) 0.4 100 System Response (ppm) 0.7 100 System Bias (% of span) 0.29 0.13 Sptem Bias (% of span) 0.29 0.17 System Bias (% of span) 0.21 0.17 System Bias (% of span) 0.29 0.00 System Bias (% of span) 0.13 0.04 System Bias (% of span) 0.25 0.04 Drift (% of span) 0.04 0.29 Drift (% of span) 0.00 0.04 Drift (% of span) 0.08 0.00 Drift (% of span) 0.08 0.17 Drift (% of span) 0.17 0.04 Drift (% of span) 0.13 0.00 I I I I I I I I I I I I I t I I I I I136 of 220 GP08 1AS-041757-RT- 1 600 Post-test #10 Bias Anallzer Response System Response Sptem Bias (% of span) 0.21 0.13 Drift (% of span) 0.04 0.17 (ppm) 0.1 99.9 (ppm) 0.6 99.6 Post-test #1'l Bias Analper Response Syatem Response System Bias (% of span) 0.04 41.97 Drifi (% of span) 0.25 41.85 (ppm) 0.1 99.9 (ppm) 137 of 220 GP08 1AS-041757-RT- 1 600 Gompany Source Date Sample Gas Span Cylinder Value (ppm) 0 101.9 247 lnltlalBias Analper Response (ppm) 0 247.1 Analvzer Calibration Sunnyside Unit EU #1 512312024 NOx 247 I I I I I I I I I I T I t I t I t I I System Response (ppm) 0.3 247.2 Post-test #1 Bias Ana[zer Response System Response(ppm) (ppm) 0 0.2247.1 247.7 Post-test #2 Bias Analper Response System Response(ppm) (ppm)0 0.2247.1 247.8 Post-test #3 Blas Analper Response System Response(ppm) (ppm)0 0.2247.1 247.7 Analper Response (ppm) 0 101.3 247.1 Absolute Difference (ppm) 0.0 0.6 0.1 Difference (% of span) 0.00 0.24 0.04 Drift (% of span) 0.04 0.20 Drift (% of span) 0.00 0.04 Drift (% of span) 0.00 0.04 System Bias (% of span) 0.12 0.04 System Bias (% of span) 0.08 0.24 System Bias (% of span) 0.08 0.28 Syatem Bias (% of span) 0.08 0.24 138 of 220 GP08 1AS-041 757-RT- 1600 I I T I I I t t I t t T I I I t T t T Post-test #4 Bias Anallzer Response System Response System Bias (% of span) 0.04 0.32 Drift (% of span) 0.04 0.08 (ppm) 0 247.1 Post-test #5 Bias (ppm) 0.1 247.9 Analper Response System Response System Bias (% of span) 0.04 0.16 Drift (% of span) 0.00 0.16 (ppm) 0 247.1 Post-test #6 BIas (ppm) 0.1 247.5 Anallzer Response System Response System Bias (% of span) 0.08 0.20 Drift (% of span) 0.04 0.04 (ppm) 0 247.1 Post-test #7 Bias (ppm) 0.2 247.6 Analyzer Response Syatem Response System Bias (% of span) 0.08 0.20 Drift (% of span) 0.00 0.00 (ppm) 0 247.1 Post-test #8 Bias (ppm) 0.2 247.6 Analyzer Response System Response Syrstem Bias (% of span) 0.04 0.24 Drift (% of span) 0.04 0.04 (ppm) 0 247.',| Post-test #9 Bias (ppm) 0.1 247.7 Analyzer Response System Response System Bias (% of span) 0.08 0.24 Drift (% of span) 0.04 0.00 (ppm) 0 247.1 (ppm) 0.2 247.7 t39 of 22O GP08 1AS-041 757-RT- 1600 Post-test #10 Bias AnalyzerResponse SyrstemResponse(ppm) (ppm)0 0.3247.1 247.6 Post-test #11 Bias Analyzer Response System Response(ppm) (ppm) 0 247.1 System Bias (% of span) 0.12 0.20 Drift (% of span) 0.04 0.04 Sptem Bias (% of span) 0.00 100.04 Drift (% of span) 0.12 100.24 l4O ot 22O GP08 1AS-041757-RT- 1600 I I I I t I I I t I I I I I I I T I t Gompany Source Date Sample Gas Span Cylinder Value (ppm) 0 25.3 50.2 lnltlalBlas Analyzer Response (ppm) 0.1 25.7 Analvzer Calibration Sunnyside Unit EU #1 512312024 co 50.2 Sptem Response (ppm) 0.1 25.4 Post-test #1 Bias Analyzer Response System Response(ppm) (ppm) 0.1 0.125.7 25.2 Post-test #2 Bias Analyzer Response System Response(ppm) (ppm) 0.1 0.125.7 25.1 Post-test #8 Blas Ana[zer Response System Response (ppm) 0.1 25.7 (ppm) 0 2s.2 Analyzer Response (ppm) 0.1 25.7 50.1 Absolute Difference (ppm) 0.1 0.4 0.1 Difference (% of span) 0.20 0.80 0.20 Drift (% of span) 0.00 0.40 Drift (% of span) 0.00 0.20 Drift (% of span) 0.20 0.20 System Bias (% of span) 0.00 0.60 System Bias (% of span) 0.00 1.00 System Bias (% of span) 0.00 1.20 System Bias (% of span) 0.20 1.00 t4t of 22O GP08 1AS-041757-RT- 1 600 Post-test #f Bias Anallzer Response System Response I I I I I I t I I I t I t I I t T T Anallrzer Response System Response (ppm) 0.1 25.7 Post-test #5 Bias (ppm) 0.1 25.7 Post-test #6 Blas (ppm) 0.1 25.7 Post-test #7 Bias (ppm) 0.1 25.7 Post-test #8 Bias (ppm) 0.1 25.7 Post-test #9 Bias (ppm) 0.1 25.7 (ppm) 0 25.1 (ppm) 0 25.3 (ppm) 0 25.3 (ppm) 0.1 25.2 (ppm) 0 25.1 (ppm) 0 25.2 System Bias (% of span) 0.20 1.20 Sptem Bias (7o of span) 0.20 0.80 System Bias (% of span) 0.20 0.80 System Bias (% of span) 0.00 1.00 System Bias (% of span) 0.20 1.20 System Bias (% of span) 0.20 1.00 Drift (% of span) 0.00 0.20 Drift (7o of span) 0.00 0.40 Drift (% of span) 0.00 0.00 Drift (% of span) 0.20 0.20 Drift (% of span) 0.20 0.20 Drift (% of span) 0.00 0.20 Anallzer Response System Response Analyzer Response System Response Anallzer Response System Response Analyzer Response System Response t142 of 22O GP08 1AS-041757-RT- 1 600 Post-test #10 Bias Anallzer Response System Response System Bias (% of span) 0.20 1.20 Drift (% of span) 0.00 0.20 (ppm) 0.1 25.7 (ppm) 0 25.1 Post-test #1'l Bias Anallzer Response System Response(ppm) (ppm) 0.1 25.7 System Bias (% of span) 0.20 51.20 Drift (% of span) 0.00 50.00 143 of 22O GP08 1AS-041757-RT- 1500 Plant: Source: Date: Run: NO2 eff: MONTROSE AIR QUALITY SERVICES, LLC. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 Sunnyside Unit EU #1 05123124 Post NO2 Conversion I I t I I l T I I T I I I I T T I t 0.79 % Date and Tlme 512312416:52 512312416:53 512312416:54 512312416:55 512312416:56 512312416:57 5123124'16:58 512312416:59 512312417:00 512312417:01 512312417:02 512312417:03 512312417:04 512312417:05 512312417:06 512312417:07 512312417:08 512312417:09 512312417:10 512312417:11 512312417:12 512312417:13 5123124'17:14 512312417:15 512312417:16 512312417:17 512312417:18 512312417:19 512312417:20 512312417:21 olo Dift: NOr (ppm) 89.5 89.4 89.4 89.3 89.4 89.3 89.4 89.3 89.3 89.3 89.2 co so2(oom) (pom) o2 gn 0.0 0.0 0.0 Goz gn 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 89.2 89.2 89.2 89.2 89.2 89.2 89.1 89.0 89.1 89.'l 89.0 89.0 89.0 88.9 88.9 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 88.9 88.9 88.9 88.8 0.79 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 744 of 22O GP08 1AS-041 757-RT- 1600 Plant Source Date Run I I I I I MONTROSE AIR QUALITY SERVICES, LLC. 6823 South 3600 West 801-266-7111 Spanish Fork, Utah 84660 Sunnyside Unit EU #1 05123124 10 Sec Date and Time 512312024 8:14:37 512312024 8:14:47 512312024 8:14:57 512312024 8:15:07 512312024 8:15:17 512312024 8:15:27 512312024 8:15:37 512312024 8:15:47 512312024 8:15:57 512312024 8:16:07 512312024 8:16:17 512312024 8:16:27 512312024 8:16:37 512312024 8:16:47 512312024 8:16:57 512312024 8:17:07 512312024 8:17:17 512312024 8:17:27 512312024 8:17:37 512312024 8;17:47 512312024 8:17:57 512312024 8:18:07 512312024 8:18:'17 512312024 8:18:27 512312024 8:18:37 512312024 8:18:47 512312024 8:18:57 512312024 8:19:07 512312024 8:19:17 512312024 8:19:27 512312024 8:19:37 512312024 8:19:47 512312024 8:19:57 512312024 8:20:07 512312024 8:20:17 512312024 8:20:27 512312024 8:20:37 512312024 8:20:47 512312024 8:20:57 512312024 8:21:07 512312024 8:2'l:17 8.3 8.0 8.2 8.0 8.1 8.1 8.1 8.2 8.2 8.1 8.3 8.2 1.0 0.2 0.1 0.2 0.2 0.5 0.1 0.0 0.4 0.3 -0.2 0.1 0.3 0.2 0.1 0.1 -0.1 0.1 0.1 0.'1 -0.2 0.0 0.0 0.2 0.0 0.0 0.2 0.1 0.0 -0.1 -0.1 -0.1 -0.1 -0.1 -0.2 -0.2 -0.2 -0.2 0.0 0.0 0.0 0.0 0.0 0.0 0.00.0 Lin 0.0 0.6 9.8 10.5 10.s 10.5 10.6 10.6 10.6 10.6 10.7 10.7 10.7 10.7 10.7 10.7 '10.7 10.7 10.7 7.0 0.6 0.2 0.2 0.0 NO, CO SO2 02 COz(ppm) (opm) (ppm) tYel I%l t I I I I I I I I I I I I 0.2 0.1 0.3 0.2 0.0 0.0 -0.3 0.0 0.0 -0.3 0.0 0.0 0.1 -0.1 0.0 0.0 0.1 0.1 -0.1 -0.2 -0.2 0.0 -0.1 -0.1 0.0 -0.2 0.0 -0.1 0.0 -0.1 -0.1 0.0 -0.1 -0.'1 -0.1 0.1 -0.1 0.1 -0.1 0.1 0.0 99.9 99.9 99.9 99.9 95.2 77.9 60.9 52.1 49.4 48.8 48.9 48.7 48.8 48.9 48.8 48.7 48.6 47.3 45.8 41.7 29.7 16.6 7.4 2.5 0.6 0.1 0.0 0.0 -0.1 0.0 0.0 0.0 0.1 0.1 0.1 0.0 0.1 o.z 19.8 33.1 42.1 21.1 21.1 21.1 5.3 0.2 0.1 0.1 0.1 0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 -0.1 0.3 15.4 18.7 18.8 20.4 20.4 20.5 20.5 20.5 20.5 20.5 20.5 20.5 20.5 20.5 20.5 20.5 20.4 17.0 1.8 0.1 0.0 0.0 745 of 220 GP08 1AS-041757-RT- 1600 512312024 8:21:27 512312024 8:21:37 512312024 8:21:47 512312024 8:21:57 512312024 8:22:07 512312024 8:22:17 512312024 8:22:27 512312024 8:22:37 512312024 8:22:47 512312024 8:22:57 512312024 8:23:07 512312024 8:23:17 512312024 8:23:27 512312024 8:23:37 512312024 8:23:47 512312024 8:23:57 512312024 8:24:07 512312024 8:24:17 512312024 8:24:27 512312024 8:24:37 512312024 8:24:47 512312024 8:24:57 512312024 8:25:07 512312024 8:25:17 512312024 8:25:27 512312024 8:25:37 512312024 8:25:47 512312024 8:25:57 512312024 8:26:07 512312024 8:26:17 512312024 8:26:27 512312024 8:26:37 512312024 8:26:47 512312024 8:26:57 512312024 8:27:07 512312024 8:27:17 512312024 8:27:27 512312024 8:27:37 512312024 8:27:47 512312024 8:27:57 512312024 8:28:07 512312024 8:28:17 512312024 8:28:27 512312024 8:28:37 512312024 8:28:47 512312024 8:28:57 512312024 8:29:07 512312024 8:29:17 512312024 8:29:27 512312024 8:29:37 512312024 8:29:47 512312024 8:29:57 512312024 8:30:07 512312024 8:30:17 512312024 8:30:27 0.0 0.0 0.3 0.1 0.2 -0.1 0.1 0.1 -0.1 0.0 0.1 0.1 0.2 0.0 0.2 0.3 -0.2 -0.1 -0.3 0.0 0.0 -0.1 0.2 -0.3 0.0 -0.3 -0.3 -0.1 0.0 0.0 -0.1 0.0 -0.1 -0.2 0.1 -0.2 -0.1 0.0 0.1 -0.1 -0.1 -1.9 -52.4 -74.9 0.3 -0.2 57.6 193.3 196.0 196.6 209.6 239.2 238.8 238.8 238.7 -0.1 -0.1 -0.2 0.2 0.0 0.0 -0.2 -0.1 0.0 -0.1 -0.1 3.1 189.3 198.5 198.7 199.'l 199.2 199.8 199.7 209.2 246.8 246.9 247.1 247.',| 201.7 153.7 138.4 157.4 33.6 2.3 't.7 1.4 1.5 1.2 1.3 1.1 1.0 1.1 1.2 1.1 1.1 1.0 0.8 0.8 0.7 0.5 1.4 1.2 1.1 1.1 0.9 1.0 1.1 0.9 0.7 46.5 47.9 48.4 48.3 48.5 49.9 50.2 50.1 50.2 50.1 50.3 49.3 46.1 34.0 19.2 7.4 1.9 0.6 0.4 0.4 0.4 0.4 0.4 0.5 0.5 0.6 1.0 1.9 2.7 2.5 1.7 0.9 0.6 0.4 0.4 0.4 0.4 0.4 0.5 0.4 0.5 0.7 2.0 4.7 8.0 11.2 14.7 13.9 9.7 4.8 1.6 0.6 0.4 0.4 o.4 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.6 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.5 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 -0.1 -0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.'l -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.'r -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.1 -0.2 -0.1 -0.2 -0.1 -0.1 I I I I I I t T t t t I I I I I T I I146 of 22O GP08 1AS-041757-RT- 1 600 I I t T I I I I 512312024 8:30:37 512312024 8:30:47 512312024 8:30:57 512312024 8:31:07 512312024 8:31:17 512312024 8:3'l:27 512312024 8:31:37 512312024 8:31:47 512312024 8:31:57 512312024 8:32:07 512312024 8:32:17 512312024 8:32:27 512312024 8:32:37 512312024 8:32:47 512312024 8:32:57 512312024 8:33:07 512312024 8:33:17 512312024 8:33:27 512312024 8:33:37 512312024 8:33:47 512312024 8:33:57 512312024 8:34:07 512312024 8:34:17 512312024 8:34:27 512312024 8:34:37 512312024 8:?4:47 512312024 8:34:57 512312024 8:35:07 512312024 8:35:17 512312024 8:35:27 512312024 8:35:37 512312024 8:35:47 512312024 8:35:57 512312024 8:36:07 512312024 8:36:17 512312024 8:36:27 512312024 8:36:37 512312024 8:36:47 512312024 8:36:57 512312024 8:37'i7 512312024 8:37:17 512312024 8:37:27 512312024 8:37:37 512312024 8:37:47 512312024 8:37:57 512312024 8:38:07 512312024 8:38:17 512312024 8:38:27 512312024 8:38:37 512312024 8:38:47 512312024 8:38:57 512312024 8:39:07 512312024 8:39:17 512312024 8:39:27 512312024 8:39:37 0.9 0.9 0.5 0.7 0.7 0.2 0.1 0.2 0.1 0.0 0.2 0.3 0.3 0.3 0.3 0.2 0.3 0.4 0.4 0.3 0.3 0.2 0.3 0.4 0.4 0.4 0.2 0.3 0.5 0.1 0.2 0.1 0.2 0.1 0.1 0.1 0.0 0.1 0.2 0.1 0.2 0.1 0.1 -0.1 0.0 0.1 0.2 0.0 0.0 0.0 0.2 0.2 0.1 0.1 0.1 0.5 0.4 0.5 1.3 3.3 4.2 3.5 1.9 0.7 0.2 0.3 1.3 3.8 7.1 10.5 14.0 17.9 22.1 26.3 30.4 u.4 38.3 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166.4 163.5 1s6.9 163.3 171.2 171.2 167.2 166.3 161.3 159.6 166.0 169.0 170.8 173.4 176.7 169.2 167.2 '170.8 168.2 16/..1 172.4 169.2 166.7 0.7 0.7 0.6 0.7 0.7 0.7 0.7 0.9 2.9 5.9 8.8 10.9 12.2 12.9 13.0 13.1 13.2 13.3 13.4 13.5 13.5 13.5 13.5 13.5 13.4 13.2 13.2 13.2 13.2 13.2 13.2 13.2 13.3 13.2 13.2 13.0 12.9 13.1 13.3 13.3 13.2 13.1 13.1 13.2 13.2 13.3 13.5 13.3 13.3 13.2 13.1 13.2 13.2 13.2 13.2 98.5 98.8 99.1 99.5 100.0 100.2 100.6 112.9 100.0 98.9 102.4 98.4 95.2 97.5 99.0 92.2 89.6 90.5 92.7 92.1 86.6 86.6 100.8 111.1 't14.6 115.8 108.9 101.2 99.1 104.1 104.9 99.4 101.2 106.6 1'.t3.4 114.5 103.6 92.2 90.9 97.1 103.0 104.0 94.0 88.8 83.1 76.8 74.3 90.1 94.1 78.3 74.3 76.2 75.3 78.3 83.8 0.2 0.2 0.2 0.2 0.2 0.2 0.2 2.3 5.7 5.8 5.7 5.8 5.8 5.8 5.7 5.8 5.9 6.0 5.8 5.8 5.8 5.8 5.7 5.7 5.7 5.6 5.6 5.7 5.6 5.7 5.7 5.8 5.7 5.7 5.7 5.6 5.8 6.0 5.9 5.9 5.7 5.6 5.8 5.9 5.9 6.0 6.1 6.0 5.8 6.0 6.1 6.1 6.3 6.0 5.9 0.0 0.0 0.0 0.0 0.0 0.0 0.0 8.3 13.6 13.8 13.9 13.9 13.9 14.0 14.1 14.0 13.9 13.8 14.0 14.0 14.0 14.1 14.2 14.2 '14.2 14.2 14.2 14.2 14.3 14.2 14.2 14.1 14.2 14.2 14.2 14.3 14.0 13.9 14.0 14.0 14.2 14.3 14.1 14.0 14.0 13.9 13.9 14.0 't4.1 13.9 13.9 't3.7 13.8 14.0 14.1 797 of 22O GP08 1AS-04 1757-RT- 1600 512312024 16:18:07 51231202416:18:17 512312024 16:18:27 51231202416:18:37 512312024 16:18:47 512312024 16:18:57 512312024 16:19:07 51231202416:19:17 512312024'16:19.,27 512312024 16:1 9:37 512312024 16:19:47 512312024 16:1 9:57 512312024 16:20:07 512312024 16:20:17 512312024 16:20:27 512312024 16:20:37 512312024 16:20:47 512312024 16:20:57 512312024 16:21:07 512312024 16:21:17 512312024 16:21:27 512312024 16:21:37 512312024 16:21:47 512312024 16:21:57 512312024 16:22:07 512312024 16:22:17 512312024 16:22:27 512312024 16:22:37 512312024 16:22:47 512312024 16:22:57 512312024 16:23:07 512312024 16:23:17 512312024 16:23:27 512312024 16:23:37 512312024 16:23:47 512312024 16;23:57 512312024 16:24:07 512312024 16:24:17 512312024 16;24:27 512312024 16:24:37 512312024 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20.2 20.2 20.2 20.2 20.2 20.2 20.2 14.2 1.8 0.3 0.3 0.2 0.2 0.2 0.2 2.2 0.4 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 5.1 19.9 20.9 21.0 21.0 21.0 4.9 5.9 5.9 5.9 5.9 5.9 5.9 s.9 5.9 5.9 5.9 5.9 7.3 1 1.5 11.9 11.9 12.0 11.9 11.9 11.9 11.9 1 1.8 11.8 5.7 0.7 0.2 0.1 0.1 0.1 0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 I I I I T I I I I I I I I2OO of 220 GP08 1AS-041757-RT- 1500 t I I I I I 512312024 16:45:37 512312024 16:45:47 512312024 16:45:57 51231202416:46:07 512312024 16:46:17 512312024 16:46:27 51231202416:46:37 512312024 16:46:47 512312024 16:46:57 512312024 16:47:07 512312024 16:47:17 512312024 16:47:27 512312024 16:47:37 512312024 16:47:47 512312024 16:47:57 51231202416:48:07 512312024 16:48:17 512312024 16:48:27 51231202416:48:37 512312024 16:48:47 512312024 16:48:57 512312024 16:49:07 512312024 16:49:17 512312024 16:49:27 512312024 16:49:37 512312024 16:49:47 512312024 16:49:57 512312024 16:50:07 512312024 16:50:17 512312024 16:50:27 512312024 16:50:37 512312024 16:50:47 512312024 16:50:57 512312024 16:51:07 512312024 16:51:17 512312024 16:51:27 51231202416:51:37 512312024 '16:51:47 512312024 16:51:57 512312024'16:52:07 512312024 16:52:17 512312024 16:52:27 512312024 16;52:37 512312024'16:52:47 512312024 16:52:57 512312024 16:53:07 51231202416:53:17 512312024 16:53:27 512312A24 16:53:37 51231202416:53:47 512312024 16:53:57 512312024 16:54:07 512312024 16:54:17 512312024 16:54:27 512312024 16:54:37 0.2 0.2 0.1 0.1 0.0 0.3 0.1 0.3 0.3 0.0 0.3 0.1 0.3 0.3 0.4 0.4 0.4 0.4 0.5 0.2 0.4 0.5 0.5 0.6 0.5 0.6 0.3 0.5 0.5 0.4 16.7 89.5 89.4 89.4 89.5 89.4 89.4 89.4 89.5 89.5 89.6 89.4 89.6 89.5 89.5 89.4 89.6 89.5 89.4 89.5 89.5 89.3 89.3 89.5 89.4 0.3 0.4 0.1 0.4 0.6 0.4 0.4 0.5 0.5 0.2 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 9.3 7.4 6.2 5.1 4.4 3.5 3.1 2.8 2.7 1.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 21.1 21.0 21.0 21.1 21.0 21.0 21.0 21.0 21.0 10.5 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0I I 2Ol of 22O GP08 1AS-04 1757-RT- 1600 t I51231202416:54:47 89.2 0.0 0.0 0.0 0.0 51231202416:54:57 89.6 0.0 0.0 0.0 0.0 51231202416:55:07 89.6 0.0 0.0 0.0 0.0 51231202416:55:17 89.4 0.0 0.0 0.0 0.0 51231202416:55:27 89.4 0.0 0.0 0.0 0.0 51231202416:55:37 89.3 0.0 0.0 0.0 0.0 51231202416:55:47 89.4 0.0 0.0 0.0 0.0 51231202416:55:57 89.2 0.0 0.0 0.0 0.0 51231202416:56:07 89.4 0.0 0.0 0.0 0.0 51231202416:56:17 89.4 0.0 0.0 0.0 0.0 51231202416:56:27 89.4 0.0 0.0 0.0 0.0 51231202416:56:37 89.4 0.0 0.0 0.0 0.0 51231202416:56:47 89.4 0.0 0.0 0.0 0.0 512312024'16:56:57 89.3 0.0 0.0 0.0 0.0 51231202416:57:07 89.3 0.0 0.0 0.0 0.0 512312024'16:57:17 89.4 0.0 0.0 0.0 0.0 51231202416:57:27 89.3 0.0 0.0 0.0 0.0 51231202416:57:37 89.4 0.0 0.0 0.0 0.0 51231202416:57:47 89.4 0.0 0.0 0.0 0.0 51231202416:57:57 89.3 0.0 0.0 0.0 0.0 51231202416:58:07 89.5 0.0 0.0 0.0 0.0 51231202416:58:17 89.2 0.0 0.0 0.0 0.0 51231202416:58:27 89.3 0.0 0.0 0.0 0.0 51231202416:58:37 89.5 0.0 0.0 0.0 0.0 51231202416:58:47 89.4 0.0 0.0 0.0 0.0 51231202416:58:57 89.2 0.0 0.0 0.0 0.0 51231202416:59:07 89.5 0.0 0.0 0.0 0.0 51231202416:59:17 89.4 0.0 0.0 0.0 0.0 51231202416:59:27 89.5 0.0 0.0 0.0 0.0 51231202416:59:37 89.2 0.0 0.0 0.0 0.0 51231202416:59:47 89.2 0.0 0.0 0.0 0.0 51231202416:59:57 89.4 0.0 0.0 0.0 0.0 51231202417:00:07 89.3 0.0 0.0 0.0 0.0 512312024'17:00:17 89.2 0.0 0.0 0.0 0.0 51231202417:00:27 89.3 0.0 0.0 0.0 0.0 51231202417:00:37 89.3 0.0 0.0 0.0 0.0 51231202417:00:47 89.3 0.0 0.0 0.0 0.0 51231202417:00:57 89.2 0.0 0.0 0.0 0.0 51231202417:01:07 89.4 0.0 0.0 0.0 0.0 51231202417:01:17 89-2 0.0 0.0 0.0 0.0 51231202417:01:27 89.2 0.0 0.0 0.0 0.0 51231202417:01:37 89.4 0.0 0.0 0.0 0.0 51231202417:01:47 89.3 0.0 0.0 0.0 0.0 51231202417:01:57 89.2 0.0 0.0 0.0 0.0 51231202417:02:07 89.3 0.0 0.0 0.0 0.0 51231202417:02:17 89.3 0.0 0.0 0.0 0.0 51231202417:02:27 89.2 0.0 0.0 0.0 0.0 51231202417:02:37 89.1 0.0 0.0 0.0 0.0 51231202417:02:47 89.4 0.0 0.0 0.0 0.0 51231202417:02:57 89.3 0.0 0.0 0.0 0.0 51231202417:03:07 89.4 0.0 0.0 0.0 0.0 51231202417:03:17 89.2 0.0 0.0 0.0 0.0 51231202417:03:27 89.2 0.0 0.0 0.0 0.0 51231202417:03:37 89.2 0.0 0.0 0.0 0.0 51231202417:03:47 89.0 0.0 0.0 0.0 0.0 I I I I I I I t I 202 of 22o GPoslAs-0417s7-RT-1600 t 512312024 17:03:57 512312024 17:04:07 512312024 17:04:17 512312024 17:04:27 512312024 17:04:37 512312024 17:04:47 512312024 17:04:57 512312024 17:05:07 512312024 17:05:17 512312024 17:05:27 512312024 17:05:37 512312024 17:05:47 512312024 17:05:57 512312024 17:06:07 512312024 17:O6:17 512312024 17:06:27 512312024 17:06:37 512312024 17:06:47 512312024 17:06:57 512312024 17:07:07 512312024 17:07:17 512312024 17:07:27 512312024 17:07:37 512312024 17:07:47 512312024 17:07:57 512312024 17:08:07 512312024 17:08:17 512312024 17:08:27 512312024 17:08:37 512312024 17:08:47 512312024 17:08:57 512312024 17:09:07 512312024 17:09:17 512312024 17:09:27 512312024 17:09:37 512312024 17:09:47 512312024 17:09:57 512312024 17:'10:07 512312024 17:10:17 512312024 17:10:27 512312024 17:10:37 512312024 17:10:47 512312024 17:10:57 512312024 17:11:07 512312024 17:'11:17 512312024 17:11:27 512312024 17:'t't:37 512312024 17:11:47 512312024 17:11:57 512312024 17:12:07 512312024 17:12:17 512312024 17:12:27 512312024 17:12:37 512312024 17:12:47 512312024 17:12:57 89.2 89.4 89.3 89.4 89.3 89.2 89.2 89.4 89.2 89.1 89.4 89.1 89.3 89.3 89.2 89.2 89.2 89.3 89.1 89.2 89.3 89.4 89.2 89.2 89.3 89.1 89.1 89.2 89.1 89.0 89.2 89.3 89.2 89.1 89.2 89.1 89.1 89.2 89.1 89.1 89.3 89.0 88.9 89.0 89.0 89.1 89.1 89.0 89.2 89.1 89.1 88.8 89.0 89.2 89.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 2O3 of 22O GP08 1AS-041757-RT- 1600 512312024 17:13:07 512312024 17:13:17 512312024 17:13:27 512312024 17:13:37 512312024 17:13:47 512312024 17:13:57 512312024 17:14:07 512312024 17:14:17 512312024 17:14:27 512312024 17:14:37 512312024 17:14:47 512312024 17:14:57 512312024 17:15:07 512312024 17:15:17 512312024 17:15:27 512312024 17:15:37 512312024 17:15:47 512312024 17:15:57 512312024 17:16:07 512312024 17:16:17 512312024 17:16:27 512312024 17:16:37 512312024 17:16:47 512312024 17:16:57 512312024 17:17:07 512312024 17:17:17 512312024 17:17:27 512312024'17:17:37 512312024 17:17:47 512312024 17:17:57 512312024 17:18:07 512312024 17:18:17 512312024 17:18:27 512312024 17;18:37 512312024 17:18:47 512312024 17:18:57 512312024 17:19:OT 512312024 17:19:17 512312024 17:19:27 512312024 17:19:37 512312024 17:19:47 512312024 17:'19:57 512312024 17:20:07 512312024 17.,20:17 512312024 17:20:27 512312024 17:20:37 512312024 17:20:47 512312024 17:20:57 512312024 17:21:07 512312024 '17:21:17 512312024 17:21:27 512312024 17:21:37 512312024 17:2'l:47 512312024 17:21:57 512312024 17:22:07 89.0 89.2 89.0 89.0 89.2 89.0 88.7 89.0 88.9 89.0 89.0 88.8 88.8 89.2 88.9 89.0 88.9 88.9 89.0 89.0 89.0 88.9 88.7 88.9 89.0 88.9 89.0 89.0 88.9 89.0 88.9 88.7 88.8 88.7 89.0 88.9 89.0 89.0 88.9 88.9 88.6 89.1 88.8 88.9 89.1 89.0 89.0 88.8 89.0 88.9 88.8 88.7 88.7 89.0 88.8 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 2O4 of 22O GP08 1AS-041757- RT- 1600 T I 512312024 17:22:17 512312024 17:22:27 512312024 17:22:37 512312024 17:22:47 512312024 17:22;57 512312024 17:23:07 512312024 17:23:17 512312024 17:23:27 512312024 17:23:37 512312024 17:23:47 512312024 17:23:57 512312024 17:24:07 512312024 17:24:17 512312024 17:24:27 512312024 17:24:37 512312024 17:24:47 512312024 17:24:57 512312024 17:25:07 512312024 17:25:17 512312024 17:25:27 512312024 17:25:37 512312024 17:25:47 512312024 17:25:57 512312024 17:26:07 512312024 17:26:17 512312024 17:26:27 512312024 17:26:37 512312024 17:26:47 512312024 17:26:57 512312024 17:27:07 512312024 17:27:17 88.9 88.9 88.9 88.6 58.0 3.0 1.6 2.0 0.7 0.1 0.3 0.2 0.2 0.2 0.2 0.1 0.1 0.0 0.2 0.1 0.1 0.1 0.2 0.1 0.6 0.7 0.5 0.0 0.0 0.0 -0.2 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0,0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 I I I I I I I I I I 205 of 22O GP08 1AS-041757-RT- 1600 Appendix C.4 Calibration Gas Certificates GP08 1AS-041757-RT-1600 I t Doolrlur$cr: lUlll7! Lrtga u.. c qlgiraElaa llE ttToo !.Alelttedr torrtLooArt bCAt00ttTrl: tzl4!l{t5{F.x:71a{4a{t!i FOVP IB F:UO2I I I I I I I I I I I I I I I I I I ffindHtnhlr..b.oF.FltdarorrqU.t!yqrJd!..l.prbrftt lhdrcrf EqfprrdlB trtl$rtldLf,frltrhtfi&.ib.drtrfinh.lrnllC0l..naltdrlrrErrcst ortranrHoomcltldIrr?.&Irqx.Ftfin 4-r*rm;a4,r'rrrr*-t-ahrJ[&otlh.rrdtrlfiilfrrE.lvprror.,Ih.ilb.rfirLcffiili!runcttfitrtt:]lr.Dotirt,oarlbrlatrbc.laErrirltld!!.r, hm.v.rrlr!1rl-Iyol l5d.o..3EcrFrrrB.astq.noltrrr-dlrffioncoalrhdluitE dG.f.tl&ljtrEu,6ne rdhtil!.lfl Pre.loll ,Q/tu nL Crfrd fy CERTTFICATE OF AT{ALYSIS / EPA PROTOCOL GAS C},Ai,o'],,,&(ruI4brt dot L(EFl(oFRo\'OuITlllzti ! lltDtBlnnl PXWYFR(l,ilr,T tao{li **dEr-Edr.6r0crltrE Ifr.Or(lhflAnh lrllzo+raFrrrfirlr: Ia tttotEE{saffForSrar: tLiut9s tr*o{raim Lorr*rrr: 70t(ll(10.Crfte$aaatttAl og^@ QEa,,'tfitt ttrdaG 2O0p.h l/t413 ForRdaauc Cedffulion Inlonsfun:Corfrf,/t/r,tDrtc:06mn0l23 lcrm: E8Monthl Erybatlon Odta: 05/04/20111 Thbctl.|roril.d.dntrrb0rr2Ol2EP^tr.r..tryho.ol.hr.natcP /Eo,E,lzrEtf.uhf Ft!.inO't.th-.lddrrborLGF!-dr.bdb4.nfid ,;;rimylrr,lo,q#rautmrdaOlyi6tagtnrry.lb.r'ZDtlqtLLltatIi.Siht-ul!h h.thr! 1oOPaO. 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Abmed.8b..t LooAngcbr CA0O05ITd:t2:ld6fl5aFu:7ll{l2ittE POVPtr)l2frE2otz2 IDocllumtoc JlGl0l CERTIFICATE OF ANALYSIS / EPA PROTOCOL GAS I CwolOilalqrotttu rcTTRO8€ AN ql^UTY !ETN4CE'relttrowSEArs!fl FOF!( UT !ae.to. C..n!-fr!:uEA.l',,'tllta,,, Ltudt*t.,df,|t1?d,tg7lHrttd.r:NlMEIIC{8 t&.3ois,,lnalLdffrnr:roEtla&l Iqrfr*Sor.tOe ABGid,*handf,SaG10fde oc^t0t$t, C.oacqtafua Iocrfl120!0 Cy'lnder Nur$en ALg{SZ1CC Expordod t nc.rbtrly Al Wn llltrlcorl& tt ppm Brhtc' ilfogcn I For Rc{ucacc Only: ncrx2tT pwt Ccrtlfiudoalnfotnalloa: @ffibatloz.0otc:oon1Bozz lona:g6ltionthr turfzdqnoue,:OAmrZ}l/J tT}r.qfh.IEsrrtd.En'lgterh2012Emfmolryfuet DoE[.nlEP]&i'IZ!SI.gritProaArrOt.lho.i.tt,ttcirhlE.urrrrdOq.r{romufl(rv.lt bfldodr.h,t-dT9EttraU0$l;ill.6,qall'Et-2.9o t{ol t r nL8lmrtrd]Prrrrra brtiJr f 00 PtlO. AnsWcelM;t. A,lFrrn pFfralrt l, Srrird, ZrLfo e.+ CrOp Caiftl,Illlleda.i.hytrtli.ltrt Tyt rqltd-G Gfa6rOTO@e5t n Crrdo.Ett*c zt0FtlO,*dffir atrnalfruiltlE Tlr.IEEHulaaAi{9flru!,! 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Ettrt Lor Angclo CA00058 Tcl:323{EC{l$l Frr: 714-5t12-86t9 PGVP lD: F2llll23Docilumbor: 55lil76 I Crrffi. brm Od' 0t Oll2&Xl I.},6fu?,W.725i86,, Prrrli-D.r Nl OO26ME"AS o.,,,ur,PoMrn,rl,o8Iz2,,C Fatuomtaa Lo,r*rax rutEIEloa q/herSrJ,a t Afr AB COAtSoCwftwrnrdn..'20@Pde laoElI Ctt fraaMolrlotfron LOEPKO PROI'O UT }tB 1211 8 hlOlJlBrRlAL PXWY PRO/O UT !{dE{t!E I I I Cenifualon Informdon:Cefifrcgltlon Dab.'08r01202t lerm: 96 Monlha Exilraflon Dater 081012031 TLortnd.rwadi.dmrdhobor2orzEPATE .b[yP,obolDoorrriaEPljoorR.'t2r5llt.rhgProadmot.t otldnly_lbd.5..9lt..dd.b.olrl.ra.rd.d ;i1,Lty-d. bt i Ja -ot-+eanrlU 05!3 rfirr r imrlr Laor r . Z Oo t5t ttI lht Snilttd f Pm b ba rnlr tO PAIG. I AnalytlcAl Dda.' (F-ntr'flo srsd' zrzm o.l, cros c'T drt' l. cocan,rc crrbonnoood.h R.ta.nolbndt'rl! 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Name: Beckie Hawkins Title: District Manager Region: Great Plains Region, Utah Office Email : BeHawkins@montrose-env.com Phone: 80 L-372-7O49 Name: Title: Region: Email: Phone: Cheyney Guymon Field Project Manager Great Plains Region, Utah Office ChGuymon@ montrose-env. com 801-352 -4978 AH DEPARTME IRONMENTAL ( JUN 26 2024 \LITYl DIVISION OF AIR OUALlTY 220 of 220 GP08 1AS-041757-RT- 1600 Sunnyside EU#1 RATA RM 1, 2, 3A, 4, 6C, 7E (tested 5-23-2024) Reference Methods 2, 3A, 6C, 7E, 10, & 19 Source Information Company Name Sunnyside Cogen. Company Contact:Rusty Netz Contact Phone No.435-888-4476 Stack Designation:Unit No. 1 Test & Review Dates Test Date:5/23/2024 Review Date: 10/3/2024 Observer:Not Observed Reviewer:Rob Leishman Emission Limits Emission Rates SO2 NOX CO SO2 NOX CO lbs./MMBtu 0.4200 0.2500 0.0850 0.186 0.254 0.013 lbs./hr. 462.0 142.94 ppm 207.9 96.20 87.530 13.455 %O2 Correction as a whole # Test Information Stack I.D. inches As ft^2 Y Dl H @ Cp Pbar Pq (static) Ps Stack Pressure 101.00 55.638 1.0060 1.695 0.8411 25.32 -0.75 25.264853 Contractor Information Contact:Andrew Bruning Contracting Company: Montrose Air Quality Services Address: 990 W 43rd Avenue, Denver, CO 80211 Phone No.: 303-810-2168 Project No.: 1800 Division of Air Quality Instrumental Reference Methods - Gaseous Measurements Round Method 19 - F factors for Coal, Oil, and Gas Fd Fw Fc dscf/MMBtu wscf/MMBtu scf/MMBtu Diluent F factor used O2 CO2 Anthracite 2 Bituminous 2 Lignite Natural Propane Butane 10100 COAL OIL GAS 9780 9860 9190 8710 8710 8710 10540 10640 11950 320 10610 10200 10390 1970 1800 1910 1420 1040 1190 1250 Wet CEM Correct For O2 CO2 Interference w/CO Yes Yes Yes Sunnyside EU#1 RATA RM 1, 2, 3A, 4, 6C, 7E (tested 5-23-2024) Company Sunnyside Cogen. Point Source Unit No. 1 Test Date 5/23/24 Start Time End Time Run CO2 % Flow SCFM NOx PPM SO2 PPM Production MW NOx lb/MMBtu O2 % SO2 lb/hr SO2 ln/MMBtu Headers Here Headers Here Headers Here 10:36 10:57 1 14 175005.3 166.1 71.9 55.2 0.268 5.8 102.4 0.162 11:10 11:31 2 13.9 174799.5 168.2 78.2 55.2 0.273 5.9 111.7 0.176 11:43 12:04 3 13.9 174652.5 165 88 55.2 0.268 5.9 125.6 0.198 12:16 12:37 4 13.9 174205.7 164.3 85.4 55 0.266 5.9 121.8 0.193 13:21 13:42 5 13.9 174094.7 165.6 84.7 55.1 0.269 5.9 120.7 0.191 13:56 14:17 6 14 174459.6 167.5 85.5 55.2 0.271 5.9 121.9 0.193 14:32 14:53 7 14 174968.3 170.5 82.4 55.1 0.276 5.9 117.3 0.186 15:05 15:26 8 13.9 175156.4 169 81.9 55 0.274 5.9 116.8 0.185 15:38 15:59 9 13.9 174640.4 167.7 83.4 55 0.272 5.9 119.1 0.188 16:12 16:33 10 13.9 174226.3 166.6 87 55 0.27 5.9 123.8 0.196 11 12 13 14 15 16 Sunnyside EU#1 RATA RM 1, 2, 3A, 4, 6C, 7E (tested 5-23-2024) Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Sunnyside Cogen. Unit No. 1 SO2 Analyzer:Serial No.: CO2 Analyzer:Serial No.: Acquisition System:Serial No.: Acquisition System: Serial No.: Equivalent Emission Limit:207.94 0.42 462.00 Test Date SO2 Dry SO2 Dry SO2 Test Date % CO2 Dry 5/23/2024 RM CEMS Diff RM CEMS Diff RM CEMS Diff 5/23/2024 RM CEMS Diff Run#Start Time End Time ppm lbs./MMBtu lbs./hr. Run# Start Time End Time %c %c 1 10:36 10:57 Y 69.1 71.9 -2.80 0.1483 0.162 Y 113.30 102.4 10.9 1 10:36 10:57 Y 13.9 14 -0.06 2 11:10 11:31 Y 82.6 78.2 4.43 Y 0.1768 0.176 0.001 Y 135.88 111.7 24.2 2 11:10 11:31 Y 14.0 13.9 0.08 3 11:43 12:04 Y 94.1 88 6.06 Y 0.2021 0.198 0.004 Y 153.41 125.6 27.8 3 11:43 12:04 Y 13.9 13.9 0.02 4 12:16 12:37 Y 91.3 85.4 5.94 Y 0.1957 0.193 0.003 Y 147.80 121.8 26.0 4 12:16 12:37 Y 14.0 13.9 0.07 5 13:21 13:42 Y 84.7 84.7 -0.01 Y 0.1800 0.191 -0.011 Y 137.21 120.7 16.5 5 13:21 13:42 Y 14.1 13.9 0.17 6 13:56 14:17 93.3 85.5 Y 0.1955 0.193 0.002 153.15 121.9 6 13:56 14:17 Y 14.3 14 0.28 7 14:32 14:53 Y 88.4 82.4 6.01 Y 0.1866 0.186 0.001 Y 144.37 117.3 27.1 7 14:32 14:53 Y 14.2 14 0.17 8 15:05 15:26 Y 88.4 81.9 6.50 Y 0.1886 0.185 0.004 Y 144.02 116.8 27.2 8 15:05 15:26 Y 14.0 13.9 0.12 9 15:38 15:59 Y 90.0 83.4 6.57 Y 0.1898 0.188 0.002 Y 147.55 119.1 28.5 9 15:38 15:59 14.2 13.9 10 16:12 16:33 Y 93.4 87 6.36 Y 0.1969 0.196 0.001 Y 152.75 123.8 29.0 10 16:12 16:33 Y 14.2 13.9 0.28 11 11 12 12 13 13 14 14 15 15 16 16 Average = 86.9 82.54 4.34 0.190 0.190 0.001 141.8 117.689 24.122 Average = 14.060 13.930 0.127 Sd Standard Deviation = 3.39 Sd Standard Deviation = 0.005 Sd Standard Deviation = 6.227 Sd Standard Deviation = 0.11 Confidence Coefficient = 2.61 Confidence Coefficient = 0.004 Confidence Coefficient = 4.8 Confidence Coefficient = 0.088 RA - Relative Accuracy = RA RA RA - Relative Accuracy =1.52% n = 9 9 9 n = 9 or RA of 1%0.13% t0.975 = 2.306 2.306 2.306 t0.975 = 2.306 E.L. Relative Accuracy = 42% 3.34% 45% 1.19% 31% 6.26% a For steam generators;b Average of three samples;9 c Make sure that RM and M data are on a consistent basis either wet or dry. 40 CFR 60 Performance Specification 2 For SO2 and NOx Continuous Emission Monitoring Systems 13.2 Relative accuracy Performance Specification. The RA of the CEMSS must be not greater than 20 percent when RM is used in the denominator of Eq. 2-6 (average emissions during test are greater than 50 percent of the emission standard)or 10 percent when the applicable emission standard is used in the denominator of Eq. 2-6 (average emissions during test are less than 50 percent of the emission standard). Up dated January 17, 2006 40 CFR 60 Performance Specification 3 For O2 and CO2 Continuous Emission Monitoring Systems 13.2 CEMS Relative Accuracy Perfromance Specification. The RA of the CEMS must be no grater than 20 percent of the mean value of the reference method (RM) data. 1 percent O2 or CO2. The results are also acceptable if the absolute value of the difference between the mean RM value and the mean CEMS value is less than or equal to 1.0 percent O2 (or CO2). Up dated September 14, 2016 40 CFR 60 Performance Specification 6 For Continuous Emission Rate Monitoring Systems (CERMS) 13.2 CERMS Relative Accuracy. The RA of the CERMS shall be no greater than 20 percent of the mean value of the RM's test data in terms of the nits of the emission standard, or 10 percent of the applicable standard, which err is greater. Up dated January 17, 2006 PassedPassedPassedPassed Ac t i v a t e R u n ? Ac t i v a t e R u n ? Ac t i v a t e R u n ? Eco Chem - MC3 163 Ac t i v a t e R u n ? Sunnyside EU#1 RATA RM 1, 2, 3A, 4, 6C, 7E (tested 5-23-2024) Division of Air Quality Relative Accuracy Test Audit of Sunnyside Cogen. Unit No. 1 NOX Analyzer:Serial No.: O2 Analyzer:Serial No.: Acquisition System:Serial No.: Acquisition System: Serial No.: Equivalent Emission Limit:0.25 Date NOx Dry NOx Dry NOx Test Date % O2 Dry 5/23/2024 RM CEMS Diff RM CEMS Diff RM CEMS Diff 9/30/2014 RM CEMS Diff Run#Start Time End Time ppm lbs./MMBtu lbs./hr. Run# Start Time End Time %c %c 1 10:36 10:57 Y 165.4 166.1 -0.7 Y 0.255 0.268 -0.013 194.94 1 10:36 10:57 Y 5.6 5.8 -0.167 2 11:10 11:31 Y 167.0 168.2 -1.2 Y 0.257 0.273 -0.016 197.42 2 11:10 11:31 Y 5.6 5.9 -0.261 3 11:43 12:04 Y 163.9 165 -1.1 Y 0.253 0.268 -0.015 192.17 3 11:43 12:04 Y 5.6 5.9 -0.261 4 12:16 12:37 Y 162.8 164.3 -1.5 Y 0.251 0.266 -0.015 189.37 4 12:16 12:37 Y 5.6 5.9 -0.261 5 13:21 13:42 Y 164.2 165.6 -1.4 Y 0.251 0.269 -0.018 191.21 5 13:21 13:42 Y 5.7 5.9 -0.160 6 13:56 14:17 Y 167.1 167.5 -0.4 0.251 0.271 197.04 6 13:56 14:17 Y 5.6 5.9 -0.261 7 14:32 14:53 Y 169.3 170.5 -1.2 Y 0.257 0.276 -0.019 198.74 7 14:32 14:53 Y 5.6 5.9 -0.261 8 15:05 15:26 167.3 169 Y 0.257 0.274 -0.017 195.91 8 15:05 15:26 Y 5.7 5.9 -0.160 9 15:38 15:59 Y 167.2 167.7 -0.5 Y 0.253 0.272 -0.019 197.08 9 15:38 15:59 5.7 5.9 10 16:12 16:33 Y 165.4 166.6 -1.2 Y 0.251 0.27 -0.019 194.49 10 16:12 16:33 Y 5.6 5.9 -0.261 11 11 12 12 13 13 14 14 15 15 16 16 Average = 165.8 166.8 1.013 0.25 0.271 0.017 Average = 5.660 5.880 0.228 Sd Standard Deviation = 0.38 Sd Standard Deviation = 0.002 Sd Standard Deviation = Sd Standard Deviation = 0.05 Confidence Coefficient = 0.294 Confidence Coefficient = 0.002 Confidence Coefficient = Confidence Coefficient = 0.037 RA - Relative Accuracy =0.80%Relative Accuracy =7.50%Relative Accuracy = RA - Relative Accuracy =4.68% n = 9 9 0 n = 9 or RA of 1%0.22% t0.975 = 2.306 t0.975 = 2.306 t0.975 = t0.975 = 2.306 E.L. Relative Accuracy = EMRA 102% EMRA a For steam generators;b Average of three samples; c Make sure that RM and M data are on a consistent basis either wet or dry. 40 CFR 60 Performance Specification 2 For SO2 and NOx Continuous Emission Monitoring Systems 4. Performance and Equipment Specifications 4.3 Relative accuracy. The RA of the CEMSS shall be no grater than 20 percent of the mean value of the RM test data in terms of the units of the emission standard or 10 percent of the applicable standard, whichever is greater For SO2 emission standards between 0.30 and 0.20 lbs./MMBtu use 15 Percent of the applicable standard; For SO2 emission standards below 0.20 lbs./MMBtu use 20 Percent of the emission standard; 40 CFR 60 Performance Specification 3 For O2 and CO2 Continuous Emission Monitoring Systems 12. Calculate the arithmetic difference between the RM and the CEMSS output for each run. The average of the nine (of more) data sets constitute the RA. 13.2 Relative accuracy. The RA of the CEMSS must be no grater than 1 percent O2 or CO2. 40 CFR 60 Performance Specification 6 For Continuous Emission Rate Monitoring Systems (CERMS) 13.2 CERMS Relative Accuracy. The RA of the CERMS shall be no greater than 20 percent of the mean value of the RM's test data in terms of the nits of the emission standard, or 10 percent of the applicable standard, which err is greater. Up dated January 17, 2006 Ac t i v a t e R u n ? Ac t i v a t e R u n ? Ac t i v a t e R u n ? Ac t i v a t e R u n ? PassedPassedPassed 163Eco Chem - MC3 Eco Chem - MC3 163 Sunnyside EU#1 RATA RM 1, 2, 3A, 4, 6C, 7E (tested 5-23-2024) Division of Air Quality Relative Accuracy Test Audit of Sunnyside Cogen. Unit No. 1 CO Analyzer:Serial No.: Acquisition System: Acquisition System: Serial No.: Equivalent Emission Limit:96.20 0.085 Date CO Dry CO Dry CO 5/23/2024 RM CEMS Diff RM CEMS Diff RM CEMS Diff Run#Start Time End Time ppm lbs./MMBtu lbs./hr. 1 10:36 10:57 13.93 0.013 9.99 2 11:10 11:31 13.51 0.013 9.72 3 11:43 12:04 13.36 0.013 9.53 4 12:16 12:37 13.58 0.013 9.61 5 13:21 13:42 13.45 0.013 9.54 6 13:56 14:17 13.40 0.012 9.62 7 14:32 14:53 13.30 0.012 9.50 8 15:05 15:26 13.46 0.013 9.59 9 15:38 15:59 13.28 0.012 9.53 10 16:12 16:33 13.28 0.012 9.51 11 12 13 14 15 16 Average = Sd Standard Deviation = Confidence Coefficient = RA - Relative Accuracy = n = 0 0 0 t0.975 = E.L. Relative Accuracy = a For steam generators;b Average of three samples; c Make sure that RM and M data are on a consistent basis either wet or dry. 40 CFR 60 Performance Specification 4 For Carbon Monoxide (CO) Continuous Emission Monitoring Systems applicable emission standard is used to calculate RA. 40 CFR 60 Performance Specification 4A For Carbon Monoxide (CO) Continuous Emission Monitoring Systems 13.2 Relative accuracy. The RA of the CEMSS must be no greater than 10 percent when the average RM value is used to calculate RA, 5 percent when the applicable emission standard is used to calculate RA, or within 5 ppmv when the RA is calculated as the absolute average difference between the RM and CEMSS plus the 2.5 percent confidence coefficient. 40 CFR 60 Performance Specification 6 For Continuous Emission Rate Monitoring Systems (CERMS) 13.2 CERMS Relative Accuracy. The RA of the CERMS shall be no greater than 20 percent of the mean value of the RM's test data in terms of the nits of the emission standard, or 10 percent of the applicable standard, which err is greater. Up dated January 17, 2006 13.2 Relative accuracy. The RA of the CEMSS must be no grater than 10 percent when the average of the RM value is used to calculate RA or 5 percent when the Ac t i v a t e R u n ? Ac t i v a t e R u n ? Ac t i v a t e R u n ? Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Dry Volumetric Flow dscfh Run Date Start Time End Time RM CEM Diff 1 5/23/24 10:36 10:57 9,866,135.59 2 5/23/24 11:10 11:31 9,895,226.52 3 5/23/24 11:43 12:04 9,813,558.50 4 5/23/24 12:16 12:37 9,736,842.56 5 5/23/24 13:21 13:42 9,748,817.63 6 5/23/24 13:56 14:17 9,873,154.58 7 5/23/24 14:32 14:53 9,825,879.13 8 5/23/24 15:05 15:26 9,802,994.41 9 5/23/24 15:38 15:59 9,868,883.51 10 5/23/24 16:12 16:33 9,845,434.07 11 5/23/24 12 5/23/24 13 5/23/24 14 5/23/24 15 5/23/24 16 5/23/24 Average = Standard Deviation Confidence Coefficient = RA - Relative Accuracy = n = 0 t0.975 = Dry Volumetric Flow dscfm Run Date Start Time End Time RM CEM Diff 1 5/23/24 10:36 10:57 164,435.59 2 5/23/24 11:10 11:31 164,920.44 3 5/23/24 11:43 12:04 163,559.31 4 5/23/24 12:16 12:37 162,280.71 5 5/23/24 13:21 13:42 162,480.29 6 5/23/24 13:56 14:17 164,552.58 7 5/23/24 14:32 14:53 163,764.65 8 5/23/24 15:05 15:26 163,383.24 9 5/23/24 15:38 15:59 164,481.39 10 5/23/24 16:12 16:33 164,090.57 11 5/23/24 12 5/23/24 13 5/23/24 14 5/23/24 15 5/23/24 16 5/23/24 Average = Standard Deviation En t e r Us e En t e r Us e Sunnyside Cogen. Unit No. 1 Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Sunnyside Cogen. Unit No. 1 Confidence Coefficient = RA - Relative Accuracy = n = 0 t0.975 = Actual Volumetric Flow acfm Run Date Start Time End Time RM CEM Diff 1 5/23/24 10:36 10:57 305,686.30 2 5/23/24 11:10 11:31 306,587.64 3 5/23/24 11:43 12:04 304,017.16 4 5/23/24 12:16 12:37 301,680.36 5 5/23/24 13:21 13:42 301,546.83 6 5/23/24 13:56 14:17 305,352.47 7 5/23/24 14:32 14:53 303,850.25 8 5/23/24 15:05 15:26 303,182.59 9 5/23/24 15:38 15:59 303,549.80 10 5/23/24 16:12 16:33 302,748.61 11 5/23/24 12 5/23/24 13 5/23/24 14 5/23/24 15 5/23/24 16 5/23/24 Average = Standard Deviation Confidence Coefficient = RA - Relative Accuracy = n = 0 t0.975 = WET VOLUMETRIC FLOW wscfh Run Date Start Time End Time RM CEM Diff 1 5/23/24 10:36 10:57 10,791,026.16 2 5/23/24 11:10 11:31 10,822,844.20 3 5/23/24 11:43 12:04 10,733,520.29 4 5/23/24 12:16 12:37 10,649,612.70 5 5/23/24 13:21 13:42 10,646,303.81 6 5/23/24 13:56 14:17 10,782,087.34 7 5/23/24 14:32 14:53 10,730,459.66 8 5/23/24 15:05 15:26 10,705,468.15 9 5/23/24 15:38 15:59 10,715,605.65 10 5/23/24 16:12 16:33 10,690,144.32 11 5/23/24 12 5/23/24 13 5/23/24 En t e r Us e En t e r Us e Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Sunnyside Cogen. Unit No. 1 14 5/23/24 15 5/23/24 16 5/23/24 Average = Standard Deviation Confidence Coefficient = RA - Relative Accuracy = n = 0 t0.975 = Wet Volumetric Flow wscfm Run Date Start Time End Time RM CEM Diff 1 5/23/24 10:36 10:57 Y 179,850.44 175005.3 4,845.14 2 5/23/24 11:10 11:31 180,380.74 174799.5 3 5/23/24 11:43 12:04 Y 178,892.00 174652.5 4,239.50 4 5/23/24 12:16 12:37 Y 177,493.54 174205.7 3,287.84 5 5/23/24 13:21 13:42 Y 177,438.40 174094.7 3,343.70 6 5/23/24 13:56 14:17 Y 179,701.46 174459.6 5,241.86 7 5/23/24 14:32 14:53 Y 178,840.99 174968.3 3,872.69 8 5/23/24 15:05 15:26 Y 178,424.47 175156.4 3,268.07 9 5/23/24 15:38 15:59 Y 178,593.43 174640.4 3,953.03 10 5/23/24 16:12 16:33 Y 178,169.07 174226.3 3,942.77 11 5/23/24 12 5/23/24 13 5/23/24 14 5/23/24 15 5/23/24 16 5/23/24 Average = 178,600.42 174,601.02 3,999.40 Standard Deviation 690 Confidence Coefficient = 530 RA - Relative Accuracy =1 2.5% n = 9 t0.975 =2.306 En t e r Us e Sunnyside EU#1 RATA RM 1, 2, 3A, 4, 6C, 7E (tested 5-23-2024) Test Overview NSPS Relative Accuracy Performance Specification Test - CEMS Certification Sunnyside Cogen. Point Source Unit No. 1 Contact Phone No.Rusty Netz Stack Designation:Unit No. 1 Project No.:0 Run Run # 1 Run # 2 Run # 3 Run # 4 Run # 5 Run # 6 Run # 7 Run # 8 Run # 9 Run # 10 Run # 11 Run # 12 Test Date 5/23/2024 5/23/2024 5/23/2024 5/23/2024 5/23/2024 5/23/2024 5/23/2024 5/23/2024 5/23/2024 5/23/2024 5/23/2024 5/23/2024 Start Time 10:36 11:10 11:43 12:16 13:21 13:56 14:32 15:05 15:38 16:12 Stop Time 10:57 11:31 12:04 12:37 13:42 14:17 14:53 15:26 15:59 16:33 Run Time 0:21 0:21 0:21 0:21 0:21 0:21 0:21 0:21 0:21 0:21 Stack I.D. (inches)101.00 101.00 101.00 101.00 101.00 101.00 101.00 101.00 101.00 101.00 101.00 101.00 As ft^2 55.64 55.64 55.64 55.64 55.64 55.64 55.64 55.64 55.64 55.64 55.64 55.64 Cp (Pitot Tube Coefficient)0.84 0.84 0.84 0.84 0.84 0.84 0.84 0.84 0.84 0.84 0.84 0.84 Yd Meter Y Factor (unit less)1.0060 1.0060 1.0060 1.0060 1.0060 1.0060 1.0060 1.0060 1.0060 1.0060 1.0060 1.0060 Pbar Barometric Pressure ("Hg)25.32 25.32 25.32 25.32 25.32 25.32 25.32 25.32 25.32 25.32 25.32 25.32 Pq (Static Pressure)-0.75 -0.75 -0.75 -0.75 -0.75 -0.75 -0.75 -0.75 -0.75 -0.75 -0.75 -0.75 Ps (Pressure of the Stack)25.26 25.26 25.26 25.26 25.26 25.26 25.26 25.26 25.26 25.26 25.26 25.26 Ts Stack Temp Avg. oF 297.80 297.80 297.70 297.80 297.70 297.60 297.50 297.60 297.80 297.60 Tm Meter Temperature oF 54.00 54.00 54.00 54.00 58.00 58.00 58.00 58.00 59.00 59.00 CO2 (carbon dioxide)13.94 13.98 13.92 13.97 14.07 14.28 14.17 14.02 14.18 14.18 O2 (oxygen)5.63 5.64 5.64 5.64 5.74 5.64 5.64 5.74 5.74 5.64 Md Molecular Weight Dry 30.46 30.46 30.45 30.46 30.48 30.51 30.49 30.47 30.50 30.49 #VALUE!#VALUE! Ms Molecular Weight Wet 29.39 29.39 29.38 29.39 29.43 29.46 29.44 29.42 29.51 29.50 #VALUE!#VALUE! N2 (nitrogen)80.43 80.38 80.44 80.40 80.19 80.08 80.19 80.24 80.08 80.18 #VALUE!#VALUE! Vm Sample Volume (cf)80.76 80.76 80.76 80.76 80.34 80.34 80.34 80.34 39.48 39.48 0.00 0.00 Vm std Standard Volume (dscf)70.60 70.60 70.60 70.60 69.69 69.69 69.69 69.69 34.18 34.18 Vlc Moisture (g)140.60 140.60 140.60 140.60 136.30 136.30 136.30 136.30 62.30 62.30 Vwstd Moisture Volume (scf)6.62 6.62 6.62 6.62 6.42 6.42 6.42 6.42 2.93 2.93 Bws Moisture Content (%100)8.57%8.57%8.57%8.57%8.43%8.43%8.43%8.43%7.90%7.90% S Bws (saturation moisture)99.90%99.90%99.90%99.90%99.90%99.90%99.90%99.90%99.90%99.90% AvgSqrtDlp √∆P 1.261 1.264 1.254 1.244 1.244 1.261 1.254 1.251 1.254 1.251 Vs. Gas Velocity (ft./sec)91.57 91.84 91.07 90.37 90.33 91.47 91.02 90.82 90.93 90.69 Qa (stack actual flow rate) acfm 305,686 306,588 304,017 301,680 301,547 305,352 303,850 303,183 303,550 302,749 Qs (stack std. flow rate) dscfm 164,436 164,920 163,559 162,281 162,480 164,553 163,765 163,383 164,481 164,091 #VALUE!#VALUE! Qsd (stack std. flow rate) dscfh 9,866,136 9,895,227 9,813,559 9,736,843 9,748,818 9,873,155 9,825,879 9,802,994 9,868,884 9,845,434 Qw (stack flow rate) wscfm 10,791,026 10,822,844 10,733,520 10,649,613 10,646,304 10,782,087 10,730,460 10,705,468 10,715,606 10,690,144 Sunnyside EU#1 RATA RM 1, 2, 3A, 4, 6C, 7E (tested 5-23-2024) Test Overview NSPS Relative Accuracy Performance Specification Test - CEMS Certification Sunnyside Cogen. Point Source Unit No. 1 Contact Phone No.Rusty Netz Stack Designation:Unit No. 1 Project No.:0 Run Run # 1 Run # 2 Run # 3 Run # 4 Run # 5 Run # 6 Run # 7 Run # 8 Run # 9 Run # 10 Run # 11 Run # 12 Test Date 5/23/2024 5/23/2024 5/23/2024 5/23/2024 5/23/2024 5/23/2024 5/23/2024 5/23/2024 5/23/2024 5/23/2024 5/23/2024 5/23/2024 Heat Input - BTU/hr. F factor - scf/MMBtu 1800.0 1800.0 1800.0 1800.0 1800.0 1800.0 1800.0 1800.0 1800.0 1800.0 1800.0 1800.0 Fuel Analysis - ft3/min 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 1050.0 Fuel Flow - ft3/min 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 Heat Input - BTU/hr.0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SO2 Concentrations Uncorrected 68.80 81.60 93.20 90.90 84.60 93.10 88.40 88.60 90.20 93.40 Dry Corrected 69.10 82.63 94.06 91.34 84.69 93.34 88.41 88.40 89.97 93.36 Wet Corrected NOx Concentrations Uncorrected 165.80 167.60 164.50 163.40 164.70 167.50 169.80 167.80 167.70 165.90 Dry Corrected 165.42 167.03 163.94 162.82 164.20 167.08 169.33 167.31 167.18 165.38 Wet Corrected CO Concentrations Uncorrected 14.00 13.50 13.30 13.50 13.40 13.40 13.30 13.40 13.20 13.20 Dry Corrected 13.93 13.51 13.36 13.58 13.45 13.40 13.30 13.46 13.28 13.28 Wet Corrected CO2 Concentrations Uncorrected 13.90 13.90 13.90 14.00 14.10 14.30 14.20 14.00 14.10 14.10 Dry Corrected 13.94 13.98 13.92 13.97 14.07 14.28 14.17 14.02 14.18 14.18 Wet Corrected O2 Concentrations Uncorrected 5.80 5.80 5.80 5.80 5.90 5.80 5.80 5.90 5.90 5.80 Dry Corrected 5.63 5.64 5.64 5.64 5.74 5.64 5.64 5.74 5.74 5.64 Wet Corrected Sunnyside EU#1 RATA RM 1, 2, 3A, 4, 6C, 7E (tested 5-23-2024) Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Sunnyside Cogen. Unit No. 1 Average Emission Dry SO2 NOX CO lbs./MMBtu 0.186 0.254 0.013 Average % concentration lbs./hr.142.94 CO2 O2 ppm or % 87.53 165.97 13.46 14.07 5.67 Run 1 Enter O2 or CO2 Dry SO2 NOX CO CO2 O2 CO2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)1.48E-01 2.55E-01 1.31E-02 E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 1.148E-05 1.976E-05 1.013E-06 lbs./hr.113.30 194.94 9.99 13.94 5.63 ppm or %69.10 165.42 13.93 13.90 5.80 Run 2 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)1.77E-01 2.57E-01 1.26E-02 E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 1.373E-05 1.995E-05 9.823E-07 lbs./hr.135.88 197.42 9.72 13.98 5.64 ppm or %82.63 167.03 13.51 13.90 5.80 Raw Value Run 3 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)2.02E-01 2.53E-01 1.26E-02 E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 1.563E-05 1.958E-05 9.711E-07 lbs./hr.153.41 192.17 9.53 13.92 5.64 ppm or %94.06 163.94 13.36 13.90 5.80 Raw Value Run 4 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)1.96E-01 2.51E-01 1.27E-02 E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 1.518E-05 1.945E-05 9.874E-07 lbs./hr.147.80 189.37 9.61 13.97 5.64 ppm or %91.34 162.82 13.58 14.00 5.80 Raw Value Run 5 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)1.80E-01 2.51E-01 1.25E-02 E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 1.407E-05 1.961E-05 9.782E-07 lbs./hr.137.21 191.2106 9.54 14.07 5.74 ppm or %84.69 164.20 13.45 14.10 5.90 Raw Value Corrected For Cal. Drift Raw Value Corrected For Cal. Drift Corrected For Cal. Drift Corrected For Cal. Drift Corrected For Cal. Drift O2 CO2 Clear lbs./MMBTU Sunnyside EU#1 RATA RM 1, 2, 3A, 4, 6C, 7E (tested 5-23-2024) Division of Air Quality NSPS Relative Accuracy Performance Specification Test - CEMS Certification Sunnyside Cogen. Unit No. 1 O2 CO2 Clear lbs./MMBTU Run 6 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)1.95E-01 2.51E-01 1.23E-02 E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 1.551E-05 1.996E-05 9.743E-07 lbs./hr.153.15 197.0435 9.62 14.28 5.64 ppm or %93.34 167.08 13.40 14.30 5.80 Raw Value Run 7 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)1.87E-01 2.57E-01 1.23E-02 E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 1.469E-05 2.023E-05 9.672E-07 lbs./hr.144.37 198.74 9.50 14.17 5.64 ppm or %88.41 169.33 13.30 14.20 5.80 Raw Value Run 8 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)1.89E-01 2.57E-01 1.26E-02 E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 1.469E-05 1.999E-05 9.784E-07 lbs./hr.144.02 195.91 9.59 14.02 5.74 ppm or %88.40 167.31 13.46 14.00 5.90 Raw Value Run 9 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)1.90E-01 2.53E-01 1.23E-02 E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 1.495E-05 1.997E-05 9.655E-07 lbs./hr.147.55 197.07 9.53 14.18 5.74 ppm or %89.97 167.18 13.28 14.10 5.90 Raw Value Run 10 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)1.97E-01 2.51E-01 1.23E-02 E=Cd x Fc x (100 / % CO2d) lbs./cu.ft 1.552E-05 1.975E-05 9.655E-07 lbs./hr.152.75 194.49 9.51 14.18 5.64 ppm or %93.36 165.38 13.28 14.10 5.80 Raw Value Run 11 Dry SO2 NOX CO CO2 O2 Atomic Weight 64 46 28 lbs./MMBtu (O2)E=Cd x Fd x (20.9/(20.9-%O2d)) lbs./MMBtu (CO2)E=Cd x Fc x (100 / % CO2d) lbs./cu.ft lbs./hr. ppm or %Raw Value Corrected For Cal. Drift Corrected For Cal. Drift Corrected For Cal. Drift Corrected For Cal. Drift Corrected For Cal. Drift Corrected For Cal. Drift Sunnyside EU#1 RATA RM 1, 2, 3A, 4, 6C, 7E (tested 5-23-2024) Calibration Error Test Test Date May 23, 2024 O2 CS - Cal. Span 20.45 Units % Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 0.00 0.00 0.00% Passed Cal. Mid-level 10.07 10.20 0.13 0.64% Passed Cal. High-level 20.45 20.50 0.05 0.24% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of CS - Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 49.24% 100% of Cal. Span High-level 100.00% Test Date May 23, 2024 CO2 CS - Cal. Span 22.79 Units % Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 0.00 0.00 0.000% Passed Cal. Mid-level 11.97 11.80 0.17 0.746% Passed Cal. High-level 22.79 22.90 0.11 0.483% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 52.52% 100% of Cal. Span High-level 100.00% Test Date May 23, 2024 SO2 CS - Cal. Span 238.00 Units ppm Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 0.10 0.10 0.042% Passed Cal. Mid-level 99.80 99.90 0.10 0.042% Passed Cal. High-level 238.00 238.70 0.70 0.294% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 41.93% 100% of Cal. Span High-level 100.00% Test Date May 23, 2024 NOx CS - Cal. Span 247.00 Units ppm Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 0.00 0.00 0.000% Passed Cal. Mid-level 101.90 101.30 0.60 0.243% Passed Cal. High-level 247.00 247.10 0.10 0.040% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 41.26% 100% of Cal. Span High-level 100.00% Test Date May 23, 2024 CO CS - Cal. Span 50.20 96.2 Units ppm Cylinder No. Expiration Date Cal. Gas CV- Certified Concentration CDir or CS - Measured Concentration Difference ACE Eq. 7E-1 Analyzer Cal. Error Status Low-level 0.00 0.10 0.10 0.199% Passed Cal. Mid-level 25.30 25.70 0.40 0.797% Passed Cal. High-level 50.20 50.10 0.10 0.199% Passed Cal. % of Span Sec. 8.2.1 Cal Gas Verification 0 to 20% of Cal. Span Low-Level 0.00% 40 to 60% of Cal. Span Mid-level 50.40% 100% of Cal. Span High-level 100.00%