DSHW-2024-007994

DEPARTMENT OF THE ARMY
TOOELE ARMY DEPOT/HEADQUARTERS
1 TOOELE ARMY DEPOT, BUILDING 1
TOOELE, UT 84074-5003

August 26, 2024

SUBJECT: Response to Water Well WIN 9549 Sampling and Risk Assessment, Tooele
Army Depot North Area (TEAD-N), State/EPA I.D. Number UT3213820894.

Mr. Doug Hansen
Director, Division Waste Management and Radiation Control
195 North 1950 West
Salt Lake City, UT 84114-4880

Dear Mr. Hansen:

TEAD is submitting the Response to Water Well WIN 9549 Sampling and Risk
Assessment. Original Letter received from UDWMRC April 24, 2024; Response letter
Water Supply Well Win 9549, from BRAC PM (Stephanie Santiago) sent May 21, 2024;
Approval of response to Water Supply Well WIN 9549, SWMU 58-TCE Plume May 24,
2024.

Please see included Draft 2024 Spring Gravel Pit Well WIN-9549 Sampling Event
Results and Quality Control Summary Report with included Quantitative Human Health
Risk Assessment (HHRA).

TEAD will address a permit modification for language in Module IX.A.2.a for exposure
and compliance.

If you have any questions regarding this request, please contact Tyson Erickson at
[phone].

SUBJECT: Response to Water Well WIN 9549 Sampling and Risk Assessment, Tooele
Army Depot North Area (TEAD-N), State/EPA I.D. Number UT3213820894.

2
*I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations.

Sincerely,

Lonnie Brown
Chief, Environmental Division *CERTIFICATION STATEMENT

BROWN.LONNIE.D
ANIELS.140243232
9
Digitally signed by
BROWN.LONNIE.DANIELS.1402
432329
Date: 2024.08.26 15:10:37 -06'00'

DRAFT
2024 Spring Gravel Pit Well WIN-9549 Sampling Event
Results and Quality Control Summary Report
Tooele Army Depot North
August 2024

Contract No. W9124J-21-D-0006

U.S. Army Environmental Command Tooele Army Depot

DRAFT
2024 Spring Gravel Pit Well WIN-9549 Sampling Event
Results and Quality Control Summary Report
Tooele Army Depot North
August 2024

Contract No. W9124J-21-D-0006

Prepared For:

U.S. Army Mission and Installation Contracting Command
Fort Sam Houston (MICC – FSH), U.S. Army Environmental Command (USAEC), and Tooele Army Depot (TEAD)

Prepared By:

Brice Engineering, LLC
3700 Centerpoint Drive, Suite 8223
Anchorage, Alaska 99503
907.275.2896 PH
www.BriceEng.com

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2024 Spring Gravel Pit Well WIN-9549 Sampling Event Results and Quality Control Summary Report i
Tooele Army Depot North, Utah
TABLE OF CONTENTS
ACRONYMS AND ABBREVIATIONS ...................................................................................................... III
1.0 INTRODUCTION ....................................................................................................................... 1
2.0 WIN-9549 WELL SAMPLING ..................................................................................................... 1
3.0 WIN-9549 RESULTS .................................................................................................................. 1
4.0 REFERENCES ............................................................................................................................ 2
FIGURES
Figure 1 WIN-9549 Location
APPENDICES
Appendix A Quality Control Summary Report
Appendix B Field Forms
Appendix C Analytical Laboratory Reports

2024 Spring Gravel Pit Well WIN-9549 Sampling Event Results and Quality Control Summary Report ii
Tooele Army Depot North, Utah

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2024 Spring Gravel Pit Well WIN-9549 Sampling Event Results and Quality Control Summary Report iii
Tooele Army Depot North, Utah
ACRONYMS AND ABBREVIATIONS
μg/L micrograms per liter
DWMRC Division of Waste Management and Radiation Control
EPA U.S. Environmental Protection Agency
MICC-FSH U.S. Army Mission and Installation Contracting Command Fort Sam Houston
PAL project action level
SWMU Solid Waste Management Unit
TCE trichloroethene
TEAD Tooele Army Depot
TEAD-N Tooele Army Depot North
USAEC U.S. Army Environmental Command

2024 Spring Gravel Pit Well WIN-9549 Sampling Event Results and Quality Control Summary Report iv
Tooele Army Depot North, Utah

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2024 Spring Gravel Pit Well WIN-9549 Sampling Event Results and Quality Control Summary Report 1
Tooele Army Depot North, Utah
1.0 INTRODUCTION
This report documents sampling activities conducted at the Gravel Pit Well (WIN-9549) on 23 May 2024.
WIN-9549 is located at 1830 Highway 112, Tooele Utah, offsite of Tooele Army Depot North (TEAD-N) but
within the Solid Waste Management Unit (SWMU) 58 groundwater plume (Figure 1). The well is owned
by Bolinder Resources LLC and is used in a gravel pit mine for non-potable applications such as dust
suppression and gravel washing.
In a letter dated 24 April 2024 from the Division of Waste Management and Radiation Control (DWMRC),
concerns were raised about use of groundwater from WIN-9549 as it falls within the SWMU 58
trichloroethene (TCE) groundwater plume (DWMRC 2024a). The DWMRC requested that the well be
evaluated for risks associated with use of WIN-9549 to ensure ongoing protection of human and ecological
exposure to the contaminated groundwater. In response, TEAD-N outlined a plan for sampling and
procured a Right of Entry agreement with Bolinder Resources LLC. TEAD-N submitted a formal request to
the DWMRC to sample the well in a letter dated 21 May 2024 (TEAD-N 2024). The DWMRC granted the
request in a letter dated 24 May 2024 (DWMRC 2024b).
2.0 WIN-9549 WELL SAMPLING
Sampling of WIN-9549 was conducted by Brice Engineering, LLC in accordance with the procedure
outlined in the letter from TEAD-N on 21 May 2024. The samples were collected on 23 May 2024 via a
sampling port on the well head. Because the well was operational, the port was purged for 5 minutes prior
to collection. Primary, field duplicate, and matrix spike/matrix spike duplicate samples were collected to
allow for validation of the laboratory data. These samples were shipped to EMAX Laboratories, Inc. in
Torrance, California, for analysis. A Quality Control Summary Report discussing data quality is included as
Appendix A. Analytical results for the samples are presented in Attachment A-2. A data validation report
is included in Attachment A-4. A field sampling form is included in Appendix B. Analytical laboratory
reports are included as Appendix C.
3.0 WIN-9549 RESULTS
Laboratory analytical results for WIN-9549 are included in Attachment A-2. Analytical results were
compared to the project action levels (PALs) in Table X-2 of the Post Closure Permit. All results were less
than PALs with the exception of TCE detected at a concentration of 33 micrograms per liter (µg/L) which
exceeds the PAL of 5 µg/L. Several compounds were detected at concentrations below their respective
PALs including carbon tetrachloride, 1,2-dichloroethane, and chloroform.

2024 Spring Gravel Pit Well WIN-9549 Sampling Event Results and Quality Control Summary Report 2
Tooele Army Depot North, Utah
4.0 REFERENCES
Division of Waste Management and Radiation Control (DWMRC). 2024a. RE: Water Supply Well
WIN 9549. Letter dated 24 April 2024, from Douglas Hanson, Director, DWMRC, to Lonnie
Brown, Chief, Environmental Management Division, Tooele Army Depot.
DWMRC. 2024b. RE: Approval of Response to Water Supply Well WIN 9549, SWMU 58 – TCE Plume,
Tooele Army Depot North Area EPA ID # UT3213820894. Letter dated 24 May 2024, from
Douglas Hanson, Director, DWMRC, to Lonnie Brown, Chief, Environmental Management
Division, Tooele Army Depot.
Tooele Army Depot North (TEAD-N). 2024. Subject: Water Supply Well WIN 9549, SWMU 58 – TCE
Plume, Tooele Army Depot North Area (TEAD-N), State/EPA I.D. Number UT3213820894. Letter
dated 21 May 2024, from Stephanie Santiago, Program Manager, Office of Deputy Chief of
Staff G-9, BRAC, to Doug Hansen, Director, DWMRC.

FIGURES

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!U
TOOELE ARMY
DEPOT - NORTH
WIN-9549
1 INCH
3,000 0 3,000 6,0001,500
SCALE IN FEET
1
A.C
DRAWN:P.M.:
PROJECT No.:FIGURE:DATE:
Legend
!U WIN-9549
Inferred Fault Location
2023 TCE Isoconcentration Contour (5 μg/L)
2023 TCE Isoconcentration Contour (50 μg/L)
2023 TCE Isoconcentration Contour (100 μg/L)
Former Sanitary Landfill
Old Industrial Waste Lagoon
Industrial Waste Lagoon
Tooele Army Depot North Boundary
BRAC Parcel
770108 8/8/2024
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p 2024 SPRING GRAVEL PIT WELL WIN-9549
SAMPLING EVENT RESULTS AND QUALITY
CONTROL SUMMARY REPORT
TOOELE ARMY DEPOT, UTAH
WIN-9549 LOCATION
SWMU-58
FIGURE EXTENT
WGS84, UTM ZONE 12 N, METERS
HORIZONAL DATUM: WGS 1984 | VERTICAL DATUM: NAVD88
Abbreviations
μg/L micrograms per liter
BRAC Base Realignment and Closure
SWMU Solid Waste Management Unit
TCE trichloroethene
Notes
1. TCE isoconcentration contours were updated using results from the 2023
Annual Groundwater Report.
2. For conceptual purposes only. All locations are approximate.
3. Map produced using ESRI ArcMap v. 10.7.
References
1. Basemap source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics,
CNES/Airbus DS, USDA, USGS, AeroGRID, IGN, and the GIS User Community
Copyright: © 2013 National Geographic Society, i-cubed

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APPENDIX A
QUALITY CONTROL SUMMARY REPORT

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Appendix A – Quality Control Summary Report A-i
2024 Spring Gravel Pit Well WIN-9549 Sampling Event Results and Quality Control Summary Report
Tooele Army Depot North, Utah
TABLE OF CONTENTS
ACRONYMS AND ABBREVIATIONS ................................................................................................... A-III
1.0 INTRODUCTION .................................................................................................................... A-1
2.0 DATA VERIFICATION, DATA QUALITY REVIEW, AND QUALIFICATION ..................................... A-1
3.0 CHEMICAL DATA QUALITY REVIEW ....................................................................................... A-3
3.1 Analytical Sample and Field Quality Control Sample Summary ..................................... A-4
3.2 Sample Handling and Chain-of-Custody ......................................................................... A-4
3.3 Sample Preservation and Holding Time Compliance ...................................................... A-4
3.4 Sample Limits of Detection and Limits of Quantitation .................................................. A-4
3.5 Blanks .............................................................................................................................. A-4
3.5.1 Method Blanks ................................................................................................... A-4
3.5.2 Trip Blanks .......................................................................................................... A-5
3.6 Laboratory Control Samples ........................................................................................... A-5
3.7 Matrix Spike Samples and Duplicates ............................................................................. A-5
3.8 Surrogates ....................................................................................................................... A-5
3.9 Field Duplicate Precision ................................................................................................. A-5
3.10 Additional Quality Control Discrepancies ....................................................................... A-5
4.0 COMPLETENESS .................................................................................................................... A-6
5.0 OVERALL DATA QUALITY AND USABILITY ASSESSMENT ........................................................ A-6
6.0 REFERENCES ......................................................................................................................... A-6
TABLES
Table 1 Data Qualifiers ............................................................................................................. A-3
ATTACHMENTS
Attachment A-1 Sample Summary
Attachment A-2 Data Summary Table
Attachment A-3 Field Duplicate Precision Report
Attachment A-4 Data Validation Reports

Appendix A – Quality Control Summary Report A-ii
2024 Spring Gravel Pit Well WIN-9549 Sampling Event Results and Quality Control Summary Report
Tooele Army Depot North, Utah

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Appendix A – Quality Control Summary Report A-iii
2024 Spring Gravel Pit Well WIN-9549 Sampling Event Results and Quality Control Summary Report
Tooele Army Depot North, Utah
ACRONYMS AND ABBREVIATIONS
°C degrees Celsius
Brice Brice Engineering, LLC
CoC chain-of-custody
DL detection limit
DoD Department of Defense
DQO data quality objective
EB equipment blank
EMAX EMAX Laboratories, Inc.
EPA U.S. Environmental Protection Agency
FD field duplicate
GC/MS gas chromatography/mass spectrometry
LCS laboratory control sample
LCSD laboratory control sample duplicate
LOD limit of detection
LOQ limit of quantitation
MB method blank
MCL maximum contaminant level
MPC measurement performance criteria
MS matrix spike
MSD matrix spike duplicate
PAL project action level
QA quality assurance
QAPP Quality Assurance Project Plan
QC quality control
QCSR Quality Control Summary Report
QSM Quality Systems Manual
RPD relative percent difference
SOP standard operating procedure
TB trip blank
TEAD Tooele Army Depot
TEAD-N Tooele Army Depot North
UFP-QAPP Uniform Federal Policy-Quality Assurance Project Plan
Appendix A – Quality Control Summary Report A-iv
2024 Spring Gravel Pit Well WIN-9549 Sampling Event Results and Quality Control Summary Report
Tooele Army Depot North, Utah

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Appendix A – Quality Control Summary Report A-1
2024 Spring Gravel Pit Well WIN-9549 Sampling Event Results and Quality Control Summary Report
Tooele Army Depot North, Utah
1.0 INTRODUCTION
This Quality Control Summary Report (QCSR) summarizes the evaluation of laboratory data collected
during the Gravel Pit Well (WIN-9549) Groundwater Sampling event. These data have been reviewed to
evaluate compliance with quality assurance (QA)/quality control (QC) criteria based on data quality
objectives (DQOs) specified in the approved Final Uniform Federal Policy-Quality Assurance Project Plan
(UFP-QAPP), Tooele Army Depot North (TEAD-N), Utah (Brice Engineering, LLC [Brice] 2022), hereafter
referred to as the QAPP.
This QCSR includes the report narrative; a sample summary, including all samples collected and submitted
to the laboratory for the associated sample delivery group in Attachment A-1; complete analytical results
presented in crosstab format in Attachment A-2; an evaluation of field duplicates (FD) relative percent
differences (RPDs) in Attachment A-3, and data validation report in Attachment A-4.
2.0 DATA VERIFICATION, DATA QUALITY REVIEW,
AND QUALIFICATION
EMAX Laboratories, Inc. (EMAX) in Torrance, California was the primary laboratory for this project. EMAX
holds current State of Utah certification under the National Environmental Laboratories Accreditation
Conference and Department of Defense (DoD) Environmental Laboratory Accreditation Program
certifications for all requested analyses, and chemical analyses for all parameters were performed in
accordance with the DoD Quality Systems Manual (QSM) for Environmental Laboratories, Version 5.4
(DoD 2021). Samples were prepared and analyzed in accordance with analytical methods specified in Test
Methods for Evaluating Solid Waste SW-846 (U.S. Environmental Protection Agency [EPA] 2022) and
laboratory standard operating procedures (SOPs).
The data quality review and assessment were performed by an experienced QA chemist at Synectics in
Sacramento, California who is independent of the analytical laboratory. This evaluation included a review
of the analytical data including lab and field QC sample results, field and laboratory documentation, and
Stage 4 data submittals. At a minimum, the level of review is at Stage 2B, with a minimum of 10% of the
samples for the project reviewed at Stage 4. Groundwater analytical results were compared to project
action levels (PALs), which were defined as either the values shown in Table X-2 of the Tooele Army Depot
(TEAD) Post-Closure Permit (TEAD 2023) or the EPA maximum contaminant level (MCL).
All project data were reviewed on an analytical-batch basis by assessing QC samples and associated field
sample results. Data quality review and usability assessment were performed using the QC criteria defined
in the QAPP (Brice 2022); DoD QSM (DoD 2021); DoD General Data Validation Guidelines (DoD 2019); DoD
Data Validation Guidelines Module 1: Data Validation Procedure for Organic Analysis by Gas
Chromatography/Mass Spectrometry (GC/MS; DoD 2020); Test Methods for Evaluating Solid Waste
SW-846 (EPA 2022); and the laboratory SOPs, in that order.
The following information was reviewed as part of the data quality review and assessment:
• Sample handling and chain-of-custody (CoC)
• Sample preservation and holding time compliance
• Field QC samples, including trip blanks (TBs), equipment blanks (EBs), and FDs
• Laboratory reporting limits, including limits of detection (LODs) and limits of quantitation (LOQs)
• Method blanks (MBs)

Appendix A – Quality Control Summary Report A-2
2024 Spring Gravel Pit Well WIN-9549 Sampling Event Results and Quality Control Summary Report
Tooele Army Depot North, Utah
• Laboratory control sample (LCS) and laboratory control sample duplicate (LCSD) recoveries
• Surrogate spike recoveries
• Matrix spike (MS) and matrix spike duplicate (MSD) recoveries
• Initial and continuing calibration summary information
• Internal standards performance (GC/MS)
• Precision, including RPD values for duplicate analyses
• Case narrative review, laboratory flagging review, and other analytical method-specific criteria
The data quality review and assessment identified results requiring qualification and potential effects on
data usability based on the measurement performance criteria (MPC) defined in the QAPP. The following
MPC were used for this data quality review and assessment:
• Precision is a measure of the reproducibility of measurements, which can be used to verify
laboratory procedures, determine matrix effect, or sample homogeneity. Precision was
measured by the RPD between LCS and LCSDs, MS and MSDs, or primary and FD results.
• Accuracy is a measure of the correctness or closeness to the true value. Accuracy was evaluated
by reviewing the following elements: calibrations, surrogates, LCS, LCSD, MS, MSD, MBs, relative
response factors and relative standard deviations, tune criteria, second column confirmations,
and internal standards.
• Representativeness is a measure of the degree to which the samples reflect the site
characteristics. Representativeness was measured by reviewing sampling design, sampling
procedures, sample documentation, holding times, and preservations.
• Completeness is a measure of the amount of valid data obtained compared to the amount that
was expected to be obtained under correct, normal conditions. For completeness requirements,
valid results were all results not rejected and determined to be usable in the context of the
DQOs. Completeness was evaluated for each analytical method for a particular sampling event
with respect to each DQO or end data use. The completeness goal is 90% for this project.
• Comparability is a measure of the confidence with which one data set can be compared to
another. The following were reviewed to ensure comparability: use of standard methods for
sampling and analysis, reporting in standard units, operating instruments within calibrated
ranges, and using standard and comprehensive reporting formats.
• Sensitivity is a measure of the ability of a method or instrument to detect the target analyte at
the level of interest. The laboratory-specific limits were evaluated against the project PALs to
determine whether the analytical methods and/or laboratory procedures were able to meet the
project DQOs.
The qualifiers listed in Table 1 were applied to the analytical data set, as appropriate.

Appendix A – Quality Control Summary Report A-3
2024 Spring Gravel Pit Well WIN-9549 Sampling Event Results and Quality Control Summary Report
Tooele Army Depot North, Utah
Table 1 Data Qualifiers
QUALIFIER DESCRIPTION
U The analyte was analyzed for, but not detected, or the analyte was detected in the sample at a concentration
less than or equal to 5 times (10 times for common laboratory contaminants) the blank concentration.
J
The analyte was positively identified, and the quantitation is an estimation because of discrepancies in
meeting certain analyte-specific QC criteria. Or the analyte was positively identified, but the associated
concentration is estimated above the DL and below the LOQ.
J+ The analyte is considered an estimated value with a possible high-bias due to a QC deviation.
J- The analyte is considered an estimated value with a possible low-bias due to a QC deviation.
UJ The analyte was not detected; however, the result is estimated because of discrepancies in meeting certain
analyte-specific QC criteria.
X
The sample results were affected by serious deficiencies in the ability to analyze the sample and to meet
published method and project QC criteria. The presence or absence of the analyte cannot be substantiated by
the data provided. Acceptance or rejection of the data should be decided by the project team, but exclusion
of the data is recommended.
Notes:
For definitions, refer to the Acronyms and Abbreviations section.

Qualification was not required in the following circumstances:
• Surrogate or MS recoveries were outside QC limits, and dilution of the sample resulted in
surrogate or spike dilution to a level beyond quantitation.
• MS recoveries were outside QC limits, and the spiked concentration was less than four times
that of the parent sample.
• An analyte was detected in the associated blank, but there was no detection in the associated
sample.
• MS/MSD or LCS/LCSD recoveries exceeded upper control limits and there was no detection in
the sample(s).
Data quality exceptions that do not result in qualifications are not discussed in this report.
3.0 CHEMICAL DATA QUALITY REVIEW
The data verification and QCSR were performed to assess the overall quality and usability of the
data collected to support sampling activities for the Gravel Pit Well (WIN-9549) Groundwater Sampling
event.
Complete details for the review and evaluation of field samples and associated QC samples are included
in this QCSR. During the data quality review, analytical results or recoveries that fell outside acceptance
criteria were identified and qualifiers were applied to the results, where appropriate, in accordance with
the project QAPP. Qualified results are considered estimated, and whenever possible, direction of
potential bias was assigned and effects on usability are discussed.

Appendix A – Quality Control Summary Report A-4
2024 Spring Gravel Pit Well WIN-9549 Sampling Event Results and Quality Control Summary Report
Tooele Army Depot North, Utah
3.1 Analytical Sample and Field Quality Control Sample Summary
A total of one primary groundwater sample, one FD groundwater sample, and one TB were collected and
analyzed in support of project activities. The sample summary table in Attachment A-1 includes all field
samples submitted to the analytical laboratory.
The overall project-required frequency of one FD for every 10 or fewer primary samples, per analyte, per
matrix, was met.
An MS/MSD was collected and submitted to the laboratory at the project-required frequency of one set
for every 20 or fewer project samples (5%). A designated MS/MSD sample was included in the shipment
of samples; however, the laboratory did not always perform an MS/MSD on a project sample in every
preparatory batch.
EBs were not collected as all samples were collected with disposable sampling equipment.
A TB was included in the cooler containing samples for volatile organic analysis (i.e., SW8260C).
3.2 Sample Handling and Chain-of-Custody
CoC forms and laboratory case narratives were reviewed to assess sample handling procedures that may
affect the integrity of the samples and quality of the resulting data. Copies of CoCs and cooler receipt
forms are included in the final laboratory report. Samples were required to be maintained at 0 to
6 degrees Celsius (°C) following collection, during storage, and upon receipt at the laboratory.
Samples were packed with frozen gel packs in accordance with the Brice packaging and shipping SOP
BE-SOP-03 (Labeling, Packaging, and Shipping Samples). Samples were shipped to EMAX in Torrance,
California, via FedEx. All sample coolers containing groundwater samples were received with temperature
blank and ambient cooler temperatures between 0 and 6°C.
3.3 Sample Preservation and Holding Time Compliance
All samples were extracted and/or analyzed within the recommended holding times and were properly
preserved for the analytical procedures used for this project.
3.4 Sample Limits of Detection and Limits of Quantitation
Sample LOQs and LODs for non-detects were compared to PALs to determine whether the laboratory data
met the MPC for sensitivity. PALs for groundwater analytical results were compared to limits listed in
Table X-2 of the TEAD Post-Closure Permit (TEAD 2023), or where no post-closure permit value exists, the
results were compared to EPA MCLs, if available.
3.5 Blanks
The following sections describe the results of the review and assessment of data for each analytical
method. QC parameters met project MPCs and DoD QSM v.5.4 criteria except where noted.
3.5.1 Method Blanks
An MB was included with each preparatory batch of 20 or fewer samples, as required. MB detections are
indicative of laboratory cross-contamination.

Appendix A – Quality Control Summary Report A-5
2024 Spring Gravel Pit Well WIN-9549 Sampling Event Results and Quality Control Summary Report
Tooele Army Depot North, Utah
No target analytes were detected in the MBs.
3.5.2 Trip Blanks
A TB was included with each cooler containing volatile samples, as required. TB detections are indicative
of shipment and storage cross-contamination.
No target analytes were detected in the TB.
3.6 Laboratory Control Samples
An LCS or LCS/LCSD pair was included with each preparatory batch, as required. LCS and LCSD percent
recovery and LCS/LCSD RPD were compared to the project MPC. LCS/LCSD recoveries were within control
limits and LCS/LCSD precision was within the RPD limit.
3.7 Matrix Spike Samples and Duplicates
Project-specific MS/MSD samples were collected and submitted at the project-required frequency of one
for each preparatory batch and one MS/MSD per 20 or fewer samples. MS and MSD samples were
prepared and analyzed for each laboratory batch with the following exception:
24E186: SW8260C batch CVO01E1113 did not contain an MS/MSD.
MS/MSD recoveries and MS/MSD RPD were compared to project MPCs and met acceptance criteria.
3.8 Surrogates
Surrogates were included with all laboratory QC and field samples, as required. Surrogate recoveries were
reviewed and compared to project MPC. All surrogate recoveries were within control limits for laboratory
QC and field samples.
3.9 Field Duplicate Precision
FD precision was evaluated by calculating the RPD between the parent sample result and the FD result
when both results were above the LOQ, and when one result fell between the LOD and the LOQ.
Acceptance criteria were less than 30% for water results.
A total of one FD sample was submitted and analyzed for one primary groundwater sample. The FD pair
was analyzed by Method SW8260C.
Attachment A-3 summarizes the FD detections that were included in precision evaluations.
3.10 Additional Quality Control Discrepancies
No additional QC items that required data qualification were identified.

Appendix A – Quality Control Summary Report A-6
2024 Spring Gravel Pit Well WIN-9549 Sampling Event Results and Quality Control Summary Report
Tooele Army Depot North, Utah
4.0 COMPLETENESS
Completeness is a measure of the amount of valid data obtained compared with the amount that was
expected to be obtained under correct, normal conditions. For completeness requirements, valid results
are all results not rejected and determined to be usable in the context of project DQOs.
Completeness was evaluated using the formula below. The goal for completeness was 90% for all
methods and matrices. % 𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶 = 100 𝑥𝑥 (𝑉𝑉𝐶𝐶 )
Where: V = number of measurements judged valid
n = total number of measurements
No results were rejected and all results were considered usable. The overall project completeness for this
event is 100%.
5.0 OVERALL DATA QUALITY AND USABILITY ASSESSMENT
The overall quality of the project data was acceptable and completeness goals were met, as no data were
qualified during the data review process.
6.0 REFERENCES
Brice Engineering, LLC (Brice). 2022. Final Uniform Federal Policy Quality Assurance Project Plan Tooele
Army Depot North, Utah. February.
Department of Defense (DoD). 2019. General Data Validation Guidelines. November.
DoD. 2020. Data Validation Guidelines Module 1: Data Validation Procedure for Organic Analysis by
GC/MS. May.
DoD. 2021. Quality Systems Manual for Environmental Laboratories, Version 5.4. October.
Tooele Army Depot. 2023. Part B Permit: Tooele Army Depot North (TEAD-N). EPA ID UT3213820894.
October.
U.S. Environmental Protection Agency (EPA). 2022. Test Methods for Evaluating Solid Waste:
Physical/Chemical Methods Compendium (SW-846), through Revision 7. July.

Attachment A-1
Sample Summary

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Field Sample ID Location
Begin 
Depth
End 
Depth Matrix Sample Type Sample 
Method Sampling Date Lab SDG Analysis
TEAD‐05‐24‐WIN9549 WIN‐9549 0 0 GW N/MS/MSD G 5/23/2024 EMXT  24E186 VOCs by SW8260C
TEAD‐05‐24‐S‐WIN9569 WIN‐9549 0 0 GW FD G 5/23/2024 EMXT  24E186 VOCs by SW8260C
TB20240523 Trip Blank ‐‐ ‐‐GW TB ‐‐5/23/2024 EMXT  24E186 VOCs by SW8260C
Notes:
EMXT – EMAX Laboratories, Inc.
FD – field duplicate
G – grab
GW – groundwater
MS – matrix spike
MSD – matrix spike duplicate
N – normal sample
SDG – sample delivery group
TB – trip blank
VOC – volatile organic compound
Attachment A‐1  Sample Summary
2024 Spring Gravel Pit Well WIN‐9549 Sampling Event
Tooele Army Depot North, Utah
Page 1 of 1
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Attachment A-2
Data Summary Table

This page intentionally blank
Trip Blank
TEAD‐05‐24‐WIN9549 TEAD‐05‐24‐S‐WIN9569 TB20240523
5/23/2024 5/23/2024 5/23/2024
NFDTB
VOC (µg/L) Matrix Screening Limit Type PAL
1,1,1‐Trichloroethane GW Table X‐2 of PCP 200 0.20 U0.20 U0.20 U
1,1,2‐Trichloroethane GW Table X‐2 of PCP 5 0.20 U0.20 U0.20 U
1,1‐Dichloroethane GW Table X‐2 of PCP 170 0.20 U0.20 U0.20 U
1,1‐Dichloroethene GW Table X‐2 of PCP 7 0.20 U0.20 U0.20 U
1,2‐Dichloroethane GW Table X‐2 of PCP 5 0.25 J0.26 J 0.20 U
1,2‐Dichloroethene GW Table X‐2 of PCP 70 0.20 U0.20 U0.20 U
Carbon Tetrachloride GW Table X‐2 of PCP 5 1.4 1.4 0.20 U
Chloroform GW Table X‐2 of PCP 100 0.29 J0.28 J 0.20 U
cis‐1,2‐Dichloroethene GW Table X‐2 of PCP 70 0.20 U0.20 U0.20 U
Methylene chloride GW Table X‐2 of PCP 5 1.0 U1.0 U1.0 U
Tetrachloroethene GW Table X‐2 of PCP 5 0.30 U0.30 U0.30 U
Trichloroethene GW Table X‐2 of PCP 5 33 34 0.20 U
Highlighted cells indicate detections that exceed the selected screening level. 
µg/L – micrograms per liter
FD – field duplicate
GW – groundwater
J – the result is an estimated value based on a QC issue and/or is less than the LOQ.
LOD – limit of detection
LOQ – limit of quantitation
N – normal
PAL – project action level
PCP – post closure permit
TB – trip blank
U – not detected; the compound/analyte was analyzed for, but not detected above the LOD unless otherwise noted
VOC – volatile organic compound
Attachment A‐2   Data Summary Table
2024 Spring Gravel Pit Well WIN‐9549 Sampling Event
Tooele Army Depot North, Utah
WIN‐9549
Notes:
Detected results appear in bold font.
Sample Date:
Sample Type:
Location ID:
Field Sample ID:
Page 1 of 1
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Attachment A-3
Field Duplicate Precision Report

This page intentionally blank
TEAD‐05‐24‐WIN9549
24E186‐02N
05/23/2024
N
VOCs by SW8260C Units Result Result RPD (%)
1,1,1‐Trichloroethane µg/L 0.20 U0.20 UNC
1,1,2‐Trichloroethane µg/L 0.20 U0.20 UNC
1,1‐Dichloroethane µg/L 0.20 U0.20 UNC
1,1‐Dichloroethene µg/L 0.20 U0.20 UNC
1,2‐Dichloroethane µg/L 0.25 J0.26 JNC*
1,2‐Dichloroethene µg/L 0.20 U0.20 UNC
Carbon Tetrachloride µg/L 1.4 1.4 0.00
Chloroform µg/L 0.29 J0.28 JNC*
cis‐1,2‐Dichloroethene µg/L 0.20 U0.20 UNC
Methylene chloride µg/L 1.0 U1.0 UNC
Tetrachloroethene µg/L 0.30 U0.30 UNC
trans‐1,2‐Dichloroethene µg/L 0.20 U0.20 UNC
Trichloroethene µg/L 33 34 2.99
Notes:
Bold – detected results appear in bold font.
* Both results were detected less than the LOQ and relative percent difference was not calculated.
µg/L – micrograms per liter
FD – field duplicate
ID – identification
J – the reported result is an estimated value
LOD – limit of detection
LOQ – limit of quantitation
N ‐ normal sample
NC – not calculated; both results were not detected or both results were less than the LOQ.
RPD – relative percent difference
QC – quality control
U – not detected; the analyte was analyzed for, but not detected above the LOD unless otherwise noted.
VOC – volatile organic compound
WIN‐9549
Sample Date: 05/23/2024
Field QC: FD
Location ID:
Field Sample ID: TEAD‐05‐24‐S‐WIN9569
Lab Sample ID: 24E186‐01
Attachment A‐3  Field Duplicate Precision Report
2024 Spring Gravel Pit Well WIN‐9549 Sampling Event
Tooele Army Depot North, Utah
Page 1 of 1
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Attachment A-4
Data Validation Reports

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Data Validation Report for 24E186
SDG:
Facility:
Guidance Document:
Event:
Data Review Contractor:
Data Review Level:
24E186
USAEC, TEAD-N
FINAL Uniform Federal Policy - Quality Assurance Project Plan Tooele Army
Depot North, Utah, February 2022
2024.05 Gravel Pit Well WIN-9549 Sampling
Synectics, Sacramento, CA
S4VEM
Project Manager:
Date Submitted:
Andrew Castor
July 29, 2024
Primary Data Reviewer:Calvin Tanaka, Data Review Chemist
Field Sample ID Lab Sample ID Matrix Type/Type Code SW
8
2
6
0
C
TB20240523 24E186-03 Water Trip Blank/TB X
TEAD-05-24-S-WIN9569 24E186-01 Water Field Duplicate/FD X
TEAD-05-24-WIN9549 24E186-02N Water Field Sample/N X
Second Reviewer:Kathryn Cantone, Senior Scientist
Contract Laboratory(ies):EMAX Laboratories, Inc., Torrance, CA
Prime Contractor:Brice Environmental Services Corporation, Salt Lake City, UT
eQAPP Version: eQAPP_TEAD-TEAD-TEAD-PHASE.000000
ENV.ADR
July 29, 2024 Page 1 of 7
Data Validation Report for 24E186
This report assesses the analytical data quality associated with the analyses listed on the preceding cover
page at S4VEM data validation level. This assessment has been made through a combination of automated
data review (ADR) and supplemental manual review, the details of which are described below. The approach
taken in the review of this data set is consistent with the requirements contained in the FINAL Uniform Federal
Policy - Quality Assurance Project Plan Tooele Army Depot North, Utah, February 2022 and the additional
guidance documents incorporated by reference to the extent possible. Where definitive guidance is not
provided, results have been evaluated in a conservative manner using professional judgment.
Sample collection was managed and directed by Brice Environmental Services Corporation, Salt Lake City,
UT; analyses were performed by EMAX Laboratories, Inc., Torrance, CA and were reported under sample
delivery group (SDG) 24E186. Data have been evaluated electronically based on electronic data deliverables
(EDDs) provided by the laboratory, and hard copy data summary forms have also been reviewed during this
effort and compared to the automated review output by the reviewers whose signatures appear on the
following page. Findings based on the automated data submission and manual data verification processes are
detailed in the ADR narrative and throughout this report.
All quality control (QC) elements associated with this SDG have been reviewed by a project chemist in
accordance with the requirements defined for the project. This review is documented in the attached Data
Review Checklists. The QC elements listed below were supported by the electronic deliverable and were
evaluated using ADR processes.
Results of the ADR process were subsequently reviewed and updated as applicable by the data review
chemists identified on the signature page. Quality control elements that were not included in the electronic
deliverable were reviewed manually and findings are documented within this report. Summaries of findings
and associated qualified results are documented throughout this report.
A total of 0 results (0.00%) out of the 39 results (sample and field QC samples) reported are qualified based
on review and 0 results (0.00%) have been rejected or deemed a serious deficiency (X qualifier). Trace
values, defined as results that are qualified as estimated because they fall between the detection limit and the
reporting limit/limit of quantitation, are not counted as qualified results in the above count. The qualified
results are detailed throughout this report and discussed in the narrative below, where appropriate.
Continuing Calibration Verification
Field Duplicate RPD
Lab Blank
LCS Recovery
LCS RPD
MS Recovery
MS RPD
Prep Hold Time
Surrogate
Test Hold Time
Trip Blank
eQAPP Version: eQAPP_TEAD-TEAD-TEAD-PHASE.000000
ENV.ADR
July 29, 2024 Page 2 of 7
Data Validation Report for 24E186
Sample 24E186-01 underwent S4VEM review and the remaining samples S2BVEM.
Analytical Method Data Reviewer Comment
SW8260C No additional comments; see Checklist for detail.
Narrative Comments
Reviewed by Calvin Tanaka, Data Review Chemist, Synectics,
Sacramento, CA
July 18, 2024
Reviewed by Kathryn Cantone, Senior Scientist, Synectics,
Sacramento, CA
July 29, 2024
As the First Reviewer, I certify that I have performed a data review process in accordance with the
requirements of the project guidance document, and have compared the electronic data to the laboratory's
hard copy report and have verified the consistency of the reported sample results and method quality control
data between the two deliverables.
As the Second Reviewer, I certify that I have performed a quality assurance review of the report generated
by the First Reviewer.
eQAPP Version: eQAPP_TEAD-TEAD-TEAD-PHASE.000000
ENV.ADR
July 29, 2024 Page 3 of 7
Data Validation Report for 24E186
No Outliers were associated with this sample delivery group.
Qualified Results
No results associated with this sample delivery group required qualification.
Reason Code Definitions
Code Definition
TR Trace Level Detect
Flag Code and Definitions
Flag Definition
J Estimated Value
N The analysis indicates the presence of an analyte for which there was presumptive evidence to make a tentative identification.
NJ
The analyte has been tentatively identified or presumptively as present
and the associated numerical value was the estimated concentration in
the sample.
R The data are rejected due to deficiencies in meeting QC criteria and may not be used for decision making.
U Undetected: The analyte was analyzed for, but not detected.
UJ The analyte was not detected; however, the result is estimated due to discrepancies in meeting certain analyte-specific quality
control criteria.
X Result may require rejection; PDT attention required
Bias
-The result may be biased low
+The result may be biased high
eQAPP Version: eQAPP_TEAD-TEAD-TEAD-PHASE.000000
ENV.ADR
July 29, 2024 Page 4 of 7
Data Validation Report for 24E186
Note - The bias field is a separate field; however, it is an integral part of the final flag (qualifier) on the sample result
eQAPP Version: eQAPP_TEAD-TEAD-TEAD-PHASE.000000
ENV.ADR
July 29, 2024 Page 5 of 7
Data Validation Report for 24E186
Review Questions
Method: SW8260C (Volatile Organic Compounds by GC/MS)
Review Questions Yes No NA Comment
Were there discrepancies between the COC and the
samples received?•
Were there discrepancies between the COC and the
sample labels?•
Were samples relinquished properly on the COC?•
Were all samples properly preserved?•
Were sampling dates/times, date and time of laboratory
receipt of samples, and sample conditions upon receipt
at the laboratory (including preservation, pH, and
temperature) documented?
•
Were sample results reported with percent moisture
correction if required?•
Were analytical methods performed and analysis dates
present?•
Were all requested target analytes reported?•
Were QAPP specified Project Quantitation Limit Goals
achieved? (The laboratory LOQ is compared to the
QAPP Project Quantitation Goal)
•
Were holding times met?•
Were trip blanks analyzed at the proper frequency and in
control?•
Were field blanks analyzed at the proper frequency and
in control?•
Were equipment blanks analyzed at the proper frequency
and in control?•
Was a method blank prepared and analyzed with each
batch?•
Were target analytes in the method blank less than DL?•
Was an LCS/LCSD pair prepared and analyzed with each
batch?•
Were LCS/LCSD recoveries within project acceptance
limits?•
Was the LCS/LCSD RPD within project acceptance
limits?•
Was a MS/MSD pair prepared with each batch?•One of two batches had SDG specific MS/MSD
Were MS/MSD recoveries within project acceptance
limits?•
Was the MS/MSD RPD within project acceptance limits?•
If ISM was used for sample collection, were laboratory
triplicates analyzed and within project acceptance limits?•
Were surrogate recoveries within project acceptance
limits?•
Were field replicates (duplicates, triplicates, etc.)
analyzed at the proper frequency and in control?•
Were reported sample concentrations within calibration
range?•
Was the GC/MS system properly tuned based on method
criteria?•
Was instrument tuning completed every 12 hours during
sample analysis?•
Was the Calibration within project acceptance criteria?•
eQAPP Version: eQAPP_TEAD-TEAD-TEAD-PHASE.000000
ENV.ADR
July 29, 2024 Page 6 of 7
Data Validation Report for 24E186
Review Questions
Method: SW8260C (Volatile Organic Compounds by GC/MS)
Review Questions Yes No NA Comment
Was a ICV performed after each ICAL prior to sample
analysis and within project acceptance criteria?•
Were CCVs run at the required frequency and within
project acceptance criteria?•
Were internal standard retention times and area criteria
within project acceptance criteria?•
Were internal standards spiked for every sample,
standard, and QC sample?•
Were instrument run logs present and filled out
appropriately?•
Were sample preparation sheets present and filled out
appropriately?•
Were certificates of standard traceability and
documentation of standard solution preparation provided?•
Were recalculation of QC Elements and Sample Results
performed?•
Were Relative Retention Times (RRTs) within ± 0.06
RRT units (may be updated based on daily CCV)?•
Were chromatograms checked for peak integration?
(10% of automated integration and 100% of manual
integrations)
•
Were chromatograms checked for correct baseline/peak
integration and possible interferences?•
Were qualitative ion mass present?•
Have all Laboratory Case Narrative comments/findings
been addressed in the data review process?•
Were DoD QSM corrective actions followed if deviations
were noted?•
Were any data recommended for exclusion in the data
validation process?•
eQAPP Version: eQAPP_TEAD-TEAD-TEAD-PHASE.000000
ENV.ADR
July 29, 2024 Page 7 of 7
SDG #:24E186 Date: 7/18/2024
Lab:Emax Page: 1 of 1
Client:Brice Validated by: CT
Matrix:Water Second Review by: KMC
Tune ID: REV528.D
Recalculated Ion Ratio: 176:174
Reported Ratio: 96.2%p. 122
Relative Abundance (Ion Ratio) = Response of Target Mass × 100%
Response of Reference Mass
Target Mass Response = 16406 p. 122
Reference Mass Response = 17060 p. 122
Calculated Ratio = 96.2%Match
S4VEM
INSTRUMENT PERFORMANCE CHECK / TUNE
EPA 8260C
CALCULATIONS
Inst Perf
SDG #:24E186 Date: 7/18/2024
Lab:Emax Page: 1 of 1
Client:Brice Validated by: CT
Matrix:Water Second Review by: KMC
RRF Standard ID: REV198.D
Analyte: Chloroform
Calibration Level: 3
Reported Calibration RRF: 0.594 p. 60
RRF = Analyte Resp. × ISTD Conc.
ISTD Resp. × Analyte Conc.
Analyte Response = 55743 p. 73
ISTD Response = 938282 p. 73 ISTD: 1,4-Difluorobenzene
Analyte Conc. = 1.0 p. 73
ISTD Conc. = 10.00 p. 73
Calculated RRF = 0.594 Match
Calibration ID: ICAL 05/11/24
Analyte: Carbon tetrachloride
Reported Average RRF: 0.382 p. 60
Reported %RSD: 4.43%p. 60
%RSD = Standard Deviation × 100%
Average RRF
RF Lvl 1: 0.390 RF Lvl 6: 0.365
RF Lvl 2: 0.393 RF Lvl 7: 0.403
RF Lvl 3: 0.352 RF Lvl 8: 0.383
RF Lvl 4: 0.387 RF Lvl 9: 0.403
RF Lvl 5: 0.366 RF Lvl 10: 0.374
Standard Deviation = 0.017
Calculated Average RRF = 0.382 Match
Calculated %RSD = 4.45%Match
S4VEM
INITIAL CALIBRATION
EPA 8260C
CALCULATIONS
ICAL
SDG #:24E186 Date: 7/18/2024
Lab:Emax Page: 1 of 1
Client:Brice Validated by: CT
Matrix:Water Second Review by: KMC
%D = 100% × ( CV RRF - Avg RRF ) / Avg RRF RRF = Analyte Resp. × ISTD Conc.
ISTD Resp. × Analyte Conc.
ICV ID: REV210
Analyte: 1,2-Dichloroethane
ISTD: 1,4-Difluorobenzene
Reported ICV RRF: 0.279 p. 113
Reported %D: -3.7%p. 113
Analyte Response = 252838 p. 116
ISTD Response = 907856 p. 115
Analyte Conc. = 10.0 p. 116
ISTD Conc. = 10.00 p. 115
Mean RRF (ICAL) = 0.269 p. 113
Calculated ICV RRF =0.279 Match
Calculated %D = 3.7%Match
CCV ID: REV530
Analyte: Trichloroethene
ISTD: 1,4-Difluorobenzene
Reported CCV RRF: 0.346 p. 127
Reported %D: 0.0%p. 127
Analyte Response = 293811 p. 130
ISTD Response = 847951 p. 129
Analyte Conc. = 10.0 p. 130
ISTD Conc. = 10.00 p. 129
Mean RRF (ICAL) = 0.346 p. 127
Calculated CCV RRF =0.346 Match
Calculated %D = 0.1%Match
S4VEM
INITIAL / CONTINUING CALIBRATION VERIFICATION
EPA 8260C
CALCULATIONS
ICV-CCV
SURROGATE SPIKES/SYSTEM MONITORING COMPOUNDS
SDG #:24E186 Date: 7/18/2024
Lab:Emax Page: 1 of 1
Client:Brice Validated by: CT
Matrix:Water Second Review by: KMC
Sample ID: TEAD·05·24·S·WIN9569 / 24E186-01
Compound ID: 1,2-Dichloroethane-d4
Reported %Recovery: 109%p. 10
% Recovery = Conc. Surr. In Sample × 100%
Conc. Surr. Spiked
Conc. In Sample = 10.9 p. 10
Surr. Spike Conc. = 10.0 p. 10
Calculated %Recovery = 109% Match
CALCULATIONS
S4VEM
EPA 8260C
Surr
SDG #:24E186 Date: 7/18/2024
Lab:Emax Page: 1 of 1
Client:Brice Validated by: CT
Matrix:Water Second Review by: KMC
LCS Sample ID: V001E25L
Analyte: Carbon tetrachloride
Reported %Recovery: 103%p. 25
%Recovery = Conc. LCS × 100%
LCS Spike Conc.
Conc. LCS = 10.3 p. 25
LCS Spike Conc. = 10.0 p. 25
Calculated %Recovery = 103% Match
LCS/LCSD Sample ID: V001E25L / V001E25C
Analyte: Trichloroethene
Reported RPD: 6%p. 25
RPD = | LCS Conc. - LCSD Conc.| × 100%
(LCS Conc. + LCSD Conc.)/2
LCS Conc. = 9.96 p. 25
LCSD Conc. = 9.35 p. 25
Calculated RPD = 6% Match
S4VEM
EPA 8260C
LABORATORY CONTROL SAMPLES
CALCULATIONS
LCS
SDG #: 24E186 Date: 7/18/2024
Lab: Emax Page: 1 of 1
Client: Brice Validated by: CT
Matrix: Water Second Review by: KMC
Sample ID: TEADꞏ05ꞏ24ꞏSꞏWIN9569 / 24E186-01
Compound ID: Carbon Tetrachloride
Reported Result (µg/L): 1.4 p. 10
Raw Data Result (µg/L): 1.37 p. 11
Conc. In Sample = Analyte Resp. × Conc. of IS × Final Volume × Dilution Factor
IS Resp. Average RRF Initial Amount
Analyte Response = 44648 p. 11
IS Response = 855624 p. 11 IS: 1,4-Difluorobenzene
IS Conc. = 10.00 p. 11
Average RRF = 0.382 p 60
Final Volume (mL) = 25 p. 10
Initial Amount (mL) = 25 p. 10
Dilution Factor = 1 p. 10
Conc. In Sample (µg/L) = 1.4 Match
S4VEM
EPA 8260C
SAMPLE RESULT VERIFICATION
CALCULATIONS
Rslt Ver
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APPENDIX B
FIELD FORMS

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GROUNDWATER SA M PLING DATA FORM
Project Name: L[t-\ D -ld.___
Project Number: ------
Sampling Team: _ (_ i,1,\ ~( L / L _ ----
Sample ID: T €Av -D5 -'2.4 -W}fv15,ft
T[ Ai)··os ·-ZA--S • W1.AJ1S-lc1
T[~ D -045 --i L{ -wl 0q f'{l
Sample ID:
Sample ID:
Depth to Top of Product (BTOC):
Depth to Oil/Water Interface (BTOC):
Casing Diameter:
liters/ft of casing:
Pump Intake Depth:
Stable DTW (B TOC):
1 in.
0.16
Method of Purging (circle one):
----
Pump: SUB BLDR PERIST OTHER :
2in.
0.62
4in.
2.47
Da te:
Start Time: I~
End Time: _1~6
Time: \ 3o5" /:'
Time : -rzfls C:/ pri mary -
Time: \ 3o.F -
primary
To tal Depth (B TOC):
Depth to Water (BTOC) --
Water Column (ft) Ca sing
Volume (liters)
Screen Interval Measured --
Stick-up
Bailer: TEFLON SS OTHER:
dup
&j;'
dup
othe r:
othe r:
Pu mp Type: Flow Rate (1pm): Requ ired Pulls: Bai ler Vol. (gal): 0.25 / 0.33
Pump T ime:
Time
To tal Volume
Purged
(l iters)
Water Level
(ft BTOC) Draw Down
Vol. Purged (gal):
WELL STABILIZATION DAT A
Temp.
(°F or 0 C)
±3%
p H
± 0.1
~-----
Conducti v ity
(µSiem)
±3%
O RP
(mV)
±10mV
-----
_ _J 3 _/ 4.___---'-Pc.r C\ ~--\---r vt'-&l f _ '"Skel-+ _ I b ,2.-I 0-=---c?.-'----'--7.:....._. I..\ 7 ~
"' -------I ----------·-+------_ _,_ ____ ------
0 .0.
(mg/L)
± 10%
Turbidity
(NTU)
± 10% or <10 NTU
( I
Notes: Drawdown should be less than 0.3 feet from the original DTW. Minimal drawdown achieved and measured by: 1) pumping at a low ra te (approx. 1 liter/3 minutes or
0.26 gallons/3 minutes or 50-500 mUmin) and 2) continually measuring water levels in the well.
Sample after 1) removing min . of 3 casing volumes or 2) min. of 3 parameters stabilize (4, if using temp.), or 3) for low yield wells, entire we ll casing is evacuated (ADEC, 2013).
Sensory Observations
Color: ~r. Amber, Tan, Brown, Gray, Milky White, Other
Odor:
T urb idity:
Comments:
N,Qoe, Low , Medium , Hi gh, Very Strong, H2S, Fuel-Like, Ch emical ?, Unknown
~e. Low, Medium , High, Very Turbid, Heavy Silts
Reference: ADEC, 2013. Monitoling Well Guidance , September. GW Sampling Form
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APPENDIX C
ANALYTICAL LABORATORY REPORTS

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LABORATORIES, INC.
3051 Fujita Street
Torrance, CA90505
Tel: [phone]
Date: 06·18·2024
EMAX Batch No.: 24E186
Attn: Travis Gouveia
8rice
3700 Centerpoint Dr. Suite 8223
Anchorage. /lJ< 99503
Subject: Laboratory Report
Project: TEAD·N
Enclosed is the Laboratory report for samples received on OS/29/24.
The data reported relate only to samples listed below:
Sample 10 Control # Col Date Matrix
___ M ___ M_ ••••••••
TEAD· 05·24· S· WIN9569 E186·01 OS/23/24 WATER
TEAD· 05·24· WIN9549 E186·02 OS/23/24 WATER
TB20240523 E186·03 OS/23/24 WATER
TEAD·05·24·WIN9549MS E186·02M OS/23/24 WATER
TEAD· 05·24· WI N9549MSD E186·02S OS/23/24 WATER
The results are summarized on the following pages.
Please feel free to call if you have any questions concerning
these results.
Caspar J. Pang
Laboratory Di rector
L
Analysis
VOCS BY 8260C
VOCS BY 8260C
VOCS BY 8260C
VOCS 8Y 8260C
VOCS BY 8260C
This report is confidential and intended solely for the use of the individual or
entity to whom it is addressed. This report shall not be reproduced except in full
or without the written approval of EMAX.
EMAX certifies that results included in this report meets all TNI & DOD requirements
unless noted in the Case Narrative.
NELAP Accredited Certificate Number CA002912023·25
ANAB Accredited 000 ELAP and ISOIIEC 17025 Certificate Number L2278 Testing
California ELAP Accredited Certificate Number 2672
REPORT ID: 24E186 Page 1 of 217
CHAIN-OF-CUSTODY RECORD Brice Engineering, Salt Lake City, UT COC # 202405GPW
Andrew Castor [phone], [e-mail]
362 W. Pierpont Ave
SLC. UT 84101
Project Name: USAEC, TEAD-N
Project Number: TEAD-N 770108
WBS Code:
Comments:
SW8260C (F) ~ VOCs Short List
Notes
Event: 2024.05 Gravel Pit Well WIN-9549 Sampling
Sample ID Matrix Date
1 TEAD-05-24-S-WIN9569 W 5/23/2024
2 TEAD-05-24-WIN9549 W 5/23/2024
3 TB20240523 W 5/23/2024
Turnaround Time: NA
----------------------------------------_ .. _-----
/"-~'~ /-: LIp' Jib 1/ -
LReli~d by: (Siam vrlIV '? (P' ~
Date 5!l.fi3( y:./s/gnature)
Time /hW~
Received by' (5' . Ignature)
GravelPitWellSampleTrackingCOC.xlsx
Time
1205
1305
800
Ui
Cll I-
(ij
.~ ""C
- 0 ~..c: III _
.:: Cll <:2
Samp
Init.
CMH/IL
CMHIIL
CMH/IL
Laboratory: EMAX Laboratories, Inc., Torrance, CA
POC: Caspar Pang; [e-mail]
Ship to: Ship to: 3051 Fujita Street Torrance, CA 90505
u::-
()
0
CD
C\I
<Xl
S
en
7
X
X
X
Code Matrix
W Water
WQ Water Quality Control Matrix
Code I Container/Preservative
7 13x 40 mL VOA vial, HCLto pH < 2. Cool4C
Date
Time
Sample
Location ID Type
WIN-9549 N1
WIN-9549 N1/MS1/SD1
TB WQ
~
Q40
Shipping Date: 5(tdVf
Received by Laboratory: (Signature, Date, Time) & conditio
zye\~Ct
Event: 2024.05 Gravel Pit Well WIN-
9549 Sampling
i
.
Depth (ft bgs)
Top -Bottom Cooler Comments
0.00 0.00 1
0.00 0.00 1
0.00 0.00 1
teJmr ~.\ 0
REPORT ID: 24E186 Page 2 of 217
REFERENCE: EMAX-SM02 Rev. 12
SAMPLE RECEIPT FORM 1
/ Type of Delivety Airbill / Tracking Number ECN 14t:-l0CP
tJ Fedex o UPS o GSO o Others 11US 9B'lfl qOl-Oj Recipient NClhMet1 (\.laCti\VlV\
o EMAX Courier 0 Client Delivery Date (j§ /2/1/24-Time Q40
rOC INSPECTION ,
mpientName !6pient PM/FC 4YSampler Name ~mpling Dateffime p(,Sample ID u1 Matrix
dAddress liTel #/Fax # o Courier Signature Analysis Required ~reservative (if any) o TAT
Safety Issues (if any) o High concentrations expected o From Superfund Si te ORad screening required
Note:
PACKAGING INSPECTION
Container WCooler o Box o Other
C;ondition ~ustodY Seal o Intact o Damaged
Packaging ~ubble Pack o Styrofoam DPopcom o Sut1icient 0
Temperatures Coolerl~ "c o Cooler 2 ___ "c o Cooler 3 ---°c o Cooler 4 ---"c o Cooler 5 ---"c
(Cool, $6 "C but not frozen) o Cooler 6 "c o Cooler 7 "c o Cooler 8 °c cff) Cooler 9 "c o Cooler 10 "c
B -SIN '1-?JOOLNfU, 0
---
D SIN Z2>OOWL/ff51 ---
Thermometer: A • SIN 2J61fDli2;1l. C -SIN! ~OOlfJ.l$11
Comments: o Temperature is out of range. PM was informed IMMEDIA TEL Y.
Note:
DISCREPANCIES
LabSampleID LabSampkContainerID Code ClientSample LabellD / Information COlTective Action
/ /
/ /
/ /
/ /'
/ /
./' /
/' /
/ /
/ /
// A /
t-<Il/?~ 'r1/
0 p H holdin g timere q uirement for water sam p les is 15 mins. Water sam les for p p H anal sis are received be and 1~ minutes from sam y y lin p g time.
NOTES/OBSERVA TlONS:
SAMPLE MATRIX IS DRINKfNG WATER? 0 YES 0 NO
LEGEND:
Code Description-Sample Management
Dl Analysis is not indicated in ___ _
D2 Analysis mismatch COC vs label
D3 Sample ID mismatch COC vs label
D4 Sample ill is not indicated in ___ _
DS Container -[improper] [leaking] [broken]
D6 DatelTime is not indicated in ___ _
D7 DatelTime mismatch COC vs label
D8 Sample listed in COC is not received
D9 Sample received is not listed in COC
DI0 No initial/date on cOlTections in COCllabel
011 Container count mismatch COC vs received
012 Container size mismatch COC vs received
REVIEWS: Ntl~dcC'Vj
Code Description-Sample Management
DB Out of Holding Time
D14 Bubble is >6mm
DIS No trip blank in cooler
DI6 Preservation not indicated in ___ _
DI7 Preservation mismatch COC vs label
D18 Insufficient chemical preservative
019 Insufficient Sample
D20 No filtration info for dissolved analysis
021 No sample for moisture detennination
022 _________________ _
023 -------------------
Sample Labeling NV\ (101 Vl C\
Date -=OC::§"*Z q;;;-T:Z,--;--t--:::rt--:;.;[-f:"'f'"
EMAX Laboratories. Inc. 3051 Fujita St., Torrance. CA 90505
o Continue to next page.
Code Description-Sample Management
RI Proceed as indicated in 0 COC 0 Label
R2 Refer to attached instmetion
R3 Cancel the analysis
R4 Use vial with smallest bubble first
R5 Log-in with latest sampling date and time+ I min
R6 Adjust pH as neeessal)'
R7 Filter and preserved as neeessal)'
R8 ________________ _
R9 __________________________ __
RIO __________________________________ _
RII -----------------------------
R12 -----------------------------------
PM Ut
Date 5.12/1IL4'
REPORT ID: 24E186 Page 3 of 217
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REPORT ID: 24E186 Page 4 of 217
REPORTING CONVENTIONS
DATA QUALIFIERS:
Lab Qualifier AFCEE Qualifier Description
J F Indicates that the analyte is positively identified and the result is less
than LOQ/RL but greater than LOD/MDLlDL.
N Indicates presumptive evidence of a compound.
B B Indicates that the analyte is found in the associated method blank
as well as in the sample at above QC level.
E J Indicates that the result is above the maximum calibration range or
estimated value.
* * Out of QC limit.
Note: The above qualifiers are used to flag the results unless the project requires a different
set of qualification criteria.
ACRONYMS AND ABBREVIATIONS:
CRDL Contract Required Detection Limit
RL Reporting Limit
MRL Method Reporting Limit
MOL Method Detection Limit
DL Detection Limit
LOD Limit of Detection
LOQ Limit of Quantitation
DO Diluted out
DATES
The date and time information for leaching and preparation reflect the beginning date and time of the
procedure unless the method, protocol, or project specifically requires otherwise.
REPORT ID: 24E186 Page 5 of 217
LABORATORY REPORT FOR
BRICE
TEAD-N
METHOD SW5030C/8260C
VOLATILE ORGANICS BY GC/MS
SDG#: 24E186
REPORT ID: 24E186 Page 6 of 217
Client : BRICE
Project: TEAD-N
SDG 24E186
CASE NARRATIVE
METHOD SW5030C/8260C
VOLATILE ORGANICS BY GC/MS
A total of three(3) water samples were received on OS/29/24 to be analyzed for
Volatile Organics by GC/MS in accordance with Method SW5030C/8260C and project
specific requirements.
Holding Time
Samples were analyzed within the prescribed holding time.
Instrument Performance and Calibration
Instrument tune check was performed prior to calibration. Result was within
acceptance criteria. Multi-calibration points were generated to establish
initial calibration (ICAL). ICAL was verified using secondary source (ICV).
Continuing calibration (CCV) was carried out at a frequency required by the
project. There were four(4)CCVs (Data File IDs: REV530, REV55 0 , RFV002 and
RFV025) associated with this SDG. All calibration requirements were satisfied.
Refer to calibration summary forms of I CAL , ICV and CCV for details.
Method Blank
Method blank was prepared and analyzed at the frequency required by the project.
For this SDG, two (2) method blanks were analyzed. V001E25Q and V001F01B were
compliant to project requirement. Refer to sample result summary forms for
details.
Lab Control Sample
Lab control sample was prepared and analyzed at a frequency required by the
project. For this SDG, two (2) sets of LCS/LCD were analyzed. V001E25L/V001E25C
and V001F01L/V001F01C were within LCS limits. Refer to LCS summary forms for
details.
Matrix QC Sample
Matrix spike sample was prepared and analyzed at a frequency required by the
project. For this SDG, one(l) set of MS/MSD was analyzed. 24E186-02M/24E186-02S
-all analytes were within MS QC limits. Refer to Matrix QC summary form for
details.
Surrogate
Surrogates were added on QC and field samples. All surrogate recoveries were
within QC limits. Refer to sample result summary forms for details.
Sample Analysis
Samples were analyzed according to prescribed analytical procedures. Results
were evaluated in accordance to project requirements. For this SDG, all quality
control requirements were met.
REPORT ID: 24E186 Page 7 of 217
Client : BRICE
Project : TEAD·N
Client
Sample ID
LCS1W
LCD1W
MBLK1W
TB20240523
TEAD·05·24·S·WIN9569
LCS2W
LCD2W
MBLK2W
TEAD·05· 24·WIN9549
TEAD-05-24-WIN9549MS
TEAD-05· 24-WIN9549MSD
FN Filename
% Moist Percent Moisture
Laboratory Dilution
Sample ID Factor
V001E25L 1
V001E25C 1
V001E25Q 1
24E186·03 1
24E186·01 1
V001F01L 1
V001F01C 1
V001F01B 1
24E186·02N 1
24E186·02M 1
24E186·02S 1
LAB CHRONICLE
VOLATILE ORGANICS BY GC/MS
WATER
% Analysis Extraction
Moist DateTime DateTime
~ ... ----.. --- --. -. ~ .. -.. --
NA 05/29/2411: 54 05/29/2411:54
NA 05/29/2413:01 05/29/2413:01
NA 05/2912415:03 05/29/2415:03
NA 05/29/2416:02 05/29/2416: 02
NA 05/29/2418: 31 05/29/2418:31
NA 06/03/2411 :49 06/03/2411:49
NA 06/03/2412:18 06/03/2412:18
NA 06/03/2413:20 06/03/2413: 20
NA 06/03/2415:22 06/0312415:22
NA 06/03/2415:52 06/03/2415: 52
NA 06/03/2416:21 06/03/2416:21
SDG NO. : 24E186
Instrument ID : 01
Sample Calibration Prep.
Data FN Data FN Batch Notes
.. --------------.-------
REV531 REV201 V001E25 Lab Control Sample (LCS)
REV532 REV201 V001E25 LCS Dup 1 i cate
REV536 REV201 V001E25 Method Blank
REV538 REV201 V001E25 Field Sample
REV543 REV201 V001E25 Field Sample
RFV003 REV201 V001F01 Lab Control Sample (LCS)
RFV004 REV201 V001F01 LCS Duplicate
RFV006 REV201 V001F01 Method Bl ank
RFV010 REV201 V001F01 Field Sample
RFVOll REV201 V001F01 Matrix Spike Sample (MS)
RFV012 REV201 V001F01 MS Duplicate (MSD)
REPORT ID: 24E186 Page 8 of 217
SAMPLE RESULTS
REPORT ID: 24E186 Page 9 of 217
METHOD SW5030c/8260C
VOLATILE ORGANICS BY GC/MS
Client BRICE
Project TEAD·N
Batch No. 24E186
Sample ID : TEAD·05·24·S·WIN9569
Lab Samp ID: 24E186·01
Lab File ID: REV543
Ext Btch ID: V001E25
Cal ib. Ref.: REV201
RESULTS
PAMMETER(S) (ug/L)
............. -........ _-_. ___ .0._·---
1.1.1· Trichloroethane ND
1.1.2·Trichloroethane ND
1.1· Di ch 1 oroethane ND
1.1· Di ch 1 oroethene ND
1.2· Di ch 1 oro ethane 0.26J
Carbon Tetrachloride 1.4
Chloroform 0.28J
ci s·1.2·Dichloroethene ND
Methylene Chloride ND
Tetrach 1 oroethene ND
Trans ·1. 2 ·Di chl oroethene ND
Trichloroethene 34
1.2· Di ch 1 oroethene (T ota 1 ) ND
SURROGATE P AMMETER (S) RESULT
....... -......... _-----.--•• __ 0 •• ___ -
1.2· Di ch 1 oroethane· d4 10.9
4· Bromofl uorobenzene 9.62
Toluene·d8 9.45
Di bromofl uoromethane 10.6
Notes:
Date Collected: OS/23/24 12:05
Date Received: OS/29/24
Date Extracted: 05129/24 18:31
Date Analyzed: OS/29/24 18:31
Dilution Factor: 1
Matrix: WATER
% Moisture: NA
Instrument ID: 01
LOQ DL LOD
(ug/L) (ug/L) (ug/L)
........... . ........ -. -----------
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
2.0 0.50 1.0
1.0 0.15 0.30
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
SPK_AMT %RECOVERY QC LIMIT
-_ ... --_ ... _._--------...........
10.0 109 81·118
10.0 96 85·114
10.0 94 89·112
10.0 106 80·119
Sample Amount : 25ml Final Volume: 25ml
Prepared by : LPri et Analyzed by : LPri et
Detection limits are reported relative to sample result significant figures.
REPORT ID: 24E186 Page 10 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E29\REV543.D
Acq On 29 May 2024 6:31 pm
Sample 24E186-01
Misc 25mL
(QT Reviewed)
Vial: 16
Operator: LPriet
01 Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: Jun 6 12:21 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Internal Standards R.T. QIon Response Conc units Dev(Min)
1) l,4-DIFLUOROBENZENE 8.54 114 855624 10.00 ug/l 0.00
53) CHLOROBENZENE-D5 13.71 117 708676 10.00 ug/l 0.00
72) l,2-DICHLOROBENZENE-D4 18.67 152 295180 10.00 ug/l 0.00
System Monitoring Compounds
34) Dibromofluoromethane 7.23 111 279647 10.56 ug/l 0.00
Spiked Amount 10.000 Recovery :::= 105.60%
41) l,2-Dichloroethane-d4 7.97 65 196796 10.90 ug/l 0.00
Spiked Amount 10.000 Recovery :::= 109.'c}O%
\
54) Toluene-d8 11.02 98 1003546 9.45 ug/J.,/l -0.02
Spiked Amount 10.000 Recovery :::= 94.50%
76 ) 4-Bromofluorobenzene 15.99 95 386660 9.62 ug/rI/ -0.02
Spiked Amount 10.000 Recovery :::= 96/.20%
Target Compounds Qvalue
31) Chloroform 6.90 83 14717 ;;-" 0.28 ug/l 93
39) Carbon tetrachloride 7.88 119 44648 ~1.37 ug/l 99
43) l,2-Dichloroethane 8.11 62 6034 /0.26 ug/l 91
44) Trichloroethene 9.06 130 1007007 34.06 ug/l 98
,~
(#) :::= qualifier out of range (m) :::= manual integration
REV543.D V001E11.M Thu Jun 06 12:21:48 2024 Page 1
REPORT ID: 24E186 Page 11 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E29\REV543.D
Aeq On 29 May 2024 6:31 pm
Sample 24E186-01
Mise 25mL
Vial:
Operator:
Inst
Multiplr:
16
LPriet
01
1. 00
MS Integration Params: RTE.P
Quant Time: Jun 6 12:21 2024 Quant Results File: V001E11.RES
Method
Title
Last Update
Response via
Abundance
1900000
1800000
1700000
1600000
1500000
1400000
1300000
1200000
1100000
1000000
900000
800000
700000
600000
500000
400000
300000
200000
100000
0 ~
Time--> 2.b6 3.bo 4.bb
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
TIC: REV543.D
~
CI)
00 on
ui "% 0
z c: W " z W :J W N '0 N z f-Z W
In W
0 In
a: 0 CI)
0 a: oi
::> 0 c:
-' -' " I N U. c:
is () " .0 ..!:. e
0
:J q:
0
E
CI) e
In oi ... c:
'" ~
E CI) e .;
0 "% :J
'i5 c:
E '" e 0;
" .0 :e is * ::;: ~ r: .£l~ () "" If _0
.E r~ e
.Q
.s::
()
-.i'-J Trllll!IIIIIIIIIIIIIIIIIIIIIIII~III-·IIII--11 5.bo 6.bo 7.b6 8.bo 9.bb 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.0
~ z
W
N
Z
W
In
~ g
I
()
is
N.
REV543.D V001E11.M Thu Jun 06 12:21:49 2024 Page 2
REPORT ID: 24E186 Page 12 of 217
bundance
RefO
0
Iz-->
bundance
Ra~
0
Iz-->
bundance
Sub
50
o
RefO
0
Iz-->
bundance
Ra~
Sub
50
30
40
47
40 50
5T6J!OZ min): REVZ01.D (-)
83
83
120 , 1~0 ' " I
#31
Chloroform
Concen: 0.28 ug/l
RT: 6.90 min Scan# 364
Delta R.T. -0.00 min
Lab File: REV543.D
Acq: 29 May 2024 6:31 pm
Tgt Ion: 83 Resp: 14717
Ion Ratio Lower Upper
83 100
85 61. 5 38.2 98.2
47 26.6 0.0 54.7
bundance on . Q18Z:7UTolrTIO):R"EV5'ITD
5000 Ion 85.00 (84.70 to 85.70): REV543.D
Ion 47.00 (46.70 to 47.70): REV543.D
4000 6.90
3000
2000
1000
40 50 60 70 80 ,1,9'0'" 160 ' , 110 ' , 120 ' , 'I ime--> Ol;:;:;::;:::;:::;::;:::;:::;::¢;,;:;:::;:::;::;:::;:::;::;:::;:::;:~:;:::;:::;::;:::;:::;:::;::;::;
#39
117 Carbon tetrachloride
Concen: 1. 37 ug/l
RT: 7.88 min Scan# 430
Delta R.T. -0.00 min
43 Lab File: REV543.D
55 87 Acq: 29 May 2024 6:31 pm
37 Tgt Ion:119 Resp: 44648
Ion Ratio Lower Upper
1 7 119 100
117 106.9 74.0 137.4
1 7
6000
4000
2000 47 82
'---/Z_--_>_o~_3-,0:::3~7_4-,-0:'_=_' _'~1_'5'-r1'o:,:,_'~_'6~'o-,-':':,_,,,~_'_0~,,-,:,:'8_,O~1+1:,.~,9_'''0_,~,-'-':1_0"0-,-'~'~'-1:_0,,_~~-,-L_.,L_~_--=~ ___ ==-=;:_~~'::::;7=-';j=;Q--~-t-.!3-Q-~~~--'~""8-.O-~~~~~~_!
REV543.D V001E11.M Thu Jun 06 12:21:50 2024 Page 3
REPORT ID: 24E186 Page 13 of 217
bundance
RefO
Iz-->
bundance
Ra~
bundance
Sub
50
30
62
52
98
90 '6 915' 'n) '1'65 ' ,
62
49
49
Iz-->
O!"'TTTTTTT'T 'TO' ~f,I~~' ,+,11", ,rr, Il-r-I l-rl , or' "fTTT-rrr+-rJ-.t,~"'rrr' rrrrrTTrrT""~~rrrrrrr-r
30 35 40 45 50 55
IAbundance
RefO
0
m/z-->
f.bundance
Ra~
0
m/z-->
Abundance
Sub
50
30
30
47
37 I
40 50
37 Y
40 50
Scan 510 (9.063 min): REV201.D (-)
9'5
60
,1 66 72 82 1 ,I 114
60 70 80 90 1Q0 110
~can 509(9.063 min): REV543.D
95
60
1,166 72 82 1 ,I 114
60 70 80 90 100 110
~can 509 (9:Uo3 mln):~EV543.D (-)
60
130
l,i36
120 1 0 140
130
J36
120 1 0 140
130
#43
l,2-Diehloroethane
Coneen: 0.26 ug/l
RT: 8.11 min Sean# 446
Delta R.T. 0.01 min
Lab File: REVS43.D
Aeq: 29 May 2024 6:31 pm
Tgt Ion: 62 Resp: 6034
Ion Ratio Lower Upper
62 100
64 26.9 1.9 61. 9
#44
Triehloroethene
Coneen: 34.06 ug/l
RT: 9.06 min Sean# S09
Delta R.T. 0.00 min
Lab File: REVS43.D
Aeq: 29 May 2024 6:31 pm
300000
200000
m/z--> I
100000
o 30 71~4b" ~I~~b' , , ,~~I '~'\b,2, , '81~12" , '9b'-Il-fl+J 111L,-O'0~1rTi 1'-10"-1r2T"'10~1rl"¥)H3~ ~im~-> ~.Im8.11o' 9.bo ·9~9.2ii ·9.30·9.\~0----,
REVS43.D V001E11.M Thu Jun 06 12:21:S0 2024 Page 4
REPORT ID: 24E186 Page 14 of 217
METHOD SW5030c/8260C
VOLATILE ORGANICS BY GC/MS
Cl i ent : BRICE
Project : TEAD·N
Batch No. : 24E186
Sample ID : TEAD·05·24·WIN9549
Lab Samp ID: 24E186· 02N
Lab File ID: RFV010
Ext Btch ID: V001F01
Calib. Ref.: REV201
PARAMETER(S)
•• __ oo ________________ • ___
1.1.1· Trichloroethane
1.1.2· Trichloroethane
1.1· Di ch 1 oroethane
1.1· Di ch 1 oroethene
1.2· Di ch 1 oroethane
Carbon Tetrachloride
Chloroform
ci s·l. 2·Dichloroethene
Methylene Chloride
Tetrach 1 oroethene
Trans· 1. 2·Dichloroethene
Trichloroethene
1.2· Di ch 1 oroethene (T ota 1)
SURROGATE PARAMETER (S)
.0 ______ -----.-------._---
1.2· Di ch 1 oroethane· d4
4· Bromofl uorobenzene
Toluene·d8
Di bromofl uoromethane
Notes:
RESULTS
(ug/L)
____ 0 _____ -
ND
ND
ND
ND
0.25J
l.4
0.29J
ND
ND
ND
ND
33
ND
RESULT
___ .0 •••• --
11.1
9.52
9.81
10.3
Date Collected: OS/23/24 13:05
Date Received: OS/29/24
Date Extracted: 06/03/24 15: 22
Date Analyzed: 06/03/24 15:22
Dilution Factor: 1
Matri x: WATER
% Moi sture: NA
Instrument ID: 01
LOQ DL LOD
(ug/L) (ug/L) (ug/L)
__ •• 0 0 ------___ 00 •• ---____ 0_ ••• --
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
l.0 0.10 0.20
l.0 0.10 0.20
l.0 0.10 0.20
2.0 0.50 l.0
1.0 0.15 0.30
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
SPK AMT %RECOVERY QC LIMIT
____ 0 ____ ---___ 0 ___ ••• ____ 0_.-._.
10.0 III 81·118
10.0 95 85·114
10.0 98 89·112
10.0 103 80·119
Sample Amount : 25ml Final Volume: 25ml
Prepared by : LPri et Analyzed by : LPri et
Detection limits are reported relative to sample result significant figures.
REPORT ID: 24E186 Page 15 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24F03\RFV010.D
Acq On 3 Jun 2024 3:22 pm
Sample 24E186-02N
Misc 2.5mL
(QT Reviewed)
Vial: 10
Operator: LPriet
Inst 01
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Jun 13 14:46 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Internal Standards R.T. QIon Response Conc Units Dev(Min)
-------------------------------------------------------------------------
1) l,4-DIFLUOROBENZENE 8.56 114 838939 10.00 ug/l 0.02
53) CHLOROBENZENE-D5 13.73 117 667073 10.00 ug/l 0.01
72) l,2-DICHLOROBENZENE-D4 18.69 152 289333 10.00 ug/l 0.01
System Monitoring Compounds
34) Dibromofluoromethane 7.24 111 268554 10.34 ug/l 0.01
Spiked Amount 10.000 Recovery = 103.40%
41) l,2-Dichloroethane-d4 7.98 65 196067 11.07 ug/l /0.01
Spiked Amount 10.000 Recovery = 110.70%
54) Toluene-d8 11.03 98 981103 9.81 ug/l'~ 0.00
Spiked Amount 10.000 Recovery 98.1Y%
76) 4-Bromofluorobenzene 16.02 95 375030 9.52 ug/l 0.01
Spiked Amount 10.000 Recovery = 95)Y%
Target Compounds Qvalue
31 ) Chloroform 6.92 83 15034 ,/0.29 ug/l 98
39 ) Carbon tetrachloride 7.89 119 43980 .,... 1. 37 ug/l 100
43) l,2-Dichloroethane 8.13 62 5569 /.25 ug/l 92
44) Trichloroethene 9.08 130 966282 33.33 ug/l 98
t/
(#) = qualifier out of range (m) = manual integration
RFV010.D V001E11.M Thu Jun 13 14:47:19 2024 Page 1
REPORT ID: 24E186 Page 16 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24F03\RFV010.D
Aeq On 3 Jun 2024 3:22 pm
Sample 24E186-02N
Mise 2.SmL
Vial:
Operator:
Inst
Multiplr:
10
LPriet
01
l. 00
MS Integration Params: RTE.P
Quant Time: Jun 13 14:46 2024 Quant Results File: V001E11.RES
Method
Title
Last Update
Response via
f.bundance
1800000
1700000
1600000
1500000
1400000
1300000
1200000
1100000
1000000
900000
800000
700000
600000
500000
400000
300000
200000
100000
0 r---
ime--> 2.bo 3.bo 4.bo
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 2Smls
Mon May 13 13:20:11 2024
Initial Calibration
TIC: RFV010.D
~
CJ)
ui ro
Z " ill d> c: N " z ::J
ill ~ m
0 a::
0 :::>
...J u.
is
..t.
CJ)
oi c:
'" ,£;
" E CJ) e ~ 0
::J " '5 d> c: E '" e ,£;
,g ~ 0
~.
:; jT,;
~ q 0 g .!!o
6.2 .g ~~ e
~
0
J
.~.~.".-
~
0
W
.,; z
ill 0 N W z
Z ill
ill m
N 0 z CJ) a::
ill .,; 0 m c: ...J
0 " I a:: N 0 c: 0 " is ...J .0 N. I e 0 0
::J
'5
E e m ..t
i II il '-___ ~J l ____ .
5.bo 6.bo 7.bo 8.bo 9J)0' '10~00 11 ~oo '12~00 13~OO'14~00 15~00 16~00 17:00 18~0019~00 20~0
RFV010.D V001E11.M Thu Jun 13 14:47:20 2024
i I ':I" ...... o 21.00
Page 2
REPORT ID: 24E186 Page 17 of 217
bundance
Ref<>
47
min): REV201.D (-)
83
Iz-->
o L,--,-,--,-,--,L,-,-L,~ 57
40 50'
bundance
Ra~
Iz-->
bundance
Sub
50
Iz-->
bundance
Ref<>
40
47
40
47
40 50 60 70 80
Scan 431 (7.880 min): REV201.D (-)
43
55 87
120
117
37 67 O~~~~~Tr~~~t~~~¥r~~~~~·~~~~
Iz--> 30 60 70 80 90 1 0 fi'b;.::u'--n-.-da-n-c-e--=-c=------'-=-----=-=-------.S""'cO==a~n ~43"';'1:"""(7]j93 min ): RFVOT~.-r..----'-''-=------'-''''''----'-==-=--i
Ra~
40
47
bundance can
Sub
50
47
1 7
0~~~~~~~~~,~~4+~~~~~~~~~~
Iz--> 30 40 50 60 70 80
#31
Chloroform
Concen: 0.29 ug/l
RT: 6.92 min Scan# 365
Delta R.T. 0.01 min
Lab File: RFV010.D
Acq: 3 Jun 2024 3:22 pm
Tgt
Ion
83
85
47
Ion: 83
Ratio
100
66.3
25.9
Resp:
Lower
38.2
0.0
15034
Upper
98.2
54.7
bundance on 83-:-01fr82~rrOTRF
Ion 85.00 (84.70 to 85.70): RFV010.D
Ion 47.00 (46.70 to 47.70): RFV010.D
5000
6.92
ime-->
#39
Carbon tetrachloride
Concen: 1.37 ug/l
RT: 7.89 min Scan# 431
Delta R.T. 0.01 min
Lab File: RFV010.D
Acq: 3 Jun 2024 3:22 pm
Tgt
Ion
119
117
Ion:119
Ratio
100
105.3
Resp:
Lower
74.0
43980
Upper
137.4
RFV010.D V001E11.M Thu Jun 13 14:47:21 2024 Page 3
REPORT ID: 24E186 Page 18 of 217
bundance
RefO
O'-rrrTTTTTT +l4-rr~-rt-t-I+!+'-'-';:'.'r-rl+l+ho.rri.';"'H+I+~~ ;~~-.+rI~~~
/z--> 30
undance
Ra,%
bundance
#43
l,2-Dichloroethane
Concen: 0.25 ug/l
RT: 8.13 min Scan# 447
Delta R.T. 0.03 min
Lab File: RFV010.D
Acq: 3 Jun 2024 3:22 pm
Tgt
Ion
62
64
Ion: 62
Ratio
100
27.7
Resp:
Lower
1.9
5569
Upper
61. 9
RFV010.D V001E11.M Thu Jun 13 14:47:21 2024 Page 4
REPORT ID: 24E186 Page 19 of 217
METHOD SW5030Cl8260C
VOLATILE ORGANICS BY GClMS
Client BRICE Date Co 11 ected: OS/23/24 08: 00
Project TEAD·N Date Recei ved: OS/29/24
Batch No. 24E186 Date Extracted: OS/29/24 16: 02
Sample ID TB20240523 Date Analyzed: OS/29/24 16:02
Lab Samp ID: 24E186·03 Dilution Factor: 1
Lab File ID: REV538 Matrix: WATER
Ext Btch ID: V001E25 % Moisture: NA
Calib. Ref.: REV201 Instrument ID: 01
RESULTS LOO DL LOD
PARAMETER(S) (ug/l) (ug/l) (ug/L) (ug/l)
~ ~ ~ . --. ----.......... -. --. .. -........ ........ __ . ........... ...........
1.1.1·Trichloroethane ND 1.0 0.10 0.20
1.1.2· Tri ch 1 oroethane ND 1.0 0.10 0.20
1.1· Di ch 1 oroethane ND 1.0 0.10 0.20
1.1· Di ch 1 oroethene ND 1.0 0.10 0.20
1.2' Di ch 1 oroethane ND 1.0 0.10 0.20
Carbon Tetrachloride ND 1.0 0.10 0.20
Chloroform ND 1.0 0.10 0.20
ci s·l. 2·Dichloroethene ND 1.0 0.10 0.20
Methylene Chloride ND 2.0 0.50 1.0
Tetrachloroethene ND 1.0 0.15 0.30
Trans ·1. 2· Di ch 1 oroethene ND 1.0 0.10 0.20
Trichloroethene ND 1.0 0.10 0.20
1.2· Di ch 1 oroethene (T ota 1) ND 1.0 0.10 0.20
SURROGATE PARAMETER (S) RESULT SPK AMT %RECOVERY QC LIMIT
.................. _--.. -.-•• __ 0 •••••• •• __ .w ••••• ---_.-..... .-._ ..... _.
1.2· Di ch 1 oro ethane . d4 10.8 10.0 108 81·118
4· Bromofl uorobenzene 9.82 10.0 98 85·114
Toluene·d8 9.61 10.0 96 89·112
Di bromofl uoromethane 10.2 10.0 102 80·119
Notes:
Sample Amount : 25ml Final Volume: 25ml
Prepared by : LPriet Analyzed by : LPriet
Detection limits are reported relative to sample result significant figures.
REPORT ID: 24E186 Page 20 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E29\REV538.D
Acq On 29 May 2024 4:02 pm
Sample 24E186-03
Misc 25mL
MS Integration Params: RTE.P
Quant Time: Jun 6 12:20 2024
Vial: 11
Operator: LPriet
Inst 01
Multiplr: 1.00
Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 8.54 114 821097 10.00 ug/l 0.00
53) CHLOROBENZENE-D5 13.71 117 670477 10.00 ug/l 0.00
72) l,2-DICHLOROBENZENE-D4 18.67 152 276329 10.00 ug/l 0.00
System Monitoring Compounds
34) Dibromofluoromethane 7.23 111 258418 10.17 ug/l 0.00
Spiked Amount 10.000 Recovery = 101.70%
41) l,2-Dichloroethane-d4 7.97 65 187878 10.84 ug/l 0.00
Spiked Amount 10.000 Recovery = 108.40%
54) Toluene-d8 11.02 98 965682 9.61 ug/l ~0.02
Spiked Amount 10.000 Recovery = 96.10%
76) 4-Bromofluorobenzene 15.99 95 369649 9.82 ug /1/,/ -0 . 02
Spiked Amount 10.000 Recovery = 98. '20%
./
Target Compounds Qvalue
(#) = qualifier out of range (m) = manual integration
REV538.D V001E11.M Thu Jun 06 12:20:53 2024 Page 1
REPORT ID: 24E186 Page 21 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E29\REV538.D
Aeq On 29 May 2024 4:02 pm
Sample 24E186-03
Mise 25mL
Vial:
Operator:
Inst
Multiplr:
11
LPriet
01
1. 00
MS Integration Params: RTE.P
Quant Time: Jun 6 12:20 2024 Quant Results File: VOOIEll.RES
Method
Title
Last Update
Response via
Abundance
800000
750000
700000
650000
600000
550000
500000
450000
400000
350000
300000
250000
200000
150000
100000
50000
~
D:\HPCHEM\l\METHODS\VOOIEll.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
TIC: REV538.D
u.i z
UJ
N z
UJ
!Il
0 a::
0
::l
...J u..
~
C/) .; c::
'" ~
E e
0
:J
'5
C/) E e " .0 "9
is Q) c::
'" :;
Q) e
~
N.
'---'--f
" 0
uJ z
UJ on N
0 z
UJ uJ !Il
Z 0 UJ a:: N 0 Z
UJ ...J
I !Il () 0 is a::
0 N. ...J
I
()
C/)
.; c:: I Q)
N c::
Q)
.0 e
0
:J
'5
E e
!Il ....
i
I
f\ ~J\ __ ._~
I
-~~~~-~ o flA
ime--> 2.:>0 3.bo 4.bo 5.bo 6.bo 7.bo 8.bo 9.bo 10.00 11.00 12.00 13.00 14.00 15.0016:00 17:00 '18:00 19:00 20:00 21:00 ' ,
REV538.D VOOIEll.M Thu Jun 06 12:20:54 2024 Page 2
REPORT ID: 24E186 Page 22 of 217
QC SUMMARIES
REPORT ID: 24E186 Page 23 of 217
Client BRICE
Project TEAD·N
Batch No. 24E186
Sample ID MBLK1W
Lab Samp ID: V001E25Q
Lab File 10: REV536
Ext Btch 10: V001E25
Calib. Ref.: REV201
PARAMETER(S)
..........................
1,1,1· Trichloroethane
1,1,2·Trichloroethane
1, 1· Di ch 1 oroethane
1,1·Dichloroethene
1,2·Dichloroethane
Carbon Tetrachloride
Chloroform
ci s·l, 2·Dichloroethene
Methylene Chloride
Tetrachloroethene
Trans·1,2·Dichloroethene
Trichloroethene
1,2· Di ch 1 oroethene (T ota 1)
SURROGATE PARAMETER(S)
• __ .0 ___ o_ ... ____ ... ______
1,2· Di ch 1 oroethane· d4
4· Bromofl uorobenzene
Toluene·d8
Di bromofl uoromethane
Notes:
METHOD SW5030Cl8260C
VOLATILE ORGANICS BY GClMS
RESULTS
(ug/L)
...........
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
RESULT
_ .. -._-_ ...
10.7
9.71
9.68
10.1
Date Collected: OS/29/24 15:03
Date Received: OS/29/24
Date Extracted: OS/29/24 15: 03
Date Analyzed: OS/29/24 15:03
Dilution Factor: 1
Matrix: WATER
% Moi sture: NA
Instrument 10: 01
LOQ DL LOD
(ug/L) (ug/L) (ug/L)
. .......... ....... --.-. ..........
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
2.0 0.50 1.0
1.0 0.15 0.30
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
SPK AMT %RECOVERY QC LIMIT
........ _--............ .. --._-_ ...
10.0 107 81-118
10.0 97 85·114
10.0 97 89·112
10.0 101 80·119
Sample Amount : 25ml Final Volume: 25ml
Prepared by : LPriet Analyzed by : LPriet
Detection limits are reported relative to sample result significant figures.
REPORT ID: 24E186 Page 24 of 217
EMAX QUALITY CONTROL DATA
LAB CONTROL SAMPLE ANALYSIS
CLIENT
PROJECT
BATCH NO.
METHOD
: BRICE
: TEAD·N
24E1B6
: SW5030C/B260C
MATRIX : WATER
DILUTION FACTOR: 1
SAMPLE ID : MBLK1W
LAB SAMPLE ID : V001E25Q
LAB FILE ID : REV536
DATE PREPARED : 05/29/24 15: 03
DATE ANALYZED : 05/29/24 15: 03
PREP BATCH : V001E25
CALIBRATION REF: REV201
ACCESSION:
1
LCS1W
V001E25L
REV531
05/29/24 ll: 54
05/29/24 ll: 54
V001E25
REV201
MBResult SpikeAmt LCSResult
PARAMETERS (ug/L) (ug/L) (ug/L)
................. __ .... _--_ ... ... --...... • ___ 0 ____ -
1.1.1· Trichloroethane ND 10.0 10.3
1. 1. 2·Trichloroethane ND 10.0 9.45
1.1· Di ch 1 oroethane ND 10.0 9.81
1.1· Di ch 1 oroethene ND 10.0 9.00
1.2· Di ch 1 oro ethane ND 10.0 10.6
Carbon Tetrachloride ND 10.0 10.3
Chloroform ND 10.0 9.99
cis·1.2·Dichloroethene ND 10.0 9.44
Methylene Chloride ND 10.0 9.64
Tetrach 1 oroethene ND 10.0 9.96
Trans·1.2·Dichloroethene ND 10.0 9.17
Tri ch 1 oroethene ND 10.0 9.99
1.2·Dichloroethene (Total) ND 20.0 18.6
SpikeAmt LCSResult
SURROGATE PARAMETERS (ug/L) (ug/L)
• ______ 0 ____ •• ------------
1.2·Dichloroethane·d4 10.0 10.2
4· Bromofl uorobenzene 10.0 9.79
Toluene·d8 10.0 9.56
Di bromofl uoromethane 10.0 10.1
% MOISTURE:NA
1
LCD1W
V001E25C
REV532
OS/29/24 13:01
05/29/24 13: 01
V001E25
REV201
LCSRec SpikeAmt
(%) (ug/L)
103 10.0
95 10.0
98 10.0
90 10.0
106 10.0
103 10.0
100 10.0
94 10.0
96 10.0
100 10.0
92 10.0
100 10.0
93 20.0
LCSRec SpikeAmt
(%) (ug/L)
102 10.0
9B 10.0
96 10.0
101 10.0
MB: Method Blank sample LCS: Lab Control Sample LCD: Lab Control Sample Duplicate
LCDResult LCDRec RPD QCLimit MaxRPD
(ug/L) (%) (%) (%) (%)
--_ .......
9.93 99 4 74·131 20
9.B8 99 4 BO·ll9 20
9.42 94 4 77·125 20
B.67 B7 4 71·l31 20
ll.O llO 4 73·128 20
10.0 100 3 72·l36 20
9.94 99 1 79·124 20
9.14 91 3 78·123 20
9.59 96 1 74·124 20
9.35 94 6 74·129 20
8.96 90 2 75·124 20
9.70 97 3 79·123 20
18.1 91 3 79·121 20
LCDResult LCDRec QCLimit
(uglL) (%) (%)
... _-_ ....
1l. 3 ll3 81·ll8
9.62 96 B5·ll4
9.23 92 89·ll2
10.4 104 BO·ll9
REPORT ID: 24E186 Page 25 of 217
Client BRICE
Project TEAD-N
Batch No _ 24El86
Sample ID MBLK2W
Lab' Samp 10: V001F018
Lab File 10: RFV006
Ext Btch 10: V001F01
Calib. Ref.: REV201
PARAMETER(S)
..........................
1.1. I-Trichloroethane
1. 1. 2-Trichloroethane
1.1-Di ch 1 oroethane
1.1-Dichloroethene
1.2-Di ch 1 oroethane
Carbon Tetrachloride
Chloroform
ci s-l. 2-Dichloroethene
Methylene Ch 1 ori de
Tetrachloroethene
Trans-1.2-Dichloroethene
Tri chl oroethene
1.2-Dichloroethene (Total)
SURROGATE PARAMETER(S)
............................
1.2 -Di ch 1 oroethane -d4
4 -Bromefl uorobenzene
Toluene-d8
Di bromefl uoromethane
Notes:
METHOD SW5030C/8260C
VOLATILE ORGANICS BY GC/MS
RESULTS
(ug/L)
..... -_ .....
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
RESULT
............
11.1
9.37
9.48
10.4
Date Collected: 06/03/24 13:20
Date Recei ved: 06/03/24
Date Extracted: 06/03/24 13:20
Date Analyzed: 06/03/24 13:20
Dilution Factor: 1
Matrix: WATER
% Moisture: NA
Instrument 10: 01
LOQ DL LOD
(ug/l) (ug/l) (ug/L)
............ ........... . ...........
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
2.0 0.50 1.0
1.0 0.15 0.30
1.0 0.10 0.20
1.0 0.10 0.20
1.0 0.10 0.20
SPK_AMT %RECOVERY QC LIMIT
........... . .......... ...........
10.0 111 81-118
10.0 94 85-114
10.0 95 89-112
10.0 104 80-119
Sample Amount : 25ml Final Volume: 25ml
Prepared by : LPriet Analyzed by : LPriet
Detection limits are reported relative to sample result Significant figures.
REPORT ID: 24E186 Page 26 of 217
EMAX QUALITY CONTROL DATA
LAB CONTROL SAMPLE ANALYSIS
CLIENT : BRICE
PROJECT : TEAD·N
BATCH NO. 24E186
METHOD : SW5030C/8260C
MATRIX : WATER % MOISTURE:NA
DILUTION FACTOR: 1 1 1
SAMPLE ID : MBLK2W LCS2W LCD2W
LAB SAMPLE ID : V001F01B V001F01L V001F01C
LAB FILE ID : RFV006 RFV003 RFV004
DATE PREPARED 06/03/24 13: 20 06/03/24 11: 49 06/03/24 12: 18
DATE ANALYZED 06/03/24 13: 20 06/03/24 11: 49 06/03/24 12: 18
PREP BATCH V001F01 V001F01 V001F01
CALIBRATION REF: REV201 REV201 REV201
ACCESSION:
MBResult SpikeAmt LCSResult LCSRec SpikeAmt LCDResult LCDRec RPD QCLimit MaxRPD
PARAMETERS (ug/L) (ug/L) (ug/l) (%) (ug/L) (ug/l) (%) (%) (%) (%)
.......................... .......... . .........
1.1.1-Trichloroethane ND 10.0 10.3 103 10.0 11.0 110 7 74-131 20
1.1.2-Trichloroethane ND 10.0 10.1 101 10.0 10.0 100 1 80-119 20
1. 1-Di ch 1 oroethane ND 10.0 9.78 98 10.0 10.3 103 5 77-125 20
1.1-Dichloroethene ND 10.0 8.78 88 10.0 9.40 94 7 71-131 20
1.2-Di ch 1 oro ethane ND 10.0 11.2 ll2 10.0 11.2 112 0 73-128 20
Carbon Tetrach 1 ori de ND 10.0 10.4 104 10.0 11.0 110 6 72-136 20
Chloroform ND 10.0 10.1 101 10.0 10.5 105 4 79-124 20
ci s-l. 2-Di chloroethene ND 10.0 9.58 96 10.0 9.74 97 2 78-123 20
Methylene Chloride ND 10.0 9.67 97 10.0 9.78 98 1 74-124 20
Tetrachloroethene ND 10.0 9.66 97 10.0 10.3 103 6 74-129 20
Trans-1.2-Dichloroethene ND 10.0 9.14 91 10.0 9.57 96 5 75-124 20
Trichloroethene ND 10.0 9.83 98 10.0 10.5 105 7 79-123 20
1.2·Dichloroethene (Total) ND 20.0 18.7 94 20.0 19.3 97 3 79-121 20
SpikeAmt LCSResult LCSRec SpikeAmt LCDResult LCDRec QCLimit
SURROGATE PARAMETERS (ug/l) (ug/l) (%) (ug/l) (ug/l) (%) (%)
............ ---... __ ..... --~ . -......
1.2 -Di ch 1 oroethane· d4 10.0 11.0 110 10.0 10.7 107 81-118
4-Bromofl uorobenzene 10.0 9.61 96 10.0 9.47 95 85-114
Toluene-d8 10.0 9.59 96 10.0 9.59 96 89-112
Dibromofluoromethane 10.0 10.3 103 10.0 10.3 103 80-119
MB: Method Blank sample LCS: Lab Control Sample LCD: Lab Control Sample Duplicate
REPORT ID: 24E186 Page 27 of 217
CLIENT
PROJECT
BATCH NO.
METHOD
: BRICE
: TEAD-N
: 24E186
: SW5030c/8260C
MATRIX : WATER
DILUTION FACTOR: 1
SAMPLE ID : TEAD·05-24-WIN9549
LAB SAMPLE ID 24E186 -02N
LAB FILE ID RFV010
DATE PREPARED 06/03/24 15: 22
DATE ANALYZED 06/03/24 15: 22
PREP BATCH V001F01
CALIBRATION REF: REV201
ACCESSION:
PSResult
PARAMETERS (ug/l)
-.--------------------_._. ........ _-
1.1.1· Trichloroethane ND
1.1.2-Trichloroethane ND
1.1· Di chl oroethane ND
1. 1-Di ch 1 oroethene ND
1.2-Di ch 1 oroethane 0.246J
Carbon Tetrachloride 1.37
Chloroform 0.293J
ci s·l. 2-Dichloroethene ND
Methylene Chloride ND
Tetrachloroethene ND
Trans-I. 2 ·Di chl oroethene ND
Trichloroethene 33.3
1.2-Dichloroethene (Total) ND
SURROGATE PARAMETERS
..... -.-.. --.. --_._-_ .......
1.2· Di ch 1 oroethane -d4
4 -Bromofl uorobenzene
Toluene·d8
Di bromofl uoromethane
SpikeAmt
(ug/l)
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
20.0
SpikeAmt
(ug/l)
10.0
10.0
10.0
10.0
EMAX QUALITY CONTROL DATA
MS/MSD ANALYSIS
1
TEAD· 05· 24-WIN9549MS
24E186·02M
RFV011
06/03/24 15:52
06/03/24 15:52
V001F01
REV201
MSResult
(ug/l)
---.. -.-.. -
11.0
9.67
9.99
9.28
11.2
12.4
10.7
9.49
9.48
10.2
9.57
43.6
19.1
MSResult
(ug/L)
10.8
9.47
9.71
10.4
MSRec
(%)
110
97
100
93
110
110
104
95
95
102
96
103
96
MSRec
(%)
108
95
97
104
SpikeAmt
(ug/l)
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
20.0
SpikeAmt
(ug/l)
10.0
10.0
10.0
10.0
PS: Parent Sample MS: Matrix Spike MSD: Matrix Spike Duplicate
MSDResult
(ug/L)
10.4
10.2
9.64
9.89
10.9
11.8
10.4
9.77
9.50
9.96
9.60
42.3
19.4
MSDResult
(ug/l)
10.7
9.44
9.49
10.3
% MOISTURE:NA
1
TEAD-05-24-WIN9549MSD
24E186·02S
RFV012
06/03/24 16: 21
06/03124 16: 21
V001F01
REV201
MSDRec RPD
(%) (%)
104 6
102 5
96 4
99 6
107 3
104 5
101 3
98 3
95 0
100 2
96 0
90 3
97 2
MSDRec
(%)
107
94
95
103
QCLimit
(%)
74-131
80·119
77·125
71·131
73·128
72-136
79-124
78-123
74·124
74-129
75·124
79·123
79·121
QCLimit
(%)
____ 0. __ ••
81-118
85-114
89·112
80·119
MaxRPD
(%)
20
20
20
20
20
20
20
20
20
20
20
20
20
REPORT ID: 24E186 Page 28 of 217
QC DATA
REPORT ID: 24E186 Page 29 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E29\REV536.D
Acq On 29 May 2024 3:03 pm
Vial: 9
Operator: LPriet
01 Sample V001E25Q
Misc 25mL
Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: Jun 13 18:41 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 8.55 114 824228 10.00 ug/l 0.00
53) CHLOROBENZENE-D5 13.71 117 670629 10.00 ug/l 0.00
72) l,2-DICHLOROBENZENE-D4 18.67 152 285230 10.00 ug/l 0.00
System Monitoring Compounds
34) Dibromofluoromethane 7.23 111 257969 10.11 ug/l 0.00
Spiked Amount 10.000 Recovery = 101.10%
41) l,2-Dichloroethane-d4 7.97 65 186429 10.71 ug/l/ 0.00
Spiked Amount 10.000 Recovery = 107.'10%
54) Toluene-d8 11.02 98 972815 9.68 ug /1 ,------ 0 . 01
Spiked Amount 10.000 Recovery = 96.8;0%
76) 4-Bromofluorobenzene 15.99 95 377396 9.71 ug/)/ -0.02
Spiked Amount 10.000 Recovery = 97.10%
,/'
Target Compounds Qvalue
(#) = qualifier out of range (m) = manual integration
REV536.D V001E11.M Thu Jun 13 18:44:01 2024 Page 1
REPORT ID: 24E186 Page 30 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E29\REV536.D
Aeq On 29 May 2024 3:03 pm
Sample V001E25Q
Mise 25mL
Vial:
Operator:
Inst
Multiplr:
9
LPriet
01
1. 00
MS Integration Params: RTE.P
Quant Time: Jun 13 18:41 2024 Quant Results File: V001E11.RES
Method
Title
Last Update
Response via
f-bundance
850000
800000
750000
700000
650000
600000
550000
500000
450000
400000
350000
300000
250000
200000
150000
100000
50000
iii ~
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
nC:~6.D
u.i z f ill N z
ill
CD
0 c::
0
:;J
...J u.
15
..t.
rn
oj
r::
'" ,s
Q)
E e
0
" '" 0
E rn e .; .0
"% [5
r::
'" ,s
Q) e
.Q
1i
0
N.
'-----~
.;
0
uJ
Z
ill
N z
ill ",' CD 0 0 uJ c:: z 0 ill ...J
N :c z ()
ill ~ CD
0 c::
0
...J :c rn
() oj
r::
Q)
~
Q)
.0 e
0
" '" 0
E e
CD ..t
'---.. ~~ '--.-~---0
ime--> 2.bo 3.bo 4.bo 5.bo 6.bo 7.bo 8.bo 9.06' '10:00 '11:00 '12:00 13:00 '14:00 15:00 16:00 '17:00 '18:00 19:00 20:00 21:00
I
1
REV536.D V001E11.M Thu Jun 13 18:44:02 2024 Page 2
REPORT ID: 24E186 Page 31 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E29\REV531.D
Acq On 29 May 2024 11:54 am
Sample VOOIE25L
Vial:
Operator:
4
LPriet
01
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 29 12:16 2024 Quant Results File: VOOIEll.RES
Quant Method
Title
D:\HPCHEM\l\METHODS\VOOIEll.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13: 20: 11 2024 ./
Initial Calibration
VOOIEll
Internal Standards
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
72) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
3) Dichlorodifluoromethane
5) Chloromethane
6) Vinyl chloride
7) Bromomethane
8) Chloroethane
9) Dichlorofluoromethane
10) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-l,2,2-trif
13) Acetone
14) 1,1-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
18) Methylene chloride
19) Carbon disulfide
20) Acrylonitrile
21) tert-Butyl methyl ether (M
22) trans-l/2-D~chloroethene
23) Isopropyl ether (DIPE)
24) Vinyl acetate
25) 1,1-Dichloroethane
27) tert-Butyl ethyl ether (ET
28) 2-Butanone
29) 2,2-Dichloropropane
30) cis-l,2-Dichloroethene
31) Chloroform
R.T. Qlon Response Conc Units Dev(Min)
8.55 114
13.70 117
18.67 152
7.21
7.95
11.02
15.99
2.17
2.48
2.61
3.15
3.18
3.27
3.55
3.98
4.07
4.04
4.22
4.34
4.63
4.65
4.86
4.87
5.02
5.05
5.24
5.66
5.82
5.82
6.23
6.41
6.62
6.68
6.90
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
142
43
49
76
53
73
61
45
43
63
59
43
77
96
83
832746
690880
278386
261509
10.00 ug/l
10.00 ug/l
10.00 ug/l
10.15
0.00
-0.02
0.00
Recovery =
ug/l -0.02
101.50%
ug/l -0.02
102 . ..2-0%
179605 10.22
Recovery =
989667 9.56
Recovery =
371013 9.79
Recovery =
ug/1 -0.01
95.60%
ug/} -0.02
97.)-0%
193661
242380
224826
263435
156781
553931
331924
75685
180114
159577
399883
216448
508470
106759
343603
1003041
181188
410430
392305
922585
280099
491112
599046
246029
395792
325064
509327
8.69 ug/l
7.77 ug/l
8.65 ug/l
8.52 ug/l
8.32 ug/l
10.35 ug/l
9.44 ug/l
40.46 ug/l
10.25 ug/l
52.50 ug/l
9.00 ug/l
233.49 ug/l
10.68 ug/l
12.88 ug/l
9.64 ug/l
10.56 ug/l
46.99 ug/l
9.40 ug/l
9.17 ug/l
10.09 ug/l
8.92 ug/l
9.81 ug/l
9.14 ug/l
52.75 ug/l
9.41 ug/l
9.44 ug/l
9.99 ug/l
Qvalue
99
99
99
100
90
99
100
97
100
94
100
85
98
100
99
99
98
99
99
99
99
100
96
99
99
100
99
(#) = qualifier out of range (m) = manual integration
REV531.D VOOIEll.M Thu Jun 13 14:42:56 2024 Page 1
REPORT ID: 24E186 Page 32 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E29\REV531.D
Acq On 29 May 2024 11:54 am
Sample V001E25L
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
4
LPriet
01
1. 00
Quant Time: May 29 12:16 2024 Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Conc Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) 1,1,1-Trichloroethane
36) Cyclohexane
38) 1,1-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) Benzene
43) 1,2-Dichloroethane
44) Trichloroethene
45) Methylcyclohexane
46) 1,2-Dichloropropane
47) Bromodichloromethane
48) 1,4-Dioxane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) 1,1,2-Trichloroethane
59) 2-Hexanone
60) 1,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
63) 1,2-Dibromoethane
64) 1-Chlorohexane
65) Chlorobenzene
66) 1,1,1,2-Tetrachloroethane
67) Ethylbenzene
68) m-Xylene & p-Xylene
69) o-Xylene
70) Styrene
71) Isopropylbenzene
73) Bromoform
74) trans-1,4-Dichloro-2-buten
75) 1,1,2,2-Tetrachloroethane
77) 1,2,3-Trichloropropane
78) n-Propylbenzene
79) Bromobenzene
7.14
7.20
7.49
7.52
7.71
7.86
7.88
8.11
8.09
9.06
9.15
9.33
9.72
9.77
9.80
10.22
10.26
10.60
11.15
11.45
11.46
11.73
11. 76
12.17
12.29
12.65
13.02
13.30
13.77
13.85
13.86
14.01
14.82
14.90
15.51
15.55
15.62
15.85
16.13
16.28
16.36
49
42
97
84
110
119
73
78
62
130
83
63
83
88
93
63
43
75
91
69
75
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
53
83
110
91
156
189955
24749
438024
436917
135250
328278
467638
1054423
236781
287335
508404
233138
340807
18758
119964
83270
618180
374329
1126282
176603
269582
151809
347467
268337
254002
190773
149055
483454
695338
219380
1331080
2010972
1008190
773249
1223890
109117
39983
163442
42987
1611087
269265
(#) = qualifier out of range (m) = manual integration
REV531.D V001E11.M Thu Jun 13 14:42:57 2024
9.48 ug/l
8.39 ug/l
.... .-10.27 ug/l
. 10.51 ug/l
9.33 ug/l
10.33 ug/l
9.17 ug/l
9.48 ug/l
10.55 ug/l
9.99 ug/l
11.12 ug/l
9.37 ug/l
9.86 ug/l
184.07 ug/l
10.22 ug/l
13.18 ug/l
50.21 ug/l
9.66 ug/l
9.18 ug/l
9.59 ug/l
9.45 ug/l
9.45 ug/l
47.68 ug/l
9.84 ug/l
9.96 ug/l
9.73 ug/l
9.38 ug/l
9.13 ug/l
9.51 ug/l
9.74 ug/l
9.51 ug/l
19.62 ug/l
9.56 ug/l
9.46 ug/l
8.81 ug/l
9.92 ug/l
8.33 ug/l
8.82 ug/l
9.07 ug/l
8.90 ug/l
9.40 ug/l
Qvalue
98
98
100
98
100
100
100
100
100
98
99
94
99
96
95
99
98
99
100
94
98
99
96
100
99
100
100
99
100
99
98
97
98
99
100
97
99
99
100
99
100
Page 2
REPORT ID: 24E186 Page 33 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E29\REV531.D
Aeq On 29 May 2024 11:54 am
Sample V001E25L
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
4
LPriet
01
1. 00
Quant Time: May 29 12:16 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. Qlon Response Cone Unit
80) l,3,5-Trimethylbenzene 16.59 105 983831 8.51 ug/l
81) 2-Chlorotoluene 16.62 91 1006577 9.24 ug/l
82) 4-Chlorotoluene 16.72 91 827672 8.58 ug/l
83) tert-Butylbenzene 17.27 134 216346 8.92 ug/l
84) l,2,4-Trimethylbenzene 17.34 105 977038 8.63 ug/l
85) see-Butylbenzene 17.64 105 1386352 8.72 ug/l
86) p-Isopropyltoluene 17.86 119 1048058 8.55 ug/l
87) l,3-Diehlorobenzene 18.01 146 511295 9.40 ug/l
88) l,2,3-Trimethylbenzene 18.11 105 908259 8.60 ug/l
89) l,4-Diehlorobenzene 18.17 146 488852 9.16 ug/l
90) n-Butylbenzene 18.48 91 1100099 8.67 ug/l
91) l,2-Diehlorobenzene 18.70 146 406219 9.11 ug/l
92) l,2-Dibromo-3-ehloropropan 19.71 157 24917 8.81 ug/l
93) l,2,4-Triehlorobenzene 20.79 180 296990 9.12 ug/l
94) Hexaehlorobutadiene 20.96 225 165584 8.54 ug/l
95) Naphthalene 21.13 128 328010 8.63 ug/l
96) 1, 2, 3-Triehlorobenzene 21.46 180 227561 9.28 ug/l
,(#) = qualifier out of range (m) = manual integration
REV531.D V001E11.M Thu Jun 13 14:42:58 2024
Qvalue
99
99
100
95
99
100
99
99
99
99
99
99
96
100
96
100
99
Page 3
REPORT ID: 24E186 Page 34 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E29\REV531.D
Aeq On 29 May 2024 11:54 am
Sample V001E25L
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
4
LPriet
01
1.00
Quant Time: May 29 12:16 2024 Quant Results File: V001E11.RES
Method
Title
Last Update
Response via
fl\bundance
1800000
1700000
1600000
1500000
1400000
1300000
1200000
1100000
1000000
900000
800000
700000
600000
500000
400000
300000
200000
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
TIC: REV531.D
100000
o ~/~ ~ ~ \~
~ime-> 2.)0 3.bo 4.bo 5.bo 6.bo 7.bo
REV531.D V001E11.M Thu Jun 13 14:43:01 2024 Page 4
REPORT ID: 24E186 Page 35 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E29\REV532.D
Acq On 29 May 2024 1:01 pm
Sample V001E25C
Vial: 5
Operator: LPriet
Inst 01
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: May 29 13:23 2024 Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration ~
V001E11
Internal Standards
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
72) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
3) Dichlorodifluoromethane
5) Chloromethane
6) Vinyl chloride
7) Bromomethane
8) Chloroethane
9) Dichlorofluoromethane
10) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
18) Methylene chloride
19) Carbon disulfide
20) Acrylonitrile
21) tert-Butyl methyl ether (M
22) trans-1,2-Dichloroethene
23) Isopropyl ether (DIPE)
24) Vinyl acetate
25) l,l-Dichloroethane
27) tert-Butyl ethyl ether (ET
28) 2-Butanone
29) 2,2-Dichloropropane
30) cis-1,2-Dichloroethene
31) Chloroform
R.T. Qlon Response Conc Units Dev(Min)
8.55 114
13.70 117
18.67 152
7.21
7.95
11.02
15.99
2.16
2.48
2.60
3.15
3.20
3.27
3.55
3.97
4.07
4.04
4.22
4.32
4.63
4.63
4.86
4.87
5.02
5.05
5.24
5.66
5.82
5.82
6.22
6.41
6.62
6.68
6.90
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
142
43
49
76
53
73
61
45
43
63
59
43
77
96
83
788526
677822
292730
254004
10.00 ug/l
10.00 ug/l
10.00 ug/l
10.41
0.00
-0.02
0.00
Recovery =
ug/l -0.02
104.10%
188199 11.31 ug/l -0.02
113.jp-%"--
ug/Y" -0.01
Recovery =
937960 9.23
Recovery =
383697 9.62
Recovery =
92.30%
ug/l/ -0.02
96(20%
179721
220248
209261
239357
140768
509934
317539
76905
160650
160296
364789
242598
459838
105017
323618
877159
185735
431039
363132
876645
282284
446135
595309
244875
366459
298043
479887
/
8.52 ug/l
7.46 ug/l
8.51 ug/l
8.17 ug/l
7.89 ug/l
10.06 ug/l
9.54 ug/l
43.42 ug/l
9.66 ug/l
55.69 ug/l
8.67 ug/l
276.37 ug/l
10.20 ug/l
13.38 ug/l
9.59 ug/l
9.75 ug/l
50.87 ug/l
10.42 ug/l
8.96 ug/l
10.13 ug/l
9.50 ug/l
9.42 ug/l
9.60 ug/l
55.45 ug/l
9.20 ug/l
9.14 ug/l
9.94 ug/l
Qvalue
98
100
98
99
89
99
98
98
99
93
99
85
98
98
99
99
99
98
99
98
99
99
96
98
99
99
99
(#) = qualifier out of range (m) = manual integration
REV532.D V001E11.M Thu Jun 13 14:43:15 2024 Page 1
REPORT ID: 24E186 Page 36 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E29\REV532.D
Acq On 29 May 2024 1:01 pm
Sample V001E25C
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
5
LPriet
01
1.00
Quant Time: May 29 13:23 2024 Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Conc Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) l,l,l-Trichloroethane
36) Cyclohexane
38) l,l-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) Benzene
43) l,2-Dichloroethane
44) Trichloroethene
45) Methylcyclohexane
46) l,2-Dichloropropane
47) Bromodichloromethane
48) l,4-Dioxane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) l,l,2-Trichloroethane
59) 2-Hexanone
60) l,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
63) l,2-Dibromoethane
64) 1-Chlorohexane
65) Chlorobenzene
66) l,l,l,2-Tetrachloroethane
67) Ethylbenzene
68) m-Xylene & p-Xylene
69) o-Xylene
70) Styrene
71) Isopropylbenzene
73) Bromoform
74) trans-1,4-Dichloro-2-buten
75) l,l,2,2-Tetrachloroethane
77) l,2,3-Trichloropropane
78) n-Propylbenzene
79) Bromobenzene
7.14
7.18
7.49
7.51
7.71
7.86
7.88
8.11
8.10
9.06
9.15
9.33
9.72
9.77
9.80
10.22
10.26
10.60
11.15
11.45
11.46
11. 74
11.76
12.19
12.29
12.66
13.02
13.30
13.77
13.85
13.86
14.01
14.82
14.90
15.51
15.55
15.62
15.85
16.14
16.29
16.38
49
42
97
84
110
119
73
78
62
130
83
63
83
88
93
63
43
75
91
69
75
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
53
83
110
91
156
186415
25839
401023
374819
120525
301566
460421
971900
233564
264363
430811
219780
328015
20153
118635
86819
651802
359777
1029411
185017
272281
155760
369867
263197
233854
189348
151123
447619
646836
210371
1246493
1873142
970758
754695
1181801
113993
43016
176621
45568
1511127
268217
(#) = qualifier out of range (m) = manual integration
REV532.D V001E11.M Thu Jun 13 14:43:16 2024
9.83 ug/l
9.25 ug/l
9.93 ug/l
~.53 ug/l
8.78 ug/l
10.02 ug/l
9.54 ug/l
9.23 ug/l
10.99 ug/l
9.70 ug/l
9.95 ug/l
9.32 ug/l
10.03 ug/l
208.85 ug/l
10.67 ug/l
14.51 ug/l
55.60 ug/l
9.81 ug/l
8.55 ug/l
10.24 ug/l
9.73 ug/l
9.88 ug/l
51.32 ug/l
9.84 ug/l
9.35 ug/l
9.84 ug/l
9.69 ug/l
8.61 ug/l
9.01 ug/l
9.52 ug/l
9.07 ug/l
18.63 ug/l
9.38 ug/l
9.41 ug/l
8.67 ug/l
9.86 ug/l
8.52 ug/l
9.06 ug/l
9.14 ug/l
7.94 ug/l
8.91 ug/l
Qvalue
99
97
99
98
99
99
99
99
100
99
99
92
100
90
94
99
97
99
100
93
96
99
97
100
99
100
99
100
100
100
99
97
98
99
99
99
99
100
98
99
100
Page 2
REPORT ID: 24E186 Page 37 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E29\REV532.D
Aeq On 29 May 2024 1:01 pm
Sample V001E25C
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
TBA
Vial:
Operator:
Inst
Multiplr:
5
LPriet
01
1. 00
Quant Time: May 29 13:23 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Cone unit
80) l,3,5-Trimethylbenzene 16.59 105 947007 7.79 ug/l
81) 2-Chlorotoluene 16.63 91 952195 8.31 ug/l
82) 4-Chlorotoluene 16.72 91 839816 8.28 ug/l
83) tert-Butylbenzene 17.28 134 202548 7.94 ug/l
84) l,2,4-Trimethylbenzene 17.34 105 937813 7.88 ug/l
85) see-Butylbenzene 17.64 105 1305630 7.81 ug/l
86) p-Isopropyltoluene 17.87 119 1006769 7.81 ug/l
87) l,3-Diehlorobenzene 18.02 146 491932 8.60 ug/l
88) l,2,3-Trimethylbenzene 18.13 105 889161 8.00 ug/l
89) l,4-Diehlorobenzene 18.19 146 474115 8.45 ug/l
90) n-Butylbenzene 18.48 91 1043154 7.81 ug/l
91) l,2-Diehlorobenzene 18.70 146 402943 8.59 ug/l
92) l,2-Dibromo-3-ehloropropan 19.71 157 26317 8.84 ug/l
93) l,2,4-Triehlorobenzene 20.79 180 302599 8.84 ug/l
94) Hexachlorobutadiene 20.97 225 162759 7.98 ug/l
95) Naphthalene 21.15 128 347359 8.69 ug/l
96) l,2,3-Triehlorobenzene 21.46 180 233213 9.04 ug/l
(#) = qualifier out of range (m) = manual integration
REV532.D V001E11.M Thu Jun 13 14:43:17 2024
Qvalue
100
100
99
97
99
100
99
98
99
99
99
99
99
99
97
100
100
Page 3
REPORT ID: 24E186 Page 38 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E29\REVS32.D
Aeq On 29 May 2024 1:01 pm
Sample V001E2SC
Mise 10ppb 8260/S0ppb KET-AA/2S0ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
5
LPriet
01
1.00
Quant Time: May 29 13:23 2024 Quant Results File: V001E11.RES
Method
Title
Last Update
Response via
1700000
1600000
1500000
1400000
1300000
1200000
1100000
1000000
900000
sooooo
700000
600000
500000
400000
300000
200000
100000
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 2Smls
Mon May 13 13:20:11 2024
Initial Calibration
TIC: KEV532.D
,
:; r:
~
Q)
~
:; r:
Q)
@
~
:; r:
Q)
t:
Q)
I:!
Q) .a ~ e a.
0
.!/l
en
of t:
Q)
I:!
.2l e
0
" '5
E e
al
.,j.
~
.::;
:; r:
Q)
t: ~
Q) :;,9
r:~
Q)Q)
~·i ~~. .2l' .
>. a. e c..
r!:
~.
,;
t:
Q)
" 0 e ~ ~
~
o ~!WIv v
ime--> 2. DO 3.bi> 4.bo 5.bo 6.bo 7.bo s.bo 9.bo 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 1S.00 19.0020.0021.00
REVS32.D V001E11.M Thu Jun 13 14:43:20 2024 Page 4
REPORT ID: 24E186 Page 39 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24F03\RFV006.D
Acq On 3 Jun 2024 1:20 pm
Sample V001F01B
Misc 25mL
(QT Reviewed)
Vial: 6
Operator: LPriet
Inst 01
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Jun 4 12:22 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration . _____ .
V001E11 ~
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 8.56 114 878386 10.00 ug/l 0.02
53) CHLOROBENZENE-D5 13.73 117 731451 10.00 ug/l 0.01
72) l,2-DICHLOROBENZENE-D4 18.69 152 311188 10.00 ug/l 0.01
System Monitoring Compounds
34) Dibromofluoromethane 7.23 111 282020 10.37 ug/l 0.00
Spiked Amount 10.000 Recovery = 103.70%
41) l,2-Dichloroethane-d4 7.97 65 204902 11.05 ug/l .' 0.00
Spiked Amount 10.000 Recovery = 11 Or:5O %
54) Toluene-d8 11. 03 98 1039012 9.48 ug/l/' 0.00
Spiked Amount 10.000 Recovery = 94.80%
76) 4-Bromofluorobenzene 16.01 95 397337 9.37 ug/;I:/ 0.00
Spiked Amount 10.000 Recovery = 93.70%
/
Target Compounds Qvalue
(#) = qualifier out of range (m) = manual integration
RFV006.D V001E11.M Thu Jun 13 16:11:32 2024 Page 1
REPORT ID: 24E186 Page 40 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24F03\RFV006.D
Aeq On 3 Jun 2024 1:20 pm
Sample V001F01B
Mise 2SmL
Vial:
Operator:
Inst
Multiplr:
6
LPriet
01
1. 00
MS Integration Params: RTE.P
Quant Time: Jun 4 12:22 2024 Quant Results File: V001E11.RES
Method
Title
Last Update
Response via
fl\bundance
900000
850000
800000
750000
700000
650000
600000
550000
500000
450000
400000
350000
300000
250000
200000
150000
100000
50000
~ 0 ~ime--> 2.0 3.bi> 4.bo
. .A
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
Ill,;: RFV006.D
iii
Z
/;!l
Z w
CD
0
0:
0
::l
...J
"-is ....
"l. .,
C
IV
ti
E e
0
::l
'5 "l. E e ~ .c
i5
IV
.5 ~
~
0
~
'-~
..j
0
W
OJ z
~ 0 z W w z CD w 0 N 0: Z 0 W ...J CD J: 5! <..l
is g rI..
J:
<..l
If) g .,
~ .,
.c e
0 ::l
~ e
CD ...
~~~
5.bi> 6.bi> 7.bi> 8.bo 9.bo 10.00 11.00 12.00 13.00 14.00 15.00 16.00 1ioo 18.00 19.0020.0021.00
I
I
I
I
RFV006.D V001E11.M Thu Jun 13 16:11:33 2024 Page 2
REPORT ID: 24E186 Page 41 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24F03\RFV003.D
Acq On 3 Jun 2024 11:49 am
Sample V001F01L
Misc 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
Vial: 3
Operator: LPriet
Inst 01
TBA Multiplr: 1.00
Quant Time: Jun 3 12:11 2024 Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration ~-
V001E11
Internal Standards
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
72) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
3) Dichlorodifluoromethane
5) Chloromethane
6) Vinyl chloride
7) Bromomethane
8) Chloroethane
9) Dichlorofluoromethane
10) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
18) Methylene chloride
19) Carbon disulfide
20) Acrylonitrile
21) tert-Butyl methyl ether (M
22) trans-1,2-Dichloroethene
23) Isopropyl ether (DIPE)
24) Vinyl acetate
25) l,l-Dichloroethane
27) tert-Butyl ethyl ether (ET
28) 2-Butanone
29) 2,2-Dichloropropane
30) cis-1,2-Dichloroethene
31) Chloroform
R.T. QIon Response Conc Units Dev(Min)
8.55 114
13.71 117
18.69 152
7.23
7.97
11.03
16.01
2.18
2.49
2.62
3.15
3.20
3.29
3.57
3.98
4.09
4.06
4.23
4.34
4.65
4.65
4.86
4.89
5.03
5.06
5.26
5.67
5.83
5.83
6.23
6.41
6.63
6.68
6.91
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
142
43
49
76
53
73
61
45
43
63
59
43
77
96
83
860850
722112
303533
10.00 ug/l
10.00 ug/l
10.00 ug/l
275604 10.34
Recovery =
200104 11.01
Recovery =
1038085 9.59
Recovery =
397360 9.61
Recovery =
ug/l
103.40%
ugly
110.10%
ug/V
95.90%
ug/l/'
96.?-0%
0.00
0.00
0.01
0.00
0.00
0.00
0.00
223831
288087
245240
307634
185708
576012
392165
9.72 ug/l
8.93 ug/l
9.13 ug/l
9.66 ug/l
9.53 ug/l
Qvalue
100
99
97
85040
183031
177914
403251
253878
521077
117629
356160
1130615
198133
472631
404381
970104
357495
505782
662745
265643
415554
341175
530375
10.41 ug/l
10.79 ug/l
43.98 ug/l
10.08 ug/l
56.62 ug/l
8.78 ug/l
264.92 ug/l
10.59 ug/l
13.73 ug/l
9.67 ug/l
11.52 ug/l
49.70 ug/l
10.47 ug/l
9.14 ug/l
10.26 ug/l
11.02 ug/l
9.78 ug/l
9.79 ug/l
55.09 ug/l
9.55 ug/l
9.58 ug/l
10.06 ug/l
100
94
99
97
98
100
93
99
85
99
99
99
100
98
98
99
99
99
99
96
99
99
99
100
(#) = qualifier out of range (m) = manual integration
RFV003.D V001E11.M Thu Jun 13 16:12:20 2024 Page 1
REPORT ID: 24E186 Page 42 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24F03\RFV003.D
Acq On 3 Jun 2024 11:49 am
Vial: 3
Operator: LPriet
Sample V001F01L . Inst 01
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Jun 3 12:11 2024 Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. Qlon Response Conc Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) 1,1,1-Trichloroethane
36) Cyclohexane
38) 1,1-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) Benzene
43) 1,2-Dichloroethane
44) Trichloroethene
45) Methylcyclohexane
46) 1,2-Dichloropropane
47) Bromodichloromethane
48) 1,4-Dioxane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) 1,1,2-Trichloroethane
59) 2-Hexanone
60) l,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
63) 1,2-Dibromoethane
64) 1-Chlorohexane
65) Chlorobenzene
66) 1,1,1,2-Tetrachloroethane
67) Ethylbenzene
68) m-Xylene & p-Xylene
69) o-Xylene
70) Styrene
71) Isopropylbenzene
73) Bromoform
74) trans-1,4-Dichloro-2-buten
75) 1,l,2,2-Tetrachloroethane
77) 1,2,3-Trichloropropane
78) n-Propylbenzene
79) Bromobenzene
7.15
7.20
7.51
7.52
7.73
7.88
7.89
8.13
8.10
9.08
9.17
9.35
9.73
9.77
9.82
10.23
10.26
10.62
11.17
11.46
11. 48
11. 76
11.77
12.19
12.31
12.68
13.03
13.31
13.79
13.86
13.88
14.02
14.84
14.91
15.52
15.56
15.64
15.86
16.16
16.31
16.38
49
42
97
84
110
119
73
78
62
130
83
63
83
88
93
63
43
75
91
69
75
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
53
83
110
91
156
203993
32967
454727
428461
138338
341893
522590
1084091
259069
292383
493672
244597
366910
20536
125141
92299
678468
402468
1158555
194224
298389
169783
384285
288477
257403
208936
166030
499901
728073
232844
1390345
2055077
1040373
799263
1271806
122909
49266
184240
48603
1651970
288053
(#) = qualifier out of range (m) = manual integration
RFV003.D V001E11.M Thu Jun 13 16:12:21 2024
9.85 ug/l
10.81 ug/l
~.31 ug/l
9.97 ug/l
9.23 ug/l
10.41 ug/l
9.92 ug/l
9.43 ug/l
11.17 ug/l
9.83 ug/l
10.45 ug/l
9.51 ug/l
10.27 ug/l
194.94 ug/l
10.31 ug/l
14.13 ug/l
53.14 ug/l
10.05 ug/l
9.03 ug/l
10.09 ug/l
10.01 ug/l
10.11 ug/l
50.17 ug/l
10.12 ug/l
9.66 ug/l
10.19 ug/l
10.00 ug/l
9.03 ug/l
9.52 ug/l
9.89 ug/l
9.50 ug/l
19.18 ug/l
9.43 ug/l
9.35 ug/l
8.75 ug/l
10.24 ug/l
9.41 ug/l
9.12 ug/l
9.40 ug/l
8.37 ug/l
9.23 ug/l
Qvalue
99
92
100
98
99
100
99
100
100
98
100
94
99
92
99
100
97
99
99
93
97
100
97
99
99
99
98
99
100
100
98
97
98
98
99
98
97
100
97
99
99
Page 2
REPORT ID: 24E186 Page 43 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24F03\RFV003.D
Aeq On 3 Jun 2024 11:49 am
Vial: 3
Operator: LPriet
Sample V001F01L Inst 01
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Jun 3 12:11 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Cone Unit
80 ) l,3,5-Trimethylbenzene 16.60 105 1022271 8.11 ug/l
81) 2-Chlorotoluene 16.65 91 1033521 8.70 ug/l
82) 4-Chlorotoluene 16.73 91 899150 8.55 ug/l
83) tert-Butylbenzene 17.30 134 219070 8.28 ug/l
84) l,2,4-Trimethylbenzene 17.36 105 1019322 8.26 ug/l
85) see-Butylbenzene 17.65 105 1444224 8.33 ug/l
86) p-Isopropyltoluene 17.88 119 1121898 8.40 ug/l
87) l,3-Dichlorobenzene 18.02 146 541347 9.12 ug/l
88) l,2,3-Trimethylbenzene 18.14 105 956360 8.30 ug/l
89) l,4-Dichlorobenzene 18.19 146 515501 8.86 ug/l
90) n-Butylbenzene 18.50 91 1159058 8.37 ug/l
91) l,2-Dichlorobenzene 18.72 146 445165 9.16 ug/l
92) l,2-Dibromo-3-ehloropropan 19.73 157 28193 9.12 ug/l
93) 1, 2, 4-Triehlorobenzene 20.81 180 326164 9.19 ug/l
94) Hexaehlorobutadiene 20.97 225 179726 8.50 ug/l
95) Naphthalene 21.16 128 374692 9.04 ug/l
96 ) l,2,3-Triehlorobenzene 21.47 180 251752 9.42 ug/l
(#) = qualifier out of range (m) = manual integration
RFV003.D V001E11.M Thu Jun 13 16:12:21 2024
Qvalue
100
99
100
96
99
99
99
99
99
99
99
99
97
99
97
100
99
Page 3
REPORT ID: 24E186 Page 44 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24F03\RFV003.D Vial: 3
Acq On 3 Jun 2024 11:49 am
Sample V001F01L
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Operator:
Inst
Multiplr:
LPriet
01
1. 00
Quant Time: Jun 3 12:11 2024 Quant Results File: V001E11.RES
Method
Title
Last Update
Response via
~bundance
1900000
1800000
1700000
1600000
1500000
1400000
1300000
1200000
1100000
1000000
900000
800000
700000
600000
500000
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
"v: Kt"VUU;j.U
RFV003.D V001E11.M Thu Jun 13 16:12:24 2024 Page 4
REPORT ID: 24E186 Page 45 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24F03\RFV004.D
Acq On 3 Jun 2024 12:18 pm
Sample V001F01C
Vial:
Operator:
4
LPriet
01
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: Jun 3 12:40 2024
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V001E11.M
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Quant Results File: V001E11.RES
(RTE Integrator)
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) 1,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
72) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) 1,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
3) Dichlorodifluoromethane
5) Chloromethane
6) Vinyl chloride
7) Bromomethane
8) Chloroethane
9) Dichlorofluoromethane
10) Trichlorofluoromethane
11) Acrolein
12) 1,1,2-Trichloro-1,2,2-trif
13) Acetone
14) 1,1-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
18) Methylene chloride
19) Carbon disulfide
20) Acrylonitrile
21) tert-Butyl methyl ether (M
22) trans-1,2-Dichloroethene
23) Isopropyl ether (DIPE)
24) Vinyl acetate
25) l,l-Dichloroethane
27) tert-Butyl ethyl ether (ET
28) 2-Butanone
29) 2,2-Dichloropropane
30) cis-1,2-Dichloroethene
31) Chloroform
8.56 114
13.71 117
18.69 152
7.23
7.97
11.03
16.01
2.18
2.49
2.63
3.17
3.21
3.30
3.57
4.00
4.09
4.07
4.24
4.35
4.65
4.67
4.87
4.90
5.04
5.07
5.26
5.67
5.84
5.84
6.25
6.43
6.63
6.69
6.92
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
142
43
49
76
53
73
61
45
43
63
59
43
77
96
83
865358
730757
301967
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.01
0.00
0.01
275492 10.29
Recovery =
196226 10.74
Recovery =
1050483 9.59
Recovery =
389608 9.47
Recovery =
228041
285949
245705
305688
181532
602992
398818
79416
195139
158221
433610
246885
546216
107919
362060
1157306
181456
461151
425577
1006577
330610
534497
677789
245794
440295
348475
558727
9.85
8.82
9.10
9.54
9.27
10.84
10.92
40.86
10.69
50.09
9.39
256.28
11.04
12.53
9.78
11. 73
45.28
10.16
9.57
10.59
10.14
10.28
9.96
50.71
10.07
9.74
10.54
ug/l 0.00
102.90%
ug/V 0.00
107.40%
ug/l /" 0.00
95.90%
ug/V 0.00
94.70%
./ Qvalue
ug/l 100
ug/l 100
ug/l 97
ug/l 99
ug/l 90
ug/l 99
ug/l 99
ug/l 96
ug/l 99
ug/l 94
ug/l 100
ug/l 85
ug/l 98
ug/l 100
ug/l 97
ug/l 100
ug/l 98
ug/l 98
ug/l 100
ug/l 100
ug/l 100
ug/l 100
ug/l 96
ug/l 99
ug/l 99
ug/l 99
ug/l 99
(#) = qualifier out of range (m) = manual integration
RFV004.D V001E11.M Thu Jun 13 16:12:33 2024 Page 1
REPORT ID: 24E186 Page 46 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24F03\RFV004.D
Acq On 3 Jun 2024 12:18 pm
Sample V001F01C
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
4
LPriet
01
1. 00
Quant Time: Jun 3 12:40 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Conc Unit
32)
33)
35)
36)
38)
39)
40 )
42)
43}
44)
45)
46)
47)
48)
49)
50)
51)
52)
55)
56)
57)
58)
59)
60)
61)
62)
63)
64)
65)
66)
67)
68)
69)
70)
71)
73)
74)
75)
77)
78)
79)
Bromochloromethane
Tetrahydrofuran
1, 1, 1-Trichloroethane
Cyclohexane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
l,2-Dichloroethane
Trichloroethene
Methylcyclohexane
l,2-Dichloropropane
Bromodichloromethane
l,4-Dioxane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
Ethyl methacrylate
trans-1,3-Dichloropropene
l,l,2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, 1, 2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
trans-1,4-Dichloro-2-buten
1, 1,2, 2-Tetrachloroethane
1,2,3-Trichloropropane
n-Propylbenzene
Bromobenzene
7.15
7.21
7.51
7.54
7.73
7.89
7.89
8.13
8.12
9.08
9.17
9.36
9.73
9.79
9.83
10.23
10.28
10.62
11.17
11.46
11.48
11. 74
11. 77
12.20
12.31
12.68
13.03
13.31
13.79
13.86
13.88
14.02
14.84
14.91
15.52
15.56
15.64
15.86
16.16
16.29
16.38
49
42
97
84
110
119
73
78
62
130
83
63
83
88
93
63
43
75
91
69
75
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
53
83
110
91
156
204743
27159
485907
439159
144760
362885
521620
1138355
261711
315279
505617
253558
380324
20414
128933
91908
639449
415964
1229503
199874
301082
170277
353038
293826
277186
213094
167866
535888
764889
239508
1451883
2172918
1104017
846234
1338687
122796
48328
181675
47493
1772693
297704
(#) = qualifier out of range (m) = manual integration
RFV004.D V001E11.M Thu Jun 13 16:12:34 2024
9.84
8.86
10.96
,~10.17
9.61
10.99
9.85
9.85
11. 23
10.54
10.64
9.80
10.59
192.77
10.57
14.00
49.99
10.33
9.47
10.26
9.98
10.02
45.99
10.19
10.28
10.27
9.99
9.56
9.89
10.05
9.80
20.04
9.89
9.78
9.11
10.28
9.28
9.04
9.23
9.03
9.58
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
97
96
99
98
100
100
99
99
99
98
99
94
100
93
97
98
97
99
100
97
97
99
97
100
99
99
99
99
100
99
98
97
98
98
99
98
97
99
98
99
100
Page 2
REPORT ID: 24E186 Page 47 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24F03\RFV004.D
Aeq On 3 Jun 2024 12:18 pm
Sample V001F01C
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
4
LPriet
01
1. 00
Quant Time: Jun 3 12:40 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. Qlon Response Cone Unit
80) l,3,5-Trimethylbenzene 16.60 105 1083897 8.64 ug/l
81) 2-Chlorotoluene 16.64 91 1098832 9.30 ug/l
82) 4-Chlorotoluene 16.73 91 927341 8.86 ug/l
83) tert-Butylbenzene 17.28 134 239796 9.11 ug/l
84) l,2,4-Trimethylbenzene 17.36 105 1092231 8.90 ug/l
85) see-Butylbenzene 17.65 105 1538370 8.92 ug/l
86) p-Isopropyltoluene 17.87 119 1170492 8.80 ug/l
87) l,3-Diehlorobenzene 18.02 146 565605 9.58 ug/l
88) l,2,3-Trimethylbenzene 18.13 105 1011172 8.82 ug/l
89) l,4-Diehlorobenzene 18.19 146 545897 9.43 ug/l
90) n-Butylbenzene 18.50 91 1254757 9.11 ug/l
91) l,2-Diehlorobenzene 18.72 146 463985 9.59 ug/l
92) l,2-Dibromo-3-ehloropropan 19.71 157 28706 9.32 ug/.l
93) l,2,4-Triehlorobenzene 20.81 180 346899 9.82 ug/l
94) Hexaehlorobutadiene 20.97 225 195310 9.28 ug/l
95) Naphthalene 21.15 128 384254 9.32 ug/l
96) l,2,3-Triehlorobenzene 21.47 180 265438 9.98 ug/l
(#) = qualifier out of range (m) = manual integration
RFV004.D V001E11.M Thu Jun 13 16:12:34 2024
Qvalue
100
100
100
97
99
99
99
99
100
99
99
99
100
99
97
100
100
Page 3
REPORT ID: 24E186 Page 48 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24F03\RFV004.D
Aeq On 3 Jun 2024 12:18 pm
Sample V001F01C
Mise 10ppb 8260/S0ppb KET-AA/2S0ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
4
LPriet
01
1. 00
Quant Time: Jun 3 12:40 2024 Quant Results File: V001E11.RES
Method
Title
Last Update
Response via
Abundance
2000000
1900000
1800000
1700000
1600000
1500000
1400000
1300000
1200000
1100000
1000000
900000
800000
700000
600000
500000
400000
300000
200000
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 2Smls
Mon May 13 13:20:11 2024
Initial Calibration
II~: KrVUU4.U
:t o
~ c:
" ~ 6
::;; ..:
" ~ ~
::;; ..:
" c:
" ::;;~
..:~
~'fij ~ .~
::;; 1!J; ..: ~<:! ~ e .
" a. ~ c
il ~ e
Q, ~ 0
.!!!
M
" :J
0 e ~ en
ai c:
" ~
" ~ .0 e
0
:J
'5
E e
In
..j.
~~ Ii
~~
II
~~
~
::;; ..:
" c:
::;; ~ ::;;..: " .0
~ ..,:~ ." In ~~ c
:q~::;;
1-• .0 e . Q)~g.~ ~rgi~
" " en .0 ... f ~ 0
W ~ i z
cu. I ~
!#.l "e ; .00 ~ <!}
l
I i I
I
::;; ..:
" c: .,
Q, e
Q, e
.2
~
E e
.0
i5
N.
l , , '-J 1 ~ ~ l ,_ ,,1
::;; ....:.
~ ~~
.8§ ~ .!2c ::;; tie 'cQ ..: ~ ~ ~ ~
"':J: " .0 e
.2 :g
l-~~ I-.
ai~ c:
~
,£; .c: ~I
11 I
11
10000: iflt ~ l I~
Time-> 2.bo 3.bo 4.bi> 5.bi> 6.bi> 7.bo 8.bi> 9.bo 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.0020.0021.00
RFV001.D V001E11.M Thu .J1.ln 13 16:: 12: 38 2024 Page 4
REPORT ID: 24E186 Page 49 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24F03\RFV011.D
Acq On 3 Jun 2024 3:52 pm
Sample 24E186-02M
Misc 25mL
MS Integration Params: RTE.P
Quant Time: Jun 3 16:14 2024
Vial: 11
Operator: LPriet
Inst 01
Multiplr: 1.00
Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 8.56 114 767644 10.00 ug/l 0.02
53) CHLOROBENZENE-D5 13.73 117 634144 10.00 ug/l 0.01
72) l,2-DICHLOROBENZENE-D4 18.69 152 271494 10.00 ug/l 0.01
System Monitoring Compounds
34) Dibromofluoromethane 7.23 111 246352 10.37 ug/l 0.00
Spiked Amount 10.000 Recovery = 103.70%"
41) l,2-Dichloroethane-d4 7.97 65 175612 10.84 ug/l 0.00
Spiked Amount 10.000 Recovery = 108.4()%
54) Toluene-d8 11.03 98 923004 9.71 ug/l .~ 0.00
Spiked Amount 10.000 Recovery = 97.10%"
76) 4-Bromofluorobenzene 16.02 95 350346 9.47 ug/l / 0.01
Spiked Amount 10.000 Recovery = 94.70%"
./ Target Compounds Qvalue
3) Dichlorodifluoromethane 2.18 85 236585 11.52 ug/l 100
5) Chloromethane 2.48 50 273901 9.52 ug/l 99
6) Vinyl chloride 2.62 62 237455 9.91 ug/l 97
7) Bromomethane 3.17 94 289075 10.19 ug/l 100
8) Chloroethane 3.21 64 172090 9.90 ug/l 90
9) Dichlorofluoromethane 3.29 67 552823 11. 20 ug/l 98
10 ) Trichlorofluoromethane 3.57 101 397433 12.26 ug/l 98
11) Acrolein 4.00 56 66750 38.71 ug/l 97
12) l,l,2-Trichloro-1,2,2-trif 4.09 151 177514 10.96 ug/l 100
13) Acetone 4.06 43 124140 44.30 ug/l 92
14) l,l-Dichloroethene 4.23 61 379742 9.28 ug/l 98
15) tert-Butyl alcohol 4.35 59 183803 215.09 ug/l 81
16 ) Iodomethane 4.65 142 474544 10.81 ug/l 96
17) Methyl acetate 4.65 43 92096 12.05 ug/l 100
18) Methylene chloride 4.87 49 311480 9.48 ug/l 98
19) Carbon disulfide 4.89 76 1047348 11. 96 ug/l 100
20 ) Acrylonitrile 5.03 53 156379 43.99 ug/l 100
21) tert-Butyl methyl ether (M 5.06 73 381018 9.46 ug/l 92
22) trans-1,2-Dichloroethene 5.26 61 377657 9.57 ug/l 99
23) Isopropyl ether (DIPE) 5.67 45 839969 9.97 ug/l 99
24) vinyl acetate 5.83 43 311352 10.76 ug/l 98
25) l,l-Dichloroethane 5.83 63 460822 9.99 ug/l 100
27) tert-Butyl ethyl ether (ET 6.25 59 554667 9.18 ug/l 97
28 ) 2-Butanone 6.43 43 190931 44.41 ug/l 99
29 ) 2,2-Dichloropropane 6.63 77 382720 9.87 ug/l 98
30) cis-1,2-Dichloroethene 6.69 96 301234 9.49 ug/l 98
31) Chloroform 6.91 83 503211 10.70 ug/l 99
(#) = qualifier out of range (m) = manual integration
RFV011.D V001E11.M Thu Jun 13 14:47:36 2024 Page 1
REPORT ID: 24E186 Page 50 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24F03\RFV011.D
Acq On 3 Jun 2024 3:52 pm
Sample 24E186-02M
Misc 25mL
(QT Reviewed)
Vial: 11
Operator: LPriet
Inst 01
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Jun 3 16:14 2024 Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. Qlon Response Conc Unit
32)
33)
35)
36)
38 )
39)
40 )
42)
43)
44)
45 )
46)
47)
48 )
49)
51)
52)
55)
56 )
57)
58)
59)
60)
61 )
62)
63)
64)
65 )
66)
67)
68)
69)
70 )
71)
73)
74)
75)
77)
78)
79)
80 )
Bromochloromethane
Tetrahydrofuran
1, 1, 1-Trichloroethane
Cyclohexane
1,1-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
1,2-Dichloroethane
Trichloroethene
Methylcyclohexane
1,2-Dichloropropane
Bromodichloromethane
1,4-Dioxane
Dibromomethane
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
Ethyl methacrylate
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
2-Hexanone
1,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
1,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, 1,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
trans-1,4-Dichloro-2-buten
1, 11 21 2-Tetrachloroethane
1, 2, 3-Trichloropropane
n-Propylbenzene
Bromobenzene
l,3,5-Trimethylbenzene
7.15
7.21
7.51
7.54
7.73
7.89
7.89
8.13
8.11
9.08
9.17
9.36
9.73
9.79
9.83
10.28
10.63
11.17
11.48
11.49
11. 76
11.77
12.20
12.31
12.68
13.05
13.31
13.80
13.88
13.89
14.02
14.85
14.91
15.53
15.56
15.64
15.88
16.16
16.30
16.39
16.62
49
42
97
84
110
119
73
78
62
130
83
63
83
88
93
43
75
91
69
75
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
53
83
110
91
156
105
177117
29875
431289
393783
124091
363819
422392
990852
231765
1156930
453060
214049
326383
15898
108321
458928
342057
1056943
160278
248315
142642
278739
250877
238167
177873
138565
460660
642660
205525
1269795
1928143
991031
737384
1191989
103000
38975
156226
40705
1589037
263744
950725
(#) = qualifier out of range (m) = manual integration
RFV011.D V001E11.M Thu Jun 13 14:47:37 2024
9.59 ug/l
10.99 ug/l
~10. 97 ug/l
10.28 ug/l
9.28 ug/l
12.42 ug/l
8.99 ug/l
9.66 ug/l
11.21 ug/l
43.62 ug/l
10.75 ug/l
9.33 ug/l
10.25 ug/l
169.24 ug/l
10.01 ug/l
40.96 ug/l
9.58 ug/l
9.39 ug/l
9.48 ug/l
9.49 ug/l
9.67 ug/l
42.28 ug/l
10.02 ug/l
10.17 ug/l
9.88 ug/l
9.50 ug/l
9.47 ug/l
9.57 ug/l
9.94 ug/l
9.88 ug/l
20.49 ug/l
10.23 ug/l
9.82 ug/l
9.34 ug/l
9.61 ug/l
8.32 ug/l
8.64 ug/l
8.80 ug/l
9.00 ug/l
9.44 ug/l
8.43 ug/l
Qvalue
99
80
99
98
100
100
99
99
99
99
96
93
100
89
97
98
98
99
94
96
99
95
100
99
99
98
99
100
100
97
97
98
98
99
97
99
100
99
98
99
99
Page 2
REPORT ID: 24E186 Page 51 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24F03\RFV011.D
Aeq On 3 Jun 2024 3:52 pm
Sample 24E186-02M
Mise 25mL
(QT Reviewed)
Vial: 11
Operator: LPriet
Inst 01
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Jun 3 16:14 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Cone Unit
81) 2-Chlorotoluene 16.65 91 945324 8.89 ug/l
82) 4-Chlorotoluene 16.73 91 842739 8.96 ug/l
83) tert-Butylbenzene 17.30 134 211860 8.95 ug/l
84) l,2,4-Trimethylbenzene 17.36 105 954252 8.65 ug/l
85) see-Butylbenzene 17.67 105 1356194 8.75 ug/l
86) p-Isopropyltoluene 17.89 119 1046097 8.75 ug/l
87) l,3-Diehlorobenzene 18.04 146 488392 9.20 ug/l
88) 1, 2, 3-Trimethylbenzene 18.14 105 881702 8.56 ug/l
89) l,4-Diehlorobenzene 18.20 146 482933 9.28 ug/l
90 ) n-Butylbenzene 18.50 91 1085526 8.77 ug/l
91) l,2-Diehlorobenzene 18.72 146 402034 9.25 ug/l
92) l,2-Dibromo-3-ehloropropan 19.73 157 22594 8.23 ug/l
93) l,2,4-Triehlorobenzene 20.81 180 282431 8.90 ug/l
94) Hexaehlorobutadiene 20.98 225 167853 8.87 ug/l
95) Naphthalene 21.16 128 304492 8.22 ug/l
96) 1, 2, 3-Triehlorobenzene 21.47 180 211443 8.84 ug/l
(#) = qualifier out of range (m) = manual integration
RFV011.D V001E11.M Thu Jun 13 14:47:38 2024
Qvalue
99
100
100
99
100
99
99
99
99
99
100
100
99
97
100
99
Page 3
REPORT ID: 24E186 Page 52 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24F03\RFVOll.D
Aeq On 3 Jun 2024 3:52 pm
Sample 24E186-02M
Mise 25mL
Vial:
Operator:
Inst
Multiplr:
11
LPriet
01
1. 00
MS Integration Params: RTE.P
Quant Time: Jun 3 16:14 2024 Quant Results File: VOOIEll.RES
Method
Title
Last Update
Response via
I bundance
:::;:
:t
~
:::;:
400000 r::;:
~
[}>.
300000 I
200000 S ~
100000
D:\HPCHEM\l\METHODS\VOOIEll.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
TIc:RFV01T.D
11.00 12.00 1
:::;: r-:
Q) c:
j
:::;: r-:
Q) c:
Q)
N c:
Q)
.0 >. a. e a.
0
.!!l
:::;: r-: :::;: Q) c: r-: Q)
N Q)
c: c:
Q) ~ .n >. j a. e a.
~
df.
~.
$"
RFVOll.D VOOIEll.M Thu Jun 13 14:47:41 2024 Page 4
REPORT ID: 24E186 Page 53 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24F03\RFV012.D
Acq On 3 Jun 2024 4:21 pm
Sample 24E186-02S
Misc 25mL
(QT Reviewed)
Vial: 12
Operator: LPriet
Inst 01
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Jun 3 16:43 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 8.56 114 824891 10.00 ug/l 0.02
53) CHLOROBENZENE-D5 13.73 117 681937 10.00 ug/l 0.01
72) l,2-DICHLOROBENZENE-D4 18.69 152 285916 10.00 ug/l 0.01
System Monitoring Compounds
34) Dibromofluoromethane 7.24 111 263716 10.33 ug/l 0.01
Spiked Amount 10.000 Recovery = 103.30%
41) l,2-Dichloroethane-d4 7.97 65 185793 10.67 ug/l'-0.00
Spiked Amount 10.000 Recovery = 106.70%
54) Toluene-d8 11.03 98 969509 9.49 ug/l/" 0.00
Spiked Amount 10.000 Recovery = 94..",90%
76) 4-Bromofluorobenzene 16.02 95 367573 9.44 ug/l 0.01
Spiked Amount 10.000 Recovery = 94.40%
/
Target Compounds Qvalue
3) Dichlorodifluoromethane 2.18 85 268025 12.14 ug/l 99
5) Chloromethane 2.49 50 262015 8.48 ug/l 99
6) Vinyl chloride 2.62 62 260466 10.12 ug/l 97
7) Bromomethane 3.17 94 287132 9.40 ug/l 99
8) Chloroethane 3.21 64 203092 10.88 ug/l 96
9) Dichlorofluoromethane 3.29 67 502089 9.47 ug/l 98
10) Trichlorofluoromethane 3.57 101 400799 11.51 ug/l 99
11) Acrolein 3.98 56 88048 47.52 ug/l 97
12) l,l,2-Trichloro-1,2,2-trif 4.09 151 191636 11.01 ug/l 99
13) Acetone 4.06 43 142108 47.20 ug/l 94
14) l,l-Dichloroethene 4.24 61 435149 9.89 ug/l 99
15) tert-Butyl alcohol 4.34 59 221066 240.74 ug/l 83
16) Iodomethane 4.65 142 493432 10.46 ug/l 98
17) Methyl acetate 4.66 43 100170 12.20 ug/l 99
18) Methylene chloride 4.87 49 335308 9.50 ug/l 97
19) Carbon disulfide 4.89 76 858947 9.13 ug/l 99
20 ) Acrylonitrile 5.03 53 181625 47.55 ug/l 98
21) tert-Butyl methyl ether (M 5.06 73 425262 9.83 ug/l 97
22) trans-1,2-Dichloroethene 5.26 61 406972 9.60 ug/l 99
23) Isopropyl ether (DIPE) 5.69 45 866331 9.57 ug/l 100
24) Vinyl acetate 5.83 43 318669 10.25 ug/l 99
25) l,l-Dichloroethane 5.83 63 477699 9.64 ug/l 99
27) tert-Butyl ethyl ether (ET 6.25 59 631287 9.73 ug/l 99
28) 2-Butanone 6.43 43 234534 50.76 ug/l 99
29) 2,2-Dichloropropane 6.65 77 401834 9.64 ug/l 99
30) cis-1,2-Dichloroethene 6.69 96 333484 9.77 ug/l 99
31) Chloroform 6.92 83 525288 10.40 ug/l 99
(#) = qualifier out of range (m) = manual integration
RFV012.D V001E11.M Thu Jun 13 14:48:03 2024 Page 1
REPORT ID: 24E186 Page 54 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24F03\RFV012.D
Acq On 3 Jun 2024 4:21 pm
Sample 24E186-02S
Misc 25mL
(QT Reviewed)
Vial: 12
Operator: LPriet
Inst 01
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Jun 3 16:43 2024 Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. Qlon Response Conc Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) l,l,l-Trichloroethane
36) Cyclohexane
38) l,l-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) Benzene
43) l,2-Dichloroethane
44) Trichloroethene
45) Methylcyclohexane
46) l,2-Dichloropropane
47) Bromodichloromethane
48) l,4-Dioxane
49) Dibromomethane
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) l,l,2-Trichloroethane
59) 2-Hexanone
60) l,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
63) l,2-Dibromoethane
64) 1-Chlorohexane
65) Chlorobenzene
66) l,l,l,2-Tetrachloroethane
67) Ethylbenzene
68) m-Xylene & p-Xylene
69) o-Xylene
70) Styrene
71) Isopropylbenzene
73) Bromoform
74) trans-1,4-Dichloro-2-buten
75) l,l,2,2-Tetrachloroethane
77) l,2,3-Trichloropropane
78) n-Propylbenzene
79) Bromobenzene
80) l,3,5-Trimethylbenzene
7.17
7.21
7.51
7.54
7.73
7.89
7.91
8.14
8.12
9.08
9.17
9.36
9.74
9.80
9.83
10.28
10.63
11.18
11.48
11. 49
11. 76
11.77
12.20
12.31
12.68
13.05
13.33
13.80
13.88
13.89
14.02
14.85
14.93
15.53
15.58
15.65
15.88
16.16
16.30
16.39
16.62
49
42
97
84
110
119
73
78
62
130
83
63
83
88
93
43
75
91
69
75
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
53
83
110
91
156
105
195205
30123
440576
442637
134682
372754
455634
1026198
242974
1205027
485536
225656
347540
18026
123174
521693
368082
1148106
174327
272194
161584
319639
267641
250611
196369
157206
485321
688762
226761
1354397
1962068
1014057
739276
1314672
105190
42156
173127
44577
1611662
282208
1024359
(#) = qualifier out of range (m) = manual integration
RFV012.D V001E11.M Thu Jun 13 14:48:04 2024
9.84 ug/l
10.31 ug/l
10.42 ug/l
rio.75 ug/l
9.38 ug/l
11.84 ug/l
9.02 ug/l
9.31 ug/l
10.93 ug/l
42.28 ug/l
10.72 ug/l
9.15 ug/l
10.15 ug/l
178.57 ug/l
10.59 ug/l
43.18 ug/l
9.59 ug/l
9.48 ug/l
9.59 ug/l
9.67 ug/l
10.19 ug/l
44.76 ug/l
9.94 ug/l
9.96 ug/l
10.15 ug/l
10.02 ug/l
9.28 ug/l
9.54 ug/l
10.20 ug/l
9.80 ug/l
19.39 ug/l
9.74 ug/l
9.16 ug/l
9.58 ug/l
9.33 ug/l
8.55 ug/l
9.10 ug/l
9.15 ug/l
8.67 ug/l
9.60 ug/l
8.62 ug/l
Qvalue
97
87
99
98
100
100
98
100
99
99
96
94
100
90
97
98
99
99
92
97
98
97
100
99
100
99
99
100
99
98
97
98
97
99
98
99
99
99
99
99
99
Page 2
REPORT ID: 24E186 Page 55 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24F03\RFV012.D
Aeq On 3 Jun 2024 4:21 pm
Sample 24E186-02S
Mise 25mL
(QT Reviewed)
Vial: 12
Operator: LPriet
Inst 01
Multiplr: 1.00
MS Integration Params: RTE.P
Quant Time: Jun 3 16:43 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Cone Unit
81) 2-Chlorotoluene 16.65 91 1064924 9.51 ug/l
82) 4-Chlorotoluene 16.75 91 844192 8.52 ug/l
83) tert-Butylbenzene 17.30 134 218130 8.75 ug/l
84) l,2,4-Trimethylbenzene 17.37 105 1012783 8.71 ug/l
85) see-Butylbenzene 17.67 105 1399219 8.57 ug/l
86 ) p-Isopropyltoluene 17.89 119 1100884 8.75 ug/l
87 ) l,3-Diehlorobenzene 18.04 146 520709 9.32 ug/l
88) 1, 2, 3-Trimethylbenzene 18.14 105 962153 8.87 ug/l
89 ) l,4-Diehlorobenzene 18.20 146 515900 9.42 ug/l
90 ) n-Butylbenzene 18.50 91 1161986 8.91 ug/l
91) l,2-Diehlorobenzene 18.73 146 430817 9.41 ug/l
92) l,2-Dibromo-3-ehloropropan 19.73 157 25448 8.76 ug/l
93) l,2,4-Triehlorobenzene 20.82 180 311863 9.33 ug/l
94) Hexaehlorobutadiene 20.98 225 182949 9.18 ug/l
95) Naphthalene 21.16 128 358939 9.20 ug/l
96 ) l,2,3-Triehlorobenzene 21.49 180 242737 9.64 ug/l
(#) = qualifier out of range (m) = manual integration
RFV012.D V001E11.M Thu Jun 13 14:48:04 2024
Qvalue
99
100
98
98
100
99
99
99
99
98
99
99
99
98
100
99
Page 3
REPORT ID: 24E186 Page 56 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24F03\RFV012.D
Aeq On 3 Jun 2024 4:21 pm
Sample 24E186-02S
Mise 2SmL
Vial:
Operator:
Inst
Multiplr:
12
LPriet
01
1. 00
MS Integration Params: RTE.P
Quant Time: Jun 3 16:43 2024 Quant Results File: V001E11.RES
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 2Smls
Last Update
Response via
Mon May 13 13:20:11 2024
Initial Calibration
11(,;: KI-VU1~.U
2200000
2100000
2000000
~
1900000
1 BOOOOO
1700000
1600000
1500000
1400000
1300000
1200000
1100000
1000000
::ii ::ii.
900000
BOOOOO
700000
600000
'j !:;~ l!j ~. ::ii~~'iz • r: ~ ~e ~ ;; ~ Q) H,·,m ~ or::; ~ oCO ~
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Irime--> 2.bo 3.bo 4.bo 5.bo 6.bb 7.bb B.bo 9.)0 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 1B.00 19.0020.0021.00
RFV012.D V001E11.M Thu Jun 13 14:48:08 2024 Page 4
REPORT ID: 24E186 Page 57 of 217
INITIAL CALIBRATION(S)
REPORT ID: 24E186 Page 58 of 217
Lab Name
Lab Code
FORM 5
VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK
BROMOFLUOROBENZENE (BFB)
EMAX Laboratories, Inc.
EMAX
Project
SDG No
ICAL
I CAL
Lab File ID: REV195
Instrument ID: 01
BFB Injection Date: 05/11/24
BFB Injection Time: 10:20
% RELATIVE
1 m/e 1 ION ABUNDANCE CRITERIA ABUNDANCE
1=====1========================================1================1
50 15 -40% of mass 95 18.517 1
75 30 -60% of mass 95 42.491
95 Base Peak, 100% relative abundance __ 1 100.000
96 5 -9% of mass 95 7.286
173 Less than 2% of mass 174 0.000(0)1
174 Greater than 50% of mass 95 75.428
175 5 -9% of mass 174 5.582(7.4)1
176 95 -101% % of mass 174 72.070(95.55)1
177 5 -9% % of mass 176 5.085(7.06)2
1 __ 1 ___________________ _
I-Value is % mass 174 2-Value is % mass 176
This check applies to the following Calibration Standards:
EPA LAB LAB 1 DATE TIME
1 SAMPLE NO. 1 SAMPLE ID 1 FILE ID 1 ANALYZED 1 ANALYZED 1
1====================1================1============1==========1==========1
II VSTDO.3 IVOOIEl11 IREVl96 05/11/24 10:58
2IVSTDO.5 IVOOIE112 IREV197 05/11/24 11:27
31VSTDI IVOOIE113 IREV198 05/11/24 11:56
41VSTD2 IV001E114 IREV199 05/11/24 12 :30
51VSTD5 IVOOIE115 IREV200 05/11/24 12 :59
61 VSTDI0 IV001E116 IREV201 05/11/24 13:28
71vSTD20 IVOOIE117 IREV202 05/11/24 13:58
81 VSTD 30 IV001E118 IREV203 05/11/24 14:27
91VSTD50 IVOOIE119 IREV204 05/11/24 14:56
10lVSTDI00 IVOOIDEI110 IREV205 05/11/24 15:26
REPORT ID: 24E186 Page 59 of 217
~nstru~ent ID 'Ql e~~~nug~t Da~stame : 05/11/24 10: 5B e Flle :REVZOI
--
INITIAL_CALIBRATION -RELATIVE_RESPONSE_FACTOR
'Jse Least Sguare Linle~rAmRegreS~iOn with weighting factor of inverse concentration for comps with % RSD > 15 ~esp_Ratlo -xo + x t_Ratlo -
IDl I~~~~~!~~~~entanone :-~~,~~~~l ~~,l~~~1 ~~,I~~ ~ ~ 1/1~ ! ;!'B,g~.,.3.'h'o",,,P'"' ! !!!! ! lsI! ! III ~ 'I",> I
1 :
1 :
: [g 1~~
J~ ,~
3 :
REPORT ID: 24E186 Page 60 of 217
Instrument ID :01
Be~innin~ DateTime :05/11/24 10:58
Splke Unlts :PPB
IC File :REV201
M IDX Parameters
======= =====================================
1 1,4-DIFLUOROBENZENE
2 Chlorotrifluoroethylene
3 Dichlorodifluoromethane
4 2-Chloro-l,1,1-trifluoroethane
5 Chloromethane
6 Vinyl chloride
7 Bromomethane
8 Chloroethane
9 Dichlorofluoromethane
10 Trichlorofluoromethane
5 11 Acrolein
12 1,1,2-Trichloro-1,2,2-trifluoroethane
5 13 Acetone
14 1,1-Dichloroethene
25 15 tert-Butyl alcohol
16 Iodomethane
17 Methyl acetate
18 Methylene chloride
19 Carbon disulfide
5 20 Acrylonitrile
21 tert-Butyl methyl ether (MTBE)
22 trans-1,2-Dichloroethene
23 Isopropyl ether (DIPE)
24 Vinyl acetate
25 1,1-Dichloroethane
25 26 2-Butanol
27 tert-Butyl ethyl ether (ETBE)
5 28 2-Blltanone
29 2,2-Dichloropropane
30 cis-1,2-Dichloroethene
31 Chloroform
32 Bromochloromethane
33 Tetrahydrofuran
34 Dibromofluoromethane
35 1,1, I-Trichloroethane
36 Cyclohexane
37 2,2,4-Trimethylpentane
38 1,1-Dichloropropene
39 Carbon tetrachloride
40 tert-Amyl methhl ether (TAME)
41 1,2-Dichloroet ane-d4
42 Benzene
43 1,2-Dichloroethane
44 Trichloroethene
45 Methylcyclohexane
46 1,2-Dichloropropane
47 Bromodichloromethane
20 48 1,4-Dioxane
49 Dibromomethane
50 2-Chloroethyl vinyl ether
5 51 4-Methyl-2-pentanone
52 ciS-1,3-Dichloropropene
53 CHLOROBENZENE-D5
54 Toluene-d8
55 Toluene
56 Ethyl methacrylate
57 trans-l,3-Dichloropropene
58 1,1,2-Trichloroethane
5 59 2-Hexanone
60 1,3-Dichloropropane
61 Tetrachloroethene
62 Dibromochloromethane
63 1,2-Dibromoethane
64 1-Chlorohexane
65 Chlorobenzene
66 1,1,1,2-Tetrachloroethane
67 Ethylbenzene
2 68 m-Xylene & p-Xylene
69 o-Xylene
70 Styrene
71 Isopropylbenzene
72 1,2-DICHLOROBENZENE-D4
73 Bromoform
74 trans-1,4-Dichloro-2-butene
75 1, 1, 2, 2-Tetrachloroethane
76 4-Bromofluorobenzene
77 1,2,3-Trichloropropane
78 n-Propylbenzene
79 Bromobenzene
80 1,3,5-Trimethylbenzene
81 2-Chlorotoluene
82 4-Chlorotoluene
83 tert-But¥lbenzene
84 1,2,4-Trlmethylbenzene
85 sec-Butylbenzene
86 p-Iso~ropyltoluene
87 1,3-Dlchlorobenzene
88 1,2,3-Trimethylbenzene
89 1,4-Dichlorobenzene
90 n-But¥lbenzene
91 1,2-Dlchlorobenzene
92 1,2-Dibromo-3-chloropropane
93 1,2,4-Trichlorobenzene
94 Hexachlorobutadiene
95 Naphthalene
96 1,2,3-Trichlorobenzene
----
INITIAL_CALIBRATION -RELATIVE_RESPONSE_FACTOR(%REC)
.3 .5
11: 5~ 12:3~ 10:58 11:27
REVl96 REV197 REV198 REV199
------------------======
1 1 1 1
------------------------
103 108 92 102
------------------------
114 108 97 105
98 102 91 108
------114 99 101
104 101 95 96
117 110 98 100
104 110 96 105
------------------100
82 103 93 109
------------132 100
97 103 91 103
91 91 91 100
97 99 92 100
------------------114
105 103 98 102
110 95 94 99
107 100 96 96
102 105 95 101
98 101 96 102
100 102 94 99
------90 84 95
97 102 94 102
------------------------
98 98 96 105
------89 88 89
104 105 95 101
98 102 95 99
117 109 97 97
98 102 93 100
------------------109
92 106 93 106
100 105 95 100
101 109 95 105
------------------------
97 104 97 102
102 103 92 101
108 102 97 102
99 102 91 109
104 105 95 101
99 100 94 102
97 98 92 99
103 110 98 106
102 105 91 98
114 107 95 99
------------------76
96 103 96 101
------------88 96
------------115 93
99 97 93 98
1 1 1 1
99 102 92 108
102 108 93 101
------------87 98
97 98 91 100
106 98 94 102
------------123 93
96 98 95 103
98 106 95 103
107 104 93 98
93 96 93 102
103 107 93 103
99 103 95 101
100 101 96 101
102 106 94 101
103 107 96 102
107 106 96 102
103 102 96 101
101 106 94 102
1 1 1 1
------116 98 104
------------84 97
111 100 93 98
107 106 93 101
1------83 90 102
103 108 91 97
97 102 91 97
105 108 90 97
103 109 95 95
100 106 89 101
104 102 91 97
103 106 92 98
105 108 90 99
102 109 91 101
100 107 92 98
105 108 94 99
108 107 94 98
106 109 92 99
101 104 95 100
------------114 106
93 98 89 98
95 99 88 96
93 95 88 97
95 97 90 99
------------
12 :5~ 13:~~ 13:~~
REV200 REV201 REV202
====== ====== ======
1 1 1
------------------
99 95 101
------------------
101 93 101
108 99 106
95 88 103
100 93 104
94 90 102
101 94 99
100 91 109
100 100 106
97 84 95
98 96 107
100 91 109
98 95 108
101 84 102
98 93 104
101 94 108
100 93 104
98 90 105
98 93 107
98 94 108
105 91 110
98 94 108
------------------
99 92 108
96 95 109
97 94 105
98 95 107
96 90 103
99 93 107
97 86 106
103 91 108
97 94 106
102 91 103 ------------------
97 94 106
96 96 105
96 88 104
103 88 107
99 94 105
99 93 107
97 97 108
100 90 101
96 93 107
97 90 104
93 89 110
99 89 106
95 91 108
93 87 101
98 93 108
1 1 1
102 93 105
97 96 103
94 93 109
98 94 108
97 93 104
93 87 101
96 93 107
96 97 104
95 92 105
99 93 109
95 97 103
97 97 106
96 96 106
97 98 105
98 96 105
96 95 103
97 96 106
97 97 106
1 1 1
96 86 101
94 90 109
96 89 104
98 90 106
99 94 110
96 97 106
98 96 108
96 97 106
96 95 104
100 98 107
96 97 107
97 97 106
96 97 106
97 96 106
96 96 107
97 95 105
97 95 105
96 97 106
98 93 106
96 83 100
97 95 110
96 100 111
96 93 111
97 95 110
---------
~ ~ ;LtRo
S L,/'-
5(\S!v{
14:~~
REV203
======
1
------
99 ------
94
98
97
100
95
96
100
103
92
101
109
102
97
96
99
100
100
101
100
106
101 ------
101
109
100
101
95
103
100
101
99
94
------
101
100
99
102
98
101
101
93
100
96
106
101
107
99
103
1
98
97
103
102
100
99
101
99
99
103
99
99
99
99
98
98
100
99
1
97
104
100
98
104
99
101
99
98
100
99
100
98
98
100
99
98
99
99
96
106
105
107
104
---
Column Spec :RXI-624SILMS ID :0.25MM
Ending DateTime :05/11/24 15:26
HPChem Method :V001E11
14:~~ 15~~~
REV204 REV205 AvDRec %_RSD AV_Rt_M
====== ====== ====== ------=======
1 1 1 0 8.5509
------------0.000 0.00 0.0000
102 99 3.4 4.44 2.1690 ------_ .. ----0.000 0.00 0.0000
97 90 5.9 7.39 2.4709
100 90 4.8 6.31 2.6048
103 100 12.3 17.96 3.1458
106 103 3.4 4.21 3.1896
100 93 5.9 8.21 3.2755
100 95 4.1 5.20 3.5526
109 105 4.5 5.86 3.9857
108 95 5.9 8.11 4.0696
100 92 9.1 14.45 4.0577
106 99 3.7 4.74 4.2296
118 109 8.2 9.12 4.3422
107 102 3.6 4.85 4.6385 ------------7.2 10.84 4.6531
103 97 3.4 3.90 4.8577 ------------4.7 6.08 4.8800
107 102 3.5 4.77 5.0252
104 99 3.4 4.67 5.0607
106 98 3.3 4.44 5.2489
104 100 3 4.21 5.6696
110 108 8.7 9.82 5.8322
105 99 3.6 4.54 5.8296
------------0.000 0.00 0.0000
103 98 3.5 4.52 6.2400
116 107 9.3 10.70 6.4281
103 % 3.6 4.21 6.6291
105 99 3.2 4.03 6.6859
100 97 5.9 8.00 6.9082
107 100 3.5 4.73 7.1481
111 103 6.5 8.25 7.2006
------------6 7.01 7.2281
104 99 3.2 4.19 7.4993
------------5 6.15 7.5244
------------0.000 0.00 0.0000
105 99 3.4 4.16 7.7230
105 98 3.6 4.43 7.8785
105 97 4.3 5.64 7.8889
------ ------5.6 7.18 7.9652
102 98 3.4 4.04 8.1304
105 100 3.1 4.45 8.1037
108 102 3.9 4.96 9.0723
------------4.8 6.46 9.1653
106 100 4.2 5.38 9.3509
103 97 5.5 6.99 9.7316
117 109 0 14.49 9.7831
109 101 4 5.30 9.8235
109 104 7.2 8.06 10.2338
106 98 15.4 18.90 10.2764
108 102 4.2 5.31 10.6250
1 1 1 0 13.7168 ------------4.3 5.48 11.0301
104 98 3.8 4.50 11.1687
112 105 7.1 8.54 11.4708
109 103 4.4 5.62 11.4842
105 99 3.6 4.45 11.7509
106 99 28.5 36.80 11.7912
107 103 4.2 5.08 12.1953
104 99 3.4 3.83 12.2990
107 101 4.6 5.55 12.6665
110 103 5.2 6.28 13.0383
103 96 4.1 4.69 13.3080
105 99 3 3.64 13.7909
105 99 2.7 3.59 13.8650
102 95 3.4 4.07 13.8813
100 94 3.5 4.23 14.0205
102 94 4.1 4.66 14.8428
104 96 3.2 3.78 14.9094
102 96 3.3 3.97 15.5243
1 1 1 0 18.6798
100 102 15.5 20.61 15.5589
110 109 8.2 9.77 15.6338
105 103 4.7 6.36 15.8650 ------ ------4.9 6.06 16.0153
112 109 7.8 9.82 16.1515
102 101 4 5.03 16.2976
106 105 4.3 5.26 16.3835
102 100 4.2 5.49 16.6058
100 103 4 4.84 16.6354
104 94 3.9 5.46 16.7332
104 103 3.9 4.70 17.2872
102 100 3.4 4.41 17.3598
102 98 4.2 5.27 17.6576
101 98 4 5.17 17.8798
103 101 3.7 4.87 18.0280
101 98 3.9 4.70 18.1317
101 98 4 4.92 18.1909
101 95 4.4 5.46 18.4887
104 100 3.1 4.06 18.7243
104 101 12.6 16.02 19.7172
111 105 6.3 7.49 20.8013
109 100 5.1 6.95 20.9673
113 106 7.4 8.50 21.1480
109 104 5.5 6.66 21. 4665
----------------
REPORT ID: 24E186 Page 61 of 217
Compound List Report 01
Method D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
Title METHOD 8260 25mls
Last Update Mon May 13 13:20:11 2024
Response via Initial Calibration
Total Cpnds 96
PK# Compound Name QIon Exp_RT Rel_RT Cal #Qual A/H ID
--------------------------------------------------------------------------
1 I l,4-DIFLUOROBENZENE 114 8.54 1.000 A 1 A B
2 T Chlorotrifluoroethylene 116 2.08 0.243 A 2 A B
3 T Dichlorodifluoromethane 85 2.17 0.253 A 1 A B
4 T 2-Chloro-1,1, 1-trifluoroethane 118 2.53 0.296 A 2 A B
5 T Chloromethane 50 2.46 0.288 A 1 A B
6 T Vinyl chloride 62 2.61 0.305 A 1 A B
7 T Bromomethane 94 3.14 0.367 LV' 1 A B
8 T Chloroethane 64 3.18 0.373 A 1 A B
9 T Dichlorofluoromethane 67 3.27 0.383 A 1 A B
10 T Trichlorofluoromethane 101 3.55 0.416 A 1 A B
11 T Acrolein 56 3.98 0.466 A 1 A B
12 T 1, l,2-Trichloro-1,2,2-trifluor 151 4.06 0.475 A 1 A B
13 T Acetone 43 4.06 0.475 A 1 A B
14 T l,l-Dichloroethene 61 4.22 0.494 A 2 A B
15 T tert-Butyl alcohol 59 '4.34 0.508 A 1 A B
16 T Iodomethane 142 4.64 0.543 A 1 A B
17 T Methyl acetate 43 4.65 0.544 A 1 A B
18 T Methylene chloride 49 4.86 0.569 A 2 A B
19 T Carbon disulfide 76 4.87 0.570 A 1 A B
20 T Acrylonitrile 53 5.02 0.588 A 2 A B
21 T tert-Butyl methyl ether (MTBE) 73 5.07 0.593 A 1 A B
22 T trans-1,2-Dichloroethene 61 5.24 0.614 A 2 A B
23 T Isopropyl ether (DIPE) 45 5.67 0.664 A 1 A B
24 T Vinyl acetate 43 5.82 0.681 A 1 A B
25 T l,l-Dichloroethane 63 ,5.82 0.681 A 2 A B
26 T 2-Butanol 45 6.16 0.721 A 1 A B
27 T tert-Butyl ethyl ether (ETBE) 59 6.24 0.730 A 1 A B
28 T 2-Butanone 43 6.41 0.751 A 1 A B
29 T 2,2-Dichloropropane 77 6.62 0.775 A 2 A B
30 T cis-1,2-Dichloroethene 96 6.68 0.782 A 2 A B
31 T Chloroform 83 6.90 0.808 A ·2 A B
32 T Bromochloromethane 49 7.14 0.836 A 2 A B
33 T Tetrahydrofuran 42 7.20 0.842 A 2 A B
34 S Dibromofluoromethane 111 7.23 0.846 A 2 A B
35 T l,l,l-Trichloroethane 97 7.49 0.877 A 2 A B
36 T Cyclohexane 84 7.52 0.881 A 1 A B
37 T 2,2,4-Trimethylpentane 57 7.52 0.881 A 1 A B
38 T l,l-Dichloropropene 110 7.72 0.903 A 1 A B
39 T Carbon tetrachloride 119 7.88 0.922 A 1 A B
40 T tert-Amyl methyl ether (TAME) 73 7.88 0.922 A 1 A B
41 S l,2-Dichloroethane-d4 65 7.97 0.933 A 1 A B ~\ 42 T Benzene 78 I' 8.13 0.952 A 2 A B o \11 43 T l,2-Dichloroethane 62 /8.10 0.948 A 1 A B \0 44 T Trichloroethene 130 9.06 1.061 A 3 A B ~\ 45 T Methylcyclohexane 83 9.1~ 1.073 A 2 A B
46 T l,2-Dichloropropane 63 9.34 1. 094 A 1 A B
47 T Bromodichloromethane 83 9.73 1.139 A 1 A B
48 T l,4-Dioxane 88 9.7-9 1.146 A 1 A B
49 T Dibromomethane 93 9.82 1.149 A 2 A B
50 T 2-Chloroethyl vinyl ether 63 .10.23 1.198 A 2 A B
51 T 4-Methyl-2-pentanone 43 10.26 1. 201 LiI" 3 A B
52 T cis-1,3-Dichloropropene 75 10.62 1. 243 A 1 A B
REPORT ID: 24E186 Page 62 of 217
53 I CHLOROBENZENE-D5 117 13.71 1. 000 A 2 A B
54 S Toluene-d8 98 11.03 0.804 A 1 A B
55 T Toluene 91 11.17 0.814 A 1 A B
56 T Ethyl methacrylate 69 11.46 0.836 A 1 A B
57 T trans-1,3-Dichloropropene 75 11.48 0.837 A 1 A B
58 T l,l,2-Trichloroethane 97 11.74 0.856 A 2 A B
59 T 2-Hexanone 43 11.76 0.857 Lv 1 A B
60 T l,3-Dichloropropane 76 12.19 0.889 A 1 A B
61 T Tetrachloroethene 164 12.29 0.896 A 3 A B
62 T Dibromochloromethane 129 12.66 0.923 A 1 A B
63 T l,2-Dibromoethane 107 13.03 0.950 A 1 A B
64 T 1-Chlorohexane 91 , 13.30 0.970 A 1 A B
65 F,M Chlorobenzene 112 13.79 1.005 A 1 A B
66 T 1, 1, 1, 2-Tetrachloroethane 131 13.86 1.011 A 1 A B
67 T Ethylbenzene 91 ,13.88 1.012 A 1 A B
68 T m-Xylene & p-Xylene 91 ' 14.01 1.022 A 1 A B
69 T o-Xylene 91, 14.84 1.082 A 1 A B
70 T Styrene 104 14.90 1.086 A 2 A B
71 T Isopropylbenzene 105 /15.52 1.132 A 3 A B
72 I l,2-DICHLOROBENZENE-D4 152 18.68 1. 000 A 1 A B
73 T Bromoform 173 15.55 0.833 Lv 1 A B
74 T trans-1,4-Dichloro-2-butene 53 15.63 0.837 A 1 A B
75 T l,l,2,2-Tetrachloroethane 83 15.86 0.849 A 1 A B
76 S 4-Bromofluorobenzene 95 16.01 0.857 A 2 A B
77 T 1, 2, 3-Trichloropropane 110 16.14 0.864 A 1 A B
78 T n-Fropylbenzene 91 16.29 0.872 A 2 A B
79 T Bromobenzene 156 16.38 0.877 A 1 A B
80 T l,3,5-Trimethylbenzene 105 /16.60 0.889 A 2 A B
81 T 2-Chlorotoluene 91 16.63 0.891 A 1 A B
82 T 4-Chlorotoluene 91, 16.72 0.895 A 1 A B
83 T tert-Butylbenzene 134 17.29 0.925 A 1 A B
84 T l,2,4-Trimethylbenzene 105 ,17.36 0.929 A 1 A B
85 T sec-Butylbenzene 105 /17.66 0.945 A 1 A B
86 T p-Isopropyltoluene 119 ,17.88 0.957 A 2 A B
87 T l,3-Dichlorobenzene 146 18.03 0.965 A 2 A B
88 T 1, 2, 3-Trimethylbenzene 105"~ 18.13 0.971 A 2 A B
89 T l,4-Dichlorobenzene 146 , 18.19 0.974 A 2 A B
90 T n-Butylbenzene 91 18.49 0.990 A 2 A B
91 T l,2-Dichlorobenzene 146 ~18.72 1.002 A ~1 A B
92 T l,2-Dibromo-3-chloropropane 157 19.71 1.055 L 1 A B
93 T l,2,4-Trichlorobenzene 180 .~20.80 1.113 A 2 A B
94 T Hexachlorobutadiene 225 20.96 1.122 A 1 A B
95 T Naphthalene 128 21.14 1.132 A 1 A B
96 T l,2,3-Trichlorobenzene 180 / 21.46 1.149 A 2 A B
Cal A = Average L = Linear LO = Linear w/origin Q = Quad QO = Quad w/origin
#Qual = number of qualifiers
A/H = Area or Height
ID R = R.T. B = R.T. & Q Q = Qvalue L = Largest A = All
--------------------------------------------------------------------------
V001E11.M Mon May 13 14:36:08 2024
:7 V--I~ 6\\S
REPORT ID: 24E186 Page 63 of 217
BFB
Data File D:\HPCHEM\1\DATA\24E11\REV195.D
Acq On 11 May 2024 10:20 am
Sample BFB01E11
Misc T/CHK
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
1
LPriet
01
1. 00
Method D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
Title : METHOD 8260 25mls
18000
16000
14000
12000
10000
8000
6000
4000
2000
o~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
ime-->
bundance
18000
16000
14000
12000
10000
8000
6000
4000
Iz-->
174
75
50
AutoFind: Scans 978, 979, 980; Background Corrected with Scan 972
I Target I ReI. to I Lower I Upper I
Mass Mass Limit% Limit%
50 95 15 40
75 95 30 60
95 95 100 100
96 95 5 9
173 174 0.00 2
174 95 50 100
175 174 5 9
176 174 95 101
177 176 5 9
ReI.
Abn%
18.5
42.5
100.0
7.3
0.0
75.4
7.4
95.5
7.1
REV195.D V001E11.M Mon May 13 14:35:03 2024
Raw
Abn
3281
7529
17719
1291
0
13365
989
12770
901
I
Result
Pass/Fail
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
REPORT ID: 24E186 Page 64 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E11\REV196.D
Acq On 11 May 2024 10:58 am
Sample V001E111 0.03/0.15
Misc 0.3ppb 8260/1.5ppb KET-AA/7.5ppb
MS Integration Params: RTE.P
Quant Time: May 13 14:29 2024
TBA
Vial:
Operator:
Inst
Multiplr:
2
LPriet
01
1. 00
Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) 1,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
72) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) 1,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
3) Dichlorodifluoromethane
5) Chloromethane
6) Vinyl chloride
8) Chloroethane
9) Dichlorofluoromethane
10) Trichlorofluoromethane
12) l,l,2-Trichloro-1,2,2-trif
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
18) Methylene chloride
19) Carbon disulfide
20) Acrylonitrile
21) tert-Butyl methyl ether (M
22) trans-1,2-Dichloroethene
23) Isopropyl ether (DIPE)
25) l,l-Dichloroethane
27) tert-Butyl ethyl ether (ET
29) 2,2-Dichloropropane
30) cis-1,2-Dichloroethene
31) Chloroform
32) Bromochloromethane
35) 1,l,l-Trichloroethane
36) Cyclohexane
38) l,l-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
8.55 114
13.72 117
18.68 152
7.23 111
7.95 65
11.03 98
16.03 95
2.16
2.46
2.59
3.18
3.26
3.52
4.06
4.22
4.34
4.62
4.84
4.87
5.02
5.05
5.24
5.66
5.82
6.24
6.62
6.68
6.90
7.14
7.49
7.52
7.72
7.87
7.89
85
50
62
64
67
101
151
61
r 59
142
49
76
53
73
/"61
45
63
59
77
/ 96
83
49
97
84
110
119
73
981871
797187
299571
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
8387 0.28 ug/l 0.00
Recovery = 2.80%
6117 0.30 ug/l -0.01
Recovery = 3.00%
35624 0.30 ug/l 0.00
Recovery = 3.00%
13047 0.32 ug/l 0.02
Recovery = 3.20%
8140
12543
8988
6888
22206
12948
5097
15229
7470
16364
13215
36989
7271
15688
14865
32481
17229
22788
15398
11947
21166
6943
15125
14801
4945
11491
19458
0.31 ug/l
0.34 ug/l
0.29 ug/l
0.31 ug/l
0.35 ug/l
0.31 ug/l
0.25 ug/l
0.29 ug/l
6.83 ug/l
0.29 ug/l
0.31 ug/l
0.33 ug/l
1. 60 ug/l
0.30 ug/l
0.29 ug/l
0.30 ug/l
0.29 ug/l
0.30 ug/l
0.31 ug/l
0.29 ug/l
0.35 ug/l
0.29 ug/l
0.30 ug/l
0.30 ug/l
0.29 ug/l
0.31 ug/l
0.32 ug/l
Qvalue
65
86
89
80
73
100
94
94
79
99
98
99
91
81
99
98
98
100
97
98
98
91
97
88
94
97
91
(#) = qualifier out of range (m) = manual integration
REV196.D V001E11.M Mon May 13 14:29:11 2024 Page 1
REPORT ID: 24E186 Page 65 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E11\REV196.D
Aeq On 11 May 2024 10:58 am
Sample V001E111 0.03/0.15
Mise 0.3ppb 8260/1.5ppb KET-AA/7.5ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
2
LPriet
01
1. 00
Quant Time: May 13 14:29 2024 Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAeq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Cone Unit
.42) Benzene
43) l,2-Diehloroethane
44) Triehloroethene
45) Methyleyelohexane
46) l,2-Diehloropropane
47) Bromodiehloromethane
49) Dibromomethane
52) eis-1,3-Diehloropropene
55) Toluene
57) trans-1,3-Diehloropropene
58) l,l,2-Triehloroethane
60) l,3-Diehloropropane
61) Tetraehloroethene
62) Dibromoehloromethane
63) l,2-Dibromoethane
64) 1-Chlorohexane
65) Chlorobenzene
66) l,l,l,2-Tetraehloroethane
67) Ethylbenzene
68) m-Xylene & p-Xylene
69) o-Xylene
70) Styrene
71) Isopropylbenzene
75) l,l,2,2-Tetraehloroethane
78) n-Propylbenzene
79) Bromobenzene
80) l,3,5-Trimethylbenzene
81) 2-Chlorotoluene
82) 4-Chlorotoluene
83) tert-Butylbenzene
84) l,2,4-Trimethylbenzene
85) see-Butylbenzene
86) p-Isopropyltoluene
87) l,3-Diehlorobenzene
88) l,2,3-Trimethylbenzene
89) l,4-Diehlorobenzene
90) n-Butylbenzene
91) l,2-Diehlorobenzene
93) l,2,4-Triehlorobenzene
94) Hexaehlorobutadiene
95) Naphthalene
8.1278
8.10 / 62
9.08 130
9.17 83
9.36 63
9.73 83
9.82 93
10.63 ,75
11.17 91
11.49 (75
11. 76 97
12.21 76
12.29 164
12.68 129
13.05 107
13.32 91
13.79 112
13.86 131
13.89 91
14.03 91
14.84 91
14.93 104
15.52 105
15.86 83
16.31 91
16.38 156
16.61 ,105
16.63 91
16.74' 91
17.29 134
17.36 < 105
17.66 105
17.88 119
18.03 146
18.13 105
18.19 146
18.50 91
18.72 146
20.81 180
20.96 .' 225
21.15 128
40894
7854
9853
16634
9009
13928
3964
13583
43467
9569
5879
9101
8630
7252
5114
18908
25024
7766
49666
73348
39020
29115
48372
6639
60366
8946
39112
36258
31256
8128
37452
53765
40416
17654
35674
18537
43628
14596
9721
5978
11441
0.31 ug/l
0.30 ug/l
0.29 ug/l
0.31 ug/l
0.31 ug/l
0.34 ug/l
0.29 ug/l
0.30 ug/l
0.31 ug/l
0.29 ug/l
0.32 ug/l
0.29 ug/l
0.29 ug/l
0.32 ug/l
0.28 ug/l
0.31 ug/l
0.30 ug/l
0.30 ug/l
0.31 ug/l
0.62 ug/l
0.32 ug/l
0.31 ug/l
0.30 ug/l
0.33 ug/l
0.31 ug/l
0.29 ug/l
0.31 ug/l
0.31 ug/l
0.30 ug/l
0.31 ug/l
0.31 ug/l
0.31 ug/l
0.31 ug/l
0.30 ug/l
0.31 ug/l
0.32 ug/l
0.32 ug/l
0.30 ug/l
0.28 ug/l
0.29 ug/l
0.28 ug/l
Qvalue
98
93
97
98
91
78
85
94
97
95
95
94
98
99
93
95
99
97
99
99
95
95
99
100
99
100
100
99
99
96
99
98
94
99
97
97
95
96
99
94
94
(#) = qualifier out of range (m) = manual integration 0 L/'-~
REV196.D V001E11.M Mon May 13 14:29:12 2024 --~\\S})) Page 2
REPORT ID: 24E186 Page 66 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E11\REV196.D
Aeq On 11 May 2024 10:58 am
Sample V001E111 0.03/0.15
Mise 0.3ppb 8260/1.5ppb KET-AA/7.5ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
2
LPriet
01
1. 00
Quant Time: May 13 14:29 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
Compound
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
R.T. Qlon Response Cone Unit
96) l,2,3-Triehlorobenzene 21. 46 180 7501 0.28 ug/l
Qvalue
96
~ {/-./\ \.S J'2---L-\ _______________________________________________________ 2_~ _____________ _
(#) = qualifier out of range (m) = manual integration
REV196.D V001E11.M Mon May 13 14:29:12 2024 Page 3
REPORT ID: 24E186 Page 67 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E11\REV196.D
Acq On 11 May 2024 10:58 am
Sample V001E111 0.03/0.15
Mise 0.3ppb 8260/1.5ppb KET-AA/7.5ppb TBA
Vial:
Operator:
Inst
Multiplr:
2
LPriet
01
1. 00
MS Integration Params: RTE.P
Quant Time: May 13 14:29 2024 Quant Results File: V001E11.RES
Method
Title
Last Update
Response via
bundance
750000
700000
650000
600000
550000
500000
450000
400000
350000
300000
250000
200000
150000
100000
50000
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
9. 0 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.0020.00 21.00
REV196.D V001E11.M Mon May 13 14:29:14 2024 Page 4
REPORT ID: 24E186 Page 68 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E11\REV197.D
Acq On 11 May 2024 11:27 am
Sample V001El12 0.05/0.25
Misc 0.5ppb 8260/2.5ppb KET-AA/12.5ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
3
LPriet
01
1. 00
Quant Time: May 13 14:30 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 8.54 114 958207 10.00 ug/l 0.00
53) CHLOROBENZENE-D5 13.71 117 782724 10.00 ug/l 0.00
72) l,2-DICHLOROBENZENE-D4 18.68 152 292911 10.00 ug/l 0.00
System Monitoring Compounds
34) Dibromofluoromethane 7.23 111 15713 0.53 ug/l 0.00
Spiked Amount 10.000 Recovery = 5.30%
41) l,2-Dichloroethane-d4 7.97 65 10333 0.51 ug/l 0.00
Spiked Amount 10.000 Recovery = 5.10%
54) Toluene-d8 11.03 98 59771 0.51 ug/l 0.00
Spiked Amount 10.000 Recovery = 5.10%
76) 4-Bromofluorobenzene 16.01 95 21050 0.53 ug/l 0.00
Spiked Amount 10.000 Recovery = 5.30%
Target Compounds Qvalue
3) Dichlorodifluoromethane 2.17 85 13823 0.54 ug/l 95
5) Chloromethane 2.47 50 19466 0.54 ug/l 94
6) Vinyl chloride 2.60 62 15272 0.51 ug/l 97
7) Bromomethane 3.14 94 27166 0.57 ug/l 73
8) Chloroethane 3.18 64 10907 0.50 ug/l 88
9) Dichlorofluoromethane 3.27 67 33964 0.55 ug/l 88
10) Trichlorofluoromethane 3.55 101 22334 0.55 ug/l 96
12) l,l,2-Trichloro-1,2,2-trif 4.06 151 10414 0.52 ug/l 99
14) l,l-Dichloroethene 4.22 r61 26419 0.52 ug/l 97
15) tert-Butyl alcohol 4.35 59 11518 10.80 ug/l 75
16) Iodomethane 4.64 142 27278 0.50 ug/l 99
18) Methylene chloride 4.86 49 21078 0.51 ug/l 99
19) Carbon disulfide 4.87 76 52077 0.48 ug/l 98
20 ) Acrylonitrile 5.04 53 11053 2.49 ug/l 93
21) tert-Butyl methyl ether (M 5.05 73 26332 0.52 ug/l 92
22) trans-1,2-Dichloroethene 5.24 61 24833 0.50 ug/l 98
23) Isopropyl ether (DIPE) 5.67 ,/ 45 53730 0.51 ug/l 97
24) Vinyl acetate 5.85 43 16307 0.45 ug/l 86
25) l,l-Dichloroethane 5.82 »3 29442 0.51 ug/l 97
27) tert-Butyl ethyl ether (ET 6.24 59 37115 0.49 ug/l 96
28 ) 2-Butanone 6.46 43 11997 2.24 ug/l 72
29) 2,2-Dichloropropane 6.62 77 25455 0.53 ug/l 98
30 ) cis-1,2-Dichloroethene 6.68 / 96 20337 0.51 ug/l 99
31) Chloroform 6.90 83 32100 0.55 ug/l 99
32 ) Bromochloromethane 7.14 49 11696 0.51 ug/l 95
35) l,l,l-Trichloroethane 7.50 97 25812 0.53 ug/l 98
36) Cyclohexane 7.52 84 26045 0.54 ug/l 94
-------------------------------------------------------------------------
(# ) = qualifier out of range (m) = manual integration ~\\5 lJ-tlr Page 1 REV197.D V001E11.M Mon May 13 14:30:15 2024
REPORT ID: 24E186 Page 69 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E11\REV197.D
Acq On 11 May 2024 11:27 am
Sample V001El12 0.05/0.25
Misc 0.5ppb 8260/2.5ppb KET-AA/12.5ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
3
LPriet
01
1. 00
Quant Time: May 13 14:30 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Conc Unit
38) 1,1-Dichloropropene 7.72 110 8678 0.52 ug/l
39) Carbon tetrachloride 7.88 119 18823 0.51 ug/l
40 ) tert-Amyl methyl ether (TA 7.88 73 30034 0.51 ug/l
42) Benzene 8.13 78 67162 0.52 ug/l
43) 1,2-Dichloroethane 8.10 62 12935 0.50 ug/l
44} Trichloroethene 9.08 130 16301 0.49 ug/l
45} Methylcyclohexane 9.17 83 28860 0.55 ug/l
46 } 1,2-Dichloropropane 9.36 63 15082 0.53 ug/l
47} Bromodichloromethane 9.73 83 21158 0.53 ug/l
49} Dibromomethane 9.83 93 6952 0.51 ug/l
52} cis-1,3-Dichloropropene 10.63 75 21629 0.49 ug/l
55} Toluene 11.17 91 74965 0.54 ug/l
57} trans-1,3-Dichloropropene 11.49 < 75 15855 0.49 ug/l
58} 1,1,2-Trichloroethane 11.76 97 8909 0.49 ug/l
60} 1,3-Dichloropropane 12.20 76 15204 0.49 ug/l
61} Tetrachloroethene 12.31 164 15270 0.53 ug/l
62} Dibromochloromethane 12.66 129 11514 0.52 ug/l
63} 1,2-Dibromoethane 13.05 107 8602 0.48 ug/l
64} 1-Chlorohexane 13.31 91 32200 0.54 ug/l
65} Chlorobenzene 13.79 112 42586 0.51 ug/l
66} 1, 1, 1,2-Tetrachloroethane 13.86 131 12904 0.51 ug/l
67} Ethylbenzene 13.88
~
91 84216 0.53 ug/l
68} m-Xylene & p-Xylene 14.03 , 91 123954 1. 07 ug/l
69} o-Xylene 14.84 .-91 63511 0.53 ug/l
70 } Styrene 14.91 104 47295 0.51 ug/l
71} Isopropylbenzene 15.52 105 83169 0.53 ug/l
73} Bromoform 15.57 173 2997 0.58 ug/l
75} 1,1,2,2-Tetrachloroethane 15.86 83 9761 0.50 ug/l
77} 1,2,3-Trichloropropane 16.17 110 2065 0.41 ug/l
78} n-Propylbenzene 16.31 91 102429 0.54 ug/l
79} Bromobenzene 16.38 156 15359 0.51 ug/l
80 } 1, 3, 5-Trimethylbenzene 16.60 105 65890 0.54 ug/l
81} 2-Chlorotoluene 16.63 91 62476 0.54 ug/l
82} 4-Chlorotoluene 16.74-: 91 53625 0.53 ug/l
83} tert-Butylbenzene 17.29 134 13038 0.51 ug/l
84} 1,2,4-Trimethylbenzene 17.36 /105 62834 0.53 ug/l
85} sec-Butylbenzene 17.66 / 105 90100 0.54 ug/l
86} p-Isopropyltoluene 17.88 119 70430 0.55 ug/l
87} 1,3-Dichlorobenzene 18.03 146 30579 0.53 ug/l
88} 1, 2, 3-Trimethylbenzene 18.13 105 60108 0.54 ug/l
89} 1,4-Dichlorobenzene 18.19 146 30059 0.54 ug/l
Qvalue
98
98
99
99
96
93
98
92
92
88
99
95
96
95
97
99
99
99
99
99
99
99
99
99
98
98
70
94
98
99
98
99
99
100
98
94
99
95
97
97
97
-------------------------------------------------------------------------
(# ) = qualifier out of range (m) = manual integration 0~\\S(z){ REV197.D V001E11.M Mon May 13 14:30:16 2024 Page 2
REPORT ID: 24E186 Page 70 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E11\REV197.D
Aeq On 11 May 2024 11:27 am
Sample V001El12 0.05/0.25
Mise 0.5ppb 8260/2.5ppb KET-AA/12.5ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
3
LPriet
01
1. 00
Quant Time: May 13 14:30 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. Qlon Response Cone Unit
90) n-Butylbenzene 18.49 /91 72685 0.54 ug/l
91) l,2-Diehlorobenzene 18.72 146 24372 0.52 ug/l
93) l,2,4-Triehlorobenzene 20.81 '180 16768 0.49 ug/l
94) Hexaehlorobutadiene 20.96 225 10138 0.50 ug/l
95) Naphthalene 21.15 128 19046 0.48 ug/l
96) 1, 2, 3-Triehlorobenzene 21.48 (180 12506 0.48 ug/l
Qvalue
98
97
98
96
100
96
~ l/'---./ I \ 5J; L1; -----------------------------------------------------~----11~---------
(#) = qualifier out of range (m) = manual integration
REV197.D V001E11.M Mon May 13 14:30:16 2024 Page 3
REPORT ID: 24E186 Page 71 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E11\REV197.D
Aeq On 11 May 2024 11:27 am
Sample V001El12 0.05/0.25
Mise 0.5ppb 8260/2.5ppb KET-AA/12.5ppb TBA
Vial:
Operator:
Inst
Multiplr:
3
LPriet
01
1. 00
MS Integration Params: RTE.P
Quant Time: May 13 14:30 2024 Quant Results File: V001E11.RES
Method
Title
Last Update
Response via
bundance
50000
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
ui z
~ m
~ o
:3 u..
~
REV197.D V001E11.M Mon May 13 14:30:18 2024 Page 4
REPORT ID: 24E186 Page 72 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E11\REV198.D
Acq On 11 May 2024 11:56 am
Sample V001El13 0.1/0.5
Misc : 1ppb 8260/5ppb KET-AA/25ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
4
LPriet
01
1.00
Quant Time: May 13 14:30 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 8.54 114 938282 10.00 ug/l 0.00
53) CHLOROBENZENE-D5 13.71 117 769560 10.00 ug/l 0.00
72) l,2-DICHLOROBENZENE-D4 18.68 152 301168 10.00 ug/l 0.00
System Monitoring Compounds
34) Dibromofluoromethane 7.::n 111 27033 0.93 uq/l 0.00
Spiked Amount 10.000 Recovery = 9.30%
41) l,2-Dichloroethane-d4 7.97 65 18064 0.91 ug/l 0.00
Spiked Amount 10.000 Recovery = 9.10%
54) Toluene-d8 11. 03 98 106585 0.92 ug/l 0.00
Spiked Amount 10.000 Recovery = 9.20%
76) 4-Bromofluorobenzene 16.01 95 38225 0.93 ug/l 0.00
Spiked Amount 10.000 Recovery = 9.30%
Target Compounds Qvalue
3) Dichlorodifluoromethane 2.16 85 23088 0.92 ug/l 94
5) Chloromethane 2.46 50 33932 0.97 ug/l 95
6) Vinyl chloride 2.60 62 26741 0.91 ug/l 96
7) Bromomethane 3.14 94 40909 0.99 ug/l 78
8) Chloroethane 3.18 64 20092 0.95 ug/l 95
9) Dichlorofluoromethane 3.27 67 59133 0.98 ug/l 89
10) Trichlorofluoromethane 3.54 101 38039 0.96 ug/l 99
12) l,l,2-Trichloro-1,2,2-trif 4.07 151 18470 0.93 ug/l 97
13) Acetone 4.06 43 22798 6.66 ug/l 97
14) l,l-Dichloroethene 4.24 (' 61 45534 0.91 ug/l 98
15) tert-Butyl alcohol 4.35 59 24124 23.10 ug/l 96
16) Iodomethane 4.64 142 49230 0.92 ug/l 99
18) Methylene chloride 4.86 49 39235 0.98 ug/l 97
19) Carbon disulfide 4.89 76 100956 0.94 ug/l 98
20 ) Acrylonitrile 5.04 53 20752 4.78 ug/l 96
21) tert-Butyl methyl ether (M 5.07 73 46754 0.95 ug/l 93
22) trans-1,2-Dichloroethene 5.24 .(' 61 46060 0.96 ug/l 98
23) Isopropyl ether (DIPE) 5.67 45 97086 0.94 ug/l 99
24) Vinyl acetate 5.85 43 29673 0.84 ug/l 95
25) l,l-Dichloroethane 5.84 / 63 53046 0.94 ug/l 99
27) tert-Butyl ethyl ether (ET 6.24 59 70971 0.96 ug/l 99
28 ) 2-Butanone 6.46 43 22810 4.34 ug/l 98
29) 2,2-Dichloropropane 6.64 77 44935 0.95 ug/l 99
30 ) cis-1,2-Dichloroethene 6.70 / 96 36770 0.95 ug/l 100
31) Chloroform 6.90 83 55743 0.97 ug/l 99
32) Bromochloromethane 7.15 49 20957 0.93 ug/l 97
35) l,l,l-Trichloroethane 7.50 97 45525 0.95 ug/l 98
(#) = qualifier out of range (m)
REV198.D V001E11.M Mon May
= manual integration
13 14:30:41 2024 ?7 LA-
--~S \ \6/;J-Lt
Page 1
REPORT ID: 24E186 Page 73 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E11\REV198.D
Acq On 11 May 2024 11:56 am
Sample V001El13 0.1/0.5
Misc 1ppb 8260/5ppb KET-AA/25ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
4
LPriet
01
1. 00
Quant Time: May 13 14:30 2024 Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Conc Unit
36)
38)
39)
40)
42)
43)
44)
45)
46)
47)
49)
50)
51)
52)
55)
56)
57)
58)
59)
60 )
61)
62)
63)
64)
65)
66)
67)
68)
69 )
70 )
71)
73)
74)
75)
77)
78)
79)
80 )
81)
82)
83)
Cyclohexane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
l,2-Dichloroethane
Trichloroethene
Methylcyclohexane
l,2-Dichloropropane
Bromodichloromethane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
Ethyl methacrylate
trans-1,3-Dichloropropene
1, 1, 2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, l,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
trans-1,4-Dichloro-2-buten
l,l,2,2-Tetrachloroethane
l,2,3-Trichloropropane
n-Propylbenzene
Bromobenzene
1, 3, 5-Trimethylbenzene
2-Chlorotoluene
4-Chlorotoluene
tert-Butylbenzene
7.52
7.72
7.88
7.90
8.13
8.10
9.08
9.17
9.36
9.73
9.83
10.26
10.31
10.63
11.17
11.54
11.49
11.76
11.92
12.20
12.31
12.66
13.03
13.31
13.79
13.86
13.88
14.03
14.84
14.91
15.52
15.57
15.66
15.86
16.14
16.29
16.38
16.60
16.63
16.74
17.29
84
110
119
73
/ 78
/ 62
130
83
63
83
93
63
43
".75
91
69
; 75
97
43
76
164
129
107
91
/.'112
131
/ 91
/ 91
/ 91
104
105
173
53
83
110
91
/156
105
/ 91
91
134
44404
15802
33069
55848
118978
23808
29954
50363
25645
36838
12791
6310
44214
40679
127757
17884
28905
16916
11666
28770
26996
20338
16471
54872
·77497
24060
146785
218771
113075
87190
145909
7931
4400
18640
4598
177771
28202
112460
111646
93055
23977
0.95 ug/l
0.97 ug/l
0.92 ug/l
0.97 ug/l
0.95 ug/l
0.94 ug/l
0.92 ug/l
0.98 ug/l
0.91 ug/l
0.95 ug/l
0.97 ug/l
0.89 ug/l
5.73 ug/l
0.93 ug/l
0.93 ug/l
0.87 ug/l
0.91 ug/l
0.95 ug/l
6.13 ug/l
0.95 ug/l
0.95 ug/l
0.93 ug/l
0.93 ug/l
0.93 ug/l
0.95 ug/l
0.96 ug/l
0.94 ug/l
1.92 ug/l
0.96 ug/l
0.96 ug/l
0.94 ug/l
0.98 ug/l
0.85 ug/l
0.93 ug/l
0.90 ug/l
0.91 ug/l
0.91 ug/l
0.90 ug/l
0.95 ug/l
0.89 ug/l
0.91 ug/l
(#) = qualifier out of range (m) = manual integration c:::, l/'--'
REV198.D V001E11.M Mon May 13 14:30:42 2024 ---3\\~ /J-..Lt
Qvalue
94
96
99
96
100
98
98
98
99
93
94
89
98
98
99
84
100
99
79
100
97
98
99
99
98
96
99
98
98
100
100
88
88
99
94
99
99
97
100
99
99
Page 2
REPORT ID: 24E186 Page 74 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E11\REV198.D
Aeq On 11 May 2024 11:56 am
Sample V001El13 0.1/0.5
Mise 1ppb 8260/5ppb KET-AA/25ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
4
LPriet
01
1.00
Quant Time: May 13 14:30 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last update
Response via
DataAeq Meth
Compound
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
R.T. Qlon Response Cone Unit Qvalue
-------------------------------------------------------------------------
84) 1,2,4-Trimethylbenzene 17.36 ' 105 112239 0.92 ug/l 98
85) see-Butylbenzene 17.66 105 155515 0.90 ug/l 100
86) p-Isopropyltoluene 17.88
,
119 121109 0.91 ug/l 97
87) 1,3-Diehlorobenzene 18.03 / 146 54062 0.92 ug/l 100
88) 1,2,3-Trimethylbenzene 18.13 105 107510 0.94 ug/l 99
89) 1,4-Diehlorobenzene 18.19 146 54049 0.94 ug/l 99
90) n-Butylbenzene 18.49·r 91 126285 0.92 ug/l 99
91) 1,2-Diehlorobenzene 18.72 / 146 45597 0.95 ug/l 100
92) 1,2-Dibromo-3-ehloropropan 19.71 157 2008 1.14 ug/l 82
93) 1,2,4-Triehlorobenzene 20.80',180 31265 0.89 ug/l 96
94) Hexaehlorobutadiene 20.97 225 18414 0.88 ug/l 96
95) Naphthalene 21.15 128 36313 0.88 ug/l 99
96) 1,2,3-Triehlorobenzene 21. 46 ! 180 23830 0.90 ug/l 98
__________________________________________ -_ -__ -_ -__ -_ -_,?:-_ il~sl ~~----
(#) = qualifier out of range (m) = manual integration
REV198.D V001E11.M Mon May 13 14:30:42 2024 Page 3
REPORT ID: 24E186 Page 75 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E11\REV198.D
Aeq On 11 May 2024 11:56 am
Sample V001El13 0.1/0.5
Mise 1ppb 8260/5ppb KET-AA/25ppb TBA
Vial:
Operator:
Inst
Multiplr:
4
LPriet
01
1. 00
MS Integration Params: RTE.P
Quant Time: May 13 14:30 2024 Quant Results File: V001E11.RES
Method
Title
Last Update
Re se via
500000
450000
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
ui z
~ w m
~ o
=!
LL
~ -
REV198.D V001E11.M Mon May 13 14:30:44 2024 Page 4
REPORT ID: 24E186 Page 76 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E11\REV199.D
Acq On 11 May 2024 12:30 pm
Sample V001El14 0.2/1.0
Misc 2ppb 8260/10ppb KET-AA/50ppb TBA
MS Integration Params: RTE.P
Quant Time: May 13 13:54 2024
Vial:
Operator:
Inst
Multiplr:
5
LPriet
01
1. 00
Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
72) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
3) Dichlorodifluoromethane
5) Chloromethane
6) Vinyl chloride
7) Bromomethane
8) Chloroethane
9) Dichlorofluoromethane
10) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
18) Methylene chloride
19) Carbon disulfide
20) Acrylonitrile
21) tert-Butyl methyl ether (M
22) trans-1,2-Dichloroethene
23) Isopropyl ether (DIPE)
24) Vinyl acetate
25) l,l-Dichloroethane
27) tert-Butyl ethyl ether (ET
28) 2-Butanone
29) 2,2-Dichloropropane
30) cis-1,2-Dichloroethene
31) Chloroform
8.55 114
13.72 117
18.68 152
7.21 111
7.95 65
11. 02 98
16.01 95
2.15
2.47
2.60
3.14
3.18.
3.27
3.54
3.98
4.07
4.04
4.22
4.34
4.64
4.65
4.84
4.87
5.02
5.05
5.24
5.66
5.84
5.82
6.24
6.43
6.62
6.68
6.90
85
50
62
94
64
67
101
56
151
43
/ 61
59
142
43
49
76
53
73
/61
45
43
/ 63
59
43
77
I 96
83
923954
742613
293562
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.00
0.00
0.00
60611 2.12 ug/l -0.02
Recovery = 21.20%
42296 2.17 ug/l -0.01
Recovery = 21.70%
240432 2.16 ug/l -0.01
Recovery = 21.60%
81025 2.03 ug/l 0.00
Recovery = 20.30%
50374
72647
62031
74605
40122
119218
81560
20592
42426
34198
101014
52952
105323
21059
80640
207998
40810
98170
96611
200708
66565
112928
152096
46317
94455
75331
109165
2.04
2.10
2.15
2.01
1. 92
2.01
2.09
9.92
2.18
10.14
2.05
51.48
1. 99
2.29
2.04
1. 97
9.54
2.03
2.03
1. 98
1. 91
2.03
2.09
8.95
2.02
1. 97
1. 93
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
98
93
97
87
98
96
99
89
100
99
98
92
100
89
98
99
94
99
99
100
97
99
99
99
99
99
99
(#) = qualifier out of range (m) = manual integration
REV199.D V001E11.M Mon May 13 14:31:07 2024
REPORT ID: 24E186 Page 77 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E11\REV199.D
Acq On 11 May 2024 12:30 pm
Sample V001El14 0.2/1.0
Misc 2ppb 8260/10ppb KET-AA/50ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
5
LPriet
01
1. 00
Quant Time: May 13 13:54 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. Qlon Response Conc Unit
32)
33)
35)
36)
38 )
39)
40 )
42)
43)
44)
45)
46)
47)
48 )
49)
50)
51)
52)
55)
56)
57)
58)
59)
60)
61)
62)
63)
64)
65)
66)
67)
68)
69)
70)
71)
73)
74)
75 )
77)
78)
79)
Bromochloromethane
Tetrahydrofuran
l,l,l-Trichloroethane
Cyclohexane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
l,2-Dichloroethane
Trichloroethene
Methylcyclohexane
l,2-Dichloropropane
Bromodichloromethane
l,4-Dioxane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
Ethyl methacrylate
trans-1,3-Dichloropropene
l,l,2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, 1, 2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
trans-1,4-Dichloro-2-buten
1, 1, 2, 2-Tetrachloroethane
1, 2, 3-Trichloropropane
n-Propylbenzene
Bromobenzene
7.14 49
7.20 42
7.49 97
7.51 84
7.72 110
7.86 119
7.88 73
8.12 /' 78
8.10 / 62
9.06 130
9.15 83
9.35 63
9.73 83
9.82 88
9.82 93
10.25 63
10.29 43
10.62 ~75
11.17 91
11.49 69
11.48 / 75
11. 75 97
11. 83 43
12.19 76
12.29 164
12.66 129
13.03 107
13.32 I' 91
13.79 112
13.86 131
13.88 r 91
14.01 / 91
14.84 / 91
14.92 104
15.52 105
15.57 173
15.64 53
15.86 83
16.16 110
16.29 91
16.38 156
I
44566
6950
94535
97188
32679
71508
115389
248582
50716
63296
107421
54414
75727
3445
26199
13477
96326
84540
267463
38804
61587
35305
38468
60220
56394
41132
34770
117841
158702
48976
304664
450609
231237
177724
305906
21027
9849
38426
10163
370739
58783
2.01
2.12
2.00
2.11
2.03
2.03
2.04
2.01
2.04
1. 98
2.12
1. 97
1. 98
30.47
2.01
1. 92
9.38
1. 97
2.03
1. 96
2.01
2.04
9.25
2.05
2.06
1. 95
2.04
2.07
2.02
2.02
2.02
4.09
2.04
2.02
2.05
2.08
1. 94
1. 97
2.03
1. 94
1. 95
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
100
84
99
97
100
98
97
100
99
98
99
98
99
71
97
95
98
99
100
97
97
99
97
100
100
98
98
99
99
99
99
99
99
99
99
97
85
99
95
100
100
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration
REV199.D V001E11.M Mon May 13 14:31:08 2024 Page 2
REPORT ID: 24E186 Page 78 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E11\REV199.D
Aeq On 11 May 2024 12:30 pm
Sample V001El14 0.2/1.0
Mise 2ppb 8260/10ppb KET-AA/50ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
5
LPriet
01
1. 00
Quant Time: May 13 13:54 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. Qlon Response Cone Unit
80 ) 1, 3, 5-Trimethylbenzene 16.60 /105 237589 1. 95 ug/l
81) 2-Chlorotoluene 16.63 / 91 219062 1.91 ug/l
82) 4-Chlorotoluene 16.74 / 91 206396 2.03 ug/l
83) tert-Butylbenzene 17.29 134 49658 1. 94 ug/l
84) l,2,4-Trimethylbenzene 17.36 1105 233094 1. 95 ug/l
85) see-Butylbenzene 17.66 / 105 332693 1. 98 ug/l
86) p-Isopropyltoluene 17.88 119 260761 2.02 ug/l
87) l,3-Diehlorobenzene 18.03 146 112316 1. 96 ug/l
88) 1, 2, 3-Trimethylbenzene 18.13 105 219653 1. 97 ug/l
89) l,4-Diehlorobenzene 18.19 <146 110373 1. 96 ug/l
90) n-Butylbenzene 18.49 91 265074 1. 98 ug/l
91) l,2-Diehlorobenzene 18.72 /146 94251 2.00 ug/l
92) l,2-Dibromo-3-ehloropropan 19.72 157 5091 2.12 ug/l
93) 1, 2, 4-Triehlorobenzene 20.80/180 67009 1. 95 ug/l
94) Hexaehlorobutadiene 20.96 225 39320 1. 92 ug/l
95) Naphthalene 21.15 128 77920 1. 94 ug/l
96) 1, 2, 3-Triehlorobenzene 21. 46 cI 180 51155 1. 98 ug/l
Qvalue
98
95
97
98
98
99
99
99
99
100
99
99
97
98
97
99
100
------------------- - -------- ----- ----- - - -------- - ----~~~ -~\ ~ ~ ~ ----
(#) = qualifier out of range (m) = manual integration
REV199.D V001E11.M Mon May 13 14:31:08 2024 Page 3
REPORT ID: 24E186 Page 79 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24Ell\REV199.D
Aeq On 11 May 2024 12:30 pm
Sample VOOIEl14 0.2/1.0
Mise 2ppb 8260/10ppb KET-AA/50ppb TBA
Vial:
Operator:
Inst
Multiplr:
5
LPriet
01
1. 00
MS Integration Params: RTE.P
Quant Time: May 13 13:54 2024 Quant Results File: VOOIEll.RES
Method
Title
Last Update
Response via
bundance
600000
450000
400000
350000
300000
200000
150000
100000
D:\HPCHEM\l\METHODS\VOOIEll.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
ui z
~ w m o
0:: o
:3 u.
~.
REV199.D VOOIEll.M Mon May 13 14:31:11 2024 Page 4
REPORT ID: 24E186 Page 80 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E11\REV200.D
Acq On 11 May 2024 12:59 pm
Sample V001El15 0.5/2.5
Misc : 5ppb 8260/25ppb KET-AA/125ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
6
LPriet
01
1. 00
Quant Time: May 13 13:56 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) 1,4-DIFLUOROBENZENE 8.54 114 900656 10.00 ug/l 0.00
53) CHLOROBENZENE-D5 13.71 117 744900 10.00 ug/l 0.00
72) 1,2-DICHLOROBENZENE-D4 18.68 152 284539 10.00 ug/l 0.00
System Monitoring Compounds
34) Dibromofluoromethane 7.23 111 143298 5.14 ug/l 0.00
Spiked Amount 10.000 Recovery = 51. 40%'
41) 1,2-Dichloroethane-d4 7.97 65 97715 5.14 ug/l 0.00
Spiked Amount 10.000 Recovery = 51.40%'
54) Toluene-d8 11.03 98 569302 5.10 ug/l 0.00
Spiked Amount 10.000 Recovery = 51.00%'
76) 4-Bromofluorobenzene 16.01 95 190707 4.92 ug/l 0.00
Spiked Amount 10.000 Recovery = 49.20%'
Target Compounds Qvalue
3) Dichlorodifluoromethane 2.18 85 119456 4.96 ug/l 98
5) Chloromethane 2.48 50 170900 5.06 ug/l 99
6) Vinyl chloride 2.60 62 151684 5.40 ug/l 98
7) Bromomethane 3.14 94 161543 4.74 ug/l 99
8) Chloroethane 3.18 64 101909 5.00 ug/l 100
9) Dichlorofluoromethane 3.27 67 272435 4.71 ug/l 98
10 ) Trichlorofluoromethane 3.55 101 192432 5.06 ug/l 98
11) Acrolein 3.98 56 50318 24.87 ug/l 98
12) 1,1,2-Trichloro-1,2,2-trif 4.07 151 95572 5.03 ug/l 99
13) Acetone 4.06 43 80312 24.43 ug/l 100
14) 1,1-Dichloroethene 4.24 I 61 236110 4.92 ug/l 100
15) tert-Butyl alcohol 4.34 59 126289 125.96 ug/l 98
16) Iodomethane 4.64 142 253734 4.93 ug/l 100
17) Methyl acetate 4.65 43 45270 5.05 ug/l 100
18) Methylene chloride 4.86 49 189706 4.92 ug/l 98
19) Carbon disulfide 4.89 76 519242 5.06 ug/l 99
20) Acrylonitrile 5.02 53 104491 25.05 ug/l 99
21) tert-Butyl methyl ether (M 5.07 73 232923 4.93 ug/l 98
22) trans-1,2-Dichloroethene 5.24 r 61 227623 4.92 ug/l 99
23) Isopropyl ether (DIPE) 5.67 45 486332 4.92 ug/l 99
24) Vinyl acetate 5.84 43 178828 5.27 ug/l 98
25) 1,1-Dichloroethane 5.84 ./ 63 265434 4.90 ug/l 100
27) tert-Butyl ethyl ether (ET 6.24 59 350636 4.95 ug/l 99
28) 2-Butanone 6.43 43 122252 24.23 ug/l 98
29) 2,2-Dichloropropane 6.62 77 221475 4.87 ug/l 100
30 ) cis-1,2-Dichloroethene 6.68 96 182793 4.91 ug/l 99
31) Chloroform 6.90/ 83 263399 4.78 ug/l 100
(#) = qualifier out of range (m) = manual integration
REV200.D V001E11.M Mon May 13 14:31:41 2024
REPORT ID: 24E186 Page 81 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E11\REV200.D
Acq On 11 May 2024 12:59 pm
Sample V001El15 0.5/2.5
Misc 5ppb 8260/25ppb KET-AA/125ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
6
LPriet
01
1. 00
Quant Time: May 13 13:56 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Conc Unit
32)
33)
35)
36)
38 )
39)
40)
42)
43)
44)
45)
46)
47)
48)
49)
50)
51)
52)
55)
56)
57)
58)
59 )
60 )
61)
62)
63)
64)
65)
66)
67)
68)
69)
70 )
71)
73)
74)
75)
77 )
78)
79)
Bromochloromethane
Tetrahydrofuran
l,l,l-Trichloroethane
Cyclohexane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
l,2-Dichloroethane
Trichloroethene
Methylcyclohexane
l,2-Dichloropropane
Bromodichloromethane
l,4-Dioxane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
Ethyl methacrylate
trans-1,3-Dichloropropene
l,l,2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, 1, 2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
trans-1,4-Dichloro-2-buten
1, 1, 2, 2-Tetrachloroethane
1, 2, 3-Trichloropropane
n-Propylbenzene
Bromobenzene
7.15
7.20
7.50
7.53
7.72
7.88
7.88
8.13
8.10
9.08
9.17
9.34
9.73
9.80
9.82
10.23
10.28
10.62
11.17
11.46
11.48
11.74
11.79
12.19
12.29
12.66
13.03
13.30
13.79
13.86
13.88
14.01
14.84
14.90
15.52
15.55
15.63
15.86
16.14
16.29 /
16.38
49
42
97
84
110
119
73
r 78
r 62
130
83
_ 63
83
88
93
( 63
43
~75
91
69
.( 75
97
43
76
164
129
107
r 91
112
131
r 91
/ 91
I 91
104
105
173
53
83
110
91
156
107126
15395
223490
229091
75641
164649
265148
593170
119634
151454
246613
129424
180624
10209
62590
32624
302538
205197
638964
93055
150076
84096
161653
141872
131949
100908
84804
270570
382775
116917
730874
1083475
543905
426095
729567
52073
23167
90996
24020
891243
142872
4.95
4.82
4.84
5.10
4.82
4.79
4.81
4.93
4.93
4.87
4.99
4.81
4.83
92.63
4.93
4.78
24.21
4.90
4.83
4.69
4.88
4.86
23.32
4.83
4.80
4.77
4.95
4.74
4.85
4.81
4.84
9.80
4.78
4.83
4.87
4.81
4.72
4.80
4.96
4.82
4.88
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
(#) = qualifier out of range (m) = manual integration~ ~
REV200.D V001Ell.M Mon May 13 14:31:42 2024 -5t~<JI2J('
Qvalue
100
99
100
100
99
99
100
100
100
99
98
99
99
95
96
99
100
100
99
97
99
100
98
99
99
99
98
100
100
99
100
99
100
99
100
98
99
100
100
100
100
Page 2
REPORT ID: 24E186 Page 82 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E11\REV200.D
Aeq On 11 May 2024 12:59 pm
Sample V001El15 0.5/2.5
Mise 5ppb 8260/25ppb KET-AA/125ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
6
LPriet
01
1.00
Quant Time: May 13 13:56 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Cone Unit
80) l,3,5-Trimethylbenzene 16.60 ,,105 568375 4.81 ug/l
81) 2-Chlorotoluene 16.63 91 534726 4.80 ug/l
82) 4-Chlorotoluene 16.72 91 491373 4.98 ug/l
83) tert-Butylbenzene 17.29 ' 134 119387 4.81 ug/l
84) 1,2,4 -TL'lmethylbenzene 17.36 -105 562027 4.R6 ug/l
85) see-Butylbenzene 17.66 105 782171 4.81 ug/l
86) p-Isopropyltoluene 17.88 J 119 604455 4.83 ug/l
87) l,3-Diehlorobenzene 18.03 146 266427 4.79 ug/l
88) l,2,3-Trimethylbenzene 18.13 I 105 523914 4.85 ug/l
89) l,4-Diehlorobenzene 18.19 146 264166 4.84 ug/l
90) n-Butylbenzene 18.49 91 624902 4.82 ug/l
91) l,2-Diehlorobenzene 18.72 / 146 222834 4.89 ug/l
92) l,2-Dibromo-3-ehloropropan 19.71 157 13172 4.81 ug/l
93) l,2,4-Triehlorobenzene 20.80 ( 180 161262 4.85 ug/l
94) Hexaehlorobutadiene 20.96 225 94994 4.79 ug/l
95) Naphthalene 21.15 / 128 187349 4.82 ug/l
96) 1, 2, 3-Triehlorobenzene 21. 46 180 121965 4.87 ug/l
Qvalue
100
100
99
100
99
99
100
99
99
99
100
99
96
99
99
99
100
-------------------------------------------------;2~-~J~5jJ:!t-------
(#) = qualifier out of range (m) = manual integration
REV200.D V001E11.M Mon May 13 14:31:42 2024 Page 3
REPORT ID: 24E186 Page 83 of 217
QuantitationReport
Data File D:\HPCHEM\1\DATA\24Ell\REV200.D
Aeq On 11 May 2024 12:59 pm
Sample VOOIEl15 0.5/2.5
Mise 5ppb 8260/25ppb KET-AA/125ppb TBA
Vial:
Operator:
Inst
Multiplr:
6
LPriet
01
1. 00
MS Integration Params: RTE.P
Quant Time: May 13 13:56 2024 Quant Results File: VOOIEll.RES
Method
Title
Last Update
Response via
f.bundance
1000000
950000
900000
850000
800000
750000
700000
650000
600000
550000
500000
450000
400000
350000
300000
250000
200000
150000
100000
D:\HPCHEM\l\METHODS\VOOIEll.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
iii z
~
W
ID
~ o
:3 u.
~
TIC: REV200.D
~ime--> 2.bo 3.bo 4.bo 5.bo 6.bo 7.bo 8.bo 9.bo 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.0020.0021.00
REV200.D VOOIEll.M Mon May 13 14:31:45 2024 Page 4
REPORT ID: 24E186 Page 84 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E11\REV201.D
Acq On 11 May 2024 1:28 pm
Sample V001El16 1.0/5.0
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
7
LPriet
01
1. 00
Quant Time: May 13 13:58 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) 1,4-DIFLUOROBENZENE 8.54 114 920983 10.00 ug/l 0.00
53) CHLOROBENZENE-D5 13.71 117 742213 10.00 ug/l 0.00
72) l,2-DICHLOROBENZENE-D4 18.68 152 284055 10.00 ug/l 0.00
System Monitoring Compounds
34) Dibromofluoromethane 7.23 111 258776 9.08 ug/l 0.00
Spiked Amount 10.000 Recovery = 90.80%
41) 1,2-Dichloroethane-d4 7.97 65 170981 8.79 ug/l 0.00
Spiked Amount 10.000 Recovery = 87.90%
54) Toluene-d8 11.03 98 1034495 9.30 ug/l 0.00
Spiked Amount 10.000 Recovery = 93.00%
76) 4-Bromofluorobenzene 16.01 95 349924 9.04 ug/l 0.00
Spiked Amount 10.000 Recovery = 90.40%
Target Compounds Qvalue
3) Dichlorodifluoromethane 2.17 85 233807 9.49 ug/l 100
5) Chloromethane 2.46 50 319578 9.26 ug/l 100
6) Vinyl chloride 2.61 62 285699 9.94 ug/l 100
7) Bromomethane 3.14 94 303178 8.88 ug/l 100
8) Chloroethane 3.18 64 194643 9.34 ug/l 100
9) Dichlorofluoromethane 3.27 67 535368 9.04 ug/l 100
10) Trichlorofluoromethane 3.55 101 365519 9.40 ug/l 100
11) Acrolein 3.98 56 91543 44.25 ug/l 100
12) l,l,2-Trichloro-1,2,2-trif 4.06 151 193689 9.97 ug/l 100
13) Acetone 4.06 43 141862 42.20 ug/l 100
14) 1,1-Dichloroethene 4.22 61 473083 9.63 ug/l 100
15) tert-Butyl alcohol 4.34 ""-59 232900 227.17 ug/l 100
16) Iodomethane 4.64 142 502181 9.54 ug/l 100
17) Methyl acetate 4.65 43 77293 8.43 ug/l 100
18) Methylene chloride 4.86 49 367504 9.33 ug/l 100
19) Carbon disulfide 4.87 76 984042 9.37 ug/l 100
20) Acrylonitrile 5.02 53 196137 45.99 ug/l 100
21) tert-Butyl methyl ether (M 5.07 73 435419 9.01 ug/l 100
22) trans-1,2-Dichloroethene 5.24 <" 61 438850 9.27 ug/l 100
23) Isopropyl ether (DIPE) 5.67 45 945894 9.35 ug/l 100
24) Vinyl acetate 5.82 43 316675 9.12 ug/l 100
25) 1,1-Dichloroethane 5.82 <' 63 520416 9.40 ug/l 100
27) tert-Butyl ethyl ether (ET 6.24 59 667502 9.21 ug/l 100
28 ) 2-Butanone 6.41 43 244678 47.43 ug/l 100
29) 2,2-Dichloropropane 6.62 77 438788 9.43 ug/l 100
30 ) cis-1,2-Dichloroethene 6.68 96 363843 9.55 ug/l 100
31) Chloroform 6.90 / 83 508562 9.02 ug/l 100
-------------------------------------------------------------------------
(#) = qualifier out of range (m) = manual integration ?7~~aJt
REV201. D V001E11. M Mon May 13 14: 32: 05 2024 ~ E5 \ Page 1
REPORT ID: 24E186 Page 85 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E11\REV201.D
Acq On 11 May 2024 1:28 pm
Sample V001El16 1.0/5.0
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
7
LPriet
01
1.00
Quant Time: May 13 13:58 2024 Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Conc Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) 1,1,1-Trichloroethane
36) Cyclohexane
38) 1,1-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) Benzene
43) 1,2-Dichloroethane
44) Trichloroethene
45) Methylcyclohexane
46) 1,2-Dichloropropane
47) Bromodichloromethane
48) 1,4-Dioxane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) 1,1,2-Trichloroethane
59) 2-Hexanone
60) 1,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
63) 1,2-Dibromoethane
64) 1-Chlorohexane
65) Chlorobenzene
66) 1,1,1,2-Tetrachloroethane
67) Ethylbenzene
68) m-Xylene & p-Xylene
69) o-Xylene
70) Styrene
71) Isopropylbenzene
73) Bromoform
74) trans-1,4-Dichloro-2-buten
75) 1,1,2,2-Tetrachloroethane
77) 1,2,3-Trichloropropane
78) n-Propylbenzene
79) Bromobenzene
7.14
7.20
7.49
7.52
7.72
7.88
7.88
49
42
97
84
110
119
73
8.13 ~ 78
8.10 , 62
9.06 130
9.17 83
9.34 ' 63
9.73 ·83
9.79 88
9.82 93
10.23 -63
10.26 43
10.62 75
11.17 91
11.46 69
11.48 -75
11.74 97
11. 76 43
12.19 76
12.29 164
12.66 129
13.03 107
13.30
13.79
13.86
13.88
14.01
14.84
14.90
15.52
15.55
15.63
15.86
16.14
16.29
16.38
" 91
112
,
131
91
/ 91
~ 91
104
~ 105
173
53
83
110
91
156
205550
27463
444990
417453
150631
336330
497165
1153601
229577
307851
454050
256137
342146
20047
116361
63930
589994
398855
1262539
182985
289239
160672
335905
271863
266498
193517
159304
551589
759554
232054
1473355
2121368
1078385
842539
1453974
95720
44316
168234
45054
1790558
279576
9.28 ug/l
8.42 ug/l
9.43 ug/l
9.08 ug/l
9.39 ug/l
9.57 ug/l
8.82 ug/l
9.38 ug/l
9.25 ug/l
9.67 ug/l
8.98 ug/l
9.30 ug/l
8.95 ug/l
177.87 ug/l
8.96 ug/l
9.15 ug/l
43.70 ug/l
9.31 ug/l
9.58 ug/l
9.25 ug/l
9.44 ug/l
9.31 ug/l
43.39 ug/l
9.28 ug/l
9.73 ug/l
9.19 ug/l
9.33 ug/l
9.69 ug/l
9.67 ug/l
9.59 ug/l
9.79 ug/l
19.26 ug/l
9.51 ug/l
9.59 ug/l
9.74 ug/l
8.57 ug/l
9.04 ug/l
8.90 ug/l
9.31 ug/l
9.70 ug/l
9.57 ug/l
Qvalue
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
99
100
100
(#) = qualifier out of range (m) = manual integration 5~ j
REV201.D V001E11.M Mon May 13 14: 32: OS 2024 5\ \ ~ d-Cf Page 2
REPORT ID: 24E186 Page 86 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E11\REV201.D
Aeq On 11 May 2024 1:28 pm
Sample V001El16 1.0/5.0
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
7
LPriet
01
1. 00
Quant Time: May 13 13:58 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Cone Unit
80 ) 1, 3, 5-Trimethylbenzene 16.60 "'105 1139657 9.66 ug/l
81) 2-Chlorotoluene 16.63 .-' 91 1060747 9.54 ug/l
82) 4-Chlorotoluene 16.72 / 91 963048 9.78 ug/l
83) tert-Butylbenzene 17.29 ,134 239466 9.67 ug/l
84) l,2,4-Trimethylbenzene 17.36 105 1122345 9.72 ug/l
85) see-Butylbenzene 17.66 105 1569792 9.68 ug/l
86) p-Isopropyltoluene 17.88 <119 1201659 9.61 ug/l
87) l,3-Diehlorobenzene 18.03 -146 533251 9.60 ug/l
88 ) 1, 2, 3-Trimethylbenzene 18.13 '105 1019164 9.45 ug/l
89) l,4-Diehlorobenzene 18.19 -146 518636 9.53 ug/l
90) n-Butylbenzene 18.49 91 1250551 9.65 ug/l
91) l,2-Diehlorobenzene 18.72 / 146 424621 9.33 ug/l
92) l,2-Dibromo-3-ehloropropan 19.71 157 23773 8.27 ug/l
93) l,2,4-Triehlorobenzene 20.80 180 314594 9.47 ug/l
94) Hexaehlorobutadiene 20.96 225 197705 9.99 ug/l
95) Naphthalene 21.14 128 358996 9.26 ug/l
96) 1, 2, 3-Triehlorobenzene 21. 46 ~ 180 236728 9.46 ug/l
Qvalue
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
~~fA 5 1\:5/ d.-t{ ___________________________________________________________________ J ____ _
(#) = qualifier out of range (m) = manual integration
REV201.D V001E11.M Mon May 13 14:32:06 2024 Page 3
REPORT ID: 24E186 Page 87 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E11\REV201.D
Aeq On 11 May 2024 1:28 pm
Sample V001El16 1.0/5.0
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
7
LPriet
01
1. 00
Quant Time: May 13 13:58 2024 Quant Results File: V001E11.RES
Method
Title
Last Update
Response via
f.bundance
2000000
1900000
1800000
1700000
1600000
1500000
1400000
1300000
1200000
1100000
1000000
900000
800000
700000
600000
500000
400000
300000
200000
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
TIC: REV201.D
:
(
c~ ~~\ \cU" ,-~l, ~ ~ c,
~,~, ~ ~ ,I ~
1000: ~j VI \ ~
ime--> 2. 0 3.bo 4.bo 5.b6 6.bo 7.bo 8.vO 9.vO 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.0020.0021.00
REV201.D V001E11.M Mon May 13 14:32:08 2024 Page 4
REPORT ID: 24E186 Page 88 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E11\REV202.D
Acq On 11 May 2024 1:58 pm
Sample V001El17 2.0/10
Misc 20ppb 8260/100ppb KET-AA/500ppb
MS Integration Params: RTE.P
Quant Time: May 13 14:00 2024
Vial: 8
Operator: LPriet
Inst : 01
TBA Multiplr: 1.00
Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
72) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
3) Dichlorodifluoromethane
5) Chloromethane
6) Vinyl chloride
7) Bromomethane
8) Chloroethane
9) Dichlorofluoromethane
10) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
18) Methylene chloride
19) Carbon disulfide
20) Acrylonitrile
21) tert-Butyl methyl ether (M
22) trans-1,2-Dichloroethene
23) Isopropyl ether (DIPE)
24) Vinyl acetate
25) l,l-Dichloroethane
27) tert-Butyl ethyl ether (ET
28) 2-Butanone
29) 2,2-Dichloropropane
30) cis-1,2-Dichloroethene
31) Chloroform
8.56 114
13.73 117
18.69 152
7.24
7.97
11.03
16.03
2.17
2.47
2.61
3.15
3.20
3.29
3.55
3.98
4.07
4.06
4.24
4.34
4.65
4.66
4.87
4.89
5.04
5.06
5.26
5.67
5.84
5.84
6.25
6.43
6.64
6.69
6.92
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
142
43
49
76
53
73
,. 61
45
43
" 63
59
43
77
'" 96
83
816915
679573
256277
546945
10.00 ug/l
10.00 ug/l
10.00 ug/l
21.63
0.02
0.02
0.02
0.01
Recovery =
ug/l
216.30%
ug/l
213.60%
ug/l
210.50%
ug/l
212.40%
368310 21.36
Recovery =
2143971 21.05
Recovery =
741429 21.24
Recovery =
443172
619334
541540
618346
385600
1066762
683028
192986
365492
284979
930390
495292
1006828
166847
730623
2006384
392428
899904
902607
1935724
675084
1063100
1387307
502145
865612
725941
1028651
20.27 ug/l
20.24 ug/l
21. 25 ug/l
20.69 ug/l
20.85 ug/l
20.31 ug/l
19.81 ug/l
105.17 ug/l
21.21 ug/l
95.57 ug/l
21.35 ug/l
544.64 ug/l
21. 55 ug/l
20.52 ug/l
20.90 ug/l
21. 54 ug/l
103.74 ug/l
21. 00 ug/l
21.50 ug/l
21.58 ug/l
21.93 ug/l
21.66 ug/l
21. 59 ug/l
109.75 ug/l
20.97 ug/l
21.48 ug/l
20.56 ug/l
0.00
0.00
0.02
Qvalue
99
100
100
97
99
99
99
96
99
99
100
99
100
99
100
100
100
99
99
99
100
100
99
100
100
100
100
(#) = qualifier out of range (m) = manual integration
REV202.D V001E11.M Mon May 13 14:32:26 2024
REPORT ID: 24E186 Page 89 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E11\REV202.D
Acq On 11 May 2024 1:58 pm
Sample V001El17 2.0/10
Misc 20ppb 8260/100ppb KET-AA/500ppb
MS Integration Params: RTE.P
Vial: 8
Operator: LPriet
Inst 01
TBA Multiplr: 1.00
Quant Time: May 13 14:00 2024 Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. Qlon Response Conc Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) l,l,l-Trichloroethane
36) Cyclohexane
38) l,l-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) Benzene
43) l,2-Dichloroethane
44) Trichloroethene
45) Methylcyclohexane
46) l,2-Dichloropropane
47) Bromodichloromethane
48) l,4-Dioxane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) l,l,2-Trichloroethane
59) 2-Hexanone
60) l,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
63) l,2-Dibromoethane
64) 1-Chlorohexane
65) Chlorobenzene
66) l,l,l,2-Tetrachloroethane
67) Ethylbenzene
68) m-Xylene & p-Xylene
69) o-Xylene
70) Styrene
71) Isopropylbenzene
73) Bromoform
74) trans-1,4-Dichloro-2-buten
75) l,l,2,2-Tetrachloroethane
77) l,2,3-Trichloropropane
78) n-propylbenzene
79) Bromobenzene
7.15 49
7.21 42
7.51 97
7.54 84
7.73 110
7.89 119
7.89 73
8.15 78
8.12 62
9.08 130
9.17 83
9.36 '063
9.74 83
<'
9.79 88
9.83 93
10.23 63
10.28 43
10.63 r 75
11.18 91
11. 46 69
11.49 ; 75
11. 76 97
11.77 43
12.20 76
12.31 164
12.68 129
13.05 107
13.32/ 91
13.80 112
13.88 131
13.89 ' 91
14.03 I 91
14.86" 91
14.92 104
15.54/ 105
15.57 173
15.64 53
15.88 83
16.16 110
16.31 91
16.40 156
418099
59689
890497
839410
301701
658847
1043076
2297893
472900
611530
904979
521244
704865
43990
243286
134190
1288906
818576
2491900
395514
603742
330926
767459
575688
522743
406460
339123
1076692
1529085
470126
2901232
4237521
2143592
1701411
2885751
208560
96395
354915
95768
3533479
569509
21.28 ug/l
20.62 ug/l
21. 28 ug/l
20.59 ug/l
21. 21 ug/l
21.13 ug/l
20.86 ug/l
21. 05 ug/l
21. 49 ug/l
21.66 ug/l
20.18 ug/l
21. 35 ug/l
20.80 ug/l
440.03 ug/l
21.12 ug/l
21.65 ug/l
103.66 ug/l
21. 54 ug/l
20.65 ug/l
21.84 ug/l
21.52 ug/l
20.94 ug/l
101.03 ug/l
21.46 ug/l
20.84 ug/l
21. 07 ug/l
21.70 ug/l
20.66 ug/l
21. 25 ug/l
21.22 ug/l
21. 06 ug/l
42.03 ug/l
20.66 ug/l
21.15 ug/l
21.11 ug/l
20.24 ug/l
21.80 ug/l
20.80 ug/l
21.94 ug/l
21.21 ug/l
21. 60 ug/l
Qvalue
99
99
100
100
99
99
100
100
99
99
100
100
100
99
99
98
100
100
100
98
100
99
100
99
99
99
99
100
100
99
99
100
99
100
100
99
97
99
98
100
99
(#) = qualifier out of range (m) = manual integration
REV202.D V001E11.M Mon May 13 14:32:27 2024
?;lA U "-5\\~/Y Page 2 REPORT ID: 24E186 Page 90 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E11\REV202.D
Aeq On 11 May 2024 1:58 pm
Sample V001El17 2.0/10
Mise : 20ppb 8260/100ppb KET-AA/500ppb
MS Integration Params: RTE.P
Quant Time: May 13 14:00 2024
Quant Method D:\HPCHEM\1\METHODS\V001E11.M
Title METHOD 8260 25mls
Last Update Mon May 13 13:20:11 2024
Response via Initial Calibration
DataAeq Meth V001E11
Compound R.T. Qlon
TBA
Vial:
Operator:
Inst
Multiplr:
8
LPriet
01
1. 00
Quant Results File: V001E11.RES
(RTE Integrator)
Response Cone Unit Qvalue
-------------------------------------------------------------------------
80) l,3,5-Trimethylbenzene 16.62 105 2263948 21. 26 ug/l 99 ,
81) 2-Chlorotoluene 16.65 ( 91 2094475 20.88 ug/l 100
82) 4-Chlorotoluene 16.74 / 91 1908157 21.48 ug/l 100
83) tert-Butylbenzene 17.30/134 478610 21.43 ug/l 99
84) l,2,4-Trimethylbenzene 17.37 105 2219029 21. 30 ug/l 100
85) see-Butylbenzene 17.67 105 3115101 21. 28 ug/l 100
86) p-Isopropyltoluene 17.89 , 119 2394992 21.23 ug/l 100
87) l,3-Diehlorobenzene 18.04 ' 146 1072675 21.41 ug/l 100
88) l,2,3-Trimethylbenzene 18.14 -105 2044493 21.02 ug/l 100
89) l,4-Diehlorobenzene 18.20,146 1030532 20.98 ug/l 100
90) n-Butylbenzene 18.50 91 2472290 21.16 ug/l 100
91) l,2-Diehlorobenzene 18.74'146 871915 21. 24 ug/l 100
92) l,2-Dibromo-3-ehloropropan 19.73 157 54040 20.05 ug/l 99
93) 1, 2, 4-Triehlorobenzene 20.81'180 660275 22.03 ug/l 100
94) Hexaehlorobutadiene 20.99 225 397807 22.28 ug/l 100
95) Naphthalene 21.15 128 776440 22.20 ug/l 99
96) l,2,3-Triehlorobenzene 21. 48 J 180 496067 21.97 ug/l 100
(#) = qualifier out of range (m) = manual integration
REV202.D V001E11.M Mon May 13 14:32:27 2024 Page 3
REPORT ID: 24E186 Page 91 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E11\REV202.D
Aeq On 11 May 2024 1:58 pm
Sample V001El17 2.0/10
Mise 20ppb 8260/100ppb KET-AA/500ppb TBA
Vial:
Operator:
Inst
Multiplr:
8
LPriet
01
1. 00
MS Integration Params: RTE.P
Quant Time: May 13 14:00 2024 Quant Results File: V001E11.RES
Method
Title
Last Update
Response via
3800000
3600000
3400000
3200000
3000000
2800000
2600000
2400000
2200000
2000000
1800000
1600000
1400000
1200000
1000000
800000
600000
400000
200000 ~~
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
Ill;: Kt: V;lU;l.U
::; ...: .,
c .,
>. t
0)
c
I!! ~
::; ...: .,
c ~ ., ,<l
i
E ·c ::;.~
I-:.~
::; 2l~
...: ~ ~ ., ill! c
~ ~ e .,
.c 0.. ~ r!: e c.
il
::E.
0) c .,
" 0 e ~ ~ en
0)
c ~ ~ il ~ ~
" ~ e m
..j-
::; . ...:
~,~~ 4O., 9~ Iii
ije
ge .,0
I-;'
N
.N
f
::; ...: .,
c
~
il
~ w ::; r!: ::;r-:
...:~ m~:;
l;!JilI-:. .,,,,.,
,<lc.c ~~U :i mgil i ~6.~ U> .,
E 'c i ~ I <'i ~
1lj. t-f-.
.2Ii .,'" • Cc ~ .,~
::; ...: .,
c ~ .,
.c e ~ -e ~.
.Ii z
::; ...: .,
C .,
~ ~g
~ ::;
~ ...: .,
C
N-e ~ '0 C ti .,
.c ~ e
:t ~ 'C
I-
::; ::;.<'l
~~ ...: .,~
c 2l ~ ::l = e '5. c. .. e
~ z
(,
E e
£! c
~
oN~~ / V\ \j
Irime--> 2.bb 3.bb 4.bb 5.bo 6.bo 7.bo 8.bb 9.bo 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.0020.0021.00
REV202.D V001E11.M Mon May 13 14:32:30 2024 Page 4
REPORT ID: 24E186 Page 92 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E11\REV203.D
Acq On 11 May 2024 2:27 pm
Sample V001El18 3.0/15
Misc 30ppb 8260/150ppb KET-AA/750ppb
MS Integration Params: RTE.P
Quant Time: May 13 14:02 2024
TBA
Vial:
Operator:
Inst
Multiplr:
9
LPriet
01
1. 00
Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
72) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
3) Dichlorodifluoromethane
5) Chloromethane
6) Vinyl chloride
7) Bromomethane
8) Chloroethane
9) Dichlorofluoromethane
10) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
18) Methylene chloride
19) Carbon disulfide
20) Acrylonitrile
21) tert-Butyl methyl ether (M
22) trans-1,2-Dichloroethene
23) Isopropyl ether (DIPE)
24) Vinyl acetate
25) l,l-Dichloroethane
27) tert-Butyl ethyl ether (ET
28) 2-Butanone
29) 2,2-Dichloropropane
30) cis-1,2-Dichloroethene
31) Chloroform
8.56 114
13.72 117
18.68 152
7.23
7.97
11.02
16.01
2.18
2.48
2.61
3.15
3.20
3.27
3.57
3.98
4.07
4.06
4.23
4.34
4.65
4.65
4.86
4.89
5.02
5.06
5.26
5.67
5.82
5.83
6.23
6.41
6.63
6.69
6.92
111
65
98
95
85
50
62
94
64
67
101
56
151
43
t' 61
59
142
43
49
76
53
73
/ 61
45
43
63
.(' 59
43
77
96
83
849708
707238
267331
799087
10.00 ug/l
10.00 ug/l
10.00 ug/l
0.02
0.00
0.00
30.38 ug/l 0.00
Recovery = 303.80%
550662 30.70 ug/l 0.00
Recovery = 307.00%
3115280 29.39
Recovery =
ug/l -0.01
293.90%
1073630 29.49 ug/l 0.00
Recovery = 294.90%
673565
894520
776773
899449
574606
1551702
1032985
286661
554202
435360
1367312
759636
1484308
247532
1052102
2879778
590477
1337887
1319053
2808667
1017586
1541259
2031979
780834
1283925
1065003
1477710
29.62 ug/l
28.10 ug/l
29.30 ug/l
29.03 ug/l
29.88 ug/l
28.41 ug/l
28.80 ug/l
150.20 ug/l
30.92 ug/l
140.37 ug/l
30.17 ug/l
803.08 ug/l
30.55 ug/l
29.27 ug/l
28.94 ug/l
29.72 ug/l
150.07 ug/l
30.02 ug/l
30.21 ug/l
30.11 ug/l
31.77 ug/l
30.19 ug/l
30.40 ug/l
164.07 ug/l
29.91 ug/l
30.30 ug/l
28.40 ug/l
Qvalue
98
100
100
97
100
99
99
97
100
97
100
99
100
100
100
100
99
98
100
100
100
100
100
100
100
100
100
(#) = qualifier out of range (m) = manual integration
REV203.D V001E11.M Mon May 13 14:32:40 2024
REPORT ID: 24E186 Page 93 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24Ell\REV203.D
Acq On 11 May 2024 2:27 pm
Sample V001El18 3.0/15
Misc 30ppb 8260/150ppb KET-AA/750ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
9
LPriet
01
1. 00
Quant Time: May 13 14:02 2024 Quant Results File: V001Ell.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001Ell.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001Ell
Compound R.T. Qlon Response Conc Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) l,l,l-Trichloroethane
36) Cyclohexane
38) l,l-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) Benzene
43) l,2-Dichloroethane
44) Trichloroethene
45) Methylcyclohexane
46) l,2-Dichloropropane
47) Bromodichloromethane
48) l,4-Dioxane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-l,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-l,3-Dichloropropene
58) l,l,2-Trichloroethane
59) 2-Hexanone
60) l,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
63) l,2-Dibromoethane
64) 1-Chlorohexane
65) Chlorobenzene
66) l,l,l,2-Tetrachloroethane
67) Ethylbenzene
68) m-Xylene & p-Xylene
69) o-Xylene
70) Styrene
71) Isopropylbenzene
73) Bromoform
74) trans-l,4-Dichloro-2-buten
75) l,l,2,2-Tetrachloroethane
77) l,2,3-Trichloropropane
78) n-Propylbenzene
79) Bromobenzene
7.15 49
7.20 42
7.49 97
7.52 84
7.73 110
7.88 119
7.89 73
8.13 78
8.10 62
9.06 130
9.17 /83
9.35 r 63
9.73 /' 83
9.76' 88
9.82 93
10.22 ..-63
10.26 43
10.62 r 75
11.17 91
11. 45 69
11.48~ 75
11. 75 97
11. 76 43
12.19 76
12.29 164
12.66 129
13.03 107
13.30 91
13.79 ./ 112
13.86 131
13.88 / 91
14.01 j 91
14.84 I 91
14.90 104
15.52 -105
15.55 / 173
15.63 53
15.86 83
16.15 110
16.29 91
16.38 156
628929
89460
1293540
1200311
446401
976969
1549323
3348702
692754
891995
1305359
761086
1014655
66102
364896
205504
1958633
1217843
3665193
584066
891028
494541
1192685
844763
772439
594252
501525
1608154
2219576
687136
4240845
6175129
3177799
2503360
4219160
312940
144056
534853
141561
5144010
831254
30.78 ug/l
29.72 ug/l
29.71 ug/l
28.31 ug/l
30.17 ug/l
30.13 ug/l
29.79 ug/l
29.50 ug/l
30.26 ug/l
30.38 ug/l
27.98 ug/l
29.96 ug/l
28.78 ug/l
635.70 ug/l
30.46 ug/l
31.88 ug/l
150.19 ug/l
30.81 ug/l
29.18 ug/l
30.99 ug/l
30.52 ug/l
30.07 ug/l
148.48 ug/l
30.26 ug/l
29.59 ug/l
29.60 ug/l
30.83 ug/l
29.65 ug/l
29.64 ug/l
29.80 ug/l
29.59 ug/l
58.85 ug/l
29.42 ug/l
29.90 ug/l
29.65 ug/l
28.97 ug/l
31. 24 ug/l
30.05 ug/l
31.09 ug/l
29.59 ug/l
30.23 ug/l
(#) = qualifier out of range (m) = manual integration /..;' V'-. 1(/
REV203 . D V001E11. M Mon May 13 14: 32: 41 2024 ------~5' \ ,S( J-'-L
Qvalue
100
98
100
100
99
100
99
100
99
99
100
100
100
99
97
98
100
100
100
97
100
99
99
99
99
99
99
100
100
99
100
100
100
100
100
99
96
99
97
100
100
Page 2
REPORT ID: 24E186 Page 94 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E11\REV203.D
Aeq On 11 May 2024 2:27 pm
Sample V001El18 3.0/15
Mise 30ppb 8260/150ppb KET-AA/750ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
9
LPriet
01
1. 00
Quant Time: May 13 14:02 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Cone Unit
80 ) l,3,5-Trimethylbenzene 16.60 /105 3300850 29.72 ug/l
81) 2-Chlorotoluene 16.63 91 3091027 29.54 ug/l
82) 4-Chlorotoluene 16.72 91 2792432 30.14 ug/l
83) tert-Butylbenzene 17.29 '134 693102 29.75 ug/l
84) l,2,4-Trimethylbenzene 17.35 -105 3247834 29.89 ug/l
85) see-Butylbenzene 17.66' 105 4497766 29.46 ug/l
86 ) p-Isopropyltoluene 17.88/119 3456736 29.37 ug/l
87) l,3-Diehlorobenzene 18.03 ,146 1566009 29.97 ug/l
88) l,2,3-Trimethylbenzene 18.13 / 105 3006443 29.63 ug/l
89) l,4-Diehlorobenzene 18.19 146 1511456 29.50 ug/l
90) n-Butylbenzene 18.49.1 91 3615477 29.66 ug/l
91) l,2-Diehlorobenzene 18.72/ 146 1277031 29.82 ug/l
92) l,2-Dibromo-3-ehloropropan 19.72 157 81915 28.90 ug/l
93) l,2,4-Triehlorobenzene 20.80/ 180 991777 31.73 ug/l
94) Hexaehlorobutadiene 20.96 225 585385 31. 43 ug/l
95) Naphthalene 21.14 128 1169103 32.04 ug/l
96) l,2,3-Triehlorobenzene 21.46/ 180 737458 31.32 ug/l
(#) = qualifier out of range (m) = manual integration
REV203.D V001E11.M Mon May 13 14:32:42 2024
Qvalue
99
100
99
99
99
100
100
100
100
100
100
100
100
100
99
100
99
REPORT ID: 24E186 Page 95 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E11\REV203.D
Acq On 11 May 2024 2:27 pm
Sample V001El18 3.0/15
Mise 30ppb 8260/150ppb KET-AA/750ppb TBA
Vial:
Operator:
Inst
Multiplr:
9
LPriet
01
1. 00
MS Integration Params: RTE.P
Quant Time: May 13 14:02 2024 Quant Results File: V001E11.RES
Method
Title
Last Update
Response via
~bundance
6000000
5800000
5600000
5400000
5200000
5000000
4800000
4600000
4400000
4200000
4000000
3800000
3600000
3400000
3200000
3000000
2800000
2600000
2400000
2200000
2000000
1800000
1600000
1400000
1200000
1000000
800000
600000
400000
200000 t \rJ\ I
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
II\,;: M:I::V£V".U
I
F
-,
o AJ~\ / v V '-
ime--> 2.bo 3.bo 4.bo 5.bo
REV203.D V001E11.M Mon May 13 14:32:44 2024 Page 4
REPORT ID: 24E186 Page 96 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E11\REV204.D
Acq On 11 May 2024 2:56 pm
Sample V001El19 5.0/25
Misc 50ppb 8260/250ppb KET-AA/1250ppb
MS Integration Params: RTE.P
Quant Time: May 13 14:33 2024
TBA
Vial:
Operator:
Inst
Multiplr:
10
LPriet
01
1. 00
Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
72) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
3) Dichlorodifluoromethane
5) Chloromethane
6) Vinyl chloride
7) Bromomethane
8) Chloroethane
9) Dichlorofluoromethane
10) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
18) Methylene chloride
20) Acrylonitrile
21) tert-Butyl methyl ether (M
22) trans-1,2-Dichloroethene
23) Isopropyl ether (DIPE)
24) Vinyl acetate
25) l,l-Dichloroethane
27) tert-Butyl ethyl ether (ET
28) 2-Butanone
29) 2,2-Dichloropropane
30) cis-1,2-Dichloroethene
31) Chloroform
32) Bromochloromethane
33) Tetrahydrofuran
8.56 114
13.71 117
18.68 152
0.00 111
0.00 65
0.00 98
0.00 95
2.17
2.47
2.62
3.15
3.20
3.29
3.57
3.98
4.07
4.06
4.24
4.34
4.64
4.86
5.02
5.07
5.26
5.67
5.82
5.84
6.25
6.41
6.64
6.68
6.92
7.15
7.20
85
50
62
94
64
67
101
56
151
43
/ 61
59
142
49
53
73
/61
45
43
,/ 63
59
43
77
/96
83
49
42
790188
650561
247844
10.00 ug/l
10.00 ug/l
10.00 ug/l
o 0.00 ug/l
0.01
0.00
0.00
Recovery = 0.00%
Od 0.00 ug/l
Recovery = 0.00%
Od 0.00 ug/l
Recovery = 0.00%
Od 0.00 ug/l
Recovery = 0.00%
1081177
1438807
1235915
1484374
946787
2533049
1663384
473669
901773
730855
2222510
1234938
2410819
1737751
973695
2163847
2150916
4495028
1638323
2492540
3217505
1277785
2063550
1715982
2420327
1013155
153627
51.13 ug/l
48.60 ug/l
50.13 ug/l
51.68 ug/l
52.94 ug/l
49.87 ug/l
49.87 ug/l
266.87 ug/l
54.10 ug/l
253.40 ug/l
52.74 ug/l
1403.91 ug/l
53.35 ug/l
51.40 ug/l
266.10 ug/l
52.20 ug/l
52.97 ug/l
51.81 ug/l
55.01 ug/l
52.49 ug/l
51.76 ug/l
288.71 ug/l
51.69 ug/l
52.50 ug/l
50.02 ug/l
53.31 ug/l
54.88 ug/l
Qvalue
98
100
100
98
99
98
99
99
100
100
100
99
100
100
99
99
99
99
100
100
98
100
100
99
100
98
97
(#) = qualifier out of range (m) = manual integration
REV204.D V001E11.M Mon May 13 14:33:16 2024
REPORT ID: 24E186 Page 97 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E11\REV204.D
Acq On 11 May 2024 2:56 pm
Sample V001El19 5.0/25
Misc 50ppb 8260/250ppb KET-AA/1250ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
10
LPriet
01
1. 00
Quant Time: May 13 14:33 2024 Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. Qlon Response Conc Unit
35)
38 )
39)
40)
42)
43 )
44)
46)
47)
48)
49)
50)
51)
52)
55)
56)
57)
58)
59)
60 )
61)
62)
63)
64)
65)
66)
67)
68)
69)
70 )
71)
73)
74)
75)
77)
78)
79)
80)
81)
82)
83)
l,l,l-Trichloroethane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
l,2-Dichloroethane
Trichloroethene
l,2-Dichloropropane
Bromodichloromethane
l,4-Dioxane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
Ethyl methacrylate
trans-1,3-Dichloropropene
1, 1, 2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, l,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
trans-1,4-Dichloro-2-buten
1, 1, 2, 2-Tetrachloroethane
l,2,3-Trichloropropane
n-Propylbenzene
Bromobenzene
l,3,5-Trimethylbenzene
2-Chlorotoluene
4-Chlorotoluene
tert-Butylbenzene
7.51
7.73
7.88
7.90
8.13
8.10
9.08
9.34
9.73
9.76
9.82
10.22
10.26
10.62
11.17
11. 45
11.48
11. 74
11.74
12.19
12.29
12.66
13.03
13.30
13.79
13.86
13.88
14.03
14.84
14.90
15.52
15.55
15.63
15.86
16.14
16.29
16.38
16.60
16.63
16.74
17.29
97
110
119
73
78
62
130
63
83
'88
</ 93
63
43
75
"" 91
69
./ 75
97
43
76
164
129
107
91
/112
131
. 91
-91
"' 91
104
~105
173
-53
83
110
91
(156
105
-' 91
91
, 134
2111400
723523
1591100
2542219
5383213
1118925
1468714
1258335
1690988
113358
602961
329105
3235283
1992729
6025151
966319
1465798
796053
1992542
1380516
1249230
985487
822866
2572709
3610696
1116459
6718588
9682404
5069451
4017810
6705142
504524
237301
869256
235480
8220515
1345207
5240717
4859918
4476659
1119401
52.15 ug/l
52.58 ug/l
52.76 ug/l
52.56 ug/l
50.99 ug/l
52.56 ug/l
53.79 ug/l
53.27 ug/l
51.58 ug/l
1172.28 ug/l
54.12 ug/l
54.91 ug/l
264.67 ug/l
54.21 ug/l
52.15 ug/l
55.74 ug/l
54.58 ug/l
52.63 ug/l
265.71 ug/l
53.77 ug/l
52.02 ug/l
53.37 ug/l
54.99 ug/l
51. 57 ug/l
52.42 ug/l
52.63 ug/l
50.95 ug/l
100.31 ug/l
51.03 ug/l
52.17 ug/l
51. 23 ug/l
50.13 ug/l
55.50 ug/l
52.68 ug/l
55.79 ug/l
51.01 ug/l
52.77 ug/l
50.90 ug/l
50.09 ug/l
52.12 ug/l
51. 83 ug/l
Qvalue
100
99
99
99
100
100
99
100
100
97
98
98
99
99
100
98
99
100
99
99
100
99
99
100
99
99
99
99
99
99
100
99
96
99
92
100
100
99
95
97
98
(#) = qualifier out of range (m) = manual integration ~ ~ ~/. vf
REV204.D V001E11.M Mon May 13 14: 33: 17 2024 ~j \ \-=.> r Page 2
REPORT ID: 24E186 Page 98 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E11\REV204.D
Aeq On 11 May 2024 2:56 pm
Sample V001El19 5.0/25
Mise 50ppb 8260/250ppb KET-AA/1250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
10
LPriet
01
1. 00
Quant Time: May 13 14:33 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Cone Unit
84) 1,2,4-Trimethylbenzene 17.36 '105 5150477 51.12 ug/l
85) see-Butylbenzene 17.66 105 7213677 50.97 ug/l
86) p-Isopropyltoluene 17.88 '" 119 5536086 50.73 ug/l
87) 1,3-Diehlorobenzene 18.03 t 146 2506660 51.74 ug/l
88) 1, 2, 3-Trimethylbenzene 18.13 t-105 4772026 50.74 ug/l
89) 1,4-Diehlorobenzene 18.19 (146 2389062 50.30 ug/l
90) n-Butylbenzene 18.49 91 5704101 50.47 ug/l
91) 1,2-Diehlorobenzene 18.72(146 2055877 51. 79 ug/l
92) 1,2-Dibromo-3-ehloropropan 19.71(157 138333 52.22 ug/l
93) 1, 2, 4-Triehlorobenzene 20.80 180 1603778 55.34 ug/l
94) Hexaehlorobutadiene 20.97 225 940175 54.45 ug/l
95) Naphthalene 21.15 128 1911993 56.52 ug/l
96) 1, 2, 3-Triehlorobenzene 21.46 I 180 1194867 54.73 ug/l
Qvalue
99
100
100
100
99
99
100
100
99
100
100
100
100
_________________________________________________________ !!_ ~~ _ ~~ _ ~ ~ ~~l ~_~
(#) = qualifier out of range (m) = manual integration
REV204.D V001E11.M Mon May 13 14:33:17 2024 Page 3
REPORT ID: 24E186 Page 99 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24Ell\REV204.D
Aeq On 11 May 2024 2:56 pm
Sample VOOIEl19 5.0/25
Mise 50ppb 8260/250ppb KET-AA/1250ppb TBA
Vial:
Operator:
Inst
Multiplr:
10
LPriet
01
l. 00
MS Integration Params: RTE.P
Quant Time: May 13 14:33 2024 Quant Results File: VOOIEll.RES
Method
Title
Last Update
Response via
IAbundance
9000000
8500000
8000000
7500000
7000000
6500000
6000000
5500000
5000000
4500000
4000000
3500000
3000000
2500000
2000000
1500000
1000000
500000
o ~l ~
!Time-> 2.bo 3.bo 4.bo
D:\HPCHEM\l\METHODS\VOOIEll.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
ui z
~
W
III
~ o
:3 u. o
..\:
~
TIC: REV204.D
5.bi> 6.bo 7.bo 8.bo 9.bo 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19:0020:0021:00
REV204.D VOOIEll.M Mon May 13 14:33:19 2024 Page 4
REPORT ID: 24E186 Page 100 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E11\REV205.D
Acq On 11 May 2024 3:26 pm
Sample V001DE1110 10/50
Misc : 100ppb 8260/500ppb KET-AA/2500ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
11
LPriet
01
1. 00
Quant Time: May 13 14:34 2024 Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
72) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
3) Dichlorodifluoromethane
5) Chloromethane
6) Vinyl chloride
7) Bromomethane
8) Chloroethane
9) Dichlorofluoromethane
10) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
18) Methylene chloride
20) Acrylonitrile
21) tert-Butyl methyl ether (M
22) trans-1,2-Dichloroethene
23) Isopropyl ether (DIPE)
24) Vinyl acetate
25) l,l-Dichloroethane
27) tert-Butyl ethyl ether (ET
28) 2-Butanone
29) 2,2-Dichloropropane
30) cis-1,2-Dichloroethene
31) Chloroform
32) Bromochloromethane
33) Tetrahydrofuran
8.56 114
13.72 117
18.68 152
0.00 111
0.00 65
0.00 98
0.00 95
2.18
2.48
2.61
3.15
3.20
3.29
3.57
4.00
4.09
4.07
4.24
4.34
4.65
4.87
5.02
5.07
5.26
5.67
5.82
5.84
6.25
6.41
6.64
6.69
6.92
7.15
7.20
85
50
62
94
64
67
101
56
151
43
,/' 61
59
142
49
53
73
/61
45
43
63
<' 59
43
77
96
./ 83
49
42
813917
663851
236992
10.00 ug/l
10.00 ug/l
10.00 ug/l
o 0.00 ug/l
Recovery = 0.00%
Od 0.00 ug/l
Recovery = 0.00%
Od 0.00 ug/l
Recovery = 0.00%
Od 0.00 ug/l
Recovery = 0.00%
0.02
0.00
0.00
2149061
2757462
2275750
2950163
1887602
4893407
3259184
98.68
90.43
89.61
99.92
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Qvalue
98
99
920713
1635111
1378975
4287129
2428061
4731046
3383840
1892610
4236425
4113790
8979646
3315001
4821432
6309833
2458656
3940507
3330208
4814377
1957186
291915
102.46
93.53
94.86
503.62
95.23
464.17
98.76
2679.81
101.65
97.16
502.15
99.23
98.36
100.48
108.06
98.58
98.54
539.33
95.83
98.92
96.59
99.99
101. 24
100
97
99
98
100
97
100
96
100
99
100
99
99
99
100
100
99
100
98
99
100
99
100
98
96
(#) = qualifier out of range (m) = manual integration c:~
REV205.D V001E11.M Mon May 13 14:34:29 2024 ~5\\) (~U Page 1
REPORT ID: 24E186 Page 101 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E11\REV205.D
Acq On 11 May 2024 3:26 pm
Sample V001DE1110 10/50
Misc 100ppb 8260/500ppb KET-AA/2500ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
11
LPriet
01
1. 00
Quant Time: May 13 14:34 2024 Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. Qlon Response Conc Unit
35)
38)
39)
40 )
42)
43 )
44)
46)
47)
48)
49)
50)
51)
52)
55)
56)
57)
58)
59 )
60)
61)
62)
63)
64)
65)
66)
67)
68)
69)
70)
71)
73)
74)
75)
77)
78)
79)
80 )
81)
82)
83)
l,l,l-Trichloroethane
l,l-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TA
Benzene
l,2-Dichloroethane
Trichloroethene
l,2-Dichloropropane
Bromodichloromethane
l,4-Dioxane
D ibromome thane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
Toluene
Ethyl methacrylate
trans-1,3-Dichloropropene
l,l,2-Trichloroethane
2-Hexanone
l,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
l,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1, 1, l,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
Bromoform
trans-1,4-Dichloro-2-buten
l,l,2,2-Tetrachloroethane
l,2,3-Trichloropropane
n-Propylbenzene
Bromobenzene
1, 3, 5-Trimethylbenzene
2-Chlorotoluene
4-Chlorotoluene
tert-Butylbenzene
7.51
7.73
7.88
7.89
8.13
8.10
9.06
9.35
9.73
9.76
9.82
10.22
10.26
10.62
11.17
11.45
11.48
11.75
11. 75
12.19
12.31
12.66
13.03
13.30
13.79
13.86
13.88
14.03
14.84
14.90
15.52
15.55
15.63
15.86
16.15
16.29
16.38
16.61
16.63
16.74
17.29
97
110
119
73
78
62
130
63
83
88
93
63
43
/75
91
69
if' 75
97
43
76
164
129
107
/ 91
112
131
) 91
i 91
) 91
104
105
173
53
83
110
91
156
105
c: 91
< 91
/134
4134538
1407010
3044744
4847551
10614708
2198375
2868237
2435072
3272651
217292
1156972
641035
6179211
3875584
11521987
1848777
2820520
1530353
3802288
2688647
2415182
1898169
1574680
4899203
6936484
2153843
12839879
18532298
9582592
7538023
12772431
986318
446145
1626217
438929
15596079
2566592
9823432
9603952
7702833
2120781
99.15 ug/l
99.26 ug/l
98.02 ug/l
97.30 ug/l
97.62 ug/l
100.25 ug/l
101.98 ug/l
100.09 ug/l
96.91 ug/l
2181. 59 ug/l
100.82 ug/l
103.83 ug/l
488.45 ug/l
102.36 ug/l
97.73 ug/l
104.51 ug/l
102.93 ug/l
99.15 ug/l
492.69 ug/l
102.62 ug/l
98.56 ug/l
100.74 ug/l
103.12 ug/l
96.24 ug/l
98.69 ug/l
99.50 ug/l
95.43 ug/l
188.15 ug/l
94.53 ug/l
95.93 ug/l
95.63 ug/l
102.14 ug/l
109.12 ug/l
103.07 ug/l
108.75 ug/l
101. 22 ug/l
105.28 ug/l
99.77 ug/l
103.52 ug/l
93.79 ug/l
102.68 ug/l
(#) = qualifier out of range (m) = manual integration ~~ ~tV
REV205.D V001E11.M Mon May 13 14: 34: 30 2024 --5 \ \ Sr v .
Qvalue
100
98
99
99
100
100
99
100
100
95
98
97
100
99
99
97
99
99
100
99
100
99
99
100
99
99
98
98
98
99
99
99
93
99
92
99
100
98
98
98
96
Page 2
REPORT ID: 24E186 Page 102 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E11\REV205.D
Aeq On 11 May 2024 3:26 pm
Sample V001DE1110 10/50
Mise 100ppb 8260/500ppb KET-AA/2500ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
11
LPriet
01
1.00
Quant Time: May 13 14:34 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Cone Unit
84) 1, 2, 4-Trimethylbenzene 17.36 ',105 9615877 99.82 ug/l
85) see-Butylbenzene 17.66 ,,105 13298763 98.26 ug/l
86) p-Isopropyltoluene 17.88 119 10259365 98.33 ug/l
87) l,3-Diehlorobenzene 18.03 • 146 4662217 100.65 ug/l
88 ) l,2,3-Trimethylbenzene 18.13 ( 105 8781878 97.65 ug/l
89) l,4-Diehlorobenzene 18.19 < 146 4430571 97.55 ug/l
90 ) n-Butylbenzene 18.49 91 10299843 95.31 ug/l
91) l,2-Diehlorobenzene 18.72 f 146 3781801 99.63 ug/l
92) l,2-Dibromo-3-ehloropropan 19.72 157 255821 100.50 ug/l
93) 1, 2, 4-Triehlorobenzene 20.80 /180 2909800 105.00 ug/l
94) Hexaehlorobutadiene 20.98 225 1658054 100.43 ug/l
95) Naphthalene 21.14 128 3426614 105.94 ug/l
96) l,2,3-Triehlorobenzene 21.46 180 2169257 103.91 ug/l
Qvalue
97
99
99
100
99
100
99
100
100
100
100
100
100
_""~:5' ~ ~1 \ b 1 J. Lt-------------------------------------------------------------~~---~------
(#) = qualifier out of range (m) = manual integration
REV205.D V001E11.M Mon May 13 14:34:30 2024 Page 3
REPORT ID: 24E186 Page 103 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E11\REV205.D
Aeq On 11 May 2024 3:26 pm
Sample V001DE1110 10/50
Mise 100ppb 8260/500ppb KET-AA/2500ppb TBA
Vial:
Operator:
Inst
Multiplr:
11
LPriet
01
1. 00
MS Integration Params: RTE.P
Quant Time: May 13 14:34 2024 Quant Results File: V001E11.RES
Method
Title
Last Update
Response via
Abundance
1.7e+07
1.6e+07
1.5e+07
1.4e+07
1.3e+07
1.2e+07
1.1e+07
1e+07
9000000
8000000
7000000
6000000
5000000
4000000
::;:.::;:
fo-. a)'t-: co.
3000000 ~t E .
~I 2000000 ~
.Q ~
:§ 5 c
1000000
o ~J V\
ime--> 2.bo 3.bb 4.bb
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
Ill,;: REV2IT5.D
::;: ...:
Q) c
I1J
,5
Q)
E ::;: E! •
.Q I-a
"fi ~ ~i ,g E
C E!
.0
i5 ~
i ::;: ~f-:
a~:E
~,11J f0-~~ ~
~ ~.Q l\' "fiE! ~~j
~~:g
~?~ ~:::
,
(
5.bb 6.bo 7. 0 8.bo 9. 0 10:00 11.00 12.00 13.00 14:00 15.00 16.00 17.00 18.00 19.0020.0021.00
REV205.D V001E11.M Mon May 13 14:34:33 2024
REPORT ID: 24E186 Page 104 of 217
SECOND SOURCE
VERIFICATION
REPORT ID: 24E186 Page 105 of 217
Lab Name
Lab Code
FORM 5
VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK
BROMOFLUOROBENZENE (BFB)
EMAX Laboratories, Inc.
EMAX
Project
SDG No
I CAL
I CAL
Lab File ID: REV209 BFB Injection Date: 05/13/24
BFB Injection Time: 11:31 Instrument ID: 01
m/e ION ABUNDANCE CRITERIA
'I; RELATIVE
ABUNDANCE
=====1========================================1================1
50 15 -40% of mass 95 1 17.676 1
75 30 -60% of mass 95 40.505
95 Base Peak, 100% relative abundance ___ 1 100.000
96 5 -% of mass 95 6.366
173 Less than' n of mass 174 0.000(0)1
174 Greater than 50% of mass 95 77.234
175 5 -9% of mass 174 5.650(7.32)1
176 95 -101% % of mass 174 75.082(97.21)1
177 5 9% % of mass 176 4.812(6.41)2
____ 1 __________________________________________ _
I-Value is % mass 174 2-Value is % mass 176
This check applies to the following Calibration Standards:
EPA LAB LAB DATE TIME
1 SAMPLE NO. SAMPLE ID 1 FILE ID ANALYZED ANALYZED
1====================1================1============1==========1==========1
11VSTD10 1 IV001Ell02 IREV210 1 05/13/24 1 12:06 1
REPORT ID: 24E186 Page 106 of 217
CONTINUE_CALIBRATION -CALIBRATION VERIFICATION
Instrument ID :01
IC Beginning DateTime :05/11/24 10:58
Sp1ke Amount :10 PPB
CC/CV File :REV210
IC File :REV201
1
2
3
4
5
6
7
8
9
10
5 11
12
5 13
14
25 15
16
17
18
19
5 20
21
22
23
24
25
25 26
27
5 28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
20 48
49
50
5 51
52
53
54
55
56
57
58
5 59
60
61
62
63
64
65
66
67
2 68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
1,4-DIFLUOROBENZENE
Chlorotrifluoroethylene
Dichlorodifluoromethane
2-Chloro-1,1,1-trifluoroethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Dichlorofluoromethane
Trichlorofluoromethane
Acrolein
1,1,2-Trichloro-1,2,2-trifluoroethane
Acetone
1,1-Dichloroethene
tert-Butyl alcohol
Iodomethane
Methyl acetate
Methylene chloride
Carbon disulfide
Acrylonitrile
tert-Butyl methyl ether (MTBE)
trans-1,2-Dichloroethene
Isopropyl ether (DIPE)
Vinyl acetate
1,1-Dichloroethane
2-Butanol
tert-Butyl ethyl ether (ETBE)
2-Butanone
2,2-Dichloropropane
cis-1,2-Dichloroethene
Chloroform
Bromochloromethane
Tetrahydrofuran
Dibromofluoromethane
1, 1, I-Trichloroethane
Cyclohexane
2,2,4-Trimethylpentane
1,1-Dichloropropene
Carbon tetrachloride
tert-Amyl methyl ether (TAME)
1,2-Dichloroethane-d4
Benzene
1,2-Dichloroethane
Trichloroethene
Methylcyclohexane
1,2-Dichloropropane
Bromodichloromethane
1/4-Dioxane
Dibromomethane
2-Chloroethyl vinyl ether
4-Methyl-2-pentanone
cis-1,3-Dichloropropene
CHLOROBENZENE-D5
Toluene-d8
Toluene
Ethyl methacrylate
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
2-Hexanone
1,3-Dichloropropane
Tetrachloroethene
Dibromochloromethane
1,2-Dibromoethane
1-Chlorohexane
Chlorobenzene
1,1,1,2-Tetrachloroethane
Ethylbenzene
m-Xylene & p-Xylene
o-Xylene
Styrene
Isopropylbenzene
1,2-DICHLOROBENZENE-D4
Bromoform
trans-1,4-Dichloro-2-butene
l,l,2,2-Tetrachloroethane
4-Bromofluorobenzene
1,2,3-Trichloropropane
n-Propylbenzene
Bromobenzene
1,3,5-Trimethylbenzene
2-Chlorotoluene
4-Chlorotoluene
tert-Butylbenzene
1,2,4-Tr~methylbenzene
sec-Butylbenzene
p-Iso~ropyltoluene
1,3-D~chlorobenzene
1,2,3-Trimethylbenzene
1,4-Dichlorobenzene
n-Butylbenzene
1,2-D~chlorobenzene
1,2-Dibromo-3-chloropropane
1,2,4-Trichlorobenzene
Hexachlorobutadiene
Naphthalene
l,2,3-Trichlorobenzene
Sp~ke Amount -Nom~nal Amount * M
10.000
10.744
10.222
11. 091
9.886
9.929
9.809
10.405
46.638
10.699
46.249
10.534
272.706
10.129
9.648
10.396
9.410
49.767
10.216
10.334
10.406
10.436
10.385
10.658
52.383
10.370
10.325
9.820
10.539
10.289
9.898
10.373
10.548
10.276
10.352
10.127
9.949
10.090
10.336
10.150
10.259
10.115
9.862
205.358
10.344
10.212
49.033
10.274
10.000
9.566
9.906
10.213
10.298
10.145
47.364
10.169
9.999
10.064
10.349
10.259
10.061
10.136
9.991
20.234
9.950
9.968
10.036
10.000
9.781
10.276
9.917
9.429
10.138
9.836
9.996
9.883
10.005
10.002
9.950
9.900
9.967
9.795
10.012
9.931
9.894
9.925
9.987
9.352
10.080
9.944
10.201
10.141
o
7.4
2.2
10.9
-1.1
-0.7
-1.9
4.0
-6.7
7.0
-7.5
5.3
9.1
1.3
-3.5
4.0
-5.9
-0.5
2.2
3.3
4.1
4.4
3.9
6.6
4.8
3.7
3.2
-1. 8
5.4
2.9
-1. 0
3.7
5.5
2.8
3.5
1.3
-0.5
0.9
3.4
1.5
2.6
1.1
-1. 4
2.7
3.4
2.1
-1.9
2.7 o
-4.3
-0.9
2.1
3.0
1.5
-5.3
1.7
-0.0
0.6
3.5
2.6
0.6
1.4
-0.1
1.2
-0.5
-0.3
0.4 o
-2.2
2.8
-0.8
-5.7
1.4
-1.6
-0.0
-1. 2
0.1
0.0
-0.5
-1. 0
-0.3
-2.0
0.1
-0.7
-1.1
-0.7
-0.1
-6.5
0.8
-0.6
2.0
1.4
907856 1 1
261017 0.288 0.268
347692
3J.4201
332015
204024
572473
398783
95103
204924
153258
510086
275606
525854
87177
403861
974363
209223
486511
482107
1037346
357100
566566
761232
266366
475647
387725
545984
230106
33093
278148
482510
477860
162485
358693
562793
190681
1223803
252838
318416
511326
274499
371496
22815
132415
70329
657246
433879
757489
1085971
1332719
206172
322019
178678
378200
304011
279605
216381
180319
595972
806907
250367
1533890
2274121
1150973
893787
1529556
290545
112241
51511
191835
373151
50167
1858212
298744
1193060
1138017
1007192
251948
1169308
1653826
1252965
568580
1095079
550958
1315009
464758
27714
342507
201295
404546
259547
0.383
0.346
0.366
0.225
0.631
0.439
0.021
0.226
0.034
0.562
0.012
0.579
0.096
0.445
1.073
0.046
0.536
0.531
1.143
0.393
0.624
0.838
0.059
0.524
0.427
0.601
0.253
0.036
0.306
0.531
0.526
0.179
0.395
0.620
0.210
1.348
0.279
0.351
0.563
0.302
0.409
0.001
0.146
0.077
0.145
0.478
1
1.434
1. 759
0.272
0.425
0.236
0.100
0.401
0.369
0.286
0.238
0.787
l. 065
0.331
2.025
1. 501
1.519
1.180
2.019
1
0.386
0.177
0.660
1.284
0.173
6.396
1.028
4.106
3.917
3.467
0.867
4.025
5.692
4.312
1.957
3.769
1.896
4.526
l. 600
0.095
1.179
0.693
1.392
0.893
0.375
0.312
0.396
0.226
0.643
0.422
0.022
0.211
0.037
0.533
0.011
0.572
0.100
0.428
1.140
0.046
0.525
0.514
1. 098
0.377
0.601
0.787
0.056
0.505
0.414
0.612
0.240
0.035
0.310
0.512
0.499
0.174
0.382
0.612
0.211
1. 336
0.269
0.346
0.549
0.299
0.415
0.001
0.141
0.076
0.136
0.465
1
1.499
1.776
0.266
0.413
0.233
0.090
0.395
0.369
0.284
0.230
0.767
1.059
0.326
2.027
1.484
1. 527
1.184
2.012
1
0.350
0.173
0.666
1. 362
0.170
6.502
1. 029
4.155
3.915
3.466
0.871
4.065
5.711
4.403
1.955
3.795
1.916
4.560
1. 602
0.095
l.169
0.697
1. 365
0.881
-----------------
8.546
2.174
2.487
2.615
3.154
3.198
3.287
3.554
3.984
4.073
4. 058
4.235
4.339
4.635
4.650
4.858
4.887
5.021
5.065
5.243
5.658
5.821
5.821
6.235
6.413
6.621
6.680
6.902
7.139
7.198
7.228
7.495
7.524
7.717
7.880
7.880
7.954
8.132
8.102
9.064
9.153
9.346
9.716
9.775
9.820
10.220
10.264
10.620
13.716
11. 020
11.153
11.449
11. 479
11.746
11.761
12.190
12.294
12.664
13.035
13.301
13.775
13.864
13.879
14.012
14.827
14.901
15.509
18.679
15.553
15.627
15.849
15.998
16.146
16.294
16.383
16.605
16.635
16.723
17.287
17.346
17.657
17.879
18.027
18.131
18.190
18.486
18.709
19.716
20.798
20.961
21.138
21.464
8.551
2.169
2.471
2.605
3.146
3.190
3.276
3.553
3.986
4.070
4.058
4.230
4.342
4.639
4.653
4.858
4.880
5.025
5.061
5.249
5.670
5.832
5.830
6.240
6.428
6.628
6.686
6.908
7.148
7.201
7.228
7.499
7.524
7.723
7.878
7.889
7.965
8.130
8.104
9.072
9.165
9.351
9.732
9.783
9.823
10.234
10.276
10.625
13.717
1l. 030
11.169
11.471
11.484
11.751
11.791
12.195
12.299
12.667
13.038
13.308
13.791
13.865
13.881
14.021
14.843
14.909
15.524
18.680
15.559
15.634
15.865
16.015
16.152
16.298
16.383
16.606
16.635
16.733
17.287
17.360
17.658
17.880
18.028
18.132
18.191
18.489
18.724
19.717
20.801
20.967
21.148
21.466
Column Spec :RXI-624SILMS ID :0.25MM
IC Ending DateTime :05/11/24 15:26
HPChem Method :V001E11
Date_Time :05/13/24 12:06
o
4.44
7.39
6.31
17.96
4.21
8.21
5.20
5.86
8.11
14.45
4.74
9.12
4.85
10.84
3.90
6.08
4.77
4.67
4.44
4.21
9.82
4.54
4.52
10.70
4.21
4.03
8.00
4.73
8.25
7.01
4.19
6.15
4.16
4.43
5.64
7.18
4.04
4.45
4.96
6.46
5.38
6.99
14.49
5.30
8.06
18.90
5.31 o
5.48
4.50
8.54
5.62
4.45
36.80
5.08
3.83
5.55
6.28
4.69
3.64
3.59
4.07
4.23
4.66
3.78
3.97 o
20.61
9.77
6.36
6.06
9.82
5.03
5.26
5.49
4.84
5.46
4.70
4.41
5.27
5.17
4.87
4.70
4.92
5.46
4.06
16.02
7.49
6.95
8.50
6.66
0.0078 0.3620
-0.0424 0.1563
-0.0568 0.1174
-0.0135 0.4088
-0.0056 0.1080
0.9993
0.9988
0.9987
0.9992
0.9987
REPORT ID: 24E186 Page 107 of 217
BFB
Data File D:\HPCHEM\1\DATA\24E13\REV209.D
Acq On 13 May 2024 11:31 am
Sample BFB01E12
Misc T/CHK
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
Method D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
Title : METHOD 8260 25mls
bundance
20000
15000
10000
5000
20000
174
15000
10000
75
5000
50
Iz-->
AutoFind: Scans 978, 979, 980; Background Corrected with Scan 972
1
LPriet
01
1. 00
I Target I ReI. to I Lower I Upper I
Mass Mass Limit% Limit%
ReI.
Abn%
Raw
Abn I Result
Pass/Fail
50
75
95
96
173
174
175
176
177
95
95
95
95
174
95
174
174
176
REV209.D V001E11.M
15
30
100
5
0.00
50
5
95
5
40
60
100
9
2
100
9
101
9
17.7
40.5
100.0
6.4
0.0
77.2
7.3
97.2
6.4
3629
8316
20531
1307
o
15857
1160
15415
988
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
C::;' tI\ \\ c: /'1 L-t Mon May 13 14:37:52 2024---~ J r
REPORT ID: 24E186 Page 108 of 217
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24E13\REV210.D
Acq On 13 May 2024 12:06 pm
Sample IV001E1102 1.0/5.0
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
2
LPriet
01
l. 00
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
1 I l,4-DIFLUOROBENZENE
2 T,M Chlorotrifluoroethylene
3 T,M 'Dichlorodifluoromethane
4 T,M 2-Chloro-1,l,l-trifluoroeth
S P,T,M Chloromethane
6 C/T,M Vinyl chloride
7 T,M Bromomethane
8 T,M Chloroethane
9 T,M Dichlorofluoromethane
10 T,M Trichlorofluoromethane
11 T,M Acrolein
12 T,M l,l /2-Trichloro-1,2 /2-trifl
13 T,M Acetone
14 C,T,M l,l-Dichloroethene
15 T,M tert-Butyl alcohol
16 T,M Iodomethane
17 T,M Methyl acetate
18 T,M Methylene chloride
19 T,M Carbon disulfide
20 T,M Acrylonitrile
21 T,M tert-Butyl methyl ether (MT
22 T,M trans-1,2-Dichloroethene
23 T,M Isopropyl ether (DIPE)
24 T,M Vinyl acetate
25 P/T/M 1 /1-Dichloroethane
26 T,M 2-Butanol
27 T,M tert-Butyl ethyl ether (ETB
28 T,M 2-Butanone
29 T,M 2,2-Dichloropropane
30 T,M cis-1 /2-Dichloroethene
31 C,T,M Chloroform
32 T,M Bromochloromethane
33 T,M Tetrahydrofuran
34 S Dibromofluoromethane
35 T,M l,l,l-Trichloroethane
36 T,M Cyclohexane
37 T,M 2,2 /4-Trimethylpentane
38 T,M l,l-Dichloropropene
39 T,M Carbon tetrachloride
40 T,M tert-Amyl methyl ether (TAM
41 S 1 /2-Dichloroethane-d4
Amount Calc.
10.000 10.000
-l.000 0.000
10.000 10.745
-1.000 0.000
10.000 10.??1
10.000 11.092
10.000 9.887
10.000 9.929
10.000 9.809
10.000 10.405
50.000 46.638
10.000 10.700
50.000 46.249
10.000 10.535
250.000 272.707
10.000 10.129
10.000 9.648
10.000 10.396
10.000 9.411
50.000 49.767
10.000 10.216
10.000 10.335
10.000 10.407
10.000 10.436
10.000 10.386
250.000 0.000
10.000 10.658
50.000 52.384
10.000 10.370
10.000 10.325
10.000 9.821
10.000 10.539
10.000 10.289
10.000 9.898
10.000 10.374
10.000 10.549
10.000 0.000
10.000 10.277
10.000 10.352
10.000 10.128
10.000 9.949
%Dev Area% Dev(min)
0.0
0.0
-7.4
0.0
-2.2
-10.9
l.1
0.7
l.9
-4.0
6.7
-7.0
7.5
-5.4
-9.1
-l. 3
3.5
-4.0
5.9
0.5
-2.2
-3.4
-4.1
-4.4
-3.9
100.0#
-6.6
-4.8
-3.7
-3.2
l.8
-5.4
-2.9
l.0
-3.7
-5.5
100.0#
-2.8
-3.5
-l. 3
0.5
99
o
112
o
109
110
110
105
107
109
104
106
108
108
118
105
113
110
99
107
112
110
110
113
109
o
114
109
108
107
107
112
121
107
108
114
o
108
107
113
112
0.00
-2.08#
0.00
-2.53#
0.02
0.00
0.01
0.01
0.01
0.00
0.00
0.01
0.00
0.01
0.00
0.00
0.00
0.00
0.02
0.00
0.00
0.00
-0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-0.01
(#) = Out of Range
REV210.D V001E11.M
? ,/L 'j)J-f
Mon May 13 14:38:09 2024~~\~ , Page 1
REPORT ID: 24E186 Page 109 of 217
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24E13\REV210.D
Acq On 13 May 2024 12:06 pm
Sample IV001E1102 1.0/5.0
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
2
LPriet
01
1. 00
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Min. RRF
Max. RRF Dev
Mon May 13 13:20:11 2024
Multiple Level Calibration
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
42 T,M Benzene
43 T,M l,2-Dichloroethane
44 T,M Trichloroethene
45 T,M Methylcyclohexane
46 C,T,M l,2-Dichloropropane
47 T,M Bromodichloromethane
48 T,M l,4-Dioxane
49 T,M Dibromomethane
50 T,M 2-Chloroethyl vinyl ether
51 T,M 4-Methyl-2-pentanone
52 T,M cis-1,3-Dichloropropene
53 I CHLOROBENZENE-D5
54 S Toluene-d8
55 C,T,M Toluene
56 T,M Ethyl methacrylate
57 T,M trans-1,3-Dichloropropene
58 T,M l,l,2-Trichloroethane
59 T,M 2-Hexanone
60 T,M l,3-Dichloropropane
61 T,M Tetrachloroethene
62 T,M Dibromochloromethane
63 T,M l,2-Dibromoethane
64 T,M 1-Chlorohexane
65 P,M Chlorobenzene
66 T,M l,l,l,2-Tetrachloroethane
67 C,T,M Ethylbenzene
68 T,M m-Xylene & p-Xylene
69 T,M o-Xylene
70 T,M Styrene
71 T,M Isopropylbenzene
72 I l,2-DICHLOROBENZENE-D4
73 P,T,M Bromoform
74 T,M trans-l,4-Dichloro-2-butene
75 T,M l,l,2,2-Tetrachloroethane
76 S 4-Bromofluorobenzene
77 T,M l,2,3-Trichloropropane
78 T,M n-Propylbenzene
79 T,M Bromobenzene
80 T,M l,3,5-Trimethylbenzene
10.000
10.000
10.000
10.000
10.000
10.000
200.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
20.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.090
10.337
10.150
10.260
10.115
9.863
205.359
10.345
10.212
49.033
10.274
10.000
9.567
9.907
10.214
10.299
10.145
47.365
10.169
9.999
10.064
10.349
10.260
10.062
10.136
9.991
20.234
9.950
9.968
10.037
10.000
9.781
10.277
9.918
9.430
10.138
9.837
9.996
9.884
-0.9
-3.4
-1. 5
-2.6
-1. 2
1.4
-2.7
-3.5
-2.1
1.9
-2.7
0.0
4.3
0.9
-2.1
-3.0
-1.4
5.3
-1. 7
0.0
-0.6
-3.5
-2.6
-0.6
-1.4
0.1
-1. 2
0.5
0.3
-0.4
0.0
2.2
-2.8
0.8
5.7
-1. 4
1.6
0.0
1.2
106
110
103
113
107
109
114
114
110
111
109
102
105
106
113
111
111
113
112
105
112
113
108
106
108
104
107
107
106
105
102
117
116
114
107
111
104
107
105
(#) = Out of Range
REV210. D V001E11. M Mon May 13 14: 38: 10 2024 ?5-\\5' (J..Lf
0.00
0.00
0.00
-0.01
0.00
-0.01
-0.01
0.00
-0.01
0.00
0.00
0.00
-0.01
-0.01
-0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-0.01
0.00
0.00
0.00
-0.01
0.00
-0.01
0.00
0.00
0.00
-0.01
-0.01
0.00
0.00
0.00
0.00
Page 2
REPORT ID: 24E186 Page 110 of 217
81
82
83
84
85
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87
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89
90
91
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94
95
96
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24E13\REV210.D
Acq On 13 May 2024 12:06 pm
Sample IV001E1102 1.0/5.0
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
2
LPriet
01
1. 00
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
T,M 2-Chlorotoluene 10.000 10.006 -0.1 107 0.00
T,M 4-Chlorotoluene 10.000 10.003 -0.0 105 0.00
T,M tert-Butylbenzene 10.000 9.950 0.5 105 0.00
T,M 1,2,4-Trimethylbenzene 10.000 9.901 1.0 104 -0.01
T,M sec-Butylbenzene 10.000 9.967 0.3 105 0.00
T,M p-Isopropyltoluene 10.000 9.795 2.1 104 0.00
T,M 1,3-Dichlorobenzene 10.000 10.012 -0.1 107 0.00
T,M 1, 2, 3-Trimethylbenzene 10.000 9.932 0.7 107 0.00
T,M 1,4-Dichlorobenzene 10.000 9.895 1.1 106 0.00
T,M n-Butylbenzene 10.000 9.925 0.7 105 0.00
T,M 1,2-Dichlorobenzene 10.000 9.987 0.1 109 -0.01
T,M 1,2-Dibromo-3-chloropropane 10.000 9.353 6.5 117 0.00
T,M 1,2,4-Trichlorobenzene 10.000 10.081 -0.8 109 0.00
T,M Hexachlorobutadiene 10.000 9.945 0.5 102 0.00
T,M Naphthalene 10.000 10.202 -2.0 113 0.00
T,M 1, 2, 3-Trichlorobenzene 10.000 10.141 -1.4 110 0.00
(#) = Out of Range
REV210.D V001E11.M
SPCC's out = 0 CCC's out = 0
Mon May 13 14: 38: 11 2024 ? (/\ 5\ \5(~4-Page 3
REPORT ID: 24E186 Page 111 of 217
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24E13\REV210.D
Acq On 13 May 2024 12:06 pm
Sample IV001E1102 1.0/5.0
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
2
LPriet
01
1. 00
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
1 I 1,4-DIFLUOROBENZENE
2 T,M Chlorotrifluoroethylene
3 T,M Dichlorodifluoromethane
4 T,M 2-Chloro-1,1,1-trifluoroeth
5 P,T,M Chloromethane
6 C,T,M Vinyl chloride
7 T,M Bromomethane
8 T,M Chloroethane
9 T,M Dichlorofluoromethane
10 T,M Trichlorofluoromethane
11 T,M Acrolein
12 T,M l,l,2-Trichloro-1,2,2-trifl
13 T,M Acetone
14 C,T,M 1,1-Dichloroethene
15 T,M tert-Butyl alcohol
16 T,M Iodomethane
17 T,M Methyl acetate
18 T,M Methylene chloride
19 T,M Carbon disulfide
20 T,M Acrylonitrile
21 T,M tert-Butyl methyl ether (MT
22 T,M trans-1,2-Dichloroethene
23 T,M Isopropyl ether (DIPE)
24 T,M Vinyl acetate
25 P,T,M 1,1-Dichloroethane
26 T,M 2-Butanol
27 T,M tert-Butyl ethyl ether (ETB
28 T,M 2-Butanone
29 T,M 2,2-Dichloropropane
30 T,M cis-1,2-Dichloroethene
31 C,T,M Chloroform
32 T,M Bromochloromethane
33 T,M Tetrahydrofuran
34 S Dibromofluoromethane
35 T,M l,l,l-Trichloroethane
36 T,M Cyclohexane
37 T,M 2,2,4-Trimethylpentane
38 T,M 1,1-Dichloropropene
39 T,M Carbon tetrachloride
40 T,M tert-Amyl methyl ether (TAM
41 S 1,2-Dichloroethane-d4
AvgRF CCRF
1. 000 1. 000
0.000 0.000
0.268 0.288
0.000 0.000
0.375!' 0.383
0.312 0.346
0.396 0.366
0.226 0.225
0.643 0.631
0.422 0.439
0.022 0.021
0.211 0.226
0.037 0.034
0.533 0.562
0.011 0.012
0.572 0.579
0.100 0.096
0.428 0.445
1.140 1. 073
0.046 0.046
0.525 0.536
0.514 0.531
1. 098 1.143
0.377 0.393
o . 601 /' 0.624
0.000 0.010
0.787 0.838
0.056 0.059
0.505 0.524
0.414 0.427
0.612 0.601
0.240 0.253
0.035 0.036
0.310 0.306
0.512 0.531
0.499 0.526
0.000 0.032
0.174 0.179
0.382 0.395
0.612 0.620
0.211 0.210
(#) = Out of Range
REV210.D V001E11.M Mon May 13 14:38:15 2024
%Dev Area% Dev(min)
0.0
0.0
-7.5
0.0
-2.1
-10.9
7.6
0.4
1.9
-4.0
4.5
-7.1
8.1
-5.4
-9.1
-1.2
4.0
-4.0
5.9
0.0
-2.1
-3.3
-4.1
-4.2
-3.8
0.0
-6.5
-5.4
-3.8
-3.1
1.8
-5.4
-2.9
1.3
-3.7
-5.4
0.0
-2.9
-3.4
-1.3
0.5
99
0#
112
0#
109
110
110
105
107
109
104
106
108
108
118
105
113
110
99
107
112
110
110
113
109
0#
114
109
108
107
107
112
121
107
108
114
0#
108
107
113
112
0.00
-2.08#
0.00
-2.53#
0.02
0.00
0.01
0.01
0.01
0.00
0.00
0.01
0.00
0.01
0.00
0.00
0.00
0.00
0.02
0.00
0.00
0.00
-0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-0.01
Page 1
REPORT ID: 24E186 Page 112 of 217
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24E13\REV210.D
Acq On 13 May 2024 12:06 pm
Sample IV001E1102 1.0/5.0
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
2
LPriet
01
1. 00
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
42 T,M Benzene
43 T,M 1,2-Dichloroethane
44 T,M Trichloroethene
45 T,M Methylcyclohexane
46 C,T,M 1,2-Dichloropropane
47 T,M Bromodichloromethane
48 T,M 1,4-Dioxane
49 T,M Dibromomethane
50 T,M 2-Chloroethyl vinyl ether
51 T,M 4-Methyl-2-pentanone
52 T,M cis-1,3-Dichloropropene
53 I CHLOROBENZENE-D5
54 S Toluene-d8
55 C,T,M Toluene
56 T,M Ethyl methacrylate
57 T,M trans-1,3-Dichloropropene
58 T,M 1,1,2-Trichloroethane
59 T,M 2-Hexanone
60 T,M 1,3-Dichloropropane
61 T,M Tetrachloroethene
62 T,M Dibromochloromethane
63 T,M 1,2-Dibromoethane
64 T,M 1-Chlorohexane
65 P,M Chlorobenzene
66 T,M 1,1,1,2-Tetrachloroethane
67 C,T,M Ethylbenzene
68 T,M m-Xylene & p-Xylene
69 T,M o-Xylene
70 T,M Styrene
71 T,M Isopropylbenzene
72 I 1,2-DICHLOROBENZENE-D4
73 P,T,M Bromoform
74 T,M trans-1,4-Dichloro-2-butene
75 T,M 1,1,2,2-Tetrachloroethane
76 S 4-Bromofluorobenzene
77 T,M 1,2,3-Trichloropropane
78 T,M n-Propylbenzene
79 T,M Bromobenzene
80 T,M 1,3,5-Trimethylbenzene
AvgRF
1.336
0.269
0.346
0.549
0.299
0.415
0.001
0.141
0.076
0.136
0.465
1. 000
1.499
1.776
0.266
0.413
0.233
0.090
0.395
0.369
0.284
0.230
0.767
1.059
0.326 ,A
2.027
1.484
1.527
1.184
2.012
1.000
0.350/
0.173
0.666
1.362 ./
0.170
6.502
1.029
4.155
CCRF
1. 348
0.279
0.351
0.563
0.302
0.409
0.001
0.146
0.077
0.145
0.478
1. 000
1.434
1.759
0.272
0.425
0.236
0.100
0.401
0.369
0.286
0.238
0.787
1.065
0.331
2.025
1. 501
1.519
1.180
2.019
1. 000
0.386
0.177
0.660
1. 284
0.173
6.396
1.028
4.106
(#) = Out of Range '
REV210.D V001E11.M Mon May 13 14:38:18 2024
%Dev Area% Dev(min)
-0.9
-3.7
-1.4
-2.6
-1. 0
1.4
0.0
-3.5
-1. 3
-6.6
-2.8
0.0
4.3
1.0
-2.3
-2.9
-1. 3
-11.1
-1.5
0.0
-0.7
-3.5
-2.6
-0.6
-1. 5
0.1
-1.1
0.5
0.3
-0.3
0.0
-10.3
-2.3
0.9
5.7
-1. 8
1.6
0.1
1.2
106
110
103
113
107
109
114
114
110
111
109
102
105
106
113
111
111
113
112
105
112
113
108
106
108
104
107
107
106
105
102
117
116
114
107
111
104
107
105
0.00
0.00
0.00
-0.01
0.00
-0.01
-0.01
0.00
-0.01
0.00
0.00
0.00
-0.01
-0.01
-0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-0.01
0.00
0.00
0.00
-0.01
0.00
-0.01
0.00
0.00
0.00
-0.01
-0.01
0.00
0.00
0.00
0.00
Page 2
REPORT ID: 24E186 Page 113 of 217
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24E13\REV210.D
Aeq On 13 May 2024 12:06 pm
Sample IV001E1102 1.0/5.0
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
2
LPriet
01
1. 00
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound AvgRF CCRF %Dev Area% Dev(min)
T,M 2-Chlorotoluene 3.915 3.917 -0.1 107 0.00
T,M 4-Chlorotoluene 3.466 3.467 -0.0 105 0.00
T,M tert-Butylbenzene 0.871 0.867 0.5 105 0.00
T,M 1, 2, 4-Trimethylbenzene 4.065 4.025 1.0 104 -0.01
T,M see-Butylbenzene 5.711 5.692 0.3 105 0.00
T,M p-Isopropyltoluene 4.403 4.312 2.1 104 0.00
T,M l,3-Diehlorobenzene 1.955 1.957 -0.1 107 0.00
T,M l,2,3-Trimethylbenzene 3.795 3.769 0.7 107 0.00
T,M l,4-Diehlorobenzene 1.916 1. 896 1.0 106 0.00
T,M n-Butylbenzene 4.560 4.526 0.7 105 0.00
T,M l,2-Diehlorobenzene 1.602 1.600 0.1 109 -0.01
T,M l,2-Dibromo-3-ehloropropane 0.095 0.095 0.0 117 0.00
T,M l,2,4-Triehlorobenzene 1.169 1.179 -0.9 109 0.00
T,M Hexaehlorobutadiene 0.697 0.693 0.6 102 0.00
T,M Naphthalene 1. 365 1. 392 -2.0 113 0.00
T,M l,2,3-Triehlorobenzene 0.881 0.893 -1.4 110 0.00
------------------------------------------------------~~--~~~/~~---
(#) = Out of Range
REV210.D V001E11.M
SPCC's out = 0 CCC's out = 0
Mon May 13 14:38:19 2024 Page 3
REPORT ID: 24E186 Page 114 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E13\REV210.D
Acq On 13 May 2024 12:06 pm
Sample IV001E1102 1.0/5.0
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
2
LPriet
01
1. 00
Quant Time: May 13 13:24 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAcq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE 8.55 114 907856 10.00 ug/l 0.00
53) CHLOROBENZENE-D5 13.72 117 757489 10.00 ug/l 0.00
72) l,2-DICHLOROBENZENE-D4 18.68 152 290545 10.00 ug/l 0.00
System Monitoring Compounds
34) Dibromofluoromethane 7.23 111 278148 9.90 ug/l 0.00
Spiked Amount 10.000 Recovery = 99.00%
41) l,2-Dichloroethane-d4 7.95 65 190681 9.95 ug/l -0.01
Spiked Amount 10.000 Recovery = 99.50%
54) Toluene-d8 11.02 98 1085971 9.57 ug/l -0.01
Spiked Amount 10.000 Recovery = 95.70%
76) 4-Bromofluorobenzene 16.00 95 373151 9.43 ug/l -0.01
Spiked Amount 10.000 Recovery = 94.30%
Target Compounds Qvalue
3) Dichlorodifluoromethane 2.17 85 261017 10.74 ug/l 99
5) Chloromethane 2.49 50 347692 10.22 ug/l 99
6) Vinyl chloride 2.62 62 314201 11. 09 ug/l 99
7) Bromomethane 3.15 94 332015 9.89 ug/l 99
8) Chloroethane 3.20 64 204024 9.93 ug/l 98
9) Dichlorofluoromethane 3.29 67 572473 9.81 ug/l 97
10) Trichlorofluoromethane 3.55 101 398783 10.41 ug/l 99
11) Acrolein 3.98 56 95103 46.64 ug/l 99
12) l,l,2-Trichloro-1,2,2-trif 4.07 151 204924 10.70 ug/l 100
13) Acetone 4.06 43 153258 46.25 ug/l 100
14) l,l-Dichloroethene 4.24 " 61 510086 10.53 ug/l 99
15) tert-Butyl alcohol 4.34 59 275606 272.71 ug/l 99
16) Iodomethane 4.64 142 525854 10.13 ug/l 100
17) Methyl acetate 4.65 43 87177 9.65 ug/l 97
18) Methylene chloride 4.86 49 403861 10.40 ug/l 98
19) Carbon disulfide 4.89 76 974363 9.41 ug/l 99
20 ) Acrylonitrile 5.02 53 209223 49.77 ug/l 100
21) tert-Butyl methyl ether (M 5.07 73 486511 10.22 ug/l 100
22) trans-1,2-Dichloroethene 5.24 61 482107 10.33 ug/l 98
23) Isopropyl ether (DIPE) 5.66 45 1037346 10.41 ug/l 98
24) Vinyl acetate 5.82 43 357100 10.44 ug/l 99
25) l,l-Dichloroethane 5.82 ; 63 566566 10.39 ug/l 100
27) tert-Butyl ethyl ether (ET 6.24 59 761232 10.66 ug/l 100
28 ) 2-Butanone 6.41 43 266366 52.38 ug/l 100
29) 2,2-Dichloropropane 6.62 77 475647 10.37 ug/l 100
30 ) cis-1,2-Dichloroethene 6.68 .( 96 387725 10.33 ug/l 99
31) Chloroform 6.90 83 545984 9.82 ug/l 99
-------------------------------------------------------------------------
(# ) = qualifier out of range (m) = manual integration ~~ :J(V5j~age 1 REV210.D V001E11.M Mon May 13 14:38:25 2024
~ REPORT ID: 24E186 Page 115 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E13\REV210.D
Acq On 13 May 2024 12:06 pm
Sample IV001E1102 1.0/5.0
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
2
LPriet
01
1. 00
Quant Time: May 13 13:24 2024 Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Conc Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) l,l,l-Trichloroethane
36) Cyclohexane
38) l,l-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) Benzene
43) l,2-Dichloroethane
44) Trichloroethene
45) Methylcyclohexane
46) l,2-Dichloropropane
47) Bromodichloromethane
48) l,4-Dioxane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) l,l,2-Trichloroethane
59) 2-Hexanone
60) l,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
63) l,2-Dibromoethane
64) 1-Chlorohexane
65) Chlorobenzene
66) l,l,l,2-Tetrachloroethane
67) Ethylbenzene
68) m-Xylene & p-Xylene
69) o-Xylene
70) Styrene
71) Isopropylbenzene
73) Bromoform
74) trans-1,4-Dichloro-2-buten
75) l,l,2,2-Tetrachloroethane
77) l,2,3-Trichloropropane
78) n-Propylbenzene
79) Bromobenzene
7.14
7.20
7.49
7.52
7.72
7.88
7.88
8.13
8.10
9.06
9.15
9.35
9.72
9.78
9.82
49
42
97
84
110
119
, 73
/78
62
130
83
63
83
88
93
63
43
" 75
91
69
< 75
97
43
76
164
129
107
10.22
10.26
10.62
11.15
11. 45
11.48
11.75
11. 76
12.19
12.29
12.66
13.03
13.30
13.78
13.86
13.88
14.01
14.83
14.90
15.51
15.55
15.63
15.85
16.15
16.29 I
16.38
[ 91
112
131
, 91
/ 91
/ 91
104
105
173
53
83
110
91
156
230106
33093
482510
477860
162485
358693
562793
1223803
252838
318416
511326
274499
371496
22815
132415
70329
657246
433879
1332719
206172
322019
178678
378200
304011
279605
216381
180319
595972
806907
250367
1533890
2274121
1150973
893787
1529556
112241
51511
191835
50167
1858212
298744
10.54 ug/l
10.29 ug/l
10.37 ug/l
10.55 ug/l
10.28 ug/l
10.35 ug/l
10.13 ug/l
10.09 ug/l
10.34 ug/l
10.15 ug/l
10.26 ug/l
10.12 ug/l
9.86 ug/l
205.36 ug/l
10.34 ug/l
10.21 ug/l
49.03 ug/l
10.27 ug/l
9.91 ug/l
10.21 ug/l
10.30 ug/l
10.15 ug/l
47.36 ug/l
10.17 ug/l
10.00 ug/l
10.06 ug/l
10.35 ug/l
10.26 ug/l
10.06 ug/l
10.14 ug/l
9.99 ug/l
20.23 ug/l
9.95 ug/l
9.97 ug/l
10.04 ug/l
9.78 ug/l
10.28 ug/l
9.92 ug/l
10.14 ug/l
9.84 ug/l
10.00 ug/l
Qvalue
98
97
100
100
99
99
100
100
99
98
99
99
99
99
98
99
100
100
100
98
99
99
100
100
99
100
99
100
100
98
100
100
100
100
100
97
100
98
97
100
99
(#) = qualifier out of range (m) = manual integration
REV210.D V001E11.M Mon May 13 14:38:26 2024 ~ ~15/tf...Lf Page 2
REPORT ID: 24E186 Page 116 of 217
Quantitation Report
Data File. D:\HPCHEM\1\DATA\24E13\REV210.D
Aeq On 13 May 2024 12:06 pm
Sample IV001E1102 1.0/5.0
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
2
LPriet
01
1.00
Quant Time: May 13 13:24 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Cone Unit
80 ) 1, 3, 5-Trimethylbenzene 16.61 'lOS 1193060 9.88 ug/l
81) 2-Chlorotoluene 16.63 ' 91 1138017 10.01 ug/l
82) 4-Chlorotoluene 16.72 , 91 1007192 10.00 ug/l
83) tert-Butylbenzene 17.29 134 251948 9.95 ug/l
84) 1,2,4-Trimethylbenzene 17.35 -105 1169308 9.90 ug/l
85) see-Butylbenzene 17.66 ' 105 1653826 9.97 ug/l
86) p-Isopropyltoluene 17.88 119 1252965 9.80 ug/l
87) 1,3-Diehlorobenzene 18.03 / 146 568580 10.01 ug/l
88) 1, 2, 3-Trimethylbenzene 18.13 105 1095079 9.93 ug/l
89) 1,4-Diehlorobenzene 18.19 ( 146 550958 9.89 ug/l
90 ) n-Butylbenzene 18.49 91 1315009 9.93 ug/l
91) 1,2-Diehlorobenzene 18.71 (146 464758 9.99 ug/l
92) 1,2-Dibromo-3-ehloropropan 19.72 157 27714 9.35 ug/l
93) 1,2,4-Triehlorobenzene 20.80 ( 180 342507 10.08 ug/l
94) Hexaehlorobutadiene 20.96 225 201295 9.94 ug/l
95) Naphthalene 21.14 128 404546 10.20 ug/l
96) 1, 2, 3-Triehlorobenzene 21.46 180 259547 10.14 ug/l
Qvalue
99
100
100
98
99
100
100
100
99
100
100
99
99
99
98
100
99
-----------------------------------------------------~~-~l~~~~!----
(#) = qualifier out of range (m) = manual integration
REV210.D V001E11.M Mon May 13 14:38:26 2024 Page 3
REPORT ID: 24E186 Page 117 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E13\REV210.D
Aeq On 13 May 2024 12:06 pm
Sample IV001E1102 1.0/5.0
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
2
LPriet
01
1. 00
Quant Time: May 13 13:24 2024 Quant Results File: V001E11.RES
Method
Title
Last Update
Response via
bundance
2100000
2000000
1900000
1800000
1700000
1600000
1500000
1400000
1300000
1200000
1100000
1000000
900000
800000
700000
600000
500000
400000
300000
200000
100000
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
I I' iii I" iiI' i, i I \ I i I I' Iii I I I I ,
10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.0020.0021.00
REV210.D V001E11.M Mon May 13 14:38:29 2024 ~'fA ~51 t~/aJ{ Page 4
REPORT ID: 24E186 Page 118 of 217
DAILY CALIBRATIONS
REPORT ID: 24E186 Page 119 of 217
FORM 5
VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK
BROMOFLUOROBENZENE (BFB)
Lab Name: EMAX Laboratories. Inc.
Lab Code : EMAX
Lab File ID: REV528
Instrument ID: 01
Project : TEAD· N
SDG No : 24E186
BFB Injection Date: OS/29/24
BFB Injection Time: 10:14
1 1 1 % RELATIVE 1
1 m/e 1 ION ABUNDANCE CRITERIA 1 ABUNDANCE 1
1=1 1 1
1 50 1 15 . 40% of mass 95 1 18.206 1
1 75 1 30 . 60% of mass 95 1 43.380 1
1 95 1 Base Peak,' 100% relative abundance __ 1 100.000 1
1 ·96 1 5 . 9% of mass 95 1 6.078 1
1 173 1 Less than 2% of mass 174 1 0.000(0)1 1
1 174 1 Greater than 50% of mass 95 1 82.431 1
1 175 1 5 . 9% of mass 174 1 5.750(6.98)1 1
1 176 1 95 . 101% % of mass 174 1 79.271(96.17)1 1
1 177 1 5 . 9% % of mass 176 1 5.417(6.83)2 1
1 ____ 1 1 1
l·Value is % mass 174 2·Value is % mass 176
This check applies to the following samples. Lab QCs and Standards:
1 EPA 1 LAB 1 LAB 1 DATE 1 TIME 1
1 SAMPLE NO. 1 SAMPLE ID 1 FI LE ID 1 ANALYZED 1 ANALYZED 1
1=======1====1===1 1 1
11VSTDlO ICV001E1113 IREV530 1 OS/29/24 1 11:25 1
21 LCS1W IV001E25L IREV531 1 OS/29/24 1 11:54 1
31 LCD1W 1 V001E25C 1 REV532 1 OS/29/24 1 13: 01 1
41 MBLK1W 1 V001E25Q 1 REV536 1 OS/29/24 1 15: 03 1
51TB20240523 1 24E186·03 IREV538 1 OS/29/24 1 16:02 1
6ITEAD-05-24·S·WIN9569 124E186·01 IREV543 1 OS/29/24 1 18:31 1
71 VSTD10 1 EV001E1l13 1 REV550 1 OS/29/24 1 21: 55 1
1 1 1 1 1 1
REPORT ID: 24E186 Page 120 of 217
FORM 8
VOLATILE INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY
lab Name: EMAX laboratories. Inc.
lab Code: EMAX
lab File ID: REV201
Instrument ID: 01
1 INTERNAL STANDARD (IS)
1
1
1 12 HOUR STD
1 UPPER LIMIT
1 lOWER LIMIT
1
1
1
11VSTD10
21 lCS1W
31 lCDlW
41MBlK1W
51 TB20240523
61 TEAD· 05· 24·S·WIN9569
71VSTD10
1
1.4· DI FlUOROBENZENE
Area # 1
1
920983 1
1841966 1
460492 1
1
Area # 1
1
847951 1
832746 1
788526 1
824228 I
821097 I
855624 1
717198 1
1
Area Upper limit = +100% of ICAl Midpoint IS Area
Area lower limit = ·50% of ICAl Midpoint IS Area
1 CHlOROBENZENE· D5
RT #1 Area # 1
1 1
8.54 1 742213 1
8.71 I 1484426 1
8.37 I 371107 1
I 1
RT # I Area # 1
1 1
8.54 1 725980 1
8.55 1 690880 I
8.55 1 677822 1
8.55 1 670629 1
8.54 1 670477 1
8.54 I 708676 1
8.55 I 616471 1
1 I
Retention Time(RT) Upper limit = +10 seconds of ICAl Midpoint IS RT
Retention Time(RT) lower limit = ·10 seconds of ICAl Midpoint IS RT
1
RT #1
1
13.71 1
13.88 1
13.54 1
1
RT # I
1
13.70 1
13.70 1
13.70 1
13.71 1
13.71 I
13.71 1
13.70 1
1
Project: TEAD· N
SDG No: 24E186
Date Analyzed: 05/11/24
Time Analyzed: 13:28
1.2·DICHlOROBENZENE·D4 1
Area # 1 RT #1
1 1
284055 1 18.68 1
568110 1 18.85 1
142028 1 18.51 1
1 1
Area # 1 RT # 1
I I
301910 1 18.67 1
278386 1 18.67 1
292730 1 18.67 1
285230 1 18.67 1
276329 1 18.67 1
295180 1 18.67 1
254988 1 18.67 1
1 1
REPORT ID: 24E186 Page 121 of 217
BFB
Data File D:\HPCHEM\1\DATA\24E29\REV528.D
Acq On 29 May 2024 10:14 am
Sample BFB01E25
Misc T/CHK
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
1
LPriet
01
1. 00
Method D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
Title : METHOD 8260 25mls
20000
15000
10000
5000
ime->
bundance
20000
174
15000
10000 75
5000 50
Iz-->
AutoFind: Scans 978, 979, 980; Background Corrected with Scan 971
I Target I ReI. to I Lower I Upper I
Mass Mass Limit% Limit%
ReI.
Abn%
Raw
Abn I
Result
Pass/Fail
----------------------------------------------------------------------
50 95 15 40 18.2/ 3768 PASS
75 95 30 60 43.4/ 8978 PASS
95 95 100 100 100.0 20696 PASS
96 95 5 9 6.1,/' 1258 PASS
173 174 0.00 2 0.0 0 PASS
174 95 50 100 82.4 17060 PASS
175 174 5 9 7.0 / 1190 PASS
176 174 95 101 96.2' 16406 PASS
177 176 5 9 6.8/ 1121 PASS
REV528.D V001E11.M Thu Jun 13 14:39:16 2024
REPORT ID: 24E186 Page 122 of 217
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24E29\REV530.D
Acq On 29 May 2024 11:25 am
Sample CV001Ell13
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
3
LPriet
01
1. 00
Method
Title
D:\HPCHEM\1\METHODS\V001Ell.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon ~aYI 13 13:20:1~ 202~ ~
MultlP e Level Callbratl0n
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
5U% Max. R.T. Dev 0.16min
200%
Compound
I l,4-DIFLUOROBENZENE
T,M Chlorotrifluoroethylene
T,M Dichlorodifluoromethane
T,M 2-Chloro-1,l,l-trifluoroeth
P,T,M Chloromethane
C,T,M Vinyl chloride
T,M Bromomethane
T,M Chloroethane
T,M Dichlorofluoromethane
T,M Trichlorofluoromethane
T,M Acrolein
T,M l,l,2-Trichloro-1,2,2-trifl
T,M Acetone
C,T,M l,l-Dichloroethene
T,M tert-Butyl alcohol
T,M Iodomethane
T,M Methyl acetate
T,M Methylene chloride
T,M Carbon disulfide
T,M Acrylonitrile
T,M tert-Butyl methyl ether (MT
T,M trans-1,2-Dichloroethene
T,M Isopropyl ether (DIPE)
T,M Vinyl acetate
P,T,M l,l-Dichloroethane
T,M 2-Butanol
T,M tert-Butyl ethyl ether (ETB
T,M 2-Butanone
T,M 2,2-Dichloropropane
T,M cis-1,2-Dichloroethene
C,T,M Chloroform
T,M Bromochloromethane
T,M Tetrahydrofuran
S Dibromofluoromethane
T,M l,l,l-Trichloroethane
T,M Cyclohexane
T,M 2,2,4-Trimethylpentane
T,M l,l-Dichloropropene
T,M Carbon tetrachloride
T,M tert-Amyl methyl ether (TAM
S l,2-Dichloroethane-d4
Amount Calc.
10.000 10.000
-1.000 0.000
10.000 8.880
-1.000 0.000
10.000 8.094
10.000 9.010,....,
10.000 8.530
10.000 8.426
10.000 10.643
10.000 9.822
50.000 43.776
10.000 10.466
50.000 56.582
10.000 9.131 ~
250.000 279.576
10.000 10.738
10.000 14.023
10.000 9.971
10.000 10.131
50.000 51.524
10.000 10.511
10.000 9.450
10.000 10.497
10.000 9.900
10.000 9.711
250.000 0.000
10.000 9.861
50.000 55.888
10.000 9.628
10.000 9.596
10.000 10.212 /"
10.000 10.079
10.000 9.734
10.000 10.569
10.000 10.451
10.000 10.353
10.000 0.000
10.000 9.386
10.000 10.449
10.000 9.867
10.000 10.869
%Dev Area% Dev(min)
0.0
0.0
11. 2
0.0
19.1
9.9
14.7
15.7
-6.4
1.8
12.4
-4.7
-13.2
8.7
-11. 8
-7.4
-40.2#
0.3
-1. 3
-3.0
-5.1
5.5
-5.0
1.0
2.9
100.0#
1.4
-11.8
3.7
4.0
-2.1
-0.8
2.7
-5.7
-4.5
-3.5
100.0#
6.1
-4.5
1.3
-8.7
92
o
86
o
80
83
89
83
108
96
91
97
123
87
113
104
153
98
100
103
107
94
103
100
95
o
99
108
94
93
104
100
106
107
102
105
o
92
101
103
114
0.00
-2.08#
0.01
-2.53#
0.01
0.00
0.02
0.02
0.00
0.00
-0.01
0.02
-0.01
0.00
-0.01
0.00
-0.01
-0.01
0.00
-0.01
-0.01
-0.01
-0.02
-0.01
0.00
0.06
-0.02
-0.02
0.00
-0.02
-0.02
0.00
-0.02
-0.02
-0.02
-0.02
-0.02
-0.02
-0.02
0.00
-0.02
(#) = Out of Range
REV530.D V001E11.M Thu Jun 13 14:39:33 2024 Page 1
REPORT ID: 24E186 Page 123 of 217
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24E29\REV530.D
Acq On 29 May 2024 11:25 am
Sample CV001Ell13
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
3
LPriet
01
1.00
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
42 T,M Benzene 10.000 9.471 5.3 93 -0.02
43 T,M l,2-Dichloroethane 10.000 11.177 -11. 8 111 -0.02
44 T,M Trichloroethene 10.000 10.028 -0.3 95 0.00
45 T,M Methylcyclohexane 10.000 10.881 -8.8 112 -0.01
46 C,T,M l,2-Dichloropropane 10.000 9.650 3.5 95 -0.01
47 T,M Bromodichloromethane 10.000 10.230 / -2.3 105 -0.02
48 T,M l,4-Dioxane 200.000 197.952 1.0 102 -0.03
49 T,M Dibromomethane 10.000 10.877 -8.8 112 -0.02
50 T,M 2-Chloroethyl vinyl ether 10.000 14.251 -42.5# 143 -0.02
51 T,M 4-Methyl-2-pentanone 50.000 55.245 -10.5 118 -0.01
52 T,M cis-1,3-Dichloropropene 10.000 10.070 -0.7 100 -0.02
53 I CHLOROBENZENE-D5 10.000 10.000 0.0 98 -0.02
54 S Toluene-d8 10.000 9.380 6.2 99 -0.02
55 C,T,M Toluene 10.000 8.986 10.1 92 -0.02
56 T,M Ethyl methacrylate 10.000 10.317 -./ -3.2 109 -0.01
57 T,M trans-1,3-Dichloropropene 10.000 9.826 1.7 102 -0.02
58 T,M l,l,2-Trichloroethane 10.000 9.813 1.9 103 -0.02
59 T,M 2-Hexanone 50.000 51.967 -3.9 120 0.00
60 T,M l,3-Dichloropropane 10.000 10.127 -1.3 107 -0.02
61 T,M Tetrachloroethene 10.000 9.642 3.6 97 0.00
62 T,M Dibromochloromethane 10.000 10.117 -1. 2 108 -0.02
63 T,M l,2-Dibromoethane 10.000 9.892 1.1 104 -0.02
64 T,M 1-Chlorohexane 10.000 9.108 8.9 92 0.00
65 P,M Chlorobenzene 10.000 9.387 6.1 95 -0.02
66 T,M 1, 1, 1, 2-Tetrachloroethane 10.000 9.742 . 2.6 99 -0.02
67 C,T,M Ethylbenzene 10.000 9.261/ 7.4 92 -0.02
68 T,M m-Xylene & p-Xylene 20.000 19.198 4.0 97 0.00
69 T,M o-Xylene 10.000 9.423 5.8 97 -0.02
70 T,M Styrene 10.000 9.547 4.5 97 0.00
71 T,M Isopropylbenzene 10.000 8.795 12.1 88 -0.02
72 I l,2-DICHLOROBENZENE-D4 10.000 10.000 0.0 106 0.00
73 P,T,M Bromoform 10.000 10.266 -2.7 128 0.00
74 T,M trans-1,4-Dichloro-2-butene 10.000 8.839 11.6 104 0.00
75 T,M 1, 1,2, 2-Tetrachloroethane 10.000 9.201 8.0 110 -0.02
76 S 4-Bromofluorobenzene 10.000 9.478 5.2 111 -0.02
77 T,M 1, 2, 3-Trichloropropane 10.000 9.445 5.5 108 0.00
78 T,M n-Propylbenzene 10.000 8.382 16.2 92 -0.02
79 T,M Bromobenzene 10.000 9.195 8.0 102 -0.02
80 T,M l,3,5-Tri~ethylbenzene 10.000 8.227 17.7 91 -0.02
--------------------------------------------------------------------------
(# ) = Out of Range
REV530.D VOO1E11.M Thu Jun 13 14:39:34 2024 Page 2
REPORT ID: 24E186 Page 124 of 217
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Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24E29\REV530.D
Acq On 29 May 2024 11:25 am
Sample CV001Ell13
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
3
LPriet
01
1. 00
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
T,M 2-Chlorotoluene 10.000 8.856 11.4 99 0.00
T,M 4-Chlorotoluene 10.000 8.486 15.1 92 0.00
T,M tert-Butylbenzene 10.000 8.520 14.8 94 -0.02
T,M l,2,4-Trimethylbenzene 10.000 8.388 16.1 92 -0.02
T,M sec-Butylbenzene 10.000 8.447 15.5 93 -0.02
T,M p-Isopropyltoluene 10.000 8.361 16.4 92 -0.02
T,M l,3-Dichlorobenzene 10.000 9.071 9.3 100 0.00
T,M l,2,3-Trimethylbenzene 10.000 8.449 15.5 95 0.00
T,M l,4-Dichlorobenzene 10.000 8.975 10.3 100 0.00
T,M n-Butylbenzene 10.000 8.364 16.4 92 0.00
T,M l,2-Dichlorobenzene 10.000 9.188 8.1 105 -0.02
T,M l,2-Dibromo-3-chloropropane 10.000 9.185 8.1 119 0.00
T,M l,2,4-Trichlorobenzene 10.000 9.288 7.1 104 0.00
T,M Hexachlorobutadiene 10.000 8.297 17.0 88 0.00
T,M Naphthalene 10.000 9.194 8.1 106 0.00
T,M l,2,3-Trichlorobenzene 10.000 9.595 4.0 108 0.00
(#) = Out of Range
REV530.D V001E11.M
SPCC's out = 0 CCC's out = 0
Thu Jun 13 14:39:34 2024 Page 3
REPORT ID: 24E186 Page 125 of 217
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Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24E29\REV530.D
Acq On 29 May 2024 11:25 am
Sample CV001Ell13
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
3
LPriet
01
1. 00
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Min. RRF
Max. RRF Dev
Compound
Mon May 13 13:20:11 2024
Multiple Level Calibration
0.000 Min. ReI. Area
20% Max. ReI. Area
AvgRF
I l,4-DIFLUOROBENZENE 1.000
T,M Chlorotrifluoroethylene 0.000
T,M Dichlorodifluoromethane 0.268
T,M 2-Chloro-1,1, 1-trifluoroeth 0.000
50% Max. R.T. Dev 0.16min
200%
CCRF %Dev Area% Dev(min)
1.000 0.0 92 0.00
0.000 0.0 0# -2.08#
0.238 11. 2 86 0.01
0.000 0.0 0# -2.53#
P,T,M Chloromethane 0.375"......-0.303 19.2 80 0.01
C,T,M Vinyl chloride 0.312 0.281 9.9 83 0.00
T,M Bromomethane 0.396 0.317 19.9 89 0.02
T,M Chloroethane 0.226 0.191 15.5 83 0.02
T,M Dichlorofluoromethane 0.643 0.684 -6.4 108 0.00
T,M Trichlorofluoromethane 0.422 0.415 1.7 96 0.00
T,M Acrolein 0.022 0.020 9.1 91 -0.01
T,M l,l,2-Trichloro-1,2,2-trifl 0.211 0.221 -4.7 97 0.02
T,M Acetone 0.037 0.041 -10.8 123 -0.01
C,T,M l,l-Dichloroethene 0.533 0.487 8.6 87 0.00
T,M tert-Butyl alcohol 0.011 0.012 -9.1 113 -0.01
T,M Iodomethane 0.572 0.614 -7.3 104 0.00
T,M Methyl acetate 0.100 0.140 -40.0# 153 -0.01
T,M Methylene chloride 0.428 0.427 0.2 98 -0.01
T,M Carbon disulfide 1.140 1.155 -1. 3 100 0.00
T,M Acrylonitrile 0.046 0.048 -4.3 103 -0.01
T,M tert-Butyl methyl ether (MT 0.525 0.551 -5.0 107 -0.01
T,M trans-1 /2-Dichloroethene 0.514 0.486 5.4 94 -0.01
T,M Isopropyl ether (DIPE) 1. 098 1.153 -5.0 103 -0.02
T,M Vinyl acetate 0.377 0.373 1.1 100 -0.01
P,T,M l,l-Dichloroethane 0.601 /.584 2.8 95 0.00
T,M 2-Butanol 0.000 0.001 0.0 0# 0.06
T,M tert-Butyl ethyl ether (ETB 0.787 0.776 1.4 99 -0.02
T,M 2-Butanone 0.056 0.063 -12.5 108 -0.02
T,M 2,2-Dichloropropane 0.505 0.486 3.8 94 0.00
T,M cis-1,2-Dichloroethene 0.414 0.397 4.1 93 -0.02
C,T,M Chloroform 0.612 0.625 -2.1 104 -0.02
T,M Bromochloromethane 0.240 0.242 -0.8 100 0.00
T,M Tetrahydrofuran 0.035 0.034 2.9 106 -0.02
S Dibromofluoromethane 0.310 0.327 -5.5 107 -0.02
T,M l,l,l-Trichloroethane 0.512 0.535 -4.5 102 -0.02
T,M Cyclohexane 0.499 0.517 -3.6 105 -0.02
T,M 2,2,4-Trimethylpentane 0.000 0.026 0.0 0# -0.02
T,M l,l-Dichloropropene 0.174 0.163 6.3 92 -0.02
T,M Carbon tetrachloride 0.382 0.399 -4.5 101 -0.02
T,M tert-Amyl methyl ether (TAM 0.612 0.604 1.3 103 0.00
S 1,2-Dichloroethane-d4 0.211 0.229 -8.5 114 -0.02
(#) = Out of Range
REV530.D V001E11.M Thu Jun 13 14:39:41 2024 Page 1
REPORT ID: 24E186 Page 126 of 217
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55
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63
64
65
66
67
68
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74
75
76
77
78
79
80
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24E29\REV530.D
Acq On 29 May 2024 11:25 am
Sample CV001Ell13
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
3
LPriet
01
1.00
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound AvgRF
T,M Benzene 1. 336
T,M l,2-Dichloroethane 0.269
T,M Trichloroethene 0.346
T,M Methylcyclohexane 0.549
C,T,M l,2-Dichloropropane 0.299
T,M Bromodichloromethane 0.415
T,M 1 /4-Dioxane 0.001
T,M Dibromomethane 0.141
T,M 2-Chloroethyl vinyl ether 0.076
T,M 4-Methyl-2-pentanone 0.136
T,M cis-1,3-Dichloropropene 0.465
I CHLOROBENZENE-D5 1.000
S Toluene-d8 1.499
C,T,M Toluene 1.776
T,M Ethyl methacrylate 0.266
T,M trans-1,3-Dichloropropene 0.413
T,M 1, 1, 2-Trichloroethane 0.233
T,M 2-Hexanone 0.090
T,M l,3-Dichloropropane 0.395
T,M Tetrachloroethene 0.369
T,M Dibromochloromethane 0.284
T,M l,2-Dibromoethane 0.230
T,M 1-Chlorohexane 0.767
P,M Chlorobenzene 1.059
T,M l,l,l,2-Tetrachloroethane 0.326
C,T,M Ethylbenzene 2.027
T,M m-Xylene & p-Xylene 1.484
T,M o-Xylene 1. 527
T,M Styrene 1.184
T,M Isopropylbenzene 2.012
I l,2-DICHLOROBENZENE-D4 1.000
P,T,M Bromoform 0.350
T,M trans-1,4-Dichloro-2-butene 0.173
T,M 1, 1, 2, 2-Tetrachloroethane 0.666
S 4-Bromofluorobenzene 1. 362
T,M l,2,3-Trichloropropane 0.170
T,M n-Propylbenzene 6.502
T,M Bromobenzene 1.029
T,M l,3,5-Trimethylbenzene 4.155
50% Max. R.T. Dev 0.16min
200%
CCRF %Dev Area% Dev(min)
1. 265 5.3 93 -0.02
0.301 -11. 9 111 -0.02
0.346 0.0 95 0.00
0.597 -8.7 112 -0.01
0.288 3.7 95 -0.01
0.424 -2.2 105 -0.02
0.001 0.0 102 -0.03
0.153 -8.5 112 -0.02
0.108 -42.1# 143 -0.02
0.164 -20.6# 118 -0.01
0.468 -0.6 100 -0.02
1.000 0.0 98 -0.02
1.406 6.2 99 -0.02
1. 596 10.1 92 -0.02
0.275 -3.4 109 -0.01
0.406 1.7 102 -0.02
0.228 2.1 103 -0.02
0.111 -23.3# 120 0.00
0.400 -1. 3 107 -0.02
0.356 3.5 97 0.00
0.287 -1.1 108 -0.02
0.228 0.9 104 -0.02
0.698 9.0 92 0.00
0.994 6.1 95 -0.02
/0.318 2.5 99 -0.02
1.877 7.4 92 -0.02
1.424 4.0 97 0.00
1.439 5.8 97 -0.02
1.130 4.6 97 0.00
1. 769 12.1 88 -0.02
1. 000 0.0 106 0.00
,/ 0.406 -16.0 128 0.00
~·152 12.1 104 0.00
0.613 8.0 110 -0.02
1. 291 5.2 111 -0.02
0.161 5.3 108 0.00
5.450 16.2 92 -0.02
0.946 8.1 102 -0.02
3.418 17.7 91 -0.02
(#) = Out of Range
REV530.D V001E11.M Thu Jun 13 14:39:44 2024 Page 2
REPORT ID: 24E186 Page 127 of 217
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Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24E29\REV530.D
Aeq On 29 May 2024 11:25·am
Sample CV001Ell13
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
3
LPriet
01
1. 00
Min. RRF·
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound AvgRF CCRF %Dev Area% Dev(min)
T,M 2-Chlorotoluene 3.915 3.467 11. 4 99 0.00
T,M 4-Chlorotoluene 3.466 2.941 15.1 92 0.00
T,M tert-Butylbenzene 0.871 0.743 14.7 94 -0.02
T,M l,2,4-Trimethylbenzene 4.065 3.409 16.1 92 -0.02
T,M see-Butylbenzene 5.711 4.824 15.5 93 -0.02
T,M p-Isopropyltoluene 4.403 3.681 16.4 92 -0.02
T,M l,3-Diehlorobenzene 1.955 1.773 9.3 100 0.00
T,M l,2,3-Trimethylbenzene 3.795 3.206 15.5 95 0.00
T,M l,4-Diehlorobenzene 1.916 1. 720 10.2 100 0.00
T,M n-Butylbenzene 4.560 3.814 16.4 92 0.00
T,M l,2-Diehlorobenzene 1. 602 1.472 8.1 105 -0.02
T,M l,2-Dibromo-3-ehloropropane 0.095 0.094 1.1 119 0.00
T,M l,2,4-Trichlorobenzene 1.169 1. 086 7.1 104 0.00
T,M Hexaehlorobutadiene 0.697 0.578 17.1 88 0.00
T,M Naphthalene 1.365 1.255 8.1 106 0.00
T,M 1, 2, 3-Triehlorobenzene 0.881 0.845 4.1 108 0.00
(#) = Out of Range
REV530.D V001E11.M
sPCC's out = 0 CCC's out = 0
Thu Jun 13 14:39:46 2024 Page 3
REPORT ID: 24E186 Page 128 of 217
Quantitation Report (Not Reviewed)
Data File D:\HPCHEM\1\DATA\24E29\REV530.D
Acq On 29 May 2024 11:25 am
Sample CV001E1113
Vial:
Operator:
3
LPriet
01
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: May 29 11:47 2024 Quant Results File: V001Ell.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001Ell.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001Ell
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
72) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
3) Dichlorodifluoromethane
5) Chloromethane
6) Vinyl chloride
7) Bromomethane
8) Chloroethane
9) Dichlorofluoromethane
10) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-l,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
18) Methylene chloride
19) Carbon disulfide
20) Acrylonitrile
21) tert-Butyl methyl ether (M
22) trans-l,2-Dichloroethene
23) Isopropyl ether (DIPE)
24) Vinyl acetate
25) 1,1-Dichloroethane
27) tert-Butyl ethyl ether (ET
28) 2-Butanone
29) 2,2-Dichloropropane
30) cis-l,2-Dichloroethene
31) Chloroform
8.54
13.70
18.67
7.21
7.95
11.02
15.99
2.18
2.48
2.60
3.15
3.20
3.27
3.55
3.97
4.07
4.04
4.22
4.32
4.64
4.64
4.84
4.87
5.01
5.05
5.23
5.66
5.81
5.82
6.22
6.40
6.62
6.66
6.89
114
117
152
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
142
43
49
76
53
73
61
45
43
63
59
43
77
96
83
847951 //
725980
301910 j
277407
10.00 ug/l
10.00 ug/l
10.00 ug/l
10.57
0.00
-0.02
0.00
Recovery =
ug/l -0.02
105.70%
194558 10.87
Recovery =
ug/l -0.02
108.70%
1020461 9.38
Recovery =
ug/l -0.02
93.80%
389752 9.48
Recovery =
ug/l -0.02
94.80%
201482
257128
238392
268473
161719
580164
351590
83376
187219
175127
412936
263904
520676
118345
361793
979680
202315
467512
411765
977312
316387
494783
657792
265434
412455
336569
530289
8.88 ug/l
8.09 ug/l
9.01 ug/l
8.53 ug/l
8.43 ug/l
10.64 ug/l
9.82 ug/l
43.78 ug/l
10.47 ug/l
56.58 ug/l
9.13 ug/l
279.58 ug/l
10.74 ug/l
14.02 ug/l
9.97 ug/l
10.13 ug/l
51. 52 ug/l
10.51 ug/l
9.45 ug/l
10.50 ug/l
9.90 ug/l
9.71 ug/l
9.86 ug/l
55.89 ug/l
9.63 ug/l
9.60 ug/l
10.21 ug/l
Qvalue
99
100
99
99
91
99
98
98
100
95
100
85
98
98
99
99
98
98
99
99
98
99
97
100
99
100
99
(#) = qualifier out of range (m) = manual integration
REV530.D V001E11.M Thu Jun 13 14:39:55 2024 Page 1
REPORT ID: 24E186 Page 129 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E29\REV530.D
Acq On 29 May 2024 11:25 am
Sample CV001Ell13
Misc : 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
(Not Reviewed)
Vial:
Operator:
Inst
Multiplr:
3
LPriet
01
1. 00
Quant Time: May 29 11:47 2024 Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Cone Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) l,l,l-Trichloroethane
36) Cyclohexane
38) l,l-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) Benzene
43) l,2-Dichloroethane
44) Trichloroethene
45) Methylcyclohexane
46) l,2-Dichloropropane
47) Bromodichloromethane
48) l,4-Dioxane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) l,l,2-Trichloroethane
59) 2-Hexanone
60) l,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
63) l,2-Dibromoethane
64) 1-Chlorohexane
65) Chlorobenzene
66) l,l,l,2-Tetrachloroethane
67) Ethylbenzene
68) m-Xylene & p-Xylene
69) o-Xylene
70) Styrene
71) Isopropylbenzene
73) Bromoform
74) trans-1,4-Dichloro-2-buten
75) l,l,2,2-Tetrachloroethane
77) l,2,3-Trichloropropane
78) n-Propylbenzene
79) Bromobenzene
7.14
7.18
7.48
7.51
7.70
7.86
7.88
8.12
8.09
9.06
9.15
9.33
9.71
9.76
9.80
10.22
10.25
10.60
11.15
11.45
11.46
11.73
11.76
1'2.17
12.29
12.65
13.02
13.30
13.77
13.85
13.86
14.01
14.82
14.90
15.50
15.55
15.62
15.85
16.14
16.27
16.36
49
42
97
84
110
119
73
78
62
130
83
63
83
88
93
63
43
75
91
69
75
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
53
83
110
91
156
205541
29243
454045
438035
138605
338136
512140
1072982
255359
293811
506515
244602
359906
20541
130044
91668
696205
397209
1158593
199594
294455
165642
401694
290156
258394
208472
165185
507082
721523
230620
1362682
2067977
1044617
820437
1284571
122608
46036
184931
48565
1645272
285559
(#) = qualifier out of range (m) = manual integration
REV530.D V001E11.M Thu Jun 13 14:39:56 2024
10.08 ug/l
9.73 ug/l
10.45 ug/l
10.35 ug/l
9.39 ug/l
10.45 ug/l
9.87 ug/l
9.47 ug/l
11.18 ug/l
10.03 ug/l
10.88 ug/l
9.65 ug/l
10.23 ug/l
197.95 ug/l
10.88 ug/l
14.25 ug/l
55.25 ug/l
10.07 ug/l
8.99 ug/l
10.32 ug/l
9.83 ug/l
9.81 ug/l
51. 97 ug/l
10.13 ug/l
9.64 ug/l
10.12 ug/l
9.89 ug/l
9.11 ug/l
9.39 ug/l
9.74 ug/l
9.26 ug/l
19.20 ug/l
9.42 ug/l
9.55 ug/l
8.80 ug/l
10.27 ug/l
8.84 ug/l
9.20 ug/l
9.45 ug/l
8.38 ug/l
9.20 ug/l
Qvalue
98
98
99
98
98
100
99
100
99
98
99
94
100
97
95
98
98
98
100
94
97
99
96
100
99
99
99
100
99
100
98
97
99
99
99
97
97
98
99
99
100
Page 2
REPORT ID: 24E186 Page 130 of 217
Quantitation Report (Not Reviewed)
Data File D:\HPCHEM\1\DATA\24E29\REV530.D
Aeq On 29 May 2024 11:25 am
Sample CV001Ell13
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
3
LPriet
01
1. 00
Quant Time: May 29 11:47 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. Qlon Response Cone Unit
80) l,3,5-Trimethylbenzene 16.59 105 1031919 8.23 ug/l
81) 2-Chlorotoluene 16.63 91 1046633 8.86 ug/l
82) 4-Chlorotoluene 16.72 91 887891 8.49 ug/l
83) tert-Butylbenzene 17.27 134 224174 8.52 ug/l
84) l,2,4-Trimethylbenzene 17.34 105 1029358 8.39 ug/l
85) see-Butylbenzene 17.64 105 1456373 8.45 ug/l
86) p-Isopropyltoluene 17.86 119 1111416 8.36 ug/l
87) l,3-Diehlorobenzene 18.02 146 535287 9.07 ug/l
88) l,2,3-Trimethylbenzene 18.13 105 967977 8.45 ug/l
89) l,4-Diehlorobenzene 18.19 146 519269 8.97 ug/l
90) n-Butylbenzene 18.48 91 1151471 8.36 ug/l
91) l,2-Diehlorobenzene 18.70 146 444280 9.19 ug/l
92) 1,2-Dibromo-3-ehloropropan 19.71 157 28251 9.18 ug/l
93) l,2,4-Triehlorobenzene 20.79 180 327927 9.29 ug/l
94) Hexaehlorobutadiene 20.95 225 174506 8.30 ug/l
95) Naphthalene 21.13 128 378839 9.19 ug/l
96) l,2,3-Triehlorobenzene 21.46 180 255161 9.59 ug/l
(#) = qualifier out of range (m) = manual integration
REV530.D V001E11.M Thu Jun 13 14:39:56 2024
Qvalue
99
100
99
96
99
100
99
99
99
99
99
99
96
100
96
100
99
Page 3
REPORT ID: 24E186 Page 131 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E29\REV530.D
Aeq On 29 May 2024 11:25 am
Sample CV001Ell13
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
3
LPriet
01
1. 00
Quant Time: May 29 11:47 2024 Quant Results File: V001E11.RES
Method
Title
Last Update
Response via
bundance
11
1000000
900000
::!i .,.:-
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
~
~::!i 1-:.,.:-
~~
,m ~
i
:;;
::!i
~
REV530.D V001E11.M Thu Jun 13 14:39:59 2024 Page 4
REPORT ID: 24E186 Page 132 of 217
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24E29\REV550.D
Acq On 29 May 2024 9:55 pm
Sample EV001Ell13
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
23
LPriet
01
1. 00
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024 ~
Multiple Level Calibration ~
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
1 I l,4-DIFLUOROBENZENE
2 T,M Chlorotrifluoroethylene
3 T,M Dichlorodifluoromethane
4 T,M 2-Chloro-1,l,l-trifluoroeth
5 P,T,M Chloromethane
6 C,T,M Vinyl chloride
7 T,M Bromomethane
8 T,M Chloroethane
9 T,M Dichlorofluoromethane
10 T,M Trichlorofluoromethane
11 T,M Acrolein
12 T,M l,l,2-Trichloro-1,2,2-trifl
13 T,M Acetone
14 C,T,M 1,1-Dichloroethene
15 T,M tert-Butyl alcohol
16 T,M Iodomethane
17 T,M Methyl acetate
18 T,M Methylene chloride
19 T,M Carbon disulfide
20 T,M Acrylonitrile
21 T,M tert-Butyl methyl ether (MT
22 T,M trans-1,2-Dichloroethene
23 T,M Isopropyl ether (DIPE)
24 T,M vinyl acetate
25 P,T,M l,l-Dichloroethane
26 T,M 2-Butanol
27 T,M tert-Butyl ethyl ether (ETB
28 T,M 2-Butanone
29 T,M 2,2-Dichloropropane
30 T,M cis-1,2-Dichloroethene
31 C,T,M Chloroform
32 T,M Bromochloromethane
33 T,M Tetrahydrofuran
34 S Dibromofluoromethane
35 T,M l,l,l-Trichloroethane
36 T,M Cyclohexane
37 T,M 2,2,4-Trimethylpentane
38 T,M l,l-Dichloropropene
39 T,M Carbon tetrachloride
40 T,M tert-Amyl methyl ether (TAM
41 S l,2-Dichloroethane-d4
Amount Calc.
10.000 10.000
-1. 000 0.000
10.000 9.394
-1.000 0.000
10.000 8.800
10.000 9.382
10.000 9.940
10.000 9.079
10.000 9.791
10.000 10.138
50.000 42.001
10.000 10.314
50.000 44.565
10.000 9.942
250.000 207.314
10.000 10.722
10.000 8.772
10.000 10.426
10.000 8.029
50.000 46.939
10.000 9.399
10.000 10.190
10.000 10.019
10.000 9.013
10.000 10.624
250.000 0.000
10.000 9.604
50.000 49.630
10.000 9.503
10.000 10.398
10.000 10.823
10.000 10.433
10.000 9.188
10.000 10.542
10.000 10.853
10.000 8.812
10.000 0.000
10.000 9.398
10.000 11. 249
10.000 8.941
10.000 10.757
(#) = Out of Range
REV550.D V001E11.M Thu Jun 13 14:40:33 2024
%Dev Area% Dev(min)
0.0
0.0
6.1
0.0
12.0
6.2
0.6
9.2
2.1
-1. 4
16.0
-3.1
10.9
0.6
17.1
-7.2
12.3
-4.3
19.7
6.1
6.0
-1. 9
-0.2
9.9
-6.2
100.0#
4.0
0.7
5.0
-4.0
-8.2
-4.3
8.1
-5.4
-8.5
11. 9
100.0#
6.0
-12.5
10.6
-7.6
78
o
77
o
74
73
87
76
84
84
74
81
82
80
71
88
81
87
67
79
81
86
83
77
88
o
81
81
78
85
93
88
85
90
90
76
o
78
92
79
95
0.00
-2.08#
0.01
-2.53#
0.03
0.01
0.01
0.01
0.01
0.00
0.00
0.01
0.00
0.01
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.01
0.01
0.01
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-0.02
Page 1
REPORT ID: 24E186 Page 133 of 217
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24E29\REV550.D
Acq On 29 May 2024 9:55 pm
Sample EV001E1113
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial: 23
Operator: LPriet
Inst 01
Multiplr: 1.00
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
42 T,M Benzene
43 T,M 1,2-Dichloroethane
44 T,M Trichloroethene
45 T,M Methylcyclohexane
46 C,T,M 1,2-Dichloropropane
47 T,M Bromodichloromethane
48 T,M 1,4-Dioxane
49 T,M Dibromomethane
50 T,M 2-Chloroethyl vinyl ether
51 T,M 4-Methyl-2-pentanone
52 T,M cis-1,3-Dichloropropene
53 I CHLOROBENZENE-D5
54 S Toluene-d8
55 C,T,M Toluene
56 T,M Ethyl methacrylate
57 T,M trans-1,3-Dichloropropene
58 T,M 1,1,2-Trichloroethane
59 T,M 2-Hexanone
60 T,M 1,3-Dichloropropane
61 T,M Tetrachloroethene
62 T,M Dibromochloromethane
63 T,M 1,2-Dibromoethane
64 T,M 1-Chlorohexane
65 P,M Chlorobenzene
66 T,M 1,1,1,2-Tetrachloroethane
67 C,T,M Ethylbenzene
68 T,M m-Xylene & p-Xylene
69 T,M o-Xylene
70 T,M Styrene
71 T,M Isopropylbenzene
72 I 1,2-DICHLOROBENZENE-D4
73 P,T,M Bromoform
74 T,M trans-1,4-Dichloro-2-butene
75 T,M 1,1,2,2-Tetrachloroethane
76 S 4-Bromofluorobenzene
77 T,M 1,2,3-Trichloropropane
78 T,M n-propylbenzene
79 T,M Bromobenzene
80 T,M l,3,5-Trimethylbenzene
Amount Calc.
10.000
10.000
10.000
10.000
10.000
10.000
200.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
20.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.233
11. 381
10.275
8.689
9.989
10.638
165.256
11. 293
11.410
46.760
9.977
10.000
9.457
9.884
8.997
9.542
9.844
42.092
9.953
10.223
9.951
9.720
9.398
9.974
10.273
10.212
20.677
10.452
10.000
10.119
10.000
9.184
8.173
8.791
9.673
9.075
9.358
10.062
9.260
(#) = Out of Range
REV550.D V001E11.M Thu Jun 13 14:40:34 2024
%Dev Area% Dev(min)
-2.3
-13.8
-2.8
13.1
0.1
-6.4
17.4
-12.9
-14.1
6.5
0.2
0.0
5.4
1.2
10.0
4.6
1.6
15.8
0.5
-2.2
0.5
2.8
6.0
0.3
-2.7
-2.1
-3.4
-4.5
0.0
-1. 2
0.0
8.2
18.3
12.1
3.3
9.3
6.4
-0.6
7.4
85
96
83
75
84
93
72
98
97
84
83
83
84
86
81
84
88
80
89
87
90
87
81
86
89
87
89
91
87
86
90
96
81
89
96
87
87
94
86
0.00
0.00
0.00
-0.01
0.00
-0.01
-0.01
0.00
-0.01
0.00
0.00
-0.02
-0.01
-0.02
-0.01
0.00
0.00
0.00
0.00
0.00
0.00
-0.02
0.00
-0.02
0.00
-0.02
0.00
-0.02
0.00
-0.02
0.00
0.00
0.00
-0.02
-0.02
0.00
0.00
0.00
-0.02
Page 2
REPORT ID: 24E186 Page 134 of 217
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24E29\REV550.D
Acq On 29 May 2024 9:55 pm
Sample EV001Ell13
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
23
LPriet
01
1. 00
Min. RRF
Max. RRF Dev
0.000 Min. Rel. Area
20% Max. Rel. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
T,M 2-Chlorotoluene 10.000 9.904 1.0 93 0.00
T,M 4-Chlorotoluene 10.000 9.558 4.4 88 0.00
T,M tert-Butylbenzene 10.000 9.231 7.7 86 0.00
T,M l,2,4-Trimethylbenzene 10.000 9.327 6.7 86 -0.02
T,M sec-Butylbenzene 10.000 9.020 9.8 84 -0.02
T,M p-Isopropyltoluene 10.000 9.123 8.8 85 0.00
T,M 1,3-Dichlorobenzene 10.000 9.773 2.3 91 0.00
T,M l,2,3-Trimethylbenzene 10.000 9.398 6.0 89 0.00
T,M l,4-Dichlorobenzene 10.000 9.701 3.0 91 0.00
T,M n-Butylbenzene 10.000 9.145 8.6 85 0.00
T,M 1,2-Dichlorobenzene 10.000 9.713 2.9 93 -0.02
T,M l,2-Dibromo-3-chloropropane 10.000 7.994 20.1# 87 0.00
T,M 1,2,4-Trichlorobenzene 10.000 9.077 9.2 86 0.00
T,M Hexachlorobutadiene 10.000 8.990 10.1 81 0.01
T,M Naphthalene 10.000 8.514 14.9 83 0.01
T,M l,2,3-Trichlorobenzene 10.000 8.969 10.3 85 0.00
(#) = Out of Range
REV550.D V001E11.M
SPCC's out = 0 CCC's out = 0
Thu Jun 13 14:40:34 2024 Page 3
REPORT ID: 24E186 Page 135 of 217
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24E29\REV550.D
Acq On 29 May 2024 9:55 pm
Sample EV001Ell13
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
23
LPriet
01
1. 00
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound
1 I l,4-DIFLUOROBENZENE
2 T,M Chlorotrifluoroethylene
3 T,M Dichlorodifluoromethane
4 T,M 2-Chloro-1,l,l-trifluoroeth
5 P,T,M Chloromethane
6 C,T,M Vinyl chloride
7 T,M Bromomethane
8 T,M Chloroethane
9 T,M Dichlorofluoromethane
10 T,M Trichlorofluoromethane
11 T,M Acrolein
12 T,M l,l,2-Trichloro-1,2,2-trifl
13 T,M Acetone
14 C,T,M l,l-Dichloroethene
15 T,M tert-Butyl alcohol
16 T,M Iodomethane
17 T,M Methyl acetate
18 T,M Methylene chloride
19 T,M Carbon disulfide
20 T,M Acrylonitrile
21 T,M tert-Butyl methyl ether (MT
22 T,M trans-1,2-Dichloroethene
23 T,M Isopropyl ether (DIPE)
24 T,M Vinyl acetate
25 P,T,M l,l-Dichloroethane
26 T,M 2-Butanol
27 T,M tert-Butyl ethyl ether (ETB
28 T,M 2-Butanone
29 T,M 2,2-Dichloropropane
30 T,M cis-1,2-Dichloroethene
31 C,T,M Chloroform
32 T,M Bromochloromethane
33 T,M Tetrahydrofuran
34 S Dibromofluoromethane
35 T,M l,l,l-Trichloroethane
36 T,M Cyclohexane
37 T,M 2,2,4-Trimethylpentane
38 T,M l,l-Dichloropropene
39 T,M Carbon tetrachloride
40 T,M tert-Amyl methyl ether (TAM
41 S l,2-Dichloroethane-d4
AvgRF
1.000
0.000
0.268
0.000
0.375
0.312
0.396
0.226
0.643
0.422
0.022
0.211
0.037
0.533
0.011
0.572
0.100
0.428
1.140
0.046
0.525
0.514
1. 098
0.377
0.601
0.000
0.787
0.056
0.505
0.414
0.612
0.240
0.035
0.310
0.512
0.499
0.000
0.174
0.382
0.612
0.211
50% Max. R.T. Dev 0.16min
200%
CCRF
1. 000
0.000
0.251
0.000
0.330
0.293
0.368
0.205
0.629
0.428
0.019
0.218
0.033
0.530
0.009
0.613
0.087
0.446
0.916
0.043
0.493
0.524
1.100
0.340
0.638
0.007
0.756
0.056
0.480
0.430
0.663
0.251
0.033
0.326
0.556
0.440
0.021
0.164
0.429
0.547
0.227
%Dev Area% Dev(min)
0.0
0.0
6.3
0.0
12.0
6.1
7.1
9.3
2.2
-1.4
13.6
-3.3
10.8
0.6
18.2
-7.2
13.0
-4.2
19.6
6.5
6.1
-1. 9
-0.2
9.8
-6.2
0.0
3.9
0.0
5.0
-3.9
-8.3
-4.6
5.7
-5.2
-8.6
11. 8
0.0
5.7
-12.3
10.6
-7.6
78
0#
77
0#
74
73
87
76
84
84
74
81
82
80
71
88
81
87
67
79
81
86
83
77
88
0#
81
81
78
85
93
88
85
90
90
76
0#
78
92
79
95
0.00
-2.08#
0.01
-2.53#
0.03
0.01
0.01
0.01
0.01
0.00
0.00
0.01
0.00
0.01
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.01
0.01
0.01
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-0.02
(#) = Out of Range
REV550.D V001E11.M Thu Jun 13 14:40:41 2024 Page 1
REPORT ID: 24E186 Page 136 of 217
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24E29\REV550.D
Acq On 29 May 2024 9:55 pm
Sample EV001Ell13
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
23
LPriet
01
1. 00
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound
42 T,M Benzene
43 T,M l,2-Dichloroethane
44 T,M Trichloroethene
45 T,M Methylcyclohexane
46 C,T,M l,2-Dichloropropane
47 T,M Bromodichloromethane
48 T,M l,4-Dioxane
49 T,M Dibromomethane
50 T,M 2-Chloroethyl vinyl ether
51 T,M 4-Methyl-2-pentanone
52 T,M cis-1,3-Dichloropropene
53 I CHLOROBENZENE-D5
54 S Toluene-d8
55 C,T,M Toluene
56 T,M Ethyl methacrylate
57 T,M trans-1,3-Dichloropropene
58 T,M l,l,2-Trichloroethane
59 T,M 2-Hexanone
60 T,M l,3-Dichloropropane
61 T,M Tetrachloroethene
62 T,M Dibromochloromethane
63 T,M l,2-Dibromoethane
64 T,M 1-Chlorohexane
65 P,M Chlorobenzene
66 T,M l,l,l,2-Tetrachloroethane
67 C,T,M Ethylbenzene
68 T,M m-Xylene & p-Xylene
69 T,M o-Xylene
70 T,M Styrene
71 T,M Isopropylbenzene
72 I l,2-DICHLOROBENZENE-D4
73 P,T,M Bromoform
74 T,M trans-1,4-Dichloro-2-butene
75 T,M l,l,2,2-Tetrachloroethane
76 S 4-Bromofluorobenzene
77 T,M 1 ,2,3-Trichloropropane
78 T,M n-Propylbenzene
79 T,M Bromobenzene
80 T,M l,3,5-Trimethylbenzene
AvgRF
1. 336
0.269
0.346
0.549
0.299
0.415
0.001
0.141
0.076
0.136
0.465
1.000
1.499
1.776
0.266
0.413
0.233
0.090
0.395
0.369
0.284
0.230
0.767
1.059
0.326
2.027
1.484
1.527
1.184
2.012
1.000
0.350
0.173
0.666
1. 362
0.170
6.502
1.029
4.155
50% Max. R.T. Dev 0.16min
200%
CCRF
1. 367
0.307
0.355
0.477
0.299
0.441
0.001
0.159
0.087
0.138
0.464
1. 000
1. 417
1.755
0.240
0.394
0.229
0.087
0.393
0.377
0.282
0.224
0.721
1.056
0.335
2.070
1.534
1. 596
1.184
2.036
1.000
0.362
0.141
0.585
1. 317
0.155
6.084
1.035
3.847
%Dev Area% Dev(min)
-2.3
-14.1
-2.6
13.1
0.0
-6.3
0.0
-12.8
-14.5
-1. 5
0.2
0.0
5.5
1.2
9.8
4.6
1.7
3.3
0.5
-2.2
0.7
2.6
6.0
0.3
-2.8
-2.1
-3.4
-4.5
0.0
-1. 2
0.0
-3.4
18.5
12.2
3.3
8.8
6.4
-0.6
7.4
85 0.00
96 0.00
83 0.00
75 -0.01
84 0.00
93 -0.01
72 -0.01
98 0.00
97 -0.01
84 0.00
83 0.00
83 -0.02
84 -0.01
86 -0.02
81 -0.01
84 0.00
88 0.00
80 0.00
89 0.00
87 0.00
90 0.00
87 -0.02
81 0.00
86 -0.02
89 0.00
87 -0.02
89 0.00
91 -0.02
87 0.00
86 -0.02
90 0.00
96 0.00
81 0.00
89 -0.02
96 -0.02
87 0.00
87 0.00
94 0.00
86 -0.02
(#) = Out of Range
REV550.D V001E11.M Thu Jun 13 14:40:44 2024 Page 2
REPORT ID: 24E186 Page 137 of 217
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24E29\REV550.D
Aeq On 29 May 2024 9:55 pm
Sample EV001Ell13
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
23
LPriet
01
1. 00
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound AvgRF CCRF %Dev Area% Dev(min)
T,M 2-Chlorotoluene 3.915 3.877 1.0 93 0.00
T,M 4-Chlorotoluene 3.466 3.313 4.4 88 0.00
T,M tert-Butylbenzene 0.871 0.804 7.7 86 0.00
T,M l,2,4-Trimethylbenzene 4.065 3.791 6.7 86 -0.02
T,M see-Butylbenzene 5.711 5.151 9.8 84 -0.02
T,M p-Isopropyltoluene 4.403 4.016 8.8 85 0.00
T,M l,3-Diehlorobenzene 1.955 1.910 2.3 91 0.00
T,M l,2,3-Trimethylbenzene 3.795 3.567 6.0 89 0.00
T,M l,4-Dichlorobenzene 1.916 1. 859 3.0 91 0.00
T,M n-Butylbenzene 4.560 4.170 8.6 85 0.00
T,M l,2-Dichlorobenzene 1.602 1. 556 2.9 93 -0.02
T,M l,2-Dibromo-3-ehloropropane 0.095 0.081 14.7 87 0.00
T,M l,2,4-Triehlorobenzene 1.169 1.061 9.2 86 0.00
T,M Hexachlorobutadiene 0.697 0.626 10.2 81 0.01
T,M Naphthalene 1. 365 1.162 14.9 83 0.01
T,M l,2,3-Triehlorobenzene 0.881 0.790 10.3 85 0.00
(#) = Out of Range
REV550.D V001E11.M
SPCC's out = 0 CCC's out = 0
Thu Jun 13 14:40:45 2024 Page 3
REPORT ID: 24E186 Page 138 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E29\REV550.D Vial:
Acq On 29 May 2024 9:55 pm Operator:
Sample EV001Ell13
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
Inst
Multiplr:
23
LPriet
01
1.00
MS Integration Params: RTE.P
Quant Time: May 29 22:17 2024 Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Internal Standards R.T. QIon Response Conc Units Dev(Min)
----------------------------------------------------~-------------------
1) l,4-DIFLUOROBENZENE 8.55 114 717198/' 10.00 ug/l 0.00
53) CHLOROBENZENE-D5 13.70 117 616471 10.00 ug/l -0.02
72) l,2-DICHLOROBENZENE-D4 18.67 152 254988 / 10.00 ug/l 0.00
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
3) Dichlorodifluoromethane
5) Chloromethane
6) Vinyl chloride
7) Bromomethane
8) Chloroethane
9) Dichlorofluoromethane
10) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
18) Methylene chloride
19) Carbon disulfide
20) Acrylonitrile
21) tert-Butyl methyl ether (M
22) trans-1,2-Dichloroethene
23) Isopropyl ether (DIPE)
24) Vinyl acetate
25) l,l-Dichloroethane
27) tert-Butyl ethyl ether (ET
28) 2-Butanone
29) 2,2-Dichloropropane
30) cis-1,2-Dichloroethene
31) Chloroform
7.23
7.95
11.02
15.99
2.18
2.49
2.62
3.15
3.20
3.29
3.55
3.98
4.07
4.06
4.23
4.34
4.63
4.65
4.86
4.89
5.02
5.06
5.24
5.67
5.83
5.83
6.23
6.41
6.63
6.68
6.90
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
142
43
49
76
53
73
61
45
43
63
59
43
77
96
83
234016 10.54 ug/l 0.00
Recovery = 105.40%
162868 10.76 ug/l -0.02
107.60% Recovery =
873693 9.46
Recovery =
ug/l -0.01
94.60%
335921 9.67 ug/l -0.02
96.70% Recovery =
180278
236456
209962
263674
147381
451427
306949
67660
156048
116664
380308
165517
439716
62613
319955
656736
155891
353598
375540
788956
243644
457869
541901
199364
344347
308447
475372
9.39 ug/l
8.80 ug/l
9.38 ug/l
9.94 ug/l
9.08 ug/l
9.79 ug/l
10.14 ug/l
42.00 ug/l
10.31 ug/l
44.57 ug/l
9.94 ug/l
207.31 ug/l
10.72 ug/l
8.77 ug/l
10.43 ug/l
8.03 ug/l
46.94 ug/l
9.40 ug/l
10.19 ug/l
10.02 ug/l
9.01 ug/l
10.62 ug/l
9.60 ug/l
49.63 ug/l
9.50 ug/l
10.40 ug/l
10.82 ug/l
Qvalue
100
99
100
95
91
99
99
94
100
92
98
81
97
100
99
99
99
94
99
98
99
99
99
97
99
99
99
(#) = qualifier out of range (m) = manual integration
REV550.D V001E11.M Thu Jun 13 14:40:52 2024 Page 1
REPORT ID: 24E186 Page 139 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E29\REV550.D
Acq On 29 May 2024 9:55 pm
Sample EV001Ell13
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
23
LPriet
01
1. 00
Quant Time: May 29 22:17 2024 Quant Results File: V001Ell.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001Ell.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001Ell
Compound R.T. QIon Response Conc Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) l,l,l-Trichloroethane
36) Cyclohexane
38) 1,1-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) Benzene
43) 1,2-Dichloroethane
44) Trichloroethene
45) Methylcyclohexane
46) 1,2-Dichloropropane
47) Bromodichloromethane
48) 1,4-Dioxane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-l,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-l,3-Dichloropropene
58) l,l,2-Trichloroethane
59) 2-Hexanone
60) l,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
63) 1,2-Dibromoethane
64) l-Chlorohexane
65) Chlorobenzene
66) 1,l,l,2-Tetrachloroethane
67) Ethylbenzene
68) m-Xylene & p-Xylene
69) o-Xylene
70) Styrene
71) Isopropylbenzene
73) Bromoform
74) trans-l,4-Dichloro-2-buten
75) l,l,2,2-Tetrachloroethane
77) l,2,3-Trichloropropane
78) n-Propylbenzene
79) Bromobenzene
7.14
7.20
7.49
7.52
7.71
7.88
7.88
8.13
8.10
9.06
9.15
9.34
9.71
9.77
9.82
10.22
10.26
10.62
11.15
11.45
11.48
11.74
11. 76
12.19
12.29
12.66
13.02
13.30
13.77
13.86
13.86
14.01
14.82
14.90
15.51
15.55
15.62
15.85
16.14
16.29
16.38
49
42
97
84
110
119
73
78
62
130
83
63
83
88
93
63
43
75
91
69
75
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
53
83
110
91
156
179949
23345
398783
315345
117384
307920
392514
980486
219916
254651
342097
214144
316551
14504
114189
62073
493738
332860
1082068
147811
242822
141105
269630
242152
232631
174125
137822
444290
650953
206502
1275875
1891274
983973
729741
1254975
92275
35953
149238
39412
1551443
263914
(#) = qualifier out of range (m) = manual integration
REV550.D V001Ell.M Thu Jun 13 14:40:53 2024
10.43 ug/l
9.19 ug/l
10.85 ug/l
8.81 ug/l
9.40 ug/l
11. 25 ug/l
8.94 ug/l
10.23 ug/l
11. 38 ug/l
10.28 ug/l
8.69 ug/l
9.99 ug/l
10.64 ug/l
165.26 ug/l
11.29 ug/l
11. 41 ug/l
46.76 ug/l
9.98 ug/l
9.88 ug/l
9.00 ug/l
9.54 ug/l
9.84 ug/l
42.09 ug/l
9.95 ug/l
10.22 ug/l
9.95 ug/l
9.72 ug/l
9.40 ug/l
9.97 ug/l
10.27 ug/l
10.21 ug/l
20.68 ug/l
10.45 ug/l
10.00 ug/l
10.12 ug/l
9.18 ug/l
8.17 ug/l
8.79 ug/l
9.08 ug/l
9.36 ug/l
10.06 ug/l
Qvalue
99
91
98
98
98
100
99
100
99
98
99
93
100
93
93
99
97
97
99
94
95
98
96
100
98
100
100
99
100
99
97
96
98
97
99
97
95
100
99
98
100
Page 2
REPORT ID: 24E186 Page 140 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24E29\REV550.D
Aeq On 29 May 2024 9:55 pm
Sample EV001Ell13
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
TBA
Vial:
Operator:
Inst
Multiplr:
23
LPriet
01
1. 00
Quant Time: May 29 22:17 2024 Quant Results File: V001Ell.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V001Ell.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001Ell
Compound R.T. QIon Response Cone Unit
80) 1, 3, 5-Trimethylbenzene 16.59 105 980991 9.26 ug/l
81) 2-Chlorotoluene 16.63 91 988635 9.90 ug/l
82) 4-Chlorotoluene 16.72 91 844648 9.56 ug/l
83) tert-Butylbenzene 17.28 134 205132 9.23 ug/l
84) l,2,4-Trimethylbenzene 17.34 105 966740 9.33 ug/l
85) see-Butylbenzene 17.64 105 1313441 9.02 ug/l
86) p-Isopropyltoluene 17.87 119 1024156 9.12 ug/l
87) l,3-Diehlorobenzene 18.02 146 487094 9.77 ug/l
88) 1, 2, 3-Trimethylbenzene 18.13 105 909421 9.40 ug/l
89) l,4-Diehlorobenzene 18.19 146 474055 9.70 ug/l
90) n-Butylbenzene 18.48 91 1063353 9.15 ug/l
91) l,2-Diehlorobenzene 18.70 146 396679 9.71 ug/l
92) l,2-Dibromo-3-ehloropropan 19.71 157 20583 7.99 ug/l
93) l,2,4-Triehlorobenzene 20.79 180 270645 9.08 ug/l
94) Hexaehlorobutadiene 20.97 225 159706 8.99 ug/l
95) Naphthalene 21.15 128 296291 8.51 ug/l
96) 1, 2, 3-Triehlorobenzene 21.46 180 201449 8.97 ug/l
(#) = qualifier out of range (m) = manual integration
REV550.D V001Ell.M Thu Jun 13 14:40:53 2024
Qvalue
99
99
98
97
98
100
99
99
100
99
98
99
99
99
98
100
99
Page 3
REPORT ID: 24E186 Page 141 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24E29\REV550.D
Aeq On 29 May 2024 9:55 pm
Sample EV001Ell13
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr~
23
LPriet
01
1. 00
Quant Time: May 29 22:17 2024 Quant Results File: V001E11.RES
Method
Title
Last Update
Response via
~bundance
1800000
1700000
1600000
1500000
1400000
1300000
1200000
1100000
1000000
900000
800000
700000
600000
500000
400000
300000
200000
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
Ilv: KcVOOU.U
::0 ...:-,
~ ~ .c: e
i! ~
:I:
0
:::0 ...:
CD c
CD ~
:::0 ...:
CD
l
W '--\'--J\j,--"-J ~'---o1J '-" ~~_ '----
1000: ~(hL
Time--> 2. 0 3.bi> 4.bo 5.bo 6.bi> 7.bi> 8.bi> 9.bi> 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.0020.0021.00
REV550.D V001E11.M Thu Jun 13 14:40:57 2024 Page 4
REPORT ID: 24E186 Page 142 of 217
FORM 5
VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK
BROMOFLUOROBENZENE (BFB)
Lab Name : EMAX Laboratori es, Inc.
Lab. Code : EMAX
Lab File ID: RFV001
Instrument ID: 01
Project : TEAD -N
SDG No : 24E186
BFB Injection Date: 06/03/24
BFB Injection Time: 10:38
I I % RELATIVE I
I m/e I ION ABUNDANCE CRITERIA ABUNDANCE I
1=1==============1
I 50 I 15 -40% of mass 95 18.139 I
I 75 I 30 -60% of mass 95 I 42.568 I
I 95 I Base Peak, 100% relative abundance __ 1 100.000 I
I 96 I 5 -9% of mass 95 I 6.671 I
I 173 I Less than 2% of mass 174 I 0.000(0)1 I
I 174 I Greater than 50% of mass 95 I 80.896 I
I 175 I 5 -9% of mass 174 I 5.809(7.18)1 I
I 176 I 95 -101% % of mass 174 I 78.623(97.19)1 I
I 177 I 5 -9% % of mass 176 I 5.236(6.66)2 I
I_I I I
I-Value is % mass 174 2-Value is % mass 176
Thi scheck app 1 i es to the fo 11 owi ng samples, Lab QCs and Standards:
I EPA I LAB I LAB I DATE I TIME
I SAMPLE NO. I SAMPLE ID I FI LE ID I ANALYZED I ANALYZED
1=======1====1===1 1===
11 VSTD10 I CV001E1116 I RFV002 I 06/03/24 I 11: 10
21 LCS2W I V001F01L I RFV003 I 06/03/24 I 11: 49
31 LCD2W I V001F01C I RFV004 I 06/03/24 I 12: 18
41MBLK2W IV001F01B IRFV006 I 06/03/24 I 13:20
5ITEAD-05-24-WIN9549 I 24E186-02N IRFV010 I 06/03/24 I 15:22
6ITEAD-05-24-WIN9549MS I 24E186-02M IRFV011 I 06/03/24 I 15:52
7ITEAD-05-24-WIN9549MSD I 24E186-02S IRFV012 I 06/03/24 I 16:21
81VSTD10 I EV001Ell16 IRFV025 I 06/03/24 I 22:42
I I I I 1 __ _
REPORT ID: 24E186 Page 143 of 217
FORM 8
VOLATILE INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY
lab Name: EMAX laboratories. Inc.
lab Code: EMAX
lab File ID: REV201
Instrument ID: 01
I INTERNAL STANDARD (IS)
I
I
I 12 HOUR STD
I UPPER LIMIT
I lOWER LIMIT
I
I
I
11 VSTD10
21 lCS2W
31 lCD2W
4IMBlK2W
5ITEAD·05·24·WIN9549
6ITEAD·05·24·WIN9549MS
71 TEAD· 05· 24· WIN9549MSD
81VSTD10
I
1. 4· D I FlUOROBENZENE
Area #
920983
1841966
460492
Area #
803255
860850
865358
878386
838939
767644
824891
828597
Area Upper limit = +100% of ICAl Midpoint IS Area
Area lower limit = ·50% of ICAl Midpoint IS Area
I CHlOROBENZENE· D5
RT #1 Area # I
I I
8.54 I 742213 I
8.71 I 1484426 I
8.37 I 371107 I
I I
RT # I Area # I
I I
8.55 I 669938 I
8.55 I 722112 I
8.56 I 730757 I
8.56 I 731451 I
8.56 I 667073 I
8.56 I 634144 I
8.56 I 681937 I
8.56 I 679361 I
I I
Retention Time(RT) Upper limit = +10 seconds of ICAl Midpoint IS RT
Retention Time(RT) lower limit = ·10 seconds of ICAl Midpoint IS RT
I
RT #1
I
13.71 I
13.88 I
13.54 I
I
RT # I
I
13.71 I
13.71 I
13.71 I
13.73 I
13.73 I
13.73 I
13.73 I
13.73 I
I
Project: TEAD·N
SDG No: 24E186
Date Analyzed: 05/11/24
Time Analyzed: 13:28
1.2· DICHLOROBENZENE· D4 I
Area # I RT #1
I I
284055 I 18.68 I
568110 I 1B.85 I
142028 I 18.51 I
I I
Area # I RT # I
I I
282761 I 18.69 I
303533 I 18.69 I
301967 I 18.69 I
311188 I 18.69 I
289333 I 18.69 I
271494 I 18.69 I
285916 I 18.69 I
287981 I 18.69 I
I I
REPORT ID: 24E186 Page 144 of 217
BFB
Data File D:\HPCHEM\1\DATA\24F03\RFV001.D
Acq On 3 Jun 2024 10:38 am
Sample BFB01F01
Misc T/CHK
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
1
LPriet
01
1. 00
Method D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
Title : METHOD 8260 25mls
bundance
20000
15000
10000
5000
0
ime->
bundance
20000
174
15000
10000 75
5000 50
Iz->
AutoFind: Scans 979, 980, 981; Background Corrected with Scan 972
I Target I ReI. to I Lower I Upper I
Mass Mass Limit% Limit%
50 95 15 40
75 95 30 60
95 95 100 100
96 95 5 9
173 174 0.00 2
174 95 50 100
175 174 5 9
176 174 95 101
177 176 5 9
ReI.
Abn%
18.1
42.6
100.0
6.7
0.0
80.9
7.2
97.2
6.7
RFV001.D V001E11.M Thu Jun 13 16:09:46 2024
Raw
Abn
3894
9138
21467
1432
0
17366
1247
16878
1124
I
Result
Pass/Fail
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
REPORT ID: 24E186 Page 145 of 217
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24F03\RFV002.D
Acq On 3 Jun 2024 11:10 am
Sample CV001Ell16
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
2
LPriet
01
1. 00
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
1 I l,4-DIFLUOROBENZENE
2 T,M Chlorotrifluoroethylene
3 T,M Dichlorodifluoromethane
4 T,M 2-Chloro-1,l,l-trifluoroeth
5 P,T,M Chloromethane
6 C,T,M Vinyl chloride
7 T,M Bromomethane
8 T,M Chloroethane
9 T,M Dichlorofluoromethane
10 T,M Trichlorofluoromethane
11 T,M Acrolein
12 T,M l,l,2-Trichloro-1,2,2-trifl
13 T,M Acetone
14 C,T,M l,l-Dichloroethene
15 T,M tert-Butyl alcohol
16 T,M Iodomethane
17 T,M Methyl acetate
18 T,M Methylene chloride
19 T,M Carbon disulfide
20 T,M Acrylonitrile
21 T,M tert-Butyl methyl ether (MT
22 T,M trans-1,2-Dichloroethene
23 T,M Isopropyl ether (DIPE)
24 T,M Vinyl acetate
25 P,T,M l,l-Dichloroethane
26 T,M 2-Butanol
27 T,M tert-Butyl ethyl ether (ETB
28 T,M 2-Butanone
29 T,M 2,2-Dichloropropane
30 T,M cis-1,2-Dichloroethene
31 C,T,M Chloroform
32 T,M Bromochloromethane
33 T,M Tetrahydrofuran
34 S Dibromofluoromethane
35 T,M 1, 1, 1-Trichloroethane
36 T,M Cyclohexane
37 T,M 2, 2, 4-Trimethylpentane
38 T,M l,l-Dichloropropene
39 T,M Carbon tetrachloride
40 T,M tert-Amyl methyl ether (TAM
41 S l,2-Dichloroethane-d4
Amount Calc.
10.000 10.000
-1.000 0.000
10.000 12.167
-1.000 0.000
10.000 8.592
10.000 10.749
10.000 9.178
10.000 10.675
10.000 9.769
10.000 11.810
50.000 45.184
10.000 10.870
50.000 47.194
10.000 10.124
250.000 249.520
10.000 10.483
10.000 10.958
10.000 10.026
10.000 9.569
50.000 46.764
10.000 9.860
10.000 10.050
10.000 9.886
10.000 10.383
10.000 10.481
250.000 0.000
10.000 9.999
50.000 51. 613
10.000 10.889
10.000 10.069
10.000 10.700
10.000 10.380
10.000 9.435
10.000 10.389
10.000 11.296
10.000 10.368
10.000 0.000
10.000 9.704
10.000 11. 041
10.000 9.409
10.000 11.463
(#) -Out of Range
RFV002.D V001E11.M Thu Jun 13 16:09:55 2024
%Dev Area% Dev(min)
0.0
0.0
-21.7#
0.0
14.1
-7.5
8.2
-6.8
2.3
-18.1
9.6
-8.7
5.6
-1. 2
0.2
-4.8
-9.6
-0.3
4.3
6.5
1.4
-0.5
1.1
-3.8
-4.8
100.0#
0.0
-3.2
-8.9
-0.7
-7.0
-3.8
5.6
-3.9
-13.0
-3.7
100.0#
3.0
-10.4
5.9
-14.6
87
o
112
o
81
94
90
100
94
110
89
95
98
92
96
96
113
94
89
89
95
95
92
99
97
o
95
95
101
92
103
98
98
100
104
100
o
90
101
93
114
0.00
-2.08#
0.01
-2.53#
0.02
0.01
0.03
0.03
0.01
0.01
0.01
0.03
0.00
0.01
0.00
0.00
0.00
0.01
0.01
0.01
0.00
0.01
0.00
0.01
0.01
0.00
0.00
0.00
0.01
0.01
0.01
0.01
0.00
0.00
0.01
0.00
0.00
0.01
0.00
0.01
0.00
Page 1
REPORT ID: 24E186 Page 146 of 217
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24F03\RFV002.D
Acq On 3 Jun 2024 11:10 am
Sample CV001Ell16
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
2
LPriet
01
1.00
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Min. RRF
Max. RRF Dev
Mon May 13 13:20:11 2024
Multiple Level Calibration
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
42 T,M Benzene
43 T,M 1 /2-Dichloroethane
44 T,M Trichloroethene
45 T,M Methylcyclohexane
46 C/T,M 1 /2-Dichloropropane
47 T,M Bromodichloromethane
48 T,M 1/4-Dioxane
49 T,M D ibromome thane
50 T,M 2-Chloroethyl vinyl ether
51 T,M 4-Methyl-2-pentanone
52 T,M cis-1 /3-Dichloropropene
53 I CHLOROBENZENE-D5
54 S Toluene-d8
55 C/T,M Toluene
56 T,M Ethyl methacrylate
57 T,M trans-1 /3-Dichloropropene
58 T,M 1 /1 /2-Trichloroethane
59 T,M 2-Hexanone
60 T,M 1 /3-Dichloropropane
61 T,M Tetrachloroethene
62 T,M Dibromochloromethane
63 T,M 1 /2-Dibromoethane
64 T,M 1-Chlorohexane
65 P/M Chlorobenzene
66 T,M 1 /1 /1 /2-Tetrachloroethane
67 C/T/M Ethylbenzene
68 T,M m-Xylene & p-Xylene
69 T,M o-Xylene
70 T,M Styrene
71 T,M Isopropylbenzene
72 I 1 /2-DICHLOROBENZENE-D4
73 P,T/M Bromoform
74 T,M trans-1 /4-Dichloro-2-butene
75 T,M 1 /1 /2 /2-Tetrachloroethane
76 S 4-Bromofluorobenzene
77 T,M 1 /2 /3-Trichloropropane
78 T,M n-Propylbenzene
79 T,M Bromobenzene
80 T,M 1 /3,5-Trimethylbenzene
10.000
10.000
10.000
10.000
10.000
10.000
200.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
20.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
9.995
11.471
10.311
10.242
9.888
10.671
190.320
10.822
12.387
49.782
10.294
10.000
9.617
10.016
9.840
10.321
10.040
46.092
10.278
10.469
10.494
9.960
9.813
10.026
10.660
10.327
21.440
10.417
10.310
10.398
10.000
9.809
9.600
9.269
9.448
9.639
9.370
10.007
9.201
(#) = Out of Range
RFV002.D V001E11.M Thu Jun 13 16:09:56 2024
0.1
-14.7
-3.1
-2.4
1.1
-6.7
4.8
-8.2
-23.9#
0.4
-2.9
0.0
3.8
-0.2
1.6
-3.2
-0.4
7.8
-2.8
-4.7
-4.9
0.4
1.9
-0.3
-6.6
-3.3
-7.2
-4.2
-3.1
-4.0
0.0
1.9
4.0
7.3
5.5
3.6
6.3
-0.1
8.0
93
108
93
99
93
104
93
105
118
100
96
90
93
94
96
99
97
97
100
97
103
96
91
94
100
95
100
99
97
96
100
114
106
104
104
103
96
104
95
0.00
0.00
0.02
0.00
0.00
0.00
-0.01
0.00
0.00
0.02
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.00
0.01
0.00
0.00
0.01
0.00
0.00
0.00
0.01
0.00
0.01
0.00
0.01
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Page 2
REPORT ID: 24E186 Page 147 of 217
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24F03\RFV002.D
Acq On 3 Jun 2024 11:10 am
Sample CV001E1116
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
2
LPriet
01
1. 00
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
T,M 2-Chlorotoluene 10.000 9.891 1.1 103 0.01
T,M 4-Chlorotoluene 10.000 9.327 6.7 95 0.01
T,M tert-Butylbenzene 10.000 9.203 8.0 95 0.00
T,M 1, 2, 4-Trimethylbenzene 10.000 9.202 8.0 94 0.00
T,M sec-Butylbenzene 10.000 9.187 8.1 95 0.00
T,M p-Isopropyltoluene 10.000 9.232 7.7 96 0.00
T,M 1 /3-Dichlorobenzene 10.000 9.783 2.2 101 0.00
T,M 1, 2, 3-Trimethylbenzene 10.000 9.294 7.1 98 0.00
T,M 1 /4-Dichlorobenzene 10.000 9.742 2.6 102 0.00
T,M n-Butylbenzene 10.000 9.343 6.6 96 0.01
T,M 1 /2-Dichlorobenzene 10.000 9.933 0.7 106 0.00
T,M 1 /2-Dibromo-3-chloropropane 10.000 8.795 12.1 106 0.01
T,M 1 /2 /4-Trichlorobenzene 10.000 9.561 4.4 100 0.01
T,M Hexachlorobutadiene 10.000 9.338 6.6 93 0.01
T,M Naphthalene 10.000 8.938 10.6 96 0.01
T,M 1 /2 /3-Trichlorobenzene 10.000 9.426 5.7 99 0.01
(#) = Out of Range
RFV002.D V001E11.M
SPcc's out = a CCC's out = a
Thu Jun 13 16:09:56 2024 Page 3
REPORT ID: 24E186 Page 148 of 217
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24F03\RFV002.D
Acq On 3 Jun 2024 11:10 am
Sample CV001Ell16
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
2
LPriet
01
1. 00
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound
1 I l,4-DIFLUOROBENZENE
2 T,M Chlorotrifluoroethylene
3 T,M Dichlorodifluoromethane
4 T,M 2-Chloro-1,l,l-trifluoroeth
5 P,T,M Chloromethane
6 C,T,M vinyl chloride
7 T,M Bromomethane
8 T,M Chloroethane
9 T,M Dichlorofluoromethane
10 T,M Trichlorofluoromethane
11 T,M Acrolein
12 T,M l,l,2-Trichloro-1,2,2-trifl
13 T,M Acetone
14 C,T,M l,l-Dichloroethene
15 T,M tert-Butyl alcohol
16 T,M ~odomethane
17 T,M Methyl acetate
18 T,M Methylene chloride
19 T,M Carbon disulfide
20 T,M Acrylonitrile
21 T,M tert-Butyl methyl ether (MT
22 T,M trans-1,2-Dichloroethene
23 T,M Isopropyl ether (DIPE)
24 T,M Vinyl acetate
25 P,T,M l,l-Dichloroethane
26 T,M 2-Butanol
27 T,M tert-Butyl ethyl ether {ETB
28 T,M 2-Butanone
29 T,M 2,2-Dichloropropane
30 T,M cis-1,2-Dichloroethene
31 C,T,M Chloroform
32 T,M Bromochloromethane
33 T,M Tetrahydrofuran
34 S Dibromofluoromethane
35 T,M l,l,l-Trichloroethane
36 T,M Cyclohexane
37 T,M 2,2,4-Trimethylpentane
38 T,M l,l-Dichloropropene
39 T,M Carbon tetrachloride
40 T,M tert-Amyl methyl ether (TAM
41 S 1,2-Dichloroethane-d4
AvgRF
1.000
0.000
0.268
0.000
0.375
0.312
0.396
0.226
0.643
0.422
0.022
0.211
0.037
0.533
0.011
0.572
0.100
0.428
1.140
0.046
0.525
0.514
1. 098
0.377
0.601
0.000
0.787
0.056
0.505
0.414
0.612
0.240
0.035
0.310
0.512
0.499
0.000
0.174
0.382
0.612
0.211
50% Max. R.T. Dev 0.16min
200%
CCRF
1.000
0.000
0.326
0.000
0.322
0.335
0.340
0.242
0.628
0.499
0.020
0.229
0.034
0.540
0.011
0.599
0.109
0.429
1.091
0.043
0.517
0.516
1. 085
0.391
0.630
0.009
0.787
0.058
0.550
0.416
0.655
0.250
0.033
0.322
0.579
0.517
0.025
0.169
0.421
0.576
0.242
%Dev Area% Dev(min)
0.0
0.0
-21. 6#
0.0
14.1
-7.4
14.1
-7.1
2.3
-18.2
9.1
-8.5
8.1
-1.3
0.0
-4.7
-9.0
-0.2
4.3
6.5
1.5
-0.4
1.2
-3.7
-4.8
0.0
0.0
-3.6
-8.9
-0.5
-7.0
-4.2
5.7
-3.9
-13.1
-3.6
0.0
2.9
-10.2
5.9
-14.7
87
0#
112
0#
81
94
90
100
94
110
89
95
98
92
96
96
113
94
89
89
95
95
92
99
97
0#
95
95
101
92
103
98
98
100
104
100
0#
90
101
93
114
0.00
-2.08#
0.01
-2.53#
0.02
0.01
0.03
0.03
0.01
0.01
0.01
0.03 '
0.00
0.01
0.00
0.00
0.00
0.01
0.01
0.01
0.00
0.01
0.00
0.01
0.01
0.00
0.00
0.00
0.01
0.01
0.01
0.01
0.00
0.00
0.01
0.00
0.00
0.01
0.00
0.01
0.00
(#) = Out of Range
RFV002.D V001E11.M Thu Jun 13 16:10:02 2024 Page 1
REPORT ID: 24E186 Page 149 of 217
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24F03\RFV002.D
Acq On 3 Jun 2024 11:10 am
Sample CV001Ell16
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
2
LPriet
01
1. 00
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound
42 T,M Benzene
43 T,M l,2-Dichloroethane
44 T,M Trichloroethene
45 T,M Methylcyclohexane
46 C,T,M l,2-Dichloropropane
47 T,M Bromodichloromethane
48 T,M l,4-Dioxane
49 T,M Dibromomethane
50 T,M 2-Chloroethyl vinyl ether
51 T,M 4-Methyl-2-pentanone
52 T,M cis-1,3-Dichloropropene
53 I CHLOROBENZENE-D5
54 S Toluene-d8
55 C,T,M Toluene
56 T,M Ethyl methacrylate
57 T,M trans-1,3-Dichloropropene
58 T,M l,l,2-Trichloroethane
59 T,M 2-Hexanone
60 T,M l,3-Dichloropropane
61 T,M Tetrachloroethene
62 T,M Dibromochloromethane
63 T,M l,2-Dibromoethane
64 T,M 1-Chlorohexane
65 P,M Chlorobenzene
66 T,M l,l,l,2-Tetrachloroethane
67 C,T,M Ethylbenzene
68 T,M m-Xylene & p-Xylene
69 T,M o-Xylene
70 T,M Styrene
71 T,M Isopropylbenzene
72 I 1 /2-DICHLOROBENZENE-D4
73 P,T,M Bromoform
74 T,M trans-1,4-Dichloro-2-butene
75 T,M l,l,2,2-Tetrachloroethane
76 S 4-Bromofluorobenzene
77 T,M l,2,3-Trichloropropane
78 T,M n-Propylbenzene
79 T,M Bromobenzene
80 T,M 1 /3,5-Trimethylbenzene
AvgRF
1. 336
0.269
0.346
0.549
0.299
0.415
0.001
0.141
0.076
0.136
0.465
1.000
1.499
1.776
0.266
0.413
0.233
0.090
0.395
0.369
0.284
0.230
0.767
1.059
0.326
2.027
1.484
1.527
1.184
2.012
1.000
0.350
0.173
0.666
1. 362
0.170
6.502
1.029
4.155
50% Max. R.T. Dev 0.16min
200%
CCRF
1. 335
0.309
0.356
0.562
0.296
0.443
0.001
0.153
0.094
0.147
0.479
1.000
1.441
1. 779
0.262
0.426
0.233
0.097
0.406
0.386
0.298
0.229
0.752
1. 061
0.348
2.093
1. 591
1.591
1. 220
2.092
1.000
0.387
0.166
0.617
1. 287
0.164
6.092
1. 029
3.822
%Dev Area% Dev(min)
0.1
-14.9
-2.9
-2.4
1.0
-6.7
0.0
-8.5
-23.7#
-8.1
-3.0
0.0
3.9
-0.2
1.5
-3.1
0.0
-7.8
-2.8
-4.6
-4.9
0.4
2.0
-0.2
-6.7
-3.3
-7.2
-4.2
-3.0
-4.0
0.0
-10.6
4.0
7.4
5.5
3.5
6.3
0.0
8.0
93
108
93
99
93
104
93
105
118
100
96
90
93
94
96
99
97
97
100
97
103
96
91
94
100
95
100
99
97
96
100
114
106
104
104
103
96
104
95
0.00
0.00
0.02
0.00
0.00
0.00
-0.01
0.00
0.00
0.02
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.01
0.00
0.01
0.00
0.00
0.01
0.00
0.00
0.00
0.01
0.00
0.01
0.00
0.01
0.01
0.00
0.00
0.00
0.00
0.00
0.00
0.00
(#) = Out of Range
RFV002.D V001E11.M Thu Jun 13 16:10:05 2024 Page 2
REPORT ID: 24E186 Page 150 of 217
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24F03\RFV002.D
Aeq On 3 Jun 2024 11:10 am
Sample CV001Ell16
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
2
LPriet
01
1. 00
Min. RRF
Max. RRF Dev
0.000 Min. Rel. Area
20% Max. Rel. Area
50% Max. R.T. Dev 0.16min
200%
Compound AvgRF CCRF %Dev Area% Dev(min)
T,M 2-Chlorotoluene 3.915 3.872 1.1 103 0.01
T,M 4-Chlorotoluene 3.466 3.233 6.7 95 0.01
T,M tert-Butylbenzene 0.871 0.802 7.9 95 0.00
T,M 1,2,4-Trimethylbenzene 4.065 3.740 8.0 94 0.00
T,M see-Butylbenzene 5.711 5.247 8.1 95 0.00
T,M p-Isopropyltoluene 4.403 4.065 7.7 96 0.00
T,M 1,3-Diehlorobenzene 1.955 1. 912 2.2 101 0.00
T,M 1,2,3-Trimethylbenzene 3.795 3.527 7.1 98 0.00
T,M 1,4-Diehlorobenzene 1.916 1. 867 2.6 102 0.00
T,M n-Butylbenzene 4.560 4.260 6.6 96 0.01
T,M 1,2-Diehlorobenzene 1.602 1. 591 0.7 106 0.00
T,M 1,2-Dibromo-3-ehloropropane 0.095 0.089 6.3 106 0.01
T,M 1,2,4-Triehlorobenzene 1.169 1.118 4.4 100 0.01
T,M Hexaehlorobutadiene 0.697 0.651 6.6 93 0.01
T,M Naphthalene 1.365 1. 220 10.6 96 0.01
T,M 1,2,3-Trichlorobenzene 0.881 0.830 5.8 99 0.01
(#) = Out of Range
RFV002.D V001E11.M
SPCC's out = 0 CCC's out = 0
Thu Jun 13 16:10:07 2024 Page 3
REPORT ID: 24E186 Page 151 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24F03\RFV002.D
Acq On 3 Jun 2024 11:10 am
Sample CV001Ell16
Vial:
Operator:
2
LPriet
01
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: Jun 3 11:32 2024 Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Internal Standards R.T. QIon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
72) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
3) Dichlorodifluoromethane
5) Chloromethane
6) Vinyl chloride
7) Bromomethane
8) Chloroethane
9) Dichlorofluoromethane
10) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17} Methyl acetate
18) Methylene chloride
19) Carbon disulfide
20) Acrylonitrile
21) tert-Butyl methyl ether (M
22) trans-1,2-Dichloroethene
23) Isopropyl ether (DIPE)
24) Vinyl acetate
25) 1,1-Dichloroethane
27) tert-Butyl ethyl ether (ET
28) 2-Butanone
29) 2,2-Dichloropropane
30) cis-1,2-Dichloroethene
31) Chloroform
8.55 114
13.71 117
18.69 152
7.23
7.97
11.03
16.01
2.18
2.49
2.62
3.17
3.21
3.29
3.57
4.00
4.09
4.06
4.23
4.34
4.63
4.65
4.87
4.89
5.03
5.06
5.26
5.67
5.83
5.83
6.23
6.41
6.63
6.69
6.91
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
142
43
49
76
53
73
61
45
43
63
59
43
77
96
83
803255
669938
282761
10.00 ug/l
10.00 ug/l
10.00 ug/l
258290 10.39
Recovery =
194379 11.46
Recovery =
965494 9.62
Recovery =
363855 9.45
Recovery =
ug/l
103.90%
ug/l
114.60%
ug/l
96.20%
ug/l
94.50%
0.00
0.00
0.01
0.00
0.00
0.00
0.00
261522
258541
269414
273165
194078
504432
400474
12.17 ug/l
8.59 ug/l
10.75 ug/l
9.18 ug/l
10.67 ug/l
Qvalue
99
99
100
100
94
81523
184192
138370
433703
223118
481520
87607
344607
876543
173945
415442
414802
871912
314339
505867
631869
232206
441891
334536
526338
9.77 ug/l
11.81 ug/l
45.18 ug/l
10.87 ug/l
47.19 ug/l
10.12 ug/l
249.52 ug/l
10.48 ug/l
10.96 ug/l
10.03 ug/l
9.57 ug/l
46.76 ug/l
9.86 ug/l
10.05 ug/l
9.89 ug/l
10.38 ug/l
10.48 ug/l
10.00 ug/l
51. 61 ug/l
10.89 ug/l
10.07 ug/l
10.70 ug/l
99
100
92
99
91
98
86
95
100
100
100
98
97
98
98
99
99
99
99
98
98
99
(#) = qualifier out of range (m) = manual integration
RFV002.D V001E11.M Thu Jun 13 16:10:17 2024 Page 1
REPORT ID: 24E186 Page 152 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24F03\RFV002.D
Acq On 3 Jun 2024 11:10 am
Sample CV001E1116
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
2
LPriet
01
1. 00
Quant Time: Jun 3 11:32 2024 Quant Results File: V001El1.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Cone Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) l,l,l-Trichloroethane
36) Cyclohexane
38) l,l-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) Benzene
43) l,2-Dichloroethane
44) Trichloroethene
45) Methylcyclohexane
46) l,2-Dichloropropane
47) Bromodichloromethane
48) l,4-Dioxane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-l,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) l,l,2-Trichloroethane
59) 2-Hexanone
60) l,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
63) l,2-Dibromoethane
64) 1-Chlorohexane
65) Chlorobenzene
66) l,l,l,2-Tetrachloroethane
67) Ethylbenzene
68) m-Xylene & p-Xylene
69) o-Xylene
70) Styrene
71) Isopropylbenzene
73) Bromoform
74) trans-1,4-Dichloro-2-buten
75) l,l,2,2-Tetrachloroethane
77) 1,2,3-Trichloropropane
78) n-Propylbenzene
79) Bromobenzene
7.15
7.20
7.51
7.52
7.73
7.88
7.89
8.13
8.10
9.08
9.17
9.35
9.73
9.77
9.82
10.23
10.28
10.62
11.17
11.46
11.48
11. 74
11. 77
12.19
12.31
12.66
13.03
13.31
13.79
13.86
13.88
14.02
14.84
14.91
15.52
15.56
15.62
15.86
16.14
16.29
16.38
49
42
97
84
110
119
73
78
62
130
83
63
83
88
93
63
43
75
91
69
75
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
53
83
110
91
156
200521
26850
464881
415571
135751
338485
462593
1072629
248246
286206
451621
237410
355645
18708
122559
75477
590919
384636
1191655
175675
285410
156387
324476
271741
258897
199545
153486
504115
711126
232875
1402159
2131154
1065676
817588
1401466
109557
46831
174485
46421
1722628
291059
(#) = qualifier out of range (m) = manual integration
RFV002.D V001E11.M Thu Jun 13 16:10:17 2024
10.38 ug/l
9.44 ug/l
11. 30 ug/l
10.37 ug/l
9.70 ug/l
11.04 ug/l
9.41 ug/l
10.00 ug/l
11.47 ug/l
10.31 ug/l
10.24 ug/l
9.89 ug/l
10.67 ug/l
190.32 ug/l
10.82 ug/l
12.39 ug/l
49.78 ug/l
10.29 ug/l
10.02 ug/l
9.84 ug/l
10.32 ug/l
10.04 ug/l
46.09 ug/l
10.28 ug/l
10.47 ug/l
10.49 ug/l
9.96 ug/l
9.81 ug/l
10.03 ug/l
10.66 ug/l
10.33 ug/l
21.44 ug/l
10.42 ug/l
10.31 ug/l
10.40 ug/l
9.81 ug/l
9.60 ug/l
9.27 ug/l
9.64 ug/l
9.37 ug/l
10.01 ug/l
Qvalue
100
93
98
98
97
99
100
100
100
98
99
94
99
94
98
99
97
98
99
93
96
99
96
100
99
100
99
99
100
100
97
97
98
99
99
98
100
100
100
99
99
Page 2
REPORT ID: 24E186 Page 153 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24F03\RFV002.D
Acq On 3 Jun 2024 11:10 am
Sample CV001Ell16
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
TBA
Vial:
Operator:
Inst
Multiplr:
2
LPriet
01
1. 00
Quant Time: Jun 3 11:32 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Cone Unit
80 ) l,3,5-Trimethylbenzene 16.60 105 1080833 9.20 ug/l
81) 2-Chlorotoluene 16.65 91 1094851 9.89 ug/l
82) 4-Chlorotoluene 16.73 91 914027 9.33 ug/l
83) tert-Butylbenzene 17.28 134 226788 9.20 ug/l
84) l,2,4-Trimethylbenzene 17.36 105 1057657 9.20 ug/l
85) see-Butylbenzene 17.65 105 1483572 9.19 ug/l
86) p-Isopropyltoluene 17.88 119 1149283 9.23 ug/l
87) l,3-Diehlorobenzene 18.02 146 540671 9.78 ug/l
88) l,2,3-Trimethylbenzene 18.13 105 997247 9.29 ug/l
89 ) l,4-Diehlorobenzene 18.19 146 527909 9.74 ug/l
90) n-Butylbenzene 18.50 91 1204670 9.34 ug/l
91) l,2-Diehlorobenzene 18.72 146 449866 9.93 ug/l
92) l,2-Dibromo-3-ehloropropan 19.73 157 25269 8.79 ug/l
93) l,2,4-Triehlorobenzene 20.81 180 316133 9.56 ug/l
94) Hexaehlorobutadiene 20.97 225 183950 9.34 ug/l
95) Naphthalene 21.15 128 344951 8.94 ug/l
96) 1, 2, 3-Triehlorobenzene 21.47 180 234789 9.43 ug/l
(#) = qualifier out of range (m) = manual integration
RFV002.D V001E11.M Thu Jun 13 16:10:18 2024
Qvalue
100
99
99
94
99
99
99
98
99
99
99
99
99
98
97
100
99
Page 3
REPORT ID: 24E186 Page 154 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24F03\RFV002.D
Aeq On 3 Jun 2024 11:10 am
Sample CV001Ell16
Mise 10ppb 8260/S0ppb KET-AA/2S0ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
2
LPriet
01
1.00
Quant Time: Jun 3 11:32 2024 Quant Results File: V001E11.RES
Method
Title
Last Update
Response via
1900000
1800000
1700000
1600000
1500000
1400000
1300000
1200000
1100000
1000000
900000
800000
700000
600000
500000
400000
300000
200000
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 2Smls
Mon May 13 13:20:11 2024
Initial Calibration
11(,;: Kt-VUU2.LJ
10000: I~M I ~ " ~ l.. 1. ,_ .' lj~ tL ~
trime--> 2.:>0 3.bb 4.bb 5.bb 6.bb 7.bb 8.bb 9.bo 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.0020.00 21.00
RFV002.D V001E11.M Thu Jun 13 16:10:21 2024 Page 4
REPORT ID: 24E186 Page 155 of 217
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24F03\RFV025.D
Acq On 3 Jun 2024 10:42 pm
Sample EV001Ell16
Misc 10ppb 8260/50ppb KET-AA!250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
25
LPriet
01
1. 00
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound
1 I l,4-DIFLUOROBENZENE
2 T,M Chlorotrifluoroethylene
3 T,M Dichlorodifluoromethane
4 T,M 2-Chloro-1,l,l-trifluoroeth
5 P,T,M Chloromethane
6 C,T,M Vinyl chloride
7 T,M Bromomethane
8 T,M Chloroethane
9 T,M Dichlorofluoromethane
10 T,M Trichlorofluoromethane
11 T,M Acrolein
12 T,M l,l,2-Trichloro-1,2,2-trifl
13 T,M Acetone
14 C,T,M l,l-Dichloroethene
15 T,M tert-Butyl alcohol
16 T,M Iodomethane
17 T,M Methyl acetate
18 T,M Methylene chloride
19 T,M Carbon disulfide
20 T,M Acrylonitrile
21 T,M tert-Butyl methyl ether (MT
22 T,M trans-1,2-Dichloroethene
23 T,M Isopropyl ether (DIPE)
24 T,M Vinyl acetate
25 P,T,M l,l-Dichloroethane
26 T,M 2-Butanol
27 T,M tert-Butyl ethyl ether (ETB
28 T,M 2-Butanone
29 T,M 2,2-Dichloropropane
30 T,M cis-1,2-Dichloroethene
31 C,T,M Chloroform
32 T,M Bromochloromethane
33 T,M Tetrahydrofuran
34 S Dibromofluoromethane
35 T,M l,l,l-Trichloroethane
36 T,M Cyclohexane
37 T,M 2,2,4-Trimethylpentane
38 T,M 1,1-Dichloropropene
39 T,M Carbon tetrachloride
40 T,M tert-Amyl methyl ether (TAM
41 S l,2-Dichloroethane-d4
Amount Calc.
10.000 10.000
-1.000 0.000
10.000 10.992
-1. 000 O. 000
10.000 8.712
10.000 10.200
10.000 9.267
10.000 10.708
10.000 9.403
10.000 11.048
50.000 44.555
10.000 10.343
50.000 46.478
10.000 9.688
250.000 205.707
10.000 10.592
10.000 11.755
10.000 10.154
10.000 9.125
50.000 48.463
10.000 9.949
10.000 9.913
10.000 10.115
10.000 9.809
10.000 10.020
250.000 0.000
10.000 9.862
50.000 49.599
10.000 9.281
10.000 10.291
10.000 10.625
10.000 10.451
10.000 9.392
10.000 10.272
10.000 10.668
10.000 10.484
10.000 0.000
10.000 9.382
10.000 10.440
10.000 9.357
10.000 10.685
(ff) ~ Out of Range
RFV025.D V001E11.M Thu Jun 13 16:10:45 2024
%Dev Area% Dev(min)
0.0
0.0
-9.9
0.0
12.9
-2.0
7.3
-7.1
6.0
-10.5
10.9
-3.4
7.0
3.1
17.7
-5.9
-17.6
-1.5
8.8
3.1
0.5
0.9
-1. 2
1.9
-0.2
100.0#
1.4
0.8
7.2
-2.9
-6.3
-4.5
6.1
-2.7
-6.7
-4.8
100.0#
6.2
-4.4
6.4
-6.9
90
a
104
o
85
92
94
103
94
106
91
93
99
91
81
100
125
98
88
95
99
96
97
97
96
o
96
94
89
97
106
101
100
102
102
104
o
90
98
95
109
0.02
-2.08#
0.01
-2.53#
0.03
0.01
0.02
0.02
0.02
0.00
0'.02
0.02
0.00
0.02
0.02
0.02
0.02
0.01
0.02
0.01
0.00
0.01
0.00
0.02
0.01
0.00
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.00
0.01
0.01
0.01
0.01
0.01
0.01
0.00
Page 1
REPORT ID: 24E186 Page 156 of 217
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24F03\RFV025.D
Acq On 3 Jun 2024 10:42 pm
Sample EV001Ell16
Misc 10ppb 8260/50ppb KET-AA!250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
25
LPriet
01
1. 00
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Min. RRF
Max. RRF Dev
Mon May 13 13:20:11 2024
Multiple Level Calibration
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
42 T,M Benzene
43 T,M 1,2-Dichloroethane
44 T,M Trichloroethene
45 T,M Methylcyclohexane
46 C,T,M 1,2-Dichloropropane
47 T,M Bromodichloromethane
48 T,M 1,4-Dioxane
49 T,M Dibromomethane
50 T,M 2-Chloroethyl vinyl ether
51 T,M 4-Methyl-2-pentanone
52 T,M cis-1,3-Dichloropropene
53 I CHLOROBENZENE-D5
54 S Toluene-d8
55 C,T,M Toluene
56 T,M Ethyl methacrylate
57 T,M trans-1,3-Dichloropropene
58 T,M 1,1,2-Trichloroethane
59 T,M 2-Hexanone
60 T,M 1,3-Dichloropropane
61 T,M Tetrachloroethene
62 T,M Dibromochloromethane
63 T,M 1,2-Dibromoethane
64 T,M 1-Chlorohexane
65 P,M Chlorobenzene
66 T,M 1,1,1,2-Tetrachloroethane
67 C,T,M Ethylbenzene
68 T,M m-Xylene & p-Xylene
69 T,M o-Xylene
70 T,M Styrene
71 T,M Isopropylbenzene
72 I 1,2-DICHLOROBENZENE-D4
73 P,T,M Bromoform
74 T,M trans-1,4-Dichloro-2-butene
75 T,M 1,1,2 ,2-Tetrachloroethane
76 S 4-Bromofluorobenzene
77 T,M 1,2,3-Trichloropropane
78 T,M n-Propylbenzene
79 T,M Bromobenzene
80 T,M 1,3,5-Trimethylbenzene
10.000
10.000
10.000
10.000
10.000
10.000
200.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
50.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
20.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
9.884
11. 069
10.327
10.241
9.830
10.464
158.463
10.852
12.557
49.691
10.026
10.000
9.723
10.143
10.072
10.147
10.545
46.985
10.391
10.271
10.730
10.403
9.350
10.187
10.745
10.140
20.688
10.354
10.103
9.934
10.000
9.681
8.677
9.341
9.723
9.470
9.006
9.996
8.913
(#) = Out of Range
RFV025.D V001E11.M Thu Jun 13 16:10:46 2024
1.2
-10.7
-3.3
-2.4
1.7
-4.6
20.8#
-8.5
-25.6#
0.6
-0.3
0.0
2.8
-1.4
-0.7
-1. 5
-5.4
6.0
-3.9
-2.7
-7.3
-4.0
6.5
-1. 9
-7.4
-1.4
-3.4
-3.5
-1. 0
0.7
0.0
3.2
13.2
6.6
2.8
5.3
9.9
0.0
10.9
95
108
96
103
95
105
80
109
123
103
97
92
96
97
100
98
104
100
102
97
107
102
88
96
103
95
98
100
96
93
101
115
97
106
109
103
94
106
94
0.00
0.01
0.02
0.00
0.02
0.00
0.00
0.01
0.00
0.02
0.01
0.01
0.00
0.00
0.00
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.00
0.01
0.01
0.01
0.00
0.01
0.01
0.01
0.01
0.01
0.00
0.00
0.01
0.01
0.01
0.01
Page 2
REPORT ID: 24E186 Page 157 of 217
81
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96
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24F03\RFV025.D
Acq On 3 Jun 2024 10:42 pm
Sample EV001Ell16
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
25
LPriet
01
1. 00
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound Amount Calc. %Dev Area% Dev(min)
T,M 2-Chlorotoluene 10.000 9.478 5.2 101 0.01
T,M 4-Chlorotoluene 10.000 9.361 6.4 97 0.01
T,M tert-Butylbenzene 10.000 8.724 12.8 91 0.01
T,M 1 /2 /4-Trimethylbenzene 10.000 9.069 9.3 95 0.00
T,M sec-Butylbenzene 10.000 8.599 14.0 90 0.00
T,M p-Isopropyltoluene 10.000 8.697 13.0 92 0.01
T,M 1 /3-Dichlorobenzene 10.000 9.666 3.3 102 0.01
T,M 1 /2 /3-Trimethylbenzene 10.000 9.287 7.1 100 0.01
T,M 1 /4-Dichlorobenzene 10.000 9.558 4.4 102 0.01
T,M n-Butylbenzene 10.000 8.800 12.0 92 0.01
T,M 1 /2-Dichlorobenzene 10.000 9.777 2.2 106 0.00
T,M 1 /2-Dibromo-3-chloropropane 10.000 9.072 9.3 112 0.00
T,M 1 /2 /4-Trichlorobenzene 10.000 9.335 6.6 100 0.01
T,M Hexachlorobutadiene 10.000 8.451 15.5 86 0.01
T,M Naphthalene 10.000 9.520 4.8 104 0.01
T,M 1 /2 /3-Trichlorobenzene 10.000 9.563 4.4 102 0.00
(#) = Out of Range
RFV025.D V001E11.M
SPCC's out = 0 CCC's out = 0
Thu Jun 13 16:10:46 2024 Page 3
REPORT ID: 24E186 Page 158 of 217
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24F03\RFV025.D
Acq On 3 Jun 2024 10:42 pm
Sample EV001Ell16
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
25
LPriet
01
1. 00
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
Compound
1 I l,4-DIFLUOROBENZENE
2 T,M Chlorotrifluoroethylene
3 T,M Dichlorodifluoromethane
4 T,M 2-Chloro-1,l,l-trifluoroeth
5 P,T,M Chloromethane
6 C,T,M Vinyl chloride
7 T,M Bromomethane
8 T,M Chloroethane
9 T,M Dichlorofluoromethane
10 T,M Trichlorofluoromethane
11 T,M Acrolein
12 T,M l,l,2-Trichloro-1,2,2-trifl
13 T,M Acetone
14 C,T,M l,l-Dichloroethene
15 T,M tert-Butyl alcohol
16 T,M Iodomethane
17 T,M Methyl acetate
18 T,M Methylene chloride
19 T,M Carbon disulfide
20 T,M Acrylonitrile
21 T,M tert-Butyl methyl ether (MT
22 T,M trans-1,2-Dichloroethene
23 T,M Isopropyl ether (DIPE)
24 T,M Vinyl acetate
25 P,T,M l,l-Dichloroethane
26 T,M 2-Butanol
27 T,M tert-Butyl ethyl ether (ETB
28 T,M 2-Butanone
29 T,M 2,2-Dichloropropane
30 T,M cis-1,2-Dichloroethene
31 C,T,M Chloroform
32 T,M Bromochloromethane
33 T,M Tetrahydrofuran
34 S Dibromofluoromethane
35 T,M l,l,l-Trichloroethane
36 T,M Cyclohexane
37 T,M 2,2,4-Trimethylpentane
38 T,M l,l-Dichloropropene
39 T,M Carbon tetrachloride
40 T,M tert-Amyl methyl ether (TAM
41 S l,2-Dichloroethane-d4
AvgRF
1. 000
0.000
0.268
0.000
0.375
0.312
0.396
0.226
0.643
0.422
0.022
0.211
0.037
0.533
0.011
0.572
0.100
0.428
1.140
0.046
0.525
0.514
1. 098
0.377
0.601
0.000
0.787
0.056
0.505
0.414
0.612
0.240
0.035
0.310
0.512
0.499
0.000
0.174
0.382
0.612
0.211
50% Max. R.T. Dev 0.16min
200%
CCRF
1. 000
0.000
0.294
0.000
0.326
0.318
0.343
0.242
0.604
0.466
0.020
0.218
0.034
0.517
0.009
0.606
0.117
0.434
1. 041
0.045
0.522
0.509
1.111
0.370
0.602
0.008
0.776
0.056
0.469
0.426
0.651
0.251
0.033
0.318
0.547
0.523
0.025
0.163
0.398
0.573
0.226
%Dev Area% Dev(min)
0.0
0.0
-9.7
0.0
13.1
-1. 9
13.4
-7.1
6.1
-10.4
9.1
-3.3
8.1
3.0
18.2
-5.9
-17.0
-1. 4
8.7
2.2
0.6
1.0
-1. 2
1.9
-0.2
0.0
1.4
0.0
7.1
-2.9
-6.4
-4.6
5.7
-2.6
-6.8
-4.8
0.0
6.3
-4.2
6.4
-7.1
90
0#
104
0#
85
92
94
103
94
106
91
93
99
91
81
100
125
98
88
95
99
96
97
97
96
0#
96
94
89
97
106
101
100
102
102
104
0#
90
98
95
109
0.02
-2.08#
0.01
-2.53#
0.03
0.01
0.02
0.02
0.02
0.00
0.02
0.02
0.00
0.02
0.02
0.02
0.02
0.01
0.02
0.01
0.00
0.01
0.00
0.02
0.01
0.00
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.00
0.01
0.01
0.01
0.01
0.01
0.01
0.00
(#) = Out of Range
RFV025.D V001E11.M Thu Jun 13 16:10:52 2024 Page 1
REPORT ID: 24E186 Page 159 of 217
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24F03\RFV025.D
Acq On 3 Jun 2024 10:42 pm
Sample EV001Ell16
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
25
LPriet
01
1. 00
Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
Min. RRF
Max. RRF Dev
0.000 Min. Rel. Area
20% Max. Rel. Area
Compound
42 T,M Benzene
43 T,M l,2-Dichloroethane
44 T,M Trichloroethene
45 T,M Methylcyclohexane
46 C,T,M l,2-Dichloropropane
47 T,M Bromodichloromethane
48 T,M l,4-Dioxane
49 T,M Dibromomethane
50 T,M 2-Chloroethyl vinyl ether
51 T,M 4-Methyl-2-pentanone
52 T,M cis-1,3-Dichloropropene
53 I CHLOROBENZENE-D5
54 S Toluene-d8
55 C,T,M Toluene
56 T,M Ethyl methacrylate
57 T,M trans-1,3-Dichloropropene
58 T,M l,l,2-Trichloroethane
59 T,M 2-Hexanone
60 T,M l,3-Dichloropropane
61 T,M Tetrachloroethene
62 T,M Dibromochloromethane
63 T,M l,2-Dibromoethane
64 T,M 1-Chlorohexane
65 P,M Chlorobenzene
66 T,M l,l,l,2-Tetrachloroethane
67 C,T,M Ethylbenzene
68 T,M m-Xylene & p-Xylene
69 T,M o-Xylene
70 T,M Styrene
71 T,M Isopropylbenzene
72 I l,2-DICHLOROBENZENE-D4
73 P,T,M Bromoform
74 T,M trans-1,4-Dichloro-2-butene
75 T,M l,l,2,2-Tetrachloroethane
76 S 4-Bromofluorobenzene
77 T,M l,2,3-Trichloropropane
78 T,M n-Propylbenzene
79 T,M Bromobenzene
80 T,M 1,3,5-Trimethylbenzene
AvgRF
1. 336
0.269
0.346
0.549
0.299
0.415
0.001
0.141
0.076
0.136
0.465
1.000
1.499
1. 776
0.266
0.413
0.233
0.090
0.395
0.369
0.284
0.230
0.767
1.059
0.326
2.027
1.484
1. 527
1.184
2.012
1.000
0.350
0.173
0.666
1. 362
0.170
6.502
1. 029
4.155
50% Max. R.T. Dev 0.16min
200%
CCRF
1. 320
0.298
0.357
0.562
0.294
0.434
0.001
0.153
0.095
0.147
0.466
1. 000
1.457
1. 801
0.268
0.419
0.245
0.099
0.410
0.379
0.305
0.239
0.717
1. 079
0.350
2.055
1. 535
1. 581
1.196
1. 999
1. 000
0.382
0.150
0.622
1. 324
0.161
5.856
1. 028
3.703
%Dev Area% Dev(min)
1.2
-10.8
-3.2
-2.4
1.7
-4.6
0.0
-8.5
-25.0#
-8.1
-0.2
0.0
2.8
-1. 4
-0.8
-1. 5
-5.2
-10.0
-3.8
-2.7
-7.4
-3.9
6.5
-1. 9
-7.4
-1. 4
-3.4
-3.5
-1. 0
0.6
0.0
-9.1
13.3
6.6
2.8
5.3
9.9
0.1
10.9
95
108
96
103
95
105
80
109
123
103
97
92
96
97
100
98
104
100
102
97
107
102
88
96
103
95
98
100
96
93
101
115
97
106
109
103
94
106
94
0.00
0.01
0.02
0.00
0.02
0.00
0.00
0.01
0.00
0.02
0.01
0.01
0.00
0.00
0.00
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.00
0.01
0.01
0.01
0.00
0.01
0.01
0.01
0.01
0.01
0.00
0.00
0.01
0.01
0.01
0.01
(#) = Out of Range
RFV025.D V001E11.M Thu Jun 13 16:10:55 2024 Page 2
REPORT ID: 24E186 Page 160 of 217
81
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96
Evaluate Continuing Calibration Report
Data File D:\HPCHEM\1\DATA\24F03\RFV025.D
Aeq On 3 Jun 2024 10:42 pm
Sample EVOOIEll16
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
Method
Title
D:\HPCHEM\l\METHODS\VOOIEll.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
Mon May 13 13:20:11 2024
Multiple Level Calibration
25
LPriet
01
1. 00
Min. RRF
Max. RRF Dev
0.000 Min. ReI. Area
20% Max. ReI. Area
50% Max. R.T. Dev 0.16min
200%
Compound AvgRF CCRF %Dev Area% Dev(min)
T,M 2-Chlorotoluene 3.915 3.710 5.2 101 0.01
T,M 4-Chlorotoluene 3.466 3.244 6.4 97 0.01
T,M tert-Butylbenzene 0.871 0.760 12.7 91 0.01
T,M l,2,4-Trimethylbenzene 4.065 3.686 9.3 95 0.00
T,M see-Butylbenzene 5.711 4.911 14.0 90 0.00
T,M p-Isopropyltoluene 4.403 3.829 13.0 92 0.01
T,M l,3-Diehlorobenzene 1.955 1. 889 3.4 102 0.01
T,M 1, 2, 3-Trimethylbenzene 3.795 3.524 7.1 100 0.01
T,M l,4-Diehlorobenzene 1.916 1.832 4.4 102 0.01
T,M n-Butylbenzene 4.560 4.013 12.0 92 0.01
T,M l,2-Diehlorobenzene 1.602 1. 566 2.2 106 0.00
T,M l,2-Dibromo-3-ehloropropane 0.095 0.092 3.2 112 0.00
T,M l,2,4-Triehlorobenzene 1.169 1.092 6.6 100 0.01
T,M Hexaehlorobutadiene 0.697 0.589 15.5 86 0.01
T,M Naphthalene 1. 365 1. 299 4.8 104 0.01
T,M 1, 2, 3-Triehlorobenzene 0.881 0.842 4.4 102 0.00
(#) = Out of Range
RFV025.D VOOIEll.M
sPCC's out = 0 CCC's out = 0
Thu Jun 13 16:10:57 2024 Page 3
REPORT ID: 24E186 Page 161 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24F03\RFV025.D
Acq On 3 Jun 2024 10:42 pm
Sample EV001Ell16
Vial:
Operator:
25
LPriet
01
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
Inst
Multiplr: 1. 00
MS Integration Params: RTE.P
Quant Time: Jun 3 23:04 2024 Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Internal Standards R.T. Qlon Response Conc Units Dev(Min)
1) l,4-DIFLUOROBENZENE
53) CHLOROBENZENE-D5
72) l,2-DICHLOROBENZENE-D4
System Monitoring Compounds
34) Dibromofluoromethane
Spiked Amount 10.000
41) l,2-Dichloroethane-d4
Spiked Amount 10.000
54) Toluene-d8
Spiked Amount 10.000
76) 4-Bromofluorobenzene
Spiked Amount 10.000
Target Compounds
3) Dichlorodifluoromethane
5) Chloromethane
6) Vinyl chloride
7) Bromomethane
8) Chloroethane
9) Dichlorofluoromethane
10) Trichlorofluoromethane
11) Acrolein
12) l,l,2-Trichloro-1,2,2-trif
13) Acetone
14) l,l-Dichloroethene
15) tert-Butyl alcohol
16) Iodomethane
17) Methyl acetate
18) Methylene chloride
19) Carbon disulfide
20) Acrylonitrile
21) tert-Butyl methyl ether (M
22) trans-1,2-Dichloroethene
23) Isopropyl ether (DIPE)
24) Vinyl acetate
25) l,l-Dichloroethane
27) tert-Butyl ethyl ether (ET
28) 2-Butanone
29) 2,2-Dichloropropane
30) cis-1,2-Dichloroethene
31) Chloroform
8.56 114
13.73 117
18.69 152
7.23
7.97
11.03
16.01
2.18
2.49
2.62
3.15
3.20
3.29
3.55
4.00
4.07
4.06
4.24
4.35
4.65
4.67
4.87
4.89
5.04
5.07
5.26
5.67
5.84
5.84
6.25
6.43
6.63
6.69
6.92
111
65
98
95
85
50
62
94
64
67
101
56
151
43
61
59
142
43
49
76
53
73
61
45
43
63
59
43
77
96
83
828597
679361
287981
10.00 ug/l
10.00 ug/l
10.00 ug/l
263458 10.27
Recovery =
186900 10.68
Recovery =
989922 9.72
Recovery =
381361 9.72
Recovery =
ug/l
102.70%
ug/l
106.80%
ug/l
97.20%
ug/l
97.20%
0.02
0.01
0.01
0.00
0.00
0.00
0.00
243715
270430
263701
284435
200828
500878
386456
10.99 ug/l
8.71 ug/l
10.20 ug/l
9.27 ug/l
10.71 ug/l
Qvalue
100
99
97
82923
180807
140571
428156
189744
501869
96945
359997
862309
185951
432435
422049
920192
306339
498888
642871
230185
388543
352695
539128
9.40 ug/l
11.05 ug/l
44.55 ug/l
10.34 ug/l
46.48 ug/l
9.69 ug/l
205.71 ug/l
10.59 ug/l
11. 76 ug/l
10.15 ug/l
9.13 ug/l
48.46 ug/l
9.95 ug/l
9.91 ug/l
10.11 ug/l
9.81 ug/l
10.02 ug/l
9.86 ug/l
49.60 ug/l
9.28 ug/l
10.29 ug/l
10.62 ug/l
100
96
99
97
96
99
94
99
81
98
99
99
99
99
94
99
98
99
99
99
100
99
100
99
(#) = qualifier out of range (m) = manual integration
RFV025.D V001E11.M Thu Jun 13 16:11:04 2024 Page 1
REPORT ID: 24E186 Page 162 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24F03\RFV025.D
Acq On 3 Jun 2024 10:42 pm
Sample EV001Ell16
Misc 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
(QT Reviewed)
Vial:
Operator:
Inst
Multiplr:
25
LPriet
01
1.00
Quant Time: Jun 3 23:04 2024 Quant Results File: V001E11.RES
Quant Method
Title
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Last Update
Response via
DataAcq Meth
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. Qlon Response Conc Unit
32) Bromochloromethane
33) Tetrahydrofuran
35) 1,1,1-Trichloroethane
36) Cyclohexane
38) 1,1-Dichloropropene
39) Carbon tetrachloride
40) tert-Amyl methyl ether (TA
42) Benzene
43) 1,2-Dichloroethane
44) Trichloroethene
45) Methylcyclohexane
46) 1,2-Dichloropropane
47) Bromodichloromethane
48) 1,4-Dioxane
49) Dibromomethane
50) 2-Chloroethyl vinyl ether
51) 4-Methyl-2-pentanone
52) cis-1,3-Dichloropropene
55) Toluene
56) Ethyl methacrylate
57) trans-1,3-Dichloropropene
58) 1,1,2-Trichloroethane
59) 2-Hexanone
60) 1,3-Dichloropropane
61) Tetrachloroethene
62) Dibromochloromethane
63) 1,2-Dibromoethane
64) 1-Chlorohexane
65) Chlorobenzene
66) 1,1,1,2-Tetrachloroethane
67) Ethylbenzene
68) m-Xylene & p-Xylene
69) o-Xylene
70) Styrene
71) Isopropylbenzene
73) Bromoform
74) trans-1,4-Dichloro-2-buten
75) 1,1,2,2-Tetrachloroethane
77) 1,2,3-Trichloropropane
78) n-Propylbenzene
79) Bromobenzene
7;15
7.21
7.51
7.54
7.73
7.89
7.89
8.13
8.12
9.08
9.17
9.36
9.73
9.79
9.83
10.23
10.28
10.63
11.17
11.46
11.49
11.76
11.77
12.20
12.31
12.68
13.05
13.31
13.79
13.88
13.89
14.02
14.84
14.91
15.53
15.56
15.64
15.86
16.16
16.30
16.39
49
42
97
84
110
119
73
78
62
130
83
63
83
88
93
63
43
75
91
69
75
97
43
76
164
129
107
91
112
131
91
91
91
104
105
173
53
83
110
91
156
208258
27569
452874
433483
135383
330144
474546
1094125
247109
295686
465846
243477
359722
16068
126782
78928
608384
386439
1223753
182338
284544
166567
336165
278611
257586
206907
162558
487112
732719
238022
1396147
2085369
1074201
812479
1357804
110066
43107
179081
46446
1686308
296116
(#) = qualifier out of range (m) = manual integration
RFV025.D V001E11.M Thu Jun 13 16:11:05 2024
10.45 ug/l
9.39 ug/l
10.67 ug/l
10.48 ug/l
9.38 ug/l
10.44 ug/l
9.36 ug/l
9.88 ug/l
11.07 ug/l
10.33 ug/l
10.24 ug/l
9.83 ug/l
10.46 ug/l
158.46 ug/l
10.85 ug/l
12.56 ug/l
49.69 ug/l
10.03 ug/l
10.14 ug/l
10.07 ug/l
10.15 ug/l
10.55 ug/l
46.99 ug/l
10.39 ug/l
10.27 ug/l
10.73 ug/l
10.40 ug/l
9.35 ug/l
10.19 ug/l
10.74 ug/l
10.14 ug/l
20.69 ug/l
10.35 ug/l
10.10 ug/l
9.93 ug/l
9.68 ug/l
8.68 ug/l
9.34 ug/l
9.47 ug/l
9.01 ug/l
10.00 ug/l
Qvalue
99
90
99
99
99
100
99
99
99
98
99
94
100
90
96
98
97
98
98
93
96
100
96
99
98
98
99
99
99
99
97
96
97
97
99
99
97
99
98
99
99
Page 2
REPORT ID: 24E186 Page 163 of 217
Quantitation Report (QT Reviewed)
Data File D:\HPCHEM\1\DATA\24F03\RFV025.D
Aeq On 3 Jun 2024 10:42 pm
Sample EV001Ell16
Mise 10ppb 8260/50ppb KET-AA/250ppb
MS Integration Params: RTE.P
TBA
Vial:
Operator:
Inst
Multiplr:
25
LPriet
01
1.00
Quant Time: Jun 3 23:04 2024 Quant Results File: V001E11.RES
Quant Method
Title
Last Update
Response via
DataAeq Meth
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
V001E11
Compound R.T. QIon Response Cone Unit
80) 1, 3, 5-Trimethylbenzene 16.62 105 1066396 8.91 ug/l
81) 2-Chlorotoluene 16.65 91 1068515 9.48 ug/l
82) 4-Chlorotoluene 16.73 91 934235 9.36 ug/l
83) tert-Butylbenzene 17.30 134 218950 8.72 ug/l
84) l,2,4-Trimethylbenzene 17.36 105 1061594 9.07 ug/l
85) see-Butylbenzene 17.65 105 1414209 8.60 ug/l
86) p-Isopropyltoluene 17.89 119 1102705 8.70 ug/l
87) l,3-Diehlorobenzene 18.04 146 544082 9.67 ug/l
88) l,2,3-Trimethylbenzene 18.14 105 1014989 9.29 ug/l
89 ) l,4-Diehlorobenzene 18.20 146 527499 9.56 ug/l
90) n-Butylbenzene 18.50 91 1155653 8.80 ug/l
91) l,2-Diehlorobenzene 18.72 146 450975 9.78 ug/l
92) l,2-Dibromo-3-ehloropropan 19.71 157 26597 9.07 ug/l
93) l,2,4-Triehlorobenzene 20.81 180 314364 9.33 ug/l
94) Hexaehlorobutadiene 20.97 225 169550 8.45 ug/l
95) Naphthalene 21.15 128 374179 9.52 ug/l
96) 1, 2, 3-Triehlorobenzene 21.47 180 242581 9.56 ug/l
(#) = qualifier out of range (m) = manual integration
RFV025.D V001E11.M Thu Jun 13 16:11:05 2024
Qvalue
98
98
99
97
98
100
98
99
99
99
98
100
99
100
97
100
99
Page 3
REPORT ID: 24E186 Page 164 of 217
Quantitation Report
Data File D:\HPCHEM\1\DATA\24F03\RFV025.D
Aeq On 3 Jun 2024 10:42 pm
Sample EV001Ell16
Mise 10ppb 8260/50ppb KET-AA/250ppb TBA
MS Integration Params: RTE.P
Vial:
Operator:
Inst
Multiplr:
25
LPriet
01
1. 00
Quant Time: Jun 3 23:04 2024 Quant Results File: V001E11.RES
Method
Title
Last Update
Response via
fA,bundance
1900000
1800000
1700000
1600000
1500000
1400000
1300000
1200000
1100000
1000000
900000
800000
700000
600000
500000
400000
300000
200000
D:\HPCHEM\1\METHODS\V001E11.M (RTE Integrator)
METHOD 8260 25mls
Mon May 13 13:20:11 2024
Initial Calibration
Ilv: Kt"VU:lO.U
r
100~ lAM / ~I ~ ~ \,","1~~\ ~~
Time-> 2.)0 3.bo 4.bo 5.bo 6.bo 7.bi> 8.bi> 9.bo 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.0020.0021.00
RFV025.D V001E11.M Thu Jun 13 16:11:08 2024 Page 4
REPORT ID: 24E186 Page 165 of 217
ANALYTICAL LOG(S)
REPORT ID: 24E186 Page 166 of 217
ANALYSIS RUN LOG
for
VOLATILES
Note: For samples and relevant QCs/Standards
analyzed, refer to attached analytical sequence.
Comments:
DATE
ICALID
NAME
DCC ~t
DCC 'IAI'D
DCC fj2610
DCC lc6T
BFB
%S IS/SURR.C.~
ICV/lCS~
SOP# Icv/lcs&AR>
I!l1 EMAX-8260 Rev. No. 10 ICV/lCS eZflO
D EMAX-8260C Rev. No.1 ICV/LCS ICef
IData File
D EMAX-8260SIM Rev. No.1 Folder
D EMAX-M8260SIM Rev. No. 0
D EMAX-TCPSIM Rev. No.2 pH strip
D EMAX-624 Rev. No.6 Chlorine strip
D EMAX-624.1 Rev. No.1 Methanol
NaHSO.
PURGE AMOUNT Reagent Water
D 5-mL Purge Sand
D lO-mL Purge
61 25-mL Purge
SAMPLE MATRIX
Page 27
Book": A01-076
Instrument No.: 01
Analytical Sequence: 2.l.ff'11
Method File: '1/0011:11
Analytical Batch: ..,001 En (p
INITIAL CALIBRATION REFERENCE
6/11121./
vool..f.ll
STANDARDS
10 Amount Cone.
lull (mg!L)
SVI-'i~_~g:Jl -iT ft: -0-0
-45-0.2 1.50 -".-01 50
~13-o.3 ,11 2~0
-3f)-02. I 60
-4"~03 , ISO
-8:J..-ol ". 15'0
~CI,:.-ol. , lag --()I I
-""..03 5 So
-l~-oa 5 5 D
, ·1"-62 6 150
lLfE-11
lOT # Syringe lot #
N/A ! ti&y..o~-Olf-U.-"
~ -011-12.. .. (,
-o~"'z.a
,~ -07.-1"1
'''''-23-00,
ELECTRONIC DATA ARCHIVAL
Location Date
D Soil (refer to sample weight log) HPCHEM_ VOA/TOOI
D Water Analyzed By: LAP
D pH <2. Outliers indicated on analytical sequence. Date: !7/1112."l
D Ci 2 <5ppm. Outliers indicated on analytical sequence. Disposed By: LAP
rJJ pH <2 and CI2 are not applicable. Date Disposed:
REPORT ID: 24E186 Page 167 of 217
Injection log
Directory: D:\HPCHEM\ 1 \DATA\24E11
Line Vial FileName Multiplier SampleName Misc Info Injected
1 1 REV195.D 1. BFB01E11 T/CHK 11 May 2024 10:20
2 2 REV196.D 1. V001 E111 0.03/0.15 0.3ppb 8260/1.5ppb KET -AAl7.5ppb TBA
3 3 REV197.D 1. V001 E112 0.05/0.25
11 May 2024 10:58
0.5ppb 8260/2.5ppb KET-AAl12.5ppb TBA
11 May 202411:27
4 4 REV198.D 1. V001E113 0.1/0.5 1 ppb 8260/5ppb KET -AAl25ppb TBA
5 5 REV199.D 1. V001E114 0.211.0
11 May 202411:56
2ppb 8260/10ppb KET -AAl50ppb TBA
6 6 REV200.D 1. V001 E115 0.5/2.5
11 May 202412:30
5ppb 8260/25ppb KET -AAl125ppb TBA
7 7 REV201.D 1. V001 E116 1.0/5.0
11 May 2024 12:59
10ppb 8260/50ppb KET -AAl250ppb TBA
8 8 REV202.D 1. V001 E117 2.0/10
11 May 2024 13:28
20ppb 8260/100ppb KET -AAl500ppb TBA
9 9 REV203.D 1. V001 E118 3.0/15
11 May 2024 13:58
30ppb 82601150ppb KET -AAl750ppb TBA
11 May 2024 14:27
10 10 REV204.D 1. V001 E119 5.0/25 50ppb 8260/250ppb KET -AAl125~pb TBA
11 ay 202414:56
11 11 REV205.D 1. VOO'l DE'1'1 '10 10/50 100ppb 8260/500ppb KET-AAl2500ppb TBA
11 May 2024 15:26
12 12 REV206.D 1. RINSE 11 May 2024 15:55
13 13 REV207.D 1. RINSE 11 May 2024 16:24
14 14 REV208.D 1. IV001E1101 1.0/5.0 9"'f'\ofofrtl '/.1'+ 1 Oppb 8260/50ppb KET -AAl250ppb TBA
11 May 2024 16:53
Page 1 13 May 202417:22 REPORT ID: 24E186 Page 168 of 217
ANALYSIS RUN lOG
for
VOLATilES
Note: For samples and relevant QCs/Standards
analyzed, refer to attached analytical sequence.
Comments:"
DATE
leAL 10
NAME
Dee
Dce
Dec
DCC
BFB
tS
IS/SURR. s$
($2
ICV/LCS .;''is
SOP# Icv/LCS",",
~ EMAX-8260 Rev. No. 10 levlLes 8z.G
D EMAX-8260C Rev. No.1 ICV/LCS ICet
ILJata ~lIe
D EMAX-8260SIM Rev. No.1 Folder
D EMAX-M8260SIM Rev. No. 0
D EMAX-TCPSIM Rev. No.2 pH strip
D EMAX-624 Rev. NO.6 Chlorine strip
D EMAX-624.1 Rev. No.1 Methanol
NaHSO.
PURGE AMOUNT Reagent Water
D 5-mL Purge Sand
D 10-mL Purge
~ 25-mL Purge
SAMPLE MATRIX
Page 28
Book#: A01-076
Instrument No.: 01
Analytical Sequence:
Method File: VOO'~II
Analytical Batch: '''00 II?" b2.
INITIAL CALIBRATION REFERENCE
S /11/2."
vaOl e-I I
STANDARDS
10 Amount Cone.
lull (mgfL\
I S'I' ... 'I , -rle"'liZ I ,.
:i~~ I ~ I -It°Z. I t; ... "'0\ I
• 61-ob 6 to
-l&.ob I; ~.
~ -""..01 e 2SO
lL4"~
LOT # Syringe Lot #
tJJA-iMSV-Db-O"-Il-"
~ ~ -11."",
2WQ -2.3--001
ELECTRONIC DATA ARCHIVAL
Location Date
D Soil (refer to sample weight log) HPCHEM_ VOA/TOOl
D Water Analyzed By: LAP
D pH <2. Outliers indicated on analytical sequence. Date:
D CI 2 <5ppm. Outliers indicated on analytical sequence. Disposed By:
~ pH <2 and CI2 are not applicable. Date Disposed: 5 L 1"\ 11..4
REPORT ID: 24E186 Page 169 of 217
Injection Log
Directory: D:\HPCHEM\ 1 \DATA\24E13
Line Vial FileName Multiplier SampleName Misc Info Injected
1 1 REV209.D 1. BFB01E12 T/CHK 13 May 202411:31
2 2 REV210.D 1. IV001 E11 02 1.0/5.0 10ppb 8260/50ppb KET -AAl250ppb TBA
13 May 2024 12:06
3 1 REV211.D 1. BFB01E13 T/CHK 13 May 2024 12:45
4 2 REV212.D 1. CV001E1101 10ppb 8260/50ppb KET -AAl250ppb TBA
13 May 202413:17
5 3 REV213.D 1. V001E13L 10ppb 8260/50ppb KET -AAl250ppb TBA
6 4 REV214.D 1.
13 May 2024 13:48
V001E13C 10ppb 8260/50ppb KET-AAl250ppb TBA
13 May 202414:17
7 5 REV215.D 1. RINSE 13 May 202414:47
8 6 REV216.D 1. V001E13B 25mL 13 May 202415:17
9 7 REV217.D 1. 24E021-01 25mL 13 May 2024 15:46
10 8 REV218.D 1. 24E021-11 25mL 13 May 202416:16
11 9 REV219.D 1. 24E072-05 25mL 13 May 2024 16:45
12 10 REV220.D 1. 24E021-04 25mL 13 May 202417:15
13 11 REV221.D 1. 24E021-05 25mL 13 May 2024 17:45
14 12 REV222.D 1. 24E021-06 25mL 13 May 202418:14
15 13 REV223.D 1. 24E021-07 25mL 13 May 2024 18:43
16 14 REV224.D 1. 24E021-08 25mL 13 May 202419:12
17 15 REV225.D 1. 24E021-09 25mL 13 May 202419:41
18 16 REV226.D 1. 24E021-10 25mL 13 May 2024 20:10
19 17 REV227.D 1. 24E021-12 25mL 13 May 2024 20:40
20 18 REV228.D 1. 24E021-14 25mL 13 May 2024 21 :09
21 19 REV229.D 1. 24E021-15 25mL 13 May 2024 21 :38
22 20 REV230.D 1. 24E021-16 25mL 13 May 2024 22:07
23 21 REV231.D 1. 24E072-01 25mL 13 May 2024 22:36
24 22 REV232.D 1. 24E072-02 25mL 13 May 2024 23:05
25 23 REV233.D 1. 24E072-03 25mL 13 May 2024 23:34
26 24 REV234.D 1. 24E072-04 25mL 14 May 2024 00:02
27 25 REV235.D 1. 24E021-02 25mL 14 May 2024 00:31
28 26 REV236.D 1. EV001E1101 10ppb 8260/50ppb KET -AAl250ppb TBA
14 May 2024 01 :00
29 27 REV237.D 1. EV001E1101 10ppb 8260/50ppb KET -AAl250ppb TBA
14 May 2024 01 :29
30 28 REV238.D 1. EV001E1101 10ppb 8260/50ppb KET -AAl250ppb TBA
14 May 2024 01 :58
31 29 REV239.D 1. RINSE 10ppb 8260/50ppb KET -AAl250ppb TBA
14 May 2024 02:26
32 30 REV240.D 1. RINSE 10ppb 8260/50ppb KET -AAl250ppb TBA
14 May 2024 02:55
Page 1 14 May 2024 10:44 REPORT ID: 24E186 Page 170 of 217
ANALYSIS RUN LOG
for
VOLATILES
Note: For samples and relevant QCs/Standards
analyzed, refer to attached analytical sequence:
Comments:
DATE
ICALID
NAME
c.s~
DCC 0, AS
DCC '1APD
DCC 9~"O
DCC "~1
BFB
ISISURR.
CS!2.
ICV/LCS GtI\S
SOP# ICV/LCS alUV
~ EMAX-8260 Rev. No. 10 ICV/LCS eUoD
~ EMAX-8260C Rev. No.1 ICVILCS ~T
lJata Hie
D EMAX-8260SIM Rev. No.1 Folder
D ·EMAX-M8260SIM Rev. No. 0
D EMAX-TCPSIM Rev. No.2 pH strip
D EMAX-624 Rev. No.6 Chlorine strip
D EMAX-624.1 Rev. No.1 Methanol
NaHSO.
PURGE AMOUNT Reagent Water
D 5-mL Purge Sand
D lO-mL Purge
rIJ 25-mL Purge
SAMPLE MATRIX
Page 41
Book #: A01-076
Instrument No.: 01
Analytical Sequence:
Method File: VOOI &1\
Analytical Batch: CVOO\ ~ Ill?>
INITIAL CALIBRATION REFERENCE
~1Il1 ,.11
VOOl6" 1 \
STANDARDS
ID Amount Cone.
(,II (mg/1.\
S'II,Lj b~q'O -0, I _ 0-07.-,
.'15--1>1 I
~e,,-Cl( 5
,q?J-Ol> S
-~5-01 I
-Gl3,bl S 56/2. SO
-~-o, I AI ,01 ,
-r,tI .-0 3 (;
-li> 1)& S
• '!"I" Il. 5 ...
LOT # Syringe Lot #
Hli"l3'1'116 MSV .. O~ -1>4 -''2-'4
~2q30&fJ J -~
~N4-1.~-OOI
ElECTRONIC DATA ARCHIVAL
Location Date
D Soil (refer to sample weight log) HPCHEM_ VOA!TOOI
rJ Water Analyzed By: U\P
IJI pH <2. Outliers indicated on analytical sequence. Date: '5 llq l2.q
~ CI 2 <5ppm. Outliers indicated on analytical sequence. Disposed By: LAP
D pH <2 and CI2 are no~ applicable. Date Disposed: S I ~()I2."I
REPORT ID: 24E186 Page 171 of 217
Injection Log
Directory: D:\HPCHEM\1\DATA\24E29
Line Vial FileName Multiplier SampleName Misc Info Injected
1 1 REV528.D 1. BFB01E25 T/CHK 29 May 202410:14
2 2 REV529.D 1. STD CHK 10ppb 8260/50ppb KET -AAl250ppb TBA
3 3 REV530.D 1. CV001E1113
29 May 2024 10:45
10ppb 8260/50ppb KET-AAl250ppb TBA
4 4 REV531.D 1.
29 May 2024 11 :25
V001E25L 10ppb 8260/50ppb KET -AAl250ppb TBA
29 May 2024 11 :54
5 5 REV532.D 1. V001E25C 10ppb 8260/50ppb KET -AAl250ppb TBA
29 May 202413:01
6 6 REV533.D 1. RINSE 29 May 2024 13:34
7 7 REV534.D 1. V001E25B 25mL 29 May 2024 14:04
8 8 REV535.D 1. TB p" <I 25mL 29 May 202414:33
9 9 REV536.D 1. V001E25Q 25mL 29 May 2024 15:03
10 10 REV537.D 1. 24E185_011'e-OO~-OfD'O'O 25mL 29 May 2024 1 q:33
11 11 REV538.D 1. 24E186-03 1 -'2 25mL 29 May 2024 16:02
12 12 REV539.D 1. 24E187-06 • OJ, 25mL 29 May 2024 16:32
13 13 REV540.D 1. 24E175-01 N ~ O~ 25mL 29 May 2024 17:02
14 14 REV541.D 1. 24E187-07 25mL 29 May 2024 17:32
15 15 REV542.D 1. 24E185-02 25mL 29 May 2024 18:02
16 16 REV543.D 1. 24E186-01 Re~-MIS 25mL 29 May 2024 18:31
17 17 REV544.D 1. 24E186-02 25mL 29 May 2024 19:00
18 18 REV545.D 1. 24E187-02 25mL 29 May 2024 19:30
19 19 REV546.D 1. 24E187-03 25mL 29 May 2024 19:59
20 20 REV547.D 1. 24E187-04 25mL 29 May 2024 20:28
21 21 REV548.D 1. 24E187-05 25mL 29 May 2024 20:57
22 22 REV549.D 1. 24E187-01 25mL 29 May 2024 21 :27
23 23 REV550.D 1. EV001E1113 10ppb 8260/50ppb KET -AAl250ppb TBA
24 24 REV551.D 1. EV001 E11131
29 May 2024 21 :55
10ppb 8260/50ppb KET-AAl250ppb TBA
25 25 REV552.D 1. EV001 E11132
29 May 2024 22:24
10ppb 8260/50ppb KET-AAl250ppb TBA
26 26 REV553.D 1. RINSE
29 May 2024 22:53
29 May 2024 23:22
27 27 REV554.D 1. RINSE 29 May 2024 23:51
28 28 REV555.D 1. RINSE 30 May 2024 00:20
Page 1 30 May 2024 10:56 REPORT ID: 24E186 Page 172 of 217
ANALYSIS RUN LOG
for
VOLATILES
Note: For samples and relevant QCs/Standards
analyzed, refer to attached analytical sequence.
Comments:
DATE
ICALID
NAME
($2
DCC til\>
DCC &.lAP!>
DCC tzlOO
DCC ~,.
BFB
IS/SURR.
C5~
ICV/LCSOl-AS
SOP# ICV/LCS~ItW
ri EMAX-8260 Rev. No. 10 ICV /LCS '62J1O
riJ EMAX-8260C Rev. No.1 (CV/Les wr
[lYata ile
D EMAX-8260SIM Rev. No.1 Folder
D £MAX-M8260SIM Rev. No. 0
D EMAX-TCPSIM Rev. No.2 pH strip
D EMAX-624 Rev. No.6 Chlorine strip
D EMAX-624.1 Rev. No.1 Methanol
NaHS04
PURGE AMOUNT Reagent Water
D S-mL Purge Sand
D 10-mL Purge
QJ 2S-mL Purge
SAMPLE MATRIX
Page 44
Book#: A01·076
Instrument No.: 01
Analytical Sequence:
Method File: v'OOHS II
Analytical Batch: CV()O I Ell'"
INITIAL CALIBRATION REFERENCE
5/11/"2"1
V001 E-I I
STANDARDS
ID Amount Cone.
(ull (mg/L)
5VI-",~-qD -O~ : h
-&ffJ ~ OJ) I
-q5~OZ ,
-M-Ol 5
-~.,-O2 5
-3D-02 I
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-rA-03 5
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24FO.3
LOT # Syringe Lot #
H UfS <f 'f 1-S IwIS ,,-0 ~-D1I-/2. .-q
3Z'f~OSG oj -1#
ItW4, '2.'3...()OI
ELECTRONIC DATA ARCHIVAL
location Date
D Soil (refer to sample weight log) HPCHEM_ VOA/TOOl
B Water Analyzed By: LA-l?
.rJJ pH <2. Outliers indicated on analytical sequence. Date: tL 3/28
r:} CI 2 <Sppm. Outliers indicated on analytical sequence. Disposed By: LAP
D pH <2 and CI2 are not applicable. Date Disposed:
REPORT ID: 24E186 Page 173 of 217
Injection log
Directory: D:\HPCHEM\ 1 \DATA\24F03
Line Vial FileName Multiplier SampleName Misc Info Injected
1 1 RFV001.D 1. BFB01F01 T/CHK 3 Jun 2024 10:38
2 2 RFV002.D 1. CV001 E1116 10ppb 8260/50ppb KET-AAl250ppb TBA
3 Jun 202411 :10
3 3 RFV003.D 1. VOO1F01L 10ppb 8260/50ppb KET -AAl250ppb TBA
3 Jun 2024 11 :49
4 4 RFV004.D 1. VOO1F01C 10ppb 8260/50ppb KET -AAl250ppb TBA
3 Jun 2024 12:18
5 5 RFV005.D 1. RINSE 3 Jun 202412:47
6 6 RFV006.D 1. VOO1F01B 25mL 3 Jun 2024 13:20
7 7 RFV007.D 1. 24F005-01 25mL 3 Jun 2024 13:49
8 8 RFV008.D 1. 24E193-04 25mL 3 Jun 2024 14:23
9 9 RFV009.D 1. 24E187-01 10X 2.5mL 3 Jun 2024 14:52
10 10 RFV01O.D 1. 24E186-02N 2.5mL 3 Jun 2024 15:22
11 11 RFV011.D 1. 24E186-02M 25mL 3 Jun 2024 15:52
12 12 RFV012.D 1. 24E186-02S 25mL 3 Jun 2024 16:21
13 13 RFV013.D 1. RINSE 10ppb 8260/50ppb KET -AAl250ppb TBA
3 Jun 202416:51
14 14 RFV014.D 1. RINSE
3 Jun 2024 17:21
15 15 RFV015.D 1. 24F002-02 25mL 3 Jun 2024 17:51
16 16 RFV016.D 1. 24F002-03 25mL 3 Jun 2024 18:20
17 17 RFV017.D 1. 24F002-05 25mL 3 Jun 2024 18:50
18 18 RFV018.D 1. 24F002-01 1'1'1 (f) 25mL 3 Jun 2024 19:19
19 19 RFV019.D 1. 24F002-04 25mL 3 Jun 2024 19:48
20 20 RFV020.D 1. 24E193-01 25mL 3 Jun 2024 20:17
21 21 RFV021.D 1. 24E193-02 25mL 3 Jun 2024 20:46
22 22 RFV022.D 1. 24E193-03 25mL 3 Jun 2024 21 :15
23 23 RFV023.D 1. 24F002-01 M 1't\\P 25mL 3 Jun 2024 21 :44
24 24 RFV024.D 1. 24F002-01 S 1'1\ 5 25mL 3 Jun 2024 22:13
25 25 RFV025.D 1. EVOO1E1116 10ppb 8260/50ppb KET -AAl250ppb TBA
3 Jun 2024 22:42
26 26 RFV026.D 1. EV001 E11161 10ppb 8260/50ppb KET -AAl250ppb TBA
3 Jun 2024 23:11
27 27 RFV027.D 1. EV001 E11162 10ppb 8260/50ppb KET -AAl250ppb TBA
3 Jun 2024 23:40
28 28 RFV028.D 1. RINSE 4 Jun 2024 00:09
29 29 RFV029.D 1. RINSE 4 Jun 2024 00:38
Page 1 04 Jun 202414:20
REPORT ID: 24E186 Page 174 of 217
REPORT ID: 24E186 Page 175 of 217
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Book No: SVl-43
Standard 10 SVl-43-38-01
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Prep. Date \ ,'1)n'1
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Prep. Date IHh'1
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Prep. Date 1/-.,11-4
Exp. Date 1/'" I'L'1
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Comments:
REPORT ID: 24E186 Page 176 of 217
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Book No: SVl-43
Standard 10 SVl-43-69-01
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MeOH Solvent ID I ~W\A -b l\-l4·ol.
Prep. Date Z.i1/t4
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Comments:
Standard 10 SVl-43-69-02
Name 11.4-TMf' ft")
Final Volume 1..0mL
MeOH Solvent ID ')W\A -1)\ \-~4-dL
Prep. Date 2./1/1.4
Exp. Date Y/1/1.t.t
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Comments:
Standard ID SVl-43-69-03
Name ·~dil.tJ (1.6)
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MeOH Solvent ID ~ \/'J \1.\ -t'll 1.1.11·· U \..
Prep. Date ?./1/·~4
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Comments:
REPORT ID: 24E186 Page 177 of 217
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STANDARDS LOG FOR VOLATILES
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Book No: SV1·43
Standard ID SVl-43-78-0l
Name :z,S S~
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Prep. Date V-'d°L./r "J..>{
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Name
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Prep. Date
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Name 'Oflbp (-z.o)
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MeOH Solvent ID SWI A -PII-1A-D2
Prep. Date 03./ CI (24-
Exp. Date mIll h/J
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Syringe 10: Vv{SV-123.:...o3-Of
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REPORT ID: 24E186 Page 178 of 217
I Page 79
STANDARDS LOG FOR VOLATILES
Book No: SVl-43
I Parent ID Parent Standard Name Conc. Aliquot Final Conc. Standard ID SVl-43-79-01
sn-311HI-\'O Carbon Di~u\f\de. fj'oOOpp~ '2.5 O}l I.. 2..1:;°11.,111 Name tSZ l.I")
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REPORT ID: 24E186 Page 179 of 217
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STANDARDS LOG FOR VOLATILES
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Book No: SVl-43
Standard ID SVl-43-87-01
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REPORT ID: 24E186 Page 181 of 217
Page 90
STANDARDS LOG FOR VOLATILES
Book No: SVl-43
Standard ID
Name
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MeOH Solvent ID
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Parent ID Standard ID
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Comments:
REPORT ID: 24E186 Page 182 of 217
Page 93
STANDARDS lOG FOR VOLATilES
Book No: SVl-43
Standard ID SVl-43-93-01
Name ;s/5$ I ';.,3 'fer
Final Volume 2·th..L
MeOH Solvent ID 5WIA-orl-~"'-/JIj
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REPORT ID: 24E186 Page 183 of 217
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Comments:
Page 94
MS"· Dl)-Db-II
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Comments:
REPORT ID: 24E186 Page 184 of 217
STANDARDS lOG FOR VOLATILES
Parent 10 Parent Standard Name Conc. Aliquot Final Conc.
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Page 95
Book No: SVl-43
Standard ID SVl-43-95-01
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Final Volume
MeOH Solvent ID
Prep. Date
Exp. Date
Prepared By
Syringe ID:
Comments:
MSV" Of>-Q?J' II
J -04-cR~
REPORT ID: 24E186 Page 185 of 217
/' ~ .... RESTEK® CERTIFIED REFERENCE MATERIAL
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
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Catalog No. : 30003
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0150458
Description: VOA Tuning Compound Mix
VOA Tuning Compound Mix 5,000jJg/mL, P&T Methanol, 1mLlampui
Container Size: 2 mL --------------------Pkg Amt: > 1 mL -----------------Expiration Date: September 30, 2024 Storage: DOC or colder
':'."'
~~,
~\;
p;cf'RED.@
IsonEC 17025 Aecredited
Testlng l>bor,rory
Certifiate f 3222.02
CERTIFIED VALUES
Compound
I-Bromo-4-fluorobenzene (BFB)
CAS # 460-00-4 (Lot2040IKO)
Purity 99%
Solven~: P&T Methanol
CAS # 67-56-1
Purity 99%
Grav. Cone.
I (weight/volume)
5,030.0 llg/mL
Expanded Uncertainty
(95% C.L.; K:;2)
+/-29.5189
+/. '282.0557
+/. 288.6541
f.!g/mL
f.!g/mL
f.!g/mL
Gravimetric
Unstressed
Stressed
REPORT ID: 24E186 Page 186 of 217
sRe~{'
D~; SPEXerti/icate®
Reference Materials Producer
Cert #2495.01
Certificate of Reference Material
Catalog Number: Sw3893 Lot No. ND210224010
Description: Methyl acetate
Ship Date: January 5, 2023 Matrix: Expiration Date: January 4, 2026
This SPEXOrganics® Certified Reference Material, CRM. is intended primarily for use as a calibration standard or quality
control standard for organic chromatography instrumentation such as GC. GC-MS, LC, and LC-MS. It can be employed In
USEPA, ASTM and other methods relevant to the certified properties listed below.
Methanol (Purge & Trap Grade)
Certified Compounds:
Compound
Methyl acetate
S V I -~~ l 0 ~ 08
~
79-20-9
• -Isomer ratios (when applicable) are an uncertified parameter.
Final Solution Verification:
Labeled
1000 j.lg/mL
Purity
99.5%
Certifiedt
1015 j.lg/mL
Uncertainty
± 36 j.lg/mL
Final solution integrity verified by Gas Chromatography/Mass Spectrometry. The mass spectrum of each compound was
confirmed against the NIST mass spectral database.
t Certified concentration based on gravimetric weights and corrected for the purity of the compound(s) used to prepare the
standard. Analytical balance calibration is verified daily and traceable to NIST and NJ Division of Weights and Measures.
This CRM is guaranteed stable and accurate to within the uncertainty listed for the certified value. This includes uncertainty
components due to preparation, homogeneity, short term and long term stability. During the stated period of validity, the
purchaser will be notified if this product is recalled due to any significant changes in the stability of the solution. For further
information, contact the Sales Support Department at [e-mail].
Date of Certification: January 5, 2023 Certifying Officer: 3~ ~.
Shannon Macieira, Operations Manager
Page 1 of 2
© 20211 Spex, an Anij!e'tl(ientifiA:ompany.
REPORT ID: 24E186 Page 187 of 217
Catalog Number:
Description:
Matrix:
SPEXertificate@
Certificate of Reference Material
S-1015
Cyclohexane
Lot No. NSI231122602
Methanol (Purge & Trap Grade) Manufactured Date:
Expiration Dale:
11/2212023
11/30/2026
This SPEXOrganlcs® Certified Reference Material, CRM, was manufactured by NSI Lab Solutions (www.nsilabsolutions.com) and is intended
primarily for use as a calibration standard or quality control standard for organic chromatography instrumentation such as GC, GC-MS, LC, and
LC-MS. It can be employed in USEPA, ASTM and other methods relevant to the certified properties listed below.
Certified Compounds:
Compound £AU !:!!W!m Purity Cld!!!t!lt !,!n!<llli!in1ll
(ug/mL) (ug/mL) (ug/mL)
Cyclohexane 110-82-7 1000 100.0% 999 ± 7.05
•• Isomer ratios (when applicable) are an uncertified parameter.
Final Solution Verification:
Final solution integrity verified Volumetrically and Analytically. The mass spectrum of each compound was confirmed against the
NIST mass spectral database.
t Certified concentration is based on gravimetric or volumetric measurements. All balances are checked daily by an in-house
standard operating procedure. The weights used for this daily verification are calibrated annually by an ISOIIEC 17025
accredited calibration laboratory and are certified traceable to NIST. Certificate of Calibration and Traceability available upon
request. All glassware used in the manufacturing of this standard is Class A. Volumetric pipettors are calibrated every four
months by an ISOIIEC 17025 accredited calibration laboratory.
This CRM is guaranteed stable and accurate to within the uncertainty listed for the certified value. This includes uncertainty
components due to preparation, homogeneity, short term and long term stability. During the stated period of validity, the
purchaser will be notified if this product is recalled due to any significant changes in the stability of the solution. For further
information, contact the Sales Support Department at [e-mail].
Date of Certification: 11/2212023 Certifying Officer: -:-:-_--:--::----,_....,...,--_______ _
Kenneth Grzybowski
Page 1 of2
Rev.O
REPORT ID: 24E186 Page 188 of 217
Catalog Number:
Description:
Matrix:
SPEXertificate@
Certificate of Reference Material
5-2470
Methylcyclohexane
P&T Methanol
Lot No. N51231116202
Manufactured Date:
Expiration Date:
1111612023
11/3012026
This SPEXOrganlcs® Certified Reference Material, CRM, was manufactured by NSI Lab Solutions (www.nsilabsolutions.com) and is intended
primarily for use as a calibration standard or quality control standard for organic chromatography instrumentation such as GC, GC-MS, LC, and
LC-MS. It can be employed in USEPA, ASTM and other methods relevant to the certified properties listed below.
Certified Compounds:
Compound CAS # .bl!!!!tW! f.I!.!:.!1l CS!!:tH!lult Unc!!!:li!I!ln!
(ug/mL) (ug/mL) (ug/mL)
Methylcyclohexane 108-87-2 1000 98.0% 1000 ± 7.05
t;v;t-' bX-14 -II
• -Isomer ratios (when applicable) are an uncertified parameter.
Final Solution Verification:
Final solution integrity verified Volumetrically and Analytically. The mass spectrum of each compound was confirmed against the
NIST mass spectral database.
t Certified concentration is based on gravimetric or volumetric measurements. All balances are checked daily by an in-house
standard operating procedure. The weights used for this daily verification are calibrated annually by an ISOIIEC 17025
accredited calibration laboratory and are certified traceable to NIST. Certificate of Calibration and Traceability available upon
request. All glassware used in the manufacturing of this standard is Class A. Volumetric pipettors are calibrated every four
months by an ISOIIEC 17025 accredited calibration laboratory.
This CRM is guaranteed stable and accurate to within the uncertainty listed for the certified value. This includes uncertainty
components due to preparation, homogeneity, short term and long term stability. During the stated period of validity, the
purchaser will be notified if this product is recalled due to any significant changes in the stability of the solution. For further
information, contact the Sales Support Department at [e-mail].
Date of Certification: 11/16/2023 Certifying Officer: ":":"_-::--:::-~:-----:'-:--_______ _
Kenneth Grzybowski
Page 1 of2
Rev. 0
REPORT ID: 24E186 Page 189 of 217
~ ....
RESTEK
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Bellefonte, PA 16823-8812
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Fax: [phone]
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Catalog No. : 575702
CERTIFIED REFERENCE MATERIAL
Certificate of Analysis
chromatographic
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0191824
Description: Custom Revised 8260 Megamix
Custom Revised 8260 Megamix 2,000 -40,OOOJ.lg/mL, P& T Methanol,
1mUampui
Container Size: 2 mL ---------------------Pkg Amt: > 1 mL --~~-----------
Expiration Date: November 30, 2025 Storage: O·C or colder
Ship: Ambient
ISO 11834,,",_'"
~Mat~'Pioduc-er
CQl1ifn:ate~l2U01
ISOIIEC 11025 ADe ... litod
T_""""""'l'
Certlfidrltsjl2ll00.
CERTIFIED VALUES
• - - - -'-,. - - • --••• < -""'" • .~--~, .; ~ • ---• Expanded.
ElutiQn compound' ,', 'CAS # P-Lot # Purity Grav. Conc, Uncertainty' '.
Order I I (wEllght/volume) (95% C,L.; K=2)
Dichlorofluoromethane (CFC-21) 75-43-4 12841600 99% 2,000.0 flglmL +/-69.1292
2 Diethyl ether (ethyl ether) 60-29-7 SHBP5008 99% 2,01l.0 flg /mL +/-69.5094
3 1, I ,2-Trichlorotrifluoroethalle (CFC-I13) 76-13-1 00016133 99% 2,008.0 flg/mL +/. 69.4057
4 I,I-dichloroethene 75-35-4 SHBG8609V 99% 2,001.6 flg/mL +/. 69.9029
5 Iodomethane (methyl iodide) 74-88-4 RD220125 99% 2,007.5 flg/mL +/-69.3884
6 Allyl chloride ( 3-chloropropene ) 107-05-1 RP220405A 99% 2,01l.0 flg/mL +/-69.5094
7 Methylene chloride (dichloromethanc) 75-09-2 SHBP1417 99% 2,001.6 flg/mL +/-69.9056
8 trans-I ,2-Dichloroethellc 156-60-5 MKBH9850V 99% 2,001.7 flglmL +/-69.9064
9 I,I-Dichloroethanc 75-34-3 760200 99% 2,001.1 flglmL +1-69.8864
10 Chloroprelle (2-chloro-l ,3-butadiene) 126-99-8 220712JLM 99% 2,014.0 flg/mL +1-69.6131
Jl Propiollitrile 107-12-0 BCCF4167 99% 20,009.5 flglmL +1-691.5748
12 2,2-Dichloropropane 594-20-7 RD220812 99% 2,004.3 flg/mL +/-70.0110
13 cis-l,2-Dichloroethene 156-59-2 MKCP7830 99% 2,014.0 /lg/mL +/-70.3516
14 Methacrylonitrile 126-98-7 1012014 99% 20,031.5 flglmL +/. 692.3351
15 Methyl acrylate 96·33-3 SHBG6616V 99% 2,007.0 flg/mL +/-69.3711
16 Isobutanol (2-Methyl-I-propanol) 78-83-1 SHBP7066 99% 40,013.5 flg/mL +/-1,382.9594
01-Nov-2022 rev. 1of5
REPORT ID: 24E186 Page 190 of 217
/' to:;;:. .... Q.ESTEK CERTIFIED REFERENCE MATERIAL
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Catalog No. : 30465
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0168072
Description: California Oxygenates Mixture #1
California Oxygenates Mixture #1 2000-10000!-,g/mL, P& T Methanol,
1mLlampui
Container Size: 2 mL Pkg Amt: > 1 mL -----------------------------------..---Expiration Date: January 31, 2026 Storage: O°C or colder
Ship: Ambient
, ':.:.., ..
~'}
(AC£jmjl'rjD)
ISO 11034 A""'.d~.d
Reference M.l1.alial PtodUCQf
CenifK.lte #l3moi
CERTIFIED VALUES .. , "Compound" , ...... ,,~k ~faw()onc ... " ..
: (weight/volume)
. . Expanded Uncertainty:, '",.. "" .,
(95% C.L.; K;:2)
tert-Butanol (TBA) \0;038.8 flg/mL +1-58.7794 flg /mL Gravimetric
CAS# 75-65-0 (Lot SHBL5806) +1-215.0444 flg /mL Unstressed
Purity 99% +/-221.2897 Ilg/mL Stressed
2 Methyl-teI1-butyl ether ( MTBE ) 2,005.6 flg/mL +/-11.7700 flg/mL Gravimetric
CAS # 1634-04-4 (Lot SHBL0822) +1-42.9699 flg/mL Unstressed
Purity 99% +1-44.2174 Jlg/mL Stressed
3 Diisopropyl ether ( DIPE ) 2,009.6 flg/mL +/-11.7935 Jlg/mL Gravimetric
CAS # 108-20-3 (Lot SHBH1927V) +1-43.0556 Jlg/mL Unstressed
Purity 99% +/-44.3056 Jlg/mL Stressed
4 Ethyl-tert-butyl ether (ETBE) 2,006.0 Jlg/mL +/-11.7723 JlglmL Gravimetric
CAS # 637-92-3 (Lot MKCM3774) +1-42.9785 Jlg/mL Unstressed
Purity 99% +1-44.2263 Jlg/mL Stressed
5 tcti-Amyl methyl ether (TAME) 2,007.2 flglmL +1-11.7794 flg/mL Gravimetric
CAS# 994-05-8 (Loi HMBG7745V) +1-43.0042 flg/mL Unstressed
Purity 99% +/-44.2527 flg /mL Stressed
01-Au9-2020 rev. 1013
REPORT ID: 24E186 Page 191 of 217
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
CERTIFICATE OF ANALYSIS
Catalog No: M-601C-10X
Description: 2-Chloroethylvinyl ether
Lot: 223041132
Solvent: Methanol
Hazards: Refer to SOS for complete safety information
Signal Word: Danger
Date Certified: Apr 11, 2023
Expiration: Apr 11, 2026
Sample Size: 1 mL
Components: 1
Storage Conditi~n: Freeze «-10 ·C)
Certified Reference Material
Tel [phone]
Fax [phone]
www.Acc~Standard.com
Component CAS # Purity· % pr,4.~~.red Certified Analyte
Concentratlgo' Concentration' .. !rg~~otJ (1J9/mL)
2-Chloroethylvinyl ether 110-75-8 100.0
. .:.)::: ....
This Certified Reference Material was verified iri~6cord:~~~:Wlth ISOIIEC 17025 (AT -1339) and ISO 17034 (AR-1463)
A product with a suffix (-1A, -2B, etc. or -01,.::,0.2, ';f¢»::9n:[t~d~{humber has had its expiration date extended and is identical to the same lot number without the suffix.
, Certified Analyte Concentration = PU~IW:;(Pr';paredbQribiintration.
The Uncertainty associated with the c~~iiied conq~qtration reported on this certificate is ±2,4%. This value is the combined expanded uncertainty and represents an
estimated standard deviation equal to 'ihi:i::P9sitlv~)lquare root of the total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K=2 is chosen usingep.Pr\'lXimai';IY~W5·,.i, confidence level.
2 All weights are traceable tt@ugh NIS,J\:Test No. 684/291344-18 & 684/292805-19
3 PurltylidentitY:determined@:ooe or n,'Q:re of the following methods: GC/MS. LC/MS, NMR, FTIR, Melting Point.
Labels and c~Riii¢~t$,E; .. ,fOIlOWm~i:¢~Mentions In reporting numerical values: A comma (.) is used to separate units of one-thousand or greater. A period (.) is used as
a decimal pla~~m~~k~r? ' . ," .
The informatioW~~Jhi,s;:~rtjfjcate may not be reproduced without the express permission of the manufacturer. See'teverse side for additional information
Hazard InfOrma;i~!1:ji\i'~'~se refer to the SDS for information regarding the hazards associated with using this material.
This product was p'r~~,,,,red according to in-house procedures and is guaranteed to be homogeneous.
Certified By:
Paga 1 of 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISO/IEC 17025 and certified to ISO 9001 :2015 QR·ORGiINO·QQl
Rev. 7/20
REPORT ID: 24E186 Page 192 of 217
Trusted Answers
Reference Material Certificate
Product Information Sheet
Product Name: l-Chlorohexane Standard
Product Number: EPA-12Oa-,
Storage Conditions: Store at Room Temperature (15° to 30°C).
Matrix: methanol (methyl alcohol)
Tt.W=
Description:
ISO 17034
Lot Number: 0006735507
Lot Issue Date: 20-Mar-2023
Expiration Date: 30-Apr-2026
·:::::'w wr .. :: •. 1?:r:::!Z!!l::: :J
This document is prepared in accordance with ISO 17034 and Guide 31. This analytical reference material (RM) standard was
manufactured and verified in accordance with an ISO 9001 registered quality system and analyte concentrations were verified by an
ISO 17025 accredited laboratory. The concentration and uncertainty value at the 95% confidence level for each analyte, determined
gravimetrically, is listed above. Purity values are taken from approved vendor raw material certificates.
Traceability:
The balances used for these measurements are calibrated with weights traceable to NIST in compliance with ANSIINCSL Z540.3,
ISO 9001, ISO 17025, and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are
calibrated against a NIST traceable thermometer in accordance with NIST Special Publication 1088.
Homogeneity:
This analytical reference (RM) standard was unitized according to an in-house procedure and is guaranteed to be homogeneous.
There is no minimum sub-sample size required.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at 20°C to 25°C immediately after opening the container and should be processed
without delay for the certified values to be valid within the stated uncertainties.
Safety:
Refer to the Safety Data Sheet on www.agilent.com for information regarding this analytical reference material.
Intended Use:
This analytical reference (RM) standard is intended for the preparation of working reference samples for use in routine laboratory
analyses, calibration of instruments, validation of analytical methods, assessments of measurement methods, and continuing
calibration verification.
Expiration of Certification:
The certification of this analytical reference standard (RM) is valid until the expiration date specified above, provided the material is
handled and stored in accordance with the instructions given in this certificate. This certification is nullified if the material is
damaged, contaminated, or otherwise modified.
Page: 10f2
CSD-QA-01S.1 ISO 17025
REPORT ID: 24E186 Page 193 of 217
I +'f' SCle.ntllC
Ibis Scientific, 7330 Smoke Ranch Rd., Suite B, Las Vegas, NV 89128 [phone] Page 1 of 1
Date manufactured: 6/24/2022
Original issue date: 6/24/2022
Catalog No.: Lot No.:
3200-44 503601
Compound
1,2,3-trimethylbenzene
Certificate of Analvsis Date Received:
Storage: Solvent:
PIT Methanol
Expiration
Date:
23-Jun-2027
Description:
1,2,3-Trimethylbenzene Solution,
2500 mg/L, 1 mL
Rev 0
CAS No. Purity (%) Neat Material Lot No. Concentration, mall
526-73-8 92.7 869.8.4.1P 2536 ± 32.33
REPORT ID: 24E186 Page 194 of 217
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110 Benner Circle
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Catalog No. : 30470
Certificate of Analysis
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
Lot No.: A0188432
Description: tert-Butanol Standard
tert-Butanol Std 50,OOOIJg/mL, P&T Methanol, 1mUampui
Container Size: 2 mL ~~---------------Pkg Amt: > 1 mL --~~-----------Expiration Date: August 31, 2025 Storage: O°C or colder
Ship: Ambient
R~reoce fi..'1.lhNlal Pfoduc~
CeftificltHl.222.Qi
lsom,c 17025 Ao",edited
resting Labor.tory
c.rtifiote .322>m
CERTIFIED VALUES
lert-Butanol (TBA)
CAS # 75-65-0
Purity 99%
Solvent: P&T Methanol
CAS # 67-56-1
Purity 99%
50,300.0 J.lg/mL
(Lot 101619K21F-l)
+1-294.5176
+1-1,077.4927
+1-1,108.7850
Gravimetric
Unstressed
Stressed
01-Aug-2020 rev. 1 of 3
REPORT ID: 24E186 Page 195 of 217
SVI-38-o~-o0
Certificate of Analysis
Product Name: Carbon Disulfide Standard
Product Number: EPA-l012-1
Lot Number: 0006557585
Description:
Lot Issue Date:
Expiration Date:
2.1-Sep-2.020
30-Sep-2.02.4
This analytical reference material (RM) was manufactured and verified in accordance with an ISO 9001 registered quality system and analyte
concentrations were verified by an ISO 17025 accredited laboratory_ The concentration and uncertainty value at the 95% confidence level for each
analyte. determined gravimetrically. is listed below_
Analyte
carbon disulfide
Matrix: methanol (methyl alcohol)
Storage Conditions: Store Frozen (-25° to -10° C)_
Traceability:
CAS#
000015-15-0
Analyte Lot
RMOB158
Concentration ± Uncertainty
502.3 ± 2.5 J,lg/mL
The balances used for these measurements are calibrated with weights traceable to NIST in compliance with ANSI/NCSL Z540.3. ISO 9001, ISO 1702.5,
and ISO 11034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are calibrated against a NIST traceable
thermometer in accordance with NIST Special Publication 108B.
Homogeneity:
This RM was unitized according to an in-house procedure and is guaranteed to be homogeneous. There is no minimum sub-sample size required.
Intended Usa:
This RM is intended for the preparation of working reference samples for use in routine laboratory analyses, calibration of instruments, validation of
analytical methods. assessments of measurement methods, and continuing calibration verification.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at 2.0·C to 2.5·C immediately after opening the container and should be processed without delay for
the certified values to be valid within the stated uncertainties.
Hazards:
Refer to the Safety Data Sheet on www.agilent.com for information regarding this RM.
Expiration of Certification:
The certification of this RM is valid until the expiration date specified above, provided the RM is handled and stored in accordance with the
instructions given in this certificate. This certification is nullified if the RM is damaged. contaminated, or otherwise modified.
Maintenance of Certification:
If substantive changes are noted that affect the certification before the expiration of this certificate, Agilent will notify the purchaser.
~
ACCREDITj::;:O
Ii
REFERENce MATE!l!AI,.
PAQOUCf:A
ISO 17034 Cert
No. AR-1936
RM was produced in accordance with TUV USA Inc registered ISO 9001 Ouality
Management System. Cert # 56 10018560026
Page: 1 of 1
www.agilent.com/quality/
CSO-0A-015.1
Sample lot approver:
~QOJ.AgzO/J
Monica Bourgeois
QMS Representative
~
ACCReOITED
Tl;STING LABORATORY
ISO 1702.5 Cart
No. AT-1937
250 Srnith S~reet Nonh I<:nqstc"wl Rhode Isiand 02852 www.agih:mt.com/quaiity
REPORT ID: 24E186 Page 196 of 217
CPI
Date manufactured: 3/13/2023
Original issue date: 3/1312023
Catalog No.: Lot No.: Storage:
Z-G34 498957 :S -10°C
-126047-01
Certified Values:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Analysis Date Received:
Page 1 of 5
Solvent:
PIT Methanol
Expiration
Date:
13-Sep-2024
Description:
Custom Volatiles Mix, 73-6047, Various
Concentrations, 1 mL
Rev 0
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (OC) or gas chromatograph/mass spectrometry (OCIMS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, m!!/L
2-nitropropane 79-46-9 97.7 219.1.2P 2003 ± 110
ally I ch loride 107-05-1 98.9 227.1.2P 2024 ± 120
benzene 71-43-2 99.99 146.l.IOP 1997 ± 110
bromobenzene 108-86-1 100 147.7.1P 1999 ± 140
bromochloromethane 74-97-5 99.7 148.1.3P 1998 ± 110
bromodichlorometbane 75-27-4 99.2 149. l.l 2P 1988 ± 110
bromoform 75-25-2 99.3 150.7.2P 1989 ± 110
n-butylbenzene 104-51-8 99.2 IS1.7.3.2P 1997 ± 110
sec-butylbenzene 135-98-8 99.5 152.1.2.1P 1999 ± 110
tert-butylbenzene 98-06-6 99.9 IS3.29.1P 1999 ± 110
carbon tetrachloride 56-23-5 100 IS4.9.1P 1997 ± 110
chlorobenzene 108-90-7 99.9 IS5.29.IP 2001 ± 110
2-chloroetbanol 107-07-3 99.5 217.1.3P 2000 ± 110
chloroform 67-66-3 99.8 IS6.7.IP 1998 ± 110
chloroprene 126-99-8 98.9 315.5.22P 1982 ± 140
2-chloroto1uene 95-49-8 99.5 157.7.1P 1998 ± 110
4-chlorotoluene 106-43-4 99.9 158.9.3P 2000 ± 110
REPORT ID: 24E186 Page 197 of 217
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USA ~ AccuStandard®
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Tel (203)786·5290
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CERTIFICATE OF ANALYSIS
Catalog No: OGAD-001
Description: Oxygenate Gasoline Additive Standard
Lot: 222081419
Solvent: Methanol
Hazards: Refer to SOS for complete safety information
Signal Word: Danger
Date Certified: Aug 29, 2022
Expiration: Aug 29, 2025
Sample Size: 1 mL
Components: 5
Storage Condition: Refrig (0-5 ·C)
Certified Reference Material
.~-
AR·1463
Component Purity % !?"r..,ared Certified Analyte
Conceritr.tI9n· Concentration'
CAS #
(GC/MS) <@iffil:.) (jJg/mL)
MtBE
EtBE
isopropyl ether
TAME
t·Butanol
This Certified Reference Material was verified iri ei¢<:;ordancii with ISO/IEC 17025
1634-04-4
637-92-3
108-20-3
994-05-8
75-65-0
2061:
.. 2004
';\;2010
2000
10005
1997
2002
2010
1980
9965
A product with a suffix (-1A, -28, etc. or:;01;;02, etc:) on Its lot number has had its expiration date extended and is identical to the same lot number without the suffix.
'Ail weights are traceable through NI$T, Test NO/6B4/289871-17
, Certified Analyte Concentration = PuritY.x.pr<l~~red Concentration.
The Uncertainty associated v,.iih ihe certifiei:H:oncentration reported on this certificate is ±2.4%. This value is the combined expanded uncertainty and represents an
estimated standard deviatlpifequal to .the positive square root of the total variation of the uncertainty of components, A normal distribution is assumed and a coverage
factor of K=2 is chosen usirig.l;lpproximately a 95% confidence level.
Labels andceftifl~te.s followU.S. Conventions In reporting numerical values: A comma (,) is used to separate units of one-thousand or greater. A period (.) Is used as
a decimal place marker:
The information on this·.Certificate may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard Information:)'lease refer to the SDS for information regarding the hazards associated with using this material.
This product was prepared according to in-house procedures and Is guaranteed to be homogeneous.
Certified By:
Larry Decker, Organic ac Manager
Page 1 of 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISOIIEC 17025 and certified to ISO 9001:2015 QR-ORG/INO-OO1
Rev. 7/20
REPORT ID: 24E186 Page 198 of 217
CPI
INTERNATIONAL
Date manufactured: 8/24/2022
Original issue date: 8/24/2022
Catalog No.: Lot No.: Storage:
Z-G34 492308 ~ -to °C
-020145-02
Certified Values:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Analysis Date Received: 10 I kl-z,~
Page 1 of 2 Rev 0
Solvent: Expiration Description:
Date:
23-Aug-2027 2-Chloroethyl Vinyl Ether Solution, 2,000 mg/L, 1 mL PIT Methanol
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, ml!/L
2-chloroethylvinyl ether 110·75-8 99.8 145.l.5P 2010 ± 110
"'Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLCIMS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods.This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLCIMS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
% Change = (-0.0 ISln(x+ 31) + 0.1157) + 636.54y'3.202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assumes the container is stored at -10°C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
(95% confidence) values listed are determined gravimetriclly.
REPORT ID: 24E186 Page 199 of 217
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
SVi -6~·'1,-1'6
CERTIFICATE OF ANALYSIS
Catalog No: M·8010R·1-04·10X
Description: 1·Chlorohexane
Lot: 223031117
Solvent: Methanol
Date Certified: Mar 8, 2023
Expiration: Mar 8, 2033
Sample Size: 1 mL
Components: 1
Tel [phone]
Fax [phone]
www.AccuStandard.com
Hazards: Refer to SDS for complete safety information Storage Condition: Ambient (>5 0c)
Certified Reference Material
Signal Word: Danger
Component CAS # Purity' % !.'!,~~pared Certified Analyte
1-Chlorohexane 544-10-5 98.0
Concenth~.!Qn· Concentration'
(MS;~J. >. (f!g~;8L1
:-.:;"., ::":'
. ·:·~··!:::;~;:~)t:::)/·
This Certified Reference Material was ver~led:in accordaric~With ISOIIEC 17025 (AT-1339) and ISO 17034 (AR-1463)
A product with a suffix (-lA, -2B, etc. or -01, -02; eteJO.n itsiot number has had its expiration date extended and is identical to the same lot number without the suffix.
, Certified Analyte Concentration = PurilYX·preparedCQr\centration.
The Uncertainty associated with the :G\jnified concentration reported on this certificate Is :1:2.4%. This value is the combined expanded uncertainty and represents an
estimated standard deviation equal t6jh~ .. posltive square root of the total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K=2 is chosen using ·ap·proximateJYa95% confidence level.
, All weights are traceable through NI.ST, Test No. 684/291344-18 & 684/292805-19
, Puritylldentlty determinedl)y one or::riiore of the following methods: GC/MS, LC/MS, NMR, FTIR, Melting Point.
Labels andc~nlt.C?ltes follow\J,S: qbhventlons in reporting numerical values: A comma (.) is used to separate units of one-thousand or greater. A period (.) Is used as
a decimal place marker, ...
The information on this certificate may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard Information:· Please refer to the SDS for information regarding the hazards associated with using this material.
This product was prepared according to in-house procedures and is guaranteed to be homogeneous.
Certified By:
Page 1 of 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISOIIEe 17025 and certified to ISO 9001:2015 QR·QRGlINO·001
Rev. 7/20
REPORT ID: 24E186 Page 200 of 217
CPI
IN T ERN AT I ON AL
Date manufactured: 6/24/2022
Original issue date: 6/24/2022
Catalog No.: Lot No.: Storage:
Z-G34 484154 ~ -10 °c
-020869-08
Certified Values:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
(800)878",7654 Toll Free
[phone] Fax
SV\-?~-I~ -r;
Certificate of Anal • SIS Date Received:
Page 1 of 2 Rev 0
Solvent:
PIT Methanol
Expiration
Date:
23-Jun-2027
Description:
1,2,3-Trimethylbenzene Solution, 2,500 mglL, 1 mL
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, llIl!lL
l,2,3-trimethylbenzcne 526-73-8 92.7 869.8.4.IP 2536 ± 140
·Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may aslo be used for various USEPA. NIOSH,
and ASTM methods. This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLCIMS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
% Change = (-0.018In(x+31) + 0.1157) + 636.54y-3.202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y <; boiling point of the solvent (degrees K)
This model assumes the container is stored at -\ 0 °c and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. 1. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
(95% confidence) values listed are determined gravimetriclly.
REPORT ID: 24E186 Page 201 of 217
Date manufactured: 11/16/2022
Original issue date: 11116/2022
Catalog No.: Lot No.: Storage:
Z-G34 492310 :'S -10 °C
-020511-06
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Fn:u
[phone] Fax
Certificate of Analysis Date Received:
Page 1 of 2
Solvent: Expiration Description:
Rev 0
Date: 15-Nov-2027 t-Butyl Alcohol Solution, 50,000 mgIL, I mL Ptr Methanol
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confinned by gas chromatography (GC) or gas chromatograph/mass spectrometry (GCIMS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, ml!/L
tert-butyl alcohol 75-65-0 100 511.7.2P 501I0 ±2600
*Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for usc as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GCIMS, HPLC, and HPLCIMS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods.This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GCIMS, HPLC, and HPLCIMS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
% Change = (-0.018In(x+31) + 0.1157) + 636.54y"3.202
where x == boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assumes the container is stored at -10°C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 24E186 Page 202 of 217
~ ....
RESTEK
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30240
CERTI
Certific"~I:,Q':Analysis
chrorna.~!i;;Plus
:.:: .. :.:"
...... '{:.,'., ....•..••. ', ••. ', •........ ,
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative and/or quantitative determination of the analyte(s) listed.
"",
Lot No.: &1192204
Description ; 8260A Surrogate Mix
8260ASurrogate Mix 2,500jJg/mL, P&T Methanol, 1mUampui
Container Size ; 2mL PkgAmt: ' > 1 mL
--~~----------
Expiration Date: December 31, 2027 Storage: O·C or colder
Ship: Ambient
_;~i
~
1SO'IlU4Acuod1ed
~HllterialPJoduc.
~~I!)lll.01
!Ii
JSOMiC 170'2:5 Aoorodi1e: _tAm...,.
CertIfic:P.Jl2l~
CERTIFIED VALUES
: Expanded
, Elution Compound I CAS # Lot # PUlity Grav. Conc. Uncertainty *
Order . (weight/volume) {95% C.L.; K::2
Dibromofluoromethane 1868-53-7 022013 99% 2,517.6 IlglmL +1-141.4279
2 1,2-Dichloroethane-d4 17060-07-0 PR-32845 99% 2,507.6 IlglmL +/-140.8661
3 Toluene-d8 2037-26-5 1-27008 99% 2,511.4 Ilgl mL +1-141.0796
4 I-Bromo-4-fluorobenzene (BFB) 460-00-4 184975 99"10 2,517.8 IlglmL +/-141.4391
.. Expanded Uncertainty displaved in same units as Grav. Cor
Solvent: P&T Methanol
CAS # 67-56-1
Purity 99%
. ....--....
01-Nov-2022 rev, RESTEK
REPORT ID: 24E186 Page 203 of 217
Trusted Answers
Product Name: VOC Gas Standard
Product Number: DWM-544-1
Reference Material Certificate
Product Information Sheet
ISO 17034
lot Number: 0006744131
lot Issue Date: 23-May-2023
chloroethane 2008 ± 10 1J9/mL 000075-00-3 RM00065
dichlorodifluoromethane 2010 ± 10 lJg/mL 000075-71-8 RM05289
vinyl chloride 2009 ± 10 1J9/mL 000075-01-4 RM05458
Matrix: methanol (methyl alcohol)
Description:
This document is prepared in accordance with ISO 17034 and Guide 31. This analytical reference material standard was
manufactured and verified in accordance with an ISO 9001 registered quality system and analyte concentrations were verified by an
ISO 17025 accredited laboratory. The concentration and uncertainty value at the 95% confidence level for each analyte, determined
gravimetrically, is listed above.
Traceability:
The balances used for these measurements are calibrated with weights traceable to NIST in compliance with ANSIINCSL Z540.3,
ISO 9001, ISO 17025, and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are
calibrated against a NIST traceable thermometer in accordance with NIST Special Publication 1088.
Homogeneity:
This analytical reference standard was unitized according to an in-house procedure and is guaranteed to be homogeneous. There is
no minimum sub-sample size required.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at 20°C to 25°C immediately after opening the container and should be processed
without delay for the certified values to be valid within the stated uncertainties.
Safety:
Refer to the Safety Data Sheet on www.agilent.com for information regarding this analytical reference material.
Intended Use:
This analytical reference standard is intended for the preparation of working reference samples for use in routine laboratory
analyses, calibration of instruments, validation of analytical methods, assessments of measurement methods, and continuing
calibration verification.
Page: 10f2
CSD-QA-015.2 ISO 17025
Cert No. AT-1937
REPORT ID: 24E186 Page 204 of 217
CPI
INTERNATIONAL
Date manufactured: 11116/2022
Original issue date: 11116/2022
Catalog No.: Lot No.: Storage:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal • Date Received:
SIS Page 1 of 2
Solvent: Expiration Description:
Rev 0
Z-G34 492307 :S -10 °C
Date:
20-Nov-2025 Vinyl Acetate Solution, 2,500 mg/L, 1 mL PIT Methanol
-020232-10
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, ml!/L
vinyl acetate 108-05-4 99.9 232.7.lP 2496 ± 160
<'vA-?J g.-14 -D9 *Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods.This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
% Change = (-0.018In(x+31) + 0.1157) + 636.54i3202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assumes the container is stored at _10°C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. 1. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 24E186 Page 205 of 217
CPI
INTERNATIONAl,
Date manufactured: 3/10/2023
Original issue date: 3/10/2023
Catalog No.: Lot No.: Storage:
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal
Solvent:
• SIS
Date Received:
Page 1 of 2 Rev 0
Description:
Z-G34 498954 :s; -10°C PIT Methanol
Expiration
Date:
8-Mar-2028 Carbon Disulfide Solution, 5,000 mg/L, 1 ml
-020200-04
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (OC) or gas chromatograph/mass spectrometry (OCIMS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, ml!"iL
carbon disulfide 75-15-0 99.9 200.24.1 VP 5075 ± 260
·Nul u certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods.This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
% Change = (-0.0 18In(x+ 31) + 0.1157) + 636.54y-3.202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assumes the container is stored at -10°C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. I. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 24E186 Page 206 of 217
~"
,RESTEK
110 Benner Circle
Bellefonte, PA 16823-8812
Tel: [phone]
Fax: [phone]
www.restek.com
Catalog No. : 30006
~V\ -1~-14-o~
CERTIFIED REFERENCE MATERIAL
Certificate of Analysis
chromatographic plus
FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE.
This Reference Material is intended for Laboratory Use Only as a standard for
the qualitative andlor quantitative determination of the analyte(s) listed.
Lot No.: A0198760
Description: VOA Calibration Mix #1
VOA Calibration Mix #1 5,000)Jg/mL, P&T MethanollWater(90:10),
1mUampui
Container Size : ~2_m_L _______ _ Pkg Amt: > 1 mL -----------------Expiration Date: September 30, 2026 Storage: O°C or colder
Ship: Ambient
CERTIFIED VALUES
, , " Expanded
Elution Compound C'AS # Lot # Purity Grav. Conc. Uncertainty *
Order (weight/volul11e) (95% C,L,; K=2)
Acetone 67-64-1 27D1062005 99% 5,000.2 J.lg/mL +/-172.7826
2 2-Butanone (MEK) 78-93-3 SHBL5543 99% 5,006.0 J.lg/mL +/-172.9842
3 4-Methyl-2-pentanone (MffiK) 108-10-1 SHBN3601 99% 5,009.5 J.lg/mL +/-173.1052
4 2-Hexanone 591-78-6 MKCQ6663 99% 5,009.3 J.lg/mL +/-173.0994
* Expanded Uncertaintv displayed in same units as Grav. Cone,
Solvent: P&T MethanollWater (90:10)
CAS # 67-56-117732-18-5
Purity 99%
01-Nov-2022 rev, 1013
REPORT ID: 24E186 Page 207 of 217
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
CERTIFICATE OF ANALYSIS
Catalog No: M-603-M-5X
Description: Acrolein & Acrylonitrile
Lot: 224031415
Date Certified: Mar 26. 2024
Expiration: Jul 26. 2024
Sample Size: 1 mL
Components: 2
Tet [phone]
Fax [phone]
Vf/'IVi.AccuStandard.com
Solvent: Methanol (90%)
Water (10%) Storage Condition: Freeze «-10 ·C)
Hazards: Refer to SOS for complete safety information
Signal Word: Danger
Component CAS #
Certified Reference Material
Purity' % P~~~.~red
Concentration'
!f!(ilml}
Certified Analyte
Concentration I
(flg/mL )
Acrolein
Acrylonitrile
107-02-8
107-13-1
90.5
99.8 ··jjj·j:f?~.~~.'··········· . 5005
5050
.:<::;:::., "." :: ..
Thh "'.h,' R,f,,""~ M,.,.I W"' ~I"" '" ,=~i~!~:!::;t~"25 (AT-",,) eo' ISO 1 T034 (AR-1"')
• Weight compensated to 100% purity..·.:}:.
A product with a suffix (-1A, -2B, etc. or -01.' .• :R.2,~ii::X9n .. it~.:.i~Fgumber has had its expiration date extended and Is identical to the same lot number without the suffix.
, Certified Analyte Concentration = Puri.ti~·PM~ared\i;i&@li~·iration.
The Uncertainty associated with the c~Riiied conc~iitration reported on this certificate is ±2.4% and was determined in accordance with ISO 17034. This value is the
combined expanded uncertainty and r~pt~:~.El.nts ~W~stimated standard deviation equal to the positive square root of the total variation of the uncertainty of
components. A normal distrib,\l.t,lil@K·assi\i:i'iil.i,Lii(iJ!fa coverage factor of K=2 is chosen using approximately a 95% confidence level.
'All weights are traceable tlj&U9h·NIST;.J~~m~. 684/291344-18 & 684/292805-19
, Puritylldentityc;letermined ·iM~n.e or riiMi3 of the following methods: GC/MS, LC/MS, NMR, FTIR, Melting Point.
Labels and C~4\~~.M~!'Jollowb:$;:.g96~~ntions In reporting numerical values: A comma (,) is used to separate units of one-thousand or greater. A period (.) is used as
a decimal plac~Jjj~Hi\i.t::>::.. . •..
The Informatlo~::M ... thi&·.B.\i~i~B~i!fmay not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard InfOrmatlSik~·i~~~·e ;~f~'r to. the SDS for information regarding the hazards associated with using this material.
This product waspi~~~red according to in-house procedures and is guaranteed to be homogeneous.
Certified By:
Page 1 of 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, iSOIiEC 17025 and certified to ISO 9001 :2015 QR·ORCl/INO-OOl
Rev. 7120
REPORT ID: 24E186 Page 208 of 217
.. ,.-.... . ... ,., ............ :: ..
ibis scientific
Ibis Scientific, 7330 Smoke Ranch Rd., Suite B, Las Vegas, NV 89128 [phone]
Date manufactured: 12/14/2023
Original issue date: 1211412023
Catalog No.: Lot No.:
Certificate of Analysis Date Received:
Solvent: Expiration Description:
Date:
Page 1 of 3
Rev 0
3200-G34
-120016-03 513798
Storage:
!: -10 DC PIT Methanol 12-Dec-2028 ISO 17034 -Method 8260 Gases, 2,000 mg/L, 2 x 0.6
mL
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been confirmed by
gas chromatography (GC), gas chromatography/mass spectrometry (GC/MS), or High Pressure Liquid
Chromatography (HPLC) using an internally developed method against an independent source. The uncertainty value
is calculated for a 95% confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, mgfL
bromomethane 74-83-9 99.9 139.158.2.1P 1962 ± 23
chloroethane 75-00-3 99.94 141.2.3P 1995 ± 23
chloromethane 74-87-3 99.7 140.158.3P 2018 ± 24
dichlorodifluoromethane 75-71-8 99 142.158.5.1P 2026 ± 47
trichlorofluoromethane 75-69-4 99 144.1.3P 1995 ± 38
vinyl chloride 75-01-4 99 143.158.5.3P 1962 ± 45
Second Source standards are prepared according to NELAC requirements.
Intended Use:
This certified reference material (CRM) is intended for use as a calibration standard or a quality control standard
for chromatography instrumentation such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for
various USEPA, NIOSH, and ASTM methods.
Recommended storage container for ampouled products after opening is a 12mmx32mm amber vial with screw
cap Teflon lined silicon septum. The modeled % change per day can be calculated using the following:
% Change:;:: (-O.018In(x+31) + 0.1157) + 636.54y-3.202
where x = boiling point of the most volatile analyte in the mix
y = boiling point of the solvent
This model assumes the container is stored at -10 DC and is unopened during storage. The user should
determine what the acceptable error for their process is and calculate the maximum number of days the opened
REPORT ID: 24E186 Page 209 of 217
125 Market Street
New Haven, CT 06513
USA
CERTIFICATE OF ANALYSIS
Catalog No: APP-9-211-20X
Description: Vinyl acetate
Lot: 224031313
Solvent: Methanol
Date Certified: Mar 22, 2024
Expiration: Sep 22, 2024
Sample Size: 1 mL
Components: 1
Tel [phone]
Fax [phone]
www.AccuSlandard.com
Hazards: Refer to SOS for complete safety information Storage Condition: Freeze «-10 ·C)
~o~, ~ ,)VI-w' 1'-0
Certified Reference Material
AR-1463
Component CAS # Purity' % ~r!,pared Certified Analyte
Concentr~tll;l!1' Concentration'
.!H9linL) (lJg/mL)
Vinyl acetate 108-05-4 100.0 . 2006 2006
This Certified Reference Material was verlfled'16 .. !,!9.cord~Il~\Vith ISOIIEC 17025 (AT-1339) and ISO 17034 (AR-1463)
A product with a suffix (-lA, -2B, etc. or -O.1..~o2>ti~9Jpni\~)¢tnumber has had Its expiration date extended and Is identical 10 Ihe same 101 number wlthoutlhe suffix.
, Certified Analyte Concentration = Purliy';(p~epar~dGpfi~ntration.
The Uncertainty associated with the d~Aified co~¢",ntration reported on this certificate Is :1:2.4% and was determined in accordanca with ISO 17034. This value is the
combined expanded uncertainty and 'i~iittlsents.'~·i1 estimated standard deviation equal to the positive square root of the total variation of the uncertainty of
components. A normal dlstrll?l!Jlii6Js a·~~D.mll(t~niJ a coverage factor of K=2 Is chosen using approximately a 95% confidence lavel.
, All weights are traceablelh}6~g~NIST, T~s;No. 684/291344-18 & 684/292805_19
, Puritylldentity determined·:~Yone o/@'iire of the following methods: GC/MS, LC/MS, NMR, FTIR, Malting Point.
Labels andqe.rtlftgEltl;ls fOllo0\i.S:.C.911~Elntions in reporting numerical values: A comma (,) is used to separate units of one-thousand or greater. A period (.) Is used as
a decimal pl~2e riiai'kfir> ... . ...
The inforrnatlcti;:on thlsM'iiini;ate may not be reproduced without the express permission of the manufacturer. See reverse side for additional Information
Hazard Informatlgn;·:W(k~ser~fer to the SDS for Information regarding the hazards associated with using this material.
This product was :~.f~Rared according to in-house procedures and is guaranteed to be homogeneous.
Certified By:
Page 1 of 1 For use in routine laboratory analYSis.
AccuStandard is accredited to ISO 17034, ISO/IEC 17025 and certified to ISO 9001 :2015 QR·ORG/INO-OOl
Rev. 7/20
REPORT ID: 24E186 Page 210 of 217
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#223
Irvine, CA 92620
Quality System
Audited & Registered
by TUV USA to ISO 9001:2015
Catalog No.: Lot No.: Storage:
G34-3200-121020 480682 ::; -10 °C
-17
Compound
acetone
2-butanone (MEK)
4-methvl-2-oentanone (MIBK)
2-hexanone
Certified By:
naa scientrffc
Certificate of Analysis
For Chemical Emergency, Spill,
Leak, Fire Exposure or Accident
Call Chromanex Day or Night
800.390.4202
Date Received: 2.1 ~ 124
Rev 0 Page
Solvent: Exp. Date: Description:
PIT MeOH:Water 9:1 4/28/2027 Ketones Solution, 2500 mg/L, 1 m1 IS017034
CAS No Purity (%) Compound Lot No Concentration, ml!lL
67-64-1 99.6 196.271.4P 2498 :1:53.47 mWL
78-93-3 99.9 I 97.1.2P 2498 :1:53.51 mWL
108-10-1 99.88 198.421. J.2P 2500 :1:54.02 mWL
591-78-6 100 I 99.7.3P 2501 :I: 53.58 mWL
---------------------------------All weights are traceable through N. I. S. T. Test No. 8221264157-00.
Concentration (correct for ouritv) and uncertainty (95% confidence) values
Melissa Workoff
REPORT ID: 24E186 Page 211 of 217
. . . . . u~:~e .. Agilent . ~ ~ ~
Trusted ISO 17034
Product Name:
Product Number:
Reference Material Certificate
Product Information Sheet
Acrolein and Acrylonitrile Standard
AMN-623-1
lot Number: 0006788822
lot Issue Date: 20-Mar-2024
Storage Conditions: Store Frozen (-25° to -10°C): <3VI -32> -(~-/f Expiration Date: 31-Jul-2024
acrylonitrile 2009 ± 10llg/mL 000107-13-1 RM20527
Matrix: methanol (methyl alcohol)
Description:
This document is prepared in accordance with ISO 17034 and Guide 31. This analytical reference material standard was
manufactured and verified in accordance with an ISO 9001 registered quality system and analyte concentrations were verified by an
ISO 17025 accredited laboratory. The concentration and uncertainty value at the 95% confidence level for each analyte, determined
gravimetrically, is listed above.
T 1i;ll;ei;llJi lily:
The balances used for these measurements are calibrated with weights traceable to NIST in compliance with ANSI/NCSL Z540.3,
ISO 9001, ISO 17025, and ISO 17034. Calibrated Class A glassware is used for volumetric measurements. Thermometers are
calibrated against a NIST traceable thermometer in accordance with NIST Special Publication 1088.
Homogeneity:
This analytical reference standard was unitized according to an in-house procedure and is guaranteed to be homogeneous. There is
no minimum sub-sample size required.
Instructions for Use:
Sample aliquots for analysis should be withdrawn at 20°C to 25°C immediately after opening the container and should be processed
without delay for the certified values to be valid within the stated uncertainties.
Safety:
Refer to the Safety Data Sheet on www.agilent.comforinformationregardingthisanalyti.calreference material.
Intended Use:
This analytical reference standard is intended for the preparation of working reference samples for use in routine laboratory
analyses, calibration of instruments, validation of analytical methods, assessments of measurement methods, and continuing
calibration verification.
Expiration of Certification:
The certification of this analytical reference standard is valid until the expiration date specified above, provided the material is
handled and stored in accordance with the instructions given in this certificate. This certification is nullified if the material is
damaged, contaminated, or otherwise modified.
Page: 1 of 2
CSO-QA-015.2
250 Smith Street North Kingstown, Rhode Island 02852 www.agilent.com/quality
ISO 17025
Cert No. AT-1937
REPORT ID: 24E186 Page 212 of 217
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INTERNATIONAL
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Date manufactured: 7/13/2022
Original issue date: 7/13/2022
Catalog No.: Lot No.:
Z-G34 484785
-122455-05
Certificate of Anal • SIS
Date Received:
Page 1 of 2 Rev 0
Storage: Solvent:
-18°C +1-4°C PIT Methanol
Expiration
Date:
12-Jul-2027
Description:
Method 8260 Internal Standard Mix, 3-30, 2,500
mg/L, 1 ml
Certified Values:
The certified value is based on gravimetric and volumetric preparation ofthis CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of 2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, ml!/L
chlorobenzene-d5 3114-554 99.5 128.120.lP 2504 ;, 130
1,2-dichlorobenzcne-d, 2199-69-1 99.7 247.29.3P 2514 ;, 130
1,4-difluorobenzene 540-36-3 99.3 129.158.1.2P 2523 ;, 140
*Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods. This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GC/MS, HPLC, and HPLC/MS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
% Change = (-0.01 8In(x+3 1) + 0.1157) + 636.54y"3.202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assumes the container is stored at -10 DC and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
REPORT ID: 24E186 Page 213 of 217
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
C~RTIFICATE OF ANALYSIS
Catalog No: S-6524-0.25X
Description: Methyl acetate
Lot: 223081092
Solvent: Methanol
Date Certified: Aug 7, 2023
Expiration: Aug 7, 2033
Sample Size: 1 mL
Components: 1
Tel [phone]
Fax [phone]
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Hazards: Refer to SDS for complete safety information Storage Condition: Ambient (>5 °C)
Signal Word: Danger
Component CAS #
Methyl acetate 79-20-9
Certified Reference Material
Purity' %
100.0
Flr~pared
Conceht&~!ona
...!Qfil.~.7.)
2509
.:...... -,:'
'::-:::;:/;.:::::::./-:;
This Certified Reference Material was verified Ihaccordi'Ir19~'with ISO/IEC 17025 (AT-1339) and ISO 17034 (AR-1463)
Certified Analyte
Concentration'
(f!g/mL)
2506
A product with a suffix (-lA, -2B, etc. or -01, -02;ei\;J on,i,t$'lilt number has had its expiration date extended and is identical to the same lot number without the suffix.
, Certified Analyte Concentration = PuruY)(PreparedC(jn~Elntration.
The Uncertainty associated with the •. cil·rtified ccm¢entration reported on this certificate is ±2,4%. This value is the combined expanded uncertainty and represents an
estimated standard deviation equal to.'l.h", positive:square root of the total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K=2 is chosen uslngap'PJoxiiii~i~lya95% confidence level.
2 All weights are traceable.through NI$T,Test No. 684/291344-18 & 684/292805-19
3 Puritylldentlty determlneidby. one or more of the following methods: GC/MS, LC/MS, NMR, FTIR, Melting Point.
Labels and.tertlftpat"s foIl6WU;§;:.(jdnventions in reporting numerical values: A comma (,) is used to separate units of one-thousand or greater. A period (.) is used as
a decimal pl~q~m~l1<f,ir. . .
The informatlon':on thlsCerti.ncBte may not be reproduced without the express permission of the manufacturer. See reverse side for additional information
Hazard InfOmi~MIJ:Please refer to the SDS for Information regarding the hazards associated with using this material.
This product was'Pfepared according to in-house procedures and Is guaranteed to be homogeneous.
Certified By:
Page 1 of 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034, ISOIIEC 17025 and certified to ISO 9001:2015 QR'()AGIINQ·OQl
Rev. 7/20
REPORT ID: 24E186 Page 214 of 217
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Tel [phone]
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CERTIFICATE OF ANALYSIS
&\j\-b9-\'l-1~
Catalog No: TK-102-09S-12.5X
Description: Methylcyclohexane
Lot: 222081023
Solvent: Methanol
Hazards: Refer to SOS for complete safety information
Signal Word: Danger
Component
Methylcyclohexane
This Certified Reference Material was verified in accordance with ISOIIEC 17025
CAS #
108-87-2
Date Certified: Aug 2, 2022
Expiration: Aug 2, 2032
Sample Size: 1 mL
Components: 1
Storage Condition: Ambient (>5 ·C)
Certified Reference Material
Purity %
(GC/FID)
100.0
Pt!pared
Conceii~At!pn2
(i!9iML,)
Certified Analyte
Concentration'
()Jg/mL)
2538
A product with a suffix (-1A. -2B, etc. or -01, -02, etc.) on its lot number has had its expiration date extended and is identical to the same lot number without the suffix.
2 All weights are traceable through NI$T, Test No. 684/289871-17
, Certified Analyte Concentration = Purity x Prepared Concentration.
The Uncertainty associatedwitll the certified concentration reported on this certificate is :1:2.4%. This value is the combined expanded uncertainty and represents an
estimated standard deviatlO~ equal to the positive square root of the total variation of the uncertainty of components. A normal distribution is assumed and a coverage
factor of K=2 Is chosen uslngllPproxlmately a 95% confidence level.
Labels and certificates follow \,J.S.Conventions In reporting numerical values: A comma (,) is used to separate units of one-thousand or greater. A period (.) Is used as
a decimal piace marker.
The information on this certificate may not be reproduced without the express permission of the manufacturer. See reverse side for additional Information
Hazard Information: Please refer to the 80S for information regarding the hazards associated with using this mllterial.
This product was prepared according to in-house procedures and is guaranteed to be homogeneous.
Certified By:
Larry Decker. Organic QC Menager
Page 1 of 1 For use in routine laboratory analysis.
Accl.lStandard is accredited to ISO 17034, ISOIIEC 17025 and certified to ISO 9001 :2015 QR'()RG/INO·OOI
Rev. 7/20
REPORT ID: 24E186 Page 215 of 217
125 Market Street
New Haven, CT 06513
USA ~ AccuStandard®
$v 1-~8-(1-'ltj
CERTIFICATE OF ANALYSIS
Catalog No: TK-102-08S-10X
Description: Cyclohexane
Lot: 221101280
Solvent: Methanol
Date Certified: Oct 19, 2021
Expiration: Oct 19, 2031
Sample Size: 1 mL
Components: 1
Tel (203)786·5290
Fax (203)786·5287
www.AccuStandard.com
Hazards: Refer to SOS for complete safety information Storage Condition: Ambient (>5 ·C)
Signal Word: Danger
Component CAS #
Cyclohexane 110·82·7
This Certified Reference Material was verified i~"~@OWdan~~\Nith ISOIIEC 17025
Certified Reference Material • MI'E:III!~L:
AFI·1463
Purity %
(GC/MS)
100.0
e~"pared
Concentrallon'
.tJJQlMbl
~:~ >;:::'
.. \\~~\~~}rJ: ::"
Certified Analyte
Concentration'
(jJg/mL)
2008
A product with a suffix (·1A, ·28, etc. 0['01, '02, e;H:kd'it~ lot number has had its expiration date extended and is Identical to the same lot number without the suffix.
'All weights are traceable through NISI, Test t-I#;.684/289871-17
, Certified Analyte Concentration = Purity x PrEJ~~ied Concentration.
The Uncertainty associated:wiitithe certitiEldc6ncentration reported on this certificate Is ±2.4%. This value is the combined expanded uncertainty and represents an
estimated standard deviati.oli equal to,tne positive square root of the total variation of the uncertainty of components. A normal distribution Is assumed and a coverage
factor of K=2 I.s chosen usihg,.approxiiriately a 95% confidence level.
Labels and~@Wcates fOllovlLJ;$/Q8hventions in reporting numerical values: A comma (,) Is used to separate units of one-thousand .or greater. A period (.) is used as
a decimal pliiqe marker: .
The Informatiiinon this certificate may not be reproduced without the express permission of ths manufacturer. See reverse sids for additional information
Hazard Information: Please refer to the SDS for Information regarding the hazards associated with using this material.
This product was prepared according to In·house procedures and is guaranteed to be homogeneous.
Certified By:
Larry Decker, Organic ac Manegsr
Page 1 of 1 -Rev. 1 For use in routine laboratory analysis.
AccuStandard is accredited to ISO 17034. ISOIIEC 17025 and certified to ISO 9001 :2015 QR·ORG/INO·DOl
Rev. 7/20
REPORT ID: 24E186 Page 216 of 217
Date manufactured: 10/4/2022
Original issue date: 10/4/2022
Catalog No.: Lot No.: Storage:
Z-G34 489953 ::; -10°C
-020354-09
5580 Skylane Blvd
Santa Rosa, CA 95403
[phone]
[phone] Toll Free
[phone] Fax
Certificate of Anal • SIS
Date Received:
Page 1 of 2
Solvent:
PIT Methanol
Expiration
Date:
3-0ct-2027
Description:
2-Butanol Solution, 50000 mg/L, 1 ml
Rev 0
Certified Values:
The certified value is based on gravimetric and volumetric preparation of this CRM. This CRM has been
confirmed by gas chromatography (GC) or gas chromatograph/mass spectrometry (GC/MS) using an
internally developed method against an independent source. The uncertainty value is calculated for a 95%
confidence interval with a k value of2.
Compound CAS No. Purity (%) Neat Material Lot No. Concentration, mf!fL
2-butanol 78-92-2 99.8 354.7.lP 50000 ± 2600
+Not a certified value
Intended Uses:
This Certified Reference material (CRM) is intended for use as a calibration standard or a quality control standard for
Chromatography Equipment such as GC, GCIMS, HPLC, and HPLCIMS. It may aslo be used for various USEPA, NIOSH,
and ASTM methods. This Certified Reference material (CRM) is intended for use as a calibration standard or a quality
control standard for Chromatography Equipment such as GC, GCIMS, HPLC, and HPLCIMS. It may also be used for
various EN, ISO, EPA, and ASTM methods.
Recommended storage container for ampuled products after opening is a 12mmx32mm amber vial with screw cap Teflon
lined silicon septum. The modeled % change per day can be calculated using the following:
% Change = (-0.018In(x+31) + 0.1157) + 636.54y"3.202
where x = boiling point of the most volatile analyte in the mix (degrees K)
y = boiling point of the solvent (degrees K)
This model assumes the container is stored at -10°C and is unopened during storage. The user should determine what the
acceptable error for their process is and calculate the maximum number of days the opened ampule should be stored.
Method of Preparation:
All weights are traceable through N. 1. S. T. Test No. 822/264157-00. Concentration (correct for purity) and uncertainty
REPORT ID: 24E186 Page 217 of 217
This page intentionally blank
Draft 1 August 2024
A quantitative human health risk assessment (HHRA) was performed to evaluate and
identify the existing or potential adverse effects of site contamination that may be posed
to human health by exposure to hazardous substances at the Tooele Army Depot North
(TEAD-N).

Data were screened against risk-based screening levels to identify chemicals of
potential concern (COPCs) as shown in Table 1. Potential human receptors with a
complete exposure pathway that were evaluated included an outdoor worker. All
analyses were consistent with the current and anticipated future commercial/industrial
land use.

Carcinogenic risks and noncarcinogenic hazards were evaluated for all COPCs for all
potential exposure routes as presented in Tables 2, 3, and 4. No unacceptable cancer
risks were identified for the commercial/industrial scenario. This indicates that exposure
to the COPCs at TEAD-N does not pose a potential concern for adverse carcinogenic
human health effects. All noncarcinogenic HQs were below one for the outdoor worker
resulting in a cumulative HI that did not exceed one, and therefore, no unacceptable
noncancer hazards were identified for this receptor. This indicates that exposure to the
COPCs at TEAD-N does not pose a potential concern for adverse noncarcinogenic
human health effects. With that, no chemicals of concern (COCs) were identified.

The risk characterization followed the methodology described in US Environmental
Protection Agency (EPA) guidance. The EPA methods are appropriately designed to be
health-protective and tend to overestimate, rather than underestimate, risk. The risk
results are, therefore, conservative.
Table 1
Selection of COPCs, Groundwater
Tooele Army Depot North
Chemical Location ID Units Range of Detected
Concentrations1
Concentration Used
for Screening2 Retain as COPC?Rationale for Chemical
Deletion or Selection4
VOCs
1,2-Dichloroethane WIN-9549 ug/L 0.25 J - 0.26 J 0.255 0.17 c yes ASL
Carbon Tetrachloride WIN-9549 ug/L 1.4 - 1.4 1.4 0.46 c yes ASL
Chloroform WIN-9549 ug/L 0.28 J - 0.29 J 0.285 0.22 c yes ASL
Trichloroethene WIN-9549 ug/L 33 - 34 33.5 0.28 a n yes ASL
Notes:Definitions:
1 Minimum and maximum detected concentrations.c = cancer
2 Based on the average of the normal sample TEAD-05-24-WIN9569 and the field duplicate TEAD-05-24-S-WIN9569.COPC = Chemical of Potential Concern
3 Based on the EPA RSL Summary Table (TR=1E-6, HQ=0.1) for Tap Water dated May 2024.EPA = U.S. Environmental Protection Agency
a Trichloroethylene J = estimated value
4 Rationale:Selection Reason:Above Screening Level (ASL)n = noncancer
Shading indicates the chemical is selected as a COPC.RBSL = Risk-Based Screening Level
RSL = Regional Screening Level
ug/L = micrograms per liter
VOCs = Volatile Organic Compounds
RBSL3
Draft Page 1 of 1 August 2024
Table 2
Toxicity and Oral/Dermal Chemical-Specific Values for COPCs
Tooele Army Depot North
Gastrointestinal
Absorption Factor
Dermal Absorption
Factor Fraction Absorbed
Value Units Value Units Value Units Value Units Value Units Value Units Value Units Value Units Value Units
1,2-Dichloroethane 2.6E-05 (ug/m3)-1 9.1E-02 (mg/kg-day)-1 9.1E-02 (mg/kg-day)-1 7.0E-03 mg/m3 6.0E-03 mg/kg-day 6.0E-03 mg/kg-day 1 --1 4.2E-03 cm/hour 0.38 hours/event 0.133 L/m3
Carbon Tetrachloride 6.0E-06 (ug/m3)-1 7.0E-02 (mg/kg-day)-1 7.0E-02 (mg/kg-day)-1 1.0E-01 mg/m3 4.0E-03 mg/kg-day 4.0E-03 mg/kg-day 1 --1 1.6E-02 cm/hour 0.78 hours/event 0.133 L/m3
Chloroform 2.3E-05 (ug/m3)-1 3.1E-02 (mg/kg-day)-1 3.1E-02 (mg/kg-day)-1 1.95E-03 mg/m3 1.0E-02 mg/kg-day 1.0E-02 mg/kg-day 1 --1 6.8E-03 cm/hour 0.50 hours/event 0.133 L/m3
Trichloroethene 4.1E-06 (ug/m3)-1 4.6E-02 (mg/kg-day)-1 4.6E-02 (mg/kg-day)-1 2.0E-03 mg/m3 5.0E-04 mg/kg-day 5.0E-04 mg/kg-day 1 --1 1.2E-02 cm/hour 0.58 hours/event 0.133 L/m3
Chemical of
Potential Concern
Cancer Toxicity Data Noncancer Toxicity Data Dermal Permeability
Coefficient Lag Time
tauRfDoRfDadjGAFABSdFAKp
Volatilization
Factor
IUR SFo SFadj RfC VFw
Draft Page 1 of 1 August 2024
Table 3
Intake and Risk Calculation Parameters
Commercial/Industrial - Outdoor Worker
Tooele Army Depot North
Exposure Route Receptor Population Age Group Exposure Point Parameter
Code Parameter Definition Value Units Intake/Risk Equation
VFw Volatilization factor from water chemical-specific L/m3 VFw = (kwg)/(k)(μ/L)(H)*1000 (L/m3)
kwg Overall mass transfer coefficient from the water phase to the gas
phase 3.0E-06 m/s
k Air mixing rate 0.5
μ Average wind speed 0.45 m/s
L Average length 30 m
H Average depth 3 m
Cwoa Concentration of chemical in outdoor air from groundwater chemical-specific ug/m3 Cwoa = Cw x VFw
Cw Exposure point concentration of chemical in groundwater chemical-specific ug/L
CF Conversion factor 1,000 ug/mg
ECc Exposure concentration in outdoor air from groundwater - cancer chemical-specific ug/m3 ECc = (Cwoa x ET x ED x EF)/ATc
ECnc Exposure concentration in outdoor air from groundwater - noncancer chemical-specific ug/m3 ECnc = (Cwoa x ET x ED x EF)/ATnc
ET Exposure time 8 hours/day
ED Exposure duration 25 years
EF Exposure frequency 225 days/year
ATc Averaging time - carcinogenic 613,200 hours ATc = 70 x 365 days/year x 24 hours/day
ATnc Averaging time - noncarcinogenic 219,000 hours ATnc = ED x 365 days/year x 24 hours/day
ILCR Incremental lifetime cancer risk chemical-specific ILCR = IUR x ECc
HQ Hazard quotient chemical-specific HQ = ECnc/(RfC x CF)
IUR Inhalation unit risk chemical-specific (ug/m3)-1
RfC Reference concentration chemical-specific mg/m3
Iw = (Cw x IR x EF x ED x CF)/(BW x ATc)
Iw = (Cw x IR x EF x ED x CF)/(BW x ATnc)
Cw Exposure point concentration of chemical in groundwater chemical-specific ug/L
IR Ingestion rate 1 L/day
EF Exposure frequency 225 days/year
ED Exposure duration 25 years
CF Conversion factor 0.001 mg/ug
BW Body weight 80 kg
ATc Averaging time - carcinogenic 25,550 days ATc = 70 years x 365 days/year
ATnc Averaging time - noncarcinogenic 9,125 days ATnc = ED x 365 days/year
ILCR Incremental lifetime cancer risk chemical-specific ILCR = Iw x SFo
HQ Hazard quotient chemical-specific HQ = Iw/RfDo
SFo Oral slope factor chemical-specific (mg/kg-day)-1
RfDo Oral reference dose chemical-specific mg/kg-day
DADwOrganic = (2 x FA x Kp x Cw x sqrt[(6 x tau x tevent)/pi] x EV x ED x EF x SA x CF1 x CF2)/(BW x ATc)
DADwOrganic = (2 x FA x Kp x Cw x sqrt[(6 x tau x tevent)/pi] x EV x ED x EF x SA x CF1 x CF2)/(BW x ATnc)
FA Fraction absorbed chemical-specific
Kp Permeability coefficient chemical-specific cm/hour
Cw Exposure point concentration of chemical in groundwater chemical-specific ug/L
tau Lag time chemical-specific hours/event
tevent Event duration 1 hours/event
pi 3.14
EV Event frequency 1 events/day
ED Exposure duration 25 years
EF Exposure frequency 225 days/year
SA Surface area 3,527 cm2
CF1 Conversion factor 0.001 L/cm3
CF2 Conversion factor 0.001 mg/ug
BW Body weight 80 kg
ATc Averaging time - carcinogenic 25,550 days ATc = 70 years x 365 days/year
ATnc Averaging time - noncarcinogenic 9,125 days ATnc = ED x 365 days/year
ILCR Incremental lifetime cancer risk chemical-specific ILCR = DADw x SFadj
HQ Hazard quotient chemical-specific HQ = DADw/RfDadj
GAF Gastrointestinal absorption factor chemical-specific
SFadj Adjusted slope factor chemical-specific (mg/kg-day)-1 Oral SF divided by the GAF to derive dermal SF only if GAF is less than 0.50
SFo Oral slope factor chemical-specific (mg/kg-day)-1
RfDadj Adjusted reference dose chemical-specific mg/kg-day Oral RfD multiplied by the GAF to derive dermal RfD only if GAF is less than 0.50
RfDo Oral reference dose chemical-specific mg/kg-day
Ingestion
Inhalation Commercial/Industrial -
Outdoor Worker
Adult Vapors in Outdoor Air
from Groundwater
Commercial/Industrial -
Outdoor Worker
Adult Groundwater
Dermally absorbed dose of chemical in groundwater chemical-specific mg/kg-day
Iw Ingested dose of chemical in groundwater chemical-specific mg/kg-day
Dermal Contact Commercial/Industrial -
Outdoor Worker
Adult Groundwater DADw
Draft Page 1 of 1 August 2024
Table 4
Summary of Risks and Hazards
Commercial/Industrial - Outdoor Worker
Tooele Army Depot North
Scenario Timeframe:Current and Future
Receptor Population:Commercial/Industrial - Outdoor Worker
Value Units Value Units Value Units Value Units
1,2-Dichloroethane 0.255 ug/L 2.E-03 ug/m3 2.6E-05 (ug/m3)-1 6.E-08 7.E-03 ug/m3 7.0E-03 mg/m3 0.001
Carbon Tetrachloride 1.4 ug/L 1.E-02 ug/m3 6.0E-06 (ug/m3)-1 8.E-08 4.E-02 ug/m3 1.0E-01 mg/m3 0.0004
Chloroform 0.285 ug/L 3.E-03 ug/m3 2.3E-05 (ug/m3)-1 6.E-08 8.E-03 ug/m3 2.0E-03 mg/m3 0.004
Trichloroethene 33.5 ug/L 3.E-01 ug/m3 4.1E-06 (ug/m3)-1 1.E-06 9.E-01 ug/m3 2.0E-03 mg/m3 0.5
Exposure Route Total 2.E-06 0.5
1,2-Dichloroethane 0.255 ug/L 7.0E-07 mg/kg-day 9.1E-02 (mg/kg-day)-1 6.E-08 2.0E-06 mg/kg-day 6.0E-03 mg/kg-day 0.0003
Carbon Tetrachloride 1.4 ug/L 3.9E-06 mg/kg-day 7.0E-02 (mg/kg-day)-1 3.E-07 1.1E-05 mg/kg-day 4.0E-03 mg/kg-day 0.003
Chloroform 0.285 ug/L 7.8E-07 mg/kg-day 3.1E-02 (mg/kg-day)-1 2.E-08 2.2E-06 mg/kg-day 1.0E-02 mg/kg-day 0.0002
Trichloroethene 33.5 ug/L 9.2E-05 mg/kg-day 4.6E-02 (mg/kg-day)-1 4.E-06 2.6E-04 mg/kg-day 5.0E-04 mg/kg-day 0.5
Exposure Route Total 5.E-06 0.5
1,2-Dichloroethane 0.255 ug/L 1.8E-08 mg/kg-day 9.1E-02 (mg/kg-day)-1 2.E-09 5.0E-08 mg/kg-day 6.0E-03 mg/kg-day 0.000008
Carbon Tetrachloride 1.4 ug/L 5.3E-07 mg/kg-day 7.0E-02 (mg/kg-day)-1 4.E-08 1.5E-06 mg/kg-day 4.0E-03 mg/kg-day 0.0004
Chloroform 0.285 ug/L 3.7E-08 mg/kg-day 3.1E-02 (mg/kg-day)-1 1.E-09 1.0E-07 mg/kg-day 1.0E-02 mg/kg-day 0.00001
Trichloroethene 33.5 ug/L 8.2E-06 mg/kg-day 4.6E-02 (mg/kg-day)-1 4.E-07 2.3E-05 mg/kg-day 5.0E-04 mg/kg-day 0.05
Exposure Route Total 4.E-07 0.05
Exposure Point Total 7.E-06 1
Exposure Medium Total 7.E-06 1
7.E-06 1
7.E-06 1Total Risk Across All Media (ILCR)Total Hazard Across All Media (HI)
Groundwater Medium Total
Groundwater Groundwater Tap Water
Inhalation of Vapors in Outdoor Air
Ingestion
Dermal Contact
Medium
Units
Chemical of
Potential ConcernExposure RouteExposure
Point
Exposure
Medium
Noncancer Hazard CalculationsEPCCancer Risk Calculations
Hazard Quotient
(HQ)Value
Intake/Exposure
Concentration SF/IUR Intake/Exposure
Concentration RfD/RfCCancer Risk
(ILCR)
Draft Page 1 of 1 August 2024