Loading...
HomeMy WebLinkAboutDAQ-2024-0104681 DAQC-957-24 Site ID 12103 (B4) MEMORANDUM TO: STACK TEST FILE – MOUNTAINWEST PIPELINE, LLC – Oak Spring Turbine Compressor Station THROUGH: Rik Ombach, Minor Source Oil and Gas Compliance Section Manager FROM: Paul Bushman, Environmental Scientist DATE: September 24, 2024 SUBJECT: Source: Solar Taurus 60-7800S Turbine; Unit ID: Turbine T-3 Location: 6.5 miles west of Spring Glen remote site in Carbon County Contact: Dani Baldwin: 801-201-2595 Tester: Oasis Emission Consultants, Inc. Site ID #: 12103 Permit/AO #: DAQE-AN121030019-20, dated July 14, 2020 Subject: Review of Pretest Protocol dated September 23, 2024 On September 23, 2024, Utah Division of Air Quality (DAQ) received a protocol for testing of Turbine T-3 at MountainWest Pipeline, LLC Oak Spring Turbine Compressor Station in Carbon County, Utah. Testing will be performed on November 12, 2024, to determine compliance with the emission limits found in condition II.B.2 of DAQE-AN121030019-20 and 40 CFR Part 60, Subpart GG. PROTOCOL CONDITIONS: 1. RM 1 used to determine sample velocity traverses: OK 2. RM 3A used to determine O2 and CO2 concentrations: OK 3. RM 7E used to determine NOx emissions: OK 4. RM 10 used to determine CO emissions: OK 5. RM 19 used to determine the exhaust effluent flow: OK 6. RM 20 used to determine emissions from stationary combustion turbines: OK DEVIATIONS: None. CONCLUSION: The protocol appears to be acceptable. RECOMMENDATION: Send protocol review and test date confirmation notice. ATTACHMENTS: MountainWest Pipeline, LLC test notification letter and pretest protocol. Via Electronic September 23, 2024 Utah Division of Air Quality Attn: Director, NSR Section P.O. Box 144820 Salt Lake City, UT 84114-4820 RE: MountainWest Pipeline, LLC Oak Spring Turbine Compressor Station Approval Order DAQE-AN121030019-20 Performance Test Notification for T-3 Dear Mr. Bird: The purpose of this correspondence is to provide notification that Oak Spring Turbine Compressor Station will be conducting a performance test on the Solar Taurus 60-7800S turbine, T-3. The turbine will be tested for nitrogen oxides (NOX) and carbon monoxide (CO) emissions in accordance with the Approval Order Number DAQE-AN121030019-20, Condition II.B.2.a. The performance test is scheduled for November 12, 2024, between the hours of 7:00 A.M. and 7:00 P.M. However, in the event of unforeseen circumstances, or as operational conditions dictate, testing may extend past 7:00 P.M. The performance test protocol is enclosed for your review. Questions regarding this submittal should be referred to Dani Baldwin at (801) 201-0595 or dani.baldwin@williams.com. Sincerely, Dani Baldwin Environmental Specialist Enclosure MountainWest Pipeline, LLC P.O. Box 45922 Salt Lake City, Utah 84145 Utah Department of Environmental Quality Division of Air Quality Source Test Protocol Approval Order # DAQE-AN121030019-20 & EPA 40 CFR 60 (NSPS), Subpart GG Turbine: Solar Taurus 60-7800S Permit ID: T-3 Unit ID: #3 MountainWest Pipeline, LLC Oak Spring Turbine Compressor Station, Carbon County, Utah September 23, 2024 Prepared By: Oasis Emission Consultants, Inc. 2730 Commercial Way Rock Springs, WY 82901 CERTIFICATION STATEMENT This statement certifies that “to the best of their knowledge,” based on State and Federal regulations, operating permits, plan approvals applicable to each source or control device to be tested, and reasonable inquiry, the statements and information presented in the attached document are true, accurate, and complete. If the information herein is found to be inaccurate or incomplete by any participant, the protocol will be reviewed and all reasonable measures will be taken to make necessary changes. SOLAR TAURUS 60-7800S PERMIT ID: T-3 / UNIT ID: #3 COMPLIANCE TEST PROTOCOL MOUNTAINWEST PIPELINE, LLC OAK SPRING TURBINE COMPRESSOR STATION / CARBON COUNTY / UTAH Name: Shawna O’Brien______ Date: September 23rd, 2024 Title: Sr. Environmental Scientist Company: Oasis Emission Consultants, Inc. Signature: ________________________________________________ __________________ Dani Baldwin Date Environmental Specialist MountainWest Pipeline, LLC 9/23/2024 1 TABLE OF CONTENTS 1.0 Introduction........................................................................................................................................2 1.1 Test Program Organization.......................................................................................................2 1.2 Test Project Objective(s)...........................................................................................................4 1.3 Facility Description..................................................................................................................5 2.0 Source Test Program Description.......................................................................................................5 2.1 Test Contractor........................................................................................................................5 2.2 Test Date.................................................................................................................................5 2.3 Time........................................................................................................................................5 2.4 Report Date.............................................................................................................................5 2.5 Test Report Format..................................................................................................................6 3.0 Testing Methodology and Procedures................................................................................................7 3.1 Permitted Limits and Standards................................................................................................7 3.1.1 UDEQ AO # DAQE-AN121030019-20 Limits...........................................................................7 3.1.2 NSPS Subpart GG Standard........................................................................................7 3.2 Sampling Matrix......................................................................................................................7 3.3 Stack Sampling Location..........................................................................................................8 3.4 Emission Measurement Methodologies.......................................................................................9 3.4.1 Method 19 Fd Factor...............................................................................................12 3.5 Equipment Utilization.............................................................................................................12 3.6 Test Quality Assurance Procedures..........................................................................................12 3.6.1 Sampling Protocol...................................................................................................12 3.6.2 Equipment Calibration and Measurement....................................................................13 3.7 Turbine Load Approximation.................................................................................................13 3.8 Test Methods.........................................................................................................................13 List of Figures and Tables Table 1 – Report Contents................................................................................................................................6 Table 2 – Source Summary and Permitted Limitations....................................................................................7 Table 3 – NSPS Subpart GG NOx Standard.....................................................................................................7 Table 4 – Sampling Matrix...............................................................................................................................7 Figure 1 – Sample Location Diagram...............................................................................................................9 Figure 2 – EPA Method 3A, 7E and 10 Sampling Train Schematic..............................................................11 Appendices APPENDIX A: Example Calculations APPENDIX B: Sample Calibration Sheets 2 1.0 Introduction The purpose of this document is to provide relevant information pertaining to proposed emissions testing at MountainWest Pipeline, LLC’s Oak Spring Turbine Compressor Station in Carbon County, Utah. Emissions testing will be conducted in accordance with the Utah Department of Environmental Quality (UDEQ) Approval Order # DAQE-AN121030019-20 (Issuance Date: July 14, 2020) and in accordance with EPA 40 CFR 60 (NSPS), Subpart GG. The emission test is being conducted following a permanent like-kind turbine core replacement on the Solar Taurus 60-7800S turbine (Permit ID: T-3 or Turbine #3; Unit ID: #3). Testing will be conducted by Oasis Emission Consultants, Inc. 1.1 Test Program Organization Approval Order No.: DAQE-AN121030019-20 Federal Regulation: NSPS Subpart GG Facility / Location: Oak Spring Turbine Compressor Station (Site ID: 12103) The Oak Spring Turbine Compressor Station is located at a remote site approximately 6.5 miles west of Spring Glen in Carbon County, Utah. UTM Coordinates: 501,700 m Easting, 4,390,000 m Northing UTM Zone 12 Permit ID: T-3: Natural Gas Turbine Compressor, Solar Taurus 60-7800S The Oak Spring Compressor Station Unit #3 is identified as T-3 or Turbine #3 in UDEQ Approval Order (AO) # DAQE- AN1210300019-20 Section II.A.4. The turbine is subject to the requirements of NSPS Subpart GG. Client Owner / Operator: MountainWest Pipeline, LLC Address: P.O. Box 45922, Salt Lake City, UT 84145 Contact: Dani Baldwin, Environmental Specialist Email: Dani.Baldwin@Williams.com Cell.: (801) 201-0595 Test Company: Oasis Emission Consultants, Inc. Address: 2730 Commercial Way Rock Springs, WY 82901 Contact: Chris Knott, P.Eng., Director, Engineering & Operations Phone: (307) 382-3297 Fax: (307) 382-3327 3 State Authority: Utah Department Of Environmental Quality Address: PO Box 144820 Salt Lake City, UT 84114-4820 Contact: Rik Ombach, Minor Source Compliance Manager Email: rombach@utah.gov Phone: (801) 536-4164 Stack Test Report Submission: https://utahgov.co1.qualtrics.com/jfe/form/SV_3dSxf7JSzy4jwGh 4 1.2 Test Project Objective(s) The purpose of the emissions compliance demonstration is to satisfy the requirements of the UDEQ AO # DAQE-AN121030019-20 (Issuance Date: July 14, 2020) and NSPS Subpart GG. The Solar Taurus 60-7800S turbine had a permanent like-kind turbine core replacement. The overhauled turbine is being tested in accordance with the procedures of 40 CFR 60. In order to demonstrate compliance with NSPS Subpart GG, the turbine will be tested for nitrogen oxides (NOx) according to EPA Test Methods 1, 3A and 7E. Oxygen will be measured to allow for NOx emission levels to be corrected to 15% O2. Additionally, testing will be conducted to demonstrate compliance with UDEQ AO # DAQE-AN121030019-20 Conditions II.B.2.a., II.B.2.a.1. and II.B.2.a.2. Under the permit, testing for NOx and carbon monoxide (CO) at full load conditions will be conducted following EPA Test Methods 1, 3A, 7E, 10 and 19. Testing will comply with EPA’s Method 20 requirements. EPA Test Method 19 will be used to determine the volumetric flow rate based on the fuel flow determined by the fuel gas meter and exhaust O2 concentration. The Solar Taurus 60-7800S turbine will be tested for NOx for three test runs at three separate load points, selected from the normal operating range of the turbine, for a total of nine test runs. Each test run will consist of 21-minute readings. An additional three test runs will be performed at full load conditions for NOx and CO. Each test run will consist of 60 readings taken at one minute intervals. The three 21-minute test runs at the high load conditions for NOx (using Methods 1, 3A and 7E) will be taken from the required UDEQ permit three, one hour test runs to meet NSPS Subpart GG requirements. Thereby, a total of twelve test runs will be conducted on the turbine for NOx and a total of three test runs will be conducted on the turbine for CO. A detailed test procedure is provided in Section 3.4 of this protocol. The Solar Taurus 60-7800S turbine has a rated output of 7,684 horsepower (hp) at base load and a derated load, or site rated load, of 6,082 hp. The percent load during the test will be calculated based on the derated site horsepower. In accordance with 40 CFR 60.335(b)(2), NOx testing will be conducted at four evenly spaced load points in the normal operating range of the turbine, including the minimum point and the 90-to-100 percent peak load. If 90-to-100 percent peak load is not achievable in practice, testing will be conducted at the highest achievable load point. The turbine has a rated heat rate of 8,038 Btu/hp-hr at site rating. Process parameters expected to be collected during the performance testing include, but are not limited to: atmospheric pressure, atmospheric temperature, fuel flow, humidity and O2%. Turbine operating parameters (e.g. horsepower, %NGP and T-5) will be monitored during the test period and recorded on the turbine test sheets and included in the test report. 5 1.3 Facility Description MountainWest Pipeline, LLC operates the Oak Spring Turbine Compressor Station located approximately 6.5 miles west of Spring Glen in Carbon County, Utah. The Oak Spring Turbine Compressor Station consists of three turbine compressor engines and one backup generator. The facility is classified as a minor source. The compliance emission test will be conducted on the natural gas fired Solar Taurus 60-7800S turbine identified as T-3 or Turbine #3 in DAQE-AN121030019-20, Section II.A.4. 2.0 Source Test Program Description 2.1 Test Contractor All source emission tests will be performed by Oasis Emission Consultants, Inc., based out of Rock Springs and Sheridan, Wyoming. Processed test results and all raw data captured during the tests are forwarded to Chris Knott, P.Eng., Director of Engineering and Operations and/or Charles Chapman, Manager of Technical Services, for quality control and data checking. Once approved, tests are forwarded to the client. 2.2 Test Date Emissions testing is currently scheduled to be conducted and completed on November 12, 2024. 2.3 Time Testing is currently scheduled to be conducted between the hours of 7:00 A.M. and 7:00 P.M. However, in the event of unforeseen circumstances, or as operational conditions dictate, testing may extend past 7:00 P.M. 2.4 Report Date The compliance test report will be submitted to the UDEQ no later than 60 days following the compliance test. 6 2.5 Test Report Format The following table illustrates the format used for reports submitted. Table 1: Report Contents. Content Description Cover The cover will contain the air testing company information, facility name and source summary. Introduction The introduction will include the test objective and descriptions of the source and control equipment (as applicable). Stack Sampling Location The stack sampling location details the sampling site location. Discussion of Test Results The test results provide the results for each test run. Stack Sampling Methods and Procedures The stack sampling methods and procedures will include a detailed description of the methods utilized in the testing process and any deviations from the submitted protocol. Equipment Utilization The equipment utilization provides a list of the test equipment employed in conjunction with the sampling test methods. Process Parameters Process parameters summarizes the source parameters recorded during the test runs. Quality Assurances Quality assurance and quality control procedures pertaining to the methods and equipment calibrations will be included in the emission source test report. Appendices The report’s appendices will contain test data, quality assurance/calibration data, Fd factor determination, example equations and field notes. 7 3.0 Testing Methodology and Procedures 3.1 Permitted Limits and Standards The purpose of the compliance test on the Solar Taurus 60-7800S turbine is to demonstrate compliance for NOx and CO permit limits and the NSPS Subpart GG standard for NOx. The permitted limits and Subpart GG standard are provided in the following tables. 3.1.1 UDEQ AO # DAQE-AN121030019-20 Limits Table 2: Source Summary and Permitted Limitations. *The rated output is derived from UDEQ AO # DAQE-AN121030019-20. The permitted “base load” is the sea level performance for the Solar Taurus 60-7800S turbine. The “derated output” is the site rated load and is determined based on the altitude and site conditions. Therefore, this is the approved rating for the turbine load. The percent load during the test will be calculated based on the derated site horsepower. Oasis Emission Consultants, Inc. will approximate the turbine load using process parameters measured, such as gas throughput, suction/discharge pressure/temperature, manufacturer’s BSFC, panel reading or fuel measurement (if available). **The serial number will be provided in the test report, if currently unavailable. 3.1.2 NSPS Subpart GG Standard Table 3: NSPS Subpart GG NOx Standard. 3.2 Sampling Matrix Table 4: Sampling Matrix. Method Title Parameter Reference Number of Tests EPA 40 CFR 60 Appendix A, Method 1 Sample and Velocity Traverses for Stationary Sources Sampling Point Determination https://www.epa.gov/syst em/files/documents/2023- 09/2023%20Final%20MS %20%20Method%201_0. pdf EPA 40 CFR 60 Appendix A, Method 3A Determination of Oxygen and Carbon Dioxide Concentrations in Emissions From Stationary Sources (Instrumental Analyzer Procedure) O2 https://www.epa.gov/sites /default/files/2017- 08/documents/method_3a .pdf Permit ID Unit ID Source Rated Output* Permit NOx Permit CO T-3 (Turbine #3) Unit #3 Solar Taurus 60-7800S turbine 7,684 hp @ base load (6,082 hp derated) 8.70 lb/hr, 42 ppmvd @ 15% O2 6.30 lb/hr Permit ID Unit ID Source EPA Standard NOx T-3 (Turbine #3) Unit #3 Solar Taurus 60-7800S turbine 42 ppmvd @ 15% O2 8 EPA 40 CFR 60 Appendix A, Method 7E Determination of Nitrogen Oxides Emissions From Stationary Sources (Instrumental Analyzer Procedure) NOx https://www.epa.gov/sites /default/files/2020- 12/documents/method_7e _2.pdf 9 x 21 minutes and 3 x 1 hr EPA 40 CFR 60 Appendix A, Method 10 Determination Of Carbon Monoxide Emissions From Stationary Sources (Instrumental Analyzer Procedure) CO https://www.epa.gov/sites /default/files/2017- 08/documents/method_10 .pdf 3 x 1 hr EPA 40 CFR 60 Appendix A, Method 19 Determination of Sulfur Dioxide Removal Efficiency and Particulate Matter, Sulfur Dioxide and Nitrogen Oxide Emission Rates Exhaust effluent flow- mass emission rates will be calculated using Method 19 and the fuel consumption recorded during the tests https://www.epa.gov/sites /default/files/2017- 08/documents/method_19 .pdf 3 x 1 hr EPA 40 CFR 60 Appendix A, Method 20 Determination of Nitrogen Oxides, Sulfur Dioxide, and Diluent Emissions From Stationary Gas Turbines NOx https://www.epa.gov/sites /default/files/2017- 08/documents/method_20 .pdf EPA 40 CFR 60 Subpart GG §60.335 Subpart GG Standards of Performance for Stationary Combustion Turbines NOx https://www.ecfr.gov/curr ent/title-40/chapter- I/subchapter-C/part- 60/subpart-GG U.S. Environmental Protection Agency. “EMC Promulgated Test Methods.” Air Emission Measurement Center (EMC). 9 July 2024. Web. 23 September 2024. <https://www.epa.gov/ emc/emc-promulgated-test-methods>. U.S. Environmental Protection Agency. “Subpart GG–Standards of Performance for Stationary Combustion Turbines.” Title 40: Protection of Environment. Part 60 –Standards of Performance for New Stationary Sources (Continued). Title 40. Chapter 1. Subchapter C. Part 60. Subpart GG. 40 CFR 60, 2019. Washington: GPO. 19 September 2024. Web. 23 September 2024. <https://www.ecfr.gov/current/title-40/chapter-I/subchapter-C/part-60/subpart-GG >. 3.3 Stack Sampling Location The inner exhaust stack diameter for the Solar Taurus 60-7800S (Permit ID T-3, Unit ID: #3) was previously measured as 36 inches. The sampling ports for flow, NOx and CO measurements is approximately 5.0 pipe diameters downstream from the nearest flow disturbance and 1.0 pipe diameters upstream from the nearest disturbance. The test location will be verified during the test program to meet the minimum specifications of a sampling location as defined by EPA Method 1. An aerial lift will be utilized, if needed, to conduct sampling. 9 Figure 1: Sample Location Diagram. 3.4 Emission Measurement Methodologies Testing will be performed and calculated in accordance with EPA Test Methods 1, 3A, 7E and 20 for NOx for the nine 21-minute test runs at evenly spaced load conditions according to the requirements of NSPS Subpart GG. Oxygen will be measured to allow for emission levels to be corrected to 15% O2. In order to comply with the DAQE-AN121030019-20 requirements, testing at full load conditions will be conducted for three, one hour test runs for NOx and CO. Testing will be performed in accordance with EPA’s Methods 1, 3A, 7E, 10, 19 and 20. The step-by- step example calculations are provided in Appendix A. Testing will be conducted for three runs at four evenly spaced loads as required by NSPS Subpart GG. The proposed procedural guideline is provided below: 1) Linearity checks of O2, CO and NOx analyzers according to EPA Test Methods 3A, 7E and 10. 2)(NSPS Subpart GG Requirement) O2 stratification check will be conducted to determine the point at which the effluent gas is to be sampled on all tests. 3) Measurement of relative humidity (wet/dry bulb), barometric pressure and ambient temperature at the test site. 4)(UDEQ Compliance Requirement) Three, one hour tests at full load conditions according to EPA Test Methods 1, 3A, 7E, 10, 19 and 20. Oxygen will be measured to allow for NOx emission levels to be corrected to 15% O2. Sample bias checks will be conducted before/after each 1 hour test run. (NSPS Subpart GG Requirement) Three, 21-minute test runs at three, evenly spaced load conditions for NOx on a ppmvd @ 15% O2 basis, for a total of nine test runs according to Subpart GG requirements. Three equally spaced load points will be 10 selected near the normal operating range of the turbine, with the lowest attainable load to be tested last. Additionally, the three high load 21-minute test runs for NOx will be taken from the three, one hour UDEQ compliance test runs to meet the Subpart GG requirements. A total of twelve test runs will be conducted to meet NSPS Subpart GG requirements. The schematic for our sampling system is shown on the following page. 11 Figure 2: EPA Methods 3A, 7E and 10 Sampling Train Schematic. 12 3.4.1 Method 19 Fd Factor Exhaust effluent flow during testing is determined using EPA’s Method 19. Method 19 establishes appropriate F factors. An F factor is the ratio of the combustion gas volume to the heat content of the fuel. The dry F factor (Fd) includes all components of combustion less water. The emissions in terms of lb/hr will be calculated using EPA’s Method 19 and the fuel consumption recorded during testing. The fuel consumption and the site fuel analysis will be provided in the test report. 3.5 Equipment Utilization Oasis Emission Consultants Inc. will utilize the following gas analyzers and associated equipment for this testing:  API 300M CO NDIR Analyzer  API 200AH NOx/O2 Chemiluminescent/Paramagnetic Analyzer  75 ft. Heated Sample Line  Fyrite Analyzer for Carbon Dioxide Measurement  Universal Analyzer 3040SSP Sample Gas Conditioner  EPA G1 Protocol Calibration Gas  Laptop Computer To Download Raw Analyzer Data 3.6 Test Quality Assurance Procedures 3.6.1 Sampling Protocol Precautions are taken to keep the gas analyzer in a clean, thermally stable, vibration free environment to minimize analyzer drift and associated errors. Pre test calibrations and post test operations are performed within the testing trailer environment. Samples are taken according to EPA Methods 1, 3A, 7E, 10, 19, 20 and applicable Subpart GG procedures. The data from the samples are converted directly into computer language and recorded in the Compliance Specialist’s laptop computer. This eliminates the need for sample labeling and secures the preservation of the data while reducing human error. In addition, parameters associated with the turbine are recorded on test sheets at the time of the test. Linearity checks are perform using certified calibration gases to ensure that the zero, mid, and upscale calibrations are within the certified calibration level and zero. Pre-test calibrations are then conducted on the zero and selected mid or upscale calibration gas determined by observing the native concentration of the target analytes in the sampled. exhaust. After each test run the same zero and selected mid or upscale calibration gas are analyzed to verify they are within the required specifications. 13 3.6.2 Equipment Calibration and Measurement Preventive diagnostic functions are built directly into the equipment utilized for the testing. This diagnostic function provides the Compliance Specialist with failure warnings allowing the determination of when repairs are necessary without performing painstaking preventative maintenance procedures. However, equipment is inspected regularly by the Compliance Specialists to guarantee maximum operational status. The process involved with equipment calibration ensures that there is no divergence from the manufacturer’s specifications. 3.7 Turbine Load Approximation Oasis Emission Consultants Inc. will approximate the turbine load using process parameters measured, such as gas throughput, suction/discharge pressure/temperature, manufacturer’s BSFC, panel reading or fuel measurement (if available). In accordance with 40 CFR 60.335(b)(2), NOx testing will be conducted at four evenly spaced load points in the normal operating range of the turbine, including the minimum point and the 90-to-100 percent peak load. If 90-to-100 percent peak load is not achievable in practice, testing will be conducted at the highest achievable load point. 3.8 Test Methods Oasis Emission Consultants, Inc. will employ EPA 40 CFR 60 (A) methods as required by UDEQ AO # DAQE-AN121030019-20 and in accordance with 40 CFR 60.335 (Subpart GG). These methods are described below.  EPA 40 CFR 60 Appendix A, Method 1: Method 1 requires measurement of the various physical attributes of a stack to establish appropriate sampling locations.  EPA 40 CFR 60 Appendix A, Method 3A: O2 measurements will be conducted using an instrumental analyzer according to Method 3A. The O2 levels will be used in conjunction with Method 19 to determine the overall exhaust effluent flow. The O2 levels will also be used to allow for the correction of NOx to ppmvd @ 15% O2.  EPA 40 CFR 60 Appendix A, Method 7E: Method 7E is the instrumental method for measuring the NOx concentration in the effluent stream. After passing through a sample conditioning system, NOx concentration is measured by a chemiluminescent gas analyzer. The analyzer is calibrated using EPA Protocol G1 gas before and after each one hour test run.  EPA 40 CFR 60 Appendix A, Method 10: Method 10 is the instrumental method for measuring the CO concentration in the effluent stream. After passing through a sample conditioning system, CO concentration is measured by an NDIR gas analyzer. The analyzer is calibrated using EPA Protocol G1 gas before and after each one hour test run.  EPA 40 CFR 60 Appendix A, Method 20: Method 20 is the instrumental method for measuring NOx and/or O2 concentrations from stationary gas turbines. NOx and O2 are 14 measured using Method 7E and 3A, respectively, for a duration of at least 21-minutes per test run.  EPA 40 CFR 60 Appendix A, Method 19: Method 19 utilizes a fuel metering system to measure the fuel flow consumed by the turbine. This data is correlated with the fuel gas composition and the measured exhaust gas Oxygen content, to arrive at the overall exhaust effluent flow.  EPA 40 CFR 60 Subpart GG § 60.335: Subpart GG regulates the NOx and Sulfur Dioxide (SO2) pollutants. NOx will be measured using Method 7E or Method 20. A stratification check will be performed prior to testing to determine sampling location according to 40 CFR 60.335(a)(5)(i)(B). APPENDIX A Example Calculations: The following is a step-by-step example of the calculations that will be utilized for each test run. Test Parameters  Average O2  Turbine Load EPA Method 19: Determination of Stack Gas Flow Rate Volumetric Flow Rate At Outlet (dscfm) = q * Fd * 1E-6 * HHV * 20.9 / (20.9 – O2) Where: q – Fuel flow (scf/min) Fd – Fuel factor, dry (dscf/mmBtu) HHV – Higher heating value of fuel (Btu/scf) O2 – Oxygen content in exhaust (%) 1E-6 – Conversion from Btu to mmBtu EPA Method 7E & 10: Determination of NOx and CO Emissions From Stationary Sources Corrected Flue Gas Concentration (PPM) = (CR - CO) * CMa / (CM – CO) Where: CR – Average flue gas concentration indicated by gas analyzer (ppm) CO – Average of initial and final zero system bias checks (ppm) CM – Average of initial and final span system bias checks (ppm) CMa – Actual concentration of span gas (ppm) Method 7E: NOx Emission Rate (lb/hr) = PPMO * MW * QO * 60 / (385.3 * 1000000) Where: NOx – Nitrogen Oxides PPMO – Average concentration of corrected pollutant at outlet (ppm) QO – Volumetric flow rate at outlet (dscfm) MW – Molecular Weight 60 – Conversion factor (minutes per hour) 385.3 – Volume occupied by one pound of gas at standard conditions (dscf/lb-mole) 1000000 – Conversion factor (ppm to mole fraction) NOx Correction to 15% O2 = PPMO * (20.9 – 15) / *(20.9 – O2%) Where: NOx – Nitrogen Oxides PPMO – Average Concentration Of Corrected Pollutant At Outlet O2 – Oxygen Concentration in Exhaust Stream (%) NOx Correction to ISO Standard Conditions = (NOxO)(Pr / PO)0.5 e19 * (HO – 0.00633) (288K / Ta)1.53 Where: NOxO – Nitrogen Oxides Concentration @ 15% O2 Pr – Reference Absolute Pressure at 101.3 Kilopascals Ambient Pressure PO – Observed Absolute Pressure At Test HO – Observed Humidity Of Ambient Air, gH2O/g air e – Transcendental Constant, 2.718 Ta – Ambient Temperature, K Method 10: CO Emission Rate (lb/hr) = PPMO * MW * QO * 60 / (385.3 * 1000000) Where: CO – Carbon Monoxide PPMO – Average concentration of corrected pollutant at outlet (ppm) QO – Volumetric flow rate at outlet (dscfm) MW – Molecular Weight 60 – Conversion factor (minutes per hour) 385.3 – Volume occupied by one pound of gas at standard conditions (dscf/lb-mole) 1000000 – Conversion factor (ppm to mole fraction) APPENDIX B SAMPLE SAMPLE Airgas an Air Liquide company Part Number: Cylinder Number: Laboratory: pc;vp Number: Gas Code: Airgas Specialty Gases Airgas USA LLC 525 North Industrial Loop Road Tooele,UT 84074 Airgas.com CERTIFICATE OF ANALYSIS Grade of Product:EPA PROTOCOL STANDARD E02N199E15A0497 CC93412 124 -Tooele (SAP)-UT B72023 CO,BALN Reference Number: Cylinder Volume: Cylinder Pressure: Valve Outlet: Certification Date: 153-402750636-1 144.0 CF 2015 PSIG 350 May 22,2023 Expiration Date:Ma 22 2031 Certificationperformed in accordance with "EPA Traceability Protocol for Assay and Certificationof Gaseous Calibration Standards (May 2012)"documentEPA 600/R-12/531,using the assay procedures listed.Analytical Methodology does not require correction for analytical interference,This cylinder has a total analytical uncertainty as stated below with a confidencelevel of 95%.There are no significantimpurities which affect the use of this calibrationmixture.All concentrations are on a mole/mole basis unless otherwise noted.The results relate only to the iterns tested. The report shall not be reproduced exceptin full without approval of the laboratory.Do Not Use This Cylinder below 100 psig, i.e.0.7 megapascals. ANALYTICAL RESULTS Component CARBON MONOXIDE RequestedConcentration 30.00 PPM Balance Cylinder No CC714889 19060528 Actual Concentration 29.94 PPM Protocol Method Gl NITROGEN Type NTRM NTRM Lot ID 20060920 190605 CALIBRATION STANDARDS Concentration 26.54 PPM CARBON MONOXIDE-INITROGEN 495.2 PPM SULFUR DIOXIDE/NITROGEN Total Relative Uncertainty +/-0.5%NIST Traceable Uncertainty 0.4% 0.5% AssayDates 05/22/2023 Expiration Date Jun 28,2027 Aug 02,2025 The SRM,NTRM,PRM,or RGM noted above is only in reference to the GMIS used in the assay and not part of the analysis. ANALYTICAL EQUIPMENT Instrument/Make/ModeI Thermo 48i-TLE 1163640031 CO Triad Data Available Upon Request Approve Analytical Principle CO NDIR (Mason) for Rele se Last Multipoint Calibration Apr 26,2023 11 Page 1 of 1 SAMPLE SAMPLE Airgas an Air Liquide company Part Number: Cylinder Number: Laboratory PGVP Number: Gas Code: Airgas Specialty Gases Airgas USA LLC 525 North Industrial Loop Road Tooele,UT 84074 Airgas.com CERTIFICATE OF ANALYSIS Grade of Product:EPA PROTOCOL STANDARD E03N180E15A0138 CC349454 124 -Tooele (SAP)-UT B72022 Reference Number: Cylinder Volume: Cylinder Pressure: Valve Outlet: Certification Date: 153-402554387-1 141.0 CF 2015 PSIG 590 sep 27,2022 Expiration Date:Se 27 2030 Certificationperformed in accordance with 'EPA Traceability Protocol for Assay and Certificationof Gaseous Calibration Standards (May 2012)"document EPA 600/R-12/531,using the assay procedures listed.Analytical Methodology does not require correction for analytical interference.This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%.There are no significantimpurities Which affect the use Of this calibration mixture.All concentrations are on amole/mole basis unless otherwise noted. Do Not Use This C linder below 100 si ,i.e.0.7 me a ascaiS. ANALYTICAL RESULTS Component CARBON DIOXIDE OXYGEN NITROGEN RequestedConcentration 10.00 % 10.00 % Balance Cylinder No CC411744 SG9161286BAL ActualConcentration 9.924 %10.09 % ProtocolMethod Gl Type NTRM NTRM Lot ID 13060405 98051010 CALIBRATION STANDARDS Concentration 7.489 %CARBON DIOXIDE-INITROGEN 12.05 %OXYGEN/NITROGEN ANALYTICAL EQUIPMENT Analytical Principle C02 NDIR (Dixon) 02 Paramagnetic (Mason) Total Relative Uncertainty +1-1.2%NIST Traceable +1-0.7%NIST Traceable Uncertainty 0.6% 0.7% AssayDates 09/27/2022 09/27/2022 Expiration Date May 14,2025 Dec 14,2023 Instrument/Make/ModeI Horiba VIA-510 SV4MEUTJ C02 Horiba MPA-510 W603MM58 02 Triad Data Available Upon Request Last Multipoint Calibration sep 14,2022 Sep 14,2022 Approved for Relea Page 1 of •i SAMPLE SAMPLE SAMPLE