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HomeMy WebLinkAboutDERR-2024-010980August 13, 2024 Section 8 CS 40.2354/-110.3688 Duchesne, UT Re: Section 311 Notification for new Facility, KMA-Section 8 Compressor Station, UT ID#: UT011539 To Whom It May Concern, We are providing notification that the following facility has become subject to the requirements of EPCRA 311 for the chemicals: Triethylene Glycol, Antifreeze (Jefcool E105N; ethylene glycol based), Methanol, Natural Gas Condensate, Oily water, Amine Nalco Champion qualifier, Petroleum Hydrocarbons - Engine Lube Oil (New & Used) at the following facilities: Section 8 CS 40.2354/-110.3688 Duchesne, UT Tier II State ID: # UT011539 Natural Gas Condensate generation is contingent on completing construction and commissioning of a downstream facility. Thus, condensate generation is not anticipated until mid-September or October. If you have any questions, please reach out to Stacey Malerba at (303) 601-8497 or stacey_malerba@kindermorgan.com. Thank you, Attachment: Safety Data Sheet Product Name: MOBIL PEGASUS 805 Revision Date: 26 Nov 2019 Page 1 of 11 ______________________________________________________________________________________________________________________ SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: MOBIL PEGASUS 805 Product Description: Base Oil and Additives Product Code: 201525106010, 602466-00, 97D936 Intended Use: Natural gas engine oil COMPANY IDENTIFICATION Supplier:EXXON MOBIL CORPORATION 22777 Springwoods Village Parkway Spring, TX 77389 USA 24 Hour Health Emergency 609-737-4411 Transportation Emergency Phone 800-424-9300 or 703-527-3887 CHEMTREC Product Technical Information 800-662-4525 MSDS Internet Address www.exxon.com, www.mobil.com SECTION 2 HAZARDS IDENTIFICATION This material is not hazardous according to regulatory guidelines (see (M)SDS Section 15). Other hazard information: HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200. PHYSICAL / CHEMICAL HAZARDS No significant hazards. HEALTH HAZARDS High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin, or respiratory irritation. ENVIRONMENTAL HAZARDS No significant hazards. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 Product Name: MOBIL PEGASUS 805 Revision Date: 26 Nov 2019 Page 2 of 11 ______________________________________________________________________________________________________________________ NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS This material is defined as a mixture. Hazardous Substance(s) or Complex Substance(s) required for disclosure Name CAS# Concentration* GHS Hazard Codes 2,5-FURANDIONE, DIHYDRO-, POLYBUTENYL DERIVS. REACTION PRODUCTS WITH TETRAETHYLENEPENTAMINE 68583-75-5 1 - < 5% H413 2-PENTANOL, 4-METHYL-, HYDROGEN PHOSPHORODITHIOATE, ZINC SALT 2215-35-2 0.1 - < 1% H303, H315, H318, H401, H411 BENZENE PROPANOIC ACID, 3,5-BIS(1,1- DIMETHYLETHYL)-4-HYDROXY-, C7-9 BRANCHED ALKYL ESTERS 125643-61-0 1 - < 5% H413 BENZENE SULFONIC ACIDS, C10-16 ALKYL DERIVS., CA SALTS 68584-23-6 0.1 - < 1% H317 BENZENESULFONIC ACID, MONO-C16-24-ALKYL DERIVS. CALCIUM SALTS 70024-69-0 0.1 - < 1% H317 SULFONIC ACIDS, PETROLEUM, CALCIUM SALTS 61789-86-4 0.1 - < 1% H317 * All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. As per paragraph (i) of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity and exact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact percentage composition will be provided to health professionals, employees, or designated representatives in accordance with applicable provisions of paragraph (i). SECTION 4 FIRST AID MEASURES INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION First aid is normally not required. Seek medical attention if discomfort occurs. Product Name: MOBIL PEGASUS 805 Revision Date: 26 Nov 2019 Page 3 of 11 ______________________________________________________________________________________________________________________ SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight Streams of Water FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Aldehydes, Incomplete combustion products, Oxides of carbon, Smoke, Fume, Sulfur oxides FLAMMABILITY PROPERTIES Flash Point [Method]: >245°C (473°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. US regulations require reporting releases of this material to the environment which exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National Response Center can be reached at (800)424-8802. PROTECTIVE MEASURES Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended. Product Name: MOBIL PEGASUS 805 Revision Date: 26 Nov 2019 Page 4 of 11 ______________________________________________________________________________________________________________________ SPILL MANAGEMENT Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. SECTION 7 HANDLING AND STORAGE HANDLING Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present (e.g., during switch-loading operations). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator. STORAGE The type of container used to store the material may affect static accumulation and dissipation. Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosols can occur the following are recommended: 5 mg/m³ - ACGIH TLV (inhalable fraction), 5 mg/m³ - OSHA PEL. NOTE: Limits/standards shown for guidance only. Follow applicable regulations. No biological limits allocated. ENGINEERING CONTROLS Product Name: MOBIL PEGASUS 805 Revision Date: 26 Nov 2019 Page 5 of 11 ______________________________________________________________________________________________________________________ The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventilation. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION Product Name: MOBIL PEGASUS 805 Revision Date: 26 Nov 2019 Page 6 of 11 ______________________________________________________________________________________________________________________ Physical State: Liquid Color: Amber Odor: Characteristic Odor Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15.6 °C): 0.89 Flammability (Solid, Gas): N/A Flash Point [Method]: >245°C (473°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 288°C (550°F) Decomposition Temperature: N/D Vapor Density (Air = 1): > 2 at 101 kPa Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C Evaporation Rate (n-butyl acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 130 cSt (130 mm2/sec) at 40 °C | 13.5 cSt (13.5 mm2/sec) at 100°C [ASTM D 445] Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: N/D Melting Point: N/A Pour Point: -12°C (10°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt SECTION 10 STABILITY AND REACTIVITY REACTIVITY: See sub-sections below. STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS Hazard Class Conclusion / Remarks Inhalation Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material.Negligible hazard at ambient/normal handling temperatures. Product Name: MOBIL PEGASUS 805 Revision Date: 26 Nov 2019 Page 7 of 11 ______________________________________________________________________________________________________________________ Ingestion Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Skin Corrosion/Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on assessment of the components. Eye Serious Eye Damage/Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on assessment of the components. Sensitization Respiratory Sensitization: No end point data for material. Not expected to be a respiratory sensitizer. Skin Sensitization: No end point data for material. Not expected to be a skin sensitizer. Based on assessment of the components. Aspiration: Data available.Not expected to be an aspiration hazard. Based on physico- chemical properties of the material. Germ Cell Mutagenicity: No end point data for material. Not expected to be a germ cell mutagen. Based on assessment of the components. Carcinogenicity: No end point data for material. Not expected to cause cancer. Based on assessment of the components. Reproductive Toxicity: No end point data for material. Not expected to be a reproductive toxicant. Based on assessment of the components. Lactation: No end point data for material.Not expected to cause harm to breast-fed children. Specific Target Organ Toxicity (STOT) Single Exposure: No end point data for material. Not expected to cause organ damage from a single exposure. Repeated Exposure: No end point data for material. Not expected to cause organ damage from prolonged or repeated exposure. Based on assessment of the components. TOXICITY FOR SUBSTANCES NAME ACUTE TOXICITY 2-PENTANOL, 4-METHYL-, HYDROGEN PHOSPHORODITHIOATE, ZINC SALT Oral Lethality: LD50 2230 mg/kg (Rat) OTHER INFORMATION For the product itself: Component concentrations in this formulation would not be expected to cause skin sensitization, based on tests of the components, this formulation, or similar formulations. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. Sulfonates: This product contains sulfonates which have been reported to cause skin sensitization. The following ingredients are cited on the lists below: None. Product Name: MOBIL PEGASUS 805 Revision Date: 26 Nov 2019 Page 8 of 11 ______________________________________________________________________________________________________________________ --REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC SECTION 12 ECOLOGICAL INFORMATION The information given is based on data for the material, components of the material, or for similar materials, through the application of bridging principals. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability. SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. Protect the environment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents, brake fluids or coolants. REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used product may be regulated. Product Name: MOBIL PEGASUS 805 Revision Date: 26 Nov 2019 Page 9 of 11 ______________________________________________________________________________________________________________________ Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (DOT): Not Regulated for Land Transport LAND (TDG): Not Regulated for Land Transport SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code Marine Pollutant: No AIR (IATA): Not Regulated for Air Transport SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance with OSHA HazCom 2012, 29 CFR 1910.1200. Listed or exempt from listing/notification on the following chemical inventories: AICS, DSL, ENCS, ISHL, KECI, PICCS, TCSI, TSCA Special Cases: Inventory Status IECSC Restrictions Apply SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302 SARA (311/312) REPORTABLE GHS HAZARD CLASSES: None. SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification requirements of the SARA 313 Toxic Release Program. The following ingredients are cited on the lists below: Product Name: MOBIL PEGASUS 805 Revision Date: 26 Nov 2019 Page 10 of 11 ______________________________________________________________________________________________________________________ Chemical Name CAS Number List Citations 2-PENTANOL, 4-METHYL-, HYDROGEN PHOSPHORODITHIOATE, ZINC SALT 2215-35-2 15 SEVERELY HYDROTREATED HEAVY PARAFFINIC DISTILLATE 64742-54-7 17, 18, 19 --REGULATORY LISTS SEARCHED-- 1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK 2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK 3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK 4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK 5 = TSCA 4 10 = CA P65 CARC 15 = MI 293 Code key: CARC=Carcinogen; REPRO=Reproductive SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only): H303: May be harmful if swallowed; Acute Tox Oral, Cat 5 H315: Causes skin irritation; Skin Corr/Irritation, Cat 2 H317: May cause allergic skin reaction; Skin Sensitization, Cat 1 H318: Causes serious eye damage; Serious Eye Damage/Irr, Cat 1 H401: Toxic to aquatic life; Acute Env Tox, Cat 2 H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2 H413: May cause long lasting harmful effects to aquatic life; Chronic Env Tox, Cat 4 THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Composition: Component Table information was modified. Section 09: Vapor Pressure information was added. Section 11 Acute Toxicity data - Header information was added. Section 11 Substance Name - Header information was added. Section 11 Substance Toxicity table - Header information was added. Section 11 Substance Toxicology table information was added. Section 12: information was modified. Section 15: List Citations Table information was modified. Section 15: National Chemical Inventory Listing information was modified. Section 16: HCode Key information was modified. ----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is Product Name: MOBIL PEGASUS 805 Revision Date: 26 Nov 2019 Page 11 of 11 ______________________________________________________________________________________________________________________ included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re- publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest. ----------------------------------------------------------------------------------------------------------------------------------------------------- Internal Use Only MHC: 0B, 0B, 0, 0, 0, 0 PPEC: A DGN: 2007675XUS (1015410) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Exxon Mobil Corporation, All rights reserved SAFETY DATA SHEET ULFB27678W 1 / 11 Section: 1. PRODUCT AND COMPANY IDENTIFICATION Product name : ULFB27678W Other means of identification : Not applicable. Recommended use : H2S Scavenger to oil/crude oil / Triazine Restrictions on use : Refer to available product literature or ask your local Sales Representative for restrictions on use and dose limits. Company : ChampionX LLC 11177 S. Stadium Drive Sugar Land, Texas 77478 USA TEL: (281) 632-6500 Emergency telephone number : (800) 424-9300 (24 Hours) CHEMTREC Issuing date : 06/24/2020 Section: 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids : Category 3 Acute toxicity (Oral) : Category 4 Acute toxicity (Inhalation) : Category 4 Skin irritation : Category 2 Eye irritation : Category 2A Skin sensitization : Category 1 Specific target organ toxicity - single exposure : Category 2 (Eyes) Specific target organ toxicity - single exposure : Category 3 (Respiratory system, Central Nervous System) GHS Label element Hazard pictograms : Signal Word : Warning Hazard Statements : Flammable liquid and vapour. Harmful if swallowed or if inhaled. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. May cause damage to organs (Eyes). SAFETY DATA SHEET ULFB27678W 2 / 11 Precautionary Statements : Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/ eye protection/ face protection. Response: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Storage: Store in a well-ventilated place. Disposal: Dispose of contents/ container to an approved waste disposal plant. Other hazards : None known. Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration: (%) Substituted alkylamine Proprietary 30 - 60 Methanol 67-56-1 1 - 5 Monoethanolamine 141-43-5 1 - 5 Section: 4. FIRST AID MEASURES In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention. In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. If swallowed : Rinse mouth. Get medical attention if symptoms occur. If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention. Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt, contact emergency responders. Use personal protective equipment as required. Notes to physician : Treat symptomatically. Most important symptoms and effects, both acute and delayed : See Section 11 for more detailed information on health effects and symptoms. Section: 5. FIREFIGHTING MEASURES SAFETY DATA SHEET ULFB27678W 3 / 11 Suitable extinguishing media : Foam Carbon dioxide Dry powder Other extinguishing agent suitable for Class B fires For large fires, use water spray or fog, thoroughly drenching the burning material. Unsuitable extinguishing media : None known. Specific hazards during firefighting : Fire Hazard Keep away from heat and sources of ignition. Flash back possible over considerable distance. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Hazardous combustion products : Carbon oxides nitrogen oxides (NOx) Special protective equipment for firefighters : Use personal protective equipment. Specific extinguishing methods : Use water spray to cool unopened containers. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. Section: 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Ensure adequate ventilation. Remove all sources of ignition. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up : Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Flush away traces with water. Section: 7. HANDLING AND STORAGE Advice on safe handling : Avoid contact with skin and eyes. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Do not ingest. Keep away from fire, sparks and heated surfaces. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash hands thoroughly after handling. Use only with adequate ventilation. Conditions for safe storage : Keep away from heat and sources of ignition. Keep in a cool, well-ventilated place. Keep away from oxidizing agents. Keep out of reach of children. Keep container tightly closed. Store in suitable labelled containers. SAFETY DATA SHEET ULFB27678W 4 / 11 Suitable material : The following compatibility data is suggested based on similar product data and/or industry experience: Shipping and long term storage compatibility with construction materials can vary; we therefore recommend that compatibility is tested prior to use. Unsuitable material : not determined Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Form of exposure Permissible concentration Basis Methanol 67-56-1 TWA 200 ppm ACGIH STEL 250 ppm ACGIH TWA 200 ppm 260 mg/m3 NIOSH REL STEL 250 ppm 325 mg/m3 NIOSH REL TWA 200 ppm 260 mg/m3 OSHA Z1 Monoethanolamine 141-43-5 TWA 3 ppm ACGIH STEL 6 ppm ACGIH TWA 3 ppm 8 mg/m3 NIOSH REL STEL 6 ppm 15 mg/m3 NIOSH REL TWA 3 ppm 6 mg/m3 OSHA Z1 Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection : Safety goggles Face-shield Hand protection : Wear impervious chemical-resistant gloves when handling this product. The following glove types are recommended based on our review of glove manufacturer information and/or other available sources. Nitrile-rubber, Butyl-Rubber and Neoprene gloves. Other glove types may be used for short term, incidental contact if determined by testing to provide adequate worker protection. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Skin protection : Wear suitable protective clothing. Respiratory protection : Use local exhaust ventilation or other engineering controls as necessary to control airborne vapour and mist. Where concentrations in air m ay exceed the limits given in this section or when significant vapours are generated, use an approved air purifying respirator fitted with a gas and vapour cartridge. SAFETY DATA SHEET ULFB27678W 5 / 11 Use a particulate pre-filter where operations generate significant mists or aerosols. Recommended gas and vapour cartridge: Multi-purpose combination filter In event of emergency or planned entry into unknown concentrations, a positive pressure, full-facepiece SCBA or supplied-air respirator should be used. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. The Personal Protective Equipment (PPE) recommendations provided above have been made in good faith based on typical expected conditions of use. PPE selection should always be completed in conjunction with a proper risk assessment and in accordance with a PPE management program. Section: 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Liquid Colour : colourless Odour : amine-like Flash point : > 60.0 °C, Method: PMCC pH : 10.5 - 12.0, Neat Odour Threshold : no data available Melting point/freezing point : POUR POINT: -23.3 °C, > Initial boiling point and boiling range : no data available Evaporation rate : no data available Flammability (solid, gas) : Not applicable. Upper explosion limit : no data available Lower explosion limit : no data available Vapour pressure : no data available Relative vapour density : no data available Relative density : 1.042 - 1.072, (20.0 °C), Density : no data available Water solubility : Complete Solubility in other solvents : no data available Partition coefficient: n- octanol/water : no data available Auto-ignition temperature : no data available Thermal decomposition : no data available Viscosity, dynamic : 2 - 12 mPa.s Viscosity, kinematic : no data available Molecular weight : no data available SAFETY DATA SHEET ULFB27678W 6 / 11 VOC : no data available Section: 10. STABILITY AND REACTIVITY Reactivity : No dangerous reaction known under conditions of normal use. Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. Conditions to avoid : Heat, flames and sparks. Incompatible materials : Strong oxidizing agents Hazardous decomposition products : In case of fire, hazardous decomposition products may be produced such as: Carbon oxides nitrogen oxides (NOx) Section: 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Eyes : Causes serious eye irritation. Skin : Causes skin irritation. May cause allergic skin reaction. Ingestion : May cause blindness if swallowed. Harmful if swallowed. Inhalation : May cause respiratory tract irritation. Harmful if inhaled. May cause nose, throat, and lung irritation. Inhalation may cause central nervous system effects. Chronic Exposure : Health injuries are not known or expected under normal use. Experience with human exposure Eye contact : Redness, Pain, Irritation Skin contact : Redness, Irritation, Allergic reactions Ingestion : No information available. Inhalation : Respiratory irritation, Cough, Dizziness, Drowsiness Toxicity Product SAFETY DATA SHEET ULFB27678W 7 / 11 Acute oral toxicity : Acute toxicity estimate: 1,411 mg/kg Acute inhalation toxicity : Acute toxicity estimate: 1.11 mg/l Exposure time: 4 h Test atmosphere: dust/mist Acute dermal toxicity : Acute toxicity estimate: > 5,000 mg/kg Skin corrosion/irritation : no data available Serious eye damage/eye irritation : no data available Respiratory or skin sensitization : no data available Carcinogenicity : no data available Reproductive effects : no data available Germ cell mutagenicity : no data available Teratogenicity : no data available STOT - single exposure : no data available STOT - repeated exposure : no data available Aspiration toxicity : no data available Section: 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects : Toxic to aquatic life. Components Toxicity to fish : Substituted alkylamine LC50 Fish: 16.07 mg/l Exposure time: 96 h Methanol LC50: 15,400 mg/l Exposure time: 96 h Components Toxicity to daphnia and other aquatic invertebrates : Substituted alkylamine EC50 Aquatic Invertebrate: 11.9 mg/l Exposure time: 48 h Methanol EC50 : > 10,000 mg/l Exposure time: 48 h Monoethanolamine LC50 : 65 mg/l Exposure time: 48 h Components SAFETY DATA SHEET ULFB27678W 8 / 11 Toxicity to algae : Substituted alkylamine EC50 Aquatic Plant: 6.66 mg/l Exposure time: 72 h Methanol EC50 : 22,000 mg/l Exposure time: 72 h Components Toxicity to bacteria : Methanol > 1,000 mg/l Components Toxicity to fish (Chronic toxicity) : Methanol NOEC: 7,900 mg/l Exposure time: 8.3 d Components Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : Monoethanolamine NOEC: 0.85 mg/l Exposure time: 21 d Persistence and degradability The organic portion of this preparation is expected to be inherently biodegradable. Mobility The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models. If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages; Air : <5% Water : 30 - 50% Soil : 50 - 70% The portion in water is expected to be soluble or dispersible. Bioaccumulative potential This preparation or material is not expected to bioaccumulate. Other information no data available Section: 13. DISPOSAL CONSIDERATIONS SAFETY DATA SHEET ULFB27678W 9 / 11 The information presented only applies to the material as supplied. The classification or waste code may not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated at the time of disposal to determine the proper waste identification and disposal methods in compliance with applicable regulations. Disposal methods : The product should not be allowed to enter drains, water courses or the soil. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. Section: 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (DOT) Proper shipping name : FLAMMABLE LIQUID, N.O.S. Technical name(s) : Methanol UN/ID No. : UN 1993 Transport hazard class(es) : 3 Packing group : III Air transport (IATA) Proper shipping name : FLAMMABLE LIQUID, N.O.S. Technical name(s) : Methanol UN/ID No. : UN 1993 Transport hazard class(es) : 3 Packing group : III Sea transport (IMDG/IMO) Proper shipping name : FLAMMABLE LIQUID, N.O.S. Technical name(s) : Methanol UN/ID No. : UN 1993 Transport hazard class(es) : 3 Packing group : III Section: 15. REGULATORY INFORMATION TSCA list : No substances are subject to a Significant New Use Rule. The following substance(s) is/are subject to TSCA 12(b) export notification requirements: Hexahydro-1,3,5-Tris(2-Hydroxyethyl)-S- Triazine EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity SAFETY DATA SHEET ULFB27678W 10 / 11 Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Methanol 67-56-1 5000 126454 SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids) Acute toxicity (any route of exposure) Skin corrosion or irritation Serious eye damage or eye irritation Respiratory or skin sensitisation Specific target organ toxicity (single or repeated exposure) SARA 302 : This material does not contain any components with a section 302 EHS TPQ. SARA 313 : The following components are subject to reporting levels established by SARA Title III, Section 313: Methanol 67-56-1 1 - 5 % California Prop. 65 WARNING: Reproductive Harm - www.P65Warnings.ca.gov Methanol 67-56-1 INTERNATIONAL CHEMICAL CONTROL LAWS : United States TSCA Inventory On or in compliance with the active portion of the TSCA inventory Australia. Industrial Chemical (Notification and Assessment) Act On the inventory, or in compliance with the inventory. Japan. ENCS - Existing and New Chemical Substances Inventory On the inventory, or in compliance with the inventory. Korea. Korean Existing Chemicals Inventory (KECI) On the inventory, or in compliance with the inventory. Philippines Inventory of Chemicals and Chemical Substances (PICCS) On the inventory, or in compliance with the inventory. China Inventory of Existing Chemical Substances On the inventory, or in compliance with the inventory. Taiwan Chemical Substance Inventory On the inventory, or in compliance with the inventory. Section: 16. OTHER INFORMATION SAFETY DATA SHEET ULFB27678W 11 / 11 NFPA: HMIS III: Revision Date : 06/24/2020 Version Number : 1.4 Prepared By : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Safety Data Sheet is correct to the best of our knowledge, informatio n and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Flammability He a l t h In s t a b i l i t y 2 2 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 2 0 2* Special hazard. 0 = not significant, 1 = Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic