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HomeMy WebLinkAboutDERR-2024-011015 SAMPLING RESULTS REPORT Reilly Tar Utah County, Utah UTD009087644 April, 2022 SAMPLING RESULTS REPORT Reilly Tar Utah County, Utah UTD009087644 Utah Department of Environmental Quality Division of Environmental Response and Remediation Prepared by: Michael Swistak Approved: Date: _________ Michael Swistak, Project Manager Approved: Date: _________ Thomas Daniels, Site Assessment Section Manager Approved: Date: _________ Martin McComb, On-Scene Coordinator EPA Region 8 Table of Contents 1.0 INTRODUCTION 1 2.0 OBJECTIVES 1 3.0 SITE DESCRIPTION 1 3.1 Site Location and Description 1 3.2 Site History 2 3.3 Previous Investigations 2 3.4 Removal Activities 3 4.0 FIELD ACTIVITIES 5 4.1 Scope 5 4.2 Sampling Strategy 5 4.3 Data collection schedule 6 4.4 Groundwater Sample Collection 7 4.5 Soil Sample Collection 7 4.6 Quality Control Samples 8 4.7 Equipment Decontamination 8 4.8 Site Restoration 8 5.0 LABORATORY ANALYTICAL METHODS 8 6.0 SUMMARY OF ANALYTICAL RESULTS 9 6.1 Soil Data Summary 10 6.2 Groundwater Data Summary 10 7.0 DATA QUALITY ASSESSMENT 11 8.0 DATA EVALUATION 12 8.1 Soil Sample Results 12 8.2 Groundwater Sample Results 13 9.0 CONCLUSIONS 13 10.0 REFERENCES 15 APPENDICES Appendix A Figures and Tables Figure 1 General Site Location Map Figure 2 Site Map Figure 3 Groundwater Potentiometric Surface Map Appendix B Data Tables Table 1 Inorganic Groundwater Results Table 2 VOC and SVOC Groundwater Results Table 3 Inorganic Groundwater RPD QA QC Table 4 Organic Groundwater RPD QA QC Appendix C START Trip Report Enclosure 1 Photolog Enclosure 2 Site Figures (Site Location, Test Pit Location, Soil Sample Exceedances) Enclosure 3 Data Tables (Headspace Air Monitoring Readings, Subsurface Soil Sample Results) Appendix D Field Activities Report and Site Photographs Appendix E Consent for Access to Property Form Appendix F Groundwater Sample Laboratory Analytical Packages Appendix G Chain-of-Custody and Shipping Documentation Appendix H DERR Historical Soil and Groundwater Data Appendix I START Trip Report Enclosure 4 Soil Sample Laboratory Analytical Packages Sampling Results Report Reilly Tar – UTD009087644 1 1.0 INTRODUCTION This Sampling Results Report was prepared by the Utah Department of Environmental Quality, Division of Environmental Response and Remediation to summarize site conditions at the Reilly Tar (Vertellus Provo) Site (Site), (CERCLIS ID #UTD009087644), located at 2555 South Industrial Parkway in Provo, Utah. The scope of this investigation included recording groundwater elevations and collecting groundwater samples for semi-volatile organic compounds (SVOCs), volatile organic compounds (VOCs), and metals. Additionally, test pits were excavated and sampled to delineate the extent of coal tar in the subsurface. The purpose of this Sampling Results Report (SRR) is to present new data, summarize pertinent results from previous studies, identify potentially hazardous conditions, identify data gaps in order to determine the appropriate next steps to protect human health and the environment at the Site. 2.0 OBJECTIVES Field sampling activities were conducted in September of 2021, and involved the collection of groundwater samples from the existing well network on Site and the collection of soil samples from test pits dug by an excavator. All samples were analyzed for volatile organic compounds (VOCs), semi-volatile organic compounds (SVOCs), and total metals. The objectives of the Sampling Work Plan were as follows: • Characterize the location and spread of contamination at the Site, specifically in the southern portion of the property. • Determine if Site contaminants are present in on and off-site groundwater. • Determine the distribution and concentration levels of contamination on Site. • Evaluate human health and environmental targets associated with the soil and groundwater exposure pathways, and determine if these targets are being exposed. 3.0 SITE DESCRIPTION 3.1 Site Location and Description The Site is a former coal tar processing facility located on the lot at 2555 South Industrial Parkway in Provo, Utah County, Utah (Appendix A, Figure 1). All buildings and structures have been removed from the Site with some foundations remaining. The Site covers approximately 31.84 acres. The northern portion of the Site is dry, and is bounded by the Ironton Canal which Sampling Results Report Reilly Tar – UTD009087644 2 eventually drains into Utah Lake to the west. The southern portion of the Site is a seasonal wetland. Industrial properties border the Site to the east, west, and south. 3.2 Site History The Site operated as a coal tar distillery from 1924 to 2002. The Site was initially developed by the Republic Creosote Company in 1924 (ERM, 2009). The Republic Creosote Company changed their name to Reilly Tar and Chemical in 1961, which became Reilly Industries in 1989. Former structures at the Site included two pole barns, a separation tank, a condenser, storage tanks, a wastewater biotreatment system, and an evaporation pond. As a result of these operations, soil, sediment, groundwater, and surface water on Site has been contaminated with volatile organic compounds (VOCs), semi-volatile organic compounds (SVOCs), and metals. Products produced at the Site include creosote oil, electrode binder pitch, and various other oil and tar products. Waste products generated at the Site include polycyclic aromatic hydrocarbons (PAH’s), phenols, benzene, cyanides, and sulfides (McComb, 2017). From 1982 to 1985 spills cleanup waste material was buried on Site in windrows. Much of this material remains in place at the Site (August Mack, 2003). The Resource Conservation and Recovery Act (RCRA) program administered by the Division of Waste Management and Radiation Control (DWMRC) has regulated the site since the early 1990’s. Reilly discontinued production operation at the Site in early 2001 and decommissioned the facility during 2002. In September of 2005, Arsenal Capital Partners acquired Reilly Industries and in July of 2006, Arsenal merged Reilly with another company to form Vertellus. Vertellus removed all existing structures from the Site during 2006. Currently only concrete foundations remain at the Site. The property owner was preparing to do a Risk Assessment at the site when the owners of the property declared bankruptcy May 2016. 3.3 Previous Investigations A Preliminary Assessment Plus completed by EPA for the Site in 1993 identified 10 solid waste management units (SWMUs) at the Site. Reilly entered into a Stipulation and Consent Agreement (Consent Agreement) with the DSHW on November 13, 1996 that required Reilly to investigate and perform corrective action, as necessary, for the 10 SWMUs identified at the Site. A phase II RFI Supplemental Work Plan was completed by August Mack Environmental on March 6, 2007. A follow up Phase II Groundwater and Surface Water Monitoring Report was completed by August Mack on April 28, 2010. A Revised Risk Assessment Work Plan was completed by URS Corporation in December, 2012. On July 18, 2011 a Risk Assessment Work Plan was submitted by URS Corporation to the Utah Division of Solid & Hazardous Waste. A follow up Risk Assessment was submitted by URS Corporation in June of 2013. A Phase I Environmental Site Assessment was completed by Enviro Assessment P.C. on March 24, 2014. Findings of these reports all indicate the presence of contamination in the soil and groundwater. Sampling Results Report Reilly Tar – UTD009087644 3 A Site Risk Assessment was prepared by URS in June of 2013. An overview of SWMU Areas at the Site can be seen in this report as Figure 1-1 (URS, 2013). This report provided a baseline evaluation of current or potential threats to human health and the environment from chemical releases at the Vertellus property (URS, 2013). They determined that the human health risk at the Site will be managed in a Site Management Plan and an Environmental Covenant without additional correction action for certain areas (URS, 2013). However, in some areas cancer risk to all receptors exceeded thresholds, and therefore, the Site Management Plan must include procedures for a Corrective Action Plan to mitigate the risks to human health in these areas. 3.4 Removal Activities In June of 2017 a Superfund Technical Assessment and Response Team (START) and Emergency and Rapid Response Services (ERRS) conducted a Removal Site Inspection with UDEQ. Sitewide contamination including PAHs and volatile organic compounds (VOC's) was observed, in some places reaching deeper than 13 feet. These contaminants were solid in the eastern portion of the Site, but aqueous and mobile in the western portion of the Site, leading to concerns that these contaminants could flow into the Ironton canal and discharge into Provo Bay. Numerous asbestos containing tiles were also found at the site (McComb, 2017). In November of 2017, EPA personnel conducted a limited time critical removal action (TCRA) at the site to address concerns related to potential impacts to the Ironton Canal from contamination in the northwest portion of the property. The TCRA consisted of the installation of a flood resistant liner to prevent contamination from entering the Ironton canal and the excavation of approximately 2,000 cubic yards of contaminated soil from the northern corner of the Site and placing the excavated soil in an in-situ land farm on the eastern perimeter of the Site. Runoff controls were established around the land farm area. Additionally, 1,780 pounds of asbestos containing tiles were removed and properly disposed of off Site. Lastly, the entire area was graded to ensure that surface water drains southward, erosion control features were installed across the Site, and the entire area was re-seeded (Giggleman, 2018). 3.4.1 Post Removal Sampling In 2017, six samples were collected from the soil that was placed in an in-situ land farm. RT-SS- 003 and RT-SS-006 were analyzed for metals (Appendix H). RT-SS-001 and RT-SS-004 were analyzed for VOA's (Appendix H). RT-SS-002 and RT-SS-005 were analyzed for Semi-VOA's and PAH's (Appendix H). Land farm samples exceeded the EPA's Industrial Soil Regional Screening Level (RSL) for arsenic, nickel, benzo(a)anthracene, benzo(a)pyrene, benzo(b)fluoranthene), benzo(g,h,i)perylene, benzo(k)fluoranthene, chrysene, dibenzo(a,h)anthracene, dibenzofuran, indeno(1,2,3-cd)pyrene, N-nitrosodiphenylamine, and naphthalene. Additionally, 66 other non-volatile compounds were detected at fairly high Sampling Results Report Reilly Tar – UTD009087644 4 concentrations (Appendix B, Table 4). Additional sampling was scheduled annually, but was not able to be completed as planned. Data gaps currently exist as to the effectiveness of the land farm. 31 monitoring wells were installed around, across, and adjacent to the site by Vertellus Specialties Inc. in 2009 (URS, 2011). Twelve of those wells were sampled in November of 2017 to assess groundwater contamination at the Site (Appendix H). Samples were analyzed for metals, VOA's, semi-VOA's, PAH's, and non-volatile contaminants. Groundwater samples exceeded the 2020 SCDM Benchmark Values for arsenic, cobalt, thallium, benzene, ethylbenzene, 2-methylnaphthalene, 2,4-Dimethylphenol, 4-Methylphenol, benzo(a)anthracene, benzo(a)pyrene, dibenzofuran, dibenzo(a,h)anthracene, indeno(1,2,3-cd)pyrene, naphthalene, phenanthrene and phenol. 96 other non-volatile compounds were also detected in the groundwater. Thirteen of the monitoring wells around and across the property were sampled in May of 2018. The same analytes were assessed for. In 2018 the following analytes were present at concentrations that exceed 2020 SCDM benchmarks: arsenic, thallium, benzene, ethylbenzene, benzo(a)anthracene, benzo(a)pyrene, benzo(k)fluoranthene, dibenzo(a,h)anthracene, indeno(1,2,3-cd)pyrene, naphthalene, 4-Methylnaphthalene, 2,4-Dimethylphenol, 4- Methylphenol and dibenzofuran (Appendix H). Additionally, nearly 200 non-volatile compounds were detected in monitoring well samples in 2018. In April of 2018 the indoor air at a guard room across the road from the Site was tested to determine if chlorinated solvents from the contaminated groundwater at the site were traveling and volatilizing into structures located on the adjacent property. A Summa canister was used to collect a 24-hour air sample from a location inside the guard station (Figure 2). No contaminants were detected in concentrations above the EPA's 2018 Regional Screening Levels for Industrial Air. Sampling Results Report Reilly Tar – UTD009087644 5 4.0 FIELD ACTIVITIES 4.1 Scope The Site sampling activities were developed in the Field Sampling Work Plan and designed according to the Site Conceptual Model (DERR, 2021a). The approved scope of work for this Field Sampling Work Plan consisted of the following: • Excavation of 15 test pits for the purpose of delineation of contamination in the southern portion of the property, and up to four soil samples to be taken from the test pits. • Collection of seven groundwater samples from the existing monitoring well network on Site. • Gauging depth to water from 10 monitoring wells on Site. Due to field conditions or other specific factors, modifications to the scope of work were made. It was proposed in the work plan that a geoprobe advance 20 soil borings; however, due to equipment availability, time constraints, and field conditions, an excavator was brought out on Site to excavate 15 test pits instead. A summary of field activities can be seen in Appendix D. 4.2 Sampling Strategy The sampling strategy for soil excavations was designed to assess the vertical and horizontal extent of impacts to soils at the Site. The test pits in the southern portion of the Site were designed to assess the extent of contamination in the vicinity of the former solid waste management units (SWMUs) and determine if contamination was deposited in other areas which had not been investigated. These samples were analyzed for volatile organic compounds (VOCs), semi volatile organic compounds (SVOCs), polycyclic aromatic hydrocarbons (PAHs), and metals. After observation and sample collection was complete, each test pit was properly backfilled and graded to surface conditions. The sampling strategy for groundwater samples was designed to determine concentrations of contamination on Site and to determine if contamination was migrating off Site to the adjacent property. Four groundwater monitoring wells and three piezometers were gauged and sampled for VOCs, SVOCs, PAHS, and metals. Groundwater and soil samples were delivered to an analytical laboratory within holding times for all analytical methods to generate analytical data. The table below provides a summary description of the sample locations, sample types, sampling naming convention, laboratory analysis, and sampling rationale: Sampling Results Report Reilly Tar – UTD009087644 6 SUMMARY OF SOIL AND GROUNDWATER SAMPLES Sample Location Rationale Sample IDs Sample Matrix Analytes MW-19 Delineate groundwater contamination. H0AA0 Groundwater VOCs, SVOCs, PAHs, Metals MW-22 Delineate groundwater contamination. H0AA1 Groundwater VOCs, SVOCs, PAHs, Metals MW-33 Delineate groundwater contamination. H0AA2 Groundwater VOCs, SVOCs, Metals MW-18 Delineate groundwater contamination. H0AA3 Groundwater VOCs, SVOCs, Metals PZ-4 Delineate groundwater contamination. H0AA4 Groundwater VOCs, SVOCs, Metals PZ-5 Delineate groundwater contamination. H0AA5 Groundwater VOCs, SVOCs, Metals PZ-6 Delineate groundwater contamination. H0AA6 Groundwater VOCs, SVOCs, Metals TP01 Determine impacts to soil. RCT-SS-TP01 Soil VOCs, SVOCs, Metals TP04 Determine impacts to soil. RCT-SS-TP13 Soil VOCs, SVOCs, Metals TP14 Determine impacts to soil. RCT-SS-TP14 Soil VOCs, SVOCs, Metals 4.3 Data collection schedule The sampling for the Site was conducted during two separate sampling events (September 8, and September 29-30, 2021). EPA Superfund Technical Assessment & Response Team (START) contractors were on-Site to provide excavator services to dig test pits around the Site to delineate the extent of soil contamination, as well as collecting soil samples from a few of the test pits (September 8, 2021). DERR conducted a separate groundwater sampling event of the existing well network at the Site (September 29-30, 2022). Site sampling Sampling Results Report Reilly Tar – UTD009087644 7 activities were conducted in accordance with the DERR Quality Assurance Project Plan (QAPP) (DERR, 2020b). 4.3.1 Deviations from the work plan The work plan stated 21 soil borings were to be advanced in the southern portion of the Site; however, due to time constraints and availability of contractors, an excavator was brought to the Site to dig test pits instead. Three soil samples were analyzed for the analyses requested in the Sampling Work Plan. 4.4 Groundwater Sample Collection Four monitoring wells and three piezometers were sampled on September 29 and 30, 2021 using low-flow sampling methods. The wells were evacuated with a low-flow peristaltic pump. New high-density polyethylene (HDPE) tubing was used for each well, the inlet of which was placed within the top foot of the water column. Water quality parameters (pH, temperature, conductivity, and turbidity) were measured with a Horiba U-51 Multiparameter Meter, calibrated prior to use according to manufacturer’s specifications. Using depth to water and total depth of well measurements, the casing volume of water for each well was calculated. The wells were purged until one of the following criteria were met: • Groundwater quality parameters of pH, temperature, conductivity, and turbidity readings stabilized to within 10% over three consecutive readings. Readings were taken every five minutes; • Three casing volumes were removed; or • The well no longer produced water. In two of the three piezometers, groundwater did not recharge quickly enough, so members of UDEQ DERR measured water levels of other wells around the Site while waiting for the piezometers to recharge. After letting the piezometers recharge, groundwater samples were taken immediately. An access agreement was signed and returned to DERR prior to sampling wells located on the McWane Ductile property, which is located to the west of the Site (Appendix E). 4.5 Soil Sample Collection Environmental Restoration LLC (ER) and Tetra Tech, EPA’s START contractor, conducted soil sampling activities on Site with the DERR providing oversight (Tetra Tech, 2022). As directed by the U.S. EPA, ER excavated 15 test pits to the maximum depth the excavator could reach, between 10-20 feet below ground surface (bgs). Test pit locations were determined in the field Sampling Results Report Reilly Tar – UTD009087644 8 based on Site conditions and ability to safely maneuver and operate the excavator. Test pit locations can be seen in Figure 2 and 3 of Appendix C. During excavation activities, START photo-documented excavated soil conditions and used a MultiRAE Pro to screen VOC concentrations in soil throughout investigation activities (Appendix C). START identified the presence of coal tar in Test Pit (TP) 01, 14, and 15. The remaining test pits did not reveal the presence of coal tar throughout the soil profile. START collected grab subsurface samples from three test pits: two test pits that had observed coal tar (TP01 and TP14) and one test pit without the presence of coal tar as a background (TP13). 4.6 Quality Control Samples A field duplicate sample was collected for soil and groundwater as stated in the Sampling Work Plan. For this investigation, the soil field duplicate was analyzed for VOCs, SVOCs, TPH, and Metals. The groundwater field duplicate was analyzed for VOCs, SVOCs, and Metals. The duplicate samples were as follows: • H0AA7 is a field duplicate for H0AA3 for VOCs, SVOCs, and Metals. o These samples were both taken from MW-18. • RCT-SS-TP01-DUP is a field duplicate for RCT-SS-TP01 for VOCs, SVOCs, TPH, and Metals. A laboratory-prepared trip blank accompanied the soil samples during sample collection activities and sample storage. The trip blank was sent to the laboratory with the rest of the soil samples and analyzed for VOCs. 4.7 Equipment Decontamination Clean disposable, single-use sampling equipment was used to conduct the soil and groundwater sampling, and was properly disposed of after each use therefore decontamination of equipment was not necessary. 4.8 Site Restoration After sample collection was completed, each test pit was properly backfilled with native soil and the surface was regraded to match the surrounding area. 5.0 LABORATORY ANALYTICAL METHODS All soil and groundwater samples (including field duplicates and trip blanks) were placed in iced coolers. The groundwater samples that were being analyzed for metals were shipped in iced Sampling Results Report Reilly Tar – UTD009087644 9 coolers under chain-of-custody protocols via overnight courier to Pace Analytical Services, LLC in West Columbia, South Carolina (a CLP Certified Laboratory). Groundwater samples being analyzed for VOCs and SVOCs were shipped to CHEMTEX in Port Arthur, Texas (a CLP Certified Laboratory). Soil samples (including field duplicates and trip blanks) were placed in iced coolers and shipped under chain-of-custody protocols via overnight courier to ALS Environmental in Fort Collins, Colorado (a CLP Certified Laboratory). Samples were analyzed using the following methods: Sample Type Number of Samples Analysis / Method Test pit soil 3 plus 1 duplicate VOCs / SW-846 8260C SVOCs / SW-846 8270E 1TPH-GRO / SW-846 8015D 2TPH-DRO / SW-846 8015M_mod 3TPH-ORO / SW-846 8015C Metals / SW-846 6020B Groundwater 7 plus 1 duplicate VOCs / SW-846 8260C SVOCs / SW-846 8270D Metals / SW-846 6010D 1GRO = Gasoline Range Organics 2DRO = Diesel Range Organics 3ORO = Oil Range Organics 6.0 SUMMARY OF ANALYTICAL RESULTS A summary of the groundwater analytical results with those constituents detected above the laboratory limits are provided in Tables 1 and 2 of Appendix B. Analytical results for soil and groundwater samples can be found in Appendix H. For soil, copies of reports and sample chain- of-custody records can be found in Appendix C. For groundwater, copies of reports are found in appendix F and sample chain-of-custody records are provided in Appendix G. Constituent concentrations in soils were compared to current EPA Removal Management Levels (RMLs) for industrial soil with target excess cancer risk level of 10-4 and a target hazard quotient of 1.0 for non-carcinogens (Tetra Tech, 2022). Analytical results for soil were also compared to current EPA RSLs for industrial soil with a target excess cancer risk level of 10-6 and a target hazard quotient of 1.0 (Tetra Tech, 2022). Constituent concentrations in groundwater were compared to current EPA Maximum Contaminant Levels (MCL) and the EPA Tap Water RSLs. Constituents of concern that did not have a listed MCL were compared to Tap Water RSLs. However, this shallow groundwater is Sampling Results Report Reilly Tar – UTD009087644 10 highly unlikely to be used for drinking water. There are no drinking water municipal wells located within four downgradient miles of the Site. 6.1 Soil Data Summary Analytical results for soil samples are summarized in Enclosure 3 of Appendix C. • Metals: Arsenic was reported in soil samples RCT-SS-TP01 and RCT-SS-TP13 at concentrations that exceed the EPA’s industrial RSL. The arsenic concentrations identified in soil ranged from 6.8 to 7.0 mg/kg. Arsenic was the only contaminant of concern that exceed EPA screening levels for metals. • VOCs and TPH: TPH-DRO was detected in two samples at concentrations exceeding EPA’s industrial RSL and RML [RSL = 440 mg/kg; RML = 440 mg/kg]. TPH-DRO concentrations in soil samples ranged from 7,100 to 77,000 mg/kg. TPH-ORO and TPH- GRO were detected at concentrations above EPA’s industrial RSL and RML [ORO RSL: 40,000mg/kg, RML: 40,000mg/kg; GRO RSL: 420mg/kg, RML: 420mg/kg] in sample RCT-SS-TP14. Naphthalene was detected at concentrations ranging from 1,500 to 46,000 mg/kg in three of the soil samples, which is above EPA’s industrial RML of 590 mg/kg. Benzene and Ethylbenzene were also detected in soil samples above the industrial RSL. • SVOCs: 2-Methylnaphthalene, Benzo(a)pyrene, and Dibenzofuran were detected in RCT-SS-TP14 at concentrations above EPA’s industrial RMLs. 1-Methylnaphthalene, Benzo(a)anthracene, Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene, Dibenz(a,h)anthracene, and Indeno(1,2,3-cd)pyrene were detected in soil samples above EPA’s industrial RSL. Periodic headspace air monitoring readings for VOCs were also taken from test pits during the sampling event (Appendix C, Table 1). Four of the readings were above the short-term exposure limit (STEL) of 5.0 ppm and the permissible exposure limit (PEL) of 12 ppm. Headspace air monitoring sample locations with exceedances are identified in Appendix C, Figure 2. 6.2 Groundwater Data Summary Analytical results for groundwater samples are summarized in Appendix B. • Metals: Arsenic, Thallium, Lead, Cadmium, Cobalt, Iron, and Manganese were all detected above reported detection limits. Arsenic and Thallium were detected in numerous samples at levels above EPA’s MCL and Tap water RSL. Arsenic was detected above EPA’s MCL of 10 ug/L in four groundwater samples at concentrations ranging from 15 to 100 ug/L. Thallium was detected above EPA’s MCL of 2 ug/L in five groundwater samples at concentrations ranging from 6.6 to 15 ug/L. Sampling Results Report Reilly Tar – UTD009087644 11 • VOCs: Benzene and 1,2-Dichloropropane were the only two VOCs detected above EPA’s MCL’s (5 and 5 ug/L, respectively). Benzene was detected in MW-33 at 29 ug/L and 1,2-Dichloropropane was detected in MW-19 at 5.6 ug/L. Naphthalene and phenol were detected above EPA’s Tap Water RSL. Naphthalene was detected in four samples and phenol was detected in one sample above the RSL. • SVOCs: 1,1’-Biphenyl, 1-Methylnaphthalene, 2,4-Dimethylphenol, 2,4-Dinitrotoluene, and Dibenzofuran were all detected in MW-18 and MW-33 above EPA’s Tap Water RSL. 2-Methylnaphthalene was detected above the Tap Water RSL in MW-33. 7.0 DATA QUALITY ASSESSMENT Quality control for the sampling program included using standardized sample collection and handling methods, documenting pertinent field information, and keeping chain-of-custody records. The sampling work consisted of two phases of sampling: soil sampling and groundwater sampling. Soil sampling included the collection of three samples plus one duplicate. Soil samples went through a data validation process. Groundwater sampling included the collection of seven groundwater sampling plus one duplicate. Groundwater samples did not go through a data validation process as instructed by the EPA. Documentation provided with the laboratory analytical results reports included case narratives; analytical data with minimum detection limits (MDLs) and reported detection limits (RDLs) listed for all analyses; surrogate recoveries for GC/MS analyses with laboratory control limits; chain-of-custody records; and quality control summary, including method blanks, matrix spike/matrix spike duplicates (MS/MSD) with control limits, laboratory control samples and duplicates (LCS/LCSD) with control limits; and application of data qualifiers where warranted. A summary of the quality control assessment for analytical precision is presented below: • Soil samples were collected and received by ALS Environmental on 9/10/21. These samples were analyzed following the current revision of SOP 424 generally based on SW-846 Methods 8000C and 8015D. All initial and continuation calibration criteria were met. All method blank criteria were met. All laboratory control sample and laboratory control sample duplicate recoveries and relative percent differences (RPD) were within acceptable criteria. All matrix spike and matrix spike duplicate recoveries and RPDs were within acceptance criteria (Appendix G, Enclosure 4). • Groundwater samples analyzed for metals were sent to Pace Analytical, LLC. These groundwater samples were analyzed within holding times and of the 22 analytes that were analyzed for, sodium was outside the standard RPD of 25% (Appendix B, Table 3). Sampling Results Report Reilly Tar – UTD009087644 12 • Groundwater samples analyzed for VOCs and SVOCs were shipped to CHEMTEX. Groundwater samples analyzed for SVOCs were analyzed for within holding times; however, samples being analyzed for VOCs were analyzed outside of holding times by about four to five hours by the lab. The samples that were analyzed outside of holding times were given a R qualifier for rejected; however, if the sample contained detections of an analyte, it was reported with a J qualifier for estimated. • 43 analytes had a calculable RPD value, and of these 43 analytes there were 12 that were outside the standard RPD of 25% (Appendix B, Table 4). 8.0 DATA EVALUATION The following is an overview of the identified contaminants in soil and groundwater sampling during the course of this sampling event. 8.1 Soil Sample Results Observations made during the excavation of 15 test pits showed the presence of coal tar in only the northwest region of the investigated area, where a former solid waste management unit (SWMU) existed (Appendix C, Enclosure 2). Three of the 15 test pits had observable coal tar: TP01, TP14, and TP15. The three test pits with observed coal tar all lie within SWMU Area 4 (Figure 2) (ERM, 2010). The other 12 test pits were dug throughout the southern portion of the property where no SWMUs previously existed and none of these test pits showed the presence of coal tar. Headspace readings were taken to screen for VOCs in each test pit except TP15. Exceedances of the STEL and PEL occurred in TP01, TP04, and TP14. TP01 and TP14 had observable coal tar, but TP04 did not. VOCs in TP04 were detected in soil 10 feet bgs, but not from soil screened at 3 feet bgs. Groundwater at the Site was encountered at 4 feet bgs. TP04 is within close proximity and down the hydraulic gradient from the SWMU where TP01 and TP14 were dug; it is possible groundwater has transported contaminants through the soil to TP04. In samples from TP01 and TP14 there were exceedances of the EPA RMLs for TPH-DRO, TPH- ORO, TPH-GRO, 2-methylnaphthalene, benzo(a)pyrene, dibenzofuran, and naphthalene. Additionally there were exceedances of the EPA RSLs for 1-Methylnaphthalene, benz(a)anthracene, benzo(b)fluoranthene, benzo(k)fruoranthene, dibenz(a,h)anthracene, indeno(1,2,3-cd)pyrene, benzene, ethylbenzene, and arsenic. All exceedances of EPA RMLs and RSLs corresponded to samples taken from test pits with observable coal tar, except arsenic. Arsenic was detected above the RSL in TP13, which did not have coal tar. Arsenic values may have been high in TP13 due to contamination migrating via the groundwater pathway into areas without coal tar presence. Sampling Results Report Reilly Tar – UTD009087644 13 8.2 Groundwater Sample Results Groundwater elevation and survey data was used to calculate the direction of groundwater flow. Depth to groundwater at the Site ranged from three to ten feet bgs. The data indicates that groundwater at the Site is generally flowing to the seasonal wetland at the south end of the Site with a hydraulic gradient of 0.0063 feet/feet (Appendix A, Figure 3). Arsenic and Thallium were detected above the MCL in MW-22, MW-33, PZ-4 and PZ-5. Thallium was also detected above the MCL in MW-18. MW-18 and MW-33 are along the perimeter of the Site in SWMU Area 4, while MW-22, PZ-4 and PZ-5 are down the hydraulic gradient and have no known former SWMUs near them. This suggests metal contamination associated with SWMU Area 4 may be transported through groundwater down the hydraulic gradient. Naphthalene was detected in MW-18, MW-33, PZ-4, and PZ-5 above the EPA Tap Water RSL; this also suggests contamination is moving via the groundwater pathway. It is also possible arsenic and thallium levels in groundwater may be impacted by industrial operations at McWane Ductile. As mentioned in Section 7.0, groundwater samples that were analyzed for VOCs were analyzed outside of laboratory holding times. These samples were given an R qualifier; however, analytes, such as Benzene, that had detections were given a J qualifier. Benzene and 1,2-Dichloropropane were the only two VOCs above MCLs. 1,2-Dichloropropane was found in MW-19, located next to the Ironton Canal. Benzene was only found in MW-33, where SWMU Area 4 is. In URS’s 2011 groundwater sampling investigation, they reported benzene as non-detect in MW-18 and MW-33 as an estimated detection of 42 ug/L (URS, 2012). In this investigation, MW-18 was also non-detect and MW-33 had a detection of 29 ug/L J. While this groundwater data was analyzed outside of laboratory holding times, the data is consistent with the URS’s groundwater sampling event in 2011 (URS, 2012). Analytical data associated with VOCs is presented in this report for informational purposes only, and does not represent quantitative data for current groundwater levels. 9.0 CONCLUSIONS This Sampling Results Report indicates that impacts to soil and groundwater are associated with known SWMUs found on Site. 15 test pits were dug throughout the southern portion of the property. Test pits with observable coal tar were only found in the former SWMU Area 4. Soil samples were taken from two test pits with observable coal tar. These soil samples exceeded screening levels for numerous contaminants of concern, including TPH, SVOCs, VOCs, and Metals. Test pits dug during this investigation indicate that soil contamination is limited to the northwestern portion of the investigated area. Sampling Results Report Reilly Tar – UTD009087644 14 Groundwater impacts appear to be most significant near the SWMU in MW-18 and MW-33, however there still are multiple detections of contaminants of concern in MW-22, PZ-4, and PZ- 5. MW-19 and PZ-6 had little to no detections above screening levels. It is likely that contamination from SWMUs is migrating via the groundwater pathway on Site. Both human health and environmental exposure pathways for soil and groundwater are impacted by contaminants at the Site. The indoor air (soil vapor intrusion) and surface water exposure pathways do not appear to be impacted by Site contamination at this time. The 2013 Risk Assessment prepared by URS recommended a Site Management Plan, Environmental Covenant, and Corrective Action Plan to mitigate risk from Site contaminants. None of these recommendations have been put in place. A few quality control/quality assurance issues were identified in this investigation. All effort was taken to ensure the proper collection of groundwater samples; however, due to uncontrollable circumstances, many groundwater VOC samples were analyzed outside of holding times by the lab and flagged as rejected. Analytes that were detected were flagged as estimated and these values were consistent with groundwater data collected at the Site in 2011. RPDs for soil were all within acceptable criteria, but groundwater samples exceeded acceptable criteria for numerous samples. Most notably this investigation shows that coal tar is unlikely to be present in the southern portion of the Site. While there was observable coal tar in three of the test pits, these all existed in the former SWMU Area 4 and most likely do not extend outside of that boundary. Sampling Results Report Reilly Tar – UTD009087644 15 10.0 REFERENCES DERR, 2021a; Utah Department of Environmental Quality, Division of Environmental Response and Remediation; Field Sampling Work Plan for Reilly Tar, UTD0090087644 DERR, 2020b; Utah Department of Environmental Quality, Division of Environmental Response and Remediation; Quality Assurance Program Plan for Environmental Data Operations for the CERCLA Branch, Final Plan – Revision No. 8; September 2011, Revised January 2020. Tetra Tech Inc., 2022, Trip Report – Revision 0, Reilly Coal Tar Removal Assessment, Provo, Utah ERM, 2010, Phase II Supplemental Investigation – Groundwater and Surface Water Monitoring Report URS, 2012, Progress Report (4th Quarter 2011) Reilly Industries, Inc., Provo, Utah UTD0090087644 URS, 2013, Risk Assessment – Former Reilly Industries, Provo, Utah UTD0090087644 Sampling Results Report 3220 South Solvents – UTD009087655 20 APPENDIX A FIGURES Figure 1Site Location MapReilly Tar2555 South Industrail ParkwayProvo, UT Prepared By: Michael Swistak Date: Reference Scale:Map Scale: 3/31/2021 $) UTD009087644 1:48,000 1 inch = 4,000 feet01,750 3,500 5,250 7,000875Feet Subject Property Property Boundary @A@A @A@A @A @A @A @A @A@A @A@A @A @A @A @A ED @A EDED ED @A @A @A @A @A @A @A @A ED @A @A@A@A @A ED EDED@A @A @A @A Ironton Canal Mountain Springs Pkwy E 1800 S St SWMU #1 SWMU #2 SWMU #3 SWMU #4 SWMU #5 SWMU #6 SWMU #7 SWMU #8 SWMU #9 SWMU #11 SWMU #12 SWMU #14 SWMU AREA 4 (SW MU 's # 11 & 12) SWMU AREA 2 (SWMU's # 2, 3, & 10) SWMU AREA 1 (Ironton Canal SW MU #1) SWMU AREA #3 (SWMU's # 4,5,6,7,8,9,14) SWMU #10 MW-10 MW-14 MW-12 MW-13 MW-32 MW-9 MW-30 MW-29 MW-2 MW-31 MW-3 MW-5 MW-28 MW-27 MW-26 MW-16 PZ-7 MW-36 PZ-6PZ-5 PZ-4 MW-17 MW-11 MW-21 MW-18 MW-33 MW-22 MW-20 MW-19 PZ-9 MW-39 MW-34 TW-3 TW-2 MW-8 PZ-3 PZ-2 PZ-1 TW-1 MW-1 MW-6 MW-15 Figure 3Sept. 2021 Potentiometric Surface MapReilly Tar2555 South Industrial ParkwayProvo, UT Prepared By: Michael Swistak Date: Reference Scale:Map Scale: 6/15/2022 $UTD009087644 1:3600 1 inch = 300 feet012525037550062.5 Feet Legend @A Monitoring W ell ED Piezometer SWMU Boundary SWMU Area Boundary water Railroad Property Boundary @A@A @A@A @A @A @A @A @A@A @A@A @A @A @A @A ED @A EDED ED @A @A @A @A @A @A @A @A ED @A @A @A @A @A ED EDED @A @A @A @A E E E E Iron ton Canal Mountain Springs Pkwy E 1800 S St MW-10MW-14 MW-12MW-13 MW-32 MW-9 MW-30 MW-29 MW-2 MW-31 MW-3 MW-5 MW-28 MW-27 MW-26 MW-16 PZ-7 MW-36 PZ-6PZ-5 PZ-4 MW-17 MW-11 MW-21 MW-18 MW-33 MW-22 MW-20 MW-19 PZ-9 MW-39 MW-34 TW-3 TW-2 MW-8 PZ-3 PZ-2 PZ-1 TW-1 MW-1 MW-6 MW-15 4494.94 4491.35 4492.38 4491.70 4488.30 4489.58 4490.06 4490.10 4489.70 4489.10 4 4 9 2 4491 4 4 9 0 4 4 8 9 4 4 9 4 4 4 9 3 Figure 3Sept. 2021 Potentiometric Surface MapReilly Tar2555 South Industrial ParkwayProvo, UT Prepared By: Michael Swistak Date: Reference Scale:Map Scale: 1/5/2022 $UTD009087644 1:3000 1 inch = 250 feet010020030040050Feet Legend E Groundwa ter Flow Direction Groundwa ter Elevation (feet) Groundwa ter C ontour (feet) @A Monitoring W ell ED Piezometer Railroad Prop erty Boundary4494 Sampling Results Report 3220 South Solvents – UTD009087655 21 APPENDIX B TABLES T Q D Q T Q D Q T Q D Q T Q D Q T Q D Q T Q D Q T Q D Q T Q D Q MCL (ug/L)Tapwater RSL (ug/L)Aluminum --20000 n 200 U 200 U 200 U 200 U 200 U 200 U 48 J 200 U 71 J 200 U 2700 200 U 11000 NA 460 NAAntimony67.8 n 60 U 60 U 60 U 60 U 60 U 60 U 60 U 60 U 60 U 60 U 60 U 60 U 60 U NA 60 U NAArsenic100.052 c 10 U 10 U 10 U 10 U 10 U 10 U 72 J+42 J+100 J+100 J+15 J+10 U 16 J+NA 10 U NABarium20003800 n 28 J 29 J 29 J 29 J 23 J 24 J 200 U 22 J 200 U 200 U 38 J 200 U 78 J NA 200 U NABeryllium----5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 0.79 J NA 5.0 U NACadmium59.2 n 5.0 U 5.0 U 5.0 U 0.82 J 5.0 U 5.0 U 1.8 J 1.4 J 2.2 J 2.1 J 1.6 J 5.0 U 5.9 NA 1.5 J NACalcium----410000 400000 380000 360000 130000 140000 590000 570000 480000 530000 270000 240000 530000 NA 450000 NAChromium100--10 U 10 U 10 U 10 U 10 U 10 U 10 U 10 U 10 U 10 U 6.1 J 10 U 20 NA 10 U NACobalt--6 n 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 8.1 J NA 50 U NACopper1300230 n 10 J 11 J 9.6 J 12 J 4.4 J 4.3 J 14 J 16 J 14 J 15 J 15 J 7.5 J 35 NA 14 J NAIron--14000 n 100 U 100 U 100 U 100 U 100 U 100 U 13000 J+12000 J+9100 J+8900 J+12000 J+4700 J+20000 J+NA 12000 J+NALead15156.2 J 7.4 J 5.9 J 5.7 J 10 U 10 U 10 11 11 9.1 J 10 10 U 20 NA 8.0 J NAMagnesium----100000 110000 110000 110000 53000 57000 360000 350000 45000 49000 1500000 1600000 3400000 NA 3100000 NAManganese--430 n 290 280 290 280 9.4 J 11 J 210 270 150 160 200 150 490 NA 150 NANickel----40 U 40 U 40 U 40 U 40 U 40 U 7.1 J 8.5 J 6.3 J 40 U 12 J 9.0 J 40 NA 14 J NAPotassium----41000 43000 42000 42000 9800 11000 38000 45000 32000 35000 170000 170000 270000 NA 270000 NASelenium5010035U35U35U35U35U35U35U35U35U35U35U35U35UNA35UNASilver--94 n 10 U 10 U 10 U 10 U 10 U 10 U 10 U 10 U 10 U 10 U 10 U 10 U 10 U NA 10 U NASodium----590000 630000 J+61000 560000 J+68000 J+73000 J+630000 600000 J+780000 J+930000 J+3700000 3800000 J+8500000 NA 3900000 NAThallium20.2 25 U 9.3 J 6.8 J 8.3 J 25 U 25 U 11 J 12 J 6.4 J 25 U 6.6 J 25 U 15 J NA 25 U NAVanadium--86 n 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 27 J NA 50 U NAZinc--6000 n 60 U 60 U 60 U 60 U 60 U 60 U 60 U 60 U 30 J 60 U 83 31 J 78 NA 16 J NA Notes: Bolded and Red Detection above 2022 EPA MCL Benchmark Shaded orange Detection above 2022 EPA Tapwater RSL Benchmark Shaded orange and bolded red Detection above 2022 EPA Tapwater RSL and MCL Benchmarks MCL Maximum Contaminant Level J Concentration is estimated U Analyte was not detected UJ Analyte was not detected due to deficiencies in one or more quality control criteria NJ Analyte has been "tentatively identified" and the value is the approximate concentration in the sample R Rejected (Sample was analyzed outside of laboratory holding time) J-Concentration is estimated, biased low J+Concentration is estimated, biased high NA Not analyzed for T Total Metals D Dissolved Metals --No MCL or RSL value n Noncancer Tapwater RSL c Cancer Tapwater RSL MW-18_DUP H0AA7 Table 1: Groundwater Inorganics Results for Reilly Tar Sept. 2021 MW-PZ-4 H0AA4 PZ-5 H0AA5 PZ-6 H0AA6 MW-19 H0AA0 MW-22 H0AA1 MW-33 H0AA2H0AA3Monitoring Well ID: Sample Number: Total/Dissolved Analyte MW-18 H0AA3 Q H0AA7 Q H0AA0 Q H0AA1 Q H0AA2 Q H0AA4 Q H0AA5 Q H0AA6 Q MCL (ug/L)Tapwater RSL (ug/L) 1(2H)-Isoquinolinone ----270 NJ 360 NJ NA NA 120 NJ NA NA NA 1,1'-Biphenyl --0.83 n 7.4 4.1 J 5.0 U 5.0 U 32 NA NA 5.0 U 1,2,4-Trimethylbenzene --56 n 5.0 R 5.0 R 5.0 R 5.0 R 7.2 J 0.50 U 0.50 U 0.50 U 1,2-Dichloropropane 5 0.85 5.0 R 5.0 R 5.6 J 5.0 R 5.0 R 0.50 U 0.50 U 0.50 U 1,4-Dichlorobenzene 75 0.48 c 5.0 R 5.0 R NA 5.0 R 5.0 R 0.50 U 0.50 U NA 1,4-Benzenedicarboxylic acid ----NA NA 7.7 NJ NA NA NA NA 4.3 NJ 1,4-Dihydronaphthalene ----NA NA NA NA 16 NJ NA NA NA 1H-Indene, 2,3-dihydro-5-me...--NA NA NA NA 12 NJ NA NA NA 1-Methylnaphthalene --1.1 c 35 17 5.0 U 5.0 U 160 J 0.080 J 0.18 0.10 U 1-Naphthalenecarbonitrile ----18 NJ 28 NJ NA NA NA NA NA NA 1-Naphthalenol ----58 NJ 56 NJ NA NA NA NA NA NA 1-Naphthalenol, 2-methyl-----36 NJ NA NA NA 11 NJ NA NA NA 2(1H)-Quinolinone, 4,8-dime...----12 NJ 46 NJ NA NA 290 NJ NA NA NA 2,4-Dimethylphenol --360 n 230 180 5.0 U 5.0 U 770 NA NA 5.0 U 2,4-Dinitrotoluene --0.24 c 14 16 5.0 U 5.0 U 5.0 U NA NA 5.0 U 2-Benzothiophene #----16 NJ NA NA NA 410 NJ NA NA NA 2-Dibenzofuranol (01)----26 NJ 36 NJ NA NA NA NA NA NA 2-Hydroxyfluorene ----11 NJ NA NA NA NA NA NA NA 2-Methylindene ----NA NA NA NA 24 NJ NA NA NA 2-Methylnaphthalene --36 n 2.9 J 79 5.0 U 5.0 U 370 0.060 J 0.10 0.10 U 2-Methylphenol ----12 14 10 U 10 U 1400 NA NA 10 U 2-Naphthalenol, 1-amino---31 NJ 24 J+5.0 U 5.0 U 5.0 U NA NA 5.0 U 2-Nitroaniline --190 n 5.0 UJ NA NA NA NA NA NA NA 3-Hydroxybiphenyl (01)----7.4 NJ NA NA NA NA NA NA NA 3-Phenyl-2-propyn-1-ol ----NA NA NA NA 41 NJ NA NA NA 3-Phenylbut-1-ene ----NA NA NA NA 21 NJ NA NA NA 4-Methylphenol ----4.2 J 4.8 J 10 U 10 U 2100 NA NA 10 U 5-Aminoindan --51 NJ 61 NJ NA NA NA NA NA NA 5H-Indeno[1,2-b]pyridine --24 NJ 59 NJ NA NA 74 NJ NA NA NA 6(5H)-Phenanthridinone (01)--49 NJ 60 NJ NA NA NA NA NA NA 9H-Pyrido[3,4-b]indole --NA 46 NJ NA NA NA NA NA NA Acenaphthene --530 n 160 100 5.0 U 5.0 U 460 0.10 U 0.070 J 0.10 U Acenaphthylene ----5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 0.10 U 0.070 J 0.10 U Anthracene --1800 n 4.0 J 4.1 J 5.0 U 5.0 U 40 0.10 U 0.080 J 0.10 U Benz[cd]indol-2(1H)-one (01)--14 NJ NA NA NA NA NA NA NA Benzene 5 0.46 5.0 R 5.0 R 5.0 R 5.0 R 29 J 0.50 U 0.50 U 0.50 U Benzene, 1-ethyl-4-methoxy-----NA 17 NJ NA NA NA NA NA NA Benzene, 1,2,3-trimethyl---55 n NA NA NA NA 7.0 NJ NA NA NA Benzene, 1-ethyl-2-methyl-----NA NA NA NA 5.7 NJ NA NA NA Benzocycloheptatriene ----NA 9.6 NJ NA NA NA NA NA NA Benzofuran, 2-methyl-----8.2 NJ 7.8 NJ NA NA NA NA NA NA Biphenyl ----NA 5.8 NJ NA NA NA NA NA NA Benzo[b]thiophene, 2-methyl-----NA NA NA NA 6.6 NJ NA NA NA Benzo[b]thiophene, 4-methyl-----NA NA NA NA 7.6 NJ NA NA NA Benzofuran ----NA NA NA NA 44 NJ NA NA NA Benzofuran, 2-methyl-----NA NA NA NA 88 NJ NA NA NA Carbazole ----74 84 10 U 10 U 340 J NA NA 10 U Chrysene --25 c 5.0 U 5.0 U 5.0 U 5.0 U 5.0 R 0.10 U 0.19 0.10 U Cyclotetrasiloxane, octamet...--NA 7.0 NJ NA NA 8.2 NJ NA NA 0.68 NJ Dibenzofuran --7.9 n 48 37 5.0 U 5.0 U 170 J NA NA 5.0 U Di-n-octylphthalate ----2.4 J 10 U 10 U 10 U 10 U NA NA 2.2 J Fluoranthene ----5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 0.10 U 0.17 0.10 U Fluorene --290 n 30 26 5.0 U 5.0 U 170 J 0.10 U 0.10 U 0.10 U Formamide, N,N-dimethyl-----NA NA 5.1 NJ NA NA NA NA NA Hexanedioic acid, bis(2-eth...----9.6 NJ NA 11 NJ NA NA NA NA 8.5 NJ Indane ----15 NJ 16 NJ NA NA 180 NJ NA NA NA Indene ----NA NA NA NA 310 NJ NA NA NA Indeno(1,2,3-cd)pyrene --0.25 c 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 0.10 U 0.090 J 0.10 U Isoquinoline, 1-methyl-----NA 53 NJ NA NA 13 NJ NA NA NA m,p-Xylene ----5.0 R 5.0 R 5.0 R 5.0 R 13 J 0.50 U 0.50 U 0.50 U Methylcyclohexane --5.0 R 5.0 R 7.1 J 5.0 R 5.0 R 0.50 U 0.50 U 0.50 U Naphthalene --0.12 c 140 52 5.0 U 5.0 U 7100 0.97 0.94 0.10 U o-Xylene ----5.0 R 5.0 R 5.0 R 5.0 R 7.2 J 0.50 U 0.50 U 0.50 U Pentachlorophenol 1 0.041 c 10 U 10 U 10 U 10 U 10 U 0.20 UJ 0.20 UJ 0.20 UJ Phenanthrene ----35 35 5.0 U 5.0 U 64 0.10 U 0.090 J 0.10 U Phenol --5800 n 4.1 J 6.8 J 10 U 10 U 8800 NA NA 10 U Phenol, 3,5-dimethyl-----7.9 NJ 62 NJ NA NA NA NA NA NA Pyrene --120 n 5.0 U 5 U 5.0 U 5.0 U 5.0 U 0.10 U 0.18 0.10 U Quinoline, 2,4-dimethyl-----11 NJ 130 NJ NA NA NA NA NA NA Quinoline, 2,7-dimethyl-----20 NJ NA NA NA 100 NJ NA NA NA Toluene 1000 1100 5.0 R 5.0 R 5.0 R 5.0 R 14 J 0.50 U 0.50 U 0.50 U Total Alkanes ----15 J 16 J 9.5 J NA 180 J NA NA N NA Notes: Bolded and Red Detection above 2022 EPA MCL Benchmark Shaded orange Detection above 2022 EPA Tapwater RSL Benchmark Shaded orange and bolded red Detection above 2022 EPA Tapwater RSL and MCL Benchmarks MCL Maximum Contaminant Level RSL Regional Screening Level J Concentration is Estimated U Analyte was not detected UJ Analyte was not detected due to deficiencies in one or more quality control criteria NJ Analyte has been "tentatively identified" and the value is the approximate concentration in the sample R Rejected (Sample was analyzed outside of laboratory holding time) NA Not analyzed for --No MCL or RSL value n Noncancer Tapwater RSL c Cancer Tapwater RSL Table 2: Groundwater VOC, SVOC, and PAHs Results for Reilly Tar Sept. 2021 MW-18 MW-33 PZ-4MW-18DUP MW-19 MW-22 PZ-5 PZ-6Monitoring Well ID: Analyte Sample Number: Screening Level Benchmarks: RPD RPD T D T D T D MCL (ug/L)Tapwater RSL (ug/L)Aluminum --20000 n 200 U 200 U 200 U 200 U 0.00 0.00Antimony67.8 n 60 U 60 U 60 U 60 U 0.00 0.00Arsenic100.052 c 10 U 10 U 10 U 10 U 0.00 0.00Barium20003800 n 28 J 29 J 29 J 29 J -3.51 0.00Beryllium----5.0 U 5.0 U 5.0 U 5.0 U 0.00 0.00Cadmium59.2 n 5.0 U 5.0 U 5.0 U 0.82 J 0.00 NCCalcium----410000 400000 380000 360000 7.59 10.53Chromium100--10 U 10 U 10 U 10 U 0.00 0.00Cobalt--6 n 50 U 50 U 50 U 50 U 0.00 0.00Copper1300230 n 10 J 11 J 9.6 J 12 J 4.08 -8.70Iron--14000 n 100 U 100 U 100 U 100 U 0.00 0.00Lead15156.2 J 7.4 J 5.9 J 5.7 J 4.96 25.95Magnesium----100000 110000 110000 110000 -9.52 0.00Manganese--430 n 290 280 290 280 0.00 0.00Nickel----40 U 40 U 40 U 40 U 0.00 0.00Potassium----41000 43000 42000 42000 -2.41 2.35Selenium5010035U35U35U35U0.00 0.00Silver--94 n 10 U 10 U 10 U 10 U 0.00 0.00Sodium----590000 630000 J+61000 560000 J+162.52 11.76Thallium20.2 25 U 9.3 J 6.8 J 8.3 J NC 11.36Vanadium--86 n 50 U 50 U 50 U 50 U 0.00 0.00Zinc--6000 n 60 U 60 U 60 U 60 U 0.00 0.00 Notes: Bolded and Red Detection above 2022 EPA MCL Benchmark NC RPD Not Calculated MCL Maximum Contaminant Level T Total Metals D Dissolved Metals --No MCL or RSL value n Noncancer Tapwater RSL c Cancer Tapwater RSL RPD Relative Percent Difference J Concentration is estimated U Analyte was not detected UJ Analyte was not detected due to deficiencies in one or more quality control criteria NJ Analyte has been "tentatively identified" and the value is the approximate concentration in the sample R Rejected (Sample was analyzed outside of laboratory holding time) J-Concentration is estimated, biased low J+Concentration is estimated, biased high Table 3: Inorganic Groundwater RPD QA QC Analyte Monitoring Well ID:MW-18 MW-18_DUP Sample Number:H0AA3 H0AA7 Total/Dissolved RPD H0AA3 Q H0AA7 Q MCL (ug/L)Tapwater RSL (ug/L) 1(2H)-Isoquinolinone ----270 NJ 360 NJ -28.57 1,1'-Biphenyl --0.83 n 7.4 4.1 J 57.39 1,2,4-Trimethylbenzene --56 n 5.0 R 5.0 R 0.00 1,2-Dichloropropane 5 0.85 5.0 R 5.0 R 0.00 1,4-Dichlorobenzene 75 0.48 c 5.0 R 5.0 R 0.00 1-Methylnaphthalene --1.1 c 35 17 69.23 1-Naphthalenecarbonitrile ----18 NJ 28 NJ -43.48 1-Naphthalenol ----58 NJ 56 NJ 3.51 1-Naphthalenol, 2-methyl-----36 NJ NA NC 2(1H)-Quinolinone, 4,8-dime...----12 NJ 46 NJ -117.24 2,4-Dimethylphenol --360 n 230 180 24.39 2,4-Dinitrotoluene --0.24 c 14 16 -13.33 2-Benzothiophene #----16 NJ NA NC 2-Dibenzofuranol (01)----26 NJ 36 NJ -32.26 2-Hydroxyfluorene ----11 NJ NA NC 2-Methylindene ----NA NA NC 2-Methylnaphthalene --36 n 2.9 J 79 -185.84 2-Methylphenol ----12 14 -15.38 2-Naphthalenol, 1-amino---31 NJ 24 J+25.45 2-Nitroaniline --190 n 5.0 UJ NA NC 3-Hydroxybiphenyl (01)----7.4 NJ NA NC 4-Methylphenol ----4.2 J 4.8 J -13.33 5-Aminoindan --51 NJ 61 NJ -17.86 5H-Indeno[1,2-b]pyridine --24 NJ 59 NJ -84.34 6(5H)-Phenanthridinone (01)--49 NJ 60 NJ -20.18 9H-Pyrido[3,4-b]indole --NA 46 NJ NC Acenaphthene --530 n 160 100 46.15 Acenaphthylene ----5.0 U 5.0 U 0.00 Anthracene --1800 n 4.0 J 4.1 J -2.47 Benz[cd]indol-2(1H)-one (01)--14 NJ NA NC Benzene 5 0.46 5.0 R 5.0 R 0.00 Benzene, 1-ethyl-4-methoxy-----NA 17 NJ NC Benzocycloheptatriene ----NA 9.6 NJ NC Benzofuran, 2-methyl-----8.2 NJ 7.8 NJ 5.00 Biphenyl ----NA 5.8 NJ NC Carbazole ----74 84 -12.66 Chrysene --25 c 5.0 U 5.0 U 0.00 Cyclotetrasiloxane, octamet...--NA 7.0 NJ NC Dibenzofuran --7.9 n 48 37 25.88 Di-n-octylphthalate ----2.4 J 10 U NC Fluoranthene ----5.0 U 5.0 U 0.00 Fluorene --290 n 30 26 14.29 Hexanedioic acid, bis(2-eth...----9.6 NJ NA NC Indane ----15 NJ 16 NJ -6.45 Indeno(1,2,3-cd)pyrene --0.25 c 5.0 U 5.0 U 0.00 Isoquinoline, 1-methyl-----NA 53 NJ NC m,p-Xylene ----5.0 R 5.0 R 0.00 Methylcyclohexane --5.0 R 5.0 R 0.00 Naphthalene --0.12 c 140 52 91.67 o-Xylene ----5.0 R 5.0 R 0.00 Pentachlorophenol 1 0.041 c 10 U 10 U 0.00 Phenanthrene ----35 35 0.00 Phenol --5800 n 4.1 J 6.8 J -49.54 Phenol, 3,5-dimethyl-----7.9 NJ 62 NJ -154.79 Pyrene --120 n 5.0 U 5 U 0.00 Quinoline, 2,4-dimethyl-----11 NJ 130 NJ -168.79 Quinoline, 2,7-dimethyl-----20 NJ NA NC Toluene 1000 1100 5.0 R 5.0 R 0.00 Total Alkanes ----15 J 16 J -6.45 Notes: Bolded and Red Detection above 2022 EPA MCL Benchmark NC RPD Not Calculated MCL Maximum Contaminant Level T Total Metals D Dissolved Metals --No MCL or RSL value n Noncancer Tapwater RSL c Cancer Tapwater RSL RPD Relative Percent Difference J Concentration is estimated U Analyte was not detected UJ Analyte was not detected due to deficiencies in one or more quality control criteria NJ Analyte has been "tentatively identified" and the value is the approximate concentration in the sample R Rejected (Sample was analyzed outside of laboratory holding time) J-Concentration is estimated, biased low J+Concentration is estimated, biased high Table 4: Organic Groundwater RPD QA QC Analyte Monitoring Well ID:MW-18 MW-18DUP Sample Number: Screening Level Benchmarks: Sampling Results Report 3220 South Solvents – UTD009087655 22 APPENDIX C START TRIP REPORT ENCLOSURES 1-3 1 February 17, 2022 Mr. Martin McComb On-Scene Coordinator U.S. Environmental Protection Agency, Region 8 1595 Wynkoop Street Denver, Colorado 80202 Subject: Trip Report – Revision 0 Reilly Coal Tar Removal Assessment, Provo, Utah U.S. EPA Region 8 START 5, Contract No. 68HE0820D0001 Task Order No. 68HE0820F0071 Task Monitor: Marty McComb, EPA On-Scene Coordinator Dear Mr. McComb: The Tetra Tech Inc. (Tetra Tech) Superfund Technical Assessment and Response Team (START) is submitting this Trip Report – Revision 0 for the Reilly Coal Tar Removal Assessment (the Site) in Provo, Utah County, Utah for your review and comment. This report summarizes field activities conducted at the Site during the September 8, 2021 investigation and sampling event. The scope of this project was to provide technical assistance and sampling support to characterize the extent and magnitude of contamination in subsurface soils on the 23-acre southern portion of the Site. This trip report summarizes site activities and findings, including site background and physical location, site activities, analytical results, and conclusions. Enclosure 1 presents the photolog; Enclosure 2 presents the site figures; Enclosure 3 contains tables; and Enclosure 3 presents the verified laboratory data package. SITE BACKGROUND AND PHYSICAL LOCATION The Site is located at 2555 South Industrial Parkway, Provo, Utah County, Utah (Figure 1). The geographic coordinates for the approximate center of the site are 40.199167° north latitude, - 111.630154° west longitude. The Site is an abandoned coal tar distillery that operated from 1924 to 2002. Land use in the area is largely industrial. The Ironton Canal constitutes the northern boundary of the Site and discharges into Spring Creek and Utah Lake’s Provo Bay, approximately 1.5 miles west of the Site. The southern portion of the Site is now a seasonal wetland, and groundwater tends to flow westward beneath a nearby industrial facility. SITE ACTIVITES Environmental Restoration LLC (ER) and START conducted investigation and soil sampling activities 2 on September 8, 2021. As directed by the U.S. Environmental Protection Agency (EPA), ER conducted the excavation of fifteen test pits to the maximum depth the excavator could reach, between 10 feet below ground surface (bgs) to 20 feet bgs. Test pit locations were selected based on site conditions and accessibility to safely maneuver and operate the excavator. Test pit locations are identified on Figure 2 and 3. During excavation activities, START photo documented excavated soil conditions and used a MultiRAE Pro to screen VOC concentrations in soil throughout investigation activities. Headspace monitoring results are summarized in Table 1. START identified the presence of coal tar in Test Pit (TP) 01, 14, and 15. The remaining test pits did not reveal the presence of coal tar throughout the soil profile of the test pit. START collected a grab subsurface sample from three test pits; two test pits that contained coal tar (TP01 and TP14) and one test pit without the presence of coal tar as a background (TP13). After completing the documentation of test pit locations, all soil was returned to the original test pit to match the surrounding grade. ANALYTICAL RESULTS The three subsurface soil samples and associated QC samples collected during the site activities were analyzed by ALS Laboratory in Fort Collins, Colorado. Samples were analyzed for total petroleum hydrocarbons gasoline range organics (TPH-GRO), total petroleum hydrocarbons diesel range organics (TPH-DRO), total petroleum hydrocarbons oil range organics (TPH-ORO), Semi-volatile organic compound s (SVOCs), Target Analyte List (TAL) Metals, and VOCs. Analytical results were compared to EPA Removal Management Level (RML) for industrial soil with a target excess cancer risk level of 10-4 and a target hazard quotient of 1.0 for non-carcinogens (EPA 2021a). Analytical results were also compared to EPA regional screening levels (RSL) for industrial soil with a target excess cancer risk level of 10-6 and a target hazard quotient of 1.0 (EPA 2021b). In three of the samples, there were exceedances of the EPA RMLs for TPH-DRO, TPH-ORO, TPH- GRO, 2-methylnaphthalene, benzo(a)pyrene, dibenzofuran, and naphthalene. Additionally there were exceedances of the EPA RSLs for 1-methylnaphthalene, benz(a)anthracene, benzo(b)fluoranthene, benzo(k)fluoranthene, dibenz(a,h)anthracene, indeno(1,2,3-cd)pyrene, benzene, ethylbenzene, and arsenic. Table 2 summarizes the analytical results for the subsurface soil samples. Subsurface soil sample locations with exceedances are identified on Figure 3. Table 1 lists the readings documented from the periodic headspace air monitoring for VOCs. Four of the readings were above the short-term exposure limit (STEL) of 5.0 ppm and the PEL of 12 ppm. Headspace air monitoring sample locations with exceedances are identified on Figure 2. CONCLUSIONS START personnel collected a subsurface soil samples at three separate test pit locations (TP01, TP13, and TP14). The presence of coal tar was identified in three test pits located in the northwest area of the investigated area (TP01, TP14, and TP15. DATA MANAGEMENT START personnel collected mobile data using ESRI’s Survey123 mobile data collection application to 3 document subsurface soil information, and to collect general photos and other site observations. All subsurface soil sample data and analytical results were loaded into a Scribe database. If you have any questions or comments regarding this trip report, please call me at (804) 357-6775. Sincerely, Madison Ericson START V Project Manager Enclosures (4) Enclosure 1 – Photolog Enclosure 2 – Site Figures Enclosure 3 – Table Enclosure 4 – Laboratory Analytical Packages cc: Di Di Fung, START Region 8 Program Manager Clayton Longest, START Region 8 Document Control Coordinator ENCLOSURE 1 PHOTOLOG PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: NW corner of site Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 1 Photo Description: The site from the northwest corner looking southeast. Date/Time Taken: 09/08/2021 9:17:AM Photographer: Resch_Ryan Latitude: 40.19799183 Longitude: -111.6298815 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: NW corner of site Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 2 Photo Description: The site from the northwest corner looking east. Date/Time Taken: 09/08/2021 9:18:AM Photographer: Resch_Ryan Latitude: 40.19799483 Longitude: -111.62984761 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: NW corner of site Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 3 Photo Description: The site from the northwest corner looking south. Date/Time Taken: 09/08/2021 9:18:AM Photographer: Resch_Ryan Latitude: 40.19796842 Longitude: -111.62985317 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: SE corner of site Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 4 Photo Description: The site from the southeast corner looking west. Date/Time Taken: 09/08/2021 2:14:PM Photographer: Resch_Ryan Latitude: 40.19562333 Longitude: -111.62684641 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: SE corner of site Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 5 Photo Description: The site from the southeast corner looking northwest Date/Time Taken: 09/08/2021 2:15:PM Photographer: Resch_Ryan Latitude: 40.19573386 Longitude: -111.62685408 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP01 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 6 Photo Description: Advancement of TP01. Date/Time Taken: 09/08/2021 10:23:AM Photographer: Resch_Ryan Latitude: 40.19763072 Longitude: -111.62975789 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP01 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 7 Photo Description: Coal tar present in soil removed from TP01. Date/Time Taken: 09/08/2021 10:59:AM Photographer: Resch_Ryan Latitude: 40.19858333 Longitude: -111.62533264 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP01 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 8 Photo Description: Soil profile of TP01. Date/Time Taken: 09/08/2021 10:59:AM Photographer: Resch_Ryan Latitude: 40.19763867 Longitude: -111.62967317 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP02 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 9 Photo Description: Soil removed from TP02 Date/Time Taken: 09/08/2021 11:43:AM Photographer: Resch_Ryan Latitude: 40.19694181 Longitude: -111.62939525 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP02 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 10 Photo Description: Soil profile of TP02. Date/Time Taken: 09/08/2021 11:44:AM Photographer: Latitude: 40.19694703 Longitude: -111.62935818 Photo Direction: N Photo Description: Date/Time Taken: Photographer: Resch_Ryan Latitude: 0 Longitude: 0 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP03 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 11 Photo Description: Soil removed from TP03. Date/Time Taken: 09/08/2021 11:51:AM Photographer: Resch_Ryan Latitude: 40.19642528 Longitude: -111.62932528 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP03 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 12 Photo Description: Soil profile of TP03. Date/Time Taken: 09/08/2021 11:52:AM Photographer: Resch_Ryan Latitude: 40.19641429 Longitude: -111.62924561 Photo Direction: N Photo Description: Date/Time Taken: 09/08/2021 12:02:PM Photographer: Resch_Ryan Latitude: 0 Longitude: 0 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP04 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 13 Photo Description: Advancement of TP04. Date/Time Taken: 09/08/2021 12:06:PM Photographer: Resch_Ryan Latitude: 40.19765775 Longitude: -111.62899697 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP04 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 14 Photo Description: Soil profile of TP04. Date/Time Taken: 09/08/2021 12:11:PM Photographer: Resch_Ryan Latitude: 40.19772872 Longitude: -111.629109 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP04 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 15 Photo Description: Soil removed from TP04. Date/Time Taken: 09/08/2021 12:11:PM Photographer: Resch_Ryan Latitude: 40.19775683 Longitude: -111.62910833 Photo Direction: N Photo Description: Date/Time Taken: 09/08/2021 12:21:PM Photographer: Resch_Ryan Latitude: 0 Longitude: 0 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP05 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 16 Photo Description: Advancement of TP05. Date/Time Taken: 09/08/2021 12:26:PM Photographer: Resch_Ryan Latitude: 40.19717058 Longitude: -111.62902806 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP05 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 17 Photo Description: Soil profile of TP05. Date/Time Taken: 09/08/2021 12:27:PM Photographer: Resch_Ryan Latitude: 40.19704608 Longitude: -111.62896453 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP05 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 18 Photo Description: Soil removed from TP05. Date/Time Taken: 09/08/2021 12:29:PM Photographer: Resch_Ryan Latitude: 40.19704983 Longitude: -111.62897936 Photo Direction: N Photo Description: Date/Time Taken: 09/08/2021 12:34:PM Photographer: Resch_Ryan Latitude: 0 Longitude: 0 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP06 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 19 Photo Description: Soil profile of TP06. Date/Time Taken: 09/08/2021 12:40:PM Photographer: Resch_Ryan Latitude: 40.196444 Longitude: -111.62865106 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP06 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 20 Photo Description: Soil removed from TP06. Date/Time Taken: 09/08/2021 12:41:PM Photographer: Resch_Ryan Latitude: 40.19642461 Longitude: -111.62868872 Photo Direction: N Photo Description: Date/Time Taken: Photographer: Resch_Ryan Latitude: 0 Longitude: 0 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP07 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 21 Photo Description: Soil profile of TP07. Date/Time Taken: 09/08/2021 12:53:PM Photographer: Resch_Ryan Latitude: 40.19675925 Longitude: -111.62816583 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP07 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 22 Photo Description: Soil removed from TP07. Date/Time Taken: 09/08/2021 12:55:PM Photographer: Resch_Ryan Latitude: 40.19674542 Longitude: -111.62813703 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP08 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 23 Photo Description: Advancement of TP08. Date/Time Taken: 09/08/2021 1:48:PM Photographer: Resch_Ryan Latitude: 40.19705211 Longitude: -111.62748093 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP08 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 24 Photo Description: Soil profile of TP08. Date/Time Taken: 09/08/2021 1:53:PM Photographer: Resch_Ryan Latitude: 40.19700764 Longitude: -111.62732246 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP08 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 25 Photo Description: Soil removed from TP08. Date/Time Taken: 09/08/2021 1:53:PM Photographer: Resch_Ryan Latitude: 40.19700122 Longitude: -111.62728436 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP09 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 26 Photo Description: Soil profile of TP09. Date/Time Taken: 09/08/2021 2:04:PM Photographer: Resch_Ryan Latitude: 40.19642689 Longitude: -111.62682424 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP09 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 27 Photo Description: Soil removed from TP09. Date/Time Taken: 09/08/2021 2:05:PM Photographer: Resch_Ryan Latitude: 40.19640939 Longitude: -111.62684675 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP10 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 28 Photo Description: Soil profile of TP10. Date/Time Taken: 09/08/2021 2:23:PM Photographer: Resch_Ryan Latitude: 40.19569178 Longitude: -111.62677073 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP10 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 29 Photo Description: Soil removed from TP10 Date/Time Taken: 09/08/2021 2:23:PM Photographer: Resch_Ryan Latitude: 40.19568156 Longitude: -111.62676797 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP11 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 30 Photo Description: Soil profile of TP11. Date/Time Taken: 09/08/2021 2:33:PM Photographer: Resch_Ryan Latitude: 40.19615999 Longitude: -111.62825926 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP12 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 31 Photo Description: Soil profile of TP12. Date/Time Taken: 09/08/2021 2:40:PM Photographer: Resch_Ryan Latitude: 40.19571864 Longitude: -111.62924853 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP13 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 32 Photo Description: Soil profile of TP13. Date/Time Taken: 09/08/2021 2:54:PM Photographer: Resch_Ryan Latitude: 40.19748083 Longitude: -111.62827597 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP14 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 33 Photo Description: Soil profile of TP14. Date/Time Taken: 09/08/2021 3:22:PM Photographer: Latitude: 40.19734597 Longitude: -111.62974572 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP14 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 34 Photo Description: Soil removed from TP14. Date/Time Taken: 09/08/2021 3:23:PM Photographer: Resch_Ryan Latitude: 40.19732264 Longitude: -111.62974337 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP15 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 35 Photo Description: Soil profile of TP15. Date/Time Taken: 09/08/2021 3:51:PM Photographer: Resch_Ryan Latitude: 40.19802586 Longitude: -111.63015481 Photo Direction: N PHOTOGRAPH LOG Project Name: Reilly Coal Tar Site Location: TP15 Project No. 2071-2105-06 U.S. Environmental Protection Agency - Region 8 1595 Wynkoop St. Denver, CO 80202 Page | 36 Photo Description: Soil removed from TP15. Date/Time Taken: 09/08/2021 3:51:PM Photographer: Resch_Ryan Latitude: 40.19802114 Longitude: -111.63013633 Photo Direction: N ENCLOSURE 2 SITE FIGURES TP01 TP02TP03 TP04 TP05 TP06 TP07 TP08 TP09 TP10 TP11 TP12 TP13 TP14 TP15 Arizona Colorado Idaho Nevada New Mexico Utah Wyoming 0 100 20050 Feet Utah County File: \\tts194fs1\CAD\GIS\R8STARTV\ReillyCoalTar\ArcGIS_Pro FIGURE 2 2071-2105-06 Reilly Coal Tar Test Pit Locations with Headspace Exceedances TD No.: Site Name: UtahUtahIronton State:County: United States Environmental Protection Agency Region 8 ± Date: 2/9/2022 City: Investigated Area Site Boundary Test Pit Locations Spatial Reference Name: GCS North American 1983 GCS: GCS North American 1983 Datum: North American 1983 Map Units: Degree Depth VOC Results 20’ bgs 15.38 Depth VOC Results 3’ bgs 0 10’ bgs *510 Depth VOC Results 4’ bgs 32.7 10’ bgs 18.05 XXX The reported concentration exceeds permissible exposure limit (PEL) *Saturated soil at depth bgs Below Ground Surface VOC Volatile Organic Compounds All sample results are presented in units of parts per million (ppm) All depths below ground surface are presented in feet (') TP01 TP02TP03 TP04 TP05 TP06 TP07 TP08 TP09 TP10 TP11 TP12 TP13 TP14 TP15 Arizona Colorado Idaho Nevada New Mexico Utah Wyoming 0 100 20050 Feet Spatial Reference Name: GCS North American 1983 GCS: GCS North American 1983 Datum: North American 1983 Map Units: Degree Utah County File: \\tts194fs1\CAD\GIS\R8STARTV\ReillyCoalTar\ArcGIS_Pro FIGURE 3 2071-2105-06 Reilly Coal Tar Soil Sample Exceedances TD No.: Site Name: UtahUtahIronton State:County: United States Environmental Protection Agency Region 8 ± Date: 2/9/2022 City: Test Pit Locations Investigated Area Site Boundary XXX The reported concentration exceeds the RSL for industrial soil XXX The reported concentration exceeds the RML and RSL for industrial soil RML Removal Management Level, with hazard quotient = 1.0 for non-carcinogens RSL Regional Screening Level, with hazard quotient = 1.0 NJ Analyte has been "tentatively identified" and the value is the approximate concentration in the sample J Concentration is estimated J-Concentration is estimated, biased low *All sample results are presented in units of milligrams per kilograms Analyte Results Diesel Range Organics 7,100 J Oil Range Organics 1,800 J 1-Methylnaphthalene 210 Benz(a)anthracene 98 Benzo(a)pyrene 39 Benzo(b)fluoranthene 50 Dibenz(a,h)anthracene 3.3 J Benzene 15 J Naphthalene 1,500 Arsenic 6.8 -- 3,000 7.3 4,100 J 310 130 55 70 5.0 J RCT-SS-TP01 RCT-SS-TP01-DUP Results 11,000 J Analyte Results Arsenic 7 RCT-SS-TP13 Analyte Results Diesel Range Organics 77,000 Oil Range Organics 30,000 NJ Gasoline Range Organics 1500 J- 1-Methylnaphthalene 2,900 2-Methylnaphthalene 5,600 Benz(a)anthracene 1,600 Benzo(a)pyrene 1,200 Benzo(b)fluoranthene 1,400 Benzo(k)fluoranthene 620 Dibenz(a,h)anthracene 110 J Dibenzofuran 3,400 Indeno(1,2,3-cd)pyrene 430 Benzene 100 Ethylbenzene 62 Naphthalene 46,000 RCT-SS-TP14 ENCLOSURE 3 TABLES Table 1. Headspace Air Monitoring Readings Depth Below Ground Surface(bgs) Lower Explosive Limit (LEL) Oxygen (O2) Volatile Organic Compounds (VOCs) Carbon Monoxide (CO) Hydrogen Sulfide (H2S) ft %%ppm ppm ppm TP01 20’ bgs 4 20.9 15.38 4 3.4 4’ bgs 0 21.3 0 0 0 10’ bgs 0 21.3 0 0 0 3’ bgs 0 21.3 0 0 0 10’ bgs 0 21.3 0 0 0 3’ bgs 0 21.4 0 0 0 10’ bgs *0 21.3 510 0 0 3’ bgs 0 21.3 0 0 0 10’ bgs 0 21.3 0 0 0 3’ bgs 0 21.3 0 0 0 10’ bgs 0 21.3 0 0 0 10’ bgs 0 21.3 0 0 0 3’ bgs 0 21.3 0 0 0 10’ bgs 0 21.4 0 0 0 3’ bgs 0 21.4 0 0 0 TP09 11’ bgs 0 21.4 0 0 0 TP10 12’ bgs 0 21.3 0 0 0 TP11 10’ bgs 0 21.4 0 0 0 TP12 10’ bgs 0 21.3 0 0 0 3’ bgs 0 21.3 0 0 0 10’ bgs 0 21.3 0 0 0 4’ bgs 4 20.9 32.7 5 3.5 10’ bgs 3 20.9 18.05 3 3.3 10%>19.5%5 ppm 25 ppm 10 ppm 10%>19.5%12 ppm 50 ppm 20 ppm Notes: * saturated soil at depth Bolded and shaded orange result indicates detection above the permissible exposure limit ft Feet PEL STEL ppm Parts per million Short-term exposure limit, is the maximum concentration of a chemical to which workers may be exposed continuously for a short period of time without any danger to health, safety or work efficiency TP08 TP13 TP14 Test Pit (TP)# PEL Permissible exposure limit, is the maximum amount or concentration of a chemical that a worker may be exposed to under OSHA regulations STEL TP02 TP03 TP04 TP05 TP06 TP07 1 of 1 Table 2. Subsurface Soil Sample Results RCT-SS-TP01 RCT-SS-TP01- DUP RCT-SS-TP13 RCT-SS-TP14 (mg/kg) (mg/kg)(mg/kg)(mg/kg)(mg/kg)(mg/kg) Diesel Range Organics 440 440 7,100 J 11,000 J 11 U 77,000 Oil Range Organics 30,000 30,000 1,800 J 4,100 J 11 UJ 30,000 NJ Gasoline Range Organics 420 420 19 J 110 J 0.52 U 1500 J- 1-Methylnaphthalene 73 53,000 210 310 0.90U 2,900 2,3,4,6-Tetrachlorophenol 25,000 25,000 20 U 20 U 0.90U 160 U 2,4,5-Trichlorophenol 82,000 82,000 20 U 20 U 0.90U 160 U 2,4,6-Trichlorophenol 210 820 20 U 20 U 0.90U 160 U 2,4-Dichlorophenol 2,500 2,500 20 U 20 U 0.90U 160 U 2,4-Dimethylphenol 16,000 16,000 56 69 0.90U 490 2,4-Dinitrophenol 1,600 1,600 39 U 39 U 1.8 U 320 U 2,4-Dinitrotoluene 7.4 1,600 20 U 20 U 0.90U 160 U 2,6-Dinitrotoluene 1.5 250 20 U 20 U 0.90U 160 U 2-Chloronaphthalene 60,000 60,000 20 U 20 U 0.90U 160 U 2-Chlorophenol 5,800 5,800 20 U 20 U 0.90U 160 U 2-Methylnaphthalene 3,000 3,000 330 560 0.90U 5,600 2-Methylphenol ----110 130 0.90U 920 2-Nitroaniline 8,000 8,000 39 U 39 U 1.8 U 320 U 2-Nitrophenol ----20 U 20 U 0.90U 160 U 3,3'-Dichlorobenzidine 5.1 --20 U 20 U 0.90U 160 U 3+4-Methylphenol ----270 430 0.90U 2,100 3-Nitroaniline ----39 U 39 U 1.8 U 320 U 4,6-Dinitro-2-methylphenol ----79 U 79 U 3.6 U 640 U 4-Bromophenyl phenyl ether ----20 U 20 U 0.90U 160 U 4-Chloro-3-methylphenol ----20 U 20 U 0.90U 160 U 4-Chloroaniline 11 410 20 U 20 U 0.90U 160 U p-Chlorophenyl phenyl ether ----20 U 20 U 0.90U 160 U 4-Nitroaniline 110 3,300 39 U 39 U 1.8 U 320 U 4-Nitrophenol ----39 U 39 U .26 J 320 U Acenaphthene 45,000 --450 760 0.90U 8,200 Acenaphthylene ----34 48 0.90U 1,100 Aniline 400 5700 20 U 20 U .27 J 160 U Anthracene 230,000 --200 320 0.90U 2,800 Azobenzene 26 --20 U 20 U 0.90U 160 U Benz(a)anthracene 21 --98 130 .39 J+1,600 Benzo(a)pyrene 2.1 220 39 55 .46 J+1,200 Benzo(b)fluoranthene 21 --50 70 0.51 J+1,400 Benzo(g,h,i)perylene ----13 J 21 0.25 J 510 Benzo(k)fluoranthene 210 --18 J 25 0.19 J 620 Benzoic Acid 3,300,000 3,300,000 98 UJ 98 UJ 4.6 UJ 800 UJ Benzyl alcohol 82,000 82,000 20 U 20 U 0.92U 160 U Bis(2-chloroethoxy)methane 2,500 2,500 20 U 20 U 0.92U 160 U Bis(2-chloroethyl) ether 1 --20 U 20 U 0.92U 160 U Bis(2-chloroisopropyl) ether ----20 U 20 U 0.92U 160 U Bis(2-ethylhexyl) phthalate 160 16,000 29 U 29 U 1.4 U 240 U Analyte EPA Industrial RSL EPA Industrial RML Sample Concentration by Location Total Petroleum Hydrocarbons (TPH) Semi-Volatile Organic Compound (SVOC) 1 of 4 Table 2. Subsurface Soil Sample Results RCT-SS-TP01 RCT-SS-TP01- DUP RCT-SS-TP13 RCT-SS-TP14 (mg/kg) (mg/kg)(mg/kg)(mg/kg)(mg/kg)(mg/kg) Analyte EPA Industrial RSL EPA Industrial RML Sample Concentration by Location Butyl benzyl phthalate 1,200 160,000 20 U 20 U 0.92U 160 U Carbazole ----140 180 0.90U 1,700 Chrysene 2100 --100 140 .48 J+1,600 Dibenz(a,h)anthracene 2.1 --3.3 J 5.0 J 0.19 J 110 J Dibenzofuran 1,200 1,200 210 200 U 0.90U 3,400 Diethyl phthalate 660,000 660,000 20 U 20 U 0.90U 160 U Dimethyl phthalate ----20 U 20 U 0.90U 160 U Di-n-butyl phthalate 82,000 --20 U 20 U 0.90U 160 U Di-n-octyl phthalate 8,200 --29 U 29 U 1.4 U 240 U Fluoranthene 30,000 30,000 380 650 0.88J 7,600 Fluorene 30,000 30,000 320 540 0.90U 5,600 Hexachlorobenzene 96 12 20 U 20 U 0.90U 160 U Hexachlorocyclopentadiene 7.5 7.5 20 U 20 U 0.90U 160 U Hexachloroethane 8 460 20 U 20 U 0.90U 160 U Indeno(1,2,3-cd)pyrene 21 --12 J 18 J .25 J 430 Isophorone 2,400 160,000 20 U 20 U 0.92U 160 U Nitrobenzene 22 1,300 20 U 20 U 0.90U 160 U N-Nitrosodimethylamine 0.034 5.7 20 U 20 U 0.90U 160 U n-Nitrosodi-n-propylamine 0.33 --20 U 20 U 0.90U 160 U n-Nitrosodiphenylamine 470 --20 U 20 U 0.90U 160 U Pentachlorophenol 4 2,800 79 U 79 U 3.6 U 640 U Phenanthrene ----960 1600 1.3 J+18,000 Phenol 250,000 250,000 260 440 0.90U 2,800 Pyrene 23,000 23,000 390 690 1.1 J+7,600 Pyridine 1,200 1,200 59 U 59 U 2.7 U 480 U 1,1,1,2-Tetrachloroethane 8.8 35,000 37 U 38 U 0.0076 UJ 31 U 1,1,1-Trichloroethane 36,000 36,000 37 U 38 U 0.0076 UJ 31 U 1,1,2,2-Tetrachloroethane 2.7 23,000 37 U 38 U 0.0076 UJ 31 U 1,1,2-Trichloro-1,2,2-trifluoroethane 28,000 28,000 37 U 38 U 0.0076 UJ 31 U 1,1,2-Trichloroethane 5 6.3 37 U 38 U 0.0076 UJ 31 U 1,1-Dichloroethane 16 230,000 37 U 38 U 0.0076 UJ 31 U 1,1-Dichloroethene --1,000 37 U 38 U 0.0076 UJ 31 U 1,1-Dichloropropene ----37 U 38 U 0.0076 UJ 31 U 1,2,3-Trichlorobenzene 930 930 37 U 38 U 0.0076 UJ 31 U 1,2,3-Trichloropropane 0.11 21 37 U 38 U 0.0076 UJ 31 U 1,2,4-Trichlorobenzene 110 260 37 U 38 U 0.0076 UJ 31 U 1,2,4-Trimethylbenzene 1,800 1,800 37 U 38 U 0.0076 UJ 74 1,2-Dibromo-3-chloropropane 0.064 25 75 U 76 U 0.015 UJ 62 U 1,2-Dibromoethane 0.16 330 37 U 38 U 0.0076 UJ 31 U 1,2-Dichlorobenzene 9,300 9,300 37 U 38 U 0.0076 UJ 31 U 1,2-Dichloroethane 2 140 45 U 46 U 0.0091 UJ 37 U 1,2-Dichloropropane 11 66 37 U 38 U 0.0076 UJ 31 U 1,3,5-Trimethylbenzene 1,500 1,500 37 U 38 U 0.0076 UJ 33 1,3-Dichlorobenzene ----37 U 38 U 0.0076 UJ 31 U 1,3-Dichloropropene 23,000 23,000 37 U 38 U 0.0076 UJ 31 U 1,4-Dichlorobenzene 11 25,000 37 U 38 U 0.0076 UJ 31 U Volatile Organic Compound (VOC) 2 of 4 Table 2. Subsurface Soil Sample Results RCT-SS-TP01 RCT-SS-TP01- DUP RCT-SS-TP13 RCT-SS-TP14 (mg/kg) (mg/kg)(mg/kg)(mg/kg)(mg/kg)(mg/kg) Analyte EPA Industrial RSL EPA Industrial RML Sample Concentration by Location 1-Chlorohexane ----37 U 38 U 0.0076 UJ 31 U 2,2-Dichloropropane ----37 U 38 U 0.0076 UJ 31 U 2-Butanone 190,000 190,000 150 U 150 U 0.030 UJ 120 U 2-Chlorotoluene 23,000 --37 U 38 U 0.0076 UJ 31 U 2-Hexanone 1,300 1,300 150 U 150 U 0.030 UJ 120 U 4-Chlorotoluene 23,000 23,000 37 U 38 U 0.0076 UJ 31 U 4-Methyl-2-pentanone 140,000 140,000 150 U 150 U 0.030 UJ 120 U Acetone 1,100,000 1,100,000 370 U 380 U 0.076 UJ 310 U Benzene 5.1 420 15 J 38 U 0.0076 UJ 100 Bromobenzene 1,800 1,800 37 U 38 U 0.0076 UJ 31 U Bromochloromethane 630 630 37 U 38 U 0.0076 UJ 31 U Bromodichloromethane 1.3 9,300 37 U 38 U 0.0076 UJ 31 U Bromoform 86 23,000 37 U 38 U 0.0076 UJ 31 U Bromomethane 30 30 37 U 38 U 0.0076 UJ 31 U Carbon disulfide 3500 3500 37 U 38 U 0.0076 UJ 31 U Carbon tetrachloride 2.9 570 37 U 38 U 0.0076 UJ 31 U Chlorobenzene 1,300 1,300 37 U 38 U 0.0076 UJ 31 U Chloroethane 23,000 23,000 37 U 38 U 0.0076 UJ 31 U Chloroform 1.4 1,000 37 U 38 U 0.0076 UJ 31 U Chloromethane 460 460 37 U 38 U 0.0076 UJ 31 U cis-1,2-dichloroethene ----37 U 38 U 0.0076 UJ 31 U cis-1,3-Dichloropropene --310 37 U 38 U 0.0076 UJ 31 U Dibromochloromethane 39 23,000 37 U 38 U 0.0076 UJ 31 U Dibromomethane 99 330 37 U 38 U 0.0076 UJ 31 U Dichlorodifluoromethane 370 370 45 U 46 U 0.0091 UJ 37 U Ethylbenzene 25 17,000 37 U 38 U 0.0076 UJ 62 Hexachlorobutadiene 5.3 1,200 37 U 38 U 0.0076 UJ 31 U Iodomethane ----37 U 38 U 0.0076 UJ 31 U Isopropylbenzene ----37 U 38 U 0.0076 UJ 31 U m+p-Xylene 2,400 2,400 52 U 53 U 0.011 UJ 150 Methyl tert-butyl ether (MTBE)210 64,000 60 U 61 U 0.012 UJ 49 U Methylene chloride 1,000 3,200 75 U 76 U 0.015 UJ 62 U Naphthalene 8.6 590 1,500 3,000 0.011 J-46,000 n-Butylbenzene 58,000 58,000 37 U 38 U 0.0076 UJ 31 U n-Propylbenzene --24,000 37 U 38 U 0.0076 UJ 31 U o-Xylene 2,800 2,800 37 U 38 U 0.0076 UJ 76 p-Isopropyltoluene ----37 U 38 U 0.0076 UJ 31 U Sec-butylbenzene 120,000 120,000 37 U 38 U 0.0076 UJ 31 U Styrene 35,000 35,000 37 U 38 U 0.0076 UJ 31 Tert-butylbenzene 120,000 120,000 37 U 38 U 0.0076 UJ 31 U Tetrachloroethene ----37 U 38 U 0.0076 UJ 31 U Toluene 47,000 47,000 30 J 38 U 0.0076 UJ 200 trans-1,2-Dichloroethene ----37 U 38 U 0.0076 UJ 31 U trans-1,3-Dichloropropene ----37 U 38 U 0.0076 UJ 31 U Trichloroethene ----37 U 38 U 0.0076 UJ 31 U Trichlorofluoromethane 350,000 350,000 37 U 38 U 0.0076 UJ 31 U Vinyl acetate 3,800 3,800 150 U 150 U 0.030 UJ 120 U 3 of 4 Table 2. Subsurface Soil Sample Results RCT-SS-TP01 RCT-SS-TP01- DUP RCT-SS-TP13 RCT-SS-TP14 (mg/kg) (mg/kg)(mg/kg)(mg/kg)(mg/kg)(mg/kg) Analyte EPA Industrial RSL EPA Industrial RML Sample Concentration by Location Vinyl chloride 1.7 310 37 U 38 U 0.0076 UJ 31 U Aluminum 1,100,000 1,100,000 6,600 6,200 3,600 480 Aatimony 470 470 .22 J 0.26 0.1 J-0.11 U Arsenic 3 480 6.8 7.3 7 2.2 Barium 220,000 220,000 180 200 120 20 Beryllium 2,300 2,300 1.8 1.7 0.49 0.078 Cadmium 100 100 0.79 0.77 0.34 .21 J Calcium ----150,000 150,000 150,000 J 35,000 Chromium 1,800,000 1,800,000 30 29 10 3.4 Cobalt 350 350 4.2 4.2 3.7 1.4 Copper 47,000 47,000 11 9.1 6.6 1.6 J Iron 820,000 820,000 10,000 9,800 6,400 470 Lead 800 800 8.1 7.8 6.1 J 1.9 Magnesium ----4,600 4,400 7,800 720 Manganese 26,000 26,000 130 130 110 42 Nickel 22,000 22,000 31 30 19 5.1 Potassium ----1,700 1,600 1,700 160 Selenium 5,800 5,800 2.5 2.4 1.3 J 0.89J Silver 5,800 5,800 0.14 0.13 0.065 J 0.022 J Sodium ----2,900 2,700 7,600 1,000 Thallium 12 12 0.3 0.29 0.13 0.029 Vanadium 5,800 5,800 14 12 8.9 8 Zinc 350,000 350,000 170 160 49 23 Mercury 46 46 0.066 J 0.19 J 0.011 J 0.04 Notes: Bolded and green shaded result indicates detection above only EPA industrial RML Bolded and yellow shaded result indicates detection above the EPA industrial RSL EPA RML U.S. Environmental Protection Agency Removal Management Level, with hazard quotient = 1.0 for non-carcinogens EPA RSL U.S. Environmental Protection Agency Regional Screening Level, with hazard quotient = 1.0 J Concentration is estimated J-Concentration is estimated, biased low J+ Concentration is estimated, biased high mg/kg Milligrams per kilogram NJ Analyte has been "tentatively identified" and the value is the approximate concentration in the sample U Analyte was not detected UJ Analyte was not detected due to deficiencies in one or more quality control criteria Target Analyte List (TAL) Metals 4 of 4 Sampling Results Report 3220 South Solvents – UTD009087655 23 APPENDIX D FIELD ACTIVIES REPORT AND SITE PHOTOGRAPHS 1 Reilly Tar Field Activities Report September 29 & 30, 2021 On September 29 and 30, 2021 Michael Swistak, along with Tom Daniels, Chris Howell, Wes Sandlin, and Hannah Marty, took groundwater samples from four monitoring wells and three piezometers at the Reilly Tar Site in Provo, Utah. Groundwater sampling was conducted using low-flow sampling methods. The wells were evacuated with a low-flow peristaltic pump. New high-density polyethylene (HDPE) tubing was used for each well, the inlet of which was placed within the top food of the water column. Water quality parameters (pH, temperature, conductivity, and turbidity) were measured with a Horiba U- 51 Multiparameter Meter, calibrated prior to use according to manufacturer’s specifications. Using depth to water and total depth of well measurements collected with a water level indicator prior to sampling, the casing volume of water for each well was calculated. The wells were purged until one of the following criteria were met: • Groundwater quality parameters of pH, temperature, conductivity, and turbidity readings stabilized to within 10% over three consecutive readings. Readings were taken every five minutes; • three casing volumes were removed; or • The well had pumped dry. In two of the three piezometers, groundwater did not recharge quickly enough, so members of UDEQ DERR gauged other wells around the Site while waiting for the piezometers to recharge. Wells that were gauged were as follows: PZ-7, MW-10, and MW-11. After letting the piezometers recharge, groundwater samples were taken immediately. An access agreement was signed and returned to DERR prior to sampling wells located on the0 McWane Ductile property, which is located to the west of the Site. Groundwater samples were collected from MW-18, MW-19, MW-22, MW-33, PZ-4, PZ-5, and PZ-6. A field duplicate was collected from MW-18. VOC water samples were preserved with HCl and metal water samples were preserved with HNO3. All samples were placed in a cooler filled with ice after collection. Scribe was used to print labels and chain-of-custody (CoC) for the samples. Samples were packaged and shipped as environmental samples via chain-of-custody to an EPA registered CLP laboratory and analyzed for VOCs, SVOCs, and Metals using EPA approved methods SW-846 8260C, SW-846 8270D, and SW-846 6010D, respectively. All samples described in the work plan were taken during this sampling event. Photos from the sampling event can be seen below. 2 Photo 1: Groundwater sampling at MW-19 @ 0900 on 9/29/21 with Wes, Tom, and Chris. 3 Photo 2 and 3: Groundwater Sampling at MW-22 @ 1015 on 9/29/21 with Wes, Chris, and Tom. 4 Photo 4 and 5: Groundwater Sampling at MW-33 @ 1145 on 9/29/21 with Wes, Chris, and Tom. 5 Photo 6: Groundwater Sampling at MW-33 @ 1310 on 9/29/21 with Wes. 6 Photo 7: Groundwater Sampling at PZ-4 @ 0900 on 9/30/21 with Chris. 7 Photo 8: Groundwater Sampling at PZ-4 @ 1040 on 9/30/21 with Chris and Hannah. 8 Photo 9: Groundwater Sampling at PZ-4 @ 1140 on 9/30/21. 9 Photo 10: MW-16 documentation of damage done to MW-16. Potentially from excavator during soil sampling earlier in September. Sampling Results Report 3220 South Solvents – UTD009087655 24 APPENDIX E CONSENT FOR ACCESS TO PROPERTY FORM Sampling Results Report 3220 South Solvents – UTD009087655 25 APPENDIX F GROUNDWATER SAMPLE LABORATORY ANALYTICAL PACKAGE Sampling Results Report 3220 South Solvents – UTD009087655 26 APPENDIX G CHAIN-OF-CUSTODY AND SHIPPING DOCUMENTATION Sampling Results Report 3220 South Solvents – UTD009087655 27 APPENDIX H DERR Historical Data Monitoring Well ID:MW #1 MW #10 MW #12 MW #14 MW #2 MW #29 MW #3 MW #30 MW #31 MW #32 MW #5 MW #9 Traffic Number:MH0AJ2 Q MH0AK2 Q MH0AK3 Q MH0AK1 Q MH0AJ1 Q MH0AJ8 Q MH0AJ4 Q MH0AJ9 Q MH0AJ3 Q MH0AJ7 Q MH0AJ5 Q MH0AJ6 Q Analyte 2020 SCDM Benchmark Value (mg/kg)Aluminum --22400 18600 1520 894 14000 45400 19100 16900 1240 3730 103 J 3890Antimony31.3 60.0 UJ 60.0 UJ 60.0 UJ 60.0 UJ 60.0 UJ 60.0 UJ 60.0 UJ 60.0 UJ 60.0 UJ 60.0 UJ 60.0 UJ 60.0 UJArsenic39.1 35.5 278 56.1 46.0 21.4 34.3 206 41.1 10.0 U 11.5 10.0 U 74.9Barium15600585301200U200U375852812362200U200U200U200 UBeryllium1562.1 J 1.3 J 5.0 U 5.0 U 1.8 J 3.5 J 1.7 J 1.5 J 0.37 J 5.0 U 5.0 U 0.31 JCadmium39.1 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 UCalcium--1130000 710000 152000 597000 1110000 1260000 898000 690000 742000 363000 181000 408000Chromium23550.2 40.5 9.3 J 5.1 J 32.8 84.5 35.8 38.2 2.4 J 25.0 10.0 U 8.0 JCobalt23.5 26.5 J 9.6 J 2.7 J 50.0 U 15.0 J 34.2 J 11.0 J 12.5 J 50.0 U 3.0 J 50.0 U 1.3 JCopper313085.5 17.2 J 85.5 25.0 U 38.6 66.4 33.4 53.8 25.0 U 2.2 J 25.0 U 3.0 JIron--79500 25300 7680 2680 47900 68000 55000 45300 5010 4950 268 5880Lead400**59.1 23.5 16.9 10.0 U 34.7 109 93.0 25.6 2.8 J 2.1 J 10.0 U 9.1 JMagnesium--134000 620000 537000 117000 130000 119000 91200 316000 54300 326000 60300 58600Manganese1100013406601941711310183058163026210358.2 158Nickel156010343.4 27.7 J 19.0 J 66.3 121 46.4 45.0 4.9 J 10.1 J 1.1 J 13.0 JPotassium--13600 118000 85300 38600 11500 32500 15600 53300 9800 107000 5920 24600Selenium39135.0 U 35.0 U 35.0 U 35.0 U 35.0 U 35.0 U 35.0 U 35.0 U 35.0 U 35.0 U 35.0 U 35.0 USilver39110.0 U 10.0 U 1.0 J 0.80 J 10.0 U 10.0 U 10.0 U 10.0 U 10.0 U 1.0 J 10.0 U 10.0 USodium--53200 878000 7920000 1220000 55100 139000 117000 396000 51800 10600000 58400 1160000Thallium0.78 2.4 J 25.0 U 25.0 U 2.7 J 2.9 J 1.6 J 2.1 J 1.8 J 1.8 J 25.0 U 25.0 U 1.6 JVanadium39458.9 37.7 J 39.9 J 5.3 J 41.5 J 86.9 47.8 J 47.3 J 2.8 J 43.8 J 50.0 U 10.2 JZinc2350051013111224.9 J 404 346 404 148 35.2 J 31.4 J 6.9 J 38.7 J Hardness --3200 2680 1950 3180 3580 2650 3030 2070 2250 700 1260 *Superfund Chemical Data Matrix 10/2020 Q = Qualifier J, blank = detected by the laboratory ** = Regional Screening Level, 10/2020 U, UJ, R = Undetected A bolded red value indicates the concentration is equal to or greater than the threshold value listed in the SCDM Benchmark Value columns . Table 1: Groundwater Inorganics Results for Reilly Tar 2017 MW #1 MW #10 MW #12 MW #14 MW #13 MW #2 MW #29 MW #3 MW #30 MW #31 MW #32 MW #4 MW #5 MW #9 H0AJ2 Q H0AK2 Q H0AK3 Q H0AK1 Q H0AK0 Q H0AJ1 Q H0AJ8 Q H0AJ4 Q H0AJ9 Q H0AJ3 Q H0AJ7 Q H0AK4 Q H0AJ5 Q H0AJ6 Q Analyte Cancer Risk Non-cancer Risk 1,4-Dichlorobenzene 14.4 1400 0.22 J 25 U 100 U 50 U 0.5 U 0.29 J 5.0 U 0.50 U 5 U 2.5 U 130 U 0.5 U 0.5 U 13 U Acetone --1800 1.3 J 250 U 1000 U 69 J 1.2 J 1.3 J 6.1 J 1.9 J 6.1 J 25 U 240 J 7.1 5 U 130 U Benzene 1.42 80.2 0.5 U 620 900 530 0.73 0.5 U 5.0 U 0.50 U 5 U 25 820 0.5 U 0.5 U 95 Carbon disulfide --2010 0.5 U 25 U 100 U 50 U 0.5 U 0.5 U 5.0 U 0.50 U 5 U 2.5 U 130 U 1.7 0.5 U 13 U Chlorobenzene 100 401 0.5 U 25 U 100 U 50 U 0.5 U 0.5 U 5.0 U 0.50 U 5 U 2.5 U 130 U 0.74 0.5 U 13 U Chloromethane ----0.5 U 25 U 100 U 50 U 0.5 U 0.5 U 5.0 U 0.50 U 5 U 2.5 U 130 U 0.27 J 0.5 U 13 U Ethylbenzene 7.08 2010 1 150 55 J 93 1.1 1.1 5.0 U 0.39 J 5 U 2.5 U 57 J 0.5 U 0.52 18 Isopropylbenzene ----1.8 25 U 100 U 50 U 0.5 U 1.9 5.0 U 0.48 J 5 U 19 130 U 0.5 U 0.15 J 13 U m,p-Xylene --4010 0.5 U 120 110 240 0.96 0.11 J 5.0 U 0.14 J 5 U 23 150 0.5 U 0.5 U 39 Methylene chloride 12.5 120 0.5 U 25 U 100 U 50 U 0.5 U 0.5 U 5.0 U 0.50 U 5 U 2.5 U 130 U 0.18 J 0.5 U 13 U o-Xylene --4010 0.41 J 20 J 66 J 130 0.58 0.4 J 5.0 U 0.50 U 5 U 81 81 J 0.5 U 0.5 U 22 Toluene 1000 1600 0.2 J 6 J 230 590 0.53 0.22 J 5.0 U 0.50 U 5 U 8.9 270 0.5 U 0.11 J 34 *Superfund Chemical Data Matrix 10/2020 Q = Qualifier J, blank = detected by the laboratory ** = Regional Screening Level, 10/2020 U, UJ, R = Undetected A bold value indicates the concentration is equal to or greater than the non-cancer threshold value listed in the SCDM Benchmark Value column. A bolded red value indicates the concentration is equal to or greater than the cancer risk threshold value listed in the SCDM Benchmark Value columns . Table 2: Groundwater Volatile Organic Compounds for Reilly Tar 2017 Monitoring Well ID: Traffic Number:2020 SCDM Benchmark Value (µg/L) MW #1 MW #10 MW #12 MW #14 MW #13 MW #2 MW #29 MW #3 MW #30 MW #31 MW #32 MW #5 MW #9 H0AJ2 Q H0AK2 Q H0AK3 Q H0AK1 Q H0AK0 Q H0AJ1 Q H0AJ8 Q H0AJ4 Q H0AJ9 Q H0AJ3 Q H0AJ7 Q H0AJ5 Q H0AJ6 Q Analyte Cancer Risk Non-cancer Risk 1,1'-Biphenyl ----6.2 2.6 J 9.6 33 6.7 8.3 5.0 U 5.0 U 5.0 U 49 16 5.0 U 5.0 U2-Chlorophenol ----5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 R 5.0 U 1.8 J2-Methylnaphthalene --80.2 5.0 U 5.0 U 110 J 340 J 1.7 J 2.0 J 5.0 U 5.0 U 5.0 U 2.1 J 1000 U 5.0 U 652-Methylphenol ----10 U 6.0 J 130 1000 J 10 U 10 U 10 U 10 U 10 U 10 U 6000 10 U 320 J2,4-Dimethylphenol --401 5.0 U 28 710 1200 3.9 J 5.0 U 5.0 U 5.0 U 3.7 J 5.0 U 5000 5.0 U 31004-Methylphenol --2.01 10 U 3.8 J 200 J 2200 10 U 10 U 10 U 10 U 10 U 10 U 10 U 10 U 60Acenaphthene--1200 220 260 110 J 290 J 120 300 5.0 UJ 220 58 380 1000 U 98 390Acenaphthylene----5.0 U 3.5 J 5.0 U 19 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 8.6 9.1 1.5 J 5.0 UAcetophenone----10 U 10 U 10 U 10 U 10 U 10 U 10 U 10 U 10 U 1.8 J 10 U 10 U 10 UAnthracene--6020 2.8 J 5.0 U 5.0 U 57 5.0 U 4.0 J 5.0 U 6.4 5.0 U 14 5.6 4.8 J 8.0Benzaldehyde----10 U 10 U 10 U 10 U 10 U 10 U 10 U 10 U 10 U 10 U 10 U 10 U 1.8 JBenzo(a)anthracene --0.25 5.0 U 5.0 U 1.3 J 10 J+5.0 U 5.0 U 5.0 U 1.3 J 1.6 J 1.6 J 5.0 U 1.6 J 5.0 UBenzo(a)pyrene 0.02 6.02 5.0 UJ 5.0 U 5.0 R 4.8 J+5.0 UJ 5.0 UJ 1.4 J 5.0 UJ 2.3 J-1.3 J 5.0 U 5.0 U 5.0 RBenzo(b)fluoranthene ----5.0 UJ 5.0 U 5.0 R 7.4 J+5.0 UJ 5.0 UJ 1.4 J 5.0 UJ 2.5 J-1.3 J 5.0 U 5.0 U 5.0 RBenzo(g,h,i)perylene ----5.0 UJ 5.0 U 5.0 R 5.0 R 5.0 UJ 5.0 UJ 5.0 U 5.0 UJ 1.5 J-5.0 U 5.0 U 5.0 U 5.0 RBenzo(k)fluoranthene 2.5 --5.0 UJ 5.0 U 5.0 R 2.1 J+5.0 UJ 5.0 UJ 5.0 U 5.0 UJ 5.0 UJ 5.0 U 5.0 U 5.0 U 5.0 RCarbazole----10 UJ 10 UJ 27 J 10 UJ 4.4 J 1.9 J 10 UJ 5.1 J 10 UJ 190 27 J 2.9 J 10 UJChrysene25.1 --5.0 U 5.0 U 1.3 J 7.5 J+5.0 U 5.0 U 1.4 J 5.0 U 2.2 J 1.8 J 5.0 U 1.4 J 5.0 UDibenzofuran--20 19 7.0 23 600 U 16 26 5.0 U 12 5.0 U 160 26 21 5.0 UFluoranthene----1.8 J 10 U 8.0 J 27 2.1 J 2.4 J 1.5 J 12 3.0 J 12 3.5 J 15 10 UFluorene--802 16 2.3 J 29 600 U 9.7 21 5.0 U 22 5.0 U 140 16 27 26Indeno(1,2,3-cd)pyrene 0.25 --5.0 UJ 5.0 U 5.0 R 5.0 R 5.0 UJ 5.0 UJ 5.0 U 5.0 UJ 1.4 J-0.96 J 5.0 U 5.0 U 5.0 RNaphthalene0.6 401 5.0 U 9.9 1600 6400 27 5.0 U 5.0 U 5.0 U 5.0 U 580 4400 5.0 U 1400Phenanthrene----5.0 U 23 39 180 J 23 5.0 U 5.0 U 5.0 U 1.9 J 78 23 5.0 U 39Phenol--6020 10 U 9.0 J 41 4000 10 U 10 U 10 U 10 U 10 U 10 U 17000 10 U 34Pyrene--602 1.9 J 5.0 U 8.1 600 U 1.8 J 2.7 J 2.0 J 12 3.6 J 5.0 U 3.9 J 14 5.0 U *Superfund Chemical Data Matrix 10/2020 Q = Qualifier J, blank = detected by the laboratory ** = Regional Screening Level, 10/2020 U, UJ, R = Undetected A bold value indicates the concentration is equal to or greater than the non-cancer threshold value listed in the SCDM Benchmark Value column. A bolded red value indicates the concentration is equal to or greater than the cancer risk threshold value listed in the SCDM Benchmark Value columns . Table 3: Groundwater Semivolatile Organic Compounds and Polycyclic Aromatic Hydrocarbons for Reilly Tar 2017 Monitoring Well ID: Traffic Number:2020 SCDM Benchmark Value (µg/L) Monitoring Well ID:MW #11 MW #12 MW #13 MW #14 MW #2 MW #29 MW #3 MW #30 MW #31 MW #32 MW #5 MW #6 MW #9 Traffic Number:MH0AL2 Q MH0AL3 Q MH0AL4 Q MH0AL5 Q MH0AL6 Q MH0AL7 Q MH0AL8 Q MH0AL9 Q MH0AM0 Q MH0AM1 Q MH0AM2 Q MH0AM3 Q MH0AM4 Q Analyte 2020 SCDM Benchmark Value (mg/kg)Aluminum --1280 J 234 J 2100 J 1070 J 7390 J 5340 J 7480 J 1990 J 1170 J 3240 J 1940 J 2530 J 5320 JAntimony31.3 60.0 U 4.3 J 60.0 U 60.0 U 60.0 U 60.0 U 3.0 J 3.1 J 60.0 U 60.0 U 60.0 U 60.0 U 60.0 UArsenic39.1 261 113 99.4 34.8 21.5 15.2 121 11.8 4.2 J 10.4 9.0 J 11.8 47.5Barium1560018.8 J 12.4 J 62.2 J 36.8 J 283 122 J 434 106 J 34.6 J 49.7 J 119 J 129 J 150 JBeryllium1560.87 J 5.0 U 0.45 J 0.44 J 1.6 J 0.86 J 1.5 J 0.40 J 5.0 U 0.50 J 0.43 J 0.50 J 0.81 JCalcium--455000 395000 503000 624000 800000 780000 861000 418000 675000 439000 527000 541000 492000Chromium23510.0 UJ 6.2 J 4.8 J 5.1 J 16.2 J 10.5 J 13.2 J 4.8 J 91.9 J 16.1 J 3.1 J 3.9 J 12.1 JCobalt23.5 21.1 J 50.0 U 2.4 J 50.0 U 10.2 J 4.7 J 7.1 J 1.8 J 50.0 U 50.0 U 50.0 U 50.0 U 50.0 UIron--51300 J 15700 J 10700 J 2820 J 39400 J 8370 J 26100 J 5760 J 2680 J 3150 J 4810 J 6610 J 7060 JLead400*5.6 J 10.0 U 19.7 5.5 J 35.6 24.7 110 8.2 J 8.6 J 13.8 15.1 15.6 20.5Magnesium--1740000 672000 237000 146000 146000 78400 97800 174000 47100 167000 201000 203000 65200Manganese1100041512714045886130551536963.1 104 488 516 225Nickel156046.2 17.2 J 17.1 J 13.3 J 50.2 17.4 J 27.9 J 9.0 J 52.8 5.5 J 4.8 J 6.9 J 7.5 JPotassium--138000 113000 45700 91400 8560 19100 11200 26200 9040 63300 23100 23300 24000Selenium3916.8 J 12.9 J 35.0 U 35.0 U 35.0 U 35.0 U 35.0 U 35.0 U 35.0 U 37.8 7.7 J 35.0 U 20.0 JSodium--5970000 12100000 2010000 1270000 59600 119000 130000 99500 65700 6370000 313000 313000 1400000Thallium0.78 25.0 U 25.0 U 25.0 U 25.0 U 25.0 U 25.0 U 25.0 U 25.0 U 25.0 U 25.0 U 25.0 U 25.0 U 4.5 JVanadium3948.1 J 14.0 J 5.9 J 50.0 U 23.5 J 12.1 J 25.3 J 4.7 J 50.0 U 24.0 J 50.0 U 5.9 J 13.4 JZinc2350028.8 J 43.6 J 29.3 J 53.5 J 240 70.6 433 29.6 J 93.1 50.1 J 54.4 J 76.5 54.8 J *Superfund Chemical Data Matrix 10/2020 Q = Qualifier J, blank = detected by the laboratory ** = Regional Screening Level, 10/2020 U, UJ, R = Undetected A bold value indicates the concentration is equal to or greater than the non-cancer threshold value listed in the SCDM Benchmark Value column. A bolded red value indicates the concentration is equal to or greater than the cancer risk threshold value listed in the SCDM Benchmark Value columns . Table 4: Groundwater Inorganics for Reilly Tar 2018 MW #1 MW #11 MW #12 MW #13 MW #14 MW #2 MW #29 MW #3 MW #30 MW #31 MW #32 MW #5 MW #6 MW #9 H0AL1 Q H0AL2 Q H0AL3 Q H0AL4 Q H0AL5 Q H0AL6 Q H0AL7 Q H0AL8 Q H0AL9 Q H0AM0 Q H0AM1 Q H0AM2 Q H0AM3 Q H0AM4 Q Analyte Cancer Risk Non-Cancer RiskAcetone--1800 10 U 10 U 6.5 J+10 U 10 J+10 U 10 U 10 U 10 U 10 U 200 R 10 U 10 U 10 RBenzene1.42 80.2 5.0 U 5.0 U 1500 J 3.3 J 290 5.0 U 5.0 U 5.0 U 5.0 U 46 2500 J 3.5 J 3.1 J 110 JCarbon disulfide --2010 2.1 J 5.0 U 5.0 U 5.0 U 2.9 J 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 100 R 5.0 U 5.0 U 1.8 JChlorobenzene1004011.5 J 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 5.0 U 100 R 5.0 U 5.0 U 5.0 REthylbenzene7.08 2010 5.0 U 5.0 U 76 4.2 J 70 5.0 U 5.0 U 5.0 U 5.0 U 290 170 J 5.4 5.7 21 JIsopropylbenzene----5.0 U 5.0 U 2.6 J 5.0 U 3.5 J 5.0 U 5.0 U 5.0 U 5.0 U 26 100 R 5.0 U 5.0 U 1.5 Jm,p-Xylene --4010 5.0 U 5.0 U 170 3.7 J 190 5.0 U 5.0 U 5.0 U 5.0 U 190 460 J 1.2 J 1.3 J 43 Jo-xylene --4010 5.0 U 5.0 U 100 2.2 J 100 5.0 U 5.0 U 5.0 U 5.0 U 170 260 J 1.4 J 1.2 J 24 JToluene100016005.0 U 5.0 U 360 J 2.3 J 350 5.0 U 5.0 U 5.0 U 5.0 U 70 810 J 1.9 J 1.9 J 39 J *Superfund Chemical Data Matrix 10/2020 Q = Qualifier J, blank = detected by the laboratory ** = Regional Screening Level, 10/2020 U, UJ, R = Undetected A bold value indicates the concentration is equal to or greater than the non-cancer threshold value listed in the SCDM Benchmark Value column. A bolded red value indicates the concentration is equal to or greater than the cancer risk threshold value listed in the SCDM Benchmark Value columns . Table 5: Groundwater Volatile Organic Compounds for Reilly Tar 2018 Monitoring Well ID: Traffic Number: 2020 SCDM Benchmark Value (ug/L) MW #11 MW #12 MW #13 MW #14 MW #2 MW #29 MW #3 MW #30 MW #31 MW #32 MW #5 MW #6 MW #9 H0AL2 Q H0AL3 Q H0AL4 Q H0AL5 Q H0AL6 Q H0AL7 Q H0AL8 Q H0AL9 Q H0AM0 Q H0AM1 Q H0AM2 Q H0AM3 Q H0AM4 Q Analyte Cancer Risk Non-Cancer Risk1,1-Biphenyl ----5.0 U 16 16 40 J 1.7 J 5.0 U 5.3 U 5.0 U 91 44 J 4.6 J 2.8 J 202-Chlorophenol ----5.0 U 5.0 U 5.0 U 50 U 5.0 U 5.0 U 5.3 U 5.0 U 6.8 U 50 U 5.0 U 5.0 U 3.5 J2-Methylnaphthalene --80.2 5.0 U 210 31 310 5.0 U 5.0 U 5.3 U 5.0 U 22 440 5.0 U 5.0 U 1002-Methylphenol ----10 U 300 10 U 450 10 U 10 U 11 U 10 U 14 U 5400 2.3 J 10 U 4602,4-Dimethylphenol --401 5.0 U 1300 10 460 5.0 U 5.0 U 5.3 U 5.0 U 6.8 U 5400 20 15 43004-Methylphenol --2.01 10 U 150 10 U 630 10 U 10 U 11 U 10 U 14 U 910 10 U 10 U 110Acenaphthene--1200 5.0 U 170 230 320 190 5.0 U 300 10 600 J 330 190 150 190Acenaphthylene----5.0 U 14 2.6 J 15 J 3.2 J 5.0 U 5.3 5.0 U 9.9 17 J 5.0 U 1.9 J 5.0 UAcetophenone----10 U 10 U 10 U 100 U 10 U 10 U 11 U 10 U 7.2 J 53 J+10 U 10 U 10 UAnthracene--6020 5.0 U 12 5.9 87 3.8 J 1.3 J 16 2.4 J 24 50 U 9.0 8.0 26 J+Benzo(a)anthracene --0.25 5.0 U 5.0 U 3.6 J 18 J 1.9 J 8.7 12 7.0 8.8 50 U 3.9 J 3.9 J 3.2 JBenzo(a)pyrene 0.02 6.02 5.0 U 5.0 U 5.0 U 50 U 2.6 J 15 9.9 9.9 8.8 50 U 5.0 U 2.3 J 1.7 JBenzo(b)fluoranthene ----5.0 U 5.0 U 2.0 J 50 U 2.7 J 16 9.9 11 9.3 50 U 2.6 J 2.8 J 2.2 JBenzo(g,h,i)perylene ----5.0 U 5.0 U 5.0 U 50 U 2.7 J 12 5.0 J 6.5 8.0 50 U 5.0 U 5.0 U 5.0 UBenzo(k)fluoranthene 2.5 --5.0 U 5.0 U 5.0 U 50 U 5.0 U 6.0 4.8 J 3.6 J 3.3 J 50 U 5.0 U 5.0 U 5.0 UCarbazole----10 U 39 13 160 10 U 10 U 6.3 J 10 U 170 26 J 12 9.9 J 51Chrysene25.1 --5.0 U 5.0 U 3.2 J 21 J 2.6 J 12 17 9.2 11 50 U 5.4 5.2 3.7 JDibenzo(a,h)anthracene 0.0251 --5.0 U 5.0 U 5.0 U 50 U 5.0 U 3.2 J 1.7 J 1.8 J 2.0 J 50 U 5.0 U 5.0 U 5.0 UDibenzofuran--20 5.0 U 35 39 120 17 5.0 U 16 5.0 U 250 66 51 38 51Dimethylphthalate----1.9 J 3.0 J 2.6 J 50 U 2.9 J 1.4 J 5.3 U 5.0 U 6.8 U 50 U 3.2 J 1.8 J 3.7 JFluoranthene----10 U 9.2 J 19 68 J 4.9 J 11 40 12 33 100 U 28 25 21Fluorene--802 5.0 U 45 38 160 18 5.0 U 37 5.0 U 210 32 J 58 44 48Indeno(1,2,3-cd)pyrene 0.25 --5.0 U 5.0 U 5.0 U 50 U 1.7 J 9.8 4.3 J 5.6 6.1 J 50 U 5.0 U 5.0 U 5.0 UNaphthalene0.6 401 5.0 U 3600 210 4600 5.0 U 5.0 U 1.7 J 5.0 U 2100 8400 29 21 2500Phenanthrene----5.0 U 45 74 250 5.0 U 5.4 2.3 J 6.8 190 55 1.9 J 1.9 J 69Phenol--6020 10 U 16 1.3 J 580 10 U 10 U 11 U 10 U 1.9 J 770 10 U 10 U 81Pyrene--602 5.0 U 7.8 16 68 4.9 J 14 21 14 31 50 U 24 22 16 *Superfund Chemical Data Matrix 10/2020 Q = Qualifier J, blank = detected by the laboratory ** = Regional Screening Level, 10/2020 U, UJ, R = Undetected A bold value indicates the concentration is equal to or greater than the non-cancer threshold value listed in the SCDM Benchmark Value column. A bolded red value indicates the concentration is equal to or greater than the cancer risk threshold value listed in the SCDM Benchmark Value columns . Table 6: Groundwater Semi-volatile Organic Compounds and Polycyclic Aromatic Hydrocarbons for Reilly Tar 2018 Monitoring Well ID: Traffic Number: 2020 SCDM Benchmark Value (ug/L) Monitoring Well ID: Sample Number: Industrial RSL (mg/kg):Q Q Q Aluminum 1100000 8460 11000 10200Antimony4700.68 J 0.59 J 0.55 JArsenic37.9 9.8 9.0Barium220000153J232J178Beryllium23000.96 1.2 1.0Cadmium--2.2 1.9 2.0Calcium--106000 133000 123000Chromium--14.5 12.7 13.5Cobalt3504.8 J 5.8 5.7Copper4700025.4 27.8 29.5Iron820000166001890017300Lead800126160145Magnesium--14700 15900 15100Manganese26000402378352Nickel--16.9 20.5 20.1Potassium--1620 1920 1830Selenium58003.6 U 3.3 3.3Silver58000.24 J 0.26 J 0.23 JSodium--1170 1400 1330Thallium122.6 U 2.2 U 0.55 JVanadium580034.8 33.3 35.3Zinc350000441423415 Notes: Bolded and Red Detection above 2022 EPA Industrial Soil Benchmark RSL Regional Screening Level J Concentration is Estimated U Analyte was not detected --No MCL or RSL value Q Qualifier Analyte RT-SS-003 RT-SS-006 MH0AL0 Table 7: Soil Inorganics Results for Reilly Tar Landfarm 2017 RT-SS-006DUP MH0AL0DH0AK7 Monitoring Well ID: Sample Number:H0AK6 Q H0AK9 Q Industrial RSL (ug/kg): Analysis: CLP Semivolatiles + PAH SIM 1,1'-Biphenyl 200 130000 200000 11H-Benzo[b]fluorene --670000 950000 13H-Dibenzo[a,h]fluorene --550000 700000 1-Isopropenylnaphthalene --1400 J 1800 J2,4-Dimethylphenol 16000 200000 230000 2-Methylnaphthalene 3000 210000 36000 JN 4H-Cyclopenta[def]phenanthrene --26000 JN 270000 J 4-Methylphenol --130000 J 19000 9-(Cyanomethylene)fluorene --17000 370000 9-Octadecenamide, (Z)---340000 2900 J Acenaphthene 45000 NA 630000 J Acenaphthylene --510000 2600 J Anthracene 230000 1500 J 760000 Benz[a]anthracene, 7-methyl---560000 72000 Benzo(a)anthracene 21 23000 260000 Benzo(a)pyrene 2.1 210000 95000 Benzo(a)pyrene 4,5-oxide --65000 270000 Benzo(b)fluoranthene 21 240000 53000 Benzo(g,h,i)perylene --23000 47000 Benzo(k)fluoranthene 210 43000 64000 Benzo[b]triphenylene --57000 19000 Benzo[e]pyrene --6700 280000 J Benzo[j]fluoranthene --210000 140000 Carbazole --48000 15000 JN Chrysene 2100 13000 JN 73000 JN Dibenzo(a,h)anthracene --33000 JN NA Dibenzo[def,mno]chrysene --12000 JN 5200 JN Dibenzofuran 1200 NA 6900 JNDibenzofuran, 4-methyl---6800 JN 5900 JN Fluoranthene 30000 5300 JN NA Fluoranthene, 2-methyl---9700 JN 6900 JN Fluorene 30000 6200 JN NA Indeno(1,2,3-cd)pyrene 21 14000 JN 29000 JN Naphthalene --26000 JN 54000 JNNaphthalene, 1,3-dimethyl---43000 JN NA Naphthalene, 1,4-dimethyl---12000 JN 26000 JNNaphthalene, 1,5-dimethyl---NA NA Naphthalene, 1,5-dimethyl---7800 JN 29000 JN Naphthalene, 1,6-dimethyl---NA 23000 JN Naphthalene, 1-methyl---22000 JN 28000 JNNaphthalene, 2,3,6-trimethyl---NA NANaphthalene, 2-ethyl---13000 JN 22000 JNN-Nitrosodiphenylamine 470 20000 JN 17000 JN Pentaphene --51000 JN 11000 JN Perylene --NA 14000 JNPerylene--NA 110000 JN Phenanthrene --94000 JN NA Phenol 250000 82000 JN 110000 JN Picene --NA 18000 JN Pyrene 23000 14000 JN 6200 JN Pyrene, 1-methyl---5200 JN NA Triphenylene, 2-methyl---4600 JN 8700 JN Monitoring Well ID: Sample Number:H0AK5 Q H0AK8 Q Screening Level Benchmarks: Industrial RSL (ug/kg): Analysis: CLP Volatiles1H-Indene, 1-methyl---NA 460 JN 2-Methylindene --330 JN 650 JN Benzofuran, 2-methyl---760 JN 1000 JN Acetone 670000 63 J 36 J Benzene 5.1 12 J 19 J Benzene, (1-methyl-2-cyclopropen-1-yl)---480 JN NA Benzene, 1,2,3-trimethyl-2000 540 JN 280 JNBenzene, 1,2,4-trimethyl-1800 NA 710 JN 1H-Indene, 2,3-dihydro-4-methyl---260 JN 320 JN Benzene, 1-ethyl-3-methyl---170 JN 190 JN Benzene, 2-ethyl-1,4-dimethyl---79 JN NA Benzo[b]thiophene --400 JN NA Benzofuran, 7-methyl---320 JN 400 JN Carbon disulfide 3500 5.7 J 6.4 J 2,4-Dimethylstyrene --520 JN 1000 JN Ethylbenzene 25 26 J 29 J Indan, 1-methyl---290 JN 350 JN Indene --1500 JN 2300 JN m,p-Xylene --470 610 Mesitylene --210 JN NA Naphthalene, 1-methyl-73 1300 JN 480 JN o-Xylene 2800 260 340 Styrene 35000 100 140 Tetrachloroethene 100 8.6 J 9.9 J Notes: Bolded and Red Detection above 2022 EPA MCL Benchmark RSL Regional Screening Level J Concentration is Estimated U Analyte was not detected JN Analyte has been "tentatively identified" and the value is the approximate concentration in the sample NA Not analyzed for --No MCL or RSL value Q Qualifier Table 8: Soil Organics Results for Reilly Tar Landfarm 2017 RT-SS-002 RT-SS-004 Analyte Analyte RT-SS-004RT-SS-001 Sampling Results Report 3220 South Solvents – UTD009087655 28 APPENDIX I START TRIP REPORT ENCLOSURE 4 1 February 17, 2022 Mr. Martin McComb On-Scene Coordinator U.S. Environmental Protection Agency, Region 8 1595 Wynkoop Street Denver, Colorado 80202 Subject: Trip Report – Revision 0 Reilly Coal Tar Removal Assessment, Provo, Utah U.S. EPA Region 8 START 5, Contract No. 68HE0820D0001 Task Order No. 68HE0820F0071 Task Monitor: Marty McComb, EPA On-Scene Coordinator Dear Mr. McComb: The Tetra Tech Inc. (Tetra Tech) Superfund Technical Assessment and Response Team (START) is submitting this Trip Report – Revision 0 for the Reilly Coal Tar Removal Assessment (the Site) in Provo, Utah County, Utah for your review and comment. This report summarizes field activities conducted at the Site during the September 8, 2021 investigation and sampling event. The scope of this project was to provide technical assistance and sampling support to characterize the extent and magnitude of contamination in subsurface soils on the 23-acre southern portion of the Site. This trip report summarizes site activities and findings, including site background and physical location, site activities, analytical results, and conclusions. Enclosure 1 presents the photolog; Enclosure 2 presents the site figures; Enclosure 3 contains tables; and Enclosure 3 presents the verified laboratory data package. SITE BACKGROUND AND PHYSICAL LOCATION The Site is located at 2555 South Industrial Parkway, Provo, Utah County, Utah (Figure 1). The geographic coordinates for the approximate center of the site are 40.199167° north latitude, - 111.630154° west longitude. The Site is an abandoned coal tar distillery that operated from 1924 to 2002. Land use in the area is largely industrial. The Ironton Canal constitutes the northern boundary of the Site and discharges into Spring Creek and Utah Lake’s Provo Bay, approximately 1.5 miles west of the Site. The southern portion of the Site is now a seasonal wetland, and groundwater tends to flow westward beneath a nearby industrial facility. SITE ACTIVITES Environmental Restoration LLC (ER) and START conducted investigation and soil sampling activities 2 on September 8, 2021. As directed by the U.S. Environmental Protection Agency (EPA), ER conducted the excavation of fifteen test pits to the maximum depth the excavator could reach, between 10 feet below ground surface (bgs) to 20 feet bgs. Test pit locations were selected based on site conditions and accessibility to safely maneuver and operate the excavator. Test pit locations are identified on Figure 2 and 3. During excavation activities, START photo documented excavated soil conditions and used a MultiRAE Pro to screen VOC concentrations in soil throughout investigation activities. Headspace monitoring results are summarized in Table 1. START identified the presence of coal tar in Test Pit (TP) 01, 14, and 15. The remaining test pits did not reveal the presence of coal tar throughout the soil profile of the test pit. START collected a grab subsurface sample from three test pits; two test pits that contained coal tar (TP01 and TP14) and one test pit without the presence of coal tar as a background (TP13). After completing the documentation of test pit locations, all soil was returned to the original test pit to match the surrounding grade. ANALYTICAL RESULTS The three subsurface soil samples and associated QC samples collected during the site activities were analyzed by ALS Laboratory in Fort Collins, Colorado. Samples were analyzed for total petroleum hydrocarbons gasoline range organics (TPH-GRO), total petroleum hydrocarbons diesel range organics (TPH-DRO), total petroleum hydrocarbons oil range organics (TPH-ORO), Semi-volatile organic compound s (SVOCs), Target Analyte List (TAL) Metals, and VOCs. Analytical results were compared to EPA Removal Management Level (RML) for industrial soil with a target excess cancer risk level of 10-4 and a target hazard quotient of 1.0 for non-carcinogens (EPA 2021a). Analytical results were also compared to EPA regional screening levels (RSL) for industrial soil with a target excess cancer risk level of 10-6 and a target hazard quotient of 1.0 (EPA 2021b). In three of the samples, there were exceedances of the EPA RMLs for TPH-DRO, TPH-ORO, TPH- GRO, 2-methylnaphthalene, benzo(a)pyrene, dibenzofuran, and naphthalene. Additionally there were exceedances of the EPA RSLs for 1-methylnaphthalene, benz(a)anthracene, benzo(b)fluoranthene, benzo(k)fluoranthene, dibenz(a,h)anthracene, indeno(1,2,3-cd)pyrene, benzene, ethylbenzene, and arsenic. Table 2 summarizes the analytical results for the subsurface soil samples. Subsurface soil sample locations with exceedances are identified on Figure 3. Table 1 lists the readings documented from the periodic headspace air monitoring for VOCs. Four of the readings were above the short-term exposure limit (STEL) of 5.0 ppm and the PEL of 12 ppm. Headspace air monitoring sample locations with exceedances are identified on Figure 2. CONCLUSIONS START personnel collected a subsurface soil samples at three separate test pit locations (TP01, TP13, and TP14). The presence of coal tar was identified in three test pits located in the northwest area of the investigated area (TP01, TP14, and TP15. DATA MANAGEMENT START personnel collected mobile data using ESRI’s Survey123 mobile data collection application to 3 document subsurface soil information, and to collect general photos and other site observations. All subsurface soil sample data and analytical results were loaded into a Scribe database. If you have any questions or comments regarding this trip report, please call me at (804) 357-6775. Sincerely, Madison Ericson START V Project Manager Enclosures (4) Enclosure 1 – Photolog Enclosure 2 – Site Figures Enclosure 3 – Table Enclosure 4 – Laboratory Analytical Packages cc: Di Di Fung, START Region 8 Program Manager Clayton Longest, START Region 8 Document Control Coordinator ENCLOSURE 4 LABORATORY ANALYTICAL PACKAGES