HomeMy WebLinkAboutDERR-2024-010980August 13, 2024
Section 8 CS
40.2354/-110.3688
Duchesne, UT
Re: Section 311 Notification for new Facility, KMA-Section 8 Compressor Station, UT ID#:
UT011539
To Whom It May Concern,
We are providing notification that the following facility has become subject to the requirements
of EPCRA 311 for the chemicals: Triethylene Glycol, Antifreeze (Jefcool E105N; ethylene glycol
based), Methanol, Natural Gas Condensate, Oily water, Amine Nalco Champion qualifier,
Petroleum Hydrocarbons - Engine Lube Oil (New & Used) at the following facilities:
Section 8 CS
40.2354/-110.3688
Duchesne, UT
Tier II State ID: # UT011539
Natural Gas Condensate generation is contingent on completing construction and
commissioning of a downstream facility. Thus, condensate generation is not anticipated until
mid-September or October.
If you have any questions, please reach out to Stacey Malerba at (303) 601-8497 or
stacey_malerba@kindermorgan.com.
Thank you,
Attachment: Safety Data Sheet
Product Name: MOBIL PEGASUS 805
Revision Date: 26 Nov 2019
Page 1 of 11
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SAFETY DATA SHEET
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
PRODUCT
Product Name: MOBIL PEGASUS 805
Product Description: Base Oil and Additives
Product Code: 201525106010, 602466-00, 97D936
Intended Use: Natural gas engine oil
COMPANY IDENTIFICATION
Supplier:EXXON MOBIL CORPORATION
22777 Springwoods Village Parkway
Spring, TX 77389 USA
24 Hour Health Emergency 609-737-4411
Transportation Emergency Phone 800-424-9300 or 703-527-3887 CHEMTREC
Product Technical Information 800-662-4525
MSDS Internet Address www.exxon.com, www.mobil.com
SECTION 2 HAZARDS IDENTIFICATION
This material is not hazardous according to regulatory guidelines (see (M)SDS Section 15).
Other hazard information:
HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200.
PHYSICAL / CHEMICAL HAZARDS
No significant hazards.
HEALTH HAZARDS
High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin,
or respiratory irritation.
ENVIRONMENTAL HAZARDS
No significant hazards.
NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0
HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0
Product Name: MOBIL PEGASUS 805
Revision Date: 26 Nov 2019
Page 2 of 11
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NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert
advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary
from person to person.
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
This material is defined as a mixture.
Hazardous Substance(s) or Complex Substance(s) required for disclosure
Name CAS#
Concentration*
GHS Hazard Codes
2,5-FURANDIONE, DIHYDRO-, POLYBUTENYL DERIVS.
REACTION PRODUCTS WITH
TETRAETHYLENEPENTAMINE
68583-75-5 1 - < 5% H413
2-PENTANOL, 4-METHYL-, HYDROGEN
PHOSPHORODITHIOATE, ZINC SALT
2215-35-2 0.1 - < 1% H303, H315, H318, H401,
H411
BENZENE PROPANOIC ACID, 3,5-BIS(1,1-
DIMETHYLETHYL)-4-HYDROXY-, C7-9 BRANCHED
ALKYL ESTERS
125643-61-0 1 - < 5% H413
BENZENE SULFONIC ACIDS, C10-16 ALKYL DERIVS.,
CA SALTS
68584-23-6 0.1 - < 1% H317
BENZENESULFONIC ACID, MONO-C16-24-ALKYL
DERIVS. CALCIUM SALTS
70024-69-0 0.1 - < 1% H317
SULFONIC ACIDS, PETROLEUM, CALCIUM SALTS 61789-86-4 0.1 - < 1% H317
* All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume.
As per paragraph (i) of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity and
exact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact
percentage composition will be provided to health professionals, employees, or designated representatives in
accordance with applicable provisions of paragraph (i).
SECTION 4 FIRST AID MEASURES
INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use
adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use
mouth-to-mouth resuscitation.
SKIN CONTACT
Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the
body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by
a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be
minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent
of injury.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.
INGESTION
First aid is normally not required. Seek medical attention if discomfort occurs.
Product Name: MOBIL PEGASUS 805
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SECTION 5 FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.
Inappropriate Extinguishing Media: Straight Streams of Water
FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering
streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in
enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces
and to protect personnel.
Hazardous Combustion Products: Aldehydes, Incomplete combustion products, Oxides of carbon, Smoke,
Fume, Sulfur oxides
FLAMMABILITY PROPERTIES
Flash Point [Method]: >245°C (473°F) [ASTM D-92]
Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0
Autoignition Temperature: N/D
SECTION 6 ACCIDENTAL RELEASE MEASURES
NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations. US regulations require reporting releases of this material to the environment which exceed the
applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The
National Response Center can be reached at (800)424-8802.
PROTECTIVE MEASURES
Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification
Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum
requirements for personal protective equipment. Additional protective measures may be necessary, depending
on the specific circumstances and/or the expert judgment of the emergency responders.
For emergency responders: Respiratory protection: respiratory protection will be necessary only in special
cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self
Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of
exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible
or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended.
Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use.
Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal
antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic
material is recommended.
Product Name: MOBIL PEGASUS 805
Revision Date: 26 Nov 2019
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SPILL MANAGEMENT
Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent.
Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other
shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist
before using dispersants.
Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways,
sewers, basements or confined areas.
SECTION 7 HANDLING AND STORAGE
HANDLING
Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause
an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any
flammable vapors from liquids or residues that may be present (e.g., during switch-loading operations). Use
proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from
static accumulation. Consult local applicable standards for guidance. Additional references include American
Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or
National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404
(Electrostatics - Code of practice for the avoidance of hazards due to static electricity).
Static Accumulator: This material is a static accumulator.
STORAGE
The type of container used to store the material may affect static accumulation and dissipation. Do not store
in open or unlabelled containers.
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosols
can occur the following are recommended: 5 mg/m³ - ACGIH TLV (inhalable fraction), 5 mg/m³ - OSHA PEL.
NOTE: Limits/standards shown for guidance only. Follow applicable regulations.
No biological limits allocated.
ENGINEERING CONTROLS
Product Name: MOBIL PEGASUS 805
Revision Date: 26 Nov 2019
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The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
No special requirements under ordinary conditions of use and with adequate ventilation.
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a
level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
No special requirements under ordinary conditions of use and with adequate ventilation.
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.
Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use
conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material
include:
No protection is ordinarily required under normal conditions of use.
Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
No skin protection is ordinarily required under normal conditions of use. In accordance with good
industrial hygiene practices, precautions should be taken to avoid skin contact.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and
protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be
cleaned. Practice good housekeeping.
ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharge to air, water and
soil. Protect the environment by applying appropriate control measures to prevent or limit
emissions.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Note: Physical and chemical properties are provided for safety, health and environmental considerations only
and may not fully represent product specifications. Contact the Supplier for additional information.
GENERAL INFORMATION
Product Name: MOBIL PEGASUS 805
Revision Date: 26 Nov 2019
Page 6 of 11
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Physical State: Liquid
Color: Amber
Odor: Characteristic
Odor Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15.6 °C): 0.89
Flammability (Solid, Gas): N/A
Flash Point [Method]: >245°C (473°F) [ASTM D-92]
Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0
Autoignition Temperature: N/D
Boiling Point / Range: > 288°C (550°F)
Decomposition Temperature: N/D
Vapor Density (Air = 1): > 2 at 101 kPa
Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C
Evaporation Rate (n-butyl acetate = 1): N/D
pH: N/A
Log Pow (n-Octanol/Water Partition Coefficient): > 3.5
Solubility in Water: Negligible
Viscosity: 130 cSt (130 mm2/sec) at 40 °C | 13.5 cSt (13.5 mm2/sec) at 100°C [ASTM D 445]
Oxidizing Properties: See Hazards Identification Section.
OTHER INFORMATION
Freezing Point: N/D
Melting Point: N/A
Pour Point: -12°C (10°F)
DMSO Extract (mineral oil only), IP-346: < 3 %wt
SECTION 10 STABILITY AND REACTIVITY
REACTIVITY: See sub-sections below.
STABILITY: Material is stable under normal conditions.
CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition.
MATERIALS TO AVOID: Strong oxidizers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur.
SECTION 11 TOXICOLOGICAL INFORMATION
INFORMATION ON TOXICOLOGICAL EFFECTS
Hazard Class Conclusion / Remarks
Inhalation
Acute Toxicity: No end point data for
material.
Minimally Toxic. Based on assessment of the components.
Irritation: No end point data for material.Negligible hazard at ambient/normal handling temperatures.
Product Name: MOBIL PEGASUS 805
Revision Date: 26 Nov 2019
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Ingestion
Acute Toxicity: No end point data for
material.
Minimally Toxic. Based on assessment of the components.
Skin
Acute Toxicity: No end point data for
material.
Minimally Toxic. Based on assessment of the components.
Skin Corrosion/Irritation: No end point data
for material.
Negligible irritation to skin at ambient temperatures. Based on
assessment of the components.
Eye
Serious Eye Damage/Irritation: No end point
data for material.
May cause mild, short-lasting discomfort to eyes. Based on
assessment of the components.
Sensitization
Respiratory Sensitization: No end point data
for material.
Not expected to be a respiratory sensitizer.
Skin Sensitization: No end point data for
material.
Not expected to be a skin sensitizer. Based on assessment of the
components.
Aspiration: Data available.Not expected to be an aspiration hazard. Based on physico-
chemical properties of the material.
Germ Cell Mutagenicity: No end point data
for material.
Not expected to be a germ cell mutagen. Based on assessment of
the components.
Carcinogenicity: No end point data for
material.
Not expected to cause cancer. Based on assessment of the
components.
Reproductive Toxicity: No end point data
for material.
Not expected to be a reproductive toxicant. Based on assessment
of the components.
Lactation: No end point data for material.Not expected to cause harm to breast-fed children.
Specific Target Organ Toxicity (STOT)
Single Exposure: No end point data for
material.
Not expected to cause organ damage from a single exposure.
Repeated Exposure: No end point data for
material.
Not expected to cause organ damage from prolonged or repeated
exposure. Based on assessment of the components.
TOXICITY FOR SUBSTANCES
NAME ACUTE TOXICITY
2-PENTANOL, 4-METHYL-, HYDROGEN
PHOSPHORODITHIOATE, ZINC SALT
Oral Lethality: LD50 2230 mg/kg (Rat)
OTHER INFORMATION
For the product itself:
Component concentrations in this formulation would not be expected to cause skin sensitization, based on tests of the
components, this formulation, or similar formulations.
Contains:
Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames
test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of
immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals.
Sulfonates: This product contains sulfonates which have been reported to cause skin sensitization.
The following ingredients are cited on the lists below: None.
Product Name: MOBIL PEGASUS 805
Revision Date: 26 Nov 2019
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--REGULATORY LISTS SEARCHED--
1 = NTP CARC 3 = IARC 1 5 = IARC 2B
2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC
SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data for the material, components of the material, or for similar materials, through the
application of bridging principals.
ECOTOXICITY
Material -- Not expected to be harmful to aquatic organisms.
MOBILITY
Base oil component -- Low solubility and floats and is expected to migrate from water to the land.
Expected to partition to sediment and wastewater solids.
PERSISTENCE AND DEGRADABILITY
Biodegradation:
Base oil component -- Expected to be inherently biodegradable
BIOACCUMULATION POTENTIAL
Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties
may reduce the bioconcentration or limit bioavailability.
SECTION 13 DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.
DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised
incineration at very high temperatures to prevent formation of undesirable combustion products. Protect the
environment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents,
brake fluids or coolants.
REGULATORY DISPOSAL INFORMATION
RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous
waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It
does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with
contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used
product may be regulated.
Product Name: MOBIL PEGASUS 805
Revision Date: 26 Nov 2019
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Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue
and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should
be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be
taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with
governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION
LAND (DOT): Not Regulated for Land Transport
LAND (TDG): Not Regulated for Land Transport
SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code
Marine Pollutant: No
AIR (IATA): Not Regulated for Air Transport
SECTION 15 REGULATORY INFORMATION
OSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance with
OSHA HazCom 2012, 29 CFR 1910.1200.
Listed or exempt from listing/notification on the following chemical inventories: AICS, DSL, ENCS, ISHL,
KECI, PICCS, TCSI, TSCA
Special Cases:
Inventory Status
IECSC Restrictions Apply
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302
SARA (311/312) REPORTABLE GHS HAZARD CLASSES: None.
SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification
requirements of the SARA 313 Toxic Release Program.
The following ingredients are cited on the lists below:
Product Name: MOBIL PEGASUS 805
Revision Date: 26 Nov 2019
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Chemical Name CAS Number List Citations
2-PENTANOL, 4-METHYL-,
HYDROGEN
PHOSPHORODITHIOATE, ZINC
SALT
2215-35-2 15
SEVERELY HYDROTREATED
HEAVY PARAFFINIC
DISTILLATE
64742-54-7 17, 18, 19
--REGULATORY LISTS SEARCHED--
1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK
2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK
3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK
4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK
5 = TSCA 4 10 = CA P65 CARC 15 = MI 293
Code key: CARC=Carcinogen; REPRO=Reproductive
SECTION 16 OTHER INFORMATION
N/D = Not determined, N/A = Not applicable
KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only):
H303: May be harmful if swallowed; Acute Tox Oral, Cat 5
H315: Causes skin irritation; Skin Corr/Irritation, Cat 2
H317: May cause allergic skin reaction; Skin Sensitization, Cat 1
H318: Causes serious eye damage; Serious Eye Damage/Irr, Cat 1
H401: Toxic to aquatic life; Acute Env Tox, Cat 2
H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2
H413: May cause long lasting harmful effects to aquatic life; Chronic Env Tox, Cat 4
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:
Composition: Component Table information was modified.
Section 09: Vapor Pressure information was added.
Section 11 Acute Toxicity data - Header information was added.
Section 11 Substance Name - Header information was added.
Section 11 Substance Toxicity table - Header information was added.
Section 11 Substance Toxicology table information was added.
Section 12: information was modified.
Section 15: List Citations Table information was modified.
Section 15: National Chemical Inventory Listing information was modified.
Section 16: HCode Key information was modified.
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The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate
and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current
available from ExxonMobil. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
Product Name: MOBIL PEGASUS 805
Revision Date: 26 Nov 2019
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included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-
publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for
convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any
affiliates in which they directly or indirectly hold any interest.
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Internal Use Only
MHC: 0B, 0B, 0, 0, 0, 0 PPEC: A
DGN: 2007675XUS (1015410)
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Copyright 2002 Exxon Mobil Corporation, All rights reserved
SAFETY DATA SHEET
ULFB27678W
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Section: 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : ULFB27678W
Other means of identification : Not applicable.
Recommended use : H2S Scavenger to oil/crude oil / Triazine
Restrictions on use : Refer to available product literature or ask your local Sales Representative for
restrictions on use and dose limits.
Company : ChampionX LLC
11177 S. Stadium Drive
Sugar Land, Texas 77478
USA
TEL: (281) 632-6500
Emergency telephone
number
: (800) 424-9300 (24 Hours) CHEMTREC
Issuing date : 06/24/2020
Section: 2. HAZARDS IDENTIFICATION
GHS Classification
Flammable liquids : Category 3
Acute toxicity (Oral) : Category 4
Acute toxicity (Inhalation) : Category 4
Skin irritation : Category 2
Eye irritation : Category 2A
Skin sensitization : Category 1
Specific target organ toxicity
- single exposure
: Category 2 (Eyes)
Specific target organ toxicity
- single exposure
: Category 3 (Respiratory system, Central Nervous System)
GHS Label element
Hazard pictograms :
Signal Word : Warning
Hazard Statements : Flammable liquid and vapour.
Harmful if swallowed or if inhaled.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
May cause respiratory irritation.
May cause drowsiness or dizziness.
May cause damage to organs (Eyes).
SAFETY DATA SHEET
ULFB27678W
2 / 11
Precautionary Statements : Prevention:
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not
breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/ eye
protection/ face protection.
Response:
IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel
unwell. Rinse mouth. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Call a POISON CENTER
or doctor/ physician if you feel unwell. IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
Storage:
Store in a well-ventilated place.
Disposal:
Dispose of contents/ container to an approved waste disposal plant.
Other hazards : None known.
Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS
Pure substance/mixture : Mixture
Chemical Name CAS-No. Concentration: (%)
Substituted alkylamine Proprietary 30 - 60
Methanol 67-56-1 1 - 5
Monoethanolamine 141-43-5 1 - 5
Section: 4. FIRST AID MEASURES
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Get medical attention.
In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild
soap if available. Wash clothing before reuse. Thoroughly clean shoes before
reuse. Get medical attention.
If swallowed : Rinse mouth. Get medical attention if symptoms occur.
If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention.
Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put
yourself at risk of injury. If in doubt, contact emergency responders. Use
personal protective equipment as required.
Notes to physician : Treat symptomatically.
Most important symptoms
and effects, both acute and
delayed
: See Section 11 for more detailed information on health effects and symptoms.
Section: 5. FIREFIGHTING MEASURES
SAFETY DATA SHEET
ULFB27678W
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Suitable extinguishing media : Foam
Carbon dioxide
Dry powder
Other extinguishing agent suitable for Class B fires
For large fires, use water spray or fog, thoroughly drenching the burning
material.
Unsuitable extinguishing
media
: None known.
Specific hazards during
firefighting
: Fire Hazard
Keep away from heat and sources of ignition.
Flash back possible over considerable distance.
Beware of vapours accumulating to form explosive concentrations. Vapours can
accumulate in low areas.
Hazardous combustion
products
: Carbon oxides nitrogen oxides (NOx)
Special protective equipment
for firefighters
: Use personal protective equipment.
Specific extinguishing
methods
: Use water spray to cool unopened containers. Fire residues and contaminated
fire extinguishing water must be disposed of in accordance with local
regulations. In the event of fire and/or explosion do not breathe fumes.
Section: 6. ACCIDENTAL RELEASE MEASURES
Personal precautions,
protective equipment and
emergency procedures
: Ensure adequate ventilation. Remove all sources of ignition. Ensure clean-up is
conducted by trained personnel only. Refer to protective measures listed in
sections 7 and 8.
Environmental precautions : Do not allow contact with soil, surface or ground water.
Methods and materials for
containment and cleaning up
: Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. Contain
spillage, and then collect with non-combustible absorbent material, (e.g. sand,
earth, diatomaceous earth, vermiculite) and place in container for disposal
according to local / national regulations (see section 13). For large spills, dike
spilled material or otherwise contain material to ensure runoff does not reach a
waterway. Flush away traces with water.
Section: 7. HANDLING AND STORAGE
Advice on safe handling : Avoid contact with skin and eyes. Take necessary action to avoid static
electricity discharge (which might cause ignition of organic vapours). Do not
ingest. Keep away from fire, sparks and heated surfaces. Do not breathe
dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing.
Wash hands thoroughly after handling. Use only with adequate ventilation.
Conditions for safe storage : Keep away from heat and sources of ignition. Keep in a cool, well-ventilated
place. Keep away from oxidizing agents. Keep out of reach of children. Keep
container tightly closed. Store in suitable labelled containers.
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Suitable material : The following compatibility data is suggested based on similar product data
and/or industry experience: Shipping and long term storage compatibility with
construction materials can vary; we therefore recommend that compatibility is
tested prior to use.
Unsuitable material : not determined
Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Form of exposure Permissible
concentration
Basis
Methanol 67-56-1 TWA 200 ppm ACGIH
STEL 250 ppm ACGIH
TWA 200 ppm
260 mg/m3
NIOSH REL
STEL 250 ppm
325 mg/m3
NIOSH REL
TWA 200 ppm
260 mg/m3
OSHA Z1
Monoethanolamine 141-43-5 TWA 3 ppm ACGIH
STEL 6 ppm ACGIH
TWA 3 ppm
8 mg/m3
NIOSH REL
STEL 6 ppm
15 mg/m3
NIOSH REL
TWA 3 ppm
6 mg/m3
OSHA Z1
Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below
occupational exposure standards.
Personal protective equipment
Eye protection : Safety goggles
Face-shield
Hand protection : Wear impervious chemical-resistant gloves when handling this product.
The following glove types are recommended based on our review of glove
manufacturer information and/or other available sources.
Nitrile-rubber, Butyl-Rubber and Neoprene gloves.
Other glove types may be used for short term, incidental contact if determined
by testing to provide adequate worker protection.
Gloves should be discarded and replaced if there is any indication of
degradation or chemical breakthrough.
Skin protection : Wear suitable protective clothing.
Respiratory protection : Use local exhaust ventilation or other engineering controls as necessary to
control airborne vapour and mist.
Where concentrations in air m ay exceed the limits given in this section or when
significant vapours are generated, use an approved air purifying respirator fitted
with a gas and vapour cartridge.
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Use a particulate pre-filter where operations generate significant mists or
aerosols.
Recommended gas and vapour cartridge:
Multi-purpose combination filter
In event of emergency or planned entry into unknown concentrations, a positive
pressure, full-facepiece SCBA or supplied-air respirator should be used.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove
and wash contaminated clothing before re-use. Wash face, hands and any
exposed skin thoroughly after handling.
The Personal Protective Equipment (PPE) recommendations provided above have been made in good faith based
on typical expected conditions of use. PPE selection should always be completed in conjunction with a proper risk
assessment and in accordance with a PPE management program.
Section: 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Liquid
Colour : colourless
Odour : amine-like
Flash point : > 60.0 °C, Method: PMCC
pH : 10.5 - 12.0, Neat
Odour Threshold : no data available
Melting point/freezing point : POUR POINT: -23.3 °C, >
Initial boiling point and boiling
range
: no data available
Evaporation rate : no data available
Flammability (solid, gas) : Not applicable.
Upper explosion limit : no data available
Lower explosion limit : no data available
Vapour pressure : no data available
Relative vapour density : no data available
Relative density : 1.042 - 1.072, (20.0 °C),
Density : no data available
Water solubility : Complete
Solubility in other solvents : no data available
Partition coefficient: n-
octanol/water
: no data available
Auto-ignition temperature : no data available
Thermal decomposition : no data available
Viscosity, dynamic : 2 - 12 mPa.s
Viscosity, kinematic : no data available
Molecular weight : no data available
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VOC : no data available
Section: 10. STABILITY AND REACTIVITY
Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : Stable under normal conditions.
Possibility of hazardous
reactions
: No dangerous reaction known under conditions of normal use.
Conditions to avoid : Heat, flames and sparks.
Incompatible materials : Strong oxidizing agents
Hazardous decomposition
products
: In case of fire, hazardous decomposition products may be produced such as:
Carbon oxides
nitrogen oxides (NOx)
Section: 11. TOXICOLOGICAL INFORMATION
Information on likely routes of
exposure
: Inhalation, Eye contact, Skin contact
Potential Health Effects
Eyes : Causes serious eye irritation.
Skin : Causes skin irritation. May cause allergic skin reaction.
Ingestion : May cause blindness if swallowed. Harmful if swallowed.
Inhalation : May cause respiratory tract irritation. Harmful if inhaled. May cause nose, throat,
and lung irritation. Inhalation may cause central nervous system effects.
Chronic Exposure : Health injuries are not known or expected under normal use.
Experience with human exposure
Eye contact : Redness, Pain, Irritation
Skin contact : Redness, Irritation, Allergic reactions
Ingestion : No information available.
Inhalation : Respiratory irritation, Cough, Dizziness, Drowsiness
Toxicity
Product
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Acute oral toxicity : Acute toxicity estimate: 1,411 mg/kg
Acute inhalation toxicity : Acute toxicity estimate: 1.11 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Acute dermal toxicity : Acute toxicity estimate: > 5,000 mg/kg
Skin corrosion/irritation : no data available
Serious eye damage/eye
irritation
: no data available
Respiratory or skin
sensitization
: no data available
Carcinogenicity : no data available
Reproductive effects : no data available
Germ cell mutagenicity : no data available
Teratogenicity : no data available
STOT - single exposure : no data available
STOT - repeated exposure : no data available
Aspiration toxicity : no data available
Section: 12. ECOLOGICAL INFORMATION
Ecotoxicity
Environmental Effects : Toxic to aquatic life.
Components
Toxicity to fish : Substituted alkylamine
LC50 Fish: 16.07 mg/l
Exposure time: 96 h
Methanol
LC50: 15,400 mg/l
Exposure time: 96 h
Components
Toxicity to daphnia and other
aquatic invertebrates
: Substituted alkylamine
EC50 Aquatic Invertebrate: 11.9 mg/l
Exposure time: 48 h
Methanol
EC50 : > 10,000 mg/l
Exposure time: 48 h
Monoethanolamine
LC50 : 65 mg/l
Exposure time: 48 h
Components
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Toxicity to algae : Substituted alkylamine
EC50 Aquatic Plant: 6.66 mg/l
Exposure time: 72 h
Methanol
EC50 : 22,000 mg/l
Exposure time: 72 h
Components
Toxicity to bacteria : Methanol
> 1,000 mg/l
Components
Toxicity to fish (Chronic
toxicity)
: Methanol
NOEC: 7,900 mg/l
Exposure time: 8.3 d
Components
Toxicity to daphnia and other
aquatic invertebrates
(Chronic toxicity)
: Monoethanolamine
NOEC: 0.85 mg/l
Exposure time: 21 d
Persistence and degradability
The organic portion of this preparation is expected to be inherently biodegradable.
Mobility
The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program
interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input
and output. The level III model does not require equilibrium between the defined media. The information provided is
intended to give the user a general estimate of the environmental fate of this product under the defined conditions of
the models.
If released into the environment this material is expected to distribute to the air, water and soil/sediment in the
approximate respective percentages;
Air : <5%
Water : 30 - 50%
Soil : 50 - 70%
The portion in water is expected to be soluble or dispersible.
Bioaccumulative potential
This preparation or material is not expected to bioaccumulate.
Other information
no data available
Section: 13. DISPOSAL CONSIDERATIONS
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The information presented only applies to the material as supplied. The classification or waste code may not apply if
the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine
the toxicity and physical properties of the material generated at the time of disposal to determine the proper waste
identification and disposal methods in compliance with applicable regulations.
Disposal methods : The product should not be allowed to enter drains, water
courses or the soil. Where possible recycling is preferred to
disposal or incineration. If recycling is not practicable, dispose
of in compliance with local regulations. Dispose of wastes in
an approved waste disposal facility.
Disposal considerations : Dispose of as unused product. Empty containers should be
taken to an approved waste handling site for recycling or
disposal. Do not re-use empty containers.
Section: 14. TRANSPORT INFORMATION
The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance
with the selected mode of transport.
Land transport (DOT)
Proper shipping name : FLAMMABLE LIQUID, N.O.S.
Technical name(s) : Methanol
UN/ID No. : UN 1993
Transport hazard class(es) : 3
Packing group : III
Air transport (IATA)
Proper shipping name : FLAMMABLE LIQUID, N.O.S.
Technical name(s) : Methanol
UN/ID No. : UN 1993
Transport hazard class(es) : 3
Packing group : III
Sea transport (IMDG/IMO)
Proper shipping name : FLAMMABLE LIQUID, N.O.S.
Technical name(s) : Methanol
UN/ID No. : UN 1993
Transport hazard class(es) : 3
Packing group : III
Section: 15. REGULATORY INFORMATION
TSCA list : No substances are subject to a Significant New Use Rule.
The following substance(s) is/are subject to TSCA 12(b) export
notification requirements: Hexahydro-1,3,5-Tris(2-Hydroxyethyl)-S-
Triazine
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
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Components CAS-No. Component RQ (lbs) Calculated product RQ
(lbs)
Methanol 67-56-1 5000 126454
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)
Acute toxicity (any route of exposure)
Skin corrosion or irritation
Serious eye damage or eye irritation
Respiratory or skin sensitisation
Specific target organ toxicity (single or repeated exposure)
SARA 302 : This material does not contain any components with a section 302
EHS TPQ.
SARA 313 : The following components are subject to reporting levels established
by SARA Title III, Section 313:
Methanol 67-56-1 1 - 5 %
California Prop. 65
WARNING: Reproductive Harm - www.P65Warnings.ca.gov
Methanol 67-56-1
INTERNATIONAL CHEMICAL CONTROL LAWS :
United States TSCA Inventory
On or in compliance with the active portion of the TSCA inventory
Australia. Industrial Chemical (Notification and Assessment) Act
On the inventory, or in compliance with the inventory.
Japan. ENCS - Existing and New Chemical Substances Inventory
On the inventory, or in compliance with the inventory.
Korea. Korean Existing Chemicals Inventory (KECI)
On the inventory, or in compliance with the inventory.
Philippines Inventory of Chemicals and Chemical Substances (PICCS)
On the inventory, or in compliance with the inventory.
China Inventory of Existing Chemical Substances
On the inventory, or in compliance with the inventory.
Taiwan Chemical Substance Inventory
On the inventory, or in compliance with the inventory.
Section: 16. OTHER INFORMATION
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NFPA: HMIS III:
Revision Date : 06/24/2020
Version Number : 1.4
Prepared By : Regulatory Affairs
REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by
a bar in the left-hand margin of the SDS.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, informatio n and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use,
processing, storage, transportation, disposal and release and is not to be considered a warranty or quality
specification. The information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified in the text.
Flammability
He
a
l
t
h
In
s
t
a
b
i
l
i
t
y
2
2
0
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
2
0
2*
Special hazard. 0 = not significant, 1 = Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic