DSHW-2024-006979

Clean Harbors Aragonite, LLC .
11600 N Aptus Road
P.O. Box 1339
Aragonite, UT 84029
June 27, 2024
Submitted via email to [e-mail]
Mr. Douglas J. Hansen, Director
Division of Waste Management & Radiation Control
Department of Environmental Quality
195 North 1950 West
P.O. Box 144880
Salt Lake City, UT 84114-4880
RE: Second Quarter 2024 Calibration Error Results
Clean Harbors Aragonite, LLC
EPA ID# UTD 981 552177
Dear Mr. Hansen,
In accordance with Attachment 15 Section 7.2 of the Clean Harbors Aragonite, LLC RCRA Permit,
attached are results of the Second Quarter 2024 Calibration Error Testing, which indicate that the
continuous emission monitors (CEM) are in proper working condition.
I hereby certify under penalty of law that this document was prepared under my direct supervision in
accordance with a system desi.gned to assure that qualified personnel properly gather and evaluate the
information submitted. Based upon my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the infonnatioo submitted is , to the best of my knowledge and
belief, true, accurate and complete . r am aware that there are significant penalties for submitting false
information, including the possibility of fine and imprisonment for known violations.
Should you have any questions regarding this matter, please contact me at the number listed below.
William Simmons
Facility GM III
Clean Harbors Aragonite, LLC
11600 North Aptus Road
PO Box 1339
Grantsville, Utah 84029-1339
(o) 435.844.8351
(c) 870.310.6029
[e-mail]
www.cleanharbors.com
DSHW-2024-006979
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MEMORANDUM FOR RECORD
DATE: June 27, 2024
SUBJECT: CALIBRATION ERROR TESTING
CLEAN HARBORS ARAGONITE, LLC
The calibration error testing for the # 1 CEM was completed for the carbon monoxide (low and
high) analyzers, the oxygen monitor, total hydrocarbon analyzer, and the carbon dioxide monitor.
The results are given in the table below:
Instrument Date of Test Error Error mid Error high Pass criteria zero/low
CO lo 5/9/2024 0.38 0.20 1.12 5% of span
CO hi 5/9/2024 0.05 0.42 0.10 5% of span
02 5/16/2024 0.03 0.04 0.11 0.5% volume
THC 5/10/2024 0.10 0.33 0.86 5% of span
CO2 5/16/2024 0.20 0.14 0.02 0.5% volume
The calibration error testing for the #2 CEM was completed for the carbon monoxide (low and
high) analyzers, the oxygen monitor, total hydrocarbon analyzer, and the carbon dioxide monitor.
The results are given in the table below:
Instrument Date of Test Error zero/low Error mid Error high Pass criteria
CO lo 5/9/2024 0.26 0.26 0.10 5% of span
CO hi 5/9/2024 0.55 0.40 0.08 5% of span
02 5/16/2024 0.23 0.19 0.05 0.5% volume
THC 5/15/2024 0.08 0.32 0.72 5% of span
CO2 5/16/2024 0.20 0.14 0.01 0.5% volume
The procedure followed was the calibration error procedure as described in 40 CFR part 266,
Appendix IX. Attached to this memo are copies of the field data sheets.
Date of Test: 9 May 2024
Quarter: fl 1..
Monitor Type: Low CO
Manufacturer: Servomex
Serial Number: 653204
Run Number Calibration
Value
1 -zero 19.78
2-mid 70.48
3 -hi h 150.6
4-mid 19.78
5 -zero 70.48
6-hi h 150.6
7 -zero 19.78
8-mid 70.48
9 -hi h 150.6
vUUUllUUU:) .L,.UH:):)1UH 1V.lU.UHV1
Calibration Error Test
Field Data Sheet
Test Technicians: Nathan Haney _____ ..,__ _____ _
mA Value
5.64
9.61
16.23
9.61
5.64
16.21
5.65
9.60
16.24
Monitor
Response
20.50
70.13
152.88
70.13
20.50
152.63
20.63
70.0
153.0
Mean
Difference =
Calibration
Error% of
Span=
CEM # --=---1 _________ _
Span: 0 -200 PPM
Zero/Low 1 Mid 1 High 1
2 2 2
.76 .40 2.23
3 3 3
.38 .20 1.12
Test Times (start and finish): 08:09 -08:19
Cylinder ID No. CC359903
Certification Date : 13 JuJ 2020
Expiration Date : 13 Jul 2028
Cylinder ID No. CC480934
Certification Date: 23 Dec 2019
Expiration Date: 23 Dec 2027
Cylinder ID No. ALM024621
Certification Date : 14 Aug 2020
Expiration Date: 14 Aug 2028
Comments:
1 Absolute Difference= I Calibration value -
Monitor Response I
2 Mean Difference= Sum of Absolute Differences/ 3
3Calibration Error= (Mean Difference/ Span) x 100%
3
CO pass/fa ii
</= 5% of span
</=10 ppm (lo range)
</=100 ppm(hi range)
2
02 and Co2 pass/fail
Criteria
Co2 and 02 </= 0.5%
Date of Test: 9 May 2024
Quarter: A'.' :l.
Monitor Type: Low CO
Manufacturer: Servomex
Serial Number: 653305
Run Number Calibration
Value
1 -zero 19.78
2-mid 70.48
3 -hi h 150.6
4-mid 19.78
5 -zero 70.48
6-hi h 150.6
7 -zero 19.78
8-mid 70.48
9-h~h 150.6
'"-.,,V.1.1L11J.UVU.:) L.1.lJ.J..:).:JJ.V.1.1 .lV.lU.1.llLV.l
Calibration Error Test
Field Data Sheet
Test Technicians: Nathan Haney ------'--------
mA Value
5.62
9.67
16.07
9.69
5.62
16.07
5.63
9.68
16.05
Monitor
Response
20.25
70.88
150.88
71.13
20.25
150.88
20.38
71. 0
150.63
Mean
Difference=
Calibration
Error% of
Span=
CEM# 2 ------------
Span: 0 -200 PPM
Zero/Low 1 Mid 1 High 1
.51 .52 .19
3 3 3
.26 .26 .10
Test Times (start and finish): 08:26 --08:37
Cylinder ID No. CC359903
Certification Date: 13Jul2020
Expiration Date: 13Jul2028
Cylinder ID No. CC480934
Certification Date: 23 Dec 2019
Expiration Date: 23 Dec 2027
Cylinder ID No. ALM024621
Certification Date : 14 Aug 2020
Expiration Date: 14 Aug 2028
Comments:
1 Absolute Difference = I Calibration value -
Monitor Response I
2 Mean Difference= Sum of Absolute Differences/ 3
3Calibration Error= (Mean Difference/ Span) x 100%
3
CO pass/fail
</= 5% of span
</=10 ppm (lo range)
</=100 ppm(hi range)
2
02 and Co2 pass/fail
Criteria
Co2 and 02 </= 0.5%
Date of Test: 9 May 2024
Quarter:
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Calibration Error Test
Field Data Sheet
Test Technicians: Nathan Haney _____ _,__ _____ _
Monitor Type: High co ---=-----------
Manufacturer: Servomex
Serial Number: 653204 ------------
Run Number Calibration mA Value
Value
1 -zero 1251. 5.98
2-mid 3520. 9.69
3 -hi h 7495. 15.98
4-mid 1251. 9.71
5 -zero 3520. 6.0
6-hi h 7495. 15.98
7 -zero 1251. 6.0
8-mid 3520. 9.70
9-hi h 7495. 15.97
Monitor
Response
1237.50
3556.25
7487.50
3568.75
1250.0
7487.50
1250.0
3562.50
7481.25
Mean
Difference =
Calibration
Error% of
Span=
CEM # ---'-1---=-----------
Span: 0-10000 PPM
Zero/Low 1 Mid 1 High 1
5.17 42.50 9.58
3 3 3
.05 .42 .10
Test Times (start and finish): 13:54 --14:04
Cylinder ID No. CC266951
Certification Date : 4 Oct 2022
Expiration Date: 4 Oct 2030
Cylinder ID No. CC213578
Certification Date: 1 Sep 2023
Expiration Date: 1 Sep 2031
Cylinder ID No. CC330683
Certification Date : 1 Sep 2023
Expiration Date: 1 Sep 2031
Comments:
1 Absolute Difference= I Calibration value -
Monitor Response I
2 Mean Difference = Sum of Absolute Differences/ 3
3Calibration Error= (Mean Difference/ Span) x 100%
3
CO pass/fail
</= 5% of span
</=10 ppm (lo range)
</=100 ppm(hi range)
2
02 and Co2 pass/fail
Criteria
Co2 and 02 </= 0.5%
Calibration Error Test
Field Data Sheet
Date of Test: 9 May 2024
Quarter:
Monitor Type: High CO
Manufacturer: Servomex ------------Serial Number: 653305 ------------
Run Number Calibration mA Value
Value
1 -zero 1251. 6.08
2-mid 3520. 9.70
3 -hi h 7495 . 15.99
4-mid 1251. 9.70
5 -zero 3520. 6.ld'
6-hi h 7495. 15.97
7 -zero 1251. 6.09
8-mid 3520. 9.69
9-hi h 7495. 15.98
Test Technicians: Nathan Haney _____ __,__ _____ _
Monitor
Response
1300.0
3562.50
7493.75
3562.50
13'12.50
7481.25
1306.25
3556.25
7487 .50
Mean
Difference =
Calibration
Error% of
Span=
CEM # _2~----------
Span: 0 -10000 PPM
Zero/Low 1 Mid 1 High 1
55.25 40.42 7.50
3 3 3
.55 .40 .08
Test Times (start and finish): 15:08 --15:17
Cylinder ID No. CC266951
Certification Date: 4 Oct 2022
Expiration Date: 4 Oct 2030
Cylinder ID No . CC213578
Certification Date: 1 Sep 2023
Expiration Date: 1 Sep 2031
Cylinder ID No. CC330683
Certification Date: 1 Sep 202 3
Expiration Date: 1 Sep 2031
Comments:
1 Absolute Difference = I Calibration value -
Monitor Response I
2 Mean Difference= Sum of Absolute Differences/ 3
3 Calibration Error= (Mean Difference/ Span) x 100%
3
CO pass/fa ii
</= 5% of span
</=10 ppm (lo range)
</=100 ppm(hi range)
2
02 and Co2 pass/fail
Criteria
Co2 and 02 </= 0.5%
Date of Test: 16 May 2024
Quarter: J., l,
Monitor Type: 02
Manufacturer: Servomex
Serial Number: 4021
Run Number Calibration
Value
I -zero .996
2-mid 9.033
3 -hi h 15.04
4-mid .996
5 -zero 9.033
6-hi h 15.04
7 -zero .996
8-mid 9.033
15.04
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Calibration Error Test
Field Data Sheet
Test Technicians : Nathan Haney ------''-------
mA Value
4.63
9.78
13.65
9.80
4.64
13.64
4.64
9.78
13.64
Monitor
Response
.98
9.03
15.08
9.06
1.0
15.06
1.0
9.03
15.06
Mean
Difference =
Calibration
Error% of
Span=
CEM # --=-1 __________ _
Span: 0-25 %
Zero/Low 1 Mid 1 High 1
.01 .01 .03
3 3 3
.03 .04 .11
Test Times (start and finish): 13:37 --13:48
Cylinder ID No. EB0122991
Certification Date: 1 Nov 2021
Expiration Date: 1 Nov 2029
Cylinder ID No. CC47205
Certification Date: 14Jul 2020
Expiration Date: 14Jul2028
Cylinder ID No. CC151392
Certification Date: 31 Aug 2020
Expiration Date: 31 Aug 2028
Comments:
1 Absolute Difference = I Calibration value -
Monitor Response I
2 Mean Difference = Sum of Absolute Differences/ 3
3 Calibration Error= (Mean Difference/ Span) x 100%
3
CO pass/fail
</= 5% of span
</=10 ppm (lo range)
</=100 ppm(hi range)
2
02 and Co2 pass/fail
Criteria
Co2 and 02 </= 0.5%
~Vl1Lll1UUU;:) .L,11J.1;:);:)1Vl1 H.1Vl1HV1
Calibration Error Test
Field Data Sheet
Date of Test: 16 May 2024 Test Technicians: Nathan Haney _____ ...,__ _____ _
Quarter:
Monitor Type: 02
Manufacturer: Servomex ------------Serial Number: 652525 ------------
Run Number Calibration mA Value
Value
1 -zero .996 4.59
2-mid 9.033 9.75
3 -hi h 15.04 13.62
4-mid .996 9.73
5 -zero 9.033 '4.60
6-hi h 15.04 13.63
7 -zero .996 4.61
8-mid 9.033 9.77
9-hi h 15.04 13.64
Monitor
Response
.92
8.98
15.03
8.95
.94
15.05
.95
9.02
15.06
Mean
Difference =
Calibration
Error% of
Span=
CEM# -=-2 __________ _
Span: 0-25 %
Zero/Low 1 Mid 1 High 1
2 2 2
.06 .OS .01
3 3 3
.23 .19 .OS
Test Times (start and finish): 13:20 -13:35
Cylinder ID No. EB0122991
Certification Date: 1 Nov 2021
Expiration Date: 1 Nov 2029
Cylinder ID No. CC47205
Certification Date: 14Jul 2020
Expiration Date: 14Jul2028
Cylinder ID No. CC151392
Certification Date : 31 Aug 2020
Expiration Date: 31 Aug 2028
Comments:
1 Absolute Difference = I Calibration value -
Monitor Response I
2 Mean Difference = Sum of Absolute Differences/ 3
3Calibration Error= (Mean Difference/ Span) x 100%
3
CO pass/fail
</= 5% of span
</=10 ppm (lo range)
</=100 ppm(hi range)
2
02 and Co2 pass/fail
Criteria
Co2 and 02 </= 0.5%
Date of Test:
Quarter:
Monitor Type:
Manufacturer:
Serial Number:
10 May 2024
THC
Thermo Scientific
1203299855
Calibration Error Test
Field Data Sheet
Test Technicians: Nathan Haney _____ _,__ _____ _
CEM# -----=-1 __________ _
------------Span: 0 -100 PPM
Run Number Calibration mA Value
Value
1 -zero .0 4.0
2-mid 35.04 9.52
3 -hi h 75.38 15.87
4-mid .0 9.59
5 -zero 35.04 4.02
6-hi h 75.38 15.92
7 -zero .0 4.03
8-mid 35.04 9.55
9-hi h 75.38 15.98
Monitor
Response
.00
34.50
74.19
34.94
.12
74.50
.19
34.69
74.88
Mean
Difference =
Calibration
Error% of
Span=
Zero/Low1 Mid 1 High 1
.10 .33 .86
3 3
.10 .33 .86
Test Times (start and finish): 14:48 --15:07
Cylinder ID No. ALM024524
Certification Date: 24 Feb 202 4
Expiration Date: 24 Feb 2032
Cylinder ID No. EB0122971
Certification Date: 3 Oct 2022
Expiration Date: 3 Oct 2030
Cylinder ID No. CC189252
Certification Date : 6 Sep 2023
Expiration Date: 6 Sep 2031
Comments:
1 Absolute Difference = I Calibration value -
Monitor Response I
2 Mean Difference= Sum of Absolute Differences/ 3
3Calibration Error= (Mean Difference/ Span) x 100%
3
CO pass/fail
</= 5% of span
</=10 ppm (lo range)
</=100 ppm(hi range)
2
02 and Co2 pass/fail
Criteria
Co2 and 02 </= 0.5%
3
Date of Test: 15 May 2024
Quarter: ~ l-
Monitor Type: THC
Manufacturer: Thermo Scientific
Serial Number: 1203299856
Run Number Calibration
Value
1 -zero .0
2-mid 35.04
3 -hi h 75.38
4-mid .0
S -zero 35.04
6-hi h 75.38
7 -zero .0
8-mid 35.04
9-hi h 75.38
Calibration Error Test
Field Data Sheet
Test Technicians: Nathan Haney _____ _,__ _____ _
mA Value
3.99
9.60
16.13
9.70
3.99
16.18
3.98
9.66
16.22
Monitor
Response
-.06
35.0
75.81
35.63
-.06
76.13
-.13
35.38
76.38
Mean
Difference=
Calibration
Error% of
Span=
CEM # -'2=-------------
Span: 0 -100 PPM
Zero/Low 1 Mid 1 High 1
.08 .32 .72
3 3 3
.08 .32 .72
Test Times (start and finish): 14:14 --14:30
Cylinder ID No. ALM024524
Certification Date: 24 Feb 2024
Expiration Date: 24 Feb 2032
Cylinder ID No. EB0122971
Certification Date: 3 Oct 2022
Expiration Date: 3 Oct 2030
Cylinder ID No. CC189252
Certification Date: 6 Sep 2023
Expiration Date: 6 Sep 2031
Comments:
1 Absolute Difference = I Calibration value -
Monitor Response I
2 Mean Difference = Sum of Absolute Differences/ 3
3Calibration Error= (Mean Difference/ Span) x 100%
3
CO pass/fail
</= 5% of span
</=10 ppm (lo range)
</=100 ppm(hi range)
2
02 and Co2 pass/fail
Criteria
Co2 and 02 </= 0.5%
Date of Test: 16 May 2024
Quarter: ~~
Monitor Type: Co2
Manufacturer: Servomex
Serial Number: 653204
Run Number Calibration
Value
1 -zero 2.007
2 -mid 7.006
3 -hi 15.14
4-mid 2.007
5 -zero 7.006
6-hi h 15.14
7 -zero 2.007
8-mid 7.006
_J -high 15.14
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Calibration Error Test
Field Data Sheet
Test Technicians : Nathan Haney _____ .,__ _____ _
mA Value
5.76
9.68
16.12
9.76
5.76
16.08
5.77
9.72
16.10
Monitor
Response
2.20
7.10
15.15
7.20
2.20
15.10
2.21
7.15
15.13
Mean
Difference =
Calibration
Error% of
Span=
CEM # --=--1 __________ _
Span: 0-20 %
Zero/Low 1 Mid 1 High 1
.20 .14 .02
3 3 3
.99 .72 .11
Test Times (start and finish): 10:33 --10:43
Cylinder ID No. XC0313108
Certification Date: 30 Aug 2016
Expiration Date: 30Aug 2024
Cylinder ID No. EB0123063
Certification Date: 23 Dec 2019
Expiration Date: 23 Dec 2027
Cylinder ID No. EB0106597
Certification Date: 5 Mar 2019
Expiration Date: 5 Mar 2027
Comments:
1 Absolute Difference = I Calibration value -
Monitor Response I
2 Mean Difference = Sum of Absolute Differences/ 3
3Calibration Error= (Mean Difference/ Span) x 100%
3
CO pass/fail
</= 5% of span
</=10 ppm (lo range)
</=100 ppm(hi range)
2
02 and Co2 pass/fail
Criteria
Co2 and 02 </= 0.5%
Date of Test: 16 May 2024
Quarter: ¥ ;x.
Monitor Type: Co2
Manufacturer: Servomex
Serial Number: 653305
Run Number Calibration
Value
1 -zero 2.007
2-mid 7.006
3 -hi h 15.14
4-mid 2.007
5 -zero 7.006
6-hi h 15.14
7 -zero 2.007
8-mid 7.006
9 -pigh 15.14 ------·
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Calibration Error Test
Field Data Sheet
Test Technicians: Nathan Haney ------'--------
mA Value
5.77
9.71
16.13
9.73
5.76
16.10
5.77
9.70
Monitor
Response
2.21
7.14
15.16
7.16
2.20
15.13
2.21
7.13
Mean
Difference =
Calibration
Error% of
Span=
CEM # _2=------------
Span: 0-20 %
Zero/Low 1 Mid 1 High 1
2 2 2
.20 .14 .01
3 3 3
1.01 .68 .07
Test Times (start and finish): 12:40 -12:50
Cylinder ID No. XC031310B
Certification Date: 30 Aug 2016
Expiration Date: 30 Aug 2024
Cylinder ID No. EB0123063
Certification Date: 23 Dec 2019
Expiration Date: 23 Dec 2027
Cylinder ID No. EB0106597
Certification Date: 5 Mar 2019
Expiration Date: 5 Mar 2027
Comments:
1 Absolute Difference = I Calibration value -
Monitor Response I
2 Mean Difference= Sum of Absolute Differences/ 3
3Calibration Error= (Mean Difference/ Span) x 100%
3
CO pass/fail
</= 5% of span
</=10 ppm (lo range)
</=100 ppm(hi range)
2
02 and Co2 pass/fail
Criteria
Co2 and 02 </= 0.5%