DSHW-2024-007827

We$lnghouse RECEIV
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SOLID & HAZARDOUS WASTE
WESTINGHOUSE ELECTRIC COMPANY
Western Zirconium Plant
Quarterly Monitoring Report
Third Quarter: September 2005
Volume II of II
Appendix I)
Prepared by
November 2005
HHfi IVED
soL,#ffiffiA*
WESTINGHOUSE ELECTRIC COMPANY
Western Zirconium Plant
Quarterly Monitoring Report
Third Quarter: September 2005
Volume II of II
Appendix D
Prepared by
URS Corporation
November 2005
This report is for Westinghouse use only, and is not to be distributed to third parties outside the Westinghouse organization.
This report is based on data, site conditions and other information that is generally applicable as of November 2005, and the
conclusions and recommendations herein are therefore applicable only to that time frame.
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Quarterly Monitoring Report - Third Quarter 2005
Ongoing Monitoring Program
November 2005
APPENDIXD
ANALYTICAL LABORATORY REPORTS
URS
o
a
STI-Denver
Data Packages
Note: Data Packages re in order as discussed in the Data Validation Report (see Appendix C):
Data Pacloge D5I020230
Data Package D5Il00l53
Data Packagc D51070270
Data Pacloge D5I030139
Dab Package D5I130198
Data Package D5I090176
Data Package D5I080243
STL Denver
4955 Yarrow Street
Arvada, CO 80002
Tel: [phone]
www.stl-inc.com
STL
303 431 7t7t
ANALYTICAL REPORT
Western Zirconiurn Proj ect
I-ot #: D5I020230
Sheri O'Connor
URS Corporation
8181 East Tufts Avenue,
Denveq CO 80237
STLDENVER
Linda L. Benkers
Project Manager
September 28,20As
Severn Trent Laboratories, lnc.
Table Of Contents
Sta ndard Del ive rabl es with S u pporti ng D ocu mentati on
Report Contents
$tandard Dellverables
(fne Cover Letter and the Report Cover page are conslderecl integral
parts af this Standard Deliverable pacleage. Ihis report is lncomplete
unless all pages indicated in thts Table of Contents are included.)
. Table of Contentso Case Narrutive
I Executlve Summary - Detection rrlghlights
o Methods Surnmery
o Method/Analyst Sumrnnry
. Lot Sample Summary
. Analyticnl Resultso QC l)ata Association Surnmary
. QC Sample Results
o Chain-of-Custody
Su pporti ng Docu mentatl on
Note: A one-page "Description of Supporting Docwnentation" rs
provided at the heginning of this section.).
r Volatile GC/MS
o Semivoletile GC/IUS
r Voletile GC
r Semlvolatile GC
. LCI1VIS or HPLC
r Metals
I GenerrlChemlstry
r Radiochemistry
r Subcontracted Data
Number of Pages
aqs
Check below when
supporttng
docuurentation is
present.
mFnEmmn
STL Denver
Case Narrative
DsI020230
With exceptions noted as flags or footnotes, standard analytical proiocols were followed in the
analysis of the samples and no problems were eircormtered or anomalies observed. All
laboratory quality control samples araly.d in corfunction with the samples in this project were
within established oontrol limits, with any exceptions noted.
The test results presented in this report meef all requirerne,nts of NELAC, and any excqrtions are
noted. This report shall not be reproduced, excqlt in fulI, without written permission fiom the
Iaboratory.
Sample Recelvlng
Seven samples were received under chain of custody on September 2,2A05. The samples were
received in good condition at teurperatures of 2.3"C, 2.4oC, 2-6"C, 2.3"C, 2.7"C,2.8"C, and
5.8"C
Sample aliquots for all radiological analyses are logged in under a separate lot and were seot to
STL St. Louis; 13715 Rider Trail North; Earth City; MO 63045, phone [phone].
GC/MS Volatiles SWE46 82608
Sample D5I020230-@3 dernonstratod a recovery below the control limit for the surrogate
toluenc-d8. The sample mahix was foarny; therefore the sample was heatd with an antifoauring
age,nt and te-analyzed at a dilution The re-analyzed sarnple also demonstrated a low recovery for
the surrogate toluene-d8, confirming the matrix interference. The initial undiluted data is
rEported.
The MS/]vISD perfomed on sample D5I020230-004 was in control.
No other anomalies were observed.
GC/IUS Semivolatlles, SW846 8270C
Sample D5I020230-003 dernonshated recoveries below the control limi* for sunogates 2-
fluorophenol and phenol-d5. Sample D51020230-005 demonstrated recoveries below the control
limits for surrogates phenol{S,2, 4, 6-tribromophenol, and 2-fluorophe,nol. These samples were
reextracted past holding time in batch 52575M- The re-extractd samples demonstrated
recoveries below the contol limits for phenold5, 2, 4,6-hibromophenol, and 2-fluorophenol,
confirming mafrix inte,rfsrmm Target ggmpound$ lysrg not dctigtgd in eifrgr run nild bofit uEto
of data for samples 003 and 005 are included in this report.
The MS/I\IISD associated with batch 5249rc3 was performed on sample D5I020230-004 and was
in conhol.
A MSA{SD associatd with re-extaction batch 52575M could not be
insufficient sample volume. An LCS/LCSD was anallzed and was in control.
STL Denver
performed due to
The average Relative Standard Deviation (RSD) for all in the Initial Calibration
(ICAL) was less than l5%; therefore the ICAL met all criteria for the method. However, the
ICAL associated with samples D5I020230-002 through 004, the MSA{SD, 005 and 006 in batch
5249103 deuronstrated RSD greater than 15% for benzidine at32.9Yo.
The avoage Relative Standarid Deviation (RSD) for all eomporxrds in the Initial Calibration
[CAL) was less than I5%; therefore the ICAL met all criteria for the method. However, the
ICAL associated with the re-exftaction of saurples D5I020230-003 and 005 in batch 52575U
demonstrated RSD greater than 15Yo for benzidine at l6.0Yo, 1,4-naphthoquinone at 27.TYa, and
rnethapyrilsne at 35.8%.
The ICV second source verification of the initial calibration associated with the re-extraction of
samples D5I020230-003 and 005 in batch 5257544 demronshatd recoveries above the control
limits for benzidine at 228Yo, and aniline at l37Yo. The continuing calibration verification was
acceptable for these compounds and these compounds wse not detected in the associated
samples.
No other anomalies were observed.
GC/IUS SemlvolaflIes Best Pracdce - Pentachlorophenol SW846 8270C
Sample D5I020230-003 demonstrated recoveries below the contrrol limit for surrogates phenol-
d5, 2, 4, 6-tribrornophenol, terphenyl-d5, and 2-fluorophenol. Sample D5I020230-005
derronstrated rrcoveries below the control limit for surrogates 2-fluorophenol, Z, 4, 6-
hibromophenol, and phenol-dS. The sarrples were not reextracted sincc matrix interfe,rence was
confirmed by the full scan re*-extraction associated with batch 525754 (see above).
The MS/MSD associated with batch 5250435 was ffiormed on sarnple D5I020230-004 and
demonstrated percent recoveries below the control limits for pyrene. This samplo was analyzed
for pentachlorophenol only. Due to a data system constraint, the associated Best Practice LCS
and MSiMSD QC data are rcported with all standard spiking compounds.
No other anomalies were observed.
Total Metals, SW846 60108, 6020 & 7470A
Sarnples D5I020230-002 through 006 were analped at dilutions for several metals by methods
60108 and 6020 due to matrix interference and/or high target compound concenfrations. The
re,porting limits are adjusted accordingly.
Sample D5I020230-006 demonstated makix interfqence with no dilution required for lead. The
sample displayed a negative reading greater than the reporting limit for lead. The reporting limit
is adjusted accordingly and associated data are flagged *G'.
Sample D5I020230-003 demonshated matrix interference during the mercury digestion
procedure. This sample was re-digested at a lOX dilution with acceptable results. The reporting
limit is adjusted accordingly.
STL Denver
Magnesiunr was detected in the method 60108 blank at a concenhation below thereporting limit
but above the method detection limit. Associated positive sample results are flagged 'T'.
The method 6020 MSAdSD performed on sample D5I020230-004 deinonshated recoveries
below the control limits forcadmium and abovethe contol limits for selenium.
The method 60108 MSA{SD performed on sample D5I020230-004 dernonstratd recoveries
above the conhol limits for arse,nic. The MS demonstrated a recoverybelow the confrol limit for
lead. Also, the relative percent difference (RPD) for iron was ebove the conhol limit. The
recoveries of calcium" magnesiunr, potassium, and sodium were not calculated because the
sample concentrations were greater than four times the sprking amounts.
The method 7470A MSA{SD performed on sample D5I02023G'004 dernonstated recoveries
below the oontrol limit formercrnry.
The method 7470AMSA{SD associated with batch 5262486 was performed on a sanple fiom
another client and/or lot and was not in control.
No other anomalies were observed.
General Chemistry, Verious Methods
Samples D5I020230-002 thrrough 006 were analyzdl at dilutions for several compounds due to
hig! analyte concenfrations. The reporting limits are adjusted accordingly and the associated
data is flagged "Q".
Fluoride and sulfate were detected in the method blanks at ooncenkations below the reporting
limits, but above the method detection limits. Associated positive sarnple results are flagged "J".
The MS/}vISD perforrred on samples D5I020230-002 and D5I020230404 were in control for
ammoniaasN.
The MS/IvISD performed on sample D5I020230-004 was in contol fornitrat+nitrite and sulfate.
The method 325.2MSA{SD was performed on sample D5I020230-004 however; the recoveries
fo,r chloride could not be calculated due to the required dilution and/or interfering analytes.
The MS/IvISD perfomred on sample D5I020230-004 demonstrated percent recoveries below the
control limit for fluoride and above the control limit for total cyanide.
AII other MSA{SD samples were perforrred on samples from other clients and/or lots and were
in control.
ThepH duplicateperformod on sampleD5l020230-0M was in conkol.
No other anomalies were observed.
STL Denver
EXEffi W - Iletection Highlights
D5IO2A23-fJ
RESUIJT
REPORTTNG
LIMfT IINfTS
AI{IA[.,YTICAIT
METHODPARiAMETER
sflB-9I-O-OgO1Os OeloLlus O7:OO OO2
Barlum
Nicke1
ZLnc
CalcLum
Potassirrrn
Mag:reeium
Sodium
Acetone
Chloride
Fluoride
Total C[ranJ.de
pH
Sulfate
Ammonia as N
SHB-9-O9O1"O5 Oe/AL/ OS 1O:55 OO3
Selenium
Areenic
Barfuun
NlckeI
Calcium
Potaseiurn
Magrneelrrrn
Sodtum
Carbon dLsulfid.e
ChI orod i bromome E tran e
B romod i chl o rometstran e
Bromof orm
Bromomethane
Chloroform
Chloromethane
Chlorlde
Fluorlde
Nit,rate
Nitrat,e-Nl-trite
Total Cyanlde
pH
Sulfate
Ammonia as N
0 ,43
0,032 B
o.a24 B
1.60 0
1800
r-2 00 ,r
35000
15
ss000 0
0.14 ir
0.0028 B
8.7
13 O0O J, Q
o.38
o.094 B
0 .23
1.5
o. 029 B
2100
6800
9200.J
770 00
1,3
5.4
3-0
34
0.42 J
o .77 Lr
5.3
200O0O 0
a.26 ir
3200
3200 0
0 .037
7,0
5500 J, Q
864
(Contlnued on nexu
0.050
0 .20
0.10
2.0
30
2.4
50
10
1,000
0. 10
0.010
0.10
2500
o-10
a .20
o. 15
0.10
0.40
2-A
60
2 -O
100
1.0
f--o
1.0
1-0
2-O
1.0
2.O
4000
0. 10
0.10
100
0-0L0
0. 10
1200
2.5
page)
$Jg /T'
mg/r.
ms/r,
nrg /l'
mg/r'
mg/1.
mg lT,
lug/t
mg/r,
rng / T'
mg/T,
No Units
rng/r,
mg/t
lrrrglr,
mglT"
mg/t
mglt'
mglT,
mg lT'
mg /I,
nrg/r'
ug/T,
ug /r'
ug/r,
ug/t,
ug/t-,
:ug/r'
vg /T'
mg/L
rtug/L
ms/L
nts/L
mg /r,
No UniUs
nslL
ng/r,
SIrl845 50L0B
sw846 60108
sw846 50108
sw84 5 50108
sw84 5 60108
gw84 6 6 0108
sw846 50108
sw846 82608
McAI{w 325.2
MCAI{I{ 34O.2
sw845 9Or. AB/ 901-2A
sw846 90408
DIICAI{I{ 375 .4
MCAWTil 350 . l-
sw846 6020 o
sr{846 60108
9w846 60108
sw8 46 50108
sw846 50108
sw8,06 50108
gw8{6 50108
sw846 60108
sril846 82508
SI1f845 82608
sur845 82508
sul845 82608
sw846 82608
sI{846 82608
sw846 82608
MeAWw 325.2
MCATtI[il 344 -2
MeAvit!il 353.2
MCAWW 353 .2
srrr845 eOIOB/90L2A
sw846 90408
MCAWW 3'.15.4
McAvf,W 350 . l-
STL Denver
E W-MIfigLIigLts
D5r020230
RESUITT
REPORTING
IJIMIT TINITSPARAMETER
gwB-1o-o9o1o5 oglol,los 12:1O O04
gelenl,um
Arsenic
Barium
Nickel
Vanadium
Zi.n.c
Calcium
Iron
Potassirrro
Magrreslurn
Sodiurn
ChI orodibrornomethane
Bromodlch1oromethane
Bromoform
Clrlorof orm
ChlorLde
Fluorlde
Total Cyanlde
pH
Sulfate
Ammonia acr N
8HB-3-O9O1O5 09/0L lOS 13:37 OO5
0.040 B
o,025 B
o.41
0.015 B
0.014 B
o.024 B
Ls00
o.38 B
170 0
1,200 ,I
33 000
0.55 ,I
a.62 J
1.6
0.23 J
ss000 0
o.15 ;I
o.0058 B
8.8
1-4000 .f,Q
o .45
0. oo13 B
0.0081 B
0.17 B
0.o58
o .24
0.012
0,036 B
o - 015
o.0L9 B
850
o.26 B
27A
540 J
62 00
0.058 B
0.7L J
9.7,J
0.48 J
2 .'.l
Cadmium
Selenium
A].urninum
Areenic
Barium
Copper
NickeI
Vanadium
ZLnc
Calcium
fron
Potaesirrrn
Magnesium
Sodium
Zirconlum
Chlorodibromomethane
Acetone
Bromodichloromethane
Brornoform
0.080
0.o75
0.050
o .20
0-050
o. 10
2.0
1.,0
30
2.0
50
l-.0
1.0
1.0
1-O
l-0 00
0-l"o
0 . 01,0
o-10
2500
0 .10
o. o10
0.020
o_50
0.015
0. 010
0,01"0
0 - 040
o.010
o. 020
1,0
0.50
1_5
1.0
25
0. 075
J-.0
l-0
1.0
1.0
page)
mg /T'
mg/r,
mg/l'
rns /r,
mg /t'
w/t,
mg/T.
mg/r,
nlg/L
mg/r'
mg/r,
:ug/T'
ug/r,
lug/t
ug /r-'
$tg /r'
ms/L
lrltg/t"
No Unlts
firg/T'
lrrq/t,
mg/t
mg/L
mg/r-,
mg/r.
mg/r,
mg/r,
mg /r,
mg/r'
mg/r,
mg/r,
rfig /T'
tug/T.,
rnglL
mg/r.
wlL
ug/L
ug/t
us/r,
ug/L
sw846 6024
sw846 50108
sw846 60108
sw845 50108
sw846 60108
sw845 60L08
sw846 50108
sw845 5010B
sw845 50108
sw845 50108
sw846 501-OB
sw846 82608
slr846 82508
sw846 82508
sw845 82508
MCAI{W 325.2
lrIcAWI{ 340 -2
sw846 9O1OB/ 901,2A
sw845 9 04 0B
MCAT{I!r 375 -4
Meastw 350.1
8W846 6020
swB46 6020
sw846 60108
sw845 5010ts
gw84 6 60108
9w845 50I-08
sw846 60108
sw845 50108
sw846 60108
9w845 60108
sw845 50108
9w846 50108
sYr845 60108
sw846 50108
sws46 60108
sw846 82508
st[845 82508
sw846 82508
sw846 82508
STL Denver
(Continued on next
-I}ef,wtionHighlights
D5rO20230
RESUIJT
R-BPORTING
LMfT UNfTS
A}IAIJYTTCAL
METTIODPARJAI{ETER
gHB-3-O9Or.Os O9IOLIOS 13:37 OO5
Chloroform
Chloride
Fluorlde
Nltrate
NLtraEe-r.ritrlte
Tota1 Qyanide
pH
Sulf at,e
AmmonLa aa N
gwB-7-o9o1o5 oglol,los 14:2o 006
Selenium
Arsenic
Barium
Nicke1
Caleirrm
Iron
PoEassium
Magneeiufii
Sodium
Carbon disulfide
ChI orodl-bromome t hane
Bromodteh1oromethane
Bromoform
Chloroform
Chloride
Fluorlde
Total Clranide
pH
Sulfatre
Arnmonla as N
rB-o91OO5 Oel Ouos 1{:3O OO7
Acet,one
Chloroform
11
1300O O
2.2 J
160
L?A O
0-015
8.0
lgoo J, Q
130 0
0,0027 B
0.083
o .13
0.0019 B
r.3 0
o.050 B
300
57O LT
2900
0.99 J
o.29 J
0,25 J
o,95 J
o - 32 ir
ssoo 0
l- .1- .I
0,0048 B
8-2.
l-L00 ir,Q
0. o58 B
2.1_ J
o _L7 LI
1.0
200
0.10
0.10
5.0
o.010
o_10
500
5,0
0. o10
0.0L5
o.010
0.040
0 .20
0 ,10
3-0
o.20
5.0
1,0
1.0
1,0
1.O
J,.0
100
0,10
0. o10
0.l-0
500
0,10
1-0
1.0
ug /r'
mg /t-,
mg/r,
mg/t'
mg/r,
mg/t'
No Units
ng /r'
ms/L
mg/t'
mg/L
mg/t
mg/r,
mg/r,
mg/r.,
mg/L
rrl,g/r-,
mg/T-,
ug /t'
ug/r-,
ug/t'
ug/r,
:ug/r'
mg/t'
mg/t'
mg/t'
No Units
mg/T'
mg /1,
ug /t'
ug lt
sw846 82608
MCAWW 325.2
IvICAlrnV 34A .2
l,tcAr{r{ 353.2
MCAy{W 353 .2
sw846 9Ol OB/ eO12A
sr'I845 90408
II{CAWW 375 ,4
MeAWW 350.1
9w846 8250B
sw845 82 508
sw845 5020
srir846 60L08
sril84 6 6 0108
:ffil::31:: osw84 6 6 01"08
slf84 5 6 0108
sv[84 6 5 0108
sw845 60108
sw845 82608
sw846 82608
sw84 6 82508
sw846 82608
9w845 82508
MCAI{I{ 325 .2
MCAWW 340.2
sw846 9O1OB/ 901-2A
9w845 90408
MCAWW 375.4
MCAWW 350. 1
STL Denver
MEIHODSW
Dsro20230
PARAMEIrER
A}IALYTICAIJ
METIIOD
PREPAR'A:rION
METHOD
pH Aqueous
Chloride (Colorirnetrlc, Autornat ed Ferricya-nide)
Fluorlde (Potentiometrlc, ron Selective Electrode)
InductJ,vely Coupled Plaema ( fCp) MeEals
rCP-I*Ig (602o)
Mercury in tiquid Waste (Manual Co1d-Vapor)
Nitrate
NLtrate-Nitrlte
Nitrogen, Arunonla
SernivolaEL1e Organic Compounde by Ge/rq9
Sulfate
Tota1 Clranlde
Trace Inductlvely Coupled Plasrna (fCp) Metals
Vo1atile Organics by GC/MS
RefereuGcr:
su[845 90408
MCAWW 325 -2
MeJtWW 34,4.2
sw8,06 50108
sw846 5A20
sw846 7 47AA
MCA['im 353-2
MCAWW 353.2
MCABWiI 350.1
sr{846 8270C
MCAWW 375.4
9w846 e01aBl e01
sw846 60108
sw845 82608
sw845 90{08
MCASIW 325 -2
MCA!{V0 340,2
sw846 3 0104
9w845 3 0204
sr{845 7470A-
MCAWII 353-2
MeArfiir 353 - 2
IICATYW 350.1
sw845 3520e
MCAI{W 375 .4
9w845 90108
9w846 3 010A
sw8{5 so3 oF/ 825
MCAT{T{
sw846
,Methode for Chemieal ilnalyeLe of Water and wastesr,
EPA-600/4-79-o2o, March 1983 and subsequent revisionE.
trTest Methods for Erraluating Solid ifaste, Physical/Chemlcal
MeEhodai, rhl.rd Bdition, November 1986 and lta updatea.
STL Denver
AI{TALYTICAI,
METTIOD
METHOI}/ANALYSTW
Dsroz0230
ANATYST
AI{AITYST
ID
MCABW{ 325 .2
MCAWW 340.2
MeAIrnt 35O.1
MCA[{I{ 353.2
MCAWIiI 375.4
swB45 50108
sw846 60108
sw846 60108
sw846 6020
sw846 747AA
sw846 82508
9w845 8270C
sw845 827 AC
sw845 eo1 aB/ 9O12A
sw846 9040B
Refereuceg:
MCAVIW
gw8{ 5
Evra Kud1a
Fougere M. Danl-e1le
Claire L,Lkar
C1aire r,ikar
DuetJ. o. Criqui
.fane1 MotLchha
.7ane1 Motichlca
Irynn-Anne Trudell
Thomas lrill
,fanice S. Collins
Heather Despres
pavid Kidd
iloamn Petergon
DustL o. criqtri
Andrit,a Scofleld
001 L67
o0648L
o 04 382
o04 382
o05s8 9
o02 862
2862
00654s
005 929
011558
o0925 0
00753 5
011 67 4
005589
004409
BMethods for Chemlcal Anal-ysie of Water and Wastes",
gpa-ooo/a-79-o2o, March 1983 altd subsequent revlsions.
rTeat Methode for EvaluatJ-ng solid waste, Physlcal/Chemical
Methodatr, rhlrd Editl.on, rilovernber 1986 and its updatea.
STL Denver
SAIT{PIT
D5rO20230
SAI"IPITED SAI.{P
DATE TIMEwo#SAMPI,8#CLfEMf SAII{PIrE ID
II,IfP2 OOl
HJVQA 002
H.r\/Qs OO3
HinrQg 0 04
H.ITRM OO5
H.lvRv 006
HJVru( OO7
TB- 09 0105
swB-9L0-090105
swB- 9 - 090L0s
swB-10-0e0105
swB-3-090105
swB-7-0g0L0s
FB- 09L00s
oe/oL/as
a9 / o1los o7 : oo
oe/aa/as 1o:55
09 /o1/ as 12: 1o
oe / 01/0s L3 :37
ae/oL/as 1{:20
a9 /oL/ os 14 :30
rvclfB (s) :
- Thc amlyticll rcsrlB of tho rrrnpla llgod atrovo ero prcecucd on rhc folowing ps3a.
- AU otqrlations ar€pcfomrirt bcforc rourrdinj to rvoi, mrd{tT6r0rs ln crlcubtod rqtlts-
- Rcnrlrs nolcd es 'ND'were rm dctcclld er or ebovc thc tM IfuniL
- Thir rcport mu$ not be rcpro&rcut, eroel,t iE firll. wirhou tte wrlucn epproval of thc labonory,
- Rdills for drE followin! par8mcters erc mvcr rportod on 8 dry wdgbt basis: color, corrosivity, denslty, ,trshpoinr, lgnlrabillty. tsyers, odor,
priat filrcr rcsr, pH, poroslty prcsotro, r€adiviry, rcdox porddd. +cciflc gr:vrty. spot rcsB. sollds, sofubillty, tf(Wererufc. viscosity, ard weight.
STL Denver 10
IIRS Oorlnratio
Clieut Saqfie ID: rB-0901O5
GC/IE vol"atl.I.ee
Ipt-Saqfle *. - -: D5I020230-001 Xork Order *- - -: HWP21AA
Date Saq[ed.-.-. Og/oL/oS Date Received- -r og/Ozlos
Prep Datse -r og/L2/os analyeis rrate- -z o9/L2/05
kep Bat(t *- - - : 5256224 Ina-lye,.a Tine- - : O9:15
Diarrtim Factor: 1
llethod- - - -: SW845 82508
Irlatrixo--------! wQ
REgt IrT
REPORTTNG
IJIMIT TINIT9PARAMETER
Acet,onltrile
Acrolein
Acrylonl-trile
Ally1 ehlorLde
Carbon disulfide
1-Chlorohexane
2 -Chloroethy1 vinyl ettrer
Cyclohexane
D 1 ch1 oro f luoromethane
trane-L,a-Dlchloro-
2-butene
t ,l-Diox€ule
Ethano].
Ethyl methaerylate
Iodomethane
Igobutyl alcohol
Methacrylonltrile
I'IethyI methacryIate
Propionltrile
Tet.rahydrofuran
Vinyl acetate
n-Butar1o].
tert-Butyl alcohol
Chl- o rod ibromome thane
Cyclotrexanone
Ethy1 acetat,e
Ethyl ether
Hexane
Ieopropyl ether
2-Nltropropane
rri ehlorot ri f 1 uoroethane
2-Pentanone
cis- 1, 4 -Dichloro-2-butene
Acetone
Benzene
BromodichloromeEhane
Bromoform
Bromomethane
ND
t[D
t[D
t[D
TID
IID
tlD
IUD
ND
ND
IUD
ND
ND
t[D
ND
TID
ND
}TD
ND
}TD
ND
T{D
ND
ND
ND
IUD
ND
IUD
ND
ND
}UD
t[D
ND
IID
ND
IUD
ND
(Cont,inued
200
200
l-,0
L,0
50
10
1-O
2A
5-O
2_O
50
50
1.0
20
5.0
2.0
1.O
10
2.0
1.0
2.0
L-0
10
1.0
L.0
1.0
2.A
on next page)
20 vg/I'
zo ug/t'
20 ug/L
2.o ug/1"
1 . o LLg/r,
1. O Ltg/T'
2 . a ug/r,
2.0 ug/L
2 . a ug/T,
1- . 0 ug/l'
:u,g/T,
:ug/r.
ug /r,
lug/L
:ug/T-,
trg/L
:ug/r-,
ug/r,
ug/r,
ug/r,
ug/r,
ug /r"
ug /r'
ug /r,
ug/r,
ug/L
vglL
ug/t
.ug/r,
ug/t
ug/L
ug/T,
ug/r,
uslL
us/1,
ug/t"
ug/t'
STL Denver
IIRS CorporErtion
C1ieut Saryfie II): 1B-o9O1Os
sf.lt{6 vol,atsileo
D5I02O23O-001 Work Orrder f;- - - : HJ\IP21AA llatrlJ(. - - O - - - . , : I{Qfot-Saryl1e
PARAIVIEfER RESI ITT
REPORTING
I,IMIT I'NTTS
2 -Butanone (MEK)
Carbon tet.rachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibrornomethane
A, Z-Dibromoettrane ( EDB )
L ,z-Dichlorobenzene
t, 3 -Dich]-orobenzene
L , 4-Dictrlorobenzerre
Dl chlorodi f luoromethane
L , L-Dichloroettrarre
L ,Z-Dichloroethane
1, l-Dtchloroethene
a ,Z-DichloroeEhene
( total )
cl-s - L, 2 -Diehloroethene
trans - L, 2 -Dl,ehloroethone
L ,2-DichJ"oropropane
cis - 1, 3 -Dlctrloroproperae
Lrans -L ,3 -Dichloropropene
EthyI-benzene
2 -IlexaJrone
Methylene chloride
4 -Methyl -2-pentanone
Styrene
1, 1, L 12- Tetrachloroethane
1, 1 ,2 ,2 -Tetrachloroethane
Tetrachloroettrene
Toluene
L ,2 ,4-Trl-chloro-
benzene
1, 1, f. -Trlchloroethane
1 , 1 ,z-Trichloroethane
Trlchloroethene
Tri chl orof luorome thane
L ,2, 3 -frichloropropane
VJ-nyI chloride
xyrenes (tqtal)
n-Butylbenzene
sec-Butylbenzene
Isopropylbenzene
ND
IUD
ND
![D
TUD
ND
ND
IUD
ND
ND
ND
ND
I$D
IUD
ND
ND
llD
ND
ND
r[D
IUD
IUD
ND
ND
ND
IUD
ND
IID
ND
IUD
tuD
5.O
1.0
1-0
2.0
1,,0
2.O
1.O
1.0
f-.0
1.O
1.0
2.0
1.0
1.0
L,o
1--0
1.0
1-O
1.0
1.0
1.0
l_.0
5.0
1.0
5.0
1.0
1.0
1.0
1,.0
1.0
1,0
1.0
1-O
1.0
2.4
L.0
1,0
2,0
1.0
1,0
1.0
next page)
uglt
:ug/I'
rug/L
ug/t-'
ug/r'
ug /t
ug/t'
:ug/T.
ug/r,
lug/t
ug/t"
ug /t'
ug/r,
ug/l'
lug/r'
:ug/r,
:ug/T'
ug /t'
ug/r,
ug/r'
ug/L
:ug/r-,
ug/t'
ug/t'
ug/r,
ug/L
:ug/r,
ug/r,
ug/t
ug/T'
ug/r,
ll'g /L
ug/L
:ug/T'
ug /r'
uglr,
lug/t-,
us/L
ug/1,
ug/r,
ug/t,
ND
ND
ND
IUD
ND
ND
IID
I{ID
IID
ND
(Continued on
1,2
STL Denver
: Dsr020230-001
URS Corpor:atLon
Cl.ient, Sanpl.e ID: Tts-OgOLOs
K/Hg vol.atl-I.es
Ilork Order f,- - -: Hin/P21AA tlatrlx,.--.-----: wQIot,-Sanpl.e *.
PARAT'IETER REST,IJT
L, 2, 4 -TrLmethylbenzene
1, 3, 5 -Trimethylbenzene
n-Propylbenzene
tert -Butylbenzene
2 -Chlorotoluene
4 -Chlorot,oluene
L ,2-Dlbromo-3 -
chloropropcure (DBCP)
1 , 3 -Dichloroprop€rne
2 ,Z-Dlchloropropane
1, 1-Dichloropropene
Hexachlorobutadiene
4 - faopropyltoluene
Methyl tert-butyl ether
L ,2, 3 -trichlorobenzene
Brornobenzene
Bromochlorornethane
Naphtha3-ene
ST}RROGATE
ND
tlD
IID
IUD
IUD
ND
IID
ND
t[D
TID
}UD
luD
ND
IID
IUD
IID
t[D
PERCENT
RECO\IERY
REPORTTNG
LfMfT UNITS
1- O ug/t'
1 - O ug/r,
1. o ug/L
1.0 ug/L
1. O ug/I'
1. o ug/T,
2.A LL1/T'
1.O
5.0
L.O
1,0
1-0
5.O
1-o
1.0
1.0
1.0
RECO\IERY
tIMITg
(zE L18)
$z 128 )
(za 118)
(77 1L7)
vg /T'
Ltg/L
:ug/t
tJg/T'
ug /r.
trg /T'
ug /r,
ug/r,
ug/r'
ug/r,O
D ib romo f 1 uorome th€rne
A , 2 -Dichloroethane - d4
4 -Bromofluorobenzene
Toluene-dB
91"
83
94
10s
O
STL Denver 13
IIRII Corlrcnatl.on
aB-o9010s
GCAfs vol-atLlee
D5IA2O23A-001 lIork Order *: HiruP2lAA ratri-x: wQIot-8aryfle
r'rAss sPEeTRoMErEn/nata SYSTEM
PARAIVTETER
Unknown
rurB ($) :
(MSos ) fEIUTATIVEIJY IDEIITIFIED
ESTTI,IATED
COMPOT]NDS
RETENTTON
TTMEcAq # BESITLT ._T]NITS
2 .9 ,f M 11 . O15 :ug/L
M: Rcsult was mcasurod ugainst neare$ intcrnnl eandard assunrlng s rcsponse factor of l.
L4
Iot-Saqll.e #- - -:
Ilate Saryl1ed..--I
Prep Da.tgoo----3
Prep Batch *- - -:
Dll.ution h.ctor:
Dsro20230-002
09 / ollos o7: oo
oe / Lzl os
s256224
1
IIRS CorporatLon
Cl-i"ent, 8aryfle ID : SrsB-91O-o9O1O5
etcll+6 vol.atil.es
Uork Ordor *- - -: H.J1IQA1A3
rlate Received. - r a9 / a2 / as
Anatysl-e llat'e- - i 09 / L2 / os
enaAyais Tlme--: 09:34
Ilethod- . ., - - - - - : 9W845 82608
llatri:r,!!-,----i GW
REST'LT
REPORTTNG
IJfMIT UNITSPARAMETER
Acetonitrrile
Acrolein
Aerylonltrile
AIIyI chloride
Carbon dl-sulflde
1*Chlorohexcrne
z-Chloroethy1 vinyl eLher
Cyc1.ohexarre
Di ch1 oro f 1 uorornetharre
trang -L,4-Dichloro-
2-butene
L r [-Dioxane
Ethano].
Ethyl methacrTlate
IodomeLtrane,
rsobutyl alcohol
Ivlethacryl0nitriIe
Methy1 methacrylat.e
PropLonitrile
Tetrahydrofuran
Vinyl acetate
n-But,anol
tert-Butry1 alcohol
Chlorodibromomethane
Qyclohexanone
Ethyl acetate
Ethyl ether
Hexane
Isopropyl ether
2 -Nitropropane
Tr I chl oroL r L f luoroethane
2 - Pentanone
cl-s- 1, 4 -Dlchlora-z-but,ene
Acetone
Benzene
Bromodichloromethane
Bromoform
Bromomethane
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
![D
I(D
IUD
ND
IID
ND
ND
ND
IID
ND
ND
ND
IID
}UD
ND
ND
}TD
ND
t[D
ND
16
I'ID
DID
IID
IilD
20 vg /r,2a ug/L
20 vg /I'
2 . O ug/r,
1.0 ug/I'
1.0 Ltg/I'
2.O ug/t
2. o ug/l'
2 . O :ug/T'
1.0 :ug/I'
2AA
200
1.O
1.0
50
10
1-,0
2A
5-O
2.O
50
s0
1.0
20
5.0
2.0
1.0
r.0
2.4
1,0
2.o
1.0
10
1.0
1.0
1.0
2.4
ug/t,
vg/r'
ug/t
ug /T,
]ug/L
rtg /t'
ug/T'
:ug/t 'ug/r-,
ug/t'
:ug/r'
ug/r,
ug /r'
rtg /r'
vg/L
:ug/t'
rtg /r,
ug/r,
ug/r,
ug /t,
vg /I'
ug/r,
u.glr,
ug/t
ug/T,
trg/L
ug/r,
STL Denver
(Continued on next page)
IIRSI Corponation
Cl.l.eut Aarytle ID: SrB-91O-O9O1O5
rcll,.l8 vol-ati1ee
DsI02A230-002 rork Order f - - -: HfVQAIA3 Itratrix-: GTVIot-Saup1e
PARAMETER
2 -But€ul,one (lrIEK)
Carbon tetrachloride
Chlorobenzene
Ch]-oroettrane
Chloroform
Chloromettrane
DibromomeEhane
L, z-Dibrornoetlrane ( gDg)
t ,Z-Dichlorobenzene
L ,3-Dichlorobenzene
L , A-Dl-chl-orobenzene
D i chlorodi f luorornethane
1, l--Dlchloroethane
L ,Z-Dlch].oroethane
1 , 1 -Dichloroethene
L ,Z-Pl-chloroethene(rotaI)
cis - 1, 2 -DLehloroeLhene
tran s - 1, 2 -Dichloroethene
a ,Z-DiehJ-oropropane
cis - L, 3 -Dl,chloropropene
trans- 1, 3 -Dlchloropropene
Ethylbenzene
2-Hexanone
Methylene chlorlde
4 -Methy1 -2 -pent;rnone
SEyrene
1, 1, L,2 -Tetrachloroethane
1, 1 ,2 ,2 *Tetrachloroethane
feErachloroeEhene
Toluene
L ;2 t 4-Trichloro-
benzene
1, 1, 1 -TrLchl-oroettr^ane
1, 1, z-Trichloroethane
Trichloroethene
Tr I chloro f luorome thane
L, 2, 3 -TrLchloropropErne
vinyl chloride
[ylene$ [[otal)
n-Butylbenzene
sec-Butylbenzene
fsopropylbenzene
REPORTTNG
I,IMIT UNTTSRESTIIJT
ND
TID
TUD
ND
IUD
IUD
}ID
IID
ITD
IID
(Continued on
ND
t[D
ND
IID
ND
tlD
ND
ND
ND
ND
r[D
ND
t{D
ND
rvD
t[D
IUD
t{D
ND
ND
l[D
ND
t[D
ND
DID
ND
ND
luD
ND
ND
IID
1-0
1.0
f_.0
L,0
1.0
f-.0
5.0
1-0
5.0
1.0
1.0
1.0
1,O
1.O
1.0
1-0
1.0
l_.0
2.4
1.0
1.0
,.0
1.0
1.0
L.0
next, page)
5.0 :ug/r,
l- . 0 lJg/I'
1.0 ug/T,
2.a ug/L
1.0 ug/1"
2 . o :ug/t,
1. O ug/t
1. O uS/T'
1- O ug/t'
1. O ug/I'
1 . o llg/r,
2.a ug/t
L . 0 lJg/T'
1. O ug/t'
1. O tJg/I'
1 .0 ug/I,
ug/t
ug /T'
ug/r,
ug/t
ug/r,
ug/1,
us /T,
ug/t,
ug/T'
ug/r'
ug/r,
ug/n
ug/r'
vg/r,
:ug/r.'
ug/t'
ug/r,
ug/t
ug/t-,
uglT.
:ug/L
us/t
ug/r,
ug/r,
ug/L
STL Denver 1,6
Cl.ient Saryrle
UnS Corporatim
cf,.firs
II}: SHB-91O-O9O105
Vo1atl-Ies
Iot-Sanp1e # -
PARAIT,IETER
: D5I OZA23 o- 0 02 f,ork Order *.
R-ESIILT
ND
t[D
ND
ND
TID
ND
![D
ND
ND
ND
IID
ND
ND
ND
ND
ND
lUD
PEREET{TT
RECOTfERY
: HWQA1A3 Dlatrir---o.o..o: GW
REPORTINC}
frfMIT UNfTS
-
L, 2, 4 -Trlrnethylbenzene
1 , 3 , 5 -Trimethylbenzene
n-Propylbenzene
tert -Butylbenzene
2-ehloroLoluene
4-Chlorotoluene
L ,Z-Dlbromo-3 -
chloropropEure (DBCP)
1, 3 -Dlchloropropane
2 ,2-DichloropropErne
1 , 1-Dichloropropene
Hexachlorobut,adLene
4 -fsopropylEoluene
Methy1 tert -butyl ether
L, 2, 3 -frichlorobenzene
Bromobenzene
Brornochloromethane
Naphthalene
SITRROGATE
1. O rug/L
1. o :ug/L
l- , O ug/I'
1.0 ug/I'
1 .0 ug/r,
L.0 ug/l'
2 -a ug/L
1,0
5.0
1.O
1.0
l-.0
5.0
1,O
1-0
1.0
1-0
RECO\IERY
IJIMITg
(tt 118 )
(62 L28l
(78 118)
fit 1"17)
ug/t'
ug/r'
ug /r'
ug/L
ug lt
ug /r'
vg/r,
ug/r'
ug /r.
ug/t,
D ibromo f I uo rorne t trane
L, 2- Dichloroetlrane - d4
4 -Bromofluorobenzene
Toluene-dB
103
LL2
1,0d
95
STL Denver 1,7
Iot-Saryr1e *: Dsf 02023 O- OA2
IUIASS SPECTROMETER/DATA SYSTEM
PARAMETER
None
URA Corporatlon
sf,B-910-090105
(Jcfi{6 vo1a,til.es
Ilork Order *: HLfVQAIA3
(USNS) TENTETTVEIJY IDEIITIFIED
ESTIMATBD
e3,s #RESUITT
llatrlx: GW
EOMPOT'NDS
RETENTTON
TIME UNTTS
:ug/t'
STL Denver 1B
CII-mt Saryrle
TIRII Corporation
eclus
ID: SHB-9-O9O105
VoIatri].ee
o
f-ot-Baryile fi- - -:
Date SanE 1ed- - - l
Prep Datg-.,---i
Prep Batch fi- - -:
DL].utlon Faetor:
DsI020230-003
09 IaL/05 Lo:55
oe/Lz/os
52s6224
L
Ilork Order *--.: H.n/QsLAE
rlate Receiwd.. - ! 09 / 02 / as
Anaaysis Date- - 3 ag/Lzl os
Jmalyeio TLme--r O9:53
Itgtlod, -, - . . . . - 3 Sw846 82608
tiatrfur-?-!-r-oo: GW
RESIIIJT
RBPORTING
I,IMIT t}NITgPARAMETER
Acetonttrile
Acrolel-n
AcrylonitrtIe
Allyl chlorlde
Carbon, dl-su]-fl-de
1-Chlorolrexane
2-Chloroethyl vJ-ny1 ether
Clrclohexane
D I chl oro f luoromethane
trans-7-r4-Dichloro-
2-but.ene
L,[-Dioxane
Bthanol
Ethy1 mettracrlrlate
Iodomethane
fsobutyl alcohol
Methacrylonitrile
MeE,hyI methacrylate
Propionitrlle
Tet.rahydrofuran
Vinyl acetate
n-Butano1
tert-Buty1 alcohol
Ctrlor thane
Cyclohexanone
Ethyl acetate
Ethyl ether
Hexane
Isopropyl ether
2 -Nitropropane
fr i chl orot ri f luoroethane
2-Pentanone
cls - L, 4 -Dichloro- 2 -buEene
Acetone
E0nEene
Brmilichlormethane
Bmfonn
Bromethane
ND
![D
tlD
IID
r,.3
ND
ND
ND
}TD
ND
IUD
}(D
ND
ND
ND
IUD
ND
I(D
ND
ND
ND
ND
5-4
ND
ND
ND
ND
ND
ND
ND
llD
}UD
ND
IID
3-O
34
o.42 J
(Contlnued
2a ug/T'
2A :ug/T'
20 ug/L
2.a ug/L
1- O urglr'
1- 0 :ug/I'
2 . A ug/l'
2.a ug/t,
2.O ug/l'
1.0 ug/t'
200
200
1.0
1-O
50
10
.f-.0
20
5.O
2 _A
50
50
1-o
2A
5.0
2.O
L.O
10
2.O
1.O
2-A
1,0
1_0
1.0
1-O
1.0
2-A
on next page)
ug/r,
ug /t,
ug /t
ug/t,
ug/t'
ug /t'
ug /T'
ug /T'
ug/r,
ug/t'
vg /r'
:ug/t,
1u.glI,;
vg /t'
ug/r'
wg/T-,
ug/r-,
ug/t'
trg /r,
ug/r,
ug/t'
ug/t'
ug/t
uslL
ug/r,
ug/n
ug/r,
STL Denver
IIRIT Corporation
Cl.ient Sa4lle ID: SI|B-9-O9O1O5
sclI,a vo]-atL]'es
DsIA2A23O-003 Hork Order *- - - i HiIyQSlAE l.Iatri;r- ! o - ! - - . - 3 GWIot-$aqll.e
PARJNIETER
2_Butanone (I.GK)
Carbon tetrachlorlde
Chlorobenzene
Chloroethane
Chf-orpform
Chlorrethane
Dibromomethane
L, Z-Dl-bromoethane ( EDB)
L ,Z-Dichlorobenzene
1, 3 -Dichlorobenzene
L , -Dlchlorobenzene
Di chlorodi f luororne thane
1 , 1 -DLchloroeEhane
t ,?-Diehloroethane
1 , 1-Dtchloroettrene
t ,Z-Dichloroet.hene
( total )
cLs -L ,2 -Dlchloroetlrene
trane - L, 2 -Dichloroethene
L,Z-Dichloropropane
cis - L, 3 -Dichloropropene
t rans - L, 3 -Di chloropropene
Ethylbenzene
2-Hexanone
Methylene chlorLde
4 -l*lethy} - 2 -pentanone
Styrene
1, 1, L,2 -Tetraehloroettmne
1, 1 ,2 ,2-Tet,rachloroethane
TetrachloroeLhene
Toluene
L, z ,4-rrichloro-
benzene
1, 1, 1- -Trichloroethane
1, 1, z-Triehloroethane
Trichloroethene
Tri ch1 orof 1 uorome thane
L ,2, 3 -Trlchloropropane
vinyl chlorlde
Xylenes (tota1)
n-Butylbenzene
Eee-Butylbenzene
Isopropylbenzene
RESIIL,T
REPORTING
LTMIT T'NTTS
ITD
ND
luD
ND
o .T-l ir
5-3
IID
IID
}TD
ND
IUD
TID
IUD
IID
ND
}UD
t[D
IID
ND
IUD
ND
ND
ND
ND
ND
ITD
luD
IID
ND
IUD
IUD
ND
tlD
t[D
ND
ND
ND
IUD
IID
IID
![D
5-O
1-0
1.O
2.O
1-O
2-o
1,O
1.0
1,0
1.0
1.0
2.O
],.o
1-0
1.0
1.O
1.0
1-.0
1.0
1-0
1,0
1.O
5.O
1-0
5-0
1.O
1.O
l-.0
1-0
1-.0
1,0
1.O
1-0
1.0
2.O
1.O
1.0
2.4
1.0
1,0
1.0
on next page)
ug/t'
rtg /r,
ug/t
ug/t
ug,lt
u,g,ll'
ug /t'
ug lt
ug /T'
ug/r,
ug/t'
ug/t'
ug/r,
ug /T'
ug /r'
rtg /r'
ug/r,
:ug/T'
ta.g /T,
vg/r'
t;..g /T'
vg /r'
rug/t'
ug/L,
ug lr'
ug/r,
:ug/t'
ug/r'
ug/r,
rtg /T'
vg /T'
uglt'
ug/t,
ug /r'
vg/r'
ug/L
ug/T,
ug/t'
ug/r'
ug/1,
ug/L
STL Denver
(eontinued
2A
Iots-sary)Ie #.
PARAMETER
URA Corporation
Clieut, saqfie ID: SIIB-9-O9O1O5
gf.fiqg VolatiJ.es
3 D5f O2O23O-003 Hork Order *- - -: HII\/Q51AE ttlatri-r- r - ? r . . . . r GW
RESUITT
REPORTTNG
IJIMIT I'NTTS
L ,2 | 4-rrimethylbenzene
t, 3 , s-TrLmethylbenzene
n-Propylbenzene
tert -Butylbenzene
2-Chlorotoluene
4 -Chlorotoluene
L,z-Dibromo-3 -
chloropropane (DBCP)
1 , 3 -nichloroproparre
2 ,Z-Dichloropropane
1 , 1-Dlchloropropene
Hexachlorobutadlene
4 - Isopropyltoluene
Methyl tert-butyl ether
L ,2, 3 -Trlchlorobenzene
Brornobenzene
Brornochloromethane
Naphthalene
STIRROGATE
ND
}TD
ND
r[D
I{D
l[D
IVD
DID
ND
ND
ND
IVD
llD
ND
ND
ND
ND
PERCEI{IT
RECOT[,ERY
L. o ug/T,
1. o ug/t'
f- . o ug/T,
1. o :ug/t
1.0 vg/L,
1 . o ug/f,
2 . O ug/t'
1.0
5.0
L.0
1.0
L.0
5,0
1.0
1.0
1.0
1,O
RECO\IERY
I,IMITS
ug/t
us/t
:ug/L
ug/r,
ug/r,
ug/t,
]ug/L
ug/L
lug/1.
:ug/r,
DLbromof luoromethane
L, Z-Di chloroethane - d4
4 -B romo f luoroben,z ene
Toluene-dB
rwrB(B):
102
LzL
LA2
23*
(tt r"1"8 )
$z L28 )(78 118)
(tz 117 )
i Surro3ulo ruooycry Ia outside starcd @ntrol ltmlts.
J Estlmatod rcallt. Rosrh ts less than RL.
STL Denver 2L
Iot-8aryt1e *: D5IO2 O23O-OO3
IIRSI Corporatton
silB-9-090105
ccnls vol.atLleo
ISork Order *: IIJ\IQSIAE
rfiSS SPECTROI,'ETER/DATA SYSTE}.T (MSDS) TENTATIVEIJY IDENTIFIED
PAXAIIETER eAs #
EgTTMATED
RESULT
I{atri:x: GW
COMPOUNDS
RETEMTION
TIME I]NIT8
0.0 Ir[ 8.98 ug/t'
4.9 ,f M 9.9594 ug/L
5.3 *T M 10.073 ug/f'
Clrclotetraalloxane, octamethyl
Unknown
Unknown
I EE(8) =
s55 -67 -2
M: Rcsutt ryts mcosured egaimt m:f,rcst internal standerd assuming 0 raponso factor of L
STL Denver
IIRS CorporatLon
Cl.lent Saryfle E): SHB-10-O9O1O5
Ge/us vo]-atsl-Ies
PARJAIT{ETER
Acetonit,rile
Acrolein
AcrylonLtrlIe
AIIyI chloride
Carbon disul-fide
1-Chlorohexarre
2 -Chloroethyl vlnyl ettrer
Cyclohexane
D 1 chloro f luoromethane
trane -L,4 -Dl-chloro-
2-buEene
L ,4-Dloxane
Ettranol
Ethy1 methacrylate
Iodometlrane
Isobutyl alcohol
MethacrTlonitrile
Methyl methacrlrlate
Proplonitrlle
Tetrahydrofuran
Vinyl aeetate
n-Butanol
Lert-Buty1 alcohol
Chf.or tlane
Cyclohexanone
Ethyl acetate
Ethyl ether
Hexane
rsopropyl ether
2 -Nitropropane
Tri chl oroLr L f I uoroe thane
2 -Pentanone
cis -7- ,4 -Dlchloro- 2 -buLene
Acet,one
Benzene
Brmdlchlormethane
Brmfonn
Bromomethane
I.ot-Saryll"e #, - -:
Datg 8arylled.---r
Prgp Datg- - - - - - I
Prep Bat& #-, - 3
Dl-Iution Factor:
D5r02 0230 - 004
09/at/as 12:Lo
ae/L2/os
s2s6224
1-
flork Order *- - -:
Date Receirred- - 3
Analyele llate-. 3
Anaayels time - .3
I{gt}od,--- --- ---3
RESUITT
ND
ND
ND
ND
![D
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
IUD
ND
ND
ND
![D
IUD
0-65 .f
ND
ND
ND
ND
ND
ND
ND
IUD
ND
}UD
}ID
0.62 J
1.6
I{D
(Continued on
HLTVQ9].AB
oe/oz/as
oe/L2/os
1,0 : 13
9w845 82608
REPORTTNG
TIMIT UNITS
rratrl-x,-, -, - - - -, r GIiI
20 vg /I'
20 ttg / T,
2a us/L
2.a :ug/L
1 . o ug/l'
1- 0 ug/T'
2.O ug/t,
2.O uglt,
2 . o ug/l'
1.0 :ug/L
200
200
1.0
L.o
50
10
1.0
2A
5.0
2,A
s0
50
1-O
20
5.0
2 -O
1.O
10
2,O
1,0
2.4
1-0
10
1.0
1-o
1.0
2.0
next page)
:ug/t
ug/r,
ug/t
ug/r,
.ug/r'
:u.g/L
ug/t
LLg / r'
ug/r'
ug/r,
ug/t'
:ug/r'
u.gll'
vs/L
,ng / T,
ug /T'
uglr,
ug/t'
rtg /r.'
ug/L
ug/t'
ug/r,
ug/t'
uslL
ug/L
vglr'
ug/t
O
STL Denver
ND
ND
ND
ND
O -23 .f
luD
IUD
l[D
IID
TID
ND
IID
ND
IUD
IID
ND
IrRg Corgnration
el-ient Saqll.e
Gclll.s
srrB-10-09010s
Iot-Saq)Ie
PARA}IETER
2 -Butanone (I,IEK)
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chf.orofom
Chloromethane
Dibromomettrane
L, 2-Dibromoettrane (EDB)
L ,2 -Diehlorobenzene
1, 3 -Dichlorobenzene
L , 4-Dichlorobenzene
Di chl orod I f luorome t hane
1, l-Dichloroethane
L ,2-Dichloroethane
1, l-Dichloroethene
L ,2-Diehloroethene
(toua].)
cte - L, 2 -Dl-chloroethene
trans - 1., 2 -Dichloroethene
t ,Z-Dtchloroproparre
cis -L ,3 -Dlchloropropene
trarrs- 1, 3 -Dl-chloropropene
Ethylbenzene
2-Hexanone
Methylene chlorlde
4 - !,Iethyl - 2 -pentanone
Styrene
L, L, L,2 -Tetrachforoethane
1, 1 ,2 ,2 -Tetrachloroethane
Tet,ractrloroethene
Toluene
L,2 ,4-Trichloro-
benzene
1, 1, 1--Trl-chloroethane
1, 1, 2 -Ttichloroethane
Trichloroethene
Tr L chlorof luoromethane
L, 2, 3 -frichloropropane
Vinyl chloride
l{ylenos [total)
n-Butylbenzene
sec-Butylbenzene
fsopropylbenzene
Volatl"les
DSIO2O23O-OO4 lSork Orden *---: II.r\/Q91AE llatrix- ..-: GIII
RESUIJT
REPORTINCI
I,TMIT UNTTS
ND
ND
ND
ND
ND
ND
IID
I{D
ND
ND
l[D
IID
lsD
ND
ND
5,O
1-0
1.0
2 -O
1--O
2.O
1,0
1.0
l-.0
1.0
1.O
2.4
1.O
1.0
1-0
1.O
1.O
L.0
f_.0
L.0
1.0
1.O
5.0
1.0
5-0
1,O
1.0
1.0
l-,0
1,0
l,.o
1,0
1.0
J-.0
2.0
1.0
1.O
2.0
L.o
l_-0
1.0
next page)
ug/r-,
ug/t'
ug /r'
ug/r,
ruglT'
uglT'
:ug/t'
:ug/L
:ug/r'
ug/L
ug/r.
ug/t
:ug/t,
vg /T"
ug/r,
ug/t-,
v-g/L
trg/L
ug/T'
:ug/T'
rug/t"
ug/T'
tu.g /I'
wg/L
:u.g/r'
ug/r,
ug/r,
ug/t'
:ug/r,
ug/T,
:ug/t'
u9/r,
ug/r,
:ug/l'
ug /r'
ug/t,
ug/t'
vslL
ug/L
ug /t,
ug/t,
IID
ND
lUD
ND
ND
ND
I{D
IID
IID
IID
(Continued on
STL Denver 24
C1lent gaq)I-e
IIRA Corlrcration
ec/us
ID: gIrB-1o-O9O1O5
Vol.atLIes
I.ot-garyr1e *- - -:
PARAMETER
Dsf AZA230-004 llork Order S- - , : HJITQgXAE lltriiltrl-x- ---3 GliI
REgt IJT
REPORTING
LTMIT t'NITg
L, 2, 4 -Trimethylb€rrzene
1 , 3 , 5 -Trimethylbenzene
n-Propylbenzene
tert -Butylbenzene
2 -Chlorotoluene
4-Chlorotoluene
L ,2-DLbromo-3 -
chloropropane (DBCP)
1, 3 -Dichloropropane
2 ,Z-Dichloropropane
L , L-Dichloropropene
Hexachlorobutadiene
4 -Ieopropyltoluene
Methy1 tert-buty} ether
L ,2, 3 -Trichlorobenzene
Bromobenzene
Bromochloromethane
Naphthalene
SURROGATE
I(D
ND
ND
ND
ND
ND
IUD
}TD
IUD
ND
ND
ITD
ND
ND
luD
ND
luD
PERCEDIT
RECOVERY
1. O vg/L
l-.0 ug/L
1, O ug/l'
1-,0 ug/l'
l- , 0 ug/r,
1 .0 ug/n
2. O :ug/Y'
L-0
5.0
1.0
1.0
1.0
5.O
1-O
1-O
1.0
1,0
RECO\IERY
LrMrrs
ug /t'
ug/r,
ug /t'
ug/t'
Lrg/r.
ug/r,
LLg /L
ug/L
ug /t'
,ng /r.
Dibromof].uoromethane
L, Z-Diehloroet trane - d4
4 -Bromofluorobenzene
Toluene-d8
L02
1 l-o
104
9s
(tt 118 )(52 128 )
( ze 118 )(tt 117 )
nCIrE(8):
J Estimrtod renrlt- Remlt ls Ims &an RL.
STL Denver 25
Iot-saryfle *: D5f020230-004
!,IA.9S SPECTROMETER/pATA SYSTEM
PARAITIETER
UnA &rgnration
8t|B-10-090105
cr'ft{g Volatil.ee
work order *: HJ1/Q91AE
(MSDS)
Uatrl:r: GVI
EOMPOUDUDS
RETEtrITION
TIME TINITS
1. 5286 ug/t'
8 . 9803 ug/t'
11, OL7 :ug/t'
DLmethyl sulfide
qfclotetrasiloxane, octamethyl
AceLic acid, z-ethylhexyl este
twrB (s) :
TEMTATIIIEIrY IDENTf FIm
ESTIMATED
CAS #-. RBSUI,T. ,-
75-18-3 0,0 M
556-67-2 0-0 M
L03-09-3 3-5 J M
M: Resrh was mcsgurcd agalnst noorost intcrnat gtsrdard assumlng a rosponso froor of 1.
STL Denver 26
UR-s brfioration
Cl-Leut Aaqll.e ID: 8HB-3-O9O1O5
ec,lug vo]-atiles
o
PARAMETER
Acetonl-t.ri1e
Acrolel-n
acrylonitrlle
Allyl ehloride
Carbon disulflde
I -Chlorohexane
2-Chloroethyl vinyl etsher
C\rclohexane
D L chl oro f luoromethane
trans -L ,4 -Dichloro-
2 -butrene
L r il-Dioxane
Ethano]-
Ethyl rnethacrylate
Iodomethane
fsobutyl alcohol
Methacrylonit,rile
Methy} methacrylat,e
Propionltrile
Tetrahydrofuran
Vinyl acetatre
n-Butano1
t.ert*Butyl alcohol
Ch]-or e
Cyclohexanone
Ethyl acetaLe
Ethy} ether
Hexane
fsopropyl ether
2 -Nitropropane
rr I chl oro t, ri f luoroethane
2 -Pent anone
cie - 1, 4 -Dl-chloro- 2 -butene
Acetone
Benzene
Bronodichlorsrcthane
Brmofonr
Bromomethane
Iot-sarqrl.e *- - -:
Date Sarylled- --Z
Prg1) Date-?o-.-3
IteB Batdr #-. - !
DL].ution Factor:
DsrA2A230-005
ae / oL/ os L3 ;37
oe/Lz/as
52s6224
L
Ilork Order #- -. :
Ilate neceived- - !
Ana-Iysis Date- - i
nna-Iysie Tlme. . l
.}lgthod-!..o...-3
RESTILT
ND
ND
ND
ND
NI)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
lTD
ND
ND
ND
ND
O.TL J
![D
ND
ND
ND
IUD
ND
ND
l{D
ND
g-7 ir
}ID
O-48 .f
2-7
![D
(Continued on
H{NMIUIAE
ae / o2/ os
oe /Lz/ os
L1 : l-0
sw845 82508
REPORTING
TIMIT UNITS
UatrirE-----.---3 GW
2A ug/t'
zo ug/r,
2A ug/l'
2-o ug/L
L.0 ug/T'
1. O :ug/I'
2.o ug/t
2. o :ug/r,
2 -o :ug/I-,
1,. O ug/L
200
2AO
1.0
1.0
50
10
1.0
20
5.0
2.O
s0
50
1.O
2A
s-0
2.0
1.0
10
2.4
1_0
2.4
1,0
10
1,0
1.O
1.0
2.0
next page)
ug/r,
trg/I'
LLg /T'
ug/t'
ug/r,
ug/t-,
ug/t
ug/L
:ug/t'
ug/r,
ug /t'
ug /r'
urglr'
ug/L
]ug/t
]ug/L
ug/r,
lug/L
ug/t'
ug/l'
:ug/r"
ug/L
u,gln
uslL
rugln
ug/n
ug/t
STL Denver
IIRA @rporatlon
ClLeut Sa4ile ltD: 8f,B-3-O9O1-Os
oelH8 volat,.leo
Iot-Saryrle *- - -: D5I020230-005 Iork order X- - -: ILTVRMLAE
REgUL,T
REPORTINC
LNIIT UNTTSPARAIyIETER
Z-Butanone (lGK)
Carbon totrachloride
Chlorobenzene
ChloroeEhane
Chloroform
Chloromethane
Dibromomethane
L, z-Dibromoettrane (EDB )
L ,2-Diehlorobenzene
1, 3 -Dichlorobenzene
L , L-Dl-chlorobenzene
D i chlorodi f luorornethane
1, I-Dichloroethane
L , z-Dichloroethane
L, L-Dichloroethene
L,2-Dichloroethene
(total )
ci s - L, 2 -Dl-chJ-oroethene
trans - 1, 2 -DLclrloroethene
L ,Z-Dichloropropane
cis- 1, 3 -Dlchloropropene
Lrane - L, 3 -Dichloropropene
Ethylbenzene
2-Hexanone
Methylene chloride
4 -Methyl -2 -pentanone
Styre,ne
1, 1 ,l ,2-Tetrachloroethane
1, 1 ,2 ,2 -TeE,ractrloroethane
Tetrachloroethene
Toluene,
L ,2 , 4-Trichloro-
benzene
1 , 1, l-Trlctrloroethane
1, 1, z-Trlchloroethane
rrlchloroethene
Tr i ch1 oro f luoromet hane
L ,2, 3 -Trichloropropane
vlnyl chloride
Xylenes (total)
n-Butylbenzene
sec-Butylbenzene
Isopropylbenzene
luD
TID
IID
ND
11
![D
ND
ND
ND
ND
ND
I{D
ND
ND
ND
ND
ND
ND
r{D
}UD
IqD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
IUD
}UD
I'ID
IUD
r{D
}ID
5. o :uig/r,
1. O :ug/t
1-O ug/t'
2 - A :ug/I'
f-- O urglr,
2.a ug/t
1.0 :ug/I"
1. 0 lug/L
1- 0 ug/r"
1 . 0 :ug/I'
1. O luglT'
2.a :ug/L
1.0 tug/I'
1.0 lug/L
J, , 0 :ug/T'
1- - 0 ug/r,
l_ - o lJg/T,
1 . 0 rJg/r,
l- , 0 trg/T,
1. O ug/T,
1,0 ,rg/L
1- 0 ugll'
5 - O :ug/l'
1 .0 ug/t'
5.0 ug/T'
l-. O vg/I,
1. O :ug/T,
1, O vg/T,
1.0 :ug/I'
f- . O ug/I'
1.O ug/t
l- . O :ug/T'
1 . o ag/I'
f-. O ug/T'
2 . A ug/Tt
r . o ug/t
l-, O ug/L
2.0 uqll
1.0 ug/L
f. .0 ug/r,
L .0 ug/L
STL Denver
(Continued on nexL page)
URS Corporatim.
C3.ir=nt, Saqlle ID: AIIB-3-O9O1O5
gcltqs vol-atI.leo
D5I02O23O-OO5 l{ork Order *- -. 3 H.I\IRMIAE
REST}LT
REPORTTNG
IJTMIT
r+aLrix----,----3 Gw
t NrTs , .,,_
ug/r-'
vg/r'
rug/r.
rrg/L
ug /T,
ug/r,
ug/t,
us/L
ug lr'
ug/L
ug/u
ug/r'
ug/T,
vg/r,
ug /r'
lug/t
ug/r,
O
I"ot-8a1ry[e ft- - -:
PARAMETER
L ,2 , 4-Trimethylbenzene
1 , 3 , 5 -Trimethylbenzene
n-Propylbenzene
tert -Butylbenzene
2 -Chlorotoluene
4 -Chlorotoluene
L,Z-Dibromo-3 -
chloropropane (DBCP)
1 , 3 -Dichloropropane
2 ,2 -Dichloropropeure
1, l-Dtchloropropene
Hexaehlorobutadlene
4 -Isopropyltoluene
MeEhyI tert-buEy1 ether
L ,2, 3 -frichlorobenzene
Bromobenzene
BromochloromettrEure
Naphthalene
SURROGATE
ND
IID
IUD
ND
TID
ND
ND
ND
ND
ND
ND
ND
TID
ND
ND
ND
ND
PERCET(f
RECOVERY
1.0
1.0
1,0
1.0
1-0
1.0
2-0
1.0
5,0
1,0
f--0
1.0
5.0
1.O
1.0
1.O
1.O
RECO\'IERY
ITfMITS
(tt 118)
(62 L28)(zs 118 )
0t LLTI
Dibromof luoromethane
L, Z-Dlchloroethane - d4
4 -Bromofluorobenzene
Toluene-dB
ilOrts (8) :
9B
94
98
100
I Esdmatotl rcsrlt. Rmult ls Ioss than RL.
STL Denver
Iot-Sary>I-e * : D5I02O23 O- O05
IIRIT Cor;nratlon
SIIB-3-090105
fffiilB vo1attlee
fork Omdtrr *: HifVnM].AE
MASS sPEcTnoaeTEn/DATA SYSTEM (!'sDs) TENTATwEI,Y IDEIITIFIBD
PARAMETER CAS #
ESTIIVIATED
RESULT
None
I{atrl:r: GW
COMPOTINDS
RETEIiITION
TIME IINITS
:os/T,
STL Denver 30
Iot-gaq,I.e *---:
Date 8aryrl.ed.---3
Prqp Datter-----!
Prep Batch fi- -,:
DI.f.utiou. Factor:
IIRS Corpor:atlon
Cl-ient' 8a4l1e ID: SflB-7-O9O1O5
ce^ig vo1atl-I.eo
I5ork Order #-,-3 H.rVRV1AQ
Datre Recelwed- - 3 oY / a2/ os
Analyals Date- - 3 a9 / L2/ a5
Aualysis Tfure.-i I.L:30
fiatrix---,--.--r GWDsra20230-006
09/at/os 14:2o
oe/tz/os
525 6224
I.
Hetftod- - - o - - - - . : SW846 82508
RESULT
REPORTTNG
LIMTT ITNTTSPAR.AMETER
AcetonLtrile
acrolein
acrylontt,rile
Ally1 chloride
@rbon di-su1fide
L -Chlorohexalle
z-Chloroethy1 vLnyl ether
Cfrelotrexane
oi chl oro f luoromethane
trane-1 , 4 -Dlchloro-
2-buEene
L,4-Dioxane
Ethano].
Ethyl methacrylaEe
Iodomethane
Ieobutyl alcohol
MethacrlrlonLtrile
Methyl methaerylate
Propionitrlle
Tetratrydrofurarr
Vinyl acetate
n-Butano1
tert-Butyl alcohol
Chf. orodibrupmr=ttrane
Cfrelohexanone
Ethyl aceLate
Ethyl eLher
Hexane
fsopropyl ether
2 -Nttropropane
Tr1 chl orot ri f luoroet hane
2 -Pentanone
cls - 1, 4 -Diehloro- 2 -butene
Acetone
Benzene
Bromodl- ctr-I oromethane
Brmform
Bromomethane
ND
}TD
ND
IID
o-99
ND
IUD
ND
ND
ND
ND
ND
ND
tuD
ND
ND
IID
ND
ND
ND
ND
IID
a -29
tlD
TID
ND
ND
IUD
ND
ND
}UD
IID
IUD
I'lD
a -25
o-96
ND
200
200
f_.0
1.0
50
10
1.0
20
5.0
2.O
50
50
1.O
2A
5.0
2.0
1.0
10
2.0
1.0
2.0
l_,0
10
1.0
LO
1-O
2.0
ug/t'
ug/r,
lug/r'
ug/r,
ug /T'
ug/T'
ug/t'
ug/L'
ug/t
ug /r'
ug /T'
Lrg /T'
u.glr'
ug lt
ug /t'
:ug/r'
ug/r,
ug/t"
:ug/r,
rrg /T,
ug/r,
ug/r,
trg /T'
uslt
uglt'
uglr,
ugll,
2A ug/t"
2a wg/t'
2a :ug/L
2 . O ug/f'
1- o ug/f
1.o :ug/t
2.0 ttg/I'
2 . A ug/I,
2 . O rtg/I'
1. o ug/T,
ir
J
ir
STL Denver
(ConElnued on next page)
Lot-Saryl1e
PARAMETER
IIRS Corporatslou
Cl-lent Slaryfie ID: grB-7-O9O1O5
cc,lttg vol.atil.es
D5f02A210-006 Work Order *- - -: HJ\IRVIAQ
RESIILT
REPORTTNG
IJIMIT
Uatri-x-O--.)---3 GTI
ITUITS
rug/L
lug/L
lug/t,
ug/r'
rnglr,
lurg/L
ug/L
:ug/L
lu.g/u
ug /T'
vg /r,
ug/t'
ug /t'
lug/L
ug/t
ug/L
:.g/T'
ug /r'
ug/r,
ug/t'
ug/t"
tg /T,
u.g/n
:uglr'
ug/T,
:ug/t"
ug/t'
ug /r,
ug/T'
]urg/t
:ug/t'
ug/r'
ug/t"
:ug/T'
ug /t'
ug/r,
LLg /r,
uslL
ug/L
:ug/r'
trg / r'
2-Butanone (MEK)
Carbon tetraehloride
Chlorobenzene
Chloroethane
Chloroform
Chlorornethane
Dibromomethane
L, Z-Dibrornoethane ( EDB)
L ,Z-Dichlorobenzene
L ,3-Dichlorobenzene
L ,4-Dichlorobenzene
D i chl orodi f luoromethane
1, l-Dichloroethane
L ,Z-Dichloroethane
1, l-Dichloroethene
L ,Z-Dtchloroethene
( total )
cLs - 1, 2 -Diehloroethene
trans- L, 2 -DLchloroethene
L ,Z-Dichloropropane
cis - 1, 3 -Diehloropropene
trans- 1, 3 -Dlchloropropene
Etrhylbenzene
2 -Hexanone
Methylene chloride
{-Methyl-2-pentanone
Styrene
1, 1, L, 2 -Tetrachloroethane
1 , 1 ,2 ,2 -Tetrachloroethane
Tetrachloroethene
Toluene
I ,2 , 4-Trichloro-
benzene
1, 1, 1 -Trichloroethane
1, 1, z-Trichloroethane
frichloroethene
Tr L chloro f luoromethane
L ,2 ,3 -trichloropropane
Vinyl chloride
rrylenes (total)
n-Butylbenzene
sec -BuLylbenzene
Ieopropylbenzene
TID
lilD
ND
}UD
o -32 ir
ND
IUD
ND
ND
ND
ND
}UD
ND
ND
l$D
t[D
5.O
1.0
1-0
2-0
1-O
2.4
1-0
l_.0
1-0
1.O
1.O
2.4
t.o
1.0
1.O
1.O
1-0
1.0
1.0
1.0
1.0
1. O
5,0
1.0
5.0
1.O
1.O
1.0
1.0
1.0
f_.o
1.0
1.0
1.0
2.O
1.0
1.0
2.4
1.0
1.0
1,0
next page)
IID
ND
ND
ND
IID
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
TSD
ND
ND
ND
ND
I{D
TID
ND
ND
STL Denver
(Continued on
32
Lot*Saryl1e *-
PARAMETER
IIRA Corgnration
Cl.ient Saryfie ID: SHB-7-O9O1O5
GC|US VolatI-Ies
: D5I02A230-006' Ilork Order *- - -: HTIIRVLAQ liiatsrix--------+: GW
RESUIJT
REPORTTNG
ITTMIT UNITS
L, 2, 4 -Trimethylbenzene
L ,3, 5 -Trimethylbenzene
n-Propylbenzene
tert-Butylbenzene
2 -ehlorotoluene
4 -Chlorotoluene
L ,2-Dibromo-3 -
chloropropane (DBCP)
L ,3 -Dichloropropane
2 ,Z-Dlchloroproparle
1, l-Dichloropropene
HexactrlorobutadLene
4 -f eopropylt,oluene
Ivrethyl tert -butyl eEher
L ,2 ,3 -Trj"chlorobenzene
Brornobenzene
Bromochloromethane
Naphthalene
STTRROGATE
ND
ND
ND
ND
}UD
ITD
ND
ND
ND
ND
ND
ND
tlD
}UD
ND
IID
ND
PERCMIT
RECO\TERY
1- - O :ug/L
1. o lug/\'
1.0 ug/l'
1- o ug/t'
1- 0 ug/l'
1- 0 ug/t'
z -a wg/T'
1. O ug/l'
5. O ug/T'
1. o ug/L
1 . O LL9/T'
1. o ug/L
5.0 ug/t'
1 - 0 ug/t'
1. o ug/t
1- 0 ug/T'
l- . o ug/L
RECOVERY
L'fMITg
(zs 1L8)
(62 A2g')
(zs 118)
(72 117 )
Dibromofluoromethane
t, 2-Dtchloroethane - d4
4 -Bromofluorobenzene
Toluene-d8
NCIrB (8) :
93
85
9s
10s
J Esdrnated remrll Resutt Ie less Oran RL.
STL Denver 33
Iot-saq>Ie *: D5I020230-006
IVIASS SPECTROMETER/DATA SYSTE}I
PARA}IETER
Cyclotetraslloxane, octameEhyl
Acetic acid, Z-ethy1herryl este
Unknown
Dro['B (s] :
IIR.S Corpor:atlon
srB-7-09010s
Gtr,lw voIats1Ieg
rcrk Order *: HiIVRV1AQ Uatri-x: GW
(MSDS) rnNrerrvELy rDErflrrFrED eoMPouI[DS
CAS #
EgTIIYIATED
RESUITT
RETENTION
TIME t]NITS
8.9796 ug/L
11.015 ug/L
11 . 697 ug/It
556 -67 -2
103 - 09 -3
o,0
7.2 'J4.A ,J
M
M
M
M: Rsult was memured against rtoart:* intcrnal stsndard assuming s req)ooso fauor of l.
STL Denver
URS Corgnration
C1ieut Saqrle ID= EB-091OO5
GcA{s vol-atiles
PARATI{ETER
AcetonitrLle
Acrolein
Acrylonitrl-1e
AIly} chloride
Carbon disulfide
1-Chlorotrexane
2 -Chloroethyf vinyl ether
Clrclohexane
Di ehloro f luorornet hane
trans -L,4 -Dichloro-
2 -butene
L r 4-Diox€rne
Ethanol
Ethyl methacrylate
Iodomethane
Isobutyl alcohol
MethaerlrlonLtrile
Iurethyl mettracr^}rlat e
Propionit,rile
Tetratrydrof uran
Vinyl acetate
n-Butrano1
tert-Buty1 aleohol
ChIorodlbromomethane
Cfrclohexanone
Ethyl acetate
Ethy1 ether
Hexane
Isopropyl ether
2-Nitropropane
?ri ch1 orot ri f luoroethane
2 -Pentanone
cis - L, 4 -Dlchloro- 2 -butene
Acetone
Benu ene
Bromodichloromethane
Bromoform
Bromomethane
fot-Saqll-e #---:
Date Sarylled-. - i
Prep Datg------:
Prep Batdr S. - . :
Dil.ution Factor:
Dsr020230-007
oe / orlos 14 :30
ae /L2 / os
52s 6224
1
I[ork Order fr- - - 3
Date Recelved. .3
AnatysLs llate- - 3
Ana-lyeis Time. - 3
Hgthod,---------3
RESUITT .-_
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
IID
ND
ND
ND
ND
ND
t{D
ND
ND
IgD
IUD
ND
IID
ND
TID
2.L J
ND
IID
luD
ND
(Contlnued on next
Htmru(1AA
oe/az/as
oe/L2/os
1L:49
sw84 6 82608
REPORTING
TIMIT UNTTS
l[atri-x. , ! o , - - - ,: .E['[
20 ug/r,
2a Dg/I'
20 ug/I'
2 . a ug/T,
l-.0 ug/L
f- . 0 vg/r,
2 . A ug/I'
2 . O lug/f'
2 . A vg/T'
l-.0 ug/L
200
200
1.0
1.0
50
10
1,0
2A
5.0
2.o
50
50
1.0
20
5.0
2 -O
1.0
10
2.0
L.0
2.0
1,0
10
1,0
l_.0
L,0
2.0
page)
ug /r,
vg /I'
ug/n
ug/r,
vg [I'
ug/t-,
ug/r.
ug/t'
wg /r'
ug/t'
ug/r,
ug/r,
:ug/t'
ug/t'
luglL
rtg / I'
lg /T'
ug/t
ug/t
lrg /r,
trg /T'
\glL
Iutgll,l
us/L
ug/I'
Lrg / r,
ug /T'
STL Denver
IIRS Corporation
Cl.ient Ilarylle ID: EB-O91OO5
Gf,firB volatiles
D5I020230-007 Work Order f;- - - ! HinIru(LAAIot-Saryrl-e
PARAII{ETER
REPORTING
IJIMIT UNIT9RESUIJT
ND
}UD
r[D
ND
o.L7 ir
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ITD
ND
ND
ND
ND
IID
IUD
ND
}TD
ND
ND
t[D
IID
ND
ND
ND
IUD
ND
IID
I$D
ITD
ND
ND
TID
ND
ND
(Continued on
2-But,anone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroettrane
Chl-orofom
Chloromethane
Dlbromomethane
L, Z-Dibromoethane ( mB)
L ,Z-Dich]-orobenzene
L,3 -Dlclrlorobenzene
L , 4-Dichlorobenzene
DL chL o rodl, f luoromettrane
L , L-Dlchloroethane
L , Z-Dichloroethane
1, l-Dich1oroethene
L ,2-Dichloroethene(roral)
cJ.s- 1 , 2-Diehloroethene
trans - L, 2 -Dichloroethene
L ,Z-Dichloropropane
cis - 1, 3 -Dichloropropene
trarrs -L ,3 -DLehloropropene
Ethylbenzene
2 -Hexa-rrone
Methylene chloride
4 -Methyl-2-pentanone
Styrene
1, 1, a, 2 -TetrachloroeLhane
1, 1 ,2 ,2 -TetsractrloroeEhane
Tet,rachloroetrhene
Toluene
L ,2 , [-Trichloro-
benzene
1, 1, 1 -Trichloroethane
L, L, 2 -Trl-chloroethane
Trlchloroethene
Trl" chlorof luoromethane
L ,2, 3 -TrLchloropropane
Vinyl chloride
Iylenee {total}
n-Butylbenzene
sec*Butylbenzene
Isopropylbenzene
l,.o
1.0
1.0
1,0
l-.0
1.O
5.0
1-0
5.0
1--0
1.0
1.O
1.0
1.0
1.0
1"-0
L.0
1.0
2.4
L.0
1.0
2.4
L.0
1.0
1.0
next page)
5 . 0 uglt"
1- 0 ug/t
1- o ug/t'
2.0 Lrg/L
1- O ug/L
2 . A ug/I'
1. O ug/t'
f,. o tJg/T,
1, O ug/L
1. o ug/T,
J-. 0 vg/l'
2 . a ug/r,
L.0 ug/t
1 . o uglr,
1. 0 ug/T'
1. o ug/L
ug/r,
ug/t'
ug/t,
ug/r,
ug/L
rtg /r'
lug/r.
ug /T,
ug/T,
us/r,
:ug/T'
ug /r'
ug/r,
ug/t
us/L
ug /t,
ug /T'
ag/T,
ug/t'
:ug/t'
:ug/r'
wh,
ug/r,
u9/t
ug/T'
STL Denver 36
IIRA CorSrcratlon
Cl.ient' Saryr1e ID: EB-O9LOOS
GenrB vol-ati].es
I,ot-Saryrl.e * - - . 3 D5I02023 0- 007
PARAII{ETER
L ,2 , 4-Trimethylbenzene
1 , 3 , 5 -Trlmethylbenzene
n- Propylbenzerae
tert -BuLylbenzene
2 -Chlorotoluene
4 -Chlorotoluene
L ,Z-Dl-bromo- 3 -
chloropropane (oncp)
L ,3 -Dtctrloropropane
2 ,Z-Dtctrloropropane
1, I-Diehloropropene
Hexachlorobutadiene
4 - Isopropyltoluene
Methy1 tert-butyl ether
L ,2, 3 -Trl,chlorobenzene
Bromobenzene
Bromochlorometharle
Naphthalene
SURROGATE
Dlbromofluoromethane
L, 2- Dichloroethane -d{
4 -Bromofluorobenzene
Toluene-dB
nC)|fB (8) :
IIork Order *-
REgULT
ND
ND
IID
ND
}UD
ND
DID
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
PERCF;TUT
RECO\TERY
91
84
9'l
107
Hatrfur.-------.3 EW
UNITS
vg /T)
tug /r"
ug /t,
ug/r,
ug/L
ug/t'
ug/t
ru.g/t
ug/r,
ug/1,
ug /T'
lu.g/L
ug ll'
:ug/T'
lug/t
lug/r''
ug/r,
HiI\Iru(1AA
REPORTING
I,IMTT
l-.0
1.0
1,0
1.0
1-O
l-. 0
2.O
J-.0
5.0
L.0
l_.0
1-O
5.0
1.O
1.0
1,0
1.0
RECO\IERY
IJIMITS
(7t 11I )(ez 128)
( zs l-r.s )
(77 117)
O
I Fstimated rcsult. Rogult is less than RL.
STL Denver
I,ot-Sary>I-e * : D5rO2 0230 - 007
},IASS SPECTROIIETEN/OATE SYSTET{
PARAITIETER
IIRA Corporatl-on
EB-O91005
Gf,.ltr6 vo1atLl-ea
I$ork Omder *: H;nIru(1AA
(MsDs)
ilatrlx: EW
COMPOT]NDS
RETENTTON
TTME T'NITS
11 .015 ug/L
TENTATWELY IDEIITIFIED
ESTTIVIATEDc+-q-$_ REsuLr
103-09-3 7.6 'J Ivlecetic acLd, ?-ethylhoryl eete
rwfB(8):
M: Rc.sttlt wag nreasurod againgt naarst internal standand asnrming a respoue factor of l.
STL Denver 38
URg Corlrcration
Cl.ieut Saqrle il): SIIB-gI.o-OgO1os
Gf,.lr+tc SemLrrol.atil.ee
o
Iot-Sary)Ie *- . - l
Date Saryr1ed---l
Prep Datg------I
Prep Batch #- - -:
Dl.lution Factor:
Dsr020230-002
09 / oL/ os o7: oo
ae/05/os
5249103
1
Ilork Order S-. -:
Date ReceLrred- - 3
Anal.ysis Date- - 3
^trnal.ygis Tl-re. - 3
Dlgthl)d.-lr-----!
RESUITt
HJTTQALAS
ae/02/os
aeh o/os
O0 :44
sw846 8270C
REPORTINGI
I,TMTIr UNITS
lfatrl-x -= CIW
PARAMETER
Acenaphthene
Acenaphthylene
.B.cet,ophenone
2 - Acetyl amino f lrrorene
4 -AminobLphenyl
Aniline
Anthracene
eramite
Benzidlne
Benzo (a) anthracene
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzoic acid
Benzo (ghi) perylene
Benzo (a) pyrene
Benzyl alcohol
bl- e (Z -Chloroetho>ry )
met,hane
bis (Z- Chloroethyl ) -
eLher
bis Q -chloroisopropyl )
ether
bis (2-Ethylhercyl )
phtha"Iate
4 -Brornoptrenyl phenyl
ether
Butyl benzyl phthalate
Carbazole
4-ehloroanlline
Chlorobenzilate
4 -Chloro - 3 - methylphenol
2 - Chloronaphthalene
2 -Chlorophenol
4 -Chloroptrenyl phenyl
eIher
Chrysene
DlaIlate
Dl-benz (a, h) anthracene
ND
ND
ND
ND
ND
IID
ND
ND
ND
IUD
IID
ND
ND
luD
ND
ND
ND
DID
ND
TID
(Continued on
10
10
10
100
s0
10
10
20
100
10
10
1-0
50
10
10
L0
L0
10
1-0
L0
10
10
10
1_0
10
10
10
10
10
L0
20
10
next page)
ug /t'
rug/L
ug /r'
ug /t'
ug /T"
ug/r,
:us/L
ug /t
]uglL
ug /t'
ug /t'
ug /T'
:ug/T'
ug/t'
ug /t'
ug/r'
ug/r'
ug/r,
uglt'
ug/L
ug/r,
lug/L
ug/l'
ug/t
ug/t'
lug/L
ug/T'
ug/t'
ug/t
ug/L
ug/L
lulg/L
ND
ND
ND
IID
ND
ND
ITD
TUD
STL Denver
IIRS Oorgnratio
C1Lent saqrle ID: SB-91o-o9o1O5
e{/w Semftrol-atiJ-es
Iot-Saqr1e *. -.: D5I020230-002 IorIC order t- - -: II\T[/OA1A8
PARAMETER RESTII,T
REPORTTNG
LTMTT
Dibenzofuran
Di-n-buryl phthalate
3, 3' -Dlchlorob ertzidLne
2 , A-Dichlorophenol
2 ,6-Dichlorophenol
Dlethyl. phthalate
Dl-methoate
7 ,L?-Dimethylbenz (a) -
anttrracene
3, 3 I -Dimethylbenzidine
2 , 4-Dimethyl-phenol
Dimethyl phthalate
1, 3 -Dinitrobenzene
4 ,6*Dinitro-
2 -rnethylphenol
2 ,4-Dinit,rophenol
2 ,4-Dinitrotoluene
2 , 6-Dinitrotoluene
Di-n-octy1 phthalate
ol"phenylamine
1, Z-Diphenylhydraz ine
Disulfot on
Ethyl methanesulfonate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachl o rocyc I openta -
dlene
Hexachloroethane
Hexachloropropene
rndeno ( 1 ,2 ,3 -cd) pyrene
Ieod,rin
fsophorone
Isosafrole
Methapyrilene
3 - Me t, hyl chol ant hrene
Methyl rnethanesulfonate
2 -Methylnaphthalene
1, -Methylnaphthalene
MeLhyl parathion
2 -Ptethylphenol
3 -Methylphenol &
4-tlethylphenol
ND
ND
ND
IID
IID
ND
ND
ND
IID
}UD
ND
ND
ND
ND
ND
IUD
ND
ND
ND
ND
ND
ND
ND
IUD
ND
10
l_0
s0
L0
10
1o
20
20
20
1_O
10
10
50
50
1-0
10
10
10
1-0
50
10
10
10
10
50
10
L00
10
10
10
2A
50
20
l-0
10
10
s0
10
L0
on next page)
uatri-x-?--.----: GsI
TTNITS
vg /T'
:ug/t'
ug/t'
ug/t'
rrg/L
ug/L
:ug/r,
us/L
ug/t
Dg /r'
ug/r,
lug/t'
rJg/r,
:ug/T'
ug /r'
rulg/t
ug/t
ug/n
ug/r,
ug/r,
ug/L
ug/T'
us/r,
luglT,
uglT,
uslL
lug/L
lug/t'
vg /l'
vg/r'
:ug/t
:ug/T'
ug/t
ug/n
lug/r'
ug/t
uslL
ug/r,
ug/t
IUD
ND
}TD
ND
ND
ND
ND
IUD
}UD
ND
ND
IID
tlD
ND
(eontinued
STL Denver
Iot-Saqll-e fi---3
PARAMETER
L , 4-Naphthoquinone
1-Naphthylamine
2 -Naphthylamine
2 -Nitroaniline
3 -Nitroaniline
4-NitroanilLne
Nit.robenzene
2-Nitrophenol
4 -Nlt,rophenol
4 -Nitroquinoline-
L-oxide
N-Nl t,rosodL - n -buEylamine
N - Ni t, ro sodl ethyl aml-ne
N - Ni t roeodime thy 1 amine
N - Ni t ro s odipherry I amine
N- Ni trosodi - n - propyl -
amine
N -Nl t rosomethyl ethyl amine
N-Nitroeomorpholine
N -NL t, roErop iperi dine
N-Nltroaopyrrolidine
5 -Nitro-o- toluldine
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachloronl t, robenz ene
Pentachloroplrenol
Phenacetln
Phenanttrrene
PhenoI
Phorate
2 -Picoline
Pronamide
Pyrene
ryridine
L ,2 , 4 ,5 -Tetraetrloro-
benzene
2, 3, 4, 6-Tetrachlorophenol
ThLonazLn
0-T0luidlne
L,2 ,4-Trichloro-
benzene
2 ,4, 5 -Trichloro-
phenol
IIRS CorporaEl.on
CII-ent Sa4fle ID: SHB-91O-O9O1O5
gclug BenLvol.ati]-es
D5IO20230-002 Hork Order *---! H.ItQAIAB
REgTIIJT
REPORTING
TTMIT
Uatri-x.--.-----: GII
uNrrq. ._-__
lug/r'
ug/r,
lug/L
ug /r'
ug/t'
ug/r,
ug/t,
:ug/T-,
trg/L
ug /t'
Ltg/T'
lcg/t'
ug/r,
tl.g / T"
rug/L
ug/L
lus/L
ug /t'
ug/t
ug/r,
ug/r,
us/L
]ug/L
lu,g/L
ug /r'
ug /t
]ug/L
ug lt
tJg /T"
ug /r,
ug/r,
ug/r-,
vg /r'
ug /T'
ug/L
LLg /T,
uslt
ug/T,
ug/L
ND
ND
IUD
IUD
ND
tlD
ND
rlD
t[D
ND
t[D
ND
ND
IID
ND
TgD
ND
ND
IID
ND
ND
r[D
ND
ND
ND
ND
ND
ND
ND
ND
t[D
DID
}(D
ND
IUD
(continued
s0
10
10
s0
50
50
10
10
s0
1-00
1_0
10
t_0
10
10
L0
10
L0
10
20
50
10
s0
50
50
20
1-0
10
50
20
20
10
2A
10
50
1-0
10
1.0
10
on next page)
tlD
ND
I{D
l[D
STL Denver
IIRS Corporation
Cl.ient Saryfie srrB-910-o9010s
eC/us Senirrol-atl.I-eg
D5IA2O23O-002 llork Order *- - - 3 H,r\IQA1AS Itlatrfur.-------?: GWIot-Saqr1e
PARAMETER RESIJLT
REPORTING
LIMIT IINTTS
2 , 4 , 6 -Triehloro-
phenoJ-
O, O, O- Triethylphosphoro -
thioate
1, 3, 5 -Trinitrobenzene
SIIRROGATE
ND
ND
PERCETVT
RECOT'ERY
10 ug /T'
50 ug/I'
so ug/L
RECO\IERY
IrfMf TS
2-Fluorophenol
Phenol-d5
Uitrobenzene-d5
2 -Fluorobiphenyl
2 ,4 ,C-Tribromophenol
Terphenyl-d1-4
77
79
76
70
83
2A
STL Denver 42
IIRA CorlnraLLon
snB-910-o9010s
cc/ldS Benirrol.atsi1ee
Ipf,-ltarErls *: D5I02023A-002 work Order *: HiI\/QA1AB
O
IYTASS SPECTRoMETER/paTa SYSTEM
PARAMETER
(MSDS) rmUraTrVErrY TDENTIFTED
ESTIMATED
CAS #RESULf
tratrl:r: GsI
COMPOI]NDS
RETEITTION
qII,qF ..UNITS
2 . a84 ug /T,
2.229 ug/L
2 .3095 trg /f'
5 ,5 623 :ug/t,
5 - 8 828 vg /I-'
8 .2999 ug /t,
Unknown
Qyclohexane
Unknown
Unknown
Unknown
DiethyltoluamLde
rwE(s):
110 -82-7
1_34 - 62-3
7.3 J
33J
s9J
4.9 J
5.7 LT
6.2 J
FI
M
M
M
M
M
M: Resutt wag fleasurcd against nearest intornal gndand asrmlng I responsc factor of l.
STL Denver
URg Corpor:atLon
Cl'Leut Baqrl.e ID: SfnB-91O-O9O1o5
Gf.lu9 semirrolati]'es
fot,-garugll.e #- - -:
flate 8aryrl.ed.--3
fep Date-,r---l
Prep BatcJt *- - . 3
Df.I.ution Faetor:
Dsr02 a23 0- 002
0e/oL/ as oz: oo
oe/or/as
525043 s
L
sork Order f-, -:
Date Recel.rred- -:
nnalysis Date. - !
llnalyefs Time- - !
Dlethod!--o.----3
EEsrryT .-
ND
PERSEI{T
RECO\IERY
53
68
70
72
67
24
H,J\IQA1A9
oe / 02/ os
oe/tt/os
2A -.47
gw8{5 827AC
REPORrrING
TIMTT UNITS
triatri;r--3 GW
PARAMETER
Pentachlorophenol
SURROC,ATE
4.o lug/L
RECOTdERY
LIMffS(ag 116)(zz 109 )(ze L25l
(38 114 )
(37 105)
0z L42l
2 -Fluorobiphenyl
2 -Fluorophenol
2,4 ,F-Tribromophenol
Nitrobenzene-d5
Phenot-d5
Terphenyl-d14
STL Denver 44
IIRA Corporation
ClLent 8aryfie ID: gHB-9-O9O1os
Gr.lrr8 Senlvol.atil.ee
Iot-San4lle $- - -:
Date Saryfled.---l
Prep [late- - - - - - 3
PreB Ba.tcfr *- - -:
Dl-I.ution Factor:
Dsr020230-003
oe / oLlos 1o:55
ae/06/os
5249103
1
tork Order *- - -:
Date Receird.- - 3
Anaaygis Date- - l
Ana-IyaLe tfurc- - !
[rgtrhod----o----!
REptlLT ,.
HinIQsILK
oe/a2/0s
oe/Lo/os
O1-:05
sw845 8270C
REPORTING
IrfIt{If UNITS
lrlatrix]Oro-.---r CW
PARAMETER
Acenaphthene
Acenaphthylene
Acetophenone
2 -Ac et yl aml,no f luorene
4 -Amlnobiphenyl
AniIl-ne
Anthraeene
Aramite
Benzidlne
Benzo (a) anthracene
Benzo (b) f luoranthene
Benzo (k) fluoranthene
Benzoic acid
Benzo (ght) perylene
Benzo (a) pyrene
Benzyl aJ.cohol
bis Q-chloroethoxy)
rneEhane
bis (z-Chloroethyl) -
ether
bis ( 2 - Ctrloroi sopropyl )
ettrer
ble (z-Erhylhexyl)
phthalate
{-Bromophenyl phenyl
ether
Butyl benzyl phthalate
Carbazole
4 -Chloroarliline
Chlorobenzilate
4 - Chloro - 3 -methylphenol
2 -Chloronaphthalene
2 -Chloroptrenol
4 -Chloroptrenyl phenyl
etner
Chrysene
DiaIlate
Dlbenz (a, h) anthracene
ND
ND
ND
ND
ND
IUD
ND
ND
ND
IUD
ND
ND
ND
ND
ND
ND
ND
}ID
TID
IUD
(Contlnued on
10
L0
10
100
50
10
10
20
1.0 0
1-0
10
1-0
s0
10
10
10
10
L0
10
10
10
10
L0
10
10
10
10
1.0
L0
10
2A
l-0
next page)
ug/t
Lrg /r'
:ug/t'
ug /t'
ug /T'
ug/t-'
vg/r'
Ltg/L
rug/t
uglt'
ug/L
rtg /r'
ug/r-,
rug/L
ug/r,
ug/t'
ug lt
ug/T'
ug/r"
rtg /T'
ug /T,
:ug/t
ug/r,
ug/r,
ug/T'
ug/L
lug/t
ug/r
ug /r'
ug/L
ug/1,
ug/L
IUD
ITD
IUD
ND
IUD
r[D
ND
ND
STL Denver
URg Corporation
Cl.ient 8aryrl.e ID: 8HB-9-O9O1-O5
or,lW 8emfircIatil.es
D5ro2023o-o03 Hork order *- - . 3 HJI'Q51AK llatriJr. - - ' - - , ! . : GWIot-Saryfle
PARA},IETER
REPORTING
IJfMIT UNITSREST'I,T
ND
t[D
ND
ND
ND
ND
TUD
ND
ND
IUD
TID
IID
ND
ND
(Continued on
DLbenzofuran
Dl-n-buty1 phthalaLe
3, 3 ' -DLctrlorobenzidlne
2 ,4-Dlchlorophenol
2 , 6 -Dichlorophenol
Dietrhy1 phthal.ate
Dimethoate
7 ,L2-Dimethylbenz (a) -
anthraeene
3, 3' -Dl-meLhyJ-benzldlne
2 ,4-DJ-methylphenol
Dimethyl phthalate
1, 3 -Dinltrobenzene
4 ,6-Pinitro-
2 -rnethylphenol
2 ,4-Dinitrophenol
2 ,4-Dinl-Erotoluene
2 , i-Plnitrotoluene
Dl-n-octyl phthalate
Dl,pheny)-amine
L, Z-Diphenylhyd T azlne
Dioulfoton
Ethyl methanesulfonate
E'luoranthene
Fluorene
Hexachlorobenzene
Hexachl orocycl openta -
diene
Hexachloroethane
Hexactrloropropene
Indeno ( 1, 2 ,3 -cd) p)rrene
feodrLn
Isophorone
rsosafrole
Ptethapyrllene
3 -Methylcholanthrene
Methy} methanesulfonat,e
2 -Methylnaphthalene
1-Methylnaphthalene
[Iemyl parathion
2-Methylphenol
3 -Methylphenol &
4 -l'lethylphenol
ND
IUD
ND
TID
ND
ND
ND
ND
t[D
Itu
IID
}UD
ND
10
10
50
10
r0
10
20
20
2A
r.0
10
t-0
50
50
10
L0
Lo
ro
10
50
10
l,o
10
1-O
50
10
100
10
10
1-0
20
50
2A
L0
10
L0
50
10
1-0
next page)
ug/t'
ug /t'
ug/u
ug/t'
:ug/T'
Ltg /r,
ug/t'
ug/r,
ug/r,
ug /t'
ug/T'
us/L
ug/t
Vg /T,
ug/t
]J,g/L
ug /r'
lug/t
ug/T'
:ug/T'
ltg /T'
uglu
.u,g/r'
ug /T.
uglr,
ug /r'
ug/r,
ug/T'
trg /T'
ug/T'
lug/r'
ug /T'
ug lr,
ug/L
trg /T'
ug/t
uslL
ug/1,
ug/I,
IgD
ND
I{D
ND
DID
IID
ND
t[D
ND
ND
DID
ND
STL Denver 46
Ung CorporatLon
Cl-imt 8aryrl.e ID: $I[B-9-O9O1O5
gcArs Benlrro].atil.es
IIork Order #---: HiI\IQSIAK lIat.rL:ro - - . - - - - - 3 Gwfot-Saqll-e * - - - : DsI 020230- 003
PARAMETER
A ,4-Naptrthoquinone
1-Naphthylarnine
2-Naphthylamine
2 -NttroanilLne
3 -Nl-troanlll-ne
4 -Nitroanlline
NLtrobenzen'e
2 -Nitrophenol
4 -Nttrophenol
4 -NiLroquinoline-
1,-oxlde
N-Nl t rosodi - n- butryl amine
N - Ni t ro sodi et hyl amLne
N - Ni t rosodl-me Ehyl aml-ne
N - Ni t ro god iphenyl amine
N- Nit,rosodi - n-propyl -
amine
N - NL t ro a ome t hyJ. ethyl aml-ne
N-Nitrosomorpholine
N-Nitrosopiperl-dLne
N-Nitrosopyrrolidlne
5 -NLtro-o-toluidine
ParaEhion
Pentachlorobenzene
Pentach].oroethane
Pentaclrl oron t t robenz ene
Pentachlorophenol
Phenacetin
Phenanthrene
PhenoI
Phorate
2 -Pieollne
Pronamide
Pyrene
Spridine
L,2,4,S-Tetrachloro-
benzene
2, 3, 4, 6 -Tetrachlorophenol
rhionazin
0-Toluidine
L ,2 ,4-Trichloro-
benzene
2, A, 5-TrLchloro-
phenol
REST'LT
M)
(Continued. on next
REPORTING
IJIMIT T,NITS
ND
ND
ND
ND
ND
ND
ND
ND
ND
IUD
IID
IID
ND
ND
ND
ND
tlD
ND
ND
r{D
ND
IID
t{D
ND
ND
ND
IUD
ND
}TD
ND
lsD
ND
ND
ND
50 ug/t
10 ug/L
10 ug /I'
so :ug/T,
50 :ug/T'
s0 ug/r
10 ulg/L
10 ug /T,
so ug/L
1-oO ug/r'
10
1_0
10
10
10
1-O
1_0
10
1,0
20
50
10
50
50
50
2A
10
10
50
20
20
L0
20
10
s0
10
10
L0
:ug/r.
ug/t'
ug/T'
ug/r-,
trg/L
ug/r,
LLgIL
ug/r,
ug /t"
ug/t
ug/r,
Vg/L
ug /t,
wg /T'
lug/T'
ug/r,
ug/T,
ug/t
ug /t
lu.g/L
ug/r,
lrg /T,
lug/L
:ug/L
Ltg /T,
ug /t,
uslt
ug/t-,
10 uglt
page)
IUD
ND
I{D
ND
STL Denver
Iot.-Sa4l1e *-, -:
PARAI,IETER
IrRg Corporatlon
C1ient, Saryll.e ID: AilB-9-O9O1O5
W,lbtg. semivo].atil-es
D5I02O230-003 Work order *---3 H.r1IQSIAI(
REPORTTNG
LIMIT
ItatrLx-rO...---: GI{
UNITS
ug/t'
lug/L
ug/t
RESULT
-
2,4 ,6-Trichloro-
phenol
O, O, O-Triethylphosphoro-
thl-oate
1, 3 , S-Trinltrobenzene
ST}RROGATE
t[D
PERCBTT
RECO\IERY
10
50
50
RECO\TERY
LIMITS
2 -Fluorophenol
Phenol-d5
Nitrobenzene-d5
2 -Fluorobiphenyl
2,4 | 6-Tribromophenol
Terpheny}--d14
r5C)|fB (8) :
4L*
23*
74
55
52
7L
(as e2 )'(49 e8 )(so ee )(+E eI )(48 1-13 )
( 10 1so)
I Surrogatc rcrovery ic outside statod control limitr.
STL Denver
Iot,-Saryfle *: DsI02023 0 -003
I4Ag8 SPECTROMETER/DATA SYSTEM
PARAMETER
Unknown
Clrclohexane
Unknown
Unknovrn
2 - But€utone, 3 - hydrotry-
Unknorrn
Urrknown
Dimethyl sulfoxide
Unknowrr
DLmethyl sulfone
Unlcnown
Unknown
Unknonrn
Unknown
Unknown
Unknown
Unknown
Unknown
2 -E'luoro- 6 -nltrophenol
Ethano} , 2- (2-buEoxyet,hory) -
Unknown
Unlrrrown
Unknown
1, 3 -Butadlene, ?-methyl-
Phenol, 2 - fluoro-4 -nitro-
Unknorsn
Unknown
2 (4H) -benzofuranone, 5 ,6,'l ,7a-
Unknown
IUTts(S} :
IIRS Corgloration
sHB-9-090105
GCAIs Senirzol-atil-ee
I5ork Onder #: H,JIIQSIAK Irratrl-x: GTt
(uSns} rMUrerr\IEIJY IDEMTIFIED COMPOTINDS
ESTIMATED
CAS # REST'LT
19 .I
43J
87 ir
20 .f
6.9 LT
9.9 'J5.5 .T
28J
7 .O .J
10J
5.8 J
6.0 ir
7 .8 iI
6-0 J
19 ir
5.1 J
L4 ir
6,7 ,f
5.4 ,J
8.5 ,J
7 .A ,f
7 -O J
23 rI
15 .f
15 ir
8.4 ,f
5,8 ,f
6.8 .I
7-B ,]
RETEMTTON
TIME
1* 9813 wg/L
2,2282 :uLg/T,
2 -3087 ug/T.
2 -3946 :uig/L,
2 .5449 ug/t'
2.92A6 ug/n
3 -4252 luig/L
3 .5?55 ug/I,
3 . 9995 ug/r,
4 . 1928 ug/T'
4.284 :ug/T,
4 .3 8 06 lug/I'
5 . 13 21 ug/L
5 -27L7 ug/T'
5 .41L3 ug/t'
5.'187 ug/L
5.845 ug/t'
5.8 997 ugll
5 .9534 ug/l'
6.093 ug/t'
6.3 A71 :ug/T'
6.409? :ug/I"
6 -7478 ug/T"
6 .8444 :ug/L
7 , AL62 ug /T,
7.3383 ug/I'
8.0736 ug/r,
8.20?8 vg/I'
8 .4916 rug/T'
1,10 -82-7
5l_3-85-O
67-68-5
67 -7L- O
1525- 17 -6
t]z-34 -s
78-79-5
o-oo-o
170 9?--92-L
M
M
M
M
M
M
M
M
M
M
M
M
M
M
Ir{
M
M
M
M
M
M
M
M
M
M
M
M
M
M
M: Result was mcasurod against nearest inrcrnal ganderd assuming a response factor of I.
STL Denver
Iot-Saryfle *. , -:
Date Saryrl-ed-.-3
kgp flatg. ! - - - - 3
Prep Bat,ch #,. -:Dilution Factor:
IIRS @rtrrcratloa
C1ient Saqr1e ID: 8IIB-9-O9O1O5
olcfif6 aenirrol-atLl.ee
tlork Order f;.-.: H.J[IQS1AI,
Date Receiwed- . 3 09 / A2 / 05
ana-lyeie Date. - 3 09h3/05
Anal'yeie fime--: 2L:O7
frcthod- - ., - - - - - 3 SW846 B27Oe
Dsra20230-003
oe/aL/os 10:55
oe/07/os
s25043 5
L
PAIUIMETER RESUIJT
REPORTTNG
LIJI{IT UNfTS
PenLachlorophenol
ST]RROGATE
}UD
PERCENT
REEOT/ERY
4 . O ug/r,
RECO\IERY
IJIMITS
(sg 116)(zz 10e)
Qa L26l
(te 114)
(37 r.06 )(tt L4zI
2 -F).uorobiphenyJ.
2 - Fluorophenol
2,4 ,i-Trlbromophenol
ttltrobenzene - d5
Phenol -d5
Terphenyl-d14
NCrrB (B) :
51_
L3*
L2*
76
5.J. *
15*
a Surrogate r@very is outside statcd control limits.
STL Denver 50
IIRII CorporatLon
Cl'imt IIanpI-e ID: SIIB-9-O9O1O5
CCAf,s Semlrro].atil.es
f.ot-Sampl-e f;---3
Irate Saqll.ed--.3
Prep Date------l
Prrep Batch *. . - :
DlJ.ution Faetor:
Dsr02023 0 - 003
a9/oL/as 1o:55
ae/14/as
s257544
1"
Ilork Ordr=r *- - -:
Ilate Recelwd- - 3
lna-lyria llate- - 3
Anal-ygls TiEe- - !
lletlrcd- - - - - - - - - l
RESULT
HirVQS2AI(
oe/02/os
ae/2L/os
22 zL6
sw846 8274C
REPORTING
IJIMIT T]NITS
lfiafli--, - . , - - - -: GW
PARAMETER
Aconaphthene
Acenaphthylene
Acetophenone
2 -Acetyl amino f luorene
4 -Aminobl-phenyl
Anlline
Anthracene
aramLt,e
Benzidine
Benzo (a) artthracene
Benzo (b) f luoranthene
Benzo (k ) f luorantlrene
Benzolc acl-d
Benzo (ghi) peryIene
Benzo (a) pyrene
nenzyl alcohol
bl s ( Z -Ctrloroetholry )
methane
bis Q-Ctrloroethy}) -
ether
bis (Z -Chloroi sopropyl )
etlrer
bts (2-nthylhelryl )
phthaJ.ate
4-Bromophenyl phenyl
ether
Butyl benzyl phthalate
Carbazole
{ -Chloroanlline
Chlorobenzilate
{ - Chloro - 3 -methy}phenol
2 -Chloronaphthalene
2 -Chlorophenol
4-Chloropheny1 phenyl
ether
Chrysene
Dl-aIlate
Dibenz (a, h) anLhracene
TID
ND
ND
(Continued. on
ND
ND
t[D
ND
I{D
ND
ND
r[D
ND
ND
ND
IUD
IqD
ND
ND
IID
!{D
10
10
10
100
50
1_0
10
2A
100
10
10
10
50
10
10
l_o
L0
10
l-o
10
r.o
10
10
1_0
1-0
10
10
10
10
10
2A
10
next page)
lug/u
ru.g/t
:og/r'
:ug/T"
ug/r'
ug/r'
ug/T'
ug/r'
:ug/L
ug/r,
ug /t'
ug/T'
:ug/r,
ug/r,
ug/t,
:ug/r'
:ug/t'
ug /t'
Vg /T,
ug/r,
lu,g/t
trg /I'
ug/t,
tuig /T'
ugll'
ug /r.
vg /T'
ug/L
ug /t'
ug/t'
ug/T'
ug/L
r[D
IUD
IUD
t[D
IUD
ND
I{D
IUD
STL Denver
IIRS Corporation
Client llaryfle ID: 8HB-9-O9O1O5
Gf,h{8 Semfiro].ati].es
Iot-Saqrl.e
PAIUNYIETER
DsI 42023 0 -003 lrork Order
RESUITT
t- . - : HJVQ52AK Hatri-x-, - - - - - -- i GW
REPORTING
IJIMTT UNITS
Plbenzofuran
Dl--n-buty1 phthalate
3, 3 t -Dl-ctrlorobenzl,dine
2 , 4-Dichlorophenol
2 , i-Dichlorophenol
Diethyl phthalate
Dl-methoate
7 , L2 -Dlrnethylbenz (a) -
ant,trracene
3, 3 t -DLmethylbenzldlne
2 ,4-Dimethylphenol
Dimethyl phthalate
1, 3 -Dinltrobenzene
4 ,6-Dinitro-
2-methylphenol
2 ,l-Pinit,rophenol
2 , 4-Dinltrotoluene
2 ,F-Dinitrrotoluene
Di-n-octy1 phtshalate
Dlphenylamine
A, Z-Diphenylhydraz ine
Dieu]-foton
Ethy1 methanesulfonaE,e
Fluoranthene
Fluorene
Hexachlorobenzene
Hexa ctrl orocyc I opent a -
diene
Hexachloroet,hane
Hexachloropropene
Indeno ( L, 2,E -cd) pyrene
rsodrin
fsophorone
Isosafro]-e
Methapyrilene
3 -Methylcholanthrene
I*Iet hy} methanesul fonate
2 -Methylnaphthalene
1 -Methylnaphthalene
Methyl parathion
2 -Methylphenol
3 -Methylphenol &
4 -Methylphenol
}UD
ND
ND
ND
IID
ND
IUD
l{D
tlD
ND
l[D
ND
I{ID
IID
(Continued on next
ND
TID
IID
IID
IgD
ND
IUD
ND
IUD
ND
IID
IID
ND
1_0
r-0
50
L0
10
10
20
20
2A
10
10
10
50
s0
1-0
10
10
10
L0
50
10
L0
10
10
50
10
1.0 0
10
10
10
20
50
2A
10
10
10
50
10
10
page)
ug/r,
ug/r,
lug/L
ug/T'
:ug/r-,
lug/T'
:ug/t'
ug/L
:ug/T'
rug/L
ug/t'
ug/L
ug/L
ug/r,
:ug/T'
ug /T'
uglr,
:ug/t
ug/r,
ug/r,
:ug/T'
ug /T'
ug /T'
ug/r-
ug /T'
rug/r'
ug/t'
:ug/L
rtg/L
ug /r'
ug /r,
:ug/t'
ug/r,
ug/r'
ug/t,
ug /t'
uslL
us/L
ug/t,
ND
t[D
ND
r[D
ND
}TD
ND
ND
ND
ND
IUD
ND
STL Denver 52
URI! Cortrrcratl-on
Client, Baqfle ID: SIIB-9-O901O5
Gf.lt*s senlrrolatl.les
Iot-Staryile f; - - - 3 DsI O2O23 0- OO3
PARAMETER
L , A-NaphthoquLnone
1-Naphthylamine
2 -Naphthylamine
2-Nitroaniline
3 -NlEroantline
4 -Nitroaniline
Nitrobenzene
2-Nitrophenol
4 -Nltrophenol
4 -Nlt,rogulnoline-
L -oxide
N- Ni t ros odl - n -butyl arnLne
N - Ni t ro e odi ethyl aml-ne
N- Ni t ro e odime thyl amine
N - NL t ro sodiphenyl amine
N - Nltrosodi -n - propyl -
amlne
N- Nl- t ro s ome thy I ethyl amine
N - Nl t, ros ornorphol l-ne
N-NitroaopiperJ-dine
N-NitrosoByrrol idine
5 -Nitro-o-toluidine
Parathion
Pent.ach].orobenzene
Pentach]-oroetrhane
Pent achl oroni t roben z ene
PenEachJ-orophenol
Phenacetin
Phenanttrrene
Phenol
Phorat,e
2 -Picoline
Pronamide
Pyrene
PyrJ-dine
L ,2 , 4 ,5 -Tetrachloro-
benzene
2 ,3 , 4 ,5 -Tetrachlorophenol
ThionazLn
0-Toluidine
L ,2 , 4-Trlchloro-
benzene
2 ,4, 5 -Trlchloro-
phenol
Ilork order #---: H.I/QS2AK Hatri-x---------: GIII
RESUIJT
REPORTTNG
TIMTT UNTTS
ND
ltD
ND
ND
ND
ND
ND
ND
ND
ND
ND
IID
ND
ND
ND
ND
ND
ND
ND
ND
ND
IUD
tlD
ND
ND
ND
ND
ND
IID
50 ug/T'
10 ug/L
10 ug /T'
so :ug/L
sO wg/r
50 ug/t
l- 0 ug/t,
1- O vg /f'
so ug/r,
10O vg/I'
ND
ND
ND
ND
ND
10
1_O
10
10
10
10
1_0
10
1.0
2A
50
10
50
50
s0
2A
10
10
50
2A
2A
1-0
20
L0
s0
L0
10
10
L0
ug/t'
lug/L
ug/r,
:ug/r'
ug/r,
ug/r,
:ug/r'
wg/T'
ug/L
ug/T,
ug/r,
ug /T'
Iug/t
ug/T.
:ug/T-'
vg /r'
ug/L
:ug/t,
ug/r,
ug/L
ug/t
ug/L
:ug/t,
ug /t'
vg/r,
ug/r,
us/L
tl'g /r'
ug/r,
ND
}UD
I\ID
ND
STL Denver
(ContLnued on next page)
Iot-Saryl1e
PARAIVIETER
URg corlloratl"on
C1ient 8a4fle ID: SHB-9-O9O105
oefi{,8 Seml-rrol.atlJ-eg
D5f 02023 O- OO3 Hork Order * - - . : HWQ52AK tiatri:r.--.ro.-.! GW
RESUL'T
REPORTING
LIMIT UNITS
2,4,6-Trichloro-
phenol
O, O, A-friet,hylphosphoro-
thioate
1, 3, 5 -TrLnitrobenzene
SURROGATE
ND
PERCE:MT
RECOVERY
10 ug/t
50 ug/r,
:ug/r'50
R.ECO1IERY
LIMTTS(+s e2
(+g 98
(so ee
(ag e1
(ea 113
(ro 1s0
2 - Fluorophenol
Phenol-d5
Nl-trobenzene-d5
2 - Fluoroblphenyl
2,4 ,F-Tribromophenol
Terphenyl-d14
IWTE (S} :
L7*
4.7 *
58
45
30 *
37
. Surrogate rocoycry is outside sotod control limlts.
STL Denver 54
I,ot-Saryr1e *: D5I020230-003
MASS SPECTROMETERIDaTA
PARAMETER
rrRsl corporation
gttB-9-oeo1os
Gf,,filug Semlrrolatiles
Ilork order *: HiruQs2AK ffatri:r: GIII
SYSTEM (T.ISOS) TENTETIVELY IDENTTFIED COMPOT'IIDS
CAS #
EgTTMATED
RESTILT
RETEMTION
TIME T}NITS
Unknourn
Unlcnown
Unknown
But,ane , 2 -met,horry- 2 -methyl -
Unlcnown
3 -Methyl - 3 - ctrloro- 1 -butene
Unknown
Unknown
Methane, dlbromochloro-
Unknown
Unknown
Unknor^rn
Unlnown
Unknown
Unknown
Un]cnown
Methane, tribromo-
UnJcnown
Urrknown
Unknor*rr
Unlrrrown
Unknown
Urrknown
Unknown
Unknown
Unknown
Unkrrown
Unknown
Urrknown
Unknown
ITC'IIE (S} :
994-05.8
2190-48-9
1,24-49-L
75-2s-2
L5 ir
8.9 J
39 ,J
14O Lf
20J
27 .T
14 ar
130 J
11 ar
9.L iI
11 ir
LLJ
18 ,,7
L7 ir
30 ,f
11O .I
44J
240 .f
26 .T
23 .T
8-5 .f
78;r
13 .T
1-3 ,f
15 .T
1sJ
L4J
L2 ir
I .4 ,.7
8.1 ,f
M 2.A22L lug/T,
M 2.2574 ug/L
M 2.2788 ug/t,
M 2 -3697 ug/T'
M 2.4285 ug/L,
M 2.5033 :ug/L
M 3.0005 ug/L
M 3.17LG :ug/L
M 3,4282 ug/1,
M 3.4764 ug/I,
M 3-s191 ug/L
M 3 ,5 673 lrg/L
M 3,61.54 ug/r,
M 3-6955 rlg/I'
M 3 .7918 ug/L
l-I 4.1L26 ug/t'
M 4.2088 ug/I'
M 4.2tE9 ug/L
M 4.3959 ug/t'
P[ 4 ,551 ug/t'
M 4.87L8 ug/t"
M 4.95?3 ug/L
M 5,1l-zq ug/t
M 5.8288 ug/l'
M 5.9GzB lug/t'
M 6.4329 ug/I,
M 5 , 8506 ug /T'
M 7 .L226 lug/L
M 7.7749 ug/t,
M 8.7265 ug/I'
M: Result was nrcasure<l rtgainat nearc,st httgrnrl candard asruming & rosponse factor of l.
STL Denver
fot,-Sarylle #-. -:
Ilate Salqtled,-..I
Prgp llate-.,.-.3
Prep Batc:h *. - - 3
DJ-I'utl-on Faetor:
IrRg Corporation
Clieut Saqrl-e ID: sHB-1o-o9O1O5
Gtr.lD{8 seni\rolatiles
Ilork Ordgr #- - -: H.IIQ9IAI(
Date Receirred- - 3 Ag / az / os
Ana-Iysie rlate--3 09 lli/Os
ena-lyele Tt.ue- . 3 OL :26
Hgthod-, i o o o . -, : SVil846 827aC
Xat,ri:r--,,,-or-: GWDsr A2023 0- 004
ae/oL/os 12:10
oe/06/os
s2491 03
1
PARAI{ET.ER RESUIJT
ITD
![D
IVD
(Continued on
REPORTING
T,IMIT TINITS
Acenaphthene
Acenaphthylene
Acetoplrenone
2 -Acetyl aminof luorene
4 -Aminobiphenyl
Anillne
Anthracene
Aramite
Benzldine
Benzo (a) anthracene
Benzo (b) f }uoranthene
Benzo (k) f luoranthene
Benzoic aeLd
Benzo (ghi) perylene
Benzo (a) pyrene
Benzyl al.cohol
bis (2-Chloroetho)cy)
methane
bis (Z-Chloroethyl ) -
ether
bl- e (Z -Ctrlorot eopropyl )
ether
bie (z-Ethylhexyl)
phthalate
4-Bromophenyl phenyl
eLher
Butyl benzyl phthalate
Carbazole
4 - Chloroanl-l ine
Chlorobenzilate
4 - ehloro- 3 -methylphenol
2 -ehloronaphthalene
2-ehlorophenol
4-Chloropheny1 phenyl
eIher
Chryeene
Diallate
Dibenz (a, h) anEhracene
ND
IUD
IUD
r[D
IID
ND
IID
ND
ND
ND
ND
ND
t[D
ND
ND
ND
I$D
1_O
L0
1"0
100
50
10
10
20
100
1-0
10
10
s0
t"o
1-0
l-o
10
10
10
1,0
10
10
10
1-O
10
10
10
L0
1_0
10
20
10
next page)
lg/L
ug/L
ug /I'
uglt'
rug/r'
ug/r'
:ug/t'
:ug/r'
ug /r,
ug/r,
wg /t
vg /T,
ug/l'
ug /t'
vg/r,
ug/r,
ug/r,
uglL
ug /t'
us/L
rlg/ r,
ug/r-,
ug /r-,
lug/r,
ug/l'
lug/L
ug/r'
ug/r"
ug /t'
ug/n
ug/1,
ug/1,
ND
r[D
ND
rlD
TID
ND
lvD
llD
s5STL Denver
IIRA Corporatl.on
C1ieut, Sanp1e ID: SHB-1O-O90I-O5
ef,'hilS semlrrol.atil.ee
D5f 02A230-004 llork Order #- - -: HiItIQ91AI(Uatri-xf o----...3 GTIIot-Eangll.e f . - -:
PARAT.{ETER
REPORTING
LTMTT UNITSRESUITT
llD
ND
ND
ND
IUD
}UD
IUD
!ilD
luD
ND
}UD
I'ID
IlrD
ND
(Contlnued on
Dilrenzofuran
Dl--n-butyl phthalate
3, 3' -Dichlorobenzidine
2 , 4-Dichlorophenol
2 ,5-Dichlorophenol
DJ.ethyl phthalate
Dlmethoate
z ,)2-Dimethylbenz (a) -
anthracene
3 ,3 r -Dlmethylbenzldine
2 , 4-Dimethylphenol-
DJ.methyl phthalat,e
t, 3 -Dinltrobenzene
4 ,6-Dinltro-
2 -meLhylphenol
2 ,4-Dinitrophenol
2 ,A-oinitrotoluene
2 , 6 -DLnitrotoJ-uene
Dl-n-octyl phthalate
Dlphenylamine
L, 2- D iphenylhydraz l-ne
Disulf oton
Ethyl methanesulfonat,e
F].uoranthene
E.luorene
Hexactrlorobenzene
Hexachlo ro cyc 1 opent a -
diene
Hexachloroethane
Hexachloropropene
Indeno ( 1 ,2 ,3 -cd) pyrene
Isodrin
fsophorone
Isosafrole
Methapyrllene
3 -Methylcholanthrene
Methyl methanesulfonate
2 -Methylnapht,halene
L -Mettrylnaphthalene
I'Iethyl para[hlon
2 -Methylphenol
3-Methylphenol &
4 -Methylpheno1
DID
ND
IUD
ND
ND
IID
N:D
ND
ND
ND
ND
ND
ND
10
10
50
10
10
10
20
2A
20
10
10
1.0
50
s0
10
10
10
1,O
10
s0
10
10
10
10
50
10 ug/t
10O ug/t
10 vg/I'
10 ug /I'
10 rtg/L
20 ug/L
50 ug/t"
20 trg /T'
10 ug /r'
10 uglt
10 ug /T'50 usll
1-0 ug/L
1.0 ug/1,
next page)
:ug/r,
rtg /r'
ug/1,
ug/r,
wg/1,
Dg /1,
vs/L
ug/r,
ug/T,
lug/L
:ug/t'
ug/t
:ug/r'
lu,g/L
LLg /T,
lug/L
uglT'
ttg /T'
ug /r,
lrgh,
ug/r,
trg /T'
ug /r,
Ltg /r'
ug/r,
I$D
IID
TID
ND
ND
ND
ND
IUD
tlD
ND
}ID
ND
STL Denver
Iot,-Saryl1e *.
PARAIT{ETER
URg CorporatLon
Clieut Sary>Ie ID: SIIB-1O-O9O1O5
@fi* Sernivolatiles
: D5Ia2o230-004 Hork order *' ' ' : H'11/Q9L'N(Hatri:r------.--3 GI{
RESUITT
REPORTING
LTMIT UNTTS
L , 4-Naphthoquinone
1-Naphthylaml-ne
2-Naphthylamlne
2 -Nltrroanlline
3 -Nitroaniline
4 -Nitroanillne
NlErobenzene
2 -Nitrophenol
4 -Nttrropheno1
4 -Nitroqulnoline-
l--oxide
N- Ni troeodL - n - butyl arnine
N - Ni Ero eodi e thyl amine
N - Nitroeodime thylamine
N - Ni t ro s odiphenylamine
N-Nitrosodi - n-propyl -
amine
N - Ni U ros ornethyl eEhy1 amlne
N-Nlt,roBomorpholine
II-NLtrosopiperldine
N-NLtrosopyrrolidine
5 -Nitro-o- tolul-dine
ParathLon
Pentachlorobenzene
Pentachloroethane
Pentachloron 1 t robenz ene
PenLachlorophenol
Phenacetl-n
Ptrenanttrrene
Phenol
Phorate
2 - Picol ine
Pronamide
Pyrene
Pyridine
L ,2 ,4 ,5 -TeLrachloro-
benzene
2, 3, 4, 6 -Tetrachlorophenol
ThionazLn
0-Toluidine
L,2 ,4-frichloro-
benzene
2 ,4, 5 -Trichloro-
pheuol
ND
ND
}TD
ND
ND
IID
}UD
rlD
IID
ND
ND
DID
IUD
ND
IID
IID
ND
ND
IUD
ND
ND
IUD
luD
![D
ND
}TD
![D
tlD
IID
IID
ND
}UD
}UD
ND
10
10
10
10
10
10
10
10
t0
20
s0
10
50
50
50
20
10
10
50
2A
20
L0
20
10
50
1-0
10
10
10
next page)
sO ug/I'
10 ug/t'
10 ug/r'
s0 ug/L
s0 ug/L
s0 ug/T'
Lo ug/I'
10 u.g/L
so vg/r,
100 ug/t
ug/r,
ug /T'
rrg /T'
ug/t'
rug/t
ug /r'
ug/T'
rug/r,
:ug/T'
ug /r,
uglr-
lus/t,
ug/r,
rug/t
us/L
LLg /r,
ug/T,
ug /r'
ug/r,
ug /t,
:ug/r"
ug /r,
ug/t''
ug /r'
ug/r,
ug/t'
uslL
trg /T'
us/L
t[D
}UD
ND
l[D
IitD
(Contl.nued on
STL Denver
URg Corgrcration
CJ-ient Saryrl.e il): SI|B-I-O-O9O1O5
ccArg sent\ro}atl.I-ee
Dsf 020230-004 lIork Oalder *- - - I H,WQ91AK Uatri:c--- ---: GIIIot-Saryl1e *-.-3
PARAMETER REST'I,T
2 , 4 , 6 -Trichloro-
phenol
O, O, O-Trlethylphosphoro-
t,hioate
L ,3, 5 -Trinitrobenzene
SI'RROGATE
llD
PERCENT
REEO\IERY
REPORTTNG
I,IMIT IINITS
10 ug/n
50 ug /t
50 vg/I'
REEOV(ERY
LTMTTS(4s e2 )(ag e8 )(so ee )(43 91 )(es 113)
( 10 1s0)
2 -Fluorophenol
Phenol-d5
NiErobenzene-d5
2 -Fluorobiptrenyl
2 , 4 , C-Tribromophenol
Terphenyl-d14
80
81_
79
76
85
28
STL Denver
fotr-Saryfie *: Dsf A2A230-004
TT{ASS SPECTROMETER/PETA SYSTEM
PAIU\MEjtBR
Unknown
Qgclohexane
Urrhnown
2 ,S-Furandlone, 3 -ethyl-4 -meth
Unknown
Unknourrr
Diethyltoluamlde
Unknown
UnJcnown
rrcfts (s) :
IIRS Corporation
$DIB- r-O-O90r.O5
c*lrrS senivolatLl.ee
Ilork Order *: HuT\IQ91AI(
(tlsos ) rnxrerr\rEr,Y TDEMTTFTED
llatrl:r: GW
COMPOUNDS
RETET{TION
TTME TINITS
M 2.O87L rtg/L
M 2.2256 ug/L
M 2.3071 vg/I'
M 5.5554 ug/l'
M 5.8858 ug/I'
M 7.2{55 ug/I'
M 8.3 o29 ug/T,
M 8-8826 ug/t
M g .6663 :ug/T'
ESTITvIATED
CAS # RESUIJT
9.9 J
34J
52 ,.7
6.2 LT
14 LT
4-5 .T
2L .I
26J
7L ,J
110 -82-7
3552-33-8
L34 -62-3
M: Reult was rncasured against ncerost lnternal suDdud eemrming 0 roqporrso Paetor of I.
STL Denver
Iot'-ganple #. - -:
Ilate Baqlled.---3
kep lla-tg.-----3
Prep Betch *. - - 3
Dll.utrLon Factor:
URA Corlrcratlon
Clieut Saqrl-e E): 8[B-1O-O9O1O5
GC/I,6 Seulvol-atil-es
ISork Order *-..r HWQSIAIT
Date ReceLrn=d, - 3 09 / oz / 05
Anaf.yoio llate- - i A9 / L3 / as
.Dnatyeis Tlme-. r 2L:27
ligtJrod- - - - - - - r . : SW845 827Ae
Hatrin------,,-= GW
o
Dsr o2a230- 004
A9/oL/os L2zLo
oe/a7/a5
s25043 s
L
PARAI,IETER R.ESUI,T
REPORTTNG
LIMTT UNTTS
Pentactr1-orophenol
STIRROGATE
ND
PERCENT
RECOTIIERY
4,A :ug/T,
RECO\IERY
IrfMIfg
(a g 116)
(zz 10e )(zs L25)
(sa 114 )(rz 105)
(rz L4z)
2 -FJ.uorobiphenyl-
2-F1uorophenol
2, 4, 6 -Tribrornophenol
NLtrobenzene-d5
Phenol-d5
ferphenyl -d14
55
76
76
79
75
25
STL Denver
tIRg Corporation
C1ient Saryll'e ID: SIIB-3-09O1O5
er^llre SenirrcI-atiles
PARAMETER
Iot,-Sary>le *. - - !
Date Saqll-ed,---!
Prgp Ilateo -, - - - l
Prep Batch *.. . 3
Dil.ution Factor:
Dsro2a230-005
ae/01/os 13:37
ae/06/os
s249103
1-
Ilork Order f - - -:
Ilate Receirred- - :
ana-Iyele Date- - 3
analysig Ti-ne- - 3
Dlgthod-.o.----.1
REgULT
ND
ND
IID
IUD
ND
ND
IUD
ND
IID
ND
ND
ND
}UD
ND
IID
ND
IID
HrI/RIt{1AI(
oe/02/0s
oe/La/a5
O2:28
sw845 8270e
REPORTING
I,IMTT UNITS
llatri-rr- - - - - - . - - : GII
Acenaphthene
Acenaphthylene
Acetophenone
2 -Acetyl amlno f luorene
4 -Aminoblphenyl
AniLine
Anthraeene
AramLte
Benzidl-ne
Benzo (a) anEhrace,ne
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzolc acid
Benzo (grhl) perylene
Benzo (a) pyrene
Benzyl alcoho1.
bie (Z-Chloroetholry)
metharre
bie Q-Chloroethy1) -
eLher
bis Q -Chloroisopropyl )
ether
bts (z -Ethy1hexyl )
phthalate
4 -Brornophenyl phenyl
ether
Butyl benzyl phthalate
Carbazole
4 -Chloroaniline
Chlorobenzilate
4 - Chloro - 3 -methylphenol
2 -Chloronaphthalene
2 -Chloropheno1
4-Chlorophenyl phenyl
other
Chrysene
Diallate
Dibenz (a, h) anthracene
r0
10
10
10
t-0
10
10
10
10
10
10
10
10
20
10
10 ug/L
10 ug/t
10 ug/t,
1OO ug/t'
s0 trg/L
10 ug/L
L0 ug /f'
20 lug/t
100 ug/t'
10 lg /T'
10 vg /T'
10 ug/t-'
s0 ug/t
10 ug /I'
10 ug/t'
10 vg/r,
L 0 ug/T'
:ug/r.
us/T'
ug/r,
us/r'
Lrg/T-'
LLg /r,
ug/r,
ug/r'
:u,g/t'
ug /r,
:ug/r,
ug/t
ug/t'
ug /r'
ug /r,
ND
ND
IUD
ND
ND
luD
ND
IUD
}UD
}ID
r[D
62STL Denver
(Continued on ne,(u page)
Iot,-Saryll-e #- - -:
PARA}IETER
URg Corporation
Cl.ieut Saqr1e ID: SD|B-3-O9OI-O5
GC/HS Semlrrol.ati]-es
Dsf A2O23 0- 005 llork Order #- - -: H{IVRMIAI(
REPORTING
I,IMTTRESUIJT
llatrLx---------i GTI
UN4TF
ug/T'
r;..g /T'
rtg /T'
ug/t'
ug/t'
ug/t'
lu,g/t
ug/t
rtg /T.'
ug/t
ug/r-'
vglT,
ug/u
LLg /T'
wg /t
1rg /r,
lug/L
ug/r'
ug/t
ug/r,
LLg /T'
ug/L
:u'g/t'
ug lT'
ug/t'
ug/r,
ug /t,
lug/T'
ug/r,
ug/t'
ug/T'
us/L
ug/L
ug/r,
ug /r,
ug/r,
us/t
ug/t"
ug lI'
Dibenzofuran
Di-n-butyl phthalat.e
3, 3' -Dichlorobenzidlne
2 ,4-Dtclrlorophenol
2 ,6-Dichloroptrenol
Dlethyl phthalate
Dl.methoate
7 ,Lz-DimeLhylbenz (a) -
anthracene
3, 3' -Dirnethylbenzidlne
2 ,4-Dl-methylphenol
DLmethyl phthalate
1, 3 -DLnitrobenzene
4,6-Dinitro-
2-methylphenol
2 , 4-Dinitrophenol
2 ,(-Dinl,trotoluene
2 ,F-DLnitrotoluene
oi-n-octry1 phthalate
Dl-phenylamLne
L, Z-Dtpheny1 hydraz l-ne
Dleulfoton
Ethyl methanesul fonate
F].uoranthene
Fluorene
Hexachlorobenzerre
Hexa chl- o ro cye I opent a -
dlene
Hexachloroethane
Hexachloropropene
Indeno ( 1, 2,E -cd) pyrene
Isodrin
fsophorons
Isosafrole
Methapyrilene
3 - l,Iethyl ehol ant hrene
MeEhyI met.hamesul f onate
2-Methylnaphthalene
1 -MeLhylnaphthalene
I,lethyl para[hion
2-Methylpheno1
3-MeLhylphenol &
4 -llethy1phenol
tlD
ND
tlD
ND
rvD
ND
ND
ND
ND
ND
IilD
ND
ND
1_0
10
50
1-0
1o
t_0
2A
20
20
10
1_0
10
50
s0
10
10
10
10
10
50
10
10
10
10
50
1-O
100
10
L0
10
20
s0
2A
10
10
10
50
10
L0
on next page)
ND
ND
ND
ND
IUD
ND
ND
ND
ND
ND
ND
ND
}UD
rlD
ND
rlD
ND
IID
IID
ND
ND
ND
ND
IID
IUD
IUD
(Continued
STL Denver
IIRS Corporation
cl.ient saqfie rD: stB-3-o9or"o5
Gclr{s sentrrcIatl-Iee
*, - -: D5I020230-005 llork Order f - - .: HiIIIRM1AK triat,ri-x- - .,, -,,, : G"[t[Iot-Saryfie
PAIUIMETER
L ,4-Naphthoquinone
1-Naphthylamine
2-Naphthylamine
2-Nitroanilino
3 -Nitroanlline
4-Nitroaniline
Nltrobenzene
2-Nitrophenol
4 -Nl-trophenol
4 -Nit,roqul-noline-
1-oxlde
N - Nit ros odl - n -butylamine
N -Ni t, ro eodiethyl amine
N - Nl t rosodimethylamlne
N -Ni t roeodiphenyl amine
N -Nitrosodi -n -propyl -
annine
N - N I t ros omethy 1 e t hyl annine
N-Nltrosonorpholine
N-Nitrgsoplperl-dine
N-Nltrosopyrrolldine
5-Nttro-o- toluidine
Pa.rathion
Pentachlorobenzene
Pentachloroethane
Pent aehl oronL t roben z ene
Pentachlorophenol
Phenacetin
PhenanLhrene
Phenol
Phorate
2 -Picoltne
PronarnLde
srrene
Fyridine
L,2,4,5-Tetrachloro-
benzene
2 ,3 ,4 ,6-Tetrachlorophenol
Thlonazin
0-Toluidtno
L,2 ,4-Trichloro-
benzene
2 ,4, 5rTrlchloro-
BhenoI
RESUIJT
TID
(Continued on ne>(t
REPORTING
LIMIT UNITS
}TD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
I$D
TID
ND
TUD
ND
ND
ND
ND
ND
luD
!{D
ND
l[D
ND
lUD
ISD
IID
TID
llD
t[D
ND
50 ug/t'
L0 ug/T,
10 ug lr,,
50 uglt'
5 0 uglt'
50 vg/T,
10 ug/r,
L0 us/L
50 vg/T'
100 :ug/t"
10
10
1_0
10
L0
L0
10
10
10
2A
50
1-0
50
50
50
20
10
10
s0
2A
2A
10
20
10
50
10
10
10
10
page)
:ug/T'
vg/T"
ug/t'
ug/T,
ug IT'
ug/t'
ug/t
lug/T,
ug/r.
ug /T'
ug/t
ug/t
ug/L
ug/r,
ug/t,
:ug/t
ug/r,
:ug/T'
ug/T'
ug lT'
ug /Y'
rush,
.ug/T'
ug/l'
ug/T"
ug/r,
uqlL
ug/r'
ug/1,
IUD
![D
I\ID
TUD
64STL Denver
Iot-Saryl1e *. - -:
PARAMETER
Gf,lt;,s Semlvol-atll-ee
D5I02A230-005 Hork order *- - -:
R"EgTIIT
IIRS Corporation
Client Saryll-e ID: SIIB-3-O9O1O5
ND
PERCEMT
RECO\IERY
26*
3.4 *
80
75
30 *
47
HinmMlAI( ffatrL:c- - . . - r . - . ! GI{
REPORTING
LIMIT UNITS
10 uglL
50 rtg/T'
s o vg/T,
RECOVERY
LIMITS
2,4 ,6-Triehloro-
phenol
O, O, O-Trlethytphosphoro-
thioate
L ,3, 5 -Trinltrobenzene
SURROGATB
2-Fluoropheno1
Phenol-d5
Nltrobenzene-d5
2 -Fluorobiphenyl
2 , 4 , 6-Trlbromophenol
rerphenyl -d14
NOTB (S} :
I Surrogoto recovery ls outsi<lg etated control llnrlts.
l
t
I
I
I
I
I
I
I
I
t
STL Denver
f.oE-Saqfle * : D5I 02023 O - 0O5
IIRA Corlrcration
gHB-3-O9010s
Gf.fitg Senl-rro]atil-en
Iforlr order *: H{I\mM1AK l{atrix: G}I{
MASS SPBCTROI,TSTtsR/DAII SYSTEM (MS!DS) TENTATI\/EIJY IDBITIFIED COMPOT'IIDS
PARAI"IETER CAS #
ESTIIyIATED
RESUIJT
RETENTTON
TIME -...,
Urrknown
Qpclohexane
Unknown
3 -Methyl - 3 - chloro- 1 -butene
Urrknown
Unknourn
Unknorrm
Unknown
Unhnown
Unknown
Unknorvn
2 - Fluoro- 5 -nl Erophenol
Unknourr
Urrknown
Unlcnown
Phenol, 2-fluoro-+-nitro-
Unknown
Unlcnown
Urrknown
Unknown
Unknowrr
UnJ<nown
Unknown
Unknor.rn
Unknown
Phenol, 2, 6-dibromo- 4 -nl-tro-
Unknown
twrB (8) :
1l_0 - 82-7
2L90-48-9
1,526-L7 -6
0-00-0
99-28-s
24 .J
34 .T
50 .I
13J
15 ,J
s3J
B .3 .,f
11 J
19 'J4.3 J
2L 'J5-1 iI
20 ir
26 iI
6.3 ir
7.7.f
4.6 J
37J
9.0 J
4.8 J
7.5 .,
8.8 ir
19 ir
L4 iI
9.2 \r
I_3 ir
5-5 ,]
M 1,9813 ug/l'
M 2.2335 ug/L
M 2.308? :ug/L
M 2.4375 ug/L
tvl 3.4198 ruLg/L
M 3 .9995 :ug/r,
NI 4.279G ug/f'
M tL .4343 ug/L
M 5,4 LLz rug/L
M s.BLgz ug/t
M 5.8 4O7 rug/L
M 5.9534 ug/T'
M 6,6727 ug/T,
M 5.7424 ug/T'
M 6.8605 ug/T'
M 7.0055 ug/T.
M 7.0805 :ug/L
M 7.2148 ug/T'
M 7 .33 83 :ug/I'
M 7.6't64 :ug/t
M 8.L434 ug/t,
Ir{ 8 -2078 :ug/T,
M 8-6e0e ug/L
M 8 .7553 ug/l'
M 9.0023 vg/I'
M 9.3L89 ug/T.
M 10.059 ug/T,
M: Roeult !v:ls rncasured agalnst nearoot internal stsrderd esmrning a rc$ponsc fe<tor of 1.
STL Denver 65
Iot,-Baup1e *., - 3
Date Saq)Ied---3
Prep Datg------3
Prep Batch #- - - :
Dll"ution Fact'or:
IIRA Corgrcration
C1teu,t Saryrl.e ID: gHB-3-O9o1O5
Gellns Samivolatf"lee
Ilork Order #- - -: HlruRIvIlAL
Date ReceLved- - i A9 / 02/ Os
Ana-lysis Date- - I 09/ 13/05
.ena-Iygig Tirne-. ! 22227
liletbod- - - - - - - - - r g[1I845 827Oe
l.iatri-x- -,, ! ? . - - r GWD5r020230-005
os / oUos 13 :37
ae/07/os
s2s0435
1
PARAMETER RESIIIJT
REPORTING
T,IMIT T]NITS
Pentachlorophenol
SURROGATE
ND
PERCEMT
RECOT/ERY
4. O tugl["
RECO\IERY
tJIMIT9
(39 116)(zz L0e)(zs L26)(aa 114)(37 1,0 6 )
( rz L42l
2 - Fluoroblphenyl
2 - Fluorophenol
2 ,4 ,6-Tribromophenol
Nitrobenzene-d5
Phenol-d5
Terl>henyl-d14
rUIts(S}:
66
L9 *
22*
74
4.2 *
28
+ Surrogete recovcry is outside st td control lin:its.
STL Denver
IIRS CorTloration
C1ient Saqfle ID: 8HB-3-O9O1O5
ccfiis Senirrol-atil.es
Iot-Saryll-e *- - -:
Date Barylled.---3
hep llatgo.----3
Prep Batch *- - - l
DL].ution Factot:
0-005 llork Order *- . -:
13:37 Date Receirred- - i
Analygis Date- - 3
enal.yalo Time. . 3
lfetlod--o,-...-3
Hinmlvl2AI(
oe/02/os
ae / 2L/ os
22 t36
srr846 827 AC
REPORTING
IrI}'IIT UNITS
uatrix-------,-3 Gv[D5I 02023
oe l o1los
ae/L4/os
s2s7544
l-
PARAMETER RESUI,T
I{D
I$D
IrD
(Cont,inued on
Acenaphthene
Acenaphthylene
Acet,ophenone
2 - Ace tyl amLnof luorene
4 -Aminobiphenyl
Aniline
Arrthracene
Ararnite
Benzidine
Benzo (a) anthraeerae
Benzo (b) fluoranthene
Benzo (k) f luoranthene
Benzolc acid
Benzo (ghi) perylene
Benzo (a) pyrene
eenzyl alcohol
bis (z-Chloroethoxy)
mettrane
bie (z -cfrtoroethyl ) -
ether
bi g (z -Chloroieopropyl )
ether
b1s (z-Ethylhercyl)
phthalate
4 -Brornophenyl phenyl
ether
Buty1 benzyl phthalate
Carbazole
4 -Chloroanill-ne
Chlorobenzilate
4 - Chloro - 3 - methylphenol
2 -Chloronaphthalene
2 -Chlorophenol
4-ehlorophenyl phenyl
ether
Chrysene
Diallate
nibenz (a, h) anthracene
IUD
ND
ND
}UD
ND
ND
ND
ND
ND
l[D
ND
ND
ND
I{D
DTD
ND
}TD
L0
t0
10
100
50
10
L0
20
100
10
10
10
50
10
L0
1-O
10
10
1-O
10
10
10
LO
Lo
1_0
1-0
10
10
1-0
10
20
1,0
next page)
vg/L
ug/n
ug/t'
ug/r'
lug/L
:ug/T'
vg /r'
ug/t
us/r,
Lrg/L
ug/L
:ug/v'
ug/r,
:ug/I'
ug/t'
:ug/T'
ug/r,
ug/r,
:ug/t'
ug /r'
ug /T)
:us/r,
:ug/r'
ug/t
ug/t
ug /r'
ug/r,
ug/t'
ug/L
us/L
uglt
us/L
ND
IID
ND
IUD
ITD
ND
ND
ND
STL Denver 58
Iot-Saryl1e f,- - - 3
PARAMETER
IIRE Corgnration
CII-ent 8aryll.e [): SHB-3-O9O1O5
@clus aemirrolatLles
D5IO2O23O-OO5 llork Order fi- - - ! H{IVRIvI2AK
REST,IJT
REPORTTNG
IJIMIT
Irratsri;r- - - - , . - - - ! GW
TTNITS -.....ug /r'
ug/t
ug/t
ug/r,
ug/r'
ug/r'
ug/t
rtg / T'
:ug/r,
vg/\'
ug/r,
us/L
ug/T'
lu'g/L
ug/r,
rtg /T,
vg /r'
ug/T.
ug /T'
ug/T'
:ug/t,
:ug/t'
lug/T'
:og/T'
ug/t
ug/1,
ug/T'
lug/T'
us /T,
trg /T'
lug/r'
:ug/r,
ug/t'
ug/T'
ug/t,
:ug/r'
uglt
ug/1,
ug/r,
Dibenzofura-n
Di-n-buty} phthalate
3, 3 ' -DLchlorobenzidine
2 ,A-Dichlorophenol
2 , 6 -Dichlorophenol
nl,ethyl phthalate
DJ.methoate
7 ,a2-Dimethylbenz (a) -
anthraeene
3, 3 ' -Dimethylbenzidine
2 , 4-Dimethylphenol
oimeE,hyl pht,halate
1, 3 -Dinitrobenzene
4,6-Dinltro-
2 -metrhylphenol
2 , 4-Dlnl-trophenol
2 , 4.-Dlnitrotoluene
2 , 6-Dinitrotoluene
Di-n-octyl phthalate
Dl-phenylamine
L, 2 - Diphenylhydraz ine
Disulfoton
Ethy1 methaneeulfonate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachl orocyc lopenta -
diene
Hexachloroethane
HexaehJ.oropropene
fndeno ( 1 ,2 ,3 -cd) pyrene
Ieodrin
Ieoptrorone
Isosafrole
Methapyrllene
3 -MeEhylcholanthrene
Methyl metha'lesul fonate
2 -Methylnaphthalene
I -Methylnaphthalene
Me*yl parathion
2 -Methylphenol
3 -l,lethy1phenol &
4 -Methylphenol'
ND
ND
tlD
tlD
rlD
ND
ND
ND
ND
ND
IID
ND
![D
10
10
50
10
10
10
20
2A
2A
10
10
10
50
s0
10
L0
1-0
LO
t0
50
10
10
10
L0
s0
10
L00
10
10
1-O
2A
50
20
10
10
10
50
10
r0
on next page)
ND
ND
t[D
ND
ND
IUD
ND
ND
DUD
r{D
ND
t[D
ND
ND
ND
I{D
ND
TID
}TD
TID
TID
ND
ND
[rD
}ID
T{TD
(Continued o
STL Denver
IIRSI CorporatI-on
Clieut Baryr1e ID: 8IIB-3-O90105
&lW Seulrrclatil-es
DSIOZA230-OO5 Hork Order f---: H,J\RI{2AK liatr*E,--------: GWIpt*Sampl-e *- - -:
PARAMETER RESULT
REPORTTNO
LIMIT UNITS
L , 4-Naplrtrhoguj-none
L -Naphthylamlne
2 -Naphthylamine
2 -Nit,roaniline
3-Nitroaniline
4 -Nitroaniline
Nltrobenzene
2 -Nitrophenol
4 -NlLrophenol
4 -Nitroqul-no11ne-
1--oxl-de
N- Nlt rosodi -n - butylamine
N- Nit ro s odl et hyl arnine
N - Ni t, ro sodlmet hylamine
N - Nit, ro e odiphenylanine
N - Nit,rosodl - n - propyl -
amine
N - N i t roeornethyl ethyl amine
N-Ntt.rosomorpholine
N-Nitrosoplperidine
N-Nitrosopyrrolldine
5 -Nttro-o- toluidine
ParaLhl-on
Pentachlorobenzene
Pentachloroethane
P entachl oroni t robenz ene
Pentachlorophenol
Phenacetin
Ptrenanthrene
PhenoI
Phorate
2 - Picol l-ne
Pronamide
Pyrene
!yridlne
L ,2 , 4 ,5 -Tetrachloro-
benzene
2 ,3 , 4 ,6 -Tetrachloropheno]
ThionazLtt
o-ToLuidine
L ,2 , 4-Trichloro-
benzene
2 , 4 ,S-Trichloro-
phenol
ND
ND
IID
ND
ND
}UD
ND
}UD
}UD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
}UD
ND
ND
ND
ND
ND
ND
so vg/L
10 vg /I'
10 ug/I'
so uglt
50 ugll'
so ug/L
r- o ug/r,
10 :ug/L
so vg/T,
1OO :ugll'
!{D
ND
ND
ND
l{D
10
10
1_0
10
1,0
10
1,0
10
10
20
50
10
50
50
50
20
L0
L0
50
20
20
10
20
1-0
50
10
10
L0
LLg lr,
ug/T"
:ug/T'
rus/L
ug/l'
:ug/r'
rug/r,
uglt
ug/r'
ug/l'
ug/r,
vg/L
vg /r'
ug/t
ug/r,
:ug/T'
uglr,
ug/T-,
ug/L
ug/r,
ug/t'
:ug/t'
ug/T'
Lrg /r-'
LLg /r,
ug/t
ug/L
ug/L
luD
ND
ND
btD
10 ug/1,
STL Denver
(Continued on nexL page)
70
IIRS (-oqroration
C1Lent Saryr1e ID: gttB-3-O9O1o5
trltlffJ aenuirrol.atil-es
o
Iot-Saqll'e fr- - -:
PARAIVIETER
DsIO2A230-005 Ilork oder *-
RESI]IJT
ND
ND
PERCEMT
RECOVERY
L4*
2.L *
69
66
26r
56
: I{,.7\IRtr{2AI(INatri:r- - - - - - - - - 3 GTI
REPORTTNG
ITIMfT IINITS
2 , 4 , 6 -Trichloro-
phenol
O, O, O- friethylphosphoro -
thl-oate
1, 3, 5 -Trinl-trobenzene
STIRROGATE
ND 10 ug/r'
5 O ug/t'
5 O vg/T'
RECO\/ERY
IrII{ITS
(4s e2 )
(eg 98(so ee(as e1
(+e 113)
( ro lso)
2-Fluorophenol
Phenol-dF
Nl-trobenzene-d5
2 -Fluorobiphenyl
2 , 4 , F-Tribromophenol
Terphenyl-d14
rcIB(S)
=t Surrogate req)vcry Ls ousltle statml conrol lirnits,
STL Denver
Iot-Saryrl.e * = Dsr 020230 - 005
TYIA.SS SPECTROMETENIONTA SYSTEM
PAXAMETER
Unknown
Unknown
Cyclohexane
Butane , 2 -methoxy - 2 -methyl -
Unlrrrown
Unknown
UnJcrrown
Unknown
Urrknown
Unkrrown
Unlcrrown
Unkrrown
Urrknown
Unknown
Unknown
Phenol , 2-fluoro-c -nl-tro-
Unknown
Unknown
Unknown
Unknown
Unknowrr
Urrknown
Unknorrrn
Unknown
Phenol, 2, 6-dLbromo-4.nitro-
rsrE (s) :
URg Cor1pr:atim,
sf,B-3-()90r_O5
GC/HS seutrrol.atLl-ee
Ilork Order *: H'J\I'RM2AK
(t'lsos ) tmrtaurfElrY IDEMTTFTED
EgTII,IATED
eAS # RESULT
0-00-0
20 ir
5.5 iI
26J
140 J
13 ir
5.3 LT
40 .I
5.5 \f
LZ .T
5.4 .J
7.7.f
2L ,J
20J
1-3 \T
5-2 J
5.4 tJ
46 ,.f
7-L tl
3.8 J
4.8 ir
L2J
27 'J9.1 ir
5.O .T
14J99 -28 -s
llatri-x: GW
COMPOIINDS
RETEMTION
TTME UNITS
M 2 -A}LB ug/L
M 2.1341- ug/t,
M 2.2891 ug/I'
M 2.3593 ug/f'
t{ 3.5135 ug/T'
M 3 .5 952 tuig/L
M 4.LL23 ug/n
M 4.3949 vg/T'
M 4 .5453 rtg/L
M 5.1709 ug/T'
M 5,529L ug/I'
M s-gs68 vg/L,
IvI 6.7952 vg/I'
M 6-855 Lrg/I'
rvt 6 -9779 ug/t
M 7 . LL69 ug /r,
M 7 .33 61 trg /I'
M ? -44 84 vg /I"
M 7 .7 592 ug /I'
M 8.213 wg/T'
M 8 .2 77L rug/|,
M 8 .72A9 vg/T,
M 8 -7743 :ug/L
M 8.9935 vg/L
M 9.2876 :ug/T,
110 -82-7
994-05-8
M: Rcsttlt was moosured against nearest intcrorl gedrrd assuming a rc.sponse factor of l.
Denver 72
URE Corporation
Cl.ient Saqrl-e ID: gIlB-7-o9O1O5
cc/Idg Bemlvol.atil-es
Iot-8aryll-e *- - -:
Da.te Saryll.ed---!
Prep Date.--.--!
Prep Batc.h *- - -:
Dl-lution Firctor:
D5rA20230-006
a9 / 0]'/os L4 -.2O
oe/a6/os
5249103
1
Hork Order S. - - !
Date neceirred. . l
nnalyale llate- - r
ana.Iysis Time. - 3
Itlgthod-,,,.,.,.I
RESUI-,T
HiIvRVlAW
oe/a2/as
oe / 1olos
02 :49
sI{84 6 827 0C
REPORTTNG
IJIMIT UNTTS
Itatrlx-oD,!!.-!: GhI
PARAMETER
Acenaptrthene
Acenaphthylene
AceEophenone
2 -Acet yl amlnof luorene
4 -Amtnoblphenyl
Anlll-ne
Anthracene
Aramite
Benzldlne
Benzo (a) anthracene
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzoic aci-d
Benzo (ghi ) peqflene
Benzo (a) pyrene
Benzy1 aJ-cohol
bis (Z-Ctrloroethoxy)
methane
bis Q-Chloroethyl) -
ether
bi e (z -Chlorolaopropy1 )
ether
bis (e-uthylhexyl)
phthalate
4-Bromophenyl phenyl
ettrer
Buty1 benzyl phthalate
Carbazole
4 -Chloroanlline
Chlorobenztlate
4 - Chl oro - 3 -methylphenol
2 -Chloronaphthalene
2 -Chlorophenol
4-Chloropheny1 phenyl
eLher
Chrysene
Dlallat,e
Dibenz (a, h) anthracene
ND
ND
ND
ND
ND
ND
trD
ND
ND
IUD
ND
ND
ND
ND
ND
ND
ND
}TD
![D
I{D
(Contlnued
10
10
1_O
100
50
L0
L0
2A
100
I-0
10
10
so
10
L0
10
1_0
10
L0
10
10
10
10
10
10
10
10
10
10
1,0
20
10
on next page)
ug/L
ug /r,
lug/T'
trg /T'
rug/I'
uglT'
ug/r,
ug /r'
:ug/T'
trg /r,
us lT,
ug/t
LLg /T,
ug/T'
vg/r'
ug/r,
ug/L
ug/T'
ug /T'
vg /r'
ug/t
ug lt
ug/r,
ug/t,
ug/L
ug/r,
ug/T'
ug/r-,
ug/L
ug/r,
ug/L
us/L
ND
ND
ND
IUD
IUD
t[D
ITD
!ilD
STL Denver
Iot-Saryl1e #- - - l
PARAMETER
URS CorporatLon
C1ient Saryr1e ID: gllB-7-O9O1O5
gtr,lns Semivol.ati].es
D5f O2O23O-006 llork Order *- - - i H.IIIRVIAW
RESUITT
REPORTTNG
LII,ITT
Iiatrir ----..: GW
T'NITS
us/r,
ug /t,
lug/r'
rdg /I'
vs/T-,
us/T,
ttg /T'
ug/t
ug/r,
ug /r,
:ug/r,
ug/t
ug/r,
]ug/L
]uglL
vg /r'
ug/n
ug /t,
rtg /r,
lug/r,
ug/r.
ug/I'
lug/r'
ug/t'
us/t
:ug/T'
ug/r,
ug/t'
ruglt,
rug/r.
:ug/t,
ug /t'
ug/T'
ug/L
ug/T'
vg/T.
uslL
ug/t
:ug/T,
Dibenzof urarr
Di-n-buty} phthalate
3, 3 ' -Dl-chlorobenzidine
2 , 4-Dichlorophenol
2 , 6 -Dichlorophenol
Diet,hy1 phthalate
Dimettroate
7 ,L2*Dl-methylbenz (a) -
anthraeene
3, 3 t -Dimethylbenzidine
2 , 4-DimeLhylptrenol
DimeEhyl phthalate
1, 3 -Dinl-trobenzene
4,5 -DiniLro-
2 -met,hylphenol
2 ,4-Dini-trophenol
2 , 4-Dlnitrotoluene
2 , 6 -Dlnttrotoluene
Di-n-ocry} phthalate
Diphenylamine
L, Z-Diphenylhydraz ine
Dleulf oton
Ethyl mettraneeul fonate
Fluoranthene
Fluorene
Hexacb,lorobenzene
Hexachlorocyc 1 opent a -
diene
Hexaehloroethane
Hexachloropropene
Indeno (1 ,2 ,3 -cd) pyrene
fsodrLn
fsophorone
fsosafrole
Methapyrilene
3 -Methylcholanthrene
Methyl methanesulfonate
2 -Methylnaphthalene
1- -Methylnaphthalene
Methvl parathion
2-Methy1pheno1
3 -MeEhylphenol &
4-Methylphenol
IID
IID
ISD
l[D
IUD
IUD
}TD
IID
ND
ND
ND
ND
![D
ND
(Contlnued on next
ND
ND
ND
I{D
ND
ND
ND
ND
ND
ISD
IID
t[D
ND
10
1_O
50
1-0
10
10
20
20
2A
10
L0
1,0
50
50
r.0
10
10
10
10
50
10
10
1"0
1-0
50
L0
L00
10
1-0
10
20
50
20
10
1_0
10
s0
10
L0
page)
ND
TID
ND
ND
ND
ND
IID
IUD
ND
ND
ND
ND
STL Denver
IIRS Corporation
Client Sary>Ie rD: grtB-7-o9or-o5
Gf,,lu9 Seutivol.atl-leo
Dsf 02A230-006 trork Order f - - -: H,J\IRVI-AW liatri:r----.!,--3 GWIot-$arylle *- -. :
PARAI'IETER RESTIIJT
ND
(Continued on
REPORTING
LIMIT ITNITS
L , A-Naphthoguinone
1-Naphthylaml-ne
2-NaphthytamLne
2-Nit,roaniline
3 -Nitroaniline
4 -Nitroanlline
Nitrobenzene
2 -Nitrophenol
4 -Nltrophenol
4 -NLtroquinoline-
1-oxLde
N - Ni t roeodi - n- buEy1 amine
N- NL t ro sodt et hyl amine
N- N I t rosod ime thyl arnine
N - Nl t rosodlphenyl amine
N-Ntt rosodi -n-propyl -
aml-ne
N- Ni t, ro s omethyJ. ethyl amine
N-Nitrosomorpholine
N - NL t rosopipe rJ- dl-ne
N - Nl- t ros opyrrol ldine
5 -Nitro-o-toluidine
Parathion
Pentachloroberrzene
Pentaclrloroethane
Pentachl oroni t, robenz ene
Pent,actrlorophenol
Phenacetin
Phenanthrene
PhenoI
Phorat,e
2-PLcoline
Pronamide
Pyrene
qgrtdine
L,2,4 ,5-Tetrachloro-
benzene
2, 3, 4, 6 -Tetrachlorophenol
Thionazin
o-To1uidlne
L ,2 t 4-Trichloro-
benzene
2 ,4, 5-Trichloro-
phenol
ND
![D
IID
![D
ND
tlD
ND
TUD
ND
t[D
ND
ND
ND
ND
ND
ND
ND
ND
ND
llD
ND
ND
ND
l{D
DID
}ID
IID
ND
ruD
50 ug/t'
r,o ug/t
1-0 rtg/I'
50 ug/I'
5 O uglr.
s 0 vg /T-,
10 ug/L
10 ug /t'
so :ug/T,
100 vg/r,
IUD
ND
ND
}UD
ND
10
1-0
1-0
10
1-0
10
10
10
10
2A
50
10
50
50
50
20
10
10
50
20
2A
10
2A
L0
50
10
10
10
1.0
next page)
ug/t'
:ug/r,
:ug/T'
rrg /r,
:ug/T'
ug/r,
ug/r,
ug /t'
ug/T,
vg /r'
ug/r,
us/t
:ug/t,
ug/L
ug/r,
ug/T'
ug /r,
ug /T'
]u,g/L
us /T,
ug /T'
ug /r,
:ug/r.
]ug/L
ug /r,
r:.g /r.,
us/L
vg /r'
ug/t
DID
ND
ND
IID
STL Denver
Iot-Saqlk= *- - -:
PARAI{ETER
IIRS Corlrcration
Cllent Sary)I.e ID: SHB-7-o9O1o5
Gf,.l$g Safiro1atlleg
Dsf O2O23A - 006 llork Order *- - -: HinfRVlAIt[
REPORTING
LfMfTREgt,LT
Hatri:r- - - - - - - - - : GSI
TTNITg
ug/t
ug/u
us/T,
2,4,6-Trl-chloro-
phenol
o, O, O- Triethylphosphoro-
thioat,e
1, 3, s-Trinitrobenzene
SIIRROGATE
IrD
PERCEI{TT
RECOVERY
10
s0
s0
RECO\IERY
IJIMITS
(+s e2
(eg eB
(so ee
(aE eL
(ee 113
(ro 1so
2-Fluoropheno1
Phenol -d5
Nltrobenzene-d5
2 -Fluorobiphenyl
2, 4, 6 -Tribromoplrenol
rerphenyl-d14
79
BL
79
77
92
81
)
)
)
)
)
)
STL Denver
Iot-sary)Ie *: D5I020230-006
I.TASS SpECTROMETER/DATA SYSTEM
PARAMBTER
UR.s @rporation
gtIB-7-O90105
tr'lHg Eenrhrolatl.I.ee
Ilork Order #: HiIVRV1AW
(t{sps) rrureuvEr,Y TDENTTFTED
l{atri:r: C}W
CAS #
EgTII,IATED
RESUIIT
EOMPOT,NDS
RETENTTON
TTI.{E
UnJ<rrown
C)rclohexane
Butane, 2 -methoxy- 2 -methyJ.-
Unknown
rwfE(s):
110 -82-7
994-0s-8
UNTTS
8 .2 ,J M 2 . A867 ug/t"
23 .T M 2.23L7 ug/f,
54 ,J M 2.9058 ug/t,
29 ,J M 2.3981 ug/t'
M: Reult weo measured agalnst nelre.$ intcrnal standard assrrmiry s rospofise factor of l.
STL Denver
Iot-Saryfie #-.. !
Ilate Saryr1ed---3
kgp Date,,,---l
Prep Batch #, - - 3
DLlutf"on Factor:
IrRg Corgnration
Cl.ieut Saryfle ID: gIsB-7-O9O1os
oe/HS Senirro1ati]-es
Ifork Order *---: HfifRVlA)(
Date Recefured - - : 09 / OZ / AS
Aual.ysis Date- - 3 09 / L3 / Os
Ana.I.ysis Time- - : 22 247
liatrir- - - - - o . - . E GTIDsr 02023 0- O05
09 / o1los t4 zza
ae/07/os
52s043 5
1
lletlodr - . -, ., - - 3 SW846 827Oe
PARAMETER RESI ITT
ND
PERCBWT
RECO\IERY
REPORTTNGI
I,IIVIIT UNITS
4 . 0 ug/r,
RECO\IERY
I,IMITS
(gg 116)(zz lo9 )(28 L26l
(gs 11-4)(tz r.06 )(tt L42l
(*l 1,421
Pentaehlorophenol
SITRROGATE
2 - Fluoroblphenyl
2 - Fluorophenol
2,4r5-Tribromophenol
Nitrobenzene-d5
Phenol -d5
Terphenyl -d14
L,[-Dioxane-dB
58
74
74
78
69
60
STL Denver 78
Lot-Sary)I-e *- - -:
Ilate Ssry)I-ed---3
PARAMETER
IIRE CorgnratLon
Cl-ieut Saryfle ID: SIIB-91O-O9O1O5
I'ICIEAI, Uetal-e
D5IO2A230-002
09 / 0r/os 07 : 00 rlate Becelrred- . i 0g / ozl os
RESUI,T
REPORTING
TIMIT T]NITS METHOD
PREPARATION. WORK
ANATTYSIS DATE ORDER #
Prgp Bat,eh *- - -:
Cadmlum
SelenLum
52495L6
ND
IilD
0.020
DllutLon
0.040
Dilut,ion
mg/L
Factor:20
ms/r.r
Factor:20
0. o50 nrg/L
Dl-lutLon Fastror; 5
1- O mg/r,
Dilutlon Faetor: 1O
0.075 mg/L
Di].ution Factor: 5
o - osO rytfi,
Dllution factor: 5
2 -O rg,IT'
Pllutl"on Fastorr 10
0,050 rW/T'
Dilutioa Faetor: 5
0. 050 ng/t'
DLlut,Lon Factor: 5
1.0 rflg/L
Dllutlon Factror: 1O
30 ry,lt
DLluElon Eactor: 10
2 -o rylt,
Dl,IutLon FacBor: 1O
50 wlI"l
Dilutlon Faetorl 10
9w846
enalyeie
swB4 5
Analysl-e
6020
Tim6, -: A7:25
5020
Ttme. . : O7;25
sw845 60L08
Jlna1.ysie Tirna- - : 2O : 4O
sw845 50108
Analyeis Time..: L7:42
sw846 50108
itnalyaie Time - - : 2A : 4A
9H846 50tOB
Arralyeis Tlme. - : 20 :4O
srr846 60108
nnalyeie Time.. c a7:42
sv[846 60108
Ana1ysI-r Tlme. . : 2O :{O
gr{846 60108
Analysls Tlme..: 2O:4O
9w846 50108
Analysis Tl.me. . : L7'.42
sr845 60r-08
Analysie Time. . : L7 t42
sH846 60108
Analyel-s TLme., : L7 : 12
sH846 50r.OB
Analyrla fLme.-: L7:$2
next page)
oe / 15 - 09 / 23 / os H.TVQA]-A4
ae lr.s- oe /zt / os HiruQAlAs
Prep Batch.
Silver
Alumlnum
ArsenLc
Bariun
Calcirm
Chromium
Copper
Iron
Pota^aeirm
l,Iagmeeitul
Sodlirm
*. -.: 52496L7
IID
ND
ND
o -{3
15(}0
ND
ND
ND
r_800
1200 ir
3soo0
ae/15-ae/L6/05
aehs-aelLe/as
ae/1s-oe/L6 los
ae f]-s-ae 116los
oell.s-aelLgf ss
aells-ae/LG/os
oe/r.s-oe/L6/as
aelrs-aelre/os
oe/1s-oe ltglos
oelr.s -oell:elas
H'WQALAII
HJVQALATT
H.JVOAlAKo
II.rVQAIAL
TIJIIOA]-L\r
HJVQAl-AM
H.I/QAl-AIT
Hlr\IQAlAW
E,:rIIOAAAX
EII\IOAI-,AO
STL Denver
(Continued on
09 I Ls-ae I Ls I as ETvOALAL
Iot-Saqll.e fi- - -:
URII Corporation
Cl.ient Saryr1e fI): SHB-91O-O9O1O5
lt0EAL lhta-I.s
D5I020230-002 triatri-x- - - - - - - - , : GIil
PREPARJATION- WORK
AI\TALYSIS DAIE ORDER #
REPORTING
PARAIT{ETER RESI}LT LIMIT UNITS MEIIIOD
Nidcel.
Iread
Vanadium
Zi^nc
Zirconium
Prep BatcII *- -.l
Mercury
o-o32 B
ND
ND
o-o2{ B
ND
525834 I
tsD
O-2O ug,II,;
PlluElon Factor: 5
0.0L5 mg/t'
ntlution Factor: 5
0 . 050 ng/T'
Dilution Factor: 5
O - 10 rylt,
nLluEJ.on f,'actor: 5
0.15 ng/t
Dilution FaeLor: I"O
0.00020 mg/1,
Dilutlon Fact,or: 1
oe l Ls-ae lr.a I as
oe/ L5- ae/L6/os
ae/1s-oe/LG/os
oel 1s- oe lt6l os
oe/r.s-oe/Le/os
E'il7OA]lllP
HWQAlAQ
HiTQATAR
ETVOAIAT
HJTTQALA2
srr846 60108
Aualyeie TLme, -: 20:{0
sril845 6010B
Arralysl-s Time. . : 2O :4O
sw845 60108
AnalyaLe Tfune-.: 20:40
srl845 501(}8
Analysie Timc..: 20:40
sw846 6010B
Analysie TLme. . : 7,7 :42
sw846 74't OA A9 / Le / Os
Analyeie Time,.: 16;38
HJ\/QAl-AU
o
rplrts (8) :
I Metbul blank contamination. Thc associated mcrhod btant contains the targct anatytc at e rc?ortable lcvel.
B Estirnatcd result. Resrlt is less than RL.
STL Denver
Iot-ga4p1e *- - - 3
Ilate Sary[ed,---3
PARAMETER
UnS Corporation
Clieut saryfie ID: 8HB-9-O9OI"O5
AUEAIJ }EtA.[B
D5I420230-O03
a9 / 01,/05 1o :55 Date Receirred- - i 09 / azl os
RESIITT
REPORTING
LTMIT UNITS METHOD
PREPARATTON- WORK
AI{IAt'YSTS DATE ORDER #
hrep B&tch
Sl-Iver
Aluminurn
Arsenic
Barirm
Calcium
Chroml-um
Copper
Iron
Fotassirm
Ilagn'esium
Eod.lum
*- - -: 52496L7
luD
ND
o-23
f--6
2100
ND
tilD
![D
6800
92OO rT
?7000
0.L0
0. 10
Dl-lution
1_.0
pLlutLon
o-15
Dl"Iution
o-10
Dilutlon
2-O
ul,lutlon
0.l-0
olluElon
o.1"0
Dllubion
1.0
Dllutiou
60
DLlutl-ou
2-O
nL1utlon
kep Batch *-. -:
Cadmium
Seleafum
52495L6
ND
o- 09{ B
DiluEion Factor: 10O
O-2o ry,IL
Dilution Factor: 100
ntg /T'
mglL
Factror: 10
mg/t
Factor: LO
ryln
Factor: 1O
rglr.
Factor: 10
rog,lT'
Factor: LO
mg /r'
Faetor:1,O
mg/t'
Factor: 10
rflg/L
E'actor:10
Wln
Factor: 20
ng,lr'
Factor: 10
sw8{ 5
Analye.ls
9II845
Analysj-e
5020
Timc. . : 12;01
5020
Tima--: 12:01
sur845 50L08
nnalyeLe TLme..: 17:53
sw845 50108
Analyele Tl,rae. , ; L? 247
str845 50108
eual.yslg Tlme--: 17:53
srr845 50108
Analysis Ti$e.,: 17;53
sr58{5 50108
Arral.ysLa TLme- . : L7 t47
sw846 50108
Arralyelo Tl-me. . : 17 r 53
sw846 60108
Analyala Time..: 17:53
sw846 60108
Arralye1e Tlme. . : L7 :47
sD5846 60108
nnalysls TLme- . : 12: o5
sH846 50108
Analygis Tl.me" . : L'l 247
9w846 60108
Analyols TLmG..: t2:06
next page)
oe / ls- ae /23 / os HuveslAF
oe lls- 09 I 23 I as E'rrQsxLG
ae/ls-ae/Le/os
oe/r.s-ae/Le/os
H.nIQs1AU
H;ruQs1AV
100 wlr,
Dllution Factor r 2O
oelr-s-oellglas tr.l ,*rL
09 I ts - 09 I tg I os HrrrQs r-,Lx
og /ts-oelr:g I os
oe/1s-oe/Le/os
ae / 1s- oe /Le / as
oe/1s-oe/Le/os
oel I.s- aelzol os
oe l r-s- oe lr.e l os
HilIAsilA7
HinIQs1AO
HiruQs1A1
1rwQ51A8
H.rvQsLAg
EnrQsilAA
STL Denver
(Continued on
oel ls- oe lzolos E^TIrQsrLe
fot-garple t., - i D5f02A23O-003
PARAMETER RESTIIJT
Nr.clce1 o-o2g B
ND
ND
ND
ND
Fnep Batcfi
Ivlercury
N€rrts (8) :
f,- - -: 5262486
ND
t RS Corporatl-on
Cl.l-ent 8aryfle ID: S'f,8-9-O9o1o5
TUEAL HetAI.S
REPORTING
LIMTT I]NITS }i[ETIIOD
fhtri-x--.-----.: GXI
PREPARATION- T{ORK
AI{AIJYSIS DATE ORDER #
vanadium
Zinc
Zirconium
o - 40 trylt"
Dllut,lon Eactor; 10
0.030 fi:q,/T'
DllutLou Factor: 10
o.1O mg/L
Dllutlou Factor: 10
0.2O mg/L
Dl}utLon Factor: 1O
O . 15 mg/t'
Dilution Factor: I"0
0.0020 r*g/I'
Dl-lutlon. Factor: 10
sw8{6 60108
AnalyeJ.e Time. . : 17 : 53
sw846 50108
Analyala Timc--: 17:53
sw846 60108
Analyeia Time..: 17:53
sw846 50108
Analysle time..: 17:53
sw845 60108
Anal.yel-e Tl.me. . ; L7 :47
ae/Ls-oelLg/os
oells-oe/ae/os
oel 1s- ae / Le / as
oells-ae/Lelas
oeh s- oe /Le / as
EfVOs7A2
Hin/QslA3
HirfQslA4
HirvQs1A5
HirtIQslAD
sw845 747OA A9/22/OS
anal.yeie Ti:ne. . I 19 :25
HiruQs1A6
B Estirnated resrlt. Res,trh ls less rtran RL.
I Mctltod blank contaminntion. The as.cociatcd metrod blunk contains the uarget anatyrc at a reportablc levol,
STL Denver 82
f..ot-Sauple *- - -
Date Sarylled- - -
PARAMETER
URg Corporation
el-ient Sary)le tn: sHB-1o-O9O1O5
ltO|fAIr Ueta-I.s
Dsr020230-004
a9 / aL/ as 12 : 10 rlate Receiwed- , 3 09 / oz / aS
RESUIJIr
REPORTTNG
IJIMTT UNTTS METIIOD
Dtatrj:r,ao----i GW
PREPARATION- UIORK
ANAITYSIS DATE ORDER #
Prep Bat& {[- - -
Cadmtum
slel.enlum
Prep Bateh {f - - -
Silwer
AlumLnum
Areerric
Barl-um
Ca-I-cium
ChromLum
Copper
fron
Potassirtrr
l{agneeirm
Sodium
0.040 mg/t
nilution Factor: 40
O - O8O Wlt,
Dilutrion Factor: 40
sw84 6 6020
Analyeig Time.-: 12:05
grr845 5020
haalyeie Tim6-.: 12:05
sw846 60L08
Alralyeie TLme..: 20r50
sw845 60L08
Arralysio Tl-me. . : L7 :23
sr845 60108
AnalysLs TLme..; 2O:50
sn845 5(}108
Analyeie TLme..: 20:50
81846 50108
Analyeie Tlme..: L7t23
sw8{5 50108
Analysle TJ,me. . : 20: 5O
9w846 60108
Analysle Time..: 20:5O
9w846 50108
Analyaie Time..: 17:23
BII845 60I-08
Analyele Tlme..; L7:23
91846 5',0108
Analyeie Tlme..: 17:23
sH846 60108
Analysie Time. . : 17 t23
next page)
oe / J.s - a9 / 23 / os Hirveg LAtr'
oeAs- a9 |zt I os EilreerAc
52496L6
ND
o-o40 B
52495L7
ND
t[D
o-o25 B
o-41
1500
ND
ND
o-38 B
1700
1200 J
33000
o-050
Dilution
1.0
Pl,lutJ.on
o_o75
Dl-Iutlon
o-o50
Dilution
2-A
Dilutlon
o.o50
DLluELon
o.050
DlluE l.on
1-O
Dilution
30
DLlutl-on
2.O
DLlutlon
50
mg /T'
Faetor: 5
mg/r.,
Eactor: 1O
nglr,
E'actor: 5
rytlr'
Pactor: 5
rglt'
FacEor:10
mg/L'
tr'actor t 5
mg/T'
Factor: 5
nglt
Fact,or: 1O
rglt
Factsor: l-0
ng,lt,
Factor: 1O
wlr'
oe/1s-oelL6/os
oehs-ae/Le/os
H.nrQg1AU
HWQ9I-Av
Pllutlon Factor: 10
ae I Ls-oe I L6 / as rr,rvee5
09 lr.s-ae I L6 I os tr-rveer-ax
oe I Ls- oe I Le I os hrvee twt
oe/i,s-ae/L6/as
oells-oe/L6/os
oel I-s- aelLelos
oe I Ls-ae I Lel as
oel1s -oelLelos
H.r\/Qgl.AO
HflrQ9LA1_
ETIVQ9IAS
EirvQgLA9
B,ilIQ9IAA
STL Denver
(Continued on
oe / Ls- ae I Lg I as H,ilregr"ac
Iot-8aql1e *- - -:
URA Corporation
Cl-ient Saryfle ID: SWB-I-O-O9O1O5
I\UEAL ltetal8
D5I020230-004 llatrix---------E GW
PREPARATION_ WORI(
AI{AITYSTS DATE ORDER #
REPORTTNG
PARA}{ETER RESUI,T IJTMfT UNITS METHOD
Iricke]-
Iread.
Vanadirn
ZLnc
Zlrconium
o-o15 B
TUD
o-o14 B
o. o24 B
ND
O-20 ry,Il,;
Dilution Factor: 5
0.0L5 mg/L
DLlut,lon Fector: 5
O - O5O ryl['
Dl-Iutlou Factor: 5
O - 10 ry,ll'
Dilution FacEor: 5
0 . l-5 mg /T,
Dl-lutlon Factor: 10
0.00020 mg/L
Dilution Factor: 1
sH845 60108
AnalyeLs TimB..: 20:50
sv[84 5 5 0108
Analysle Tlme..: 20:50
srr846 50108
Aualyal.e Tine, . : 2O : 50
sn8{6 50108
Analysle Time..: 2O:5O
sr[845 50108
Analyeia Time..: L7:23
ae ll-s-oelL6l os
oe/Ls-oe/L6/os
oel :ts- oef L6los
oelLs-oel1:slos
ae/1s-oe/Le/os
E fVQgLArl
H.x/Qg1A3
E\TIIQ91jA{
EirvQgr-jas
HJTIQgl.AD
Prep Batclr S---3 5258348
Mercury ND
rsufB (s) :
sw846 7470a. 09 /L9 / 0s
Analyoia rime-.: 16:41
H.IIQg1A6
B Eetfunrtod resrlt. Rcstlt is Iess than RL.
J Method blank couamination. The assoclaod merhod blmk connins ilre mrga analyrc at a reporrrble level.
STL Denver
Irot-Baql1e *- -. i
Date Saryll.ed.--3
PARJAI{ETER
IIRS CorarcraEion
Cl-t-eut Ilaryrle ID: 8HB-3-O9O105
llyTAIr lhta]-s
D5rA2A230-005
09 / 01/05 13 :37 Date Received- - 3 a9 /Az/ 05
RESULT
REPORTING
IJIMTT UNITS METHOD
PREPARJATION- WORK
ANALYSIS DATE ORDER #
Prep Batch #-. -:
Cadmftn
Se].enl.um
52495 15
o -oo13 B
o-oo81 B
O - O1O rglf'
Dl,Iutlon Factor: 1O
o - O2o Wln
Dllution Faetor: 10
0.010 tng/I'
Dllutlon FacEor: L
O - 50 ry,ll,
Dilution Factor: 5
o - O15 rylt,
nj-Iutlon Paet,or: 1
O - O1O rylt
Dl1utlon Factor: 1
1-o ryln
DLlutLon Factor: 5
O.0LO mg/T'
Dilutioa Factor: 1
o - O1o ry/1,
DL1utl.on Factor; 1
O-5O rylt
Dilution Faetor: 5
15 rglT'
Dilution Faetor: 5
1.0 ryln
Dilution Faetor: 5
25 rylL
Dllutlon Faetor: 5
(Contlnued
sH8{16 5O2O
Analyale Time..: A7:57
s'II8d5 5020
Analyeie Time. . : A7 257
sw84 5 501_ 0B
Analyals TLme..: L4:?9
sH8{6 60108
Arralyeie Time- -: L'l 252
sr846 60108
Analyele Tlme..: 14:39
srr846 60108
Rnalyeig Time..: 14;39
grr845 50108
Rnalyeia Time--: L7;52
sw846 6010B
Analyaia Time..: 14:39
9H845 50108
Analyeie Tlme. . : 1{ :3 9
stn845 60108
Analyels Tlme. . : l? t52
srI845 50108
Analyele TLme..: 77:52
srr846 60108
Analysie Tirna. - : L? :52
9w845 60108
Analyels Time..: L7:52
next page)
09 I Ls- oe |z3 I os E{rvRuilar
oe f ls- oe I 23 f os HttrRuLaG
hep Bateh
Silwer
Ahminrun
Arsenic
Barium
CalcLum
Chrornl-um
Copper
Iron
Potassirm
Hagnesiru
Bodirm
*---3 52496L7
![D
o-r-7 B
o-o58
o -24
850
ND
o. o12
0-26 B
270
5{O J
5200
ae/ 15- oe/L6 las
oelLs-ae/Lglos
oelLs-oelLg.l as
oe lls-oelL6l os
oe /Ls-aelLg I os
oelIs- oe/L6/os
oef Ls-aelL6las
oelLs*oellel os
oe lLs-oel Lg los
oelLs-aelLgl as
H{I\JIRI'IIAU
H'ilTRllIA\/
HiNIRMI.AO
EilIrmtljar-
E,I\IRTTLLS
E.rvRrrua9
II,ilIfRI&AA
rc
IIJTIRITLAX
ae / Ls- oe I Lg I os ErvRrrlAe
o
STL Denver
Iot-Sampl.e S- - -:
IIRA @rporatl-on
Cl.ient Saqrl.e II): SHB-3-O9O1O5
T€If,AL tr{etal s
Dsr020230-005
REPORTING PREPAR,ATTON-
AI{ALYSIS DATE
hIORK
ORDER #PARAIITETER RESUL,T ITIMIT UNfTS METHOD
NLcke].
Lead
Vanaillum
ZInc
Zlrc<rnium
Prep Batch *- - -:
Mercurlr
IUTB (8} :
O - O4O W/1,
DL1utlon FacEor: 1
O. O03O mg/L
Dilution Factor: l-
O-O1O rylr
Dllutlon FacEor: 1
o -O20 ryln
Dilut.Lon Faetor: 1
o. oz5 ry,lt,
Dilutioa Fact,or: 5
o - 00020 mg/L
Dilution Faetor: L
9w845 60108
Analyeie Tl-me. . : 14 : 39
sw846 50108
Analyala TimB..: 1{:39
sIn845 60108
Analygis Timc-.: 14:39
sH845 501(}8
Anal.yeie Time--: 14:39
sH845 50108
Anal-yala Tirne. - : L7 :52
ae lLs- oe l Ls I os
ae/ls-ae/L6/os
oe ll-s-oe lL6l os
oe lLs-oelL6l os
oelLs-ae llg I os
o- o35 B
ND
o-o15
o. or_g B
0-06g B
s2583 4 8
ND
E,rITRIIUA2
HJVBI{].A3
EiTIIRIIIA4
ILfVRHIA5
IIrI.I.iLAD
sw846 747oA O,/Le(OS
Arralyele Tlme. . : t 6 ; rl5
HJVRIU].AS
B Estinrated recnlt. Rwuh is lcss rhan RL.
I Method blenk eonntninadon. The assoclated rrrethod blenk conhins the target analyte et a reponablc tevel.
STL Denver 85
IrRS Corporation
C1ient 8aq>1e ID: 8HB-7-O9O1O5
TOltrAL ltleta1s
Dsr02a230-006
a9 / 01/05 L4 rza Date Received- . 3 og I 02/ oS
REPORTING
LIMTT UNITS T\4ETHOD
!Iatri:r.. - . - - - - r G"II
PREPARJATION. }TORK
AIitAfJYSfS DATB ORDER *
O
Iot-Sary>Ie *. -. !
Datse Saryrled,. - -:
PARAMETER RESULT
Prep Bat,ch {lL- -.
Cadmlurn
Se]-enium
: 52496'16
ND
o-oo27 B
0.0050 nq/t'
Dilut,lon FacEor: 5
O - O1O ryln
Dllution Factor: 5
0. ol-o mgll
Dllutlon FacE,or: 1
. 0.10 mg/I'
Dl.lutiou Factor: 1
o. o15 ryln
Pi]"utlon Factor: l-
0.010 ry,IT'
Dllutl-ou Factor: 1
o - 20 ryll,
Dilrrtion Fact,or: L
O - O1O mg/I,
Di]-ut'lon Factor; 1
o - o1o mg/L
Dilut,ion Factor: L
O - 10 ryll'
Dl-Iution Factror: 1
3-O ry,II,,
PllutLon Factor: 1
O - 20 rytlT,
Dilution Factor: L
5-O ryl["
Dilution FacEor: 1
(Continued
Prep Batch
Sl-lver
AlumLnum
Argenic
garirm
Ca].cirm
Chromium
Copper
fron
Potassiurn
l.Iaguesirm
Sodium
#- -. i 52496L7
ND
ND
o-o83
o-r.3
1_30
ND
ND
o-o50 B
300
57(} J
2900
oe/ls-ae/L6/as
oe/1s-oe/L6/os
os ll.s-oe/Lel os
oe lyrs-ae lL6l os
oel:.s -oe lLsl os
ae/1s-ae/L6/as
aelrs-oe/L6/os
oe lLs*oelL6, I os
oe lls-ae lL6/as
oel 1s- oelL6las
HiruRV1A5
H.T\IRVLAT
HiNIR\rIAJ
H{NIRVIAA
H,JVRVlAC
ILN'R\rTAK
EJIIR\TITAII
H,JVRII"I-BH
sw846 6020
Aaalyelo Tlme..; 08;01
srr846 6A20
Irralyeia Time. . : 08 : O1
sw84 5 6 0108
Analysie Time- -: L4:43
sw845 50108
Analysie Tl-me. - : 17 : 19
arr845 6(}1_08
enalygls Tlme--: 14:43
9H845 50108
Aoalyeie Tirne. . : 1{ :43
g11846 60108
Analyela Tlme- - : 17: I"9
9w846 50108
Analysls Tlloo. . ; 1{ ;43
ghr84 5 5 01-OB
AnalysLs Tl-me. . : 14 :43
5'H945 50108
nualysls Tlme,.: L7zL9
gDI846 50108
Analyaie Time..: 17;19
8H846 50r_OB
Analysls Tlme. .: L7:19
9H846 60108
Analyeie Time..: L7;L9
next page)
a9 / 1s - as / zt / os HJlrRvlAR
oe I Ls-og | zslos g,ilIR\rurr
rc
ILTI'R\NA9
STL Denver
o9l 1s - ag | rc I os ErnlRvr-arr
IIR^S Corgrcration
C1Lent Sarylle ID: 8IIB-7-O9O1O5
IOlf,AL lletar g
fot,-8aryll.e f; - - - : D5I02 O23O- 006
R"EPORTING
PARNIIETER RESUTJT IJIMIT UNTTS METHOD
Hatri-x ) - ) - - - - - -: ClIt[
PREPARATION. WORK
AITATJYSIS DATE ORDER #fcl-cfEel o-oo19 B o.o4o ry,ll, sEEr[6 60108 oglas-ogl,Lelos EryErrlLar]
DLlutlou Factor: 1 AltalysJ-s Ttun6..: t,t:43
Iread IUD G o. O07O tw/t sw846 60108 Og/tS-Og/tS/OS H\rVRVleE
Dilution PBctor: X Aaalyaia Tinre..: 1t:{3
0. o1o nq/t 9w846 5o1oB og/ts-og/ta/os H.Jr/RV1AF
Dllutl@ Factor: 1 ABalyolo *fine..r 1{:113
o. o2o mg/t sw84d 60108 og/ts-og/te /os Hir\rRvr.Ac
Dilutio Faetor: 1 Anelysis Ti$e..: 1{:rl3
0,01s ,rq/r, 9w846 6010B og/ts-og/rc/os rrJ\rRvlAp
Dilutlon Factor: 1 lBalyeLe Time..: 1?:19
Prep Batch *- - -: 5258348
Mercury ND 0.00020 rq/t, sw846 7470A og/ts/os g,nrRvI-AH
DLlution Faetor! 1 .Inalyala ?ine..: 15:rl8
rctB_(8) : _ -..B Egtimtcd rsult" R@tr is lcsEthmRl.
J Mceod blant oltminaioo, Iho essocirbd mc6od blrnk contains thE tarSa anrlyre rl ! roporrrbb level.
G Elmrcd reporting limlr Thc rcporting limh Is clerratort duc to I,trtlir intcrfcrerrce,
Vanadlum ND
Zinc ND
Ztrconium ND
STL Denver BB
Iot-Saryll-e il. - - !
Date gaqiled.--3
PARAMETER
IIRSi Corporation
C1ient Aaryrl.e ID: SIIB-91O-O9O1O5
General. Clrcnistry
Ilork Order *- - -: H.r1IQA
Date Received- - r 09 / 02 / A5
tfatri-x- , - - - - - - - : GsI
PREPARATION_ PREP
ANATYSTS DATE BATCH #
Dsr020230-002
09 / ollos or : oo
RESUIJT RIr IINfTS IvIETHOD
8-7 o - 10 IIo [Inite 511846pH
emnia a^s 15
Ch-I-orlde
F1 roride
Nitrat,e
NitraEe-NitrLte
SuIfatse
Tota1 Qranide
I5CTTE (S) :
ot lutton Factor: 1
O-38 0-L0 ryll,r
Dilution Factor: L
ssooo 0 l"ooo ry/L
ollutLon FacLor: 40o
o-1-4 .T O-1O ryll,
Dilution Faetor; L
DUD 0.10 nrg/L
DiluEion Factor: 1
ND O.1O wrg/L
Dilution Factor: 1
t3ooo J, e zsoo wlT,
Dllution Factor; 5OO
O - OO28 B O. O1O ry,lT,
Dilution Factor: 1
Anal-yeLa
TiCAITTS
Analyel-e
HcIilH
Analysis
UMHtr
analysLe
},ICAT{W
Analyeis
MCAIIM
Analysia
tilc[str
erralyels
s'tr846
Analyele
904()8
Tl-ma. . :
350-1
Tlme. , :
325 -2
Timg, . :
3{O-2
TLme-. :
353.2
Time-.:
353.2
Timc. . :
375-4
oe l ozl os
13:35
oe lza / as
17: OO
oeloslos
1O: 0O
oe / oel os
I"1:3O
ae/a2/05
12: OO
oe/za/os
15: OO
5245546
5265424
s252250.
525254(t
5265577
s26srl
5249585oe/06las
Tlme- . : 1{:30
9O1OB I gO12A 09 lL[-oe lLs I os s2s7{,27
TLme..: 12:3O
RL Reponing Umlt
a Eovatod roporting limit. The roporting lirnit is elevated duo to high analyre levets-
J Mcthod blsnk contamlnatlon. Tho associatod merhod blank mntainc the targct anallnc ar a rcponable lcvel.
B Estlmated resuh. Re$lr is teoe thrn RL.
STL Denver
Iot-Saql1e *- - -:
Ilate Saryll.ed,-.-I
PARAMETER
t Rg Corlrcration
C1ieut 8aryt1e ID: SI|B-9-O9O1O5
cenera} Chenistry
Ilork Order *.-.: HiI\IQs
rlate Receirred- . 3 09 / 02 / 05
T]NITS IvIETHOD
llatri:r--..--.--: GW
PREPARATION- PREP
AIVAI,YSIS DATE BATCH #
Dsr020230-003
09 / 01,/ os r.o:55
RESULT
pE
AmnLa aB II
Ch].oride
Fl.uorlde
ttitratre
7.O
850 2-5 Ug,ltl
oilutrlon Factor z 25
20oooo Ct {ooo ryll,
Pllutlon Factor: 1500
A -26 .f O - 10 try,lt'
Di1utlon Factor: L
32OO O-1o ryll-
DLlutLon Factor: 1
3200 0 100 ryrlt,
oLluEl.on Factor: 10OO
55oO J,Q 12OO ry/t'
Pllutj.ou E'actor: 25O
O-O37 O-O1O r{f/f-.
niluEl.on Factor: 1
sH845 eo4oB 09/ o2l os s24ss{5
Analyel-s TLme. . : 13 : 38
INCLrfir 3sO - 1 O9l?0l OS s26s424
AnalyeLa T{rne. . : 17: O0
rrcNilr 325 -2 OglOslOS 52522sO
anal-yeis Time - . : 1O: 0O
ucArwr 31ro -2 oglaglos s2s2s40
Analyel-a Tl-me - - : 11 : 3O
ucAHr 3s3 - 2 OglA2lOS s265577
Analyeig Time..: 12:0O
l.rcAffir 353 - 2 OglzOlOS 5265542
Analyeie Tl-me. - : 16 : 0O
IrciAHrr 37s -4 09106l 05 52{9585
Analyeia Time..: 14:30
B11846 9O1OB I gOI.Ztr, 09 lL1-AglLSl aS s2s-t+27
Anal-yaia Time - . : 12 r 3O
O - 10 I5o unl.te
PllutLon Factor: l-
O r{itrate-ruirrte
SrrI-fate
total Cfranide
lurE (s) :
RL Reporting Limit
a Hevatod rqorting limit. The roponiug limit ir clevatcd duo ro high analym lovels.
, Metbod blank coninminrtion. The assoclahit method blsnk contrins the nr3a anrlyre il e r€pornble lovel.
STL Denver 90
Iot-Saqll.e *- - -:
Date Saryll.ed---3
PARA},IETER
IIRS Corgrcration
C1ient Saryll.e III: SHB-1O-O9O1O5
Genera-I- Chcnistrlr
tortc Order *---: HflrQg
Date Received- . 3 A9 / A2/ Os
TINITS
llatri:c---------3 GW
PREPARATION- PREP
A}IA}YSIS DATE BATCH #
Dsra20230-004
09 / oLlos L2:LO
RESULT METHOD
PTI
Annpnia €r^g II
ChlorLde
Fl.uoride
Nitrat,e
NLtrate-Nitrlte
Suffate
Total Cyanide
norrB (s) :
8-a o-1o rilo rrrita sw8a6 9o4oB aglozlos
Diluti@ factor, 1 Analyeie Tlme.,: 13:40
o-45 o-1o rylt, llcArfir 3so-1 ogltUos
Dllutlm Bactor: 1 Alralyele flme..: O5:O0
ssooo e r.ooo wlt ucart 325-2 ogloglos
Dilutlq Factor: 400 Inalyal.e fime..: 10:0o
0.16 ir o-1o ry,lt uceilf, t4o-2 ogloglos
pllutLon Factor: 1 Artalyale Tlme..: 11:30
ND o.1o rry/t' McAww 3s3.2 og/oz/os
Dr.IutLoEl Factor: 1 Analysie ftmc..: 12:OO
IID 0.10 rg/t Mcayrw 3s3 .2 Og/Za/os
Dilut,loB Factor: 1 Acalyala Tlme..: 15;00
14OOO .r,O 2sOO wln ilCe[f, 375-4 OglOelOS
Dilutio Factor: 500 .DlrallraiB fima..: 14:30
o-oos8 B o-o1o rylt sr8{6 goros/gotaL ogl,.4-otl]-slos
DL1ut,loq Factor: 1 Inalyals TLme..: 12:30
s245546
52573-74
szs22sO
52525{O
5,265577
526sro
5249586
525742-l
RL Rryorting Limit
a Elevarcd reporting limit. The reporting limlt is slevated duo ro high analyn hvels.
I Method btank conurmination. Thc associatcd mcrhod blsnk mntrlns tho mrget enalyte rt r reportable level,
B Estimatcd result. Reoult ie ltxs thun RL.
STL Denver
Iot,-garyfle S- . .3
Date Sa4t1ed,-.-3
PARJNyTETER
URg Corporatsion
Clieut Saryrle ID: 8I|B-3-O9O1O5
General. Chenistrlr
D5fO2O230-005 llork Order *- - - ! Hin/RM
og / oL/ as t-3 : 37 Date Receiwed- . r og / 02/ 05
RESUI,T RIJ IJNTTS MEITIOD
IrlaLri:r, - - - - . . . . 3 GW
PR.EPARATION- PREP
AIVALYSTS DATE BATCH #
pH
Armnl-a aB lt
Ch].oride
Fl-uorl.de
Ilitrate
Itltrat,e-Nitrite
Su].fate
Tot,al" C)ranide
IW:[B(S):
8-O O,1O IIo Units
oilutLou FacEorr 1
13OO 5-O rylL
Oilutlon Fact,or: 5O
1-3000 O 2OO nq,lr'
Pllutiou Factor: 80
2-2 J O.1o ry,Il,t
Dilution Faetor: 1
1-60 O-1O rrylL
Dilutlon FacEor: 1
1zo 0 s.o ry/t,
Pllutlou FacEor: 5O
LSoo J, Q 5OO rry,ll
nllutlon FacEor: 100
O-O15 O-O1O ryll'
Dilutl-on FacEor: 1
5'Ir846
Analysis
IIICAf,III
Analyaia
HGATT
aualysie
UC;AHII
AnalysLs
I'TCATII{
AnalyeLa
UCAHT
Anal-yele
ITSHXIH
enalysls
sr846
nnalyeia
90408
Tl-me. , : L3:4tl
350-1
Timg-,: 17:0o
325 -2
Timo. , 3 10:0O
340 -2
TLme..: 1L:3O
3s3 -2
Tlme. . : 12:00
353.2
Tima-.: 16:0O
375 -C
ael ozl as
aelzol os
ae l oslas
aeloelos
ael o2l os
oe lza / os
aelo,6los
5245546
s265421
525225o,
s252s40
52655"1-l
s265542
5249585
Time. . : 14:30
eor-oB I go],,zJ,, 09 f1l-o9 lLs I os s257127
Time-,: 12:30
RL Rcporting Lirnit
a Elevated rcponing limit. The reportiry limit is clcvarcd duc to hi3h analpe lcvcls.
J Mcthod blaok contarnination. The asrcctatod metrod blank conalm fire nrycr analyrc u s roponsble levcl.
STL Denver 92
Iot-8aryll"e #. - -:
Date Saqll.ed,---l
PARAMETER
URS (-orporation
Cliertt I3aqfle ID: SHB-7-O9O1O5
Genera-l Chemist'ry
I[ork order *--,: H.ilIRV
Ilate Received- - 3 09 / OZI 05
RIJ UNITS TYIETHOD
ttatrLf,------.--3 GSI
PREPARATION- PREP
AIiTAIJYSIS DATE BATCH #
Dsr020230-005
ae / aL/ os L4:2a
RESIILT
pE
.Bmnl-a a,a !t
ChI-orlde
Fluoride
Nitrate
NitraEe-Nltrite
Brr]'fate
Total ClanLde
Irc|fE(S} :
1oo ug,lr,
Di}.ut,Lon FacEor: 4O
O.1O rg,IT'
Dllution Factor: L
O. J"0 rg/1,
Di]-ution Factor: 1
O,1O fftg/L
Dilution Factor; 1
s6oo 0
1-1 J
luD
ND
A -2 O - LO IUo llai-ts
Dllution Factor: I
0-068 B O-1O Wln
Dilution Factsor: 1
srr846 9O4oB ael0zlaS
Analyels Time--: 13:{5
ucBHr 35o - 1 a?lzol as
Analyeia Time. . ; 17; 00
uoNrrr 325 -2 Agf O8IAS
Analyela Tlme..: LOrOO
Analyeie Tirna. . : 11 :30
MeArilw 353.2 A9/021A5
Anal-yeie Time-.: L2:O0
MCAWII 353.2 O9/2O/O5
Arral.yeie TLtrle. . : 1-6 : OO
HchrrH 37s-4 A9fA6lAS
nnalysis Tlme.-: 14:3O
sw846 9O1OB lgDI,J,, Ael7-4-sg/I.SIAS
Analysr.e TLrne. . : 12 : 30
5245546
5265424
52s22sA
s252540
5265577
11oO il,Q sOO ryln
Dilutl,on Factor: 1OO
O - oo48 B O. O1O rylt
ol-lutLon Factor: 1
s25ss4o
s249586
s257*27
RL Rcportlng Linrit
B Esirnatod rcsult. Rcsrlt is less fran RL
a Ehvated roporting limt:. Tho rqorting limit is elevrtcd due to high analytc lcvols,
J Method blstlk oontaminatlon. Tho associatod rnofrod blanlc mntains tlrc taryct malyto $ r r@ortable level.
STL Denver
0crlATaAssffioN
D5r020230
Sarnple PreparaLion and Analyeis Control
SAI.{PLE#I,IATRIX
00L
oa2
003
004
wQ
GW
GW
GW
GVT
GW
GW
GW
GW
GW
GW
GW
GW
GW
G}T
clw
GI{
GVT
GW
G$I
GW
GW
GW
GTI
GTI{I
GT{I
GTI
G'rs
GW
GW
AI{AIrYTf eAIr
IT{ETHOD
sw846 82608
MCA?IW 325 .2
MCAWW 34A.2
MCAITIW 353.2
MCAWW 353 -2
9w846 9010B/ 9012A
sw846 6020
sw8{5 747ofi*
9w845 90408
sw845 82608
swg45 82',70c
sw846 50108
MCAV|III 375 .4
MCAWW 350.1
sw846 8270e
MCAWW 325.2
MCAVTW 344 .2
MCAUII{ 353.2
MCAWW 353 .2
sw846 901-OB /gar-2A
sw846 6A20
991846 7474A
srilB46 9040B
s[1r845 82508
9w846 8270C
9w845 8270C
9w846 50108
I{CAVI}il 375 .4
MCAWW 350.1
9w846 9270c
MCAWW 325.2
MCAWW 340 .2
MCAWW 353 .2
MCAWW 353.2
sw846 sahaslgoL2A
sw845 5020
9w845 7 47 0A
sw846 90408
slr846 82608
sw846 8270e
(Cont lnued on
IJEACH
BATCH *
Numbers
PREP
BATCH *
szs6224
52522sO
5252s40
s26s542
5265577
5257 427
5249515
5258348
5245 54 6
s256224
5249103
s2496L7
5249586
5265424
s2504 3 5
52s2250
s252s40
5265542
s255577
5257 42-l
s2496L6
s262486
524554 6
5256224
s249 1 03
525 7544
52496L7
5249s85
5265424
s2s043 5
52522s0
5252s40
s265542
5265577
s2s7427
5249 616
5258348
524554 5
525 6224
5249103
FISI RI'N#
525 6L44
525523l-
52s5 099
52653 3 9
s2s7289
s2493 57
s2s8228
52513 83
s2 s 6t44
s249055
s2493 58
s249328
s26s3 3 0
5250258
s25523 1
5255099
s2653 3 9
5257289
5249357
5252328
szs 13 83
5255a44
52i19 056
5249358
s249328
s25s3 3 0
52s0258
52s523L
s255099
5265339
s2s 7299
s2+93 57
s2sB22B
s25L3 83
s256144
s249055
GW
GW
G['I
GW
GW
G![
GW
GW
GI'I
GTT
STL Denver
next page)
acrlaTaassmw
D5rO20230
9ampIe Preparatlon and Analysl-s Control Numbere
SAII{PIrE#MATRIX
o04 GW
GUI
GW
GW
GI{
GW
GW
GW
GVI
GW
GW
GW
GTU
GW
GW
Gtw
GViI
GI{
GI'T
GW
GW
GW
GUI
GW
GW
Gtw
G}T
GTI
GW
GW
GW
GTII
GW
EW
00s
AIIALYTICAT
METHOD
sw845 501-0B
MCA9{W 375 - 4
MCAfrnil 350 - 1
sv[845 827 AC
MCAWW 325.2
I"ICAUffi 34O .2
MCA$II{ 353.2
MCAWW 353 .2
sw846 9010E/ 9012A
gw84 5 6A20
sw845 7 47 0A
sru845 90408
slr846 82508
sw845 827AC
sw846 8270C
gul84 5 5 0108
MCATiIIII 375 ,4
MCAWW 350. L
sw846 827AC
MCAITW 325 .2
DICAhIW 344.2
MCAI^IW 353 .2
MCAUm 353 .2
sw846 90108 /gO12A
sw846 6020
9w845 74704
sw845 90408
sw846 826 0B
sRI84 6 827 0C
sw846 60L08
MCAWW 375.4
!,ICAW$I 350.1
sw845 827AC
sw845 82608
oo5
007
fTEACI{
BATCH #
PREP
BATCH #
52496L7
524 9s86
5257378
525 043 5
525 2250
5252540
5265542
s265577
s257427
5249616
5258348
524554 6
5256224
5249103
5257544
52495L7
s249s86
5255424
s2s043s
525 2254
52 5 2540
5265542
5265577
525742"1
524967.5
525 8348
5245545
5256224
5249 L03
52496L7
s249s85
s265424
5250435
szs6224
MS RTTN#
s24 93 s8
s249328
s257262
s250268
525523 1
s255 099
s2653 3 9
525 7289
52493 57
525 8228
52 51_3 I3
s256L44
5249056
s2493 58
5249328
526s3 3 0
5250268
s2s 523L
s2s5 099
52653 3 9
525 7 289
52493 57
525 8228
52513 B3
szs6L44
5249 0 55
52493 58
5249328
52653 3 0
s25 A268
52 5 6L44
STL Denver
IIEIEOD BIIaIIK REFORT
etr.Irrg vol-atil-ee
tlork ffier t. - -:C1ieut tot *- -. : D5IO2O23O
llB lot-Aary)Ie #: D5I130000-224
Analyele llate- - : 09 /1,2/ As
Dj.lutlon Factor: 1
PARAMETER
Acetonitrile
Acro]-eln
Acrylonitrile
Carbon dlsulftde
ChIorodibromomethane
2 -Chloroethyl vinyl eEher
1 -Chlorohexane
AIIyI chlorl"de
Cyclohexane
Cyclohexanone
cie- 1, 4 -DLchloro-2-buEene
trane - 7., 4 -DJ- chloro -
2 -butene
D i ch]- o rof I uo rornetr trane
L,4-Dloxane
Ethanol
Ethyl acetate
Ethyl ether
Ethyl methacrylate
Iodomet,hane
Isobutyl alcohol
Isopropyl ether
Mettracrylonitrl-1e
t,ert-Buty1 alcohol
Methyl rneEhacryIate
2 -Nitropropane
2 -Pentanone
eropionitrile
Tetrahydrofuran
Viny1 aeet.ate
n-Butanol
Tr i ch 1 oro t, ri f luoroettrane
Hexane
AceEone
Benzene
Bromodichloromethane
Bromoform
Bromomethane
2 -Butanone (IEK)
Carbon tetrachloride
Chlorobenzene
liatri:r- - -.,, - - - 3 I{ASER
Analysie Tl-me- . 3 08 :55
I,/TETHOD
kep flate-
Prep Batch
HKE\TLlAA
oelLz/os
5256224
RESUI,T
REPORTTNG
I-,IMIT T'NTTg
ND
IID
t[D
ND
IID
IID
ND
ND
ND
ND
llD
ND
t[D
ND
ND
ND
ND
ND
ND
ND
ND
TVD
ND
ND
IID
ND
ND
IUD
ND
ND
ND
ND
tlD
ND
ND
}UD
IUD
t[D
IID
tlD
2A
20
2A
1.0
1-0
2-A
1.0
2.O
2-0
2A
1--0
L.0
2.O
200
200
5.0
2.4
1.0
1.0
50
10
10
50
t.o
2.0
2.O
20
5.0
2.0
50
1-0
1.0
10
1-O
1.0
1.0
2.4
5.0
1.0
L.0
uglr,
ug/L
Vg/L
ug/r'
:ug/t
rug/T,
uslT,
rtg /L
ug/r.
ug/t,
]u,g/t
ug/t
ru.g/t
ug/t
ug/t
wg/r,
us/r-,
:ug/r.
us /T'
ug /T'
luglL
:ug/r'
ug/r,
wg /l'
ug /t,
ug /t-,
ug/L
ug/r,
us/L
ug/r,
lug/r,
ug lt,
:u9/t'
ug/r,
uglr
ug/t
:ug/r,
ug/t
ug/r'
trg / r'
sw845 8260B
sw845 82508
9w845 82508
sw84 5 82508
sw846 82508
sw846 82608
sr{845 82 608
sw846 82508
sw846 82508
sw846 82508
9w845 82608
sw846 82508
sw845 82508
sw845 82608
svr846 82508
sw846 82508
sw846 82608
sw845 82608
sw845 82608
sw846 82608
sI{845 82508
sr{845 82508
sw846 82508
srr846 8250B
sw84 5 82 608
sw84 5 82 508
9w846 82508
sw846 82608
sw845 82508
sw846 82508
sw846 82508
9w846 82608
sYr846 82608
sw846 82608
sw84 5 82508
sw84 6 826 0B
sw846 82608
sw845 82608
sw845 82508
sr{845 8250B
STL Denver
(Continued on next page)
HEIEOD BIAIIK REPORT
C1ieut Lot fi- - -:
PARAMETER
D5rO2 0 234
ChloroeLhane
Chloroform
Chloromethane
Dibromomethane
L . z-Dlbromoethane (EDB )
L ,Z-Dichlorobenzene
1, 3 -Dichlorobenzene
L , 4-Dichlorobenzene
D i ch1 orod.i f luoromethane
1, l-DLchloroethane
L ,2-Diehloroethane
L, L-Diehloroethene
L ,2-DLchloroet,hene
( total )
cis - 1, 2 -DJ-chloroethene
trarrs - 1, 2 -DLchloroethene
L , 2-Dichloropropane
cLs- 1, 3 -Dichloropropene
trans- 1, 3 -Dichloropropene
Ethylbenzene
2-Hexanone
Met.hylene chlorlde
4 -Methyl -z-pentanone
Styrene
1, 1 , L,2-Tet,rachloroethane
1, 1 ,2 ,2 -Tetrachloroethane
Tetrachloroethene
Toluene
L , 2 , 4-Trichloro-
benzene
1, 1 , L-Trlchloroethane
1, 1, z-Trichloroethane
Trichloroethene
rr i chl oro f luoromeLhane
L, 2, 3 -Trichloropropane
VJ.nyI chloride
Xylenes (tota1)
n-Buty1.benzene
Bec -Butylbenzene
reopropvlbenzene
L ,2 , 4-Trimethylbenzene
1, 3, S-Trimethylbenzene
n-Propylbenzene
tert -Butylbenzene
2-Chlorotoluene
cC/I.ls
Ilork Order
RESUT,T
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
}ID
llD
tlD
ND
ND
ND
tvD
ND
IUD
ND
ND
ND
l[D
lTD
ND
ND
}ID
t[D
}UD
IUD
ND
IUD
(cont.lnued on
Vol'atI.I.es
*- - -: HICEI,IIJIAA
2.4
1.0
2-O
1_.0
1--0
1.0
1.0
1-0
2_A
1--0
1.0
1.0
1.0
1.0
1-0
1.0
1-O
1-0
1.0
s_0
1.0
5.0
1.0
1.0
1.0
L.0
1-0
r.0
1_.0
1.0
1.0
2.0
l-,0
1.0
2.4
1.O
1.O
1.0
1.0
1.0
1.0
1.0
L,0
next page)
REPORTING
IJfI'IIT UNITS
tr|ag1i:r--.. - -.. -3 WATER
METHOD
rJg / T'
ug /r,
ug/r,
trg/L
ug/T'
ug/t
ug/t
ug /r,
:ug/r'
:ug/t'
rug/L
ug/L
wg/L
rag / r'
:ug/r,
ug/T'
ug/L
:ug/r'
Lrg /r"
ug /T'
ug/r-,
:ug/t
ug/r,
:ug/t"
:ug/l'
:ug/L
ug /t'
rtg/L
sw845 82608
sr{846 82608
sw845 82608
sw846 82608
sw845 82608
sw845 82508
sw845 8260B
sw845 82608
sw845 82608
sv[846 82608
sw845 82508
9w846 82608
sw846 82608
sw8(l5 82608
sw846 82608
sw84 6 82508
sw845 82608
sw845 82508
sw845 82608
sts845 82608
sw84 5 82508
sw84 6 82 508
sw84 6 82 608
sw846 82508
9w845 82508
sw846 82508
sw846 82608
gw84 6 826 0B
sw845 82608
sw846 82508
SI'I845 82608
sw845 82508
sw845 82508
swB4 6 826 0B
sw846 82508
sw84 6 826 0B
9w846 82508
sw846 A26AB
sw846 826 0B
sw846 82608
sw846 82 6 0B
sw846 82508
sw846 82608
rtg / T'
ug/L
ug/r.,
ug/t'
ug/ T'
trg /r,
]u.g/L
ug/r,
ug/t
ugh'
ug/L
ug/r,
ug/L
us/r,
ug /r,
STL Denver
IIIEIEOD BLAIIK RBPORT
Gc/us vo].at'ilee
Client f.ot
PARAMETER
D5r 02A23A
4 -Chlorotoluene
L ,Z-Dibromo-3 -
chloropropalle (DBCP)
t, 3 -Dichloropropane
2 ,2-Dichloropropane
1, 1-Dictrloropropene
Hexa ctrl orobut ad, i ene
4 -fsopropyltoluene
Methyl terE-butyl ether
L, 2, 3 -Trj chlorobenzene
Bromobenzene
Bromoctrloromethane
Naphthalene
SIIRROGATE
Dibromof 1uoromethane
L, Z-Dichloroethane - d4
{ -Bromofluorobenzene
Toluene-dB
r0rr(8) :
rlork order
RES{ILT
*- - -: HKE\ILIAA
REPORTING
I,IMIT TTNITS
r.ratrix- - - - - - - . - : IIIATER
tvIETHOD
ND
ND
1,0
2.4
1,0
5.0
1.0
J_.O
1.0
5.O
1.0
1.0
1-0
1.0
RECO\IERY
LIMITS
(z: 118)
(62 L28l
(78 118)
0t LL7 )
]ug/L
:ug/t'
]uig/L
ug/r,
ug/t
ug/r.
lus/L
ug/r-,
ug/r'
]u.g/L
ug/r'
uglr'
sw84 5 82 608
sw845 8260B
slir846 82608
sw845 82608
grs846 82508
s!ir845 82608
sw845 826 0B
9w846 82508
sw846 82608
sw845 82508
grf845 82508
sw845 82508
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
PERCENT
RECO\IERY
100
96
LA2
106
Cnlculations are pcrfornnd beforc rounding to rvoid rourd-off orrore ln calculatod results.
STL Denver 98
IIRA Corporatl.on
l{ethod Bl-anls Report
ge/t$ vo].atil-es
Ilot-Saryll.e *: D5f13000O-224 B llork Onder *: HKEIIIT1AA
IitAgg spEctnoraersn/DATA sysrEx{ (MstDs) TENTATrvEr,y rDENrrBrm
PARA}TETER CAS #
ESTTMATED
RESTIIJT
O
5477 4- 91- 3
trtratri-x: WATER
COMPOT}NDS
RETENTTON
TIYE t]NITS
1.3 M 1-1- - OL7 ug/T'
1.3 M 11".94 ruig/L
2-Propenoic acid, i-methylhept
Unknown
mrE($):
M: Rc'sult, wos measrred agalns noores imernal sandard assumin3 e reoponso faaor of l.
STL Denver
W COTFIROIT S,BUPITE BIfAIlmrfOU REtrORT
ec/rr.s vol.atil-ee
Cl-ieut Iot *. - - 3
If,S Iot-Sarylle*:
Prep Da.tg..----3
Prep BaEeJr *- - - :
DLl.ution Factor:
PARAIVIETER
D5r02A23A
D5rl_3 0000 - 224
ae/Lz/as
s256224
L
Ilork Order t- -
Analysis Date-
Ana1ysl"e Time.
HKmffrlAC-IrCS tlatrl-x!, -, ! - r + r 3
HKE[It1AD-LCSD
oe/L2/os
08 : l-7
RPD
RPD I,IMTTS METHOD
UTATER
Bp,nzelle
Ch]-orobenzene
1, I.-DLchl oroetshene
Tohrene
I?ich1orroetlx=ne
SURROGATE
D ib romo f 1 uorome ttran e
L, 2- Dichloroeth^ane - da
4 - Brorno f }uorobenzene
Toluene-d8
ITCTIE (S} :
PBREEI T
RECO\TERY
92
96
106
105
89
96
LO7
110
99
101
RECO\IERY
IJTMITS(rs 12o)(7s 120)(zs 118)(zs 1r-8)(so 132)(es r"3z)
(78 118)
(za r-18)
ltg L22|.
t79 L22l
PERCENT
RECpvERY
97
104
94
9B
105
ao7
L08
LL2
4 ,6 (O-21)
o -4e (o-2al
7 -L (O-26)
2 -3 (0-221
2 -L (O-23)
RECO\IERY
LTMITS
(73 11-8 )
(73 1.18 )
(62 L28)
(62 1-28 )
(ze 118 )
( zs 118)
(tt 117)
(zt 117)
sH846 82608
9H846 82608
9w845 82508
sn846 82508
s'tr845 82608
su8{5 a25o.,,_
9158.{15 826(18
9II845 82608
g11846 82608
9tr846 82508
Calanlationo aro perforrncd before rounding to avoid round-off orrorB in calcutarcd resullq.
Bold print denotes control ptramercrs
STL Denver 100
ffi CONIROL SEHPIIB DATA REPORT
eclw Vol.at,il.ee
cl.l-ent tot f;- - . :
ICS tot-gaq)I.e*:
Prep llate- D - - - - 3
Prep Ba'tch *-. -:
Dil-utl-on Factor:
PARAMETER
D5I020230 Uork Order *-
D5r13 00 00 - 224
ae/L2/as
s25 6224
1-
Ana.lyaia llate- - !
analyste Ttme. - 3
HKEt(trlAe-IrCS
HKE\IIJIAD - IrCSD
oe/L2/os
O8;17
lflafa'lvc-. -e -.. o: WATER
SPIKE
AIvIOU]ff
10-o
10-o
to_o
10. o
to-o
1(}-o
10-o
10-o
10_o
10_o
MEASIURED
A!{OI]NIP
g-19
9 -62
10.6
t-o-6
8-93
9-59
10-7
11 .O
9.93
10-1
T]NITS METHOD
PERCENT
RECO\IERY RPD
Benzene
Ch]-orobenzene
1, 1-Dichf-oroethene
Toluene
trichl.oroethene
STIRROGATE
Dlbromof luoromethane
L, 2-Dlchloroethane -d4
4 -Bromofluorobenzene
Toluene-d8
IWTE (8} :
u.glr'
UlglT'
luglt,
]utg/L
rnglr,
vSlr,
ug/r,
us/L
utglI-
ruglt,
PERCENT
RBCO\IERY
92
96
106
1(}6
B9
96
LO7
110
99
10r-
RECO\IERY
ITIMfTS
1-6
o-49
T.L
2-3
2-L
str846 82508
g118{6 82608
91846 82608
sr8{5 82508
sr8{6 82508
9H845 82608
9H846 82608
5:Xr845 82508
9H845 82508
gtr846 82508
o97
104
9{
98
10s
LO7
108
1,L2
(tl 118)
(tt 118 )(az 128)
(sz 128)
(zg 118)
(78 1-18)
(zt 1L7 )
(7 Z It?)1
Calculatiors are perfomre<l bcfore roundin3 to avoid round-off crrorS in calorlated results.
Bold print donotes control psremolorn
STL Denver 101
CIienL Lot S- - - l
ri$ fot-Saryr1e *:
Date Sary)I-ed---!
Prgp Datg--.---i
Prep BatcII *- - - :
Dl.}utLon Eaetor:
PARAMETER
D5r020230
D5I02 023 0- 004
oe / oL/ as L2:Lo
oe/az/as
s2s6224
1
Date Received.-. 3
Analygig Date- - i
Anal.ysie Tlrne- - l
H.ryQ9LET -MSD
ae/02/as
ae/L2/os
10:32
RPD
RPD LTMITS
IATnIT gPIf,G SETTPLB BITAITILTION REFORT
GC/rf,S Vo]-atl.]-ee
Ilork Order *- - -: HifVQ91C6-MS rratrix--!-..-.-! GTI
METHOD
Beu.zene
Ch^I'orobenzene
1, 1-DJ-chf-oroethene
Toluene
1?ichl-oroethene
gI,RROGATE
D I b romo f luoromettrane
L, 2- Di chloroettrane - d4
4 - B rornof luorobenz ene
Toluene-dB
IWTB (S) t
87
88
9s
94
84
85
92
93
90
92
PERCENT
RECO\IERY
RECOVERY
I,IIyIITS
(ts 120)
(7s 12O)
(zs 118)
(78 118)
(ee 132)
(oo L32)
(zs 11.8)(zs 118)
('19 L22l
(tg L22l
PERCENT
BHggEB]{
L03
L00
115
114
103
10.{
96
9z
o - 91 (O-za)
o - 02 (o-zo)
o - 71 (0-26)
a -71 (o-22)
1-5 (O-23)
srr846 82508
sw846 82508
sH846 82608
9w845 82508
sH8{6 82608
sr8{5 82608
sr846 82608
g11846 82508
gH846 82508
5'H845 82508
RECO\IERY
LIMITS
(zs 118)
(?3 11"8)
(sz L28 )(az 128 )(za 118)
(78 118 )(zt 117 )(77 LLTI
Calculations are porforned before rounding to avoid rourd-off errors in cslculatod rearls.
Bold prlnt denotcs control par&rnoters
STL Denver aa2
ClLent Ipt f;-.-:
I.GI Iot-Baryfle *:
Ilate Barpl.ed---:
PreSl Ilate? - o - - - 3
kep Bat,ch *, -.:
Di].utLon Factor:
PARAMETER
Dsr 020230
D5I020230- 004
0e / otl os L2 =L0oe/L2/os
52s6224
1
Date Receiwrsd- -:
Ana-lysLs Date- . 3
Bnalysis Ttre- - !
T{AIRIX SPIffi S,E}IPI,E DAIA REFOIIT
ecir+s voIatiles
Ilork order * -HiruQ91C6 -Mg
HWQ9LCT -MSID
ae/a2/os
oe /L2 I as
1O:32
Irlatrl-x-,----r-?: GW
SAIt{PLE SPIKE
AIvIOt NT Af'fT
MEASRD
AIVIOUNT UNITg
PERCTflT
RECI'IRY RPD METHOD
Benzene
Chlorobenzene
1, I--DichJ-oroethene
ToI.uene
trichr oroethene
SIIRROGATE
ITD 1O-O
TTD 10. O
uD 10-o
IID 1O-O
IID LO. O
ND I-O. O
ItD 1(l-O
ITD 1O-O
IID 10. O
ITD 10. O
8-73
g .81
9 -45
9.45
8.'+,2
8 -48
9-19
9 -26
9-(,5
9-r-8
PERCEITT
RECO\TERY
103
100
11s
114
103
10{
95
97
wlt
u,slIt
u.glr,
ruglr,
ruglT,
wl,'
u.glr,
luglt'
wg/T,
ruglT'
a7
88
95
94
84
85
92
93
90
92
RECO\TERY
LIMITS
srr845 82608
o - 91 gtr846 82508
sH845 82508
o - 02 srr846 82608
B11846 82508
a -lL SItr8{5' 825(t8
srr846 82508
a -74 9w845 82608
sr846 82508
1-5 sr846 82608
Dibromofluoroffi€t}.ane
L, 2- Diehloroethane-d4
4 -Bromofluorobenzene
Toluene-dB
rsoifB (s) :
(tt 11s )(zr 118)
(62 128 )(ez 128 )
0a 118 )
( zs 118 )
fiz 117)(zt 117 )
Calctlarlong arc performod boforc roundln3 to svoid round-of,f crrors ln calculatod resrlrg-
Bold print dcnotes control perameters
STL Denver 103
Cl-ient Iot fi- - -: D5I020230
ItlB lot-Saup].e #: D5I060000-L03
Ana1lrsie rlate. - 3 09 / 09 / 05
Dil.ution Factor: L
PARAMETER
Acenaphthene
Acenaphthylene
Acetophenone
2 - Ace ty1 atninof luo rene
4-Aminoblphenyl
Aniline
Anthracene
eramite
Benzl-dine
Benzo (a) anthracene
Benzo (b) f luorarrtrhene
Benzo (k) f luoranthene
Benzolc acid
Benzo (ghi ) perylene
Benzo (a) pyrene
Benzyl alcohol
bl-s (z-Chloroethoxy)
methane
bl-s (z-ChloroeEhyl) -
ether
bls (2 -Chloro i sopropyl )
ether
bis (z-Ethylhocyl )
phthalate
4 -Bromophenyl
ether
Buty} benzyl
Carbazole
phenyl
phthalate
4 - Chloroanl-l ine
Chlorobenzilate
4 - ehloro - 3 -meEhylphenol
2 -Chloronaphthalene
2 -Chlorophenol
4-Chlorophenyl phenyl
ether
Chrysene
DiallaLe
Dibenz (a, h) anthracene
Dlbenzofuran
Di-n-butyl phthalate
3, 3 ' -Dichlorobenzidlne
}IETTIOD BIAITK REFORT
Gf.llrt$ Semlrrol.atlJ-es
Ilork Order f---: H.]0Q01AA
Prep llate- - - - - - : o9/o6/as
Prep Betdr #.. . i 5249103
REPORTING
REST'I,T I,IMTT UNITS
}TaIrTr. DOD O }. - - 3 WATER
Ana.IyaLs Tfure--3 L9:49
IVIETHOD
ND
ND
ND
ND
ND
ND
ND
ITD
ITD
ND
ND
ND
ND
ND
IUD
ND
}UD
l\ID
rlD
ND
ND
I{TD
ND
(Continued on
10
10
10
100
50
10
1-0
20
1_00
1_0
10
10
50
10
10
10
1_0
10
10
10
L0
L0
10
10
Lo
10
1.0
L0
L0
10
20
10
10
L0
50
next, page)
ug/t
uglr,
ug/L
ug /r.
lrg /r.,
ug/t
ug/r,
1u'g/L
uglt
ug /T.
:uglt,
Lrg /T'
ug/r
ug/r,
ug/l'
ug/r'
uslT,
Ltg/r'
ug/l'
ug/T'
ug/r,
vg/T,
ug/t'
.ug/r'
ug /r'
ug/t
ug /t'
ug/r,
ug/t
ugh'
uglr'
ug/t
ug/L
us/L
ug/r-,
sw846 8270C
sw845 8274C
srir84 6 927 0c
sw846 8270C
sw846 827Ae
sw845 9270C
sw846 8270C
sw846 8270e
sw845 827AC
su[845 8-27 0c
sw845 8270C
sw845 8274c
911846 8270C
9w846 8270C
sw846 8270e
sw845 g27AC
sw846 8270c
sv{846 8210e
sTr84 5 827 AC
sw845 8270C
sw846 8274C
sw846 82',7 AC
sw845 8274e
9w846 8270C
sr{845 827 0C
sw846 8274C
svr846 82-lOC
sw845 8270C
9w846 827Ac
sw846 bZtic
sw846 8270C
sw846 827 0C
sY{846 8270C
sw846 8270e
sw845 8270C
ND
ND
ND
ND
ND
ND
luD
ND
STL Denver 104
elieut Ipt #---:
PARAIIIETER
D5I02023 0
2 ,4-Dichloropherrol
2 , 6 -DLchlorophenol
Diethyl phthalate
Dirnetlroat,e
7 , L2 -Dlmethylbenz (a) -
arrthraeerle
3, 3' -DLmethylbenzl-dine
2 , 4-Dimethylphenol
DLmethyl phthalate
1, 3 -Dinitrobenzene
4,6-Dinl^tro-
2-methylphenol
2 ,4-Dinitrophenol
2 ,4-Dinltrotoluene
2 , 6-Dinitrotoluene
Dl-n-octyl phthalate
Diphenylamine
L, 2- Diphenylhydraz ine
DLsu].foton
Ethyl methanesulfonate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachl orocyc I opent a -
diene
Hexachloroetlrane
Hexachloropropene
rndeno ( 1 ,2 ,9 -ed) pyrene
f sodrl-n
Isophorone
fsosafrole
Methapyrilene
3 -Methylcholanthrene
Methyl methanesulfonat,e
2 -MeEhylnaphthalene
1 -Methylnaphthalene
Methyl parathl-on
2 -MeLhy1pheno1
3 -Methytphenol tc
4 -Methy1pheno}
L , 4-Naphthoguinone
1-Naphthylamine
2 -Naphthylamlne
2 -Nitroaniline
3 -Nlt,roanLline
IIHTEOD BIJAISK RtsPORT
Gf-I}/[8 Serulvolatil.es
Hork Order *---: H.I0Q01AA
REPORTING
RESUI,T LITT{IT T]NITS
llatrl-x! - -, - - - - -3 WATER
}4ETHOD
ND
IUD
ND
ND
DID
ND
ND
ND
ND
ND
}UD
}UD
Ii[D
}TD
ND
(Cont.Lnued on
1_0
10
1_0
20
20
20
10
1.0
10
50
50
10
10
10
10
L0
50
10
IO
10
10
50
10
100
10
10
10
2A
50
20
L0
10
10
50
10
10
50
10
10
50
50
next page)
rJg / T'
rrg/L
ug/r,
ug/L
ug/r,
ug/t"
:uig/t'
ug/n
us/L
:ug/L
ug/L
ug /T,
wg /r'
rtg /L'
ug/L
:ug/r'
ug/r,
wg/r,
ug/r,
lug/r,
:ug/T'
lu.g/t
lug/r,
:ug/T.,
:ug/r,
ttg / f'
ug/r,
rrg /r'
ug/t,
ug/t
ug/L
ug /T,
ug/t
ug /r,
ug /r,
wg/r,
ug/L
ug/I'
ug/t'
:ug/L
ug/1,
sw846 827 0e
sw845 827 0c
sw845 8270C
sw845 8270C
sw846 927 0C
sw8{6 8270C
sw846 8270e
sw845 8270C
sw846 82'l0C
sw846 8270C
sw845 8270C
sw845 8270e
sw845 8270C
sv[846 8270C
sw846 827 0C
sw845 e27AC
sw846 8270C
sw846 8270C
slr845 8270C
sw845 827 0C
sr{846 8270C
sw846 827AC
sw846 8270C
sw846 8270C
sw84 5 827 0e
srt846 827 AC
sw845 8270C
sw845 8270C
9w846 8270e
sv{845 8270C
sw845 8270C
sr{84 6 827 AC
sw845 8270C
sw845 B27AC
sr{84 5 827 AC
sw845 8270C
sw845 8270C
sw845 827AC
9w845 8270e
sw846 8270C
svr846 827AC
ND
IUD
ND
ND
ND
ND
ND
ND
ND
ND
IID
ND
ND
DID
ND
ND
IUD
ND
ND
luD
ND
IUD
ND
ND
IUD
ND
STL Denver 105
}IEIIIOD BIJEITK RtsPlORT
ec/nS Benirro1atslles
C1ient. Lot f---: D5I02O23O
PAR;AI[ETER.-. -
4 -Nitroanill-ne
Nit,robenzene
2 -Nitrophenol
4 -NJ-trophenol
4 -Nitroquinoline-
l,-oxide
N - Ni t rosodl- - n - butyl amine
N - Nl- t ros odlethyl amine
N - Nt t ros odimethylamine
N - Ni t, ros odiphenyl aml-ne
N -Ni t rosodi - n - propyl -
amine
N - Ni t ros omethy I ethyl amine
N-Nitrosomorphol ine
N-Nl-trosoplperidine
N - Ni t, ro s opyrro I idl-ne
5 -Nltro-o- toluidl-ne
Parathion
Psntactrlorobenzene
Pentactrloroethane
Pent achl oron i t robenzene
Pentachlorophenol
Phenacetin
Phenanthrene
Phenol
Phorat,e
2 -Picoline
Pronaml-de
Pyrene
Pyridl-ne
L,2,4 ,5-Tetrachloro-
benzene
2 ,3 ,4 ,6-Tetrachlorophenol
Thlonazin
o-Toluidine
L ,2 , [-Trichloro-
benzene
2,4, 5-Trichloro-
phenol
2 ,l ,6-frichloro-
phenol
O, O, O - rriethylphoephoro -
thioate
1, 3, 5 -Trinltrobenzene
Ilork Order #.
RESULT
IUD
ND
IilD
wD
: HJOQO1AA
REPORTINGr,.J!gg. uNrrs
llatrix--.--,.-.3
METHOD
VTATER
![D
ND
IUD
ND
ND
ND
ND
ND
ND
ND
s0
Lo
10
s0
1_00
10
t0
10
1.0
L0
10
10
10
to
2A
50
10
50
s0
s0
20
10
10
s0
20
2A
L0
2A
10
s0
10
1,0
1,0
L0
10
50
s0
ug/t'
:ug/r'
rlg / r.
us/L
rug/t,
lug/t'
ug/t
ug/t'
ug/L
ug/r,
rus/T,
ug /r-,
ug/r'
]ug/L
ug/L
ug/r,
ug/t
ttg /I'
ug/r,
ug/r,
us/L
ug/L
ug/t
LLg /T'
ug /t'
ug/t
ug/t,
trg/L
ug/r,
:ug/T'
us /\,
ug/r,
ug/r,
ug/r'
uslL
ug/t'
ug/L
sw846 827 0C
sw845 B27Ae
sw846 8270C
sw845 8270C
gI{84 6 827 0C
sw845 8270C
sw845 U^270C
sw846 g27AC
9w846 8270C
sw846 8270C
9w846 8274C
sur84 5 8270C
swB46 8270e
9w846 8274e
sw846 8274C
sw846 8270C
sw846 8270C
swB46 B27AC
sw846 8270C
9w846 8274C
9w846 8270C
sw846 827AC
sw845 8270e
sw84 6 827 0C
sw84 6 827 Ae
sw84 5 8274C
sw845 8270C
sr{84 5 827 0C
sw846 8270e
sw84 6 827 AC
sw84 5 827 0C
SIII84 6 827 AC
sw845 8270C
sw84 5 827 0C
gr{046 g2l Ae
sw845 927 0C
sr{845 8270C
ND
ND
IUD
ND
ND
ND
ND
I{D
ND
ND
ND
ND
IID
t[D
ND
ND
ND
I{ID
ND
ND
ND
IUD
ND
STL Denver
(Contfnued on next page)
105
IIETEOD BIAISK REBORT
Gf.hrB 8enlvolatiles
C1ieut Iot #-
PARA}IETER
: D5I02O23O nork Order *-
RESIIITT
: HI,T0Q01AA
REPORTING
IJfMf T UI{ITS
l[atrfu(---.or,..i
METHOD
V{ATER
STIRROGATE
PERCEIiIT
RECO\IERY
BL
83
BO
74
B5
107
REEO\TERY
ITfMITS
(es g2'l
(49 e8)(so ee)(+a el)
(as 113 )
( ro 1so)
2 -Fluorophenol
Phenol-d5
Nitrobenzene-d5
2 - Fluoroblphenyl
2, 4, 6 -Trl-bromophenol
Terphenyl -d14
twfB(8):
Celcu}ationg rro performcd beforo rounding to avoil round-offcrrors In calculatcd rcsults.
STL Denver L07
IIRB CorSnratLm
I'Iethod Bl-ank Refiort
ecArs Eeuivolatileo
Iot-Ea4l1e *: D5fO60000-103 B llork Order *: H,f0Q01AA llatri-: VIATER
MASS SPECTROIYIETER/DATA SYSTEM (MSDS) TENTATIVEIJY IDENTIFIM COMPOUIIDS
ESTI}ATED RETENTION
PARAMETER CAS # RESTIIJT TI}48 TTNITS
Urrknown
Cfrclohexane
Unknown
rwfB (s) :
26 J M2-A876 rtg/L
11O -82-7 26 ,.7 M 2.2325 ug/1,
34 J IvI 2.3A77 LLIj./L
M: Rcsttlt was meacurcd agalnr oesro$ inprnal $andard arsrming 8 rcspotrsc factor of t,
STL Denver 108
HETUOD BT,EITK REPORT
ec/UB sernirrotatik=s
C1ieut Iot *-
llB lot-garyfie
Ana1ysie Date- - 3
Dllution Factor:
D5r020 23A
D5rO70000-435
oe/L3/os
1
I5ork Order *-
Prgp Date-,--
Prep Batch *-
RESTILT
ND
PERCEDflT
RECO\IERY
74
68
51-
66
70
70
H,J4RKIAA
oe/a7/as
5250435
REPORTING
IrfMfT UNITS
ffatri-x- - - - - - ---3 WATER
Analygl,g Ti^re- - i 18 :3 0
METHOD
-O-
{J-It-
PARAMETER
Pentactrloroptrenol
STJRROGATE
4 , O ug/I'
RECOVERY
LIMITS
(gg 1,15)
Q2 10e)
(ze L26l
(se 114)
(sz 105)
(tt L42)
sw845 8270C
2 -Fluorobiphenyl
2-Fluorophenol
2 r 4 ,6-Tribromophenol
Nltrobenzene-d5
Phenol -d5
rerphenyl-d14
ruotfB (s) :
Calcrrladono &rc performed bnfore rourding to rvoid rourd-off errorg in talculated rcsulte.
O
STL Denver 109
Cl-lent Iot *---: D5I02O23A
IIB Iot-l3ary>I.cr *: DSI14000O-544
.Bnal-ysis f,|ate- - r ag /2L/ os
Dl.I"ution Factsor: 1
PARAMETER
Acenaphthene
Acenaphthylene
Acetophenone
2 - Aeet yI aminof luorene
4-AminobLphenyl
Ani]-ine
Anthraeene
Arannl,te
Benzidine
Benzo (a) anthracene
Benzo (b) f luoranthene
Benzo (k) f luoranttrene
Benzoic aeld
Benzo (ghi) perylene
Benzo (a) pyrene,
BenzyJ. alcohoJ.
bLs (Z-Chloroethoxy)
rnettrane
bls (z-Chloroethyl ) -
ether
bis lZ -Chloroisopropyl )
ether
bis (z-Ethylheryl)
phthalate
4-Bromophenyl phenyl
ether
Buty1 benzyl phthalate
Carbazole
{ - Ch}oroanilLne
Chlorobenzilate
{ - Chloro- 3 -methylphenol
2 -Chloronaphthalene
2 -Chloropheno1
4-Chlorophenyl phenyl
ether
Chrysene
Diallate
Dibenz (a, h) anthracene
Dibenzofuran
Di-n-buLyl phthalate
3, 3 t -DLchlorobenzidine
HTISOD BIATK REPIORT
Gl9ll{6 SenirrcIat,il-ee
Hork Order f---: HK.T551AA
Prep rlater rb . . . . : 0 g / tE/ Os
Prep Batch *- - -: 5257544
REPORTING
RESU['T LIMIT IINITS
It[atri^r- --- - ?. - -: WATER
enalysig Tirre..3 17:53
IvIETHOD
ND
ND
ND
ND
}UD
ND
ND
ND
tlD
ND
rlD
ND
ND
ND
ND
ND
ND
1-0
10
10
100
50
10
10
20
100
10
10
10
50
10
10
10
10
10
1,0
10
10
LO
10
L0
10
10
10
10
L0
10
20
10
10
10
s0
next page)
ug/t
:ug/t,
ug/L
ug/r'
ug/t'
vg /T"
ug/r,
ug/r,
ug/t
ugl].
ug/t,
ug lt'
ug/r,
uglr,
ug /t'
vg /r'
u9/r-,
rrg /r,
ug/L
vg lI'
ug/t
ug /T'
vg /r'
ug/L
ug/r,
ug /t'
lug/L
ug/t
vg/T,
uslL
ug/L
ug/L
ug/r,
ug/L
ug/L
sw846 827AC
sw846 8270e
sw845 827AC
sw845 8270c
sw845 8274C
sur84 6 927 0e
sur846 827 AC
sw846 827AC
sI{846 827AC
sw845 8270C
9w845 827 AC
sw84 6 827 0C
sw846 827 0e
sw846 8270C
sw845 827AC
sw846 8274C
sw846 8270C
sw845 8270C
sw845 821AC
sw846 827AC
9w846 8270C
sw8{5 827AC
sv{846 827 0C
sw845 8270C
sw845 8270e
s[I845 82-lOC
sw846 827 0C
swg45 g27ac
sw845 9270C
s[r046 g2lae
sw846 82-l0C
gr{845 827 AC
sw845 8270C
sw845 8270C
sw846 8270C
ND
ITD
ND
ND
ND
ND
IUD
}UD
ND
![D
ITD
ND
ND
}TD
(Cont,inued. on
STL Denver 110
Cl.ient Iot
PARJAMETER
*---: D5I020230
2 , 4-Dichlorophenol
2 , 6-Dichlorophenol
Diethyl phthalate
Dimethoat,e
7 , L2 -Dimethylbenz (a) -
anthraeene
3, 3 r -Dimethylbenzldine
2 , A-Dimethylphenol
Dimethyl phthalate
1, 3 -Dinitrobenzene
4 ,6-Dinitro-
2 -methylphenol
2 ,4-Dlnitrophenol
2 ,4-Dinitrotoluene
2 ,6-Dinttrotoluene
oL-n-oetyl phLhalate
Diphenylamine
L, 2- Dtphenylhydraz ine
Dteu1f ot,on
Ethyl methanegulfonate
Fluoranthene
Fluorene
Hexach].orobenzene
Hexachl orocyc I opent a -
dLene
Hexaetrloroethane
Hexachloropropene
Ind.eno ( 1. ,2 ,3 -cd) pyrene
rsodrln
Isophorone
Isosafrole
Methapyrilene
3 -Methyl chol antlrrene
Methyl metharresul fonate
2 -Methylnaphthalene
1-Methylnaphthalene
Methy1 parathion
2 -Methy1phenol
3 -Methylpheno1 &
t-t{e[hy]phenol
a , 4-Naphthoquinone
L-Naphthylamlne
2 -Naphthylamine
2 -Nitroaniline
3 -Nitroaniline
}TBTEOD BI,ENK RBPORT
e/uS Bmlrrol-atiles
ISork Order #- - -: HK\T66LiAA
REPORTING
RESULT LTMIT UNITS
l[atri-x- -.-. --- -3 WATER
METHOD
ND
ND
ND
IID
ND
ND
tlD
ND
ND
ND
IID
ND
ND
Ii[D
I{ID
(ConLlnued on
10
10
L0
20
20
2A
10
10
10
50
50
10
10
1-O
10
L0
50
L0
10
10
l-0
50
10
100
10
r0
t_o
20
50
20
10
10
1-0
50
10
L0
s0
10
10
50
50
nexL page)
ug/L
vg/T'
ug/r,
LLg /l'
ug/r.
ug/r..
ug/r,
ug/t-,
luig/r'
ug/t'
lug/t
:ug/r,
ug/t
ug/t'
lug/r-'
ug/r-'
ug/t
ug/t,
ug /t'
:u.g/t,
:ug/L
lu,g/L
ug/u
ug /r,
ug/t
u9/t'
ug/r,
ug/t
ug/r,
wg/T,
ug/t
ug/t
ug/t
ug /T,
]ug/L
ug /t,
ug/r,
vg/L
ug/r,
ug/L
ug/L
sw846 827AC
sw845 827 0e
sw845 827 AC
sw846 827 0C
sw846 8270C
sw846 827Ae
sw846 827 0C
sw845 8270e
9w846 fJ270e
s[rl845 8270C
sw8{6 827AC
sv[846 8270C
9w845 827AC
svr84 5 827 0e
sw846 8270C
sw846 8270C
sw845 8270C
sw845 9270C
sw846 827AC
sw846 8270C
9w845 8270C
9w846 827 AC
s[r[84 6 82 70C
sw846 8-270C
sw84 6 827 AC
gw845 8270e
swg45 827AC
9w845 8270C
sw845 8270e
slir846 8270C
sw845 8270C
sw846 827 0C
gIrIS{ 5 827 0C
gr{845 8270C
sw845 g27Ae
sw84 5 827 0C
sw84 6 827 Ae
sw845 827Ae
sw846 827 Ae
sw845 827 0C
sw845 827AC
ND
ND
IID
ND
ND
ND
ND
r[D
ND
ND
ND
ND
ND
ND
ND
ND
IUD
ND
ND
ND
ND
ND
ND
ND
ND
ND
o
STL Denver 111
C1ient Iot
PARNYIETER
4 -Nitroaniline
Nitrobenzene
2 -Nitrophenol
4 -Nltrophenol
4 -Nltroquinoll-ne-
1-oxide
N- Nit rosodi - n- butyl amlne
N- Ntt ros odl ethylamine
N - Ni t ro s odlme thyl amirie
N - Ni t ro sodl-phenyl amLne
N- Nltrosodl - n- propyl -
arnine
N - Ni t ro g ome thyl ethyl amlne
N-NLtrosomorpholine
N-NiLroaopiperldlne
N-Nitrosopyrrolldine
5 -Nit,ro - o - toluid i-ne
Parathion
PenEachlorobenzene
Pentachloroethane
Pent, achl oron i t robenz ene
PenEachloroptrenol
PhenacetLn
Phenanttrrene
PhenoI
Phorate
2 - Picoline
PronarnLde
flrrene
Pyrldlne
L,2 , 4 ,S-Tetrrachloro-
benzene
2, 3, 4, 6 -Tetrachlorophenol
Thionazin
o-ToluidLne
L,2 ,4-Trichloro-
benzene
2,4, 5 -Trichloro-
phenol
2,1,6*friehloro-
phenol
O, O, O- Triethylphosphoro -
thioate
1, 3, 5 -TriniLrobenzene
IflETHOD BLBIIK RBPORT
(Jrcllfr$ Serrlrro1atl.I.eo
Dsr02 023 0 hrk Order *-. - 3 HKif551AA
REPORTING
REgtILT IJIMIT TINITS
so wg/T,
10 ug/I'
10 uglL
50 ug/t'
10 o ug/r,
tr;af,1i x -WATER
METHOD
ND
ND
l[D
IID
ND
ND
ND
ND
ND
ND
sw84 5
9w846
sw845
sw84 5
sw845
sw846
sw846
9w845
sw845
sw846
sw845
sw846
sw84 5
sw845
sw84 6
9w846
sw845
sw846
sri[84 5
sw846
sw8{5
sw845
gw84 6
gw84 6
sw84 5
sw84 6
svr84 6
9w846
sw84 5
sw84 6
sw846
sw845
sv{84 6
sw84 5
B27AC
827 0C
827 AC
827 0C
I 270C
827 0C
827 Ae
827 AC
827 AC
B27AC
8270e
8270C
8270C
827 AC
827 0C
8270C
8270C
827 0C
827 0C
8270C
827 0C
827 0C
827 0C
827 Ae
827 AC
827 0e
827 0C
827 AC
827 AC
827 0C
827 AC
827 0C
827 0C
827 0e
IID
ND
ND
ND
ND
ND
ND
ND
ND
DilD
ND
ND
ND
IUD
ND
ND
ND
ND
ND
1-0
L0
10
10
10
L0
L0
10
10
20
50
r_0
50
50
50
20
10
l_0
50
2A
2A
10
20
10
50
10
10
t0
r.0
70
50
s0
next page)
sw046 a27Ae
st{846 8270e
slt846 8270C
ug/r.
trg /I'
vg/r,
us/T,
rug/T'
:u,g/T,
]ug/L
ug/r,
trg /r.
ug/r,
ug /T'
:ug/r,
ug/r,
ug /t,
ug/T,
ug/t
:ug/r.
us/L
:us/T,
Ltg I T,
ug/t'
ug/t,
ug /r,
ug/L
vg/r'
ug/L
ug/T,
ug/r,
ug/r'
uslL
ug/t
ug/t
ND
ND
}ID
ND
IID
t[D
(Continued on
STL Denver a72
I.IEIIIOD BIf,IIK nEgORT
GCAt-g Semlrrol.atil-es
C]-lent lpt *-
PARAMETER
: D5T02023o Hork Order *-
RESULT
: HKJ551-AA
REPORTING
I,IMIT TINITS
llatrL:r - - , - o. -,,3
METHOD
IiIATER
SURROGATE
PEREEMT
RECOVERY
73
78
7L
69
79
59
RECO\IERY
IJIMITS(4s e2l(+g e8 )(so eel(as el)(ae r-13 )
( ro lso)
2-Fluorophenol
Phenol-d5
Nitrobenzene-d5
2 - Fluorobiphenyl
2,4 ,6-Trlbromophenol
Terphenyl -dra
rufB (sl :
Calculations arc performed before rounding to avoid rourdoff errors in calculatcd results.
STL Denver 113
Iot-Saqfle
IIRS Corporatlon
Ilethod BIanIE Relrcrt
Ge/us senivrrl.atilee
D5fL40000-544 B lilork Order #: HIGJ661AA
II,IA.SS SPECTRO}4BTER/DATA SYSTEM
PARAMETER
Unknown
C|rclotrexane
Unknown
rwrE (s) :
(MSDS ) rmsTATr\rErrY TDEIflTTFIED
ESTT}hTED
CAS # RESULT
llatri-x: WATER
COMPOT}NDS
RETENTION
TIME UNTTS
2 - L3 51 rLg/I'
2.29A2 ug/!'
2 -3704 ug/t'
_G
L4 LT
1r.o -82-7 28 ir
140 ,,
M
M
M
M: Resull wsg moesrro'd againrt ncrrest intcrnal standard asruming I rqsponcc fecor of l.
STL Denver aL4
IrIBORAaQRY CQilI?Ofr 8ADTPIrB ffi REFORT
ee/us Seni\rol-atiles
ClLeut Iot *- - - l
LCII Iot-Saryl1e#:
Prep Datg,-----!
Prep Batch, fi-. -:
Di1ution Factor:
PARAMETER
D5 r 02023 0
D5r050000-103
ae / o6los
5249 1 03
L
HorI( Order #-.
analyeLe flate-
aral.yel.e Tr-re-
PERCEDIT
RECO\IERY
H..TOQOIAC
oe/ae/os
20:1O
llatrix- !, ! !,---: I{ATER
RECOV,ERY
IJIMITS METHOD
Acpnatrthtlrene
L, 4 - Die-hl-oroben-zerre
4 - ChI oro - 3 -metblrlphenol-
2-frIoropheno1
2 r4-Pr{ni trotolreue
4-I5Ltropheno1
N-Iritroeodl- -n-prqryI. -
am{ne
Pentachl.orogrhenol.
Phenol.
Plrrene
Lr2,4-friehl.oro-
benzene
STIRROGATE
2-Fluorophenol
Phenol-d5
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-TrLbromophenol
Terphenyl *d14
IIOI"B (s)
=
85
81
88
86
100
95
77
99
83
92
8{
(sr
(tt
(ss
(sr
(se
(45
(sr
(cs
(so
(sn(lr
es)
87,
101_)
ee)
105)
10e)
ea)
1091
101)
111)
eol
PERCEE{T
RECO\IERY
82
85
82
79
90
97
slr845 8270C
sn845 8274e
sw845 8.27Ac
sw846 8270C
sH845 8.27AC
sH845 827o,C
sH845 827AC
srr846 8.27o,c
sr846 827$C
sr58{5 8270e
g118{6 8270e
RECO\IERY
LIMITg
(s+ e4 )
( ss 101)
(s0 e?l(ea es)(s+ r.10 )
$t L2a'l
Calculations are perforrned before rounding to avoid round-off crror3 In cahulatcd rcsults-
Bold prirrt <Imotes conrol par&me[crs
STL Denver 115
Cllent Iot *- - - i
rcB Iot-Sary>Ie*:
Prgp Datg-?,-,-i
Prep Batch *., - 3
OLl.ution Pactor:
PARAT4ETER
D5 I02 023 0
D5r060000-103
ae/a6/os
5249L 03
L
Anal-yaie
Analyeia
SPIKE
A]lgt Nr
100
100
150
150
100
150
100
150
150
100
100
Da.te- - r a9/09/os
TiEe- - ! 20:10
MEAS{TRED
AI"IOUNT
85-2
80-7
L32
L29
1(}0
L42
'17 -3
L49
L21
91- 6
84-4
PERCEI\IT
RECO\IERY
B2
85
B2
79
90
97
ffi mIltROL S.,AHPIrE DATA REORT
trllrrs Senlvolatil.es
Ilork Order f---: H,JOQOIAC ItlatrLx..-o ! - -..3 WATER
PERCEIIT
RECOVERY METHODUNTTg
Acenafilrtheue
L,4-Dichlorobmzerne
{ - Cft I oro- 3 -retIylpheno]-
2-Chf-orogrlrenol
2,4-Dirrl.trotoluene
4-Ifitrophenol
rr- Ni trosoftl - n -progryrl -
aud-ue
Pentachl.orophenoI.
Pheno].
Plmene
L,2,4-Itichf.oro-
banzene
SURROGATE
2-Fluorophenol
Phenol-d,5
Nitrobenzene-d5
2 - FluorobLphenyl
2 ,4, 6 -Tribrornophenol
Terphenyf -d14
rugln
u.glt'
utslI.
luglr,
ug/r,
utglr'
urglr'
rury,lr,
u.glT'
]rsfi,
aglt'
RECO\IERY
LTMTTS
85
81
88
86
100
9s
77
99
83
92
84
sH846 8270e
sH846 8270eg[846 8,27o,C
aw8c5 8.270c
sH8{6 8270e
8F845 8270'c
91845 827o,c
811846 8270C
g11846 827oC
sw8{6 8.270e
srrE{6 8.270e
(s+ e4 )(s5 101)
( se e7l(+s es)
(se 110 )(sz L2L)
rufB(s) :
Calculations trc pcrformd beforo rounding to avoid round-off errors in crlculrtod roults.
Bold print donores conrol par&motors
STL Denver 115
W C0IIIROIT AIUPITB ffi REPIORT
GC/IIS Semivol.atil-ee
C1ient Ltlt *. - - r
f,e$ Iot-Saryfle*:
Prgp Date------l
Prep Batch *- - - 3
Dil.utLon Factor:
PAIU{METER
Ds r 02023 0
Dsr070000-43s
oe/a7/os
525043s
1
Ilork Order *---3 HJ4RK1AC
Ana-Iysie llate. . 3 09 / B / A5
ena-lyal.e Tl-me. - r 18 :50
t{atri:r--. --. r- o: WATER
Perrta.chlorophenol.
L 12,4-Trichl.oro-
benzene
2,4-D{nl trotolueue
2-Chl-orophenol-
4 - Chloro- 3 -rethylphenol-
4-Iritrophenol
nsannFhthen.e
II -I5l- t rosodi -n - prropyl -
amlne
PhenoI
Pyrene
L,4-Di&I.orobenzelne
Lr4-Dioxane
ST'RROGATE
2 - Fluorobiphenyl
2-F1uorophenol
2 , 4 , F-Tribromophenol
Nl-trobenzene-d5
Phenol--d5
Terphenyl -d14
rya!ry(s):
PERCTMT
RECO\IERY
74
75
81
a2
78
69
78
76
82
74
7A
73
RECO\MRY
LTMITS
(r+ 111)
(se 101)
METHOD
(ss
(58
(sg
(rs
(66
(sz
lot
(69
(ss
(sg
10s)
108)
1071
LLZI
1061
102)
107)
1oe,
es)
1I-e)
PERCEMT
RECO\IERY
74
70
7L
73
73
74
sH846 827Ae
sil845 8270C
8W846 8.270C
sr845 8270e
9u845 8.27oC
gn846 8270e
9w845 8.270e
sE8{5 427o,C
sH846 827oC
srr846 8.270C
sH8{6 8270C
sH846 A27o'C
RECO\TERY
LIMITS
(6+ 104)
(sz 103)
(sz 111)
$z 102 )(61 101)
(os Log )
o
Crlculetions are pcrformed before rounding to woid round-off errors in catculated rcsutts.
Bold print denotes slntrol paran)ders
STL Denver 7L7
ITABORATORY COI$TROL gAHgtB DATB, RBORT
glclus Smlwo]-ati].es
C1ient f.ot #, - -:
ICS I.ot-Sa1ple#:
Pref, Date- . G - - - 3
Prep Batd' f,- -.:
Ot-lution Factor:
PARAMETER
D5I02 023 0
Dsr070000-435
0e/07las
525043s
1
Hork Order #- -
.eual.ysis Date-
Ana.lyele Tl,.De-
HJ4RKl.AC
oe/L3/as
18 :5O
tfaf,3i'r--- ---3 WATER
PEREHVT
RECO\IERY METHOD
frentachl"orophmol-
L,2, {-Trictrloro-
benzeue
2,il-11ini trotolrrene
2-Chl.orophenol.
{ - Chloro- 3 -nethylpheno}
4-Isitropherol-
Acenephtheue
It- ili trogodl. -n-pro1ryrl. -
nmin(=
Phenol-
Pyrene
L, 4- Di ch-I-orobenzene
1, d-Dioxane
STTRROGATE
2 - Fluorobl-phenyl
2 - Fluorophenol
2 , 4 , i-Tribromophenol
witrobenzene-d5
Phenol-d5
Terphenyl -d14
rwrB(s) :
SPIKE
AIYIOITTIT
10. o
10-o
10-o
1(}-O
10-o
10-o
10_o
10-o
10. o
10-o
10_o
10-o
MEAST}RED
AII{OUNT
7 -40
7 -49
8-13
8.2+
7 -76
6 -92
7 -76
7-59
8.15
7 -!7
7 .03
7 -32
PERCEMT
RECO\IERY
74
70
7L
73
73
74
I'NITS
utglr,
u.glr,
u.gfr,
wlt,
rqg,lr,
Iug,lt
rugfr,
ruglr,
v-glr,
ruglT,
utg/t
urglT'
RECOVERY
I,TMITS
74
75
81
a2
7A
69
7A
-16
82
7lL
70
73
sH846 827o,e
sr8f,6 g.270e
9H845 8.27o,c
sw845 8.21o,e
sr845 8,27Ac
sr846 A270e
glt846 8270c
sH8{6 8210e
srrs{6 8270e
sw845 A270c
sr845 A270e
4rr845 8.27fJC
(0+ 1.04 )
lsz 103 )(st 111)
(ez 102)
(0r 101)
(es 108)
Calculetion$ arc pcrformed before roundin3 to avoid round-off errors hr celculatcd rcnrlts.
Bold print dcnotcs control peramotsrs
Denver 118
ffi C0illROL SIAUPI,B ETTALItrtrTIOIT RBPORI
GCAig Semirro]-ati]-es
Cf.ie.nt Iot #-. -:
LeS lot-Baryr1e*:
Prrcp Date,',---3
Prep Bat& #. - - 3
PLlution Finctor:
PARAMETER
D5r02023A IIorIr Order *- - - 3
D5I1-40000 -544
HKJ6SLAC-IrCS llatrj-x-, -, - - . - . : $IATER
HIGJ6 5lAD- IJC9D
oe/2t/as
18 :13
ae/Le/os
5257544
1
AnallraJ.a
Ana-lysis
PERCENT
RECO\IERY
79
73
72
6-l
83
81
82
80
85
82
,I9
'19
57
61
80
76
79
75
1A
68
77
73
RECO\IERY
LrI{ITS(sr es)(se es)(+z s-tl
(+t 8-ll(ss 101)(ss 101)(sr eel(s3 ee)(s+ 106)(5+ 105)(45 r.Og)(46 1oe)(sr e1)
(s1 eu
(+s 1oe)(+s r.oe)(so 101)(so 101)(s+ 111)(sa 111)(+e eo)
PERCENT
RECO\IERY
RPD
RPD IJIMITS METHOD
;lgenaFhthene
L, 4-DJ-ctrI Orobeuzene
{ - ehl.oro - 3 -methylpheno}
2-ChJ.orophenol.
2,4-Din.itrotol-uene
{-ilitrophenol-
II- Ni trosodi -n - propyl -
amane
Peutachl.orophenol.
Pherrrl
Prrene
L 12, 4-Trl.chl.oro-
benzene
SURROGATE
2 -Fluoropheno1
Phenol-d5
Nit,robenzene-d5
2 -E'luorobiphenyL
2,4 ,6-fribromophenol
Terphenyl -d14
7 -8 (O-28)
7 -4 (o-so)
2.6 (O-Ze)
2 -9 (O-38)
4 -7 (O-30)
a -L7 (O-53 )
3 -5
5-6
4-4
2-7
5.5
RECO\jlERY
IJIMITS(s+ e4 )(s+ e{ }(ss L01)
( ss 101 )(se e7l(s6 e7l
(as es )(+r es )(s+ 1-10)
( s+ 1-l-0 )(sz 121)
srrs{6 8.274e
sH8{6 8.270e
srr8{6 8270e
sfl846 827o,c
B11846 A27o,C
sr8{5 827o,e
s:rr845 8270e
grx845 8.27o,c
911846 827o,C
911846 827(}C
g11846 a27o,c
911846 827o,C
srr845 8270c
(o- zrl slr845 e.27oe
srr846 8270c
(o-so) grx845 a27oe;
sr846 A270e
(o-35) sr8{6 8.270e
sw8{6 8270e
(o-33 ) g11846 a.27oe.
s'rr8{6 8.270c
(o-44) Srr845 8270c
73
-70
78
74
75
72
71
69
BL
80
73
(Continued on nexL
STL Denver
page)
119
ffi COIITBOL SAIITPT,B E\TELTI TIOIT REPORT
etr.ltqB Benirrol.atiles
Clieut Iot *- - -:
ICS Iot-gaq)Ie#:
SURROGATE
D5I02023 0
D5I140000 -544
Ilork Order *. - -: HKJ56LAC-IJCS tIatsri-xo, ?, r,, - -.: $IATER
HK,J5'6lJ\D-LCSD
PERCEMT RECOVERY
RECO\IERY IJIMTTS
7L (sz LzLl
IIOEE (TI) :
Calculatiorls arc perforrned bcfore rounding to avoid roundoff crrors in calculated results.
Botd prlltt donotes control p&renretero
STL Denver 1,20
ITABONAT'IORY @ITA?OL ST}IPIIB DAEA NBSORT
@firg Senivolati].es
D5I02O23O ltrork Order l-.-: IIKiI661AC-LCS lNatrlx- ---: WATER
D5r140000-544 HrGJ651-AD-r,CSD
Cl.ient Iot *- . -:
ICS lot-gaq)Ie*:
Prep DateD,o-.-i
kep B&tch *,. - 3
Di]-utsion Faetor:
PARAT'IETER
oe/L4/05
5257544
l"
Ana-lyel.e
AnaJ.ysig
oe / 2L/ os
18:13
gPTKE
AIT'IOUMP
MEASI,IRED
AIqOUMT T]NITS
100 78 _5
100 -f2 -7
100 72 -5
100 67 .3
150 L25
150 L22
150 1-23
150 119
100 85-5
100 8r- - 7
150 119
150 r-19
100 66 -6
100 54 -3
150 120
150 11{
150 118
1-50 113
1(}0 69 -g
100 68.1
100 77 -5
100 73 -3
1g.g/t
u.glt,
u.gfT'
ug/r
u.glT'
u.gfr'
tuglT,
urglr'
utglI,
u.glt
u.glr'
u.glr,
urg,lT,
u.glr,
u.glr.
wlt
ugf t'
u.slr,
u.glT'
ruglr,
ug,lT,
ruglr,
PERCENT
RECO\TERY
PERCEMT
RECOVERY RPD
79
73
72
6z
83
BI.
82
80
86
82
79
79
67
64 3-5
9w845 A270C
s"w845 8270e
9H845 A27o,c.
s'r846 8.27o,e
91846 8270e
5Tr845 8.270c
grr845 a270,c
9n846 8.27o,c.
sr845 8.270e
9r{846 A270c
Brf845 8.27o,e'
8rr845 8.27o,c'
sH846 8270e
sr846 A27Ac.
srr846 a270C
sH8{6 8.210e
sH8d5 8.270e
srr846 8.210e
art8{5 A270e
9n846 8.27o,c.
Brf845 A27AC
METHOD
Acenafhthene
L,4-Di&Iorobenzene
4 - Chloro - 3 -retJryl.phenol-
2-Chloropheuol.
2r4-Dinitrotol-uene
{-ilitrophenol.
N-Ilitrosodl- - n- propyl -
nmine
Penta&IorophenoI.
PhenoI
Amene
L,2, {-Trichl-orrr-
beuzene
STIRROGATE
2 -Fluoropheno1
Pheno1 -d5
Nitrob ertzene- d5
2 -Fluorobiphenyl
2,4r5-Tribromophenol
Terphenyl -d14
73
7A
78
74
75
72
73
69
8L
80
73
(Contl-nued on next
'l -8
7.4
2.6
2-9
4,.7
o. r-7
5-6
4.4
2_7
o
80
76
79
75
70
68
77
73 5-5
RECO\TERY
LIMTTS(s+ 94)(s+ e4)(ss 10r )(ss 101)(se e7l(se e7l(al es )(+s es)(s+ 110)(s+ L1.0)(sz 12r")
STL Denver
page)
3_24
ffi CONTROI, SAHPIJE IIATA REPORT
(Jf,,lrr9 S€d\rolatl-lea
Client Iot *- - -: D5IO2023O rork Order *- - -: HKJ651AC-IJCS liatrix,- -..: WATER
ICg Lot,-Saryrl.e#: Dsf 140000-544
SURROGATE
rrcfr (s) :
HK.f6 6IAD-ITCSD
PERCENT RECO\IERY
RECOVERY LfMfTg
7L (sz L21)
Calculatlors f,re performed bcforc rounding rc lvoid rourd+ff €rrrors in calculated results.
BoH print denotcs control parErnorcrs
STL Denver 1,22
TATRIT SPIre SAI{PIIE EIIILTIITTION RPIORT
CC.firB Seluivo1ati]-es
Cl-ient Iot, $. - . :
Us tot'-Balp1e *:
Date Saryll.ed---i
Prep llatg? ,. - - - !
Prep Batch #- - -:
Dil.utl.on Factor:
PARAMETER
D5r02A23A
D5r020230-004
ae / aL/ as 12: 1o
aela6/os
s249103
1
Work Order #- - -:
Date Recelrred- - l
ena-lysl-a llatre- - 3
.Bna-Iysis Ti-re, - 3
H.IVQ9lDF-I{S
H,.n7Q9IDG-MSD
oe/02/os
ae/La/05
OL:47
llafii-:- - - . . - - - - l GI{
MEfiIOD
PERCENT
RECO\'IERY
RECO\TERY
TIMITS
RPD
RPD TJTMITS
lgennfrhthene
L,4-Dl-ch-I-orobeu.zene
4 - ehl-oro - 3 -metlryl-pheuol.
2-Chlorophenol-
2 rl-Dinitrotol-uene
4-Nitrophenol.
II-Nit roeod.l - n-propy1 -
amine
PeutachIorophenol-
PIrenoI
Ptrrene
LrT,4-tri&J-oro-
benzene
SURROOATE
2 - Fluorophenol
Phenol-d5
Nitrobenzene-d5
2 - Fluorobiphenyl
2,4 ,i-Tribronophenol
(lE 1o3 )(ls 1o3 )(t2 el)
Gz eI.)
(ea L22l
(ta Lzzl
(*z 10s)
(+t 10s)
(so Lr-3 )(so 113 )(35 123 )(36 1-23 )(4s 1OO)
(+s 1oo)
(2e 130)
lzg 130)
(+z LaTl(.*z r_o7)
(rg 13o)
(rg 13o)
(+r e7l
(41 e7)
PERCEI{:T
RECO\IERY
77
84
78
86
79
81
73
77
77
92
(Continued on next
74
80
v6
79
7A
91
80
86
8s
lo5
85
111
75
77
85
110
75
a2
46
62
77
81
6 -1 (O-42li
2 -4 (O-{?)
I-s (o-70)
6 -2 (O-58)
2t (o-44)
27 (O-73 )
sw8c5 a270ci
sn845 A27(}C
sH8{6 8270e
sr846 8210e
8H845 A27o,e.
sH8r6 A270c
srr846 8270e
sr846 8.270e
srr846 az-7o,C
s"tr845 a27AC
gtr845 827o.e
9w845 8.27fJc
9w846 8.270C
sw8{5 a27o.c
g11846 a27oc
s'tr845 8270C
srr845 aaTilg,
sw8{5 a270e
sH846 8,270e
srr845 a2l0e
9w845 8274e
2-{
23
7_7
2A
4-3
(o-sr)
(o-ss)
(o-71)
(o-s3)
( 0-46)
RECOVERY
TTMITS(es ezl(as e2)(4e e8 )(eg e8)(so ee)
(s o sel
(43 el)
(43 el)
(es 113)(ae 113)
STL Denver
page)
1-23
TATRET SPIre SJET.iPLB M REPiORT
Cl1errt Iot *. . - :
HS tot-garyfle *:
gT]RROGATE
D5r020230
D5r020230- 004
ec/Ms Seuhrol-atl-]-es
Ilork Ordelr *- - - : H'X/Q91DF-MS, }htri:r. - - - - - - . . 3
HWQ9lDG-tr{SD
PERCEIUT RECO\TERY
RECO\TERY LIMITS
( ro 1s0)
( ro 1s0)
Terphenyl -d14
IW[B (s)
=
L4
33
Calorlations arc perforured beforo rounding to avoid round<rff errors in calculatod results.
Boftl print denotcs control perrmolgr8
724STL Denver
I,BI?IX SPIXCB SIUilf)r.E IIAf,L RBPORT
er.file Seniwol.atil.es
Client Ipt #---3
UA l.ot-garyll.e *:
Ilate Baryrl.ed---3
Prep Datgoe ,-.-3
Prep Batch *- - -:
Ill-Iutl-on Factor:
PARAMETER
DsI 020230
Dsr020230-00{
oe / oa/ as 12 :1o
ae/oG/os
s249 r.03
L
Ilork Order *. - - :
Ilate Recefired- - !
ena-Iyel,a Date. . !
Anal.lmLs Tl-re- - i
HWQ9IDF-MS
HJVQ9lDG-MgD
oe/azlas
oe/La/os
AL:47
I{atrix----,--..3 GW
I{ETHOD
SAII{PIJE SPIKE
AMOUMT AM:r
ND 1I.O
IID 109
IID 11O
ItD 109
rrD 155
ITD I-54
ITD 165
ITD L64
ITD 11.O
IID I-O9
ITD 165
ITD L6,4
ITD 11O
ME..A.SRD
AIUOT]NT I]NTTS
81- 3 agll'
85.8 rugll'
83 - 8 ruglt'
85 - 9 utglt
L29 t:tg/I'
LLe \gfr,
132 lugll'
14I- ury,lr,
93 - o luglr,
115 ruglf,
139 lurglr,
Laz luglt
8? - 5 ug/n
PERCaIT
RECVRY RPD
acenephthene
t, 4 -Dl.chl.orobenl=ne
4 - ehl-oro- 3 -retlr1rlphenol-
2-Ch1orophenol.
2 r 4-DiniLrotolueue
4-Irl.troplreuol.
It - Ni trosoCl -n-propryrl. -
amine
Pentachl.orophenol
Pheuo].
Pyrene
L,2,4-Trieil.oro-
benzene
74
go 6-4
76
79 2 -tL
78
91 1_5
80
g5 6-2
85
106 2L
85
111 27
75
g11846 a27o,c
sr846 8.270e
glr845 A270C
91845 827o,C
Brr845 A21o,C
sw8{5 8.270e
slrg,{6 o.270c
sn846 A270e
811846 8.270e
sI58{5 8.270e
sr846 A270e
sH8{6 8.270e
sr8{6 a270c
77 2 -4 SH8{6 AZ70e
86 SIr845 8.270e
110 23 SH845 8.27o,e
7s sIrS{5 A270e
82 7 -7 SH846 8.21Ae
46 Str845 8270C
62 28 9n846 8270C
77 srtI846 8270C
81 4-3 SrrB{5 8270e
RECO\IERY
IrIMffS(+s ezl
(4S g2'l
(4e e8 )(+g e8)(so ee)(so ee)
(43 e 1)
(at el)(ae 113 )(48 1,L3)
r-o9
155
154
155
15{
110
109
110
r_o9
8{. {
L42
L7g
L25
r-35
50-g
6T.L
g5_o
gg-g
PERCEMT
RECOVERY
77
84
7B
85
79
81
73
77
77
92
(ContJ-nued on nexE page)
l{D
IID
ND
ND
IID
ND
ND
ru.glr'
rugll'
:ug/r'
urglr,
lu.glt
1u.glt
rng,fl'
ug/L
]u.glL,
SURROGATE
2 - Fluorophenol
Phenol -d5
Nitrobenzene-dS
2 -Fluorobiphenyl
2, 4, G*Tribromophenol-
STL Denver 1,25
}trTRIT SPTffi SAriPIlB DATJB. RBPORT
Gf.ltqB Benivol.ati].es
D5I02O23O lIork Order *- . .: H,J\IQ91DF-II{S
D5r020230-004 HinrQglDG-MSD
frlatri-x- - - - - - - - - : GIi[Cf.ient lot *---:
li$ Iot-8al5tle *:
SI]RROCATE
PERCETTT
RECO\IERY
L4
33
RECO\IERY
IJTMITS
( ro 1so)(ro 1so)
Terphenyl-d14
rwfB (s) :
Calculations are pcrformed bofore rounding to avoid round-off errors in catrcttated results.
Bold print denotes control paramcters
726STL Denver
IATRIT SPIIG SJEHPIiB ffi REPORT
Gf.l>B Semftrolati1eo
Cl-l.ant Iot #- - -:
ItrI Iot-Saryll.e #:
Ilate Saq)Ied,---3
Flaep Dateo---.-!
kep Batch *.. -:
Dil.ut,ion Factor:
PARAMETER
Dsr02023 0
D5r020230-004
ae / 0Llos 12: Lo
oe/07/os
5250435
I
Work Order *- - -:
Date Recelved- - r
Analyeie Ilate- - !
aual-ysLg Tl-Ee- - 3
HirvQ9lDH-MS
HWQ91D'J-tISD
oe/02/os
oe/::los
2L=47
Itlatrl-x--- --- ---: GFil
METHOD
Pentachl'oropheno1-
Lr2r4-frichrsao-
benzene
2,6-Dlni trotol.ueue
2-Chlorophenol
4 - ehloro - 3 -ilEthyl-pheno1
4[-I5l-trophenol.
Acenaplrthene
I5-H1tr<rsodl- -n - propyl- -
amine
Pheuo1
Plmeue
a,4-Dichl-orobenzene
SI'RROGATE
2 -Fluorobiphenyl
2 -Fluoropheno1
2,4 ,5-fribromophenol
lgltrobenzene-d5
Phenol-d5
62
5s
74
7L
73
16
74
73
72
70
(continued on next
LO2
LO7
7L
68
-12
75
79
75
83
83
110
r_o4
66
69
77
73
79
78
40a
44a
6s
62
PERCE![T
RECO\IERY
RECO\IERY
P..IY-IJS(43 1s9l(ts lse)(ss ee)
(se ee)
(oz r"oe)
(62 l.oe)
lez 108)
162 r.o8)
(er 121)
(or 121)(ar r.zs)(er lzs)(az 1o4l(62 r-o{}(sa 11o)
(sa a1o)
(ez 11o)(sz 11o)(sz 110)(sz 110 )(ss es)(ss es)
PERCEMT
REgg\rERY
RPD
RPD LIMITS
o - 25 (o-5o)
'l -l (o-44)
f--1 (o-ez)
7 -2 (O-38 )
2 -6 (O-28)
gw846 8270C
sw8{5 a27o,c
sn846 8.270C
8rr845 8270e
sr8{5 8270c
gr{846 827o,e;
sH845 827Ae;
srrE{5 8.274e;
sn846 A27o,C
8r{845 Az7fJe
8H845 827oe
sH845 827(}C
sw806 a27o,c
sH846 827o,C
g11846 A270e
9n846 8-270e
srr846 827o.e
g18+6 8270e
srr846 8270e
9H845 8.27o.e
801846 827o,e
9-2
1--O
8-8
5-4
5-1
'l -2
( o-s3 )
(o-28)
(o-271
( o-s5 )
(o-rs )
(o-so)
RECO\IERY
TTMITS
(gg L15)
(sg 116)
(22 10e)
(zz loe )(zs 726)
lts t26t
(3s 114 )(38 r14)
(gz 106)
( sz r"06 )
STL Denver
page)
127
laLIB:tI, SPIXB seItISIlE BI'EI{IATIOIT REFORT
@fi$ EemLvol.atil.eo
D5I02023o llork Orrder *. - -: HlrvQglDH-MS! llatru- ., -: GliI
D5r02O230-O04 Ir.JVQ91D,I-MSD
C1ient Ipt *- - - 3
uA lot-Baryll.e #:
ST'RROGATE
PERCEIIT
RECO\IE:RY
L7
2L
RECO\IERY
IJIMf Tg
(tt L42)
(tt t42l
Terphenyl -d14
rrcrrB (s) :
Calculations tre pcrforrnecl before rouding to avoid round-off erron in otlarlatod results.
Bold prlnt deooms oontrol paranrgers
a Spiked anelyte recovcry is outride eteted control lirnits.
STL Denver t2B
O}trIRIT SPIffi AAUPI,B DATtr RBPORT
GCAi.s semirrcI-atil.es
elient, Lot #- - - :
lt8 lpt-Saryl1e *:
Date Eaqll.ed---3
Prop llatg-D----!
Prep Batch *- - -:
DLlutiou Factor:
PARAMBTER
D5r020230
Dsr020230-O04
09/o:-/os 12:to
oe/a7/os
525043s
1
Uork Order *. -, !
Ilate Reeeived- - 3
Anal-ysie Date- - :
Analyeis firne.-3
HJ\IQ9IDH-MS
HWQ9IDT-MgD
ae/02/as
ae/L3/0s
2L:4'7
r.Iatri:ro , , , - - - - - : GUI
METHOD
SAIUPLE SPIIG
AI',IOT'}TT AIVIT
IID 9-8O
ITD 9.49
ND g-go
ITD 9.49
MEASRD
AI,TOUMT UNTTS
PERCNT
REC\IRY RPD
Elentaehl oropheno].
Lr2r4-Ik:.tchl.oro-
benzene
2,F-Diuitrcrblueue
2-Chloropheuo1
-{ - ChJ-oro - 3 -methylphenol.
4-lfitropheuol"
Aeeuapht,heue
n-ilt trosodi -n-proglyl- -
amlne
Pheno1
Plmene
1r 4-Dlchl-orobenzene
SURROGATE
2 -Fluoroblphenyl
2 - Fluorophenol
2,4, 6-Trlbromophenol
Nitrobenzene-d5
Phenol-d5
10-o
10-1
6.92
6 -{5
9.80 7 -O4
9 -49 7 -L2
9-go 7-78
9 -49 7 -?i'.
9-80 8-10
9 -49 7 -89
9-80 Lo-g
9 -49 9,83
g -go 5-46
g -49 6 -52g_8(} 7-55
9,49 6 -92
9-80 7 -77
9 -49 7 -37
9.80 3 - 93
9-49 +-18
g-go 5-36
9 -{9 5. ga
PERCENT
RECo-vrE-BJ
62
65
74
7L
73
76
74
73
72
70
(Continued on next
rng/r'
rcglr'
wg/t
u.glT'
u.glt
u.glr'
utgll'
ug/r,
Iuiglt
Itr.gfIJ
qglr,
Wlt
luglT,
ug/r,
ug/r,
utgfr,
IugfL.
u.glr'
ro.glr,
utgfL
ruglT,
Iuslr
102
LO7
7L
72
75
79
-16
83
83
11()
10t
66
59
77
-13
'19
7g
4(} a.
4*a
6s
62
RECO\ZERY
LIT{TTg
58 7 -L SrrE{5 A270e
sH8{5 A27o,c;
o -75 9H846 8270e
g11846 827o,e
gn8{6 a270e
1-1 SW8{6 8.270e
g11846 8270C
7 -Z SH84[6 A27AC;
sr845 A270C
2 -6 sr1846 8.27o,c
sn845 A270C
9 -2 sr845 A270C
911846 8.274e
1- O 6'11846 A270C
sH845 8270e
8-8 sr8{5 A270C
g11846 827Ae,
5 -4 915845 8270,e
sH845 827o,C
6 - r- sr846 A27AC
slr846 8.270e
7 -2 glr845 8.2-lOC
ITD
ITD
rID
ND
ND
ITD
IID
ITD
}ID
IID
ITD
IID
ITD
ITD
ND
ITD
ItD
ITD
(ag 115)
(gg 11G)(zz 109)(zz 1-0e )
Qa 1'26)
(a s 126l
(rs 114)
(sa 114)
Bz 106)
(rz 106)
STL Denver
page)
a29
elieut tot #- - - 3
ug lot-sanple *:
gURROCIATE
T'tAIXIf, 8PIKE SADTPTiB DA'f,B. RBPtORjf
Gf,.ftt9 BemfurcI-atil.es
D5I020230 Hork Order *- - -: HIT\/Q91DH-II{S
D5rA2A23O-OO4 H.I1IQ91D,-MSD
PERCENT
RECOVIERY
liatri:r- - . - - - - - . 3 GW
L7
2L
RECO\TERY
LfIvIITS
(tt L42l
Itz 1,42)
Terphenyl -dI-4
rufB(s) :
Calanladono aro pcrformod bcfore roundlng to avoid round-ofF crrors in cclcrrlatod rosulm.
Bold print derrotcs oontrol peramctens
z Spikod annlyte r@very rs outside slf,t€d control limits.
STL Denver 13 0
IIIETHOD BTAITK NBPORT
TOtrAIr tleta.lg
Cl.ient lot
PARAIyIETER
D5r02023 0
RESIIITT
REPORTING
ITIMIT UNITS
S- -, 3 l,Iatri:rr , - - - - - - - 3 TTATER
PR]EPARATION- WORIC
A}IALYSIS DATE ORDER #D,IETHOD
lm lot-garyr1e
Cadmium
Bariurn
Calcium
Chrornium
Copper
Iron
Lead
#: D5I050000-515 Pnefi Betch *-.
ND 0. 0010 $rg/L
DiluEion Factor: 1
Analyele Time. . : 07 ;1-'l
ND O.0A2O nry./n
PL1utlon Fact,or: 1
analysis Tima. . : 07 tL-l
SeIenj.um
uB lot,-Sarylle *: DsI050000-6L7 Prep Batch *. -Alumlnum ND O - 10 rng/L
Dilution Eactor: 1
Analysla TLmo. . : 15 ; 1.9
ArsenLc sw846 5 0108 09 / 15 - 09 / L6 / 05 H,r2,r.r0.015 mg/L,
Dilution Factor: 1
enalyoig Time..; 14;13
0.010 mg/I'
Dilution Factor: 1
AnalyaLo T!.trte. . : 14 : 13
0.20 mg/T.
Dl-lutton Factor: 1
Analyola Time--: 15:19
0.010 mg/L
Dj.Iutl-on Factor: L
Analyoie Time. . ; Lrl : L3
0.010 mg/L
Dilutlou Factor: 1
Analyale Tj"me-, : 14 : 13
O.l-0 ng/I'
Dllutl,on Factor: L
AnalysLs TLmo. . : 15: L9
0.0030 ms/L
Dilution Factor: 1
Analygia Time..: 14:13
(Continued on next
s249516
sw845 5020
sr{845 6020
52496L7
sw845 5 0I-08
svr846 50L0B
sw846 50108
sr{846 60L08
ae / 1s - ae / 23 / os H'J2{IG1AA
09 / 1s - 09 / 23 / Os H,J2JG1AC
a9 / 1s - 09 / LG / os HJ2.],J1AC
oe / r.s - oe / rG / os HJ2J.T1AB
oe / 1s - oe / L6 / as HirzJirlAM
a9 / 15 - A9 / L6 / 05 H,J2,JJ]-AF
1AD
o
ND
I.UD
oshs-oslrclos
sw84 5 50108 09 / 15 - 09 /LG / os H.l2rfrfl-Acl
sw846 60108 oe / r-s - oe / L5 / os HJzJJIAN
9![846 60108 HJ2JJlAJ
STL Denver
I{D
page)
131
ITIETTIOD BLEilK RMORT
ItUtrAIr lrieta,Le
C]-ient' Iot
PARAMETER
: DSIA2O23O
RESTIIJT
REPORTING
IJIMIT UNITS METHOD
lrlatri:c- . - . - - - - - 3 WATER
PREPARATION- TIIORK
AI{IAtYSTS DATE ORDER #
llagnesLum
NlckeI
Pot,assiurn
gLlver
Sodium
Vanadium
Zirconium
l,IB lot-saryl1e
Mercurlr
HB lot-Saqrle
Mercury
o-o51 B
ND
ND
o-20
Dilution
Analyel-a
o.040
DlluEl.ou
Analysis
3.0
nllutlon
Analyele
0.01_0
Dilution
Analyaie
5-0
DLlutl-on
Analysls
o.010
Dllut,ion
Analyaia
0,020
DLlution
Analyaie
0.015
DLlution
Analyeie
wlt'
Fact,or: 1
Tl-me-. : 15:19
trtg /T-,
Factor: I
Tl-me-.: 14:13
mg/t
Factor: 1
TLme. -: 16:19
mg/t,
Factor: 1
Tl-me..: 1{;13
mg/t
Fact,or: 1
Tl-me-,: 17:14
mg /r'
Factor; 1
Time. - ; 1{:13
mg /t,
Fa,etor: 1
Timg..: 1{:13
nlg/L
Fector: 1
Time- -: 15:l-9
IqD
g11846 60r_08 oe I Ls - oe I Ls / os rr^rzirfi:to
sw846 50108 oe / Is - 09 / LG / os H,J2irJlArI
sw845 50108 a9 / 1s - 09 / LG l os HJzJ,ylAP
sw846 601-08 oe / r.s - a9 / 16 / os HJ2ir.TlAA
ND
rqD
ND
D5II"50000-348 Prep Batch fi- - . i
O.0OO2O mg/1,
Dllutlon Factor: 1
Analyaie TLme, . : LG: ZB
D5f190000 -496 prep Batch f,-, ,:
sw846 60108 ae / 1s- 09 / L6/ os HJ2ir.TlAT
sr{846 60108
sll84 5 50108
sw846 60108
52 5834 I
sw846 7470A
5262496
slr846 747AA
09 / l.s - a9 / Le / os H,J2JJ1AR
oe / Is- oe / L6l os Hir2iriruAK
09 / 15- ae / L6 / os H,Jzirrl.ut
ae/Le/os HKMDIJ].AA
HICWl91AA0.00020 rrry,ll,
Dilutiou Factor: 1
Analyeie Time..: 19:20
STL Denver
ND
(Continued on next page)
oe / 221 as
]-32
UETTIOD BIJEITK REBORT
TCrTAL Hetal-s
Cl.ient, tot *-,,: D5I020230
ncrB(S):
Calolations ate performod bcfore rounding to evoid rouud-off errorc In calculattxl rwults.
B Estlmatod resuh. Rcsrlt Is tess than RL.
STL Denver
W COIIIROL S,BUPLB BIIAI{IATIOIU RBBOR,T
I!oTAL lrteta.lg
Iot-Saryll.e
PAR;AMETER
Mercrrrlr
Mercury
D5r 020230
PEREMUT REEOVERY
R_ECO\rERY r,IyrTS RPp
Hatri:x- -- -- - - - -: WATER
RPD
IJIMITS METHOD
PREPARATION_
A}IAIJYSTS DATE
PREP-
BATEH #
525 83 48
52583,{ I
s252486
s262486
98
101
(8s 1.14)
(8s 114) s.g (O-L0)
DLlutLon Pactor: 1
(es 114)
(8s 114) L.2 (o-10)
Dilut,l-on Factor: 1
9w846 7470A
sw846 7474A.
Analyele TLme,. r
sw845',l470A_
sw846 74704
Ana1yaie Time. . :
oe/Le/os
oe/Le/os
15:33
oe/22/os
oe/22las
L9:2L
rwfB (81 :
Calctlatlotrs tre performod bsforo rounding ro rvold rormd<rff etrors In crlcularcd resulo.
STL Denver L34
W CoIraBOL gAHPf,E DATA REFORT
IU.IAL Ueta.I.o
Iot-Saqrl.e *- - - 3 D5I0zO23o
SPIKE MEASTIRED
P.ARAI{ETER ATUOIINT }MOmm
Mercury
Dlatri:r- - - . - - . - - i Wl\fER
I]NTTS
PERCNT
RECVRY RPD METHOD
PREPARATION-
AMITYSIS DATE
PREP
BATCH #
s25834 I
52583 4 B
52624A6
s262486
0.00500 0.00499
0.00500 0. 00505
0.00500 0. 00518
o . 00500 0. 0 a512
mg/L
mg/T'
DLlut,ion
mg/I'
mg/T'
DL]-ution
9B
L01
Factor: 1
104
102
Factor: 1
9w845 7470A
3 ,3 gWB45 7470A
Analyaie TLme..: 16:33
sw845 747AA
L.2 SW845 7470A
Analysie Ti[re. . : L9:2L
oe/Le/as
oelle/os
oe/22/os
oe/22/os
Mercury
ITCITE (S} :
C-alcurlations are performed before rounding to rvoid roundrff orron in calculrted resulu.
STL Denver 13 5
W C:OWIOIr S.AITIPLB EIJ7ILIBTION RBtrORT
TqfAL ;66er s
C]-iett Iot
PARAMETER
D5r02023 0
PERCETT RECO\IERY
RECOI,ERY ITfMITS
100
100
liatrL:r- - - - - - - - . : WATER
PREPARATION-
A}IAIJYSTS DATE WORI( ORDER #
I,CS lot-Saqll-e*: D5I06000O-516 Prep Batdr #. - -: 5249615
cadmlum 99 (89 110) Sw845 6020
Dilutlon Factor: l.Analyal-e
Selenium (82 LL2) sw846 6A2A
Dilution Factor: 1
ICS lot-Baryrle*: D5fO60000-617 PTep Batch *- - -: 52496L7
silver 99 (ss - r.14) sws45 60108 og/ts-og/L6/os gJ2J.rlAu
Dllutl"on Faetor: L Analyeie Tl,me. -: 14:18
METHOD
oe / 1s - ae / 23 / os HJ2JG1A[
Tlme..: O7=2L
oe / ls - 09 / zt / os HJ2JcIAE
(eo 108) sw846 50108 ae / 1s - 09 / L6 / os H'JziIJt AV
DilutLou Faetor: 1
(sg L0e) sw846 60108 09 / ts- oe / LG / as HJ2iru1Aw
Dilutiou Factor: 1
(gr 113 ) SW845 60108 ae / 1s - 0e / L6 / a5 HJ2.r,r1A)r
DLlution Factor: 1
(sg LL2) SW845 50108 09 / 1s - 09 / i-6 / as H\r2,JJlAo
Dl-Iut,lon Faetor: 1
(eo 110) sw846 50108 oe / Is - oe / L6 / as HJzJJIAr.
Dilutlon Factor: L
(go 110) sw846 60108 a9 / 1s - a9 /15 / os H.t2,J'JlAz
Dllutiou Factor: 1
(gr 111) SW846 60108 oe / ls - 09 / L6 / a5 HJ2,J,]LA3
DLlut,l,on FaeEor: 1
(ee LLz) SW8{5 60108 oe / r-s - ae / 16 / os HJ2JJ1A4
Dllutl-on Factor: 1
(es 110) sw846 50108 09 /t-5 - 09 / rc / as H.r2.r.f1A,5
Dilutlon Factor: L analyeia Tl,me. . : 14 : 18
(0q - 110) swgd6 60100
Dllution Factor: 1
AlurnLnum
Arsenie
Barium
ChromLurn
Copper
Nieke1
Vanadium
zinc
CATC1UM
STL Denver
(Continued on next page)
oshs- oe l Le l aB IIJ2JJ L\6
135
Cl.lent Iot
PAR.AMETER
Iron.
PotassLum
Flagnesiunr
Sodium
ZLrconium
Ncrrts(s):
Dsr02023a
PERCENT
RECgyERY
96
1.02
98
95
108
RECOVERY
I,TMTTS METHOD
(aa 110) sw8{5
Dllut,ion Factor: 1
(ee 1Lt-) swg{6
Dil-ution Factor: 1
(gr 111) swg45
Dllution Factor: 1
(gr rr,z} swa45
Dl-1utlon Factor: 1
(zs 725) SW846
Dl-Iution Factor: 1
60108
nnal-yeLs
60L0B
Analyelo
501-OB
erralysJ.e
6 0108
Analyeie
50108
Ana1ysl,s
*- - -:
ffi @IIIROL SAIIPITE EIf,ALIATIOII
aUtrAL ltretal-s
RBPORT
llat.rix--- - - -- -. i WATER
PREPARATTON-
A}IALYSTS DATE WORK ORDER #
09 / 15- a9 / L6 / as HJ2.I,rtA"?
TLme. . : 15:2{
ogh s- oe / L6 / os HJ2,r,r1AB
Time. -: 16:24
ae / 1s- 09 / L6 / as HJ2J.JLA9
Time. . : 16:2{
09 /1s - a9 llo/os H,Jzir.rleA
TLne. . : L6:24
09 / ls- 09 / LG / os H,r2,f,f:.ce
Timc. . : 16:2{
Celculations iro performocl bctbre rounding to avoid round-off orror$ in calcutarod re^sults,
STL Denver a37
W COIIIROIi SIUPI'B DATjA REFORT
Il0trLL l.ietals
Cl-ient I.ot *- - -: D5I02O23O
SPIKE MEASI]RED
PARAMETER AI{OUNT AIUOUI.IT IrNfTg
PERCITT
REC\mY METIIOD
liatri:r- -, - - -. --: WATER
PREPARATTON- WORK
AIVAIJYSTS DATE ORDER *
SLlver
Aluminum
Arsenic
BarLum
Chroml-um
Copper
NLcke1
Vanadium
Zinc
Caleiuln
2 - 00 1.95
2.00 1 - 93
2.00 2 .oL
o.200
0 .250
0 ,500
0,500
o.500
o - s00
rcS Iot-Saqfle*: D5r050000-615 Pr,ep Batdh. *- - -: 52496LG
cadmium 0 .0400 0. 0394 rg/r, 99 sw845 5020
Dilutioa FBctor: 1 tnalyc{e Tine..:
selenium 0-0400 0.0362 rg/t 90 sw846 6020
DLlutlon Eactor: 1 AnaLyeie fime..:
rcS Iot-Saqrl-e*: D5IO60000-6L7 Prep Bateh f,---: 52496]..7
sw845 50108O - 0500 O . 04 94 tttg/t 99
DLlutLon Factor: L Analysis Time..:
sw846 6010B
Ar.a1yols TLme. , :
sw846 50L08
Analyeie Tl,Be. , :
9w846 6010B
Analyala Tl,me. - :
sw846 60108
Analyels Tlmc..:
sw8{6 60108
enalyeie Tirne. . :
9w846 60108
enalygis Tlrne. . :
sw845 50108
Analyeie Time. .:
sw846 60108
enalyels Tlme-. :
ser845 50108
Analyeia Tlme. -:
8tll046 60108
Analyols Tlme. . :
ffig /I'97
Dl.Iution FacEor; 1
mg/r,97
Pllutlon Faetor; t
mg /t,100
DLlutLon Fastror: L
o. l_97
0 .235
0 .491-
0,483
o-4gg
4.474
wlg/T'99
Dl-Iution Eactor: 1
rng / r,94
DilutLon Factor: 1
rns/L 98
Dilution Factor: 1
ng/n 97
Dilut,l,on Factor: 1
ms/L t 00
DLlution Fact,or r 1
mg/L 95
Dilutl-on Pactor: 1
ae / ls - a9 / 23 / 05 H.I2IIGLAD
O7:2L
oehs- ae I 23 / os HJz'JGIAE
o7 -.2L
09 / Ls- 09 / ts / os H.I2J-IIAU
14:L8
09 lls - ae / LG / os HJzJ,JIAv
L6:24
09 / 15 - 09 / LG / os H,r2\T.rlAw
14:18
a9 / r-s - 09 / LG / as HirzJ.rrAx
14 :18
ae / 1s - a9 / L6 / os Hir2JirlAo
14: 18
ae / 1s - 09 / LG / os HJ2JJ1A1
L4:LB
a9 / 15 - a9 / L6 / as HJz,J.llAz
14 :18
oe / i.s - oe / LG / os HJ2JJLA3
L{ : l-8
09 / 1s - a9 / LG / as HLf2.]J1A4
14 :18
09 / 1s- ae /aG/ os HJ2JJIAs
14 :18
50.0 d0. g mq/L 90 oehs- r,slrclor
17:18Dilution Factor: 1
STL Denver
( Contl-nued on next page)
IIJ2JJ1A6
13I
Cl.Lent rot
PARJAI{ETER
*- - -: D5f020230
SPf KE I-IEAfIURED
AMOUTM AIvIOT]NT
ffi CUITTROIT SAIIPLB DATzI' RBFORT
TC[f,Af, Hetale
PERENT
TINTTS REC\IRY METHOD
Hatrj:r- - - - - - - - - !
PREPARATION-
AIIAIJYSI9 DATE
WATER
T{ORK
ORDER #
fron
Potasslum
Magneeirrrn
Sodium
Zirconl-um
NcrfB (s) :
1.00
50.0
50.0
50.0
0.500
o -964
s0_9
49.1
47 .g
0.538
mg/L eG
Dllution FacEor: 1
mg/L Laz
Dilut,ion Factor: 1
mg/r, 98
Dilutsion Factor: L
nq /t, 95
Di]-utton Factor: 1
ms/L 1oB
DilutLon Factor: L
sw846 60108
enalysig Tlme. . :
sI{84 5 5 01_08
Analyeie TLme. ,:
sw846 60108
Analysle TLme. .:
sw845 50108
Analyels TLme. .:
sur846 50L08
Aualyala TLme. .:
oe / 1s - a9 / L6 / os HJziruL'"T
L6 224
oehs- 09 / aG / os H,r2irirlAg
L6 :24
a9 / Is - 09 / L6 / as HJ2LTLTIAS
16 :24
09 l1s - a9 / L6 / as HJ2,J,J1cA
L6 t2tl
a9h5 - 09 / LG / os HLT2iI'J1cc
L6:2tL
Calculatlons tro pcrformed bcfore rourrding to avoid rourld<ff error$ in colcuktrd rc$lo.
STL Denver 139
TililITIf, SPIXE SBIIIPLts BTAIJNLITOIT RMORT
Itc):felr Uetal-o
Clierrt Iot *---: D5IO2A23O
Ilate gary)Ied- - - ! 09 / oL/ oS 12 : 10 Ilate
PARAMETER
PERCET\IT RECOVERY
RECOVERY LIMTTS RPD
IIIII rot-Saryfie *:
RPD
IJIMfTS
L3s)
1,35) 1.5 (O-251
Pl-lutlon Factor: 5
AnalyslB TLmc..: 21:00
L29l
- 129) 3.0 (0- 25lI
Dilut,lon Factor: 5
Analyaie Tl-mo. . : 2L : 00
: og/az/as
I\mTHOD
llat,giv, - -. ! , ! . O : G[l[
PREPARATTON- WORK
AIIAITYSfS DATE ORDER #
CadmLum
Selenlurn
Barium
Calcium
Chromium
Copper
NC, Iv[gB
NC, MSB
Idg I.ot-8aryll-e *:
Aluml-num 90
92
Areenic
DSI02023A-004 rtep Batch #-
(sg 110)
(gg 1-1,0) 13 (O-20)
Pllut,lon Factor: 4o
Analysie Time, . : L2 :L6
LL2)
LLz) 8 ,9 (O-20)
Dilutlou Factor: {0
Analyele Time.-: L2zLG
(a+
(a+
(ss
(ss
50N
69N
L72 N
L49 N
L26 N
L2s N
103
1-03
L24
120
(82
(az
(tz
(zz
(az
(82
D5I02023A-004 Prep Batch #. - - : 52496L7
(gs 1i.9) swg46 60108
(as 1191 Z-Z (O-zsl Sw846 60108
Dl-lutlon FacEor: 1O
arralysl-e Tlme. . : A7 =32
a24l
L24) 1.2 (O-251
DlluEion Factor; 5
Ana1ysJ.e TirtrG., : 21:OO
L20)
12A) O.3o (O-zs)
Dilutl-ou Fector: 5
Analyele Tlme..: 21:O0
oe / 1s - a9 / 2z / as HirvQet-eg
a9 / 1s - ae / 23 / as HinrQg 1e9
ae /1s- a9 / zt / os HwQelDA
ae/ Is- ae/n/as HJlrQglDC
oe / 1s- oe / Le / as HiruQelDo
ae / ls- 09 / L9 / os H.rtreet Dl
09/ r.s - oe / L6 / os Hin/Qg LDz
ae / 1s- ae / L6 / a5 Hd\rQ91.D3
ae / Ls- oe /LG / as HWQeLD4
oe / r.s - ae l L6 / os HJVQeIDS
oe / ls- ae / Le / as H.JvQelcR
oe / l-s - 09 / L9 / as HirvQelCT
oe / 1s - oe / L6 / as Hiryee lcA
oe /1s- oe / L6 / os H.l\Ieelee
oe / t-s- 09 /L6 / os H.rvQelcD
ogh 5 - ae lrl I as Hfloelcn
-: 5249516
sw845 6A20
sw846 602A
svr845 5020
sw846 5020
slr846 60108
sw846 60L08
sw846 60108
sw846 50108
sur845 50108
sw846 5 0108
sw845 50108
sI{045 60108
( +g 153 ) SVir84 6 5 O l- oB
(ce 153) (0-2s't sri845 5o10B
DilutLon Factor: 1O
AnalyeLo Time. , : L7 t32
STL Denver
(Continued on next page)
140
Cl.Lent Iot, #--.r D5f02O23A
Date saryrled.- - -: 09/OL/05 LZzi.O Date
PARAMETER
PERCEhIT RECOTfERY
R.ECOVERY I.,IMITS ...- RPD
Iron
HAIRIT SPIre SAHPI,B EIT:ALUATTGI NEPiORT
TO|IAL Meta]-e
Receirred..3 og/o2/As
uatrfuco.-----..! Gw
PREPARAIION- [{ORK
AI.IAr.,YSIq_-DATE ORDER #
oe / ].s - ae / L9 / 0s H-nrQ91CU
oe / t-s - 09 / L9 / a5 H.n/Q9LCV
oe / 1s- oe / L6l 05 H.nIQglcH
oe / r.s- ae /L6/ os H.]l/Qg]-CJ
ae / 1s - 09 / Le / as HJt/Qe leo
oe / L5- 09 / L9 / as HiruQet.er.
oe / J"s- oe /L6/ os HJryQglcF
09/ :.s- oe/LG/os HiruQelec
oe / 1s - a9 / Lg / os HiruQs 1cril
oe / 1s - 09 / rs / os HinrQeLcx
0e / l"s - ae / L6 / as H.nIQelDw
09 / 1s - oe / L5 / os HiruQeLDx
ae / ]"s - oe lLg / os H(nIQe LCz
oe/ ls- oe/Le/os HJvQeLC3
ae /1s- oe /L5 / os HirVQeICK
oe / i.s - oe / LG / 05 HwQg lclr
a9 lLs-oglte los r{JvQelct{
ae / 1s - ae / L6 / os HflrQgleN
RPD
LIMITS METHOD
138
g7*
87N
LL2
1L0
r- o8
L25
L24
1L0
1-0 9
(sz lss )(se 1ss) s+ (o- zsll
Dilutioa Factor: LO
Analyele TLmo. . : L7 ;32
L21)
1211 zS (o-zsl
Pllut,Loa Pactor: 5
Inalyel-e Time. . : 21: OO
(8e
(sg
( es Lzo)(as L20) o
DJ.lution
Analyela
(50 137)
(00 L37 ) E
ollution
Analyeis
srf,84 5
sw845
6 0108
50108
Iread
Magnesirun
Nl-cke1
Pot,assirrrn
Silver
Sodlum
Vanadiurn
Zinc
NC, MSB (ZO 203 )
NC,MSB (ZO 203 )
Dilutlon
.Bnalyeis
sw84 5 5 0l-oB
sw845 50108
sw846 501OB
sw846 50108
NC, Ir,tSB $Z L4G ) SWB4 6 50108
NC,MSB $Z 145) (0-2sl SW846 50108
DlLution Factor: 1O
Analygle Tlme. - : L7 :32
NC,MSB 0e L32) SWB46 60108
NC,MSB fie l-32) (0-2s) SW846 60108
Di]-utLon Factor: t 0
Aaalyeto Timc. - ; L7 232
(8+ LzA) SW845 60108
(e+ LzA) r - S (0- 2s) SW846 5o1OB
DilutLon Factor: 5
Analyels Tlme-.: 21:00
(7s L41,) SW846 5O1OB(zs 141) 1.4 (o-25) srrl846 60r.08
Dilutl-on Factor: 5
enalyeie Tl-me, -: 21:00
(o-40)
Factor: L0
Tlme.. i I-'l:32
,55 (O-251
Factor: 5
Time-.: 21:00
.7 (O-251
Fact,or: 5
Tlme. . : 21:00
sw84 6
sw846
6010B
60L08
L2A
L24
sI^I84 5
sw84 6
601 0B
6 0108
STL Denver
(eontinued on next page)
t4L
ClI.errt Lot #. . -: D5IOZAZ3O
Date Saryll-ed- - - ! 09 / OL/ 0S 12 : 10
fielruf SPIKB SlUpIrB EIi:AI'IIATIOII RBPORI
I\OtAL liletaf-g
Ilate Recoirred. . ! a9 / az / OS
RPD
l{atrlx.- - - - - - r ? ? : G}t
PERCE} T
PARATIETER. RECO\rERI{
Zirconium L 0l-
104
Mercury 28N
28 N
RECO\TERY
LTMTTg RPD IJIMITS MBTIIOD
(eo Lzo) sw845 5o1oB
(80 LzA) 3.2 (O-251 SW846 50108
Dilutlon Factor: 10
Analyaie Tlme. . : L7 :32
(ss 1r_4) sw845 7470A
(85 11-4) 0.]-s (0-10) 9w846 7470}'
Dl-Iutlon Factror: 1
Analyals Tima-.: 15:43
oe/ 1-s- ae/Le/ os Hir\/Qelc4
09 / Ls - oe / Le I as HJ\rQe les
oe / Le / as HirvQelcP
a9 / 1e / 05 H'J1rQeleQ
PREPARATTON-
AT.IALYSIS DATE
WORK
ORDER #
lllg tot-Saryt1e *: D5f02023O-004 Prep Batrdr #- - -: 5258348
ncfE (s) :
Celculetionr rrc psrformcd beforc rouodkrg ro avold rouul+ff cnorg in cakuhod roeils,
N Spilrcd uulyrc recovery Is ouBidc slaed coDtrol lindis"
NC ltc rccovcry enrl/or11pp gsro rt cdorllttd.
IvISB The rccovery and RPD wcre not cEtctht€d bccare the samph snrmt was grcser dran four tlmeg thc spike enrount,
. Reletivc percant differurcc (RPD) is ourslro sstcd coilrot limir^
STL Denver L42
Clieut Iot f;---:
Date San[rl.ed---3
SAI{PLE
IA:[SIT gPIre S,B}IPLB DLT[, REPORT
aUtrAL Dieta]-s
Ilate Recelved- . ! 09 / a2/ 05
llatrl:r- - r - - . - - - : G$I
PREPARATION- WORK
AI{AITYSIS DATE ORDER #PARAMETER AII,IOUMT AI' T AMOUMT UNTTS
D5r020230
a9 / aL/ os L2:ta
SPIICE MEASRD PERCIIT
REC\IRY RPD METHOD
lI8 Iot-Sanpl-e *:
Cadmiurn
ND
Selenium
0.040
o.040
IUD
ND
Arsenic
0.o25
0-025
Bariurn
0.41
0 - 41-
Calcium
1.500
1500
D5I020230-004 Prep Batch
o . 0400 A . 0242 Eg /L
Qualifiers: N
0.0400 0.0277 fftg/I'
5249 5 15
sw84 5 6020
13 SW845 5020
sw846 5020
8-9 SW845 6420
52495L7
sw846 50L08
2 -2 gWB45 50108
sw84 5 60108
L .2 SW84 5 50108
sw84 6 50108
0.30 sw845 60108
sw84 5 60108
s$l0{6 60108
oe / Ls - oe / 23 / os H;nlQeles
oe/ Ls- ae/23/os HJtIQelee
ae / 1s- oe /2t / as HWQeIDA
osh s- oe /23 / os HWQeI-DC
oe / r.s - ae / Le / as HJvQel-Do
as/ 1s- ae/L9/os HWQ91D1
oe lls - oe / LG / os HJVQe r.Dz
oe/ r-s- oe /Ls / os H.r\rQel-D3
oe / 1s - ae / 16 / os H.n/Qe 1D4
09 / ls - oe / t6los H.nrQelDs
HiruQ9LCR
H.TV091CT
Qualifiers: N
Dilution Eactor: 4 0
Analygis Time..: L2:L6
0 .0400 0,109 N mg/L L72
0,04OO O.0998 mg/L 149
Qua1l,f iero: N
Dllutloa Factor:40
Analyeie TJ-me. . : 12 : 16
*- - -:
60
59
f,. - -:
90
92
I{g Iot-Elarqrl.e *: D5f A2A23 0- OOC Prep Batch
Alumlnum
2.00
2.00
2.AO
2 .00
2. oo
2 - OO
50.0
50. 0
L .84 ng/1,
l-.88 mgll'
Dilution Factor:
.[ualyelo Tim6. . :
2.55 N mglT,
2.52 N mg/I'
DilutLon Faetor:
Analyeie rlme. . :
2.47 nq,/L
2 . tlg mg/L
Dilution Factror:
Analyela TLme- -:
10
L7t32
L26
L25
5
21: 0O
103
103
5
21;00
L47 A ng lL
Qualif iers: NC, litSB
1510 mq/L
Qualifiers: NC,MSB
Pllution Factor: 10
Analyais TLme. . ; L7 -.32
oe/ ls- oe/Le/05
ashs- osl:slos
STL Denver
(Continued on next page)
L43
fATRIf SPIf,B SJBIIPLE IIATA. REPORT
TCIEAI, Ueta.I.e
Cl"ieut Ipt *-..: D5I02O23O
Date saqfled---z o9/ot/as L2z1o Date Received. -. og/oz/os
SAMPIJE 9PIKE
AIYIOT]IVT AIUT
IvIEASIRD
AIIIOUMT UNITS
PERCNT
RECTTRY RPD PIETHOD
ttratri-xr - - - ? - - -, 3 Gt[
PREPARATION- WORK
ATiIATJYSIS DATE ORDER #@
Chromium
Copper
fron
Magrresiurn
Nickel
Potaesirrrn
ND O .200
IUD 0.200
o - 2L9 mg/r,
O . 21.6 mg /I'
ollutlon Factor:
AnalyeLg Timo.,;
o . 3I-1 nrg/t
0.301- mg/t
Dllution FacEor:
Analygig Time.. :
L .7 6 nrg /I'
L -24 * mg /T'
Dl-Iution Factor:
Analyels TLme.. :
O.435 N mg/f'
O , 558 fiig /T'
DilutLon Factor:
AnalysLe Tlme-.:
110
108 1.5
5
21: 0O
L24
L2A
5
21: 00
138
87
10
L-l t32
87
LL2
sw84 6 50108
sw846 50108
sw845 60108
3.0 sw845 60108
34
2s
sw845 50108
sw846 5 0108
sw845 6 01-08
1.3 SW845 50108
oe/ ls- ae / L5 / as H'J\/Qe].eA
oe / ls - oe / L6 / os HirvQelce
oe lt s- oe / LG / os Hin/Qel,cD
09 / ls - 09 / 16 / as Hirueelcg
a9 / ls - ae / LG / os H.JVQSIcH
a9 / 1s - a9 / L6 / as Hinreelc.I
09 lls- oe/L6/as HinrQglcF
oe/ i.s- oe/LG/os H.nreelce
ND
ND
o - 38
0.39
ND
ND
12 00
1200
o.016
0-015
L70 0
1700
0_250
o_250
1-.00
J_. 00
o.500
o - 500
50. 0
so-0
o.500
o.500
50. o
50.0
9w846 5o1OB oe/1,s-oe/L9/Os H.r\/Qgl-CU
sw845 5o1oB Oells-O}/L9/A5 H.nlQglgv
5
21,: OO
118 0 mg/r,
Quall-f iers : NC, ItIsB
LZOA mg /I'
Quall-f iers : NC, MSB
Pllutl-on Factor: l-O
Aaalyelp TLme..: 17:32
o - 564 mg/L 110
0.557 mg/t L09
DilutLon Factor: 5
AnalysLa Time. - r 21: O0
L74A $ry/L
Oua1if iers ' Nd,l'{EB
L790 ng/I'
Qualif iers: NC, MSB
Dllution Pactror: 10
Analysle Tl,me., : L7 :32
sw846 601oB 09/1s-09/t9/as H.J\IQ91C0
swglt5 50L0B a9/15- 09/Lg/as rr.J\rQg1cL
sw845 6010B 09 / r.s - Oe / L9 / Os H.nrQelCI{
sw846 60108 A9 / 1s - 09 / 19 / As HWQglcx
STL Denver
(Continued on next page)
a44
TtrtB.ET SPIKR 8AUPT,B I}AT[.' RBPIORT
IOlf,BIr lttetale
Cl-Lent lot *- - . !
Date Sarylled---l
SAIVTPLE
PARAMETER AMOIINT
Sllver
ND
ND
Sodium
33000
33000
Vanadium
0,014
o.oL4
Zinc
o .024
0.024
Zj,re.anium
ND
ND
I.IB lpt'-garyll-e
Mercury
DID
N(I[B(S} :
D5 I02 023 0
oe / oL/ as 12 : Lo DaEe
SPIIG TVIEJASRD
AMT AIUOT}I{ T UNTTS
Reeeirred-.3 09/02/05
uatrix-----.-..3 GW
PREPARATTON-
AIVAI,YSIS DATE
PERCMT
REfiTRY RPD METHOD
WORK
ORDER #
O,0500 0.0 626 mg/r,
O, OSOO O.0518 mg/I'
9w846 50108
1.4 SW845 60L08
sur846 60108
sw84 5 60r-08
9w845 60108
sw845 50108
sw846 50108
3.7 SWB46 60L0B
gw84 6 601-08
3 .2 SW84 5 601_08
szs8348
9w845 747AA
0.15 SW846 7470A
oells-oe/L5/a5
ae/1s-oe/L6/os
L25
124
L20
L24
5
21: OO
101
104
l.o
L7:32
ffruQgLDW
H'.TIIQ9]-DX
Dllution f,'actsor: 5
Analyete Time..: 21:OO
50.0 31700 rftg/I'
Quatl"f iers : NC, MgB
5o.0 33600 lriry,/t,
Qualifiers: NC,M$B
Dilutl"on Factor: 1O
Analysl-e Tim€. . : L7 :32
0.500 0.565 mg/r, 110
0.500 0.551 mg/T, 109 0.55
Dilution Factor: 5
Analysia TLme..: 21:0O
aells-oe/Le/05
ae/ r-s- oe/Le/as
HJVQ9 LC2
H,.ryQg1C3
oe/i-s-ae/L6/os
ae/1s-oe/L5/os
H,X/QglCK
H,f\/Qg].Ct
0-500
o.500
o.500
0.500
O .622 mg/t'
0.545 mg/L
Dllutl.on Factor:
Ana1ygia rl-me. . :
o.505 mg/r,
o .522 lrrrg/L
Dilutrlon Pactor:
Analysl-e Time. . :
oe / 1s- a9 / L6 / as HwQelcM
oe / 1s- ae /L6 / as HiruQeLcN
ae / Is- oe / Le / os HWQ91C4
09 / r.s- oe / Le / as HiruQer-cs
09 / 1,9 / os H.rvQglcP
oe / re / 05 HinIQelcQ
*: D5f020230-00{ Prep Bat'ch
0.00500 0.0 oL42 mg/t
Qtralif l-ers: N
O,00500 O.OOL42 mg/t"
Qualiflers: N
Dilutl-ou Factor:
Analysis Time. . :
#- -.3
28
28
1
16:43
calolations ue pcrforned bcfore rouding to rvoid romd-off enors in calculrtcd resulo.
N Spiked enalyre recovcry ie outsiSe $atrd coilrol limits.
NC The rccovery &d/or RPD werc not cElcilleldl.
MSB The rccovery and R?D wcrc not celcrilred bgulc ttrc crnrplc atrlout war grcatcr than four timcs thc ryitc rmount.
r Rclrdve pcrcurt diffcrcncc (RPD) b ou$lde sutcd coilrot limiB.
STL Denver 1,45
HLI?IX SPIXCB SBHPI.B EITALTIATIOII RBPORT
lOlEBIr lfist.nl sr
C1ient Iot *---: D5I02O230
Date sary)Ied- - - : 09/ 15/os 14:30 Ilate
Merctrry
Recelvrsd--3 09/17 los
RPD
llatri-x,,,, ? o- - - E WATER
PREPARATION- WORK
AI{AI,YSTS DATE ORDER *PARJAI{ETER
PERCENT RECO\TERY
RECO\IERY I,IMTTS RPD ITIMIT9 IUBTHOD
US lot-Saryrl.e *: D5I1701-95-001 kep Batrch *-
84N
78 N
( 8s 11,4 )
( ss LL[l 7 .2 (O-10)
Dilut,Lou Faetor: L
Analyeie TLme, . : 19: 33
: 5262486
sw845 7470A
9w845 7470e
ae/22/ os HKTIEL34
ae/22/os HKTIE1C5
IUIB (S) :
Calculations arc psrtbrmcd bcfore rounding to avoid roundoff errors in calculrted results.
N Spikul analye rGcovery ts outsidc $arcd oootrol limits,
STL Denver L46
Clieut lot, *, - - :
Date gary,Ied,---l
g;54pr.E
PARAI{ETER AI{OUNT
D5 r02 023 0
a9 / 1sl05 L4 :3 o
SPIKE ME,ASRD
A}TT AIvIOT]NT T]NTTS
UAITn SPIKE SAHPT,B DHIh REPIORT
TCIItrAIr lteta]-s
Ilate Beceirrcd- - r 09/L7 /OS
: I{ATER
PREPARJATION- WORK
ANALYSIS DATE ORDER #
l.Iatrfur.
PERCNT
RECVRY RPD METHOD
H.S Lots-Ealqfie *:
tlercury
ND
ND
NcrfB (8) :
Dsr170L96-001 Prop Batch
O. 00500 O. O0418 firg/T'
Quall-f iers: N
0.O05oo O.00389 W/1,
5262486
sw846 7474}l
7.2 9W846 7470A
ae / 22 / 05 HKTLE1C4
09 / 22 / os HKTl-El-cs
s- _ - :
84
78
Qualifiers: N
Dl-]-utton Fact,or: I
Rnalysia Tl-me. . : 19 : 33
Calarlations aro performed beforc roundlng !o rvoid round-off erronr in calculated results-
N Spikcd andyte rccovery Is outsidc strtod control lirnito,
STL Denver ]-47
STL DENVER
o
LaI)
traeb:
Codc:
Total Metals Analvsis
COVER PAGE - INORCANIC ANALYSIS DATA PACKAGE
tRg Corlroration gDG No.: D5f020230
STLDEN Caec No. t SLS $k). :
SOW No. r
Sarnfrlr ID -
swB-10-090105
I.rb SanEl]'e No,
Dsr0202 3 0- 00{
o
Irlc
sr{tB-10-090105 us Dsr0202 30- 00{s
sr{B-10-090105 tlgD Dsr020230-OO{gD
g$rB-3 - 09 0105 D5r02 02 3 0 -00 5
gwB-7 -o9010s Dsro20230-oo5
swB-e -090105 D5r020230-003
gr'rB- 910 - 090105 D5r020230-O02
rs ICP intcrelcment, corrcstl.ona aDDIicA?Ycg./No YEg
Ware ICP brckgrorrnd correctsl,ont eppl.l,cdZ
ff yca-wor. rrw d,ntl lfanoratred before
appJ.icr,tiorrr of background corroctlona?
Coruocrrtg 3
ycs/No YES
Yeg/No
r o6rtify thrt, uh18 daca Dackrgc ir Ln ooqlllancc rrr.th thc torn8 arrd condlElons of thc
cosltrret, botlr tcchuical\. and for comlrlet.ncrl, for othcr thru thc conditioos detai].ed
above. RGl.caac of thc drtr cougaLned Ln thic bEdcoDy drta prckege end in tb.e cory)utar-raadrlrlc drta
lubml.ttcdl on flofltnr dlakette has been autborlzcd by thGl Lsborator-lz l}Ir^Brgrlr or Ehc ![tatgerr3 dogLgttcc, ac
werLfied by chc lo1lowing aigaaturc.
O"rurs , .. li) {t-....,((fi ,,i.{r"-,)r,Dcc Kattule
Dauo' .,-- 'il.4{r,:t
Nemc;
titla I
PAGE INSTL Denver COVER
Data f,na}y;t
1,48
STL DENYER
Total lVletals Analvsis
-2A-
INITIAL AND CONTINUING CALIBRATION VERIFICATION
Corrtsract! IIRS Corporatlon
Lab Code s STITDEN Caga No.:SAg No. r aDGI No. r D5I020230
rnLtial Crllbratlon Eorrrcc r
Continul.ngr CalibratsLon gorrrcs :
nLgb Purity, Spcx
Inorgru,ie Vcnturcrl
.illuminurn :l
AlrlrninuIn :l
Calclurn L l
Ca].oium Hl
Concentrats:lon UnLt,a r urgl/I1
39.39 I 98.5
39.93 I 99. g
51.301 102.6
52.511 105.2
Ilna].yt,c
InitLal. Ca]'Lbration
Tnrc Forrnd %R (1)
ContsLnuing Calibrat ion
Tnre Found, e6R ( 1) Found ,6R ( 1)M
fron Lo I 0.5081 101.5 I P
I rron Hi I lo.ol {o.zolroo-sl so.ol sz.rsl10r.3l I lpl
Potarnium I 50-391 100-8 I P
Magrnesium I 20.051 100.3 I P
lsodiumr,ol I I I s.ol I I s. oal 101.6 | P I
Sodl.um Hf I {0 . 02 1100 ,0 52.241 104 - 5
ZLrcoairrm I
(1) Control r.initg:Mcrcury 80-120t Other Mctalg 90-110r CYanida 85-115
o, {gg l 99.8 I P
STL Denver Forsr II (Part 1) IN a49
STL DEIVVER
Contract: IIRS Cor;poratl-on
Totel Metals Analvsis
-2A_
INITIAL AT.{D CONTINUING CALIBITATION VERIFTCATION
Cage No.:gAg Ntr. t
Eigrh Purity, Spcx
Inorgranio Vcnturo;
LEL codc r STLDEIhI
-rrLtl-a]- Callbrat,iou Elouroc r
Contsl.nuing Cnl.Lbratrl,oa Sourcc r
sDc DIo, : D5I020230
ConcentreEion UuiEr I ng/t,
Anallt,c
rnLtLal Calibratioa
Trrra Found, e6R ( 1)
Contiuulng Crlibrrtion
trrnrc Found reR (1) Found tR ( 1)u
.LLrrnirrurn :l
I n1uninum :l I
0 .50
50.O I d9. sol 99,0 I
0-493 98.5
Calciun L I
CnlcLrrm II I
Iron fro I
Iron HL l
Potassium I
I uagrnaetuln I I I
5-o
50. o
0 .50
50. 0
50.o
20 - O I
49-1 98;3
48-87 97 .7
5.03 100 .5
0 .497 99 .4
50.32 100-5
1e-s7l 99.8 I p I
lsoaiun r,o I I 5.0 I s- oel rot.z l p l
Sodlum Ei I
I zi=c=alq4l I
50. o
o.5o I
50 .7 101.5
o,sool 1oo-o I p I
( 1) ConLroI lrl.mtus :!,Icrctrry 80-120t othcr Mrtalg 90-110, watrLde 85-115
STL Denver Form fr (Part, 1) IN 1s0
STL DEIVVER
Total Metals Analvsis
-24_
INITIAL AND CONTINI]ING CALIBRATION VERIFICATION
CoErtrrctr t RS CorDorrtlon
Ld) Coda 3 S1FLDEIV Caetl No. r SISI No. r
laitial CaltbratLon Sourcc:
Continuingr Cali.bration Sourcr t
Higrh PurLty, Spax
InorgenLc Venturet
sDc NO-: D5TA2023O
Conocntration UniEe z $glt
ll'rumtnu,*J I 1,,._,L-,-...s,9,,,0 1-,,-, lz.lrl gr.gl ls.oll go.rlel
lcarcrun nl I [. .-. I so.o I rs.z.?l . go.l I ls.gsl gr.g I e-l
I -ron lri I I I I so.ol n5-3sl 90.?l 46.13 I gz.sf rl
.lna1yEc
rnitial Callbratlon
1[rrra Found BR ( 1]
Contlnulng Calibrrtsion
lfrrro Fotrnd tR ( 1) Found' esR ( 1)![
Sod.f,rrst Hi I
(1)Control LLnLts: Mcrcury 80-120; Other MetrLr 90-110, C:/inLde 85-115
48.1-31 95.3 dg.70l 97-tLl P
STL Denver FOIM II (ParL 1)-I}[151
STL DENVER
contract: IIRS Corporatioa
Total Metals Analvsis
-2A-
INITIAL AND CONTINUING CALIBRATION \MRIF'ICATION
Cage f[o. r Sl,fI No. :
Higrh PurLty, Spax
Iaorganio VcuturGs
Lab Cod,c r STLDEII
rnl.tLal CalibntLou Sourca :
Cont,lnuingr CrllbratLon Sourco r
sDG No.: D5I020230
Concsntsrrtsl-orr trnLts; r mglr,
.}nrI.yBc
fnitirl. CrI.l.brltl-on
Tnrc Found tR ( 1)
Continulng Ca1lbratj.on
trnre Found e6R (1) Fou:rd e6R ( 1)M
AlumLnum rl o .50 0-{7 95 .8
A]-uurt rrlun :l 50. o 47 .8L 95.6
Cal-ciun Ll 5.0 l.7gl 95.8
lsarci'rnrl - | ..,.,- I I so.ol I I ns.erl gr.zlil
Iron Lo I 0 .50 0.4881 97.6
I rron IIt- I I I I so.ol I I cs.ggJ gz.olp
IrotarrLumI I I I so.ol so.zglloo.Gl I Jrl
Irlagrncal"um I 20. o 19.701 98.5
LEoai"+ Hr I I IIlzi1conrunl I .-l I o.sol o.sorl roo-el I lel
(1) ConEroI r,initsg:Mercurar 80-120r OEhcr Mctall 90-1101 Cfranlde 85-115
so.ol I I ce,6sl gs.lfel
STL Denver fom II (Part 1) rN 1,52
STLDETWER
Total Metals Analvsis
-2A.-
INITIAL AIID CONTINUING CALIBRATION VBRII'ICATION
corEracts I,RS CorDoretioa
r,ib Codc 3 STITDEN Cage No. r SASI No. r
InLtial Crlibration Sourccr
Continuing Crl'ibraELon Sourec r
Htgrh Purity, Spcx
InorgrnLc Ventureg
sDo No. r D5f020230
Coneentrabion UnLt,r t rrgfL
Ana.Lyt'a
rnl.tl-a1 Calibration
Trnre Found ,6R ( 1)
ContLnuingr Call,bration
rnrc f,ound 96,R ( 1) Found %R ( 1)M
AlurnLnuro :l
AlurnLnutrr :l
Calcium L l
Calclum H I
I trorr Lo I
0.50 0 .48 95.0
50.0
5.0 {.8 9T .2
50 .0
o.5o I o.{881 97.51
{8 .31 96-5
{7 .28 94.6
Irronni I I I so.ol I I 17 -Lr.l sc-s I n I
Lrtrursgiunl I 5o.o I 50.8il 101.5 I lpl
Magaosiun I 20 .0 19.{51 97.3
fsooinmnrl I I I so.ol I I tg.ttl 99.51
ZLrconiuur I
(1) Control Limitar Dlercur:r 80-1201 Othar
0 .50 o. {ggl 99. 6
MrEaIg 90-110r Cyanldr 85-115
STL Denver Form II (Part 1) IN 1s3
STL DENVER
Contre'ct, t [rIiU; Corg,orat1on
Total Metals Analvsis
-2A-
INITIAL A}[D CONTINUING CALIBRATION VERIF'ICATION
Caac No. t 8.[.S No. t
Ht gh PurLty, Spsx
InorganLc Venturcs
Ilab Code : STITDEN
Initirl Callbration Bourccr
Cont,tnuLng Calibrat,lon Source:
gDc NO.: D5I02023O
Concentration Unitr t mg/L
.Lrralfrer
rnLtLa1 cr1l-bratlon
Trnrc Sound e6R ( 1)
Contsiaulng callbratlon
Tnrr tround e6R( 1) Eourrd, e5R ( 1)ItT
l.'I.uilinrun :l
I c.lcium r, I I
0 .50
5.0 I
0.4951 99.2
{.961 99,2 I
fron f,o I
Potrrssirun I
lm.Feaiuml I
0 .50 o.4g9l 99. B
50-o 50-g8l 102-0
I I 2o.oJ re.G3l eg.2l I IPI
ZirconLunr I 0 .50 0. {9{l 9g . g
(1) Control tLmLt,gr lllcrsurf, 80-12Oi Other ueBa].a 90-110; crraaLdc 85-115
STL Denver rorn II (Part 1) n[1,_5 4
STL DENVER
Total Metals Analvsis
-2^.-
INITIAL AND CONTINT]ING CAI,IBRATION VERIFICATION
contractss IIRS Corporation
Lab Codrrr SlILDEN Ca'rr tr[o. r fIAg No. r
rniticI Calibration Source :
Continuing Ca1Lbretion Souree:
Higrh PtrrLty, Spcx
Inorganic Vonturoa
sDo No. s DSI02023O
Conecntratsion m,lEa r ng lT'
f rr."ninum :l o.zsl 0.2461 gs.l I I I I I
ena}f't,e
rnl"tial CrlLbntlon
T:nrc Found ,6R ( 1)
Conts lnul-ngr Calibration
Tnrc Found ,6R ( 1) f,ound' 95R ( 1)Ir!
Calciun L l 2.2 .01 1100 .5
Iron Lo I o.2 o .259 1103.5
Potaeciurn I 20.0 20.33 1101,6
eium I 10.g-57 I 95.7
Sodium Lo I 2.2.05 1102.5
lzircoarunl o.zsl ,, o.zlsl gz.zl I -...L I I lpl
( 1) Control t,imlts r Mcrcurfr 80-120r Other Mctals 90-110r Cyanldc 85-115
STL Denver Form If (Prrt 1) fN 155
STL DENVER
ContracE r IIRS Corporation
Total Metals Analvsis
-7A-
INITIAL AI'[D CONTINUING CALIBRATION VERIF TCATI ON
Cage No.:g.trg trIo. t
Higrh hrrLty, Spcx
rnorgenio Vrrntures
Lrb Code: STITDEN
rnl-tLa1 CaLLbratsion Souroc r
Continuingr calLbrabion Bourcc:
sDe No. : D5I020230
ConcentrrtsLon tnel-tg: mg lL
Ilnal.trcc
fnitj.al Callbration
Trrrc Found AR ( 1)
Contirruing Calt bratsl,on
Trrrc Forrnd, e6R ( 1) Found t,R ( 1)M
lnunrnum:l I | | o.sol ,,-. I I o.szrlron.zlpl
lrrunrnun:l .to.ol :g.gsl gs.l,l,,_ so.ol le.gef. gz-gl I lpl
Calcium L l 5-0 5-O0l 100.o I P
lca+ci"- rl lo,.ol rg.ezl gg.o | ,,so-o I lg.ssl gg..21..., ,,_. I I e Ilr5onpo I I I I o-sol I I o.s:r7l rol,elrl
[.ron Ht I 40. ol 39.831 99-61 so.ol le.3?l 9B,zl I lpl
Pota,ssium I
anl-um I
I soqiu+ r,o I I
50.0
20.0
I :.0 I
50.011 100.0 I B
19-821 99.1 I P
5-oel ro1.z J p I
Sodiurn IIf I {0,0 {o.02 100 .0 50. o 49 .7 99.5
ZLrconium I
( 1) ConEroI lrimlts:Mercrrry. 80-1?0; Other MctrIB 90-110; Cyanidc 85-115
o. {93 98. 6
STL Denver Fom rr (ParE 1) IN
1s5
STL DENVER
Total Metals Analysis
-2A-
INITIAL A}ID CONTINTM{G CALIBRATION VERIFrcATION
CoEltrrcts IIRS Co:ilrorat,lon
Lab Codc r STLDTI{Crrr No. t 8f,S No. t
rnLti.al Cf,libratLon Source :
ContrLDuLngr Calibrrtion Sourec :
Irierh Purity, SI>cx
Irrorganie VenturGa
SDc trrO- : D5IO2O23O
Couccntration Unltrs t mg llt
.Lrra1rru,o
taieirl Cal-lbraElon
Trnrc Found tR( l)
Contlnulng Crllbntioa
lf r:rn Pound tR ( 1) f,or:nd, tR ( 1)}I
Al.umirrurn :l 0.50 0.{g5l 97.0 I p
J.ltunrauu:l I I I so.ol le.grl sz.al I lBl
lc.r"i'r- r,l | | l. s.,o I I I c.ggl sg.e,l g.l
lcarcl.r-nl ,., I I ,l,,.,sg.ol tP.ezl gg.al I JLI
Iron LO I 0.50 0.{g4l 98.8 I p
lrronrr I | | I so.ol lg.rrl ga.zl - I lBl
PotaseLun I 50 .0 50.101 100.2 I p
luasnarLunl I I I zo.oJ I I rs.azl rs.llrl
I soatt - r,o I I I I s,ol I I s-otltol.d I p I
I soaturn Hi I I I I so.ol as.s3l ee-1l I lrl
I zlrconiuml I I I o.sol I I o.rg4l gs.alpl
( 1) Control Li.ln{.t,s r Mcrourtr 80-120; Other Motalg 90-110r CYanidc 85-115
STL Denver
Dorm II (Part 1) IN
L57
STL DENVER
Contract,: IIRS Corporat,Lon
Total Metals Analysis
-2A-
]NI'TIAI, AND CON'IIN UTNG CALIBRATION VERIFICATION
Cagc No,:AIS No. t
Hlgrh PurJ-ty, Spcx
InorganLc VenturcrB
Lab Code: STLDEN
fnitial Calibratl-on Souroc:
Continuing CaLlbratLon Source:
sDG No.r D5f020230
Conccntration Unl,t,s t mglt
Analyte
Inieirl. Cr1lbratl-on
Trrre tr'orrnd tR ( 1)
Continuing Cal.lbratlon
Tnrc Found e6R ( 1) f,orr-nd ,6R ( 1)M
Llurntnrrm :l
Ieru*inurn:l I I I so.ol {8.851 97.7 |I lP
Calcirm t I
Cal-cirrnr H I
Iron Lo t
lrronai ! I I I so.ol ra.esl gz.sl I
PotaseLum J 50,o{1100-1
lr'lrp"siuml I I I r9.Bol ee,olpl
lsoattrnqgl I .1, ....L , _s.o-L - I I s.oglroo._sle. l
Sod,irurr Hf I llg.{xl gg.g
I ztrconirrn I I I I o.sol I I o.lgzl ga.llpl
20.o l
(r)Control LlmLtg:Mercrrrar 80-1201 Othor Metalc 90-110; CfranLd.e 85-115
STL Denver
Fonn II (Part 1) IN
158
STL DEIVVER
Total Metals Analysis
-2A-
INITIAL AND CONTINUING CALIBRATION VERM'ICATION
contraot: IIRS CorIoretiou
Lab Codc r STLDEN Caar SIo - I SAS No. r
fnlEial Cf,libratl-on Source :
Contlnuingr Callbratton Sourcc:
HLgrh f,\rrity, Spcx
fnorgrrrlc Vcntures
sDo NO-: D5TO20230
Concentrrt,ion UuiEu t m:f,[L
AEalfrt,c
-nltlal CalLbratsion
Trrrc Found. ,sn ( 1)
Contl-nulngr Ca1l-bratsLon
:rrnrc Forrnd. t,R ( 1) Found 9sR ( 1)![
l.a,runiurm:l I I I o.sol I I o.czel sEql2j
Alumimlrn :l 48.711 97 .4 P
Ca].cirrrn L l 4.931 98.61 P
lc.rcru+xl | ,.,, I I so.ol re.ssl gz-..2-,1 I lel
Iron Irtr I 0. {gg I 97.8 I P
rron Hi I 48.551 97.3
I eotaarELun I I I I so.ol I I so-oslroo.rlpl
Magrncsiusr I 19-631 98.2 I r
lsoar-ynrol I I I s..g1,,,-.,,-,.-., l-..,,, I s.oelroe.zlpl
Sodiun IIf I 49.501 99. O P
J ziroonlunJ I I l o-sol I I o.4e3l s8.6 I P I
(1)Control Linits r Mcrcrrry 80-1201 Othar Motale 90-110, Wanido 85-115
STL Denver
Form II (Part 1) IN
159
STL DE]V}/ER
Contrlot r IIRS CorponEton
Total Metals Analysis
2L_
INMAL AI\D CONTINUING CALTBRATION VERTFICATION
Caga No- :StS No- :
Higrh Purity, Stlrrx
fnorgrnte Vcnturca
LAI} COdA t STIJDEN
rnl.tlal Crlibratlon Source I
ConEtnuiag CrllbratLoa Sourcr:
SDc [Io- r D5IO2O230
Aluml,nun :l 4.2
CalcLum Ii I 2.A
CorrcrntratLon Utcita s str,ll;l
0.263 1105.2
1, gg I gg.0
I_Pote sgirurr I zo. ol 20. 18 lloo .9 I I
Itnal.ytc
InLtl.a1 CallbratsLon
Trnrc Found, tR (1)
Conti,nulngr CalibraELon
Tnrc Found, rgR ( 1) Found tsR ( 1 )M
flroato I o.zsl o.zs7lr.oz.el I I I I lpl
lpl
I urgocslum I ro . ol e.s2 I 9s.2 I I I tl Ipl
I s<>atu* ro I 2. ol z. os lro1. s I lpl
ZLrconiun I 0.2 o -240 I 96. o
( 1) Control IrimLte r Mcrcrrry 80-1201 Othrr Uctr1g 90-1101 Clzanide 85-115
STL Denver Forn II (Part 1) IlI 150
STL DENVER
Total Metals Analysis
-2^,-
IN I'I'IAL AND CONTIN UING CALIBRATION VERTFICAfiON
Contract: IIRS Corpont,Lon
Lab Coda t STITDEN Ceae No. t
Hightnitial Ce,lt bration Sourcc:
Continuing Ca].Lbrat,l.on Sourcc :
Purity, Spax
InorganLe Vonturos
SAS No. t sDc No.: D5I020230
I rot*aoLrml
Concrrntrltion UnJ"ts r rBfr/IJ
I I so-ol I I so.ezlrol.elpl
Ana1lt,e
Initial CalLbntLon
Tnrc Found AR ( 1)
ContLuulng Calilrration
Tnre Forrod tR ( 1) Found tBR ( 1)M
Sod.Lrrrn f,o J 5-Ogl 101.8 I P
I soaio* Hl I ao.ol 3e.rel ge-zl so-ol so.esl1o1.3l I lpl
(1)Control lul.nita:Morcury 80-1201 OEhor Uctals 90-1101 Cf'anido 85-115
STL Denver Fonr I.f (Part, 1) I![151
STL DENVER
Contract: LIRS CorporatLon
Total Metals Analysis
-2A-
rNI'TIAL AND CONTINUING CALIBRATION VERTFICATION
Casc No. t S.trS No.:
Higrh Purity, Sllcx
faorganlo VarrturGa
r,ab Coda: STLDEN
Inj.tial Calibretl.oa Sourcc:
Contrirruingr Crll"bration Sourcc r
SDs No. r D5I020230
ConcrntntLon urrl,ee t lmrglt'
Analrt,c
fnitial Call-brntlon
Trrrc Found e6R ( 1)
Contlnutng Cal{braElon
Tlrra Found %R ( 1) Eound
'6R
( 1)u
Poteseium I 51.091LOz.2 I p
lFoarunr,ol . I .,-. I I s.ol I I s.osfror-slel
Sod,lrun Hi I 51.2L1 102.4 P
(1) Control L{ ra{ ts : Marcury 8O-120;Other Mctah 90-1101 Crranidc 85-115
STL Denver Fom II (Partr X) IN
L62
STLDENVER
Totel Metals Analvsis
-2A-
INITIAL AND CONTINT]ING CALIBRATION VERTFICATION
Coatsrtct: IrRS Corporation
r-,ab Code 3 STLDTN Craa Nt). I Alg No.:
rnl,tl,a] Calibrrt:ton Source;
Contlnuingr CalLbrat,Lon Sourec r
High PurLBy, Spcx
fnorganic Vontrurol
gDc lilo. : DSf 02023A
Conscntration Unitr : mg ll,
lnalytro
InltsLn1 Calibratsion
Tnrc Found tR( 1)
CorrtLnuLngr Cr1LbntLon
Tnrc Found, tR ( 1) Forrnd, %R ( 1)u
PotaseLun I
Sodirrm Iro I
(1) Control LinLtr:Mercury 80-120; Othcr Mctalg 90-110r C:ranidc 85-115
STL Denver
Fonrr II (Pert 1) G IN
153
STL DENVER
Total Metels Analvsis
-7A-
INI'IIAL AND CONTINUING CALIBRATION VERIFICATION
IIRS CorDorrtLosContracE:
f,eb Code 3 STITDEN Cage No. t g.il,S No. t SDG No-: D5f020230
Initl"a1 CalibraElon Sourcc r
Cont.inul-ng Ca1ibraE l-on Sorrrcc r
Inorganlc VonEuroa
Htgh Purity, Spex
Conscntration UnLtt t mff/r,
ArsrrnLc I
Bariurn I
Chromirrm I
copDsr I
Lcnd I
tilLeke]. I
I sttver I o. zsl o-zr3 I 97.zI o.sol
0.9971 99 .7 100 ,5
0.5051 101.2
o.5051 101.0
0 - {941 98.8 99.4 I P
o.5001 100,0
0.5091 101-, g
0.4921 98.{l o.{esl 99.ofrl
Anal6c
rnitirL CnlLbratLon
Tnre Pound ,6n( 1)
Contiauingr call'bntLon
Trrrc Found e6R ( 1) Found %R ( 1)M
vanadLum I o,5051 101.0
Z,Lnc 0 .4971 99 .4
(1) eontrol ri.niEar Iltercur1r 80-120; othor ldatala 90-11Or CyanLtte 85-115
STL Denver
For^ra II (Part 1) fN
1,5 4
STL DENVER
Contrrrct E
Irab Codc r
Total Metals Analvsis
-2A-
INITTAL AND CONI'INUING CALIBRATION VERIFICATION
UBS Corporatl-on
STLDEN eagc No. I SAS No- t SDCI No. r D5f 020230
Initial" Callbratlon Bource:
Cont,l.nu:lag Call,bration Sourcc r
Inorganic Venturct
Hf.grh ptrrlty, sDex
ConcrnEre,tLon lh1tt t mrgll
AD,al.yto
rnl,t{aI call-bration
Tnrc Found t,R ( 1)
Continuirrg Crl.Lbnt,ion
I'rnr. Found 96,R ( 1) Found tR ( 1)M
ArganLc I
Be.rJ.um l
Chroml,urn I
coDDer I
Iraad, I
I uterer I I
1. 0031 100 . 3 1.002 I 100. 2
0. 5051 101.3 0.500 I 100. 0
0. 507J 101. {0.5111 102.2
0,4951 99.0 0.4ggl 97 .6
0 . 5021 100. {0,505 1 101. 0
0.501 0.s121102,{l o.514lLaz.8lpl
J sir.rcr I I I o.sol o.{eil sr.zl o.4s7 l gl.tl pl
I veurdium I I o, so I 0.5091 101.8 I 0.5tz I 102 .4 I p I
o. {961 gg .2 o.d96l 99.2
( 1) Control r,lnits : Mercury 80-120; other Motale 90-110; Wanlde 85-115
STL Denver Form II (Part 1) IN 155
STL DENVER
Cont,rrct r
f.eb Code:
Total Metals Analvsis
INITIAL AND CON TIN UIN G CAL IBRATION VERITTICATION
URS CorDoratiou
gTLDEN Carr No. t S.e,S No. t
InorgranLo VtrnErrrGg
SDs No. r D5TO2O230
raLtlal CalibntLon Souroc s
Cont,inuing Ca].ibration Bource:Iltgh Prrrl.ty, Sperr
Conoantration Units ? mglt'
Analfrtc
Init,l-a1 Ca1Lbratrl-on
Trnrc Found t6R ( 1)
Continuing Crlibration
Tnro Forrnd %R ( 1) Found e6R ( 1)M
I nrrenio I I I I r.ool r.ozol1o2.0l r.otslror.elpl
lsafrum I I l, I o.sol o.sorl roo.zl o-lgzl gg._llFJ
Chronui.um t 0.5231 10{ .6 0.53{l 106.8 I P
I eopper I I I I o.sol o,{eel ee.Bl o.{eel es.Blpl
I rcad. I I I o.so I o.s12l Laz.4l o.saslros.z I p I
I uickrll- I I II o.so I o. s2sl 1os. o l o, s36l Lo7 .z l p I
lsrl.wcr I I I o-50 I o.sool 1oo.ol o.50611o1-zl p I
I vqaqqlaq I I o.50 I o.s23J 10{.61 o.53zJro6.4 I r I
Izrnc I I o. so l o, s1ol Laz.o l 0,5211 10{. a l p l
(1) Control l,lnltsr Moreury 80-120t other Metala 90-1101 CYanido 85-115
STL Denver Form II (Part, 1) IN L65
STL DENYER
Total Metals Analvsis
-2A-
IN IT IAI, AND CONTIN UTNG CALI BRA TION VERIFICATION
IIRS CorloratLoa
S'lrLDTN Caac No.:SI.SI No. l
rnLtial Celibratl,on Sourcc: Inorganic VantrrrGa
Contsinuing CalibratLon Source r Ht"grh Ptrrity, spax
Contract:
LaI) Codo:sDO IIo. : D5I020230
BarLum I 4.2
Conccutsntlon UnLte r nglft
a .25{ 1101 . 5 0.5071 101.4 0.5041 100.8 I P
fnalyte
rnl,tlal. Calibret ion
Tnrc found t6R ( 1)
Continuing Celibretion
Trnre Found e5R ( 1) f,ound t6R ( 1 )M
lrreanlc I o.zsl o.zl3lgo.sl r.ool r.ooglroo.gl. o.ggel gg-gIpl
Gtrroml-unt I 0.25 o.248I gg.2 0 .50 0.5021 100.4 0.5001 100,0 I P
I copp.= I o.zsl o.zizl ge.a I o-so I o.lgzl gg.l I o.agsl rr.o I r I
taad o.25 a.242 I 96.8 0 .50 0. {991 99.8 0-5011100.2 I p
lNrcrer,, I o.?sl- o.zlgl gg.el o-sol o,so?lror-ol o-soglror.elel
Isuvor I o.zsl o.zllf sz.z J o.so I o.cgzl se.l I o.lgzl ga.l.,l | |
l vaaaoiun I o.zsl ,.-. o.zso lroo.o l o.so l 0...s_o?1.1.90.{ l o. soslroo.e l e l
I 4c" I o. zsl 0.243 I 97.?l O.5OI o.{s7l se.{ | o.49Bl 99-5 [ P I
( 1) Control Llnits: Mercural,80-120t Othu Met,els 90-110r CYenidc 85-115
STL Denver Por^n II (Part 1) fll 1-67
STL DENVER
Contract r
Total Metals Analvsis
-rA-
INITIAI, AND CONTIN UING CALIBRATION VEMFICATION
URS Corl)orrtl,on
gTLDEtit Crac [Io. t glSI No.:sDGl trrc). s D5lO2023O
rnJ.tla]- Calibrltl-on Source:
Coat,l-nuj-ngr Ca].ibrlts:Lon Source :
Inorganie Vtrntrrrele
Hlglr PrrLty, Spcrc
Coneentration Un:lEr : Bg /r'
]rnaLyte
-nitial CalibrntLou,
1rnrG Fouod %R ( 1)
Contlnulng CalLbratLon
Trrrc found e5R ( 1) Found tR ( 1)M
llraanrc I ,., I I I r.ool r.ozrl 1oz.gl r.ozglroz.glpl
lalfi,r- 1,,- I I I o.sol o.lgal ge.ll o.lgll gs.elpl
Chrom,ium I 0.5311 104 - 2 0.5241 104.8 I P
I copprrr I I I o.sol o.{s{l eB.Bl o-{ssl ee-olpl
Lr,eea I I I o.so I o.sldl 1oa.BI o.5161103.2 I r I
I uicr.r I I I I o.sol o. szrl rol . B I a.szol ro s.z I p I
I srt-wer I o.so I o,{9gl 9e,61 o.so1l1oo.2[pl
[_vrnadl,urn I I tl o,5o I o.51Bl 1o3.GJ o.52rlrot.2 In IEip"
-l
I I 0.50 1 o.s1iltaz.zl o.sld] Loz.Bf pl
( 1) Control Limitg: Mcreury 80-120,' Othcr Mcta1s 90-110r CtranLde 85-115
STL Denver Fom II (Part t) rN
168
STL DENYER
Total Metals Analvsis
eA-
INITIAL AND CONTINUING CALTBRATION VERITICATION
ContrBct,: IrRS Corlroratlon
r,rb Codcs STLDTN Crac No, r SAS No. t
InitiaL Crlibrttl.on Source :
Coneinul"ng Callbration Sourcc r
NIST
Ultra ScientifLc
gDc NO.: D5TA20230
Cou,crntrrtsLon UaiC; t mglL
Analyte
fnitia.l, Crllbnt.Lou
Tnrtr Found %R ( 1)
Cont,l-nrrlng Crl ibntion
tDrnrrr E'ouad }sR ( 1) f,'ound ,611 ( 1 )lrt
o . o o2L'17 0 . o a2L47 0 . 00500 0 0 .00511
(1) ControL rLmlEs:Mcreury 80-120; Other Hetr1g 90-110,. C3ranida 85-115
0 .0 04472
STL Denver D'orrn II (Part, 1) IN a69
STL DENVER
Contraotr: URS Corporation
Total Metals Analvsis
-2A-
INITIAL AND CONI"INUING CALIBRA'T'ION VERIF'ICATION
Cace No.:gAS No. r
DITST
Ultra Sclentific
Lab Codc r S1ILDEN
rni-tlal Ca1ibrat,Lon Souree:
ConEiuul,ng Calibrat,ion Slourcc :
SDC NO. : D5f 020230
Couccnt,rat,ion UnlUg t mgll
.lErl-yt,c
.nl-tia]- Calibration
Trnre Found t6R ( 1)
ConELnulng CaL j.brati-on
T:crrs Forrnd
'6R
( 1) found %R ( 1)M
0.005000 0.00{98
(1) Control L1lnlts:Morcury 80-120, Other Uetals 90-110, Wan!-de 85-115
0 .0049{8
STL Denver
Form II (ParE 1) IN 170
STL DENVER
Total Metals Annlvsis
_24-
INITIAL AI\D CONTINIITNG CALIBRATION VERIF'ICATION
Cortractr URS Corpontion
frab Codc i 8TI{DEN Cur llo. t
NTST
SA"g No. t
Initlal- calLbntion Source:
Cont,inuing Call-bration Sourcc r U1tra SoicntLfio
sDo No.: D5Iou 0230
Coa,ccatratl-on UnLtsg : tugllt
enaI-yts
fnitirl CrllbratLou
Tnrc Found e6R ( 1)
Contlnulng Calibration
l[rnrt Found, tr,R ( 1) Found tR ( 1)It[
0.005000 0.00500
(1) Control nfunlts:lllercury 80-1201 Othrr Mcte}e 90-1101 Cfranidc 85-115
STL Denver Fo:m If (Part 1) IN 1,7 7
STL DENVER
Contract: URS Corporrtion
Total Metals Analvsis
-24-
INITIAL A}.ID CONTINUING CALIBRATION VERIF.ICATION
Case gl.g No. I
NIST
Ultra ScLentific
Lab Code: STITDEN
rnLt,{a1 Crlibration Sorrree :
ContLnuing Callbration Source r
SDc sIO. t D5TO2023O
(1)
Concentration Unit,s z mglr.
Control f.lnits: Uorarry 80-120; Other litetele 90-1101 C!'aniitc 85-115
AnalyLe
Init,Lal Calibration
Errre Found ,6R ( 1)
Cont:Lnulng Call-bration
Tnra Found, e6R ( 1) Found ebR ( 1)M
luercurv I o-oozrzzl o.oozrzz lroo.o I o.,oo?ooo I o.oosrozl roz.o I o.oosrzz.llgg.s.lcvl
STL Denver Fom II (Part 1) IN 1,7 2
STL DENVER
Total Metals Analvsis
-2A.-
INITIAL AND CONTINUING CALIBRATION VERII'ICATION
Coutraotr URS CorporatLon
Lab Codcs STLDEN gAS No. I gDC N0, rCage
rnitLa1 CalLbraEion Sourcc r
ContLnulngr CalLbration Sourcl :Ultrr ScienELfle
No. :
IfIST
Concentration UnLts 3 mg ltt
Mcrorrrryr 0. 005000 o.oa527 10s-s 0.005348
( 1) Control Linrits:Mcrcury 80-1201 Other Motala 90-110; Clranlda B5-L15
D5r020230
L73
.Lrra1ytc
lnitia]. CalLbratsLorr
Trcuc Pound tR (1)
Contsirruing Cal ibrat lon
Trrrc Forrnd. 96R ( 1) r'ound %R ( 1)M
STL Denver Form II (Part X) IN
STL DEIVVER
Contrract: IIRS Corgoration
Total Metals Analvsis
-2lt-
INITIAL AI\D CONI'INUING CALIBRATION VERIFICATTON
Cagc No. 3
lrlST
gLg No. :
U1tra Soiantifio
Lab Codc 3 9TITDEN
IniEirL CalLbratrLon Source:
Contlnulng Calibrntion Sorrrec r
sDO NO. : D5I020230
Conccntrat,Lon Unlte t wgll'
"B,nal.yte
rnl"tLa]. Calibration
Tnro Eourrd tR ( 1)
ContsLnuinft Calibratlon
Trrrc round BR ( 1) Found es3 ( 1)M
0.005000 0.00542
( 1) cont,rol t initgr Marcury 80-L2O;Othor Mcta1r 90-11.0r CYanLde 85-115
STL Denver Fonu II (Part t) IN L74
STL DENVER
Total Metals Analvsis
-2A-
INITIAL AI{D CONTINUING CALTBRATION VERIF'ICATION
Coatracts IIRE Corporation
f,rb Code : STI.DEN Crrc No. t Sng No.:
InitLaI- Ca1ibrrE,Lon Source:
Contirrrrirrgr Cr]-l-bration gorrrec r
Higrh Prrrlty
InorganLc VenturGt
sDc No.: D5f020230
Concentsrrrtslon tlnLt a r mg lL'
.nnaIl&o
rnit,ia]. CaltbratLon
Tnrs Found %R ( 1)
Contluu:lag Callbratlon
rruc 1loqnd e6R ( 1) Found e6R ( 1)!d
Cadhnirrur o. 04 0.0{01 1100.2 0-050 o .05011 100 .2 I 0.05011 10 0 .2
I sotenium o.orol o.orroo lroo.o I o.oso I o.osozl to1.4l o.osulroz.a I u I
( t ) Control LLrn{ ts t Mrrcury 80-L2Ot Othor Meta1c 90-110r C!,anI.de 85-115
STL Denver Fom II (Part,1) rN a75
STL DENVER
Contract,: URS Cor1>oratlon
Total Metals Analvsls
-2A-
INITIAL AN I} CONTINT]ING CA LIBT{ATION VERIII TCATION
gl'g No. t
Hisrh Purity
Inorg.nLc Venturclg
Lrb Codo: STIJIEN Crnc
InLtial Ca1ibrrtJ-on Sourcc r
Contlnuing Cal.ibratlon Sourca:
SDo DIo-: D5I020230
Cortcontratlon Unl.ta r W lL
.f,naly'Ca
taitLel" Calibrrt:lon
Tnrc found eGR ( 1)
ContinuLag Calibrabion
Trtre Forrnd tR ( 1) Pound e6R ( 1)Irl
CadmLum 0.050 o .051 103-O o. o{99 99.8
Sel-euLum I 0.050 0.oeg
(1) CoDtroI Ll.rl.t,lt uerculf,, 80-120r Othcr Dlctalr 9O-110r CYrnidc 85-115
98.4 0.0489 97 .6
STL Denver Fom II (Pcrt 1) r IN
1,7 5
STL DENVER
Total Metals Analvsis
_2A_
INITIAL AT{D CONTINUING CALIBRATION VERIFICATION
Contrrctt IIRS Coearoratioa
tab Cod.c s STITDEN Caee No. I S.}.S No. :
Init,ia1 Calibration Sourco :
Contlnulngr CalLbraEion Eource:
Higrh Puriuy
Inorgunic Vantursr
SDg NO,: D5T020230
Coacsntratlon tlnl,ta t mglL
lnalytc
fnitia]- Calibration
Tme Found %R(1)
Cont, inrrlng CalibntLon
Tnrrr Found tR ( 1) Forrnd ,6R ( 1)u
Lglqailr. I I I I o.osol o.osrol1o2.ol o.osozlroo.llul
I sctcniurr I I I I 0.050 I o.o{941 9g.Bl 0.os11l Loz.zlul
(1)Coatrol Llmlts:Mercurlr 80-120;Othcr Mctals 90-110; Ctranida 85-115
STL Denver
E'orur II ( Part 1) f![1,7 7
STL DENVER
Contnctr tRg Corporatlon
Total Metals Analvsis
-2A-
INI:I'IAL ATID CONTINUING CALIBRATION \TERIFICATION
Crsc
Htgrh Prrrity
InorgrnLo VanturGs
Lab Cod,c 3 STITDEN
rnl-t,l-a1 Call,bratrion Sotroe :
Contlnuing Calibrrtlon Sourccr
sDG No.: D5I020230
Concentratlon tlnit,r z u{/IIg,
.f,ntlyte
InLtlal CrlLbratlon
Tr:ue Found tR ( 1)
Co,o,t:lnulng Calibrat ion
Trnrc Found rtR ( 1) Found tR ( 1)M
lcaamlu- I I I I o.osol o.ososl101.6f o.osoolror.zlul
I srtcnlun I I I I o.osol o.oaggl gg.sl o.osoelror.zlul
{1) Control rial.tc: l{.rsury 80-12O; Othcr u.trlt 90-110; CYanido 85-115
STL Denver Fom II (Part, 1) IN
L78
STL DENVER
Total Metals Analvsis
-2A-
INITIAI, AND CONTINTM{G CALIBRATION VERIFICATION
co[tracts: tlRB Corporatioa
Ltrb Codc s STITDEDI Cagc No.:SASI No. r
Initia]. Cal'ibratLon Souroar
ContLnuingr Calibratsiorr Sourcc r
Hlgh PurLty
Inorgenl.c Venturaa
sDo NO.: D5I020230
Concentration UnLts r ng lT'
.LnaIyte
InLtia]. Calibration
Errrc Eound ,6R (1)
ConBinulng CalibratLon
rru,, Found e6R ( 1) Found %R ( 1)M
CadknLrrn
Sel.errirur I
( 1) Control Irimiue r Mcrcur-y 8O-12 0,.
0.050 0.0{9 99 .5
o-o50 0.050 100 ,2
Other Mctalt 90-110; Clrnlfl. 85-115
STL Denver Fom II (Part t) IN 1,7 9
STL DETWER
Total Metals Anrlvsis
-2B.-
C'RI}L STANDARD F'OR AA AND ICP
Contract: IIRS Corlnntion
Lab Codct STIJDEN
A.f, CRDIT Stsanda,rd Sourcc:
ICP CRDIJ Stsandard, Sourcc t
Cage No. :8.1,9 Dtro. :SDG No-: D5I020230
Inorgtnlc VenturCl
CRDL Standard for ICP
Initirl Final
Trrre Pound. 96R Found' %R
CRDL Strndard for .[.l'
Truc Dound tR
nluminum I
Conocntration Unitr : mg /I'
0. 10 0.0991 9g,0
Ca1cLun, Ir l o. 20 0.205 I 102. 5
Iron IrO I 0 .030 0 - 0357 I 119. O
leotaeaiuIll | | ll +.0-J r-oel roe.ol I IMlgrarlslum I o .207 I 103.5
Sodlum Lo I
I ziroonLrrmJ
1-O 1.04 I 104.0
I I ll o,oosl o.ooselrra.ol
STL Denver Forra II (Part 2) IN 180
STL DENVER
Total Metals Analysis
-2B^-
CRDL STANDARD FOR AA AI.{I) ICP
Contract: IIRB Cor5>oratLon
Lab Codcr STITDEN
.tr.[' CRDL Standard, Boursa:
ICP CRDL Stmdard Eourccr Inorgranio VanturaE
Cage No. r SAA !fo. :D5r020 234
ConcentntLon ttnLtt r mglt'l,
Alumlnum I
CRDL Standard for ICP
ruitial Final
l[nrc Found e6R Found 9eR
CRDL Strndard for ne,
Trrtre Found
o. 10 0.0961 95-0
Cal.cLutm Ir l 0.20 0.190 I 95.0
Iron Lo I 0.030 0.0311 I 103.7
Potrsgium.l
I u"frocaLum I
1.O 1,.051 105.0
I I ll o.zol 0.126l BB,ol
$odl,r:m Iro I 1.0 1.021 102-0
Zl,rconiumf o. 005 0.00{8 I 95.0
STL Denver Form II (Part 2) IN 181
STL DENVER
Total Metals Analvsis
-28-
CRD[, STANDARD TOR AA AI\D ICP
cont,raot r IIRS Corryorat,i-on
rrab Code : SELDEN
nn CRDL Standard Sourcc:
ICP CRDL gtandnrd gourccr
Casc l\[o. r SASI No. r SDCI No. r D5I020230
Inorganicr Vantsuraa
CRDII Strarrdard lor rcP
rnLtiul FlnrL
1lound t6R FOrrIId
CRDL Standard for .[.l,
Tnre Found tR
Potlrriuml
Sod,J.run to I
ConocntraE,:lon tmlta t ngfl,
STL Denver For:n rI (Part 2) I![1,82
STL DENVER
Total Metals Analvsis
-28-
CRDL STANT}ARD FOR AA AT{D ICP
Coatract r IrRS Corporation
fral) Code r SIITDEN
Af, CRDL AEarrdard Eorrrgc r
XCP CRDL Strndard Sorrrcrr
Cagc No,:gAg No, r gDO No. t D5I020230
Higrh PurLty, Spex, Inorganio VcnturoB
Conccutrut,l.oa Unitg 3 mg/f,
0 .010 0.0103 I 103.0
lsarrun l, I I ll o,.ogs-o,l o.oososl ror.ol I - IChroml.rrm I o.o10 0.0101 I x01.0
CRDL St,andard for ICP
rnl-tia1 FLna1
?[rrrc Found tR forrnd tR
CRDII Standard for AA
1frue Found %R
I[rsonic I
Coppar I 0.010 o. oog5 I 85.0
Lead
I xiclcel. I
0.0030 0.00316 I 105.3
I I ll o.o1ol o.orozl1o2.ol I ISL1vcr I 0 .010 0.0095 1 95,0
Vanad,ium I 0 .010 o - 0101 I 101. O
[zinc I ] I ll o.ozol o.olBBI gd.o] I
STL Denver Fomr II (Part 2l IN 183
STL DET{VER
Total Metals Analvsis
-7b
CRI}L STANDAITD FORAA AND ICP
Contrrct r
Lrb Codcs
IIRS Corporation
Caea No.3 g.f,'g No.:9DO llo. : D5I020230STLDEN
AA CRDL Standrrd Gtorrroc r
ICP CRDL Btandard Eorrrce :High Purity, Spax, Inorganic Vcnturoa
Clrromiurn I
Concentratl.on llnit,s r W lL
o .010
0.010
o. 0067 l 67 .0
0.0Lo?l 102.o
CRDII Etendnrd, for ICP
rnltLr]. Pinal
Tnre Found t,R Found tR
CRDL Standard for t.}'
Tnrc f,ound
.l,rsoaic I
lsariun I I I ll o.oosol o.ooslzlroa.ll I I
copDer I 0 .010 0.0093 I 93.0
Lead,0,0030 0,0030{ l 101,3
Nicktll I 0-010 0.0095I 95-0
Silvcr I
I v1nad,J.um I I
0-010 0.0100 1 100,0
ll o. o1o I o. o1o3 I ro2, o I
Zinc 0.020 0.0L97 I 98.5
STL Denver Form II (Pert 2l - IN 184
STL DENVER
Total Metals Analvsis
-28-
CRDL STA}IDARD FOR AA AND ICP
Contract: IIRS Cor;porat,ion
r,ab Code r StrLDEN
AA CRDL Standlrd Eourcs:
ICP CRDL Standard Eouroa:
Cagg No- :
U1tra Scienttfic
geS No. r SDO No. r D5I02O230
Concentrat:Lon UnLt; r mg,lL
CRDL Standard for AA
lfnrrr Found,
CRDL Standard for ICP
rnLtLe.L tLnel.
tfrnn torrnd e6R Found %R
o.000200 0 . 00016
STL Denver Form II (Part 2l IN 185
STL DENVER
Total Metals Analvsis
_28_
CRDI, STANI)ARD FOR AA AT'{D ICP
Cont,*ct r IIRS CoEp==*t.
Leb Code3 STLDEN Cage No-:8J[A I{o. r
AI. CRDIJ Standard Souroe;
ICP CBDIJ Stand,nrd Sourca:
U1tra SclcntLflc
sDo No-: D5IO2O230
Concentration urrl-t,r t mg fl'
CRDL Etandard for .L.f,
Trmo Found 96n
CRDr, Standard for IeP
InLth]. Fl.na1
Found ,t,n Fotrnd
o. ooo200 0 - 00020
STL Denver f,onrt II (Pert 2 ) IN 185
STLDENWR
Total Metals Analvsis
-2:R-
CRDL STAI{DAITD FOR AA AI{D ICP
Contracts: IIRS Coqporatrlon
rrb Codc I gtrLDmI
.8.[, CRDI. Standard Sourcg r
ICP CRDfr Strandard Sorrrcr r
Cage No-:Sl'S !ilo-:sDc No-: D5TO2O230
fnorgranLc Vcnturog
Concentratsion UnLtsr ; uig|t
CnDr. gBaad^a,rd for ICP
Initial FInaI.
Trrrc Forrnd tR Fsund eGR
CRDIr Strandard for .f,.L
trmc Found,
Cadlmirlm I 0 .0010 0.001021 102.o
lscretrium I I I ll o.oorol o.ooossl ss.ol I
STL Denver Font fI (Part 2) IN L87
@c'T'u
@TII.L
URS Corporatlon
Total Metals Anelysis Data Shcet
l,ab Nnme:S,t.I., r\FNYER
Lot/SDC Number: D-51020230
Matrlx: WATEB
o/o Nloisture:
Brsis: YgI
Arralysis Method: 60lQII
Unlt: rng/L
QC Batch ID: s2495LZ
Sample Aliquot: 50 rnL
f)llution Factor: I
Client Sample ID;
Lnb Srmple ID: D5l060tlt)0-6174
Lab \Vorkortler: HJ2.IJ
Dste/Tlme Collcctcd:
Date/Tlme Recelved:
tlrte/Tlnre Leached:
Date/Tkne Extracted: 09/15/05 15:30
Dtte/Tlme Analyzed: 09/16/05 16: 19
Instrument ID: 021
CAS No.Analytc Conc.MDL RL a
742e-90-5 Alurninunr 0.0t z 0,0r7 0.t0 U
7439-(39-6 Iron 0.02 r 0-021 0,l0 tl
7439-95-4 Magnosium 0.051 0-043 0.20 B
7440-09-7 Potassium 0.24 0.24 3.0 I,J
744$-(t'l -7 Zirconium 0.0016 0.00 t 6 0.0r 5 [,
7440-70-?Calciurn 0.034 0.034 0.20 U
STL Denver
Form 3 Prep Blank Eqaivalent
188
ffisrt
IIRS Corportdon
Total Metds Anrlysis Dttu Sheet
Lrb Name:srL pENVER
I,oUSDG Number: D51020230
Matrlx: \ilA'l'ER
Yo Molsture:
Basls: Wet
Analysis Method: 60I0F
Unlt: mg/L
QC Brtch ID: 52496!1
Sample Allquot: 50 nrl
Dllutlon Frctor: I
Cllent Sample ID:
Lab Sernple ID: pJI060000-6178
Lrb WorkOrder: IIJ2JJ
Drte/Tirne Collected:
DatelTime Received:
Date/Tlme Leached:
Date/Tlme Extracted: 09/15/05 I5:30
Date/Tlme Analped: (,9119/05 17:14
trnstrument lD: 021
CAS No.,Analyte Conc.MDL RL 0
7440-23-5 Sodiunr l.l l.l 5.0 U
STL Denver
Form 3 Prep Blank Eguivolent
189
ffi$rL
URS Corporatlon
Total Metals Analysis Data Sheet
Lsb Name:
LoUSDC Number:
Mntrix:
7o Motsture:
Basls:
Analysis lVlethod:
Unlt:
QC Batch ID:
Sample Allquot:
Dllution Factor:
STL DENVER
p51020230
\il.TER
Wct
60r08
ms/L
s2496t7
50 mL
I
Cllent Sample lD:
Lab Srmplc ID:
Lrb Workorder:
Date/Time Collected:
Date/fime Received:
Dttd'I'ime Lerched:
Dtte/Time Extrncted:
Date/Tlme Analyz-ed:
Instrument ID:
P51060000-6178
HTZJJ
0?l!.5/0s l5:30
09i t 6i05 l4: I3
021t
CAS No.Annlyte Conc,MDL RL a
7MA48-2 Arscnic 0.00aa 0,0044 0.0r s U
7419-92-l kad 0.0026 0.0026 0.0030 U
7440-39-3 Bariurn 0.00070 0.00070 0.0r 0 U
7440-02-0 Nickcl 0.00r 2 0.()012 0.040 U
7440-224 Silvcr 0.0028 0.0028 0.0r0 U
744A-62-2 Varradium 0.002s 0.0025 0.0t 0 tJ
744A-66-6 Zinc 0.0045 0.0045 0.020 U
x+40-47-3 Chrrrmium 0.0026 0,0026 0.0t0 U
|+qo-so-s (loppcr 0.0045 0.0045 0.0I0 U
STL Denver
Form 3 Prep Blank Equlvalent
190
ffisrt
tlRS Corporatlon
Total Metds Anilysis Data Sheet
Lab Name;
LoUSDG Number:
Matrlx:
o/o lVloisture:
Basis:
Anrlysis Method:
Unlt:
QC Bntch ID:
Sample Allquot:
Dilution Factor:
SIL DENVER
ps1020230
wA'l'r'R
Wct
7!70A
rng/L
52s31$
I
Cllent Snmple ID:
Lab Semple ID:
Lab Workorder:
Date/Tlme Collected:
Date/Time Received:
Date/Time Leached:
Date/Tlme Extracted:
Date/Tlme Anrlyzed:
Instrument ID:
CAS No.Analyte Conc,MDL RL a
7439-L)7-6 Mercury 0.000027 0.000027 0.00020 U
STL Denver
Form 3 Prep Blank Equivalent
191
ffisrt
URS Corporation
Total Metals Analysis Data Sheet
Lab Name:
LoUSDG Nurrrber:
Matrlx;
7o Molsture:
Busis;
Analysis Method:
Unit:
QC Brtch lD:
Sample Aliquot:
Dilutlon Foctor:
STL DENYER
D51020230
WATER
us
7470A
$gJL
5262486
l_
Client Sample ID:
Lsb Srmple ID:
Lab WorkOrder:
Date/Tlme Collected:
Dote/Tlme Recelved:
Date/Tlme l,eached:
Date/Tlme Extracted:
Date/Tlme Analyzed:
Instrument ID:
Dsn 900m-4868
I IKW I9
09/22/05 1434
$9/2N05 t9:20
0r9
CAS No.Analyte Conc,MDL RL a
7439-97-6 Mercury 0.000027 0.000027 0.00020 U
STL Denver
Form 3 Prep Blanh Equivalent
1,92
ffiSTt
URS Corporation
'fotal Metals Analysls Data
Lrb Name:
LoUSDG Nurnber:
Matrix:
o/" Nloisture:
Bssls:
Analysis Method:
Unit:
QC Batch ID:
Surnple Aliquot:
Dilutlon Factor:
STL NF'NVER
D5t020230
WATF'R
Ys
6020
mg/['
s2496t6
50 mL
I
Sheet
Client Snmple tD:
l,rb Sample ID:
Lnb Workorder:
Date/Time Collected;
Dttel-I'ime Recelved:
Date/Tlme Leached:
Dntc/Tlme Extracted:
Date/Time Anulyzed:
Instrument fD:
D5t060000-6168
HJ?IS
oe/ts/0s u;]0
A9D3l05 07:17
0a4
CAS No.Analyte Conc,MDL RL a
77824e-2 Sclenium 0.00033 0.00033 0.0020 U
744Q-43-g Cadrnium 0.un040 0.000040 0.00 r 0 U
STL Denver
Form 3 Prep Blank Equivalent
193
STL DENVER
Total Metals Analvsis
-3-
BLANKS
Contraetr r
Irab Code:
Praparatl-on
PreDaratsiou.
IIRS Corlroratrion
S:PLDEN Ce;a No. t glg No-:sDG No. g D5f02O23O
B1arrk Mnt,rLx (rol,I/watcr) r WITIIR
B}rrnk Conocntratsion Units (rwll' or ryrlkg) r T!G/L
Contl.nulng Ca1LbrrrE,:Lon
Blank (mglf,)
InitLel
Cal.Lb.
BIardE
(mslL)
nl.un'inun t o I o.017
Cal-clum Lo 0.034
Iron Lo o.021
PotaraLum 0.24
I'Iagneegium o. 0d3
Sodiurn Lo 0.031
Ziroonlurn o .00150
o.017
0. 034
0,021
o.043
o.031
0 .00160
0 .017
0-o3l
o, o21
o.ztl
0.043
0 .031
0.00160
0.017
0.03{
o. o21
0 .043
o.77A
0.00160
0 .017
0-03{
0-021
o.24
0. 051
0.0016
STL Denver
FoTo III IN a94
STL DENVER
Total Metals Analvsis
-3-
BLANKS
Contract:
IraI, Codc:
IIRS Corporation
Cage No. B SAS ![o - :SDG NO. :STTJDEN
ProIlaration Bl"ank
Prcparation glarrk
Matrix ( rol-1/water) :[{LTER
ConccntrrtLon Unl"ts (mglL or rlrglkgl t MG/L
Dsr A202 3 0
fnitl,nI'
Ca1lb,
Blank
(ryr/r)
Prc5>erltsIon
BI-arrk
Continuing Calibratsion
Bl,adE (mg/r,)
AIum{RruB fro I
Celeirrn Lo
Iron Lo
Potaesium
MegmaoLum
Sodiun Iro
ZLrconiurn
0 .017
0.0{1
0. 021
0 .24
0. 0{3
0. {83
o.00150
STL Denver Fom III - IN
STL DENVER
Total Metals Analysis
-3-
BLANKS
Contnct r IIRS CorporatLon
r,ab Codc: SILDEN Cage No. i
Prcparation Blrnk l{atsrl,x (soil./watsrr} :
gAg No. t 8DGI NO. : D5I020234
UINTER
Conocntration
Prcpar.a*olr
81ank
Continulng Calibration
Blank (utglIr)
1czc3c
rnitl.aL
Crlib.
Blanlr
(ng/r-,)
l,l-umi.nrun IJo
Calclum Lo
Iron lro
PotaasLrrm.
!flagnesium
SodLum to
Zlrconirrm 0 .00160 o.00160 0.00160 0. o0150
STL Denver
Porrn III IN
]-95
STL DETVVER
Total Metals Analysis
-3-
BLANKS
Contraet g
Lrb Codc:
PrcparatLon
PreparatLon
URS Corlroration
STT,DEN Cagc No. r
B]-ank uatrix (golI/water) :
Blanlr ConcentratrLon UnLts
S.D.S No. t sDO sIO,: D5I020230
(mgll, or mg/kg) :I{LG I I.
AnaIyt.e
rnl,El,r1
Calj.b,
B1ardE
lmgl;1 c
Contiuuiag Celibration
Bkrrk (mglL)
1 c 2 c 3 c
PrsparatLon
BLanJr
c u
Potsaesl.rrm I 0 .241U 0.2{lu
-o,032lB
P
I
P
STL Denver folm III IN L97
STL DEIVVER
Tota! Metals Analysis
-3-
}II,AN KS
Contrects r
LaL Codr:
IIRS CorporatLon
gAg No. r sDs No. r D5I020230STLDEN Ca,sc No. i
PrcDaration Blanh MaErl,x (ooLl/wat,cr) :WI'TER
Praparation B1ank Concentration Uaitg (nglL or ngr/hg) :YIG /Ir
Contl,nulngr Callbratloa
Blank (nglt )
Inltl-a1
Cr1Lb.
glrr:ilE
(mglt'l
ArganLe
Barium
C romiurn
CopSrtrr
Lrrld,
NLckeL
SiLvar
Vanadiurn
Zinc
0 - 00{{0,0044
0.00070 0.00070
o-oo260 o - 00260
o. oo45 o - oo{5
0.0026 0.0026
o. 0 0L2 0.00L2
o - 00290 o. 00280
o,0025 o. 0025
0.0045 o .0045
0.00,04
0.00070
o-oo26a
0.0045
0.0025
0.0aLZ
0.00280
0.0025
0.0045
0 .00{4
0.00070
o. o0260
0.0045
o.oo25
0 .0012
o. 00280
0.0025
0 .0045
0,00{{
0.00070
o - oo25
o. oo{5
0.0025
0.0aLa
o - 0028
0.0025
0.00{5
STL Denver Dom III rt{
198
STL DENYER
Total Metals Analvsis
-3-
BI.,ANKS
Contrract:
Lab Codcr
IrRS Corporation
SlfI No.:8DG No. r DSI02O230gTtDEN Cagc No. I
PreparatLon B1a,n,k Mat,rl,x (eoi]./uetcr) r
PreDarnt,Lon BIanIs Coacantration Units (
Wf,TER
.B.rg('nic
tsariun "
Chronrirrm
CoDper
Nl-ckeI.
Silwar
VarradLrrn
0.00{{
0.00070
0 - 00260
0 - 00{5
0 - 0025
0.0012
0.00280
0.0025
o.00{5
/t' or mf,/kg) r
0.00{{
0.00070
0.00250
0.0045
0.0026
0 - oo12
o.00290
0. oo25
0 , oo45
ContLnulng CrlLbraEion
BIarrIc (nglL)
lczc3c
rnitl.el
CaILIr.
B].a.nlc
(uglr,)
STL Denver rorur III IN
199
STL DENVER
Total Metals Analvsis
-3-
BI,ANKS
contract r IIRS CorSrcratlon
I-lab Cod,a r STLDEN etrBc No, :gAg No. r sDo trro. r D5r020230
PrcparatLon Blan"h ruatrLx ( so{I./watcr} :I^IATER
Prtrparation Blarrk Correcnt,rat.{on Unltg (trrrtl' or nglkg) :DIG/I,
Prcparatlon
B].errh
fnitLa]'
CaIl.b,
818dE,
(ng/L)
ContLnulng CrllbratLon
BladE (urglnl
Areenic
BarLum
Chrom1um
Coppar
Nl,ckc].
Si].rrrrr
Vrrrtrdium
ZLnc
0.00{{
0.00070
o.00250
0.00{5
o. 0025
0.oal,z
o . o02go
0.0025
0 .0045
0.0044
o, 00070
o.oo260
0.0045
o. 0026
o. 0012
o. oo280
0.0025
0. o0{5
0 .00{{
0,00070
0.00260
0.00{5
o.oo26
0.0012
o. oo280
0,0025
0 .00{5
0.00{{
0.00070
0.00260
0 - oo{5
0,oo26
0.0012
o - oo280
0. 0025
0.0045
STL Denver fom III. IN
200
STL DENVER
Total Mctals Analysis
-3-
BLANKS
ConErrct r
Irab Cod,e r
Prsprratl,oa
Prcplration
IIRS CorporatLon
STLDEN Caae No.:
B].ank Matrix (aoIl/wrtor) r
Bl'ank Concrrrt,ration UnLt,;
S.}S No.:sIrc No. : D5IA2023O
(mfr/L or mg|
Anal-ytG
rDltl,al
Ca1tb-
Blrnk
(ns lLl c
Contl,nuing CaI l-bnt,l-orr
Blartc (mg/L)
1c2c3c
Pre5rrntLon
BLrDlc
c l[
llercury -0.0000311 B 0.o00o27lvl -0.000029 lB I 0.00oa27 I u o-oo0027 I U c"v
STL Denver Form IIf nil 207
STL DEIVVER
Total Metals Analysis
-3-
BLANKS
Contracts:
Lrb Codc:
PraparatLon
PraDaratioa
IIRS Corlroration
STLDTN Crac No. t
B1antr, l{rtrLx ( eoL}/watcr) r
slrnk Conoentrration UnlEg
glg No.3 sDo IsO. : D5I020230
UIATEn-
(mglf, or mg/kg) :VIGIr,,
.Lnrl1t,c
ruLtLal
Ca1lb -
BIadr
(mglL)
e
Cont,Lnuing CalibraL ion
Bl,rak (tugltl
lczc3c
Preparat,Lon
BIank
C lr
Mcrorrry I o.000030 IB I 0.000027 lv Ctr
STL Denver E.oM III IN 202
STL DENVER
Total Mctals Analysis
J.
BLANKS
ContraoE r '
Let, Codc r
Prerlaratsion
Preparetrl.on
IIRS Corporn'tion
STITDEII Cage No - :
B1a:rk Matri.x (aol,I/water) :
B1ank Concorrt,mtLon tDeite
glg No. r SDGI NO-: D5f020230
(mglL or mgr/kg) :MO/I,
AnaIytse
rnitstal
CalLb.
BIanL
(w lt"\
C
Continuingr Ca1ibration
Blarrk (nglt)
1 c 2 3c c
Preparrtro'
BLrnk
C u
lrcrcury I 0.0000271u I o.ooooezlul 0,0000271u I o.oo0o27 lu 0.000027 I U gtr
STL Denver forur III IN 203
STL DEIYVER
Total Metals Analysis
-3-
BLANKS
Cont,rrct r
LrI, Codc r
Preparatrl.on
PrGparation
IIRS Corlprrrtl.on
STf,,DEN Case No. t
Blank Matrrl-x ( soLl/watcr) :
B1ank Conccntsration Unit,a
Sl'g No.3 gDO NO. r D5I020230
(ng/L or ng/kgr) :VIGIr",
Dna.].yt,c
InltLal-
Cal'l-b,
Blanlr
(mg 1r.y
e
Contiauing Crl-l,brrtlon
Blrnk (rogr/L,)
1 c ?C 3 c
Prerrar.Lroo
Blank
c M
Mcroury I O. OOO027 l U l O, OOoo27 lU gu
STL Denver Forrr rII IN
244
STL DENVER
Total Metals Analvsis
-3-
BLANKS
Cont,raot r
LaL Codrrr
PreprratLon
Prcparatl,on
IIRS CorDoration
STITDEN Caae No.:
Blank Matrrix (goil/wrter) r
Blrnlc Co,nocntratLoa uaLt a (mgln or mg/kg) :
8f,SI No. r
WATER
VIOII'
D5r02 023 0
245
Anr1yta
Ial.tial
Crllb.
BLE-uk
(ruI/L,)c
Conts,LnuLng Caltbrat ion
Blank (ug/L)
1czc3c
Preparaaton
BIeD.k
e M
Cedmiun
S"1".f.-,
o. 0000{ol uI
0 . 0003301 u
0.0000{0lul 0.ooo.otolu I 0.0000{0 I u
0,0003301u1 0.0003301u I 0.000330 I u
u
u
0.0000{
0,00033
u
E
M
STL Denver Forur III IN
STL DENVER
Total Metals Analvsis
J-
BLANKS
Contract r
f,lb Code :
Prcparatsl,on
PrcDaration
IIRS CorporatLon
STfTDEhI Cerc !fo. r
Blank Matrlx (rotl/watrer) :
Blank Concentrrtion UnLtg
SAS No. 3 sINt ilIo.r D5f020230
(agll' or ngllcg) :YlGlT.
enaLytc
fnitl-aI
Ca].I.b.
slank(ry/L)
c
Corrts inulng CeI l-bratsion
Blank (ng/L)
1czc3c
Preparat,ios
B]-ank
c u
Cadniun Is"1"q o.oooo,4olul o.0000,40 1uI o,ooo040 Iu
o.0o033olul 0.0003s01u I 0.000330 I u
M
}T
STL Denver FoTUT III IN
205
STL DENVER
Total Metals Arralvsis
-3-
BLANKS
Contract:
Irab Codc t
Pra1laration
PnDult,l-on
URS Corporatlon
STLDTN Cagc No- t
Bl.lnk Matrl,x (eol.llwater) r
glank ConeentrrrtsLon Unl,t e
8Ag No.:SDCI rr0. t D5TA20230
(mgll or mglkg) r I[,,lGIL
Arralyt,c
rnLttal
Ca1lb.
Blanlr
(nglr")c
ContrInulng Call,bratsion
BlanIE (W lll
1 c 7 e 3 c
Pr.,rlar.tto,,
BIrnlr
c M
CadmLum
S.1..i.r-
o.o0o04ol u.f . 0.0000{0 lu I 0,00,00{0-fI,
0.O0O33OlUl 0-0003301U I 0.000330 I u
M-M
STL Denver Forrr III F IN
247
STL DENVER
Total Metals Analvsis
-4-
ICP INTERFERENCE CHBCK SAIVIPLE
Contractr: IIRB Corlpration
r,ab Codc s STITDEN Crsc No. t
rCP rD ![umbrrrr TJI' InErepid ICP
SAS No.:SDO NO. r D5I020230
ICg Sorrrcc r Hlgh Prrri"ty, 8pex,
Conccntratsioa ual.ta) r tug /r.
enalytc
T:nr
so1 .A fI01 .^Lri
rnltLal Found
gol,A 8oI..AB ,6R
a
rinal Found
EoI .A So1 ..AB r5R
lel*Lnum Hl I 500.0 500, 0 505.30 s18.30 | r03.7 I
alcirrm Hl 500.0 500 .0 17 L. 19 {7 6.1e I S5.2 I
Jrron Hl I 200.0 200.0 196.73 189.291 94.51
PotaasLrrm o-o 50-o -0.042 56,33 I L1,?.71
IM.g*"aLum 500.0 500 .0 516 .23 524 , {t J r04 .91
iun Iro 0.0 0.008
um HL 50 .0 53. 22ll 105. { I
Zirconium 0-0 1.0 -0 - 007 1.1951 119.51
STL Denver Fom IV IN
208
STL DET,{VER
Total Metals Analvsis
-4-
ICP INTERFERENCE CHECK SA]VIPLE
Coutrect r IIRS Corporctl,on
r,ab codc r STLDEIU Casc llo. t
ICP ID Nunbar: fJA fntrrr1lid ICP
slg I\[o. 3 sDo DIo. : D5IO20230
ICg Eorrrcr:Hlgh Purl-ty, Spex,
Coneentration unl,tr) r rra.slL
fn{tJ-a1 Found
Sol .A SoI-..r8
Flua]' Found
EIo]..l SoI .lB
Trrre
Glol .A gol .lB
Jefuninun Hi I 5O0. O 500.0 526 .7 A szs.30 I r05.1 I
alcium Hl. I SO0. o 500.0 5 03 , tLlL 499 .27 I S9. 9 I
Iron Hi I ZO0. O 200.0 200.09 198.31 ] S9.21
Potaggl-um I 0 .0 50 .0 -o - o11 55.6t I 111.3 IgEresirrm I SOO-O 500.0 515 .82 51{.98 | rOr.0 I
Sod.Lurr Iro I 0-O 0 .031
Sodtun Hi 50.0 5{. 32|! 108.6 IZiroonLrun I O-O 1.0 -0.002 1.1{2 I 114.2 I
STL Denver f,om IV - IN
2A9
STL DENVER
Total Metals Analvsis
4-
ICP INTERT'ERENCE CHECK SAIVIPLE
Contract r IIRS Corporatrlon
LAb COdC: STLDEN CArr NO. T
ICP rD Nugrbcr: TiIl' Intrcpid ICP
SlSt No. r gDO No. r D5I020230
ICg Souroer Higrh PurJ.ty, Spex,
ConcentratLon Unitt) r mglt
nne.I.fto
trrmc
8o1 -A 8o1 .AB
rnit.ial round,
So1.t SoI ..[B tR
Fin,al l!'or:nd
8o1 -t sol,JLB 96R
lrotaaoLrrrn I 0. O 50.0 -0.055 55.9{111.9
Sodium Lo 0-o -0. o22
Sodiun IIL 50 .0 5d ,07 108 .1
STL Denver Folm IV - IN
2L0
STL DENVER
Total Metals Analvsis
ri-
ICP INTERFERENCE C}IECK SA]VIPLE
eonEraet r IIRS Cora>oratl-on
f,ab Codr r STITDIIN Catt No. i 8l.g No. r sDo No. r D5To20230
fCg ElouroGr HI-gh Ptrrit,y, Spex,ICP ID lrtrrnbcr: SUPIRTRACE rI
Tnra
SoI ..L SoL..}B
ConccntrltLon UnLts);ntglE,
rnitial D'ound
So1 .A 8o1 .^AB
rlnal rouad
8o1 .^lL So1 .AB
lnreeuio I O. O0 2.00 o.003 2. 09 I 104.5 |
JBariun I O.OO o. 50 o. oo1 o.5{9 | ro9 .8 Irrm I O.O0 0,50 0.004 0.51{ I 102.81
oppor I 0. O0 0.50 o,003 0. s6o l LLz. O l
JLead --f- 0. O0 1.00 -o,002 1-03l 1o3,OI
Iurctrer- o. oo 1. OO o.004 1.01 I 101.0 I
Sil-vrrr I O. OO 1- 00 0.001 1.101 rro.ol
anad,Lurn I O. O0 0. 50 0,005 o. 521 I 104 -2llnc I o.o 1,O 0.005 1.031 103-Ol
STL Denver Form IV - IN
2LA
STL DENYER
I'otal Metals Analvsis
4-
ICP INTIiRFERENCB CIIBCK SAMPLE
eontracts: IIRS Cor2orat:ton
r,ab Codc: STLDEN Carc No. t 8 S ![o,r SDo NO. r D5T.A20230
ICS Sourec:Ei.gh f\rrlty, Spcx,ICP ID Mrrnbcrt BT,PERTR.},EE II
Trrn
Bo1 -A EloL..}I]
Concentration uaLta) I lllg IL
rnitial found
80I .A f,0L.LIt
Fl.na1 Found
EoL.l, SoL -lII
lrrecnic
lBarLrun
um
ppcr
INlckeI
SL lrrcr
[Vanad.lurr
Zinc
o.00
0.00
0. oo
0. oo
o .00
o,00
o-oo
o-00
0.0
-0.005 2.11 I ros.5 I
0.50 0. 001 0,5501 110.01,
llrronl.urn I O.OO 0.50 o.003 o .516 I 1O3 .2 I
0 .50 0.003 o. 558 I 111. 6 I
1.00 -0.003 1,031 1o3.Ol
1,00 0 - 002 1. 01 1 101.0 1
1. 00 o. 001 1.101 11O,Ol
0.50 o. oo4 o . s z,.l 104 .21
1.0 0.00{1.03 I 103 .0 I
STL Denver
Form, IV IN
212
STLDENVER
Total Metals Analvsis
4-
ICP INTERSER"ENCE CIIECK SAIUPLE
Contraot: IIRS Corporation
Lrb Codc s STLIIEN
ICP rD Nunbrrt PE ICPM9
Caeg No.3 g.trg No.:sDg Ho. r D5IO20230
ICA Eorrrcr:fnorgrnic Vent,urGB
ConccntraEton Unl,ts) r tuslL
-
Tnrc I rnitlal Found, J rinrl Eound
.larlttc I sor.r Bor.rB lsot.e sol.rB tR lsor..n 9o1 .lB *R
0 .0974
0.1089 I 109.9 o.1095
STL Denver Form MN 21,_3
ffiSTL
URS Corporatlon
Total Metals Analysis Dnta Sheet
Lsb Name:
LoUSDC Number:
Mrtrlx:
o/o Malsture:
Basls:
Analysls Method:
Unit:
QC Batch ID:
MS Srrnple Aliquot:
MS Dllutlon Factor:
STL DENVER
Dsl02023o
WATER
N'&
IysT
60r 0B
rng/L
s242LlJ
50 mL
IO
Cllent Snntple ID:
MS Lsb Sample ID:
MS Lab Workorder:
Date./f lme Collectetl :
Dtte/Tlme Recelved:
Date/Time Leached:
Date/Time Ertrtcted:
Date/Tlme Analyzed:
Instrument lD:
swB-I0-0e0l0s
psr020230-004s
HJYQ9
09/01/05 12: I 0
09/02/05 09:00
09115i05 I5:30
09119/$5 17:32
02t
Analyte
Spike
Amount
Sample
Result C
MS
Result C
a/o
Rcc a QC
Llmlt
Aluminum 2.00 0. l7 U r.84 90 83 - r 19
Calciurn 50.0 I 500 t47A MSB NC 48 - r53
Iron I.00 0.38 B 1.76 138 s2 - 155
Magncsium s0.0 r 200 J I 180 MSB NC 62 - 146
Potassiunr 50.0 r 700 174(t MSB N(:76 - t37
Sodium 50,0 33000 31700 MSB NC 7a - 203
Zirconiurn 0.s00 0.0t6 U 0.50s t0l 80 - 120
STL Denver
Form 5A MS Analysis Data Sheet Eqaivalent
21,4
ffisrr
URS Corporation
Totrl Metrls Analysls Datt Sheet
Latr Name:
Lot/SD(i Number:
Matrix:
o/o Molgture:
Brrsis:
Analysls Method:
Unit:
QC Batch ID:
MSD Stmple Aliquot:
MSD Dllutlon Factor:
STL DENVER
pst02_0230
WATER
N/A
Wst
60I OB
IF9/L
s?496t7
50 mL
r!
Client Srmple ID:
MSI) Lab Sample lD:
MSt) Lab Workorder:
D*e/Time Collected:
Date/Tlme Recelved:
DatelTime Leached:
Date/Tlme Extracted:
Date/Tlme Analyzed:
Instrument ID:
swB-r 0-090105
p5r0z0z30-00+o
HJVQ9
09i01105 I2: I0
09/02/05 09:00
09/15/05 I5:30
A9/19105 17:12
@L
Analyte Splke
Amount
Semple
Result
C MSD
Result
C % Itec a RPD a
QC Llmlts
7o Rec RPD
Aluminum 2.00 0-I7 LJ I .88 92 2.2 83 - I 19 25
Calcium s0.0 r s00 r 510 MSB NC NC 48 - 153 25
Iron 1.00 0.38 B 1.24 87 34 *s2 - lss 25
Magnesium 50.0 I 200 J r 200 MSB NC NC 62 - t46 25
Potassium s0.0 l 700 r 790 MSB NC NC 76 - 137 25
Socliurn s0.0 33f,00 33600 MSB NC NC 7A - 203 aol
Zirconium 0.s00 0.0r 6 U 0.522 IM 3.2 80 - 120 2il
STL Denver
Form 5A MSD Analysis Data Sheet Equivalent
275
ffisrt
URS Corporation
Total Metals Analysls Data Sheet
l,ab Nrme:
Lot/SDG Number:
M.atrlx:
7" Molsture:
Basls:
Analysis Method:
Unit:
QC Batch ID:
MS Sample Aliquot:
MS Dilution Factor:
STL DENY-HB
psr02o23q
WATEB
NA
-&
60I OB
nrg/L
sz498t7
50 ml.
5
L
Cllent Sample ID:
MS Lab Sample ID:
MS Lnb WorkOrder;
Datc/Time Collected:
Dste/Time Received:
Drte/l'ime Lenched:
Date/Tlme Extracted:
Dtte/Time .A,ntlyzed:
Instrument lD:
swB-l0-090105
ps1020230-004s
FIJVQg
0.9J01/0s 12: I 0
0e/$?/.Q5 0e:00
09115/05 l5:30
0PJIS/O[ 21.:00
Q20
Analyte Splke
Amount
Sample
Result C
MS
Result C
%
Rec a QC
Limit
Arsenic 2.00 0_02s B 2.55 r26 N 84 - t24
Barium 2.00 0.41 2.47 r03 85 - I20
Clrrornium 0.200 0.0 r3 U 4.2t9 il0 73 - 135
Coppcr 0.2s0 0.u22 U 0.3I I t24 82 - t29
[,cad 0.500 0,0r3 U 0.43s 87 N 89 - r2t
Nickcl 0.500 0.016 B 0.s64 r r0 84 - 120
Silvcr 0.0s0r)0.014 U 0.0626 t25 75 - r4l
)anadium 0.500 0.0t4 B 0.56s lt0 85 - r20
7
Zinc 0.s00 a.024 B 0.622 I20 60- I37
STL Denver
Form 5A MS Analysis Data Sheet Equivalent
276
ffisrr
URS Corporttion
Totel Metals Analysis Datn
Ltb Name:
Lot/SDG Number:
Mttrlx:
7o Moisture:
Basls:
Antlysls Method:
Unlt:
QC Batch lD:
MSD Sample Allquot:
MSD Dllutlon Factor:
STI qENVER
D5102()230
WATER
N/A
Yt!
(i0l 0B
rnc/L
s2496t7
50 nrl.
I
Shcet
Cllent Sample ID:
MSD Lnb Srmple ID:
MSD Lnb Workorder:
Date/Tlme Collected:
Date/Ttme Received:
Date/Time Lerrched:
Date/Tlme Extrrcted:
Date/Tlnre Anrlyzetl:
Instrument ID:
swB-10-.090.1 0I
D5JQ?0;230-oo4rl
H.rvQe
09/01/05 t2: I0
0gl0r/05 09:fi)
09/l5/05 I -5:30
0e/16/0s 2l;.0!
t)20
Analyte Spike
Arnount
Snmple
Result
C MSD
Result
C o/o Rec a RPt}a
QC l-,lmlts
7u Rec RPD
Arsenic 2.00 0.025 B 2.52 r25 N l.z 8l -124 25
Bariurn 2.00 0.4 r 2.48 103 0,30 85 - 120 25
(hromium 0.2()0 0.0t3 TI 0.2r6 r08 I.5 73 r35 25
Copper 0.250 0.022 TJ 0.30 t 120 3.0 82 - t29 25
Lead 0.s00 0.0r 3 U 0.558 I 12 25 .rtg - tzl 25
Nickel 0.500 0.0t6 B 0.s57 t08 I-3 84 - 120 2A
Silvcr 0.0500 0.0 t4 U 0.0618 124 1.4 75 - l4l 2I
Vanadium 0.500 0.0r4 B 0.56r 109 0.66 ri5 - 120 25
Zinc 0.500 0.024 B 0.646 124 3.7 60 - r37 25
STL Denver
f'orm 5A MSD Analysis Data Sheet Equlvulent
21,7
ffiSTt
URS Corporation
Total Metals Analysls Data Sheet
Ltb Name:
LoUSDG Number:
Mntrlx:
7o Molsture:
Busis:
Analysis Method:
Unlt:
QC Brtch ID:
MS Sample Aliquot:
MS Dllution Factor:
$IL DENVER
Ds1020230
WATFR
N'A
-UUst
747$A
mg/1.
525834rt
I
Client Sample ID:
MS Lab Samplc ID:
MS Lab Workorder:
Date/Tlme Collccted:
Drte/Time Recelved:
Date/Tlme Leached:
Drte/Time lfxtracted:
Drte/Ttme Annlyzed:
Instrument ID:
swB-r 0-0901 0s
D5r020230-004s
HJvqe
0e101105 I2;lQ
09/02/05 09:00
09/19/05 l2:30
09/19/05 I6:43
019
Anelyte Splke
Amount
Snmple
Result C
MS
Result C
oh
Rec a QC
Llmtt
Mercury 0.00500 0_000027 U 0.00142 28 N 8s - I 14
STL Denver
Form 5A I][S Analysls Data Sheet Equivalent
ffiSTt
URS Corporation
Tottl Metals Analysis Data Sheet
Lab Name:
Lot/SDG Number:
Mntrix:
Vo Molsture:
llrsis:
Annlysis Method:
Unit:
QC Batch ID:
MSD Sample Allquot:
MSD Dilution Factor:
STL I}ENVER
DJI020^10
WATER
NlA
UIeI
7470/.
rng/L
s2s83*,[
T
Cllent Sample ID:
MSD Lnb Snmple ID:
wISD Lab Work0rder:
Date/Tlme Collected;
Date/Tlme Recolvedr
DatelTime Lerched:
Date/Tlme Extracted:
Dnte/Time Analyz-ed;
Instrument ID:
swB-l0-090105
nsl020?g):00SD
HIVqe
09/01/05 l2:10
0,9102105 09:00
09/19/05 I2:30
03t19/0s I.6:+3
ot_g
Analyte Spike
Amount
Srmple
Result
C MSt}
Result
C 7" Rec a RPD a
QC l,lmlts
7o Rec RPD
Mcrcury 0.00500 0.000027 U 0,00 r42 28 N 0.15 85 - r 14 t0
STL Denver
Form 5A MSD Analysls Data Sheet Equivalent
2l.9
ffiSTL
URS Corporation
Totel Metals Aurlysis Data Sheet
l,ab Name:
l,oUSDG Number:
Mrtrlx:
%o Molsture:
Basis:
Anelysis Method:
Unlt:
QC Batch ID:
MS Stmple Aliquot:
MS Dllution Factor:
s'l'l nENVER
p5l0'0230
wArnn
N/n
Us
7*7QA
mg/L
526248$
l-
Client Sample ID:
MS Lab Sample [D:
MS Lab Workorder:
Date/Tlme Collected:
Dnte/Tlme Recelvcd:
Date/'l'ime l.,eached:
Date/Time Extracted:
Dute/Tlme Annlyzxl:
Instrument ID:
LAB MS/MSD
psr r 70 r e&0Q [s
HKTI ti
09/l 5/0-5 I a:30
09/17105 09: l5
ae/2T45. .w3a
09/22105 L9:33
0r_9
Annlyte
Splke
Amount
Snmple
Result C
MS
Result C
o/o
Rec a QC
Llmlt
Mcrcury 0.00s00 0.000027 U 0.0041.3 84 N 85 - r 14
STL Denver
fr orm 5A MS Analysis Data Sheet Equivalent
224
STL
URS Corporation
Total Metals Analysls Data $heet
Lab Name:
LoUSDG Number:
Matrix:
7o Moisture:
Basls:
Analysis Method:
Unlt:
QC Botch ID:
MSD Sample Aliquot:
MSD tlilutlon B'rctor:
STI, DENVER
Dst020230
WATER
N/A
Wet
7470A
nils.ll
52(t2!86
l_
Client Sample ID:
MSD Lab Sample ID:
MSD Lnb Workorder:
DateJTlmc Collected:
Date/Time Recelved:
Date/Tlnc Leached:
tlatc/Tinre Extracted :
Date/Tlrnc Anrlyzed:
lnstrument ID:
L\R MS/MSD
p5ll70r e6-o0l D
HKTI E
09i l5105 la:3Q
091I 7/05_09: l5
}e.{LHAS V:10
Qet2z/05 -.19:33
0r-2
Analyte Spike
Amount
Sample
Result
C MSD
Result
C 7" Rec a RPD a
aC Llmits
7o Rec RI,I)
Mucury 0.00s00 0.000027 TJ 0.00389 78 N 7.2 85 - I 14 l0
STL Denver
f orm 5A MSD Analysis Data Sheet Equivolent
224
ffisTr
URS Corporation
Total Metals Analysis Datn
Lab Name:
Lot/SI)(I Number:
Mntrix:
7o Molsture:
Basls:
Analysis Method:
Unit:
QC Batch lD:
MS Snrnple Allquot:
MS Dllution Fac.tor:
STI, DENVER
p51020230
WATER
N/A
we(
6020
tng/L
52{e6 I 6
50 mL
40
Sheet
Client Sample ID:
MS Ltb Sample ID:
MS Lab Workorder:
Date/Tlme Collected:
Dste/Tlme Recelved:
Datelfime Leached:
Date/Tlme Extracted:
Datel'fime Analyz*d:
lnstrument ID:
swB-10.:99010s
Dsr020230-004s
HJVOg
09/01/05 I2:10
Qe/Q2l05 0e:00
09/15/0I -I5:30
0c)123105 l2:tb
004
Antlyte Splke
Amount
Sample
Re*lult C
MS
Result C
Yo
Rcc a QC
l,lmlt
Cadrniurn 0.0400 0.0016 L'0.0242 60 N 89 - il()
Sclcniunr 0.0400 0,040 B 0.10e 172 N 82 - I t2
STL Denver
Form 5A MS Analysls Data Sheet Equivalent
222
ffiSTL
URS Corporation
'l'otal Metals Analysls Data
Lnb Name:
LotlSDG Number:
Mntrix:
t/o Molsturc:
Busis:
Analysis Method:
Llnlt:
QC llarch ID:
MSD Stmple Allquot:
MSD Dilutlon Factor:
sTr, pf,NvER
p5roan23o
WATER
NiA
Wct
6020
n0gt
s24901-0
50 rnl.
40
Sheet
Cllent Srmple ID;
MSD Lab Sample ID:
MSD Lth trVork0rder:
Ilate/Tlme Collected;
Date/Tlme Recelved:
DttdTime Leached:
DrtteIl'ime E,x trtcted :
Date/Tlme Annlyzed:
lnstrument ID:
swB-10-09010s
ps1020230-004D
HJVclg
09/01i05 I 2: l0
09/02i05 09:00
09/15/05 l5:30
09/.21{05-.I2rt0
O(ts
Anolyte Splke
Amount
Sample
Resutt
C MSD
Rcsult
C 7o Rec a RPD a
QC Llmits
7" Rcc RPI}
Cadrniunr 0.0400 0.00 r 6 U 4.0277 69 N I3 89 - I l0 20
Seleniurn 0.0400 0.040 B 0.0998 149 N 8.9 82- lr2 20
STL Denver
Form 5A MSD Analysis Data Sheet Equivalent
223
STL DENVER
Total Metals Analvsis
-58-
POST DIGES'I SPIKE SAMPLE RECOVERY
Contraet: URS Coqporation
Lab Code: STLIIEN Cagc No. r SlS, No. r sDO No.: D5I020230
!ilrtrix ( goll /watorl r I{l'TtR Lcvc1 ( Iow/rrcd) t
SAIUPITE NO.
s$tB-10-090105 PDs
ConccntrltLon UnLter mg lI'
.}nalyEe Control
r,imLt, tR
Spl,kcd Sangrle
Regults (SgR) C
Samplc
Rcault ( Onl c
Spl,ke
.Ldded,(8}')BR a M
Cadmiuur ) 75 125 0 . 183 937 o,oooo4olu I o.2o 92.4 M
Sel-enLrrm I 75 L25 0 .195409 0.001007 I B 0.20 97 .2 M
o
Cormtcn
STL Denver Forrr V (PART 2l r IN 224
ffi$Tr"
URS Corporadon
Total Mettls Anrlysis Data
Lab Nsme:
LoUSDG Nurnber:
Mrtrix:
7o Moisture:
Brsis:
Antlysls Method:
Unlt;
QC Batch ID:
Sample Aliquot:
Dllutlon l-rctor:
STL DENVER
D5r020230
VTATER
NIA
Wet
60LoB
mslL
sz4e[]7
50 mL
I
Sheet
Cllent Sample II):
Lab Sample ID;
Lab Workorder:
Date/Tkne Collected:
Date/Tlme Recelved:
Date/Tlme Leached:
Date/I'ime Ertracted:
Dnte/Time Analyzed:
Instrument ID:
D5t060000417c
I IJ2JJ
09/15/05 l5:30
09/16/QS 16;24
aet
A.nrlyte 'f rue Found ToRec a Limits
Aluminurn 2.00 1.95 9't 86 - t08
Irrrn t.00 (),964 96 88 - I r0
Magnesiurn s0.0 49.1 98 9t-1il
Potassiurn 50.0 50.9 t02 86- rll
Sodium s0.0 47.9 96 9l - lt2
Zirconiurn 0.s00 0.s38 r0g 75 - 125
STL Denver
Form 7 LCS Analysis Data Sheet Equivalent
225
ffisrt
URS Corporadon
Total Metals Analysls Date Sheet
l,nb Nnrne:
I,oUSD(I Number:
Mutrtx:
ol, Moisturc:
Bmis:
Analysls Method:
Unlt:
QC Batch ID:
Sample Aliquot:
Dllutlon Frctor:
s'I'r .pFNVER
psL020?30
WATF.R.
wA
wcl
6010F
rnq/L
s7496t1
50 rnl
I
Cllent Sample ID:
Lsb Sample ID:
Lab r#orkOrder:
tlate/Tlme Collected:
tlatelTlrne Received:
Date/f ime Lenched:
Date/Tlmc Ertrrcted:
Date/Tlme Annlyz.ed:
Instrumcnt ID:
f,)5r060000-6r 7c
I{J2JJ
Oei l5/QL .t5:30
09/ I 919..1- l7: l8
92L
Antlyte True Found ToRcc a Limits
Calciurn s0.0 48.tr 98 89 - r r0
STL Denver
Form 7 LCS Analysis Data Sheet Equivulent
226
ffisTt
URS Corporation
'I'otal Mettls Analysls Drrtu Sheet
Lab Namc:
LoUSDG Nurnber:
Mrtrlx:
o/o Molsture:
Basis:
Analysis Method:
Unlt:
QC Batch lD:
Sample Aliquot:
Dilutlon F'ac{or:
STL DENVER
p5r020230
wATER
N/A
lYsI
s0r0B
StL
52!9617
50 mL
t
Client Snmple ID:
Lab Sarnple ID:
Lab Workorder:
Date/Tlme Collected:
Date/Tlme Received:
tlete/Tlme Leached:
Date/Tlme Extracted:
Date/Time Analyzed:
Instrument ID:
Dl06oo0o-617c
HJ2JJ
09ll s/05 ,.t5:30
Oell8/05 la;18
020
Anulyte True Found ToRec a Lirnits
Arucnic 2.00 r.93 97 89 - r09
Lcad 0-500 0.483 9l 9I-III
Barium 2.()0 2.01 r00 93 - r 13
Nickcl 0.500 0.49r 98 90 - I l0
Silver 0.0500 0.0494 99 85 - l 14
Vanadiunr 0.500 0.499 r00 88 - r 12
Zinc 0.s00 0.474 9s 85 - l l0
Chrt>rniunt 0.200 0.1 97 e1)8e- r12 I
Oopper 0.2s0 0-235 94 86- ilO
STL Denver
Form 7I.CS Analysis Data Sheet Equivalent
227
ffisrt
URS Corporation
Total Metals Antlysis Data Sheet
Lab Name:
LoUSDG Nurnber:
Matrlx:
% Moisturc:
Besis:
Analysls Method:
Llnlt:
QC Batch ID:
Sample Allquot:
Dilutton Frctor:
STL DENVIiR
Ds102023!
WATtrB
N/A
Wct
7470b
nrg/L
52s834,1
.L
Cllent Sample ID:
Lab Sample lt):
Lnb WorkOrder:
Detefl'ime Collectcd:
Date/Tlme Recclved;
Dateffime Lenched:
Date/Tirne Extractcd:
Date/Tlme Analyeed:
Instrurnent I D:
D5l I50000-348C
HKMDL
09/19/05 I2:30
09/19/0s I6:33.
0I9
Analyte True Found TsRec a Llmlts
Mercury 0,00500 0.0048tr e8 85 - t 14
STL Denver
Form 7 LCS Analysis Data Sheet Equivalent
228
ffiSTt
URS Corporation
Total Metals Analysls Data
I..ab Nnme:
Lot/SDG Number:
Matrir:
o/" Moisture:
Basis:
Analysls Method:
Unlt:
QC tlatch trD:
Srmple Aliquot:
Dllutlon ]-sctor:
STL DENVER
psr02021Q
WATER
br/A
Wet
74704
msll
5?"5tr348
I
Sheet
Cllent Sample II):
Lab Strnple lD:
Lab Workorder:
Datc/Tlme Collected:
Drte/Tlme Recelved:
Dnte/Tlmc Lerched:
Datc/Time Extracted:
Datefl'ime Anrlyzed:
Instrument ID:
p5r r so000-34$L
HKMDL
09/19i05 I2:30
09/19/05 l6:3a
tug
Analyte True Found C 7" Rec a RPt}a
QC Lirnits
7" Rec RPD
Mcrcury 0.00500 ().00505 t0r J.J 85-n4 t0
STL Denver
Form 7 LCSD Analysis Dato Sheet Equivalent
229
ffisrr
URS Corporatlon
'l'otal Metals Anelysis Data Sheet
Lab Nnme:
I-oUSDG Nurnber:
Matrix:
7o Moisture:
Brsis:
Analysis lVlethod:
Urrlt:
QC Batch lD:
Srmplc Aliquot:
Dllutlon Factor:
STL DENVER
D.II020230
WA'.TER
N/A
wst
7470A
ms/I-,
s262*86
1
Cllent Sample lD:
Lab Sarnple ID:
Lab WorkOrder:
Date/Time Collectcd:
Date/Tirne RecelYed:
Date/Tlme Lcached:
Dntc/Time Extrnctcd:
Date/Tlme Analyzcd:
Instrument ID:
ps"tl-eo00o486c
HKWI9
09t22/05 ta30
091ZTA5 l9:?t
0t9
Analyte True Found ToRec a Llmits
Mcrcury 0.00500 0.00s 18 r04 85 - I t4
STL Denver
Form 7 LCS Analysis Duta Sheet Equivalent
230
ffiSTt
IIRS Corporatlon
Total Metals Analysis Data Sheet
Lab Nsme:
l-oUSDC Nunrber:
Matrlx:
o/, Moisture:
Basis:
Analysir Method:
Unit:
QC Batch ID:
Sample Aliqurx:
Dllution Frctor:
STL DENVER
D51020230
WATER
N/A
lYiI
7470A.
mgll..
5"62486
I
Client Sample ID:
Lab Srmple ID:
l,,ab WorkOrder:
Date/Tlme Collected:
Drte/f ime Received:
Detcflfinre Lerched:
Date/Time llxtructed:
Date/Time Antlyzed:
Instrument ID:
pst r 90000+861.
I IKW 19
a9D2t05 14.30
09/22/Q5 19:23
Ql_t
Analyte True Found C 7o Rec 0 RPD a
QC Limits
o/o Rec RPI)
Mcrcury 0.00500 0.005 t 2 r02 1.2 85 - 114 t0
STL Denver
f-orm 7 LCSD Analysis Data Sheet Equivalent
23L
ffisrt
URS Corporetion
Total Metals Analysls Data Shect
Ltb Name:
Lot/SDG Number:
Matrix:
7o Molsture:
Basls:
Antlysis Method:
Unit:
QC Batch lD:
Sample Aliquot:
Dilution Fsctor:
STL DENVER
pslg20230
WATI]R
}UA
Wct
6020
mg/L
s2426t6
50 m[,
I
Client Stnrple ID:
Lab Sample lD:
[,ab Workorder:
Date/Tlme Collected:
Datc/Time Recelved:
Dtte/Tlme Leached:
Date/Tlme Extracted:
DntelTime Analyzed:
Instrument ID:
p5r060000-616Q
HJ2JG
09/15/05 l5:30
09123t0s 07:21
Q04
I orm 7 LCS Analysis Du:tu Sheet Equivalent
Analyte True Found ToRec 0 Limits
Selcniurn 0.0400 0.0362 90 82-fiZ
Cadmiurn 0.0,400 0.0394 99 89 - r r0
STL Denver 232
STL DENVER
Total Metals Analysis
-9-
ICP SERIAL DILUTIONS
Contract r IIRS Corporat,l.on
SAMPITE DIO.
srirB-10-090105 sER
SDGI EIO. r D5I020230
Lrwr1. (lovrr/rnrd): ITOIII
r,ab Code : S1DLDEN Cur No. r
Matrix (aofl/water) : [![LTER
SAS No. t
ConoanrtratsIon unltg 3 mglL
AnrLyte
rniEial SamIrIe
RcruLt (r)
c
Seriel Dilution
RceuIE (s)
e
9G
DLffcr-
(Dncc
a M
J a,luninrrm I 0.017 U 0.085 P
Calelum II 150.6{156 -46 3.9 P
Iron lro 0.038 B 0.105 U 100. o P
Potaggirrrn L7 0. 63 159.83 5-3 P
Magnrasiun 115.15 LL7 .7 4 2-2 P
Sod1r:m Hr 3292.40 31{4.80 {.5 P
Zirconiurn o. 00160 U 0 - 00800 TI F
STL Denver
Forn IX III
233
STL DETWER
'fotal Metals Analvsis
-9-
ICP SERIAL DTLUTIONS
Contsraot r IJRS Cora>oraBLon
a.ruPrJE
SU{IB-10-090105 SER
gDO NO. r Dsr 020230
Lsnr1 ( low/ncd) t
Lrb Code : STITDEN
Matrlx (goil/watcr): WITTER
Cagc No. I grg No. r
ConocnEration Uuit;r mfrlL
Anal.ytc
-nLtial Banpl-c
Rrlu].t ( r )
C
Srrlrl PLl-ution
Rosults (g)
c
96
DLffrr-
ence
a M
I ereenio I o. o0{9 B o. o22o Ju 100. o P
Barl,un o.093 o.085 I 3.6 P
um 0.00260 u 0. 01300 lu P
Copper 0.0045 U o, 0225 [U P
0,0025 u o. o13o lu P
NiokeI-o , 0033 B o . oo5o Ju 100. o P
SLl-ver o. 00?80 U o. o14oo [u P
Vaned,Lum 0.0027 B O. o12s Ju 100.0 P
Zinc o-oo5 B o. 025 [u 100. o P
STL Denver ForN IX IN
STL DENVER
Total Metals Analvsis
-9-
ICP SERIAL DILUTIONS
Contract r IIRB Corporat,Loa
SADTPLE NO,
sgirB-10-090105 gtR
sDc No,: D5T020230
Lcvc1 (Low/med) :
LEb codc: STLDEN Cagc No. t S.e,S No - :
Matrix (;ol-I/watcr) r WATEB'
Concentre,tLon tDrits : tw lL
lna,lytc
-nitirl Earuple
Regult ( r )
c
Sarial Pil.ut:lon
Rcgu1t (s)
c
96
Diffor-
cnoc
0 M
I cadlnLum o . 00 00{0 u O. OOO2oo lu M
Srrlenium 0.001 007 B 0. oo16so Ju 1OO. ol ITI
STL Denver Form IX M 235
STL DENVER
Total Metals Analysis
- t0-
M ETHOD DETE,CTION LII\{ITS
Contsract: URS CorporatLon
Lrl, Codc r STLDTN Ce,tc No. t
ICP fD Numbrrr fJtr Intreptd ICP
T1anc ^[l, ID Dhunbcrr
I\rrrrrcc JfA fD Dlurrbcr:
Sf,g No. :
Datc r 5tLAl2005
ADCI NO-: D5I020230
Analytc
ltlavc-
lcngth
(m)
Back-
ground PQI,
(ng/L)
MDIr
(nglL)M
Llr:rninurn t 167.O 0,10 0.017 I p
AlumLnunr Il 309 .2 1.0 P
lC-I-Eutrr t 317.933 0.20 I o. o34 I p
Calcl.urn H 318.1 10 P
lrron Lo 259.9 0.10 0-021 lP
fron IIi 2,7 L . illll 1.0t lP
lPotasilun 766.{91 3,0 0.24 lP
Magncgiuln I
Scrd { rrm Tn I
i27s.078 I
-
i58q-E I
0.20 I 0.043t
1_ol n o?l
P
F
F
F
Sodium Hl,
ffi
10 I
otrunGnte:
STL Denver Foru X IN 236
STL DENYER
Total Metals Analysis
-I0-
M E'THOD DETECTION LITUITS
ConEract: IIRS CorporatLon
Lrab Codc: STITDEN Cage ![c> - :
ICP ID Nunbcr: SITPI9RTRACE ff
rlamc Le, fD Mrrnberr
E\rrrracc .hl, fD Numbrr:
S.LS t{o, t
Date:s/La12005
sDCl No. r DSf 020230
ArraJ-ytr
Wava-
langth
(nm)
Brck-
ground,PQL
(mglL)
IYIDIJ
(rrylr,)!{
ArarrnLe 1gg.o42 0.010 o. 004{P
Brrium 493.409 0.010 0..00070 P
Chromlum 267. ?16 0.010 o.0026 P
CopDer 324,753 0 .010 0 . o0{5 P
Laad 220.353 0.0050 0.0026 P
NickG]-23I..60{0 .0{0 0.00L2 P
Sl,Lvcr 328 - 059 0-010 o.oo28 P
pa;m-fuut 292 .442 0-010 o.0025 P
Zinc 2L3 - 955 0 .020 0.0045 P
Cornmonte:
STL Denver Fom X IN
237
STL DENVER
Totrl Metals Analysis
-10-
M ETHOD I}ETECTION LIIVIITS
Contract: - IIRS CorDOratl,On
Lab Coder SttDEN
ICP ID lifirrnber:
Case No. t SAS No. l
Drr,r: 9lLSlzAA5,
SDC No.: D5I020230
f,lamc AA ID t{hr.ubar:
hrrnacc fA ID lhrmbcr r
PE C\III'
}rraltrtr
Wwo-
Icngth
( run)
Baok-
ground PQL
lms lnl
!@Ir
(mg/L)M
llercu51,253. 7 0 0.00020 0.000027 gtr
Coruuontg I
STL Denver For:t X - IN 238
STL DENVER
Total Metals Analysis
-I0-
METHOD DETECTION LIMITS
Contract t tlRS Cor:p6lration
Lab Codc: STLDTN
ICP fD Ntrmbcr: PE f CPMS
Flanr AA ID ![\rnber r
hrrnace .[I, ID ]lrrmber:
Clac No,:SJLS No, r
Dat,or 5lLAlz00s
sDcl No. r D5I020230
Inr1.yEc
IrotoDc Brck-
ground PQI,
(ng/r.)
MDL
(ng/L)![
Cadurf.urn 111 o - oo10 0 . 000 0{o ![
SalcnLum 82 .0050 o. 00033 Dt
Comnrants:
STL Denver Forrr X IN 239
STL DENYER
'I'otal Metals Analysis
-11A-
ICP INTERELEMENT CORRECTION FACTOR.S (ANNUALLY)
Contraet r URS CorrooratLon
Lab Code r gTtrDEN
rCP fD ![rfiber: l[JA
Cage No.:
tntrepid IcP
gl,g tilo - 3
Dater 8 llg/2AO5
Dsr02023 0
.rnal1t,c
Wavc-
lcngrttr
(nm)A1
Interelemeat Correctl,on Factorg for r
Ca Fe Mg Ag
/, rrw;-r,' r<-r-r-.r I gg9 ' 198 o. oooooo0 I 0,0000000 o. oo0ooool o. ooo0oo0 I o. ooooooo
rtum!.mrm lfez.0B1 0.0000000 [ 0.0000000 0.00192001 0.0oooooo I o. ooo0000
rlnmlnum lgOg.zTL 0.0000000 | o. oooooo0 o.oooooool o-ooo7?tlol o.00ooo00
Anrimony I ,05.838 0. 00ooooo | 0.0000000 o.00000001 0.0000000| o-ooooooo
.f,rsenic I ttg.0{a o. o0oo0o0 | o. oo000oo o.oooooool o.oooooool o.ooooooo
BarLuru I 005.003 0. 0000000 J o. o0o0o00 o. oooooool o. ooooooo J o - ooooooo
Beryllirrm ISff .Otz 0.0000000 | o. oooooo0 o. oooooooJ o. ooo000o I o. ooooooo
Boron lzag. GTB o. o0000oo I o.00o0ooo o. oooooooJ o. ooooooo I o - ooooooo
cadnLurn 1116.502 o. ooo0000 I 0.0000000 o,ooooczol o.oooooool o.ooooooo
calclum Isrz-933 0.0000000 I o. 0000000 o-00000001 0,0000320f o.ooooooo
lcarciust Iare-12I 0.o00oo0o I o-ooooo0o o.oooooool o.oooooool o.ooooooo
chronLum I ,O't .77-6 0. ooooooo I o.00ooooo o. ooooooo J o. ooooooo ] o. ooooooo
cobalt I zzg. E15 0. o0ooo0o I o.0oo0oo0 0, oooooool o . ooooooo f o. oooo0oo
copper llZtL.zS3 0.0000000 | o.0ooo0oo -0.ooooeool 0.0000000J o-0000000
rron I,s9-9{0 o.00ooooo J o. ooo0000 o-oooooool o-oooooool o,ooooooo
rron lzz1.6d1 o.0ooooo0 I o. o0000oo o. oooooool o. oo2o1oo I o. ooooooo
r,ead lrro.3 s3 0.0000000 I o-ooooo00 o. oooooool o, ooooooo I o. ooooooo
r,Lthtrrm I Sr0.78{o. ooo0000 I 0. oooo55o o. oooooool o. ooooooo I o. ooooooo
Malrnasirrm lzr9. oT9 o. ooooooo l o, ooooooo o. oooeozol o . ooooooo I o. ooooooo
Mangarr€ra lzsz.610 o. ooo0000 I 0.0000000 o. oooooool o. 0000160 ! o. ooooooo
lrolybd.cnrrm lzOZ,030 o. ooooooo I o. ooooooo 0.0000000[
-0.0000000
f 0,0000000
wickel I zs 1. 50 4 tz o.0000000 | o-ooooo00 o. oooooool o. ooooooo I o. ooooooo
Phosptrorus Jfr8.287 o-0000000 I 0.000oooo o. oooooool o - ooooooo I o. ooooooo
Potassium I ,e5. {91 o. ooooooo I o. ooooooo o. ooooooo J o. ooooooo I o. ooooooo
Selcnlum J tgo.090 o. ooooooo I o. ooooooo o.oo00o00l 0.00ooo0ol o.ooooooo
stllcon lzsl-.6l.z o.0ooo000 I o.00oo0o0 o-oooooool o.ooooooo I o-ooooooo
gtrl,con I au1. 615 0.0oooo00 I o-0oo0ooo o. ooooooo[ o. ooooooo I o. ooooooo
Sl }wer I irs. oeo 0.0ooooo0 I o.0oooooo o. oooooool o. ooooooo I o - ooooooo
Bodlrrrn I rg9.59z 0.00ooooo I o.0oooo00 o. oooooool o. ooooooo l o, ooooooo
{rodrllln I ar8.326 0. oooo000 I o.0oo0o00 o - oooooool o. ooooooo I o. ooooooo
ptroatlum lloz .T7L 0.0000000 | 0.0001670 o.oooooooJ o-oooooooJ o.ooooooo
Thallium I fgO. BG{0.0000000 I O. 0000000 o. oooo00ol o. ooooooo l o, ooooooo
E'orm XI (PART 1)IN
Cormrentg:
STL Denve
STL DENYER
Total Metals Analysis
-t1A-
ICP INTERELEMENT CORRECTION FACTOR$ (AI$NUALLY)
Contract: ttRS CorcOOratLoa
Lab Codes SU,DEN Case No.:
Intrepid fePICP ID tftrmberl TJA Dat,e: 81L912005
gl8 No.:SDe NO. r D5I020230
trhorlura | 283 .730 0. 000ooo0 J 0.0000000 0,00085001 o-oooooooI o.ooooooo
Tin I 189.989 0.0000000 J o. ooooooo 0.00000001 o. 0000000 | o. ooooooo
rl.ranlum I ra{ .9{1 0.0000000 I -0-0000320 0.00000001 o. ooooa{o I o. ooooooo
uranl.rrm I raS.95B 0.0000000 I -0.0001020 -0-00085{01 0.0000000 I 0.0000000
vanadlum lzlz -4a2 o - oo0o000 l o, ooooooo 0.00010101 -0-0000130 I o.0000000
zl-ne Iarr.gs6 o-oooo130 I o-0o0oo0o o. o0oo59ol 0.0oo0oo0 I 0. oo0oo0o
Commeuts:
STL Denve
Form XI (PART 1)-IN
STL DENVER
Total Metals Analvsis
-ttB-
tcP INTERELEMENT (IORRECTTON TACTORS (ANNUA I,LY)
Cont,ract r IIRS Corrcoration
rab codes SIItDEN
ICP ID llrrrnber: TJA
Cagc No.3
IntreDid, reP
gAg No.:
Dato: I llg lz00s
gDc DIO. : D5T.O2023 0
r.ualtta
Wave-
length
(nm)Ag
rnteral,emcnt Correct,ion Factorg
BBa
for:
Be Cd
F-r l'-CC;:? r Lr_fi-r I o.00oo00o I o.0000000 o, oo00oo0l 0. oo000oo I o. ooo00oo
Alumlnrun Ifez.081 o. ooo0oo0 I o. oo00oo0 0. ooo0oo0l o. o0ooo00 l 0,0000000
rlumtnum lEo9.27L 0.0000000 I 0.0000000 0.0ooo0ool 0.00000001 o.o00ooo0
Anr,imony lzo6. B38 0.0000000 I o.0ooo00o o.0oo0oool o. oooo00o I o.00oo00o
rrscnic | 1s9 .a42 o.00oo00o I o. oooo00o 0.0ooo0ool o. o00oooo I o. o00ooo0
Barl-urn I OrS. {03 0 - o00oo00 | o. 0o0oo00 o,00oo0o0f o.oo00oool 0.oo00oo0
BerTLLium laff .O$2 0.0000000 | o. o00o0o0 o. o-0o0o0ol o. 0ooo00o | 0.0000000
Boron lzt9.6z8 o .0000000 | o. ooo00oo 0. ooo0oool o.00ooo00 I o.00ooo00
CadurLr:m 1225. 502 o,0000000 I o. 00o00oo 0. ooo0oool o.0oooo0o I o. ooooo00
Calcl,rrm Ift7-933 0.0000000 I o-oo00oo0 o. ooooooof o. o0ooo00 I o. o00oooo
f:alctun 1318.138 0-0000000 | 0.0000000 o. ooooooof o. oooo00o I o. oooooo0
Ehrontum lz0l-,716 o,0000000 | 0.0000000 0. oo00oool 0.0000000 | 0.0000000
Cobalt, |,128.615 0.0000000 I 0.0oo00oo 0. oo000ool o. oo000oo | 0. ooo00oo
coppar I sza.z53 0.0000000 | o.00ooo00 o - 00oooool o. oooo00o I o. ooo0ooo
rron | 259.9{0 o-0000000 | o-o0ooooo o. oooooool o. ooooooo I o. ooooooo
rron lzr 1.4d1 0.00000001 o_0oooo0o o.oo-o0o0o-l 0.0000000| o-0000000
r,ead 1rr0.353 0.0000000 | 0.0000000 o. ooooo0ol o. oooo0oo I o.0ooo0oo
r,ithLum leZo.T8{o.00o00oo I 0.0000000 o. ooo0oool o. oooooo0 I 0. oo00ooo
Irlagmcslum 127 9.079 0.0000000 I o.0000000 o.00ooo0ol o, ooooo00 l o. oo00oo0
lrraBganGso lzst.610 0.0000000 | 0.0000000 o.oooooool o-oooooool o,ooooooo
MolYbdenufi IZOZ.030 0.0000000 I 0.0000000 o. ooooooo l o. ooooooo f o, ooooooo
uichcl la3r..GoL/2 0. oo0ooo0 [ o. ooo00oo o. oooooool o. ooooooo I o. ooooooo
nhosptronrr IfZ8.Zg7 0.0000000 I o. oo00ooo o.oooooool o.oooooool o.ooooooo
Potasstum 1766. {91 0.0000000 I 0.0000000 o. oooooool o. ooooooo I o. o0o0ooo
selcni.um Ifr6.090 0.0000000 | 0,0000000 o.0ooo0ool o. ooooooo I o. o0ooooo
sllLcon I,tL.6Lz o.0oo00o0 | 0. o00ooo0 0.0000000f o. ooo000o I 0.0oo00oo
silLcon I ru1.61s o. o0o000o I 0. oo000o0 o.o0o00o0l o.00oooo0f o.oo0oo00
$llver I 329.060 0.0000000 | o, ooooooo 0. 00000001 - 0.0000000 | 0.0000000
Sodium I sB9. 592 o.ooo0ooo f
- oSoooooo o. oo0ooo0l o. oo00ooo I o. o00oo0o
jltT I"8'326 0.00000001 0.o0oo00o o. oooooool o. o0oo00o I o. ooooo00
lrontium I aor.7n 0 .0000000 | o.0ooo00o 0. oo00oo0l o.00ooo0o I o. oooo0oo
Thallium I fgo.8G{0 .0000000 I 0.0000000 o.0oo00ool 0. ooooooo I o. oo0o0oo
lorrunents:
242
STL Denver
Fom XI (PIRT 2l -IN
STL DENVER
Total Metals Analvsis
-1I8.
ICP INTEREI,EMENT CORRECTION FACTOR$ (ANNUALLY)
ColLractr IrRS eomoratLoil
Lab Codo s srrrDEI{Cage No.:
Intrepid fCPICP rD Nuruber: IPJA 8tL9t200s
cormerts:
s.f,g
Date:
gDO NO.: D5TO2O230
lrtroriun | 283 .730 o. ooooooo I 0.0000000 0.0ooooool 0.0000000 I o. ooooooo
rt-n I 189 .989 o.0000ooo I o. oooo000 o - o0000ool 0.0000000 I o. 0000000
rLraniurn leg4.9{1 0.0000000 I 0,00oooo0 0.0000000[ o. ooooo00 I o. ooooooo
uranium I ses.958 o.00ooo00 I 0.0000000 o - 00000001 o. ooooooo I o. 0oooooo
vanadiurn lzlz - 402 0.0000000 | o-oooo0o0 o. oooooool o. ooooooo I o. ooooooo
zinc I ztl.8so 0,0000000 I 0-0o0oo0o o. o0o0oool o - 0oooo0o l o, ooooooo
STL Denver
Eomt XI (PIRT 2l IIN
STL DENVER
Total Metals Analvsis
.I IB.
I C P INTERELEMENT C O RRECTION F'A CTOR$ (ANNI.IA LLY )
Contract: IIRE Corrcoration
rab Codc: S.1II,11EI!
ICP ID Number: TiIA
Care No. t
Intrapid ICP
S.Lg [ilo. t
Dator 8 lLglz00s
Dsr02 023 0
l'na].yte
Wave-
langrtb
(uu)Co
rnterelamant CorreetLon ractors for:
CreuK MA
'{r'r-*rr'r r'r+--f1 I 339 ' 198 0.0000000 I -0.0012800 o.ooooo0ol o.oooooo0l o.oooo000
rlrrutlmrm I te?.081 0.0000000 | o. o00o00o o.0o0ooool 0.00000001 0.0000000
AlumLnurn I f Og.zTL 0.0000000 I o. ooo0000 o.00000001 0.ooooo00l 0.0000000
Anr!.mony I ,06.838 0,0000000 1 0.0000000 0. o0oooool 0.0o0oooo I 0.00ooooo
trrsenic | 189 .a42 0.0000000 | o. o000o0o o. oooooool o. oo000oo I o. o0000oo
sarl,um lass.{03 0. 0000000 I 0. o000ooo 0. oooo0ool o.0000ooo I o. o0o0ooo
Ber:rrll-irrm If ra.A42 0 .0000000 | o. 0000000 0. o00ooool 0. ooooooo I 0. ooooo0o
Boron 1ro9.578 0.0oooo00 I o. oo00ooo 0. oooooool 0.000oooo | 0.0oooooo
Cadruiurn 1225.5oz 0.0000000 | o. o000ooo o. oooooo0l o. ooooooo J o, ooooooo
calclum l S fz.933 o-0000000| 0.0000000 0.00ooooof o.ooooo00f o-0000000
carcium l Sf8,12B 0.0000000 I 0.0000000 o. oooooo0l o. ooooooo I o. ooooooo
Ctrromir,:rn |-26?.zLG 0.0000000 I 0.0oo0o0o o.0o000ool o-0000000I 0.0000720
cobalr lzza.616 0,0000000 | o. ooooo0o o - o0o0oo0l o.00o0ooo I o. ooooooo
Copper I azt. z53 o.00oo0o0 J o.o0oo000 o. oooooool o - ooooooo I o. ooooooo
rron I 2s9.940 0.0000000 | o.0ooo0o0 o. oooooool o. ooooooo I o. ooooooo
rron lrr 1. {{1 0,1300000 I o. o00oo00 0.000ooool 0. ooooo00 I 0. ooo0o00
read 1220.353 0.0000000 I o.00oooo0 o. oooooool o - ooooooo I o. ooooooo
r.Lttrlr:nr I t, A .7 g{0.0000000 J o.00oo00o o. ooooo0ol o. ooooooo l 0,0000000
Magnesiusr lrr9. Oz9 o. o000ooo I o. oooo00o 0.00000001 o.o0o0o00l -0.0035590
r'raagraao,. I asz.610 0.0000000 I 0.0000000 0,00oooool o-0000000| o.0000000
Motybdenrrm jzoz.03o o.000oooo I o. oo00o00 o.ooo0oo0l o.ooooooof o.ooooooo
ulckel lrl1,5 o4t2 0.0000000 I 0.0000000 o. oooooool o. ooooooo I o. ooooooo
Phogpborur |.rr8.287 o.00ooo00 I 0.0000000 o.oooooool o.ooooooof o.ooooooo
PotasrLum I ,t5. {91 o. o00oooo | 0.0000000 o,oooooooI o-oooooooI o.ooooooo
solenl.rur I 196. 090 o-0000000 | 0.0000000 o. ooooooo I o. ooooooo I o. ooooooo
gtlLeon lzsl.6Lz 0.00ooooo I o-ooo00oo o.oooooool o.oooooool o.ooooooo
stlLcon I zSr- 51s 0.0000000 [ 0.0000000 o.oooooooJ o. ooooooo I o. ooooooo
gi lver | 3rB. o6B o - 0000000 | o. oo0oo00 o.00oooool o.oooooool o.ooooo0o
Sodiun I ,r9 . 5ez 0.0000000 I o .0000000 o.0ooooool o. o00oooo I o.0000ooo
€odluru I ata .326 o.000oooo J 0.0000000 0.00000001 0.00000001 o.ooo00o0
pt,ronth:rn loOT .77L 0. 0000000 | 0.0000000 o - oooooool o. ooooooo I o. ooooooo
Thallirrm I f S0.864 0. 0000000 I 0.0000000 o. oooooool o. ooooooo I o. ooooooo
Comrentg:
STL DENVC
Fom XI tPmt 2)AIN
STL DENVER
Total Metals Analvsis
-ttB-
ICP INTERELEMENT CORRECTTON FACTORS (ANNUALLY)
Contract r IIRS Corroor:atlon
r,ab Codc: STITDEII
ICP ID !firmlrorr TilA
Cage !uo. :
Intrepid fCP
6lAS tilo. r
Datet 8l1g lz00s
gDC NO.: D5T020230
trhorlum I 283.730 o-0000000 I 0.0000000 00 I o. o00oooo
rln lrae .989 o. o0o0o00 I 0. oooooo0 o.ooooooof 0.0000000| o-ooooooo
rltanirrm I gg{.941 o.0000000 ! 0.0003150 o.oooooool o.oo0oo0ol 0.0000000
uraniurn I 38i.958 0.0oo0ooo I o. oooo000 0.0000000 ,oo0oo0oJ o-ooooooo
varradlum lzlz.4O2 0.0000000 I o-0002290 0.00000001 o.0o0ooooI o-ooooooo
zLnc I 2t3.8sG o. oooooo0 I o.0o00o0o 0-0009{l(l0l 0.0000000 1 0.0000000
Comments I
STL Denver
Form XI (PART 2l -IN
245
STL DENVER
SDc No.: D5I020230
Total Metals Analvsis
-lLB-
ICP INTER ELEMENT CORRECTION FA CTORS (ANNTIALLY)
Cage No.:SAS No.3
OI
Contract : URS CgrrporatLoft
Lab Code: gTLfrEN
Dator I /L9l?OOsrCP rD Numberr TifA Iutrepid Iep
.f,rral.frtc
Wave-
fength
(nm)Mo
rntorelenent Corrcction Eactorg
lUE Ni
for:
Pb sb
Z)'rvwt Lc-<^^ | "9 ' 198 0.0009000 J 0.0000000 o. ooooooof o.0000000 | o. ooooooo
ALrrminu$r Ifez-OB1 0.0ooo0o0 I 0.0000000 o . ooooooo I o. ooooooo I o. ooooooo
.f,1rrmLnrrm I30g.z7L o. oooooo0 I 0.0000000 o.oooooool o.oooooool 0.0000000
ffxtimony I eO6. B3B 0.0000000 I 0. o0oooo0 0.00000001 o-oo0oooo I o.oo00o0o
Arsanic J 189, o{2 0.0000000 | o.0oooooo 0.o00o0ool 0.0000000J o.ooooooo
Earl.rrm I 1S5.403 0.0000000 I o. oooo0o0 o. ooooooo[ o - ooooooo I o. ooooooo
Berrlllum I afs .Atz 0.0000000 | o,0o0oooo o. oooooool o. oooooo0 I o. o00o0o0
Boron I ,l9.62g o - 00ooooo I o. 0000006 o.oooooool o,oooooool o.ooooooo
cadmLum lr=6 - 502 o-0000000 I o.00ooooo -0. o00rrzo I o. 0000000 I 0.0000000
calcl,um IrrZ.933 0.0ooo0oo I 0.0000000 o. ooooooo J o. ooooooo I o. ooooooo
calcium IffB.12B o.0oo0o00 J o. 0000000 o.00oooool o. o0ooooo I o. ooo00oo
chronrium lZU. ?16 0.0000000 I 0-0000000 0.00000001 0.00000001 o.oo0oooo
cobalr l=rg,616 o-0000000 J 0.0000000 o-oooooool o.oooooool o.ooooooo
coppcr
J rza.753 o. ooo3400 I 0.0000000 o. o00oo00 I o. oooo0o0 | o. 0oooooo
rron
1
259,9{0 o.0000000 I 0.00ooooo o. ooooooo J 0.0000000 I 0.0000000
rron lrrl-{{1 o. Golsooo I o. ooooooo o. ooooooo[ o. ooooooo I o - ooooooo
r,ead lzzo.353 0.0000000 J o. ooooooo o - oooooool o. ooooooo I o. ooooooo
r.lthiurn lero.?Bd o. ooooo00 | o,0oo0ooo o.oo0o0o0l o.oooooool o.oo00o0o
ltagrnosium lzl9. o?9 -0.0359000 I o.0oooooo o. ooooooof o. ooooooo I o. ooooooo
Manganorc lzst,6i0 0.0000000 | o-0000000 0, oooooool o. oooooo0 | o. ooo0ooo
Molybdonum I 202.030 0.0000000 [ o-ooooooo o.ooo3{ooI o-o0o0o0oI 0.0o0o0oo
nLckcl I ,g t- .6at 12 0.0000000 | o. ooo0o00 0.0000000f o.0ooooo0 I o. ooooooo
phosphorus I,rg.287 0.00ooooo I o. oo0000o o.oooooool o.oooooool o.ooooooo
Porassium l 16o, {9L o - oo0o000 I 0. o0oo00o o. oooooool o. ooooooo l o - ooooooo
Selenium I tt6.090 0.0oooooo I o.0oo0ooo o.oooooool o.oooooool o.ooooooo
stlLeon lrr1-.6Lz 0.0093000 I 0.0000000 o. oooooool o. ooooooo I o - ooooooo
gtlLcon
I zSr.61i 0.0092000 I o. ooo0o0o o. ooooooo[ o. ooooooo I o - ooooooo
silver | 3r8. oG8 0.0000000 I o. o00o00o o. oooooool o. ooooooo f o . ooooooo
sodium I ug9.59a 0-0000000 I o.0000000 o. oooooool o. ooooooo I o. ooooooo
Sodlum Irrs.3rG 0.0000000 J o. oooooo0 0. oooooo0l 0. o0ooooo | 0.0000000
ftroutlrrm I oO7 ,z'tl:o.000ooo0 [ o.0ooo0oo o. ooooooo[ o. ooooooo I o. ooooooo
Thallium I 190.85{0.0000000 I 0.0000000 o. oooooool o. ooooooo I o. ooooooo
Fozm Xf (PART 2l
Comnrentg r
STL DeNVC
STL DENVER
Total Metals Analvsis
-ltB-
ICP INTERELEMENT CORRECTION FACTOR^S (ANNUALL9
Contract: I,RS Comorat:Lon
Lab Code: STITDEN Casg DIo. 3
fntrepld fCP Date: 8 l1.glz00s
Cournent,g:
gf,g No.:SDO NO. r D5IO20230
ICP rD ![tunber: TifA
Ttrorium I 283.730 0.0000000 | 0.0000000 0.00000001 0.0000000 I o. ooooooo
rLn I 189.989 o - oooooo0 | o. ooooo00 0 , oooooool 0.0o00ooo I o. ooooooo
ritanLum I 33{ .9{1 0. oo000oo I o. oo0ooo0 0, o0ooo00l -- o. ooo0ooo I 0.0000000
uranlrrm l 385.958 0.00oooo0 I 0.0000000 o.o0o000ol o.oo0ooool o-0000000
vanadlrrm lZS2. LAz -0. orz5o00 f - o. oo00oo0 o. oooo000f o. ooooooo I 0.0000000
zinc I zrs.855 o.0000000 I o-ooooooo o. oo{38001 o.0000000 I o, ooooooo
STL Denver
Form XI (Penf 2l IIN
47
STL DETVYER
rcP rD Numb€r: T.IA Intrepid ICp
Total Metals Analysis
-118-
ICP TNTEREIJ MEI{T CO RRECTIO N FACTORS (A NNUALLY)
Dat6: 8lI9 |'2OOS
contractr IIRS ForDo{Ftion,,, _ , _ ,,
rab Code s ST1TDEN Cara No.:SAg No. i gDc !iro.: D5IO2O230
wavc-
I-cngttr
(nml
rnterelement, Correctl"on ractorr for l
9r.nnalrte 8e si Sn rl.
T.1r.r.c.z-r. rrirn 1 "9 ' 198 0.0000000 | o. ooo00o0 o.000oooof o-oooo0o0! o-o0o0oo0
Alullltnum J r02.081 o.0oooo00 | o. ooo000o 0.00000001- 0.0000000 | 0.0000000
rlnmLnurn 1309 -ZTL 0.0000000 | o.00ooo00 o, 0000oooJ o.0000ooo I 0. o0oooo0
.rnrlmony l 20C, B3B o. oo00o0o J o. oo00ooo o-ooooo00[ o.000ooooI o-oooooo0
Arrenl,c I 189 .Oll2 o. 00ooooo [ 0,0000000 0. ooooooo[ o. ooooooo J o. oo00ooo
Bariuru 1455. {O3 0.0000000 ! o. o0000oo 0.00000001 o-0000000] -0.0001930
Berarllium ]f fS .Atz 0-0000000 I 0,0000000 o-0o00oool o-oooo000I o-0000000
Boron 1249.628 0.0000000 | o.000ooo0 o. o00ooool o. 0o00ooo I 0. oooo000
cadmLurn l22O. SO2 0.00o0ooo I o. ooo000o 0.oooo00ol o-ooo0o00l o.000oooo
calclrrm laf?.933 0.0000000 | o-0000000 o. ooooooo[ o. ooooooo I o. ooooooo
CalcLuur 1318.L28\0.0000000 I o.00o00oo o.0000000J 0.0000000 | 0.00ooooo
ptrronLum lzn. 216 0.0000000 I 0. oooo000 0. oooooool o. ooooooo I o. oo12ooo
cobalr 1228.6I.6 0. oo0000o I o. o000ooo 0-0000000[- 0,00000001 o'0018000
copper l3z{.753 0.0000000 | o. oo0oo00 o. ooooo00l 0. o0ooooo I o. oo0oooo
rron lrr9.9{0 o-o000ooo I 0.0000000 0-oooo0o0l o.oooo00ol o.000oooo
rroB 127 1. {{1 o.00oooo0 I o.0oooo00 o. ooooooof o. ooooooo I o. ooooooo
Load lzza. 3 s3 o. ooooooo I o.00oooo0 o.o00ooool o.000ooool o.ooooooo
r,ithlum I 5?0.28{o. o0000oo I o. ooo00o0 o.0ooooo0[ 0.0ooooo0| o-0000000
Irragnerium lz7 9.0?9 o. o0000oo I o.0o00ooo o. ooooooo[ o. ooooooo I o - ooooooo
I'tanganaso J ZSZ.51O 0. ooo0000 | o.00oooo0 o.oooooool o.oooooool o-ooooooo
[lolybdsfirm 12a2. 03 0 0. o000ooo I o. oo000o0 0. ooooo00[ o. ooooo00 | o. o00oooo
Nicket I ,s1.0 ot lz o. ooooooo I o. ooooooo 0.00000001 --0-0000000I 0-0000000
Ptrosphonrr Ifrg.287 0.0000000 | 0.0000000 0.00000001 0.oooooool o*o00oooo
Poraaslum 1 765. d9L 0 .0000000 | o.00oo00o 0.00000001- 0.0000000f 0.0000000
selenlun 1 fg5,090 o, oo00ooo I o.0oooooo o. oooooool o. ooooooo I o - ooooooo
stlicon I 251.612 0.0000000 | o.0oo00o0 0.00000001 - 0.ooo0000| o-0000000
siLLcon I zsl. G15 o, ooooooo I o. ooooooo o. ooooooof o. ooooooo I o. ooooooo
Sllver Jaze. oe a 0,00000001 -o.ooooo0o o.ooooooo[ o. ooooooo I o. ooo35{o
sodlum I 589.592 0.0000000 | o. o0ooo00 o. oooooool - 0.0000000 | 0.0000000
sodlurn
J tr8.325 0.0000000 | o. oo0o00o o. oooo0o0l o. ooooo0o I o. ooo0000
[.rontlun I oo7 -77L 0 .0000000 I o.000ooo0 o.0ooooool o.oooooool o.ooooooo
rhalllum I rg0.86a 0.0000000 I 0.0000000 0, o0oooo0l o.0ooooo0 | o. oooo0oo
Comments:
STL Denve
Eonn XI (PART 2 )IN
248
STL DENVER
Totel Metals Analvsis
-1lB-
rcP TNTERELEMENT CORRECTTON FACTOR^S (ANNUALLY)
contract: IIRS CorooratLon
Lab Code 3 STITDEN Cage No.:
Intrepid ICPrCP ID lhrmber: TifA Dat6: I lAg lzAOs
Corunentg:
gl'g Dlo. 3 sDc NO. r D5TA20230
lrhorium
J 283 -730 0.0000000 I 0.0000000 0.00000001 0.0000000 I o. ooooooo
tr.Ln I ra9.9o9 o.0000000 I 0.0000000 o.000ooool o.oo0o0ool o.0o000oo
rl-tanLrun I 33c.9{1 o. ooo0000 | o. 000oo0o o.0o00o0ol 0.0000000 I o. ooooooo
uraniurn IfA5.9sB 0.0000000 [ 0.0000000 0.oooooool o.oooooool o.oo00o0o
vanad,l.um lZlz. taz 0.0000000 I o.00o00oo o.00o0oool o.ooooooo I 0.000{100
zinc I are. g55 0.0oooo00 I o.0000ooo o.00oooool o, ooooooo l o. oo00o0o
STL Denver
Form XI (P.ilRT 2l rN
STL DEIVVER
Total Metals Analvsis
-il8-
tc p FTTERELEMENT CO RRECTION FA CTORS (ANN UALTY)
Contraet r IIRS Coroorat,ion
rab Codc: S1ry,DEN
ICP rD Nurnber: TifA
Case No.:
Intrepid ICP
Sfg fiIO. 3
Dato: I llg lzAAs
SDc lIO. r D5I024230
Wawe-
lengttr
( run)
rtlterelement correctlon Factorg for r
Zttlnalrt,e T1 U v Th
Li*o-r-) ,u-r?1 I rag ' 198 0.0000000 | o. oo000o0 0. ooo000ol o,000oooo l 0.0319000
.rlurnLnum I rez.0B1 o. 0000ooo | 0.0000000 o-00000001 o-oooooooI 0.0000000
Aluminum I 3O9 .27L o-0000000 | 0.0000000 o. ooo000of o - ooooooo J o. ooooooo
rnrinony I 206.938 0.0000000 | o.0o0oo0o o. oooooool o. ooooooo I o. o00oooo
ArrcnLc I tgg .Od,z 0.0000000 | o-0000000 o-ooo00ool o.oooooooI o-000oooo
Barlum I lrs. {03 0.0000000 J 0.0000000 0.0ooooool o. ooooooo I o. ooo3o3o
Bery11lum ]f ff .A$z 0.0000000 | 0.0000000 0.00035901 0.0000000 I -0.0000100
Boron 1249.6?8 0.0000000 I o. ooo0000 o.0000000I 0-00oooooI 0.000oooo
ca&rrLr:ru 1116. S0Z 0.0ooooo0 I -0. 0oo3o70 0.oooo0o0l 0.0000000 1 0.0000000
calcLum I 33-7.933 0.0000000 I o.0000000 o. ooooCIoo I o. ooooooo I o. ooooooo
aCalclum IgtB.128 o-0000000 I o.0000000 o.0000000 I o. ooooooo I o.0559ooo
ptrrontrrrn lzsl .7 LG o.o000ooo I o-0007060 0.o000ooof o.0o0oo0ol -0.000597a
cobalr 1228 - 516 0.0000000 I 0. oo0oooo o.ooooo0ol o-oooooooI o.ooooooo
copper I r, | .7 s3 0.0000000 ! 0.0008{20 0. ooooooo[ o. ooooooo I o. oo232o0
rron I ,s9.9co o. oo0000o I o. o0ooo0o o. oooooool o. ooooooo I o. ooooooo
rron lzll. {{1 o.00ooooo I o. ooo00o0 o. oooooool o. ooooooo I o - ooooooo
Lead 1220 -353 0.0oooo00 ! o. oooo0o0 o.ooo0o00l o.0ooooool o.0000ooo
rlthtnm I e,o. zB{0.0000000 I 0.0000000 o.ooooo00f o.ooo00oof o.o0o0o0o
lrlagrnesJ.um |,27 9.0?9 0,0oooo00 | o.oo7560o 0.0000000! 0.0000000 I -o ' 0{18000
Mangraness lzsl.610 0.0000000 | o. oo01220 -0.00016801 0,0000000 1 0.0000000
Molybd,cnum IZOZ. 03 0 0.0000000 I -0.000?050 o. o0oooo0l o. ooooooo I o. oo175oo
NLcket l rf l. G ot t z 0.0000000 I o.00o0ooo o.ooooooo| o-oooooooI o.ooooooo
phoephorua I 1z g.ZB7 0.0000000 I 0.0oooo00 o - 0000ooo[- 0.0000000 I o. 0000000
PotassLrrn 17 66 . 491 o. ooooooo I o. ooooooo o. ooooooo I o. ooooooo I o. ooooooo
Selenl.um I tg5. oio 0.0oooo00 I o.0000ooo o. ooooooo[ o - ooooooo I o. ooooooo
slllcon I 251.612 0. 000oooo I o.0o0oooo o. oooooool o. ooooooo I o. ooooooo
stlicon I ,t1.5t5 o. ooooooo I o. ooooooo o. oooooool o. ooooooo I o. ooooooo
sirver I SzA.oGB o.0ooooo0 I -oloo22oo -0 .01{90001 0 .0000000 [ 0.0005880
sodtum I urg.5g2 o,o000o0o I o.00ooooo o. oooooool o. oo000oo I o - oooo000
sodlum I ara.326\0. o000ooo ! 0.0000000 o . oooooool o. ooooooo I o. ooooooo
)u,rontlum I ao7 .77L 0.00ooooo I o. ooooo00 o. oooooool o. ooooooo I o. ooooooo
Thallt-um l rg0, g5{0.0000000 I 0.0000000 o. oooooool o. ooooooo I o. ooooooo
Corunentg:
STL Denvef
Form XI (PART 2)-IN
STL DENYER
Total Metals Analvsis
-1lB-
ICP INTERELEMENT CORR.ECTION FACTORS (ANNUALLY)
coBtract: lrRS eorooratloa
Lab Codc: STLDEN Care No. t
Intrepid ICP Datc: 8 lL9l2AO5
Couunonts:
grg No. l sDc No.: D5I02O23O
fCP ID Number r Tifl'
Thorlum I 283. ?30 0.0000000 I 0.0155000 0.00000001 0, 0000000 1 o. ooooooo
TLn I 189.989 o. ooooo00 I 0.0000000 o - oooooool 0,000oooo l o. ooooooo
Tl.tanLum I aS{.9t1 0.0000000 I 0.0002850 o.oooooool o-oooooooI 0.0o0oooo
uranl,uru I ggs
" 988 0. ooo0o00 | o.0o0o0oo 0.00000001 0.0000000 I -0.0287 000
vanad,iurn lZlz .4Az 0-0000000 I -0.00021120 0.00oooool 0.0000000 I o. ools6oo
zt nc I erf. 856 o.0000ooo I 0.0000000 0.00000001 0.00000001 o.oo00ooo
STL Denver
Porm xI (PIRT 2l .IN
257
STL DENVER
Contract: IIRS Comoration
Total Metals Analvsis
-ltA-
ICP INTERELEMENT C ORRECTION FACTORS (ANNUALLY)
Cage No.:
rI
gfS No. l
Date : 8 1112005
Lab Code: SI1,I,1)EN
rcP ID ll\rrnbcr: SUPERI:R"trCE
Dsr0202 3 0
Wawc-
Langth
(nn)
Interelenent CorrectLon f,actorg for:
Itlgr
Analfrte IgA1Caf'e
llurntnutrl I 308.215 0.000oooo I o.0o0oo00 o.oooooooJ o-oooo59oI o.o0ooooo
Antl.mony I 206. 83L lL 0. ooooo00 I 0.0000000 0.0000140 J o. o0ooo00 I o. ooooooo
rnul,mony I 206 . 83 Llz 0.0o0000o I o. o00oo00 o. oo0024o I 0. 0000ooo I o. ooooooo
rrsenLc lfgg.a42 0.0000000 | o. o0oo00o 0. oooooool o. 0000000 I o. ooooooo
Barirrm I{93.{09 0.0000000 I 0.0000000 o.0o00o0ol o. oooooo0 I 0.0000000
sarlrllLurn I af a.0{2 0. ooooo00 J o.000oooo 0. 0000000 I 0. 000oooo I o. 0000000
Boron ,219.6?8 0.0000000 | o.000oooo 0. 0000ooo I 0.0000000 I 0. ooooooo
Cadmlum |,225. s02 0.0000000 I 0.0000000 o. 0001210 I 0. 0000ooo I 0.0000000
calcium I arz.933 0.0000000 I o. o00oo0o -o,00020001 0.0000000 I 0.0000000
chromium lZeZ .77-6 o.ooo0000 | o-0000000 -0-0oo01o0l 0.00000,i0J 0,0000000
\cobalr 1228 - 616 0. oo0o00o | -0.0011320 o - ooooooo I o. ooooooo I o. ooooooo
Tcopper Isza .7sl 0.0000000 I 0.0000000 o - ooo0o50l o.0o0ooo0 I 0.00ooooo
rron 127 1. {{1 o - 0000000 I o. ooooooo o.o0oooool 0,00000001 o.ooooooo
rcad lzzo.3 sLlL 0.0003820 I o.0oooooo o.00011601 o. ooooogo I 0.0000000
r.ead 1220 - 3 5L/ 2 -0.0002590 I o. oo0o000 o. oooo6l0f 0.0000100 1 0,0oooooo
ttagrnegl,um lZr g.078 o-00000001 0.0000000 -0.00010801 0.0000000 [ 0.0000000
Manganera lzsl.510 0.0000000 [ o.0o0ooo0 0.0000020 1 o. oooot? o l o. ooo0o0o
Molybdemrm I 202. O3o o.0000000 I o.0oooooo -0.oo0o20ol 0.0000000 1 0.0000000
Nicker I ,r 1. 6 or t,0.0000000 | o.0000000 o. oooooool o. ooooooo I o. ooooooo
selenlum Iffe.02L/t 0-o0ooo00| o.0oo0ooo -0.00002501 0-00000001 0,0000000
Selenium I fg6.0zLlz 0.00ooooo J o.0oo000o -0.00020301 0.0000000 I 0.0000000
stll.con I ,tB. 1s8 0,0000000 | o. 0000000 o. oooooool o. ooooooo I o. ooooooo
silvsr 1328.058 o-0000000 I o.0000000 o.oooooool o-0000000I 0.000oooo
gtrontium I or1. s52 0.0000000 | 0.0000000 o, oooooool o. oooo0oo I o. ooooooo
rhrilllum I tgo.86{o:0000000 I 0. o0o0ooo -0. ooooraol 0 - 0000000 I 0. 0000000
rfhorLum lOO1.91O 0.0000000 | 0.0000500 o. oooooool o - ooooooo I o. ooooooo
rtn I ts9.9a9 0.0000000 I 0.0000000 o. o0ooo0ol o.0oooooo I o. ooo0000
ritanium I 33{.9{1 o. 0000000 I o. 0000000 0. oooooool o. ooooo0o J o. o000ooo
uranLusr I 009.01{0.0000000 I o.0002200 o. ooolaool o. ooooooo I o. ooooooo
vanadlum 1292.tLOz o.0000ooo I o. oo0oo00 -0.00029101 -0.0000060 I 0.0000000
flnc I zrs. 856 0.000oooo I 0,0000000 o. ooolosol 0.0000070 | 0.0000000
Form xI (PART 1)-IN
CoumenLs:
STL Denve
STL DENYER
Total Metals Analvsis
-1lB-
ICP INTERELEMENT CORRECTION TACTORS (ANNUALLY)
coatract: g3s-sq1pgXtrtion _
Iab code: STLDEN Cage No. r
II
gAS hIO. r
ICP rD Numbort SITPERI|RACE Deto: 81L12005
6DCt !rO.: D5fO20230
Anallt e
Wave-
tangth
(nm)
Interelarnent Correctlon Factorg for:
BBaBe CdAg
rlumlnum I308-21s o.0000ooo I 0.00o0ooo o. o000oool o. ooooo00 | o - o00oooo
lrrt{.monrr I ,06.8lLlL 0. oooo00o I o. o0000oo o. o000ooof o.0000ooo I 0. oooooo0
Anrimony I zo6. g3 Lt2 0.0000000 [ o.00o00oo 0.0o0ooo0l o. o0ooo00 I o.0000000
Argenlc I 1Bg -o4z o. o000oo0 I 0.0000000 o.000oooof o-0000000I 0.0oooooo
Bariun I{93.{09 0. ooo000o I o.00ooo00 o.00oooo0[ o.ooooo00| o-0000000
Ber^yl1ium I aff .A42 o - 0000000 J o. ooo00oo 0 - ooo0000l o. o0o000o I 0. ooooooo
Boron 1249 - Gzg 0.0000000 I o. o00o00o 0.00000001 0.oooooo0l o.0000ooo
cadmtum 1116.50z o.o000oooI o-0000000 o. ooo000ol o.0000ooo I o. oooo000
Cal.cl,rrsr ! Sfz.933 o . o0ooooo !, . -- .--,o, oenoooo o - o0o000ol o. o0000oo I o. oooooo0
Ctrronl,um lZ67 -7LG o. ooooo00 I 0. oooo0oo 0, oooo00ol 0. oooooo0 I o.000oooo
Cobalt, lrr8 - 616 0.0000000 I 0.0000000 o - 0o00oool 0.00ooooo I -0, ooo5oq
cop1>er I tr4 .7 5-o.oo00oo0 [ o-0000000 0.ooooo00l o.ooo00ool 0.ooooooo
rron lrr1. c{l o. o000ooo I o,00oooo0 o.000ooool o.0000000 | 0.0oooooo
r,ead lrro.3sitt 0.0000000 | o-0000000 o.00oo0o0l 0-o0o0oool o.ooooooo
r,oad lr^0.3 5Ll2 0.oo000oo I o-0000000 0.0ooo0oo[ o-oooo0ooI o.00ooooo
MagrrrGsLrun ler g. o?B 0. 0000000 I 0.0000000 o-oooooool o.ooooooof o-ooooooo
Mangranos6 IZSZ. 510 o. o00oooo I o. oooooo0 0.0ooooool o. ooooooo I o. ooo00oo
Molybd,onrlrn IZOZ.03O 0. ooo000o I o.000ooo0 o. oooooool o. ooooooo l o, ooooooo
ulclrel I ,r L.6Ot lz o.0ooooo0 [ o. o0oooo0 o-o0ooooof o.ooooo00I o-oo00ooo
solenLum Itt6.OZL|I:o. oo0000o I o,00036?0 o.0000oool o.000ooooI 0-0ooooo0
sclenLun I 196.02 Lt2 0.0000000 I -0,0002{90 o.oooooool o.oooooool o.ooooooo
slllcon ! et8. lse 0.0000000 | o. o000ooo 0.oooooool o.0ooo0ool o-ooooooo
silver I gz8.068 0.0000000 [ o. o000ooo o. oooooool o - ooooooo l o. ooooooo
StrontLuur I Or1- 552 o.000ooo0 | o-0000000 0. oooo0o0l 0. oooo000 I 0.0000000
ThallLum I tro. g64 0.0000000 | 0.0000000 0. ooooooof o.00o0ooo I 0.0oooooo
Thorl,um IoO1.91o 0.0000000 J o.0000000 o. oooooool o. ooooooo I o. ooooooo
rl.n I rag.989 o, ooooooo I o. ooooooo o. oooooool o - ooooooo I o. ooooooo
Tltanlum
J
33{. r{1 0.0000000 | o.oooo000 0.0000000[ o. o000ooo I 0. oooo000
Uranium I oo9 .01{o.o0ooo00 I 0.0000000 o.000oooo[ 0.0000000 I o.00ooo0o
vanadlum l29Z.{O2 0.0000000 | o. oooo00o 0 .00000001 0 .0000000 | o. 00000001
zinc |zrs.gs6 0.0000000 | o,0oooo00 0.00oooo0l o.oooo000l o,000oooo
Corunentg:
STL Denve
Form XI (PART 2l IN
253
STL DENVER
Contraet; IIRS Corrcoration
'fotal Metals Analvsis
-IIB-
T CP INTERELE M ENT C ORRECT I O N FACTORS (ANN TIA LLY)
Cage No. :
IT
grS No. :
Datss: 81L12005
f,ab Code: STITDEN
ICP ID Nurnber: St PERIIR.I,CE
sDC No.: D5TA20230
Lnalyt,O
$Iave-
lengrth
(mt)Co
rntrerelament CorrectLon Factorg
Cr Cu
for r
lIn Mo
rh:mLnum 1308.?15 0.0000000 I o. ooooo00 0.0ooooool 0.0000000 | o. oo{0830
tntimony I ,o6.83LtL 0.0000000 ! o. oo83og0 0.00000001 o. o0ooooo I -o,0006500
Antimony 1206.83L12 0.0000000 I o.ood377o 0. o000o0ol 0.0000000 I -o - 0033500
rrsenie ll8g-o{2 0 . 0000000 J -o . oo{173 00 o. o00oo00l o. ooo0o00 I -0 - 0 o?42oo
Barium I lSa.409 0.0000000 I o. oooo0o0 o.oooooool o,o0000ool o.ooooooo
Berlrllturn Iars .ol!2 0-0000000 | o-0oooooo o. oooooool o.0o0oooo I o. oooooo0
Boron lztg.678 0.0013sso I o. ooo0000 o.o0oo0oo! o.oooooool o.ooo000o
cadmLum 1116 - s02 -0.0002200 I o. oo000o0 o. o00o00ol o.0oooooo I o.00ooooo
calcLum I rrz.933 o. o0000oo I 0.0000000 0. o00ooool o. oooo0o0 | o . ooooooo
Chromlurn lzil. z16 0.0000000 I 0,0000000 o. ooooooo ] o. ooooooo I o. ooooooo
Cobalt 1228.616 0.0000000 | o. oo00o00 o. 0000000 I 0. 0oooooo | 0 .000oooo
co1>por I ree-?53 0.00oooo0 I 0.00oooo0 o. oooooo0 ! 0.0000000 J o.0004910
rron lzr1. {{1 0.08027 80 I 0.0038290 o.ooooooof o-oooooool 0.0oooooo
r,ead 1210.3 sl.l L -0.0028{00 J o-0000000 o,0000000| o-0000000I -0.0008s80
r,ead lzzo .3 st.lz 0. ooo0000 | o. ooo0000 0.00000001 o. 0000000 I -o.0002710
r*ragrnasiurn lz7g-0zB 0.0000000 I 0.0000000 o. 0oooooo I o. ooooooo I 0.0000000
Icancranese lZSl. 510 0. oooo000 I o. ooooo00 o. ooooo00 l 0.0000000 1 o. oo0o000
Molybdenum
1
r02.030 0.0000000 | o.00o00oo 0 , 0ooooo0 | o. 0000000 | o. ooooo0o
xLckel I re1.50 4/2 -0. o00ezso J 0. oo00oo0 o. ooooooof o. ooooooo I 0.0o0oooo
selenLurn l1.g6.ozI-tL 0. 0005500 I 0.0000000 o. oooo000l 0.0003610 | o. 0005620
selenlum I 196. OZLIz 0. oo00oo0 | o.000o0oo 0.0000000 | o. 0003o20 I -0. 0002370
silLcon I ,48.158 0.0000000 I 0.0o0oooo 0 . 0000000 I o. 0000000 I -0. 0056 zao
sllver I arg.068 0.0000000 | o. 00oo0oo 0 - 00000001 o.0000000 I -0.0003 190
strontlurn 1421. s52 0.0000000 I o.0000000 o. oo0ooool o. ooooooo I o. o0ooooo
Thalllum I tgo. 864 0-oa2g6g0 | o.oo032oo 0.00000001 -0.0024130 I 0.0000000
rhorlum I oo1.91o 0.0000{t9o I 0.0000000 o. ooooooof o. ooo0ooo I o. ooooo0o
rln I rre. gSg 0. o0000oo I 0.0000000 o. ooooooof o. ooooooo I o. 0ooo0oo
riranium I ,r{.9{1 0.0000000 I 0.0000000 o. oooo000[ o. ooo0ooo I 0. o0ooooo
uranLum l aOg. old 0.0000000 I 0.0000000 0.00000001 o.0000ooo I o. ooooooo
varradlum I ,g 2.402\0. o00o0oo l -0,0010200 o, oooooool o. ooooooo I o. ooooooo
/rnc Izra,856 0.0000?50 I 0.0000000 o. ooozSooJ o .000o0oo l o. ooooooo
Comnents:
STL DCNVC
Form XI (PART 2l -IN
254
STL DENVER
Total Metals Analvsis
-il8-
ICP INTERELEM ENT CORR.ECTION FACTOR^S (ANNUALLY)
coEtsract: UBILSCfgECEion _
Lab Code: STLDEN Cage No.:SAS fitro. t
ICP rD ltunber: SUPERTH.LCE II Dato: I l4l2005
D5r02 023 0
Analtte
Wave-
lcngrth
(rm)Hi
Intorelement Correetlon traetorg forr
Pb Sb Se st
Alumlrrrrn I 308 .215 o.0oo000o I o.oooooo0 o. oooooo0l o - oo00ooo I 0. ooo000o
Anrl"mony I 206.83 Lt]:-0-0006200 | o.00oooo0 o.0oooo00l o. oooo0oo I o.0ooo00o
^trntimony I 206 - 83 L12 0.0000000 | o. o0oo00o o. oooo0ool o. oo0oooo I o. ooo0ooo
Arsenic I tAg -O{z 0,0000000 1 0.0000000 0-0000000| 0.0000000I o-oo00ooo
BarLurr Ilg3-{09 0.oo000o0 I o-o000oo0 o. ooooo00l 0. ooo00oo I o.0oooooo
Beryl1l"um f f fs.o{,2 o.0oo000o I o. oo000oo 0.0oo0oool o. ooooooo I o. o00oooo
Boron |,249.6?8 o.0oo00oo I o. o00oo00 0.00000001 o.000ooooI o-0001290
Cadmirrur lzZe.502 o.00oo00o I o.00ooo0o o.0ooo0oo I o. oo0ooo0 I 0. ooo0ooo
Calcl"um I afz.933 o.0oo000o I o.00oo00o o. oooooool o. ooooooo I o. ooo0ooo
chromlrrm lZSl .lLG 0. 0000000 | 0.0000000 o.o0oo0ool o-oooooooI o-o0oooor.
cobalr 1228.516 o.0oo19oo I O. oo000o0 o - oooo0ool o. ooooooo I o. oo0ooo!
copper I fal -7s3 0. o00oo00 | o.00ooo00 0.0000000f o. oo000oo I 0. 0oo00oo
rron lzt 1. {{1 o.0o000oo I o. o00oo0o o-oooooool o.oooooooI o-ooooooo
Lead 1220 . 3 sr.t L 0.0005000 | 0.0000000 -0.0001{5ol 0,0000000 1 -0.0001300
r.ead lrro,3sLlz 0.0000000 I 0.0000000 -a.00015001 0-0000000 I 0.0000000
lragnesLu$r l.27 9.078 0.0000000 | o-0000000 o.00ooo00I o-o00oooo| 0.ooo0ooo
!'rangra,,cse l,2s7.610 0. oo000o0 I 0.0000000 o.oooooooI o.oooooooI o-ooooooo
Molybd,enum IZAZ. O30 o. o0ooo0o I o. o00oo00 o. o000oo0[ o. o0oo000 | 0.0000000
ulckel I 23L.50 4t2 0.0000000 | o.0o0o0oo o. ooooooof o. ooooooo I o. ooooooo
selenLum I rg6.02LtL 0 .0000000 I 0. 0000200 o .00o0oool o. oooo00o I o. oooo52o
sclenlum I rt 6.ozt-lz 0.0000000 I -0.0000100 o - oo0oo0ol 0. oooo000 | 0.0000650
silLcon I ,eB.158 0. oo00oo0 | o. oooo00o o. oooooool o - ooooooo I o. ooooooo
silwcr I 32B. oGB o.0o000oo I 0.0000000 0.0000000r
-o,oooo0oo I o'0000000
strontium laz1. s52 0.0000000 I 0.0000000 o-0000000I 0.0ooo00oI o-o00oooo
t.hallLrrm I tgO. 86{o.0000000 | 0.0000000 o - ooooooof o. ooooooo I o. ooooooo
TtrorLum IoO1.91o o. oo00oo0 | o,0o000oo o. oooooool o. ooooooo I o. ooooooo
rin I ree.9g9 0.0000000 | o.0ooooo0 0. o0o0oool o. ooooooo J 0.0000000
rlrantun I lg 4.gll 0.00ooooo I 0.0000000 0.0000000f o. oooo0oo
uranLum I 009.010 0.0000000 | o.0oooo00 o - oooooool o. ooooooo I o. ooooooo
vanadlum lzsz.toz o. oo00o00 [ o. oo00o00 o,0000000f 0.0000000 I o. ooooooo
zinc I zrs.856 0.0034900 [ o.000ooo0 o,ooooooo[ o.oooooool o.ooooooo
ConunenLs:
STL Denver
Forrn xI (PABT 2l -rN
255
STL DENVER
Contraet r IIRS Corooration
Total lVletals Analvsis
-llB-
ICP INTERELE M ENT C ORRECTTON FACTORS (A IYNTIA LLY)
Carc No.3
rI
. gAA No.:
Dat6: 8l Ll20O5
LEb Coder S1LDEN
rCP ID lhrmber: SITPER'I]R-},CE
gDc NO-: D5f020230
WEv6-
lengrth
(utt)
fntarelcurent Corectlon ractorg for:
U
e,naltrte vSnSrr1
rlurnLnum J f OB,215 0.0000000 I 0.0000000 o.oooooool o-oooooo0| o.0239{oo
Antl.mony I 206. 931/ 1 -0.0029000 J o.00oo00o 0.00000001 *o - 0005200 I -0.0089100
}'nrinoay I 205.83 Lt2 0. o0o0o0o I 0.0000000 0.00000001 -0.0003(100 I 0.0000000
Arranic I 189 .OtLz 0.oo0oooo I o-0000000 o. oooooool o. ooooooo I o. ooo0ooo
Barium I {93. {09 0. oo0oooo I 0.0000000 o, oooooool o. ooooo0o I o. ooooooo
BeryIlturn ISf3.0{2 0.0000000 [ o.0000ooo o.oo0o0ool o.ooooS6ol o.ooo129o
Boron 1|219.678 0.0000000 J o.0oooooo 0.00000001 o.oooooool o.ooooooo
cadnI.um lrr5.502 0.0000000 | o. ooooooo o.000ooool 0.00000001 0.ooooooo
calclrrm I arz.933 0. oooo000 I 0. o00oo00 o. oooooool o. ooooooo l o . ooooooo
Chromlum lZm.TL6 0.0oooooo I o.00ooooo o. o0oo000l o - ooo32oo I o. ooooooo
coba1r. 11228.615 o. ooooo00 [ 0.0000000 o. oooo000! o. ooo11oo I 0.0000000
coDDer Ilzl-?53 o. 0000000 | o.00o0oo0 0.00000001 -0.0008900 | 0.0000000
rron ll27 1. {41 o. o000ooo I 0.0000000 0.00000001 -0-05756001 0-0119000
Laad lr220.3 51/1 0.0000000 [ o.00008so o, oooooool o. ooogooo I o. ooooooo
r,ead lrzo.3 SL|Z 0.0000000 J o-0000000 0 - 00000001 o.0015000 I -0.0004{s0
Ma€rneel.um lZ7 9.0T8 0.0000000 t- 0.0oo0oo0 0,00000001 -0.0133900! o'0000000
lilangunera |zsl. 610 o.0000oooI o-ooo0oo0 o. o0ooooo J 0.0001700 | o. ooooooo
nolybd,enrrn lzOZ.03o 0.ooooo00 I 0.0000000 o. ooo0000l -o - ooo3?oo I o. oo0000o
ulckel 1231-6oifz 0.0000000 I 0.0000000 -0.00098001 0.0000000 1 0,0000000
Ecleaiurn I 19 6.O?L|L 0.0000000 [ 0.0008130 o. oooooool o, ooooooo l o. oo0322o
sclenLr:m Itg6.0ZLl2 o. 0000000 I -0 - 0005130 0.00000001 -0.00008001 0.0000000
stlLcon I ,gB.1sB o.0190000 I o. oooo0oo o. oooooool o. ooooooo I o. ooooooo
s1lver l32B. 068 o-0000000I o-ooooo00 0.0000000[ o.0012900 I o. ooooooo
Stronrlum lor1.5S2 0.0000000 I 0,0000000 o. ooo0o00l o. ooooooo J 0.0000000
Thalllum I tgo. g64 0-0000000 ] o.0000ooo o. oo0ooool o. ooooooo I o - oo188oo
Ttrorlum Id01.gl0 0.0000000 I o. o0o0ooo 0.000ooool -0.0069600 I 0.0000000
rin I tg9.9e9 o. ooooo0o I o.0o00oo0 o. oooooool -0.0006700 | 0.0000000
ritanlum I 33{.9{1 o. oooo000 | o. o0oooo0 o. oooooo0l 0, o00oooo f o. ooooooo
uranium I AO9.01d o.0000ooo I -0.0260000 o,ooooooof o.oooooool o,ooo0000
vanadLusr lZlz.l}z 0.0000000 I 0.0000000 0.oooo000l -0.0002800 I 0,0000000
linc lrii.8s6 0.0o00ooo I 0.0000000 o. oooooool o.000oooo I o. ooooooo
Form, XI (PART 2l -IN
Cornmenta:
STL DENVC
STL DENVER
Total Metals Analvsis
-rm-
ICP NITERELEMET{T CORRECTION FACTORS (ANNUAITY)
coatract! Irng Coroiorat:fon
Lab Codc: S1lLDtrN Cage No. :
II
gAg No. :
Datc: I lll 2005
Cormnentg:
SDGI NO. : D5TO20230
ICP ID t{urnber: $UPERERACE
Wava-
leagrth'
( nrn)
Interelsnant Corectrlon tractort
Ttr
tort
e,.nalyte Ztt
llunrtnrrm I 3o8.21I o.o000ooo I o.o5o2L7O
ArrrLmony I eO6 . 83 Lt L 0-0000000 I -0.000oltoo
AnrLmony I eo6. g3 Llz 0.0000000 | o. ooo0000
ArgenLe I reS-042 o.00oooo0 | o. ooo0ooo
BarLurn l{93.{09 0.0000000 | o. oo01g0o
Berry'llLum I 313 .a{,z o. oo0000o I o.0oooo00
Boron lrog -G7B o.000oooo I o.000oooo
cadrntr:rn 1226. 5oz 0.0000000 I o-oo005oo T
calcl-urn lf rz. 933 0.0000000I -o-oo5550o
Clrrornlum lZW. T16 0.0000000 [ 0.0000000
cobalr lrr8 - 616 0.00ooooo I o. ooooooo
Co12por llza. zs3 0.0000000f o-0026{00
rron lrr 1.8{1 o - 0000000 I -0. 1145000
r.ead 1220 . 3 5L lL 0.0000000 I -0.0030000 t
Lead lt220.3 5Lt2 0.0000000 | o. o0o0ooo
MagncsLum lzr9. oz8 0.0000000 | 0.0000000
llaaganoso |zsl - 610 o-0000000 I -0.000{100
Mor.ybdenutrl Iro2-03o o. o0000oo I o. oooooo0
ul,ckeL l 231. 5 04 t2 o, oo0000o I o. oo00oo0
selenLum Itg6.ozt.lL 0.0000000 I -0.0290s00
selenLrrn l196.0.ALtz 0.0000000 I -0.0002{00
stllcon I 299.158 0.0000000 I o_0000000
silver I f28.068 0.0000000 I o.0002800
Stroatiurn l{21. 552 0. oo0000o I 0.0000000
rhrrlll.rrm I tr0. SOd 0.0oooo00 J o. oooo000
rhorl,rrm I oO1.91o o.0000ooo J o_0000000
rln I re9.9g9 0. ooooo00 J o. o000ooo -I
titanium J33ffd1 o. ooooooo | 0.0000000
uranium I aog. o14 0.0000000 | o .oazgsoo
vanadium l agz.t}z 0. oo00ooo | 0.0011500 I
Zinc Izm.BE6 0.00000001 o.o0ooooo \
STL Denver
Form xI (PART 2l IN
STL DEAIVER
o
Con
Lib
tnct: IIRS Cor+>ontLon
Total Metals Analvsis
ICP LINU,AR RANGES (QUNRTERLY)
SAS No.:
Drrtc: I lLS lz00s
SfI.DESI sDo No. : D5I020230
rCP TD T.Il, Intrcptd fCP
Anal.yte
Intcg.
rLme
( Sec. ;
Concentration
mgr lL M
ln'I-*Lnum ro I 50.00 lr
lrluninurn Et I 20. o0 1000 lp
lCalciurn r,o 20.00 50 lr
lCafcLum Irt 20 .00 2000 tP
I fron Lo 20.00 Ip
I rroa Ht lrt-2000
I noteggLum 20. 00
Ma.gmerium
500 lr
l SodLun Lcl 20.00 10 ln
f sodium Ht 20.00
ZLrooniunt
10000
50
Jr
!,,o,.nta,
STL Denver Fora XII IN
258
STL DENVER
Total Metals Analvsis
-12-
ICP LINEAR RANGES (QUARTERTY}
Contract:
Lrb Codet Caae No.:
ICP ID ![Umbsr r SUPERTRACE II
IIRS CorDoretion
SAg lilo
Date:8l3l?AAs
sDc No.; D5I020230
Arralyto
Itlteg.
Tlne
(Scc - )
Concontration
(ng/L)
M
l eracnLo 15.O0
lsarJ.um
J Lcad.
I N{ckrll
l st lwer Jr
Ivanadl,um 15.00
fztnc 15.00 Jn
Cornruent a r
STL Denver Foru XfI IN 259
STL DENVER
o
Con
Irab
IEP
Eraet: IIRS Corporrtiou
Total Metals Analvsis
-12'
ICP LINEAR RANGES (QUARTERLIO
gAS No. :
Datc:8lL9 12005
Codct STLDEN
ID Nunbcr: pE fCm[S
Case No. t gDs NO.: D5f020230
f,nalyte
Irrtcgr.
Tirrrr
(8ec. )
Conccnt,ration
(mg /r'l
M
O
ruUUSffE, f :
STL Denver Form XII IIt[
260
STL DETVYER
Totrl Mctals Analvsis
I.3-
PREPARATIONLOG
Contracts:
Lrb Code:
Methodr P
URg Corporetion
gTLDEN Cagc No. t S.trS No. t
Prorr Mcthod:
D5r020230
g+?,rIEDlc fD PrGparation Dr,t,c
InLulal Vol.rrnrc I rlnrl.
I vol,unc (mr,)
surB-910 - 09010 5 9 tlsl200s 50.0 I 50.0
gr{B- 9 - 09 010 5 91L512005 50.0 I s0. o
suIB-10 - 09 0105 9 tL5l2AA5 50.0 I 50.0
s$rB-10-090105 MS e lL5l200s 50.0 I 50.0
shrB- 10 - 09010 5 MsD 9/15 12005 50.0 I 50.0
swB-3-09010s 9 tts t20a5 50. o I so.o
shrB-7 -09 0105 9 lls/2005 50. o I 50.0
MBs2496L7 etLSlzaos 50.0 I 50.0
CIIECK S.BI{PI,E 9 / L5 t200b 50-o I 50.o
Couuantg:
STL Denver
FonI XIII
STL DEATVER
Total Metals Analvsls
13-
PREPARATION LOG
Contrrct:
Lrb Code:
Method:
URg Corporetion
STLDEN Cuc No.:gIS, DIo. t sDo NO. r D5f02O23O
cv PrcD Mcthodr
Sampk fD Prcparation DrEa
InLtj.a1 voluma I FLne'r
I Voltrns (nlr)
slilB- 10- 090105 9lL9 12005 10.0 I 10.0
$IWEI-10-O90105 ![g 9lLe t20a5 10. o I r0.0
s9iIB-10 - 09010 5 tYrstD 9lL9l20as 10. o I 10.0
sgrB-3 - 0g 010 5 9lLe 1200s 10.0 I 10.0
s!{B-7-090105 9llg t20A5 10.0 I 10.0
M852s8348 9 tL9l200s 10.0 I 10.0
CHTCK S^trIIPIrE 9 t]-e /20a5 10.0 I 10-o
DUPTJTEITE CIIECK 9lL9 l2Aa5 10.0 I 10.0
Comuents:
STL Denver
tront, XIII IN
262
STL DENVER
Total Metals Analvsis
.13-
PREPARATION LOG
Contract r
Lab Cod.e :
Mottrod r
IIRS CorporatLon
STLDE}I Cage ![o - t g"Lg No.:sDo No. t D5I020230
PreD ![ct]rod:
Arruplc fD PrcDarats:Lon Datr
Inl-tiel Volume J rl'nel.
I Volumt (Er,)
swB-9-ogo105 912212005 1,0 I 10.0
Ilif,rB.n -tAB QC 9122120A5 10.0 I 10.0
LIB MS I 1221200s 10, 0 I 10.0
I*eB MSD 9122t2005 10. o I 10.0
rrB52 52{ 86 9 /22 12005 10.0 I 10.o
CHECK S.nTIPLE 9 l22l2AO5 10.o -l 10.0
DUPLICTTE CHEEK 9 122 t200s 10.0 I 10,0
Corursuts:
STL Denver FoTn I(III IN
263
STL DENVER
Total Metals Anslvsis
,I3-
PREPARATION LOG
ContncE r
fral Codc:
lfethodr
IrRS CoriI>oratLon
STI,DEDI Cage No. l g g tb.:sDc No.: D5f020?30
PraD Mcthodr
grrnDf 6 ID PrcDaratlon Date
fnLtial- Vol.umc I rinrl.
I volune (nlr)
surB-910-090105 9tL5t?005 50,0 I 50.0
S['IB- 9 - 09 010 5 etLSlzaos 50.0 I 50 .0
sI$rB-10-090105 9 tL5l20As 50,0 I 50.0
gurB-10-o90105 us 9 t LS l?Aos 50.0 I 50. O
s$rB-10-090105 }rsD e tL5l20a5 50,0 I 50. 0
swB-3-090105 9/Is l"oa5 50.0 I 50.0
swB-7 -o9 0105 9 / L5l200s 50.o I 50-0
M8s249615 9/15 t2A0s 50.0 I 50.0
gTITCK S.[I{PI,E 9 I L5 /2005 50. o I 50.0
CormenEg:
STL Denver
FOrur XIII IN
264
STL DENVER
'fotal M-lils Analvsis
ANALYSE RUN I,OG
Contract r
L,ab Code r
rnatrrrment,
St,art Date r
URS Corpomtion
STLDEII
ID ![unberr
9lL6 1200s
Cage No. r
riIJt fntrcptd ICP
SAg No.:
Mrthod r
SDG No.: D5I020230
End, Datc: 9 / LG l2OA5
r - IlBDotas ailtlltionl rloratc (oth.r thBE tb.atqrdlrd gtP olucat3) arr rGDroioBtcd[ oa alothcr for[ 1l
STL Denver
seqple
ID.
Dlr Tino esR
.f,nalytcg
il51 l trftl:lil :FI;]II ffil -l ;lrlIlIl"lil;
gtdl--BIank 1.00 11:49 x x x x x x
rc.ll,l 1. OO 11:53 x x x x x x
re.u2 1. oo 11t57 x x x x
ICAfr].1- O0 12rOO x x x x x x
IC}I,2 1. 00 12r05 x x x x x x
rglllt 1. oo 12r09 x x x x
zrcl,l[r 1.00 12:1{
esuH 1, OO 12r18 x x x x
cc\r&1- Oo LZ =22 x x x x x x
rCB 1.00 12r26 x x x x x x
RLSTD2 1- O0 12r31 x x x x x x I
ICTL 1. OO L2:35 x x x x x x T
ICgA 1. O0 12r{1 x x x x x x
ICSAB 1.00 LZt46 x x x x x x
cevH 1- oo 12r50 x x x x
cgvt,I .00 12;54 x x x x x x
CCB 1. Oo 12r58 x x x x x x
Cgtrll 1. oo 15:50 x x x x
CC1rII 1. OO 15:53 x x x x
CC'\III 1. O0 15:57 x x x x x
ccB 1.. OO 16:O1 x x x x x x
27,?'27,2 5-OO t5: O5
zzzzzT,1. OO 16:10 f-l F n
27.7,2717.1. OO 16:15
MB524 96L7 1- O0 16'r 19 x x x x x
CHTCK S.LDilPLE 1. OO 16r21 x x x x x
zD5r 02023 0- 000 1. 00 16:28
rD5I0A0ZJ0'00llr 5.00 10: 13
zD5I 020230-004s 1- 00 15r38
2D5r020230-000sD 1.00 16: {0
2D5r02023 0- 002 1. oo 16r{9
CCUT{1- 00 t5:55 x lx x x
CC1JrL 1,00 16:59 x x x x x
Fom XrV - IN
265
STL DEN}/ER
Total M-:if Analvsis
ANALYSIS RIIN LOG
Contract:
rab Codcr
InsEnrment,
€ltart Drtcr
IIRS Corporation
STLDEN
ID ll\uubcr r
e/L61200s
Caec No. t
TJL fntrtrpid ICP
SnS lilo. :
Method r
und Datc: 9 lL6l?AOs
sDO No. r D5I0'20230
P
Sarglle
ID.
DIE TImc 96R
tnll-ytcs
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snrB-7 -o90105 1. 00 17 :19 x x x lx x l*l
zzz7,7,z 1.00 Ll t?tl
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7.Z7,ZZZ 1. OO 17r39
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7'ZZ7,ZZ 1- OO 17 :54
cctrH 1. O0 17r59 x x x lx
CCTL 1. 00 18rO3 x x x lx x
CCB 1. OO 18: O7 x x x Ix x xl
t
STL
DcDoLaa rililitloael olomrtg (otber thaE tLe stildard CtP .lu.nt.) rrf, r.Dr...ated or rDoth.r ror. 1a
Denver
loran IIII - IN
256
STL DEIWER
Total Metals Analvsis
-14-
ANALYSH RTIN LOG
Contsract:
rab Codcr
Inetrnrncnt
Etrrt Dater
IIRSI Cozaroration
STLDEN
ID l[Urnbor:
e /L61200s
Caec No. t
TiIt' rnErepid fCP
SAg No-:
Mcthod: P
Eud Dat<rr 9 /LGl2OO5
SIlc No. : D5f 020230
8ampl.o
rD.DIr rLnc tR
lnalytcr
B I'
U
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Dr
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feAI{1 1.00 L1:53 x
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rc[L1 1. O0 12:0O x
IC.trL2 1. o0 12;05 x
Ig\TH 1. O0 12r09
zrcuL 1. Ool 12r1{
CCIIH 1- O0 12r18
cgvL 1. O0 L2:22 x
ICB 1- O0 LZ 226 x
RLgTD2 1- 0q 12:31 x
rc\rl,1- od 12:35 x a
ICSe.1. 00 L2: tLL x T
ICSAB 1- od L2tl6 x
CSTIH 1.00 12:5O
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ccB 1.O0 12t58 x
CC,\IH 1- O0 15r50
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cg\rL 1. Ool 15:57 x
ccB 1. O0 16: O1 x
zz7,zz7.5. O0 15: O6
T,ZZZZZ 1- O0 16:1O
zzzzzr.1.00 16r15
MBs2{9617 1. O0 16r19 x
CHECK SII'IPLE 1. ool LG 224 x
zDsr02 023 0- o04 1- O0 16r28
zDsr02 0330- o0{r,5.00 16r33
zDsr 024?30-0049 1.00 15r38
uD5ror 0rI 0-00{su 1.00 16r{{
2D5r02023 0 - 002 1. 00 16:09
CC\fiI 1.00 16r55 I
cguL 1. 00 15: 59 x I
ccB 1. 00 17r0{x
STL Denver Form I(IV IN
267
STL DENVER
Total Metals Analvsis
-14-
ANALYSNRTIN LOG
ContneE:
LrI) Code :
Irlst,rumcnt
Etart Datcr
IIRS Cor+roration
STI,DEN
fD Dhrmberr
9/L6t200s
Casa No. I
fill fntrepid rcP
g.Lg No. r
Mcthodt P
gDg No. r D5T420230
End Datcr 9 lLGl20A5
258Fom XIV f![
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P
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I
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cgwr 1. OO 17r59
cgt,tr,1. 00 18: O3 x
!cr 1.00 18:O7 x
STL Denver
STL DENVER
Total M"]ils Anslvsis
ANALYSIS RUN LOG
Contract r
Lab Codel
Inrt:nrmcnt,
gtart Datc:
IIRS Corpontloa
gTI,DEN
ID Nrrrtrlccr r
9/L9l2OA5
Cage No.:
Tittr fntrcptd ICP
S.I'g No. r
Msthod:
End Dare: 9 lL9IZOO5
SDo No-: D5I020230
P
Samtrllrr
ID.
Dlr Tirrc t6R
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ICI'L1 1.00 Lt t22 x x x x x x
ICnIrz 1. OO L{r25 x x x x x x
IC\III 1. 00 14 :3L x x x x
ZIg\It,1. OO 1{ :35
IgvT,1.00 I'tt : 39 x x x x x x
cc'\rH 1. OO 1{r4{x x x x
CC\TTJ r-. o0 14r{9 x x x x x x
ICB 1.00 1{ :53 x x x x x x IRLATD21. O0 14r58 x x x x x x
rcs.[,1. O0 15r02 x x x x x x
rcslB 1. O0 15r05 x x x x x x
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CCVT.r 1- 00 15r18 x x x x x x
CCB 1. OO Li t22 x x x x x x
CC1IH 1. OO 15r56 x x x x
cg\,rL 1.00 17r00 x x x x x x
ccB 1. OO 17rOl x x x x x x
ZZT,ZZZ 1. 00 17: O9
MBs2{ 96L7 1. OO 17r14 x
CHECK S}DfiPIIE 1. OO L7r18 x
swB-10-090r.05 10. o0 17r23 x x x x x x
gr{B-10-090105 sER 5.OO L7 :27 x x x x x x
swB-10-090105 Ms 10. o0 L7 232 x x x x x x
8WB-10*090LO5 IIISD 10.00 L'l z 37 x x x x x x
ssrB-9Lo- 09 010 5 10, 00 L7 t17 Ir It x x x x
ssrB-9 -09010s 10. 00 L7 t47 x x x x
61{8-3 - 090105 5.00 L7 252 x x x x x x
I
CC:VII 1 .00 L'l t57 x x x x T
CCYIJ 1,00 18r01 x x x x x x
ccB 1.00 18:05 x x x x x x
I
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STL Denver
tro:.r Xn, - IN
269
STL DETVVER
I'otal Metals Analvsis
'14-
ANALYSIS RUN LOG
Cortractt tRS Corporat,.ou
Lab Codc: STLDEN Cagc No. :gt.8 No. r
Iostrunoot ID lftrubcr: Tirl lBtrcptd ICP Methodt P
SDc No. t D5I020230
Start Datc: 9 lL9 lzOAs End, Date : 9 llg lzOOs
Sarfr].c
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x
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cgwr I1- 0q 1{r14
cg\rr.1.O0 1{r{9 x
ICB 1-o0 1{:53 x
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ICgAB 1.0d
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cglrt 1 .00 15t18 x
ccB 1. 00 15r22 x
CC'IIH 1. 00 16:56
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swB-10-o9010s Ms 10. 0c L-I t32 x
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swB*910-o9 01 05 10.oc L7 t42 x
swB-g - 090 105 10. 00 L7 z4l x
sl[B-3 - 090105 5. 00 lt $2 T
cc'\rH 1 .00 17 :57
Cg\TL 1- 00 18:01 x
hr 1.00 18r05 x
STL Denver Pont XI\f IN
274
STL DENVER
Total M-lils Analvsis
ANALY$S RUNLOG
Contract r
tab eodcr
Instrrrrmcnt
Start Datrr
IIRS Corporation
STI,DEN
ID ll\unbcr r
9/2A12005
Caee No.:
TJI' Int,rcptd ICP
8AS No. t
Mctrhod:
und Drtcr 9 l?O/ZAAs
P
sDG IVo. t D5I020230
I ! Dcnotra addltional rlenouEr
STL Denver
(other than thc rtondard eLP cltmntss) ar. roDresentrd
Form XIV IN
Bamplc
ID.
D/t trlma TR
gtdI.-Bhnk 1. oo 10r55 x x
rgr&1 1.00 11tO1 x x
ICf,Lz 1. O0 11r05 x
ICALI-1- OO 11: O9 x x
fCAIra 1- o0 11:14 x x
rc'vH 1.00 11r28 x
IC1rr,1- 00 11r33 x x
CCIIH 1- oo 11:37 x
ccur,1- OO LL:42 x x
ICB 1. OO 11:47 x x
Rf,gEDz 1.OO 11:52 x x
ICgI.1- 00 11:55 x x -
ICSTB 1. OO 12rO1 x x
swrl- 9 - og010s 20. oo 12: O5 x x
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cg\rL 1- OO LZ zZL x x
eeB 1. OO 12 :26 x x
on rnobher Forru 1ll
27 I
STL DENVER
Tota[ M-lils Analvsis
ANALYSIS RUN LOG
Coatract:
trb Codrrg
Ingtnrmcnt,
start Dat('r
IrRg Corporation
STI,DEN
ID ll\rmbar;
9lL6l200s
Crac No. r
SUPERTR.LCE II
SfA No.:
Methodr
SDg No.: D5I020230
End Darc: 9 lL6l 2005
(other tlren thr ate-ndard eLP ollneutr) ar. roprrt.ntcd on anothcr Form 1lI Donoter addiUloaal clmeatg
STL Denver 272
Earqple
ID.
DID TLme ?6R
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HIGH 1.00 11:58 x x x x x x x x x
ICt,lr 1. 00 12: O3 x x x x x x x x x
cg\rT 1. O0 12rO8 x x x x x xl x x x
ICB 1. 00 L2:.LZ x x x x x x x x x
NLATD 1. OO 1-2:L7 x x x x x x x x x
rcs 1. 00 L2 t22 x x x x x xl x x x
ICS.hS 1.00 L2:27 x x x x x x x x x
I,R 1,OO L2232 x x x x x x x x
LR E3 1. OO L2 237 x
cc\rr | 1 1. oo t2 z tL2 x x x x x x x x x
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cclrr | 3 1,OO 14r03 x x x x x x x x x
ccBl3 l-. oo 1{: O8 x x x Ix x x x x x
MB52{9517 1.00 1{r13 x x x x x x x x x
CHECK S}IIPIJE 1. OO 14:18 x x x x x x x x x
z,D5702023 0- OO2 1. OO 14:23
2D5r020230-003 1. OO Ll227
2D5r020230-oo{1. 00 1{ :32
swB-3 -090105 1. OO 1{r39 x x x x x x x x x
sr{B-7 -090105 1. OO 14 :43 x x x x x x x x x
cs\,lr I4 1.00 1{r48 x x x x x xl x x x
ccBl{1. oo 14 :53 x x x x x x x x x
cc,\nr Irr 1.00 ?O:31 x x x x x x x x x
ccB I rr 1.00 20:35 x x x x x x x x x
swB- 910- 09 010s 5.00 20:{0 x x x x x x x x x
2D5r02023 0 - 003 5r00 30 il0
gwB- 10- 09 01 05 5 .00 20t50 x x x x x x x x {
swB-10-090105 8ER 5 .00 20:55 x x x x x .l x x x
S:$IB-10-090105 usl 5.00 21r00 x x x x x xl x x x
lsrua-10-o9o1o5 usD 5,OO 21tO5 x x x x x x x x x
z7,z7,zz 2.00 21r10
Porm Xr\I fN
STL DETWER
Total Int-:lls Analvsis
ANALYSNRI'NLOG
Contract:
Lrb Codcr
fartrnrncnE,
Stsrrt, Datsa r
IrRS Cort>oratLon
gTI,DEN
ID lihunbcr r
9 /L6t200s
Carc No.:
ST'PERTN.LCE II
AIA No. t
Mrttrodl
IEnd Datc: 9 l LG l?OOs
SIXI No. : D8I020230
Samgr1e
rD-
Dlv Tinc tR
.Brralytcr
.L
fr
g
B
L
g
B
A
B
E
c
D
c
A
c
R
c
o
ral
"l EI ;M
o
M
N
H
G}
Nr K s
E
A
o
rlr
"1""l;C
N
cs\m |tz 1. oo 21r15 x x x x I I*l xl x x x
ccB ltz 1. O0 21:2o x x lx x I f x l*l I l*[ I l*x
r - IlDtotos aatdtt.losrl .l.neata (other tha,r tho rtard.rd CLP cloD.Dt.) rre roDr.lGnted 6 !,Bother Fo6 1l!
STL Denver ,orr XIV - fN
273
STL DEIVVER
Total M.llls Analvsis
ANAI,YSIS RUN LOG
Contnet:
f,lb Codc I
Ingtnrltent
Etart Datcr
IrRg Corlrorat,r.on
STI,DEN
ID llluuber r
9 / L9 t20A5
Cacc No.:
SUPERTRACE II
gAS No. t
Methodr
IEnd Datrr 9lLg l?OAs
SDO No.: D5I020230
gantrrlc
ID.
DIr Timc 96R
lnalyber
^f,
L
s
B
L
I
B
l,
s Je
"1,
c
.f,
c
R
c
o
Clr
"1"
P
B
uluol*H
G II"s
E
.lL,
G
N
l'
,:Il
L
v z
N
e
N
STD1 -BI"}IUK 1. O0 11rOB x x x x xi x x x
HISTD 1- O0 11:13 x x x x xl x x x
HTOH 1. 00 11r18 x x x x x x x x x
Igur 1.00 11r23 x x x x x x x x x
cg\rlt 1. 00 11:28 x x x x x x x x x
IcB t. oo 11 :33 x IC x x x x x x x
RLgTD 1. OO 11t38 x x x x x x x x x
ICg.L 1. OO 11r63 x x x x x x x x x
ICSAB 1.00 11:48 x x x x x x x x x
I,R 1. OO 11r53 x x x x x x x x
LR G3 1.00 11:58 x
CC,\IT J 1 1.OO 12;O{x x x x x x x x x
ccBll 1. oo 12: O9 x x x x x xi x x x
ccrm la 1. OO 17:{3 x x x Jx x xl x x x
ccsla 1. OO L7 :48 x x x x x xl x x x
swB-9 -090105 10. o0 17r53 x x x x x x x x x
z%zzzz 5. OO l7 257
ZT,ZT,Z,Z 1. OO 18: O2
?,T'ZTZZZ 5. O0 18: O8
Z,Z,Z,7,7,7,10.00 18r13
T,Zzzzz 2. O0 18r17
cc\mls 1. oo LB 222 x x x x x x x x x
CCBIg 1. O0 LB t27 x x x x x x x x x
. - D.[otG. adldLtiolal eleoonta (oth€r thr! the Blardrrd eLp'Glcatta) are r.gr.rsrtedl oo uotbor For! 1a
STL Denver Foril )CtV - IN
274
STL DEIVVER
Total *-jff Analvsls
AI{ALYSIS RUN LOG
Contract r
Lab Coder
Ingtnrncnt
Start Drta:
IIRS Cora>oration
STI,DEN
ID Nurubsr s
9tL912005
Cagc No.:
PE CTIAI,
Sng No.:
Mctrhod:
End Drtc: 9 ll9 l2aa5
gug No. r D5T420230
w
Sarqple
ID.
D/P Timr IR
.fnalytrra
.L
TJ
g
B
l'
g
B
n,
B
t
clc
"lo
c
n';l;l F
E
P
B
M
o
uln*lo DI
I
K s
E
.l'
o
N
A
lttl
L
v 7t
N
c
N
Ca1lb Blan'k 1- oo 15:12 x
0.2 Dpb 1- oo 15:14 x
0.5 ppb 1- O0 15r16 x
1. O ppb 1- OO 15:18 x
2.4 Drrb 1, OO 1,5 r 19 x
5. O ppb 1. OO 15 :21 x
10.O D;>b 1. OO 15r23 x
ICB 1. OO 15r25 x
rc\r 1- oo L5 z2'l x
ceyl.1- OO 15 :28 x
CCBI,1. o0 15r30 x I
RI,1- 00 15r32 x I
zz7,7,zz 1.00 15r33
zzzzz,z 1.00 15 :35
ZZZZZZ 1- O0 15r37
T,ZZZZZ 1. OO 15 :38
zz7,zz7.1. oo 15:4O
Z7,7,ZZT.1, OO LSt42
zzzzzz 1. OO 15r{3
zzz7.zz.1. OO 15:{5
7,ZT.ZZZ 1. OO L5=47
ccv?1. OO 15r49 x
CCB2 1. O0 15 :5O x
cgu3 1. O0 15r09 x
ccB3 1.00 16:1O x
7.227,27,1.00 16r12
zzzzzz 1- 00 L6r1{
Zlr7r7,Z7r 1. 00 16:15
7,Z,Z,7,7,2 1. 00 16: 17
zzzzzz,1.00 16r19
7.7r7rZZZ L. 00 16:2I.
7,ZZZ7,7,1. 00 LG g22
7,ZZ7,ZZ 1.00 15r21 I I
I
I
r - D.rctar rdditioDal ol,eD3rrt, (other thlu thr atasdard clr! el[aotB) ara rGDr..e8tc{l m rnothar rom 1{
STL Denver
loru )(Iv - IN
275
STL DENVER
Total M-lils Analvsis
AIIAI,YSN RUN LOG
Contraets:
Lab Coder
Inatnutcnt
Start, Datrr
IIRS CorI>oratlon
SltrLDEN
ID l{lrrubcr r
9llg 1200s
CctG No. t
PE C\,1LN,
8.B.EI No,:
Mcthod:
SDc No. r D5I02023A
t Denotra additlonal eLrnentss
STL Denver
CV
End Dltrrr 9l1,glz00s
(othor than thr;tandard Cr,p rleuentr) aro r.pr.r.nEcd on aootsher For^n 1l
SamIrlo
rD-
D/r Tirrc IR
.tnal-ytes
I'
IJ
s
B
l'
g
B
t,
B
E
c
D
c
Jt
c
R
c
o
c
U
r
E
P
B
u
g
M
N
H
-tt
N
r
K g
!-,
I'
G
N
l'
T
L
v 7.
N
c
N
zzzzzz,1.00 16r25
MBs258348 1. 00 16r28 x
cg\ru 1. oo L6:29 x
ccB{1.00 16:31 x
CHECTI g"N'PLE 1. O0 15:33 x
DUPLIef,l[E eIIECK 1.00 15r3{x --l I
HK'IFI'1- Oo 15r36 x
Z7,ZZ7.Z 1.00 16:38
zDsro2A230-oO3 1- OO 15r39
arrB-10-090105 1. oo 15r{1 x
gwB-10-o90105 MSr 1- O0 16: {3 x
swB-10-o90105 MAD 1. OO 16r44 x
gwB-3-og0105 1- OO 15r46 x
sr[B-7-090105 1. oo 15r{8 x
ceu5 1. OO 15r49 x
ceBS 1. OO 15r51 x
FoM XIV IN
276
STL DENVER
I'otal lnt-lif Antlvsis
AI\ALYSIS RUN [,OG
Conbnct r
LiI, Code:
InsErnrnent
Start Drtc:
IrRg Corpore,tion
gTLDEhI
ID Numbcrr
91221200s
Caee No. t
PE CXr}B.
gAg No. r
Mcthodr gv
End. Datrrs 9l22lzA0s
gDo l\Io. r D5I020230
sarylIo
ID.
DIF Timc IR
Alealytes
A
Ir
s
B
I'
g
B
A : l;l:c
R Ill tl"[;l ;
Ca1ib BLanIG 1. O0 17r11 x
O. 2 pplr 1- O0 17r13 x
O-5 pptt 1.O0 17 :15 x
1.O ppb 1. OO L7 tLT x
2. O ppb 1. OO 17 ;18 x
5.O ppb 1. O0 L7 tZA x
10. O ppb 1. OO L'l t22 x
ICB 1. OO L7:{5 x
rcv 1-OO Ll t tLT x
cc\r[1.00 17:{8 x
ccB].1. OO 17 :5O x I
RL 1- OO L7 r52 x t
7rZZZ7,7,1- OO 17r53
?,7,7,ZZ7,1.00 17r55
T,ZZZZZ 1. OO 17:57
zzzz7,7,1. O0 L7'-58,
zzzzzT.1- OO 18:OO
Z'7,2Z.7.7.1- OO 18rO?
zzzzz,z 1. OO 18: O3 I
zzzz,zz L. oo 18: O5
7.2r.27r7,1. O0 18rO7
cg\r2 1. 00 18: O9 x
ecB2 1.00 18:1O x
ccvs 1- 00 19:O9 x
CCB5 1. 00 19r11 x
Z7.7.7rZZ 1- O0 19r13
zzzzzz,1. OO 19:15
\TIATZTI 1' 00 11i10
7.27.7.Tr2 1.00 19:18
M85262t186 1.00 19r20 x
CHECK STUPLE 1.00 19:21 x
DUPIJTCATE CHECK 1.00 19:23 x I I
gurB- 9 -090105 1.00 19:25 x
r - DeDDtar addltlo!,rl oIGbatB (othar thar tb. rtildrrat Crrp 61u.ata) aro r.Dr.r.ntad o[ rmtbor Fon 1l
STL Denver
fom XIV IN
277
STL DENVER
Total *-:lls Analvsis
ANALYSIS RUN LOG
Contract:
Lrb Codc:
InetnrrnGnt
Start Datcr
IrRg Corporation
gTLDtN
fD liltrmber r
9/221200s
Caec No.:
PE C:VT.}.
gJlfl No- r
Hctbodr
gDs No. ! D5f02O230
t Deuotes adcllt,lonal clencutt
STL Denver
cl,
End, Drte: 9 122 lz00s
(otbcr than thr rtrndard CLD ahn+ats) aro r.DroBontrd on anothor Form 1l
enalytsot
Sa4rl-e lD/P lrLne ltR
Foru, XMN
278
STL DENVER
Total M.jils Analvsis
ANALYSH RIIN LOG
Contracts r
LaI) Codc r
Instrutnant
Start Drtc:
IIRS Corporatl,oa
STLDEN
ID ![umber I
9122/200s
Crec No. t
PE ICPT{g
S.l,g No. t
Methodr
sDc No. r D5IO20230
M
r - DG,otoE addlitlonal olurnbe (oth.r tbatr thc EtaEdard cLp .1.L6trt,.) ara r6Dre..atrd oa arrothcr poa 1rt
STL Denver
fortl XIV - IN
Samgrlc
rD.
Dlg Timc TR
Arralyt,cr
I
L
g
B
t
s
sls
"l=;l:c
R
c
o
c
u
r
E
D
B
M
GI
M
N
H
o
![
I
K s
E
L
G
N
.t'
T
IJ
v T.
N
c
N
BIanlc 1. O0 2A:4L x x
Standrrd 1 1- OO 2O: {4 x x
ac std 1.1. O0 20:48 x x
QC Sr,d 2 1- O0 2O: 51 x x
RLStrD 1. O0 2O: 55 x x
zzz7,7,z 1- OO 2Or59
ICAA 1. OO 21r02 x x
rESAB 1- o0 21:06 x x
RI}ISE 1. O0 21:10 x x
HICII CHECI(1. 00 21r1{x x
RINgE 1.00 2LzL7 x x I
ac srd 3 1.00 21r21 x x
oc srd 4 1. O0 2Lt?5 x x
BIenk 1. oo 23r15 x x
Btandard 1 1.00 73:2L,x x
ac srd 3 1. O0 23 t25 x x
oc srd. 4 1. oo 23 :38 x x
ac srd' 3 1.00 O7r1O x x
ac std IL 1- OO A7 :Lt x x
MBs 249 616 1. oo O7 tLT x x
CHECK ATDIPI,T 1. 00 O7 t21 x x
svilB-910- 090105 20-00 A7 :25 x x
zDsr020230-003 c0.00 O7r28
zDsrO2073 0-O04 20. oo 07'.32
2D5r020230-OO{L 5, OO O7:35
zD5r 02423 0- 00{r 1. O0 07r39
2D5r020230-00118 20. oo O7 r43 n [l
zDsr02az30- 00{gD 30r00 07r10
QC Std,3 1. 00 07r50 x x
ac sEd 4 1. 00 07 :5{x x
swB-3 - 09 010 5 10.00 O7 257 x x t
srrB-7 - 09 0105 5.00 08r01 x x
Z7r7r7.ZZ 1, O0 08r05
279
STL DENVER
Total M"]il: Ao"Ivsis
AI\ALYSIS RUN LOG
ContracE:
Lrb Code:
fnetsnrrtcnt
Start Dater
t RS Corporat,Lon
STI,DEN
ID lhtnbcr r
9122 1200s
Caac lilo. :
PE :ICPMS
SAS No-:
Mstbod:
Erd Daurl3 9 12312005
gDc No.: D5TO2023O
M
8amplo
ID.
Dlr Tlme 96R i
zzT,ZZZ 1. 00 OErOB
ZZT.7'Z,Z 1- oo OBr12
z%7,zzz 1. O0 OBr16
T,ZZZZZ 20-oo O8:19
T,ZZZZZ 100. oo 08r23
oc srd. 3 1 .00 A8:27 x x I_
ac sBd {1. OO O8:30 x x
BI.auk 1- O0 10:16 Jx x
Strndard, 1 1. OO 1O:21 x x
Qe std, 3 1. oo 1Or2{x x
ac srd 4 1. OO 1O:28 Jx x
rCSA 1. O0 10r32 x x
ICA}B 1. 00 10r36 x x
RTNgE 1. oo 10r39 x x
ac sEd 3 1. OO 1O r 113 x x
ac srd I 1. O0 1Or{7 x x
ac sEd 3 1- O0 11r52 x x
ac srd 4 1. OO 11r56 x x
swB-9 -0901 05 100. o0 12: O1 x x
gr1rB-10-090105 {o. o0 12: O5 x x
swB-10-090105 sER 5. O0 12: O9 x x
swB-10-090105 PDs 1. O0 LZ tL?x x
s9[B-10-090105 USr {0. 00 L2 tLG x x
swB-10-090105 DrsID {o. 00 L2'-L9 x x
oc sr,d 3 1.00 12123 Ix x
Qc srd 4 1- o0 L2 t27 x x
t ' D.Eotca oddltioqrl .lori.Dt. (otbrr the.o th. ltaillit:it CLt' c1ffi6ntt) a!. !6lrro8.Dt.d ola laotlr€r ,'or[ 1a
STL Denver
Form )tIV IN
280
C1ient, Iot
PARA}ITETER
#---: D5f02023O
IiETECID BIJATTK REFORT
General- Chentatrlr
IT{ETHOD
lratri:r-,-, -- -- -: WATER
PREPARATION- PREP
AI{TAIJYSIS DATE BATCH #
REPORTTNG
RESULT LIMfT UIIfTS
Ammonia as N
Ammonia as N
Clrloride
Fl-uorLde
Nitrate
Nitrate-Nitrite
Su]-fate
Total Qyanide
rurE (s) :
o_o17 B
ND
2-g B
Irlork Order #: HKH94I-AA
0 , 10 mg/I'
Dl.lution E'actor: 1
AnaIyBiE Time..: 05:00
Work Order #: HKGNLTIAA
0.L0 mg/T,
Dllutlon Factor:. 1
enalysie Tlmrl,.: L?:OO
Work Order #: HKDP11AA
2 .5 mg /r,
Dl-Iutl-on Factor: 1
Analyeie Tl:ne. . : LO : 00
Work Order #: HKCX41AA
O - 10 rytll
DLlution Factor: I
Analycle Tirna- , : 1tr :30
Work Order #: HKTI,CI-AA
0. 10 rng/L
Dilution Factor; L
Analyelg Time..: 12:OO
Work order #: HKTFII:.AA
o. 10 mg/L
Dilutiou Paetror: 1
Analyels Tlme.,: 16:0O
lilork Order #: ll\tZGIrlAA
5-O ryll,
DLlutlon Factor: 1
-analyeJ.s Time- . : 14 : 30
Work order #: HIGIHW1AA
0,010 mg/t
Dtlutlon F'actor: I
Analysi.o TLrne. . : t2:3O
MB lrot*Sample
MCAI{W 350.1
MB lrot-Samp1e
IvICAWW 350.1
D{B Lot-Samp}e
MCAI{IS 325 .2
IUB Irot-sarnple
ueaml 340 - 2
!,IB lrot-Sample
MCAUIIII 353 - 2
D{B Lot-Samp}e
MCAWW 353 .2
MB Lot-Sample
Itchffi 375 -4
MB tot-Sarqr1e *:
sll845 901O8/g012^A,
Dsr140000 -378
oe /Lq/ as s2s7378
D5r220000- 424
oe/za/ as s26s424
Dsr090000-250
a9 / oglos szszzsa
D5r090000 - s4 0oslos/os s2s2s4o
D5T220000-577
ae / 02/ as s26ss
D5T22000 A-542
09 /20/ os s26ss42
D5IO50000-s86
oe/a6los s249s86'
Dsrl_40000 -427
oe / L4- oe / ts / os s2s7 427
o
77
r[D
Crl*lrtions ars performd hfore rounding to avoid roundoffenors in calculatd results.
B Ectinutul rcsult. Reurtt is less rhan RL.
STL Denver 2Ba
ffi COIIaSOI.r SiltlPlfi EIZBLIIATTOH RBFORT
Geueral. Clrcnistry
I,ot-Baryl1e *. . . 3 D5IA2O23O
PERCEMT RECO\IERY
RECOVERY ITfMITS
RPD
RPD IJIMITS METHOD
trlatri:r. - - - - , - - - : WATER
PREPARATION- PREP
AIIAITYSTS DATB BATCH #
Lot-Samp1e# : D5r020000-545
oe / oz/ os 524ss45
09 / 02/ as s24ss45
Lot- Samp1e# : D5I14 0000-3 78
a9 / L4 / A5 52s73't I
o? /L4/as s2s7378
Lot-Samp1e# : D5I060000-s85
09 / a6 / as 5249s86
ae / a6 / as s24es85
PAIUNvIETER
pH
100
100
Ammonia aa N
108
l- 10
Arnmonl-a aB N
L01
99
Fluoride
Ititrate
97
97
NLtrate-Nitrite
105
101
Sulfate
LO2
LA7
Tota1 Cyanlde
1-0 7
106
wo# : H.I7T51AA- r,CS /HJ7T5IAC-ITCSD LCS
(gt 102 ) swgc o e 04 oB
(97 102) 0.0 (O-5.0) SW8A6 90408
Dl-}utrlon Factor; L
wo# : HKIIS4LAe-teS/HKIIg4LAD-r,eSD LCS
(go 110) MeAww 350.1
(go 110) 1.5 (O-10) MCAWW 350.1
wo# : HiI2Gr,lAC- ICS/H.]2GL1AD - LCSD LCS
(gr LLz) ucAwl{ 375.q
(9r LLz) 4.2 (O-15) FICAWW 375.4
Dilution Factor: 1
wo# :HK6N,J1AC-r,CS/HK6NJ!AD-LCSD LCS r,ot- Sary>le* : D5r220000 -424
(9o - 110) McArlw 3s0.1 oglzo/os 5265424
(90 - 110) 2.0 (0-10) McAww 3s0.1 }g/zo/os s265424
Dilut,ion Factor: I Anal-yeis TLme, - : 17 : O0
IrD# : HKCX41AC-LCS/HKCX41AD-LCSD LeS IJot- Sample* : D5I09OOO0 - 54 0
93 (82 - 114) McAww 340-2 og/aglos s2s2540
e6 (87 - 114) 3.3 (0-16) MeAww 340.2 og/oglos s2s254o
ol-].utlon Pactor: L
Wo# :HKTLCIAC-rc8/HKTIJCLAD-IJCSD r,CS r,ot-sample# : D5r22o0o0-577
(86 - 110) Mcar{rf, 3s3.2 ogloz/os s265577
(86 - 1r-0) 0.61 (o-10) McAyrw 3s3.2 og/ozlos s265577
DLlut,lon Factor: 1 AnaIyBlB TLme..; L2:O0
l$o# : HKTENIAC-LCS/HKTFNLAD-L,CSD IJCS Lot-sample* : D5I22 0O0O-542
192 - LLz, MeAww 3ss.2 oelzo/os sz6ss42
(gz - 112) {.5 (o-10) MeAww 3s3.2 og/zo/os s26ss42
DiluEion Factor; 1
Dllutlon Faetor: 1
[IO# : HIGIIIWTaC- I,CS/HK.THWIAD-LCSD tCS Lot - gample# : D5I14 0 O0 0 - 4 2 7
(89 10e)sw846 9o1AB/ 90L2A A9 /L4-A9 / 1sl0s 5257427
(s9 - 1o9) o.e3 (o-20) sws1r6 goton/gotze, oglta-og/:.s/os 5257427
Dil.ution Factor: 1
STL Denver
(Continued on next page)
282
ffi mIITROL SAHPI,B ffi
Geueral. Chenistry
RBFORT
Lot-Sarqll-e *-, . r D5IA2O23 0
PERCENT RECOVERY RPD
PARAMETER RECO\TERY IJIMITS RPD IJTMITS D/TETHOD
IKrfE (S) :
liat.ri-x- - - - - . . - - i WATER
PREPARATTON- PREP
AIIAITYSTS DATE BATCH *
Calcrrladolls Bre performed before rounding to avoirl rourd+ff crrors in cslculatcd rcsrrls,
STL Denver 283
m COI5:IROIT SAUPITB DAm. REgORf
General Cheniatry
Irot-Saryl1e *- - -: D5IO2O23A
SPIKE MEJASTIRED PERCNT
PARAMETER A}{OI,NT AMOI]NT I]NITS RECIB.Y RPD METHOD
pH WO# : Hr,7?T5 LAA- I-,eS / UJ7fs IAC - IrCSD
7. OO 7 ,02
7.00 7 _o2
No Units 100 sw84 5
No Units L00 0-0 sw845
Dilution Factor: 1 Analysl-a
Arnmonia as N WO# : HK}I94 LAC- L,CS/HKH9 4 1AD - LCSD
tlatri:r- - - - - - o - . : WATER
PREPARATION- PREP
AI{ATJYSIS DATE BATCH #
IICS Lot-$am5lle# : D5IA2O000-545
eo4oB 09 / a2/ as 5245545
eo4oB 09 / 02/ os s245s46
Tlme-.: 1,2;10
LCS Lot-Sample# : D5I140000-378
350.1- oe/a4/os s2s7378
3so . L ae / L4/ 0s 5257378
Tirne..l 05:OO
te9 lrot-Sarylle#: D5I22O000 -424
3s0. L 09 /zo/ os 5265424
350.r- Ae/2A/05 s26s424
Time..: 17:OO
IrCS Lot-Sarylle# : D5I090000-540
34A.2 AelAg/os s252s40
34O .2 09 / A9 / 05 s25254O
?ime, . : 11:30
IreS Lot-Sample# : D5T22000O-577
353 .2 Oe / 02/ Os s26ss77
353.2 O9/A2/A5 526ss77
TJ.me..: 12:00
tCg Lot-Sample#: D5I220000-542
353 .2 Oe/zOlOS s26ss42
3 s3 . 2 09 / 2O / OS s26ss42
Tl.me..; L6rOO
4.00
4.00
4 - 00
4-OO
4.33
4 .40
4.03
3.95
PllutLon Factor: 1 Arralysle
wo# : HKSNJLAC- LCS / HK6NJ1AD - LCSD
101 MCAhm
99 2.O MCAWW
.a,nalyelenl-lutl-on Factor: 1
wo# : HKCX4lAC -LCS /HKCX4IAD-ITCSD
mg/t
mg/r,
mg/t,
mg/t
nrg /I'
ms/r,
mg /I'
mg/r,
Pi].utlon FacEor: 1
108 MCAhIW
110 L .6 MCAWW
93 MCAWW
96 3-3 MCAIJW
105 MCAWW
101_ 4_6 MeAlrW
Anmonia aa N
Fluoride
NiLrate
Nitrate-Nitrite
4 .00
4 .00
Sulfat e
25. O
25-0
Total Clfanide
0"100
0, 100
5. OO 4.53
5. O0 4.79
4.2L
4-02
0.0500 O-0483 mg/L
0.05oO 0.0485 mg/L
Dl1utlon Factor: 1 Analyeie
wo# : HK?I_,eil\e - LCS/HK7I,C LAD- LCSD
97 MCAWW
9-l 0.51 MCAWW
Dl-lutlon FacEor: L Analyala
WO* : HK? FIiIIAC - I,CS /HK7 ET{ ].AD - I,CSD
nnalyels
WO* : Hif2GLUC-ICS/UiI2GIr1AD-ITCSD LCS Lot - Sample* : DsIO 6 OOO0 - 5 I 5
2s -6 rg/r, Lo2 McAr'r!{ 37s.4 o9/o6/a5 sz4gsa626.6 w/t, to7 4.2 McAww 37s.4 og/oe /os 5249s86
ollutlon Pactor: 1 Ana,lyale Tlme..: t{r3o
wo# : HIG[rrrrlAC -LCS /HKJI{WLAD - LCSD
0.107 mg/L
o . 106 mg/T,
LO',l sw84 6
L06 0.93 SW846
DiluEl,on Factor: 1 AnalysLe
(Continued on next page)
IJCS Lot -Samp1e# : D5I14000 0 -427
e01 0B/ e012A 09 / 14 - Oe / L5 / Os s2s7427
901 AB/ eALaA ae l14 - 09 / rs / Os s2s7 427
Tlme. -: 1"2;30
STL Denver 284
O
W COtrISO .. 8,EUPIiE I}AEA RBEORT
General Chemlstry
Iot,-Saqtl.e *- . - : D5f020230
SPIKE MEASIIRED
PARAMETER AIvIOI,I\flT AII{OUNT T,NITS
PERCITT
REC\'IRY RPD METHOD
llatri:r- - O + - - - - - : WATER
PREPARArION- PREP
AI{ALYSfS DATE BATCH #
rwfB (s) :
Cslculations are pcrformed bofore rourr<tlng to avoid roud+ff orrors in calqrlatod rsults.
STL Denver 285
ffi OOIT.IROL SEDIHEE TIILIilIATTOT RBBOR:r
General- Chemistsry
Cl.ient Iot il -
B}BAI{BTERChloride
s,Its(s):
: D5I02O23A
PERCENT RECOVERY
RECOVERY IJIMITS IUIETHOD
100
llatri:r-- - - -- - --3 WATER
PREPARATION- PREP
AI{AI,YSIS DATE.. BATCH flfork Order #: HI(DP11AC IJCS Lot-Sample#: D5I090O0O-25O
(9O - 11O) MCAVTW 32s.2 Og/OA/OS 52522sO
Dllutrion Pactor; 1
Calcuhtions arc pcrforrned before roundfu to avold roundofforrors in calculated resuhs.
STL Denver 286
W EONTIROIJ SAUPI'B DATA RBtrORT
GeneraJ. CIrcnLatry
PERCMT
TINITS RECVR,Y I{ETHOD
l[atsri:r- - - - - - - - - i IiIATER
PREPARJhTTON- PREP
AIIBI.,YSTS DATE BATCH #
CII-ent fot
PARJAII{ETER
Chloride
rrolfB (s) :
*- - -: D5f020230
SPIKE MEASURED
AII{OI}NT AI'{OI]NT
50. o
Tlork Order *: HKDPI1AC LCS Lot-garylle#: DSIo9OOOO-250
50.0 nsh, 100 MeAr{w 32s.2 og/oglos 5252250
OLJ'utlo Factor: 1 laElyei.e Tine..: 1O:00
CslmlafioDs are pcrformed bsfore rourdlng to avoid rourxl<rff erron$ in calculatcd rcsults.
STL Denver 287
PAR:AII{ETER RECOTTTERI -III$ITF RPD IJIMITS MEIIIOD
C1ieut, t.ot S---! D5IO2O230
Date gar5)I"ed- - - ! a9 / A6 / As
PERCEIM RECOVERY
Ammonia as N
100
101
AnunonLa as N
l[LtRIf, SPIIG SAUPITB ffi RBBORI
Geueral Chenistry
Date Recelved- - i A9 / 09 / 05
RPD
llatrLx-: I{ATER
PREPARATION- PREP
Ar{Ar,Ysrs DAT_E BATCH #
MS Lot-Sample #: D5IO90L52-001
ae /L4/ os s257378
oe /L4/as s2s7378
I,ot * Sample * : D5rO9O3 77 -A32
09/L4/os 52s7378
oe / L4 / os s2s 7378
Lot-Sample # : D5f02O229-001
ae/ o8los s2s22sO
09 / o8los s2s22sa
wo# : HLI8E01AJ-MS/H.I8E01AK-MSD
(++ 13o) ucAww 350. L
Qq 130) o-82 (O-30) MCAr{r{ 350.1
Dllut,Lon Factor: L
erralyeie Time. . : 05 : OO
10L
98
105
L04
(++
(**
(go
(e0
wo#:
130)
13O) 1. 5 ( o-3 o)
DLluElon Factor: 1
Analyaie Tima. . : 05: O0
wo#:
110 )
11_O) 0.39 ( O-1-0)
Dilution Factor: 1
Analygie ?ime,. . : 10: OO
Hr(AA1 lAD - MS /HrGA1 lAE-t/tSD MS
MCAWW 350.1
MCAWW 350.1-
Htr\IPo IAR-MS /Xinrpo IAT-MSD MSI
MCAI{V{ 325.2
MCAT{I{ 325.2
Chloride
rufB(s) :
Calcthtions ere pcrformerl before roulrdlng to rvoirt roulrd-off orrorc in calculeted reguls.
STL Denver 288
Cl.ieut lot f,---; D5I020230
Date Saqlled- . . 3 A9 / 06 / AS
PARAITETER
Anunonia aa
SAIyIPITE SPIKE
A}IOUNT AIVIT
N
0.58 4 . O0
0.58 4,00
}BTRIT APIffi S,IUPIiB DATA RBBORT
General' Chemlstrlr
Date Recelved- - 3 09 / 09 / Os
llatrlx- - - - - - - - - :
PREPARATION- PREP
AT{IAIJYSTS DATE BATCH #
oe/L4/os s2s7378
ae /L4l as s2s7378
#: DsI090377 - 032
09/L4/ os s2s7378
oe/L4/ as s2s7378
#: D5I020229 -00L
ae / os / 05 s2s22so
os / og/os s2s 22so
O
UIATBR
MEASRD
AIUOTTNT UNTTS
PERCNT
REC\IRY RPD METHOD
1_00 MCAWW 350.1
101 0.92 MCAWII 350.].
wo*: HirSEore.r-us/nr8E01AK-MgD Mg Iot-sary)le #: D5r09o152-0O1
4 - 58 mg/t'
4.6!. mg/L
Ammonia as N
t7
a7
Chlorlde
24
24
20.o
20-o
50.o
50 .0
DLlution Factor: 1
Analyalg Time..: O5:00
wo# : HI(AA11AD-MS/HKaa1I-AE-MSD MS r,ot-Sample
37 - 6 rng/L 1-01- MeAliIIiI 350 . 1
37-A mg/T, 98 1.6 IvIeAww 350.1
Dtlutlon Faetor: 1
Analygie Tirne. . : O5 : oo
wO# : H,T1IP0LAR-MS/H,nIP0LRT-MSD MS Lot-Saq>Ie
76.4 mg/t i.05 MCAww 3zs -z
76 .L mg/r, 104 0.39 t4CAlIW 325.2
Pl.lutlon Factor: 1
Analyeis Time. . : 1O: 00
IWTE (S) :
Calculatlons Bro porforrned before roundlrry rc avoid round-off erors in celcutrttd results.
STL Denver 289
HLMIT BPIre SEUPIfi BITAI,TNTIOIY REPORT
G€nera1 Ctlenletry
Clieut rot *---: D5r020230
Date saqDl-cd--- = 09/oLlos 12:10 Date Received--= o9lo2/os
PERCENT RECO\IBRY
RECO1IERY LNI{ITS
RPD
PARAI"IETER RPD LTMITS IT{ETHOD
wo#:
130)
HirvQAICC-MS/H.nrQalCD-MSD It{S
130) O-31- (O-30)
DLlution Factor: 1
Aualyele Ttme. , : 1?: OO
MCAT{IiI 350.1
MCAI'III 35O.1
lrro#:
- 130)
HWQeIDP-MS/H.nrQ9IDQ-MSD MS
13O) 1.2 (O-30)
Dllution Factor: 1
Analyais Tima-. : 05:00
MCAWW 350.1
MCAI{W 350,1
wO# : HirtIQg 1-DK-lrts/x.nrQ91DL-MsD
11O) t'tCAt{I[ 325.2
110) ( 0- 10) MCATIW 325 .2
DLlution Fact,or: 1
Aualysla TIme-.: LO;OO
wo#:
107 )
HJ\IQ9 1DI,r-MS/HJUQ9 IDN-MSD MS
L07 ) 0,40 (O-10)
Dilution Fact,or: 1
Analyria Time-.: 11:3O
MCAWW 344.2
MCAWW 340 -2
WO# I
11e )
HJtIQe 1"DD-MS/HinrQg lDE-MSD MS
119) 1 ,7 (0-30)
Dilrrtion Factor: 1
Analyela Time-.: 16:OO
MCAI{!{ 353-2
MCAWW 353 - 2
wo*:
1s3 )
H.f\rQg 1DR- MSI /HWQ9 1DT - MSD
MeA[lm 375.4
MCATvW 375 _4
Dlatrfuc- . . o - - - - - : GIi[
PREPARATTON- PREP
AI{[A]-,YSIS DATE BATSH #
Lot-Sample # : DsI O2A23 0- OO2
a9 /2a/os 526s424
ae /zal os 525s424
Lot-sample # : D5IA2O230-004
ae /L4/ a5 s2s7378
ae /L4/ as s2s7378
Lot-Sample # : D5f02 A23O-004
0e / o8/os s2s22so
ae / 08 / a5 s2s 22sa
Armonia as N
Armonia aB N
Chloride
Fluoride
NC, DIIJ
NC, DIIJ
95
94
99
98
55N
55 N
LL? N
116 N
(++
QA
(+*
(++
(go
(go
(sz
(sz
(62
162
(*s
(ts
I-,ot-Samp1e #:
ae / oelos
oe/os/as
Dsro20230-004
5252s40
s25 2540
Nitrate-Nltrtte
99
98
Sulfate
98
98
Total Clanlde
Irot-Sample *:
oe /20 / as
oe/20/os
D5r020230-004
5265542
s26s542
MS I-,ot-Samp1e #: D5IA2O23O-004
09 / a6/a5 s249s86
a9 / a6 I as sz49s861-s3) o-02 (o-z]-t
oi].ut,Lon FacEor I I-
eaalyaie ?ime..: I.a:30
wo*: HwQgrou-Ms/$wQ91Dv-MsD M9 r,or-saq>le #: D5IO2O23O-004
(89 - 10e) sw845 goros/goreL 09/14-og/ts/os s257427
(eg - r-oe) 3.3 (0-20) swB4G 90108/eo12e, og/tq-09/Ls/os szs't422
Dilution Frctor: 1
Analysio Tl,me. , : L2 t30
rum(Q): _. _
Calculations are porformed bcforo rounding D avoid round+ff crrors in cslollf,red re$llq.
N Spiked snafnc recovery is outsidc statod control limirs.
NC The recovery and/or RPD wero nor calculatod,
DIL The conccntration is cmimated or not rryorted duo to dilution or lho pre$ence of interferiry rnalytcs.
STL Denver 290
Client rot #- - ,
Ilate Saq>I-ed- - -
IBTRTE SPIXG SAI,IPI,E DAIL REFORT
eenera-I Chemistry
D5r02 0230
A9 / 01/05 Lz t La Date Recelrred- - 3 09 / a2 / oS
Ilatrix- ? . - -. - - - 3 GIr
PREPARATION- PREP
ANAITYSIS DATq. , BATCTI #
oe/2a/os s25s424
ae /zo / os s26s424
PARAMETER
SA}IIPLE SPIKE
AMOUNT AIyfT
AnrnonLa as N
o.38 4.OO
o.38 4.OO
ME.ASRD
A}IOUMT {INITS
PERCNT
REC\IRY RPD METHOD
lvo#: HWQATCC-MS/IUVOAICD-MSD MS r.or-Saq)Ie *: Dsr020230-002
Ammonia aB N
0.45
0.45
Chlorlde
4 -L7 mg/T'
4 . L5 mg/T'
4.42 fftg/T'
4 .37 rfig /T'
2.95 N nrg/T,
2 .96 N mg/I'
25900 mg /T,
26000 ttq./T,
95 MCAWW 350.1
94 0.31 MeAlIr{ 350.1
99 MCAW9I 350.1
98 L.2 MCAIlnil 350.1
4.OO
4 .00
ss000 100
55000 100
0.15 5. O0
o.16 5.oo
4.OO
4_00
D{lution tractor: ]'
.laalyaie Tine. .: 17:00
wo#: HWQgrpp-Ms/HwQ91DQ-rvlIiD !i!S r,ot-Saml)]e #: Dsro2o23O-OO4
oe/L4/05
oe /L4 / os
5257378
5257378
Fluoride
PilutLon Factsor: 1
nnalyeLs Tlme..; 05:00
wo# : HiIVQg1-DK-MSlHirVQg1-DIr-Ir{SD MS Lot-Sample
NC,DIIr nq/L IICAWW 325-2
NC, DIIr tftg/T, MCAI{W 325 .2
Dl-lution Factor: 1
Analyeie Tl.me. . : L0 : 00
wo# : HWQ9LDM-MS/HWQ91.DN-MSID MS r,ot-Sanple
55 0 - 40 MCAWW 340.2
MCA?|W 34A .2
MCAWW 375.tL
0 . 02 MCAUII^I 315 - 4
#: Dsro2O230-004
ae / oglos s2s 22sa
oe / o8/0s s2s 22s0
o;,ii?,Zi'3'-Hil
09 / oe / as s2s2s4o
#: D5I020230-004
ae /za / as sz6ss42
ae /za/as s25ss42
#: DsIo2O230-004
oe / 06 / os s24es85
ae los / os s24e586
s6
Nitrate-Nitrl.te
ND
ND
Di}utrion Faetor: 1
Analysls Tl,mo. . : 11:3 O
vilo# : HJ1/Q91DD-MS/HWQ91DE-MSD MS Lor -Sarnple
3 .97 mg/T, 99 MCAww 353 . z
3 . 90 mg/r, 9g L.7 MCAww 353 - 2
Dllution Faetor: I
AnalysLe TLme..: 16:0O
wo# : IIJ\IQ91DR-MSIHJ\IQ91DT-MSD MS Lot-SampleSulfate
14 000 12500
111o00 1_2500
Total Qyanide
0, 0059 0. 100
o.o05g 0,L00
NCnts(S):
98
98
ullutLoa FasEor: 1
.analyaie Time., : 1{:30
wo#: HdrI/Qg1DU-MS/HWQ91DV-!,fi'D MS Lot-Saq)le #: D5I020230-004
0.118 ru mg/r, LLz sws46 ga:-or/g og/t+-og/rslos s2s7427
0.L22 N mglr, 116 3.3 swg46 gotos/g o9/L4-o9/rslos s2s7427
DilutloE tractor: 1
Analysis Time.. : 72230
Crlcul*iolB arc pcrformod bofore rounding to avoid round+ff error3 in calcutatcxl rcsul6.
N Spikod analyre recovory is outside starcd comrol IImiB.
NC The re@vcry and/or RPD woro not calcrrlatcd.
DIL The cooccrltrrtion is estlmated or not reporlcd due to dilution or thc prcscnce of inrerfering analyrcs.
STL Denver 297
Ctrl.ent I6t *- - -:
Ilate Saqll.ed---!
PAIU\M RESUIIT
STAUPI,E DT'PLTCAIE ffi RMORT
General. Chenistry
D5I02 023 0 Hork Order *- - -: HJ1IQ9-SMP
HII{IQ9-DUP
as / oL/ os 12: 10 Date Receirred- - : 09 / a2/ as
DUPLICATE RPD
RESTILT UNITS RPD IJfMfT l,IErTIg-q
PRBPARJtrTTON_
ANAI-'YSIS DATE
PREP
BATCH #
pH
8.8 8,8
gD Lot-sample # t
No unit,s o.o (o-5,0) swg+o 9o4oB
DllutLon Factor: 1 Analyele Tlme. .: 13:40
Dsra20230-004
oe/a2/os 524ss45
STL Denver 292
r^ot r, ?5:W)Q0J,.?0-
CompanyName & Sampling Site:-U
STL Denver
Sarnple Receiving Checklist
Datc/Time Received:
PM to Complete This Section: Ies
Rcsidrnl chlorirre chcck requircd:tr
No
-B Quaranlined :
7'es NoDB
Quotc #:
Special Inrrmctions:
q'7o qg
Time Zonc:
. EDT/EST . CDT/CST . MDl'/l\4ST' PL)T/PST . OTIIEB
Unpacking Checks:
Coolcr#(s): -V s_
?-3 -z
L-LT <-L
>
, ('.tr_
t,
Z-s
.s
T;urpcratres("C): ? .i
o8.
tr 9.
u t0,
{,,
tr 12.
0tl
u 14.
tr {rt.
.{ rt 16.
D{n
STL Denver
N/A Yes No
tr f D t.
,w D 2.
u {t
D {4.
rD-i-DFr6.
FD7
:$
tr
t;tr.tr
Cool=r seals intaa? [N/A jfhand de]ivered) If no, doctrmsDt on CIfR-
Chain oi'custody presgnt? If no, doaun=nt on C'IJR.
Bottlcs brokeu and/or are leaking? If yes, d,ocurneDt on C[-IR
Multiphasic sarryies obvior.rs? U Yes, docunrcut on CLIR.
Prop=i containsr & prcservatives used? (r"f. Atrachment D of SOH DEN-QA-0003)
plI of all sarryles cbcclled and mee'|. requiroments? Hno, doeumcxrt on CLIR-
If no, docr:m;ut on C[IR.
Suficieut voluure provided for all analysis rrqucsted? (ref- Auachnem D of SOP# DEN-QA-0003) if no,
docrprent on CIJR, aud contacl-P-M before proce*diag.
Did chaiu of custodl,agree with labcls iD and samples rcceived? Uno, docrrcat on CUR-
Wcrc VOA saryles without bcarispace? Ifno, doament on CLIR-
Were VOA vials preserved? ?rcservariv7ddL} -.14*2"C Dsodium Thiosulfate S.Ascorbic Acjd
Did sarplcs requir prcscrvation wi& sodirm thiosulfate?
If yes to #11, riid the saryles contain rrsidual cilorine? If yes, docrmsDt on CUR.
Sdtm,,utptessttiu disolvedlil'ctnd bottlesl Hyls, docuuenl or CIJR-
Is suffrcicnl voiunre provided for cljcni. regucstcd MS, MSD or matrix duplicates? If no, docrrment on CUX, and
coDtacl PIvl bcfore proc*ding.
Rcceipt datelsl > 48 horus pas the collection date(s)? If yes, uotifl PAIPM.
Arc analyses with short holding times reguested?
Was a quich Tun Arormd [IAT) requested?
293
STL Denver
Sample Receiving Checklist
fI
E
il
D
O
Lab Jnitials
.]'I\--4,r1-
_-4uLl
0
dr
,'{Sr
:fiLr
;5II
Login Checks;
NlA )'es No
t{
rt
,t
o
rt
n
P
D
tr
,6 D 18. Suflicient volume provid ed {or all analysis rcgucsted? (ref. Anaclunent D of SOP# DEN-QA-0003)
doormcnl on CUR, arrd conlacl PI4 bcforc procecdirrg.
tr 19- Is nrfficicnl volume provided for client reguested h4S, MSD or matrix duplicatcs? lf no, documcnt on CUR, aud
contrct PM bcfore proceeding
O 20- Did the chain of custofi,includcs "received blr'arrd "relirrguished" by sig'naturcs, dates, and timas?
tr ? l . Were special log in instructions rcad and followcd?
fl 22. Were AI'CEE mctals loggcd for rcfiigcraled storage? I
tr 23. Wcrc tc.srs Iogged checked agains the COC? Which samplcs u'crc confimrd? |
tl 24. \Vas a Ru*r frrrn complclcd for quict TAT?
tl 25. \\rara ShortHoldform complcled foranyehortholds?
,{ zs- Is "Sria ICoc-required?
A 27- Wcrc special archiving instructions indicated in tlrc Genaral Comments? lf so, uibal were the;4
eliog and Storage Checks:
I 28. Was the subcontracl COC sigrred and rcnt wid: sanples to bottle prcp?
! 29. Were sanplelabels doublc-checlr^-d by a sccond parson?
:l 30. Were sryIe bottl--s aod COC doublc cbckrd firr dissolrrd/fillr:red motals by a second person?
D 3I. Did thc sarrple ID, Date, aud lime fioro lahel match utral uas loged?
X 32. Were sticliers for special archiving instructions affixed to each box arri to the ICOC? Sce #2?
D 33. Were AFCEErmtals stored refrigerated'i
tr 34. Were "Striu ICOC" copies givca to sat^Jlite storage areas'/
Documenl anyproblems or discrcpancies and thr aclions taken to resoh,e them on a Condition llpon Receipl "F,nomal1'
Reporl (CIJR).
STL Denver 294
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STL D,enver
4955 Yarrow Street
Arvada, CO 80002
Tel: [phone]
www.stl-inc.com
STL
303 431 7L7t
AIYALYTICAL REPORT
Western Zirconium Project
Lot#: D5Il00l53
Sheri O'Connor
URS Corporation
8181 East Tufts Avenuo,
Denver, CO 80237
STLDENVER
Linda L. Benkers
Project Manager
October 5, 2005
Severn Trent Laboratories, lnc.
Table Of Contents
Standard Dellverables wtth Supporting Documentation
Report Contents
Sf,andard Deliverables
(fnt Cover Lener and the Report Cover page are considered integral
parts of this Standard Deliverable pacfuge. This report is incomplete
unless all pages indleated in this Table of Contents are included.)
o Table of Contents. Case Naruative
. Executive Summary - Detection llightights
r Methods Summary
. Method/Analyst Surnmary
o Lot Sample Summary
r Analytical Results
. QC Data Assoctntlon Surnmaryo QC Sarnple Results
. Chatn-of-Custody
Number of Pages
S upporti ng Docu mentatl on
Check below when
supportlng
documentaflon ls
present.
(Note: A anc-page "Descrlptlon of Supportlng Documentation" is
provided at the beginning af thls section.).
r Volrtlle GC/IVIS
I Semivolatile GC/MS
. Volatlle GC
. Semivolntlle GC
' LCIIVIS or IIPLC
o Metnls
r General Chemistry
r Radiochemistry
r Subcontracted Dnta
Enn
O
SfL Denver
Case Narrative
Dsr100153
With exceptions noted as flags or footnotes, standard analytical protoools were followed in the
analysis of the samples and no problems were encounte,red or anomalies observed. All laboratory
quality conhol samples arulyzed in conjunction with the samples in this project were within
established control limits, with any exceptions noted.
The test results presented in this report meet all roquirerrents of NELAC, and any exceptions are
noted. This report shall not be reproduced, except in full, without writte,n permission from the
laboratory.
Sample Receiving
Eight samples were received under chain of orstody on Septemrber 10, 2005. The samples were
received in good condition at temperatures of2.3oC, 4.0oC, 4-9"C,4.9oC, 2.2oC, and 4.7"C.
Please note that the samples subrnitted for 82608 analyses require reporting of Chloroform only
as per client request.
Sample aliquots for all radiological anallnes are logged in under a separate lot and were se, t to
STL St. Inuis; 13715 RiderTrail North; Earth City; MO 63045, phone [phone].
GC/lvIS Volrtiles, SW846 82608
Samples D5Il00l53-001 through 008 requesting chloroform only were batched with samples
from another client and/or lot requesting fuIl list compounds for 82608. Therefore the method
blank associated with batch 5265406 contains full list compounds.
The MS/Ir{SD associated with batch 52654A6 was performed on sample D5I100153-003 and was
in conhol-
No anomalies were observed.
Total Metals, SWM6 60108,6020 & 7470A
Samples D5I100153-002 through 006 were analyzed at dilutions for several metals by methods
60108 and/or 6020 due to matrix interference and/or higfr target compound concentrations. The
reporting limits are adjusted accordingly.
Sample DsIl00l53-005 demonstrated matix interference with no dilution requird for lead. The
sarnple disptayea a ne6ative readin6 yeater than the.Torti"6limit for lead. The reporting limit
is adjusted accordingly and associated data is flagged "G".
The method 60108 MS/I{SD associated with batch 5265222 was performed on sample
D5I100153-003 and was in conhol. The recoveries for sodium are not calculated because the
sample amount was greater than four times the spike amount.
STL Denver
The method 747AA MS/}vISD associated with batch 5266336 was performed on sample
D5I100153-003 and was in conffol for mercury.
The method 6020 MS/tr{SD associated rvith batch 5265180 was performed on sample
D5II00l53-003 and was in control.
Serial dilution of a digestate in analytical batch 5265222 performed on sample D5I100153-003
indicates that physical and chefirical interferences are present for calcium. The associated data are
flagged "L".
No other anomalies were observed.
General Chemistry, Various Methods
Saurple.s D5II00I53-002 through 006 and 008 were amlyzd at dilutions for several compounds
due to higfo analyte concentrations. The reporting limits are adjusted accordingly and the
associated data is flagged "Q".
Chloride, fluoridq and sulfate were detected in the method blanks at concentrations below the
reporting limits, but above the method detection limits. Associated positive sample results are
flagged "J".
The MS/]vISD performed on sample D5Il00l53-003 was in control for ammonia and nitrate
nirate.
The MSIvISD performed on sample D5I100153-003 demonstrated recoveries above the control
limit for ctrloride- The MSD dernonstrated a recovery above the oontnol limit for fluoride. Also,
the MS/IvISD demonstrated recoveries bclow the control limits for sulfate and cyanide and the
relative percent difference (RPD) was above the control limit for cyanide.
All other MS/}VISD samples were performed on samples from other clients and/or lots and some
were not in control.
The pH duplicate performed on a sample from another client and/or lot was in oonhol.
No other anomalies were observed-
STL Denver
W-Iletection@
Dsr100153
RESUL:r
REPORTING
ITIMIT UNITS
ATiIALYTTCAI.,
METTIODPARAMETER
Glr-rrgl.- ogo9os og I og I os o8 : oo oo2
Arsenic
Barium
NickeI
Zinc
Calcium
Iron
Pot.assitrrn
Maganeelum
Sodlum
Zlrcontum
Chlorlde
Fluoride
NLtrratre
Niurate-Nitrite
pH
Sulfate
amrnonia as N
Grr-il1-o90905 09l09los o9:25 003
Areenlc
Barium
Copper
NickeI
ZLn.c
Calcium
Iron
Potaeeiurrr
l'lagrneeiunt
Sodium
Zirconium
Ch].oride
Fluoride
NLt.rate
Nitrate -NitrLte
Tota1 CyanJ-de
pH
Sulfate
Ammonia aa N
0.012 B
0.20
o.0027 B
0.018 B
1L0 tr
0. r_9
7L
a2
170 0
0.0051 B
22AA J, Q
L.2 ir
0,11
o.11
7 .4
120 J, Q
o.76
o. o15
o - 21
0.020
o. oazl B
0.015 B
110 L
0.20
72
84
1700
0. 0058 B
2240 J, Q
L.2 ir
o. L7
0.18
0.056
7.4
350 J,Q
0.75
0.015
0.0L0
0.040
0. 020
o.20
0.L0
3.O
0.20
5.0
0,015
250
0. Lo
o. r0
0.10
0.10
25
0,10
0.015
0-010
o. o10
0,040
0. 020
0.20
0.10
3-0
o .24
5,0
0 .015
25A
0.10
0.10
0.Lo
0,010
0.10
50
0.10
mg/T,
mg/r,
mg/r-'
mg/T'
ng /l'
nrg/T-,
ng lr,
m9/L
mg/T"
ng,/L
rf,rtg/L
mg /t'
mg/I'
mg/T'
No Units
rftg /T,
mg /r,
ntg /r,
nrg/r,
$g/r,
mg/r"
mg/r,
mg/t,
mg/L
m9/t
ng/r'
mg/r'
mg/r,
ntg /r,
mg/r,
mg/r,
rftg / T'
mg/L
No UniUs
mg/t'
ms/t
sw84 5
9w845
sw846
sw845
sw846
sw845
sw846
9w845
9w845
sw846
I.[CAI{W-
MCAWW
MCAWW
MCAT{W
sw846
MCAWW
D4eAWlt
60 108
5 0r.08
60108
5 010B
60L08
6 0108
50108
60108
60108
50108
325.2
340 -2
353 .2
353 .2
904 0B
375 .4
350.1
sw846 601-oB
sw845 50108
sw845 60108
9w846 60108
svr845 50L08
sw845 50108
sw846 50108
sw846 50108
sw846 50L08
sw846 60108
s9il84 5 5 0L08
MCAWW' 325.2
MCAWW 340.2
MCAWW 353.2
MCAWW 353.2
sw846 90L AB/ 9012A
sw846 904 0B
MeAIrl!{ 375 .4
MCAI{W 350.1
STL Denver
(Continued on next page)
EXECIITIIIE -I}etectionlfighlig[ts
D5I100153
RESIIIJT
REPOR?TNG
IJIMIT UNITS
AIilAfrnICAL
MHTHODPARAMETER
Gn-sB-oeoeos ogloglos oe:35 oo{
Selenium
Areenic
Barium
Nl,elceI
CalcLum
Potaeelum
Magrresium
Sodium
Zirconl-um
Chlorl-de
Fluorlde
Nitrate
Nitrate-Nitrite
pH
Sulfate
Ammonl-a aE N
Cadrnium
gelenLum
Alumlnum
Areenlc
BarLum
Nl-ckeI
Vanadium
zLnc
Calcium
Iron
Potassiunr
Magrreslum
9od.lum
Chloroform
Chloride
Fluoride
Nitrate
Nltrate*Nitrl-te
pH
Sulfate
Anrnonia as N
GIf-sD-OeOgOs O9l A9l OS r-O:45 OO5
0.00076 B
0.0078 B
0. oL8 B
0,0088 B
0 .25
o-0058 B
o. oo29 B
0.0062 B
540 L
0.048 B
390
340
s 100
A .47 .f
11000 J, Q
o.73 J
80
800
7 -5
33O0 JrQ
670
0,0092 B
0.010 B
o.L7
o. oozL B
25O IJ
810
400
I 900
o. o1g B
19O0O J, Q
0.80 'J
33
340
7.9
1700 J,0
2200 0
tr.g/L
mg /T'
rng /T'
rng /r,
wg/t
n.g,/t'
mg/r'
mg /T'
mg/T'
mg/T,
rrE/L,
rng /r,
rrq,/L
vg /T'
mg /I'
nq /l'
nrg /T,
nlq./T,
No UnLts
firg /T'
nrg /T'
mg/r,
ry/r,
Ifl'frg/L
mg/r,
mg/r'
mg/t'
mg/r,
mg/r,
mg/1,
mg /r,
mg/t'
mg/t
nq /r'
No Units
ngh'
mg/L
sw846 6020
sw845 6020
sw8{6 50L08
sw846 601-08
svrr845 50108
9ril846 5 0108
sw846 50108
svtS{5 60108
9w846 50108
sw846 50108
sw845 50108
sw845 60108
sw846 50108
5111846 826 0B
MCAWI{ 325.2
MCAIi[f 340 .2
MCAV|IW 353 .2
MCAWW 353 -2
sri[845 90408
I'ICAWI{ 375 ,4
MCAT{TW 35O.1
sw845 5A2A
svt845 501.08
sri[845 60108
sw845 60108
sw846 60108
sw845 50108
9w84 5 6 0108
sw845 60108
sr{846 60108
lrIeAI{w 325.2
MCAWW 340.2
MCAWW 353 .2
MCAIrnil 353.2
sw846 9040B
MeAlt!*I 375 .4
MCAWW 350,L
0.010
0-020
o. 10
0,015
0.010
o. 040
0.010
0. 020
0 ,20
0.10
3.0
0.20
5.0
1.0
250
0.Lo
2,5
2-5
o-10
s00
2.5
o-040
0. 01,5
0-010
o.040
2.A
30
2.0
s0
o.15
1200
0.10
o.10
1_-0
o. l-o
s00
L00
STL Denver
(Continued on next page)
EXIUWW-I}etectionW
D5r1001-53
RESU[,T
REPORTING
LIMIT TINITS
AIIAITYTf CAIT
METHODPAR..AMETER
w-s6- o9090s o9l 09 I os 1L :55 006
SelenLum
Areenic
Bartum
ZLn.c
Calcium
fron
PotaesLurn
Magnesiurn
Eodium
Zlrconium
Chloride
Fluoride
Nitrate
ttitrate -r.Tl-trlte
pH
Sulfate
Amrnonia as N
Gr-7e-oeo9os oelaelas L2z2o oo8
0,015 B
0 .015
0,097
0.0045 B
86 IJ
0-50 B
240
294
1-0 000
a.027 B
150O0 J, Q
O -76 ,J
a .L2
o -L2
8.2
2700 J, Q
5.0
o.0001,2 B
0.00039 B
0. 12
o.24
o-011
0.0023 B
0,017 B
L"l IJ
0.32
48
t_L
280
0.0029 B
4+O .J, Q
0-77 J
0.35
0.35
8.1
3.1 BrJ
4.3
0.040
0.015
0,010
0.020
2.O
1.0
30
2-O
s0
0 .15
250
0-l-o
0 .10
0.Lo
0.10
12 00
0. J.0
0.0010
0 . 0020
0. L0
0.010
o-010
0,040
0.020
0.20
0 - 10
3.0
o -24
5.0
0.015
L2
0.10
0.10
o.10
o. 10
5,0
0.10
vrg/t
rc.g,/T,
nrg/r,
mg/t'
rftg /r'
W/T,
mg/t'
fftg /T"
r*g /r,
ng,/t
mg/t'
rng lT,
ntg /T'
ng/t
No Units
nrg /t'
mg/T'
mg/T'
mg/T'
mg/T'
mg/r,
rry/t
nrg/r,
rrg, /T,
nq./T'
nrg/T,
mg/l'
mg/T'
rJtg /r'
mg/T.'
mg/t'
ms/r,
mg /T'
mg/n
No Unlts
nrg/r
rw/t
9w845 6020
sw846 50108
sw846 50108
sw845 50108
sw845 50108
sw846 60108
sw846 50108
su[845 50L08
svr846 5010B
sw845 50L08
MCAVIW 325.2
MeAUnrI 344.2
MCAT{W 353 ,2
MCATVW 353 .2
sw846 90408
MCAlrnV 375 .4
MCA!{W 350.1
sw845 6024
sr{846 6020
sw845 60L08
sw845 50108
sw845 5010B
sw846 60L0B
sw846 50108
sw846 6 0108
sw84 6 6 0108
SIrI84 5 5 0108
svr845 50108
sw845 5 0108
sw845 60108
MCAI{Iil 325 .2
MCAWW 340.2
MCAhIII 353 .2
IvICAY{W 353,2
sw845 90408
MCAVII{ 375,4
MCAVII{ 350.1
Cadmlum
geIenl-um
Alumlnum
garLum
Copper
Nickel
Zinc
Calcium
Iron
Potassium
Ivlagnesium
Sodium
Zirconlum
Chloride
Fluoride
Nitrate
Nit,rate-Nitrite
pH
Sulfate
Ammonia as N
STL Denver
METIIODSW
D51100r,53
PARiAIvIETER
AI{IALYTTEAL
ITIETHOD
PREPARATION
METHOD
pH Aqueoue
Chlorlde (colorimetrlc, AuEomated Ferricyanide)
Fluoride (potentiometric, fon SelectLve Electrode)
Inductively Coupled Plasma (Iep) Meta1s
ICP-MS (6020}
Mercury in l-,1-quid Waste (Manua1 Co1d-vapor)
Nitrate
Nitrate-luitrite
Nit,rogen, Arrunonia
Sulfate
ToEal cyanide
Trace InducE,ively Coupled P1.asnla ( feP) Meta1s
Vo1atlle Organics by GC/MS
References:
MCA![I{
sw845
sw845 90408
MCAWW 32s -2
MCAWW 340.2
sTrI845 50108
sw846 5020
sw846 7474A-
MCAWW 353,2
MeAlrw 353.2
MCAWW 350.1
MCAI{W 3 75 .4
sw845 e01aB/ 90L
sw846 50108
sw846 82608
9w845 90408
MCAI{I{ 325 .2
N[CAT{I{ 34O ,2
9w846 3010A
9w846 30204
sw846 7470A
MCATilW 353.2
MeArilw 353.2
MCA9[I{ 350.1
MCAWW 375.4
sw84 5 90L08
gw84 5 3 010A
sw846 503 OB/ 826
"Methoda for Chemical Analyeis of WaEer and l{aeEee",
spa-eoO/+-'t9-o2o, March 1983 ard subsequeot revislons.
'Test Methode for Evaluatlng So1l.d WaBte, Pbyeicat/chemlcal
Methodsr, Itrlrd Edition, November 1985 and lt6 updates.
STL Denver
AI{IALNICAL
METHOD
METHOI}/ANALYS:TW
D5I100153
AI{AIJYST
MCAWI{ 325.2
MCJLT{W 34O .2
MCAWW 350.1
MCAI{W 353,2
MCAWW 375.4
sr{846 60108
sw845 60108
gw8{5 5020
sw846 5020
9w846 7470A
9w846 82608
slr845 9010P/ 90L2A
sw84 5 904 0B
Refererlceg:
MCAWW
sw84 5
Claire Likar
Fougere M. Danielle
Clalre Likar
Clalre Llkar
Dusti o. crtqut
lTanel Motlchka
Llmn*Anne Tr:udell
Thomas Irill
Thomas I-,i11
,Ianice s. CollLne
Heather Deepree
Dusti o. Criqui
Fougere M. Danielle
A}IAIJYgT
ID
004382
006481-
0 04 382
004382
005589
0 02 862
0055{5
o06 929
6929
011668
0 092so
0 0658 9
006481
trMethods for Chemical ArralysLe of $Iater and Wastes",
EPA-500/4-79-020, t&arch 1983 and subeequenL revislone.
lTeEt Methods for EvaluatLug Solld Waste, Physical/Chemical
Methoden, Tlrird Edition, November 1986 and its utrrdatee.
STL Denver
sffiw
D5rr-oo153
wo#SAIVIPLE# CIIEIIT SAII{PLE ID
SAMPIJED SAII{P
DA?E TTME
HKAR4
HKART
HKAR9
HKATC
HKAID
HKATE
HKATG
HKATJ
lwfB (s) :
001 TB-O90905
AOZ GW-N91-O9O90s\ -003 cr{-N1-0e0905 )r0
004 cw-58- 0909 05
o05 Gw-5D-09090s
o06 GTr-s6-09090s
oa7 EB-090905
o08 Gw-7e- o90905
ae/oe/os
a9/oe/os o8:oo
09/09/os 09:.25
oe/ae/as 0e:35
09/oe/as 1o:45
09/oe/as 11:55
oe / 09/ as L2:25
oe / oe / os L2:20
- fho enalytiel rcsults cf rhc ompl6 ll$€d rboyc arc prrembd on O16 folbwing prgca.
-.All calculatlong are pcrformsd bcforc rounding ro evoid round-ofi crrors in calorlarcd rcarlB.
- R€otlrs mrcd at 'ND' wcfe mt dct ct€d rt or ebova rhe saed linit.
- Thfu rtpon mu$ not be roproducad, cxcopt in fuil. wilhort thc wriuen rppmval of thc hboratory.
- Rcsults for tho foltowing prremctcrs uc nerrer rc?ortcd on a dry weight besrs: color. conosivity, darsity, n$hpoir, lgnlnbility, laycs, odor,
pal,tr frlter t.st. pH. potosity prcssrc. rEactiyity, rcdo[ potcntlal, splcltie Brsvaty. rpot tc.sa, olids, sohrbility, tcopa'ature, visoosity, .rd wolSDG
STL Denver
URA Corporation
C1ient Sanp1e ID: AB-O9O9O5
se/Es vol.atil.ee
Iot-gaqll.e S- - -:
Ilate Saqtl-ed---i
Prep fiateo---.,3
kep Batch #- - -:
Dil.utiou, Faetor:
Dsrl00153-00L
oe/ae/os
ae /2L/ os
526s4 06
1
Hork Order f..-:
Date Receirred. - E
anal.yele llate. , 3
nnalyeis Tlme- -:
ltethod
RESTII,T
ND
PERCENT
RECO\TERY
92
80
93
1-O9
HI(AR41AC
ae/Lo/os
ae / 2L/ 0s
09:14
sw846 82508
REPORTING
IJIJ-IIT IlIil-ITS
tfaf,a'i"r- o o o - - - . .3 WQ
PARAMETER
Chloroform
ST}RROGATE
1. o ug/n
RECO\IERY
TIMTTS
(tz 118 )
(62 - 128 )
fia 118 )(zz LLTI
D1bromofluoromethane
L, 2- DLchloroethane- d4
4 -Bromofluorobenzene
Toluene-dB
STL Denver 10
IrRS Corporation
client sanprF rD: gr-I591-o9o9o5
@lW vol-atilee
PARAMETER
Iot*Saryfie ft- -.:
Ilate Sary)I-ed---!
kep Datg- r,, - - 3
PreB Batell *- . - E
ni]-utim Factor:
D51100L53 - O02
oe/oe/as o8:oo
oe/2t/os
5265{tO6
L
I5ork. Order *- - - 3
Date Reeelrred- - :
Analyeie Date. - 3
Ana-lygl-s Tlme. - !
Itethod
RESI,IJT
ND
PERCENT
RECO\IERY
94
90
93
104
HI(AR?1A9
ae/Lo/as
ae l2L/ as
O9:33
sw845 82508
REPOR?TNCI
LIMTT I'NITS
1.0 ug/L
RECO\IERY
LTMTTg
(7s L18 )(sz 128)(ta 118 )(tz LLz't
Iriatri:r- ] - - o . - - - i GT{
Chloroform
gTIRROGATE
D Lb rornof 1uc>rome t hane
L, 2- Dl-chloroethane - d4
4 -Bromofluorobenzene
?oluene-d8
STL Denver 11
Lot-Saryll-e *. - -:Ilate Sary)}ed---!
Prep Date.,----3
Prqp BatcIr *- - - :
DLl.utlon Factor:
tlRS Corporation
C1ient Saryl1e ID: GII-I[1-O9O9O5
Gc.lt{'8 vol.atil-es
Hork Order *- -.3 HI(AR91D0
Ilate Received--3 a9 lL0/A5
lnalyris Date- . r a9 / 2L/ Os
Analyeie Ti-ue- . 3 09 : 53
l{atri:r. - - - D - - } ! : Gh[DsrL001.53 -003
ae/oe/os oe:25
ae / 2L/ os
5265406
1
I[gthod- - - ., - . . . ! SW846 82508
PARAMETER RESI ITT
REPORTING
LfMfT UNfTS
Chloroform
SIIRROG}ATE
ND
PERCEMT
RECOVERY
1. O rug/L
RECO\IERY
IJIMITS
(73 L18 )(sz 128)
(zs 118)
(zt 1r- 7 )
Dibromof luoromethane
L, 2- Dlch1 oroethane - d4
4 -Bromofluorobenzene
Toluene-d8
94
87
94
10s
STL Denver 1-2
IIRS Corporatioa
Cl.iemt Saryile D: GT-58-09O9O5
etcfii$ vol-atiles
o
Iot-Saq)Ie *- -.3
Dat,e Saq)I.ed-.-3
Pr:ep Ilate- - - - - -:
kep Bateh *- - - 3
Dil.ution Factor:
Dsr100153 - 004
09/ae/as o9:35
oe/2t/as
526s406
].
Hork Order #- -. !
Ilate Recelrred,- - i
Ana-lyaLe llate- - l
anallrel-e TLre- - 3
Ugthod.---.----l
REgUIJT
o -47 ;r
PERCEI\IT
RECO\IERY
96
89
94
103
HKATCIAS
ae/Lo/os
ae/2L/as
10:50
sw845 82508
REPORTING
I,IMIT IINITS
Hatri:x---.-.--.3 GW
PARAMHTER
Chf.oroform
STIRROGATE
t - O urgl[,
REEOVIERY
I,IMITS
(tt 118 )
$z 128 )
( za 1r.8 )(zz t-17 )
D ib romo f I uo romettrane
L, Z-Dichloroethane - d4
4 -Bromofluorobenzene
Toluene-d8
rsctB (s) :
t Esdntsrcd resrlt. Resrh is lcss tran RL.
STL Denver 13
IIRS Corporation
Cl.lent garylle ID: GII-5D-O9O9O5
Gc/t{s vol.atl-Iee
Iot-Saryr1e *---:
Date Saryiled.--3
Prep llate, , , - - - l
Prep Bateh *. - -:
Dil.utsLon Factor:
Dsr1001s3 - 00s
ae l09 / os I-o :45
oe / 2L/ os
s26s4 0 5
1
work Order *-. .:
Ilate Received. - !
aualysis Date- - :
euallrais Ti-Ee. - 3
llgthod---------3
RESTJIJT
ND
PERCEIIT
RECOVERY
95
91
91
99
HKATDlAs
oe/Lo/os
09 / 21,/ Os
11.: t0
sw846 82508
REPORTING
IrfMIf UNfTS
rratrix--!!,-.-.: GW
PARAMHTER
Chloroform
SIIRROGATE
1.0 lrg/L
RECO\IERY
IJIITIITS(zs 1-18)
(62 128 )(ze 118)
(zt LL7 |
D ibrorno f I uo rome L hane
L, Z-Dich1-oroethane - d4
4 -Bromofluorobenzene
Toluene-dB
STL Denver 1,4
URg @rporation
Clleut Saryfle ID: GII-S5-O9o9os
@clu'6 vol.ati1eg
I.ot-Bary>Ie *- - -:
Date Saryl1ed.---3
Prep llate------3
fep Batch *. - - l
DihrtLon Factor:
D5r100153-OO5
aelae/as 1L:55
oelza/os
52654 06
1
Work Order *- - -:
Date Recelved- - !
analysis llate- - 3
nna-lyel-e Ttme-. 3
HethOdtr-a?---..!
RESTII,T
ND
PERCEMT
RECO\IERY
100
95
95
1_0 0
HKATElAS
ae / 1olos
ae/2L/os
LL:29
sw846 82508
R^BPORTTNCI
I,IMTT UNITS
Dratri:r,,, -.----i Gw
PARAMETER
Chloroforrn
STTRROGATE
1 . O rJg/T.
REEO\TERY
LIMITg
(tt r.18 )
Gz 128 )
(78 118 )(zt LrTl
D ibrorno f I uorome t trane
L, 2- Dichloroethane - d{
4 -Bromofluorobenzene
toluene-dB
STL Denver
IIRS Corporatl-on
Clieut Saryr1e ID: EB-O9O9O5
rc,lug vol-atLres
Iot-BarryIe *. - - 3
Date Sary)I.ed-. - r
Prep Datg,,----3
Prep Batr& *-. - i
Dil-ution Factor:
Ds1100153 -007
09 / oe / os t2:25
oe / zll as
s26s4 05
1
Ilork Oder *- - -:
Date Receirred.- - l
Analyeie llate- - 3
Anal-yel-e flme- - 3
Ugthod---------l
RESULT
ND
PERCENT
RECO\IERY
98
93
93
L03
HI(ATC}1AA
ae / 1olos
oe /2t/ as
11:48
sw845 82608
REPORTING
LTMTT UNITS
Itatrl-x,: Elt
PARJAIT{EIIER
Ch]-oroform
SIIRROGATE
1- 0 :ug/T"
RECO\IERY
I,IMITS
(zs t i.B)
(sz 128 )
0e 118)
(tt 1L7)
D i-Ic romo f I uo romethane
L, Z-Dichloroethane- d4
4 -Bromofluorobenzene
Toluene-dB
STL Denver 76
IIRA Corporation
C1imt Saq)Ie E): Gf-7e-O9O9O5
rc/frg Volatiles
Iot-8aryl1e f -. -:
Date Saqfled---3
Prrcp Datg------!
fep Batch f---:
Dl'lution. Eactor:
Ds11001s3 - 008
09 / a9 / os 12:2o
ae/2L/05
52554 06
1
Ilork Order *. - -:
Date Receirred- - l
Anal-ygig Date- - r
enrlysis Tlme- - 3
Hcthod-----.---!
RESIII-,7
ND
PERCENT
RECOVERY
94
90
93
103
I{KAT,JlAB
ae/La/as
oe / zL/ os
t2:07
sw845 82508
REPORTING
LfMIf UNfTS
llatrix----,,..-: GW
PARAMETER
Chloroform
gURROGATE
1 , 0 wg/I'
RECO\IERY
LItIITS
(tt 118)
(sz 128 )(zs 118)
(tt 117 )
D ibromo f I uorome tha.ne
L, 2- DLchloroetlrane - d4
4 -Bromofluorobenzene
Toluene-dB
STL Denver 1-7
Iot-garyll-e #. . -:
Ilate Bary)Ied.---!
PARAMETER
URg Cortoration
e1ient saqfle ID: Gn-r59L-O9O9O5
ITCIDAI, lletar s
Dsr1001s3 -ao2
09/09/05 08:00 llate Received--3 09/Lo/as
RESI]IJT
REPORTING
LIMIT ITNITS METHOD
I.latri:c--..-3 GW
PREPARATION- WORK
AI{AIJYSIS DATE ORDER #
frrep Batch
Cadmium
Selenium
Prep Batch
Silwer
Alumlnum
Arsenie
Barium
Cla-}.cirm
Chromium
Copper
*---: 5255180
ND
S-. - 3 5265222
ND
}UD
o-or-2 B
o-20
110 L
ND
tlD
o_19
7L
82
1700
O . OO50 mg/I'
Dilutlm Factor: 5
0 - 010 mg/t'
Dilution Factor: 5
sw845 5020
Analysle TLme.-: O4:18
sw846 5020
Analyais Tlme. . : 04 :18
9w846 50108
Analyeie ?ins- . : 12: O3
sw845 50108
Analygls TIme..: 20:19
slw8t6 50108
Analygla Time..: 12:03
s'1I845 60108
nualygla Tlme..: 12:03
grr845 50108
Analyeie Ti.ure. . : 20: 19
9w846 60108
Analysle TLme.-: 12:03
sw84 6 6 0108
analysls Tl-me. . ; 12: O3
s'H8{6 50LOB
Analyals Tl-me. - : 20: 19
srrS{6 50108
Analyale Tlme..: 20:19
9H845 50LOB
Inalyaie Tino..: 20:19
sr845 50L08
Analyals Tl-me. . : 20: 19
next page)
a9 /23 -o e / 27 / os HI(AR71A4
oe / 23 -o 9 / 27 / os HI(AR71As
oe /23 -o e / 27 / os HKARTIArI
09 / 23 - o 9 / zs / os HKARTle*r
0-010
Dilution
0-10
Dllutlon
o-o15
tlilutlon
o-o10
Dil-ution
a -20
Dllution
0.010
DlluLl.on
0.010
oilutlon
o-10
Dilut,lou
3-O
Dllutiou
o. ?0
DLlutLon
ng/t
Eactror: 1
nlg /T'
Factor: L
rylr"
Factor: 1
ug,lt'
FacEor: 1
uglt
Faetor: 1
mg /r'
Factor: 1
mg/r'
Factor: L
rylt'
Factor: 1
ryIlt,
FacLor: 1
rylr,
Factor: 1
aelzs-oelzt los
oe l23 -oe 127 | as
oelzJ-oe lzol os
ae/zt-oe/zt/os
ae/23-oe/27/as
oe /23-oe lZa I os
aelz3-oe[20./os
oel23-oe lze / os
HKARTIAf,
HMRTLAL
EITARTUA\I
HKART1.AI{
HKARTLAIV
HKARITljAJf
IIKARTLAX
EKARTILO
Potagel-rn
I{agneeirm
Sodirm 5-o ryll,
Dll-utlon F'actor: 1
(Continued
ae I n - oe I 26 I os HKARztal
STL Denver 18
Iot-garyfle f;. -.:
tIRg Corporatslon
Cl.ient Saryrl-e ID: GIIrIrgI.-O9O9Os
IlCIf,AIT lletal.e
D5r100153 -OA2 I{atrl-x- - - - - - . o . : GsI
PREPARAITTON- WORK
AIVAITYSIS DATE ORDER #
REPORTTNO
PARAMETER RESUIJT IlfMIT IINITS METHOD
IilieleI
Lread
Vanadium
Zi-nc
Zirconfum
o -oo27 B
ND
ND
o-ol-g B
o.oo51 B
o - o{o [rg,ll-J,
Dllutiou E'acEor: 1
0.0O3O mg/T.
Dilut.l-on Factor: 1
0 , 010 mg /T,
Dilution Faetor: 1
o - o2o rylL
Dl-lutl-on Factor: 1
O - 015 WIL
DLlut.ion Factorr 1
oe lz3-aelzt I os
oe/23-Oel27/as
ae/23-oe/27/as
oel23-oel27 I os
oe lzT-oe 126l as
EKARTUAP
HI(AR71AQ
HKARTlAR
EMRTIA:r
HXnR77-A2
9II845 50108
.Analyeie Tima. . : 12 r 03
9w845 50108
Analyels Tl,me. . : 12 : O3
sw846 60108
Analyele Tlme..r 12:03
silr8t6 60108
Analyslg TLme-.: 12;O3
sH845 60108
Analyale TLme.,: 2O:19
Prep Bateh *---: 5265335
Mercury ND O.0O02O mg/f,
Dilrrtion Factor: 1
IUIE(S):
sw846 747AA Oe/25/ aS
Analysls TLme. . : 19; O1
HKAR?O
B Elim.tcd rarlt- Rsult ir lu thm RL,
L S€rlal dltuttoo of r du$ot. h tbc aoatyticar barctr iuficarca &4 physicrl lId drcrnical intcrfcrcrrcs src prcscr[
STL Denver
Iot*Saqr1e #---!
Date 8arylIed---3
PARAIT{ETER
IIRS Corporatlon
Cl"ieut Sarqrl-e ID: gr-il1-O9O9O5
IlCItrAL tletaJ.o
Ds11001s3 -003
09 / 09/ os 09 : 25 Date Receirred. - i 09 / L0 / as
RESULT
R.EPORTING
IJIMIT UIII.TS METHOD
Uat.rk+------i GW
PREPARATION- WORK
AIIAIJYSIS DATE ORDER *
Prep Batch #- - -:
Cadmium
Selenium
526518 0
ND
ND
0 , 0050 rfig /T'
Dilution Factor: 5
0,010 $rg/L
Dilution Factor: 5
9w846 6020
enalyeie Time.. . : O4 ;22
sw846 6020
nu.elysie ?ime. . : O4'.22
swg46 60108
Ana1ysJ.e Tltne. . : 12 :08
sT{846 50L0B
Analyela Tlme-.: 19:45
gII845 60r.(}8
AnalyeLs TLme..: 12:OB
5II845 60r-(}8
AoalysLs Tl.me. . ; 12: o8
91846 501(,8
Ana}yele Timc--: 19:{6
sw846 6 01_OB
Aualyale TLme. - : 12: oB
s'r846 601(,8
Anal.yais Time-.: 12:08
sr846 50108
Analyate Tilne..; 19:46
sw8{5 50108
Analyaia Tine-.: 19:46
5'H846 50108
AnalyeJ.e TLme. . : 19 :46
sw846 50108
AnalysLa Time- -: 19:{6
next page)
ae / 23- oe /27 / as HKARe1AF
oe / 23 - ae / 27 / as HI(ARe lAG
Prep BateJr
Silver
Aluminurn
ArgenLc
narium
CaI'cirm
Chromium
Copper
fron
Potaselum
Itiagnesl-rn
Sodl-un
*. - -: 5265222
ND
ND
o-o15
o -2L
110 L
ND
o-o20
a -24
72
84
1700
$tg /T,
Factor: 1
wg /t'
Feetor: 1
ryln
Faetor: 1
ug,lI,.
Factor: L
nglt
Factor: 1
mg/L
Factor: 1
rylt
Dactor: 1
rylT'
Factor: 1
rylt
Faetor: t
wlt
Factor: 1
ae/23-oe/27/os
ae/23-oe/26/as
aelz3-oel2r I as
oelzt-ael27 los
aelzs-oelze los
oe/zt-oe/27/os
aelz3-oel2zlos
oelzs-aelzslos
aelzs-oel26/as
ae lz3-oe lzol as
HKAR9ULR
HKAR9lAT
EMRgLAT'
EMR,9IAV
trMR9LLs
HI(ARg1ATT
IIMIRg1JIX
EKARg1..A6
EKAR9LAT
IIKERgI,EA
0.o10
Pilutlon
0.10
DL1ut,l-on
.
o-o15
Dilution
o-o10
Dl-].utLon
o .20
Dilution
o. o10
DllutLon
o-o10
Dl-Iution
o.10
Dllutl-on
3-O
ul-lutLon
o-20
Dilution
5-o rrylt
Dllutlon !'aetor: 1
(continued
ae I 23 -oe | 26 I 05 EmRgr.,Ae
STL Denver 20
uRs Go4roratlm
CLieut Saqrl.e II): GDI-il1-O9O9os
S(}l'ifL Iqetale
Iot-Saqrl-e *.. -: D5T100153-003
PARAMETER RESUIJT
REPORTING
IJIT{TT UNTTS METHOD
Uatri:r-r-.-,---3 OW
PREPARATION- WORK
AI{AITYSfS DATE ORDER *
N1elel.
Iread.
Vanadium
Zf-uc
Zirconirm
Prep Batch *- - - 3
Mercury
IICIfB (B) :
o- oo21 B
ND
ND
o-o15 B
o-oo5g B
s2653 3 5
ND
o-o{o ryln
DLluELon Factror: 1
0.0030 mg/L,
Dilution Factor: L
o - o1-o mg/t,
Dilution Factor: L
o - O2O vy,ll
Dilutlon Factor: 1
O - O15 rylt,
Dl-Iution Factor: 1
0.00020 nry/L
Dilution Factor: I-
oef 23-oel27 los
ae/23-ae/zt/os
oe/zt-oe/27/os
asl23-osl27 los
ael23-oelz6los
EKtrR9IAO
HKARg1A1
HI(ARgLA2
EKARgilL3
EKARgIAI)
811846 601(}8
Analyola Tlme..: 12:08
sw845 60108
Analyeis Time..: 12:08
9w846 50108
nnafyeie Tima-.: 12:OB
sr845 501(}8
Analyaie T{me..: 12:OB
9H846 60108
Analyeie Tlme..: 19:46
sw846 747OI. Oe/26/Os
Analysle Tl-rne. - : 19 : O3
L Sctial dlludon of I dige$rb tr tttc snrtydcrl brt fi iilticila thrt pnysicsl strat ctrmicrl lilcrfcrences arc pr.scril.
B Esiotatod rc6lrlt' R6uh ls leas thltr RL
STL Denver
Irot-Saqll.e *., .3
Date Saq)Ied. . ,3
PARA},IETER
IrRg @rporatLon
C1ieut 8aq>1e ID: Gf,-sB-OgOgOs
lOlf,AL Hetals
D5I100r.53 -004
09 / a9 / os 09 : 35 Date Received, . 3 09 /Lo / 05
RESUIJT
REPORTTNG
I,IMTT UNITS METIIOD
PREPARATTON-
AI{[AITYSIS DATE
Gtw
WORK
oRDER #
kep Betch *- -.1
Cadmium
BeI-enirm
526s18 0
0-00076 B
o-o078 B
o-o10
Dllutlon
o_o20
DLlutlon
ng,ln
Factor: 10
rylt,
Factor; 1O
o. o1o nrg/L
Dllution Factor: 1
O - 10 ryl['
Dtlut,ton Factror: 1
O - O15 rylL
DLluE,Lon Factor: 1
O - O10 ryll'
DLlut,l"on Factor: L
O -20 rylt'
DllutLon Factor: 1
O. O10 mg/L
Dllutston Factor: 1
o. o1o firy,/L
Dilution Pactor: 1
O -1O rylt
Dllutl.ou Factror: 1
3, O W/t'
DlluElon Feetor: 1
o - 20 ngln
Dilut,ion Faetor: 1
5-O rylL
Dl1ut,lon F'actor: L
(Continued on
sH845 6020
Analyala Tlme..: 0{:{7
8H846 502r,
Arralysie rime. - : O4 :47
srir846 5010B
Analysig Time..: L2223
6'H845 60108
AnalyeLe TJ.me. . : 2A224
srr846 60108
Anelysis Tlme..: L2:23
9H846 50108
Analyaia Tlme..; L2t23
gII845 60108
Analyeis TLme. . : 2A'.24
sw846 50108
AnalygLs Tlme..: L2:23
slrr845 5 0108
nnalyeis TLme..; L2223
srH845 60108
AnalysLe Time.,: 20224
snr845 6()I-(,8
AnalysLs TlmB..: 2O:24
srrS{5 50L08
Analyel-s Time. . : 2A:24
9w846 60108
Analyeie Tine.,: 2o=24
next page)
oe I 23-og I zz I as lrf,arlcrilr
oe | 23-og I z7 | os EmrertrG
kep Batch
Sllver
Alumtnrm
Arsenic
Bariuu
Ca-I.cirm
ChromLum
Copper
fron
Potagsirm
liagnesirm
f. - -: 5265222
ND
o*o18 B
o-oogg B
o-25
640 Ir
ND
ND
o-o48 B
39(,
340
5100
oe/23-ae/27/as
aeln-oe126los
oe l23-ae l27l os
oef z3-oelzr las
oe l23-ae lzel as
oe/23-oelzt/os
oe/23-ae/2t/os
ael"t-oe126los
ae /zt-ae l2e los
ael23-oelzalos
oe lzs*oe lzsl os
HKATClAR
ENTELilT
EMa1EIAU
HmattAv
HI TEAA5
HKATCTAW
HKATC]-AX
EMa!CIAS
EKNrc7-L7
HKATCLAA
Hmrcl,acSodirm
STL Denver
IIRS Corporation
C1l.ent Baryfle ID: cffi-5B-O9O9O5
aUTAIT l.letsal s
D5r100153-004 l{atri:r- - - } } o - - - Z GIlr
PREPARATION- WORI(
AIIAITYSfS DATE ORDER *
O
Iot-Saryl1e *- - -:
PARAIvTETER REgT}LT
REPORTTNG
ITIMIT UNITS I{ETHOD
r5l.cke1
Iread
vanadirm
ZLuc
Zirconium
kep Batch #- - -:
Mercurll
IwrB (s)
=
0-(}(}68 B
![D
o. oo29 B
o-oo52 B
ND
52663 3 5
ND
o - o4o rylr,
Dilutioa Paetor: 1
O-0030 mg/I'
Dl1utlon Factror: 1
O - 0L0 ry/t
Dl-Iut,l-oa Factor: 1
O - o2o rg/t,
Dllutlon Factsor: 1
0.015 nq/L
Dilutlon Factor: r-
O - OOO2O rng/L
Dl-Irrt,loa Factor: 1
oglzt-oelzr los
oe/23-oelzt /as
oel23-oel27 los
aelzt-oelz7 f os
oe/23-oe/ze/as
IIKHrcIAO
HI(ATC1A1
HNIIEIA2
EMTCI.L?
HI(ATClAD
Btr845 60r.(}8
Analyais Timc..: L2:23
sw84 6 6 0108
Analyeis Time. . ; L2..23
srr845 60108
Aualysle Tl-me. . : L2'.2t
arr846 60LOB
Analysle TJ'.me. .: t2'.23
sw845 50108
Arralysle Timo. . ; 2Q 224
slrg4 6 747OA. Oe / 2e / OS
AnaLysj.s TLrre- . : 19 : OB
Hr(Areo
B Btiorff.d rc$lt. Re$rt is loss thm RL
L Serlrl dllution of a ttigc*ra in thc anlytical betdr ildicatcr &at physicsl rDd c,heDicel intEfc[€nc6 Er! prcscrlt.
STL Denver
Iot-Seryr1e *---:
Date Sarylled.--3
PARAMETER
IIRIi Corporation
client saryile rD: qt-sD-ogogos
TCTf,AL HeIaIg
D5r1 001s3 - 00s
og / a9 / 05 10 : 45 Date Received. - r ae / 10/ 0s
RESULT
REPORTING
LTMIT TINITS METHOD
GW
PREPARJATION- WORK
AI\IATJYSIS DATE ORDER #
Prep Batch S- - - :
Cadmium
Selenfum
s26s180
ND
o-oo92 B
Pregl Batch
Sllver
Aluminum
Areeul-c
O Bartun
Calcirm
ChromLum
Copper
Iron
Potassirm
liagnesirm
Sodirm
f---: 5265222
ND
tuD
o. o1o B
o-17
26f, L
ND
ND
ND
81(}
400
8900
0. o20
Dllution
o-o40
DilutLon
ng,/L
Factorz 20
ry,lT,
Factor: 20
0 . 0l-0 nq/l'
Dilution Faetor: 1
L.0 nrq,/t'
PL1utlon E'actsor: l.O
o - o15 Wln
DtluEl"on Factor: 1
O - O1O uglt
Dilution Factor: 1
2-O rglt
PLluElou Factor; 10
0.010 mg/I-'
Dilution Factor: 1
0 , 010 mg/T'
Dilutioa Paetor: 1
1. O fftg/I'
Dilutlon Factor: 1O
30 ryllr,
Di1ution Factor: 1O
2-A ry,II,,
Dilution Factor: 10
s0 wlr,
Dilutioa Factor: 10
(Continued
SDII846 6020
Aaalyaio Time.. r 04:51
sw8{6 6020
nualyele Tlme..: O4:5L
sur845 50108
Aualyeig Tlme. . : L2 :27
Slrl84 6 6 010B
AEalyBiB Time..: 0O:51
sH845 5010B
Analyele TJ-me., : L2 :27
9II845 50108
Analyeie TLme. - : L2 t2'7
sH846 50108
Analyeig Time- -: 00151,
sw845 5010B
Analyele TJ"me. , : L2 t27
sw846 50108
Analyel-e Tl,me. . : L2 :27
sw8{6 60108
Analyel.e Tlme. . : O0 : 51
sr8{5 60108
enalyele Tirne..; 00;51
6'H846 60108
Analyeis TLme. - : 00 :51
sw845 60108
Aualyeie Time..; 00;51
next page)
ae l 23 - 09 / 27 / as HKATDLLF
ae lz3-oe I 2r I os rrmrDlac
ae I 23 -oe I zB I os Hmrr)lae
oe 123 -oe /27 / os
ae/23-oe/2s/os
oel23-oe lzz /as
ae lz3-oe lz7 I as
ae lz3-oe lzB l os
oe/23-oe/27/os
ae/23-oe/27/os
oe/23-ae/28/as
oe l23-aelzel as
oel23^oe l28l os
HKATDIAR
HKATD1-AT
HIEAIT)LLU
EELTI)Lil\r
EKLIDTA5
HKAfDIAW
HKATDlAX
HKATDlAs
EM[I)IAT
EMII}LAA
STL Denver 24
Iot-8aqll.e *- . - 3
t Rg 6rporation
Cl.ieut Saqr1e ID: (III-5D-O909O5
aUXAL Uetral-a
DsI100153-005 rfatri-x.-.-.--.-r GW
PREPARATION- WORK
AI{A[,YSIS DATE ORDER #PARAMETER
IIickel.
Iread
Vanadlum
Zi:nc
ZLreon.lum
Prrep Batch *- - -:
Mercury
IUCTE (S} :
REPORTTNG
RESULT LIMIT UNITS
o - o4o rg/t,
Dllutlon Eaetor: L
o. 0 07A mg/L
Dilutioa Factor: 1
o - 010 mg/L
Dl-lution Factor: L
o. 020 mg/r,
ol-Iutl-on Factor: 1
o-15 wlT'
OLlutLon Factor: 1O
52663 3 6
IID 0.00020 mg/L
Dl}utrlon Factor; 1
9Is846 501OB
itnalyais Time - . : 1.'2'.27
sw845 60108
Analyele TLme..: I,2:27
sF[846 60108
- Analysie Time. - : L2 :2'l
svr845 50108
Analyaie Tl,me. . : 12 227
srtr846 60108
AnaIyBiB Time . -: O0:51
METHOD
o-oo21 B
NDG
ND
ND
o-or.g B
og 123-oe lzt / as
ae/23-oe/zt/as
ae/23-oe/27/as
oel23-ae/27/as
ael23-aelzelos
HKATDI-..e.O
HKATD]-JAl
HKATDTAz
HKATDl.A:}
IIKATI}LAD
svr846 7 47 OA Og / z5 / As
Analyaia TLme..: t9:10
Hr(ArDo
B Eglrnrd rcautt. Rcsultisls thm RL
L Serhl dilutlon of a discshtc in &c anatyticsl brtch irdicatc drst physical and dcmical intcrfcrcnccr irc prcscot.
G Elcvrtod reponiry limit. Thc rcponlDg limlt Is elwercd duc to mrulr lnrcrfcltnc.
STL Denver
f.ot-Saqlle f;- . -:
Date SaEfrl-ed---!
PARAMETER
URA Corporation
C}ient Saqfte ID: GH-96-O9O9O5
TOXAIT iletale
Dsr100153 - 006
09 / a9 / a5 11 : 55 Date Rec-eived- - : a9 / La / as
RESUI-,T
REPORTING
IJIMTT UNITS METHOD
PREPARATTON-
AIILAITY9IS DATE
WORK
oRpER #
Prep Bateh
CadrnJ-um
SeI-enium
kep Batch
Silver
Aluminum
Arseni c
52651,8 0
ND
0-016 B
o-o15
o-o97
86t
o-50 B
240
29A
10000
oe/zt-oe/27/as
oe/23-oe/zs/os
ae/zt-oelz7 los
ae lzt-oe l2z I os
oelzs-oelzvlos
ae/23-oe/27/os
oe/23-ae/zz/as
ae l23-ae l28los
oe/21-oel2s/os
oe 123-oe lzsf os
oelz:-oel28los
HKATEI-AR
HI(ATELAT
Ef,AlBItrU
EKATBIA\/
HtrATBilL5
HKATElAW
HKATEIAT(
Ef,AIlB1A6
HKAIBILT
Hffitts1AA
HmltsIAe
0.020
Dl.lution
o-o+o
Dl-IutLon
mg /t'
Faetor: 2A
rylt
Factor: 20
0.010 mg/L
DLlutLon Factor: 1
L. O mg/L
DilutLon l.actor: 1O
O - O1s ry/t
Dllutl"on Factor: L
O - O1O ryll,r
Dilution Factor: 1
2-O ry/L
Dilution Factor: 10
0 . 0L0 mg/t'
Di LuE,l-on Factor: 1
O. O10 mg/L
DL1ut,Lon Factor: 1
f--o ng,Ir-
Dilution Factor: 10
30 lrrg,ll
Dilution Factor: 10
2.O rgll,
DLlutlon Factor: 10
50 ngll
Dllutlon Factor: 10
sw84 5 6A20
AnalysJ.e Tlme. . : 0{ : 55
811846 6020
Analyeia Timc--: O4:55
sw845 60108
Analyels Tl-me. . : L2..33
sw845 50108
Analyste TLme..: 0O:56
9t846 601(}8
AnaIyEiB Tima..: 12:33
91846 601(}8
Analyoj-e flme. . : !2 t33
glr845 60108
Arralysie TLme. . : O0 :55
sL{846 50L08
Analysle TLme..: 12:33
9w846 60L08
.nrralyola Time. . : 12 : 33
sIr846 60108
Arralysls Tlme. . : 00 : 55
8U846 60r_08
Analyel"o Time. . : 00 : 56
811846 60108
enalysls Time..: 00:56
9w845 60108
Analysls Ttme..; 00:56
next page)
09 lz3-oe/27 /os HI(ATEIaF
ae I zg^-oe I 27 I os EKATBTae
o Barirm
Ca-Lcirm
ChromLum
Copper
Potaegirm
l.iagnesira
Sod.lum
STL Denver
(Continued on
Iot-Saryl1e *- - -:
IIRA @rporation
cl.Lenc garyile rf): GTr-46-o9o9o5
lUf,Afr Heta-I-o
DsI1001-53-006 llatri:r- D - --. -, o: GTII
PREPARATTON- WORK
AhIALYSIS DATE ORDER #PAXAIUIETER RESTIIJT
REPORTING
I,TMIT UNTTS METHOD
Nickel
Lead
vanadium
Zinc
Zirconirm,
kep Batch *- - -:
Ivlercury
ITCIB (S) :
T{D
o-00{6 B
o -o27 B
5266336
ND
O. O4O mg/r,
Dilution Factor: 1
0,0030 mg/t'
DlluEl,on Factor: 1
0 . 010 ng /I,
Dj,Iurl.on Factor: 1
O - O2O rg/T'
Di]-ution Factor: 1
o-15 wglt-
DlluE,Lon Faetor: l-O
O. Ooo20 mg/L
Dilution Factor: 1
ae/23-oe/27/os
ae/23*oe/22/os
os/23-as/27/os
ae /23-oe lzz I os
oe/zt*aelzslos
HKATElAO
HKATElAl
HKATELAz
HKAIBILJ
HMTBTAD
IUD
sw845 50108
Analyele Time..: L2:33
sw846 60108
Analysls Tlme. . : 1.2 : 33
sw845 50108
Analyele Tlme. . ; r-2 : 33
str8{6 60108
Analysls Tlme. -: 12:33
sr846 601()8
Aualysie Time..: 00:56
sw846 747OA oe/26/As
Analysla TLme-.: 19:12
B EsiD:arcd reriltll Re$rlt b less lDm RL
L Serial dlludoa of a diBeriatc in thc amtyticaf bat*r indicacs [ur physical l,d drcrnic&l interfereoces rrc prtscnt.
STL Denver
.Ia^uac TIS
'I*'sild or8 $iltaraJxlol rcFtorp Fr8 FcF,(qd rs$ scrqpq qarq m{rul ilp q e|urrrElp r Jo [osqlp F-u.s .I
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I :roxc8d uoTxnTTc
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T :ro?cEd uoTlnIT(I
utu glo-0
T :rolaBd uoTxnTTG
T,ltru OZO'O
I :-rolcBdt uoTlnrT(I
l/6ttt 0TO'0
I ;roacEd uoT?nrTG
't /Ew 0800'0
I :rolcEs uoTlnTTc
ilfu oto-o
: (B) ETOff
qI{ rlznc:alrl
9€g9gCS :'- -* qDAEE dara
GrT.CT\DIH
Etrt.rililH
e\ilI..f,\DIH
IVTf.I\DIH
oIrr-e;f,rflH
so l9z,l60-EZl60
sol Lc,l6,o-Ezl60
so/LZ/60-tz/60
so/Lz/50-EZ,/60
sol tzleo-Ezl60
€5: OZ : ' 'eulTtr, elArtleUU
solog 9r8rs
LE: ZT :'' "utTtr a5ar{1uu1g
aoro9 9?8ris
L€.i zT :' . ?ur[,f, elsrllutrq
s0T09 9?8ms
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90I09 9?8tds
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EOTOg 9?8[S
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8OO- EETOOTISCI
sIElt Iluilolt'
SO6OGO-AL-8, :fi atfueg, atre113
rroTaBrodroa suo
GOH,f,EilSTINN .tIhIIT
eNI,ruodfrlr
lItr.f,E[trtfttd
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E9:08 :"eurr& ETE^rPuu I :rolc?J uoT3nITO
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€S:OZ :..aurTf sfsrlEutt T ::oqoEd rroT?RITC
g\[Ife\uE golgel6o-Ez,l6o solog 9t8xs Tlfiu oT-o zr-'o rx]rl
LS.CT ; "euTJ, 6T8](,TEtrV I :rolJBd uoTlnTTc
xnTF.f,ruE sol,.zl6o-f.zl6,o aolog 9"8t8 'iltu oTo'o ITo'o .roddoo
Le.zT r '-orrrT& aT6/('IEEV' I ::o1Csd uoTltrITG
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Lq-:.z,T : "?ruT.tr ezer(1ruq' I :jrol3td uoT?nTTG
AYTI}EEXE 9OlLZ,l6O-€Zl6O AOIO9 9t8rl8 vtn OIO'O tZ'O rErTres
. LE27T i"aurTJ, ETTiIEET{ I :rolcea uoTlnTTc
o\iT.eJvJrr so/LT,/6o-ez,/6o s0To9 9?8lit6 'I/Fxt SIO'O GN cTuaarv
€E:02 :"euTf e1e.(1atq{ I :ro JBd EoT?nfTq
L1-rz1- 2..enrTi elsl(pug, T :rolced uoTlnTTq
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ZZZS9ZS :---* qcaEg darA
gg:to :"euT& s;e,(1eug I :roloEd uoTlnTTq
8S:r0 :"eury.tr eler(1rug I :IolctJ rcTltrITG
dgIf,;f\uE 9tol,"zl6o-f-z,l6o ozog 9r8rs vrfr oloo'0 s zlooo'o urTu[rPt)
0SIS9ZS :-.-* rIafEA ard
* USGEO SJV(I 8I6.I'Tmfir OOHJ.S!iI S.I.il.IO .II!,[IT .ITOSSU US,ESI^ftnftfd
)ruoil -Nol.l\nrvdtud oNr&uoilEu
so/ot/60 :"IxlaTo<rq! eaBg ozzzr 90/60/60 :"'IleT&eg aaac
uo:' 'rFr?Era 80O-E9IOOTI9(I:--'*aI6rcA-?sI
BItlan 1rEI(};f,
5O6O6O-3r.-ffi1 :OI a16ue5 luaTTJ
(a6ed Sxeu uo panuTluoc)
€g:oz r "errTg, eler(1tuv r :rolced uoT?nIlc
Jtsr.eruxH solgzl6a-Eulao a0r0e er8ils I|tu o's
f,torlsroaroi) silun
O B,,.rate
Total Qyanide
NUIE (s)
=
IIRS Corryloration
Cl-ient Saqfle ID: GII-II9L-O9O9O5
ce!rcraf- Chemistry
D5IL00153 -AA2 fork Order *- - - 3 HKART
a9 / a9 / as 08 : 0o rlate Receirred-, 3 0g /La / os
RESTIIJT RIJ IINITS METHOD
liatriJ(---o-.o,-: GWIot-8aryfle *- - -:
Datre Sanpled---3
PANAMETER
PREPARATION- PREP
ANAIJYSIS DATF BATCTI #
PII
AurnOnta aa II
Chlorlde
F].uoride
ISltrate
Ifitrate-ilitrite
7 -4 O - tO No Unl.te
Dilut,lon Factor: I
A -76 O.1O W/t
Dl-].utLon Factor: l.
22oo J,Q 25o ry,lr,
DiJ-utlou Faetror: LOO
L-2 if O-1O ryll'
OilutLon Faetor: 1
O-11 O-1O frg,lL
tlLlutlou Faetor: 1
o-11 O-1O ry,lL
Dl-IutLon Faetor: 1
12O .f,Q 25 rylT,
ol-lutiou E.actor: 5
IUD 0 . 010 rrq, /I'
Dilutlon Factor: 1
04:OO
oe ltal as s26l262
17: 00
oell+los 52s7s7a
13 :15
oell.olas sznssaz
15:00
09 l2o-o9 I zLl os sz65ss2
02:00
SIIS{5 90{OB
AnalyaLe TLme. .:
Hcliln 350.1
analysl.s Etme. . :
DTCAIIH 325 -2
Ana,lysls Time. -:
He;Bnr 34A -2
Analyeie Tima-.:
ucilHr 353 -2
Analyeie Tirnc. . :
ucAnfl 353 -2
Rnalyeie time..:
ucBHr 375 -4
oe lla/ as
15:33
ael2llos
5253L01
5265478,
oelz,Slas 5272L73
Analyslg Time-.: 15:40
sw845 9O1OB/e012A Oe/21-0el2z/os s264s39
Analyals Tlme. - : L2: OO
RL Reporting Limit
J Method blank comtminrtion. Thc assoclrtod mshod bltnk comins tre targa analyre at a reportable levet.
a Etevatod reponiry llnrit. llre rcporting llmfi is olovaed due :o higlr analytc levels.
STL Denver
Iot-$arylle *- - -:
Ilate Sary,I.ed---I
PARAIT{ETER
IIRS Corporation
cl-ient saq)Is ID: ffi-tu-o9o9o5
Geuera^L Chemistry
D5f100153-003 rcrk Order #. . - r HI(AR9
oe / og / 05 09:25 Date Received- - i 09 /La/ as
llatrix-].--D---: CIW
PREPARATTON- PREP
AI{AtYSIS DATE BATCH #RESIILT RTJ TINITS METHOD
-t -1 o-1o tro ueits swa46 gorloB ol/tolos 52531rt1
DLlutlotr Factor: 1 Analycl-e T1me..: 15:35
o-?5 o-1o wlt Hceffi 3so-1 o9l2llo5 526st78
Dilutiorr FBcUori 1 anal.yeLs Tlrne.,: 0l:00
22oo d,e 2so wlt uorr !zs-2 oglr.elos 526a.262
DLIutloD Factor: 1o0 Aoa1yoJ.o Tlme..: 17;00
L-2 J O-lO rylt HCDrf, 3110-2 O9lL4lO5, 5.2s7578
Dllutlsr Fector: 1 Arrr1yaia Tima..: 13:15
o-1? o-ro rylt riclrf, 3s3-2 ogltolos 5265s87
Dilution tractor: 1 lEBlyais Ti.me..: 15:00
o-18 o-r-o u,lt HsAnr 3s3.2 osl2o-oslztlos szesssf
D,'lutloa Pactor3 1 Analysis Timc--: 02:00 V
3so J,o 50 wlt uGxlr 375-+ oglzalos s272L't3
Dilutlon Pactor: 10 ADaIyEIB TLme.,; 15:40
o-os5 o-o1o wlt sf,8r5 goroa/gorztt ag/zt-oglzzlos s26.1s39
Dj.IutLotr Factor: 1 }Ealyeie tinc.-: 12:OO
pE
AmnLa as II
Chf.oride
Fl.uortde
Ititr:ate
ISitratse-NLtrite
Buf"fate
Toraf- clnniae
rscfB (8) :
RL Rcportlng Limit
I Metnod blank contamloatlon- The rsoociatcd method blank contains rhc nrgct analytc at e rcponable level-
a Elevatod reporting limit. Thc rcponlng limit is elevatcd due to high analytc lcvcls.
STL Denver
Lot-8ary>I.e *. - - 3
Ilate Saupl-ed..--i
PARAMETER
IIRS Corporation
C1.l-ent San[IIe ID: cil-58-O9O9O5
Genera-I Chemiotry
D5I100153-004 llork order *- -. 3 HKATC
09 / 09/as 09 : 35 Dat,e Receirred- . i 09 /L0/os
RESIII,T RIJ T]NITS METIIOD
I{atrix-...-----! GTv
PREPARJATTON- PREP
A}IALYSTS DATE BATCH #
pE
Amonia aa II
CtrIorLde
Pluoride
ItLtrate
7-5 O-10 No Unlts
Dilut,ioa Faetor: 1
6T O 2-S ryl['
Dl-}utlon F'actor: 25
11OOO J, Q zs0 tugll,r
Dllution Pactor: 1OO
A .73 .f O - 10 Wll'
Dilutlon Factor; 1
80 2 -S wgtll'
olluElon Factor: 25
8o a 2-s nlglr'
Dilutiou Factor: 25
33OO .f , Q 500 WlI,.
ni].utlou Factor: LOO
O.010 r*g/l-'
Dilution Factor: 1
sH846 90{OB
Aoalyaia Time..: 15:39
Hearml 350 - 1
Analyste Time-.; 22zaa
HctrlfiI 325 -2
Analysle Tl-me. . : 1,7: OO
HeAnH 340 - 2
Ana1yaig Timq. . : 13 :15
Hei[nr 353 -2
Analysis Tlme. . : 15: OO
HCBHH 353 -2
AualyeLe Time..: 18:00
HCAmr 375 - 4
Analysls Tlme..; 15:{0
sw846 901- AB/ 9ol-2A
Rnal.yeJ.e ?ime. - : 12: OO
ae / zl-oe / 22 / as s264s3e
oe lLol os
oe l2r las
oelr,slas
oell''las
oe / r.al os
oel2T los
ae/2t8f as
5253101
5:]-7L454
5263262
52575'18.
s27L7a7
s27L679
5272L73-
O
lvitratse-nLtrl_te
Suf-fate
Total Cyanide
ryorB (s) :
ND
RL Reportlry Lirrrit
a Elevatod roporting lirnit- The reporting limit is elovat€d due m high anatyre levelr
I Mcthod blank contamination. Thc associatd method btenk contains the target analyte at a reportable level.
STL Denver 32
Iot-Sa4fle *.. -:
Date Barqfled---!
PARAIUETER RESTILT RIJ
IIRSI Corporatlon.
Client 8aryr1e ID: GtI-sD-O9O9os
General- Chemiotry
D5I1O0153-005 f,ork Order *.. - i HKATD
09 / og / as r.0 :45 Date Received. - i a9 / La / as
METIIOD
Ilatri-x, - - . - - . - - : GtI
PREPARATION- PREP
AIVAIJYSIS DATE BATCH #TINITS
pH
Amonia as I[
Ch1oride
Fluorl.de
lfLtr:ate
IfLtrate-Irit,rite
SuI.fate
Total ClranLde
rcr'E (s) :
7-g o-10 to units 8t1846 9o4oB oglnlas s2s31o1
DilutL@ Fastor: 1 AtralyBis Tinc..: 15:42
22Oo Q 1-OO wlt HCArr 3sO-1 O9121-lOs 52654'ra
Dilutioa factors 1000 eoalyaiE Tiro..: 04:o0
tgooo .r,Q 12oo rylt' l&Anr 325-2 O9lL8lO5 s261262
ollutLon Pactor: 500 ,Arra1ysl.a rLae..: 17:00
o-80 J o.1o rylt lEhflr 310.2 osl,trlos 5j2s75't8
Dl.IutLoD Factor: 1 AnalyoLe T1ne..: 13:15
33 O-1O rylt HCAnf, 353-2 OgltOlos s2655A7
oLlut.lon tractor: I arralyela rl.me..: 15:OO
34 Q 1-O rylt r'rcNilr 3s3-2 aglzo-oglztlos s2ssssl
DiIuEioR Pactor: 10 itrralyeis ?ine..: 02:o0 U
17OO J,Q sOO rylt, UcBffi 3?s-+ OglZslOS s2'r2a73
pilutioa Factor! 100 loalyaie Time.-: 15s4O
ND O.O1O nq,/t SW845 gOtOS/gOtZe Og/ztaglZz/oS 526453e
Dllutton Factor: 1 laalyaJ.a BLne..: 12:OO
RL Rcportlng Umit
a Elevated reporting llrnit. The reporting limit is elevated due ro hllr rnrtyte levels.
I Method blank conunrimtion. The assoclated rnettrod blank connins the tcrgot rnalyte &t I reporrable level.
STL Denver
Iot-Saqll.e *- - - !
Ilatg Saq)Ied---i
PARAMETER
URA Corporation
e1ient Saryl1e ID: Gfl-S6-O9o9O5
General Chemiatrlr
Dsf 100l-53-006 f,ork Order *- - -: HKATE
09 / og / as 11 : 55 Date Received- - ! og /Lo I a5
RESULT RL T'NITg METHOD
![atrftr,.,--.--..! GW
PREPARATTON- PREP
AIVALYSIS DATE BATCH #
pE
Jlmnla aa II
CtrI.oride
F]-uoride
IUitrate
8 -2 O - 10 IIo Unite
Dllutlon Factor: L
5-O O.1O rytl['
Dl,IutsLon E'actor: 1
15ooo J,Q 250 rylL
Dl}utl-on Faetor: 10O
A -76 .f O - 10 rylll'
Di].utLoa Faetor: 1
O-12 O-1O Wln
ni]-utLore Factror I 1
O - 12 O .1O ury,I['
Di]-utioa Faetor: 1
27OA J, Q r-2OO rylt
Dilution f'aetor z 25O
ND 0-0Lo mg/L
Dil.ut'ion F:rctor: 1
sw8{5 90408 OglI0loS s2s3101
Analysle Time..: 15:51
DrcArrw 3so . 1 oglLLl os 526s17fi
Analysia Tl-me. . : 04: 00
HCAnu t2s -2 o gltslos s26326?
AnalyoLe Tlme. . : 17: 00
HCAHH 3{O -2 OglL4lOS 5"57578.
Analyaie Time. . : 13: L5
ricrHf, 3s3 -2 ugl1:olos 527L7A7
Aaalyeie Time, - : 15: OO
r'reLHrs 3s3 -2 O9l27lOS 52tL679
Aaal-ysig Tlme. . : 1.8 :0O
ucBnw 37s -4 a}lzBl0.S 5272L71
Analyeie Tl-me - - : 15 r 4O
sw846 e0108/9012A 09 /2L-a9 /22/ A5 s264s3e
Analyaie Time. . : 12: OO
o
rrLrrare-r5itsr,.re
SuIfate
Tota1 Cyanide
rcfB(S):
RL Reporting Limit
I Mc$tod blsnk crrntemination. Tlrc assoclated meilrod btank con:alns the urrgot anrlyto at 8 reponable level,
a Ekvated rcporting limit. The reporting llmlt ts olovated due to hhh analyt€ leyols.
STL Denver
I.ot-Ann{ll-e *- - - 3
Ilate fiary)Ied,---i
PARAMETER RESULT RIr I]NITS METHOD
IIR8 @4loratiorr
C1ient Saryfie ID: GII-7C-O9O9O5
general. ChemLotrlr
D5I10O153-008 Work Order #- * - : HKATif
09 / 09 / as L2 z2a rlate Receirred.- . i ag / tO / as
liatri-r. - - o o - ! - - : GIi[
PREPARATTON- PREP
AI{AIJYSIS DATE BATCH #
PH
Amnia aa N
Chloride
Fl,uorl.de
Nl.trate
rul-trate-xitrl-te
SrrI.fate
Total qranide
IUTts(S}:
8-1
{-3
44O it, Q
O - 10 fdo Unito
Dilut.lon Factor: 1
O -1O rylt,
DilutLon Faetor: 1
sr846
AnalyeLe
HEJLITT
Analyels
}TCltITtr
nnalyeie
}TgAIilI
Analyaie
ITGIITT
AnalysLe
rnc[Hfl
Analyaia
ricnffi
AnaIyBlB
sw8{6
Aualysla
90408
rime. . :
350.1
Tlme. . ;
325 -2
Timc-.:
340-2
Time. . :
353 -2
Ti.me. , :
353 -2
TLme. . :
,-75 -4
ae llol os
16: 02
oel2Llos
Ott : 00
oehslos
17:OO
oellllos
13r15
oelLal os
1,5: 00
oelT7 las
18: OO
52531O1-
s265478.
s263262
5257578.
s27L707
L2 rytlr'
Dilutlon Eactor: 5
A -77 ,t O - 10 urglt'
Dl-lutLon Factor; 1
O - 35 O .1O ryll'
Dilutioa Factor: 1
O-35 O-1O rglt'
DiLutLon Factor; 1
3-1 BrJ 5-O rylI
Dllution F'actsor; 1
ND 0.01-0 mg/L
Dllutlon Factor: 1
s27L6o
ae l28l as 52'l2L73,
Time.. : 15:4O
e01 oE/ eo12A oe /21- - o e /22 / os 5254s3 e
TJ-me..; 12:OO
RL Rcponlng Limit
J trtdroO bl&nl( coataminetion. Thc a$sociatcd mstrod bhnk conulns the target analyte at r rcportablc lcvel.
a Elevated reporting limit. The reportlng limir Is olsvated dus o hfh rnalyto lovots.
B Estlmated resnrll Reeutt ig less than RL.
STL Denver
acDATA oNw
DsrI_OO153
sample Preparation and Analysis Control Ntrmbere
I'{ATRIXSaI"IPLE#
001
o02
o03
o04
wQ
AI{AIJYTTCAI,
METHOD
9n845 82608
MCAWW 325.2
MCAITffi 344 .2
MCAWW 353 -2
MCJL}|m 353 .2
sw846 9o1AB/ 9012A
sw845 6020
sw846 74704
sw846 90408
sw846 82508
sw846 5 01,0B
MCAUM 3T5.4
MCAVE9I 350.1
MCJIWW 325.2
I,ICJ\WW 34O .2
MCAITIII 353.2
MCaI{W 353.2
sw845 9o1AB/ 9012A
gw845 5020
sw846 747AA
sw846 90408
sw845 82608
gwB46 50108
IrlcAww 375 .4
MCJ$IrS 350. L
MCAWW 325.2
MCAWVI 340 .2
MCAWW 353.2
MCAWW 353 _ 2
sw846 90L ABl9Or.2A
sw845 5020
gwB46 7 470A
sT{846 90408
sw845 82608
sw845 60108
MCAWW 375.4
MCAWW 350,1
(Contl"nued on next
I,EACH
BATCH #
PREP
BATCH #
52654 0 6
5253262
5257578,
5265552
5255587
s264s3 9
s26518 0
s2653 3 6
5 253 10 r-
5255405
5265222
5272L73
526547 8
5253 252
5257 578
5265552
52555 I 7
526453 9
s26s1B 0
s25633 6
5253 10 1
5255406
5265222
s272L73
s25s478
s263 262
52s7 57 8
s27L67 9
527L7 07
526453 9
5255L80
525533 6
5253 L01
52654 05
s26s222
5272L73
s27 14 54
l,1g R[IN#
5265258
5263 170
s25 815 7
5255344
5264340
s26sr.16
526627 0
525612l-
s265258
s255746
5272L49
s265290
s26317 A
s25 81,5 7
s25s344
526434 0
52651_ 1- 5
526627 0
525 6L2L
5255258
s26s14 6
5272L49
526529 0
5263 17 0
525 81_5 7
527L432
5264344
s26 s1_l- 5
s26627 A
52s 61,2L
s26 s258
52651,46
52721,49
527 13 06
GI'T
G[{
G9r
GW
GW
GUI
GW
GW
GW
GW
GW
GW
GW
GW
GTT
G[iI
GW
GTT
G['I
GW
GW
or{
GIII
GI{
GTT
GW
GI{
GW
GW
GW
GIIT
GTT
GW
GW
GI{
GTY
STL Denver
page)
.35
OCDATA
D5r100153
Sample PreparatLon and Analysis Control Ntlnbers
SAII'IPITE*.
oo5
oo5
oo7
009
I,IATRfX
I,EACH
BATCH #
PREP
BA:rCH #
5263?52
5257s7 8
5265552
526s58 7
s26453 9
526518 0
s26633 5
s2s3 101
s2654 0 5
s265222
5272L73
5255478
s263262
525757 I
s27 L67 9
527L7 07
s26453 9
525518 0
s2653 3 5
52 531- O 1
52654 0 5
s265222
5272L73
52654'.18
s25s406
s2 53 262
525757t3
s27 L67 9
527 7-7 4"7
526453 9
s26sL8 0
s26633 5
5253101
s2654 0 6
s265222
5272L73
526s47 8
MS RT'N#
5263L7 0
52581_57
5265344
526434 0
526s116
526627 0
szs6L2L
52652s8
s265 14 6
s2721-4 9
5265294
5253t7 0
5258L57
527L432
52643i[0
526sLL6
526 627 A
s2s 6L2L
526s25fj
s26s1{6
5272L49
526s294
5265258
s26377 A
52581s7
527L432
526434 0
526s115
526627 A
s2 5 6L2L
s26s2s8
s26514 6
527214 9
s26s2 90
GT1I
GW
GW
GW
GW
GW
GTI
GW
GVI
GTI
GW
GW
GW
GW
Gmr
GW
G}I{
cffi
GI,!f
GUI
GW
GVit
G}r{f
GW
GW
Gtw
GI{
Gvr
GW
GI{
GUr
GW
GW
G}T
GVI
G}T
A}IATYTIEAL
METHOD
MCAT{I{ 325.2
MCAITISI 340 ,2
MCAWW 353 .2
MCAIm 353 .2
sw845 eol oB/ 9012A
sw845 6020
gw845 7470A-
sw846 90408
sw845 82508
9w845 6 0108
MCAWW 375.4
MCAlrnil 350 .1
MCAWW 325 -2
MCAI,{I{ 344 .2
MCAViil{ 353 _ 2
MCAnm 353 - 2
sw846 9O1OB/ 9O12A
sw846 6020
9w846 741A,'."
sw845 904 0B
sw846 82608
svit84 6 6 0108
MCAWW 375 -4
MCAWW 350.1
sw846 82608
MCAI'IW 325.2
PrCA$IW 340 -2
MCAWW 353 - 2
MCAWW 353 .2
sr{845 eol aB/ eo12A
sw846 6420
sw846 ',7470A-
sw846 90408
sw8{6 82508
sr{84 6 5 0108
MCAyIW 375 .4
TICAWW 350. L
STL Denver
C1l-eut, I.ot #---3 D5I100153
IIB Lots-garyr1e *: D5T220000-406
Analyele Datre.. r a9/2l/o5
Dilution Factor: 1
PARA}IETER
Acrylonltrlle
Carbon disulfide
Ctr 1 o rodib r ornome t han e
trane -L,4 -Dichloro-
2-butene
Iodomet,hane
VJ-nyI acetate
L,4-Dl-oxane
Acetonitrile
Acrolein
2-Ch}oroethyl vinyl ether
1 -Chlorohexane
AIIyI ch1.orl-de
Clrclohexane
Cyc).ohexanone
cl-s - 1, 4 -Dichloro- 2 -buLene
D i ch1 oro f luoromethane
Ethanol
Ethyl acetate
Ethy1 ether
Ethyl metrhacrTlate
Ieobutyl alcohol
Iaopropyl ether
ulethacqflonitrile
tert-Butyl alcohol
Methy1 methacrylate
2-NiLropropane
2 -Pentanone
Proplonitrile
Tetrahydrofuran
n-Butanol
Tr i chlorot ri f luoroettrane
Hexane
Acetone
1, 1-Dichloroethene
Benzene
B rornodl chl o rome t hane
Bromoform
Chlorobenzene
Bromomethane
Toluene
I{HIUOD BLtrItK RmORr
gtr.lus vo].atilee
Ilork Order t.--: IIK6ITCIAA
Prep Date- - - - - - : 0 9 /2a/ 05
I{atrlx,, o- -...-3 }IATER
Anal.yeLa ri-ne. . r 08 : 55
I'[ETI{ODRESTIIJT
REPORTING
LTMTT UNITS
ND
ND
ND
ND
ND
ND
ND
rlD
IID
}UD
IUD
ND
IUD
}UD
ND
IID
IID
ND
IUD
ND
}ID
ND
ITD
ND
ND
ND
IID
ND
luD
ND
luD
ND
IUD
IID
IVD
ND
IID
DID
}UD
IUD
20
L.0
1.0
1,0
1,0
2.O
200
2A
2A
2.0
1.0
2.O
2.4
20
1.0
2.O
200
5.0
2.O
1.0
50
10
10
50
1,0
2.0
2.4
2A
5-0
50
1.0
l_.0
1_0
1.0
1.0
1,0
1.0
1.0
2.4
1.0
ug/r,
:ug/T,
ru.g/t'
]utg/L
vg/r,
ug/r,
ug/n
:ug/r.
ug/r,
ug/r,
ug/r'
Lrg /T'
ug/t
ug/I'
ug/t'
ug/t
ug/r,
LLg /r'
us/T,
vg /r'
ug/t'
ug/r,
ug/T'
vg /r,
ug/r'
ug/r,
ug/T,
lu.r/t
ug/r.
lug/t,
:ug/r,
ug /t
ug /r'
ug/r,
us/t
ug/t'
ug /r'
tJg /r'
rtg /r.'
ug/L
9w845 82608
9w845 82608
srir845 825',OB
9w846 825 0B
9w846 82608
sw845 8260B
sIiI845 82508
svi[846 82608
sw84 6 82608
sw845 82608
sr{846 8260B
sw846 82608
sw845 82608
sw845 82608
9w846 82608
9w845 82608
sw846 82508
sI{84 6 82608
sw846 82508
gw845 82508
sw845 82608
sw845 82508
sw845 82608
8W845 82508
gw84 6 82648
gw84 5 82508
BW84 5 82508
gY[846 82508
sw84 6 825 0B
gw84 6 82508
sw84 6 82508
sw8{16 82608
sw84 5 826 0B
sw845 82608
9w845 92608
sw84 6 82508
sw845 82608
sw846 82508
sll84 5 82508
sw846 82608
STL Denver
(ConUinued. on next page)
-38
Cl.l-eut Iot f;- - -:
PAITAIVIETER
D5r 10 01-s3
2-Butanone (I@K)
Carbon tetrachlorlde
Trichloroethene
Chloroethane
Chlorof orrn
Chloromethane
Dl"bromomet'hane
L, Z-DLbromoethane (rPg)
L ,Z-Dl-chlorobenzene
1, 3 -Dlchlorobenzene
L , 4-Dichlorobenzene
D I chl orodi f luoromet hane
L, t-Dl-chloroetlrane
L ,2-Dichloroethane
L ,z-Dlchloroethene
(tota]. )
cl-s - L, 2 -DLchloroethene
trans - L, 2 -Dlchloroethene
L ,Z-Dichloropropane
cLe - 1, 3 -Dichloropropene
Erans- 1, 3 -Dlctrloropropene
Ethylbenzene
2 -Hexanone
Methyl-ene chloride
4-MeLhyl-2-pentanone
Styrene
1, 1, l, 2 -Tetrrachloroethane
1, 1 ! 2,2-Tetrachloroethane
Tetrachloroethene
L ,2, 4 -Trichloro-
benzene
1, 1 , L-frlclrloroettrane
1 , 1 ,z-Trichloroettrane
Tr i shl o ro f I uorometlrane
L, 2, 3 - Trichloropropane
Vinyl chlorlde
Xylenes (total )
n-Butylbenzene
sec-Butylbenzene
fsopropylbenzene
t, 2, 4 -Trimethylbenzene
1, 3, 5 -Trimethylbenzene
n-Propylbenzene
tert, -Butylbenzene
2 -Chlorotoluene
HETTIOD BIJNNK REPORT
etr.lW vol-atl-Ies
Hork Order #---3 HK6IrelAA
REPORTTNG
RESTILT LIII,ITT U}rI-Tq
Itatri-r---.-.---3
METHOD
ITATER
IID
IID
IID
IID
r{D
ND
ND
ND
TUD
ND
ND
ND
ND
IID
ND
ND
ND
ND
ND
ND
ND
ND
lsD
ND
ND
TID
ND
IID
ND
5.0
l_.0
1.0
2.4
1,0
2.0
J.,0
J..0
1_0
1.0
1,0
2.0
1_-0
l_.0
1-0
J-.0
J_.0
J-,0
1.0
1.0
1.,0
5.0
l_.0
5.0
1--0
1.0
l_,0
1.0
1,0
1".0
l-.0
2.0
L.0
1.0
2.O
J-.0
l-.0
1.0
L.0
1.0
L.0
1.0
L,0
next page)
ug/t
lug/T'
ug/T'
ug/T,
ug/t
ug/t
ug/t'
ug/T"
uglt,
ug /t'
:ug/r'
ug/r,
LLg /L
:ug/t'
ug/t,
rtg / I'
ug/r,
ug/t'
ug /l'
ug/r'
:ug/t,
ug/r.
ug/r,
ug/t
ug/t
ug/L
vg /r'
ug/L
lug/r,
tJ.g /r'
vg lr'
:ug/t'
ug/r,
vg/r'
vg /r'
ug /r'
ug/r,
ug/1,
ug/t
ug/r-,
ug /I'
ug/L
ug/L
sw84 5 826 0B
sw845 82608
sr{845 82608
s$r846 82608
sw846 82608
9w845 82608
sw845 82608
9w846 82608
5111846 82608
sw846 82508
sw84 6 826 0B
gw84 6 82608
9w846 82508
sw84 5 82608
9w846 82608
9w845 82608
9w845 82508
9w845 82608
sw845 82608
sw846 82608
9w845 82608
sw8116 82608
sw84 5 82608
9w846 82608
sw845 82508
sw81r6 82608
9w846 82608
sw84 5 826 0B
9w845 82608
sw845 82608
sw84 6 82608
s[r846 82508
sw845 82608
sw84 5 826 0B
sw84 5 826 0B
sw84 6 825 0B
9w845 82608
sw845 82508
sw846 82608
sw845 82508
gw84 5 82608
sw846 82508
sw845 82608
ND
ND
ND
IUD
ND
IID
ND
t[D
t[D
}UD
ND
DID
ND
}UD
(Continued on
STL Denver 39
HEIEOD BIttrITf, RBFORT
rclilB vol.atil.es
Cl-ient Iot
PARJAIT{ETER
f . - -: D5I1-001-53
4 - ehlorotoluene
L,Z-Dibromo-3-
chloropropane (DBCP)
1, 3 -Dichloropropane
2 , Z-Dlchloropropane
1, 1-Dl"chloropropene
Hexactr]'orobutadiene
4 - Isopropyltoluene
Methyl tert*butyl ether
L, 2, 3 - Trichlorobenzene
Bromobenzene
Bromochloromethane
Naphthalene
ST}RROGATE
Dibromofluorometrhane
L, 2-Dichloroethane- d4
4 -Bromofluorobenzene
Toluene-dB
NqrB (s) t
Order S---: HKSITC1AA
REPORTTNG
VTATER
REgUIJT IrfI{IT UNITS ME:rIIOD
ND
ND
ND
ND
ND
ND
IID
ND
ND
ND
ND
IUD
PERCEI{T
RECO\IERY
ug /t'
lug/L
ug/r,
uglt
ug/T,
uglr,
ug /t'
]u.g/L
ug/r,
ug/r-,
rug/r,
ug/r,
]'O
2-A
1.0
5.O
1,0
1--O
1.0
5.0
1.0
1.0
1.0
1.0
RECO\IERY
I,IMITS
(zt L18 )
(oz L28)
( zg 118 )(zz 11r )
sw845 82608
sw846 82508
sw845 82508
svr845 82508
sw845 82608
gTI845 82508
sw846 82608
sw84 6 826 0B
sw846 82508
gw84 6 82608
9w845 82608
sw845 82608
94
91_
96
105
Calmlations Bro porforned before rounding to avoid round-off crroro In calculatod rcsulls.
STL Denver
ffi COH:rROL SAT@I,E ffi REPiORT
er,lrus volatl-J.es
Cl.l-ent Iot #- -.3
LCS Iot-ga4fle#:
Prep llate------l
kep Batd. *- -.:
Dihrtion Factor:
PARAMETER
D5r1001s3
DsI2 2AO00 -4 05
oe / 21,/ 05
526s4 06
1-
rork Orrder *-.
^Bnnlyels Date-
An,alyeLe TLme.
HK6LClAC
oe/2t/os
08: L5
!,ltratr,.x-- -- - r,- r 3 I,{ATER
Benzeue
Chf-oroberrzene
L, L-Dl-crrIorcetJrene
To].uene
I?t(frIoroethme
gI]RROGATE
ol-b rorno f 1 uorome t hane
L, 2- Dichloroethane - d4
4 -Bromofluorobenzene
to]-uene-dB
rror'E (s) :
PERCENT
RECOIfERY
9a
99
94
103
100
RECO\TERY
I-,fMfTS METHOD
(zs
(za
(ee
(zs
(7e
r_20,
118 )
L32l
118,
L22l
PERCEMT
RECOVERY
90
B7
92
LA2
sH8{6 82508
9H845 82508
sDr845 826(}8
ar845 82508
sn8{6 82508
RECO\IERY
ITfMITS
(zg 118 )(oz 128 )(ta 118)
(zt LLT l
Crlcularions are pcrformed bcfore roundiry to avold rourd-off erroffi h calculand rqrltr.
BoId print denotcs control psrurretoro
STL Denver
ffi CI)IMROL SATIPLE TTATA NPOR:r
K,ltlg vo].ati]-ee
Cf.l-ent, Lot #---:
ICS tot-Aaqfle*:
Prep llaga------I
Prep Batctr ff- -.:
Dilution Factor:
PARAMETER
D5Ir- 0 0 L53
D5r2 2AO00 -4 06
oe / 2L/ os
52654 06
1
[orlc Order *-.
Anal.yeLe Date-
AnafygLe Tr-me-
SPIKE
AI40UNT
HKSIrClAe
oe/2L/as
O8 :16
llatrl-x-,,-- -.. -! WATER
PERCE}IT
RECO\IERY IyIETTIOD
Benzene
Chf-orobenzene
1, 1-Dichl-oroethene
ToI-uene
fl-ch].oroethene
STTRROGATE
Dibromof luoromethane
l, Z-Dichloroethane- d4
4 -Bromofluorobenzene
To1uene-dB
rrCIrB (s) :
10-o
10. o
10-o
10. o
10-o
MEAST]RED
AIqOT]NT
9-r_e
9.89
9-36
10-3
10-o
PERCENUT
RECOVERY
90
87
92
102
UNITS
u.glr,
wlt,
rury,lT,
wlr-
wg/t'
RECOIJIERY
IJIMITS
(tz 1L8 )(ez 128 )(za 118)
(zz 117 )
sH8r5 82608
9H845 82508
s'H846 82508
91845 82608
sIrS{G 82608
91
99
94
103
1(}0
Crl$latlonc are perfornrctl beforc rounding to avoid round+ff errorB in calculated roruIts.
Bold print dmotos conrol prrerncteE
STL Denver 42
tEIRn gPIre geHPIrE BIrArtIATIotr REPORT
ccft,g vol.aril.es
CILLent tot *, - - :
ft8 L,ot-8aryfle *:
Date Saryt1ed---!
Prep Datg--.---i
Prep Batch #- - -:
Di].utlon Factor:
PARA}4ETER
D5I10 0153
D5I100153-O03
a9 / oel os o9 :25
oe / 2L/ os
52654 05
l-
Ilork Order #- - -:
Ilate Received- - l
enal.yoLe Ilate- - 3
nnal-ysis Time- - 3
HI(ARg1D1-M{I
HKARgLD?_MSD
oe/Lo/os
oe / 2t/ as
10: L2
l[atrbr----ro-.-3 Gv[
RPD
RPD ITIMfTS IIIETHOD
PE:RCENT
RECOVERY
RECOVERY
LIMITg(zs 12o)(zs 120)(zs 118)(78 r,r-8)(so 132)(oe L32l(za 1r-8)(za 118)
(79 L22}
(tg Lzz)
PERCEMT
BE_-g_o\rERY
92
94
86
8B
90
92
103
LO2
Benzme
Chlorobenzene
1, 1-Dicahl-onoethe,e
Tolrrene
trichLoroet,hene
STIRROGATE
DLbromo f luo rome ttrane
L, Z-Dichloroetrhane - d4
4 -Bromofluorobenzene
Toluene-d8
rurts (8) :
9(}
9r.
99
97
9s
96
101
101
95
99
811846 82508
1.3 (O-21) S18{6 82508
sH846 82608
1- I (o-2O) Ar8{5 82608
sH8{5 82508
o -92 (O-25) S1846 82508
gr8{5 82608
a -7L lO-22) St846 82508
sH8.C5 826'08
2 -2 (O-23) St846 82508
RECO\TERY
IJIMITS--
,(zg L18 )
(zs 118 )(ez 128 )(az L28)
(te 118 )(78 118 )(tz 117 )(77 117)
Calculationg are porformed before roundi;ng to evoid roud-off erors io crlculrtod resuls-
Bold print denotes conrrol parametcrs
STL Denver
}trt x SPIXE !I}INP1g DATA RBDORT
gtr.ltg vol.atiles
Client Iot fi- - - !
I,E Lot-Saryfle *:
Ilate Sary>Ied-.-3
Prep Datg----.-3
Prep Batch *. - - 3
Dil.rrtion Faetor:
PARAMETER
Dsr1001.53
Dsrr_00r.53-003
oe/ae/os aez2s
0e / 2L/ 0s
s2654 0 5
1
Ilork Order *. - - 3
Date Receirred,- - 3
anaaygis Date-.3
Bnalysis Timc- - l
HI(AR9lD1-ti{S
HIGR9LD?_MSD
ae/Lo/as
ae/2L/os
1O:L2
Ilatri:r- . . ) ) ). - - I GTf
SAII{PLE SPTI(E ME,ASRD
AlYlOI}NT AItr AIIIOI'MT UNTTS
PERCNT
REC\IRY RPD METHOD
Beuzene
Ctrlorobenzene
I-, L-DieJrl-oroetlene
Iloluene
Trichloroethene
SURROGATE
D ib r omo f 1 uorome ttran e
L, 2- Pl-chloroethane - da
4 -Bromofluorobenzene
Toluene-dB
NCrIts (S} :
IID 10. O
ITD 10. O
ITD 10. O
rD 10_o
ITD I.O. O
IID 1O-O
IID I.O - O
ITD 1O-O
IID 10. O
ITD 10. O
8 -97 uigll'
9 - 09 uglt,
9 - 89 rugll'
9 -zL urglL
9 - 5(} utglt
9 - 58 utgll'
10 - 1 vglt'
10 - 1 rug/t'
9 - 54 ruglL
9 - 85 ug/r,
PERCE}.IT
RECO\TERY
92
94
85
88
90
92
103
LA2
9w846 82508
1- 3 SW845 826(}8
sw846 82508
1-8 91846 825(}8
sw846 82608
a -92 grr845 825(}8
gtI845 82508
o - 71 gtl846 825(}8
gH8{6 82508
2 -2 9W846 826(,8
90
91
99
97
9s
96
101
101
96
99
RECO\IERY
IJTMTTg
(73 118)
(73 118 )
Gz 1zB )(52 L28l
0e 118 )(za 11s)(zz 1r.z)
(tz 117 )
Crlctrtrtiong aro perfornrcd bcforc rotrndlng to rvoid round+ff errorB in calculatcd rcsulrg.
Bold pdnt denorcs control perrmerens
STL Denver 44
TiETEOD BITIT REPORT
Tt'gtrL lrtrotal-a
Cl-Lent Itot I- - -: D5I100153
REPORTING
PAR.EI{ETM RESI'IJT IJIMIT UNITS MEfiIOD
liatrtx- - - - o . o . - : $IATER
PREPARLTION- WORK
AI{ALYSIS DATE ORDER *
ItlB Iot-Aaq[e *: D5I220000-190 Prqr BatcD. *---: 5265180
cadmium ND O.0o1o ng/t, sw845 5020 Og/Zl-Og/27/OS HK5DA1AA
DLlutim Factor: I
ADaIyalB Tl.me.. : 03 :56
selenium ND 0.0ozo trq/T, swsc6 G020 og/zt-aglzz/os HK5DAIAC
DLlutsIon Factor; 1
.e,aalyais Tino, - : 03:56
UB Iot-saryile *: D5I22O0AO-222 kep Batsc:h *-,,: 5265222aLuminum ND o-10 tns/r, swg{G G0108 o9/23-o9/26/os HK5KoIAN
Dllutlor Eactor: 1
.Boalysia Timc.. : 19:05
Arsentc ND o.o1s wlL sw846 GoloB og/zz-og/27/a5 HKsKclAp
DLlution Factor: 1
Ilralyc,.s Tlme..: 11:03
Barirun DID 0 - O1o filg'/t svrg46 60108
Dilutioa PaCtOr: 1
Analyeia TimG..: 11:03
os /23 - o s / 27 / asHKsKctt
calcium I{D 0.20 tfts/L swg45 60108 o9/23-09/26/as IIKsKG1Ao
DllutloB Pactor: 1
Analyels Tlme-.: 19:05
chromium ND 0.010 tg'/L gwg46 60108 og/zt-og/zz/os HKsKGtr-aR
Dilutloa tractor: 1
ADEIyEiE Tlme..: 11:03
eopper ND 0.0r.0 nq./r, swgrc 5o1oB og/zz-og/22/as HK5KGIAT
Dilutlon Factor: 1
Analy8la Timc..: 11:03
rron ND o.1o trrs/L slr84c Go10B 09/23-09/26/05 HKSKGaAI
DllutloD FacCoE: 1
Aaalyale tims.-: 19:06
Iead ND 0.0030 ngh, sr,ls46 60108 oglx-aglztlos ffisr{cllv
Dllution Factor: 1
.lnalyel-a Tine. . : 11: 03
STL Denver
(ContJ-nued on next page)
45
I{HTEU) BIfrITK REgORT
TCIIhL Hetsa1s
Cl.ient Iot
PARAMETER
liatrix-: SIATER
REPORTING PREPARATION-
AI.IAIJYSfS DATE
WORI(
ORDER. #I,IMTT UNIT9 METHOD
Magrnesirrrn
Nlckel
Potaeslum
Sl1ver
Sodium
O.2O rW/I'
Pllutlon Fector: 1
Analyaia Time. . : 19: 05
0. O4O nry,/L
Dl"Iution f,'actor: I
Analyale Tima. -: 11:03
3 . O r*S/L'
nl-lutlon Factor: 1
.Dna1-ysie Time - - : 19:O6
0. O1O rng/r,
Dilutiorr Factor: 1
Analyels Tl-me- - : 11 : 03
5 . 0 tttg/I'
PLlutlon Factor: l-
nnalyele Tltne. . : 19 : 06
0 - 010 mg/T'
Dl-IuE,lon Fact'or: 1
Analysia Time.,: 11:03
0.020 mg/L
Dilution Faetor: 1
Analysls Tlme. - : 11: O3
0,0L5 mg/T,
DLlutl,on Factor: 1
Aoalyeie Time.-: 19:O5
9w845 50108
sv[84 5 50108
sw846 60L08
sw845 50108
sw845 60108
sw846 60108
52663 3 5
sw846 7474A
sw846 60L0B oe / 23 -oe / zG / os HKSKG1A3
sv[845 6010B oe / 23 -o e / 27 / os HKSKcIAUND
}UD
}UD
llD
ND
09 / 23 -o e / zs / os HKsKGIA.z
og / 23 -o e /zt / os HK5KGLjaDl
ae /23-oe /26 / as HKSKGIA{
a9 / 23 - o s / zz / as HKsKGtuLw
oe / zl-oe /27 / os HKsKclet(
oe / 23 -o e lze I os HKSKGIAs
ae/26/os HK94T1AA
*: D5I230000-335' Prep Batcft *-, . !
ND 0.00020 wtg/L
Dllutl-on Factor: 1
Analysia Time..: L8:55
O vanadlum
ZLnc
zl-rconium
llB lot-8ary>Ie
Mercury
rurE (8) :
f;---: D5f100153
RESULT
Calculatlons ere pcrforrned beforo roundlng rc avoll rourd-off errors in calctrlatcd roults.
STL Denver 46
ffi eCI[IlROfr BAIIPLB EIIALIIATIOII R]BBORT
aUTAL !&taIe
Cf.ieut f.ot #- - -:
PARAMETER
Dsr10 01_53
PERCEUT RECO\IERY
RECOVERY ITIMITS METI{OD
D5I22OO0O-L80 fep Batch *- - - ! 52651,80
Hatrix - - -, - - - - - : WATER
PREPARATION-
A}IAIJYSIS DATE WORK ORDER *
I'CS Iot-garyl1e*:
Cadrnium
Selenium
If,g lot-garyr1e#:
9l-lver
Aluminum
Arsenic
Barium
Ctrromium
Copper
NLcke1
I-read
Vanadium
Zinc
Caleium
(eg r.1o) sw845 6020
Pi]-uEion Factor: 1
(82 LLz) SW845 602A
DLlution Factor: 1
oe / 23 - oe / 27 / as HKSDAI-AD
Time.-: Od:OO
oe / 23 - oe / 27 / os HKSDAIAE
Timg,.: O4:00
97
94
100
98
99
106
98
L0L
99
100
l,00
93
92
Analyeie
nnalyole
D5I220000-222 tteB Batclt f;. - -: 5265222
(85 LL4) SW845 60108 09 /23-oe / zt /as HKsKcllA6
Dllution Factor t 1 Analyal.o Tl-me..: 11 :08
(86 108) SW846 60108 oe / 23 -ae / ze / as HKSKGLAT
Dllutlon Factror: I nnalyeie rl-me- - : 19 : 10
(89 109) Sw845 501-08 ae / zJ - ae / 27 I as HKSKGIAB
Diluf,ion Faetor: t AnaLysie Tl-me- - : l"L : 08
( gg L 1-3 ) SW845 60r.08 09 / zt - ae / 27 / os HI<sKGIAe
DilutLon Factor: 1-Aoalysls Tlme..: 11;08
(ag LL2) SW846 50108 oe /23-09 /zt /os HKSKGIcA
Dilut,l-on Factor; 1 Aaalysis Time. - : 11: OB
(8S 110) Sw845 60108 09 / 23 -oe / 27 / os HKsKGlce
Dllutlon Factor; 1 Rnalyele Tlme. - : 11: OB
(go 110) sw846 60108 oe / 23- oe / zt / os IrKsKGlcD
Dl,Iutl,on Factor; L Analysia T1.me--: 11:oB
(gr 111) swg46 GoloB 09 /23-a9 127 fas HKsKclcE
Dilution Factor: 1 Analyo!.e Tlme. . : 1L : 08
(88 LLz) SW845 5o1oB oe /23-09 /27 / as HKsKGlcF
Dilution Faetor: 1 Analysis Tl,me. . : 11 : 08
(Bs 1L0) SW846 60L08 ae /23-ae/27 /as HKSKGICG
Dilution Factor: 1
(sg 110) sw846
ollutlou FaeEorl 1
(Continued on
Analyel-a Time. . : 11, r 08
5o1oB as 123 -o s 126 los HIGKGIcH
.hnalysie Time. . : 19: 10
next page)
STL Denver 47
ffi COIFIROIT geHPLB EIIAITUhTIOX RBPORT
IlCtrAIr }tretaf e
Client, Lot *- - -: D5I100153 t{atri:r- - - . o r . - - ! [![ATER
PREPARJI,TION-
ANATJYSIS DATE }TORK ORDER #
PERCENT RECO\IERY
PARAIUETER R.ECOVERY IJTMTTS MEIIIOD
Iron ro2 (BB - 110) sw846 GoloB og/zs-og/ze/os HKsKGlc.T
Dilutio[ Fector: 1 Ina]yele Tlne.-: 19:10
Potaseium 101 (S5 - 11l) grf846 5O10B OS/ZZ-OS|ZO/OS srSrCrCX
ollucion Pactor: 1 Analyale Tlme..; 19:10
Magmealum 99 (91 - 1r-1) svrg46 d0108 og/zl-og/ze /os nxsKolcrr
Sodlum
pllutlon Factori 1 Inalyele Tlne..: 19:10
106 (91 - 112) sw845 60108 oglzs-og/ze/os IIK5KG,].CI{
pilution Factor: 1 enalyeLe Tlme.. r 00;42
zlrconl-um 101 (7s - 125) swB4G 60108 og/zl-og/ze/os HK5KGIcN
Dilution fector! 1 Analysle flrne..: 19:10
I,cS Iot-Aaqrle*: D5I230000-336 Prep Batclr *.--: 5266336
Mercury 100 (85 - 114) SW846 747OA OS/ZS/OS rrK94T1AC
Dilutl-on Fector: 1 laalyel.e Tlme..; 18:56
rurB(a):
Calculttions ore perforrnod before rourding to avoid rourd-off crrors in celculatsd reBultt.
STL Denver 48
ffi
Cl-ient Iot *- -.: D5f100153
SPTI(E MEASTIRED
PARiAMETER A}IOI}NIT AMOU!(T I}NITS
COIITROL A,BUPLE DAItr
1r0TAIT ltetaLe
PERCNT
REer\,fRY MEISIOD
REPORT
liatrtr---r-----3
PREPARATTON-
AI{AIJYSTS DATE
ICS lot-Saryfl-e*: D5I22OO0O-180 PTeI, Bat(t *- - -: 5265180
CadmLum o.04oo o.o38g rns/r, 97 sw846 6020
Dilution Factor: 1 Aoalysie Tlme..:
8W845 6020Selenium0,0400 0. O3?5 W/L 94
Dilution Factor: 1 lDalyaJ.a Timc..:
I,Cg l,ot-Saqrte*: D5I22OOOO-222 Pre5r Bateh *- - -: 5265222
Sl-lver 0.0500 0.0502 ,tg/f' 1OO SWBrt6 60108
o:llut,Lon PacEor: 1 lEa1yels tJ.me- - :
Al-uminum 2.00 1.95 rrrs/L 98 SWS46 60108
Dilution Eactor: 1 tlalyaia Tlnc..:
ArBenLc 2.00 1.98 l,/q/t 99 sw846 60108
Dilutsion tractorr 1 Aaa].yeie rime,-:
Barlum 2.00 2 -L2 lllg/t 106 Syr846 60108
Dilut,ion Pactor: 1 Arre1yrl.a Time.,:
chromlum o-20o 0.196 l[|ls/t 9g sTI846 50108
Dllutlon Fectar; 1 Aralyele ffure..:
copper o.a50 0.253 rrrSh, 1o1 swa46 GoloB
Dilution Pactor: 1 .lnalyeie Timc..:
Nickel 0 .500 o . t194 l[lq,/t 99 sw846 60108
olluEiom Factor: 1 lnalysJ.a Tlme..:
r,ead 0,500 0.498 r|q,/r, 1oo sy{846 50108
Dl.IuELon Factor: 1 .lnalyeie Time..;
vanadium 0.500 0.498 r{lg/L loo sw846 60108
Dllut.l,on Factor: 1 lnalyal,a Tlrae..:
zinc o.soo 0.4d5 \g/T. 93 sws46 60108
Dl1utsj.or Factor: 1 Anatyste TLme..:
Ca1ej.um, s0.0 46. o rqh 92 swg46 60108
DllutloD Pactor: 1 Analyaia Time,.:
(Continued on next page)
ae/23-oe/27/as
OaI : OO
oe/zt-ae/27/as
04:00
ae/23-oe/27/as
11: 08
oe/23roe/zslos
L9: 10
oe/23-oe/27/os
1,1 : O8
11,o0;
/zz-oe /zz/os
11, 0089
/ zl'o9 / 2z / as
,,, oo,g
/ zl- 09 / zz / os
oe/23-oe/27 /os
11: OB
oe/23-oe lzz/os
11; 08
oe/23-ae/zz/os
1-1: 08
ae/23-oe/27/os
L1: 08
HKsKel-Ae o
HKsKG].CA
HK5KG].CC
TTKsKG1CD
HKsKG1CE
I{KsKG1CF
HK5KG1CG}
Hn6ltctc[
WATER
WORK
oRpF.R. #
}IK5DAlAD
HK5DAIAE
HKsKGT1A5
HK5KG1A7
HK5KG1A8
aglx-oe lxlos
19: 1O
STL Denver
Clieut Irot
PARAMETER
*-.-: D5I100153
SPIIG MEAST'RED
AMOUNT AIqOUMT
W
IINITS
CUYIROL SAIIPLB
IICIIAL Hetnl g
PERCI.IT
RECXIRY METHOD
DA:[A RBPORT
Irlatrfuro - - - , ! - . . !
PREPARATTON-
AI{ALYSIS DATE
WATER
WORK
ORDER #
Iron
Potasstun
Magnesiunr
Sodium
ZLrconlum
lrlercury
IrcITE (S} :
L.oo L.02
50-0
50. 0
50. o
0.500
50 .7
49.3
53.L
0 .507
mg /T, Loz
Dllutslon Factor: 1
mg/r, 101
Dl-lutlon Factor: l"
mg/L ee
Oilutlon Factor: 1
mg/1, 106
Dl-Iut,l-on Factor: 1
mg /T. 101
ghr845 60108
Analysla TJ;ne. . ;
sw845 60108
Analyeia Timc-.:
sw84 6 6 0108
Analyais Time. . :
sr{845 50108
Ana)-yeie Tl,me. . :
sw84 6 50108
Analyeie Tl-me- -:
52663s 5
sv[846 74704
Analyeie TLme-.:
09 /23 - o 9 /26 / os HKSKOIC,J
19:1O
oe /23-oe / zs / os HKSKolcK
19 :1O
ae / zt- oe / ze / os uKsKolcr,
L9: 10
a9 / 23 -o 9 / 28 / as HKsKclcrvl
00:{2
oe / 23 - o e / 26 / os nrsKcll-cll
L9:L0
oe/26/os
18r56
HK94T1AC
DllutLon Factor: 1
IfS t,ot-8aqr1e*: D5I23OO0O-335 ftep Batch *- - -:
0.00500 0.00501 mg/L 100
DllutLou EacEor: 1
Calcuhtlons Bre porforrred Moro rounding to avoid round-off crrorr in calculatcd rcmlts.
STL Denver 50
C]-ient Iot *- - -: D5IL001-53
Date llaryrled- - . i A9 / 09 / OS 09 :25
PANAMETER
PERCEI{ T RECOVERY
RECO\IERY I,IMTTS
IIILIRIT SPTffi SATTPI.B ffi RBPORT
Tgf,AL l{eta-I-s
Ilate Recel-ved- - 3 A9 / LO / Os
RPD
RPD IJTMITS METHOD
Irlatrix-
PREPARATTON- WORK
AIiTAIJYSIS DATE ORDER #
Itg lot-Saryr1e #:
Cadmiurn 97
99
Selenium LA2
109
Hg Ipt-Sary>Ie #:
Aluminum 109
108
Arsenlc LO7
109
BarJ-um 101
L03
Calcium 85
9L
Chronriurn 97
98
Copper 108
110
D5I100153-003 Prep Bateh
(8g 1L0)
*---t 5265180
(gg 1.1,0) 1.4 (O-2Ol
oilution Factor: 5
Anal-ysls TLme. . : 0{ :{0
(82 LLz)
(sz tIz) 5. B (O-zal
Diluuj.orr Factor: 5
Analyal.e TimE, , : 04 :4 0
D5I100153-003 IEep Batch *- -(er 11e)(ss 1Le) 0.26 (o-Zsl
Dllut lon D'actsor: 1
enalyeis Timc.-: 19:5I
(sc Lzl)
(g+ L24) 1.9 (O- zsl
Dl,Iutrl,on Factor: 1
analyeis Tl-me. - ; 12 : l-3
(ss 12o)(ss 1-20) L.7 (o-2s)
Pll-utLon Factor: 1
AnalyaLa Tl-me. . : 12 r 1.3
(es 1s3 )(+a 153) 1,9 (O-zsl.
Dilutlon Factsor; I-
Analyels fLme.-: 19:51
(zs 1,3 s )(tt 13s) 1.3 (O-2s)
DI-IuE,Lon F'aetor: 1
Analyel-e Tlme. . : 12 : 1-3
(ez L29)
$z a l.2gl z.o (o- zsl
ollut,l.on Faetor: 1
AnalygJ.B TLme. . : L2 : 13
oe /23 -o e /27 / as HKAReLcz
ae/23-ae /27 / as HKARelc3
oe /23 -o 9 / 27 / os HKAR91C4
oe / 23 - o 9 / 27 / as HKARglcs
oe / 23 -o e /za / os HKAReIDM
09 /23 - o e /26/ os HKAReIDN
os /23 -o s /27 / as HKAReIDP Ooe/23-oe /zz /os HKAReIDQ
09 / 23-ae /zt / os HKARSIDR
oe / 23 -oe / 27 / os HInReIDT
oe /23 -o e I zs / os HKAReIcK
oe / 23 -o 9 / 26 / as HI(AReLCrr
oe /23 -o e I 27 / os HKAReIDU
oe /23*o 9 / 27 / os HI(ARSIDv
HKARgl-DW
Ilffif,gIDII
sw845 6020
st{845 5020
sw846 5020
sur8115 6 02 0
: 5265222
sw845 50108
sw84 5 50108
gw84 6
slrE{ 5
6 01_ 0B
50L0B
gw84 6
sw84 6
6 01_ 08
50L0B
sT{84 6
sw845
601_ 0B
50108
sw84 6
sw845
5 0108
5 01.08
sw846
SI'184 6
60108
50108
oe/23-ae/27 los
oglzt-oe ln lf,s
STL Denver
(Continued on next, page)
ItHtRIf gPfXB BaI{PLB EIru}InTIOI RBPORT
Cl.lent Iot #-,
Date garyrled,. -
PAR;AI"IETER
Iron
D5I1_0 0 L53
09 / 09 / os o9 :25 Date
IIOIDAII llbtaf.s
Reeeirrcd-,3 og/La/As
tltatri:x, - r, - - - . -. i gr[
PREPARATTON- WORK
AIIIAI,YSTF- DATE ORDER #
oe /23 - o e / 2e / as HKAReIcM
a9 / 23 - o e / 26 / as HI(ARelcr.r
oe / 23- oe / 2? / os HKAReIcA
oe / 23- oe / zt / os HKAReI-cc
oe / 23 -oe / 26 / os HI(ARe lcR
oe / 23 -09 / ze / os HICARglcr
oe /z3-oe /27 /os HKAReIAB
ae / 23 - o9 / 27 / Os Hr(ARe lAe
oe / 23 - o e / 26 / os HI(ARelcP
ae /23 -o 9 / 26 / Os Hr(AR9lCQ
ae /23 -oe / 27 / as HKAReIDK
ae / 23 -o9 / 27 / os HKARgtDrr
oe / 23 - 09 / 26 / as HKARS lctr
ae / 23 -oe / 26 / as HKARels\r
ae / 23 - oe / zt / os HKARei.cD
oe /23-oe /27 / os HKAReICE
ba l rl - 0 9 h1 l 0E III{m010r'
PERCEI{T RECOVERY
RECOV-ERY IJIMITS
89
93
(eg
(sg
RPD
IJIMITS MHITIOD
$z 1ss ) sw846 601-08
(sz L55) 3.5 (O-251 SlI845 60L08
DllutLon Factor: 1
Analysl-s Tl-me - - : I-9 : 51
RPD
Magnesirrrr
Niclcel
LO2
L03
91
95
96
98
r-14
1L6
98
99
(62
(sz
( 8e 72A')
(aa
fie
(ts
121)
LzL) 1.3 (O-2s)
Di].utlon Factor: 1
Inalyaia TimG..: 12:13
1_45)
L45) 1.4 (O-2s)
Dl-lutlon Fact,or: 1
Analyeie Tim€,.: 19:51
sw846 60108
sw845 60108
sw845 50108
sw845 50108
sT[845 60108
sw845 60108
slr845 50108
sw846 50108
sw846 50108
sw845 501-08
Er,r0td d0100
sI{845 5 010B
O Potaseium
Silver
Sodium
vanadium
LzA) 1.9 (O-2s)
Dilutlon Factor: 1
Analyeie Time--: 12:13
132)
L32 l L.7 ( O- zsl
Dl-lutl-on Factor: 1
analyeie Time,.I 19:51
NC, MSB
NC, MSB
( 75 141) Sri[84 5 5O1OB
fis 141) 2.0 (O-25',' SW846 60108
Dilution Factor: 1
Analysle TLme.. : t2:13
(to 2a3) sw845 60108(to 203) (o-40) sT{845 50108
Dllutl-on Factor: L
Analyele Tl-me. . ; 19: 51
0d
98
(8s 120)
(8s L2O) 1. s (O-2s)
Dilutlon tr'actor: 1
Analyels Tlme..: 12r13
11 7)
L37 ) 2. 0 (O- 251
Dilutlon Factor: L
Analyeis Time..: 12:13
{eo
(oo
STL Denver
(Contlnued on next page)
ae / 23 -oe /27 / as HKAReICG
52
C1Lent Lot *-
Date 8aryll-ed-
PARAIVIETER
ZLrconlum
Ug lot-Sanp1e #:
Mereury 92
92
PERCEMT RECO\IERY
EU-COT\IERY r,rldITg RPD
1-01
102
RPD
LTMITS METHOD
T&IR,IX SPIXG 6A}TPIJB BIIBLINTIOII REPORT
IICIDAIT lletal.e
: DsI100153
: og/ag/os o9:25 rlate Received--3 og/Io/o5
uatri:roO-----.-3 GVI
PREPAR'LTTON- WORK
ANAr,Ys Tg . DATE ORDER-..#
09 / 23 - a9 / 25 / as HKARe Lct!I
ae / 23 -ae / 26 / as HKARelcx
09 /2e / os HKAR9ICH
oe lzs / os HKARe l.cir
(ao Lzo) sw845 60108
(eo L20) 0,45 (o-25) SW846 60108
Dllutl.on Factor: l-
^Rna1yslg Tlme. . : 19 ; 51
Dsf 100153-003 kep Batclr *- -(8s 114)
(es 114) 0.49 (O-10)
Dilution Factor: 1
Analysie TimG..: 19:05
: 5 2663 36
sw845 7470A
9w845 74-70A
rcrS(s):
CalqrtrdotB lle performod Dcfore rourding to avoid round-otf crrors in calcndaiEd rcsrb.
NC Thc rgoovert 8od/or nPD wtrc not calcrila&d. !
MSB Thc reoovcty and RPD ucre not cahlhtod bcc8use the sanplc amout wae jrcater than four timcs the ryiko unouat.
STL Denver
IATREf,' SPIE geUPIrB IIXIA RBBOIUI
IICIEAT Uetals
ClLent Iot t-. -: D5I100153 tlatrir. -. -: OW
Date 8aqfled---= O9/O9/AS 09:25 Date R€ceived- -r og/Lo/os
SAITTPI,E SPIKE MEA^SRD PERCI{T PREPARATTON- TIORK
PARAMETER A!@UIIIT A!,tT AIr{OIINT IINITS RECVRY RPD METHOD A}IALY8IS DATE ORDER #
INS lot-Saqr]-e. *: D5I1OO153-003 ltep Batd, *-.,: 5255180
Cadmium
ND O.O4OO O.O391 wts/t s7 9W846 5O2O Ogln-Ogl?lli, HKAR91C2
ND O.O4OO 0.0396 fig,/r, ss 1.4 9W846 6020 O9/23-O9/27/O5 HKAR91C3
Dilutioo Factor: 5
Aualyeia Timc. . : Otl:{0
Selenium
llD o.o4o0 o.o4o9 ilq,/t 102 sw846 6020 o9l8-09/27/o5 HKAR91q4
ND 0.0400 0.0437 IIIls/t, 1o9 6.8 SW846 6020 O9/23-O9/27/O5 HKAR91C5
Di]-ution Factor: 5
Aoalysle Tlme..: Ol;{0
ldS llot-Saq)I.e *: D5I100153-oO3 Prep Batch *-..: 5255222
Ahuninum
llD 2.oo 2.Lg rg,h, 109 sn845 60108 09/23-09/26/A5 HKAR91DM
ND z.o0 z.Lg n:g,/T, 108 o-28 9w846 60108 o9/zg-09/26/os HtraR91DN
DllutLotr Eactor: 1
Ao8lysl6 Tlme..: a9:51
Arsenlc
o.01s 2-oo 2.16 mg/r, 107 SW845 5O1oB A9/23-09/27105 HKAR91DP
o.01s z.oa 2.2o nE,/r. 109 L.s sw846 60108 O9/23-O9/27/OS HKAR91DQ
Dilutslon Psctor: 1
Aoalyeia T!re,.: 12:13
Barlum
o.21 2.oo 2.22 rrg/t 101 swB4G 60108 a9/n-a9/27/as HKAR91DR
o.21 2.OO 2.26 ,0rls/r, ,103 1-7 SW846 60108 O9/23-O9/27l05 HKAR91DT
Dllut.lon FacEor: t
Aaalyaia Tima.-: 12:13
Calcium
I.to so-o L49 lftrS/r, Bs 9w846 60108 o9/23*os/26/os HKAReICK
110 so.o 1sl \q/L 91 1.9 Sr{846 60108 A9/23-09/26/Os HKAR91Cr,
Dilutsion Factor: 1
AnalyBis Tima..: 19:51
Chromium
llD 0.200 0.194 rrg/L 97 SW846 50108 O9/23-09/27lOs HKAR91DU
luD 0.200 0.195 ng,/r, 98 1.3 SW845 50108 Oeln-A9/27l05 HT(AR91DV
Dllutloa Pactor: 1
Ioalyois Time..: 12:13
STL Denver
(Conti-nued on next page)
54
rfiLASIT SPIE SAUELB DBM,. REBORT
TOf,AIJ tletals
Client Iot *- - -: D5r100153
SAIIIPLE 9PIKE
PARAMETM AITIOUNT AIvIT
MEASRD
A!{OUMT UNTTS
PERCMT
REC\TRY RPD IVIETHOD
l{atri-:x- - - - - - - - - 3 GW
PREPARATTON- WORK
AI{AIJYSIS DATE ORDER #
Copper
Iron
Iread
Magrresr,urn
Nickel
PotassLum
9l-Iver
0.020 0 _ 250
0.020 0.250
0.290 tftg/T,
A .296 ng/l'
DL1utl-on Factor:
Analyols Tl.me. . :
1. 09 ng,lT,
L . L3 ng/t
Dllutlon Factor:
Arra1yEie Ti[t€. . ;
L3 0 wry./L
L32 W/r,
Dilutl,on Factor:
Analysl.s Tlme. . ;
O.484 rng/L
0 - 494 mg/L
Dilution Faetorr
Analysis Time. - :
L23 nq /1,
Lzs mg/t,
Dilution FacLor:
Arralyeie TJ.m€. . :
108
LL0 2.A
1
12: 13
89
93
1
19: 51
LO2
103
1
r.? : 13
9I,
95
1
19;51
96
98
1
a2:L3
LA2
L07
1
19:5L
1 1,4
115
1
12: 13
sw845 60108
gw84 6 6 0108
sw84 6 50108
3.5 9I{846 50108
sTtg46 50r.08
1.3 SW846 60108
oe / 23 -o9 / 27 / os HKAR9IDL
ae/23-oe 127 /as HKAReIDx
ae/23-oe /ze /os HI(ARercTut
oe / 23 -og / 26 / as HKARSIcN
oe / 23- Oe / 27 / Os HKAReICA
oe / 23 -oe / 27 / as HlcaRelec
o - 20
0.20
ND
IID
84
84
-72
72
ND
IUD
t.oo
1. OO
50.0
s0-o
50. o
50. o
0,500 0.5J.0 n:q./t'
0.500 0.517 mg/1,
Dilution Factor:
^RualyeJ.e Tl.trre, . :
svr846 50108 Osl23*Os/26 OS "r.O"aL-4 sW8{560108 O9/23-oe/25/as HKARflIET
0 - 0a2t 0.500
o. 0021 0.500
sw845 60L08
1.9 SWg46 50LOB
sw846 6010B
L.7 grIB45 60L08
9w845 50108
2.4 SWB46 60L08
ae / 23 -o9 / 27 / os HKAR91A8
a9 / 23 - o e /27 / as HI(AReIAe
09 / zs - oe / za / as HI(ARSIcP
oe / 23 -o9 /2e / as HKAReI-CQ
a9 / 23 - 09 / 27 / os HKARe I-DK
09 / 2i - oe / 27 / os HKARe IDIJ
0.0500 0.0572 mg/t,
0. 0500 0 . 0584 mg/r,
Dl-Iutlon Faetor:
Analyeie TLme. .:
(Continued on next page)
o
STL Denver 55
IAASIX SPIIE sIHPtlE I}ATA REPffiT
lUf,lL }letaf.s
Cll-ent Iot *. - -: D5I100153 fhtri-x- -. -: GW
Date Saqrled.--: O9/o9 lo5 o9:25 Date, Recelved.--. O,/LO/O5
SAMPIJE SPIKE MEA.SRD PERCNT PREPARATION- WORK
PA.RAIIETER AMOITI{T AII{T AITiOI]NT t IIrTs REC\rRY RPD MBTHOD _ ANAITY8E? DATE ORDER #
Sodlum
1700 so.o 1710 $gh, sw845 5O1OB O9/23-Oe/26/05 TIKAR91CU
Quatifiers: IiIC,MSB
t7oo so-o 7-760 tts/r, sw845 5o1oB a9/n-a9/26/05 IIKAReICI/
QuallfLerB: NC,M8B
Dilution tra.ctor: 1
Analyela Tl.me.. : 19151
Vanadium
rlD o.soo 0.489 trls/r, e8 sw8.{6 60108 o9/23-o9/27/Os HKAR9ICD
ND 0-500 0.496 r.g,/t 99 1.s swg46 Gor.oB o9/23-o9/27/as HKARSIcE
D11ut.lon Bactor: 1
AtraIyElB TLne..: 12:13
ZLnc
0,01s o.soo o.4es rytlr, 96 swg46 60108 09/23-09/22/05 HKARSIcF
0.01s o.soo o.sos rs/r, eB 2-o sws4c Gor.oB 09/23-09/27/os HI0[R91cc
Dl]'utl.@ PBctor: 1
Analyeis flme..: L2:13
Zlrconirun
o-00s8 o.5oo o.s12 r:g/r, 101 sw846 60108 o9/n*a9/25105 HKAR9T.C'L
0.00s8 0,500 0.514 rq/n ]-az o.4s sw8{5 60108 oe/23-09/26/os EirAR9ICX
Dilutiorr Factor: 1
Ualyeie Time.. t 19:51
Il8 I'ot-Saqr1e *: D5I100153-003 I*ep Batch I---: 5266336
Mercur.y
ND O.OO5OO O.OOaSr mglr, 92 SW846 747OA 09/26105 rrKARgleH
ND O.OO5OO 0-00461 mg/rr 92 0.(19 SW845 747OA 09126/05 HKARglCir
Dl.lutLo! raecorr I
)loalyaie Ti-n6.. : 19:Oi
lElts(S): _
Celculations arc pcrfonncd before roundlol to rvoid rotmd-off crore In olcutltcd rc6ults.
NC The recovery rdlor RPD wtrc not crloilrtcd.
MSB Thc rccovery srld XPD x,d€ not csf6lhted bccau$c tbe slrqlc amouil we3 gt t€r &rn four rtne &c ryikc .mour$,
STL Denver 55
STL DENVER
Contraets:
LaL Codcr
EIOW No.:
Total Metals AnalYsis
COVER PAGE . INORCAI\IC ATIALYSIS DATA PACKAGE
frRg CorlroratsLon
STLDE}I Cagc trIo. :
SDG No. r
S.Lg No. r
Dsr1001s3
saryrLs rT!:
GgiI-58-090905
LaIr Sarq>Ie No.
Dsr 10 01s3 -0 0{
GV[-5D-090905 Dsr10 01s3 - O0 5
GRir-7C-090905 DsrX.0 0153 - 008
Ger-Nl- 0909 05 Dsr 10 0153 - 003
G[,iI-N1-090905 ]IS D5r100153-0039
G$[-N1-090905 MgD Dsr100153-0039D
GW-Ng1-090905 Dsr 100153- OO2
G3{I-S5-OgOg 05 D51100153-006
Wcre IeP Lntcrclcncnt oorrectiorra rppl.l-cd?
Wertr IeP baclcgrorrnd correctiona appl.Lcd?
If yGa-lrorc rrw data grcnontcd bcforc
ap5l1.Lcation of blokground corrcet,ion;?
rca/lilo YES
Iaa/No t,ES
YaelNo
Comrcutg:
r corulfy that thia drta Daclcage it iu oo@Ilance rtth the tenoa endl conoitionc of tsheoontract, both tcchnicrlly and lor conDlet.r.rr, for othcr thtD eh6 condltLou dlGtrllodabovc. R(rlea3. of tha d,atr cortrlucd Ln thlr hardcoDy data gechgr rnd iu thr coogrtcr-r.adablc data
Bubmittcd on llolrDy d,l.ahcttsc has been ruttrorlzcd by thG Liborator-lf lllragror or th6 ltrnagGr.a dcallrncc, aavrrLficd b5ir th. lollorrlng cigDrturc.
Eligmatura;
Date:
Narue: De6 KeUfuLa
rltle3 Data Analyat
STL Denver
lo lt lcE
CO\IER PAGE - III
STL DENYER
o
. Con
LrL
Total Metals Anslvsis
-2A-
INI'I'IAL A}ID CONTINT]ING CALIBRATION VERIFICATION
trnct3 tlRS Corporrtsion
Codc: STLDmiI Cagc rlo - r A.[8 ![o. 3 sDo No.: D5I100153
tnitir1 Callbratsion gourocr
Cont,inu:Lng Ca]-lbratlou Bouree:
Higrh hrrity, SIlcx
InorganLo Vanturor
Concerrtsrat,l-on Unier r ngr/L
lna].frtcl
-lrit{a} CelibratLon
Tnre rorrnd esR ( 1)
Contl-nulug CalibratLon
Tnre g'ound ,6R ( 1 ) Found, tR ( 1)![
L].uminum :l
A].umLnrrm :l 40.
I cal-,oLum r. I I
50.0
I I s.ol
0,4951 99.0
{8.9 97 .9
I I s.o{lroo.Blpl
0 ,50
38.75 96.9
Calci.rrm II I {0.39.90 97 .2
Iron lro I
rron III- I 40.39 .01 97 -5
PotaseLun I
luasnesi.*l I I
50. o
50. o
I zo,ol I
50. 0
0 .50
{9-5 gg,2
{9.0 98.1
0 .511 LA? -2
50 .12 100 ,2
19.6{l 98.2 | r
[_S_oAium r,o I 5.O I s.ocl101.2lPl
Sod,lum ni I {0.0
I ztrconiunl I
38.93 97 .3 50 .0
I o.so I
50, 19 100 .4
o.dg{l 9B.B I r
( 1) Control rrLnLt, s r McrcurT 80-1201 Otber Motalr 90-1101 Clranide 85-115
STL Denver Porm II (Part 1} IN 58
STL DENVER
Total Metals Analvsis
-2A-
INITIAL AND CONTINTJING CALIBRATION V}:RTF'ICATION
Contsract: IIRS Corporatlon
frab Codc 3 gTt DEII Cage No.:g.Lg No.:
raLtLal. Cal-ibra,tsion Boursc r
Contlnuingr Ca].t-bratl,on Sourcc :
H:lgrb Purity, Elpcx
Inorgranl-c Vcnturgs
sDGl No. s D5I100153
ConocntratLon Unl,tg 3 ng lL
lnaJ.yt,e
.nLtl,al Calibration
Trnrc f,ound kR (1)
Continuing Calibration
Trrrc Found, r6R ( 1) Found tR ( 1)![
Al-rrmiuum :l
It].umtnrrm :l
J eatct.rrm r, I I
0 .50 0.518 103. 5
50. 0 {g - 271 95.5
I s.ol I I s.o{lroo.slpl
Calcium Ir I 50.0 49.191 98. I
Iron to I
I rroqlti I I
0 .50 0.5101 102.0 I p
I I so-ol 18.6{l e7.31 I lPl
Potaeel.usr I
Lr"gorrairur I I
50 .0 50.051 100.1 I P
I zo.ol I I re.srl sz.BlPl
I_-soatur, r,o I I 5,O I s-oe lroL.z l p I
I soaio* Irr I I so.ol 49.851 gg.7 I I lpl
I rtrconl-um I I o.sol I I o.{eol ee-zfel
( 1) Control Llnritr :Merourl 80-1201 Othrr McEeLs 90-110, CYanido 85-115
STL Denver Fotm II (Part 1} IN
STL DENI/ER
Contract: IIRS Cortroratl,oa
Total Metals Analvsis
-2A-
INITIAL AND CONTINUING CALIBRATION VERIFICATION
Crrr No- t StE No. r
Higrh Purj-ty, Srnx
fnorgrnl,c Venturoa
LaI) Code: STLDEII
fnltl,al CelibratLon Sourcc:
ContsLnulng Ca].ibretion Bourea:
BDo rro. r D5I100153
ConcrnErrtlon Unltr r mrglt
lnalyts,o
.nLtial Cal'ibration
Trnrc Found r6R( 1)
Cont,i-uul-ng Crlt bntsion
Trnrc Fonnd %R( 1) Found *R(1)}T
lnrurniaun.:l I - | I o.sol I I o.lrol gl..,ole-l
llrunrn'rn:l ,,_ | .. 1 | so.o l ls.rsl ge .rl l - le l
I c*tol-um t I I I I s,ol I I c.eel gr.zlel
CaloLrun Ir I
rron Lo I
rron lrt I
I potagsr.um I I
50. 0
0.50
50 .0
50,O I
45. 821 91.6
45.99 92-0
o.478 95.6
{e. 561 9e,3 | n I
MagzeooLum I
Sodium rol
I soafrun Hr I I
20.0
5.O
ll 50.o I 68.ool 96.01
19.53 98 .2
5. 03 100.6
I zlrconiuml I o.5o I o.aztl 9d.8lPl
( 1) Control Iris,{ ts r Mercurlz 80-120f OtJter UoEeIl 90-110; Crranldc 85-115
STL Denver Ponn If (Part 1) IN 50
STLDENWR
Total Metals Analvsis
-2.A-
INITIAL AND CONTINUING CALIBRATION VT]RItrICATION
Contrrotsr URE CorlrorrtiOa
LaL Codc r STITDEN Carc Slo, t S.LS No. t
Initia1 Ca]-Lbration Eouroc r
contLnuLngr ca].ibnrlon souree :
Htgrh PurLty, Epex
InorgrrnLc Venturcg
SDO NO. r D5f100153
ConconErat,Loa Unitt r mgl[.
A],umLrrum :l o .50 o .480 95-0
Alurninum :l 50.0 48.3 96.7
Calciunr L l 5,O I -72 94.4
Calcium II I 50 .0 45.31 92 ,6
Iron Lo I o .50 o-{g5l 9-l .2
lrroam I ..- | I I so.ol le.srl gr.rl I lrl
Pot,as;irun I 50.0 t g.g1l 99.8 P
I M.goosium I I I ; zo.ol I I rg,ozl sa.rlp
Ana].rte
rnl-t{a1 CalLbration
trutr Fouad esR( 1)
ConEiuuing Crlibrrtion
1lrnre Forrnd e6R ( 1) Pound tR ( 1)!0
I goqf.r- Lo I I I I s.ol I s,osl1o1.o I p I
SodLugr Hf I
I zi,rconturn I
50 .0
I I o.sol I o.c76l es.zlrl
49.6 97.3
( 1) Contro]. Li"nite:Mereurar 80-120r Othcr Uttals 90-110t CYanidc 85-115
STL Denver Form II (Part 1) IN
STL DEIVVER
Contraot s IIRS CorTprrELon
Total Metals Analvsis
-2A-
INITIAL AN T} CONTIN I.]I NG CALI BIIATION VERIFICATION
Caec No. r SILS DIo. r
Htgh hrrLty, SIlerG
InorganLc Vanturas
r.ab Cod,as STLDEN
rnltlal Calibrat,ion Sourca s
ContLnuLng Crl.ibratlon Souree :
gDc I\IO. r D5I100153
Concsntratioa Units z ttgll,
Lrral-lrta
rnj.tial calibration
Trrre Fouad tR ( 1)
Continuing Call,bratlon
1''rc 1t'oqgd ,6R ( 1) Found tR ( 1)!{
Iaf*;num :l I o,50 I 0.lt991 ee.8 I P I
Alrrninutrt :l
Cal.cirrm L l
Caloiun II I
50. o
5.0
50.0
49. 5 97 .L
47 .L?l 94.3
{.81 96.2
rron Lo I
tr=onnl I I
0 .50 0-{911 98.2 I P
5o.ol t7.1il s{.2 I I lPl
Pot,assitrn I
Magmcel-urr I
Lgq4iq, r,o I I
50. 0
20. o
5.0 I
50 .251 100.5 I p
19-63 I 98-2 lP
s.r.alroz.i I p I
Sodium Iil I 50,0 {9.1 98.2
zJ.rooniurt I 0 .50
(1) control rrLIn1us:Dlcrcuty 80-L2Ot Othcr Metels 90-110, CyanLdc 85-115
0.485 97 .o
STL Denver Porcn If (Part 1) - fN 62
STL DENVER
Totsl Metals Analvsis
-24-
INITHL AIID CONTINUTNG CALTBRATION VERTF'ICATION
CoDt,rrct: URS Corporatlon
Lrb codc: STLDEN Crgr No. t A.B.SI [[o. :
rnltia], Crlibratl.on gorrrcrt
Continu:Lngr cr].Lbratsion Sorrroc r
Htgrh Purlty, SI>cx
Inorganl-c Vcnt,urer
sDs IirO. r D5I100153
I nruminum :l I
Concentsrrt{on Unlte r mg/Ir
I I so.ol lB-B5l s7.7 I I IPI
Jtna]'ytc
fuitLal Crlibrntion
Tnrc Forrad tR ( 1)
ConBLnuing Calibration
Tme rorrnd tR(1) round tR(1)}I
ll'runinum:l I I I o.sol | | o.lgsl gg.elel
I carciun r, ]I s.o l t-ztl gd.g l p I
lcrrstum Hl I I I so.ol lr.6sl es.{l I lpl
Iron t,o I
fron Hi I
o.50
50. o
0.4891 97.8 I P
47-5 95 .2
Potaerirur I 50 .0 {9. {O l 98,8 I P
[-ursrragLrrn I I I I zo.oI I I re.l{l gs,7 lpl
I socttrm ro I I I s.ol I I s.a7 lrot.tlrl
I soatum Er I I 5o.o I {g .{21 98 .8 I Jpl
Zlrcoaiun I 0.50
(1) Control Llml.ta r Mercrrrlr 80-1201 Othrr Met,als 90-110; Ctranlde 85-115
a .177 95. O
STL Denver Fom II (Part 1) IN
STL DEIYI/ER
Contract: (IRg CorporatlOn
Total Metals Analvsis
-2A.-
INITIAL AND CONTINUING CALIBRATION VERIFICATION
Cage ![o. r SAg No. g
HLgh Prrity, Spex
fnorganLc VcaturGs
Lrrb Codc: STLDEII
Initial. Ccltbration Eoursct
ContlnuLng CrlLbratLon Sourcc r
sDo r\ro. r D5r100153
Coneent,retion Unitsa t urgllt
rnallt,e
In{tLa1 Callbration
Tnrc Found tR(t)
Continul.ng Crl-ibrrELon
Trnrr Fouad, t,R ( 1) Forrnd tR ( 1)H
.}],uminum rl o .257 1102.9
Caleium Ll 1. gg I 99,0
fron f-,o I a .250 1100 .0
lpotaieiunl zo.ol ao.rglror.ol I I I I lpl
Magmortun I g.cg I 94,9
lsoarurnr,ol .,- z.ol -z.orlror.sl J_._-_-l | ...1. lpl
lziroourr:nl, o.zsl o.zrzlgo-eJ I I I | [p-l
(f) eontrol tirriEg: tiersury 80-1201 OtLff llctela 90-110r CYanido 85-115
STL Denver foru II (Parts U IN 64
STL DENVER
Total Metals Analysis
-2A-
INITIAL AND CONTINUTNG CALIBRATION VERIFICATION
coatraeli f:In9 Corgoration
LtD Codc s STITDEN Claa No. t
Htsrhlnitia]. Calibratlon Source:
contLnur-ng Calibnt,{on Sourctr :
PurLty, Spcx
fnorg.trLc V1rntrrrGa
SASI No. r gDC NO.: D5I100153
Coneentration Uaitg t trrglL
.trnaJ.ytrtr
rnLtl,al CalLbration
Trnrc Found e6R ( 1)
Continul,Eg CallbratLon
Tr:ua Forrnd tR ( 1) Found 9sR ( 1)DT
Ll.rrninum .J 0 .50 0. 500
Ca].ciun tI
Ca].ciren H I [o. o
I rron Lo I
5.0 5.03
{0.15 1100. {50-o 50.351 100.7
I I I o.5ol I I o.s:-zl
Iron IIL l {o-
J rot.rriun|
{0.53 1101.3 50 .0trl50,o I
50.031 L00. I
I so.4al
luasraeriunl I I I zo.ol I I re.gel
Sodirrn lro I 5.0 5.07
J soatum Hi I lo.ol {0.08hoo.eI so.oI ls-gsl sc.gI I
100. o
l etumtaun :l ro.ol 39.6t I gg.r I so.o I ls.sol ga.e I I
101.0
99 .9
101.4
99.8ZLreoniumlo.50
(1) CoBtroI lui.uitg: lbrcuraz 80-120; OEher I.IotalE 90-110r CTanlde S5-115
0 .499
STL Denver For:n If (Part, 1) - IN
STL DENVER
Contract: IIRS Corporation
Total Metals Analysis
-2A-
IMTTAL A}[D CONTINUTNG CALIBITATION VERTFICATION
Cagc No.:g.l,S No. :
High hrrity, Spex
fnorgtnie Vantrrr.g
tf,L Coda r STITDEN
f,nLtla]. CalibrrtJ.on Sourcc :
ContlnuLng CelibraBion Ssurce :
sDe No, r D5f100153
ConccntsratLon tlbltr r mg / T',
}rrelyta
lnl,tLal Calibration
:rr:trtr Found tR ( 1)
Contiauing Calibratl,on
Tnrc Found tR ( 1) Forrnd e6R ( 1)u
AlurnLnum :l
Jnf,mfrrum :l
o.50 0.5181 103.6 I p
I I I so.o; rs.eol gg.gl I lpl
Calcirrm L !5.O {.951 99.2 I p
Cal.cirrur II I 50,0 {9, {91 99 . 0
I.Ir.,''r,o 1... I [,.-._l o.sol I I o.sozlror.rlel
l.ronxi I I I I so,ol rr.r{ ge.sl I lpllpoccraiurl ..1- I I so.ol I I so.lglror.olpl
Ittaglrerrur!1,_ I | | zo.ol I I rg.gll gg.zlrl
lsoarunnol [ .._ I I s.ol I I s.ollroo.alel
Sodl-um Hi I 49,811 99. 6
zLreonLum I 0 .50 0.{99 99 .8
(1) Control LlmLts: Meroury 80-120r- Other Mctala 90-110; Cyanidc 85-115
STL Denver fom II (Part, 1) IN 65
STL DENVER
Total Metals Analysis
_2A,
INITIAL AND CONTINUING CALIBRATION VERIFTCATION
contEctsr IIRS CorporatLon
Leb Coda r STITDEN Caac No. t
Highfnitia]. Crlibratlon Souree:
CoutLnul-ngr Ca].ibratLon Source :
hrrity, Spcx
InorganLc VonEuroE
S.IS No. :sDg Dlo- r D5I100153
Concentratsion UnLt,r r urfrll'
Analyte
rniUl.a1 CaLl,brati-on
lfma Found tR(1)
Contl-nuLng CalLbratLon
Tnra Found, e$R ( X ) Found r6R ( 1)![
I efur,t-nrun :l I I o.50 I o.srl{l roa.8 I r I
Lluml.nurn ;l
I cnroium r, I
50. o 49. g{l gg, g
I I I s.ol I I s.erlroe.elpl
[q-r.rqrnHl I I 50.O I 53.541 LA7 -1 I Irl
Iron Lo I
Iron IIL l
l_rotasrtum I I tt
0.50
50.0
50.O I
52.53 105.1
0.539 107.8
50.711101.{ I p I
Magrrrcaium I 20. o 19.971 99.8 I P
Sodium fro J 5-o 5.111 142.2 I P
I sodi*,, sr I I I I so-ol sr.rzl r.az.ll I lpl
I ziroqnlrnI I I I o.sol I I o.s:.tl roe.lJrl
(1)Control tl.ntt,g:Marctrtlr 80-120; Othcr trtatala 90-1101 ClranLdc 85-115
STL Denver For:rn II (Part 1) - IN
STL DENYER
Contracts r IIRS Corporation
Total Metals Analysis
-2A-
INITIAL AIYD CONTINUING CALIBITATION VERIFICATION
Crae No.:gAg No. r
Ht grh PrrrLty, gpex
Inorgrnl"c Venturct
LtI, Code : STI..DEII
rnl-tl.al Cal.ibrat,lon Sourcc ;
Cont,inuLngr Ca1Lbratsioa Souree :
sDs IiIo. r D5f100153
CouccntratrLon Unl.Us 3 mg/L
lrral.ytc
InitLal Ca].ibratiorr
Trrrc found, t6R ( 1)
Conts,lsuLng CalLbrrtLon
Trnee Found ,6R ( 1) pound %R ( 1)Dt
lmunragn:l | | ..1 o.sol I I o.srzlroz.llel
Lluninum :l 50. o 50.361 100 .7
CaLcirun L l 5.0 5,35 LA7 .Z
lcql"!.-, HI I ll 50.O I 58.zz)108.dI I lel
Iron rro I
I rron lrL l
0-50
50. o I s3.131 1o8.3 J
0. 530 106.O
lpl
Potagoi-un I 50. o
Llalg*c;Luml I I I 2o.ol
51.351 LOZ.'l I p
I I zo,ozlr.oo.tIPI
Sod.Lrrnt Iro I
I soarum Ei I I
5,O 5 ,L7l 103. { I Pllso. o l s1, z5l 103.5 l I lpl
J ziroonLu:n I t I o.sol I I o.szzl:-ort.{lPI
(r)ControL r.Lnita r Mercury 80-120; Othar Mctals 90-1101 Clranido 85-115
STL Denver
Fom II (Part 1) I![
5B
STL DENVER
Total Metals Analysis
_2A_
INITIAL A}ID CONTINUING CALIBRATION VERIFICATION
Co!.trBctr IIRS Corporatl-on
Lab Codc s STLDEII Crac trb. r g^[S No- :sDs ![o. t D5f100153
InltLal Calibration Bourocr
Cont,l,nur,ng Calibnt.l.on Sourcc :
Ht grh PurJ.ty, Spcrc
Inorg.nLc Vcnturcr
ConcentratLon Unit,r r ngr/L
ena1yt c
rnLtlal Call-bratioa
Tnrc Found tR (1)
Continuingr CrlibratLon
T,.e Fouad tR(l) Found tR(1)M
I erumrnum :l o.zsl o.zsThoz.el I I I I lpllcarcrunr.l a.ol z.oolroo.ol I | _ I I lellrronro I . o.zsl o.a.srlroo-ll I I I I lel
Potaesirrm I 20.20.15 1100-g
Mrgncat-um I 10.g .52 I 95.2
I Soair-, rro I a.ol z.orlroo.sl I I I I
Jzirconl-uml o.2sl o.ztol go.ol I I I I lpl
( 1) Control L5.nit,p r l{orcury 80-1201 OEhtr Meta1s 90-110r Crranldc 85-115
STL Denver form II (Part 1) r IN
STL DET\TVER
Coatraot r IIRS Cor;poratLon
Total Metnls Analysis
_2L-
INITIAL AI.[D CONTNUNG CALTBRATION VERIFIC ATION
Cur llo - t gfg No. r
Inorganl.e Ventureg
Eigh hrrity, Spcx
Lab Codc t STtrDtN
rn{Clal. Ca].ibnt,Lou Eourorlr
ContinuLng Cal-ibratiorr Eorrroa r
ADG, I[O. r D5I1OO153
Conccntsntlore tlnLt,n r \gll,
Arganl.c I 0 .25 0.2{9 I gg.5 1. O0 1.0071 100.7 1 - 0141 101. {
I sarrun I o-asl o.zsz lroo.e I ,,, o.sg I q.poel ror.z I o.soslror.o I .il
Ctrrornlrrn I 0 .25 0.2{8 I 99.2 0.50 0.5031 100.5 0.5041 100, I
rl o .25 a .242 I 96. I 0 .50 0.4981 99 - 5 0.5001 100.o
I read I o.zrl 0.2{5 I 98.0 I 0.50 I o.so{l 1oo.B J o.sozl 101.{ I
AnaIfrtsc
rnl-tLal Callbration
Trnrr Found gtR ( 1)
ConEl,nutng CalibraElon
llnrc 1'.otrad tR ( 1) Found BR ( 1)It!
I utclret I o.zsl a -252 l1OO.8 I 0.50 I o. so?l 101. d I o. sogl 101.6 J P I[ry.t.*.r I o.asl o.z41l 96.{ I o.5o I o.{9il 98.2 I o. c94l 98.8 J p I
Ltqq*dt.r+ I o .251 o.2{8 I gg .2 I o.5o I o.so{J x.oo.B l o.sodl1oo.8l P I
Zino o .25 o.2{{ I 97 .6 0 .50 o.5121 102.4 0.504 I 100.8
(1)Control Lfuutts r Mcrotrry 80-LzO; Other Mote1g 90-110r Crranlde 85-115
STL Denver Form II (Part,1) rN
STLDENVER
Contsraot:
Irab Codc t
Inicl-al Calibration Source:
ContinuLng Ca1ibrrE,ion Source :
Total Metals Analvsis
_2A_
INITIAL AND CONTINUING CALIBRATION VERIFICATION
IIRS Corlnrrtlon
STTJDEN Ca;a No. r g.[S No. :
Inorgarrlc Venturog
gDc No.: D5I100153
Irtgh E\rrity, Spax
Conccntsration urrLet t mgll
Arra1.ytc
rn:[ti.a]. Calibratioa
Trrra Found tR ( 1)
Contl-rrul-ng Crli.bntj.on
Tme Found e6R (1) Forrnd tR( 1)![
lrscnic I 1. O0 1. O00l 100.0 1.0111 101.1 I p
Berl,un I 0 ,50 o,5241 10{,8 o.5211 10{.2 I p
lorrorruu I I I I o.sol o.ragl sz.al o.lgll gg.slpl
lcop4r I .. | | I o-sol o.srsl ros-ol o.sralroe.llpl
Lcad 0 .50 0 .5031 100.6 I 0.507 I 101.{ I p
I luickol I I I I 0.50 I o.{991 99.9 I o,soll 100.2 | r I
SLlver I 0 ,50 0.4921 98. {o.4921 98.{ I p
l.v-ruaaiunl 1,, I I o.sol o.lgel gg.zl o.soolroo.olel
zLn:c o .50 o.o58l 93.5 0.{g1l 96.2
( 1) Control Limit,e r Mercury 80-1201 Other Mctals 90-110r CYanidc 85-115
STL Denver
Form II (Part X} b IN
STLDETWER
Contract r IIRS Corporttion
Total Metals Analvsls
-2A-
INITIAL AI.ID CONTINUING CALIBRATION VERIFICATION
Cago No.:g.f,g ltro. r
fnorganio VentrrraB
Irigh Purity, Spox
LtL Codcr STLDEN
tnitial crl.Lbratsl.oa Sorrcr r
ContlnuLng Ca1ibrrtl,on Source :
sDGl lso. : D5I100153
Conccntrrt,Lon UnLts t rrrglt,
.lnal"y't,c
Initial. Crl.lbntj.on
Trtr. Found tR(l)
Continuingr Calibration
Trnra Forrnd t6R(1) Found e6R(1)t{
leracnio I I I I i.ool r,oozl1oo.2l I Lryl
srrium I
Chromiun I
Coppar I
Ircad, I
till-cka} l
Sil.wrrr I
Vaurd,iurn I
I zinc
o .50 o.5171 103.4
o-50 o.5011 100,2
o .50 o.5051 101.2
o.50 0.5071 101.{
0 .50 0 - 5081 101.6
0 .50 o.{941 98.8
0 .50 0.5021 100.4
I I I o.sol o.{eol eg.ol I
P
(1) Control LinLtc:Uergury 80-1201 Other lIetalt 9O-110; C}ranide 85-115
STL Denver Fom, fI (Part 1) IN
72
STL DENVER
Total Metals Analysis
-24-
INITIAL AI\D CONTINUING CAI,IBRATION VERIF'ICATION
eotrbract! IrRS CorDontl-on
I,ab Code: STTDEN Caga lilo. :gAg No. g sDO t{o. : D5I100153
InitLaL Calibre.rlon Source:
ContinuLugr Cal!-bretion Sourec r Ultra SoLcntific
NIST
Ana,I.1ft.a
rnLtLal Cal.Lbration
Tme Found tR(l)
ContLnuLngr Cr1l.bnt,Lon
Tnrc Tound e6R( 1) Found e6R ( 1)M
luo'.,'=v I .g.oozrzzl o.oozrzz I gg.s I ,o.oosooo I o.ooqgzzl gs.s I o.oolsscl gg.l lg'vl
Concr.r,trrtlon Unltr t mg llt
( 1) Control r.lnlts:Msrcurfr 80-12O; Other Metr1e 90-110; CYrnide 85-115
STL Denver
Fom II (Part 1) - IN
STL DENYER
Contract: IIRS Corpontion
Total Metals Analvsis
-2lv
INITIAL A}.ID CONTIN UING CALIBIIATION \iERITICATION
Cage No- :S.B,g No. :
NIS,:t'
U1tra ScianttfLc
Irab Codo: STLTDEN
rnJ.tial CalLbrltlon flource :
Continuiag CaLl,bratsLon Sourcc r
sDs No. r D5I100153
ConeantratLon UnLtg : rg lL
Ana1yt,c
Initial Callbratlon
Trnrc fcytrnd gtR(l)
Continuingr Calibratl,on
tnuc round tR ( 1) Found egR ( 1)M
Marcrrry 0.005000 0.00511 102 .3
( 1) Control lrinitg;!.Icrcury 80-1201 Other Mctalg 90-110, Cyenida 85-115
0.005150 t-a3.2 cv
STL Denver
Fom II (Part 1) ) fN
74
STL DENVER
Total Metals Analvsis
-2L-
INITIAL AND CONTINUING CALIBRATION VERIF'ICATION
coatracts IIRS CorporrUion
I.aJD Code : 8TITDEN Cacc No- t gf,S, No. I
Iaitl,a1 Calf,bration gourcc r
Cont,Lnuingr Crlibratrlon Sourcs :
NIST
Ultre Soiantific
gDo No-: D5I100153
ConoentratLon Unite z frfllL
fnrJ.frt,a
rnLtLal. Call-trration
Tnrc Found t,R ( 1,
ContLuuingr CalLbration
Tnre Forrad tR ( 1) Found ,6R ( 1)!l
0.005000 0 .00517
(1)Control Linite:Mercury 80-120r OEhcr t{eteLs 90-110, CYanide B5-11S
STL Denver
for^m II (Partr 1) IN
75
STL DENVER
Total Metals Analvsis
_2A_
INITIAI, AND CONTIN TIING CATIBRATION VERII'ICATI ON
Contract: IIRS Corporlltl,on
rab Code 3 S,8LDtl{ Cage No. 3 gAg No. :
rnLtLal- Callbrat'ion Glourec r Htgh ttrrl"ty
Continuiag Call.bratrion gourcc r Inorgfanio Vcnturos
SIXI NO. r D5I100153
Cou,scntrrtl.on Unlts I r{JII)
Analf'te
InitLrl Cal.l"brrtl.on
Trnra Fouad %R ( 1)
CoutLnuing Cal{bration
1.rrrc pogad rbR (1) Found tR ( 1)u
lcaauum ,1, o.olol o.gl.r,p.lr,or.z I o.oso I o.osorl roo.z I o.o?.oolroo-o I u I
I s.r.,"i.rn.. I o.olol o:olor Jroo.z I o.oso I o.osogl roo.e I o.olgsl gg,.o I q I
O
(1) coutrol r,inLugr H.rqrrar 80-120; Othcr Motals 90-110t cyauldr 85-115
STL Denver Form II (Part 1) G M 76
STL DENVER
Total Metals Analvsis
-2A-
INITIAL AND CONTINUING CALIBRATION VERIF'ICATION
eoltract s IIRS Corfrorrtio[
Lrl, codc I STLDEII Cage No.:SAS No. t
rnLCl.al Calibnt,Lon Sourcc :
Cont,iauing Ca].lbrat,ioa Bourec :
Hl-gh Purlty
Inorganl-e Venturer
SDO sl0. r D5f 1OO153
Concantrat,Lon gnt cr t ngft
.lnrl.yt,c
rnl,tial- CalLbrrtl-on
Ttrrc Found tR(I.)
ContLaulnrr Call.bration
Tnrc Found tR ( 1) Forrnd tR ( 1)M
l.c_rani.un I I .. I I o.osol o.osorl roo.rl o.osrzlroz.llul
I setenium I I o,osool 1oo.ol o.otszl ge.cf ulI I o.osol
(1)ControL Limitg:Mcrcury 80-120; Otsher Mrtelg 90-110r eranide 85-115
STL Denver Form rI (Part 1) IN
STL DENVER
ConBraet,: $RS Corporation
Total Metals Analvsls
_2A_
INITIAI, AND CONTINUING CALIBRATION VERIF'ICATION
Clac No. I Sr.[l No. r
Eigrh Purlty
Inorgrrnic Vanturog
Lnb Coda: STITDEII
InItieI Callbration Sotrrcc:
Continul.ng Ca1.ibnt,Lon Souree :
sDg No. r D5I100t 53
Conocntsratiou uaLte t tr{Illt
enalytsc
rnl.tl,al Calibrat,Lon
Truc tround ,6R(1)
Continuiag Crlibrrtion
'lDnrl fourrd tR ( 1) 8or:a'd e6R ( 1 )Ir!
I crami,m I I 0.o5ol o.os06l 101 .zl o.0s01lroa,-zInl
Scleniun I
( 1) ConE,roI l,initg:Mcrcury 80-120p Othcr Motalt
0 ,050 0. 050 100.2 0.0505 I 101. O
90-110; C:rrnldo 85-115
STL Denver Form II (Pert 1) IN 7B
STL DENVER
Total Metnls Analvsis
-2A,-
INIIIAL AND CONTINUING CALIBRATION VERIFICATION
Coatraot: tRS Corporrtsion
Lab Codr: EELDEN Carr No- t Atg Nrr. r
rnl.tial Callbrrt loa Eouroc;
Coutinul.ng Cal'ibrrELon Sourec :
Hlgb Purlty
Inorgrnl-c V11nturetg
sDG llo. r D5I100153
ConccntraElon Unlts t mg/T'
ArraLytc
rnJ-tial- Ca].ibratLou
Tr:uc Found tR ( t )
Cont:LnuLng Crl.LbrrtLon
13rnrc round tR ( 1) Found e6R ( 1)M
Cadniusr 0,050 0.049 99-0 0. 0500 100 .0
SclenLum
( 1) Control t,imitg :IdoreurT 80-1201 othcr Metals 90-1101 CYanidt 85-115
STL Denver Eorm II (Part 1} IN
STL DEIVVER
Total Metals Analvsis
-7B,-
CRDL STANDARD FOR AA ANI} ICP
Coatraotr r IIRS CorporatLon
LsIr Codc r STLDEN
A.L CRDL Starrdard Sotrrce r
ICP CRDI Standa.rd Eourcc r
Cage No- 3 g.f,g N<r- t sDGt No. : D5I100153
rnorgenis Vcuturaa
ConocntratsLoa uultr :, mg f l,
A1umlrrum I 0 .10 0.113 I 113 .0
lcelciuull I I ll o.zol or.?zgl-ru.sl I Ilr'o. b I I , I ll o.orgl_, .- o.osnol rr.gl .-,.. ,. I IPotaaaiuml1.0 1. 1{ I 114 .0
eRDIr EBrndrrd for ICP
rnltLal FJ.naI
Tnrc Forrnd, ,6R FOUnd.
CRDL Etrndllrd for .el.
lErgrncat uml o,20 0.192 J 96, O
SodLum toI 1.0 1. 12 I 112 .0
Zirconiumf 0.005 o. o05g I 116.0
STL Denver (Part
STLDENYER
Total Metals Analysis
-7B.-
CRDL STANDARI} FORAAA}ID ICP
Contsrrct r IIRB CorporatLon
Lrb Codc: STITDEN
.Le, CRDIr Stendard Sourcc:
fCP CRDf. Atanda,rd Slorrrcr r
Casc No.:gl,g No. :SDs No. r D5I100153
Irrorganic VcnturG!
Concsntrat,iou Unit g : ng lL
CRDIJ St,asdnrd for .LI.
Trtrc f,ound
CRDIJ Stand^ard for fCP
rnitial FJ.nal
ttrnre lroruod, t,R Found, %R
}'lrrlnl-nun I 0 .10 0-1001 100.0
Cal.cius Irl 0-20 0-1971 98.5
fron Lo I o-030 0.03221 107 .3
Pot,asriumt 1.O 1.011 101. O
I{a,grnrrslumf 0.20 0 .209 I 10{. 5lsoaruar,ol -l I ll r.ol e.ozl roz.ol I IZl.rconfuml 0.005 0.0057 I 114.0
STL Denver
( Part,
STL DENYER
o
Con
frab
trrot r
Code :
t RS Corporatl,on
STLDEN Case No.:
Total Metals Analysis
-28-
CRDL STA}.IDARD FORAA AhID ICP
SIS No. r
ELgrh Ptrrlty, Spcx, Inorg:anl,c vent,urog
SDO No. r D5I100153
AA CRDfr Standard flourcc r
ICP CRD[, Standard Sorrrcc r
Concentration Unitg : mg/f,
CRDL Standard for IeP
rnttial' Flna].
Fotrnd e6R Found
CRDL Btrnfllrd for Al'
Tnre f,ound
Argcaic
Be,riurn
0 .010 0.01411 141, O
0.0050 0.005161 103.2
Ch,romLrrm
J eoppcr
o. o10 0. o111 I 111. 0
I I Il o.o1ol o.oroel1o6.ol I I
Lcrd
I luiokrrl
0. oo30 0.001951 65.3
I I Il o-o1ol o-or.aolLzo.ol I I
Silvcr o. o10 o. 0093 l 93, o
vena.d.j,urn I o. o10 o . 0108 I ro8. o
Zl-nc 0.020 0.0233 1 115,5
STL Denver Forn fI (Part, 2l IN
B2
STLDENVER
Total Metals Analysis
-28-
CRDL STA|.,IDARD FORAAAND ICP
Contsract: IIRS Corlroratl,on
r,ab Code : STLDEN
AA CRDL 9tandllrrd Sorrrcc:
ICP CRDI, Standlrd Sorrca r
Cenc I{[o. t
Ult,ra ScLent,Lfic
gAg lilo - :sDo No.: D5I100153
ConccntratLon Unl,ts z mg/L
0 .00021 107. O
CRDL Stsandrrd for AA
Tnrrl E orrnd, t,R
CRDL gtrndrrd for fCP
rniuial Pinal
,frurr Found ,6R Forrnd, 9bR
Mercury I O.0OO?00
STL Denver Fono II (Part 2) D IN
STL DENVER
Total Metals Analvsis
-2B.-
CRDL STANDARD FOR AA AIYD ICP
Contsraet: IIRB CorporatLou
Lab Codct STLDEN
l.L CRDL Standrrd Eource:
ICP CnDIr Standard gouroc:
Cagc No.:AAS N<>. I sDGl No. r D5I1O0153
Inorgrrnto Vcnturoa
Co,ocontsratsion rfni.ta t ryll'
CRDL Strandard for l.l,
Tnrr Found,
CRDf, Btandrrd for ICP
rnLt!.a]- FLnl1
Trnrc Forrnd tR Found
Ca&nlum 0.0010 0.00100 100. o
0,0010 0.0009L
STL Denver f,om fI (Part 2) IN 84
ffiSTt
tiRS Corporation
fotal Metals Analysis Drtr Sheet
Lnb Name:
LoUSDG Numbcr:
Matrlx:
7o Moisture:
Basis:
Analysls Method:
Unlt:
QC Batch It):
Sample Aliquot:
Dllutlon Frrctor:
STL, DENVER
psn 00t53
WATER
Wet
60108
me/L
17652'2
50 mL
I
CIIent Srrnple lD:
Lab Srmple ID:
Lrb Workorrler:
DstcIl]me Collected:
Drte/Time Recelved:
Dete/Time Leached:
Dnte/Time Extracted:
Drte/Tlme Andyzedr
Instrument ID:
D5t220000-2228
HK5KG
09/23105 I5:30
09126105 19:06
9?J
CAS No.Analyte Conc.MDL RL 0
7429-90-5 Alurninunr 0.0t 7 0.017 0.10 U
7439-8e-6 lron 0.021 0.021 0.t0 U
7439-9s-4 Magncsiurn 0.043 0.043 0.20 U
7444-A9-7 Potiusium 0.74 0.24 3.0 U
744A-?3-5 Sodium l.t r_l 5.0 U
7M0-67-7 Zirconiunr 0.00r6 0.00r6 0.0r 5 U
740-74-2 Calcium 0.034 0.034 0.20 U
STL Denver
Form 3 Prep Blonk Equivalent
ffiSTL
URS Corporatlon
Total Metals Analysis Data Sheet
Lab Nnme:
I,oUSIIG Number:
Mntrlx:
7o Molsture:
Basls:
Analysls Method:
Unlt:
QC Batch ID:
Sarnple Aliquot:
Dilution Factor:
STL DEN\/ER
nsr 100t 53
IYATER
Ws!
60108
mpll,
526s222
50.rnL
I
Client Sample ID:
Lab Sample ID:
Lab Work0rder:
Date/Tlrne Collected:
Dste/Thnc Recclved:
Date/Tlme Leached:
Date/Tlme Extracted:
Drte/I'ime Analyzed:
Instrument ID:
D51220000-2^^n
HKsKq
0ei23l0s..J15#.0
09/27 lltl I l:43
0t6
C-AS No,Annlyte Conc.MDL RL 0
7MA-38-2 Arsenic 0.0044 0.0044 0.015 U
7439-92-l Lead 0.0026 0.0026 0.0030 U
7440-39-3 Barium 0.00070 0.00070 0.0r 0 U
744042-0 Nickel 0.00 t 2 0.0012 0.040 U
7444-224 Silver 0.0028 0.0028 0.0t 0 U
7440-62-2 Vanadium 0.002s 0.0025 0.010 LJ
7440-66-6 Zinc 0.0045 0.0045 0.020 U
744047-3 Chromium 0.0026 0.0026 0.0r0 U
[ao-so-s Copper 0-0045 0.0045 0.010 U
STL Denver
Form 3 Prett Blank Equivalent
B5
ffisrr
URS Corporadon
Total Metals Analysis Data Sheet
Leb Nume:
LoUSDG Number:
Matrlx:
7o Molsture:
Basis:
Analysls Method:
U nit:
QC Bttch ID:
Sample Aliquot;
Dllution Factor:
STI., DENVER
psll00l s3
WATER
wet
7470A
mglL
5266336
I
CIIcnt Snmple ID:
Lnb Semple ID:
[,ab Workorder:
Date/Tlrne Collected:
Dtrte/Time Received:
Dste/Tlme Lenched:
Drte/Tlme Extrrcted:
Drte/Tirne Analyzed:
Instrument ID:
p5r230000-3368
HK94I:
Q9t26105 tZ:as
09/26105 I8:55
0r9
CAS No-Analyte Conc.MDL RL a
7439-97-6 Mercury 0.000044 0.000044 0.00020 U
STL Denver
f'orm 3 Prep Blank Equlvalent
mffi sTt
URS Corporation
Total Metals Analysls Data Sheet
Lab Nune:
LoUSD(J Number:
Matrlx:
7o Molsture:
Brsis:
A,nnlysis Method:
Unlt:
QC Batch ID:
Sample Aliquot:
Dllution Factor:
STI DENvTR
psr lCIQJ s3
WATER
Ust
6020
mdl.
s26s l 80
50 rnl
L
Cllont Sample ID:
Lab Sample [D:
Lab Workorder:
Date/Tlme Collected:
Drte/Tlme Received:
Datc/Time Leached:
Drte/Tlme Extraetcd:
Datc/Time Analyzrd:
Instrumcnt ID:
D5I220000-1808
HKsNA
09/23105 08:00
Wt}JNs a3:s6
004
CAS No.Analyte Conc-MDL RL a
778249-2 Selenium 0.00033 0,00033 0.0020 U
74d.0-43-9 Cadmium 0,000040 0.000040 0,0010 U
STL Denver
Form 3 Prep Blank Equivalent
88
STL DENI/ER
Total Metals Analysis
-3-
BLAI{KS
Contract:
L,ab Codc r
IIRS CoralonELon
STI,DEN Cage No.:S.LS lfo - :gDc NO.: D5I100153
PreperatLon Blarrk MatrrLx (soil/watcr) t I{ATER
Prcparatlon Blank CcrnccntrraEl.on UaLt,s (tWlI' or rrff/kg):[TGlI,
rn{tlal
CaIlb.
BIrDI(
(lnrr/L)
Concinulng Crli-brrt,lon
B1cnIE (uglIr)
1czc3c
Preparation
g].ank
ItJ.uninun Lo I o .017
Calcium f,ro 0.052
Iron fro o-021
Potaseirrn o .2{
tr[agncel.un o.o{3
Soditun Lo o .032
ZiroonLun o.00160
0 .017
0.03{
o, o21
4.24
0 .043
0 .031
0.00160
0 .017
0,03{
0.021
0, 0{3
0. o31
o.00150
0.017
0.03{
0.021
a.2l
0-0{3
0. o31
0.00160
0.017
o,03{
o.021
a.2L
o.o{3
1.100
0 . oo15
STL Denver trorrm IrI IN
STL DENVER
Total Metals Analysis
-3-
BI,ANKS
Contract r
rlb Codc:
t RS Corpontion
STLDEN Crrr N<r. t gl,S No.:sDo No. r D5I100153
PrrpnratJ.on BJ.rnk
PrcDaratLon BLan'l(
Matrrlx ( goil,/vnt,rr) t W}TTR
ConcrntratLon Units (ngll or mg/kg) r YIGIT,
fnitiaL
errll-b-
BIaDIB
(rng/Ir)
Contl,nul,ngr Calibratioa
Blsgr B (mg/L)
AlumLfiun lro I
Cal.cLrrrr Iro
Irou to
PoEEgnirur
Magnesl,run
Sod{tm lro
ZiroouLum
0 .017
0.o34
0.o21
o .2{
0.043
0,082
o.00160
o.017
0-03{
o. 021
4.2{
0.043
0.197
0.00160
STL Denver Font IfI - IN 90
STL DENVER
Total Metals Analysls
-3-
BLANKS
Contrrct r
frab Codc r
PrcDaraELon
Prspantlon
t RS Corrylorrtion
gTLDEN Cacc No. r
Matrix ( rot-]-/watsclr) :[!TTTER
8.[.9 No. :sgo !ro- r D5I100153
Blrnk
BIanlc Conoantsration Unl.ta (mgll, or figl MG/L
AlunLnum Lo I o.017
Ca]"ciurr Lo 0,034
Iron Lo 0. 021
PotageLrrrn
lUrgno;iusr o. 043
SodLrun fro o-o31
Z,Lrc,onirrm 0. 00160
0. o17
0.034
o.o21
o .0{3
o. o31
0 - 00150
o.017
0.03{
0 .021
4.24
0,o{3
0 .031
0 .00160
0. 017
0.03{
0-021
0 .043
0.039
0.00160
Initial
C!.ll.b-
Blaaft
(nglL)
PreDa"rraon
BLrDk
Contsinuiog CrlLbratlon
slarrlE (ng/fr)
lczc3c
STL Denver f,'Onn III IEI
STL DENVER
Total Mettls Anrlysis
-3-
BLANKS
Contsnct r
Irab Codc t
IIRS Cor:>oratl,on
STI,DEN Cagc No- r s[.9 No. r aDCl NO. r D5I100L53
PrrprratsLon B}lnk Matrix (ro{]-/watcr) :UILTTR
PraDantLon BLank Conccntration UnLtt $sglf, or nglkg) r YlG/t
Preparatioa
Blarrk
fuitl,al
Cllib.
BIrDk
(mgr/L)
Contlnulng Calibration
BhDIc (mglf'l
0,0025 I U
.a.rgcnio
Brrium
Ctrrorrium
Collper
Laad
NLckc]'
SL].vor
Vanadl.urn
Zl,nc
0 . oo4{
0 - oo070
0.00250
0. oo{5
0.0a26
0.00L2
0.00280
0. 0025
0 - 00{5
0 .00{{
o.00070
0.00260
0,00{5
0.0026
0.00L2
0. 00280
0.0025
o.0045
0.ooa(
0.00070
0 .002 60
0 .0045
0.0026
o . oo12
o.00280
0.0025
0 - o0d5
o - oo{4
0,00070
0-00250
0,00{5
o.0025
o ,0012
o.00280
0.0025
0.0045
0. oo{4
0 - 0007
o. 0026
0.00{5
u
U
u
u
o.0025
0.04L2
0.0028
o.00{5
STL Denver FoTm III - IN
92
STL DEIVVER
Total Mctals Analvsis
-3-
BLAI\KS
Contnct r
Lrb Codcr
Prrprrrti.on
PrcparatLon
IrRg CorporatLon
gTT',DEN Cage ![o. :
Ma.trLx ( aol.l /water) :W}TER
g.LA No. t 8DCI No. r D5I100153
B]-ank
B]-rnlE Conoontsrabioa UnLtt (Eg/r,or nfr/kg) r VlOl I'
ContLnulng Cal{bratLon
Bl.rnlr (tWlt'\
lczc3c
ra.LtLrL
Ca1lb.
BLanTIE
(nf,r/r,)
A,reonLc
Barfu:rn
C'hromfum
Copper
Lerad
NickrlL
Silwer
VanadLrrnr
ziao
0.00{{
0 - 00070
0.00250
o. 00{5
o. 0026
0.0012
o,00290
0.0025
0.0045
STL Denver
FoTm III I![
93
STL DEN}/ER
Total Metals Analysis
-3-
BLANKS
Cont,raot r
rab Codc:
Ilrcparatl-oa.
Preparation
IIR$ Corporatsl-on
gTTJDEN Cage No - :
B].anrk, Matrix ( soil/watsrr) :
Bl-ank CoacenErat,ion Un.Lt;
S^tr^S t{o. :aDO srO- r D5f 100153
(rWlT, or mgl
rnalyte
Initirl.
Calib.
BlanIE
(mglL)
C
Continuing CalLbrrtl-on
B].rn.h (rlglf,,)
1 c 2 c 3 C
PrgDaration
81ank
c M
r{crourlr I o.o00044lU O.oO0044l ul 0.00004{ lU I 0.000044 I U 0.0000{{ I U gv
STL Denver I!.om IIT IN 94
STL DETVVER
Total Metals Analvsis
-3-
BLANKS
Contract:
Lib Code:
FrcDarat,ion
PrcprratLon
IIRS Coq>oratLon
STIJDEN Caee No. t
BIanlE tdatrLx (goiI/watcr) :
Bl-anlr Conecu,tration Units
gt8 No. t sDC NO- : D5I1OO153
WITTER
(ng/r, or mglkq) :MG/fr
Analytc
rnltl,a]'
Ca1Lb.
Bhnk
(rnglIr)
a|
fe
conBlnuing Calt bntLoa.
BItnlE (ng/L)
lczc3c
Preparatsion
BIcrrk
c u
MrrrcurT I 0.0000{{lUI 0.000044 lU w
STL Denver
Fonn III IN
STL DENVER
Total Metals Analvsis
-3-
BLANKS
Contract: IIRB CorSnratLon
Irrb Codc: $TLDEN Crrc No. r gf.S No - t
Fraparat,ion B1ank MrtrLx (aoLl/waBer) : IIIJITER.
PrcDrratsl.@. Bl.rnl3 Coaceatrrts:loa Urrlts (ngll or Erylkgl t $Alrg
SDCI No. r D5I100153
Anal.ytc
rDltLaI.
Cel:Lb.
BlADK
(lug/r,)c
ContLnulng Callbration
Blank (mgll)
Ic2c3c
Prcpat.aton
Blank
c M
Cadnium
S.1.nf,r*
0 . oooo. ol u
o - 0003301 u
o.og0o4olul 0.00.00{0lu I 0.000040 I u
o.ooo33oIuI 0.000330Ju I o-ooo330 I u
o. oooo{ I U
o. ooo33 I u
u
M
STL Denver E'orur III ff 96
STL DEIVVER
Total Metals Analvsis
-3-
BI,ANKS
Coutraot r
LaI) Codc r
Prcperatl,on
PrcDaraEion
UnS CorporatLon
STI,DE}I Crrc No. t
Bl'rnk MatrLx (goil/watcr) r
Blenk Concentration tlnLt,g
gl,S No. r SDGI No. s D5I100153
Wf,TER
(ng/r or mglkg) t lrcl r,
lnalytc
rnltLal
Calilr,
Blanlr
(wlt'l
c
Contl.nulng CalilrreEion
Blrnk (mg/rr)
1czc3c
Prcpar.tioo'
BI.arrlr
c M
Cafulrrm
S"t-rf,r-
0. ooo0r0,l L[ 0 . 0000{0 lu J o .000o40'l u
0.0o033olul 0.ooo330lu I o.000330 J u
![-u
STL Denver Fom III IN
STL DE]YVER
Total Metals Analvsis
-3-
BLANKS
Contsracts, r IIRS Corporation
Lab Codc: STITDEN Caea No - :g.trS No.3
Prcl>aration BIanJr MrtrLx (eoi1/wetrr) r WATER
PrcDaratiou Blrdr Coac.Dtntl.on Uaitc (ng/L oiliBlkgl: !G./L
sDg trIo. t D5r100L53
.nnalft,e
Inl-tLa1
ClILb.
BI.r.nIE
(mcfr)c
Corrtrl,nulng Crltbratiou
Blruk (rnrrtr,)
lczc3c
Prrpr=.t*.,,'
ghak
c u
CadmLun
S.ltrf.r*
o.oooo4ol u I _ o.oooo4o tuo.0oo33olul 0.000330Ju
}I
I
M
STL Denver FoTn III IN 9B
STL DENVER
Total Metals Analvsis
-4-
ICP I]\TERF'ERENCE CHECK SAMPLE
Contraets: URS CorporatsLon
r.ab Codc: STI.DEN Cage No.:
fCP rD Nunbcr r TiFL lntrepid fCP
8AII No- r sDG No.: D5I1OO153
ICS Sourcc:Hlgrh hrrLty, Spax,
Concrntrrtlon Uai-Us) :8g ll,
Trrre I rnJ-t{a1 Found I final Found
llerlyte I sot.r gol.t3 | sot.r ool.ls tR I sot.r 9o1.AB *11
F1*Lnum Ef I 5O0.0 500. o 507 .58 507,58 101. 5 I
aloLum Ht I S00.0 500.0 487.55 {80.83 96.21
fron Hi I aOO,O 200-o 193 .27 190.37 95.21
Pot,asrium J O_O 50 .0 -o .0{9 53.13 1o5.3 J
gneeeirun I SOO-O 500 .0 {93 , 93 {99.18 9?.81
SodLrrm Lo I O. O o,012
Sod.t-um H 50-o 51,99 10{.ot
Zl-rconium I 0, o 1.0 0.000 1-168 116.8 I
STL Denver
STL DEIVVER
Total Metals Analvsls
-4-
ICP INTER}-I.],RENCE CH'ECK SAMPLE
Contrraet: IIRS Corporetioa
LaI, Codo r STITDEN Clac No. I
ICP ID !$rmbcr: T\rl. Iutrepid ICP
g.l,S No. :sDc No. r D5I100153
ICg Sorrrcc r EJ.grh Purity, Spcx,
trnrc
gol .t' Sol -lB
Concentrntion unt-te) r rltg llt
lnitia]. Foturd
So1..l,6o1 .t'B
Flnal Forrnd
sol .l 80L --LI]
lel*inum IIf I SOO. O 500.0 525.06 529.76l rO5.ol
Jdalchrm Hi 500. O 500 .0 {98.0{497 .57 [ S9 .51
Iron HL l Z0O _O 200.0 198 -76 198.43f S9.21
PotaaeLunr I 0.0 50 .0 -0.09{54.49I 109.oI
cgLr:.m I SOO. O soo-o 51{ .32 515.10J rOS.ot
Sodiun Lo I 0. O o. o07
um Hi 50.0 53.90I 107.gI
lzirconlun I 0. o 1.0 -0. oo1 1.098 I 109.8 I
STL Denver
tr'om, f\r IN
100
STL DENVER
Total Metals Analvsis
-4-
ICP INTERTER.ENCE CIIECK SANIPLE
ContraeE: IIRS CorporatLon
Ls.b eodo r SlftDtll
ICP ID !firnbcr: SUPERTR.trCE
Cagc DIo - :S}SI No. I SDo No. r D5I100153
fCS Source:Higrh Prrrlttt', Spex,
concentsration, unl-tr) r mglr-,
rnit,iel Forrnd
gOI..A SOl .AB
Fl,nal Found
So1 .A Sol .AB
Trrre
slol .A So1 ..l.B
precnio I O.0O 2.OO 0.005 2. 00 1OO.Ol
JBarI.un I O.0O 0 .50 0-000 o,516 to3.2l
IbromLum I O,0O o.50 0.004 0.{80 95.01
o .00 o-50 o.000 0 .534 105.81d I o-oo 1.00 -0 - oo1 o. 98 98.ol
lNlckcl- O. OO x.. 00 o-oo3 o.9{94 .01
Jsilvcr f o.O0 1 .00 0.001 x.. 04 loc. o I
[VanadLurn I O.OO 0 .50 0,002 0.{79 95.81
zj.a,a I O.0 1.0 o.o12 0.91 91.01
STL Denver
FOTzt IY IN
101
STLDETYWR
Total Metals Analvsis
-4-
ICP INTERI..E,RENCE CHECK SAMPI,E
Contrract: IIRS Corporat,Lon
Irrb Code : $TLIIEN
rcP rD r\hrnbcr: PE IePUg
Carc No.:818 No. t gDO NO.: D5I100153
ICg Sourccr Inorganlc VaatrrrGa
Cou.scntratsion tILitr ) r mg lI'
P{na1 Forrnd
8o1.1 8o1-.[IlLnrl.ytq
lcadnium
a1onitrm
o. 0988 f S8. B I
Trnre
801 .A 801 ..[B
rnl.tl-al Found
8o1 .A SoI ..[B tR
0 ,10310.10531 106,31 0.001
STL Denver Form IV rtl 1,02
ffisrr
URS Corporadon
Total Metals Anrlysis Data Sheet
Lab Name:
Lot/SDG Number:
Matrlx:
o/o Moisture:
Baeis:
Analysls Method:
Unlt:
QC Batch ID:
MS Sanrple Allquot:
MS Dilution Factor:
ST[, DENVER
Dsrt00|53
WATER
NA
Wet
601QE
WL
sz0s?22
50 mL
1
Cllent Sample ID:
MS Lab Sample ID:
MS l,ab WorkOrder:
Date/Time Collected:
Date/Time Received:
Date/Tlme Lerched:
Date/Tlme Extracted:
Ilate/Tirne Analyzed:
Instrument ID:
GW-NI-090q05
psr r 00 153-003s
HKAR9
09/09/05 09:25
09/10/05 08: l5
09/23/0s 1.5:10
09126105 19:51
oet
Analyte
Spike
Amount
Sample
Result C
MS
Result C
o//o
Rec a QC
Limit
Alurninum 2.00 0.017 U 2. t8 t09 83 - 119
Calcium 50,0 r r0 L 149 85 48 - 153
Iron I.00 0.20 I.09 89 52 - 155
Magnesium 50.0 84 130 9I 62 - t46
Potussium 50.0 72 123 ta2 76 - t32;
Sodiunr 50.0 I 700 1710 MSB NC 70 - 203
Zirconiunr 0.500 0.00s8 B 0.512 r0r 80 - r20
STL Denver
Form 5A MS Analysk Data Sheet Equivalent
103
ffisrt
UR.,S Corporation
Total Metals Analysls Data Sheet
Lab Nrme:
LoUSDG Number:
Matrir:
o/o Malsture:
Bagis:
Analysls Method:
Unlt:
QC Batch ID:
MSD Sarnple Aliquot:
l\lSD Dilution Factor:
sII, pENVER
Dsl r 00153
WATER
N/A
UET
60108
mgiL
s265222
so mL
I
Cllent Semple ID:
MSD Lnb Srmple ID:
MSD Ltb Workorder:
Date/Tlnre Collected:
Dtteffime Received:
Drte/Tlme Letched:
Dateffime Extrscted:
Date/Tlme Analyzed:
Instrumont ID:
cw-Nr-0e0905
p5ltlq0H3.403p
HKAR9
09109/05 09:25
09110/05 08:15
09/23/05 l5:30
09/26105 19:51
QAI.
Analyte Spike
Amount
Semple
Result
C MSD
Result
C 7o Rec a RPD a
QC Limits
Yo Rec RPD
Aluminum 2,00 0.0r 7 U 2.18 r08 0.26 83 - I 19 25
Calciurn 50.0 I t0 L I5I 9I 1.9 48 - r53 25
Iron I.00 0.20 r. t3 93 3.5 52 - 155 25
Magncsium 50.0 84 132 95 1.4 62 - t46 25
Potassium s0.0 72 t2.5 107 1.7 76 - 132 25
Sodium 50.0 I 700 I 760 MSB NC NC 70 - 243 4A
]rconium 0.500 0.00s8 B 0.5 I4 102 0.4s 80 - r20 2s
STL Denver
Form 5A MSD Analysis Data Shaet Equivalent
104
ffi$Tr
URS Corporetion
Total Metals Analysis Data Sheet
Lab Nrrne:
Lot/SDG Number:
Matrlx:
%" Moisture:
Basls:
Analysis Method:
Unit:
QC Brrch ID:
MS Sample Aliquot:
MS tlllutlon Frrctor:
STL DENVEK
Dsll00t 53
WAIER
hIIA
Wet
601 0B
rng/L
s2652??
50.url-
l-
CIIent Sample lD:
MS Lrb Stmple ID:
MS Lab WorkOrder:
Date/Tirne Collected:
Date/Time Received:
Date/Time [,eached:
Drte/Tlme lixtracted:
Drte/Tlme Analyzed:
Instrumcnt ID:
GW-NI -090905
D5U.09t53.-AA3$.
HKAR9
0ei09l05 0e;25
09/10/05 08:15
09/23i05 l s:30
09/?7/Q5. t ?;l3.
016
Anrrlyte
Spiko
Amount
Sample
Result C
MS
Result c
oh
Rec a QC
Limlt
Arscnic 2.00 0.01s 2.16 107 84 - t24
Barium 2,00 0.2t 2.22 r0r 8s-120
C)rrorniunr 0.200 0.0026 U 0.194 97 73 - r35
Coppcr 0.250 0.020 0.290 108 82 - 129
Lead 0.500 0.0026 LI 0,510 102 89 - l2l
Nickel 0,500 0.002 r B 0.484 96 8+-r20
Silvcr 0.()500 0.0028 TJ 0,0572 tt4 7s - l4l
Vanadium 0.500 0.0025 tj 0.489 98 8s - t20a
Zinc 0.500 0.0r s B 0.495 96 60- 13il
STL Denver
Form 5A MS Analysis Data Sheet Equivalent
105
ffiSTL
URS Corporation
Total Metnls Analysis Data Sheet
Lab Narne:
LoUSDC Number:
Matrlx:
7o Moisture:
Basls:
Analysls Method:
Unlt:
QC Butch ID:
MSD Surnple Allquot:
MSD Dllution liactor:
STL DENVER
pstI00153
F/NTER
N/^
wcI
60I OB
Elr,lL
s26s222
50 rnl-
T
Cllent Samplc ID:
MSD Lab Sample ID:
MSD Lab Work0rder:
Drte/Time Collected:
Date/Tlme Recolved:
Date/Tlme Leached:
Date/Tlme Extracted:
Dtte/Time Analyzed:
Instrument ID:
GW-Nl-0e0e0t
p5t I00l s3-003p
HI(AR9
09/09/05 09:25
09/10/05 08: l5
09/23105 l5:30
A9D7l05 12:13
0r-6
Analyte Splke
Amount
Sample
ResuIt
C MSD
Result
C 7o Rec 0 RPD a
QC Llmlts
7n Rec RPI)
Arsenic 2.00 0,015 2.20 109 t.9 84 - 124 25
Barium 2.00 0.2t 2.26 t03 1.7 85 - r20 25
Clhnrmium 0.200 0.0026 U 0.r96 e8 1.3 73 - 135 ?s
Copper 0.250 0.020 Q.296 I IO 2.0 82 - 129 25
I-ead 0.s00 0.0026 U 0.51 7 103 t.3 89 - l2r 25
Nickcl 0.s00 0.0021 B 0.494 98 1.9 84 - r20 25
filver 0.0s00 0.0028 Li 0.0584 lt6 2.0 75 - 141 2s
&anadium 0.500 0.002s U 0.496 99 1.5 8s - r20 25
Zinc 0.500 0.015 B 0.50s 98 2.0 60 - 137 25
STL Denver
Form 5A MSD Analysis Data Sheet Equivulent
105
ffisrL
IIRS Corporrtion
Total Metals Anilysis Drtr Sheet
Lab Name:
LoUSDG Nurnber:
Mttrlx:
7o Molsture:
Brsls:
Antlysfs Method:
Unlt:
QC Batch ID:
MS Sample Allquot:
MS Dllution Frctor:
$TL DENVER
p5r r 00r 53
WATER
N4A
Wst
747QA-
mg/L
s266336
I
Cllent Sanrple ID:
MS Ltb Srmple ID:
MS Lab Work0rder:
Date/Time Collected:
Drte/Tlme Recelved:
Date/'firne Lenched:
Date/Tlme Ertractctl:
Date/Time Anrlyzed:
Instrument ID:
GW-N r -090905
p5r I ()0r 53-003s
HI(ARO
0910e/0l0e:25
09/10i05 08;! 5
09126105 l?:45
09126/05 19:05
sr9
Analyte
Splke
Amount
Samplc
Result C
MS
Result C
,
Rec a QC
Llmlt
Mcrcury 0.00s00 0.000044 U 0.00459 92 tr5-114
STL Denver
Form 5A MS Analysis Data Sheet Equivalent
aa7
ffisrr
URS Corporation
Totsl Metals Analysis Data Sheet
Lsb Name:
LoUSDG Number:
Mntrlx:
% Molsture:
Brsis:
Analysls Method;
Unit:
QC Batch ID:
MSD Srmple Allquot:
MSI) Dllutlon Factor:
STL DENVER
psl t00r s3
VTA.TER
NlA
Wct
747.9A
mglL
s266336
l_
Cllent Srmple ID;
MSD Lab Sample ID:
MSD Lab Workorder:
Dnte/Tlme Collected:
Date/Tlme Rcceivcd:
Datc/T[me Leached:
Drte/Tlme Extracted:
Ilate/Tlrne Analyzed:
lnstrument ID:
GW-NI -090905
Fst 100153-003D
HKAR9
09/09/05 09:25
09/10/05 08: l5
99.1?fi/fr5- !2;+5,
09/26l0s l9:0s
0r9
Annlyte Splke
Amount
Sarnple
Result
C IVISD
Result
C 7o Rec a RPD a
QC l,imits
7o Rec RPD
Mcrcury 0.00500 0.0()0044 U 0-0046 t 92 0.49 85 - I 14 l0
Denver
Form 5A MSD Analysis Data Sheet Eqaivslent
108
ffisrr
LIRS Corporetion
Total llletals Analysis Date Sheet
Lrb Name:
LoUSI)G Number:
Matrix:
% Molsture:
Basls:
Analysis Method:
Unlt:
QC Batch ID:
MS Srmple Allguot:
MS Dilution Factor:
STI DnNvtO
Dsl r 00l s3
WATER
IilA
Wct
6Q?Q
rfigll ,
5265 1 n0
so. mL
t
Cllent Sample ID:
MS Lrb Srmple ID:
MS Lrb WorkOrder:
Date/Tlme Collected:
DstelTlme Recelved:
DatelTlme Leached:
Date/Tlme Extmcted:
Date/Time Analyzcd:
Instrunrent I D:
o\{:br I -09090s
psr t0QI.5J$03S
HKAR9
0e/0o/q5_O9j2s.
09/l0l0s 08: I5
09/23l(I5 08:00
a9D7/05 04:40
0a4
Andyte Splke
Amount
Sample
Result C
MS
Result C
%
Rec a QC
l,imit
Cadrnium 0.0400 0.00020 U 0.039 r 97 89 - 110
Selenium 0.0400 0.0016 U 0.0409 I02 82-fiz
STL Denver
Form 5A MS Analysls Data Sheet Equivalent
109
ffisrt
IIRS Corporatlon
Total Metals Analysls Data Sheet
Lrb Name:
Lot/SDC Number:
Mttrix:
7o Moisture:
Basls:
Analysis Method:
Unit:
QC Batch ID:
MSD Stmple Allquot:
MSD Dllution Frctor:
STL T,ENVER
Dsl 100I 53
WATER
N/A
lUs
60'0
mg/L
5265 r 80
sQ mL
5
Client Semple ID:
MSI) Lnb Sample ID:
MSD Lab Workorder:
Date/Time Collected:
Date/Tlme Recelved:
Datc/Tlme Lcached:
Datefl'irne Extrtcted:
Date/Tlme Analyzed:
Instrument [D:
Gw-Nr-090905
psr t 00l s3-003D
HKARg
09/09/05 f)9:2s
09110/05 08: 15
0e/23l05 0il00
09/27/05 M:40
004
Analyte Spike
Amount
Sample
Result
C MSD
Result
C 7u Rec a RPD a
QC Llmlts
o/" Rec RPD
Cadrni.um 0.0400 0,0(ru20 U 0.0396 99 1.4 89 - I t0 20
Selcnium 0.0400 0.00r 6 U 0.0437 r09 6.8 82-il}2$
STL Denver
Form 5A MSD Analvsis Data Sheet Eqaivalent
110
STL DEN}/ER
Total Metals Analvsis
-sB-
POSTDIGEST SPIKE SAMPLE RIiCOVERY
ContnetI tRS CorlpratLon
SAMPITE NO.
Gvr-N1-090905 PDg
gDO No- t D5I10O153
Ireve1 ( Loqr/med) :LoW
Lab Codc r STITDEN Caee No.:S}SI No. :
I{atrix (sol,I.lwatcr) r $ItrTER
Conocntratsion Unltar mg /1,
.trna]-yte Control
rl,nit tR
gpiked Clrro5r1c
Rrrult ( BsR) c
grqrh
Rcau].t ( SR) C
Spilcr
lddod (sA)96R a u
Cadml.rrm 175 125 0.188804 0.0000{0 I u o-20 9{-lL M
Sclenium I 75 125 0 - 19182{o.o0o330lu 0.20 95 .9 M
Com,cnte:
For:ur V (PrnT 7l INSTL Denver 111
@CTTffi r.-Itr-,
URS Corporatlon
Totel Metols Analysis Data Sheet
Lab Name: STL DENVER Client Srmple ID:
LoUSDG Number: D5ll00l53 Lab Samplc ID: D5I22OA0$222C
Matrix: WATER Lab lVorkOrder: HK5KG
o/o Moirture: N/A Date/Time Collectcd:
Baslg: ]{S Date/Timo Received:
Analysis Method: 60108 Drte/Time Leached:
Unit: nglL DrtdTlme Extracted: 09123145 $:30
QC Batch lD: 5265222 DatdTlmc Analyzed: 09/26105 I9:I0
Srmple Allquot: 50 mL Instrument ID: VL
Dilutlon Fsctor: I
Analyte True Found ToRec 0 Limlts
Aluminum 2.00 r.95 98 86 - 108
lron 1.00 t.02 r02 88 - r r0
Magnesium s0.0 49.3 99 9l ilt
Potassiunr s0.0 50.7 l0r 86- ril
Zirconium 0.500 0,507 r0r 75 - 125
Calcium s0.0 46.0 y2 89 - I t0
STL Denver
Form 7 LCS Anolysis Dutu Sheet Equivalent
772
ffisrr
URS Corpomtion
Total Metals Analysis Datt Sheet
I,tb Name:
LoUSDC Number:
Mntrlx:
oh ltlolsture:
Basis:
Analysis Method:
Unlt:
QC Batch lD:
Srnrple Allquot:
Dllution Factor:
STL DT:NYEB
I)-ItI00rs3
WATER
N/A
wet
OQIOB
mg/I.
s26s2n
50 rnL
I
Cllent Sample ID:
Lab Sample ID:
Lab trVork0rder:
Date/Tlme Collected:
Ilate/Tlme Recelvetl:
tlate/Tlme Leached:
Datc/fime Extracted:
Date/Time Antlyzed:
Instrument ID:
pst22W00-?2Zg
HKsKG
09/23105 15:30
09128/05 00:4^
92L
Analyte True Found TrRec a Llmlts
Sodiunr s0.0 53. I r06 9t-il2
STL Denver
Form 7 LCS Analysis Data Sheet Equivolent
113
ffisrt
URS Corporatlon
fotal Metals Analysls Data Sheet
Lnb Name:
LotlSDC Number:
Matrlx:
7" Moi$ture:
Brsis:
Anrlysls Method:
Unit:
QC Batch ID:
Sarnple Allquot:
t)ilution Factor:
STL DENVER
DIII 00r s3
VVATFR
N/A
Wet
6010B
rng/ln
s26s2z2
s0 tql
I
Clleut Sample ID:
[,ab Sample ID:
Lnb Workorder:
DatelTlme Collected:
Dete/Tlmc Recelved:
Dote/Tlme Leached:
Date/Tlme Ertracted:
Dnte/Time Analyzed:
Instrument ID:
D51220000-222C
HKsKG
09/23105 t5:30
A9lZ7/05 11:08
0r6
Analytc True Found o/oRcc a Llmlts
Arscnic 2.00 r.98 99 89 - I09
Lead 0.500 0.498 r00 9I III
Barium 2.00 2,12 r06 93 - n3
Nickel 0.500 0.494 99 90 - I I0
Silver 0.0500 0.0s02 100 8s - I 14
Vanadium 0.500 0.498 to0 88 - 112
Zinc 0.500 0.465 93 8s - 110
Chrrrmium 0.200 0.1 96 98 89 - I 12
)ppo 0.2s0 0-253 r0l 86 - I r0
STL Denver
Form 7 LCS Analysk Data Sheet Equivalent
114
ffisTL
URS Corporutlon
Total Metals Anrlysis Data Sheet
Lab Nnme:
Lot/SDG Number:
Mntrix:
7o Molsture:
Basls:
Analysls Method:
Unit:
QC Batch ID:
Sample Aliquot:
Dllution Factor:
sTl, nFNvER
pil r 00l s3
WATER
NIA
Wct
747$A
TnS/L
s266336
I
Cllent Sample ID:
Lsb Semple ID:
Leb Workorder:
Datc/Tlmc Collected:
Date/Tlme Recelved:
Date/Tlme Leached:
tltte/fime Extracted:
Ilate/Time Analyzed:
Instrurnent ID:
D5t230000-336C
HK94'r
Oetz0ll0L t?:aS
09/26105 l8:58
0t9
Analyte True Found ToRec a Llmlts
Mercury 0.00s00 0.00501 r00 85-t14
STL Denver
Form 7 LCS Analysk Dota Sheet Equtvalent
115
ffisrt
IJRS Corooration
Total Metats Analysls Ihta Sheet
Lab Name: STL DENVER Clleut Sample ID:
LoUSDG Number: p5ll00l53 Lab Sample ID: D5122000G180C
Matrlx: WATER LrbWorkorder: HK5DA
7r Moisturc: N/A Drte/Tlmc Collected:
Basls: W€t Dltc/Tlme Recclved:
Analysls Method: 6020 Drte/Timeleached:
Unit: mp/L Date./Tlme Extracted: 09/23105 08:00
QC Brtch tD: 5265t80 Date/TimeAnelyzcd: 09127fi5 04:.40
Sample Aliquot: 50 mL lnstrument lD: $gt
Dllution Frctor: 1
Antlyte True Found 7"Rec a Llmlts
Selcnium 0.0400 0.0375 94 82 - tt2
Cadrnium 0.0400 0.0389 97 89 - r l0
STL Denver
Form 7 LCS Analysis Data Sheet Equivalent
115
STL DENVER
Total Metals Analysls
-9-
ICP SERIAL DILUTIONS
ContrasE r IIRS Cort>orrtLon
SAI|IPLE NO.
Gril-N1- 0909 05 gER
sDGMo. r D5f 100153
Leve1 (I-ow/ned) :Low
fral) Code : STITDEI{
Matrix (noil/water): WATER
Crse No. r SJtg No. :
rnitirl Saqrlc
Rcault (r)
slcrl.al Dllutt on
Rarult (8)
105 - 19 L26.54
16g9 .20 L7stl. g0
0.00581 0 . 00800
I n rurnfuum
Ca1ciurn H
Iron Lo
Potaeriurn
MrgmcsLrrm
Sodium IIL
ZiroonLum
Concmtsrrts:loa Ulrita r mg /T,
0. o17 ul o. o8s Ju
STL Denver
Fom IX a IN
tL7
STL DENYER
Total Metals Analysis
-9-
ICP SERIAL DILU"TIONS
Contract: IIRS Cort>oratLon
g}}TPLE NO-
f!WIR^[,-frJIB QC SER
grlo I\IO. : D5f 100153
Lsvel (Iow/ned) :LO$T
Ltb Codc: SELDEN Crrc No. t S.Lg No. :
MaBrLx (roLl/watar): WJ\TER
InncnLo
BarS-rrrn
Chromium
CoDI>er
tcad.
Niokc
Si].rrar
Couccu.tsratLou UnLts:tst'I lL
o.0973 o. 0987 I
InLtl-al gamDlc
Rcgu1t (r)
ScrLaL DLluE,lon
Ruult' (g)
0.00260 0.01300
0 .0045 0. o225
0-o026 0 .0130
0 . oo1{0. oo50
0. 00280 0, 01{00
0.0025 0.0125
STL Denver Forn IX M
118
STL DENYER
Total Metals Analysis
-9-
ICP SERIAL DILUTIONS
Contract: URSI CorporatLon
S}}lPLt rUlO.
o$I-N1-090905 grR
sDc No. : D5f 100153
Leve1 (Iow/ned) r LO!.I
r.ab Coda I STLDtrDI Cagc No. r SAS No. I
Matrix (roil/water) : WTTER
rnLtl,al. Sanpl,c
Rc;rrlt, ( f )
SrrLr1 Dll'uBlon
Rrnrlt, (g)
o - 000330 o. 001650
J cndmium
Selenl-rrm
Coneantsratlou Unlte t mgll'
0.000040 0.000200
STL Denver
Foru IX IN
119
STL DEIYYER
Total Metals Analysis
-10-
ME'I HOD DETECTION LhIIITS
contracr r uRs cgqlroration
LTb COdC T BTIJDEN Caar ![o. I
ICP ID ![umber: TifA IntrepJ.d fCP
Flrnc .trt fD Nurnbrr r
Furarco II' ID tiltrrnber:
SAS, Dfo. r
Dutrr 5 ILO l2OO5
sDc NO.: D5f100153
lrralytc
Wava-
lcngth
lnm)
Beck-
grround,PQT,
(ng/L)
MDIJ
(rwtt)l M
Al-rrninun f 157.O 0.101 o-017 lp
AlumLuum Il 309 .2 1.O P
ci.um t 3L7 .933 0.20 0.034 I p
Calci-um H 318.1 10 P
fron lro
ffi;i.ET
259.9
b27L.4lA
0.10-il3 0.021 lp
P
Potateium 7 66 .49L 3,0 o.24 I p
Mcgmcal.un 279.079 0.20 o.0{3 I P
urn Lo 589.5 1.O I O.O31 IP
Sodiun Ei 818 .3 10 P
Zirconirur 339. 1 0,00501 0.00161P
STL Denver Form X - IN L20
STL DENVER
Total Metals Analysis
- I0 -
METHOI} DETECTION LIMITS
Contsract 3 lrRS CorTroration
Ld, Codc: BTTDEN Crrc !ilo. :Sl,g Ne. r
Drt,et 5lLAl20A5ICP ID Nunbcr r $UPERTR.I,CE
F1amn .I.}, ID lilunbcr I
Frrr-rroc A.tr, ID l[rrmbcr r
tnrllt'r
UIIBvG-
Icngtb
(nsr)
Brck-
ground PQL
(mgll)
!ilDL
(ng/L)M
f,rrtrnic 189.A42 0.0101 0.00{a P
BarLrrra {93.{09 0-010 0.00 P
Chr um 267,.7 L6 0.010 0.0o25 F
Coppcr 324.7 53 0. 010 0.0045 P
fre Ad 224. 3 53 o. oo50 0 .0 426 P
Nl.ckcl 231.60e 0.0{0 I 0.0012 P
SLlvar 328 .0 68 0 .010 0 - 0028 P
Ivan-dlurn 292 . {O2 0.010 0.0025 P
ziJ,c 206,200 0.020 I 0,00,c5 P
D5r100153
12a
Commcntr r
STL Denver
Fom X - III
STL DENI/ER
Il{etals Analysis
-r0-
METIIOD DETECTION LIMITS
Coatract r IIBS Corlroratlon
LTb Co{lI: STI,DEN
ICP ID TiITrNbCr:
Cage No- l SIS ![o. l
Drtcr 11 lL2l2OA{r
SDc AIO. : D5f 1O0153
flanr .r.L ID ![umbcr;
Ilrrrnrec A.}, ID Nrntrror r
PE CVr^[,
.Baallft,r
$Ilv6 -
lcngrth
(nn!
Baok-
grouad PQI,
(mg/r,)
llDtr
(mglL)M
rcurJf 253 .7 0 0,00020 0.00004{glt
eL-"Es:
STL Denver Eomr X IN L22
STL DEIVVER
Total Metals Annlysis
-I0-
METHOI) DETI'CTION LIII{ITS
Contrrct r IIRS Cor?orat,ion
LaI) Code: STITDEN
ICP ID Ntrnbcr g PE ICP!,IS
Flarno .f,rL ID tihrmbcr:
furn'aea AA ID Numbcrr
Cata No.:SrS No. r
Date : 5lLOl"AAs
sDc No.: D5f100153
Arralfrte
Irotopr Blok-
ground,PQI,
(mgllr)
UDI,
(mg lr,)M
Cadml.urn 111 0.0010 o.0000{0 M
Scl,cnLurn 82 0.0050 0 .0003 DT
Commcntg:
STL Denver
FomXbIN
1,23
STL DENVER
o
co
Total Metals Analvsis
-114-
ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY)
ntracEs IrRS gorDoration , ..
Lab Code 3 Sr1.1TDEN Carc No. :SIS lib - 3
rcP rD Nlllnber r TiIA Intrepid rcP Dater 8 /L9l200s
gDC llo. : DSI100153
enalyte
Wavc-
lencrtsh
(nm)A1
fntcrcltrnent CorreetLon Factors
Ca FE
for:
Mg Ag
1^ . I 339.198ktf(*L1r Cr-rn I 0.0000000I o-ooooooo o.oooo0ool o.oo0oo0ol o.ooooooo
rluminrrm IfeZ.081 o. ooo0000 I o. oo0o000 0.00182001 o.oooooool o.0oooooo
elrrrnLnum I309.27!0.000oooo I o. o0ooooo o.oooooo0l o-00077401 0.0000000
Anrl,mony I ,oE. B38 0.0000000 I o-000oooo o.0oooo0ol 0-o0ooo0oI o.ooooooo
trsenlc I 189.0t2 0.0000000 | o-0000000 0,00000001 o. ooooooo I o. ooooooo
Barl,rrn I {t55. {03 0.0000000 I o. 00oo0oo o-oooooool 0.0000000I 0.0000000
serfrllfu:m 1313-0{2 o. ooo0o0o I o.0oooooo o.oooooo0l 0.00000001 o.ooooooo
Boron 1249 - 5?8 0-0000000J o-0000000 0.00000001 0. ooooooo I o. ooooooo
cadntLum l=25.503 0,0000000 | 0.0000000 0.0000d201 0.00ooo0oJ o-ooooooo
CalcLusr I 317.933 0.0000000 | o,0o0oo00 o. oooooool o. oooo32o I o. ooooooo
Calclum I a18.128\o-0000000| 0.0000000 o. oooooool 0.0000000 I 0.0000000
Itr"*iunr lzil.7!G 0.000oooo I o-0o0oo0o 0 . obooooo[ -4. ooooooo I o . 000000 0
cobalr 1228.516 0.0000000 I 0.0000000 o.0000oool o. ooooooo I o. ooooooo
corrper I fr{.?53 0.0000000 ! 0.0000000 -0.00002001 0.00000001 0.0000000
rron I 259.9{0 0.0000000 | 0.0000000 o. ooooooo J o. ooo0000 l 0.0000000
rron 1271-{d1 o.0000000 I o. 0000000 o.oooooool o-oo2o1ooI o-ooooooo
Lead lzz0 -3s3 0.0ooo0o0 I o.0ooo000 0.00000001 o. ooooooo l o, ooooooo
rithtr:m I 670. ?8{0.ooo00o0 I 0.0000550 o.oo00o0ol o,oooooool o.000o0oo
I{agDcsium lrl9.0?9 0.0000000 I o. ooo0000 0.00050201 0.00000001 0.oooo00o
Manganese |25t.510 0.0000000 I 0.0000000 o. oooooool o. oo0o150 I 0. oo00o0o
Molybdenum lzaz,030 0.0000000 I o. ooooooo 0. 0000000 | o. ooooooo I o. 0oooooo
rslckcl lrgl,5o4lz 0.0000000 | o-0oo0o00 0. oo000oo I o. ooo0o00 I o. oooo0oo
phogphonr.r I tr8 .28?0.0000000 I 0.0000000 0.0000000f o. ooooooo I o. ooooo0o
Potassiunr I 755. {91 o - 0000000 I o. 000o0oo o.oooooool 0.0000000 I 0.ooo0ooo
sclcnium I tg6. O9O 0.0000000 I o. o0000oo o.0ooooool o-oooooool o.ooooooo
gtllcon
I 251.612 0.0000000 I 0.0000000 0. 0000000 | o.0o0o0oo I o. ooooooo
silLcon l ro1. G15 0.0000000 | 0.0000000 0.00ooo00| o-oooooooI 0.0000000
Sllver I ,r8. 068 o. oo00o0o I 0. 0000000 o. oooooool o. ooooooo I o. ooooooo
Bod,lum I sag. 592 0.0000000 I 0.0000000 0. oooooo0l o. ooooooo f o, ooooooo
sodlum I are.326 0.0000000 | o.0o00oo0 o. oooooool o. ooooooo I o. ooooooo
[routirrm IAOz .,'tTL 0.000oooo I o. 00015?0 0. ooooo00[ o. o000oo0 I 0. oo0o00o
-Thalttum I rg0. gG{0 .0000000 I o. 0o0oo00 o. o0oooool o. ooooooo I o. ooooooo
Corurrentg:
STL DCNVCE
Forcm xf (PAnf 1) - fN
124
STL DE|VYER
Total Metals Anatvsis
-ltA-
ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY)
Contract: IIRS Comorat{on
Lab Cod,e r S1,ITDEN Caac No - :
Intrepid IePICD rD Dnrrnbsr: TifA Datn: 8 ll,glz00s
Commentg:
glg llo. r SDg No. i D5f100153
Trrortum I 283 .23 0 o-ooooooo I 0.0000000 il0o0-dE06l- 0.0000000 I 0-0000000
Tln lre9-989 0,0000000 I 0. o0o00oo o. o0oooool o. ooooooo I o.0o000oo
rLtanlum I fS{.941 o - oo0o0oo I -0. ooo0320 o.oooooool o.ooooz4o I 0.0000000
uranlum I gts- 958 0.0000000 I -0-0oo1o2o -0.00085{ol o.0o00o0of 0.0000000
vanadj.urn la9z.tA2 0.0000000I o-0000000 0.00010101 -0.0000130 I 0.0000000
zLnc I ,a3 .856 0.0000130 I 0.0000000 0.o0oo59ol o,0ooo000l o-ooooooo
STL Denvef 1,25
Form XI (PART 1) IN
STL DETYVER
Contraet r IIRS Comomtion
Total Metals Analvsis
-1lB-
ICP INTEREIJMENT C ORRECTION FACTOR,S (AN N UA tLY)
Carc No - :S^S No.:gDG No, r D5I1OO153rab Code t Sr1.frDEN
ICP ID Nrxnber r TJA Intrepid ICp Daeer 8 ll9l2005
Wave-
length
(nrn)
Intcreleurent CorrcctLon Factom for:
Be
Anallt,a
Ae B Ba cd
Z;..*...1 r^-.,r: I 339 - 198 0. o00oooo I o. oo00o00 o. oooooool 0.0000000 I o. oooo0oo
Alumlnun [ 162.081 0.0000000 I o.0o00ooo o. oooo00ol 0.0000000 I o. ooooooo
ntumlilun IgOg.ZTL 0. 0000000 | 0.0000000 o.0o0oo00l 0.0000000 I 0. ooooooo
AnrLmonfr 1206.838 0.0000000 | o. ooooooo o.oooooool o-ooo0o00I 0.0000000
Arranic lfAg-o4z o.00o00oo | 0.0000000 0. oooooool o. ooooooo I o. o00oo00
Barium I lss.403 0.0oo0ooo I o-000oooo o.oooooool 0.0000000| o-ooooooo
serylllum IerS.AtZ 0.0000000 | o-ooooooo o. oooooool o. ooo0000 l 0,00o0ooo
Boron lzi9.67g o .0000000 | o. o0o0o00 0,00000001 o. ooooooo I 0.0000000
cadnrLrrm l^16.502 o-000oooo I o-0oo0oo0 o.oooo0ool 0.0000000I o-ooooooo
calcLum I Sfz. g33 0.0000000 I o. o0oo0o0 o. ooo0o0ol o. oooooo0 I o.00oooo0
acalctum ISrB.12g 0.0000000 | o. ooooooo o. oo00oo0l o. ooooooo I 0.0000000
lEhromi,un 126l .7L6 0.0000000 [ o. o0oo000 o. oooooool o.00ooo0o I o. ooo0ooo
cobalr 1229.615 0.0000000 I 0. 0000000 o.oooooool o.oooooool o.ooooooo
coDper llzt- 753 o.0000000 I o. 00oo00o o. oooooool o. ooooooo I o - ooooooo
rron I 259.9d0 0.0000000 | o. oooo0oo o - oooooool 0.0000000 J o. ooooooo
rron ler l.cdl-0.0000000| o-0000000 o. oooooool o - ooooooo l o. ooooooo
r,aad !220.3 53 0.0000000| o-0000000 o. ooooooof o. oooo0oo I o.0ooooo0
rltbtr:sr I ozo. ?Ba 0.00oooo0 I o-0000000 0-o0oooool o-ooooo00l 0,0000000
Magr:aerLum lZZg - o7g 0.0000000 I o. ooooooo o. oooooool o. ooooooo I o. ooooooo
MangaDaro lzsl.6L0 0.0000000 I 0.0000000 0.00000001 0.0000000 | o. oooooo0
Mol]rbdaillm lZaZ.030 0.0000000 J 0.0000000 0.00000001 0.0000000 I 0. ooooooo
uieker l ra 1. 6 at t2 0.0000000 | o. o00oo00 o - oooooool o. ooooooo l o, ooooooo
Phosptrorua I178-287 o. ooooooo I o. ooooooo o. oooooool o. ooooooo l o, ooooooo
PotasrLum 17 65. {91 0.0000000 | 0.0000000 0.00000001 0-ooo0000l o.oooo00o
SelenLum I tg6.0gO o - oo0o0o0 I o. o0ooo00 o. oooo0ool o. ooooooo I o. ooooooo
stlLeon l ZuL.6Lz 0.0000000 | o.0000000 0.00000001 0.00000001 o-ooooooo
Stll.eon I ,St. G15 o.00ooooo I o. oo000oo 0.00000001 o.00oo0ooI o-ooooooo
Eilvcr I ,rB.06g 0. oooooo0 I 0.0000000 o.oooooool o.ooooooof o.ooooooo
Sodium I ut9.592 0. 0000000 | o. o00oooo o. oooooo0l 0.0000000 | o. oooooo0
sod{um I gr 9.326 0.0000000 I o. oooooo0 o.ooooooof 0.o0ooooof 0.0000000
ftrontium f aOZ .7't!0 . oo0oooo I 0. 0000000 o. oooo0o0l o, ooooooo I o. ooooooo
rhal1lum l 190, BG{0.0000000 I 0.0000000 o. oooooool 0.0000000 I o. oooo0oo
Coumant,s:
STL Denve
I'onn XI (PART 2l - I,N
]-26
STL DENVER
Total Metals Analvsis
-1I8.
ICP INTERELEMENT C ORRECTION FACTORS (ANNT}ALLY)
Contract: IIRS Corncoration
rab Cod,ai STLDEN
IcP ID Mrmbef : TirA
Cara No. :
Intrepld ICP
gtrg No-:
Dater 8 /L9 l?AAs
gDc NO-: D5I100153
ThorLurn I 283.73O 0. oooo00o I 0.00o000o 0-00000001 0-00000001 o-ooooooo
TLa I 139.989 o.0000000 I 0.0000000 o.0ooooool o-0000000I 0.0000000
rl"taninn I eg{.9{1 0.00ooooo I 0.0000000 o , oooooool o, o00oooo I o. ooooooo
uraniun I 38s.958 0.0000000 I o.0oooo0o o. ooo0o0ol o. ooo0o00 | 0. o0o00oo
vanrd,ium IZSZ.4O2 o. ooooo00 I 0.0000000 o, oooooool o. oo000o0 I 0. ooo00oo
zine I zrr.856 0.0000000 I o-0000000 0.00000001 o.oooooooJ o,o0ooo00
Connents:
STL Denver
Porm XI (PART e)IN
127
STL DENYER
Total Metals Analvsis
-118-
ICP INTERELEMENT C ORRECTION FA CTOR,S (ANNUA LLY)
ConEraet: IIRS Corporatlon
Lab Cod.e: Sa,ITDEN Cage No, !
Intrepid IePICP ID lllrrnber r TJA
g.Lg No. :
DaEo: I |L9/2OO5
gDc NO. g D5I10O153
Analrt,e
Wave-
langttr
(nm)Co
Interelocnt CorroetLoa Fastorg
Cr C\r
forr
K ![n
'z-.. I agg. 198A- I r(C''r'lr oL\h I 0.0000000 I -0,0012800 o.0oo0o00l o. ooooooo | 0.0000000
AlrrrLtnrrn I 157 . 08 t o. ooooooo I 0,0000000 o. ooo0oool o. ooo0o00 I 0.00ooooo
.e,Iuninum lgO9.27L 0, ooooooo I 0.0000000 o. oooooool o, ooo00o0 l o - ooooooo
Antimony I ZOe.838 o. ooo0ooo I o.0000000 0.00000001 o-oooooooI 0.0000000
Arsonic I 189,042 0-0oooooo I o.0000000 o. o0o0o00l o. ooooooo l 0 - 0oo00oo
Barturn I aSS. OO3 0.000oooo [ 0.0000000 0.00000001 o. oooo0o0 I 0. ooo0ooo
Berylltr:m 1313 .A{2 o. oooooo0 | 0.0000000 0.00000001 o,00oooool o.oooooo0
Boron lza9.6?B o - 0000000 | o. ooo0oo0 o.oooooo0l 0.00000001 0.ooo0ooo
Cadurlun 1116. 502 0.0000000 I o.0ooo00o o. o0oooool 0.0000000 I 0.0oo00oo
calcium I arz.933 0.0000000 | 0.0000000 0.00000001 0. ooooo0o ! o. ooooooo
calclum I arA.128 0-0000000 | o-0oooooo o.oooo0ooI 0.0000000I 0.ooooooo
Tclrrord.um 126z.7L6 o-0000000 I 0.0000000 o.00000001 o. ooooo00 I 0.0000720
Cobalt lrr8.6t6 0.0000000 I o. o0ooooo o. oooooool o. ooooooo I o. ooooooo
copper I 324.283 0.0000000 | o. oo0o000 o.oooooool o.oooooool o,ooooooo
rron I 259.9{0 0.0000000 I 0.0000000 o. oooooool o - ooooooo l o, oooo0o0
rron lzll-d{tt 0.1300000 I 0.0000000 o. ooo000ol o. ooooooo I 0.0000000
r,ead 1220.353 0.0000000 I 0.0000000 0.00000001 0.00000001 o.ooooooo
rithir:n I 6?0.78d 0.0000000 I 0.0000000 o - oooooool 0.0000000 | 0.0000000
MagncrLum |.rr9.079 0.0000000 I 0.0000000 0.0oooooof 0.0000000 I -0 ' 0035690
Manganortr lzsl.6t0 0.0000000 | o. o0o00oo o. oo0ooool 0.0000000 I 0.0000000
uolybderurm 1202. 03 o 0.0000000 | o. oo00o00 0.0oo0oo0l o-ooo0o00 I 0.ooo0ooo
Nlcke1- I 231.6 A4/Z 0.0000000 I o-ooooooo o.oooooool o.oooooool o.ooooooo
phosphorrrg Jfrg.zB7 o-0000000 I 0.0000000 o. 0o0oo0o I o. ooo0000 I o. ooooooo
PotasrLum l, e5 - {191 0.0000000 I 0.0000000 o. ooo0o0ol o. oooo000 | o. o0o0ooo
selenLum I 196.090 0.0000000 | o. ooooo0o o.oooooool o-oooooool o.ooooooo
stlicon ll25j..6L2 0.0000000| o-ooo0o00 o. oooooool o. ooooooo I 0.0000000
sllicon I 251.515 o.0000000 J o. oo00o0o o.oooooool o.oooooool 0.0000000
sllver I ,rB. oGB o. 0000000 I 0.0000000 o.oooooool o.o0oooool o.ooooooo
Bodium I sg9.59z 0, 00ooooo I 0,0000000 o, o000oo0l o. ooooooo I 0.0000000
sodium I Atg.326\o.0o00o0o I o. o00o0o0 o.oooooool 0.00000001 0.0000000
fstrontlurn I aoz .77L o. oo00ooo I o. oooo000 o. ooooooo I o. ooooooo ! o. o00oo0o
Tha.lllrrrrr I rg0.86{0.0000000 I o.0000000 0. o0ooooo l o. o00o00o l o. oo0000o
Comnentg:
STL Denve
2l-rNForm XI (PART
T2B
STL DENYER
Total Metals Analvsis
-t18-
ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY)
Coatract: IIRS Corooratlon
Lab Codtr 3 STIJIEII Cage No.:
fntrepid ICP
g.f,g lilo. r gDg NO.; D5f1O0153
ICP rD lnrnbcr: T.IA Dat,er S lLgl?OOs
Conurretrts:
STL Denve
rhorl,um I 283 - 73 0 0.0000000 I 0.0000000 0. oooo00ol 0.0000000 I o. ooooooo
Ttn I rr9-989 0.0000000 I o.0000000 o. oooooool o. ooo0000 I 0.0oooooo
ritanl-um l33A.g{1 0.0000000 I o. ooo315o o. oooooool 0.0000000 | o, oooooo0
uranLum l gg5.95B 0.0000000 I o. o0ooooo o-oooooool 0.00000001 o.oooooo0
vanadlun I ZgZ.i}z 0-0000000 I o.ooozzga o.oooooool o-oooooooI o-0000000
zlnc Izrr-BsG o - 0000000 I 0. o0ooo0o o. ooo9{4ol o, o0ooo0o l o - ooooooo
Form XI (PART 2l -IN
L29
STL DENVER
Total Metals Analvsis
-1lB-
ICP INTERELEMENT CORRECTION FACTORS (ANNUA LLY)
Contract r IIRS Corrooration
Lab Code r 6ayTDEN
rcP rD lllrrnber: TJA
Care No. :
Intrepid ICP
g.f,g No. r
Pate: I /L9l?AOs
gDG I{O. r D5f100153
Wavc-
lengttr
(nm)
fnterelancnt Correetloa Fastorg for r
PbAnaltrteNi Sf)Mo Na
'z;r@ti
^.....-, I ,39 - 198 0.0009000 J 0.0000000 o. oooooool o. ooooo00 l 0 ' 0000000
Aluminurm IfeZ-081 0.0000000 I o-ooo0o0o o - 0ooooool 0.0000000 I o. ooooooo
x,lrrrrtnum lfO9.27L o. oo0o000 I o. oooooo0 o.ooo0oool 0,oooooool 0.0000000
Anrimony I ,o6. B3B 0,0000000 | o. ooooooo o. ooooooof 0.0000000 J 0.0000000
.Lrronie Ittg-a42 0.0000000 I 0.0000000 o.oooooool o.oooooool 0.0000000
Barlum I ous-{03 0. 0000000 I o.0000000 o. ooooooo I o, ooooooo I o .00oo0oo
BeaTrlll,nr lf fs .A42 0.0000000 I 0.0000000 o.0000000I 0.0000000| 0.ooo00oo
noron lZog - 6?8 0.0000000 I 0. oo00oo0 0.00000001 o, ooooo0o l 0.0000000
cadmirrnr IZZA.502 o. 0000000 | o.00o0ooo -0.00o19?ol 0.0000000 J o. ooooooo
calclun If f2.933 0.0000000 | o.00ooooo o.oooooool o.oooooool o.ooooooo
aCalcluur I318-128 0.00o0ooo J o.00oo00o o. oooooool o.000oooo I 0.0000000
pbrontuur 1257 .7L6 0.0000000 I 0.0000000 o.0o0ooo0[ o.oooooool 0.ooooooo
cotralt 1228 . 616 0,0000000 I 0.0000000 0.00000001 0.000oooo I o. ooooooo
copper I 32 t.zs3 o.0003{00 | 0.0000000 o.oooooool o.oooooool o-ooooooo
rron I zss.g{o 0.ooooo0ol 0-00ooooo 0. o0oooool o. ooooooo I 0.0000000
rron lz7 1. {{1 0.60r.sooo I 0.0000000 o. oooooool o, ooooooo l o. ooooooo
r,ead |220.353 0.0000000 I 0.0000000 o. ooo0o0ol 0 .0000000 I o. ooooooo
r,lthiun, l6T0.TBd 0,ooo0o00 J o-0000000 0. oooooo0l o. ooooooo I o. ooo0oo0
MagnesLum lZrg-079 -o,0358000I o-o0ooo00 o. oooooool o. ooooooo I o. ooooooo
Manganaae 1257.6L0 0.0000000 ] o.0o0oo00 0. oooooool o. oo00ooo I o. ooooo0o
Molybdonum 1202.030 0.0o0o0oo I 0.0000000 0.0003{00J o.oo0000ol o.ooooooo
Hickel I 231.5 Ar 12 o. oo000o0 I 0.0000000 o.00000001 0. o0ooooo I 0.0000000
Phogphonrs I f r8.28?0. 0000000 I 0.0000000 o.oooooool o.oooooool o.o0ooooo
Potasgiuxr I 755. {191 0.0000000 ! o,0oooooo o-oooooooI o.oooooooI o.ooooooo
selenLum I 195.090 o.ooooooo I o.0000000 o.oooooool o.oooooool 0.0o00ooo
gtllcon
I 25L.6L2 0.0092000 I o.0ooo0oo o.0000000J o. oooooo0 I 0.00o0ooo
sLl l,eon lrur..Gls 0.0 092000 I 0.0000000 o. oooooool o.00ooooo l 0,0000000
sllver I 3zB.06g 0.0000000 I 0.0000000 0.0000000! o.ooooooo I o.o0oo0oo
sodlum I st9.5g2 0,0000000 | o. oooooo0 o. oooooool o. ooooooo I o. o000ooo
Sodlum I gr8.326 0.0000000 | o-o0ooo00 0.oooooooJ o. ooooooo I 0.0000000
)trontium looT -l"tL 0.0000000 I o. oooo000 0.000oooo[ o. ooooooo I o. oo0oooo
Tbnllium I rg0. g6{0.0000000 I 0.0000000 0.00000001 o.oooooooJ o-ooooooo
Cornrnents:
STL Denvc
Fom xI (PART 2 )IN
130
STL DENYER
Total Metnls Analvsis
-llB-
ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY)
contracts IBSIgAO[elion
Lab Code: SI1,LDH{Cags No. t
rntrepLd fCPfCP ID ttumber: TifA Datc: 8lt,glzOOs
SAS No. :sDC !rO. : D5I100153
Tlrorlum 1283 -730 o.ooo0o0oI 0-0000000 0.00000001 0.0000000 I 0.000oooo
.fin ltgg.ggg o. ooo0ooo I o.0000000 o. o0o0oool o. ooooo00 I o. o000ooo
Titanl-urn 133{.9{1 o. ooo0o00 I 0.0000000 o. ooooo00l o. ooooooo I 0.00o0ooo
uranlum I re5. gs8 0.0oo0oo0 I 0.0oo00oo 0.00000001 o-0000000I o.ooooooo
vanadl,un 129? - 4oz -0.0175000 I o.0oo0o00 o.oooooool 0.00000001 0.0000000
zLnc J zra. gs6 0.0oooooo I 0.0000000 0.00{3800f o. ooooooo I 0.0000000
COrmrents:
STL Denve
For:m XI (PIRT 2l IN
131
STL DENVER
Total Metals Analvsis
-I IB-
ICP INTERELEMENT C ORRECTION FA CTORS (ANNUALLY)
Contraet r IIRS Comoration
rab Code r ETIJ)EI
ICP ID !fiunberr |P.T}.
Carc No - :
Intrepid IcP
gAg IIg. :
Datc: I lL9l2OO5
sDc No.: D5I1OO153
Wave-
].ength
(nm)
rntcrelerreat, Corsctlon ractors for:
SrAnal.lte si Sn rlSe
Z; n(c.r,-r i r-*-r^. I 339 ' 198 0-o00oo00 I 0.0000000 o-oooooool o.0000000] o-oooooo0
lluminuun I 16? - 08 t 0.0000000 | 0,0000000 0.oooooool o.oooo0ooJ o-o0ooooo
rluml-num I 30 9.27L o - 0000000 I o. 0oo00oo o. oooooool o. ooooooo I 0.0000000
rntLmony
1
205.838 o. ooooooo I 0.0000000 0. ooo0000 | o. ooooooo J 0. 0000000
AnenLc I t8g. 0{2 0.0000000 I 0.0000000 o. oooooool o. ooo0o0o [ 0. oo000oo
Barium I uus- 003 0-0000000 | 0.0000000 0.0000000f o.0000000 I *0.0001930
Ber:rllium Iaff .042 o-ooooooo I 0.0000000 o.0oooooof o.oooooool o.ooooooo
Boron lzrg - G7B o.00o00oo | 0.0000000 o. oo00o00l o. ooooo00 I o. ooooooo
Cadmi.nm 1226. S0z 0.0000000 I o. ooooo0o o - ooo00ool o. ooo0o00 I o. ooooooo
calciun I afz. g33 o-oooo0oo I 0.0000000 0.00000001 0.00000001 o-ooooooo
calcLum
1 318.1 28\o - oooo0oo I o. oo0o0oo 0.ooo0o00l o-oooooooI 0.0000000
Fhromium Iro7 .zLG o - 0000000 I o. o0o0ooo o.00ooo0o ! o. 0000000 I o. ool2ooo
cobalt |1228.615 o. oo0oo00 I 0.0000000 o.ooo00ool 0.0000000 I o.oo18ooo
co1>3lar I gz{. ?s3 o.0oooooo J 0,0000000 0. oo0ooo0 I o. ooooooo ] 0.0000000
rron [ ?59.9{0 0-0000000 I 0-0000000 o.oooooool o.ooooooof o.ooooooo
rron lz7 1. d41 o. oooooo0 | 0.0000000 0.0000000J o.oooooooJ 0.0000000
Lcad lzz0 - 3i3 o. oo00oo0 | 0.0000000 o. oooooool o. ooooooo J o - ooooooo
rltuiun I Gzo. TB{0. 0000000 [ o. o0o000o o. ooooooof o. ooooooo ! o. ooooooo
r{agnerLrrm lZ7 9. or9 0.0000000 I 0. o0o00oo o. ooooooo I o. ooooooo I o. ooooooo
Mangranese lzsl.610 0.0000000 I 0.0000000 0. 0oo0ooo I o. oooo000 I 0.0000000
lcolybd€num I 202 . 03 0 0.0000000 I o. ooo0o00 o.oooooool 0.0000000I o-ooooooo
Nickel lrl1. 6 a4 l2 0.0000000 I 0.0000000 0. oooooool o. ooooooo I o. ooooooo
DhosDhortrr Itr8.297 0.0000000 [ o. ooo0ooo 0.00000001 0.00000001 o.ooooooo
Potasglum l, s5. {91 0 .0000000 I o. o0o00oo 0.ooo0oooI o.oooooooI o-ooooooo
selonlum I tr6.090 0.00oo0oo I 0.0000000 0.00000001 o, ooooooo l 0.0000000
silicon I zs1.61a 0.0000000 I 0.0000000 o. oooooool o. ooooooo I 0.0000000
silicon I zrr.6t5 0.0000000 I 0.0000000 o.oooooooI o.oooooooI o-ooooooo
sitver lrr8.oGB 0.0000000 I o.00oo0o0 o. ooooooof o.00o0ooo | 0.00035{0
sodium I 589.592 0.0000000 I o. oo0o0oo o.0ooo000l o.oooooo0J 0.ooooooo
sodtum I
gt8.3z5 0.00o0ooo | 0,0000000 o. ooooooof o. oo0o000 I 0.0000000
)tronttum I40T .T7L 0.0000000 I 0,0000000 o. oooooool o. ooooooo | 0.0000000
rhallturn IfSO.86{0.0000000 I 0.0000000 o. ooooooo l o. oooooo0 l 0.0000000
Corurrentg:
STL Denve
Forrm xI ( PI.RT 2 )bIN
1,_32
STL DENVER
Total Metals Analvsis
-IIB-
ICP INTERET.EMENT CORRE TTON FACTORS (ANNUALLY)
Coatract: uRg Corooration
Lab Codc: S1.I,1)EN Cage No. r g.LS No. :sDG I{!O. s D5f1OO153
ICP fD lllunbcr: Tin, Intrepid, ICp Date: 8 1L9 lz00s
Corurreot,S:
Thorlum I 283.730 o-oo0oooo I 0.0000000 0.00000001 0.00000001 o-ooooooo
Tl,n I 199.989 0.0000000 I 0.0000000 0.00000001 o.oooooo0l 0.0oooooo
rltanlum I 334.941 0.0000000 J o. o00ooo0 0.00000001 o. oooo000 I 0. o0o0ooo
uranlrrsr l3B5-9S8 0.0000000 [ 0.0000000 0.00000001 0.0000000I o-oooooo0
vanadiunr I 29? -l}z 0.0000000 I 0, o00ooo0 0. oo0o000l 0. o0000oo J o. oo0{100
zt ne I zrf. gso 0.0000000 I 0. oooooo0 o. oooooool 0.000oooo I 0.0000000
STL Denvef
Form XI (PART 2I IN
133
STL DENYER
Total Metals Analvsis
-1IB-
ICP INTERELEMENT C ORRBCTION T'ACTORS (ANNUALLY)
Contraet r IIRS Corrnoration
r,ab Code, SIIITDEf,{I
ICD rD lltrmbar: TJA
Carc No. :
IntropLd ICP
gAS No.;
Dato: 8 lLg/2OOS
sDe No.: D5I10O153
wavo-
length
(nn)
Intcrclcmanrt Corcctioa raetors for:
?,ltArurlntcT1 ThUv
a. lagg-lggl-'t f:Lcr?a ' fA Y7\ I 0.0000000 I 0.0000000 0. o00o0oo I o. ooooooo I 0. o319ooo
rlrrmLrrum lfez,O81 0-oooooool 0.0000000 o. oooooool o. oooo0oo ! o - 0000000
Alnrrl,num 130 g.Z7L 0 .0000000 | o. ooooooo o.o0oooooJ o.oooooool 0.0000000
AnrLmony I 205.838 o .0000000 I 0.0000000 0.00000001 o-oooooool o.0000ooo
rrgenlc I 189 .A$z o . oo0oooo I o. o0o00o0 0 - 0000000 I o. ooooooo I 0. oo0oooo
sarir:sr ld5S.{03 o. ooo0o0o I 0.0000000 o.oooooo0l o-ooooooo| 0.0003030
nerylllum Jf rf .042 0.0000000 I 0.0000000 0.00035901 0,0000000 1 -0.0000100
Boron I z{g.6z8 0-0oooooo I 0.0000000 0 - 00000001 o. ooooooo | 0.0000000
cadmirrm lZ"G. s02 o-ooooooo I -0.0002070 0.00oooool o-ooooooo[ 0.0000000
calcl.um I af Z.933 0.0000000 [ o-o00oo0o o - ooooooo I o. ooooooo I 0. 0000000
{alcirrm Ifre.lz8 0.0000000 J o, o00ooo0 0.00000001 o. oooo000 I 0. o559ooo
lhronl"um l2G7 .lLG 0.0000000 [ 0.000?060 0.00000001 o.oo0oo00 I -o,ooo597o
cobalt |228.615 o. ooooooo I o. o0oo000 0.00000001 0.0oooooo I o. oooooo0
copper I szt.753 0.0000000 I 0.0009 tzo 0.00000001 o.o00o00ol o-oo232oo
rron I ,r9.9do o.0000000 I 0-oooo0oo o.ooooooof 0.0000000I o-ooooo00
rron ln 1.4c1 o-0000000 I o.0o0oo00 o. ooooooo I o. ooooooo I o. ooooooo
r,ead lrr0 .3 53 0.0000000 J o.0oooo0o o - oooooool 0.0000000 I o. oo0oooo
r,ithtr:m |.670.zBc 0.0000000 I 0.0000000 o. ooooooo I o. ooooooo I 0. 00o00oo
Magrnesiun l^r9-029 o. oo0oooo I 0.00?5500 o,00000001 o. 0oo000o I -0.0{118000
Manganoso lzst.610 0.0000000 I o. ooo122o -o.00016801 0.0000000 I 0. 0000000
Drolybdcnum lzoz. 03 o 0.0000000 I -0.0002050 0,0000000f o. ooooooo I 0.0017500
xickel I ,s r.6 0L tz o-0000000 | o-0000000 o.oooooool o.oooooool o.ooooooo
nhotptrorus I trg. aB?0 ,00o0ooo J 0.0000000 0,00000001 o. ooooooo | 0.0000000
Dotassiunr l, e6 . d91 0.0000000 I 0.0000000 0.00000001 0.0000000 I 0.o0ooooo
SclonLum I 196.090 o-0000000 I o.0o00ooo o. oooooool o. oooooo0 J o. ooooooo
sllLeon I 451.612 0.0000000 I o. oo00ooo 0.o0oo0o0l 0.0o0ooool 0.0000000
stll.con IZo1.G1s o.0o000oo | 0-ooo0ooo o.oooooool o.oo0oooof o.ooooooo
Sllver I ,ra. o6g 0.0000000 I -0. 0002200 -0.01490001 0.0000000 I 0.0005880
Sodlum I rge. se2 0.0000000 | o.0oooooo o. ooo0oool o. ooooooo | 0.0000000
sodium I efa.3zEL.0.0000000 I 0. o00oooo o - ooooo00l o. ooooooo I 0. 0o0oo00
[ronrlum I loz .77L 0.0000000 I 0.0000000 0.00o0oool o. ooooooo I o.0o0oooo
Thatllum I 190.85{0.00000001 0.0000000 0.0000000[ o. ooooooo I o. ooooooo
Comnents:
STL Denve
Form XI (PlRr 2l IN
L34
STL DENYER
Total Metals Analysis
-llB-
ICP INTEREIJMENT CORRECTION FACTORS (ANNUALLY)
coEtracti IIRS Cefporation
Lab Code 3 STIJ;IEI{Cara No.:
Intrepid. IePICP ID lrrrmbgr: TifA Datra: I /L9l?OAs
gAg No. r gDGl NO. ; D5r100153
Tlrorium 1283 - 730 0.0000000 I 0.0155000 0-o0000ool o.ooooooo I o-ooooooo
Tln I re9.989 0.0000000 I o. ooooooo o.oooooool 0.0000000 [ 0.0000000
TltanLum I ,r{.9{l 0.0000000 I 0.0002850 o. oo0ooool o. oooo0oo | 0.00ooooo
uraulum I ras.95B 0.0000000 | 0.0000000 0.ooo0oo0l 0,0000000 I -0.028?ooo
vanadirrm I,rz-e.A2 0 - 0000000 I -0.0 aaztao o. o0ooo0ol o - ooooo00 I 0. 00 15600
zLnc lzrr-856 0. 0000ooo | 0.0000000 0, oooooo0l o. ooooooo I o. 0000000
cottngnts:
STL Denve
E'orrn Xr ( pnnt 2l -IN
135
STL DENYER
Contract r IIRS Cor:ooration
Total Metals Analvsis
-1lA-
IC P INTERELEMENT C ORRE CT ION FA CTOR^S (ANNUA LLY)
Cage No. t g.f,g IIo. t
Pate t 7 l23l?AOs
r,ab Codes STLDEN
ICP ID Number: SUPERTR.LCE
SDc No.: D5I1O0153
Wavc-
lenCrth
(nn)
raterelement CorrcctsLon Factors for r
Mg
rnal1ru,e Fe .B'gA1Ca
ehml.nuln 1308.21s 0.0000000f o-0ooooo0 o - ooo11oor o. o00o29o I o. oo0ooo0
Antimony I 205.838 0.0000000 I o-00o0oo0 0.0ooo22ol 0.0000000 I o. ooooo00
rrgenlc I18g-ot2 0.0000000 I 0. ooooooo -0.0000160f o. ooooooo I o.0000000
Barl-un Jlef.{09 o, o0o0oo0 l o. ooo0ooo o.oooooooI o.oo000ooI o-ooooooo
Barryrlllum I 313 .0{2 o.oooooool 0.0000000 o. o0oooo0l o. ooooooo I o. ooooooo
Boron lztg. G?B o. ooooooo I 0.0000000 -0.00007001 0.0000000 I 0.0000000
cadmirrm, 1225. 502 0,0000000 I o. o0ooooo o.ooo141ol 0.00000001 o.oo0ooo0
calcium IfrS-933 0.0000650 I o. ooooooo o - ooooooo I o. ooooooo I o. 0o0oo00
chronLun lZe 7.7LG o. ooooooo I 0.0000000 -0.00001001 o.o0oooo0 I 0.0000000
cobalt 1228.616 0.0000000 I 0.0000000 o. ooooooo[ o, ooooooo l o. ooooooo
lcornar Jsza.zs3 0.0000000 I 0.0000000 -0.00002501 0.00000110 I 0.0000000
Eron lz71- {{1 0.0000000 I 0.0000000 0.00000001 0.0003{00 I o. ooooooo
Laad 1220.3 51/1 0.0002970 I O.00o00oo o. oool3ool 0.0000060 I o. ooooooo
Load lrro.3 sttz -0.0001800 J o. oo00o00 0. ooooSool o. ooooloo I o. ooooooo
l4sgrnogLus l2?9.078 0-00oooo0 I 0.0000000 0.00002701 o-0000000I 0.0oooooo
I,Iangranese lZSl. 610 0,0000000 1 o.00ooooo -0.0000060[ 0.00002oo I o.0000000
l,lohzbdenun I 202 - 03 0 0.00oo0oo I o. ooo0oo0 -0.oooolaol o.0000oool 0.0000000
lulclccl l 23 1- 6 0l 12 0.0000000 I 0.0000000 0.00000001 o. o0ooooo I 0.0000000
Selenl-um I 196.02 Ll L -o - 0000030 I o. o0o0o00 o, ooooozol o. ooooo{o I o - ooooooo
Selenlunr 1
196,0 21 /2 o-o0oooool 0.0000000 -0.00017801 0.0000000 I 0.0000000
stllcon I 288.158 0.0000000 I 0.0000000 0.00000001 o. oooo000 ] o. ooooooo
gilver I gra.05B 0,0000000 I o. ooooooo o. oooooool 0.0000000 I 0.0000000
Strontluur 1421,552 0.0000000 | 0.0000000 o. oo00o00l o. ooooooo I 0.0000000
|rhalltufll I tgo. g64 o. oooo000 I 0.0000000 o . oooog6o I o. oo0oooo I 0.0000000
Thoriurn I{01.910 0.0000000 I -0.0000250 0.0000000! o,oooooool 0.0oooooo
rin I 189.989 o. ooooooo | 0.0000000 0.00000001 o. oooooo0 I o. ooo0ooo
tltanlum I ,r{.9{1 o. oo0o000 | o.0000000 o. o000oo0J o. oooo2oo I o. ooooooo
Uranirrn I sgE.958 0.0000000 I -o. oooo3oo o. ooo86o0f o. ooo0140 | o. ooo0ooo
vanadlum I afe .$oz o.0o0o0oo I 0.0000000 -0.0003{o0l 0. 0000000 I 0. 0000000
zlnc l rt3. 956 0.0000000 | o.0o0oooo o. ooooooo I 0.0000020 I o. 00o00oo
Comneats:
STL Denve
Form. XI (Prnr 1)-rN
136
STL DENYER
Contract r IIRS Comoration
Total Metals Anatvsis
-I IB-
ICP INTERELEMENT C ORRECTION FACTOR^S (A N NUALTY)
Cage No. r gAS No. t
DatG: 7 l23l2A$s
Lab Code r BT1TIIEI{
rCP ID lnrmbgf : 8UPERTRACE
gDG No.: D5I100153
Wawc-
lengrth
(nn)
Intarclament Correctlon ractors for:
Be.Lnaltte cdArBBa
l,lutrrinrrm I 308.2L5 0.0000000 I o. o00oo00 o. oooooool o.0oooooo I 0.0000000
Antimony lrO6-838 o, ooo0oo0 | 0.0000000 0. oooooool o, oo0oooo I o - 0000000
rrsenLe I tt9.042 0.0000000 | o. ooo0ooo @ -o-ooooooo I o.ooooooo
EarLum lag3.{09 0,0000000 | o-0000000 o. oooooool 0.0000000 | o. oooooo0
Barylll-um 1313.0{a 0.0000000 | o. ooooooo o. oooooool o. ooooooo | 0.0000000
Boron lrag. OZB 0,0000000 I o. ooooooo o. oooooool o. ooooooo I o . ooooooo
Cadmfu:sr 1226. 502 0-o0ooo00 I 0.0000000 o. ooooooo! o. ooooooo I o. ooooooo
calclum I srr.933 o-0000000 I 0.0000000 0.0000000t o. ooooooo I o. oo0000o
Chromlum lz6: -215 0.0000000 J o. o0oo000 o-ooooooof o.oooooool o.ooooooo
CoIraLt, 1228.616 0.0000000 I 0. o00ooo0 -0. ao1[2000l 0.0000000 ] o. 0000000
coppcr I ar4 -7s3 0.0000000 J o. ooooooo o.oooooool o.oooooooI o-ooooool
rron 1271-{{1 0.0000000 [ o.0oooooo o.oooooool o.ooooooof o.ooooool
r,ead lzz0.3 stll 0.0000000I o-oooooo0 o. oooooool o - ooooooo l o. ooooooo
Lead 1220.3 5Ll2 0.00ooooo | 0.0000000 0.00000001 o-ooooo0oI o.oooooo0
llagnesl"urn lrr 9. 078 o. ooooooo | 0.0000000 0.0000000r- 0.00000001 o'0000000
Manganese 1257 . 610 0.0000000 | 0.0000000 o.oooooool o.oooooool o-ooooooo
Irrolybdorum I 202. 03 0 0.00oo0ool o-0oooooo o - ooooooo J o, ooooooo I o. ooooooo
rsickel lrg1.6aLt2 0.0000000 | o.0ooo000 o. opoooool o. ooooooo I o. ooooooo
gelenium 1196-02tlL o. ooooooo I o. o0oo00o o,0o0oo0ol o. ooooooo I o.0o0o0oo
salcnium I 195.02Lt2 o-oo0oooo I 0.0000000 0. 00000001 o, ooo000o l o. ooooooo
siricon I zBB. l5g 0.0000000 I 0.0000000 o. oooooool o. ooooooo I o.0oooooo
gllver I gza. 068 0.0000000 I 0.0000000 o.ooooooof o'oooooool o.ooooooo
Strontlrrrn I 4?1- 552 0.0000000 I o. ooooooo o.oo0000o[ o-oooo0o0] o.0oooooo
tr,hal-lt um I 190. 96{0,0000000 I 0.0000000 0. 000oooof o. oo0oooo I o.00ooooo
Ttrorlum I 001. 910 0.0000000 I o.0ooo0oo o. oooooool o. ooooooo J o. ooooooo
rLn I te9.9a9 o. ooooooo I o.00ooo00 o.oo0ooool o.oooooool o-ooooooo
ritantum
I
ara.9cl o ,0oooooo | 0. o0ooo00 o. ooooooof o, ooooooo l o. ooooooo
uranlum I 3Bs.95g 0.0000000 I o. ooooooo o. ooooooo[ o. ooooooo I o. ooooooo
varradlum lrg2.lO2 o.0oooooo [ 0.0000000 0.00000001 o. ooooo0o I o. ooooooo
zlnc I213-B5G 0.0000000 | 0.0000000 o, oooooool o. ooooooo I o - ooooooo
Fot:r XI (PAR[ 2)-IN
Coumentg:
STL Denve
STL DENVER
Contract: IIRS Corooration
Total Metals Analvsis
-llB-
ICP TNTERELEMENT C ORRECTION FA CTORS (ANNUALLY)
Cage No. r sAg lib. :
oate t 7 /23l2OAs
Lab Codos STITDEN
rcP rD Nt[ubcr: SUPERTRACE
SDO NO. r D5r1001s3
Anallt,e
Wave-
lencrth
(nm)
Intarclament CorrectLon factorg
Cr Cu
for r
Mn MoCo
eluntnum Ifo8.Z15 0.0000000 | o.00ts00o 0.0000000f o. ooooooo I 0.0058500
AarLmony I 206.838 0.0000o0o I 0.0038900 0.0000000 I o. 0000000 I -o. 005sso0
ArrenLc I 189.O42 0-0000000 I 0.0001?00 0.00000001 0.00000001 o.ooo31oo
aarlum I {93. cog 0. ooo0ooo I 0,0000000 o.oooooo0l 0.0000000 I 0.0000000
ner1rllJ.tlsl Ieff .A$2 o. ooooooo I o. o0o0o00 0.00000001 0.0000000 [ o. ooooooo
Boron 1249.6?8 0.0009800I 0-oo0oo00 o.0ooooool 0,0000000 1 o. ooooo00
CadnLuur lrZ6 - s0,-0.0002200 I 0,0000000 o. o0000ool o. ooo0oo0 I o. ooooooo
calct rrn
1 319 . 933 o - 0000000 1 o. ooooooo o. ooooooof 0.0000000 | o. o00o0o0
clrromLurn lre 7 -'lL6 0.0000000 | o.0000000 o.00000001 0.0000000 I -0.0001700
cobalr Iza8-615 0-00000001 0.o000ooo o. oooooooJ o. ooooooo I o. ooooooo
,conncr Iaal-zs3 0.0o0oooo J 0.0000000 0.0oo0oo0l o. ooooooo I 0. 000ooo0
Trron lz71 - o{1 0.0885900 | 0.0030800 0.00000001 o. ooooooo I o. ooooooo
r,ead lzzo-3sl t]i -0.0020470 | 0.0000000 0.00000001 0.0000000 I -o.0009600
r,ead 1220.3 sL/z 0.0000000 I 0.0000000 0.00000001 0.0000000 I -0.0002600
Magrnoslrrn lZrg - ozB 0.0000000 I 0.0000000 o. ooooooof o. oooooo0 f o , 0o000oo
Manganoae I asz.610 o-oo0ooo0 I 0.0000000 0.00000001 0.0ooooooJ o-oooooo0
uolr'bdonurB I ZOe . 03 0 0.0000000 I o. ooooooo o. oooooool o. ooooooo I o. ooooooo
uLckcr Irgl-6ottz -0.0005200 | 0-0000000 0. ooo0oool 0.0000000 I o. ooooooo
gelenl.trm I ,g6 . 02 1, t L o.ooosoool 0.0000000 0.0000000J o. ooo3soo I 0.0000000
soloniun I tr6.02 Ltz -0. 0001s00 I 0.0000000 o.000ooo0l 0.0002200 | o. ooooooo
silLeon l rre.15B o. ooooooo I o. ooooooo o. oo0000o[ 0.0000000 I -0. 00{3{00
sLlver I 3ag.OGg 0.0000000I o-0000000 o. oooooool o, ooooooo I o. ooooooo
stronttun I {21- 552 0.00ooo0o I o.0000000 0.00000001 0.0000000[ o-ooooooo
rhallLum I 190-B6t 0,0017{70 I 0. oo02g0o o. oooooool -o. oo{?zoo I o - ooooooo
rhorLrrsr I d01.910 o-0000000 I o.0000000 o. ooo0o00l 0. oosoz8o I o. o0ooo00
rLn I rse. gBe 0.0000000 I 0.0000000 o. o00ooool o. ooooooo I o. 0ooooo0
tLt,anLum lrra.edl o. oo00o00 I o. o0oo000 o - ooooooof o.0000000 | o. ooo0ooo
Uranium | ,r5 - esB 0.0000000 J o. ooo75oo o. oooooool 0.0000000 f o, ooooooo
vanadLum lzgz . taz 0.0000000 I -0.0009700 0, o00o00ol o. ooo0ooo I 0.0000000
.zinc larr.gsc o. ooo0oo0 I -0.0032900 0,0000000f 0,0000000f o.ooooooo
Comnent,s:
STL Denve
Form XI (PIRT 2l IIN
13 B
STL DENVER
Cont,ract: IIR$ Coroorrution
Total Metals Analvsis
-I18.
ICP INTERELEMENT CO RRECTION FACTORS (ANN UA LLY)
Cage
Date t 7 l23lz$As
Lab Code s g1,frDp{
rcP rD lr\rmbor: SUPERTRACE
sDo No. r D5I100153
rnalyt,e
Wavc-
Lannrth
(nn)Ni
fntcrtrlameat Correctlon ractoru
PI) Sb
for:
8e si
Alnnrlnum 1308.2Lr.0.0000000 J 0.0000000 0.0ooo0o0l 0.00000001 0.o0o0ooo
Antimony I 206.838 0. oo0o000 I o. oo0o00o o-ooooo0ol o-0000000| o-ooooo00
Aruanl-e I t99.0{2 0.0000000 | o-ooooooo o.0000oool o.oooooool o.o0ooooo
BarLum I {93 .409 o.00o0ooo I o. 0000000 0.00000001 o.ooo0000I o.oooo000
Baryrllum ISrr.otz 0.0000000 I o. oo0oooo o. oooooool 0 .0000000 1 0.0000000
Boron I rog. GzB o - 0000000 I o. o0ooooo o. oooooool o. ooooooo I o. ooooooo
Cadmtunr 1225. sO2 0.0000000 I o. ooo0ooo o. oooooool o. ooooooo I o. ooooooo
calclum I 319.933 0.0000000 | o. ooooooo o-oooo00ol 0.00000001 o,ooooo00
ctrromLr:m lz6: .TL6 o. oooooo0 I 0.0000000 o. o0oooool 0,0oo0ooo l 0.0000000
cobalt 1229.615 0.0aa2770 I 0.0000000 o. o0oooool 0.0000000 I o. ooooo00
copper 132 {-zsg o - 0000000 J 0. 0000000 0.00000001 0.0000000J 0.00000001
rron 1rr1.441 0-ooooooo I 0.0000000 o. oooooool o. ooooooo I o. oooooo(
Lead lezo.3 sLtL -o - 0001{oo I o. o0ooooo o.00000001 -0. oooo2o0 I -0 - 0001020
Lcad 1220.3 5Ll2 0. 0000540 1 o, ooooo0o 0.00000001 -0.0001400 I -0.0000370
Magncrlum lZrg- 078 0.0000000 I o. oooo000 o - oooooool o. ooooooo I o. ooooooo
Mansanose lzsz.510 0,0000000 I 0.0000000 o.oooooool o.oo0000oJ 0.0o0oooo
ruolybd.onum I zoe,03o 0.0000000 I o. 0000000 o. oooooool o. ooooooo I o. ooooooo
ulckel 1231.6At12 0.0000000 I 0.0000000 o. oooooool o. ooooooo I o - ooooooo
selenirrm [ 19 6.ALL|L 0.0000000 J 0.0000000 o. ooooo0ol o. ooooooo I o. 0oo1o0o
SelenLun Irg6-0?,Ltz 0.0000000 I 0.0000000 o-oooooool o.oooooooI o-0oooooo
stticon I ze8. lr8 0.0000000 [ o. ooooooo o.oooooool o.oooooool o-ooooooo
6i1wer I 32B.oGB 0.0000000 | 0.0000000 o. ooooooo[ o - ooooooo I o. ooooooo
Strontlum 1421. s52 0.0000000 I 0.0000000 0,0ooooool o-ooo00ooI 0.o0o0ooo
Thallturn I tgo. g6{0.0000000 | 0.0000000 o. oooooool o. ooooooo I o. ooooooo
Thorlus I401.9I.0 0.0000000 I -0.000{200 0.000ooool o. o000ooo I o.00o0ooo
rin |tr9-989 0, oo0o0oo I 0.0000000 o, ooooooof o. ooooooo I o. ooooooo
tl,tanl,um l rrd. eEl 0.0000000 | 0.0000000 o. oooooool o. ooooooo I o. ooooooo
Uranlum lla5.rtB o. oo0o00o I 0.0000000 o. ooooooo I o. ooooooo I o. ooooooo
vanadium I rgz.t1z 0.0000000 I 0.0000000 0. o0oooool 0 - oooo0o0 I 0. o00ooo0
zLnc Izu.85E 0.0000000 | o.0oo0oo0 0.00000001 0.0000000 1 0.0000000/
Fomr XI (Pfnt 2l -IN
Corunents:
STL Denve
STL DENVER
Contract r tIRg Conooration
Total Metals Analvsis
-IIB-
TCP INTERELEMENT CORRECTION FACTOR^S (ANN TIALLY)
Care No-:gfg llo. t
Dat,o: 7 123 12005
r,ab Code: SUTDEN
ICP ID Nrlnbar: 8UPERTRACE
sDG llO- : D5I100153
.Lnallt,e
Wov6*
Iengrttr
(nm)
rrrtorelenrent Corect Lon ractoru
Sr 1FL
for:
T1Sn U
elumluum I308.215 0.0000000 | 0.0000000 0 . 0oo0o00 I o. ooooooo I -o , 0014000
Antl,mony I ,05.838 0.0oooo0o I 0.0000000 o. o0oo0ool o. ooooooo I o. oooooo0
lrgonl"c Irtg-OE2 o. o00oo0o I o. o00ooo0 o. oooooool 0. ooooooo I 0.0000000
BarLum 1693.{09 o.0000000 I o. o00oo00 o. oooooo0l 0.00ooooo I o. oooooo0
nor^ylllum ISff.Od2 0.0000000 | 0.0000000 0.oooooool o,oooooool 0.0000000
Boron lro9.6z8 0. ooooooo I o.00o0oo0 0.00000001 o.0o000ool o.ooooooo
CadrnLurn lz26. s02 0. o0000oo I o. oo0oo00 o. o00ooo0l o.0oo00oo I o. oooooo0
caleLrur Iers.933 0,0000000 I 0. oooo0oo o. oooooool o. ooooooo l 0,0031000
Clrrontum lzit .7 L6 0. o0ooooo I 0. o00oo00 o.0ooo000l 0.00000001 0.oool1oo
cobalt 1228.516 0.0000000 I 0.0000000 o. oo2{{ool o. oooo0o0 I 0. oooog6o
. coDrrcr I rzc . r5t\o. ooo0000 I o.00ooo0o o.0000000J o.oooooool 0.0005300
fron lrr 1. {{1 0 . ooo0000 I o. o00oooo 0.00000001 0.0000000 I -0,002{000
Lead lr^0 .351/ 1 0.0000000 | o. o0ooooo o. oooooool o. ooooo0o J o - o010o5o
nead lzzo.3 sttz 0. o0ooo0o I 0,0000000 0.00000001 o. oooo000 | o. 0011600
MagnarLun lz7 9.078 0.0000000 I 0.0000000 0.00000001 0.0000000 I -0.011{000
Manganese lzsl.610 o. ooo0o0o I 0.0000000 o. o00oo00l o, ooooooo l o. oool3oo
Molybdenum I,02. 030 0.0000000 [ o.00o0oo0 0.00000001 0.0000000 I -0.0002100
lul,ckal l231.6ottz 0.0000000 | o. ooooooo 0.00000001 -0.00094001 0.0000000
SelenLum I tg6. ozLtL 0 .0000000 I o. o0oo0o0 o-oooooool o.oooooooI o.ooooEoo
Solenirrn 1196-OZLtz 0.0000000 | o.000ooo0 o-oooooool o.oooooool o.o000ooo
stlLcon lZeB. rss 0.03125001 o-ooooo0o o - oo88ooof o. 0000000 I o. ooo8{00
silver I 328. 06g 0.0000000 I 0.0000000 0.00000001 o. oooooo0 I 0. ooo93oo
strontLrrn lCel. S52 0,0000000 I o, ooooooo 0. o0oo000l o - 0000000 I o. ooooooo
rhalllum l 190.86d o-ooooooo I 0.0000000 0.00000001 0. o0o0ooo I 0. 0000000
Tlroriun I401.910 0.0000000 I 0.0000000 o. oooooool o. ooooooo I o. oo233oo
rtn I ra9.9a9 o. ooooooo I o. ooooooo o. oooooool o. ooooooo l o, ooooooo
rltanlusr lrr{.9{1 0. 00oo0oo
I
0. 0000000 o. ooooooof 0.0000000 I 0.0003000
uranl,uur lsas.sse 0.0000000 I 0.0000000 o, oooooool o. ooooooo I o. ooooooo
var:adl"um I,rZ.l}z 0.0000000 I 0.0000000 0.00062001 0.0000000 I -0.0000600
zLnc 12L3.956 0.0000000 I o. ooooooo o. oooooool o. ooo0000 I 0.0000000
Conrments:
STL Denve
Folmr XI (PART 2l .IN
140
STL DEIVVER
Total Metals Analvsis
-118-
ICP INTERELEMENT CORRECTION FACTOR,S (ANNUALLY)
Contracts IrRS eorDoration
Lab Coder SI1rLDEN Case [Io. t g^Ig No-:
rcP ID tftrrnber I SUPERI:RACE Datet 7 l23lzA$s
sDG No.: D5I100153
wavo-
langrEh
(nm)
Irrterolannsnt Correotlon ractorg
7.n TIr
for:
Analytc v
AlunLnun 1r08.215 0. 0316700 I o. oo0o000 o . 05061oo I
Ant,l-norey I 205.838 0.0000000 I 0-ooo0ooo o . ooooooo I
nrgenl,c l18g-04a 0.0000000 I o-0000000 o . ooooooo I
Bariun J{93.1109 o.0ooooo0 I 0.0000000 o . ooooooo I
Barrrlligm Iaff.0{2 o. oo01g00 I o, oooo000 o . ooooooo I
Boron lrog.578 0 - 0000000 ! o. ooo0ooo o . 0000200 I
cadmlum 1226. soa 0.0000000 I o-0000000 o. ooooooo I
calclun I 319.933 o.0000000 | o-o0ooooo -o - oal77 00 I
ChromLum 1267 .7L6 0.0ooo00o I o.0o00oo0 o. ooooooo I
Cobalt, 1228.515 o. oo00o00 I 0,0000000 o . ooooooo I
cogDer I 32 4.'ts3 0.0000000 | 0.0000000 o. oo?15ool I 1rron lrr1. d41 -0. 5347500 f 0,0000000 o. oo{57501 I I
Lcad 1220 .3 'tl t 0.0000000 I 0.000oooo -o. oo3 5600l
Lcad Jzzo.3sLla -0. 0003200 | o.0000000 o . ooooooo I
Magnarl,run l=r9-0Zg o. o0000oo I o. oooo0oo o. ooooooof
Mangranese lzsz - Glo o.0oo0oo0 I o.0000000 o . ooooooo I
Molybdcnlra I ,02 - 03 O o. oo0o0oo I o.00ooooo o . oooo00o I
nLcket I ,r 1. 5 at t2 o.0ooo000 J o. o0ooo00 o . ooooooo I
Selenlum I 196,0ZLlL 0.0002100 J o-o0ooooo -0. o2'I930ol
Beleattzn 119G.02Lt2 0.0000000 I o-oo0oo00 -0. oo024o0 I
gtlLcon
I 289.158 0.0000000 I 0.0000000 o . o0o070o I
gLlver l gZE,058 0 - 0000000 I o. o000o0o o, o0o349ol
st,rontLrrm I {21. 552 0.0000000 I o. ooooooo o.oooo0ool
Thall-ium I fgO-86{0.0011700 I 0-0000000 -o . ooorzoo I
rlhorium I oO1.9lO 0.0002000 I 0.0000000 o. ooooooo I
Tin I rr9.989 0.0000000 I 0. oo0oooo -o . ooo33oo I
rLtaniurn I ,r{.901 0.0000000 | o.0oo0ooo o. ooooooo I
uranJ.um I
ge5.95B -o. o0g0?00 I o. ooooooo 0 . 001?000 I
vanadlun lzlz.tli 0.0000000 I 0.0000000 o. oooEgoo Iztnc Izrr.BsG 0.0000000 I o. oooo0o0 o,oooog3ol
Form XI (PART 2l rN
Coruuentg:
STL Denve
STL DENVER
O
Con
Lab
ICP
g1rLDETI Cage No,:
ID Ntunbcr t Tr:n Intrcpid rcP
Total Metals Analvsis
-12-
tcP LINEAR RANGES (QUAR'I]ERtY)
gl,A No.3
Datcr 8 1L512005
gDo tr[o- : D5I100153
traoE r
Codc:
IIRS Cor:porat,l,on
.Inalytc
Irrtsrg -
Tlnc
(Scc, )
Conccntrrtl,on
(ug/r,)
M
[.Llumtnun Lo I 60 .00 IrI
lAluninum Hi I 20.00 1000 fn
ICal.cirrn I,o 20.00 50 Ir
IealcLun IIi 20.00 2000 lp
[Iron Io 20.00 Ip
f lron Ht 20.00 2000 fp
f Potassr.um 20.00 500 fr
Ilhgr"egl-um 20.00 2000 In
J Sodtum Lo 20.00 10 Ir
lSodium IIi 20.00 10000
50
Ir
,ruuent a :
STL Denver f,onu XII IN a42
STL DENVER
Contracts:
LaL Codct
IIRS CorporatJ.on
STI,DEDI Cuc fVo. t
Total Metals Analvsis
-12-
ICP LINEAR RANGES (QUARTERI,Y}
gf,g Ho. r
Date= 7 l22l2i0s
sDs No. r D5I100153
ICP ID l[umbcr r gUPERTRACE
Analytc
Integ-
rine
(8cc. )
Conoentratlon
(ms llrl
M
I nraanio 15-00 20 Ir
I aerium 15.00 25 In
f Chromlun 15. O0 50 Ir
I Copper 15 .00 50 lr
f Laad.15.00 100 Ir
l Nickal 15.00 50 fr
l sflver 15.00 lr
lVanadLrrur 15.00 50 Ie
Iztnc 15.00 50 Ir
Copment,B I
STL Denver Forra XII IN 1_43
STL DENVER
o
Con
IJaI,
ICP
tract: IIRS Corporation
Total Metals Analvsis
-tL
ICP LINEAR RANGES (OUARTERLY)
DaEcr 8 l1.glz005l
Code: STLDEN
ID Nuubrrt pE fq5lgg
SDO NO. : D5I100153
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Concsntratlon
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STL Denver Fom XIf - IN 744
STL DENYER
Total Metals Analvsis
,13-
PREPARATION LOG
Contsract s
r,lrb Code:
Mcthods P
t Rg CorDoratlon
STITDEIT Cltc No- I gl^8 No.:gDO NO. : D5f1O0153
Prcp Motshod:
SamD].o ID Prcprrlt:Lon Date
rnLtLa.l. volume I rinal
I volugtc (nL)
e$r-N91- o 9 0go5 9 l zs lz00s 50-o I 50.0
cI[lI-IitI.-Og0g05 9 t33t2005 50. o I 50.0
Gilr-N1-090905 Ms 9 t23t?005 50. o I s0.0
GU[-N1-090905 MgD e 12312005 50.0 I 50.0
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IIIB5Z65222 91231?00s 50. o I so.o
CIIECK SAtrIPT,E 9 lzs /200 5 50. o I 50.0
Commentg r
STL Denver
Form XIIT IN
STL DENVER
Total Metals Analvsis
t3-
PREPARATIONLOG
Contsract:
f,a,b Codc r
Mothod r
t RS Corporet{on
STIJDEN Case ![o. :SIS ![o. :sDc No.: D5f100153
Prop Mrthodr
Sauplo ID Preparatiorr Datc
rnitLal Voluna I rinal
I vohmc (nf,,)
cru-Ng1- 090905 9 t261200s 10. o I 10.0
Gr$r-NI-Og0g05 9 1261200s 10.0 I 10.0
G[il-N1-OgOg05 Ug 912612005 10.0 I 10.0
cyr-N1-090905 usD 9t261200s 10.0 I r0,0
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GUr-5D- O90905 9 126 /200s 10.0 I 10 ,0
Gvr-g6- 0909 0s 9 /26t2005 10.0 I r0,0
GAf-7 C-.0 9 0905 9 126120 0 s 10.0 I 10.0
uB52 5633 6 91261200s 10. o I 10.0
CHECK SAMPLE 9 /26/2005 10. o I 10.0
Coruracnts:
STL Denver
Dom XIII T IN
745
STL DENVER
Total Metals Analvsis
,13-
PREPARATION LOG
Cont,rer:t' r
Lab Coder
Mcthod:
t RS Corryrorati-on
STLDEN caac No- r SAg ![o. r
lfs Prep Mcthod.r
Earqp]-a ID Preparatsion Dat,e
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cw-NI-- 090905 9t23/2AO5 50.0 I s0.0
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GII,II-N1-0909O5 MSD 91231200s 50. o I 50.0
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GTr-7C- O9 090s 9 t23t2005 50.0 I 50, 0
M85255180 912312005 50.0 I 50-0
CHECK SETIPLE 9la3 /200s 50. o I s0.0
Dsr100153
1-47
Comncntt r
STL Denver
Fom XfIf IN
STL DEIYVER
Total M-llls Analvsis
ANAI,YSIS RTIN LOGO
Coutractr r
Lab Codc r
Ingbnrnmt,
Start Drtcr
URS Corporatl,on
STI,DEN
fD !fipobcr r
9 12612005
Caae No. t
T,.IL Intraptd ICP
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Method:
sIrc No. r D5I100153
End Date: 9 126 lzOOs
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ICSA 1. OO 1O929 x x x x x x
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Forn XIV * IN
a48
STL DENVER
Total *"11f Analvsis
ANALYSIS RUN LOG
Contnct r
Irab Codc:
Inatntrmont
Strart Detcr
IIRS Corryloration
gTLDEN
ID lllunbor r
91261200s
Crac N<l. t
TifA lutreptd ICP
gAS No. t
Mcthod:
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P
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End Datar 9 126l20As
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Forxr X]]lr - IN
1-49
STL DENYER
Total Metals Analvsis
-14-
ANALYSISRUNLOG
outsnctt IIRS Corporat:Lon
Lab Code3 STITDEN Caae Dlo. t Sng No. :
rDrerrrnont ID tlumbcrr 8t[ fntreptd ICF Mothodr P
sDG No. s D5I10O153
Startr Drt'e I 9 /26 l?OAs Brrd Datcr 9l26l2OA5
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STL Denver Form XIV IN 150
STL DEIYVER
Total Metals Analvsis
-14-
ANALYSE RUN LOG
Contsraet:
Lrb Codcr
Ingtnrrncnt
Start Datsc:
URg Corporatsion
STLDE}I
ID lfl\rmbcr r
el25l200s
Caac No. t
T;IA Intrcpid IcP
SAS No. t
Matrhodr P
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STL Denver Form XMN 151
STL DENVER
Total Metal: Aoolvsis
ANALYS$ RTIN I,OG
Contrect r
frab Code :
InaErrunant
strart Drtor
gTLDE![
fD !firnbcrr
9 127 12005
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Fom XIV IN
152
STL DENYER
Total Metals Arrtlvsis
nnnriToRrrNLoc
Contraot r
Lab Codcs
Inrt,rnrnont
Sltart Datso:
URS CorporatLon
STI,DEN
ID N\:nbrr r
e /27 t2005
Cr;c No. I
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STL Denver Fom XfV IN 153
STL DENVER
Total M"1ils Analvsis
AI.{ALYSN RUN LOGo
Corrtsrrct r
Lrb Codcr
Inatrnrnont
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IIRS CorporatI.on
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ttran thc
Fonu, XMN
154
STL DENVER
Total M-:ils Analvsis
AI\ALYSIS RT]N LOG
Contraots r
Lr-b Cod,a;
Intt,rumant,
Starts Drtscr
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ID Mrnbcrr
91?61200s
Ca;c No. t
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155
STL DBIVVER
o
Contracts:
IraI, Codc:
Inatrrrment
Start Data:
Total M.:if Analvsis
ANALYSIS RTIN LOG
IIR$ Coranratl-on
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STL Denver
Form XIV - LN
155
STL DEIVVER
Total M.:ils Analvsis
ANALYSIS RUN LOG
Contsraet r
Lab Cod.e:
Inetrnrmcnt
St,art, Datrr :
t RS Cor:poratLon
STLDE}I
ID Dltuubcr:
91261200s
Cagc No. t
PE STI}.[,
glg No. l
ucthodt
sDc No.: D5I100153
C-tt
. Druoteg acldltlonal rleueata
STL Denver
hd Drtc r 9 126 l2AO5
(othrr than bha str.aderd CLp eleurntr) arG r.Dr.rantrd on rnother Doro 1a
SrnpLc
ID.
DIY fl-na tbR
.f,nrlyt,rr
A
L
s
B
.B
g
B
t.
B
vtIL
c
D
ct C
n
c
o ;lrl:l xlrl ffil II'I;I;
M85466336 1. 00 18:55 x
CHESK SNIIPLT 1- 00 18:56 x
cc\r11 1.00 18:58 x
ccB11 1. 00 19: OO x
qr-Ng1-090905 1. 00 19:O1 x
crril-N1-- 090905 1. O0 19: O3 x
G1[-Nr--090905 lIs 1. O0 19r05 x
GTr-N1-O90905 MgD 1- O0 L9: O5 x
Grw- 5s- 0909 05 1. 00 19: OB x
cw-5D-o9090s 1. O0 19r1O x
qil-86-0909O5 1- O0 19:12 x
our-7c- 09 09 05 1- OO 19r13 x
7,7,Z7,ZZ 1. OO 19r15
z?.27.27,1- O0 19:16
cgtr12 1. o0 19r18 x
CCB12 1- 00 19 :2O x
Forn XrlI - IN
1,57
STL DENVER
O
conBract s
Lab Co6or
In;t:rrmcnt,
Start Datcr
Total M-:ils A,nalvsis
ANALYSIS RUN LOG
IIRS Corporatlon
gTLDEN
fD Nurubrr r
9126/200s
Crrc No. I
PE IEPMS
S.LS No. r
Mcthodr
End Darcr 9 lzt /2045
sDc No.: D5I100153
M
Analytca
sagp]-c I atv lrinc I e6 R
0c sEd 3
QC srd 4
9tradrrd. 1
ac ard 3
QC gtd ,l
Qc strd 3
QC stsd I
QC sbd 3
ac std 4
Stendard 1
Qc strd 3
I'I852 5518O
t - Dalota. rtldltlonal .l@Ets (othar tUlE Eho stEderal Cl,P aloaata) lro rsDr.aesEoil oB rrctlcE fo!! 1a
STL Denver
E'om XfV IN
158
STL DENYER
Total *.11f Analvsis
ATIALYSIS RUN LOG
Contract:
Lrb Code:
Instnr.merrt,
9tart, Dater
IIRS CorT>oratLon
STr,f)EN
ID lltrmber:
912612005
Carc No. t
PT ICPMS
EAS IiIo. t
Mtrthod.:
SDG No.: D5I100153
u
* Dauotes addltlonal elcmcntt
STL Denver
Eud Darcr 9 127 12005
(other thaa thc EtEndard CLP elcreuts) are rcprcocnBcd on aaothcr Form 1{
saqrrle
rD-
Dlt lfine erR
.f,naI'ytcr
t
L
g
B
t'
g
B
L
B
E
c
D
c
.t'
c
R ;I;II plu
"l .M
N
II
o
N
I
K g
E
Jt
G
N
,\
T
TJ
v z
N
c
N
7r7rT.ZZ7,5. O0 0{:07
27.227.7.100. oo O{r11
T'TrZZZZ 1. OO Olr15
@r-Ng1-0gog05 5-oO O{r18 Jx l l l n I x
cw-N1-oeog05 5-OO O&t72 x x
QC Stsd 3 1- OO O4:25 xl x
QC Std {1.00 O4 ;29 xl x
GV[-t{1-090905 sER 5. 00 Olr33 l*l x
ew-N1-090905 PDs 1- OO Olt36 x x
cDy-N1-O90905 Us 5. O0 04r4O x x
Grr-N1-090905 tdsrD 5-OO O{r44 x x
cr[-58- o90905 10-oo Alt&7 xl x
crg-5D-090905 20. o0 O{:51 x x
cw-s6- 090905 20. oo O{r55 x x
GTr-?e- 090905 1. OO O{r58 x x
ac srd. 3 1, O0 05rO2 x x
ac sEdL d 1.00 05;06 x x
Forn XIV - rN
159
HITIIOD BfilITK REPORT
General. Chemt-stry
Cl-ient Ipt
PARAT{ETER
D5I1-O O 1-5 3
RESUITT
#- - - :Itatrtr, . - - - - - - . ! WATER
Arrunonia aEl N
Ammonla as N
Ch].oridl=
F1uoride
Nit,rate
NI-trate
Nl-trate-Nitrl-te
Nl-trare-NiErite
Sulfat'e
Itlork Order #: HLJ851AA
O. LO mg/T,
Dilution Faet,or: 1
Analyeie Timc - - : 22..AA
Work Order #: Hrc(s8LAA
2-5 ryll,
Dl"lut.Lon Factor: L
Arralygie Time, . : 17 : 00
Work Order #: HICITKT1AA
O - aO rglt'
Dllution Factor: 1
lnalyals Tl-me. - ; 1-3 :15
Work Order #: HK7Ir71AA
O. LO mg/f-,
DLlution Factor: 1
Analyels Tl,me. . : 1,5 : 0O
Work Order #: HIIIrMP1A.,H,
0 ,10 mg/L
Dllutlon Factor: L
AnalysLe TLme. -: 15:O0
$Iork Order *: HKTIIE1AA
0. l-o mg/t
Dllutlon E'aetor: 1
A:talysle Tlme. . ; 22; O0
Work Order #, HIrIrDglAjA
0.10 mg/T*
Dilutiou Factor; 1
Analyel-s Tlme. . : 18 : 0O
Itlork Order #: HLIYIHK1AA
5,0 rylt,
Dilutlon Faetor: 1
Analysls Tlme..: 15:40
(Continued on next
MB Lot-$ample
MCAWW 350 .1
MB lpt-Samp1e
I'ICAIItr 325 -2
IvIB Lot-Sample
I'iCAilI5 3{O - 2
MB Lot-Samp1e
MCAnm 353.2
MB Lot, - Sarnple
MCA9gW 353 .2
MB Lot-Samp1e
MCAITffi 353 .2
MB Lot-Sample
MCAhrlr 353 .2
MB Lot,-Sample
uetmf 375 -1
REPORTING
IrfMfT UNfTS }IlETHOD
Work Order #: HK6XALAA MB LoE-SampIe
ND 0.10 lI,figlt MCAWI{ 350. L
Dilution Faetor: 1
enalysl-g Tj-me. , : O4 :0O
PREPARATTON- PREP
ArvALYg_rS pATE BATCII #
DsI22A000 -47fJ
oe /Ztl as 526s478
DsT280000- 454
oe /2t / as s2714s4
D51200000- 262
os lLBl as s263262
Dsrl.{0 000 - 578
oel1llos s2s1s7B
D5I220000-s87
oe /ta/os 526ss87
Ds1280000-7a7
a9 / 1A / A5 52'tL7 07
Ds1220000-552
ae / 2a / os s26sss2
Dsr280000 -679
oe /27 / os s2?]-67e
D5r290000-L73
as lzslos szrzl:ls
I..8 B
o-or_9 B
ND
STL Denver
2.5 B
page)
150
IIIEIEOD BI,aIIK REFiORT
Gerrera.I, Clrcmlstry
Cl-ientr tot *- - -:
PARAMETER
Dsr1001s3
RESUI,T
R^EPORTING
I,fldIT UNfTS METTIOD
Ilatrl-x-- D-.. --.: WATER
PREPAR;ATTON- PREP
AI{ATYSIS DATE BATCII *
Total CYanide Irlork Order * ; HK3 6E'LAA
o - o10 mg/T,
Dilution Factor: 1
AnalyaJ-e Time. . : 12 : 00
MB Lot-Sample #:
sw845 901O8/ eO12A
D5T210000 - s3 9
oe / zt-09 I 22/ os sz54s39
IUTB(S):
Cslculadono aro performcd before rouodirg to avoid roundotf ernors In calcutued rcsults,
B Etimatod resu[ Re,$lt lc les than RL.
STL Denver 151
ffi COITIROL SIATIPT,E EIIALTIATION
General Chemietry
RBPORT
Iot-Baqrl.e *-
PARAMEqER
pH
Anunonia aB N
ArnmonLa aB N
Chloride
Fluorlde
: D5f10O1-53
PERCENT RECOVERY
RECO\IERY LIMITS
RPD
RPD LTMITS },IETHOD
wo# : HICEQJIAA-LCS/HIGQJIAC-LCSD LCS
(gt Laz) sw84 5 904 oB
(9t L02) 0.0 (o-5.0) swg+e 90408
(go 1-L0) t'lcArilv{ 350,1(90 L10) 0.34 (O-1,0) MCAI{W 350,1-
WO# : }IK7HB 1AC - T'Cg / HK?HE ].AD - I,CSD
(gz LLz) t'lcAww 3 53 . 2
l9Z L1.2) 0.10 (o-10) MCAIIW 353 .2
Dllutlon PacEor: 1
llatrix- - -- - -- - -3 WATER
PREP,ARATION- PREP
ANALYq.r..S pArE BATCH .f.
LoE- Sample# : D5I1OOO00 - 1-O1-
oe / Lo / os s2s3 101
ae / lolos s2s3 L01
ae/zt /os sz7L4s4
ae /27 / as s27L4s4
LCS Lot, - Sample# : D5I,220 0o0 - 5 52
oe/za / as s25sss2
oe /za / as szasss2
100
L00
1_OO
100
101
101
L06
1_0 5
DLlutl-on Factor: 1
vlo# : HKSXATnC-I,CS/HX5XA1AD-ITCSD IJCS l.ot - Samtrlle* : D5I22 OOOO - 4 78
(9o - 1Lo) Meeww 3so.1 og/zt/os s26s47g
(9o - r1o) o.77 (0-10) Mcaww 3s0.1 og/zt/os s26s47s
Dilution Factor: 1 nnalyeie ?imc, . : O4: OO
WO* :HhT85faC-f,CS/ULifS5IAD-LeSD LCS IJot- Sanqrle# : D5I2IoOOO -454
Dlluti-on Factor: 1
I{O# : HKX58 faC-f,cs /HKx58 IAD-IICSD I,CS r,ot, - Samtrlle* : D5 f2 0OoOo - 2 52
99 (90 - 110) rrrcAww 32s-2 ag/te/as 5263262
9e (90 - 110) O-3{ (O-1O} MCAWW 32s.2 OgltslOS 5263262
Dilutloa Factor: L Analyal.e Tlme. . ; 17 ; 00
WO* : HKJKT1IC-ICS/XKLK?LAD-ITCSD IJCS Lot - Sampte* : D5f 14 oOOO - 578
(82 - 114) McAnw 3{0.2 ag/t+/os s2s757g
(ez - 114) 0.0 (0-1G) MeAww 3{0.2 ogltalos szs?s7g
Nitrate
Nitrate
94
97
Nit,rate-Nitrite
96
96
DllutLoa Factor: 1 Analyel-e Tl-me- . r L3 : 15
910# : HK7L7rAc-I,cS/HKTIrTLAD-LCSD LCS Lot -Sarqrl-ef : D5I22000O - 5879+ (s6 - 110) McAr{w 3s3.2 og/to/os s26sss7
91 (s6 - 11o) 2.e (o-10) McAww 3s3.2 og/tolas s26ssgz
Dilution Factor: 1 Analyeie Time..: 15:00
wo# :IILLilPTaC-I,CS/XLLMPLAD-IJCSD LeS Lot-Sample* : D5I2I00OO-7 07
(BG - 1r.o) MeAww tss.z ogltolos sz7l7o7
(86 - 110) 2.e (o-10) Mcalrw tst.z og/to/os sz7l7o7
Dilution Factor; t
STL Denver
(Cont,inued on next page)
a62
Iot-Sarylle *- - - : D5I100153
PERCENT
PIIUUVIETER RECO\IERY
Nitrate-NlErlte
99
99
Sulfate
110
109
Total Cyanide
1_07
108
ffi COITTROI, AAIIPTJB EIruTIATION RBBORT
General. Cheutstf,y
RECO\IERY RPD
IrfMI?S RPD IJII.,IITS METHOD
lfatri-x.' . - . - - - - . 3 WATER
PREPARATTON- PREP
ATiIAIJYSIS DATE BATCH #
Lot-Sample# : D5T28OO0 A-679
oe/22 /as s27l67e
oe/27 / as s27L579
wo# 3 HrJJrgilA,c-LCs/urr,nglAD-LCSD LCS
(gz tL?) lqcarYw 353.2
(92 L1,2) 0.15 (0-10) MCAWW 353 - 2
Pl.lutLon Factror: 1
Wo# : HII|HK1AC-LCS/HIMITLAD- rrcsD Ircs r,ot - sanple* : D5I290o 0 0 - 173
(91 - 112) MCAI{!{ 37s.4 og/ze/as sz72l73
(el - 112) 0.63 {o-ls) McAww i7s.4 og/ze/as 5272L73
nl-IuLLon Faetor: 1 Analyele TLme..: 15:10
vIo* : HK36PreC-r,CS/rXl6F1AD-rJCgD LCS Lot, -Sa4>La* ; D5I21O00o - 539
(s9 - 109) sn846 goros/gorzz. oglzr-oel22/os 5264s3e
(Be - 109) 0.93 (o-20) gws46 9o1oB/eo12 09/2t-og/zz/as sz6ts39
DllutloB Faceor. 1 .llalyela Tlne--: 12:oo
IICITB (S) :
Calculadons are performod bcforo rourdlng to evoid rourd-off erron in celculatcd resrdts.
STL Denver 1_53
W @IIIROIT gAltIPIrE Dilf,B' RffiORT
Geueral. CheoiBtry
Iot-'Bary>Ie *- - - : D5f1OO1-53
PARAII{ETER
SPTI(E MEASIURED PERCMT
AI.{OI]MT AIvTOIINT UNITS REC'\IRY RPD MEfiIOD
Hatrl,:r--- ---! WATER
PREPARATION- PREP
A}UALYSIS DATE. BATCH #
pH wo# : HlcEQirree- rrcs/gxEQirlAc-rrcsD r,cg Irot-sarple* : D5I1 oo0 o 0 - 1o1
7,00 7. 01
7.00 7.01
sw846 90408
Pl,IucLon E'actor: 1
wo# 3 HK6XATAC-I,CS/HK5XA1AD-r,CSD LCS r,ot- gaqrle# : D5I22000 O - 478
No UnLte 1o0
No Units 1-00 0 . 0 sw845 90408
ae/Lo/05
oel 1.0/ os
oe / 2t/ as
ae / 2t/ as
oe/27/as
ag /27 I as
oe/L8/os
oe / 18l os
oe/L4/os
oe / ].4/ as
oe/aolos
ae / 1olos
oe/20/as
oe/zo/os
5253 101
5253 101
5265478
5265478
s27L454
527L454
5253252
s263262
5257578
s257578
527L7 A7
527l.7 07
5265552
525s5s2
Ammonia ag N
Ammonia as N
Ctrloride
Fluorl-de
Nitrate
Nltrate
4.OO
4.00
4.00
4.00
50. o
50.0
3 .98
4.O1,
4.03
4 .44
49 .7
49 .6
mg/r'
mg/r,
mg/r,
mg/L
mg/T'
mg/L
uq /t'
nrg/r,
Dllutlon Factor: L AunlyeLe
wo# : IIrJS 5 1AC-r.CS/Hr^TS5LAD- LCSD LCS Lot - Sample# : Dsr28 OO 0 0 -4 54
100 MCAWW
100 0.77 MCAWW
101 MCAWW
L01 0.34 MCAWW
99 MCAVWiI
99 O .34 I'ICAfiniI
AnalyeLe
350.1
350-1
Elme. . : 0*:00
350.1
350.1
Tlme..: 22:OODl}utlon Factor: 1 Analyels
Wo* : HBx(58 fec-rfs/gxxsI1AD-r,csD IJCS Lot- Saq>le* : D5I2 00000 -262
325 -2
325.2
TLme. . : L7:00DiluELon F'actor: 1
wo# : Hl(tfi? LAC-ICS/HKIJKTLAD-LCSD IrCS Irot - Sample# : D5I 14 0O0O - 578
5.00 5,2g
5. OO 5.29
0.0500 0.0 469 mg/f,
0.0500 0.0483 mg/T'
0.0500 0.0 469 nrg/f
O. O50O O - 0483 mg/f.
mg/r,
mg/T,
MCAWW 340 .2
o. o McAww 340 .2
Analyele fLme..: 13:L5
94 MCAWW
97 2,9 MCAWW
Analyel.a
94 IT{CAT{Ifl 353 .2
353 .2
Tl-rne..: 15:00
97 2 .9 MCAhIIil
353.2
353,2
Time..; 15:oo
MCAWW 353 -2
0. 10 MCAWW 353 .2
Aaalyeie Tinc..: 22:OO
ae/tolos s26ss87
oe/Lo/as 5265587
L05
r,06
Pl,lutl-on Factor: 1
wo# : HKTL?1AC-LCS/HKTIJTLAD-ITCSD IJCS IoE-Sample* : D5I2200O O - 587
DilutLon Factor: L
wo# :Hlr,MPrac-rcs/uLum1aD-LcsD IJcs Lot-sample* : D5r2g0o00-707
Dllution Factor; 1 nnalysls
wo* :HKTHEraC-IrCS/BKTIIELAD-ITCSD IlcS Ilot-Saryrle# : D5I220OO0-552Nlurate-NLtrlte
4 .00 3 .95
4 ,00 3 .95
DL1utl-on Factor: 1
95
96
STL Denver
(Continued on next page)
L64
ffi COIIIROIT geHPIrB DATA REPIORT
Geur:ral Chemistr1r
Iot-Saupl-e *-. - : Dsf 1001-53 I.iatri:c-. - - - ]-. - ! TiIATER
PREPARJATTON- PREP
ANAI,YSTS DATE BATCH #
SPTKE MEAST,RED PERCNT
PARAMETER AI{OUMT A}TOT}NT T]NITS RESVRY RPD },IETHOD
wo# : HI-rI-rDg1AC-LCS/HLLDg1AD-LCSD IJeg Lot-Sarytle# : D5T28oOo A-679Nitrate-NLtrite
4. OO
4.00
25. O
25-0
0.100
0.100
3.96
3.95
o.107
0.L0B
oe /27 / as
ae /2t / os
527L679
s27 L67 9
s272L73
s272L73
rng lT,
vtr,/t
Dilution Faetor: 1
nq /t'
mg/T'
99
99
LA7
1-O B
MCAVSW 353.2
0.15 MCAWW 353 .2
Analysle Tlme..: 18:OO
Sulfate
Total Cyanide
wo# : Irr-rMHKlAc- Lcs/HL[vrHKlAD- LCSD LeS
27 -4 trg,/T-, 11-0 MCAI{If 3 75 .4
2'l .2 $q/T, 1-09 o-53 MCAI{I{ 325.4
DllutLon Factorr L nrralyeie Time- -
Lot- Samp1e* : D5I29O000-1-73
oe /2e / os
ae /28 / os
: 15:4O
sw845 e01 oB/eoL2A oe / zL-ae / 22/ as 5264s3e
o . 93 SW846 e01AB/ e01-2A Ae / 2L-09 /221Os s26453 9
Dilution Fector: 1 Analyela flme. . : 12:OO
wo# : HK3 6FrAC-I,CS/HXS 6F1AD-IJCSD LCS Lot- Sample* : D5I21OO0O- 539
IWIts(S):
C-alcrrlations arc perforrned before rourding to avoid round-off orrorB in cehulrted reeirlts.
STL Denver 155
TATRIT SPIffi SAUPIfi ffi RB}ORT
Genera-L Chcni8try
Cl,.eut tot I---: D5r10o153
rlate sary'ted.-- ? 09107/O5 09:55 rlate Recetved. -. og/og/os
PERCENT RECO\IERY
RECO\IERY IJTMTTS
RPD
PARJAIVTETER RPD IJIMITS METHOD
llatrLx- - - -, -, - - : WATER
PREPARATION-
AIVALYSIS DATE
PREP
BATerI. #
Amrnonia aa N
Chlorlde
Fluorlde
rucfE (s) :
Nitrate-Nitrite
92
90
Nitrate-Nltrlte
92
88
Total Cyanide
wo#:
13 0)
130) 0.2L (0-30)
Dllutlon E'actor: 1
ArralyeLa Time - . : 22:OO
wo*:
110 )
1r.o) 0.33 (o-10)
nLlut,lon Factor: 1
Aaalyaie Time. . : 17: O0
wo#:
LO7 )
LO7) O.4L (O-10)
Pl.Iutlon Factor: L
Analyel-e Tlme- - : 13 : 15
$ro#:
119 )
Llel 2.L (O-30)
D1lutlon Factor: 1
analyele TLme..: 22:OO
wo#:
11e )
1_1gl 2.L (0-30)
DLlutlon Factor; L
Ana1-yele Tl-rne, . : l-8 : O0
wo#:
10e )
1-09) 1.9 (O-2Al
DLlution Facbor: 1
Analysl-e Time. - : 12 : 00
94
95
114 N
lls N
1-0 6
105
57N
55N
(44
(4+
(go
(go
(82
(8t
(ez
(ez
HKE3 01e8 -MS/rUCn:01C9 -MSD MS
MCAWW 325.2
MCAT{W 325 .2
HKT\ID7,C7 -MS/HKr\rDLC8 -MSD Mg
MCAWW 350, L
MCAWW 350.1
I,oE,-Sarry>Ie # : D5I170L91--OO1
09/z7 Ias s27r-4s4
09/ 27 / Os s271454
Lot-Sample # : D5I130198-004
os /LB / as s263z5z
a9/ LBlos 5263 z;z
Lot-Sample # : D5f09O153-0O1
oe/L4/os s2s7s78
a9/L4/ as szsTsTs
I,ot-Sample # : D5IO7 027 O*0O2
oe /2o / os 526sss2
oe/za / os s26sss2
Iot-Sample #: Dsf 080243 - 0O4
oe/27 / 0s s27l67e
ae/27 / os s27l6rg
HJ8GV1m-MS/HJSGrrlDR-MSD MS
MCAWW 340.2
MeAWTg 340 .2
Hir3 5N1CE -MS /Htt6N1CF-Ir{SlD }rfl
McAWw 353.2
MCAIrnt 353 .2
(62
$z
HJsJMLCT -MS/HJ5JlrLe8 -MsD MS
MeArgrI 353 .2
MCAefW 353 -2
(sg
(sg
HKE3 OIDH-MS/HKE3 01DJ-I{SD },rS Lot- garnp}e # : D5I13 0198 - 004
sw846 eo]- oB/eo12A 09 /21-O e / 22/ AS s26453e
sw846 90108 /gO12A a9/2L-oe/22/aS 5264s3e
Calculatlons ero pcrforrncd beforc rounding to svoid round-off crrors in caloilated regults-
N Spil(ed mntytc rccovcry is ourside stated control limits.
STL Denver 1,6 5
INMIf, SPIX(B IIAUPIA uATE REPORI
Gcneral- Chcmiatry
Client Iot #- - -: D5I100153
Date 8aryrl.ed--. z o9/o7/os o9:55 Date ttecetrred- -. a9/08/05
SAMPIJE SPTKE
AMOT]NT A}IT
llatrl,x- -- -. - ---! IIIATER
PAB+LrFrER
Anurronia aa
MEASRD PERCITT
AD,IOtnlT UNITS REC\m'Y RPD METHOD
WO#: HKTVDTCZ-t'lS/UrrVnlCg-MftD MS Lc't-Sample #: D5I1ZO191-001
3.79 mg/l'
3 . B0 rfig/L
11200 N mg/t
1-1300 N mg/L
5,83 mg/t
5 - Bo n:q/T,
MCAT{II 350.1
o .2L MCAWTf, 350. L
PREPARATION- PREP
AI\TAIJYSIS DATE BATCH #
oe/27 / 0s s27]-cs4
oe / 27 / as s27:.cs4
N
0.020 4.00
0.o20 4.oo
s000
5000
5-00
5. O0
4.00
4 .00
400
400
94
95
DilutioE FacEor: 1
AnaLyri8 Ttme..: 22zOO
wo*: HKE301C8-MS/HKE3O1C9-MgD MSt lrot-Ssmple #: D5I1301s8-0o4Chloride
5 500
ss00
Fluoride
0-54
0.54
Nitrate-Nitrite
0 .24
o .24
NJ-trate-Nitrite
320
320
Tota1 Clranlde
ND
ItrItts (S} :
Dilutlsn tractsor: 1
.eaalyeie Ti-trrc.. : 1?:o0
wo#: ILTBGVfoQ-t'1s/H,f8GV1DR-l,IslD Ms r,ot-sample *: D5r09o163-001
114 MCAWW 325.2
115 0.33 MCAWI{ 325.2
106 MCAWW 3{0.2
105 0.41 I4CAWW 344 .2
oe/L8/os
aeh 8/os
oe/L4/as
ae/:.4/os
5263262
5263262
525757 8
s2s 757 I
o - 100
0.100
oL1utLo Pactor: 1
.BnaIyBLB Timc.. : 13:15
!{o*: IIJ36NTCS-MS/H.Ta6N1CP-MSD MS rot-Sample #: D'TA7O27O-OO} /)3.e4 r",/t s2 r.,reAr{w 3s3.2 ,rTiitiu-'-;;;O
3.Bs ug/t eo 2.L McAww 3s3.2 og/zolos s265552
Dilution Fector! 1
loalyaia Tinc,,: 22tOQ
wO*: H.r6JMfCZ-tUS/ff.f5.IM1C8-IrtgD MS Lot-salllple *: Dslo8o243-oo4
690 rq/t, 92 McAwer 353.2 og/zt/os 527L579
676 mg/r, 88 2.L I,!CAI{W 353.2 Og/Zt/OS 527L679
Dllutl,oq Factor: 1
Alr8.Ly6ia Tin6-. : 18:00
wo*: HKB3OTOU-IAS/SKE301DJ-MS,D !ffr r"ot-Sarple *: D5I130198-OO4
o.os?2 ng/t s7 swa{6 gotoe/g oglzt-og/zz/as sz64s3e
Qualifiers: N
0. 0551 mg/L
Qualifiers: N
DLlutLon Faetor:
analyele Tl.me. . :
s5 L. e sr{846 eol oE/9 09/21 -Oe/22/A5 5264s3e
1
L?: OO
Calcularlons &re porformod before roundlnj to avoirl rountt-off erroil] in celculated rooults.
N Spiked analyte rooovery is ounide $arcd control limis.
STL Denver 1,57
lAaBIf gPIffi SAHPI'B ffi REFORI
ceDeral Cheulatry
Clieut Lot *---: D5I100153
Date 8aryfled--- z Og/Og/o5 09:25 uate nec.elved--. O!/LO/OS
PERCENT
PARAMETER REC9\rEXX
Ammonia aa N
97
97
Chloride
LLz N
113 N
Fluoride
98
108 N
Nitrate-Nl-trl-te
100
97
Sulfate
29N
32N
Total Cyanide
32N
56 N, *
IWTB (9} :
RECO1IERY
LIMITS
RPD
RPD LI}4ITS MBTTIOD
llatri:r----o----3 GW
PREPARATTON- PREP
AI{IAI,YSIS DATE BATCH #
Lot,-Sample * : D5IL0O153-003
09 /2L/ Os 526s4't8
oe / zll 05 s26s478
Lot-Saqrle #: D5I100153 -0O3
o 9 / Lglos s263 262
oe /LB/os s263262
Lot-Saq>Ie # : D5I1001-53-003
09 /L4/ as 5257s7a-
oe/L4/os szszs78
l,ot-Sample #: D5f 1001-53 - 003
ae /20-o e /2t/ os s26sss2
ae /2o-o g lztl os s26sss2
LoE-SampIe * : D5f1OO1s3 -OO3
09 /2a / os s272L73
09/2s/ os s272L73
(++
(a+
wo*:
130)
13O) O.1o (O-30)
Dllutlou Factor: l-
Analyel-a fime. - : 04 r 00
wo#:
110 )
11-O) O.35 (O-10)
DiluE,ioa Factor: 1
analyels Tirne. - : 17 : 00
Tfo*:
107 )
r_071 t_+ (o-10)
Dilut,ion Faetor: 1
.nnalyeJ,e Time, . : 1.3 :15
r{o#:
11e )
1-1-s) S-g (o-30)
Dllutlon Factor: 1
AnalyeLe Tlme,.: O2:00
wo#:
1s3 )
Hr(AR9lDD-MS/Urang IDE-MSD Mg
McAwvI 350.1
MCAWI{ 350,1
(go
(go
(87
(sz
$z
(62
(4s
(es
Hr(ARe1e8 -MS/HKARg1C9 -MSD MS
MCAWW 325.2
MCAWW 325.2
HKAR9 r.DA-r{S/HrGR9 1De-MSD MS
MCAWW 340.2
MCAWW 344.2
rrKARg1C6 -MS/HrGR9LC7 -MSD MS
MCAWI{ 353 .2
MCaWW 353,2
HKAR9 ]-DF-MS/sXene IDG-MSD MS
MCAVIW 3-15 .4
MCATilW 375 .41s3 ) 1,2 (O- 2L)
PLlution Factror; l-
enalysle Time. . : L5: {0
wo#: HKARSTDH-DrS/HKAR91D,I-MSD MS I,ot-Saq)le #: D5r100153-OO3
(89 - 109) swg46 goros/sorza. og/zt-o9/zz/os s264s39
(se - 109) 2r (o-2o) sws46 goros/gorzu oe/zl-og/zz/os sz6tl539
DilutiOn Factors 1
AnalysL8 Tlme..: 12:00
Cdculationt are perforrned befom rounding to avold round-off onorl in calorlarcd results.
N Splkcd anatyte reooyory is outgide strted control limits.
t Relrtlve porcrrt diffcrcncc (RPD) is ouuide marcd conrrol llmiu.
158STL Denver
rf,xtRIT SPIXB SBI{PLE I}Nf,A REONT
General- Chqrni6!1y
cli€nt. rot *---: D5r100153
SAD'IPITE SPfKE
A},IOUNT AIqT
ME..ASRD PERCMf
O
RESIRY RPD ME:rHOD
llatrix-------i-: GW
PR-EPARATION- PREP
ANAI,YSIS DATE BATCH #PARAMETER
Arnmonia ag
Chlorlde
Fluorlde
AIT{OT]NT T'NTTS
I{0*: I$GRgrnn-us/uxen9lDE-MsD Msl r,ot-samlrle #: D5r10o153-003N
0.75 4 .00
0.75 4 .00
2200 5000
2200 5000
4 ,62 wrg /l' 97
4 .62 mg /t 97
Dilution Factor: 1
Analysl-e Tl-me. - : O4 : O0
McAww 350.1
0.10 MCAWW 350,1
MCAWW 325.2
0.35 MCAIIW 325.2
MCA$II{ 34O .2
7 .4 MCAV{W 34A.2
wo# : HI(AR91C8-MS/UKnR91C9-MSD MS r,ot-Sample #: DsIL00153-003
oe/za/os
oe / 2L/ as
oe/LB/os
ae/L8/os
oe/28/os
ae/2slos
5265d 7 8
5265478
5263252
s263262
5257578
5257578
5272L73
s27 2L73
7850 N mg/I'
?880 N mg/t
Dilutioa Factor: 1
6.LZ mg/T"
5.59 N mg/t'
Dl1ution Faetor: 1
nrraJ.ysis Tlme. - : 17: OO
WO# : HI(AR91DA-MS/HKAR9I.DC-MSD MS LOT-SAq>IE
1"L2
113
98
108
L.2
L-2
3so
350
5.00
5.00
2so
250
#: D5r100153 - 003
ae/L4/os
09/1,4/os
Analysie fl-me. - : 13 :15
Nltrate-Nitrite
o _ 1g 4 . 00
o - 19 4.00
SUI fate
wo# : Hr(AR91C6 -MS/HXaR91C?-IUSD MSI
4.L'l mg/l'
4 . 04 rng/L
PilutLon Factor: L
Analysl"e Tl.me. . : 02 : 0O
WO* : HI(ARg IDF-MS/HI(AR9 I"DG-I,ISD MS I,OI-SAMP}C
4L9 N mg/T, 29 MCAWIiI 37s-4
424 N rg,/t, 32 L.2 MCAWI{ 375 ,4
DiluLion Fact,or: 1
Aualyeie Tiule. . : 15: t0
100 MCAWW
97 3 .3 MCASII{
T;:f";J;,:;:)ilffi :::O
3 s3 - 2 ae / 2O- A9 / 2t/ AS s26ss52
*: D5I10o1"s3-003
Tota} Cyanide
0.056 0. L00
o - 056 0 . L00
Na!s_(s):
TIO*: IIKARSTOH-MS/HKAR91DJ-MSD MS Lot-Sample *: D5I1OO153-003
0.0883 W/t 32 sw846 gotos/g og/zt-og/zz/os s264s3e
Quallflers: N
Qualifierg: N,*
DilrrEiorr Factor: 1
AnalyaLe Tl,me. -: 12:00
Calculation3 arc performed bcfore roundlng to avoid rourrd-off crrors in calodatod resulte.
N Spiked analyte reoovery is ouside statcd control limis.
* Relrrive percent diffcrcncc (RPD) is outsido surted control limlts.
STL Denver ].69
gBUPf.B DTIPLICLTB BIrAI,ITATIO{ REPORT
Geueral. ehelnistrlr
Client Iot *---3 D5I100L53
Date Eaqll.ed--.!
PAIUUvI RESUITT
trork Order *-. - 3 HKC8P-SMP
HKCS P-DTIP
a9 / a9 / os o7 : 00 rlate Recei\red-, 3 09 / A9 / os
DUPIJICATE RPD PREPARATION- PREP
AI{AIJYSTS DATE BATCH #
5253 100
REgtrLT IINITS RPp r,rrgl] MEfirOp
7.7
SD LoE-Samp1e #: DSIO9O7-37-OO3
No unirs o.13 (o-s,o) sweae 9o4oB og/Lo/as
DllutLon FacEor: L Analyeie Time. - : 13 : O9
pH
7.7
STL Denver 1-7 0
STL Denver
Sample Receiving Checklist
Lot#: )<?/c,or.;J DatelTime x"cavea: 't|rafi"f nf.l\- ... )
C- .4,kr^ ' .f I.. -CompanyName & Sampling Site:
PM to Complete This Section: Ies
Resid,,al chlorine check required:O
Quote #:
Speuial Ins:uuctions:
Time Zone:
. EDT/EST . CDT/CST ' MDTI]VIST ' PDTIPST ' OTFIER
q Quarantined :
Yes
tr
No
G
Unpacking Checks:
Cooler#(s): f . E- 3 cr r' (
Terryrcratures("c)r...]'3 -.?.d U-7 V.7 2'L V.+
N/A Yes No InitialsInrt;zk
-.t/Aifhard delivered) Hno- docnmeot on CUR. 6 !tr F tr 1. Coolcr seals intact? (N/A if hand delivered) Hno, docnmeot on CUR
Ip tr 2. Chain of cusodypreseut? If no, documcnt on CUR.Chain of cusodypreseut? If no, documcnt on CUR.
tr fi 3. Bottles brokeu and/or arc leaking? If yes, document on C[-IR
ItJ S 4. Multiphasic sarnples obvious? If ycs, document on CllR.
+ tl 5. Proper contaiuer & preservatives used? (ref- Attacbment D of SOP# DEN-QA-0003) If nq docurrrnt on CUR.
Itr p tr 6. pH ofall sarrples checked audmectrequircrncots? Ifno, documeaton CIIR
I
P O 7. Sufficient volume provided for all analpis requested? (ref. Atachment D of SOP# DEN-QA-0003) Ifno,
I a"cument on CUR, and contact P.M before proceeding.l'& Et 8. Did chain of custody agree with labels ID and sarnples received?-$no, document on CUR.A trl 8- Did chain of custody agree with labels ID and sarnples receirypn\r
tr U fi 9. Were VOA saryles witbout headspacc? Ifoo, ao",r-"ot46UR
-)O p tl 10. Wcre VOA vialspreserrred? Prcservative QHCf ftfoi2"C fsodiurnThiosr.rlfate E Ascorbic Acid
fi d 1 I. Did samples require preservation with sodirrm thiozulfate?
h D tr 12.Ifyesto#lI,didthcsarnplescontainresidualchlorine?Ifyes,dooraeutouCLIR.l'd tr g 13. Sediment present in dissolved/filtered bottles? If yes, docurent on CIJR
E B E 14. IssuffrcientvolumeprovidedforclientrequestedMS,MSDormatrixduplicates?lfno,documentonCUR,and
' coutactPMbeforeproceeding.
0 A 15. Receipt date(s) > 48 hours past the collection date(s)? lf yes, notify PA/PM.
dt g 16. Are aaalyses with short holding times requested?
O q 17. Was a quick Trru Aromd (TAT) requested?o
STL Denver
fQA\Fonns\Sampie Receiving\Sampie Rcceiving Checklist 12 13 04 revision }2tllj,la4 L7 I
STL Denver
Sample Receiving Checklist
Lor#brncbtf3
L-ogin Chccks:
NlA )'cs No
{ U I8. Suflicicnt volumeprovidcd for all analysis regucsted? $ef.
documcnl on Cll& and conlacl Phl beforc procecding.
fiptl
Qr
Dfl D
fio Lr
BD
6rE
tr$D
Dd
Lr {,
Attaclrmcnl D of SOP# DEN-QA-(ttr03) lf rro,
19- Is slfllcionl volumc providcd for clicnl rcguested MS, [{.SD or matrix duplicatcslt lf no, documerrt on CUR, and
contac, PM beforc proceeding
Z0- p;d ttrc clrain of cusody includcs'receired b;/' and "relinguislrcd* by signalurcs, dalcs, arrd rimcs?
2I. \\rcre spccial log in inslnrcliom read and followed?
??. Wcre AFCEE maals togcd for rcfrigeralcd storage?
23- Were tcstt loggcrt checked agains the COCI llhich mmples were confirnred?
24. Was a Rldr fmur conpletcd for guic,k TAT?
25. Was a Shorl Hold form corr{ laed for an;, sfu111 1p16s2
26. Is'Sticl ICOC'rcAuired?
27, Wcrc special areiving instructions indicarsd in the Goreral Comncnts? lfso, u,ha{ u,erc the)4
and Storage Checks:
28. l\ras thc subcouhf,ct COC signcd and scDl witb samples to bottl e prqpT
29. Wcre sauryplc Isbcls dorrble-checked by a Fccond pcrson?
O
Labeling
{t!
,{o
;,{^A- = 30. WsrcsarylebotlcsandCOCdoubJecirecLedfordissolr,edlfiltcredrnelalsb)'asecondperson?nA
6'J 3I. Didthe sarryleID,Datc, aud lime fiomlab;l urard u,hat uas log:d?
32. Yirse stickcrs for special achiving instruaiux afi;.ed to cacb bo>; aod to thc ICOG.} See #27
33. Wcre AFffiE mdals storcd re, igeratcd?
34. Wcre "Sda ICOS'copix givcn to sarcllite storage areas?
Documenl any problerus or discrepancies and the actions talcn to resol'r,e them on a Condition Upon Receipl Anomaly
{=;
Repor{ (fin)
STL Denver 772
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STL Denver
4955 Yarrow Street
Arvada, CO 80002
Tel: [phone] Fax:
www.stl-inc.corn
STL
303 431 7t7t
AhIALYTICAL REPORT
Weste rn Zirconium Proj ect
Lot #: D5I070274
Sheri O'Connor
URS Corporation
8181 East Tufts Avenue,
Denver, CO 80237
STL DENVER
@hnk
Linda L. Benkers
Project Manager
September 30, 2005
Severn Trent Laboratories, lnc.
Table Of Contents
Sfan dard Del iverables with Sup porti ng
Report Contents
Sfandard Deliverables
(fne Cover Letter and the Report Cover page are considered integral
parts of this Stundard Deliverable paclcnge, This report is incomplete
unle.ss all pages indicated in this Table of Contents are included.)
. Table of Contents
r Case Narrative
o Executive Sumrnary - Detection Highlights
o Methods Summary
r MethodlAnalyst Sumrnary
o I,ot Sample Summary
o Analytical Results
o QC Data Association Summary
. QC Evaluation and/or Data Reports
. Chain-of-Custody
,
Supp orti ng Doc u me ntati on
(Nctte: A one-poge "Description of Supporting Docurtentation" ,s
providetl at the beginning of this section.).
r Volatile GC/I}IS
. Semivolatile GC/MS
r Volatile GC
. Semivolatile GC
.LCIMS oTHPLC
o Metals
o General Chemistry
r Radiochemistry
I Subcontracted Data
Documentation
Nurnber of Pages
Check below when
supporting
documentttion Is
pre$ent.nnnnnnEnn
STL Denver
Case Narrative
D5tO70270
With exceptions noted as flags or footnotes, standard analytical protocols were followed in the
analysis of the samples and no problans were encountered br anomalies observed- All laboratory
quality control samples analyzed in conjunction with the samples in this project were within
established control limits, with any exceptions noted.
The test results prcsented in this report meet all requirements of NELAC, and any exceptions are
noted. This report shall not be rcproduccd, except in full, without written permission from the
laboratory.
Sample Receiving
Four samples were received under chain of custody on Septembcr 7,20A5- The sarnples were
received in good condition at tcmperatures of 3.8oC and 3.3oC.
Please note that for sample ID GW-7A-090605 3 of 3 VOA vials were received containing 4mm
bubbles. The sample waS logged for the requested analysis. Also note that thc samples submitted
for 8260B analyses only require reporting of Chlorofonn only as per client request.
GC/I\{S Volatiles, SW846 82608
The MS[r4SD performed on a sample &om another client and/or lot was in control.
No anomalies were obsenred.
Total Metals, SW846 60108,6020 & 7470A
Samples D51070270-003 and 004 were analped at dilutions for several metals by methods
60108 and/or 6020 due to matrix interference andlor intemal standard failures. The reporting
limits are adjusted accordingly.
The method 60108 MS/I\4SD associated with batch 5265261was performed on a sample ftom
another client and/or lot and was not in control.
The method 7470AMS/MSD associated with batch 5259425 was perfbrmed on sarnple
D5\O7A270-002 and was in control for mercury.
The method 6020 MS/MSD associated with batch 5265180 was performed on a sample from
another client and/or lot.and was in control.
No other anomalies were observed.
General Chemistry, Various Methods
Samples D51A70270-002 through 004 were analyzed at dilutions for several compounds due to
high analyte concentrations. The reporting limits are adjusted accordingly and the associated
data is flagged "Q".
STL Denver
Chloride and fluoride were detected in the method blanks at concentrations below the reporting
limits, but above tle method detection limits. Associated positive sample results are flagged'i1".
The method 353.2 MS/MSD was performed on sample D5I070270-OOZ and was in control for
nitrate-nitrite.
AII other MSA4SD samples were performed on samples from other clients and/or lots and were
in control except for fluoride.
The pH duplicate was performed on sample D5I070270-002 and was in control.
No other anomalies were observed.
STL Denver
Eruffi W - Iletection Highlights
D5IO7027 A
RESULT
REPORTING
LTMTT UNITS
AIVALNICAL
METHODPARAMETER
cw-BA-oeocos a9/ 06/os 1o:3s aoz
Cadmium
Seleniurn
Arsenic
Barium
Ni ckel
Zinc
Calcium
PotasBium
Ivlagnesium
Sodiurn
Zirconium
Chloride
Fluoride
Ni traLe
Nlt.rat,e -Nitrite
pH
Sul- f ate
Amrnonia as N
Gn-8B-O9O5O5 Ae/06/A5 12:O5 OO3
0.000090
Qualifiers: B
0.00072 B
0 .0094 B
0 .17
0.0029 B
0.0045 B
52
45
45
s00
0.0a23 B
710 J, Q
1.1 J
o .24
o .24
7 .g
1_90 0
0,35
0 .00068
0 .0017 B
0,041 B
0 .0055 B
0 - 18
0.0050 B
170
0 _ 10
140
1-7 0
990
0_0029 B
2600 J, Q
0.69 J
24
24a
7,5
2500 0
260 0
mg/L
mg/L
mg/T,
mg/1.
mg/L
mg/T'
mg /r,
mg/r,
mg/L
mg/L
IJJ,g,/L
mg/L
mg/L
mg/r,
mglr-,
No Units
mg/t"
mg/L
mglL
mg/L
mg/L
mg/L
mg/L
mg/I'
mglL
mg/t
mg/L
mg/L
mg/L
mg/L
mg /r,
mg/L
mslL
mg/L
No Units
mg/1,
rr.g/t
sw845 5020
sw84 5 6A2A
sw846 60108
shr845 501-08
sw845 501-08
SWB45 5OlOB
sw845 50108
sw846 60L0B
sw846 60I_08
sw845 50108
shr845 50L08
MCAWI{ 325 .2
MCAWW 34A .2
MCAWW 353 -2
MCAWW 353 .2
sw846 90408
MCAWW 375 -4
MCAWW 350. L
shr845 6020
sw845 5020
sw84 5 6 0108
sw845 60108
sw84 5 6 0108
sw846 50108
sw845 60108
sw846 60L08
slAI84 5 5 0108
sw84 5 5 0108
svl846 50108
sw84 6 5 01_08
MCAWW 325.2
MCAWW 344.2
MeAlm 353.2
MCAI^IW 353.2
sv[845 90408
[4CAI^n^l 375 -4
MCAITil^l 350.1
0.0010
0 - 0020
0 - 015
0 ,010
0 - 040
0 - 020
0 _ 20
3.0
0.20
5.0
0.015
2s
0 - 10
0 .l-0
0.10
0 . L0
50
0 .10
0 .0050
0 .0L0
0 .10
0,01"5
0.0L0
0.040
o.zo
0.10
3-0
0 ,20
5-O
o - 015
254
0 . L0
0.1-0
1_.0
0.10
500
10
Cadmium
Selenium
Aluminum
Arseni c
Barium
Nickel
Calcium
Iron
Potassium
Irlagnesium
Sodium
ZLrconium
Chloride
Fluoride
Nitrate
Nltrate-Nitrlte
pH
SuI fat e
Ammonia as N
STL Denver
(Continued on next page)
EI(BCIITwE W - Iletecfion Highlights
D5rO7 4270
RESUIJT
REPORTING
LINITT UNITS
ANATYTICAL
METTIODPAIU\}IETER
Gw-'tA-o9ooo5 oglos/as 13:1o oo4
Cadmium
Selenium
Arsenic
Barium
Nickel
Z:,rr:c
Calcium
Potassium
I,Iagnesium
Sodium
Zirc,onium
Chl-orof orm
Chloride
F luoride
Nitrate
Nitrate-Nitrite
pH
SuI fate
Ammonia a.a N
0 .0089 B
0 .045 B
0.035 B
0 .059
O.L2 B
0. 045 B
6s0
2500
2500
220AO
a -a74 B
o -24 J
91000 J, Q
0.95 J
510
sr.0 0
7 -A
r_1000 0
14000 0
0 .10
0 .20
0 .075
0.050
a.20
0.10
2.A
30
2 -O
s0
0 .15
1,0
12 00
0 .10
0.10
l_o
0 .l"o
2500
500
mg/I'
mg/ t'
mg/L
mg/L
mg/L
mg/L
mg/L
wrylL
mg/L
mg/r,
mg/L
ug/L
mglL
mg/L
mglt'
rng/L
No Units
mg/L
mg/T'
sur84 6 6024
sv[845 6020
sw84 5 5 0108
sw84 5 5 0108
sw84 6 6 0108
sw845 6010B
sw84 5 6 0108
sw846 5010B
sw846 60108
sw845 50108
sw845 50L 08
sw845 82508
MCAWW 325.2
MCAWW 340 .2
MCAWW 353 .2
MCASil^I 353 .2
sw845 90408
MCAWW 375.4
MCAWW 350 ,1
STL Denver
METTIODSW
Dsr07027tJ
PAIUU4ETER
AI{ALYTICAL
METHOD
PREPARATION
METHOD
pH Aqueous
Chloride (Colorimetric, Automated Ferricyanide)
Fluoride (Potentiometric, Ion Selective Electrode)
fnductively Coupled P1asma ( f Cp) t.tetals
ICP_MS (5 O2 O )
Mercury ln Liquid Vlaste (Manual Cold-Vapor)
Nitrate
Ni trate -Ni t ri te
Nitrogen, Ammonia
SuI f ate
Tota1 Cyanide
Trace fnductively Coupled Plasma (fCP) Metals
Volatile Organics by GC/MS
Referenceg:
MCAWV'I
sw845
sw845 90408
MCAWW 325.2
MCAWI^I 344 -2
sw845 50108
sw846 5020
sw84 5 7 47AA
MCAVII{ 353 .2
MCAWW 353 .2
MCAWW 350 - t_
MCAWW 375.4
sw845 9or.oB/901-
sw846 50L08
sw846 8250B
sw845 90408
MCAWW 325.2
I,ICAWW 344.2
sw84 5 3 0L0A
sl,il845 3020A
sw845 747AA
MCAWW 353.2
MCAWW 353.2
MCAWW 350 - 1
MCAWW 375.4
sw846 90108
SWB45 3O],OA
sw845 s03 0B/ 826
"Methods for Chemical Analysis of Water and Wastee " ,
EPA-60O/4-79-o2O, March 1983 and subsequent revieions
I'Test Methods for Bvaluat,ing Solid Waste, Phyeical/Chemical.
Methodsr, Third Edit,ion, November 1985 and its updates.
STL Denver
A}IALYTICAI,
METHOD
METHOD/ANALYST
D5IO7A21A
A}TAIJYST
AI\TAI,YST
ID
MCASM
MCAI{W
MCAI^TW
MCAWW
MCAWW
sw84 5
SWB4 5
sw84 5
s![846
sw84 5
sw84 5
sw84 5
sw84 5
sw84 5
stil845
325 .2
340.2
350 .l"
353 .2
375 -4
5 0108
6 01- 08
50L0B
50108
6020
5020
7470p.
B25OB
eol- oBl e012A
90408
Claire Likar
Fougere Iq. Danielle
Claire Likar
Claire Likar
DusEi O - Criqui
Janel Motichka
Janel Motichka
Lynn-Anne Trudell
Lyrrn-Anne Trudell
Thomas ti11
Thomas ti1I
Janice S. Collins
Heat,her Despres
DusEi O - Crigui
Fougere M. Dahielle
004 382
005481
0 04 382
004 382
005589
aa28 52
2862
00554s
664s
006929
692e
0r.L668
o09250
005589
005481
Refererrceg:
MCAWI,il
SWB4 5
t'Methods f or Chemical Rnalysis of Water and Waetes " ,
EPA-500 /+-79-020, March l-983 and subsequent revlsions.
'tTest ttethods for Evaluating Solid hlaste, Physical/Chemical-
MeE,hods", Third Edition, November 1986 and its updatses.
STL Denver
SAIVIPLEW
Dsr 01 027 0
wo#SAMPLE# CIJIENT SAI,IPLE TD
SAIVIPIJED SAMP
DATE TIME
HJ35IJ OO]-
HJ35N 002
HiI3 55 0 03
HJ3 55 004
NO:[B (S) :
TB-090505
GW-8.4,-090505
GW-BB-090605
GW-7A-09060s
ae/06/os
agloslos Lo:35
a9/a6/as 12:05
as/a6/os 13:10
- 'llrc analydcal raslls of &c samplcs list.(l ebove arc prcsernal m Ihc torlowlng pa8cs.
- All calculations arc pertoilncd bcforc r<ruudil4 to avold round-off crrots ln calcuhtcd rcsults.
- Rc$rls notcd 6 'ND'wcrc nor detEclcd at or abovc &c sraul llnUt.
- This rs?on must not hc rcprrxluud, cxccpt ln full, yithwt lhc \/dtlcn approvd of lhc lahorarory.
- Rcgulb for tuc Fotlo\vlng parametcrB rrc rEvcr rcponcd m r dry wclSht basis: color, corroslylty. ddsity, fhshpolnt, l8nitability, laycB, odor.
paint 6lEr Dsr, pH, porosity pressure. rcacdvity. r"dox porcndal, spccific gravily, spot rcsts, silids, solub,llry, Empcraturo, vlscosity, anrt wclght.
STL Denver
IIRS Corporation
Cl.ient Sar4rl-e fD: I3-O905O5
cc/HS volatil.es
I"ot-Sanqrle #...;
Date S.amp1ed...3
Prep Date- .'- - - - :
Prep Batch #- - -:
Di].ution Factor:
DsI07027A-001
ae/06/os
oe/].4/as
s2581 3 0
1_
Ilork Order #- - -:
Date Received- - :
Analysis Date. .3
Analysie Time.. !
Metlrod. . , o - - - - - :
RESUI,T . ..
I.[D
PERCENT
RECOVERY
95
83
94
103
HJ35L]-AC
oe/07/as
oe/L4/a5
15:00
sw846 82508
REPORTING
LIMIT UNITS
tlatriX..- OC+.---: WQ
PAITJ{METER
Chl-oroform
SURROGATE
1-.0 ug/t-,
RECOVERY
LIMTTS
(73 118)
(ez 128)
(ze 118 )(7t 117)
Dibromof luoromethane
I ,2 -DichloroeEhane -d4
4 -Bromofluorobenzene
Toluene-dB
STL Denver
URS Corporation
C1ient Sarqrle lft: Gt{-8A-O9O5O5
cc/us volatiles
Iot-Sample #-.-:
Date Saryr1ed---:
Prep Datg.-..,.3
Prep Batch #. - . :
Dilution Factor:
D5r070270-002
a9 / A6/ A5 10 :35
oe/J.4/0s
szsB130
1
I[ork Order *- - -:
Date Receiwed- -:
anal-ysis Date- -:
An^alysis Time. - !
Flgthod. . . . -. . . .
RESULT
I'UD
PERCEMT
RECOVERY
95
87
97
103
HJ35N1A9
ae/07/os
0e/L4/os
15:20
sw84 5 82 608
REPORTING
IJIT,IIT UNITS
tlatrix-- ----r GW
PATU\}TETER
Chloroform
SURROGATE
1.0 ug/L
RECOVERY
I,IMITS
(z: 118)
(sz L28l
(za 118)
(tt 117 )
Dibromofluoromethane
L ,2 -Dichloroet,hane - d4
4 -Bromofluorobenzene
Toluene -dB
STL Denver 10
URS Corporation
CI.ient Sanp).e ID: GT{-88-O9O5O5
ccll{S volati}es
Iot-SarryIe #- - -:
Date SarryIed- - - :
Prep Date.-o---:
Prep Batch #, . . 1
Di].ution Factor:
D5I07027A-003
09laG/os 12:05
ae/L4/os
s2s813 0
l_
Work Order *- -.:
Date Received. . 3
An^alyeig Date-.3
Anal.yeis Tirne- -:
Method,.r,..,--:
RESULT..
ND
PERCE}TT
RECOVERY
95
83
93
100
HJ3 5slAe
ae/a7/os
ae/L4/os
15:39
sw846 82 5 0B
REPORTING
LTMIT UNITS
Dlatrix- - - - - - ;
PAIUqMETER
-
Chloroform
SURROGATE
1-.0 ug/L
RECOVERY
LIMITS
(tt 118)
(az 128)
(78 118)
(tt LL7 )
Dibromofluoromethane
L ,2 -Dichloroet,hane - d4
4 -Bromofluorobenzene
Toluene -dB
STL Denver
IIRS Corporation
C1ient Saryle fD: cfl-7A-O9O6O5
cclMs volatiles
Lot-Sanple *. - -:
Date SarryIed---:
trrep Date ---:
Prep Batch *- - -:
Dilutiorr Factor:
Dsr070270-004
A9/06/As 13:l-o
09/74/as
s25Br30
1
IYork Order *- - -:
Date Received. . !
Arral-ysis Date. . !
Arral-ysie Time. . 3
Mgthod--.ro?...!
RESIILT -o-24 J
PERCENT
RECO\IERY
108
7_1-2
1A2
95
HJ3 5 51A8
oe/a7/os
oe / L4/ as
l-5 ; 58
sw846 82508
REPORTING
LTMIT I]NITS
1- o lugl[,
RECO\IERY
LTMTTS
(73 118)
(62 128 )
(78 118)
(tt LL7 |
Dlatrix-GW
PNU\METER
Chloroform
SURROGATE
Dibromof Iuoromethane
L, 2 - Dichloroethane - d4
4 -Bromofluorobenzene
Toluene - dB
NolE (s) :
J Estirnatal re.sult- Rasult ls lcss than RL.
STL Denver L2
Lot-Sanrqrle *...:
Da.te, Sanpl.ed- - -:
PARAMETER
URS Corporation
Cl-ient Sauqrle fD; G!tl-8A-09O5O5
TO{IAL Meta].s
Date Received- - :ae/07/os
METHOD
Matrix.:GW
PREPARATTON- WORK
A}IALYSTS DATE ORDER #
D5r070270-002
09106/a5 10:35
RESULT
REPORTING
LIMIT UNITS
Prep Batch #,
Mercury
frep Batch #.
Cadmium
Selenium
Prep Batch. *-
Si l-ver
Aluminum
Areenic
Ba.rium
Ca].cium
Chromium
Copper
I ron
Potassium
: 5259425
ND
:5265180
o - oooo90
0 - ooa72 B
: 525526L
ND
ND
o. oo94 B
o-L7
52
l[D
}ID
}UD
46
0.00020 mg/L
oilut.ion Factor: 1
0 . OO1O rrg,/L
DiLut ion Fact,or : 1
o-oazo ng,/r,
Dilution Factor: 1
B sy{846 602A 09 / 23 - Oe / 27 / As Hir3 5NLA4
Analyeis Time..: 04:04
sw846 5O2O Oe /23-A9 /27 I 05 ll'f3srrljAs
Analysie Tlme..: 04:04
sw845 7470A ae / 2t / Os
Analyole Tlme-. : 18:37
sw846 6o1oB 09/23-O9/27 /As
Analysis Time..: 09:33
sw846 501-oB 09/23-09124/05
Analysls TJ.me. -: 00:10
sw846 50108
analysis Tirne. . : 09 :33
sr{845 601-08
Analyols Time..: o9:33
sll845 5(}108
Analysle Time..: 00:10
oe/23-oe/27 /os
ae/23-oe/27 /os
oe l73-09l24l os
sw846 60L08 09 /23-ae /27 / os
Analyeie Tirne. . : 09 : 33
sw846 60108 oe /23-Oe /27 / as
Analyaia Time..: 09:33
sw845 50108 a9 /23-ae 124/ os
Analyeie Time..: o0:10
IIJ3 5N1AU
HJ3 5N].AII0 ,010
Di lut ion
o .10
Pilution
o .015
DlluE Lon
o. o10
Di ]-ut ion
o-20
Di Iut ion
0. 010
Di lut ion
0 .010
Di lut ion
0 .10
Di lut ion
mg/t
Factor: L
tng/L
!'actor: 1
UoglL
Factor r 1
rng/L
Factor: 1
rylt
Pactor: 1
mg/L
Factor: 1
ms/r'
Factor: 1
rfiIlg/L
Factor: L
r{J35N1a
EJ36NUAK
IIJ35N1AL
EJ3sNLA\T
HJ3 5N]-AIq
HJ3 6N]-AI{
H,J3 5N1AW
3-0 wry,/L
Dilution Factor: 1
sw846 50108 Ael?3-Ag l24l05 H^]36rrrM
Analysis Time. . : 00 : 1.0
STL Denver
(Continued on next page)
13
Lot-sanrpl-e * -
PAITJ\METER RESULT
IIRS Corporati'on
C1ient Samgr1.e ID: GW-8A-O9O605
IIO|IAL Uetal.e
: D5I07OZ70-002
REPORTING
LIMTT UNTTS METHOD
[tatrix. . o o . . . , , ] GW
PREPARATION- WORK
ANALYSTS DATE ORDER #
Magneeium
Sodiunt
IUickel
Lead
Vanadium
Zinc
45
500
o - oo29 B
o_0046 B
o,0923 B
o .20 t0g,/L
Dllutlon Factor: 1
5-O rrlg,lT,
Di 1ut ion Fact,or : 1
0 .040 trrg,/L
Dllutlon FacEor: 1
0 . 0030 mg/L
Di luE,lon Factor: L
0 _ 010 mg/L
Pilut.ion Factor: 1
o. o20 uglt,
Dl}utlon Factor: L
o .015 rlg,/L
Ollutlon Factor: 1
sn845 50108
Analyeio Tlme. . : 00 ;10
sw846 50108
Analyeis Time..: 00:10
sH846 601(}8
Analysisr Time. . : 09 :33
sw845 60108
Arralysis Time . . ; 09 : 33
sw845 50l,oB
Analysls Tlme..: 09:33
srr845 5'0108
Analysie Time.,: 09:33
sr{845 60ros
Analyeie Time. . : 00 :10
09 /23-oe/24/ os EircchnjAo
ae / 23 -oe / 24 / 05 H.I36rSt L1
09 123 -o g / zt / as EJ3GNLAP
ae / 23 - oe / 27 / 05 HJ3 6N1AQ
oe / 23 - oe / 27 / os HJ3 5N1AR
oe I 23-09 / 27 / 05 EJ35NI3T
ae /23-o 9/2+/Os rlr36trrjA2O zirconium
NOtrE (S} :
B Estirrrated result. Rcsult is less than RL.
STL Denver L4
Iot-Sarqlle #- . -:
Datre Saqlled.. - j
PARAI{ETER
URS Cortrroratrion
Client Saryle fD: GTY-88-09O605
TO{FAL !tet,a,}s
D5r07027A-003
a9/05/aS 7.2=05 Date Receirred..! a9/A7/os
RESULT
REPORTTNG
LIMTT UNITS METHOD
:5259425
ND sw845 't470A Ae/2L/O5
Arralysla Tlme. . : L8 z 42
tlatrix.:GW
PREPARATTON- WORK
AI{ALYSIS DATE ORDER #
Prep Bateh #.
Mercury
Prep Batch #-
Cadrnitm
Selenium
hrep Batch * -
Si lver
Aluminum
Areenic
Barium
Calcium
Chromium
Copper
fron
Potaesium
: 5265180
0 - 00068 B
o-oo17 B
; 526525:.
IilD
o-o41 B
o. oo55 B
o-18
1_70
ND
IilD
o-10
140
oe/23-oe/27los
oe l23-oe/241os
oe/23-oel27 /as
a9 / 23- oe /z-t I os
oel23-09/24lAs
oe/23-oe/27/05
ae/23-09/27 l05
os /23*ae /24/ as
HJ3".
H.r365IAV
EJ355ILI{
H..B55IA5
HJ3 5s1ru(
H,J3 5 51A0
II^f355IA7
nfi65m0
0.00020 mg/L
Dllution Factor; 1
o - ooso ryll
Dllution Factor: 5
o - o10 WlL
OiluEion Factor: 5
0.01-0 mg/L
Dilution Factor: I
0 - 10 mg/L
Dllution Factor: 1
O - o15 ttg,/L
Dilutlon Factor: 1
o - o1O rg/T,
Pi IuEion Factor: 1
O -2o vq,lLl
Di]utlon Factor: L
0 - 0L0 nrg/L
Dilut iorr FacEor : 1
0 . 010 mg/L
Dilution F&ctor: L
O.1O mg/Y,
Di l-ut ion F actor : L
sw846
AnalysJ. e
ST{845
Analyeie
602 0
fime..: 04r07
5020
Time..= 04:07
sw84 5 50108
Analysie Time..: 09:38
srr846 60108
Analyaie Time..: 00:14
sw845 50108
aDalyeis Tlme..: 09:38
sru846 50108
enalyeis Time..: 09:38
srl845 501OB
Analysis Time, . : 00: L4
sw845 50108
Analysie ?ime . , : 09 :3 8
sw846 60108
Analysis Time . . : 09 :3 B
sw845 60108
Analysia Tlme, . : 00 :14
g[846 60108
Analysis Time. . : 00 :1-4
next page)
HJ3 5 51As
ae / 23-09/ 27 / OS EJ3ssrAP
a9 / 23 - ae I 27 / os H.r36sl.ac
HJ3 6 51AT
3.0
Dilution Factor: 1
wlL 09 123-A9 l24lA5
STL Denver
(Continued on
Iot,*Samp1e # -
PARA},IETER RESUI.,T
IIRS Corporation
Client SanpJ.e ID: GII-88-O9O6O5
TOTAL ileta]-s
: D5I07 027 0 - 003
REPORTTNG
METHOD
Matrix-..-.- : GW
PREPAITJ\TION- WORK
ANALYSIS DATE ORDER #LIMIT UNITS
t{agnesiun
Sodium
Ilicke].
Lead,
Vanadium
Zinc
]_7A
990
o-oo50 B
O - 20 vg,/T,
Dilution Factor: I
5-O rrylL
DilutLon Factor: 1
O - O4O vtg/L
DiLution Factor r L
0.0030 mg/L
nilutlon Factor: 1
0 - o1o mg/L
Dilutlon Factor: 1
0.020 mg/L
Dilution Factor: l
o - o1s rylr,
Dilution Factor: I
sll845 50108
Anal)reie ?ime. . : 0O:14
sw846 60108
Analygls Time..: 00:14
sH845 50L08
Analysig Time,.r 09:38
sw8d5 50108
Analyalo Time..: 09;38
sw845 501-08
Analysis Tl,me. - r 09 : 3g
sw845 50108
Arralysig Time, . : 09 ; 38
slr846 60108
Arralysie Time. . : 00 : 14
09 I 23 -O e / 24 / OS EI3651AA
09 /23- A9 I 24 / Os Ef365rAC
oe / 23 -a9 I 27 / OS HiB6srAr.
09 / z3-oe / 27 / os HJ3 6sLA2
09 /23 -09 / 27 / as HJ3651A3
ae / 23 - ae / 27 / 0s HJ3 6s1-A4
oe / 23-oe / 24 I os EJ365LADO zirconirm o-oa29 B
NOTE (S} :
B Esrhnated rcsult. Rasult Ls less rhan RL.
STL Denver 15
Lot-Saryle *.,,:
Date Saqlled. - -:
PARAMETER
URS Coryoration
Client Sanqrle ID; GTI- 7P.- 09O5O5
IIOIAL lletalg
Date Receiwed- . :ae/07/os
METHOD
D5r070270-004
a9/06/as l-3:l-o
t{atrix- -
PREPARATTON-
A}TALYSIS D.ITTE
:GW
RESULT
REPORTTNG
LTMIT UNITS
WORK
ORDER #
HJ3 6 5lAG
Prep Batch # -
Ivlercury
Prep Batch *.
Ca&niurn
Selenium
Prrep Batch # -
Si lver
Aluminum
Arsenic
Barium
CaIcium
Chromium
Copper
Iron
Potassium
:5259425
ND
:5265180
o-oo89 B
0-045 B
:526525L
ND
ND
0-035 B
o.o5g
550
IUD
buD
DUD
2604
0.00020 rrrg/L
Dilution Factor r L
o-10
Di 1ut ion
0-20
oi 1ut ion
vry,/L
Factor, 1.OO
n'g,/L
Factor: 100
0 .050 mg/L
Pilutlon Factor: 5
L. 0 rrtg/L
DIlut,ion Fact.or: LO
o - o7s rrg,/L
Dilution Fact,or: 5
O . O5O trg,/I'
Dllution Factor; 5
2 . O trg,/t,
nilutlon Factor: 10
0.050 mg/L
Dilution Factor: 5
0.050 mg/L
Di 1ut ion Fact,or t 5
1 ,0 mg/L
Di l-ut ion Factor : 1 0
30 ng/L
Dilu:ion Fact.or: 10
(Continued on
sw845 747AA o9/2L/ 0s
Rnalyolo Bime..; 18:44
sTrB46 5020
Analyslo Time.
sw846 6020
Arralyei s Time.
sw846 5oI.oB O9123-oe l27 / Os
Analysie Time. . : l-? : 53
sr{846 5or-oB oe/23-oel27 los
Analyols Tirne. . : 12 :53
slr845 60r.08 o9123-oe/27/O5
Analysis Tlme..: 00:0{
sw846 50108 A9/23-09/27/os
Arralysls Tirne. . : 12 : 53
sw846 60108 A9 / 23 -09 127 / os
nl,alyeis TLma. . : 12 r53
sw845 501-08 Ae/23-09/27 /OS
Analyeie Time. . r 00 :0{
sTr845 60108
Analysis Tlme,. : 00:0{
next page)
sw845 50108 0e/23-A9/27/os HJ3561A3
Analysis Time..: L2:53
sw84 5 6 01OB Oe / 23 - Oe / 21 / OS HJ3 657_
AnalysJ-e Time. . : 00 : 04
oelz3-o9127 f Os Er366r-AQ
04 :11
oe/23 -o el27 / os rLr356rAR
04:L1
H^r365I45
Hir365LL5
H*I355lAE
HJ3 66\A7
H,f3 651AA
H.T3 5 51AJ
STL Denver
09 / 23 - 09 / 27 / os B,tr366rAK
L7
Iot-SarryIe # -
PARAMETER RESULT
IIR.'S Corlrcration
Cl.ient Sanqrle ID: GW-7A-O9O6O5
TOIIAL Hetals
: D5I074270-004
REPORTING
Uatrri]G. . . ? t . - . - : GIAI
LTPIIT UNTTS TVIETHOD
PREPARATTON-
ANALYSIS DATE
WORK
ORDER #
Magnesium
Sodium
NickeI
Lead
Vanadium
Zi'nc
Zirconirrm
NOTB (S} :
2soo
2204O
O.Lz B
ND
}UD
o.o45 B
o-o74 B
2, O ulglr'
Pi lut,ion Fact,or: 10
50 ng,lL
Dilution Pact,or: 10
A.2A rgg,/t,
Pl lutlon FacE,or: 5
0 .015 ms/L
Pilution Factor: 5
0.050 urg/1.
Dilution Factor: 5
O .1O vlg/I'
nilution Factor: 5
0 - 15 vlg/L
Di lut ion Fact,or: 10
sn845 5O1OB 09 /23-Oe /27 I Os E;B65rAL
Analyaie Time.. : 00:04
sw845 6Ql-08 09/23-Ae/27/A5 HJ3661AD
Irnalysig Time., : L2 : 53
sr^r845 60108 A9/23-A9/27 /05 HJ3651AE
Analyeio Time. . : 12 :53
sw845 5O1OB Oelz3-oe /27 | os
Analyeie Time,,; 00:04
sn845 5O1OB Oe/23-Ae/27 / Os
Analysla Time..: 12r53
sr{846 5O1OB Oe 123-09127 | As
enalysie ?ime. . : 12 :53
sr{846 5O1OB Oe/z3-Ae/Zt / OS
Analysis Tl,me- . : 00 r 04
HJ3551;AIrl
H'B55IAC
EiBSSIAF
E^I355IAN
B Esimarcd renrlt- Rcsult Is lcss rhan RL.
STL Denver 1B
Iot,-Sanrqrl.e #- - -:
Date Sampled- --:
PARAMETER
IIRS Corporation
Client Saqrle If): GT[-8A-O90505
General. Chemistrlr
D5f07027A-0AZ Dlork O:ider *--,; H,J35N
a9 / aG / a5 10:35 Date Received- - : a9 / a7 / as
RESULT RIJ I]NITS METHOD
o - 10 No Unit,s SIt845 90408pE
Aurnonia aa IV
Ch-I-oride
Pluoride
lUitrate
Nitrate-I$itrite
Su].fate
Total Cyanide
J,Q 25
oe / o8/ os
oel2a/os
oe/Ltr/ os
aeloe/as
ael 08/os
oel2ol os
oe /L3l os
s25L527
5265473
s263252
52s2s4L
5255581
s2sssrb
5255526
7-fJ
o_3s
7LA
1.1 J
o.24
o.24
Ieo 0
}TD
w/L
Diluclon Factor: 1
O - 10 wrg/L
ollutlon Pactor: 1
Analyeis TLme..: 13:11
ucAwlr 350 - 1
erralyeie TJ,me. . : 22 :aa
!{cArrw 325 -2
Analysis Tirne., : L7 : 00
ucArilw 344 -2
Analysis Time..: II:30
ucLrilr 353 _2
Analyeie Time..: 0B:20
UCAITT{ 353 - 2
Arralyels TLme. . : 22 t OA
IrtcAwrr 375 -4
enalyeLe Time. . : 12 :00
sw845 90108/ e0r.2A
furalyeis Time-.: 15:40
Dilution Factor: t0
0 - 10 tug,lL
Di lution Factor : l-
o.1o rry/L
Dilution Factor: 1
O .10 rug,ll,
oilutlon Faetor: 1
50 vrylt
Dl }ut. ion Fact or r 1 0
0.010 mg/L
Dilution Pactor: 1
09/1s-oelB/a5 52s9]-76
O
Ftatrix, . ,. . - - - - :
PREPARATION- PREP
AI{AIYSTS DATE BATCH #
RL Rcponlng ljmir
J Method blank contamlnatlolr. The arsociatcd rncthul blank contalns rhc target anulyte at a rcporrabk level.
a Ehvatsd reponlng llrnit. 'lhe reporting lhnlt is clevutetl due ro hfh anatye levels.
STL Denver
Iot-Sarylle *,..:
Date Sanp1ed....l
PARAMETER
IIRS Corlroration
Client Sanryle fDr GW-8B-O9O6O5
General ChemiBtry
Ilork Order *. . -: HJ355
Dat,e Received. - 3 09 / A7 / As
RL UNTTS METHOD
FIatrrix-- ---.! GW
PREPARATION- PREP
AI$AIJYSIS DATE BATCH *
Dsr070270-003
oe / AG / os 1-2 :05
RESUI,T
PII
Anunonia aB Il
Ch.].oride
Fluoride
tititrate
7.5
260_ 0
240
260o_
ND
L0 vg,/r,
Dtlution Factor: 1 00
2600 J, Q zsO wlg,/T'
nllution Factor r L00
o-59 J o-1O vtg/L
Dl lut,ion Factor : 1
24 o-10 nrg/L
Dilution Factor r 1
srs845 eo4oB oe l08l0s s25L527
Analysia Time. . : 13 :l-8
I.IeArflW 350.1 O9/2O(O5 5265473
Analyeie Time..: 22zAA
rieAr{H 32s -2 oelI-.slos 52632s2
Analyoie Time.., L7:00
rrfcAww 340.2 a9/o9/a5 525254L
Lnalysis Time..: 1L:30
rrtcAhrsr 353 - 2 agl o8/o5 527L542
Analyele Time. -: 0B:20
ucArrrrir 353 .2 09127 / 05 527L579
Analyeie Tlme. . : 1.8 :00
MeAHn 375 -4 O9/L3/O5 5256526
Ar:alyais Time- . r 12 : 00
sw845 901 a8/e012A Oe /l-5- 09 /L9 / 05 5259L76
Arralyeis Time, . : 15 :40
O.1O No Unite
Dilut.lon Factor: 1
O
Nitrate-Nitrrite
SnI.fate
Total Cyanide
r[o:fE (s] :
1 . o vq,/T'
Dl lut ion Fact,or : 1 0
a soo rrrg,/L
Dilution Factor: 100
0 , 010 mg/1,
Dilution Pactor: I
R[. Rcporting Limlt
a Elevated reportlng lirnit- Thc rcporting limlt Is clcvated due ro hlgh analyte levels.
J Mothod blank corrtirmination. Thc asurciatcd urcdrod bkurk contalns ilrc urget analyte at a rcportablc level.
STL Denver 20
I^ot-Samp1e #...:
Date Sarytled.. . l
PAIU\METER
IIRS CorSrcratrion
Cl-ient Sanr4r1e II): GW-7A-O9O5O5
General. Cheuristrlr
D5I07027A-004 Work Order #...: H,J355
09 / 06/ a5 13 : L0 Date Received. - ! A9 / 07 / 05
RESULT RI.,I]NITS METHOD
l{atrix-- ----: GW
PREPARATION- PREP
A\TA,LYSIS DATE BATCH #
r
Anurmnia aa t{
Chloride
F].uoride
Nitrate
lilitra.te-Nitrite
SuI-fate
Total Cyanide
DrotrB (s) :
O - 10 lrrry,/L
Oilution Factor: 1
0-10 ng,IL;
Dilution Factor: 1
10 vtg/L
Dilution Factor: I00
25Oo vE lL
Dllutlon Factor: 500
0 .01o mg/L
Dllutlon Factor: I
7-O
14000 0 500 nq,lL;
Pilution Factor; 5000
91000 iF, Q L200 W/1,
Dilution Factor: 500
Arralyale Time - .' 13 : 23
I.iCAIfIf 35O - 1
Analysis Time..: 18:00
MCAITW 325 -2
Analysis Tlne..: 17:00
MCAYTTT 34O .2
Arralysis Time. . : 11 : 30
HEATTTY 353 .2
Analysis Tlme..: 0B:20
MCAI{TU 353 .2
nnal,ysis Time. . : 18 :O0
DrcAI{t{ 375 -4
enalysie Time. . : 12 :00
o .10 No urrits sw846 90408
Dllutlon Factor: 1
oe / o8l 05
oelzt / as
oe lLs/ as
oe / oelos
oe / o8los
ae/27 /05
ae/L3 / os
5271,6ro
5256526
525L527
527L429
5263252
525254L
527l-542
o_95 J
510
s1o 0
11000 0
ND sw845 e0r0B/ 90r.2A 09/ l-5- 09lLe/a5 szseL76
Analysie Time..: 16:{0
RL Rcportlng Llnlt
a Hlrvated reporting lirrrit. Ilre reportirtg lirnit is elevated due to hlgh analytc levels.
J Method blank conmmlnadon. Thc associaad nrcrhod blank conrains ilre nrger anatyrc ar a reponahle levet.
STL Denver
ac DATA A"SSoCIATION W
DsI A7U.27o.
Sample Preparation and Analysis Control Numbers
SAYTPTE#
0 01-
002
003
004
IVIATRIX
wQ
GW
GW
GW
GW
GW
GI^I
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GI^I
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GV[
GW
GW
LEACH
BATCH #
PREP
BATCH #
szs8130
s253252
525254 1
s26ss s 2
52655 8 1
s2s9L7 6
52651_ I0
5259425
525L527
s2s81 3 0
526526t
5256526
5265473
5263252
525254 r_
527L542
s27L67 9
5259L7 6
s26518 0
s2s9425
s2sls27
s258130
52652 51
szs6s26
526547 3
5253252
525254L
527L642
527L57 9
5259176
5265 r.8 0
525942s
525L527
525813 0
s26s 2 51
szs5525
527L429
MS RUN#
5258057
s26316 6
52s5LA2
s265344
5259497
s265 r_ 1- 5
52621A2
5255129
s258057
5265L7 9
52553 7 0
52652 B B
5263 16 5
5255r_ 0 2
527 L432
5259497
526511_ 5
s252142
5255L29
s25 80 57
52651_7 9
525637 0
52652 I I
s26315 5
525sL02
5277,432
52s9A97
525511 5
5262102
52551,29
5258057
525517 9
525637 0
s27].294
AhIAIJYTTCAI,
METHOD
sw845 82508
MCAWW 325 .2
MCAWW 340 -2
MCAtyW 353 .2
MCAWW 353.2
sw84 5 90 r- aB/ 90r-2A
sw845 6020
sw846 74704
sw845 90408
SI^I846 82508
sw84 6 5 0108
MCAWW 375.q
MCAV'IW 350 . L
MCAWW 325 .2
MC.AWW 344.2
MCAWW 353 .2
MCAWW 353 - 2
sw846 eoL oB/ 90r2A
swB45 6020
sw846 7470A
sw846 90408
sw84 6 82 508
sw84 5 50108
MCAhII{ 37 5 .4
MCAWW 350.1
IVICAWW 325.2
MCAWW 340 .2
IYICAIW{ 353.2
MCA}ilW 353 _ 2
sw845 9010B/ 90L2A
5I/1846 6020
sw846 74704
sw845 9040B
sw845 82608
sI{845 50108
IVICAI^II^I 37 5 .4
MCAWW 350 .1
STL Denver 22
METEOD BI,AT{K REPORT
GCluS Vol.atsileo
Client Ipt #---: D5r07027O
It{B lotr-Sampl-e *: D5Il-50000-130
Arralyois Date - - : A9 / L4 / 05
Dilution Factor: 1
PAHqMETER
Chloroform
SURROGATE
Dibromofluoromethane
L, z-Di chloroethane - d4
4 -Bromofluorobenzene
Toluene-dB
rr0rE (s) :
Itork Order #- - -:
Prep DaEe-. ... , l
Prep Batrch #. -.:
TIMIT UNITS
Mat,rix-- ----: WI\TER
;qnal-ysis Time - - : 09 : 52
METHOD
HKKOP].AA
oe/L4/os
525813 0
RESULT
REPORTING
(z: 118)
(ez 128)
(za 1t-8)
(tt 117)
ND
PERCENT
RECO\rERY
99
89
97
LA2
L .0 ug/L
RECOVERY
LIMTTS
sw845 82508
(hlculations arc pcrfonmtl beforc rouncling to avold rouud-off erront in calculatcd re.qrlLs.
STL Denver
W CO}UTROI, SAUPI,E ETIALUATTON REFORT
GC/Dl^s Volati1.ee
Work Order #.--: HKK0P1AC lllatri.x. . - - - - - - - : WATERClient Lot, #---;
f,CS lot-Saqrlef :
Prep Date-.----:
Prep Batch #...:
Dilution Factor:
PA]U\IVTETER
D5r070274
Dsr150000 -130
oe/74/os
s258130
l_
Anal-ysie Date.. ! a9/14/o5
Analysis Time- -: 09:14
PERCENT RECOVERY
RECOVERY LIIIITS METHOD
1, I-Dich].oroetfrene
Benzene
Chloroberrzene
Toluene
Trichl oroethene
SI]RROC,ATE
Dibromofluoromethane
a, 2- Di chloroethane - d+
4 -Bromofluorobenzene
Toluene-dB
BICIE (S)
=
107
99
1_O6
107
108
(oo L32l(zs 1zo)
fia t-r-8)
(78 LL8)
(79 L22')
PERCEMT
RECOvERI
95
88
97
1-0 I
sw845 82508
sr{845 82608
s'Ir845 82508
srr845 82508
sw845 82508
RECOVERY
LIMTTS
(z: 118 )(62 128 )(ze 118)
(7t LL7)
Calculatlons arc pcrforrned before roundlng to avoiJ rourxl-off errors in calculated rcsults.
Bold print denorqs control perarncters
STL Denver 24
Client Iot fi. - . :
LCS Irot-Saryrk=#:
Prep Datg.,. -.. !
Prep Batch #- - -:
Dihrtion Factor:
PAIU\METER
D5 1070 27 0
D5I150000-L30
oe/14/as
525 8L3 0
1
I-.ABORANORY CONIROL SAUPI,B DATA RBPORT
cCl!{S Vo}atiles
Tlork Order #- - -: HI(K0PLAC
Analysis Date. . ! A9 /L4lA5
Analyeie Time. . ! 09: L4
Itlatri:r : WATER
PERCENT
RECOVERY METHOD
1, l-Dichl-oroethene
Benzene
Ch]-orobenzene
Toltrene
Trichl oroethene
SURROGATE
SPIKE
AFIOUNT
10-o
10-o
10.o
10_o
f-o.o
MEASURED
AMOUNT
10-7
9. 95
10 .6
10-7
10-8
PERCENT
RECOVERY
9s
88
97
10L
UNTTS
ug/L
ug/L
rug/I'
IJ,g/L
wg/L
RECOVERY
LIIvIITS
107
99
106
LO7
108
sw846 82508
sw846 82508
sw845 82508
sr{846 82608
stl846 82508
Dibromofluoromethane
L, 2- Di chloroethane - da
4 -Bromofluorobenzene
Toluene -d8
NOTE (S) :
( zs LL8)
(az L28l
(za 118)
(77 1L7)
Calculations are perfornrcd bcforc roundlog to avold round-off crrors in calculatal regults.
Bold print denorcs conrrol paranrccrs
STL Denver
ITIATRIX SPIKE SA}TPI,E EIIALIIATION RBtrORT
Gc/I.r.S voJ.atsiles
C1ient l^ot' fi. - . :
MS Lot-Sanrp1e #:
Date Saqlled- - - =Prep Date ---:
Prep Batch *- - -:
Dilution Factor:
PAIU\ME:rER
DSI070270
DsI090287-002
a9/07/05 15:05
oe/L4/a5
525813 0
1
I[ork Order #- - -
=
Date Received--=
enalysis Date- -:
Ana}.yeis Time- -:
HiI9MEIAC-TvlS
HJgME].AD-MSD
oe/oe/os
oe/14/os
10:50
RPD
RPD LIMTTS
Matrix- . D . - . . - . ! WA?ER
[vIETHOD
1, l-Dichloroetrhene
Benzeue
ChI-orobenzene
Tol.uene
Trichloroethene
SURROGATE
Dibromofluoromethane
L, 2- Di chloroethane - d4
4 -Bromofluorobenzene
Toluene -d.8
NOirE (S) :
107
1_O3
99
98
105
106
109
107
LO9
105
PERCENT
RECO\TERY
RECOTTI.ERY
LTMITS
(e 5 L32l
(e e 132)
(7s 12o)
(zs 120)
0e 118)
(za 1r-8)
( za r-18)(za 1r"B)
(tg Lzzl
(79 L22l
PERCENT
RECOVERY
9s
95
B7
84
93
93
L02
1.0 3
3 -7 (o- 26)
r. - 9 (o-zLl
o .28 (O- 2Al
1.8 (O-221
2 -5 (O-231
slr845 82508
srr846 82608
sIY845 82608
sw845 82508
sw846 82608
srr846 82508
sw846 82608
sw845 82608
sw846 82508
sw846 82608
RECOVERY
IJIMITS
(z: Ll8)(73 118)
(ez 128)
(ez 128)
(ze 118)
(ze 118)
(tt r"17)(tz rrr)
Calsulatlons arc pcrlbrmerl before roulrdlng to avoitl round-off errors in calculated resrlls.
Bold prtnt denotcs conrrol paramcrcrs
STL Denver 26
HATRTX SPIIG SA}dPI.B DATA REPORT
cc/tds Vo1atil.es
Cl.ient lrot #. . - =
HS lot-Sample *:
Date SaryI-ed- - -:
frep Date ... !
Prep Batch #.. -:
Dilution Factor:
PAIU\METER
D5I070 27 0
D5r090287-002
09/o7/as l-5:05
oe/]-4/as
52s813 0
l_
Work Ord,er #- -.3
Dat,e Receiwed. - l
arral-ygie Dat.e. . 3
Analysis Time. - l
HJgMElAC-MS
HJ9MB1AD-MSD
ae/ae/as
oe/14/os
10 :50
Matrix.- ,---r WATER
SPTKE MEASRD
A}4T AMOTINT
PERCNT
REC\MY RPD METIJOD
SAII{PIJE
'AI,lOUlm
ND
IiID
ND
}ID
ITD
ND
ND
ND
tlD
ND
TINITS
1, a-Dichl-oroethene
Benzeu.e
Ch]-orobenzene
Tol-uene
TrichI-oroetlrere
SURROGATE
10 - o L0.7
10.o 10-3
1-O-O 9.g5
Lo-o 9.76
10-o 10.5
10 - 0 10.5
f_o. o 10 .9
10-o Lo.7
10-o 10-9
10 - 0 10.6
PERCENT
RECOYERY
95
e5
87
B4
93
93
LO2
103
luglL
\s/L
u.s/L
Iu.g/L
Iug/L
]u.g/t
U.g/L
U.g/L
wg/I'
lug/L
107
103
99
98
105
106
109
107
l-o9
1_O6
RECO\TERY
LIMTTS
(73 118 )(zr 118)
(ez 128)
(e z L28l
(za 118)
( 78 l_18)
(tt r_17 )(7t 117)
sw845 82508
3 -7 SI{846 82508
s'w845 82508
1 .9 SI{845 82608
sn845 82508
o -28 Sr845 82508
s"w846 82608
1 -B SH846 82608
sw845 82608
2.5 SI{B45 82508
D l- b romo f 1 uorome E hane
L ,2 -Dichloroethane -d4
4 -Bromofluorobenzene
Toluene-d8
DrorE (s) :
Calculations are pcrforntcd beforc rouuding to avoitl round-off crrors in calculacd rc.sulB.
BoId print denotes conrol peramctcrs
STL Denver
Tf,HfHOD BI,ANK RBPORT
TULAL Uetals
Client lot' * -
PARAI*IETER
: D5IO7 A27 0
RESULT
REPORTING
LTMIT UNITS METHOD
Hat,rix- - O . . . . . - r WATER
PREPAIUITION- WORK
A}IA.LYSTS DATE ORDER #
UB Iot-Sanp1e #: D5f160000 -425 Prep Batc.h #- -
Mercury ND 0.00020 rftg/t
olluLlon Factor: L
nnalysle Tlme,,: 18:05
uB lrot-Sanup1e #: D5I22A 000 -180 kep Batc.tr # -
Cadmium ND 0 - 001-0 mq/L
Selenlum
Dllution Factor r I
Analysis Time. . : 03: 55
ND 0-0020 mg/L
Dilution Factor: I
Analysia time,.: 03:56
IIIB I.ot-Saryl1e #: D5I22A000 -26]- Prep Ba.tch #-
A,luminum IVD 0 ,10 mg/L
Arsenic
Dllutlon Factor: 1
Analysig Time..: 23:4L
0 .015 ntg/L
Dl lut, Lon Factor r 1
Analyoio Time..: o9223
0.010 mg/1,
Dllut,ion Factror r 1
Analyeis Tlme..; 09:23
0.20 mg/L
Dilution Factor: I
Analyels Tlme..: 2324L
0.010 mg/L
DiluLion Factor: 1
Analyeis Time..: 09:23
0.010 mg/L
DiLutlon Factor: 1
Analysis Time, . : 09 :23
0.l-0 $g/L
Dilution Factor: I
Analysis Time. , : 23 z4a
Barium ND
Calcium
Chromium
Copper
Iron
sw845 50108 oe / 23 - ae / 27 / os HKsQwl-AD
sw845 50108 09 /23- o e /27 / os HKSQW1AE
sw846 50108 0e/*/as HK5QWIAIyI
sw84 5 5 0108 oe / 23 - a9 / 27 / os HKSQWI-AF
sw845 50r_08 09 / 23 - A9 / 27 / As HKsQWIAG
swB46 50108
525942s
sw845 74704
52651 I O
sw846 6020
sw845 5020
526525L
sI,I845 60108
oe/2r/os HK\IT{314A
09 / 23 -09 / 27 I os HKSDAIA.A,'
a9 /23 - 0 9 /27 / As HKSDAI-AC
ae/23/os HKSQWlAC
ND
IUD
ND
ND
STL Denver
T{ID
(Continued on next page)
ae/23/05 HKsQVI1A]I
28
I{ETEOD BI,ATTK RBtrORT
ItO(fAL lteta].s
Client Ipt * -
PARAMETER
: D5I0 7 427 a
RESULT
REPORTING
LTI{TT UNITS
uatrix.. ---.3 WATER
METHOD
PREPARATION_ WORK
ANAI,YSIS DATE ORDER #
Lead
Magnesium
Nicke]
Potrassium
Si lver
Sodium
Vanadium
Z inc
Zirconium
NOTB (S) :
ND
ND
ND
ND
0. 0030 rlrg/t
ollution Factor: 1
Arralysls Time, . : 09 :23
0.20 mg/L
Dllution Factor: 1
Analysle Time..: 23:4t
0 .040 mg/L
ollution Factor: 1
Analyeie TLme.,: 09:23
3.0 l;rrg/L
Dilutlon Faqtor: 1
Analysle Time, . : 23 :a}
0 - 010 ng/I'
Di lut ion Fact.or ; 1-
Analyelo Time. -: 09:23
s-o mg/L
nilution Factor: 1
Analyels Time. . : 23 -.41
0.0L0 mg/L
Pllufion Factor: 1
Analyele Time,. : 09:23
0.020 mg/L
Dllution Factor: 1
Aralysie Time..: 09:23
0 - ols r,;tg/L
Dllution Factor: 1
.lnalysis Time-. : 23:{I
sw845 50L0B oe / 23 - 09 / 27 / os HKsQwlA,r
sw845 501-08 oe/n/as HKSQW1AQ
swB45 60108 ae / 23 - 09 / 27 / a5 HKsQwlAlr
sw846 50108 ae/23/0s HK5QWlAP
sw84 6 50108 09 /23-a9 /27 I os HKSQWLAAND
ND
ND oel23/os HK5QW'J
ND
ND
sw845 50108
SI^I845 50108 oe / 23-ae / 27 / AS HKSQWIAK
sI,\I845 60108 0e /23-09 /27 / OS HKSQW1AL
swB45 60108 oe/23/05 HKsQW1AT
Calculatlons ere perfornrd before rourding to avold rourxl-off error$ in calculatcd results.
STL Denver
I,ABOR;ATORY @IUTROL SATTPIJB ETZILTIATION REPORT
T0TAL Meta]-s
Iot-Sanple *. - - : D5f07027A
PERCENT
PARAI,IET.ER RECO\TERY
Dlatrix.- --,.r WATER
RECO\IERY
LIMITS RPD
RPD
LIMITS
PREPARATION-
A\IALYSTS DATE
PREP-
BATCH #
Mercury
NOTB (S) :
98
99
METHOD
( 8S 114 ) SV{84 5 7 47 AA
(as 1l-4'l t.t (o-10) swa4d 7470A
ollurion Fact.or: 1 Analyele Tirno..: 18:07
0e / 2L/ as s2se42s
ae/ 2a/ os 525942s
Calcularlons are yrcrfornrcd before roundlng to avoid round-of'f errors in calculuetl raslts.
STL Denver
I.ABORATORY CCINTROL SAUPIJE DATA REPORT
IlOTAL Metals
Lot-Sample #. . - : D5I A7 027A
SPIKE MEASTIRED
PAIU\METER AIYIOUITT AMOUNT UNITS
PERCNT
RECVRY RPD METHOD
Irlatrix- . . - - - . - - r [vArER
PREPARATION-
AIVALYSTS DATE
PREP
BATCH #
Mercury
NOTB (S) :
o-00500 0-00488 mg/L
0.00500 0.0A497 mg/L
Dllution
sw845 7470A
L.7 SW845 747AA
Analysis rlme.,: 18:0?
0e /2L/ os s2se425
a9 /2L/ aS s2s942s
98
99
Factor: 1
(.lalculatlons are pcrfornrcd before roundlng to avoid round-off error$ in calcularcd results.
STL Denver
OBarium
Chromiurn
Copper
Nickel
Lead
Vanadium
Zin.c
Crlci.um
I,ABORATORY COII:IROL SA}TPI,B ETIALTIATION REFORT
T(}TAL ltteta].s
Cl.ient Iot, #.
PAIU{METER
LCS L'ot-Sanple#:
Cadmium
Selenium
Aluminum
Arsenic
DSr07027A
PERCENT RECOVERY
RECOVERY LIMITS I'{ETHOD
I{atrix-- ....3 WATER
PREPARATION-
ANAIJYSIS DATE I^IORK ORDER #
LeS lot-Saup1e#: D5T220000-261- Prep Batch * -
Silver 98 ( Bs 114) Sw846
1_00
DiluEion Factor: 1
(ae 108) sw845
Dllution Factor: 1
( ag 109) sw846
nilutlon Factor: J.
(gg l_13) sw846
Dilution Pactor: 1
(eg Ltz) sw846
nilution Factor: I
(85 l-r0) sw846
nllucion Factor: 1
( 9o 1l-0 ) sw845
Pilutlon F'actor: L
( gr 111) sw84 5
Dllution Factor: 1
(BB 1,]-2) SWB45
Di lution Fact,or : 1
(es 110) sw845
ollucion Factor: 1
(sg t-Lo) swl46
Di Iut. ion Pactor : 1
oe / 23 - a9 / 27 I 0s HKSDAI-AE
TLme.. : o4:oo
0e / 23 -oe /27 / as HKSQWIAU
Tlme..: 09;28
ae /23 / as HKsQwLAv
Tlme..: 23246
09 / 23 - Ae / 27 / 0s HK5QI'I1AW
Time.. = 09:28
oe / 23 - 09 / 27 / os r{KsQw]-N(
Tlms..: 09:28
0e I 23 - a9 / 27 / 05 HKsQWr.Ao
Time. - ' 09:28
09 / 23-oe / 27 / OS HK5QW1A1
Tlme..: 09:28
D5I220000-180 hep BaEch *-
97 (ag 110) Sw846
Di lut ion FacE,or : 1
(az ttz) sw946
Dilution Factor: 1
lo2
- : 52651,8 0
5020 09 / 23 - oe / 27 / As HKSDA1AD
Analysis Tirne., : 04 : 00
5a2A
Arralys i s
- -: 5255251
5 01_ 0B
AnaLysi a
5 0108
Analys i s
6 0108
Analyoiu
5 010B
Analyeis
5 0108
Analyei s
5 0108
Analyeie
60108 09/23-Ae/27 /as HKsQw]-Az
Analysis Time..: 09:28
501-oB oe/23-09/27/As HK5QW1A3
Analyeia Time..: 09;28
5010B 09/23-A9/27/0s HKSQW1A4
Analyele Time..: 09:28
50108 Oe/23-oe/27 los HKSQWTAS
Analysis Tlme..: 09t28
5o1oB Ae / 23 / a5
Analysis Tlme.. r 23246
next page)
STL Denver
(Cont inued on
HKSQW1A6
32
I,ABORATORY
Dsr070270
PERCENT RECO\TERY
RECOVERY ]_,_LMrrS
COIUTROL SATTTPIJE EITAITIATION REPORT
TOTAL Metra}g
Client Iot * -
PARAMETER ,...Iron
PotaBEium
Magnesium
Sodium
Zirconium
trufE (s) :
96
103
oo
100
104
METIIOD
( gs 110 ) sw845
ollut.lon Factor: 1
(ae 111) swg46
Dilution FacE,or: L
( gr 11r- ) sw846
Dilution Factor: 1
(gr LLz) swB4G
nl-lut ion Factor : 1
(7 s L25) Sw84 5
oilutlon Factor: 1
5 0108
trra lysl s
5 010B
enalysis
6 0108
Analysi s
6 01_ 08
Analyei s
50108
Analye i o
lllatrix-- ----: WATER
PREPARATION-
AhrAr,YSrs pATE qrg-RJ( ORDER #
09 /23 / os HKsewlAT
Time..: 23246
a9 / 23 / 05 rIKsQwlAB
Time..: 23246
oe /23 / os HKsQvAIlAe
Time. .: 23t45
a9 /23 / as HKSQW1CA
Time..: 23246
oe /n / as HKsQwrcc
Time. . : 23:46
Calculatlors are performed bcforc rourullng to avoid round-off crrors in calculoted results.
STL Denver 33
Cl-ient l,ot *-..3 D5f07027O
SPTKE IVIEASIIRED
PNU\IvIETER A}4OUNT AMOUNT T]NITS
I,ABOR.NTORY COI{IROL SAI{PI.B DATA
IIOTAL MeTa}s
PERCNT
REC\TRY METHOD
Matrix-- ----: WATER
PREPAILATTON- WORK
A}IALYSIS DATE ORDER #
RBPC}RT
LCS Iot-Sanrp1e#: D5T220000-180 Prep Batch *-
Cadmium 0 . 0400 0 . 03 BB ffig/L 97
Pilutlon Factor: 1
Sel-enium 0.0400 0.0375 mg/L 94
Pilutrion Pactor: 1
I,CS Iot-Sanqrle* : D5l22O0 0 O -26L Prep Batch * -
Silver 0-0500 0.0489 mg/L 98
Pilutlon Factor; 1
Aluminum 2.00 2.00 mg/L L00
Dilutlon Pactor: I
Arsenic 2 - 00 1.89 mg/L 95
Dilution Factor: 1
Barium 2-00 2.O4 mg/L LAz
oifuElon Factor: 1
Chromlurn 0-200 0.195 ng/t, 98
Dllution Factor: 1
Copper 0 . 250 0 .245 rftg/L 98
Pllutlon F&ctor: I
Nickel 0 .500 o - 487 mg/L 97
PiluEion Factor: L
Lead 0.500 o .485 mg/L 97
Pilution FacE,or: 1
Vanadium 0.500 0-492 mg/t 98
Dllut ion Factor r l.
Zinc 0.500 0.464 mg/L 93
Pllutlon Factor: L
Calcium rtg/L 9s
Dilutlon FacEor: 1
(Continued on
: 5255180
sw846 5020
Analysis Time-. :
sw845 6A20
Analyeia Time- - '
: 526526L
s[1I846 6010B
Arralyaie Time-.:
sw84 5 5 0108
furalysis Time. . :
sw845 50108
Analyelo Time. - :
sw846 50r-08
Arralyaia Time. . :
sw846 60108
Analysle TLme. . :
sw846 50108
Analyeis Time. .
=
sw845 50108
Analyeie Time..:
sw84 5 5 0108
Analyels Time. , :
swB46 50108
Analyelo Tlme. , :
SWB4 6 5O 1OB
Arralyeie Time,,:
ae / 23 -09127 I As HKSDA1AD
04 :00
oe / 23 - a9 / 27 / 05 HKSDA1AE
04 :00
09/23-ae/27 / As HKSQWTAU
09:28
0e /23 / 0s HKSQW1AV
23 :46
ae / 23 - oe /27 / as HKsQwlAw
O9 :28
a9 / 23 - oe / 27 / os HKsewlar(
09:28
ae /23-0 e / 27 / 0s HKsQw].Ao
09:28
09 / z3-ae / 27 / os HKsewlAl
09:28
oe / 23 - oe / 27 / os HKsQwlA2
09:28
0e / 23 -09 / 27 / 05 HK5O.W1.A3
09:28
oe /23 -09 / 27 / os HKsQwlA4
09 -.28
09 / 23 - oe / 27 / Os HKSQWIA5
09 :28
sw845 60L08 09/23/os
Arralyeie Time. . : 23 245
next page)
STL Denver
50.0 47 -7 HK5QWlA5
34
Clierrt Lot *.
PARAMETER
Iron
Potaslsiurn
Magnesium
Sodium
Zireonium
NGTE (S) :
. - z D5I07027O
SPTKE MEASURED
A},IOUI{T AMOUNT
1.00 A-964 mg/L
' pilutrlon
50 - 0 5L .4 mg/t'
oi lutl on
50 - 0 49 .5 mg/l'
Di lut ion
50.0 50.0 mg/L
- Dilution
0.500 0.51-9 mglf,
oi lut lon
ITABORAI1f,RY COIITROL SA}TPIJE DATA
TOTAL ITIetaIs
LINITS
PERCNT
REC\MY METHOD
REPORT
sw845 50108
Analyale Time. - :
sw846 601-08
nnalyols Time..:
sw84 5 50I_08
Analysie ?ime. . :
sw845 501_08
Analysis rime.. :
sw845 50108
Analyeis Tlme. . :
Itlatrix.-.------:
PREPARATION-
ANALYSIS DATE
WATER
WORK
ORDER #
HKsQW1A7
HKsQWlA8
HKSQW1.A9
HK5QWT-CA
HKSQWlCC
96
F acE,or r 1
103
Factor r 1
99
FacEor: 1
100
Fact,or: 1
104
Factor: 1
ael2slos
23 :46
oe/23/os
23:{5
ae/n/as
23 :46
ae l23 / os
23 zS6
0e/23/os
23 246
Calculations are pcrlbrnrcd before rouncllng to avoitl round-ofl'crrors in calculated rcsults.
STL Denver
ULTR.rX SPIKE SAI{PI,B SIrAIJIrArION
I1OTAL Metale
Client Iot #...: D5I070270
Date Sarqrl-ed-... 09/06/05 1O:35 Date Received-.= 09/07/Os
REPORT
PERCEMT RECOVERY
PARAMETER RECO\TERY I,IMTTS
RPD
RPD LIMTTS METHOD
Matrix.o..-, : GW
PREPARATION-
AI{ALYSTS DATE
WORK
ORDER #
ldS L,ot-Sanpl.e *: D5I07O27O-002 Frep Batch #-..: 5259425
Mercury 88 (85 - L14) SW845 747OA
87 (85 - r_r_4) 0.33 (0-10) SW846 747AA
Dilution Pactor: 1
Analyola ?lme..:18:39
IICIIE (S} :
09 /2L/ as HJ35N1CC
oe / 2L / os HJ3 5N1"CD
Calculatlol$ are perforuled before roundit4 to avold rouud-off errors [n calculatcd results.
STL Denver 36
C].ierrt Lot fi-..:
Date Sam;r}-ed- - -:
SAI{PIJE
PAIU\METER AMOUMT
D5r070270
09/oG/ os.l-o:35
SPTKE MEASRD
AIvIT AMOTIMT
IIIATRIX SPITG SEUPI,E DATA REPORT
TOTAL }Ietrale
DaEe Received. - ! 09 / a7 / a5
Itlatrix. : GW
PREPARATION- WORK
A}IAI,YSTS DATE ORDER #I]NITS
PERCNT
RECTMY RPD METHOD
MS Iotr-Sarqr1e *: D5I07027A-002 Prep Bat,ch
Mercury
0 - 00500 0.00438 mg/L
0.00500 0.00437 mg/L
. nllutlon Factor:
Arralysis Time. . :
5259425
sw845 7470A-
0 - 33 SW846 7 47 AA
oe/2L/ as HJ35N1CC
a9 lzL/ as HJ35NLCD
#.,.:
88
B7
}UD
tlD
1
18:39
NqfE (s)
=
(hlculatlons arc perl'orrrrctl before rounding to avold rouM-otT errors in calculated results.
STL Denver
UT(IS.IX SPIG S,AIiTPI,E E\IAT TATTOII
IIOTAL Uetala
C].ient IpE #-..: D5f070270
Date Sanryled-- -r o9/09/o5 09:25 Date Received..r og/Lo/os
RBPORT
PERCETIT RECOVERY
RECOVERY I,IMITS
RPD
RPD LIMITS METHOD
Matrrix. . . . - - - - - : WATER
PREPARATION- WORK
ANA],YSIS DATE ORDER #PARAIVIETER
lts lot-Sarp1e
Cadmium
*: D51100153-003 Prep Bat'ch *.
97
99
(ag 110)
(eg 1r.o) 1.4 (o-20)
Dilution Factor: 5
Analysia Tlme-.: 04:40
(az 112 )(az 1L2) 5.8 (o-Zo)
Dilution Factor: 5
Analysie Time. . : 04 :40
;5265180
sw845 5020
sw845 6020
sw84 6 6020
sw845 5020
09 / 23 -09 / 27 / 0s HKAReIC2
a9 / 23 -ae / 27 / as HKAR9I-C3
a9 / 23 -ae /27 / os HKAReIC4
os / 23 - 0e / 27 / 05 HKARelcs
Seleniurn
}IOI'B (S) :
LA2
109
Calculutions are performcd bclbtt rounding to avold round-off crrors ln calculatetl resuks.
STL Denver 38
C1ient l,ot *. . . :
Date Saupled, - -:
SAIvIPLE
PAIU\METER ATIOUNT
IIIATRIX SPIffi SAII{PI,E DATA REPORT
I:OTAL Meta}s
D5r070270
09 / 09 / aS 09 :25 Date Received- . r a9 / 10/05
SPTI(E MEASRD PERCNT
AMT AMOU}iT I,]NITS RECVRY RPD METTIOD
Matrix-- ----: WATER
PREPARATION- WORK
A}IALYSIS DATE ORDER #
trl.S l,ot-Sample #: D5I100L53-003 Prep Batch
Cadrnium
0.0400 0.0391 mg/L
0.0400 0.0396 rfig/L
oilut.lon Factor:
Analysla TLme..;
0.0400 0.04O9 mg/L
0.0400 0-0437 $rg/L
Di lution F'actor:
Analyeis Time..:
5?6518 0
sw845 5020
a -4 sw846 6A2A
sw846 5020
5.8 SW845 5020
ae /23-oe/27 / as HKAR9LCa
ae /23-a9/27 / 05 HKAReIC3
a9 / 23 *oe / 27 / os HKARslc4
oe / 23 - ae / 27 / as Hr(ARelcs
#-
luD
}ID
97
99
5
04:40
LA2
109
5
04:{0
Selenium
NOTE (S} :
ND
ND
(;rlculatior$ are lrcrformcrJ bcfore rouutling tn avold round-off crrors In calculatcrl rcsults.
STL Denver
}IATRIX SPIKE SAUPI'E EIrALTIATION RBPORT
TOTAL Metal s
Client lpt #...: D5I070270
Date Sary>Ied- - - = a9 / a7 105 09:55 Date Received- - : a9 /08/05
RPD
RPD LIIVIITS METHOD
Hatrix. . . - . . . . . ! WATER
PREPAR^A,TION* WORK
Ar{ALYSTS DATE ORDER #
PERCENI
RECO\TERY
RECOVERY
IJTMITSPAIU\METER
It{S tot-Sary>Ie #:
Aluminum 98
101
Arsenic 1-07
l-L2
Barium 95
99
CalcLum
Chromium 85
89
Copper LL7
L22
fron 93
93
Lead 93
97
D5I080243-004 Prep Batrch *-(83 11e)
(es 119) 2.s (O-zsl
Pi 1ut. ion Factor : 5
Rnalyeis Time..: 23:54
L24)
L24) +.r (o-Zsl
Di lut,ion Pactor : 1
Analysis Time..: lA:22
120)
L20) :,9 (o-2s)
Dilution Factor: 1
Analyslo Tirne. . : LO :22
1s3 )1s3) (0-2s)
Di1ut.lon FacLor: 5
AnalysLs Time,.: 23:54
(tt
(7t
L3s)
13s) q.z (o-?sl
DiLution Factor: 1
Analyolo TLme. . :'l,a :22
= 5255261,-
sw845 50108
sw845 60108
sw845 50108
sw846 50108
sw846 60108
sw84 5 5 010E}
SWB45 5O1OB
sw846 501"08
SWB45 5O1OB
sw845 50108
sw845 601-08
sw845 5 010E}
sw845 5010E}
sw845 601-08
sw846 60108
sw845 50108
oe/23-o9/27/Os
ael23-ae/27 /as
HJ6JM1DV
HJ6JM1DW
a9 / 23 - 09 / 25 I 05 HJ5JMLDQ
09 /23 -A9 / 26 / a5 HJsJM1DR
ae / 23-0e / 27 / 0s HJsJM1DT
ae / 23 - a9 127 / Os HJ5JMLDU
(a+
(aa
(gs
(ss
Nc, MSB (aA
NC,MSB (48
oe/23-oe/26/os
ae/23-oe/26/os
HJSJIVIICN
HJSJM1CP
ae/23-ae/27/os
ae/23-ae/27/os
HJSJM1DX
HJSJMIDO
(az
(az
(sz
(sz
L2g',
L29) 4 .6 ( O- 2s)
Dilution Factor: 1
JLrralyeie Tlme. . : LO -.22
1ss )
1ss) 0.70 (o-2s)
Dilut ion Factor r 5
Analyels Tlme..: 23:54
121 )
L21) 3.s (O-2s)
Pilut,ion Factor: 1
Analysis Time..: lo 22
ae/23-oe/27/os
ae/23-oe/27/as
HJ6JM]-A9
HJSJM1CA
oe/23-ae/26/as
ae/23-oe/25/as
HJSJM1CQ
H,J5in{l_cR
(eg
(89
ae / 23 - oe / 27 / os HJ5JMICE
a9 / 23 - 09 / 27 / os HJ5JMLcF
STL Denver
(Continued on. next page)
4A
C].ient I,ot #.
Date SaryIed-
PARAMETER
I*lagnesium
Nickel
Potassium
Silver
Sodium
Vanadium
Zinc
Zirconium
NOrlE (S) :
(ez l-45)
GZ L46) ( a-zsl
Dilution Fact.or: 5
Analysis Time..r 23;54
(ee 120)
(e+ ]-zol 3.2 (0-2s).
Dilution Factor: I
Analyele Tlme. - : 7O t22
(t e l-32 )
(76 ]32) (o-2s)
Dllutlon Factor: 5
lysis Time-.: 23:54
(7S 14L)
(7s 1_41) 4-o (O-2s)
ollutlon Factror: I
Analyeie Time. . t LO 222
(7a 203 )(70 203) (0-40)
Dilution Factorr 5
Analysis TLme, , : 23 t54
( es 120)
(8s ].'za) 3.4 (O-2s)
Dilution FacEor: L
Analyeie Tirne. . : l0 :ZZ
(50 137)
(60 1,3-l) 3.3 (O-251
' Dilution Factor: 1
Analyair Time. . : l0 t22
(80 120)
(80 1_20) 2.1 (o-25)-
ni lut, ion Fact,or : 5
Analysis Tirne. . : 23 :54
II'AI?TX SPIIG SAIIPIIE EITALIIATIOIU REPORT
TOifAL lletal s
: D5 TA7 027 0
: 09/07/oS 09:55 Da.te Receiwed--: a9/08/05
PERCENT RECO\IERY RPD
RECOVERY LIMITS RPD LTMITS METHOD
Matrix-- ----: WATER
PREPARATTON- WORK
ANATYSJq. pArE ORDER #
a9 / 23 -09 / zG / os Hir6'JuLcv
09 / 23 - 09 / 26 / 0s H.rsJrvrlcw
a9 123 - a9 / 27 / as HJ6,Jl,Il-cc
09 / 23-09 /27 / Os HJ6JIYII-CD
09 / 23 - Oe / 26 / Os HJ6JI,n-CT
09 / 23 - 09 / zG / os H,J5,JI'{lcu
09 / 23 - 09 / 27 / Os H.f 6JM1DN
a9 / 23 - a9 / 27 / os HJ6.rI{1Dp
oe / 23 -o9 / 26 / A5 HJSirrYllCX
a9 / 23 - 09 / 26 / os HJ5JM1C0
oe /23*ae /27 / os HJ6JM1CG
09 / 23 - A9 / 27 / 05 HJ5,JM1CH
oe /23-ae /27 / os HJ6JMIcJ
09 / 23 - 09 / 27 / Os H.r6JIvIlCK
09 / 23 -09 / 26 / as HJGJMIcI
09 / 23 - 09 / 26 / A5 H'J6JM1C2
NC, MSB
NC, MSB
SW84 6
sv{84 5
5 0108
50t 0B
Ne, IvISB
NC, MSB
NC, MSB
NC, MSB
83N
87
130
135
90
93
85
8B
t_03
105
sw84 5 5 0108
sw846 50L08
sw845 60108
sw845 60108
sw846 601_08
sw845 60108
sw846 601-08
sw845 50108
sw845 601.08
sw845 50108
sw845 60108
sw846 60108
sw84 6 50108
swB45 60108
Calculetlons are pcrfonncd bcfore roundhg to avoid romd-off crrors ir celculated rxulrs,
N Spiked aoalyrc recovery is outsiJc statcd coltrol limits.
NC The recovery ardlor RPD were nor calculated.
MSB'llc recovery aul l{PD were not calcutatcd }recauqe the sample amount vas gircatcr than four tlmes thc spftc amount.
STL Denver 47
IATRIX SPIKB SAI.IPIJE DATA REFORT
I'IOTAI, Meta1s
Date Received.. r A9/ 08/05
Matrix-- ---.r WATERClient' L'ot *- - -:
Date Saqlled-. . !
SAIUPLE
PARAMETER A}4OIJNT
Dsra7027a
09 / 07 / os 0e:55
SPTI(E MEASRD
AMT AI-IOUlqf
PERCMT
RECVRY RPD METHOD
PREPARATION_ WORK
A}JALYSIS DATE ORDER #I]NITS
ItLS Iot-Saup1e *: D5I080243-004 Prep Batcl. *---: 526526L
Alumirrum
ND 2 .O0 2 -04 wrg/t 98 SW846 60108
ND 2 -OO z.LO *g/t 101- 2 .5 SW845 50108
oilutlon Pactor: 5
Analysis Time.. t 23:54
Arsenic
oe / 23 -os / 25 / as HJ6JM1DQ
09 / 23 - A9 / 26 / A5 H,J6,.IMr-DR
sw846 60108 09 /23 -A9 /2t / oS HJsJM1DT
sw84 5 5 01" 0B 09 123 - 09 / 27 / OS HJS,JIr{1DU
sw84 5 6 0108 Ae / 23 - 09 / 21 / aS HJ6irMlDV
sw84 5 5 01- 08 ae / 23 - a9 / 27 / 05 HJ5JI41DW
swB4 5 6 0108 09 / 23 -Ae / 26 / As rrJsJMlCN
sw84 5 5 0108 09 / 23 - Ae I 26 / A5 HJ5,JI'I1CP
2
2
.l-5 mg/L
.24 mg/L
Dilution Factor:
Analysie Time. - r
2 -a4 mg/L
2 -L2 mg/L
Di lut ion Fact,or :
Analysle Tlme. . :
O .1,7 2 mg/ f,
0 . l,80 mg/t'
oilutlon Factor:
enalysie Time. . :
0.295 rrrglL
o .3oe mg/L
Dllution FacEor:
Rnalysls Tlme. . :
.0s mg/L
.05 ng/L
DiluElon Pactor:
nnalysie Time. . :
4.2
sw845 50108
sw845 5010E}
4.5
sw84 5 6 0108
sw846 50r.08
sw84 6 60L0B
0.70 sw845 50108
107
LL2
1_
lO t22
95
99
1
70 t22
85
89
1
7A 222
Lt7
L22
1
70 t22
93
93
5
23 254
4_l_
3-9
Barium
Calcium
Chromium
Copper
fron
0 _0078
0.0078
0 -13
0 _ t_3
1400
1400
ND
ND
IUD
ND
0 .13
0. L3
2 .04
2.00
2 ,00
2.00
s0 - 0
50 _ 0
0.200
0.200
0.250
0 .250
1.00
1_ 00
1390 mglt
Qualifiers: NC, MSB
143 0 mg/t-,
Qualifiers ; NC, MSB
Dilution Faetor: 5
Analyeig Time..: 23:54
1
1
09 I 23 -ae / 27 / os HJ5ilvl:.Dx
09 / 23 - Ae / 27 / Os HJ5,TM1D0
09 / 23 -A9 /27 / Os HJSJM1Ae
ae /23- 09 / 27 / AS HJSJM1CA
os / 23-a9 / 26 / os HJsJM1CQ
ae / 23 - a9 126 / As HJ6JTU1CR
STL Denver
(Continued on next page)
42
ClienE Iot ff. . . :
Date Sary)Ied.. . l
SAMPI,E
PARAMETER AI,TOI+.IT
Iread
IITiATRIX SPII(B SAUPI,E DATA REtrORT
I1OTAL Flet,a]-s
Date Received, - ! A9 /08/05
lllatrix-- -.-.r WATERD5r A7 A27 A
09/a7/os oe:55
SPTKE ME.A,SRD
AI.IIT AIvTOUNT UNITS
PERCNT
RECV:RY RPD METHOD
PREPAXATION- WORK
AIVALYSIS DATE ORDER #
Magnes ium
NickeI
Potas s ium
ND
ND
530
530
0 .080
o - 080
44A
440
5500
5500
50 - 0
50 ,0
0.500
0.500
50 .0
50 .0
50,0
50.0
IUD
ND
o . 500 0 .455 mg/L 93
0-500 0.483 mg/I' 97
Dllution Factor: 1
Analysls Time. - : L0 -.22
SWB46 6OlOB
3 .5 SWB45 50108
sw84 6 5 0108
sw845 50108
3.2
sw845 50r-08
sw845 60108
4.0
sw845 50108
sw84 5 5 0108
sw845 50108
sw84 6 5 010B
oe / 23 - ae / 27 I as HJ6JMT.CE
09 / 23 - oe / 27 / as HJGJI,IIcF
09 / 23 - 09 / 26 / As HJ6JMICV
oe / 23 - 09 / 26 / As HJSJrvl]-CW
oe / 23 - oe /26 / 05 HJ5fivrLCT
a9 / 23 - 09 / 26 / As HJsJM].cu
oe / 23 -a9 127 / 05 HJ5,JM1DN
ae / 23 - 09 / 27 / 05 HJ6,JM1DP
a9 / 23 - a9 / zG / as HJG.lIvIlcx
oe / 23 - oe / 25 / os HJ6JM1C0
0.0500 0.05s3 mg/L 1-30
0.0500 0. 0580 mg/L L35
nilution Factor: 1
Analysie Time..: 70:22
677 mg/L
Qualifiers: NC, MSB
5 ee mg/L
Qualifiers: NC, MSB
Pilution Factor: 5
analyels Time. .: 23254
a.4e7 N mg/L 83
0 .513 mg/L 87
Dilution Factor: L
Arralysls Time. . : lA 222
Aez mg/L
Qualifiers : NC, MSB
s09 mg/L
Qualifiers : NC, MSB
Dilution Factor: 5
Analyoio Time. . ; 23 :54
5490 mg/L
Qualifiers: NC, MSB
s6s0 mg/L
Qualifierg ; NC, MSB
Ollution Factor: 5
Analyeie Time,.; 23:54
sw84 6 5 0108 09 / 23 -A9 / 27 / A5 HJ6.TrvlLCC
sw84 5 5 0108 Oe / 23 - A9 / 27 / Os HJSJIYI.CD
Silver
Sodium
STL Denver
(Continued on next page)
43
Client L'otr *.
Datre Sarpled -
Ii{ATRIX SPIKE g2gqpr.E DATA REFORT
I1OTAL Dleta]-s
: D5I0 7 027 O
: 09/07/a5 09:55 Date Received..r 09/08/05
llatrri)c-- ----: WATER
SAMPLE SPIIG MEASRD
AMOI,]NT ATVIT AI{OUNT UNITS
PERCNT
REC\MY RPD METHOD
PREPARATION- WORK
AI{ALYSIS DATE ORDER #PARAMETER
Vanadium
Zinc
Zirconium
No1rts (s) :
}TD
I.ID
0.015
0.015
0.021
0 .021-
0 - 500
0 .500
0 - 500
0 _ 500
0 ,500
o ,500
0 .4s1 mg/L
A .466 mg/L
Dilution Factor r
^Analyaie Time. . :
O.443 mg/t-'
a .4s7 mg/T,
Dilution Factor:
nnalysie Time. . :
0 . s34 mg/L
0.546 rll.g/L
Dilution E'act.or:
Analyole TLme.. :
sw845 50108
sw84 5 501.08
sw845 50108
sw845 50108
SWB45 5O1OB
sw846 60r-08
90
93
1
10 -.22
8s
88
1
t0 t22
103
105
5
23 :54
3.4
3.3
2-a
oe / 23 - as / 27 / as HJsJM1CG
a9 / 23 - Os / 27 / As HJEJM1CH
oe / 23 - oe / 27 / as HJSJM1CJ
as l23- oe / 27 / os HJ5,]M1CK
a9 / 23 - 09 / 26 / As HJ6JIvllCl
os / 23 - os iz6 / as HJGJMI:2
Calculatlons arc pcrforrr{ bcforc roundln3 to avold rourd-offcnors in elcu[rtql reslts.
N Spikcd malyrc rcovcry is outsiric statcd srnrol limitc.
NC Thc recovery md/or RPD werc ret calculaed,
MSD'llrc rccovery 0trd Rl'D werc not calcuiaEd bccausc r,lc sample amount ms grealcr dtan fur timx Ulc s?ikc &Dount.
STL Denver 44
STL DENYER
Contsract r
Total Metals Analvsis
COVER PAGE -INORGANIC ANAI,YSrc DATA PACKAGE
IIRS Corgorrtion srro ![o. r D5IO7O27O
tab Codcs STTDEN
gOW No.:
Caee No-:SI.IS No. t
Samp]r-a. ID-
GT[- 7A- 09 0 505
Glrrr-8n'-090505
GTi[- 81.- 090 5O5 MS
oe[- 8n -090505 MsD
Gt,{I- 88- 090 605
IeP l-nt,erclcmcnts corroctrlone appli.ed?
Irab Samplc No.
Dsr 07 027 0 - 00{
Dsr0702-t o - 002
Dsr07027A-002S
D5r07027A-002SD
Dsr070270-003
Wcrc
wcro
Ye g/No rs
ICP background, eorrcctions afplLed?
ff yaa-urrrc raw data gerrcratrrd bcfors
application of baclrgrround. corrGetiong?
Ycg./No YES
Yea/No NO
Coruncnta r
I cartLly that Ehig drta lrrekago ir in oom[rlLa-ca wlth the tor,rrr rad condit:Ioaa of tbo
contsract, both tachnlcally and for couDletcDc'!, for otsher than the conditiong detsai1ed
abwe. RGIcase of t'hc data contrrlnrrd Ln thlg hardcoSry' drta paokagc and La thc eomDutar-rcadrblc drur
aubEittcd oa lloppy dl.akctte hcg brcn authorlzed bry. tlrc IJrboratory lialrlrgcr or thc t![.nag6r'! dccignce, ar
verifLrd bg' the follovlag eignrturc.
stgnaturr , ,.. /(, o, '( t f7-:, [,,,\ .,-
Datr , g/zr lo$__
Nanc:
tlt1e r
Dee Kettule
STL Denver CO1IER PAGE - IN
Data Analyrt
45
ffiSTt
t RS Corporetion
Total Metals Analysis Data Shcet
Lab Nnme:
Lot/SDG Number:
Mntrix:
7o Molsture:
Basls:
Analysls Method:
Unit:
QC Bttch ID:
Sample Allquot:
Dilution Foctor:
STL DE.NVEB
D51070270
WATER
N/4
Wet
00t08
mg,lL
s265261
58. uol
l_
Client Sample ID:
Lab Sample ID:
Lab Workorder:
Date/Time Collected:
Date/Tlme Recelved:
Dete/Tlme Leached:
Datelfime Extracted:
Date/Iime Anrlyzed:
Ingtrument l D:
cw-,$A-090605
p51070270-002
I.IJ36N
09/06/05 I0;35
09/07/05 09:3Q
09/23105 08:00
09/24105 00: l0
EL
CAS No.Analyte Conc.MDL ITL a
742q-90-s Alunrinun'r 0.017 0.0r 7 0. 10 U
7440-70-2 Calcium 52 0.034 0.20
7439-89-6 lron 0.021 0.021 0.10 U
7439-9s-4 Magncsium 45 0^043 0.20
7440-49-7 Potassium 46 4.24 3.0
7440-21-s Sodiurn s00 l.l 5.0
7440-67-7 Zirconium 0.0023 0.00r 6 0.0r5 B
STL Denver
Frr-... I A-t.l..i.. h-r- IFL^-J Dn..L.-l^-1
45
ffisrt
I.IRS Corporntion
Total Metals Analysls llata Sheet
Lab Nrme:
Lot/SDG Nrrmber:
M atrix:
Yo Molsture:
Brsis:
Annlysis Methotl:
Unit:
QC Barch lD:
Sample Allquot:
Dllution Factor:
STL DENVER
n51070270
WATER
N/A
WsI
60108
mg/[.,
s26s?61
sQ.xrL
I
CIIent Samplc ID:
Lab Sample ID:
Lnb Workorder:
DatelTime Collected:
DntelTlme Re*eived:
Date/Tlme Leachcd:
Drte/I'ime Extmcted:
Date/Tlme Analyzed:
lnstrument ID:
QW-8A-09060s,
p5r070270-002
r il.3orY.
09/06/0L-10:35
0e/07/05 ()9:30
09/23105 08:00
09127105 09:33
Ql$
CAS No.Analyte Conc.MDL RL a
7440-38-2 Arsenic 0.0094 0.0044 0.015 B
7M0-39-3 Bariurn 0.I7 ().00070 0.0t 0
7M(W7-3 Chrorniurn 0.0026 0.0026 0.0r 0 IJ
7440-50-8 Copper 0.004s 0.0045 0.010 U
7439-e2-l I.,cad 0.0026 0.0026 0.0030 U
74/,0-02-0 Nickcl 0.0029 0.0012 0.M0 B
7444-224 Silver 0.0028 0.0029 0.010 TJ
74l'0-62-2 Vanadium 0.002s 0.0025 0.01 0 U
7MA-66-6 Zinc 0.0046 0.0045 0.020 B
STL Denver
ffisrt
URS Corporntion
Total Metals Analysis Data Sheet
l,ab Namc:
Lot/SDG Number:
Matrix:
7o Molsture:
Basls:
Anelysis Method:
Unit:
QC Batch ID:
Sarnple Allquot:
Dilrrtion Factor:
STI DENVER
D51070270
WATER
].{/A
Wet
7479A
ruslL
5?5942s
I
Cllent Sample ID:
Lab Sample lD:
Lrb Workorder:
DatdTlme Collected:
Date/Tlme Received:
Date/Tlme Lenched:
Dato/Tlme Extractcd:
DatelTirne Analyred:
In$trument lD:
GW-8A-09061L1
D5t070270-002
HJ3(rN
09/06/05 10:35
Q9/.Qll05 0e:30
09t21105 12:50
tJe/?l/()j I8:37
0r9
CAS No.Analyte Conc.MI}L RL a
7439-c)7-6 Mercury 0,000044 0.000044 0.00020 I.J
STL Denver
D^-- , l--l..nln h..1^ (frl.--t D.---3---l^--t
4B
ffisrt
tlRS Corporation
Total Metals Antlysis Data Sheet
Lab Name:
LoUSDG Number:
Matrix:
oh Moisture:
Btsis:
Annlysis Method:
Unlt:
QC Batclt ID:
Snmple Allquot:
Ililutlon Factor:
[iTL I-rtrNvER
psr07!270
WATER
N/A
$&r
6020
*ty'l*
s265.lffQ
50 rnL
I
Client Sample lD:
Lab Sunple ID:
Lab Work0rder:
Drte/Tlme Collected:
DatelTime Received:
Date/Tlmc Leached:
Date/Time Extracted:
Date/Tlme Analyzed:
Instrument ID:
cw-8A-oe0@5"
D51070270-002
H.r36N
09/06/05 l0:35
09i07/0s 09:30
09/23105 08:(D
Q9r27105 Q4:Q4
0Q4
CAS No.Analytc Conc.MDL RL a
1440-43-L)Cadmium 0.000090 0.000040 0.00 t 0 B
778249-?Selenium 0.00072 0.00033 0.0020 B
STL Denver
I.n..- I l-r.f-.ni.:71 -tn (oL^^t D.---:---l^-t
ffiSTt
URS Corporation
'I'otel Mctals Analysis Data Sheet
Lab Neme:
LoUSDC Number:
Metrh:
o/o Nloisture:
Btsis:
Analysls Method:
Unlt:
QC Butch ID:
Sample Aliquot:
Dllutlon F'actor:
STL DENVER
Dsr070270
WATNR
N/A
et
60t 08
ms&
520$26 I
50 rnl
I
Cllent Sample ID:
Lab Sample ID:
Lab Workorder:
Date/I'ime Collected:
Date/Time Recelved:
Dntc/Tlme Leached:
Date/Tlme Ertracted:
Dnte/Tlme Anrlyzed:
Instrument ID:
GW-8B-09060s
ps1070270-003
HJ365
09/06/05 l2:05
0e/0JlQ5. 0e:30
09i23/05 08;00
09/24105 00: Ll
azr
CAS No.Analyte Conc.MDL RL a
7429-9$-5 Aluminum 0.041 0.01 7 0. l0 B
7M0-74-2 Calcium 170 0.034 0.20
7439-8e-6 lron 0-10 0.021 0.10
7439-9s-4 Magnesium r70 0.M3 0.20
7440-49-1 Potassium I40 0.24 3.0
7M0-23-5 Sodiurn 990 l.l .5.0
7440-67-7 Zirconium 0.0029 0.001 6 0.015 B
STL Denver
F-..r... I A-nl..il.Jr. h^Jr. 9Lant Drr.,3.'^ln-l
50
ffi$Tr
UR.S Corporttion
'fotnl Mctnls Analysis Data Sheet
Lub Name:
LoUSDG Number:
Mstrix:
7o Molsture:
Bnsis:
Analysls Metbod;
Unit:
QC Betch ID:
Snmple Allquot:
Dllution l.'rctor:
STT. DEI\TVER
p5t070?10
,YYATER
NIA
Wct
60108
FlqiI
s2$5261
50 rnL
I
Cllent Sarnple ID:
Lab Sarnple ID:
Lab Workorder:
Date/'f irne Collected :
Datc/Time Received:
Date/Tlme Lenched:
Dntel'finre Extmcted;
Date/Time Anrlyzrd:
lnstrument lD:
Gw-88-09060s
p5t070270-003
HJ365
Q.?0610.5 12:05
09/07/05 09:30
0e/23/05 0tl:01)
09/27105 09:38
016
CAS No.Analyte Conc.MDL RI,a
7440-38-2 Arsenic 0-00s6 0,0044 0.015 B
7440-39-3 Bariurn 0.lE 0.00070 0.010
7MO-47-3 Chromium 0.0026 0.0026 0.010 U
7440-50-8 Coppcr 0.004s 0.004s 0.0t 0 U
7439-97-l Lerd 0.0026 0.0026 0.0030 U
74l,A-A2-0 Nickcl 0.0050 0.0012 0,040 B
7440-224 Silvcr 0.fi)28 0,0028 0_010 U
7440-62-2 Vanadiurn 0.0025 0.002s 0.0r 0 U
74li0-66-6 Zinc 0.0045 0.0045 0.020 U
STL Denver
D^-.-- , ,J--l--^i^ h-l- FL.--t IJ---9---l---z-
ffisrt
URS Corporution
'fottl Metals Analysls Data Sheet
t,rb Narne:
Analysls Method:
Unit:
QC Brtch ID:
Sample Aliquot:
Dllution F-ac-tor:
STL DE',NYIJR
p51070270
wATER
N/A
Wet
7479A
rnglL
s2s94?7
I
Cllent Srmple ID:
Lub Snmple ID:
Lnb Work0rder:
Date/Tlme Collected:
DaterlTlme Recelved:
Date/Tirne Lerched:
Date/Tlme Extracted:
Drrte/Time Anrlyzed:
Instrument ID:
GW-EB-090605
ps1070270-003
tuSfs
0P/00/05 12:05
09107/05 09:30
09121105 12:50
A9/21105 18:42
0t9
CAS No.Anulyte Conc.MDL RL a
7439-97-6 Mercury 0.000044 0.00fi)44 0.00020 U
STL Denver
Drr-* I l-rrl...*r'o DrrJn QLn.>l En.rS.ralattt
52
ffi$Tr
URS Corporatlon
Tottl Metals Annlysis Data Sheet
Lnb lt{rme:
LoUSDG Nurnbcr:
Matrlx:
Yo Molsture:
Basis:
Analysis Method:
Unlt:
QC Brtch lll:
Sample Allquot:
Dilutlon Factor:
STL DENVER
D51070270
WATER
N/A
Wet
6020
ru/L
526s I 80
50 mL
5
Cllent Sample ID:
Lub Stmple ID:
Lab WorkOrder:
DatelTlme Collected:
Date/Tlme Recelved:
Datefl'ime Leached:
Dste/Time Extmcted:
Date/Time Analyzed:
Instmment ID:
GW-8B-090605
nsr070?20-9Q3.
HJ365
09i06/05 I ?:05
0e.&7/05-09;30
09123rc5 qsJ(l
09/27105 M:()7
044
CAS No.Analyte Conc,MDL RL a
744043-9 Cadmium 0.00068 0.00020 0,0050 B
7782^49-2 Selcniurrr 0.0017 0.00 r6 0.0 t0 B
STL Denver
f]n-rr,r I tllrnl*oi* fl,.trt Ql.rr..t Fr'rri.rrrla-l
ffi$rt
URS Corporadon
Total Metals Analysls l)ata Sheet
Lrb Name:
LoUSDC Number:
Matrix:
7o Molsture:
Basls:
Analysls Method:
Unltl
QC Brtch [D;
Sample Aliquot:
Dllution Factor:
STL DENVER
p,5r070270
W
^TER
N/A
-er
60IOB
mgll .
5265261
50 rnl-
lg
CIIent Sample ID:
Lnb Srrnple [D:
Ltb rvYorkorder:
Drte/Ttme Collectcd:
Date/Time Recelved:
Date/Tlme Leached:
Date/Tlme Extracted:
Datc/Tlme Analyzed:
Instmment ID;
GW-7A-090605
psr070270--004
HJ366
09/06/05 l3: l0
09/07/05 09:30
09i23/05 08:00
0ei2z0,l...QI[$,4
0zr
CAS No.Analyte Conc.MDL RL a
7429-90-5 Aluminum 0.17 0. t7 1.0 IJ
7440-70-2 Calcium 650 0.34 ?.4
7439-89-6 Iron 0.2 t 0.2t t.0 U
7439-9s4 Magntxium 2540 0.43 2.0
74/,0-Aq-7 Potassium 2600 2.4 30
7M0-23-5 Sodiunt 22000 ll 50
7440-67 -7 Zirconiurn 0.074 0.0r6 0.rs B
STL Denver 54
ffi$Tt
URS Corporatiou
Total Metals Analysis Datr Sheet
Lab Namo:
LoUSDG Numher:
Matrlx:
Yo Motsture:
Bnsis:
Analysls Method:
Unlt:
QC Batch ID:
Sample Allquot:
Dllution Factor:
S]'L DENVER
D51070170
WAl'ER
NiA
Wst
60I OB
mg/L
5265261
50 mL
5
Client Snmple II):
Lab Srmple ID:
Lalr WorkOrder:
Drtc/Time Collected:
Date/Tlme Recelved:
DrtelTime Leached:
Date/Tlme Bxtrrcted:
Date/Time Antlyzed:
lnstrument ID:
GW-7A-09060s
Ds1070270-004
I lJ3(r6
09/06/05 I 3: I0
09/07/05 09:30
0e/23i05--QE;QO
(t912795. L7:53
016
CAS No.Analyte Conc.MDL RL a
7440-38-2 Arrcnic 0-035 0.022 0.075 B
74p,0-39-3 Barium 0.069 0.0035 0.050
7440-47-3 Chromium 0.0r3 0.0r 3 0.0s0 U
7440-50-8 Coppcr 4.022 4.422 0.050 IJ
7439-92-l Lcsd 0.0r3 0.013 0.0I5 U
7444-02-A Nickel 0.12 0.0058 0.20 B
7440-22-4 Silvet 0.014 0.014 0.0s0 U
7MA-62-2 Vanadium 0.01 2 0.0r 2 0.050 Li
7444-66-6 Zinc 0.045 0.023 0.r0 B
STL Denver
I,,n-* , l-nl.ro3o llnln Qhoril Dnrtirrnlr>nt
55
ffi$TL
URS Corporation
Total Metals Analysls Data Sheet
Leb Name:
LoUSDG Number:
Illatrix:
7o Moisture:
Basls:
Anrlysis Method:
Unlt:
QC Brrtch lD:
Snrnple Aliquot;
Dilution Factor:
f,II, DENVER
D51070270
W4!TFR
N/A
Wet
7470A
mg/L
s25g42s
I
Client Sample ID:
Lrb Sample [D:
Lab rrtirorkorder:
Date/Tlme Collected:
Date/Tlme Recelved:
Date/Tlme L,erched:
Drte/Time Extrscted:
Date/Tlme Analyzed:
Instrument lD:
cw-7A-090.60s
D51070270-004
HJ366
0?/06/!s 13: l0
09/Q7l05 09:30
09121105 l2:5lt
09/?1t05 18:44
019
CAS No,Annlyte (lonc.MDI,RL a
t43L)-97 -6 Mercury 0.000044 0.000044 0.00020 TJ
STL Denver
h'orltln I /na.hrcic Dn)n .Qhool Fnuittnlonl
55
ffisrr
URS Corporation
Total Metds Antlysis Detn Sheet
Lab Nemc:
Lot/SDG Number:
Matrlx:
7o Moisture:
Bnsis:
Analysls Method:
Unlt;
QC Bntch ID:
Sample Allquot:
Dilution Factor:
STI..DENVER
D5t070270
WATER
N/A
Y,st
6020
mg/I,
5265 I 80
I0 mL
l!0
Client Snmple ID:
Lrb Sample ID:
[,ab WorkOrder:
Date/Tlme Collected:
Drte/Time Received:
Date/Tlme Lenched:
Dnte/Time Extrrrcted:
Dete/'fime Anrlyzed:
Instrument ID:
cw-7A-oe060s
ns107020.;0S4
HJ366
09/06/05 13: l0
09/07/05 09:30
091"3/05 08:0-Q
Q9127/05 M:tl
ggJ
CAS No.Analyte Conc-MDL RI,a
744043-e Cadrniurn 0.0089 0.0040 0.10 B
778249-2 Seleniunr 0,045 0.033 0.20 B
STL Denver
STL I)ET{VER
Contract: IIRS Corporation
Total Metals Analysis
-2A-
INITIAI. AT.[D CON TIN UIN G CAL IBITATION VERII-.ICA.I.I ON
Carr !ilo. r
Etgrh Purlty, Spcn
Inorgeuic VcnturGt
IiaI) Codc: STLDEN
InLtsi.a1 Calibratioa Oouroc r
Continuingr Cn1l.bratrLon Sorrrcr r
SIXI ilIO. r D5LA7O27O
I aluninum :l
ConcrntsntLon Ua!.t; r mg/T.
I I I o.sol o.so2l 100.4 | P I
rnalytse
rni.tlal Calibration
Tnre Fourd rsn( 1)
Coat,inuing CrlLbrrtsLon
Tnrc Found e6R ( 1) For:rrd ,6R ( 1)![
A].umLnurn :l 39.99 I 97'-2 49 .x.U 99.2
Calcirrm t I
Ca].cirrm H I 39.{51 gg.6 {9.811 gg - 6
fron Lo I
I r=on Ht I lo.ol 3e.51 I gs.e I so.o I lg,szl ga.z I I
Potasel-rrm J 50.201100.4
esiulr J 19 ,78 1 98 .9
SodLrrm fro I 5.06110L.2
I soatt m Irf I ao.ol 3s.27lse.zl so.ol so.osl1o0.1l I lrl
Zl:c,onium I
( 1) ConBroI Liltl.t,g :Mcrcurlr 80-LZAt Othcr ltlotalr
o.dg6l gg.2
90-110r Cfranl,drr 85-115
STL Denver Forn II (Part 1) IN
58
STL DENI1ER
Total Metals Analysis
-2A-
INITIAL AND CONTIN UING CALIBRATION VERIFICATION
conErast! URS CorDoratlorr
I,ab Code : gtLDEN Caec No.:gl'g ![o. t
rnLtLa]. Calibratl.on Sourcr t
Coutl,nuiag Ce,ll,bratsion ScmroG r
Ill.gh PrrriDy, SDex
InorganLc Vontureg
SDe No. r D5f070274
Concrnt,ratl-on UnLUg 3 mg lL
Analyte
Ial,trLal Calibratlon
T:nr Found BR(I.)
Contrl,nuingr Calibration
Tnre tround ,6R ( 1) Found, tR ( 1)!t
Itl.uninum :l
A1uml-ttum, fl
Calciurn t I
Cal.cium H I
[_;-ronr,o I I I o.5o I I o-s1{lroz-s I p I
rron Hl I
I potasstulnl I I
s8:7
I so,o I I so.z{lroo.s I p I
I urgrrcrLum I I I zo.o I I re-Bgl ee.dlpl
Sodlurn to I
I soAtrrr, rrf I
5.021 100.{ I p
so.oJ e9.631 99.31 I lpl
ZLrcont-um I
Control Limit,s: MrrcurT,80-L2A; Othar MrEals 90-110t Cfranlde 85-115(1)
STL Denver
Fonn II (Part 1) IN
STL DENYER
Corrt,nct r IIRS CorT>oratLon
Total Metals Analysis
-2A-
INITIAL AIID CONTINUING CALTBRATION VERIFICATION
CtrBc No. I glg No.3
Higrh Ptrr1ty, SDax
InorganLc Ventures
Lab Codo r STITDEI{
Initial crll,brltlon Sourco:
Contl-nuing Ca1l,bre.t l,on Sourcc :
sDc NO. r D5I07O27A
Conccntrrt,Loa UnLg; t n9f T.
frtrmtuun:l I I I o.sol I I o.lzsl cs-olp
A]'umtnum :l 50 .0 50.541 101,1
Crl.cLum L l 5.0 4. 80 95. O
Lcercium EI I 5O.O I tg .1Bl 98. { I
.Lna}tr!e
rnitial CrlLbrrt,lon
lfrrrc Found, tR ( 1]
Contlnulng Call.brrtlon
Trnrc Found ,bR ( 1) rourrd, %R ( 1)u
I_1poo r.o I I o.5o I I I o.{e{l eB.BlPI
rron Hi I
I notaselun I I
50 .0tl50,o I
48 .9 97 .8
I I so.{111oo.sIp
I Eega'g_ium I I 20.O I I I 1e.5el eg.llpl
SodLurn lro I
I soatrrr. Hf I I
5.0 5.101 102.0 I P
I I 5o.ol so-zol1o1-s[ I lPl
ZlrconLusr I 0 .50
(1) contro} Linitg:Mcrourlr 80-1201 Othor McEaIs 90-110r Cl,anidc BS-11S
0.{g5l 97.2 I p
STL Denver lom II (Part 1) IN 50
STLDENVER
Total Metals Analysis
-2A.'
INITIAL AND CONTINUING CALIBRATION VERIFICATION
coatrrctsl IIRS Cor:poratl.oa
[d] Codc: STLDEN Cage No.:g^Lg No. r
Initia]" Calt brat,ion €lotrrcc r
Contl-nrrlngr CalLbrrtion Source :
Higrh PurLty, BDex
Inorganl-c Ventsurea
gIlG $[o- : D5I07 027 O
ConccntraElon UnLts z mg/L
lnaI.yte
rnl.tial Cal.ibrrtsLoa
Tr:tre Sorrnd t6R ( 1)
Cont,LnuLng Crll.brrtlon
Trrrc Fotrnd tR ( 1) Found tR ( 1)M
Ietr:nlaun:l I I I o.sol I I o.asll sz.elp-l
A1urninutrl :l
J c.t.l-um t I
50.o 51.231 LOz.5 I P
I I I ' s.ol I I c.zel rs.zlrl
Calcirrrrr II I 50 ,0 49.221 98. {
rron t,o I 0.50 0,495 99-O
rron IIt I 50.0 {9.031 98.1
lpotraarrrnl I I I so.ol I I so.eolrgr.olel
MagaeeLrrrn I 20 .0 19.741 98.-7 I P
Sod.irun Hi I 50 .0 51. 681 103. {
zirconium I o .50 o.487 9'l .4
( 1) Control LLnit,r :Mercury 80-120r Othor !ilrt,aIs 90*110, Cyanidc 85-115
Isoaiunr,ol I I I s.ol I I s.lelrog.zlpl
STL Denver
Form II (Part T} IN
STL DENVER
contsract, : IIRS Corlrorat,l,on
Total Metals Analysis
-7A-
INITIAL AND CONTINUING CALIBRATION \rcRTFICATIO}.I
Craa gl,g No-:
Eigrh Purlty, SI>ax
InorgranLc V(lntrrrGs
r,ab Code : SITLDEDI
rnl-tLaI Calibrr.tlon Sourcc:
Continuing CalLbration Ecnrrco r
gDc $lO. : D5LATA27O
ConccnEratrLon Urribg : mg ft,
.Lrrrlyt,a
-nitial Caltbrat,l-on
Tnre Found e6R( 1)
ContLnulng CrlibrrtLon
T:nro pound esR ( 1) Eorurd r6R ( 1)Dt
I].rrniBus :l 0.252W00.9
CalcLu$r L l 1-99 I gg,5
Iron I,o I 0 ,25e 1101. 6
lpotagqrunl zo.ol zo.azhor.ll I I I I lpllqfgocrrurpl ro.ol gr.sol gs.ol I | | | lpl
Isoat.un r.ol 2.ol z-ozlro1.o I I lpllzirconru+l o.zsl ,_. o.alal ge.el [,..--.-_l ,l_,,..-. I lel
(1) Coutrol L:luitsr ]lersurfz 80-120; Othcr UGErlr 90-110r C!.anldtc 85-115
STL Denver
Form II (Part 1) - IN
62
STL DENVER
Total Metals Analysis
-2A-
INITIAL ATID CONTINUING CALIBRATTON VERIF'ICATION
Contraee: URS CorporrtLoa
LaI) Cod,e 3 STITDEN Crac No. t S.B"SI No. :
fnl,tial CrlLbratrLon Eourcr r
Contiuuing Cal-Lbratiou Source:
HLgrh hrrlty, SI>ex
Inorgtttic Venture'
SDC [IO- : D5I07O27O
Corecrnt,rrt,lon Unl,t,s t tnrf,llt
Analyto
rnl-tial Cal.ibntLon
Trrre fourrd t,R ( 1l
ContinutnEr Calibrauion
Ernrc Forrnd %R ( 1) Found, t,R ( 1)M
Il,Lrrninrun :l
Ltum'inrm :l
Celcium L I 5.0{l 100.8
lcarcrunxl - lo.ol sa...e_ol gz.zl so.ol- cg.sal gg.zJ I lpl[zroap I I I I o.sol I I o.511lroz.z lp I
I rron rrl-_ I ao . ol 39.o1I 9?-sI so.oI tg.ool 98.1I fpl
I pot."riurn I I 50.o I I so.Lzl roa.z lp I
I n goeaiun! I I I 2o,ol I rs.64l gB.zlpl
I soaiq{n r,o I I I 5,0 I 5.oolrol-.z l p I
Sodl,um ni I
lziroont-rry, 1 I I o.5o I o.{941 98.B I P I
(1) control Liruits: l.tcr6rrx' 80-1201 oth6r lrotal8 90-110r cyanl.dc 85-115
L
STL Denver
For:n ff (Part 1) r f![
STL DENVER
Contrractr: t RS CorporaEl.on
Total Metals Analvsis
-2A-
IN ITIAL AI{D CONTINUING CALIBRATION \TERIF'ICATION
Cagg No. l SrS No. r
nigrh Purity, spax
InorgrnJ.c Venturoa
Lib Coder STLDEN
rnitial Cr1i.bratrton Sourcr r
Contlnuing Cal.lbratl,on Sourcar
SDs DIo. r D5TO7 O27 A
Cou.crntra,tLon Unl,E g : mg lL
InaI-yte
InLtLal CalLbratioa
Trrua fouDd e6R ( 1)
Continulng Celt brrt,ion
Tnre Fouad t6R ( 1) Forrnd %R ( 1)u
Alum{num :J
AlumLnusr :l
I careium r, I
0 .50
L8.2 96. 5
0 .518 103.6
s-oll roo.B I P I
50.oI I I s.ol I
[e.rci.rrrr_xl I I I so. o l ce,19l eB.{ l lpl
Irronr.o I I I I o.sol I o.slol 102.0 I p I
I r=qq Hl- | I 5o.ol cB.6dl 92.31 Irl
Potarrirrm I
Magrneeiu$ I
Sodl-uur ro I
Iqodr.utrr Hi I I
50 .0
20,0
5.0
50.o I {g.g5l gg.? I
50.05 100 .1
19.5?97 .8
5.06 101.2
lpl
J zi=oonlum| I o.5o I I I o.deol ss.zlpl
( 1) Control LLruLta r Mcrcrrry 80-120t Othcr Urta1s 90-110r Cl.anLdr 85-115
STL Denver
Forra If (Part 1) IN
54
STLDENVER
Total Metals Analvsis
-2A.-
INITIAL AI{D CONI'INUING CALIBRATION VERIT'ICATION
cootrBctr [IRS, Cor?oratl-on
Lab Codet STTDEN Cagc No.:gAA No. r
rnitial Callbrrtion Source :
ContiDul-ng Calibretion Sourcc:
Higrh hrrLty, EDex
fnorganie Vanturaa
sDo No. r D5f 070270
ConocntraElon Units : ng/f,
.Lrralfrte
lnit,irl CrltbratLon
Trrrc Forrnd t,R ( t.)
Cont,Lnuingr Calibration
Tnrc Found, xR ( 1) Sound tR (1)M
I efuninunr :l tll o,so I I o.5o9l 101.8 | e I
lluminum :l
Calcl.um I, I
Calciurn H I
Iron t,o I
Iron IIL l
J rot.rsiunl
50.0 {9.{9g .8
5.0 {.85 97 .O
50. 0 {8-57 97 .1
o. 50 0 .502 100.{
50.0 49.171 96-3
I I I so.ol I I so-sslror.alrl
luasneriuTl I | | .-_-qo.ol I I rg.erl ge-olel
Sodf-um to I 5,191 103,6
SodLum IIi I 50.0 49,511 99 .2
Ziroonl-un I 0.50 a -492 98.{
( 1) Control LLnit,g r Mrrcury 80-120; Other Uctalt 90-110; Ctrenlde 85-115
STL Denver Fom fI (Part 1) - IN
STL DENYER
ConEract: IIRS Corlrontion
Total Metels Analvsis
-2A-
TNITIAL AND CONTINUING CALIBRATION VERTTICATION
Care No. r g.LS No. r
Htgrh Ptrrity, spax
Inorganic Vanturcs
Lab Codc r $TI,DEN
rnl.tl-a]. Calibratlon Source :
Continrriug CallbnEion Sourcs :
SDO NO.: D5IO7O27O
ConccnEntsLon tlnLtg t \g lL
AlumLrrun :l 0 .50
Al-umLlrr[r ;J 50. 0
Calol,urn t I 5.0
Calciusr H I 50. o
L-=rorLo I I I I o.sol
0,502 100,{
49.{9g .8
l-74 94 .8
&7.4 9l,g
I I o.4egl ee.6lPl
Arrrl.ytc
InitLal Ca1l,brat,ion
Truc Found e6R ( 1)
ContLnulng CalibratLon
Trrrc Found" e6R ( 1) Found tGR ( 1)![
Lrror. Hl- I I I I so.ol a7,zel ed,6l I lPl
I notarriurnl I I I so.oI I I sa.?zlrol.sf Pl
I uagne;Luml I rl 20.o I I I le-Gol ea-olPl
I soaru+ rol I ll 5.O I s.1af rol.s I n I
Sod.Lrrrn IIf I
I ztrconium! I
50. o
I o.so I
{g.o 98.2
o.cBal 9?.51 P I
(1) ConErol Limltsr MercurY 80-1201 othar Metalg 90-110; Crranidc gs-115
STL Denver Form fI (Prrts 1) - IN
65
STL DETVVER
Total Metals Analvsls
-2L-
IMTIAL AND CONTINUTN G CALTBRATION VERI}ICATION
qontractsB IIRS Corporaeioa
Lrb Codc s STLDEN Carr No. t
rnitia]. CalLbratsl.on Sorrrcc r
ContLnulngr CllLbratlon Sourcer
High Purity, S1lcx
Inorgrnic Vcnturcl
gDc NO- : D5I07AZ7A
Concentrrtion Unitsr t nrgl[)
llurnl.nurn :l
lJ-u:aLrlutrr :l 49, 601 99 .2
lcatctunr,l I I I s.ol I I l.osl st.alrl
Iron Lo I
rron Hi I
Magrrrcrium I
d6.7gl 93.6
0.49{l 98.81 P
19.501 98.0 I p
enalyLc
lnLtt-rt Callbratioa
Trrr Found tn (1)
Contl,nul,ng CelJ.bratslorr
Tnrc f,ound }sR ( 1) Forrnd ,GR ( 1)M
lcetciumnl I I I so.ol rz.orl cl.rl I lpl
lroreaaturl I I I so.ol I I so.sslror.zlrl
lsoaiumurl I I I so.ol tg.:-zl ge.zl I lpllsoaruu r.ol ,, I .l I s.o l ._ I I s.gglros.e ln llsoaiunsrl I I I so.ol.,.. lg.rzl ge.zl I lpl
ZLrconium I a.4g3l 96.6lP
(t) Control Linltg:Marctrtlr 80-120t Othcr l{atalg 90-110r CYanLdr 85-115
STL Denver Fom II (Prrt 1) - rN
STL DENVER
Contracu: IIRS Cou?oratLon
Total Metals Analysis
_2A_
INITIAL Ah[D CONTINUING CALIBRATION \MRIFICATION
Ce;c No.:ALA No. r
HLgh Prrrity, Sprrx
InorganLc Venturea
r.ab Code : STLDEN
fnLtLal Call,bration Sourea r
Contl.nuln0r Celj.bratl-on [Icvurce r
SDc No,: DSI07O27A
Conccntrratrlon UaLtr ; mg lt
lnalyBc
rnLtLa]. CallbntLon
Tnre Forrnd ,6R( 1)
Conb inuingr CalLbrrELou
trnrc Found esR ( 1) Pound e6R ( 1)M
Alrrml.aum I o,25 0,257 1102.8
I carciun r,l z.ol r.sal gg.o I I I I I lrl
Iron Lo I a.2 0.250 1100.0
PotaseLun I 20. o 2A .19 1101.0
IMagnaelrun| ro.ol g.tg! 9c.9 I trtl
Sodtirrm Iro I 2.0 2 .03 1101.5
I gi=.oorqql o .251 o-2raI e6.8 I rll
(X) control Linite:Mcrcury 80-120r Othor McEaIg 90-1101 CYanl,dc 85-115
STL Denver
Forn II (Eart 1) III
58
STL DENVER
Total Metals Analysis
-24-
INITIAL AND CONTINUING CALIBRATION VERIFICATION
cootracr! IlRs corporat:Lon
Lab Codas STLDEN Cagc No. t S.LS No. r
InLtLr]. Ca}ibratLon Source;
Continulng Ca]-ibntl-on Source r
Inorganl,c Vantrurer
Hlgrb hrrity, Spcx
sDo No. r D5I070270
Conccntratl.on Uaits z rrg/L
lnsLfrt,c
fnLti-al Crl.l-lrre.t,lon
Trmc Foured %R( 1)
Coatinuing Crl'Lbrnt,ion
Tnre D'ound e6R ( 1) Found 96R ( 1)M
Arsonio I a .2{9 I 99. 5 1.0071 100.7 1. Olrl I 101.4 I P
Beriurn I 0.252 1100.8 0.5061 101.2 0.5051 101,0 I p
CbromLum I 0 .248 1 99 ,2 0.5031 100.5 0-50{l 100.8 I p
I copp.r I o.zsl o. a t2l 96.8 I o. so I o,4981 99.61 o.5oollOO.olBl
a.2{5 I 98-0 0.50{l 100.8 0.5071 101.{ I p
I Nrctcr - I o.zsl o.zsz lroo.e I o.so I. o.sozl ror-e I o.sosl ror.o I e I
SLlvcr I 0.2{1 I 96. {0 .4911 98 .2 o-{9{I 98-8 I P
Ivan.d,l-um I o,z5l o.2{8 I gg .2 I 0, so l o.50cl 10o.8 J o, soc l loo. g l p l
0.244 I 97 .6
( 1) Control Liurit,g r Mcrcury 80-1?01 Othrr ldotala 90-1101 Cyanldr 85-115
0.5121 102,4 0.50{l 100,8 I P
STL Denver
Forar II (Part 1) fN
STL DENVER
Contsnct, t
Lab codr r
Total Metals Analysis
aA-
INITIAL AIYD CONTINUING CAI,IBRATION VERIFTCATION
IIRS Corlrorrtslon
STI,DEN Caec No.:SJLII No. i
Inorgrenl.c Vcaturoa
SDc NO, : D5lO702'lO
Initia]" Calibntion Sourcc r
Contl,nul"ng Calibrat,Lon Bource :HiErh PurLty, Spax
Coneeutratioa Uaits r ng /t'
Ana1ytr
rnLtial CalLbntsi.ou
Tnr Forrnd ,6R ( 1)
Conti.nul-ng CalLbratlon
Tnre Found tn (1) Found rg,R ( f )u
Argenic I 1.00 1.0071 100,7 1.0L21101.2
lgarrurt I ,1.. I I q.r,:gl o.sozl ror.rl o.srolroz.g.l,pJ
[cnrqqt.r- [ I I I o.sol o.rgsl 99-01 0.s0ol10o-olpl
lcopp.= [ I I o,5oI o.{991 99.81 0.5ozl1o1.tlel
lr.era I ,, | | I o.sol o.sorl roo.zl o.soslror.olBl
lrvtokc]. I I I I o.5o I 0. soil 1oo. a I 0. sog I 101.0 I p I
I stt.r.= I I I o.so I o.{B?l 9z-{l o.{931 98.6lPl
va.nrdlum I
Lslo. I I II o .50 o.5001 100.0 0.503 I 100. 6
o.5o I o.{B2f 96.{ I o.{BTl 9?.{ I P I
( 1) Control r.initg r Morcurfz BO-LZAt Othrr Mete1a 90-110t eyanlde 85-115
STL Denver fom II (Part 1) - IN
70
STL DENYER
Contrect r
Lrb Coder
Total Metals Analysis
-2A-
INITIAL AI{D CON'I'INUING CALIBRATION VERIF'ICATION
URS CorporaElon
SrLDEN Care Dilo, t sJtS No, :
Inorgrnio Vanturaa
gDO slO. s DsI0?0270
fnLtiaL Cr].l"bratrLon Sourca t
Contl,nu:Lng CalibntLon Source :III-gh Purl,ty, Sprrx
Couccnt'rlt,lon Ualtrg z mg lL
lnrlytc
fnLtial Ca]-l-bntlon
Tme Found e6R(1)
ContinuLag Crlt bnt,lon
Trrrc Found esg ( 1) Found e6R ( 1)M
lelsenic I | ,. I I ,r.oo-l r.oozlroo.zl r.ooolroo.olpl
BarLun I 0.51{l 102.8 o.52{l 104.8 I P
J ctrroml-run I I I I o-so I o.rgsl gs.ol o.ragl gz.el p I
lcopper I | ,- I I o.sol o.srol roz.ol o.srslrot.olpl
0 .50{l 100 .8 o-5031 100.5 I P
lulctcr I ,, | | | --o.sol o.sosl ror.ol o.lggl gg.slpl
Sl- I-rrcr I 0.4951 gg. o o.{921 98.{ I p
Vanadirrm I o.5001 100 - 0 o-4961 99-2 I P
0. {851 97 .A 0.4581 93.5 [ P
( 1) Cont,ro1 Ll,mitg:Merctrrlr 80-1201 Othrr MeEelg 90-110; CYanl"de 85-115
STL Denver
Forsr If (Prrt 1) - IN
7L
STL DENYER
Contract r [IRS CorDoration
Total Metals Analvsis
_24_
INITIAI, AND CONTINUING CAI,IRRATION Vtr,IUT'ICATION
Crea No.:AAg No. r
T{IIgT
Ultra Scicntific
Lab Codc: STLDEN
fnltial. Crll"bration Eouroc r
Coat,l,nuing Ca]-LbratLon gorrroc r
gDO NO.: D5IO7O27O
Conccntration Unl,tr t m{,l[t
nnr1fftc
Initill Calj,bration
Trnrl Found t,R ( 1)
ContinuLngr CeI ibrrtion
Trrre f,ound ?6,R ( 1 ) Iroulld, e5n ( 1)M
lq"r.''-y I o.oozrzzl,, o-oozzrz lror.q I o.oosooo I o.oongool gs.+ I o.oolgTll gs.: ls.vl
(1) eotrtrol r,lnlt,ar Mercurar 8O-120r Other UeEeIa 9O-110; C!'rnidc g5-115
STL Denver For:n II ( Part 1) IN 72
STL DETIVER
Total Metals Analvsis
-2A-
INITIAI. AM) CON TIN UING CALIBRATION VERIF'ICATION
Coatracts: IIRB Corlpratj.on
r-'ab Codc: STLDEN Case No.:
NIST
gAS No. r
fnitl-al" Crl-i"bratl-on s€/urec I
ContLnuLng CaLj-bratLon Sorrrcc r Ultra Sclenttfio
SDG NO. : D5f 070270
Conocntratsioa Unl.tr t ngft'
.Lrrrlyt,c
rnl.ttal Calibratlou
Tnrr Found t,R ( 1)
Continuiog Crlt brrt,Lon
Trrrc Fou.nd t,R ( 1) Found tn ( 1)M
Mcrcury o.005000 0 . 0 44924
( 1) Control r,imlte:MereutY 80-L20t Othor uet,rl8 90-110; CYanide 85-115
0.004936
STL Denver Forzr II (Parts 1) fN
STL DEIWER
Contract 3 IIRS Cor:>oretion
Total Metals Analvsis
-2A-
INITIAL AND CONTINUING CAI,IBRATION VERIFTCATTON
Carr Ng, t gl.g trlo. t
IIIgT
Ultra Scl-antLfLc
IJab Codc r STfTDEDI
InLti.ll. Ca1ibnt,i.on Source r
Contl,nuingr Ca1ibrat,ion Eouree :
sl)o No. r D5f 07 A?7 O
Conecnt,ration UnLtra t mglt'
lnalytc
InitirL call-bration
Tnr Found, ,GR ( 1)
Continuing CrLLbre.tLon
Trnrc f,ound. e6R ( 1 ) I|ound ft,R ( 1)M
Mcrorrry 0.005000 o.oo{95
Control Linj-te r Morcurar 80-1201 Othrr Meta1u 90-110, CIratrldt 85-115
0 , 0049 59
(1)
STL Denver For:n II (Part 1) IN 74
STL DENVER
Total Metals Analvsis
-24-
INITIAL AND CONTINUING CALIBRATION YERIT'ICATION
Contract: (IRS Co::pont:lon
Lab Codc3 STLDEN Ca;c No. t Slg No. l
rnit.iaL ca].l.brariorl Bource :
ConcinuLng Calibratlon Eource:
HLgh Purlty
rnorganLo Venturcs
SDs NO.: DSI07O?74
ConcrntntsLon UnLtss : mg lL
I caarri,r*o.oaol o.ot13 lros.z I o.oso I o.osorl 1o0.2 I o.osool roo.o I u I
Analyt,c
rni.tJ.a} CalibratLou
Truc Found tR ( 1)
Cont,lnuLng CrI LbratLou
Tnre For:nd ,6R ( 1) Found e6R ( 1)M
I sercnium I o. olol o. o4o1 lroo.2 I o. o5o I o.oso3l t.oo-51 o.o495l g9.olt'll
( 1) Control Lirrlt,s :Merqrry 80-L20t Obher trretals 90-1101 eranldc 85-115
STL Denver
Fo:mr II (Part 1) IN
STL DENVER
Contract t IIRS Corporetion
Totnl Metals Analvsis
-2A-
INITIAL AND CONTINUING CALIBITATION YERIFICATION
Cage No.:SA8 No. l
ELgrh hrrl,ty
Inorgrnic Venturea
Lab Coda t STITDEDI
InitLa]. Ca]'ibrntLon $ource:
ContLnuing CallbratLon Eouroe r
sDG No, g D5 T07 027 A
Conc;ntraEion tfnl,ts 3 ng/f,
Analyt,c
rnLtla1 CalibrrELon
Tme Found es3 ( 1)
Continuiug Crl.Lbrrt,lon
Trrrc Found %R ( 1) Found %R( 1)M
Crdmlum 0.050 0.0501 100 .2 0.05L2 102 -4
Strlanrl-rrrn
(1) Contro1 Llnitgr Mlrcury 80-120; Othcr Mot,alr 90-110r Cyanidr 85-115
STL Denver
Forcur ff (Part 1) IN
75
STL DENVER
Total Metals Analvsis
'2A.-
INITIAI, AND CONTINUING CALIBRATION VERIFICATION
coDtractsr IIRS Corporatioa
LrI, Cod,o 3 BTITDEN Crae No. r gf,S lb- l
frritial Crll,bratrLon Sourcc r
Continuing CaU.bration gourec r
Ht gh ttrrluy
InorganLe Vcntureg
sDo No. r D5r070270
I Cr.Ornium I
Couccnt.retLon tlaLt.e z roglL
I I o.osol o. osool 101.4 I o. o5o1l ro o.z l u I
.Lrrelytc
rnl-t,l-a]- CalibratsLon
Tnrc f,ound e6R (1)
Contl.nuing Calibration
fnrc Found, tsR (1) Found tR (1)u
I serrnium I I o, o5o I o. osoil 100.2 I o. oso5l 101.0 I M I
( 1) ConEroI Limit,s r Mucury 80-120,. Other Metalt 90-110; Cfranido 85-115
STL Denver Fom II (Part U IN
STL DENYER
Contrrct s [IIlSl CoqporatLon
Total Metals Analvsis
-2A-
INITIAI, AND CONTIN T}ING CALIBRATION \TERIFICATION
Cace No. r SI^S Ho.:
Hlgh Purity
InorganLe Venturea
Lab Codrrr STLDEN
rnl.tLa]' Calibrrt Lon Sourcc :
ContrLnuing CrU-bration Slorrrcc r
ADO NO. : D5IO7 O27A
Concentratl.on UnLtg 3 mglL
Cadnl.rrm I 0.050 0,04951 99,01 0.05001100.0 1 t1
Iseroarum [ | I | ,o.g,s.gl o.osodroo-al o.osoalror.olMl
(1) coatror r,inLtg: llcrcury 80-120; oEhcr ttGtal3 90-110r ctranldc 85-115
lnalytc
rnitia]. crli.bratrion
Truc [ound BR(1)
Continul-ng CelLbratton
Tnre Found t,R ( 1) Found tn ( 1)M
STL Denver lom II (Part, 1) IN
7B
STL DENVER
Total Metals Analysis
-78-
CRDL STANDARD FORAAAT.ID ICP
Coatre.otr tR,S CorporltLon
reb Coda: STLDEN
.[lL CRIrIr Standlrrd Eource :
ICP CRDfr St,andard Source :
Cr;c No.:9f,8 No. t sDc No,: D5IO7OZ7O
Inorganic Vonturoa
Conccatntion Unltg t rrlll;l
l,lurninrrm I
C:BDL Bt,andard for fCP
rrrl,tLrl. rLnal,
Trnre Found tR Found e6R
CRDL Btarrdard for AA
Tnra Pound. ftR
0.100 I 100.0
lcarerunr.l .. I - I ll o.zol o.rgzl se.sl I IIron lro I 0,0330 I 110. O
Potasaluml
Mrgmc;Lurn I
SodLum LoI
1.06 I 105. O
0. 18X. I 90 .5
1,02 1 102.0
lztrcoa.tuml I I ll o.oosl o.oos{l ros.ol I I
STL Denver
So:m II (Part 2) IN
STL DENVER
Total Metals Analvsis
-28-
CIIDL STAI\DARI} FOR AA AND ICPo
Con
Lrb
tract: IIRS Corarorat,Lon
eoder STLDEN
r.L CRDL Standrrdl Source I
ICP CRDIJ gtandard Soursc r
Caaa ilIo - :SAg No. r sDG No. : D5lO7A27A
Inorganl-c Vont,urer
CRDL Et,rndlrd tor .lJt
Tnre XFound tER
CRDIr Standard for fCP
rnLtial Final
Tnre found t$R Fotrnd BR
J nrumrnun I I
Couccntratlon UrrLt g'- ng l L
o-10 I 0.1131 rrs.ol
Calciun' Ir l
I rron r,9 I I I ll o.o3ol
o.22gl 114.5
o - 03{ol rr3 .3 I
Potsaaat rrnl
MrgrnGalunl
Sodlun tol
J ziroontuml I
1.1{ I 11{.0
0.192 I 95.0
1.12 I r.12.0
o, oos I o, o058 l rr5. o l
STL Denver
Form, If (Pert 2l ts IN
80
STL DENVER
Total Metals Antlysis
-2R,-
CRDL STANDARD FOR AAAI{D ICP
CoatrecE r IIRS Coriporetion
IraI) Codr r STLDEN
.tt CRDIr Standrrd Source :
fCP CRD[, Standerd Sqtrrce:
Caac No-:EIAA No. t
Higrh PurLty, 8pcx, Inorganic VantrrrGa
SDGI No. r D5f 07 427 O
ConoanEration Unitg t mglt
CRDL Standard for fCP
rnLtl,al Fina].
Found ttrt Forrnd,
CRDfr Standrrd for .Le
Tnre xlound,
Arronl,c I 0-010 o.01{11 1{1. O
BarLrrn I o - 0050 0 .005161 Lo3 .2
leurorniuml | ,. I ll o..o+ol o.orul rrr.ol I I
I coppar I I I I o. o1o I o. 01061 106. o I
I r,ead I I ll o.oo3ol o-oorgel ss.sl I I
Nickal I
LE$'r= I I I
0.010 0.0120 I 120. O
ll o.o1ol o.ooe3l g3.ol
Va.ned.iurn I 0,010 0 - 0108 I 109. o
lzro" I I I ll o.ozol -.9:ozsslrrs-sl I I
STL Denver
Fom rI (ParE 2) M
STL DETVVER
Total Metals Anslvsis
-28-
CRDL S'TANDARD FOR A 4. A}ID ICPO
Cont ract r IIRS Cor:poratf,on
I,ab Codc: STTDEN
A.n CRDL 9Eandard Sourca r
IeIl CRDL EErndtrd Eourec:
Cage No-:
Ultra ScLcntLfl.c
SIS I[o. 3 sDe No-: D5I07O27O
Conocntration Unitr : eg /L
lr,rcrcurlr. I o.oooaoo! o.ooorgd gz-oll I I I I
CRDL Standard for .f,Jl CRDfr Standard lor fCP
rnl,ti-a1 Flnal
Tnrt Eouad tR Fouad
STL Denver
Form rI (Part 2) IN
B2
STL DENVER
Total Mctals Analvsis
-2B.-
CRDL STANDARD F'OR AAAND ICP
Contract: IIRS CorporatLon
IraL Codc r SBITDEII
.f,.n CRDL Btandard Souroc r
ICP CRDL Stsandard, Sourcer
Clnc No.:glg fllo - t gDO No.: D5I07O27A
Inorgani-c Venturoa
Conccntration Unitsr z mglL
I I o.oor.of o-oolool 10o-oI
CRDL Standard, for .nf,
Trnrc Found
CRDIr Standard for ICP
rni.tLrl FLnr,I'
Tnrc Found tR Found
Scl.rrnLr:n I 0.0010 o.00091 91. O
STL Denver
Form II (Pnrt 2 ) IN
ffisrr
URS Corporation
Total Metals Analysis Date Sheet
I-,ab Name:
Lot/SDG Nurnber:
Matrix:
o/o Moisture:
Bnsis:
Annlysis Method:
Unlt:
QC Butch ID:
Sample Aliquot:
Dilution Frctor:
sTI nENVER
Dst070270
WATEIT
]IEI
60108
mCtr
526s?6t
so nL
l_
Cllent Sample ID:
Lab Sample lD:
Lrb Work0rdcr:
Dste/Tlme Collectedi
Date/Tlrne Rccelved:
Date/Tlmo Lenched:
Dtte/Tlme Extrrcted:
Date/I'Irne Analyzed:
lnstrurnent ID:
Dst220000-261B
r rKsQw
09/23105 08:00
091?3/.05 T:at
E!.
CAS No.Anrlyte (-'0uc,MDL RL a
1429-90-s Aluminum 0.0t7 0.017 0.r0 U
7439-89-6 Ircm 0.021 0.021 0. l0 LJ
7439-95-4 Magne$um 0.043 0.043 0.20 L]
7440-09-7 Putassiurn 4.24 a-24 3-0 U
7M0-23-5 Sodiunr I.l t.t 5-0 U
7440-67-7 Zirconium 0.0016 0.0016 0.01s TJ
7440-70-2 Calcium 0.034 0.034 0.20 U
STL Denver 84
ffisrt
URS Corporation
I'otel Mctnls Analysls Data Sheet
Lub Name:
Lot/SDG Number:
M atrix:
"h Molsture:
Basis:
Analysls Method:
lJnlt:
QC Batch ID:
Sarnple Aliquot:
llilutlon Fsctor:
srl r)F'NyER
psr070?70
WATER
Wct
6Qton
mgll"
5265^61
50 mL
I
Client Sample lD:
[.,ub Sample ID:
Lrb Work0rder:
Date/Tlme Collected:
Drte/Tlme Recelved:
Date/Tfune Lenched:
Date/Tlmc Ertrocted:
Date/Tlme Analyzed:
lnstrument ID:
D5I220000-26t B
lrKsQw
Q9/23/05..08;Q0
09/27105 Q9:23
016
CAS No-Anrlyte Conc.MDL RL a
7440-38-2 Arscnic 0.0044 0.0044 0.0ts U
7439-92-l l*ad 0.0026 0.0026 0.0030 IJ
7440-39-3 Bariurn 0.00070 0.00070 0.010 U
1440-a2-a Nickel 0,00t 2 0.0012 0.M0 U
744U2?4 Silver 0"0028 0,0028 0.0r0 LJ
7440-62-2 Vanadium 0.0025 0.0025 0.010 U
7M0-66-6 Zinc 0.0045 0.0045 0.020 U
744047-3 Chromiurn 0.0026 0.0026 0.010 L'
7440-50-8 Coppcr 0.0045 0.0045 0.010 Li
STL Denver
ffisrt
URS Corporadon
Totnl Metals Analysis Drta Sheet
[,ab Name:
Lot/SDG Nurnber:
Matrlx:
% Moisture:
Basls:
Analysls Method:
Unlt:
QC Bntch ID:
Sample Aliquot:
Dllution Ftctor:
srL pF.Nv-EB
p.51070270
WATER
-WiI
74754
p8/L
52s9425
1
Client Sarnple ID:
Lab Sample ID:
l,ab r#ork0rder:
Date/Tirne Collerted:
Date/Tlme Recelved:
Date/Tkne Lerched:
Date/Tlmc Extracted:
Date/Time Analyzed:
Instrument ID:
pst r 60000-42s8
HKVN3
0e/?l/05, .le.sj)
0q/21l05 I 8:05
019
CAS No,Anrlyte Conc.Illt]L RL 0
7439-974 Mcrcury 0.000M4 0.000()44 0.00020 U
STL Denver
D^-- 2 D-",- Dl--r- D^-..:-.nln--!
85
ffi$Tt
URS Corporation
Total Metals Analysls Drta
Lab Neme:
LoUSllG Number:
Matrlx:
7o Moisture:
Basis:
Analysis Metlrod:
Unit:
QC Brtch ID:
Sanrple Aliquot:
Dllutlon F'tctor:
STL DENVER
D5t070270
WATER
wst
602{l^
mg/L
526s I 80
50 mL
t
Sheet
Cllent Semple ID:
Lnb Sample It):
Lab Work0rder:
Drte/Tlme Collected:
Dnte/Ttme Received:
Date/Tlme Leached:
Date/Tlme Ertracted:
Date/Tirne Antlyzed:
Instrument ID:
Dst220000-1808
HKSDA
09/23105 08;00
09127/05 03:56
004
CAS No-Analyte Conc-MDL RL 0
7782-49-?Selcnium 0.00033 0.00033 0.0020 U
744443-q Cadrnium 0,000040 0.000040 0.00t 0 tJ
STL Denver
D^----- 2 ')--- t>r---r-
STL DENVER
Total Metals Analysis
-3-
BI,ANKS
Corrt.ract I IIRS Corporation
STLDEN Caac No.3 SAg No- :SDO NO. r D5I07 O270
PreDarrtsiou Blank MrtrLx ( eoil'/wetscr) r
Preparation Bhnk Concent,re,tJ,on Unitc lmg It or nglkg) :tltcr lt
CoauLuulng Calibretlon
Bl'ank (rylt l
1czc3c
PreDaration
Blank
Inl-tsi-aI
Cllib -
BlLnk
(mslr)
.l,lrrrrinrrm I-ro I
Celcirrm Lo
fron Lo
PotaEsl-um
MagmecLun
Sod,Lum to
ZLrconLum 0.00150 0 .00160 o.00150 0.00160 0 .0015
STL Denver Fom III IN
BB
STL DENYER
Total Mettls Analysis
-3-
BLANKS
Contsract:
rab code:
URS Corporatl-on
STLDEN Crac No. r S.tg t{o. t gDO HO. r D5IA1O27O
PraDaratsion B1ank Matr1x (aoLl/watcr) :WATER
Prcparatsion Blrnk CoocrntrrtsLon Unitse (mglt or mglkll t IUG/I.
ruLttrl
Celtb-
rlenlc
(mg/L)
CoaEj.nulng CalLbrat,ion
Blank (nglL)PrcperrtLon
BIank
Alulrlinum Lo I
CnlcLrrm Lo
Iron Iro
PotrsaLurn
Magneesium
Sodium Lo
Ziroonl-rrrn 0.00150 o.00150
o.105
o.00160 o.00160
STL Denver
Eorm TII IN
STL DENVER
Total Metals Analvsis
a-
BLiI,NKS
Contraet:
Irab Codc r
PrcDaraEion
Prrrparatsion
t RS CorlroratLon
Cuc No. r SAS Ro.:aDo No. r D5f 07 O27 A
B1ank uatrlx (soil/wrtcr) I
Blarrlt ConccntraEion Uaitn (tu9IL,or ng/kg) r MG.fi,
PrcDaratlon
BIrnk
rul,El,r1
CalLb,
BI.arh
ftr$1t 7
Coatinulng CalLbratLon
BIatrk (nglL)
1czc3c
lJ-umiaum to I
CeloLum Lo
Ircin I.o
Potasslum
Magrncsl-urr
Sod,Lum Iro
Ziroonlrrm o. o0160
STL Denver
EorM TII IN
STL DENVER
Total Mctals Analysis
-3-
BLANKS
Contract:t Rg Corporat,lon
LaI, Coda t STITDEN Caro No. t
PreparatLon Blank t'tatrLx (soiI/water) :W.LTER
gnS No. t sDG No. : D5IA7 O27 A
Praparatsion BIanIr, ConcantratLon Unitr (mrll, or nglkg):uc/r,
Cont,inuing Cellbratl,on
Blank lmrl[')
rul.t,la,I
Call.b.
Blank
(mg /t'l
Argenio
BarLtrn
Chroruirun
Coppcr
Lcrd
Nl,ckal-
SL1ver
Vanadius
Zi.nc
0 - 00{rl
0.00070
0.00260
0 - 00{5
o. oo25
o. oo12
0 - 00290
0.oo25
0.00{5
0.0044
0.00070
0. oo250
0 - 00{5
0.0026
0.00L2
0.00290
0. oo25
0 .0045
0. 0044
0.00070
0.00260
0 - 0045
o. 0026
0.00L2
0.00280
0 . 0025
0 ,00{5
0,00{{
0.00070
o. 00250
o.0045
0.0025
0.00L2
0.00280
o .0025
0.00{5
0. oo{o
0.00070
0.0o26
u
U
0 - OO1t5
o.0026
0 .0012
0. oo28
0. oo25
0. oo{5
STL Denver
EOm III IN
STL DENVER
Total Metals Analvsis
-3-
BLANKS
Contract:
Lab Codc:
IIRS Corporation
STITDEN Casa No - :glg N(r. t sDc No.: D5I07O27O
PrcparatsI.on BI.anIE,
Preparatlon Blsnk
MrE,rLx ( eoi1/wrtar) r
Concentrratl"on Uniue (msr/t or mg/kg) :I,{G /T,
Cont,inu:lug CalLbratlon
Bl.rnk (ng/L)PreDaration
Blarrk
Inl-tslnI
Cellb.
B].r.n.IE
('rrsll-l
Areeaio
BrrLrrm
ChromLun
Coppcr
till-ckeL
Sil.vtrr
VanadlLum
o .0044
o. ooo70
o. 00260
o.00{5
0.0025
0. 0012
0.00290
0. oo25
o. oo{5
STL Denver
EoT:Tt III IN
92
STL DETVVER
Total Metals Analvsls
-3-
BLANKS
Cout,nct r IIRS Cor-poration
rab Code: STLDEN Caec No. i
Praparat,ion Blank uatrix ( coil/watlrr) :
preparatl_on sLank ConclcntrratLon Unita (mgll or nglkg) r
D5r07 0 27 0
Ana1ytt
InitirI.
Crlib.
BIanlc(nglLl
c
ConuinrrLng cr1l.bration
BI-rrrIE (ngll)
1czc3c
Praprntlon
B].rnk
C !{
Mercurlr I 0.0000{4lU 0.0000{{lul 0.00004{lU I 0.0000{4 I U o.0000 tt I U CV
STL Denver
Forzr III I![
STL DEN}/ER
Total Metals Analvsis
-3-
BLANKS
Contrrct r
Lrb Cod.s:
Prelrarrtlon
Prrparatrion
IIRS Corporation
8T[-,DEN Cuc No.:
BITnIE Matrirr ( aoil./wrtcr) r
B]-ank CoaocnErat,:Lon Unit,s
Stg ![o. r SDO NO, : D5I07O2-lO
UII,EEn'
(W/t' or nglhg) t ![c/L
lnelytc
rn{tl-al-
CaIlb.
11a:rls
(ms/ry
e
Cont,inulng CalibnEion
Blantc (ng/L)
1 c 7 c 3 c
Prepa"*tro,,
BIaDIE
C Irl
Mercury I 0.0000{{lUl o.0000{{lU I o,00004{ I U Clr
STL Denver
FoTM III IN
94
STL DENYER
Total Metals Analvsis
-3-
BLANKS
Contract:
Lab Coder
Prctrrrltrion
Prcparatl,on
t RS Cora>oratLon
STLDEN Cagc No.:
B1rnk MatrLx (aoil-/watrr) r
glank Couccntration uolta (ng/L
S}II No. r sDG No- : D5TA7 027 0
wl![ER
or sg lB;gl t MG/L
enaltt,c
InLtstrl
Crlib.
BhnIE
(nglL)c
Cont,inuLng CalLbration
Blank (mslLl
1c2c3c
PreDaratsion
B].rnk
c M
Cedmium
g"Lrf*r,
0.0000{0
0. ooo33o
u
U
0.0ooo{ol.ul 0.0000{0 l,u.l 0.0000{o I u
0.00o33olul o.0003301u I 0.000330 I u
0 -.qqgg"!gl-u
o.00033 I u
u-![
STL Denver
FoTm III IN
STL DENVER
Total Metals Analvsis
-3-
BLANI(s
Contrrct r
f..eb Codc:
Prcparatsion
Pre5>aratLon
t RS Corporatton
STI,DEN Cagc No. t
BLardE Mrt,rlx ( eoil/wrtcr) :
Blank Couccntratiou Unltg
8lg No.:sDg No. r D5ro'10270
T.iILTER
(mg/L or mglkg) r MG/L
enalytc
raLt,Ln].
CelLb.
BIT.aIT
(ncr/L)c
Cont.:Lnrrlng Calibrrtlon
Blank (mglLl
1 c 2 c 3 c
Preparation
BIank
c M
Crdrnl-un
S"1""i.-,
o..oooo4ol u J,,,9.0000{0 lu I 0.0.00040 I u
0.0003301u1 0.0003301u I 0.000330 J u
I{
M
STL Denver f,.ornn III IN
96
STL DENVER
Total Metals Analvsis
-3-
BLANKS
Contrrot r
Lcb Codcr
Prcprrrtrlon
PrcprrrtLon
IIRS Corl>orrtl-on
SIILDEDI Caga No.:
Blanl( tlaUrix ( cot l/wat.cr) r
Bl"ank Concsntntion unLta
Al'g lilo. :SDO NO- : D5f 07A27O
hIATTR
(urglr,_ or mglkg) r VIClf.
ena].yEe
Inltlal
Crll.b,
Bl"a.uk
(mg/L)c
ContlnuJ.ng Crlt bntLon
Blank (ulrrlr,.l
1 c 2 3c C
Prrparation
Blank
c M
Crdmium
g.I.tlr*,
o-oooo{ol u l,,0,-q9,9,9j_q.lq
O-O0o33olUl O.OOO33Ofu
![
M
STL Denver Fom III IN 97
STL DETVVER
I'otal Metals Analvsis
-4-
ICP IN'TERFE,RENCE CHECK SAMPI,E
Contnct r IIRS CorporrtsLon
f,ab Codc: STLDEN Cr;c DiIo. l
ICP fD ll\unbcr r T,JA Intraptd fCP
glg No.3 gDc tr[O. : D5I07 02'10
ICg Sourcs:Hi-grh hrrity, Spcx,
Trrrc
fI01 -.D. So1.[El
Consentratioa, uul'tr) r
rnl.tLal Fouad
SoI ,l 8o1,.lB
fLnrl Found
8o1 ..L SoL.AB
lrfuurfnun IIi [ 500. O 500.0 5X7.91 s2s.18l ros.ol
eJ'oLurn El- I SOO. 0 500. 0 505.90 502.55 | roo.5 IIron Hi I ZO0. O 200.0 202. O{199.9{l rOo.Ol
PotstnaLurn I O, O 50 .0 -0.o55 56.59 I 113 .21
gEIGBLrrm I 5OO. 0 500.o 519.8?518.58 I rO3 .7 I
Sodiurn lro I O, O -0,01{
SodLurn Hi 50 .0 54.S11 109.51
irconlurn I 0 .0 1.0 -0 - 003 1,171 1 LL7.1l
STL Denver
Ronr MN
98
STL DENVER
Total Metals Annlvsis
-4-
ICP INTTiRT'ER.ENCE CTIECK SAMPLE,
Cont,rnct r URS CorT>oration
IraL Codc t STITDEN Crac No. r
ICP ID Numbrr r T{FA Intrcptd feP
SlSl No. :sDo No. r D5I070270
fCS Sorrrcc r Higrh Purity, S5rx,
Analytc
trnrc
SoL.A Clo1 .A.B
rnltial Found I "isrl Found
soI ,r gol.tEt e6H | "o, .^ 8oL.AB r.R
le,Iumfnurn Hi I SOO. o 500-0 507.58 so2.7ol roo.5l
alcitrm tlL l SOO. O 500.0 487. 55 480.831 e 6.21
ron IIi I ZOO. O 200-o 193 .27 19O .37 ! S5 .2 J
JnotaeoLrrrn o-0 50.0 -o.oE9 s3.13 I 106.3 Igroagl-unr I S00-O 500 .0 {93.93 {89.18 | S?.9 I
Sod.ium Lo o.0 0 .012
Sodium Hi 50-O s]..991 1O4.Ol
ZLrconium I o.0 1.0 0-000 1.158 [ 116.8 I
Concontratrlou Unit;) r roifllL
STL Denver
Forrr MliI
STL DENYER
Total Metals Analvsis
-4-
ICP INTERF'ERENCE CIIECK SAMPLE
Contract r LIRS Corlrorrtion
f,ab Code: STLDEN
ICP ID !ftrrnbor: SITPERTR.LCE
Cagc No.:SAA No. :sDO No. : D5I07A27A
ICS Source:HLgrh PurLty, Spox,
Conecntrrt,Lon UnlEs) :yslr,
An'rLyte
Tnre
8o1 .L Etol .IlB
rnitl.al rorrnd I tinal rouna
ISoI .t, go1 .LB e6B J so1 .l. SoL.^lB BR
pracnio I O.O0 2, 00 0. 005 2.ooI 1oo.oI
af,.um 0.00 0.50 0 .000 0.5151 103 .21
Chroml,rrn 0.00 0 .50 0.004 o.{80l 95.01
lCopprrr 0.00 o .50 0. o00 0.53{ I 105.81
ILeedt 0.00 1.00 -0,001 0.98 1 98.0 1
prichcl o .00 1- O0 0-003 0.9{l s{.ol
Sllvcr 0-o0 1. 00 0 .001 1.0{l rod.ol
anadLun 0. oo 0 .50 0.002 o.{79 I 95.81
Zino I O. O 1-0 0.012 0 .91 1 91.0 f
STL Denver
Fota IV IN
100
STL DEIVVER
Total Metals Analvsis
4-
ICP INTER}-ER"ENCE CHECK SA}IPLE
Contraets: IIRS Corporatlon
r,rl, Code r STLDEN
rCP fD Number: pE ICI)Ms
Craa No.:Sl,g DIo. t sDs No. r D5I07 427 O
ICg 9or.rrcrr:Inorganie Vantsurrre
.hrrrlyte
Tnrs
EIo]. .A 8oI .AB
rnl,ul,al Found
8oI .A 9oL.AB t5R
FLnaI Fouad,
8ol .A 8o1 .ILB t611
lCadniun o. 00 o .10 0.001 o. oggg I 98.8 0.0031 0.0973 97 .3
Selsnium I O,0O 0.x.o 0.002 0.1063 I 105.3 o.o01l 0.1031 103-1
Conccnt,rrt:lon Unit,r ] r ,lflfI lr'
STL Denver Form fV IN
101
ffisrr
URS Corporatlon
Total Metals Analysis Data Sheet
Lnb Neme:
Lot/SDG Number:
Matrix:
7o Moisture:
Brsis:
Annlysis Method:
Unit:
QC Batch lD:
MS Sample Aliquot:
MS Dilution Fsctor;
STL DIINVEB
F51070270
wA'l'tiR
NiA
Wet
601 0B
mg/L
5a65261
s0 rnL
T
Client Sample ID:
MS Lab Sumple lD:
MS l,ab Work0rder;
DrttelTime Collected:
Date/Tlme Recelved:
Drte/Tlme Leached:
Dete/Time Extroctetl:
I)ate/'ilme Analyzed:
Instrument ID:
LAB MS/MSD
D5t080243-0045
HJ6JM
09/07/05 09:55
09/0tt/05 09:30
09/23105 0tl:00
ae/2610s 23'-s4
azr
Analyte
Splke
Amount
Srmple
Result C
N{S
Rcsult C
oh
Rec a QC
l.,lmlt
Alurninunr 2.00 0.084 U 2.04 98 83 - r 19
Calciurn s0.0 I 400 I 390 MSB NC 48 - I53
Iron r.00 0. I3 B I.05 93 52 - t55
Magnesiurn 50.0 630 677 MSB NC 62 - 146
Potassium s0.0 444 492 MSB NC 76 - t32
Sodiunt s0.0 s500 5490 MSB NC 70 - 203
Zircottium 0.s00 0.021 B 0.534 I03 80- r20
STL Denver
E^-- C a lr(o l-.nl-.nia D^4- Crl--*t D---:-.-l---t
L02
ffisTL
LIRS Corporrtion
'I'otal Metals Annlysis Data Sheet
Leb Nrme:
I,oUSDG Nurnber:
Matrlx:
7o Molsture:
Basls:
Analysls Method:
Unlt:
QC Bntch lD:
MSD Stmple Allquot:
MSD Dilutlon Factor:
STL DENVIiR.
psr07q27-q
wArER
NA
Wct
0010B
rng/1,
s?05261
50 mL
5
Cllent Sarnple ID:
MSD Lab Sample ID:
MSD Lab WorkOrdcr:
Date/I'inre Col lected ;
Drte/Tlme Recelved;
tlate/Tinre l,eich etl:
Drtc/Tlme Extracted:
Dute/Tlme Analyzed:
Instrument ID:
LAB MS/MSD
D51080243-fi)4p
I t.t6JM
0e/07/05 09:55
09i08i05 09:30
0e/23i05 9-$;0q
Q9/26t05 23:54
oel
Annlyte Splke
Amount
Sample
Result C MSD
Result
C 7" Rec a RPD a
QC Limits
7e Rec RPD
Alunrinunl 2.00 0.084 U 2. r0 t01 2.5 83 - I 19 25
Calciurn s0.0 I 400 r 430 MSB NC NC 48 - 153 25
Iron r.00 0.r3 B l -06 e3 0.70 52- t55 25
Magncsiunr 50.0 630 699 MSB NC NC 62 - 146 2s
Potassium s0.0 MA 509 MSB NC NC 76 - t32 25
Sodium 50.0 s500 5650 MSB NC NC 7a - 203 40
Zirconium 0.500 0.021 B 0.546 I0s 2.t 80 - 120 2sl
D^-.--
STL Denver
tr I I lf0ft I - -l-.-:^ h-J- (oL - ^t D -..3-.nl ^-{
103
ffisrr
LIR.S Corporation
Total Metels Analysis Data Sheet
Lab Name:
LotlSD(i Number:
Mrtrlx:
o/o Moisture;
Basis:
Analysis Method:
LInit:
QC Bstrh ID:
MS Samplc Aliquot:
MS Dilutlon Factor:
STI, I}ENVER
D51070270
WATER
N/A
wet
6010I
nsL
526s26L
so mL
I
Client Sample lD;
MS Lsb Sample ID:
MS Lnb Workorder:
DatelTlme Collected:
Datc/'l'ime Recelved:
Date/time Leached:
Date/Tlme Extrrcted:
Datefl'ime Analyzed:
Instrument ID:
LAB MS/MSt)
triIgLQ?43-004s
HJ6JM
09/07/05 09:5s
0e/08/0s 0gf(}
09123/05 08:00
09127/05J0:'^
al-6
Analyte
Splkc
Amount
Sample
Result C
MS
Result C
Yo
Rec a QC
Limlt
Arsenic 2.00 0.0078 B 2.t s 107 84 - t24
Barium 2.00 0.r3 2.M 95 85 - 120
Chrottriunr 0.200 0_0026 U 0.t72 85 73 - r35
Copper 0.250 0.0045 LI 4.29s t17 82 - t29
L,ead 0.500 0.0026 U 0,466 93 89 - r2l
Nickcl 0.500 0.080 0.4c)7 83 N 84 - 120
Silvcr 0.0s00 0.0028 U 0.06s3 130 75 l4l
fpadium 0.500 0.0025 U 0.45 r 90 85 120
J,,.0.s00 0.015 B 0.443 85 60 - I37
STL Denver 104
ffisrt
URS Corporstion
Total Metels Analysis Dsta Sheet
Lrb Name:STL DENVER
Lot/SDG Number: D-5107027A
Matrix: WATER
7o Moisture: N/A
Basls: Wct
.Analysls Method: 60108
Unlu mg/L
QC Bntch rD: 5265261
MSD Sumple Allquot: 50 mL
MSI) Dilutlon Factor: I
Client Sample ID: I.AB MS/MSD
MSD Lnb Snmplc ID: D51080243-004D
MSD Lab Workorder: I{J6JM
DatelTtme Collected: (la/07/05 0955
tlate/Tlme Recelved: 09/08/05 -Q.9;30
Date/Tlme Leached:
Date/Tlme Extracted: 09/23105 08:00
Date/Tlme Analyzed: A9/27/05 lA:22
Instrument ID: 016
Analyte Spike
Arnount
Sample
Result
C Msn
Result
C 7" Rec 0 RPD a
QC Limits
7o Rec RPD
Arsenic 2.00 0.0078 B 2,24 tt2 4.1 84 - 124 25
Bariurn 2.00 0. t3 2.r2 99 3.9 85 - r20 25
Cltromiurn 0.200 0.0026 LJ 0.t80 89 4.2 73 - r35 25
Copper 0.250 0.oMs U 0.309 122 4.6 82 129 25
Lead 0,500 0.0026 U 0.483 97 3.s 89 - l2l 25
Nickel 0.s00 0.080 0.513 87 1.2 84-nA 25
Silver 0.0500 0.0028 U 0,0680 135 4.0 75 I4I 2rl
Vanadiunr 0.500 0.0025 U 0.466 93 3.4 85 l2(l 25
Zinc 0.500 0.0t s B 0.457 88 3.3 60 - r37 25
STL Denver
7cn..u. E I lr(on / -. ^L.^-'^ h -r- (lL ^ -t t --.i-. *l -,--l
105
ffiSTL
URS Corpomtion
Total Metals Analysis Data Sheet
Lab Nrrne:
LoUSDG Number:
Matrlx:
7o Molsture:
Basis;
Analysls Method:
Unit:
QC Batch ID:
MS Sample AIIquot:
MS Dilutlon Fnctor:
S.TI., DENVER
D5W7A27f.'
WATER
N/A
Wct
T47AA
mg/1.
525942s
t
Cllent Sample ID:
MS l,ab Sample ID:
MS Lab r#ork0rder:
Drte/Time Collected:
Date/Time Received:
Date/Tlme Leached:
DatdTlme Ertracted:
DttelTlrne Analyz.ed:
Instrument ID:
GW-8A-09060s
p5r070270-002s.
HJ36N
09/06105 10;3.5
09/07/05 09:30
0e/ZVOlJ2:50
09/21105 I Il:39
019
Analyte
Spike
Amount
Srmple
Result C
MS
Result C
Yo
Rec a QC
Llmlt
Mercury 0.00500 0.000044 U 0.00438 88 85 - l14
STL Denver 105
ffisrt,
URS Corporatlon
Total Metals Antlysis Dntn Sheet
Lab Nrme:
LoUSDC Nurnber:
Matrlx:
7o Molstrtre:
Basls:
Annlysls Method:
Unit:
QC Batch lD:
MSD Sample Aliquot:
MSD Dllutlon Fac-tor:
STL DENVER
p5rq7J)270
WATER
N/A
Wct
7470A
rnglL
szse4,.?5.
I
Cllent Sample ID:
MSI) Lab Sample ID:
MSD Lab Workorder:
Date/Tlme Collected:
DetelTlme Received:
Dato/Time Leached:
Dete/Tlme Extrrcted:
DatclTlrne Analyzed:
Instrument lD:
Gw-8A-09060s
psr070?70.-p02D
I IJ36N
0P/Q0/Q5 I t):35
O,e/0ZQL 09;.30
09/2l105 I2:50
09/21105 I 8:39
019
Annlyte Sptke
Amount
Sample
Result
C MSt)
Result
C 7" Rec a RPD a
QC Limits
7o Rec RPt)
Mcrcury 0.00500 0.000044 tJ 0.00437 87 0.33 tr5 - I 14 r0
STL Denver
E^-.- C I
aa7
ffiSTt
URS Corporation
Total Metnls Analysis l)ata Sheet
Lnb Name:
LoUSDCi Number:
Matrix:
Yo Molsture:
Basls:
Anrlysls Mctlrod:
Unit:
QC tlrtch ID:
MS Srmple Allquot:
MS Dilutlon Factor:
STL DENVER
Dsl07a270
WATER
NA
Wct
6020
mg/L
526s r 80
50 mL
5
Cllent Sample ID:
MS Lrb Srmple ID:
MS Lab WorkOrder:
Ilate/Tlme Collected:
tlate/Time Recelved:
Date/Time Leached:
Dete/Tlmo Extractod:
Dnte/Time Analyzed:
Instrumcnt ID:
LAR MS/MSI)
psr 100153-003s
HKAR9
09/091A5 09:25
09/10/05 08: I 5
09/?3/05 .0tt:00
09[?Z0LQ4;40
J}(ts
Analyte
Splke
Amount
Sample
Result C
MS
Result C
o/fo
Rcc a QC
LImlt
(ladmiunr 0.04ff)0.00020 U 0.039r 97 89 - I r0
Sclcniunr 0.0400 0.00r 6 U 0.0409 r02 82 - tt2
STL Denver
D---- e t t,fl 'l\
-z-- afr- - -,e Fj ----:.- -.1 - .-t
108
ffisrr
uR^S Corporation
Tottl Metals Analysis I)rta Sheet
Lnb Name:
I,oUSDG Number:
Mntrix:
o/o Molsture:
Basls:
Analysis Method:
Unit:
QC Batch ID:
MSD Sample Allquot:
MSI) Dilutlon Fsctor:
STI., DENVER
D5t07A77A.
WATER
N/A
lu$
602Q
rng/L
526s r 80
5[rnL
5
Cllent Snmple ID:
MSD l,ab Sample ID:
MSD [,ab Workorder:
Date/Time Collccted:
tlate/Time Received:
Date/Tirne Leached:
Date/I'ime Extrncted:
Dste/Time Antlyzed:
Instrument I D:
LAB MS/MSD
D5.IlJ)p.153-oo3D
IIK{R9
09/09/05 09:2s
09/10/0s 08; Il
09/23105 08:00
991il/45 M:aa
004
Annlyte Splke
Amount
Sample
Result
C MSD
Result
C %o Rec a RPD a
QC Llrnits
7o Rec RPD
Cadnriunr t).0400 0.00020 U 0.0396 99 1.4 89 - I t0 2A
Selenium 0,0400 0.0016 U 0.0437 r09 6.8 82 - lta 20
STL Denver
E',"r... ( rl IrCn lonl..n2n Il-r- (tL- -t'lD---t-.-l---t
109
STL DENYER
Total Metals Analvsis
-58-
POST DIGEST SPIKE SAIVIPLE RECOVERY
Contract, r URS Corplo4tsion
Irab codc t STLDEDiI Cagc IIlo. r gfg DIo. r sDg No. r D5I070270
ua.trLx (coil/watcr): VIATER Lcwc]. (Isw/med) l
SAIEPI.IE NO.
ConcentntrLon tlnlte:rlglL
Analf'tr ControL
Linit e6R
EpLkcd 8aryrle
Rcrult (SSR) c saqrlc
Raau1t (sR) c
Epihe
.Lddcd (Sl'}t6n o M
CadmLrrrn 175 b L25 0 .188804 o.oooo4oIu o.20 9{.4 ![
Seloniuur I 75 125 o.1glg24 0 .000330 I u o.2a 95.9 ITT
O
Couren
STL Denver Form, V (PIRT 2) IN 110
ffisrl
URS Corporadon
Total Metals Analysis Detu Sheet
Lsb Nsme:
Lot/SDG Number:
Matrlx:
o/o Moisture;
Basls:
Annlysls Method:
Unit:
QC Batch [D:
Sarnple Aliquot:
Dilution Factor:
STI DENVER
p51070270
WATER
N/A
Wct
0Qr oB
milL
s26,j261
50 rnl,
I
Cllent Sample ID:
Lnb Sample II):
Lab Workorder:
Date/Tlme Collected:
Dste/Tlme Received:
Dnte/Tlme Lenched:
Date/Tlme Extracted:
Date/Time Anrlyzed:
Instrument I D:
p5r220000-261(l
r rKsQw
09/23105 08:00
09123105 23:46
azl
Analyte True Found 7"Rec a LimIts
Aluminum 7.00 2.00 r00 86 - I08
Iron r.00 0.964 96 88- ilO
Magnesium 50.0 49.5 99 9t - lll
Potassiurn s0.0 5 1.4 r03 86- 1il
Srxlium 50,0 50.0 t00 9l-il2
Zirconium 0.s00 0.51 e r04 75 - t?5
Calcium s0.0 47.7 95 8q - r r0
STL Denver
F,n-n 7 f fg rtr.rrlrrn3n llnlrr (Lnnt En'.3..n1 .,nt
111
ffisrt
IJRS Corporation
Total Metals Analysis Deta Sheet
Lsb Nnme:
Lot/SDG Number:
Matrix:
%o Moisture:
Basis:
Analysls Method:
Unit:
QC Batch tD:
Snmple Allquot:
Dilutlon Factor:
STL DENVER
D51070270
WATER
N/A
WET
60rQB
me/L
s26s26l
50 rnl,
I
Client Srrrnple ID:
Leb Sample ID:
Lrb Workorder:
Date/Tlme Collected:
Drte/l'lme Recelved:
Date/Tlme Leached:
Dtte/Tlme Extrtcted:
Dete/Time Analyzed:
Instrurnent ID:
D5t220000-261c
HK'QW
09/r3l05 08:00
A9D7fi5 A9:7.8
016
Inr _ .. .. t- I faj,
Annlyte True Found ToRec a Limits
Arscnic 2.00 r.89 95 89 - r09
Lead 0.500 0.48fi 97 9I - IlI
Bariunr 2.AO 2.O4 r02 93 - I 13
Nickcl 0.s00 0.487 97 e0- ilo
Silvcr 0.0s00 0.0489 98 tr5- I14
Vanadiunr 0.500 0.492 98 88 - I 12
Zinc 0.500 4.464 93 8s - r l0
f\rorniunr 0.200 0.1 95 e8 89 - I 12
ho.,0.250 4.246 98 rJ6 - I It)
STL Denver 7l-2
ffisTL
URS Corporation
Total Metals Analysls Data Sheet
Lab Nnme:
Lot/SDC Number:
M&trix:
7o Molsture:
Basis:
Analysls Method:
Unit:
QC Batch lD:
Sample Aliquot:
Dilutlon Factor:
STI- DENVER
Dsr07o270
WATER
IUA
Wet
74.7QA
Itr8&
57s942s
I
Cllcnt Sample ID:
Ltb Srmple [D:
Lab Workorder:
Dete/Time Collected:
Dst€/TIme Reccived:
Date/Tlme Leachcd:
Date/Time Extructed:
Date/fime Analyzed:
Instrument ID:
p5r 160000-425c
FIKVN3
99?lt05 t2:50
09/21l05 I 8:07
Qrg
Annlyte True Found 7"Rcc 0 Llmlts
Mercury fi.00s00 0.00488 98 n5-l14
STL Denver
D^----- '| t f(r Il -r^ CrL - ^.e D ---:-- -l ---z,
113
ffiSTL
URS Corporatlon
Total Metals Analycis Data Sheet
Lab Nnme:
Lot/SDG Number:
Matrlx:
7o Motsture'.
Basls:
Analysis Method:
Unlt:
QC Bntch ID:
Sample Aliquot:
llilutlon Factor:
STL DENVER
pst01{)27Q
WATER
N/A
Ws!
7470A
wg/L
5^{9425
I
Cllent Sample ID:
[,ab Sample ID:
Lsb Workorder:
Date/Tlme Collccted;
Date/Time Received:
IlatelTlme Lcached:
Date/Tlrne Extracted:
Date/Tlme Analyzed:
Instrument ID:
psr r60000-425L
I.LKYN}
09121/05 I 2:50
09/21lOs. I,$:Qt
lltg
Aualyte True Found C o/" Rec a RPT)a
QC Limits
Yo Rec RPD
Mercury 0-00500 0.00497 99 t.7 85 - I 14 l0
STL Denver
F..--. 7 f ncfr / - *r----i- l\ -r- oL - -t l? .---2-- *l ---.t
LL4
ffisrt
URS Corporstlon
'.fotal Metals Analysis l)ata Sheet
I-,ab lrlame:
Lot/SDC Nunrlrer:
Matrix:
ol, Nloisture:
Basls:
Analysls Method:
lJnlt:
QC Batch ID:
Sample Allquot:
Dilutlon Factor:
STL DENVER
pst070270
WATER
N/A
Wet
(t02Q
rng/L
526s I 80
50 mL
T
Client Sample ID:
Lab Sample ID:
Lab Workorder:
Dnte/Tlme Collected:
Dnte/Tlme Recelved:
Dute/T[me Lerchcd:
Datc/Tlme Extracted:
Drte/Tlme Analyzed:
Instrument ID:
p512?0000-180c
r{r$lEA
09/23105 08:00
09f27/05 M:LO
0a{
Aualyte True Found o/oRec 0 Limits
Seleniurn 0,0400 0.0375 94 8?-n2
Cadntiurn 0.04fi)0.0388 97 89 - I I0
STL Denver 115
STL DETVVER
Total Metals Analysis
-9-
ICP SERTAL DILUTIONS
Contrlot r IIRS Corporation
SIltPfrE NO.
IttrRA-LlB QC gER
gD(l NO. t D5IO7027O
Lowr1 ( Low/rlrd) t IrOf{
Lrb Codc r STITDEII erEo lrlo. r g.Lg ![o. :
Mr.trLx (eol,I/watc) t ffiTER
I lrrrminrrm
Calclrrm E
Iron Lo
Potasgirrrn
Magnegiun
Sodium Ht
Zirsorrlrrsr
Conctnt,ntl-on trrl,tt r mgfl-,
o-o17 o.o85 Ju
Scrlr1 Dilutlon
Re sults (S)fnitia1. Errqrl.o
RasulE (I)
27 4.29 27f3-88
L26 .67 128.18
10gg,00 1091 .50
0.00150 0.0093{
STL Denver
For:n IX IN
116
STL DENVER
Total Metals Analvsis
-9-
ICP SEITIAL DILUTIONS
ConEract: IIRS CorpontLon
S}}{PLE NO.
INTRT-I-,[I] AC gER
gDc No, : D5I07O27O
Lovcl ( low/ncd) :LOI{
Lrb Codc r STITDEN
Mat,rix (roil/watcr) : WATER
Crac No. t SAS No. t
InitirL srqrla
RcsuIE (I)
Erri-rl DLlutLorr
RcsuIE (s)
0.00250 0,01300
o.0045 0.0225
o-0026 o. 0130
0.0802 0.og?l
0. 00280 0 .01400
0.0025 0.0L25
| ^Lrreaic
Bariurn
Chromitua
Coppar
I-cad,
Ni.ckaI
Sil.vcr
Vaaadium
Concontnt:Lon tErLt,r t lorglL
0.0079 0 - 0220
STL Denver
Form fX f![
L1,7
STLDENVER
Total Metals Analvsis
-9-
ICP SERIAL DILUTIONS
Contrrct r IIRS Cor-Irontlon
S I{PIrE }IO '
IlERe,-tlB AC SER
sDc No- : D5I07O27O
Lcvc1 ( low/med) :LOUI
L'ab Code: SfLDEN
I{atrix (roll/water) : I{trfER
Cagc No-:8l.El Elo. t
.}naI-ytse
IleitLa1 sarqllc
Rrrult (r )
ScrLal DllutLon
Rcault (s )
0.000330 0 - 001550
I Crdmirrm
ElclanLum.
Conocntsratslon llnLtg: mg/L
0.0000{ro o. ooo2oo Ju
STL Denver
Form fX IN
118
STL DEIVVER
Total Metals Analysls
-r0-
METHOD DETECTION LIMITS
I,Trb Code : STLDEN Crac No. r
ICP ID Nunrber: TJl, fntrcpid ICP
Flanr AA fD Nunber:
Ftrrnacc ll, ID ll\unbar r
SLS No. t
Date: 5 ILO lz00s
sDs No. r D5I07027O
.Bnrl.ytr
lrlawe -
lcagth
(nn)
Blck-
grorrnd PQL
(urglL)
MDL
(mg /l'l t[
Aluminum L 157.0 0.101 0.017 IP
Aluminum B 309-2 1.0 P
Cr].cLrr.m L 317 .933 0 .20 0.034 I P
Crlcium H 318-1 t0 P
Iron lro 259.9 0 .10 0-021 lP
Iron II 2-lL -44L 1.O P
Potrrgium 7 66 -{91 3.0 o-2c I P
Magrncgl-um 279.078 o-20 o-o{3 lP
Sodlum Lo 589 .5 1-O 0, 031 P
um Hi 818 .3 10 1.11P
Zil.rcelnLrrn 339 -0.00501 o.0016 lP
Comcnts:
STL Denver Forea X IN 119
STL DENVER
Total Metals Analysis
-r0-
METIIOD DETECTION LIMITS
Contract: IIRS Corrroration
rrb Codrr STLDEN
rCP rD Numbcr: SUPERTR.trCE
F]'aIIte AA fD Nunber:
hrm,acc AJt ID l!\rmbor r
gAg No. I
Datr3 5 lLOlzAAs
sDo No. : D5IA7 A27 O
Jlnalyte
WavG-
lcngth
f nn)
rack-
grround PQI,
(mg/L)
}IDT,
(nglL)DT
rsenLc 189.A4?0 - 010 0. o0{l P
Barl-un 493 .409 o. 010 0. ooo70 P
Chronl,um 267.?15 0-010 o.0026 P
Copper
IrGid
321 ,7 53
zm'E
0.010
0.60ffi
0.00{5 I P
AffiTF
NLckel 23L.50{0 .000 0.0012 P
SlIwcr 328.068 o, 010 o .0029 P
Vanadlum 292 .4A2 0.010 0.0025 P
ZLr.c 206.200 0.020 o - oo{5 p
STL Denver Forrr X - IN a2a
STL DENVER
Total Dletals Analvsis
-10-
METHOD DETE,CTION LIMITS
Cont,raet: IIRS Corlrorrtion
Lab Code r STIJIEN
fCP ID lihrmbrrr:
Cagc Slo. l S.B,S !ilo, t
Drtc r
Dsr A7 027 A
LL 1L21200t
F1ana Ar rD [hrmlrcr:
hrrnacc JLr fD Nrrmbcr:
PE CI'IAA
Anallte
Wave-
lcngth
(nm)
Brck-
grrorrnd,PQL
(rrg/I, )
UDIr
(mg/L)u
Marcurlr 253 .7 A 0 . 00020 o .000044 c-tr
Cornnents:
STL Denver Form X IN 127
STLDENVER
Total Metals Analysls
-I0-
METIIOD DETECTION LIMITS
Contraet: IIRS Corporatl.on
Lab Coda: STTDEN
ICP ID lllrnrlrrr r PE ICP}TS
P1anc ^LL ID Numbcrr
ftrrnecc .l.n fD Numbcr r
Carn sDc li[O. r D5TA7A27A
Datct 5lLAl?AOs
lrrrlytrr
Ieotopc Baok-
ground.PQL
(uryllLl
MDIJ
(ng/L)M
Cadmlrrnr 1111 o.0010 o-0000{0 lId
8elcaium 82 0.0050 0.000330 DT
STL Denver fonn x IN L22
STL DEIVVER
Total Metals Analvsis
-1lA-
ICP INTER"ELEMENT CORRECTION FACTORS (ANNUALL)O
CoDtract,: IIRS CorDorratioa
Lab Coda: STLDEN Calle No.:
Intrepid rCPrCP ID lfi:rubar: TiIA Dates 8lI9 l200s
gAg No. r gDC }IO. r D5TA7O27O
Analyta
wave-
length
(nn)
rntorolamont Corroetlon Fastoru
Ca Fe
for:
MgA1 Ag
I 339.198 o. ooooo0o I 0.0000000 0.0000000| o.0000oooJ o-ooooooo
eluml-num I 162.081 0.0000000 I 0.0000000 0.00192001 o.oooooool o.0oo00o0
rluntnum 1309.27a 0.0000000 I o-oooooo0 o - ooo0oool 0,0007?40 1 o. o0o000o
Antinony I 206 - 83 8 o. 0000000 I 0.0000000 0.00000001 0. ooooooo I o. ooooooo
lrgenlc I 18g.al,z o.o0oo000 J o-0000000 o-o0ooo0ol o.ooo0000l o.ooooooo
BarLum l ass, {03 0.0000000 | 0.0000000 o.oo00oool o.0ooooooI o-oooo000
Bery,llium Iffa-O{2 0.0ooo00o I o_0000000 o.ooo0oo0J o.0o0o00ol o.ooooooo
Boron lztg.G7$0.0000000 [ o. 0000000 0. 0000000 I o. 000oooo I o. ooooooo
cadrutum |_226 - 5oz 0.0oooo00 | o,0oo00oo o. oooo{2ol 0.0000000 I 0.0000000
calcLur Iffz.g33 0.0000000 | o. o0o00oo o - ooooooo I o. oooo32o I o. ooooooo
Calcium I,f8-148 0.0000000 | o-0000000 o-oooooool 0.0000000 I 0.000000I
Chromium lzw -TLG 0.0000000 | 0.0000000 o.oo000o0f o-oooooooI 0.000000{
cobalr l^18.616 0-ooooooo I o*0000000 o. oooo0ool o. ooooooo I o. ooooooo
copper I SZt. ?53 0-0000000 I o-0000000 -0.00002001 0.0000000| o-0000000
rron Iass-g{o 0.0000000 I o-00o0ooo o-oooooooJ 0.0000000 I 0.ooo0ooo
rron lz7 1.{41 0.0000000 | o.0o0oo0o o.ooooooof o.oo2o1ooI o.ooooooo
Lcad |rz0 -353 0.0000000 I 0.0000000 o. ooooooo I o. ooooooo J o. ooooooo
r.,itrrlnm I6?0.zB{0.0000000 I 0.0000550 o. ooooooof o. ooooooo I o. ooooooo
MagncrLrrm lrl9. O7g o.00o0ooo I 0.0000000 0.00050201 0.0000000 | o. ooooooo
t{angranoge lZSt. 610 o - 0000000 I o. ooo0o0o 0.00000001 o. oooo15o I o. ooooooo
Molybdornrn |ZOZ. 03 0 o-0000000 I 0.0000000 0.00000001 o.oooooool 0.0000000
nl.ckal leg1.5a412 o.00ooooo I 0.0000000 0.00000001 o.000ooool o'ooooooo
Phospfronr,s I 178 .282 0.0000000 | 0.0000000 o.oooooool o. oo0000o I 0.0000000
Potasglum I z6e. d91 0,0000000 1 0.0000000 o. ooooooo[ o. 0000000 I 0.0000000
Selenl.urn I 196. o9o 0.00ooooo | 0.0000000 0. ooooooof o.000oooo I o. oo0ooo0
stll.cou I 251.61.2 o. oo0oo00 I 0. 0000000 o. o000oool o. ooooooo I o. ooo0ooo
silieon I 251. G15 0.0000000 I o.0000ooo 0.00000001 o. ooooooo I 0.0000000
Sllver I frs.068 o. ooo0o00 | 0.0000000 0 .0000000 I o. ooo0ooo I o .0000000
sodium I tag.592 0.0000000 I 0,0000000 0.00000001 o.oooooool o,0oo0ooo
sodium I tte.326 0.0000000 J o.ooo00o0 o.oooooooJ o,ooo0000l 0,ooo0ooo.
St,rontium IaOz -77L 0,0000000 J 0.00016?0 o. oooooooJ o. ooooooo I o. oooooo(
Thalliun I rg0 .964 0,0000000 I 0.0000000 o,oooooool o.oo00oool 0,ooooooo
723
Cgmncrrts:
STL Denve
STL DEIVVER
Total Metals Anatvsis
.IIA.
O rcp TNTERELEMENT coRRECTToN FACT,R* (AI\.NUALL,)
coDtrrct: gB$-C9fpefggion _
Lab Codos SrLDEN Case No.: _ glg Bo.r _
rcP rD t|llmber: ,I,arA IatreDtd rcp Darc: 8ll9l2a05
gDc No. 3 D5IO7A27A
Thorl-rrm I 283 . 73 0 o-ooooooo I 0.0000000 o.ooossool 0-0000000I 0.0000000
rl.n I lgg. ggg 0.0000000 I o. oo000oo o. oooo00ol o. 0000000 I o. ooooooo
TLtaniun 1330.941 0.00ooooo I -0.0000320 0.00000001 0.00o02,t10 I 0.0000000
uranium I
g95.958 o.0000000 I -0-o0o1o20 -0.00085{01 o.0oo0o0o I 0.0000000
vanadium l rr2.4Oz o. o0ooooo I o.00oo0o0 0.00010101 -0.0000130 | o. 0000000
zLnc I 213 -BsE 0.00001.30 | 0.0000000 0.00005901 o, o0ooo0o l o, oo0oo00
Cormentg:
STL Denve
Etaq tiT , ttlDltr 1 \
ST'L DENVER
Total Metals Anatvsis
-llB-
r c P I NT ERELEMEI{T C O RRE CTION rA C TO R^S (A NNUALLY}
Corrtract r (IRS Cor:troration
I"ab Codo s Sl1l1DEN
ICP ID ltrrnlrer: l[iFA
Cage No.3
IntrepJ-d, ICP
glg No.3
DBto: I lLgl?OOs
sDc No. : D5TO7A27O
rna1trc.c
Wavo-
Iengttr
(nm)
rntcralomont Correctlon Factorr
BBa
for:
Be CdAg
I 339.198 0.0000000 J o-0000000 0.00000001 o-0ooooooI o-ooooooo
Jrlumlnum I f 0z .08 t 0.0000000 | 0.0000000 o - 00000001 o.0oo0ooo I o. ooooooo
rlrrsrlnum I go9 -271 0. 00ooooo I o. 0000000 o - ooooooof o. ooooooo I o. oooo0oo
rntl.mony l_2o6.838 o.00ooooo I o. 0o0oooo 0.0000000[ o-oooooooJ o-ooooooo
rraanle I 189.042 o. oo000o0 J 0.0000000 o. ooo0oool o. ooo000o I o - ooooooo
Barlurn lot5.o03 0.0000000 I 0.000oooo 0.0000000T-0.0000000 I 0.0000000
ser:rlliurn Ifff.0{2 0.oooo000J o-0000000 o . ooooooof o, ooooooo l o. ooooooo
Boron lrog - 578 o-0000000 I 0.0000000 0.00000001 ---0.0000000 I 0.0000000
cadmium 11226.502 o.00ooo00 I 0.0000000 o, oooooool o. oooooo0 | o - ooooooo
Carcl-uur Iffz.g33 o. oo000o0 I o. oo0000o o. oooooool o. ooooooo I o - ooooooo
CalcLum l 3tB.1zB 0.0000000 [ o. ooo0o00 o.00oo00ol - 0.oooo000 I o.0000ool
chromtum I a0z.715 0-ooo0000 I 0.0000000 0.o00ooool o.o0o0oooI o.ooooool
cobal-t 1228.616 o. 0000000 [ o. 0000000 0.00000001 o. ooooooo I 0.00ooooo
coppar I aza.z53 0.0000000 I 0. 0000000 o. ooooooof o. ooooooo I o. ooooooo
rron I 259.9{0 0.0oooooo I o. o00o0o0 o. ooooooof o. ooooooo I o. ooooooo
rrorr lzT 1. {41 o. ooooooo I o. oo0000o o. oooo0ool o. ooooooo I o - ooooo0o
Lead 1220.353 0.0000000 I o. 0000000 o.oooooooJ o.oooooool o-ooooooo
rlrhium I 570 .7gr 0 .0000000 I o. 0oo00o0 0.oooo0o0l o.oooooool o.ooooooo
litragnogturn I ?.79 .a79 0.0ooooo0 I 0.0000000 0.00000001-- 0.0000000 J 0.0000000
!flangranoge Izsr.6to 0.0000000 J 0.0000000 o. oooooool o. ooooooo I o . ooooooo
Molybdenum I 202.030 0.0000000 [ 0-0000000 o. oooooool o - ooooooo J o. ooooooo
utckel l23t.6otlz 0.0000000 I o.0000ooo 0.0000000| o-0000000I 0.0000ooo
Phosptrorur 1128.287 0.00oooo0 I o.0000ooo o. oooooool o. ooooooo I o. ooooooo
Potaagium I ,e5. {91 0.0oooo00 | o.0000ooo o. oooooool o. ooooooo I o. ooooooo
sslenl.um lr9e.O90 o. ooo0000 | o.0000ooo o.oooooool o.oooooool o.ooooooo
stlicon f esr .6L2 0.0000000 [ o.0000000 o, oooooool o - ooooooo I o. ooooooo
stlLcon
1
2u1.615 o-oo000oo I o.0o0o0o0 o. oooo00o[ o - oo0o0oo I o. ooo0ooo
gllver
I ,2B. 068 0.0000000 f o. oo00o0o o . ooooooo I o. oooooo0 I 0,0000000
sodiurn I Sag. Sg2 0.0000000 | o. ooo0000 o.oooooool o.oooooool o.ooooooo
Sodium lrr8.3zG 0, oooo00o I o.000ooo0 0.00000001 0,0000000[ 0.0000000a
StronLlum I oO7 .77L 0.0000000 J 0.0000000 o .00000001 0.0000000 | o. oooooo(
rhallium I rg0. g6{0.0000000 1 0,0000000 o. oooooool o.00o00oo I o. ooooooo
L25
Cosmentg:
STL Denve
STL DENVER
Total Metals Analvsis
-1lB-
I CP INTERELEMENT C ORRECTION FACTORS (A NN UALLY)
Contract: t RS ComoratLon
Lab Codes S1.LDEN
ICP ID lUlunber: TifA
Care No. r
fntrepl-d fCP
S.Lg [Io. t
Dats: I ll9l2005
gDc No. : D5TA7A27O
Tlrorl'rrrn 1 283,730 o. oo0o0oo I 0.0000000 o. ooo0o00r 0.0000000 | o. ooooooo
Tln I rag. e8g 0.0000000 | 0.0000000 o. ooo000ol o. ooo000o | 0.0000000
rl,taaLtlnr flac.9{1 0.000oooo I 0.0000000 o. oooo00ol o. oooo0o0 I o.00ooooo
uranj.urn I ge5.958 0.0000000 I o. oo00o0o o . ooooooo I o. oo0000o | 0. ooooo0o
vanadir.rm 1292 -1102 0.0000000 | o-0000000 0. ooo00o0 I o.0oo00o0 I o.000oooo
zLnc I 213.856 0.000oooo I 0.0000000 o-oooo000l o.ooo0000 I o.oo0oooo
Corunents:
STL Denver
Fnvrn IT , DLPrn , \TN
1,26
STL DENVER
TotalMetah Analvsis
_l1B-
ICP INTERELEMENT CORRECTION FACTORS (AI{NUALLY}
Cortractr IIRS Comoration
tab Coda 3 S'11TDEN Cage No. :
Intrepid fCPfCP ID lWrmbar: 1[,IA Date: I lL9l2005
glg I[o. r
Arrellfta
WAvo-
I"ongth
(nm)
Intcrclanrcnt Corrcction Factorr
Cr Cu
for:
K MnCo
1339-198 0. 0000000 I -0 - 0012900 o-00ooo00l o-oooooool o.ooooooo
Alumlnum I foZ.0B1 0.0000000 I o-00ooooo o.oooooo0l 0.0000000f o.ooooooo
tlumlrrurn I aOS .27L 0.0000000 I 0.0o00ooo o.ooo0oool 0.00000001 0.oo000oo
Antl,mony I,06-83I 0,0000000 I o. oooo000 o.o0o00o0l 0,0oooo0ol o-ooooooo
Arrcnic I ttg.o4z o - 0000000 I o. ooooooo o.oo0000ol o-ooooooo| 0.0000000
narl,um l oss, {03 0. ooooooo I 0.0000000 0.00000001 o.0ooo0oo I o. ooooooo
Berrrllium I 313 .0{2 0.0000000 I o. ooooooo o. oooooool o. ooooooo l 0 - 0000000
Boron I eo9.6zg o-0000000 I 0.0000000 o. ooo0o0ol o. ooooooo I o. ooooooo
cadurl.rrm 1225. 502 o-0000000 J 0,0000000 0.00000001 0-oooooool o-ooooooo
calclum I rrz.933 0.0000000 | 0.0000000 0.00000001 o. oo0oooo J o. ooooooo
Calclum I Sre.12B 0-0000000 I 0.0000000 o. oooo000J o. ooooooo I 0.000000I
clrromLum lZSt. 216 0.0000000 I 0.0000000 o.0o00o0ol 0.0000000 1 0.000072(N
cobalr l22g - 516 o - 0000000 | o. o0ooooo o. oooooool o - ooooooo I o. ooooooo
copper I Sza.753 0. 0000000 I 0.0000000 0. oo00oool 0. ooooooo I o - ooooooo
rron |259-9oo 0.0000000 I 0-oo0oooo o. oooooool o. ooooooo I o. ooooooo
rron lrr1. {41 0.13o0ooo I 0.0000000 o. oooooool o. ooo0ooo I o. ooooooo
Lcad 1rr0.353 0-0000000 | 0.0000000 o. oooooool o. ooooooo I o. ooooooo
r.ittrtun I S, a.784 0.0000000 I o.0oooooo o. ooooooof 0.0000000 J o. oo0oooo
MagmesLum 1279 - 079 0.0000000 I 0.0000000 0. 00000001 0,0000000 1 -0.0035690
Marganase lzsz - 610 0-0000000 I o-0000000 o. oo0ooo0l o - 0000000 I o. ooooooo
Molybd€nun I ZOz.030 0.0000000| o-0o0o0oo o. oooooool 0.0000000 I o. oooo0oo
Nt ckel I 231.6 o4 tz 0.0000000 J o. ooooo0o 0.00000001 0.00ooo0o I o. ooooooo
phorpbonrs I tr 8,287 o-0000000 J 0.0000000 o. ooooooof o. ooooooo I o. ooooooo
PotassLum l, e6.491 0.0000000 I o.0000000 o. oo00oool o. ooooooo I 0.0000000
Salenfu:m I tg6.090 0.0000000 I o. oooo000 o.00ooo0ol 0,00000001 o.0oooooo
gtll,eon
I zsr -6Lz 0.0000000 I 0.0000000 0. o0o0o00l o. o0ooooo I o - ooooooo
stlicon lro1.G1s o. ooo0ooo I 0.0000000 o. oooooool o. ooooooo I 0. ooooooo
sLlver l szg.06g 0.0000000 I 0.0000000 o, oooooool o, o0000oo l o. oooooo0
sodlum I og9. s92 0, ooo0o00 I 0.0000000 0.00000001 o.o00ooool 0.0000000
Sodlum I
gt8,3zo 0.0000000 I 0.0000000 0.00000001 0.0000000 I 0.00000001
EtrontLum Ioo7 .-IzL 0. oooo0o0 I o.0000000 o. oooooool o. ooooooo I o. ooooooo\
rhalltum I fgO. g6{0. 0000000 I 0.0000000 o.oooooool o.oooooool o.000oooo
Dsr07 0 27 A
a27
Cornncntg:
STL Denve
STL DENVER
Total Metals Analvsis
-118-
ICP TNTERELEMENT CORRECTTON FACTORS (ANN UALLY)
Contract : UBII Cormoraf.,ion
Lab Cod.e: STLDEN
IeP ID lhrmberr TJA
Care No.:
IntrepLd ICP
SAg No. r
Dat,er 8llg l2AO5
Tborlrrn 1283 -730 o. 0000000 | o. o0o00oo 0. 00000001 o. o0oo00o I o. o0ooooo
Tl.n I 189.989 o. oo0oo00 I o. o000ooo o. oooooool o - 0000000 I 0. 0000000
Tlranlun I rgt. g{1 o.0000000I 0-ooo3150 o,oo0ooo0l o-oooo000l 0.0000000
Uranium
1 385.958 0.0000000 | 0. o00oooo o. oooooool o - ooooooo I o. o0ooo00
VanadLrrnr lZlZ.4O2 0.0000000 | o.0oo229o o.oooooool o-oooo0ooI o-o00ooo0
zinc I err.856 0.0000000I 0-0000000 0.0009{{ol o. o0oo000 I 0.0000000
Couunentg:
STL Denve
Etrrr,.r* Vll I nr Pm a) l -rrt
1,28
STL DEIVVER
Total Metals Alralvsis
-llB-
ICp TNTERELEMENT CORRECTTON FACTORS (AI{I{UALT ,Y)
Contracts r IIRS Corrrcoratlon
Lab Cod,c: gTfrDEN
rCP ID lnrmberl 1[JA
Care No.:
IntrepLd, ICP
g.tg No. t
Dater 8 /L9l?OAs
gDO NO. : D5I07 O27 O
Analfrte
Wawg-
I.cngGh
(rn)
Intcralemant Corrcet,Loa Faetom
Na Nt
for:
Pb SI)Mo
| ,ae.19B 0. 0009000 I o.0000000 o. oooooool o. ooooooo l o - oo0ooo0
elumlnrlm I 152.081 o. ooooooo | 0.0000000 o,0oooo0ol o. o0ooooo I o. o0ooooo
Aluminrun la09- 27L 0-0ooo0o0| 0.0000000 o. oooooool 0 .0000000 1 o,0ooooo0
Antlnprry I ,06, B3I 0.0000000[ o-ooooooo o - oooooool o. ooooooo I 0.0000000
.lrgenre I1Bg-Oa2 0.0000000 I 0.0000000 o. ooooooo I 0. 0000000 I o. ooooooo
sarlum I ots- {03 0.0000000 | 0.0000000 0.00000001 o-oooooooJ 0.0000000
nerTllium !aff.O42 0.0000000 I o-o0ooooo o-oooooool o-ooooooo! o.ooooooo
Boron lztg - 628 0.0000000 | o,00oo0oo o.oooooool o.oooooool o.ooooooo
CadrnLum I,r5-502 o-0000000 I o.0000000 -0.00019701 0.0000000 I 0.0000000
calciurr I erz.933 o-0000000 I 0.0000000 o. ooooooof o - ooooooo l o. ooooooo
CalcLrln I ,rB. 12I 0 - 0000000 | o. 0000000 o.oooooool 0.0000000I o-oooooor
chronLum I257.7LG 0.0000000| o-0ooooo0 o.ooo0oo0l o-oooo0ooI 0.00o0oo(Jl
cobalt l|229.516 o. ooo0000 I 0.0o0o0oo o, oooooool o. ooooooo I o - ooooooo
copper 132L.7s3 o, oo03{00 1 o, oo0o00o 0.0000000J o. oooooo0 | 0.00oo0oo
rron I zsg.gco 0.0000000 I 0.0000000 o. oooooool o. ooooooo J o, ooooooo
rron 127 1. d{L 0.5015000 I o-ooooooo o. oooooool o. ooooooo I o - ooooooo
Lead |1220.353 o.0000000 I o. oooooo0 o. oooooool o - ooooooo I o. ooooooo
r.ithlum l67o -784 0.0000000 I 0.0000000 o. o0oooool o. o00oooo I 0.0000000
Ir,Egrnosium 1279.029 -o - 03 s8000 I 0. 0000000 0.0000000J o.oo0o00ol o-ooooooo
Dranganoa€ lzst. G 10 0.0000000 | o-0000000 o - oooooooJ o. ooooooo I o. ooooooo
Molybdanrrm I 202 - 03 0 0 .0000000 | o.0000000 0.00034001 o. oo0o0o0 I 0.00o0ooo
xLskel l zg1.6 a{t2 0.0000000 | o.0oooooo o. ooooooof o. ooooooo l o - ooooooo
Plrosptrorug ItrB.287 0. 0oooooo I o.00o0o0o o. oooooool o. ooooooo I o. ooooooo
Potarrlum I ,s6. {91 0.0000000 I 0.0000000 0.0000000[ o.o00ooo0l o.ooooooo
selenium I 196.090 0.0000000 I 0.0000000 o. oooooool o. ooooooo I o, ooooooo
st licon
1
rul.612 o. oogzooo I o. ooooooo o.oooooool o.oooooool o.ooooooo
gLll,con Izsr.615 o.0092000 | o.0000000 o. oooooool o. ooooooo I o - ooooooo
siLver I ,rB.0G8 o.0o00ooo J 0.0000000 o. oooooool o. oo0oooo I o.0o000oo
sodium I sgg.5g2 0.0000000 | 0.0000000 0,oooo0oof o.oooooool o.ooooooo
sod,lum I ar8.325 o. ooooo00 | 0.0000000 0.00000001 o. 0000000 I 0.0000000/
Stroutlurn I OO7 .77L 0.0oooooo | 0.0000000 0.00000001 0.00000001 0.0000000I
rhalllun I 190.864 0.0000000 I 0.0000000 0.0000000J o. ooooooo l 0 .0000000
L29
Comnentg:
STL Denve
STL DENVER
o
Co
TotalMetals Analvsis
-t18-
I.CP INTf,RELEMENT CORRECTION FACTOR.S (ANNUALLY)
atracts IIRS Corrcoration
Lab Coda 3 STLSIEN Cage No.3
Intrepid ICPICP ID t\Iurnllar: TiIA Dates 811912005
gAg NO.:SDG NO. : D5T.07O274
[Iroriurn I 283 . 73 0 o-00000001 0,0000000 0.00000001 0.0000000 I o. ooooooo
rln I 1B9.9gg 0.0000000 I o. oooo00o 0.00000001 o. ooooooo I o. oooooo0
rLtaniurrr I 33c.9{1 o. oo0o000 I 0. o0o000o o. oooooool 0 .0000000 1 0.0000000
uranlum I ta5- g5B o-oooooo0 ! o.0000000 o, oooooool o. o00o0o0 I 0.0000000
vanadLum I,gz.tlz -0.0125000 I 0.0000000 o - 0o00oool o. ooooo0o I o. oo0oooo
zl.ne Iarr - B5G 0.0000000 [ o, ooo00oo o.oo4380ol o-oooooooI o-ooooooo
Corunentg:
STL DCNVC
tra-ra .lrf , raf ]rrn a I
13 0
STL DENVER
Total Metals Analvsis
-llB-
rcP TNTERELEMf,T{T CORRECTTON TACTORS (ANI{UALLY)
Contractr IIRB Cor:rorati_on
Lab Code s STITDEN Case No. r
Intrepid ICPICP rD Number: TiIA
gAS No. r
Datsc: I llg tZAAs
SDG No. : D5I07 A27 O
Wave-
longrth
(nn)
Intcralomont CorrcctLon ractora for:
SrArrBllt,c riSesiSn
I 33e.1eB 0-oooooo0I 0.0000000 o. oooooool o. oooooo0 I o. o00oooo
rlr:rntnum I reZ. OB1 0.0000000 [ o. o0oooo0 o. oooooool 0.0000000 I 0.0000000
Alumlmrm 1309.271.0.0000000 I 0.0000000 0.00000001 o. ooooooo I o. ooooooo
AntLmony [ 205.939 0.0000000 I 0.0000000 0.oooooool o-00000001 0.0000000
Argeot c I 1s9.0E2 0-o000ooo I o.0000000 o. oooooool o. ooooo0o I o - ooooooo
narlum I css. {03 0. o0ooooo I o. ooo0ooo 0.00000001 0.0000000 I -0.0001930
Berylllum I rrr .a{2 0.0000000 J 0.0000000 o. oooooool 0.0000000 I 0.0000000
Boron lzl,S.6zg 0.000oooo J o.000oooo o - oooooool o. o000oo0 I 0.0000000
cadmlum 1116. sOz 0.0000000 I 0.0000000 o. oooooool 0. ooo0oo0 I 0.0000000
Calciurn lefz.933 0.0000000 I o, oooooo0 0,0000000J 0.0000000 I o. ooo0ooo
CaLeLum JfrA.L2g 0.0000000 I o. oo00oo0 0 - oooooool 0.0000000 I o. ooo0o orl
ctrromLun lZeZ .TLG o, o0oooo0 I o. o0ooooo o.00000001 0. ooo0000 I 0.00L200q
cobalt |1229.616 0.0000000 J o. ooooooo 0.00000001 0.0000000I o-oo18ooo
coppcr I sec-753 0.0000000 | 0.0000000 0.00000001 o.oooooool o.ooooooo
rron Izss-g{o 0,0000000 1 0.0000000 o. oooooool 0.0000000 [ 0.0000000
rron lrr7.. AIL 0.0000000 [ o. ooooooo 0.00000001 o-00oooooJ o.ooooooo
L(rad lzzo -353 o.oo00o00 | o-0000000 0.00000001 o. ooooooo I 0.0000000
r,lthlrrm lerO.TB{.0. ooooooo I 0.0000000 0.oo00oo0l 0.ooo0oool o.ooooooo
lrragncrium 1rr9.079 0.0000000 | o. 0000000 0. o00o0oof 0.0000000 I o. oooo0oo
Manganes€ lzSz.610 0.0000000 | 0.0000000 0. oooooool o. oooooo0 | 0.000oooo
r'rolybdorrutrr 1202.030 0.0000000 I o.000oooo o. ooooooo I o. ooooooo I o. ooooooo
rrlLctel lzg1.5o{t2 o.0oooo00I 0-000oooo o. oooooool o. ooooooo I o. ooooooo
Ptrogphorur I rr8.287 0.0000000 | o. oo0oo00 0-o0oooooJ 0.00000001 o.ooooooo
Dotasrl-uur I 755. d91 0.0000000 I 0. 00o0ooo o. ooooooo ! o. oooo000 l 0.0000000
salenlum I 196. 090 0.0000000 I 0.0000000 o. oooooool o. ooooooo l o, ooooooo
stlicon I rs]-.6L2 0,0000000 I 0.0000000 0.00000001 0.oo000ooI o.oo0oo00
stllcon
I
zsr.61s 0.0000000 I o. oooo000 o . ooooooo
I
0.0000000 I o. ooooooo
silvcr I ae8.05g 0.0000000 I o. oooo000 o. oooooool o.0oo0oo0 | 0.00035{0
sodh:m l Sg9 .5 gz o, 0o00oo0 I 0,0000000 o. oooooool 0.0000000 I 0.0000000
Bodluur I are. fae o.0oooooo I o.0000ooo 0.00000001 0.0000000 I 0.0000000/
Strontl,urn IOO?.77L 0.0000000 | 0.0000000 o. oooooool 0.0000000 | o. oooooo(
rhalllum I fgO.96{0 .0000000 I 0.0000000 o . 0oo0ooo I o. 0000000 I o. ooooooo
131
Conq\ents:
STL Denve
STL DENYER
o
Con
frab
rcP
Totrl Metals Analvsis
-118-
rcp TNTERELEMENT CORRECTTON FACTORS (ANNUALLY)
traet: IIRS Corooration
Code ! ST1,DEN Care No.:
tntrepS-d rCPID ltumber: TifA Dato: 8 l!9l?OOs
g.Lg No. ;SDG HlO. : DSf 07A27A
Elrorlun I 283 . 73 0 o. 0000000 I 0.0000000 0.00000001 o. ooooooo I o. ooooooo
Tl"n I 18g. ggg o. 0000000 I 0.0000000 o. oo0ooool 0.0000000 I 0.0000000
rLtanfnn I ff{.9{1 0,00o0o00 I o. oo00oo0 o. oooooo0l 0.0000000 I 0.0000000
uranLum I ,t5.958 0,0000000 I o.0000000 0.00000001 0.00o0ooo I o. ooooooo
vanadLum I 292.t}z 0.0000000 I 0.0000000 o. oooooool 0.0000000 I 0.0001100
zine J zrS. BsE 0.0000000 | o. ooooooo 0.00000001 o-0o0oo0oI 0.0000000
Conunentt;
STL Denve
Eam \'T ,lllDnr Dl Tf,T
L32
STL DENVER
Total Metals Anatvsis
-llB-
ICP INTERELEMENT CORRECTION FACTOR^S (ANNUALLY)
eontract: IIRS Corrooration
Lab Code3 S,3.LDEN Case [Io - :
IntrepLd ICPICP rD !fiInber: TiIA DaEo: 8 llg l2OA5
gAg No. :SDe No-: D5I07O27A
Ana.lytc
Wava-
Langth
(nn)T1
Intarelcmcnt Correetion Faetorg
tv
f orr
Ztr Th
I 33e.1eB 0.0000000 | 0.0000000 o.00ooo0ol 0.0000000 | o. o319ooo
Alurnl-nun Irez.081 o.0000000 J o.0000000 o.oooooool 0.o0oooool 0.0000000
rlr:ml-num I309.27L 0.0000000 I o. ooooooo o. oooooool 0.0000000 I o. oooooo0
Autl;nony I 205.838 0.0000000 I o. ooooooo o. oooooool o. ooo0o0o I 0.0000000
r.rsenLc I ttg.042 o.0000000 I o.0000000 o. oooooool 0.0000000 I 0. ooo0ooo
sarl,um I ots. {03 0.0000000 [ o-0000000 0.00000001 o-oooooooI o,ooo3o3o
Bery'Lllun I af3 ,ALz 0,00ooo00 | o. 0000000 0.0003590J 0.0000000 I -0.0000100
Boron I 2{9.628 0.0000000 I 0.0000000 0.0000000J o, ooooooo l o. 0ooo00o
cadnium ll225. 502 0. 0000000 I -0,0002070 0.0000000] o. ooooooo I o. ooooooo
Calcl"urn ISfz.933 0.0000000 | 0.0000000 0.00oooo0l 0. ooo0o00 [ o. ooooooo
Calclunr J 318.128 0.0oooooo | 0.0000000 0.00000001 o. 000o0oo I o . 0ss9o oo/
Chromi.rrm 1267 -7 7.6 o.0000000 [ o-000?050 0.00000001 0.0000000 I -0.000592{
Coba1t, l|118.616 0.0000000 I o-0000000 o-oooooool o.oooooooI o-o0ooooo
copper I faC,?s3 0.0000000 I o-0008{20 0. ooooo0of o. ooooooo I 0. oo232oo
rron !zug-g{0 0-0000000 | o_0000000 o. oo0ooo0l o. oooooo0 J o - 0000000
rron lzz 1. d{1 o. oooo0o0 I 0.0000000 o. oooooool o. ooooooo I o. ooooooo
r,ead .220.353 0.00ooooo J o.0000000 o. o0oo000l o. ooooooo I o - 0000000
rithtum I 670 .7gtl 0.0000000 J o. 0000000 0.00000001 o. ooooooo l 0,0000000
MagrrrGrLurn Iz7g-o?9 0.0000000 I 0.0075600 0.00000001 0.0000000 I -0.0418000
Mangarrora l2s7 - 610 0.0000000 I 0.00 aL22a *0.00016801 0.0o0o0oo I 0.0000000
Molybd,eaum lzaz.030 0.0000000 I -0.0007050 0.00000001 0.0000000 I 0.0017500
Nr,ckeL l ,r 1. G Aa /2 o. ooooo00 I 0.0000000 o. ooooooo I o. ooooooo J o. ooooooo
phorpbotrus
J fza .zg?0-0000000 J 0.0000000 o . oooo0o0 I 0. 0000000 I 0. ooo00oo
PotasgLun l?55,491 0.0000000 I 0.0000000 o . ooooo0o I o. 0000000 I o. o00oo00
selenLum I 196. o90 0.0000000 | 0.0000000 0.00000001 o,o00oo0oI o-ooooo00
stlLcon I 25L.612 0.00ooooo I o-o00oo00 o. ooooooo l o, ooooooo l o. ooooooo
stll,con
I
,tl. G15 0.0000000 J o. oooo0oo o - oooooool o. ooooooo I o. ooooooo
silver I ,r8. 0OB 0.0000000 I -0.0002200 -0.01{90001 0. 0000000 | 0.0005880
sodlum I ssS. i9z o.oooo0o0 I 0.0000000 o-00000001 0.00000001 0.ooooooo
sodtum I arg,320 0 .0000000 I o. o00oooo o.o00oo0ol o.oooooool o.ooo0orr.
Btrontlum f aOz .iTL o.00o0o0o I 0.0000000 o. oo00o0ol o. ooooooo I o. ooo000(
Tlralllurn Ifgo.BG{0. oooo000 I 0.0000000 0.00oo0ool 0.0000000 I 0.00o0ooo
133
Comrrentg r
STL Denve
STT. DET{YER
Contract: URS Comoration
Total Metals Analvsis
-l18-
ICp TNTERELEMEM' C ORRE CTION l-A CTORS (A NNUALLY)
Cage No. t
rcP
gAg No.:
Datc: 8 lI9 lzAOs
Lab Codei SU,DEN
ICP ID lttrrnber: TifA Int.repl_d
gDc No.: D5f07A270
tnhorlum I 283,730 o. oooo00o I 0.0155000 0.00000001 0.00o0ooo I o. ooooooo
Tt n I ta9.9a9 0.0000000 I 0.0000000 o. oooooool o - ooooooo I o. o00o0o0
rl,tanium I rro.9{1 0.0000000 I o-0002850 o. oooooool 0.0oooooo I o. ooooo0o
uranium
1
385.958 o. ooooooo I o.00ooo00 0.0000000J o. ooooooo I -0.028?000
vanadLum lzlz.d02 o.0000000 I -0.0002{20 o.oooooo0l 0.00000001 o.0015600
zLnc Izrs-8s6 0.0000000 I o. o0oo000 0.00000001 o. ooooooo I 0.0000000
Co$mentg:
STL Denve 734
STL DENYER
Total Metals Analysis
-11A-
ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY)
Corrtfact 3 IIRS Cor,ooratioa
LaI) Code: gTfrDEN Cara No. r S.Lg Dlo - r
ICP ID lllrrnber: gUpERTR.[,eE DatG = 7 l23l20As
COrmorrto:
gDc NO- 3 D5f07 O27O
fnalft,e
Wave-
lengrth
(nm)AI.
Intcrelement Corrcetl,on ractorg
Ca Fe
for:
Mg Ag
Altrnrinun I 308.21S 0.0000000 I o. 0oooooo 0 .0001100 J o. 0000290 I o. ooooooo
rlrtlmow 12}6. 83g o. 0000000 J o. o0o00o0 0, oooo zeol o, ooooooo | 0. o00oooo
Arueaic I tug. o{2 o.000oooo I o-0000000 -o.00001501 0.0000000 I 0.0000000
Barium JCsf.{09 0,0ooooo0 | o. oo000o0 o-oo0000ol 0.00ooooo I 0.0000000
BeryllLum I eff .Od,z 0 - ooo0000 J o. oooooo0 0. 00ooooo I o. ooooooo I 0.0000000
Boron lrog - 628 0. 00ooooo J 0.0000000 -0.0000?001 0.0000000I o-ooo0000
Cadmirrm |,216. 504 0.0000000 I 0.0000000 0.0001{10l o-00000001 o-ooooooo
CalcLurn IfrS.g33 0.0000650 ! 0.0000000 0. oooooool o. ooooooo I o - ooooooo
ctrromirrn lzSZ -TLG 0.00oo0oo I o.0000ooo -0,00001001 0. o0ooooo I o. ooo0000
cobalr 1228.515 o.0000000 | o.00ooo0o o.00oooool o-oooo000 I o. ooooooo
copner lsel .7s3 0. 00oooo0 I o.0o0oooo -0.00002501 0. o0000to I 0. 00000 laa
rron lr27 1. {{1 0.0000000 | o.0000ooo o. o0oooool o. ooo3{oo I o. o0ooo0!
road lzro.3 iLtL o. oo02g70 | 0.0000000 o-00013001 o-ooooo50| o.000oooo
r-,ead I zzo.3sLtz -0.0001800 I o. ooo0000 o.ooo050ol 0.0000100I o-ooooooo
Magneglurn ,1279.078 0 - 0000000 | o. 0000000 0.00002?01 0.oooooo0l 0.0000000
Maaganoso lzst.610 0.0000000 I o. oooo000 -0, 0000060l o. oo0o200 I o. ooooooo
Molybdorlum J ZOZ.030 0. oooo000 I o.00ooooo -0.00001801 0.0000000I 0-0000000
rrrLckel lzE1.5Dtltz 0.0000000 | 0.0000000 0.00oooooI 0-oooooooI o-ooo0000
seleniurn Itg 6.AZL|L -0.0000030 I o .0000000 o. ooooo2ol o. o00oo40 I o. o0oo00o
seloniurn l196.o"Ltz 0.0000000 J o. 0o00ooo -0.00017801 0.0000000 1 0.0000000
gtlLcon
I zae.158 0.0000000 [ o-oooo0o0 o. ooooooof o. ooooooo I 0.0000000
sl.rvor lf rB.068 0.0000000 | o.0oooooo o. ooooooo I o. o0o0o0o I o. 0oooooo
srrontl,uur lt21 . 552 0. 00ooooo I o.0000000 o.00o00ool 0.0000000 I o. ooooooo
rhalllum I ag0. BE{0.0000000 | o. oooo0oo 0 - oooo950 l o. ooo0ooo l 0,0000000
TlrorLum 1401.910 0.0000000 I -0.00002s0 o. oooooo0l o. ooooo0o I 0.0000000
rin I re9-989 0 . 0000000 | o. 0000000 0.00000001 0.0000000 I o. ooo0ooo
ritanlum I 33{.9{1 0.0000000 I 0.0000000 o. oo00o00f o. oooo200 I 0.0000000
uranium I rt5.gsg o. oo0oo0o I -0.0000300 0.00086001 o. ooool{o I 0.000oooo
vanadium fztz.4oa o. oo000oo I 0.0000000 -0.0003{001 0.00000001 0.0000000
zinc I at3.8ic o. oo0000o I o.00ooooo 0.0000000[ 0.0000020 I o. 00000 00.
STL Denve
Dlas ltrf I t.tr rrrrr rl L
135
STL DEIVVER
Contractr: URS Conreoration
Total Metals Analvsis
-118-
ICP INTERELEMENT CORRE(:TION FACTORS (ANNTIALLY)
Cara No. :SAg No.:
Datez 7 /23l2AOs
Lab Codc i STLDEI{
rCP ID [Iumbar: STIPERIIR.LCE
SDc NO. : DSTO'I 027 O
wave-
leaOrttr
(mn)
rnt,erelement correctLon ractorg forr
BeAnal:tr.e cd,Ag B Ba
AlunLlnum 1308.215 0.0000000 | o.0ooo000 0.00000001 0.oooooool 0'0000000
rntinony I 205.838 0.0000000 I o. ooooooo o. oooooool o. ooooooo l o ' ooooooo
rrrcnic I 189 -042 0 .0000000 I o. o0o0o0o o. oooooool 0.0000000 1 0,0oo0ooo
BarLurn I lsa. {09 o. oooooo0 I 0.0000000 0.0o00oool o.0ooo000 I 0.0000000
nertrlLl.ust I 313.0{2 0. o0o00oo I 0.0000000 0, o000oool o. 0o00o0o J o. ooooooo
Boron l2tg.678 0.0oooooo I 0.0o0oooo o. oooooool o.0000000 I o. ooooooo
Cadnrlrrur 1116. 502 o. oo000o0 | o.00o0ooo o,ooo00ool o-ooooooo| 0.0000000
caleium
1 319-933 0. oo000o0 I o.0000000 0,00000001 o. ooooooo I o. ooooooo
Chrorntnnr lzil. 716 0.00ooooo ] o-0ooo0o0 0.00000001 o. ooooooo I 0. o0o0oo0
cobalr 1229.616 0.0000000 I 0.0oooooo -0-00120001 0.0000000 1 0.0000000
aCogner I g, 4 .7 33 0,0000000 I o. ooo0ooo 0.00000001 o. ooooooo J o, ooooooo
pron lrr 1. {{1 0.0000000 I o. ooooooo o. oooooool o. ooooooo l o, ooooooo
r.ead lzzo. 3 5 Lt L o. ooooooo | 0.0000000 o.oooooool o-oooooooI o,ooooooo
read lzzo-3s:-t2 0.0000000 I 0.0000000 0.00000001 o-oooooooJ o.ooooooo
Magncrlusr 127 9.0?8 o. ooo0000 [ o. ooo0000 0.00000001 o. ooooooo I o. ooooooo
Manganero lzst -61 0 0.0000000 I o.00o00oo 0. ooo00ool o. oooo0o0 I o. ooooooo
trolybdeBrrm I 202.030 0.00ooooo I o-ooooo00 o, ooooo0o[ o. ooooooo l o - 00ooooo
Nlckcr. lrgl.6aalz 0.0000000 I 0.0000000 0.00000001 0.0000000 J o. ooooooo
Sel.enLuur I 196.0?LlL 0.000oooo I 0.0000000 o.0ooooool o. oooo0oo I 0.0000000
selenLum l 196.0zl tZ 0.0000000 I o. ooo0000 o. oooooool o, ooooooo l o. ooooooo
stlieon lrt8.ls8 0.0000000 | 0.0000000 o. oooooool o. ooooooo I o. ooooooo
Si.lvcr I ga8 - 068 0.0000000 | o. 0000000 o-oooooool o-oooooool o.ooooooo
strontium ,1011.552 0.0000000 | o. 0000000 o.0o0ooool o. ooooooo I 0.0000000
Thalltusr I 190.861 o. oooo000 | 0.0000000 0.00000001 0,00000001 o.ooo0ooo
lrhorlum I lo L. g10 o.0000000 I o. oo0o000 0. o0ooooo! o. ooooo0o I o. o00o0oo
rl,n I 189.989 0.0000000 | o, oo0o0oo o - oooooool 0. oooooo0 I o. 0000000
ritanlum I ,r{.9{1 0.0000000 | 0.0000000 o . ooooooo
I
o. o0ooo0o [ 0, ooo0ooo
uranium I rg5.95B 0.0000000 | 0.0000000 o.ooooooof o.o00oo00l o.00o0oo0
vanadlusr l rrT-$02 0.0ooooo0 I 0.0000000 o. ooooooo I o. ooooooo I o. ooo0o0o
zine\l rit. es6 o. oo000o0 I o,0000000 o.ooooooof o.oooooooI o.ooo0000
135
Comuento:
STL Denve
STL DENVER
Contraet: TIRS Conroration
Total Metals Analvsis
-l tB-
rcP IIVTERELEMENT CORRECTION FACTORS (ANNUA LLY)
Cage slo. t gAg No. i
DaUct 'l /23 lzOOs
Lab Codes STLDEN
ICP ID Mrnber: SITPERTR.LCE
SDGI NO. : D5f 07 O27 A
ArrA,lfrt11
wa\ro-
lengrth
(nm)Co
fnterelement Corroetlon Factorr
Cr eu
for:
I,In Mo
rlumt"nurn 1308.21I 0,0000000 I o. o015oo0 o - oooooool 0.0000000 ! o. oos8soo
enrJ.mony I 206. 83I 0.0000000| o-0038900 0.00000001 o-0o0o0o0l -0.0055500
Argenic I,t9-0{2 0.0000000 | o,0oo1?oo o-oooooool o.000o0ooJ o.ooo31o0
earLum I493-aog 0.0000000 J 0.0000000 o. o0oooool 0. o0ooooo I o. oooooo0
Ber.1'IlLusr 1313-0{2 0.0oooooo I o.0000000 0. oo000o0l o. ooooooo I 0.0000000
Boron l^o9.6?8 0.0009800 I 0.0000000 0.0000000I o-oooooo0I 0.0000000
CadrrLrrsr 1226. 502 -o-ooa22o0I 0.0000000 0.00000001 o.000o0oo I o. ooooooo
Calcl,um lfrs-933 o.0000ooo I 0.0000000 0.00000001 o. ooooooo I o.0ooo0oo
Chromiurr lzit .7 LG o. oo000o0 | 0.0000000 0.0000000f o. o0ooooo I -o. o0o1?00
cobalr 1228.615 0. o0o0000 J o. o0o000o o. oooooool o. ooooooo I o. ooooooo
coDper I e, &.7s3 0.0000000 I 0. oo0o0oo o. oo0000ol 0.0000000 J o. 00000 ool
rron l27I- - 4{11 0.088eSoO I O.0030goo 0.00000001 o-oooooooI o.oooooo(
r,ead l2zo.3sL/L -0.0020{70 I o. ooo0ooo o. oo00oool 0.0000000 I -0. 0009600
Lead lzzo.3 5Lt2 0.00ooooo I 0.0000000 0.00000001 0.00oo0oo I -0.0002500
Magnesium lrr9.0Z8 0,0000000 I o.0oooo0o o. oo00o0o l 0. o00ooo0 l o, oooo0oo
Dlansanase lZSl. 610 o .0oooooo I 0.0000000 0.00000001 o. ooooooo I o. ooo0ooo
uolybdsDum IZOZ.030 0.o0oooooI o-o00oooo o - oooooool o. ooooooo I o. ooooooo
rtckel I 231.6 A4/2 -0.0006200 I 0.0000000 0.0000000f 0.0000000 J o. ooooooo
selenl,rrn 1195.02t1L 0.0005000 | o. ooooo0o o.oooooool o.ooo35oo I 0.0000000
sclenium Ift6.o2ltz -0.0001s00 I 0.0000000 o. oo00oool o. ooo22oo I o. ooooooo
silicon I 2gg.15g o. o0oo00o J 0.0000000 0.00000001 0.00000001 -0.00{3{00
sLrver l gz8.OGB 0 -0000000 I 0.0000000 o.ooo0oo0l o.oooooool o-ooooooo
strontlusr |.421 - 552 0-0000000 | 0.0000000 o.ooooooof o.oooooool o.ooooooo
rhalltum l1g0-85lt 0.0012 a,7a [ 0.0002900 0.00000001 -0.00{7700 J 0.0000000
TtrorLum lAoL.910 0.0000000 I o.0o00o0o o. oooo0ool o. ooso28o I o. oo0oooo
rin I aa9.989 0.0000000 I 0.0000000 o. ooo00ool o. ooooooo J o. ooooooo
titanLr:m Irr{.9d1 o.oo000ooI o-ooooooo o.ooooooof o. oooooo0 | 0.0000000
uranium I
gg5.95g 0.0000000 | 0.0007600 o.oooooo0l o.oooooool o.ooooooo
vanadLum l r9z.iLz o. ooo0000 I -0,0009?00 o. oooooool 0.0000000 I o. ooo0o0o
zLnc I rr3.855 0.0000000 I -0.0032900 0.0000000! o. ooooooo | 0.0000000,
Coumeutg:
STL Denve
STL DET\TVER
Contract: IIRS Cormoratlon
Total Metals Analvsis
-llB-
ICP INTE RE LEMENT CORRECTION FACTORS (A NNTIALLY)
Care No-:gAS No.3
Datot 7l23lzOAs
I.aI) Codtr 3 STITDEN
ICP ID Numbsr: SUPERTRACE
SDc No. : D5T07 027 O
Analrt,e
WAvo-
langrth
(nn)Ni
Iutorelement Correctlon Factorr
pb sb
for:
Se sl
.rlum,Lnum lgo8.zls o-0000000 J o-0000000 0.00000001 o.ooo000oI o.ooooo00
rntl"rnony I 205.938 0.0000000 I o. oo0oooo 0 .0ooooo0l 0.00ooooo I o. ooo0ooo
rrsenic 1189.A42 o. ooooooo I 0.0000000 o.ooooooof 0.00000001 0.ooooo00
sarlum Ilsr.d09 0.0000000 I o.0000000 0,00o0oool 0.0000000 I o.0oo0oo0
Ber1rl1l-rrrn ISfa .OA2 o,0000000 I o, oooo000 o. ooo0000l o.0oo00oo I o. ooooo00
Boron l2ag.6z8 0.0000000 I o. ooooooo o-o0oo0o0l 0.0000000I o-oooooo0
cadml,um lZZ5. 502 o-ooo00ooI o-ooo0o00 0 .0o0oooo I o. o0o0ooo I 0. oo00o0o
cal-eLum I 3 19.933 o-o0ooooo | 0.0000000 0.00000001 o.oooooool o-ooooooo
Chromirrm I 267 .TL6 0.0000000 ! o.0000000 0. oooooool 0.0000000 I o. oooooo0
cobalr 1229.615 0.000277a I o. o0o000o 0.00000001 0. ooooooo I 0.0oooooo
.coDDer If za.zs3 0.0000000 I 0.0000000 o.000ooool o. o00oooo I o. ooooooo
/rron lzr r. i{l o. o0ooooo I 0.0000000 0. o0ooooo I o. ooooooo I 0. o0ooooo
r,ead lzz0.3 sLlL -0.0001400 | 0.0000000 0. 00000001 -0.0000200 I -0.0001020
Lead |1220.3 5Lt2 0,00006{0 l 0.0000000 0.00000001 -0,0001{00 I -0.000037a
Magmegiunr lzr g. ozg 0.0000000 | 0.0000000 0.0000000J 0.0000000 1 0,0oooo00
ldangan€se lzsl. 610 0.0000000 | o. oooo0oo o-00000001 0.00ooooo I 0.0oooooo
Uolr'bdenum ]ZOZ. 03 0 0.0000000 [ o. o0ooo0o o-oooooool o.oooooo0I o-ooooooo
Nt"ckel 1231,6O1t2 0.0000000 | o. o0ooooo 0.00000001 0,0000000f o-oooooo0
Seleniurn I 195.02LtL o. oo00oo0 I 0.0000000 0.00000001 o. o0000oo I o. o0o1ooo
sclenium I 196.02 Lt2 0.0000000 I o. ooo0000 o.00000001 0.0000000 | 0.0oooooo
gtllcon
I aa8,15g 0.0000000 I 0.0000000 0.00000001 o.0oooooo I o. ooooooo
sllvar I 329.069 0.0000000 I o.0000ooo o. ooo00ool o. ooooo00 l o - oooo000
Strontl"un I Or1- 552 o.oo0oooo ! 0.0000000 o. ooooooof o. ooooooo I o. ooooooo
rhalllum l tto. BG{0-o00oo0oI 0.0000000 o. ooooooof o - ooooooo I o. ooooooo
Thorluur I401.910 0.0000000 I -0.000{200 o. oooooool o. ooooooo I o. ooooooo
rln I rr9-999 0.0000000 I o. o000oo0 0.0ooooool o.oooooooJ 0.0000000
TitanLum I,r{.9{1 0.0000000 | 0.0000000 0.00000001 o. oooooo0 I o. oo00o0o
uranl,um I le5.95g 0.0000000 | 0.0000000 o. ooooooof 0.0000000 | o. oooooo0
varradium lrgZ.l}z 0.0000000 [ o. ooooooo o.oooooool o.0o00oo0[ o.ooo0ooo
zlnc\fzir. ase 0.0oooo00 I o, oooo0o0 o. oooooool o. oooooo0 I 0.0000000
Comnents:
STL Denve
STL DENVER
Contract: IIRS Cormoratlon
Total Metals Analvsis
-llB-
I C P INTERELEMENT C ORREC TION F A C TOR^S (A NNUALLY)
Care No. t SIS No. t
Date: 7 123/2OAs
Lab Codct STLDEN
ICP ID Numberr SUPERTRACE
SDc NO- r D5I07 O27 O
wavo-
lcngrth
(nn)
fnterelemont Correctlon Factorg for:
AnaIyEe Ti T1 u8nSr
Alumlnum I 3 08.215 0. 00ooo00 I 0.0000000 0.00000001 0.0000000 I -0 - 001d00o
tnt,imony I?05.83I 0.000oooo J o-oooo0oo 0, ooooooof o. 000o0oo I 0 - oooooo0
Arrcnie I 189.O12 0.0000000 I o. ooooooo 0.ooooooof o. oooo00o I 0.00ooooo
sarir:n [ 493. {09 o - 0000000 I 0. 0o000oo 0.00000001 0.0ooooooI o-oooo000
Bcl:vLlLr:m f afa .O$2 0.0000000 | 0.0000000 o - oooooool o. oooo0oo I o. ooo0ooo
Boron lro9.6z8 0.0000000 J o. o0ooooo 0 ,0000000[ o. ooooo00 I o. 0000000
Cadmlum 1?,25. 5oz 0.0000000 I o. ooooooo o.00o0oool 0.0ooooooJ o-ooooo00
carclurn lfrS.933 0, o0ooo00 ] 0.0000000 0.00000001 o. oooooo0 | o. o0310oo
chrornlum lzdZ .7L5 0.0000000 | 0.0000000 o-0000000] o.oooo000 l 0.0004100
cobalr l1228.516 o, o0000oo I 0.0000000 o-oo2&400l o.0oooo00J o-0000960
coppar I fza.?53 0.0000000 J o-o0oo00o 0.00000001 0.0000000 I o.00053 oo/
rron lrrt. {{1 o.ooo0000 I 0-0000000 o - 0000000 ! o.0000000 I -0. oo2{00!
r,ead. lzzo . 3 sll L 0.0000000 | o. ooooooo o. oooooool o. ooooooo I o - oolooSo
r,ead ll220.3 5Ll2 0. o000oo0 I 0.0oooooo 0.ooooooot * ooo0o00 l o. 0014600
Magrnesium l,27 9.078 0.0000000 I 0.0000000 0.00000001 0.0000000 I -0.01{11000
t'Iangranaro lZSl.510 0.0000000 I 0. ooooooo o. oo0oooor o. ooooooo l o ' 0001300
Molybdarrum I aOa.03O o.ooo0o00 I o-0000000 o - ooo000o[ o.0000000 I -0.0002100
nlckcl 1 23L.6A412 0. oooo000 I 0. o0ooooo 0.00oo0oo[- -o - 00091100 [ o.000o0oo
flelenl-urn Its6.ozllL 0.0000000 I o. oooooo0 o.oooooool o.ooooooo I o.ooooSoo
solonlum lrg6.02Lt2 0.0000000 I o.00oo0o0 o . ooooo0o I o. ooooo00 I 0.0000000
st-ILeon I 288.158 0-0312600 I o.0000000 o. ooaBooo[ o. ooooooo I o. ooo8{oo
sLlvcr I ,r8.068 0.0000000 [ 0.0000000 o-ooooooo] o-oooo00oI o.0ooe3oo
stront,lum I Ar1. 552 o, ooooooo J o. ooooooo o. ooooooof o - ooooooo I o. ooooooo
lrhalltum I 190,864 0.0000000 ] 0.0000000 o-00000001 o.oooooooI o-oooo000
thorLum I oo1- 910 0. oooo000 J o.0o00ooo o. oooooool o. ooooooo I o. oo233oo
rLn I ,a9.989 0. o0o0ooo I o.00o00oo 0.0000000[-0.0000000 J 0.0000000
rLtanLum
1
rr4.961 o. oooo000 | o. oo0ooo0 o. ooooooof o. ooooooo I o. ooo3ooo
uranLum l ggs. gs8 0.0000000 I 0.0000000 o . ooooooo I o. ooooooo I o. ooooooo
vanad,ium IZSZ - {Az 0.0000000 I o. ooooooo 0.0 oo6z00f 0.0000000 I -0.0000500
zlnc I zrr. Bs6 0.0000000I o-oooo000 o. ooo00oo l o. ooooooo l 0. 00ooooo
Efa- lt.r , r1r Drtt a \'rrI
Comnentg:
STL Denve
STL DENYER
Cont.raet r IIRS Corloorat'l-on
Total Metals Analvsis
-l1B-
ICP INTERELEMENT CORRECTION FACTORS (ANI\ruALLY)
Casg No. :srg t\b. r
Date: 7 l23l20Os
Lab Coda: STITDEN
ICP ID hhrmber: EUPERI]R.LCE
gDG NO. r D5TO7O27O
Irlave-
lengrth
(nm)
rnterelement Correctl.on ractorg for r
RnaLlt,a v Zn Ttr
rlumLnuun I 308.21S 0.02L6700 I 0.0000000 0.05051001
Antimony | ,06.838 o. oo0ooo0 I 0. 0000000 o - oooooo0l
rreenic I 189.042 0.0000000 [ 0.0000000 o - ooooooo I
sarlum I lsf.409 o. ooooo00 | o.0oo00o0 o . ooooooo I
Bcr:rrl.lium I era.0{2 0. o0o18oo | 0.0000000 o , ooooooo I
Boron lzag.6?B 0.0000000 I 0.0000000 o . oooo2oo I
Cadmiun I 326.502 0. ooooooo I 0.0000000 o . ooooooo I
CalcLrrru I 319.933 0 - 0000000 | o. 0oooooo -0 . 00177 0o I
chromium IZeZ .7!6 0.0000000 | 0.0000000 o. oooo0o0 I
cobalt 1?,28.615 o. ooo0000 I 0.0000000 o . ooooooo I
aCoDDer I err - zs3 0.0000000 I 0.0000000 0 . oo215o0 I
[ron lzl1. {{1 -o - 53{ZSOO | 0. o000o0o o.oa4576ol
Lead lzz0.3 sttL o. ooooooo I 0.0000000 -0. oo3s6oo I
read lzzo.3 sl tz -0,0003200 J o- 0000000 o - oooooool
I,Iagncrium lZlg-0?8 0,00ooooo I 0.0000000 o. ooooooo I
Mangarr6rc lzsz.610 0.0000000 | o-ooooo00 o, ooooooo l
MolybdGnuln I,Oz. o30 0.0o0oooo I 0.0000000 o . ooooooo I
nlckel I 2s1.5 04t2 o-000oooo | 0.0000000 o. oooooool
Sclanirrm ltr6.02LtL 0.0002100 I o. 0000000 -0. 02793ool
gelenLrrn 1195.02Lt2 0.0000000 I o.0000000 -o . ooo2{oo I
sillcon I 2gg.15g 0.0000000 | o.0000000 0 . 0oo0? 00 I
silver I ,rB.oGB o. ooooooo I 0.0000000 o.ooo3{90l
Strontt urn l $21 . I52 o.0000000 I 0.0000000 o . ooooooo I
Thallturt I f 90.864 0.0011?00 I o.0000000 -0. ooo17o0 I
rhorlurn I{01.9L0 0,0002000 I o.ooooooo o . ooooooo I
rr.n I 199.989 0.0000000 | o. ooooooo -o. ooo3aoo I
ritanl,ust lrrd.e41 0.0000000 I 0.0000000 o . ooooooo I
uraniurn l3B5-958 -0.0090700 I 0.0000000 o . ool2ooo I
vanadium lzlz.4Oz 0.0000000 I 0.0000000 o. oooSgoo I
zinc I a13.856 0.0000000 I 0.0000000 o.0oo093ol
tltas arq? , ttr tt}lt O I
14 0
Comentsl
STL Denve
STL DENYER
ConEraet:
fral, Codrr r SrLDEN Crrc No. I
ICP ID N\unbcr r Tim. fntropid ICP
Total Metals Analvsis
-12-
ICP LINEAR ITANGES (QUARTERLY)
gtr'S No. I
Dater I lLGlzAAs
sDo No. : D5f07 A27O
IIRS Corpontion
Ln,r].ytc
IDfcgf .
rl-mr
(EIcs. )
Concentsrati.on
(ms /L)M
Jlfuminum t o I 50. 00 Jr I
Inluninum Hi I 20.00 1000 Ir I
l Celciunr Lo 20.00 50 ln I
f erloiusr HL 20.00 2000 lr I
I rron Lo 20-00 lr I
I rron Ht 20,00 2000 fr I
J Potacriua,20.00 500 In I
llr.grrrlslum 20. oo 2000
Sodium lro 20.00 10
EodLum 20. O0 10000
Zireonl-rrrn
CormerttB:
STL Denver fom xIr I}I 1_47
STL DETWER
O
Con
frab
ICP
trract,:
Code:STI,DEN Crtc tilo. r
t RS Cor.1>orrtLon
Total Metals Analvsis
-12-
ICP LINEAR R,A.NGES (QUARI'ERLY)
gAg No- r
Drttl t 7 l22l2t$s
SDGI No. r D5IO7 O27 O
ID liftr.rrbcr:SUPERTN.}.CE
rrrallt,c
fntcg -
Tl.mc
(Sco. )
Conocntsratrl,on
(nglL)
!,I
lnraanJ.c 15.00 I 20 Jr
laeriurn 15.00 I 25 Ir
IChronium 1s. oo I 50 Jr
J Coppcr 15-oo I 50 Ir
I Laad 1s.0o I 100 Ir
I Ntckel 1s. oo I s0 Ie
I Silvar x.s.oo I
IVanadLrrm rs. o0 I
Jztuo 15.00 I
,mnfOnte r
STL Denver Fom xrr IN 1,42
STLDENYER
Total Metals Analvsis
-12-
ICP LINEAR RANGES (QUARTERLY)
Contract,: IIRS CorSroratLon
frab Codc: STLDEN
ICP rD ![trnbert pE ICpI*IS
Crrr lk,. r S.f,S \Io. t
Detc r
Dsr07 0 27 0
8trg t2005
.LrraLytc
Intrg.
rLmc
(Sec - )
ConcratsntLoa
(nglL,)![
lcadmfu:m 0,001 Ju
Isclanl-un o. o01 lul
Couurantrg:
STL Denver Foru IIII - XN
STLDENWR
Total Metals Analvsis
13-
PREPARATION LOG
Cootrrct, r
Lab Codcr
Mrthodr P
t RS Corpontion
STITDtN Cagc No,:g.Ag N(r - r SDo NO. : D5 TO7 O27 O
Prcp McthodI
Eampla fD Prrrpr.ratlon Date
Ini-tial Volurnc I rinal
I volurnc (ruL)
GW-81,- 09050 5 9t23/200s 50.0 I 50.0
Grr-88-090605 9/23/200s 50.0 I 50.0
cnu-7A- 09 0 60 5 9 lz3 I 200s 50.0 I 50.0
fhITRA-LAB QC 9 1"312005 50.0 I 50.0
IrAB ItlS 9123 1200s 50.0 I s0.0
I,}B MSD 9/231200s 50.0 I s0-0
M8526s251 9 l23lz00s 50. o t 50.0
CIIECK S.LIVIPT.E 9/?3/200s 50.0 I s0.0
Conuucatg:
STL Denver
?orm XffI fll
L44
STL DENYER
Total Metals Analvsis
r3-
PREPARATION LOG
Contracb:
Lrab Code :
Matlrod.:
URg Cora>oratlon
gTfrDEN Caes No. :gAg No. r
Prop Method:
D5r07 0 27 A
Saqp].e ID Prcparatlon Date
Inibial Vo1uma I E'l'nnl
I vo1ume (nI')
GW- 81,- Og 0 60 5 s t2L/2005 10.0 I r0.o
g{-8.},-090505 MS 9lzl/ZOO5 10,o I ro-o
G"$[-8A-090605 MgD 9 t2L/2005 10.0 I r0. o
GTU-88-09 0 605 elzll2005 10.0 I 10,0
G[iI-7A- 09 0 605 9 t2Lt2005 10.0 I 10.0
M85259{2s elzll200s 10.o I 10-O
CHECK S}!,IPLE 9l2L/200s 10.0 I t0, o
DUPLIEtrTE CIIECK 9 lzll200s 10.0 I 10.0
Comncnts:
STL Denver
Ponn XIII IN
STL DEIVYER
Total Metals Analvsis
,t3-
PREPARATION I,OG
Cont,nct r
LrL Coda:
Mcthod:
IIRS CorDorrtl,on
STLDEN Caga No-:8fg No. r gDC ![O. : D5LA7 0270
ProD Method:
Sarqple rD PrcparaBLon Date
fnitiel Voluma J rLnrl'
I volumc (mr,)
Glr-8.n-ogo505 9 123 / 200s 50.0 I 50.0
GliI-88-090605 9 t231200s 50.0 I 50.0
GW-7A-090605 912312005 50.0 I 50.0
fllTnn'-IrAB Qe 9 t23 /2005 50,0 I so,o
LAB Ug s/23t2005 sCI.O I 50.O
T,AB IilSD 91231200s 50.0 I so.o
MBs265180 912312005 50,0 I 50.0
CIIICK SAMPLE e /231200s 50.0 I 50.0
ComtanLs:
STL Denver forrr XrII IN L46
STL DENYER
Total Metals Analvsis
-14-
AI\ALYSHRTINLOG
Contract r
f,ab Code:
fnatrrrmant
Btrrt, Datc:
XrRg Corporation
gTLDTBI
ID Nurubcr r
e /23 t2005
Cn;c No. t
f.71, fntroptd
gJ[g No.:
End Datse:912{/200s
EDGI No. r D5I07 O27 O
ICP
ga'rDlc
ID.DIr T:[mc e6R
Analrtes
B tlr M
o
o
I
P
D
P Pr ar 'Pl :F l"l'l;ih"rl
Std].-Bhnk 1. O0 11r{2 x
IC.nI,1-1. ool LLt 47 x
IC}I,2 1. ooi 11:51
ICAI,I'1. O0 11: 55 x
IETL2 1. OO 11:59 x
Ig\III 1. O0 12: O{
ICtltr 1. O0 12: OB x
Cg\ruI 1. od 12r13
ccvr,1. 00 LZ tL7 x
ICB 1. O0 LZt22 x
RLgTD2 1. O0 12r26 x
ICSA 1. O0 12:30 x
ICSAB 1. O0 12:35 x
CCUH 1. O0 12: {O !
CCML 1. OO L2:44 x
CCB 1. O0 Lz^t49 x
CgtIH 1. O0 23r23
cg\rrl 1. O0 23:28 x
ccB 1- OO 23 =32
x
ZZZZZZ 1.00 23 236
MBs265261 1- O0 23r{1 x
CHECK SA}IPLE 1.00 ?3t{6 x
zDsI0802{3- O0,l 1. O0 23:50
zDsr 08 0243 - OO{L 5. o0 23:55
2D5r0802{3-OOds 1.00 O0:00
T.Dsr08 0243-OO4SD 1.O0 00r05
G:rfl-8A-090605 1. O0 OOr].0 x
cer- 88- 09 0605 1. o0 O0t1{x
7,D5r07 027 0-00{1. 00 00r19
CeIfII 1- 00 00:2[
CC'\[J 1.00 00r?9 x
ccB 1- 0d 00:33 x
STL Denver form XfV IN 148
ST'L DE|VVER
Total M.:ils Analvsls
AI.IALYS$ RUN LOGO
Contract:
f,ab Code:
In;t::urncnt
Strart Date:
IIRS CorSroratLon
STLDEN
ID l[\rnber:
e /23 12005
Cagc No.:
TJA INtrCDid ICP
sl.ng No. :
Mctbodr
rnd DaEcr 9/2ll2AO5
SDO No. r D5IO7O27O
SarpIe
ID.
DIY Tl"rua %R
en^alrtes
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Std1--shnk 1. O0 11:42 x x x x x x
IeALI 1. OO 11r47 x x x x x x
IClI,2 1. oo 11: 51 x x x x
IEe'L]"1. OO 11r55 x x x x x x
IGB.Ir2 1. O0 11r59 x x x x x x
IC1NI 1, OO 12rO4 x x x x
IEUL 1. OO 12r08 x x x x x x
CC-TTH 1. 00 12 :13 x x x x
Cg\,lL 1. OO L2 =L7 x x x x x x
ICB 1. OO LZ t27 x x x x x x
RLgTD2 1. OO L2:26 x x x x x x
res.f,1- OO 12:3O x x x x x x
ICgAB 1. O0 12:35 x x x x x x
CC'\III 1. OO 12:{0 x x x x
CC\TL 1. OO LZzl4 x x x x x x
CCB 1. 00 12: {9 x x x x x x
cguH 1. OO 23 223 x x x x
CC\II.1. 00 23:28 x x x x x x
CCB 1. O0 23:32 x x x x x x
Z,ZZZTTZ 1. OO 23 r 36
M8526526L 1. 00 23:41 x x x x x x
C}IECK s.f,MPLE 1. 00 23:{6'x x x x x x
zD5ro802{3-OO{1.00 23 :50
2D5ro8(}243 - Oo{L 5. O0 23:55
2D5r080243 - OOlrs 1. 00 00r00
zD5rO802{3-004SD 1.00 0O: 05
GII{-8n -09 0 605 1. 00 00r10 x x x x x x
m-gB-090505 1.00 00:11 x ]t It rt I T
zDsr070270-00{1. 00 00:19
cc-lnt 1. O0 00:2{x x x x
Cg\rl,1. 00 00 r 29 x x x x x x
CCB 1. 00 00:33 x x x x x x
| - Da[otas edllitioaal al.ra&t. (otber tLru the stmal,aril CIiP elm6uto) rre r6Dre6eat.dl olr a.r'oth.t FoEr la
STL Denver
Eranrt YTlt - Tlt
1_47
ST'L DENVER
Total *-lils Analvsis
ANALYSN RI]NLOG
Contract:
Lab Codrrr
InetrarrB.nt
8trart Datc:
t RS Corporatlou
STLDEN
ID Nunber:
912612005
Cagc No,:
Tirr, rntrcPid IcP
SJtg No. :
Mcttrod;
End Datser 9 127 l20As
gDct No. r D5I07 A27 A
Sary>l-c
ID.
Dlt timc trR
Analtr[6a
l"lil:
SEdl-Blenk 1.00 09:{1 x x x x x x
IEEL1 1 .00 09: O5 x x x x x x
rcr,L2 1- OO 09r50 x x x x
ICII,I.1- 00 O9t53 x x x x x,x
ICTI,z 1. O0 O9:57 x x x x x x
ICVH 1. O0 1O: O2 x x x I t x
rc\I[,1- OO 1OrO5 x x x x x x
Cg\IH 1- O0 10: L1 x x x x
CC\If,1- O0 1O:15 x x x x x x
ICB 1- OO 1Or2O x x x x x x
RI,gTD2 1. OO 1Or24 x x x x x x
rCAA 1- OO l-O r 29 x x x x x x
ICSJI]B 1. O0 1O:3{x x x x x x
cgwr 1. OO 10:39 x x x x
cgur.'1. O0 1O:43 x x x x x x
ceB 1. O0 1O: l8 x x x x x x
CE\IH 1. O0 22 t&O x x x x
eeul,1, OO 27 t 114 x x x x x x
cgB 1. OO ?2t19 x x x x x x
zzzzzz 1- OO 22 253
zzzzzz,1.00 22:58 -l
zz7.z7.z 1. O0 23 :03
zz7,zz7,1. O0 23r07
7'Zz7r7r7r 1. OO ?3t12
zT.zzzz 1- OO 23 tL7
7,Z7,ZZZ 1. O0 23 tZL
T.Z7.Z7'Z 1, 00 23 =26
-l l
IMNA-LIB OC 5. 00 l}10 I T I I I I
INTRA-I.AB OC SER 5. 00 23:35 x x x x x x
CC,\TH 1. 00 23r39 x x x x
CgvIL 1. 00 ?3t44 x x x x x x I
CCB 1. 00 23:{9 x x x x x x t
Lf,B MS 5. O0 23r5{x x x x x x
I - DoDot.. additlqal .I@eDts (otbor thrn tho ttaldard. cLP clc!6at8) a.r6 roDreBotrtsd ou anothor roru 1l
TL Denver L49
STL DEIVVER
Total M-llls Analvsis
ANALYSIS RUN LO(;
Cont,rrct, r
IrrL Codc r
Ingtnrnont
St,art Datc r
IIRS Corporation
STIJDEN
ID Number:
el26/200s
Caga No.:
Tiftr Introptd ICP
g.LS No, ;
urtlrod, r
Erd Drte; 9/27 l?OOs
SDG} No. r D5IO7 O27 O
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z7,z7,zz 10-o0 OOr28
CCl/H 1.00 00 :33 x x x x
CgVL 1. 00 OOr38 x x x x x x
CCB 1.00 OAzL2 x x x x x x
t llcDotct addl.tlonal elementg (otb,or tbau the otardard CLP
STL Denver
Font
rlrurntr) aro rrDrurntod
XI\I It{
ou anothrr Pon 1{
150
STL DENYER
Total Metals Analvsis
- I4-
A}IALYSIS RTJN LOG
Contract:
L6b Coder
fnstnrtrlent
Sltart Dato r
URS Corlrcratton
Sff,DEBI
fD Numbarr
e l26/2005
Clac No. t
TJA Intrcpid
SAS No. t
Mathod: P
End Drtcr 9 lZ7 l?AOs
sDo No. r D5TO7O27A
ICP
Bamp]-e
ID.Dlr TLne tsR
.hnrl.ytcr
B A
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M
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P
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Stdl-Bl-ank 1. ool O9r41 x
ICAIJl 1, Ool O9 :45 x
ICAIJ2 1, O0 O9r5O
IC3I,1 1. O0 O9r53 x
IC}I,2 1. O0 O9:57 x
Igtrll 1. o0 1OrO2
IC\ITJ 1.00 10: 06 x
CC1NT 1. Ool 10r11
cglrr,1. O0 1OrL5 x
ICB 1. O0 1O:2O x
RL-gTD2 1. O0 LA t2/A x
ICEA 1. O0 1Or29 x
rcg.tr3 1. O0 1O:34 x
CSIIH x.o0 1O:39 I
CCTL 1- O0 10r43 x
ccB 1- O0 1Or48 x
cg\nr 1. 00 22r4O
CCUL 1. O0 22r{l x
CCB 1. O0 27ti49 x
zzzT.zz 1, OO 22 t53
zzzzT,z 1- Oq 22:58
Z,?r7.ZZZ 1- 0d 23r03
ZZZZ7.7,1. O0 73t47
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zzzzr.z 1.0d 23 =L7
7,ZZZZ7,1. O0 23 tZL
Z7,7,Z7,Z 1.00 23 :26
ITiITRA-LAB QC 5. O0 23 r 3O x
rrilfRA-r*B oc gER s-0d 23r35 x
ecur 1. 00 23:39
cclrl 1. Ool 23 244 x
CCB 1. ool ?3:{9 x
LAB MS 5. 00 23:51 x I
f,AB !,ISD 5.00 23r59 x t
STL Denver Fom XIV IN 151
STL DENVER
O"D.traotr
Irab Codr r gTtrDEDil
Inrtrrrmcnt, fD llirnbcr :
8tsnrt Drttrr 9126lzAOs
t Rg Cor:poratioa
Totsl Metals Analvsis
-14-
AI{ALYSH RTINLOG
Cagc No. r
TJJL Intrc1ltd
grg DIo. :
McEtrod t P
Erd Drt,rt glZl/?AOs
SrXl No- r D5f O7O27 O
IEP
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ID.DIF Tina e6R
Anal.ytar
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o$it*7r-o90505 10-Od OOrO{Ix
ZW,ZZZ 5 .00 OO: 09
ZZZT.ZZ 10-o0 OOt1.{
"*7rZ7rZZ
10. oc 0O:18
z7.7,ZZZ 10. o0 OOr23
zzzzz,z 10.0c 0Or28
cc'\m 1.0(OO:33
cs\rrr 1.00 0O: 38 x
ecB 1-00 OO: {2 x
STL Denver For:n XMN L52
STL DENVER
Total *-]if Analvsis
AI{ALYS$ RUN LOG
Contract:
Lrb Codc:
fnetrnrrrent
Strrt Datc:
IrRg CorporatLon
* Donottr tddltloaal 6fanron!,1 (other than the
STL Denver
Slg No- :
McEhodt
End, Drt,rr 9 127 lz00s
sErrdrrd qLP oltuentc) are rrgr.r.nErd on aaotber troro 1l
STLDEN
ID $hunber:
el26l200s
Carc No.:
SUPERTNTCE
sDe No-: D5I070270
grynff g
ID.
D/F 'fi-mc e5R
fnrl.ytrcr
T
IJ
g
B
I.
s
B
.er
B
F
c
D
c
L
c
R
e
o
c
U
r
t
plu
"l o
u
N
E
o I["g
t ^[.
o
N
.[,Il"z
N
c
N
STDL-Bhnk 1. OO 11r55 x x x x x xl x x x
HISflTD 1. OO 12rO1 x x x x x x x x x
HTGH 1-o0 12r06 x x x x x xl x x x
IC\'lf 1. OO L2 21,2 x x x x x xl x x x
ecur 1. OO LZ zL7 x x x x x x x x x
ICB 1- oo LZ t23 x x x x x x x x x
RfJS|[D 1. O0 L2:28 x x x x x xl x x x
ICA.L 1. OO 12r33 x x x x x x x x x
rCEIAB 1.O0 12 :39 x x x x x x x x x
tR 1. O0 LZz4{;x x x x x x x x x
ccvtr J1 1. OO 12r50 x x x x x x x x x
ccBl1.1- OO 12r55 x x x x x xl x x x
CC'\,? [ZC 1. OO O9r05 x x x x x x x x x
ccur lze 1- O0 O9r10 x x x x x xl x x x
ccB I ze 1. OO O9a15 x x x x x xl x x x
!lrB52 652 6L 1. OO O9t23 x x x x x x x x x
CITTCK A.LIIPLE 1. Oo O9r28 x x x x x x x x x
@r-8A-090505 t-oo O9r33 x x x x x x x x x
G',II-88-090605 1- O0 O9r38 x x x x x x x x x
Gw-71- 090605 1. OO 09rC3 x x x x x x x x x
zzT.7.zz 1. o0 09 r48
Z7,7rT.ZrZ 1. O0 O9:53
z,27,7,7,n 1. OO 09r58
ccv\r lzt 1.O0 1O: O3 x x x x x x x x x
qcts lzt 1..00 1O: 08 x x x x x x x x x
ITiITRA-IrnB QC 1. oo 10r12 x x x x x x x x x
rr\ITRn'-LLB AC SER 5. 00 10:17 x x x x x x x x x
IrtB MS 1. 00 7Afi}I I I I I rl rl I I I
LAB MSD 1. 00 L0 t27 x x x x x xl x x x
zz7.z7.T,1. 00 1O:32
7,ZZZZ7.1.00 10:37 I I
7,27,,2717,1. 00 10r{2 T
7.27.f,27.1. 00 10r{7
Erarrr tl?lt "fN
153
STL DENVER
Total M.]1}s Analvsis
ANALYSIS RT]N LOGo
Contsract:
Irab Cod.c r
Ilrgtrannont,
Etart Drtcr
t RS Cor5>oratLon
STLDT![
fD lllrrnbcr r
9 126 1200s
Caee No.:
SUPIIRTR.N,CE
gJtS f,lo. l
Motbodr
SDO No. r D5TO7A27A
P
I Drnotce addit,lonal olrucntr
STL Denver
Ead, Date : 9127 lz00s
(obhrr tbarr th. rtaadrrd CLD elshonts) rre rGDresentod on euotber Sort Ia
gample
ID.
Dlr TLma e6R
.Lnal1te g
.L
L
g
B
A
g
B
L ;I;I;I ;C
o
c
u ;l;l xJr
H
G}
N
r
K s
E
t'
G
N
A
T
IT
v Z
N
C
N
csur I za 1- OO 1Or52 x x lx x l*l x x xlx
crB Izg 1.00 10:57 x x Ix x lxl x x l*l*
Forror XMN
L54
STL DEIYVER
Total M-lils Analvsls
ANAI,YSIS RI.IN I,OG
Contract:
Leb Codcr
Ingt,nrracat
Slt,rrt Datre r
t Rg Corporatlon
STI,DEN
ID }Iumber:
9 1a]-t2005
Crge No. r
PE SVA.A
gAB No. t
MeElrod I
EDd Darcr 9 /2Ll2OO5
gDc No- : D5IO1A27O
cv
Sarp1tr
ID.
DIT Tlmlr %R
fnll.ytrc;
rl ilrl
Calib BLrnk 1. OO 15:56 x
0.2 Irpb 1.00 15r5E x
O-5 I>Ilb 1. OO 15tOO x
1.O 1rpb 1. OO 15rO1 x
2.O DDb 1.00 15rO3 x
5. O llllb 1- OO 16rO5 x
1O-O rlpb 1. OO 15r07 x I
IEB 1. OO 16: O9 x
IC"V 1.00 15:11 x
cg\,:t 1. OO 15r12 x
CCB1.1. O0 16s1{x l-
RL 1- OO 16r16 x ll
7,7,ZZZZ 1. Oo 15r17
zzzzzT,1. O0 16:19
T,ZZZZZ 1- OO LG tZL
zz7,zz7,1. OO 15:22
ZZZZZZ 1. O0 16r24
zzzT,zz 1. O0 16926
7.7i7.7.7r7,1- OO LG r27 I I
T.7,7.ZZZ 1. O0 16r29
7127127.7.1, O0 16:31
ec'\12 1- OO 15r33 x
CCB2 1- O0 16r34 x -l
CC.Y5 1- 00 L7 254 x
c-eB6 1 .00 17 :55 x
T.7.fr7r7.7t 1. O0 17 r57 I
zzzzT.z 1. o0 17r59
7r7'T,Z\7,1. 00 18r00
7r27,7.7,,2,1- 00 18:02
Z,ZZ"Y.Z,Zt 1. 00 18r0{I -l
DrBs259{25 1.00 18:05 x V
CHECK TUPLE 1.00 18: 07 x !
DIIPITICLTI CIIECK 1. 00 18:09 x
r - D.alotoB additiod olmtr (othcr tbB th. ,Ualdrral gLD eI6.Dt!) ar. r.Draa.trtao oil anothar pon ,.a
STL Denver
Fa*rr .tfTlt Tlt
155
STL DENVER
Total M"lils Anslvsis
ANALYSERTIN LOG
Contract r
Lab Codcr
Inttnrment
Starts Detet
t Rg Corporatl,on
STLDEN
ID Nurubcr r
9 /2Lt200s
Caee No. r
PE gIITI'
S.[A No,:
Method.:
Eud Datc: 9 l2L/2005
gDO No.: D5f07O27O
Cv
t Dcaotes addltion"al elements
STL Denver
ehnoate) rro
vrrr Ytt
8en1r1c
rD-
DIT Tinc ,6R
A.naIIrte g
.L
L
a
B
A
g
B
A
B
E
c
D
c
.L
c
R
C
o
e
u
r
E
P
B
!,
G
M
N :lr "l:.lr
c
N
A
T
L
v z
N
C
N
7.7.27.27r 1- O0 18r11
zzzzzz 1- oo LBt12
cc\r,1. 00 18 :14 x
CCBT 1. O0 18r16 x
7.L7.7'7t7t 1. 00 18:17
71742,7.1,7.1- OO 18r19
Z7,7r7rZZ 1. OO 18r21
T,ZZZzz 1. OO LB t2?,
7rZZ7'7'Z 1. O0 18:2{
zzzzzz,1- O0 18:25
zzzT,zz 1. 00 LB z2'I l-
I
zzzzzz 1- O0 18:29
7,ZZZ7.T,1- O0 18:30
Z7,ZZZ7.1. OO 18r32
Cg\IB 1" 00 18 :34 x
CCBE 1. O0 18:35 x
GM-8r.-O90605 1. oo 18r37 x
gw-8r-o90605 Ms 1. OO 18r39 x
GTU-8e-O90605 lrsrD 1. O0 18 :41 x
crw-88-090505 1. OO 18r42 x
cmr-7A-090605 1. O0 18:4{x
ZZ7'7'ZZ 1- oo 18rd6
7rZ7r7.ZZ 1. oo 18r47
zzzzzz 1- OO LBr49
zzzzz,z 1. OO 18:51
zzzzzz 1. OO 18:52
CC\Tg 1. 00 18r5{x
CCD'1, 00 lE!50 T
(otber than tho rtendrrd eLP roprca.Dtrd oa anotbor Fo:n 1l
1s5
STL DENVER
Total M-j*s Analvsis
ANALYSIS RUN LOG
ContrecE r
Irab Code r
InstrunrenE,
St,art Drt,c r
URS Corporation
gTLDTN
rD Nunbar:
e /26t200s
Cage No.:
PT ICPDTS'
gfg Ncr. r
Method:
Ead Drte r 9 127 l?OOs
SDc f$o.: D5fO7027O
}I
Srmple
ID.
Dlp Tl.ms IR
.trnaIfrtse s
.n
L
g
B
t
g
E
t'
B
E
c
D
c
A
c
R
c
o F]
Y
E
P
B
M
o
uln
"1"
N
I
K s
E :IIII v Z
N
c
N
BLank 1. O0 17:{6 x x
Standard. 1 1. O0 17r19 x x
ac srd 1 1. OO 17r53 x t
]x T
ac srd 2 1. O0 L7 t57 x x
RIJEITD 1. O0 18r00 x x
7r7r7rZZZ 1. OO 18rO{
ICg.A 1.O0 18: OB x x
ICSAB 1- OO 18r11 x t x
RINST 1, O0 18 :15 x x
HISH CHECK 1. OO 18r19 x x
RINgE 1.00 18r2?x x .1
QC Sr,d, 3 1. oo 18r26 x x
OC BE,d 4 1. O0 18 :30 x x
BIank 1. OO 19 :17 x x
standard 1 1.00 19r21 x x
oc srd 3 1. oo 19 :25 x x
oc srd, {1- O0 19 :32 x x
oc 8r,d 3 1. OO 22r08 x x
QC Strd {1.00 22: L2 lx x
rCgA 1. O0 ?2 :15 x x
IESNB 1. 00 22r19 x x
RINSE 1. O0 22t23 x x
ac aEd 3 1- O0 22 t?7 x x
QC gEd tL 1. OO 22 t3O x x
BIank 1, 00 22234 x x
Standard 1 1. 00 22:38 x x
ac srd, 3 1. 00 22:.41 x x
0c sld I 1. 00 llt15 I I
oc srd 3 1.00 03:{9 x -l I x -l
0c srd I 1 .00 03r53 x x
rB52 55180 1.00 03r56 x x
{CHICK S.AMPLE 1. O0 04r00 x x
q[-8"n-og0605 1. 00 0l:04 x x
t - DeEotoE adlllltloaal eloerrtc (otLrr tlran th. tttDdard CLD .lu.ata) ara raDr...at.A oltl cnothcr Fon 1l
STL Denver 1-5'7
STL DENVER
Total *-:lf Analvsls
ANALYSISRT]N LOG
Contractr:
r,rb Codc t
Inatnrnarrt,
Strrt DaEcr
t RS Corporatlon
STI,DEN
ID ![rrmbcr r
I t2612005
Cage lilo - t
PE ICPMS
gfg ilb. t
Mcthodr
nrrd Drtc r 9 127 l?OAs
SDO No.: DSTA7A27O
!,I
I - f)rnotra add.ltlonal clsnsntr
STL Denver
rlouonta) ar.
vTtt Tll
Sarp1c
rD.
Dlt rl"mc ebR
AnaIyEes
tl : lr I :l: l:l :l ilrl"Inl;
Gtrr-88- 09 0605 5. O0 O{:07 x x
qr-?.n'-0906'05 100. o0 O{r11 x x
ZZZZZT'l-,oo Od :15
7.7.z,z,7.2 5. OO O{r18
rlwfRA-LAB QC 1. O0 A{ 2?,2 x x
ac ard 3 1. OO O{:25 x x
Qe srd a 1. OO 04 :29 x x
rtif,rrRA-LAB AC gtR 5.00 0{:33 x x
r![TR.e.-LeB ac PDs 1. OO 0{1 r 35 x x
I,AB Mg 5.OO 0{ :40 x x
IIAB II{SD 5-OO O{t{4 Ix x
ZZZZZZ 10. oo O8: i7
Z7rZ7rZ7,20-oo O{r51
ZZZZZI,20. o0 O{:55
7.7.ZZZZ 1.00 0{:58
Qe srd 3 1. 00 05rO2 x x
0c std, 6 1 .00 05rO6 x x
(othrr tban the gt,ardard CLP r.Drai.ated os another Poru ltl
158
MEITTOD BI,A}IK REPORT
General- Chernistry
Client I-ot # -
PARAMETER
: D5LA7027A
RESUI,T
REPORTING
LTMTT UNITS
[Iatrix-- ---.! WATER
IVIB l:ot - Sarnple # t
MCAUil^I 350 -1-
PREPARATION- PREP
AI\TALYSI_q ,pATE. BATCH #
D5r220000 -473
oe / 20 / os s255473
D51280000 -429
09 /27 / 05 527L42e
Work Order #: HLJ6K1AA
0 .l-0 mg/L
DiLution E'actor: L
Analys{s Tlme. . : l-8 :00
Work Order #: HIQ(SEIAA
2 -S nq/L
Ollutlon Factor: 1
Analyole Tlme..: 17:00
Work Order #: HKCOR]-AA
O - 10 rrtg/L
Dilution Factor: 1
Analysis Time..: 11:30
Work Order *: HKTLR1AA
0 . l-0 rlirg/L
Dilut ion Factor : 1
Analysis Time..: 08:20
Work Order #: HLLC01AA
0.l-0 mg/r,
DilutLon Factor: 1
Analygle Tlme.-: 0B:20
Work Order #; HKTHE1AA
0 - 10 mglL'
Pllutlon Fact,or: I
Analyole Tlme..: 22:oa
Work Order #, HLLD91AA
0 .10 mg/L
Dllutlon Factor: 1
Analysis Time.,: 18r00
Work Order #: HKGAX1AA
5 . 0 mg/t,
Dilut,ion Factor: 1
Analyeia Tirne. . r 12 : 00
METHOD
Ammonia as N
Ammonia as N
Ch].oride
Fl-uoride
Nitrate
Nitrate
Ni trat e - Ni trite
Ni trate-Ni Eri te
Sul fate
Work Order #: HKSVP1AA IVIB Lot-Sample
ND 0.10 mg/L MCAWW 350.1
oilution Factor r 1
Analyelo Time. . ' 22 z0o
}UD
MB Lot-Sample #:
MCAI{W 325 -2
D5r200000 -252
ogllgl as sz63zsz1-B B
o-021 B
IUD
IVIB LoE -Sample #:
MCAWH 340.2
D5r090000-541aelaelas szszs4l-
MB Lot-Sample
IVICAWW 353 -2
#: DsI?2A000-581
as/oB/osND
ND
TTD
IVIB Lot -Sample #:
MCAWW 353 .2
D5r280000 -642
a9/08/os s271"642
MB Lot-Sample #,
MCAWW 353 .2
Dsr22A000-552
a9 I 20 / os s25sss2
MB Lot*Sample #:
MCAI^IW 353.2
D51280000 -679
a9 / 27 / 05 s27]-67 e
MB Lot-Sample #:
MCAWW 375.4
D5rr_30000 -526
ae / L3 / os s2s 6s26
o
526s5BL
STL Denver
ND
(Continued on next page)
1s9
HHIIIOD BI,ANK RBtrORT
@neral Cheuristrlr
C1ient Iot
PARAMETER
D5r070270
RESULT
REPORTTNG
LIMIT UNTTS METHOD
I[at,rix.- ----: WATER
PREPARATION- PREP
ANALYSIS DATE BATCH #
Total Cyanide
r{orE (s) :
Work Order #: HKN551AA
0 - 010 mg/L
oilution Factor: 1
Analysis Time..: 16:4O
IvIB Lot -Sample # :
sw846 9010B/ 9012A
Dsr1"60000 -L76
09/ 1s- ae/as/os s2se776
ftlculation.s are lrcrfcrrmed bcfore rounding to avold round-off crrors ln cafculatcd rcsults.
B Esdn:atcd rcsult. Rcsult Is lcss than RL.
STL Denver 150
Iot-Sanqrl-e * -
PARAMETER
pH
ffi CONTROL SAITTPI,E EVALUATION RBFORT
@neral. Chemistry
- -: D5I070270
PERCE}flT RECOVERY RPD
RECOVERY LIMTTS RPD LIMITS IVIETHOD
WO# : HKCSM1AA- LCS/HKC5I\,T1AC- LCSD LCS Lot -Sample# : D5I08000 O -527
(gt Lazl sw845 90408
(gt ]_aZ) o.o (0-5,0) sw845 9o4oB
Dilution Factor: I Analysls Tlme,
I^IO# : HK6VP1AC- LCS/UTOVPIAD-LCSD I.,CS
110) UCAWW 350.1
110) O-15 (O-10) MCAWI^I 350.1
Dilution Factor: L Ana lyal e Tlrne .
wo# : HLJ5I(1AC -LCS /HrrJsKlAD- LCSD LCS
(go 1-1-0) mcAww 350.1-
(go 110) o-52 (o-10) McAww 3s0.1-
oilutLon Factor: 1 Analysis Time..
wo# : HIC(SEIAC -LCS/ HrO(5EIAD-LCSD LCS
(go 1l-0) ttCAWW 32s.2
(go r1o) o -4G (o-10) McAww 3zs.z
oilucion Factor: 1 Anal.ysis Tirne.
wo# r HKCOR1AC-LCS/HKC0RLAD-LCSD LCS
( ez 114 ) MCAWW 34O .2
(Bz LL4) O. Bo (O-16) MCAWW 340.2
nilution Factor: 1 Analyai o Tirne .
WO# : HKTLRIAC -ICS/HK7LRIAD- LCSD LCS
( se 110) MCAWW 3s3 - 2
(85 110) 0.59 (O-10) MCAWW 353-2
Dilution Factor: 1 Analyele Time.
wo# : HLLG0 IAC - LCS/HLLCO 1AD - LCSD LCS
(Ae 110) ttCAWW 353.2(as 1r_o) o.s9 (o-10) McAww 3s3.2
Di lut ion Factor : 1.Analysls Time.
H,atri:r. . . r . . . . . : WATER
PREPAITJ\TION- PREP
AIVALYSIS DATE BATCH #
oe / oBlos
ae/08/os
: 11:59
Lot-Sample# : D5L22000A -473
oe/20/as
ae /20 / as
z 22 zAO
LoE,-Sample# : D5I2 8000 A -429
l_00
100
Arnmonia as N
97
97
Ammonia as N
101
100
Chloride
99
99
Fluoride
92
9l_
Nit.rate
L01_
r01
Nitrate
101
101
Nitrate -Nitrite
96
96
(go
(go
(gz
(gz
ae/27/as
oe/27 los
: 18r00
LoE -Sample# : D5I2A000 A -252;
ae / 18/os
oe/LB/05
: 17:0O
Lot-Sample# : D5I090000 -541
ae/20/05
ae/20/05
5251-527
525L527
526547 3
525547 3
527 L429
527L429
5253252
s263252
s25254L
525254L
5265 5 81
5265 s 81
527 L642
52'7L642
52655s2
5265 s s2
oe/ae/os
oe/oelos
: 1L;30
Lot -Sample# : D5T220000 -581
ae / oBlos
oe l oBlos
: 08:20
Lot-Samp1e# : D5128000O- 642
oe/o8/os
oe/08/os
: 08 :20
Lot-Sample# : D51220000-552WO# : HKTHE1AC - LCS/HTZHEIAD_ LCSD LCS
LLz) ttCAWW 353 .2
LLz) O.r_O (O-10) FTCAWW 353.2
pi lut,ion Fact.or : L Ana1ysi s Time .l 22240
STL Denver
(Continued on next page)
161
I,ot-Sample #- - - = D5I0702]A
I,ABORATORY COTTTROL SAIT{PI,B BTIATITATTOI{I
General- Chenistrlr
RECOVERY RPD
LIMITS RPD LIMITS IV1ETHOD
Flatrix : WATER
PREPARATION- PREP
A\TALYSIS DATE BATCH #
LCS Lot-Sarnpte# : D5I28000 A -579
09/27 /0S 527L679
oe/27 /os s27L57e
REPORT
PERCENT
PARAIVIETER RECOVERY
Ni t rate -Ni trite
99
99
Sul fate
LO7
LA7
Tota] Cyanide
B9
90
NurB (s) :
wo# : HLLDgl-AC -LCS / HLLD91AD- LCSD
(gz LLz)
(gz LLz) 0.ts (o-10)
nilution Factor: L
(gr LLzl(el r-12) O-11_ (O-ls)
nilution Pactor: L
MCAWW 353.2
IvICAWW 353 .2
Analyele Tlme..: 18:00
WO# : HKGAX1AC _LCS/ HKGAXIAD_ LCSD LCS Lot-SarnpIe# ; D5Il-3000 A-525
MCAr^rW 37s.4 09/13/A5 5256s25
MCAWW 37s.4 O9/L310s s2s5s25
Analyoio Time. , : 12 ;00
wo# : HKNS61AC-LCS/HKN551AD- LCSD LCS IJot -Sample# : D5 I 1"60 0 0 O -L7 6
(sg 109)
(89 10e) 0.44 (o-zaj
Pilution Factor: 1
sw845 90LA]8_/e012A Oe /rs- oe /te / os sTseL75
sw845 901 0B/9012A 09 /rs- Oe /Le / 0s s2seL76
Analyols Tlme, . : 15 :40
Calculatlons arc pcrfonned before rounding to avoid round-off errors In calculatcd rczults.
STL Denver a52
urBoRAllORY mIITROIT SAIIIPLB DATjA REIIORT
General. Chemietay
Iot-Sarrpl.e #.
PARA}IETER
pH
: DSI0 7 027 O
SPIKE MEAST]RED
A}IOTINT AMOUNT I]NITS
Matrix- - ., - - - - - : WATER
PERCNT
No Units 100
No Unit s l-0 0
Dllutlon Factor: L
PREPARATTON- PREP
AIVAIJYSTS DATE BATCH #RECVRY RPD ME:rHOD
wo# : HKcSMr-AA- LCS/XrcCSMl-AC-LCSD LCS Lot -Sample# : D5f08000 A -527
7 .00
7.00
Ammonia a6 N
4.00
4 .00
Ammonia as N
4. 00
4.00
Chloride
50.0
50.0
Fluoride
5.00
s - 00
Ni trate
0.0500
0.0500
Nitrate
0 - 0500
o .0500
Ni traEe -Ni t rite
4 - 00
4 - 00
7 .00
7.00
3 . BB
3 .89
4 -44
4 -A2
49.5
49 _3
4 - 50
4 .55
wo#
0 _ 0504
0 - 0507
3 . 85
3 .85
mglL
mg/L
ollutlon Factor: 1
MCAWW
0.15 MCAWW
Analysi s
LCS
350 .l-
350 .1-
Time..: 22t0O
oe l oB/os
oe/o8/0s
oe/za/as
oe/za/os
ae/27/os
oe/27/0s
oe / 1Blos
ae / 1Blos
525L527
525L527
s25547 3
s25547 3
527 L429
527L429
52632s2s25rro
sw845 90408
o . 0 sw845 904 0B
Analysis Time. . : 11 :59
wo# : HK6Vp]-AC - LCS /HXSVPIAD - LCSD Lot-Sample# : D5T22000 O-473
[{o# : HLJ6KTaC-I.CS/HIJ5K1AD- r,eSD LCS Lot - Sample# : D5I28000 O - 429
97
97
1_O r
100
99
99
mg/L
mg/L
oi lut Lon Factor : L
MCAWW 350.1
O.62 MCAI^II^I 350.1-
Arralysio Time. .18:00
wo# : HKXSE1AC -LCS / HI0(5E1AD - LCSD Lot -Sample# : D5T20000 O -252
MCAWW
a -46 MCAWW
AnaLysi s
LCS
325 -2
325.2
Time. . : 17:00
mg/L
mg/L
niIution FacEor: L
WO# : HKCOR1AC -LCS / HKCORI-AD _ LCSD LCS Lot-sample# : D5I090000-541
34O .2 09 / 09 / A5 525254L
340.2 09/ o9/os 52s2s4l
Time.,: LL:30
mg/L
ms/L
Dllution Factor: 1
MCAWW
O.8O MCAWW
Analyai s
wc# : HKTLR1AC-LeS /IfrXt LRLAD-LCSD Lot -Sample# : D5I22000O -581-
92
9l-
L01
101
LCS
353 .2
353.2
oe / o8/os
ae/08/os
s265 5 81
s2555 B 1
0 .0504 mg/I-,
0.0507 mglL
101
101
Dilution FacEor: 1
MCAI^M
0 .59 I'lCAhn^I
Analyoi e
mg/L
mg/t'
Dilution Factor: I
MCAWW
O .59 IvICAWW
Analyel e
: HLLC0 1AC - LCS / HLL30 1AD - LCSD
Time. . : 08:20
IrCS Lot-Samp1e# : D5T2B000A-642
3s3.2 A9/08/0s s27L642
353 .2 A9 / 08/05 527L642
TLme. . : 08:20
wo# : HKTHE1AC - r,CS /nrct HEIAD - LCSD LoL-Sample# ; D5I220000 - 552
rir..g/L
ms/L
Dilution Factor: L
MC.AI,fi^I
0 .10 MCAWI^I
Analysis
next page)
LCS
353 .2
353 .2
Time.. : 22:A0
95
95
ae/20/os
oe/20/os
525 5552
s25s552
STL Denver
(Continued on
163
I,ABORATORY CO}UTROI, SAUPT,B DATA REPORT
General Chemietry
Lot-sampl.e #- - - : D5f 07 027 A
SPIKE
Nitrat,e -Nitri te
4.00
4 .00
SuI fat e
25.O
25 .0
Tota1 Cyanide
o .100
0.100
NOTE (s)
=
Dilution Factor: 1 Analysi e
wo# : HI(NS 5 1Ae - LCS /nrOlS 5 r-AD -LCSD
IrIatriJ(- . . . . - . . . r WATER
PREPARATTON- PREP
AI{ALYSIS DATE BATCH #
LCS Lot -Sample# r D5f l-3000 0-525
375.4 09/L3/As 52s5526
375 .4 09 /B / As s2s6s26
TLme. . : L2:00
LCS Lot-Sarnp1e# : D5f160000-176
e01oB/9012A 09/15- 09 /1-9/05 s2s9L76
e01aB/ e012A ae/ 1s- a9/a9/as s259t76
Tlme..: 15:40
PAIU\METER AMOI]NT RECVRY RPD METHOD
wo# : IILLDSI-AC- IrCS/HLLD9T,AD-LCSD tCS LoE -Samplef : D5 12 80 00 O - 57 9
3 .95 I[q,/t 99 MCAWW 353 .2 09/2'7 /05 527A679
3.95 r,lq/r. 99 0.1s MCAWW 3s3.2 09/27 /O5 52't1679
oilution Factsor: I Analyelo TLrne..: 18:00
wo# : HKGAX1AC - LCS /HKGA)(LAD - tCSD
MEASURED
AIUOUNT I,]NTTS
PERCNT
107 lrrcAww
ta7 0 ,11 MCATf,W
26 .8
26 .7
mg/L
mg/L
0.0 894 mg/t"
0 . 08?8 mg/r.
B9
90
Dilution Faqtor: I
sw84 6
o .44 SW845
Ana lys i s
Calculntions arc performed lrcforc rourdlng to avoid rourul-off errors in calculated results-
STL Denver L54
Clieut I,otr # -
Datre SarryIed.
PARAIVIETER
Amrnonia as N
Ammonia as N
Chloride
Fluoride
Sulfat e
PERCENT RECOVERY
RECOVERY I,IMITS
IITATRIX SPIKE SATIPIiE EIIAIJTIATION REPORT
General- Chemistry
: D5 T07 027 A
: 09/07/oS 13:58 Dat'e Receiwed--= 09/08/05
Matri:r ---: WATER
PREPAIU+TION- PREP
AIVATYSTS DATE BATCH #
MS Lot-Sample #: D5I080243-004
09 / 20 -09 /21/ a5 s26s473
09 / 20 - 09 / 2L/ os s26s47 3
tIS Lot-Sarnple #: D5I150297 - 00L
a9 / 27 / as sz7l42e
ae/27 /05 527L429
MS Lot, -Sample # : D5 f 150 z1.,l- 001
a9 /L8/ As s2632s2
ae / 18los s2632s2
Lot-Sample # t D5I080243-OO4
ae / ae / as s2s2s4l"
oe / oelos s2s2s4]-
Lot-Sample #: D5r080243- 004
09 /27 / Os s27]-679
09/27 /As s27L67e
Lot -Sarnple # : D5f100153-003
oe / 20 -ae / 2L / as 525sss2
ae / 2a-oe /2L/ a5 52655s2
MS Lot-Samp1e #, D5f090340-002
oe / L3/os s2s6s26
ae/n / 0s s2s6526
RPD
RPD LIMTTS METHOD
wo# : HJ5.IMIDG-MS / Wl
'ltutlDH-MSDt-30) MCAWW 350.1
t_30) r-r (o-30) MCAww 350.1
nilution Factor: 1
Analyeis Time. . : 03 :00
wo# : HIovrQ]. ]-DA- MS/HrA{Q1r"DC -MSD
130) l,rCAwW 350.1
l-30) 2.5 (O-30) MCAWW 3s0.1-
Oilution Factor r 1
Analyeig Tirne- . : 18 : 00
wo# : HKr,WAICE-MS/HKLWAI-CF-MSD
110) MCAWW 325 -2
1-L0) 0.1-0 (O-r.0) MCAWW 325.2
Dilution Factor: 1
Analysis Tirne- - : 17:00
HJ6JM1DE-MS/HJ6JM]-DF_MSD MS
Nitrate -Nitrite
92
88
Ni t.rate -Nitri te
99
9B
87
90
109
108
76 N
79 N
r_00
97
r05
t0s
(go
(go
(az
(az
(62
(az
wo#:
107)
L07't z.+ (o-10)
Pllutlon Factor: 1
Analyeis Tlme- . : l.L :30
WO# : H.]6JIVI1C7 -MS /ruI CJI,IICB -T"ISD MS
(ez - 119) MCAWW 3s3 -2
(ez 119) 2.L (O-30) MCAWW 353.2
olluc ion Factor : l-
Arralyole Time. . : 18 :00
wo# :
rle)
HI(AR9l_C5 -MS/HXang1C? -MSD MS
MCAWW 340 .2
MCAWW 34A.2
MCAWW 353 .2
MCAWW 353 .211e) 3.3 (0-30)
Dllution Factor: 1
Analysis Tirne. . : 02 : 00
wo# : HJ9IE]-AR-IIS /HISIE1AT-MSD
(es 153) vtcAww 375.4
(45 153) 0,48 (O-2L) MCAWW 37s.4
Dllution Factor: 1
Analysie Time. . : 12 :00
STL Denver
(Continued on next page)
155
}IATRIX SPTKE SAT{PI,E E\NLTIATTON REPORT
Genera.I Chemietry
C].ient Lot *.
Date Sanpl.ed-
D5IO7027A
09/ a7 / a5 L3 :58 Date
ttlat'rix-- ----r WATER
PREPARATTON- PREP
AI{ALYSTS DATE BATCH #
PERCENT
PIBA+IETER RECOVERY
Tot,a1 Cyanide
86
91
r{orE (s} :
RECOVERY
LTI{TTS
Receiwed.. r 09/ 08/05
RPD
RPD IJIMITS METHOD
wo*: H,J57,JLCU-MS,/H,J57,J1CV-MSD MS Irot-Sample #: D5r080199-005
(78 - 120) swg4g gotoB/go].zA 09/1s-09/L9/o5 szs9L74
08 - AzAl 6-r- (0-20) SW845 eO]-AB/9012a OglrS-09/19/Os s2s9]-74
oilution Factor: 1
AnalyEiB titBe,.: 16:40
(lalctlatir)ri are performed bcfore roundlng m avold rountl-otf crrors In calcula&d rt'sults.
N Sptkcd analytc rccovery is outside statctl control limits.
STL Denver L66
TIIATR X SPTKE SAT,TPI,E DATJA, RBPORT
Generaf Chemist.ry
: D5 T.07 427 A
: 09/07 /a5 13:58 Date Received. . ! a9/ 08/05
Matrix-- ----: WATERC].ient tot #.
Date Saqlled.
PARAMETER
Amrnonia as
SAMPLE SPIKE
AIvIOUNT AMT
MEASRD PERgNT
AIVIOI.]NT UNTTS RECVRY RPD METHOD
WO# : HJ 5JMlDG - MS/HJ5J}VI1DH - MSD
PREPAIU\TION- PREP
A}UALYSIS DATE BATCH #
N
540
540
Ammonia a6 N
a .24
a .24
Chloride
1400
1400
Fluoride
2.2
2.2
Nitrrate -Nitri te
320
320
NitraEe-Nitrite
0,18
0 .18
Sul- f ate
6 .7
6.7
Dllution Factor: 1
Analysig Tirne. . : 03 : 00
wo# : HKrvIQ1]_DA-MS/UKUO11DC-MSD
MS Lot-sample #: D5I0B02 43-004
MCAsn^r 3s0.L o9/20-09/zt/os s265473
MCAWW 3 s0 . L 09 / 2A - 09 / 2L/ As s25s47 3
MS Lot-Sample
MCAWW 350 .1
MCAhn^I 350 .l-
#: D51150297 -001
oe/27/os s271-429
oe / 27 I as 527L429
MS LoE-Samp1e * : D5f 1502Lt- 001-
MCAWW 325 .2 09 / 18l0s s2532s2
rYlcAWW 32s .2 0e / 78 / 05 s263252
2000
2000
4 .00
4 .00
500
500
s _ 00
5.00
400
400
4 .00
4 - 00
25 -A
2s _ 0
wo# :
33 .1_
32 .9
mg/t
llr'g/t
ael27/os
oel27/os
09/L3/05
0e/13/os
527 L67 9
5271,67 9
5256s26
52s6s26
Tsza mg/I,
24eo mg/L
3 .7 4 r;rg/L
3 .83 mg/L
l- e7 0 rrrg/L
1e7 0 mglL
6.00 N mg/I'
5-1s N mg/L,
5 90 mg/t
67 6 mg/T,
Dilubion Factor: 1
Analyeio Time. . : 18 :00
WO# : HKLWALCE - MS/HKLWA]-CF - I\,[SD
99
98
75
79
B7
90
109
108
1.1
2.5
0 .10
2 _4
Dllution Factor: 1
enalysis Tlme,.: 17;00
WO# : HJSJM1DE -MS /HIAJI.,[1DF-T"1SD MS Lot-Sample
MCAWW 340.2
MCAWW 340 .2
o;,i; ;i;.'n' ::;,)
0elae/as 52sZ54L
Dilution Factor: 1
Analyeis Time..: l-1 :30
wo#; H,J6JMTCZ-MS/HU6JM1C8-MSD MS LoE-Sample #: D5I080243-OO4
Dilution Factor: 1
analysis Time. - : l-8 :00
wo#: HKAR91C6-MS/HKAR9IC7-MSD MS Lot-Sample #: D51100153-003
4.17 mg/t 100 MCAWW 3s3-2 O9l2O-09/2L/Os s26sss2
4.04 *g/t e7 3.3 MCAWW 353.2 09/20-09/2L/Os 5265s52
Dilutio! Factorr 1
Analyais fime..; o2:00
92
88
105
r_ o5
2-L
MCAWW 353.2
MCAWI{ 353 .2
MCAWW 375 -4
0 .4 8 IvICAWW 37 5 - 4
HJ9 1E1AR - MS / Ht g1 E IAT-MSD MS Lot-Sample #: D5I090340-OOz
Dilution Factor; 1
Analysis Time. . : 12 :00
STL Denver
(Continued on next page)
767
Client l,ot #.
Date Sarqrl-ed.-
SAIVIPI,E SPTI(E
PARAMETER AIITOUNT AMT
T,IATRIX SPIKE SAI{PI,B DATA REFORT
General Cheudetry
: D5f07O27A
: 09/a7/as 13:58 Date Received--: a9108/05
Matri:c, - . - - - - - r : WATER
MEASRD
A}TOUMT I]NTTS
PERCNT PREPARATION- PREP
ANAIJYSIS DATE BATCH #RECITRY RPD METHOD
wo#: HJ57J1CU-MS/HJ57J1CV-MSD MS Lot-Sample #: D5I080199-006
0.0857 mg/t 85 SW846 eor-OB/9 O9/L5-09/L9/05 5259L74
0.0911" utg/t s]- 6.1 SW846 9010819 O9/L5-09/L9/05 52s9L74
Dllution FacEor: 1
Analysis Tine..: 16:40
Total Cyanide
ND
ND
NOIIB (S) ;
0 .100
0.100
Calculadorls arc pertbnrretl befilre rounding to avoid round-off errors ln calcularcd rcsults.
N Spltced analyte rocovery is rlutside statcd conuol llmlts.
STL Denver 158
C1ient Lot. # -
Date Saqrl-ed-
PARAI,IETER REC.OVERY
Ni Erat e -Nit.ri te
o?JL
90
MATRIX SPTKE SAIITPI,B EITALTIATTON REPORT
Genera]- Cherni gtrlr
- -: D5I07027O
--: A9/A6/05 10;35 Date Receiwed--: a9/a7/aS
PBRCENT RECO\IERY RPD
f{atrix......,..r GW
PREPARATTON- PREP
AhrA:LYSTS-DATE BATCH #
MS Lot-Sample #: D5r070270-002
oe / 20 / os 5265ss2
oe /20 / 05 s26sss2
LIMITS RPD IJTMITS METHOD
(52
(ez
wo# : HJ36N1CE-MS /H,tI6N1-CF-MSD
119) t"lCAWW 353.2
11gl 2.L (O-30) MCAWW 353.2
Dilution Factor; 1
Analysis Time-.r 22:AO
NOTB (S) :
Calculatlons arc pcrlbrrtted beftrre rounding to avoid rourd-off crrors ln calculatcd results.
STL Denver 169
Client Lot *.
Date Saqr1ed.
SAMPLE
PARAIVTETBR A},IOUNT
Nitrate -Nitri te
HAIRTX SPIKE SAMPT,E DATA RBPORT
General- Chernistry
D5I070274
09/06/05 l-0:35 Date Received--: 09/07/os
SPIKE
AMT
MEASRD PERC}{IT
Dlat,rix-- ----: GW
PREPAIU\TTON- PREP
AlrALYSrs pArE BlTqq..t
ae /2a / os s255552
oe / zo / os sz;sssz
AMOUNT UNTTS RECVRY RPD IV1ETHOD
wo# : HJ35N1-CE-MS/H,J36N]-CF-MSD MS Lot-Sample # : D5IO7O270-002
a-24 4.00
o,24 4.00
3 .94 rl;rg/L
3 . 85 nrg/L
MCAWW 353 .2
2.1 IvICAWW 353.2
92
90
nllution Factor: 1
Arralysie Time. . : 22zoo
NCIfE (S} :
Calculatlor)s ere performetl before rounding to avoid round-off crror$ ln calculatcd rcsutts.
STL Denver 170
Client, Lot #- - - =
Da.te Saryr1ed- - -:
PARAM RESULT
pH
'7 ,8
g;rytrPT.If DTIPLICATE E\TALTIATION REPORT
General. Chemietrlr
D5I070270
oe/06/05 10:35
DUPLICATE
RESULT T}NITS RPD LIMTT METHOD
I{ork Order *---: HJ35N-SI{P
HJ3 5N-DUP
Datre Received. . i 09 / 07 / A5
RPD
Matrix-
No Units 0.13
Dilution Factor: 1
SD Lot-Sample
(o-s.0) sw845 90408
PREPARATTON- PREP
AI{ALYSTS DATE BATCH #
D5r070270-002
a9 / 08/0s s2sLs277.8
STL Denver 1,7 7
Lot#: WW?D??o
Company Narne & Samplins Site:
STL Denver
Sample Receiving Checklist
Date/Time Received:
l^.{L>l eZ
ql+t"r O17o
PM to Complete This Section: Ies
R.esidual chlorine chcck required:tr
Quote #:
Special Insrnrctions:
Time Zone:
. EDT/EST. CDT/CST 'MDTA{ST . PDT/}ST . OT}IER
Yes
D
No
[]Qmrantined :
]io
U
Unpacking Checks:
zCooler #(s):
Terrperames ("C),
N/A Yes No
Datrr.
EAz_
DF3.
D& 4.
ED5.
EFD6.
hD 7.
D8.
,E g.
tr 10.
6 11.
tr 12.
0 13.
3.5"
Cooler seals intact? (N/A if hand delivered) If no, document ou CUR-
Chain of custody presc,Bt? If no, documcnt oa CIIR
Bottles brokeu and/or are leaking? Ifycs, document on CUR
Multiphasic samples obvious? If yes, documeut ou CllR.
Proper container & prescrvatives used? (ref. Attaclrment D of SOP# DEN-QA-0003)
pH of a1l sarnples checkcd and meet reguirements? If uo, documcnt on CUR.
Initialsrv)V
If no, docurnent on CIIR.
Sqfficient volurre provided for all aaalysis requested? (ref. Attacbment D of SOF# DEN-QA-0003) If no,
documcnt on CUR, and contact-P.M beforc pmcecding-
Did chain of custody agree with labels ID and samples received? If no, document oo CUR.
Were VoA samples witho't heaGpacc? ,rr@*, *&='
Wcrc VOA vials prcscrved? Preservative pHCr O4+?"C Dsodium Thiosulfate 3 Ascorbic Acid
Did samples require presewatiou with sodium thiosulfate?
If yes to #11, did the saryles contain residual chlorine? If yes, docnment on CUR.
Sediment present in dissolved/frltered bottles? Ifyes, docurreut ou CUR
A 15.
tr 16.
P 17-
p
trtr
aF
tr
&Dtotlt' {r
o
p
tr
D 14. Is zuficieni rolum, prorid"d lor cli.ot r.qu"sieJ MS, MSD or matrix duficafes? If no, documeat oo CII& ,od
coDtact PM before proceeding.
Receipt date(s) > 48 hours past the colJectiou date(s)? If yes, notify PA/PM.
Are analyses with short holding times requested?
Was a quick Tum Around GAT) requested?
STL Denver
\QA\Forms\Sample Receiving\Sample Rccciving Checklist 12 13 04 revision LA13tA4
]-72
hD
STL Denver
Sample Receiving Checklist
Lor # .u6.]; Ep-t ?D-
I-ogin Checkr:
Nln )'es Na
g D 18. Sufficicnt volwncprovided for all arral;,sis rcqueslcd'l (rcf. Anachnrent D of SOIY DEN-QA-0003)
documcnl on CUR, and contact PI4 beforc proccedinq.
tl 19. Is sufficicnt volume providcd for client rcguestcd MS, l{SD or matrix duplicates'l If no, documcnt on CUII, and
cofiad PM bcfore procecding
20. Did the drain ofcustody includcs "rcceivcd b)r'and "rclinquished" b1'signaturcs, dates, and rimes?
21 - Wcrc qpecial log in insfnrclions rcad aild followed?
22. S'ere AFCEE mctal$ Ioggicd for refrigeraled .storage?
23. Were tcsts logged chuclled against the (.OC? Urhich sarnples u,cre confirnrcd?
24. \\ras a Rurh forrn completcd for quick T/+T'!
25. \\/as a Shorl Hold fomr cornpletcd for an),Ehofl holds?
26. Ir ".Strict ICO0'reguired?
27. Were spccial archii,iag instructiors irdicalcd in the General Commcnts? lf so, v.,hat wcre they?
I nitiaJs
0"*)
If no,
D
E
D
I
BD
EI
IJtr
*tr
uu
}ED
trfi
Lul
Labeliug and Storage Checlrs:
3 ! 28. \\)as thc subcontact COC signcd and scnl u,itb samples to botJc prep?
{ tr 29. lircrc sauplc ]abels dor:blc-checkcd b1, a scconc! psrson?
30. Were sar4plcbottl^-s aud COC doublc chsckcd for dissolvcd/Eltered mrla]s by a second person?
3I - Did &e sample ID, Date, and Timc frorp )abel malch rrbal uns logged?
32. Were rtickcrs for special archiving iustruaions affxed to eacb box aud to the ICOC: See #27
fl D 33. Wcrc AFCEE mclals storcd refrigeratcd?
I tr 34. 'Werc "stricl ICOC'copics gircn to satellite storage areas?
Documsnl anl,problems or discrepancies and the actions talien to resoh,e thgm on a Condition lJpon Receip Anomaly
Reporl (CLIR).
rt'-' I f
{.t
IT
F*
STL Denver 173
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STL Denver
4955 Yarrow Street
Arvada, CO 80002
Te!: 303 736 0100
www.stl-inc.com
STL
303 431 7t7L
ANALYTICAL REPORT
Weste rn Zirconium Proj ect
Lot #: D5I030I39
Sheri O'Cormor
URS Corporation
8181 East Tufts Avenue,
Denver, CO 80237
STLDENVER
fur
Linda L. Benkers
Project Manager
September 28,2005
Sevem Trent Laboratories, lnc.
Table Of Contents
Standa rd Del iverables with S u ppo rti n g Documentatio n
Report Contents
Sfandard Deliverables
(fn* Cover Letter and the Report Cover page ere considered integral
parts of this Standard Deltverable paclcage. Thts report is lncomplete
unless all pages indicated in this Table of Contents are included.)
o Table of Contentso Case Narratlve
. Executive Summary - Detection Hfghnghts
o Methods Summary
. Method/Analyst Summsry
. Lot Sample Surnmary
o Analyticel Results
. QC Data Association Surnmery
. QC Sample Results
. Chaln-of-Custody
Su pportt ng Docu me ntation
Note: A one-page "Descrtptlon of Supporting Doqtmentation" is
provided at the beginning of this sectton.).
r Yolatlle GC/MS
r Semivolatlle GC/}IS
o Volatile GC
r Semivolatlle GC
r LC/IIS or IIPLC
o Metals
o General Chemtstry
r Radiochemtstry
o Subcontracted Data
Number of Pages
Check below when
supporting
documentetion is
precent.
nnnnmEnn
STL Denver
Case Narrative
Dsr030139
With exceptions notod as flags or footnotes, standad analytical protocols were followed in the
amlpis of the samples and no problems were encormtered or anomalies observed. All laboratory
quality conhol samples analped in oonjunction with the samples in this project were within
established control limits, with any exceptions noted.
The test results presented in this repdrt meet all requirerrents ofNELAC, and any exceptions are
noted. This repon shall not be ryproducod, excqlt in full, without writte,n prmission from the
Iaboratory.
Sample Receiving
Seven samples were rgceived under chain of custody on September 3, 2005. The sarnples were
received in good condition at tqnpe,ratur€s of 4.3oC, 43oC,4.2"C,3.6oc,and 3-2"C.
Please note that for sample ID GW-68-0902A5 3 of 3 VOA vials were received containing 7mm
bubbles. The sample was logged for the reguested analpis.
Also note that for sanrple ID's GW-6B-090205 and GW-6A-090205 the pH for cyanide was
approximately 10. The sarnples were logged and the lab adjusted the pH to the method
recomme,ndd12.
Sanrple aliquots for all radiological analyses ae logged in under a sqmrate lot and were sent to
STL St. tnuis; 13715 Rider Trail North; Earth Cit),; MO 63045, phone [phone].
GCfll{S Voladles, SWt46 82608
The MS/LISD performed on a sample from another client and/or lot was in conhol.
No anomalies were obssvd.
Total Mctals, SW846 60108,6020 & 747OA
Samples D5I030139-004, 006 and 007 were analyzed at dilutions for several metals by methods
60108, 7470A and/or 6020 due to ma&ix interference and/or high target compound
concenkations. The reporting limits are adjusted accordingly.
Sample D5I030139-006 derronshated mahix interference with no dilution required for lead. The
sarnple displayed a negative reading greater than the reporting limit for lead. The reporting limit
is adjusted accordingly and associated data is flagged "G".
Sample D5I030139-007 demonstrated mafiix interference during the mercury digestion
procodure. This sanrple was re-digested at a lOX dihrion with acceptable results. The reporting
limit is adjusted accordingly.
Magnesiurn was detected in the method 60108 blank at a conce,ntation below the reporting limit
but above the method detection limit Associated positive sanrple results are flagged "J".
STL Denver
The method 60108 and 6020 MSINTISD were performed on saurples from another client and/or
lot and were not in contnol.
Themethod 7470A MS/I\,ISD associated withbatch 5258350 was perforrred on sample
D5I030139-002 and was in control for mercury.
The method !47OAMSA{SD associated with batch 5262486was performed on a sample from
another client and/or lot and was not in control for mercury.
No other anomalies were observed.
General Chemlstry, Various Methods
Samples D5I030l 3g-O}zthrough 007 were analped at dilutions for several comporxrds due to
high analyte concenfrations. The reporting limits are adjusted accordingly and the associatod
data is flagged "Q".
Fluoride aud sulfate were detected in the method blanks at concenfations below the reporting
limits, but above the method detection limits. Associated positive sample results are flagged'T".
All MSA{SD samples were performed on samples from other clients and/or lots and some were
not in control.
The pH dtrplicate was perfomred on a sample from another client and./or lot and was in control.
No other anomalies were observed.
STL Denver
E"[EW -I)'etectionHighlights
D5IO3(}139
RESUITT
REPORTTNG
LIIVIIT T]NITS
AI{AIJYTICAIJ
METHODPARATI{ETER
Grr-R1-OeOzOs OelAzlOS O9:35 OO2
Eelenium
eluminum
Arsenic
BarLum
Nickel
Caleium
Iron
PoEaesium
Magneeirxn
SodLum
Zirconium
Chlor1de
Fluorlde
pH
Sulfate
AmrnonLa aB N
Gr-ge-ogozos oelazlas 1o:1o oo3
A].urninum
Barium
Chromlum
Nl-ckel
Ca]-cium
Iron
Potassirrrn
Magrneslum
Sodium
Chloride
Fluoride
pH
Su]-fate
Ammonia as N
Gfi-98-O9O2Os OglOzlOS 11 : OO OO4
0.002L
a.26
0,0L4 B
0.082
0.0016 B
110
3.2
27
49 .f
460
0.0017 B
824 0
0 ,70 ,J
1.7
520 ir, Q
2.7
0.15
0. L9
0 - 0r-8
0-0070 B
14
o.28
38
10J
r.90
240 0
0.72 J
8,2
2.5 BrJ
3-6
o.0a20
0.10
0.015
0.0Lo
o-o40
0.20
0 ,10
3-0
a .24
5,0
0.015
1,2
0.10
0. L0
100
0_L0
0.10
o.010
0.010
0.040
o .20
o.l-0
3.0
0,20
5.0
5-0
0,1-0
0.10
s_0
0.l-0
mg/r,
trq,/t
mg/t'
mg/t'
rry/r,
mg /T'
nrg/r,
nry,/t
ng,/r'
nq./1"
nrg/1,
fitg /T'
ng /t'
No units
mg/r,
mg/r,
rfig / r'
mg/r,
rlrg/T'
IIKI/I,
rrq/t
mg/r,
rw/t,
mg/1.
mg /I'
rrg /r'
mg/r,
No Untts
mg /r'
mg lr-,
mg /r'
Ktg /T'
n,g/T'
nlg /T,
mg/L
mg/L
mg/t,
sw846 6020
sw845 50108
sw845 601-0B
sw845 50108
svrE{5 5 0108
9w846 50108
sw846 50L08
sw846 601-08
sur846 60108
sw846 50L08
sw845 50L08
MCAWW 325.2
MCAI{W 340 .2
sw846 90408
MCAWW 375.4
MCAWW 350.l,
sw846 60108
sw846 60108
sr{845 60108
sw846 6 0108
sw845 60108
sw84 5 5 0108
sw846 60108
sr{845 501_08
surS{5 50108
MCAWW 325.2
McAIilw 340 .2
9w845 90408
MCAWW 375.4
MCAWIII 35O - 1
sw8,05 502a
9w845 5020
slrS{ 5 6 0108
sw845 50108
sw84 5 6 0108
sw845 60108
sw84 5 5 0108
Cadmium
Selenium
Areenic
Bariurn
Nicke1
Zinc
Calclum
o.00032 B 0,0010
0 - 0020 0.0020
o.Lz 0.0L5
o.1t 0 - 0L0
o.0027 B 0.040
0. 0093 B 0.020
1L0 0.20
STL Denver
(Continued on next page)
EXEWSM-IletctionW
D5IO30139
RESUIJT
REPORTING
LIMTT UNTTS
o
A}IAIYTICAIJ
METHODPARAMETER
Gn-sg-ogo2os ag|ozlos 11:oo oo4
Iron
Potasslunr
Magrresium
Sodium
Zlrconium
Chlorlde
FluorLde
Nlt,rat,e
Nltrate-Nitrite
Total Clranide
pH
Sulfate
Ammonia aE N
Grr-s7-o9o2o5 ogloz/as r-1:46 oos
o.4g
96
280 ir
1300
o-0038 B
2300 0
0.86 .I
5.4
5.4
0.0a44 B
7.9
850 J, Q
2.7
o.0aa22 B
0.00050 B
3 .1-
0.0055 B
0 .30
0.0051 B
0.0062 B
0,0444
0.0095 B
0.014 B
L7
{.5
54
11 J
444
0.0047 B
674 0
0 .86 'J0.050 B
0,060 B
8.4
4-6 B,J
3.8
(ConLinued on next
Cadrnirrm
Selenium
Aluminum
Arsenic
Barium
Chrornium
NickeI
Iread.
Vanadiurn
Zi-ne
CaIcJ-um
Iron
Potasslutn
Magneslurn
Sodium
Zireonlum
Chlorlde
Fluoride
Nltrate
t''litrate-Nit,rite
pH
Sulfate
Ammonia aB N
o.l_o
3.0
0.20
2s
0, 0L5
100
o-10
0.L0
0-10
0.010
0. 10
250
0.10
o. 00L0
o.oo?a
0-19
o. oLs
o.010
o.010
0.040
o.0030
o.010
0 .020
0.20
0.10
3.0
0,20
5,0
0.015
2A
0.10
o. L0
o. t0
o. L0
5,0
0. J_0
page)
ms/r,
mg/T,
rng /I'
nq/t-,
$rS /T'
mg /I'
rng /T-,
mg/L
mg/r,
ntg /T,
No Unl,ts
mg /r'
mg/t'
mg/r,
ng /T'
mg/r,
n,g/r'
ng,/r,
nlg/L
mg /r'
mg/t
mg/r,
mg/t"
mg/t
mg/t,
mg/L
mg/r,
ng/t
mg/t'
ng /r'
mg/T,
mg /r,
mg /r'
No Unite
mg /r'
mglr,
sw845 60108
sw8{5 50108
srilS{6 50108
sw846 50108
9w846 601-08
MCAWW 325.2
MCA!{W 340.2
MCAT{I{ 353.2
MCA![I{ 3 53 ,2
9w846 9o1OE/ eo12A
9w846 9 04 0B
MCAWW 375.4
MCAVilW 3 50 . 1
sw845 5 020
sw845 5020
sw84 5 6 0108
sw81l5 6 0108
svt846 5 0108
sw846 60108
sr{845 50108
swB45 50108
sw8{6 50108
9w845 60108
sw846 60108
sw846 60108
sw846 50108
sw845 60108
sI{84 5 5 0108
sw845 50108
MCAWVI 325.2
MeAriIuI 340.2
MCAWW 353.2
MCAltnfl 353.2
sw845 90408
MCAT{I{ 375 .4
MCAI'WI 350.1
STL Denver
EXECIITMW-I)etectiontHighlig[b
DsrO30139
RESI ITT
REPORTING
LTMIT UNITS
AI{IATJYTICAI.'
METHODPARJAIT{ETER
GII-5A-OeO2O5 OglaZloS L2:45 OO5
Cadmium
Selenium
Arsenie
Barium
Nicke1
Vanadium
CalcJ.um
Potassirrrn
Magrnesirrrn
Sodlum
Chloroform
Chloride
Fluoride
Nl-trate
NiLrate-Nitrlte
pH
Sulfate
Ammonia aa N
GTI-5B-O9O2O5 A9lO2l OS 13 :3O 007
Cadrnium
Arsenic
Barl-um
NickeI
Iread
Vanadium
Zinc
Calciurn
Pot,aeeir:rn
MagResium
SodLum
Zirconl-um
Ctr]-oroforrn
ChIorLde
Fluorlde
Nltrate
Nl-trate-Nltrite
pH
Sulfate
Armonia as N
o.0024 B
0.0087 B
0.01-2 B
o -24
0.021 B
0.0028 B
l-900
1400
1400 ir
8500
0 .55 LT
42OAA 0
1.0 rJ
110 0
1100 0
7.O
3300 J, Q
7800 0
0.052 B
0. 050
0.17
0.1{
0 - 035
0-01L B
o - 1_1-
1?00
110 0
1900 J
14 000
0-032 B
4-2
t_3 0000 0
o.29 J
1300
1300 O
7.O
8800 ,J, Q
3s000 o
0, o20
0.040
0.0L5
0. 010
0.040
o-010
2.0
30
2.4
50
1.0
1-000
0,10
0-1"0
50
0. J.0
1000
254
0, l_0
0.030
0, 020
0.080
o - 0060
o. 020
0.040
2.4
30
2.O
50
o ,l-5
1.0
4 000
o.10
0, 10
50
0. L0
2s00
10 00
mg /r,
mg/r-,
mg/r,
ng/t,
mg/t
rng /T,
mg /r,
mg/T'
mg/T.
rw/r'
ug/L
rrrrg/r'
r*g / t,
rrrg/r,
rlr.g/T,
No Units
nq/r'
mg/t'
nlg/T'
ntg/T'
mg/T,
mg /r'
nlg./t
mg/t
mg/L
ms/L
mglr,
mg/t'
rftS /T"
rng /T"
ugh'
rq/t
rlg,/t'
mg /t,
ng/t,
No Unit,s
Irlrg/t
mg/L
sw846 6A2A
sw846 5020
sw845 60L08
sw845 50108
sw81r 5 6 0108
grr84 6 6 0108
sw845 60108
sw845 60108
sw8(15 50108
sw845 50108
sw845 8260B
IYICAIII?{ 325 .2
MCAITffi 34O.2
MCABIII 353.2
MCAWW 353 -2
sw845 90408
MCA}TI{ 37 5 .4
MCAWW 350. L
sw845 6020
sw845 60108
sw846 60108
sw84 5 6 0108
sw846 50108
gw8{5 50108
sw846 60L0B
swB46 50108
swB45 60LOB
sYr846 50108
9w845 60108
9w846 60108
sw845 82608
MCAWW 325.2
I{CAWW 340,2
McAWriI 353 .2
MCAWW 353 .2
9w845 90408
II{CAV{W 37 5 .4
MCAWW 350.1
STL Denver
MEIHODS
D5rO30139
PARAMETER
A}IAIJYTICAIJ
I'IETIIOD
PREPARATION
METHOD
pH Agueous
ChlorLde (eolorimeEric, Automated Ferricyanide)
Fluortde (PotentiometrLc, Ion Selectlve Electrode)
fnducE,Lve1y Coupled Plaema (fCp) pretals
rcP-Ms (6o2al
Mercury in Ltquid $[aet,e (tlarrual Co]d-Vapor]
Nitrate
Nl-t,raLe-t{itrite
Nitrogen, Arnmonia
Sulfate
Tot,al eyanlde
Trace fnductJ-vely Coupled Plasna (ICP) Meta1a
Vo1atile Organies by GCIMS
Referenceg:
MCAWTiI
sw84 6
sw845 90408
MCAWW 325 -2
MCAVIW 34A.2
sr{846 50108
sw845 6020
sw84 5 747 0A
MCAWW 353.2
MCATVW 353 .2
MCAWW 350.1
IT|CAWW 375 .4
gr{845 9O1OB/901
gvit84 5 50108
sw845 82608
gw8{5 90408
MCAWW 325.2
I.{CAIlm 34O .2
sw845 3 0104
9w846 3 0204
sril845 7470A
MCAI{W 353 .2
MCA9IW 353 .2
MCAWW 350.1
![eAItIIil 3 75 .4
9w846 90108
sw845 3 010A
sw845 503 AB/ 826
tMethoda for Chemical Analysie of water and wastea,,
epa-eoO/+-79-020, Marctr 1983 and aubeequent revieions.
'rTest Methode for EvaluaElng Solld waste, PhysLcal/Chenical
Methoden, T'hlrd Edition, Noveniber 1985 and lte updatee-
o
STL Denver
o MEIHOD/AI{ALYSTW
D5IO30L39
AI{IATJYST
AI{AIJYTIEAI.I
METHOD
AI{AIJYST
ID
oo1 L57
o051181
oo4 382
o04 382
o0558 9
oa2s62
2852
o055115
664s
oo5 929
6929
0t-1658
0o925 0
oo6s8 9
0044 0 9
MgAum 32.5.2
MCAWW 340.2
MCAWW 350.L
MCAI{II 353 .2
MCAhI$I 375.4
sw846 50108
9w846 60L0B
sw845 50108
sw846 6010B
gw8{15 6a20
sw846 6A20
9w846 7470n-
sw846 82508
sw846 eol oB/ 9012A
9w846 90408
Referenceg:
MCA}flT{
sw846
Ewa Kudla
Fougrere M. Danielle
C1al-re L,ikar
Claire Likar
Dusti O. Crlqut
Jane1 Motichka
'Janel Motichka
Lynn-Arure Trude1l
I-,ynn-Arrne Tnrdell
Thornas I-,i11
Thomas lrll}
*Tanice g - Co11!ne
Heather Degprea
Dueti O- Criqui
andrita Scofield
iMethode for chenical Analyeis of lvater a[d lvaBtes!.
epe,-eoo/+-79-o2o, March 1983 and subsequent revlelone.
,Teet Methods for Evaluating 9o11d waBEe, Physical/Chernical
MeEhodE", Tlrird EdLEion, Novedber 1985 and its updates,
STL Denver
SAIVIPLE
D5rO30139
SAI{PLED SAI'{P
DATE :rIMEwo#SAMPLE#CIrIEIiff SAII{PLE ID
HJIo(rJ 00L
HJXlr2 0 02
HJJQ(g OO3
H,IJ(OA 0 04
H.IXOD OO5
HiD(OF OO5
H,JXOH OA7
rurts(s) :
TB- O90205
Gr{-R]_- 09020s
cvr- s9 - 09 02 0s
chr- s8 - 09 02 0s
cw-s7- o9020s
GW-5A-090205
Grs-58-090205
oe/oz/os
oe/02/os oe:35
a9 / 02/ os 1o:10
09 / oz/ os L1-: oo
a9/02/os l-1:45
09/ 02l os L2:45
oe/az/as t-3:30
- Tho rulyticd rsqrlo of tbc samplG $stcd rbovo rrc presarcd on thc loltowi4 prgcs.
- All cstculilions trc porfomc.f bcforc roundlag o rvoitt ioud<ff crrors in crlorhtcd rurdts
- Radts Dot d rs 'ND' wcrc not dercded 8t or rbovc thc garcd llmlr
- TDis rpon muc noa bo rc?rodrcGd, qcq}t io fu[. witDut he wrluan rpprovat of thc laboraory.
- Rcsillts for lhe foltowlng putmeterr .rc ncvcr rq,orted on r dry n cight basis: oolor. corroslvfu, deDcity, It sbpoirt isnitability. laycrs odor,
poi$ frlEr tEst. pH, porodty pressrc, rcrctivlry, rcdox potcotial. ryccific anvlty, spot test8, solits. sotubitity, tcrnperaurre. vlsoosity, rnd wefhr.
STL Denver
Iotr-Saq)I-e *- - -:
Ilat.e Saryll-ed.--!
Erep Dateo!,..-l
Prep Batsch *-. - I
Di]-ution Factor:
IIR8 Corarcration
c1Lent saryfle rD: ats-ogo20s
*hG vol-atileo
nork Order *.--! HifXlffrlAC
Ilate Received- - : 09 / 03 / 05
Anaaysie Date. - r 09 113/05
Ana-lyeie Ti-ne- - 3 12 : 13
Itgthod- . . . . - - - - : SlI845 82608
Dsr030139-001
oe / 02/ os
aeh 3 /os
5257247
1
Irlatri:r -WQ
PARAMETgR R.ESULT
REPORTING
IrfMfT UNITS
Chloroform
SURROGATE
TID
PERCENT
RECO\IERY
1. O ug/l'
RECO\ERY
I,IMITS
( zE J.r.8 )(az 128)
fie 118 )(tt 117 )
D L b romo f luo r ome t trane
L, z-Dlehloroethane- d+
4 -Bromofluorobenzene
Toluene-dB
102
96
99
100
STL Denver
IIRB Corporation
Cl.ient San4rL= ID: gr-R1-O9O2O5
Gtr.l''6 vo].ati]"es
Irot-garyile #.--3
Date sam[rl.ed-.,!
Pre5l Ilate. - - - - - i
kep Batdt *- - -:
Dilutlon Factor:
Dsr03 013 9- 002
ae/oz/as o9:35
oe/L3/os
52 57247
1
Inork Order *- . - !
Ilate Becefired- - !
lnaJ-ysl-a Date- - !
Analysls Ttre- - I
tlethod.--,---.-E
REgUL'T
ND
PERCEI{IT
R.EC-Olt',ERY
97
90
98
96
H[JO(2LA-7
oe/a3/as
ae/L3/os
12:31
sw84 5 8264}j-
REPORTING
LTMIT UNITS
llErtrfu(.--.-..--: GW
PARJAIT{ETER
Chloroforrn
SURROGATE
1.0 vg/T'
RECO\IERY
LIMfTS
(7i 1LB )
Gz 128 )
( ze 118)
(ll LL-t)
DLbromofIuoromethane
L, z-DichloroeEhane - d4
4 -Bromofluorobenzene
Toluene-dB
STL Denver
Corporati.on
Client 8aryfle ID: G$-99-09O205
gtr.ll,rg VoIatl.IeB
IIRS
t6t-garyl1e *- - -:
Ilate 8alryIed,-.-3
Prep Datg--.-..1
fep Batch *-. - !
Dl-I.ution Faetror:
D5r030139-O03
09/02/as t o:10
0e/13/os
s257207
1
Ilork Order *-..:
Date Receirred- - i
Analysis llate- . 3
Analyaie Ti.me- - 3
Uethod-.o.o--.-I
RESUITI__.-_.
ND
PERCETUT
RECOVERY
96
89
10s
102
I{fi0(91A,J
oe/ot/os
oe/u/as
L2..50
sw84 6 826 0B
REPORTING
LIIT{IT TINITS
1.0 :ug/l'
RECO\IERY
LIMTTS
(tt 118 )
(52 128 )
( ze 11,8 )
(77 117 )
I.latrfur- o - . ., . - - r Gt{
PARAMETER
Chloroform
SURROGATE
Dibromof luoromethane
L, Z-Pichloroethane - d4
4 -Bromofluorobenzene
Toluene-dB
STL Denver L2
IIRA Cor;nration
C1ient 8aryrl-e ID: GDI-S8-O9O2O5
GC/INS Vo]-atl-Ies
o
Iot-8aryfle f;. -. :
Date garytl.ed.---!
firep Datg--O-.-!
Prep Batch #- - - 3
Dilution Factor:
D5r0301.39-004
ae/a2/os 1-l-:oo
oe/L3/os
5257 207
1
Itork Order *-. - !
Date Recelrred.- - i
l[na1yg1s Date- - 3
ana-lysie Tt"re. - l
lilettrod,--o-.----l
RESUITT
ND
PEREENT
RECOVERY
93
90
100
104
HJX0A1A.I
ae / o3los
oeln/0s
L3 :08
sw845 82608
REPORTING
I,IMTT I]NITS
t{atrix---! GTI
PARAMETER
Chloroform
gT]RROGATE
1. o :ulg/t
RECOVERY
I-IIMITS
(tt 118 )
(ez 128 )
Qa 118 )
(zt 117 )
Dlbromof luoromethane
L, 2- Dt ctrloroethane - d4
4 -Bromofluorobenzene
Toluene-dB
STL Denver 13
IrBg Corporation
cl'ient saryl}e ID: Gfl-97-O9O2O5
w,fis volatiles
Lot-ganpl.e f;- - -:
Date Saryfied- -.3
Prep Dateo.--.-i
kep Batch *- - - i
Dil.ution Factor:
D5r03 013 9- 005
09/a2/os 11:45
oe /L3 / os
5257207
1
ilork Order *...3
Ilate necelved-. !
Analysio Date- - 3
Ana1ysie fime- - 3
Dlgthod-..-o----:
RESUITT .,._
ND
PERCENT
RECO\IERY
97
98
92
97
HiTXODI-AJ
oe / 03 /0s
ae/L3/os
L3 =27
sw84 5 825 0B
REPORTTNCI
IJIMTT UNITS
Itatrlrr- - - - - - - ,,: c[9I
PARAIT{ETER
Chloroform
STIRROGATE
1 . 0 ug/I'
RECO\IERY
IJIMITS
(73 118 )
loz L28l
( zs 118)
(zz Lt7)
Dibromofluoromethane
L, 2-Di chloroeEhEule - d4
4 -Bromofluorobenzene
Toluene-d8
STL Denver 74
IIRA Corporat'ion
Cl.ient Saqrle ID: Gf-54-0902O5
gf,lug volatll'ee
Lot,-Saqll.e *- - - 3
Ilate Saqll.ed---3
kep Datg----..3
Prep Batclh *- - -:
Di1utLon Factor:
Dsr030139-005
ae/ oz/ os L2:45
oe/L3/os
5257207
I
Hork On:dsr *- - - 3
Date Recelved- - 3
Ana.Iygis Date- - !
.Enal-yeig Ti-rne- - 3
Irlothod-
RESIII,T
o-55 ir
PERCENT
RECOVERY
104
104
97
9L
H,II(0F14*T
oe I 03/0s
oe / rrlos
1.3 :45
sw8{6 82508
REPORTING
LIMIT I]NTTS
Uatsrtx--rO-o.--3 GW
PARAMETER
Chloroform
SURROG}ATE
1- O rug,l[,
RECO\TERY
ITIIvIf TS
(7t L18 )
(62 128 )
(78 118)
(77 117 )
Dibromofluoromethane
1 , 2 -Dtchloroethane - d4
4 - Bromo f luoroberrz ene
Toluene-dB
rufE (s) :
J Estimetcd result. Resutt is less than RL.
STL Denver
Lot-Sarqlle #- - - :
Ilate Seq)Ied,--i
Prep Ilate----.-3
fep Batdr f---:
Di]-utLm Factor:
IrRg Corporatlon
Cl-ient Saqrle ID: Gtt-58-O9O2O5
eclr,le Vol.atil.es
flork Order *...3 H{IXOHIA,J
Datse Recelved. - 3 09/ o:/os
lna1ysis Date- - i A9 / B / A5
Anal-ysis TiEe- - 3 14 : 04
lnetlrcd- . - - - . - - - 3 SI{845 82608
Itlatrlx- o - . e , , , , : GTIDsr030r-39-007
oe/oz/as 13:30
oe/n/as
5257207
1
PARJAII{ETER
REPORTING
RESqf_- ..- - LIMIT ITNITg
1. O ugll'
RECO\IERY
IJIMITS
(73 1L8 )(az L28)
( ze 11.8 )(77 La7)
Ch].oroform
STIRROGATE
4-2
PERCE}UT
RECO\IERY
Dibromof luoromethane
L, 2- Dichloroethane- d4
4 -Bromofluorobenzene
Toluene-dB
105
115
103
90
STL Denver 15
Iot-Saqlle *- - - 3
Date Sar4lled---I
PARAMETER
IIRS Corporation
CJ.ient Saryr1e ID: ffi-R1-O9O2O5
IUILL Irletal.e
D5r0301_3s-002
09 / 02/ os 09 :35 rlate Received- - : 09 /03/05
RESUITT
REPORrING
LIMIT T]NITS METHOD
PREPARATTON- WORI(
AI{ALYSIS DATE ORDER #
GW
Prep Batch *. - -:
Cadmlum
Se]-enium
5249515
ND
o - oo21
#.. - 3 52496L7
ND
0.00L0 $tg/T'
Dllutiou Factor: I
O - OO2O Wln
Dilution Factor: 1
O. O1O mg/f,
Dilution Factor; I-
O - 10 frg,ll'
Dilution Faetor: I
o - O15 ury,lt
Dl}ution Fact,or: L
O - O1O rglt
Dllution FacEor: 1
O -2o rylr,
Dl.IutLon Factor: 1
O. O10 fitg/L
Dllutton Factor: 1
O . 010 ng /t'
Dllutlon Faetor: 1
O - 10 wglr'
Dilutl"on Factor: 1
3. o Wll,
DLluE,ion Factor r L
o - 20 trg,lT,
Dilutsion Factor: 1
5-o Wll,
ul-lutlon F'actor; 1
(Contlnued on
sw846 5020
Anelysio TiBe..: 08:05
sH845 6020
Aoalyeie Time-.r 08:05
sw845 60108
Analyaia Tirre. . : 1{ : 58
6'H946 50108
Analyaie Tirne. , ; L7 t2{;
sfl845 60108
Analyele Tima..: 1{:58
sr846 50108
Analyeie Tirnc. . : 14 : 58
sIrS{6 60108
Analyeie Time- . : L7 : 2,*
sw845 60108
Analysie Time, . : 1{ :58
sw845 5 0108
Analygls Time.-: 14:58
grf846 60108
Analyels Time,.: L7:24
sr845 60108
Analyeie Tine. . ; t7 t21
6'rrg45 60108
ena).yele Tlme, . ; l7 t24
sr845 50108
Analysie Time. . : L7 r24
next page)
09 / 15 - a9 / 23 / os HrrI0(21A3
09 I Ls- a9 I 23 I os g'ncrzuL4
a9 / 1s- a9 /L6 I as HiDO(zLAIr
a9 I Ls-og ILG I os g,nBzxArr
Preryl Batch
SLlver
Alrmtnun
Arseol,c
Barirrm
ea-I.cirun
Ctrromlum
Copper
Iron
PotaBsiutrl
Itagnesium
8odftm
a -26
o_o1-4 B
o, o82
110
IID
ITD
3-2
27
49J
46',O
aells-oe/L6/os
ae/1s-oe/L6/os
oe lLs-oe llsl as
oe lLs-oel L6l os
aelLs-aelL6los
oe /Ls-oe lLGl os
H,IT()(2LAII{
H.Dfiz1Al{
II^TE2LAXT
EIIICTzLLX
II,IE2LAO
IITE2I.eI-
oel,Ls-oell.Bl os Hi,*l
09 I 1s- 09 I ae I as H,.DrxzLLrr
oe I Ls- a9 I Ls I os n'nrf,zr-jav
STL Denver
URS Corporatl-on
C1ient Saqfle ID: GII-R1-O9O2O5
IOtrIL Hetal-s
Iot-Saryrl-e *- - - : D5IO3O139- 002
REPORTING
PARAMETER RESIII,T I,IMTT UNITS MHTHOD
Hatri-x ------! GVI
PREPARATTON- TilORK
A}IAIJYSIS DATE ORDBR #
!rid(el. 0.00r.6 B o.o.ro rylt, sf,846 5o1oB oclts-ogltelos EirEr21jaP
fread
Dilution Factor: 1 Aralyela T1!le..: 1l:58
0.0030 nslr, sw846 5o1oB og/ts-og/rc/os Hirxx2LAQ
Dllutlon Factor: 1 Analyaie Tirne..: 1{:58
0.010 ry/r, sr{846 6oloB og/ts-ag/to/o5 H.rrcl(2LAR
Dllutlotr Factor: 1 ADalyele Tlue.,: 1l:58
Vanadj-um ND
ZLnc,ND 0.020 rqg/t SW846 5O1OB O9/L5-O9/L6/OS Hirx)t2lAT
DLlutlon Factor! 1 lEalyeie Tine..: 1l:58
Zirc@-trn o.oo1z B o-o1s rylt s[s46 60108 oglts-agltelos rfrErrB2
Dilutlon tractor: 1 Analyaie rlne..z L7z2l
luD
Etep Batch *- - -: 5258350
Mercury IUD
rurE(s) :
0.00020 nl./n sw846 747oA agltg/os HirpplAu
Dilutio. Factori 1 Analysls tlme..: 18:55
B Estimatod result. Rourlt is less than RL.
I Method blanl( contamination. Thc assoclatod rnethod blarrk couins thc target analyte at a rcponsblc lel,cl,
STL Denver 1-8
Ipt-garyll.e $---:
Date Sarylled,--3
PARiAIUIETER
IIR8 Corlrcration
Clleut 8aryflr= ID: G[-99-O9O2O5
$SDAL lletal.s
D5I030139-003
a9 / 02/ os 10 r 10 rlate Received- - r a9 / 03/05
RESTILT
REPORTING
IrfI[IT UNITS TIETHOD
GW
PREPARJR,TTON- WORK
AI{ALYSTS DATE ORDER #
Prq) Batch *- - -:
Cadml-um
Selenium
5249 61- 5
ND
ND
0.0010 mg/I'
Dil-utioa FacEor I 1
0.0020 ng/I'
PL].ut,l.on Eactor: r,
O. O1O nrg/L
DLlutLon Factor: 1
0.10 ry/I'
Dilutlon Factor: 1
0.015 mg/L
Dilution Fastror; I
O - O1O ryl['
PilutLor. E'aetor: 1
o -2o rylt
Pl"lutlm FacBor: L
o. O1O rylt,
Dllutrton Factor: 1
0.010 mg/t
Dllution Factor: 1
O,10 rry/t
Dilutiou Factor: L
3.O rgl['
Dl,lutLon Factor: 1
o. zo rog,ll,
Dilution Factor: l.
5- o Wll,
DLlutlon Factor: 1
(Conttnued on
sw846 6020
Inalyeie Tlme..; 08:08
sw846 602A
Analysr.s Ttme. . : 08: 08
gltl84 6 6 0108
.Rnalyeie Time. . ; 15 : 03
5'W845 50108
Analyeia Tirne. . : L7 :29
sv{845 60108
Analyeig TLme. . : 15: 03
sH846 60108
Analyela Tlme..: 15:03
swB45 601(}8
Analyeie Timc. . : L7 :29
sw845 50LOB
nnalyele TLmB. . : 15: O3
sw846 6 01_08
Anal.ysis Tl-me- . : I-5 : O3
sw8{6 60108
Analysl-g TLme. - : L7 :29
sr58{6 60108
Analyel-a TLmer. . : L-I 229
gn8{6 60108
Analyele Tlme- . : L7 t29
gDrE{6 50r-oB
AIaaIyElE Tl.me, . : L7 ;29
next page)
oe / r-s- oe /23 / as Hfi(x91AE
oe / 1s - ag lzt / os Hilo(elA^r
Prep Bat,clr
Sl-lver
A.f.uri-urn
Areenlc
Barium
Ca-I-eirrm
Chromi:rm
Copper
fron
btassLum
uaglrresirrm
aodLum
#---: 5249617
ND
o-15
IUD
o-19
14
o.019
t[D
o-28
38
10J
190
oe/1s-ae/Le/os
oel1s -oelrr los
oshs- os/16 los
oe las-oe lL6los
oelrs -oelL0 los
oells -oelr.alas
ae /Ls- oe / ts / os
oe lts-oe lLe /os
oells-oelL6las
ae l,ts-ae /L5l os
oe lLs-ae lL6l as
H'J'Q(g ].AR
H.Trcf,gLAT
H,Do(eo
EIXTXgULV
E DEr9ID'5
Erg,gLAr
Hirx)rglAX
H,If?gUL5
IIiDET9ILT
H,IlrvgLAA
II^nCfgaAe
o
STL Denver
IIRa @rporation
client 8qile ID: 6f-89-O9O2O5
IEELIr l{etaf.g
Iot-SaEp]-e *. - -: D5IO30139-003
REPORTING
PARAIYIETER RESTILT T.IMS uNrrs MEfiIOD
l{atri:r- , , ? ? - . - - : GRI
PREPAR^B,TION- WORK
AI{ALYSIS DATE ORDER #
Irt-ele].
Iread
Vanadium
ZLnc
ZLrconium
Prep Batch *- - -:
Mercur1r
tscrE (s) :
o-oo70 B
ND
ND
ND
ND
s2583 5 0
ND
o. o40 sry,lr,
oi1ution Faetor: I
0.0030 mg/t
Dilutsion Factor: t
0. 010 mg/r,
Dllutlon Factor:1
0. 020 mg/T,
Dilution Factor: 1
0.015 rtug/r'
Dt"lutlon Pactor: 1
O. O002O mg/I'
Dllutlou I'actor: 1
selLs-oe llsl os
ae/r.s-ae/L6/as
oells-0e/L6/05
oe/ 1s- aeh 5/os
oe/ 1s- oe/16/ os
EinrrgrLo
Hfl(J(g141
HJXXg7A2
H;rJffig1A3
H,JXI(914D
g118{6 50108
Analyele Tl-me. - : 15 : O3
sw845 5-O108
Analyale TLme.-: 15:03
sw846 50108
Aualyala TJ.me. . : t5: 03
sw845 50108
Aualyslc Time..: 15:03
sw84 5 60108
Analysle Tlme. . : L7 :29
9w846 747AA O?/L,/O5
.[nalysle Tl.me. . : 19 :OO
HJ)O(gLA'4
, lvlcEod blrr* contremlnatiort- The associated mc$od blrnk oontrino tbo trrga rnalyte et s rcponable lorel.
B Eg,imated resrrlt. Regtlt ig loss thsn RL-
STL Denver 2A
Iot-Saryl1e *- - -:
Date Saqlled,---!
PARAMETER
uBg CorSrcration
Client Saryr}-e ID: Gfl-S8-O9O2O5
TUEAIT lteta-Ls
D5IO30r.39-O04
09 / oz/ os 11" : 00 rlate Recelved,. . r 09 / a3 / os
RESUIJT
REPORTING
ITIIvIIT [INITS TT{ETHOD
ilatrlx---,,--l
PREPARATION-
AIIAIJYSIS DATE
O
GW
WORK
ORDER #
Prep Batdr #.
Silver
Aluminum
Areeni g
Barirm
Ca^LcLru
Chroml-um
Copper
Iron
Potsa.eslum
tiagnesl-um
Sodirua
: 52495L7
ND
ND
o -L2
o-11
110
ND
ND
o ,49
95
28a ir
13 00
ae/1s-ae/L6/os
oe/1s-oe/L6/a5
oe /Ls-aelL6 | os
oe lLs-aef Ls / as
oe lls-oe llsl os
oe / 1s - oeh 6/os
oe/ls-oe/L6/as
oe lls-ae lL6/ as
oel r.s- oe/L6los
oel15 -oe /LGlos
oe lLs-aelLelos
HirJ(OA1AR
HJJ(OA1AT
HirxoAltruo
E'nXOAIA\I
E.IXOAIJAs
IIJ]TOAI.AW
Hirr(oA1Ax
ILIXOA1AS
H.IXOAIB,T
IIiDCOAI.JAA
H,txoaliac
Prep Batscb #- -
eaenl,rm
SeIenl-um
: 5249616
o- ooo32 B
o - oo20
0 - OO1O wglT'
DlluUlon Faetor; 1
O - 0O2O Wlt,
Dilution Factror: 1
0,010 mg/t
Dl-Iutl-on Factor: 1
O,1O rW/t
Dl}utLon, Factor: I
O- 015 rylL
Dilutioa Pactor: 1
O - O1O ry,IL
Dl.lutlon Factor: 1
O - 20 rry/l'
Dl.luElon Factor: 1
0.010 mg/L
Dilution Faetor: - 1
0.010 mS/L
Dl-lutlon Factor: 1
O.1O rylt
Dl-lutLon Fact,or: 1
3-O rg,IL
Di}ut,ion Factor: 1
O-20 ry,II-
ffilution Factor: L
25 rglt,
DtluEton Factor: 5
(Continued
sr846 6020
Aaalyeia Time..: 08:12
sr846 5020
Analyaia Time..: O8:12
srf,846 50108
Analygle Tlme..: L5:08
swB4 6 60 L08
Aualysle TLme..: L7:3{
9H845 60108
Analyeia Timc.,r 15:08
g11846 60108
Analyais Time-.: 15:08
sr8{6 60108
AualyeLe Time-.: 17:34
sw846 60108
.nnalyele rime. -: 15:OB
swB45 60108
Analygle TLme-.: 15:O8
sw845 60108
Arralyele Tl-me. . : L7 :34
srr845 501OB
enalyoLs fime. . ; L7 234
sw8{6 60108
Arralysle Time. . : 17 :3{
9II845 50108
Analyeia Timc..: 18:10
nexE page)
09 / L5-o9l23l os E'rxoAljag
ae /Ls-ag /z3l os rrrrxoAl-iap
STL Denver
Lot-Saq,Ie
PARAITIETER
TIRII CorporatLm.
Client 8aryr1e ID: ffi-S8-O9O2o5
TCIEAIT lle,ta-Lg
Dsr030139-004
RESUITT
REPORTING
LIMIT UNITS METHOD
llatri:r----o----: GW
PREPARJATTON- WORK
AI\IAIJYSIS DATE ORDER #
oe I Ls- oe f Lo I os E^TxoAl.Bo
09 / i-s - 09 / 1,G / as HiD(oA1Al
oe / i.s - as / L6 / as HiD(oAtA2
oe hs-oe I LG I os Erxoiarl3
oe I L5- a9 f Lo I os ErxoArLD
HJXOA1A4
Ifi-cIEeI.
Vanadl-um
Zl.rconinm
Prep Bat&
Mercury
o. oo27 B
o-oo93 B
o-oo38 B
o-040 wlt
DL]ution Factor; 1
O.0O3O mg/t'
Dilutioa Factor: 1
0.010 ng /l'
Dilution Factor: 1
O - O2O ry,lr,
olIut,lon Factor: 1
o-o15 ry,ll"l
Dilution Factor: L
0.0O02O mg/t
DLlutlou Factor: 1
s"r845 60108
Analyeis Timc-.: 15:08
sw845 5010B
Analyels T{me..: 15:08
sw84 6 5010B
Analyele Time. . : 15: 08
srr845 60108
Aaalyeie TLme-.: 15:08
sw846 60108
Analysie Tima. , : L7 234
gsr845 747aA Ae/Le/os
Analyels TLme. . : 19: 01
B Esdmrted re$rlr. Rcsulr Is less thtn RL.
J Method blank contaminarioa. The assoclatod metbod blenk contrins thc arget analyte st a reporuble larel.
STL Denver 22
URA Corporatl.ou
Cl-ient Saryr1e ID: GDI-97-O9O2O5
ltOlf,Alr tletal.s
Dsr030139-005
a9 / az / os L1 : 45 Date neceirred- . 3 09 103 /05
RESULT
REPORTING
IJIMTT T'NTTS METHOD
PREPARATION_ TTORK
AI{AI'YSIS DATE ORDER #
o
Iot-Sary)Ie *,.-i
Date $aqtled- -.3
PARAMETER
G}T
Prep Ba.teh *- -. :
Cadnium
AeI.eu.iuur
52496L6
o.ooo22 B
o. ooo50 B
o - oo1o ryln
Dilution Factor: r.
O. OO2O rylT'
Dilutj.ou Factor: 1
0. O1O mg/I'
DllutLon Faetor: 1
o-10 ry/t
Dilution FacEor: 1
O - O15 mglf'
Dl,lutlotr Factor: 1
O - OI.O ryln
rrLlutrl.ou Factor: 1
O -2O Wlt'
PLluuion Factor: 1
O. OI.o rylt,
Pj.IutLon Factor: 1
0 , O1O mg/I'
Dilution Faetor: 1
O - tO frg/I'
Dilutioa Factor: 1
3 - O mg/T,
DLlutlon F'actor; I
O - 20 rglT'
Dilution Fact-or: 1
5-O rglr"
Dllution Factor: 1
(Cont.lnued on
slr846 5020
Analyeie Timo..: 08:16
BIf845 5020
Rnalysls Tlme..t 08:15
sw845 60108
Analyels Tirna. . : 15: 13
sH845 60108
Analyaie fime..; L7:39
sH846 50108
Arralyele Time. . : 15 : L3
sn845 50108
Analyer"e Tf-me - . : 15 : 13
9II845 60108
Analyels Tlme..: 17:39
sw845 50108
Analyeig Time..: 15:13
sw845 50108
lnalysls Tl"me. . : 15 : 13
911846 50108
lDaIyBlB TLme,,: 17:39
sr846 60108
Analygie Time..: 17;39
8[845 60108
.nualyele Tl"me. . : L? : 39
sr846 60108
Analysla Tlme.-: 17:39
next page)
09 l1s- a9 123 I os H'DroDxLB
ae f Ls- ae I zt I os g'rxoDrar
PrgI) Batrch *. - - 3
Silver
Ahnt:num
Arsenie
Barirn
CaI-cirm
Chrmirm
Copper
Iron
Potaseitnn
l[agnesirun
Sodirm
52{96L7
luD
3-1
o- 0056 B
o .30
L7
o. oo51 B
ND
4-5
64
11 J
d40
ae/1s-oe/L6/os
og lts-oelLe I os
aelLs-oelr.e I os
oel:-s-oe ll.e /os
aef L5-oe llol os
oe lLs-oelr.e I os
oells-oe/L6/os
aefLs-aelaelos
oehs-aelL6los
oe/ rs- oelL6las
oel ls- oelL6/os
HJXODlAR
E.TNOD1JLT
:-"4
E'IXODLAV
EtrfoDUtrs
H'IXOD1JAIS
Hirr(0D1Ax
EirxoDl-,8.5
H,if:fODID'7
H'IXODIAA
E..TXODIAE
STL Denver
Iot-Sary)I-e
IIRA Corporation
Cl.Lent Sary)Ie ID: ffi-S7-O9O2O5
Il(If,ilL l.let,al-s
*-..: D5IO30139-005
REPORTING
fratrl-x-r-r-!-o-: GW
PREPARATTON- WORK
ANAI,YSIS DATE ORDER #PARAMETER REST'I,T
IIickeI
TTMTT UNITS I,IETHOD
Vanadhm
Zireonfirm
Prep Batcll
Mercury
nc):rE (s) :
o-oo52 B
o - oo44
0.0096 B
o-o14 B
o-oo{7 B
*- - - i 5258350
l[D
O - O4O ry,Ill
Di1ution Factor; 1
O - OO3O Wlt'
Dilution Factror: 1
O - O1O rytl['
Dllutl-on Factor: 1
O - O2o rylr,
DLlutlon Factor: 1
O - 0L5 vglt'
Dilution Factor; 1
O.0002O ,rllr9/T,
Dilut,ioa Faetor; 1
9n846 5O1OB AglLs-OglLFlOs ETXODaAO
Aualyele ?lme-.: 15:13
slrr81t6 5O1OB Og/Ls-OglLelAS H,ilJ(oDIAl
enalysl,s TLme, . : L5 : L3
sr845 60108 O9lL5-A9lL6lAs HirxoDI.Aa
AnalyeLe Tlme..: 15:13
5'1846 60108 A9lL5-O9lL6lOs E,TXODTL3
naelygig TLrre. , : 15: L3
sr846 60108 O9lL5-A9lL6lAs H,rXODrAn
Analyele Time. . : L7 t39
gTf846 747oh Ae/Le/os
AnalyeLa Tlme- . : 19: O3
HiD(OD1A4
B Esdmatetl re$lt. Rcsuh Is lcss than RL,
J Method blaok contrmination. Thc associued rrothod blank onhinc the targcr analyte &t a r€portabte hvel.
STL Denver 24
Ipt-8aryl1e *- - -:
Itate Sarqt1ed,--.1
PAIUAMETER
t Rs corporatsion
Cl.l-ent 9aryr1e ID: ffi-64-090205
IICTDAL HCt,AlS
D5I030139-006
a9 / 02 / os L2 :45 rlat'e necelrred- . 3 og / 03 / as
RESULT
REPORTTNG
IJIMIT TINTTS Tt{ETHOD
IlatrL:r-,?----! GVI
PREPARATION- [{ORK
ANAIJYSIS DATE ORDER *
Prep Batch f;- -.3
Cadnium
SeI.enirm
s2496L6
o-oo24 B
o, oo87 B
o-o20
DLlutrlon
o, o40
Dllution
rglt"
Factor r 2O
Ery,lI-
Faetor: 20
0.010 nq /L
Dilutlon Factor: L
I. O rlg,/L
DlLutlon Factor: 1O
O. O15 nry,It'
DLlution Factor: 1
O. O1O ry,II'
Dl]utLon FactorI L
2-A rylr"'
Dl1utj"on Factor: 1O
0 . 010 rng /I'
Dl-Iutl-on E'a.ct'or: 1
0.01-0 mg/L
Di]-ut,ion Faetor: 1
1- 0 mg/L
Dilution Factor: 10
30 frglT'
Dilution Factor: 10
2.o wlT,
DlluE l.on Factor ; 10
50 rylr,
Dilution Factor: 10
(ContLnued on
sH845 6020
Analyoie Tfune..; 0B;19
9II845 6020
Analyslo Time-.: OB:19
sw846 60108
enalyeis Time. . : 15: l,B
sw846 50108
AnalyeJ.e Tlme. . ; L8 : a5
srrE{6 60108
Analycla TLmc..: 15:18
srIE{6 501(}8
Analysie TLme..: 15;18
sH845 50108
Aaalysla Tlme. . ; tB rL5
sw8{5 501_08
Analyele Time. -: 15:18
sw845 60108
AnalyeJ.e TLme. . : 15: 18
sw84 5 60108
Analyeie Time.. r 18:L5
9w845 60108
Arlalygie Time., : LB ; 15
5rr845 60108
Analysie TLme..: LB:15
srr846 60108
Arralyale TLma..: 18:15
next page)
oe I Ls-ag I z3 I os lrrrxorraE
09 I Ls *ae I zr I os Hirf,oxtl;ar
Prep BateJr
Sl-Iver
eluminum
Arsenic
Barirm
Catclum
Chromiurn
Copper
Iron
Potassirilt
Diagnesirm
Eodl.trn
#. - - 3 52496L7
ND
ND
o-olz B
o -24
19(}0
ND
ND
ND
1400
1{OO J
8600
oe/ls-oe/L6/os
oells-ae/Le/as
oel1s -aelL6los
oely-s-oe1relos
oe ly-s-oelLe l os
oells-oe/L6/os
ae/r.s-ae/L6/os
ae/1s-oelLe/os
oelLs-oe l,''glos
oell.s-oe ltg/os
ae lls-ae ll.e /os
HJD(OF1AR
IILIr(0F1AT
=-.-o
HlTxOFLB\I
Hirxotrrjas
HJXOFIAW
HJXOFI^LK
H;D(oF.145
H,:I[OFlAT
H,ffiOTLAA
EirIOFilAC
STL Denver
Una Corlrontl@
cueut 8a4rle ID: @l-6j1.-o9o2os
SCf,AL Hetarg
Irot-Saqr1e *- - -: D5I03o139-oO5 llatrbr- -. . : GW
REPORTING PREPARATION- WORK
PARAMBTER RESUIJT IJIMIT UNITS MBT}IOD AIIAITYSTS DATE ORDER #
nLclrel 0.021 B o-o4o ryllt sr846 60108 o9lt5-O9ll:6l0s EJITOF,,AO
Lead
Diluttotr Factor: 1 ADalyela rimc..: 15:l'8
ND G 0-016 tQs/L SW845 60108 O9/15-O9/L6/05 H.rXoFtAl
Di}ullon factor: 1 Arra)'yels Tima..: 15:18
vanadlnn o-oo2s B o,olo ry,lr, sig46 60108 o9lu5-o9lrr6los EiIIorrIt2
Zinc
Dllution tractor: 1 Analysia Time..: 15:18
ND o.o2o ng,/r, sw846 60108 oe/Ls-o9ll6/os H,rr(oFrag
ZLrconlum ND
DLlutl.on Fector: 1 laalyala Airnc.-: 15:18
0.15 nq/r' 9w846 50108 os/ts-ol/t9los H,rxoFlAD
Dllution Factor: 10 AEalyEia !ime--: 18115
0. ooo2o rq,/r, sr845 74"toL ogltg/os HirxoFrA4
Dr.Iutl.oE rtactor! 1 Analyaie rine-.: 19:95
Prep Bat&, *- - -: 5258350
Mercury ND
rrufB(s):
B Eetirnrmd result. Rcsult is loss firrn RL.
I Metbod bl8ilt( contaruiortloo. Tho assoctated method blank contrins the targot analytc st a reportable level,
G Elo,atetl reponlng limh. The reporting limit is clevetcd drrc to matrix interferencc.
STL Denver 26
Iot-Saq>}e #. - -:
Date Salryt1ed---!
PARAI"IETER
URg Corgroration,
Cl-ierrt Salql1e ID: GII-68-O9O2O5
lIOtrAIr lteta-I-s
Dsr030139-007
ag / a2/ os 13 : 30 fiate Received- . 3 ag' /03105
RESUIJT
REPORTING
I,IMIT T,NITS METHOD
fiatrl-x.------i GW
PREPARATION- WORK
AI{AITYSIS DATE ORDER #
Prep Batch
Cafuirm
Selenlum
#- - -: 524961-5
o. o52 B
: 52496L7
ND
ND
o-o5(}
o_17
1700
ND
ND
ND
1100
1900 ir
14000
o-10
Dilution
0,20
DLlution
ry,lr'
Faetor;100
ms/L
Factor: 10O
0.020 mg/L,
ol].ution Factor: 2
l- . 0 rrrg/L
Dilution F'actor: 10
O - o3o W/f,
Dilution Eactor: 2
O. O2O rytlT'
oLlutLoa Factror; 2
2 -O rylT'
DLlution Factor: 10
0.020 mg/T'
Dilutio,n PacEor: 2
0.020 wg./I'
DiluElon Factor: 2
L . 0 rng/t
Dllutlon Pactor: 1O
30 rglt
Dilution Factor: LO
2 -O ry/1,
Dilution FacEor: 10
50 rylr,
Dllutl.on Factor: 1O
(Continued
sn846 6020
Rnalyele Tlm6..; 08;23
9w845 6020
AnalysLe TLme--: 08:23
sw846 50108
Analyets Tl,me. . : 21: 10
sw846 50108
Analysls Tl,me., : L8 ; 2O
sllrS{6 60108
Analysle Tlme. . : 21,: LO
srr845 50108
Analyoie Tl-me. . : 21: 1O
9H846 60108
Rn^alyele Time. . : 18 : 20
sw845 60108
.nnalysr.s TL.me. . : 21 : 1O
slr846 60108
Aaalyeie Tlme.. r 21:10
sw84 5 60108
Analysio Time. . : 19 :2O
slr845 60L0B
Analyele TLme..: 18:20
sr845 60108
Arralysle TLme. . : 18 :20
91846 50108
Rnalyale TJfie.,; 18:20
next, page)
oel ls- oelz3|os Eilxourag
og / 15 - 09 / 2g / as H.TxoHlAF
Prep Batch #. - -Silver
Aluminum
Arseu.l.c
Barirrrr
Ca1cfum
Ctrrornium
Copper
Iron
Potassirrn
Ualpresium
Sodirm
oe/1s-ae/L6/os
aelrs-oe/Le/os
H\TXOH]-AR
H.D(0HLAT
O
oelt-s-oefrefos "*rU
09 I Ls-og I LG I os H.rxoHLLv
agf Ls-oglts/ os Ernrogrns
09/15-09/1,6/os
oe/ts-ae/16/os
oe/1,s-oe/Le/os
agll-s-oelLelas
oel r.s- oel:.:elas
aells-oe lLgl os
H.]X0H1AW
Hirr(0HLAx
HJXOH1A6
EilXOHUhT
ILfXOELAA
ETXOHLAC
STL Denver
Iot-saryr1e
PARAMETER
rIRs corlrcratlon
C1ient 8aqrle ID: ffi-5B-O9O2O5
I1O([AI, Itleta-Le
Dsr030139-007
RESUI,T
REPORTING
LfMIT UNITS METHOD
Itartrljr- - - . . - r - - : CIW
PREPARATION- TilORK
AI{AIrYsrS DATE ORDER #
IUidre1
Vanadirut
Z'ilic
Zl-reoaium
PreI) Batch
Mercury
rrotrE (s) :
o-f,4
o-o35
o-o11 B
o-11
o. o32 B
o-o80 rylr,
Dilution Factor: 2
O - OOSo rylt
PLlutlon Faetor: 2
o-o20 rytlr'
Dllutlon FaeEor: 2
o-040 urslr
DLluUlon Factor: 2
0-t5 nglr,
Dj"lut.l.on Faetor; LO
O,OAZA rrg,/T'
Dilutioa Factor: 1O
811846 60108
.nnalysLs TLrne, . : 21: 10
srr846 60108
Anal-yeie Tlrne. . : 21: 1O
grrE/[5 50108
^Analysla Tl-me. - : 21 : 10
sf,845 60108
Analygis Tl-me. . ; 2L: 10
sH846 50108
Analyala Tl"me. . : 18 : 2O
slr84 5
Analygie
747A4
TLme..: L9:26
oe I Ls-og I Le I os n'tf,onrao
oel15- 09 I LG I os IrJxoELat.
og/rs -oe I LG I os g,nronran
oe I Ls-og I Le I os E^rxoEril3
oe I Ls-oe I Lg I os EtxoHLeD
oel22/os HiD[OH1A4
B E*imated result, Rcsult Is lese thur RL-
, Motlrcd blank comemination. Tho ausociatcd nrcdrod blenk contains fre targu analyte ar a reporubte level.
STL Denver
Iot-8aryrle *- - -:
Date Sary>}ed---I
PARA}IETER
IIRA eorporation
Client Saryrl-e ID: ffi-81-O902o5
Geueral. Cheuirtry
Dsf 030139 -OOZ Hork Order #.,. i HifX)(2
og / oz/ os 09 : 35 rlate Receiwed- . ! a9 / a3 / as
RESUTT
7-7
2-7
82O A
TTNITS METHOD
o-10 No uaits sw846 90408 oelorlos
llatrijr-----!-,-: GW
PREPARATTON- PREP
ANAIJYSIS DATE BJATCH #
52461(}(t
s2s7378
s2s2250
5252540
5265579
5265s42
5249586
5257 427
pE
ArrmOnia aa If
ChI-orl.de
Fl.uoride
Nltrate
Nltrate-Nltrlte
Su]-fate
Total Cyanide
rrorfE (8) :
Dilution Factor: 1
o.1O rylt,
Dl].utioa Factor: L
L2 ry,ln
Pilution E'actor; 5
0 - 70 if O.10 rry,Il'
DLlutLon Factor: 1
ND 0. L0 mg/t
Dj.lution Factor: 1
ND o.1o mg/t
DilutLon FacEor: 1
52O ir,Q 1OO ryrlT,
tll-].ution Factor: 20
ND 0.010 nq/1,
nilutioa Pactor: 1
Ana1ysLs Tlme, . : 14: L{
HsAxlr 350 - 1- OglL1l aS
Analygle Tlme..: 05:0O
ucAflr 325 -2 09lA8lAS
Arralysle TLme. . : 10 : OO
ucAIlIf 34O .2 Ael O9I OS
Analyslo Time..: 11t30
MCAr^rr{ 3s3.2 A9/A3/OS
naalyais Tlme..; 12:00
rr{cA$rn 353.2 09/20/Os
Asalyele Tima..: 15:oo
HCAHr 37s-+ OelAFlOS
Raalysie Time..; 14:3O
sw845 e0L oB/ 9012A 09 / 14 - Oe /L5 / 0s
ilnalyeie Tlme., : 12 : 3O
RL Reportlng Llnrlt
a dcvated rcporting limit. Tlre reporting limit ic etevercd due to hlth nnalyte levels.
, Mcthod blank contaminrtion. The associatcd mettrotl blank connins ttre target analyte xt e roportable levcl.
STL Denver
Iot-garylle f;. -. :
Date Saryl1ed.---3
PARAMETER
URg Corporation
Cl.ieut 8aryrIe ID: cf-S9-O9O2O5
Gleneral. ChentetrT
Dsf 030139-003 llork Order fi- - - : H'J)()(g
09 / 02 / 05 1-0 : L0 Date nec.eived. . E a9 / og/os
RESULT RL UNITS METHOD
: G"lg
PREPARATION- PREP
AlrArJYsrs DATE BATCH #
llatllr -
PII
AmronLa aE II
ChLoride
Fl-uoride
Nitrate
8-2
3.5
244 0
ollutl-on Factror: 2
O -72 if O,1O qtlT'
Dilution Faetor: 1
IID 0,10 wtg/I,
DLlution Factor: 1
ND 0.10 nrg/L
Dllutslon Factor; I
2-5 B,J 5-O Wll,
Dllutlon Factor: L
l[D 0. O10 fi]g/I'
Dilution Pactor: 1
8||845 9o4oB OelOrlOS s2151OO
Raalyeie Time..: L4222
ucBHr 3so - 1 oelL4las 525737lt
analyele TLme..: 05:0O
IICAHH 325 -2 O9/OS IAS s25225O
Anal-yglg Tirre- . : 1O : 0O
rrtcAHw 3do -2 ogloglas 5.25254lJ
AualysLs TLme,- . : L1 : 30
MeAWlr 3s3 .2 09 / 03/05 s26s579
Analyais Time-.: 12:0O
McAww 353.2 Ae/zA/os 5265s42
Rnalysls Tlme. . ; 16: OO
lrelxlfr 375 -4 OglO6lAS 5249585
Analyeie Tlme..: 1{:30
sw84 5 eol aB/ 9012A 09 / 1.4 - 09/1 s/os s2s 7 427
Analysig Time..: 12r30
O - 10 No lDlite
Dilutl.ou Eactor: I
O - 10 ryrlf,
DilutLon Factor; 1
5-O Wl\'
O Nirrare-Nir,riLe
Suf-fate
Tota1 Ctranide
IwrB (s)
=
RL Reponing LIrnIt
a Elsvnted repeirting hmit. Thc rcportlng lknlt is slevared duo to hlgh analyn levels.
I Motltod blank contarnination. The associlted mothod blank contairn tlrc targo analyte ar s roporteble lovel.
B Estimatod result. Re,$It ie less than RL.
30STL Denver
Lot-Sarytl.e S- - -:
Date Saryrl.ed.---3
PARAMETER
URS Corgrcration
Client Sauqlle ID: Gil-88-O9O2O5
Genera-l eherniatra/
Hork CIr&r #.-.3 HifX0A
Ilate Receiwed. - 3 Og / Ag / OS
RL IINITS METHOD
HatrlJr,o-,?----: GW
PREPARATTON- PREP
ATIIAITYSIS DATE BATCH #
O
D5r030139-004
oe/02/os 11:oo
RESUITT
pE
Amnia aa lI
Ch].oridn
Fluoride
l{[itraLe
Nl.rrate-ttitrite
SrrLfate
TotaJ. eyasi6*
IUUTB (S} :
7 -g O - 10 I[o [InLto
Pilution Faetor: 1
2 -7 O.1O ug,ll'
Dilution Factor: L
23oo 0 1oo ryll-
ol-Iut,ion Faetor: 4 O
O-85 if O-1O ryll'
Dilution Factor: 1
5-4 O-1O ng,II'
Dllut,{on Factor: 1
5-{O - 10 rylt'
Dl-lut lon Factor; I
.r,Cl 25o rglt"850
oi]-utioa Faetor: 50
O - OO44 B O. O1O rrry,lT,
Dilution Factor: 1
gr8{6
AnalyaLs
HEIIH
Analyois
rieAlrlr
Aaalyeie
ITCBHTT
Analysl.g
}igAIIH
.hnalyeie
HCBITT
Rna,lyele
ricrtllH
Analyois
sH846
Analyaie
1,{ :28
05: O0
1O: O0
11:30
12:00
16: OO
oelaslos
ae lL4l os
oelaBlos
oeloelos
ae la3 I as
oe lzol os
oe I 06l as
s25sso
52{9586
5245100
s257378,
s2s225A
5252s40
s255579
oe / t+-ae llsf os s2sr 4zT
RL Regortiug Limit
a Ehvatcd reponing llrnit. T[o reporting limit is elevatcd duc to high analyte lcvels.
I Mcthod blenk conuamination. The associatcd matrod blank contains rhe targct analyrc at a rcportable level.
B Ertinrarcd rczulr. Resuh is loss then RL.
31STL Denver
fot-Saqll.e #- . - i
Date Saryll.ed---!
PARAMETER
IIRA Co.lnration
Clientr 8arylIe ID: Gt-S7-ogozos
General- Chml-etr1r
D5IO30139-005 f,ork Order *. - - 3 HiD(OD
09 / 02/ as t 1 :45 Date Recelved.- . 3 A9 / 03 / 05
RESUTT RIr UNTTS },IETHOD
lftrtrlJr.-.....,-3 GW
PREPARATION- PRBP
AIIAITYSIS DATE BATCH #
PII
AmpnI.a as If
ChlorLde
Fl-uorlde
ISitrate
8.4
3-g
670 0 20 ry,lL
ffilution Factor: 8
0 - 86 J O.1O rylt'
Pllution Pactror; L
0-060 B O-1O ry,II'
DL1utsLon Factor: 1
O - 060 B O.1O ryll"
DiluE,ion Eaetor: 1
4.6 BrJ 5-o ry,ll,
Dilution Factor: 1
ND 0, OLO mg/I,
tlilutLon Factor; 1
8H846 9O4OB OglA3laS s2tL6LOO
Analyeie Time,, r 1al : 57
lrcJtntr 35o - 1 oellel os s2s7378
Analyeie Tirna. . : 05 : O0
rrcAxtr 32s.2 OglOAlaS s2s2250
Analyeis Time..: IOlOO
ueJ[Ilr 340-2 aeloglos 52s2s{o
Analyela Tirne. . : 11 : 30
licBHrr 3s3 - 2 o9l o3los s265sr9
Analyeis Tl-me- . : 12 : 00
HCFXr 353 -2 Ogl2OlOS s265542
Analyeis Time- . : 15: OO
HGAHH 37s-{ 09106lOS s2.9s86
Analyeie ?ima--: 14:3O
sw845 90108/e012A 09/ 14- oehslos s2s7427
Analyeie Tlme. . : L2; 30
O - 10 IIo t}tl.its
oLlutl-on Factor: 1
O.1O ry,lt'
nilutlon Factor: 1
O Nitrate-xirrire
$rrf-fate
Total Clanlde
norE (s) :
RL Reportirrg Limit
a Ebvated repordng lisrit. The rcporting limir is elcvated due to h[h enelyte levels.
J Mctbod bhnk eonurnlnetion. The asrociarcd me&od btank corlalns Oe target analyte a[ 8 roporuble level.
B Estirnatod result. Resltt is less than RL.
STL Denver 32
Iot-garylJ,e *---:
Date Saryfled,-. - !
PARJN,IETER
IIRS Corporatl.on
Cl-Lent Saqrl.o ID: GDI-5A-O9O2O5
ceneral. Chffiisiry
D5f030139-005 Work Order *-.. i HJX0F
09/02/os L2:4s Date Received- - 3 og/03105
RE9UT,T RIJ T]NITS METHOD
I.Iatri:r - - - - - - . - - : GTt
PREPARATTON- PREP
ANATYSIS DATE BATCH #
PII
Amnia aE It
ChI.orLde
F]-uoride
ltl.trate
I5l-trate-Ititrite
$uAfate
Total CyanJ-de
rufB(8):
7-O
zgoo 0 zso rytlr,
Dl.lution Factor: 2500
42OOO O 1OOO ry,lt
Dilution Factor: {OO
1-O ir o.l-o ry,lr,
Dilution Factor: 1
11OO O-1O Wlt
Pt1uti"on Factor: 1
1100 a so rylr,
PLlutl.on Factsor: 500
33OO.J,O l.ooo try/l'
Pllutlon Eactor: 2OO
r$D o . o1o mg /t
Dilution Faetorr 1
O - 10 lto Unl.t'e
Di.lutloa Factor: I
sH8{5 eo{oB Ogl0sl0,s
Analyeie Time,.: 15:04
rrcBHH 3sO - 1 Ogf 2O/OS
Analyeie Time. . : 17: O0
rrrcArrr 32s -2 09/OS I OS
Rnalysle Tl,me. . : LO : 00
lrcAHrr 34A -Z O9l A9 / OS
Analyals Tlme..: 1L:30
ueArrr 3s3-2 ogloBIos
hraLyaie Timc..: 12:0o
HoIHH 353 -2 A9I?OIOS
Analyeie Time..: 16:00
rrcBrr 375 - 4 09106l os
Analysls Tlme..: 1{:3O
sw845 eol oB/ eol2A 09 /L[-Oe /t-S/ os
Arralyel.n fl,me. . ; 1.2 : 3O
52451_Oo
526s4?.1
s252250
s2s254L
526ss7e
s25so
s249586,
s2s7i[27
RL Rcporting Limit
a Elevated reportlng limir The reponing limit is elevated due to high rnelyte levels.
I Method blnnk contamination. Tho associeted metrod blank conains he rarger analyte Dt e reporhblo level.
STL Denver
Iot-Saryfie *---:
Ilate Saryll.ed,.--I
PARAMETER
IIR8 Corgnration
Cl.l.eut $aqrle ID: GH-58-O9O2O5
Genera-l Chemistry
D5I030139-007 Hork Order *.. .: Hfl(0H
09 / 02/ as 13 :3 0 Date Recelrred- - ! 09 / 03/05
RESTIIJT RIJ T'NITS ME:rHOD
r.ratrlJc--.!.,..-i Gw
PREPARATION-
AI{AIJYSTS DATE
PREP
BATCTI.. #
pE
Amonia aa If
Chloride
F].uoride
Illtrate
Nitrate-HitrLte
Srrf.fate
Tota1 Cyanide
!ror3 (B) :
7 -O O - 10 rro UnLte
Diluclon Factor: 1
3sooo 0 l-ooo rylt
DllutLon Fsctor: 100OO
13oooo 0 {ooo wlt
DllutLon FacEor: 1600
O - 29 if O.1O rgll*
DllutLon Factor: 1
L3OO O -1O rrg,ll-
Dilution Faetor: L
1300 0 so ryIlr'
DLlutlon Factor: 500
88OO *I, Q 25OO nrgtlr,
Pilution Factor: 5O0
ND O . 010 mg /T'
Dilution Factor: 1
BrI845 9o4OB A9l $lOS 5245r-OO
Analysie Tlme-.: 15:09
DrelrrH 35o - t- oglL4los 52s7378
AnalysLe Tlrue. - : 05 : 0O
ucBrfl 32s -2 ae/oBlOs s2s225A
AnalygLg TLrtte, . : 10: OO
r nr 340.2 og/aglos s2s2s{:
Analyel-s Tirtre. . : 11 : 30
IICBWH 353 - 2 O9l O3l OS 5265s79
nnalyaie Time. . : 1"2 : OO
r|Gnr 3s3.2 oe/zAlOS s26s542
.Analyeis Tirne. - : 15: O0
lrcAHH 3 75 - 4 Oe I A6l 05 s2{9s8 5
AnalysLs TLme..: 14:30
shr846 e01os/e0r.2A oe/ 1{- oe/Ls/os s2s7427
Analyeia ?irne. - : 12 :30
RL ReponinB Lirnit
a Ehvated reporting limit. Thc reponing limit is elevatod duc to high uralytc levels.
I Msthod blank contarnination. The associarcd metrod blank contrins tbc targot rnalyte nt a reponablc level-
STL Denver 34
acrlATAAsSffiw
D5rO30139
Sample Preparatlon and analysis Control Numbers
SAIvIPL,E#I'IATRIX
O
o01
o02
o03
004
wQ
GW
GW
GW
GW
GW
GW
GW
Gv[
G[{
ctw
GW
GW
GTI{
Gti[
GW
GW
GW
GW
GW
GT{
GW
GTg
GW
GUI
GW
clvg
GTg
GW
GW
GW
GW
GW
GW
Gtw
GIW
Glltf
AIVAIJYTICAIJ
I,TETHOD
I,EACH
BATCH #
sw845 82608
MCAItn{ 325 .2
MCAWW 340.2
pleAww 353 .2
MCAWW 353 .2
sw846 901O8/9O12A
sw845 602A
swg(15 7470A-
sw846 90408
sw845 82608
sw845 60108
MCAI{W 375.4
D{CA}m 350 - L
MCAWW 325.2
MCAItm 340 .2
MCJLIIIVT 353 .2
MCJIhII^I 353 .2
gw8{5 eo]' oB/ e012A
sw8{16 5A2A
9w845 7470A-
9w846 90408
gvr846 82608
sw846 60108
MCAWW 375.4
I'ICAIIil{ 350 ,l-
IyICAI{I{ 325 .2
MCAWW 340.2
MCAWW 353 .2
MCAIiIyS 353 - 2
sw845 eolaB/9012A
sw845 6020
sw845 7 47 0\
sw845 90408
sw845 82608
sw845 50L0B
MCAWW 37s -4
MCAWW 350.1
(Contl-nued on next page)
PREP
BATCH #
5257207
52s2250
s252540
s265542
5255579
5257 427
s249616
s2583 50
52461- 0 0
52572A7
52496L7
5249585
52s737 g
52527^50
525254 0
5265s42
5265s7 9
5257 427
5249 5 16
52583 s0
52451 00
5257207
52495L7
s249s I 5
s257378
5252250
s25 2544
5265542
526ss79
5257427
52496L5
5258350
s24610 0
s2s72A7
52496L7
s2L95 I 5
s257378
MS Rt'N#
s257L35
52ss23 1
s255099
526533 9
5257289
5249357
52s823 0
52513 84
525713 5
52493 s8
5249328
5257262
525523 1
5255099
525s3 3 9
5257 289
52493s7
525823 0
52513 I 4
5257 13 5
52493 58
52493 28
5257262
5255 237,
5255099
526s33 9
5257289
52493 5 7
525823 0
52s13 84
5257135
s2493 58
5249328
525'1262
o
STL Denver
QCI}ATA ONSUffi
D5IO30139
Sample Preparation and analysie Control
SAI.{PtE*IvIATRIX
005
006
oo7
GW
GliI
GW
GW
GT{
GW
GW
GYI
Glil
GW
GW
GW
GW
GW
Gl'r
GW
GW
GW
GW
GW
GhI
GVT
GW
G}Ti[
GW
GI,{
GW
Glw
GIi[
GW
GW
GW
G[tr
GW
GW
GW
AI'{IAIrYTIeAL
MEflIOD
MCASII{ 325.2
I{CAWW 340.2
illeAllm 353-2
MCAI{T{ 353 .2
sw846 901OE/ eo12A
sw845 602A
sw845 747AA
sw846 9 04 0B
su[846 82508
sw845 60108
MCAI{ril 375 .4
MCJLWSI 350,1
MeAItm 325 -z
MCAITIW 34O -2
MCAWnT 353.2
MCAWUT 353 .2
sw846 901 AB/ 9012A
sw84 5 5020
sw8{5 7470,''^
grrl8{6 90408
sr{845 82508
sw845 50108
MCAYTW 3 75 .4
MCAWW 350.1
MCAWW 325.2
ITICAWW 34O .2
MCAWW 353.2
MCAWW 353.2
sw846 9o1AB/ 9012A
sw846 5A2|o^
SIlf846 7 47 AA
sril846 90408
sr{845 82608
sw846 6 0 r.08
II{CAWW 375 .4
MCAUTW 350.1
LEACH
BATCH *
Nr:mbers
PREP
BATCH #
52522 5 0
52s2s4A
526s542
s26557 9
5257 427
5249 6 r-6
s2s83 5 0
52451 00
5257247
52496L7
524958 6
s25737 I
52s22sO
525254 1
5255 542
526ss79
5257 42?
52496 1 6
5258350
5245100
52 5 7207
52495l.7
s249s I 6
526s424
52s22sO
52s2s4L
s26ss42
526s s79
52s7 427
5249616
5262486
5245100
5257207
52496L7
s249s I 5
s2s7 37 8
MS RT]N*
52ss23L
5255099
52 5533 9
s257289
52493s7
525823 0
52513 84
5257L35
5249358
5249328
5257262
s25523 1
s255102
526533 9
5257289
52493 s7
5258230
52513 84
5257 L3 5
s24 93 58
s249328
s265330
s25523L
5255102
52553 3 9
5257289
s2493 57
s252328
52513 8{
525713 5
52493 5 I
5249328
5257262
STL Denver
}IETEOD BTf,NK RBFOET
sclrf,B vol.atLl.ee
Hork Order *.Cl.ient lot *- - -:
llB lot-Saryil-e *:
Ana1ygLg Date- - l
ol-Iutl.on Factor:
PARAMETER
D5r03 01-3 9
Dsr140000 -207
ae/L3/os
1
uatrLx- - e -, - - - - ! WATER
Ana-lysis Tl-re- - 3 09 : 05
METHOD
Prep flate.
Prep Bateh
RESI ITT
HKHAE1AA
oe/L3/os
s2 s 7207;:
REPORTING
ITIMIT IINITS
Ch]-oroform
SURROG}ATE
DID
PERCENT
RECO\IERY
LOZ
9s
97
100
l-.0 ug/I'
RECO\TERY
LIMITS
(tz 118)
(52 128 )
(za 118)
(77 L17 )
gw84 5 825 0B
Dlbromof Iuoromethane
L, Z-Dichloroethane - de
{ - Brornof luorobenz ene
Toluene-d8
IWIE(S}:
Calcularions ere performed bcfore rourdlng to avoid roundoff errors In calcutued rcsrrltg,
STL Denver
W GOIYI?OLr gBilPIrB EIfAIIIATION REPORT
ecltrg vo].atil-es
Client lpt #---3
IflS Lot,-Sary)Ie*:
Prgp Datg--,.--!
Pre,p Batsc.lr *- - . !
Dl.lution Factor:
PARAIITETBR
Dsr03 0 13 9
D5r14 0 000 -2a7
oe/L3/os
5257207
1
llork Grder *..-: HKHACI-AC
lfnal.ysls Date - - i A9 / L3 / 05
Ana1yeir Tt-me- . 3 08 : 48
I.latrl-x- - - --- -- -: WATER
I-, I.-Didloroethene
Benzene
C'h1.or&elrzene
alolueue
ltLch].orroetlrene
SI}RROGATE
PERCENT
RECOVERY
85
90
100
94
86
RECO\TERY
L,IMffS
(ee 132)
(7s 12(})
(zs 118)
(78 118)
('19 L22)
PEREENT
RECO\IERY
100
88
96
101
IUETHOD
9H846 82608
g11846 82508
8H8{5 82508
g18{6 82508
srr8{6 82508
R.ECO\rERY
LNIETS
03 118 )(ez 128 )(ze 118)
(77 117 )
D ibrorno f luorome thane
l, 2-Dlchloroethane -d4
4 -Bromofluorobenzene
Toluene-dB
NurE (s) :
Calculations arc porfonDcd beforo rourdin3 to svoid round-off eron in calculetod re$Is-
Bold prlnt denotes conrol paruno06rl
STL Denver 38
ffi CUlEtsOt An}iPLB ITATA REBORT
GC/Hs Volatil-es
C]-l.ent IoL #. - - l
rcg tot-Saq)Ie*:
Pree Da.te------!
Pxep Bat,ch. *. . - 3
Dl-].ution Factor:
PARAMETER
D5IO30139 Hork Order *-
D5I140000 *2A7
ae/r,3/os
s257207
1
Analyeis
aual.yele
SPTICE
AIYIOUNIT
10-o
10-o
10. o
10. o
10-o
I)aEe -
Tlme.
HKHAClAC
oe/L3/os
08:48
llatrir-!, r O..-.: T{ATER
PERCENT
RECOVERY METHOD
a, a-Dlchf.oroethene
Beuzzeue
ChlOrOlrerrzerte
Tol.uene
TrJ-&Ioroethene
SITRROGATE
Dibromofluoromethane
L, 2-DichloroeLhane- d4
4 -Bromofluorobenzene
Toluene-d.8
IWTE (S} ;
ME.A,ST}RED
AI{OI}NT
8-58
9-Os
9-99
9-35
8-5{
PERCENT
RECO\JIERY
100
88
95
101
T]NITg
ug/r,
qglT,
u,glr'
u.glr'
wglr,
RECOI/ERY
I,IMITg
(tt 1rB )(sz 128 )(za 118 )(tt LL7II
91845 825o,d-
911846 82508
g11846 82508
sf,845 82508
sw845 82508
86
90
1(}0
94
85',
Calqrlations are performd before rounding to rvoid rcund-off orron in calcrftted results.
Bold print derrotes control parirmctcrs
STL Denver
Client lot ]---:
llS Iots-8ary>I.e *:
Ilate Eaqlled-.-3
Prep llate- - - - - - 3
kep Bateh *... i
Dl,Iution Faetor:
PARAMETER
1, I.-Dishloroetlrenr=
Benzeue
Ch1orobeuzene
Tol.uene
firichf-or:oethene
SURROGATE
D ibrorno f I uoromethane
L, Z-Dlchloroet hane - d4
4 -Bromofluorobenzene
Toluene-dB
IUTB(S):
PERCENT REEOTfBRY
RECO\IERY TJIMITS
RPD
RPD IrfMfTg
Iulatrlxo -.. o. - -- 3 I{ATER
METHOD
ItrIRIr SPIffi EAIIPLB ffi REPORT
ercltls Vo1atiles
D5I03O139 llork Order S- - - : HJ7.I8LAC-M8
D5f 080384- 01-B Hir7,T81Af)-MgD
09 / oB /05 16 : 1o Date Recelrred- - : 09 / oe / os
Og / L3 I oS anal.yele Date, . 3 09 / L3 / os
52572A7 mal-ysia TtJre. . ! 10:40
1
111
96
r.03
101
LO7
107
I-O8
109
101
90
(6e
(ee
(7s
(7s
(78
(7s
(78
(78
(tg
ltg
132)
132)
120)
120)
118)
118)
118)
118)
I.22l
L22l
1{ (0-26}
2-O (O-21)
o - 05 (o-2o)
o - 96 (A-ZZI
srw846 82508
gtr846 82508
81846 82608
9n846 82608
8f,846 82508
915846 82608
9H846 82608
811846 82608
sr845 82608
srr846 8260811
PERCBIT
RECO\TERY
99
92
96
88
96
LO2
89
93
(o-23)
RECO\IERY
I,IMITS
( za 118)
(tz 118 )
(62 128 )
(62 L28 )
(78 1L8 )
(78 118)
(tz L17)
(tt 117 )
C.alculstions arc porformed bcfore rourrding to avoid round+ff srroro in calcutated resul$.
Bold print denotes control pararncrere
STL Denver 40
O
Cf-ient Iot *- -. E
HS Ipt-Saryr1e *:
Date Slaqpled--.i
kep Date--o---!
Prep Batch *...:
Dl,hrtion Factor:
PARAMETER
tmTRIf SPIffi SAIIPI'B DAT[, RBPORI
trfn$ vol.atiles
Hork Order *.. .3
Date Received- . r
^Bna1yal-e Date, . i
.Bna1yele fi-E- - 3
D5I03 013 9
D5rO80384-018
09 / oBlos 16 : i.o
ae/L3/as
5257207
1
HLITirE1AC-MSI lratrfur. - . - . - - . - : WATER
H'J7'J8IAD-lvlgD
oe l 08/os
oe /L3 / os
L0 :40
SAI.{PIrE SPfKE MEASRD
AIUOUNT ry_ AI.{OUNT UNITS
PERCMT
REC\/RY RPD MEITIOD
L,L-Dichf,ortrethene
Beu.zene
Chf.orobenzene
ToI.uene
trichlonoetlrene
ST'RROGATE
D I bromo f I uo r ornetharr e
L, z-Pichloroethane - d4
4 -Bromofluorobenzene
Toluene-d8
NO'IE (S) :
ND
ITD
IID
ND
IID
ITD
ND
IID
o-19
o-r-8
u{glI"
1uglI.
Iu(glL
u,gl\'
lu.glt'
Iu.glt
U.glL
ug/r,
u.glr,
ug/r,
111
96
103
101
LA7
LO7
108
r.o9
to1
90
RECO\TERY
IJIMITS
10-o 11-1
10-o 9-64
10. o 10 -3
10- o 10,1
10-O 10- 7
10. o Lo -7
10-o 10-g
10 - o 1(}-9
10. o 10 -3
10-o g-22
PERCETIT
R.ECO\IERY
99
92
96
88
96
LO2
89
93
srr846 82608
14 S1846 82608
sr846 82608
2 -A 5:1846 82608
8II8+5 82608
o - 05 9tr845 825(}8
9H845 82508
o.96 811846 825(,8
sw845 82508
11 8rt846 82608
(73 118 )
(tt 11- 8 )
(ez 128 )
(62 L28 )
( 78 1t-8 )
(ze 1L8)
(tt i.1r )
(tz 117)
Cdlctrlations are pcrformod bcforo rounding to avoid round+ffcrrorc In cetarlatcd rcsults.
Bold prlnt dcnotcs sontrol parametors
STL Denver
UETXOD BI,ATSK REFORT
ItCf,Lf, Hetale
Client Lot #.
PARAMETER
: D5r030139
RESUITf
R.EPORTING
I-,IMIT T]NITS
llatri:r, ! o,,-- -.: WATER
METHOD
PREPARATTON- WORI(
AIIAL,YSIS DATE ORDER #
HB Lot-Aalqll.e
CadmLurn
Selenium
llB Iot-Sary>Ie
Alurnlnum
Areenic
Barlum
Caleium
ChrornLum
Copper
fron
I-,ead,
0 - 01-0 rng /T'
Dilution Factror: 1
Aaalyels Tlrne- . : 1{ ; 13
O.2O mg/1,
Dllut,lon Faetor: L
AnalyeLe TimB..; L6:19
0.0I-0 mg/t'
Dl}ut.ton FacEor: 1
Analyglg Time. . : 14 :13
O . 010 rftg /I'
Dllutl-on F'actor: 1
Analysie Tl-me. . : 14 :13
o.10 mg/L
PLluEl.on Factor: L
AnaJ-ysls Tlrna. . : 16 :19
0.0030 rnS/L,
DiluElon Faetor: I.
Analyels Tlme..: 1r:13
(Continued on next
52496L6
sw846 5020
svl846 6020
52t196a7
sw846 60108
9w845 50108
slIE{l5 5 0L08
a9 / Ls - 09 / 2t / os HJ2.]cLAA
a9 / 1s - 09 /23 / os H.r2rTclAC
oe / 1s - 09 / L6 / as HJzirirr'Ac
a9As- as / LG / os HJ2J,y1AD
ae / ls- as / L6 / 05 H.f2.ru1AF
#: D5I050000-616 PreI, Batch *- . . :
IUD 0.001-0 firg/T'
DlluE,lon Factor: L
Ana1ysle ?ime. . : O7 :L7
ND 0. 0020 $q/L
ollutlon Factor: t
nnalysle Tima. . : 01 :L'7
*: D5I060000 -6L7 Prep Batch *- - - :
ND 0-l-0 rW/L
Dilutlon FacLorr 1
Analysie Tlme..: 15:19
ND 0. 0L5 *g/t
oilutLon Fector: 1
Analyel,c Tlme. . : 1{ ; 13
sw846 50108 a9 / 15 - 09 / L6 / os H,Jz.TJ1AE
sw845 5',0108 oe / 1s - a9 / L6 / os H,J2J'JLAIU
ND
ND
ND
ND
sw846 60108 oe/ 1s- oe/L6/as HJ2JJLAG
sw84 5 60108 ae / 1s - oe / L6 / 05 H,r2,rJlAr{
gI{84 6 a9 / ls - 09 / LG / os HJ2.fLT1A.y
STL Denver
IUD
page)
5 010B
42
IIETEOD BIAITK RBFORI
llUEHIr lleta-Ls
C].ient lot
PARAMETER
D5r03013e
RESULT
REPORTING
*- - - :uatrir - - - -, - - - + : WATER
PREPARATION- WORK
AI{AIJYSIS DATE ORDER #IJIMIT..,-- UNITS METHOD
I[agEesiun o-o51 B
Nickel
Potassl-um
Sl-lver
SodLum IUD
Vanadium
Zinc ND
Zirconium
ND
o.20
nLlutLon
Analyele
0.040
DLIuElon
ArralyslE
3.0
ol-lutlon
Analyal.e
0. 010
Di].ution
Arra}yels
5-0
DilutrLon
Anal.yala
0.010
PLlutt'on
Analyeis
0.020
DiI'utl-on
Analyoie
0.oLs
Dllut,ioa
Analyeie
rglt'
Factor: 1
Time, . : 16;19
mg/I'
Factor: L
Tl-me..: 1{:I.3
mg/L
Faetor: 1
TI-mc-.: 16;1.9
rng /T,
Factsor: 1
Tl"me..: 14:13
rlg/L
Factor: 1
Tlme..: 1?:I-t
mg/t'
Factor: 1
TLme-.; 14:13
mg /t'
Factor: 1
Tlme..: 1lt:13
mg/r-'
Factor: 1
TJ.me..: 16's19
SW84[5 6010B
9w845 50108
oe I Ls-o} | L6 I 05 Hirzirin-Bo
09 / ls- a9 /rG / os H,lz.rulAll
sw846 60108 ae/1s- oe/L6/os HJ2'JJIAP
sw84 5 5 0108 oe/1s-oe/L6/os HJ2JJ1AA
HJ2JJlARsw84 6 60108 oe / r,s- ae /Lg / os
IUD sw845 60108 asli.s - os / LG / osH.rzrri
ND
llB Iot-Saqrle *: D5I150000-35O prep BatcJr *-. -: 525B3SOMercury ND 0.0oo2o rw/r. sw845 ?470}.
Dllutlon Factor: 1
ilnElyaia Time.. : 18:33
xB lot-Sa4[e *: D5I190000-486 prep Batdr #---: 52624g6uercury ND 0.00020 mg/r. gll845 74?oA
Dllutios Factor: 1
.hnalyeie flrne.. : 19:20
sw846 50r.oB oe/r.s-oe/LGlas HJ2JJIAIr
sr{846 601_08 oe/1s-09/L6/as H.T2J.IIAT
oe/Le/as HKMDTlAA
HK}SL 9 LAA
O
STL Denver
(continued on nexr page)
oe/zz/os
DIEIffiD BITNIK RE,BORI
fiIf,AL l,treta.le
Cf-ient lot, f---: D5f030139 llat,rir- - - . . . - - - 3 WATER
Culorlations arc performcd before nounding to avoid round-off errors in calcrrletcd rcsults.
B Estimated rcsull Roult is tils Ulan RL
STL Denver 44
ffi COIWROL $tr[1p19 BIfAHrATIOIS REFORT
TOTAIT Uetal-e
Lot-Saqile *. - - ! D5I030139 llatri-x- -,,,, - - - r WATER
PARAMETER
PERCE}{IT RECO\TERY
RECO\TERY I,IMITS RPD
RPD
LIMTTS METHOD
PREPARATION-
AI{AI,YSIS DATE
PREP-
BATC'H #
Mercury
rrc,:rB (s) :
10{
1_ 02
( 8s 11"4 )(85 L14, L.2 (O-10)
nl-Iutl.on Factor: 1
SIII845 74704
sw845 747AA
Analyele TLme.. : L9:27
09 /22/ OS s262485
ae /22/ os 5252486
Caloltuioils are performed beforo roundlng to rvold round<rff errons ln catculued resulB.
STL Denver
ffi COISIROIr SA}IPfjB DAIA RmORf
I!gEAL Heta]s
Iot-Saryll-e #-
PARAMETER
Mercury
no:r-E(s):
: D5I030139
SPIKE MEASIIIRED
AII{OT}NT A}!OT'NT I]NTTS
llatri-ro,, r ! -,, ? : WATER
PERCTiIT
REC\TRY
PREPARATTON-
AI{IALYSTS DATE
PREP
BATCH #RPD METHOD
0. oo500 0,00518 mg/L 104 9w845 747AA
o.0o500 0,00512 ,f|'g/t L02 L.2 sw846 747OA-
Dl-Iut,lon Faetor: 1 Analyele Tlme, . : L9:21
oe / 22 / As s262486
ae /22/ os s262486
Calculatloos ere performcd bcforc rourding to evoid rourdoff errors in celculetcd rcsrlts-
STL Denver 46
ffi MNTROI, SEMPI,B ffi RBFONHI
ItCtrAf' l{eta].e
C1ient Iot *- - -:
P]\RAI{ETER
D5rO3 0 13 9
PERCB}TT RECOVERY
RECO\IERY LIII{ITS IVIETHOD
D5I060000-616 Prep Bateh *. - . i 5249616
99 (eg 110) 9w845 5020
Dilution E.aetor: 1 Analyaia
90 (82 LLz) SW845 6020
Dllutlon Faetor: 1 Analysig
DIatri:r. -,.-- o --. i WATER
PREPARATION-
ANALYSIS DATE WORK ORDER #
IrCS lot,-Sary)Ie#:
Cadmlum
9elenlum
I.rCS lrot-Saryrlef:
Silver
Alurninum
Arsenic
Barium
Clrromium
Copper
Nlckel
Iread
Vanadium
ZLnc
Calclum
09 / ts- 09 / 23 / os H,r2JolaD
Time-.; O7t2L
oe / rs - oe / zt / os HJ2JcIAE
Tinre-.: A7:2L
D5I050000- 6L7 Prep Bateh *. - - : 52496L7
(as LL4) SW8{5 601"08 oe / 1s- oe / L6 / as HJ2JirlAU99
97
97
100
99
94
98
97
100
95
98
Dj.lutiou Factsor: L AoalyeLe Tl.me. . : L{ : L8
(86 108) SW846 60108 09 / ls - 09 / LG / os H,r2.Tir1Av
Dilutlon FacEor: 1 AnalysLs TLme..: LG224
(eg 1oe) sw846 60108 09 / 15 - 09 / LG / os H,]zrTirl.Aw
Dilutl-on Factor: 1 Aaalyeie Tima-.: 14:18
(gs 113 ) swg46 GoloB a9 / 1s - 09 / LG / os H.T2JJLiNK
Dllution Factor: 1 enalyeie Time. . ; 1tl : 18
(89 L],z) SW845 50108 oe / ls - oe / L6 / os HJ2JJ1A0
ol.lut,lon Factror: L Analysie TLme. , : 14 :18
(se 110) swr46 50108 09 / l5 - 09 / L6 / os HLTzirJl-Al-
Dilution Faetror: 1 Arralyals Tl"me. . : 1.4 :18
(go 1i-o) swg46 60108 09 / 15 - 09 / L6 / os H.r2ir.TaAz
Dilution Fact,or: 1 enalysle Tlne..: 1{:18
(g:. r-i-1) swg46 GoLoB 09 / 1,5 - 09 / LG / as H.t2J,rI-A3
Dilutioa E'actor: l.Analyal.e TLme. . : 1.4 ;1.8
( 88 LLz) SW846 50108 a9 / 1s - 09 / L6 / as HLr2irJlA4
ollutLon Factor: L Analysls Tlme..: L4:18
(es 110) sw846 601,08 09 / i.s- 09 / LG / os H.T2JJ1As
Dilution tr'actor: l,Analyele Tlme..: L4:LB
(gg 110) sw845 60108 a9 / 15- a9 / Le / os IIJ2JJ1Ao
nllutton Factor: 1 Analyeie TLme..: 17:18
STL Denver
(continued on nect page)
C]-ient Ipt
PARAMETER
Iron
Potaseium
Magneeiurn
Sodium
zirconLum
#.--3 D5I030139
PERCEIiTT
RECO\MRY
96
LO2
98
95
109
W COIFIROL S,BUPIfi ffi
TUEAL lleta-ls
RECO\IERY
I,TMITS METIIOD
(ea 110) sw846 50L08
Dilution Factor: 1 AnalysLs
(s0 111) SW846 60108
DllutLon Factror: I AnalyeLs
(91 1-1-1) SW846 5o1oB
Dilution Faetor: 1 Asalysle
(9r LLz) SW845 5o1oB
Dilution Factor: 1 Analysl.e
REFORT
llatrLr. - o ! . . - . . 3 WATER
PREPARATION-
AT{AI,YSTS DATE WORK ORDER #
a9 / Is - og / LG / 05 H,r2rr\T1A7
Time. . : LGt24
09/ ls- a9/L6/os H,J2JJ1A8
Time. . : t6:24
09 115- A9 /L5 I A5 H,J2,J,J1A9
Tl.tne.. : L5;21
ae / ls - oe / L5 / os HJzir.flcA
TLme..: LGz24
oe / 1s- ae / L6 / as H,J2JJi-cc
Tim6.. : L6t24
09 / L9 / 05 HKMDTI.I\C
TLme- . : 18:35
0s Lzs) swB4G GoloB
frllutlon FacBor: 1 Analyeis
Ifrg lot-Saqile*: D5I150000-350 Prep Batch *- - -: 5258350
Me,reury 97 ( 85 114 ) SWB4G 7 47 AA
Dilution FacEor: l.Analysle
rwfE (s) :
Calculetions arc porforncd bofore roundiry to rvoid rourd-off orrorc in calculated resulB-
STL Denver
O
ffi COilI?OIr AlUPfiB DATA RBFORT
IICItrAIr lfigfal s
C1Lent Iot #- - - i Dsf 030139
SPIKE MEASURED
PARAMETER AI,IOUNT AII,IOUMT UNITS
PERCMT
RECIIRY METHOD
tlatrrJc---,,r---3
PREPARATTON-
AI{AIJYSTS DATE
If,S llot-Saqrle*: D5IO60OOO-615 Prep Batclh *---: 52495L6
cadmium 0.0400 0.0394 nl]/t 99 9w846 6020
Dllutlon Pactor: 1 Aaalyoia Tima. . :
sw846 5020Selenium0.0400 0.0362 mgl[.90
Dilutioa FBqEor: 1 ArBlyela Tlne..:
IICS Iot-Baqr1e*: D5I06O00O-617 Prep Batch *---: 5249617
silver 0.0500 0.0494 xq/t 99 sw845 60108
D1lutlon Factor: 1 nnalyaia Tirna..:
Aluminum z.oo t-95 fiS/r, 97 sw846 60108
Dilution Factor: 1 Analyele tlme..:
Arsenic 2 .oa 1.93 rq/t 97 syr846 60108
DllutL@ Faceor: 1 Analyala Ti.ne,.:
Barl-um 2 . OO 2.OL $rs/r, 100 sW846 50108
DlluElon Factor: 1 Aoalyaia Tirne.,:
Chroml"um 0 .200 0.197 mg/t 99 sw846 60toB
Dilution Factor: 1 tnalyels fl.me..:
copper 0 .zso o .2ts w/t 94 sw845 60108
Dl-}ucl@ FacEor: 1 Analyaie Aima..:
Nickel 0.500 0-491 nrg/t 98 sllg46 60108
Dilutslon Eactor: 1 Arlalyelg Tina- -:
r,ead 0.500 0.483 ms/L 97 SW846 5O1OB
Dllutio Factor: 1 Aa.alyela Tlme..:
vanadlum 0.500 0.499 trg'/L 100 Sw846 60108
Dilutio Factorr 1 AEalyale Tlme-.:
ziI;rc 0 .5o0 0.474 trts/T, 95 sw846 60108
Dil.utlo Bactor: 1 A[alyais Tima..:
calclum 50.0 48. 8 rfis/t, 98 swB46 60108
Dllutie Factor! 1 AnaLyaie Tinc,.:
(ConElnued on next page)
oe/ 1s- oe/zs/as
A7:2L
ae / 1s- oe /23 / os
A'7 z 2t
ae/ 1s- oe/L6/os
14: 18
oe/rs-ae/L6/os
L6 :24
oe/1s-oe/L6/os
1{: 18
oe/Ls-oe/Le/os
14:18
oe/1s-ae/L6/os
l,{ : L8
oe/1s-oe/L6/as
14 :18
oehs-ae/L6/as
14 :18
oeh 5- ae/16/a5
14 :18
oelrs-oe/L6/as
14: 18
aehs-ae/L6/as
14 :18
aells-oe/tg/os
17: 18
WATER
WORK
oRpER t-,.
H'J2JG1AD
HJ2TGIAE
HJ2JJlAU
HL72JJ1AV
HJ2JJIAW
Hr2rrlJ
HJziI'JLAO
H.72,IJIAI
HJ2J{T1A2
HJ2LTrflA3
HJz.IrflA4
H.Iz,f,f]..As
HJ2JJ1A6
O
STL Denver
Cl-ient Iot
PAIU\METER
#---: D5I030139
SPIKE MEAST]RED
AIUOTTNT AIT{OUNT
ffi CUIJr.TBOJ SEUPIiB IEEA REBORT
tlCTEAt, ttetals
TTNITS
PERCNT
RECYRY METHOD
lfatri-x ------3
PREPARATION-
A}IATYSTS DATE
TATER
WORK
ORDER #
fron
Potassiunr
Magnesirrrrr
Sodium
Zirconium
IrIercury
rufB (s) :
L, 00
50. o
50.0
50. o
0,500
DilutLon Faetor: 1
rcS rot-Batqrle*: D5I150000-3so Prep Batclr *- - -:
0.00500 0.00{185 nrg/r,97
Dilutiss Factor: 1
0 ,954 nrg/L 95
Dllutlon Factor: 1
50,9 mg/r.' Laz
DLlution Factor: 1
49.L mg/r, 98
Dllutlon Pactor: 1
47.9 fitg/L 96
DLlution Factror: 1
0.538 ng/t, 1o8
9w846 601_08
Arra1yeJ-a Tlme. . :
sw846 50L08
lnalyrle Tl.me. . :
9w845 50108
AualyslB Tlme..:
s[1t846 50108
enalyets Tlme. .:
sw846 50108
Analyele Time. -:
52583 5 0
sw846 7470A.
Analysia Timc., :
09 / ls- 09 / LG / os H,Iz.I.TLA7
LG t?t
aghs - 09 / L6 / a5 H,r2,r.rLAB
L5 224
ae l]-s-o 9 / Le / os HJ2JJIAe
L5 -,24
a9 / L5 - o 9 / L6 / os HJ2.f,J1ea
L6:.24
oeh s- 09 / L6 / os HJ2,r,Jlcc
L6:21
oe llg / os
18 :35
HKMDT1JAC
Calculetioos Ero porformed bcforc munding to avoid round-off crrors ln calculatod rosults.
STL Denver 50
C1ierrtr Iot *--.: D5I030139
Date Saryll-ed- - - 3 09/ 0I/05 LZzLO
PARAMETER
PERCEMT RECO\TERY
RECO\IERY I,IMITS
US lot-Saryl1e *:
Cadmium 50
69
Selenium L72 N
L49 N
IIS lot-Sanpl.e #:
Aluminum 90
92
Arsenic
IIIAMIX SPTKE SIAI,IPIIE ffi NBPORT
IIO1EAfT Ueta1s
rlate Received- - 3 A9 / 02 / 05
lIatrlx, -',,,, - - i WATER
RPD
IJIMITS METHOD
PREPARATTON-
AIiIAIJYSIS DATE
}IORK
ORDER #
D5IO2023A-0O4 Prep Batc:h *- - -: 52496LG
N (ag 110) sw846 602A
N (89 r.10) rs (o-20) srir846 6020
DLlutLou Factor: 40
Ana}ysle TiEe..I 12:15
(az LLz) sws46 Gozo(82 LLz) 8.9 (o-2Al Sw846 6020
DLlut,ion Factor: {0
Analyala Tima..: 12;16
oe / 1s- 09 /23 I as HWQ91C8
09 /1s- ae / n I os H,nrQ91ee
oe / i.s- oe /23 / as HWeelDA
oe / ls- oe / 23 / os HwQelDC
oe / Ls - oe / Le / as HwQglDo
oe / Ls - oe / Le / as HweglDl
oe / 1s - oe / te / os HinrQg LDz
oe / ls - ae / L6 / os Hiruee 1D3
D5I020230-004 Prep Batch #- - - ! 52496L7(sg 1-l-9) sw845 601-08
(ag 1191 2.2 (O-zs) SW846 60108
oLlutlon Factsor: 1O
J[nalysls Tl-me. . : 17 :32
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Barium
Calcium
Chromium
Copper
L26 N
L25 N
103
103
1- 10
r_08
1,24
L20
NC, MSB
NC, I{SB
(e+ L24l(aa Lz4l L.z (o-2s)
Dilutioa FacEor; 5
Analyeis Time. - : 21: 0O
(es 120)
(ss Lza) o.3o (o-2s)
Dilution Factor: 5
Analyaie Tlme. . : 21: OO
(ea 1s3 )(+e 1s3) (0-2s)
PiluElon Factor: 1O
analysle TLme. . : a7 *2
(73 13s)
(tz 13s) 1.5 (0-25)
DLlution Factor:5
Analyaie Tl,me, . : 21 : 0O
( 8e Lze)(az t29) 3.0 (O-25).
Pllutlon Fact,or; 5
Analyols Tlme-.: 21;00
sw845 60108
sw846 50108
svr845 60L08
swB46 60108
sw845 60108
9w846 60108
sw845 60108
sw845 50108
sw8 4 5' 5 01- 08
sw846 501_08
ae/Ls-oe /rc/os
oe/t.s-oelL6/os
H,J\IQ91D4
H.rfQg1D5
ae/1s-ae/Ls/os
oells-oe/Ls/as
HiruQe1CR
HiruQ91CT
as/1s-oe/L6/as
oe/l.s-ae/LG/as
H.ryQ91eA
HirVQeICC
oe/ls-oe/L6/as
oe/1s-oe/L6/os
H,JlIQ91CD
HiryQg1CE
STL Denver
(ContLnued on next page)
Client lot, #-
Irate Saryt1ed-
PARAMETM ..fron
Iread
Magnesiurn
Nicke1
Potassl-urn
Silver
Sodium
vanadium
Zine
TATRLf, SPTffi S,BIIPI,B EI',LTTBITOIT REFORT
TCfDAI} lletaf-s
Dsr03 013 9
a9 f ot/ as 12 : 10 rlate Recelved- - ! 09 / oz / as
PERCEMT RECO\IERY RPD
RECO\TERY IJIMITS RPD IJIMITS METHOD
---
t--
$z 1s5 ) sw845 5O1OB
$z Lss) s+ (o-2s) sw845 5o1oB
Dilution Factor: 1O
Analyslg TimG..: L7:32
lletriJr- - - - . . - -, i WATER
PREPARATTON- WORK
$.r++rYsrs pArE oRpER #
ae / 1s- oe / Le I os HwQglcu
ae/ r.s - 09 / re / os H.rvQg Lcv
ae / 1s- oe / t5 / os H,rIQgleH
09/ 15- ae/1,6/Os HirvQglCJ
oe / ls- oe / Le / as H.nlQelco
09 / ls - 09 / L9 / os HinrQelcl
as I Ls- oe / L6 / as H,nreg1cF
oe / 1s- oe / L5 / os Hin/QgtcG
09 / 1s- oe / Le / 05 HLn/Qe]-Cr{
oe / 1s- ae / Le / as HWQelcx
oe / 1s - ae / L6 / os Hfireer.Dl{
oe / 1s- ae /La / as HinreelDx
oe / 1s- oglLe / a5 H\T\IQeLez
ae / 1s - oe I Le / os HWQerc3
as/ ls- oe/L6/os H.ryQgleK
oe/ Ls- oe/LG/os Hinreelcr,
ae /Ls-09 / rcl os HwQglcrr{
oe / 1s- oe /L6 / as H,J\reelcr{
NC, MgB
NC, MgB
1"3 I
g7*
87N
1-L2
1 r-0
1_08
l_2s
L24
1 1-0
109
120
L2IL
NC, MSB
NC, MSB
( Be 121)(sg rz1l zs (o_2s)
Dlluul-on Factor: 5
Analysle Time..: 21:00
$z 145)
(ez 145) (0-2s)
Pl-IutLou Factor: 1O
ArralyBle TJ.me, . : L7 232
( s+ r.2o)(aa Lzo) 1 .3 (o*2s)
PLlutLos Factor: 5
Analyols Tlme..: 21:00
(7 6 L32l(76 L32) ( 0-2s)
DLlution Factor: 1o
analyele Tl.me. . ; L7 :32
(zs 1-4r. )(ts 11r1) r-a (o-zsl.
PJ.lutLon Factor: 5
Analyele Tlme..; 21:00
(za 203)
(zo 203) (o-40)
Dilutiou Factor: L0
Analyeia TLme. , : L7 232
(8s LzA)(Bs LzA) o -66 (0-2s)
DlluElon Factor; 5
.Arralyels Timo. . : 21: 00
( 5o 137)
(50 t-37) 3.7 (O-zs)
Dilution Factor: 5
AnalyeJ-e Tlrne - . : 21 : OO
sw845 501OB
sw846 60108
9w846 60108
9w845 60108
sw846 50108
sw845 50108
sv[845 501_08
sw84 6 6 0108
sw84 5 6 0108
sw845 50108
s$[845-60108
sw846 50108
sw845 60108
sw845 50108
sw846 60108
sw846 60108
NC, MgB
NC, MSB
STL Denver
(Continued on next page)
52
Cl.Lent Iot #.
Dat,e 8aqrl.ed.-
PARJAIT{ETER
Zlrconium
r{qrE (sl :
(ao 120)(ao L20) s -z (o-zsl
DLlutl"on Factor: 1O
nnalyals Tlme..: L7:32
}ffiTB,TX SPIre SBIiPLB ffi REPORT
IQfrAIr lleta-ls
D5r030r.39
a9/lL/as L2:Lo rlate Recelrred--3 09/az/as
PERCENT RECO\IERY RPD
RECOTI/ERY ITIMfTS RPD ITIMITS METIIOD
!ta,t,f i-- - . . - O. - - 3 I{ATER
PREPARATION- WORK
4[4I,Ysrs pATE ORpER #
ae / ls- oe / Le I os Hirveg Lcg
09 / 1s - oe / Le / os HirvQg lcs
101
104
9w846 601.08
sw846 50108
&lorlations arc pcrformed boforo roruding to avokl round+ff crrors in crLullled ,csulB.
N Syftcd amlya rccovry ig ousidc S{rd control ltmt6.
NC Thc rccovcry rnd/o, RPD w6rc not crlodetcd.
MSBTbo rccorrcry ud RPD rrcno nol calolM bcceuEe thc srnrylc auroum wrs treet€r t[ra four dmes the rplte emorat.
t Robrirr pcrccm dilfcrcace (RPD) h ortridG $ri.d coilrot ttEirs-
o
STL Denver 53
IffIRf,T SPIXB SEUPI,B DATA REFORT
EXAIr lletara
Client lpt *. . -; D5IO30139 ltatrJ.x- - ..: WATER
Date saryiled- - - = ag/at/os 12:10 Date Receiv6d- -z a9/o2/os
SAMPI,E SPII(E MEASRD PERCXWT PREPARATION. WORK
PA&AMETER AMOT]NT A}"fT AI'OUMT ENITS REC'TIRY RPD MEMIOD ANAIJYSIS DATE ORDER #
lfII l,ot-seqrle *= D5I020230-004 Prep Batch *- - -: 524961-6
CadmLum
ND O-O4OO O -0242 $q/t 60 SW846 6020 O9/L5-O9/23/O5 rrWQ91C8
Qualifiere: N
ND o. o4o0 a.oz77 rns/r, G9 13 swB4G Go2o o9/Ls-o9/23/os H,rtrQglcg
Qualiflers: N
Dtlutlm Eactor: to
AnalyeJ.e Tfirc..: 12:16
Selenium
0.0{o 0.o40o 0.109 N ms/r. \72 swg46 6020 o9/Ls-09/23/os HweglDA
o.04o o.o4oo 0.0998 rrg/t L49 8.9 sw845 6020 O9/Ls-O9/23/As HirvQ9lDC
Qualifiers: N
Dilution Pector: 40
Analyslc TLme.. : L2:7-6
I.lS Iot-Sary)Ie *: D5I020230-004 kel, B.rtch *-. -: 5249617
AIunlil-m
ND 2.OO 1.84 rrtg/r, 90 SW846 5O1OB O9/Ls-091L9/As HWQ91D0
ND 2.Oo 1.88 nqh, 92 2.2 5!{846 60108 O9/L5-O9/L9/O5 HWQ91D1
Dilution Pactor: 10
AnalyeLe TLme. -: L?:32
Arsenic
0.025 2.OO 2.55 N rrrs/r. L26 SW846 5O1OB O9/L5-09/L6/O5 H.rVQ9l.D2
o.02s 2.oo 2.52 N tw/r. Lzs L.2 SVrs{6'60108 Og/L5-Ag/16/O5 HirVO91D3
Dilutlon Factor: 5
Analysla Tlna..: 21:00
Barium
o.41 2.oo 2.47 rw/r, 103 sr{B4G oo:.oB o9/Ls-o9/L6/os HuveglDr
o.41 2.00 2.4a rrg,/r, 103 0.30 sw846 60108 o9/L5-09/L6/os HirvQglDt
DLlutioa Pactotr 5
Analyaia TinG,.: 21:00
Calcium
L500 50.0 1{7O nrg/T'
Quallflere: NCTMSB
1500 50. O 1510 mg/L
Qrralif iere: NC, MSB
Dllutl.on Factor: 10
Analyela TLme-.: L7:32
sw846 60108 ae / 1s- a9 /L9 / Os H.I/QeICR
sw845 50108 09/1,5- A9/L9/os H.rvQgLCT
STL Denver
(Continued on next page)
54
lilTTRET BPIE SN{PTJE I}IITA REFORT
ItCIf,AII ltota1s
Clieut Lt #- - -: D5I030139
Date saqfled---z O9/oL/05 12:10 Date Receiwed. -: 09/02/0s
Itratri:r,,, ? r, - r) . - : WA,TER
PARAMETER
Ctrromium
Copper
Iron
Iread
Magnesl-un
Nicke1
Potaesiurn
SAMPLE SPTKE
AI.{OT,NT AMT
MEJASRD
.AIyIOUNI t NITS
PERCNT
RECI/RY RPD I,IETHOD
PREPARATION- WORK
AI{ALYSIS DATE ORDER #
ND 0.200
ND 0.200
A.219 mg/L
O.216 mg/L
Dilutioa FacEorr
AnaLyels Tima. .:
O.311 mg/f'
O.301 nlg/I'
nllutlon Factor:
Ana1-yele Tlne..:
L .7 6 mg/r,
L .24 * mg /t,
DLlutLon Faetor:
Analysie Tine- -:
0.435 N rrq,/l'
O.558 mg/L
ol"luUl.on f,'actor:
Analysls TLme..:
1 1_0
108 L-5
5
21;00
sw845 50108
sw84 6 60108
ae / rs- 09 I LG / as H;nrQelcA
oe / ls- oe / L6 / os IIWQelcc
ND
ND
0.38
o.38
IUD
ND
12 o0
L200
o , 0J,6
o . 01.5
1700
1700
0.250
0.250
1,00
l-.00
0.500
o - 500
50. o
50. o
0.500
o.500
50, o
50.0
7,24
120
5
2L;0O
r.3 I
87
10
L7232
87
142
5
21:OO
3-0
sw845 60108 09/ts-09/L6/os HwQeLcD
sw846 60108 Ae/1s- oe/L|/Os HinrQelcE
34
25
sw84 5 5o1oB Oe / ls - Ae / Le / Os
sw845 sOLOB Ae/1s- A9lLel}s
sw846 60108 Oe/ls-0e/L6/05
sw845 50LoB ae/ ls- ae/L6/Os
H.rvQg1CU
HinrQgl-C"tr
,,*n
HWQ9I-C,f
118 0 mg/t,
Quall-f Lers : NC, MsB
1?oo ntS/L
Oralif iers : Ne, MSB
DLlutlon Faetor: L0
Analyele Timo-.: L7:32
0.554 nrg/T, 110
0.557 mg/L 108
Dllutlon Factor: 5
Rnalysle Time..: 21:0O
L7 40 mg /1"
Qualif lers : NC, MsB
179 0 mg /t'
Qualifiers: NC,MSB
Dilutl.on Factor: 10
Rualysls Time - . : 7,7 :32
gw84 5 50L 0B
sw845 50108
sw845 50L08
L.3 sw8{6'50108
oe / i.s - oe lLe / os H;nrQelco
a9 / ls - a9 / Le / os Hweelcl
oe / Ls - 09 / L6 / os HirvQelci
09 /L5- a9 /LG / os HLn/Qelc(
sw845 50L08 oe/1s- A9/L9/As H;n/Q91CTV
sw84 5 6 0108 09 / ls - 0e / L9 / 0s H.IIIIQe lcx
STL Denver
(Contlnued on next Page)
!trITIf,' SPIG SAITPIJB DATA RBBORT
IIC):EAL l6gal g
Date Received- - 3 ag l 02 / 05
llatri-x- - . ) - - - - . : I{ATERCf.ient Iot *---:
Date led.,-3
SAI{PIrE
P+RAMETER AIr{OU}im
Silver
ND
ND
D5I030139
a9/orlas 12:1o
SPTKE MEASRD
AMT AMOT]MT
PERCMT
RECURY RPD METHOD
PREPARJATION. WORK
AI{AtYSIS DATE ORDER #T]NITS
O. 0500 0.0 626 mg/L 125
o - 0500 o , 0618 mg/L L24 1 .4
ni]-utloa Factor; 5
AnEI'yBlB Tlme..; 21:00
50.0 31700 fiq,/T'
Qualifiers: NCTMSB
50 . 0 33500 mg /T'
Qualif iere : NC, ![SB
Dilution Factor: 10
AnalysLs Tl-me. . : A7 :tZ
0 . 500 O . 565 fiig/T, 110
0.500 0.551 rrlg./T, 109 0-55
Pl-Iut.ton Factor: 5
Analygie Tirne- . : 21: 00
ae /Ls- o 9 /L6 / a5 HJVQslDvr
aeh s- ae/rc/as HJtreei.Dx
ae/15-aelwlas Hin/Q91-c2
ae l1s- ae / Le/ as HirvQelc3
ae/ ls- ae/L6/os H;nrQglcK
aehs- ae / L6 / os HwQglerr
oe lls - ae l L6 / as Hirveelcl,I
oe / 1s- o9/L6/ os H.r\IQelcN
oel ls - oe / L9 / as H,rrQe lc{t
ae / rs- oe lte / os Hweelcs
sr{84 6
sw846
50108
6010B
Sodium
Vanadium
Zl-nc
33000
33000
0. o14
o.014
0. 024
0. 024
gw84 6
sw845
50108
5010B
Zirconium
I.ID
ND
rucrB (s) :
A.622 $q/L
0.645 rrq.lt
DllutLon Factor:
Analyeia Time. , r
0 - 505 rlrg/r.
a -522 rng/I,
Dilution FacEor;
Arralyelo TLme. . :
sw84 6 60108
gw84 5 601_ 0B
sw84 5 6 0108
3.7 SW846 50108
sI{845 50108
3.2 SI{845 60108
0.500
0-500
o. 500
0.500
120
L24
5
21; 00
L01
L04
10
LT 232
Celoilrfiorn arc pcrfomEd bcfore rounrling o avoil round-off craors ir crtcril.tod rcsulB.
N Splked anelytc rccovcry is oursi<te sla!.d ontrot limiLr-
NC Thc nrovcry md/or RPD wcl! not crlqthEd,
li[SB Thc rccovcry std RPD vGrc Dot cr]o{eud bccause ttre srmplo 8nlomt u/ss gre$or ttun four tifiEs tho qpile emounr.I Rclitlvc pofcd dificrcncc (RPD) b outii(te nstad oodrol r;-iB.
STL Denver
ITtrIT.f,E SPIXB AAIIPTJE BVBI'TNT'IN
SOTIL iletal-s
Cl.r.ent Lot *- - -: D5IO3O139
PERCBIIT RECO\IERY RPD
PARAMETER RECO\TERY IJIiIITS RPD I,IMTTS METIIOD
REPiOR:r
lratrix---,,,--o: GTr
PREPARiLTION- WORK
AIiTALYSIS DATE ORDER #
IfS lot-Sarryll.e *:
Mercury 95
101
rwrts (s) :
D5fO30139-002 Prep Batch f,- - -: 5258350
(es 114)9w846 7474A
(as 114) 6.0 (O-10) SW845 747OA
DiLution Pactor; 1
Analygie TLme,.: L8:56
ae / Le / os Hil0(21cc
ae /Le / os HilorzlcD
Cal$htions arc perfirrrmcd beforo rounding to avoid roud-off error$ in calculatod reslts.
STL Denver
Cl.ient Ipt f--,:
flate 8a4l1gd- - - 3
gAIvIPIJE
PARAMETER A},IOUNT
Dsr03 01_3 9
ae/02/a5 09:35 rlate
SPIKE MEASRD
AMT AMOT]NT T]NITS
I.ATRIE SPIffi S,BUPLE DATB. REPORT
TUEtrL Hetals
Recelrred- - 3 09/ 03/05
ItlatrLx-- - - - - - - o: G"!il
PREPARJA.TTON- WORK
AIVAIJYSTS DATE ORDER #
PERCTVT
RECX/RY RPD I,IETHOD
HA lot-Saryr1e #: D5IO3O139-002 Prep Batch
Mereurlr
O.00500 O.00475 mg/f,
O.00500 0. 00505 mg/L
DlluElon Factor:
Analyalo Time- -:
s2s83 s 0
sw846 7474A
6.0 sw846 7470A
09 / L9 / Os HiDor2lCC
oe / Le / os HiDorzlcD
*. - - 3
9s
101
ND
ND
1
18:56
r(ufB (s) :
Calculatlons arc perforrrcd bcfore rounding to avoid round-offerTore in calanlatod rcsutts.
STL Denver 58
fATRXf SPIKB SAilPfrE EIALITATIOII RBPTORT
IUXAI, lletals
elient l.ot *---: D5Io30139
Date Sary[eal--.. O9/L9/oS 14:30 Date ReceLrred.-z o9/L7/O5
PERCEhIT RECO\IERY
PARAMETER RECOVERY TIMITS
RPD
RPD I,IMITS METHOD
HaLri-x : WATER
PREPARATION- WORI(
A}IALYSIS DATE ORDER #
US Lot-8aryile *:
Ivlercurry 84
7B
rrc|IE (8) :
Dsf L7 0196- Oo1 Prep Batch
N (es 114)
*. - -: 5262486
sw8{5 7470A
gw84 5 747 AA
oe / 22/ a5 HKT1E1C4
oe /22/ as HKrlELcs(85 114]. 7.2 (O-10)
DiluE,ion Factor: L
Raalysis Time- -: 19:33
Calculatlons ore performod bofore rourding to avoid rourtd-offorrors in calculucd results.
N Spiked analyte rccovery lr outside stated control limits.
O
STL Denver
C1ieut f.ot *. . . 3
Ilate Sary)I-ed---I
SAIIPITE
IATRLE SPIre SAUHLB DJI:rA RBFOI T
IIUELL lieta].s
Date Receirred- - 3 09 / L7 / 05
llatri:r, - - - - - - - . 3 WATERD5IO3 013 9
ae/Ls/as 14:30
SPIKE MEASRD PERCNT
REC\IRY RPD MEfiIOD
PREPARATTON- WORK
AIVAIJYSIS DATE ORDER *PARAT{ETER AMOUMT AI,TT A},IOT'NT I]NITS
IrGl l^ot-Saryl1e *:
Mercury
TID
IID
n(}rE (s) ;
D5IL7A196-001 kep Batch #. - .3 5262486
o. oo5oo 0.00418 Ing/L 84 sw846 747OA
Quall,f Lers: N
0.00500 0,00389 mg/L 78 7.2 sW846 747OA
Qualifiers: N
Dilution FacEor: 1
Analygig Tirne. . : 19: 33
ae / 22 / os Hr(T1E1e4
ae /22/ os HKTIE1C5
Cdculations aro perfonned bcfore roundiag to evoid round<rff crrors in calanlated resrlr-
N Spikcd anatyte roooyory is ouBidc stared control llmiu.
50STL Denver
STL DENVER
Contrect r
Lab Code:
SOW No. !
Total Metals Analvsis
COVER PAGE . INORGANIC ATIALYS$ DATA PACKAGE
URS Corporation
STITDEN Cage No,:
gDO No. t
gl,g No. :
Dsxo3 0139
SanD].c ID.
GW- 5n -090205
GTil- 6B-090205
cw-R1-o90205
q'[-S7-0902o5
cw-s8-090205
GW-S9-090205
Wcrc ICP l-nterc].rrurntr correctloal appl.l-cd?
Were rCP baokgrotrnd, corrcetioar r1lDllcd?
If ycr-wero ratr d,rta gGncratrd. bcforc
al>plication of background corrGetlons?
Conulrcnts:
Lab Sary>lc !ilo.
D5r030139-006
Dsr030139-007
Dsr030139 -002
Dsr030139 -OO5
Dsr030139-00{
Dsro30139 - 003
rg
NO
I eertlfy that tbir drEa DaclGrgc Ls ln coutrrliracr wLth thc tcrmr atld conditioni of thr
cosrtract, botb tnch[ically aad for cq)I.tanGgBr for oth.r tshEn th.c conoLtLona dcballcdabove. R.lcaEG of ttrc data co[ta1ucd la Bhl.a hardco5ry drer prchrgc and ln EhG cors)utar-raadablo drt,ta
Euboittcd oa f1o34ryr digkett.l har bacn auttrorl.zcd blr thc Laborato4, tdenegor or thc ![nnrgiGr'a doa:Llracc, ea
werlfLcd ttr tbc lollorrring rl.graature .
Ycr/No
Ye glNo
Yc;/No
Y:ES
aigraaEure :
Datse:,i/drr, /o s
Nanr I
TLt1e : Data Anrlygt
Kattulr
STL Denver
CO\TER PI'SIE IN
51
STL DENVER
ContrraeE: IIRS Corporat,Lon
Totel Metals Analvsis
-2A-
INITIAL AND CON"TINUTNG CALIBRATION VERITTCATION
Cage lilo. t gAS tilo - :
Higrh Ptrrity, Sprrx
InorgtnLc Venture'
r,rb Codc r STIJIEIiI
fnitia^L Ca].l"bratrLon Eourcc r
ContrLnul,ng Calibratrl.on Sourcc r
gDc No.: D5I030139
ConcenEnELon uni.tr r W llll
tnrLyte
rnLtial Calibnt'iou
Tnrc Found ,6R( 1)
Coatinuingr Calibration
Tnrc Found tR ( 1 ) Found, e6R ( 1)M
Ll.un,inrrrn :l o. 500 I 100.0 I P
I carcium r, I I I I s.ol I I s-oglror.elpl
l rruminum :l lo.oJ 3e.3e l se.s I so.o I sr.rol roz.e I I ll-J
Calciurn H I
J.ron Lo I
39.93 I gg.8 52,611 105.2
I I I o.sol I o.soslror.6lpl
I rron lri I 40 . ol d0 .20 l1o0 .5 I s0 .0 I sz . tsl 10{ .3 I lrl
I rotrsriuml I I I so.oI I 50.sgl1oo.Blpl
Megncrium I
Sodiura fro I
IFoq41un_4il co.of {o. 02 [100. o I so.o I 52.2{J 104.5 I
2A -061 100 . 3
5.081 101-6
I zirconiryl l o.5o I o-deel 99,8 I P I
(1)ControL Linits:Meretrry 80-120; Othcr Mctalg 90-110r Ctrrnidc 85-115
STL Denver Fom II ( Pert 1) Ittr 52
STL DEIVYER
Total Metals Anahsis
_2A_
INITIAL AND CONTINUING CALIBRATION VERMICATION
eotrtracc! IIRB Corlnration
Irab Code3 STITDEN Crlo ![o, t S.LSI lilo - :
fnl-tl,aI CalibrutLon Sourco :
ContlnuLng Cnll.brrtLon Sourcc :
Htgrh PurLty, Spox
Inorgfanic VcnturcB
sDo No. r D5I030139
I nfuminum .l I
Concrntsntloa tlnLta r mgl[,
ll o,sol I I o.4e3l eB.ElPl
Ana1-yte
raitsial calLbrrt,Lon
Tnr. Found tR(x)
Continuing Calibratslon
Trrrr f,ound, tn ( 1) Fotrnd e6R ( 1)M
l4l.qqinum :l I 50.o I {9.501 99.01 lpl
Lq.r.ium rl I 5-o I I I s-oslroo.GJPl
Lsa,1slum Hl I so,o I {9,r-t] 98,3 I Ipl
I rron Lo I o,50 I I o.tszl ge,{lpl
Llrsn Hl, I I so.o I {g, g7J 97 .7 1 lpl
I potaggLuml I 50.O I I so.3zlroo.dl P I
MngncsLum I
I soaium r,o I I I1 20.0
s.o I
19.g7l gg.8 I P
s.oe lroL.z l p I
I soarum ni I I I 50.O I so.Tsl 1o1.sl I lpl
ZLrconiun I 0.50
Control LimLEe:Mercuryr 80-120; Othcr Mrtelt 90-110r Cfrrnidc 85-115
o-500 100-o
(1)
STL Denver Form II (Part, 1) IN
STL DENVER
Contract: IIRS CorporatLon
Total Metals Analvsis
-7,A-
INI'ITIAL AI{D CONTINUING CALIBRATION VERIFICATION
Cere No. t gAS !ilo. :
Higrh Purity, Spax
Inorganio Vcuturoa
Lab Code : STLDEII
IaLtl-aL CalLbratiolr Eorrroc r
Contl,nuing Calibratl.on Sourcc :
sDGl NO. r D5f030139
CorrccntratLon Unltsa r mgllt
.[nalft,c
rnltial Calibrrtion
Trrre Found tn ( 1)
Conul,nuingr Call-bratl.on
Trnn Found tR ( 1) Found %R ( 1)M
Alumtnum :l 50.0 i7 ,431 9{,9 {8. O{l 96.1 I P
Ca].cirrm Ir I
Ilronni | |
50,o
I I so.ol
{5. 221 g0 .4 {5.951 91.9 I P
{5.351 90. z I {6.131 e2.3 I p I
I sodiru!_Ei I I so.o I {8.131 96.3 I 48.7ol s7.4lp I
(1) Coatrol Lr.nLt,lr llcrcury 80-120r Ottcr tict.als 9O-110; Cyrnide 85-115
STL Denver Form II (Prrt 1) IN 54
STL DENVER
Total Metals Analvsis
-2A-
INITIAL AND CONTINUING CALIBRATION VERIFICATION
CoEtract: IIBII Coqroratlos
tab Codrls STLDTN Caee lilo. i AAS llo. r
InLtLa]. Call-bratiore Eourctr:
Cont,lnuingr CalLbraE,Lon Sourcc :
Higrh PurLty, Spax
Inorgranlo Vcnturcg
sDs NO. r D5f030139
Conccntrats:lou urrLtr t mg lt
rnallte
rnl,uial Call,bntion
Enrc Found e6R ( 1)
Continuiag calibration
l[rer(' Found e5R ( 1) Found tR ( 1)I{
Aluminun :l 0.50 0.{7gl 95.8
lrruninrrlr:l I l_ | so.ol I I lz.srl gs.e lpl
Cs].ciun Ll 5.0 4.791 95.8 P
Cal-cium H 50.0 {5-83 9L.7
rron Lo I 0 .50 0 ,49 97 -6
Iron Hi I 50 .0 45*ggl 92.01 p
leoraesiunl - I I I so.ol so.zel rg-o..gl I lelltltg,"eriurnl L ,- I I zo.gl rg.zol ge.sl I ,.1-?,1lsodi.r-r,ol, I I I s.ol s.odroo.el I lp,l
Sodiurn IIf I 50.o 49 .65 I 99.3 I p
Zirconl-rrn I 0 .50 0 .50 100. 6
(1) control timJ.ts:Mercrrrlr 80-120; Othrr Mctal;9O-11Or c)ranLdc 85-115
STL Denver Form II (Part 1) fN
STL DENVER
Contract: IIRS Cor-porat,lon
Total Metals Analvsis
-2A-
INITIAL AIYD CONTINUING CAI,IBRATION VERIFICATION
Cagc l\lo. r S^ilS No. :
Htgrh Purity, Spax
Inorganio VcnturcB
Lrb Codcr StrLDtDI
Initirl Cal-lbration Sourea r
ContLnuJ.ng Ca1ibru,tsLon Sourcc :
sDo No. r D5I030139
Concontrat,ion Unl,tt r rrgll,
Analtte
rnl,tial Calt bntLon
Tnrc Fouad eGR (1)
Contl,nuing Calibration
Trrrc Found %R ( 1) Found e6R ( 1)T{
I rlunrLnun :J I o.so I o.tBol 96.o I
nJ.ulrinum :l
CaLciurn L l
CalcLum II I
I rron lio I I o.5o I
lL7.28l 9{.6
o,tsgl ez-61 I lPl
lrronttt I _ I I so.o I I lr.13l g{.3 J r I
Potnssl,un I
Lttryoaslun I I
50 . g1l x.ox,. 6
2O.O I 19.461 g?.31
Sodiurn El I
zLrconiurn I
( 1) Control r,irntEe:Mcrcury 80-1201 OBher Metals 90-110; Cfrraide 85-115
STL Denver Form rI (Part 1) fN 56
STL DENIIER
Total Metals Analvsis
-2A.-
INITHL AND CONTINTIING CAI,IBRATION VERIflCATION
Coatrrct r t RS. eorDorat,ion -
Lrb Codcr STLDEN Cage No.:gf,g No. t
fnitirL Call"bration Soursc r
ConELnuingr CllLbratl.on gourcr r
nl.gh hrity, 85rox
faorga.u,io Vcnturas
sDo rvo. r D5r030139
Concrntrrtion Unl.ts; t mgll
Ana,lfftc
InitLr1 crl.Lbratlon
T:trrc Found tR ( 1)
Contirrul.ngr CrlLbratLorr
Tnrc Fotrnd tR ( 1) Fouad e6R ( 1)!{
lrrumuun.j.l | _ | I o.sol o,.,rgql ..pg.zl I lel
Calciurn L' I 5.0 4. 951 99 .2 P
fron Iro I 0.50 0.{991 99.8
Pote.raiugt I 50,0 5O;981 102 .0
I u.goesiuml I I ao.ol r.9,631 9B,zl
I zircoaLurn I I I o-so I o,{g{l gg. g I frl
(1) ConEroL t Lnit; r MrreutY 80-1201 Othu Mctela 90-11.01 CrranLdc 85-115
STL Denver Form II (Part t) rN
STL DENVER
Contract: IIRS Corporation
Total Metals Analvsis
-2L-
INITIAI, AND CONTINUING CALIBRATION VERIFICATION
Caac No.3 Sl.g DIcr - r
Ht-gh Pur!.Ey, Spcx
Inorgranio VcnturGB
Lab Codc r STITDEN
lnit,ial Calt"bratLon Sourcc r
Contlnulngr Calibratslon Bource:
sDCs llo. : DSf 030139
Concentratioa Unl,tr r mgll,
Ana].ftc
fni.tial CrlLbratlon
rIrua Fsrrnd e6R ( 1)
Continuing Calibrat,ion
Tnrc Found tR( 1) Found %R ( 1)M
lnuniuunr:l o.zsl o.2lol ga.ll I I I I lpl
I gatciunr r-, I z.ol e.orlroo.sl I I I I lpl
I rrp;n rro I o. esl o,259 1103.5 I I -l-EJI rotaanl.um I ao.ol 2o.tllror.el I I I I lpl
Magrnerium I 10.0 9,57 I 95 .7
Sodiunr lro I 2.0 2 .05 1102 . 5
I zt rcouium l o . zgl a .z{3 I g"t .z I I
( 1) Control LirnlEe:Mercurar 80-LZA; OEhcr llctalg 90-110; Cfrrnidc 85-115
STL Denver Forrr If (Part 1) rN 58
STL DEIVVER
Total Metals Analysis
-24-
INITIAL AND CON'I'IN T] ING CALIBRATION VERIFICATION
cont.ract: UBS CorporrtLon
Lab Codes STLDEN Castl No. r gl'8 No. r
rnJ.tLa1 Ca]'ibrBt,Lon Source r
ContLnuLng Cal.ibratioa Sourcc :
Higrh Purlty, SDex
Inorgrrnic VenturGt
gDc No. : D5f030139
Conccnt,rrt,l-on IrnLtr r sg lT.
anaLyte
rnLtial Calibntl,on
Tnrc Found r6R(1)
Continulngr CalibratLon
Truc fotrnd ,6R ( 1) Forrnd e6R ( 1)lrl
lmr:rnLnurn:1, [ -_ I I o.sol ,., ,f, ,l o.szrlrot.zlpl
A1umt nu,m :l 39-38 I 99.4 48.961 97 .9 P
I catclum r" I I I I 's.ol I I s.ool roo.o J P I
Calcirlrr H I 39.52 I gg.0 49 - 5gl 99 .2
lrroar.o I | 1... I o.sol I I o-srzlror,nlpl
lrroanr I ao-ol sg..grl gg-el so.of ,-,1-g,-1il gg.zl | --l_plleoqreErulrl I I I qo.o.[ I I so-orlroo.olel
Magmeetum I 19.82 1 99 -1 I P
SodLurn Lo I 5. O5l 101.2 I P
Sodiurn Hi I
I ztrcouiuml I o.5o I I 0.{931 eB.Gl P I
(1) Control LLmlegr Mcroury 80-L2Ot Othcr Matalg 90-110; Cfranide 85-115
STL Denver Forn rI (Part 1) fDI
STL DENVER
Contract 3 IIRS Corporatl,on
Total Metals Analvsls
_2A_
INITTAL A}ID COI$TINUING CALIBRATTON VERIFICATION
Cage No. r
nlgh furity, Spcx
InorganLo VenturGs
Lab Code: STI{DEN
fnitiaL Crllbration Sourcrr
Cont,Lnu:l,ngf Calibrat,ion Sourec :
sDs No. r D5I030139
Coneentration Unit,s z nrglt'
Ana]-trt,e
fnitia1 Crllbretlon
Tnrc Found, ,6R ( 1)
Contiauing Calibration
Tnre Fogod e6R ( t ) Found 9tR ( 1)M
I rrqainqm :l I I o.so| I o.4asl gz,olrl
I nro*inunr :l I I so-ol {8.gil 9z. B I lpl
I eatciurr r, I 5.0 I 4.99J 99.8 I p I
J c.rcium HI 50. o I 19. 621 99.2 I lpl
fron lro I
Iron III I
0 .50
50.0
0.{9{98,8
4g .1 98.2
Potaerium I
I
50.0
20.o I
50-10I 100.2 I p
I re.B7l ge.tJrl
lsoarum rcl rl s.ol I I s-ozl ro1.{lpl
Sodium Hf I
zirconLum l
50.0
0 ,50
{9.531 99.1
0 .494 99.8
( 1) ControL f,iniet r Morcrrry 8O- LZA t OtSer Metel.s 90-110r C3ranLdc g5-115
STL Denver For:n ff ( Part 1) IN 7A
STL DENVER
Total Metals Analvsis
-2A-
INITIAL AI{D CONTINUTNG CALIBRATION VERIF'ICATION
coDtract: IIRS Coqroratlon
Lab Codos STLDTN Cagc No.:gra No, r
Inl"tLal CalibrrtLon Sourcc:
Coutinrring Ca1{bratiorr Eorrrcc r
Htgh ftrrity, Spcx
InorganLc Vcnturct
8Ds No. r D5I030139
Concontration Uu,itr r rrgft
AnaIlt,c
fnitial' Crllbratton
Trnrc Found tR ( 1)
CoatinuLngr CalLbration
Tnrc Fognd r6R ( 1) Found tR ( 1)!n
lluminrun fl
Lhrfirirrurt :l
J catcirrrn L l
0.50
50. o
5.0 I
48. 85 97 -7
o .117 9 95.8
c.931 98.6 I P I
Ca].cl um II I
Iron r.o I
I rron Hi I
50 .0 {8. g3 9? .7
0. 50
I I I so.o] lg.6sl e7.Bl
0. {88 97 .6
lpl
J rotassiuml rl I so.ol I ] so.o{lroo.tJrl
I urgocriurn I rl I zo.ol I I re.Bol ee.olPI
J soaiun r,o I I I I s,ol I I s.o3lroo,elrl
Sod,lurn ni J
I zirconl,um I I
50.0
o.5o I
{9.{1 98-8
I o-{ezl eB.clPl
( 1) Cont,ro1 r"LruLtg :Mtrcury 80-L2O; Othrr Matala 9O-11O1 C)'anLde 85-115
STL Denver Fom ff (Part 1} IN
STL DEIVVER
Contraet: IIRS Corpontiou
Total Metals Analvsis
-2A-
INIT'IAL AI{D CONTINUING CALIBRATION VERIF'ICATION
Cagc ![o. r SIS No. ;
Higrh PurLty, Spex
Inorganl,c Venturct
Lrb Codct StrLDEN
fnitie]. CalLbratsion Souroas
Contl,nuing CnLLbratlon Sorrrcc r
SDe IrE). I D5f 030139
ConccnE,rrtsIon Urrj.ta s ng lL
lnr]'lrt,e
Initial crlLbratsLon
Tnr Found e6R(1)
Continui,ngr Crl.lbntLon
Tnre Found *,R ( 1) Found %R ( 1)!i
Lluminum :l 0 .50 0.4791 95.5 l P
I nrurninllln :l I | | so.ol ra.zrl ez.rl I lpl
lcercrun.r,l ,l | | s.ol | | l.ggl ga.elel
CalcLun HI 50 .0 48.851 97 .7 P
Iron l.,o I 0 .50 o,{89 97 .8
Iron Hi I 50 .0 49. 5 97 .3
lrotarsiuml I so.o I I I so. osl roo.1 I P I
I e.gq el,um I I I I 2o.ol I I re.G3J so-zlrl
I soafum rol I I 5.ol I I s.oslro:-.zlpl
Sodiurn Hf I 50.0 {9.501 99.0
Ziroont-um I 0 .50
ControL lrl,nits r Mercurlr 80-120r Otrhcr Mcta].s 90-110; Cyanide 85-115
0 .493 98.5
(1)
STL Denver Foz:rr Ir ( Fartr 1) IDI 72
STL DENYER
Total Metals Analvsis
-2A.-
INITIAL AND CONTIITIIING CALTBRATION VERTF'ICATION
coatnctt ttRS Corporat:l-oa
Lab Codet STLDEN Carc No. t SLg No. :
tnitia]. CalLbratrLon Sourcc r
Cont,inulngr Calibratlon Bouroe I
HLgrh PurJ.t,y, S1>ex
Inorgenic VcnturcB
sDs No. r D5I030139
Concentratsion Uni.tsr r mglr.
r.nr,Lyte
rnitLal Calibntl,on
Trnrc found t6R ( 1)
Cont,Laulng Crlibrrtion
Tmr found e6R ( 1) tround e6R ( 1)M
Ieru+iaun :l ,.. | | I o.so I _. -.. 1... I o.rsol gs.o le I
I a.furruinum :l I I I so.ol c8.6ol sl.zl I lpl
Calciurn t I
I catciurn rr J I
5.0 { .95 99.O
I I so.ol ae.13l ea.3l I
Iron Lo I o,50 0.{g7l 97.{ t p
lrroarl -l l, I I so.01.,,...-.1-grPsl_Jl.sl I lel
Irotreeirrml I I I so.ol I I rg.ttl gg.slpl
I u.groesiu'nl I I I 2o.ol I I rs.64l gs.zlrl
lsoqrunrcl I I I s.ol I I s.ozlroo.rlel
I sodtiurn Hf I I I I so.ol {9.s31 99-1 J I lPl
z{roonl,un I 0.50
( 1) Cont,rol LimiEE I Mereurl' 80-L2O; Othrr Mat,aLa 90-1101 CtranLdo 85-115
0 ,493 98,5
STL Denver Fom If (Part 1) rN
STL DENYER
Contracts: IIRS Cory>oratloa
Total Metals Analysis
-2A-
INITIAL AI\[D CONTINUING CALIBTTATION VERIFICATION
Cagc No. t grA No. t
HLgh Purl-ty, Epex
InorgrnJ.c Venturoa
L,ab Code : STIJ)EN
fnitl.a]. CallbraEion gorrrec :
Contl,nuingr Clll"bratlon Eourco r
sDo No.: D5I030139
ConoantratLon Unitg z \g lL
LAU*,rnum :l o-zsl o .253 I1o5 .2 I
Arra].ytc
InitLrl Ca]'Lbratlon
trnre Found tR ( 1)
ContLnuingr Ca1lbratsLon
Tnro Forrnd e6R (1) Pound BR ( 1)M
Ca].cLum LI 1.gg I gg.0
Iron lro I 0 .257 I102 . I
I potresirun I zo . ol 20 .18 lt.oo .9 I rrl lpl
LMcgresiun I ro. ol 9.s2 I gs.z I I I I I lpl
I soai.-, Lo I 2.01 z.o3 1101.5 I lpl
zirconiurn I 4.2{0 I 95.0
( 1) Control Ll.nLtg :Morcury 80-1?0; Other Mcta1r 90-1101 Clranl,dc 85-115
STL Denver Form fI (Part 1) IN 74
STL DENVER
Contsractr 3
Lab Codc:
Total Mctals Analvsis,L-
INITIAL A}ID CON'I'INUING CALIBRATION VERIFICATION
I[tS Cor1roratl.oIe
STLDEII Caac No,:8r,g No, t
Inorganl-c Vanturea
sDo Ho. r D5I030139
rnl-tl-al- Calibrrt,ion Sourcc:
Continuing Cr1l-bratsLoa Slourcc r High Purl.ty, SDcx
Concentrrtion Un:|.trr t $gf t
tnalyta
Inl-tLal. CalibratioIr
Tnre Found tR (1)
Contlnulngr CalLbratLon
Trrr€t Found e6R ( 1) Found tR ( 1)M
Arsonie I o.2 o.217 I gg.g 1.00 0 .9971 gg .7 1.005 100, 5
I saritn I o.zsl o.zss lror.a I o-so I o.soel ror.z ! o.sogl ror.a I e I
[ ,cEqomiun I o.2sJ o.2s2 l1oo.8 I 0.i0 I o.sosl 1o1-ol o,5o9llot.B_lLl
I eoppe= I 0.251 o .2{o I 95.0 I o.50 I o.{9{l 98.g I o.{9zl 99.{ I p I
Vanrdirrrn I o.25 a.252 I100.8 0 .5051 101. 0 0.5101 102.0
Iztrr. I o.2sl o.zrtl gt.e; o.so I o.lgzl gg.l I o.sorl roo.z I p
ll,caa I o.esl o.zlsl ge.ol o.sol o.soolroo.ol o.soslror.olel
INrchr I 0..2fl o.zsg lrorra,l o.so I o.sogl ror.s I o.srslror.o I e I
I strver I o.asl o,.zr1l gz-a I o.so I o.,l?.2[ _gs.rl-- o.lgsl gg.ql-?-l
( 1) Control r.imLt; s McrcurT 80-120;Other McEals 90-110t Ctranide 85-115
STL Denver Form II (Part 1) IN
STL DETVVER
Contraot:
Total Metals Analysis
_2A_
IMTIAL AND CONTINUING CALIBRATION VERIBICATION
IIRS CorDoratioa
gTLDEN Cut No. t Stl,S No. 3
Inorganic Vanturat
Lab
rnLtl"al Callbrat,ion Source :
ContirruLng Cal.l.brabion gouroe r
SDc No.: D5f030139
HLgrh Purl.ty, SDex
Conccutratlon Unitg = nrg/L
.Lnalrcc
rnIUj.aI Calibration
Trfllo r.ou.nd, tR ( 1)
Con t,l-anrlng CrI lbrrt:Lon
Trrrc rround t,R ( 1) Found 96R ( 1)![
Jur,"nic t I I 1.001 r-o03l1oo.3l 1.o0alloo.alBl
Barl.un I 0 .50 0.5061 101.2 0.5001 100.0 I p
Chrorniun I
[,c"pp.= I I
0 .50 0.5071 101.{0.5111 LAz.2 I p
I I o,sol o.tgsl e9.01 o.aBBI gz.Glpl
IrCad.
I xt.t.r I I
0.50
I I o.sol
0 .5021 100 . {0-5051 101.0 I p
o.s1zl Loz.{ | o.sr.rl1oz.8 I p I
I sirr.= I l o.5o I 0.c9il 98.21 o.cBTl gT.tlpl
I v.ordtuq, I I tl o.so I o.5o9l 101.8I o.steI Laz.t l r I
Zinc
(1) Contrrol LinLta:MerctrT 80-LZA, Othrr Motels 9O-110t Clrraidr 85-115
o .50 0 .4961 99 .2 0.d961 99..2 lP
STL Denver For:nr II (Pare 1) IN 75
STL DENWR
ContracE:
Total Metals AnalYsis
-2A-
INIIIAL AND CONTINTIING CALIBRATION VERIHCATION
IIRS Corporat:Lon
Lab Coda 3 STITDEN Caac No. t gAS No. t sDs No. s D5f030139
fnicLe.L Callbration Sourcr r
ContLaulng Calibnt,l,on Sotrrcc r
Iaorganio Vcnturct
Iligh Puri ty, Sgcrr
ConcontratLon Unltg 3 mrglI!
Arralfrt,er
rnl-tLa1 Calibrat,ion
Tnrc torrnd tR ( 1)
ContLnulng Calt bratLon
Tr:ge Forrnd t6R ( 1 ) Found tR ( 1)!{
AreenLc I 1. 00 1.0211 102,1 1.0201 102.0 I p
lsarr'rn I I I I o.sol o.sosl ror.ol o.sorlroo.zlBl
lsruonruro I | | I 0..?.9 I o.srrl roz.zl o.szrlrol.e.Lel
lcoee.' I I I I g-sol o.lgel gg.el o.aggl sg.elpf
I r,aaa I I I I o.sol o.sozl1o1..l o.srzlroz.llpl
Nl-ctrel- I 0 .50 0.5151 103.2 o.5251 105.O I P
SL1vrrr I 0 .50 0.{921 gg. {0.5001 100.0 I B
lvlpaatun I | | | o.sol o.srslror.ol o.szrlrol.slpl
J zino I I I I o.sol o.sorl100.6l o.sroltoz.olpl
( 1) Control IrLnitr I Mcroury 80-1?0;Other Metalg 90-110,' CrranLde 85-115
STL Denver Form II (Prrt 1) IN 71
STL DENVER
Contraet r IIRS Corporatl,on
Total Metals AnalYsis
_2A-
INITIAL AND CONTNUING CALIBRATION \{ERIFICATION
Caac ![o. r S.ng No. :
fnorgl-lc Vonturog
HLgrh zurLty, $pex
frab Codct STLDEI{
lnitia]' Crlt bratLon Sourcc r
Contlnuingr CrlLbratrLon Eource :
sDs No. r D5I030139
Concrnt,ntLon UrrLt,a r mg/L
arralyte
rnLtial CalibntLon
T.'ur Found ,6R( 1)
ConELnuLng CrJ' lbntioa
lrrnrc porrnd r6R ( 1) Found tR ( 1)M
Aracnl,c I 1.00 1.0361 103,5
BarLum I o.50 o .lg7l 99 . {
lo"'on+rsl I- J I o.sol o.srdroe.el .l lplIcoep"' I l- I I g.:ol o.rggl gg.sl L| ellr,eea I l,- I I g=sol o.saol ros.zl I ...1 .ellurcter- I _ I I ..,[- o-sol o.sgcl roz.zl I lel
freed -,!Nlckel I
9,-?"9
o-50
o.5261 1O5.2
o. 5351 LO7 .2
fsit"cr I I I I o-sol o.soellal-zl I lpl
lvanaaiun,l. I i { -._o.sol o.sgal roe.ll I lplzrnc I I I I o.sol o.szrl Lor.zl t lp
ControL lrLml.tg t Mcrsurfr 80-120I Other Mctal;90-110r CrranLdc 85-115(11
STL Denver x'orn II (Part, 1) fN 78
STL DE|VVER
Total Metals Analvsis
-2A-
INITIAL AIID CONTINUING CALIBRATION YERIFICATION
Coatilct! URS Corporatlon
Ltrb Code: STLDEN Cage [Io, :gl.g No. t
Initirl Call.bration Sourcc r
Contl-nul.ng CalibratLon Sourca:
Nrgr
Ultrr Sclentifio
gDc NO.: D5I030139
Concrntntl-ou. tlaLta r rr{Jll,
fnrlytc
rnl.tLal Ca].ibntion
Tnrc Found esR( 1)
Conuinulng Call.braBlon
Erme Found' tR ( 1) Found e5R ( 1)M
Marcury 0 . 0 a2L77 0 . 0 02L47 98.5 o.005000 o,00511 102,3 0-0a[g72 97 .4
(1) Control Llnits r Mcrcury 80-1201 Otrhcr Matalg 90-110; elranLde 85-115
STL Denver Forur fI (Part 1) ilr
STL DENYER
Contrlot r IIRS CorporrtLon
Total Metals Analvsis
-2A,-
INITIAI, AhID CON TINUING CALIBRATION VERIF'ICATION
Cagc trlo. 3 S.[,g No- :
}IIST
Ultra SoLcntlflo
Llrb Codc: STITDEIU
fnLtial. CalibraE,l-on Source :
ContLanr:lng Cal'ibration gorrrsc r
sDo DIO. r D5r030139
Conoentration Units r tug lL
Analyte
rnLuLal Calibration
Tnrc Found t6R ( 1)
Coutinuing Crlibration
Tnrc Foured, 9sR ( 1) trorrnd tR ( 1)u
Mercury 0 .005000 0 .00489
( X ) Cont,rol LLnLt,g r Mcrcurar 80-120; Othor Mctalo 90-1101 CYanLda 85-115
0.00(t928
STL Denver Forru If (Part 1) il 80
STL DENVER
Total Metals Analvsis
-2A._
INITIAL AND CONTINUING CALIBRATION VERINCATION
Coutract: UltS Cottrortrtloa
LBb Codcr STITDEN Caec trlo. t SAg No.:
rnLtial Calibnt,Lon Bourcc :
ConeirruLng Call-bration Eourcc r
NTST
U1tra ScLaatslfLc
SDGMO. r D5fO3O139
Conccntrrtion tlnlta r ng/Ir
nnal-ytse
rnLUia1 Calibration
Trnrl Found tn'( 1)
CorrtLnul,ng Callbrrtl-oa
Tnn llsuad, tR ( 1) Found e5R ( 1)!{
0.005000 0 .00{93
( 1) Control. IrLmlt,s r D[crsurfr 80-LZA t Othcr Mctsals 90-110; Crranide 85-115
STL Denver Forn II (Part 1} I}I
B1
STL DENVER
Contraet: URS CorporatLon
Total Metals Analvsis
_2L_
INITIAL AI.[D CONTINUING CALIBRATION VERIFICA'I'ION
Caac No,:SI^[.SI No, :
NIgE
Ultra Scicntific
r,ab Codcr STITDEN
Iaitirrl CaU.braELon Sourcc r
Continuing CalLbratsl,on Sourcc r
sDs No. r D5I030139
Concentrat,ioa Units : ng lt,
Anallrte
Init,ial crLl.bratLon
Trnrc round, tR ( 1)
Contj-nulng CalLbraElon
Tnrc Fouad tR ( 1) Found tR ( 1)!{
Mercury 0.0a2L7 0 . 0 a2L77 100.0 0.005000
(1) Control rinit,c r Mercury 80-120; Othcr McEals
0.005102 102 .0 0 - 005177 103.5 cv
90-1101 C)ranLdc 85-1X5
STL Denver Formr fI (Part 1) rN
STL DENVER
Total Metals Analvsis
-2A-
INITIAL AND COIIITINUING CALIBRATION VERIFICATION
contraotI IIRS CorDoretion
Lab Codc r STITDBII Crrr No- t
NIST
S.f,.fl No. t
InitiaL CelLbratl.on Source :
Cont,l"nulngr CalibratLon Glorrcc r Ultra Sol-entifio
sDo fvo. r D5I030139
Conoentratl.on UnLtg : mj lb
I ruercury_ | I I I o.oosooo ! o.oosuzd ros.s I o.oosuelroz.o lcvl
Analrrte
fnitial Caltbratl-on
Trnrc Found, ?6lt ( 1)
CoutLnu:lng Crl Lbrrtion
Tme Porrnd e6n ( 1) Found t6R ( 1)M
( 1) Control r,Lnl,ta:Mercurar 80-7.20 t Otrhor Mctalt 90-110y Cfrrrrido 85-115
STL Denver f,'or:n ff (Prrt 1} IN
83
STL DENVER
Contrracts: IIRS Corporat,ion
Total Metals Analvsis
-2A-
IN ITIAL AIT{D CONTINI ]ING CALIBRATION VERIEICATION
Cese No. t SnA ilIo. :
NIgtr
Ultra SsicntifLc
Lab Code: STLDEN
rnl,bial- CalLbratLon Sourcc r
Contlnul-ngr CaLibnt.Lon Bource :
sDo NO. r D5I030139
Concantratlon Unl,ts s rng/f,
.[neLfrt31
InLtia]. Call,bration
Tr:rrs llorrnd tR ( 1)
Cont,inrrLa.g CrlLbntl.oo
Tnre Found tR ( 1) Found' e6n(l)!,I
0 ,005000 0 . oo5{,2
( 1) Cont,rol lrLml.tg r Mcreunr 8o-120; othcr Mctale 9O-110t C:rantdc 85-115
STL Denver Forn rI (Pnrt 1) fN 84
STL DENYER
Total Metals Analvsis
-24-
INITIAL Ai\D CONTINTITNG CALIBRATION VERIFICATION
eotrtraet3 t RS eoryoratiou
f-,ab Codc 3 9TITDEN Crac No.:8f,EI No.:
Init,Ln]" Ca]"ibratsLon Bourcc:
Contl.nuingr Ce]-LbratLon Bsurcc r
Htgh PurJ.ty
fnorganl,c VenturoE
gDc No.: D5I030139
Corrcentration tlal"ta t \g llt
lsqqa!ry-- I o-ocol o. o{01 l10o.2 I o. o5o I o. osoil 1oo. z I o.05o1lroo.2 f r't I
nnalyte
rnl-t,Lal CalibrrtLon
lrrnrc [ouad tR ( 1]
Continuing Crlibretion
Truo Found t6R ( 1) Found ft,R (1)M
Leclgrrl,rrm I o. otrol o.04ool10o.o I o. o5o I o. o5o7l 1o1 . { |0.os1{[toz,g I u I
( 1) ConEroI rirnita :Mercury' 80-120; Other Mctalg 90-110; ClzanJ.de 85-115
STL Denver Fornn II (Prrt 1) - IN
STL DENVER
contract: IJRS CorporatLon
Total Metals ^A,nalvsis-2A-
INITIAL AND CONTINUTNG CALIBRATION VERIF'ICATION
Cagc No. :gng lle. t
HLgrh PurLty
Inorganic Vcaturaa
Ltb Codc r STL,DEN
rnl-tia1 CrlLbraElon Sourer r
Coatinulng CaJ.ibnt:lon Sorrrce :
gDO tr[o. ; D5I030139
ConctutntLon trnl,ts s rugltJ
Arraltrtr
rnl-tLal Calibration
TruG Found tR(I.)
Contlnulng Call.bratj.on
Tnrc Found e6R ( 1) Found tR ( 1)D[
Cadnium 0.050 0.051 103 ,0 0 .0{99 99.8
Srrl-enium I 0.050 0.0{9 98. {
( 1) Control Ll.nttg :Mcreury 80-120,' Other DIctaIg 90-110r Cyanl,de 85-115
0. 0488 97 .6
STL Denver Poru II (ParE 1) IN 85
STL DEIYVER
Total Metals Analvsis
-2A-
IMTIAL AND CONTINUING CALIBRATION \TERINCATION
Contr.,cU: IIRII Corporatlon
Lab Codc r STITDEN Cagc No, 3 g.Lg No. l
Initl,a]. Calibration Source :
Continuiug Callbratiorr Bouroe r
Higrh PurLty
Inorgrnl-c Venturor
sDO NO.: D5I03O139
Conscntratlon Utrits : fig lL
.f,na].lte
rnitia} Crltbratlon
Enrc Fouad e6R ( 1)
Contiauing Celibrrtion
Tnra Found tR ( t ) Feund e5R ( 1)u
lcaanrun I I I I o.osol o.gsrol+oz.ql o.osozlroo.llul
ls'rcaruml I ._ | I o.osol .g.olgll gs.sl_o.qsr-llroz.zlill
(x) coDtrol tLultse: ucroutaz 80-120r othcr !(ctalB 9O-110; cyanLdc 85-115
STL Denver Form ff (Part, 1) Ill
STL DET{VER
Coatraot I IIRS Corporation
Total Metals Analvsis
-2A-
INITIAL AND CONTINI]ING CALIBRATION VERIFICATION
Clac No. t SfS No. r
Htgh Pur{ty
rnorgrenj.c Venturog
trb Codcr STLDEN
InLtl-al Call.bration Sourec r
Continuiag CnLt bratLon Sourcc :
SDc No.: D5I030139
ConcentntsLon llaLta r ng lL
.LnaIft,c
Inirial cr].ibntion
Trua Found e6R ( 1)
Contl"nulnlr Calt bratLon
Tnrc Found tR(l) Forrnd e6R ( 1)M
Cedrrirun
Sclcniuur I
0.o50 0.050 101, 6 0.0505 r,01.2
0.o49 99 .8 o.0506 101.20. o50
( 1) Control lrl,nl.Es:Dilorsurtr 80-120; Otshtr Mctala 90-110, Cfranl.dc 85-115
STL Denver Fonr II (Part 1) IN 88
STL DEIVVER
Total Metals Analvsis
-2A-
INMIAL AND CONTINUING CALIBRATION VERTTICATION
Contracb: IrRg Corlroratlon
IraI, Codc: STLDEDI Cage trIo. :gl,g [Io. :
rnLUl.al Calibratiorr Elorrrce r
Cont,Lnuing Calibration Souroa r
Ht-grh PurLty
Inorgrnio Vanturar
BDo !so- r D5I030139
ConecnEratsLon Unita r ng ll'
AnaLyEc
laitial Ca].ibrrELon
Tnre Found tR (1)
Continuingr Calibration
lfrnrc lround, tR ( 1) Found. tR ( 1 )M
Cadml-urr
I satenLum
o.049gl 99.5
] I I o. oso I o.oso{ 1oo,z I I
(1) Control rinitg:Marcurar 80-120r Other Mct,els 90-1101 C:ranide 85-115
STL Denver Form If (ParE 1) IN 89
STL DENVER
Total Metals Analvsis
-zB-
CRD[, STANI}ATID FOR AA AI{D ICP
Contrrct r IIRS Corlrorrt,ion
Lab Codc r STITDEN
An CRDI, gtr.nd.ard Sourco t
IeP CRDI, Standard Eoursc r
Caea llo - :glg Slo. r SDO No. r D5f030139
InorgaaLc Vcnturog
I arumrmun I I
conocntratsLon Unitg : frg lt'
o.10 I o.o9el 98.ol
CRDL St,andard for .trf,
TruG Fouad tR
CRDIr Etandard for fCP
rnitLal FLnar
Tnrc E'ound 9sR Found ,6R
Iil
CalcLrrm tr l
Il=o,r!g I I I
a .2051 102 . 5
ll o.o3ol o,o3srlrre.ol I I
PotagsJ.unl 1.08I 108-0
MegrnarLurn I o .2a7 I 103 .5
SodLum LoI
lriroonfu:ml I I lJ o.oosl
1.O{l 10d.o
o. oo59 I rr8. o I
STL Denver rorm fI (Part, 2) fN 90
STL DENVER
Total Metals Analysls
-zB-
CRDL STANDARD FOR AA AI{D ICP
Contract: URS CorporatLon
r,ab Code : STLDITN
AA CRDIJ Atandard Ecnrree r
ICP CRDL Stsrndard Sourecr
Cagc No- 3 SAg No.3 gDo No. r D5IO3O139
Inorgani.e Venturet
Concanrtratioa UnLtn t mglL
CRDIr Et,rndrrd, for fCP
InLeLr]. Flna1
Trrr FOrrnd ,6R f,orrnd,
CRDL Btend.ard for .[l.
A1umLnun, I 0 .10 0.0961 96.0
lcaro+usrr,J ," l .., I ll -o-aol o.rgol gs.ol - ,1. Ilzronr,o I I ,. I ll o..osol o.orrel rog.zl I I
Pot'asaiumJ 1.0 1.05 I 105. O
Magneatuml 0.20 0.1761 88.0
SodJ-un ro
J 1.0 L.O2l 102 ,O
lzircontunl I I ll o.oosl o.oolal so.ol I
STL Denver For:n rI (Dart ?l IN
STL DEIVYER
Total Mctals Analvsis
-28-
CRDLSTANDARD F'OR AAAI{D ICP
Cont'rect r
Leb Codcr
t RS Corporatlon
gDc IIo. : D5I030139STLDTNCaccS.[A No.:
lt CRDfr Standard
ICP CRDL gtandrrd Sourcc:Hlgrh hrrity, Spex, rnorge,nl.c ventutrea
Concentration [Ial-tt t mg/L
I rariuru I I I ll o.oosol o.oososlror..ol
CRDL Bt,andrrd for ICP
InitLaI Fl"na1
Tnre found *,R Found tR
CRDL Strredl,rd for
^A
Truo Found tR
lrracrri-c I I I ll o.orol o.ororl 1o3.ol I I
Chromiurn I 0 .010 0 . 0101 I 101. 0
lcoppcr I I I ll o.oroJ o.ooasl as.ol I
frcad,0.0030 0.003161 105.3
NickaL l 0,010 o,0102 I 102 ,0
Silvcr I o .010 0.0095 1 95, o
Vnnad,l-uur I 0 .010 0,0101 1 101.0
Zino 0.020 0.0188 I 9{.0
STL Denver Form II (Part 2) IN 92
STL DETVYER
Total Metals Analvsis
-?B-
CRDL STAI.{DARD FOR AA AI'[D ICP
Contnct r IIRS Corporati.on
LaI) Code r STITDEN
f.l. CRDL SEandard Sourccr
ICP CRDL Strnde,rd Source:
Crrc No. t
Ultra Scf,entifio
S.f,S ![o. :sDs No. r D5fO30139
ConcmtrltLon Urel-te t prgflt
CRDIr Standard lor ICP
rnlt,lal ri-na].
Tnre Found, tR Found
CRDL Standard for t^}.
Tnrc Xourd.
STL Denver Eorzr rI (ParC 2l f![93
STL DEIVYER
Total Metals Analvsis
-28-
CRDI, ST'AtrIDARD ['OR AA AND ICP
Lab Codc r STITDEII
AJl, CRDL Standrrd Ssurcc:
fCP CRDIr Standard Sorrrcrr r
Cl;c [Io, r
U]'tra SoicntLft-c
gA,S No. l 8DO lilo.: D5I030139
ConcrntrrtrLon UrrLt,a r rnrgll
0 - 00020 101. o
CRDL Standard for An
Trnre X'orrnd.
CRDL Atandard for rCP
rnl.tLal. Fina].
Trrrs Forrnd tR Found tn
Mercury I O.000AOO
STL Denver Fonr ff (Prrt 2 ) IN 94
STLDENVER
Total Metals Analvsls
-28-
CRDL STAI''{DARD FORAAA}ID ICP
Contract: URB Corporatlon
I.aL Cod,a: SIILDTN
fn CRD[, (ttasdard Sotrrcc:
fCP CRDI, $trandard Sourcc r
Caea No,:S.ng No. :8DO lilo. r D5I030139
InOrg-t io VenturG!
Conccntration Unl,Eg : mg lL
CRDL Bttndrrd. for ICP
fnJ.tlal FLnrl
I,rrr f,ound, tn found tR
CRDL 9ta.nd,rrd, for tlt
Trnr Forrrrd ,sR
Cadlrrium I 0.0010 o.00102 I 102.0
lsereuiulnl ,..I I ll o.oorol o.ooogsl gs.ol I ,l
STL Denver Forn II (Prrt 2) r IN 95
ffisrt
URS Corporatlon
Total Metals Analysls Data Sheet
Lab Name:
l,oUSDC Nurnber:
Matrlx:
7o Molsture:
Besis:
Analysis Method:
Unit:
QC Brtch ID:
Srmple Allquot:
Dilutlon Fnctor:
STL,DENVER
p5r03qt3"2
WATF.R
Wst
60I OB
rng/L
524q6t7
50 m[,
I
Client Sample ID:
Lsb Sample ID:
Lab WorkOrder:
Dntc/Time Collected:
Date/T[me Recclved:
Date/Tlme Leached:
Date/Tlmc Extracted:
Dete/Time Anslyzed:
lnstrunrent ID:
D5lp0.o0oG6l78
HJ?JJ
0 /.151(15,. l5:30
09/ 16105 t6: I9
02r
CAS No.Analyte Conc.MDL RL a
7429-q0-5 Aluminum 0.0t 7 0.017 0.10 U
7439-89-6 Iron 0.02 t 0.021 0. r0 U
7439-95-4 Magnesium 0,051 0.043 0.20 B
7440-A9-7 Potassium 0.24 a.24 3.0 U
7M0-67-7 Zirconiurn 0.00r 6 0.001 6 0.01s U
7440-74-2 Calciurn 0.034 0.034 0.20 U
STL Denver Form 3 Prep Blonk Equivalent 96
ffisrt
URS Corporatlon
Total Metals Analysis Data Sheet
Lab Nrme:
LoUSDG Number:
Mstrlx:
7o Molsture:
Basls:
Andysis Method:
Unit:
QC Batch lD:
Sample Allquot:
Dilutlon Factor:
STL DENVER
Ds1030r 3e
WATER
Wet
60lpB
ms/!,
s2496t7
50 mL
I
Cllent Semple [D:
Leb Sample ID:
Lab Workorder:
Date/'Iime Collected:
Date/Time Rocelvcd:
Dnte/Time Lerched:
Datd'l'inre Extracted:
Drtefl'ime Antlyzed:
Instrument ID:
Dsr060000-6r 78
HIZTT
09/15i05 l5:30
A9/t9/(r5 17:14
(t2t
CAS No.Annlyte Conc.MDL RL a
7440-23-s Sodiurn t.t I _t 5.0 U
STL Denver Form 3 Prep Blank Equlvalent 97
ffisTL
URS Corporution
Total Metals Analysis Data Sheet
Ltb Name:
I.oUSDG Numher:
Mltrlx:
oh Molsture:
Bssisl
Analysis Method:
Unlt:
QC Batch lD:
Sample Allquot:
Dilution Factor:
STL DENVEIT
Ds1030l39
WATEIT
IUgJ
60tJ)E
mg/I,.
s249617
50 mL
1
Cllent Snmple ID:
Lrb Sample I I):
Lab Workorder:
Dateffime Collected:
Date/flme Rccelved:
Date/Ttme Leached:
Date/Tlme Extracted:
Drte/Tlme Antlyzed:
lnstrument lD:
psr060000-:617B
HJ2trt
oefi s/os r 5t0
09/16/05 14: I 3
024
CAS No.Analyte Conc.Mt}L RL a
744438-2 Arsenic 0.0044 0.0044 0.015 U
7439-92-l Lead 0.0026 0.0026 0.0030 LJ
740-39-3 Bariurn 0.00070 0.00070 0.0r 0 U
7444-02-A Nickel 0.00 t 2 0.00r 2 0.M0 tJ
7440-22-4 Silver 0.0028 0.0028 0.0r 0 U
744(L62-2 Vanadiurn 0.0025 0.0025 o.010 U
7440-66-6 Zinc 0.004s 0.0045 0.020 IJ
j44447-3 Chrtmium 0.0026 0.0026 0.0r0 U
7++o-so-a Coppcr 0.004s 0.004s 0.0I0 l.J
STL Denver Form 3 Pre.p Blank Equlvalent 98
ffisrr
URS Corporttion
'fotal Metals Analysis Data Sheet
Lrb Name:
LoUSDG Number:
Matrlx:
'% Molsture:
Basis:
Analysis Method:
Unit:
QC Bntch ID:
Srmple Allquot:
Dilution Factor:
STL DENVER
D5t030r 39
WATER
Wct
74.:70b
mg,ll,
s259350
I
Cllent Sample ID:
Leb Semple ID:
Lab WorkOrder:
Date/Tlme Collccted:
Date/Tlme Received:
Date/Tlme Leached:
DateJTlme Extrtcted:
Dete/Time Arrrlyzed:
Inetrument ID:
psl150000-3508
HKMDT
09/19105 I 2:30
09/19105 l8:33
019
CAS No.Analyte Conc-MDL RL a
7439-97 -6 Mcrcury 0.000027 0.00fi)27 0,00r)20 tl
STL Denver Form 3 Prep Blank Equivalent
ffisTL
IIRS Corporation
Total Metals Analysls Data Sheet
LBb Name:
Lot/SDC Nurnber:
Matrlx:
"/o Molsture:
Basls:
Analysls Method:
Unit:
QC Bttch ID:
Srmple Allquot:
Ililutlon Factor:
sT[..rJENyFR
psl030 r 3e
WATER
Yst
7474A
mg/L
s262486
l_
Cllent Srmple lD:
Lab Sample Il):
I,rb Workorder:
Dntc/Tlme Collected:
Dete/I'ime Recelved:
Date/'fime Leached:
Drte/Tirne Bxtrscted:
Date/l'irne Anulyzed:
lnstrument lD:
DJIIe0000-4868
HKWl9
aef7,?1r05 t!:30
oe/Z?lQl,te:?O
0u
CAS No.r\nnlyte Conc.MDL RL a
7439-97 -6 Mcrcury 0.000027 0.000027 0.00020 U
STL Denver Form 3 Prep Blank Equivalent
ffiSTt
URS Corporadon
Total Metals Analysls Dnta Sheet
[,tb Name:
LoUSDG Numbcr:
Matrlx:
7o Moisture:
Basis:
Analysis Metlrod:
Unlt:
QC Batch ID:
Sample Allquot:
Dllutlon Factor:
STL DENVER
Dst030l39
WA]'EB.
WsI
6Q?,Q
mEl/I,
s24e6t6
50 mL
I
Cllent Stmple Il):
Lsb Sernple lD:
Lab Workorder:
Dnteflime Collectedl
Date/Time Received:
Date/Tlme Letched:
Date/Time Extracted:
DtteIl'ime Anrlyr,ed:
lnstrument ID:
ps1060000-0r$t]
HJ2JG
09r l5/05 I .5:30
09173105 A7:tl
a04
CAS No.Analyte Conc-MDL RL a
7782-49-2 Seleniurn 0.00033 0.00033 0.0020 U
7MA43-9 Cadmiurn 0.000040 0.0000..+0 0.00r 0 tl
STL Denver I?orm i Prep Blank Equivalent l-01
STL DENVER
Total Metals Analvsls
-3-
BI,ANKS
Contract:
f,ab Code :
URg Corporat,ion
gTf.DEN Carc No. t Sl.A No.:8D(I No. r D5I030139
PrcDaratlon Blenk Matrlx (soil/untcr) r WATER
Preparat,ion B].lnlr Concentrttiou trnl.ts (ngll or rB/kg) :MG/L
fnitiel
Ct1ib.
BIanIB
$ctg lnl
Coat,LuuLng CallbratJ.on
Blanh (nolL)Prg;>arrtioo
Bhnk
Alurrinum to I 0.o17
Ca].eium Lo 0.03{
fron Lo 0 .021
Potasglrrm o ,2{
Magmeeirrgt 0. o{3
SodLun lro 0. o31
ZLrcorriuur 0.00160
0-017
0.03{
0 .021
0.043
0.031
0.00150
0.017
o .034
o .021
a.2l
0.o{3
0.031
0.00150
0.017
o.03{
0.021
0.0{3
o.770
0.00160
0.017
0-034
0.o21
0. 051
0 .0016
STL Denver Forul III Itrl aa2
STL DENVER
'fotal Metals Analvsis
-3-
BI,ANKS
Contsract:
Irab Cod,e:
IIRS Corporat,ion
gTfrDEN Ce,rl No. t S.[.S No, :SDCI No. r D5I030139
PrcDaratioa glauk
Preparat,ion Blank
MatrLx (roil/mtcr) r
Conccutrrtion UnLea (wll or n9lkg):
VTE.EER
MG/I,
rnLtLrL
ci].Lb,
BIE.nTE
(ng/L)
Cqntlnulngr Cal lbration
B]-ank (mg/t )
lczc3c
Lluminurn lro I
CalcLrrnr t,o
Irori Iro
Potaesirrrn
Magmegirr.ur
Sodlum r,o
Ziroonl.unr
0.017
o.o41
0.021
4.24
0. 0{3
o-{83
0 - oo150
STL Denver Form rff IN L03
STL DEIVVER
Total Metals Analysis
-3-
BLAI\KS
Contrrctr URS Corporation
LaI, Codc r STLDEN Crac Ncl. t 8.l,SI No, :D5r030139
Prcparation s].aak Matrix (soil/wrtrcr) r
PrcprratLon Blank ConccntratLon Unitr (ng[t or nglkg) l vlB lt,,
Inltsiel.
Crlib.
rLenk
(mglL)
Continrrl.ng Cr1Lbrrti.on
Bl.trrr]r (tug/L)
.tr1uminum lro I
Calcium Lo
Iron Lo
Potaggiun
Magneelum
Sod.ium tro
Zirconirrm 0.00150 0 .00160 0. 00160 0.00150
STL Denver FOTn III - IN
STL DE]VVER
Total Metals Analysis
-3-
BLANKS
Cont,ruot r
Lrb Coda:
IIRS Corporatlon
STLDEN Calc r[o. t gl.El Ng, r sDc !Io. r D5I030139
PrGparaELon Blanlr
Prcparation Blarrk
MrtrLr (soll/water): WATER
ConccatratLon Unit,e (mglt or nglkg) :Yrclf'
Cont,l-uul-ng CrI Lbntl-orr
BLank (ng/L)
rllLttal
Call,b.
BIanlr
(nrr/r,)
AlumLnum Lo I
Cal-cLrrm Lo
fron Lo
PoEaaeLurn
MagracsLrrn
Sod,ium Lo
Ziroonl-unr 0.00150
STL Denver 8om rII IN 105
STL DENYER
Total Metals Analvsis
-3-
BLANKS
Contract:
LaIs Codrr r
IrRg Coraroratlon
STLDEDI Ca;c trIo. :glg No. I 8Dg lip. r D5r030139
Preparrt,ion Blanh Matrix (tol.l/water) :WTTER
Prcparat{on Blautc Coneentration Unita (mglll or mglkg} :utolr,
Prepa="tioo
81ank
Ial,tiel
CelLb.
BlarlE
(ns /I'l
Cont LnuLng Calt-bratJ-on
B1ank (ng/L)
Aracnlc
Barl-rrru
ChrmLum
Copper
freed
NLckeI.
SlLver
Vanadiurn
ZLnc,
0,004t 0.00{{
0,00070 0 .00070
0.00260 0 .00260
0 , o0t5 0,0045
o-0026 0. 002 5
0.0012 0. 0012
0. 00380 o.002go
0 .0025 0.0025
0 . oo{5 0. 0045
0.00{4
0,00070
0. oo250
0.00{5
o. 0026
0.00L2
0,00290
o, oo25
0.00{5
0 .00,c{
0.00070
0.00260
0.0065
o. oo2 5
o.0012
0.00280
0.0025
0.0045
0.0044
0.00070 U
0.0026
0.0045
0.0026
0.00L2
o-0028
0.0025
0.0045
STL Denver FoTm III IN 105
STL DENVER
Total Metals Analvsis
-3-
BLANKS
Cotrt,raets I
Irab Codc:
[IR'S CorporatLon
Sng No. :sDc No. r D5f030139$TLDEN Crrr No. t
Prcparation B1ank Matrix (rolI/wetcr) r
Prerrarat,Lon Blarrk CoaccntretLon UnLt g
WATER
(mslL or ngr/lEq) :YIGIL
rlritLal
Cr1l.b,
Blrnlr
(ms lt'l
Cont:lnuLng Cal.l,bratlon
B].arrlg (ng/L)
I.czc3e
0.000?0lUI 0,000701UI 0.000701U
l.r;cnlc
Barium
Chromiurr
Copper
NickcI
Si].war
Vanadl.um
Zi-nc
0.00{{
o,00260
o.00{5
o - 0025
0-00L2
0.00290
0.0025
0.0045
0 .0 014
0.0o260
0.0045
0.0026
o,0alz
0.00280
0.0025
0.0045
0 ,001{
0.00260
0 .00{5
o-0025
o.0aL2
0 - 00280
0.0025
0.0045
STL Denver forn III fN 107
STL DENVER
Total Metals Analysis
-3-
I'LAI{KS
Contract:
Irab Code:
Prcplrrtj.on
Prcparatsion
IIRS Cor:>oration
g?fLDTN Cuc No. r
B1ank MrtrLx (goil/watcr) r
B1rnk Concentration unitg
gl,$l No - 3 gDc NO. : D5I030139
(mgfl or nglkg) :ue/L
Anal.ytc
rnltlrl
Crlib.
alanlc
(lrrgtL)
c
Cont,Luulugr Calibration
B].ank' (ng/L)
1 c 7 c 3 C
Prcparation
BI"arrk
c ![
Mercury I 0-0OO027!V O.0OO027lUI 0.000A271U I 0.00A027 I u o.000027 I U ClI
STL Denver form IfI IN 108
STL DEIYI.ER
Total Metals Analvsls
-3-
BLANKS
Contract:
rab Coda:
Prepuatl-on
Preparetlon
IIRS Corryorat':Lon
9TLDEN Cagc Ntr.:
Blank l{atrix (oot l/watar} :
Blank ConccatrrtLon llrrl,tg
gAS No. I SDO rIC). r D5I030139
WJtrTEII
$glT, or ng/kg) :D!G/L
rD.aIftc
rrrl-tl,aI
Callb-
81BDI(
(mg/r.)
c
ContLnul-ng CalLbrat{on
Blank (ng/Ir)
Lc?c3c
Prrrlraratl.on
BLtnlE
c M
Mcrcury I 0.0000A71 UI 0.000027 IU ev
STL Denver Forml ITI IN 109
STL DE]VYER
Total Metals Analysis
-3-
BLANKS
Contract r
Lab Codcr
Preparation
ProprrratJ.on
t RS Corporat,ion
gTf.DElI Canc No. I
B].ank Matrix (noil/watcr) r
Bl'artlc Conccntratlon UnLCE
S}'S tr[o.:sDg Ho- r D5I030139
(ng/L or nglhg) :Drc/L
Arralyt,e
rnLElal
Ca1lb.
BIArlIE
$tglr'l c
ContlnuLngr Ccl J.bratLon
Blank (nglIr)
1 c 2 c 3 c
Prcpa=ranorr
BIanlc
c M
Mcreuryr I -O, 0000311 B 0.oOOO2ZIul -0.00002918 I 0.000027 I U o.00002? I U g\r
STL Denver Fo:m IIf E rN 110
STL DENVER
Total Metals Analvsis
-3-
BLANKS
Contract, r
LaL Cod,c r
Pregrretion
PrGDaratsion
IIRS Corlrontl-oa
STfrDtN Crac No, t
Blanlr Matrix (aol,l/watcr) r
slrrrk Conecntration Unitr (
SAS No. I gDO No.: D5f030139
It or ng/kg) t
aEal"]t,c
Iuttlal
Cr1ib.
BIaDIC
(mslL)
c
Contlnuingr Calibration
BlrnlE (mglr.)
lczc3c
Prcpar"tro,,
BLrnk
c u
Mcrcury I O.OOOO3O IBI 0-OOO027 lV gtr
Denver 111
STL DENVER
Total Metals Analvsis
-3-
BLANKS
Contraot:
r,ab Code:
PrcperatrLon
Preprration
t R,9 Corporatlon
STLDEII Crso No. r
Bl.ank untrl-x (soil/watcr) r
B1ank Conocntsrat,ion Units
Sl.8 ![o. 3 sDc No.: D5I030139
WJTTER
(mglr, or mglkgr) r uglr,
Analytc
Iuitl-aI
Ca1l.b,
BIarrfr'
(nglt,)
e
Contl-nuing Calibration
slaDlc (mg lll
lczc3c
PrcArrrrtLon
B]-anlE
e u
CadmLr:rn
S"I.rlt
"r'
o , 0oo040J u
o .0003301 u
o-0000{0luf 0.00,0,0{0lu I 0.000040 J u
o.000330lul 0,0003301u I 0.000330 I u
o. o00o{ I U
0.00033 I u
u
E
ll
STL Denver f,onr IIr fN ]-42
STL DEIVVER
Total Metals Anrlvsis
-3-
BLANKS
Contracts:
L,ab Codc:
PreDarabion
Prcpa,re'tLon
LIRS Cor5rorat,Lon
gTLDEN Cage [Io - :
Blelok uatrix (eoll/water) :
B1ank Conccntntion UnLt r
gl8 lUo - :aDg NO. r D5IO30139
(mg/L or ng/lcg) r I'fG/L
enalyE,e
InLtLal
Call.b.
BIcJrlt
(mglL)c
Cont,LnuLng CrlLbratLon
BI-tDk (ng/L)
lczc3c
Prel>ar.tioo
Blrrek
c ![
Cedmium
g"1"rf.i-o. oooolo lu.l ,, 9..99,,0j.f,9J.y.1,..9,:.g9,go{.0 I y
o.oo0330lul 0,0oo33oJu I o,ooo330 I u
M-M
STL Denver Fom TII IN 113
STL DENWR
Total Metals Analvsis
-3-
BL.A,NKS
Contract: IIRS Coryoratl,on
I,ab Codc s STLDEN Caga Llo - :g.trg No. r
Prcperlt,Lon B1ank MatrLx ( aoJ.l/watcr) : ItltTER
RrcDaratl.on Blrak CoaoGatratlon Uaitr (nOlL or nelkg) r lrlG/L
SDGI NO. r D5I030X.39
AnaLyte
rnitlaI.
Ca1lb.
Blank
(uglr.)
C
CoaELuul'ng CalLbrntLon
Bl.ank (mfr/r,)
1czc3c
Prcparatlon
BIadc
c llI
Cadrnl-um I o.oooo4olul 0.0000{0lu I .0,ooo0{o I u
0.o0o33olul 0.0oo33olu I 0.000330 I u
M-M
STL Denver FoM TIT IN 774
STL DENVER
Total Metals Analysis
- t0-
METIIOD DETECT}.ON I.IMITS
Coatraet r IIRB CorporatLon
Lab Codc l STITDEDI Case No. r
ICP rD rtrmbcrs Titl. Intreptd ICP
Pl-anc }I. fD NunbtrI
hlrnlec A^tr ID lltrmbcr r
SAS No, :
Datse: 5 lLO 12005
SDGI llo. r D5I030139
lrralytr
WlvG-
lengttr
(nm)
Back-
ground PQI,
(ms/L)
DIDfJ
(mg lL)t{
Alurnl,nrJflr L 157 - 0 0 .10 0.017 I p
AlumLnurn Il 309.2 1.0 P
CalcLum L 3L7. 933 0,20 0,036 l p
CaLcLurn H 318. 1 10 P
fron Lo 259.9 0 ,10 0.021 I P
fron 27L, {{1 1-0 P
PotrassLu$r 7 56.491 3.0 0.24 lP
Magrncelum 279.078 0.20 0.0{3 I r
Sodium Lo 599.5 1.0 0.031 I P
Sodiun H 818 .3 10 P
ZLrconiuru 339.1 0.0050 0.0015 P o
cornrncnt,s 3
STL Denver Fon:r X fN 140
STL DENVER
Total Metals Analysis
-10-
M T:THOD DETECTION LTMITS
Coutract; IIRS Cor:porrtion
Leb Code: STLDTN Crrec No- r
ICP ID lil\unbcr: SUPERTR.LCT II
Flanno A.L fD Number:
nrrnace }.f,' ID Nunbrrr
Sl'S N<r. r
Datr: 5 lt0 l2OO5
gDo No. r D5I030139
lnr].ytc
Itlave-
Iangth
(nrn)
Ea,ch-
grouad PQI,
$tglnl
MDL
(mg/L)M
J[rsanl.c
Baffi-
189.0t12
ffi:,iTT
o .010om 0.004{
6TET0
P
F
Clrromiurn 267 .7 t-6 0.010 0.0026 P
Co5rSrcr t2{.7 53 0.010 I 0.00{5 P
Lcrd 220 - 353 0.0050 0-0026 P
Lcke 23L.50d 0.040 I 0.0012 P
Silvtrr 329.058 0.010 0.0028 P
anadinrn 292 - lLO2 0.010 I 0-0025 P
Zinc 213.956 0 - o20 0 - 00{5 P
O"*"nts:
STL Denver Form X IN
7_4L
STL DENVER
Total Metals Analysis
-10-
METHOD DETECTION I,IMITS
Coat,ract r IIRS Cor-poratLon
Irab Codrr STLDEN
ICP ID lltrmber r
Cage No. r SfS No. :
Datcr 9 lLSl?AOs
sDG No, r D5I030139
Flamo fA ID Num,bcrr
firrrraee t"l, fD Ehrrnber:
PE C'\IN,A
Arralytc
WAtrG-
3.cngth
( nm)
Back-
ground PQI,
(mg/L)
MDL
(ng /L,Dt
rcurar 12 53 .7 0 0.00020 0.00002? I ev
Commants:
STL Denver Porm X IN ]-42
STL DEIVVER
Total Metals Analvsis
4-
ICP INTERFERENCE CHECK SAIVTPLE
Contracts: IIRS CorlroratJ,on
rrab Code I STITDEN Crac No.:
rCP fD Dhrmtrrrr r lt',JI[ fntrapid ICP
gt.g lfo - r sDo NO. r D5I030139
ICg Sourccr Ht-gh hrrity, Sllax,
Concentration unLt,;) r r.s/\
Analyta
Brnrc
Slol ..L 8o1 -rrl
Initl-rl Fotrnd
I "iual Found,
,
So1 ,l 8o1 .AB tR I SoI .^n 8oL.AB t6R
Flumfnrrm Hf I 5OO. O 500 .0 505.30 518.30 I r03.7 I
oiunr HL l S00.0 500-o r,7 L. 19 47 6.19 | Ss.2 I
Iron IIi I ZOO.O 200.o 185.',13.189 .291 ge . 61
taaB:,um I O.0 50. o -0. o{2 56. 33 I LLz .7 |
grncsiun I EOO, O 500 .0 516 ,23 524.t1{ I rO4.9l
iurn Iro I O. O 0 .008
rrm H 50. o 53. 221 106.4 |Zlrconium I O, O 1-0 -0.007 1.19sI 11e.sI
STL Denver Forn' MN 115
STL DENVER
Total Metals Analvsis
-4-
ICP INTERFERENCE CHECK SA]VIPLE
Contract: IIRS Corl>oretion
f.ab Codc r STLTDEN Caac No.:
IeP ID lfirnber: fill' Intraptd ICP
gl,g No. 3 slxl No. r D5I03 0139
ICg Eourccr High h.rrl-ty, SDcx,
Conccntratl-on Units) :WILfr
lrralytrr
T:rrc
SoI ..1. 8o1.lB
tnitLa]. Forrnd
go1 .f, 8o1 .LB tR
Final Found
Glol .r, 9o1 ..LIl tR
]efuninu.ut lri I 500.0 500.0 525 - 70 525 - 30 1Os. 1 I
alcLr.rsr Hi I SOO. O 500.0 503 - tLA {99 -27 99.gl
Iron Hi 200.0 200-0 200 - 09 1gg;31 99.21
trasgl-um I O. O 50. 0 -0.011 55.6{111.3 I
Ftrm.eiuffi 5oo.o 500.0 516 .82 514.98 103. O I
iurn Iro I 0.0 o.031
urn 50. 0 5{-32 108-5I
JzfiContum 0.0 1.0 -0.002 1-1{2 11S .2 I
STL Denver Form fV IN 115
STL DENVER
Total Metals Analvsis
4-
ICP INTERFEREI\CE CHECK SAM'PI,E
Contsract: URS Corporrtl-on
rrb Co{Ia; STI,DEDI Caee }ilo - :8.LA No. r
ICS Source:
gDC No.: D5I030139
Htgh PtrrLty, Sptrx,rCP rD lWrmbar: SUptRTnLCE II
ConecntraElon UnJ.tg) :
InLuLa]. Found.
8ol ,A 8o1 .J\B
a
FJ.naI Found
8o1 .[ 8oLAB
Tnre
gol.t EoI .AEl
pracnLc I O .00 2.00 0. 003 2.A91 10{.5 I
lBarlum I O.0O 0-50 0. oo1 0.5{9 I 109.8 Ium I 0.00 0.50 0.004 o,51{ I 102,9 I
ollpor I 0.00 0 .50 0.003 o. 550 I 1,L2.0 |
Ircad I O.0O 1.00 -0.002 1.03I 103-oI
fNickcl I o. 0o 1 .00 0 .00{1.011 1O1,Ol
Si1ver I 0.00 1.00 0.o01 1.10 I 110.0 I
lVanadl,urn I 0.00 0-50 0. 005 0.521 I 104.2 IZinc I 0.0 1.0 0, o05 1,03 J rO3 ,0 l
STL Denver Fonn MN 1,77
STL DETYVER
Total Metals Analvsis
-4-
ICP INTERFERENCE CHECK SAMPI,,E
Contract: IIRS Cor;poratlon
I,aI, Code 3 STLDE}I
rcP ID DNmber: PE ICPMS
Cage No.:gn8l N<>. r sDc Ho. : DSf 030139
fCS Eource:Inorgenic Vanturca
Conccntretion ffnlUa ) r Eg lr)
raitia]. Found
8oI .^L 8o1 -lB
FLnr1 Forrnd
go1.^L SoI ..nBAnalytc
Tnrc
oo1 .A [IoI ..LIl
o.1095o.1088 109.gI o.002
0.001 I 0.0974
STL Denver lorn rlr N 118
Lrb Name: S'il" DENVER
LoUSDG lt[urntrer: D5l030l39
Matrlx:WAI'ER
ffisrt
tlRS Corporaflon
Total Metals Analysis Data Sheet
Cllent Sample tDr LAB-MYMSD
MS Ltb Sarnple lD: D51020230-$10*$
MS [,ab Workorder: HJVC]9
7o Moisture: N/A Date./Tlme Collectcd: 09/01/05 12:10
Besis: gel Dete/Time Recetved: 09/02105 09:00
Analysls Method; 60108 Drte/l'ime Lerched:
Unlt: mS/|. DatdTlme Ertracted: 09/15/05 15:30
QC Batch ID: 5249617 Drte/Time Analyzcd; 09/19/OS 17..31
MS Sample Allquot: 50 mL lmtrument lD: gll
MS Dilutlon Factor: Xl
Anelyte Splke
Amount
Sample
Result C
MS
Result C
c/o
Rec a QC
I,imit
Alutninum 2.00 0.t7 U 1.84 90 83 - l19
Calcium s0.0 r 500 t47A MSB NC 48 - ls3
Iron I -00 0.38 B 1.76 138 52 - rs5
Magne-sium 50,0 I 200 J I t80 MSB NC 62 - t46
Potassiurn 50.0 I 700 1740 MSB NC 76 - 132
Sodium s0.0 33000 31 700 MSB NC 70 - 203
Zirurniurn 0.500 0.016 U 0.50s r0r 80 - r20
STL Denver Form 5A MS Analysis Dato Sheet Equivalent 119
ffiSTL
IIRS Corporation
Total Metsls Analysis Data Sheet
Lab Name:
Lot/SDG Number:
Matrix:
a/o Molsture;
Basls:
Analysts Method:
Unlt:
QC Bntch ID:
MSD Sample Aliquot:
MSD Dllutlon Factor:
STL DENVER
psr03p1.3?.
WATER
N/A
We
60t08
mgil-
s2496t7
50 rnL
l0
Cllent Sample ID:
MSD Lab Sample ID:
MSD Lab Workorder:
Date/Time Collected:
Datef ime Received;
Date/Tlme Leached:
Date/Time Extracted:
Date/Tlme Analyzed:
Instrument lD:
LAB MS/MSD
Dsro2o230-004D
HJVCIg
99-Q1/05 l2: I ()
g?/Q?/05 0e;00
09/15i05-f5;3.0
09/19/05 17:32
02t
Analyte Splke
Amount
Strnple
Result
C MST)
Result
c 7o Rec a RPT)a
QC Llmits
7o Rec RPD
Aluminurn 2.00 0.r7 U 1.88 92 2.2 83 - r 19 25
Calcium 50.0 I s00 I5r0 MSB NC NC 48 I53 25
lron r.00 0.38 B 1,24 87 34 *52 - r55 2s
Magncsium s0.0 I 200 J r 200 MSB NC NC 62 - 146 25
PoLassium 50.0 I 700 I 790 MSB NC NC 76 - t32 25
Sodi urn 50.0 33000 33600 MSB NC NC 70 - 203 aoa
Zirconium 0.s00 0.016 II 0,s22 104 J..L 80 - 120 2il
STL Denver Form 5A IUISD Analysis Data Sheet Equivalent ]-20
ffi$rt
URS Corporation
Total Metals Analysls Data Sheet
Lab Nrme:
Lot/SDG Number:
Matrlx:
7o Moisture:
Basls:
Analysis Method:
[Inlt:
QC Batch ID:
MS Sample Aliquot:
MS Dllutlon b-rctor:
STI" DENVER
p5 1030I39
WATER
N/A
Ysl
.fol0B
mg/[
s242617,
-5() rn[,
5
Client Sample ID:
MS Lab Sample ID:
MS Lab WorkOrder:
DatelTlme Collected:
Date/Tlme Recelved:
DatelTlme Leached:
Date/Tkne Extracted:
Date/Tlme Anelyzed:
Instmmcnt ID:
I",AB MS/MSD
psr020230-004s
HJVQ9
0.9./.01/05 , I2: l0
09/02i05 0o:00
09/15/05 l5;30
09/16/05 2l:00
020
Anelyte
Splke
Amount
Sampte
Result C
MS
Result C
%
Rec a QC
Limit
Arscnic 2.00 0.025 B 2.55 t26 N 84 - 124
Barium 2.00 0.41 2.47 103 85 - 120
Chrornium 0.200 0,01 3 U 0.2r 9 I r0 73 - 135
Clopptr 0.250 4.a22 U 0.3r r t24 82 - 129
Lead 0.s00 0.013 U 0.435 87 N 89 - l2l
Nickel 0.500 0.016 B 0.564 I l0 84- 120
SiJvu-r 0.0500 0.0r4 U 0.0626 r25 75 - t4t
lVatradium 0.500 0-0r4 B 0.565 I l0 85 - I20
7- -.Ltnc 0.500 4.424 B 0.62?120 60 - t37
STL Denver Form 5A MS Analysis Dato Sheet Equivalent 1,27
ffiSTL
URS Corporadon
Total Metals Anelysis l)ats Sheet
Lab Nrrne;
Lot/SDG Nurnber:
Matrh:
ol, Moisture:
Bnsis:
Anrlysis Method:
Unit:
QC Batch ID:
MSD Sarnple AIIquot:
MSD Dilution Factor:
STL DEI\IVER
t 5t030t 39
WATER
N/A
Wet
60r08
mg/L
5249617
50 nrl
5
Client Srmple tD:
IVISI) [,tb Sample ID:
MSD l,ab Workorder;
Date/Tlme Collected:
Date/Tlme Recelved:
DateJTlme Leached:
Date/Tlme Ertrrcted:
Date/Tlme Analyzod:
Instrument ID:
LAF MS/MS[)
D5r020230-004Q
HJV09
09/01/05 I2: l0
09i02/05 09:00
09115/05 l5:30
09/ | 6/05 2l :00
020
Analyte Spike
Amount
Sample
Result
C MSD
Result
C 7o Rec a RPt)a
QC l,irnits
'% Rec RI}D
Arscnic 2.00 0.025 B 2-57 125 N t.2 84 - t24 25
Bariurn 2.{t0 0.41 2.48 103 0.30 85 - 120 25
Chromium 0.200 0.0r 3 U 0.216 r08 I.5 73 - 115 25
Copptr 0.250 0,a22 U 0.30r t20 3.0 82 - t29 2,5
Letnl 0.s00 0.01 3 U 0.558 ttz ?5 89 - t2r ?5
Nickel 0.500 0.0r6 B 0.s57 108 I.3 84 - 120 25
Silvcr 0.0s00 0.014 U 0.061 I t24 1.4 75 - l4l 2{
Vanadium 0.s0u 0.014 B 0.56r r09 0.66 85 - I20 25
Linc 0.s00 0.a24 B 0.646 124 3.7 60 - 137 25
STL Denver Form 5A MSD AnalysLs Data Sheet Equivalent L22
ffisrt
URS Corporation
Total Metnls Analysls Drta Sheet
Lab Name:
LoUSDG Number:
Matrlx:
Yo Moisture:
Basis:
Anulysis Method:
Unit:
QC Batch lD:
MS Sample Allquot:
MS Dllution Ftctor:
STL DENVER
ps10.30l3q
wA'l'l-lR
N/A
YET
7474A
ms/la
52s83s0
I
Client Stmple ID:
MS Lab Sample ID:
MS Lnb WorkOrder:
DntelTlmc Collected:
Date/Time Recelved:
Drte/Time Leached:
Dato/Tlme Extrected:
Date/Tlme Anrlyzed:
Instrumont ID:
cw-Rr-090205
Dsr030l3e-002s
HJXXz
09/02i05 09:35
09/03i05 08:30
09/19/05 I2:30
09/19/05 I 8:56
0t9
Analyte Spike
Amount
Somple
Result C
MS
Rssult C
o/o
Rec a QC
Limit
Mercury 0,00500 0.000027 U 0.00475 9s 85 - I 14
STL Denver I orm 5A MS Analysis Dato Sheet Equivalent 1,23
ffisrt
[IR.S Corporation
Total Metals Analyeis Dsta Sheet
Lab Nrme:
l,oUSDG Number:
Matrlx:
7o Molsture:
Basis:
Analysls Method:
Unlt:
QC Bntch ID:
MSD Somple ,A,liquot:
MSD Dllutlon Factor:
S-tL nr"NVfR
Dsl030l3e
WATER
N/A
Wet
7470A
mB/L
525835q
I
Cllent Sample ID; GW-RI-t190?$5
MSD Lsb Semple ID: D5I030139-002D
MSD Ltb r#orkOrder: HJXX2
()9/02/05 09:35
09103i05 08:30
Q9/l P/0s I 2:30
09/I9/0.5 ,lX:56
0u
DatelTime Collected:
Drte/Tlme Recelved:
DateI[ime Leached:
Drtefl'ime Extracted:
Ilate/Tlme Anrlyzed:
lnstrument ID:
Andyte Spike
,drnount
Stmple
Result
C MSD
Rcsult
C 7o Ree a RPI)a
QC l,imits
7o Rec RPD
Mercury 0_00500 0.000027 U 0.()0s0s IOI 6,0 85 - I 14 10
STL Denver Form 5A MSD Analysk Data Sheet Equivalent 1_24
ffisrt
URS Corporatlon
Total Metals Analysls Datn Sheet
Lab Name:
LoilSl)G Number:
Mrtrix:
%" Moisture:
Basls:
Analysls Method:
Unit:
QC Batch [D:
MS Sample Alltluot:
MS Dllutlon Factor:
STL DENVER
pJI030l3q
tyArER
N/A
Wct
7470A
uts&
5262486
I
Cllent Semple ID:
MS Lab Semple ID:
MS Lab Workorder:
Date/Tlme Collecterl:
Ilate/Tlme Recelved:
Date/Tlme Lenched:
Date/Time Extracted:
Date/Tlme Antlyzed:
Instrument ID:
LAB MS/h{SD
DsII TOI A6.00I S
HKTI E
09/15/05 I4:30
09/I7l05 09: t 5
0Pl22l0{ t.4:3Q
0q122/05 19;13-
ug
Analyte
Spike
Amount
Sample
Result C
MS
Result C
,A
Rec a QC
l,imit
Mcrcury 0.00500 0.000027 U 0.004 t I 84 N 8s - t 14
STL Denver Form 5A MS Anolysis Data Sheet Equivalent 1,25
ffiSTt
URS Corporation
Total Metals Analysig Drtt Sheet
Lab Nrme:
LoUSDG Number:
Matrix:
o/o Moisture:
Brsls:
Analysis Methtd;
I-lnltl
QC Batch lD:
MSD Snmple Allquot:
MSD Dllution h"rctor:
STL DEM/ER
pst03o l3e
WATER
N'A
Wct
747Ah
rng/I
5262486
-L
Client Sunple ID:
MSD Lab Sarnple ID:
MSD Ltb Work0rder:
Date/I'ime Collected:
Date/I'ime Received:
Date/Time l.,erched:
Date/Tlme Extracted:
Drte/Tlme Analyzed:
lnstr:ument ID:
LAB MS/MST
Dsr170196-001p
HKTIE
09/15/05 14:30
09/ | 7/05 09: 15
a9t22r05 t43A
09t22105 19:33
0I9
Analyte Spike
Amount
Sample
Result
C MSD
Result
C 7o Rec a RPT)a
QC Llmlts
7o Rec R I'I}
Mcreury 0,00500 0.000027 LJ 0.00389 78 N 7.2 85 - r 14 t0
STL Denver I'orm 5A MSD Analysis Data Sheet Equivalent 726
STL DETVVER
Contract r IIRS Corporatlon
'fotal Metals Analysis
-2A-
INITIAI, AND CONTINUING CALIBRATION VERIFICATION
Carc 8fS ![o. rLd, Codo r STITDEN
rnltirl CalLbrabion Souroc:
contrLnulng cd.Lbntl,on Sourcr r
Htgh Purj.ty, SDcx
SDG NO. r D5r0Bm,3t3
,t1'; i
Inorgrnl.o Vanturcr
Concantrael.on UnLta r mr'IlL
I er.rorinrun :l I o.{esl eg,o I P I
lilunrnun:l lo-ol - ss.zsl go.sl so.ol -.ls.grl gz.gl I lpl
Calcium t I 5.0d1 100.9 I P
Calclum H I
fron Iro I
rron HL l 39.01 I 9'1 .5
I rotasgiuml I I I so.ol I so.1zlroo,-z Ip I
I I I o.sol I
Analyte
rnl- t,in1 Ca}j.brabion
Trua Found e6R ( 1)
Continulng Call,bretion
Trrre Found %R ( 1) Found e6R ( 1)u
Llrrgqg"run f I I I 2o.ol I I re.Edl gs-2lpl
Sod.iunr fro I 5,05110L.2 I p
I soarum rrr I d0.01 39.93 I 92 .3 I s0. o I so,19l x.oo.{ I I Ipl
zLrconium I
Control Llmtt.r: Mcrcul:y 80-120;othcr Metals 90-1101 Qycrrida 85-115
0.{9al gg.8 I p
(1)
STL Denver Ponn II ( Part 1) IN
95
STL
Total Metals Analvsis
-2A-
NITIAL AND CONTINUING CALIBRATION VERIFICATION
coBtrrot: t RS CorI oratLonr
Lab Codr s STLDEDI Cree No. I AAS No. r
rnLt,ie]- Call-brrtl-on Bourcc r
Contl,nuing Ca]-lbratl-on Sourec :
Hisrh RrrLty, Spax
fnorgrnic Venturog
sDg NO. : D5I0802{3
ConcrnEratLon Units: \gII'
Aluninun I 0 .50 0,5191 103.6 I p
lmulnrnun:l l. | | so.gl ,le.zzl ge.sl I lpl
Calcium t I 5.0 5.041 100.8 I P
IcarcLrrmnl I I 50.o I {9.191 98 .4 I I lPl
rnaLyte
InLtln1 Calibration
Trnra Found e6R ( 1)
Corrtlnulng Crll,bratLon
Tnrc 1roqnd, e6R ( 1) tound t6R ( 1)M
Irou fro I
[rronrrl I I
0.5101 LoZ.0 I P
I I so.ol aa.6dl s7.3I I Ir
lrotacgirunl I I 50,o I I so. osl roo,1 I P I
l-u:s I I 2o,ol I I re.s7l s7.sIrI
Sodl-um ro I
Sodi-um IIf I 50.0
ZLrcontum I
( 1) ConEroI Llnits :Mcrcutr' 80-1201 othcr lleta1c 90-1101 c]rnido 85-115
5 - 05l 101.2 I p
0-496
STL Denver rorn II (Part 1) b IN
97
STL DENVER
ContracE r IIRS Corporation
Total Metals Analvsis
-2A-
NI'TIAL AND CONTINUTNG C.ALIBRATION VERIFICATION
Carc No. r g^l,g No. :
Htgh Purf.ty, Spcx
InorgranLc Vantutrct
f.alr Code: STITDEN
fnitLal, Calibration Source :
Continulng Calibration Sourcer
SDc No. r D5f084243
Conccntntion unLts 3 sg /r.
ArlaLytG
Initl.al Calibrat,ton
Tnrc tround eGR ( 1l
Continulng Crt ibration
Trnro Found e6R ( 1) round %R ( 1)M
flumLnlrm :l
Aluml'mun :l
Caleium f, I
leerclrrm Hl I
0 ,50
50. o
5.0
50,o I
{9.{98.8
{9. 571 g'l .L I
o. 509 101.8
4 .85 91 .a
fron lro I
rron Hi I
lpotaasi:uml I I I
0.50 0.502 100 .4
50. o {9.171 95.3
5o.ol I I so.6elro1.3lPl
Irlagrn('ciurn I
Isoalpu r.,o I I
20.0
I I E.oI I
19.51 98.0
5.181 103.6 I P
I Soafurn rli I I I I so. o I t9.6{ 99.2 I lpl
Zircontum I 0.50
( 1) Control lrteits r Mcrcury 80-1201 Other Mot,alr 90-110, CYenide 85-115
0.{93 98 .4
STL Denver
For^rr II (Part 1) - rN
9B
STL DETWER
Totsl itletals Analvsis
-2A-
INITIAL AND CONTINUING CALIBRATION VERIFICATTON
coDtErou3 tlRB Corporat,:loa
LAb COdE r STIJDEN Caee Ho. t g}'S No. :
rnl.tial Calilrrabion SourcG r
Continulng Calibratiolr Sourccr
rligh Purity, Bpax
fnorganLc Vcnturog
sDO No. : D5I080243
Conccntratlon Unita s mg/1,
faalyt,c
rnl,eial Caltbration
True Found e6R ( 1)
Contl.nulng Cal.ibration
T:nrr ltound tR ( 1) Found t6R ( 1)u
llruoraun:l . I I I o.sql I I o,.soelroo.llpl
llrtprnu,'r :l | | I so.o.l tg.lrl gg.s I I l.p I
Ca].cium L l 4.711 94.81 p
CaloLrrn H I
[rronr,o I I I I o.5o|I I o.{9BI es.6 I P
Iron Ht I
Potaseium I
MagrnarLum I
Sodium fro I
god.Lun Hl. I
lzirooniunl I I I o.sol I I o.desl s?.6lPl
( 1) Cont,rol l,i nits :llerstrry 80-t20t Othor BloEaIs 90-110; CYanide 85-115
STL Denver Fom II (Dartr 1} IN
STL DENVER
Conureet: t Rg Corporetion
Total Metals Analvsis
-2A-
I NTTIA L AI'[D CON TINUIN G CALIBRATION }'ERIFICATIOIT
Canc No. r 8}fl No. t
Eigrh Purlty, Spex
fnorgranic VeaturaE
Lab Codr r STLDEDI
Inltiel Call.bntl,on Sourcar
Contl.nulng Cr].lbraEl,on Sourcc:
slxl NO. a D5fO80243
I nrql,l.num :l I
ConctnEratLon UnLta s nrgll'
I I o.sol I o.{e3l ga.slrl
lrraLyte
rnieir], Call,bratioa
Tnrc Found 3GR ( 1)
Contlnuing Calibntj-on
Trnrr rorrnd e6R ( 1) Found e6R ( 1)M
l+l*oinum ,f I 50.o I {9.601 99.2 |frl
I catcium rl I 5,01 {,691 ss.Bl P I
[catciunrnl I I I so,o I {z. o3l e{.1 I I lpl
rron Lo I
Iron Ht I 46 .-l91 93 . 5
leotaael.unl | [ .l so-ol I I so-sglror-zlel
fi'ragrncEium I I 20. O I I re.6ol ea.olpl
I soarum r,o I I I I t.ol I I s.rlroe.slnl
I soarum Hi I so-o I 49.12f 98.2 I Ipl
ZLrconfurn I
( 1) cont,rol timl,ta:Mcreury 80-1201 othcr Mctals 90-110t CYanido 85-115
STL Denver Form II (Part 1) IN
100
STL DETVYER
Total Metals Analvsis
-24_
INITIAL AND CONTIN UING CALIBRATION VERIFICA'I'ION
coDtr.ct: URS eorloratLon
I.ab Code 3 STLDEII Carc No.3 SIS No. l
Initl-al Calibration sourca I
ConEinulng Calibratiou Souree:
Htgh PurLty, Spax
rnorgranl-e VenturGB
D5r0 802{3
Coneentsration llnitsr r tug/L
I etqninurr ;l 0.251 o .?5? J1O2 . g I rl
fnalfrta
Initl,al CalLbratLon
Trrrc FounC tR ( 1)
ConELnuing Calibratl,on
Trlre Forrnd tR ( 1) Found tR ( t )D[
Calcl-urn L I 1.98 I 99.0
fron lro I a.250 I100.0
Potaegium I 2A .19 1101- O
LUrye"Blq!! I ro. ol 9. {9 I e{.9 I I I I I lpl
Sod{um f,o I 2,03 I101.5
Lryggqfun l_ o,2sl o.z4zl 96.8 I I I I lel
(1) Control LLnttg r Msrcury 80-120; Othcr Metals 90 -110, Clranide 85-115
STL Denver Eorm If (Purt 1) - IN
101
STL DENVER
Cont.raet: IIRS Corpont,ion
Total lVletals Analvsis
-2A-
INITIAL ANt} CONTIN UING CALIBRATION VERIFICATION
Caac No, I SIg No,:
Inorganl-c Venturas
Hlgrh Purlty, Spcx
LrIr Code r STLDEN
Inl-tLal Calibratl.on $ourca r
Contsinulng CeJ.Lbratlon Souroa:
sDc NO. r D5I080243
Conccntration Unitg z trg lL
Arsanl-e I o.2,09 I gg.5 1. O07l 100.7 1.01{l 101.1
Beriurn I 0.252|100.8 0 .5061 101 - 2 0.5051 101.0
ChromLurrr I a .?{8 I 99.3 0.5031 100.5 o.504 I 100.9
Coppor I o,2L2 I 95. g 0.{981 gg.5 o.500 I 100.0
J r,ead.0.251 o-z{5 I ge,o ; o.so I o,soll 100.8 | o.sozl ror.r I p I
lrvicrsr I . o.zsl o.zsz lrqo.s I o.so I o.sozl ror-l I g:-5oslror.e I e. Ilsu.vsr | ,o.zsl o.zcrl ge..ll .o.sol o.lgrl ,se.z[ o.rell ge.eJpJ
lvaoaaiun I o.zsl o.zlal gs-.zl o.sol o.soll roo.sl o.sollroo.slpJ
Lrfqq_ I o. zsl 0.2{d I ez.6 I 0.50I 0.5121L02.rl 0,5041100,BIpl
Analytc
Inl.tl-al Cr}lbratiou
Tnre pound tR ( 1)
Coat tnuing Crllbration
Tnrc Found e6R ( 1) Found e6R ( 1)u
( 1) Cont,roL l,inltt r llarcury 80-120; Other Mrtels 90-1101 Cyanido B5-115
STL Denver forin II (ParE 1) IN
LA2
STL DEIIVER
Contrtct;
Lrb Codrr
Total Metals Annlvsis
-2A-
NMIAL AND CONTINUING CAI,IBRATION VERTFICATION
IIRS Corgoration
STIJDBN Cagc No. r gfg No.:sDo No- r D5I080243
Initl,a1 CalLbratrion Source r
Continulng Call,bntlon Source :
Inorganic Venturcg
Htgh Purl.ty, Spcx
I lraanio I
Conccntrat,J.on Unitss: mg llt
I I I r.ool r.oozlroo.zl r.orzlror.alrl
.BnaltrE,c
Inl.tl"a1 Cr].lbratioa
Truc round, 8R(1)
Contrlnuing CllLbratioo
Tnrc Porrnd er1 ( 1) forrnd tR ( 1)[!
BarLrun I 0.5071 101. {0.5101102.0 I P
Chrornium I 0.{g51 99.0 0.5001100.0 I P
lgopp'r I I | 0,501 o,0991 ee,BI o.soz[101.{lpl
lr,rlaa I I I I o.sol o.sorl roo.zl o.soslror.olpl
Lur"ral. t I I I o.so I 0,s0il100-zl 0.5081101.6lpl
9il-var I 0.{g7l 9'I .4 o.4931 98.6 I P
vanadium I 0.5001 100. o 0.5031100.6 I P
0.{821 96.{o.{871 97 -4 I p
( 1) Control tlnits r Mereury 80-1201 Othar Uot,als 90-110; CYurlde 85-115
STL Denver folror II (Part 1) fN
103
STL DENVER
Total Metals Analvsis
-2A-
IN ITIAI, AND CONTINUING CALIBRATION VE,RIFICATION
IIRS Cor5ronlion
STITDt![Crrr gAg No. t
InLtLel- Call,brrtlon Souroc r fnorganl.c VanturoB
Contsinulng Ca].Lbrat,ion Htgrh Purity, Spox
Contnct r
frd, Code:8DO NO.: D5fO8O2a3
ConccntraELon Unit,; t mg /l'
Barirrm I 0.5141 102 - 8 0.5201 104.8 I P
Ctrrornium I 0.4951 99.0 0.{891 97.8 I p
rl 0.5101 102,0 0.5151 103.0 I P
lr,aaa I I I l. o.sol o.sonl roo.el o.sos.[.roo.olel
Jurgror I l-. - | ,l o.sol o.soglror.ol o.rggl gg.slpl
lsuvcr I I I I o.sol o.ngsl gg.ol o,lgzl ge.lf el
Venad,Lun I 0.500J 100.0 0.4951 99.2 I P
f,rra].1fte
Inl.u{a1 CalibratLon
Tnrc Found %R(1)
Coutrl,nulng Call,braBLon
Trnr. found e6R (1) found tR ( 1]M
lr'acnrc .l | ,. I I r.ool .r.oozl roo.zl - r.ooolroo.olel
o. {g5l 97 -a 0. c58 I 93.6 I P
(1)Control r.'imits:I{orctrry 80-120; Other trIatals 90-110, CYarrlde 85-115
STL Denver Fonr II (Part, 1) IN
104
STL DENVER
Contraets:
LBb Codc:
Total Metals Analvsls
-2A-
INITIAL AND CONTINUINC CALIBRA,TION !'ERITICATION
IIBS CorporrEion
STLDEDI Cage No. r gAS No,:EDGI No,r D5I08AZe3
InLt,lal CalLbrrtlon gourcc ;
Contlnuing calibration Sourccr
fnorgranlc VenturGr
Htgh Purlty, Spax
Concsntrrat,Lon UnLts : ng/L
I,nrI.yEe
Initlal Ca,ltbration
Tnrc Found, e6R ( 1)
ContrLnuing Calibratrion
'I.r:trt Pound e6R ( 1) tround e6R ( 1)M
Areonic I 1.00 1.0021 100,2 1.0071100.7
faarium I I I I o.sol 0.5121103,{l 0.s181103-6fnt
Lqt qo,',*ortr I I I o.so I o.soil10o.2 l 0.4951 99.0[rl
co1>psr I
fr,aad. I I I
0 .50 0 .5061 101.2 0.5061 101.2
I o,ioI o.s07l 101.{l 0.5031100.61p1
NLche1 I 0.5081 101.6 0 .507 I 101.4
Si].vcr I o. {g{l gg.8 o.{g0l 98.0
I vanedlum I I t I o.so I o.sozl 1oo.{ | o.sool roo.o l
o.{901 9g-o 0.483 I 95-5
( 1) Cont,rol Ltnitg r Mercurar 80-120,. Othcr MoEala 90-110; Crranl.do 85-115
STL Denver Fom If (Part 1) IN
105
STL DENVER
ContrreE 3 IIRS Corporatlon
Total lMetals Analvsis
-2A-
IN ITIAL AI\[D C ON'f INUING CAI,IBfTATION VERIF ICATIOI{
Cage SfS No. t
NIS:T
U1trr geicntl,f Lo
Irab Coda: STITDEN
fnitial Calibratsion Sourcrr
Contlnulng Ca lLbret,lon Souree:
gDG 1rO. r D5I080243
Concrntratsion lrnLEs r mrglt
AnaLytre
Inl.El.aI CalLbration
Tr:rra Found ,GR ( 1)
Contl.nul,ng Ce}Lbratlon
tlrrrc E.ound eBR ( 1 ) Found e6R ( 1)l,I
lraefourrr' I o.gozrzzl. o.oozlzs lroo,o I o-oosooo I o.oolgogl ga.z I o.oosolglror.o lcvl
( 1) Coatrol Li-m,itr r DlercurY 80-120; OLhcr Metalg 90-110, CYaridt 85-115
STL Denver Fom II (Part, 1) - IN
106
STL DENVER
Total Metals Analvsis
-2A-
INITIAI, AND CONTINUING CALIBRATION VERIFICATION
contsract.. I,RS Cort)orttioa
IJab cod,o t STLDEN Caac No. B
NTST
gAg No. t
rnLtlal CalLbratsion gouree3
Contl"nuLng Cell-bration Bource :Ultra gcl.entific
sDo No. r D5I080243
Conccntration UnJ.t,s t mglt'
AnaIytse
luieLal Calibrat,ion
Tnrc Found ,6R (1)
Cont l,nul,ng Ca1l,braLion
Trnre Found tR (1) rotmd tn ( 1)u
0,005000 0.00497
( 1) Control L,tmiEs :Mereury 80- 1201 OLhcr Metals g0-110 r Cf'anide 85-115
0.005025
STL Denver Fonr II (Part 1) III
L07
STL DENVER
Contracr r IIn'S Corfrorat,ion
Total Metals Analvsis
_2A_
INTTIAL AI{D CONTINUING CALIBRATION VERITICATION
Caaa No. I 8Ag No- t
NTgT
Ultre SoLcntifio
Lrb Codr r g?fLDtN
Initl.al Call"brat,Lon Soursc r
Contl,nuingr CrlLbratLon Souroc :
sDs No. r D5I080 2{3
Consentrr,tl.on UnLtr t nglt
(1) ConLrol linltsr Meroury 80-L?0t Other Metal; g0-110, Cyanide 85-115
Analyta
InLtLal, Callbrntlon
Truo Found ,5R ( 1)
Continulng Calibrltl"on
'?Dnra found e6R ( 1) round tR ( 1)M
lucrcury | | | lo.ogsoool o.oosrzol ros.ll I lcvl
STL Denver Fom II (Part 1) fN
108
STL DENVER
Total Metals Analvsis
-2A-
INMAL AND CONTINUING CALIBRATION VERIFICATION
eontractr URS Coq)orat.loa
Lab Code: STLDEN Cagc Nrl. r
rnitLal Crlt brat,Lon Eource r
Continuj.ng calibratl,on gourcc r
Hieh Purlty
Inorganie VenturaE
Conccntration Unitr r mg/L
Cadml.um 0 .0{11
( 1) Control I'tnlEr :Mereury 80-L2Ot Othcr Mctalg 90-1101
D5r0 80 2L3
Selrrnirrm
.f,naIyt,a
InLtLal Calibrltlon
Tnrr Found e6R ( 1)
Contrinuing CalLbretion
Tnro Fognd e6R ( 1 ) round tR ( 1)M
STL Denver Forn II ( Part,1) +rN
STL DEIYVER
Contracts: [IRS Corporatl.on
Total Metals Analvsis
-24-
INITIAL AI{ D CONTINUING CALIBRATION VERI}'ICATTON
Cagr No. t SIS No.:
Hls,h ttrity
Inorgranic Vanuurca
Lab Codc: STITDEII
Initia]. CalibratrLon Elourca:
Coutlnulng CallbratLon Sourcc r
gDo No. r D5I0802{3
Concentrrti.on Unitr : ng l l'
.Frnaltrtc
fnitial CalibrrElon
Tme Forrnd 95R ( 1)
Continuing Calibration
Trnro Forrnd t6R ( 1) Found, ?6R ( 1)M
Jcaaniu-, I I .._ | | o.osol o,osofl roo.el o.osollroo.e,l.Ll
Sclanl-urn I 0.050{1 100.8 0, o4ggl gg.5 I M
(t) control LLmIEg:Mareury 80-L2O;Othr Mctalg 90-110r Cf'anlde 85-115
STL Denver Fom II (Part, 1) IN
110
STL DENVER
Total Metals Analvsis
-2A-
INITIAL AND CONTIN UING CALIBRATION VERIFICATION
eoutriot: URS Corl,orr,tios
Lab Codes STLDEN Crrc I$o, :g.L8 No.:
InitLaI Crl.l-bntl-on Souree ;
Continrrl,ng Calibntion €lourcr r
Higrh Purity
InorganLe Vrrnturcc
sDc No. r D5I08A2A3
Conceu,tration tln'LEs z mg-lrt
.ilrralyte
InLtlal CalibracLon
fnro Found
'6R
( 1)
Continulng CalibruELon
Trruc Found %R ( 1) Eound
'6R
( 1)M
Cadrnium 0-0176
$e].cnlum
(1)Cont,ro1 lrinLEr r Mcrcury 80-120r.Othcr Metalg 90-110; Cyanlde 85-115
STL Denver Dom II (Part, 1) IN
111
STL DEIVVER
Contract r (IRS CorporatLon
Total Metals Analvsls
-2A-
II\ITIAL Ar{D CONTINUTNG CAI.,IBRATION VERIFICATION
Crea llo. r A.}.8 No. r
Higrh Purity
Inorganic Venturar
r,ab Codc: STLDEI{
Inl.t1el cal-ibration Souree :
ContLnulng Cr].LbrrBLon Sourc; r
sDO No. r D5I080243
ConcrntraBl-on Unitst I fig lL
.LnaLtft.c
InitLal CrlLbratl-on
Tnrc round tR ( 1)
ContlnuLng Cr].lbration
Trn[ Iround ,5R ( 1 ) FOund tR ( 1]}T
lcaarrrsr I I [ | o.osol .o.olzal.gs,ol I Julls?r.nrurl | | I o.osol o.olgzl gz.ll I lul
(1) Control f,lcitsr: Morcrrry 80-120,- Oth.r Mctrla 90-110r Clranldc 85-115
STL Denver Eorm II (Part 1) IN
L1,2
STL DEIVVER
Total Mettls Analysis
-28-
CRDL STANDARD FOR AA A}{D ICP
Contract: IIRS Corporetiou
Irab Coda t STLDEN
.trn CRDIJ Standard Sourcc r
fCP CRDL Standard. Sourcrr
Cagc No, r glB No. !Sm, No. : D5I080243
fnorgranLg Vcnturos
ConcentrrElon Unj-ts : Dg lL
CRD[, fltrndrrd for ICP
rnLti,aL Flnal
Trnrc Forrnd, 96R Pound 96R
CRDL Standrrd lor lL
'rnrc Found t,R
Juumrn,rnl I I ll o-rol o..rool roo.ol .1, I
Calciuru L I 0.197 I gg.5
lrronr,? I I I ll ,o.osol o..otgol rro.ol ..1 I
PotrsaLurnI 1,06 1 105.0
Magrnosiuml
I soaturn LoI I
o.191 I 90.5
I ll r.o[ 1.o2lLoz.ol t_J
larr"ontuml I I ll o.oos!o.oo54l ro8.ol I
STL Denver
Form, II (Part, 2, IN
113
STL DENVER
Total Metals Analvsis
-28-
CRDL STANI}ARD FOR AA AI'{D ICP
Contsract, r URS CorporatLon
r,ab Codr t STITDEN
Af, CRDL Etandard Bource:
ICP CRDL gtind,ard Eotrrcc:
Cage No. r SASI No.:gDo No. I D5I08O2{3
f,norganic Vcnturol
ConoantratLon Uolte z mglL
CRDL St,rndard for Ar
Tnrc Found tR
CRDf, Etandard for fCP
rnl,tLal Final,
tround t6n Found
AJ'umtnum I 0 .10 0.113 I 113 .0
Crloium tl
[rronLo I I
0.20 0 .229 I 11{ .5
I ll o.o3ol o,o3{olrrs.3l
PotaaaiumJ 1.0 1.14 1 lIC,0
L4ql.rt*l I I ll o.aol o.rgal go.ol I
llgodf rr.m Lo I I I II r.ol L,Lzl rrz.ol I I
Lllrcon-l-umJ I I ll o-oosl o.ooselrrc.ol I
STL Denver Torn II (Part, 2l IN
LL4
STL DENVER
Total Metals Analvsis
-ZB-
CRDL STATYDARD F'OR AA AND ICP
Coreract: IIRS Cot?o::ntlorr
Lab Codcr STLDEN Cage No, t SDo No. r D5f0802{3
.f,n, CRDL St,rndard Soursc r
ICP CRDL Standrrd Sourccr Eigrh Furlty, Spcx, Inorgrnlc VcnturGg
CRDL St,andard for tf,
Tnrc round %R
CRDL Standrrd for ICP
Initial Final
Trnra Forrnd %R found
Arcenic I
Concent,rrtlon Unitc z mgll,
o. o10 O.01rt1l 141.0
Barlun I 0.0050 0.00516 I 103.2
Ctrromiurn I o-010 0-0111I rr1.0
Copper I 0.010 0.0105 1 105,0
I rictar I I
0.0030 0 .00196 I 55 .3
o.o1ol o.or2oltzo-ol ILsirr!._ | I lt o.o1oI o.oo93I g3,ot
venadLrun I
[_1inc I I
0.010 0.01081 108,0
o.ozol o.oz33l116.sl I I
STL Denver f,om fI (Part, ?) IN 115
STL I)ENYER
Total Metals Analvsis
-2B.-
CRDL STANDARD F'OR fuI AI\ID ICP
Contsract: URS Cor?oration
Irab Coda: STITDEN Cagc No, r gA,fl No. :
.trl' CRDtr Standard Sourea:
fCP CRDL Standrrd Soursrrr
Ultra Scl-cntf.fie
8Dg No,: D5I08A2L3
CRDL Standard f,or fCP
rnl,tla]. f inel
Trnr Found e6R Foulrd tn
CRDL Etandard for Ar.
Trrrc Porrnd ,6R
MercurT I O.000400 0.00017
ConoantratLon UnLtss r mg/t,
STL Denver Fom II (Put 2) IN
115
STL DENVER
Total Metnls Analvsis
_28_
CRDL ST'ANDARD TOR AA AI{D ICP
Contnct r IIRS CorporaEl,on ,O
f,eb Code : STITDEN
rA CRDL sltmdard Souroa r
ICP eRDIr Standrrd Sourcc r
Carc No. r 8l.SI No. I sDs No. r DSf0802{3
InorgranLc Vcnturas
ConcentsraELon llnltg r mg/L
CRDL SEandard tor fCP
rnLtial Fl"na1
triuG Found tR Pound 96R
CRDI.r Strndard for .Lf,
Tnrr Found ,6R
Cadmiust 0.0010 0.00100 100.0
Selanium I 0.0010 0.00088 88 .0
STL Denver Form II (Part 2) fN
7!7
ffisrl
URS Corporation
'l'otal lltctals Analysis Data Sheet
Lab Nune:
LoUSDG Number:
Matrix:
7o Molsture:
Basis:
Anrlysls lVlcthod:
Unit:
QC Batch It):
Sarnple Aliquot:
Dilutlon Factor:
s]-r, DENVER
D5 r()80243
WATEJB
-!YEI
60108
[,gi L
5-$526 I
50 m[.
I
Client Srmple ID:
Lrb Sample ID:
Lab Workorder:
Date/Tlmc Collected:
Date/Tlme Received:
Date/Tlme Losched:
Date/Time fl,xtracted:
Date/Tlme Andyzed:
Instrunrent ID:
nst220000-26 r8
HKs0lu
(19/23105 08:00
a9nllcts 23"41
azr
CAS No.Anall'te Conc.MDL RL a
742e-90-5 Aluminum 0.0r 7 0.01 7 0.10 U
7439-89-6 Iron 0.021 0.021 0. t0 LJ
7439-954 Magnesiurn 0.043 0.043 0.20 TJ
7440-09-7 Potussiunr 0.24 4.24 3.0 U
7444-n-5 Sodium r.l r.l 5.0 LJ
7444-67 -7 Zirconium 0_0()r 6 0.00 r 6 0.0r5 U
7444-70-?Calciurn 0.034 0.034 0.20 U
STL Denver
Form 3 Pretr Blank Equivalent
118
ffisTL
URS Corporatlon
Total Metals fuialysls Datn Sheet
Lab Nume:
I,oUSDG Number:
Mutrlx:
7rr Moisture:
Basis:
Annlysis Method:
Unitr
QC Batch ID:
Srmple Aliquot:
Dllution Fnctor:
STI. DENVER
ps10$[}2{3
$l,A'rcn
Wct
601()R
IEP/L
s26sbl
50 nrl-
1
Cllent Sample ID:
Lab Sample ID:
Lab Workorder:
Dnte/Tlrne Collected:
Date/Tlme Rcccived:
Date/Tlme Lerched:
Date/'l'ime Extracted :
Date/time Analyzed:
lnstrument ID:
I)sr220000-261 B
r{K"19}y_
09i23i05 08:00
A9t?7 /05 09:21
0r_6
CAS No.Analyte Conc.MDL RL a
7440-38-2 Arscnic 0.0044 0.0044 0.() r5 U
7439-92-l Leud 0.0026 0.0026 0.0030 U
7 441)-39-3 Buriun:0.00070 0.00070 0.010 U
7440-02-A Nickel 0.(x) l2 0.0012 0.040 U
7440-22-4 Silver 0.0028 0.0028 0.00s0 Lj
7440-62-2 Vanadium 0.0025 0.0025 0.0 t0 U
?440-66-6 Zinc 0.0045 0.0045 0.020 LJ
744{t-47-3 Chromium 0.0026 0.0026 0-010 IJ
744(l-50-8 Coppcr 0.0045 0.0045 0.010 U
STL Denver
Form 3 Pren Blank Esuivalent
119
ffiSTt
URS Corporetion
Total Metals Analysls Dtta Shcct
Lab Nrme:
Lot/SDG Number:
Matrlx:
o/o l\{olsture:
Basis:
Analysls Method:
Unit:
QC Brtch ID:
Sample Allquot:
Dllution Factor:
STL DENVJR
D5r080243
WATEB
wel
7470.^
mglL
5259437
I
Cllent Sample ID:
Leb Sample ID:
Lab Work0rder:
Date/Tlme Collected:
Dnte/Tlme Received:
DatelTlme Lcnched:
Date/Ttme Extrrcted:
Date/Tlmc Annlyzed:
Instnrment ID:
D5 r l 60000-4378
r{KVPA
09/23105 .I2:50
0e/23/05 18;Qf
0l_9
CIAS No.Analyte Conc.MDL RL a
7 439-97 -6 Mcrcury 0.0()0041 0.0()0()44 0.00020 I.J
STL Denver
Form 3 Prep Blanh Eouivalent
]-20
ffi$Tt
URS Corporation
Total Metals Analysis Ilatr Sheet
Lab Nnme;
LotlSDG Number:
Matrix:
oh Musture:
Basls:
Analysls Method:
Unlt:
QC Bttch ID:
Stnrple Allquot:
Dilutlon Factor:
STL DL;NVER
p5t080243
wAren
Wct
602Q
rng/L
5.2.6st72
59 ntL
I
Cllent Snmple lD:
Lrb Sample ID:
Lab Workorder:
Date/Tlme Collected:
DutelTlme Recelvedt
Dste/I'ime Leached:
Drte/Tlme Extrtcted:
Dst€/Time Analyzed:
Instrument lD:
pst22o0o0- I72B
HK49N
09/23/05 I5:30
09/28/05 (.i I :50
004
CAS No,Annlyte Conc.MDL RL o
'1782-49-2 Sclcnium 0.00033 0.00033 0.0020 L]
7440-43-c)Cadmium 0.0u)040 0.000040 0.001 0 U
STL Denver
Form 3 Preo Blonk Eluivalent
]-27
STL DEIVVER
Totsl Metals Analysis
-3-
BLANKS
Contrrctr URS CorDoratlon
LTb Codc: STLDEN Cagc IlIo. r
Prcparation Blank Mrt,rLx (goil/watcr) :STATER
EIDO NO. r D5f 080243
Praparatl.on Blrnh Concent,ratrLon Units
.lnalrt,c
Inl-trl.aI
CaILb.
Blrnk
Grg.lI-l
e
contrl-nuing CalibretLon
Blenk (mg/Ir)
c3c2e1
Pra3raratLon
BIank
e DI
Aluxtinrrm Lo
ffi
-
Iron lro
Prt."rlrr*ffiffi
0 , 0.l7lu
o ,034l u
o.021lu
o .24[u-
0 .,0{3lu
0.0311 u
o,,,p,17lul o..o17ful 0.017
o.o3tlul .L034 lul o.03{
q:o21luI o..o2tlul 0.021
0.24J,,:rl o.24 l.ul 0.2{
0.043Ju1.,.,.- o,o{3 lul g,:o{3
0.031[ul 0.031!u1 0.335
g
u-u
U
u
B
0.017 [ u
o,ogl I u
0,021 J u
o.?tli
o.o{3 I u
1,100 I u
P
F
P
P-P
;
ZLrcorrLun 0.00160 U o,00r.60luf o.oo15oIul o,00160Iu 0.0016 I U P
STL Denver 8oM II.I IN
122
STL DEI{YER
Total Metals Analvsls
-3-
BLANKS
Contract:
Lab Codct
Preprratl,on
Prcparrtrlon
IrRg Corporatl-on
STLDTN Cagc !Io. t
B1ank Maerix ( aoil/watar) ;
B1ank. Coneantrrtl"on UnLt;
gf,g No. :sDc No. r D5f080283
(mg/L or m9lkg) t r{GlT.
Prrsrr"Lto,,
BIank
Initlal
Callb.
BkDIc
(nog/rr)
Contsinuing Callbrttion
BIanIs (tuglt'l
^l.luminrJrr Lo I
CelcLurn Lo
Iron Lo
PotassLum
Mrgraasirrrn
Bod,lum Lro
T,Lre'elnLum o.00150
STL Denver Fonn III D IN
1-23
STL DENVER
Total Metals Analysis
-3-
BLANKS
ConEraet: IIRB Corlpretlon
Lrb codc:gTLDEN Caee N(r. t
Praparation Blanh lartrlx (goil/watar) :W}IrER
8Ag No. r 8Do No. r D5f080243
Prcpartrtloa BlanJB Coaoentret,:lon Unitg (mglL or rr[l/
Aluninum Lo I o .017 0.017
CaloLum Lo 0.052 0.034
Iron Lo 0.o21 0.021
Potarral-um
trf,agiacel-ul[o-043 o .043
Sod.irun Lo 0.032 0,031
Ziroonl-urn 0 . 00160 0.00160
![G/L
0.017
0.03{
0.021
0.043
0.105
0.00150
0.017
0.03{
0.021
o.0{3
0.099
0.00160
Prcprrltlon
BIank
ContLnu:Lng CaI lbration
BIarxI( (rW /t'l
Inl"t,l-al
Calib.
BIeDIE
(mgll)
STL Denver FoTm III . IN
L24
STL DEI\{VER
Total Metals Analvsis
-3-
BLANKS
ConEract r
Leb Code:
Prer>erats{on
Preperatl,on
IIRS CoraroratLon
STLDEN Clac No,:
Blank l{atrix (aoil/wrtcr) r
BLaak Conccntratioa Unl.Eg
fI.1,8 No, t gDs No.: DSf 08021?
(mg/L or ng/kg) r I'lGr lL
Cont,Lnuing CclLbratlon
Blank tuslLl
lczc3c
Preparatioa
Blank
A1umj.nurn lro I
Calc1um Iro
fron Lo
Potassirrn
Magme sium
SodLum Lo
Zirconirrm 0.00160
STL Denver Fom' III TN
L25
STL DENVER
Total Metals Analvsis
-3-
BLANKS
Contraet r IIRS Corporat,f.on
[,ab Coda ! STLDEN Caac No. t SIS trlo. I gDO NO.: D5I0802{3
Preparation Blnnk Matrix (roJ,I/water) I WATER
PraperatLou BLanIc ConcgnEratiou trnl.tg (mg/b or rlglkg) z ![o/L
rn{tLa1
Ca1lb.
BIt:rk
(mglr)
Contl,nulng Call.bration
Blank (mgltl Prcparation
81ank
Arscnl.e
Barium
Chroanlrrm
CoDper
Nickel
Silver
Vanadiun
0.0044 0.00{{
0 - 00070 0.00070
0.00260 0, o0260
0.00{5 0.0045
0.0026 0.0026
0.0012 0 . 00x,2
0 .00290 0.00280
0. oo25 0.0425
0.00{5 0.0045
0. 00{{
0.00070
0.00250
o,00{5
0.0026
0.00L2
0.00280
0.0025
0,0045
0.00{{
0.00070
0.00260
o.00{5
0.0025
0 .0 a,..z
0,00290
0.0025
0.00{5
0.001{
0.0007
0 , oo25
0.0045
0.0026
0,ooL3
0.0028
0.047,5
0.0005
STL Denver FoTm III IN
L26
STL DEIVVER
Total Metals Analvsis
-3-
BI.ANKS
Cout,nct I IIRS CorT>oratj.on
LBb eodo: STITDEN Cagc No.:SJilfI No. :Dsro 8 02 43
Prapare,tlon Blrnlc Dlatsrl,x (soil/wrtcr) I
PrcDaration Blanlr Coneentratl,on Unitg (ng/L or uglkg) r MO/I,
Initlal
Cal-l-b.
BI.LnK
(tng/Ir)
Contlnul.og CaLLbratLon
Blanh (mglL)
le2c3e
PrrprratLon
BLrnk
Arsonle
Burium
Clrromium
Copper
NLckeI
Sl-Iver
VanadLurn
o. 0 041
0.00070
0.00260
0.00{t5
0.0426
0.04L2
0.00280
0.0025
0,00{5
0.00tl{.
o . 00070
0.00250
0,00{5
0,0026
0. oo12
0,00290
0.0025
0.0045
0.0044
0.00070
0.00250
0.0045
0.0026
0.00L2
0.00280
0.0025
0.00t5
STL Denver POnI, III IN
L27
STL DENVER
Total Metals Analvsis
-3-
BLANKS
Cont,raet:
.l
I-rab Codc r
PraDaretLon
Proparation
IIRS Cor;pontion
gTLDEII Caec No.:
B1ank MrtrLx (roL]./water) I
B].an^k Conccntrabion rmLta
gAg No. t gDO NO. r D5I0802,C3
(mSlI' or tryl}.;gl t frdilL
^Lrral.ytc
InLtl-a1
Crllb.
BLrnls
(ms /L)c
Conti"nuing Cal lbntlon
B]'aak (nglL)
1 C 32C c
P*pr=.ttoo,
81o.nft
e M
Meroury I -0.0000511 B 0.0000G2 I B I -0.000051 lB I -0.000050 I E 0.000044 I U c\r
STL Denver Fonr IIf fN
1,28
STL DENVER
Totnl llfetals Analvsis
-3-
BLANKS
Coatrnet:
Irab Codtr r
Prapantl-on
PrGDaration
t RS Cor?oretion
STLDEN Caoe No. t
Blrrrk Matrix ( aol.l/watcr) r
B].ank ConoantreEl.on Unitc
SAA No. :SDc No. r D5I080243
W}TER
(mg/L or mr/kg) t MG/L
.[nalyta
rnLtLal
Ca1Lb.
Blealc
@glt \c
ContLnulng Ca1LbraE,ion
Blank (nglr)
1 c 2 c 3 c
Pro1lrrlBlou
BIank
c M
Mercury I O.OOOO49 lBl -0.000052 lB crr
STL Denver Fom fII, - IN
L29
STL DEIVVER
Total IWetaIs Analvsis
-3-
BL,,TNKS
Contract:
Lab Codc:
Praparation
t Rg Cor-pontion
gTL,DEN Cage No. I
B1anlr Matrix (toiI/watcr) :
B1ank ConccnEraEion llnitr
SLg No. t grlo NO. r D5I080243
Preparation $sglL or nglkg) r DIG/L
lna1-ytsr
rnltlel
Cr1Lb.
Bla.ulc
(mg /L)c
ConElnuing Ca1tbratsion
BIarrlB (ng/L)
1 c 2 c 3 c
Prepar.a*on
BIauh
c u
Cadmium
S"1"tf*r,
0 . 0o00{01 u
0.0003301 u
0. o0o0*9 I u I .-0-.0000o0 [u,I 0- 0000{o I u
0.0003301u1 0.0003301u I 0.000330 I u
o. o000{
0.00033
u
u
M-M
STL Denver Porm IIT I}I
13 0
STL DENI/ER
Totnl llletals Analvsrs
-3-
BLANKS
Contnet:
Ld, Codc:
Pregaration
Preparatl,on
URS Corlroratlon
SBIJDEDI Cagc No. r
Blnnk Matrix (goil/watar) ;
Blank ConocntreBlon Unitc
gAfl No.:sDtg NO.: D5I08O243
$rrlL or ng/kg) t ![G/L
Analytc
taLtial
CalLb.
Bhnh
(uglt';.
C
ConE J.nuing Call.brat,ion
B1ank (rng/\.|
1 e z c 3 c
Preparrtl.on
BLenk
C u
CadmLrrm I o.9000,60l I' I 0 .00:0{0 Iu J .o.000040 I u
0.00o33olul 0.0003301u I 0.000330 I u
M
M
STL Denver forn III fN
131
STL DENVER
Total Metals Analvsis
-3-
BLANKS
Contract:
LaL codcr
Prc1rrratLon
ProparrEl.on
URS CoryoratLon
STLDEN Cage Nt>. t
Blank MrtrLx (soil/wrtcr) I
Blank Coneontrat,l,on Unlts
gf,S No. :SDG NO. : DSf 08 O2[3
(mg/L or nglkg) :I{G/I,
Anallrtc
rnLtLrl
Callb.
BIaDk
$s1a7 c
Cont{nulng CalibratLon
Bhnk (mg/L)
1 c 2 C 3 c
Prrpant,l-on
B].ank
C M
CadmLurn
S"1o*f*n
o, o000tg
0.000330
U
u
IlI
I
M
STL Denver forn III IN
732
STL DEATVER
Total llletals Aualvsis
-4-
ICP INTERFEREI\CE CHECK SA]TTPLE
Coat,raet r IIRS Cot-lloration
tab Coda r STIJDEN Caee No. r
rCP rD NUrubrrr TJA IntroDtd IeP
SLS No. t sDo No. r D5I080213
Ics Souroc: Hlgh Purlty, Spex,
Concentratlon UnLt,g) :ug/.1
Tnro
Sol ..L SoI .AE
In!.t,La1 Fou.ud, I "inal t*.od
gol,.A 9ol .lB tR J sol .1, 8oI .lB tR
Jafunfnum Hf I SO0. O 500.0 527 , 91 52s,18| rO5.oI
CalcLtrm Ht I SO0 - 0 500.0 505.80 502 .55 1oo .5 I
Iron IIi I 200-0 200,0 2A2.0{199.9{1Oo. o l
Potaesium I O. O 50 .0 -0.055 55.59 113.21
gncaLrrm I S0O. O 500 ,0 519.92 518. 6g 103 .7 |
SodLrem Iro I 0. O -0.01{
um IT 50 .0 54 .81 1og-61
Zireoniurn I 0. O 1.0 -0.003 1.1?11 11?.11
STL Denver Fom, IV IN
133
STLDENWR
'fotal Metals Analvsis
-4-
ICP INTT]RFERENCE CHECK $AIVIPLE
Contract,: IIRS Corporat,ion
L8,b Codc: STIJDEN Crac No,3
rCP fD Nunrberr T,I}, fntraptd fCP
s.L8 No. ;gDC !rO. r D5I080243
fCg Sorrrea I Hlgrh Purity, Spcx,
Concrntration unLts):?stL
Errrs I rnitl,al Found I rj-nar Found,
ranlytc I sot.e gol.lB l gof.r sol.lB tn l eor.r gol.tB tR
Jefunrfnum Irn I 507 . 5g 502.70 I roo ,5 I
fdalciun tti.
ron Ht
taseium
gnaal,um
Um Iro
llm Hr.
l-rconiurn
{90.93 I 96.2lg7. 55
1g 3 .2',1 19 o .3'l
-0.0{g I 53 .13
d93 .93 489.18 I 97 .8
51.99 I 108.0
STL Denver
foM IIT IN
L34
STL DEI{VER
Tottl Metals Analvsis
-4-
ICP INTERFERENCE CHECK SAMPLT]
CoutreeE r IIRS Corporat,l,on
LTb CodE: STI,DEN
ICP ID Nunbcr: SUPERIIBACE
Caac No. :grS Ho. :SDc NO. : D5I080213
ICg Souree:Higrh Purlty, Slpex,
Conccntratioo UnlEe):ng lt'
Trnrc I raLtl,al Fouod I rinal Fotrnd
Analf'Ec I sol .r Bol.tB Jgot.r. go1 .rB tn lsof."a. So1.rB *R
fnrsenic 0.00 2,00 0.005 2.ool roo.ol
Barl-urn 0.00
0.00
o.00
ad,0.00
okrlL 0.00
JSJ,lvar 0. o0
paaJilfrun-0 .00
0.0
0.516 I 103. 2
0,00{ I 0.{80
0.53{ I 106.9
0.98 I gg.0
0.9{ I g{.0
1.04 t 10{.0
0.{7gl 95.8
0.91 1 91,0
STL Denver form fV - IN
135
STL DENVER
Total Metals Analvsis
-4-
ICP INTERFERENCE CHE,CK SAIVIPLE
Contract r IJRS CorporatLon
LrL Codc: STLDEN
ICP ID lfirrrbcr: PE ICPUS
Cage No.:A.[g No-:sDg No. r D5I0802113
ICS Souree:fnorganic VcnturGa
ConccntraEion Units) r mglL
lfma raLtlal Found Fina]. Found
Sol .A SoLAB tr,RAnrlyt,s I go1 ..L Sol ..eu l SoI.l gol .lB r6n
lcaamlum
Srrlenlum
0.0995 | S9.6 I 0.0998
0 " 10e{ l 10 {.1 0,1051
STL Denver
Fom IV . IN
136
ffiSTL
URS Corporadon
Total Metals Analysls Datt
Lab Nrrue:
LoUSD(i Number:
ll{atrix:
o/s Molsture:
Basis:
Analysis Metbod:
Unlt:
QC Brtch [D:
lltS Sample Allquot:
MS Dllution Factor:
STI,TENVER
psr0B0243
WATER
NlA
Wct
6Qt0B
rng/L
52.bs761
50 nrl
5
Sheet
Cllent Sample If):
MS Lab Sample lD:
IllS Lab Work0rder:
Drte/Time Collected:
Dlte/Tlme Recelved:
Date/Tlme Leached:
IlatelTlme Extracted:
Date/Tlme Analyzcd:
lnstrunrent lD:
Gw-s r -090705
Dsr0802j3-004s
HL6JM
09i07105 09:55
09i08/05 09:30
0ei23i0_5 08J10
09/26f05 "t:54
021
Analyc Spike
Amount
Sample
Result C
MS
Result C
o/o
Rcc a QC
Lirnit
Alurninurn 2.00 0,084 U 2.01 98 83 - I t9
Calciurn 50.0 I 400 I 390 MSB I',,fC 48 - 153
Iron r.00 0.r3 B I .0s 93 s2 - 155
Magncsium 50.0 630 617 MSB NC 62 - 146
Potassiunr s0.0 440 492 MSB NC 76 - t32
Sodium 50.0 s500 5490 MSB NC 70 - 203
Zirconiurn 0.s00 0,021 B 0.534 103 80 - 120
STL Denver
Form 5A MS Analvsis Data Sheet Eouivulent
]-37
ffiSTL
URS Corporatlon
Total llletals Analysls Data Sheet
Lab Ntme:
I-,oUSDC Number:
M atrlx:
o/o Ulolsture:
Basis:
Anrlysis Method:
Unlt:
QC Bttch ID:
MSD Sample Aliquot:
NISD llllutlon h'actor:
STL T]T:NVEB
,0JI080243
w{TER
NiA
wcf
60rOts
mg/L
526s26t
5(t rL
5
Client Srmple ID:
MSD Lab Srrnple ID:
MSD Lab rilorkorder:
Drts/Time Collected:
DstclTlme Received:
Dtte/Time Leached:
Date/Time Extracted:
tlate/Tlme Analyzed:
Instrument I D;
GW-Sr -09070s
D5t080243-004D
HJ6JM
09i07u05 09:55
09/08/05 0q:30
09/r3l05 08:00
Q9i26/05 23:5a
02r
Andyte Spike
Arnount
Sample
Result
C MSD
Rcsult
C % Rec a RPD a
QC Limits
7o Rec RPD
Aluminurn 2.00 0.084 U 2. I0 l0l 2.5 83 - I le 25
Calciurn s0.0 I 400 I 430 MSB NC NC 48 - 153 25
Iron 1.00 0.1 3 B 1.06 93 0.70 s2 - lss 25
Magncsiurrr 50.0 630 699 MSB NC NC 62 116 25
Potassium s0-0 M(j s09 MSB NC NC 16 - t32 25
Socliurl 50.0 55()0 5650 MSB NC NC 70 - 703 40
)irconiurn 0.50r)0 02r B 0.s46 r0s 2.1 80 - r20 ?5
STL Denver
Form 5A MSD Anulysis Data Sheet Esuivslent
138
ffiSTL
URS Corporatlon
Total I\fetrls Analysis Data
Lab Name:
Lot/SDG Nurnber:
Matrix:
7o llloisture:
Brsls:
Anrrlysls Method:
Unit:
QC Butch ID:
MS Sample Aliquot:
llt S Dllution Frctor:
EIL DENVER
D$jI08()241
wAI FB
MA
UsI
60108
firg/I.
526s2$L
50 mL
I
Sheet
CIIent Sample ID:
MS l.ab Sample lD:
UIS Lnb Workorder:
Drte/Tlme Collected:
Drte/Tlme Received:
Dtte/I'ime Lenched:
Dnte/Time Extrncted;
Drte/f ime Analyzcd:
Instrument I D:
cw-s r-090705
psl0s0?{3:004s
HJ(}JM
091a7/A5 09:55
09/08105 09:30
09/23105 .08:00
()91271(t5 l9:22
arc
Analyte Spike
Amount
Sarnple
Rcsult C
MS
Result C
of/o
Rec a QC
Limit
Amerric 2.00 0.0078 B 2. l5 r07 84 t24
Brriurn 2.00 0.r3 2.44 95 8s - 120
Chnnniurn 0,200 0.0026 U 0.t72 8s 73 - r35
Copper 0-250 0.004s U 0.295 t17 82 - tZ()
Leatl 0.s00 0.0026 U 0.466 93 89 - r2l
Nickel 0,500 0.080 a.497 83 N 84 - r20
Silver ()_0500 0.0028 Li 0.06s3 r30 75 - t4l
Vutradium 0.500 t).002s L;0.451 90 8s QA I
Zinc 0.s00 0.01 5 B i.M3 85 (,0 - I37
STL Denver
Form 5A hIS Analvsis Dato Sheet Eouivalcnt
139
ffisrr
tlRS Corporatlon
Total Metals Antlysis Datu Sheet
Lab Nrme:
LoUSDG Number:
Mstrlx:
o/o Moisture:
Basis:
Anulysls lVlethod:
Unlt:
QC Bntch ID:
IUSD Sample Aliquot:
MSD Dllution Ftctor:
SI'L DFNVER
ps r080241
wATER
NiA
Ust
601 0B
mgll.
s26s26t
50 nr[-
I
Cllent Snmple It):
MSD Lsb Sample ID:
IUSD Lab WorkOrder:
DttelTime Collected:
Date/Tlme Recelved:
Date/Tlrne Leached:
DatelTime Extracted:
Drte/Tlme Analyzed:
Instrument ID:
GW-S1-09070s
p51080241-004p
HJfiJM
0e/07/05 09:55
09/08i05 09:30
0ei23l05 08:00
(t9/27/()5 t0:,22
016
Anrlyte Spike
Amount
Sample
Result
C MSD
Result
C %o Rec a RPD a
QC Llmits
oh R.ec RPt}
Arscnic 2.00 0.0078 B 2.24 ltz 4t 84 - r24 2s
Barium 2.00 0.1 3 2.t2 99 3.9 85 - 120 2s
Chromiurn 0.200 0.0026 U 0.t80 89 4.2 73 - I35 25
Coppcr 0.2s0 0.004s TJ 0.30e r22 4.6 82 - t29 Z5
Leacl 0.500 ().0026 U 0.483 97 3.5 89 - r2I 2s
Nickel\0.500 0.080 0.513 87 3.2 84 - 120 2s
)tu",0.0s00 0.0028 U 0.0680 135 4.0 75 - t4l 25
\/anadiunr 0.500 0.002s L;0.466 93 3.1 85 - 120 25
/,inc 0.s00 0.0r5 B t).457 88 3.3 60 - 137 25
STL Denver
Form 5A MSD Anolvsis Duta Sheet Eauivalent
740
ffisrr
IIRS Corpomtion
Totsl Metals Analysis Duta Sheet
Lab Name:
Lot/SDG Number:
Mntrix:
o/o Molstur€t
Basls:
Analysls Method:
Unlt:
QC Brtch ID:
MS Salnple Allquot:
MS Dtlutlon Factor:
s'rL pElivER
p5108024-3
WAl ER
NIA
Uet
7470A
mg/l.
52s2437
I
Client Srmple ID:
MS Lsb Sample ID:
MS Lsb WorkOrder:
Date/Time Collected:
Date/Tlmc Received:
Date/Tlme Leached:
flate/Tlme Extracted:
Date/'l'ime Analyzed:
Instrument lD:
Gw-sr -Q1)07CI5
D5r080243-004s
HJ6JM
09/08i05 09:30
o9n3ta5 tuia
Q983r05 I8:t8
019
Analyte
Spike
Amourtt
Stmple
Result C
MS
Result C "h
Rec a QC
Llmlt
Mercurv 0.00s00 0.000044 U 0.00377 75 N 85 - I 14
STL Denver
Farm 5l M,S lnah'sis Dr.ta Shect F,ouivnl.p.nt
747
ffiSTL
URS Corporation
Total Metals Annlysis Data Sheet
Lab Nanre:
I,otlSDG Number:
IUatrix:
oh Molsture;
Bnsis:
Analysis Method:
Unlt:
QC Butch If):
MSD Sarnple Allquot:
MSD Dllution Fnctor:
STI, PFNVER
Ds1080243
WATEB
N/A
-Wc!
747LtPr
m&{,
s259437
1
Client Semple ID:
lvtsD l.ab Sarnplc ID:
MSD Lab WorkOrder:
Date/Tlnre Collected;
tlate/Time Recelved:
Date/Tlme Leached:
Dnte/Time Extracted:
Date/Time Analyzed:
lnstrument ID:
GW-Sl -090705
DJI080243-004D
HJ6JM
9e/07/0-s, 09;55
09/08105 09:30
09t23{05 12:50
09/23105 18: I8
0r9
Analytc Spike
Amount
Sanrple
Result
C II{SD
Result
C o/o Rec a RPt}0
QC Llmtts
o/o Rec RPD
Mercury (),00500 0.000044 Li 0.00365 71 N 3.3 85 - I 14 r0
STL Denver
Form 5A MSD Analysis Data Sheet Equivalent
a42
ffisrr
URS Corporatlon
I otnl Metals Analysls Datt Sheet
Lab Name:
LoUSDC Number:
Matrlx:
% tlloisture:
Basls:
Analysls Method:
[Jnlt:
QC Batch If):
MSD Surnple Allquot:
MSD Dilutlon Factor:
S.I'L DENYEB
t)5 r08(1243
\[IAFER
NiA
]&$I
60?Q
mgr'I.
5265172
50 mL
r_a
Cllent Snrnple ID:
MSD Lrb Semple ID:
MSD Lrb Work0rder:
Dnte/Tlme Collccted:
Dttef ime Received:
Drte/Tlme Leached:
Dnte/Time Extmcted:
Dnte/Tlme Anallzed:
Instrument ID:
GW-S t-01)070s
D51080243-004D
HJ6JM
09107i(t5 09:55
09/08i05 09:30
0et23l05_t t3.0,
a9n8/0s .(w;2
404
Antlyte Splke
Amount
Sample
Result
C MSt}
Result
C 7o Rec a RPD a
QC Llmits
7o Rec RPD
Cudrnium r).0400 0.0039 B 0.0,+30 98 2.0 89 - I r0 20
Seleniurn 0.0400 0.0tI B 0.05 r 4 100 7.5 82 - lr2 2A
STL Denver
Form 5A MSD Analvsis Duta Sheet Equivulent
743
ffisrl
URS Corporation
Total Metals Analvsis Data Sheet
I.,tb Name:STL.DENVER
Lot/SDC Number: D51p80243
Illatrlx: WATER
oh Molsturc: N/A
Brsis: Wst
Anulysls Method: 6020
Unit: mgll
Q(l Batch lD: 5265172
MS Sample Allquot: 50 mL
J\IS Dilutlon Factor: .lO
Cllent Semple ID: (ilM,:S I.-09U05
MS Lab Semple lD: D5108024I-004f,
IUS Lab tilork0rder: HJ6JM
Date/Tlmc Collectod: 09/07105 09:55
Drte/Tlme Recelved: 09108/05 09:30
DatelTlme Lenched:
Date/Tlme Extracted: 09/?3t(15 15;30
Date/Tlme Analyzed: 0qir8i05 02:29
Instrument ID: 404
Analyte
Splke
Amount
Sample
Result C
MS
Rcsult C
%
Rec 0 QC
Limit
Cadnriurn 0.04()0 0.0039 B 0.0421 96 89- lr0
Seleniurn 0.04.00 0.01 I B 0.0477 9I 82-lt2
STI Denver
Form 5A hIS Analvsis Data Sheet Eauivulent
744
STL DEIVYER
'fotal Metals Analvsis
-58-
POST DIGEST SPIKE SAI\IPLE RECOVERY
Contracts: IIRS Corryrorrtion
Lab Coda: ETI"DEN Caaa No.:Sa,S No. :sDo No. : D5I08A2L3
Matrix (;o1"1/water) t WATTR Leval (Iow/mod):
gntr[PLE NO.
Glr-sl- 09 07 0 5 PDS
Conecntntion Unltr r mg/L
.trnalytsc Contro]"
Li.mit ,ER
EpLkcd Saryrlc
RceuLtr (SSn1 C
Sarqp1c
Result (SR) C
spLkc
.lddad (8}')tR a M
Ca&ntura 175 E 125 o.L79732 0.000399 I B 0.20 89 .7 M
sal_entum I 75 L25 0 .190 515 o. oo112s I g 0.20 94.7 M
Conmcntg I
STL Denver Eorm v (PAntr 2) IN 745
msrt
IIRS Corporation
Total Metals Analysis Data Sheet
Lab Name:
LoUSDG Number;
Marix:
7" tltoisture:
Btsls:
Antlysig Method:
Unit:
QC Batch ID:
Sample Aliquot:
Dllutlon h'actor:
ST[, FFNVER
p5 rq80243
WATtrR
N1A
Wst
60t08
ms/I
526s761
50 m[.,
I
Cllent Sample ID:
Lab Sarnple ID:
Lab Workorder:
Date/Tlme Collected:
Date/'l'inre Received:
Date/Tlme Lerched:
Dste/Time Extractetl:
Drte/Time Analyzed:
Instrument ID:
D51220000-"61c
HK5OW
09/23l()5 08:00
$?/?3t05 T:a6
021
Analyte 'f rue Found ToRec a LImits
Alun'rinunr 2.00 200 100 86 - r08
Iron 1.00 0.9(A 96 88- lr0
Magnesiunr 50.0 49.s 99 9l III
Pottrssiurn 50.0 51.4 t03 86- ilr
Sodium s0.0 50.0 r00 9t - 112
Zirconium 0.500 0.5r9 r04 7s - 125
Calciurn s0.0 47 .l 95 fi9- II0
STL Denver
Form 7 LCS Analysis Dota Sheet Equivalent
1,1 6
ffisrt
UR,S Corporation
Total Mctds Analysis Data Sheet
Brsis:
Lab Namc:S'I'I, DENVER
LoUSDC Number: D.510802^13
Mstrlx: WAT,ER
7o Molsture: N/A
Yst
Annlysis Metlrod: qqL0R
Unit: r11g/t
QC Butch ID: 5265261
Sarnple Aliquot: 50 mt-,.
tlilutlon Factor: I
Cllent Snmple lD:
Lsb Samplc ID: D5 t220000-261C
Lrb Workorder: I{KSQW
Date/Tlme Collected:
Date/Tlme Recelved:
Date/Time Leached:
Date/Tlme Extracted: 09i23i05 08:00
Date/Tlme Analyzed: A9127105 W:L$
In$trurnent I D: 0I-0
Analyte True Found ToRec a I,lmlts
Arserric 2.00 r.89 95 89 - r09
L,eacl 0.500 0.486 97 9I Ilr
Bariurn 2.00 2,M t0z 93- I13
Nickel 0.500 0.487 97 90 - r r0
Silver 0.0s00 0.048e 98 85 - r 14
Vanadiurn 0.500 a.492 e8 88 - I 12
Zinc 0,500 0.464 93 8s - I l0
Chromiurn 0.200 0.r9s 9t{ri9 - I 12
Copptr 0.2s0 o.246 98 8(: - I l0
STL Denver
Form 7 LCS Anolysis Data Sheet Equivalent
747
ffi$TL
IIRS Corporatlon
Total Metds Andysis Data Sheet
Lnb Name:
I,otlSDG Number:
Matrix:
7o Moisture:
Bnsis:
Anrlysls Method:
Unit:
QC Bstch lD:
Snrnple Aliquot:
Dilutlon F--actor:
STL DF.NV.EB
ps[080243
WATER
IUA
Wct
7470A
mcl
5259437
I
Client Sarnple ID:
Lab Sample lD:
Lab \lbrkorder:
Drte/Time Collected:
Dute/Tlme Recelved:
Date/Tlme Leached:
Dnte/Ttme Extructed:
Dnte/-I' i nre A n rlyzed :
lnstrument [D:
p5r 160000437c
HKVPA
09i23105 l2:50
09i23/05 l8:08
(}l-g
Analyte True Found YoRcc a Limits
Mercur.y 0.0t)500 0.00s02 t00 85 - I 14
STL Denver
Form 7 LCS Analvsis Data Sheet Eouivalent
748
ffiSTL
URS Corporetion
Totnl Metals Analysis Data Sheet
Lab Nnme:
I,oUSDG Number:
Matrlxl
oh Molsture:
Basls:
Annlysis Method:
tlnlt:
QC Batch lD:
Sarnple Allquot:
Dilution Factor:
STL IXiNVER
p51080243
WATER
N/A
Yn
()o"o
u0slL
5265172
50 mL
I
Clieot Sample ID:
Lab Snmple ID:
l,ab WorkOrder:
Drte/'t'ime Collscted :
Date/Tlme Recelved:
Dete/Tlme Leached:
Dntc/Tlmc Extrsctcd:
Date/Timc Annlyzed:
Instrument ID:
{)$.r?20000- I 72c
HK49N
09121105 t53A
09i28/()5 02:00
gts
Anrlyte True Found o/oRec a Llmlts
Seleniurn 0.fi400 0.0352 88 rjz - I 12
Ctdrniurn 0.0400 0.0378 95 89 - 1 I0
STL Denver
Form 7 LCS Analysls Data Sheet Equlvalent
749
STL DETVYER
Total Metals Analysis
'9'
ICP SERIAL DILT]TIONS
Contrrct, r IIRB Corporatl-on
G[II-S1-090705 Srn
sDGt No. r D5I080243
L,evel (Iovr/ncd) r
Lab Cod.c r STLDEN
Matrix (rol1,/water) : UI^TER
Caac No, r
I nlurnl.num
Calcium H
Iron Lo
PotaBgl.rrm
Mrgracaium
ZirconLum
Conoantratlon Unitg:sg ll'
lniuiaL Beroplr
Rcrults (r)
8orl,r1 D:Llut,i.on
RrruIE (8 )
27 4.29 27 8.88
L26 .6-l 128. tg
1099.00 1091.50
0 .0 0426 0.00934
STL Denver
Forn IX IN
150
STL DENVER
Total Metals Analvsis
-9-
TCP SERIAL DTLUTIONS
Conbrect r IIRS CorTpratlon
SIMPITE NO.
GTr-91-090705 SER
sDc NO.: D5I080243
L,cwo]. ( low/mad.) ;Lo$[
Lab Codc: STITDEN Caec No.:g^l,g No. t
Matrl,x (sol.1/water) r WATER
Iemenie
BarJ.um
Chromium
Coppar
Lead
NLqlce].
Silver
Vanad,l.um
Ziuo
Concrntratrl"on Unitg: ng lL
0,0079 o - o22o Ju
rnl,t,ial- Errnpl.c
Regu1t (r)
Brr:[al. Dilutioa
ResuLt (g)
k
Dtffcr-
ence
0.00260 0 .01300
0 .0045 0.0225
0.o025 0,0130
o,0802 o.0927
0.00290 0 . 01110 0
0. 0 025 0 .0L25
STL Denver Iorrr IX IN
151
STL DENVER
Total Metals Analysis
-9-
TCP SERIAL DTLUTIONS
CoutraeE: tIRS Cor^poration
g}IiTPIfi NO.
GTr-91-09070s sER
SDc NO,: D5I08AZ[3
Lrvrl (],ow/uted) : tOIrI
relc Coda I STLDEN Cage No, :
Mntrtx ,ro*ffi wlr*R
SIf,g No. r
Concentrntlon Unltt t tagll-
.Lrralytc
rnitia]- Sarnple
RcauLt ( f )
c
ScrLrl DilutLon
Rcou1t (8)
c
t
Differ-
cncG
0 M
I Cadmlurn o,0003981 B 0.000{1{5.?ll !{
Sclanl-urn o. oo1125l B o. oox,550 Ju 1Oo, o l M
STL Denver
Porm fX r IN
L52
STL DEIVVER
Total Metals Analysis
_10-
[I[]'I'H OD DIr'f ECTION LII'I ITS
Coutraet: URS Corporat j-on
Lab Codci SfLDtlI Cage No,:
fCP fD Nrrnrber 3 TJl, Int repl-d f CP
flama Al ID Ntrmbcr I
Frrrrrrce IA fD l[\rmbcr r
8Ag No. r
Date: 5 ILAlz00s
gDc NO, : D5I08 0243
.[na1f't'c
WavG-
lcngth
(nn)
Brck-
ground PQL
(nn/L)
MDL
( utgl r. )
!{
ALunl.num t 167 .0 0.10 I o.017 P
A1 Dum Il 349 .2 1.0 P
Caloiuro L 3L7,933 o.20 0.03{P
CaLclum H 319. 1 10 P
Iron lro 259.9 0.10 I o. o21 P
Iron Hi 27 L .[tLL 1.0 p
Potarriun 766.491 3,0 4.24 P
Itq"grr""iurn 27 9. 078 0.20 0-0{3 P
Sodium Lo 589.5 1,0 0.031 P
Sodiurn Hi 818 .3 x0 1.1 P
ZLre,onium 339.1 0.0050 o,0015 P
Commcntg I
STL Denver Form X IN 153
STL DENVER
'I'otal Metals Analysis
-10-
IVIETHOD DETECTION LIMITS
CoatraoEs tRg eorr)oratlon
L,sb Code 3 STLDEN BLS l{o, :
IcP ID lfirmber: SUPEBTRACE Dater 5 lI0 l200s
flaroc AA ID Nurbrr r
Ftrrnacs AA fD Bhrrnbcr r
SDc Dlo.; D5f080243
rnal.yta
WavG-
Icngtb
(nm)
Back-
ground PQI,
(mg/L)
IITDI,
(mglt )
M
.trraenic 189.O42 o.010 I 0. o0{{P
Barium {93.409 0.010 0.00070 P
Ctrrornlrrm 267 .7 L6 10 I 0.0 026 P
Coppcr 321 .7 53 0,010 o,00{5 P
Iread 220-353 0.0050 I 0.0026 P
NiokaI 23L.60d 0,040 o - 0012 P
Eilvrrr 329. 0 6g 0-o.oazg P
Vanrdlrrrn 292 .442 o. 010 0.0025 P
ZInc 06.200 0.020 I o-o0{5 P
olulatrts:
STL Denver Foz:nr X IN 154
STL DEIVVER
Total lVletals Analysis
-10-
NI EI'HOD DETECTION LIIVIITS
Contractr URS Corfroretion
Lrb Codcr SfLDEN Caac No. r
ICP ID lfirnbe r:
flamt A.tt ID Nunbor: pE ClIL1
nrrnaca .LL ID Nurubcr I
gl,8 No. l
Drrrr 1LlLT/2004
SDO NO. r D5I0802{3
AnaI.ytc
$Ilve-
Iongtlr
(nm)
Brck-
grouad PQL
(ms /I'l
MDL
(mg/L)Itt
fC1rry 253 .7 A 0 - o00?o 0.0000811 cv
Comme[Ea:
STL Denver fora X - IN 155
STL DENVER
I'otal Metals Analysis
-r0-
ME'I'HOD DETECTTON LIMITS
ConEraot r IIRS Corporation
Lsb Codt: STT DEN
ICP ID Nusrbcr I PE ICPMS
F]-arnc AI, ID lftrmbcr r
hrrnace A.f, ID tilumbcr r
Cagc No. t g.[s No,:
Datcr 5lL0 12005
sDG No. r D5I080213
Analyt,o
frotope Back-
ground PQT,
(ng/r.)
I,IDTJ
(mg/r.)DT
Cadraiuru 111 0,0010 0.0000{10 Ir{
Sclcniuro 82 0,0050 0.00033 M
Conunentr r
STL Denver
Fom X fN 156
STL DE]VYER
Total Metals Anehsis
.IIA.
I CP I NTERELEMENT CORRf, CTION TACTORS (ANN UA LLY)
CoBtract: IIRS Co:rooratLon
Leb Coda3 STITDEN Caaa No.3
rntrapl-d rgPICP ID ![urnbar: ll'in,
SAg No.:
Dator 8 /Lgl?OAs
SDg NO. r D5I08A24?
Analtt,c
Ulava-
length
(nm)A1
rnterelsnent CorectLon tractort
Ca Fe
for:
Mgr Ag
I 339. r98 0. 0000000 J 0,0000000 0.0000000f o.oooooooI 0.00ooooo
tlrrminum lL67, 081 o. ooooooo [ 0. oo00o00 o. o0182ool o.0o0oooo I 0.0000000
Alumlnum 1309.27L o.ooooooo J 0.0000000 o.oooooool 0.0oo77to I 0.0000000
.f,ntimoay IaOe.838 0. 0000000 J 0.0000000 0.00000001 0.oooooool 0.000oooo
Araanie ll8g.Alz 0.00000001 0r0000000 o,o00o0o0J 0,00000001 o.ooooooo
BarLum | 455.403 0.0000000 I o. o0o000o 0.ooo0o00l 0.00000001 0.ooo0ooo
Berry,llium If rf .A4Z o. ooo0o00 | 0.0000000 0. oooooool o, ooooooo l 0. o0o0ooo
Boron 1249.6z8 0.0000000 I o-ooooo0o o. ooooooo I o. ooooooo I 0 .0000000
cadml-urn |.225 . s02 o-oooooooI 0.0000000 0.00004201 0,0000000 I o.oooooo0
CalcLum I Srz.933 0.0000000 I o.000o0oo o. oooooool 0.0000320 I o. oooooo0
calcirrm I 31B.1AB 0.0000000 I o. 0000000 0.oo0o0o0l 0.0000000 I 0.00000001
clrroml,um lzf: .TLG 0,0000000 I o. oooo0oo o. oooooo0l o. ooooooo I 0 .0000000\
cobalr lzza.615 0.0000000 I o_0000000 0 .00000001 o. ooooooo I 0.0000000
copper I fzl. T53 o. ooo0ooo l 0,0000000 -0.00002001 0.0000000J 0.0000000
rron I zs9.g{o o-0000000| 0.0000000 o.ooo0oool o.oooooool 0.0oo00oo
rron 127L.44L 0.0000000 | o.0ooo000 o.0oo0oo0l o-0020100I 0.0oo00oo
Lcad lt220.353 0.0000000 I o. ooooooo 0 - 0000000f 0.0000000 I o. ooooooo
rlthlurn I 520.28{o,0ooo000 l 0.0000550 0.oooooool 0,000ooool 0,0000000
Magneglum lz79.0?g 0.0000000| o-0000000 0.00060201 o. ooooooo I 0.00o0ooo
Manganoso lzsl.610 0.0000000 | o. ooo0ooo o.oooooo0J o.ooool50f o,ooooooo
Molybdcnum lzaz.030 o. oooo00o | 0.0000000 o.0oooooof o.0oooooo I 0.0000000
rrrLckel I ,r L.6ot t 2 0.0000000 I o.0ooo0oo o-oooooool o,ooooooo! o,ooooooo
phosphorus I fze .297 0.0000000 | 0.0000000 o.oooooooI o.oooooool o,o00oooo
PotassLrur lz as. d91 o. ooooooo I o.0000000 0.00000001 0.0ooooool 0.000oooo
Selenirrrn I tr6.09o 0.0000000 I 0,0000000 0.0000000J 0.00000001 o.oooooo0
strLcon I esf. Gla 0.0000000 | o. ooooooo 0.00000001 0.00000001 o-0oooooo
gt l Lcon fro1.G15 o.ooo0o00I o-0000000 o. oooooool o.0o00ooo I o. ooooooo
silvar I 328,069 0.0000000 [ o.0o0oooo o. ooooooof o. o00oo00 I 0.0000000
sodlum I rgg.592 0. oooooo0 I 0.0000000 0.00000001 0.00000001 0.o0o00oo
sodtrrn I At8.32G 0.0000000 | o. o0o00o0 o.oooooool o-oooooool 0,0000000
stront,ium I aOz .T'IL 0. 0000000 | 0.0001670 0.00000001 0.0000000 f 0,00000001
Thalll.um I rg0. g6l 0.0000000 I 0.0000000 o.oooo00o[ o.oo00o00f o.ooooooo
Porm XI (PARB 1)IN
Conunents:
STL Denve
STL DENVER
Total Metals Analvsis
-LlA-
r c p rNTER ELEM ENT C O RREC T r ON FAC TORS (ANI{UALLY)
Contract: IIRS Conooratl-on
Lab Codc 3 STITDEN
ICP rD lftrnbar: T,IA
cage No.,
rntrepLd rCP
SAS No- !
Dator 8 lLgllAAs
SDO NO, r D5f08A243
Tlrorlum I 283.730 o.ooooooo I 0-0000000 0.0008500J 0,00000001 o.ooooooo
Tln I 189.989 0 .0000000 I 0.0000000 o,00000001 0. ooooooo I 0. ooo0ooo
rltanLr.rm lael-gd1 0 .0000000 I -o. oooo320 o.ooooooof o.ooo02{0 I 0.0000000
uranLum J 385. gs8 o-oo0o0o0 I -0.0001020 -0.00085a01 0.00000001 0.0000000
vanadlurn lrg2 . Lo2 0.0000000 I 0.0000000 0.00010101 -0.0000130 I 0.0000000
zlne I zre. g56 0.0000130 | o.0o0oooo o - oooo5gol o. oooooo0 [ 0.0000000
Commsutg:
STL Denve
Fom, Xr (PI,RT 1)EIN
158
STL DENVER
Contraet,: IIRS Cor:ooratLon
Total Metnls Analvsis
-llB-
I(: P INTEREI.,EMEI{T C ORREC TI ON FA CT ORS (ANN UA LLY)
Cage No. t SAg No.3 gDg NO. : D5I08A243Lab Code 3 S"31TDEN
rCE rD number: TJA Intrepid Iep Datc: I l1,9l2OA5
Jtnalft,e
Wavc-
langrth
(nm)As
Interolemeret Corractlon Factorr
BBa
for r
Be cd
1339.198 0.0000000 | o-00o00oo o-oooooool 0,0000000I o-ooooooo
rluminum I 167,081 0.0000000 I o. ooooooo o.oooooool o.0000oool 0,0000000
llnsrinrun laOg.z71:0 .0000000 I o. ooooooo o. oooooool o.000oooo f 0,0000000
entLmony I 205.838 0.0000000 J o.0000000 0.00000001- 0.00000001 0.0000000
rrgenlc I 189.042 0.0000000 ! o-0000000 o - oooo0oof o. ooooooo J 0. 0000000
BarLum I ur5. {03 0.0000000 I 0.0000000 o. ooooooof o.0o0oooo I o. ooo0ooo
Ber:,lltum I gt3.0{2 o. ooo0o0o | 0.0000000 o.00o0oool o.ooo0o0ol o-oo0oooo
Boron 1249.6?8 0.0000000 | 0,0000000 0.00000001 o.ooooooof 0.0000000
Cadnium ]226.502 o.0o0oooo J 0.0000000 o . ooooooo J o. ooooooo J o. o00ooo0
calcium I arz. 933 o-oooooool 0.0000000 0.0000000[ o, ooooooo l 0.0000000
calclutrl f ara -L2g 0.0000000 | o.0o0o0o0 o. o000o0ol 0.0000000 ] 0.00000oo1
chroruLum
1 267 .7t6 0. 0000000 | o. o0o0o0o o.oooooool o.oooooool o.ooooooN
cobalr |1228.516 o. oooo000 I 0.0000000 o.oooooool o.oooooool o-ooooooo
coDper I 32{. Ts3 0.00ooooo I o.000oo0o o - 0oooooo | 0.0000000 I o. 0000000
rron | 259.9t0 0,0000000 J 0.0000000 0.0000000f o. ooooooo I 0.0000000
rroD lr, t .1t{1 0.0000000 I 0.0000000 0.00000001 0.o0oooool o,oooo0oo
r,ead lzzo.353 0.0000000 I o. oo0o000 0. oo000ool o. ooooooo I 0.0000000
r,Lrbium lG7 o. zB{0.00oo0oo | 0.0000000 o-o00o0o0l o-oooooooI 0.0000000
Magnesiurn 127 9.029 0.0000000 I o. ooo0o00 o . ooooooo l o, ooooooo l o. ooooooo
Mangrancrc lzsz. 610 0.0000000 I o. ooo00oo o. oooooooJ o. ooo0000 I o. ooooooo
rtlolybdcnum 1202.030 0.0000000 | o-0000000 0.00000001 0.00000001 0,0000000
xl.ckcl ln 1. 6 as t2 0.0000000 I 0.0000000 o.oooooool o-oooooool o.ooooooo
phorphorus
l7-z 8 .287 0.0000000 f o, o0oo000 0.0000000J o, ooooooo l 0.0000000
Potasgiurn lrS5.{91 0.0000000 I 0.0000000 o. oooo0oo ! o. ooooooo I o. ooo0oo0
sotanLur I 195.090 0,0000000 I 0.0000000 o. ooooooof o. ooo0ooo I o. 0000000
silicoa I ,u L.6L2 0.0000000 I o .0000000 o.oooooool o.oooooool o.ooooooo
stlicon I ,U1.61s o-0000000 I 0.0000000 o. ooooooo I o. ooooooo I o. ooooooo
sllver 1329.069 0.0000000 | o.0oooooo o. oooooool o. ooooooo I o. ooooooo
sodtun I se9.592 0 .0000000 I o. ooooooo o.oooooool o.oooooool o.ooooooo
Sodlum I ArB.32E 0 . 0000000 1 o. oo00o00 o. oooooool o. ooooooo I o. ooooooo
Strontium I oO7 .77L o. ooooooo I o.0ooo0o0 0.00000001 o.oooooool o'0ooooo!
Thallium I rg0. g5{0.0000000 I 0.0000000 0,00000001 0.00000001 o.ooo0ooo
Conunentr:
STL Denve
Form XI (PLRT 2l - IN
159
STL DENVER
Total Metals Analvsis
-l lB-
tcP TNTERf, LEMENT C O RREC TION FA CTORS (ANN LIA LLY)
Contraet t
r,ab Code s SSLDEN Case No. :gAg No.3
rCP rD NUmber: TifA fntrepid ICp Data: I lLg 12A05
gDc NO.: D5I08AZL3
Thorlum I 283.730 0,0000000 I 0.0000000 o.ooooOoo[roooo I o.ooooooo
rin I rg9.9a9 0.0000000 | 0.0000000 o.oooooool o.0oo00ool 0.0000000
rLranium I 33d.9{1 0.0000000 | o-0000000 o. ooooooo I o. ooooo00 | o.0oooooo
uranlu:n I 3S5. g5g 0 .0000000 I 0.0000000 o.ooooooo! o.oooooool o.ooooooo
vanadiun l rg?-{Az 0.0o0ooo0 | 0.0000000 o. oooooool o. ooooooo J o. ooooooo
zLnc I zra. Bs6 0.0000000 I 0.0000000 o, oooooooJ o. ooooooo I o. ooooooo
Conunentg i
STL Denve
Fom XI (PIRT 2l .IN
50
STL DENYER
Tot&l Metals Analvsis
-1lB-
ICP INTERELf,MENT CORRECTION FACTOR.S (AI\I\ruALLY)
CoBtsracts [rRS eorooration
Lab Codc I STITDEN Cage No. t gAS No,:
ICP ID ltunber: TifA latreDLd ICp Dater 8lL9 l?005
SDc NO. r D5fO8OZl3
Anallt c
Wave-
lencrth
(nm)
fntorolornant Corrcctl,on Factorg
Cr eu
for t
KCo Mn
I 339 - 198 0,0000000 I -0.0012800 o. o0o0o00l 0.0000000 I 0. o0o0oo0
llrrntnurn IfOZ.081.0.0000000 I 0.0000000 o.0ooooool 0.0000000 I o. ooooooo
l.luminutrl IgO9.27L 0.0000000 ! o.0o00ooo o. oooooool 0,0000000 1 o, ooooooo
AntLrpnl. I ro6. B3B o, o00oo00 I 0.0000000 0.00000001 0. ooooooo I o, o0oo000
lrsenLc I 1Bg.0{2 0. ooooooo | 0.0000000 0.00000001 o.ooooo00l 0.0000000
Barium I os5.403 0.00ooooo I 0.0000000 o. ooooooof o. oooo0oo J 0.0000000
Bartrllium Iafe .o42 0.0000000 | o. 00ooo0o o. oooooool o. ooo0000 I 0.0000000
Boron lzt9.678 0.0000000f o.00o0o0o o. oooooool o.0ooo0oo f 0,0000000
Cadmlum |,226. 502 0.0000000 | 0.0000000 o.oooooool 0.oo00ooof o,o0ooooo
calcium
J arz.933 0. ooooooo I 0. 0oooo00 0. ooo0oool o. ooooooo I 0.0000000
CaleLum I rra.12B 0.0000000 | 0.0000000 0.00000001 0.0000000 I 0. ooooool
Chrondum lzil. 216 0.0000000 I 0.0000000 0.00000001 o.oooooool 0.0000720\
cobalt 1228.515 o. oooo000 I 0.0000000 0.00000001 o. ooooooo I o. ooooooo
copper I ael. z53 0. ooooooo I 0. o0o0o00 0.00000001 0.0000000 I o. ooooooo
rroa
J zrr. g{o o. oo0oo0o | 0.0000000 0.00000001 o. oooooo0 I 0. ooooooo
rron lr, f. llr 0.1300000 I o.0o0o0o0 0.0000000J o. ooooooo I o. ooooooo
Lead lzzO.353 o-0000000I 0.0000000 0.0000000f o. oo0oooo I 0. o0o00oo
r,tthtum I 610.7Bc 0.0000000 I o. ooooo0o 0.00000001 0. ooooooo I 0. 0000000
Magnesium |,27 9.0?9 0. 0000000 I o. ooooo0o 0.00000001 0-0000000I -0.003s590
Manganese lZSl.610 0. 0oooo0o I 0.0000000 0.00000001 0.00000001 o-ooooo0o
Molybd,onurn l ZOS - 03 0 0.0000000 J 0.0000000 o - ooooooof o.000oo0o | 0.0000000
Nickcl I rrl.6 attz 0.0000000 I o. o0ooooo o. oooooool o. ooooooo J o. ooooooo
rtronphorur IfrB.zg7 0.0000000 I o.0oo0ooo o.oooooooJ o.oooooool 0.o0o0ooo
Potarslum l, e6. {91 0,00000001 o.ooo0o0o o.000o0oof o, o00o0o0 l o. ooooooo
selonlum I fr6.090 0.0000000 I 0.0000000 0, oooooooJ 0,0000000 f o. o0oo0oo
stricon I ,sl.61 2 0.0000000 | 0,0000000 0.00000001 o.ooooo00l 0.oooooo0
stlicon
I
zsr.61s 0.0000000 [ 0.0000000 o. 00o00oo
I
o. 0000000 | o.0oooo0o
Silver I arB. o6a 0.0000000 | o.00ooooo o. ooooooof o. o00o0o0 | o.00oo0oo
sodiun I ut9. s9a o. ooooo0o I o.000oo0o 0.ooooooof o. ooo0ooo I o. ooooooo
sodtrJln I ara.325 o. oooo000 I 0. 0000000 0.00000001 0.0000000 I 0.00000001
Strontlum f aOi .z'tl 0,0000000 I o. ooo0oo0 0.00000001 0.0000000 | 0.0000000I
Thalllurn I tgO-96{0. ooo0o00 | 0,0000000 o.0ooooool 0. o0ooooo I o. ooooooo
Fonn XI ( PIRT 2l I I}I
Cortunorltg:
STL Denve
STZ DENVER
contrract: Mi.on--.*
l,ab code 3 STTJDEIU Cage No. :gfg No. t
IeP ID !flrrnbcr: 1I,iIA Intrepid ICp
Total Metals Analvsis
-1lB-
IC P INTERELEMENT C ORREC TION FA CTORS (A NNUA LLY)
Dato: 8/L9/zAAs
sDc NO.: D5f08A2l3
Thorium I 283.730 0-0000000 J 0-0000000 0.00000001 0.0000000 I o. ooooooo
rln [189.989 o. o0ooooo | 0.0000000 o.o000oool 0.00000001 0.ooooooo
rltanLum I 33{.9{1 0. 0000000 I o. 0003 150 0.oo0ooool o.ooooooof o.o0ooooo
uranlum I 385.9s8 0-0000000 ! o.o0ooooo o.oooooool 0.0000000f 0.0oo0o0o
varradium lZSz . $02 o. oooooo0 I 0,0002290 o. oooooool o. oooo0oo I 0.0000000
zlnc I arr.B56 0.0000000 | 0.0000000 0.000911{01 0.0000000 I 0.0000000
Comments:
STL Denve
Fomt XI (Pent 2)_rN
L62
STL DENVER
Total Metals Analvsis
-ltB-
rcp TNTERELEMENT CORRECTTON TACTORS (ANNUALLY)
eoatract! IIRS Cor:ooration
Lab Coder S1LDEN Cage No. 3
Intrepl-d ICPICP ID NUIIlbgr 3 T.IA
8lg No, !
Data: I ll,glz00s
SDc NO-: D5I08AZt3
trnalltte
Wave-
laugth
(ntrt)
Interclcmant Corcctlon factore
Na Nt
for g
Pb gbMo
I gs9 - 198 0 - 0009000 I o. o0o0o00 o - oooooool 0. ooooooo I 0. ooooooo
Alumtnum Ife2.081 0.0000000 | o .0000000 o. oooooool 0.0000000 | o. ooooooo
Aluminrrn 1309.27L 0.0000000 I 0.0000000 o. oooooool 0. 00o00oo I o, ooooooo
rnt l.rnony | ,06 . 83I 0.0000000 | o-0o0o0oo o.ooooooo[ o.oo0ooo0l o.0o0oooo
rrsonle I l8g .OA2 0.0000000 I 0.0000000 o. oooooool 0.0000000 I 0.0000000
BarLrrn I 4SE. {03 0.0000000 J o. o0o0oo0 o. oooooooJ o. oooo00o I o. o0oo00o
Bery11Lum I313 .A4Z 0.0000000 | o. ooooooo o. oo0ooool o . oooo0oo l o. o0 ooo0o
Boron lzt9.67a 0.0000000 | o .0000000 0.0000000J o-oooooooI o.o00oo00
Cadnlum Jrr6 .502 o. o00oo0o I 0.0000000 -0.00019701 0.0000000 I 0.0000000
calcium Jffz.933 o.0000000 | 0.0000000 o. ooo000o! o. ooooooo I o. ooooooo
Calclum I sre.128 o.0oo0ooo | 0.0000000 0.00000001 0.0000000 I 0.00000001
Chromtum lz6l-.tLG o.0000000| o-0000000 0. oo0o000l o . oooooo0 I o. oo00ooo\
cobalr l|228.616 0.0oooooo I 0.0000000 0.00000001 0.ooooooo I o-ooooooo
copper | 324 .Ts3 0.0003{00 | 0,0000000 o. oooooool 0. 00ooooo I o - ooooooo
rron I ,rg.9ro 0. 0000000 I o. o0ooooo o. o0ooo0ol 0 ,0000000 1 o. ooooooo
rron 127 1. {{L 0.60L5000 I 0.0000000 0.0ooo0ool o.oo0o0oof o,ooooooo
read, |.220.353 0. 0000000 ! 0.0000000 o, oooooool o. ooooooo J o. ooooooo
rirhium I uro. TBc 0.00ooooo I o. 0000000 o. o0oo0o0f o. ooooooo I 0.0000000
Magnesium 1279.029 -o-0358000 I o.0000000 o. o00o00ol o. ooooooo I o, ooooooo
Mangarl€66 lzst, Gto 0.0000000 J o. ooooooo o. oooooool o. ooooooo I o. ooooooo
Molybdcnum 1202- 030 o.00ooooo I 0.0000000 o.0o03aool o.oooooool 0.0000000
rsiekal lra1.60tt2 0.00o0ooo I o. ooooooo o.oooooool o.oooooool o.ooooooo
Pbosphorur ll1rg.287 0.0000000 [ o .0oo0ooo 0.00000001 o.oooooool 0.0000000
Potsagrium I ?56. {91 0.0000000 I o. ooo000o o. oooooool o . ooooooo l o. ooooooo
Selenlum I 196.090 0.0000000 I o. ooooooo o,o0oo00ol o.oooo0ool 0.0000000
stlicon I zSr.612 0.0092000 I o .0000000 0.00000001 o,0o0o0ooJ o.ooooooo
stlicon
I
zsr. 51s 0.0 a9?,000 I 0.0000000 o. ooooooo
I
o. o0ooo0o I o, o0o000o
silver I le8.05B 0.0000000 | o.000oooo o. oooooool o. oooo0o0 I 0. ooooooo
sodium Iuti.5gz 0.oooooooI o-0000000 o. ooooooo I 0.0000000 | o. 0oo0ooo
sodtum
1 818.326 0.0000000 I o. ooo0ooo o. oo0ooool o. oooo00o I o. ooooooo
stronttum I aoz .lii 0.0000000 I o.0o000oo o.o0oo0o0l o.oooo00ol 0.o00ooo0
Thal-ll.um I f g0.g6{0.0000000 I 0.0000000 o.oooooool o.oooooo0 | o.ooooooo
Cormrent,g:
STL Denve
Forrn XI ( Panf 2l IN
153
STL DENVER
Total Metnls Analvsis
-[lB-
ICP INTEREI,EMENT CORRECTION FACTORS (ANNUA LLY)
Contraet: IIRS Corroorat'Lon
Lab Code3 S1.LDEN
IcP ID [Itrmber: TJA
Cage No. r
Intrepid ICP
gAg No. :
Deto: I lLg l?AAs
gDc Ho. : D5I080243
Tlrorlurn
J
283.730 0.0000000 I 0.0000000 0.00000001 0.0000000I o-ooooooo
rl-n l1B9-989 0.0000000 I o. ooo0000 o-oooooooI o.ooooooo| 0.0000000
rl,Eanirrm I 33{.9{1 0 .0000000 I o. 0000000 o. oooooool o. oo0ooo0 | o. ooo0ooo
uranLum l fe5.95B 0. o0ooooo | 0.0000000 o. oooooool o. ooooooo I o. ooooooo
vanadLuxr lZlZ.4Az -0. aL7 5ooo I 0. oo000oo 0.00000001 0.oo0ooooI o-oooooo0
zr.nc I zrr. g56 0.0000000 I 0.0000000 o.0063800l o,oooooooI 0.0000000
corrunonts:
STL Denve
Fomt XI (PART ?,1 IIN
L54
STL DENVER
Total Metals Analvsis
-I IB-
ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY)
Contraet : IIRS Corrooration
rab Codc: gTfrUEN
ICP rD lltrmbcr: TJA
Case No. t
Intrepid ICP
gAg No. t
Date: I llgl2OO5
sDtr NO.: D5I08A243
Wavc-
length
(nn)
Intarcl0rnant correction ractorS for r
SrAnahttast 1rl,Se Sn
I 339.19a o.0000000 I o. ooooo0o o. ooooooof o. ooooooo I o. ooooooo
llrrntnurn I f ez.081 0.0000000 | 0.0000000 o. ooooooof o. ooooooo I o. ooooooo
elumlnuur l309.zTL o. oo0oooo | 0.0000000 0.00000001 o.oooooooI o-ooo0ooo
Antlnnony I 20E. B3B 0.0000000 I 0.0000000 o. oooooool o. ooooooo I o - ooooooo
Arseal.c I 189.0{a o-oooo000 | 0.0000000 0. ooooooof o. oo0ooo0 l o, ooooooo
BarLun l Ou5.{03 0.0000000 | 0.0000000 0.00000001 0.0000000 I -0,0001930
Bartrlltum I 313 .Otz 0. ooooo00 I 0.00ooooo o. oooooool 0 -0000000 1 0. o00oooo
Boron I aog.628 0,0000000 I o.00o0ooo 0.00000001 o. ooooooo I o. oo00ooo
ca&rrium 1116.5O2 0. ooooo00 | o. 0000000 o.oooooooI o.0oo0oo0J o.00ooooo
calcirrrn I f f2.933 0.0o0o0oo I o. o000ooo o.oooooo0l o.oo000o0l o.oo0oooo
calcilxn Jrra.128 0.000oooo I o. 0000000 o.ooooooof o.ooooooo] o.oooooral
Clrrourlum lZ67 -7L6 o. ooooo00 I 0.0000000 o.oooooool o.oooooooI o.ooLzaoo\
cobalt l!228.616 0.0000000| o-0oooooo o.oo0o000l 0.0000000 1 o-ool8ooo
copper I gr tL.753 0.0000000 I 0.0000000 o.0ooooool o. ooooooo I o. ooooooo
rron l%9.9{0 0.0000000 I o. ooo0o0o 0.00000001 o.oooooooI o-ooooooo
rron 127 L. d{l 0.0000000 I 0,0000000 o.ooooooot -- -o.ooooooof o-0000000
read lrr0,353 o.0o0o0o0 | o-0000000 o,oooooool o.oooooool o.ooooooo
Ltthtum I ero.784 0.0000000 ] 0.0000000 o.oooo0ool o.ooooooo I o.ooooooo
Magnneslum lrrg.o-tg o. ooooo00 | o. 0000000 o. oooooool o, oooo00o l o. ooooooo
Mansanege |en.610 0.0000000 I 0.0ooo00o 0,00000001 o.ooooooof o-ooooooo
rqolybdenum lzo2.030 o.0000000 [ o.0000ooo o . ooooooo J o. ooooooo I o, ooooooo
ulckol 123l.60{lz 0.0000000 I 0.0000000 o.oooooool o.ooooooof o.ooooooo
phorptror:ua )rr8.zE7 0.0oooooo I 0.0000000 o. oo0ooool 0.0000000 I 0.0o0oooo
PotasrLum I 766.{91 0.0000000 | o.000oooo o.oooooooI o.oooooooI o.ooooooo
selenLum I rg6.090 o-o00ooo0 | 0.0000000 o.ooooooo| o.oooooooI o.ooooooo
si ll-con IZSL . 6Lz 0.0000000 I o.00ooooo o.oooooool o.oooooool o.ooooooo
slricon I zu1.61s o . ooo00o0 I o. 0000000 0.0000000f o.oooo0ool o-ooooooo
Bllver I fr8. oGB o.0o0oooo I o,00ooo0o 0.00000001 - 0.o00ooooI o-00035{0
sodlum I ut9.59z 0.0000000 ] o. ooooo00 0.0ooooool 0.0000000 I 0.0000000
sodium I gr8.3aG o,00o0oo0 | 0.0000000 o.oooooool o.oooooooI o-ooooooo
stronttum I coZ ,?7!0.0000000 I 0.0000000 0 . 0000000 1 0,0000000 1 0. 00000001
rhalllum I fgO.gG{0.0000000 I 0.0000000 0.00oooool o.00ooo0oI o.ooooooo
Comnentr:
STL Denve
For:ur XI (PART 2).IN
155
STL DEIVVER
Totrl Metals Anrlysis
-rtB-
ICP INTERf,LEMENT CORRECTION FACTORS (ANNUAITT)
Contraetr ERS Corooration
LaI) Code r STLDEN
ICP ID !$rmlrar r |lilA
Cago No.:
fntrepid IeP
glS !UO. r
D&tc: I l1.gl2A05
sDc No.: D5I0802{3
Tlrorlum I 283.730 o. ooooooo I 0.0000000 0.00000001 0-00000001 o.ooooooo
rt n I tr9.999 0. 0ooooo0 I 0.0000000 o - 00000001 o.0o0o0oo I 0.0000000
rttanitrm Irr{.9{1 0.0000000 [ o.00oooo0 o.oooooool 0.0000000 I o.ooooooo
uranLurn [385.958 o .0000000 [ o. ooo0oo0 0. 0000000f o. ooooooo l o, oo0oooo
vanadl,rrn I ,tZ. {02 o. oooooo0 I 0.0000000 o.oooooool o.oooooooI o.ooo{1oo
zine I zrr. g55 0.0000000 I 0.0000000 0.00000001 o. ooooooo I o. o00oooo
Conmontg r
STL Denve
Fonn XI (PART 2l IN
L55
STL DENYER
Total Metals Analvsis
-118-
ICP INTERELEMENT CORRE(]TION FACTORS (ANN UAI.,LY)
Coutraet: IIRS Corrooratlon
Lab Coder S1.LDEN
rCP rD Ntrmbar: fifA
Cage No. :
Intrepid rCP
S.trS No. ,
Dater 8llg/2005
sDc NO.: D5I08OZL3
Wavo-
lcngrth(rul
rntorelement Corrcetlon Factoru for:
Zn
InaLrte ThT1Uv
I 339 ,1eg 0,0oooooo I 0.0000000 0-0000000-l o-oo0000oI 0.03L9000
.Lluml,nlm lfOZ.081 0.0000000 I 0.0000000 o. oooooool 0.0000000 I 0. oo0ooo0
^l,luminum. I 3Og ,27L 0.00ooooo I o. o0000oo 0,0000000[ o-oooooooI o.ooooooo
entl.stony I206.838 0.0000000 I o. ooooo00 0.0000000f o-oooooooI o.ooooooo
Arsenle I 189.0{2 o-oooooo0 | 0,0000000 o. oooooool o. ooooooo I o. ooooooo
Barlrrrn I 4S5. {03 0.0000000 I 0.0000000 o. o0oooool o. ooooooo I o. ooo3o3o
Ber71lium Ifff .0Az 0.00oooo0 | 0.0000000 0.00035901 0.0000000 I -0.0000100
Boron I 2t9.5zB 0. 0000000 | 0,0000000 o. oooooool o. oo0o0oo I o.0oooooo
Cadmlum |,116.502 0.0000000 I -0.00020?0 o. oooooool o. oo000oo I o. ooooooo
calcLum I ffz.933 0, ooooooo I o.00oo0oo o. ooo0oool 0.0000000 1 o, ooooooo
CaleLum J srA .7,28 0. 0000000 | o. oooo000 o. o00oo0ol 0.0000000 I 0. o5590ool
chromium lZez .'tLG 0.0000000 | 0.0007060 0.00000001 o-00000001 -0.0005970\
cobalr |118.616 o. 00o0o00 I 0.0000000 0.00000001 o. ooooooo I o. ooooooo
copger Jfzt-?53 0.0000000 | o .0009d20 o. ooo0000J o. ooooooo I o. oo232o0
rron I ,S9.900 0.0000000 | 0.0000000 o . ooooooo l o. oo00ooo f 0. ooooooo
rron lz7 1. {{1 0.0000000 [ 0.0000000 0.oooooo0l o.oo0o00oI o.0oo0oo0
r,ead 1220.353 0.0000000 I 0.0oooooo o - oooooool o. ooooooo I o. ooooooo
Ltthtum 1670. ?8{0.0000000 I 0.0000000 o. oooooool o. oo00o0o I o. o00ooo0
I'tagnoslwn |'2r 9.079 0.0ooooo0 I 0.0075600 0,00000001 0,0000000 I -0.041-8000
uanganara lzsl.610 0.0000000 | 0.00 oL22o -0.00016801 0.0000000 I 0.0000000
rlrolybdcnum 1202. 03 0 0.0000000 I -0.0007050 o. ooooooof o. ooooooo I o. oot75oo
nlckel Jrs1.6o4t2 0.0oo0ooo I o .0000000 o.oooooool o.oooooool o.ooooooo
plrosphoruE Itr8.287 0.0000000 | o.00oooo0 0, 0000000 I o. ooooooo I o. o0ooooo
Potarsium 1"66.491 0.000oooo | 0,0000000 0.0000000[ o. oo0oooo I o. ooooooo
gcleniurn lrg6.09o 0.0000000 I 0.0000000 o.oooooool o.0ooooo0I o-ooooooo
silicon lrSL.6Lz 0.0000000f 0,0000000 o. ooooooof o. ooooooo I o. ooooooo
sttl,con 12S1.515 0.0000000 | o. 0oooooo 0.00000001 o. oooooo0 | o. o0ooo0o
sLlver lrrg-068 0.0000000 I -0.0002200 -0.01{9oool o, ooooooo I o. ooo588o
sodiurn I ugg. sgz 0.0000000 [ 0.0000000 o. ooo00o0[ 0.0000000 1 0,0000000
sodlum I 4t8.325 o. oooooo0 I 0.0000000 o. oooo000l- 0. 0000000 I 0.0000000
Btrontium I AO7 .'t7t 0.0000000 | 0,0000000 0.00000001 0.0000000 I 0.0000000 I
rhalltum I r90.85{0.0000000 I 0.0000000 o.oooooool o.oooooooI o.ooooooo
Coilunents:
STL Denve
-INFom. XI (PAR:F 2l
1,57
STL DENVER
'fotal Metals Analr"sis
-LlB-
ICP INTERELEMENT C ORRECTION FACTORS (ANNUALLY)
Contract: IIRS Comoration
r.ab Codc 3 STITDEII
rCP rD tftrmber r TiIA
Care No. t
IntrepLd ICP
gAg No. r
Datc: 8 llg lz00s
gDo No. t D5I08OAL3
Tlrorl.urn I 283 .734 0.o00000o1 0.0155000 0.0oooo0ol 0.0000000 | o. ooooooo
Tin I tt9.9a9 o. 0000000 I 0. oooo0o0 0.oooooool o.oooooo0l o.ooooooo
,fitanlum
[ 330.9{1 0,00000001 o-0002850 o. o0oooool 0.0000000 I 0. ooooooo
uranLum l3Bs-gE8 o, ooooo00 I 0.0000000 o. ooo0oool o, o0o0ooo I -0.038?oo0
vanad,tr:rn |,292 . $Az 0.0000000 I -o. oo02 r2o 0.00000001 o. ooooooo I o. 0015600
zLnc [ 213,856 0.0000000 | 0.0000000 0-00000001 o.o0oo00of o.00ooo0o
Comnonts:
STL Denve
Fornr XI (PART e)IN
158
STL DENVER
Contract: IIRS CorncoratLon
Total Metals Analvsis
-llA-
T CP I NT ERELEIIIENT C ORREC TION FA C TORS (AhINUALLY )
Cage ![o. :g^S !Eo. 3
Date: 7 /2312005
r,ab code: sIltDEN
ICP rD !ftunbcr r SUPTRIERACE
gDO No. : D5I08OZ[3
J[nal:rte
Wave-
lengrLh
(nm)A1
Ioterelement, Corraetlon ractorg
Ca FE
for:
Drg Ag
tlrrminum I 308.215 0.0000000 I o.0oooooo 0.0001100f o.ooo0290l o.oo0o000
.n,nttmony I205.83I o.000ooooJ 0.0000000 o. oooo220l 0.0000000 1 0,0000000
rrgenLc I 189.042 0-0000000 I o.0000000 -0.0000160[ 0.0000000 I 0.0000000
Barium lug3,{o9 o.ooooooo I o.0000000 o.oooooool 0.000ooool 0.0000000
Bcryl1Lum I 313 .0t12 0.0000000 I o. 0000000 o. oooooool o. ooooooo I o. ooooooo
Boron I a{9.628 o-ooooooo I o.0000000 -0. oooo?ool o. ooooo0o I o. ooooooo
cadmiun 1225.502 0.0000000 I o.oooooo0 0,0001{1ol o,ooooo00l o-oooooo0
Calcium
1
319 -933 0. 0000550 | 0.0000000 0.0000000f o. ooooooo I o. ooooooo
Chrornlum I z6"t .7L6 0,0000000 | o. oooooo0 -0.00001001 0.0000000 I 0.0000000
cobalr 11228.615 0.0000000 I 0. 0000000 o. ooooooof o. ooooooo I o. ooooooo
copper I 32 tL .7 53 o. ooooooo | 0.0000000 -0-0o0ozs0f o-00000110 I o.0o00oo0l
rron lZrl-4{1 0. 0000000 | 0.0000000 o-oooooool 0.0003{001 o.ooooooo\
Laad 1220.3 lLl L o.0oo297o | 0.0000000 o. ooot3ool o. oooooSo J o. ooooooo
Lead |11220.3 5L/2 -0-000r.800 I o.0000000 o . o0o05oo l 0.0000100 1 o, oo0oooo
lracmagl,um lz7 g. ozB 0.0000000 | 0.0000000 0.00002?01 0.0ooooool 0.0oo0ooo
Mangraneso lZSt.610 o. ooooooo I 0.0000000 -0 - 00000601 o. 0000200 I 0.0000000
uolybdenunr I zOz. 030 o.0000000 I 0.0000000 -0 - ooooreol 0.0000000 I 0.0000000
lrlckal I 231. 5 0L 12 0.0000000 J 0.0000000 o. ooooooof o. ooooooo I o. ooooooo
salanLurn I 196.02L1L -0.0000030 J 0.0000000 o.oooo020l 0.ooooo{oJ o'oooooo0
Selcnl.r:ur I196-02L/2 0. oo0o0o0 | o.0000ooo -o,ooo1?Bol o,oooooool o-ooooooo
stlieon lrtE-1sB 0. o0oo0oo I o.0000000 o.oooooool o.oooooool o-ooooooo
silver l az8, 068 0.0000000 I 0.0000000 0.00oooool o.ooo0000 I o.ooo0o0o
strontltut I OrL.552 0.0000000 | o. ooooooo 0-00000001 o.00o0ooo] o'0oooooo
Thallium I 190,96{o. 0ooo0o0 | o.0000ooo o. 0000960l o. ooooooo I o.0oooooo
rhorlum loo1.91o 0.0000000 I -0.0ooo2so o, oooooool o. ooooooo I o. ooooooo
rin I 189.989 0.0000000 | o .0000000 o .000oooo I o. ooo0000 I o. 0000000
rLtanLun
I
,r{.9{L 0.0000000 I 0.0000000 0.00000001 o. oo0o2o0 I 0.0000000
uraniunr lf as.gSB o. ooooooo I -0 .00003 oo o. ooog6oo I o. ooootco I o. ooooooo
vanadiuar l292.a}z 0.0000000 I o-0000000 -0.0003{001 0.00000001 0.0000000
zinc I ,t3. BsG 0. 0000000 | 0.0000000 0.00000001 0"0000020] o.ooooo00
Fonn XI (PART 1)AIN
69
Cornnentg a
STL Denve
STL DENVER
Contraet r IIRS Corroorat,lon
Total Metals Analvsis
-IIB-
ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY)
Cage No.:g.Lg No.:
Dato t 7 l23l2AO5
Lab Coder Sff,DEN
rce ID Number: SUPERTRACE
SDO NO.: D5I080243
Wava-
lengtlr
(nm)
Intcrelamcnt Comecttoa Factors for:
Be
.f,nalll.te
CdAeBBa
rluntnrrn 1308.215 0.0000000 I 0.0000000 o.ooooooof 0.0000000J o.ooo0o00
tnrlmony I 206.839 o. oooooo0 J o. 0000000 0. o0o0oool o. ooooooo I o. ooooooo
.rrgenle I 189.042 0.0000000 J o. o0000oo 0.0oooo0ol 0. ooooooo I o.0o000oo
BarLum l Og3. {0g 0.0000000 | o. 0000000 o. oooooool 0. ooooooo I o. ooooo00
BeryJ.lLum | 313 .012 o, ooooooo I 0.0000000 0.00oooo0l 0.0000000f o.oooooo0
Boron 12A9.678 0.0000000 | o. o00oooo o. oooo00ol o. oooo000 I 0.0000000
cadmi.um 1116. S02 0.0000000 I o.0oooooo o. oooooool 0.0000000 I o. ooooooo
calelum 1319,933 0.0000000 I o. ooooooo o. oooooool o.0oooooo I 0.0000000
Chrornlum lz6;.7L6 0.0000000 I o. oo0oooo o. oooooool 0. o0o0ooo I 0.0000000
cobalr. I zzs. ere 0.0000000 | o. ooooooo -0.00120001 0. 0000000 I 0. 0000000
fonnar f rza ,zsrr 0.0000000 | o-ooooooo o.oooooool o-oooooool o.ooooooo
Trron 1271 , {{1 0.0000000 | o. ooooooo o. oooooool o. ooooooo I o. ooooooo
r,ead lzzo.3sl l]:0.0000000 I 0.0000000 0. ooo0o00l 0, ooo0o0o l 0.0000000
rread |t220.35L/2 0.0000000 | 0.0000000 o.ooooooof o.ooooooof o.ooooo00
MagrncrLum lZrg.0zB 0.0000000 I 0.0000000 o.0ooo0ool 0,0000000 1 o. ooooooo
MangranGae lzsl. 6r.o 0.0000000 | o.000oooo o. oooooool o. ooooooo I o. ooooooo
r'rolybdcnum I 202 , 03 0 0.0000000 I o. oooo00o o. oooooool o. ooooooo I o. ooooooo
Nlcke1 I 23 L.604 t2 0 .0000000 [ 0.0000000 0,00000001 o-oooooool o.ooooooo
salenl.rrrn Itg6.0zLlL 0.0000000 I 0.0000000 0.00000001 o. ooooooo I 0.0000000
selsnlrrm lrg5.02Lt2 0.0000000 I 0.0000000 o. o000oo0l o. ooo0000 I o. ooooooo
gtlLcon
I egg. 159 0.0000000 | o. ooooooo o. oooooool o. ooooooo I o. ooooooo
sllver lrrS-068 0.0000000 [ 0.0000000 o - ooooooo] o. ooooooo l o. ooooooo
Strontlum lOr1. 5Sz 0.0000000 | 0.0000000 o. ooo0oool 0,0000000 1 o. ooooooo
Tha1liun I tiO. ASa o. oo0ooo0 | 0.0000000 o. oooooooJ o - ooooooo I o. ooooooo
ThorLtm I OOl. gto o. ooooo0o I 0.0000000 o.oooooool o.oooooool o,ooooooo
rln I ta9.9a9 o. ooooooo I o. ooooooo o.oooooool o.oooooool o.ooooooo
titaniun
I
rr{. e{1 o. ooooooo I 0.0000000 0.00000001 o.oooooool o.ooooooo
uranl,um I,t5.t-g 0.0000000 I 0.0000000 o.oooooool o.oooooool o.ooooooo
vanadiunr 1292 , tLOz 0.0000000 | o. oo0oooo o. oooooool o. ooooooo I o. ooooooo
..zlnc Jzrr. g56 0.0000000 | 0 .0000000 o.oooooool o.oooooool 0.0000000
Fonn XI ( PARIP 2l rN
Cornrnents:
STL Denve
STI, DENVER
Contraet: IlRg Corcporat,ion
Total Metals Anatvsis
-1lB-
ICP I NT ER ELE,IVIENT C ORREC TION FA CTORS (ANNUA L LY)
Cage No, r SIS lilo. :
Datet 7l23lz$As
Lab Code: S1.1TDEN
ICP ID Dfirmlrar: $UPERTRACE
Dsr080243
lnalftc
Slave-
length
(nn)Co
Int,araluncnt Correctlon Factorg
Cr eu
for r
DIrr uo
rlrrminurr leOA .zl.f.0-0000000 I 0.0015000 0.00oooo0l o.ooooooo[ 0.0058500
Arrtimony I205.83I 0.0o0o0oo | 0.0038900 0.00000001 0.0000000 I -0. 00s5s00
Arsenlc I 189.002 0.0000000 | o.0oor.7oo o.0o00oool o.00oooo0l o'ooo31oo
Barlurn I {93. {09 0. 0000000 I o. ooooooo 0.0o00oool o, oo000oo l o.000o0oo
Berylllum | 313 .A42 0.0000000 I 0.0000000 o. oooo0ool o. ooooooo I o. ooooooo
Boron 1249.578 0. 0009800 | o. ooooo00 0.00000001 o.0ooooo0 | o. ooooooo
Cadmium 1225.502 -o. oooz2oo l 0,0000000 o. oooooool o.0000ooo [ 0.00o0ooo
caleLum l ftg,933 0.0000000 | o-0000000 o. oooooo0l o. oooooo0 I 0.0000000
cbromlum lrez .7L6 0,0000000 I o.0oooooo o. o0oooool o. ooo0o0o I -0.0001?00
cobalt, 1228.516 o. o0o0o00 I 0.0000000 o. oo00oo0l 0.000oooo I 0.0000000
copper I aze. zs3 o. ooooooo I 0.0000000 o - 00000001 0.0000000 | o. 00000 aal
rron 127 1. {{1 0,0885900 | 0.0030800 o - 00000001 o. ooooooo I o. ooooooN
Laad |1220.3 StlL -0.0020{?0 I 0. ooooooo 0,00000001 0.0000000 I -0 - 0009500
r,ead lzz0.35ll2 0. 0000000 | o.0oooo00 0. 00000001 0. 0000000 I - 0. 0002600
MasmesLurr ,27 9.078 o.0000000 | o.0ooo00o o, oooooo0l 0, 0000000 J o. o0000oo
Mangranoso |ZSI.610 o.00o00oo I 0.0000000 o. oooooool o. ooo0ooo I o. o0ooooo
Mohrbdenun I202.030 0.0000000 I o. oooo0o0 o. 000oo0of o. ooooooo I o. oooooo0
nri ckel l23r , 5 A{ l2 -0.0005200 I o, oooo000 0.000oooof o. oooo000 I 0.0000000
gelenium I 19 6 .AzL lL 0.0005000 I 0.0000000 o. ooooooofi o. ooo35oo I o. oo0oooo
gelsnium
I 19E. ozLlZ -o. 000rsoo I 0.0000000 0. 00ooooo I o. 0002200 | o. oo0o00o
silieon I 288,158 0.0000000 | o. ooo0000 0.00000001 0,0000000 I -0.00{31100
silvcr I ,r8.068 0.0ooo0oo I o-0000000 o.oooooool o.oooooool o.ooooooo
Btrontlum 11421.552 o. 0000000 [ 0.0000000 o. oooooool o. oo00oo0 | o. ooooooo
Thallium I 190.864 0.00L?1t?0 I 0.0002900 o-00000001 -o.0ot770al 0.0000000
Thorl.um l{01.910 0.0000000 I 0.0000000 0, o00o0o0f o. oo5o28o I o.0oo0ooo
rln I ra9.9a9 0. oo0oooo I 0.0000000 o. ooo00ool 0. o00oooo I o. ooooo0o
rl.tanlum
I
,r{. e{1 o. ooo0000
I
0. 0000000 o. oooooool o. ooooooo I o. ooooooo
uranium I
gg5.95g o.0oooooo I o. o0o?500 o.ooloooof o.oooooooI o.ooooooo
vanadium l2gz.{Oz 0. 0000000 I -0.0008700 o. oooo00ol 0.0000000 I o. ooooooo
ziae f zrr, Bs6 0 .0000000 I -0.0032900 0 .00000001 0,0000000 1 0.0000000/
Form xI (PART 2l TIN
Comnents:
STL Denve
STL DENVER
Contract: IIRS Corporation
Total Metals Analvsis
-llB-
IC P INTER.ELEMENT C ORRECTIO N FA C TO RS (A I{NUA LLY}
Cara No-:glg No. r
Dato: 7 l23l20As
Lab Code s STLDEN
ICP ID lhmber: SUPERTRACE
gDO NO. I D5I08O2l3
.nnalfrtg
Wave-
langth
(nm)![i
rntarolernerrt Corectlon ractors
Pb sb
for:
9e si
Alurrluurtr 1308.2L5 0 - 0000000 I o. o0ooooo o.oooooool 0.00000001 o.ooooooo
Antimony I 206.838 0.0000000 I o. ooooooo o. ooooooo I o. 00ooooo I 0.0000000
Arrenlc I 189 .A42 0.0000000 I 0.0000000 o.ooooooof o-oooooooI 0.000oooo
BarLum I 493.409 0.0000000 | 0.0000000 0.00000001 0.oooooool 0.0000000
Bcrrrllium I rra.0{3 0 - 0000000 I o. ooooooo o. oooooool 0.0000000 | o. ooooooo
Boron I 2{9.628 o. o0ooooo I 0.0000000 0.0000000f o.oooooool 0.0000000
cadgdum |.225. 502 0. 0000000 I 0.0000000 o. ooooooof o. ooooooo | 0.0000000
Calcium
1 319. 933 0.0000000 I o.ooooo00 0.ooooo0ol o.oo00o00l 0.ooooooo
chrorulum lzil .7L6 0.00ooooo | 0,0000000 o. ooooo0ol o. ooooooo I 0.0000000
cobalr 11228.616 0.00 a2770 I 0.0000000 o. o0o0oo0J o. oo0oo00 I 0.0000000
lcoppsr Isza,753 0,0000000 I o. oooooo0 o. oooooool 0,0000000 1 o. ooooooo
Trron lrr 1. dt1 0.0000000 I 0-0000000 o.oooooool 0.000ooool o-ooooooo
read lrzo.3 JL/l -o. oo01{00 I 0. 0000000 0.00000001 -0.000020a1 -0.000L020
read ll220,3stl2 0.00006{0 I 0.0000000 0. 00000001 -0.0001{00 I -0.0000370
Magrncgiutrr | 279.078 0,0000000 I 0.0000000 o. oooooool o. ooooooo I o. ooooooo
r{angranoEG Jzsz. 610 o . ooo0000 I 0. 00oo0oo 0.00000001 0.00000001 o.ooooooo
Mot.ybdcnurn lzoz.03o o.0000000 I 0. oo0o0o0 o-oooooooI 0.0000000| o-ooooooo
wtckel
1
231,6 04/2 0.0000000 I o. o0ooooo o. oooooool o, o0ooooo l 0 .0000000
SelenLum I 1gO. Oz LlL o. ooo0000 I 0.0000000 0.00000001 0-oooooooI o-0001000
sclanlum I 196 - 0z Llz 0.0000000 I 0.0000000 o.ooooooof 0.0000000| o-ooooooo
stll,con I288-tsa 0.0000000 I 0.0000000 0. ooooo0ol 0.0000000 I 0. ooooooo
gilver
I 329.059 o.ooooo0ol 0.0000000 0.0000000f o.oooooool 0.0000000
Strontirlm ll21 .552 0.0oooooo I 0.0000000 0.00000001 o. ooooooo I 0.0000000
rhalllun I 190.864 0.0000000 | 0,0000000 0,.00ooooo[ 0.0000000 I o.0000000
Thorium I 001.910 0,0000000 I -0. ooo{2oo o.oooooool o.oooooool o.ooooooo
rLn I rr9.9a9 0.0000000 I 0.0000000 0.o0o0o0ol 0.0000000f o,oooooo0
TLtaniurn lrr{.9{1 0. oooooo0 I o.0oc0oo0 o. ooooooof 0.0000000 I o. ooooooo
uranium I rAs. gSB 0. oooo0o0 | o.0000ooo o.oooooool o.000o0oof o.oooo000
vanadlurn lZlZ .4Oz o.00o0ooo I o. ooooooo o.oooooool 0.0000000 I o.ooooooo
zlnc I zrs. g56 0 - 0000000 | o. 0o0ooo0 o. oooo0o0l o. ooooooo I 0.0000000
Couunentr:
STL Denve
Form Xf (PART 2l -IN
a72
STL DENVER
Total Metals Analysis
-1lB-
ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY)
Contraet: URg CoImoration
I,ab Code: STLDEN Caae No. t grg No,:
fCP fD Number: ST PERIIRAC:E Datot 7 123/zAOs
8De No.: D5I08OZA3
Analfttrc
Wava-
length
(nm)Sn
Intarelement correctlon ractors
Sr Tt
for:
T1 U
r}umLnum
1 908.215 0.0o0o0oo I o. oo0oo00 0.00000001 0.0000000 I -0.001{000
Antl-urony I 206. B3B 0.0000000 I 0.0000000 0.oooooool o,oooooool 0.ooooooo
rrsen{e Il8g.OLz 0.0000000 I o. 0000000 o.oooooool o.oooooooI 0.0000000
Barlum I {93.409 o. oooooo0 | 0,0000000 0.ooooooof o.o000oool o.0000ooo
Beryllium f f ff .Atz -0.0000000 I o. oo00o0o 0.00000001 o.ooo000o[ 0.0000000
Boron 12{9.628 0.0000000 I 0,0000000 0.oo0oooo[ o.ooooo00J 0.0000000
Cadmtum lrZo.50z o. ooo0o00 | 0.0000000 o, oooooool 0.0000000 [ o .0000ooo
Calch.rm 13X9.933 o, ooo000o I o.00ooooo o.oooooool 0.oo00o0ol o.oo31ooo
ctrromium lzil.7L6 0.0000000 ] o-0000000 o. ooo000ol 0.0000000 1 0,0004100
cobalr 1228.616 0.0000000 I 0,0000000 0-0o2tl{00] 0.0000000 I 0.0000960
coppcr I 32{. ?53 0.0000000 I o. ooooooo 0.0000000J 0.0000000 I 0.00063o01
rron 12? 1.441 0.0000000 I o .0000000 0.0000000J 0.0000000 I -0.0a2{000\
Lead ,220 .3 }Ll L 0.0000000 | o.0000000 o.ooooo00l 0.0000000J 0-0010060
Lead lrro.3 sLl2 0.0000000 I o. ooooooo 0.0000000J 0. ooooooo I o. 00l{600
Magmaclum lrr g. oz8 0.0000000 I 0.0000000 0.00000001 0.0000000 I -0.0L40000
Mangan6r6 lzsl.610 0.0000000 I 0.00oo0oo 0.00000001 o. ooo0oo0 I 0.0001300
I'rol]rbdenum lzoz- 030 0.00000001 0.0000000 0.ooooooof 0.0000000 I -0.0002100
NLckal
1
23 1.5 0L12 0.0000000 | o. ooo00o0 o. ooo0000 I -0 . 00oe{00 [ 0.0000000
selenium I 196.02LtL 0. oooo0o0 | o. 0000000 0,0000000J o.oooooooJ 0.oooo8oo
srrlcnlum I 196 .02 Ltz 0. oo00o0o I o.0000000 o. oooooooJ o. ooooooo I o. ooooooo
fttllcon I agB.158 0.0312600 I 0.0000000 o. ooeaoool o.000oooo I o. ooo8{oo
st1v8r I 328,058 0,0000000 | 0.0000000 o. oooooool o . oo00o00 J o. 00093 oo
sErontiusr I o, L.i52 0. 0000000 | o. ooooooo 0.00000001 0.oooooo0l o.ooocooo
rhalllum I190.86{0.0000000 I o .0000000 0.0o0ooool o. oo0oo00 I o. ooooo00
Thorlum I 001.910 o. 0000000 I 0.0000000 o. ooooooof o. ooooooo I o .oa233oo
Ttn I 199.989 0.0000000 [ o-0000000 o.oo0o000l o.0o0oo00l o.ooooooo
rl,tanlrrm Irr{.9{1 0,0000000 | 0. ooo0000 0.00000001 o.oooooool 0.0003000
uranium I
gt5.95B o. ooooooo I o.00o00oo o.oooooool o.oooooool o.ooooooo
vaned{um lzsz.4O2 o. ooooooo I 0.0000000 0.0ooez00] 0.0000000 I -0.0000500
ztnc I zrs, gs6 0.0000000 | 0.0000000 o,ooooooof o. o00oooo I o.0000ooo
Form xI (PART 2l -IN
Comrrentg:
STL Denve
STL DEIYVER
Contract: IIRS Comoration
Total Metals Analvsis
,LlB-
ICP INTERELEI\TTNT CORRECTION FACTORS (A N NUATLY)
Caac No.:SAS No.:
Pate t 7 l23l2AAs
Lab Code s SIITDEN
rCP rD sumberr SgpERTnB.eE
gDG NO.: D5f08AZl3
glavo-
length
(nm)
Int,crclement CorrcctLon ractorg for :
.trnalttc nhvZn
Alumlnurtr 1308.215 o.02L6700 I 0.0000000 o . 0505 1oo I
AntI-mony 1U06.838 0.0000000 J 0.0000000 o . ooooo0o I
rrsenie I l8g,Atz 0.0oooooo J 0.0000000 o . oo0oooo I
Barlurn I Or3. {09 o-0000000 I 0.0000000 o . ooooooo I
Bcrl'lltum I 313 .OtLz 0.0001800 | 0.0000000 o.o000oool
Boron l2t9. oz8 0.0000000 | o.0000000 0 - oooo2o0 I
ca&rir-rm 1226. 502 0. 0000000 | o. 0o0o00o 0.00ooooo I
calel-u:n IfrS.g33 0.0000000 I 0.0000000 -0.001?7001
chromlum lrgl.7LG 0.0000000 I o_0000000 o. o0ooooo I
coba]"t 11228.615 0.0000000 I 0.0000000 o. ooooooo I
fonoer I rzn .rsl 0.0000000 I 0.0000000 0.00215001
'rron lrr 1. ddl -0. s3{7500 I 0.0000000 0. 00{5?601
Lcad 1220.3 'L/L 0. 0000000 | o. oo00oo0 -o . o03 5600 Ir.ead lrro.3 s:.tz -0.0003200 I 0.0000000 0.o0oooool
Masncrl.um lrr9.0TB 0.0000000 J 0,0000000 o. ooooooo I
Mangranora lzsl. 610 o.000oooo I 0.0000000 0 . 000oooo I
uoly,bdenun lzoz.030 o. ooooooo I o. ooooooo o. ooooooo I
ulckol I ,r 1. 6 a4 t2 0.0000000 I 0.0000000 o . ooooooo I
SelenLrrm 1195.02LtL 0.0002100 | o. oo000o0 -0. a2793oo I
selenlurn I rse .ozl t?r o.0ooo000 I 0.0000000 -0 . 0002{oo I
stlleon I e88.158 o .0000000 I o. oo00oo0 o.oooorool
silver I sa8.OEB 0.0000000 | 0.0000000 o. ooo349ol
Strontlurn l{.21 .552 o.000oo0o J 0,0000000 0.ooooo0ol
Thallium I 190.96{0.0011700 I 0.0000000 -0. ooorzoo I
rhorlum I 801.910 0.0002000 | o. oo0o000 o.oooooool
rin I 189.989 0.0000000 | 0.0000000 -0. ooorroo I
TLtanium l rrd. e{1 0. oo0oooo f o,0o000oo o. ooooooo I
uranium I ,ts.95B -0.0090700 I o.0000o0o o.oa:,.Loool
vanadlum lzlz, {0a 0.0000000 I 0.0000000 o .ooo8eo0l
frr. lztt.8s5 0 .0000000 | o. oo0oooo 0. oooog3o I
Form XI (PART 2l 'IN
Coment,g:
STL Denve
STL DENVER
Total Metals Analvsis
-12-
ICP L.II.{EAR RANGES (QUARTERLY)
ContracE:
LEb Codcr $TLDEN Caso No. s
fCP fD !ftunbrr r T{fA Intreptd rCP
IrRS CorSrcretioa
S.[.S No. r
Datc:a/L6/200s
D5ro802113
A.oelytc
Intcg.
rlmr
(Sce. )
ConccnErat:[on
(nglL)
DI
Jaf urnirrun Iro I 60 .00
lAlumlnum Hl I 20.00
J ealclum Lo 20.00
lCalcLum El,20,0o
J lron f,o 20.00
I Iron HL 20.00
lPotesrJ-um 20 .00
ItLcroCs{um 20.00
J Bodiun Lo 20.00
]sodfum Hl 24,00
lT,Lrconiun 20.00
ColunanE8;
STL Denver Forn XIf IN
STL DEIYVER
Contncts r
Lab Codc:
t R'S Corporation
gTLDEN Cagc Ng, t
Total Metals Analvsls
-12-
ICP LINEAR RANGES (QUARTERL\O
g}fl No. :
Datc t 7 l22l20As
sDO NO. : D5I084243
ICP ID lf\xobar:SUPERTR.LCE
.Lrralfrte
Intseg.
lf:[mo
(Sre. )
ConocntratLon
(Etg /f.\M
Jnrranl,c 15. 00 2A Ir
JBart-nm 15.00 25 Jr
I Coppar 15 .00 50 ln
Ir,cad 15.00 100 le
l Nlckal 15 - 00 50 Jr
I SLlvar 15.00 Jr
JVa,nadl.um 15.00 fr
Izlnc 15.00 50 In
O coumcntg:
STL Denver Fom XII TN ]-76
STL DENVER
Coatrrct r IIRS Corporatl,on
r,rl, COdA r STIJDIEN Caaa No. t
rCP ID liltrmber: pE XepMS
Total Metals Analvsis
-12'
ICP I,INEAR RANGES (QUARTERLY)
SAB Ilo, r
Datcr 811,9 l20As
sDc No. s D5I08O243
l,ncl.ytc
fntGer.
Ifi.mc
(floc. )
Concrntntlon
(mg lLl u
Cadmlun 0,001 4 r{
lsalcnLum I 0-001 I I ful
Conm,onts:
STL Denver fom XII IN a77
STL DEIVVER
Total Metals Analvsis
l3-
PREPARATION LOG
Contraet;
r,ab code g
tlnEhod t P
URS CorporatLon
StrLDESI Cage No. :gl.S llo, r gDO ![O.r D5I0802{3
Prrp ![ottrod r
8erry>Ic fD PregantLou Dato
Initj.al Voluna I rinal
I volune (nr,)
Gw-s91-090705 9 /2I/200s 50.0 I 50.0
crv-s10-090705 9t231200s 50.0 I 50.0
ow-sl-09070s 9t23/2005 50-0 I 50-0
Gw-s1-09 07 05 Ms e t2312005 50. 0 I 50.0
GT[-S1-090705 MSD e/2312005 50.0 I 50.0
GTr- 911- 0 9 07 05 9123/200s 50.0 I 50.0
GTI-S2-09070s e /23 t2005 50.0 I 50.0
GTI-93-0907A5 9123t2005 50.0 I 50.0
GW-t[2-090705 9/23t200s 50.0 I 50.0
M8526526L 9123/2005 50.0 I 50.0
CHECK S}I}IPLE 9/23/2005 50.0 I 50-0
ConnorrLs r
STL Denver
FoTn XIII IN
1,7 B
STL DEIVVER
Total Metals Analvsis
I3-
PREPARATION LOG
Contraet:
Lrb Cod,c r
tlsthod r
IrRg Corporatl.on
S1I1TDEII Cur !ilo. r grg No. t sDs No. r D5I0 802d3
cv Prap Mcthodr
Sarple rD PrcDrrrtLon Drtc
raitir1 Volume I ri-na1
I volune (mr,]
sw-991-090705 e/23t2005 10.0 I 10.0
GW-S10 - 09 07 05 9t23t2005 10.0 I ro.0
6ir-s1-090705 9123/2005 10.0 I 10. o
GTr-S1-090705 US 9 t23 t ?OA5 10.0 I r0.0
GT[-S1-090705 DISD 912312005 10.0 I r0.0
@{-s11-090705 9t23t2005 10.0 I 10.0
@r-sz-09070s 9t2312005 10.0 I 10.0
GTil-S3-09 07 0s 9t23/2005 10 .0 I 10.0
GTr[-N2 - 09 07 0s 9/23/200s 10.0 I 10.0
MB52 59437 9t23/2005 10.0 I 10. o
CIIECK SATilPLT 9/23/200s 10,0 I r0.0
Commcntg;
STL Denver
FONT XIII - IN
L79
STL DENVER
rotal *-:ljs Analvsis
PREPARATION LOG
Contraet r
r.ab Code:
Meulrod:
IIRS CorT>ora,tion
STLDEN Caac No. I Sl,g [Io - 3 8DO NO, r D5I080243
Prc1r ![cthod:
Saryl1e ID Initial Vo1umc
50 .0
50 .0
50 .0
50.0
50. 0
50. 0
50. 0
50.0
50. 0
50.0
50.0
FinaL
Vo1umc (nL)
50 ,0
50-0
50,0
50 .0
50.o
50.0
50.0
50,o
50.0
50.0
50.0
Prcprratlorr Datc
GT{-S91-09 07 05 et23t2005
GI,v-S10-090705 912312005
GTy-S1-09 0705 9 123t2005
Gnv-s1-090705 turs 9t23/2003
chl-s].-og0705 MsD 9/23t2005
G!r-811-090705 912312005
Gltl-sz-0907a5 9/23/2005
GTI-S3 - 09 07 0 s 9/23t200s
s[!r-N2-09070s 9 t2312005
MBsz 65L7 2 e/23/2005
9 /23 t200s
Comuantg:
STL Denver
b form XIII r IN
180
STL DENVER
Totrtl Nl-llls Analvsis
ANALYSIS RUT.{ LOG
Contsract:
Lab Codc;
fnetnrnoat,
Sta,rE Datc:
IIRS Corporatl,on
gTI,DEN
ID lllrmber:
9123t2005
Case No.:
|FJA rntrcDtd IeP
gAg No. t
Mrthodr
End DaEc:e t2$/?aos
gDGl No. r D5I0802{3
r - Dctrotaa rdlilltloaal .lsaDta (othar tbat tbo str.niLrd CLP al6aata) lr. r.Drct.Etcil o rctbrr
STL Denver
rrom xIV - fN
garqple
ID.
DlE Tl-mc %R
[nalyt6B
ll :A
g
B
l': I:lrl ::l;
Stdl-B1ank 1. o0 LL=42 x x x x x x
ICrI,l 1. O0 LL= 4'7 x x x x x x
ICf,I,2 1. OO 11r51 x x x x
rcAtl 1. OO 11r55 x x x x x x
ICIL2 1.00 11: 59 x x x x x x
rcul 1. 00 12r0{x x x x
fgVf.1.00 !2=OB x x x x x x
CCl/H 1 .00 12 :13 x x x x
cgw,1.00 L2=L7 x x x x x x
IEB 1, 00 L2:22 x x x x x x
RL€ITD2 1. OO L2 t26 x x x x x x
ICSA 1. OO 12 r 30 x x x x x x
ICSAB 1. 00 12 r 35 x x x x x x
CCIIH L.00 12: {0 x x x x
CgUL 1. 00 L2 -.41 x x x x x x
ccB 1- O0 12r{9 x x x x
i t
x x
cclnt 1- OO 23 tZ3 x x x x
csw,1.00 23 228 x x x x x x
ccB 1. OO 23 t32 x x x x x x
ZZZ7,T,Z 1. 00 23r35
l,IB52 652 51 1. 00 23:{L x x x x x x
CHECK SAIIPLE 1 .00 23t46 x x x x x x
2ZD5r0802{3-O04 L-oo 23r5O l I t I
2D5r0802{3 -O0{L 5. OO 23r55
zD5r080243-00{S 1.00 OO: OO
zD5T.08 02{3- 004sD 1. O0 00r05
Z7r7r7rZZ 1. 00 00:10
7'T'7'I'7,7'1. 00 00rItr
ZZZ7,7.Z 1.00 00r19
CC.\IH 1. 00 00 :2{x x x x
eclrf,1. 00 00:29 x lx x x x x /
ecB 1. 00 00:33 x Ix x x x x T
ZZ7'7,2,7.1 .00 00:38 n
Porn 10
181
STLDEIWER
rotal M":il: *"lvsis
*.*dNi.LYSrS RUN LOC
ContracE t
f/ab Codc r
Ingtnrncnt
Etart Detc;
URg Coraloration
STLDE}I
ID !$rnber;
9 /23 1200s
Cage No. r
T{II rntrcptd rCP
SLg No. t
Mcthod:
SDO No. r D5I08A2{3
P
t Donotce addltional
STL Denver
End Datcr 9 /24/2005
(other Eban tbe standard eLP tlrurntg) arc rrDr.reated on nnothlr Forn I{
SarqPlc
ID.
Dlr Tlme t[R
.f,nal.yBcs
A
L
s
B
A
s
B
L
B
E
c
D
c
.L
c
R
c
o
e
U
F
Fv
P
B
M
o
M
I[
xluol-IC g
Eu
A
G
N
n
T
L
v 7,
ilt
c
N
2D5r0802{3 -OO2 1. O0 0O: {2
Gtrir- sl0- 09 07 05 1. O0 OO: {7 x x xl x x
zDsro8 02{3 - O0 s 1. O0 O0:52
zD5r08 0243 -OO6 1. O0 O0:56
o{-s3 -0907 05 1, O0 01:01 x x x x x x
2D5r080243-O0g 1. oo 01r06
Z7r7r7'7.2 1. oo O1r11
ZT.ZZZZ 1. OO 01: 1.5
7,717127,7.1- O0 01r20
.l
Cg\IH 1.00 OLz2l x x xl x
CC\'IL 1.00 01r29 x x xl x x x
C'CB 1 .00 O1 r 33 x x xl x x x
rlurgnBs
Pom XIV IN
782
STL DENVER
Totsl Metals Analvsis
-14-
A}IALYSIS RT]N LOG
Contrict r
L,ab Code :
fnstnrncnt
St,ert Dat,c r
IIRS Corporation
gTIJDEN
ID ![f,rnber r
9t23t2005
Caae ![o. r
T.Tl Intrcptd fCP
S.Lg No,3
Mothodr P
End Dator 912{12005
sanp-Lc
ID.D/r trJ.ne etR
J tnrlyt,cg
B A
u
L
I
}T
o
o
s
P
D
P P
T
s
I
3
""1
s
R I lu "[;l;f.
StdI.-Blank 1. O0 LLz 42 x
ICALl.1-O0 11: {7 x
rclL2 1 .0d 11r51
ICAIJI,1. OC 11 :55 x
rct,r2 1.0c 11:59 x
Ig\TH 1.0c 12rO{
IgVL 1. ool 12rOB x
CC"UTI 1.00 12r13
cgut 1- 00 LZ zL7 x
ICB 1. ool LZ 222 x
Rt STD2 1.0c LZ r26 x
rc8r,1- O0 12:30 x
rcs.trB 1- O0 13:35 x
CC"WI
l
1 .0d L2=10
ecuL 1. O0 LZt4{,x
ccB 1. O0 12r{9 x
cc-\[t 1 .00 23 t23
cguL 1- 00 2t 228 x
ecB 1.00 23 t3A x
zz,zzza 1,00 23 r 36
MB52 652 61 1. O0 23 t{1 x
CHECK SAIIPLE 1. O0 23:{5 x
2D5ro80243 -00{1. 00 23:50
zDsro802{3 -00{L 5-00 23:55
2o5T0802e3 -008s 1. 00 0O: O0
2D5ro802,43 -Oo{sD 1.00 OOr05
zzz,zzz 1. O0 OOrlO
27.7,7t27,1. O0 OOtl{
7.7,Z7.ZZ 1.00 00 :19
CIUI 1. 00 00,21
CC\IIJ 1.00 00 :29 x
ccB 1. ool 00:33 x
LZ,T,ZZZ 1. 00 00r38
zDsr08 02{3 - 002 l. 00 00r{?
D5r0 802 4 3
183STL Denver Forrr XIV IN
STL DETVVER
Total Metals Analvsis
-14-
AI{ALYSIS RT]N LOG
Contraet:
Lab Codc:
Ingtrcurarnts
Btrart Dntc r
URS Corporation
gTTJDEN
fD Ntrmbcr:
et73t2005
Carr I{Io. I
TifA IntreDid fCP
AfA No. r
Mcttrod.t P
End DaEar 9 /21t200s
SDg No, : D5IO8O2l3
Sarqp1c
ID.Dlv Tine 98R
enalytsr
B f,
tI
TJ
I
M
o
o
s
P
D
P Pr s
r
s
l*l
g
R.
U w r
N
r
H
Ea
I
ser-s]-0 - 09 07 05 1. 0c OOr47 xl
z,D5T080243 - O05 1. O0 00r52
zDsr,o8 02{[3 - OO 5 1.00 OO:56
gw-s3-0907 05 1. O0 01r01 xl
zDsr0802{3-O08 1.O0 01r06
T,ZT,ZZL 1, 00 OLr11
ZZZZT.Z 1.00 01:15
zzzzz,z 1. ool Ol :2O
EC'\'H 1. ool OI.r2e
cc"\E,1. O0 O1r29 xl
ccB 1.00 01r33 xl
STL Denver Forn XIV IN 1-84
STL DE!{VER
Total M"1*s Analvsis
AI.IALYSTS RUI\ LOG
Contrrst:
Irab Codc:
Ingt,runcnt
Stsart Datso:
t RS Cor^goratLon
gTI,DEN
fD ilhrrnbrr r
9126 /2005
Ca;c No.:
TJA Introptd rCP
gl8 No, 3
Mrthodt
End Drtcr
SDC liro. r D5I0802{3
9127 /2005
' - Denota, r'aldl.tiourl al,uoata (oth.r tbr th. rtd0dlar(t CLD GlaDaato, erc ragr.loDtod qo anothor forn la
STL Denver
SamflI-e
ID.
DlE Tiruo IR
[nalytor
r[ :I
g
B
l il-,FI ;;Fl
Stsd1*B1ank 1. OO O9r{1 x x x x x x
IC.Nr1 1. O0 09:45 x x x x x x
f CLII2 1.00 09 :5O x x x x
ICAL1 1. OO O9r53 x x x x x x
IEAL2 1. OO O9r57 x x x x x x
rg\EI 1. OO 1O: O2 x x x x
ICITL 1. O0 10: O6 x x x x x x
cclIH 1.00 1O:11 x x x x
CC\EJ 1-OO 10r15 x x x x x x
rcB L.00 1O:2O x x x x x x
RLgTD2 1 .00 10r2{x x x x x x
rCgA 1. OO 10r29 x x x x x x
ICEl}E 1. 00 10r34 x x x x x x
cc\IH 1. O0 10:39 x x x x
CC'\TL 1. o0 10: O3 x x x x x x
ccB 1, O0 10: dB x x x x x x
egwl 1.00 22tLO x x x x
Cg\,ItJ 1- OO 2224L x x x x x x
CCB 1. OO 22tt9 x x x x x x
7,ZZZ7.Z 1. OO ?2 :53
z7tzzzz 1- OO 22:58
Z,Z,?,7,,7,7.1- 00 23r03
zzT,zzz 1. 00 23 zO7
zzzzzz 1. O0 23r12
zzz7,z7,1 .00 23 tL?
zzzzzz 1 .00 2t tZL
7,ZZ7.ZZ 1. O0 23:26
Grr-sl-090705 trr00 3lil0 It T I T I x
gt{-sx.-0907 05 gER 5 .00 23:35 x x x x x x
CC1'II 1.00 23:39 x x x x
eg\,ltr 1.00 23244 x x x x x x
ccB 1. 00 23t{9 x x x x x x I
Grit-s1-0907 05 Ms 5.00 23: 5{x x x x x x
Form XMN
185
STL DENVER
Total M-lils Analvsis
ANAIJSIS RUN LOG
Contsrrct r
f.ab Codc r
Inafnlnent,
Strart DrEa:
URS CorporatLon
STLIIEN
ID l$umbcr I
9t261200s
Crac No, :
TJA Intrepl.d fCP
gfg tr[o. t
MoLhodr
Eud Datcr 9127 1?00s
gDo No. r D5I08A2[3
P
sa$I)Ic
ID.
DIP fl.me tsR
.hu1ytce
A
lr
s
B
L
g
B
A
B
E
slc,lo c
R
e
o
c
U
r
I'
I
E-
B
M
G
M
}I
H
c TI
O g
E
A
g
N
.n
T
T)
v Z
N
c
![
@r-s1-090705 tLtgD 5. O0 23r59 x fx x x x x
z,z7,zzz 10-oo O0: 0{
cm-se1-090705 5. 00 0OrO9 x x x x x x
G:ru-sl'0-o907 05 10.00 OO:1{xl
crr-811- 0907 05 10. oo 0Or18 x fx x x x xl
cilr-92-090705 10. 00 OOr23 x Ix x x x Ix
Gru-lwl - 09 07 05 10. oo 00:28 x Ix x x x xl
Cg1III 1- O0 OOr33 x x x x
Cg\TL 1.00 OOr38 x x x x x l*l
CClB 1. OO OOr42 x x x x x x
r - D6notar e(Lutlonrl .IeilaEt, (oth.r thr! Eb. rtrDdard eLD alq.at.) lre rrDr.r.nted oE rBotbar fortn 1t
STL Denver
rora ,(rY - IU
185
STL DENVER
Total Nletals Analvsis
-14-
ANALYSIS RUIY [,OG
Cont.ract:
Lab Codcr
InrtnrnenE
Start Dater
IrRg Corpontioa
STLDEN
ID ![unbar:
9126t2005
Crtc No.:
Tirr Intrepid ICP
gAg No. I
Methodr P
End Datsrr 9 127 12005
SDc No.: D5I080243
Srrqp1e
ID.DI?Tinc 96R
tnrlytce
B A
U
It
I
l.f
o
o
g
P
D
9 Pr g
I '1"'l :l r
I
u "l;h ER
l
I
I
gtd1. -B]'lnk 1. 0d O9r{1 x
ICAL1.1- od O9t{5 x
ICI.L2 1.00 09r5O
ICnI.I.1.00 09r53 x
ICAL2 1 .00 09r57 x
ICUTI 1-00 1O: 02
rglrL 1. O0 10: O6 x
Cg\rII 1, o0 1Or11
cc.\rr.1. OC 1O :15 x
ICB 1.00 10r20 x
RLgTD2 1.00 1O:24 x
ICgI'1.00 1Or29 x
rcg.tr.B 1.00 1Or3{x
cclllr 1.00 I,0 r 39
cc'\r&1. 0C 1.Ort3 x
ccB 1, O0 1Or{B x
cgvH 1.O0 22t40
CCTL 1. O0 22:ll x
ccB 1. Oe 22t19 x
ZZZT,7,Z 1. 0(22t53
T,ZZZZZ 1- od 22:58
7.7.7,7t22 1. Of,23: O3
z7,zz7,z 1- od 23:O7
7,zzz,7.7,1.00 23:12
7.Z7rT'27,1 .00 23 tL7
ZT,ZZZZ 1.00
I
23 ..27-
27,Z.Z,7.,7,1. ool 23 =26
cw-sl-0907 05 5.0c 23:30 x
crv-91- 0907 05 8ER 5 .00 23 :35 x
CSIIH 1.00 2l ,30
cc1,n 1.00 23t44 x
CCB 1. Ool 23 : tt9 x
ct{-81-090705 !{st 5 .00 23 :50 x
G-}I-S1-090705 ITISD 5 .00 23r59 x
STL Denver FOm XIV IN
187
STL DETWER
Total Metals Analvsis
-t4-
ANALYSIS RUN LOG
Contrrnct r
Lcb Codrr
InsLnl.rlcnt
Etart Datrr
{rRS Cor1loretion
STT,DEN
ID !ftrmbar:
9/26/2005
Cagc Ng, t
TiIf, Intsrc5ltd
SfS No.:
lCcthod: P
End Dat,rr 9 /27 lZOOs
Sllcl No.: D5I080243
ICP
9arpIc
ID.olE Tiurc e6R
Ane,Llrteo
B .L
U
tr M
o
o
g
P
D
9 Pr s
I
g l"o I
R
h
I
t w r
N
T
H r'
27,7.7.?7,10. od 00:04
GW-S91-Og0705 5. O0 00:09 x
cw-s10 - og 07 05 t-o. o01 Oor].{
Gil-s11-0907 05 10. o0 O0:18 x
crr{-s2-o90705 10. oc O0r23 x
@r-Nz -090? 05 10-o0 00:28 x
CC1IH 1, O0 00:33
cg\rr,1 .00 OOr38 x
ccB 1' 0q 00r{2 x
STL Denver Fonr XIV IN 18B
STLDETVVER
Total M-]ils Analvsis
AN,,\LYSIS RUN LOG
Contrract, r
LrL Code:
Instrumant
Start Datc:
IrRg CorT>oratlon
gTLDEll
ID lilurnber:
912612005
Cage No. t
SUPERTN.LCE
S.Lg No. i
Mcthod:
SDe No.: D5f08A2{3
* Dcnotcr addltionrl chueutg
STL Denver
End Datscr 9 /27 lz0As
(oEhrr thaa Ehe rtandarA eLD e),eneuta) ar. roDrelenEed ou asother Fo:cn 1l
SauUlI.c
ID.
DIT TLms %R
Jtrrrlytcs
llTTll III"lili
EltDI.-81ank 1.00 11: 55 x x x x x x x x x
HTSTD 1, O0 12rO1 x x x x x xl x x x
HIG}TI 1,00 12r06 x x x x x x x x x
TC"\IT 1. O0 LZ tx..?x x x x x xl x x x
CC'\IT 1. 00 LZ tL7 x x x It x xl x x x
ICB 1.00 L2 t23 x x x x x x x x x
RIJSTD 1.00 L2:28 x x x x x x x x x
ICS't 1. OO 12r33 x x x x x x x x x
rca^LB 1. OO 12r39 x x x x x x x x x
LR 1. OO L2tlL x x x x x x x x x
cg\rr l1 1. 00 12 :50 x x x x x x x x x
cc8l1 1. 00 12 :55 x x x x x x x x x
cc,\ru lzs 1. O0 09 :05 x x x x x x x x x
ccxn[ lze 1. O0 O9:1O x x x x x x x x x
ccBlae 1. O0 O9r15 x x x x x x x x x
M852652 51 1. 00 O9t23 x x x x x xl x x x
CIITCK S^}ITIPLT 1.00 O9:28 x x x x x x x x x
zzzz.zz 1. O0 O9r33
zzzzzT,1. OO 09r38
zzzT.zz 1, 00 O9r43
zzzzzz 1. O0 09:{8
sw-s91- 0907 05 1. OO O9r53 x x x x x x x x x
GTr-s10- 09 07 05 1, O0 09 :58 x x x x x x x x x
csvr lzl 1. 00 10: O3 x x x x x x x x x
ccB lzl 1. O0 10:08 x x x x x x x x x
Gr{-sl- 09 07 05 1.00 1O:12 x x x x x x x x x
cw-91-090705 sER 5, 00 10:17 x x x x x x x x x
sl-s1-090705 us 1.00 10r22 x T )t It T T rl T x
G"H-8L-090705 MSD 1. 00 X.0 t 27 x x x x x x x x x
Gtu-s11- 09 07 05 1.00 10r32 x x x x x x x x x
GW-S2 - 0907 05 1,00 10r37 x x x x x x x x x
qr-83 -090705 1,00 10r{2 x x x x x xl x x x
m-N2-0907 05 1 .00 10 s{7 x x x x x x x x x
Forn XfV IN
189
STL DETVYER
o
ContrBotr:
f,ab Codc t
Inetrrun nt
Stert Dater
Total M"1ils Analvsis
ANALYSIS RT]N LOG
IIRS Corporation
grfrDBtiI
ID Mrmber r
9126 t2005
Craa No.:
ST'PERTNACE
Sng No. t
Mrrthod,r
Elrd Datcr
sDGt No.: D5I08A243
e t 27 /2005
i - Deootao ailAltiond e].uratr (ot-hrr ttra th. atllatatil CtD .Io.Dtr) rr3 !.Dr..Dnted oE tDoth.r !o!!l 1l
STL Denver
for:n XIV - IN
SaruflIc
ID.
DIP Tl.me BR
rnallter
A
TJ
s
B
A
s
B
l'
B
E
c
D
C
t.
c
R
C
o
c
U
r
E
P
B
![
o
M
N
H
G
N
I
K s
E
A
GI
N
A
1[
L
v 7,
N
c
N
csvr I zg 1. O0 10r52 x x x Ix x x l*l x x
ccB I ze 1.00 1Or57 x x x Jx xl x l*l x x
csvrlso 1. O0 12: O3 x x x fx xl x Ixl I l*x
ccB I so 1. oo 12:{8 x x x x x x xl x x
zr,7.zzz 5. OO 12r53
GTr-82 -090705 5.00 12r58 x x x x x lx xl I lx x
cc-vr i 31 1. 00 13r03 x x x x xl l"l xl I lx x
CCB I gr 1. 00 13 :08 x x x x xI Ix xl x x
190
STL DETVVER
Total nt-lils Analvsis
ANAI,YS$ RUN tOG
Contraets:
f,ab Codt r
In;Enrment
Start Datc:
URS Corgoratiou
STLDEN
ID lfirmber r
sl23/200s
Cagc No.:
PE gULB,
gl8 No. :
Dlrthodt
End DaEc: 9 /23 l2OO5
gDO No. r D5f08OZe3
cv
aampLa
ID.
Dlv Timc %R
fna].ytscs
tl ffit I'lxl$
Ca1ib B].ank 1.00 1,5 r 52 x
O.2 ppb 1.00 15r5{x
0.5 g1>b 1. oo 15r55 x
1. O p1lb 1. OO 15r57 x
2.0 plrb 1.00 15r59 x
5. O p1>b t-00 15r01 x
10.0 pDb 1- OO 16r02 x
ICB 1, O0 16r05 x
IC'V 1.00 L6rO6 x
cg\rl 1- OO 15: 08 x
ccBl 1. OO 16r10 x /
NI,1 .00 15:11 x T
zzzzzT,1.00 16: 13
?.TrzrTtZZ 1. O0 16: 15
zzzzT,z 1. 00 15r15 rr l-l i-t n
7,7rZ7rZZ 1 ,00 15:18
Z7'7,2717'1. 00 t6:2O
7rZZZ7.Z 1. OO 16 r 21
T,ZZZZZ 1. 00 15r23
ZZZT,ZZ 1- OO 15r25
7.7rLL7r7r 1. 00 L6 t27
CCTIz 1. o0 16r28 x
CCB2 1.00 16r3O x
esvS 1.00 17 r{9 x
CCB6 1. O0 17 :51 x
Z7,ZZ7.Z 1.00 17r53
7,27.7rT'Tr 1.00 17 :5{t---
I
LLLUL 1.00 17r55 I
7,27,7,27,,1.00 17 :58
ZZ7r7rZ,7'1. O0 17r59
27,7,7'7rZ 1.00 18r01 t-l n L_l
7r7r27r7,7'1.00 18r03
ZT,ZZZZ l-.00 18:0{-l
* - DaDotaa atldltlcraal elaLalta (other thlra tb. itrnilrrd CLP .IaDa&t,a) ara raDrar.atod os aaothar ,oED 1l
STL Denver
For^n XMN
191
STL DENVER
Total M.lils Analvsis
ANALYSIS RUN LOG
Contnet r IIRB Corpontion
r.ab Codc r STLDEN Cr.ac No. :gtg No-:SDe No. : DSf 08OziI
fnatnutsnt ID lihrrbcr r PE gIIAf,Mcthodr C\f
Sbart Datc z 9 123 l2OA5 End Datrcr 9 123/?OAs
| - DaDotoE addltloDal olq.ntt (otbrr thaa tha rt&rdrral cLP etoDeDtr) !r. reDreroDt.d oE aBotbor DoB 1l
STL Denver L92
Eorn XIv - Il[
8rq>1e
ID.
D/E TLme 96R
hnalytca
rl;l'
g
B
.e,;l ;l:l ;cIcol,
M85259{37 1. OO 18r05 x
CIIECK S^TPLE fi,1- OO 18r08 x
ec,\n 1. O0 18r10 x --l
ccBT 1. 00 18:11 x
@r- EI91-o907 05 1.00 18r13 x
crr-s]-0- 0907 05 1. O0 18r15 x
Gw-sl-0907 05 1. O0 18g15 x
Gcw-91-09 0'l 05 Ms,1. O0 18 :18 x
Gff-sl.*090705 MSD 1. O0 18r20 x
cr9r-sll.-090705 1.00 18 :21 x
c#r-s2 - 09 07 05 1.00 18 :23 x
@[-s3 - 09 07 05 1, O0 18:2{x
crw-N3-0907 05 1.00 18:25 x
zt7,7rZZ 1. O0 18 :28
CC.IIB 1.00 18 :29 x
ccBS 1. OO 18r31 x
STL DENVER
T'otal M-lils Analvsis
AT'IALYSffiRUN [.,OG
Contract,:
Lab Code:
fnrtnrmant,
Start Date:
UBS Corgoration
STI,DEN
ID Nurobcr:
9/27 /200s
Cage No.:
PE ICPMS
gAS No.:
Method r
End Drtcs 9 /2e/zAAs
SDg No.: D5f080243
M
. - I)arcEot aoaltldal cle.nta (oth.r tbE thi at.dhrdt Cr,P .IEeDtr) ara laDr.EelrtGd oE raothar
STL Denver
Iorrl XnI - il
Saqrlc
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Dlt tlLna tR
.LnaI1rc,c;
tr
IJ
g
B
f,
g
B
A
B
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c
D
c
A
e
n
c
o
c
u
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E
P
B
![
o
M
N
H
o
N
I
K g
E
L
G
DI
.4,
T
t
v 7,
N
c
ilT
Bl-ank 1.00 15:58 ix
I
x
8t,and,ard, 1 1. 00 15rO2 x x
oc srd I 1. O0 16: O5 x x
QE grd 2 1. OO 16:09 x x
RLgTD 1. OO 15:13 x x
zzzzzz I .00 16r17
rcs.r'1. 00 16:20 x x
IESIB 1. O0 L6:24 x x
RTNSE 1. O0 16: 28 Ix x
HIGIH EHEEK 1, o0 16r31 x x
RINgT 1. O0 15r35 x x
QC srd 3 1.00 15r39 x x
QC srd 4 1.00 L6t{,?x x
BIank 1.O0 17r16 x x
Standerd 1 1,00 17 :19 Ix x
QC srd 3 1.00 L7 :23 x x
0c sEd I 1. O0 t7 z2'l x x
ac 8rd 3 1. 00 21r58 x x
QC SEd *1.00 22 zO2 lx x
ICSr.1. O0 22r05 x x
rcSrB 1.00 22tO9 x x
RINSE 1.00 22 tL3 x x
ac srd 3 1. O0 22 zL7 x x
0c 8r,d 4 1.00 22 tZL x x
0c std 3 1. O0 01:{9 x x
ac sEd 4 1.00 01: 53 x x
MB52 65L? 2 1 .00 01r56 x x
sIEgK SSIIBIJE 1,00 02100 I I
olr-s91-09 07 05 10.00 02r03 x x
GW-S10- 0907 05 5.00 02:0?x x
gJ-sl-090705 10. 00 02 :11 x x
q[-s].- 090705 ssR 5.00 02:L4 x x
G![-S]"-090705 PDg 1. O0 02r18 x x
Eoxlr 1a
193
STL DE|VVER
Total *"11[ Analvsis
AIYALYSIS RT]N LOG
Contract' r
Lab Code:
Inrtrnrmcnt
Strrt Dater
t Rg Cor5roration
gTLDEBI
ID Mrnbrrr
9 127 t2005
Carc No. r
PT TCPMS
SfS No,:
McEhod:
Etrd Drtcl 9/2812005
gDO No. r D5I08A243
M
Saryllc
ID.
Dlr,TLne t6R
.Bna1yteg
A
L
g
B
l,
g
B
t
B
E
C
D
c
.[.
c
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c
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E
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M
N
H
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K s
E rJ I T
L
v 7,
N
C
N
ac srd 3 1.00 AZ tZZ x x
9C std 4 1.00 O2r25 x x
oril-s1-o907 05 us 10. 00 O2 r29 x x
Gtr{-SI'- 09 A7 A5 MgD 10. o0 02:33 x x n
ctr{-sll-o90705 20.00 02:36 x x
GW-Sz-090705 50. 00 O2 r 40 x x
Grw-s3-09070s 5-00 O2rl4 x x
Glr-N2-0907 05 10-00 A2t17 x x
ac std 3 1.00 02r51 x x
QC Srd 4 1. O0 O3 :55 x x
r - DaDoteg rtlilitlooel chnpnbr (oth.r tb.a th. .trrdllal CLP aluati) rr. r.Dr.ietrtcdl ou another Fo:ra tl
STL Denver
form Xrv - nt
1,9 4
T,IBTIIOD BI,ANK REPORT
GeneraJ. Chemistrlr
Client Iot # -
PAITJ\METER
: D5f080243
RESULT
t{atrix-. -.. ----: WATER
PREPAITJ\TION- PREP
AI\TAI,YSIS DATE BATCH #
D5r2ZA000-413
ae / 20 / as 526s473
Work Order #: HKSVP1AA
0 - 10 nrg/t
Dl lut ion Factor : L
Ana),yeis rlme., : 22 :00
tfork Order #: HIQ(ST1AA
2-5 &glL
oi }ut ion Factor : 1
enalygis Time. . : 17 :00
Work Order #: HKC0RIAA
O.1O rrng/L
oilution Factor: 1
Analyole Time..: 11:30
Work Order #: I{KTLWIAA
0 .10 mg/L
Pilution Factor: 1
Analyoia Time..: 12:00
Work Order #: HIJITMF1AA
0 .I0 mg/L
Pilution Factor: 1
Rnalygis Time..: 17:00
Work Order #: HK?HELAA
0 .l-0 mg/L
Diiutlon Faetor: 1
Analysis Time-,: 22:00
Work Order #: HLLD91AA
0.10 mg/L
niluLion Factor: 1
Analyeis Tinre. . : l-8 : 00
Work Order #; HLL531-AA
s-O mg/L
nilutlon Factor: 1
A:ralysls Time. . r L5 :40
Work Order #: HK1GT1AA
0.010 ms/L
Dilution FacLor: 1
Analysio Time. . : 12 :00
MB Lot - Sample
MCAWW 350.1
MB Lot-Samp1e #:
ITICAWW 325 -2
REPORETNG
LTMIT UNTTS METHOD
Amrnonia as N
Chloride
Fluoride
Ni trate
Ni trat e
Ni trate -Nitri te
Ni trate -Nit ri te
Sulfate
Tota] Cyanide
ND
1.8 B
0-021 B
2.2 B
Ds1200000 -255
o9/L8/ os s2632ss
MB Lot -Sample
Ir{CAr{W 340 -2
#, D5r090000-54L
aglael os s252s41
}JD
ND
ND
IrD
MB Lot-Sample
IvlCAliT'I 353 .2
MB Lot-Sample
MCAWW 353.2
MB Lot -sample
MCAWW 353 .2
MB Lot -Sample # :
tvlCAWW 353 -2
Dsr220000 -584
ae / 08/ as s26ss84
D5r280000-705
09/08/05 527r-7os
D5r22A000 -552
09 / 20 / a5 s26sss2
Dsr2B0000 -679
a9 / 27 / 05 s27L67e
ND
MB Lot-Sample
ucAww 375 _4
MB Lot-Sample #r
gWB46 901r,lleo12A
D5r29A000 -].72
aglzalos s272L72
D5r200000-510
09 I zo-os I 2rl as s2l351o
NOTE (S) :
Clalculations are perfornted beforc rountling to aroid round-off crrors in calculared rcsults.
B Fstimared result. Result is lcss rhan RL.
STL Denver 195
I,ABORATORY COIuIROI, SA}'PIIE E\IALIIHTION REPC}RT
General- Chemistry
I.ot-Sanp1e # -
PARAMETER
pH
: D5I0B0243
PERCENT
RECOVERY
RECOVERY
LTMTTS
(eo
(so
(87 1r-4 )(w 114 )
(as
(85
Dl l-ut i orr
RPD
RPD LIMTTS METHOD
I'latrix-- ...-i WATER
PREPARATION- PREP
Ar{ALYsTs pArE E}IgL_t
Lot-Sample# : D5r08000 A -527
a9 / o8los s25L527
ae / 08 / os s25ls27
: l-1 :59
Lot -Sample# : D5T22000 0 -473
oe /2o / as 5265473
ae/2a/os s25547 3
: 22 :0A
Lot-Sarnple# : D5I2A000 A-255
a9/18/os 52532ss
ae / 1B/05 s7-53255
: 17:00
Lot-Sample# : D5I090000-541
100
100
Amrnoni a as N
97
97
Chloride
100
100
Fluoride
92
91
Ni t rate
101
10l_
Ni t rate
101
10r
Ni trate -Nitri te
96
95
Nitrate-Nitrite
99
99
IVICAWW 34O .2
114 ) O . B0 ( O-16) MCAWW 340 .2
Dl lution Fact,or : 1 Analyoie Tirne.
wo# ; HKTLW1AC -T,CS/ HKTLW1AD-LCSD
110)MCAWW 3 53
110) o.se (0-1"0) MCAww 3s3
cilution Factor: L Ana 1ya i o
wo# : HrrI-rMF1AC- LCS/HLtIqF] AD-LCSD
oe/ae/as
oe/oe/os
: 11:30
Lot-Sample# : D51220000 -584
I/{Io# : HKCSI,TIAA- LCS/HKCSMIAC-LCSD LCS
(gt taz ) sw84 5 904 0B
(gt Loz) 0.0 (o-5.0) sw846 9o4oB
Dilutlon Fact.or: 1 Analyslo Time.
L{o# : HKsVP1AC- LCS /HKiVP1AD-LCSD LCS
l-10)MCAWW 350.1
110) O-1s (O-10) MCAVnil 350.1
Dllution Factor: 1 Analysis Tlme.
wo# : HIC{STIAC- LCS /EVASTIAD- LCSD I-,CS
(go 110)MCAWW 325 .2
(go 110) o-62 (o-10) MCAWW 32s.2
Di.lution Factor: 1 Analygis Tlme.
wo# :HKCOR1AC-LCS/nXCORI^AD-LCSD LCS
(at
(aa 110)
(eo 110) 0.59 (o-10)
Dilution Factor: 1
(92 L12)(e2 t]_z ) O
LCS
.2
.2
Time.
LCS
.2
.2
Time.
LCS
,2
-2
rime.
tCS
MCAWW 353 - 2
MCAWW 353.2
Analyois Time.
next. page)
ae/oB/0s
os / o8l0s
: J.2:00
LoE-Sample# : D5T.280000 - 705
MCAI^IW 353
MCAWW 353
Ana Iys is
oe/as/as
ae /08/os
525254A
52s254L
5265s 84
5265s84
5271705
5271705
5265ssz
s265552
wo# : IIKTHEI-AC-LCS /UrctHElAD- LCSD
(gz 112 )MCAWW 353
(gz LLZ) 0.10 (O-10) MCAWW 3s3
Dilut. ion Factor r J.Analysi s
WO# : HL,LD91AC- LCS /HLLD9LAD-LCSD
: 1.7:00
LoL-Sample# : D5 T220000 -552
ae/20/os
0e/20/os
z 22:OO
Lot -Samp1e#: D5T280000 - 579
oe / 27 / aS 527t57 e
ae/27/os s27 L57 9
: l-B:00
.1s (o-10)
Factor: r
STL Denver
(Continued on
1,9 6
LABORATORY COTqIROL SAITPItr ETIAIII}XTION REPORT
General- Chemistry
Lot-Samp1.e * -
PARAMETER
Sulfate
Total Cyanide
NCtfE (S) :
: D5I0I A243
PERCENT RECOVERY
RECOVERY LIMITS
RPD
RPD I,TMTTS IVIETHOD
Matri:r- - . . - - - . . : WATER
PREPARATION- PREP
ANALYSTS DATE BATCH #.
Lot-Samp1e# : D5T.29000 0 -L72
ae/28/ os 5272L72
ae /28/ os s272]-72
: 15;40
103
105
LO4
10s
wo# : HLL53IAC - LCS /HLT,531AD - LCSD LCS
( gr LLz) tvtcAl{w 3'7 s .4
(91 1121 2.5 (o-1s) McA-v{v^I 375.4
plluEion Factor: l. Irnalyeie Tlme.
wo# : I{K1GTLAC-LCS/HK1GT1AD-IJCSD tCS Lot - Samp}eS : D512 0000 0 - 5L0
(8e 10e)
(89 109) O.9s (o-20)
Dilution Factor: 1
sw845 90r aE/9012A As / 20 -Ae / 2L / 05 s253510
s[{B46 901- AB/e012A 09 / 2A -A9 / 2Ll As 5263s10
Analyeie Time. . : L2 ;00
Calculations are perfonned bcf'ore rounrJrng to avoid rourrd<rff errors in calculued rcsults.
STL Denver a97
Lot-Sanple * -
PARAMETER
pH
I,ABORATORY CO}ITROL SAUPf.E DATA REFORT
General ChemiBtry
: D5r0B A243
SPTKE MEASURED PERCTIT
AMOUNT AMOUNT UNITS RECVRY RPD IVIETHOD
Flatrix- - ., r - - - . : WA,TER
PREPAIT'\TION. PREP
ANALYSIS DATE BATCH #
LCS Lot-Samp1e#: D5T20000 0-255
32s .2 A9 / LB / 05 s2532ss
325 .2 A9 / 1Bl 05 s26325s
Tirne..: 1-7r00
LCS Lot-Sample# : D5I090000-541
340 -2 09 / A9 / Os s2s2s41
340 .2 A9 / 09 / 05 525 254L
Time.., 11.:30
LCS Lot-Sample# : D51220000-584
353 .2 A9 / 08 / 0S 52655 84
353 .2 A9 / AB / 0S 526s584
Time. . : 12:00
LCS Lot-Sarnple#: D5 1280000-705
3s3 -2 Oe I A8 / As 527170s
3s3 . 2 A9 / 0 8/Os s27 17 Os
Time, , ; 17:00
IJCS LoE-Sample#: D5 1220000-552
3s3.2 oglTA/os s2555s2
3s3.2 OslzA/os s25s5s2
Tlme.. r 22tOO
LCS Lot-Sample# : D5TZB000O-679
353 . 2 Ca /27 / as 527167 9
353 .2 A9 /27 / 05 s27t67 9
Tlme..; 18:00
7.AO 7
7.00 7
wo# ;HKC5M1AA-ICS/HKC5MIAC-LCSD LCS tot-Samplefi : D51080000-527
-00 No uniE8 100 sw845 90408 O9/08/Os 52sL527
.00 No unirs 100 0.0 sw846 90408 09/08/05 5?5L527
Dllution Factorr 1 Analveig time,, r 11159
wo# :HK6VPLAC-LCS/HK5VP1AD-LCSD LCS Lot-Sample# : D51220000-473
.88 mg/L 97 MCAWW 350.L 09/20/Os a26s473
.8e rflg/L 97 O.1s MCAWW 3s0.1 O9/2O/O5 s26s473
Dilution Factori 1 Analysie Time..: 22:00
wo# ; HrO(STIAC - tCS /UKXSTI-AD - LCSD
Arnmonia aB N
4 .00
4 .00
Chloride
50 .0
50.0
Fluoride
5.00
5.00
Ni trate
0.0500
0 - 0500
Nitrate
0.0500
0 .0500
Ni t rate -Ni tri te
4.00
4 .00
Nitrat e -Nitrite
4 .0c
4 .00
mg/r,
ng/t'
Dilut,lon Factor: I
3
3
49 - B
s0 .1
4 .64
4 _s6
3 .85
3 . Bs
3 .95
3 - 95
mg/1"
mg/L
DiluE.{on Factor: 1
MCAWW
0 ,52 ITICAI{W
Analysl o
MCAWW
O. BO MCAWW
AnaLyei s
MCAWW
O.10 MCAWW
Ana1ys i e
MCAI,W{
O .15 MCAWW
Ana1yeis
100
l-00
I.{o# : HKCOR1AC - rrCS / IHXCOR]"AD - LCSD
92
91
wo# : HKTLWIAC-LCS /lF,XlrWlAD-LCSD
0 .0s04 mg/l-,
0 - 0s07 mg/L
101 I,ICAWW
101 0.59 MCAWI^I
Dllut.ion Factor: l-Analysi s
wo# : HLLMF1AC - LCS/HLLMFIAD - LCSD
0.0504 mg/T, 101 MCAWW
0 - 0 5a7 mg/t 101- 0.59 MCAWW
Dilutlon Factor: I Arralys I s
t{o# : HKTHE1AC -LCS / HKTHE1AD- LCSD
mg/I'
mg/t,
95
96
Dilut.ion Factor: 1
wo# : HLr,D91AC-LCS /Ut t OgLAD-LCSD
mg/L 99
mg/ t 99
Di lut ion Factor : 1
STL Denver
(Continued on next page)
198
I{ABORATORY CONTROL SAUPLB DATA RBPORT
General CIremiBLrlf
: DSI08 0243
SPTIG IVIEASURED PERCMT
AIVIOI.JNT AIUOUNT I]NITS RECVRY RPD METHOD
Matrix- . ., - ., - - I WATER
PREPARATION- PREP
AIIATYSIS pATE . BAryF t
L<lt-Saqlle # -
PAXAMEIER _Sulfate
Total Cyanide
NOIE (S)
=
0.104 mg/T,
0.105 mg/L
25.0
25.O
0.100
0. i00
wo# : HIrL53 1AC- LCS/I{IrL5 3 1AD- LCSD LCS Lor -Sample# : D5 12 90 000 - 172
2s.8 mg/L 103 MCAWW 37s.4 09/28/05 s272L72
26 .s trlg/r, 105 2 .6 MCAWW 375 -4 09/2e/ 05 5272a72
Dilueion pactor3 1 Analyois Tlme..: 15:40
wo# : HKlGTrac-r,cs/grtG?1AD-IJcsD LCS Lot-Sample* : D51200000 - 510
104 SWB45 901-AB/9012A Ael20-09/2L/AS 525351-0
10s 0-9s sw845 e01oB/9012A Ae/2A-A9/2L/As 5263510
Dllut,lon Factor: 1 Analyels Tirne..; tz-,ao
Calculations arc perfonned hcfore rourrrling to uvoid round-ol'l'crrors ln calcularcd rewlts.
STL Denver
199
Clierrt Lot *.
Date Sarpled-
PERCENT
PARLryIFTER RE.COVERY
Amrnonia as N
99
9B
Chloride
95
95
Fluoride
76 N
79 N
Nitrate-Nitrite
92
BB
Sul fate
93
7 .2 N, *
ToEaI Cyanide
0.0 N
0.0 N
NOIE (S) :
I,IAIR.IX SPIKE SA]IPLE ELIAITUATION REpORT
General Chemistry
Dsr080243
ag l a7 /0s 09 : 55 Date Received- - : 09 / 0B/05
RECO\ERY
LTMTTS
RPD
RPD LTMITS METHOD
DtaLrix-- --.-i WG
PREPAXATION- PREP
AI\TALYSIS D^ATE BATCH #
MS Lot-Sample #: D5I080243-004
oe /20 -09 /2L/ os s25s473
09 / 20 - oe / 21 / os s26s473
Lot-Sample # : D5I080243-004
ae/a8/as s2632ss
0e /L8 / 05 s2632ss
MS Lot-Sample #r D5f080243-004
09 / 0e / os 52s2s4l
a9 / a9 / a5 5252s4L
MS Lot-Sample #: D5I080243-004
a9 / 27 / As s27767 e
a9 / 27 / 05 szlt67 e
IvIS Lot-Samp1e #r D5I080243-004
a9 / 28 / As s272L72
09/28/ 05 5272L72
wo# : HJsJMIDG-MS /ntAJMlDH-r,1SD
(++ 130) rqcAww 350.1
(qe 130) 1.1 (O-30) MCA!{W 350.1
oiluElon Factor: L
Analyels Time, . : 03 :00
WO#: HJ6JIVI1DC -MS/ HJ6.]M1DD_MSD MS
(go 11 0) MCAWW 32s.2
(go lro) o.18 (0-ro) MCAWW 325.2
oiLutlon Factor: I
Arralyels Time. . : 17 ; 00
wo# : HJ5'JMLDE-MS /HJ6JM1DF-MSD
(BZ L07) MCAWI^I 340-2
(az to7) 2.4 (o-1-0) MCAWW 340.2
Dilution Factor: i
Analyeie Time..: 11:30
wO# : HJ6JMLCT -MS/HJ5,]M1-CB -MSD
(sz 119) tqcAwlril 353.2
(SZ 119, 2.L (0-30) MCAFII^I 353.2
ollut.ion Factor: 1
analyols Time..: 18:00
wo# : H,f5,JMlDJ-MS/H;s.nt1DK-MSD
(45 153) mCAI^lW 375.4
(+s - L53) 57 (O-2r) MCAWW 3"t5.4
nilution Factor: L
Analysle Tirne, . : 15 ;40
wO#; HJ5.TMI-DL*MS/HJ5,fM1DM-MSD MS Lot-Sample #: D5I080243-004
(89 - r.oe) sw846 e0108/90r-2e, og/zo-og/zllos s263sto
(89 - l"0e) 0.0 (0-20) sw846 90108/9012A Oe/20-09/2a/os 5263sLO
Dilution Eactsorr 1
Aralyaie Tlme.,: 12,00
Calculatiolts arc performed betbrc rouoding to avoitl rouM-off errors in calculated resulls.
N Spikul analyte recovery ls outsitJe staral control llntits.
i Rclath,e percent difl'crence (RPD) is ourslde smtetl control linrirs,
STL Denver 2AA
Cl.ient L'ot, # -
Date Sanrpled.
}iAIB,IX SPIKE $$1t4ry,6 DATA REFORT
General Chemietry
; D5 f 08 A243
: 09/07/05 09:55 Date Recei\red..! 09/08/05
I{atrix.- ---.: WG
PREPARATION- PREP
AI{AI,YSIS DATE BATCH #PARAMETqF
Ammonia a6 N
540
540
Chloride
11000
1r_000
Fluoride
2.2
2.2
Nitrate -Ni tri te
320
320
Sulfate
2500
2500
Tota] Cyanide
o.013
0.013
NOITE (S) :
SAMPLE SPIKE
AMOUNT AIVIT
2000
2000
MEASRD
AIVIOUNT UNITS
PERCNT
RECVRY RPD METHOD
2520 mg/L
2490 mg/L
3 510 0 mg/ I"
3s000 mg/L
5.00 N mg/t'
5 .15 N mg/L
590 mg/L
676 mg/L
Pi IuE i. on Facto r i
Analysle Time. . :
4 850 mg/L
269a mg/L
wo# : HJ6JMT-DG -MS /UIAJMIDH-MSD MS LoE-Sample #: DSI080243-004
MCAr/'il^r 350. 1 A9/20-A9/2L/ A5 5255473
MCAWW 350 .1 A9/20-09 /2L/ Os s265473
99
98
95
95
76
79
92
BB
93
7.2
L.1
2.7
57
DiluE.ion facLorr 1
,\nalysls Time. . ; 03 :00
wo# : H,I6'JMI-DC-MS/H,J6JM1-DD-MSD MS Lot-Sample #: D51080243-00rI
2s000
2s000
5 .00
s .00
400
400
2s00
2500
0.l_00
0 .100
Dilution Factor: 1
Irr:.a1ysls Time. . : 17 r 00
wo# : HJ5JlllDE -MS /HJSJIvIIDF -IvlSD
MCAWW 325 -2
0.18 MCAWW 325.2
2.4
ae/]-8/05
0e/\B/os
526325s
525325s
MS Lot-Sample #; D5I080243-004
MCAWW 340 .2 09 / Oe /Os 5252s4L
MCAWW 340 .2 09 / A9 / A5 s2s254L
nilutlon Factor: 1
Analyels Time..: 11:30
wo# : HJSJIVI]- C7 -MS/HJ5.rM1C8 -MSD FIS Lot - Sarnple
MCAWW 353.2
MCAVfl^I 353.2
o;,",7:1ZZ'n3-o i:,)
wo# : HJ5.IMLDJ-MS/HJ6.IMLDK-MSD
ae/27/os 527 L67 9
MS Lot-Sample #: D5I080243*004
MCAWT,{ 375.4 A9/28/O5 5272L72
MCAITW 3'7 5 , 4 A9 / 2B / 05 527 2L7 2
1
L8:00
Qualifiers r N, *
Dilution Factor: 1
Analysis Time..: 15:40
wo# : HJ5JM]-DL -MS /Ul e.TM]-DIvl-I"ISD
0.00760 mg/L 0-0
Qualifiers: N
0.00898 mg/L 0.0
Qualifiers: N
Di lut ion Factor : 1
Analysie TIme.,: 12:00
MS Lot-Sample #: Dsf0B0243-004
sw846 901A8/e oe/20-A9/2L/os s263510
0,0 sw845 e0LoB/e 0e/20-oe/2L/0s s263s10
Calculations arc perfornret{ belbrc roundirrg to avoid round-off err()rs in calcularctl results.
N Spiked analltc tccover) is oursidc starcd control limits.
t Relative percent differerrcc (RPt)) is outside statcd control limits.
STL Denver 207
I.AIR X SPIKB $$tP1rB B\NTLTIATTON REBORT
Geueral Chemietry
Client l,ot # -
Date Saupled-
Ds r 0I024 3
09 / 06 / as 1o :35 Date
RECO\reRY
LIMITS
Recr=ived.-3 a9/A7/oS
RPD
RPD LIMITS TIETHOD
PERCBNT
PAIU\I\4ETER RECOVERY
Ni t rat,e - Ni tri te
92
90
Nitrate-Nitrite
100
97
NOtE (s) :
wo#:
119)
119) Z.t (o-30)
oilution Factor: 1
Analysle Time..: 22:A0
[,Io# ;
11e )
Ll-e) 3.3 (O-30)
Dilutlon Factor: 1
Analyaie Tirne. . r 02 : 00
HJ35N1CE-MS /UltSNl-CF-MSD MS
I,ICAWW 353 .2
MCASII^I 353 .2
Hatrix- - - - . . . . - 3 WATER
PREPARATION- PREP
ArvALYqrs pATE . BATCH #
Lot-Sample # : D5I07027A-002
oe /2a / os 526sss2
09 / 20 / as s26sss2
Lot-Sample #: D5r100153 -003
oe /20 -0e /2r/ 0s s26sss2
09 /zA-oe / 2t/ 0s s255ss2
a-
(62
(az
(az
(az
HKAR91C5 -MS/HKARg1C7 -MSD rqs
MCAWW 353 .2
MCAI'IW 353 -2
Calculadons are pcrlbnnal before roulrding m avold round-off crrors ilr calculacd rcsults.
STL Denver 202
Client Iot * -
Date Sanp1-ed-
SAMPLE
PARAryIETER AIvIOTINT
Nitrat.e -Nitrite
a ,24
0 ,24
Nit.rate-Nitrite
0 .18
0 _1-8
NOTE (S) :
3.94 mg/!" 92
3 . Bs gJlg/L 90
Pllution Factor; 1
Anaiysis Time..: 22:00
MCAWW 353 - 2
2 .7 I,ICAWV{ 353 .2
3,3
IIILIRIX SPTKE SAUPI,B DATA RBPORT
General CherniBtry
Dsr0B0243
a9/06/oS l-0:35 Date Received.-3 a9lA7 105
SPIKE
AMT
MEASRD PERCNT
AMOUNT UNITS RECVRY RPD METHOD
l.Iatrix- - - . ? . . . . r hIATER
PREPARATTON- PREP
AT{ALYSIS DATE BATCH #
0e / 2a / as 526ss s2
ae / 20 / 0s s26sss2
wo# : HJ3 5N]"CE-MS /HJ35N1CF-MSD NIS Lot-Samp1e #: D5f 070270-A02
4 .00
4 .00
4.00
4 - O0
4.L7 mg/l'
4 - 04 mg/l'
wo# : HKAR91C6 -MS/Hran e1C7 -MSD MS Lot-Sanrple #: D5I100l-53 -003
MCAWW 353 .2 A9 / 2A-09 / 2L/ Os 526sss2
MCAI^n^I 3s3 .2 A9/2A-09/2L/ aS s26ss52
100
97
Pilucion Factor: 1
furar yais Time. . : 02:00
Calculatlor\ are pcrfomted hefore roundirtg to avoid rouM-off errors in calculatecl rcsults
STL Denver 243
Client lot #-.. =
Date Sauqlled- , . l
SAITTPLE DTIPLTCATE
Ds r 0I0 243
General
I{ork Order
A9/a5/A5 10;35 Dat.e Received..3 09/a7/a5
WATER
PREPARATION- PREP
A}IALYSTS DATE BATCH #
D5I07027A-002
oe/08/0s s25ts27
EUALTIATTO}I REFORT
Cheuietry
*- -.: HJ36N-SMP
HJ3 5N-DUP
PARiqM RESULT
DUPLTCAIE
RESULT UNITS RPD
RPD
LIMTT METHOD
pH
No Units 0 .13
Di lucion Factor : L
SD Lot - Sampl-e
(o-5.0) sw845 90408
Analyslo Time.,: L3:11
7.8 7.8
STL Denver
204
STL Denver
Sarnple Receiving Checklist
Lot #:
Company Name & Sampling Site:
DatelTtlrne Recei u"A, ?rt/A:;- 0?60
PM to Complete This Section: Yes
Residual chiorine check requireci:f X
Quote#:{+ots
Special Instructions:
CttgUtvEth c.c t-y Ii,*- Uoft' S
Timc Zone:
.'EDT lEST . CDT/CST . N/[!T,MST . PDT/PST . OTfIER
Quarantiaed :1:'' x,
Llnpacking Checks:
Cooler #(s):
-l - 7 -
_s'Y3
Temperatures("c): .S, | .3. , l,tl -7.,V f, t - S, B.
lio
f, 1. Cooler seals intact? (NiA ifhand delivered) If no, clocument on CUR-
e 2. Chain of custodyprcsent? lfno, docurnent ou CLIR-
Bottles broken and/or are leaking? If yes, docurtent or CLIR.
Multiphasic sumples obvious? If yes, documeut on CUR.
Proper coatainor & presen'atives used? (ref Attacbmem D of SOP# DEN-QA-0003) If no, documeEt ou. CJR.
pH of aU samples chccked aud meet requireincnts? If no, document on CUR.
Sufficient voiumc provided for all auaiysis requested? (ref- Attach-ent D of SOP# DEN-QA-0003) If no,
documcnt on CLIR, aud contact P.M before proceeding.
Did chrrin of cusody agree with labeis ID and sarrples rccEivcd? If no, document on Ct,B-
Wcre VOA samples u.ithout headspace? If no, rlocurnent on CUR.
Were VOA vials presewcd? Preservariv, Dl{Ct E4t2"C Dsodium Thiosulfate ! Ascorbic Acid
Did samples require presenation with sodium thiosu[ate?
If yes to #1 I, did the sampies contail residual chlorinc? If yes, document on CLIR.
Sedimeot present in dissolved/flhercd bottles? If ycs, document on CLB'
{ a 14. Is sufiisient volumo proridsd for clgnt rcquestcd MS, MSD or metnx duplicates? If ro, document o, CU}, *d
coffact PM before proceediCIg.
Receipt date(s) > 48 hours past the collection date(s)? lf yes, notif,v P^v?M.
Are aualyses with shoil holcing times requested?
Was a quick Tur.n Around [AT) requested?
tr
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STL l)enver
Sample Receiving Checklist
Lot #
Sufficicil r,olunr providcd for all ana);,sis rcqucstcd? (rcf Aruchment D of SOP# DEN-QA-0003) lf no,
documont on CUR, and conlacl PM hcfore;uocecding
,F D l9- Is sufficicnt volume provided for clicnt rcguestcd MS, h4SD or nutrix duplioares'.r If no, documcnl on CUR, and
wntact Ph4 bcforc procccding-
.{) D 20. Did the chain ofcustody includes "receivcd b)r'arrd "rrlinquished" by sigrraturcs, dalcs, and timer?
A tr 2l . Werc special log in inshlclions read and followcd'/
D t D. Wrrre AFCEE motals loggcd for rcfrigerated storagc'/
t.{ tr 23. Werc tess loged c}recksd agains thc COC? Ilhich samples were cortfirmed? I
A g 24. \[,as a Rush forsr corrp]etcd for guick TA1?
n tr 25. \lrasa ShortHoldformcorrplcted foranl,ehortholds?
D ,{ zs. Is "suia lCoc-rcquircd?
tr ,l ,1. Tierc special a'chiving insmrctions indicalcd il the General Commcnts? If so, u&al were the1,?
beliug aDd Storage Che&s:
t-l
d
,d
I
O
La Initials
,_tr
,{'-7 !
yrr
28. Was tbe srbcontact COC signcd and sent with saryles to trottle prcp?
29. \tr,cre sanple lab:Js double-dreclrcd by a second persoa?
30. WerE narylc botics and COC doublc checked for dissolved/fhsrcd mehls by a secoud porson?
31. Did tbc sarnplc ID, Date, and Time fiom label matcb u'hat uas logged?
32. Werc stick.crr for rpecial archir,fug jastruclions affixed to each bol and to thc ICOC? See #27
33. Were AFCEEmehls storcd refiigerrtcd?
.14, \l,erc "Stna ICOC'copies given to xatellite slora-gc areas'l
.,{* E f
{a
trrrtr tr
SD tr
Documenl anyproblems or discrepancies and the actions tal<en to re.solve them on a Condition Upon Rrceip Anomaly
Rcport (Ct R).
STL Denver
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Northern Analytical
Data Package
Hafnium and Thiocyanate Analyses
Notq Data Packages are in order as discussed in the Data Validation Report (see Appendix C):
Data Package 2005090102
NOBTHEBNi
REPORT TO:
602 South 25th Street
P O Box 3A315
Billings, MT 59107
Telephone: (406) 25+7226
Fax: [phone]
DATE: October 19, 2005ATTN: JEFF PORTER
URS CORPORATION
756 EAST WINCHESTER STREET, SUITE 4OO
SALT IAKE CITY, UT 84107
Water Analysis - WestemZrooniurn, 3rd Quarter 2005
JOB NUMBER:
PAGE:
INVOICE NO-:
96-904-35
1 of 173
50901 02
REPORT OF:
CASE NARRATIVE:
On September 13, 2005, these water samples (laboratory numbers 2005090102-1 through -37) were received in
our laboratory for analysis. The samples were received cooled, at 0.6" C, and properly preserved.
The samples were anallzed for total hafnium and thiocyanate- The hahium analysis was conducted in accordance
with EPAI600/R-9+111 'Methods for the Determination of Metals in Environmental Samples" Supplement l,
method 200.8. The thiocyanate analysis was conduc{ed in accordance with "Standard Methds for the
Examination of Water and Wastewater" 18* Edition, method 4500-CN-M.
Thiocyanate - The samples were analyzed using the colorimetric procedure identified above on September
28,2005, within the 284ay holding time. The samples, method blank, lab control sample and matrix spikes
were treated with ferrous sulfate to remove hexavalent chromium interferences, filtered, treated using a
macroreticrrlar resin column to remove organic and color interferences, then the thiocyanate was measured
colorimetrically. The spectrophotometer was calibrated using a blank and three to four standards. The
calibrations were linear and verified by the analysis of an initial calibration verilication standard prepared from a
separate source (identified as QCS in raw data). A method blank, lab control sample (LCS), matrix spike (MS)
and matrix spike duplicate (MSD) samples were analyzed with the batch. The results of analysis of the quality
control samples met acceptance criteria. The sample concentrations are reported without qualification.
Hafnium - Total hafnium was determined from an unfiltered, acid preserved aliquot of each sample. The total
hafnium samples were acid digested using EPA method 30204 then analyzed using an inductively coupled
plasma mass spectrometer (ICPMS) method 200-8. The samples were digested in two batches on September
22,2005 (digest batches 1666 and 1667). A method blank, LCS, and two MS/MSD pairs were digested and
analyzed with each batch.
Both batches of samples were analyzed on September 23, 2005. Because of our experience with samples from
this project, the analyst made dilutions of I part sample to 9 parts reagent grade water (10X dilution) of all
natural and quality control samples before analysis. The recovery of the LCS for Batch 1666 was outside the
quality control criteria. The LCS was analyzed again from a fresh aliquot prepared for the instrument from the
LCS digestate prepared when the batch was digested. Upon this analysis, the quality control indicators for
Batch 1666 met the quality control criteria. However, the analyst was conoerned that sample concentration
measured for "SWB-910-090105" was the result of analytical system contamination from the LCS. For "SWB-9-
090105", the intemal standard recovery was below the method acceptance criteria. For these reasons, the
data for these two samples was rejected and the samples were to be analyzed again at a later date. The
analysis of all samples in Batch 1667 was rejected due to low recovery of the LCS of Batch 1667.
The samples "SWB-910-090105" and "SWB-9-090105", the quality control samples ftom Batch 1666 and all of
Batch 1667 were analyzed again on September 26,2OOS using a dilution factor of 50. The data was rejected
as the method blank contained hafnium at 0.7u9/l which resulted in false positive concentrations when the 50
dilution factor was applied. ln addition to the method blank concentration, the recovery of hafnium in the LCS
for Batch 1667 did not meet the quality control limits.
All the natural samples and the quality control samples from Batch 1666 and Batch 1667 were analyzed on
September 28,2005 using a dilution factor of 10. The quality control samples for Batch 1666 met the quality
control criteria. However, the analyst was concemed that sample concentration measured for "SWB-910-
090105" was the result of analytical system contamination from the LCS and again (as on September23) for,
the internal standard recovery was below the method acceptance criteria. Sample concentrations from this
analysis for all samples in Batch 1666 except for "SWB-910-090105" and "SWB-9-090105" are reported herein.
Page la ot 172
October 19,2005
For Batch 1667, the LCS recovery was below the acceptance criteria. As a conective action, as a result of the
low LCS recovery of Batch 1667 on three separate oocasions, the natural samples and quality conhol samples
from Batch 1667 were digested again in Batch 1698.
Batch 1698 was analyzed on October 11 using dilution factors for all samples of 10. The LCS recovery did not
meet the control limits and the data was rejected. On October 18, 2005 the samples "SWB-910-090105" and
"SWB-9-090105", the quality control samples from Batch 1666 and all of Batch 1698 were analyzed again using
dilution factors of 20 for all natural and qc samples with the exception of "SWB-9{9010$. The results of the
analysis of the quality control samples met our quality control criteria. The sample concentrations trom this
analysis are reported herein without qualification.
Our method detection limit (mdl) for total hafnium by Method 200.8 is 0.0002 mgfl. Using a quantitation or
reporting limit of two times the mdl, a reporting limit for samples analyzed with no diluition would be 0-0004.
Therefore, for samples with a dilution factor of 20, the resultant reporting limit for Batc*r 1698 samples of 0.01
mg/l is defendable. For samples diluted by a factor of 50, the reporting limit is 0.02 mg/|. Our method
detection limit study summary is induded on page 173.
The sample results, QC sample results, QC forms and raw data are presented in the order as listed below.
Table of Contents
Case Narrative
Sarnple Results, Quality Control Sample Results
Quality Control Forms
Chain of custody, Sample Receipt Checklist
Raw Data
Total Hafnium analysis, 9l2AA5
Total Hafnium analysis, 10118/05
Metals Digest Logs
Thiocyanate analysis, 9128105
Method Detection Limit Study
Page No.
1
2-13
14-20
21-25
26-144
105-166
167-169
170-172
Page 173
Reviewed by
As a mutual protection to clients, the public and ourselves, all reports are submitted as the confidential property of our clients and authorization
for publication of statements, conclusions or extracts from or regarding our reports is reserved pending our written approval. Test results apply
specifically to the samples tested only. The entire report shall not be reproduced, except in full, without the written approva! of the laboratory.
Samples will be disposed of after testing is completed unless other arrangements are agreed to in writing
Kathleen A. Srnit - Laboratory Manager
Northern Analytical Laboratories, Inc.
Client Name: URS CORPORATION
Proiect No.: 24584461-A2
Oroi."t Name: WESTERN zlRCoNlUM
Collected by: SAGE EVANS
Date Received: 09/1 AZAAS
Matrix:WATER
Order No.: 2005090102
Page 2
Sample
Number Description
Date Measured
Collected Value
Test
Units
Test PQL Date of
Method Value Analysis
Hafnium as Hf (Total)
1 swB-910-090105 09/01 i2405 0.02 mg/l 200.8 0.01 fit1812005
2 swB-9-090105 owau2005 0.03 mg/l 200.8 0.01 14n812045
3 swB-10-090105 09/01 t2005 <0.01 mg/l 200.8 0.01 09128t2005
swB-3-090105
5 swB-7-090105 09/01 12AAS <0.01 mg/l 200.8 0.01 49n8i2005
6 GW-R1-090205 49nu2005 <0.01 mg/l 200.8 0-01 09t28t2005
7 GW-S9-090205 09t42t2005 <0.01 mg/l 200.8 0.01 wt2812005
I GW-S8-09020s a9rczD005 <0.01 mg/l 200.8 0.01 09D812005
GW-S7-090205
Northern Analytical Laboratories, Inc.
Glient Name: URS CORPORATION
Proiect No.: 24584461-02
Project Name: WESTERN ZIRCONIUM
Gollected by: SAGE EVANS
Date Received: 09/1 312005
Matrix: WATER
Order No.: 20050901A2
Page 3
Sample
Number Description
Date Measured
Collected Value
Test
Units
Test PQL Date of
Method Value Analysis
Hafnium as Hf (Total)
10 GW-64-0902A5 0910212005 <0,01 mg/l 200.8 0.01 a912812005
11 GW-68-0902A5 0910212005 <0.01 mgll 200,8 0.01 a9n8/2005
12 GW-BA-090605 09/06t2005 <0.01 mg/l 200.8 0.01 09t28t200s
13 GW-7A-090605 09106t2005 <0.01 mg/l 200.8 0_01 ost28tZI
14 GW-BB-090605 awa6l2005 <0.01 mg/l 200.8 0.01 0912812005
15 GW-Sg1-090705 091a7t2005 <0.01 mg/l 200,8 0.01 09t28t2005
16 GW-S10-090705 09t07t2005 <0.01 mg/l 200.8 0,01 4912812005
17 GW-SI-090705 49n7D005 <0.01 mg/l 200.8 0_01 0912812005
GW-S1 1-090705 a9t28t2005
Northern Analytical Laboratories, lnc.
Glient Name:
Proiect No.:
Ot.,rec-r Nairre;
Collected by:
Date Received:
Matrix:
Order No.:
Page 4
URS CORPORATION
24584461-42
WESTERN ZIRCONIUM
SAGE EVANS
09/13/2005
WATER
20050901 02
Sample
Number Description
Date Measured
Collected Value
Test
Units
Test PQL Date of
Method Value Analysis
Hafnium as Hf (Total)
19 GW-S2-0907A5 4910712005 <0.01 mg/l 200.8 0.01 a9n812005
20 GW-S3-090705 o9to7t2005 <0.01 mg/l 200.8 0.01 09n812005
21 GW-N2-090705 09t07 t2005 <0.01 mg/l 200.8 0.ol 10t18t2005
GW-sC-090805
23 GW-R2-090805 09t08t2005 <0.01 mg/l 200.8 0.01 10t18/2445
24 GW-S5-090805 09t08t2005 <0.01 mg/l 200.8 0.01 10t18t2005
25 GW4A-090805 09n8t2005 <0.01 mgll 200.8 0.01 10118t2005
26 GW-S4-090805 09to8t2005 <0.01 mg/l 200.8 0.o1 fit18i2405
GW-R4-090805 10118t2005
Northern Analytical Laboratories, lnc.
Client Narne:
Proiect No.:
Proiect Name:
Gollected by:
Date Received:
Matrix:
Order No,:
Page 5
URS CORPORATION
24584461-02
WESTERN ZIRCONIUM
SAGE EVANS
09/13/2005
WATER
20050901 02
Sample
Number Description
Date Measured
Collected Value
Test
Units
Test PQL Date of
Method Value Analysis
Hafnium as Hf (Total)
28 GW-R3-090805 a9rc$12005 <0.01 mg/l 200.8 0.01 10t18na05
29 GW-N91-090905 49rcgD005 <0.01 mg/l 200.8 0.01 1An8l2005
30 GW-N1-090905 09t09t2005 <0.01 mg/l 200.8 0.01 10t18/2005
31 GW-58-090905 49n9n005 <0.01 mgll 200.8 o.01 rotLe
32 GW-5D-090905 aw09t2005 <0.01 mg/l 200.8 0.01 14t18t2405
33 GW-S6-090905 a9rcgn005 <0.01 mgfl 200.8 o.o1 10t18/2005
34 GW-7C-090905 09rcgn005 <0.01 mg/l 200_8 0.01 10t18/2005
35 GW-8W92-091205 09/12t2005 <0.01 mgn 200.8 0.01 10t18t2045
GW-BWI-091205 1At18/2005
Northern Analytical Laboratories, lnc.
Glient Name:
Proiect No,:
q::i:::Jr:'
Date Received:
Matrix:
Order No,:
Page 6
URS CORPORATION
24584461-A2
WESTERN ZIRCONIUM
SAGE EVANS
09/1 312005
WATER
20050901 02
Sample
Number Description
Date Measured
Collected Value
Test
Units
Test PQL Date of
Method Value Analysis
Hafnium as Hf (Total)
37 GW-BW2-091205 09/1 A2AO5 <0.01 mg/l 200.8 0.01 10t1812005
38 MATRIX SP]KE OF 2OO5O9O1 A2-3 09/01 t2w5 95 Yo 175-1251 200.8 0.01 a9D8t200s
39 MATRIX SPIKE DUPLICATE OF
20050901 a2-3
09/01 t2005 3 RPD [0-201 200.8 0.01 49i28t2005
MATRIX SPIKE OF 2OO5O9O1 02-17 o/o 175-1251
41 MATRIX SPIKE DUPLICATE OF
2005090102-17
09n7n005 4 RPD [0-20]200.8 0.01 09t28t2005
42 METHOD BLANK <0.01 mgfl 200.8 0.01 a9n812005
43 ISBORATORY CONTROL SAMPLE 75 % 175-1251 200.8 0.01 09n8n005
44 MATRIX SP]KE OF 2OO5O9O1O2-30 09109t2005 90 o/o 175-1251 200.8 0,01 10t18/2005
MATRIX SP]KE DUPLICATE OF
2005090102-30
RPD [0-20]10t1812005
Northern Analytical Laboratories, lnc.
Client Name:
Proiect No.:
Proiect Name:
Collected by:
Date Received:
Matrix:
Order No.:
Page 7
URS CORPORATION
24584461-02
WESTERN Z]RCON]UM
SAGE EVANS
aw1a2a05
WATER
20050901 02
Sample
Number Description
Date Measured
Collected Value
Test
Units
Test PQL Date of
Method Value Analysis
Hafnium as Hf (Total)
46 MATRIX SPIKE OF 2005090102-37 09/12t2005 I % 175-1251 200.8 0.01 10t18/2005
47 MATRIX SPIKE DUPLICATE OF
2005090102-37
09/12nOO5 5 RPD [0-201 200.8 0.01 14n8i2005
48 METHOD BLANK <0.01 mg/l 200.8 0.01 10t18t2005
49 LABORATORY CONTROL SAMPLE 108 % 175-1251 200.8 0.01 .r,tlanl
Northern Analytical Laboratories, lnc,
Glient Name:
Proiect No.:
Ororecr Name.
Gollected by:
Date Received:
Matrix:
Order No.:
URS CORPORATION
24584461-02
WESTERN ZIRCONIUM
SAGE EVANS
09/1 312005
WATER
20050901 02
Page 8
sw8-3-090105 0912812005
GW-57-090205 45OOCNM a912812005
Sample
Number Description
Date Measured
Collected Value
Test
Units
Test PQL Date of
Method Value Analysis
Thiocyanate as SCN
1 swB-910-090105 09/01 12005 3.28 mg/l 45OOCNM 0.05 a9n8/2005
2 sw8-9-090105 09101 12005 13.8 mg/l 45OOCNM 0.05 a912812005
3 swB-10-090105 09/01 /2AO5 3.34 mg/l 45OOCNM 0.05 0912812005
5 swB-7-090105 09/01 12005 0.33 mg/l 45OOCNM 0.05 0912812005
b GW-R1-090205 091aat2005 <0.05 mgll 45OOCNM 0.05 a9n8l200s
7 GW-S9-090205 09n2t200s <0.05 mg/l 4sOOCNM 0.05 09128t2005
B GW-58-090205 09n2/2005 0.07 mg/l 4sOOCNM 0.05 0912812005
Northern Analytical Laboratories, lnc.
Glient Name: URS CORPORATION
Project No.: 24584461-02
Project Name: WESTERN ZIRCONIUM
Collected by: SAGE EVANS
Date Received: 09/1 3l2AA5
Matrix: WATER
Order No.: 200509A1A2
Page 9
Sample
Number Description
Date Measured
Collected Value
Test
Units
Test PQL Date of
Method Value Analysis
Thiocyanate as SCN
10 GW-6A-090245 awa2l2005 2.34 mg/l 4sOOCNM 0.05 0912812005
11 GW-68-090205 a910212005 7.68 mgll 4sOOCNM 0.05 49t28t2005
12 GW-8A-090605 09/06/2005 <0.05 mg/l 4sOOCNM 0,05 a912812005
13 GW-7A-090605 09/06/2005 5.03 mgll 4sOOCNM 0.05 ost28t2e
14 GW-BB-090605 owa6n005 0.10 mg/l 45OOCNM 0.05 0912812005
15 GW-Sg1-0907A5 a91071200s 0.83 mg/l 45OOCNM 0.05 09t28t2005
16 GW-S10-090705 091a712005 4.17 rngll 4sOOCNM 0.05 091281200s
17 GW-S1-090705 49rc71200s 0.88 mg/l 4SOOCNM 0.05 0912812005
GW-SI 1-090705 45OOCNM 0912812005
Northern Analytical Laboratories, lnc,
Glient Name:
d;::: xl;",
Gollected by:
Date Received:
Matrix:
Order No.:
Page 10
URS CORPORAT]ON
24584461-A2
WESTERN ZIRCONIUM
SAGE EVANS
09/1 3nA05
WATER
20050901 02
Sample
Number Description
Date Measured
Collected Value
Test
Units
Test
Method
PQL Date of
Value Analysis
Thiocyanate as SGN
19 GW-52-090705 aw0712005 2.53 mg/l 4sOOCNM 0.05 09t2812005
2A GW-53-090705 awa712005 4.22 mg/l 4sOOCNM 0,0s 09t2812005
GW-N2-090705 09147/2005 au2812005
GW-5C-090805 owa&12005 45OOCNM
23 GW-R2-090805 a9tau2005 0.82 mg/t 4sOOCNM 0.05 09t28t2005
24 GW-55-090805 0910812005 4.29 rng/l 4sOOCNM 0.05 a9t2812005
25 GW-4A-090805 awa8l200s 0.62 mg/l 4sOOCNM 0.05 09t2812005
26 GW-S4-090805 0910812005 4.47 mg/l 4sOOCNM 0.05 09t28t2005
GW-R4-090805 09t2812005
Northern Analytical Laboratories, lnc.Page 11
Glient Name:
Project No.:
Project Name:
Gollected by:
Date Received:
Matrix:
Order No.:
URS CORPORATION
24584461-42
WESTERN ZIRCONIUM
SAGE EVANS
09113/20a5
WATER
20050901 02
Sample
Number Description
Date Measured
Gollected Value
Test
Units
Test PQL Date of
Method Value Analysis
Thiocyanate as SCN
28 GW-R3-090805 09/08/2005 0.25 mg/l 45OOCNM 0.05 a912812005
29 GW-N91-090905 09/09/2005 0.17 mgll 4sOOCNM 0.05 0912812005
30 GW-N1-090905 09/09/2005 0.12 mg/l 4sOOCNM 0.05 0912812005
31 GW-58-090905 09/09/2005 4.71 mg/l 4sOOCNM 0.05 ost28t2e
32 GW-5D-090905 09/09/2005 1.34 mgn 4sOOCNM 0.05 09t28t2005
33 GW-56-090905 09/09/2005 0.92 mg/l 45OOCNM 0.05 0912812005
34 GW-7C-090905 09t0912005 0.10 mg/l 4sOOCNM 0.0s 091281200s
35 GW-8W92-091205 09/1 2t20A5 0.43 mgll 4sOOCNM 0.05 09t28t2005
GW-BW1-091205 09/1 212005 4sOOCNM a912812005
Northern Analytical Laboratories, lnc.
Glient Name:
Proiect No.:
Q::i:::Jr:'
Date Received:
Matrix:
Order No,:
Page 12
URS CORPORAT]ON
24584461-O2
WESTERN ZIRCONIUM
SAGE EVANS
09/1 3t2005
WATER
20050901 02
Sample
Number Description
Date Measured
Gollected Value
Test
Units
Test PQL Date of
Method Value Analysis
Thiocyanate as SCN
37 GW-BW2-091205 09/1A2AA5 0.40 mg/l 4SOOCNM 0.05 09t28t2005
38 MATRIX SPIKE OF 2OO5O9O1A2-3 o9n1i2005 NA 0.05
39 MATRIX SPIKE DUPLICATE OF
20050901 02-3
09/01 naas NA 0.05
MATRIX SPIKE OF 2OO5O9O102-17 o/o 175-1251
41 MATRIX SPIKE DUPLICATE OF
20050901 02-17
auo7t2005 2 RPD [0-20]4500cNM 0.05 49n812005
42 METHOD BLANK <0.05 mg/l 4500cNM 0.05 a9n8/2005
43 LABORATORY CONTROL SAMPLE 90 o/o 175-1251 4SOOCNM 0.05 49n8i2005
44 MATRIX SPIKE OF 2005090102-30 09t0912005 94 o/o 17.5--1251 4SOOCNM 0.05 09t28t2005
MATRIX SPIKE DUPLICATE OF
2005090102-30
Northern Analytical Laboratories, lnc.
Client Name:
Proiect No.:
Proiect Name:
Gollected by:
Date Received:
Matrix:
Order No.:
Page 13
URS CORPORATION
24584461-02
WESTERN ZIRCONIUM
SAGE EVANS
09/13/2005
WATER
20050901 02
Sample
Number Description
Date Measured
Collected Value
Test
Units
Test PQL Date of
Method Value Analysis
Thiocyanate as SCN
46 MATRTX SPrKE OF 2005090102-37 09/12t2005 100 o/a 175-1251 4sOOCNM 0.05 09t2812005
47 MATRIX SP]KE DUPLICATE OF
20050901 02-37
09/12t24O5 2 RPD [0-20]4500cNM 0.05 49i28t2005
48 METHOD BLANK <0.05 mgfl 45OOCNM 0.05 a9i2812005
49 LABORATORY CONTROL SAMPLE 96 % 175-1251 45OOCNM 0.05 ostzutze
Lab Name: Northern Analytical Laboratories, Inc.
Initial Calibration Standard Source:
INITIAL AND CONTINUING CALIBRATION VERIFICATION
SDG No.: 2005090102
Calibration Verifi cation Source :
Page 14
Spex Lot# 9-l32HF
Baker Potassium Thiocyanate Lof# 31038
Inorganic Ventures Lot# W-HF01028
Acros Potassium Thiocyanat e Lot# 42$0450
- Hafnium
- Thiocyanate
- Hafnium
- Thiocyanate
Units: mgl
Analvte
Initial Calibration
Verification
Continuing Calibration Verifi cation Method Date
True Found %R True Found I %R Found 2 %R
Hafnium - Total (Batch 1666)0.0400 0.041 I 103 0.0500 0.0551 I I0 0.0536 t()7 200.8 9t28t0s
(200509UA2-l through 20)Found 3 %R Found 4 %R
0.0500 0.0536 It)7 0.054 r r08 200.8 9/28t0s
Found 5 %R Found 6 %R
0.0s00 0.0s43 109 0.0537 ta7 200.8 9t28t05
Found 7 %R Found 8 %R
0.0s00 0.0539 l0.g 200.8 9t28t05
True Found %R True Found I %R Found 2 %R
Hafnium - Total (Batch 1698)0.0400 0.0406 102 0.0500 0.05 r 2 I t)2 0.0492 9ti 200.8 r 0/ I 8/05
f0050901 02-21 throueh 37)Found 3 %R Found 4 %R
I050901A2-l and 2 reruns)0.0500 0.0500 l0t)0.0501 r00 200"8 I0/18/05
t-Found 5 %R Found 6 %R
0.0500 0.0499 I t)0 0.0s 10 ta2 200.8 ta/18/05
Found 7 %R Found 8 %R
0.0500 0.0509 102 200.8 taltS/05
True Found %R True Found I %R Found 2 %R
Thiocyanate 0.40 0.38 95 0.50 0.51 ta2 0.50 r00 4500-cN-M 9/28/05
(20050901 02-l through 37)Found 3 %R Found 4 %R
0.50 0.48 96 0.52 I04 4500-cN-M 9t28/05
Found 5 %R Found 6 %R
0.50 0,5 t 102 0.s2 104 4500-cN-M 9/28/0s
Found 7 %R Found 8 %R
0.50 0.52 104 0.52 I04 4500-cN-M 9/2810s
Comments:NA - Not Analyzed
Page 15
BLANKS
Lab Name: Northern Analytical Laboratories, Inc.
Units: mgll
SDG No.: 2A050901A2
Matrix: Water
Analyte
Initial
Calibration
Blank
Continuing Calibration Blank Prep.
Blank Method Date a
t 2 3
Hafnium - Total (Batch 1666)<0.001 <0.001 <0.001 <0.001 <0.01 200.8 9l28l0s
4 5 6
<0.001 <0.001 -il <o.oot 200.8 9l28l0s
cc64 fl i,r-i U\ Vtr,tcltgl0 )
I 2\J aJ
Hafrrium - Total (Batch 1698)<0.001 <0.001 <0.001 <0.001 <0.01 200.8 tOlt8/05
4 5 6
<0.001 <0.001 <0.001 200.8 t0/18/05
I 2 3
Thiocyanate <0.05 <0.05 <0.05 <0_05 <0.05 4500-cN-M 9l28l0s
(20050901 02-1 throueh 20)4 5 6 -<0.05 <0.05 <0.05 4500-cN-M 9l28l0s
7 8 9
(20050901 02-21 throueh 37)<0.05 <0,05 4500-cN-M 9n8las
Comments:
Page t6
AQUEOUS LABORATORY CONTROL SAMPLE
Lab Narne: Northern Analytical Laboratories, Inc.
LCS Source:
- Hafnium
- Thiocyanate
Comments:
SDG No.: 2A05090102
Units: mgll
Inorganic Ventures Lot# W-HF01028
Acros Potassium Thiocyanate Lot# 4243005A
Analyte Expected Found %R Control
Limits
Method a
Hafrrium - Total (Batch 1666)0.500 4374 75 75 - 125 200.8
Hafrrium - Total (Batch 1698)0.500 0.s38 r08 75 - 125 200.8
Thiocyanate 0.50 4.45 90 75 - 125 4500-cN-M
(20050901 02-l through 20)
Thiocyanate 0.50 0.48 96 75 125 4500-cN-M
(20050901 A2-21 tluoush 37)
Page t7
Lab Name: Northern Analytical Laboratories, Inc.
MATRIX SPIKE /MATRIX SPIKE DUPLICATE RECOVERY
SDG No 2005090102
Parent Sample ID:2005090 I 02-3, SWB-I 0-0901 05
20050901 02- I 7, GW-S I -090705
2005090 I 02-30, GW-N I -090905
2005090 I 02-37, GW-BW2-09 I 205
I
2
3
4
Units:rngll
Analyte
Parent
Sample
Result
Spike
Added
MS
Spike
Added
MSD
MS
Result
%R
MSD
Result
%R
RPD
Limits
0-20
Control
Limits
%R Method a
Haftrium - Total (Batch 1666) t 0.000 0.500 0.500 a.477 95 a.46t 92 3.4 75 125 200.8
Hafrrium - Total (Batch 1666)2 0.000 0.500 0.s00 0.491 98 0.474 95 3.5 75 125 200.8
Hafnium - Total (Batch 1698) 3 0.000 0.500 0.500 0.491 98 0.538 108 9,1 75 125 200.8
Hafirium - Total (Batch 1698) 4 0.000 0.s00 0.500 0.449 90 0.473 95 5.2 75 t2s 200.8
Thiocy anatez 0.84 0.50 0.50 1.28 88 1.30 92 1.6 75 125 4500-cN-M
Thiocyanate 3 0.1 1 0.50 0.s0 0.s8 94 0.55 88 5.3 75 t2s 4s00-cN-M aThiocyanate a 0,38 0.50 0.50 0-88 r00 0.90 104 2.2 7s - 125 4500-cN-M
Comments:Note - The thiocyanate sample results have been adjusted for the dilution caused by the amount of
spike added. 190 rnls of sample was used, plus l0 mls of spike, for a total volume of 200 mls in the
spiked sample. [0.88 * (190/200)J:0.84
Page 18INTERNAL STANDARD SUMMARY
Lab Name: Northern Analytical Laboratories, Inc.
SDG Number.: 2005090102
Comments: * - The intemal standard is below the QC limit. The sample was
reanalyzed.
Samples
9t29105
Internal
Standard
%R
a Samples
taltS/05
Internal
Standard
%R
a
Initial Calibration Verification 104.4 Initial Calibration Verifi cation 98.3
Cont. Calibration Verification 97.6 Cont. Calibration Verifi cation 99.2
Initial Calibration Blank 97.6 Initial Calibration Blank 99.3
1666 Method Blank 99.9 1666 Method Blank 98.5
1666 Lab Control Sample r0r.6 1666 Lab Control Sample l0r.r
20050901 02- I 7A.t 2005090 l 02- r 8r.3
200s090t02-2 47.1 *2005090 r 02- I 8l .5
2005090102-3 68.5 2005090 r 02- r 8t.2
Cont. Calibration Verifi cation 92.6 200s09}ta2-2 (x I 0dil)47.8 *
Cont. Calibration Blank 95. I 1666 Lab Control Sample 100.5
MS on 2005090102-3 69.7 2005090102-2 (x20dil)s9.2 *
MSD of 2005090102-3 70.0 200509at02-2 (x5Odil)74.9
2005090142-4 88.8 2005090102-2 (x5Odil)74"0
2005090 l 02-s 91.4 2005090ta2-2 (x5Odil)t3.a
2005090102-6 9s.2 Cont. Calibration Verifi cation 92.8
Cont. Cal ibration Verifi cation 92.1 Cont. Calibration Blank 92.0
Cont. Calibration Blank 94.4 1698 Method Blank 93.6
2005090t02-7 98.8 1698 Lab Control Sample 92.3
200s090 r 02-8 96.7 2005090t02-21 85. I
2005090t02-9 98.8 2005090142-22 86.0
2005090r02-10 87.3 2005094102-23 86. I
200s090102-r I 78.9 Cont. Calibration Verification 92.0
Cont. Calibrat on Verification 93.2 Cont. Calibration Blank 90. r
Cont. Calibrat on Blank 95.5 2A05090102-24 89.0
2005090102-12 97 .1 2005090102-25 87.3
2005090102-13 7t.4 2005090102-26 89.5
200509a102-14 96.s 2005094102-27 90.4
200s090102-15 90.8 2AA'090rA2-28 89.7
2005090r 02- r 6 94.3 Cont. Calibration Verifi cation 91.2
Cont. Calibration Verification 93.2 Cont. Calibration Blank 90. r
Cont. Calibration Blank 96.2 2005090ta2-29 90.5
2005090t02-t7 109.9 200s090r 02-30 90. I
MS on 2005094102-17 79.4 MS on 2005090102-30 90.8
MSD of 2005090102-17 92.7 MSD of 2005090102-30 89.0
2005090102-18 82.9 2005090 I 02-3 r 87.9
2005090102-19 72.8 Cont. Calibration Verifi cation 9r.0
Cont. Calibration Verifi cation 91.4 Cont. Calibration Blank 90.0
Cont. Calibration Blank 93.6 2005090102-32 89.0
200s094t42-20 93.7 2005090 r 02-33 88.9
Cont. Calibration Verification 96.8 200509al02-34 89.7
Cont. Calibration Blank 99.9 2005090102-3s 90.7
2005090 r 02-36 0 *
Control Limits 60 - t25 Control Limits 60 - 125
PageINTERNAL STANDARD SUMMARY
Lab Name: Northern Analytical Laboratories, Inc.
SDG Number.:200s0901 02
Samples
Internal
Standard
%R
a Samples
rclt8/05
Internal
Standard
%R
a
MS on 2005094142-37 90.8
MSD of 2005090102-37 lll.0
Cont. Calibration Verification I14.4
Cont. Calibration Blank I r8.r
2005090102-2t 107.0
2005090 r 02-3 r I13.6
2005090t02-36 1 08.1
2005090102-37 I I5.8
Cont. Cal bration Verification r 18.7
Cont. Cal bration Blank I I9.I
Control Limits 60 - t25
Comments:
Page 20
HOLDING TIME SUMMARY
Lab Name: Northern Analytical Laboratories, Inc.
Comments:
SDG No.: 2005090102
* - The earliest date sampled is listed to demonstrate holding time compliance.
NA - Not applicable
Analyte Date
Collected
Date
Digested
or
Prepared
Date
Analyzed
Max.
Holding
Time (days)
Time Held
(days)Method
a
Hafnium - Total (Batch 1666)9/U05*9l22l0s 9l28l0s r80 28 200.8
Hafnium - Total (Batch 1698)glu05*9129105 ta/18/05 r80 47 200,8
Thiocyanate 91U05*9l2t l0s 9l28l0s 28 28 4500-cN-M
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TOETHEIIil
SAMPLE RECEIPT CHECKLIST
Page 25
Client Name
Project
Dear Valued Clienr This checklist documents the condition of your sample(s) as it (they) arrived at our lab. Please review it and familiarize yourf *r
its contents. Should you have any questions or comments, please contact us. Thank you for your use of our services. V
Date/Time Received 7// or't ! ': (
Date I Time
Received by
Carrier Name
Sarnple Type
Laboratory Number(s) C
"nChecklist Completed by
./2'/)5., 7
/rrtInitials
1.
2.
3.
4.
5.
6.
Shipping container in good condition?
Custody seals present gn shipping container?
Condition: Intact ;{ Broken
Chain of custody present?
NO
tZ
14. pH check performed uy, il U
15. Metals bottle(s) pH <2?:
. - :
16. Nutrient bottle(s) pH <2?
17. Cyanide bottle(s) pH >12?
18. Sulfide bottle(s) pH >9?
19. TOC bottle(s) pH <2?
24. Phenolics bottle(s) pH <2?
2l . Oil & grease bottle(s) pH <2?
(checked by analyst)
22. EPH/DRO bottle(s) pH <2?
(checked by analyst)
23. Volatiles (VOA) pH <2?
(checked by analyst)
24. Semivolatiles (525) pH <2?
(checked by analyst)
?5. Other test types
28. Date contacted
YES NO
Chain of custody signed when relinquished
and received?
Chain of custody agrees with sample labels?
Custody seals on sample bottles?
container? (circle one)
container temperature ,r{-{a 2.
* (if <0 opl0)
I 1. All samples rec'd within holding time?*
I2. VOA vials have zera headspace?
* (if contains >5mm headspace)
I3. Trip Blank received?
NOTES:
I 26. Client contacted? !
27. Person contacted
{< Critical item - if marked (6NO" contact lab manager.
COMMENTS:
Condition: Intact Broken
7. Samples in proper container/bottle?* ,Z
8. Sample containers intact?* JZI
g- Sufficient sample volume for indicated test?x ,Z
@rozen Blue Ice present in shipping
4-t9r 3/*
Samples may be affected when not transported at the temperature recommended by the EPA for the test you've selected.
Please contact the lab if you have concerns about the temperature of -v*our samples.
.ry.p*{ct* Aco" y
Sample/Batch Report
User Name: Owner
Computer Name: ICPMS02
Sample File. C:\Elandata\Sample\092805-3.sam
Report Date/Time. Wednesday, September 28,2005 17:00:39
A/S Loc. Batch lD Sample lD Description
9 092805-3 3020A BLK X 10 BATCH 1666 DIG 9122 1030
10 092805-3 3020A STD 2.5 0F 10 )BATCH 1666 DIG 91221030
11 092805-3 090102-1 X 10
12 092805-3 0901A2-2 X 10
13 092805-3 090102-3 X 10
14 092805-3 090102-38 X 10 MS-3 zBATCH 1666 URS
ffi ggOlO}3gX IOMSD-3BATGH 1666URS
BATCH 1666 URS
BATCH 1666 uRS ''; a'-^ I
BATCH 1666 URS
30 092805-3 0901 A2-4A X 10 MS-17 BATCH 1666 URS
31 092805-3 0901A241 X 10 MSD-IBATCH 1666 URS
16 09280s-3 0901024 X 10
17 092805-3 090102-5 X 10
18 092805-3 090102-6 X 10
19 092805-3 0901A2-7 X 10
20 092805-3 0901 A2-B X 10
21 09280s-3 090102-9 X 10
22 092805-3 090102-10 X 10
23 092805-3 0901 02-11 X 10
24 092805-3 090102-12 X 1A
25 092805-3 0901 A2-13 X 10
26 092805-3 0901 A2-14 X 10
27 092805-3 0901 02-15 X 10
28 092805-3 0901A2-16 X 10
29 092805-3 0901A2-17 X 10
32 092805-3 090142-18 X 10
33 092805-3 090102-19 X 10
37 092805-3 0901 A2-21 X 10
38 092805-3 0901A2-22 X 10
39 09280s-3 090102-23 X 10
40 092805-3 0901A2-24 X 10
41 092805-3 0901 02-25 X 10
42 092805-3 0901 A2-26 X 10
43 092805-3 0901A2-27 X 10
44 09280s-3 090102-28 X 10
45 092805-3 0901 A2-29 X 10
46 092805-3 090102-30 X 10
49 092805-3 0901 A2-31 X 10
50 092805-3 0901 A2-32 X 10
51 09280s-3 090 rc243 X 10
52 092805-3 090102-34 X 10
53 092805-3 090102-35 X 10
54 092805-3 090102-36 X 10
55 092805-3 090102-37 X 10
BATCH 1666 URS
BATCH 1666 URS
BATCH 1666 URS
BATCH 1666 URS
BATCH 1666 URS
BATCH 1666 URS
BATCH 1666 URS
BATCH 1666 URS
BATCH 1666 URS
BATCH 1666 URS
BATCH 1666 URS
BATCH 1666 URS
BATCH 1666 URS
BATCH 1666 URS
BATCH 1666 URS
BATCH 1666 URS
BATCH 1667 URS
BATCH 1667 URS
BATCH 1667 URS
BATCH 1667 URS
BATCH 1667 URS
BATCH 1667 URS
BATCH 1667 URS
BATCH 1667 URS
BATCH 1667 URS
BATCH 1667 URS
BATCH 1667 URS
BATCH 1667 URS
BATCH 1667 URS
BATCH 1667 URS
BATCH 1667 URS
BATCH 1667 URS
BATCH 1667 URS
34-092B*05-3Q9_0J'Lz:?9x1q--_-jA@l221040
35 092805-3 3020A BLK X 10 BATCH 1667 DIG 9122 1040
36 092805-3 30204 STD X 10 2.5 oIBATCH 1667 URS ' r-tj .{. Ct n-/\'t"-ivryt
h, 1 L{'\ to'"'l
l' ,-.)>. r
,h0 irt t''( L'i '/'
\.
.: { (1 /^ 'r' 1'}' -'
,
,l{.0r'(cic\
47 092805-3 0901A244 X 10 MS-31 BATCH 1667 URS
48 092805-3 090fi245 X 10 MSD-3BATCH 1667 URS
56 09280s-3 090102-46 X 10 MS-37BATCH 1667 URS
57 092805-3 0901 02-47 X 10 MSD-3BATCH 1667 URS
&ilrlly- ef.Filo{26
Vo{rtts l+{S{t s?bc
Ertrcrto uv rurf qK $7r; i
ry )?rr /o-b lf -J- (a0 5'7oz
lnit. Quant. Prep. Vol.
REYIE_WED--
BY Mr
DATE:t0. iQ L)
rq6ql#1,;
Aliquot Vot.
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1,000
1.000
1.000
1.000
1.000
Diluted Vol
10.00r
10-oof
10.00r
10.00r
10.00r
10.00r
10.00,
10.00'
10.00'
10.00'
10.00
10.00
10.00
1 .000 10.00
1.000 10.00
1 .000 10.00
1 .000 10.00
1.000 10.00
1 .000 10.00
1 .000 10.00
1 .000 10.00
1 .000 10.00
1 .000 10.00
1 .000 10.00
1 .000 10.00
1 .000 10.00
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1 .000
1.000
1 000
1.000
1.000
1.000
1.000
1.000
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10 00
10.00
10.00
10.00
10.00
10 00
10.0c
10.0c
10 0c
10 0c
10 0c
10 0c
10 0c
10 0c
Page 1
NC No.
ANALYTICAL NON-CONFORMAI\ CE
Page 27
Test: AD\,? # I DateAnalyzed: -N %3 Analy rr' &i4 O
Samples Affected: 040 'nA
Clients Affected /,t fls
Non-Conformance: (Check all that apply)
(Describe non-conformance at right)
Initial calibration not acceptable
- - --CgY o. CCC/SPCC's out of control
X LFBrr@rutofcontrol B l(r(r+ 'rd-
Blank out of control
Dupticate out of control
X Spike out of control B ttr 6+ ,,-^*-
Surrogates out of control
Compounds outside calibration range
Other (describe at right) -T S oortX
/
ogo i0e *,4
a
Non-Conform a nce Respons e :
(Analyst, indicate your response to the non-conformance)
Reanatyze@ilatch O'?o to?-a X to/Kro
;Dbatch B ir;?
To QA officer for response guidance
Other (describe at right)
Accept data with report flags
Accept d ata without report flags
\- XZclta r/olo I o)(^t r r)
Comments:
AnaIysUDate:
QA OfficerlDfie:d; ,ilU lt4 '/ rL l-
lilrn : typi n g\forrn s\n oirton fo nn an ce
Page 28
o
ICP-MS QADATAREVIE,W
MET moo fu ,4 uATC ru* I te,bbO lvALrrsr fril,rUDATE, fkeU
iblot 6
Comments:ilr
{lt',,'OC -lc'L-U Date
Revierve.d
Revierver's
Initials
PEER REVIEW (Calc. )I l'Z;//c*j 'J f;
QA DATA REVIEW -)
REPORTED IN VLP
VLP REVIEW
200.8 6020
QCS STD 1
(ICV)e0-110% oL-90-na%
QCS STD 3
(ccv)
Every l0 Sarnples
90- ttB% 6L-90-trO%
QCS STD 4
(rcB oRCCB)
CCB Every l0 Samples
CCB<IDL
ICSA NA No Specific Limits
ICSAB NA No Specific Limits
Suggested: 80-}2A%
LRB
Every 20 Saurples
4.2 X MDL OR<l07oAnalyte
Conc-
<2-2 X MDL OR <l07oAnalyte
Conc.
QCS STD 5
(LFB)
Every 20 samples
6 dL- @'4-L-Y g;Ytyo 7542€85-Lts%
Duplicates
Every l0 samples .\- <20RPD <2ORPD
Matrix Spikes (LFM)
(MS orMSD)
Every lO samples
( cl( 1512; t/
Actuaa-r*, '?7 5-1250.
Internal Standards
/ t , -6fci cz-z g'1;ru/ ^/\'- 60-125%30- 1200.
Dilution Test
If analyte conc. >100 x BIk I + 4 Dilution
90-rt0%
I + 4 Dilution
90-r10%
One for every 2A samples
/-,,
Nonconformance attact e/ Yesl No\*.'/
Page 29
METHOD 200.8 SUMMARY REPORT
Sample lD: Blank
Sample Dateff ime: Wednesday, September 28, 2OO5 17 :45:40
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\Blank.448
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Analyte Mass Meas. lntens- Mean
Concentration Results
Net lntens. Mean Conc. Mean Conc. SD
[,Tb
Hf
Hf
Hf
Hf
Hf
159
176
177
178
179
180
549715.643
267.773
1227.719
1772.777
918.363
2346.M5
QC Calculated Values
tnt Std 7o Recovery Spike % Recovery Dilution % Ditt
Conc. RSD Sample Unit
ug/L
uglL
ug/L
ug/L
ug/L
ug/L
Dup- Rel. % Datt
[,
Analyte Mass QC Std 7o Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QC Out Of Limits
Out of Limits MessageMeasurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
Page
[,
METHOD 200.8 SUMMARY REPORT
Sample lD: Standard 1
Sample Dateffime: Wednesday, September 28, 2OO5 1 7:49:05
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: clelandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\Standard 1.449
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Conc. Mean
10.0000
10.0000
10.0000
10.0000
10.0000
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas- lntens. Mean
s89812.562
14585.235
52379.862
77439.6U
39228.8A7
141248.126
Net lntens- Mean
s89812.56
0.02
0.09
0.13
0.06
a17
Conc. SD
0.2275
0.0757
0.0738
0-0694
0.0646
Conc, RSD
2.27y
4.7574
a.7377
0.6938
o.6l}62
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
uglL
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurernent Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
QG Calculated Values
lnt Std % Recovery Spike % Recovery Dilution o/o Ditt Dup. Rel. "/o Ditf
QC Out Of Limits
Out of Limits Message
Page 31
METHOD 200.8 SUMMARY REPORT
Sample lD: Standard2
Sa mple Date/Time: Wednesday, September 28, 2OO5 17 :52:29
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\Stand ard 2.45A
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. lntens. Mean
587163.688
28396.500
101038.411
149587.195
75108.987
194915.248
Net lntens. Mean
587163.69
0.05
0.17
o.25
0.13
0.33
Conc. Mean
19.9495
19_9225
19.9270
19.8921
19.9134
Conc. SD Conc. RSD
0.1774
0.1590
0.0718
4.2274
0.0688
0.8891
0.7979
0.3602
1.1431
0.3456
Sample Unit
ug/L
ug/L
ug/L
uglL
ug/L
ug/L
[,
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Dltt Dup. Rel. % Ditf
QC Out Of Lirnits
Out of Limits Message
Page 32
METHOD 200.8 SUMMARY REPORT
Sample lD: Standard 3
Sample Date/Time: Wednesday, September 28, 2OO5 1 7:55:56
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: clelandata\Dataset\default\Standard 3.451
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Net lntens. Mean Conc. Mean
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. lntens. Mean
584306.137
139483.285
491414.370
72138/-107
365143.552
931856.244
58-4306.1T-
4.24
0.84
1.23
0.62
1.59
99.9651
99.9215
99.8802
99.9123
99.8353
Conc. S!
0.2694
0.5334
4.7705
1.2935
0.7662
Conc. RSD Sample Unit
ug/L
0.2695 ug/L
0.5338 ug/L
4.7715 ug/L
1.2946 ug/L
0.7675 ug/L
[,
QC Galculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. % Diff
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
QC Out Of Limits
Out of Limits Message
QG Action
QC Action Line: No QC out of limits detected
Page
METHOD 200.8 SUMMARY REPORT
Sample ID: QG Std I
Sample Dateff ime : Wednesday, September 28, 2AO5 1 7 :59:24
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method!200.8\hafniumall.mth
Dataset File: c:\elandata\DataseMefault\QC Std 1.452
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c\elandata\Optimize\default.dac
Analyte Mass Meas. Intens. Mean
57364.2.828
56174.5s7
198277.722
293235.8il
147545.380
378833.990
Net lntens. Mean
t
573642.83
0.10
0.34
0.51
o.26
0.66
Conc. RSD
0.8393
0.4836
0.4567
1.5612
1.8032
Sample Unit
ug/L
uglL
ug/L
ug/L
ug/L
ug/L
[,Tb
Hf
Hf
Hf
Hf
Hf
r59
176
177
178
179
180
43432
0.1978
0.18B2
0.6396
0.7426
Analyte Mass QC Std % Recovery
Tb 159
Hf 176 102.230
Hf 177 102.271
Hf 178 103.007
Hf 179 1A2.42A
Hf 180 102.960
Dup. Rel. % Dift
[,
QC Out Of Limits
Out of Limits MessageMeasurement TypeAnatyte Mass
QG Action
QC Action Line: No QC out of limits detected
concentration Resutts gL
Conc. Mean Conc. SD
40.8919
40.9083
41.2427
40.9682
41.1839
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Ditf
104.353
Page 34
METHOD 2A0.8 SUMMARY REPORT
O Sample ID: Qc Std 3
Sample Date/Time: Wednesday, September 28,2005 18:02:52
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\Qc Std 3.453
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac rL
Concentration Results
Analyte Mass Meas. lntens. Mean Net lntens- Mean Conc. Mean Conc. SD Conc- RSD Sample Unit
ug/L
0.13 U.6297 0.5079 0.9297 ug/L
0.46 54.8208 0.22A3 0.4019 ug/L
0.68 55.0679 05749 1.044A ug/L
a[> Tb 159 53661 1.A44 53661 1.04
Hf 176 7011s.392
Hf 177 248129.896
Hf 178 366041 .4y
Hf 179 18/.121760 0.34 54.7442 01477 0.2698 ug/L
Hf 180 47U44.976 0.88 55.1202 0.6984 1.2670 ug/L
QC Calculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. % Diff
[, Tb 159 97.616
I Hf 176 109.259e ff H ;:;I3
I Hf 179 109.488
L Hf 180 110.240
QC Out Of Limits
Measurement Type Analyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page 3s
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. lntens. Mean
536649.016
351.926
1534.416
2216.172
1159.714
2855.887
Net lntens. Mean
536649.02
0.00
0.00
0.00
0.00
0.00
METHOD 200.8 SUMMARY REPORT
Sample lD: QG Std 4
Sample Date/Time: Wednesday, September 28, 2OO5 1 8:09: 1 9
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\QC Std 4.454
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
rf"
Concentration Results
Conc. Mean Conc. SD
0.0708
0.0745
0.0734
0.0786
0.0661
< i ,.lt,l
QC Calculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. % Diff
Tb 159 97.623
Hf 176
Hf 't77
Hf 178
Hf 179
Hf 180
Measurement Type Anatyte Mass
QC Out Of Lirnits
Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Conc. RSD Sample Unit
uglL
11.4065 ugll
13.9763 ug/L
6.9232 ug/L
16.2223 ug/L
6.1377 ug/L
0.0081
0.0104
0.0051
0.0128
0.0041
[,
Page 36
METHOD 200.8 SUMMARY REPORT
Sample lD: 3020A BLK X 10
Sample Date/Time: Wednesday, September 28,2OOS 18:12:43
Sample Type: Sample
Sample Description: BATCH 1666 DIG 91221030
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3-sam
Method File: c:\elandata\Method\2OO.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\3020A BLK X 1 0.455
Tuning File : c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Analyte Mass
Tb - - -l5e Meas. lntens. Mean
5491 48.U2
249.456
1116.377
1648.428
862.026
2202.671
Net lntens. Mean
5491 48.U
-0.00
-0.00
-0.00
-0.00
-0.00
Sample Unit
ug/L
ug/L
ug/L
ugll
ug/L
usL<0- o I
Conc. Mean Conc. SD Conc. RSD
[,
Hf
Hf
Hf
Hf
LHf
176
177
178
179
180
-0.1380 0.2265
4.2387 0.0419
-0.1809 0.0618
-0. 1617 0.1 365
-0.1 614 0.081 7
I'it.
164.117 1
17.5443
34.1740
84.4275
50.6087
[,
Io
I
L
QC Calculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. % Diff
Tb 159 99.897
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
QC Out Of Limits
Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page 37
METHOD 2A0.8 SUMMARY REPORT
Sample lD: 3A20A STD 2.5 OF 10 X10
Sample Date/Time: Wednesday, September 28,2005 18:16:06
Sample Type: Sample
Sample Description: BATCH 1666 DIG 9122 1030
Number of Repticates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File : c :\ela n data\Method\2OO -B\hafn iu ma I l. rnth
Dataset File: c:\elandata\DataseMefault\3020A STD 2.5 OF 10
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
[,
Analyte Mass Meas. lntens. Mean
to 159 s58637.fir5
Hf 176 493U.746
Hf 177 1749il.591
Hf 178 257124.149
Hf 179 130305.796
Hf 180 334808.439
Net Intens. Mean
558637.1 3
0.09
0.31
0.46
0.23
0.60
368.9659
370.4714
370.7577
371.2811
373.5329
4.1 983
2.9049
2.9731
0.9233
0.2549
1.1 379
0.7841
0.8019
0.2487
0.0682
('
,+iL
[,
Analyte Mass QC Std 7o Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
Goncentration Results
Conc. Mean Conc. SD Conc. RSD Sample Unit
*oo';***,'*
'@D
fi;-p{1
ug/L
ug/L
ug/L
uglL
ug/L .t
"stL:t!3-
5tfl)
QG Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Ditf Dup. Rel. % Dift
101.623
QC Out Of Limits
Out of Limits Message
O Sample ID: 0901 O2-1X t0
Sample Date/Timq Wednesday, September 28, 2OO5 1 8:22:31
Sample Type: Sarnple
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandatra\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\090 1 0 2-1 X 1 0.457
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Analyte Mass Meas. lntens. Mean Net lntens- Mean Conc. Mean Conc. SD Conc. RSD Sample Unit
5481.385 385481.39 ug/L '
Hf 176 1834.942
Hf 177 6618.880
Hf 178 9880.106
Hf 179 4975.538
Hf 180 12621 .212
QC Out Of Limits
Measurement TypeAnalyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
QG Galculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution 7o Dff Dup. Rel. 7o Diff
[> Tb 159 70.124
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Page 38
METHOD 200.8 SUMMARY REPORT
0.00 17 .9377 1.9785 1 1.0299 ug/L
0.01 17.8034 2.47A3 13.8756 ug/L
O.02 18.1826 2.2604 12.4317 ug/L
0.01 18.0230 2.1321 11.8297 ug/L
0.03 17.8807 2.1245 11.8816 uglt- O . DL
tf- r'ern Jd ,/ fr-
r"s r.u t ('ufi, O\,/(/
Page
METHOD 200.8 SUMMARY REPORT
Sample ID: 090102-2 X 10
Sample Date/Time: Wednesday, September 28,2OOS 18:25:56
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File : c :\ela ndata\M ethod\200. B\h afn i u ma I l. mth
Dataset File: c:\elandata\Dataset\default\0901 A2-2 X 1 0.458
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
5v
Analyte Mass-E rt
Hf 176
Hf 177
Hf 178
Hf 179
LHf 180
Meas. lntens. Mean
258807.691
591.526
2334.192
3431 .082
1664.431
4332.s51
Net lntens. Mean
258807.69
0.00
0.01
0.01
0.00
0.0
Conc. Mea
17
8.0882
8.1429
7-6369
7.8334
Conc. SD
t
1.4179
1.2063
1.3060
1.2193
1.1 680
Dilution % Ditt
Conc- RSD
18.7757
14.9144
16.0387
15.9657
14.9109
Sample Unit
ug/L
uglL
ug/L
ug/L
ug/L
ug/L
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
Tb 159 lnt Std for siTb 159
QC Action Lin'e: Continue
,AC Calculated Vatues
lnt Std '/o $6covery Spike % Recovery
.,/ 47-o8o
QC Out Of Limits
Out of Limits Message
lnternal Std Out of Limits
QC Action
Dup. Rel. o/o Ditf
[,
Page 4A
METHOD 200.8 SUMMARY REPORT
Sample lD:0901O2-3 X 10
Sample Date/Time: Wednesday, September 28,2OOS 18:29:22
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\090 1 02-3 X 1 0.459
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Goncentration Results
Analyle Mass Meas. lntens. Mean Net lntens. Mean Conc. Mean Conc. SD
' 376587.71
Conc. RSD Sample Unit
ug/L
26.5490 ugll
fi.5704 ugll
22.8185 ug/L
15.8930 ug/L
12.3647 ,gl,- <O, D I
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
[, Tb
344.518
1513.414
2206.505
1146.379
2840.360
0.00
0.00
0.00
0.00
0.00
1.7979
2.1296
21440
2.2444
2.0567
4.4773
0.4168
0.4883
0.3503
0.2543
Analyte Mass QC Std % Recovery
QC Calculated Vatues
lnt Std 7o Recovery Spike 7o Recovery Dilution Yo Ditf Dup. Rel. % Ditt
68.506
Hf
Hf
Hf
Hf
Hf
159
176
177
178
179
180
QC Out Of Limits
Measurement Type Analyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page 4t
METHOD 200.8 SUMMARY REPORT
Sample lD: QG Std 3
Sample Dateffime: Wednesday, September 2S, 2005 18:32:49
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandatra\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\QC Std 3.460
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Analyte Mass
.+a I> Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
L Hf 180
Meas. lntens. Mean
509052.167
64630.035
228097.992
336712.370
169260.660
437154329
Conc. SD
0.4602
0.5535
0.6618
0.5892
0.6388
Conc. RSD
0.8671
1.A422
1.2395
1.1109
1.1910
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.13
0.45
0.66
0.33
0.85
Dilution % Ditf Dup. Rel. % Dift
[,
concentration Results ft'
Net lntens. Mean Conc. Mean
s09052.17
53.0713
53.1117
53.3911
53.0400
53.6355
QC Calculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery
Tb 159 92.603
Hf 176 106.143
Hf 177 146.223
Hf 178 146.782
Hf 179 106.080
Hf 180 147 .271
Measurement Type Anatyte Mass
QC Out Of Limits
Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page 42
METHOD 200.8 SUMMARY REPORT
Sample Date/Time: Wednesday, September 28, 2005 1 8:39:1 6
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\QC Std 4.461
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
i)V1
Concentration Results YO/
Analyte Mass Meas. lntens. Mean Net lntens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit*----F-76-8ir2714.373
522714.37 ug/L
O Sarnple lD: Qc Std 4
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Hf 176 212.8A8
Hf 177 996.035
Hf 178 1488.411
Hf 179 728.352
L Hf 180 1885.662
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. 7o Diff
-0.00 -0.0336 0.0011 3.3351 ug/L
-0.00 -0.0390 0.0055 14.1045 ug/L
-0.00 -0.0306 0.0110 35-8183 ug/L
-0.00 -0.0445 0.0153 34.3292 ug/L
-0.00 -0.0415 0.0097 23.3550 ug/L
QC Calculated Values
95.088
QC Out Of Limits
Measurernent Type Analyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of lirnits detected
Page 43
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-38 X 10 MS-3 2.5 OF 10
Sample Date/Time: Wednesday, September 28, 2AO5 18:42:41
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\090102-38 X 10 MS-3 2.5 OF 10.462
Tuning File: c\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\defaulldac
Analyte Mass
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
[,
Meas. lntens, Mean
383280.789
43644.816
154714.244
228947.587
113649.782
292666.147
Net Intens. Mean
383280.79
0.11
0.40
0.59
o.29
0.76
5{r' '9\i
t ,,oa'-{Do6 '(+t esJ
Goncentration Results
Conc. Mean
475.7598
478.1780
481.8179
472.6797
476.6A72
Conc. SD
7.4175
7.7733
2.6482
7.7930
5.4295
Conc. RSD
1.47s4
1.6256
0.s496
1.6487
1.1392
ple UnitSam
uglL
ug/L
ug/L
ug/L
ug/L
ug/L 4P-qiL
567)
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QC Calculated Values
lnt Std % Recovery Spike % Recovery
69.723
Dilution Y, Ditf Dup. Rel. % Ditt
QC Out Of Limits
Out of Limits MessageMeasurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
Page 44
METHOD 2A0.8 SUMMARY REPORT
Sample lD: 090102-39 X 10 MSD-3 2.5 OF 10
Sa mple DatelTime: Wednesday, September 28, 200 5 1 8:46;07
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c\elandata\Dataset\default\090102-39 X 10 MSD-3 2.5 OF 10.463
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
5k--*fo
U
f +{'P5}
3ND
Anatyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. lntens. Mean
384il9-697
42872.778
151029.016
222183.1 13
110821.924
283814.440
Net lntens. Mean
384549.70
0.11
0.39
0.57
0.29
0.73
0.8910
1 .1661
0.9053
0.6150
o.9842
Dup. Rel. Yo Diff
Sample Unit
ug/L
ug/L
ug/L
ug/L
uo/L
,ir- +blg
-fite
Conc. Mean Conc. SD Conc. RSD
[,
465.7762
46s.1905
466.0327
459.3484
460.580s
4.1500
5.4247
4.2188
2.8251
4.s332 -q72" [lgro-
[,
OI
I
L
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Ditt
69.954
QC Out Of Limits
Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page 45
METHOD 200.8 SUMMARY REPORT
Sample lD: 0901024 X 10
Sample Date/Time: Wednesday, September 28,2OOS 18:52:34
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File : c:\ela ndata\Dataset\default\090 1 O24 X 1 O.464
Tuning File: c\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Analyte Mass Meas. lntens- Mean Conc. Mean Conc. SD Conc. RSD
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
487883.922
243.714
1187.049
17A4.435
85s.692
2211.724
Net lntens. Mean
487883.92
0.00
0.00
0.00
0.00
0.00
219.6138
37.4543
47.2843
45.9815
47.A484
Sample Unit
ug/L
ug/L
uglL
uglL
UO/L
uJn- <0- 0 (
0_0525
0.2372
a.u78
0.1337
0.1658
4.1$2
0.0889
0.1 030
0.0615
0.0780
Analyte Mass QC Std 7" Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QC Calculated Values
lnt Std % Recovery Spike 7o Recovery Dilution % Ditt
88.752
Dup. Rel. % Ditt
[,
QC Out Of Limits
Out of Limits MessageMeasurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
Page 46
METHOD 200.8 SUMMARY REPORT
O Sample lD: 0901 O2-5 X 10
Sample Date/Time: Wednesday, September 28, 2005 1 8:56:02
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\090102-5 X 10.465
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Analyte Mass Meas. lnlens. Mean Net lntens. Mean Conc. Mean Conc. SD Conc- RSD Sample Unit
l> Tb 159 502483.876 '502483.88 ' ug/L
Hf 176 49.859
Hf 177 486.008
Hf 178 781.355
Hf 179 337.337
L Hf 180 895.562
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. % Diff
-0.00 -1.6277 0.0949 5.8287 ug/L
-0.00 -1.5083 0,061 1 4.0526 ug/L
-0.00 -1.3550 0.2247 16.5849 ug/L
-0.00 -1.6020 0.0454 2.8346 ug/L
-0.00 -1.s607 0.0151 0.96s7 ugtL<O -O I
QC Galculated Values
91.408
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QC Out Of Limits
Measurement Type Analyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page 47
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-6 X 10
Sample Dateffime: Wednesday, September 28,20OS 18:59:30
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\0901 02-6 X 1 0.466
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. lntens. Mean
523429.847
-13.23s
250.002
346.004
172.3U
476.312
Net lntens. Mean
523429.85
-0.00
-0.00
-0.00
-0,00
-0.00
Conc. Mean Conc. SD Conc. RSD Sample Unitre
-2.1500
-2-0918
-2.0799
-2.1514
-2.1083
4.0221
0.0230
0.0348
0.1 130
0.0139
1.A2ffi ugll
1.0999 ug/L
1.6732 ugll
5.2537 us/L
o.65eo u],,- <O'o I
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QC Calculated Values
lnt Std % Recovery Spike % Recovery
95.218
Dilution % Ditf Dup. Rel. % Ditt
Measurement TypeAnalyte Mass
QC Action Line: No QC out of limits detected
QC Out Of Limits
Out of Limits Message
QC Action
Page 48
METHOD 200.8 SUMMARY REPORT
Sample lD: QG Std 3
Sample Date/Time: Wednesday, September 28, 2OO5 1 9:02:58
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\09280$3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\QC Std 3.467
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\defa ult.dac
PV
Concentration Results
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. lntens. Mean
ffi6527.146
64ss5.765
228568.143
338694.792
1681 53.275
434764.572
Net lntens. Mean
506527.1 5
0.1 3
0.45
o.67
0.33
0.Bs
Conc- Mean Conc. SD
53.2743
53.4902
53.9754
52.9550
53.6100
Conc. RSD Sample Unitr'.' ug/L
0.3369 0.6324 ugll
0.2599 0.4860 ug/L
0.3663 0.6786 ugll
0.2482 0.4687 ug/L
0.2062 0.3846 ug/L
QC Calculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. % Diff
Tb 159 92.143
Hf 176 106.549
Hf 177 106-980
Hf 178 107.951
Hf 179 105.910
Hf 180 107.220
Measurement Type Anatyte Mass
QC Out Of Limits
Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page 49
METHOD 200.8 SUMMARY REPORT
Sample lD: QG Std 4
Sample Date/Time : Wednesday, September 28, 2OO5 1 9:09:25
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\QC Std 4.468
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results "vConc. SD Conc. RSDAnalyte Mass Meas. lntens. Mean Net lntens. Mean
518691.861
2A4.829
1402.702
1428AO5
723.68s
1888.937
518691.86
-0.00
-0.00
-0.00
-0.00
-0.00
Conc. Mean
-0.0419
-0-0356
-0.0382
-0.0440
-0.0393
0.0074
0.a172
0.0085
0.0178
0.0041
17.7088
48.1422
22.2335
4A.4452
14.4717
Sample Unit
ug/L
ug/L
ug/L
uglL
ug/L
ug/L
Hf
Hf
Hf
Hf
Hf
176
177
178
179
180
[,
Anatyte Mass QC Std 7o Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QC Calculated Values
lnt Std % Recovery Spike % Recovery
94.3s6
Dilution Yo Dift Dup. Rel- % Dift
QC Out Of Limits
Out of Limits MessageMeasurement Type Anatyte Mass
QC Action
QC Action Line: No QC out of timits detected
Page 50
METHOD 200,8 SUMMARY REPORT
Sample lD: 090102-T X 10
Sa mple Dateff ime: Wednesday, September 28, 2OO5 1 9:1 2:52
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\DataseMefa ult\090 1 0 2-7 X 1 0.469
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Goncentration Results
Analyte Mass Meas. lntens. Mean Net lntens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit
[, Tb 1se s43068.550 -----54m68.ss ' ug/L
Hf 176 149.175 -0.00 -0.8918 0.3679 4'1.2496 ug/L
Hf 177 817.023 -0.00 -0.8685 0.0761 8.7617 ug/L
Hf 't78 1186.716 -0.00 -0.8434 0.0382 4.5345 ug/L
Hf 179 600.013 {.00 -0.9068 0.0861 9.4982 udl ,
Hf 180 1552.766 -0.00 -0.8846 0.0314 3.5458 udL zo.o I
QC Calculated Values
Analle Mass QC Std % Recovery lnt Std o/o Recovery Spike % Recovery Dllution % Diff Dup. Rel. % Diff
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
98.791
QC Out Of Limits
Measurement Type Analyte Mass Out of Lirnits Message
QC Action
QC Action Line: No QC out of limits detected
Page 51
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-8 X 10
Sample Date/Time: Wednesday, September 28, 2005 19:16:21
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File : c:\ela ndata\DataseMefa ult\090 1 0 2-8 X 1 0.47 O
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Goncentration Results
Analyte Mass Meas. lntens. Mean Net lntens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit
I-, ro rss - s31643.405 ' 5a1643.40 ug/L
Hf 176 104.957
Hf 177 698.350
Hf 178 981.700
Hf 179 466.008
Hf 180 1272.440
-0.00 -1.2156 0.0210 1.7313 ug/L
-0.00 -1.0961 0.0983 8.9696 ug/L
-0.00 -1.1182 0.0401 3,5845 ug/L
-0.00 -1.2733 0.0587 4.61 16 ug/L r
-0.00 -1.177a 0.016s 1.4054 uil IO ' O I
QC Calculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. % Diff
[> Tb 159 96.712
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QC Out Of Limits
Measurement TypeAnalyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page 52
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-g X 10
Sample Dateffime: Wednesday, September 28,2OOS 19:19:50
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File : c:\elandata\Dataset\defa ult\090 1 0 2-9 X 1 0.47 1
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
_ _Analyte
[, Tb
Hf
Hf
Hf
Hf
LHf
Mass Meas. lntens. Mean
15e SiZU2.444
176 44.721
177 405.339
178 578.345
179 313.670
180 763.554
Net lntens. Mean
il2842.44
-0.00
-0-00
-0.00
-0.00
-0.00
Conc. Mean
-1.6978
-1 .7713
-1.7524
-1.7525
-1.7966
Conc. SD
0.0836
0.0507
0.0504
0.0932
0.0449
Conc. RSD
4.9265
2.8646
2.879s
5.3180
2.4974
Sample Unit
ug/L
ug/L
ug/L
uglL
ug/L
uglt- zo. o I
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
QC Calculated Values
Int Std % Recovery Spike o/o Recovery Dilution % Ditt Dup. Rel. To Ditf
98.750
QC Out Of Limits
Out of Limits Message
Page 53
METHOD 200.8 SUMMARY REPORT
Sample lD: 0901A24A X 10
Sample Date/Time: Wednesday, September 28, 2OO5 19:23:20
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File : c:\elandata\Datraset\default\090 1 02-1 O X 1 0.47 2
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. lntens- Mean
479MA.A72
163.805
916.696
1310.393
643.014
1711.311
Net lntens. Mean
479640.O7
-0-00
-0.00
-0.00
-0.00
-o-00
Conc. Mean
-0.6111
-0.3840
-0.3998
-a.s292
-0.4396
Conc. SD
0.0961
0.1 089
0.0180
0.0391
0.0604
Conc. RSD
15.7305
28.3M8
4.4941
7.3978
13.7349
Sample Unit
uglL
ug/L
ug/L
ug/L
ug/L
;;;. zo. o /
[,
Analyte Mass QC Std o/o Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QG Calculated Values
lnt Std % Recovery Spike % Recovery
87.2s2
Dilution ok Ditf Dup. Ret. % Ditt
QC Out Of Limits
Out of Limits MessageMeasurement Type Analyte Mass
QC Action
QC Action Line: No QC out of timits detected
Page 54
METHOD 200.8 SUMMARY REPORT
Sample lD:090102-11 X 10
Sample Date/Time: Wednesday, September 28,2OOS 19:26:50
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File : c:\ela ndata\Dataset\defa ult\090 1 02-1 1 X 1 O.47 3
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. lntens. Mean
433776.863
113.948
6s4.348
953.032
477.675
1210.474
Net lntens- Mean
433776.86
-0.00
-0.00
-0.00
-0.00
-0.00
Conc- Mean Conc. SD
-0.9412 0.3738
-0.8633 0.0476
-0-8330 0-1208
-0.9129 0.0135
-0.9277 0.1070
Conc. RSD
39.71 13
5.5090
14.5044
1.4842
1 1.5363
Dilution % Ditt Dup. Rel. % Ditt
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L <O. o I
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QG Calculated Values
Int Std % Recovery Spike % Recovery
78.909
d
QC Out Of Limits
Measurement Type Analyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page
METHOD 200.8 SUMMARY REPORT
Sample lD: QC Std 3
Sample Date/Time: Wednesday, September 28,2005 19:30:20
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sarn
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\QC Std 3.47 4
Tu ning File : c:\ela nd ata\Tu n in g\defa u lt.tu n
Optirnization File: c:\elandata\Optimize\default.dac
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Meas. lntens. Mean
512325.731
65479.901
230365.s04
34A252.482
171841.397
443976.032
Net lntens. Mean
512325.73
0.13
0.45
0.66
0.33
0.86
53.4248
53.2984
53.6076
53.5044
54.1264
0.8676
0.5589
4.64/,4
0.9886
0-8637
1.6239
1.0486
1.2421
1.8477
1.5957
---rrg/L
ug/L
ug/L
ug/L
ug/L
ug/L
QC Calculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike 7o Recovery
Tb 159 93.198
Hf 176 106.850
Hf 177 106.597
Hf 178 107.215
Hf 179 107.009
Hf 180 108.2s3
Measurement Type Analyte Mass
QC Out Of Limits
Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Dilution % Diff Dup. Rel. % Diff
f,
$\4
Concentration Resutts
Conc. Mean Conc. SD Conc. RSD Sample Unit
O Sample lD: Qc Std 4
Sample Date/Time: Wednesday, September 28, 2A05 19:36:47
Sampte Type: Sample
Sample Description:
Number of Replicates: 3
Sample Fi[e: C:\Elandata\Sample\092805-3.sam
Method Fite: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\Qc Std 4 -47 5
Tun in g File : c:\ela ndata\Tuning\defa u lt.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Measurement Type Analyte Mass
QC Action Line: No QC out of limits detected
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Ditt Dup. Rel. % Ditt
95.050
QC Out Of Limits
Out of Limits Message
QC Action
Sample Unit
ug/L
ug/L
ug/L
uglL
ug/L
ug/L
Page )-)o
METHOD 200.8 SUMMARY REPORT
[,
Meas. lntens. Mean
522541307
216.147
1080.374
1543.417
734.019
1959.690
Net lntens. Mean
522505-31
-0.00
-0.00
-0.00
-0.00
-0.00
Conc. Mean
-0.0308
-0.0198
-4.0224
-0.4427
-0.0325
N4
VW
Conc. SD
0.0074
0.0148
0.0070
0.0103
0.0049
Conc. RSD
24.0680
74.6864-
31.8560
24.0927
15.0680
[,
Io
I
L
Page 57
METHOD 200.8 SUMMARY REPORT
Sample lD: 0901 O2-12X 10
Sa mple Dateff ime : Wednesday, Septem ber 28, 2OO5 1 9:4O :1 1
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\defa ult\090 1 0 2-1 2 X 1 0.47 6
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas- lntens- Mean
s33629.925
185.387
9s4.699
1355.731
701.684
1803.418
Net lntens. Mean
533629.93
-0.00
-0.00
-0.00
-0.00
-0.00
Conc. Mean Conc- SD Conc. RSD Sample Unit
[g/L t
-0.5854
-0.5286
-0.5547
-0.5700
-0.s577
o.1279
0.1 1 36
0_1023
0.0895
0.0549
21.8441
21.4864
18.4445
15.7008
9.8414
ug/L
ug/L
ug/L
uo/L
uiru U -O
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QC Calculated Vatues
lnt Std % Recovery Spike % Recovery
97.074
Dilution % Ditt Dup. Rel. % Ditt
Measurement Type Analyte Mass
QC Action Line: No QC out of limits detected
QC Out Of Limits
Out of Limits Message
QC Action
Page 58
METHOD 200.8 SUMMARY REPORT
Sample lD:0901A2-13 X 10
Sample Date/Time : Wednesday, September 28, 2OO5 1 9:43:34
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\090 1 A2- 1 3 X 1 0.47 7
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
AnafVte
Tb
Hf
Hf
Hf
Hf
Hf
Mass
159
176
177
178
179
180
Meas. lntens. Mean
392627.158
223.868
1105.710
1534.082
769.687
1969.917
Net lntens. Mean
392627.16
0.00
0.00
0.00
0.00
0.00
0.3500 0.3351
0.6954 0.2908
0.5539 0.1308
4.4652 0.1649
4.4747 0.2A75
Sample Unit
ug/L
ug/L
uglL
ug/L
uglL
ug/L 4,A I
Conc. Mean Conc. SD Conc. RSD
[,
[,
QC Calculated Values
lnt Std % Recovery Spike % Recovery
71.424
95.7435
41.8225
23.6172
35.4507
44.4770
Dilution o/o Dift Dup. Rel. % DittAnalyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QC Out Of Limits
Measurement Type Analyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page
METHOD 200.8 SUMMARY REPORT
Sample lD:090102-14 X {0
Sample DatelTime: Wednesday, September 28, 2OO5 19:46:57
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: clelandata\Method\200.8\hafniumall.mth
Dataset File : c:\ela ndata\Dataset\default\090 1 02-1 4 X 1 O.47 I
Tuning File: c:\elandata\Tuning\defaulltun
Optimization File: c:\elandata\Optimize\default.dac
Analyte Mass Meas. lntens. Mean
Concentration Results
Net Intens- Mean Conc. Mean Conc. SD Conc. RSD
[,Tb
Hf
Hf
Hf
Hf
Hf
- rss
176
177
178
179
180
s3454zBB9
3.545
343.004
489.675
263.002
627.817
530542.89
-0.00
-0.00
-0.00
-0.00
-0.00
-2.0171
-1.8909
-1.8671
-1.8839
-1.9364
9.6103
3.3063
0.6443
2.2166
1.3017
Sample Unit
dg/L
ug/L
ug/L
ug/L
ug/L
ug/L 20. o
0.1939
0.0625
0.0120
0.0418
4.4252
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QC Calculated Values
lnt Std % Recovery Spike % Recovery
96.s12
Dilution % Ditf Dup. Rel. % Dift
QC Out Of Limits
Out of Limits MessageMeasurement TypeAnalyte Mass
QC Action
QC Action Line: No QC out of limits detected
Page 60
METHOD 200.8 SUMMARY REPORT
O Sampte lD: 090 102-1 5 X t0
Hf 176 84.832
Hf 177 589.345
Hf 178 878.694
Sample Dateffime: Wednesday, September 28, 2AO5 1 9:50:22
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\defa ult\090 1 0 2-1 5 X 1 0.47 I
Tuning File c\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Goncentration Results
Analyte Mass Meas- lntens. Mean Net lntens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit
[ --49i99Ttr{ - 'ug/L
-0.00 -1.3302 0.1666 12.5275 uglL
-0.00 -1.2il3 0.0460 3.6635 ug/L
-0.00 -1.1883 0.0298 2.5074 ug/L
Hf '179 436.340 4.00 -12772 0-0389 3.0489 us/L
Hf 180 1109.666 -0.00 -1.2847 0.0771 5.9996 usLZ)-O I
QC Calculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. % Diff
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
90.834
QC Out Of Limits
Measurement Type Analyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page 6r
METHOD 200.8 SUMMARY REPORT
Sample lD:090102-16 X 10
Sample Date/Time: Wednesday, September 28, 2OO5 1 9:53:47
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Datraset File: c:\elandata\Dataset\defaulM90l 02-16 X 1 0.480
Tuning File: c:\elandata\Tuning\default-tun
Optimization File: c\elandata\Optimize\default.dac
Goncentration Results
Analyte Mass Meas. lntens. Mean Conc. Mean Conc- SD
518613.540
-3.796
288.336
393.339
200.001
539.918
Net lntens. Mean
s18613.54
-0.00
-0.00
-0.00
-0.00
-0.00
Conc. RSD Sample Unit
ug/L
4.6575 ug/L
3.2416 ug/L
1.3999 ug/L
0.0889 uolL t
2.30e4 uin- 4'O I
[, Tb
Hf
Hf
Hf
Hf
Hf
159
176
177
178
179
180
-2-4751
-1.9986
-2.OOA7
-2.0601
-2-0260
0.0966
0.0648
0.0280
0.0018
0.0468
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf
Hf
QC Calculated Values
Int Std % Recovery Spike % Recovery
94.U2
Dilution % Ditt Dup. Rel. % Ditt
179
180
QC Out Of Limits
Out of Limits MessageMeasurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
Page 62
METHOD 200.8 SUMMARY REPORT
Sample lD: QC Std 3
Sa mple Date/Time: Wednesday, September 28, 2OO5 1 9:57 :1 4
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandatra\DataseMefault\QC Std 3.481
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
[,
Analyte
Tb
Hf
Hf
Hf
Hf
Hf
Analyte
Tb
Hf
Hf
Hf
Hf
Hf
Mass
159
176
177
178
179
180
54.1188
53.9396
54.3338
s3.7263
54.3291
0.5528
0.5195
0.5393
0.5849
0.5295
1.0214
0.9631
0.9926
1.0886
0.9746
Meas- lntens. Mean
512245.793
66317.051
233084.395
344785.518
172521.712
445553.251
108.238
107.879
108.668
107.453
108.658
Net lntens. Mean
512245.79
0.1 3
0.45
0-67
0.34
0.87
QC Calculated Values
Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery
[,159
176
177
178
179
180
QC Out Of Limits
Measurement Type Analyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
rk-
Concentration Results
Conc. Mean Conc- SD Conc. RSD Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Dilution Yo Ditf Dup. Rel. % Dltf
93.184
Page 63
METHOD 200.8 SUMMARY REPORT
Sample lD: QG Std 4
Sample DatelTime: Wednesday, September 28,2005 20:03:40
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\QC Std 4.482
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
n
concentration Resutts 0+'
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. lntens. Mean
528908.473
219.808
1059.039
15s5.418
774.688
2030.735
Net lntens- Mean
52890S.47
-0.00
-0.00
-0.00
-0_00
-0.00
Conc. Mean Conc. SD Conc. RSD Sampte Unit
It -ng7r_-
ug/L
ug/L
ug/L
ug/L
ug/L
-0.0301
-4.4275
-0.0230
-0.0331
-0_0269
0.0185
0.0066
0.0146
0.0064
0.o142
61.4266
23.8624
63.45B3
19.3245
52.6659
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QC Calculated Values
tnt Std % Recovery Spike % Recovery
96.215
Dilution o/o Ditt Dup. Rel. % Ditt
QC Out Of Limits
Out of Limits MessageMeasurement Type Analyte Mass
QC Action
QC Action L[ne: No QC out of limits detected
Page 64
Sa mple Date/Time : Wednesday, September 28, 2OO5 2O:O7 :45
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\090102-17 X 1 0.483
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Analyte Mass Meas. lntens. Mean Net lntens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit
-a
[> Tb 159 604264'.233 6A4264.23 ug/L
O Sample ID: 0901 02-17 Xl 0
Hf 176 96.509
Hf 177 717.685
Hf 178 1017.036
Hf 179 490.675
Hf 180 1348.M8
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
METHOD 200.8 SUMMARY REPORT
-0.00 -1.3739 0.051 1 3.7193 ug/L
-0.00 -1-2456 0.0668 5.3630 ug/L
-0.00 -1.2505 0.0310 2.4808 ug/L
-0.00 -1.3766 0.0450 3.2662 ug/L
-0.00 -1.278s 0.M19 3.2762 ug/L ZO ' O I
QC Calculated Values
109.923
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution o/o Diff Dup. Rel. % Diff
QC Out Of Limits
Measurement Type Analyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page 65
METHOD 200.8 SUMMARY REPORT
Sample lD: 090{0240 X 10 MS-17 2.5 OF 10
Sample Date/Time: Wednesday, September 28,2OO5 20:10:31
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\09280$.3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\09010240 X 10 MS-17 2.5 OF 10.484
Tuning File: c:\elandata\Tuning\default-tun
Optimization File: c:\elandata\Optimize\default.dac
[, Tb
Hf
Hf
Hf
Hf
Hf
4363M.418
51506.559
180626.369
266237.669
133425.979
343535.931
Analyte Mass Meas. [ntens. Mean
Concentration Results
Net lntens. Mean Conc- Mean Conc. SD
4
ai2 493.2185 6.2969
0.41 490.4337 3.2972
0.61 492.2937 2.9159
0.30 487.5339 2.0133
159
176
177
178
179
180
Sample Unit
ugtr-
ug/L
ug/L
ugll
ug/L
0.78 491.4871
QC Calculated Values
1.8471
Analyte Mass QC Std % Recovery
[,Tb 159
Hf 176
Hf 177
Hf 178
Hf
Hf
179
180
QC Out Of Limits
Out of Limits MessageMeasurement TypeAnalyte Mass
QC Action
QC Action Line: No QC out of limits detected
lk=T, p{)
Conc. RSD
1.2767
4.6723
0.5923
0.4130
0.3758
lnt Std % Recovery Spike % Recovery Dilution "/, Dift Dup. Rel. o/o Ditt
79.380
Page 66
METHOD 200.8 SUMMARY REPORT
Sample lD: 0901 0241 X 10 MSD-17 2.5 OF 10
Sample Date/Time: Wednesday, September 28, 2OO5 2O:13:57
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\09010241X 10 MSD-17 2.5 OF 10.485
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Goncentration Results
Analle Mass Meas. lntens. Mean Net lntens. Mean Conc. Mean Conc- SD Conc. RSD Sample Unit
[, Tb 159 509360.878 509360.88 ugiL
Hf 176 58316.026
Hf 177 2A3722.580
Hf 178 299658.822
Hf 179 149U4.621 :Ziilyl ,qSL,Uffdffo
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
92.659
QC Out Of Limits
Measurement TypeAnalyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
*,--ry:tr;Ln
lo.
0.1 1 478.3396 5.2556 1 .0987 ug/L
0.40 473.7971 6 .2372 1.3164 ug/L
0.59 474.5943 5.0092 1.05s5 ug/L
t Hf 180 387162.159
0.29 468_U4A 5.6363 1.2035
0.76 474.4434 5.6761 1 .1964
QC Calculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. % Diff
Page 67
METHOD 200.8 SUMMARY REPORT
Sample lD:0901A248 X 10
Sample Date/Time: Wednesday, September 28,2OAS 2O:20:24
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\0901 02-18 X 1 0-486
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c\elandata\Optimize\default.dac
Concentration Results
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. lntens. Mean
455861 .547
242.889
1178.049
1688.433
834.O24
2260.383
Net Intens. Mean
45s861.55
0.00
0.00
0.00
0.00
0-00
Conc- Mean Conc. SD Conc. RSD Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
[,
0.1921
0.4183
0.3892
0.2556
0.4340
4.4428
a.fi24
0.1557
0.1433
0.1032
22.2754
31.6443
40.0098
56.0825
23.7846 -to. o I
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QC Galculated Values
lnt Std % Recovery Spike % Recovery
82.927
Ditution % Ditt Dup. Rel. % Ditt
QC Out Of Limits
Out of Limits MessageMeasurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
Page 68
METHOD 200.8 SUMMARY REPORT
Sample lD:090102-19 X 10
Sample Dateffime: Wednesday, September 28, 2OO5 20:23:51
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200-8\hafniumall.mth
Dataset File : c:\elandata\Dataset\defau 1t\090 1 02-1 I X 1 O.487
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Goncentration Results
Analyte Mass Meas. lntens. Mean Net lntens. Mean Conc. Mean Conc- SD Conc. RSD Sample Unil
[, Tb 159 400369 .382 400369.38 ug/L
Hf 176 168.088
Hf 177 809.023
Hf 178 1223.A52
Hf 179 610.013
Hf 180 1548.567
-0.00 -0.2818 0.1008 35.7698 ug/L
-0.00 -0.2s31 0.0634 25.0295 ug/L
-0.00 -0.1379 0.0438 31.7491 ugll
-0.00 -0.23l.8 0.1577 67.14A4 ugll
-0-00 -0.2514 0.0216 8.5757 ug/L 4. O t
QC Calculated Values
72.832
Analle Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Ret. % Diff
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QG Out Of Limits
Measurement TypeAnalyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page
METHOD 200.8 SUMMARY REPORT
Sample lD: QC Std 3
Sample Date/Time: Wednesday, September 28,2A05 20:27:2A
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
M ethod Fi le : c:\ela ndata\Method\2 00. 8\h afn i uma Il. mth
Dataset File: c:\elandata\Dataset\default\Qc Std 3.488
Tuning File: c:\elandata\Tuning\default.tun
Optimiza tio n Fi le : c:\ela ndata\Opti m ize\defa u It. da c
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas- lntens. Mean
542226.461
64095.723
225549.406
332463.576
167721.737
431769.192
Net lntens. Mean
sa2226.46
0.13
0.45
0.66
0.33
0.86
53.3488
53.2327
53.4341
53.2723
53.6979
[,
Concentration Results
Conc. Mgan Co_1": SD
,
d.-
0.1412
0.7271
0.9266
0.7305
0.6202
fr{L
QG Calculated Values
Analle Mass QC Std % Recovery lnt Std % Recovery Spike o/o Recovery Dilution % Diff Dup. Rel- o/o Diff
Tb 159 91.361
Hf 176 106.698
Hf 177 106.465
Hf 178 106.B68
Hf 179 106,il5
Hf 180 107.396
Measurement Type Analyte Mass
QC Out Of Limits
Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Conc. RSD Sample Unit
ug/L
0.1897 ugll
1.3659 ug/L
1.7340 ug/L
1.3712 ug/L
1.1549 ug/L
Page 70
METHOD 2A0.8 SUMMARY REPORT
Sample lD: QC Std 4
Sample Date/Time: Wednesday, September 28,2A05 20:33:46
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\QC Std 4.489
Tuning File: c:\elandata\Tuning\default.tun
Optim ization File : c:\ela ndata\O ptimize\d efa u lt. dac
il
s$l-'
Goncentration Results
Analle Mass Meas. lntens. Mean Net lntens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit
[, Tb 159 514644.493 514644.49 ug/L
Hf 176 213.080
Hf 177 1104.376
Hf 178 1662.097
Hf 179 841.425
Hf 180 2148-071
tLr)(c
-0-00 -0.0307 0.0135 44.A328 ug/L
-0.00 -0.0104 0.0138 132.8471 ugll
0.00 0.0005 0.0160 3s04.8447 uglL
-0.00 -0.0058 0.0009 15.0679 uglL
-0.00 -0.0059 0.0153 260.8620 ug/L
QC Galcutated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. % Diff
[, Tb 159 93.620
Hf 176
Hf 177
Hf 178
H' 179
Hf 180
QC Out Of Limits
Measurement TypeAnalyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page
METHOD 200.8 SUMMARY REPORT
Sample lD: 0901A2-2O X 10
Sample Date/Time : Wednesday, September 28, 2005 2A 37 :1 2
Sample Type: Sample
Sample Description: BATCH 1667 DIG 91221040
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\defau lt\090 1 02-20 X 1 0.490
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. lntens. Mean
515139.525
198.719
1004.035
1527.415
736.686
1995.286
Net lntens. Mean
5151 39.52
-0.00
-0.00
-0.00
-0.00
-0.00
Conc. Mean
-0.4219
-0,3392
-o.2097
-0.3859
-4.2482
Conc. SD
0.3043
0.4724
0.0982
o.0247
0.03s6
Dilution % Ditt
Conc. RSD
72.1194
21.2316
46.8176
6.3941
14.3482
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L ,
ug/L ZO -o/
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QC Calculated Values
lnt Std % Recovery Spike o/o Recovery
93.710
QC Out Of Limits
Out of Limits Message
Dup. Rel. % Dttt
[,
Measurement TypeAnalyte Mass
QC Action
QC Action Line: No QC out of limits detected
Page
METHOD 200.8 SUMMARY REPORT
Sample lD: 3020A BLK X 10
Sample Date/Tirne: Wednesday, September 28, 2405 20: 40:41
Sample Type: Sample
Sample Description: BATCH 1667 DIG 9122 1040
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\3020A BLK X 1 0.491
Tuning File: c:\elandata\Tuning\default.tun
Optim ization F ile : c :\e la ndata\Optim ize\d efa u lt.da c
Concentration Results
Analyte Mass
[,Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Conc- Mean
-1.8551
-1.5819
-1.s86
-1.6424
-1_7bO7
QC Calculat Values
lnt Std % Recovery Spike ecovery
95.627
Out Of Limits
Meas. lntens. Mean
525674.173
23.667
476.008
667.349
339.671
819.814
Net lntens. Mean
525674.17
-0.00
-0.00
-0.00
-0.00
-0.00
. SD Conc. RSD Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L,il /o-o {
0.0384
0.0168
0.0579
0.0s84
0.4777
Dilution % Diff
2.4714
1.0619
3.6503
3.5s52
4.5661
Dup. Rel. % Ditt
[,
d
Measurement Type Analyte Mass Out of Lin
QC Action Line. No QC out of limits detected I/i
///II
IIt
L
Page
METHOD 2A0.8 SUMMARY
Sample ID: 3A20A STD X t0 2.5 OF 10
Sample Date/Time: Wednesday, September 28,2A05 20:44:Ag
Sample Type: Sample
Sample Description: BATCH 1667 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniurnall. mth
Dataset File: c:\elandata\Dataset\default\3020A STD X 10 2.5 OF 10-492
Tuning File: c:\elandata\Tuning\default.tun
Opti mization F il e : c :\e la ndata\Optim ize\defa u It. da c
Concentration Results
REPORT
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. [ntens. Mean
524278.841
44414.808
155874.935
232345.178
1 16082.038
298838 .332
Net lntens. Mean
524278.84
0.08
0.30
0.44
0-22
0.57
Conc, Mean Conc. SD
353.4016
351 .5192
356.8031
352.2454
3s5.0859
5-1753
1.1010
6.9329
6.6244
4.1776
Colc- RSD
1.4644
0.3132
1.9431
1.8806
1.1765
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QC Calcutated Values
lnt Std % Recovery Spike % Recovery
95.373
QC Out Of Limits
Out of Limits MessageMeasurement TypeAnalyte Mass
QC Action
QC Action Line: No QC out of timits detected
Sample Unit
u97L.
ug/L
ug/L
uglL
uglL
us/L n55@
Dilution % Ditt Dup. Rel. Yo Dift
Page
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-21X 10
Sample Dateffime: Wednesday, September 28,2005 20:50:39
Sample Type: Sample
Sample Description: BATCH 1667 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset Fi le : c:\elandata\Dataset\defa ult\090 1 0 2-21 X 1 0.493
Tuning File: c:\elandata\Tuning\default.tun
Optim2ation File: c:\elandata\Optimize\default.dac
Concentration Results
Analyte Mass Meas. lntens. Mean
rb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
4&929-819
343.780
1571.4n
2284.516
1144.379
2975.451
Conc. RSD
25.3734
22.8746
22.1495
13.6352
22.5870
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Net lntens- Mean
4649n.82
0.00
0.00
0.00
0,00
0.00
Conc. Mean Conc. SD
1.0607
1.3683
1.3652
1.2692
1.3403
0.2691
0.3129
0.3024
0.1 73 1
43427
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Measurement Type Analyte Mass
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Ditt
84.576
Dup. Ret. o/o Diff
QC Out Of Limits
Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page
METHOD 200.8 SUMMARY REPORT
Sample lD:090102-22 X 10
Sample Date/Time: Wednesday, September 28,2005 20:54:08
Sample Type: Sample
Sample Description: BATCH 1667 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File : c:\elandata\DataseMefa u1t\090 1 0 2-22 X 1 0.494
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Meas. lntens. Mean
47A722.772
217.237
1061.373
1546.084
781.355
1969.861
Net lntens. Mean
' 47orz2.T2
-0.00
0.00
0.00
-0.00
-0.00
Conc. Mean
-0.1080
0.0256
0.0483
-0.0174
4.A527
Conc. SD
0.2124
0.4442
0.0862
0.1681
0.0343
Conc. RSD
196.7095
173.4452
178.5535
96s.3976
65.0914
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QC Galculated Values
lnt Std % Recovery Spike % Recovery
85.630
Dilution % Ditf Dup. Rel. % Dift
Measurement Type Analyte Mass
QC Action Line. No QC out of limits detected
QC Out Of Limits
Out of Limits Message
QC Action
Page
METHOD 200.8 SUMMARY REPORT
Sample ID: QG Std 3
Sample Date/Time: Wednesday, September 28,2A05 20:57:38
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.rnth
Dataset File: c:\elandata\Dataset\default\QC Std 3.495
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
tL{ 1
0.3s76
0.6823
1.1779
1.4057
1.0033
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Meas. lntens. Mean
s32339.932
68961 .324
241055.973
3577 1 1.159
179160.043
459822926
Net lntens. Mean
532339.93
0.13
0.45
0.67
0.33
0.86
Conc. Mean
54.1522
s3.6732
s4.2354
53.6828
53.9487
Conc. SD Conc. RSD Sample Unit
[,
0.6604 ug/L
1 .2713 ug/L
2.1718 ug/L
2.6185 ug/L
1.8597 ug/L
f,
QC Catculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. 7o Diff
Tb 159 96.839
Hf 176 108.304
Hf 177 107.346
Hf 't7B ',to8.471
Hf 179 107.366
Hf 180 107.B97
Measurement Type Analyte Mass
QC Out Of Limits
Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page 77
METHOD 200.8 SUMMARY REPORT
Sample lD: QC Std 4
Sample Date/Time: Wednesday, September 28,2AA5 21 :04:04
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\E!andata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\QC Std 4.496
Tuning File: c:\elandata\Tuning\defauJt.tun
Optimization File: c:\elandata\Optimize\default.dac rl<-
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas- lntens. Mean
549139-152
259-121
1278.391
1846.786
935.031
237A.462
Net lntens. Mean
549139.15
-0.00
0.00
0.00
0.00
0.00
Conc. Mean
-0.0063
0.0r 13
0.01 13
0.0051
0.0031
Conc. RSD
489.9908
89.4826
109.3231
125-8462
434.2010
[,
QC Calculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery
Tb 159 99.895
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
QC Out Of Limits
Out of Limits Message
QG Action
QC Action Line: No QC out of limits detected
o c,b1
Goncentration Results
Conc. SD
0.0308
0.0101
o.a124
0.0064
0.0134
Dilution % Ditt Dup. Rel. % Ditt
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Page 78
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-23 X 10
Sa mple Date/Time : Wed nesday, September 28, 2AO5 21 :O7 :32
Sample Type: Sample
Sample Description: BATCH 1667 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\i200.8\hafniumall.mth
Dataset File: c:\elandata\Datiaset\defaulM90 1 02-23 X 1 O.497
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. lntens. Mean
482649.926
230.488
1A74.04A
1580.087
772.688
2024.4A8
Net lntens- Mean
482649,93
-0.00
-0.00
0.00
-0.00
-0.00
Conc. Mean
-0.0404
-0.0096
0.0399
-0.1 1 16
-0.0464
Conc. RSD
788.8697
234.8639
211.3757
126.7124
99.1721
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Conc. SD
0.3186
4.4225
0.0843
0.1 41 5
0.0461
[,
Analyte Mass QC Std 7o Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Ditf Dup. Rel. % Dttt
87.800
QC Out Of Limits
Out of Limits Message
Page 79
METHOD 200.8 SUMMARY REPORT
Sample lD:090102-24 X 10
Sample Date/Time: Wednesday, September 28,2OAS 21:10:58
Sample Type: Sample
Sample Description: BATCH 1667 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\0901 02-24 X 1 0.498
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c\elandata\Optimize\default.dac
Concentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Meas. lntens. Mean
498219.327
Q2.436
764.687
1078.707
547.010
1371.403
Net lntens. Mean
498219.33
-0.00
-0.00
-0,00
-0.00
-0.00
Conc. Mean
-1.0156
-0.8322
-0.8598
-0.9182
-0.9515
Conc. SD
0.2277
0.0930
0.0896
0.0196
0.0153
Conc. RSD
22.4182
11.1732
10.4274
2.1352
1.6096
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
QC Action Line: No QC out of limits detected
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Ditf Dup. Rel. % Dift
90.632
QC Out Of Limits
Out of Limits Message
QC Action
Page 80
METHOD 200.8 SUMMARY REPORT
Sample lD:0901A2-25 X 10
Sample Date/Time : Wed nesday, September 28, 2005 21 :1 4:21
Sample Type: Sample
Sample Description: BATCH 1667 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: clelandata\Method\20O.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\0901 02-25 X 1 0.499
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Analyte
Tb
Hf
Hf
Hf
Hf
Hf
Mass Meas- lntens. Mean
159 482069.081
176 83.433
177 591.346
178 851.025
179 428344
180 1056.380
Net lntens. Mean
482069.08
-0.00
-0.00
-0.00
-0.00
-0.00
Conc. Mean
-1.3178
-1.1993
-1.1840
-1.2*A
-1.3040
Conc. SD
0.27 41
0.08s3
0.0650
0.0703
0.1 007
20.8018
7.1134
5.4866
5.6052
7.7244
Conc. RSD Sample Unit
[,r-
ug/L
ug/L
uglL
ug/L
ug/L
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
OC Action Line: No QC out of limits detected
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Dift Dup. Rel. % Datf
87.694
QG Out Of Limits
Out of Limits Message
QC Action
Page 81
METHOD 200.8 SUMMARY REPORT
Sample lD:090102-26 X 10
Sample Date/Time: Wednesday, September 28, 2OO5 21 :17 :45
Sample Type: Sample
Sample Description: BATCH 1667 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\defaulM90102-26 X 1 0.500
Tuning File: c:\elandata\Tuning\default-tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas- lntens. Mean
s47195.967
28.853
511.676
738.352
369.671
961.586
Net lntens. Mean
507195.97
-0.00
-0.00
-0.00
-0.00
-0.00
Conc. Mean
-1.8068
-1.4595
-1.4353
-1.5096
-1.4895
Conc. SD Conc. RSD Sample Unit
[,
14.7 579 ug/L
6.6854 ug/L
2.7082 ug/L
2.2413 ug/L
2.2583 ug/L
0.2667
0.0976
0.0389
0.0338
0.0336
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Measurement Type Analyte Mass
QC Action Line: No QC out of limits detected
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Datt Dup. Rel. % Ditt
92.265
QC Out Of Limits
Out of Limits Message
QC Action
Page 82
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-27 X 10
Sample Date/Time: Wednesday, September 28, 2005 21:21:Og
Sample Type: Sample
Sample Description: BATCH 1667 URS
Number of Replicates: 3
Sample File: C :\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\ela ndata\Dataset\default\090 1 02-27 X 1 0. 50 1
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Analyte Mass Meas. lntens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit
Hf
Hf
Hf
Hf
Hf
159
176
177
178
179
180
506397.215
37.248
408.673
562.678
304.337
745.757
Net lntens. Mean
506397.2 f
-0.00
-0.00
-0.00
-0.00
-0.00
-1.73/9
-1.6995
-1.7148
-1.7152
-1.7549
0.1 685
0.0607
0.0304
0.0576
a.0229
ug/L
9.7129 ug/L
3.5739 ug/L
1.7745 ug/L
3.3579 ug/L
1.3055 ug/L
QC Calculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery
Tb 159 92j20
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
QC Out Of Limits
Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Dilution % Ditf Dup. Rel. % Ditt
[,
Io
I
L
Page 83
METHOD 200,8 SUMMARY REPORT
Sample lD: QG Std 3
Sa mple Dateff ime: Wednesday, September 28, 2OO5 21 :24:36
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\20O.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\QC Std 3.502
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
[,
Analyte Mass
Tb 1s9
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas- lntens. Mean
559614.295
74625.278
2486123A2
366898.231
184793.473
478199.665
Net lntens. Meant
559614.30
0.13
o.44
0.65
0.33
0.8s
Concentration Results
Conc. Mean
52.7495
s2.6524
52.9158
s2.6660
53.3674
Conc. RSD
1.4491
1.99s0
1.8881
2.2709
0.9619
Sample Unit
uglL
ug/L
ug/L
ug/L
ug/L
ug/L
Analyte Mass QC Std % Recovery
Tb 159
Hf 176 105.499
Hf 177 105.305
Hf 178 105.832
Hf 179 105.332
Hf 180 106.735
Dup. Rel. % Ditt
[,
QG Out Of Limits
Out of Lirnits MessageMeasurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
"{ttConc. SD
0.7644
1.0504
0.9991
1.1960
0.5133
QG Galculated Values
lnt Std % Recovery Spike % Recovery Dilution o/o Diff
101.801
Page
METHOD 200.8 SUMMARY REPORT
Sample lD: QG Std 4
Sa mple Date/Time : Wednesday, September 28, 2OA5 21 31 :43
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniurnall.mth
Dataset File: c:\elandata\Dataset\default\QC Std 4.503
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default-dac
Concentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. Intens. Mean
567281.526
247.618
1274.724
1884.124
996.701
2481.802
Net Intens. Mean
567281.53
-0.00
0.00
0.00
0.00
0.00
Conc. Mean
-a.4212
0.0017
0.0078
0.0139
0.0067
0.0284 134.1 315
0.0125 753.9837
0.0138 175.6385
0.0048 34.5A44
0.0188 280.3139
Conc. SD Conc. RSD Sample Unit
ug
ug/L
ug/L
ug/L
ug/L
ug/L
[,
to
I
L
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
QG Calculated Vatues
lnt Std % Recovery Spike % Recovery
103.195
Dilution o/o Dift Dup. Rel. o/" Diff
QC Out Of Limits
Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page 8s
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-28 X 10
Sa mple Dateff ime: Wednesday, September 28, 2OO5 21 :34;27
Sample Type: Sample
Sample Description: BATCH 1667 URS
Number of Replicates: 3
Sample File: C:\EIandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File : c:\ela ndata\Dataset\default\0901 02-28 X 1 0.504
Tuning File : c:\elandata\Tuning\default.tun
Optirnization File: c:\elandata\Optimize\default.dac
Concentration Results
Net lntens. Mean Conc. Mean, Analyte Mass
[, Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
[,
Meas. lntens. Mean
522494.044
215.673
1142.749
1609.091
822.690
2086.791
522494.O4
-0.00
-0.00
-0.00
-0.00
-0.00
Conc. RSD
14.9514
1.8831
99.7124
104.8906
51.7503
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
-0.31 16
-0.1464
-o.1172
-0.1532
-0.1719
Conc. SD
0.0466
0.0028
0.1169
0.1607
0-0890
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QG Calculated Values
lnt Std o/o Recovery Spike % Recovery
95-048
Dilution % Ditt Dup. Rel. % Ditt
QC Out Of Limits
Out of Limits MessageMeasurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
Page 86
METHOD 200.8 SUMMARY REPORT
Sample lD:090102-29 X 10
Sa mple Date/Time : Wednesday, Se ptember 28, 2AA5 21 :37 :53
Sample Type: Sample
Sample Description: BATCH 1667 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sa m
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\090102-29 X 1 0.505
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. lntens. Mean
529902.981
116.267
764.354
11U.712
577.678
1404.741
Net lntens. Mean
529902.98
-0.00
-0.00
-0.00
-0.00
-0.00
Conc. Mean
-1.1234
-0.9422
-0.8790
-0.9306
-1.0154
Conc. RSD
16.3896
0.8s63
10.3019
5.4670
4.4346
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Conc. SD
0.1 841
0.0081
0.0906
0.0509
0.0450
QC Calculated Vatues
Anatyte Mass QC Std % Recovery Int Std % Recovery Spike % Recovery
Tb 1s9 96.396
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
QC Out Of Limits
Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Dilution % Ditf Dup. Rel. % Ditf
[,
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-30 X 10
Sample Date/Time: Wednesday, September 28, 2OOS 21 :41 :1 I
Sample Type: Sample
Sample Description: BATCH 1667 URS
Number of Replicates: 3
Sa mple File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\defaulM90102-30 X 1 0.506
Tuning File: c:\elandata\Tuning\default-tun
Optimization File: c:\elandata\Optimize\default.dac
[,
Analyte Mass Meas. lntens. Mean
Tb 159 532461 .401
Hf 176 50.2A2
Hf 177 550,344
Hf 178 806.689
Hf 179 417.006
Hf 180 1018.020
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Measurement TypeAnalyte Mass
QC Action Line: No QC out of limits detected
Concentration Results
Net lntens. Mean Conc. Mean
532461.40- ---"' t
-0.00
-0.00
-0.00
-0.00
-0.00
-1.6476
-1.4291
-1.3870
-1.4224
-1.4796
Conc. SD
0.1358
0.0408
a.oa77
0.0735
0.0370
Conc. RSD
8.24s1
2.8534
0.5561
5.1678
2.5033
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
[,
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution a/o Diff Dup. Rel. % Ditt
96,861
QC Out Of Limits
Out of Limits Message
QC Action
Page 88
METHOD 200.8 SUMMARY REPORT
Sample lD:09010244 X 10 MS-31 2.5 OF 10
Sample Date/Time: Wednesday, September 28,2005 21:44:44
Sample Type: Sample
Sample Description: BATCH 1667 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\defaulM9010244 X 10 MS-31 2.5 OF 10-507
Tuning File: c\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas- lntens. Mean
541871.088
47621.606
1681 42.521
248754.046
124894.433
321505 .341
Net Intens. Mean
541871 .09
0.09
0.31
0.46
4.23
0-59
Conc. Mean
366.7092
366.9721
369.7286
366-8300
369.7359
Conc. RSD
2.1716
2.1521
2.1392
1.7928
2.0501
Sample Unit
ug/L
ug/L
ug/L
ugll
ug/L
uglL
Conc. SD
7.9635
7.8976
7.9092
6.5766
7.5798
[,
QC Calculated Values
lnt Std % Recovery Spike % Recovery
98.573
I
Dilution % Drtt Dup. Rel. % DiftAnalyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180 tslx 570- | > Y/| 7- f. *x<ry
5oo
Is tL57
Gc li I',rr,'+)
QC Out Of Limits
Out of Limits MessageMeasurement TypeAnalyte Mass
QC Action
QC Action Line: No QC out of limits detected
Page 89
METHOD 200.8 SUMMARY REPORT
Sample lD: 09010245 X 10 MSD-30 2.5 OF 10
Sample Dateffime: Wednesday, September 28, 2005 21 :48:1 1
Sample Type: Sample
Sample Description: BATCH 1667 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\09010245X 10 MSD-30 2.5OF 10.508
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
110595.519
162698.073
81522.358
212167.A26
Meas- lntens.-Mean---,Slet lntens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit
[,162.67
198.14 831443.9142
699.92 833819.6127
1029.A2 ffi4695.5450
515.17 825949.8379
1342.16 842499.931 1
163954.8277
164476.3170
161515.8299
155367 .7342
164259.4428
r
19.71 93 ug/L
19.7256 ug/L
19.3503 ug/L
18.8108 ug/L
19.4967 ug/L
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Measurement Type Analyte Mass
Tb 159 lnt Std for siTb 159
QC Action Line: Continue
QC Galculated Values
lnt Std % Recovery Spike % Recovery Dilution % Ditf Dup. Rel. o/o Ditf
QC Out Of Limits
Out of Limits Message
lnternat Std Out of Limits
QC Action
Page 90
METHOD 200.8 SUMMARY REPORT
Sample ID: QC Std 3
Sample Date/Time: Wednesday, September 28,2AA5 21:54:39
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafnlurnall.mth
Dataset File: c:\elandata\Dataset\default\QC Std 3,509
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Goncentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. lntens, Mean
ss4689.573
71677.574
249957.341
371542.000
187234.085
481377.205
Net lntens. Mean
554689.57
0.13
0.45
0.67
0.34
0.86
Conc. Mean
54.0178
53.4145
54.0648
53.8488
54.2062
Conc. RSD
1.2688
1.4988
0.2815
0.s666
o.9474
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176 108.036
Hf 177 106.829
Hf 178 108.130
Hf 179 107.698
Hf 180 108.412
Measurement Type Analyte Mass
QG Action
QC Action Line: No QC out of limits detected
Ja-
Conc. SD
0.6854
0.8006
4.1522
0.3051
0.5135
QG Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. % Ditf
100.905
QC Out Of Limits
Out of Limits Message
Page 91
METHOD 2A0.8 SUMMARY REPORT
Sample ID: QC Std 4
Sample Date/Tirne: Wednesday, September 28, 2AAS 22:01 :06
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\e[andata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\Qc Std 4.51 0
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\ela n data\Opti mize\d efa u lt.dac
Concentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. [ntens. Mean
s71735.004
407 -581
1725.438
2546.894
1248.388
3229.959
Net lntens. Mean
571735.00
0.00
0.00
0.00
0-00
0.00
Conc. Mean
0.0949
0.0935
0.0998
0.0823
0.0867
47.3145 ug/L
22.2048 ug/L
26.0482 ug/L
21.2772 ug/L
5.5539 ug/L
Conc- SD Conc. RSD Sample Unitre_-
0.0449
0.0208
0.0260
0.0175
0.0048
QC Calculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery
Tb 159 104.006
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Measurement TypeAnalyte Mass
QC Out Of Limits
Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Dilution % Ditf Dup. Rel. % Ditf
[,
Page 92
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-31X 10
Sample Date/Time: Wednesday, September 28,2405 22:04:31
Sample Type: Sample
Sample Description: BATCH 1667 URS
Number of Replicates: 3
Sample File: C:\EIandata\Sample\092805-3.sam
Method File: c:\elandata\Method\2O0.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\defaulM90102-31 X 1 0.51 1
Tuning File: c\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Analyte Mass Meas. lntens. Mean Nel lntens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit
>Tblss.--513260.694513260.69_-_
Hf 176 371.526 0.00 0.9931 0.0997 10.0364 us/L
Hf 177 1629.760 0.00 1.1223 0.0260 2.3145 uglL
Hf flA 2418.871 0.00 '1.2066 0.0526 4.3591 ug/L
Hf 179 1190.050 0-00 1.0391 0.0737 7.0974 ug/L
Hf 180 3093.788 0.00 11040 0.0794 7.1948 ug/L
QG Calculated Values
Analyte Mass QC Std % Recovery lnt Std 7o Recovery Spike % Recovery Dilution 7o Diff Dup. Rel- % Diff
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
93.368
QC Out Of Limits
Measurement Type Analyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page 93
METHOD 200.8 SUMMARY REPORT
Sample lD:090102-32 X 10
Sample Dateffime: Wednesday, September 28,2005 22:07:59
Sample Type: Sample
Sample Description: BATCH 1667 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\defau 1t\090 1 02-32 X 1 0.512
Tuning File: c\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Net lntens. Mean
482696.41
0.00
0.00
0.00
0.00
0.00
Conc. Mean
0.1146
0.2722
0.3s47
0.3205
0.3184
Conc. SD
0.1 503
0.1 988
0.1480
0.0936
0.0864
Conc. RSD
131 .1776
73.0359
41.7378
29.2019
27.1226
Sampte Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Meas. lntens. Mean
482696.411
248.233
1188.716
1768.110
903.029
2305.479
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf r80
QC Calculated Values
lnt Std % Recovery Spike % Recovery
87.808
Dilution o/o Diff Dup- Rel. o/o Diff
QC Out Of Limits
Out of Limits MessageMeasurement Type Analyte Mass
QG Action
QC Action Line: No QC out of limits detected
Page 94
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-33 X 10
Sa mple Date/Time: Wed nesday, September 28, 2005 22:1 1 :27
Sample Type: Sample
Sample Description: BATCH 1667 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method900.8\hafniumall.mth
Dataset File : c:\elandata\Dataset\default\090 1 0 2-33 X 1 0.5 1 3
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,
Analyte
Tb
Hf
Hf
Hf
Hf
Hf
Mass
159
176
177
178
179
180
Meas. lntens. Mean
480691 .778
136.894
831.691
1179.049
624.680
1612.878
Net lntens. Mean
480691.78
-0.00
-0.00
-0.00
-0.00
-0.00
Conc. Mean Conc- SD
-0.8499 0.1258
-0.s995 0.0368
-0.6266 0.0971
-0.5953 0.1335
-0.5732 0.0167
Conc. RSD
14.8007
6.1334
15.4932
22.4231
2.9156
Sample Unit
ug/L
ug/L
uglL
ug/L
ugll
ug/L
[,
C
I
L
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QC Calculated Values
lnt Std % Recovery Spike % Recovery
87.444
Dilution "lo Ditf Dup. Rel. o/o Diff
QC Out Of Limits
Measurement TypeAnalyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-34 X 10
Sample Dateff ime: Wednesday, September 28, 2OO5 22:1 4:54
Sample Type: Sample
Sample Description: BATCH 1667 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\0901 02-34 X 1 0.514
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,
I
Anatyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. lntens. Mean
551459.961
30.531
510.342
698.350
364.338
900.580
Net lntens- Mean
551459.96
-0.00
-0.00
-0.00
-0.00
-0.00
Conc. Mean
-1.8123
-1.5587
-1.5889
-1 .6190
-1.6541
Conc. SD
0.0956
4.a776
0.0386
0.0300
0.0368
Dilution % Ditt
Conc. RSD
s.2769
4.9816
2.4262
1.8558
2.2263
Sample Unit
ugTL
uglL
ug/L
ug/L
ug/L
uglL
Analyte Mass QC Std 7o Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QC Calculated Values
lnt Std % Recovery Spike % Recovery
100.317
QC Out Of Limits
Out of Limits Message
Dup. Rel. % Datt
[,
Measurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
Page 96
METHOD 200.8 SUMMARY REPORT
O Sampte ID: 090 102-35 X 10
Sa mple Date/Time: Wed nesday, September 28, 2005 22:1 8:23
Sample Type: Sample
Sample Description: BATCH 1667 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\090102-35 X 10.51 5
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c\elandata\Optimize\default.dac
Goncentration Results
Analyte Mass Meas. lntens. Mean Net lntens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit
> Tb 159 497962.578 497962.ffi rr0lt-
Hf 176 39.369 -0.00 -1.7124 0.1121 6.5454 ug/L
Hf 177 511.676 -0.00 -1.4368 0.0995 6.9284 ug/L
Hf 'l'78 733-686 -0.00 -1.4211 0.1413 9.9455 uglL
Hf 179 383.005 -0.00 -1-4454 0.0698 4.8267 udl
Hf 180 944.747 -0.00 -1.4886 0.0779 5-2310 ug/L
QG Galculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. 7o Diff
[, Tb 159 90.585
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QC Out Of Limits
Measurement Type Analyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page 97
METHOD 200.8 SUMMARY REPORT
Sample lD: QC Std 3
Sample Date/Time: Wednesday, September 28,20A5 22:21:52
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\eJandata\Dataset\default\QC Std 3.51 6
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. lntens. Mean
544A41.990
68268.055
239391 .982
353419.9s2
177754.084
462332.791
Net lntens- Mean
544441.99
o.12
4.44
0.65
0.33
0.85
Conc. lutgan
52.4489
52.1510
52.4319
52.1111
53.4717
Conc. SD
0.4384
0.6013
0.1101
9.7427
0.81 13
Conc. RSD
0.8358
1 .1530
o.2101
1.4252
1.5287
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
QC Galculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery
Tb 159 98.968
Hf 176 104.898
Hf 177 104.302
Hf 178 104.864
Hf 179 104.222
Hf 180 106.143
Measurement Type Analyte Mass
QC Out Of Limits
Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Dilution % Dift Dup. Rel. o/o Ditt
[,
Page 98
METHOD 200.8 SUMMARY REPORT
Sample lD: QC Std 4
Sample Date/Time: Wednesday, September 28,2A05 22:28:19
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
M ethod File : c :\e la n data\M ethod\200.8\hafn iu ma I l. mth
Dataset Fite: c:\elandata\Dataset\default\Qc Std 4.517
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Goncentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Meas. lntens. Mean
563281.090
312.722
1551 .084
2213.172
1118.711
2854.541
Net lntens. Mean
563281.09
0.00
0.00
0.00
0.00
0.00
Conc. Mean
4.4287
0.0621
0.0571
0.0507
0.0502
Conc. SD
4.0251
0.020s
0.0125
0.0154
0.0161
Conc. RSD Sample Unit
ug/L
87.3184 ug/L
32.9887 ug/L
21.8114 ug/L
30.3789 ugll
32.1376 ug/L
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QC Out Of Limits
Measurement Type Analyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Ditt Dup. Rel. % Diff
102.468
Page
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-36 X 10
Sample Date/Time: Wednesday, September 28,2005 22:31:46
Sample Type: Sample
Sample Description: BATCH 1667 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\0901 02-36 X 1 0.51 I
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas- lntens. Mean
498929.400
282.402
1183.716
1703.768
831.358
2243.559
Net lntens. Mean
498929.40
0.00
0.00
0.00
-0.00
0.00
Conc. Mean
0.3311
0.1 656
0.1543
-0.0068
0.1436
Conc. SD Conc. RSD Sample Unit
[,
81.4706 ug/L
27.6686 ug/L
31.1466 ug/L
1282.2754 ug/L
34.9449 ug/L
0.2698
0.0458
0.0481
0.0873
0.0s02
QC Calculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery
Tb 159 90.761
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
QC Out Of Limits
Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Dilution % Ditf Dup. Ret. % Ditf
[,
Page 100
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-37 X 10
Sa mple Date/Time: Wednesday, September 28, 2OO5 22:35: 1 2
Sample Type: Sample
Sample Descriptlon: BATCH 1667 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Datraset\default\090 1 02-37 X 1 0. 5 1 I
Tuning File: c\elandata\Tuning\default.tun
Optimization File: c\elandata\Optimize\defa ult.dac
Concentration Results
, Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
lntgps. Mean
s19655.538
148.691
951.032
1348.064
662.349
1737.362
Mass QC Std % Recovery
159
176
177
178
179
180
Net lntens. Mean
519655.54
-0.00
-0.00
-0.00
-0.00
-0.00
QC Calculated Values
lnt Std % Recovery Spike % Recovery
94.532
Cong,_!L _ Conc. RSD Sample Unitugtr- - -
0.1 789
0.0446
0.0793
0.0545
0.0110
Dilution "/o Diff Dup. Rel. % Ditt
Conc. Mean
-0.8446
-0.4800
-0.5123
-0.634s
-0.5807
21.1853 ugll
9.2931 ug/L
15.4841 ug/L
8.5862 ug/L
1.8990 ug/L
Analyte
[, Tb
Hf
Hf
Hf
Hf
Hf
Measurement Type Analyte Mass
QC Action Line: No QC out of limits detected
QC Out Of Limits
Out of Limits Message
QC Action
Page 10I
METHOD 200.8 SUMMARY REPORT
Sample lD: 0901A246 X 10 MS-37 2.5 OF 10
Sample Date/Time: Wednesday, September 28, 2OO5 22:38:34
Sample Type: Sample
Sample Description: BATCH 1667 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\0901 0246 X 1 0 MS-37 2.5 OF 1 0.520
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Meas. lntens. Mean
523996.6s3
47016.687
166807.824
244895.s95
123442.090
319044.516
Net lntens. Mean
523996.65
0-09
0.32
0.46
4.23
0.60
Conc. Mean
374.4868
376.5719
376.4879
373.8048
37e.s036 lrk
1.5222 ug/L
1.6954 ug/L
1.2748 ug/L
2.0881 ug/L
1.5274 ug/L
conc. s_? _ 99ry. ns? _ _9rIple unit
ug/L
5.7006
6.3844
4.7844
7.8053
5.7966
[,
Analyte Mass QC Std o/o Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
QC Action
QC Action Line: No QC out of timits detected
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Ditf Dup. Rel. olo Dffi
95.321
QC Out Of Limits
Out of Limits Message
Page 102
METHOD 200.8 SUMMARY REPORT
Sample lD: 09010247 X 10 MSD-37 2.5 OF 10
Sample Date/Time: Wednesday, September 28, 2005 22:41 :57
Sample Type: Sample
Sample Description: BATCH 1667 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\09010247 X 10 MSD-37 2.5 OF 10.521
Tuning File: c:\elandatia\ tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Goncentration Results
[,
Analyte Mass
Tb 1s9
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. lntens. Mean
528303.347
48146.956
169497.01 3
252433.349
126445.632
327742.111
Net lntens. Mean
528303.35
0.09
o.32
4.47
4.24
o.62
Conc- Mean Conc. SD
380.3239 7.6152
379.5127 5.3627
384.9520 4.0548
381.0323 l, 4.5480
386.715e e-t/ 4.1453
Conc. RSD
2.0423
1.4131
1.0533
1 .1936
1 .0719
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurernent Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
QC Galculated Values
lnt Std % Recovery Spike % Recovery Dilution % D,tt Dup. Rel. % Ditf
96.1 05
QC Out Of Limits
Out of Limits Message
ol
Page 103
METHOD 200.8 SUMMARY REPORT
Sample lD: QG Std 3
Sample Date/Time: Wednesday, September 28,2OA5 22:48:23
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sarn
M eth od F i Ie : c :\ela ndata\Method\200.8\hafn iu ma ll. mth
Dataset File: c:\elandata\Dataset\default\Qc Std 3.522
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. lntens. Mean
570219.081
72351.255
254786.655
378l-78.903
189155.890
488278.420
Net tntens. Mean
57A219.08
0.13
4.44
0.66
0.33
0.85
Conc. Mean
53.0359
52.9587
53.5729
52.9094
53.4771
Conc. SD
0.6799
a.9425
0.9381
1.2396
1.1716
Conc. RSD
1.2824
1.7797
1.7510
2.3430
2.1909
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
[,
Analyte Mass QC Std 7o Recovery
Tb 159
Hf 176 146.472
Hf 177 105.917
Hf 178 fi7146
Hf 179 105.819
Hf 180 106.954
QC Galculated Vatues
lnt Std % Recovery Spike % Recovery
103.730
Dilution % Dttf Dup. Rel. % Ditf
QC Out Of Limits
Out of Limits MessageMeasurement Type Anatyte Mass
QC Action
QC Action Line: No QC out of limits detected
Page 104
METHOD 200.8 SUMMARY REPORT
Sample lD: QC Std 4
Sample Dateff ime : Wednesday, September 28, 2OO5 22:54:50
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\092805-3.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: c:\elandata\Dataset\default\QC Std 4.523
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c\elandata\Optimize\default.dac
t_
R/rc/
Concentration Results " /
Analyte Mass Meas. lntens. Mean Net lntens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit
> Tb 159 580818.079 ' 580818.08 ug/L
Hf 176 391.272
Hf 177 1821.783
0.00 0.0783 0.0166 21.1889 ug/L
0.00 0.1076 0.006s 6.0350 ug/L
Hf 178 2642.578 0.00 0.1075 0.0090 8.3339 ug/L
Hf 179 1310.060 0-00 0.0938 0.0153 16.3479 ug/L
Hf 180 3430.328 0.00 0.1028 0.0116 11.2776 ug/L
QG Calculated Values
Analyte Mass QC Std 7" Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. % Diff
[, Tb 159
I Hf 176qil fi
L Hf 180
105.658
QC Out Of Limits
Measurement Type Analyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
SamplelBatch Report
User Name: Owner
Computer Name: ICPMS02
Sample Fite: C:\Elandata\Sample\1 01 805-1 .sam
Report Date/Time: Tuesday, October 18, 2005 14:46:28
wl WMS^{,os
fflotlqcd Affi'B'ffsffibe
_nrt*e1r4
-eei'Sq 7c
t qb tof tsldg
A/S Loc. Batch lD
9 101805-1
10 101805-1
11 1 01 805-1
1 0 101805-1
12 101805-1
12 101805-1
12 10180s-1
13 101 805-1
14 f 01805-1
15 101805-1
16 101805-1
17 101805-1
1B 101805-1
19 101805-1
20 101805-1
21 101805-1
22 10180s-1
23 101805-1
24 10180s-1
25 101805-1
26 101805-1
2A 101805-1
21 101 805-1
22 101805-1
23 101805-1
24 101805-1
26 101805-1
27 101 805-1
28 101805-1
29 101805-1
Sample lD
3020A X 10
090102-2 X 50
0901 02-2 X 50
0901 02-2 X s0
3020A BLK X20
0901 a2-21 XzA
0901 a2-22X2A
0901 02-23 X 20
090102-24 X 2A
0901 02-25 X 2A
0901 a2-26 X 20
0901 02-27 X 2A
090102-28 X 20
090r 02-29 x2a
090102-30 x 20
090102-31 X 20
0901 02-32 X20
090102-33 X 2A
0901a244 X 20
090102-35 X 20
090102-36 X 20
090102-37 X 20
Description
BATCH 1666 DIG 9122 KW
BATCH 1666 URS
BATCH 1666 URS
BATCH 1666 URS
BATCH 1698 DIG 9129 KW 1414
BATCH 1698 URS
BATCH 1698 URS
BATCH 1698 URS
BATCH 1698 URS
BATCH 1698 URS
BATCH 1698 URS
BATCH 1698 URS
::iY
tnit. Quant"Prep. Vol.
3O2OA STD X 10 2.5 OIBATCH 1666 DIG 9122 KW
090102-1 X 2A BATCH 1666 URS
3O2OA STD X 10 2.5 OIBATCH 1666 DIG 9122 KW
Aliquot Vot.
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1-000
1.000
1.000
Diluted Vc
10.0c
10.0c
20.0c
10.0c
50.0c
50.0c
-s-Q'oc
20.0c
20.0c
20.00
20.00
20.00
20.o0
20.00
20.00
20.00
20.00
20.00
CBB
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
3020A STD X2A 2,5 oIBATCH 1698 DIG 9129 KW 1414
BATCH 1698 URS
BATCH 1698 URS
BATCH 1698 URS
BATCH 1698 URS
BATCH 1698 URS
BATCH 1698 URS
BATCH 1698 URS
BATCH 1698 URS
BATCH 1698 URS
BATCH 1698 URS
0901 0244 MS-30 X20BATCH 1698 URS
OgO1A2-45 MSD-30 X 2BATCH 1698 URS
0901 02-46X2A MS-37BATCH 1698 URS
O9O1 0247 X 2A MSD- :BATCH 1698 URS
.Ml
Page 1
Page 106
ICP-MS QADATAREVIEW
/METHoD BATCm* /bbbOmALYST t9# DATE,'idt/6
/bq66
o
Yes i, 19)
200.8 6020
QCS STD 1
(IC\r)eo-na% 0L 90-rla%
QCS STD 3
(ccv)
Every l0 Samples
e0- rL}% 0{t 90-ttoo6
QCS STD 4
(rcB 0RCCB)
CCB Every l0 Samples
CCB<IDL L CCB<IDL
ICSA NA No Specific Limits
ICSAB NA No Specific Limits
Suggested: 80-120%
LRB
Every 20 Sarrrples
a,o%or,S^n"*,xMDr
conc.
42X MDL OR <l0oz6Analyte
Crcnc.
QCS STD 5
(LFB)
Every 20 samples
0/a
'7q<z€
8sp8%85-tt5o.A
Duplicates
Every lO samples <2ORPD <2ORPD
Matrix Spikes (LFM)
(MS orMSD)
Every l0 samples @ 9)e'/ TilZ1 75-n5a
Internal Standards 60-rzs%
e,L--
30-t20o.
Dilution Test
lf analyte conc. >100 x BIk 1 + 4 Dilution
90-rtO%
I + 4 Dilution
90-lrcyo
One for every 20 samples
comments: ik";
i'\
Date
Reyierved
Revierver's
Initials
PEER REVIEW (Calc- ),uitrllrj 1y*,,
OA DATA REVIEW
REPORTED IN VLP
VLP REVIEW
Noncon formanc e attached
Page 107
Daily Performance Report
Sample lD: Daily Performance Check
Sample Date/Time: Tuesday, October 18, 2005 11:06:16
Sample Description:
Method File: c:\elandata\Method\Daily.mth
Dataset F ile: c:\elandata\Dataset\Optimize\Daily Performance Check.394
Tuning File: c:\elandata\Tuning\default-tun
O ptim ization Fil e : c:\e Ia ndata\Optim ize\Defa u It. da c
Dual Detector Mode: Pulse
Acq. Dead Time(ns): 35
Current Dead Time (ns): 35
Analyte
Mg
Summary
Mass Meas. lntens. Mean Net lntens. Mean
24.O 38291.0 38290.984
Net lntens. SD
310.6s1
1275V99
172A308
611 .982
560.818
1003.210
0.000
786.396
0.000
0.333
Net lntens. RSD
0.8
0.5
0.6
0.7
0.4
a.7
1.4
0_5
1.4
8.3
259691 .4
271041.5
90766.0
129579.2
139858.7
1386.5
16981 1.5
5171.5
4.0
259691.370
271AU.541
90766.A44
129579.233
139858 .712
0.010
169811.512
0.030
4.000
Rh
ln
Pb
U
f, Ba
L Ba++
[, Ce
L Ceo
Bkgd
102.9
114.9
208.0
238.1
137.9
69.0
139.9
155.9
220.4
Current Optimization File Data
Current Value Description
0.80 Nebutizer Gas Flow
6.80 Lens Voltage
1250.00 ICP RF Power
-1950.00 Analog Stage Voltage
1550.00 Pulse Stage Voltage
70.00 Discriminator Threshold
-8.50 AC Rod Offset
60.00 Service DAC 1
0.00 Quadrupole Rod Offset
-1 5.00 Differential Aperture
Current Autolens Data
Analyte Mass Num of Pts
8e936
Co 59 36
ln 115 36
DAC Value
6.3
6.5
6.8
Maximum lntensity
1 900.1
116313.9
276164.8
Sample tD. Daily Performance Check
Report Date/Time: Tuesday, October 18, 2005 11 .10.05
Page 1
Page 108
SrnartTune Wizard - Summary
fization
Summary
Wizard file: C:\Elandata\Wizard\SmartTune\Default Basic Opt.swz
Start Time: 10:35:02, Tuesday, October 18, 2005
End Time: 1 1 :10:05, Tuesday, October 1 B, 2005
Lens Voltage - [Passed] Optimum value(s): 6.8
Obtained lntensity (Rh 102.905): 266705
Nebulizer Gas - [Passed] Optimum value(s): 0.8
Obtained lntensity (Rh 102.905): 253558 Obtained Formula (CeO 155.9 / Ce 139.905): 0.029 (=4917 / 167396)
Auto Lens Calibration - [Passed] Optimum value(s): y = 0.005 x + 6.245
Mass Calibration and Resolution - [Passed] Optimum value(s): N/A
TargeUObtained mass (3.01 6/3.027), TargeUObtained resolution (0.7i0.696)
TargeUObtained mass (23.985123.979), TargeUobtained resolution (0.7/0.694)
TargeUObtained mass (102.9051102.929), TargeUObtained resolution (0.7/0.706)
TargeUObtained mass (139.905/139.928), TargeUObtained resolution (0.710.704)
TargeUObtained mass (207.9771207.978), TargeUObtained resolution (0.7/0.703)
TargeUObtained mass (238.05/238.075), TargeUObtained resolution (0.71O.712)
Djrily Performance Check - [Failed]
IOOI ined lntensity (Bkgd220):4
U OUtrined lntensity (ln 1 14.904) : 27 1O42
Obtained lntensity (Mg 23.985): 38291
Obtained lntensity (Pb 207 .977): 90766 - <Target not achieved>
Obtained lntensity (Rh 102.905): 259691
Obtained Formula (CeO 155.9 / Ce 139.905): 0.030 (=5171 I 169812)
Obtained Formula (Ba++ 68.9525 lBa+ 137.905): 0.010 (='1167 / 140339)
Report Date/Time: Tuesday, October 18, 2005 11:10.05
Page 1
Page 109
SmartTune Wizard - Details
Optimization Details
Wizard file: C:\Elandata\Wizard\SmartTune\Default Basic Opt.swz
Optimization Status
Start Time: 10:35:02, Tuesday, October 18, 2005
Lens Voltage
Optimization Settings:
Method: Optimize.mth.
First pass - StarUEnd/Step: 3/8/0.1.
lntensity Criterion: Rh 102.905 Maximum
Optimization Results:
First pass
Obtained lntensity
[Passed] Optimum value(s):
(Rh 102.905): 266705
6.8
Nebulizer Gas
Optimization Settings:
Method: Optimize.mth.
First pass - StarUEnd/Step: 0.710.95/0.01 .
lntensity Criterion: Rh 102.905 Maximum
Formula Criterion: CeO 155.9 / Ce 139.90$ <= 0.03
Optimization Results:
First pass
Obtained lntensity (Rh 102.905): 253558
Obtained lntensity (Rh 102.905): 253558 Obtained Formula (CeO 155.9 / Ce 139.905): 0.029 (=49171 167396)
[Passed] Optimum value(s): 0.8
Auto Lens Calibration
Optimization Settings:
Method: Autolens Calibration-mth.
First pass - StarUEndlStep: 5/8.5/0.1.
Optimization Results:
First pass
[Passed] Optimum value(s): y = 0.005 x + 6.245
Mass Calibration and Resolution
Optimization Settings:
Method: tuning.mth.
Tuning File: default.tun
Iterations: 6
Target accuracy (+/- amu): 0.03 for Mass Cal. and 0.1 for Resolution
Peak height (%) for Res. Opt.: 10
Optimization Results:
First pass
TargeUObtained mass (3.0 1 61 3.O27 ), TargeUObtained resolution (0.7/0.695)
TargeUObtained mass (23.985124.029), TargeUObtained resolution (0.7/0.713) - <Target not achieved>
TargeUObtained mass (1O2.9051102.879), TargeUObtained resolution (0.7/0.705)
TargeUObtained mass (139.905/139.879), TargeUObtained resolution (0.710.716)
TargeUObtained mass (2O7.9771207.979), TargeVObtained resolution (0.71O.726)
TargeUObtained mass (238.05/238.028), TargeUObtained resolution (O.71O.731)
IFailed]
Report Date/Time: Tuesday, October 18, 2005 1 1:10:05
Page 2
Page 110
Retry 1
IPassedJ
Daily Performance Check
Optimization Settings:
Method: Daily.mth.
lntensity Criterion: Bkgd 22A <= 30
lntensity Criterion: ln 114.904 > 100000
lntensity Criterion: Mg 23.985 > 20000
l11!e n$y_CrLleLpL_l ? ry7 .st 7 > 1 00000
lntensity Criterion: Rh 102.905 > 100000
Formula Criterion: CeO 155.9 / Ce 139.90$ <= 0.04
Formula Criterion: Ba++ 68.9525 I Ba+ 137.90$ <= 0.03
Optimization Results:
First pass
[FailedJ
End Time: 11:10:05, Tuesday, October 18, 2005
Report Date/Time: Tuesday, October 18, 2005 11'.10:05
Page 3
TargeUObtained mass (3.4 1 6 I 3.027 ), TargeUObtained resolution (0.7/0.696)
TargeUObtained mass (23.985/23.979), TargeUObtained resolution (0.7/0.6%)
TargeUObtained mass (102-9051102.929), TargeVObtained resolution (0.7/0.706)
TargeUObtained mass (139.905/139.928), TargeUObtained resolution (0.710.704\
TargeUObtained mass (207.5771207-978), TargeUObtained resolution (0-710.703)
TargeUObtained mass (238.051238.075), TargeUObtained resolution (0.71O.712)
Optimum value(s): N/A
a
Obtained lntensity (Bkgd 220):4
Obtained lntensity (ln 1 14.904\: 27 1042
Obtained lntensity (Mg 23.985): 38291
Obtained lntensity (Pb 2A7.977):90766 - <Target not achieved>
Obtained lntensity (Rh 102.905): 259691
Obtained Formula (CeO 155.9 I Ce 139.905): 0.030 q=51711 169812).
Obtained Forrnula (Ba++ 68.9525 I Ba+ 137.905): 0.010 1=1387 I 140339)
IFailed]
Page 111
METHOD 200.8 SUMMARY REPORT
Sample lD: Blank
Sample Date/Time: Tuesday, October 18,2005 11:23:05
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\1 0 1 805-1 .sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 01 805\1 01 805\8lank.001
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,Tb
Hf
Hf
Hf
Hf
159
176
177
178
179
180
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Ditf
Conca SD Conc. RSD Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Dup. Rel. % Ditf
LHf
-62.476
17.333
8.000
6.667
8.253
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement TypeAnalyte Mass
QC Action Line: No QC out of limits detected
QC Out Of Limits
Out of Limits Message
QC Action
Page 112
METHOD 200.8 SUMMARY REPORT
Sample lD: Standard 1
Sample Date/Time: Tuesday, October 18, 2005 11:26:29
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\l01805-1.sam
Method File: q\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 01 805\1 0 1 8O5\Standard 1 .002
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandatra\Optimize\default.dac
Concentration Results
--Asa@'.Netlntens.Mean.C91c.Mearr.Cpnc.SDConc.RSDSampleUnit> Tb 159 375794.959 375794.96 ug/L
Hf 176 9930.834 0.03 10.0000 0.2440 2.4401 ug/L
Hf 177 35153.203 0.09 10.0000 0.1044 1.0444 ug/L
Hf 178 52189.840 0.14 10.0000 0.1222 1.2216 ug/L
Hf 179 26062.755 0.07 10.0000 0-0945 0.9454 ug/L
Hf 180 67537.7U 0.18 10.0000 0.1257 1.2573 ug/L
QC Calculated Values
Ana$e Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. % Diff
> Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QC Out Of Limits
Measurement TypeAnalyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page 113
METHOD 200.8 SUMMARY REPORT
Sample lD: Standard 2
Sample Date/Time: Tuesday, October 18,2005 11:29:55
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C :\Elandata\Sample\1 0'1 805-1 .sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 01 805\1 01 8O5\Strandard 2.003
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,
Analyte MaS_S_
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
_[eas=_ l1rtg-ns_. Mean
375361 .223
18594.394
66925.422
99564.835
49817.048
129349.250
Net lntens. Mean
375361.22
0.05
0.18
a.27
0.13
0.34
Co.nc.-![e_an
19.7240
19.8057
19.8135
19.8216
19.8294
Conc. SD Conc.
0.2243
0.2358
0.3306
0.0962
4.2971
Ditution o/o Ditf
Sample Unit
ug/L
ug/L
uglL
ug/L
ug/L
ug/L
1.1373
1.1904
1.6688
0-4856
1.4982
QC Galculated Values
Analyte Mass QC Std % Recovery lnt Std 7o Recovery Spike % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Measurement TypeAnalyte Mass
QC Out Of Limits
Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Dup. Rel. % Dttf
[,
Page ll4
METHOD 200.8 SUMMARY REPORT
Sample lD: Standard 3
Sample Date/Time: Tuesday, October 18,2005 11:33:22
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101805-1.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DatraSet\101 805\1 01805\Standard 3.004
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Resutts
AnElr4e Mass Meas. lntens--lr4ean
[,Tb
Hf
Hf
Hf
Hf
Hf
159
176
177
178
179
180
378718.994
95424.465
338846.731
5A220'9.541
251487.671
650494_108
Net lntens. Mean
378718.99
0.25
0.89
1.33
0.66
1.72
Conc. Mean
100.0028
99.9717
99.9549
99.9610
99.9444
9pr9: pD
1.1605
0.9186
1.6523
1.6011
1.7241
Conc. RSD
1.1604
0.9189
1.6531
1 .6017
1.7251
, Sample Unit
ug/L
ug/L
uglL
ug/L
ug/L
ug/L
QC Galcutated Values
Analyte Mass QC Std 7o Recovery lnt Std % Recovery Spike o/o Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QC Out Of Limits
Measurement TypeAnalyte Mass Out of Limits Message
QG Action
QC Action Line: No QC out of limits detected
Dilution "/o Ditf Dup. Rel. % Dift
[,
d
I
L
Page 115
@
[> Tb 159 374780.180
1
October 18, 2005 1 1:36:49
Net lntens ,Mean Conc. Mean Conc. SD Conc. RSD Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
METHOD 200.8 SUMMARY REPORT
Sample ID: QC Std
Sample Date/Time: Tuesday,
Sample Type: Sample
Sample Description:
Nurnber of Replicates: 3
Sample File: C:\Elandata\Sample\1 01 805-1 .sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 01 805\1 01 805\QC Std 1.005
Tuning File: c:\elandata\Tuning\default.tun
Opti mizatio n F ile : c:\e la ndata\Optim ize\d efa ult. da c
L
-$ K-
Concentration Results
Hf
Hf
Hf
Hf
Hf
176
177
178
179
180
38359.029
135687.714
201083.357
100810.1 16
261381.127
374784.18
0.10
0.36
0.54
0.27
0.70
40,6597 43429
40.4500 0.2431
40-4415 4.2513
40.4895 0.1383
40-5806 0.2900
0.8434
0.6010
0.6214
0.3415
0.7147
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176 101.649
Hf 177 $1.125
Hf 178 101-104
Hf 179 1A1.224
Hf 180 141.451
Measurement TypeAnalyte Mass
QC Action Line: No QC out of limits detected
QC Calculated Values
lnt Std % Recovery Spike 7" Recovery Dilution o/o Diff Dup. Rel. o/o Ditl
98.261
QC Out Of Lirnits
Out of Limits Message
QC Action
Page I 16
METHOD 200.8 SUMMARY
Sample lD: QC Std 3
Sample Date/Time: Tuesday, October 18, 2005 1 1 :4A:17
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101 805-1 .sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 01 805\1 01 805\QC Std 3.006
Tuning File: c:\elandata\Tuning\default.tun
Opti m izatio n File: c:\ela ndata\Optim ize\defa u lt.dac
REPORT
tan
[, Tb
[,
Hf
Hf
Hf
Hf
Hf
Tb
Hf
Hf
Hf
Hf
Hf
1s9
176
177
178
179
180
159
176
177
178
179
180
378205.350
48s25.070
173358.557
2s6790.897
129296.175
333109.535
101.910
102.429
102.357
102.924
102.500
378205.35
0.13
0.46
0.68
0.34
0.88
50.9548
51.2143
51 .1 785
51.4618
51.2499
0.s278
0.4134
0.6153
0.5597
4.4442
99.1 59
QC Out Of Limits
Out of Limits MessageMeasurement Type Analyte Mass
QC Action
QC Action Line: No QC out of lirnits detected
0c (,
Goncentration Resurts rV
QG Calculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. o/o Diff
Conc,_RSD Sample Unit
ug/L
1.0358 ug/L
0.8073 ug/L
1.2422 uglL
1.0876 ug/L
0.8667 ug/L
Page ll7
METHOD 2AO.B SUMMARY REPORT
Sample ID: QC Std 4
Sample Date/Time: Tuesday, October 18,2AA5 11:46:44
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\1 0 1 805-1 .sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 01 805\1 01 805\QC Std 4.OAT
Tu n in g File : c:\elandata\Tu n in g\defa u lt.tu n
Opti mizatio n Fi le : c:\e la ndata\Opti mize\d efa u lt. dac
CC"b t
0.00 A .7 473 0.0836 1 1 .1831 ug/L
0.01 4.7237 0.0828 11.4345 ug/L
0.01 A.72AT 0.0686 9.5201 ug/L
0.00 0.7304 0.0644 8.8230 ug/L
0.01 4.7263 0.0838 11.5380 ug/L
Concentration Results
Analyte Mass Meas. lntens. Mean Net lntens. Mean Conc. fiean .Conc. SD Conc. RSD. Sample Unil
[, Tb 159 378929.264 378929.26 ug/L
Hf 176 651.596
Hf 177 247A.549
Hf 178 3629.797
Hf 179 1844.453
L Hf 180 4735.996
QG Galculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. % Diff
[> Tb 1s9 99.349
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QC Out Of Limits
Measurement TypeAnalyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page I 18
M
Sample lD: 3020A X
Sample Date/Time: Tuesday, (
Sample Type: Sample
ETHOD 200.8 SUMMARY REPORT
1; Ib.-F- M\olwlo
October 18, 2005 1 1 :50:08
Sample Description: BATCH 1666 DIG 9122 KW
Number of Replicates: 3
Sample File: C:\Elandata\Sample\1 01 805-1 .sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\101 805\1 01 805\3020A X 10.008
Tuning File: c:\elandata\Tuning\default.tun
O pti m ization Fi le : c :\ela ndata\Optim ize\d efa u lt. da c
Concentration Results
Analyte
[, Tb
Hf
Hf
Hf
Hf
Hf
375808.967
167.669
821.024
1 186.716
626.347
1620.642
375808.97
0.00
0.00
0.00
0.00
0.00
Conc, Mean
2.4196
2.3905
2.3646
2.4827
2.4969
a.2917
0.1671
41276
4.1124
4.1627
12.0571
6.990s
5.3967
4.s258
6.5166
159
176
177
178
179
180
Mass Mgas_._l{gns- Meg!___ ltg! lntens. Mean . Conc. SD Conc. RSD Sampte Unit. ..::, ,
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L lO.Ol
Dilution Yo Diff Dup. Rel- % Datt
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QC Calculated Values
lnt Std 7o Recovery Spike % Recovery
98.531
QC Out Of Limits
Measurement Type Analyte Mass Out of Limits Message
QC Action
QC Action Line. No QC out of limits detected
METHOD 200.8 SUMMARY REPORT
Sample lD: 3020A STD X 10 2.5 OF 10
Sample Date/Time: Tuesday, October 18,2005 11:53:.02
Sample Type: Sample
Sample Description: BATCH 1666 DIG 9122KW
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101805-1.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\101805\101805\3020A STD X 10 2.5 OF 10-009
Tuning File: c:\elandata\Tuning\default.tun
O pti mization Fi I e: c :\e la ndata\Opti mize\d efa u lt. d a c
Concentration Results
Page I 19
Sample Unit
uglL
ug/L
ug/L
ug/L
Hi WloCTrr as)
. - -:. Anat$e Mass Meas. lntens. Mean
[, Tb
Net lntens, M_e-?l
385729.24
0.08
0.28
0.41
0.21
0.53
Conc. Mean .SD
Hf
Hf
Hf
Hf
LHf
159
176
177
178
179
180
38s729.243
29896.306
106768.834
157607.978
79717.134
204972.883
3.4919
0.8s89
1.3085
1.1452
1.5008
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QC Calcula d Vatues
lnt Std % Recovery Spik
101j32
QC Out Of Limits
Out of Limits MessageMeasurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
s(P 5oo
Conc. RSD
1 .1 335
o.2777
a.4249
0.3681
0.4854
Recovery Dilution % Ditf Dup. Rel. % Ditt
308.0659
309.2483
307.978
311.0849
Page 120
[,
METHOD 200.8 SUMMARY REPORT
Sample lD: 090f 02-1 X20
Sample Dateffime: Tuesday, October 1 8, 2005 1 1 :57 :27
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101805-1.sam
Method File: c:\ela ndata\Method\200.8\hafniumall.mth
DatasetFile:C:\Elandata\DataSet\101805\101805\090102-1 X20.010 \ t n ,)
:'J*i:H"".fj::f':"rry*=*::
;:;",n" ""^.,f:W:;,[t,
elrlot
. Anaryre Mass Meas. rnte8s. Mean Neilntens:;:cne"txt::: ;;"'n conc. SD conc. RS
Tb 159 310251.458 310251.46 ug/L
Hf 176 1569.517 0.01 41,4308 0.7985 1.9272 ug/L
Hf 177 5828.856 0.02 41.8837 0.7540 1.8003 ug/L
Hf 178 8529.213 0.03 41-4110 0.9440 2.2795 ug/L
Hf 179 4344.994 0.01 42.1100 1.0873 25820 ug/L
Hf 180 11200.974 0.04 41.9885 0.7907 1.8830 ug/L
QC Calculated Values
Analle Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. % Diff
Tb 159 81.343
Hf 176
Hf 't77
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
QC Out Of Limits
Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
[,
Page l2l
METHOD 200.8 SUMMARY REPORT
Sample lD: 0901 O2-1 X 20
Sample Date/Time: Tuesday, October 18,2005 12:OO:51
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\10180S1.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 0 1 805\1 01 805\090 1 02- 1 X 20.O 1 1
Tuning File: c:\elandata\Tuning\defa ult.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
.;L
- - . -,,=$nalvtq,$agp-,,,=[l!=e€q,-_lltle=nq-Mean[, Tb 1 59 310887.795
847.729
3134.355
4708.461
2349. r 98
6131 .711
Hf 176
Hf '177
Hf 178
Hf 179
Hf 180
Net lntelr_g. !{ea!_
310887.79
0.00
0.01
o.o2
0.01
0.02
22.9154
22.4147
22.7865
22.6837
22_9161
Conc. SD
4.36s1
4.8263
4.2616
4.4386
4.1 351
Conc. RSD
19.0486
21.5317
18.7022
19.5674
18.0446
Sample Unit
ug/L
ug/L
ug/L
uglL
l3ii 0.o*
QC Galculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery
Tb 159 81.509
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
QC Out Of Limits
Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Dilution o/o Ditf Dup. Rel. % Ditt
[,
Page 122
METHOD 200.8 SUMMARY REPORT
O Sample ID: 0901 A2-1 XzA
--.,.--,' ===AE ) €,lila,ss-Megs. lnten-s. MeA-n
[, Tb 159 309677 .522
Sample DatelTime: Tuesday, October 18, 2005 12:A432
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\t 01 805-1 .sam
Method F i le : c:\ela ndata\Method\200. B\hafn iu ma I I.mth
Dataset File: C:\Elandata\DataSet\1 0 1 805\1 0 1 805\090 1 O2-1 X 20 .01 2
Tuning File: c:\elandata\Tuning\default.tun
Optim izatio n File: c:\ela ndata\Optimize\defa u lt. dac
Hf
Hf
Hf
Hf
Hf
176
177
178
179
180
782-465
30s2.685
4458.081
2279.195
5794.486
Concentration Results
Net lntens-.1\4_eAn__ _ Co!g,_ Mean
309677.52
0.00 21.3357
0.01 21.9206
0.01 21.663s
0.01 22.0986
0.o2 21.7432
Conc. SD
7.2426
7.5484
7.26/.5
7.3731
7.0481
Conc. RSD
33.9461
34.2527
33.5334
33.3648
32,4151
ug/L
ug/L
ug/L
uglL
ug/L
us/L O, OA
[,
d
I
L
Anatyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
QC Action Line: No QC out of limits detected
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Datf Dup. Rel. Yo Ditt
81.192
QC Out Of Limits
Out of Limits Message
QC Action
Page 123
METHOD 200.8 SUMMARY REPORT
Sample lD: 0901 O2-2 X 10
Sample Date/Time: Tuesday, October 18,2AA5 12:A7:27
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\1 01 805-1 .sam
Method File: c:\elandata\Method\200.8\hafniumall -rnth
Dataset File: C:\Elandata\DataSet\1 0 1 805\1 0 1 805\090 1 O2-2 X 1 0.01 3
Tuning File: c:\elandata\Tuning\default.tun
O p ti m i zation Fi I e : c:\e I a n da ta\O pti m ize\d efa u lt. d a c
Concentration Results
id*1,0
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Meas. lntens. Mean
182312.296
706.885
2667.253
3927.214
1952.469
5045.124
Net lntens. Mean
182312.30
0.00
0.01
0.02
0.01
0.03
Conc. Mean
16.0328
16.3022
16-2?53
16.0994
16.0931
Conc. SD
2.s170
2.4167
Conc. RSD
1B.s00B
1 5.1 675
15.1 448
15.6340
15.0170
Sarnple Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anatyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Measurement Type Analyte Mass
Tb 159 lnt Std for s;Tb 159
QC Action Line: Continue
Ditution % Ditf Dup. Rel. % Ditt
[,
QC Out f Limits
Out of Limits Messag
lnternal Std Out of Li
METHOD 200.8 SUMMARY REPORT
Sample lD: 3020A STD X 10 2.5 OF 10
Sample Date/Time: Tuesday, October 18,2005 12:10:48
Sample Type: Sample
Sample Description: BATCH 1666 DIG 9122KW
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101805-1.sam
Method File: c:\elandata\Method\200.8\hafniumall. mth
Dataset File: C:\Elandata\DataSet\101805\101805\30204 STD X 10 2.5 OF 10.014
Tuning File: c\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
ug/L
ug/L
ug/L
ug/L
ug/L
ugllxl= a9o
Page 124
G.=n8/o
€Kps& \
(1*f.}S2
m u\L,rAoA\r)Lr
Conc. RSD Sample Unit
[,
A1alyte nngt
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. lntens. Mean
383475 .454
18780-683
66327.643
98789.777
49589,940
fl8744.830
Concentration Results
Net lntens- Mean Conc- Mean
383475.45
0.05 194.8976
a.17 193.2155
0.26 194.1642
0.13 194.6367
0.34 195.2824
Conc. SD
1.4163
1.9232
1-6788
2.7810
o.8227
4.7267
0.9954
0.8M6
1.4288
o.4213
[,
d
I
L
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Measurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % D,tf Dup. Rel. % Datf
100.541
QC Out Of Limits
Out of Limits Message
Page 125
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-2X20
Sample Date/Time: Tuesday, October 18, 2005 12:-17:13
Sample Type: Sample )
Sample Description: BATCH 1666 URS / ft tNumberofReplicates:3 / ry . , \q5SampleFile:C:\Elandata\Sample\101805-1.sam / \ *-' ,if \r0T
Method File: c:\elandata\Method\200.8\hafniumall.mth / \. \ ' -?'N" ,0 \, - '
DatasetFile:C:\Elandata\DataSet\101805\101805\090102-2X20.O15 i n\ {" .\\
Tuning File: c:\elandata\Tuning\default.tun / U' & ' eY
Optimization File: c:\elandata\Optimize\default.dac I \J
II
Concentration Results II
Analvte [4ass Meas. lnlejs. Mean Net lntens. Mean Conc. Mean C{nc. SD Conc. RSD Sample Unitffira.oso '-ilsF[ii6-=:=-==- I ug/1'= ""
I Hf 176 s47.67O 0.00 34.6093 f e.SOOe 9.7281 ug/L
I Hf 177 Ug5-764 0.02 34.5164 / S.SSOZ 9-8233 ug/L
I Hf 178 5281-647 O.O2 3s.252s I Z.AZSA 7.45s2 us/L
I Hf 179 2623-576 0.01 34.9480 | 3.2307 9.^4'14 ug/L
L Hf 180 6809.749 0.03 35.0921 l/ 3.O1SO 8.5933 ug/L
,I.(lG€alcutated Vatuds
"""t'' \ i
Analyte Mass QC Std % Recovery lnt Std ?oF€-covery Sp\e % Recover/ Dilution % Diff Dup. Rel. % Diff
[, Tb 159 .,;." 59.153 | !lHf 176 / : i
Hf 177
Hf 178 j'
Hf 179 ,'iHf 180 j :
QC Out Of Lirnits
Measurement Type Analyte Mass Out of Limits Message
Tb 159 Int Std for s:Tb 159 lnternal Std Out of Limits
'... j
QC Action
QC Action Line: Continue
t,
!t:IIt',
i
Page 126
METHOD 200.8 SUMMARY REPORT
Sample lD:090102-2X50
Sample Date/Time: Tuesday, October 18,2005 12:24:O1
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101805-1.sam
Method File: c:\elandata\Method\2OO.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 0 1 805\1 0 1 805\090 1 02-2 X 50.0 1 6
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
- __Jt4eas- lntens. Mean
[, Tb
Concentration Results
Net lntens. Me€n _9!ng. Mean Conc. SD Conc. RSD
28583 1 .1 9
.lo
fetffui{g,
Sarnple Unit
ug/L
ug/L
ug/L
ug/L
uglL
ug/L o.o3
Hf
Hf
Hf
Hf
LHf
[,
159
176
177
178
179
180
285831 .1 94
382.695
1541.088
2255.522
1131.381
2988.381
0.00
0.01
0.01
0.00
0.01
29.7822
29.8463
29.6392
29.6380
30.3318
8.5246
9.0526
8.8967
9.3947
9.0146
28.6232
30.3306
30.0167
31.6980
29.7200
QC Calculated Values
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement TypeAnalyte Mass
QC Action Line: No QC out of limits detected
Ditution % Dift Dup. Rel. % Ditf
QC Out Of Limits
Out of Limits Message
QC Action
METHOD 2OO.B SUMMARY REPORT
Sample lD: 090102-2 X 50
Sample Date/Time: Tuesday, October 18,2005 12;26:56
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101805-1.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 01805\1 01805\090102-2 X 50 -017
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
=.:__:_3qglyEJagg,. .Meas. lntens. Mean Net lntens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit
ir-ru - -rss -
-28232s.ss1
-'-- --*-/6r{r'6.55- -- usll
Page 127
0.00 23.9823 8.5248 35.5461 ug/L
0.00 25.2149 8.1302 32.2437 ug/L
0.01 25.3253 7.9114 31.2392 ug/L
331 ll33l3 iiili" 311333 i{,i o,oz d-pltca*s
tt is,
Hf 176 295.190
Hf 177 1287.062
Hf 178 1903.135
Hf 179 940.366
L Hf 180 2528.937
QC Calcutated Values
Anage Mass QC Std 7o Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. % Diff
[> Tb 159 74.022
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QC Out Of Limits
Measurement Type Analyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page 128
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-Z X 50
Sample Dateffime: Tuesday, October 18,2005 12:29:52
Sample Type: Sample
Sample Description: BATCH 1666 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101805-1.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 0 1 805\1 01 805\090 1 02-2 X 50.0 1 8
Tuning File: c:\elandata\Tu ning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
--- Analyte Mass Me_ag.. conc- sP_ - --_
9.2031
8.8528
7.8622
B-4165
8.0253
[, Tb
Hf
Hf
Hf
Hf
LHf
159
176
177
178
179
180
l_q!e_ns._!!gan __Net lntens,_Mean
278392.429 278392.43
37B.B4s 0.00
1570.091 0.01
2286.524 0.01
1108.379 0.00
2989.185 0.01
Co1c, tttg-?I
34.2174
31.2377
30.8589
29.8182
31.1598
9ol..RSD
30.4566
28.3402
25.4780
28.2259
25.7s53
Sample Unit
ug/L
uglL
ug/L
ug/L
ug/L
ug/L O, Oz 6bu
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Measurernent TypeAnalyte Mass
QC Action Line: No QC out of limits detected
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Dift Dup. Rel. % Ditt
72.990
QC Out Of Limits
Out of Limits Message
QC Action
Page 129
METHOD 200.8 SUMMARY REPORT
Sample ID: QG Std 3
Sample Date/Time: Tuesday, October 18, 2005 12:32:49
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Etandata\Sample\1 01 805-1 .sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1A1805\1 0 1 805\QC Std 3.01 I
Tuning File: c:\elandata\Tuning\default.tun
Optimization Fite: c:\elandata\Optimize\default.dac
Goncentration Results
0t\/ L
dd
Analyte Mass
f;Tb- _'
--1seHf 176
Hf 177
Hf 178
Hf 179
LHf 180
Meas. Intens. Mean
3s3984.693
43679.407
154665.558
229904.070
115612.311
299121.669
Net lntens. Mean
3s3984.69
4.12
0.44
0.65
0.33
0.8s
Conc. Mean
49.0038
48.8159
48.9521
49.1627
4e.16e5 qr6 L
Conc. RSD
0.8947
0.6280
0.5411
0.1 541
0.2310
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Conc. SD
0.4385
0.3066
0.2649
0.0758
0.1 1 36
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf lBO
Measurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
QC Calculated Values
lnt Std % Recovery Spike % Reccvery Dilution "/o Diff Dup. Rel. % Ditf
92.809
QC Out Of Limits
Out of Limits Message
Page 130
METHOD 200.8 SUMMARY REPORT
Sample lD: QC Std 4
Sample Date/Time: Tuesday, October 18,2OOS 12:39:16
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101805-1 .sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 01 805\1 01805\QC Std 4.020
Tuning File: c:\elandata\Tuning\default.tun
Opti mization F i le : c:\e la nd ata\Opti mize\defa ult. da c
e)
CLbL
Concentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas. lntens. Mean
350730.203
553.1 59
2297.186
3349-727
1631 .427
4315.015
Net lntens. Mean
350730.20
0.00
0.01
0.01
0.00
0.01
Conc. Mean
0.6905
0.7267
0.7183
0.6976
4.7146
QC Calculated Values
lnt Std % Recovery Spike % Recovery
91.955
Conc. SD Conc. RSD Sample Unit
uglL
A.A244 3.5338 ug/L
0.0589 8.0982 ug/L
0.0416 5.7852 ug/L
0.0258 3.6977 ug/L
4.4423 5.9181 ug/L
Dilution % Ditt Dup. Rel. % Drtt
[,
I
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
o
Measurement TypeAnalyte Mass
QC Action Line: No QC out of limits detected
QC Out Of Limits
Out of Limits Message
QC Action
Page 131
METHOD 200.8 SUMMARY REPORT
Sample lD: 3020A BLK X20
Sample Dateffime: Tuesday, October 18,2005 12:42:41
Sample Type: Sample
Sample Description: BATCH 1698 DIG 9/29 KW 1410
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101805-1.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 0 1 805\1 0 1 805\3020A BLK X 20.021
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas- lntens. Mean
356864.499
183.163
B 16-357
1238.721
624.4M
1626.430
Net tntens_. fiIean
356864.50
0.00
0.00
0.00
0.00
0.00
Conc. Meal
5.3717
5.0135
5.2041
5.2137
5.2806
Conc. RSD
4.0730
11.1275
11.0979
7.2111
7.3807
Sample Unit- ug/L:
"'-----"
uglL
ug/L
ug/L
Conc. SD
0.2188
0.5579
4.5775
0.3760
0.3897
ug/L;r <o.ol
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QC Calculated Values
lnt Std % Recovery Spike % Recovery
93.564
Dilution % Ditt Dup. Rel. o/o Ditt
QC Out Of Limits
Out of Limits MessageMeasurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
Page 132
METHOD 200.8 SUMMARY REPORT
Sample lD: 3020A STD X20 2.5 OF 10
Sample Date/Time: Tuesday, October 18, 2005 12:45:37
Sample Type: Sample
Sample Description: BATCH 1698 DIG 9129 KW 14f0
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101 805-1.sam
Method File: cielandata\Method\2O0.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\101805\101805\3020A STD X 20 2.5 OF 10.022
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
e.{P5rr)05-las?)
Concentration Results
Ana_Me M_as_s Meas. lntens- Mean _ Net lntens. Mean Conc. Me_an Conc. SD Conc. RSD Sample Unit
> Tb 159 352137.638 352137.64 ug/L
Flf 176 23609.393 0.07 533.1683 4.6656 0.8751 uS/L
Hf 177 83830.246 0.24 531.9366 3.8436 0.7226 ug/L
Hf 178 124924.507 0.35 534.8060 4.4779 0-8373 uslL
Hf 179 62943.701 0.18 538.1247 5.8307 1.0835 ug/L _o1
Hf 180 162668.917 0.46 537.s882 6.638e 1.2us ustt lQ$ to J
QC Calculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution 7o Diff Dup. Rel. % Diff
r> Tb 159 92.324
I Hf 176oxI :1i
I Hf 179
L Hf 180
QC Out Of Limits
Measurement Type Analyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page 133
METHOD 200.8 SUMMARY REPORT
Sarnple ID: 090 1A2-21 X 2A
Sample Date/Tirne: Tuesday, October 18, 200512:52:A3
Sample Type: Sample
Sample Description: BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\1 01 805-1 .sam
Method File: c:\elandata\Method\200.8\hafniurnall.mth
Dataset File : C :\E la ndata\Data Set\1 0 1 805\1 0 1 805\090 1 A2-21 X 2A .A23
Tuning File: c:\elandata\Tuning\default.tun
Opti m ization File : c :\ela n data\O pti mize\defa u lt.da c
bfr,'fir\.
W ,D
Concentration Results
_U ns. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit
[,
Analyte Mqss_
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
324472.987
554.306
2314.188
u20.414
1769.443
4520.581
324472.99
0.00
0.01
0.01
0.01
0.01
0.6312
0.628l,
0.8937
0.8065
0.8766
4.2495
3.9671
5.6339
4.9269
5.4150
ug/L
ug/L
ug/L
ug/L
uglL
ug/L
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of timits detected
culated Values
lnt Std 7o Recove Spike % Recovery Dilution % Ditf Dup. Rel. % Ditt
QC Out Of Limits
1698 URS
Page 134
METHOD 200.8 SUMMARY REPORT
Sample lD: 0901 02-22 X 20
Sample Date/Time: Tuesday, October 18, 2005 12:55:00
Sample Type: Sample
Sample Description: BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101805-1.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 01 805\1 01805\090102-22 X 20.024
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Net Intens. Mean Conc. Mean Conc. SDMass Meas. lntens. Mean
[,
I
Analyte
Tb
Hf
Hf
Hf
Hf
Hf
159
176
177
178
179
180
328200.61
0.00
0.00
0.01
0.00
0.01
8.6s39
8.8807
8.9886
9.1069
9.2304
1 .2195
1.5066
1.4571
1.3l,67
1.2859
14.0919
16.9650
16.2103
14.7878
13.9314
32820A.607
304.1 88
1319.062
1963.471
998.369
2609.701
Conc- RSD Sample Unit
ug/L :
ug/L
ug/L
ug/L
ug/L
us/L lOrO I
[,
Ie
I
L
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
QC Action
QC Action Line: No QC out of timits detected
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Ditt Dup. Rel. % Ditf
86.049
QC Out Of Limits
Out of Limits Message
Page 135
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Meas. lntens. Mean
328229.912
146.149
71 1 .018
1095.043
544.411
1386.003
Net lntens. Mean
328229.91
0.00
0.00
0.00
0.00
0.00
METHOD 200.8 SUMMARY REPORT
Sample lD: 0901 02-23 X 20
Sample Date/Time: Tuesday, October 18, 2005 12:57:58
Sample Type: Sample
Sample Description: BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101805-1.sam
Method File: c:\elandata\Methodl200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 0 1 805\1 0 1 805\0901 02-23 X 20.025
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Cong ,Mean
4.8324
4.7397
4.9980
4.9376
4-8892
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QC Galculated Values
Int Std % Recovery Spike % Recovery
86.056
Dilution o/" D'ttf Dup. Rel. olo Ditf
Measurement Type Analyte Mass
OC Out Of Limits
Out of Limits Message
QC Action
QC Action Line. No QC out of limits detected
Conc. SD
0.8674
0.7481
0-7506
0.8328
0.9466
Conl RSD
17.9515
15.7829
15.0180
16.8654
19.3603
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L lO,Ol
[,
Page 136
METHOD 200.8 SUMMARY REPORT
Sample lD: QC Std 3
Sample Date/Time: Tuesday, October 18, 2005 13:00:56
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\l 01 805-1 .sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 01805\1 01 805\QC Std 3,026
Tuning File: c:\elandata\Tuning\default.tun
O pti miza tio n F i le : c :\ela ndata\Opti mize\defa ult.da c
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Meas- lntens- Mean
350992.255
43732.435
156065.580
231612.906
116932.650
3013M.388
Net lntens. Mean
350992.25
a.12
4.44
0.66
0.33
0.86
Concentration Results
Conc. Mean
49.4859
49.6810
49.7400
50.1495
49.9639
Conc. SD
0.5652
0.6718
0.6053
0.6187
0.7730
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QC Out Of Limits
Measurement Type Analyte Mass Out of Lirnits Message
QC Action
QC Action Line: No QC out of limits detected
c cv,)
Conc. RSD-:' :::j _-:::.1::---:.-..- I
1.1421
1.3523
1.2170
1.2337
1.5471
QC Calculated Values
lnt Std o/o Recovery Spike % Recovery Dilution % Ditt Dup. Rel. o/o Dtft
92.024
METHOD 200.8 SUMMARY
Sample ID: QC Std 4
Sample Date/Time: Tuesday, October 18, 2005 13:07:23
Sampte Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\1 01 805-1 .sam
Method File: c:\ela ndata\Method\2}0. B\h afn i u ma I l. mth
Dataset File: C:\Elandata\DataSet\1 01 805\1 01 805\QC Std 4.027
Tuning File: c:\elandata\Tuning\default.tun
Opti mization File : c:\ela ndata\Opti mize\defa ult.dac
Concentration Results
REPORT
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf lBO
Meas. lntens- Mean
343561.870
s75.526
2U3.527
3434.415
1751147
4544.431
Net lntens. Mean
343561_87
0.00
0.01
0.01
0.01
0.01
4.7293
0.7571
4.7s20
0.7&7
0.7685
0. 1 037
4.4723
0.0700
0.0388
0.0662
f,
Analyte Mass QC Std o/o Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QC Out Of Limits
Out of Limits MessageMeasurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
c crSe
Conc. Mean Conc. SD
Dilution o/o Dift Dup. Rel. % Ditt
Conc. RSD Sample Unit
ug/L
14.2163 ugll
9.5523 ug/L
9.3071 ug/L
5.0685 ugll
8.6152 ug/L
p
QC Calculated Values
lnt Std % Recovery Spike % Recovery
90.076
Page 138
METHOD 200.8 SUMMARY REPORT
Sample lD: 0901 02-24 X 20
Sample Date/Time: Tuesday, October 18, 2005 13:10:49
Sample Type: Sample
Sample Description: BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101805-1.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 01 805\1 01 805\090102-24 X 20.028
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[, Tb
Hf
Hf
Hf
Hf
Hf
159
176
177
178
179
180
339385.78s
267.306
114A379
1709.102
864.026
2176.779
Net lntens- Mean
339385.79
0.00
0.00
0.01
0.00
0.01
Conc. Mean
7.5477
7 -4470
7.5598
7.61 16
7.4389
Conc. SD
0.1859
0.2930
4.2611
0.2638
0.3687
Conc. RSD
2.4634
3.9559
3.4538
3.4653
4.9557
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
us/L lo, o I
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
QC Action Line: No QC out of limits detected
QG Calculated Values
lnt Std % Recovery Spike % Recovery Dilution o/o Ditf Dup. Rel. % Datf
88.981
QC Out Of Limits
Out of Limits Message
QC Action
METHOD 200.8 SUMMARY REPORT
Sample lD: 0901 A2-25 X 20
Sample Date/Time: Tuesday, October 18,2005 13:13:48
Sample Type: Sample
Sample Description: BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101805-1.sam
Method File: c:\elandata\Method\2O0.8\hafniumall.mth
Dataset File : C:\Ela ndata\DataSeil1 0 1 805\1 0 1 805\090 1 02-25 X 20.O29
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Page I39
O
Ana!yt_e_
Tb
Hf
Hf
Hf
Hf
Hf
MAgg__ lggl lntens. Mean
1se 93303 i.sit
219.083
901.362
1283.391
661.015
1709.973
Net lntens. Mean
3330 34.g2
0.00
0.00
0.00
0.00
0.01
Conc. Mean _Conc.
6.52A2
5.9456
5.7777
5.9228
5.9496
16.9933 ug/L
10.7695 ug/L
9.1265 ug/L
1 1 .1301 ug/L
10.52sG ugtL/lo,O t
SD Conc. RSD Sample Unit
[,
I 176
177
178
179
180
1 .1 080
0.6403
o.5273
0.6592
a.6262
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Measurement TypeAnalyte Mass
QC Action Line: No QC out of limits detected
QC Galculated Values
lnt Std % Recovery Spike % Recovery Dilution o/o Diff Dup. Rel. o/" Dift
87.316
QC Out Of Limits
Out of Limits Message
QC Action
Page UA
METHOD 200.8 SUMMARY REPORT
Sample lD: 0901 A2-26 X 2A
Sample Date/Time: Tuesday, October 18, 2005 13:16:48
Sample Type: Sample
Sample Description: BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101805-1.sam
Method File: c:\elandata\Method\2OO.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\101805\101805\090102-26 X 20.030
Tuning File: q\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Conc- Mean Conc- SD Conc. RSD Sample Unit
[,Tb
Hf
Hf
Hf
Hf
r59
176
177
178
179
180LHf
341377.448
174.716
780.O22
11&-.715
598.346
1502.581
341377.45
0.00
0.00
0.00
0.00
0.00
11.8912
14.1725
15.7168
11.1312
14.3725
Dup. Rel. % Dfit
ug/L
ug/L
ug/L
ug/L
uglL
ug/-<O,o1
5.2661
5.0055
5.1126
5-2255
5.0984
4.6262
0.7094
0.8035
0.5817
0.7328
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QC Calculated Values
Int Std % Recovery Spike 7o Recovery Dilution % Ditt
89.503
Measurement Type Analyte Mass
QC Action Line: No QC out of limits detected
QC Out Of Limits
Out of Lirnits Message
QC Action
Page l4l
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-27 X20
Sample Dateffime: Tuesday, October 18,2005 13:19:47
Sample Type: Sample
Sample Description: BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\Elandatia\Sample\101 805-1.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\101 805\101805\0901 02-27 X 2A.031
Tuning File: c\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[, Tb
Hf
Hf
Hf
Hf
Hf
159
176
177
178
179
180
344860.570
121.265
600.013
840.358
448.341
1107.030
344860.57
0.00
0.00
0.00
0.00
0.00
Conc. lvlean
4.A942
3-7876
3.6425
3-8621
3.71 13
Con9. SO
0.7a73
0.7069
0.5817
4.7451
0.6923
Conc. RSD
17.2921
r8.6623
15.9701
19.2921
18.6548
Sample Unit
ug/L
ug/L
uglL
ug/L
uo/L
;;;' <o,ol
Anatyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QG Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Datt
94.417
Dup. Rel. % Ditt
[,
QC Out Of Limits
Out of Limits MessageMeasurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
Page 142
METHOD 200.8 SUMMARY REPORT
Sample lD: 0901 02-28 X 2A
Sample Date/Time: Tuesday, October 18, 2005 13:22:47
Sample Type: Sample
Sample Description: BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\1 01805-1.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C :\Elandata\DataSetl 0 1 805\1 0 1 805\0901 02-2 I X 20.032
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[, Tb
Hf
Hf
Hf
Hf
Hf
159
176
177
178
179
180
342146.781
92.108
469.008
703.684
364.671
942.638
342146.78
0.00
0.00
0.00
0.00
0.00
.99nc- Mean
3.4350
2.9619
3.0687
3.1563
3.1809
Conc. SD
0.3523
0.2597
0.3584
0.3043
0.3668
Q_o1c._RSD _
14.2572
8.7690
11.6789
9.6404
11.5308
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
uir- <O,Ol
QC Calculated Values
Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution % Ditf Dup. Rel. % Ditt
[,
Anatyte
Tb
Hf
Hf
Hf
Hf
Hf
Measurement Type Analyte Mass
QC Action Line: No QC out of limits detected
89.705
QC Out Of Limits
Out of Limits Message
QC Action
159
176
177
178
179
1BO
METHOD 200.8 SUMMARY
Sample lD: QC Std 3
Sample Date/Time: Tuesday, October 18, 2005 13:25:46
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\1 01 805-1 -sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 01805\1 01 805\QC Std 3.033
Tuning File: c:\elandata\Tuning\default.tun
O pti mization Fi I e : c:\e la nd ata\Optimize\defa u lt. dac
Concentration Results
REPORT
[,159
176
177
178
179
180tHf
[,
Tb
Hf
Hf
Hf
Hf
347686.1 61
43A04.431
154441.082
229273.278
1 151 11.276
29919A.425
347686.1 6
ai2
o.44
0.66
0.33
0.86
Qg1c._M_ean
49.1 238
49.6295
49.7042
49.8363
50.0705
_Co1c. S_D
0.4845
4.5220
0.4160
4.4126
0.2954
Co!.c, RSD Sample gryl_
,
ug/L
0.9862 ug/L
1 .0519 ug/L
0.8369 ug/L
0.8280 ug/L
0.5899 ug/L
Dup. Rel. o/o DiftAnalyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Measurement Type Analyte Mass
QC Action Line: No QC out of limits detected
QC Out Of Limits
Out of Limits Message
QC Action
C C/4
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Dift
91 .157
Page 144
METHOD 200.8 SUMMARY REPORT
Sample ID: QG Std 4
Sample Date/Time: Tuesday, October 18, 2005 13:32:14
Sampte Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\1 01805-1 .sam
Method File : c :\ela ndata\M ethod\200.8\frafn i u ma ll. mth
Dataset File: C:\Elandata\DataSet\1 01 805\1 01 805\QC Std 4.A34
Tuning File: c:\elandata\Tuning\default,tun
O ptimization File : c :\ela nda ta\Optimize\defau lt.dac
Goncentration Results
Analyte Mass Meas. lnlens. Mean Net lntens. Mean Conc. Mean Conc. SD Conc. RSD Sample Unit
ffi' ' 343s37-213' 34:xis721'='-' ug/t--".,
Hf 176 618.370
Hf 177 2328.857
Hf 178 3524.770
cc #'t
0.00 0.7798 0.1164 14.9242 ugll
O.01 0.7529 0.0678 8.9984 ug/L
0.01 0.7723 0.0724 9.3692 ug/L
Hf 179 1751.108 0.01 0.7652 0.0621 8.1146 ug/L
Hf 180 4496.744 0.01 0.7607 0.0474 6.2298 ug/L
QC Calculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. % Diff
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
90.070
QC Out Of Limits
Measurement Type Analyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
145
METHOD 200.8 SUMMARY REPORT
Sample lD: 0901 02-29 X 20
Sample Date/Time: Tuesday, October 18, 2005 13:35:41
Sample Type: Sample
Sample Description: BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\1 01805-1.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 0 1 805\1 0 1 805\0901 02-29 X 20.035
Tuning File: c\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,
Analyte Mass
Tb t59
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Meas- lntens. Mean
- ' ':'-: ="'345159.390
291.209
1231.053
1781.778
876.027
2334.427
Net Intens. Mean
. . : 345159.38
0-00
0.00
0.01
0.00
0-01
Conc. Mean
7.9899
7.8687
7.7496
7.s882
7.8296
Conc. RSD
9.0199
3.9249
6.7446
8.0909
7.6811
Sample Unit
ugl[" "". ''
uglL
ug/L
uglL
ug/L
us/L 1o, o I
Conc. SD
0.7247
0.3088
0.5227
0.6140
0.6014
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected.
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Ditt Dup. Rel. '/" Dift
90.49s
QC Out Of Lirnits
Out of Limits Message
Page 146
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-30 X20
Sample Date/Time: Tuesday, October 18, 2005 13:38:39
Sample Type: Sample
Sample Description: BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101805-1.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandatia\DataSet\101805\1 01805\0901 02-30 X 20.036
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Anatyte
[, Tb
lHf
Hf
Hf
Hf
Hf
343518.803
200.893
852.359
1264.056
660.015
1652.679
343518.80
0.00
0.00
0.00
0.00
0.00
Conc. Mean
5.9389
5.4433
5.5160
5.7322
5.5738
Conc. SD
0.6894
0.6504
a.s342
0.7388
0.7860
Conc. RSD
1 1.6089
1 1.9483
9.6850
12.8890
14.1023
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L .t
us/L <o, o I
-Mas-s
159
176
177
178
179
180
_MeaS_._U!eLs-. [4qe!_ Net lntsns. Mean
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QC Out Of Limits
Measurement Type Analyte Mass Out of Limits Message
QC Action
QC Action Une: No QC out of limits detected
QC Calculated Values
lnt Std o/" Recovery Spike % Recovery Dilution % Ditf Dup. Rel. % Dift
90.06s
Page 147
METHOD 200.8 SUMMARY REPORT
Sample lD: 0901 0244 MS-30 X 20 2.5 OF 10
Sample Date/Time: Tuesday, October 18, 2005 13:41:33
Sample Type: Sample
Sample Description: BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101805-1.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 01 805\1 01 805\0901 0244 MS-30 X 20 2.5 OF
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
10.037
Concentration Results
_. Analyte
[, Tb
Hf
Hf
Hf
Hf
LHf
Mass Meas. lntens- Mean
159 346231-524
176 21070.565
177 75478.216
178 112421.962
179 56334.189
180 146192.869
Net lntens. Mean
346231.52
0.06
4.22
0.32
0.16
0.42
484.4758
487.0797
489.4783
489.8231
491.3536
5.1386
2.2361
2.4527
2.7757
2.7677
Dilution a/o Diff
t-[r,
Conc. RSD
1 -0615
0.4591
0.501 1
0.5667
0.5633
Conc. Mean Conc- SD
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QG Calculated Values
lnt Std % Recovery Spike % Recovery
90,776
QC Out Of Limits
Out of Limits MessageMeasurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
sksffi(ry*Dfl)
Sappl_e.Un(_
ug/L
ug/L
ug/L
ugll
ug/L
ug/L
Dup- Rel. Yo Ditf
qW =Tdo
S{D
Page 148
METHOD 200.8 SUMMARY REPORT
Sample lD:09010245 MSD-30 X20 2.5 OF 10
Sample Date/Time: Tuesday, October 18,2005 13:45:57
Sample Type: Sample
Sample Description:BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\1 01 805-1 .sam
Method File: c:\elandata\Method\20O.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 0 1 805\1 0 1 805\090 1 A245
Tuning File: c:\elandata\Tuning\default.tun
Opti mizatio n Fi Ie : c :\e la ndata\Opti m ize\d efa u lt. da c
MSD-30 X 2A 2.5 0F 10.038
Concentration Results
Analyte Mass -*[4eas- lntens-Mean Net lntens. Mean Conc. Mean Conc- SD Conc. RSD
s fr=sco(1 r--l&s1)
c\,ffRpd
[f-- W= {vfr1'(qru'J)
[, Tb
Hf
Hf
Hf
Hf
Hf
[,
159
176
177
178
179
180
339520.362
22732.920
81012.772
119974.1 15
60157.071
157008.528
339520.36
0.07
0.24
0.35
0.18
0.46
532.4341
533.1216
s32.6546
s33.3904
538.1252
1.5561
5.4284
5.4797
23A64
5.5771
0.2923
1.0182
1.0288
0.4324
1.03&r
SarnpJg Ulit
uglL
uglL
ug/L
ug/L
ug/L
ug/L
Oi
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QC Calculated Values
lnt Std o/o Recovery Spike % Recovery
89.016
Dilution o/o Diff Dup. Rel. % Ditf
Measurement Type Analyte Mass
QC Action Line: No QC out of limits detected
QC Out Of Lirnits
Out of Limits Message
QC Action
II *"*'
I METHOD 200.8 SUMMARY REPORT
I tample lD: 0901 02-31 xzl (
I i;illi:ix#fr,d::.]ff,:.'2005
13:5223
I -ilH'or Repricates:3 :.;,;;;;, , ,,. ., r,olo9 , ^ /
I 1ffiffifiu'mffim,*ffi:::: /"VW
| ^nalyle
Mass- .Meas.lnleos-Ilean------Net lntens. Mean Conc. Mean. drr"."o . co!s-8$p , Sample Unit
I l> Tb 15s 335299'767 335299'77 ,r.uurr/ 0.5682 4.183s HiiI I ff lii ,?iilil lll ,ii& ;,i;. 7s7s2 us,L
I i Hr 178 3098.670 0.ol tt.g&t 0.9437 6.78s3 us/L
I i Hr 17s 1s88.755 o.0o t/au 0.s26s 6.5163 us/L
I L Hf 180 4100.058 0.01
,/ta.xn
1.o0se 7.077s us/L
| " ccatfiatedvatues
I nnage Mass OC Std 7o Recovery lnt Std % Recovery g$iX"o/"Recovery Dilution % Diff Dup. Rel. % DiffI i'il F -'/
lil 1li / (
ixl lI; /
i ec out of Limits
Measurement TypeAnalyte Mass 9/ot f-irnit. Message
ec Action Line: No ec out of rimirs detecred
QG Action
(
Page 150
METHOD 200.8 SUMMARY REPORT
Sample lD: QC Std 3
Sample Date/Time: Tuesday, October 18, 2005 13:55.22
Sampte Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\1 01 805-1 .sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 01 805\1 01 805\QC Std 3.040
Tuning File: c:\elandata\Tuning\default.tun
Optirnization File: c:\elandata\Optimize\default.dac
Concentration Results
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
347191.316
43365.617
154003.789
2284rc.066
114285.734
298023.009
347191.32
0.13
4.44
0.66
0.33
0.86
Meas-lntens,--lll9a1_._ __ Net lntens. Meq!*
[,
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QG Calculated Values
lnt Std % Recovery Spike % Recovery
91.028
QC Out Of Limits
Measurement Type Analyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
CCV=
Conc. RSD
1.8287
1.4925
1.2503
1.5329
1.3291
Dilution % Dttt Dup. Rel. % Ditt
Sample Unit
ugl[-
ug/L
ug/L
ug/L
uglL
ug/L
P
Conc. Mean Conc- SD
49.6056 0.9071
49.5595 0.7397
49.5143 0.6191
49.5495 0.7596
4e.e46i toBbo.oosa
Page 151
METHOD 2A0.8 SUMMARY REPORT
Sample lD: QG Std 4
Sample Date/Time: Tuesday, October 18, 2005 14:01:49
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample Fite: C:\Elandata\Sample\1 01 805-1 .sam
Meth od Fi le : c:\ela ndata\M ethod\200. B\hafn i u ma Il. mth
Dataset File: C:\Elandata\DataSet\1 01 805\1 01 805\QC Std 4.A41
Tuning File: c:\elandata\Tuning\default.tun
Optim ization F i I e: c :\ela n data\Optimize\defa u lt.dac
Concentration Results
Mea tens. Mean Conc. Mean
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
343108.094
643.517
2444.542
3701 .481
1874.457
4821.565
343108.09
0.00
0.01
0.01
0.01
0.01
0.8089
0.7898
0.81 17
0.8198
0.816s
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QC Galculated Values
lnt Std % Recovery Spike % Recovery
89.957
Dilution % Ditf Dup. Rel. % Ditt
QC Out Of Limits
Out of Limits MessageMeasurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
CLry
Conc. SD
0.0s33
0.0485
0.0643
0.0489
0.0533
Conc. RSD Sample Unit
ug/L
6.5840 ug/L
6.1382 ug/L
7.9235 ug/L
5.9625 uglL
6.5317 ug/L
Page 152
METHOD 200.8 SUMMARY REPORT
Sample lD: 0901 02-32 X 20
Sample Date/Time: Tuesday, October 18, 2005 14:05:16
Sample Type: Sample
Sample Description: BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\1 01805-1.sam
Method File: c:\elandata\Method\2O0.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 01 805\1 01805\0901 02-32 X 20.042
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
339s10.694
270.896
1079.041
1625_426
836.3s8
2125.667
339510.69
0-00
0.00
0.00
0.00
0.01
Conc. Mean
7.6274
7.0008
7.1864
7.3645
7.2616
Conc. SD
[,ug/L
ug/L
uglL
ug/L
ug/L
usfl- <o,ol
0-6696
0.2743
0.2726
0.3464
4.22s2
8.7788
3.9186
3.7931
4.7039
3.1013
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Ditt Dup. Rel. % Diff
89.014
QC Out Of Limits
Out of Limits Message
Page 153
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-33 X2A
Sample Date/Time: Tuesday, October 18, 2005 14:08:16
Sample Type: Sample
Sample Description: BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101805-1.sam
Method File: c:\elandata\Method\2O0.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 0 1 805\1 0 1 805\090 1 02-33 X 20.043
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Analyte -1y3ss . .Me?s -t&tenc - tileJeg- --- -=-+leUoter6. Mean
[,Tb
Hf
Hf
Hf
Hf
Hf
159
176
177
178
179
180
339090.575
175.285
870,693
133s.729
649.015
1694.O12
339090.57
0.00
0.00
0.00
0.00
0.00
Conc. Mean
5.4427
5.6331
5.9069
5.70M
s.7891
.*. _Conc- SD
4.5204
0.4564
0.2090
0.4515
0.1 653
Conc. RSD
9.6322
8.1421
3.s383
7.9128
2.8549
Sample Unit
ug/L
ug/L
ug/L
ug/L
UC'/L
ffi,- 46,,ol
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QC Calculated Values
lnt Std % Recovery Spike % Recovery
88.904
Dilution o/o Ditf Dup. Rel. a/o Dift
Measurement TypeAnalyte Mass
QC Action Line: No QC out of timits detected
QC Out Of Limits
Out of Limits Message
QC Action
Page 154
METHOD 200.8 SUMMARY REPORT
Sample lD: 0901 02-34 X 20
Sample Dateffime: Tuesday, October 18, 2005 14:11:16
Sample Type: Sample
Sample Description: BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101805-1.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\101805\101805\090102-34 X 2A.044
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Goncentration Results
Analyte-IUass Meas- lntensrMean____Ilet_l_Dleos, Mean Conc. SD
[, Tb
Hf
Hf
Hf
Hf
Hf
159
176
177
178
179
180
34222A.884
156.342
820.357
1 152.380
576.012
1s39"282
342220.88
0.00
0.00
0"00
0.00
0.00
Conc. Mean
4.9239
5.2570
5.0459
5.0163
5.2103
0.7937
0.8139
0.6464
1.1124
0.7888
cs!_q, RqP__ 9efpl9 llnit
uglL
16.1 1 95 ug/L
15.4828 ug/L
12.8111 ug/L
22.1758 uo/L
15.1388 uin- AO'O I
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Measurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Dttf Dup. Rel. % Datf
89.724
QC Out Of Limits
Out of Limits Message
Page 155
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-35 X20
Sample Date/Time: Tuesday, October 18,2005 14:14:13
Sample Type: Sample
Sample Description: BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\'t 01 805-1.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\101805\101805\0901 02-35 X 20.045
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,
Analyte Mass - JVleas-Jntens-Mear----Nel lntens. Mean
Tb 159 345799 .207 34s799.21
Hf 176 95.788 0.00
Hf 177 626.U7 0.00
Hf 178 886-361 0.00
Hf 179 477 -AO8 0.00
Hf 180 1 162.060 0.00
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
QC Action Line: No QC out of timits detected
Conc. Mean
3.4961
3.9450
3.8312
4.0983
3.8842
Conc. $D
0.2245
4.7296
0.5918
0.7697
0.6907
6.3077
18.4942
15-4/.55
18.782A
17.7819
ug/L
ug/L
ug/L
ug/L
ug/L
usll <o,ol
[,
QC Calculated Values
lnt Std 7o Recovery Spike % Recovery Dilution % D;ltt Dup. Rel. Yo Dift
90.663
QC Out Of Limits
Out of Limits Message
QC Action
Page 156
METHOD 2A0.8 SUMMARY REPORT
Sample lD: 0901 02-36 X 20
Sample Date/Time: Tuesday, October 18,2005 14:17:07
Sample Type: Sample
Sample Description: BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\I01805-1 .sam
M ethod F ile : c:\ela ndata\Method\200. B\hafniu ma I I. mth
Dataset Fite: C:\Elandata\DataSet\f 01 805\1 0 1 805\090 1 02-36 X 20.046
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Analyte Mass _ Conc. Mean
[, Tb
Hf
Hf
Hf
Hf
LHf
159
176
177
178
179
180
2.000
2.287
3.000
3.667
2.333
1.987
2.00
1.14
1.50
1.83
1.17
0.99
lnt Std o/o Recovery Spike
0.001
QC Out Of Limits
Out of Li ts Message
lnternal td Out of Limits
QC Action
9072.4995
3352.1333
2763.8142
3512.47
1155.
.9667
935.4138
1151 .4122
1738.2482
1168.1510
59.8949
57.7368
4r.6603
49.4879
101.0591
Sample:Ulit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
QG Galculate Values
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement Type Analyte Mass
Tb 159 tnt Std for s:Tb 159
QC Action Line: Continue
ecovery Ditution % Ditt Dup. Rel. % Ditt
[,
Page 157
METHOD 200.8 SUMMARY REPORT
Sample lD: 0901 0246 X 2A MS-37
Sample Date/Time: Tuesday, October 18,2005 14:23:40
Sample Type: Sample
Sample Description: BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101 805-1.sam
Method File: c:\elandataWethod\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 01 805\1 01 805\0901 02-46 X 20 MS-37.048
Tuning File: c:\elandata\Tuning\default-tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
- - Analyte Masp Meas. lntens. Mean
[, Tb
Hf
Hf
Hf
Hf
LHf
159
176
177
178
179
180
346374.103
19338_235
69170.841
102795.165
51799.142
133657.510
Net lntens. Mean
346374.1A
0.06
o.20
0.30
0.15
0.39
Conc. Mean Conc. SD
444.1934
446.1232
447.2826
454.1221
448.9965
9.4011
4.8343
6.6785
5.4327
3.3276
Conc. RSD
2.1165
1.0836
1.4931
1.2069
4.7411
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QC Galculated Values
lnt Std % Recovery Spike % Recovery
90.813
44 --+2q01 ''<@
j
ilT--
Measurement Type Analyte Mass
QC Action Line: No QC out of limits detected
QC Out Of Limits
Out of Limits Message
QC Action
s+=s&(t*psD
Sample Unit
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Dilution % Ditt Dup. Rel. % Ditf
Page 158
o METHOD 200.8 SUMMARY REPORT
Sample ID: 0901 0247 X 20 MSD- 37
Sample Date/Time: Tuesday, October 18,2005 14:28:05
Sample Type: Sample
Sample Description: BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\EJandata\Sample\101805-1.sam
Method File: c:\elandata\Method\2OO.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\101805\101805\090102-47 X20 MSD- 37.049
Tuning File : c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf t7g
Hf 180
423237.074
24716.018
88094.165
131 143 .302
66049.020
171966.035
423237.07
0.06
4.21
0.31
0.16
0.41
464.5433
465.0530
467.0892
469.7854
472.8238
5.6717
6.2800
6.7330
5.3598
2.4947
Conc. RSD
1.2209
1.3504
1.4415
1_1409
0.4430
Sample Unit
ug/L
ug/L
ug/L
ug/L
uglL
ug/L
Concentration Results
Mpas-l=o[gns-idean--- --Nlet Intqns. [Iean Conc. Mean Conc. SD
[,
[,
Anatyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QC Out Of Limits
Measurement Type Analyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Hf,
J/
^w--Ys1,GRPdso
}ksre(15-l&s7)
Lo-rr_pPfJ.
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution o/o Diff Dup. Rel. % Ditt
110.965
METHOD 200.8 SUMMARY REPORT
Sample ID: QC Std 3
Sample Date/Time: Tuesday, October 18, 2005 14:34:32
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sarnpte File: C:\Elandata\Sample\1 01 805-1 .sam
Method Fite: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 01805\1 01 805\QC Std 3.050
Tuning Fite: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
CCVd
Concentration Results
[,
I
A-nalyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Meas. lntens. Mean
436260.1 49
55112.7A9
196950 .164
2y8n 136
147356.126
3820s9.657
Net lntens- Mean
436260.1 5
0.13
0.45
0.67
0.34
O.BB
Conc. Mean Conc. SD Conc. RSD Sample Unit
ug/L
1 .1908 ug/L
1.4814 ug/L
1.0744 ug/L
1.1201 uglL
1 .7015 ug/L
50.1723
54.4413
54.4214
50.8452
50_9s89
0.5975
4.7473
0.5415
0.5695
0.8671
[,
QC Calculated Values
Analyte Mass QC Std o/o Recovery lnt Std 7o Recovery Spike % Recovery Dilution % Diff Dup. Rel. % Diff
Tb 159 114.380
Hf 176 100.345
Hf 177 100.883
f-rf 178 100.843
Hf 179 101.690
Hf 180 f 01.918
Measurement Type Analyte Mass
QC Out Of Limits
Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page 160
METHOD 2A0.8 SUMMARY REPORT
Sample lD: QC Std 4
Sample Date/Time: Tuesday, October 18,2005 14:40:58
Sample Type: Sample
Sampte Description:
Number of Replicates: 3
Sarnple File: C:\Elandata\Sarnple\1 0 1 805-1 .sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 01 805\1 01 805\QC Std 4.051
Tuning File: c:\elandata\Tuning\default,tun
Optim ization File : c:\e la ndata\Opti mize\d efa u lt.dac
Cc6v
Concentration Results
Analyte Mass .Meas. lntens. Mean Net lntens. Mean Conc. Mean Conc. SD - ,- Con-c,. RSD Sample Unit
[, Tb 159 45A29A.340 450290.34 ug/L
Hf 176 734.626
Hf 177 3050.660
Hf 178 4578.401
Hf 179 2279.515
0.00 A.7123 0.0667 9.3673 ug/L
0.01 0.7521 0.0431 5.7374 ug/L
0.01 0.7649 0t.0262 3.4254 ug/L
0.01 0.7595 0.0306 4.0324 ug/L
0.01 0.7689 A.0243 3.1575 ug/L
QC Calculated Values
1 18.058
Hf 180 5959.250
Analle Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. % Diff
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
QC Out Of Limits
Measurement Type Analyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page 161
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-21 X20
Sample Date/Time: Tuesday, October 18,2005 14:48:55
Sample Type: Sample
Sample Description: BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101805-1.sam
Method File: c:\elandata\Methodl200.8\hafniumall.mth
Dataset File : C :\Ela ndata\Data Set\1 0 1 805\1 0 1 805\090 1 02-2 1 X 2A.O 52
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Meas- lntens. Mean
407930.460
37B.AZs
1695.768
2s7B.2U
1283.392
3355.701
f,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QC Out Of Limits
Out of Limits MessageMeasurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
Page 162
METHOD 200.8 SUMMARY REPORT
Sample lD: 0901 02-31 X20
Sample Date/Time: Tuesday, October 18,2005 14:51:53
Sample Type: Sample
Sample Description: BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\l01 805-1.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 01 805\1 0 1 805\090 1 02-31 X 20.053
Tuning File: c\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
Analyte Mass - Meas" In!en_s. Mcan,, _Net ldens. Mean Conc- Mean Qonc. SD Conc. RSP ,== Sqllgle Un!!_ ,
> Tb 159 433199.351 433199.35 ug/L
Hf 176 226.663 0.00 5.4461 0.7561 13.8834 ug/L
Hf 177 1202.385 0.00 6.0977 1.0164 16.6683 ug/L
Hf 178 1769.444 0.00 6.1228 0.7867 12.8486 ug/L
Hf 179 945.032 0.00 6.5131 1.0375 15.9294 uslL
Hf 180 2351.288 0.0'r 6.2883 1.A226 16.2617 ugtt (o.o I
QG Galculated Values
Analyte Mass QC Std o/o Recovery lnt Std % Recovery Spike % Recovery Dilution % Diff Dup. Rel. % Diff
re Hf 176
Hf 177
Hf 178
Hf 179
Hf 180.
113.577
QC Out Of Limits
Measurement Type Analyte Mass Out of Limits Message
QC Action
QC Action Line: No QC out of limits detected
Page 163
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-36 X20
Sample Date/Time: Tuesday, October 18, 2005 14:54:50
Sample Type: Sample
Sample Description: BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101805-1.sam
Method File: c:\elandata\Method\200.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\101 805\101805\0901 02-36 X 20.054
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Goncentration Results
[,
Analyte Mass htens. Mean
Tb rsg 412394.064 412394-06
Hf 176 178.813 0.00
Hf 177 995.035 0.00
Hf 178 1446-A75 0.00
Hf r79 729.352 0-00
Hf 180 1888.534 0.00
Conc. Meaqr __ ._9ong. 9q
4-7332 0.9077
5.2865 A.7294
5.2488 0.9511
5.2662 0.9310
5.2990 0.8730
Cglc, ESD
19.1779
13.7978
r8.1203
17.6791
16.4749
Dilution % Ditt Dup. Rel. % Ditf
Samplet Unit
ug/L
ug/L
ug/L
ug/L
ug/L
us/L <0,O (
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QC Calculated Values
lnt Std o/o Recovery Spike % Recovery
1A8.123
QC Out Of Limits
Out of Limits MessageMeasurement Type Analyte Mass
QC Action
QC Action Line: No QC out of limits detected
Page 164
METHOD 200.8 SUMMARY REPORT
Sample lD: 090102-37 X20
Sample Date/Time: Tuesday, October 18,2005 14:57:44
Sample Type: Sample
Sample Description: BATCH 1698 URS
Number of Replicates: 3
Sample File: C:\Elandata\Sample\101805-1.sam
Method File: c:\elandata\Method\2O0.8\hafniumall.mth
Dataset File: C:\Elandata\DataSet\1 01 805\1 01 805\0901 02-37 X 20.055
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
4417 41 .1 8 1
147.325
926.031
1352.066
688.684
1700.96s
4417 41 .18
0.00
0.00
0.00
0.00
0.00
Conc. Mean
3.9431
4.5808
4.5798
4.6389
4.4534
_Conc. SD_
0.7313
0.8230
0.9085
4.7625
0.8362
18.5474
17.9666
19.8371
16.4364
18.7764
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L <o, O
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
QC Calculated Values
lnt Std % Recovery Spike % Recovery
115.817
Dilution % Dift Dup. Rel. % Ditt
Measurement Type Analyte Mass
QC Action Line: No QC out of limits detected
QC Out Of Limits
Out of Limits Message
QC Action
Page 165
METHOD 200.8 SUMMARY REPORT
Sample ID: QG Std 3
Sampte Date/Time: Tuesday, October 18, 2005 15:00:41
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sampte File: C:\Elandata\Sample\1 01 805-1 .sam
Method File : c :\ela ndata\Method\200 .B\hafn i u mal l. mth
Dataset File: C:\Elandata\DataSet\1 01 805\1 01 805\QC Std 3.056
Tu ning File : c:\elandata\Tu nin g\default.tu n
Opti mization Fi le : c:\e la ndata\O pti m ize\defa u lt.d a c \
V
Conc. SD
Dilution % Ditt Dup. Rel. % Ditt
Cc Ua
0.7466
4.4426
0.4657
0.5391
0.5038
Conc. RSD Sample Unit
ug/L
1.5016 ug/L
0.8839 ug/L
0.9256 ug/L
1.4677 ug/L
0.9895 ug/L
Concentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Meas. lntens. Mean
452610.802
56662.230
242838.287
302128.6s5
151813.763
396052.577
Net Intens. Mean
452610.80
0.13
0.45
0.67
0.34
0.88
Conc. Mean
49.7224
50.0728
50.3155
50.4920
50.9171
[,
QC Calculated Values
Analyte Mass QC Std % Recovery lnt Std % Recovery Spike % Recovery
Tb 159 1 18-667
Hf 176 99.445
Hf 177 100.146
Hf 178 100.631
Hf 179 100.984
Hf 180 101 .834
Measurement TypeAnalyte Mass
QC Out Of Limits
Out of Limits Message
OC Action
QC Action Line: No QC out of limits detected
Page 166
METHOD 200.8 SUMMARY REPORT
Sample lD: QC Std 4
Sampte Date/Time: Tuesday, October 18, 2005 15:07:08
Sample Type: Sample
Sample Description:
Number of Replicates: 3
Sample File: C:\Elandata\Sample\1 01 805-1 .sam
Method Fite: c:\elandata\Method\200.8\hafniurnall.mth
Dataset File: C:\E[andata\DataSet\1 01 805\101 805\QC Std 4.057
Tuning File: c:\elandata\Tuning\default.tun
Optimization File: c:\elandata\Optimize\default.dac
Concentration Results
[,
Analyte Mass
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 1BO
Meas. lntens. Mean
454235.417
653.561
2735.263
4093.921
2055.148
5327.451
Net lntens- Mean
454235.42
0.00
0.01
0.01
0.00
0.01
Conc. Mean
0.63s8
0.6680
0.6779
0,6786
0.6813
. - I::"_-
0.0333
0.0478
0.0391
0.0531
0.0355
5.2328
7.1509
5.7654
7.8310
5.2119
[,
Analyte Mass QC Std % Recovery
Tb 159
Hf 176
Hf 177
Hf 178
Hf 179
Hf 180
Measurement TypeAnalyte Mass
QC Action Line: No QC out of limits detected
Cc by
Conc. SD Conc. RSD
QC Calculated Values
lnt Std % Recovery Spike % Recovery Dilution % Dttt Dup. Rel. % Dift
1 19.093
QC Out Of Limits
Out of Limits Message
QC Action
Sample Unit
ug/L t
ug/L
ug/L
ug/L
ug/L
ug/L
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STL-SI Louis
Data Packages
Radiological Analyses
Data Packages are in order as discussed in the Data Validation Report (see Appendix C):
Data Package D5I070222
Data Package D5I080237
Data Package D5J070214
Data Package D5I090189
Data Package D5I03OL44
Data Package D5Il0015l
Data Package D5I130187
Data Package D5I02O2O9
a
o
o
STL Denver
4955 Yarrow Street
Arvada, CO 80002
Tel: [phone] Fax:
www.stl-irrc.com
STL
303 431 7t7t
AI\ALYTICAL REPORT
Western Zirconium Proj ect
Lot #: D5I07A222
Sheri O'Connor
URS Corporation
8t 81 East Tufts Avenue,
Denver, CO 8An7
STL DENVER
fu-Y
Linda L. Benkers
Project Manager
September 30, 2005
Severn Trent Laboratories, Inc.
Table Of Contents
Standard Deliverables wtth Supporting Documentatlon
Report Contents
Standard Deliverables
(fU, Cover Letter and the Report Cover page ore considered integral
parts of thts Standard Dellverable package. This report is inc:omplete
unless all pages indicated in th* Table of Contents are included.)
o Table of Contents
o Case Narratlve
o Executive Summary - Iletecdon Hightights
. Methods Summary
r Method/Analyst Summsry
o Lot Sample Sumnary
o Analytical Results
. QC Dsta Association Summsry
. QC Sample Results
. Chain-of-Custody
Su pporti ng Documentatlon
Note: A one-page "Descriptlon of Supporting Documentation" is
provided at the beginning af thls section.).
r VoIaflIe GC/IUS
o Semivolatile GC/MS
o Volatile GC
r Semlvolatile GC
I LCIIVIS or HPLC
o Metals
. &neral Cfiumlshy
o Radiochemlstry
r Subcontracted Data
Number of Pages
Check below rryhen
supportlng
documentaflon ls
present.
nnnnnInH
STL Denver
Case Narrative
D5r070222
With exceptions noted as flags or footnotes, standard analytical protocols were followed in the
analysis of the samples and no problems were encountered or anomalies observed. All laboratory
quality control samples anal5zed in oonjunction with the samples in this project were within
established control limits, with any exceptions noted.
The test results presented in this report meet all requirements ofNEL,AC, and any exceptions are
noted. This report shall not be reproduced, except in full, without written pennission from the
laboratory.
Sample Receiving
Three samples were received under chain of custody on Se,ptember 7,2005. The samples were
received in good condition at temperatures of 3.8"C and 3.3"C.
The results for all radiological analyses are included in this report and were performed by STL
St. Iouis; 13715 Rider Trail Norttr; Earth Citlt MO 63A45,phone [phone].
Radiochemistry, Various Methods
The method 900.0 MOD gross beta MDA for samples D5IA70222-001 through 003 was not met
due to reduction of sample size caused byhigh residual mass. The analytical results are reported
with the MDA achieved.
A lowlevel and a high-level LCS standard were anallzed with total uranium batch 5255169 and
they are spiked at different concentrations. Therefore, the RPD value reported for these two
standards does not apply. Both LCS recoveries were in eontrol.
All MSA4SD were performed on samples from other clients and/or lots and were in control.
AIl duplicates were performed on samples from other clients and/or lots and were in control.
STL Denver
METHODSffi
D5I070222
o
PARAMETER
ANAIJYTICAI,
METHOD
PREPARATION
METHOD
Gross Alpha (COPRECIP) by
Groes Alpha/seta by GFPC
Isotoplc Thorium by Alpha
Radium-zz6 by cFPe
RadJ,um-zz9 by GFPC
Total Uranlum By Laser Ph
RefereDC€B:
GFPC
SpectroBcopy
osphorlmetry
SM['nil 71L0 MOD
EPA 9OO, O MOD EPA 900. O
EML
EPA
EPA
ASm,I
A.- O1-R I{OD
903 . O MOD
904 IIOD
5L74-91
ASTT{
EML
EPA
gMUII,II
Annua1 Book Of ASflvI Standards.
trENVIRONMBITAL MEASIIREME}iITS LABORATORY PROCEDURES MANUAIJi
HASfr-300 28TH EDITION, VOLUME I and rI DEPARIIT{EIEI OF E}IERGY
" EASTERN ETWIRONMB{TAL RADIATION FACrI.,TTY RADfOCHEMISTRY
PROCEDURES IYIJLNUJ\IJ'I US EPA EPA 52A/S_84-006 AUGUST T"984
N STA}IDARD METHODS FOR WASTE WA:rERT o
STL Denver
ANALYTTCAL
METHOD
METTIOD/ANALYSTW
D5r070222
AI{IAITYST
ASTrvl 5L74-91
EML A-01.R MOD
EPA 9OO. O MOD
EPA 9OO.O }TOD
EPA 903 .0 MOD
EPA 904 MOD
sMI^t![ 7110 MOD
Rr=ferences:
AgI}{
EMI,
EPA
SMT{I{
Mlke Andergon
.Iody Watson
RLronda Ridenhower
Rlronda RLdenhower
fvan Vania
Ivan Vania
Bob Nicholas
AIIALYST
ID
4A23 s 0
63 903
06 004 0
50040
400697
4006e7
05200 5
Annual Book Of Asfi'l Standards.
,ENVIRONMEMTAIT I4EASITREME}IIS LABORATORY PROCEDIIRES I{ANUALr
HASI,-3OO 28TH EDITION, VOLI]ME I ANd II DEPARTIT,IENT OF ENBRGY
"EASTERN EITIRONMENTAIr RADTATION FAeII,Inr RADfOCHEMfSTRY
pRocEDURES MifNUArr'r US EpA EPA 520/5-84-006 AUCIUST L984
I'STANDARD METHODS FOR WASTE WATERII
STL Denver
SAIVIPLEW
D5rO70222
wo#SAIVTPLE# CLIEI{IT SAIVIPIE TD
o
SAIvIPLED SAIUP
DATE TIME
HLT3 P6
H.J3QA
H.I3QE
NC):[B (8) :
001 GW- 8A- 09060s
002 GW- 8B- 09050s
003 Gw- 7A- 0905 0s
a9/oG/as 1o:35
ag/05/a5 t2-,a5
oe/06los 13:10
- Tho onr.lyticrl rGqdts of the sampl$ lisrcd rbovo rro presciled o, $e fotlowlnj pages
- All cslcul.tiors arc pcrformrd beforc roundhg ro evold rouDd{rf cror$ tn calc[hrcd rcsrls.
- Rcults norcd e6 'ND' wore mt dorocrEd il or rboyo thG $etod limit.
- This repon mus not bc rcproducod, oxc€pt in fult, wilDout th6 writtdl rpproval of ftc laborsiory.
- Re$ths for dte folloving puuDctcr$ ue Dcvcr rcportcd on a dry weight brsis: cotor, corosivky, dcnrity, Ilerhpoint, i3Diobility. lryers, odor,
palnt fifter n6[. pH. porosity pressrc, rc.ctlvlty, rodox poicn$al, Scciflc Sravlty, spot lcsts, solids, sofubility. ternpcrdture, viecocity, rd welsrrr.
STL Denver
O
URS Corporatlon
ClLent Sarnrcle fD: G$[-8A-090505
Scvcrn Trant rraboratorLes - Rrdtochmistra,
Lab Sarnple ID:
Work order:
I,latrix:
Parartar
D5r070222-001_
HJ3 P6
GW
lrrult
Date Collected:
Date Recelved:
a9/06/a5 1035
a9/07 /45 0930
Totrl
Unctrt.
17 o+l-l
Prop lnrlrrrlt
Dct. Detr Drtob I Yld t
GIROgg .L/B BY OTPC
Glrorr Brtr
EP 900. o ![oD
35.9
ecLlL
7.0 7.9
900. o !!oD
09 l09l05 0elLll05 5252107
ToErl Uraal,un bV
Iotrl Urr.nlurrr
KPt' }AEDT 5L7I-91
3 -94 o. {1
uf,lL
0 .31
3L7 t -91
oellSlos 09l,'lo' 52s5169
ffi,oas }' By co-PRIcIP 8!otw 7110 iloD
Orolr ll'phr 3.17 0. 9l
tCLIL
o.70
7110 DilOD
09to8/05 a9tL6l03 5.25Ll7t
Rl-226 BY EPl,-903 - O llOD
Radl,rrn (e26) 0.19 o.13
p,ct/L
o.19
903. O MOD
a9 lo8lo5 ae 127 /05 5251058 98
Rt-228 BY OrPC EPr, g0{ !fiOD gctlT)I00 DIOD
uu 228.
rrO THORII'U
o. gg
(SHOR|r gT) DOE
0.39
4.a27
o ,53
0.20
0-o71
oCIIL A-O1-R
09 tLrloS
a9/14/05
uoD
a9 tLgl05
091L9/05
oet08/05 09127 lo5,5251039 72
llhorLun 23O
Tlrorir:rn 232
.tr-ol-R ltoD
J
U
0.13
0.L2
5257300 92
52573 00 92
tr. lasq>lotr rlthout tbe o,o pr'.rrtlvr.
roC lo dotorrtaed by lE.truDalrt gorfotztaoo ooly.
lold rorultr rr. grolg.E thra tba lOC
i, Rcrult ir grrcrtor thrD, lr[Dlc CotcctloD ltatt but I.!! thrl ttrts.d rclprBlng ll.stt.
6TL Baffv€lr lor thrrr th. rruDt. dct.otlo! llDtt.
URS Cor;poratl.on
ClLent Sarnrplc IDs G$[-88-090505
Scvcrn Brant lraboratorleg - Radiochdntrtry
Lab Sample ID:
Work Order:
MaErix:
Drnrtrr
D5 r 07 4222-0A2
HJ3OA
GW
trorrrlt
Date Col}ected; 0 9 / 05 / 05 1"2 05
Date Recelved: A9 I 07 / A5 093 0
TotaI.
Uoor*.
(2 o+l -l
Prrp fsrlyrlr
Datc Drtr narch I
cRogg t/t Br orDc
Orors Bota
EPl, 900. o DtoD
112
plCIl[t 900. o MoD
a9l09lo|, 09/13 lo3 5.2321,0723
trotrl Uranl,um b8r
rotal Uranlusr
KPL nsrH 5171-91
{,06 0. a6
uslI,_
o.31
5L7 r-91
09/13 lO5 0elr.rlos s35516e
oRo88 A By CO-pRtCIp gDiWW 7110 tiOD
Orort Llphe 5.5
pc,-lt
0,9
7110 DIOD
a9 IO8lA5 09IL6|A3'215L17I
Bt-776 Br EP},-9O3. O l'!oD
RrdLurn (226) 0.{8 0.20
nCLIl'
o.2{
903.0 t[oD
09 I O8l AS 09 127 l05 5251058
u-229 BY CIrPC
Rrdl,ua 22A
EPt 901 rdoD
1 .13 0 .63
pCLII,
o-98
9 0{ ![OD
09 lo0los oelz7 la5 535105e 73
Iro ,IIIORTITDI ( SHORI
Thorlum 230
Thorium 232
cr) DoE }'-ol-R r[oD
0.15
0-025
.e,-01-R !@D
09/74/05 09/L9/As
a9/74/Os A9/L9/05
5257 300 86
5257 300 86
pCt /r,
U
U
0.1d
a -a79
o. 16
o. 14
NorE (8)
Drta raa lloqrl'otr rttLout tb. ou. llrrfrtlva.
fOC lr d.t.ml,D.A byr tnrtrunrrnt gorformror ou1y.
BoId rcrultr tr. grrGrtcr th.[ tb. UDC
J Ruult tt gr.rt.r tt [ lc4rla o.tcatl,oD ltDlt brt lorr tLu .tat.A roDortlag ltrdt.
BTt DOfnrdtr 1o.. tb.D tL. rrqrle d.t.sti@ U.nlE.
tIRg Corgoratl.on
Client $ample ID: GIIiI-7A-090605
Sevrrrn Trent Laboratorics - Radfochsd.Btry
Lab Sanple
Work Order:
Matrix;
Pr,rrnrtcr
D5 r 07 0222- 0 03
HJ3OE
GW
Rrrult
Date Collected:
Date Received:
09 / 06/0s 1310
a9/07/05 0e30
TotrI
unoert,
(7 o+l -l
PrrD
htr
fnrlfrl,r
Datr rEob I YId t
OROEE AIE BY OTPC
Ororr Brtr
lPt 900. o riloD
7{0 160
eCLIL
200
900.0 t[oD
09 loetas 0e lL3 lo3 5252Lo7
lfotel Urralun by
Totrl Ureal,un
xPr .trgru 5171-91
173
uglt 5L7 l-91
a9llllo, o9l1.3l05 525516e0.3
oRo88 r Br co-pREcrp suDrr 7110 rroD
Orosr llphr Z7 ,5 l.?
eCLlr,
1,5
7110 lrOD
09laelaS 09ll6la, ,.21147|,
nl.-226 BY rPA-903.0 DIOD
Rrdlrrn (?26) 1.28 0.30
gctlL
0 .23
903.0 l[OD
09/08/05 aelz7 la5 5251058
BJl'-228 BY OrPC EPl' 901 t[OD pCt/r,9 0{ ![oD
un 228
Iro TEORrInil
l.?3
(gHoRE C!!) DOt t-01-R MOD
1.a1
0-02 u
0 .78
o. c0
0 - 10
E,c,L IT'
0 .86
0,17
0.19
oeloSloS 49 t27 I 05 5251059
Thorirrn 23O
Thorlurn 232
r-o1-n
a9lL{l o8
09/L4/As
!@D
oslleloJ
09/19/05
5257300 7t
52573 00 7 4
(8)
tr i,r. Iloqllrtr rtthout bh. orr. narratlvo.
t|Dg 1r dctanrrtnod by tnrtnunrnt Dcrfoxanraoo only-
BoId rctultr lr. lrrretcr thtD th. ilDC
u Rrrult lr lcrr thra the aaqllc dctaction r.lmLt,.
STL Denver
acrlATA oNW
Dsro70222
Samp1e Preparation and Analyels Cont.rol Nr:mbers
SAI\4PIrE#MATRIX
001-
002
003
GW
GW
G[t[
GW
GW
GW
gw
GW
GW
GW
GW
GUr
GW
GW
GW
GW
GW
GW
AIVAIJYTICAIJ
}/ETHOD
EPA 9OO. O MOD
ASTM 5174-91-
sM9[I{ 71"10 MOD
EPA 903.O MOD
EPA 904 MOD
E}[L A-01-R MOD
EPA 900-0 !/[OD
AST!,I 5L74-91-
SMWW 71_1-0 MOD
EPA 903.0 I"10D
EPA 904 MOD
EML, A-01-R MOD
EPA 9OO. O MOD
AST!{ 5L7 4-9L
SMWI^I 7110 MOD
EPA 903.0 MOD
EPA 9O4 MOD
EMIJ A-0L-R MOD
I,EACH
BATCH *
PREP
BATCH #
5252L47
5255169
525 L47 4
52 51- 0s I
525L05 9
52573 0 0
52521A7
s2551,6 9
525 L47 4
s2510s8
s2s10s9
s257300
s2s2LA7
52551,5 9
525L47 4
5251.0 5I
52sL059
s2s73 00
MS RTIN#
s2s2 055
525s 1-4 s
52s 1_ 3 21
5257L99
5252055
s2s5L45
s25L32L
5257L99
5252055
525s145
525L 3 2L
52s7L99
O
Denver
IIETEOD B[T}}IK
Trcat lraboratorleE
REPORT
nrdiochutl'rtry
Client Lot
Matrix:
Paramtu
Scvcra
D5r070222
WATER
ISrrrrIt
lPotaL
Uactrt.
(7 o+l-l
Prcfl
Drto
LaIe 8c4llo fD
Aaalyrl.!
Dott Drtoh I rt6 t
R.f,'.228 BY (IEDC
Radlum 228
EPt 90{ uoD
*0. 06
rlcL lt,
0. 47
900 DioD
0. 81
r5r080000-0598
09 / a8l 05 a9 /27 / As 5251 059 84
nr-226 By EPt-903.0 t@D
Radlum '226) 0 .02
T,CLIL
0-13
903.0 tloD
0.24
r5r080000-0588
09 / a8 / 05 09 / 27 / 05 525L058 LO3
onosg r/D
Gross Beta
By orPc EP* 900.0 !@D
0.20 u
ecllt,
0,93
900. 0 tioD
i.6
r5r090000-107B
os / og / as 09 / 12 / 05 s252Lo7
oRo88 }' BY CO-PRECIP SUWW
Gross A1pha -0. 04
7 LLo rrOD
U
gc,-lL
0.l5
7110 DIOD
a .67
psr080000 -17 la
09 / 08 / 05 09 / 1.6 / 05 525L47 4
?otrl Unnj.rn blr
tal Uranlum
xPt tsllr 517{-91
-0.0743 U
ug /l'
0 . 0089
ecl-lt
0. 15
0.062
5L7 l-91
0.31
l-ol-R !@D
0 .12
0.059
r5r120000-1598
a9 /13 / 05 a9 /15/05 52551-69
r5r1CO000-3008
a9l,.tlos oelt9lo3 5257300 87
09/L4/05 09/L9/A55257300 8t
fso THORfm[ (8HORT Cf) DOE ],-01-R I{t}D
'lfborl.rrn 230 O.23 if
Thorium 232 A.022 U
rre lacqllrto rLthont tho carr arrrrtl.vt.
lDc Lt dctrrmtnrd urtng lnrtrerucat porforrnraor only
Bofd rcrultr tr. glrcrttr thu thr t(DC
i, R$u1t l; g:rcrtor thrn rrqrlc cctcctlon ltrnl.t but
6TL flnflyaf Icrr rhrn rhr raqrlc dctcctl.on l:[^ntr,
hrr thrD rtrtod rrporElng lLmLt.
10
t-
CIient Lot
Matrix:
Puemrtrr
LaboratoRf Control
Severn Trent Laboratorieg
D5 r 07 0222
T^IATER
ogtta r0ount, Rolult
l[otaI'
Ilaoort.
(2 o+l'l
Sarple Raport
- Radl.och@tLatraz
rab 3uO1e II)
0C Coatrol
tr Yld t lro r,lnl.tr
C'RO88 }, BT CO-PruCIP
cross Alpha
gDrHW 7110 UOD
20.6 Lg.4
Batch tr 525L474
7110 !rcD
0.s
laalyrlr Drtrr
r5r080000 -17 {c
(71, - 1d3 )
S*Llf'
89
09 /L6l05
OROgg ^fB BY
Gross Beta
gFPe EPt 900. o D|OD
105
lrtoh, I r
900. o !{oD
1
larlyrl.r Drtrr
r5ro90000-107c
( 70 72Ll
r,Bt llt
105
5252]-47
11 101
09/1,2/05
Iro TIIO&tgl{ (SIIORI
Thoriun 228
Thcrlum 234
Thorlum 232
cT) DOE r-01-R
I-81
9 -46
8.82
Eatolr * r
!,!oD
9.3
8.3
9.2
52573 00
gcllL
1.1
1,0
1-1
r-01-R t80D r5r1tO000-300c
0. 1 e2 105
0.09 92 87
0.r. 92 104
tnrlyrlr Drtrr 09 / Lg / 05
( 91 1321
(65 l-2e)
(88 L33)
NOmls)
Stl%dfr{E?"f".4 br b.larllmt portotrucr ooly
colgtrlaEl6a tre pcrtonrd bolorr rouad,lag to arolA rqrld-ot! rrtor ln orloulrt.ll r.rult.
Laboratorfz Control Saqrl,c ll,;C,8 Urplicata ReDofr
Severa Trot Laboretorlcr - nrdiochol.rtry
D51470222
I^IATER
C1ient Lot
Matrix:
Paranttrr QgtLr frcur.t, Rrarlt
Irab 8agllc ID
Ae Control.
t 1,ld t Rrc "r-rar
- Preclrio
trotel
Uaolrt.
(2 o +l-l
Rr-228 Br orPe EPl' 901 t{oD
Radiurn 228 5.26
spk 2 5.26
EatoL lr
DCL/r.90{ troD
0.98
0. 87
76 L24
85 L72
llerlyrir Drtrr
15r080000- 059c
( 56 1,47 |
(56 ]-4,71 10 tRPD
09 /27 /0s
5 -54
5. 89
s2s10s9
R.A,.-226 AY IBPI-903 .0 WD
Radium Q26) ft-Z
spk 2 LL.z
8.9
8.3
trtoh tr 525L058
903. O rtoD
1.1 99 80
1.0 100 74
frrl'yelr Drtol
r5r080000-058c
(54 135)
(54 135) e tRPD
a9/27/05
D,ELII,
ToEaI UranLuur b1l, XPt tgEli 517{-91
Total Uranlum 40_0 42_3Spk2 8-00 -?.59
Batoh lr 5255169
5L7 {-91
5.0 106
0.78 95
lna.lyrl.r Drtr r
r5r12 0000-169C
(90 112)
( 90 LLa) 139 tRPD
a9/L5/45
vg lI)
STLgiEO*IlUbnf ar. Dcrfoild boton roudlng to rtold rord-off rrror b colculrtod r.rult.
Cllent Lot
l'tat,rix;
Prrernrtlr
Saverra
D5 r0 30L44
GW
eptho
lrount
OC 8rry>}r fD
IYLD trnrc
QC Control
f,lnttr
IIATRIX SPIKE
Trent Laboratorl,eg
REPORT
- Rlrdioehmirtzy
Date Sampled; 09 / A2 / 05
Date Received: 09 / 03 / 05
Spthc
Rorult
TotrL
Irnortr,. gptho 8rqllo
(2s+l-l Ild' llclult,
Totrl
Uaccrt.
(Z o +l -l
GIROEA I BY EO-PREEIP
Gross ALpha
minvr TLLa
4L -2
BaEch
xoD
31.8
#: 5251474
peLlL
4.2
7110 tfiOD
1.85
Analysis Date; 09 /76/05
D5r0301{E-OO1
a.77 73 (tt L33)
oRoSg }.IE
Grosg Betra
BY GrPC ItP[ 900,0 DIOD
804 136
Batch #: 5252L07
900. 0 troD
30.4 6.7
DsI03O1{lt-O01
88 (s0 r"so )
Arra1ysls Date : 09 / L2 / AS
DCL/f.
79
NOrrE (s)
Data are incomplete without
Calculations a.re perforrned
STL Denver
the cass narraE.lve.
before ror,urdlng to avoid round-of f arrors in ealculated results.
13
C1ient Lot fD:
Matrix:
DenDtar
}TAIIRTX SPIKE/ITNTRIX SPTKE
flewera [rcnt teboretorl,cr
D5r100L51
GW
DUPLICTTE REPORT
F Rrdioehutlrtry
Date Sampled:
Dat,e Received:
09 I 09 / 05 Ae25
aella/45 0Bl-s
OC 8r-rh ID
r Y1d rf,,oc Sril'rt="tApl.tr
.lrcunt
sDTTI
trurr}t
Tstrl
tllrcrrt. 8pl,hc glXPLt
(? o+l-) Ild lrruIts
lotrI
Uaecrt.
12o +l-l
roo THORfIIM (gHORlf
Thorium 230
Spk2
Thorlun 232
,Srpk2
cr) DoE
9 _46
9 .46
8.82
8.82
8.2
7 .37
9-8
8-0
5257 L 99
Dcl/L t-oI.*R
1.L 81 0.15
0.99 103 0-i5
1-.3 81 0.011
r-.0 103 0-011
lnrlyrlr datr r
DIOD
u 0.15 71"
u 0.15 7l
Froelrior
u 0.055 7'J.
u 0.065 71prtoLrlor
09/1,9/05
Dsr100151-002
85 (74 130)
76 04 t3o)
1]. TRPD
111 (81. 3.241
90 (91 - t24,1
2L TRPD
Brtoh lr
IloE(s)
Crlculatl,ol ara DaafoEDC brtore rsuldtlg to ercId rornd.-ot! rrror Ll oalqqlat.d rrlultr
STL Denver
U Rrrult lr Imr thrn tho trngllo dctcotLon }l-rdt.1,4
Client Lot fD:
MaErlx:
Parurtt
MATRIX SPIKE/UHTRIX SPTKE
Sevarn Trant Leboratorl,es
F5r050203
ws
DI,PIJICTTE REPORT
- Radtoch@istrA,
DaEe Sarrpled:
Datre Received:
08/29/Os 1035
09 / 0L / 05 0900
0e 8rql].r ID
t Yrd rrnoc :ii::'="'Spthe
fmrat
SPIXT
Rrnr1t
TotrI
Ihoorts, 8lrl,t SlllPIrE
(? o+ I -l rld f,uu1t
TotaI-
Uaeort.
17s + I -\
Totel UranLun btl, XPL fgru 5
toral Uranium 40,0
.9pk2 40. O
ug lr,
4.7
4 --l
laalytLr
JLT a-91
- 0 , 0511
-0-0511
drtr r
u 0.0050
r5r060203-001
99 (83 123)
( 83 L23)
39 .4
39-s
5255145
u 0-0050 99
PrrgLrLoor 0-3 tRPD
Bateh lr a9 / L5/ 05
NoIl(S)
Celonhtlor err Drrfortri brlore rouAlng to woltt roroit-off oror ia oalsrlatoil r.rq1t.
STL DenverU Xorult ir lorr tsbru tbc .antrrlc dctcctlon llBlt,
Cl-ient LoE f D:
Mat.rix:
PartrlErr
Savcrn
D5r070222
WATER
ETtrPLE
nrrult
DUPITICATE EVAITUITION RTPORT
Trcnt Laboratorl,es - RndiochmiBtry
Date SamSrled:
Dat.e Received:
09/a2/as
a9/03/05
Totrl
Unorr:t.
(2o +l-)
DUPLICftE
lorult
tqotal
Baoort.
(2 o+l-,t r].d
0C 8r4rh ID
Prrcl,rl,o,
oRoga t' By eo-PRlcIP
Gross Alpha
g!ilmr 7110
1.85 J
Eatsh I r
lIoD piC!, /\.,
o ,71
525Ln7 A ( SamPle)
7110 DIOD
1-O1 ,I
Dsr03014{-001
59 IRPD0.65
5251,47 4 ( Dr:p1i ca te )
GROgg ^lB Br grPC
Gross Beta
EPA 900,0 D'OD
30.d
lrtob, tr
prcLlL
6-t
5252LA7 (Sampta)
900. o !iloD
30. B
DsrO301{{-001
1" tRPD7.1
5252L07 (Duplleate)
GE(s)
htr tr. hoqrl.ta ,ttlout tL. cr.a arrratlvr,
Calsutlttst arr glrforrrd brfom roudtlq to rvotal ronoll-off o::or b oelaulate0 a.mlt.
Stf, B.Stai;lrr erorter tbra aaqrlc dctcotloB ltutt tut lorr thps .trtcd rrrqtsralr ltrlt.
76
STL Denver
Sample Receiving Checklist
PivI to Complete This Section: Yes
Residual ctrlorine check requireci:f
euotc#: tl1 Dtl 5
i\bs Quarantined ;
Yes NoDT
t_p bl'a},tb 1a S*--
/cL'/s
Time Zone.
. EW/EST . CDT/CST . MDT/I\4ST . PDTPST . OTHER
Linpacking Checks:
Cooler #(s): t
Tcuperarures ('C), 3. F
N/A les No
D { o r.
{ n 2.
tr { 3.
r{o
rD5trfiu6.
IFrr7.
3.3
Cooler seals intact? (N/A if hand delivered) If no, docr:ment on CIJR-
Chain of custody present? If no, documeut on CLR.
Bottles broken irnd/or are ]eaking? If ycs, docurrent on CLiR..
Multiphasic samples obvious? If yBS, document on C'tlR.
Proper container & prescrvatives used? (ref. Attachment D of SOP# DEN-QA-0003) If no, document on CLR.
pH of all saryles checked and meet requirements? If no, document on CLIR.
Sufficient voiuure provided for all amlysis requested? (ref. Attachment D of SOP# DEN-QA-0003) If no,
document on CLr& and contact-P.M before proceedi:rg.
Did chain of custody agree r*ith labels iD and samples received? If no, document on CLIR.
Were VOA saruples witbout headspace? @^ ___=:
Wcre VOA vials preserved? Prescrvanv
"
ydCl i4-t}C lsodium Thiosulfatc r-.t Ascorbic Acid
Did samples require preservation with sodiurn thiozulfate?
If yes to #l 1, did the samples contain residuai chlorine? If yes, documert on CUR.
Sediment present in dissolverVfiitered bottles? If yes, document on CLrR.
ls suflicient volume provided for clieni requesied MS, MSD or mairix duplicates? [f no, documeni on CUR, and
contact PM before proceedirg.
tr
e
{n8
tr rfg.
q-A 10.
c {n.
D tr 12.
f tri3.
u n14
{ 15. Receipt date(s) > 48 hours past the collection date(s)? If yes, noti8/ PAiPM.
16. Are aualyses with short holding times requested?
17 . Was a quick Tum Around (TAT) requested?
tr
d
o
D
,W
S"{eoPee$fiffile Receivrng'sunple Recciving Checklisl I z 1304 revision
t7
STI- -Denver
Sample Receiving Checklist
I-ot*-alZ: t /(^^l
I.ogin Checks:
N/A )'es No
,f D 18. Sufficicnt volumc ltrovidcd for all anall,sis rcquested? (ref. Attachmcnr D of SOP# DEN-QA-0003)
docurncnl on CUII and contaol PM before procecdirrg.
l/ g D 19. Is sufl-rcient'r,olume provided for clier:t rcgucstcd hrs, IUSD or nratrix duplicatcs? If no, documenr crn L'I.JR, and
conlact PIU bcforc proceeding.
,F tl 20 Did thc clrain <rf cusrody includcs "reccivcd by" arrd "rclinquished" by silyraturcs, dates, arrd timcs?
n ,f E 21. Wcre special log iri instructions read and followedit
,{ tr D 22- Were A-FCEII nuuls logged for refrigerated storagc?
E D 23. Were tests loggcd checkcd against the COC? \\Trich samplcn wcrc confirmerl? t
.g D I 24- Was a Rush finm corryrlcted for guick TAT?
,f n tr ?5. Was a Short Hold form corr4rletcd for anl,short holds?
g .fr 26. Is "Stricr |C0C'required?
C) 2 27. Were spccial archiving inrtructions irdicatcd in the Gcneral Cormrcrtsi) If so, nbat werc they?
eling and Storage Checks:Inirials
D 28. Was t}c subcorrtract COC si-qned and scul wi$ saryJcn to bottlc prep?
I J9- Were rarryle Iabcls doubic-checilcd b1'a secoud person?
I 30. lVere sarryle bottl* and COC double chec,ked for dissolved/filered metals by a second prson?
D 3I. Did tbr cample ID, Date- and Time fiom label marcb u,hat uas loggcd?
tr 32. Wsc stickerr foi special arcbiving instructious a6xcd to esch box and to the ICOC? Sce f.27
tr 33. \terc,/-FCEE mcals stored refrigerated?
I 34. Were "Strict ICOC'copies g'ivcn to satcllite storagc areasl/
Documsnl an-yproblems or discrepancies and thc actions talon to resolve them on a Conciition Upon Receipt Anomall'
Repofl (CUR).
o
Lab
:, ,{
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Etr
F
birtE
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De
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e
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STL Denver
4955 Yarrow Street
Arvada, CO 80002
Tel: [phone]
www.stl-inc.com
STL
303 431 7171
AI\ALYTICAL REPORT
Western Zirconium Proj ect
Lot#: D5I080237
Sheri O'Connor
URS Corporation
818l East Tufts Avenue,
Denver, CO 80237
STLDENVER
t&
Linda L. Benkers
Project Manager
Octob er 7 ,2005
Severn Trent Laboratories, lnc.
Table Of Contents
Standard Deliverables with Supporting Documentation
Report Contents
Sfandard Deliverables
(fn" Cover Letter and the Report Cover page Are considered integral
parts of this Standard Deliverable pockage. ThLs report is incomplete
unless all pages lndlcated in this Table of Contents are inctuded.)
o Tnble of Contentso Case Narratlve
o Executive Surnmary - Iletection Htshlights
. Methods Sumrnary
. Method/Analyst Sumrnary
' Lot Snmple Summary
o Analytical Results
o QC Data Association Summary
o QC Sample Results
o Chaln-of-Custody
Supporti ng Doeumentation
Note: A one-page "Description of Supportlng Documentation"
provided at the beginning of this sectilan).
r Volatile GC/MS
o Semlvolatlle GC/MS
r Volatile GC
r Semivolatile GC
r LC/IVIS or IIPLC
r Metals
r Cbnersl Chemisfry
o Rndiochernistry
. Subcontracted Dsta
Number of Pages
Check below when
supporting
documentaflon ls
presenLnnnnnn
STL Denver
n
Case Narrative
D5I080237
With exceptions noted as flags or footnotes, standard analytical protocols were followed in the
analysis of the samples and no problems were encountered or anomalies observed. All laboratory
quality conhol samples anallzed in conjunction with the samples in this project were within
established conftol limits, with any exceptions noted.
The test results presented in this report meet all requirements of NE[,AC, and any exceptions are
noted. This report shall not be reproduced, except in full, without wdtten permission from the
laboratory.
Sample Receiving
Seven samples were received under chain of custody on Sepleurber 8, 2005. The samples were
received in good condition at ternperatures of 3.1"C, 3.1"C, 1.4"C,2.7"C,3.1"C and 5.7oC.
Due to a shipping error, the zubcontracting laboratory did not receive samples D5I080237-001
and 002 and only received partial sample volume fbr sample 003. Additional volume was
collected for these samples at a later date and they are logged in under a separate lot. The results
that are available for saurple 003 are reported since this sample was used as the batch MSA4SD
QC_
The results for all radiological analyses are included in this report and were pe'rforrned by STL
St. Iouis; 1,3715 Rider Trail North; Earth CiU; MO 63045,phone [phone].
Radiochemistry, Yarious Methods
The method 900.0 MOD gross beta MDA for sanrples D5I080237-003 through 007 was not met
due to reduction of sarnple size caused byhigh residual mass. The analytical rezults are rqrorted
with the MDA achiwed.
A low-level and a high-level LCS standard were anal;zed with total uranium batch 5262217 nd
they are spiked at different concentrations. Thereforg the RPD value reported for these two
standards does not apply. Both LCS rccoveries were in conhol.
The radium 226 andradium 228 MSA{SD were perfonned on sample D5I080237-003 and were
in conhol.
The gross beta MS/Ir{SD performed on sample D5I080237-003 dernonstrated recoveries below
tho control lrmit.
The total uranium MS performed on sample D5I080237-003 demonshated a recov€ry above the
control limit. The MSD was in contol.
The gross alpha MSA{SD performed on a sample from another client andlor lot was in confiol.
STL Denver
The isotopic thorium duplicates performed on sample D5I080237-006 wse in conhol. Note that
the RPD value reported for thorium 232 is calculated based on values below the reporting limit
and those valuqs do not apply.
STL Denver
o
o
METTIODSW
D5IO8A237
A}IAIYTTCAIJ PREPARATION
PARAIvIEIfER METIIOD METHOD
' Groes Alpha (COPRECIP) by GFPC sMlvw 7110 MOD
croaa Alpha/Beta by GFpe EpA 900.0 MoD EpA 9oo.o
Isot,oplc Thorlum by Alpha gpectroscopy EMIJ A-01-R ltoD
Radium-226 by GFPC EPA 903.0 MOD
Radiun-2z8 by GFPC EPA 904 MOD
Total UranLum By Laser Ph osphorlmeLry ASTII 5174-91
nef€re|oeea:
. ASIT.{ Arnual Book Of ASIIII Standarde.
EMfr'mwtnONpgUrAr,MEA8UREMEIiIT8 LABORATORY PROC$URES MANIIAIJi
HASL-3OO 28TH EDITTON, VOLT,ME I and II DEPARTIIENT OF ENERGY
' EPA TEASTERN ENVTRONMENTAL RADIATfON PACILIrY RADTOCHEMISTRY
PROCEDTRES IITANTUAIJi Ug EpA EpA s2Ols-84-OO5 AUGUST 1984
SMW}I TSTAI{DARD MET}IODS FOR WASTE qIATERN
STL Denver
MEIHOI} / AhIALYST
D5r080237
AI,IAIJYST
o
AIITAtYTTCAI,
IUETHOD
AI$AJrYST
ID
4423 50
060040
4 01- 527
40 0 697
400 697
40 1 527
ASIU 5L74-9L
EII/IL A-OI_R MOD
EPA 9OO. O MOD
EPA 903.0 MOD
EPA 904 }IOD
SMhIW 7L 10 rrIOD
ReferenccB:
ASTI{
EMIJ
EPA
SMI|fiiI
Mike Anderson
Rlronda Ridenhower
Jirruny Wllson
Ivan Vania
Ivan Vania
illmmy Wilson
Armual Book Of ASff'f Standards.
NEM/IRONME} TAIJ MEAST'REMENTS I'ABOR,AfORY PROCEDI}RES ITIIA}iIIIAI'"
IIASII-300 28lII EDITTOI{, VOIrtl{E I and II DEPARII.{ENI OP ENERGY
"E.ASTERN EI{wIRONMEI{ITAIT RADIATION FACIIrffg RADIOCHEI,IISTRY
PROCEDURES MAIi[]Ar-,r' US EpA EPA 52O / S-84 - 0 06 AUC}UST L9B4
''STAIiIDARD METHODS FOR WASTE $[ATER"o
STL Denver
SAIVIPI,EW
D5IO8s237
SAMPIJED SAMP
DATE TIMEwo#sAr{PLE#CI,IENT SAIVIPLE ID
H.T5GB 0 03
HJ6G9 00{
HJ6IIA O O 5
HJ6HC 006
Hir6HD AO7
NOITE (S) :
Gr9I-S1_-090705
GI{-S11-09070s
GIir-s2-0907as
GI{-53-O90705
c. w-N2-090705
a9/07los oe:55
as/ar/as 11:15
oe / o7 / os L2:20
ae/a7/os 1-3:00
oe/07/as L3:30
- Tho rrelyticrl rwrlo of tho ssrplo liged rbovc arc prcscDrcd on tho followim pa8cs.
- All calcDrslions rrc pcrformod bcfore rorrding ro ercid rorm<loff srrors ln cahalated rcirlts.
- Rfiil6 noted as 'ND'wefo not d€rc.tod st or rbovc rhe dat d lirDir,
- Thls rcpon mrei Doa bc rcDroduccd. cxccpr in full. withoul tbe wrlttr., approval of tbe hborerory-
- Rsults for the followinS psramcrcrs src ncvcr rcponc.l on e dry welght ba6ls: color, corosivlty, doslty, flaCrpoiu, iSDitrbtfity, llycrs. o<lor,
pdit filt r Ert, pH, porooity prssno, ro0ctivlry, r€dox potcnrial, specifrc gnvi:y, spor lc6ts, colirle. solubitity, tempersnlrc. viscosity, rnd wcighl
STL Denver
t RS Coqporatsi,on
Client Samle ID: G9[-S1-090705
Scvcrn Tr6nt Lrboratoriee - nr.diochmirtry
Lab Sarple ID:
Work Order:
Matrrj.x:
Prranrttr
D5r080237-003
HJ5G8
GW
Itrnrl't 0tral
|[otal-
Ilrrcrrrt -
(2 a+ I -l uDC
PrsD fnalyrlr
Drto IlEt. Urtoh t
Datre Collected: 09/07/05 0955
Date Received: A9 / 08/05 0930
rl.d t
GTROSS AID IY
Orotr B.tr
orPc EPt 900. o !,toD
LI,7
OcLlt 900. o uoD
a9 123 I 05 09 lzelo5 326606't
Totrl Urani.um
TotsrI Urr-Lun
bnr IcPt lEIt[ 517{-91
56-7
ug /1,317t-91
a9lzalo5 0912Ll05 52622L70.3
Rr-226 Br EP[-903. O [rOD
RrdLun (216) Z -3L 0.44
DCt/L
0 .31
903 .0 !iloD
09/09 la5 09/28/05 5252085 98
nr-228 BY orPc
Rrdl.rrrr 278
EPt 90{ ttroD
5 .13 o-87
nCLlr,
0 -91
90{ !iloD
09/09/05 09l28los 5252086 7l
Drta atr Luoqll,rtr vLtlouE tho clra nanrrt.Lvo.
ldc Ia dctrrrrlacd by rsttrnrrant Drrtormanco oD,ly.
Eold ruulte tre grGat.r thrn thc t{DC
STL Denver
IIRS CorporatLon
Cl,Lent SampLe ID: GII{-SlI.-090705
gewarn Trent Laboratorl.eg - RadLochguiatry
Lab Sample
lrlork Order:
Matrix:
?rrrnrtrr
D5r080237 -004
HJ6G9
GW
Rcnrl.t
Date CollecEed:
Date Received:
a9 / a7 / 05 111s
a9 / 08/0s 0930
furlyrl.r
Drtr
Strl
Uncctt.
(? o+l-l
Prrp
ILt.Bateh I
oRoSa I,,lB Br
Ororr llrtr
orPc EPn 900. o t{oD
390 1ao
*,Llrt
200
900. o DtoD
oel23lo5 ae l79lo5 5266067
troEel Unnl.un bL,
To:,r1 UrraLum
NPr .trssr al70-gL
1-20 0.11
u;slL
0.31
517t-91
a9120lo5 0elzt lo' 57622L7
ono88 A BY CO-PRECTP g!fl$I
Groos A1pha 0.4
7110 lrOD
U 1-1
sfi,L/t'
1.9
7110 ltOD
09 /23 / A5 09 /2s / Os s25608s
Rt-226 BY tPf-gO3.O ti[OD
Rrd,Lun (726) 1, 1?o.28
pcLlt
o.77
903, O INOD
o9lo9 lo5 09l"Blos 5252085
Rr-228 tY orPc
Rudl,ruu 7?8
rPr 90{ ![oD
L.77
pC.Lll.
o. g0
90{ ![oD
aglaglo, a9l28lo5 5252086
flrorl-un 23O
Thorlum 232
o -22
0-08
0.53
0.17
0 - L1
o.x7
0-16
09t76la3 09177 l05
a9 /26 / As A9 /27 / Os
5269393 79
s259393 79
ta
I,DC
Bold
J
gTL
(s)
aro Luoqllrtr rithotrt tbo cat. narratl"ve.
lr dctcrulncd br Lnrtnucat pcrfomanoo on1y-
rcrultr rrl grratrr thrn thc ttDC
Rcru1t k grcrtcr thin ranglla dctcst,los ltett but
mnBfefu lmg thu thr gtqllc dctootLoa thlt,.:...
B
Icra tbra ttrtcd reDortlag llrtE.
URg Coqporation
C1Lent, Samtrle fD: Gg[-S2-090705
Srvern trrerrt Laboratorieg - nadLoch@d-Btrlz
o
tab Sanple ID:
Work Order:
Matrl-x:
Paranrtu
D5r080237-005
H.J6HA
GW
Rrtul'ts
Date collected: 09 / A7 / A5 L22A
Date Received: A9 / 08/05 0930
TotrI
UEocrt.
Ouil (2 o+ 14 uDC
Drell lnrlyrlt
Drto Ibt. rrtoh t Yld a
onoEs ^lB BY
Gross Beta
orPc EPt 900.0 iloD
r.90 u
DCLIT.
200
900. o !@D
a9/23/A5 09/29/45 5265057
Total UranLun
fotr1 UrrrnLrrsr
lry XPl, Lgltrt 517{-91
25.2
ug llr 5174-91
o9t7aIo5 09lzt lo5 57622L7
oRogg l, BY co-PRtcIP gDrgw
Groeg Alpha O -97
7110 liOD
U
pcLlt 7110 lroD
a9 /23/05 09/25/As s25608s0,91 L.4
lll-7?6 Br EPA-903. O !ilOD
nadlun (226) 1.18 0.28
*LIL
0.21
903.0 MOD
aelaglos a9i28105
'.2,2085
93
Rl,-238 BI GFPC
Rrd,Luro ?,78
EPr 90{ ![OD
3,6C o-80
pcLlt,
o.95
90{ tiloD
o9lo9lo5 09 l78lo3 5?,32086 68
IoO TIIORITTU (8HORT
Thoriuru 230
Thorlum 212
C!r) DOE r-01-n ![OD
0 .21 iI
-0.031_ u
t,c,LIr,
o-15
0.15
A-01-R lloD
09126' tos 09127 I A5
09 /261Os 09 /27 / 05
5269393 90
s259393 90
oo.16
0-071
NO|E (s)
Dcta rro Lnoqllrto rl,thout thr cata n.'trrtlwc.
!@c 1g drtrnuLncd by LnrtnrnrnE Dcrfomrno. oa.ly-
Eold rtrulta LrG grtrtu tban tho tsC
rf Rcrult tt grcltor thrn tarE>Ic dctscstl.on ltmtt but
GTL OanUeLf lrrr then thc raryrlc dctcctLoa l!.el,r.
Icr; thtr rtrt,rd rrDortlng lf,nlt.
URS Corporation
C1lent Samole ID: GI[-S3-090705
Severn Trent, Laboratorlcr - nadiochanl,stry
Lab Sample fD;
Work order:
Matrix:
Prrrnlter
Dsr 0802 37 - 006
HJSHC
G'W
lrrul.t QurI
DaEe Collected:
Date Reeeived;
lfotrI
Unrrarf,.
(2 o+ I -l ilDC
a9/07 /0s 1-300
0e / 08/0s 0930
grrrp l.urlyrl.r
Drt. Ilrtr Batch I YId tr
G}ROAS AIB- BY
Grorr Bcta
oFPe EPl' 900 - o DIOD
l8
pcL/L
7L 31
900. 0 DtoD
o9t23to5 o9t79loa 3265067
Tot,al UrrnLum
Totrl Urr.ul,rgn
br KPA trAlIU 3174-9L
{. go o.50
ug lT'
0.31
5174-91
091701a5 09 lzlla5 52622.L7
GIROss T E:r CO-PRECTP glilHW TLLA }IOD
Glrorr llpbr 3 .82 o. g9g
*Ltr.
o.67
7110 lcOD
os tztto' og t25 /05 5266085
Rl,-226 lI trPA-903.0 HoD
RrdLum (226) 0.57 o.21
gc.LlL
o.23
903. O !@D
o9lo9 los a9l?Blas 52s2085 82
R.lr'-778 Br grPc
nadl,un 278
EPtr 90{ IIOD
2 .13
D,CL/L 901 !!oD
o9lo9lo5 a9t28lo3 5252085
ro .:[HORIU![ (AHORT ef) DOE .1,-01-R !ilOD
0. 81
o .20
0-088
p,cllT.l-01-R HOD
09t26lo5 ael27 l05
09/26/05 09 /21 /45
50
526939! 59
52693 93 69
ThorLtur 23O
Thorir:rn 232
a.z7
-0 - 014
J
u
o.20
0 .20
ire loooqDleto rl.tbout tLo oarr srrrrtl.vr.
l.DC lr dttrmlacd by Lngtruraot Dcrtormaaco ouly.
Bold ratultr trc gEcator thu tbo UDC
J Rcru1t Lr grrutor thfr tarqllc dctc*lon tl"ntt, but
GTL il)Afltf€lf lom theu bhc rargllc dctcotlou llnLt-10
lcrr thtn ;trtrd reportlng llnlt.
IIR$ CorDoratLon
C1Lent Samrpl-e fD: GIfiiI-S3-090705 DUP
flrvor:rr Trcnt Laboratorieg RrdLochml,tt,ry
r,ab .sanple rD: D5f080237-005X
Work Order: HJSHC
Matrix: GTil
Dararttor Rorrel.t gurl
Date Collected:
Date Recelved:
a9/07 /45 1300
09 / 0Bl0s 0930
TotrI
Ilnocrt -
l7 a+l-l
PraD
Deto
lulyrlr
Drtr Brtoh I
rlo Tlro&rm[ (sHoRT
lttorl.rm, 230
ffrorir:m 232
(Ir) DoE A-01-R rioD
a-27 il
0-01-4 u
.L-01-B lroD
a9 n6l0s 09177 I a3
09126/A5 Ae/27/45
s269393 68
5269t93 68
pci/L
o.20
o.079
o-17
0-17
NOTE (8)
Dtta tra. lDoqrlat. rlthot tha caa. urrrtiu.
llDre ti dotrtaLaod byr l.artnaoat prrlonlaol ouly.
Eoldl rrrultr u. grr.rt.r thrn Eh. EC
J f,.rlflt f,r gr.rtor tht! rqrlc datactloD ltLlt bEt ler. thea .trt.d rq>ortlug lr-Dlt.
gTL IDeIlV€l!'I... !b.o tbo rnplo d.r.oEloE thlr.11
IrR.g CorryroraEion
Client, Samtrle ID: GW-N2-09O705
Savcrnr Trant Iraboratorieg - RrdLochmLBtrlr
Lab Saruple ID:
Work Order:
Matrix:
Parenrtrr
D5r080237-007
HJ6HD
Gt'I
Rrnrtt
rotal
fholrt.
Sral (2 o+/-) HDC
DateCollected: 09/07/A5 1330
Date Received: A9 / AB/ 05 0930
PnP
htr
rnrlyrlr
Drtr fatafr *rlA t
ORO88 ,,,IB BY
Oross tctt
grPc EPl, 900. o tiloD
102
Dc.LlL 900. o uoD
as /23lo5 a9 ng la' s26505765
ToLal Uran:lun by
Totrl Urraturn
KPf, }gm{ 5L7 {-9L
2.86 o.30
ugl\'
0 .31
JLTl-91
oe lzo I 03 a9 nt I as ,.762.2L7
gRogg n BY co-PRtcIP EtffiW 7110 toD
Orotg ^l,I.pba 4.6
Dct/L ?110 t@D
oelztlos 09lzslo5 52660851.3
nL-226 BX EPL-903, O D@D
fadl.um (226) 0-62 o -20
DcLlr'
0-18 o9/o9/o5 a9l78l03 525e085 9a
Rf,-228 Br SFPC
Rrd'iun 728
EPL 90a DIOD
2.39 o.61
$Llr,
o.7g
90{ lmD
09t09l05 09l?ela5 5252086 77
Io TIIORIT,U (gEoRT CT, DOr .l.-Ol-R HOD DCUL r-01-R lroD
09176l05 oe177 lot
09 /26 /Os A9 /27 /05
5t69393 8{
5?69393 g4
tborlun 230
Thorir:m 232
o.15
0 .001
il
U
o.13
0. 064
o. x.e
0. 14
(s)
frG l,uc-Dl.t. ultbouE tLr caro narrctrvr.
ilDc lr dttrrnlnod by lrrtnrrtruB Dcrlormanoc ouly.
BoId rrault,; Bre grlftcr tbf,,tr th6 I'IDC
if Rlrnrlt lg Trlrtrr tbrn .;'pElr drtrotlon t{r'rlt, trut
6TL DCrnVelI lur bhrE thr rrrsrb drtcctLon Linlt.t2
Ictr tbrn rtrtrd rrportlng }l.ml-t,
0cDATAASSmW
D5rO8A2t7
Sample PreparaEion and Analysis Control Numbere
SAI.{PIrE#II,IATRIX
003
oo{
oo5
oo6
GI{
GW
Gt{
gri
GW
GIII
GW
GTII
GT{
GW
GW
GW
GW
GW
GW
GW
AI{ATJYTICAIJ
METHOD
EPA 9OO. O FIOD
ASTITT 5L74-91
EPA 903 ,0 I.,IOD
EPA 904 MOD
EPA 9OO. O MOD
ASIT,I 5L7 4 -91
sMhrw 7110 MOD
EPA 903 .0 IrIOD
EPA 904 MOD
EMt A-01-R !,!OD
EPA 900. 0 It0D
ASTM 5L74-91
SM[,W0 7110 l,tOD
EPA 903 .0 lvt0D
EPA 904 I.,IOD
EML A-01-R MOD
EPA 9OO-O MOD
ASTM 5L7 4.9I.
gMrm 7110 t.toD
BPA 903.O MOD
EPA 904 MOD
EML A-01-R }[OD
EPA 9OO. O MOD
A.STM 5L74-91
gllrr{w 7110 MOD
EPA 903. O MOD
EPA 904 T,IOD
EI{L A-01-R MOD
IJEACH
BATCH #
PREP
BATCH #
5266057
52622L7
5252085
s2s2 085
s266067
s2622L7
5265 085
5252 08 5
5252085
525 93 93
5266067
52622L7
s265085
5252085
5252086
52693 93
5266467
52622L7
s265 08 5
s25208s
52s2A86
526 93 93
s266A67
s2622L7
5255085
szs2085
s252085
52593 93
MS RT'N#
5266L04
5262ts6
52s2034
s252 03 3
s266 1 04
s262L56
52561-03
525 2A34
5252033
s269296
s25 dLO4
52621s6
s256L03
52s2034
s2s2a33
5269296
5265 r. O4
52521s6
5266 r.03
s252434
s2s2 033
52692e6
s266 1 04
s262L56
s265 103
s2s2034
5252 03 3
5269296
o
007
GW
GW
GT{
GW
GUI
GUr
GW
GW
GW
clw
GW
GW
O
STL Denver 13
o
ClienE Lotr rD:
Matrix:
!ilETHOD BIJTDIK
gevera Trent LrboratorJ.cr
D5r080237
IAIATER
REPORT
- Radlochml;try
ncrrrrl.t Qurl
lPotal,
Irno.lt'.
(2 o+/-)
IraL Bary>lo II)
Prap lorlyrl.r
Drtso hto Batch I YId tDrnnrtrr
nn-228 By Glf,Pc
Radirrm 228
IEPI, 9 O{ IOOD
0_1
*Llrr
0 .42
90{ troD
0_70
r5r090000-0858
09 / 09 /os a9 /28105 5252086 80
Rt-226 BY EPI.-9O3. O llOD
Radlum t226) 0. 0 0.0
Dci/r,903. O UOD
0.3
r5rO90000-08slr
09/09ta5 a9/28t05 5252085 104
OBOSE A BT CO-PRI'CTP
Groee Alpha 0.0
s!fiflw 7110 [fi)D
u
Dc!-lL
0_16
7110 lroD
0.49
r5r230000-o85n
0e /23 / 0s a9 / 25 /a5 5266085
oRogg f,/B Br orBc IrPt
Gross Bota -0.l-11
900 - 0 t|on
U
NE,LII,
0. s3
900,0 ![oD
4.97
,5r230000-06-78
as /23 / os a9 /29 /o5 5266067
Totsal UranLurn bg,
1 Uranium
IsPr, rflrxr 5174-91
-0_021L u
rto !I'HO&[UX (SIIORT C"r) IIOE .L-01-R DIOD
Thorlum 230 O, 0-9 U
Thorfuur 232 0 - 08 U
ug lr'
0 . 0023
Ef.LIL
0-14
0.10
3L7 {-91
0.31
^n-o1-R uoD
0-20
0.13
15r190000-2178
09 / 2A / 05 09 / 21. I 05 5262277
15r360000-3938
a9 /26/ A5 09 /27 t 05 5269393 9L
09/26/Os Aet27/05 526e393 9L
(8)
rra taoqllcto rlthotrt thr our n+*.-atlva.
l[}C Lr dotrrulucd url-ngr lntBnrmrut D.rf,ormtBor
BoId rorultl LrG grroa,tc thu tbc DlDc
U Rrtult 1r hrr thrn tbc tar$rlc dctcetLonSTL Denver
only
lfurdt.l4
: Lalroratoaaz Cootrol, Sanple Report
S6\roro, trcrlt Labratoricr - Badiochc,,,l ,try
cLienr Lor rD: D5I080237
ll[atiixs WATER
rotal
lhoert.
Ldc 8rql1r fD
QC Coutrol'
Perrmctrr SDl.L r@t B..rrlt (Za+l-l MDC t tltd i B.a r,jhlt.
Rn-?26 DY EPJI,-903.0 tfioD
Radlum 1226 ) 1l -2 Ll .2
Drtsoh lr 5252085
pci/r, 9o3. o uoD r5r090000-085c
1.3 A.2 100 100 (54 136)
.lnrIyrl.r Drert 09 /28f A5
RA-228 BY CIFPC EPr' 90{ DDD
Radlum 228 5 -25 5.66
Batch lr 5252086
pet/L 90{ ![oD Psr090000-086C
0-84 0.72 79 108 (55 L47l
lanl'yr.l: Dit.t 09 / 2g I 05
GrROgg ^lD BY OrPC fPl, goo. O MOD pCf /f 9OO. O trlOD
4.4 LGroes Beta
r5r230000-o67c
7e t70 L27l52.3 41-1
Drteb lr 5266067 la.rlyrtr Dat.r 09 /29 / A5
OnoaS I BY eO-PRtcrP SillW 7110 lrOD D,€LIL 7110 t6D !5I23OOOO-085C
cros$ ALpha 20-6 20.0 2.5 0.5 97 (71 - 143) ,
Ertol lr 5256085 ..lanJ.y.l. Drtor O9/ZS|O5
rro THoRTUI (ABORT CT] DOE f,-Ol.-R lr)D rcllt l-Ol.-R ilOD !5I26OOOO-393C
Thorlum 228 8.81 9.5 1.2 0.1 92 108 (91 - 132)
Thorlum 230
Thorium 232
9.46 7.7
8-82 9.6
Batoh lr 5269393
l-.0 0.06 92 82 (55 t29l
L-2 0.09 92 108 (88 133)
r;nal.y.cll Drcor 09 /27 / Os
r[c]lrE (s)
STljt8ehfvgqrrrfnra tdl llrEntDEt pcrfcrrnoo m\r 15Crlotrltld.a ero Dorlorr{l brtorr rorpAlag to rvold rsuld-off aEror h crlsulrtra r.atllta
LraboratorT Com,trol Sa4llc/LCS lluplieate Rcport
Srvcru Trrat LaboratorLeo - Badl-ochoigt4,
CLient Lot ID:
IvIatrl"x;
Prrurtcr
D5IOBO23-I
WATER
Cpth. .Dnount Rcnrj.t
Total
Ulo.rt.
12o*l-) trl'd BRes
I.rb Arqrh ID
QC Coatrol
Lr-utt; Drcol'rl'o
trotrl Uranl,un, Uf KPt
Total UranLr:m
Spk 2
t.g1lH 5L7 4-9L
40-0 38-28.00 B.Z7
Brtoh tr 5?-62277
ulf,lL 317r-91 r5r190000-2L7e
(90 7L2)
(90 I'LZI L?9 SRPD
09 /2L / 05
4.5
0. 85
96
103
ror.lyrlr Di,tc r
o
HC4tr ( g)
_
1bSffrCSgh#Ef rrr Dorlornd belorr rondl.ngr to arrold rmnd-olf rrror Is oeJ.ouhtrd a..ult.
Client Lot fD:
Mat,rix:
Prnntsr
MATR:EX
flewcrtr
Ds r 080 237
GW
SptJgr
tosrat
AC 8rryrlr rD
t Ytd tB.o OC Coatrol
LLnltr
SPTKE/ML]rRIX SPTKE
Trcnt l,aboratorict
DT'PLIEILTE REPORT
- nadLoch.mirtry
Datre Saurpled: A9 / 07 / 05
Date Received; 09/08/05
0955
0930
BDIIG
trorrrlt
TotrI
UDgtft,.
lZ o+l-l
SIltDIlE
Ilolrlt
:[otal
flbocrt.
(2o +l-l
8ptL.
Yld
oRoSg r/B
Gross Beta
BY orPc EPl' 900.0
3480
Spk2 3480
D,,cL/r,
200
200
rnalyrLr
900. o ![oD DSrOE 0237 -003
1770 a
- L770 a
tr 5265104
1,52
L52
drte r
45
45
09 /29 / 05
a (50
a (50
1s0 )
1s0 )
4,6
46
Prclr.lonr 0.06 tRPD
Batolr
Totrl Urrnirrm W IIPI'
Total Uranlum
SPk2
.t,8lEil 5
40. 0
{0. 0
Batch
110 &
98
lr 5262156
ug/r,
13
l2
lralfraLt
5L7 l-91
56 -7
56.7
drtc r
5.8
6.8
09 /2L / A5
D5rO8A237 -O03
1.32 a (90
103 (90
11-2)
L\21
Preo:lrLom.r 11 IRPD
Rl,-226 DI EPI-9O3 - O ttOD
Radium (2261 10 - I
Spk2 t 0. 8
rct/r, 903.0 troD
L.7 90 2 .5L
L .5 93 2.57
Dsr08 A"37 -OO3
L4 -9
13.8
Batoh lr 525203{
o -44
0 .4{
98 L15
98 LO4
Prcoigl.or I IRPD
(66
166
1s0 ),'L
tnalyrLr datcr 09 /28/A5
Rt-228 BY
Radium 228
otrPe tPI' 90{ uoD
5 .06
spkz 5. 0g
rrC,L/t'
L.4 6g
1-5 57
tra,lyaLr
90{ DloD
5. L3
5. L3
drtc r
D5XO8 o.?37 - OO3
10. g
11 .9
5252A33
0. 87
0-87
74 11d
74 133
(62
(62
150 )
150 )
Dreol.rLoar 9 tRPD
lrtoh, 3r 09 /28/05
oRo8g f, BI
Gross Alpha
eo-PnEcrP guww
4L -2
Spkz aL.z
Dcl/r,
5,8
4.7
.f,arlfrll'r
7110 DIOD
3-2
3-2
1-1
1-1
D5r130187 -O03
101
83
(s0
(s0
1so )
1s0 )
44.7
37 .7
s2661.03
Prcotrloar 1-8 tRPD
Ertol lr drtor 09 /25/A5
NOTE(8}
tt ulthorrt thr car.
Calcrrlatl.onr ar. rrorforud bofore roundlag
STL Denver
l SptIrrA en^al1t,c outrlda of rtatcd,
Eo rvold rsuad-off uror lo oalculatrd rrlultsa
AC LLnItr.
C1ient LoE fD:
MatrrLx:
Prrurtrr
Severu
D5r080237
WATER
DT,PLICATE EIr}LUTTION REPORT
Trcnt lraboratories - Redtochsllrtry
Date Sampled: 09/07/45
Date Received: 09 / 08/05
STUPIiE
Rrcrr,lt
Totrl
Uloort.
(2o +l-l
DUDIJCATE
t rld Rtnrlt
IotaI'
lfboc*.
(2 o+l-|r rla
AC Oaryrlc ID
P-roLrLm
Igo TIIORIT,U
Thorlum 23O
Thorium 232
(sEoRT Cr) DOE t-01-R !!OD
l;il,- J l:ll,
ratoh lr 5269393
*Llt
69
69
( Sample )
.1,-01-R D[oD
a.77 J 0.20
0-01,4 u 0.079
5269393 (Dr:pl.icaue)
68
58
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0.3 IRPD
3030 $RPD
o
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Calcrulrtlona onl Darforcrrd brforr rorrndl,ng to ovold rotrad-off
Stl Stsfil. la srrcatcr thu mryr1c dotcctlon llntt, Inrt-f - -nfuYtefr lrrr tbru tho rrnph dotoctlou ll,al,t.
rrror Ln calsulatrd rrrultr
lca; tshrn ttsltsrd r:IPrtlng ]{rn{3.
1B
STL Denver
Sarnple Receiving Checklist
,rrr, ..05j,r0tra,$+ Date/rime *"***, ilfry'u orr, (D
Company Narne & Sampling Site:
PM to Coruplete This Section: Yes
Rcsidual chlorine check required:tr
Quote#: 4+ct$,
Specinl Instructions:
No
X Quarantined :
Yes
tr V"
Tirnc Zone:
. EDT/EST . CDT/CST 'MDTA4ST. PDTIPST . OTFIER
Unpacking Checks:
Cooler #(s): fFTemperatures("C): -,1 3,I
3V--Tr rt f, I -s'. >
{Z -_s'
Cool6r seals intact? (N/A if hand delivered) If no. document on CLIR.
Chaiu of cusbdypreseut? Ifno, document on CIJR.
Bottles brokea and/or arc lcaling? Ifyes, docu:ncnt on CLIR
Multiphasic sarylcs obvious? If yes, docr"ureut on CIJR.
Proper container & preservatives used? (ref. Attachrnent D of SOP# DEN-QA-0003) If no, docrxneut on CLIR
pH of all sarryles checked and meet requiremcnB? If no, document ou CLIR.
Sufficicnt volume provided for all a.allsis requested? (ref- Anacbment D of SOP# DEN-QA-0003) If no,
document on CUR, and cbutactP.M bcfore proceeding.
Did chain of custody agree with labels lD and samples received? If no, document ou CUR.
Were VOA saryles without headspacc? If no, document on CUR-
Were VOA vials preserved? Prcservative QHCI D4t2"C trSodium Thiosulfate O Ascorbic Acid
Did sryles reguire preservation with sodjum thiosulfate?
If yes to #11, did the samples contain rcsidual chlorine? If yes, document on CUR.
Sediment present in dissolved/filtered bottles? If yes, document on CUR.
is sufiicient volume provided for client reque$ed MS, MSD or mahix duplicates? If m, document on CII& and
contact PM before procecding.
Receipt date(s1> 48 hours past the collection date(s)? if yes, notify PA/Ptvl"
Are analyses with short holding times requested?
Was a quick Turn fuound.(TAT) requested?
N/A Yes No
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STL Denver
Sample Receiving Checklist
u,*e{f,l\AJ.it-
Login Chccks:
NlA )'cs Ntt
{ U 18, Sufficicnt rtlurneprovided for all anatl,sis regucfled? (ref. Auacluncnt D of SOP# DEN-QA-0003)
documenl on Clllt and contacl PM beforc procceding-
D ,g D 19- ls suflicicnt volumr provided for clicnt regucstcd NrS, I,ISD or matrix duplicares't lf no, documcnr on C[JR, and
contacl Plv! bafore proceeding.
tr 20 Did the chain ofcusrody indudes "rcccived b)r' and 'reliuquished" by signalures, dateq and rimcs?
D 2I. Wcrc spccial log in instructions rcad and followed?
O 22. Werc AF-CEE mculs Iogged {or rcftigerde.dstoragc?
fl 23. Wcre rests loged chccked against tbc OC? tfl,hich samplcs werc conlirrned.? I
-
! 24. Was a Rush form corrplcred for guick TAT?
tr 25. \l,as a ShonHoldform corrp)etcd foranyshrrt holds?
/ zo. Is "suic,ICoC'required?
6 ,r - Wc,re spccial archiving instructions indicated il trc Geoeral Conrrnmts? lf so, u,har werc the5,?
beling and Stomge Checks:
! 28. Was the nrbcontact COC si$ed and sent witb smples ro bottje prcp?
D 29- Wcre sanplclabels douhle-checkcd by a second person?
5 30- Were sarrylebottlcs aud COC double cbccked for dissolved/filtered mculs by a second person?
! 31. Did tbe suryle ID, Date, and Time frorn label Datcb utat wts logcd?
tr 32. Wcre sticlicrs for spccial archiving insruaions aA"ucd to each box and to tbe ICOC? Sce #27
tr 33. R ere AFCEErnctals sorcd refrigcrated?
3 34. Were "Stid ICOC- copies given to salellite storagc areas?
Documenl anyproblems or discrepancies and the actions talien to resolve them on a Condition Upon Receipl Anomaly
Reporl (CL[R).
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STL Denver
4955 Yarrow Street
Arvada, CO 80002
Tel: [phone]
www.stl-inc.com
STL
303 431 7t7l
ANALYTICAL REPORT
Western Zirconium Proj ect
Lot #: D5J074274
Sheri O'Connor
URS Corporation
8l 8l East Tufts Avenue,
Denver, CO 8An7
STL DENVER
fu2
Linda L. Benkers
Project Manager
Octob er 27 ,2005
Severn Trent Laboratories, lnc.
Table Of Contents
Standard Del ive rabl es with S u pportt ng Doc umentati on
Report Contents
Standard Dellverables
(fnn Cover Letter und the Report Cover page are considered integral
parts of this Standard Deltverable package. This re.port is incomplete
unless all pages indicated in this Table of Contents are included.)
. Table of Contentso Case Narrative
o Executive Summary - Detectlon Highlights
o Methods Summary
o Method/Analyst Surnrnary
. Lot Sample Sunrmary
o Analytical Results
e QC Data Association Summary
o QC Sarnple Results
o Chain-of-Custody
Su pporti ng Docu me nttatt on
(Note: A one-pag,e "Description oJ Supporting Documentotion" fs
provided at the beglnning of this section.).
. Volatile GClt\{S
o Semivolatile GC/MS
r Volatile GC
r Semivolatile GC
r LCIUIS or HPLC
r Metrls
r 0enoral Chemi$try
o Radiochemistry
r Subcontracted Data
Number of Pages
Check below when
supportlng
documentation is
presenL
nnnnn
nm
STL Denver
Case Narrative
DsJ070274
With exceptions noted as flagp or footnotes, standard analytical protocols were followed in the
analysis of the sarnples and no proble,ms were encountered or anomalies obsenred. All laboratory
qualrty oontol samples au^lyzed in conjunction with the samples in this project were within
established confiol limits, with any exceptions noted.
The test results presented in this repo,rt meet all requirements of NEI-AC, and any exceptions are
noted. This report shall not be reproduced, except in full, without written permission ftom the
laboratory.
Sample Recclving
Three samples were received under chain of anstody on October 7,2005- The samples were
received in good condition at tenrperatures of 3.1"C and 4.1"C.
Please note that this lot represents a resampling event for samples that were not received at the
subcontracting laboratory due to shipping error on September 8, 2005. Please refer to the
narrative for report D5I080237 for additional informatiou-
The results for all radiological anallaes are included in this report and were performed by STL
St. Louis; 13715 Rider Trail NortL Earth City; MO 63M5, phone [phone].
Radiochemistry, Varlous Methods
The metlrod 900.0 MOD gross beta MDA for samples D5JA70Z74-001 through @3 was not met
due to reduction of sample size caused byhigh residual mass. The analytical results are reported
with the MDA achieved.
Samples D51070274-001 through 003 were analped at dilutions for total uranium due to matix
interference. The reporting limits are adjusted accordingly.
A low-level and a high-lcvel LCS standard were anallzed with total uranium batch 5297707 nd
they are spiked at differe,nt concentrations. Therefore, the RPD value reported for these two
standards does not apply- Both LCS reooveries we,re in conkol.
The gross alpha MS/IIISD performed on sample D5JA7027+001 demonsfiated a relative p€rcant
difference (RPD) above the control limit. The MS/I{SD recoveries were in control.
TXe Soss betq radium 220, mdiun 22E, thorium 230 and thorium 212 MS/lvlSD Wrformd on
sample Dil07A27+002 were in conhol.
The total nranium MS/}VISD performed on sarrple D5107027+002 demonstrated roooveries
below the conhol limit.
STL Denver
METHODSSM
DsJO"0274
PARAMETER
AI{IALYTTCAL
METHOD
PREPARATION
MEIHOD
Grose Alpha (COPRECTP) by
Grose A1pha /r,eta by GFPC
Isotopic Thorium by Alpha
Radl-um -226 by GFPC
Radium-z2B by GFPC
Total Uranlum By Lraser Ph
Referenc€B:
GFPC
Spectroscopy
osphorimetry
sM}fi{ 7110 MOD
EPA 9OO. O MOD
EMIr A- Ol-R MOD
EPA 903 .0 MOD
EPA 904 MOD
AST1,1 5L74-9L
EPA 900. o
ASTT,I
EML
EPA
SM9UW
Annual Book Of ASII'I Standarde.
TENVIRONMEITTAL MEASURB{ET{TS I.ABOR,ATORY PROCE"DI'RES MANUAIJT
IIASL-300 28TtI EDITION, VOLUME I and II DEPARIIIEIirT OF ENERGY
'] EAS:rERN EIWTRONMEI{ TAIJ RADIATION FACIT'TTY RADTOCHEMISTRY
PROCEDT}RES IVIANUAITM t'S EPA EPA 52O/5-84-OO5 AUGUST L984
NSTAIVDARD METHODS FOR I{A.STE WATERI'
Denver
AI{AIJYTICA]J
IV1ETHOD
METHOD/ANALYSTW
D5JO7o274
ANAIJYST
ASTII{ 5L74-91
EI{IJ A-01-R MOD
EPA 9OO. O MOD
EPA 903.0 MOD
EPA 904 MOD
sMww 7LL0 IroD
Refereneeg;
ASTM
EMIJ
EPA
sMww
Mike Anderson
'Jimmy wilson
Ivan VanLa
Iva-rr Vania
fvan Vanla
fval Vania
AI{AITYST
ID
4023 5 0
401527
400697
400697
400697
400597
Arurual Book of ASTI{ Standards.
,ENVIRONMENTAL MEASIIREMENTS ITILBORATORY PROCEDITRES MAIIIUALT
HASL-300 28TII EDfTfON, VOIJUME I and II DEPARTT{EMr OF ENERGY
t' EASTERN EMIRONTIENrAL RADIArION FAC f LTTY RADIOCHEMISTRY
pRocEDURES NIANUAI,tr US EpA EpA 52O / S-84 - 006 AUGUST 1984
'ISTANDARD METHODS FOR WASTE WATER"
STL Denver
sffiw
D5JO70274
wo#SA},IPLE# CIJIEIVT $}tr1P1,g ID
SAITIPITED SAI{P
DATE TIME
HLgKG OO1
HLgICK O 02
HLgKL OO3
riurE (8) :
GW-S9L - 100505
cw-sL-100605
GW- S1-0 - r005 0s
Lo/06/as o8:oo
tola6/os 11:oo
Lo/06/os L2z4o
- Tbo rnatJrticsl rc$lts of Ol3 sErl[lteg ligtsl abovc arc Jrrcscntcd on thc fotlowirg pagc6-
- All cahulariorrs are performcd bcforc roundin6 o :void round-ofr errors i, catcuLt€{ resul6,
- Retr lt! notcd as 'ND" wcre nol d*arr{ $ or abovc drc srar€d limil
- Thh rcpon nrust not bc rcproducod, excopt in full, without rhe wdtta epproul of dre laboraory.
- Reeults fo, dlc folloviag poraruers arc rrvcr rcporod on a dry wcigh basis: color, conosiviry. densiry, flrshpolru, ignitabilily, hycrs, odor,
paim fil&r tcsl, pH, porosity prcssurc, reacdvlty. rcttor potratirl, ryccifrc gnvity, gor tcss, solids. vrtubitity, tcxnpcratuE, viscosity, aftf wethL
STL Denver
t RS Cor:poration
Client SarcIe ID: G[il-S91-100505
$evera Trent lraboratorLes r RadLoch@l,stry
Lab Sanqll-e rD;
work Order:
t"tat,rLx:
ParD+?tsor
D5J07 027 4- 001
HL9KG
GW
Rotult
Date Collected:
Date Received:
Total
Uaclrt.
(Z o+ I -) UDe
LA / A6 / A5 0800
1A/07 /05 0930
Pr.D .lr,a1yri;
rltr Dete Drtoh *Y].A ej
Gno88 e.lB By
Glroer Bctr
(}FPC tPrr 900.0 DilOD
340
PCt/r,
59 .9
900. 0 ltloD
10/08/05 10/11 la' 5281039
lfotal Uraniun
Totr1 Uruelum
by KPt A8IU ilT i-91
96
ag ll)5L7 {-91
L9 l25l05 LO126 I 05 52977A70-6
RL-326 BY tPl-g 03 - O !@D
RrCl.un 1?76) 3.30 0.54
pCLll'
0.33
903 - O DIOD
10/10/05 LOlz5l05 5283108 98
Rr-228 BY OtrPC
nad.Lun 2,28
EPT 9OT DIOD
6.6
Pci/L 90e uoD
LOILO|AS LAlTslOs s2831090.9 TO
Iso THORIIIU (SHORT ef) DOE l-01-R l@D
Uc::iH lli ?;'1, u
0-33
a .22
Dcl/L
0-46
0.49
r-01-R uoD
1-0/1.9/A5 L0/20/05
L0/'t9/a5 7A/20i05
52923 88 3l_
52923 BB 3l-
GrRoag t, BI co-DREcrp sldlH 7110 DtoD
Oroeg .[.I'phr 1{.{
rlcl-/L 7110 DIOD
aolaBlos laltelas s291293
te ara Lnoqllotr wl,tbout tbr cara arrratslve.
DIDC ig dotorminrd by l,utnmont Derformrnor oaly.
EoId rorulto ar. gx.rt,cr tban Eho UDC
u Rerult tt ltts thrn thr trmplc dcttotl,on llnl.t.
STL Denver
t RS Corporation
Client, Samnle ID: GI{-91-100505
Severrr Trcnt LaboratorLcg - nadLochmJ.stry
Lab Saq>Ie fD:
Work Order:
Mat,rix:
Paranrter
D5J07 027 4-0A2
HLgKK
GW
Itrrrr].t
Date Colleeted.:
Datre Received:
L0/06/0s 1100
L0/a7 /os 0930
Prep lna1yrLt
Drtc Drtr Drtoh *
rotal
I}bclrt.
(Z o+/-l
sRogg r,IB.
Gror; Ertr
BY GlrPC EP} 9OO. O DIOD
356
DCLIT,900. o l[oD
10108/05 tolLLlos s281039
rotrl Uranlum by KP}' .tr81!f 5171-91
Totel UranLum 91
!o;glI",517{-91
LOt"5l03 tOl26105 5297707o-6
R.l,-225 BY EP -903. O IIIOD
Brdlun (2251 2 -79 0.50
scLlL
0.31
903 - O UOD
10/10/05 LAlzSlAs 5283108
NA-E28 BY OFPC
Rrdlrun ?,28
EPr 90{ !{OD
6.09 o.90
i,c,LI!.
o -76
90{ lroD
LOtLAtAs LAlz'lO' 5283109
Ito trrroRrlrM (gHoRr cT) rloE .tr-01-R D[oD tCL lt L-O1-R !ilClD
ftorluJr 23O 0-69 3 o.27 o.1a talr,gtos tol?o|o' 519238a e9 --.
"horir.m 232 0.077 u 0.096 0.72 LO/LI/A5 7O/20/o5 s2s2388 89 I
clRoas l BY CO-PRECIP g!0m 7110 tfioD Dci /Ir 7110 MOD
10/t0l05 LOla9lOS 52e12e3Oroes Ll'phr 97
NOrE (s)
DaEa rro lncqptetc rLthOut the cara nartrtLve.
uDc Lr drltorainod by l.nrtrrnrcnt, prrformeaoc onry.Bold rtrulto ar. grcltor thrn thc pC
ir r.crulE lr grrcrt,.r tlrrq ;rry>ro dotoctlon lt-ntB but
U___ Ruult ir lcra thrn thc srtrtrrh dctoctsLon lLnl_t-STL Denver-
lorr therr atetod rolrortlng ll.rrlt.
URS Cort>oration
Cl.ient Samolc ID: GIfil-S1O-100505
Scvgrn, Tren,t Laboratorl,es Rld,LochsliBtrlr
Lab Sample ID:
Work order:
Matrix:
Parunrter
D5J0707.74-003
HL9KL
GW
Rrrult
Date Col-IecEed:
Date Received:
r0 / 06 / a5 124A
1A/07 /Os 0930
PrcA lnrlyrit
DaEc Drte Brtoh I
Total
lhcort.
(7 a+l-l YI'a i
eno88 I.lB
Grorr Brtr
BY GITDC EPl' 9OO. O MOD
85
D,cL lr,900.0 !iloD
LOtOstAs LO/LLIA' 528103911
rotal Urarirur
Total Urralun
b1t KPl, l8lm{ 517O-91
o. 353 ir o. o37
ug lt'
0.31
517r-91
LOllslaS LO176lA3 3297707
Rr-226 lY EPt-go3-o t{oD
Raditm (226) 1. 07 o -27
pct/r,
o.2?
903 - O IIIOD
LAILAIOS LOl25lO5 5283ro8 98
Rt-228 BY Grgc
Radir:m 228
EP} gOC !ilOD
0.45 0.51
gCLlt
0. 84
904 lnOD
1.0/L0/45 La/25/05 5283109 87
Igo lrEoR]rtru (sHoRT C?) DOE l-01-R tlOD
JC:iil;ti t:ii, u
0 .16
0-059
I,,cLlt
0.13
0.10
l,-01-R ![oD
LOtL9lAs AAtzolOs
70 t1,9 / 05 LO /2A / 05
5292388 89
5292388 89
oRo8s t. BY CO-PnE|CIP S!ilwtf
GEort rl.gha Z.7O
7110 MOD
J 0 ,87
ecilL
0.76
7110 MOD
L0118/05 LAlI.elOs 5291293
Drta .ac lacqrl,.te rtthoot tbc or.. anrrrtl,vr.
pe lr dotetrluod by Lartrrurrat pcrfOr::oaaco oal,y.
Bo1d, rc.uIt. ..rG gr.tt.E tha tb. XDC
I R.tult {r lrrootcr tbra rarElc dotootlon lt rlt but ]'.ra thr.D rtatcd roDortLlg lLult.
"Sfl n,DEiVir I'crr rbrn tbc 'rqrl. dorcottou lt-rtr.
0crlaTAAssmsM
Dsiro70274
Sample Preparatl-on and Analysis Control Numbers
SAMPI,E#D{ATRIX
oo1 GhI
GUI
GW
G!{
GTV
GW
GW
GYT
GW
GW
GW
GItl
GW
GW
GW
GW
GW
G}T
o02
oo3
AMITYTfCAIT
METHOD
EPA 9OO, O MOD
4S11,1 5L74-9L
slvrww 71_10 MoD
EPA 903 ,0 MOD
EPA 9A4 MOD
EMIr A-01-R MOD
EPA 9OO. O MOD
AST}4 5L74-91
sMww 71r-0 MoD
EPA 903 .0 MOD
EPA 904 MOD
EMIJ A-O].-R MOD
EPA 900.0 D10D
ASTM sL74- 9I_
SMlrlIfl 7110 MOD
EPA 903 .0 IVIOD
EPA 904 llloD
EML A-OI-R MOD
IJEACH
BATCH #
PREP
BATCH #
528L03 9
s2977 A7
5291-293
5283l-08
5283l_O9
529 23 88
s281039
52977 A7
5291293
5283 108
s283109
52923 8 I
s281039
52977 07
529L293
5283 108
5283 r. O 9
s2923 88
MS Rt]N#
s28LA27
52982L2
529 12 18
5283055
5283 054
s2922s3
528LO27
s2982L2
5291218
s28306s
5283064
52922s3
5281027
s2982L2
5291218
5283 055
s283 054
5292253
STL Denver
IIETHOD BI"A}IK
Severn Trent LaboratorLeg
D5J07 427 4
WATER
REPORT
- Radl,ocbmistry
Client Irot ID:
Matrix:
Prrurtrr Rorrl-t Oull
Totrl
UDoort.
(2 6+l-1
Lab 8aqr1c ID
Prqr lrrly!:L,
Dttsc f,b,tr Brtoh, t IIA T
gRog8 t' BY co-PnrcrP gDrww
Gross Alpha A.24
7110 DIOD
U
pct/L
0.25
TLLO DilOD
0. 38
f,5ir180000-2938
ta/L8l05 L0/79 /05 529L293
Igo TEORIU!! (gHORr CT) IloE r-01-R uoD
lflrorLun Z3O 0 .21 iI
Thoriurn 232 -0 - 0L 8 U
pcLlL
0,16
0.052
r,-01-R lnoD
0.15
0. 14
r5.r190000-3888
LAlLglOS LAlzOl 0s s2e2388 83
LAIL, /A5 \A/20/05 5292388 83
oRoss r/a
Gross Beta
BY erPC EPl, 900.0 MOD
0.22 u
eCLIL
0-49
900.0 DIOD
0-82
r5dro80000- o398
L0 /08/05 1-0 /LL / A5 s28l-039
R.n.-2Z-8 BY GITPC
dlum 228
EPI. 9OI HOD
0 .02
r,C.LIL
pcL/L
904 MOD
4.72
903.0 uoD
a.21
r5tI100000-1098
10/L0l0s Lo/25l05 5293109 90
r5dr100000-1088
10/10/05 LA/25/05 5283108 1-07
RA-226 BY fP.}'-903.0
Radlum 1226t 0-09
4.42
0.12
TotsaI Urrnj.u.m br1r
Total Urani.um
KP"B, .e,STtt 5171-91
-0-133 U
u.s/L
0-01"7
5L7 {-91
0-31-
vsJztOOOo -7 A7E
7A/25l05 LA/25/A5 s29774'l
Drtr m lnooq)Ict. rithout tb. ornc nnrrativr-
!@C k dcta:ad.D.d, uriag {artsnrurat 9cfonnaaoc only
Eold rcrult,a aro gr.rtar than thr IIIE
i, n rult I'l grroctrr thrE ,.qrlc dotoctloa llnlt t,trt 1... tb.r it.t.d roDortl.ag lta{t.
BTL tDgflf6!2'lrrr thr.o tto rrqrlo d.t.otl.or 1t$1r.10
LaboraUorTlt' Control Sangrl.e Report
gever:a Trent taboratorl,es - BadiochoniBtrTr
D5,J07 427 4
I^IATER
Cl-ient Lot fD:
Matrix:
Paramrtrr SpLkt fmrot Borult
rOGAI
Unorrt -
(2 o+l-) mlc
Lrb 8nryflo ID
QC Control-
t Ild t Rtc [,in{ tl
oRogg r/B
Gross Beta
BT GIFPC TPI, 9OO. O DIOD
52.3
Ertob *r
sC;ilt'900.0 ldoD
s.5 4.7
fna.I'yrJ,i Datcr
r5J080000-039c
(70 121)51.-8
52 81,03 9
99
latLL/05
nr.-225 BY tPt-9o3. o
Radlum (2261
HOD
L1_ .2
lrtoh lr
oci/t 903. O uoD
0.2
lnrlyrLr Datcr
r5rrlO0OOO-1O8C
(54 135)8-7
s283108
10L 77
tQ/25/05
u-e28 BY OrPC
Radlum 228
EPA 904 UOD
5 - 21
Batoh, *r
r,c,LlL
0. 81.
90{ uoD
0.71
rnalyrlr fiat,r:
91 LA2
L0/25/05
rsirl.oo000-109c
( 56 147',t5.34
52831 09
GO88 I' BY CO-PNECIP
Gross elpha
Dci/t r5ir180000-293c
Iso TrrORrrrM (8HoRT er) DoE r-o1-R !@D
suww 7110
20.5
Batoh *t
8. 81
9-46
I-82
Eltcb Ir
DIOD
1B.s
5291293
9.1
8.6
9.3
5292388
'E,LfL
7110 !,toD
0.3
fnr1frir Datr:
r-01-R llDD
0.5
0-4
0-3
lnrlyrl.r Drtrr
90
\0 /L9 / A5
85 103
85 eL
85 105
lo /20/ 05
{7t 143 }
r5J190000-388c
( 91 1.32',t
( 5s t29)
(88 133)
Thoriun 228
Thorlum 23A
Thorium 232
L.3
L.2
t-2
![CIrE f I ]
roc lr dctonlard by lutrurut D.rfore. a.Ifr
STLFrRghVCgt !.t. t.tlono(l Dotora rou8lag to avotd rorud-off rrror la orlouletotl rcrultr 11
Laboratory Control Sary>le IIf'S DuplLcatse Report
Sevgrn Trent Laboratorles - Radlocbeilafgtr:y
D5,J07 A27 4
ITIATER
Client Lot
Matrix:
Pr.nrtrr
totaI'
Unoe-t.
Apilr rroor.rrt Rcgult 12 o + I -) rs Yld t Rcc
LaI, 8alOlo fD
QC Cmtrol'
llrl ts Prlcl'rLm
Total Unalum br1r
Total Uranlun
spk
KPl, LsTu 517{-91
40 - 0 38.17 8.00 8-55
Batsob Ir 52977A7
vg lr,5174-91 r5ir2{0000-7 07C
( e0 r.r.2 )(e0 7\21 L27
LA /26 / 05
tRPD
{.5
0.87
9s
LA7
fanlyrl,r DrEo r
Norr (sl
---Crloslrtlo[a ln prrfotrrd boforo rouldl.Dg eo avold rould-o!! rror Iu orlouhtcd rrrulttSTL Denver 72
IYIATRIX
Eevern
D5,J07 027 4
GW
gpthr
frouut
SPTKE/}ITTRIX SPIKE
Trent f.aboratorl,e;
DITPITfCITE REPOR:I
- RadLochsdgtty
Dat,e Sampled: 1A / 05 / 05
Date Received: LA / 07 / 05
0800
093 0
Client Lot ID:
Mat.rlx:
PuuoEcr SPIXE
Reoult
trote1
Iluorrt. ElrLkt g.lltpLE
l2 o+l -l Y16 nlrult
AC 8r4>1e ID
tr Yld ernre
Total
Unoert.
(2o +l-l
Oe Cogtrol
Ltnl"tr
GROgg .I, BY
Gross Alpha
CO-PRECIP g![rIW
4L -2
spk2 4L -z
htseL I r
68
40-5
52912L8
pci/r 7110 DIOD D5.r07 O27 4 -O01
10 14.{ 3.3 131 (47 1-33}
6_6 Llr.4 3.3 54 (47 133)
Drcolrloar 51 tRPD
lnrlyrl.r datrr 1Oll9/As
C}ROAS AIB- BY
Gross Beta
GIrPc EP.l, 900. o
3480
Spk2 3480
3560
3760
*r 5287027
D,c.LIL
380
400
lnalyrLr
900.0 MOD
356
355
datr r
62
62
Dsiro7 077 4*002
92
9B
proclrl.on: 5 tRPD
(s0 1_s0)
(50 1s0)
Brtsoh 1A/LT/0s
lDotrl Urrniun bryr IrPl
^gXU 5
TotaL Uralium 40.0
spk2 40- 0
htoh Ir
l-05 a
111 a
529821 2
u'glt
13
1_3
.lnrlyrt r
5L7 4-91
9r_ 11
91 11
drtor 1A/26/A5
,5ir070771- OO2
35 I (90 ,rD
Prootrion r :t *"*rl'o
t 'l
Rr,-225 Br EPI-903. O t{oD
Radlum (2?61 L1 . 5
Spk2 11.6
1-3. s
1d. 5
Batob *r 5283055
pcilt 9o3. o troD
1.5 89 2 -'.78
1.7 92 2.79
0. 50
0. 50
B9
89
D5.rO7 A27 {-002
93
102
(30 Lt 5)
(30 116)
PrccLrl.oa:7 IRPD
lr,a).yrlr tr+tr t t0 /2s / 05
nl-228 BY
Radlun 228
c!'Pc rPA 90{ !{OD
5.3s
Spk2 5.38
pCi/r,
1.s 80
1 - 5 79
rnalytlr
904 MOD
6.08
6 .08
duto r
D5iro7 027l-O02
1,2 .4
12 .4
Ir 5283 064
0. 90
0-90
Drco:[e:[ou r 4
(62 lso )
t62 1.s0)
tRPD
8L
81-
119
1- 10
Batob LO /25 / 05
Iro TIIORTmT (8HORT
Thorl-urn 23A
Spk2
Thorlum 232
Spk2
er) DoE
..
9 .46
I .46
8.82
8, 82
7-9
7.8
9.0
9 -4
5292253
E cL / t, t - 01 -R MoD D5.r07 O27 l- 0 02
1-1 89 0-69 ,J 0-27 89 77 (74 L30)
1 .1 91 0.69 J O .27 89 75 04 130 )
PrrsLrl-on r L tRPD
L.2 89 0-077 U 0.096 89 1.02, (81 124).
L.2 91 A-O77 u 0.096 8e l-06 (81 124\
Prccialonr 4 tRPD
lnrlyrLr drte r 1A 120 / A5BatoL *r
CrlcnLtl'o8rr ere DrrfotDd brloro rurdlirll to awoL(l r(,rrsd-olt crror ln calolrtad r.rultst
r apthod.D.Iytc sutrLdc of rtrt.d eC lrrlltr.
a, Rotu1t La lrortor than ilqr1. dctootLoD llLtt brt lrrr tsbra rtrtOd rcportlag
STLT$6?rverI, ncaulB I'r 1or. th.E tbo trqt1o dctoctr.oa tlDLt.
13
STL Denver
Sample Receiving Checklist
O
^r.0, .D.rf,\f\ al4 Daterrime Received:
Cornpany Nlame & Sampling Site:
PM to Complete This Section: I'es
Residrnl chlorine cbeck require&D Qr-rarautined :XIes
tr
euore#: t{4Cqb
Special Instnrctious:
A:
t1
tc
Unpacking Checks:
-/4
,a
I
D
,a
,a
A
Coolcr #(s): I c-
O;r*'ffi:
("c): 'Itl 'J'l'-
D
tr
F.
/
I
IJ
tr
I
tr
tr
p
D
fI
D
F.
E
F
F.
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.p'
I
D
fI
tr
tr
1. Cooler seals intact'? (N/A ifhand delivcrsd) If no, docr:ment on C'[IR
?. Chaiu of custoriy prcscnt? lfno, document on C'[fR
3. Bottles broken and/or arc leal.ing? If Ycs, document on CIJR
4. Multiphasic sanples obvious? If ICs, document on CIJR.
5. Proper contaimr & prescrvaives usd? (r:f- Anacbme,nt D of SOP# DEN-QA-0003} If ao, docr.ment oa CATR
5- pH of aII sauplcs checked aad ureet rcguirerneds? Ifao, documod on CtlR
7. Suffcient voiume provided 1e1 2ll anall*is rcquesed? (ref. -dtta.bmed D of SOP# DEN-QA-0003) If no,
tiocturcnt oo CU& and coutad.PM before proc*riing-
8. Did cbain of custody agree with labels ID and sarnples received? Ifno, docrrnsut on CUR
9^ Were VOA saryles witbout headspace? Hno, documeat on CIIR-
10. WereVOA vialsprcserved?Preservadve DHO 3'r"C DSodiuroThiosulfateDAscorbicAcid
I l. Did saqles require preservation wittr sodi,'ur thiosulfate?
12. if ycs to #I l, did the samples conlain rcsidual chlorine? If ycs, documsnt on CLIR.
13. Scdiment prEsent in dissolvcd/filtsr:d botties? Ifyes, docr.mcut on CIJR.
Id. Is suflicient volume provided for cfient requested M$ MSD or mahix duplicaies? If oo, document on CU& and
coutact PM before pro63ding.
A p 15. Recciptdate(s)>48hor.uspastthccollectiondate(s)? lfyes,notifrPAPlvl.
D 4 15. Are analyses with short holding timcs reouested?
tr .6 17. Was a quick Tum Arourd (TAT) requesred?
STL Denver
\QA\Fornrs\Sample Rccciving\lsamplc Reeeiving Ch:CCist i2 13 (X revision tutStu
a4
STL Dcnver
Sample Receiving Checklist
Lot#,25*T0id;7+
Login Checks:
N/'l l'es No
/ O 18. Suflicient volume providcd for all anall,sis requested? (rcf. Auachmenr D of SOP# DEN-QA-0003)
O
If no,
R,, doo:rrment on CUII, and conlactr PM bcfore proceeding.
N H| Ct 19. Is suflicient rolume providcd for client rcguestcd N,lS, IUSD or matrix duplicates? lf no, document on CUR, and\ \-/ conlact PM b,cfore proceeding.
D 20. Did thc chain of custody includcs "received b)r'and'tclinquished" by signaturcs, dates, and timcs?
O ?l- Were qpccial log in insrruaionn rcad and followcd?
tr 22- Were AFCEEmctals Iogged for rcfrigerated storage?
tr ?3. Were tests logged chccked against the COC? Vr'hich samplcs were conJirnpd? I
D 24. Wasa Rushform completedfor guick TAT?
D 25. Was a Shofl Hold form completed for an1, short holds?
6 N- Is "sria ICoc" required?
F Zl. Werc special archiving instrucrions inrlicared ir the Gcneral Comments? If so, u'hal were they?
Labeling and Storage Checks:
5 28. Was the subcontraa COC signed and senl witb sanples to bottle pre,p?
D 29. Were sarrplc labels double-chccked by a second person?
EJ 30. Were sauple bottles and COC tlouble checkcd for dissolvetVfiltercd maals by a second persou?
A 3I. Did thc sauple ID, Datc, and Time from label matdr uihat was logged?
tr 32- Were stickers for special archiving instnraions affrxed to each box and to rhe ICOC? See #27
tr 33. Were AFCEE metals stored refrigerated?
tr 34. Werc *Stict ICOC'copics given to satellilc storage areas?
Documeil any probJems or discrepansies and the actions taken to resolve them on a Condirion Upon Receipt Anomaly
Report (CLIR).
STL Denver
\(tA\Frlrms\Sanrnle Rm.e.ivinr,\Sarnnlc llere.ivinp Chrcklist l? l-i 04 revision
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303 431 7t7I
AI\ALYTICAL REPORT
Western Zirconium Project
Lot #: D5I090t 89
Sheri O'Connor
URS Corporation
8181 East Tufts Avenue,
Denver, CO 8An7
STL DENVER
Linda L. Benkers
Project Man ager
STL Denver
4955 Yanow Street
Arvada, CO 80002
Tel: [phone]
www.stl-inc.com
Septanber 30, 2A05
Severn Trent Laboratories, lnc.
Table Of Contents
Standard Dellverables with Supporting Documentation
Report Contents
Stan dard Detlverabtes
(Thr Cover Letter and the Rqort Cover page ore considered integral
parts of this Standard Deliverable package. Thls report ls incomplete
unless all pages indicated in this Tcble of Contents are included.)
o Table of Contentso Case Narratlve
o Executlve Surnmsry - Detectlon Highttghts
o Methods Surnmary
o Method/Analyst SurnmarT
o Lot Sample Sumrnary
. Analytical Results
o QC Data Assocladon Summary
o QC Sample Results
. Chain-of-Custody
Supportl ng Documentation
(Note: A one-page "Description of Suppctrting Documentotion" is
provided at the beginning af this sectlon.).
o Volatile GC/I\{S
o Semlvolatile GC/MS
o Volatile GC
o Semlvolatile GC
r LCIIVIS or HPLC
r Metals
r General Chemistry
o Radlochemistry
r Subcontracted Data
Nunrrber of Pages
Check below when
cupporting
documentafion is
present.
o
nnnnnnmE
STL Denver
Case Narrative
D5r090189
With exceptions noted as flags or footnotes, standard analytical protocols were followed in the
analysis ofthe samples and no problems were encountered or anomalies observed. All laboratory
quality control samples analped in conjunction with the samples in this project were within
established control limits, with any exceptions noted.
The test results presented in this report meet all requirements ofNELAC, and any exceptions are
noted. This report shall not be re,produced except in full, without written pemrission from the
Iaboratory
Sample Recelvlng
Seven samples were received under chain of custody on Septernber 9, 2005. The samples were
received in good condition at temperatures of 3.3oC, 3.8"C, 3.6oC, 4.4"C andZ.7"C.
The results for all radiological analyses are included in this report and were performed by STL
St. Louis; 13715 Rider Trail North; Earth City; MO 63045, phone 3l+298-8566.
Radiochernlstry, Verious Methods
The method 900.0 MOD gross beta MDA for samples D5I090189-001 through 007 was not met
due to reduction of sample size caused byhigh residual mass. The analytical results are reported
with the MDA achieved.
The method 7ll0 MOD gross alpha MDA for samples D5I090189-00I ttrough 007 was not met
due to reduction of sample size caused by high residual mass. The analytical results are reported
with theMDA achieved.
A low-level and a high-level LCS standanl were analyzed with total uranium batches 5262217
and 5269090 and they are spiked at different concentrations. Therefore, the RPD value reported
for these two standards does not apply. Both LCS recoveries were in control.
AII MSA,ISD were performed on samples from other clients and/or lots and some were not in
control.
Denver
METIIODSW
D5rO90r_89
PAIUTMETER
AIVAIJYTICAIJ
METHOD
PREPAR.,.ATTON
MEfiIOD
Gross Alpha (COPRECIP) by
Grose Alpha /seva by cFPC
Isotopic Thorium by Alpha
RadLurn-226 by GFPC
Radium-zzB by GFPC
Total Uranium By Lager Ph
Referr:nc€B:
GFPC
SpectrosCopy
oephorlmetry
sM9rlil 711_ 0 MOD
EPA 900.0 tvtOD
EI{Ir A- 0L -R MOD
EPA 903.0 MOD
EPA 9O4 MOD
AST!,I 5L7 4- 91
EPA 900.0
ASTM
EMI,
EPA
sMr|w
Anrrual Book Of ASTM 9tandards.
IEIN'IRONMENTAI, MEASUREMENTS ITABORATORY PROCEDUREg I{ANUA]'T
HASL-300 28fH EDITION, VOLIIME I and II DEPARI'!,IENT OF ENERGY
N EASTERN E}WTRONMENTAI, RADIATTON F'ACTLITY RADIOCHEMISTRY
PROCEDURES Mi\NUJ\rrr US EpA EpA 52A / S-84 - 006 AUGUST 1-984
IISTATVDARD METHODS FOR I.IASTE WATERN
STL Denver
METHOD /ANALYSTW
Dsrog0189
A}IALYST
A}IAIJYTICAIJ
METIIOD
AI{AI,YST
rD
4023 5 0
40L627
4 01_ 627
4 00 597
400697
400597
ASTM 5L74-91
EMIJ A-01-R MOD
EPA 9OO. O MOD
EPA 903.0 MOD
EPA 904 NIOD
sMr{!il 71L0 MOD
AgI1}I
EMI,
EPA
I"Il-ke Anderson
Jtmnry Wl}son
,7immy Wilson
fvan Vania
fwan Vania
Ivan Vania
Anrrual Book Of ASTIVI Standards.
trENVIRONMENTAI, ME,ASI'REMEICIS I,ABORATORY PROCEDI'RES I'II,ANUAI,N
HASIr-300 28TH EDITION, VOLITME I and Ir DEPARTD{ENf OF ENERGY
,I EASTER}I EMTTRONMEMTAI, RADIATION FACTLTTY RADTOCHEMTSTRY
PROCEDT}RES TVIANUAIJ'' US EPA EPA 52A/S-84-OO5 AUGUSIr 1984
'ISTANDARD METHODS FOR }TASTE WATER'I
STL Denver
sffiw
Dsro9(}r.8g
O
WO # SILIviPLE# CLIENT SAI{PIrE fD
SAMPIJED SAMP
DATE TIME
H.tBeM oot Gw-5c-o9o805
HJ8QX OO2 cW-R2 - 09080s
H,J8QO OO3 GW-35- 0go8os
Hir8QI 004 GVir-4A- 0g0B 0s
H,J8Q2 00s cw-s4-09080s
H,J8Q5 005 Glr-R4-0g0g0s
H.I8Q7 007 gvil-R3 -090805
IKIrts (S} :
oe/a8/os o9:1-5
09 / os/ as oe:25
09/08/os 1o:38
a9/08/os r,1:oo
og / oBlos 11 :50
a9l o8los L2:4a
09/a8/as l-4:15
- Thc amlytical results of thc ssnphs liged rbovc rro proscntcd oo rhc foltowing pagcs.
- AII cllculations are pertorEdl bcforc rouldinl ro rvoid rousd+ff crrors in calculrtcd r6uhs.
- Results noicd as "ND' were not dcrcctcd !t or aDote tha statod limir.
- Thi6 r€pon mu$ not bc rcproduoad, accpt in ftrll, wirtrout thc wrfiteir rpproval of rhc laborlory.
- RcsrlB for the followinS psrrnrotor3 arc ncvcr rcponcd oD r dry peighl besis: color, (prrosiviDr, d.rEity, flashpoim. igniEbilty, Iaycrs. odor,
paior flltsr test, pH. poroslty pr66ure, rcaetivity, rcdox porentJrl, specifr grsyiry. spoi t sts, sohds, solubility. tcmpcrrurc. vircosry, a]d wciSht.
STL Denver
o t Rg Corlpration
C].lent Sarmle fDr G9[-5C-090805
Sevcrn Trcnt lraboratoriee - Radiochmigtrfr
Lab Sample ID:
lrlork Order:
Matrix:
Parclrtor
D5r090189-001
HJEOM
GW
Xorult
Dat,e Collected:
Date Received:
Tota]'
Ilsorrt ,
gull 12 a+ I -l DIDC
a9 / 08/05 0915
a9/09/a5 0e30
Prop
htt
enrlyrlrDetr Batob I rla t
sRosa ^lsGlro;: Eotr
BY OrPC EPt 900. 0 !@D
3E3
W,LIL 900-0 HOD
a9 t21l05 09t74tA5 526{1?9
Totrl. Urenlum bf
ToEal Urulu,rn
KPr ^LgrM 517{-91
18. {
u;fllL 5L7 4-91
09l70la5 aelztl07 r26z2t7
cRogg t BY co-pREclp allr|w 7110 uoD
Grort ^Llpbr 3.1
DEL IIJ 7110 lfOD
o9ll7 lo5 a9l7alo5 5260068t.7
RIr- 226 BY EPI'-903 . O l.lOD
Rrrdl.um 1226) 2 .53 0 .06
t L lT.
0.33
903.0 DloD
09/101a, 0e/2elo, 52t3061 93
Rt-228 By OrPe
Rrdtrrn 228
fPt 901 tiloD
3.{2
Dct/L 901 t[oD
09lto I 05 0e l28l o5 3253062
Igo THOnrgD!
Thorir:m 2 3 0
thorium 232
(8IIORT CTT} DOE T-01-R
0. 092 u0.008 u
0-67
0. 091
0-044
Dct/L
4.75
0.L0
0.094
r-01-R
09/16/45
a9/16/45
uoD
a9/20i05
09/20/O€)
5259114 l-1-0
525971.4 11 0
NOEE (g}
tr rn Lnoqllotst yl.thout tho oit uratlvo,
loc l.r drErralnod br Lnrtnrnrcnt Dufororao. ouly.
Bold rcrult,r rr. grcatrr tbtr tbc llDC
U trrrulE Lr lcrr thrn th. ralqlh dotootl.ou lLnlt,
STL Denver
IIR$ Corporatsion
ClLent Sannole IDr GIrI-R2-090805
Sevcna Trcat taboratsorleE - fudl.ochutgtry
Lab Sample ID:
Work order:
&Iatrix:
Prnmtrr
Dsr0901_89-002
HJBOX
Gt^I
Rcrult
Date Collected: 09 / 08/05
09/0el0s
092 5
0930
Prrp fnalyrl;
htr Datr Batcb I
Date Received;
Totrl
utroort.
$lrl (2 o+ I -l ilrrc YlA t
OROSS f,/B BT
Ororr Ertr
oFPC EPt, 900.0 ltOD
250
rrcl.lt 900.0 r@D
agl7ll os oglztloa 126{12,5{
Total Uraulun b1t,
Totai Uranlum
trPr r,gtu 5L7{-91
o. 117 u 0.013
Lrg lI)
0.31
3L7 t-91
09/27 /A5 09/28/45 s269090
gRosg .n By co-pnEcIp BlrIyTI 7110 t00D
Orotr .l],phr 5. t
ecl.l!-7110 DIOD
a9tl7 las 09120105 5260068L.7
nr,-226 BY rEDl-903. 0 ![oD
f,rdtnm (2261 2,O7 o.ao
*Lltr
0. a9
903. 0 lioD
09/10/05 a9tz8l05 5253061 9t
R.f,,-?78 BY OrPC
Rrd,tun 27A
rP 904 rioD
3 ,29 0. 67
PCt/L
o.79
90{ ltoD
oello lo5 091218103 5253062 91
Igo THORIINT
&orlum 2lO
Thorium 232
(sHORT er) DOE n'-Ol-R rrOD
0,26 c
0.0 u
Dct/t l-01-R
ae ltc I a3
09/76/s5
loD
ae lza I 03
a9 /zo/ 05
0.16
0-0
o-12
0-06
525911{ 85
525911"4 85
lrorr ( I )
DiEr an LDc(]rlat. rl,tlout tha otra lrrraEM.
llDC Lr ilotorutao(t blr lartnlErqt tr6rfotrr.,Do. a1y.
lolA rcirltr rr. gEG.t.a thr[ tha I@C
J R..rrlt 1,. lE.ttar thrE ..qrlc dot.otloq tlIrl,.t bqt 1.rr tLrr rtrt.A rqprtl,ag llEtt.g R..Elt, lr htr tlia th. rqrlt datcctlor 1hlt.
STL Denver
IIRS Corporatl,on
Clicnt Sannrle fD: GTi[-S5-090805
Sevem Treut, Laboratorias - RrdiochstiBtrT'
Lab Sample f D:
hlork order:
tlatrix:
Prrurtrr
D5r0901-89-003
H,JBOO
GW
Rcnrl.t QurI
Date Collected:
Date Received:
TotsrI
Ilnoafr.
12 o+l-) toc
a9/08105 1038
09/09/0s 0930
PrlP r'rtlylll
Detr Datc ratch I
GROgg t./B BT
Glrorr Brtr
orPc EPt 900. o DloD
113
E,C,LII)
77
900,0 tioD
ae t2Lla5- oe lTll a5 3261129
Total Uranl-un b1t
Tofrl Ur-":[u.m
KPr tgm[ 5L7t-91
0.591 ir 0. 063
tulglL
0.31
,L7 {-91
a9 tla lo5 a9lzlla5 57622L7
gnosg r' BT CO-PRECIP 8!IS'?Y 7 LLO
Ororr llpba 1,29
TTIOD
J o.77
r,C.Llf'
o.9a
7110 uoD
oeltT loi a9l20l03 5260068
nl-236 BY fPA-903.0 UOD
Radlum (226) O.80 0 .25
EeLnt
0.25
903. O teOD
09l1.ol os a9 n8la5 5253051
nl.-228 BY CrPC
Radlua ?28
EDr, 90{ DIOD
1 ,15
I>CiII,904 uoD
09/10/05 091281 as 52530630.51 0.77 87
IIo THORITIII
Thorlun 230
Thorlum 232
(8HORT C[] DOE ]-01-R
o,tg J
0-021. U
r,cLlt n - 01-R
09 /16 / 05
09/L6/05
DCOD
09 tlat05
09/2A/05
o.2l
0,078
o.la
0.16
5259111 5J
5259114 55
![(lTt (8)
a lro t-noq>lrtr rl.thout thr o6r urrrtl,vo.
l.t drtrrnl,uod by fuutnrnrnt, pcrlormraor ou1y,
Eold r.rulta ara g8.rtar th-i tbo EC
., : narrlt lr grortes tbra rqrlo Cotoctlon lLutt but lcrr tbu rtrt.d rq)ortlltg ltdt.
U f,orult Lr lcrr tL.! tb. rqllr d.taotloB tlrrlt-
STL Denver
IIRS Cort>oratLon
C1ient Samolc ID: GII[-{A-090805
Scvcm, trcr,t Lrboratorler - RrdlocholBtry
Irab Sarnple ID:
Work Order:
Matrix:
Parauttrr
Dsr090189-004
HJBOl
GW
Rtrult ht. h.t.natoh t Yld rr
Date Collected: 0 9 / 08/ 05 1L00
DateReceived; 09/A9/AS 0930
![otrI
Ilb,sl*.
Sral (2o+/-) UDe
lnrlyrir
ONOSS }.IE BY
Ororr Bote
GTPC BPA 9OO. O DTOD
253
*Llt 900. 0 r{oD
09 I
"L
I 05 09 l zl I O' ,2647.2969
lDoua1 Uranitrn b1t
lfoEa1 Uranl.un
KPl' I.grH 5L7l-91
0.5{9 ir 0.061
lclsl/-J'
o,31
5174 -91
09 I Z0 / 05 09 121,I 05 57627L7
G,RO8g Ir BI CO-pnECrP 8ur5r[ 7110 DiOD
Glror ^trAphr 5.9
ecllL 7110 t{OD
09lL7 l05 09lzalo5 52600687.4
m-226 BY EPA-903.0 UOD
Rrdiurn (726) O. 95 0,30
plCLlt
o.30
903 . O ttOD
oellatos 0el28lo3 5253061 63
R[-228 BY CTPC
RrdLun 278
IBPA 90{ !f,OD
3 .34
pcLlL 901 t[oD
09110/05 091281os 5253052
Iro IPHOIiIEIA
Iltorl.urn 23 O
Thorium 232
(gHoRT C:r) DOE t-01-R
o.2g J
0.043 u
0.gg
0.16
o-075
9CL lf'
0. 09
0.0s9
r-01-R
09tL6l05
a9/L6l05
![oD
a9 tzat 05
09/2AtAs
55
5a5911{ 86
525911d 86
NOtrE (s)
hta lr'r Lncqllotr vLtborrt thr ouo Drrratlvl.
l{DC Lt dotcratnrd blr Lnrtnrno,st prrfo-rrnnoc ouly.
Bold rotulur rr. grrcatr thrD thc lnDe
ir Rrrrult La grcrtrr thm n4llr dotcctloa 1latt hrE loac
U Rorult Lt lor than tbr arqllc drtrotl.on lLErLt.
STL Denver
tba-u rtsrtrd rolprtslug 1LnLts.
URS Corpora.tLon
CIIent Sarp1e ID: Gsr-gl-090805
Scvcra Trrat Ireboretorieg - RadiochffitirtrT
Lab Sample ID:
Work Order:
Matrix;
Paramter
D5r090189-00s
HJ8O2
GW
Rorult
Date Collected:
Date Received:
TotrI
Uuoorts.
17 o+l -l rDc
09 l0Bl 0s 1_1_50
ae I oe / a5 0930
lnalytlt
llat. BaBch I
Drrp
Dat.
OROSS t.Il BY TPC
Orote Dcta
EPI, 9OO. O IDD
742
*,Llr,
51
900.0 t[oD
ae tzltas 09l2ll0s 526ltz9
Totr1 UrrnLun blf
Totrl Urrnlua
xPt, rglIfl JL7{-91
0.877 J 0.095
uslL
0.31
3L? t-91
09170/05 a9 nll 05 52672L7
sRosg t' BY .co-PREcIP gliFr 7110
Groes Alpha 1,05
pet /L
0.83 L.2
?LLA UOD
09 /L7 / 05 09 /20/05 5260068
DtoD
U
m-226 BY trP.f,-903. O ![OD
nr6iun (226) 0.59 o ,20
*Llt
o.21
903 .0 DAOD
09/10 tol 09t28ta5 s353061 96
Rl'-?,28 BY OrPC
Radtrrm 228
EPT 90{ HOD
t-33
ifr,LlI-90{ lroD
09 t 1,o I o5 09 l28 t 05 5e53062
IIo THORTTNi
Thorlurn 2 3 0
Thorium 23?
(Bnonr cr) Dor t-oI,-R t[oD
0_07 u0.010 u
0.51
0. 11
0.078
S,CLIL
o-73
0.15
0_15
r.-01-R
Ag/-L6/Os
a9/L6/As
uoD
09t20105
09 /20/05
5259114 90
52s9114 90
-![otrt (g]
tc rr. Laeqllrtr rLtbout tJrt olro nrlratl,rra.
l@c Lr dot,cralard blr lartnrmaB porforrunot only.
Bold ruultl uG grtrtor tbra tbr t[DC
it Rrrult Lr grrtrtrr tbta ruttrr1r dtteott oa l{plt but
U Rotult Le lorr thra tbc rcmllo drtootLoo lfunlt.
STL Denver
lur tshrn rtrtrd rqprtlag lLrd,t.
10
IIRS CorporatLon
C1l,ent, Sanml,e IDr GIil-R{-090805
Scvarn TrenB Laboratsorles - nadtochmlBtr:tz
Lab Samp1e ID;
Work Order:
Matr{x:
Pcranrtrr
D5r090L89-005
HJBO5
GW
Rmult
Date Colleeted:
Date Recelved:
lDotal
llaorrt.
(2 o+l -) lDC
09 / 08/05 1,240
a9/a9/05 0930
DreIl tsllyrlr
Drtc Drtl Ertsob fl
oRoss ,.lB BY orPe
Orort Brte
EPt 900.0 uoD
L37
pct/r,
25 75
900. 0 DtoD
a9 nuoS 091"5/os r764L29
Total Unol,un W
Total Urarrir:sr
xPl, tsrllt 517{-91
-0.0147 u
ug lr'
0-0018 0-31
517{ -91
a9 /20/05 09 /2L / A5 52622L7
oRo88 .L By CO-PnrCrp StltfDt 7110 DIOD
Ororr .Elpba 3,1
DcLIT)7110 lnOD
09 tL7 t05 0ef 70I o5 52600681.3
RL-226 BT EPf,-903.0 MOD
nadl.um (226) 1.5a 0 -31
*Llr,
o .20
903. O uoD
09lr.0/o5 091781oi 5253051 10e
TB-228 B:r CFPC
RrdLtrt 228
EPl' 90{ I.IOD
3 .39
scL lr,90{ uoD
09lt0l05 a9l"lBlo5 5251062
Ieo TRORII,II
TborLuur 23O
Thorium 232
(aIIORT Cr) DaE r-Ol-R
o-13 ir
-0-004 u
o.62
0.11
0.047
pcLlt
o. 66
0. 06
o-o91
r-01-R
a9 tL6 ta5
a9/76/05
!0D
091z.0la5.
a9/24/05
525911{ 86
5259114 86
NorE (8)
DaEr tr. l.ncoqphtse rl.thout thr oerc alnatirrr.
uDc Lt dotcrrnl.ad by lnrBnunrat pcrtormraor oa1y.
BoId rctultr rr. grrcattr tbrn tbc UDg
J Rcrult Lr grrcatcr tbr.a ;alq>h drtrotion I.ln{! but lotr
U Rcsult lr lrte Ehru tshr trrry>lrr drttoElon llmlt.
STL Denver
thrn rtrtrd rrportlag lLs{e-
11
t Rg Corporation
Client SarrcLe IDt G$I-R3-090805
gewern Trcut LeboratorleE - RadLochodrtrtr
Lab Sample ID:
Work order:
Matrj.x:
Prrenrtrr
Dsr090189-007
H.]BQ7
GW
traru1t
DaEe CollecEed:
DaEe Received:
a9/08/0s L415
a9/09/0s 0930
Drrg .lanlyll.c
Drtr Ilrto Htsb *
TotrI
UrrOa*.
(2 o+l-l
GIROAS t.IE
Ororr BoEr
Br grPc EPr 900.0 ![oD
88
*Llt'900 - o DoD
a9l?L1o5 a9l25lo5 5261129L7
trotr], UrrnLuro
Totrl Uraniun
blr XPl' ^I.SIlIril 5Ll{-91
L.22 0.13
Lrf,lI.
0.31
5L7 r-91
a9l3al03 09l2llo3 5762?L7
oRog8 t BY co-PRtcrP s!finw
Orotr tl.pbr 1.58
7110 ![OD
J o .90
sc'.ll,-
0 .99
7110 t0D
a9tL7 las a9l20lo3 326005t
Rr,-226 BY tPt'-903 . O lfioD
Rrdl,trn (225) 0.83 o.77
DCLII'
o,L7
903.0 tcoD
09tLatos 09l2gta,5253061 105
nif,,-238 By orPc
Rrd,l.uro 77e
EPr 90{ lroD
1 .81
*ilL 90{ !iloD
oe/Lolo5 ae l78l03 5253062
IgO THONIU}T
ItorLrrn 230
Thorlurn 232
(glroRT er) DoE
0. {g
0.01.4
A-ol-R DIOD
ir
U
lpD
a9 t"o I oi
a9/20/05
525911{ E1
s2591 14 81
0.22
0_052
r,C.t ll'
o-66
o.12
0.11
.1,- O1-R
09 tL6l as
09/L6/05
NOIE (s]
tsr, lr. laoqfrlctr rlthorrt tht ort. nrrratLvo.
Le dcteraLuod by Laatnrsrrat prrformnaoo only.
BoId rrrultt u. grrcrtrr thru thr HDC
., Xolults la erruttr thtr nrErlr dctcctLon !{nl3 bnrt
U tcsulE lr lcrr thrn thc rrrgrlo dotcotlou 1fuD.lt.
STL Denver
lcrr thra rt:tod rqlortlng IfutLt.
72
acrlaTAAssffioNw
D5rO9(}189
Sample PreparatLon and Analyeie Control Numbere
gAMPLE#I{ArRrX
o01
o02
003
004
00s
006
AT.IALYTTCAL
METHOD
EPA 9OO. O MOD
ASTM 5L74-91
sMww 7r.10 MoD
EPA 903.O MOD
EPA 90{ MOD
EML A- 01-R MOD
EPA 9OO. O MOD
ASTM 5L74- 91-
gMww 711-0 MOD
EPA 903.O MOD
EPA 904 MOD
EIVIL A-01--R MOD
EPA 9OO. O MOD
ASTM 5174-9L
sMulw 77-to MoD
EPA 903.0 MOD
EPA 904 MOD
EMII A-01-R MOD
EPA 9OO. O MOD
AST1\{ 5L74-91
sMm{ 7110 MOD
EPA 903.0 MOD
EPA. 9A4 MOD
EMIr A-01,-R MOD
EPA 9OO. O MOD
ASTTU 5L7 4-9L
sMww 7LL0 MoD
EPA 903.0 TvIOD
EPA 90{ }110D
EMIr A-OI-R MOD
EPA 9OO, O MOD
A*ST[,! 5L74-g].
sM$[!{ 7110 MOD
EPA 903.0 MOD
EPA 904 MOD
EMIJ A-01-R MOD
(conEinued on no(t.
GW
GW
GW
GW
GTT
GW
clw
GW
GW
GTI
GW
GW
GIII
GW
ctw
GVT
GW
GW
GW
GW
GW
GT{
GW
GW
GW
GW
GW
cyr
GW
GW
GW
GUI
GTI
GVt
GI{
GW
TEACH
BATCH #
PREP
BATCH #
52641,29
52622L7
s250058
s2s3051
52 53 052
s259 1 14
5264]-29
5269090
5260068
s253061
5253052
5259LL4
52641-29
5262217
5260068
5253 05r,
s2s3 052
s25911{
5264L29
s2622L7
5260 05 I
5253 06 1
5253 062
5259LL4
525 4L29
s2622L7
s26006 I
s253 061_
5253 062
525 9 L1{
5264129
5252277
5260068
s25305L
s253 052
5259L1-4
I'IS RIJN#
52640 9 0
526215 5
s260033
s253 0{ I
s253 447
5259A47
5264 090
526 9 051
5250033
s253048
5253 A47
5259047
s264 090
s262Ls6
s26003 3
s253048
5253047
5259047
5264 090
526215 5
s26 003 3
s253 04 I
5253047
s2590+7
526409 0
s262L55
s260033
5253 048
5253 047
52s9A47
5264090
5262L56
5260033
s253 0{18
s2s 3047
s2s 9447
STL Denver
page)
o acDATA ONW
DsrO90189
Sample PreparaEion and anal.yel-e Control
SAIvtPITEf T-IATRIX
o07 GVT
GY
GW
GW
GW
GW
ATiIAI,YTICAIJ
METHOD
EPA 9OO. O MOD
ASTM 5L74-9I.
sMrvr{ 7110 MoD
EPA 9O3 .0 MOD
EPA 904 TVTOD
El'{L A-01-R MOD
T,EACII
BATEH #
Numbers
PREP
BATCH #
s264L29
s2622L7
s260058
s2s3 051
s2s3 052
5259 1 14
t'{g Rt N#
s2640 9 0
s262Ls6
s26003 3
s253 04 I
s2s 3447
52s9047
STL Denver 74,
Client Lot fD:
Matrix:
Drrrnltrr
Eewern Errnt
D5r090189
WATER
IlmuLt gurl
DIETIIOD BI.}DIK
Lrboretorice
REPORT
- Radiochm.iatrrr
Totrl
Unoort.
(2 o+l-l
PrrD
Dltc
L.b 8rxllr ID
eralyrlrDr.t. Batcb I rld t
GIROSS ^lDGrogs Beta
BY OrPe EPl' 900. 0 troD
0.68 U o -67
pct/r 900. 0 DIOD
i_-1-
r5r2to000-1298
09 /21 /0s 09 /25 / 05 5264L29
NA.228 BY OFPC EPI 90{ UOD
Radium 228 0.03 o -27
DCi/L 901 lroD
o .47
15r100000-0628
09 /1,A / 05 09 /28105 5253A62 90
nr,-226 BY lP -903.0 EIOD
Rad.itrrn (226) 0,04 0 - 12
gcLlL 903. 0 t[oD
o - 2L "5r100000-
0618
09/1,0105 09/28/05 5253061 93
IEO THORIUDT (SHORT CT} DOE T-01-R I{OD
Tboriur 23O O .21 iI
Thorium 232 -0.004 U
E,€,LIL
o.1{
0.045
l-01-R uoD
0 ,06
o_087
15r150000-11{B
o9/16la5 09l2al0t 525911{ e5
Q9 /16/ A5 09 /2A/ 05 5259114 95
CROSS T BT CO-PRECTP
Grose Alpha -0.09
srf,wDl 7110 DloD
U 0.34
gCLIL 7110 UOD
0. 55
r5r17 0000- o68B
09 /L1 /05 09 /2L/A5 5260068
Totrl Uranlun btr
llotal Uranlurn
xPr, lgxu 3L7l-91
-0 - 02r,1 u
vg llt
0.0023
517{ -91
0,3L
13r190000-2178
09 / 20/05 09 tztl 05 s2622L7
Tota} Ur-''Lun by
trotrl Ur.nLun
KPr, n'gr![ 5174-91
0. {65 ir
ug/I{
0 .0{9
5174-91
o.31
P5r260000- 0908
a9t27 fal 09tZ.Bt05 5269090
NOEE (B}
Drtr ar. t-nOoryllotc yLthouE thr ceta "ttt.atlvc.
DlDc 1r dottrr:nlnrd uilag l,nrtrnrncnt gcrlonnraor only
BoId rcsultr trc grort.r thrg tbo t{DC
ir Botu1t lt gr:rcatcr Ehrn ceqllc drtrotLoa ltrLLt but
U Rcrult lr hu tban tho 3rnD,!6 dctootloa li.ml-t.
STL Denver
lcm tbrn ,uttd roDortlag llnlt,
15
Client Lot
Matrix:
Prnmrtrr
Iraboratory Control
Sovern Tront Laboratorl.u
Dsr090L89
WATER
qpfl. lnstmts trenrIt
Iotal
Ilaccrt.
(2 o +l-l
Saryrle ReDort,
- ttrdiochaList,r:xr
Irb 8r411o fD
0C Coatrol
t Yld t Itoo LllLt'r
Iso TlroRIIm (gEORlr er) DOt A-01-R ltOD
Thorium 2?8 8.81 9 -z
Thorium 23O 9 -{6 7 -7
Ttrorium 232 L 82 9.1
Ertclr I r 5ZS9]-]-4
eC!-lt
1.1
1-0
L-l_
l-01-R uoD
0,1
0.09
0. 09
fnrf,.yrlr Ilrtor
F5r160000-I.1tc
96
96
96
L04
82
103
( 91 L32l
( 65 1,29)
( 88 r.33 )
09/20/05
CIROSB l' BT CO-PRESrD
Gross A1pha
g!fitw 7110 DroD
20.6 1 6.1
Drteb lr 5260068
7110 lrOD
0.5
lnrlrrrtr Drt. r
sJr.L1 0000 - o68c
78 l1L 1{3)
09/2\/45
pcLlL,
2-7
OROSS .a'/B BY GlrPC
Gross Beta
EPt 900. o t[oD
52 .3 4,2 .2
Ertob tr 526n729
900. o !rcD
1.0
tr.grlyrLr Drtrr
r5r210000-129c
(7 A 121" I
pCLIL
81
09/25/Os
NCIIE t 8)
r l. dat.rahGd by lrlrtEust D.rforr.[o. @ly
C.lo!ilrrttoor rrc arrf,otrdl lrfo:rr rouadtag to rvold rourd-oll l:zoz l[ calgutrtrd r.mlta
STL Denver 15
Laboratorfr Coatrol 8aryrlc llCg DuplLcatG Rclrort
Scvcra rront Laboratortec - RadLocbmLrtry
D5r0901 89
WATER
Ctient Lot fD:
Matrix:
Drrrnottr Splhr twunt DuuLt t Yld t Beo
Irb 8rglle ID
9C Contsrol
r,Lnrtr ProoLrl'oa
fotrl
Ilncarrt.
(2 o +l-)
Rl,-228 Br CrPC tPt
Radium 228
Spk 2
90{ !iloD
5 .26
5.26
Drtob tr
gCLl[r
6 .42
6 -72
s253062
904 lroD
0.89
0_94
91 L22
89 1_28
lnalyrLr Drtrr
( 56 L47l
(s5 L47) 5
09 / 28/ 0s
r5r100000-062c
tRPD
Rr-226 BY EPL-9O3. O
Radirrn (72-6)
Spk 2
lroD
71_ -2
77.2
Bl'tob lr
t*!-lt'
10. 9
1,2 .4
5253061
903. O
1-3
L_{
DIOD
91_ 98
90 110
lnrlyrlr Drter
151100000-061c
(s{ 135}(54 136) L2
a9 /28/ 05
tRPD
Tota1 UrrnLrrn b1r
Totai Uranl-um
spk
KPr A8|[![ 517a-91
40 _ 0 38.22 9.00 g.zt
Batch {l I 52G221_7
u;fllL
'LT{-91 15r190000-2L7c
96 ( 90 LLzl
1_03 (90 L72) 729
laa}.yrLr Decrr 09 /2L/05
IRPD
4.5
0. 85
Totrl. Uranl-urn
Total Uraniurn
by ICPI ^trSTll 5L74-91
40.0
spk 2 8-0O
Drtob, tr
ufIlL 3L7t-91
97 ( 90 ltzt98 (90 112)
tnr1trrlr Drtrr 09 / 28 / 05
15r260000- 090c
133 TRPD
39.0
7 -84
5269 09 0
4.6
0-80
Ctlculatl.onr
STL Denver
rr. p.rforud boforo roundl.ag to rvol,C rouail-off .rnor hl orlcruhtrd rrtultr
l7
Client Lot fD:
Matrix:
Prnntcr
![trTnIX
Egrrern
D5 r OBA237
GIII\I
SpIkr
frcunt
SPIKE/}TTtrRTX SPIKE
Tront teboratorior
DI'PLTEIIET REPON]IP
r Radj,och@1rtrf,
Date Sampled:
Date Received:
gPIXI
lmult
totrl
II[orIrE. 85likr AN(PII
(7 o+ I -J r1d Rorult
09 / a7 / as 0955
09 / 08/0s 0930
0C 844>1r rD
tYIO tnc
![otal
Ihclrt.
(2o +l',
9C Coatrol
I.,lr{ tr
Total UraaLun
Tota1 Urarrium
blr KPl, t,glmfi 5
40-0
Spk2 40.0
urglL
13
L2
tnrlyrLr
5L7 l-91
56 .7
56 -7
drtsc r
6.8
6-8
09 /2]-/ A5
110 a
98
Ir 5262156
Dsr08 0717 -003
132 a (90 LLzl
1"03 (90 11.21
Prrsl;lonr L1 $RPD
Drtoh
GIROAA \ID BI TPC EPl' 9OO. O
Gross Beta B0{
spk2 I04
641
723
*r 526409A
eCLlt
59
7-l
r.arlyrlr
900. 0
39
39
drtrr
!iloD
L2
1,2
09/25/0s
D51100151-002
75
85
PrrcLrloar L2 tRPD
( 50 1s0)
( 50 1s0)
Batsolr
oRo8g l, Br
Groes Alpha
O
CO.PRECTP glmlw
4L .2
qpk2 4L -2
Drtob tr
49 .2
65 -9 &
s260033
ecL lt,
7 .6
9.97
larl3rnlr
7110 rilOD
2.7
2-7
drto r
U 2.L
U 2.L
09/20/05
D5r1 00151- 002
113 (50 1s0)
156 a (s0 150)
Prrcl,rLoo r 31 $RPD
nr-226 BY EPr-903 . O !!OD
Radium 12251 LL-7
spk2 11 _ I
10.0
9.4
Ertoh lr 5253048
pC;L llt
L -2 1_01
1, .2 L02
lnalyrlt
DIOD
J 0.17
ir 0 .L7
a9/28/05
D51100151 - 002903.0
0.39
0,39
drtr r
101 82
10i 77
(65 150)
(66 rsoi
TRPDPrcel.;lmr 5
Rr-228 rr
RadLum 228
G}TPC EPI, 90{ DIOD
5.52
spk2 5.53
7 _3L
6. 90
lr 5253 047
Dci/L
0. 99 89
0-94 96
.lnrlyglc
904 E00D
0.70
0 .70
drtor
Dsr100151-O03
6 IRPD
162 1. so )
(62 1s0)
J 0-37 93 720
J 0.37 93
rtrsl.rion r
09/28/05
L12
oRogg ^lB
BT
Gross Beta
grPc tPA 900.0
77 4A
Spk2 L-t 40
1690
1,6 80
lr 5264090
Dci/L
1_80
180
900. o uoD
95
9s
?,6
26
D5r13 0187 - 003
92
91
prrolrl.or 0 .5 tRPD
(s0 1s0)
( 50 l-so )
Brtch lorlyrLr drto r 09/25/05
TotsaL UnnLun by K"t lgDI 5
Total Uranlum {0.0
Spk2 d0 _ 0
36.3 a
35.9 a
*r 5269051
\g ll,
4.3
4.2
larlyrlr
517a-91
0.415 J
0. {15 J
D5r1301t7 -003
0. 067 90 a ( 90 LL2l
0. 04? 89 a ( 90 Ltzl
Drlcirl,onr 1 tRPD
STL Denver
Ertoh detr r 09/28l05
18
!{f,TRIX SPIKE/IILTRTX SPIKE
Sevem lfrent taboratorlcs
D5113 0187
GW
DUPLICATE REPORT
- RadtochuLtBtrryz
Date Sampled: A9 /L2 / A5
DaLe Received: 09 /L3 / 05
L222
0 915
Client Lot ID;
Matrix:
Prnrter eptlo
trnorrat
SDITE
Rrru1t
trotalIllrcrrt. BpLho 8I!IPL!
12 o+l-) Yld Rcrult
0C 8aq>h ID
t YLd, tR.o
lDotrl
UDcort.
(7o +l-l
Igo TIIONTT,DI ( EIIORT
Thorium 23A
Spk2
Thoriunt 232
Spk2
cr) DoE
9 -46
e .46
8-82
8 -82
7 -93
7.6
8.1
9-1
lr 5259047
pCi. /Ir
0.99
1-0
l-01-R DroD
93 0,18 ,J
91 0-18 ,J
0, 1.3
0.13
8d
84
D5r130187 -003
82
7g
(74 1.30)
(74 L30)
(81 L24l
124t
1.0 93 -0 - 008
1.1, 91 *0.008
rnrl.ytlr drttr
0. 053 84
u 0.053 84
DrcoLrionr
a9 /20 / 0s
Drcoirl.oar 4 IRPD
92
104
IZ tRPD
Drtob
NOTDE(g)
ta lrc cara aanrtlvr,
Cdoulrtl'oDt era ,I.8to3!.d, b.lora rol&AIlO to rrcl6 rgEd-ott rr=or ls c.16r1.t.d n.Irltr
r aDr.I.d .D.lr&. outrl.dr o! rtrtod 0e llnttr.
it Raault tr grretor tba! riqrlc Cct.otlor llldt hrt 1.rr tb.E .t.t.d rcfprtlog
]'r-gltt.
SEL DAnUel3 lot tb.! tbc rerrrlo drtootlo lttrtr.
STL Denver
Sample Receiving Checklist
O r**, Df?a7o-!-8 1-- pate,ryime*-.- ul zl,{f or oql= -
companyName & sampling r,r"'
-t]ilZS- LtlZ ,
PM to Complete This Section: Ies
Rcsidual chlorine chcck required:3
Nofr Quarantined :
Yes Noau
Quote #:
Special Insrructions.
Time Zone:
. EDT/EST . CDT/CST . MDTA4ST . PDT,PST . OTIIER
L-1 -] otis
IJnpacking Checks:
Cooler #(s): I '.' :3- L{ -- -(
Tenperarures ("C): T.5 --:-.f-
t'{, t{ V ?.,.->
^fob
- U I. Cooler seals intact? (NiA ifhand deiivered) If oo, document on CIIR-
3 2. Chain of custodv prescntT lf no, document ou CIIR.
.E' 3 - Bottles broken aod/or are leaking? If yeS, docurnent on CLB..
-J.d 4. Multiphasic samples obvious? If YCS, docr,rurent on ClrR.
tr 5- Proper container & presuvatives used? (ref. Attachment D of SOP# DEN-QA-0003) If no, document on CUR
O 6. pH of all sanples checked and meet requirements? If no, document on CtlR-
D 7. Sufficient volume provided for all analysis requested? (ref. Anachrnent D of SOP# DEN-QA-0003) If no,
document on CU& and contact PM before proceeding.
A 8. Did chain of custody agree with Iabels ID and samples received? If no, doctmem on CUR-
tr 9. Wcre VOA smples without headspace? If no, docurrent on CUR.
tr 10. Were VOA vials prescwed? Preservative OHCI O4+?"C DSodium Thiosulfate E Ascorbic Acid
{tl. Did samplcs iequirc preservation with sodium thiosulfate?
tr I2. If yes to #11, did the samples contain residual chloriae? If yes, document on CUR.
tr 13. Sediment present in dissolvedi/fiitered bottles? lf yes, document on CUR
tr 14. Is sufficient lolume prolided for cl.ient requested MS, MSD or matrix duplicates? If no, docurrrent on CUR, and
contact PM before proceeding.
15. Reccipt date(s) > 48 hours past the collection date(s)? If yes, notify PA/PI'/[.
16. Are aDalyses with short holdiug tinres requested?
17. Was a quick Turn Arounc (TAT) requested?
N/A Yes
Dd
d"
I
D
rJI
dfiuttr
Ttr
[trto
n
tr
tr
\QtrForms\Sample Receiving\Sarepie Recciving Chccklist l2 ll 04 revisionSTL Denver'12!13/04 20
STL Denver
Sample Receiving Checklist
C[JR, and
U
I]
fr
D
!
D
f
+
20. Did thc chain ofcusrody irrludes "reccit cd b)r' and "rclirrquirhcd" b;, signaturcs, datcs, and rirnes?
21. Werc special log in instructions rcad and followed?
22. \[,cre A]CEE maals logged for rcfrigeraled Erorage?
23. Vi,ere tests loggcd checkcd againnl the COC? \frtrich samplcs u'erc ccmfirmed?
24- \\/as a Rush forrn comprlctcd for guick TAT?
25. \\/an a Shofl Hold form completcd for ffrl), shor holds?
26. In'Suict ICOC' reguircd?
27. Wcrc special ar&iving instructions iudicalcd ia the General Commcnts? lf so, u,bal werc thc14
L*tu }{-r??o_/F'i
I.ogin Checks:
)liA )'es Na
+D18
qfi
t'
frd
EID
rg
Fut,r
D
tr
u tg"
Suflicicnt volrrrncprovidcd for all arrall,sir rcquc$ed? (rcf- Anachment D ol'SOP# DEN-QA-0003)
documcnt on CU\ and conlacl PJvl bcforc procccdirrg.
Is sufficient volunr providcd for dicnt rcguc.stcd l\,rs, h4SD or matrix duplicares? If no, docunrcil orr
coilact PM bcfrxc proceeding-
rfr
,gt
A
-P flnD
,wl
Labeliry and Stol:age Ctreeks:
!l 28. Iizas the subcoutract COC signed and ssnl witb ""qFles to botle prc4r?
! 29- ll,ae saryle labCs doublc-checked by a sacond persou?
3 30- '\lrcre raryle botlcr aud COC double clrec&ed for riissolred/fltcred metals by a second person?
U 31. Did the sarryle II), Datc, aod Time Aom hbd match u,bal u'as loggtd?
tr i2. Werc stici.ers for ryecial archiviug insruaions afrxcd to each bo>; aud to thc ILOC? Scc #27
D 33. Wcre AFCEEmads stored refrigcrated?
! 34. Itr/erc "Stict ICOC'copies givcn to Eatellite storagc areas?
Documeni anl,problens or discrepancies and the actions taken to resoive tbem on a Condition Upon Receip Anomaly
Reporl (CLIR)
STL Denver
f,m
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303 431 7t7t
ANALYTICAL REPORT
Western Zkconium Project
Lot #: D5I03OI44
Sheri O'Connor
URS Corporation
818I East Tufts Avenue,
Denver, CO 80237
STL DENVER
Linda L. Benkers
Project Manager
STL Denver
4955 Yarrow Street
Arvada, CO 80002
Tel: [phone]
www.stl-inc.com
Septanber 30, 20A5
Severn Trent Laboratories, lnc.
Table Of Contents
Standard Deliverables wtth Supporting Documentation
Report Contents
Standard Deliverables
(fne Cover Letter and the Report Cover psge are consldered integral
parts of this Stcndard Deliverable paclmge, Thts report is incomplete
unless all pages lndlcated in th{s Table of Contents are included.)
o Table of Contentso Case Narrative
o Executive Summary - Detection tlighlights
, Methods Summary
. IVlethodlAnalyst Summery
o Lot Sample Sumurary
. Analyfical Results
o QC Data Association Summary
o QC Sample Results
. Chaln-of-Custody
Number of Pages
Supporti ng Doc umentation
Check below when
cupporting
documentaflon is
present
(Note: A one-poge "Descriptlon of Supporting Documentation" i.s
provided at the beginnlng of thls section.).
r Volatile GC/]S
r Semivolatile GC/IVIS
. Volatile GC
r Semlvolatile GC
r LClll{S or HPLC
r Metals
o General Chemistry
o Radlochemlstry
r Subcontracted Deta
nmnnnnnE o
STL Denver
Case Narrative
D5I030144
With exceptions noted as flags or footnotes, standard analytical protocols were followed in the
analysis of the samples and no problems were en@lmtered or anomalies obseryed. All laboratory
quality control samples analyzeA in conjunction with the sarnples in this project were within
established control limits, with any exceptions noted.
The test results presented in this report meet all requirements ofNELAC, and any exceptions are
noted. This report shall not be reproduced, except in full, without written permission from ttre
laboratory.
Sample Recelvlng
Six samples were received under chain of custody on Septerrber 3,2A05. The samples were
received in good condition at tefirperatures of 4.3"C, 4.3oC, 4.2oC,3.6oC Lrrd3.2"C.
The results for all radiological analyses are included in this report and were performed by STL
St.lpuis; 13715 RiderTrail North; Earth Cify; MO 63045,phone [phone].
Radiochemistry, Various Methods
The rnethod 900.0 MOD gross beta MDA for samples D5I03014+001 through 006 was not met
due to reduction of sample size caused by high residual mass. The analytical results are reported
withtheMDA achieved.
Samples D5I030144-002, 005 and 006 were analyzed at a dilution for total rnanium due to
matrix interference. The reporting limits are adjusted accordingly-
A lowJevel and a high-level LCS standard were analyzd wiflr total uranium batch 5255166 and
they are spiked at different concentrations. Thereforg the RPD value reported for these two
standards does not apply. Both LCS recoveries were in conml.
The gross alpha MS perfomred on sample D5I03014+001 was in control.
The gross beta MS perforrned on sample D5I030144-001 was in con&ol.
All other MS/IVISD were performed on samples from other clients and/or lots and some were not
in control-
The duplicates performed on sarnple D5I030144-001 were in control for gross alpha and gross
beta.
STL Denver
METHOIN
Dsro30144
ANATYTTCAJ,
METHOD
PREPARJATION
METHODPARAMETER
Gross Alpha (COPRECIP) by GFPC
Groee Alpha /aet a by GIFPC
fsotopic Thorium by Alpha Spectroscopy
Radlurn -225 by CIFPC
Radl,um-zzB by ctFPC
Tota1 Uranlum By Ilaser Ph osphorLmetry
References:
sMww 7110 MoD
EPA 9OO. O MOD
EML A-01--R MOD
EPA 903-0 MOD
EPA 904 TUOD
A.gItvI 5L7 4- 91
EPA 900. O
ASTD{
EMT,
EPA
sMww
Annual Book Of ASTM Standarde.
trEI{\,IIRONMENIAIJ MEASITREMENTS LABORATORY PROCmURES It{lAliIlIeIn
EASL-300 28TII mIrfON, VOLTME I and rI DEPARTI{ENT OF ENBGY
NEAgTERN E}NTIRONMENTAL RADTATION PACII,TTY RADIOCHEMISTRY
PROCEDURES I'IANUAIn US EPA EPA 52O/S-84-OO5 AUGUST 1984
'' STA}IDARD METTIODS FOR WASTE WATERN
STL Denver
METHOI}/ANALYST
D5IO3(}144
A}i[ATYgT
ASI1'I 5L7 4-9L
EMIJ A- 01-R plOD
EMTJ A-OI-R MOD
EML A-01.-R MOD
EPA 9OO, O MOD
EPA 9OO. O MOD
EPA 903.0 MOD
EPA 904 MOD
EPA 904 MOD
SMMil 7 LLO MOD
Referenceg:
ASTU
EML
EPA
gMww
Mike Andergorr
.Tody Wateon
Rtronda Rldenhower
Rtronda Rlder*rower
Rhonda Ridenhovrer
Rtronda Ridenhower
,fimmy wilson
Bob Nicholae
Bob Nicholas
Bob Nicholas
AMITYST
rD
4023 s0
63903
060040
6004 0
050040
600{0
401627
a62006
52005
o62005
Anrrual sook Of ASI}I gtandards.
'BMRONMENTAIJ MEASUREMENTS LABORATORY PROCEDURES l'IAlilUAIrtr
I{ASL-3OO 28TII EDITION, VOLITME I and fI DEPARIT,IENT OF ENERGY
" I1ASTERN EN\IIRONMEI{IIAL RADIATION FACfLf TY RADIOCHEIITISTRY
PROCEDURES DAIItrA[-rt' US EpA EpA 520 /S-84-006 AUGUST 1984
IISTA}IDARD METIIODS FOR Y{ASTE WATERI'
AI{ALYTICAI
METHOD
STL Denver
SAIVIPIJW
D5IO301{11
SAITtPLED SAIVIP
DATE TII'IEwo*SAI{PI,E# CIJIENT SAMPI'E TD
Hirxo7 001
Hirxlc oo2
Harx].H oo3
H,JXIJ 004
HirJ(IK OO5
HirJ(IIYI 006
NOTE(S):
GW-R1- 090205
GTr-S9-090205
GT[- S8 - 0902 05
GTs- S7 - 09 02 05
clir-54-090205
GT[- 5B-090205
aela2/os oe:35
ae / a2/ 05 1o: l-o
ae / a2/ os 11: oo
09/02/as 1l- r45
oe/02/as r,2:45
oe/02/as 13:30
- Tho rDlytiql Icsrl$ of &c ramplcS Usled abovc lrG prGcntcd on thc following pagct.
- AII calorlatioru arc pcrforrncd bcforo rurndln3 o rvor roundofi errors In crlculatcd rcsrls.
- Rcsuh ootod cs 'ND" wcf,e noa d(leci€d el or abovo tho sr.rad limlt.
* Thlr repof nruet oot bo r€produccd. xccpf in firlt. without ll:o wido epproval of tho liboratory,
- RGoulIc for iba folbwing panrncrcrc arc ncvcr rcportcd on a dry wcight basis: color, conorivity, d€miry, tlrsbpolnt, l8nlbblllty. hycrs. odor,
p&inr fiItcr !E$, pH, pororiry prcsglr. rcicdvlty, rcdox porcndal. gocifr gravity. pot tcatr. slids, eolubility, Emporrture, vlscoslty. ed waigbf
STL Denver
Lab Saq>le ID:
Work Order:
Matrix;
Paralrttr
D5 r 03 01 44- 0 0l-
Hirx07
GW
B.rlrlt QurI
ToGrI
Unorrts,
(Z o+l-! uoC
Pr p rarlyrLr
f,bto Ilrtr Drtob I
IIRS Corporation
C1{ent Sanp1e fD: GIU-R1-090205
Scvern Trcat LaboratorJ.eg E nldiochcrl.rtry
Date Collected: 0 9 I 02 / 05 093 5
Date Received: A9 / 03 /05 0830
YI.d tr
oRog8 I'/r
Gross elpha
Orocr Bctsr
Er grPc EPI' 900. o tiloD
4.2 u
30. {
9_0
6.7
Dct/&
L6
8.1
900. o D[oD
ae / a9 / 05 09/13 /05 5252LO7
aelog lo|, 09/13 los szszLaT
lfotal. Ur+nl.rrm
lfotr]. Urerj.un
br KPt r'arDl 517{-91
0.899 ir o.093
u;gllt
o-!1
517{-91
09/13 lA5 Aellsl0s 3255166
OROSS t' BY EO.PruCIP gDtrITY
Ororr l'lphr 1.85
7110 ![oD
J o.77
DCLII'
0.78
7110 !0D
09108/05 a9la6los ,.25L17.,
Rl,-226 BY EPI-9O3.0 MOD
f,adl,unr l?.26) O.l9 4.72
pctlt
0.29
903, O ![oD
09106105 a91771or 52t9099 90
Rn-228 BY GIIIPC DCLIIg,EPt 90{ r[oD
1. gg
90[ ![oD
a9106105 09 lzalas 52{9100 BO
5256085 95
5255085 95
Iso THORfInil (SrrOnr
ThorLum 23O
Thorium 232
Gr) DOE r-01-R !ilOD
o.15 ir
o-o12 u
o.7 6
w,Ltt,
0 ,08
0.094
l-01-R lroD
09lL}to' 0el16/05
09/73/05 09/76/05
o.55
o.11
0. 04s
NorE (s)
lrc LnocEllrtr yltbrnr,t thr caa. ninatLvo,
Lr dotcrutaod by Lnrtn:arcnE, gorformraco only.
Bolal rcrult. rrc gra..t.r th.D tbc ttDC
tr *orult lr lrort.r ttao ruqrlo drtootlon ].lr{t but l..r Eb.rl rtrtrd rrlprtl.gg Ifuilt.
U lcr;ult lt l.or thr! thc rurgrlo dtleotlon lldt.
STL Denver
URS CoEporatLon
Clicnt Samole IDr GIil-R1-090205 DUP
flevern Trent LaboratorLaB - Radtochemri Btry
Lab Sampl-e ID : D5 I0 3 01 44- 0 01X
Work Order: HJX07
Idat,rix; GW
Date Collected:
Date Received;
a9 / 02/ os 0935
ae / 03/0s 0830
tarlyrlr
Dut.Parrnrtrr Rorrrlt
Totrl
Uuo.*-
(2 o+l-l
PraD
Drtr natch t
oRosg A Br CO-PRECIP slilWW 7110
Grorr l1phr 1-01
IDD
a,
*Llt 7110 !!OD
09 lo8l05 0911,6 las 57sla7.,0.65 o-86
onog8 r'fs Br
Glrorr Botr
GPC EPI. 9OO. O ITOD
30, E
DC.Lltt 900-0 uoD
09/09 lag 09/13 las 52521077.L 8.7
!rcrlt (g )-l
Drtr rrc lacqllotr rr.thortt th. oaaa nlrrtlwa-
tog fr drtrrnLmd ttr LEatauD.Et porf,or:trnoo ooly- V
Eold rrrultr rra gEattGr thrrt th. EC
ir '. n .ult ,.4 elrcalc thra .rB[. d.t.ctr.oE 1lnrt but l.aaa tb& rt.t.d roportlag ll"Btt.
STL Denver
IIRS Corporatl,on \
Cliant Sample fDr GTil-S9-090205
Scvern Trcnt taboratorLeg - Radiochdatgtry
Lab Sample ID:
V[ork Order:
Ivlatrix:
Prrurtcr
D5r030744-042
H.I(1G
GhI
Rrnrlt qrral
Date CollecEed:
DaEe Received:
a9 I 02 / A5 L010
oe / 03 /05 0830
Pr.D fulyrlr
f,ntr Drto Drtoh
$otrI
Ir4oarit -
(2 o+l-l I Ytd r
GIROAA AIE_ BT GFPC
Ororr lctsr
EPI 900. O t[OD
27 .l
Dtci-lL 900 - o l[oD
ogloeloS 09/13 lo5 52521071-u
trotrl UrenLun b[r
lPotal Uraniurn
KPn .nsru 517t-91
-o-35 u
ug lr'
0. 1,0 0.62
5174-91
a9tL3/A5 09/L5/05 5255165
gRosg A BI co-PRrcrP gloil 7110
(iross Alpha 0.30
PCLIL
0-51 0-85
7110 !@D
09 /08/05 a9 /L6/A5 525L474
!@D
U
nf,-226 BY fPr-903 - 0 troD
Radium Q26) 0-15
plCLlt,903 . O !@D
a9 / 06 / 0s 09 /22 / as 5249099 1000. 18 a.29
RL-228 BY OrPC
Radium 228
EPr 90{ uoD
-0. 01
eeLly-l 901 lroD
a9 /a6/05 0e /22/a5 52491000 - a9
0. t5
0-05L
oCLlt
0. 84
o. 09
0.11
77
I;o THORTIffi (sHoRtr er) DOE l-01-R DIOD .L-01-R ![OD
aglLSlas 09116105 5256085
a9tL3/A5 09 /:-6/As s25608s
lfborl-un 23O
Thorium 232
o-2{
0- 014
87
87
i,
U
rro{Pf, (g}
tr rre l.aooqrlrtr rl.thorrt tho oeto nrnatl.va.
1r dotrr:aLnod bff Lurtrumrot pufoaoanco on1y.
Bold taau]'tr rrc !E at.t thr! tb. I@C
a, R.ruIt Lr Err.rt.r thll rqrlc drtooul.oa l.ttdt hrt 1..r tbltr rtrt.a roDortl.ag llEtt-
U R.rult Lr lccc thr! tD. .uEI. datcotr.oo ltDtt.
STL Denver
IrRg CorporatLon
Client Sarple ID: GIS[-S8-090205
Srvern l[rcat LaboratorLer - RadLochmigt,rt,
Lab Sarrple ID:
Work Order:
MatrLx:
Paranrtrr
D5 r 03 01,44- 0 03
HJXlH
GTf
Brnllt Qrrel
Date Collected:
Date Received:
09 / 02 / os LL00
ae / 03 /05 0830
a.totrl
Unoort -
(2 o+l-l
Prrp latlyrl'r
Date Drtc Drtoh I I1A t
cRogg ,.IB BY
Ororr Betr
ffi9c EPt 900-0 ![OD
91
gc;LIIg,900. o ![oD
09109 lo5 09113 los 5252107
Tot,a1 UnnLuu b1l'
Tota1 Urrnl,un
KPl' .Agn[ 517{-91
1{. g
u9lrl,5L7 l-91
aglLrla5 09/15 lar 5235166
gRoaa ^l' By eo-pnf,erp 8!0IIT 7110 ![OD
Oror Llpbr, 12.8
Dct/r,7110 ttr)D
oslastos 0glr.6ta5 525117{
Rl,-226 tr EPt-go3.o tloD
Rrdiuu (226) 0.{3 o.72
pCl-/r
o.29
903. O lrOD
o9la6lo5 g-el72lo5 5249099 96
Rn-228 BY GIrPC
RrdLtru 728
EPt 901 uoD
1 .1a o. 51
Df;LIL
0.76
90{ ![oD
09l06ta3 0912214|, 52{9100 76
Iro EIIORIIffi (SHORE Cr) DOE I-OI'-R ![OD piCt llt l'-ol.-R ![oD
a9lltlos 09l!6145
09/L3/A5 09t]-6/05
5255085 A7
5256085 87
Thoriun 23O
Ttrorlum 232
0.15
0-009
ir
U
o. 12
0. 054
0.09
a _L2
No|rf, (s)
DaCa aro l.noqrlctt rLthout thr ouo Dlrrrtlvr.
uIrc ir drtoral,ncd by Lurtnrnrnt plrfornaacc oaly.
BoId rcrultg lr. grrrrttr thrn thc tdDC
.r Rorult Lr grortrr thl- raq>lc dctcotLon ltmlt trut
u Ruurt, Ls lcrr tbrn thr mugrh drtootl,on Il,nLt.
STL Denver
lorr tbrn rtrtGd rcDortlng Il.mlt.
IIRS CorporatLon
elicnt Sampla IDg Gfil-57-090205
Scrrarn Trant lra,boratorlce - Badtochmigtry
Lab Sample
Work Order:
Matrix;
Pr,faLltt.r
ID: D5I03 0I44- 004
HJX1J
GW
IrmrIt
Date Collected:
Date Received:
09 / 02/ a5 1145
og/03/0s 0830
PrrD tnalytLr
Datt Drtr Brtob I
Totrl
Irlloart,
(? o+l-l
crnosg ,.IB Br orPc
Ororr Bett
EPt 900-0 !00D
17 .6
pcllt'900 - o D[oD
oelo9los 09/13 l05 5z57LO75.1
Totrl Urrul.um b!t,
Total Uranium
KPl, ngmrI l74-gL
0.144 U 0.015
ug llt
0.31
5L7 l-91
a9 /L3 /A5 A9 l]s/Os 5255165
oBogs t BY
Groes Alpha
co-PREcrP 8ttrn{ 7110 t@D
0.54 U
Pcr.lt 7110 ![OD
09/a8/a5 09/t6/Os 525L4740.70 1-1
Rl,-z?6 BX EPr,-903-O t@D
f,adltun (a25) O -29 0.18
gc!.1r.
o.26
go3 - O uoD
09106105 a9t72l05 5219099
R.l,-228 Br orPc
Rad.Lum 228
EPl. 90t r@D
0-34
DCl/t
0 _ 73
90{ lroD
09/06 /a5 ae /22/ 0s s2{e100
IBo TIIORIIII (gIIoRT g[) DOI' .L-ol-R ltOD
o .57 ir
o.la i,
o -44
o-26
o.11
*LtL l-01-R
09 tL3 los
a9 tll I O5
DOD
09lt6los
09/16 IOJ
!ftorl.un 2tO
'l[horl.uu 232
o. 07
0.11
52360C5 7L
5235005 71
NC}.:[E (s)
ta ara luoq>Lat. wLthout tha oare trarratlvt.
HDC Is dotorziaod by lIrrtrrmrnt porlorrnrnoe ouly.
BoId rolulEr lrc Efrcatrlr tL"' thr IIDC
if Rrtult Lr grratcr f,hrn rergrlr drtootLoa l{ml q but
U RoruIE Lr lur thrn tbc larErla drtootLoa lfuliE -
STL Denver
lcrr thaa ;tetod rrlrortlng Ij.mLt.
10
URS Corlpration,
Client Samle IDr GIIU-6JL-090205
Srvorn 8rontr IralroratorLu - Radl,octreml BtE-IZ
O
t ab Sample ID:
Work order:
Matrix:
Drrruatcr
D5r0303,44-005
H.TXI-K
GW
XrruIt
DaEe Collected: 09 / 02 I Ab
Date Recelved: A9 / 03/05
L245
083 0
llotaI'
Ilacrtt.
g4lr1 (2 o+ I -) fOC
Prrp larlyrl,r
Dato Dttc Ertoh f I1d, i
oRosa ^lBOrorr Brtr
BY OIIPC tPf, 900. O It OD
1180
ecllI,
130
900. o ![oD
agtogtos oel13 las 5251107
Tot,al UranLun bUr
Totrl Urrulrrm
K"e rsmr 5L7l-91
73.g
ttgII.r 3L7 l-91
o9/1t tol 09/15/05 5e55166
CROgg .[' ET CO-PRTCIP gUgTW TLLO lMD
Gror tlpbr 12.3
ECLIL 7110 lmD
ogloa/a5 a9 I 15/05 5251{7.1.1
Rn-226 BY rPt-9o3. O !{oD
xld,Lrm (226) {.29 o. 6l
r>Ci/r,
0.19
903.0 t@D
oelaFlos 09l2alo5 52.909e 83
Nr..228 BY GrPC
Rrd{urt 7z_lB
EPl, 90{ r[OD
4.85
pctlt,
o.85
904 ltoD
a9l06l05 091721a5 52{e100
Ioo THoRrtm (8HORI C]r) DOI! .['-OI.-R
lllb,orLrrm 23O 0.20 iI
Thorium ?32 -0.004 U
o.83
o. 13
0. 043
Dct/t
o. 0g
0.084
l-01-R ![oD
09/13 lO5 A9lL6lA5
09 / L3 / A5 0e / 16/0s
5256085 9l
s2s608s 94
NCxEf, ( g)
Irttr ra. ,,Bqrl.it. yltbolC thr eur arrrrtl,vr.
UDc l.r dctotrLB.d by laalnumt gorforuraoo only.
BoId r.rulta .r. g':r.rt.r thra lbc t{DC
i, ncrult ,.r g:..rtcr thau rrqrlr drEootlos llDl-t bnt 1..r tlrD rtsrt.d rqprtlag Unlt.
U R6alrlt, Lr 1ot. thrs thG rcry>lo dotrstl.oa ltlrlt.
STL Denver
URS CorDoration
Cl,l,ent Saspl.e ID: GT{I-68-090 zOs
flsrrcm, TrGnt raboretorLag - RadLochgor-Bt,taz
Lab Sample
Work order:
Matrl.x:
Drraantrr
D5r030144-006
Hirxl"M
GW
trrrult
DaEe Collected:
Date Received:
a9 / 02 / a5 1330
09 / 03 /05 0830
lsrlyrll
Drtc
ibtal
[IEorrt.
(7 o+l-l
Prrp
Datr lrtsb I
gnosa l,lB BY
Gror Betr
orPc EPr 900.0 lioD
1150 ?LA
ocLlt'
230
900. o !iloD
o9lo9 lo5 09 113/05 5.757LO7
Total UranLun
Totr1 llrrnl,un
bry I(Pn .f,gfil 5L71-91
?L -7 2.3
ulslr"-
o,6
5L7 4-91
09/13 lA5 09l1'5l0s 5255166
onosa I. By eo-DRtcIp gDlrfvr 7110 ![oD
Grorr f,Ipbr 3.2 2.0
*Llt'
7.7
7110 noD
09/o8/o5 091L6l05 533117{
nf,-226 lY EPI-gO3 . O lrOD
Rrdl.un 17,26) 5.37 0,90
rrC;Llf'
o-3{
903. O MOD
o9to5lo5 oel?,zlal, 52{9099
Rn-228 BY grPC
Rrdluu 228
EPt 90t t[oD
15.1
Dctlt 90{ t{oD
09to6to5 aelz2lal, 3249100
fro trHORIIrli
?ftorLun 2!0
fhorium 232
(grroRT cr) Dor
o. 15
-0-0L
r,-01-R ![oD l-01-n
09/13 I Os
a9/L3/05
t@D
09 n6l aJ
a9 /t6 / 05
2.0
o.11
0-062
Dci/L
1.O
o.1
0. 14
52560t5 93
5256085 93
NC[.E (S)
tr ara Lnoqlhtso r:ltbout tho oar. urrrts:lwr.
7
IilDC lr dotrermlnod by Inatnrmrut lnrlormrrnor oaly-
BoId r.ml.tr rac gEcrt.r ttr! fb. EC
U n ruIt L. grrartGr tbrD rqrl. dLt.ottor ttdt tnrt 1.r' th.Jr rtrt.d rqrcrtl.ug ll^'dt,
U R.ru1t lr lora tln'tF tb. rrqrlo drtrotlo IIEIE.
STL Denver \2
ACDATA W
D5ro30144
gamp1e Pretrnratlon and enalyeis ConErol Numbers
SAI{PIrE*I,IATRIX
001
002
oo3
o04
GV{I
GTII
GW
GII
GTg
GTI
GW
GW
GW
GW
GW
GW
GW
GW
GW
G9T
GTI
GTI
ANAIJYTICAI.,
MEflIOD
EPA 9OO, O MOD
ASTI{ 51-74 - 91
sMww 711"0 MoD
EPA 903 .0 IIIOD
EPA 944 MOD
EMt A-01-R ltoD
EPA 900 .0 l@D
A.gTTU 5L7 4- 91
SMhIW TLLO T'TOD
EPA 903.0 IYIOD
EPA 904 MOD
Eltfltr A-01-R MOD
EPA 9OO. O MOD
ASITvI 5L7 4- 9L
sMB{r0 7110 MOD
EPA 903.0 MOD
EPA 9O4 MOD
EMII A-0L-R MOD
EPA 900.0 DlloD
ASTI'I 5a',7 4- 91_
sM?{w 7110 tvroD
EPA 903.0 F'IOD
EPA 904 MOD
EMII A-01-R MOD
EPA 9OO. O F{OD
ASTM s174-91
sM[!m 7110 MOD
EPA 903. O MOD
EPA 904 MOD
EML A-01-R MOD
EPA 9OO. O MOD
ASTM 5a74-91_
gMstw 7110 MoD
EPA 9O3.O IyIOD
EPA 9O4 MOD
EML A-OI-R !,IOD
IJEACH
BATCH #
PREP
BATCH #
5252LO7
5255 L65
525L474
s249099
s249100
52560 85
5252LO7
5255 166
s2sl47 4
s249 0 99
s249 100
5256085
52s 2LO7
5255166
525L474
s249099
s249100
s2550 Bs
5252r_07
5255 15 6
525 L47 4
5249099
5249L00
5255085
s2s2L07
szss 16 5
525L47 4
s249099
5249L00
5256085
5252147
525s 1- 6 5
525L47 4
5249099
5249100
5255085
MS RT}N*
s252A55
5255L42
525L32L
5249 05 5
s249 053
s?s6L42
s2s2055
s2ssL42
s25L32L
5249 0s 5
5249 0s 3
s256L42
52520s5
s255L42
52513 2 1
52490s5
5249 0s3
525 6L42
52s2055
s2s5L42
s25r-321
5249055
s249053
s25 6L42
5252055
5255L42
s2s132 1
5249 05 s
s249053
52s6L42
525 2 055
525 5L42
5251"32L
5249055
5249053
525 5L42
00s
005
GTI
GI![
GTil
GTU
GT'I
GI{
ctw
GII{
GW
GW
G[lI
GW
gw
GW
GW
GT.iI
GW
G}T
STL Denver
ClLent tot fD:
Matrix:
Prrurter
UETTIOD BI,A}IK REPORT
Lalrorator:Lcs - Radl,ochtunf. rtrryr
Irrb B.q>b ID
r[eI.y.Lr
Datr Biteh I Yld t
Sever:a Trcat
D5r03 0L44
WATER
RrarlB $rrr
ltotrI
Ilncrrt -
12 o+l-l
Prrl}
ILtr
n -2X8 BY O'PC
Radium 228
EDA 90{ IIOD
-0_06 0.38
Dct/L 901 !rcD
0 - 66
15r060000-1001
09/a6/os a9/22/A5 s249100 83
Rt.-?76 BY EPI-903-O ttoD
Radium (226) 0. 02 0 - 1L
gC,Lll'903. O ltoD
o -2L
r5r060000-0991
09 I A6 / 05 09 I 22 / A5 5249099 L02
qRoss .il'/s
Gross Beta
BY OFPC IEPI' 900 - O ![OD
0.20 u 0, 93
pCLlt'900. o ttoD
1.5
r5r090000-1078
09 I 09 / 05 09 / L2 / A5 52s2107
GIROSS A BT CO-PRECTP gDiMlV
Gross Alpha -0 - 04
7110 UOD
U
ecl.lI,J,7110 t[()D
a -670.35
r5r080000 -17 lB
09/08 /05 09 /\6/ a5 525L474
Tstl]. Uranir:n lrlf l$I. tSfU 517{-91
otal- Uranium -0 - 100 U
ug lr'
0.013
5174-91
0.31
15r120000-1668
09 /L3 /05 09 / 15/0s s2ssL66
Igo TIIORIIIU (8HORT ef) DOII .8.-01-8 DIOD
Thorl.rrlr e3O O.21 iI
T{rorium 232 0.0 U
o.1l
0.0
Dc!"1\,A-OI-R IIOD
o. 09
0.06
15r130000-0858
oel13 IOJ 09 lt 6IA5 5256085 87
09/L3/A5 0e/76/05 52s608s 8?
(s)
lr. l"oq>lrto wLtbouts thr catr nanatlvr.
XDc Lr dctcrrluod urLag lartnrat porloanuoo ooly
BolA aaruIt,. rr. g?.rtcr thr.a tsh. f,Dc
.r Rc3ult lr grroetor tbra ar4rl. d.t.oEL@ ]'ttt1t brrt lorc tban rtrtcd r.flortlag 1t6tt.
U n rult l. lo'r thrr tbc srrlE,'lo d.t.dtl.oa lLlltt.STL Denver L4
ClienL LoE
Matrix:
Prrrnrtor
Iraborattlr1r Control"
Severrn, Trent t aboratorl,er
D5r030L44
WATER
Apthr .Brcrrat Duult
TotrI'
Uaotrt.
12 o+l-l
Saryl1c ReDort
r Rldj.och@Lgtry
O
I,rI, Eaqplr ID
0C Control
t YIA t trrs f.tul'tr
R^-226 BY llPf,-903. O
Radlum (2261
DIOD
LL.2
aatotr tr
pCL/tr
10.7 L,2
524 9099
903. o DIOD
0-2
^Itrl.yrr.i DiEct
15r06000()-099c
(54 136)109 95
09/22/05
nr-228 BY orPc
Radiusr 228
EPf, 90{ UOD
5 -27
Bctoh lr
D,f,LIL
5.01 0. 85
s24 e1 00
90{ tloD
0. 69
lnalyrLr Drtrr
15ro50000-100c
90 r_14
09 /22 /As
(s5 L47)
ORO88 l, BY CO-PRTCID
Groes Alpha
glotw 7110 lroD pcLlt,
2A.6 19.4 2-3
Barorr lr 5ZSL474
7110 !frOD
0.5
laal.yr:Lr Dator
r5r080000 -17 lc
( 71" L43 )89
a9/16t05
CIROgg AID BY
Grogs Bet-a
cIrPC EPt' 900.0 UOD frC,LlI.
105 1 06 11
rrtolr I r 5252107
900. o DloD
L
larl,yrlr
101
Drtrr 09 /12/05
r5r090000-107c
(70 ]-zLl
Iro ![EOnfUll
Thorlum 228
Ilroriun 23O
Thorluur 232
(gIIoRr cT) Dot f,-o]'-R
I .81
9 .46
8. 82
lrtelr il r
A-OI-R MOD
0.1
0-05
0. 05
lnrlyrl.r
93 104
93 BB
93 LOz
DrEor 09 /16/05
r5r130000-o85c
(e1
(6s
(88
DTOD
9-2
8-3
9.0
5256085
DC,LIr'
1.5
1-3
t.4
132 )
729t ..
r.33 )
O
![o|rl (sl
XDC Lr dttoralard, try, :lnatrrrrrnt DrrforDrao.
Caloulrtlo-t arc Dorformd brlorr roundiugDenver
oaly
to avoid round-off, orror J.a oelou]'etod rotultrSTL
Laboratorlr Control Saryrle ll.,C,g oupLicato RcDorU
Scvrra trrnt, Iraboratorlcg - Rnd,l.ochgttrtra,
D5r030L44
WATER
Cl-ient Lot ID:
Matrix:
Perartrr
Totsrl
IInoart.
g5>ttrr tlonat, Rmu1t (2 o + | -) t Y1d t lro
LtI, 8aryrlr II)
QC Coatrol.
Llnr.tr Prcclrion
Total Uraniun brl,
Tot,aL Uranium
spk
Kpr r8r!I 5L7{-91
40.0 4a.72 9.00 7-30
Drtsh Ir 5255156
uiglL 517{-91
4.8
0. 75
1.02
91
lsrlyrlr Dttrr
r5r120000-156e
( 9 0 L1'21
(90 L1,2 ) 139
09 /L5/ 05
tRPD
l[0rl! (8)
. erlculatlor rn p.rforlrd D.for. B|,Eldllg to .vor.d roud-off arror I[ oaloul.t.d r..uIta
STL Denver L6
Client Lot Id:
MaErix:
Prrmctor
D!f,TRTX SPTKE
Severrn Trent LaboratorLeE
D5r03014{
GW
REPORT
nadt ochmLetrlz
Date Sampled:
Date Recej"ved:
Iot,rL
Uaecrt.
(2 o +l-)
Eplho
l,lurnt
8piko
Rtrrrlt
ToEal
Unorrt. &i.kr 8rryllo
(7a +l-) nd' Rrrnlt'
ae/a2/05
a9 / 03 /0s
AC 8rryrlo ID
IYTJ) IREC
AC Coatrol
LLttl.tr
gRogg t' IY CO-PRECIP
Groes Alpha
DIOD
31--8
f: 525L474
stww 7110
4,L.2
Batch
ncr-71
4.?
7110 UOD
1.95
sis Dat,e I
0.77
09/16/05
D5r0301{{-O01
73 $7 133 )
Anal
G'ROS8 ,-IE BY SFPC EPA
Gross Beta
900. o !0D
804
Batch #:
900. o !!oD
30.{6-7
D5r0301{{-oo1
88 ( s0 1s0)736
5252147 Analvsl,s De Ee:09/L2t05
-//
NCXIE (8)
Data are incomplete wlEhout.
Calculations are performed
the case narrat l-ve -
before rounding to avoid round-off Glrrors
STL Denver
ln calculaEed resulEs.
Client Lot
Matrix:
Danllter
!,IATRIX SPIKE/!.TATRTT SPIKE
geverm, l[rerrt IraboratorLcg
D5r 020209
G'til
DITPrTICITE REPOntr
r Rrdiochcmtstry
DaEe Sarnpled;
Date Received:
oe / 0110s L2r0
09 / a2 / 05 0900
AC Earyllo rD
t grdr tnoo lijft="tqplt
lnouat
8PIf,T
Rrrul't
lotr1
Ilusrrt. gllllc SfXPLll
(7 o+ t -) Ild Run'lt
IcotaI'
llnclrt.
lAo +l-l
Rl,-226 Br fPA-903.0
Radiurn (2261
SPk2
ItoD
11 -5
LL.7
Batclr
pcLl,. 903-0 uoD
0.20 74 0.01 u
D5r030209-010
0.30 J
A.2L U
Ir 5249055
a
a
0,13 7L 2
0.13 7L 2
a ( 55 L50)
a ( 66 L50)0 - 18 75 0.01
.larlyaLr drtc r
u
a9 /22 / 05
PrroLrl-oor 3d tRPD
Iao TIIORII,U
Thorlum 230
spk2
Thorirrm 232
sk2
(gnonr cr) DoE
9 .46
9 .46
8.82
8. 82
Drtob
8.0
7-8
8-5
9-0
I r 52561-42
Dct/L r-Ol-R uoD D5rO2O3O9-O1O
1.0 9L 0.23 J 0-16 72 82 fig 130)
1-0 86 0-23 ,J 0-15 72 80 09 130)
Prrnl,rl.oar 2 tRPD
1.1 91 0.026 U 0.072 72 g'I (?0 L28)
1_1 BG 0.026 u O-A72 72 toz (70 LZS!
DrcqLrior 5 IRPD
.f,srIyrl.r drtcr 09/16/05
Rt'-228 Br OrPC tEI' gO{ UOD
Radirrn 228 5.43
spk2 5.49
lrtoL ilr
L-42 a
1.27 a
5249 0s3
Dc;LII,,90{ }roD
0.57 66 1-04
0 - 55 66 r..04
.}anlycir d.e,tar
0- 60 61
0-60 6L
DnoLrLoar
09/22/45
D5r020209-010
-0.4 a 162 150)
4 e $2 150)
22 IRPD
lsorE (8)
ara tsbrr car ntl5it{yi-
lcu,latlG,. rr. tartor.D.dl bclora rorailaor to e?ol,(l rqud-o!! onc ta crlahtrd r.fnltt
r Eptkcd rhrlyta oNrtrl.d. o! rtrlcd QC lLnltr.
i, noault ,.r grr.oitcr tb.[ .alD].a dctoctloa ll8lt but l..r tbr! .trt.ll rc5rortlag
I'tDl,r.
SltL Bll,nft€b lc'. tbra th. ,.ryrl. d.t.otLoB thtt.1B
Client Lot
Ivlatrix:
Darantlr
![rTRrx
Severn
D5r 420249
WltI
ApLko
lootrnt
IotrI
Irro.rt, E5rLlsr Eftplfi
(2 a+ t -l Yld' n"rult
SPIKE/UITRIX SPIKE
Trent Laboratorles
DIIPLIEATE RIPORT
RrdLochmistry
Date sampled: 09 / 01/ A5 l-515
DaEe Reeeived: 09/02/OS 0900
SPIIE
Rrrul.t
Totll
flbcrrt.
(2o +l-l
AC 8ary>h fD
9C Coatrol.t YI,d trr.o L{ q{ tr
Tota]. Uranirrm lytr IEPI,
TotaL Uranium
spk2
r8r![ 5
d,000
4 000
Batsh
3590 a
3850 a
I r 5255i-42
r:lglr' JL7l-91
230 50{0
460 5040
rnrlyrlr {lato r
D5r020209-002
-35 a (90 11"21
-30 a (90 L12)
Prerohloar 7 IRPD
500
500
a9 /15/ 05
Rl,-226 Br tP.l.-903. O Dloo
Radlum (226) 11 ' 4
spk2 tL - 4
30.2
32-2 E
rrtoh tr 5249055
p,cllL 903. o !@D
3 .3 77 15.1
3-5 69 1,5.1,
Dsr020209 - OO2
73 133 (66 Ls0)
?3 151 a ( 6G i.50 )
PnoLriou,r 7 tRPD
1-8
1.g
lnrlyrl; drtrr 09/22/05
nr,-279 BY
Radirmr 228
:
oFPC tPt 904 ![oD
5. 3d
Spk2 s.3s
p,CLIJ./.
2-L 64
2 -A 59
.trnrlrrrfu
90{ !iloD
10 - 2
LA.2
dlte r
D5rO2 0209 - 002
Datgb *r
77 -9
17. 0
524 9 053
1.3
1.3
64 14s
6i L26
Prooj.rloar 5 $RPD
(62
(62 L
09/22/05
rao TIIORII,II ( SIIORT
Thorlum 23A
spk2
Thorirrm 232
Spk2
er) DoE
9.46
9.46
8_82
8-82
Datch
gELll, I-OI'-R
L.7 55 3-57
1.6 58 3-67
1-5 ss 0-66
1_{ 68 0_65
rnrJ.yrlr drtrr
Proolrlo,r
\T 0 -29 65
J A.29 55
Prrohl,oar
a9 /16 / as
D5r020209 -O02
79 a (79 130)
11 IRPD
L0? (70 128)
102 fiO 128')
5 TRPD
11 ,1 a
12 _5
L0.1
9-5
lr 5256]^42
a -74
0 -74
65
65
NorE (g)
Drtr ara
Crloulationr
r splh.d
J Roru]-t
cro plrfomrd boforo rouadlag to evold round-off arlror La orlsrrhtrd rerultr
ar,alpo outrLdr of rtatod eC llrnLtr -
Lr grrcatGr tbea rrqllr drtcctl,on Ifurit brut lotr thrn rtrtcd roDortf,ag
AH_ -l.lnLt.SU'l., H$ny€Fl rc;a rhan tshe reqerr drrrorLon rbrtt.
IX'P',ICTTE E\TTIJ'LTION RIPORT
Serrem l[reat Laboratsorirg - ir6i6strantrtrlr
DSI030144 Dale Sarnsrled: O9/A2/05WATER Date Reeeived: 09/03/05
Client Lot, rD:
Matrix:
Pr,rurtor SfXPLI3
Itorult
ToErl
Unctrt.
(2o+l-l
DSDLIef,I!
t I1d lenrlt
TotsrI
Ihclrt.
(2 o +l-,
Qe 3rryrlo rD
PrurirLoat Yld
GTROEg I. BT EO-PtrUTCIP
Gross Alpha
stsrw 7110
1 .85 ,I
Brtob lr
!@D sCLl\,
4.77
5257474 (sarple)
7110 D|OD
1 .01 .] 0 .65
525L47 4 (DrplicaEe)
D5r0301{{-001
59 IRPD
GOAS ,.IE- BY
Gross Beta
orPc tPt 900,0 trcD
30-4
SetcL lr
Dcl /L
6-7
52521"07 ( SarnPle )
900. o lDD
30.8 7.L
52527A-f (Dttpltcate)
D5r03014{-001
1 IRPD
rrr Lncq>I.at. vltborrt tlrr oara urrrt:l.vt.
Caleulat,lou aro Dorfomd Drtom roundLug to tnot0 rorad,-ott
J' Rr;ult lg grrertrr thra trogh drtootl,ou ltantt brrt
STL Denver
crrotr tu calculatrd rerult;
lcm tbtrn 3titcd rGDorttng ltmlt.
20
STL Denver
Sample Receiving Checklist
Lot#: DsTo 3"1 v V'Darerl-imeRecei ""a, 1 /.5/-Z{ - O ffiA -)
Company Narne & Sarnpling Site:
(*<_gJ*t4 ?;rc..
PM to Cornplete This Section: Ies
Residrnl ctrlorine check required:E
Quote #:
Special Instructions:
Time Zone:
. EDT/EST. CDT/CST . MDT/I{ST . PDTIPST . OT}IER
Quarantined :
Yes
u
No
D
Unpacking Checks:
Tenperatures (oC): % 3
N/A Yes No
"( ,< - Lk--3.C ie
5-
fiio*'Ol. Cooler seals intact? tNlA if hand delivered) If no, document on CIIR
2. Ctain of custody prcseut? If uo, document on CLIR.
3. Botfles brokeu andlor are leakiug? If yes, docuureut on CUR
4. Multiphasic saryles obvious? If yes, docr.nnent on CUR.
5. Proper coutainer & prescrvatives used? (ref. Attachmeut D of SOP#DENQA-0003) Ifno, docrunent oo CLIR.
6. pH of all sarryles checked and meet requiremenB? If uo, docunent on C[JR-
7. Srf6cient volume provided for all *nalysis rcqucsted? (ref. Attacbment D of SOF# DEN-QA-0003) If uo,
docurnent ou CU& and coutact P.M before procceding.
8. Did chain of custody agrcc witl labels ID and saraples received? If no, docurocut on CUR-
9. Wcre VOA sarrples witbout beadspace? If no, documeut on C[IR.
10. Were VOA vials presewed? Prescrvative OHCI CJ4-|-2"C DSodiumThiosulfate D Ascorbic Acid
11. Did samples require preservation with sodium thiosulfate?
12. If yes to #1 1, did the samples contain residual chloriac? If yes, documcDt oD CUIL
1-1. Sedirnent present in dissolved/{iitered bottles? If yes, document on C[iR.
14. ls sufficient volume provided for client rcquested MS, MSD or matrix duplicates? Ifno, document on CUR, and
contact PM before proceeding-
15. Reccipt dat($ > 48 hours past the collection date(s)? lf yes, notif PA/PM.
I6. Are analyscs with short holding hnes requested?
17. Was a quick Turn Aromd (TAT) requcsted?
OPil
brf,T
cc
cfI
I)tr+D
CD
Jf
qr r
Crr o
Dq
E!
fD
OE
rlq
loq
iICU
\Q!\FontrsSample Receiving\Samplc Rcceiving Chccklist I7 13 04 revisionSTL Denver t2n3t04
o
STL l)envcr
Sample Receiving Checklist
Lotu -Iffo3:tv<
Lngro Checks: lnitials
N/rl l'rs Nct
-4-b D 18. Suffioicnt volunnprovirled for all anal1,sls rcgue$cd? (ref. Af,achmcnt D of SOPf/ DEhl-QA-0t)03) lf no,
documcnl on CllR, and conlad PIr/ before proceeding.
4 tr tr 19. Is suffrcicnr rolume provided for client rcguested MS, MSD or malrix duplicatcs? lf no, document on CU\ and
contacl PM before proceeding.
O r0. Did thc cbain of custody irrcludes "reccived by'' and 'telinquished" by eig'naturct, datcq and times?
D 21. Wcre special login instructions read and followed?
D ?2. Werc A.FCEErEtalr logged for refrigcrated Eloragc?
O 23. Were tcsts Ioged chocked ,goinst thc COC? \*\'hich sampler wcre confirrnc ilD&-
24. litas a Rush forrn completed for guicl TAT?
25. Was a SlroflHold form completed foranl,short holds?
26. Is'Srid IC0f rcquired?
27. lilcrc special arcbiviqg instructions indicared in the General Corrrrcnts? If so, thal werc thc1,?
Latreling and Storage Checks:
I
L !l 28. tr'as the srbcontrao COC sigrred and s:nt witb saryles to boltle prep?
dn 29- t,cre sarylclabels doublc-chccked b1,a sccond person?
-tt I 30. Wcre sarryle botles and COC double checked for dissoh,ed/filtcred metals b1, a second person?
{l 31. Did thc sarrylc ID, Date, aud Time fiom label match ufiat rrms logged?
tr L 32- Wcre stickers for special archiving insuuaiorr-s afrv.ed to eacb box and to the ICOC? See *D7
! D 33- Were AFCEEmoals stored rcfrigerated?
tr ! 34. Wcrc "Suicr ICOC' copcs given to satellite storagc areas?
Documcnl any problems or discrepancies and the actions talien Lo resolve them on a Condition Upon Receip Alomaly
Report (CUf).
tI
r
fr
h
tr
fJ
!
!
D
tr
g
tr
I
I
o
Initialsdb
:I
STL Denver
a ET =!xU'
TmI m m(f
'noa 7 @o :DIov @ is o =m J =m :E IDrrz0 oTrnz rf
l
(,
(D*c,
r>,F J rn{m =T |ec,a,
rn>f :l
!
'8
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co a
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8
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FF
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=
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De
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STL
STL Denver
4955 Yarrow Street
Aruada, CO 80002
Tel: [phone] Fax: [phone]l
www.stl-inc.com
ANALYTICAL REPORT
Western Zircnnium Proj ect
Lot#: D5I100151
Sheri O'Connor
URS Corporation
8181 East Tufts Avenue,
Denver, CO 80237
STLDENVER
Linda L. Benkers
Project Manager
Septanber 30, 2005
Severn Trent Laboratories, lnc.
Table Of Contents
Standard Dellverables with Supportlng Documentation O
Report Contents
Sf,andard Dellverables
(fnu Cover Letur and the Report Cover page are consldered integral
parts of this Standard Dellverable package- Ihis report is incomplete
unless all pages indicated in this Table of Contents are included.)
. Table of Contents
. Case Nnrrative
. Executive Surnmary - Detecflon Highlights
. Methods Summa{F
. Method/Analyst SurnmarT
o Lot Sarnple Summary
t Analytlcal Results
o QC Data Associatlon Summsry
o QC Sanrple Results
o Chsln-of-Custody
Supporti ng Docu mentation
(I{ote: A one-page "Description of Supporting Documentatlon" rs
provlded a the begtnning of this section.).
o Volatile GCI1VIS
o Semivolntile GCA{S
r Volatlle GC
r Sernlvolntile GC
e LCI1WS or HPLC
o Metals
. Cen*rul C[.-lshy
r RadiochemlstrT
r Subcontracted Data
Numher of Pages
Check below when
supportlng
documentation ls
precent.nnnnnnnnF o
STL Denver
Case Narrative
D5t100151
With exceptions noted as flags or footnotes, standard analytical protocols were followed in the
analysis of the samples and no problems were encountered or anomalies observed. All laboratory
quality contol saurples analped in conjunction with the samples in this project were within
established control limits, with any exceptions noted-
The test results presented in this report meet all requirements of NEt AC, and any exceptions are
noted. This report shall not be reproduced, except in full, without written permission from the
laboratory.
Sample ReceMng
Six sarnples were received under chain ofcustody on September 10, 2005. The samples were
received in good condition at temperatures of 2.3"C,4-A"C,4.9"C,4.9"C,2.2"C and 4-7"C.
The results for all radiological analpes are included in this re,port and wereperformed by STL
St. touis; 13715 Rider Trail North; Earth Citlt MO 63045, phone [phone].
Rndiochemistry, Various Methods
The method 900.0 MOD gross beta MDA for samples D5Il00I5l-00I through 006 was not met
due to reduction of sample size caused byhigh residual mass. The analytical results are reported
withthe MDA achieved.
The method 7110 MOD gross alpha MDA for samples D5Il00l51-001,002, 004 and 005 was
not met due to reduction of sample size caused by high residual mass. The analytical results are
reported with the MDA achieved.
The thoriuur 229 fracerrecoveries for samples D5I100151-004 and 005 were below the control
limit. The samples were re-prepared and analped with acceptable tracer recovery.
A low-level and a high-level LCS standard were anallzed with total uraniurn batch 5269088 and
they are spiked at different concenhations. Therefore, the RPD value reported for these two
standmds does not apply. Both LCS recoveries were in control.
The gross beta, radium 226, radium 228, thorium 230 and thorium 23?MS|MSD performed on
sample D5Il00l5l-002 were in contnol.
fte totfl ureilum MS performd on smple DJIl00lJl.002 dernonstratd a rffiotisry below the
conhol limit. The MSD was in control.
The gross alpha MSD performed on sample D5ll00l5l-002 deuronsfiated a rerov€ry above the
control limit. TheMS was in control.
The gross beta MS/]vISD performed on a sample from another client and/or lot was in control.
STL Denver
The isotopic thoriurn duplicate was performed on a sample from another client and/or lot and
was in control.
Denver
METH(NISW
D51100151
PARAMETER
AIIALYTfeAL
},lETHOD
PREPARATION
METTIOD
Gross A1pha (COPRECIP) by
Gross Alpha/geta by GFPC
rsotopic Thorlum by Alpha
GFPC
Spectroscopy
sMww 7L10 MoD
EPA 9OO. O MOD
ET/TL A-01-R MOD
EPA 9O3.0 MOD
EPA 9O4 MOD
ASITY! 5L74-9L
EPA 900. O
Radlurn -226 by GFPC
Radium-zz& by GFPC
Total Uranium By taeer Ph oeplrorimetry
Refererrcee:
ASTITI
ET,IL
EPA
Annual Book Of ASll,I Standards.
IENTIIRONMEIIfAIJ MEAST REMENTS I,ABORATORY PROCEDIIRES MANUAIJi
HASL-300 28TII EDfffON, VOIJn{E I and fr DEPARTMEIWI oF ENERGY
II EAS]ERN EhI\IIRONIYIEMTAIJ RADIATION FACITITY RADIOCHET,TT9TRY
pRocEDURES r{ANUAr.,n US BpA EPA 52A/S-84-006 AUGUST 1984
I'STA}IDARD METHODS FOR WASTE WATERII
o
STL Denver
AIIAIJYTfCAIJ
METHOD
METIIOD/AIYALYST W
DsrI.001s1
AI{IAITYST
ASTM 5L74-91
EMIJ A- Ol-R MOD
EML A- 01-R MOD
EPA 9OO. O MOD
EPA 903.0 MOD
EPA 904 MOD
gMwlr 711_0 MOD
Referenceg:
ASTM
EMI,
EPA
SMWW
Mlke Anderson
.Tody Watson
Rhonda Rldenhower
,Iimmy Wilson
fvan Vanla
Ivan VanLa
Iwan Varria
AI{AI,YST
rD
402350
53903
06 004 0
4 0162'-1
4 00 697
4 00 697
4 00 697
Annual Book Of A91]'1 SLandards,
TENVIRONMENTAIT IIEASUREMBITS LABORATORY PROCEDURES MANIIAITn
HASIJ-300 28?H EDITION, VOITUME I and II DEpARTIIENT OF BIERGy
nEASITERN EIWIRONMEIilTAI, RADIATfON FACILfTY RADIOCHEMfSTRY
PROCEDURES II,IANUJ{IJI' US EPA EPA 520 IS-84-OO5 AUOUST 1984
NSTA}IDARD METHODS FOR WASTE WATER]I
STL Denver
o SAIVIPTE,W
D51100151
wo#SAI'{PLE# CLfETUf SAII{PLE ID
SAIvIPIJED SAIvIP
DATE TIME
HI(ARA O01 cW-N91-090905
HKARF O02 cW-Nl-O9090s
IIKARG OO3 GW-58-090905
HI(ARH 004 G'y{-sD-090905
HKARLT 005 GT[- g5 - 09 0 9 05
Hr(ARK 0 05 GW- 7C- 090905
:
rutB(s):
ae/oe/os o8;00
oe/os/os oe:25
ae / oe/ a5 0e;35
09/ae/os 10:45
oe / oe/ os 11 :55
09 / ae / as L2:2o
- Thc anrtydul rc$lt3 of the samplB llscd abovc are prcsc{tod oo l,)c followinS pagcs.
- All cekulstio[s 8ra paforrrcd bcforc rcudinE b avoid roud-offcrrors in ca]orldtcd rcsrlB.
- Itcsdtl norcd as 'ND" wor6 rlof dotdcd rt or above thc rtatcd liEit.
- Ihis rtport nuc mt bc reproduced, excepr in tt U, *ithout lho wrfu.o epptovlt oftho hborrbry.
- RrsrlB for tho followlng p&nmotors ere ncvcr rcportcd on a dry wcight basis: urtor. corrosivity. dcrBity, IlrshpolD[, l$it&bility, laycrs. odor.
priil fllEr test, pII. pororfuy presrrc, rcacrivity, rcdor potcnrial, spccific anviry, spot tcss, solids. slubility, tGiupcrelura, yiscosity, ard wcijltt.
STL Denver
IIRS Corporation
Client Sarmle ID: GIIi[-N91-090905
gsvsrn Trent Laboratorl.cn r Radl.oehsrlstrryr
o
Lab Sample fD:
Work Order:
I,traE,rix:
Pan:rr+Etr
D5r100151-001_
HKARA
Gtw
Borul.t Ourl
Total
Uncart.
Q a+l-) noc
Prcp lnaly;L;
ILtr Datr Betseh t Y1d t
DaEeCollect,ed: 09/09/OS 0800
Date Received: 09 /LOl05 0815
(nO88 r,IE_ BY GTPC
Ororr Botr
lPr 900. o troD
30.3 9.7
Dct/L
11
900,0 DfioD
oe lzLl o3 09125105 5764L29
Totel Ureal.um hJ
Eotr1 UnnLun
KPr rsmr 517l-91
o.{18 ir 0. 0{3
uglL
0 .31
5L7 l-91
09127 lo5 aglzala' 5269088
@Og8 I BY CO-PRECIP SHHW
Gross Alpha 2.4
7110 UOD
U
DcLIL 7110 !fiOD
09 /17 / A5 09 /20/05 52600683-2
nr-226 BY IZPI,-903, O tiOD
Rrdliun 17261 O. 52 a -77
Dcl/t.
o -26
903. O t[OD
09 l1.o I a5 0e laa I oJ 5253 0 61 98
RA-228 BY OFPC
Rrdlum 2ZB
EPT, 90{ DIOD
1. Og 0.4{
D,C,Llr,
0.5{
901 lroD
09 llolos aet78lo5 5253062 95
Iro |IIHORIITil (SHORIT C!!r) DOI A-O1-B
iflrorLun 230 O .60 iI
ThorLum 232 -0.014 U
r,ctlt .1,-o1-R lfoD
a9lLttos 09119/05
os/74/05 oslLs/as
5257300 70
5257300 7A
o .23
0. 086
o.19
0.19
Datr lr. Lneqlrrtr rlthout tbr oloc ncrratLvr.
loc 1r drtcrarln.d by lu;tnunrnt prrforenanco only-
BoId ruultr ar. gr.rtea tbrn thr l[DC
.f Rcrult lr grrcttor tbrD trqllc dctcctiou lfuntt, but
STL iDoxrvetlf lorr thra tho gatrtrlo drrrerr,l.on rLrl.t.
lcrc thrr rtetod rcportlng Lfnlts.
URS Corfloration
Cll,ent Sarcle fD: G[{-Nl-090905
Severn Trcnt LaboretorLes - Radiochorigtry
Lab San\ple ID:
Work Order:
Matrix:
Pannrtsrr
D5r1.001_51-002
HKARF
GW
Rc;ul.t Ourrl
Date Colleeted:
Date Received:
Totrl
hoort.
(2 o+l-) m
a9 / 0e / 0s 0925
09 / 10/05 081s
grrrp Asrlyrl:
Drt. Detc gatoh I Yad t
gRoss r./l BY
Grorl Betr
G}TPC EPf, 9OO. O MOD
39
ecLlL 900. o !iloD
09 12L105 09 l?51a5 57,61L29
Totr1 UrrnLurn b8l.
totrl Urrnl.un
KPr .LgrH 5L7a-91
0.399 J
ug/L 5L7 l-91
09 t27 tar 09l2gl 05 52690880-ot1 0 .31
GIROgg .l' BY CO-PRECIP gEilT 7110
Gross Alpha 2 -7
uoD
U
Dfr,LIL 7110 ![oD
og/17 /05 0s /20/0s s260058
nr-226 BY rPl-903.0 lioD
Brdlun (226) O-39
ecLlL 903 .0 !!oD
o9/10/0s a9lllslo' 5253061 1010.17 0.18
nA-228 BY GlrPC
Rrdlurn Z?lE
EDI 90{ DTOD
o-7(}
(gtroRt cr) DoE .t-01-R rcD
0 - 15 u
0.011 U
0.37
DC;LII'
N,c.LIL
0.56
90{ }roD
ogtlalas 0sl28lo5 5253052
.1,-01-R lroD
09/1 4 / 05 09 /L9 / As 5257300
ogtL4/05 0s /Lgta5 52s7300
9t
;IO TIIORTUDI
riurn 230 7L
7LThorium 232
(s)
rra lnooplctr wtthout tho cara rra,rrrtl.ve.
loC Ir dctornlaod bf Lartrrurots D.rtozlrDoo o'aly.
Bold rrrulta ar. gEaatcr tbrE tho ilDC
3 namlt 1r gnutor tben rrryIr dt t.otle lt-att but lcr than .tatGd rcDortlng ltrdt.
6IL il)CffV€If l.rr tLrn tbc mnDlr drrrorLon 11&1.t.
IIRS Corilloration
Client Samls ID: Gg[-58-090905
Savern Traat Laboratoricg r Radlochsnl"Btrfr
Lab Saurple fD:
Work Order:
MatrLx:
Perartt'rr
D5r100151-003
HI(ARG
GW
ResrrI.t
Date collecEed: 0 9 / 09 / 05 093 5
DateReceived: 09/LA/A5 08L5
rotal
Usoltt-
QurI 12 o+l*l fOC
Prap Aulyrl,r
Datr ILtc Ertoh I Y.Ld r
cmog8 ^lB Br
Ororr Brtr
SFPC EPt 900.0 ilOD
301
Etrt lL 900.o HoD
09lltl as ae l75l 05 J260,1:9s6
TOt1l Ufrvrirra, bryr
Totr1 urrnLrra
KPr rsrr[ 317{-91
9-54 o-98
!trglI,
o-31
517{-91
oelzT las 09l?8105 526e088
GROSS I. BY EO-PRECIP TDO{W
Gross Alpha 2.O
7110 ![OD
U
DCLIr,.7110 !rcD
09 /17 /05 09/21,/05 s2600582 _1,
n-225 BI EPl,-903. O DIOD
Rrdlun 1226) 1- 13 0 .28
DCI/L
o.2t
903 -O MOD
oellolos 09lz8lo5 5253061 9l
n -228 BI OrPe
Rrdtun 77A
TPI, 90{ DTOD
l-46
t)cL/L
o.49
900 !@D
ae 110 / 05o .51
a -27
0. t_5
pcL/L
a9l78l 05 5253062
rro TIIORIIT!il (SIIORT Cr) DOE r-Ol-R UOD
Thorium 230 0.2L U
Thoriurn 232 -0.02 U
0.35
0 - 25
t-oI.-R DtoD
09/L4/As A9/79/As
oe/t4/05 09/L9l05
52573 00 101
5257 300 101
l[cxrE(s]
Data ar. Lnoqrrrtr rlthort thr clre urratLvr.
loC lg dottrrntncd b1r Lnrtnrrucnts prrfomruo6 only.lold rorulto Lro gr.atcr than thr rcC
U Rrsult, Lt Lur tht'l trbc rurDlt drtratlon t{rn{t.
STL Denver
URS Corporation
Client Samlc fD: G9[-5D-090905
Severa Treat, Laboratoricg - RadLochsalgtrll
Lab SarrpJ.e
Work Order:
Matrix:
Deramtrr
D5r1_00151_-004
HKARH
GV0
Beoult Ou.ef
DaEe Collected:
Date Received:
TOTAI
Ihoort-
12 o+ I -l t@c
a9 / 09/0s 1-04s
09 /LO / Os 0B1s
Pr.p ltarlyrt e
Drtc Dat. Batolr t
SROSS .e'/B DY
Glror Brtr
or"c rPt 900. o ltoD
660
ecLlL
110 110
900. o !iloD
a9 lzll a8 09 l25l03 5264129
ToBal UrrnLrrn b8t'
roual Unal.um
IcPr r8Tl[ 517{-91
7 .79 a.7J
u;glL
0-31
3L7 *-91
09lz7 l05 a9l78l05 526eo88
oRoaa l' BY co-PREcrP sloilf 7110
Ororr f,lpbr 5.4 z -'l
D,cLlL
,.7
7 t 1,o lton
oglLl lo5 agtzlta' 5260068
8A-226 BY EPt-903. O UOD
RrdLun (e357 7.32 0-82
D,€;Llr.
o.20
903 - o !ilOD
09/10 /a5 a9l78lat 5253061
RA-228 lv orPc
Rrd.lum 22A
EPr. 90{ r[oD
3 -Tg
(guoRT cT) DoE .t-01-R uoD
0 - 30 u
-0-10 u
0.62
DcL/L
0.{7
petlL
90{ I'IOD
09/10/05 091781a3 52f3062
rO THORITIII
orir:n 230
Thorium 232
r-01-R moD
09/26 /Os 09 /27 /05
09/26/05 09/27/Os
5259393 84
s269393 84
(s)
lr. lnoq>htr rl.tbout tho olr. nrratlvo.
HDc l.r dctcrutnrd, by :lurtnucnt prrforre.acc oDry-
DoLd rlcultr rr. grrcrt.r tban thr t[DC
u Bcgurt ll rrlr thru Ebc uqrlc drtactlon Ifurdt.
STL Denver 10
IIRS Corporatl,on
C].Lent, Samp1e fD: g![-S5-090905
$cvern Trcats Laboratorler - Radtocherni gtry
Lab Sary>Ie ID:
Ialork Order:
Matrix:
Prruetcr
D5r100L51-005
HI(ARJ
G'W
Roult (hral
DaEe Collected: 09/A9/A5
ae/La/05
1L55
081 5
Pr.p lo^e1yrlr
Drrtr. Dctc Htnb *
Dat,e Received:
TotrI.
Ilncrrt.
(z o+l -l DDe ltd t
GIROSS t'/I BY
Ororr Brtr
orPc fPt 900. 0 ![oD
185
D}c.LIL
100
900 - 0 lIoD
09 lzLl o5 09 l25l 03 5264129
Total. Urral,um,
Totr1 Ur+alum
brtr KPI .LAX![ 5L7l-91
0.855 ar o .096
ug lr,
o-31
5L7 4-91
09 t27 I 05 09 t78l OS 5269088
oRog8 r BY co-PRtCrP slmlw
Gross A1pha 1.7
7110 DIOD
U
pieLlL 7110 lrOD
09 /L7 / A5 09 /2L / 05 s2600683.5
HL-226 Br EPn -9O3 . O UOD
RadLum (?.261 1.O5 0.26
p,cl-lL
0.16
903. O DilOD
oeltato5 09 lzgla, s2s3051
Rt-228 Br orPc
Ard,lum ?,ZA
EPr 90{ r[oD
1 .39 o.{5
D,cLlt
o .5E
90{ ![oD
ogttotos aelztlos 5253062 75
Iso 'THORIUU (8xOnr Cr)
lfhorlun l3O 0.58
Ttrorium 232 0. l-4
DOE .[.-01-R ltOD
ir
u
DCt/L [-01-n uoD
09i26las oet?T ta5 5269393
09 /26 / 05 09 /27 / 05 5269393
o .31
0-18
0-32
o -?,4
83
85
lroEE (s)
Dota rr. Lacqlloto tLtLout tb. 6ara arrrrtl.ye.
DC ir drtcralardl bU, lartnnrut porlormrBcc oaly.
Bolil rcrult. la. grrGator thrn thG lDC
it Roault l.t grrGtt.a than ..nplo d.t.ctlol 1{irt buts lo.3 tbea .tat.d r.Irortr,Bg ltrdt.
gTL lDcFltr6lp loar tbtB tbc cr4rlc dotGctloL lttutt.
IIRS Cor;poratLon
Client Sa-m1a ID: GI$[-7C-090905
Srvera Trcn't, Laborator{eg D Radiocham{ gtEy
Lab Sarple fD:
Work Order:
l'Iatrix:
Prrrntser
D5rl-001-51-006
HKARK
GW
X,oru1.t
Date Collected: 09 /09 /A5 L220
Date Received: 09 /LA / 05 0BL5
TotrI
Ilholrt-
Ourl lZ o+ I -l ilDC
Prap lrrrlyd.r
Datc Drtr Eatch I YLd t
oRogg t.Il- Br
Ororr Botr
GlrPC EPr, 9OO. O }TOD
30.5
gc,f I'900.0 MOD
oglztlo5 a9l2.5la' s25{1391.7 1.3
Tota1 Urrnlrun bryr
Total Uranium
KPr' r^glil 517{-91
-0 - 0L50 u
vf,f r'
0.00L6 0-31
3L7 {-91
09/27 /A5 09 /28/05 5269088
gRoag n BY co-PRtCrP gtoflt 7110
Gross Alpha 0.06
moD
U 0_48
D,c.Llt
0.90
7110 r{oD
09/17 /A5 09/27/O5 5260068
m-226 BI EPL-903. O t OD
Brdiun (2,261 0-37 0.15
Dct/L
0.15
903,0 r@D
og llo I o3 agl?al a5 5253061 106
RT-228 BY OEPC
Radium 228
rPl 90{ ![oD
0_49 0.33
pct /L
0-51
90{ MOD
a9 /1A / Os 09 /28/ 05 5253062 99
e::#::r (Erro*r fl,* r-o1
Thorlun 232 -0. O13 U
0.17
0.058
pcllI-,
0.13
0.12
.L-OI.-R DIOD
09 tltt 05 09lL9l os
a9/L4/05 09/L9/A5
52s7300 83
s2s7300 83
lr. lnoqrlcEe vlthout Ehe eaf. urratl.vt.
Lr drtorntn d ry lattnrncnt DrrformrnoG only.
Bold rc.ultr rrr groattr tLr! tb. Ee
it R.9ult lt grratcr thrD rq)I. d.t.ctlo llnl,t hrt I.e. thaE .trtsrd rrDort{ng ll,nit.
gTL BElil+eltr lmr thrs tbc reryrle dcrccrloo ltntt.
ACDATAASSffiONW
D5II.OO151
Sample Preparat.lon and Analyels Control Numbers
I"IATRIXSAI'IPITE*
001
o02
o03
o04
oo5
006
GW
GIlf
G}T
G}I
GT{
GW
GW
ctw
GW
GT{
GW
GI{
GW
GW
GW
clul
GW
GTV
GW
GW
G"rt
GI{
GT{I
GW
GW
GW
GW
GW
GUI
GUI
GTI
GW
Gt[
GW
GW
GTT
AI{IAIJYTICAI,
METHOD
EPA 9OO. O MOD
ASfrvI 5L74- 91
sMuulil 711 0 MOD
EPA 903.0 IVIOD
EPA 904 MOD
EML A-01.-R MOD
EPA 9OO. O MOD
ASTM 5L74-91
sMulw 7L10 MoD
EPA 903.O MOD
EPA 904 I'IOD
EI,IL A-01-R MOD
EPA 900.O D10D
ASTM 5L74-91
gMnm 71r.0 MoD
EPA 903. O MOD
EPA 904 MOD
EI{L A-01.-R MOD
EPA 9OO. O MOD
ASTM 5L74-91-
SMWTil 7I.1O }MD
EPA 903.0 MOD
EPA 9O4 MOD
EITIIJ A-01-R MOD
EPA 9OO. O MOD
AST!'I 5L7 4- 91
sMeul{ 71.1- 0 MoD
EPA 903.0 MOD
EPA 904 MOD
EI'IIJ A-01-R MOD
EPA 9OO. O MOD
ASTM 5L74-91
sMr|w 7110 MOD
EPA 903.0 MOD
EPA 904 MOD
E['{t, A-01-R MOD
I.,EACH
BATCH #
PREP
BATCH *
s264L29
5269 08 I
52600 5 8
s253061
5253 0 62
52s73 0 0
5264L29
s259088
5260058
5253051
525 3062
s2573 00
5264L29
5259 08 I
5260058
5253 05 1
s2s3062
52s73 0 0
52651,29
s269088
s260058
s253061
s2s3a62
s2693 93
5254L29
5259088
s260058
5253 061
s2s 1462
s2693 93
5264L29
s269088
s260 068
s2s3 061
5253 052
s257300
MS RI]N#
5264 090
s269052
s260 03 3
5253 048
52s 3047
5257L99
s264 090
s269 0 s2
s260033
5253 048
525 3A47
s2s7L99
s2640 90
s269052
526003 3
5253 048
s253 047
525 7 L99
5264090
52690s2
525003 3
s2s3 048
5253047
s259296
52640 9 0
5269052
526003 3
s2s3 048
5253 047
5269296
52640e0
s26go52
5260 03 3
5253 04 I
5253 047
s257L99
:.'
STL Denver
o
13
O
Client Lot
Matrix:
Pa,rrnrtrr
Eewern
D5rl-001_51
WATER
Rrnll.t
UETIIOD BI.NIK
Trent Laboratorieg
REPORITI
- Radl,ooh@l,Btry
Total
Uaoort.
Q o+l-l
r,rb 8arylb ID
Pr.D eulyrl.t
Dat. Datsc lrtob I rld t
oRoss ^l; BY
Gross Beta
orPc EPI 900.0 uoD
0.68 u
OCLlft
0.67
900,0 utoD
1.1
r5r210000-1298
09 /27/05 09 /25105 s254129
Rr-228 BY
Rad"ir:n 228
otPc EPl' 904 I.!OD
0. 03
DcL/L
4.27
90{ troD
0 .47
r5rr-o0000-0628
09 /L0l0s 09 /28/05 s253062 90
u-226 Br ltPt-9o3.0 !@D
RadLr:m (226) 0. 04
D,cLlL
o -72
903.0 DIOD
0-21
r5r100000-o618
09 /1,0/05 09 /28/05 5253051 93
rao TIIoRrtm (gltORlf Cr] Dot r-Ol-R l{oD
Thorlrn 23O 0.23 if
Thorlum 232 O -O22 U
pelll.l,
0 .15
0. 062
l-01-R uoD
o. 12
0-059
r5r140000-3009
09ltllo' 091L91o3 3257300 8T
09/L4/0s 09/r,9/0ss257300 87
O":T:;"'CO-PRITCTP gUTTfl
-0.09
7110 rroD
U
plct.lr,
0 - 34
7110 r00D
0-65
r5r170000-0688
09 /t7 t05 a9 /2L/ 05 5260068
rro TIIORIUU (SIIORT cr]
Thorlurn 23O 0.09
Thorium 232 0.08
DOt l-01'R ![OD
U
U
DCLIL
0. 14
0-10
l-01-R UOD
4.20
0. 13
r5r260000-3938
09 /26/A5 A9/27 /Os s269393 91
09/26/05 09/27 /05 s269393 9r
Total Urrnirru, bry
Total Uranium
KPJI rsxu 5171-91
-0 - 05d0 u
vg llr
0 - 006s
5L7 4-91
o-31
tr5r260000-0888
09 /27 /Os Oe/28/0s 5269088
(8)
lrl Lncq>latr rLt,h'outs tbr our nrnatLvo.
DC tr dctronlucd u.LEg lastrur.Dt Dorformanoc only
DoId rorulta arc gr.rt.a th.Ir tb. lDC
q - !.rult Ir grGrt.E thra uqrlc dctoctloo lLelt brt 1o:r thrs rtrt.dl roportlng lLett.
$fl RneV% I"u thon tb. rqrlc drtrsrloB lIDIr.
t.
a4
I
taboratory Control Sarylle ReDort,
govera Trent Laboratoriee - RrrdLochanl,rtry
Splhe lrcuat Brcult
Totrl
(IEoafr.
(3 s+l-l
o
Client lrot
Matrix:
Prrrmotrr
D5 r 10 015 r.
!{ATER
LaI, Ae4r1c ID
gC Coatrol
t Yld t Roo lrLultl
Ico ltfHORIIIlt (gHOI{f ef) DOE L-01-R ltOD
Thorium 228 B. 81 9 - 3
Ttrorium 23A 9 . 46 8. 3
Thorium 2.3?- 8-82 9-2
Batoh lr 5257300
p;cilL
1.1
1-0
1-1
.1,-01-n lDD
0.1
o. 09
0-L
tnrlyrLt Drtstr
r5r1{oOo0-300e
92 105
92 87
92 10{
09/]-9/05
( 91 1_32 )
( 6s 729t.
(88 133)
OROEg .I. BT CO-PnECIP
Grogg Alpha
g!flrw 7110 lroD
24.6 15.1
ErtoL *r 5260068
7110 troD
0.5
loal.yrlr DaEcr
r5r170000-068c
07 - 143)
DCLII.
2.t 7g
a9 /21/ 05
OROgg i'/B BT GIFPC
Gross Beta
tPl' 900.0 HoD
52.3
B.tch tr
900. o ![oD
1.0
lnrlyrLr Drtor
r5r210000-129e
(74 121)
piCLl[r
42 -2
5264].29
81
09 /25 /45
IAO TIIORTIIII (EIIORT
Thorl-r:rt 228
Ttrorj,un 23O
Thorl-urn 232
cT) DOI A-Ol.-n
8.8L
9-46
8 _82
natob tr
uoD
9_5
7-7
9 -6
52693 93
ircllL
1" -2
L.o
1-2
l-O1-R HOD r5r2 60000-393c
0.1
0. 06
0-09
fnrlXzrLr D1tc r 09 /27 t Os
9?
92
92
108
82
108
t:l -:::,1 o(88 133)
rfc)?DE ( s)
c.nr-4tjl.93tgnhdl rlr brtmt prrtorucs olv
Y<frr Er prrlozod Irrloro roundllag to rvoLd rqrad-off rrror Ln cilclrhE.d nmltr
Iraboratorf, Control Saryllal['Ca utrp1lcato ReDort
llevern Trent Laboratorleg Rrd,Lochmigtsrlr
D5rLo015L
WATER
Client Lot
MaErix:
Par!r.ter Spltr rrcust
TOETI
Unoart.
(2 o +l-,t ELd, t ltlo
Ldr 8rryth ID
QC Coqtrol
LLnLtr Prrol'rlo
RI.-228 BY
Rad,ir,rn 228
orPe EPr 90{ tiloD
5.26
spk 2 5.26
DrtcL ilr
pcL/L
6.42
6.72
5253 452
904 ![OD
0. 89
0.94
r5r100000-062c
91 122 ( 5689 L28 (s6
r'arlyrk Drtrt 09 /28/A5
L47 |
L47! 5 tRPD
Rl,-226 Bf EPrr-903.0 DIOD
Rad.iun (226) 1L.Z
Spk 2 LL _2
pCt/r.
10-9
L2 -4
Drtch *r 5253061
903. O t@D
1.3 91 98
L.4 90 110
Lorl.yrlr Drtsrr
I|5r100000-061c
(s4 136)(54 136 ) L2 tRPD
09 /28/ 05
Totr1 Urantun
Tota1 Uranium
lry KPt. tA'EDtr 5LT l-97.
d,0.0
Spk 2 8.0O
Eetob lr
lg lr,5L7 l-91 151260000-o88c
112 )
112) 1-35 tRPD
39 - 5
7 .59
5269088
4-7
0.78
lnrlrrrl r
(90
(90
ae/28/0s
99
9s
Drtrr
tlorFE ( s I
STIf.BghSeqIl riE lr.rlotr.al b.fot rourdln0 to rvoLll round-ott .rror Ln o.loulrt.d BcBIt.1,5
o![aTnrx
Sewern
D5r100L51
GW
Apiho
.f,nout
SPIKE/TLIf,ERIX SPIKE
Trent, Laboratorl,er
DITPLICI\TE REPORT
- Badl-och@rLotry
Date Sampled: Og / Ag / A5
DaLe Received: 09/1"0/05
0925
081 s
C1ient Lotr rD:
ttatrix:
Parauttr gPIXE
Rrrult
rotal
llDclrt.
17 a+l-l
arlLlco
YlA
SITPI.E
Rctult
TotlI-
IXooort.
(2o +l-}
OC 8rryrlr fD
t Xtd tRrc 0g Coutrol
r.:lrd.tr
(IRogg AIB- BY
Gross Beta
GlrPc lPf, goo. o
804
spk2 Boa
pc{/L
69
77
900-0 uoD Dfr100151-002
75
85
PrcolaLonr 12 tRPD
(s0 1s0)
(s0 150)
EcEch
641
723
ilr 5264090 fnrlfrol.e
39
39
drte r
12
L2
09 /25 / A5
IEotlL UranLun lrlf KPI lSIItI 5
Total Uralium 40-0
spk2 q0 _ 0
33.2 a
37 .2,
5259052
ulflllt
3-9
4.4
517{-91
0-399 ,J 0-041
0,399 J 0-041
Prrcl.rLoar
drurr 09/2glA5
Dsr100151-O02
82 a (90 L12l
92 ( 90 Ltzt
1-1_ tRPD
Drtolr lr lralyflr
GIROSA N, BY
Groee Alpha
co-PntclP gustt,
4L.2
Spk2 4L.2
49 -2
66.9 a
s2 60033
DCL/Ir
7.6
9 .97
7110 r@D
2.'l
2.7
drto r
u 2-1,
U 2.L
DrooLdoar
09 /20/05
D5r100151-OO2
113 ( 50 150 )li' J*nl'o "O
Drtoh t:.lnrlyT lr
m-226 BI EPI.-9O3. O
Radium (2261
SPk2
10.0
9-4
Drtob lr 5253048
903. O !ilOD
101 0-39 ,J
102 0.39 J
lnrlyrl.r drtc r 09 /28/0s
D5r100151-O02
82
17
6
lCOD
L7 .7
1-1_8
pcl/r,
1.2
t-2
0.17
0. 17
101
101
(55 150)
(66 - r-50)
prolrloar
H\-22E BT
Radlum 228
orPc EPr 904 MoD
5-52
qpkz s - 53
DcL/L
0.9e 89
0.94 95
lorlyrlr
901 I'toD
0.70 ,J
0-70 J
drtr r
ktol-rLonr
D5r100151-OO2
93 72A rcz 1sO )
93 L1-2 (62 150 )
Datoh tr
7 -31
6-90
5253047 a9/28/05
r;o TIIORTUD(
Thorlum 230
Thoriurn 232
(8HORI Crr) DOX .
9-46
Spkz 9 . {6
8. 82
Spk2 g. Bz
D,CL lr.
1-1 81
0.99 L03
1 .3 81
1.0 103
.trnrIYcla
![oD
u 0.15
D5r100151-O02
8s 174 r-30)
76 34 130)
11 TRPD
1.r1 (81 724l/
2L IRPD
Brteb
8.2
7 .37
9-8
8.0
*r 5257L99
A-01-A
0.15
0 .15
0,011
0_011
drtc r
71
u 0.1"5 7t
Prrclrl,onr
u 0.065 7l
u 0.055 7L
Drocirl.our
09tL9/05
OROSS T/B BY
Gross Beta
orPe EPr, 900.0
t7 40
Spk2 L7 40
900,0 lnoD
9s 26
9s 25
dlter 09/25/05
D5r130187-003
92
91
(s0 1s0)
( s0 1_s0 )
trEoh
L 690
16 B0
Ir 5264090
pCL lt'
180
180
tnalyrh
brfon roundlug to avold round-ott rrror Ln aalEu1atrd, ruultr
0.5 *RPD
rrcnE (8)
ere
Caloulrtlonr ar. f>.rformd
STL Denver
gai. nrrrat va.
qDtkoC enrly'tr outtLdo of Btatcd AC linlts.
tcsult tr gmtrr tbrn m4rl.c dctcct{on ltmtB hrt
lLnl.t.
X,orult Lr lur thrn tbr aa4rl.c dctoctlon Il.ult.
lorr tban rtsrBcd rQportlag
Denver 18
DI'PLTCTITE E\I}LUATION REPORT
gevern Trent LaboratorLer - Radl.ochmtrtry
Cllent Lot ID:
MatrLx:
Paranatar
D5r1-00151
WATER
8tf,DLl
Rrarlt
Date Sarrpled: 09 / 07 / 05
Date Received: 09 / 08/05
Total
TIUorrt. I,UPLICilTIE
(2o +l-) t rld, Rrlult
TotrI
llactrt.
12 o+l-l r Y1d
AC Srqrlc ID
Prrcirios
fro EHORIIff (gHORlr
Thorium 230
lflrorir:n 232
c.r) DoE r,-01-R uoD
a.77 J 0.20
'0.014 U 0.088
Batoh Ir 5269393
l*Llt
69
69
(Sa*ple I
A-oI.-R UoD
o .27 J O.20
0-0L4 u 0.079
5269393 (Drplicate)
58
68
Dsro80237 -006
0.3 IRPD
3430 tRPD
NOTE(g)
O
o
Eta arr Lncqrlctr rl.tlout tho oar. ,rrErotl.vr.
Crlsulatlonr ar. girtormrd bcton rould,lng to avold round-ott
^J__ &cgult_Lr gnrcrter thru srlph drtrotlon ltntt bute rPT - T'\ a rr'+1 L H"E[tYefl rcrr rh.o rbc rruErrr dorcorrou lr.a{.r.
.rror Iu crlculaEed rrrultr
Ic;r tsban rtrtcd rcportlng llnLt-19
STL Denver
Sarnple Receiving Checklist
r_,ot#: bff/oc, (S-l Date/Tirne Recei ura, ..? f t>( ,{ C 8ls-
Company Name & Sampling Site:tJ e-J+ .ru\ Zl ,.
PM to Complete This Section: Yes
Residual chlorine check requirceD
Quote #:
Special InstructioDs:
Time Zone:
. EDT/EST ' CDT/CST ' )\,DTMST . PDT/PST . OTIIER
No-x Quarantined, H y
Initials
DT
(;2
Clrecks:
#(s): (
("C): Z- ' )
:kin
Cool
ature
izs ,N
I eDrycra
N/A Ye
DO
pac
(
Pcft
Yt
l
il
u
f
t
fi
D
tr
D
u
K
n
,D
u
U
Te
Nt
D
D
m
I
ob
ES
Ier ,_
?.o :{'-1 2-L .- Y }
Cooler seals intact? O/A if hand delivered) Ifno, doctrment on CI-IR.
Chain of custodypresent? Ifno, documeut on CUR
Bottles broke,n aod/or are leakiug? If yes, document on CUR
Multiphasic sarrples obvious? If yes, documeot on CUR-
Proper coutainer & preservatives used? (ref. Attachrneat D of SOP# DEN-QA-0003) If no, document ou CUR
pH of aII saryles checked and meet requiremexts? If no, documcnt on CUR-
Sufficient volume provided for all analysis requested? (rcf Attachment D of SOP# DEli-QA-0003) If no,
document on CUR, and conact PM bcforc procceding-
Did chain of cusody agree with labels ID and samples reccived? If no, docuncnt on CUR*
Were VOA mrryles without headspace? If no, docrment on CUR-
Were VOA vials preserved? Presenrative DHCI f,4+2"C OSodirm Thiosulfate f, Ascorbic Acid
Did sauples require preservation with sodi,*n thiosulfate?
If ycs to #1 I, did the samples contain residual chloriuc? If yes, docrrnent on CUR.
Sediment present in dissolved/fiItered bottles? If yes, doctu:cnt on CLIR
?
Y1
No
D
tl
o
J
tJ
tr
o
n
c
D
?
fI
D
I Ldly!ry:?R, document on ctR, andIs sufficient volume provided for cfient requested MS, MSD or ma
contact PM bcfore proceediog.
Receipt date(s) > 48 hours past the collection date(s)? If yes, notiryPAPM.
Are analyses with, short holding times requested?
Was a quick Turn fuound (TAT) requested?
o 0]5,
tr t[ 16nAn.
ST\q,&BnHSHpte Recsiving\Sample Receiving Chccklisr i2 13 04 revision
C
ruB/44 2A
STL Denvel'
Sample Receiving Checktist
Lot#. wlYt7
Login Clrecks:
N/A Yes Na
Jnitiols
F U 18- Suflicicn, volunrprovided for all anallnis requcsted? (rcf. Atachrncnt D ofSOP# DEN-QA-0003) lf no,
docunnnt on Ol& and contact PIvI beforc procceding.
tt q g 19. Is suflicicnt rotunr providcd for clic,nt rcguested hrs, h4SD or matrix duplicares'.r If no, document on CUII and
wrrlaci. PM bcforc procccdirrg.
20. Did thc chain ofcusrodl,includes "rcceivcd b)r'and'rclinguishcd" by nigaaturer, dater, and limer?
21. \l,ere spccial Iog in insructions rcad and followed?
22. \l,ere AFCEEmDlals Iogged lbr refrigcrated storagc?
23. Werc te$s logged clrccllod againsl the COC? \lhich snmples u?Dre confirmed?
24- 14'as a Rush fona mmplercd for guicli TAT?
25. I{,as a Short Hold form corrplaed foranl,short holds?
26. Is'Strict ICOC- rcauired?
27. \Vcrc ryecial arclivilg io$ruaions iudicatd in fte General Cormrent? if sq r&a werr thcl,?
Iabelfug and Storage Checks:
28- 1472s fte nrbcontact COC signed and seot wift sirgrles to borlc prrp?
29. $rcre s"r'plelabels double-ched<ed by a second p:rson?
30. 'lVcrs sr"S,Icbotlcs and COC doublc checkcd fo'r dissolved/filtcred Detals by a second person?
3I - Did tte sarryle ID, Datc, and Tirne fiom label matcb u'hat uas loggcd?
32- $Iere rticLtrs for special archiving ioguaiou affixed ro eadr box and to tlre ICOC? See #27
33. Wcrc AFCEEmaals storad refigerated?
34. Werc "Strcl ICOC- copics glvsn to sarellire storage areas?
Documenl any problerns or discrepancies and the actions tal(sn t0 resoh,e them on a Condition Upon Receipt Alomaly
Ileport(CUn1
ql
DO
atr
SI
ru il
Irr
tr
tr
I
Et
El
I
g
tJ
tr
&
3 KI{s
?/n 3
{rt
?titrUE tr
&! !
STL Denver
27
t EI =:ox c2
f,mc,
rn rn(]
'nof,t(Do :D Tof,
(D :s C]Irf
i J rn =:D TD 7rzI o'u mzmtf
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b-o E
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El CL
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STL Denver
4955 Yarrow Street
Arvada, CO 80002
Tel: [phone] Fax:
www.stl-inc.com
STL
303 431 7t7r
ANALYTICAL REPORT
Western Zirconium Proj ect
Lot #: D5Il30l87
Sheri O'Connor
URS Corporation
8181 East Tufts Avenue,
Denver, CO 8An7
STLDENVER
Linda L. Benkers
Project Manager
October 7,2A05
Sevem Trent Laboratories, lnc.
Table Of Contents
Standard Deliverables wlth Supportlng Documentation
Report Contents
Standard Dellverables
(fn" Cover Lefrcr and the Report Cover page are considered integral
ports of this Standard Deliverable package. Thfs report ts lncomplete
unless all pages lndicated tn thls Tahle of Contents dre included.)
o Table of Contents
. Case Narraflve
. Executive Summgry - Detection Highlights
o Methods Summary
o Method/Anelyst Sumrrary
o Lot'Sarnple Summary
. Analytical Results
o QC Datn Assoclatlon Summary
o QC Sample Results
o Chain-of-Custody
Suppofii ng Documentation
(Note: A one-pog,e "Description af Supporttng Documentation" li
provlded at the beginning of this section.).
o Volntile GCIIUS
r Semlvolatile GC/DIS
o Volatlle GC
. Semivolatile GC
r LClll{S or HPLC
o Metals
r General Chemistry
. Radlochemistry
r Subcontracted Data
Number of Pages
Check below when
oupportlng
documentadon is
present.
mnnnnnnm
STL Denver
Case Narrative
DsI130187
With exceptions noted as flap or footnotes, standard analytical pmtocols were followed in the
analysis of the samples and no proble,ms were encormtered or anomalies observed. All laboratory
quality control samples analped in conjunction with the samples in this project were within
established control limifs, with any exceptions notd.
The test rezults prese,ntd in this report meet all requirements ofNEI-AC, and any exceptions are
noted. This report shall not be reproducod, excqrt in full, without written permission from the
laboratory.
Sample Receiving
Three sarnples were received under chain ofcustody on September 13, 2005. The sarrples were
received in good condition at tenrperatures of 3.6"C, 4.1"C,3.9"C, and 3-3"C.
The results for all radiological analyses are included in this report and were performed by STL
St. Louis; 13715 RiderTrail North; Earth City; MO 63045,phone [phone].
Radiochemistry, Varlous Methods
The method 900.0 MOD gross beta MDA for samples D5I130187-001 through 003 was not met
due to reduction of sample size caused by high residual mass. The analytical results ane re,ported
with the MDA achieved.
A lowlevel and a higlr-level LCS standard were anallzed with total uranium batch 5269090 and
they are qpiked at different concentrations. Therefore, the RPD value reported for these two
standards does not apply. Both LCS recoveries were in control.
The gross betq gross alpha, radium 226, thorium 230 and thorir.un 232MS|MSD performed on
sample D5Il30l 87-003 were in conhol.
The radiurn 228 MS performed on sample D5I130187-003 de,rnonstrated a recov.ery above the
control limit The MSD was in control.
The total uranium MS/}VISD performed on sample D5I130187-003 demonstated recoveries
below the control limit.
The gross beta MS/IItISD performed on a sample from another clierrt and/or lot was in control.
STL Denver
METHODSW ODsr130187
PARAI'IETER
AI{AIJYTICEIJ PREPARATION
METHOD },TETHOD
GroBs Alpha (CoPRECIP) by GFPC sMwll 7110 MOD
Groee Atpha/Beta by GFpc EPA 9oo.0 MoD EPA 9oo.0
IeotopLc Tlrorium by Alpha Spectroecopy EMII A-01-R MOD
Radinm-226 by GFPC EPA 903-0 MOD
Radium-228 by GFPC EPA 90{ MOD
Total Uraniurn By Laser Ph oBphorlmetry Agllrl 5174-91
Referesceg:
ASIS{ Anrrual Book Of AS$,I Standarde.
EML TBN\IIRONMENTAIMEASiIIREME'IflIS LABORATORY PROCEDURE9 MAN[rAIrrr
IIASI,-3OO 28TH EDITTON, VOIJ,ME I and IT DEPARIIT{ENT OT B{ERGY
EPA SEASTERN EI,V\/IRONMEMTAIT RADTATTON FACII'ITY RADTOEHEMISTRY
PRoCEDITRES r4Alilt Af,n US EPA E,PA 52A/5-84-006 AUGUST 19811
SMYTW ]]STA}IDARD METHODS POR I{ASTE }IATERtr
STL Denver
AMITYTICAI,
}4ETHOD
MEIHOD/AIYALYSTW
Dsr130187
ANALYST
ASTIr{ 5L7 4 -91
Ef'IIr A-0L-R MOD
EPA 9OO. O MOD
EPA 903. O MOD
EPA 904 D/TOD
gMww 7110 MOD
RefererrC€E:
Mike Anderaon
Jlnuny Wileon
..Tlmmy WLlson
,]furuny Wilaon
.Tinuny Wileon
,fimmy wileon
AMITYST
ID
4423 s 0
401527
401627
4 01 627
401627
4 01 627
ASTIVI
EMIJ
EPA
Anrrual Book Of
.'ENVTRONMENTAI,
IIASI,-3OO 28TH
ASTIvI Standards -
MEASUREMEMTS I,ABORATORY PROCEDTIRES MJU{UAL'I
EDITION, VOITUME I and II DEPARTMEMT OF ETVERGY
I' EASTERN El[\ftRONMm[fAIr RADIATION FACILITY RADIOCIIEMf STRY
PROCE'DIIRES Mi{NUl\I,n US EpA EpA 52O / S- 94 - 005 AUGUST t gB4
N STAI{DARD METHODS FOR WASTE WATER''o
STL Denver ''4
SATIPLEW
D5r130187
WO # SA}TPLE# CLTENT SAIYIPI,E ID
SAMPLED SAIYIP
DATE TIME
HKE18 001_ cW-BWg 2- A 912 0s
HKE2A OO2 cr{-B$[01- O912A5
HKE2D 003 chl-Bwaz- o9r.20s
nCIrts(s):
oe/Lz/05 o8:oo
a9/L2/as It:l-5
09 /L2/ as L2:22
- Ihc smlydcal rse$a of Ih6 ssryllc lirtGd rbovc arc prcrartod on the following pegcr.
- All cslc1llrdoos .Ic pcrfoEEd Horc roundln8 o avold round-offcrrors iD c.lqtlatcd r6un$.
- Rcsrlrs ooLd rs 'ND' wsc rnt daccred * or cbovc dre sxsrcd lknll*
- This rcpon mu$ not bo reproducd, of,c.pt itr ftll. withilt tE vrlftca rpprovel of thc labonory.
- RlstlG fot the folowing prrttrctqB ile Hcr rtgonod on a dry wc{ght b.sii: alor, conosivity, dasitn flashpoi*, iSnitrbility, lryers, odor,
prin liltcr trs, pH, poroslry prcrsur, rcactivrty. rrdor potsrtirl, ryccific gravity. +ot t ds, colfotr, solrrbiliry, taryorsntro, vlscoslry, ard wcidt.
STL Denver
O
t RS Corporation
Cl-ient Samo1e ID: GIil-BvUg );09 L2O5
Ssrrarn Trent Laboratoriee - RadLochsrlttrV
Lab Sample fD:
Work Order:
Matrix:
llalalatar
D5r130l_87-001
HKE].8
GW
lmult
Date CollecEed: 09 / 12 /A5 0800
Date Reeeived: 09 /13 / 05 09L5
IttoEal
Ilacrrt -
QurI (2 o+l -l DlDe
Ercp .lsrlyrlr
Drto Datt Drtob I Yld B
ffio88 LlB BY
Ororr Botr
ofPc EPf, 900.0 !fioD
103
ecLlr,,900.o HoD
09 laalas 09 la$la5 535.1293{
lfotrl Uranlrm b1z
Totrl UrrnLuro
KPr, .trgl[:}I ,L7 {-97-
0.688 J 0 .073
Lllfr IT,
0.31
5171-91
o9l2T lo5 0917810, 5269090
oRogB .L BI co-PnBeIP silww 7110 tNoD
Ororr tapbr 3.3
r,cllL 7110 r@D
09 tzt I a3 091251A5 52660851.4
RA-226 DY EPI-9O3.0 MOD
Radttrn . (22 5) 1 .51 0.30
D,CLIt
0.19
903 . O DIOD
as tLttos as not 05 '52s7t]-? 101
RA-228 Br OrPC
Rrdlrrn 778
EPr' 90d uoD
2-63 o .57
DCLIL
o.68
90I tfi)D
09 llll os a9 lla I o5 5.257114 79
ro THORIUII (gHORtr Clf) DOE l-01-R tlOD ecJ-lL l-01-R rroD
09116105 09t7fJ1a5,
09 /76 / 05 09 /20 t A5
5259114 9l
s259114 94
llhorLun 23O
Thorl-um 232
0.19
-0 - 008
ir
U
o.I.t
o.0{8
o.11
o-10
(8)
i qr. Lnooqgl.ots rlthoNrE thr orlc srrntlvc.
uDc I,t dctcmlmd by Lnetnuornt porforluaaoo only.
BoId rorultr rrG gfroat.r tshru tho IIDC
J Ruult k groettr bhrn reqllc dctcotLon ltntt buE
S,TL IDo$Vdr lur thrn tbc rarylla drrtactlon Il.nlt,.
losg thu gtrtod roportlng llxrLt.
IIRS eoqporation
Clt.nt Sarnrrle rD : GI[-B$I01-0 9L205
Severn Trelrt LaboratorLeg - Rldt oche{nl gtaTf
.O
Lab Samp1e ID:
work order:
MaErix:
Prrroctcr
D5113 01 87 - 002
HKE2A
GW
Itou1t
llotal
Ungcrt.
Q *l-l t@C
Pr.D rne,ly;,lr
Drtr tlrt. srtotr I
DaEe Collected: 0 9 / 12 / 05 l- 1- 15
DaEe Received: 09 / L3 / 05 09 1 5
Qu.1 YI'd I
OROBE AIB BY O'PC
Orocg Bcta
EPt 900. o DIOD
175
plcLl[t 900. o DroD
09lz]-l05 09lasla5 5"61L2966
trotsr1 Uraaluu t,t;
Totrl' Urrsltrn
KPr r8II[ 5L7t-91
0.857 u 0.092
u;glL
0.31
3L7 4-91
09127 105 09128/03 526r0to
OROSS }, BY EO-PRTCIP S!mITT
Ororr Llphr 2.9
77J.A HOD
,f
DCt/L 7110 liOD
o9l23lo5 aelzslos 52660851.3
RL-226 By EPr,-903. O !0D
RidLrrn (226) 1.lg o .31
DcLI,,
o.77
903.0 l[oD
ogltelos ogl3olos s3s7113 95
RI-228 BY OTPC
RrdLurn 278
EPr 90{ rcD
7.79 o. 61
DCT/L
o.77
90{ D[oD
og t L{ t 05 09 na t 03 s257111 72
f;o THORIUIil (gHOHf CT) DOE l-01-R
Tborlum Z3O O.1O2 df
Thorlum 232 -0,008 U
ocLlt r-01-R lroD
09/16/05 09lzOla5 525e11.
a9 /16 / 05 09 /20/05 52s91L4
0.097
0-049
0 .090
0 - 10
87
87
hta ar. Lnoqlhtr sltbouts tLr caro nrrntlve.
tDC' ls drtmlncd bfr Lurtnrmcat, perforurnoc only.
EoId roulta are groetcr thrn tbc UDC
J Ruu1t Lt grerttr tban ge$llo drtootlon llrit hrt lrrr
ETL Dcrnvdr lcrr than thc rtrEllo dttootloa llnlt.
tlrrn rtrtrd rrgortlng lldt.
IIRS Corporatl,on
Client Sanrple ID : GI!I[-BIV02-0 9L205
Esrrern Trcnt lraboretorlct - nadLochfintttry
Lab Sample
Work Order:
MaErlx:
Pa-rrnrtor
D5r1-30I87-003
HKE2D
Gt'I
Rolrlt
DaEe CoLlected:
DaEe Receive,il:
oe /L2/0s L222
a9/L3/05 0e1s
Prop
Drto
ImlfrLr
Drtr ArtoU I
OROgg AIE ET
Oroon Botr
orPe fPt 900.0 MoD
95
pct /Lr 900. o ltoD
09l2r.lo3 09125103 576r1,"e
Totrl Uranl-un W
lFourl unaLuu
KPl. laT![
o -{15
5L7 l-91 ulglr'5L7 l-91
09117 /0s a9lzBlos 526eoeo0. oo7 o ,31
oRogg }' EY co-pREcrp gusfw 7110 lroD
Oror: t}pbr 3.1
ecL lt,7110 ![oD
aglallos a9l73laa 52660851.1 1.2
Rl-236 BY llPL-9O3.0 IIOD
Radiuu 1226l L.?7.
pCLITl,903 . O t{toD
ogttttos 0e/30/05 '.2577.r,2
950.34 o -20
Rt-22E BX OrPC
RrdLun ZZA
EPL goe ![oD
1 .93
pct/r,904 lroD
oellllay, oe/30/o5o-50 o -6'I JzJ't 114
!-"' trEo*-I,'
Thort rm 23O
Thorlurn 232
(aHoR! er) Dor l-01-R MoD
o.1g
-0 - 008
gct.lL l-O1-R l@D
oell6los 0917a/o5
09tte/as a9/20/05
5a5911{ 8r
5259114 84
o-1
0.11
(s)
rro lroqllrtr rlthorrt tLe cart nerrrtl.ve .
l{Dc 1r dotarrnlaod by lnrtnlmrnt pcrfor'mancr ouly.
Bold rrrultg uo grratrr than tbt lDC
'f Rrrult tr grcrtu thrn reqrlc dctcotLoa llett but lcr
BTL Blgglfdf hr; tban tbo grmrlr drtsrotlon U-nl.t-
thnn rtatcd rtportlng lfunLt -
QC DATA ASS(rcrATrON
D5r130187
Sample Preparation and AnaJ-ysls ConEroI Nr:mbere
TIATRIXSAI.IP,I,Ef
001
002
o03
GUI
GhI
G$r
GW
GW
GW
GTI
GW
GW
G$r
GW
GTt[
GW
GIIII
G}ul
GEif
GW
GW
ANATJYTTCAI,
IUETHOD
EPA 9OO. O MOD
ASTM 5L74-91
SMViII{ 71.10 MOD
EPA 903.0 MOD
EPA 9O4 MOD
EIYIL A-OI-R MOD
EPA 9OO. O MOD
ASTII{ 5L74-9L
SMWW 71LA MOD
EPA 903-0 MOD
EPA 904 MOD
EML .8.-O1-R MOD
EPA 9OO. O MOD
ASTM 5L74- 9l-
sMsr!{ 7L10 MoD
EPA 903.0 I,!OD
EPA 904 I.IOD
EMII A-OI-R MOD
IJEJACH
BATE}I #
PREP
BATCH #
5264L29
5269090
s266 08 5
525'tLLz
525',1LL4
525 9l-14
s264L29
5269090
s26508 5
s2 57 tI'z
5257LL4
52591L4
5264L29
5269090
526608s
52 5'lLLz
52 5'7l.L4
5259114
I'[S RUN#
s264090
s269051
s265103
5257 A'18
s257 077
5259047
52640 9 0
s269 0 51
s255 1 03
5257 A7 I
5257 077
5259047
s264090
s269 05L
s255 1 03
5257 07 8
5257 0-77
5259047
STL Denver
O
C1ient Lot
Matrix:
PaflDtsr
UETIIOD BI,AIIK
flevern Trsnt Laboratoriee
D5r1_3 01-87
WATER
REPORT
- Rrdiochcmfgtry
Rcrult
:rotal
U[cort.
(2 o+l-l
Lrb arq>Ie ID
Pr.p .han1yrLr
htr Dttr Eatch I Itd i
CIROSS f,/I BY
Groes Beta
orPc tPl, 900.0 DiloD
0.68 u
1lci/t
o-67
900, o ![oD
1.1
rJr210000-1298
a9 /21/ 05 A9 /251A5 5264L29
GIROAS l' BY CO-PRIECIP
Gross Alpha 0.0
SHNW TLLO MOD
U
pet/r,
0. 16
?110 rroD
0-49
r5r23 0000- 0858
09 /23/ A5 09 /25/05 5256085
Rr-229 BY OrPC
Radlum 228
EPl' 901 !{OD
4.27
E'cLlr"
0 _ 32
90{ !iloD
0. s3
r5r1{0000-1148
09/L4/A5 09/30/05 5257L74 81
. nil.-zed lY xErA*903.0
Radlum. (226| 0. 09
DIOD rL/L
0. 11
903. O UOD
o. 18
r5r1{0000-1121
og /L4 /05 ag /30/05 52s77L2 10d
IgO .:MIORIU!!
orLurn 230
orium 23?
(SIIORT C'tf) DOE t-01-R ttoD
0.21 J
-0-oo4 u
rlC.L lr'
0.1{
0.045
t-01-R uoD
o. 06
0-087
r5r160000-11{B
ostk6las asl"oto5 5259114 95
a9/ 16/05 A9 /20/05 52s9114 95
ToEaI Uranlun btr
Totrl Ur;nLun
KPI rslTir 5L7l-91
o. {66 ar
us ll'
o-o{9
JL74-91
o.lx.
P5r260000-0908
oe tzT toa 09128105 5269090
ara Lnoqlhtt rlthout thr oa!. nrrratl.vl.
llDC It dctcrn:l.urd, urtng lartnrnrcat prrfomrno. ouly
BoIA rcrult,r rro gncatrr thrn thc DiDC
.r Rcsult [t grrortcr tban rruglr detrotlou ll-D{,t but lcgr
uSTL REhnU/gf trar rban rbr rrqrrr doroorlon ll.Ett.10thin 3tatGd rcDortlng llnlt.
Laboratorlr Contrro1
8even, Trent LaboratorLer
D5r13 0187
WATER
gDl,Lr lrcusts Rogu1t
lotrl
ullcart.
(2 o+l-l
Saryrla Raport,
r Rad.lochoLtgtrfr
o
Cllent Lot
MaErLx:
Prnnrtcr t YlCl t R.c
I,aI) 8aryr1o fD
gC Coatrol
ulnttr
m-226 BY
Ratlium (2261
EPr-903.0 DiOD
t7.2
Drtetr I r
11 .8
5257LL2
fr,LtL
1.4
903-0 lroD r5r1{O000-r12c
a.2 93 105 (54 136)
rrrlyrlr Drtr r 09 l30 / 05
R}-228 BY GTTPC
Radlum 228
EPL 90t !ilOD
5 -26
Batob *r
90{
a .97
![oD
0 .79
farlY'rtr Drtl r
68 L25
a9/30/0s
rsrI.loooo-1lrc
( s6 L47l
pcl/L
5. s5
5257]-L4
Igo IIITORfITU (SHORT CE) DOE L-OI-R !ilOD
Thorir:nr 228 8. 81 9 -2
Thortr:n 230 9.45 7 .7
Thoriun 232 8.82 9,1
lrtch ilt 525911{
D,tr;Llr,
1.1
1-O
1.L
r,-01-n uoD
0-1 96 104
0-09 96 82
0-09 96 103
tsrlyrlr Drte t O9 /20/Os
r5r160000-114c
(91 132)
t 65 L29)
(BB 133)
clRogg f,/B BI OrPc
Oroeg Beta
tPr- 900. o lroD
52.3 42.2
retob lr 5264129
900.0 lroD
t.0
lnel.yrlr Datcr
r5r310000-129C
(70 - raL)
9C;t lf.
81
09 tzsl a5
GO88 l' BY CO-ERECTP
Gross Alpha
sMww 7110 !ilclD
20 -6 20.o
Drtch lr 5266085
7110 DCOD
0-5
larl.frl,r Drtcr
r5r230000-o85c
t7L 143 )
pci/L
97
09 /25t A5
NOrE (s)
qq'ylDF\f,l.{r*?:lrrcif Dtr lartnD.lt lnrf,oreacr oaly" '*tafotstidt& rlo rrafoilc D.toaa losldfsg to avoid roro!-off .raoa l,! o.lorlrt.d r..rr1tt 11
Laboratory Control Sargllall;,C9 Dtrplicatc ReDort
Elewrra Trent lraboratorLor - R^adLochsrirtrSp
Dsr130I87
T,VATER
Client Lot
Matrix:
Prrerltor gDlk fnount,lenrlt
llotal
llDcrrt.
(2o+l-) tYtd
LaIc 8ary>1o II)
Qp Coatrol'
Llm{ f3 Erool'rl'out Rro
rotal UrrnLrrn t lf xPt Agmt 5Ll4-91
Total Uranium {0. O
spk 2 8-00
Batch lr
u;glI.,5171-91
97 (90
98 (e0
}rrrlyr:Lr Dar.s 09 / 28 / 05
r5r260000-090c
LLzI
7L2) 133 tRPD
39,O
7 .94
5259090
{.6
0.80
o
't "
![(I[f, (g]
StfflgEtt@trr. Ir.8fc!.d bofors rourdtlg to .volal roud-off ot:or Lr crlculat.d r.rult.,12
arrIL.d
f,rru1t
lLml't.
n lrrlt
rirl.lGo ortrLdo of ttrte'd AC l:lmLtr.
Lr grrrtcr thrn gaqll'o dctoctLoa ltlrlt btrB
Lr lcrr thra tbr re4r1c dotootLoo ll.rl,t.
lmr tshrn rtrtcd. rqrcrtlng
STL Denver
o
.O
13
C1ient Lot ID:
Matrix:
Parartsrr
D[trlrRIX
Scncrn
D5r1_001_5r-
GW
Apltr
Ircunt
lIotel
Ilao.rt - qgLlr AIHPIJE
l2 o+t -l Ild Borults
SPTKE/TIIATRIX SPIKE
Traat lralloretorl,cg
DI'PLICATE RTPORT
- RadlochctJ.Btry
DaEe Sarpled,: A9 / 09 / 05 0925
DateReceived: 09/LA/A5 08L5
EPIXE
lerult
Totrl gC Ar4rlr rD
Uncoxt.0C Cetrol'
(2o +t-l t Yld' ttoo r,Idtr
sRoss r'/B BY
Gross Beta
otPc EPt 900.0
804
Spk2 804
r,c,.lL 900.0
69 39
77 39
fralyrl.r dlte r
uoD
L2
L2
Prlolrlonr
09 /25 / 05
D5r100151-002
75
B5
L2 IRPD
64L
723
lr 5264090
(s0 1s0)
(s0 l-50)
Drtsh
GmogS ^ls Br
Gross BeEa
orPc ItPl goo.o
17 40
Spk2 t74O
lrtob tr
l- 690
16 80
5254090
pct/r, 9OO. O uoD
1_ 80 95
1.80 9s
D5r130187 -OO3
92 (s0 Ls0)
91 (s0 1s0)
Preoigl,osrl 0.5 $RPD
26
26
ra^alyrtr datrr 09/25/Os
Total. Ureniun
Tota1 Urarrl-runo
b8l, XPI .LgIrU 5
40.0
Spk2 40.0
36-3 a
35-9 a
Ir 525905L
us lT. 5L7 l- 91 D5I13 0187 - OO3
4.3 0.415 ,l 0-047 90 a (90 LL2l
4.2 0-415 J 0.047 89 I (90 7121
Prccl;loter 1 tRPD
tarlyrl.r drtsrr 09/28/45
GIROES }, BY CO-DRECTP S!mUW
Clroeg Alpha 4L -z
Spkz 4t -2
- Eatch
44.7
37 -2
tr 5266L03
picJ.lt,
5.8
4-7
Anrlyrir
7110 lroD
3.2
3-2
drtr r
D5r1301sZ -003
10L
B3
(s0 1s0)
(50 - 150)
1-1
1-1
a9 /2s las
Rr,-226 lY EPr-903. o lmD
Radium (2261 1L -7
spkz 11 . 6
15.3
16.3
Errotr *r 5257078
p,ci.lL 9o3 - O
L.7 96 7.7L
1.8 98 L-71
lna,lyrlr dato r
tiloD D5r130187 -003
0.34 es 1r-5 (66 150)
0-34 95 L26 (66 1.50)
Prooirlonr 7 tRF'D
09i30/as
Rl,-229 BY
Radlum 228
cxPc rPr' 90{ MoD
5. 53
SpkZ 5. d5
letch ilr
10.? a
9-4
5257 07 7
Dci/L
L.4 6s
1-2 77
}lrlyrlr
90{ }!oD
1 .93
1.93
drtr r 0e/30/05
0_54
0.5{
D5r130187 -O03
76 159 a (52 150)
7G 138 162 1s0)
ProolrLonr 13 SRPD
Ilo (srORT
Ttrorium 23 0
sbkl
Thoriurn 232
Spk2
er) DoE
9.46
9. d6
8 -82
8.82
7 _93
7.6
8.1
9.1
5259 0{ 7
SIC.Llt,
0. 99
1.0
1.0
1 .1_
.n-01-R !iloD
0. r.8 J
0.18 J
-0.008 u
-0-008 u
93
91
93
91
D5r130187-OO3
0 - 13 84 82 fi4 r.30)
o-13 s4 79 fif ilO)
Procirl-on: { tRPD
0. 053 8d, 92 ( 81 L24l.
0 - 0s3 Bd 104 ( 81 tz4t
Prcci;Lour 12 IRPD
tsoilE(e)
latch lr la^alyrl-r drto r 09/20/0s
GrlolrtLur aso Irrtorrrd bafora rotrrdlag to lvold rotrld-off rrfor h oalculrtr{l r.rsltl
STt Denver a4
STL Denver
Sample Receiving Checklist
ut*, '?atl1CI it? Date/rime *.a".a, Qft,y'i.r OqE O
Company Name & Sarnpliog Site:
PM to Complete This Section: Yes
Residual chlorinc cbcck required:tr
erote#: LllCr+O
Speciat lnsrructions:
{rl
Time Zone:
. EDT|EST . CDT/CST . MDTAdST . PDTIPST . OTIIER
Qr:arantincd :
Yes
I
Uopacking Checks:
Cooler #(s):
Terrperatures ('C):
N/A Yes No
D.F'trr_rt u z.
trrP3.
D.d4.
p'il5.
Dratr6.
,6' tr 7.
tr8.
D 9.
tr 10.
P1r
tr 13.
t] 14.
d"z+
*t. I 3,'1 -3. .i
/
3b
.w
fr'
,g
tr
u
tr
tr
tr
A)
Cooler seals intact? (N/A if hand delivered) If no, docurnent on CI-IR
Chain of custody present? If no, docr:ment on CuR.
Bottles broken and/or are leaking? If les, docurnont on CLIR
Multiphasic samplcs obvior:s? If yes, document on CIJR.
Pmpcr container & preservatives used? (ref- Attachmenr D of SOP# DEIII-QA-0003) If no, document on CI-IR-
pH of all sarples checkcd aud meet requirements? If uo, documcnt ou CUR.
Sufficienr volunr provided for all analysis requested? (ref. Attached D of SOP# DEN-QA-0003) If no,
document on CIIR, aDd contactPM before proceeding.
Did chain of custody agree with labels ID and samp)es receivcd? If no, documcnt on CUR.
Wcre VOA samples without headspace? Ifno, document on CIIR-
Were VOA vials preserved? Preservative DHCI O4+?"C OSodium Thiosulfate I Ascorbic Acid
Did samples require preservation with sodiua thiosulfate?
If yes to #1 1, did the samples contain residual chloriae? If yes, documeirt ou CUR.
Sediment present in dissolved/filtered bonles? If yes, docrurent on CLIR.
Is sufficient volume provrded for client requested MS, MSD or matrix duplicates? If no, document oo CII& aod
contact PM before proceeding..
F-
.p'
x
tr
tr
c
{ S. Receipt date(s) > 48 hours past the collection date(s)? If yes, notify pA/pM.
P' 16. Are analyses with short holding times requested?
,d fi. Was a quick Turn Around (TAT) requested?
O
STho?3,*S?"6Ie
Rrcciving\Sampte Receiving checkiist 12 13 04 revision l 2/t3/04
STL l)envcr
Sample Receiving Checklist
l-ot #_
krgin Checks:
N/A )'e.r Na
E' t lg.Sulficicnt r,olumcprovidcd for all analysis reguestcd? (rcf, Anaehmcnt D of SOP# DEN-QA-0003) lf no,
document on CllR, aod conlacl PIr4 bcforc plocccding.
O rt A 19- Ie suflicicnt rolume providcd for client reguested MS, \4SD or matrix duplicares'? Ifnq documcnt on CLJR, anrJ
contact Plvl bcftrc proceeding.
tJ
,d
20. Did the chain of cusrody includes "received bf' and "rclinquishcd" by $ienaturcs, d;rres, and timss?
2I- \\,erc spccial log in instruclions rcad and followcd?
22- Were AFCEE nrctals loggcd for refrigeratcd Btorage:'
23. Were tesls loged checlied againsl fhc COC? \4lhicb samplcs werc cortlirmcaZ I
24. \\ras a Rush frrrm corrplctcd for guick TAT".r
tr O 25. \\Iar a Shofl Hold form complctcd for anl,short holds?
D /F 26. Is'SuictlCo0'required?
tr V 21 . Wcre special ardiving instructions iadicated il thc Gcncral Conrncnts? lf so, r'.,hal were thef
Labeling and Storrge Checks:
,5 rJ
,gD
irI
{D
!D
II
fI
D
Dooum--nl anl,problems or discrepancies and the aclions taken to resol't,e them or a Con<iition Upon Receipt Ar:omaly
Report (CuR).
.w
,d
=r4
{at's :rd
{-,
EiD
trD
TI
28. S'as tln srbcoffiact COC signed and spnt witb samples ro botrle prcp?
29- Werc sample }abls double-checled b1,a secoad person?
30. Were sarylc botlcs md COC double cbecked for dissoh,ed/filtercd metals by a recond plrson?
-31. Did the sarryle ID, Date, aad limc fiom labcl march u,hat uas loggcd?
32. Wcre stickersfrl spccial archiving instruaions affir-ed to eacb box aud tofrre ICOC? See #27
33. Were AFCEEmctals slorcd refrigerared?
.34. Wcrc "Strid ICOC''copies given to satellite stora-se areas?
STL Denver a6
co
d
I.
i
l
i
,-
.
=
[E
[
f
i

g
EI
E
E
i
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'a
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r-ct
,
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.
+

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,
-
oa.T(D t?o o-
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.

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\.
-
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De
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e
r
STL Denver
4955 Yarrow Street
Aruada, CO 80002
Tel: [phone]
www.stl-inc.com
STL
303 431 7t7t
ANALYTICAL REPORT
Western Zirconium Proj ect
Lot #: D5I020209
Sheri O'Connor
URS Corporation
818 t East Tufts Avenue,
Denver, CO 80237
STL DENVER
-z
Linda L. Benkers
Project Managq
September 29,2005
Severn Trent Laboratories, lnc.
Table Of Gontents
Standard Deliverables with Supporting Documentation
Number of PagesReport Contents
Sfandard Dellverables
(Th, Cover Letter and the Report Cover page are considered integral
parts of this Standard Dellverable packnge- This report is incomplete
unless all pages indicated in this Table of Contents are included,)
. Table of Contents. Case Narratlve
o Executive Summary - Detectlon Htghltghts. ilIethods Summary
. Method/Analyst Sumrnary
r Lot Sample Summary
o Analytical Results
o QC Data Assoclation Summsry
e QC Sample Results
. Chain-of-Custody
Supporti ng Documentatlon
(Note: A one-page "Descript' n af Supporting Documentation" is
provided at the begtnntng of tltt-s section,).
o Volatile GC/MS
o Semivolatile GC/IVIS
r Volatile GC
. SemivolaflIe GC
oLCIMS oTHPLC
o Metals
I Conorol Chemistry
. Radiochemistry
r Subcontracted Data
Check bolow when
suppordng
documentation is
present.
nnnnrnmn
STL Denver
Case Narrative
D5r0202U)
With exceptions notod as flags or footnotes, standaril analytical protocols were followed in the
analysis of the samples and no problems were encormtered or anomalies observed. All laboratory
quality control samples analped in conjunction with the samples in this project were within
established control limits, with any exceptions noted.
The test results presented in this report meet all requirements ofNELAC, and any exceptions are
noted. This report shall not be reproduced, except in full, without written permission from the
laboratory.
Sample Recelvlng
Twelve samples were received under chain of custody on September 2,2005. The samples were
received in good condition at te,mperatures of 23.9"C,24.0"C,23.2"C,2.3"C,2.4oC,2.6"C,
2.3"C,2-7oC,2.8oC and 5.8"C. Note that the ending IDs for samples D5[O2A209-009 through
012 were -O91005 on the chain of custody. Per client instructions, the ending IDs were changed
to -{90105 to be consistent with the other samples in this lot.
The results for all radiological analyses are included in this report and were performed by STL
St Inuis; 13715 Rider Trail North; Earth Citlt MO 63045, phone [phone].
Radiochemistry, Various Methods
The method 900.0 MOD gross beta MDA for samples D5I020209-001 through 012 was not met
due to reduction of sarnple size caused by high residual mass. The analytical results are reported
with the MDA achieved.
The method 7110 MOD gross alpha MDA for samples D5lWA20g-001 tlnough 005, 007, 008,
009, Ol l and 012 was not met due to reduction of sample size caused by high re.sidual mass. The
analytical results are reported with the MDA achieved.
Samples D5I020209-001 ttrough 010 were analped at a dilution for total uranium due to mahix
interference. The reporting limits are adjusted accordingly.
The thorium 229 tracer recov€ry for sample D5I020209-006 was below the conhol limit. The
sample was re-pr€,pared and anabzed with accepkble hacer recovery.
Gross beta was detected in the method blank associated with batch 5252106 at a concenhation
above the re0ofting litnit. All associatd seffi0les had Soss beta concentmtions et leest five
times greater than the blank concentration and no further corrective action was taken,
A low-level and a high-level tCS standard were analped with total uranium batch 5255166 and
they are qpiked at different concentrations. Therefore, the RPD value reported for these two
standards does not apply. Both LCS recoveries were in control.
Denver
The gross beta, radium 228 and thorium 232 MS/[/[SD performed on sample D5I020209-002
were in control.
The total uranium MSA4SD performed on sample D51020209-002 demonstrated recoveries
below the conkol limit.
The gross alpha MSllrdSD performed on sample D5I020209-002 demonstrated recoveries above
the contol limit.
The radium 226 MSD performed on sample D5I020209-002 deuronstrated a recovery above the
control limit. The MS was in contol.
The thorium 230 MS performed on sample D5I020209-002 demonstuated a recovery below the
control limit. TheMSD was in conkol.
The thorium 230 and thorium 232 MSATSD performed on sample D5l02O2Og410 were in
control.
The radium 226, radium 228, total uranium and gross alpha MS/MSD performed on sample
D5I020209-010 demonstrated recoveries below the control limits. The RPD for the total
uranium MS/IvISD was also abovethe control limit.
The gross beta MSD performed on sample D5I020209-010 deinonstrated a recovery below the
control limit. The MS was in control.
The isotopic thorirun duplicate was perfomred on a sample from another client and/or lot and
was in conhol.
STL Denver
METHODSW
D5rO202f,9
PARAMETER
ANATJMTCAI.' PREPARATTON
MHTHOD T{ETHOD
Groes Alpha (COPRECIP) by GFPC Sl'tM{ 7110 MOD
crosa A1pha/Beta by GFpC EpA 900.0 liroD EpA 900.0
Ieotopie 'rborium by Alpha Spectro6copy E![IJ A-01-R MoD
Radlum-226 by GFPC EPA 903.0 I{OD
Radium-228 by GFPC EPA 90ll liloD
Tota1 llranitrm By Iraser nh osphorlmetry ASTl,t 5174-91
Referencea:
ASII'i Annual Book Of ASTI.I Standard6.
EMt TENVIRONMBNPAIr MEASTREMENTS L:ABORATORY PROCEDTRES MANUAIJT
IrASrr-30O 28TH EDITION, VOLIIME I and II DEPARITiIEI{r OF ENERGY
EPA "EiASTEB.!U ENI:IRONMEIInAITRADIATION FACILITY RADIOCHEMTSTRy
PROCEDURES tr/TAIII'AIJN US EPA EPA 52015-84-006 AUGUST 1984
SMWW 'STANDARD METIIODS EOR Y{ASTE WATERU
STL Denver
A}IAIJYTICAI-r
METHOD
MBIHOD/AIYALYSI W
D5rO20209
A}IALYST
AI{AI,YST
ID
ASTI'{ 5L7 4- 91
EML A-OL-R IIIOD
EMIJ A-01-R MOD
EPA 9OO. O MOD
EPA 903 ,0 MOD
EPA 9O4 MOD
EPA 944 MOD
sMww 7110 MOD
Referenceg:
AslIt{
EML
EPA
sMttlw
Mike Anderson
Rtronda Ridenhower
Rhonda Rl-denlrower
Rhonda Rtdenhower
.Timnry Wtleon
Bob Nicholas
Bob rulcholas
Bob Nicholas
402350
050040
60040
060040
4 01,627
4620 0 6
62006
52006
Annual Book Of AgTtvI Standards.
trEIiIVIRONMENTAL ME,AST'REMEIITS LABORATORY PROCEDI'RES MANUALT
HASI,-300 28TlI EDITION, VOIIITME I and II DEPARIIIEI{T OF ENERGY
IIEASTERN EMIIRONMENTAIJ RADIATION FACILITY RADIOCHEMTSTRY
PROCEDT]RES IUIANUAI-IT US EPA EPA 52O / S- 84 - 006 AUGIUST 1984
NSTAIqDARD METHODS FOR }IASTE WATER'T
STL Denver
SAI}IPLEW
D5rO20209
WO # SAMPLE# CLIEMT SA},IPLE ID
SAIYIPI,ED SAMP
DATE TTME
H,IWI6 001
H.JI/rc( OA2
Hir\ru(P OO3
Hir\ms 004
rIirvKS 0 05
HJ\'I[JF O O 5
H,f\ru,J 007
HifVLIr O08
H.ITLV 009
H;nrLo 010
I{J\IL3 011-
HII\'IL7 01'2
NcrrB (s) :
PW-Ag 2-A90105
P9I-A2 - 090105
PW- C2- 0901_05
PW-41- 090105
PW-W- 090105
PW-S1 - 090105
PW-Cl - 09010s
swB-910-090L05
s9rB-9-090L05
gTrB-10-090105
shlB-3 - 09010s
gwB -7 - 09010s
a9 / ot-los oB :00
a9 / oL/ as 15 :15
09/aL/05 r.5:30
oe / aL/ os 15 :35
a9/aL/as L5:40
ae/oL/os L5:.47
oe / aL/ as 15 :5e
a9 / ot/ as 07: oo
oe / o1/os 1o :55
a9 / o1los t-2:10
09/ oL/os 13 :37
a9 / aL/ os L4:20
- TDe rn8lydcal rcerlts ofrhc snpld lir6d rbovc are prctanrcd on tbc folbwinf ptgos.
- AII crlcnlritions erc pcrformcd Mor. roun ling !o tvold roBIld-off crrort h crlcidsl4d r€ful6.
- Results no&d a! "ND' ycrc not d6tadod il or rbov? thc sdod limit.
- T[ls topon musr not bc rcproducrd, acept in full, wlolout r,lc writtB apl]rovrl of lho lEbontory.
- Rentlts for the followi4 prrunelors ero lov€r roportcd on a dry wdgfu buis: color, conocivity. dmfty, fhshpoim, igniubillry, taycrr, ottor,
pAint filtc, t4 pH, poroefuy prcssurE, rcacrivity. rcrlox poeadat, ryccific gmvity. ryor tssB, solkh, rclubility, teopcra$tE, viscosity, Erd wcight.
STL Denver
URS Corporation
elient SurcIe ID: PI{-492-090105
Savarn trreat Laboratoriee - RrdLochmlstaTr
Lab Sarple fD:
Work Order:
MaErix:
Parartrr
D5r 420209-001
HiNrIIS
WW
Rcrult
5otsrl
Unocrt.
QurI (Z o+l -) rcC
?rqt lnalyrLt
Dats. Ilatc trtoh t
Date CollecEed: 09 / AL/ A5 0800
Date Received: A9/A2/45 0900
Yld t
GrROgs f,/B
Orott lctr
Br orPc tPt, 900.0 ttoD
1850
OCLllt 900. 0 !!oD
o9lo9lo' agl,.3las 5252106
totrl. tlrrn:Luu, bXr
Totrl Urrnluu
KPt ra:m[ 5L70,-91
{580
ug llt 5!71-91
09/13 lA5 oel 15/05 5255166
oRogg }. rr cp-DRnerp grofw 7110 rnoD
Orosr ll.phr 89O
r,CLlt'7110 !!OD
o9la8lo5 091L7 lo, 5251473
U-226 BY trPL-903.0 IIIOD
Rrdl,ru (2261 7.8.7
ecLlL 903. O MOD
a9 la6la3 a912,21a5 52{9099 70
R[-228 BY OFPC
Xrd,Lum 77A
EPr 90{ ![OD
10-g
D,eLlL,90{ l[oD
a9lo6los a9l7zla5 52.9100
Iro ltiHORI[ lt (gilOR':f
Thorlun 23O
Thortun 232
clr) Dot r-o1-B
3.87
0-6{ J
l-01-R rffln
oglLtlo, 09lL6las
09/13 to, oel 16/05
5256085 56
525608s 66
gcj-lt
a .71
0 .39
0.13
0 .19
Drta irG Lnoq>btr rlthouE thr om. Dlrrrtlvo.
IDC tr dctcmolnrd bry lnrtnuot pcrlornrucc only.
Boltl tcmlt. rrG !r.rt.r tbrE th. IDC
it ncrult lr llrcrtcr thra .qrl. dot.ctl.oo ltrtt hrt 1... tbaD rttt.d rogortlag lt[tt.
STL Denver
IIR$ Corporation
Cll,ent S+rrrrrle ID : PW-^L2-090105
Severa Trent taboratorLeg E nrdiochmlrtrryr
Lab Sary)le fD;
Work Order:
Matrix:
Paranttr
D5r024209-002
HiNZKK
WW
Irru1t Qu.al
lfoEel
llborrt.
12 o+ I -l lrDC
lnrlyrlr
Dagl Dat. nateh I Yld, t
Date Collected: 09 /0L/A5 1515
Date Received: 09 /02/A5 0900
cmoss r/B BY
Ororr Brtr
orPc EPA 900. o ![OD
4830
ecl,lr,
190
900. o uoD
ogloel05 09113/05 5252106
trote1 Un'tLun bry
Totrl Uranium
KPA l8rl[ 3L7t-91
50{o
taglL 5170-91
o9ll3to3 a9lt7la5 52s5166
sRoss r BY Co-PRECTD Srmr 7110 !ilOD
Orora Llphr 635
pcL/Ir 7110 tloD
o9t 08/0s 09tL7 los 5251{73
RA-226 BY IEPI,-903 , O ltOD
Rrdluu (226) 15.1
pct/r,903. O UOD
a9lo6lo5 aelazlo' 52{90ee 73
Rf,-228 BY OrPC EPt 90{ tlOD D,CLlt 90{ noD
09105/05 a9lzzla3 52a9100
.1,-01-R lloD
09/13 I OS A9 t1,61O5 5255085
o9ll3lo5 a9lt6lo, s256085
Igo TIIORTITU (SIIORT
'lftorlun, 230
llfborl,un Z32
CT} DOE f,-01-R rcD
3.67
0-66 ir
o .71
0-29
65
65
Ilata Lr. lacqllrtt rlthont tho caro nnrrativl.
DIDC ir drt,orurLatd by Lartnunrut porformrnor orrly.
1016, rtru1tt lr. gruttr thnu tho IDC
if Rrntlt la grrruor thrn mqlk dttrstLon 1l-{ b tnrt
STL Denver
Iorr thBD atatcd rr5rortlng lLutt.
IIRS Corilloratrlon
CIJ,ent, Samle ID: PW-e?-090105
Srvcrn, Trent rraboratorl,cr - nrdiochrrr{ rBrlr
l,ab Sampl-e ID: D5I020209-003
Work Order: H,JVKP
Matrix: WW
Paranrttr lou],t Qual
ItotaI
Ilaecrt.
(7 o+l-l
Date Collected:
Date Received:
09 / 01/05 Ls30
ae / a2 / 05 0900
enl yrLr
Lt.
DrrD
htc Batob t
oRogg I,IE BY
Glrorr Botr
grPc rPl 900.0 tf,oD
326
1lcL/L 900. o t@D
o9lo9lo, 09 l1.}la5 525210681100
TotsrL Urrnitrn D1z
lFotr1 Urr"1um
xPJ[ t.grl[ 517{-91
447
uslL JL? 4-91
o9ll3lo5 agt1,rlas 515516652
crnogs }. lr co-PrutcrP glDtw 7110 t@D
Orort l.1phr 20.3
DcLIL 7110 t{oD
09/08/05 agllr lo5 s251{73,1.7 2.8
Rl,-226 Br EPI-903 . O t[OD
Radiurn (226 ) 0. 03
DtcLlr,903. O !()D
a9/a6/a5 09 /22/O5 52490990-13 o.23
u-228 BY OXPC
Radium 228
EPl' 90{ ltoD
0-58
tc,LIL 90{ r@D
a9/06105 a9 /22/05 52{91000. 54
o.30
0.11
0. 86
rro THORTIIIT
'l[llrorl.rrn 23 O
l[horLum 237
(gIIOnr c:f) DoE r-ol-R lroD
o-go ir
o. 11 ir
D,C.Llt'l.-01-n,
o9l1s I OJ
oel13 I Os
ltoD
09lLSlar
ae tL6ta,
1256085
5256085
Dita ar. Lncoqllrtso rLtbout tha oaro nrrrlt:Lvc.
t@C lr doternlncd lnf lnrtnrnret Dorlomuoo ouly.
Dold r.ruIt. rr. gr.ttGr thr! tbc tOC
a, norult l,r grrcrtcr thro ru4rlo d.t.ct{6 lhtt hrt 1..a thrn .tot.d rqrotrtr.ag llDtE.
ETL fuflE€fl ler ttrrE Ehc rqrlo dotGctl,og lr.Dl.t.
t RS Corporation
C1i.ent Sasncle ID: PW-A1-090105
Scrrcrn, Tnut LaboratorLeg RrrdiochmI.rtry
Lab Sample ID:
Work Order:
Matrix:
Plramtcr
Dsr 420209- 004
Hinm5
WW
lorrrlts
totrl
Ilborrt,
OurI (2 o+ l -l ilDC
Date collected: 0 9 / AL/ A5 153 5
Date Received: A9 / OZ / A5 0900
rr.D .trnrlytl.
Ihtc ftt.
l
ratch t Yld t
GIROgS AIE. BY
Oroaa Botr
orPc EPl. 900.0 uoD
3710
rlct/r,900. o lNoD
o9lo9lo5 09l1.3lo3 5252106
Totral Urasluu bur
totrl Urnnlum
KPr, r8ril 5L74-91
3 610
luglI,317{-91
09 tLS tos 09lL$l os 5255166
mog8 .tr lr co-PREcrP 8Dtllw 7110 riloD
Ororr l'lpbr 371
rEi/r,7110 t[()D
o9lo8to5 aellT lal 5251t73
Rt-7z.6 BY tPl-903. O r[OD
Rrd,Lrrm (226) O. {O o .21
trj.lt
o .29
903.O IOD
09106/05 09l77lo3 52{9099 75
RE-228 BX OtrPC EPr' 90{ ltOD pCIlt'901 uoD
un 228
Iao 'fHORfIrDt
Tborl,usr 23O
fhorl-uur 232
10.2
(8UORr grl DOt t-01-R t[OD
1- 15
o-30 ir
a9 I 06 lAa 09 t22t as 52{9100
0.34
o. 17
Dct/t l-01-R
09/13 lO'
oel13 I As
rcD
09l16tas
a9tt6t05
o. 09
o.11
5256085
525608s
81
81
or. lrooqllrtr rLthrnrt tL. oar. na:ratlvr.
lDtC Lr d.tdrEln A bU l'attruuo' grrlo*usoo ely.
Bold rrrult. .rc grcitcr ttrlr th. tDC
i, Itcrflt La grcator tbra rrmrle dttootlo llni,t birt lur thu .trt.d roDortlag lfudt.
STL Denver
URS Corporatlon
CILent Sample ID: PI{-W-090105
Ecvern Trcnt Laboratorict E RadLooh@irtry
Lab Sample ID: D5I020209-005
hlork Order: HinruCB
Matrix: WW
Paramttr tre;ult Outl
Totsrl
Irncarlt -
(2 o+l -l
Date Collected:
DaEe Received:
09 / 01/ 05 1540
09 / 02 / a5 0900
ls:lyrlr
Ilrt.
Drep
Drtst Htorr I
GrROSg r/t BY
Ororr Bctr
orPc EDt 900-0 !!oD
L720
D,c,LI'".900. o !@D
oelogtos o9lt3lo5 52521065?0 72A
Totsal. Ureal.rrn bgz
Total. Urrul.um
KPf, .Lgttrt 3L7l-91
103 0
lg lr,517{-91
aen3lo' 0el,5lo3 5255166110
OROSS .I' BY CO-PRTCIP glilflW ?LLA
Ororr tlphr 198
![oD I)eT/I,7110 DIOD
09/08/05 091L7 las 5251{73
m-225 BY EPI-9O3.O ltOD
tr^adLtm 12261 2.91
nCLlrt 903 .0 !ilOD
a9 I 06l A' A9 nz I 03 52a9099o.5{0.36
nr.-228 BY OrPC
rrdirrn 2718
EPt 90{ riloD
6. t6
f,cl/L
o.9g o.gt
90{ tiloD
a9lo6lo5 09122103 52{9100
Iao .:IIIOnIUU
ftorlun 23O
EborLrrn 232
(sHOnr er) DoE t-o1-R toD
o-24 J
o. o51 ir
S,cLIT..1,-01-R
oelr3 ta,
ae lL3 I os
!!oD
a9lL6 t o3
09 I 16/05
5156085 89
5256085 89
0.15
0.081
0.05
0.055
Datr f,rc laoq>Lotr wLtborrt tho ors. nllrrrtlvl,
IOC l. drtoralard by Inrtrruat lnrforanaoc oaly.
BoId r.rult. rr. 9f,6rtar thr^u tb. tCrC
iF Bcrult Ir grcatrr tLaa ramrlo aLucotloB tlett tlrt 1rlr thra rtatcd rqrortlag I'lntt,.
STL Denver
t RSI Corporation
C1Lent garrmle ID: PW-SI-090105
Ssvrrn Trent l,aboratoricg - Rrdlochmlrtryr
Lab Samp1e ID:
Work order:
MatrLx:
PararrEar
Dsra20209-006
ffiruLF
hnltl
R.rtrlt Ourl
Totrl
Ilaorr:t.
(2 o+/-) ilDc
.Burlyrl,r
h,tr hg. lrtob I Yad I
Date Collected: 09 / OL/ 05 1547
Date Received: 09 / A2 / A5 0900
oRo88 L,/B By OrPC
orori tota
EPt 900.0 tmD
780
pCt/r,
760
900. o DCoD
09/09/05 09lltlos 5232106
rotrl Urrnl,un Iilf
Totr,I. Urenlur
xPjL 181ril 5L7a-91
27t
u;glL 517{-91
09 llt to, a9 l!.5las 5355166
(n@g t BY eo-PREcIP 8lffirr 7110 t[oD
Ororr Llphr 35.6
oCLlt'7110 lroD
oglotla5 09fLT ta, 52511731.3
il-225 BY EPI-903.0 INOD
nrdLun 1ZZ6) 1. 85 o.iL?
D,cLlT,
0.37
903. O !@D
a9l06lf,5 09 l22ta5 52.9099
m-229 DY GrIrPC EP,\ 90r ICOD pC;Llt'901 lEoD
22A
ao EHORII,II
2 -93
(gHoRT CB) DOE t-01-R ttOD
1.99
o. {o ir
09/05/ os 09l77la5 5249100
DC;Llr.r.-01-R
o9l25l05
09t26t05
tmD
091"7 la1
a9177 la5
|Ehortum 230
fh,orium, 232
a.76
0.36
o. {o
o.37
5269393 78
5269393 78
ta arr iacq>lrtr wlthout tho orr. nrrntivg.
f,OC Lr drtraLnod btr lartnmat D.Efornrooe ouly.
Bold raltrlta rra gaartcr thr[ thc IIDC
,I It .u1t lr qrretrr thrn rrqrb d,otrotloa lldt but l.m tbaa ltrt.d roDortlag 1tdt.
STL Denver L2
URS Corryloration
CLLent SarcIe IDs PU[-C1-090105
Srrvcra Trent LaboratorLe; - Rrdl.ochgLiatry
Lab Samp1e ID;
Work order:
Matrix:
Paramtor
Dsr0202a9-007
H,ruIJJ
WW
Rcrult gurl
l[otaI,
flagert -
(2 o+l-l roc
PrrD .trarlyrlr
Drtc ht. Ertolr I
DaEe Collected: 09 /0L/05 L559
Date Received: 09 / 02 / A5 0900
Ylo t
cRogs ^lBGross Beta
BY GIFPC EPl. 9OO-O !ilOD
88u
f,cllr!
110
900. o !iloD
09/09 los 09/].,3/o5 5252LA6
Botrl- IIrraLun, br!'
Totrl Unul,rn
xPf, rslxfl 517{-91
15.5
ug ll'517t-91
agtl3toi 0e/15/05 5255166
sRosg t By co-paEsrp glfifTt 7110 DmD
Ororr AJ.pbr 5.8
r,cl/t 7110 l@D
09toBla5 091L7 los ,75tl73,3-1
RL-226 BY EPA-903. O !ilOD
nadl,rrn (226) 0.lO o.20
s,cL ltt
a -27
903. O )DD
09106105 09lzzlos $2t9o99 86
Rl,-228 lg orPc
RrdLun 2Ag
EPL 90l ![oD
1. 05
g,C;Lll'
o-87
904 troD
oel06/05 09l22l05 52r91OO
fro THOIIUU (AHORT Cf) DOII .I-OI.-R ![OD
Eborl.um 23O O.32 if
Thorlum 232 0- 010 U
o.57
o.18
0. 058
plC!.lft
o.10
0-13
l-01-R ltoD
oel13 lo5 09tt6loi
09 /13 /as a9 /L6 los
52s5085 7A
5255085 7 8
Data ara taoq>lata rritLout tb. orro rrrrra!173.
!{De lr detor:niD.d br Lnrtnruont, pcrtornanoc onry.
BoId rorultr lrl grrrtrr thrn uhe mC
if Rctult 1l grrcatcr thtu rarrgrlr drtrotlon ltntt but
gTL tsetplrte$ Imr tshrn tho rrnplc dctootl.oa lLlrLt.
lcr Ebrn rtrt.d rcDortlng llmlt.
13
IIRS Cor?oration
Cli.ent Sample ID: STilB-910-090105
Sgrrern Trrnt LaboratorLu - Rrdiocbrqql Btrfz
Lab Sample fD:
Work Order:
Matrl-x:
Prrlnat.r
D5rA20209-008
HiruLL
GI^I
Rerult QorI
lFotal
Ilbot-t.
(2 o+l-) mc
Prrg rlrlyttt
Drto tLtr Batch t
Date Collected: 09 / OI/ A5 0700
Datre Received: A9 / A2/ 05 0900
rad r
oRosS ^lBOrotl tatt
BY OrDe ItPt 900.0 tiOD
1050
pct/tr
za0
900. o MOD
o9lo9la3 09/13 las 5252106
llotal. Uranlun bUz
rotrl. Unnl,un
KPr, tg|lltt 5L7l-91
6-73 J
u,slt 517{-91
oel13 la5 aellrlos 5255166o.70
GOgg l' Br CO-PRICTP gt{lww
Gross Alpha 1-d
7110 tfioD
u
*LlL 7110 t@D
09/08/05 a9 /L7 /As 525L4732-0,
Rr-226 BY EP -903.0 UOD
Radlr:n (226 ) 0. 05 0.14
ECLIr,-
o -26
903.0 tioD
09/06 /05 0e /22/05 5249099 71
nr-228 BY OrPC
Radirra 224
tPl 90{ ![oD
1.69
DcLIL 90{ !iloD
09106105 0el22lo5 52.e100
(srroRT er) Dor f,-01-n uoD
o.13 ir
-0. 01 u
pcllt,.L-01-R
oel1s I o9
09/13 /05
tioD
09 tl6l o3
09/L6/A5
63
5256083 77
525608s 72
Thorlun 130
Thorium 232
o.lt
0-060
0-11
o-13
to IIHORIITII
lr. lnoqllotr rlthout thr cata nrrrrrtLvl.
DIDC tt drtrrrnlaod by lutruorat gorfomauoo ouly,
BoId rrrults uG grrcrtrr thrn thr DIDC
J RcrulE t r grrrtor thtn mrylh drtrotlon t{rn{ t tnrt
$fl H11\feil lert than tbr u4r1e dotoatLoa Ituntt.
Iur thrr rtttrd rollortlug lLn1t.
1,4
t RS Corlporation
C1l,ent SanpLe fDr SISB-9-090105
Srrrcra trrent LrborltorLc; - Rrdl,ochsnlrtry
Lab Sarnple ID:
Work Order:
Matrix:
Pr'rurErr
D5r020249-009
H;MLV
GW
Brrrrlt
ItotrI
flnotrt.
17 o+l-) ulC
Prr1l lnrlytl.r
ILtr ILte Drtob I
Date Collectred: 0 9 / 0L/ 05 1055
Date Reeeived: 09 / 02 / 05 09 00
rrd r
cRosg .L/t Br
Ororr Brtr
orPC tPl 900.0 t[oD
1810
scLln
520 580
900. o !iloD
a9 lo9lo5 09/11 los s252106
Tot,r1 Urrnl.urn Dry
Totrl Uranl,um
KPr rsrlr JL1 {-9L
L71
vg llt 517{-91
oetl.sto' oe/15/o5 5255166
GrROga r' BY co-PnEclP g![g0w
Gross Alpha L-8
7110 lDD
U
Dct/L 7110 tloD
09/o8/a5 a9 /L7 /A5 52574,732-B
Rt-226 BY Ept-903.0 ltoD
Radlum (226) 0.L3 0.15
pcl/L
o.24
903.0 ltoD
09 /46/05 a9/22/05 s24e0e9
Rt-228 BY OrPC
Rrdlur 22ll
IBPI' 90{ UOD
1.76 o.6l
ecLlr,
o. 91
90t lnoD
ogloFlas oel?zlos 5249100 65
Iro THORTUII (ERORT
Thoriurn 23 0
Tt:orir:rn 232
c'lf) DoE .n-o,.-R
0. J.L u
0.0 u
r-ol-R riloD
a9/L3/45 09/16/Os
a9/L3/45 A9/16105
s2s608s 60
52s608s 60
0.13
0-0
0 - 15
a-2
Elrtr rr. tacqllrtr vl,tbout tho cata ntrrtEl.vr.
!@c Lt dotrrrnlncd by lngtnrnrnt gcrlorrnanco oury.
Bold rorultr r^r. grrcator tsbrn tbt tDC
U RcruIE Lr lrrr thrn tbr aaryllc dctcotLou llm:[t.
STL Denver
t RS Corryoration
C].Lent Samole IDr fIIiIE]-10-090105
Sewern Trent Laboratorlor - Itadloehmtigtry
Lab Sample ID:
Work Order:
Matrix:
Paraartrr
D5r020209-010 ! ,
HiruLO
GW
Irnrlt
TOIAI
Ua,olrt,,
QurI (7 o+l-l HDe
Pr.g lnllyrLr
Drtt Datr lrtoh I
Date Collected: 09 /0L/05 L210
Date Received: Og / 02 / A5 0900
Yld t
GXROSg AID BY
Glro.. DctB
GIrnC EPA 900 - O !ilOD
142 0
DlcLlt,
200
900. o ![oD
o9la9ta' oel13 lo5 5252106
trote1 Urral,uu brl,
Totrl UrraLun
KPl, tgmr 5L7l-91
5-62 o. 63
vglt
o.62
5L7 l-91
o9/1s to5 09 tLstos 5255166
SROBA I BY CO-DNECIP gHgTW
Gross Alpha 0.8
7110 ![oD
U
Dcf/t 7110 DOD
09/o8/a5 a9/L7 /05 52sL4731_9
Rn -226 Br tPt,-903.0 I'toD
Radlun (226 ) O. 01 0.13
D,c.LIL
a.24
903. O t@D
09 /06/05 09 /22/A5 5249099 7L
B.l,-229 BY OrDC
f,ldl,um 2,78
EDt 90{ ![OD
1.Ol o. 60
D,cLlr,
o-92
90{ uoD
o9lo6to3 aelz"lot 5249100 61
so THORfUII (gHoRr cT) DoE .a.-01-R lrroD
o.23 J
0.026 u
*Llt n -01-R
09 tlt I 05
09tL3/0s
![oD
091L6l0',
ae /L6 / 05
TborLrur 230
Thoriun 232
o. 16
o _472
o.11
0-069
5156085 7Z
52s6085 72
ra. laoqrlrtr rtthout tbr oem nr-rrtlvc.
tDc 1l drt,rrrnl,nrd by Lartnunrat, Dcrfor:nrneo oaly.
told ruulta atrG grcatcr thrn tb. ilDC
.f Buult 1r grrcatcr than tarfllo drtoctlou f lrn{ g but
Bfl Dg*?df lcra tbaa tbc raqrlc dotcctl.oa Itrn,t,
lcrr than ttatcd rqprtlng llntt.
76
IIR$ Coriporation
CLJ.ent Samle IDr SWB-3-090105
Eeverra [reat LaboratorLss - Iradioc[+mi stry
Lab Sample fD:
Work Order:
Matrix:
Partlll+tar
D5r a24209- 01-1-
H,WT,3
Grw
Roru1t
ltota1
thorr* -
OutI (2 o+ I -l D@C
Drrp lnrlyrlr
Ilrto D.t. Drtoh I
Date Collected: 09 / 0L/ A5 1337
DateReceived: 09/42/05 0900
YI'd t
GOSS r/B
olcort Bctc
BY G}rPC EPt 900. o DiOD
792
1rcl/L 900. o ![oD
o9to9ta5 aglttlos 5352106
ToEaI Unniun b1r
Total llranluu
KPr, lSmt 5L7l-91
51- 1
urflllr 517C-91
oe f Lt I os ae llrl a3 5255166
sRoas r By eo-PREetP gr0w 7110 !!oD
Ororr .Ll.pbr 2? .2
DC;LIT.7110 trOD
ogtasla' ogllTla7 5251.732.8
RA-226 BY I!PI-9O3. O ttCID
Brdiua (226) 0.83 0.28
pcl/r
0 .32
903. O tiloD
09 I A6 I 05 09 l22l 05 52,{9099
nn-228 BY orDc
RrdLum
"28
EPr' 901 ![oD
z.L7 o. 61
pci/r,
0-g3
90{ rcD
o9ta6to5 agtzzlas 5e49100 7L
Igo THORII,U
trborLur, ztO
Ttr<rrium 232
(8HORr er)
' 0.16
0.o
DOE r-01-R
J
u
DcLIr,l'-01-R
o9l13/05
a9/L3/05
t[oD
oe lL6l olt
09/r6/05
o-12
o-0
o-05
o-1
5256005 92
5256085 92
rrrtr ara l:roqrl'ote wl.thout thr aare unrrrt{vr-
l@c [r drtrmtaod Lry l,nrtnrurut grrformrnoc only.
Bold rt:ulBl arc grrut,tr thaa tho tIrC
J Rt:ult lr grr.rt.r thrr rrqllc dctcctl,oa It-mtt b,ut hm
Stl DEhVeU hrr then tbc raq>Ic dctcct!.on 1lmlt.
thu rtrtrd rrportlng llrnLt.
77
URS CorlpratLon
C1ient Sa.uucle ID: STIB-7-090105
Scvcnrr Ereut t aboratorleg ,' RadlochuutrtrT
Lab Sarrple ID:
Work Order:
Matrix:
Parortsar
D5r 02A209- ALz
H-"n[r7
GW
nmul't Quaf
Totel
lhorrt.
(2 o+l-) roc
ProIl enrlfrlr
Drtr Datr Ert:oh il
Date collected: 0 9 / AL/ 05 L42A
Date Received: 09 /02/05 0900
YI,d T
mo88 r../B Br OrPe
Glrorr B.Ea
rPr. 900. o D[oD
26U
DC!.lL 900. o ttoD
09t09l05 oglL'los 52s21o6
trotrl- trrrnlrrn Iryr
Totrl Urrnlun
KDt rgm[ 517d-91
7g -l
!s'IfL BLt r-91
09/13 lO5 Agll.itos 5255166
GOgg .t BY @-PRtCrP gt0m 7110 ltOD
Ororr lJ'phr 8-6
pCLlt 7110 D00D
a9108/05 09ll'l I o5 53514712.6
Rr-226 Br EDt-903 . O DIOD
Rrdirn (226) O-{O 0.26
scLlt
o.39
903. O UOD
a9 I 06l o5 Ae l22lo5 5249099
nr-228 tY otPc fPI' 90l DtoD oCt lL 901 t6D
a9la6las 09l2'2lo5 5249100rrm 729 2-11
rgo THORIIDT (SHORT cIP) DOE .n-01-R INOD
Thorl.un 330
Ttroriurn 232
0.16
0.ol-8
tr
U
o.15
0.067
0 .15
0 .1{
l-01-R ![oD
ogtl3tas 0s tL6lo5 5286085
09/L3 /05 09 /L6/45 525608s
C7
67
ta lro lnoqllcte rltbout thr orrc n&rretLva.
DIDC lr dotrnul,tlod bryr' lactruilDt perto*ataoo oaly.
BoId r..ultr ra. gE ltcr thrn tb. IDC
i, Rorult la crrirtar tbr! arw)lo drtoetlo lt.stt but l.rc th!!.trt.d roSnrtLng lr.jEtt.
STL EgtilS6[ lcu thm tb. raroglr ilotsrqtion ltntt,.1B
OqI}ATA W
D5rO20209
9ampIe Preparation and analyeie ConLrol Numbere
SAIVIPLE#D{ATRIX
001 I{I{
ww
ww
wu[
ww
htw
o02 ww
T{IT
nil{
WW
IlIIf,
I{W
003
o04
o05
wvt
unil
I{!iI
hII{
BiIW
hIIiI
ww
ww
wt{
ww
T,gT{
IM
AIiUIYTICAI,
METHOD
EPA 9OO. O MOD
ASTT{ 5L74- 91
sM$lrf 7]_10 MoD
EPA 903 .0 MOD
EPA 944 I{OD
EMIr A-01-R MOD
EPA 9OO. O MOD
ASrrvI 5L7 4- 91
sMww 7110 MOD
EPA 903 ,0 I,!OD
EPA 904 MOD
EMIJ A-01-R MOD
EPA 9OO. O MOD
ASIIT,I 5L74-91
SMWW TLLA MOD
EPA 9O3.O f'!OD
EPA 904 MOD
EI.IL A-01-R FIOD
EPA 9OO.O I.IOD
Agrtl 5L74-9L
sMww 7110 MOD
EPA 903,0 MOD
EPA 904 MOD
EMIJ A-01-R IPD
EPA 9OO. O MOD
ASTTTI 5L74-91
sMvilw 7110 MoD
EPA 903.0 MOD
EPA 9O4 MOD
EMIJ A-01-R MOD
EPA 900. O tlOD
IIgTtr[ 5L7 4- 91-
sMr|}I 7110 MoD
EPA 903.0 MOD
EPA 904 MOD
EMI, A-01-R MOD
(Cont,lnued on next
TEACH
BATCH #
PREP
BATCH *
52s2106
52551- 6 6
525L473
52490 9 9
5249100
szs5085
5252L 0 6
szss155
52sL473
5249099
s24910 0
s2s5 0 85
s252106
s2ss166
5251 473
5249099
s249LOO
52550 85
s2s21 05
52551 5 5
s25L473
s2490 99
s2491-00
s2s6 08 5
s2s2105
5255155
525L473
5249 0 99
s249100
s255 085
52s2 106
5255I- 5 6
5257473
5249099
s249 r_ 0 0
52693 93
!i[sl Rr]N#
5252053
s255L42
s2sL3 19
s249055
s249053
5256L42
s2s2 053
525sL42
525r_319
52t19055
52490 53
5256L4?
52520s3
525 st42
s25L319
s249055
s249 05 3
5256L42
5252 05 3
5255L42
5251319
s249055
52t19053
5256L42
52520s3
525 sL42
5251 3 19
s249055
5249053
5256L42
5252 053
s2 55 L42
s2s13 19
s249055
5249053
5269295
006
hnil
ww
BI![
$nil
I{W
BNiI
we[
wvu
}|lf
wrl
wrI
wrl
STL Denver
page)
19
ACDATA W
D5rO20209
Saq>Ie Preparation and Analyel-g Cont,rol Numbers
S.eMPITE#MATRIX
007
oo8
oo9
0L0
o11 GI{
G}T
GW
GW
GW
G'!Y
oL2
ww
ww
ww
ww
WH
T{I[
Glw
G}I
GYT
GW
GW
G"9!f
G'Y[
GI{
G$r
GT'I
G}I
GW
GW
Gtw
GW
G9I
cw
ovI
GVr
GW
Gvl
GW
GVT
G',9il
]II{AIJYTICJIL
METHOD
EPA 9OO. O MOD
ASTITI 5L74-91
sMr{w 7110 MOD
EPA 903.0 MOD
EPA 9O4 MOD
EMfr A-0L-R MOD
EPA 9OO. O MOD
ASrr{ 5L7 4- 91
SMwW 7110 IUOD
EPA 903.0 MOD
EPA 904 MOD
EMt A-01-R MOD
EPA 9OO. O MOD
ASTM 5L7IL_ 91
SMWW TLLO MOD
EPA 9O3. O MOD
EPA 9O4 MOD
EMI, A-01-R MOD
EPA 9OO. O MOD
ASITL{ 5L7i&-91
gMww 7110 MoD
EPA 9O3. O MOD
EPA 9O4 MOD
EMIJ A-01_R IITOD
EPA 9OO. O MOD
ASTI.{ 5L74-91
SMWW 7110 IIOD
EPA 9O3. O MOD
EPA 9OII MOD
EI,IIJ A-01-R MOD
EPA 900-0 tlOD
ASTM s174-91
gMtim 7110 MoD
EPA 903.0 MOD
EPA 904 MOD
EML A-01--R MOD
TEACH
BATCH *
PREP
BATCH #
s2s2106
52551 6 6
s2sl473
s249099
52491-0 0
5256 085
5252L46
5255155
525Lt173
s249099
s249100
s2s5085
s2szl..06
52551_55
525L473
5249 09 9
5249100
52s608s
s2521"06
5255155
525L473
5249099
524910 0
5255 08s
525210 5
s2s5 165
525 L473
5249099
5249100
s25608s
s2s2106
szss 15 6
525 7473
s249099
524910 0
s2s6085
MS RUN#
52 52 053
52 5 sL42
525 13 19
5249 0 55
52490s3
szs 6]-42
s2s2053
s255L42
5251.319
5249055
5249053
5256Lt12
52520s3
s25 5L42
s2s1-319
s249055
5249053
5256L42
s2 s20s3
525s1.43
s2513 19
5249 0 55
524e053
s2 s 6L42
s2 s2053
5255L42
52513 19
s249 05 5
5249 053
525 6L42
52 5 2A53
5255 L42
s2 51319
s249 055
5249 053
525 6L42
STL Denver 2A
C1ient Lot ID:
Matrix:
Plratatar
![EI[EOD BI.f,lTK
IPrent Laboratories
REPORT
- RrdLoch@LrtrySgrrern
D5r 020249
WATER
B.3uIt Qurl
Itotrl
lllocrt.
(2 o+l -l
Drrp
Ilrt.
I,rb 8r[rlr ID
fuIInl1t
Datr rrtoh * Ild f
Rr,-228 ItY
Radlun 228
GIrFC EPr' 9O4 ITOD
-0-06
S,cLlt
0-38
90{ uoD
0. 66
15r060000-100s
a9 /06/05 09 /22 / A5 5249100 83
Rn-226 BY
Radfu:rt (225')
EPL-903 . O ![OD
o -42
pctlt,
o- 1r-
903.0 roD
o _21
r5r060000-oeeB
a9 / 05 / 05 09 /22 / 05 524,9099 702
OROgg LIl_ DT
Glrort Brtr
GI'PC IlPl. 9OO. O HOD
a-7
pct/r,900. o tioD
1.7
t3r090000-106t
09toetas aell,TloS 5252105
GOgg .1. rI @-PREerD 8lfifw
Grosa Alpha 0- 06
7110 UOD
U
Dct/L
a -29
7110 DoD
a .5?
r5r080000-{73t
a9 / 08/ 0s oe /L7 / as 52s1 473
Totrl. Urrrrlut hryr
Total Uranl-um
t(Pl. rgmt 5174-91
-0-100 u
lslL
0.013
5174-91
0.31
FSTI,ZOOOO-1668
09/L3/05 A9/l.5/Os 52ss156
I;o EIIORIUII (BIIG)RE qr)
'llborl,rse 23O 0.21
TtrorLum 232 0. O
DOE r-01-R lrOD
iI
U
DTCLII,
0.14
0.0
^L-01-R lfiOD
o. 09
0. 06
15r130000-oE5s
09/13/05 A9lt6t0s 5256085 87
o9/73/O5 09/t6t9s s2s5085 87
fgo .|I'IIORIIffi (AIIORtr C][) DOI! l-01-R UOD
Thorium 230 0 - 09 U
Thorium ?32 0- OB U
Dct/L
0-14
0_10
l-01-n t()D
0 - 20
0.13
r5r260000-3938
a9/26/As 09/27 /05 5269393 et.
a9t26/05 09/27 /05 s269393 91
Drtt lr. Laoreloto rlthorrt thr ccr. Etrrrtl.vr.
ItrDC lr dlctorrlnld urlng lartnmut pcrtormaaoc oaly
Bold rorulta rr. gz..rt.r tbl^E tbc lDC
i, R.tult Ir lrroetG tLu rqrlr drtrotlou l,Inlt but lorr thr.n .trt.d ropo,rtlng ltDtt.Sfl flSny95 r... rbra rh. rrqrrr d.r.attoa ltrl.r.21,
ClLent Lot
lIat,rix:
Puerotrr
Irebora,tory Control
Severn Treat lraboratorl,es
D5r020209
WATER
lbLlrr trcunt Brrults
$otr,1
fDacofr,.
(? a+l-l
Sary>La Report
RldLOchGrrt;trryr
f.rb arqrlr fD
0C s@trol
t yld t ltro t Lnltr
nr-226 Br IBPI-903.0 !fioD
Radium (226) 11,.2
Batoh lr
*Llt,
L.Z
903. O t[OD
a-2
rnrlyrLt Dotot
r5r060000-099c
(54 136)LO -7
5249099
109 96
09t22t05
RN,-228 BT GIPC
Radium 228
EPr 901 rfi)D
5.27
Datoh lr
DtoD
0.69
frrrtffh Dlt,ar
90 L74
a9/27/As
r5ro60000-100c
( 56 747\
Dct/t 90{
0_855. 01
52{91 00
oltogg t Br eo-PrucIr
Gross Alpha
gilww 7110 lroD
20 -6 18.6
ratoh lr 5251 n73
7110 UOD
0.4
ranLytl. Irrt. t
r5r080000 -{73c
t7L 1113 )
D,CLIr.
90
09/L7 /Os
OROBS },IE- BT OTPC
Gross Beta
EPL 900, o liloD
104
Batch tl
900.0 lrcD
1-B
raaayeir Drtor
r5r090000-106c
(74 Lz]}
rrgr.lL
89.2
5252106
85
a9/L2/05
TrroRruil (8HoRT C!t) DOE r-01-R tfion DcLII.l'l-01-R ltoD
0 ,1 93 104
0. 05 e3 88
0-0s 93 102
lanlrtrlr Drtrr 09 /1-6/A5
r5r130000-o83c
Thorir-rm 278
Thoriurn 23O
Thoriu:n 232
8-81-
9.46
8. 82
Drtoh lr
9.2
8.3
9-0
5255085
1-5
1.3
1.4
( 91 L32},
( 6s L29l
(88 133 )
Iro TIIORrIIIII (8llOnt
Thorlum 2Zg
Thorluur 230
Thorir:ur 232
clr) DoE t-01-R
8-81_
9 -115
8_82
Drtoh lr
rioD
9.5
7-7
9-6
5269393
DcI/L
L-2
1-0
1".2
t-ol-R t[oD r5r250000-393e
0.1 92 108
0,06 92 82
0,09 92 108
lanlyrlr Drtrr 09 / 27 / As
(er 132)
(6s 129)
(88 133)
r[otrE ( s]
-_- xqg lr drtrnlnrd b1. brtnurat pcrtM ody
S'f'Irc&lBIlVSJi r-r porlorrd bolorr rorodlas to rvold rsrd-oft or:or la crlol.t.al r.tult.22
LaboratorT Control Sarp1c lLeg Uuglicate ReDort
scvcra Treat, rrrboratoriee - nrdiochoigtr:r
D5r020209
WATER
Cl-ient I.rot fD:
I.vIatrix:
Parartrr Splhr fmrnt Borult
llrotrI'
Uaout.
(2o*l-) tYld tRoo
I.rb 8rq>1o II)
QC Coutrol
Ll-uitr Prcoirlos
Tota1 Uran{un
ToEal Uranium
b1r xPr' rffiu 517{-91
40.0 40.7
spk z 8. 00 Z,3O
Batoh *r 5255166
us lr,517{-91 r5r120000-166c
( 90 LL?t
(90 1L2 ) 139 tRPD
09 / L5/ 05
4-8
0.75
L02
91
krr1'yrLt Drtrr
rqfianl .. . .. . ,.,, ,.-. -. .,_.,, , . - ..,,
Stl"tgh\iL? rn grrfonrd[ boforo rqsiE-as to rvol.ll rounll-otf .rror Lr oilcrrlat al r..dt.23
Client Lot fD:
I{atrLx:
Darertrr
UATRIX
Severu
D5r 424209
WW
SpJJsr
fnorrnt
abtrl
Urrotrt. EpLtro SfXP:tJ
(7 o+ t'l Y:l-d Duul,t
8PIKE/I'ILTRIX gPIKIi
lrent LaboratorLcr
IXIPLICtrTE NEPORT
- nadlochemi Btry
Date Sanrpled: 09/01/A5 15L5
Date Received: 09 / AZ / 05 0900
SPTE
Rrrult
Iotrl QC 8rry>Ie fD
Uroarrt. eC Coatfol
(2a +l-) tt Yld *Boo r.Lul.tr
(BO8g A/B IY
Groes Beta
orPc IlPf, 900,0
20900
spk2 20900
lrtob,
r,c,-lr, 9oo. 0
24A0 4830
2300 {830
lnrlyrLr drtor
l[oD
550
550
Pmclel.or
09 /r2 / a5
Dsr020209-O02
87
82
4 IRPD
231 00
22r00
Ir 5252053
t6z 133)
t62 133 )
rotr1 Urral.un bl1l, KPt .f,EIl[It 5
Total Uranlum 4000
spk2 4000
3590 a
3850 a
I r 52551-42
u.glL
234
460
lnalyrl.r
,LT t-91
504 0
50{ 0
drtrr
600
600
ProoLd.ar
091L5/05
Dsr0202(}9-oo2
-36 a (90 L12l
-30 a (90 112)
7 BRPD
Drtob
OROSE
d"""
} Bf CO-DRECIP
Alpha
spk2
ail$m
41-2
4L _2
lrtoh
723 a
766 a
lr 5251319
*LlT,
91
94
rDaLyrr..
83
83
DrcLrLoar
a9 /L7 /A5
Dsr020209-OO2
zLL a (50 150)
315 a (50 150)
6 tRPD
7110 tfOD
636
636
drtor
u-226 BY lPt-903. o lcoD
Radium (2261 11 ' 4
Spk2 11 -d
3A -2
12.2 a
Eatclr lr 5249055
pcl/rr 9o3. o D[oD
3.3 77 15-1
3,5 59 15,1
D5r020209-OO2
73 133 (66 1s0)
73 151 a (65 150)
Dmcl,r{o,r 7 $RPD
1.9
1-8
lnrlyrlr datrr 09 122/As
Rr-228 By
Radl-um 228
OIPC IEPA gOt[ liloD
5-34
Spk2 S.35
r,cLlt,
z.t 64
2-A 59
rnalyrLr
904 rfioD
La.2
10.2
datc r
D5r020209-OO2
L7 .g
17.0
tr 5249053
L.3
1-3
64 1{5
64 126
Pnol,rl.onr 6
t62 1,s0 )
(62 1s0)
$RPD
Drtoh 09 /22 / A5
IIo TEORTUIII (SIIORT
Thorium 23A
Spk2
Thorium 232
spk2
cr) DoE .
9 .46
9 .46
8_82
8.82
EIEOh
pct/L r-ol-R
L.7 55 3.67
L.6 68 3.67
1.6 ss 0.56
1 .4 68 0,66
lurlyrLr drtrr
a_74 5s
0-74 65
DroolrLonr
LT A .29 55
J 0.29 55
D-roLrLou,r
09/L6/45
D5r020209-O02
79 a (79 130)
93 fie 130)
11 $RPD
107 (70 128)
]-oz (70 128)
5 TRPD
a^Il_ .1 a
L2.5
10-1
9.6
lr 5256L42
ealoultl@t ara l,.!foa'D.d bator. rorrldtrg to avol,(l touDd-glf cnor I-l orloulrt.{l raaulta
ft)it al rrrrllt. utaldc o! .trt.al gC UDr.t..
Qrrrlt l. grortot thr! 3rq}1c Octratloa ltltt but lcrr tb]r .trt.d rroortlag
!4finYer
t .lrlt lr Iail thr! th. rrol.o d.t.otloa ltDlt.
24
T{rTRrX
Eevern
D5f02 02 09
GW
Bp.Iti
.[runt
SPTKE/UtrTRTX SPTKE
Trent LaboratorLcr
In PITICf,TE REPORT
- Badlocfucrn{,rtryr
Date Sampled; 09/01/A5 LZL0
Datre Received: O9 / 02/05 0900
Cll-ent Lot
Matrix:
Prnntor SPIXE
Rrlult
TotrI'
ulloa*.
(X o+l-l
fl}fPLI
Rrnrlt
lotrl
IIBO'TE.
(3o +l -,
Apihr
v1d
AC Aaqrh ID
QC Cet=o1t Yld tRro lLalt;
RL-226 lY EFl.-go3,o
Radlum Q26l
Spk2
0.30 J
a.21 u
Brtoh Ir 5249055
HOD
11 -5
L7.7
a
a
g,CLlL 903 - O uoD D5I02O3O9-O1O
0.20 "14 0.01 U 0.13 7L 2 a (66 150)
0.19 75 O.O1 U 0.13 7L Z a (66 150)" 'erool.tLoarr 34 tRPD
lorlY:l'r drtsrr 09 / 22 / A5
sRosg ,-Ir tr
Gross Beta
orPc EP 900.0
l_0{00
Spk2 20900
Batoh
Dcl/t 9oo.o
940 L4?O
870 L420
lnrlyrlr drEtr
230
230 prroLtLoar
a9 /L2/ As
D5r020209-010
6n (52 133)
29 a rcZ 133)
9 IRPD
!iloD
8160
7490 a
tr 5252053
Total. UnnLun bJr KPt f.Ealt 5
ToEaI Uranl-um 40.0
Spk2 d0 _ 0
L4, -2 a
41 -4 a
lr 52551-43
![gll'
3.6
4.9
rnalyrL.
517{-91
5 -62
5 .62
datr r
D5rO20209-010
0-63 2l d (90 ]-721
o't1=.or.rroor fi *xrj'o 'O
a9 tlsl 0sBrtcb
gRogg
Groes
.A, AY CO-PRTCIP
Alpha
spk2
ElffiH
41 -2
4,L.2
lrtob lt
scJ.lI.,
3.s
3.7
lmlyrl.l
7110 lroD
0.8
0.8
drtsr r
u 1.2
U L.2
09 /\7 / A5
Dsr020209-010
32 a (50 1s0)
35 a (50 150)
Preol.rier 10 IRPD
13.9 a
15.3 a
5251319
Iso THORIIIII (SHORT
Thorium 230
spk2
Thorium 232
SPk2
e[] Dor
9-{6
9.46
8 -82
8. 82
Drtoh
*Llh t-oI.-R
1.0 91, 0.23
1.0 86 0.23
1-1 91_ 0-026
1.1 86 0.026
lnrlyrLt drtcr
r@D
'J 0. 16 72
J 0.1,6 72
Preclr.l.or
u o -072 77
u 4.072 72
PrroLrl.mr
a9 /L6 / 05
D3IOZ0209-010
82 (79 130)
80 e9 130)
2 TRPD
97 (7A 128)
102 (70 128)
5 tRPD
8.0
7.9
8-5
9.0
I r 5255112
nr-228 Br
Radium 229
orPc EPt 90{ lroD
5 _ A3
qpk2 5.49
Batoh lr
!.42 a
L.27 a
5249053
tf,Llt
0.57 66
0. s5 56
laalfr;1|r
90a HoD
1_.0{
1.04
d+trr 09 /22 t A5
0-60
0.60
D5rO20209-010
6L -0.4 a |.62 1s0)
61 4 a (62 150 )
Prcolrtonr 22 tRPD
Crlculatlo. arr Drrfotrrd Deforo rormdlng to evold rouad-off rrror la calqrlat.d rarulta
r Sptlrod r.nlllto outaldc ol stat.d ec ltattt.
_ir__ &.ault 1.. gnartar thru t.q)Ia dl't.cttoo I{r{t b|Et l.ra thra ttrt.d rftortLngSTL flfUwer -
U Rmult lr 1or thn th. rmlr trtoctlm ltd,t.
DUPLICTTE EIITIJUTITTON REPORf
raboratoricg E RadLoahoistry
Client Lot ID:
Matrrix:
ParaEats.r
Srvrru Trcnt
D5 r O2A2A9
WA:PER
Date Sampled; 09 / 07 / 05
Date Received: 09 /OB/05
grxPII
Rrruf-t
lDotr1
Uacaft.
(2a +l-l
DUDLICLI'|!
t y'lal n fu1t
ItlotrI.
UDcaft.
(2 c +l-l t Ytd,
gC Ar4>lo II)
Drooirla
Ito EHOnrI,lt (gHORlrl
Thorium 23A
Thorlum 232
c{r} DoE }-ol-R tloD
A -27 ,, O.2O
-0.0L{. u 0_098
Batob lr 5269393r
l-01-R lmD
A.77 ,I 0.20
0. 01{ u 0.079
5259393 (Drplicate)
pCLlt'
69
69
( sa&ple)
68
58
D5r0Ba2.37 -006
0.3 $RPD
3430 tRPD
DtLr l^ra laoqllrtc rLtbout tho ou. mrrtlwr.
CrloulrtLer lro prrfomd botoro roraAlag to rvold, rsund,-off
.J*- [onr]t 1r grrrltu thu rrugrlr drtrotloa llntt but
tt't P"?llYtt Lcra thf,n tb. mmrrr dotrctlon tl.DLt.
crror ln orlauhtlC nnrltr
Lcra tbrn rtrtod, rrlprtlag llnLt,.
26
STL Denver
Sample Receiving Checklist
w*, ?5f 020,?A.8 . DarelTimc xu.iura, 9ftos 0000
CompanyName&sarnpiing srt", 't 6 U-l/$t Zif -
PM to Complete This Section: Ies
Residual chl orinc chcck rcguircd:9
No
7"
)'es NotrB
Quote #:
Spccial l-nsrructions :
s'Jbto SL buis
lt'7 0tl5
Timc Zang.
. EDTIEST. CDTICST . MDT/I4ST. PDTIPST . OTI:IER
Quarantined :
Unpacking Checks:
Y
z-s
F7 c(
Cooler #(s):
Terrycratures ("C):
N/A Tes No
D { r t.
{ c z.
r fi.
r{o
+DiDdtrG.
I+tr7-
z.3. c(z{,o z3.z ?.L 2.3
EO
@-
Cooler seals iutact? Oi/A ifhand deliverad) Hao, docurne,rt on CI-IR
Cbain ofcusrodypr:sent? Ifno, documeol on CIIR
Bottlesbroken ad/or ar;1;alcing? lf ycs, iloomeat on CIIR.
Multipiusic sarylcs obvjous? If yes, docume,ut on CUR.
Prope,r ccntaiucr & pr:servatives used? (ref. Arachacm D of SOP# DB,I-QA-0003) If ao, documeot on CuR,
pH of all sarrylcs checlced and ureet requiremmg? If no, docume,il on CllR
Sufici-rrrt volume provided for all aaa.Jysis rcqucsted? (reL /^ttacbmcnt D of SOP# DEN-QA-0003) If ao,
docummt on CIJ& and cortacl PM beforc procccding.
{ A L Did cbain of custody agree witb tabels ID and samplcs rccivcd? lf no, docum;at on CUR.
O I 9. Were VOA saqles without headspace? Iino, documeni ot CUR.
D D I0. WereVOAvialsprcserved?Prcscnative JHCI l4*2"C IsodirunTbjosulfaterJ.AscoibicAcid
E rtl- Dd sarylcs regriirc preservarion witb sodinm tbiosrrlfate?
O D 12. Ifyes ro #l I, diri the samplcs contain residual clrlorine? If yes, docmreut op CIJR.
13. SeriimenipresentiD dissolved/filrcred bottles? If yes, docrmenl on CIJR.
14. ls suffrci:fi voiume provided for cUeui requsstcd h4S, MSD or matrix duplicares? If uo, docum:nr on CIIPe and
coutact PIvf before proccoding.
O -,{t. Reerp date$) > 48 hours past the collcction dare(s)? lf yes, notify PAlPh,l.
{ @\, .t . *utyr., with shofl holding times requestcd?
tr b' fi. Was a quick Tum Arou:rd (TAT) requested?
STL Denver
STI- Denvcr
Sample Receiving Checklist
Sufficicnl volumc providcd for all analysis rcgucslcd? (rcf. Anachment D oJ'SOP# DEN-QA-0003) lf no,
dcrcumcnl on Cu& antl annlaci Plvl beforc procecding.
D F A 19. ]s slflicicnt volumc pro'r,idcd for clicnt regucstcd h,ls, I\rSD or matrix duplicarcs'/ If no, document on CUR, and
conaa P.lvl bcfore procccding
Login Checks:
N/n )'es No
,rt B rg.
Jnitials4I-
,gtrw
W-E
v
,P fl
FD
,fJ
tr
g 20. Did the chain ofcustody includcs "reccivcd bf'and "relinquished" bl,sigzrarurcs, dalcs, and rimes?
[ 21. Were special Iog in in$rucrions read and followcd?
U 22. Were AFCEE nEtals loggcd for rclrigeratcd storage'l
tl 23. Wcre tests logged chccked againsl the COC? rr\&ich samples were confirmed?
! 24. Was aRush form conyrlaed for quiek TAT?
tr 25- \\,as a Short Hold form corrpletcd for anl,short holds?
.y26. Is -Stria l@C'rcguired?
.y"27- rNerc special aniiving instnrcr,ioas iudicaled in ihc Gencral Commc,rils? Jf so, u,bar were t}lcy?
Labelir€ and Storage Checls:
I 28. Was the .subcontacl COC sfnod and scnt witb sarryles to bottle prcp?
D 29. Wcre sauqrle labels double-drecked by a second parson?
I 30. Werc sarqple bottles aud COC double cbecLed for dissolvcd/filtercd mgtals by a second parsou?
D 31. Did thc saryle ID, Datc- and Timc fiom Lrbe] march u,bat uas logged?
! 32- Were rtickers for rpecial archiviug insrructions afixcd to each box and to the ICOC? Sce *27
D 33. lltere AFCEEmrlals stored reftigcralcd?
tr 34- Wsrs "Stiot ICOC* eopies givclr to satellite s{orage arcas'?
I)ocumenl anS,problerns or discr;pancies and the actions talien to resolvc them on a Condition Upon Reccipl Anomaly
I{eport (CXIR).
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URS Corporation
Total Metrls Analysis Data Sheet
[,ab Name:
LoUStlG Number:
M atrix:
7o Moisture:
Besis:
Analysls Method:
Unlt:
QC Batch ID:
MS Sarnple Aliquot:
MS Dllutlon Fsctor:
STT,DENVER
p5lQ30r 3e
WATER
N/A
Wet
6020
me/L
s2496r 6
50 rnl-
40
Cllent Sample ID:
MS Lob Sample ID:
MS Lab Work0rder:
Date/Tlme Collected:
Date/Tlme Recelved:
Date/Tlme Leached:
Date/Tlme Extrtcted:
Date/Tlme Analyzed:
Instrument ID:
r AR MS/MS[)
psJ0?0230-004s
HJYQ9
09101/0s I 2: l0
0910?i05 09:00
09/15./05 I I:30
09/23i05 1 ":1 6
004
Analyte Splke
Amount
Sanrple
Result C
MS
Result C
o//o
Rec a Qc
Limit
Cadmium 0.0400 0.0016 U a.0242 60 N 89- ll0
Selcnium 0.0400 0-040 B 0. r09 t72 N 82 - ll2
STL Denver Form 5A MS Analysis Data Sheet Equivalent 727
ffisrr
[IR^S Corporation
Total Metals Anelysls Date Sheet
Lab Namc:
I,oUSDG Number:
Mrtrix;
oh Moisture:
Basis:
Anrlysis Method:
Unit:
QC Bntch lD:
MSD Srmple Aliquot:
MSD Dilution Factor:
STL DENVER
B5t030 r 3e
WATFA
NIA
Wet
6020.
my/ln
52496 I 6
50 rnl.
4r)
Client Snmple ID:
MSD Lab Snmple ID:
MSD Lnh Workordcr:
Date/Tlmc Collected:
Datc/Tlrne Recelved:
Dnte/Iime Leachcd:
Dnte/Tlme Extmcted:
Dnte/Timc Anelyzed:
Instrument ID:
LAB MS/MSD
D5l02o23o-0f4p
HJV09
09/01 /05 I 2: I 0
Qq/0^/05 09:0-0
09/15/05 I5:30
A9/?3105 12:16
004
.Anrlyte Spike
Amount
Sample
Result
C MSD
Result
C 7o Rec a RPD 0
QC Ltmlts
7o Rec RPT}
Cadrnium 0.0400 0.0016 U 0.0277 69 N I3 89- lt0 2A
Selcnium 0.0400 0.040 B 0.0998 149 N 8.9 82 - ltz 2$
STL Denver Forrn 5A MSD Analysis Data Sheat Equlvalent L28
STL DEIVVER
Total Metals Analvsis
-58-
POST I}ICEST SPIKE SAIVIPLE RECOVE,RY
Coutrlet r IIRS CorporrtLon
Lab Codo r STITDEN Crrr No. t 8Ag No. t sDc No-: D5I030139
Lavel (Iow/ucd) t LOfilUatrix ( roL]. /waEcr) : $IATER
SIIIPLE NO.
Conccntsratioa Unicrr tng/L
lnalyt,c Control
t imit ,6R
Splkad Saryllo
Result (ggR) c Saqple
Rc;ult (sn) c
ApLkc
trddcd(81)*R l.M
cadmium l75 t25 o.193937 0 .000040 I u 0.20 92. Ol M
S.,lcnLgm I 75 tzS | 0.195409 o.ooloozIa a.2a 97 ,21 M
STL Denver Form V (PART e) IN ]-29
@CTrE
URS Corporation
Total Metals Analysls Data Sheet
Lrb Ntme:
LoUSDG Nunrbcr:
Mutrlx:
Yo Moisture:
Bssls:
Anrlysls Method:
Unit:
QC Batch ID:
Sarnple Aliquot:
Dilutlon Fnctor:
STL DENVER
D5l030l3e
WATER
N/A
WeI
60IOB
mg/L
s}{B*17
50 nt[.
I
Client Srmple ID:
Lab Srmple ID:
I,rb Workorder:
Drte/Ttme Collected:
Date/Time Received:
Date/Tlme Leached:
Date/Tlme Extracted:
Date/Tlme Anallzed:
Instrument ID:
D51060000-617c
HJ2JJ
09i l5/05 I5:30
0?/ I 6/05 l6;2a
Q2l_
Analyte True Found o/"Rec a Llmlts
Alunrinum 2.00 t.9s 97 86 - I08
lron t.00 0.964 96 88-lt0
Magncsium s0.0 49,1 98 9t Ill
Potassiurn 50.0 50.9 I02 86-lll
Sodium s0.0 47.9 96 9l 112
Zirconiurn 0.s00 0.s38 t08 75 - t75
STL Denver Form 7 LCS Analysis Data Sheet Equivalent 13 0
ffi$rr
URS Corporation
'fotal Metals Analysis Dete Sheet
Lab Name:
Lot/SDG Number:
Matrix:
%o Molsture:
Basls:
Andysls Method:
Unit:
QC Batch ID:
Srnrple AIIquot:
Dilution F'actor:
STL TIENVER
n51030139
walrER
N/A
Wet
601 0B
mg/L
52496t7
50 rnL
1
Client Sarnple ID:
Lrb Stmple ID:
Lab WorkOrder:
Date/Ttme Collected:
Date/Tlme Recelved:
Date/Tlme Leached:
Dste/Tlme Ertracted:
Dste/Tlme Analyzed:
Instrument ID:
p5r06000&6t 7c
HJz.U
09/15/05 l5:30
09i l9105 I 7: I 8
021
Analyto 'f rue Found ToRec a Llmlts
Calciurn 50.0 48.8 98 89- ilo
STL Denver Form 7 LCS Analysk Data Sheet Equivalent 131
Mm sTr
URS Colporation
Total Metals Analysis Dtta Sheet
I.ab Namc:
LotlSD(] Number:
Matrlx:
7o Molsture:
Basis:
Analysls Method:
Unlt:
QC Batch ID:
Samplc Aliquot:
Dilutlon Factor:
STI, DENV.EIT
Ds1030l39
W,TTHB
N/A
Wet
60lllp
mdL
52496t7
5J) mL
I
Client Snmple Il):
Lab Sarnple ID:
Lnb Work0rder:
Date/Tlme Collcctcd:
Dnte/Tlme Recelvcd:
Drte/Time Leachedr
Date/Tlme Extructed:
Date/Tlme Anslyzodl
Instrument ID:
psr060000-6r 7c
HJ2JJ
09/15/05 l5:30
09i.1,6/05 l4: I 8
0a)
Antlyte True Found ToRec a Llmlts
Arsenic 2-00 I _93 97 89 - r09
I-cad 0.500 0.483 97 9t-lll
Barium 2.00 7.01 100 93 - r 13
Nickel 0.500 0.491 98 90- 110
Silver 0.0500 0.0494 99 85 - 114
Vanadium 0.500 0.499 I00 88- 112
Tinc 0.s00 a.474 9s 8s - r r0
Chromiurn 0.200 0.r97 99 8e- il2 /
Copper 0.250 0.235 94 86- r10 \
STL Denver Form 7 I,CS Analysis l)ata Sheet Equivalent 732
@CTT
W r-JlL,
tlRS Corporation
Total Metals Annlysis Data Sheet
Lrb Name:
I.oUSDG Number:
Matrix:
o/o Moisture:
Basls:
Analysls Method;
Unit:
QC Batch [t]:
Srmple Allquot:
Dilution liactor:
STL DENVER
ns1030r 39
W ^TER
Ilr/A
wc[
7f.70A
mE/1.
s25q350
1
Cllent Semple ID:
Lab Srmple [D:
Lab Workorder:
Datc/Tlme Collected:
Date/Tlme Recelved:
Date/Tlme Leached:
Date/Tlme Extracted;
Date/Tlme Analyzed:
Instrument ID:
p5r r 50000-3s0c
HKMDT
0911 9/05 l2:30
09/19/05 l8:35
0r9
Analyte True Found ToRec a LImits
Mcrcurv 0.00500 0.00486 97 85-il4
STL Denver Form 7 LCS Analysis Data Sheet Eqaivalent 133
ffisrr
tiRS Corporation
Total Metals Andysis Data
Ltb Nanre:
I.,oUSDC Nurnber:
Matrlx:
7o Moisture:
Besls:
Analysis Method:
Unit:
QC Batch ID:
Sample ,A,liquot:
Dllutlon F'uctor:
STI&DJNVFR
ps t030 r Lq
WATFR
N/A
Wfl
7470A
rng/L
5262486
l_
Sheet
Client Sample ID:
Lsb Snmplo ID:
Lab Work0rder:
Date/'l'ime Collected :
Date/Tlme Recelved:
Date/Tlme Lmchod:
DatelTlme Extrscted:
Dste/Time Anslyeed:
Instrumeut ID:
D5l r 90000-486c
HKWI9
0e/??/05 . 14:30
c)9J.??t05 .t?:Al
0t9
Analyte True Found TnRec a Llmlts
Mercury 0.00500 0.005 r 8 I04 85-il4
STL Denver Form 7 LCS Analysis Data Sheet Eqaivalent 134
ffisrr
URS Corporation
Total Metals Analysis llatr Sheet
Lab Name:
L,ot/SDG Number:
Mttrlx:
Yo Molsture:
Basls:
Analysls Method:
Unit:
QC Batch lD:
Sample Aliquot:
Dllutlon Fsctor:
STLDENVER
D51030139
WATER
N/A
Wct
7470A
m8/1"
s2624tl6
I
Cllent Sample ID:
Lab Sample ID:
Lrb Work0rderr
llrte/Time Collected:
DatelTlme Recelved:
Date/I'ime Lesched:
Date/Tlme Ertracted:
Date/Tlme Analyzed;
Instrument lD:
p5r r 90000486L
I-IKW I9
09t221Q5 V:30
99t22/05 19:23
019
Analyte True Found C 7o Rcc a RPD a
QC Limits
o/o Rcc RPD
Mcrcury 0.00s00 0.00512 rc?1.2 85 - 114 l0
STL Denver Form 7 LCSD Analysis Data Sheet Equlvalent 135
ffiSTL
URS Corporstion
Totd Metds Analysls Data Sheet
Lab Nnrne:
Lot/SDG Nurnber:
Matrlx:
7" Molsture:
Basls:
Analysls Method:
Unlt:
QC Batch ID:
Sanrple Aliquot:
Dilution F'nctor:
STL DENVER
Ds1030r 39
WA'TER
NiA
Wet
6020
ns&
5'496 I 6
50 m[,
I
Cllent Sample ID:
l,tb Srmple ID:
Lab r#orkorder:
Date/Tlme Collected:
Datelfime Recelved:
Date/'l'ime Lenched:
Date/Time Extracted:
Drte/l'ime Annlyzed:
Instrument ID:
psr060000-616c
HJ2JG
09/15/05 I5:30
A9/?3105 Q7:21
00t
Analyte True Found o/oRec a Limlts
Selenium 0.0400 0.0362 90 82 - tt7
Cadrnium 0.0400 0.0394 99 89 - r r0
STL Denver Form 7 LCS Analysis l)ata Shea Equivalent 135
STL DENYER
Total Mctals Analysis
-9-
ICP SERIAI, DII,UTIONS
Contract: IIRS Corporation
S.BMPfTE NO.
rlIrRA-r,AB QC SER
slxl ![o. r D5I030139
Lravcl ( low/nod,) :Eow
frab Codct t STITDEN
MaBrl,x ( sot ]./water) : WITER
Cage No. t SAS !Uo. t
liluminum
CaloLum II
Iron, Lro
PotassLrrur
Magrrrcal.rrm
Sodirrsr H
Zirooniurn
Concantratsion UrrLt a t ug llt
0 .017 o-085
rnit,ial Saryr]-c
Rrau1t (I)
Serial Diluti.on
nc;ul.E (S)
150. 64 156-15
170. 63 159 .93
115,15 LLI .7IL
3292 - {0 314{.80
o.00150 0.00800
STL Denver FonT IX IN 737
STL DENI.ER
Total Metals Analvsis
-9-
ICP SERIAI, I)TLUTIONS
Contract: IIRS Corllont,l.orr
S}}IPLE NO.
rDrrRA-LAB QC gER
gDO NO. r D5f030139
Level ( low/ncd) :LOVI
Lab Code : STITDEDI Cago No. 3 gAS !fo. 3
Matsrix (sotl/watcr) r I{AIEIIR
llnaLytc
fnLCiaI grrqlrlc
Rosu}t ( I )
c
Serl,al DL1ut,Lon
RrruI.t (8)
c
96
Dl.f,far-
6nc€a !,!
I Arseaic o. 0049 B o .0 220 tu 1oo - ol P
Barurm 0,093 0.086 3.6 P
ChromLurn 0.00250 U 0 .01300 tu P
Copper 0.0045 u 0 . 0225 tu P
Lraad 0.0025 u 0 .0130 U P
Nlckel 0.0033 B 0. oo50 tu 100 .0 P
SLLvcr 0. 00280 U o . o1{oo lu P
Vanrad,Lun 0.0 a27 B o.0125 (,100 .0 P
ZLnc,0.005 B o. o25 U 100 .0 P
ConccntratLon tlnitg: urgfl,,
STL Denver Ionn IX fN 138
STL DETWER
Total Metals Analvsis
-9-
ICP SERIAL DILUTIONS
Contsract: IIRS| Co=arorrgion
STUPLE NO.
ID*TR.B,-I AB AC gER
sDs NO. r D5I030139
Leve1 (Iow/med) r
Lrt Codc r STLDBI Caee SAS No. :
MaBrix (roL}/waEer): [tf,TtR
I cadmi-um
Se]-eni.rrm
Conocntration units t rrgll,;
0.0000{0 o. ooo2oo Ju
fnitirl garqplc
Rcault (r)
ErrLa1 Dilutioa
Rrnult, (8)
o - 001007 0.001550
STL Denver For:n fX IN 139
STL DENVER
Total Ntetals Analysis
- t0-
METI{OD DETECTION LIMITS
Conrrucr, t URS Corporation
Lrb Codar SILDEN
fCP ID ltuurbcr r PE f CPMS
Flamc An fD Dlumbcr I
Frrrnacc A.B ID Nrrrnbor r
Cagc No. :8AS ilIo. r
Datcr 5 ILO l3OOs
sDo NO.: D5I030139
Anrlyt,c
feotol>r Btch*
grround PQL
(trg/L)
MDT,
(ng/L)M
CadsrLrrm 111 0.0010 0.0000{0 M
ScI'cnirun 82 0.0050 o.00033 M
Coruaantg:
STL Denver Fonn X - IN
L43
STL DENVER
Total Metals Analvsis
-ilA-
ICP INTERELEMENT CORRECTION FACTORS (AhINUALLY)
Contract r IIRS CorooratLon
Lab Code t gTfrDElI
ICP ID llUmberr T.IA
Cartl No-:
rntrepl-d rCP
a g [b.:
Datc: ElL9lZOOs
gDC NO.: D5I030139
wave-
length
(un)
rnterelement Corsctlon tractors forr
Mg
rnalrt.e AgA1CaFe
Lr rr*--h' r-yn, l " I' 198 o. ooooooo I 0.0000000 0.00000001 o. o0oo0oo I o. 0oooooo
rluutnum I f ez,0B1 o.0oo0ooo I 0.0000000 0.00182001 0-oooooooI o-ooooooo
Alnnrlmrm I gO9.zTL 0.0000000 J o. oo0oooo o.oooooool 0.0007?110 I 0.0000000
AntLmony l'206.838 o.0ooooo0 | 0.0000000 o. oooooool o. oo0oo00 I 0. 0000000
rrsenLc I 189. o{a 0.0o00ooo I 0,0o00ooo o. oooooool 0.0000000 I 0.0000000
Barturn l{55.403 0.0000000 I o-0000000 0.0o00ooo[ 0,0000000 1 o. ooooooo
Berylllrrur Ifff.0{z 0.00o0ooo I o-ooo0000 o. o0oooool o. ooooooo I o. ooooooo
Boron lrog.6?8 0.0000000 | o.00ooooo o.oooooool 0.0000000J 0,0000000
CadmLum l?26. s02 o. oooooo0 ! 0.0000000 0.0000{201 0.0ooo0o0 I 0. oo0oooo
calcl,urn I arz. g33 0.0000000 J o, ooo0ooo o. oooooool o. oooo32o I o. ooooooo
calcl,um I 318. tAB 0. 0000000 I 0. 0000000 o. oo0000ol o. ooooooo I o. ooooooo
Chromlrrm lrST .7LG o,0000000 I 0. oooo0o0 0.00000001 o.oooooool o.ooooooo
cobalr 1228.616 0. ooooooo I o.000oo0o o.oooooooJ o.oooooool o.ooooooo
coppcr I ,a 4.Tl3 0.0000000 I o.0000ooo -0,00002001 0.0000000 | 0.0000000
rron I ,s9.9r0 o. ooo0000 I o.00o00oo 0.00oooool o.ooooooo I o.ooooooo
rron lz7 t. {01 0.0000000 I 0.0o0oooo o. oooooool 0.0020100 I 0. oo000o0
r,ead |1220.353 0. o0o0o00 I 0. oo0000o 0.00000001 o-oooooooI o.ooooooo
r.luhlum I szo. z8d o. ooo0000 | 0,0000550 0. oooo0ool 0,0000000 1 0.0oooooo
t{agrnerirrrn 1279. Oz9 0.0000000 J o. ooooooo o- oo05o20l o.000ooo0 I o. ooooooo
Mangartoao lZSt. 51o 0.0000000 I 0.0000000 o. ooooooo I 0. 0000150 J o. 0000000
Molybdcnum IZOZ.030 o-0000000 | 0.0000000 o.oooo0oof o.o00oo0ol 0.0o0oooo
rsl,ckal lrtl .6 a4 t2 o. ooo0000 I o.0oo0o00 0.oooo0o0l o.o0oooool o.oo0oooo
ptroephorur I L78 .ZB7 o.ooo0o00| 0.0000000 o-oooooool 0.0000000 I 0.0000000
Pot,asslurc lre6.{91 0 .0oooooo I o. 0000000 o.00ooo00l 0. 0oo00o0 I 0. o000ooo
Selcnlun I rg6.090 0.0000000 [ 0.0000000 o, o0o0oool o.0oo0ooo I o. ooooo0o
st-llcon I asf .612 0.0000000 I 0.0000000 o.oooooool o.oooooool o.ooooooo
stlicon I 2s1.61u 0.0000000 I o.000oo0o o. oooooool o. ooooooo I o. ooooooo
sl,lvor I 329.068 0.0000000 I 0.0000000 o. oooooool o. ooooooo I o. ooooooo
sodl,uu I gS9. s92 o. ooooo0o | 0.0000000 o.oooooooI o.oooooooI o-ooooooo
sodium I efa.3zo 0.0000000 I 0,0000000 0. oooo0o0[ o. ooooooo I o. oooooo0
BtrontLun lAOl .7'li 0,oooo000f 0.00016?0 0.00000001 0.0000000 I o. o0ooooo
Thalliun I 190.86{0.0000000 | 0.0000000 0 . o0oo000 I o. 000ooo0 I o.0oooooo
Corunentg r
STL Denver Form xr (PIRT 1)-IN L44
STL DENYER
Total Metals Analvsis
-llA-
ICP N\MERELEMEI\IT CORRECTION FACTORS (ANNUALLY)
contrBct: lgLCAEAeelioE .
Lab Code: SI1,LDEN Cara No. :
rnt'repid ICPfCP rD Nrrmbar: EiI}
Cortuuents !
EIfg No.:
Datc: I l1.g lz00s
gDo No. g D5I030139
ThorLurn I 283 .73O 0.0000000 I 0.0000000 0.00085001 0.0ooooo0 I 0.0000000
rln I 199.989 0, oo0oooo I 0.0000000 o.oooooool 0.0000000I o-ooooooo
Titanlunr I 33{.9{1 0.0000000 I *0.0000320 o. oooooooJ o. o0oo240 I o.0000ooo
uranl.um I 3B5. g5B 0.0oooooo I -0. ooolo2o -0.00085401 0.0000000 I 0.0000000
vanadlum I aSZ -AAz o. oooo0oo I o.00ooooo 0.00010101 -o.0000130 I 0.0000000
zLnc I arf,856 0.00001301 0.0000000 o. oooosgol 0.0000000 I 0. 0000ooo
STL Denver Form XI (P.LRT 1)-IN 745
STL DE]VVER
Total Metals Analvsis
-118-
ICP INTERELEMENT CORRECTION FACTOR,S (ANNUALIY)
Contract: IIRS Cor:ooration
f,ab Codc: STITDEN
ICP ID lguMborr TJA
Cage No, t
lntrepld ICP
8Ag No. t
Dat€r 8 /L9lz00s
sDc NO.: D5fO3O139
lna11t,e
WavG-
lcngrth
(m)Ac
rntorclcmcnt Corractlon Faetorg
BBa
for r
Be ed
Z;rcaYI ia-nt- I 339 ' 198 o,000ooo0 I 0.0000000 o. oooooool o. ooooooo J o. ooooooo
Ahrmlrztrm ! rsZ.081 o-0000000 I o-0000000 o.oooooool o.oo000ool 0.0000000
Alnnirrun 1309.27L 0.0o00ooo I 0.0000000 o, oooooool o. ooooooo I o. ooooooo
entimony I ,06.83I 0,0000000 I o. o0oo0o0 0.000ooool o.ooooooof o.ooooooo
ArscnLe l189.oa.z 0.0000000 J o.00o0ooo o. oo0000ol o - ooooooo I o. o000ooo
BarLurn Jous-{03 o.0000000 I 0.0000000 0.0000000f o. ooooooo I 0. ooooooo
gea:yllium Ieff .042 0.0000000 J 0.0000000 o. oooooool 0.0000000 I 0.0000000
Boron l2t9.6z8 0.0000000 | o.0000ooo 0.00000001 o.oooooo0 I 0.0000000
cadmium lrZ6. Soz o.ooooo0o I o-0000000 0. oooooool o.00ooooo I o. ooooooo
calciun lsrz.933 0.0000000 I 0.0000000 o. ooo0000l 0.0000000 I o. ooooooo
calcium I318-L28\o. ooo0000 J 0. o0000oo o. ooo0oool o. ooooooo I o. ooo0ooo
/chromlum lzdz. 216 0.0000000 [ o-ooooo00 o. ooo0oool o. ooooooo I o. ooooooo
cobaLt 1228.616 0.oooooo0 I 0,000oooo o. oooooool o. oo0oo0o I o. ooooo00
coppcr
J szl.z53 0. 00ooooo I o. ooo0000 o.ooooooof o.oooooool o.ooooooo
rron I 259.9{0 0.0000000 I 0. oo0oooo o. oo00o00l o, oo0oooo I 0.0000000
rron a2T1, {{1 o.0000000I o-oo0o0o0 o . ooooooo I o. ooooooo I o. ooooooo
Lcad .220.353 0.0o00ooo I o. ooo000o o . ooooooo l o. ooooooo l o. ooooooo
r.ltnirrn 16T0. zg{o. ooooooo I o. o0o00o0 o. oooooool o. ooooooo I o. ooooooo
Masmegrun Jrr 9. o?9 o. ooooooo I 0.00o0ooo 0.00000001 0.0000000 I o. oooooo0
Dran0ranare 1257 .610 0.0000000 | o. o0ooooo o.oooooooI o-oooooooI o.ooooooo
Molybd.saun IZAZ. 03 0 0.0000000 J 0.0000000 0. ooooooof 0.0000000 J o. ooooo00
Nickel I 23 L.60412 0.0000000 I 0.0000000 o,oooooooJ o.oooooool o.ooooooo
Phogptrorua Ifrg.ZB'l o.ooo0000l 0.0000000 0.00000001 o. ooo0o0o I 0.0000000
Potarrl,um 17 66. d91 0.0000000 J o-0000000 o. oooooool o. ooooooo I o. ooooooo
Seleniurn I f g6.090 0.0000000 f 0,0000000 o - oooooooJ o. ooooooo I o. ooooooo
sllicon I 251.612 0. oooooo0 | 0.0000000 o. oooooool o - ooooooo I o. ooooooo
gtllcon
I rsl. Gls 0-oooooo0 I 0.0000000 o. ooooooof o. ooooooo I o. ooooooo
sLlver 1328.058 o.0000000 [ o. o00o00o o - oooooool o. ooooooo I o. ooooooo
sodtrrm I s49,592 0.0oooooo | 0.0000000 o. ooooooof o. ooooooo I o . ooooooo
sodiunr I AfA-326 0.0000000I o.ooo00o0 o.oooooooI o.oooooooI o.ooooooo
ftrontlum I {0? .'t7 L 0.0oooooo J o. o000oo0 0.00000001 o-oooooooI o.ooo0ooo
Fholltum I rgo. gcd 0.0000000 I 0,0000000 0.00000001 o. oooo0oo I 0.0000000
STL Denver Form xr (PART 2l .IN l-45
STL DENVER
Total Metals Analvsis
-IIB-
TCP INTERELEMENT CORRECTION FACTORSI (ANNUALLY)
Contract : IIRS (orporat,ion
Lab Code: gTfrDEN
rCP rD llrmberr TifA
Carc No.:
Intrepid ICP
gtg Dfo. l
Dato: I l1,glz00s
SDg NO. t D5I030139
Trrort.run I283-730 o.ooooooo I o-0000000 o - oooooool 0.0000000 I o. ooooooo
Tin I 189. ggg 0.0000000 I 0.0oo0o0o o.0ooooool 0.0000000 I 0.0000000
Titaniurn I 330.9{1 0.0000000 [ 0.0000000 o. oooooool o. o0o0ooo I 0.0000000
uranir:rn lrt5.958 o.0000000 | o.0oooo00 o.000ooo0l o.00ooo00 I 0.0000000
vanadium lrr2.!LO2 o-oooooo0 [ 0.0000000 0. oooooool o.0ooooo0 I 0.0000000
zinic I 213.850 0.0000000 | 0.0000000 0.00000001 o. ooooooo I g. ooooooo
conmentg:
STL Denver Form Xr (PART 2'-IN L47
STL DENVER
Total Metals Analvsis
-l18-
ICP INTERELEM ENT CORRECTION FACTOR.S (ANNUALLY)
Contsraet: URS Cor:ooratLon
Lab Code: gTfrDEN
ICP ID Dfluilber r l[,IA
Care No, i
Intrepid feP
A.Lg No.:
Datc: I l1g l?OAs
gDo No. r D5r030139
.rrralrrtc
wave-
1cngtrb
( nru)
Intcrclamarrt Corroction Factorg
Cr C\r
for:
K MnCo
7;r^c6r1, r.-rn I 33 9 - 198 0. o0ooooo I -o. o o]-2g00 o. o0oooool 0.0000000 I 0.0000000
Alurrinum Ife2.081 0.0000000 I 0.0000000 0.0000000f o. ooooooo J o. ooooooo
rlumLnr.m lf og.zTL 0. o0ooo00 | o.0000000 o. ooo0oool o. ooooooo I o.0000000
.f,nt,lmony I 206.838 0.0000000 I 0.0000000 o.0o00oool o.00o00oo I o. o00oo0o
.[rgen:[c I 189.002 0.0000000 I o. o0oo00o 0.00000001 o. ooooooo I o. oooo000
BarLrrm J tSS. c03 0.0000000 I 0. o000ooo o. ooo0oool o. o0oo00o I o.0oooooo
Ber:,111",m I 313 .OtLz 0. ooooooo I o.0000000 o. oooooool o. ooooooo I o. ooooooo
Boron lrog. GzB 0.0000000 I o.0000ooo o. oooooooJ o. 0oo0oo0 | o. ooo000o
Cadml-um |,226. soa 0.0000000 | o. 0000000 0.00000001 0. ooooooo I o. oo0oooo
calcl,rrn I Sfz.933 0.0oo0ooo | 0.0000000 0. oooooool o. ooooooo I o. o0ooooo
Calct um I 318. ra8 0.0000000 I o. o0o0o0o 0.0oooo00l o-0000000I 0.ooooooo
Chromlrrm J267.'lL6 0.0000000 I o. oo0o00o 0.00000001 o.ooooooo I o.oooo720
cobalr l2,e8 - 516 0.0000000 I o.0o00o0o o. ooo0oool 0. ooo00o0 I o.0oooooo
copper
J szc.zs3 0.0000000 I 0.0000000 0.00000001 o.oo0oo0oI o-ooooooo
rroD I zsg. g{0 0. oooo000 | o.000ooo0 0. oooo0ool 0. o0o0o0o | 0. o000ooo
rron, lz7 1.4{1 o. 1300000 I 0.0000000 o - oooooool o. ooooooo I o. ooooooo
Lcad, I 220.353 o. ooo0o00 ] o. 0000000 o. ooooooo I 0. 0000000 I 0. oo0oo0o
r.Lttriunr I ezo ,794 0.0000000 I o. 00ooooo o. oooooool 0.0000000 I 0.0000000
Magllsalurn 1279.029 0 .0ooooo0 I 0. 0000000 0.00000001 0.00000001 -0-0035590
l.taapranorG lZSt. 610 0,0000000 I 0.0000000 o. ooo0000l o. ooo0ooo I 0. oooo000
Morybderuun lzaz.03o 0.0000000 I o.0oooooo o. 00000001 o.0o00oo0 I 0. oooo00o
lulckel I 23 t. 6 04 t 2 0.0oooooo I o.0000000 0. oooooool o. ooooooo J o. ooooooo
Phospborus Ifr8.282 o. o0000oo I o. ooooooo o.ooo0000l o.oooooool o.ooooooo
Potasstum I ,e6. {91 o. oooo000 | 0.0000000 o.oooooool 0.00000001 0.0000000
Selenl.rrrn Itg6-090 0.0000000 | o. ooooooo o . ooooooo J o. ooooooo I o. ooooooo
stlicon |zr1.6t?0.0000000 I o,0ooo0oo 0.00000001 o. ooooooo I o. ooooooo
stlleon I ,S1. G1s 0.0000000 I o-00oooo0 o,00000001 o. ooooooo I o. ooooooo
SLlwer I 328.068 0, oooo000 | o. o00ooo0 0.0000000f o. ooooooo I o. ooooooo
sodirrm I ug9. 59,0. o00ooo0 I o. oo000o0 0.00000001 o. ooooooo I o. ooooooo
sodfu:n Jars .tzi 0. 0000000 [ o.000oooo 0.00000001 o. o00oooo I 0.0000000
lStrontium IlOz .77L 0-000oooo I o,oo00o0o o.0oo000ol o. ooooooo I 0.0000000
7rIrallitln I rg0, gG{0. oooo0o0 | 0.0000000 o. oooooool o. ooooooo I o. ooooooo
Conurents r
STL Denver Form XI (PART 2l -IN 14 B
STL DENYER
Total Metals Analvsis
.IIB.
ICP INTEREI,EMENT CORRECTION FACTOR,S (ANNUALLY)
Coatract: URS Coroofatioa .
Lab Code r S1r1TDEN Caro No.:
rCP
flAg No.:
ICP rD lUurnbar: Ein, fntsrepid Date: 8 l19l?OOs
Cormrentg:
gDo sro. r D5I030139
Ilhorl.uur J283.730 o. ooooooo I 0.0o0oo0o 0.00000001 0.0000000 I o. ooooooo
Tln I 199.989 0. o0oooo0 I 0.0000000 o.oooooool o.oooooool 0.0000000
Titanl,rrm I 33{.9{1 0.0o0oooo I 0, ooo315o o. oooooool o. o0oo00o I 0.0000000
uranlun I aes.gs8 0.0000000 J o. oo00o0o 0.00000001 o.oooooool o.ooooooo
vanadLum I 29z-*Oz 0.0000000 | o. oo022g0 0. oooooooI o.0oooooo I o. oo0oooo
zLnc l zra. BE6 0 - 0000000 I o. o00ooo0 0.00094401 o. ooooooo l o, ooooooo
STL Denver Fom xI (PART 2l -fN 749
STL DENVER
Contracts URS Corooration
Total Metals Analvsis
-118-
ICP TNTERELEMENT CORRECTTON FA CTORS (ANNTIALL\O
Caga No. r
rCP
S.Lg No. :
Dates 8 ll9lz00s
Lab Codc a gTfrDEN
ICp ID lltrrnber: Tim. fntrepid
gDc No. r D5I030139
rna11t,e
wav6-
leugtb
(nm)
Intcrclamant CorreetLon faetors
Na NL
for:
Pb sbHo
Zir^Cgy-tr 1,.-yyr I339- 198 0.0009000 I o. ooo0000 0.o00ooool 0.00000001 o.o0ooooo
tLuminum I fez.OBL 0.0000000 | o. o0oo000 0,00000001 o. ooooooo I o. ooooooo
rlnmLnum I 30 g .27 L 0.000oooo I o.00ooooo o, oooooool 0. 0000000 I 0. 0000ooo
entlmony I 206.838 o. oooooo0 I 0.0000000 0.00000001 o. ooo0ooo I o. oooo000
^trsenic I tt g.A4z 0.0000000 | o.00o0ooo o - oooooool 0.0000000 1 0,0000000
sarlrrm lls5.{03 o. oo0o000 I 0.0000000 0. oooooool 0.0000000 I 0.0000000
serytllum I sra .042 o. 0000000 | o. ooooooo 0,0oo00ool o. ooooooo I o. ooooooo
Boron lzt9.6?B o. oo00o00 I o. oooo000 0.00000001 0. ooo0o0o I o.00o0ooo
CadmLum 1116,502 0,0000000 I o. o0000oo -0. ooolg?ol 0.0000000 I 0.0000000
calciun I afz.933 0.0000000 I o. o0o000o 0. oooooool o. ooooooo ] o. ooooooo
calcLr:m l318.LAB o. oooooo0 I o.0000000 o. oooooool 0.0000000 I 0.0000000
chromLr:n lZSz.716 0. oo0ooo0 I 0.0000000 0.00000001 o. ooooooo I o. ooooooo
cobalr 1228.615 0.0000000 | o. ooooo00 o.oooooool o.0oooooo I o.oo00oo0
copper I32{-253 0.0003{00 [ 0.0000000 0.00000001 o. ooooooo I o. ooooooo
rron I zss.g{o 0.0000000 J o. 0000000 o.00oo0ool 0. oo0oooo I o. oooo0oo
rron lzr1. {{1 o. 6015000 I o.0000000 o-oooooool o.oooooool o.ooooooo
r.€ad lrro.353 0.0000000 | 0.0000000 0.00000001 o.ooo0ooo I o.00ooooo
r.l,th,lurn l6?0.'tg{;0.0000000 I 0.0000000 o. ooo0o00l o. 00ooooo I o .0000000
MagaesLum lrr9.0?9 -0.03s8000 I 0.0000000 o. ooooooo I o. ooooooo I o. ooooooo
Mansanese IZSZ.510 0.0000000 J o. oo0oooo 0.00000001 0. o0o0ooo I o. ooooooo
Molybd,enum lZAz.030 0.0oooooo | 0, ooooooo 0. 0003400 I o. ooo0ooo I o. ooooooo
luiekel lrSt.Gat/z 0. ooooooo I o.0o000oo o. oooooool o. ooooooo I o. ooooooo
phorptrorus I rz8.2Bz o.0000000 I 0.000oooo o.oooooool o.oooooool o.ooooooo
Potasslun I zee. agi 0.000oooo I o-0000000 o . ooooooo I 0.0000000 I o. 00o0ooo
selenitrn I 195.090 0. ooo0o00 l 0,0000000 o. ooooooo I o. 00ooooo I 0. ooo00oo
stlleon I zsr. G12 0.0092000 I o.0oo0ooo 0.00000001 0. oo0oo0o I 0.0000000
stlLcon I ,u1. 615 0.0 o92ooo I o. ooo0ooo 0.00000001 o.oooooool 0.ooooooo
sLlvor I rrg.068 0.00ooooo I o.00o00oo o. o0ooo0ol o. oooo0oo I o. ooooooo
sodirrn I 599.592 0. oooooo0 | o. oo00ooo o. oooooool o. ooooooo I o. ooooooo
godlnrn
I sra .326 0.0o0oooo I o. oooo000 o.o0oooool o. oooo0oo I o. o0ooooo
aStrontiurn I AOz .77L 0.0000000 I o. oo000o0 0,00000001 o-oo0ooooI o.ooooo00
Truarltum l rgo, s6a 0.0000000 I 0.0000000 o. oooooool o. ooooooo I o. ooooooo
Comnentg I
STL Denver Form Xf (PART 2l .IN 150
STL DENVER
Total Metals Analvsis
-uB-
ICP INTERELEMEI\T CORRECTION FACTORS (AI\NUALLY)
Contractr IIRS CorooratLon
Lab Coda: STLIrEN Cage No.:
fntrepid IePrCP ID ![rMbAr: TiFA Date: 8 ll,glz00s
Cornmentg:
g.f,g No. t sDc No.: D5I030139
trhorlum I 283.730 0.0oo00oo I 0.0000000 0.-00000001 0-0000000 I 0.0000000
Tin 1199.989 0.0000000 1 0, ooooooo o - oooooool o. ooooooo J 0.0000000
Titanium lrf{.9{1 0.0000000 | 0.0000000 o. oooooool 0, 0000000 1 0.00o0ooo
uraniurn I 385.9i8 0, ooo0000 I o. o0ooo0o 0.0000000J o. ooooooo ! o. ooo0000
Vanadl,rrnr IZSZ.lA2 -0.01?s000 I 0. oo0o000 o - ooooooof o. ooooooo I 0.0000000
zinc I 213.856 0.0000000 J 0.0000000 0. oo{38ool o.0000000 I 0. ooooooo
STL Denver Form xr (PIRT 2l -IN 151
STL DENVER
Contract r IIRB Cor:ooratLon
Total Metals Analvsis
-1lB-
ICP INTERELEMENT CORRECTION FACTORS (ANN UAttY)
Caaa No.:grg [Io. r gDGl No- : D5I03O139Lab Code s STLDETI
rcp ID !$unber r l[irA rntreSlid Icp Dat,e: 8 llg lz00s
WAve-
langrth
(run)
ruterelonrent CorrectLon ractorg for:
SrArralybesi riSs8n
j t I 999.198t- lfCC,-nt ll ffr ,0.0000000 I 0.0000000 o. ooooooo I 0.0000000 I o.0o0oooo
rluml.num 11,67. OEL 0.0000000 I o. ooooooo o. oo0oooo I o.0000ooo I o. oooo000
Alumtnurn lrO9.2?L 0, oo000oo I 0.0000000 0.00000001 o.oooooool 0.0000000
Antl,moay lao6.B38 o. ooooooo I 0.0000000 0.0000000| o.oooooooI o.ooo0o00
Argenie I 189, o{z 0.0000000 I o.0000000 o. ooooooo I o. 0000000 | o.0o00ooo
Barium I {5S.403 0.0000000 I o. 0000000 0. 0000000 | 0.0000000 I -o - 0001930
Berlzlltunr J:ff .OLz o-oooo000 I 0.0000000 o.o0ooooof o.ooo00ooJ o.ooooooo
Boron I 2{9.678 0.0o00ooo I 0.0000000 0. 0000000 I o. ooooooo I o. oooo000
cadmitrm I226.50a 0.0000000 I 0.0000000 0. 0000000 1 o. ooooooo l o .0ooo0oo
cal.cLum I Srz.933 0.0000000 I o. oooo000 0.00000001 o. oo0oooo I o. ooooo00
caLcLum I 318.128 0.0000000 I 0.0000000 0.00000001 o. ooooooo I 0.0000000
ctrromium IZSZ.TLG 0.0000000 I o. oo0oo0o o. ooooooo I 0.0000000 I 0. ool2ooo
cobalt lzzt.615 o. ooooo00 I 0.0000000 o.00ooo0o I 0.0000000 | o. oolsooo
Copper ! fza. T53 0.0000000 I o.0000000 0.0000000 f o. ooooooo l 0.0oooooo
rron I zSS.9{o 0.000oooo I 0.0000000 0.00000001 o. ooooooo I 0.0000000
rron 127 1.{{1 0.0000000 I 0. ooooooo o. ooooooof 0.0000000 I 0.0000000
Lead 1120.353 0.0000000 I 0.0000000 0.0000000 1 o. ooooooo l 0,0000000
rlthtum |!670 -78{0.0000000 I 0.0000000 0.0000000 J o. ooooo0o I 0. o000ooo
I'tagraesiLrst l,279.0?9 0.0000000 I o. o00oo00 0,00o0oool o-oooooool o.oooo000
Mangrancse lzsl,610 0.0000000 I o.00o00oo 0.o00ooo0l o-oooooool 0,0000000
nrolybdanum 1202,030 0.0000000 I 0.0000000 o.oo0ooool o-oooo000l o.0000ooo
xLckal I zr L.60L/2 0.0000000 I 0.00ooooo o. ooooooo I o. ooooooo I o. ooooooo
Ptrosptrorrrs 1178.287 0-0000000 J o-0000000 o.oooooooI o.oooooooI o-ooooooo
Potasslum I 755.491 0.0000000 I 0.0000000 o.00oo00ol o.oooooooI o-o00oooo
SelenLum J 196. O9O 0,0o00ooo I o. oo0oo0o 0.0000000f o.o0oo0oo] o.oooo000
silleon ll2s1.612 0.0000000 J o.00oo0o0 0.00000001 o.oooooool 0.0000000
gtlLcon l2s1. Gls 0.0000000 | o. ooooooo o. oooooooJ o. ooooooo I o - ooooooo
sllver I ,eB. 068 o. ooooooo I o.0oo0o0o 0.00000001 o. o00oo00 I o. ooo35{o
sodlum I 589.592 0.0000000 I 0.0000000 o - oooooool o. ooooooo ! o. ooooooo
sodlun 1 S18.326 0.0000000 | 0.0000000 o. oooooool 0. ooooooo l o, oooo000
lStrontium ! COZ .77L o. oo0oo00 I o,00ooooo o - 0000000 I 0. 0000000 I 0. ooooooo
Trhal llum l 190 . BGd 0.000oooo I o.0ooo0o0 o-ooo0oool 0.0000000! o.ooooooo
Comttents:
STL Denver Forn xI ( PART Zl fN a52
STL DENVER
Total Metals Analvsis
-tlB-
ICP INTERELEMENT CORRECTION FACTOR.S (ANNUALLY)
Contnet: IIRS Comoratlon
Lab Codc r STLDEN Cage Dro. ,sAs tilo. :
ICP ID !$rmber r lfifA fntrepid ICp Date: 8/L912005
Conmentg 3
sDG No. r D5I030139
trtrorLum | 283 .730 o. ooooooo I 0. 0000000 o.O0ooooo[ o. ooooooo I o. ooooooo
Tl,n 1 199, 989 o. ooooo00 I 0,0000000 o.0000oool o.oooooool 0.0000000
Titanl.um [33{.9{1 0,0000ooo I 0. 0000000 o. o00ooool 0.0000000 | o, ooooo00
uranJ.um lEg5.95B 0.0000000 I o.0000ooo o. oooooool 0. ooooooo I 0.0000000
\nrnadlum lZlz.4Oz o.0oooooo I o-0000000 0.00000001 o-o000oo0J 0.000,1[100
zLnc, I zra. 856 0. o000ooo | 0.0000000 o.0oo0oool 0.0000000 | o.ooooooo
STL Denver (PART 1-53
STL DENVER
Total Metals Analvsis
-1 tB-
rc p r NT ER ELEM.ENT CORRECTION FACTORS (AhINUALLY)
Contract: IIR8 Corporatlon
r,ab Code: STI;DEN
ICP ID lsumbar: IfiIA
Cage No-:
rnt,rerlid ICP
grg No. r
Datsr 8 l1,gl?AOs
sDc No.: D5I030139
enalyte
wavc-
lcngrtb
(on)T1
Intaralcmant CorrcctLon Factorr
UV
for:
Zn Tb
Zicc-c>-', Lt-ffi I 339.198 0.0000000 I o.0oooooo o - 0ooooool o. o0ooooo I 0.0319000
.L}ulmtnum I 162.081 0.0000000 I o-0000000 0.0ooo0oo[ o. ooooooo I 0.0000000
Al-uml,nrrm l309.ZTL 0,0000000 I 0.0000000 o. oooooool 0.0000000 I 0. 0000000
Arrtlmony J 206. 838 o.ooooooo I o.0oo0ooo o.ooooooo[ o.ooooo0oI o.oooo0o0
rrsenle l1Sg.a[z 0.0000000 J o.0000ooo o - ooooooof 0.0000000 I 0.0000000
sarl.um I 45s. {03 0.0000000 J 0.0000000 0.00000001 o. ooooooo I o. ooo3o3o
serf,IIJ.,m ]Sff.O{2 o. ooooooo I o.0000000 0.00035901 0.0000000 I -0-0000100
Boron I z49.628 o .0000000 I 0.0000000 o. ooooooo I o. 00o0ooo I 0. 0000000
cadmium 1"26.502 0.0000000 I -0.0002070 o . ooooooo I 0. 0000000 I 0.0000000
calclum I ffz.933 0. oo0oooo J o.0o000oo o.oooooool o.ooooooof o.ooooooo
Cal clurn
1 3 18 - 14 8 0.0000000 I 0.0000000 0.00000001 o.0oooooo I o. o559ooo
chromium ,267,7tG 0.0000000 | 0.000?050 0-0oo00o0I 0.0000000I -0.0005970
cobalt 1229.615 0.0000000 [ o. ooooooo o.oooooool 0.oo0ooooI 0.0oooooo
copper I fZa, ?53 0.0o0ooo0 I 0.0008{20 o.oooooool 0.00000001 0.oo232oo
rron I 259.9{0 0.0000000 J 0.0000000 o. oooooool 0.0000000 | 0.0oooooo
rron lz71. l{1 0.0000000 I o. oooo00o 0.0000000I o.0000000I o-ooooooo
Lead 1120.353 o. ooo0o00 I o. oooo000 0.00000001 o.oooooool o.ooo000o
rLrhLurn l5?0-78{0.000oooo I o.000ooo0 o. ooooooo[ o.0000000 I o. ooooo0o
Masrnesiun l^19. 0?9 o - 0000000 I 0. o075600 0.00000001 0.0000000 I -0.0{18000
Mangraneae lZSl. 510 0-o0oooo0 I o-0oo]-zza -0.00016801 0,0000000 1 0,0000000
Mo1ybd€num |,202. O30 0.0000000 I -0.0007050 0 - 00000001 0.0000000 I 0.00L7500
arLckel I231-5A4/2 0.0000000 I o-ooooo00 0.00000001 0.0000000 I o. ooooooo
phosphorus I fZB. a8?0.0000000 | o. oooo000 o. oooooool o. o00oo00 I 0.00o0ooo
Potaosl,rrln I ,e 6. {91 0.0000000 | o.0000000 o, oooooool o. ooooooo I o. ooooooo
serenlum I 196.090 0.0000000 I o. o0o0o00 o.oo0o0ool o.oooooooI o.ooo0ooo
silieon lru1-.67,2 0.0000000 I 0.0000000 o - ooooooo I o. ooooooo I o. ooooooo
silLcon l ro1, 615 0.0000000 I o. ooooooo o. oooooool 0.0000000 1 0, 0000000
sllver l rr8.OGB 0.0000000 I -o. oo ozzaa -0.01{190001 0.0000000 I 0.0006880
Bodlun I sar.592 o. 0000000 | o. o0oo0o0 0. o0o0o0ol o. ooooooo I o . ooooooo
sodlum I 818.326 0. ooo0000 | o. oo0o0o0 0.00000001 o.0ooooool o-o0oooo0
lStrontirrm JCOZ .?7L o.0000000 | o. ooooooo o-oooooool o.oooooooI o.ooooooo
Trhalllrrm I fgo, BG{o. 0000000 J o, ooo0000 0.0000000I o-oooooooI o.0000000
Cormentg:
STL Denver Fornr Xr ( PART 2l rN t54
STL DENVER
Total Metals Analvsis
-1lB-
ICP INTERELEMENT CORRDCTION FACTORS (AIYNTIALLY)
Contract: t Rg ColaDoration
Lab Codss STLDEN Case No. r gAg No. r
rCP rD N\rnrl>er: TifA Intrepid ICp Dator 8lL9l2005
Corunents:
DsrO3 013 9
Thoriurn I 283 .730 0.0000000 I 0-0155000 0:o00I0o0l o.000ooooI o.ooooooo
rin I tt9.9a9 0. oooooo0 I 0.0000000 o. ooooooo[ 0.0000000 J 0.0000000
rl.tanLuur I 33 lL .9{L 0.0000000 I o. ooo2850 0.0000000f o-oooooooI 0.00ooooo
uranl,um I f as.9E8 0.0000000 I 0.0000000 0,0000000f o-00000001 -a.0287000
vanadLusr lZlZ.4A2 0.0000000 I -0. oo0 242a o. oo0o000] o. ooooooo | 0.0015600
zinc I zre. gs6 o. ooooooo I o.0000000 0.ooooooof o.oooo0o0 I 0.oooooo0
STL Denver Fonm XI (PART 2)IN
STL DENVER
Contract: IIRS Cormoratioa
Total Metals Analvsis
-114-
rcp nruEREI,EMENT CORRECTION FACTORS (ANNUALLn
Caae No.:
II
gf,g No. rLab Codc: STLDEN
ICP ID !ft:mberr STIPERTRACE
gDG NO. r D5IO3O139
Daue: 8 l4l2 005
ena]'rt,e
Wave-
length
(nm)
raterelement Correctlon tractorg
Ca Fe
for:
MgA1 Ag
AlumLmrm l30B.zts 0.0000000 I o.0oooooo o. oooooool 0.0000590 I 0.0oooooo
Antlmony | 206.83 LIL 0.0000000 I o. 0000000 0.000011101 0.0000000 I 0.0000000
rntlnpny I 206.83 Ll2 0.0000000 ! o .0000000 o. oooo24ol O.0000000 I 0.0000000
rrseaic I 189.042 o. oooooo0 I 0.0000000 o.0ooo00ol 0.0000000 I 0.0000000
Barl.um Jtsr-{09 o. 000oo0o I 0. 0000000 o. ooooooof o.0000000 | o. ooo0ooo
aeryllt"um I srf .04a 0.0000000 I 0.0000000 0.00000001 o.oooooool o.oooo0o0
Boron l?c9.628 o. ooooo00 | o. o000ooo o. ooooooof o - oooooo0 I 0. 0000000
cadmLrrm I 226. I02 o - 0000000 J 0. oooo0oo 0.00 ot210l o. ooooooo I 0.0000000
Calciurn f f rz.933 o. ooooooo I 0. 00oo00o -0.00020001 0.0000000 I 0. 0000000
Chrom{rrnr 126T. zl.G 0.0000000 I o. ooooooo -0.00001001 o. oo0004o l 0,0000000
cobalr lt228.615 0.0000000 I -0 .0011320 0.0000000[ o. ooooooo I o. ooo0000
coppar I fal. ?s3 0.0000000 I 0.0000000 o. ooooosol 0.0000000 I 0.0000000
rron lzl1.4{l o. oooooo0 I o. 0000000 o. oooooool o. ooooooo I 0.0000000
r,ead |.220.3 sLtL 0.0003 g2o I o.0oooooo o. 0001160 I 0.0000090 I 0. ooooooo
Lead l22O .3 5Ll2 -0.0002690 I o. oooo000 0.00005101 o. ooooloo | 0.0000000
llagnesLurn l2T 9.078 0.0000000 | o.000oooo -0.0001080I 0.0000000I 0.0000000
Manganaae lzsz. Elo 0.0000000 I o.0000000 o. ooooo?ol o.0oo017o I o. oo0oooo
Irolybderrum IZOZ. 03 0 0.0000000 I 0.0000000 -0.00002001 o.0000000 I 0.0000000
Nl"ckcl l23L.6A{t2 0.0000000 I 0.0000000 0.00000001 o. ooooooo I o. oooooo0
oelenlum I195.0ZL|L 0.0000000 I 0.0000000 -0.0000250J o.0000000I 0.0000000
saleniurn I tr6. 02 L/2 0.0000000 I 0.0000000 -0.0002030 I 0.0000000 | o. 0000000
silieon I 288.159 0.0000000 I o-ooooooo o.oo0ooool o.oooooooJ o.ooooooo
BLlvsr I 328. 068 0.0000000 I o.0oooooo o. oooooool 0.0000000 I 0.0000000
Strontl,urn lOrl .552 0.0000000 | o. o00oo0o o, ooooooof o. 0000000 I o . ooooooo
Thalltum I 190.964 0.0000000| o-ooooooo -0.00003301 0.0000000I o-oo0o000
rhorLum I {01.910 o.0000000 I 0-oooo5oo o,oooooool o.0oo00o0l 0.0o0o0oo
rt"n I 199. 989 0.0000000 I o.0o000oo o. ooooooo I o. 0000000 | 0. o000o0o
rlraalum I Er{.9{1 o. ooo0000 I o. o000ooo o, oooooool o - ooooooo I o. ooooooo
Uranl.rrsr l{09.01{0.0000000 | o-0oo22oo 0.00018001 0.00o0oool 0.0000000
vanadium lzlz,4Oz 0.0000000 I o.00ooooo -0.00029101 -0.00000501 0.0000000
zLnc
1
213.956 0.0000000 | o. oooo000 0 . 0001050 I 0. 00000?0 | o. ooooooo
Conunsnts:
STL Denver Form xf (PART 1)-IN 155
STL DENVER
Contraet: IIRS Cormoration
Total Metals Analvsis
-llB-
ICP INTERELEMENT CORRECTTON FACTOR^S (ANNUALIY)
ea8e No. t
rI
SAS No.:
Dat,o: 8/{12005
r,ab Code s STLDEN
rcP rD Number: gIrpERTR.LgE
gDG No.: D5IO3O139
AnaLIt,o
wave-
lengttr
( nrn)Ag
Interalamant corractrl0n Faetoru
BBa
for:
Be cd
rlrrmloum I308-215 0. ooooooo I 0.0000000 0.00000001 o.oooooool o-ooooo0o
Antimonv I 205.83 L/L 0.0000000 J 0.0000000 0.0000000! o.oooooooI 0,0000000
.lntimoay I ZO5.83 1'12 0.0000000 I 0.0000000 o. ooooooor 0. oo000oo I o. ooooooo
Arucnic I teg.0{2 0.0000000 ! 0.0000000 0.00000001 o-oo0ooooJ o-ooooooo
BarLum
J eSS. d09 0. o0oo000 I o.0oooo00 o. oo00oool 0.0000000 | 0. oo0oooo
Ber1r]-].j.un
1 313 .O$7 0.0000000 I o.0000000 0.0000000[ o. ooooooo I o. ooooooo
Boron |'2t9.6?B 0.0000000 | o. ooo0000 0.0000000f o'o00ooool o-ooooooo
cadmium 11226.502 o. o0oo000 I o. o0o0o0o 0.00000001 o-oooooooI o.ooooooo
Calcl.um fSrz.933 0. oo0ooo0 I o. oo0oo00 0.0000000I o-oooooooI o-ooooo00
chromium IrtT .7L6 o.0000000 | o-ooooooo o-oooooool o.ooooooo! o.ooooooo
coba]'r 1228 - 516 o. oooooo0 J o. o000ooo o-oooooooI o-ooooooo I -o.oooso!
copper I 324.253 0.0000000 I o .0000000 O. ooo0ooo Oooo-
rron |zr l.4{L 0.0000000 I o-oo0o00o 0. o0o000o I 0.0000000 I o. ooooooo
Leadl lZZ0-351/1 0-0000000 I 0.0000000 o . 0000000 ] o. ooooooo I o. ooooooo
l,ead 4220. 3 5L 12 0.0000000 I 0.0000000 o. ooooooo | 0.0000000 I 0. 00o0ooo
MagnosLrxn l27g-o?8 0. ooooooo | 0.0000000 o. o00oooo J 0.0000000 I o. oooo0oo
Dlnnganeso lzsz. 6t0 0.0000000 I 0.0000000 o. oooooool o. ooooooo I o. ooooooo
Molybdenrun I zOZ.030 0.0000000 I 0. oo0oo00 0. 0000000 | o. oo0oooo I o. ooooooo
tsickel I 23 L.60tt2 0.0000000 I o. ooooooo o.oooooooI o-oooooooI o.ooooooo
solaniun I 196. O2LIL 0.0000000 I o. 00036?0 o.0ooooool o.oooooo0 I o.ooooooo
selenlun l196.0zLtZ 0.0000000 I -0.0002a90 0.00oooool o.oooooooI o.ooooooo
stl:Lcon I 288. 158 0.0000000 I o. ooooo00 o.o0o0oool o.00oo0o0J o.ooooooo
silver I 328.058 0.0000000 | 0.0000000 o, oooooooJ o. ooooooo I o. ooooooo
EtrrontLum I {21.552 o-oooo0o0 I 0.0000000 0.00000001 o.oooooool o-ooooooo
rhalllun Itgo-86{o. ooooo0o I 0.0000000 o . ooooooo I o, ooooooo J o. ooooooo
Ttroriun I 401.910 0.000oooo I o, ooooo00 0.oo0oo0ol o.0ooooool o,0ooo000
Tr.n ! ras.ggg o.0oooo00 I o-0000000 0.00000001 o. ooo0ooo I o. ooo0o00
rlranlum I 33{.9{1 0.0000000 I o. oo0000o o.oooooooJ o.oooooool o.ooooooo
uranLum I lo9. 01{o.0ooo0o0 | 0.0000000 o-oooooool o.oooooool o.ooooooo
vanadlum |.292.{Az 0.0000000 I 0.0000000 o. oooooool o. ooooooo I o. ooooooo
zinc I213-Bs6 0.0000000 I o.00ooooo o-oooooool o.oooooooI o.ooooool
Comnents:
STL Denver Form XI ( Penr 2l IN L57
STL DETVYER
Contraet: IIRB CorrooratLon
Total Metnls Analvsis
.IIB-
IC P INTERELEMENT C ORRECTI ON FACTOR,S (ANNUALLY)
Case No.:
II
SAg No. lLab Coder S1LDEN
f CP ID ll\unbar r St PERTR.I,CE
gDO NO.: D5I030139
Dat€r 8lLl 2005
wav6-
lengttr
(nm)
fntcralamant Correctlon tractors for:
lIntna.ltrte C\r MoCoCr
Alunrtilrm I 308.215 0, oo0o000 ! o. oo00o00 0.00000001 0. ooooooo I o.00{0830
Axrt,lmony I 2o5.8}LlL 0.0000000I o-0083080 0.0000000r 0. 0000000 I -0.0005500
lat,imony J206.83L12 0.0000000 I o. oo 4377A 0.00000001 o. 0000000 I -0.0033500
ArranLc 1189.A$2 0 - 0000000 I -0. 00{7300 0.00000001 o.o00ooool -0.0024200
BarLum I{93.{09 o. 0o00ooo I 0.0000000 o. oooo000l o. ooooo00 I 0. oo0oooo
BerrrllLum l313.OtLz 0.0000000 I 0.0000000 0. o00o0oo[ o. oooo0o0 I o - ooooooo
Boron l^*g. G?g 0.0013550 I o-0000000 o-oooooo0I o.0000000I o-ooooooo
CadmLurn 1226. s02 -0. ooo22oo I 0.0000000 0.00000001 0.0000000 I 0.ooooooo
Ca1.cLurn 1312.933 o. ooo000o [ 0.0000000 o.oo00o00l o-ooooooo I 0.0000000
Chromitrn lZ57 .7LG 0.ooooooo I o-0000000 0-0oo0ooo! o-0000000I 0.0000ooo
lcobalr, lrrs . 616 o. o000ooo I 0.0000000 o. oooooo0f o. o0ooooo I o. ooooooo
copper I aZl, ?53 0.0000000 I 0.0000000 o.oooooooI o.0ooooooI o-ooo{elo
rron lZ7 1. {{1 0,08o27s0 I 0-0038290 o.oooooooI o-0000000| 0.o0ooooo
r,ead lzzo.3 sl l:r -o. oo2g,i00 J o.0oooo00 0. ooo0o00 I 0.0000000 I -o . 0008880
Lead lzzo.3 il.tz o. ooo0o0o | 0.0000000 0. 00000001 0. 0000000 I -0.0002710
Magnesl,um 127 9.028 0.0000000 | 0.0000000 o. oooooool o, ooooooo l 0.0000000
rvtranganGse lZSl. 610 0.0000000 I o. o0ooo0o o. oooooool 0. o000ooo I o - ooooo00
naolybd€num I 202 . 03 0 o. ooooooo I o.0000000 0.00000001 o. oo0o000 I o. ooooooo
rut"ckel 1231.50112 -0. aoaz7 50 I 0.0000000 o .0000000 I o. ooooooo I 0.0000000
Selenlurn 1 195 ,0 2L11:o ,0005500 I 0. 0000000 o . ooooooof o. 0003610 I 0. 0005620
selenLum I 196.02 Ll2 0-0000000 J 0.0000000 0.0000000[-- 0.00 a3420 I -0.00023?0
silicon I 288. 158 o. ooooooo I o.0000000 0. 0000000 I 0.0000000 I -0 - 0055200
gLlver I aze. 068 0.0000000 ] 0.0000000 0.00000001 0.oooo0o0l -0.0003190
Strontlum 1421.55e o.0000000 | 0.0000000 0. ooo0oool o.0oo0o00 I o. ooooooo
rhalllum I 190.86{0.00285s0 I o.0oo32oo 0.0000000 [ *0.002{130 I o. 0000000
rhorLun I {01.910 0.00001t90 I 0, 0000000 o. ooooo00l o. ooooooo I 0.0000000
rln I re9.9a9 0.000oooo I 0. 0oo0oo0 0.00000001 o.ooooooo I 0.000oooo
titanLum I 33{.9{I o-ooooooo I 0.0000000 0 . ooo0ooo I o. ooooooo I 0. 0000000
uranl,um 1409.01{0.0000000 | 0.0000000 0.0000000t o. ooooo0o I o.00ooooo
vanad,l,un |,292 .4A2 0.0000000 I -0. o01o2oo 0.0000000J o. o00oooo I o. ooooooo
frnc I 2t3. Bs6 0.0000750 I 0.0000000 0.00028001 o.ooo0oooI o.ooooooo
Conments:
STL Denver Form Xf (PART 2l -fN 158
STL DENVER
Total Metals Analvsis
-IIB-
ICP INTERELEMENT CORREC'I"TON FACTORS (ANNUALLY)
CoDtract i
Lab Code: STLDEN Cage No.:
II
gAg No. t
rCP rD N\rmber: 8ITPERTR.LEE Dat€: 814/ 2005
Comrgntgs
sDc NO. r D5I030139
rnalftc
Wave-
length
(nln)Ni
Iaterc1amant Corrcctlon Factors
Pb gt)
for:
Se si
rluml,num I 308.215 o. ooooooo | 0.0000000 o.0o0oo0oI 0-oooooooI o-oooo000
Antl.rnony IZOe-83LlL -0.0006200 I o-oo0oooo o - ooooooo I 0.0000000 [ o. ooooooo
AntLmoay I 205. 93 Lla 0.0000000 | o. o0o0oo0 o - ooooooo I 0.0000000 | o. ooooooo
ArncnLc I 189 .o4z 0.0000000 | o. o0ooooo o.oooooool 0.00000001 0.000oooo
Barirrm l{93.{09 o. oooo0oo | 0.0000000 0.0ooo0ooI o.0o00oooI o-ooo0000
saryllium f rfa .ol,2 0. oo0oooo I 0.0000000 o. 0000000 I 0. ooooooo I o. oooo000
Boron lro9.628 o. ooooooo | 0.0000000 0.00000001 0.0000000 I 0.ooo129o
cadmium l22o, soz 0.0oooooo | 0.0000000 o. oooooool 0.0000000 | 0.0000000
calcirrrn I Sfz.933 o - 0000000 | o. 0000000 o. 0000000 J o. ooooooo I o. ooooooo
chromium I aez .TL6 o. ooooooo I 0.0000000 o. ooooooo I o. ooooooo I o. 0000000
cobalr lrz8.6t"5 0.0001900 I 0.0000000 o - ooooooo J o. ooooooo I o. oooool
Copper I 32c.253 0.0000000 I 0.0000000 0. ooooooof o. ooooooo I o.0o0o00F
rron lZ, t. {{1 0.0000000 I o. oo0o000 0. 0000000 | 0.0000000 | o. ooooooo
r,ead lzzo,3il-/L 0. 0005000 1 0,0000000 -0.0001d501 0.0000000 I -0.0001300
Lcad lzzo.35 Llz o. oooo000 I 0.0000000 -0.00015001 0.0000000 I 0.0000000
MagnesLum l27g.0zB 0.0000000 I o.0oooooo o. ooooooo I o. ooooooo I o. ooooooo
Mangranese lZSl.510 0.0000000 | o. oooo0oo o. ooooooo I 0 .0000000 I o. oo00ooo
MoLybdonwr |2O2.030 o. ooo0000 I o. oooo000 0. 0000000 I o. ooooooo | 0. 0000000
Nictcel I231-.6Dtlz o. 0000000 J 0.0000000 o. ooooooo I o. ooooooo I o. ooooooo
selenium I 195 -AzLlL 0,0000000 I 0.0000300 o. ooooooo I 0.0000000 | o. ooooszo
selenium JrgG.aiL/z 0.0000000 I -0.0000100 0.0000000[ o.oooooool 0.0000550
sillcon I 289. 158 0.0000000 I 0.0000000 o - ooooooo f o. ooooooo l o. ooooooo
sJ.lver I 328.068 0,0000000f o-000oooo o . ooooooo l 0. oo0o0o0 l 0.0000000
stronttum 4421. I52 0.0000000 I o. ooooooo 0-oooo0oof o.00o0o0ol o.ooooooo
Thallturn I1g0.g6{0.0000000 I o. o000oo0 o. ooooogo I o. ooooo0o I o. ooooooo
Thorlum I tol. g1o 0.0000000 I o. o000o0o o. ooooooo I o. ooooooo I o. ooooooo
rin l ta9,9g9 0.0000000 I o. o0o0oo0 0.oooo0o0l o.oooo0ool o.ooooooo
rl"tanlum ISg4.9{1 0. ooooooo I o.0000000 o. oooooool 0.0000000 | 0.0000000
uranLurn ld09.01{0.000oooo I o. o00oooo o. ooooooo I o. 0000000 | o. ooooooo
vanadlum lzSz.4oz 0. 0000000 | o. o000o0o o. oooooool o. ooooooo I o. ooooooo
zLnc l er3.8s6 o. oo3{900 | o.0000000 o. ooooooo I o. ooooooo I o. oooooq
STL Denver Fomr XI (Pnnr 2l IIN 159
STL DENVER
Contract: IIRS Cormorat lon
Total Metals Arralvsis
.I IB-
ICP INTERELEMENT CORRECTTON FACTOR^S (ATNUALIY)
Cara tilo. :
II
gAg No.3
Datar I ltl 2005
LBb Coder SI1IITDEN
ICP ID ll\rmber: $IIPERT1R.il,CE
gDc No.; D5I030139
Wave-
lengttr
(nm)
IlltoralamcnB Corrcctlon ractorg for:
ulnalltte,lr1 vSnSr
Aluminun
J 308 -215 0. ooo0ooo I o. ooo0000 o.0000ooof o.0000000| 0.a239{oo
Antl,rnony I 205,8 3L1L -0. 0028000 I 0.0000000 0.00000001 -0,0005200 I -0.0089100
rntlmony I 205.83L12 0.0000000 [ o. ooooooo 0. 00000001 -0.0003{00 I 0. 0000000
rrsenrc I ttg.0{2 0.0000000 | 0.0000000 0.00000001 0. ooooooo l o, ooo00o0
Barl,urn I 493.{09 o. ooooooo | 0.0000000 0.0000000f o.ooo0o00l o.ooooooo
serfzllinur laff .O42 0.0000000 I 0.0000000 o. oo00ooo I o .0000850 I o. ooo1290
Boron 1249.6?8 0.0000000 I o.0o0o0oo o. oo0000ol o. 0o00ooo I o. ooooo0o
cadmlum 1225.502 o-0000000 ! o.0ooo0oo o. ooo000ol o. ooooooo I 0. oo000oo
calcium I frZ.933 0.0000000 | o. oo0oo0o o. o0oooool 0.0000000 | o. oooooo0
Chromiun lZdl -'ILG 0 ,0000000 1 0. ooooooo o-oooooo0l 0.0003200 I 0-ooooooo
lcobalr |1228 . 516 o. ooooooo I 0.0000000 0.0000000 I o. ooolloo I 0. 0000ooo
Copper I 3?{. ?83 0. 000oooo I 0. o00oo00 0.0000000I -0.0008900[ o-oooo000
rron lz? L. d{l 0.0000000 I 0.0000000 0.00000001 -0.05755001 0.0119000
Lcad lrro,3 sLtL 0. 0000000 I o. oooo85o o. oooooool 0.0009000 I o. oooo000
r,ead lzzo.3 sl-l2 0. 0000000 I 0.0000000 0. 0000000 I 0. 0015000 I -0 . 000d{s0
MagnosJ.ur lrr9. Oz8 0-o0oo0o0 J 0.0000000 o.ooo0000l -0.0133900 I 0.0000000
ltanganeso lZSl. 610 0.0000000 I 0.0000000 o.0o00oool 0.0001700 I o.ooo0000
Molybdenum 1202.030 0.0000000 I 0.0000000 o. oooooool -0.0003?00 I 0.0000000
Nlckel ln 1. 5 0t 12 0-0000000 J 0.0000000 -0.000980rI - o. 0o000oo I o.0000000
SelenLun
1
195- 02LlL 0.0000000 | o.oo0g130 0 . o000o0o I o. 0000000 | o. o0 a3220
sclenLusr I rg6. OZLlz 0.0000000 I -0.0005130 o . o0o000o I -0. 00o08oo I o. 0000000
stlleon I 2EB.15B 0,0190000 I o.0000ooo 0.0000000J o.oooooool 0.0000000
silwer I 328.059 0.0o0oo0o I o.0000000 o. oo000oo I o. 0012900 I o. ooooooo
StrontLum lt21. S52 0.0000000 ] o,0oo0o00 o.oooo000f o.oooooool 0.0000000
rha}ll,um I 190.964 o.0ooooo0 [ 0.0000000 0.00000001 o.oooooool 0.0018800
rtrorLum I{01.910 0, o0ooooo I o.0000000 0.00000001 -0,0059600 | 0.0000000
Tin I rrg. iag 0. ooooooo I o. o0o0o00 0.00000001 -0. 0005700 I 0. 0000000
'fiuaniun I33,11 .9{1 o. ooooooo I 0.0000000 o.0oo0oool o. oooooo0 I 0.0000000
uranLurn I 409. olt 0.0000000 I -0. 0260000 o . oo0oooo I o. ooooooo | 0.0000000
vanadLun lZlz. {oa 0.0oooooo I o.0000000 o.00000001 -0.0002800 I 0.0000000
f lnc I ,r3 - 8sG o. ooooooo I o.0o00oo0 0. ooo0o0o I 0. 0oooooo ! 0.0000000
Cornmentg:
STL Denver Eor:rr XI (PART 2l IN 150
STL DENVER
Total Metals Annlvsis
-llB-
ICP INTENELEMENT CORRECTION FACTORS (ANNUALLY)
Contract: IIRS Conooration
LaIr Code r S1,ITDEN Case No.:
rI
gf,g BIo. t
fCP ID lrtrrnbar: gIIpEHlIfRnCE Dat,c: 8l{l2OO5
Conunentr:
gDo No. r D5r030139
Wave-
longrtb
(run)
Intorelsnant CorrectLon tractorg
-rh
for r
AnaItt,s
Zn
Aluminun I 308.218 0. 0000000 | o. ost 2L7O
rntLrnoay I 205.83LtL 0 ,0000000 I -0.000{{oo
r,ntlmony I 206.83Lf 2 0.0000000 I o.00oooo0
ArsenLc I 189.ALz o, o000o0o I 0.0000000
sariurn I {93.409 o.0000000 I o-ooolgoo
Berrrlltum I aff .Ai2 0.0000000 I o-0000000
Boron l2i,g.67B 0. 0000000 [ o. o0oo000
cadmi.um 1"26.502 0,0000000 I o-0000500 I
Cal.c{nn I Srz.933 0.0000000 I -0.0056600
ChromLum I 262.?lG 0. 0000000 I o. ooo0000
cobalr 1228.615 0.0000000 I o.0000000 Icopper I ,r 4.TS3 o. oooo000 [ o. oo26a00 !
rron lzrl-.{{1 0 .0000000 | -0.114s000 I
r.ead |,220.3 sLtL 0.0000000 I -0-0o30ooo
r,ead lz?0.3 sLtZ 0.0000000 J 0-0ooooo0
Magncriurn lrr9. O?8 o. ooooooo | 0.0000000
ttangranogo lZSl. 610 0,0000000 I -0.0004100 -r-
Molybd.anum |1202.030 0.0000000 I o. o0000oo
NLekel I 23L.6A4t2 0.0ooooo0 | 0.0000000 IgelenLum Itg6.o?L/L 0.0000000 I -0.0280500
salcnirrm l tr6.02 Ltz 0.0000000 I -0.0002400
silicon I288-158 o.00o0oo0 | o. oooo0oo
SLlver l 32B, 068 0.000oooo I o, o0028oo
strontLum l(rl. i5Z 0.0000000 | o.00o00oo
Thalllurn I 190.96{0.0000000 I o-oooooo0
Thoriurn I 401.910 o. oo0o000 J 0.0000000
rl,n I rrg. ggg o-0000000 I 0.0000000
rltantun Irr tL.g{L 0.0000000 I o-ooooo0o
uranirrm I 409. Old 0.0000000 J o-0029500
vanadiurn I aSa .4Oz o. ooo0o00 I o. 0011500
zinc Izrr.g56 0.0000000 J o. ooooooo I
STL Denver For:rn XI (PAR'[ 2',IN 151
STL DE|VVER
Cont,rrct r IIRS Corlroration
Total Metals Analvsis
'12'
rcP LTNEAR RANGES (QUARTERLTa)
Date: I lLGl2A05
Caac No.:
TJA rntrcpid, ICP
SDg No. r D5IO3O139
ICP ID
eneJ.ytc
fntcgf .
TIurc
(8ec. )
Conocntratlon
(mg ll")u
Jnfunfnutrr rro I 50 .00 In
IAlwrinunr Ht I 20.00 1000 Ir I
JcaLolunr Lo 20.00 50 Ir I
JcaloLun HL 20.00 2000 In
J Iron fro 20. o0 Je
I Iron tll-20.00 2 000 In I
J PotnasLum 20. oo 500 Je
llarerooaium 20.o0 2000 In
I Sod.iurn Lo 20.00 10 Jr
I8od!.un Hi 20.00 10000 Ir I
] ztreonLum 20.00 50 Ie I
Cotrmtent g :
STL Denver Form XfI IN 762
STL DENVER
Contract:
Lab Cod,e:gTLDEII Caec No. t
ICP ID Stlrmber t SUPTRTNACE II
Total Metals Analvsis
-12-
ICP LINEAR RANGES (OUARTERL})
SlSt No. r
Datcr I l3l20o5
sDc No. : D5I030139
IrRg Corporr,tioa
rnnl1t,e
fretcg.
rLnc
(Sce.)
Concrntration
(rrylL)
M
f .er;rrnie 15.00 20 Ir
l BarLum 15.00 25 Ir I
lChromtunr 15.00 fr I
J Copper 15.00 25 ln I
J Lcad 15. OO 200 Ir
t Sllvcr 15.00 Ir I
lVanad,lun 15,00 Ir I
I zinc 15.00 ln I
Corment,e:
STL Denver Eorm XII fN
153
STL DEI\{VER
Contrrrct I IIRS Cor;roratl.on
Total Metsls Analvsis
-12-
ICP LNEAR RANGES (QUARTERLY)
Drtcr I llg I2AOS
r,.b Codrr r STITDEN
IeP rD lhrmbar r pE ICpMS
gDO IIIO. : D5I030139
Arra1y'trr
Integr.
Tino
(8rlc. )
ConccntraElon
(ms/t)u
lcaantum 0 - 001 lu
I Sal.anlum 0.001 Iaa I
STL Denver FOrM XII IN
L54
STL DENYER
'fotal Metals Analvsis
r3-
PREPARATION I,OG
Contsract:
f,ab Code :
Mctlrod: P
URg Corporatlon
STLDEN Cagc No.:SISI No - 3 sDo No. r D5I030139
Prtp Mrrthodr
Sanph ID Prcparatl,on Date
Inl-tLa1 Vol.uma J rLnrl
I volrrma (nrr)
IIiITRA-f-rLEl OC 9 I Ls /2005 50.0 I so-o
IJAB MS 9 I Ls l?AOs 50. o I SO.0
r.tB ![sD 9lLsl200s 50,0 I 50.0
GISr-R1-O90205 9 I L5l2AO5 50.0 I 50.0
G[$[-59-O90205 9 tL512005 .50.0 I 50.0
G[,][-S8 -O9 02O5 9lL5lzAAs 50,0 I 50.0
@r- g7 -090205 9 I L5l?0A5 50.0 I 50,0
grr-6A-090205 9 I L5 lz00s 50.o I 5O.O
@f-68-090205 9/L5l2AA5 50. o I 50.0
M8524 96L7 9 I L5 12005 50. o I 50.0
CHECK g.eMPrrE 9 tL5 1200s 50.0 I 50. o
ComrnenE,r I
STL Denver Fom XIII TN 155
STL DENVER
Total Metals Analvsls
r3-
PREPARATIONLOG
Contract:
LaI) Code :
Mettrodr
t RS Corporatlon
gTLDEN Caatl No. t Afg No. r sDo No. r D5f030139
cv Prrp Mothod:
Aarq)Lc ID PrcgaraElon Datc
raitial volune I rl.na1
J volune (nlr)
grir-R].-09 02 05 e tLs l7ao5 10.0 I 10. o
GUr-R1-090205 US 9 t L9 t2045 10.o I 10.o
GW-R1-090205 MgD 9 / L9 12005 10.0 I r0-0
GrI{-99-090205 9/I.e lxaas 10.o I 10.o
Gw-98-0902 05 9 tL9 12005 10. o I 10.0
GTr-97-090205 9 ttg t200b x.o.o l, 10.0
GW- 5A- 09 02 05 9 t L9 1200s 10.0 I 10.0
!852583s0 9 /L9l200s 10.0 I 10.0
CIITCK S.}MPLE 9lLe1200s 10-0 I r0.0
Comnent; r
STL Denver Forn XIff IN 1-6 6
STL DETYVER
Total Metals Analvsis
r3-
PREPARATION LOG
Cont,ract r
Lrb Codcr
Mathod:
t Rg Cor^1loretion
Care No. r 8.trEl trlo. t sDs No. r D5I030139
Prog MrtJrod r
Samp1c ID Prepnration Datc
fnitlal. Volurnc I rinal.
I Vo1umc (Er,)
Gr{-68-090205 9 t221200s 1.0 I 10.0
rlwrR.}'-rrAB ac 9 t221200s 10. o I ro.0
I,JLB Mg 9t2212005 10. o I 10.0
I..}B MSD 9 t221200s 10.o I 10.0
MBs 2624I6 9t221200s 10.o I 10.0
CHECK SAIIPITE 9 t221200s 10,o I 10.0
DUPTJICATE CIIECIC 9 t2212005 10.o I 10.0
Cortnenta t
STL Denver Forrn XIfI fN
STL DENYER
Total Metals Analvsrs
l3-
PREPARATION tOG
ConfraeE s
LEb Codrrr
Me tslrod:
IIRS Corryorttion
STLDEN Case tilo.:gtg No.:EDo NO.: D5I030139
Dls PreD Meuhod:
Sanple fD Prcparrtl.on, Dlt,c
rnJ.tial Vo1umc I rlnrl
I volunc (mlr)
IITERA-IJAB QC e tLS t zaos 50.0 I so.o
LAB ![S 9 tls t20as 50,0 I 50.0
TJ}E MSD sl1-st200s 50,o I 50-0
s$r-Rl-o90205 9 t Ls t20a5 50.0 I 50. o
ct9l-sg-090205 9tLst2005 50.0 I 50,0
G9r-S8 - O9 02 0 5 9 11,51200 5 50.0 I 50. o
G![-S7-090205 sflst2ao5 50.0 I 50. o
GW-6.1,-090205 9lL5t2AO5 50.0 I 50.0
Grir-68-o90205 9 lLst200s 50.0 I 50.0
!rB52{9 516 9lL5l2AO5 50.0 t 50.0
CHECK S}trf,PI.,E 91L512005 50.0 I 50.0
Comnentt r
STL Denver Forn XIIr IN l- 5I
STL DENVER
Total M-:ils Analvsis
ANALYSIS RUN LOG
Contracts:
Irab Codc:
fnetrumcnE
SErrt, Datcr
t RS Cor11eratsJ.on
StrLDEN
fD lftuuber:
9lL6 1200s
Caac No. t
TJII, Intreptd ICP
Stg No.:
Methodr
End Drte t 9 lLG lzOOs
gDc No,: D5f030139
P
' Danotol additlonrl elencntr
STL Denver
(oLher EhaA thr rta^udlrd CIrP rleuoute) lr.
Fo:rzr XfV fN
Sarryrh
ID.
Dlr Timc e6R
Inallt,ca
^L
L
s
B
A
g
B
t,: l;li rc
i.l :[;lr I
:lxlxl
Stdl-Blank 1, o0 11: {9 x x x x x x
ICLI:1 1. OO 11r53 x x x x x x
ICA];z 1. OO 11:57 x x x x
IC.nI.,1 1- 00 12: OO x x x x x x
ICTI,2 1. 00 12:05 x x x x x x
IglIll 1. OO 12rO9 x x x x
zlclrL 1. OO LZ tLI
cg\nr 1.00 12 :18 x x x x
cglJrL 1, 00 L2222 x x x x x x
IEB 1. 00 LZ t26 x x x x x x
RLgTD2 1. 00 12:31 x x x x x x tICITT,1. 00 12 :35 x x x x x x
rcg.n'1. 00 12:{1 x x x x x x
ICSAB 1. 00 L2t46 x x x x x x
cgu{1.00 12r50 x x x x
CC'\TL 1. oo 12r5{x x x x x x
ccB 1. 00 12r58 x x x x x x
zcg\Itt 1. OO LS tt4?
ZCC'\TH 1. OO 15 :45
CC\IH 1. 00 15r50 x x x x
cg\m 1.00 15 :53 x x x x
cg\,.r,1.00 15r57 x x x x x x
ECB 1.00 15rO1 x x x x x x
zzz7,7.z 5. OO 16: O5
7,Z7.ZZZ 1- OO 15r1O
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rB52{9617 1. O0 15r19 x x x x x
CHECK AAI{PIrE 1. 00 L6 z2{.x x x x x x
zDsr020230-ooc 1. OO 15r28
zDsr 020230-oo4L 5. 00 16r33
zDsr 02 023 0 - oo{s 1. O0 16r38 ^a
2D5t420230-0o{sD 1. 00 16: O{
ZT,7,Z7,Z 1.00 16r49
rrDraraatad or aaothtr For:a 1{
169
STL DENVER
Total M.lils Analvsis
ANALYSIS RTII\I LOG
Coutract:
fJab Code:
IrRg Corporatl.oa
gDs No. r D5I030139S!TLDEN
fnetsniment ID lttrnber s
Etart Detet 9lLGl?AAs
Cagc No. r
TJA Intrepid feP
6fg No. t
Metlrod:
* Donottr additiona,l elanaatt
STL Denver
End Dattt 9lLG12005
(othor tban the rturderd CLP elenente) aro roDroaouted ole r^p,othrr forn 1{
ffrr'\rll.6
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ccB 1. OO 17rO{x x x x x x
zT,zzzz 1.00 17r09
7.227.7,2 1.00 17r1{
zzT.zzz 1.00 17 :19
cffi-R1-090205 1. OO L? t24 x x x x x x
crw-s9 - 090205 1- OO L7 :29 x x x x x x
crw-s8 - 09 020s 1. 00 17r3{x x x x x
sH-s?-090205 1- OO 17r39 x x x x x x
zDsr03 0139 -OO5 1. 00 L7 tll
zDsr03 013 9* OO7 1.OO L7 tL9
7r7,7'7t7r7t 1. OO L7 t5d-
cc,\m 1. OO 17r59 x x x x
cg\,lt,1. OO 18rO3 x x x x x
ccB 1- 00 18: O7 x )E x x x x
Forut XfV + IN t_70
STL I)ENVER
Total Metals Analvsis
-14-
AI\ALYSIS RUN LOG
Contrret r
Lab Codcr
Inctru.nent
Start Date:
IIRS Corporrtl-on
STI,DEN
rD r[umbcr:
e lL6 12005
Caac No. t
TirA rntrcpid rcP
g}.s No. :
Metshod,: P
rud DrEcr 9lL6/zAAs
gDO trIo. : D5I030139
Sarnpl-e
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CSIIH 1- 00 12r18
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rcg.n"1.00 12 r41 x
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MBs2{9617 1- O0 16r19 x
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r.Dsr 02 02 3 0 -o04 1.00 16:28
zDsr 020230-OO{L s-0d t6:33
zD5I 020230-O0{S 1.0c 16:38
zDsto?0230-oo{sD 1. ool 16: {{
zT.ZZZZ 1, OOl 16: {9 -egvH 1.00 16:55
STL Denver E'orn XIV IN
1,7 L
STL DENVER
Total Metals Analvsts
-14-
AI\ALYSKRUN LOG
Contrract:
f.ab Codc r
Instrnrncnt
Btsart Dltc r
IIRS CorporrtLon
STTDEII
ID tsumbcr:
91L6 1200s
Cagc Elo. r
TJA ratrcptd ICP
gl8 No. r
McEhodr D
tad Datcr 9 tL6 t 2005
sDc [Io. r D5I030X39
sarrpl0
ID.D/t Tine IR
lnalytse a
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sn-sg - 09 020s 1. O0 L7 t29 x
GTr-S8 - 09 02 05 1.00 Ll =3tL
x
GW-S7 - 09 0205 1.00 17r39 x
zDsr 03 0139 - OO6 1. O0 1'l t 14
zDSr.O3 0139-007 1.O0 L7 t49
7.ZZZZ7,1.00 L1 t3&
cgw{1.00 17:59
egYfr 1.OC 18r03 x
CCB 1. 0c 18r07 x
STL Denver
Forrm XI\I IN
772
STL DENVER
Total M":lls Analvsis
A}IAI,YSIS RTTN LOG
Contrrct r
Lab Codc:
Inet,nrnont
Startr Date:
IIRS Corporatlon
gjrLDEN
ID N\rmbcr r
9/Le/2005
Calc t{o. :
TifA Intrrrpld ICP
[I.},S No. :
tflct]rod r
End Dat,rt 9lLglzAAs
SDO No.: D5I030139
I - Denotat additlonal
STL Denver
rd Cf,P rlruostr) ars
Forzt XMN
ln I.ytrs
sam)Io I olt frLnc I e6 R
St,d].-B].anlc
M85249617
elanrrrtr (otshcr than thc ctandard Cr,p rgDrelented ou anotsbcr Forn 1a
1,7 3
STL DEIVVER
Total M-:ils Analvsis
A.NIAI,YSIS RT'N LOG
Contract:
Lab Cod,c:
Ingtrunent
Start, Datser
IIRS CorDorrtj.on
gTLDEII
ID ililrmbcrr
9 IL9 12005
Cagc No- :
T{IA Intrapid ICP
A}.SI No. r
Mcthodr
End Datcr 9 l1,gl?AOs
SDG No. I D5I03O139
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ccB 1.00 19:09 x x x x x x
* Dsnotce addltloual elemenEr
STL Denver
(othcr than tht rtaadard CLP oleuroatr ) ara r.praaantrd on anothcr Forn
xlv - rND'orm,
1{
L74
STL DEA{VER
Total Metals Analvsis
-14-
ANALYSIS RT}N LOG
Contract:
Lal, Codc:
Inetnrmont
Start Datcr
t Rg Corporation
gTI.DEN
ID $hrrobor r
9lL9 t2005
Crec No.:
T.III Intrepid ICP
SIS No. r
lficthod r P
End Datcr 9 lL9 lz00s
SDe No,: D5f030139
DlP I fLmr
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M852496L7 1.0O 17 :1{
10.0o LT 223
1- 0O L7 zi-l
Gffi-88 - 09 02 05
STL Denver Form XMN
1,7 5
STL DENVER
Total Mctals Analvsis
-14-
ANALYSIS RUN I,OG
Cont,rlct r
Lab Code r
Inetruncnt
Stert, Datcr
IrRS CorponBLon
STLDEN
ID ![\rmber:
9tLsl200s
Caga No. r
TirA Intropid ICP
SLS ![o. :
Method: P
End Datcr 9 llg 17005
sDO No. r D5I030139
sanple
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STL Denver Forzt XfV fN
STL DENVER
Total Metals Analvsis
-14-
ANALYSIS RUN LOG
Contrnct:
IraI) Cod,e:
Inlt,rnrmcnt
Btlrt Date:
IrRg Corporation
STLDTN
fD Nunbar:
9lL6l200s
Cagc il[,o. I
SUPERTR.LCE II
gJ[g ![o - r
McEtrod r
sDO No. r D5I030139
D
* Daaot.a add{tlooal elsncntl
STL Denver
End Date: 9 lL6l2AOs
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ccur I rr 1. OO 2Or31 x x x x x x x x x
Fonn XIV a IN 477
STL DENVER
Total M-:ils Analvsis
ANAI,YSIS RUN LOG
Cou.trrct r
f,ab Coda:
fnatnunent
Start Dater
IIRS Corporatl,on
STf.DEI{
ID !!l:mbcr r
9lL6 12005
Caac No. t
SUPERTRT.CE TT
9.f,,8 No. :
Mrrthodr
End Datcr 9lLG12005
gDO No. r D5I030139
Sarqrr1e
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r.IB Mg 5.00 21: OO x x x x x x x x x
r4B I,ISD 5. O0 21:O5 x x x x x xl x x x
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cc\nr I rz 1, oo 21r15 x x x x x x x x x
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i Denotor additionrl elenaatt
STL Denver
(oEhtr tbaa thr rte.udrrd CLP eloonta) f,rc reDrtr.ntod oa eaotbrr Form 1{
Forgl XMN ]-78
STL DENVER
Total M-:il: Analvsis
ANALYSIS Rt]N LOG
Contract:
LaI) Cod,c:
In;t'nrrncnt
Start, Drtrr r
IrRg Corporation
gTLDIN
fD lllrnber:
9lL9/"00s
Caac No. r
PE gvLe.
g.Lg ![o. t
Dlothod,r c\r
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8Ds No. r D5I030139
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1.0 ppb 1. 00 15r18 x
2 -O 1>Db 1. 00 15 :19 x
5-O r>pb 1. 00 15r21 x
l-0. O IfDb 1. O0 15:23 x
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STL Denver Forrn XfV fN 1,7 9
STL DETWER
o
ConEraet:
Lab Coder
Inrtrrrrncnt
SEert, Dtrtcr
Total M"lils Analvsis
ANALYSIS RUN LOG
tIRg Corpore,tion
gTI,DEN
ID lhrrber:
9lL9 1200s
Caac ![o. r
PE cun.f,
SA^S No. t
Mcthodr
gDG No.: D5I030139
t Dcnotrr addLtLonal olrrrronta
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Ctr
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gt- 5L- og 02 05 1. O0 19:05 x
cg\r12 1. 00 19: O6 x
CCBI.2 1. O0 19: 08 x
Por-u XMN 180
STL DETWER
Total M-jils Analvsis
AI\ALYSBRUN LOG
Contrlot r
f,alc Codc:
Inat'rnrzrcnt
Etrrt Drtar
IIRS CorporaEl.on
STLDIN
ID Nunbcr:
9 12212005
Cage No.:
PE C\r}.L
Dsr03 0 13 9
Mctbodr Cv
End Drt,rt 9l22l2AAs
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ID.
DIT Time IR
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T,ZZTZZZ 1.00 19:16
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CHECK A}IITPLE 1. 00 19:21 x /
DUPT,ICITTE CHEEK 1. OO 19r23 x T
Z7,ZZ7'7,1. 00 19r25
t Denotea additlonal eleuantr
STL Denver
(othrr than thc strndr,rd CLP elemonta) mB represeD,tod on rnoEhcr
Form XMN
1{
181
STL DENVER
Total *"11f Analvsis
AI.IALYSN RUN LOG
Contraet:
Lr.I) Codc r
fngtnrnenE
Strart Datc r
URg Cora>oretion
SIITIrDEN
ID Nurnbcr: PE ClI[n,
CaEe No.;gAA tilo- :
Mcthodr gv
EIrd Dateg 9 l22l2AO5
sDe No, r D5I030139
e l22l200s
Denotor addLELounl tlturate (otshcr tlu.o tbt standard CtP rl.rurutr) rrc
XTV IN
Sanple
ID.
DIT Tl.na %R
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cw- 68-090? 05 1. 00 L9'.26 x
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LLB MS 1. O0 19r33 x
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7.Z7.ZZZ 1- 00 19g{8
cgw 1- OO 19r50 x
CCBT 1.O0 19r52 x
STL Denver For:n
roDroa6D,tcd, ou anoEhcr lotm 1l
782
STL DET{I1ER
Total *-llf Analvsis
ANALYSIS RT]NLOG
Contsract r
frab Codc:
InsE,r:ument
St,art, Dltc t
TIRS Cor+rorrt,J-on
STLDEN
ID lhrnbrrr r
9 / 221200s
Cagg ![o. :
PE ICPUS
A.l'g No. :
DIeEbod:
sDs ![o. t D5I030139
M
* Dsnotea addLEloual elomratr
STL Denver
End Dater 9 123 lzAOs
(other thrrr tha ttsarrdnrd CIrP eS.euont,a) a,re rcDrcsantscd on anothcr ?om 1l
EIaryr1c
ID.
D/v Tine e6R
enalrte c
A
IJ
g
B
A
s
B
I
B
E
c
D
e
.L
c
R
c
o
c
u
il P
EIB
![
o
D!
N
H
e
N
I
K I
E
}'
o
N
A
T
IJ
v 7t
N
c
N
BIank 1. OO 2OtlL x x
Standard 1 1. OO 2O t4L x x
ac srd 1 1- OO 2Or{8 x t-x
ac sEd 2 1. OO 2Or51 x x
RLSTD 1, OO 2Or55 x x
zzzzZ,Zt 1. 00 20s59
rcse.1. OO 21rO2 x x
rCSTB 1. oo 21rOG x t-x
RINSE 1. OO 21t1O x x
HTGH CHEeK 1. 00 21:1{x x
RTNAE 1. OO 2LtL7 x x
(ac srd 3 1. oo 21r21 x x
AC std, tL 1- OO 2L t25 x x
Bla,nh 1. OO 23t16 x x
Standard 1 1- OO 23 z?L x x
QC srd 3 1. OO 23r25 x x
ac std 4 1. 00 23 r28 x x
oc atsd 3 1- OO O7 r10 x x
0c std {1. OO 07r1*x x r
MB52{9516 1-o0 07 t L'I x x
CHECK 6TMPI.E 1. 00 A7:2L x x
7,7'7,ZZZ 20.0o O7:?5
7,7.ZZZZ 40. oo A7 :28
7,D5T020230-OO{20.o0 O7 :32
zDsr 0e 023 0- ooEr,5 .00 O7:35
2D5r020230-oo4A 1. 00 O7 r 39
2D5r020230-O0{8 20.oo O7r43
2D5r02023 0- oo4sD 20.00 O7:16
ac ard 3 1- OO 07r50 x x
oc sr,d 4 1. O0 O7 :5{x x
7,ZZZZ7,10-00 O7 t57 l /
zzzzzz 5. O0 OB: 01 t
Grw-Rl-090205 1. OO 08r05 x x
Forur XMN 183
STL DEIVVER
Total M.llf Analvsis
ANALYSN RUN LOG
Cont,racts r
Lab Code;
In;trnrmenE
Starts Dates
URS Corporatsl.on
gfLDEN
ID lhrmbcr:
9 I 22l200s
Cace No.:
PE ICPMS
g.trS [Io.:
Mctrhodt
End Datc: 9 123/zOAs
gDO No. r D5f030139
}I
Sarple
ID.
DI?TLmc BR
.trna}y'tscg
A
L
s
B
A
g
B
.n'
B
F
I
c
D
c
.L
c
R
c
o
c
u
r
rv
P
B
Dt
CI
!l
N
H
o
N
I
rls
l"
rlsnl^T
L
v z
N
e
![
crer-s9 - 09 0205 1. 00 08r08 x x
orrr*s8 - 09 02 05 1. 00 O8:12 x x
s$I-a7 - o9 02 05 1. 00 08:15 x x
@I- 6Jt -09 0205 20. oo OBr19 x x
GFr- 68-09 02 05 100. oo O8r23 x x
ac std s 1. O0 OB z2'I x x
QC std 4 1. 00 08:3O x x
B].ar:.k 1. OO 10r16 x x
Stand,ard 1 1. 00 10:21 x x
oc srd 3 1. 00 LO;ZtL x x
ac std 4 1. O0 10:28 x x
rcg.n 1. 00 10:32 x x
rcgnB 1. 00 1O:35 x x
RINSE 1.00 1O:39 x x
ac ard 3 1. OO 1Or{3 lx x
ac ard t 1. OO 1O: {7 x x
oc srd 3 1. O0 11r52 x x
ac std t 1. O0 11:56 x x
zzz?,zz 100.00 12:01
IliIfR.h'-LnB AC 40. oo 1?rO5 x x
MTRI-LIB 0C 8ER 5 .00 12: O9 x x
rlurRA-IrrB AC PDS 1. 00 L2 tLZ x x
I,AB T.[S 40.00 12 :15 x x
I,AB MgD 40-oo 12r19 x x
Qc sEd 3 1.OO 12r23 x x
ac Erd I 1, OO LZ tX,1 x x
- D€[oto[ addltioaal elenentr (othar tha[ tLa rtandrril cf,P olotoDtr) elo rcDroa8rtedl oz rrcthor Yoaa 1a
STL Denver Fom XIV IN a84
Cf-ient Iot *-. -:
PA,RAII{ETBR
D5I0301-39
RESTIIJT
ITIEISOD BI,AIUK RBORT
Gtenoral Cbemiatrlr
REPORTING
ITfMIT UNfTS !,!ETHOD
llatrfur- - --, -- -- 3 WATER
PREPARATTON- PREP
ANALYSIS DATE BATCH #
AnunonLa as N
AnunonLa as
Chlorlde
Fluorl.de
FI.uoride
NLtrate
Nit rate-lul-trite
Suf.fate
Tot,al Cyanide
ND
Work Order #: HK[I941AA
O, 10 mg/t'
Di1ution Factor: 1
Analyets Tt-me. . : 05 : 00
Work Order #: IIK6NLTI-AA
0 - L0 rng/L
Dllutlon FacEor: l-
enalyels TLne..; L?:00
Work Ord.er #: HKDP11AA
2 .5 mg /l'
Dltutl,on E'actor: 1
Analysie Tirne. . : 10: O0
$lork Order #: HKCX4lAlt
o-1o rylt
Dllutlou Fact,or: L
noalyele TLme..: LL:3O
Work Order #: HKCORIAA
Q. 10 try,lt'
Dj,lutlon FacEor; 1
Analyele Tlme..; 1L:30
Work Order #: HKTITPIAA
0.10 ng/L
Dilution Factor: 1
Analyele Time. , : 12: 0O
Work Order #: HK7EN1AA
0 - 1-0 mg/L
Dilution Faetor: 1
Analyeie Time..: tr6:00
Work Order #: H.f2GIrlAA
5.0 qlll'
DllutLon F'acEor: 1
.lnalyele TLme. . : 14 : 3O
Work Order #: HIGJIIW1AA
0 - 010 nvg /L
Dllution Faetor; 1
AnalysLe Tl,me- . : 12 : 30
MB Lot-9amp1e
MCATTW 350. 1
MB frot-Samp1e
MCAWW 350. 1
DsI140000-378
a9/L4/ as s257378
#: Dsr220000- 424
09 /zo/ os sz6s424
MB Lot-Sample #:
MCAW!{ 325,2
D5r090000-250
oe / o8/0s s2s22s0ND
o-o17 B
o-o21 B
2-9 B
MB Lot-Samp1e #:
licitrItH 34fJ -2
D5r090000-s40
oefoelos s2s2s1o
MB frot-Sanple #:
TJrcAWTI 340.2
Dsr090000-54L
oeloe/os 5?,s2s
o
41
ND
MB L,ot-gamp1e #:
McAtim 35t .2
DsT.220000- 579
oe/$/as
llB Lot-Saqr1e #:
MCAWIT 353 .2
D5r220000- s42
oe/2a/os
526ss7 9
5265542
MB Irot,-sample *:
lr(nHrl 375.1
D51060000-s86
09106l as s24es86
I\48 LoE-SampIe *:
sw846 901A8/ so12A
Ds1L40000 -427
oe / Lq-ag I Ls / as szsTazl
rucrfB (B) :
Celctlation$ are pcrformed boforc rourding to avoid round-off effors In cstcutatsd reults.
B Estinutod roult. Result is lcss rhan RL.
STL Denver 18s
W OONAROIJ SJATIPT.IB M REFORT
General. ehemistr1r
Lot-Sa4pl.e *-
PAE}UFTER
pH
Ammonia a6 N
Ammonia as N
Fluoride
Fluoride
Nitrate
95
94
witrate-NLtrlt.e
105
L01
Sulfate
LO2
107
: D5f030139
PERCEIIT RECO\IERY
RECO\IERY IrIMffS
L00
100
108
1 1-O
101
99
RPD
RPD IJII'IITS METHOD
llatrix- , - - - - . - - ! YIATER
PREPARJA,TION- PREP
AI\TAIJYSTS DATE BATCH #
LCS Lot-Sample# : D5T,220000-542
oe /2o / os 526ss42
oe /2a/ 05 s26ss42
wo* : Hir7T71AA-IrcE/HiI7T7lAc-LcgD I,cs Lot -sample* : D5I03 0000 - 10o
oi - Lo2l swg46 9o4oB og/oz/os 5245loog7 - Laz) o-0 (o-s.o) swg45 e04oB og/ol/os s246l-oo
Dilutioa Factor: 1 Analyeie Tl-me. . : 13 : 38
wO# : HKIIS 4 LAC - r-,es / uxttg4 1AD- rrcsD IrCS Irot-Samp1e# : D5TL4000O-378
oe /t4/ as 52s7378
ae /].4/ os s2s73?8
( e0 110 )I.{CA[til[ 350 - 1
(go 110) 1.6 (O-10) MCAWW 350.1
DLlutl.on FacEor: 1 Analysle Tlme..; 05:OO
wo# : IrK6N.]rAc-r.cs/nX6N,J1AD-LcSD LCg Lot- Sample$ : D5l22O O A O - 424
wo* : HKCX4TaC-I,C9IHKCX41AD-LCSD IJCS Lot-Sary>Ie* : D5I090000 -54 0
93 (g? - 114) McAsrlv 340.2 og/og/as s2s254o
eG (s7 - 114) 3-3 (0-16) McAww 340-2 og/og/os s2s2s4o
Dilutiou Factor; 1
I'IO# :HKC0BIAC-LCS/HKC0R1aD-IJCSD IJCS Lot-Sample*: D5IO90000-541
92 (B? - 114) MeAwr{ 340.2 og/og/os szs2slt
91 (sz - 114) o.Bo (0-16) MeAww 340.2 ag/og/os 52szs4L
Dilution Factor: 1 .nnaJ-yala Time. . : 11: 3O
wo# : HKTLPIAC-r,CS /HIKtt plAD-r,CgD LCg Lot-Sample# : D5I.22OOO O -57 9
oe / 03 /os s26ss7 9
09 / a3 / 05 sz;ss?e
(ee 110)MCAWW 353 .2
(es 11O) 1.5 ( O-1O) MCASIW 353 .2
DlluEl-on Factor: 1 Analyele TLme.,: 12:00
wo* : HK7 EN1AC -LCS /HK7 ENLAD - LCSD
( 90 110)(go 11o) 2. o (o-i.o)
Dilution Factor: 1
(gz L12)-
(gz LLz) 4 .5 ( O-1,0)
Dllutlou Factor: L
( el 112 )(9L LLzl 4.2 (O-l-s)
ol.Iutlon Factor: 1
MCA!{I{ 3s0.1 O9/2O/O5 5265424
I,rcAww 3s0.1- as/z0/as 526s424
Analyeia Time..: 17:00
MCAI,rm 353 - 2
MCAWW 353 .2
Arralyels Time. . : 16: 00
I{o# : HiI2GLlAc -r,cs/Hir2crJrAD-rrcgD Lcs IJot - samp}e* : D5 f 0 6 0 0 0 0 - 5 I 6
MCAUTn 375 .4 09 / 05 / 05 5249586
MCAWW 37s.4 09/A5/As 5249585
Analyels TLme..: 1a:3o
STL Denver
(Contlnued on next page)
185
f.ot-Saryl1e *. - . 3 D5I030139
PBRCENT
PARII#_.TER RECO\IERY
Total Qanide
107
106
W CC'IrIROL SJBT{PLE ffi REPORf
General eherui-stry
RECO\IERY
LTMTTS
(ag 10e)
(eg 109) 0.93 (o-2ol
Dllutlon Factor: 1
llafa'ir--.. - - o o,: WATER
PREPARATION- PREP
ANAIJYSIS DATE BATCH #
sw846 eo1 aB/9O12A Ae / t4-A9 / 7s / As s2s7427
sw845 e01aB/ 9012A 09 /L4-A9 / 15/OS s2s7427
Analysl.e Tlme. . : L2 :3 O
RPD
RPD I,IMITS METTIOD
wo{f : HKT,IIWUC-I,CS/HXOHW1AD- IJCSD IrCS Irot- Sample* : D5I14 O O 0 0 -42 7
ITCTT1B (8) :
Calculations rro performcd before rounding to rvoid round+ff orrors in calftlatcd resrlb.
Denver L87
W COITTROI, SAUPI..B DATA RMORT
General- ehemietriy
Iot-8aqll.e
PARATT{ETER
pH
Ammonla'as N
4.00
{. 00
Arnmonia as N
4. O0
4.00
Fluorlde
5. OO
5. OO
FluorLde
5. 00
5.00
Nit,rate
NLtrate-Nitrit,e
4.00
4. OO
Sulfate
25. O
25. O
*. - -: D5I0301-39
SPIKE MEASTIRED
7. OO '7 .O2
7.00 7.O2
PERCMT
AMOI]MT AIT{OI]NIT T}NITS RECIIRY RPD }IETIIOD
wo# : HiI7T7 lAiA- LCS lH,J7T7 lAC - LCSD
No units r-oo swe46
No Unlte L00 0.0 SW845
Dl-lut,ion Factor: 1 Aualye1e
wo* : HKrI94 LAC-LCS /UXHS4 IAD-IJCSD
rratrL:c. - - - - - -, - 3 VIATER
PREPARATIO$- PREP
AIIIAITYSIS DATE BATCH #
LCS Lot-garnple# : D5fO3000O-100
eo40B oe / o3los s2451oo
90408 a9 / B /as s246100
Time..: 13:38
IJCS l-rot-Sample# : D5I1{0000-378
350-1 oe/L4/Os s2s737s
3s0.1- o9/L4/05 s2s7378
TimG. . : 05:00
LCS LoL-Samp1e# : D5A22000 O-424
3so. 1 09 lzA/Os s265424
3s0.1 a9/2O/O5 5255424
Tl-me..: L7:O0
LCS Lot-Sarnp1e# : D5IO90000-540
34O .2 09 / 09 / 05 52s254O
340 .2 09 / 09 / A5 525254A
Time. -: 11:30
LeS Lot-Saq>Ie# : D5IO9000O-541
34A .2 09 / 09 / Os s2s2s4L
340.2 O9/O9/O5 s2s2s41,
Tlme.,: 11:3O
LCg Lot-Samp1e* : D5I220000-579
3s3.2 09/O3/Os s26ss79
3s3.2 O9/$/A5 s26ss79
Tl.me. . ; 12;00
LCS lrot -Samp1e# : D5f,22000 A -542
3s3 .2 09 /2O/ Os s265542
3s3 .2 O9/TA/O5 5265s42
TLme..: L6:00
IrCS Lot-Sample# : D5f050O00-586
37s.4 09/ 06/Os s2+9s86
37s .4 A9/ 06/05 s249s86
Tlne.,: 1tl:30
0.0500 0-A476 mg/T'
0 . o5oo 0 , 04 69 mg/L
w/L
ms /r,
mg/r,
mg /r'
ms/L
mg/t,
mg/t,
mg/t
PL1utlou Eactorr 1
1-08 MCAWW
L10 1.6 MCAIIW
101 MCAIIII{
99 2.O MCAI'II{
93 MCAUII{
96 3,3 MCAWW
92 MCAWW
91 0.80 McAlifhl
1-05 MCAWW
L 01- 4 .6 MCAWW
4 ,33
4_40
4.03
3.95
4 .63
4.79
4.60
4.55
4.2L
4.02
25 .6
26 .6
DLlutlon Factor; 1 Analysis
wo# : HKSNJ1AC - r,CS /HK6N.TTAD - LCSD
rtug /r,
mg /r'
DLlutLon Pactor: 1 Analygls
wo# : HKcx4 l.A.c- Lcs / llxcx4 lAD- LcsD
Dilution Fastor: 1 Analyeia
v{o# ; HKGoR1AC - L,cs /HKCoRIAD - LCSD
mg /r,
mg/t
Dl}uElou Factor: 1 Analyeis
wo# : HKTLPlAC -LCS /HKTrrpLAD- LCSD
95 MCAUm
94 1.5 MeASm
nnatyelaDilution FacEor; 1
wo# : rrr(7 PNIAC -I-,cs /HK7 FNLAD - [,CSD
Dl1utlon FacE,or: 1 Analyele
WO# : Hr]2 GIT1AC - LCS / lllZelrlAD - IJCSD
L02
L07
MCAWW
4.2 MCAWW
Analysls
STL Denver
(eontinued on nexE page)
188
ffi (]OIITROL SAI{PIIB IIAII, RBFORT
General' Cheetotry
Iot-SarylJ.e *- - - : D5I03 0139
SPTKE MEASTIRED PERCNT
PARAMETER AII'IOT]MT AII{OTINT UNITS RES\M.Y RPD METHOD
Dlatrtx! -,,, ? - - - i WATER
PREPARATTON- PREP
AIIAITYSTS DATE. BATCH #
LCS Lot-Sarnp1e# : D5I14000O-427
e01 oF/ eo12A ae I t4- ae / Ls / 0s s2s7 427
eol aE/ eo12A oe / t+- oe / ts / as s2s7 427
TLme..: 12:30
Tota1 Qyanlda
rsrB (s) :
O,107 mg/l'
0. L06 ng/f'
LO7 sw846
105 0.93 SW845
wo# : HK,JTIWIAC - r,CS / HK]HWIAD - LCSD
o,l-00
o.l-00
Pllutlou Factor: 1 Analyele
Calsululons Ero performed bcfore rourdlng to avold round-offorrort hr caleulated resulu.
o
STL Denver 189
W COI{rISOI, ABDTPT,E BI'ELIBTIOIT
General- Chenistrl/
RBPORT
PREPARATION-
AI{IL.trYSfS DATE
liatrix. r - - . - . - - 3 WATERClient, Iot # -
PABAI,IETER
Ch]orlde
NUTts (S) :
3 D5I03 0L39
PERCETVT
RECO\IERY
100
RECO\IERY
LIMITS IVIETIIOD
PREP
BATCH #
Work Order #: IIKDP11AC LCS Lot-SanpleS: D5I090000-250
(90 - 110) McAww 3zs.z ogloelos szsz2so
DLlutlon FacEor: 1
Calculations arc porformod bcfore rorndinj to avold roundoff ertors in celculatcd rsgrlu.
STL Denver 190
Clieut lot *- -. : D5I030139
ffi CoIEBOIT SaHPLE IIATH' RBFORr
GeneraJ- Chentetry
PERCNT
t{atrix. o - . - . . - r : IIIATER
PREPARATTON- PREP
RESIIRY METHOD A}IALYSIS DATE BATCH #
HKDP11AC LCS Lot,-SamPle# : D5I09O00O-250
100 McAww 325 .2 09 / 08/05 52522sO
1 Arralysls Tlme. . : 1O: O0
PARAI{ETER
SPTKE TUEAST]RED
AMOUNT AIYIOIINT TTNITS
Chloride
rufB (s) :
50. 0
Work Order #:
50. O mg/I'
Dilutioa Factor:
CrlculetionB are pcrformed belbre rounding to avoid round-ofifcrrors ln calcutated r$ults.
STL Denver 191
IATRIE SPIXB SAUPI,B EII'BIIIHTIqI RMORT
GelleraL Cqa+fgf,,-y
Client Iot. *- - -: D5I030139
Date Saqfled--- | og/ol/as L2zLo Date Received..z o9/02/os
PERCEMT RECO\IERY
PARAIIETER RECO\IERY frIIttITg
RPD
RPD IrIMfTg MEITIOD
wo#:
r-30)
13O) 0.31 (O-3O)
Dl-lutlon Factor: 1
Analysl,a TLme. . : 17: 0O
wo#:
13 0)
13ol L.2 (O-30)
Dilutl-on Factor: I
AnalysLs TLme. - : 05: oO
wo#,
t-30 )
L30) 0.82 (O-30)
Dilution Factor: 1
.RnalyeLe TLme,, : O5 : 0O
wo#:
130)
130) 1.5 (O-3O)
ullutLon Factrorr L
Aualyole Tl,me. . : O5 : 00
H,IVQAIee-I,IEI/U,.nrQelCD-MSD MS
MCAWW 350.l"
Meeww 350.1
tlatrl-x- - - - ! . . - - ! Y{ATER
PREPARATTON- PREP
+NlIiYsIs DATE BAT9H #
Lot.-Sample # ; D5IA2O230- 002
ae /2a / as s265424
oe /2o/ as 526s424
L'ot-Sarple # : D5I02023 0- 004
oe /L4/ os s2s7378
ae /t4/ os s2s7378
lLmmonl,a aEI N
Ammonia as N
ArnmonLa aB N
Armrpnia ar N
Ctrloride
Chloride
Pluoride
9s
94
99
9B
(*e
(ee
(+a
(++
HWQgIDP-MSIH.IIIQg].DQ-MSD MS
MCA?TIiI 350.1
MCAhIW 350. t-
100 (*e
1- 01 (+q
1O1 (++
e8 (++
10s ( 90
10,e (go
NC, DrL ( gO
Ne, DIL ( gO
H,.T8E0IA.I-MS/IIJ8E01AI(-MSD MS
MCAWET 350.1
MCAWW 350.l-
frot-Sample #:
oe/L4/as
ae/L4/as
Dsro90L52-001
s2s7378
s2s7378
HKAA1lAD-MS/nreallAE-MSD MS
MCAWW 350.1
MCAyIW 350.1
LoL-SampIe #:
oe/L4/as
ae/L4/as
D5r0903 77 -O32
s25 7378
5257378
wo# : Hirlrpo 1AR-Ms/HirvPolAT-MsD
110) MCAWW 325.2
LL0) 0.39 (O-10) MCAhIW 325-2
ffLlutLon Factor: I
Arralyeie Ti-me, . : 1O: O0
wo# : HirvQe lDK-Ms/HWQ9lDL-ptSD
1,L0) UCAWW 325,2
LL0) (0-10) MCAUW{ 32s.2
Dilution Factor: L
Analysls TLme. . : 10: O0
wo#:
107)
HirvQglDM-MSr/HJVQ9TDN-MgD Mg
LO7) O.40 (O-L0)
PLlut,lon Factor: 1
Analyeia TLme,.; 11:30
MCJLWW 340,2
MCAWW 34A.2
Lot-Sample # : D5IO20230-004
09 / oglos szszs{o
09 / oe / as szs2s40
Irot-Samp1e #:
oe / oB/os
ae / o8/os
Dsr020229-001
525 2250
52522s0
Irot-$aruple #:
ae / oB/ os
oe / 0810s
D5rO2A230-004
s2s225A
52522sO
55N
55N
(82
(gz
STL Denver
(ContJ.nued on next page)
]-92
ItrtNXT SPIre SA}IPIiE EInI,INTTTOH RBPORT
General Cteml-strar
eueat Iot *---: D5I030139
Date Saryfleal. - - . ogloL/05 L2:Lo Date Beceived - . -- 09/az/os
PARAMETER
PERCEITT RECO\iIERY
RECOI'ERY I,TMITS
RPD
RPD I.IMITS METHOD
H,.T5.n{lDE-MS/glf6.n{IDF-MSD }IS
MCAITnilI 34O .2
IICAITII{ 34O .2
Hatri-x- . . - . D . - - 3 WATER
PREPARATTON- PREP
Ar{AIYS}_S JATE BATCU #
Irot-Samgrle * : D5I080243-004
oe / oe/ as s2s2s41
09/ oe/ os s2s2s4:-
Lot -Sample #, Dsf 020230- 004
oe /zolos s255 542
oe /2olos s26ss42
Lot-Sample # : DSI02023O- 004
ae / a6/ os s24es86
ae / o6los s249586
Fluoride
Nitrate-Nitrite
99
98
Sulfate
98
98
Tota1 Cllanide
LL2
115
rurts(s):
wo#:
10 7)
107) 2 .4 (O-10)
DLlutlos Fact.or: L
enalyels Tlme. . : 1,1 : 30
wo#:
1le )
119) 1.7 (O-30)
oLlutl-on F'actor: 1
Analyate Tlme.-: 15:00
H.rTQgIDD-MSIH.NTQ91DE-MSD MS
MCAIW{ 353 .2
MCATU!{ 353 .2
76N
79N
(az
(fi
(ez
rc2
wo#:
1s3 )(+s 1s3) o.02 (o-21)
H.f\/QglDR-MS/HWQgIDT-MSD MS
MCAI{W 375.4
MCAIm 375 .4
(4s
I aq,
N
N
OLl'utlm Eactor: 1
Analy8ls Tlme..: l{:30
wo#: HwQgrou-las/uwQ91Dv-MsD Ms r,ot.-sarple #: D5ro2o23o-rof
(89 - 109) sw846 soron,/sotea oglrn-o9/L5/os 52s7427
(s9 - 109) 3.3 (o-20) sw8{G gotos/gotze og/ts-og/ts/os s2s74z7
Dllutlon Factor: 1
eaafysia rl-me.. : 12:30
Calculations are pcrformod bcfore roundlng 1o rvoid rourd+ff crron in catcrrlatd rcsrrtts.
NC Tho r€covory and/or RPD wers nor cslculrtod.
DIL Thc concenlradon is estimatod or not reported duo to rlilution or tbe presenoe of interfcring analytes.
N Spiked anrlyrc recovery is outside starod control lirnis.
STL Denver 193
ETSIT SPIKE S}UP[,B DATE, RBBOR:r
General Che[l-Btry
Clieut Iot *- - -: D5I030139
DaEe 8aq,Ied-- -= o9/o1/OS L2t1O Date Beeeirred- -. og/oz/os
SAIIIPITE SPIKE
PAR,,AMETER AIVIOTNTT AICP
l.IaLriix- D, . . . - - - r rmTER
Anmonla as N
0,38 4 . 00
0 ,38 {.00
4.L7 mg/L
4 . 15 mg/I'
4 -42 rrg,/t
4.37 mg/T'
4.58 mg/l'
{ . 61 fftg/T'
37 - G mg/I,
37.O mg/T'
76 .4 rW/t,
76 -L nr7,/n
NC, DIIr mg/L
NC, DrIr mg/T'
DLlutlon Factor: 1
Analygl.g Timc. . : 10 : 0O
2 .95 N mg/1"
2.96 N mg/L
MCAUII{ 350. 1
O.3L MCAIrm 350.1
MCAWW 340.2
0 .40 MCAWW 340 .2
PREPARJATION- PREP
AMLYgrg DATE BATCH #
09 /2o/ os s26s424
09 /20 / os 526s424
#: DsI 020230-004
ae /L4/ os 5257378
09 / L4 / Os s257s"18
MEASRD PERCNlr
A},IOTINT TJhIITS REC]\IRY RPD METHOD
I{O#: ILTVQATCC-I'1gIHWQA1CD-MSD Mg rrot-Sample #: D5r020230-002
95
94
DllutLon Factsor: 1
AnalysLe Tlme..: 17:00
wo# : H,J\IQ91DP-MS/HWQ91DQ-MSD MS lrot-SampleAnunonia ag N
0 .45
0 .45
ammonla aE N
0-59
0-58
Ammonia as N
L7
L7
Chloride
24
24
Chlorlde
ss000
55000
0,15
0.16
4.OO
4-OO
4.00
4.oO
20.0
20.A
50. o
50. o
100
100
5-00
s-00
DiluEioIr PacEor: 1
Analyrls Blne..: O5:00
VIO#: ILI8E01A.I-MS/H\T8EO1AK-}!S,D Ms lJot-sample #: D5I090152-0o1
99 MCAWW 350.1
98 L.2 MeAWIf 350,1 .
100 MCAWW 350.1
101 0.82 MCAWW 350. L
101 MCAWW 350.1
98 1.6 MCAWW 350.1
105 MCAWUT
104 0.39 MCAIrnt
MCAWW
MCAUM
# : DsI0e03 77 -A32
oe/L4/as
oe/L4/os
Dl.lutlou Factor: 1
analyeLs ?Lme-.: 05IOO
wo* : HICAA1LAD-MS/HI(AAI-1AE-MSID MS Lot-Sanple
ae/L4la5
ae/L4/as
52s7378
525737 I
s257378
5257378
Dilution Factorr I
Analygie Time,.: 10:00
wo# : HWQ9I_DK-MS/HWQ91DIJ-MSD MS
Dl-Iut,lon Factor: 1
Analyele TLme- -: 05:OO
wo# : HJVP0IAR-MS/HarVPO1AT-MSD MS Irot-Sample # : D5r0 2A229 -001
32s .2 09 / 08/Os s25225O
325 .2 09 / O8l Os 5252250
Lot-Sample # : D5I02023O-004
32s .2 A9 / A8 / Os s2s22t C
32s .2 09 / 08/05 s2s22t )
#: D5fO2O23o- 004
a9 / as / os s2s 2s4o
a9 / 09 / as szszs4o
Fluoride wo# : HWQ9]-DM-MS/HWQ91DN-MSD MS r,or-Sample
55
55
Dil-utl-on FacEor: 1
analyele TLme..: 11:30
(Cont,lnued on next
STL Denver
page)
1-9 4
IfltI?IT SPIKB BI}TPLB ITAtrL REPORT
Glenera1 Chem1strT
gf.ienL Iot *- - - i
Date 8arylIed.---I
SAIT{PLE
PARAMETER AMOITMT
Fluorlde
2.2
2.2
D5r0301,39
09/01/05 LZ:Lo Date
SPII(E MEASRD
Alvlotnirr UNITS
uatrfur. - . - r . - . - 3 WATER
RE(IM,Y RPD METHOD
tro#: ILf6JI,[ron-ug/U.r6JM1DF-IvIsD us lot-sary)Ie #: D5r080243-004
Receirrod- -: a9/a2/a5
PERCMT PREPARATION- PREP
AI.IAIJYSIS DATE BATCH #
oe / oe / os s252s4L
oe / oe / as szszs4r.
#: D5rA2O23O- 004
09/2O/os s25ss42
og/za/ os s26ss42
Nitrate-Nitrite
ND
ND
6-00 N rftg/T'
5.15 N mg/T,
DLlutton Factor: L
0.119 N mg/r,
O.L22 N mg/l'
Dllutl,on Factor: 1
3.97 mg/l'
3 . 90 mg/T.
Dllution Factorr
AnalyeLe TLma. - :
25900 rrg/T. 98
26000 rlrg/r, 9s
Pi1utslou Factor; l.
Analyaie Time. . : 14 :30
99 IVICAWW 353.2
98 L.7 MCAWV{ 353.2
I
15:OO
MCAWW 34A.2
2 .4 MCAI{Iil 3 40 .2
MCAWW 375.4
0.02 MCAWTII 375.4
s-00
5. O0
76
79
LLz
116
Analyele TLme..; 11:3O
wo# : H{IVQ9LDD-MS/H{rVQ91DE-I'!SD MS Lot-Sanple
4 .00
4,00
Sulfate
1.4 000 L2s00
14 000 12500
Tota1 Cyanide
0_0059 0.L00
o - oo5g 0.100
rscfB (81 :
wo# : HirvQg 1DU-MS/H.I1IQ9]-DV-MSD MS Lot.-Sample # : D5I02 O23O- 004
sw845 eolaB/e oe/L[-oe/Ls/as szs
3 - 3 Sw84 5 9o1 aB/ e Oe / 14 - ae/ 1slo5 s2s7427
wo*: rIirvQglDR-MS/nWQ91DT-MgD MS rror-Saq)Ie #: D5r02023O-004
oe/a6/as
oe/05/os
s24958 6
s2495 8 6
Analysls TLme..I L2:3O
Calcululons are performed before rounding to avoid round-off errors in calculated results.
NC The rccovery andlor RPD woro not calculatcd.
DIL The conccntration is cstlmarcd or not reported <lue to dilution or the prescnce of interftring analytes.
N Spiked analyte recovery Is ounlde $rted control limits.
o
STL Denver 195
SAHPT,B IIUPIficjAIE EITALTIATIOI5 RmOR:f
Geueral- CheNnittry
ClLeut Iot *---; D5I030139 f,ork Order *---: ILIXTN-9MP tiatri-x- -: WATER
HJXMT-DUP
Date sar{p].ed---s, a9/o2/0s 08:20 Dete neeeived,.l 09/03/05
DUPIJIEATE RPD
PARAITI RESI,IJT RESUI]T UNITS RPD I,IMIT IMTHOD
PREPARATION. PREP
AI{ALYSTS DATE BATCTI #
pH
5.9 5.9
SD IJot-gaq)Ie #: D5IO3012d-001
No Unl-rs 0.0 (0-5.0) sw8{6 9o4oB o9/03/os 5245099
Dilution Frctor: 1 lnalyele Tlme-.: 13:{9
STL Denver a96
STL Denver
Sarnple Receiving Checklist
Lot +' l[I D3o I ]'f .. Date/Time Received:tbt r
CompanyName & Sampling Site:l'perle pN ?i , c6 .^t,"r.1,-...
OESO
PM to Corrrplete This Section: Yes
Rcsidtral chlorine check required:f
Quotc #:
Special Insrructions:
Time Zanc:
. EDTTEST . CDTICST . MDT/}yIST . PDT/PST . OTFIER
Quarantined :
-Ies Norlo
Uopacking Checks:
Cooler#(s): ( L
Tcrperanlres("C): (tS '{.9
N/A Yx NoDfrr.
p!l 2.
Ltf3.
of 4
f ?ti
tr .{- 6.
Oo7.
B(r.?.
q
3,(,
r'
7.',L
Cooier seals intact? (N/A if hard delivered) If no, doorment on C[IR.
Chain of custodypresent? Hno, documcnt on CUR-
Bottles brokeu aad/or are lealring? If yes, document on CUR*
Multiphasic sarrples obvious? If yes, doctmtent on CUR.
Proper container & presewatives used? (ref. Attachrnent D of SOP# DEN-QA.r0003)
pH of all sarrples checked aud meetrequirements? ff oo, aoo&a-{r=q$ )
If no, document on CIJR.
Sufficient volu:rre provided for all analysis requested? (ref. Attacbmcnt D of SOP# DEN-QA-0003) If ao,
docuoent on CUR, and contact-PM before proceedirg.
Did chirin of custody agrce with Iabels ID and samples received? If no, docurnent on CUR
Wcrc VOA sarryles without headspace? Ifno, do$Bpe-nt o, dUR:" --
V/ere VOA vials preserved? Preservative 'eHCl .44!2"C tjsodium Thiosulfate Q.A.scorbic Acid
Did sarrples require presewatioa witt sodir:sr thiosulfate?
If yes to #1 I, did the samplcs contaia residual cblorine? Ifycs, documenr on CUR.
Sediment present in dissolved/fiitered boules? If yes, document on CLIR
Is sfficient volume provided for client requested MS, MSD or matrix dupiicates? If no, documcnt on CU& and
coDtact PM before proceeding.
Receipt date(s) > 48 hours past the collection date(s)? lf yes, noti$ PA/PM.
Are analyses with short holding times requested?
Was a quick Turn Around (TAT) rcquested?
P{l
tra
DfI
D iII
E3
DT
il 3
o
e
,#n"* o
ry
tr
?
f
fi
tr
SmtSE?{ffETrle Rcrciving\Sample Rccciving Chccklist I2 Ls 04 revision L2n3tM L97
STL Denver
Sample Receiving Checklist
Lot# b;lD3D/ s7
Login Chccks: tninals
N/A l'es No tr
p D lti. Sufficient volunuprovidcd for allanalysir rcquceled? (ref. Anachmcnr D ofSOPf DEN-QA-0003) If no,
dtr
documeil on CuR, and contacl PM beforc procccdirrg
A I9. ls suflicisnt votume providcd for client rcguested M.S, MSD or matrix duplicates? lf no, rlocument on CUR, and
ccrtttad PM beforc proceeding.
D 20- Did thc chain of custody includes "received b)," and "rclinguished'by eiglatures, dates, and timcs'l
tr 2l- Were special lq in instructions read and followed?
tr 22. Were AFCEEmctals logged for refiigcrated storage?
U
tr
m
L
il
EO
dD
&
prr
trs
n
D
B 23- Wcre rc*r Ioggd chcclied againsl thc COC? lllhich samples ncrc conlirmcd? P,
24- Util a Rrtsh lbrm complacd for guick Tel*.r
25. \llar a Slrort Hold form conpletcd for any short holds?
26. Is'Strid lC0C-rcgubed?
??- Wcrc special archiving futslrucfioDs indicarcd in rhe Gcmrat Comrpnts? lf so, u,hat wcre fhc1,?
o
Laheliry atrd Storage Checks:lnitia.lsM
i,T
{r)
fir
YCJtrtr
trtr
trE
28- Was ibe rlbcouragt COC signcd aod scnl witb samples to bottle prcp?
29- Were sasplelabels double-checkcd by a second pcrson?
30. Wcre saryleboltles aad COC double chacked frn' dissolved,/filrcred m.ub b1, a secoad pcrson?
3L Did the sarrylc ID, Datc, and Tinrc from label marcb uihal u,as loged?
32. Wcre stickcrs for ryeciat archiving insruaions affixed to Eadr box and ttr tbe ICOC? See #17
33. ll,ere .AFCEE muals stored refrigcralcd?
34. \{ere *Stid ICOC" copics givcn to sarellite storage areas?
Docuurenl any problcms or disc.rcpancies and the actions taken to resolve them on a Condition Upon Receip Anomaly
Report (CIJR).
STL Denver 198
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STL
STL Denver
4955 Yanow Street
Arvada, CO 80002
Tet: 303 736 0100 Fax: [phone]l7l
www.stl-inc.com
ANALYTICAL REPORT
Western Zirconium Project
Lot#: D5ll30I98
Sheri O'Connor
URS Corporation
81 81 East Tufts Avenue,
Denver, CO 80237
STL DENVER
fuv
Linda L. Benkers
Project Manager
October I 1, 2005
Severn frent Laboratories, lnc.
Table Of Contents
Standard Deliverables with Supporting Documentation o
Report Contents
Sfandard Deliverables
(ln, Cover Letter and the Rqon Cover page are considered integral
parts of this Standard Deliverable paclroge. This report is incomplete
unless all pages indicated in this Table of Contents are included)
o Table of Contents
o Case Narrative
o Execuflve Summary - Detectlon Hlghllghts
o Methods SummsrT
Method/An alyst S urnmsry
o Lot Sarnple Summary
o Anatydcal Results
o QC Data Association Summnry
. QC Sample Results
o Chain-of-Custody
Su pporti ng Doc u me ntatlon
(Note: A one-page "Description of Supponing Documentntion" is
pruwided at the beginning of thls sectton-).
o VoIntIIe GC/I\{S
r Semivolatlle GC/MS
r Volatile GC
o SemivolaflIe GC
o LCIMS or HPLC
r Metals
o C*o.ral Chemistry
. Radlochemistry
o Subcontracted Data
Nurnber of Pages
Check below when
supprlrtlng
documentatlon ls
present.
nnnnEEnn:
STt Denver
Case Narrative
Dsrr30t98
With exceptions noted as flags or footnotes, standard analytical protocols were followod in the
analysis of the samples and no proble,ms were e,ncountered or anomalies observed. All laboratory
quality control samples analped in conjunction with the samples in this project were within
established contol limits, with anyexceptions noted.
The test results presented in this report meet all requirements of NELAC, and any exceptions are
noted. This report shall not be reproduced, excqlt in frrll, without written perrrission from the
laboratory.
Sample Recelvlng
Four samples w€re received under chain of custody on Septenrber 13, 2005. The sarrples were
received in good condition at ternperatures of 3.6oC, 4.1"C, 3.9"C, and 3.3"C.
Please note that the samples submitted for 82608 aualyses require reporting of Chloroform only
as per client request.
Also, note that the chain of custody list samples ID's as BWI-091205 and 8W2491205. As per
clielrt request the saniple ID's were changed to BW01-091205 and BW02-09l205,respectively.
Sample aliquots for all radiological anal5rses are logged in under a separate lot and were sent to
STL St L,ouis; 13715 RiderTrait North; Earth City; MO 63045,phone [phone].
GC/IVIS Volatiles, SWM6 82608
The MS/MSD associated with batch 5268077 was performed on sample D5Il30t 98-004 and was
in control-
No anomalies were observed.
Total Metals, SW846 60108,6020 & 7470A
Samples D5I130198-002 through 004 and ttre MSiIv{SD performed on sample 0&[ were analyed
at dilutions for cadmium and selenium by method 6020 due to matrix interference. The reporting
limits are adjusted acoordingly.
Calcium was detected in the method 60108 blank at a concentration below the reporting limit but
above the method detection limit. Associated positive sample results are flagged "J".
The method 60108 MSA,ISD associated with batch 5266567 performed on sample D5I130198-
004 was in contol. The recoveries for sodium are not calculated because the sample amount was
greater than four times the spike arnount.
A second method 60108 MS/IvISD associated with batch 5266567 performed on a sample from
another client and/or lot was not in control.
Denver
The method 7470A MSA{SD associated with batch 5269496 was performed on saurple
D5Il30l98-004 and dernonstrated recoveries below the contol limit for mercury.
The method 7470A MSA,ISD associated with batdr 5269496 was performed on sample
D5I130198-002 and demonstrated recoveries below the control limits formercury.
The method 6020 MSAiISD associated with bateh 5266564 was performed on sample
D5Il30l98-004 and was in control.
A second method 6020 MSA{SD associated with batch 5266564 was performed on a sample
from another client and/or lot and was not in control.
Serial dilution of a digestate in analytical batch 5266567 performed on sample D5II30198-0M
indicates that physical and chemical interferences are present for vanadiurn. The associated data
are flagged "L".
No other anomalies were obse,rved
General Chemistry, Verlous Methods
Sarnples D5I130198-002 through 004 were arlralyzed at dilutions for chloride and sulfate due to
high analyte concenhations. The reporting limits are adusted accordingly and the associated
data is flagged "Q".
Chloride, fluoride, and sulfate were detected in the method blanks at concentrations below the
reporting limits, but above the method detection limits. Associated positive saurple results are
flagged "J"-
The MS/IvISD performed on sample D5I130198-004 was in conhol for ammonia and nitrate-
nitrite-
The MS/IvISD performed on sample D5I130198-004 demonskated recoveries above the contul
limit for chloride and sulfate. The MS demonstrated a recovery above the conhol limit for
fluoride. AIso, the MSA,ISD derronskated recoveries below the control limits for cyanide.
All other MSA{SD samples were performed on samples from other clients and/or lots and some
were not in control.
The pH duplicate performed on a sample from another client and/or lot was in contol.
No other anomalies were observed.
STL Denver
o W - I)etection Highlights
D5r130198
RESt'I,T
REPORTING
LTMTT UNITS
AI{IA[,YTIEAIJ
METHODPARATVIETER
cf,-8w92-O9120s OglLz/aS O8: OO OO2
Selenlum
Alumlnum
Barl-urn
Copper
NickeI
VanadLurn
Zirrc
Calcium
Iron
Potassiunr
Magrnesiullr
SodLum
zLrconium
Chlortde
FluorJ-de
Nitrate
Nitrate-Nitrl-te
pH
Su].fate
Ammonia aB N
Gfl-BwOL-Og1zOs Ogllzl As 11: 15 OO3
0.0038 B
0.038 B
0 ,65
0,013
0.00L2 B
0.0045
Qualifiers: B, L
o.o22
26 iI
o,23
140
s0
+200
o.003L 8
53Oo J,Q
1_3 il
o.18
0.18
B-4
620 J, Q
5_0
ntg/L
mg /t
mg/1,
mslL
mg /T'
mg/L
ntg /T,
mg/r,
wts /r'
mg /T,
mg/L
mg /T,
mg/L
mg /r'
wrg / T'
mg /T'
mg/r-,
No Unite
mg/t
mg/L
ntg /T'
ng/t,
nrg/L
mg/t,
mglr,
mglI-
mg /T'
rilg/L
mg/L
mg /T'
mg/t
r/lg/L
rvg /r'
mglL,
mg/L
mglL
No Unl-ts
mg lt
sur84 5 6a20
sw84 6 6 0L08
sw84 6 5 0l-08
sw846 50108
9w846 60108
gw845 50108
sw845 6010B
SW84 5 ,601O8
sw845 60108
sw84 6 6 0108
sw845 60108
sw84 6 6 0108
sw846 60L08
MCAWW 325.2
TICAVIW 34O.2
I,{eAww 353 .2
MCAWW 353 ,2
sr{845 90408
MCAI{W 375,4
MCAI{W 350.1
glr846 6020
sw846 60108
sw845 50I_0B
sw846 60108
sw845 60108
9w846 60108
sr{846 601-OB
sw845 60L08
sw846 60108
sw84 6 6 01-OB
sw846 60108
slr845 60L08
MCAI'[I{ 325.2
MCAWW 340.2
}{CAWW 3 53 .2
IYICAWW 353 ,2
sw846 90408
MCATilW 3 75 ,4
0.010
0. L0
0.0L0
0.010
0 - 040
o. o10
0.020
o.2a
o - l_o
3.0
0.20
s-0
0. 01,5
250
o. Lo
0.10
0.10
o. Lo
250
0.10
Selenium
AlumLnum
AreenLc
Barl-um
Copper
Vanadiurn
Zinc
CalcLum
Iron
PoEaseirun
Magnesirrrn
SodLum
Chloride
Fluoride
Nitrate
Nitrate-Nltrite
pH
Sulfate
o-0034 B
0.083 B
o. 0058 B
0,17
0-0452 B
o. 003 I
QualLflers: B, L
0,L2
92J
0-13
324
160
5800
LL000 ,], Q
0.020
o - 1_0
0. 015
0. o10
o. o10
o. ol-o
o. 020
0.20
0.10
3.0
0.20
5.0
250
0.71 J 0.10
0.17 0.l_0
0.17 0.10
8. 1 0. L0
2Lo0 J, Q 500
(Contl-nued on next page)
STL Denver
EXEW W -Iletection rlighlights
D5I1301e8
RESI}LT
REPORTING
T,TMIT T}NIlrS
AI{ALYTICAI,
METHODPARAMETER
ffi-Bwor--o912os og /Lzlos 11 :15 oo3
Rrmnonia as N
Grr-Brro2-ogl2os og/tzlos LZ=22 oo4
Selenium
aluminum
Barium
Copper
Vanadlum
CaIcl-um
Iron
Potasslurn
Magrneeiurn
Sodium
ZLrconl,um
Chlorlde
F].uoride
Nitrat e
NitraLe-Nltrlte
pH
Sulfate
Ammonia as N
6 -9
0.0037 B 0.010
o. 10 0.10
0.63 0. o10
0.0046 B 0.010
0.0045 0.010
Quallflers: B, L
24 ,f O .2O
4.24 0.10
130 3 - O
4B 0 .20
4000 5.0
o.0a24 B 0.015
5500 J, Q 25O
!.2 ,, 0-1-O
0.99 0,10
o. gg 0.10
I _4 0.10
550 J, Q 1OO
5,0 0.10
0 . LO mg/T'MCAWW 350.1
sw846 6020
gw84 6 6 0108
sr{846 601-0B
sw845 60L0B
sw845 60108
sw84 6 6 0108
sw845 50108
SIi[846 60108
sw8{ 6 5 0108
sw846 50108
sw846 60108
MeAr{w 325 -2
MCAWW 340.2
MCAWW 353 .2
MCAYIIIf 353 .2
sw845 90408
MCAWW 375 .4
MCAfnif 350.1
mg/t,
$tg/L
mg/r.
mg/r,
mg /r,
rtg / T,
rrg /r,
mg /t'
ms/r'
mg/L
mg /r'
mg/L
mg /r'
mg/T,
mg /l'
No Units
ntg/t
mg /r'
o
'':
STL Denver
o METTIODSW
DsI130a98
PARAMETER
PREPAAATIOhI
I"lETHOD
pH Aqueous 911846 90408 sw846 90408
Chlorlde (colorimeLric, Autonated Ferricyanlde) McAl{w 325-2 MCAWW 325.2
Fluoride (Potentiometric, Ion Sel-ective Electrode) MCAWW 340.2 MCAIIW 340-2
Inductivel-y eoupled Plasna (ICP) Metals sw8{6 60108 sw846 30104
rcP-Ms (6020) sw8rr6 6020 sw8{6 3020A
Mercury in Liquid waste (Manua1 Co1d-Vapor) SI{846 7470}. SW845 '747OA
Ilitrate MCAww 353.2 MCAWW 353.2
Iilitrate-Nltrite McAwvt 353.2 MCAWW 353.2
Nitrogen, AnunonLa MCAltlf 35O. f- MCAVIW 350.1
sulfate MeAv{I{ 375.4 MCAVTW 375.4
Total cYanide sw846 9O1OB/901 SW846 90108
Trace rnducuively Coupled Plasma (ICP) Metale S11846 50108 SI{846 301oA
vol-atile organJ.ce by GCIMS sI{845 82608 5T1846 50308/825
Referenaeg:
AIiIAI,YTTCA.L
METHOD
nMethode for Ctremtcal analysig of water and Wagtesrr
EPA-600/4-79-o2o, t'tarch 1983 aJBd subeequent revlslons.
ilTeBt Methods for Eval-uating Solid waste, Physical/ChemJ.cal
Iltethods',, Third EdLtlon, November 1985 and lte updates.
IT{CAWW
sw846
STL Denver 5
AIVAIJYTICAIJ
METIIOD
MEIHOD/ANALYST
Dsr130198
ANATYST
MCAWW 325 -2
MCAI{W 340.2
I"ICAWW 35O.1
MCAI{W 353 .2
MCAWW 375.4
sw846 60108
sw84 6 6 0108
sw846 60108
sw845 60108
sw845 5020
9w845 5020
sw846 74'7 0A
sw845 82508
sw846 eo1 aB/eolzA
sw846 90408
Referenees:
MCAWW
sw8{5
Claire L,l}car
Foug:ere M. Danielle
Claire l,ikar
Clal-re Likar
DusEi o. Criqui
.Iane1 Motlchka
.]anel Motlchka
Lynn-Anne TrudeII
Lynn-Anne Trudell
Thomae LiII
Thornas lrill
Janice S - Collins
Heather Despres
Dust,i o. crlquJ.
Fougere M. Uanlelle
AfilAIrYgT
ID
o043 82
006481
0 04 382
0 04 382
00658 e
0 02 862
2852
0 05645
5 545
0 05 929
5929
o11558
o09250
005589
006481
nMeEhode for Chem'iea1 Analysis of Water and Waatesrt,
npa-eOO/a-79-02A, March 1983 and eulreequents revisions.
trTest Methods for Evaluating solld Waste, Phyoical/chemleal
Methodstr, Third Edition, Noveriber 1986 and ite updates.
STL Denver
SAIVIPLEW
Dsr130198
SAII{PL,E:D SAII{P
DATE TIMEwo#SAI',IPLE*etfEluf SAI'IPLE fD
HKE3N OO1 TB- 091205
HIG3Q A02 cW-BW9 2-0 91_2 05
HKE3W O03 G'yS-BWOL-091-205
HKE3O O04 GIrI-BI{O2-A91205
rurE (8) :
oe/L2/os
oe/Lz/os o8:oo
09/1,2/05 l-1:15
ae / tzl os L2 222
O
- The analytlcal re*lB of the sample3 listed rbove are prmred oa &e following p4rs.
- All celqrbtionc ero pcrfomcd bcforc routriing to avoid roud-off qrors iD csleul&tod resohs-
- ItBdt8 Dolld ei 'ND' wcrc Dot dctcctcd il or lbove he sEtcd limit.
- ThlG repott musr not bc rGproducEd, oxcot in fuI. wifiout thc wrisen.pprovsl of drc lrbomrory.
- Rcsl6 fot thc followin3 penmerer rro mvc, reorted on a dry rrci3ht basis color, corosivity. dauity, flr$polnt, tgnltsbility. laycrs, odor,
pritrl filtd ics, pH, porosity prcssnrc, rEacrrviry, rcdor JDtmtirl, qccilic gnvity, Sot resrs, solids, Gohbility, tmpcreturc, visoosity, &nd x,cifril.
STL Denver
IrnS Corlroration
Cl-ient Saqfle II): 1B-O9a2O5
Gr,l}'6 vo]"atl.lea
Lt-Saq)le *---: D5I130198-001 &rk der *.-.; HIG3N1AA
Date saryrred-- -. o9/L2/O5 Date Receirred--r O9/t3/05
Prep Date -. O9/2L/O5 laalyeiE Date- -. O,/zL/OS
Prep Batcb *---: 5268077 eoalyel-a Tire.-: 09:25
Dilution ractor: 1
l{ethod,
RESUIJT
: SW845 82508
PARAIT{ETER
o
REPORTTNG
LN.'[TT UNITS
Ch]-oroform
ST]RROC,ATE
lTD
PERCEITT
RBCO\'IERY
L-0 rug/t
RECO\IERY
IrI!,IITS
(zs 118)
(sz 128 )(ze 118)
(tt L17 )
Dibromof 1uoromethane
L, Z-Dichloroethane- d+
4 -Bromofluorobenzene
Toluene-d8
86
74
97
105
STL Denver
tRg Gorporation
Client 8aqile rr): Gt-8f,92-o91ilo5
@/us vol-atiles
r.ot-Saq)Ie *- - -: D5I13O198-OO2 llork (}r:der *.. -: HICE3QIA7 rhtrir- - - -: GW
rlate saryrled-- -: O9/t2/05 08:00 Date Received- -. o9/L3/O5
Prrep rlate .: og/zt/os eoallzsio Date- -! a9/2l/a5
. Frep Bateh *- - - : 5268077 analyeia Tirrc- - : 09:43
Dilutim Eactor: 1
r,Iethod- - - -: SY[846 82608
REPORTINGT
PARJNTETER RESULT LIMIT UI{ITTS
Chloroform
SIIRROGATE
Dlbromof luoromethane 96
L,2-Dlchloroethane-d4 93
DID ]- . 0 vg /t'
PERCBVT RECOVERY
RECOVERY I,IMITS _.(tt L1,8 )
(sz l-28 )
(ze 118 )(tz LL7 |
4 -Bromofluorobenzene
Toluene-dB
92
B7
O
,i
o
STL Denver 10
Iot-gaq)Ie t..-3
Ilate Saq}I-ed- - -:kep llate------l
Prep Batch f,- - -:
Pt].utl-on Factor:
D51L301.98-003
a9/Lz/os I-1:15
ae / 2L/ as
s258077
L
IIRS Corpsrat'iorr
Cl.ient Sarlgll.e ID: GH-BWO1-O912O5
str'lus vo].atiles
IIork Order *.-.3 HICE3WIA^]
Ilate Becelwed- - = 09 / B / A5
Ana-Iysie Date-. r a9/2L/o5
nnalysia Ti-ne. - 3 10 : 02
tietIod, - - - - - - - - : SW846 82508
PARAMETER REST]T,T
ITD
PERCBNT
RECOVERY
REPORTING
IJIMIT
1.0
RECO\IERY
LIMfTS
(73 118 )
(dz 128)
(ze 118)
(ll ]-L7)
Chloroform
gURROGATE
D ib romo f luorome tha,ne
L', 2 - Di chI oroettrane - d4
{ -Bromof}uorobenzene
Toluene-d8
L02
gtL
101
92
tlatr{x- - - D o - - - - 3
STL Denver
o IrRS CorporatLon
Cl.ient Saryr1e D: GII-BHO2-09L205
w,lus vorati]-ee
Hork Order #-. -: HKE3OlAif
Date Recelved- . i a9 / L3 / aS
ena1lrsie Date. - ! 09 / 2L/ 05
Analyeie Time.,3 10:21
Ifigthod. - - - - - - o - : SW846 82608
llatrix-or,--,--: GWIot-Saryfle *- - -:
Date Sary)led- - -:
kep llatg---.-.1
Prep Bat& *,. - 3
Dilution Factor:
Dsr L3 0L98 - 0 04
a9/Lz/os LZ=zZ
ae / 2L/ os
5268A77
1
PARAMETER RESTILT
ND
PERCEITT
RECO\TERY
REPORTING
I,IMIT UNTTS
1.0 ug/T'
RECO\IERY
I,IMITS
( 73 1r-8 )(sz 1-28 )(za 118 )(tz LLT l
Ch].oroform
SURROGATE
D ibromo f I uorome t hEule
L, 2- Dlchloroethane - d4
4 -Bromofluorobenzene
Toluene-dB
94
89
97
92
STL Denver
:
L2
Iot-Baq[e *, -.3
Ilate Saryrl.ed--.r
PARAIUTETER
IIRS Corgrcration
ClLent Saryrle ID: ffi-BII92-O9I-2O5
TCIDAL }letals
D5r130198-002
og/Lz/as 0B:00 Date Reeelved-. 3 og/n/aS
RESULT
REPORTTNG
LIMfT UNITS IvIETHOD
llatrL:r-------3 GT|I
PREPARATION- WORK
AIVAIJYSTS DATE ORDER #
Prep Bateh
Cadrnium
8ek:uflrur
PEep Bat'ch
Silver
Alumi-num
Arsente
Barlum
.'
Ca.lcl-um
Chrornlum
.
CTPCT
Iron
Potaeeirrm
llagnegl-rm
fi---: 5266554
ND
o. oo38 B
#..-3 5266557
ND
o- o38 B
ND
o.65
26 ir
ND
o_o13
a -23^
140
50
4200
o. oo5o mg/T,
Dilution Factor r 5
0 - O1O mgll'
Dllutl-on Factor: 5
0 .0L0 rW/t
DlLutlon Factor: 1
O - 10 ryll,
Dl-lutl-on Faetor: 1
O. O15 ng/t-,
Dl}ut.Lou Factor: 1
O - Ol-o rylt
DLlution Factor: I
O -2O ryll'
Dilution Factor: L
O - O10 rfiglT'
Dllution Factorr 1
O - O1O rug,lt,
DLlutLon Factor: 1
O - 10 tng/L
Dilution FacLor: 1
3-O ug,lf'
Dilut,lou Factor: L
O - 20 rytll'
ffllutl.on Factor; 1
5.0 rylt'
Dilution Factor; 1
(Continued
sw845 6A20
Analysis Tl-me. . : 0{ ; 18
gDr846 602fJ
Analysle Tina- - : O4 :18
sw845 50L08
analyeis TLrne. . : t3 ;21
sr846 50108
Analyele Time. -: 20:48
sw84 5 5 010B
Analyaia Tlme. . : 13 :21
91846 60108
Analyeis Time. . : 13 ;21
811846 50108
Analyele tima..: 20:{8
sw845 60108
^Rnalysie Time. - r 13 r2L
9H846 60108
Analyets TIme--: 13:21
6'XI846 50108
Analyeis rime..: 15:39
sH846 60108
AnalyoiB Time.-: 2o:48
sH8{6 50108
Analyeis Tl-me. . : 20 :48
811846 60L08
Analyeia Tl,me. -: 20248
next page)
oel26-oe/28/os
ael26-oel27 las
os/zG-os/za/os
oe lz6-oelzsl os
oelz6-oelz7 I os
ae/zG-oel28/os
osl26-osf 2slas
oe l28-oe l2elas
oel26-oel2t los
oel26-oelzz los
oelzt-oelzr los
oe / 26-ae / zs / os HrcE3Q1A3
ae lz6-oelzs los EXB3Q14,4
:
:'
HKE3Q1^AH
HXB3QIA.T
IIXB3QIAIJ
EXB3QLAV
HKE3QLAIT{
Ef,B3QIAry
HXBQLAT
EXB3QUAX
HXB3QI.iAO
13
T0rL1
O
STL Denver
IIRA Cor;nration
CLLerE garqfle ID: Gfr-BII92-Oga2Os
fXAIr Heta-ls
Iot-Saryrl'e *- - -: D5I130198-OO2 l,latrLx. - -.: Gw
REPORTTNG PREPARJITTON- WORI(
PARAIIETER RASUIJT I'TMIT I'NITS METIIOD AI{AIJYSIS DATE ORDER #rrickel o-oour B o-o4o qtfi, strr846 60108 o9126-a9l28los ExE3oilAP
Dilution tractor: 1 ,lnalysis Time.,: 13;21
Iread tuD o.0o3o tns/r, gw84c 60108 o9/26-09/2s/os Irm3QlAQ
DLLutLon tractor: L ArtalyaLs Tlne..; 13:21
vanadlnrn 0-00,16 B,r, o-o1o ry,l[, sr8.G 60108 o9126-a9l2Blos Ef,Ber"BR,
Dilution Factor: 1 irDalyeie Tlme-.: L3:21
o-o22 O-O2O rylr, 8[1845 60108 o9/26-Ogl?rSl}s rrrE3orl[T
DilutioB Eactor; 1 Analysis Tine..: 13;21
zircpnirm o-0o31 B o-o15 rylr, sr846 6010B o9f26-osl2'tlo5 ExB3oaA2
Dilution Pactor: 1 Anal.yeie Tlme.-: 20:{8
Priep Batclt *. - -: 5269496
I lYlercurlr ND 0-oo02o ng/r, gwB4G 747oA og/3a/as I{KE3Q1AU
:oilutio Factor! 1 Analyo1s Timc--: 15:56
; , rcfB(B):
B Estimrtcd rmrr- Rasli l$ lcss dran RL
J Mcthod blanlr coouminetioo. The $rociated medmd blank cont8los &c largct 0n&lytc at a rcporEblc level.
L Suil Ailution of a dfcstrtc in lhc rnatytial b*ctr indicatcs Orat phpicil end Ocndcrl lnterfcrcnccs arc preant.
o
STL Denver L4
TIRII Corlrcration
C1ient Saryrl-e ID: GII-B|IOI--O9I-2a5
IIUEAL lleta].o
D5I130198-003
09 / L2/ as 11 : 15 Date Recelved- , i 09 / L3 / os
RESUI,T
REPORTING
LIMIT T'NITS METHOD
PREPARATION- WORK
AIiIALYSTS DATE ORDER *
o
Iot-Saq)I-e *,..3
Date Saryrl-ed- , -:
PARAMETER
GW
Prep Batch *-. - 3
CadmLum
Se1cnl-rm
5266564
ND
o-003{ B
0 - 010 mg/L
Dllut,Lou Factor: L0
0 - O2o ryll'
Dilution Factor: 10
O.0l-O rttg/l'
DLlutlon FacLor: '1.
0.10 rylr-
Dl.lutl,on F'actor: L
O - O15 rryll'
Dilution Factor: 1
o- O1O ry,IL
DiLution Factor: 1
O.2O ry,IL
Dilution Factor: 1
0. O1O Yrrg/L
Dllutl,on Factor: I
O - OtO trg,ll
Dilution Factor: 1
O - 1(l rytlf,
DiluE,lon Eactor: 1
3-o rytlL
Dilution Faetor: 1
O.2O rngll^,
Dllutl,on Factor: 1
5-o ryll.
Dilutlon FaeEor: L
(continued on
sw845 5020
ArralyaLs TLme. . I 04 t22
gDI845 6020
"enalyoia Timc. . : 04 :22
oe / 2G -ae / 28 / os HI(E3wLAE
ae I 26-ae 12tg I as EKB3njaF
AreenLc
Cal-cl-rur
ChromJ-um
Iron
Pota.gsirm
llagmesium
:
Sodlun
, PreD BaEeh
Silver
ehmtnun
*.-.3 5266557
ND
0-083 B
o-oo58 B
o -L7
92J
ND
o-oo52 B
o-r-3
320
160
6800
sw846 60108
Aaalyeis TI"me. - : 13 : 26
sH845 50108
hnal-ysie Time- - : 2O : 53
S111846 50108
Aual.yele TlmB..; L3:26
srr846 50108
Arralyeie Tl-me. . : 13 : 25
5:W846 60108
Analysls Tlmo..: 20:53
sw845 50108
Analyeie time..: 13:25
sw8{6 60108
AnalysJ.e Tlme. . : 13 : 26
sH846 60tOB
AnalyaJ,s Time. - : L5 :43
srr846 60108
Analysie Time..: 20:53
srr8{6 60108
enalyeia Time..: 2o:53
grI845 50108
Analysie Time..: 20:53
next page)
..
oe / 26-ae /28 / os HICE3WLjAR
oe I 26* 09 127 I As Hffi3nrar
oelzr-aelzslos ffi3
oef26-o9f2S/os EE3
09 I z6-ae I zr I as Em3rl,as
WlAU
O
rILV
ae/26-oe/28/as
oe f 26-oe l28/ os
os lzs-is tzg I os
oe/26-09lz't los
oel26-oel27 /as
oe lz6-oe lzt I os
HI(E3W].AW
EKB3rJ.JAX
HKB3W1,45
EXB3WI.B'T
EKB3WIAE
HXB3miAe
o
STL Denver
Iot-Saqrl.e f-..8
PA&AIYIETER
IIRS Corgrcration
CII-ent Saryrle il): Gfl-BHO1-091205
TCIEAI, Iteta]-s
D5I130198-OO3
RESULT
REPORTTNG
I-IIMIT UNTT9 I,lETHOD
rrlatrix--------.3
PREPARATTON- WORK
ANTAIJYSTS DATE ORDER #
NickeI
Iread
Vanadirur
Zi.nc
:
Zirconiun
ND
o-oo38 B,L
o-12
ND
0.040 mg/L
DllutLon Factor; 1
O.O03O mg/1,
OllutLon Factor: 1
O - o1-O ryll,
DLlution E'actor; 1
O - O2O rgll,
DilutLon Factor: L
0.015 mg/T,
oilution Faetor: 1
0. 00020 mg/L
Dilution Factor: 1
9w846 60108
Analyols Tlme,.: 13:25
sw846 60108
Arralyele Tl-me. . : 13 :26
sn845 50108
AnalyaLs Tl:re. . : L3 226
srl846 50108
.Bnalyeie Tl-me. . : L3'.26
sw84 5 60108
Analyaie Time.. - : 2O :53
ae/25-oe/28los
oe/26-ae/28/as
oe lz6-oe l28l0s
oel26-oel2slos
oe/26-oe/2t/os
HKB3I'T1AO
HKE3W].A1
HXE3rIB,z
Hffi3HAA3
,
HI(E3WIAI)
Erep Batch
Mercury
rrorE (s) :
S---: 5269496
ND sril84 6 747 OA Oe / 3A / as
Analyele Tima. -: 17:04
HKE3WLA4
. A Btuta0od rc$tr Re$ltisl6cthm RL
, :ueoi *t btrr,t *r,no,lmtion. Tld, ulociarra mcthod blEnt conlllnr rhc trrgcr mrlytc Et a rcporiable lcvcl.
L Schl dilutlon of a dijcstrfe in the amlydcrl batdr iDdicraes lhat ghysicrl and chcmical imerfamarcprdat.
STL Denver a6
IrRII Corporation
ClLeut Saq>Ie ID: Gfl-BWO2-O912O5
rcXAf, liet^a].a
Dsr130198-004
09 / Lzl os L2 t22 tlate Reeelrred- - 3 09 / L3 / os
rrlatrir(. - - - , - - r GTiI
PREPARATION- WORK
ANALYSIS DATE ORDER #
Iot-8aryfle *. ..3
Ilate Saqrl.ed.- - -:
PARAMETER
REPORTINCI
I,IMIT UNITSRESUIJT METHOD
Prep Batch S- - -:
Cadmium
SeIenfurm
5265564
luD
o. oo37 B
0.0050 mg/l'
Dilution Faetor: 5
O- O1O ryll'
Dllution Factor: 5
0.0050 nq,/L
Dllutlon Factor: 1
o.1o Wll'
Dl-lutlon Factor: I
0.015 ntg/L
ol-lution Fact'or: 1
o. ol.o rytll
Dtlut,l.on Factor; 1
O-2O ryll-
DL]'ut,l-on Fastor: 1
0. O1o nq,/t
DllutrLou Factor: 1
0 - O1O mg/r,
Dllution FacEor; 1
O - 10 Wlt'
PLlutJ,on FaeEor: 1
3-O rylr
Dl-Iut.lon Factor: I
O-2O ryll,
Dilution Factor; L
5-0 ryln
Dilution Factor: 1
9I{846 602A
Analyeia Time-.: O4:26
4H846 6020
AnalysI-s Time..: 0{125
sw84 6 60108
Analyeie Tl-trre., : 13 : 41
sr846 6'0108
nnalysis TLme..: 19;79
sw846 60108
Anal.yale Tl-me. . : 13 :41
g11846 60108
Inalyaie Time..: L3:{L
srr846 60108
Arralysl"e Time. . : 1,9 : 29
gw84 6 6 010B
AnalysLe TLme. . : 13: {1
sr846 60108
AnalyeLs Tlme..: L3;{1
srr846 501(}8
Analyels Tlme, . : 1"5 : 20
sII846 50108
Analysia Time..: L9:29
6"H846 60108
Analyeis TLme..; L9t29
91845 60108
Analysie TLme..; L9:29
next page)
ae / 26 - oe / 28 / os I{KE3 olAE
oe | 26- os I 2s I os EKE3 oxar
ae / 26 - o e / 2s / Os HKE30IAR
oe I zr-og I 2t I os EKE3 ortrT
*, - -: 5266567
ND
o-1(,
TID
o-53
24 ir
ND
0-0046 B
o -24
130
48
4000
Prep Bat(fr
Silver
Ahurfunln
Arsenic
,
BarJ.um
Calcirm
Chromium
Colper
Iron
.Dotaegirrm
ual;neel"tm
Sodlun
oe/26-oe/2s/os
osl26-os l2I,l Os
asl26-osl27 los
ael26-oe/zB/os
oe 126-ae/2s I os
os l2s-os l2g I os
oelz6-oelz7 los
oelz6-oe/2'I los
HKE3 O
HXB3O
8ffi30x[5
HI(83 O lAW
HKE3OTAX
IIIG30IA6
HITE3Ol;L7
Effi3OIAA
lAUo
IA\r
ae I 26*ae | 27 / as Hffi3orilc
STL Denver
(ContLnued on
Iot-Saq[e S- - .:
IrRg Cor;loratLm
C1ient Barylle rD: @I-BIIo2-0912A5
IIUEAL Hgt'ar s
D5r130198-004 Ilatrtr--,-----!: GW
PREPARATTON- WORK
A}IALYSIS DATE ORDER *PANAIVIETER REgI,IJT
REPORTING
tII{TT UNITS METHOD
NickeI
Iread
vanadirm
Z:rn.c
Zirconiun
ND
o - oo45 BrL
ISD
o- oo2{ B
0 . 040 mg/t-'
Dilution Factor: L
o-0o30 mg/r,
Dllutlon E'actor: 1
o. O1O ury,Irr
Dilution Factor: 1
0.020 mg/L
Dllut.Lou Factor: 1
O. O15 frgtll
DLlution Factor: 1
ae/26-oe/2s/os
oe/26-oe/28/CIs
oel26-oe lzsl os
as/26-os/28/as
oel26-oel27l os
HKE3 O1AO
HIG3 O1A1
Effi3OIA2
HKE3O1A3
HKETOTAI)
sw846 6010B
Analygls Time..: 13:41
sw845 50I-08
Analyeie Tlme..: 13:41
sw846 60108
lnalysis Tirue. - : 13 :{1
sw846 60108
Analysls Time. . : 13 :41-
srr846 50toB
.Anal-yeie fime- - : 7-9'.29
Prep Batch #---: 5269495
Mercurlr ND 0 . 00020 rrg /T,
oilutl-on Factor: 1
IUIE (g) :
sw846 747AA Og/3a/os
Analysle Tl-me. . : 17 : O5
HI(83 O1A4
B Brimrcd rcsufi. Rc$lt ls l€ss trrn RL,
, Mdhod bldnk contrmlnrtion, The essodrted morhod blsr* coilllm dtc targct analytc at r rqrrtablc lovcl.
[: Sriad duution of e dLessa in lho anrlytic.l b.ldr iD.tic.r.s ah$ ph]dcrl srld chcrnlcal lnrcrfaurccs arc prccnt.
STL Denver 1B
Iot-Saq[e #---3
Ilate Saq)I.ed---3
HARAMETER
IIRS Corporation
ClLent Saryrle ID: cr-8W92-O9I-2O5
Genera-I eheniatrT
Work Order *.--: HICE3Q
Ilate Received,- - 3 09 / L3 / os
D5r1301e8-002
as/Lz/os oB:oo
REST]IJT RL T]NITS MEfiIOD
o - 10 IUo t,Irits srw846 90408pE
.Bmnia Era l5
Chloride
P].uonide
Ititrate
I[itrate-Nl.trI.te
SrrIfatre
..Tota1 Cyanide
rufE (s) :
Dilutlon Factor I 1
o - 10 ry/l'
Dilution Factor: L
J,Q zso rrg,/L
DLlutl.on Factror: 50
O. O10 mg/l'
oLlutlon Factor: 1
Analyel.e ?ime. - : 13 : 59
rtcartll 350 - 1
AnalysLe Tlme. . : O1: O0
HGLrr 325 -2
Analyeie fima. . : 17: OO
r{eAnw 31a.2
Analyeie Tirne. . : 13 : 15
I.IGAHH 353 ,2
.enalygio Tlme. . : 15 : 3O
IICAH!| 353 .2
enalyaia Tlme. . : Ol-: OO
HCtrHr 375 -4
Analyele Time.-: 15:30
sw846 e01aBl9012A
Analyeie TLme..: L2:00
oe lL3l os
oelzBlos
ae ll.s I os
oe ll4l as
oe lLslos
oelzslos
1olo3 /as
ae/21-oe/22/os
s255504
s271c84
s263262
s25757s
5.27L708
s27L6b
5277304
5264s3 9
8-4
5-O
o-18
o-18
620
ND
53OO J,Q zso ng/t'
1-3 J
DllutLon f'Bctror: 1oO
o-1O ry,II-
DlluUion Factor: 1
o - 10 wlt,
Dilution Factor: 1
O.1O Wlt"
Dilution Factorr 1
o
ltatrix----!-'--: GW
PREPARATION- PREP
ANAT,YSTS IIATE BATgH #
RL Roporting Umlt
J Me&od bhnk connrnination. The assoclatod mettrod blank contains the targa analyte rt a reponabtc level.
a Elevated reporting timit. The repordnS limit in elrevrrcd drlo o high anetyre levels.
STL Denver
o
fot-Sal4fle *- - -:
Date Saq)Ied..--!
PARAMETER
URg Corporat'lm
Client sarylle rD: Gfl-Bro1-o9r"2o5
Glenera1 Chemtetrlr
Ilork Order #.-.t HKE3W
Date Received- - 3 a9/ 13/05
Itiatri:ro, . o o . - - . i GW
PREPAR'ATION-
ANATJYSIS DATE
D5r130L98-003
ae/r2/ os t 1: t 5
REgUIJT I]NTTS METHOD
pE
Amonla aB N
Chaoride
ELuoride
Nitrate
Ititrate-!Sitrite
Su]-fate
Total C'1ranJ-de
Nqtts(s):
8-1 0-L0 lto uriLe
oilution Factor: I
6-9 O-1o ry,IL
DLlutton Factorr I
11o0O J, Q 25O ryIlL
Dilution Factor: lOO
O-71 if O-1O ng,IT'
DLlutiou E'act,or: 1
A -L7 O - 10 ngll'
Dilutlon Factor; L
A-L7 O-1O rg/n
DLlutlon Eactor; 1
21OO t, Q so0 trq,/L
Dilution Factor r l"OO
ND O, 010 ng/t-'
Dilution Factor: 1
s:Ir845
Analyais .
I'iCAm
Analysie
TrcATlII
.Bnalygie
}TCAIIII
Analyole
ITTCBXTTT
enalyele
'- ueaxllr
Analysls
HEAI|IT
nnalyeia
sw846
Inal-yeia
eo40B
Time. . ;
350-1
TLme. * :
325-2
Tl-me. . :
344 -2
Time . -:
353 -2
TLme. . :
353-2
Tl.mg. . ;
375. {
Time..: L5;30
eoL oB/ 9012A
Time. -: 12:O0
oell3 los
1{:00
oelzslos
01: OO
oellslas
1.7;00
aelLdlos
13:L5
oef L3 /as
15:30
oe/zBlos
01: O0
PREP
BATCH #
52s6s04
s27I48,4
s263262
52575'19
527L?f,4
527L68.5
52773o,4Lol 03los
os / zt-og / 22/ os s264s3e
RL Reponing Umit
t' Mcthod blank oontamlnarloo. Tho aercciatod rndrod blank conuains rhc urjct analyrc at a reporteble level.
a Elcvatod reportiry timit. Tho repordng limit is olovated duc lo hlgh analyto levcls.
.
STL Denver 2A
' Iot-saqple S- - -:
Date Saryrl-ed,---!
PARA},IETER
IIRS Corporation
Cl.ient 8aq>1e II): Gtr-BfA2-0912O5
Gleneral. Cheuietrlr
f,ork Order #. - -: HKE30
Date Recelved--3 a9 ll3/a5
I{atrlx,o-,,.--.-3 GW
PREPARATION- PREP
ANATYSIS DATE BATCH #
Dsr130198-004
oe/r2/os L2:22
RESIIIJT RI-r IINITS METTIOD
BE
Amnia as It
ChLqrlde
ELuoride
Nitrate
Ilitrate-IIitrite':
Su].fate
Tota1 Cyanide
nsrE (s) :
8.4 O-1O ilo rhits SlY8t5 gOrOB O9lI,3l05 5256sO.
Dilutim Pactor: L Allalyele Tlme..: 1t:05
5-O O.1O rylt tr@rr 350.1 oglzelos sz'tr(s4
DLlutl.on Bactor: 1 AnBlyale Tirle..: 01:0o
ssoo ir,O 25O rglt' llcAxlr t25-2 Og/aAloS 5263262
Dllutl@ Pector: 1O0 InqlyElB rirnc--: 1?.0O : '_.
:1-2 r o-1o rglt lmnr 340-2 oglt*los s2575'Ie
Dilutiotr Pactor: 1 Analyois Trre.-: 13:15
o-99 O-1O rylt, rNeiB[f 3s3.2 OglI3lOS s2'rlroa
Dllution paetor! 1 Analyeia Tirnc.-: 15:30
o-ee
"r...Ll?" ,r"ylr" ffi il1:1, o.,oo
oglzalos szzre!
650 ir,o 1oo rylt rrctrf, 3zs-{ tolollos s277:to1
Dl-IutL@ Factor3 20 Analyele Tlma. - r 16:3O
l{D o.oro r:q,/L sw846 go:-os/solzA o9l21-09/22/os s264539
Dilutim Prctor: 1 ArralyBig Tine-.: 12:00
RL Rcponing Llnrit
I Mo&od blsn}' contrrnination. Thc rssociatcd method blsnk conrrins rbe nrga analyrc at a reponabte lcvcl.
' a Elovstcd rcporting liuit. The rcponing limit is eleyated due to high analyte lovels.
STL Denver
.
2L
O
SAMPIJE#I,IATRIX
o o1_
002
oo3
004 GTi
G}T
GTI
GW
GW
GW
GW
GVT
GVI
G}T
GW
GW
acDATAAS.SffiONW
D5r130198
Sample Preparation and Analysis Control Numbers
wQ
AIVAIJYTICAI
METTIOD
sw845 82508
MCAWW 325.2
MCA$IW 340.2
MCAIIIW 353 - 2
MCAWW 353 .2
sr{846 9010E/ 90L2A
sw845 6020
sw846 7 47 AA
sr{845 9 04 0B
sw846 82508
sw846 6 0108
MCAWW 375,4
I,ICAWW 350. L
MCAWW 325.2
MCAWW 340 -2
MCAI{T{ 353 .2
MCAIIIW 353 .2
9T1846 90108/ 901-2A
swB46 6 02 0
sw845 747A4
9w846 9 04 0B
sw846 82608
sI{845 5 01_ 0B
MCAVIW 375 .4
MCAWW 350.1
MCATSW 325 .2
MeAlIIt 340 .2
MCAI{I{ 353.2
MCA$IT{ 353.2
sw845 901AF/ 9012A
sw845 6A20
8r{846 7 47 0A
sw846 90408
sw846 82608
sw845 50108
I,ICAWW 3 75 .4
MCAWW 350.1
LEAgH
BATCH #
PREP
BATCH #
5268077
5263262
5257s7e
s271" 6I5
527 1708
526453 9
5265554
5269496
s2s65 04
s26gg77
5256567
52773A4
5271494
s263262
525757 9
s271- 6 B s
s27 1708
5264s3 9
5266s 54
s269496
s256s04
s268 077
5256567
52"17 3 04
5271{84
s263262
s2s7 57 9
527J.6I5
527 17 0B
s254s39
s265564
s259496
5256504
5268077
s266s67
s277304
s27 14 84
MS RT]N#
5268 014
5263 L7 0
5258ls9
527 L43 s
526434 0
52663s0
s27 0L20
s263092
s268 014
5266352
52771,77
527L326
52631.7 A
52581s9
s27 143 s
525434 0
s266350
s27 0L2 0
5263092
5258014
s2663s2
5277L77
5271326
5263 17 0
5258 ].s 9
527 143 5
526434 0
5265350
5270120
5263092
5268 014
s266352
5277L77
527L326
o
GW
clw
GW
G$r
GTT
GTI
GIII
Gtvf,
GW
GTT
GViI
GW
GW
GW
GTV
G}I
GTT
GW
GW
GW
G[il
GW
G$T
GW
STL Denver 22
Cliut tot *--.: D5f130198
IIB Lot-gaqfle *: D5I250000-O't7
Anal"ysis rlate- - : 09 / 2L / oS
Dl].utl"on Factor: L
PARAMETER
Chloroform
gT]RROGATE
I{ETEOD BIAilK REBORT
rc/w vol.atil-ee
Hork Order *---: HITDHE1AA
Prep Date., o o ?,: o9lzl/05
ep Batch $---: 5258077
Uatrl-x,o,.r r i.. -- 3 WATER
AnalysI.e timc.-3 09:04
METHODRBSULT
REPORTING
I,IMIT T]NITS
D lbromo f luor ome tha,ne
L, Z-Dlch1oroethane - d4
4 -Bromofluorobenzene
Toluene-d8
rufB (s) :
ND
PEREEhIT
RECO\IERY
1,00
91
1,0 6
10s
1- o ug/L
RECO\IERY
LIMTTS
(tt r.L8 )(ez t2I)
(zs 1r8)
(tt 117)
sw846 82508
Cdculuioru are performed bofore rounding to rvoid rourdoff errors in colculated resrrlm.
STL Denver
O
W COFISO[r SAUPITE EIDLUATION RBBORT
Gc/t{s vo}atl-1es
Clierrt lot, *. - - 3
rcS I0t,-Sary>1e*:
kep Datg---.--3
Prep Batch *. -.:
Dl-IutLon Factor:
PARAMETTR
D5I13 01-98
Dsrzs0000- 477
oe / 2L/ as
s268A77
1
[ork Order *- -
Anal.yals f,)ate-
Ana-lysia TLme-
PERCENT
RECOVIERY
HLDHElAC
oe / 2L/ os
OB :2-l
rratrix- ! -, o. ---3 VIATER
1, I.-Dlchloroetlrene
Ben-zene
Chl.orobenzene
Tof"uene
trichloroethene
gURROGATE
D ibromof 1 uorome t hErrre
L, 2-Dlchloroethane- d{
4 - Brorno f luorobenz ene
Tol-uene-dB
10s
95
106
110
97
RECO\TERY
LIMfTS
(so I.32l
(zs Lzo)l
(ze 1r.8)
(zs 118)
(tg Lzz)l
PERCENT
RE-C.O-\IERY
98
92
97
99
II,IETHOD
EW8{6 82508
sIIr845 82508
sr8{5 82608
s'[846 82608
sr846 82608
RECO\'IERY
LIMITS
(zt 118 )(62 LzBl
0a 118 )(tt 117 )
Calfllatloos &re pcrformed bsforo roundlry to avoid rourd-ofF errom in ctlculttrxl re$ln.
Bold prlnt denorx control parem$ers
STL Denver 24
o
ffi CCI[f.lROIr SIIIPLE DAIA BEFORI
GC/HS Volatiles
Work Order *-CLIent fot $- -.:
ICS Ipt,-Saqrl.e*:
Prgp Datg.,,.--3
map Bat& *-. -:
Dil-ution Faetor:
PARAMETER
I-, I.-Dichl"orcethene
Beu,zene
Chlorobenzene
To1ur=ne
Trich].oroetbeue
.
SI}RROGATE
Uatri;r! - --.o-. - 3 I{ATER
PERCMIT
RECOVERY MEfiIOD
D5I13 0198
D5r250000 - a?'r
og/zt/os
5258077
1_
Ana-IyBLB
Ana-I-ysis
SPIICE
AI,IOIIT{T
10, o
10-o
10-o
10-o
10-o
HIJDHEI.AC
ae/2L/as
AB :27
I)ate-
Tire.
MEAST]RED
AI{OT'NT
10-5
9-{g
10-5
11- O
9.59
PERCMIT
RECOII,ERY
98
92
97
99
UNITS
u.glt
u.glr,
I4I/I,
urglr,
ug/L
RECO\IERY
LIMfTS
ros
95
1(}6
110
9-I
sw8e5 82608
gr8a5 82508
sH8{6 82508
sH8{5 826()8
sr5845 82608
Dibromofluoromethane
L, 2- Dichloroethane - d4
4 -Bromofluorobenzene
Toluene-dB
IwrB (s)
=
(tt 118)(sz 128 )(ta 118)(tz 117)
oCalcrrluion$ arc perfornrod bcforc roundrry ro avoid round-otT errors in calorlated rmrlr.
BoId print denotes conrot parnmcrers
o
STL Denver
o IATRItr SPIXG SAI{PIiB E'TAI,InTIOTT REFORT
ef.lur vol.at,il-es
gl-l-ent Iot #- - -:
H8'Iot-Sarqrl.e *:
Date SarryIed.--i
Prep llate. - - - - - 3
kep Batch f- -,:
Dil.ution Pactor:
PAIUWETER
D5r13 0 r_98
D5r130198-004
09/L2/aS L2=22
ae/2L/as
5268A77
L
Ilork Order *. . . 3
Ilate Recelved. - :
Analysis Date- -:
ena-lysis Time- - 3
HKE3 O1C5-MS
HKE3 O1C7.MSD
ae/13/as
as /2L/ 05
1O:39
GW
PERCENT RECOVERY
RECO1TERY LTMITS
RPD
RPD LTMITS T.{ETI{OD
1, I.-Dichr.oroetlreue
Benzene
&]'orobeuzene
Toluene
afichloroethene
St]RROGATE
Dlbrorno f I uo rome t, hane
' I, Z-Dichloroet hane- d4
4 -BromofLuorobenzene
Toluene-dB
rurts (8) :
93
100
9(l
1(t0
99
100
96
95
88
92
(eo r.32)
(55 132)
( zs 1-20 )(ts 120)
(zs 118)
Oa 118)
(zs 118)
(78 118)
(7e a22l
l'tg L22I.
PERCE TT
RECOVERY
90
98
87
95
98
94
93
90
7 -L (O- 251
10 (o-21)
o - 39 (o-20)
o .52 (0-221
+ -2 (O-23)
RECO\IERY
IrIMIfg
(tz 118 )(tz rL8 )
Gz 128 )(62 128 )(78 118)
(ze 118 )(tz LL7\
(77 1_r.7)
9H846 826(}8
sr845 82508
sH846 82608
srrS{5 82508
sH845 82608
g11846 82608
sH846 82508
sw845 82508
sH845 82608
sw846 82608
o
Crlculadons are performed before rounding to avoid rorrnd<ff errors in calculeted results.
Botd print dcnotcl control paramctcrs
STL Denver
C1ient f.ot *-. . i
Ug lot,-8a4t1e *:
Date gary)Ied-.-3
kep llatsgoo----l
Prep Batch *- . - 3
DilutLon Eactor:
PARAI{ETER
1, l-Dieh-l oroetiene
Benzene
ChI.orobenzene
Tolueue
lkichloroethene
SURROGATE
Dlbrorno f }uoromet hane
L , Z-Dlchloroettrane- d4
4 -Bromofluorobenzene
Toluene-d8
rufB (s) :
SPTI(E MEASRD
AIT'IT AII{OI,NT UNITS
PERCITT
REC\IRY RPD METHOD
IAT?IT SPIXB SAXPTA DilEA REPORT
@,ltrs Volatfleg
D5I130198 sork Order *--. : HKE301C5-MI} HatrJr--------.:
D5r130198-004 HICE3o1C7-MSD
og/tz/os L2:22 Date Recci\rcd--r a9/L3/05
og/zt/os lnar-ysie Date- -z a9/2t/os
5268077 .enalyeie Ti.ne- - : 10:39
I
SAIYIPI,E
AIVIOUMT
IID
ND
ND
I5D
IID
ITD
ND
IID
IID
ND
10 -o g -35
10-o 10-o
10-o 9-o4
10-o 10-o
10-o 9-93
10- o g- 96
10-o 9-63
10-o 9-59
10.o g-94
10-o 9-22
PERCENT
RECOVERY
90
98
87
9s
98
94
93
90
ug/t
Urg/r,
utg/t,
urglr'
rutglt'
utslr,
ruglr,
lug/n
u.g/l'
ltrglt
93
100
90
100
99
10(}
96
96
88
92
RECO1IERY
IrIMffS
sr846 82508
? -L 91846 82608
g11846 82508
1(} 811846 82508
grr8{5 82608
o - 39 5'H8d6 82508
sr846 825(}8
o.52 S1846 826(}8
s'r846 82508
4 -2 511846 82608
o(zt 1L8)
(zE 118)
(az 128)
(az 128 )(za 118)
(za 118)
(77 LL1 |(tt 117 )
Calcuhtions etG performed before roundlng to avold round-ofif erronr In catcularod resultc.
Bold priut denotcs control par:rmercrs
STL Denver
I'HIEOD BLENK REBOBIT
IIUDAL ltetals
Cl.Lerrt Lot
PARA!!ETER
Dsr13 0198
RESTILT
REPORTING
LIMIT UNTTS
*- -;:Dlatrlx- - - ! i r r or! WATER
PREPARATION- WORK
ATIIAIJYSIS DATE ORDER}[ETHOD *
lrB rot.-sary)le
Cadmium
*: D5I230000-564 Prep Batch #- . . l
ND O.0O1O mglL
Dilution Factor: L
Analygis Tinre. . : O2 : 58
ND 0. 0O2O mg/t
Dilution Faetor: 1
analyeis Time..: 02:58
5266564
sw846 5A2A
sw845 60108
sw845 50108
sr846 60108
sw845 601,08
sw846 50108
sw845 60L0B
sw846 60108
os / 25 - 0 g / 28 / os Hr,cEFlAC
ae /26 - o 9 / zs / os Hr,eEFlqA
a9 / 26- Oe / 2t / OS HT,CEKIAC
oe / 26 - o e / 28 / as HrrcEKlAD
os / 26- os /zs I as
ael26-ael2zlos
ae / 25 - os / ze / as I{rrcEKlAF..
os / 26- os /2e / os HLCEKLAG
oe / zg- 09 / zg / os Hr,cEKlAr{
HrcEK1AJ
Selenlum
Areenic
'
Barium
:..
Calcl-rrnr
Chromlum
Copper
Iron
Lead
:. .'
.:
o
sw84 6 502 0
fB Iot-Saqlle I: D5f23OOOO-557 kep Batch *- - -: 5266557
Alumlnum t[D o.1o ns/t sw846 60108
Dilutioa Faetor: 1
Alllyaie Timc-.: 18:{3
o-o3g B
ND
ND
0 - 01-5 mg/L
DLluElon Faetor: 1
Analyele Tlrre. . : L1: {5
0 . 010 ng/t-,
Dilutlon Factor: 1
Analyeie Time.,: 11:45
O - 2t} mgll
DLlutlon Factor: 1
Analygis Time. . : 18 :rl3
O . 010 nlg/T,
DLlutiou Factror: 1
AnaIyEiB Tine..: L1:{5
0. 010 fi.q,/T-,
Dllutrlon Factor: 1
Analyele Time..; 1L:{5
0 . 10 mg/T,
DLlutLon Factor: 1
Arralysls Time. . : 1.5 ; {5
0,0030 ng/n
Dilution E'actor: 1
Analysie Time. . : 11: {6
(Continued on next
ag lz6 - oe lzs I os
2BSTL Denver
}TD
page)
HETEq) BI,hITT REPORT
TCIHAIT lteta]-e
Cll-eut t-ot #.--! D5I130198
PARAMBTER RESIII,T r-,rMrT UNITq
Iiatrl-x-: WATER
PREPARATION. WORK
AIiIAT,YSIS DATE ORDER #
REPORrING
!,IBTHOD
MagineeLum
NlclceI
Potasslum
gLlver
Sodiurn
VanadJ"um
ZLnc
zLrconiurn
.
llB Lot-Saryll.e
Mereurlr
rurts(s) :
ND
IUD
ND
ND
ND
ND
o -20 mg/L
Df-l-ution Factor: 1
Analygle Tlme. .: L8;{3
0 ,040 mg/L
Dilution Factor: 1
Analyois Tirne. . : 11 : 45
3.0 ftg/L
Dilution Factor: 1
Analysl"e TLme. . : 18 ;43
O. oO50 ng/I"
Dilution Factor: 1
Arralyel,e TLme. . : 1,1- : {6
5. o mg/L
Dl-Iut.lon Factor: 1
Analyal.e Tine. . : 18: {3
nL].utlon Factor: L
Analyeia Time. -: 11:45
0.020 fitg/L
Dl,].utl-on Pactror: 1
Arralyele Time, . ; 11: {6
0 - 015 ntg/L
DLlutlon Factor; 1
.Rna1ysle Tlme. . ; 18 :a3
0.010 mg/t sw84 6
sw845 50r"08 ae / 25- o e / 27 / os HLCEKIAQ
sw846 501 0B 09 / 26 - o e / z8l05 HrrcEKrAH
sw846 5 01_ 08 ae /26-ae /27 / os HLCEKlAP
9w846 6 0108 09 / z6-a9 / zB/ as HTJcEKUAA
sw845 60108 a9 / 26 - 09 / zr / os Hr,eEKlAR
6 01_ OB 09/20-oe/zslos HLcEK
sw84 6 501 0B oe / 26 - oe / zB / os HLcEKIAL
#: D5I260000-496 Prep Batch *---: S26g4gG
ND 0 , 0oo2o rng/L sw84 6 7 47 AA
Dilution Factor: 1
Analysia Time..: 15:52
sw846 60108 09 / 26 - 09 / 27 / as Hr,,cEKI-AT
oe/3a/os I{LFTzlAA
IID
Celcrrlatiotls rre porfonncd before rounding ro rvoid round-off orrors in crlculrpd rssuhs.
B Estirnatd result. Rcsult is lccs than RL.
STL Denver
O
ffi COIITROL SAHPLB SUALTBTION REPORT
TCIE[Ir lttetal.e
Iot-Baryll.e *. - . 3 D5f130198
PARiAIvTETER
Cadrnl-um
PEREEMT RECOVERY
RECO\IERY IJTMITS RPD
RPD
TJTMITS
( eg 11r. )
(gg L11) O.3L (O-201
Dilution Factor: 1
(az 114 )(az 114) 0.97 (O-20)
Diluuion Factort 1
(ae 108)
(eo 108) 1.4 (O-20)
Dl-lution Faetor I L
( eg roe)(eg 10e) o. g1 (o-20)
Dilutlon Factor: L
(e3 113)
( gg LL3 ) 1,5 (O-20)
nilutl-on FacLor: 1
( ag 110)
(sg 110) 1.6 (o-20)
Dilutioa Faetor: 1
(sg 112)
( 89 LLz) o - 88 (O- 2ol
Dilutioa Factorr 1
( ae 110)
(85 110) L.2 (O-20)
DLlutlon Factor: L
(ea 110)(se 110) 4.s (o-20!.
Dilution Factsor: 1
( 91 1, L1)
(gr 111) o.e1 (o-zol
Dil-ution Factor: 1
METHOD
sw845 6020
sw845 6024
eualysig Time.
sw846 6020
sw846 6020
AnalyeLe Tlme,
sw845 50L08
sw846 60108
enalyeie TLnne.
sw846 50108
sw84 6 6 0108
Analyeis Tlrne.
sw845 50L08
sul845 50108
Analysls Tlme.
sw846 60108
sw84 5 6 0108
Analysls Time.
sw846 601_OB
sw846 50108
Analyale Time.
s$r8116 50 L 0B
sw845 50108
Arralysie TLme.
sw846 50108
sw846 50L08
Analyel-e Tlme.
srf84 6 6 0108
sw846 60108
Analysle Tl-me. . :
I{atrl.:rr--------
PREPARATION-
AMITYSIS DAIE
ae/26-oe/2s/os
ae/26-oe/zs/as
11:51
ae /26-ae /27 I as
oe/2G-oe/2t/as
LB 247
: WATER
PREP-
BATCAI #
5265 s6 7
5266567
5266567
s265567
Selenium
A]-uminum
.
ArsenLc
Chromium
Copper
Iron
Lead.
94
95
89
90
t02
L04
99
99
1- 03
L04
LA2
103
95
95
l- o5
1_ 06
105
L01
96
97
ae /zo-o e /28 los s266s64
ae /26-ae /28/ os s266s64
: 03 :02
a9 /26-oe I 2a / os s266s54
09 / zt-oe I zB/ as 5265s54
O3tO2
ae / zr-ae / 27 / os s266567
09 / z6-oe / 27 /as sz;6s57
I"8;{7
a9 /26-oe /zs/ os sz65s67
09 /26-ae / zB/ os s256s57
L1 ;51
O
BAT
Calcium
oe /26-Ae / 28 / as 5266s67
oe /26- oe / 2a / as sz6;s67
1-1r 51
ae/26-ae/28/05
ae/26-oe/28/os
Ll:5L
oe/28-oe/2e/05
ae/28-ae/2e/os
15;49
sz65s 5 7
s266567
5266567
5266s67
ae /26-oe /zs/ os s266s67
,r:;/
z6-oe / zB / os sz66s67
STL Denver
(Continued on next page)
30
ffi OOIIIROL SEUPT,B EI':AIJIBTTOil REPiORT
IUIAfT Heta-ls
Iot-gaqfle *. - - 3 D5I1301,98 liatri-x-. -. f O- --3 VIATER
PARAMETER
Magrresium
NickeI
Potassium
gilver
Sodlum
VanadJ-um
Zinc
zl-rconium
rwrB(s):
PERCENT RECO\IERY
RECO\TERY IJTMITS -99
101,
96
97
1_ 03
1.05
101
102
103
105
98
99
88
89
L07
109
RPD
RPD IJIMITS
( 91 111)
(gr 111) 1,8 (o-zal
Dilut,ioa Factor: 1
(go 1L0)
(so 110) 1.3 (O-2A\
DLlutLon Factor: L
(eo 1r1)(86 111) r-e (O-2A')
DilutLon Factor: 1
(ss 114)
(gs 7L4) 1. s (O-20)
Dilution Factor: L
(gr 112)
(gr LLz) 1. a (o-2o)
DLlutLon Factor: L
(ss LLz)
(gg LLz) 1.1 (O- 201
Dl-].ution Factor: 1
( ss L10)
(es 110) 0.91 (o-201
Pllutlon Factor; -1
(zs Lzs)(zs Lzs) 1 .8 (O- 201
Dilucion Factor: 1
METHOD
PREPARATION-
AIiIAITYSIS DATE
PREP-
BATC}I #
5266567
s266567
s266567
5256567
s266567
5266s67
sw845 60108
sw845 60108
Rnalyeie Tl-me.
sw84 6 6 0108
sw845 50L08
Analygie fl,rne.
sw846 60108
9w846 60108
Aoalygis Tl,me.
sw845 60108
sw846 60r_08
Ana1yal,e fime. - :
sI{84 6 601 OB
shrg{6 60L08
Analyel-a Tlme. - :
SI^I846 60108
sul846 50108
Analyaio Time. , :
sw846 60108
sr{84 5 60108
Analyele Tlm€. . .-
sr{846 50108
slr84 5 60108
Arralyela Tl-me. - :
oelzo-oe/27los
oe /26-oe /2t / os
18: lt7
oe/26-oe/2s/os
oe/26-oe/2s/05
11:51
oe/zG-oe/27/os
as/26-as/27/05
18:47
oe /26-09 / 28 / os sz66s67
ae /26-oe /28/ as s266s67
11 : 51.
as /2d-o s /27 / os sialslT
ae /zG-o 9 /zt / as s2 66s67
L8:47
ae /zG-o 9 /2s/ os s26656'l
a9 /26-oe /zs/ os sz66s6z
11: 51
o
ae/26-oe/28/as
oe/26-oe/28/as
11: 5L
oslzo-os/27/os
og/26-oglzt/as
A8:47
5266s67
s266s67
5266s57
5266s57
Calculations &re pcrfonncd beforo rorurding to avoid round-off crrors in calculated results.
o
STL Denver 31
ffi COIWROL S;AITPI,B I}ATA RBFORT
TCIDAL Heta].s
Iot-Saryile *-
PARAIUETER
Cadml-um
SelenLum
Aluminun
Arsenic
Barium
Caleium
Chromium
Copper
fron
Lead
: D5I130198
SPII(E MEAST]RED
AIT{OUITT .A},IOUMT UNITS
PERCNT
RECIJBY RPD IvIETHOD
uatrix- - - - - - , - - : IiIATER
PREPARATION-
ANALYSIS DATE
PREP
BATCTI #
o.0400 o-0377 lf,f,tg/L 94
o.o{00 0.0379 mg/L 95
Pllubion Factor: 1
sr{846 6020
0.31 SW846 6020
Analyeis Tima--: O3:02
sw84 5 6420
0,97 SWg45 6020
Analyale Time..: 03:02
sw84 5 6 0108
1.4 9W845 60I_08
Analysle Time.-: 18:47
sw84 6 5 0108
0.81 sW846 60108
Arralyeie Time-.: 11 :51"
sw84 6 5 0108
1-5 SW845 50108
Ana1.yal-a time. . : 11: 51
sw846 60108
1.6 9W846 60108
Alralysis Time,.; Lf3:47
sw84 6 6 0108
0.88 SWB45 60108
Analyeie Tjme.-: 11:5L
gB[84 5 6 0108
L .2 gr,il84 6 5 01_ OB
Rnalyels Tl-me. - : 11 : 51
9w845 50108
4,5 9W846 60108
Analyels Time. . ; 15 r{9
sw845 501,08
0 . 91 SWB4 5 601_08
Analyeie Tjma..: 11:51
oe / 26-oe /zB/ os s255s64
ae / 26-oe / 28 / as s266s64
oe / z6-a9 / zs / os 5256s5r1
oe / 26-ae / 28 / os 5266s64
oe / 26 - 09 / 27 / os s266s67
a9 / 26-oe /27 / as 5266s67
ae / z6-ae /za/ as s266s67
ae / 26*os / zs/ os s255s67
os / 26 - os / zs / os s266s67;
oe / z6-oe / 2s / a5 s256s67
os /26-os /27 /os sz66s67
os /26-as /27 / os s266s67
09 / 26-ae /28/os s266s67
oe / z6-ae /zs/ os s266s57
:
oe / 25-oe I 28 / 05 s266s67
oe I 26-oe /zs / as sz66s67
ag / zB - as / zs / as sz6ls67
ae / zr-oe / ze / as sz66st7
ae / z6-oe lzs/ os sz66s67
oe / 26-oe / 28 / os s266s67
o.0400 0.0357
o.0400 0.0360
mg/L Be
nq /r. 90
Dilution Factor: 1
mg /T' Loz
ntg / r, i- 04
oilut,ion Factor: 1
2.AO
2 .00
2.00
2.00
2.00
2-00
50,0
50, 0
0,200
0 - 200
0.250
0 .250
1.00
1.00
o_500
0.500
2.05
2.08
L .97
L-99
2 .45
2.09
50,9
5L.7
ms/t
mg /t'
Dilutlon
mg /T.
mg /t'
oilution
99
99
Factor: 1
L03
1_ 04
Factor: 1
mg/T' Loz
mg/r" 103
Dllutlon Factor; l"
0.190 rrq/I'
O -1,92 mg/U
DiI-ution
a.262 nrg/t
0.255 mg/L
Dilution
1.05
L-01
0.48L nig/L
0.486 mg/r,
Dllut,Lon
95
96
Factor: 1
105
105
Factor: 1
mg /r, 1os
mg/r, 101
Dilution FacEorr 1
96
97
F'actor r L
STL Denver
(continued on next page)
32
ffi C0IFI?O[, SAIiPIIE DATA, REFORT
It0tf,Alr Ueta-La:..
Iot-8aryll.e *-
PJHB$YIETER
Magnesirun
NickeI
Potassium
8lIver
Sodiurn
Vanadium
Zlnc
. ZLrconium
nCrrB(a):
MEASURED
AIUOUMT UNTTS
3 D5f130198 Dtatrh- - - - - . - - - : WATER
PREPARATTON-
AI{ALYSIS DATE
gPIKE
A}IOUIIT
50. O
50 .0
o .500
0.500
50 - 0
50.0
0 - 0500
0. 0500
50. o
50. o
0-500
0,500
o. 500
o .500
0 .500
o.500
PERCNT
REC\I-RY RPD METIIOD
PREP
BATCH #
49.7 ry/t
50.5 mg/l'
Di].ution
0.479 firg/T'
O ,485 mg/L
Dilution
99
r.0 L
Factor: l-
96
97
Factor: 1
rW /T-, i- 03
mg/L Los
Dilution Factor: 1
gw84 5 50108
1.8 SWB45 60108
AnalyaiB Time,.: L8:47
sw845 50L0B
1.3 SW845 50108
AnalysLg Tlme..: 11:51
sw845 5 01_08
L.6 sw846 60108
Analysl,s Tfune. . ; 18 :{?
sw845 50108
l--5 sw845 50108
Analyeie Tl-me. . : 11: 51
sw845 50108
1.4 SW8{6 60108
analysl-e Tl-me. . : 18 : 17
sw8{6 50L0B
1.1 SW846 60108
Analyaie Time. . : 1L : 51.
sw846 60108
0,91 9w845 60108
.nnalyeig Timo. . : 11 : 5L
sw846 60L08
1.8 SW846 50108
Analysls Time..: 18:47
oe / 25-09 / 2t / oS s265s57
oe /26-0e /27 / as s266567
oe /25-oe / 28 / Os s266s67
CIe /26-09 / 28/ os s266s67
ae /25-oe / 27 / os s256s57
oe /20-o e / zt / os 5266s67
ae / 26 - oe / za / os s256s67
a9 / zo -o e / zs / os 5266s67
Z:,i:Z-3;',',1lHZ:le:;b
as / 26 -o s / 28/ as s266s67
ae /zr-oe /28/ os s256s67
oe / 26 - os / ze / os sz66s67
ae / 26 - a9 / 28 / os s266s6'l
os /zG-o s/zt / os 5256567
oe/26-oe /zt /as s266s67
51 .6
52 .4
0 . 0504
0 .05L2
51-7
52.4
mg /l'
ms/r'
Dilut lon
mg/t
nrg/I'
Dilution
0.49O mg/f'
0 .496 mg/L
oil.ut,ion
0.439 rW/T.
O .443 nlq,/t
DLlutLon
0.535 mg/t
0.545 mg/t-,
Dl.IutLon
101
LA2
Factor: 1
103
1-O5
Faetor: 1
98
99
E'aetor;
88
89
Factror:
107
L09
Factor: 1
Calculations are performed beforo rounding to avoid round+ff errors in calanletod resutts.
.
STL Denver
o
o ffi OUfm,OL gAltPLB E\IBIJBTIOIV REBORT
IlCff,Afr Heta-ls
:gtient IJot *--.: D5I1-30198 llatri:r- - - - - ! -,, 3 WATER
PREPARATION-
AI{IATJYSTS DATE WORK ORDER #PARAMETER
I'CS fot-garqrl.e*:
Mereury
rsqrB (s) :
PERCEI{IT RECO\IERY
REeOrr,tsRY LIIIITS METHOD
D5f260000-496 Prep BaLch #,
9B (8S 114) SW846
Dl-lutlon Factor: 1
a9 /30 / os HTJPTzIAC
TLme..: 15;5{
. - 3 5269496
7{7 AA
Analyels
Calorlations anc performed bofore rouruting to avold round-off errors In calctrlatcd rcsults.
STL Denver 34
W COIrI?OL $BUPLE DATA REORT
fCIf,AL lletal s
C1ient Iot *-. - 3 D5fL30L98
SPTKE MEAST]RED
PARAITTETER AIv[OI]I\[T AIvIOI]NT UNITS
PERCMT
RECVRY METHOD
llatrix. o . - o . - - . 3 WATER
PREPARLTION- WORIC
ANAIJYSIS DATE ORDER #
fCS lot-Slary)Ie*: D5T26o000-496 Prep Batdr *-
Mercury 0.00500 0.0049I. mg/T, 98
Dilution Factor: 1
IrcEts(S}:
: 5269496
sw845 7470A
Analygie Tl-me -
0e/3a/0s HLFT2LAC
15: 5{
Celolations are porforrned bcfore rounding to rvold ro,undoff efioro in calculaed results.
O
STL Denver
Cl-ient Iot *---3 D5f13Ol-98
, DaEe Saryll.ed- - - : ag / zZ/ As 13 : Oo
PAIUUYTETER
PERCETUT RECO\IERY
RECO\IERY TIMITS
lHttIf,' SPfre SADiPITB BIfAITIBTIOI5 REFORT
TUxhL uetal.e
Date Recelrred- - 3 A9 /22/ 0s
RPD
RPD LTMITS METHOD
frfatri:r- - o . - o, . . ! tIATER
PREPARJATTON- WORK
A}IALYSIS DATE ORDER #
IriS lot*8aqll"e *:
Cadml-um 94
90
DsI220342-001 kep Batch *. . .; 5266564
(89 111) SW845 5020
(89 11-1) 3-a (0-20) Sw846 6020
Dilution Pactor: 1
Analysie Tirns-. r 03:20
(az 114) sw846 5020
(az 1141 2 -4 (0-20) SW846 6020
Dl-Lutioa Faetor: 1
AnalysLe Timc..: O3:20
oe / 26 -o 9 / 28 / 0s HK68cl-As
oe /26 - o e lza / a5 HKEBcI-A6
ae / 26 - oe / 28 / os HK68C1A3
oe /26-0 s / za / as HK68c1A4
ae / 25 - o e / 2a / 0s HK6sCxar
ae / 26- o e /2a / as HK68c1-AU
os / 26- o s /za / as Hr(6scr.Av
ae / 25- o e / 28 / as HK68C1AW
09 / zG-o 9 / zs / os HKGScLAI
09 / 26- oe / zB / as HKGsclA2
ae / 26-0 e / 2a / os HK68c1,Ax
a9 / 26-09 / 28 / os HKsscrAo
l,!8 lot-Saqrl.e *: D5f22O342-AOl Pr:eI, Batdr *---r 526656'1
Areenic 93 (84 - 12rt) SWg46 60108
91 (84 - 124) 1.8 (0-2s) SW846 50108
DlLution Pactor: 1
ilaalyele lime.. : IZ:11
Selenium
ChromLum
rcrE(s) :
72N
69N
95
9s
97
1_ O3
89
g7N
(ss 120 )(85 LzA) O.2A (O-zs)
Dilution Factor: L
Analyaie Tirne. . ; 12 : 11
(zg l_3s)
(zr r3s) 3-6 (o-zs)
DiluEloa Factor: 1
Anal.ygia Tlme. . : L2; Ll.
(ag 121)
(89 LZt) 1.7 (O-25)
Dilution Factor: L
Analyaie Tlme..: 12:11
s$I845 5 0108
sw845 50108
sw8115 60108
gur846 60108
sr{84 6 60108
sw846 60108
O
calcutrrlono &rro porformod bcrbrp rountling to avold round_off error8 in cslcul8ted nxille-
. N Spikcd analyte recovory is outsrdc stsrod control limis.
STL Denver 35
ClLent Iot *- -.:
Ilate Saryrl€d---:
SAI-IPITE
PARAI.,IETER A}dOt]TitT
IATR,IT SPIXB SIAUPIJB DATB. RBPORT
aUItrL lfieta1B
Ilate Receirred- - r a9/22/ os
Ertrft-.-e r,-o,: WATERDsr13 01 98
a9 /22/ os 13 : oo
SPIKE MEASRD PERCNT
RECIIRY RPD METHOD
PREPARATION- WORK
A}IAIJYSIS DATE ORDER #AMOUIm m{ITS
Hg Lot-Saqr1e #:
Cadmium
o - oo49
0. oo4g
Selenium
D5I22O342-OO1 Prep Batdl $- - - 3
O .0400 A , 0{,24 mg/\, 94
0.0400 O,041-0 mg/I' 90
DLlution Fact,or: ]-
Analysis Time. -: 03:20
5266564
sw845 6020
3.4 SVS846 6020
sr{84 6 6A20
2 .4 SW845 5020
5266557
ser846 6010B
1.9 swg46 60L0B
sw846 60108
o.2a sw846 60108
s9I846 50108
3 .5 SW845 50108
sw845 60108
L.7 SW846 60108
oe /zG -o e / 28 / os IIK6scl,As
ae /25 -o e / 2s / as HK58eut5
oe /26-0 e / zalos HK58C1A3
os / 26-o s / za / os IIK6BC1A4
liIS lot-ganpl.e *:
Areenic
0. o0g5 0 .0400
0.oog5 0.0400
0. o{3 2 -oo
0. o43 2.00
D5I220342-001 Prep Batfr
0 . 0 371- nrE /T'
Qualifiers: N
O . 03 63 firg /I'
Qualifiers: N
Pllutlon Factor:
Analyeia Ti:ne. . :
1,9O firg/I'
1.87 mg/I'
Dl}uE,lon Factor:
nnalyeie Tl-me. - :
3 . L5 mg/L,
3.15 mg/I'
Dllutsion Faetor;
Analyaie Tirue. . ;
0.334 mg/1,
0 .347 tng/f'
oilutlon Factor:
Analyeie Time. .:
0.553 mg/r-,
0 .554 N nug/I'
Dilutiou Factor:
Rnalysle Titrre. . :
72
5e
I
03 :20
*- . - !
93
9L
HK68c;
IIKSECLAU
aelza-oe/2s/os
oe/26-oe /za/os
BarLum
1
12 :11
95
95
1_
1.2: LL
97
103
1
L2: LL
B9
8V
1
L2:LL
oe / 26 -oe / zs / as HK58c1-Av
a9 / 26 -09 I zs / os HK68c1Alr
ae / 25 - ae / 28 / os HK58C1A1
os / 26 - as / 2s / as HK58c1A2
oe / z6-ae / 28 / as HK6BCIAx
ae / z6-oe / zs / as HK58c1Ao
1-.3
L.3
2.00
2 .00
ChrornLum
o .14 0 .200
0.14 0-200
Iread
a .L2 0.500
0 - 12 0.500
rurE(s):
Crlcuhtionr are performed before rounding to avoid round-off errom iu calculrted reeults.
N Spikcd analyrc recovory is ousido sterod control limits.
STL Denver
o }NABIT BPIf,B SAIIPI,B M RBBORT
IIO|IAL trlsfal B
rlate Receirred- - 3 09 / L3 / 05
RPD
RPD IJIMTTS METHOD
!fifa'i"-- - - - - - - - -: GIW
PREPARATTON- IIIORK
AIITAIJYSIS DATE ORDER #
cl.lent Iot # -
Date saqrl.ed-
PARAIVIETER
- - i D5IL30198
.-3 ag/L2/a5 L2zz2
PERCEMT RECO\IERY
RECO\IERY LTMITS
HS lot-Saryrle *:
Cadmiurn 95
94
D5I1301-98-004 kep Batch *- - - : 5266564
(ag 11L) SW845 6020
(sg 1L1l L.7 (O-2Al SW845 6020
ol-lutlon Factor: 5
Analyeie Tlme. . ; 0rl :29
ag /26 - o e / 2s / os HKE3olco
a9 /25- o9/28/ os HKE3oLcr.
oe / 26- o 9 / zs / os HI(E3 oLc2
oe /25- 0 e / 28 / as HKE3 o1C3
ae / zG"- o e l zr / os Er(83 oLDM
ae /26-0 e /2t / os HrG3oi.DN
oe /26-0 e /zs / as HKE3oIDP
oe / zG- o e /za / as HrcE3oLDQ
ae / 26- oe /28 / os HKE3oLDR
oe / 25- oe / 28 / a5 HrcE3oLDT
oe /z6-oe /27 / os HKE3oLcK
09 / 26-09 /27 / as HICE3oLCTJ
og / 26* og / 28 / as HI(E3 olDU
09 / z6-oe / 28 / os HrcE3 olDv
ae / zt-oe / zs / os HKE3 olDw
ael2G-o glzal os HKE3olDx
Selenlum 92
93
(az 114 )(ez 114) 1.7 (0- 20)
ol-lutLon Factor: 5
Analyels Tine.-: 04:29
D5I1301^98-004 Prep Batch *- -
( 83 1Ie )
(83 1_19) 2.5 (O-25)
Dilutl-on Factor: 1
Analysl-s Tirne., ; 19 :3{
( 8+ L24)
(e+ L24) 1.7 (O-zsl
Dl-lutlon Factor: 1
.nnalysJ,s Time. . : 13 :al7
( es 120)
(BS L20) 2.5 (O-zsl
ol1utJ.on Factor: 1
AualyeJ.e TLme- . : 13 :47
(as 1s3 )(+e 1s3) 2.0 (o-zsl
Dilutlon Factor: 1
Analyein Tl,me. - : 19 :34
(zs 13s)(73 13s) r..o (O-2s)
Pilutioa Factor: 1
AnalyeLs TLme..: 13:47
(8e r.29).
(sz 12e) 3.2 (O- 2sl
Dilutlon Faetor: l"
Analyeie TLme..I 13:47
sw845 6020
sw845 5020
- i 5266567
sw846 50108
sw846 60108
sw84 6 60108
slrl845 60L0B
sw846 50108
sw846 60108
sw846 50108
sw845 60108
sI{845 50108
sw846 50L0B
sw845 60108
sI{846 60108
l{8 frot-Saqrl.e #:
Aluminum LL7
114
115
114
BarLum 10{
l-o 1
Calclum 100
97
Chromium 96
95
copper L2s
L2L
o
STL Denver
(Continued on next page)
3B
PARAMETER
Iron
Lead
Maginesiunr
NLclcel
Potassltrrn
Sllver
SodLum
Vanadtun
Zinc
PERCEMT RECOVERY
RECO\IERY IJIMITS
97
93
104
102
1_0L
97
97
95
1,25
1L6
130
L26
NC, MSB
NC, MSB
100
98
96
94
RPD
RPD IJIMTTS
$z 1ss )(sz 1_55) 2.9 (0-251
Dilution FacEor: 1
Analysie Time-.: 16:29
(s9 121)
(89 L21,) 1.4 (o-25)
DL1utl-on Faetor: 1
Analyer.e TLme. . : 13 :4?
(az 146)
$z 1461 2.2 (O-25)
IrLlutlon Factor: 1
Analyaig Time. . ; l-9 ;3{
(8+ L20)
(B+ LzO) L.7 (O-251
Dilutlou Eactor: L
An.a1yele Tl,me. . : 1"3 : 47
(t e 1,321
(to L32l- 2.4 (O-zs)
Pllutlon Factor: 1
Ana}.yals Tlme..: 19:34
(zs 141)
(zs LALI 2.4 (o-2s)
Dilut,ion E'actor: 1
Analysie Time- . : 13 :<1?
(70 203 )(7o 203) (0-40)
ni]-utj,on Factror: 1
Analyele ?imG., : 19 : 3rl
(es 120 )(8S LzA1. 2.L (O-2s)
DLlut,lou Faetor: L
Analyeie Tl.me. . : 13 :47
(eo 13Tl
(e o L37) 2.L (O- zsl
Pl-lutlon Pactor: 1
Analyals Tirne. . : 13 : 4Z
C1ieut tot fr---: D5f130198
Date gary)led.. - - 3 A9 / L2/ os a2 222
ltrrRIE SPIre SAHPLB EIIALIIATIOII RBFORT
IfIfAI' l,leta-I-e
rlate Receiwed, - 3 09 / B / a5
ffatri-:r- . o - - - . . o : GW
PREPARATION- WORK
Ar{Ar,Ysrg -_D.+TE,. ORDER #
oe/28-oe/2e / as HKE3ol(x{
09 / zs- oe / 29 / os HI(83 olcN
oe / z6-ae / 28 / os HKE3olcA
oe /26- o e / 28 / os Hr(E3o1cC
oe/25-o e/2t / os HKB3O1CR
ae / 25- o e / 27 / As HKE3O].CT
09 / 26 - o 9 / 28 / os HI(E3o1AB
oe /25 - o e / 28 / 0s HKE3 olAe
09 / 26- o e / zr / os HI(E3o1cP
ae lzt-ag /27 / os HKE3or-cQ
a9 / 26-09 128/ os HKE3oIDK
09 / zG- 09 / zs / os HKE3 olDr,
ae /26- o e /27 / as HICE3ot cu
oe / 25-o e / 27 / as HKE3olev
oe / 26- Ae / 28 / A5 HKE30lCD
ae / 25 - oe / 28 / os HKE3 or,cE
as I 26- og I ze / os HrcE3 oler
a9 / 26 -a9 / zB I as HKE3 olec
METHOD
sw845 601_08
9w845 50108
slr84 6 5 0108
sll845 601"08
sr{845 60108
9w846 60108
s?r846 60L0B
gw84 5 50108
sw845 601_08
sw846 60r,08
sr{84 5 5 0108
sll845 50108
sw846 50108
sw846 60L08
sw846 60L08
sw846 601,08
sw84 5 5 0108
sw84 5 6 0108
STL Denver
(Contlnued on next page)
O ItrTTRIT SPIE S,.AHSLE EIIEITIATIqV RBFOBT
lOlEAIr llgfpl s
D5r130L98
09/L2/os 1,2:22 Ilate Receirred--: 09/1-3/05
Dlatri:r----r,---3 GW
PREPARATION. I{ORI(
ANALYSTS D_+rE ORpER #
oe/zG-oe/27 / as HKE3olcw
ae /zo- o e /27 / os HKE3olcx
Cl-ient t-clt * -
Da"tcl Sary)I-ed.-
PARAMETER
.
ZLrconl-urn
PERCENT
RECOVERY
RECO\IERY
LII{ITS RPD
RPD
LTMITS METIIOD
L09
L09
llS lot-Saryll.e *:
Mercury 75
76
rscrE (s) :
D5fl-30198-004 Prep Batch' *. .
N (8s 11{}
N (es 114) O-83 (O-1-0)
oilutl-on FacEor: l-
Analyele Tl-me. . : L7 z O-l
(eo L2a) sr{846 60108
(eo Lzt) o .37 (o-2s) swa46 60108
Dilution FaeEor: 1
AnalygiB Timc..: 19;34
3 5269496
sw846 7470A.
9w846 74',tOI\
ae/3a/0s
ae/3o/os
HKE3 O1CH
HKE3 01C.]
o
Crlorlrtions arc perfomed bcforc rourdin& lo evoll rounddf orrors in sakrthted rcsultr.
N Spikcd analyrc rcoovery is outsidc srilcd contro, limlB.
NC Thc rcovcry and./or RPD wcro Eot rxlmlated.
MSB Tha rccovcry ard RPD wce not cttctilrtd bccausc drc samplc rmoum rns grceer rbetr four dmcs dto Npite amourr.
STL Denver 4A
IIhTRIT SPIffi 8AI{PI,B DA|f,L RBPIORT
To)|EAL lrleta].s
Date Rec'el,rred- . I 09 / B I as
tla,tri:r,GWCl.lent tot *- - . I
Ilate Saryr1ed--.l
SAIT,IPI,E
PARAMETER ADIOINIT
Dsr13 0L98
ae / Lz / os LZ:22
gPfKE I,IEASRD
AI{T A}.{OUNT
PERCMT
RECVRY RPD METHOD
PREPAEATION-
A}IALYSIS DATE
WORK
ORDER #IJNTTS
Itg Lot-Sary>Ie *: D5I130198-OO4 Prep BatcIr #-. - i
Cadml-um
0.0400 0,038L rng/T, 95
0.0400 O.O3?5 mg/l' 94
Pllutlou Factor: 5
nnalysLe Tlme. . : O4 229
5266564
sw84 6 6020
L -7 SW846 6A20
sw846 6A2A
L-7 SW846 5020
5266s67
sw845 5010B
2.6 SWB46 60108
_ sw8(16 50108
L.7 SW846 60108
9w846 60108
2.5 SW845 60108
sw846 60L08
2-O SW846 60L08
sw846 60108
1.0 sw846 50108
oe/26-oel28/os
oe/zG-ae/zs/os
HKE3 01C0
HrG3 0LC1
ND
ND
Selenium
0.0037
0. oo37
HS fot-Saryfie
A1urninum
: 0.10
0.10
Arsenl-c
ND:. ND
Barium
i.. "
:
CaleLum
0-63
0 .63
24
24
0 .0400
o - 0400
2 - 00
2-AO
2. OO
2 _ 00
2-00
2 .00
50.0
50. 0
0.200
0,200
0 , 04 04 mg/t 92
0.0411 ng/T' 93
Dl.Iution Factor: 5
arralyals Tlme, . : A4:29
ae/26-oe/2e/os
oe/25-oe/2s/os
HKE3 O1C2
HKE3 O1C3
#: D5I13O198-OO4 Prep Batch *. . - :
2,45 mg/r
2.39 mg/I'
2 .33 mg/L
2.29 mg/L
ol-].utLon Factor:
Analygig Ti:ne. . :
2.7L rng/L
2 .65 mg /T'
Dllutlon Pactor:
Arralygle Tirnc, , ;
Dilutioa Factor: L
Inalyele Ttme. -: 19:34
L7,7
LL4
1L5
114
L
L3 :47
L04
101
1
L3 z4'l
Hffii;Tae/26-oe/27/os
oe l26-oe /27 / os
ae/2G-oe/zs/os
ae/26-oe/28las
HKE3 O1DP
HKE3 O1DQ
oe/26-0e/28/os
osl26-ae/zs/as
oe/26-oel27/Os
oe/26-oe/zr/as
HKE3 O1DR
HKE3 O1DT
HKE3 OlCK
HKE3 0 LCIJ
Chromium
ND, Ti[D
73 .7 fi)g/I, 10 0
72.2 rftg/L 97
Di1utlon Factor: 1
Analys{e TLms. . : 19: 3rl
o.L94 mg/L 96
0.a92 nrg/L 95
Dllutiou Factor: 1
enalyete Tirne- -: 13:4?
ae/26-oe/zB/os
oe/26-oe /za/as
HKE3 O].DU
HKE3O]"DV
STL Denver
(Continued orr next page)
ClLeut Iot * -
Date gaq)Ied-
i D5I13 019I
: o g / tz/ os L2;22 Date
[trm.Ir SPIX(E SAUPIJE DAIA REPORT
T0TAIJ I'TeTaJ.s
Recel,ved- - r a9/13/as
ttlaf,gi--. - - - - - - -: GIY
PREPARATION- WORK
AIiTALYSTS DATE ORDER #
9AI'IPL'E SPIICE
PARjAMETER AII{OUMT AI,TT
MEAgRD
AIVIOUNT IINTTS
PERCI T
RECVIRY RPD METTIOD
Copper
fron
0 - 0046 0.250
0. o046 0.250
0.31-6 mg/L
O.3OG mg/r,
Di lutf-on Factor :
nnal-yale TIme. . :
7. -2A firy./L
L -L7 mg/r,
Dl-lutrlon Factor:
Aoalyals Tlme..;
O.519 mg/t
0.5L1 mg/L
Dilutiorr Factor;
Analysl-e Time. . :
98 - ? mg/t,
96 - 5 mg/t,
Dllutlon Factor:
Analyeia ?ime. .:
0.486 mg/L
0.478 mg/t'
Pl,IutLon Factor:
AnalysLe Tl-me. . :
1,97 mg/L
L93 mg/L
nLlutrlon Factor:
Rnalyelo TLrne. - :
sw846 60108
3.2 SW846 60108
sw846 60108
2.9 Sv[846 50]-08
as /z;-oe /zB/ os HKE3orDw
oe / zG- o e l zs / os HKE3oLDx
09 / 28-a9 / 29 / os HKE3 ol-clvr
a9 /zg-o 9 /ze / os HKE3oleN
ae /26-o e / 28 / os HKE3o:.cA
ae /26-o e / 2a I os HKE3 olcc
oe /25-o 9 / 27 / os HI(E3 olcR
os/zc-o s /zt / os HKE3ol.cr
oe / 26- o e / 2s / as HKE3 or.AB
09 /zG- o e / za / as HKE3 oLAg
a9 /26-o e /27 I as HKE3ol.cP
oe / zG- oe / 27 / os HI(83 o lcQ
ae / 26-oe / 28 / as HrcE3 oLDK
ae /26-o e / za / os HKE3 ol"Dt
L25
L27
1
L3 :47
97
93
1"
L6:29
104
LO2
L
13:{?
101
97
1
19;3{
97
95
1
13:{7
L25
1- 16
1
19:34
130
L26
1
Ll :4'I
sw84 5
1.4 SI{845
60108
50L0B
Iread
ND
IilD
Magneeium
48
48
Nickel
ND
ND
o .24
0 .24
130
130
1.00
1- 00
o.500
0.500
50.0
50.0
0 .500
0.500
50. 0
50.0
sr{84 5 6 010B
2.2 SW846 601 08
sw846
L -7 SWB46
5 0108
6 0108
Potassium
Silver
sr{84 6
2 .4 SIIE{ 5
6 010B
50 t_ 0B
ND
ND
0.0500 0. O 652 rllrg/L,
o - o500 0.0635 mg/l-,
DiluElon Factor:
Analysie t[me. - :
sw84 6
2 .4 SWB4 5
60108
50L 0B
STL Denver
(Continued on next page)
42
Client Iot f;-. . 3
Date Saryiled,. - 3
SAIYIPLE
AMOI'MT
IATRIT
D5rI-301_98
os / Lzl as :,2:22 Datse
SPTKE MEASRD
AIT{OUNT I]NITS
SPIffi SDTiPI'B IIAIA REPCIRT
Itqfel Heta-le
Recelrred. - ! a9/a3/os
Ifatrix-,.,,,...3 GW
PREPARATTON- WORK
AIVALYSIS DATE ORDER
O
PERCNT
RES\IRY RPD METTIOD *
4 000
4 000
Vanadium
0,0045 0.500
0. 0045 0.500
Zlnc
0,500
0,500
Zirconitmr
o,0024 0,500
0.0024 0.50O
Hg Lot,-Saryll.e
Mercury
ND
50.0 4220 mg/L
Qualifiers: NC,MSB
50.0 41-1-0 mg/I,
QuallfLers: NC,MsB
Dilutl-on Faetor: 1
Analyeie Time..: I9;3{
PARAMSTER
Sodium
NCTB (9) :
sw846
sw84 6
6 0108
60108
oe/26-oe/27/as
oelzo-oe/27/os
HKE3 o1clrI
HKE3O1CN7
ND
ND
0,504 rfig/r,
0.494 mg/L
ol-Iut,J.on Factor:
Analyeie Tlme. .:
0-484 mglL
O -474 nry,/t
ol}utl-on Factor:
Arralyals Timc. . :
0.548 mg/t'
0.545 mg/t
Dt-Iution Factor:
ArraLyels TLme. . :
0.O0376 mg/T'
Qualifters: N
O. OO379 xry/L
Qualiflers: N
Dilution Factsor:
Analyels TimG,,:
sw846 60L08
2 .L SWg4 6 60108
sw846 60108
2 -1" SW845 60108
sw84 6 5 01_08
0.37 9w846 60108
s2694e5
sw84 6 747 AA
0 - 83 Srir846 7 47 AA
100
98
1
13 r47
96
94
1
13;{7
10e
109
1
19:3{
ae / z6-oe / zglos HKE3olcD
as /26- o e / za / os HKE3ol-eE
as / 26- o g / zs / os IIKE3 oleF
oe / 26-09 / 28 / as HKE3 ol-ce
09 / 26-09 / 27 / os IIKE3 otc'w
09 / 26-09 /zi / as HKE3olcx
a9 /3o / os IIKE3 olcH
09 /30/05 HKE3ole'r
*: DSI130198-004 Prep Batch *- - -:
75
76
0 . 00500
0 - 00500
1
L'l z 07
Celorletions are pcrfornrod bcforc roundiag to avold rourM-olf eIrols iD cllcular€d rc$lur,
N Spited anrl)rte rccovery ig ouMc eand co!trrot timits.
NC The rcoovcry and/or RPD wer. Doa calculsred,
IED fie reoovery ed RPD vcre mt calorlrtd bectuse the umplc amount ras grcalc] than four times the spike amount.
STL Denver
O
43
l,IATRr? SPIXG 8AI{PIIB EIIAL{IATION REBORT
I(If,AL lieta-I-s
CLI-eut Iot *- - -: D5I130198
Date S4[cd-.- | ag/L2/os 08:00 Date Received. -r og/L3/05
PARAITIETER
PERCE}{IT RECOVERY
RECO\IERY I,IMTTS
RPD
LIMITS MEtHOD
I.latri:ro r t - - - - . . : GW
PREPARATION- WORK
AIIIAITYSfS DATE ORDER #B.FP...
Il8 lrot-Sary)Ie *:
Mercury 78
77
rrutB (s) :
D5f13O1-98-002 Prep Batch *. . - 3 5269496
N (SS LL4) SW8.{5 747OA
N (85 1-1-4) 0.28 (O-Lo) SW8(16 747OA
Dilution FacEor: 1
Analysis Tl.me- . : 16 : 57
ae / 3ol05 HKE3QIAe
oe /3a / as HKE3QIcA
Calorlations are perfonned before roundlng o avoid rourrd<rff crrors in ulculated results.
N Spike<l rnatyte rocovery in outsido stetcd control llmlts.
o
O
STL Denver 44
Cl.ient, Iot #- , - :
f,rate Saqll-ed.---3
SAMPI,E
PARAMETER AIgIOT'}flT
Dsr1-301,9I
oe /Lz/ as oB : oo
SPTKE MEASRD
A}!T A},IOUNT UNTTS
UhIRIT SPIffi AAHPI,B DHEA RMIORT
Ilctf,Alr l{etal g
Date neceived- . 3 09 / L3 / As
ttatrix, - - - . - . . . r G"I{
PREPARATION-
ATiIATJYSTS DATE
PERENT
RECI/RY RPD METIIOD
WORK
ORDER #
HS lot-Saqr1e *:
Mercur1z
TID
ND
iloIts(s):
D5f130198 -OOZ Prep Batch *- - -: 5269496
o. o05oo 0.00389 mg/1, 7g sw846 747aA
Qualifiers: N
o.0050o o,0o385 mg/t 77 o -29 sI{845 747OA
Qualifiers: N
Dl.Iutlon E'actor: 1
Analyslg TLme-.; 16:5?
oe/30/os
oe/3a/as
HKE3Q1A9
HKE3Q1CA
CalcutatloruI are pcrformed beforo rounding t<r avoi<l roud-off crrorB in cetculated rogrtts.
N Spiked anrlyte rcoovery is outside statcd crntrol llmls-
o
STL Denver
STL DENVER
C
frab
trlst r
Code:
Total Metals Analvsis
COVERPAGE - INORGAI\IC ANALYSIS DATA PACKAGE
URII CorDorrt:Lour gDO No. t D5I130198
STI,DEN Crge No. r SASI tilo. t
gOW !Uo. :
Saryrlr ID.
GIII-BI'IO1- 0 9120 5
Gr{-BUrOz-091205
GIVII-B?|IO2 - 0912 05 I'IS
GIW-BWO2-O91205 MgD
Grw-B$rgz- 091205
feP lat,rnl.ancnt oorrcetionB aDpl.ied?
rCP brokgrrround eorrcctionr rpplLrd?
If yGs-were rrw drta granGratcd bctore
arylllicrtLon of baokground correct:Lons?
llb Saqr1e No,
D5r130198- O 03
Dsr130198-004
D5r130198-00{S
D5r130198 - O0{SD
D5r130198 - O02
o$[orc
Wcrr
Yce/No ES
TcalNo LES
Yaa./IUo NO
Conrncnts r
r certify that Ehl.a data 1laekage Lg la con6>I-Laaco !d.th ch6 tsc:cara and coaditloog ol thc
contsraot, both tsecrhnicr].I.y aad for ceE1et,oo.rr, for otber thaD tbc conditioac dctal.lcd
abovc. R.I.rae of thr drtsa containcd ia thit hardcofry drtr Drckrgrc and In tho cory)utcr-rcrdlble dlta
ruDmLttcd on fIoIX)y digkettc hr. boen ruthorizcd by the Laboratory Drailgcr or tlr. !!anagcr'! degLlrBcc, au
vcrificd by tho fol.I'owla.g al,gmaturc.
ature i Narac r
Titla r
DAC KGttIrlB
Data r
t
I c';
STL Denver
t0i{
COVER PtrOE - II{
P:IIT IP,llvTt -..,,.,
46
STL DENYER
Total Metals Analvsis
-2A.
INITIAL AND CONTINUING CALIBRATION VERIT'ICATION
coDtnqts IIRB CorTpratiou
Ltb Codrr s STtrDtN Caac No. r gAg No. r
ral,tLa1 Calibratsiore Sourct r
Contlnul,agr CrlibraELon Sourco :
Etgrh hrrlty, Spax
Iaorga*rio Vanturar
sDc No. s D5I13O198
ConecntratLon UnLt.a t ry/T.
A1umirlum .l
I nfuninun :l lo.ol 39-6cl 99.11 so.ol l9.3oJ 98.ol
Analftc
1n{tlrI Crl.Lbntl.ou
Tnrcr Found ,6R (1)
ContsLauing Callbratl-on
lEnrc f,orrnd tR ( 1) Found, e6R ( 1)u
CalcI-un L l
Ce,lciun E I
I notraat.um| I 50.0 I ] so.delrol.o I p I
I M.gr*crLurn I I I I zo.ol I I rc.gal gg.glpl
lsoaiunLol I I I s.ol I I s.ozlror.clpl
I soarun Hi I do,ol {0.0gltoo.aI so.o I eg.951 99.9I lpl
I ztr.onLun! I I I o.sol I I o.aeel ee.Blpl
(1)Control lrl,mlcg:Mrretrrar' 80-1201 OEhcr Mctrlc 90-110r CYrnidr 85-115
STL Denver
Fonr If (Port 1) ill
STLDENVER
Contrrct r IIRS Cort>oretion
Total Metals Analvsis
-2A-
INITIAL A}ID CONTINUING CALIBRA'I'ION VERIFICATION
Caac No. r S.LS No. t
Hl,grh Ptrrl-ty, SDox
Inorga,-'lc Vonturor
f,rb Codc r STLDEDI
IaitLrL Caltbration Sourcc:
ConELnulng Ca].ibntLon gource r
sDC !ilO. : D5I130198
Concentration Uaitg : ngr/L
L1uninurn :l 0 .50
lrtumtnun :l I I I so.o I lg.lel ge.g I
0, 518 103.6
AnaLy'ta
Iait,ie.l CrlLlrntl-on
Trrrc Found, e6R ( 1)
ContLnul.ng Crl-Lbration
Tr:tre Found tR ( 1 ) Found tR ( 1)DI
Crlciu,m L l
I cercium HI
5.0
I I io.oI 49.{91 ge.oI
c. 95 99 .2
Potrraiurn I 50 .0 50.491 101.O I P
Mrgrno;ium I 20. o 19.gll 99.7 I P
lsocrun.rol I I _ I s.ol .._1- I s.ollroo.alpl
lsodiuna+l I f ., -l so.gl _rs.-B-rl gg-el I lelZircoufunlo-50 0.d991 99.8 I p
( 1) Control r,LnLts r Mareurlz 80-120f Oth,rr Metrlg 90-1101 Wenidc 85-115
STL Denver
Ior:rn If (Part 1) IN
4B
STL DENYER
Total Metals Analvsis
-2A-
INTTIAL AIYD CONTINUING CALIBRATION VERIX'ICATION
coDtrretr IIRS Corporatlon
Lrb Codcr. STITDEN Cuc No. t SAS No. r
rnitial, CalLbrrtLon Sourcc :
ContLnul.ng Calibrat,ion Sourcc r
Hlgrh Purity, Spax
InorganLc Vantrrros
gDtr No.: D5I130198
Conccntration Unitg : ng lL
Al.umlrrurr :l 0 .50 0.508 101. 6
Al,urrt nrrn :l {9-1 99.3
Ca.I'cium t I 5,0 5. O9 101-8
CeleLum II I 50.0 50.t 101.0
I nouaerl,un I 50.O I I so.ssl 101.2 I P Iluesn.Frup!. I I I zo.ol I I rg.s_sl.gg.elpl
Lggqirrn r,o I I 5.0 I s.Lzl ro2.r Jn Ilgodi'r-url ,.. | | -1.-,_ so.ol so.zol roo.rl I lel
I zlrconiunrl I I I o.5ol I I o.sozl roo.l I r I
.laalytr
InLtLrl. Crl.I.bntiou
llrnrc Found %R(1)
Cont LnuLng Crl.LbrrtsLon
Tnrc Forrnd tR ( 1 ) Found tR' ( 1)M
(1) control Lirnitr: Mercrrry 80-120; Other Matals 90-110; CYaddo 85-115
STL Denver
Form II (Prrt 1) a fN
STL DENYER
Contract: URS Coryoration
Total Metals Analvsis
-2L-
TN ITIAL AI.[D CONTINUTNG CALIBRATION \MRfF'ICATION
Cago Dlo. :gfIl No. r
Eigrh PurLty, Spax
Inorgrrnlc vrnturor
reb Code: STLDEII
r'ritLal Calibntl-on Eourec r
ContLnul,ngr Ca].ibntlon Eourcc:
sDGt !Uo. r D5f130198
Concrntratioa Unit,r : urg/L
eaaL:rtse
rnl"tLal Calibration
Trrrc Forrnd t6R ( 1)
Continuiag Calibration
rrnre f,ound tR (1) Found tR( 1)M
l,IumLnum :l 0 .50 0.5141 102.8 I P
lrrunraun:l | | I so.ol lg.lol gg.sl I lel
CalcLum tI 5.0 5.051 101.0 I P
Crlcium H I 50 .0 54.22 100.{
Poteaaiun I 50. o 50.72 101-{
lnegm.,a_l-_uml I I 20,O I 19.881 99 -{ I P
Sodl-rrn r.o I
Lggdi,-, Hi I I I I so. o I so. aol 1oo,{ I
5. 11 LOZ.2
lrl
J ziroonLurt I I I o.sol I o.5o1l 1oo .z I P I
(1) Contro]. Linl.tsa r Mererrrlr 80-1201 Other Metrlg 90-1101 Crranldc 85-115
STL Denver
Form II (Pr,rE 1) fN
50
STL DENVER
Total Metals Analvsis
-2A.-
INTTHL AND CONTINUING CALIBRATION YERIHCATION
coatrtctt IIBB Corlpration
I.tb Codo 3 STLDEII Caga [b. g al's [b. :
Inl,tLal' Calibntlon Souroa r
Continuingr Cr1Llrratlon Sourcc r
Eigrh hrrity, SDcx
Iaorga'nio VcnturGa
gDO NO. r D5I130198
AIuEt Dum :l
n].ulrLrrutn :
Cal.cl,um L I
Ca!.ciurn II I
I eot.Brr-un I
Coaecat,ratl.on tlnLtg z rrglL
o. 50 0.529 105.8
50 .0 L9.L 98.3
5.O 5.18 103.6
50. 0 51.261 102.5
I I I so.ol I I so.sllror.rlrl
.f,a,rl'yt,c
rnl,tiel Crlibrrtlon
rruc Found, tR(l)
Coatiauing CalibratLon
Trnp trlo,und tR ( 1) fcyund t6R ( 1)M
Iu.goc;LumI I I I zo.ol I I rs.zol gs.glel
lgoaiu,n.Lol 1.,.-.,_. I I s.ol I I s.rrlroz.g,le,l
SodLurn Ei I 50. o 50.701 101.4 P
ZLrconiun I 0.50 0. 50{100.8
Control lrl,rnLtg r Idcrcurtr Bo-120; othar Motalr 9O-110t Ctranida 85-115(1)
STL Denver Fom II (Part 1) IN
51
STLDENWR
Contract: URS CorporatLon
Total Metals Analvsls
aA-
TNITIAL A}ID CONTINUING CALIBRATION VERIFICATION
Crac No. t
Hiirh nrrity, Spcrc
fnorgani.c Vantrrrtre
Lab Coda: STLDEDI
taLtLr]. Crllbratl,on Souroa r
Cout,Lnul.ng crll.brat,l,on Source :
SA.8 Itro. :sDo No. r D5I130198
ConoeatraElon IInl.Es r nrg.[r.
.Lna].1t,e
rrrLt:fal. Cal.LbratLon
rruc Forrnd tR ( 1)
coat,inuingr call-brat lon
Tnrc fouud, lrR ( 1) xouad tGR ( 1)M
Alumj-rrtur :l
A.Luniilr.n :l
CalcLrun t I
Calcl,un H I
0.50
50.o
5.0
50. o
49 ,5 99.1
52 .67 105,3
a.532 106.4
5 .25 105. O
Potaesi.unI 50. o 50.501 101 .2 I P
Magment um I 20.0
lsoatunr,ol I I I l.ol I
19.971 99.{ I p
I r.L7l ro3.llrl
Sodium nf I 50. o 51.191 102. {
lzrrooarunl | _l ,l o.sol | | o.?rrlroa.zlel
(1) eontrol rLrriter MrrcuraT 80-120r othcr u.talr g0-110; cyrntde 85-115
STL Denver Fom II (Part, 1) b IN 52
STL DENVER
Total Metals Analysis
-2A-
INITIAL AND CONTINT]ING CALIBRATION VERIFICATION
goDtrrct! IIRS Corlpration
LrL Codrr gTIJ)tN Cage No. :SIA No. r
-nLtLr,l cr,LibrrtLon Sourea r
ContLnuLng Ca].ibretl,ou Clorrrocr
IlLgh PrrrLty, Spex
InorglnLc Ventsureg
sDc t[o. r D5I13O198
.l,lumLnrrD :l 0.2
Concrletrrtl-on tlnl,t,r 3 mglL
o.257 1102.8
PotaeeLum
Sod,lun lro I
20. 0
eiun I 10.
20 . t6 1100.9
9.52 I 95.2
2 . 01 1100. 5
0 ,2{0 1 95.0 I
2.
J ztrconiunI o.251
Ane,I.ltc
InLtLal' Cr]'Lbratlon
lfrrrc Found tsR ( 1)
Continuingr CalLbratsLon
Tnrs Fo.nd, tR(ll Found tn (1)u
lc.rcrunr.l z.ol a.oolroo.ol I I I I lpl
( 1) Coatrol LLrnLts:ltltrrcurfr 8O-12O; Othcr Mcbelr 90-110r Clranidc 85-115
STL Denver Fom II (Part 1) - I![53
STL DETVYER
Coutrract: IIRS Corporation
Total Metals Analysis
-2A-
INITIAL AI{D CONTINUING CALTBRATTON VERTFICATION
Crac No. t
Hiorh Prrrity, Spcrc
Inorganic VauturoE
Lrb codc r STITDEDI
Initir]. Calt bratl,on Sorrrcc I
ContrLnuLng Cr]-Lbra.tl,orr Elouree:
8AS No. :sDG rlo. r D5I130198
Corrscnt,ratton UnJ.t,s r lrrgll,
fnallte
Iaitirl. Crllbrltl,on
frrrc I'ound tR ( 1)
ContLnulng Crlibrrtion
Trerc Fouad trR ( 1) Forrnd AR ( 1)u
l,ltrminrun :l
IJ.uminum :l {o. 0 40.06 100.2
Lggr"i*mr, I I I
0.50
50. o
5.O I
llg . i2 98.8
0 .507 101. {
s. osl r01.6 I P I
Caleium II I 40. o 40.35 1100.9 50.o tlg .[l21 99.5
J eor.e'run,! I I l. .,--.-g-o.g l,- ,. I I sr.rnlroz.s | ?_lluasac"r.rpl ! I I ,.zo.,ol I I zo.golror.alil
Sodllum Lo I 5.0 5.151 103 .2
lsodrun.sil ro.ol 1,9..-sl-roo.gl so.ol so.s6l roo.J,l I lpllzrrconiunl - I | | o.sol | | o.sorlroo.alil
( 1) Control Li.mits r Marcurar 80-1201 Othrr t'tctalr 90-110; CYanide 85-115
STL Denver
Eorm II (Part 1) IN
54
STLDENYER
Total Metals Analvsis
-2A-
INITIAL AND CONTINT]ING CALIBRATION VERIFICATION
CoDtract,! IIRS CorDoratlon
Lab Code 3 gTfrIlE![SISI l\lo. r grc IIo.3 D5I130198No. 3
ELsh PurLty, gDcxrnltla]. Callbration gourcrr
Contsinuiagr CrI.t bratl,on Source :rnorgrnic vcnBurel
Conocntratl-on UrrLts t rrrg lTt
enalltc
Ioitl,al Ca]'Lbntion
Tnrc Found ,6R ( 1)
Continuinir Calibratslon
Tnrc poqnd tR ( 1) Fouad tR ( 1)M
Alulninum :l
lJ-uninrun .l
Calcitrn L I
Cal"cLum II I
Potrrtiun I
lragrnerium I
I soafgm r,o I I 5.0 I
50 . 611 101.3
20.361 101.8
5. oel 101.8 I P I
fSoOtrrm lrf I 50.O I 50,1{l 100,3 I lpl
I zirconiuml o.5o I I I o.lesl ee.olpl
( 1) Control LLml-ts r Marctrry 80-L2Ot Othcr Mcta1g 90-110; Ctzanj.de 85-115
STL Denver
Fom II (Part t) IN
STL DENYER
Cont,rnct r IIRB Corporatloa
Total Metals Analvsls
-2A_
INITIAL A}[D CONTINUING CALIBRATION \MRIFICATION
Cagc tilo. :gf^g No. 3
filgrh Purlty, Spcx
InorganLo Vanturcg
LrL eodcr STLDEN
rnJ-t,ia1 Ca]-LbrrtLon Source:
ContLnuLng CrI.t braEl,oa Sotrrco r
SDG NO. r D5I130198
Concrntrltlorr Unl"tg r urgf It
enalyta
Initill Cal.l.bratLou
Trnrc found, r6R ( X )
ContrLnulng Caltbratrlou
trnrc Fouad tR ( 1) forrnd %R ( 1)D!
LlumLrrrrrn :l
Al.umLnrrn .l
Caloium tl
Caloium HI
0.50
50. o
5.0
50 .0
48.7 97 .5
48.761 97.5
0.458 93. 6
{ ,94 98.8
Potasrfum J
I urcrrre rirrm I
50. 0 50 .35 100.7 lP
I I I ao.ol I I zo.zslror.rJrl
I soarqa r,o I I I I s.ol I I s.oslrol.o-f3j
! soaium rri I 50,o I 49 . {.1 98.9 J Irl
ZLrconium I o-50
( 1) Control LLnl-ts:Mcrcnrry 80-120r Othor tdrEals 90-110, Cyanldc 85-115
0. {91 98.2 I p
STL Denver Form II (Put 1) IN 55
STL DENVER
Totd Metals Analvsis
-2A-
INITIAL AND CONTINTM{G CALIBRATION VERIHCATION
CoDtsract: IIRSI CorporatLon
lrab Codr 3 gTIrDtN Cage No- :gl,g No. :
Initirl CrlLbratlon Sourcc:
Coat{nutagf Ca].ibnt,ion gourec g
Etgrh Hrrj.Ey, 9pc*
Inorg;rll.c Vcnturer
sDs !fO. r D5I130198
Conscrrtration Unite r ng/Ir
lrtuntnun:l o.asl o.2.5lge.ol I I I I lr
Calclusr t I 2.4 2 .03 1101.5
Potase1un I 20.0 20. 50 1103,0
Magmeelun I 10.0 9.78 I 97. g
J Soatum Lo I 2-ol z.az lro3.sl I I I
.hnalXrte
fniCiel Crll.bnti.on
Trnrc Found tR ( 1)
Coat,lnuLng Cr1l,brrt,Lon
Tnr Found tR ( 1) Fou^ud tR ( 1)M
ZirconLum I 0.25 0.2{3 I g-l .7
( 1) Control ulrd.tg r Morctrry 80-120r Othrr MeEaIs 90-110r Clranidc 85-115
STL Denver
Fom II (Part 1) IN
STL DENVER
Cont,ract t IIRS Corporttl.on
Total Metals Analvsis
-2A-
INITIAL AI{I} CONTIN UING CALIBRATION VERIF'ICAI"ION
Cage SAA No. r
Ht grh PurLty, Spcrc
Inorganl-o Ventures
frab Codo; STLTDEN
fnitirl cr].ibratsLon gourcrr
Coatl-nrrl,ngr Ca]"J.braLioo, gorrroc r
gDo No- r D5f130198
ConcanEraEl,on UnlUs z rurglL
lnrI'yte
raitial Cal-Lbration
Tnrc Forrnd tR ( I.)
ContLnuLng Callbratj.on
Tnrrr Forrnd %R ( 1) tround tn. t 1)DT
Iron to I 0.50
I rron Irl I to. ol {0.33 lr.oo,Bl s0.0 I s0.381 too,8l I
0.519 103 .8
(1) eontrol Liul.ta: t{ercurt, 80-1201 OEhcr llctalr 90-110r eyanidc 85-115
STL Denver
Eor:n II (Pert 1) IN 5B
STLDENVER
Total Metals Analvsis
-2A-
INITIAL AND CONTINUING CALIBRATION VERII:ICATION
CoDtrastr URS Corporrtl,on
r.tb Codc s STIJ)E![Cuc Ng. t gf,g !Io. 3
InitLrl' Call,bratl-on Source :
ContLnuing Callbration Sourccr
Iligh l\rrity, Sflcx
Inorgrenl,c Venturog
sDo D[O, r D5I130198
Analyte
Ini.tial CallbraBLon
Trrr fouad, tR (1)
Contiuuing Crlibntion
Trnrc round tR ( 1) tround tR ( 1)u
Concrretsntlon Uu.l.tr r loif,/l,
lrroar,o I I I I o.sol I I o.srglror.elr
fron Hi 50. 0 50.261 100.5
( 1) Control rirtitt r Dlercury 80-120f Othrrr Mtt,als 90-11O; Ctrrnl-de 85-115
STL Denver Form II (Part 1)-rN 59
STL DENVER
Contract: IrRg Corporatl,on
Total Metals Anslvsis
-2A.-
IMTIAL A}tD CONTINTM{G CALIBRATION \{ERIF"ICATION
Caga [b. :gL8 No.:
Higrh f\rrity, Spax
Inorganj-o VanturGa
r,Eb COdC: STLDIN
fnl,t,ial. Crllbratlon Source I
Cont,jnulngr CalibratsLon BsursG r
SDGI Ro. r D5I130198
ConscntratLon tlnl,ts r mg/Ir
enalfrta
Iultl-el Cal-ibration
Tnrr Found BR (1)
ContLnul.ng Call.bratl.on
I]nrc rcnrlld, tR ( 1) Found tR( 1)D[
( 1) Control LLni.Es r l{crcurAr 80-1201 Othcr BlrBalg 90-110; Clranide 85-115
STL Denver Fort II (Part 1) rrr 50
STL DENI/ER
Total Metals Analvsis
-2A-
INI'flAL AFID CONTINUING CALIBRATION VERIT'ICATION
coBEract: IrBg Corlroretion
Lrb Codc r SlffrDElI Crac SIe. r 8rA Ncl. r sIDc, No. r D5I130198
rnLtl,al Calibration Sgrroc r
Continulng Ca1l-bration Sourca r
High hrrlty, SDox
Inorganio Vcnturc;
Concra,Entiou Unl,tsr t rlgft
IroR Lo I 0.50 0.500 100.0
frroari I I I I so.ol tt.zsl gl.sl I
o
(1)Control Irirnltg r Mercur-1, 80-1201 othrr Mctalg 90-1101 cy,anidc 85-115
tnalrrtc
fnitial CaltbratLou
Tnrc Found e6R ( 1)
ContLnuLng Crl'l5rrtion
Trme Found. tR ( 1) Found, t6R( 1)u
STL Denver forn II (Part 1) IN
6t
STL DETVVER
Contnct r IIRS CorporatLon
TotrlMetals Analvsis
-2A,-
NITTAL AI\D C ONTINTIING CALIBR ATION \M,RIF'ICATION
Cagc No. r SIA No. r
Iligh Ptrrity, Spax
Inorganic VcrrturGt
Ilrb Coda s STfrDm[
fuititl CallbraElon Sourcer
ConBLnui-ng CalLbntLoa Glouroc r
sDc No. I D5I130198
Concer,tration Unitsg: ng ll,
lnrJ.1t,tr
rnLtl-a1 Callbratlon
Trnra Forrsd tR ( 1)
Contj.nul.ngr CrlLbrttLoa
Tnre 1lsund tR ( 1) Fousd tsR(l)D!
Iroa Lo I
lrronni I I
o,50 o. d96 99 ,2
so.ol 16.861 93.21 I
( 1) Control Limlt,s:Merourlr 80-120; Othcr Mota1r 90-110, C:ranlde 85-115
STL Denver Form rI (Part 1) IN 62
STL DENVER
Total Metals Analvsis
-2iA-
INITIAL AND CONTINT'ING CALIBRATION VERIHCATION
Coatract! IrRg Corlrorrtioa
Ltb Codc s STITDEbI Crr Dlo. t gl,g !ilo-:
Initial CalibntLon Eorrroc r
ContLrruLng Cal.Lbration Sourcc :
Htgrh Purl-ty, SDcx
Inorgar.l-c Vrruturrrs
sDc No. r D5f130198
Concrntrrtlon lral.tt t mglt
rDalyt,c
rnLtl.al. Ca].Lbratlon
Tnrc f,cyuad e6R ( 1)
Coati.nuLa.sr Calibration
Tnre Found tR (1) Found t6R( 1)u
(1) Control Llnittr Morcury 80-1201 Othcr Mctalr 90-1101 Cyanldc 85-115
STL Denver Fom fI (Prrt 1) IN 53
STL DENVER
Contract: IIRS CorporatLon
Total Metals Analysis
-2A-
INITIAL A}.ID CONTINUING CALIBRATION \MRIFICATION
Case \lo. I g}'g No.:
Iuorgrenio Venturc;
HLgrh Purlty, Spcx
LtI' Codrr STLDEN
IaitLrl Calt-bratLon Sourcc:
Continuingr Crll-brrtLon Sourcrr:
sDo NO. r DSI130198
Concrntrrtion Unitr r Eg/Ii
LfsecnLc I o.2sl 0.2431 gt.z I r.oo I o.sgsl cg.s I o.ggzl ss.z I r I
AnaLrrt,e
rnitia]. Ca1ibrat,ioa
Tnrc Found tR ( 1)
ContLnulng Call,bratLon
Trerc Fouad *R ( 1) Found e6R ( 1)![
I narium I o.zsl o.2sr hor.e I o.so I o.sozl 101.{ I o-sulroz.z I p I
I Or=omium I o.zsl 0,2{6 I ge.l ! o.so I o.sonl roo.8 | o.lggl sg.s I r Irl0.2{5 I gg.0 0 .50 0.5001 100. o o-5051 101.o
Iroad,0 .25 0.211{ I 97..6 0 .50 0.5021 100.4 0.5011 100.2
Niclra1 I 0 .25 0.2{9 I 99.5 0-50 0.5071 101-{0 . 5051 101.2
Silvcr I o.2 a.24Ll 96.d 0.50 o. {931 98 . 6 0.{921 98.{
I van,adLrrn J o.251 a.zlo I gg.z I o.so I o.sod 100.8 I o.sorl roo.z I p Ilzrac ,..J-_ o.zsl o.zrol so..gl_..._ o.sol 0.5_orl-r-gg..cl o.soolroo.olpl
( 1) Control r.ini tr :Dlcrcury 80-1201 Othrr Mrta1g 90-110; CYauldo 85-115
STL Denver
Form II (Prrt, 1) IN
STLDENWR
Contraot r
Irab Codo:
TotalMetals Analysis
-2A-
INITIAI, AND CONTINI]ING CALIBRATTON VERIFICATION
URS Corlpratiou
STI,DEDI Caac No, r g.tEI ![o.3
Inorganio Vcaturea
SDB ![O- : D5f13O198
InLtia]' Calibrrt,ion Sourcrr
ContLreuJ.ag Callbrat,lon Source :High Purity, Spox
ConcentratLon UnLtg t rrgfl;r
lnalrrt,e
Iait,la1 CalLbration
Truc Found tn'(I.)
Contl-nulng Cal'l.bntlon
Tnre Found tR (1) Found tR ( 1)M
Arsenio I 1. 00 0.9961 99 . 6 0.9951 99.5 I P
laa'lur I I I I .-.0-.sol o.sogl ror.sl o-?oglror.elpl
I chroml,un I t I I o.sol o.tzzl gl.ll o.rztl gs-llpl
0. 50 0.5311 106.2 0.5321 106.{ I B
Lcad 0.50 0.{861 97.2 0.{881 97.5 I P
Niokc].0.50 0 . {821 96,4 0.{g7l 97.4 I p
8ilwar
Vanad,Lum I
0.50
0-50
0,{g2l 95.4 0.4861 97.2 I p
0 . {881 9',1 .6 0.{921 98.{ I p
Zl-nc
( 1) Control l,{ n{ gs 3
0 .50
Marcury 80-120r Othcr Matalr 90-110; Clranldr 8i-11i
0.4501 g0 . 0 0-{531 90.61P
STL Denver
Forn II (ParE 1) rtr
STL DEIVVER
Contract,: IIRS CorTloratLon
Total Metals Analysls
-2A-
INITIAL AI\D CONTTN UING CALIBRATION VERIFICATION
Cagc No- 3 SLE No, r
Inorganic Vcnturoo
Et-gh Purl-ty, Spcx
rab Codcr EITLDEN
fnltLal CalibntLou Eorrrcr r
ContLnuLregr CaI.ibration Sourcrr
SDO DlO. r D5I130198
Concantratl-on UnLEs r ^gf l,
.[na1y"tc
rnLtLal Cal.Lbrltilon
Trrre Found, tR ( 1)
Continuingr Call.brrELon
tnre Found etR ( 1 ) Found. tsrt ( 1)t[
Lrscnie I 1.00 o.gg0l 99-0 0. gga l 99.4 I P
lsrrru," I I I I o.sol o.sosl ror.oJ o.lrslros.olpl
I euromtrun I I I I o.sol o.{ltl gi.sl a.$77 I gs.{Jpl
CoDpcr I o .50 0 .5271 105,4 0.5301 106.0 I P
f,erd I 0 ,50 0.{g61 97.2 0,4891 97.8 I P
[utchcr I I I I o.sol o.dB{J 9G.8 I o,{B9l 97.8 I P I
Sl.Iwar I
I venadium I
o .50 0. {831 96 - 5 0.{871 97.t I p
I I I o.sol o.lgol cs.ol o.egzl ge.llpl
lzino I I o.5o I o.{s{ 90.2 I o.{5{l go,B J p I
( 1) Contrrol r,Lrnita r Moreuty 80-120r Othor Metrls 90-110t CYanidc 85-115
STL Denver
Form II (Part 1) IN
66
STL DENVER
Total Metals Analvsis
-2L-
INITIAL AND CONTIN UING CALIBRATION VERIFICATION
Colrtrlct, IIRS Cortpratio|a.,- , ,, , ,
Lrb Codc r STITDIEN Cage lilo. :S S No.r gDC No.: D5I130198
Inl-tsir]. .Ce1ibraEion Sourcc r
Cont,inuing CaltbratLon Source :U1tra SclcntLflc
NIgT
ConcentratLon llnitg z ngllg/
.f,nal.yt,o
rnitial Calibration
'rrnrc Fsund e6R ( 1)
ConBtnuLng Ca1lbret,:Lon
?rrnrc round tR ( 1) Fouad tsR ( 1)DI
lr'rorcu4, I o.oozrzzl o,oozr.oo I ga.s I o.oosooo I o.oolged gz.r I o.oolzzrl gl.l lcvl
( 1) Control r,imits :ldcreury 80-1201 othrr Mrta1s 90-110, cyanlde 85-115
STL Denver
STL DEIY}/ER
Contract r IIRS Corporatl,on
Total Metals Analvsls
-7A-
NITIAI, Ah[D CONTINUING CALIBRATTON VERII.'ICATION
[Io. r
NTgT
Sl8 Dlo. r
UItn Scicntifio
L,ab Code : STLDTII
fnitia]- Crltbratlon Sourccr
Coretl,nuLng CaIt brats:Lon Eorrroc r
SDc NO. r D5I130198
ConccntratLon Unltr : \g ll,
Ana].fft,o
InLtLal CalibratLon
Erur Forrnd tR ( 1)
Cont,inuiag CelibratLon
Trnrc round. tR ( 1) Found. e6R ( 1 )!{
0.005000 0.00483 96.7 o . o0{ 889 97 .8 cv
( 1) Contro]. Irinitr:Msreuty 80-120; OBhcr Matalt 90-110r Cyanldo 85-115
STL Denver Fom, II (Prrt 1) - rN 5B
STL DENI/ER
Total Metals Anahsis
-2A.-
INITIAL AND CONTINTM{G CALIBRATION VERTFICATION
Cotrrtrllotr IIRS Corporatloa
trl Codc r Sff,,DEDI Cagc ![o - :gl.8 No. l
Inltl-al CalLbra,tion Sourcc r
Contl-nuLogr CelibratsLon Sourca :
NIST
U1tra Seiantific
sDo No- r D5I130198
Concentratsioa UniEs : Dg llt
.}nalyt,c
rnJ-tla1 Call,braul,on
Trnrc Found ,6R ( 1)
Contl-nuing celibratj.on
TrLc ll.ouud 96R ( 1) Pousd tR ( 1)u
0 . 0 05000 0 . oo{79
(1) contror r,Lnl,tgr ucrcurlr 80-1201 othcr Mrtarr 90-110; cyrnldr 05-115
STL Denver
Forrrr II (Part 1) IN
STL DENVER
Contract: IIRS Corporation
Total Metnls Analvsis
-2A-
IMTIAJ, AI\D CONTINUING CALTBRATION YERIF'ICATION
Cr;c No. r Ellg I[o. t
HLgh rrrf.ty
InorganLc Venturos
Ltb Codc r SIEITDIIII
Tnltial Ca]'ibntsLon Sourocr
Continuing Call"bratLon Source I
sDCt No, r D5I130198
Conocatration UnitsE: eg /T,
Sal.eniurn I 0.040 o. o39g I gg.5 0,050 0. 04951 gg .2 I 0 . 0 5L7 I 103 .4
( 1) ControL l,J.nite r Mrrcurlz 80-1201 Othor Mtt,als 90-110,' Cfrrnldo 85-115
Aaalyte
Initirl CrlLbnti.on
Txrre f,'orrnd ,6-R ( 1)
ConELnul,ng Crlibration
Tnrc I'ound 96R ( 1) D'orrnd ,6R ( 1)M
I caant,n I o.olol o.or11 lroz.g I o.oso I o.olgsl gs.o I o.osoal roo.l I u I
STL Denver
Eorn II (Part 1) rN
70
STL DEF{VER
Total Metals Analvsis
-2A-
INTHAI, ANI} CONTINT]ING CALTBRATION VERIFICATION
eoatrlrcCt URS Corlroretl,on
Irab Code : STLDEN Cage No.3 gng No. :gDo No. :
InitLrl Call.bratLon Source :
ContLnul.ng Cal.ibrrt,:lorr Sourec r Inorgranic VanturGs
ELgrh hrrltsy
Conccntration Unit,s : ^g lL
CadnLrrm 0 .050
(1) Control l,lnitt:Mercrrry 80-120; Other Mctalr
0.o50 100-8 o .050c
90-110; CYanidr 85-115
Dsr130198
100.9
ScIcnLun o,0{98
.lnal-ytc
rnLtl,al Calibration
Tnrc found tR (1)
CoutinuLngr Calibratlon
Truo round rGR ( 1) FouDd tR( 1)u
STL Denver trorm II (Drrt 1} IN
STL DEIVYER
Contracb: IIRS Corlloration
Total Metals Analvsis
-2A-
TN ITIAL AND CONTINUING CALIBRATION VERITICATION
Crac No. r Slg No. i
Ht grh rrurlty
Iaorganic Vcnturct
Lab Coda: STITDEN
rnl-t{a1 Calilrrat,l.oa Sorrrcc r
Contl-nulng CalibratLon 8<rrrrce r
sDo No- r D5f130198
Coneentratsion Uait,g = urglb
Ana1r&,e
rnt.t,lal Call,bratrl-on
Enrc Found tR ( 1)
Contlnulng Caltbrrtion
Tnrc Found e6R ( 1) Found e6R ( 1)ITI
Cadmirurr o.050 0 .0t7 95 ,6 0.0483 96.6
o. 0{65
( 1) ConErol lriruite r Mercury 80-L20; othcr tdetalr 90-110; cyanlde 85-115
STL Denver Form II (Part 1) rN 72
STL DENVER
Totel Metals Analvsis
-2A-
INITIAL AND CONTINUING CALIBRATION VERTFICATION
coatrrctr IIRS CorprctLon
Lab Codc s SE[TDEII Caac No. r A S !ilg. t
Inl-tia]. Crlibnt:lon Sourec r
ContlrruLnf, CalLbration Sorrrecr
High Ptrrity
Inorgranl"c VenEurea
aDs slo. r D5r130198
Colrcrutntloo tYrrl.tr r urgl['
.lnallt,c
Iuitirl Crll-bntLoa,
1r:nrc Found t6R ( 1)
Contl,nuing CrlLbration
Tnrc Fouad tR ( 1) f,orrnd. e6R ( 1)M
Cadml,um 0 .050 0.0{87 97 .tL 0.0 L79 95-8
Salcniurr 0.0173
( 1) Control r,Lurl-ts r Mcrcury 80-120r Othcr ltctalg 90-110; Cll,enide 85-115
STL Denver
Form II (Part 1) IN
STLDENVER
Total Metals AnalYsis
_2:B_
CRDL STAI\DARD FORAAAI\D ICP
Contrast r IIRII Corlroratl,on
Lrb Codc r STLDE{
AA CRDtr Stand,ard Sourcr r
fCP CRDL Standard Sourco:
Cagc SLS No. I sDCt No. r DSf 130198
Inorganl-c Vaaturaa
CoaocaErrtl.on IIniCr ; ng /It
Jtluml.num I
CRDL Starrdard for ICP
rnLt LrL F:lnrl
1lound, e5R FOund
CRDL Straudrrd for At'
,i[rnr Found.
0 ,10 0.100 I 100.0
CalcLunr r"'I 0.20 0.197 I 98.5
Potee;iunf 1.0 1-011 101.0
MngnreriunI 0.20 0.209 I 10{.5
SodLum Iro I
I zLreoaiumf
1.0
I ll o.oosl
r.. 021 102 . 0
o.oo57J rra,ol I
STL Denver
Forn II (Part 2) III 74
STL DENVER
Total Metals Analysis
-28-
CRDL STA}IDARD FOR AA AND ICP
Contraet r tIRSi Corpontl-on
Lrb Codcr BTLDB{
,r.L CRDL Steadrrd Sourocr
fCP CRDL Strndrrd Source:
Cetc No. t Sng No. t sDGl ![o. r D5f 130198
Inorg.n[c Vant,ros
Conccntrratio,n Unitg t mgllt
Cil)L Scarrdard for ICP
rnLtl.rl. Fia^al
trur Dound ,[R Dorrrrd,
CRDI, Strandard, for ll'
J lfunfnun I I I ll o.rol o.rozl1o2.ol I
Calcl.rrm L l o.20 0.2071 103.5
PotagrLunl 1.0 1.161 X,15.0
Irlrgaoc;tum I 0,20 o .2001 100 . 0
godium to!1.0 1.09 I 109. 0
I ziroonrunl -. I I I I o.oosf o.ooetl rzo.ol I I
STL Denver fonn II (Part
"l - IN
STL DENVER
Total Metals Analvsls
-28-
CRDL STAI,IDARD F,ORAAAI'{D ICP
Contract r TIRSI Corryoratl,on
rrb Codc r STITDEN
A.L CRDII Standard Sorrrcr r
ICP CRDIr Standard Source :
Cage l\Io. :S.[,8 ![o. t 8DO No-: D5f130198
Inorgat lc Venturoa
Concratntl,ou, Unleg z m'I/I)
il o. o3o I o. 0345l us. o l
CRDL Standard for L[,CRDL Etandard for feP
IniULrl rLnrl
Trrrc Foq4d tR lound
STL Denver
Porn II (Part 2) IN 76
STLDENVER
Total Metals Analysis
-28-
CRDL STAT.IDARD FOR AA A}ID ICP
Cotrtrrct r
Irab Cod,o r
URg Corporation
Crrr ![o, r sDs No. r D5I130198STIJDBI
t.L CRqt Etradard Sourcrrr
fCP CRDL Standard ftorrcr r
S.}S No. r
High hrrLty, Spax, Inorgaaic ventrrrea
CouocntrrtLon Uu,ltr : mg lt
EDI, Etandard lor ICP
Inl,tial f,l.nal
Pound tR Found,
CRDrr Standard, tor lr
Tma Found
lrrgcarc I .. I I ll_.o.orol o.ooezl az.ol..- I Ilseriun I | | lJ o.oosol o.ogsrrl roz.zl .. I I
CbronLum I 0-010 0.0x.10I 110,0
lcopprr I I I ll o.oloj o.o11al ru.ol ll
Lord o, 0030 0.002161 72.A
Nichcl I
SLl-war I
Vrrnadl.rrn I
I zLnc
0 .010 0.0105 I 105.0
0.010 0,00971 97.o
0.010 0.0113 I 113.0
I ll o.o2ol o.ozs2lrzc.ol I _J
STL Denver
Forcm II (Dart 2) IN
STL DENVER
Total Metals Analvsis
-2B.-
CRDL STAI.{DARI} FOR AA AND ICP
Contract: URS Corporation
frab Codr t STLTDEN
ll eRDf, Standard Sourcc:
ICP CRDL Standard Sourecr
Cage No. r
Ultra Seioatific
SnS llo. r SDGI No. : D5I13O198
Coaceirtration Unl,ta t mgfL
CHDL Standard for fCP
rnLtl.ll. Flnal.
Fouad %R Found
CRDIr Etandard for ll,
Mercuryz I o. ooo2oo o - 00021 105.0
STL Denver Forn II (Part 2l ? IN 7B
STL DENVER
Total Metals Analvsis
-28-
CRDL STANDARD I'ORAAAIYD ICP
Contract: IIRS Corpora,tion
Lrb Codc r STITDEN
I.L CRDL Standrrd gouroor
ICP CRDL Btrnd.ard Souroc I
Care [Io. :gng No. r gDo No. r D5f130198
Inorganl,o Vcnturcr
Concrntratiou Unitse r mglL
CRDL Strudud for tI
Tnre Forrnd, tR
CRDI, Strndlrd for ICP
rnit,ial Fina1
Tnre Found tR Forrnd 8R
CadmLum I o . 0010 0.00100 I 100 .0
lsclenJ.rrm I I I ll o.oo10 I o. oooEg l 88.0 1 |
STL Denver
forrn fI (Pert 2) fN
ffisrt
IJRS Corporaflon
Total Metels Analysis Drta Sheet
Lab Nnme:
LoUSDG Number:
Matrlx:
7o Moisture:
Basls:
Anrlysis Method:
Unlt:
QC Batch ID:
Sample AIIquot:
Dllutlon Factor:
$TI, DENVER
psrJ 30198
WATER
ylt
60108
mg/L
s260-s67
50 mL
I
(lllent Stmple II):
Lab Sample lD:
Leb Workordcr:
Date/Tlme Collected:
DatelTime Received:
DstelTlme Leached:
Datell irne Extrrcted:
Date/Tlme Analped:
Instrument ID:
Dst'i.CIO.()q-s678
HLCEK
09/26i05 08:0!
99fi7/A5 18:43
W
CAS No.Analyte Conc.MDL RI,a
7429-94-5 Aluminum 0.017 0.0t 7 0.r0 U
7439-95-4 Magnesium 0.G+3 0.043 0,20 IJ
7440-09-7 Potassium {t.24 0.?4 3.0 U
74A-23-s Sodium l.l I^l 5.0 U
740-67-']Zirconium 0.0016 0.0016 0.015 U
7M0-70-2 Calcium 0.039 0.034 0.20 B
STL Denver
Form 3 Prep Blank Equlvalent
80
ffiSTt
URS Corporetion
Total Metals Analyeis Date Sheet
Leb Namc: STLDENr'ER Cllent Sample lD:
LoUSDG Number: D5Il30l98 Lab Sample ID: D5I23000G5678
Maffi: WATER LrbWorkorder: HLCEK
7o Molsture: Date/Tlme Collectedl
Bagls: YEI Datc/Tlmc Rccclved:
Analy$r Method: 60108 Date/Tlme Lcached:
Unlt: nglL Drte./Tlme Ertracted: 09/28/05 15:30
QC Batcb ID: 5266567 Date/TimeAnalyzed: 09/29105 lA45
Srmple Allquot: SlLml lnstrument lD: 021
DlIutlon Fector: I
CAS No.Analyte Conc.MDL RL a
7439-89-6 Iron 0.02r 0.021 0.r0 U
STL Denver
Form 3 Prep Blank Equivalent
B1
ffisrr
IIRS Corporatlon
Total Metals Analysls Data Sheet
Lab Ntme:
Lot/SDG Number:
Mntrix:
% Moisture:
Basls:
Analysls Method:
Unit:
QC Batch ID:
Srrnple Allquot:
Dllutiorr F'ector:
STL DENVER
DsII30l e8
WATER
UlI
60t08
mg.ll,
s266567
50 m[-
I
Cllcnt Sample ID:
Lab Sample ID:
Lab t#ork0rder:
Dnte/Tlme Collected:
Dtteftime Recelved:
Date/Time l,eached:
Datc/Tirne Extrscted:
Date/I'ime Analyzed:
Instrument ID:
r-r5l23000p-.5678
HLCEK
09/26i05 08:00
09/2S105 I l:a6
0r-6
CAS No.Analyte Conc-MDL RL a
744448-2 Arsenic 0.0044 0_0044 0.0r s U
7439-92-r Irad 0.0026 0.0026 0.0030 U
7440-39-3 Barium 0.00070 0.00070 0.0r 0 U
7440-02-0 Nickel 0.001 2 0_0012 0.040 U
74p.0-224 Silver 0.0028 0.0028 0.0050 r.J
7444-62-2 Vanadium 0.002s 0.0025 0.010 U
7440-66-6 Zinc 0.004s 0.004s 0.020 U
Y44047-3 Chrorniunr 0,0026 0.0026 0_010 U
4ua-so-x Copper 0.004s 0.0045 0.0r 0 U
STL Denver
Form 3 Prep Blank Equivalent
82
ffisrr
URS Corporadon
Total Metals Analysis Data Sheet
Lrb Name:
Lot/SDC Number:
Matrlx:
c/o Moisture:
Basls:
Analysls Method:
[Inlt:
QC Batch ID:
Sarnple Allquot:
Dllutlon Factor:
$T1- pEhrvER
Dst 130t 98
WATER
Wet
7470A
trr8&
s269496
I
Client Snrnple ID:
Lsb Sample lD:
Lab Work0rder:
Dete/Tlme Collected:
Date/Tlme Received:
Date/Tlrne l-,eached:
Date/Tlrne Extrrcted:
Date/Tlme Analyzed:
lnstrument ID:
D5I26p00o-4e68
Ht,rrz
09./30/0s 12:30
09/30/05 l6:5a
019
CAS No.Analyte Conc.MDL RL a
743g-g7-6 Mcrcury 0.000027 0.000027 0.00020 U
STL Denver
Form 3 Prep Blank Equivalent
ffi$Tt
URS Corporation
Total Metals Analysls Data Sheet
Ltb Ntme:
LoUSDG Number:
Matrlx:
oh Molsturc:
Basls:
Analysls Method:
[Jnit:
QC Batch ID:
Sample Allquot:
Dilution Factor:
STL FFNVER
DsII 30198
WATER
Wet
6020
mg/L
52.f,6S64
50 mL
I
Client Sample ID:
Lab Sarrple ID:
Lab r#orkorder:
Date/Tlme Collected;
Date/Tlme Recelved:
Dste/Tlme Leached:
Dstc/Tlme Ertrscted:
Dttc/Time Antlyzed:
Instrument II):
nt1230000-s648
HLCEF
09/26105 .08:00
09128/05 02:58
!M
CAS No.Anallte Conc.MDL RL a
778249-2 Selenium 0.00033 0.00033 0,0020 U
7440-43-9 Cadmiurn 0.000040 0.000040 0.0010 U
STL Denver
Form 3 Prep Blank Equivalent
B4
STL DENVER
Total Metals Analysis
-3-
BLANKS
Contraotr r IIRS Cor;poratlou
Lab Codar STLDEN Crac No. t
Prcparatsion Bhulr Mrtrl-x (aoil/watcr) r }U\TER
gf8 Xb- 3 gDGl No.: D5I130198
PrcDaratl.on Bl,anlr ConocntrrtJ.on Unita (mglb or mglhg) r uc/L
rnLtlal
Ca1l.b,
rhnls
(ryrrL)
Continuingr Ca1l.bratlon
BLank (nglr)
Ll-umLnum IJo I
Crlcl,um lro
Potaagiun
Magrncg:[um
Sodium Lo
Zl-rconium 0.00160 0.00160
0. o3e
o. 00150 o.00160
1,1
0 . 0016
STL Denver
forur III IN
STL DENVER
Total Metals AnalYsrs
-3-
BLANKS
eontract:
LIID Coda r
t ng CorporatLon
STLDEN Crac No. I gAS ![o. r sDCl No. r D5I13O198
Drrrlrrration Blanls
Prelnrat,ion Bl.ank
Mrtrix (roil/wrtcr) r $I}TER
Concantratl,on UnLta (mg/L or lnrgllrgl t MGlfr
Frc1lrrrt,:Lou,
Blank
Cont,LnuLngr Calibration
B].rtrJr (W lt ,
lczc3c
tnl.tia1
CrIIb,
BIr.Dh
(ng/rr)
nlumtnurn L'rr I
Ca].eiun Lo
PotaeeLrrn
Magnael.uur
Sod,irrm Iro
ZLrconirrm
0.o17
o .03{
0 ,2{
0.0{3
o .031
0 .00160
0.017
0.03{
0.2{
0.0{3
0. o48
0.00160
STL Denver
FoTm III IN
B5
STL DENVER
Total Metals Analysis
-3-
RLANKS
Contract r
Irab Cods:
t RS CorTrorltlou
STITDEDI Cage No. :gl.g No.:sDs DIo. r D5f130198
Prcparatl,on BIanlE MrtrLx (aol,1/watar) r
PreDlrrtrLora EIanIr Coaceatrrtion tlnlta Lrylt or rnglkg) r MO/I,
CoutLrrulng Crlt brrtion
Bl.anlc (tng/t )
1ezc3e
llurninum fro I
Crlcium Iro
Potragrirrrn
MagrnegI.um
SodtLum Lo
Zl,raoniun 0.00160 o.00160 0 . 00160
STL Denver
FoTm III IN
STL DENVER
Total Metals Annlvsis
-3-
BLANKS
Contrrct r
Ld, Codct
PraDaration
Pro1lrrrt,i-orr
IIRS CorporatLon
gTt DEN Casc No- :
BIarrlE MrtrLx ( aoll./watcr) r
Blarrk Coucontration UnLt.g
AIIE No. I slxl ![o. r D5I130198
I{}AER
(rtgll or tng/kg) t YlGlT.
Analrtc
InLtl-r1
Caf.l-b.
Blanlr
(n{r/r,}
c
Contlnulng CelibrrtLon
E]'anlr Uwlr,|
1 c 2 c 3 c
Prrparatl,orr
gI.onk
e u
Iron Lo I 0.0211U 0.0211u1 0.021lu1 0.0211u 0.021 I U P
STL Denver FonT III IN 88
STL DENYER
Total Metals Analvsis
-3-
BLANKS
Contncts r
Lab Cod,rt
PrcprrrtLon
PrcDant,ion
IIRS Cor1loration
Care lilo - 3
BIanJr Matrir ( soLl/wrtrr) r
slrats Conecntratiorr Unit,g
sDg ![o. t D5f130198
(Ergll, or nglkg) :VlGlIr
.Lna1ttc
r'lltl.al
ci,Iib.
Blenh
(nglr,)c
ContiauLng Crlibration
Btcnk (tWlLl
1 c 2 C 3 c
PrcDa="Ltoo
Blaalr
c u
froa Iro I 0.021lu P
STL Denver form III ' IN
STL DENVER
Total Metals Analysis
-3-
BLANKS
CoatraeE:
Lrb Codcl
IIRS CorporatLoa
gAS No. :SDO Dro. : D5I130198STLDENCrlr
PraparatLon Blrrrk Mrtrix ( aoll/watcr) r
Prcparatsl,on B1anlr Coaccntration Unitsa (rg/f or ng/kg) I VIC/T'
Contrluulng CalLbrat{on
BhEh (EglL)
c2c3
InLtLal
CalLb,
BlrrJr
(nglr)
Aracrr:Lo
Barl-un
Ctrrornl,um
CopDcr
Nlckcl
Sl"Ivar
Vanad,l,un
0 . oo{4
0.00070
0 .00250
o, oo45
o. oo25
o. 0012
0.00280
o. oo25
0.0045
0 .0014
0.00070
o - 00260
0.00{5
0 .0026
0 .0012
0.00290
0. oo25
0. oo45
0. 00{4
o . ooo70
0.00260
o. 0045
0.0026
o. 0012
o, oo?80
0.0025
o. o0{ 5
0.00{{
0. 00070
0.00250
o. 0045
0,0026
0.0012
0.00280
0.0025
0 - 0045
0 .004{
0.00070
0.oo26
0 . o0{5
0. 0026
0. 0012
o.0028
o - 0025
0.0045
STL Denver
trorn III fN
90
STL DENVER
Total Metals Analvsls
-3-
BLANKS
Contraets: URS Corporatl,oa
I,ab Codc r STITDEN Crro No.:
ProSnraBlon BIanIc l.Iatrl-x ( eoil/weter) :
PreDaratLoa, Bhnlg Coucont,nti.on Uaitt (
SfS llo. :gDo NO,: D5I130198
rnltl.al
CrIl.b.
BITDIE
(ng/r)
Coatinuing Calibrationghnh (nglt)
1c2e3c
.Rrsenie
BarLurn
ChromI.rrm
Colrlrrer
NickaI
SLl.rrrrr
Vanadl.um
0.004{
0.00070
o - 00260
0 .0045
0 .0025
0.04L2
0.00280
0. 0025
o.00{5
0.00{t
0,00070
0.00260
0.00{5
0.0026
0 - 0012
o - 00280
0.0025
o, oo{5
STL Denver
Fom III - I}I
9a
STL DENVER
Total Metals Analysis
-3-
BLANKS
Contraotr r
L,rb Codc r
Frc5rlrrtLon
PraDaratl,on
URS Corpora,tion
gTfrDElI Cage llo. :
B],ank MatrLx (soil/water) :
BlanlE, Concentrrtlon Unitr (
8AS [Io. r sDo I[o. r D5I130X.98
nnrllte
rnLtlal
Ca1lb.
BIanIE
(uglr,)
c
CoutLnulag crlLbntrLon
BI.antE (mglf,)
1 c 7 c 3 c
Prcprratlon
B].aDk
c u
Morcur-y I 0.0000271U o.000027lul 0.000o27lu I 0.000027 I u 0.000027 I U ctr
STL Denver
FO::N III . I}I
92
STL DENVER
Total Metals Analvsis
-3-
BLANKS
Coutract:
LrL Cod,r r
PreparatLon
PrcDaratLon
t Rg Cora>oretion
STfJDEN Cagrr No. r
BlruIE lrtrtrLx (aol1./watcr) r
B]'ank CoacsntrltLon tlnit,r (
gnE trIo. r SDo Dro. t D5I13O19B
wlTER
It' or nglhg) :MC/I,
rnalyta
raitlel
crl:lb.
Blrnk
(ng/L)
e
ContLnuing Callbratlon
slaDIE (mg lLl
lc2c3c
r=.p.r.tion
BItnIB
c til
Mercrrry I o,0oo02?l Ul o.000027 lv c\r
STL Denver
FoTn III . IN
93
STL DEI,{VER
Total Metals Analvsis
-3-
BLANKS
Co,ntnet r IIRS CorporatLon
Lrb Codcr STf,'DEII Cagc No.:8.0,8 No. t
Prcprret,ion alarrh Matrlx ( eoll/waEar) : WATER
PrcDarat:Loa BITaIE ConecntntLon Uul.tt (ng/L or Wlbgl r ltE./L
sDo No. r D5f130198
.f,nrI.ytc
InltLal
CalLb-
BIaEIE
(tngr/r)
c
Continuing Calibratl,on
Blantr 6g lf'l
1 c 2 c 3 C
Fre;rlratioa
B]-a,als
c u
Crdm{um I 0.0000{0lU q_1,.900040 J UI 0 . q.0_0.0-jtj lU,J . o . 0000{0 I u
o.000330lul 0.0003301u I 0,000330 I U
0 . -0-91004
0. 00033
U
U
td
E
M
STL Denver
rOTtrr III IN
94
STL DENVER
Total Metals Analvsls
-3-
BLANKS
Contract s IIRS Corporatlon
LaI, Code : STITDEN Cerr No. :SIS ![o. t
PrrrDaration BI.rnIE Matrl,x (goil/water) : $fI\fER
DrGlraraeioa B]..D]r' Co,rrocntratioB lra:Lta (ngll or Wllcgl t >rclL
gDO NO.: D5I130198
.Lnalrrtrl
rnl.tLal
CrLl.b.
Bhnlr
(rylr)
e
Coat,Lnulng CrlLbratl,ou
B1ank (nrrlL)
L c 7 c 3 c
PrcDar"taoo
BI.rnk
c D!
Ca&,ium
g"I.etf.rnr
o, oogolg LII- I 0.000040 lu I 0.0000{0 I u
O.0O033OlUl o.o0O33Olu I 0.000330 I u
u
M
STL Denver
Form fff IN
95
STLDENVER
Total Metals Analvsis
-3-
BLANKS
Contraot:
f.ab Cod,a:
Preparatioa
PrcDaration
IrRS CorlpratLon
STLDEDI Cage ![o. t
Blrnh Matri:r (goil/wtE,er) :
B1enk ConcanE,ration Unita
81,8 No. :sDe NO.: D5f130198
tYlTER
(ng/r, or nglkg) :MG/L
.lnrLytrc
rnl-t,ial
CaILb.
BIa!fr(ng/r)c
Contl-nuLng Crl Lbratlon
B1r:rk (uglr,)
1 c 2 C 3 c
PraDaration
BI'ank
c M
Cadud.unrffi o . o0oo{.g.,LIr I 0.000040 Iu
0.0003301u1 0.0003301U
tl
u
STL Denver
Fom ITT IN
95
STL DENVER
Total Metals Analvsls
'4-
ICP INTERFERENCE CITECK SA]VIPLE
Contraotr r URS Corporati.on
Irab Codc: STLDEII Cage No.:
fCP ID lilurubcr: TJA IntraDid ICP
SAS No, :aDo NO. r D5I130198
ICS Sourccr High PurLty, S5rex,
Concentration Unitr):
rDLtirl, Fouod
8oI .t 8o1 ..tB
FLml Fourrd.
SoI -l SoI .AB
Flum,fnum Hl. I
alcium Hl
taaal-um
rconLurr
sas. oE l szg. TG l 1oG - o l
Trrrc
go1 .I, go1 ..trB
{98.0{497 .57
5{. {9 I 109.0
51{ .32 515.10 I r03.0
53.90 I 107.9
1.098 I 109.8
STL Denver
Forn IV IN
STL DENVER
Total Metals Analvsis
-4-
ICP INTERFERENCE CIIECK SAMPIE
coatraet g IIRS Corporrtlon
LtI, Codc r STITDEN Cage No.:
ICP ID ![unbcrt TiII' IntreDid ICP
SLSI No. :gDO DIO. r D5I130198
ICS Sourca:Higrh Purity, Sllax,
Coneantration unit;) I mfJlr,
Tnro I rnieial Eound, I rinal Fou.nd
tnal.yt. I sor-r gol.rB I sot.r sot.lB tR I sot.r gol'.tB tR
lel*lnun rri l 515.38 [ rOr.1 I
fcalclunEi
IPot,uiilrrn
SodLuru Lo
Lrconlrrn
490 .75 {95.0{
509 ,L2 508.11 I 101. 5
53.06 I r-06.1
1.1{{ I 11{. {
STL Denver
Form IV IN
9B
STL DENVER
Total Metals Analvsis
-4-
ICP INTERFERENCE CIfT,gK SA]VTPLE
Contnct r IIRS CorponBl,oa
Irab Codn s STLDEDI Cage llo. r
ICD rD !$rmbor: TJt' fntraIltd ICp
Sfg DIo. t slx, ![o. r D5I130198
ICg Sourcrr Eigh Ptrrity, Sllcx,
ConcentratLon unLtg):lgrflll.
Trerc
SoI..L go1.lB
rnit,la1 Found I tinal Found
8o1.l, Sol ..LB r6R J go1 .t go1 .lB tR
STL Denver
Form IV IN
STL DET{VER
Total Metals Analvsis
4-
ICP INTERFERENCE CITECK SAMPLE
contract r IIRS CorryonBLou
tal) Cod,r r 9T[.DESI
rCP ID !0unbur gtIPtRfR.LCE
Crrr No. t S.f,,EI No. t sINl NO- r D5I130198
ICg Esurccr Higrh PurLty, Sllrrx,
ConocntratLon Unlts) s mg/L
Analytc
laLtLr]. Found,
8oI -l' SoI .[fJ
fina]. Found
8o1 -l, 8oI .AEI
Trrrc
SoI ..1, CIoI -AB
lAracnlc ] O. oO 2 - 00 -0.002 1.9s1 99.01
um I 0.00 0.50 0.000 o. 521 I 10{ .21
ronrurl I 0. OO o-50 o. o0{o.47gl 95.81
JCoppar I O.0O o. 50 o.001 o .53? I LA7. { Id I o,oo 1.00 0.000 o.g?l 97.ol
ickcl I 0.00 1. 00 0.001 o,g{l ge.ol
Sl,Lver I O.0O 1- 00 0 ,000 1.041 ro{.Ol
lnrd.ium I O.0O 0. 50 0 .002 o-d801 95-ol
Zl-nc I 0. O 1.0 o. o12 o.90l 90.ol
STL Denver 100
STL DENVER
Total Metals Analvsis
4-
ICP INTERFERENCE CHECK SAIT{PLE
Contracts t tIRg Coqloration
Ltb Codc r SIIITDEN
ICP ID Ntrmborr PE ICDltg
Cagtl No- :Brg No, r sl)(s No. r D5I130198
ICg Sorrrcr r Inorganl,o Vcutrrrcl
Conccntratj.on unLtsa) r mglL
rnLtLa1 F<vtrndl
EloI ..L 8oI .AB
Flnal Found
8o1 .[ slol, ..ABlnal.rrtr
trrnrc
EI01.l' Sol ..lB
0 - 10{{ I 10{. {o .1051
0 - 002 I o. 0996
STL Denver
forn I\I x IN
101
ffisTt
IIRS Corporttion
Totrl lVletals Analysls Deta Sheet
Lrb Name:
LoUSDG Nurnber:
Matrlx:
7o Molsture:
Brsis:
Analysls Method:
Unlt:
QC Brtch ID:
MS Sample Allquot:
MS Dllutlon Factor:
STL DENVER
psrr30t98
WATER
N/A
Wct
60t Ots
mg/L
s266s67
50 mL
-L
Client Sample ID:
MS Lab Srmple ID:
MS Leb WorkOrder:
Drte/Time Collected:
Date/Time Recelved:
Date/Tlme Lerched:
Date/Tlme Extracted:
Drte/Tlme Analyzed:
Instrument ID:
slv-8w02-0er 205
Dsr t 3or e8-qQ4s
HKE3O
09/17/05 t2:22
091.3/05 0e: l s
0e/26l(ll-0S:00
09/27 lOS 19:14
oZL
Andyts Spike
Amount
Sample
Resrrlt C
MS
Result C
oh
Rec 0 QC
Llmtt
Alunrinum 2.00 0. r0 2.4s fi7 n3 - I 19
Calcium 50.()24 J 73.7 r00 48 - 153
Magncsium s0,0 48 98.7 l0t 62 - t46
Potassium 50.0 130 197 t25 76 - t32
Sodium 50.0 4000 4220 MSB NC 70 - 243
Zirconium 0.500 0.0024 B 0.s48 109 80 - r20
STL Denver
Form 5A MS Analysis Dato Sheet Equlvalcnt
LA2
ffisrt
IIRS Corporrtion
Totnl Metnls Analysls Deta Sheet
Leb Name:
Lot/SDG Numbcr:
Matrh:
o/o Molsture:
Brsis:
,A,nalysis Method:
Unlt:
QC Batch ID:
NISD Sarnple Allquot:
MSI) Dilutlon Fsctor:
STI DENYER
B5r r30r e8
v./4rrr
N/A
Wct
60I OB
mglL
s266L97.
50 mL.
I
Cllent Sample ID:
MSD Lab Sample lD:
MSD Lab \ilorkorder:
Drteffime Collectsd:
Date/Tlme Recelved:
DatelTlme Letched:
Datc/Tlrne Extracted:
Date/Time Analyzed:
Instrument ID:
GW-8W02-091205
DsIl30198-001D
HKE3O
O9ltUA5 l2:2?
0e/13i05 Q9;1.5
09126/05 08:00
A9/27fi5 l9:3I
AH
Analyte Splke
Amount
Semple
Result
C MSD
Result
C 7o Rec a RPD a
QC Llmits
7o Rec RPD
Aluminum 2.00 0.10 2.39 l14 2.6 83 - I le 25
Calcium 50.0 24 J 72.2 97 2.0 48 - t53 75
Magnesium 50.0 48 96.5 97 2.2 62 - t46 25
Potassium s0.0 130 193 116 2.4 76 - 132 25
Sodium s0.0 4000 4I IO MSB NC NC 70 - 203 40
Zirconium 0-s00 0.0024 B 0.s46 r09 0.37 80 - r20 25
STL Denver
Form 5A MSD Anabsis Data Sheet Equivolent
103
ffi$Tr
URS Corporafion
Total Metals Analysls Data Sheet
Lab Name: STL DENVER Client Sample ID: CW-BW0Z-091205
Lot/SllC Number: D5ll30l98 MS hb Srmple ID: D5II30I98-004S
Matrh: WATER MS Lab WorkOrder: HKE3O
7o Moisture: N/A Drte/Tlme Collccted: 09/lA$5 12:22
Bash: YCt Date/TimeReceivcd: O9ll3/0I q9;t5
Aurlysis Method: 60108 Dste/Tlme Leached:
Unlt: mc/L Drte/Tlme Ertracted: 09/28/05 15:30
QC Estch lD: 52$561 Date/Time Analyzed: 09129105 16:29
MS Srmplc Allquot: 50 mL Ingtrument ID: 0.?l
MS Dilutlon Factor: I
.AnaIyte
Splke
Amount
Sample
Result C
MS
Result C
o//o
Rec a QC
Llmit
Iron r.00 0.24 t.20 97 52 - r55
STL Denver
Form 5A MS Analysis Data Sheet Equivalent
104
I
I
I
I
I
I
I
ffisrr
URS Corporation
Totel Metals Anrlysis Data Sheet
Lrb Name: STL DENVER Client Sample ID; GW-8W02-091205
LodSDG Number: D5ll30l98 MSD Lab SrmplclD: D5II30|98-004D
Matrlx: WATER MSD Leb Workorder: HKE30
70 Molsture N/A Date/Tlme Collectedt O9ll2/05 12:22
Brsie: Wg Datc/TlmeRecoived: 09/13105 09:15
Anrlysls Method: 60108 Date/Tlme Leacted;
Unlt: rD8& DatdTlmc Ertractod: 09/28/01-lLr9
QC Betch ID: 5266567 Daiclfime Analyzrd: 09129105 16:.29
MSD Somple Allquo* 50 mL Instrument ID: 02t
MSD Dllutlon Frctor: 1
Analyte SpIke
Amount
Sample
Result
C MSD
Result
C 7o Rec a RPD a
QC Limits
7o Rec RPD
Iron 1.00 0.24 t.t7 93 ?.9 52 - r55 25
STL Denver
Form 5A MSD Analysis Duta Sheet Equivalent
105
ffisrr
URS Corporation
Total Metals Analysis Datn Sheet
Lab Nrme:
l,oUSDG Nurnber:
Matrlx:
o/o Moisture:
Brsis:
Analysls Method:
UnIt:
QC Brtch lD:
MS Sample Aliquot:
MS Dllutlon Fector:
STL DENVER
psl r 30199
WAT.ER
NIIA
Wet
60t 0.R
m8/L
5266s67
50 ,4I..
I
Cllcnt Sample ID:
MS Lab Sample ID:
MS Lab Work0rder:
Date/Tlme Collected:
Date/Tlme Recetved:
Ilate/Time Lesched:
Date/Tlme Extracted:
Dnte/Tlme Analyzed:
lnstrument ID:
GW;HW02-091205
n5r r30t 98-004s
Hrffi3q
Q9t12/05 12:22
0oll3105 09:15
09/26105 08:00
0o/281QI .13:a7
0r6
Annlyte
Splke
Amount
Sample
ResuIt C
MS
Result C
o/o
Rec a QC
Llmlt
Arsenic 2-00 0.0044 TJ 2.33 I t6 84 - 124
Barium 2.00 0.63 2.71 r04 85 - r20
Chromiunr 0.200 0.0026 U 0.1 94 96 73 - 135
Copper 0.2s0 0.0046 B 0.3r6 125 82 - t29
I-earl 0.500 0.0026 U 0-519 t04 89 - r2l
Nickel 0-s00 0.0012 U 0.486 9',1 M-120
Silrrcr 0.0s00 0.0028 U 0,0652 r30 7s - t4l
)nadium 0.500 0.004s BL 0.504 r00 8s - r20
7;n"0.5()0 0.0045 U 0.484 96 60-r37
STL Denver
Form 5A MS Analvsk Data Sheet Eauivalent
105
msrr
URS Corporation
Total Metals Analysis Datt Sheet
Leb Name:
LoUSDG Number:
Matrlx:
c/" Moisture:
Basls:
Annlysis Method:
Unlt:
QC Batch ID:
MSD Sample Aliqurrt:
MSD Dllutlou Factor:
STL DENVER
D51.1.10198
WATER
NiA
Wet
60r0I
EIEIL
s266167_
50 mL
I
Clleut Samplo lD:
MSD Lrb Sample ID:
MSD Leb WorkOrder:
flate/Tlme Collected:
Date/Tlme Recelved:
Date/Ttme Leachcd:
Date/Ttme Extracted:
Date/Tlme Analyzed:
Instrument ID:
GW-BW02-091205
psn 30l98-004D
HI(E3O
09/12105 12:22
09/ I 3i05 09; I 5
09/2$/0s 08:00
A9128t05 13:47
016
Analyte Spike
Amount
Sample
Result
C MSI)
Result
C 7" Rec 0 RPD a
QC Llmlts
o/o Rec RPD
Arsenic 2.00 0.0044 LJ 2.29 I14 t-7 84 - t24 25
Barium 2.00 0.63 2,6s l0l 2.5 8s - r20 2s
Chrornium 0.200 0.0026 U 0.r92 95 1.0 73 - r35 25
Coppcr 0.250 0.0046 B 0-306 tzt 3.2 82 - t29 25
I-cad 0.500 0.0026 U 0.51 I r02 1.4 89 - l2l 25
Nickel 0.s00 o.fi)12 U 0.478 96 t.7 84-tz0 75
Silvcr 0.0500 0.0028 U 0.0636 126 2.4 75 -l4l 2sI
Vanadium 0.s00 0.0045 BL 0.494 98 2.1 85-120 25
Zinc 0.s00 0.004s U o.474 94 2.1 60 - t37 25
STL Denver
Form 5A MSD Analysis Dsta Shea Equlvalent
LA7
ffiSTt
URS Corporatlon
Total Metals Analysls Data Sheet
Lab Name:
LoUSDC Number:
Matrlx:
7o Moisture:
Bssis:
Analysls Method:
[J nit:
QC Batch lD:
MS Sample Allquot:
MS flllution k-nctor:
Sl-L DENVER
DsIl30l98
WATER
N/A
UeI
601 0B
Nfl,IL
5266567
50 mL
I
Cllent Snmple ID:
MS Lab Sample ID:
MS Lrb Work0rder;
Date/Tlmo Collccted:
Date/Tlme Recelved:
Iltte/Tlme l-,erched:
Date/Time lixtrncted:
Date/Tlme Analyzed:
Inrtrunrent I D:
L.R MS/Mf,P
pEiI?2...0342-001 s
HKA$C
09f22105 t3:40
09/22105 15:30
0eEOl"Q5 08:00
0P/?$/0s 12: I I
016
Analyte
Splke
Amount
Sample
ResuIt C
MS
ResuIt C
o//o
Rec 0 QC
Llmlt
Arsenic 2.00 0.043 r.90 93 84 - r24
Baritnn 2_00 r,3 3_ l6 9s 85 - r20
Chromium 0.200 0.14 0.334 97 73 - r35
kad 0.500 0.r2 0.563 89 89 - 121
STL Denver
Form 5A MS Anolvsk Data Sheet Eouivalent
108
ffisrt
URS Corporadon
Total Metals Analysis Data Sheet
Lab Neme:
LoUSDG Number:
Matrix:
7o Moisture:
Bnsis:
Anrlysls Method:
Unlt:
QC Batch ID:
MSD Somple Allquot:
MSD Dllrrtlon B'nctor:
s't.L DF,NYtrB
psl 130 r98
WATER
N/A
\Yet
60108
ms/1.
526r6s67
50 rnl.
I
Cllent Semple ID:
MSD Lab Sarnple ID:
MSD Lab Workorder:
Date/Time Collected;
Drte/Time Received:
Drte/Time Leached:
Date/Time Extracted:
Date/Tlme Analyzcd:
lnstrument ID:
LAB MS/MSI)
D51"20342-001n
HK68C
Q9ZTAS fi:40
09/2T45 1534
09/26105 08:00
0.1)/28145 2:tt
0r6
Analyte Spike
Amount
Sample
Regult
C MST)
Result
C 7o Rec a RPD a
QC Llmtts
7o Rec RPD
Arsonic 2.00 0.043 I.87 9t r.g 84 - t24 2s
Barium 2.00 1.3 3,1 5 95 0.20 85 - r20 25
C,hromiurn 0.200 0.14 4347 103 3.6 73 - 135 25
t-ead 0.s00 0.r2 0.554 87 N 1.7 n9 - I2l 25
STL Denver
Form 5A MSD Analvsis Data Sheet Eguivalent
109
STLDENYER
Total Metals Analysis
-5A-
SPIKE SAN{PLERECOVERY
Contract;
Irab Codc:
t RS Cor-I>oratl-on
S.tr}TPLE NO.
allcl NO. : D5f 130198
Ircvcl (Iow/mcd) :LOYT
STITDEN
uat,rl.x ( soL]./water) :
e6 SoLldg for Seqple r
Crtc ![o. t
T{LIIfER
glg No. :
0,0
EpLlrr
Addad (sr)
Contro].
r,Lnit tR
Spikod Samfrla
Result (gsR) C
saq121c
Rcgults (SR)
Concentretioa Units (mglf, or mg/kg dry wel-ght):![G/L
o. 160 I 0.25
o.108f o-50
o. oo28 Iu I 0 .050
0 ,2e1 0.50
0.t29 0.50
Analytc
I coppar I sz Lzs
] Nt-okcl I gc J.z
J 8iJ-var I zs 1{
I vanadlrrm les L2
I ztnc I oo L37
urnenEa r HK68C
0.{21
o.5L7
0. o{9
a .715
0. 845
10e
88
98
10s
83
STL Denver
FormV (PIRT U r IN
110
STL DENVER
Total Metals Analysis
-5A-
SPIKE SAMPLE RECOVERY
ConEract r
Lrb Codag
IIRS Cor+pntLon
S.f,S No. rSTITDEhI
Dflrtrl-x ( soi]./watrr] r
8 SoJ.idr for 8aqD163
Cagc lilo - :
UILTER
SIXI lK). 3
Lrwrl (low/nrd) :
o,0
SAIIPfTE
D5r130198
Control
rrinit tn
Sfll.kad Saryl]'e
Resu1t (ggR) C
8aryrIc
Rcsu1t (SR)
ConcaatretLon Unita ($slL or ng/hgr dry waight) r MG/T,
.}nallrte
I Coppar I sz Lzs
I Ntchel I et 120
I sf1vor I zs 1d
f vanadium I as 1zo
I ztnc I eo 13?
Conrrcntg I HK68e
0.419
0.542
0.0{8
o.755
0 .851
0.150 0 .25
0.108 I 0 .50
0 . oo28 ul 0 .050
0.221 I 0 .50
0.429 I 0 .50
STL Denver
Form V (PIRT 1) IN
ffi$rr
IIRS Cor?oradon
Tottl Metals Analysis Data Sheet
Lab Name:
LoUSDG Number:
Matrix:
o/o Molsture:
Basis:
Analysis Method:
Unlt:
QC Batch ID:
MS Sample Aliquot:
MS Dilutlon Factor:
STL. DEIIwER
psrt30t98
WATE\
N/A
wrt
7474A
ms/L
5269496
t
Client Sample ID:
MS Lab Sample ID:
MS Lab lVorkOrder:
Date/Tlme Collected:
Drteltime Received:
Dste/fime Leached:
Date/Tlme Extracted:
Dste/Time Antlyred:
Instrurnent ID:
cw-Rwe2-09lzQJ
psn30r e8-ogafi
HKE3Q
09/1?105 0tl;00
09/ I 3/05 09: I 5
09/30/05 l2:30
0ei30/.0.5. ..16:17
0r-9
Analyte Splke
Amount
Semple
Result C
MS
Result C
o//o
Rec a QC
I,lmlt
Mcrcury 0.00500 0.000027 U 0_00388 78 N 85 - I 14
STL Denver
Form 5A t[S Analysis Data Sheet Equivalent
L1,2
ffisrr
IJRS Corporatlon
Total Metals Analysls Data Sheet
Lab Nrme: STL DEWER C[ent Semple lD: CW-81V92491205
LoUSDG Number: D5Il30l98 MSD hb Samplc ID: D5ll30I98-002D
Mttrir: WATER MSD LabWorkorder: HKE3O
7o Molrture NrA Date./Time Collec,ted: 09/12105 08:00
Basls: Uft Date/Tlme Recelved: 09/13/05 09:15
Analyols Method; 7470A Dote/Time Leeched:
Unlt: wlL Date/Tlme Ertncted: 09/30/05 12:30
QC Batch ID: 5269496 Datc/Tlrnc Analyzed: 09/30/0f 16:57
MSD SarmpleAttquo* Instrument ID: 019
MSD Dllution Frctor: I
Antlyte Spike
^r{mount
Sample
Result
c TI{SD
Result
C 7o Rec a RPD a
QC l,lmits
7o Rec RPD
Mercury 0,00s00 0.000027 U 0.00386 77 N 0.28 85-l14 l0
STL Denver
Form 5A MSD Analvsis Data Sheet Equivalent
1t_ 3
ffiSTL
URS Corporadon
Total Metals Analysls Drta Sheet
l,ab Name: STL DENVER Cllent Semple ID: GW-BW@491205
LoUSDG Number: D5Il30l98 MS Lrb Sample ID: D5ll30l98-004s
Mah:lx: WATER MS Lab \ilorkOrder: HKE30
7o Moisture: N/A DatelTlme Collectcd: 09112105 12:22
Brsis: JYg Drte/Ttme Recelvcd: 09113/05 09:15
Analysis lvlethod: 7470A Date/Tlme Lcrchcd:
Uni* mS& Date/Tlme Extrrcted: 09/30/05 12:30
QC Batch ID: 5269496 DatelTime Andyzed: 0980/05 17:07
MS Samplc Allquotl Instrument lD; 019
MS Dllutlon Frctor: I
Anrlyte Splke
Amount
Samplc
Result C
MS
Result C
o/u
Rec a QC
Limit
Mercury 0-00500 0.000027 U 0.00376 75 N 85-l14
STL Denver
Form 5A MS Analysls Data Sheet Equivalcnt
L74
Lab Nsme: STL DENVER
LoUSDG Number: It(I130198
Illatrh: WAIER
ffisrr
L]RS Corporatlon
Total Metals Annlysis Data Sheet
Cllent Sample ID: GW-8W02-09I205
MSD Lnb Samplc ID: D5II30lq8-004n
MSD Lab Workorder: HKE30
7o Molsture: N/A Drte/Timc Cotlected: Q2ll2l05 12:22
Basis: U$ Date/TlmcRccelved: 09/13/05 09:15
Analysls Method: 7470/t Date/Tlmc Leached:
Unlt ntlL Drtc/Tlmc Ertracted: 0980i05 12:30
QC Betch lD: 5.2Q9496 Date/Tlme Aoalyzed: Q9BA|OS l'l:07
MSD Semplc Allquot lnctrument ID: 019
MSD Dllutlon Frctor: L
Analyte Splke
Amount
SampIe
Result
C MSD
ResuIt
C 7" Rec a RPD a
QC Limlts
7o Rec RPD
Mcrcury 0.00500 0.000027 U 0.00379 76 N 0.83 85 - 114 t0
STL Denver
Form 5A IUISD Anslvsis Dau Sheet Esulvalent
115
ffiSTL
URS CorPoration
Total Metals Analysls Data Sheet
[,ab Nsme:
LoUSDG Number:
Matrix:
Y" lllolsture:
Brsls:
Anelysls Method:
Unlt:
QC Batch [D:
MS Sample Aliquot;
MS Dilution Factor:
STL DENVER
Dsl1 301 98
WATER
N/A
Wet
60^0
mg&
5266s64
50 mL
t
Client Sample ID:
MS Lab Sample ID:
MS L,rb Work0rdcr:
Drte/Tlme Collected:
Date/Tlme Recelved:
Dste/Tlme Leached:
Dateffime Extracted;
Drte/Tlme Andyzed:
lnstrument I D:
GW-BlyQ2-oel20s
pst t 30l e8-0Q+$
HKE3O
09/.l.Zt.l)5 tz:ZZ
09i I 3/05 09: I I
0el?6/0s 08:00
09/28/QS rM:29
004
Analyte
Splke
Amount
Sample
Rugult C
MS
Result C
o/o
Rec 0 QC
Limlt
Cadrnium 0.0400 0,00020 U 0.0381 95 89-ilr
Selenium 0.0400 0.0037 B 0.0404 92 82-lt4
STL Denver
Form 5A MS Analvsk Data Sheet Equlvalent
116
ffisrt
URS Corporttion
Total Metals Analysis Data Sheet
Lrb Name:
LoUSDG Number:
lVlatrh:
7o Molsture:
Brsis:
Analysis Method:
tlnlt:
QC Batch ID:
MSD Sample Allquot:
MSD Dilutlon Factor:
srl-pFNvER
psr 130 | 9g
WATER
NIA
Wet
6020
mg/L
s2665fr
50 mL
T
CIIent Srmple ID:
MSD Leb Sample ID:
MSD Leb WorkOrder:
Drte/Time Collected:
Dnte/fime Recclved:
Date/Timo Leached:
Date/Tlrne Extrscted:
Drte/Time Analyzed:
Instrument ID:
sw-8w02-0e1205
prr r 30198-0MD
HKE3O
09/I2tA5 0:22
09i l3105 09; l5
09126&5,08:00
09128105 A4:29
@
Analyte Spike
Amount
Sample
Result C MSD
Result
C 7o Rcc a RPI)a
QC Ltmlts
7o Rec RPD
Cadrnium 0.0400 0.00020 U 0.0375 94 1.7 89-il1 20
Selcnium 0.0400 0.0037 B 0.041I 93 t.7 82-il4 20
STL Denver
Form 5A MSD Analysis Data Sheet Equivalent
aL7
ffisrr
LJRS Corporttion
Total Metals Analysls Data Sheet
Lab Name:
Lot/SDG Number:
Matrix:
7o Moisture:
Brsig:
Andysis Method:
Unltl
QC Batch ID:
MS Snmple Allquot:
MS Dllutlon Ftctor:
STL DENVER
p5r L3-0198
WATER
NIA
lifet
6q?0
m8/L
s266s64
50 mL
I
Client Sample ID;
MS Lab Sample lD:
MS Lab Workorder:
Drte/Tlme Collectsd:
Dste/Tlme Received:
Date/Tlme Leached:
DatelTlme Extracted:
Ilate/Time doulyz,ed;
Instrument ID:
L ^ B MS/MSD
Ds1220342-o0l s
HK68C
Q9lZ?/(ls. 13;00
09/2?/$L rsS.Q
09/26105 08:00
09128/05 $:24
0@
Analyte
Sptke
Amount
Srmple
ResuIt C
MS
Result C
,/"
Rec a QC
Limit
Cadmiurn 0.0400 0_0049 4.0424 94 89- l1l
Seleniurn 0.0400 0.008s 0.0371 72 N 82 - 114
STL Denver
Form 5A MS Anolysis Data Sheet Equivalenl
118
ffiSTL
URS Corporadon
Total Metals Analysis Data Sheet
Lab Neme:
LoUSDG Number:
Matrlr:
c/o Moisfure:
Basls:
Antlysls Method:
Unit:
QC Batch lD:
MSD Sarnple Aliquot:
MSD Dllutlon Frctor:
sJL pENVER
Dsl130l e8
WATF.R
N/A
Wet
,6020
trlg/I
5^66564
50 m[,
I
Cllent Samplc ID:
MSD Lab Sample ID:
MSD Lab Workorder:
Date/Tkne Collected:
Date/Time Received:
Date/Tlme Lesched:
Date/Time Ertrrcted:
Drte/Tlme Anelyzed:
Instrument ID:
LAB MS/MSD
D5t?'0342-00t D
HKISC
09/22/A5 B:Nt
09/22105 l5:3O
09/26i05 08:(X)
A9/28/05 Q3:20
044
Analyte Splke
Amount
SampIe
Result
C MSD
Result
C 7o Rec a RPD a
QC Llmits
o/o Rec RPD
Cadmiunr 0_0400 0.0049 0.04 r 0 90 3.4 89- ril 20
Selenium 0.0400 0.0085 0.0363 69 N 2.4 82-n4 2A
STL Denver
Form 5A MSD Analysis Data Sheet Equivalent
STL DENVER
Total Metals Analvsis
-58*
POST DIGEST SPIKE SAMPLE RECOVERY
ConEraet g IIRS CorporetLon
[,rt Codo: STLDIEII Clac No. r glg No. r sDG No. : D5I130198
Uatrix (tol,1/watorlr I{trTEn I,cvcl (low/mcd) r
S.LMPI{E [IC).
f!!TR.l'-LlB OC PDS
Conccatration Unlus:ms/L
enal-ltc Contrro],
IJl,eit tR
Splkcd SamDle
Rmulr, (gBR) C
Barylra
Rrrule (8n1 C
SpLke
f,ddrd (sf,)TR a ![
cadmium I 75 L25 0.182023 o. oo{858 ]0.20 88. 6 M
Salcntrrm l7S L2S l 0.1G0621 0, 009536 0.20 '16.L M
o
Comtcnt
STL Denver Form V (PIBT 2l - IN
L2A
ffisrr
URS Corporation
Totrl Metals fuitlysis Data Sheet
Lab Ntme:
Lot/SDG Number:
Mrtrlx:
7o Moisture:
Brsis:
Analysls Method:
Uult:
QC Batch lD:
Sumple Allquot:
Dilutlon Factor:
STL DENVER
DsIl 301q8
}YATER
N/A
Wet
601,08
mcL
52Cr6567,
50 rnL
t
Cllent Sample lD:
Lrb Sample lD:
Lab Workorder:
Date/Tlme Collected:
Datc/Time Received:
tlateltlme Leached:
Dtte/Time Extracted:
Dntc/Tlmc Anrlyzed:
Instrument I D:
D5I'30000-567C
HLCEK
09/26105 08:f)0
a9?7l05 t8:47
ael
Form 7 LCS Analysis Data Sheet Equivalent
Analyte True Found %Rec a Llmlts
Aluminum 2.00 2.0s t02 86 - r08
Magncsium 5().0 49.7 99 91 ilt
Potnrsiurn 50,0 51.6 r03 86-lll
Sodiunr 50.0 51.7 103 9l - l12
Zinxrnium 0.s00 0.535 r07 75 - tzs
Calcium 50.0 50.9 102 89- lt0
STL Denver 1,2L
ffisrr
IJRS Corporrtion
Total Metals Analysls Data Sheet
Lub Name:
Lot/SDG Number:
Matrlx:
ou" Molsturo:
Basls:
Anrlysir Methorl:
[init:
QC Batch lD:
Sanrple Allquot:
Dllution lractor:
STL DENVE,R
Dst l30 r q8
WATER
N/A
Ifst
60t 0B
mg/L
5?66s67
50 mL
1
Cllent Sample ID:
Lsb Srmple ID:
Lab Workorder:
tltte/Time Collected;
Date/Tlme Recelved:
Date/Ttme Leached:
Dste/Time Extracted:
Date,rTlme Analyzed:
Instrrment ID:
D5r230000-567L
HLCEK
09126105 08;00
0P/?7/01, l$:5-l
021
Analyte True Found C %o Rcc a RPD a
QC Limits
7" Rec RPD
Aluminum 2.00 2.08 104 1.4 86 - I08 2A
Magncsium s0.0 50.6 l0l t.g 9l - r t I 20
Potassium 50.0 52-4 105 r.6 86- ril 20
Sodium 50.0 s2-4 105 t.4 9l-il2 20
Zirconium 0.s00 0.545 r09 I.8 15 - t?5 ZO
Calciurn 50.0 51.7 r03 r.6 89- ll0 20
STL Denver
Form 7 f .C,qn Anolvsic llnta ,fhppt hi.orthtnlpnt
1,22
ffiSTL
LIRS Corporation
Total Metals Analysis Data Sheet
Lab Nsme:
LoUSDG Number:
Matrlx:
7o Molsturc:
Brsis:
Analysls Method:
Unlt:
QC Bntch ID:
Sample Allqnot:
Dllutlon Factor:
STL DENVER
psr I 301e8
WATER
N/A
Ust
60r08
msi L
5266s67
50 mL
I
Cllent Semple ID:
Lrb Sample ID:
Lrb Work0rder:
Drte/Tlme Collected:
DrtelTime Received:
Date/Tlme Leached:
Date/fime Extracted:
Date/Tlme Analyzed:
Instrument ID:
psr230000-s67c
HLCEK
o9/28l0s_.1130
09/29105 15:49
azr_
^A,nalyte Tme Found ToRec a Llmlts
Iron r.00 l.0s l0s 88 - I l0
STL Denver
.Form 7 LCS Analysis Data Sheet Equivalent
o
ffisrr
[IR^S Corporation
Totd Metals Analysls Data Sheet
Ltb Name:
Analysls Method:
Unlt:
QC llatch ID:
Sarnple Allquot:
Dllutlon Fnctor:
STL DENVER
D5rl30r98
WATER
N/1I
Wet
601 0B
mg,&
5266567
50 mL
L
Cllent Semple ID:
Lab Sample ID:
Lab Work0rder:
Drteffime Collected:
Date/Tlme Recelved:
Date/Tirne Leached:
Dute/Tlme Extrrcted:
Date/Time Analyzed:
Instrument lD:
D5I230000-s67L
HI CEK
09/28105 l5:3Q
09/29105 I 6: 15
gzr
Analytc True Found C 7o Rec a RPD a
QC Ltmtts
7o Rec RPD
Iron 1.00 r.0r I0t 4,5 88 - I l0 20
STL Denver
Form 7 LCSD Analvsis Data Sheet Equivslent
724
ffisrt
IIRS Corporution
Total Metals Analysis Dtta Sheet
Lnb Nrme:
Lot/SDG Number:
Mttrlr:
7o Molsture:
Basis:
Analysis Method:
Unit:
QC Batch ID:
Sample AIIquot:
Dllutlon Factor:
STI., DENVER
Dsr130r 98
WAI'ER
N/A
Yql
60 r08
rng&
5266s67
50 mL
I
Cllent Somple ID:
Leb Stmple ID:
Lnb Workorder:
Date/Tirne Collected:
Date/Tlme Recelved:
Datc/Tlme Leached:
Dnte/Tlme Extracted:
I) tte/Time .A, n a I yz,ed :
Instrument ID:
n5l^?0000-567c
HLAEK
09/26105 08:00
Q948/05 I I :51
arc
Analyte True Found o/oRec a Llmlts
Arsenic 2.00 t ^97 99 89 - r09
Lead 0-500 0.481 96 9l Iil
Barium 2.00 2.0s t03 93 - I 13
Nickel 0.500 o-479 e6 90 - I r0
Silver 0.0500 0.0504 10t 85 - I t4
Vanadium 0,s00 0.490 98 88-lt2
Zinc 0.500 0.439 88 85 - lt0
Chromiunr 0.200 0.t 90 95 89 - I 12
Coppe"0.2s0 4.262 r0s 86 - r r0
STL Denver
Form 7 LCS Analysls Dau Sheet Equivalent
L25
ffiSTL
tlRS Corporation
Total Metals Annlysis Data Sheet
Lrb Narna:
LoUSDG Number:
Mntrlx:
"/o Molshlre:
Basls:
Analysls Method:
Unlt:
QC Batch ID:
Sample Allquot:
Dllutlon Frctor:
STL DENVER
psr l3Q l?!
WATER
N/A
Wet
601QE
ms/L
5266567
50 mL
I
Cltent Sample ID:
Lrb Sample ID:
Leb Workorder:
DateIl'ime Collected:
Date/Tlmc Recolved:
Date/Time Leached:
Ilate/Time Extracted:
Date/'fime Anllyzed:
Instrurnent ID:
D5I230_000-s671_{
HLCEK
09/26/05 08:00
09/28/05 1 l:56
tI16
fuinlyte True Found C 7o Rec a RPD a
QC Limits
7o Rec RPD
Arsenic 2.00 I,99 99 0.81 89 - r09 20
Lcsd 0.500 0.486 97 0.9r 9r - llr 20
Barium 2_00 2_(,9 r04 1.5 93 - I 13 20
Nickel 0.s00 0.485 97 r.3 90 - r t0 20
Silvcr 0.0500 0.0512 r02 t.5 85- lt4 20
Vanadium 0.s00 0.496 9e t.l 88 - I 12 20
(inc 0.500 0.443 89 0,91 85 - I l0 2A
]rrornium 0.200 0,r9?96 0.88 89 - I 12 ztl
Coppcr 0.250 0.265 r06 t.2 86 - r r0 70
STL Denver
Form 7 LCSD r{nalusis Datu Sheet Equivalent
L26
ffisrt
URS Corporation
Total Metds Anelysis Drta Sheet
Lab Name:
LoUSIIG Number;
Mrrrix:
7o Moisture:
Brsis:
Analysls Method:
Unlt:
QC Brtch ID:
Srmple Allquot:
Dllutlon Frctor:
STL DENVER
psr l30lp3
)vATER
N/A
u&r
7470 ^
Drs&
szoe4e6
I
CIIent Sample ID:
Lab Sample lD:
Lab WorkOrder:
Date/Tlme Collected;
Dme/Tirne Received:
Date/Time Leached:
Date/Tlme Extructed:
Dete/Tlme Analyzed:
lnstrument ID:
pst260000-496c
HLFTz
09/30/05 12:30
09/3q105- IS.;.2{
0r9
Anelyte True Fountl YuRec a Llmits
Mercuryr 0.00s00 0-00491 98 8s - I 14
Form 7 LCS Anolysis Data Sheet Equlvalent
STL Denver a27
ffisrt
IIRS Corporation
Total Metals Anrlysis Data
Lab Neme:
LoUSDG Number:
Matrh:
7" Moisture:
Besis:
Anrlysis Method:
Unit:
QC Brtch ID:
Sample Aliquot:
Dllutlon Factor:
STL DENVER
psr l l0fpj
!YATER
N/A
ITqI
6020
ulg/L
s266.5ffi.
,50 rqL
l_
Sheet
Cllent Sample ID:
Lrb Semple ID:
Lah rilorkorder:
Dete/Time Collected:
Date/Time Received:
DatelTime Leached:
Drte/Time Extrtcted:
DrtelTlrne Analyzed:
Instrument ID:
D5I230000-564C
IILCEF
Q9/26i05 08:00
09/28/05 03:02
004
Analyte True Found YoRec a Lirnits
Seleniurn 0.0400 0.03s7 89 82 - tt4
Cadrniurn 0_M00 0.0377 94 89- 1tr
STL Denver
Form 7 LCS Analvsis Data Sheet Equivalent
1-28
ffisrr
UR.S Corporation
Total Metds Analysis Dnta Sheet
Lab Name:
Lot/SDG Number:
Mntrix:
7e Moisture:
Brsis:
Analysls Method:
Unlt:
QC Betch ID:
Sample Aliquot:
Illlutlon Frctor:
STT DENVER
p5I r 30t 98
WATER
N/A
Wet
6020
mg/\.
s2fu6s64
50 m[,
I
Client Sarnple ID:
Lab Srmple ID;
Lab Work0rder:
Ilrte/Time Collected:
Drte/l'ime Received:
Date/Tlme Leached:
Date/Time Extrncted:
Date/Time Analyzed:
Instrument ID:
D5Le$000is64t.
HLCEF
0.9/26105 0.q:00
09128/05 03:06
Q@
Form 7 LCSD Analt,sis Data Sheet Eqaivalent
Analyte True Found C 7o Rec a RPD a
QC Limlts
Yo Rec RPD
Selenium 0.0400 0.0360 90 0.97 82 - I t4 20
Cadmium 0.0400 0.037e 95 0.3 r 89-llI 20
STL Denver
STL DENYER
Total Metals Analysis
-9-
ICP SERIAL DILUTIONS
ContrecB r IIRS CorDoratl.on
SiltIPI,E ![O.
ow-Bwo2-09120s sER
sDs No. r D5I130198
Lrcwc]- (Iowlncd) g L,OUI
L,rI, Codo: SELDEDI Cerr Ng. t S.trA No. r
l4[atrLx (;ol.1/water) s trILTER
I A1-uminum,
Cal.cl,rrrn Ir
Potacsl-rrn
Magm,e aiuru
Sod,l,rrm
ZiroonLum
eoDoGntratlon Unitg; nrgll,r
0.102 o .1{5
InLe:Lrl- Samp].e
RceuIB (r)
Scrial Dilution
Rcrult, (g)
13{.79 L26.61
3ggg. go 3855 - 55
0,00235 0.0L425
STL Denver
form fX r IN
13 0
STLDENVER
Total Metals Analysis
-9-
ICP SERIAI, DILUTIONS
Contnct r URB Corlpration
gfilPLE NO.
GI?[-BY[02-091205 Sm,
sDc No.: D5f130198
Lewel. (lolp/nod) :IrOW
Lrb CodGt STLDEDiI Cagc No.:glg l[o. 3
Matrl,x (roJ.I,7rrator) : t{lttn,
Conocntration UniEs r mg llr
tnitLrl 8rm5r1o
Rrnr].e ( r )
8crl.e]. DLlut,i.on
Rclrtr1t (g)
STL Denver Foru IX fU 131
STL DENVER
Total Metals Analysis
-9-
ICP SERIAL DILUTIONS
Contract r IIRS Cor1lontLon
g}UPLE I\IO,
ID[trnA-f,.tIl Qc SER
gDGl NO. : D5f 130198
Larel (Lorr/ncd) r
Lrb Codlr t STfTDEN
Matrix (soil/wrtrr) r 9[AtrER
AILS DIo. t
LOUI
J errlrrnLc
BarLrrn
Chrornitun
Coppcr
Lcad.
NLekc].
SLlrrrrr
VanadLun
Zine
Conccntratl,oa tlnl"ta r mrfIlL
o - 0{30 o.o33oF
8rrLat. Dilutl.on
Roru1t (8)rnit,irr]. Sarw>le
Rcgult (I )
0.15X310.1{019
0 .1600 0.1633
o,12530 .1199
0 .1082 o.1219
0 . oo2go 0.01{00
o,2{51o.220g
STL Denver
Pom IX IN
1,32
STL DENVER
Total Metals Analvsis
-9-
ICP SERIAL DILUTIONS
contraot t IIRS Corporetlon
8l![PIrE XIO.
IDITRJ\-I:IB QC SER
slxl No- t D5f130198
I.cvcl. ( low/mrd) :
Iilb Code: SITT,DET{Cagc No.:
trlatrix (aoll/watcr) : WATIiR
Scrial Dilutioa
Rcgults (S)rnLtLal Sanplc
Ragult (f)
0 - 009536 0.01032t
CadmLum
ScIcnlum
Coaceatration Unitr:mglL,
o.00{958 o. o o52s5 I
STL Denver
Eom IX
133
STL DENVER
Total Metals Analysis
-10-
METHOD DETECI'ION LIMITS
Contract: IIRS Corpontion
I,II, Codr T STLDEI{Crcc No. t
rcr rD Nunbrrr TJf, Intrrr1ltd ICP
f,],rsc Al, fD ![unbcr:
thrr:rracr ntr ID Nunber r
g.}8 I{Io. :
Datcr 5 ILO/2005
sDs No. r D5r130198
lnrlytc
Vilivc-
lcngtb,
(nm)
Back-
grround PQL
(Bglf,)
}IDL
(mgr/L,)!t
A]'uninum L 157 ,0 0.10 0,017 P
.}J-utnLnum Il 309 .2 1.0 P
cl.um L 3L7.933 0,20 I 0.034 -lolrrm H 318.1 10 P
Potasgl,um 755.{91 3.O a.24 P
gl-um 779.478 o .20 o.0{3 P
urn to 589.5 1-O o. 031 P
um IIt"g1g .3 10 P
Zi.roonium 339 .1 0.0050 I 0 .0015 P
STL Denver Forra X - IN 734
STL I)EIVVER
Total Metals Analysis
-10-
METTIOD DETECTION I,IMITS
Contrret r I&g CorporatLon
I,rb Codor STLDEN Crac No, t gng No,;
rlrt,or 5lLOl2AO5
D5r13 0 19 I
IeP ID Nuurber: SIIPERTR-LCE
Fl'amr At fD Shunbcr r
hrrnacs ft ID lftrmbcrr
trnalttc
$hvc-
lengrth
(nm)
gaok-
grround,PQL
(nolL)
UDII
(nn/L)![
lreanLc 189 .O42 0.010 0 .00{{P
BlrI.urn 093 .409 o. 010 0.00070 P
tlr un 267 .7L6 o.o10 I o.oo26 P
CoDDcr 321.753 o.010 I o.oo{5 D
Lead 224.353 0.0050 I 0.0025 P
ckol 231, 50{0.0{0 0 . oo12 P
8l,1vcr 329,069 0.010 I 0.0028 P
rnIcu,um 292.{02 o. o10 0,0025 P
Z 205.200 o,020 I 0.P
Comnent,s r
STL Denver Fom X IN 13 5
STL DETVWR
Total Metals Analysis
-10-
METHOD DETECTION LIIVTITS
Contract r (IRS Corporatl-on
Lrb Codc t STIJDIEN
ICP ID trhrnbrr r
Caga No, ;9.tr8 No.:
DaE,e r 9lL5 l200s
gDc NO,: D5f130198
flans t ID lilumber;
Ftrr:rrcc }trr ID Nurnbrrr
PE CVI
fnaI.]tc
WavG-
lcngth
(nm)
Back-
ground PQT,
lmslLl
Ir)Ir
(Eglr,)tl
rcury 253.70 o. o0020 0.000027 C\I
,menEg r
STL Denver Folm X IN 135
STL DENVER
Total Metals Analysis
-10-
METHOD DETECTION LIMITS
Cootrrct r IIRS Cor+loretion
l,rb Codo r STLDBI
ICP rD lhunbcr: PE fCPlIS
trIenr .}f, ID Nuulrrr r
lltrnacc tt fD Nrrntrcer:
Carr Ng. t SISI No. r
Date: 5 ILOI2AAS
ADO NO. r D5r130198
AnrLytc
faotopc Baok-
grouud,PQr.
(ng/Ir)
MDI,
(wlt'l u
Cadrnl,um 111 0 .0010 0.0000{0 M
SclrruLum 82 0 .0050 0 .00033 D!
Cormtnts:
STL Denver forn X - IN
STL DENYER
Contract: tIRg Cormorat,l"on
Total Metals Analvsis
-I 1A-
rCP INTERELEMENT C ORRECTION FACTORS (ANNUALLY}
Cage No. t g.LS No. r
Dato: 8 lL9l2005
Lab Code r STITDEI{
ICP ID }ftrmbar: TifA Intrepid ICp
sDC No. I D5I130198
lnal:rtrc
Wavc-
lencrth
(nm)A1
rntorelement Correctlon Factorg
Ca Pe
forr
uqr Ag
I 339, leg 0.0000000 | o. o00oooo o.ooooooo oI o-00oo0oo
rlumi-nurr 1 157 ,081 o.0000000 J o. oo00o00 o.oo182oofo-ooooooo ! o.ooooooo
rlumLnum 1309.27L 0.00ooooo I 0.000oooo o.oooooooJ 0.00077{0 I 0.0000000
.f,stLrnony 1206.838 .0 .00ooooo I 0.0000000 o.oooooooJ o.oooooool o.ooooooo
Arrcnic I 189.0{2 o. oooo000 I 0.0000000 0.00000001 o. o0ooooo I o. oooo0oo
sarl.um I {Es. {03 0.0000000 I 0. o0o0oo0 0.00000001 o-oooo0ool o-o0ooooo
BarYzllirrm If ff .AAz 0.0000000 I 0.0000000 o. oooooooJ o. ooo0ooo J o. ooooooo
Boron I e{9.578 o-oo0o000 I o.000oo0o 0.0000000[ o.oooooooI o-ooooooo
cadrrium |.225. s02 0 .0000000 | 0.0000000 o, ooooezol o. 0000000 I 0.0000000
calcium
J frz.933 0.0000000 [ 0.0000000 o. 0000000J o - oooo32o I o. ooooooo
folclum l3ls. tz8 0.00ooooo | 0.0000000 0.00000001 o.ooooooo I o.ooooooo
/rrrornJ.um lZ67 - 716 0.0oCIoooo | 0.0000000 0. 0000000[- o. 000oooo I o.00o00oo
cobalt 11228.616 0.00ooooo | 0.0000000 o. ooooooof o. ooooooo J o. ooooooo
coyS>er !32{.zs3 0 .0000000 I 0.0000000 -0.00002001 ---- -0. ooooooo I 0 .0000000
rrou, I as9.9{0 0.0000000 I o-0000000 0.0000000] o.ooooooo I o.ooooooo
rron |.27 1.441 o .0000000 I o. oo0o0o0 o.oooo00ol 0-0020100 I o-ooo0ooo
read 12?0.353 0. o0o0o00 I 0.0000000 0.0000000J o-ooooooo I o.ooooooo
r.lrhlum I 6?0 .78{0.0000000 I 0.0000550 o. ooooooo I o. 0000000 I 0 .0000000
MagnerLum 1279.0?9 0-0000000 I 0.0000000 o.0006020l o.00oooooI o-ooo0ooo
Irtanoranasc |1257. 51O 0.0ooo0o0 I o.0000000 0,0000000f o,0000160 [ o.ooooooo
Molybdemrm lz0z.030 o. o0o0oo0 [ 0.0000000 0 . 0o0o0oo I o. 000oo0o I o. o0o0o0o
ulckel [ 23 1. G otl lz 0.00ooooo I 0.0000000 o. ooooooo[ o. ooooooo I o. ooooooo
phorphonrs I *r8.28?0.0000000 I o. 00ooooo o-oooo0o0J o-0000000 I 0.0000000
PotaBrium I,t5-{91 0 .0000000 I o.0000ooo o. oooooool o. ooooooo I o. ooooooo
serealun I 196.090 0. ooooo0o I 0.0000000 o. ooooooof o. ooooooo I o. ooooooo
sr.licon I zs1. 612 o. oo00o0o | 0,0000000 0. o00ooool 0. 0ooo0oo I o. ooooooo
gtllcon
I
,01.51s o. oooooo0 I 0.0000000 o . ooooooo I
o - 00ooooo I 0. o0o0oo0
gilvcr
I
gZg.06g 0.0000000 | o,000o0oo o . ooooooo I 0.0000000 I 0.0000000
sodtum I lgg.592 0.0000000 I 0.0000000 o. ooo0oool 0.0000000 [ 0.0000000
sodLum I
gf8.326\o. ooo0000 ] o. oo0oo00 o. oooooool o, oooo0oo I o. oo0oooo
[.rontium IlOz .'t7L 0.0000000 I 0.00016?0 o. oooooool 0,0000000 1 0.0000000
rhallltrm IfgO.g6t 0.0000000 I 0.0000000 o. oooooo0l o. ooooooo | 0.000oooo
Form xI (PART 1) IN
138
Counsnttr:
STL Denve
STL DENIIER
Total Metals Anrlvsis
-llA-
ICP INTERELEMENT CORRECTION FASTOR^S (ANNUAIIY)
CoBtract!
tab Codes STITDEII Carc No.;Sfg No- r
ICD ID msnber: TiIA Intrepid fcp Dator I llg 12005
SDe NO.: D5I130198
Tborl.rrn I 283 .73O 0.00000oo I 0.0000000 o.00085001 0.0000000I o-ooooooo
TLn I rr9-9gg o. oo0o000 I 0.0000000 @ o.ooooooo I o.ooooooo
Titaatrrn I 331.9{1 o.000ooo0 I -0.0000320 o. oooooool 0.0000240 I o. ooooooo
uranl,un I 385.958 o.0000000 I -0. ooolo2o -0. 00085{0 I 0.0ooo0o0 I 0.0000000
vanadLun |zlz -lO2 0-oooooo0 I 0.0000000 0 - 00010101 -0 - 0000130 I 0.0000000
zl-uc I arr.856 o-0000130 I 0.0000000 o.o0oo59oJ o.oo0oo00 I 0.0000000
Cousngnts:
STL Denvc
Forcm, XI (PIRT 1) - IN
139
STL DEIVVER
Total Metals Analvsis
-118-
ICP INTEREI,EMENT CORRECTION FACTORS (ANNUALLY)
contractr FRS CorporatLon ,
LaIl Codc: gTfrDEN Caao No. r SAg No-:
rcP rD }armbar: TilA Intrq>id IcP Dat,a: 8l L9 I 2AAS
gDo No. r D5I130198
Anahrt6
wave-
length
(nm)
Intcralamant Corraetlon Facton
BBA
for:
BO cdAE
I 339.19s 0.0000000 I o. ooooo0o o . ooooooof o. ooooooo I 0.0000000
rluml-num I 162.081 0.00000001 0.0o0o000 o . oooo0oof o.0000000 I o, ooo0ooo
Alrrrnlrrunr I 3Og .27t:0.0000000 I o. oooo0oo o - oooooool o. ooooooo I 0.00ooo0o
.lntl-moay I 206.838 0.0000000 J 0.0000000 o. o000oool 0. ooooooo I o. ooooooo
rrgenle l18g.A{,z o - oo00000 I o. ooooooo o.ooo0oool o-oooooooI 0.0000000
Barl,uur l {5s, {03 0. 00ooooo I 0.0000000 o. oooooool 0.0000000 I 0.0000000
sea'ylltum I 313 .042 0.0000000 I o. ooooo0o 0.00000001 o. ooooooo I o. oooooo0
Boron )249.678 0.00ooooo I 0. o0o0ooo o. oooooool 0,0000000 1 0. ooo00oo
Cadnr{ gr1 1,226.502 0.0000000 | 0.0000000 0 .0000000J o. oooo0oo I o. ooooooo
calclun I317-933 o. oooooo0 [ o.0000000 o. oooooooJ o. ooooooo I o. oooo0o0
f.Ie:Lun ]efe.128 0.00000001 o-ooooooo o - ooo0o00l o. ooooooo I o.0000000
Etrronlum 4267 - 716 0.0000000 | o.0ooo000 o. oooooool o. ooooooo I 0.0000000
coba1r ]728 - 616 o-0000000| o.0000000 o. ooooooo[ o. ooooooo I o.0ooo0o0
copoer I 321.753 0.0000000 [ 0.0000000 o. ooooo00l 0.0000000 I o. ooooooo
rron I a59. gdO o, oooo000 | o. o00oooo o. oooooo0l o, ooooooo l 0.0000000
rron 12r 1. d41 o. ooo0000 I o. o00oooo o. oooooool o. ooooooo I 0.0000000
Lead )220.353 0. o0o0o00 I 0.0000000 o, o0o0oo0l o. oooooo0 | 0.0000000
r,ithlum I szo. zB{0.0000000 I 0.0000000 0.00000001 o. ooo00oo I o. ooooooo
Magneelum l27 9.079 0.0000000 I o. oooo000 o. oooooo0l o, ooooooo l 0.0000000
Dfanganora lZSl. 610 0.0000000 J o.0000000 0.00000001 o.ooo0oooI 0'0000000
Molybdonnm I 20?-030 0.0000000 I 0.0000000 o - 00000001 0.00ooooo I 0.0000000
Nlckel I 23 t. 5 0t 12 0.0000000 | o. ooooooo o. oooooool o. ooo0000 I 0.0000000
phorphoRra l1?8.287 0.0oooooo I 0.0000000 o.0ooo0ool o.0oooooo | 0.0000000
Potarrlum I Ze6. {91 0.0oo0o0o I o.0000000 0.00000001 o.oooooool 0.0000000
selenl.um I 196. 090 0.0000000 | o-ooooo0o o - oooooool o. ooooooo I o. ooooooo
sillcon 125L.6L2 0.0000000 | 0.0000000 o.oooooo0l o,oooooool o.oo0oo0o
sllleon
I
,Ul,615 0,0000000 f 0,0000000 o. oooooool o. ooooooo l o ' oo00ooo
sLlver I rr8.068 0.0000000 | o. ooo0oo0 0.0000000I 0.0000000I o-ooooooo
sodltm I Sg9. s92 0.0000000 | o. ooooooo o. oooo000 I o. ooooooo I o. 0000000
fodlum I 818.325 0.0000000 J o. ooooo00 0.00000001 0.00oooool o.o0ooo00
ltrontltm loOr .zTL 0.0000000 | 0.0000000 o.0ooooool o. o00oooo I o. ooo0000
Thallltm I 190. g5{0,0000000 I 0,0000000 0 .0000000 I o. ooooooo I o. oooo00o
Comncntg:
STL Denve
Fom XI (Penr 2)IN
14 0
STL DENVER
Total Metals Analrsis
-1lB-
ICP INTERBLEMENT CORRECTTON F'ACTORS (ANNUALLY)
eoatract: i (Corooratioa .
Lab Codc: Sa,ITDEN Carc No.:
Intrepld rCPICP fD Dhrmber r TJA DBtc: 8 lLg lz00s
gtg No.:gDO !rO. r DSI13O198
lflrorl.um [TB3.7XO o. ooooo0o I 0.0000000 0.00000001 o.ooo000ol s.oosoooo
Tl,n I rag. g8g 0-oooo0o0 | 0.0000000 o. oooooool o. ooo0ooo I 0. o0o00oo
ritaal.rrn I 33{ - 90 1 0.0000000 I 0.0000000 o. oooooool o. ooooo00 I 0.0000000
uranl,um I ,t5.958 0.0000000 I 0.0000000 o - 0ooooool 0.0000000 I o. ooo0ooo
vanadium IZSA - {Oa 0.0000000 I o. ooooo00 0.00000001 0.0000000 I o. ooooooo
zLnc | 213.856 0.0000000 I 0.0000000 0.000ooool o.oooooool 0.0000000
Courants:
STL Denve
Porm XI (PIRT 2l -IN
1-47
STL DENYER
Coatract.: tIBg Corporatlon
Total Metals Analvsis
-118-
ICP INTE R ELEMENT C O RRECTION FACTORS (ANNTJALLY)
Cage No.:srs tib- :SDcl tilO. r D5f130198rab Code r S'11TDEII
ICP fD lrr.rmber: TilA Intre6ll_d fcp oater 8 llg/2OOS
.trnallte
Wavo-
length
(nm)
fntcrelemcnt Correctl,on Factorl
Cr CU
for:
K I[nCo
I 33e - 198 o, oooooo0 I -0. oo12g00 o-oooooool o-oooooooI o.o00o0o0
ehmlnum I t6z. oB1 0,0000000 [ o.000o0oo o. ooo0oool o. oo0000o | 0.0000000
rlumimm 1309.27L 0. 000oooo I 0. o000o0o o. oooooool o. o0ooooo I 0.0000000
rntl,norrrr I 205 . g3 g 0.0oooooo I 0.0000000 0.0oo00ooJ o. ooooooo I o. ooooooo
lrgcnle I 189.0{e o.0oooo00 | 0,0000000 o. oooooooJ o. ooooooo I o -ooooooo
rarLurn I {85. t03 0.0000000 I 0.0000000 o.oooooool o-o0ooooo| 0.0000000
Bar:y11Lun If ff .A{2 0.0000000 | o. ooo0o0o 0.00000001 0.0000000 I 0.0000000
Boron [acs .679 0.0000000 | 0.0000000 o. oooooool o. ooooooo J o.0oooooo
ca&nLum lzz[.I02 0.0000000 I 0.0000000 o - oooooool o. o0ooo0o I 0.0000000
calcLum I frz.933 0.0ooooo0 I 0.0000000 o. oooooool o. ooooooo I o. ooooooo
lcalctum Iffe.la8 0.0000000 | 0.0000000 o.oooooool o.oo00o00l 0.oo00oo0
Etrromium Jaez-?16 0.0000000 J o.0o0o0o0 0.00000001 o.oooooooI o.oooa72a
cobulr, lze8.616 o. ooo0o00 J o.000oooo o . ooooooo I o. ooooooo I o. ooooooo
coppcr I aal.7r3 o.00ooo00 I o. o00ooo0 o. oooooool o. ooooooo l o, ooooooo
rron I 259.940 0.0000000 I o.0o00oo0 o. oooo0ool o. oooo0o0 I 0.00ooooo
rroB lz71 -{{1 o-13ooooo I 0.0000000 oloooooof o. ooooooo I o. ooooooo
rcad I 220.353 0.0000000 I 0 .0000000 o. oooooool o. ooooooo I o. ooooooo
nlttrlum l gr0. ?B{0.0000000 | 0.0000000 o.ooo0oool o.ooo0000l 0.0000000
MagmegJ.um l.27 9. ozg 0.0000000 I o_0000000 0.00000001 0.0000000 I -0.0035590
M&nganare lZSl.610 0. 0000000 | o. oooo000 o. oooooool o. ooooooo I o. ooooooo
Molybdenun I aOZ.030 0. oooo0o0 I 0.0000000 o . ooooooo J o. ooooooo I o. ooooooo
rulckel lzgt.6o4l2 0.0000000 I o. ooooooo o. oooooool o. oo00o0o I 0.0000000
phorptrorrra I tz8.z87 o-0000000 | 0.0000000 0.00000001 o,oooooool 0.0000000
PotassLum l re6. {91 0.0000000 I 0.0000000 o. ooo0oool o. ooooooo I o, ooooo0o
Sal-onlrrn I ,gO. 090 0.0000000 J o. o0oo00o o.00oooooI o.oooooooJ o-oo0o0oo
sLlLcon
1
251. 612 0.0000000 | o-0oooooo o. oooo0ool o. o0ooooo I o. oo0o0o0
gl,LLcon
I
,ut.61r 0.0000000 I 0.0000000 o, oooooool 0. ooooooo I 0.0000000
sllvor I ree- ooa 0.0000000 I 0.0000000 o. ooooooof 0,0000000 [ 0,0000000
sodlnrn I s8g. 892 0.0000000 I 0.0oooooo o.oo00oool o.ooooooof o.ooooooo
fodrum ] aia. aes 0.0000000 | o. ooooo00 o. oooooool 0.0oo00oo I o. ooooooo
ltrontlum f aOz .zTL o.0000ooo I o. ooo0o0o o.oo00oool o.oooooooI 0.0000000
rhallfu:ur IfgO.gG{o-0000000 I o.0o0ooo0 o. oooooool o. ooooooo I o. ooo000o
For^ut XI (PART 2l r IN
742
Conmcntr:
STL Denve
STL DENYER
Total Metals Analvsis
-1IB-
ICP INTERELEMENT CORRECTTON FACTORS (ANNUALLIO
Contract r IIRB CorooratLon
rab Code s SI1r1TDEN
rCP fD ![umberr TiIA
Carc No. :
Iatrepld ICP
gAg No.:
Dator 8lt9lz00s
sDo !ro. t D5I130198
Thorlum I 283 -730 0.0000000 I 0.0o0ooo0 o.00000001 0.00o000o I o.ooooooo
rl.n I tt9.989 0,0000000 ] 0.0000000 o. oooooool 0. 0000000 I 0. ooo00o0
rLtaal,run Isr{-gl1 o.0000000 | o.0003150 0. oo0oo00l o. ooooooo I o - ooooooo
UranLrur I385.958 0.0000000 [ o. 0000000 0. o0o000ol 0, o00oooo I o. ooooooo
varradLun I292-{A2 o. oooooo0 I 0.0002?90 o. o0o0oo0l 0.0000000 J o.0oo0ooo
zinc I era .855 o. 0000000 I 0.0000000 o. ooogr{ol o. ooooooo I o. ooooooo
Comnentg r
STL Denve
Fom XI (PART 2I -IN
]-43
STL DENVER
Total Metals Analvsis
-11.B-
ICP INTERELEMENT CORRECTION FACTORS (AI\DTUALLY)
Contract: IIRS ComoratLon
Lab Code t S1ILIDEN
ICP rD llrlnbor r TJA
Carc No. t
IntregLd ICP
S.trg No. t
Dat6r I /L9l?AOs
SDc [sO.: D5I13O198
.nnalfte
Ulava-
lcngth
(mt)
Intorclcments CorrectLon factorg
IiIa Ni
forr
Pb sbMo
lrr9.19B 0.0009000 I 0.0000000 o.o00ooool o-ooooo00I 0.0000000
Alrrrntnum 1 167 .081 0.00000001 o.o0o0o00 0.00000001 o. oo0oooo I o. ooooooo
Alrrlnlnum I,t9 -z7L 0.0000000 I o.0000000 o.oooo0o0l o-oooo000I 0.000oooo
Antlrnonl' I ,06.838 0.0000000 I o. oo0000o o. oooooool o. ooooooo I o. ooo0000
truanic I ra9.0{2 0.0000000 I o. ooooooo o - ooo00ool o- ooo0ooo I 0.0000000
Barlutr Id5s.{03 0.0000000 I 0.0000000 0, oooooool o.0oo00oo I o. ooooooo
BerylJ.lunr Ifff.042 0.000oooo I o.0000000 o. oooooool o. oooo000 I 0.0000000
Boron I,o9-5zB 0. o0o00oo I 0.0000000 o-oooooool o-oooooooI o.ooooooo
cadml.um 11226 - 502 0.0000000 I 0.0000000 -0.00019?01 0.ooo00ool o.ooo00o0
calclun | 31? .933 o .0000000 I o. o0ooo00 0.0000000f 0.0000000 I o. ooooooo
falctum lf fa -LzB o-0000000 I 0.0000000 o. oooooool o. ooooooo I o. ooooooo
phromlum lzel.rLG 0.0000000 | o. o00oooo 0. 0000000J o - ooooooo J o. ooooooo
coba]-t lr=8.616 0.00ooooo | 0.0000000 o, oooooool o. ooooooo I o. ooooooo
Copper I sz{.753 0,0003400 I 0.0000000 o-oooooool o.oooooool o.ooooooo
rron lzr9. g{0 0.00ooooo I o.0000000 0.00000001 o.ooooo0oI o-ooo0ooo
rron aZ7 1-t{1 o.6o1so00 I o-o00oooo o. ooooooo I o. ooooooo I o. ooooooo
L(lad 1220.353 0.0000000 J 0.0000000 o. oooooool o. ooooooo I o. ooooooo
r"Lthtrrur ltr 0. ?8{0.0000000 I 0.0000000 o, oooooool o. oooo0oo I 0.0oooooo
ttagnegLufli lrr9. O?9 -0.0358000 I 0.0000000 o. oooooooJ o. ooooooo I o. ooooooo
MangarrerG I esz. Glo o.0000000 I 0.0000000 o.oooooool o.ooooooo I o.ooooooo
Irrolybdcnum lzaz. 03 0 0.0000000 | o. oo0ooo0 o. ooo3dool o , ooooooo l o. ooooooo
url.ckal I 231.6 0{ t"0.0oooooo I 0. 0000000 o.oooooool o.oooooool o.ooooooo
shorphorus ItrB.zg7 0.0000000 I 0. 000oooo 0. 00000001 o. ooooooo I 0.0000000
Potasglun I,e6-491 0.0000000 [ 0.0000000 o.oooooool o.oo000ool o,oooo0oo
sorenlum I 195.090 0.0000000I 0-0000000 o.ooooooo] o.oooooool o-ooooooo
gtlleon
I eSr.612 0.0 a92000 | o. o0oo000 o - ooooooof o. ooooooo I o. ooooooo
sl-Iieon Irtl.615 o. oo9?ooo J o. ooooooo o. oooooool o. ooooooo I o. ooooooo
sLlvcr I 328.069 0.0000000 I o. ooooooo o, oooooo0l 0.0oooooo I o. o00oooo
sodium I ugg.59z 0. ooooooo | 0.0000000 0.00ooooof o,00ooooo l o. ooooooo
{odrm I ere .326 0.0000000 I o. ooooooo o.oooooooJ o.ooooooo[ 0.0000000
ftrontlum IAoz -77L 0.0000000 | 0.0000000 o. oooooool o. ooooooo I o. ooooooo
rhalllun I 190.86{0.0000000 I 0.0000000 0,00000001 o. ooooooo I o. ooooooo
Conmentl:
STL Denve
Eornt XI (PARI 2)IN
144
STL DENVER
Totrl Metals Analvsis
-118-
lcP INTEREL,EMENT CORRECTION FACTORS (AhINUALLY)
CoEtEactt IBE GomoXlrtion
r.ab Code s SEITDEN Carc fVO. r
Intrepl,d ICPICP fD lturnbrrr: TJA DBtor 8 llg l?OAs
glS No.:gDc rro. r D5r130198
Tlrorl'um I283-730 o-ooooooo I 0.0000000 0. 00000001 0. ooooooo I o. ooooo0o
Tln I ta9.989 0. o00o0o0 | o. oo00ooo o. oooooool o, ooooooo l o, o00oooo
TLranlum I33{.9{1 0 - ooooo00 ! o. o00o0o0 o. ooooooof o. o0ooo00 I o. ooooooo
uranLun I 385.958 0. oooo0o0 J o.0000ooo o.0ooooool 0-0000000 I o,ooooooo
vanradLun I aSe .&Az -0. o175O0O I 0.0000000 o.ooo00o0l o.0ooooooJ o-ooooooo
zlnc I zI3-gso 0-0000000 | o.0oo0ooo o.oo{38ool 0.0000000 I 0.0000000
Conuncnts r
STL DeNvC
Form xI (Pmr e).IN
1,45
STL DEA{YER
Total Metals Analvsis
-118-
ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY)
contract r IIRS Comoration
Lab Codo: STITDEII
rCP rD rthutbcr I TifA
Cagc NO. t
IntreDld ICP
grg DJo. :
Dater 8 l1,gl?OAs
gDcl NO. r D5f130198
Arul1t'e
Wave-
length,
(nm)8o
rntarelment Corrcctlon Fact,orl
8i Sn
for;
8r Ti
I 339. 198 0-0000000 | o-ooooo00 0.0000000J o-oooooooI o.oo0o0oo
rlnsrlnrrm Jroz-081 o-0000000 | o.000oooo o. ooooo00l o, ooooooo l o. oooooo0
Alumlnum 1309.z'IL o-o0000oo I o.000oooo o, ooo0000l o. ooooooo I 0.0000000
.tntlnony I 206. 938 0. oo00oo0 [ 0.0000000 o. oooooool o. oo0ooo0 I o. o00oooo
^rrssnie I tS9.Ota 0.0000000 | o-0000000 o.oooooool o.oooooool o-ooooooo
sarlun I lsS. d03 0. 0000000 I 0.0000000 0.00000001 0.0000000 I -0.0001930
BorTrllluru I f fe.0{2 0.0000000 I o. ooo0000 o. oooooool 0.0000000 I 0.0000000
Boron I z{g. G?B 0. o00oooo I 0.0000000 o. ooooooo! o. ooooooo I o. ooo0000
cadmium 1276. Soz 0.0000000 I 0.000oooo o. oo0ooool o. ooooooo I 0. o0oo0o0
cal'eiun Jrrz.933 o-ooo0oo0 | o-0000000 o. oooooool o. ooooooo l 0,0000000
lCa1ctum I 318.128 o. ooo0000 | 0.0000000 o. ooooooo[ o. ooo0000 ] o. ooooooo
Tchroml.um lzdl -TL6 0.0000000 I o. oo0ooo0 0 . 0000000 1 0. 0000000 1 0.001?ooo
cobalr )228.515 0.000oooo I o.0000ooo o.oo0000ol o.oo00o00l 0.0o18ooo
coDper 1324,. 7 53 0.0000000 I 0.0000000 o. oooooool o. ooooooo I o.000oooo
rron I zrg.gco 0. ooooo00 I 0.0000000 o.oooooool 0-ooo00ooI o.0o00ooo
rron lzz 1. {{1 o .0000000 | 0.0000000 o - oooo000J 0.0000000 I 0.0o0oooo
r.ead 1220.353 0.00ooooo I o. ooo0o00 o. ooo00ool o. ooo0o00 I 0.0000000
r.Lthtum 1570.?8t o.0oooo0o I o. o00ooo0 o. oooooool o. ooooooo I o. ooo0000
lragnGrltun lZ7 9.029 0. ooooo00 I o.00oo0oo 0. oo00o00l o - ooooooo I o. oo00000
MangBnGro I zsz. Glo 0.0oooooo I o-0000000 o. oooooool o. ooooooo I o. ooooooo
Molybdenum I 202-030 0.0000000 I o. ooo0oo0 0.0000000! 0.0000000 I 0.000oooo
NLckcl I 231.5 Ar tZ 0.0000000 I o.000ooo0 0.00000001 o-oooooooI o.ooo0000
PbosDhorur 1128.287 0.0000000 J 0.0000000 o. oooooool o. ooooooo I o. ooooooo
Potagrlum l rS5.0g1 0-0000000 I 0.0000000 o. oo0ooool o. ooooooo I o. ooooooo
Bolenl.urn I 196. 090 o. ooooo00 | 0.0000000 o. oooooool o. ooo0o00 l 0,0000000
gtllcon
I ,u1. G12 0.00oooo0 I o. 0000000 o.oooooooI o-ooooooo! o.ooooooo
stllcoa I 251.615 0.0000000 | o-ooooo00 o. ooo0ooo I 0. o00oooo I 0. 0000000
gllvcr
I
gag.058 0.0000000 J o. ooooooo o. oooooool o - ooooooo l o. ooo35{o
Sodiun I saf. sga 0.0000000 I 0.0000000 0, oooooool o. o0oo0o0 | 0. 0000000
,rsodtun I ara .!26 0.0000000 | o-oooooo0 o. oooooool o. ooooooo I o. ooooooo
ltrontlum l{07 .77L 0.0000000 I 0.0000000 o. ooo0oool o. ooooooo I 0.0000000
rhalrlum I rg0. g6{0.0000000 I 0.0000000 o. oooo00ol 0.0000000 I o. ooo0ooo
Comnentg:
STL Denve
Form XI (PART 2)TN
]-45
STL DENYER
Total Metals Analvsis
-118-
ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY)
Contract: IIRS CorooratLon
Lab Coda: STITDEN
rcP ID lhrnber: TiIA
CaBo No. :
Intrepid IeP
gfg hlo. l
Dater I l1,g l2A05
Tllorl.urtr, l2E3 -73O o.o0ooooo I 0-ooooo00 0,00000001 0, ooooo0o l o. ooooooo
rln | 189.989 0 - 0000000 I o, oooooo0 o.oooooool o.0o0o00oI o-ooo00o0
TLraaLrrn I Sf n. g{1 0-ooooo00 J 0.0000000 0. oooooool 0. o0o0ooo I o. ooo0ooo
uranlum I 385.958 0.0000000 | o. oo0o000 0,00oooool 0.0000000 I 0. o00oooo
vanadlum lZlZ.toz 0.0000000 I o.0000000 0-oooooool o.oooooool o.ooo41oo
zl,nc I zrr. g16 0.0000000 I 0.0000000 o-ooooooof o.o0oooooJ o-o0o000o
D5r130198
a47
Coaunontg:
STL Denve
For:rr XI (PIRT 2)rIN
STL DENYER
Total Metals Analvsis
-118-
ICP INTERELEMENT CORRECTION FACTOR,S (ANI\ruALLY)
Contraet. r URS Cormorats'ion
r,ab Codc: g111trDEN
ICP ID Inrmbar: TiIA
Caro ![o. r
lntrepld ICP
gAg No, :
Date: 8 l1.gl2005
sDc No.; D5I130198
Wave-
length
(nm)
fnterelernent Corrcetl.on Factors for r
ZN
.rrralrrtro ThT1uv
I 33e,198 o. ooooooo I 0.0000000 o. oooooool o. ooooooo I o. o319oo0
rlrrnlnum I 167 .081 0.0000000 I 0. oooo00o o.ooo0o0ol 0.00000001 o.ooooooo
Ilrrmtnutr I30g.27A 0.0000000 J o. ooooooo 0.00000001 0.00000001 o.0oooooo
rntLmoru, I zOG. B3E 0.0000000 I 0. oo00ooo 0.00000001 o. ooooooo I 0.0000000
trsealc I 189.042 0.0000000 | o. 0000000 0.00000001 o. o000ooo I 0.0000000
Barir:m I d55. {03 o. 0000000 | o.000oooo 0.00000001 0.0000000 I o. ooo3o3o
Borlrlllusr Ifff.042 o - 0000000 I o. oooo000 0.0o03seol 0.0000000 I -0.0000100
Boron lzog.678 o-0000000I 0.00ooo0o 0.0o0ooool 0.0000000 I o.ooooooo
Cadmlum 1225. I02 0.0oooooo I -0. 0002070 o.ooooooof o-oooooo0I 0.0000000
calcLr:m Jfrz,933 0.0000000 I o. o000oo0 0. oooooool o.0oooooo f o, o00oooo
lEalctum Iare.128 0.0000000 I 0.0000000 o - 00000001 o. oooo0o0 | 0.0559000
ltronlun lzez .7L6 0.0000000 [ o. 000?060 0. o00ooooJ o. o0ooooo I -o. ooo59?0
cobalr lzze.6l6 0 - ooo0000 I o. ooo000o 0, oooooool o. o0oo0oo I 0.0000000
Coppcr I 32{.753 0.0000000 | o. oooE{2o 0.0ooooool 0,00000001 o.oa232oo
rron I 259.9d0 0.0oooo0o I o,0o0ooo0 o.oooooool o.oooooool o.ooooooo
rron lzl 1.{41 0.0000000 I 0.0000000 o. oooooool o. o0000oo I o.00o0ooo
r-,ead ,?20-353 o. 0000000 I 0. ooooooo 0,00000001 o, o0ooo0o l 0.0000000
rittriurn ler 0. ?B{0.0000000 J 0.0000000 0.00000001 o.0o0oooo J 0. oo00o00
Magnesr"rrn J2r9.079 0.0000000 I 0.00?5500 0.0000000f 0.0000000 I -0.0{18000
Mangrancse I zsz. Glo 0.0000000 | o-oooI,22o -0,00016801 0.00000001 0.0000000
Nolybdenun IZOZ.030 0. 0000000 I -o - 0007050 0. ooooooof 0.0000000 I 0.001?so0
Ntckol lrrl-6a4t2 0.0000000 I o. ooo0000 o . ooooooo l o. oo0o0oo l o.00o0o0o
Ph,oaphonrs ltr8.28?0.0000000 I 0.0000000 o - ooooooo I o. ooooooo I 0.0000000
PotEaslunr |.766. {91 o. 0000000 I 0.0000000 o. oooooo0l o. ooooooo | 0.0000000
BelenLtun I rse .090 0.0000000 | o. o000ooo o. oooooool o. oo0oooo | 0 - 00ooooo
gtlLcon lrol.612 o. oooooo0 | o, o0o000o o - o0oooo0 I o, oooo0o0 I o. 0oooo00
gilLcon
l rul. G1s o.0000ooo I o.00o00oo 0.o0ooooof o, o0ooo0o I o. o0ooooo
911var I 32g.OGB 0,0000000 I -0.0002200 -0.01{90001 0.0000000 I 0.0006880
sodlurn I U99.592 0.0000000 I o.0000000 o . o0000oo l 0, o0o0ooo l o. ooooooo
forlhun I aru,326 o. oooo0oo | 0.0000000 o. oo000ool 0. o0ooooo I o. ooo0000
]ront,lum IcOz .77L 0.0oooo00 | o.000oooo 0 . 0oooooo I o. 0000000 I o. ooooooo
rhalltum I 190.9G{0.0000000 | o.0000000 o. oooooool o. ooooooo I o - 0000000
comncnts:
STL DCNVC
Formr XI (Pnnt 2l -IN
14I
STL DENYER
Total Metals Analvsis
-118-
ICP INTERELEMENT CORRECTION FACTORS (ANNUALL9
Costract:
Lab Coder STIrDml Carc No. t grg No. r
ICp rD lrrntbar: 1I.{IA Intrepld Iep Dater I ll,glz00s
comrant$:
gDo !ro. r D5I130198
l[horLuu I 283 - ?3 0 o. o00o00o I 0.0155000 o, oooooool 0.0000000 I o. ooooooo
rin I to9.9o9 0. 0000000 I 0,0000000 o. oooooool o. oo0oooo | 0.0o0oooo
rl.Eanirrn I 33{.9{1 0.0oo0ooo I o. ooo2g5o 0. o0ooooo I 0.0000000 I o. oo0oooo
urauLrm 1385.958 0.0000000 J o. oooooo0 o. oooooool o. ooooooo ] -0.028?000
vanadlrrm I292-4oz o. 0000000 I -0.0 oo2{2a 0. o0ooo00l o. oo0oooo | 0.0015600
zlnc I 2x3. Bs6 0.0000000 | 0.0000000 o . ooo0oool o. ooooooo I 0.0000000
STL Denvef
-IN
L49
For:m XI (Plnr 2l
STL DENVER
Total Metals Analvsis
_ttA-
O rcp TNTER.ELEMENT coRRECrroN FACT,RS (ANNUALL,)
CoDtract: IIRS Cgrrcoration ,
LaI) Codet S:I1LDEII Cara NO., _ Stg No.. _
rcp rD luElbor: SITPERTRACE Datc: 7l23l2tos
gDo No. r D5I130198
^[n..al1t6
I{ave-
leagth
(nm)A1
Intgrelaurcnt, Correction ractorr
Ca Fo
for:
Mg Agr
.lrlumlfirm Igo8.21s 0.0000000 I o.000oo0o o.oool1ool o.0ooo29ol 0.o0oo0oo
r,ntimony I 206.838 o. ooo0000 I o.0000ooo o.oooo220l o-oooooooI 0.0000000
rlrsenlc I189-0{2 0.0000000 I 0. ooooooo -0.00001601 0.0000000 I 0.0000000
Barl,um l {93 .409 0,0000000 1 0.0000000 o. o000oool o. ooooooo I o. ooo000o
Bcrrrlltun 1313.042 o. oooo000 I 0.0000000 o.ooo0oool o-oooooool 0.0000000
Boron l2ag.6?8 o. 0000000 I 0. o0ooooo -0.0o0o7ool 0.0000000 | o.0000000
Cadmlum lrr5. i02 0.0000000 J 0,0000000 o.0oo1{101 0.ooo00ooI o.ooooooo
calcl,usr If rS.933 o-0000550 ! o.0000000 o . oooooool o. ooooooo I o. ooooooo
chromLrrm 1267 -?LG 0.0000000 I 0.0000000 -0.00001001 0.0000000 I 0.0000000
cobalr 11228.515 0.000oooo I o.00ooooo 0.00000001 o. ooooooo | 0.0000000
{onnar I rzc .7s3 0,0000000 I o.0000000 -o - oo0025of 0.0000040 I 0.0000000
fron 127 1. {{1 0.0000000 I o. o00oooo 0.00oooool o.00o34oo I o. ooooooo
r,ead 4220. 3 5L/ L o. ooo2g70 J o.0000000 o.oool3ool 0.0000060 I o.ooooooo
Lead lrro-3sLta -0.0001800 | o-0000000 o. oooo6ool o. ooooloo I o. 0oo000o
MagnerLum lZ79.028 0,0000000 I 0.0000000 o.ooo02?01 o-ooooooo| 0.0000000
Manganoss lZsl - 610 0,0000000 I 0.0000000 -0.00000501 0.0000200J 0.0000000
uolvbdcnur I ZOZ.030 o.0000000 | o.0o0oooo -0.00001801 0.0000000 I 0.0000000
rsickex. 1231,50at2 0.00ooooo I 0.0000000 o. ooo0000l o - ooooooo I 0. 0000000
€lelenLum Itg6.OzLtL -0.0000030 I 0. oooo000 o. ooooozol o. ooooo4o I o. ooooooo
sclenium I 195.02L12 o.0000000 I 0-oooo0oo -0.00017801 0.0000000 I 0.0000000
sillcon I eg8. 158 0-0000000 ! 0.0000000 0.00000001 o, o0oo000 l 0,0000000
BLlvor I fr8.068 0.0000000 I 0.0000000 o-oooooool o.oooooool o'ooooooo
gtrontLum l{21.552 0.0000000 | 0.0000000 0.00000001 o.o0oo00ol o.o0o0o0o
Thall-lurn I 190.86{0,00000001 o-00o0ooo o. oooo95o I o. ooooooo I o.0oooooo
Ttrorl,um l{o1.910 0.0000000 I -0. oooo250 0.00000001 o.oooooooI o.ooooooo
rLn J rr9.989 0.0000000 I o-o0o00oo o - ooooooo I o. ooooooo I o. ooooooo
rltaaLum I 33{.9d1 0.0000000 I 0.0000000 0.0ooooool o. o00o2o0 J o, oo0oooo
uranitrn I 3B5.gs8 0.0000000 I -0.0000300 o . 0008600 I o. ooool{o I o. ooo0ooo
vanadlum l rgz.tLz o. o0000oo I o. ooo0o00 -0.0003{00[ 0.0000000 1 0,0000000
zlnc I zrr. gs6 o - 0000000 | o. 0000000 o . ooooooo J o, ooooo2o I o. ooooooo
Comments:
STL Denve
Form XI (PART 1)-IN
150
STL DENYER
Total Metals Analvsis
-I.1B-
ICP INTERELEMENT CORRECTION FACTORS (AIYNUALLY)
Contract.r [IRS Cormoration
Lab Coda3 STITDEN Caeg No.:gAg No,:
ICP rD lnrmbar: SUPERTRLCE Dato t 'l l23l2OOS
sDc No.3 D5I130198
f,nalft,e
wavo-
longrth
(no)Ls
Interelement Corractlon Eaetors
BBa
for r
BA cd
rlunLaum, I 308.215 0.0oooooo I 0.0000000 o, oooooool o. ooooooo I o - ooo0oo0
Antl.rnony I 206.83I 0.0000000 I o. o000ooo o.oooo0ool o-oooooo0 l 0.0000000
Ananie I 1S9.04?0.0oooooo J 0.0000000 o. 0ooooool o .0000000 I 0. o00oooo
Barium I og3 .409 0 - 0000000 J o. oo0oooo 0.ooo000ol o-oooooooI o.ooo0o00
serylllun ! sra.0{2 0.0000000 I o. oooo000 o,oo00oool 0.0000000 I o-ooo0ooo
Bororr 1249 - 628 o. ooo0000 | o. o00oooo o. oooooool o - ooooooo I o. ooooooo
cadmium lZZ6- 502 0.0000000 I o.0o0o0o0 o. ooooo00l o. ooooooo I o. ooo000o
calelun 1 319.933 0,0000000 I o. o000ooo o. oooooool o. ooooooo I o.0000000
Ctrroml,un lZ6z. zlo 0. oooooo0 I 0.0000000 o. oooo000l o. ooooooo I 0.0000000
corralr 1228.615 0-0000000 I o,000o0oo -o,00120001 0.00oo000 I 0.0000000
copper I sal. z53 0.0000000 | o. ooo00o0 o.0oo0o0o[ 0.00000001 0.0o0oool
rron lrr 1. {{1 0.0000000 | 0.0000000 0. ooo0ooo! o. ooooooo I o - oo0o000\
Lead lz^0.3 SL|L 0.0000000 I 0.0000000 o. ooooo0ol 0.0000000 I 0.0oooooo
Lcad I 220-35L12 o ,0000000 | o.0oo000o o. o0000ool o.0ooo000 I 0.00oooo0
!&rgrnGrLun lzz9.07I 0.0000000 J o. ooooooo 0. oooooool o. ooooooo I o. ooooooo
trangancso l2Sz. 510 0,00ooooo I 0.00ooooo o - ooo000o I 0.0000000 I 0. ooooooo
Mol.ybdGnrrtrr I aoZ . 03 o o - 0000000 I 0. o00oooo o. oooooool o. ooooooo I o ' ooooooo
uLckel lzsl,60tt2 0.0000000 | o-0000000 o. oooooool 0,0000000 I 0.0000000
Oelenl-uu 1196.02L1L 0.0000000 [ 0.0000000 o. oooooooI o. ooooooo I o. ooooooo
SelenLuur I196.02tt2 0.0000000 I 0.0000000 0.00000001 o. ooooooo I o. ooo000o
silLcon I 2BB.1SB o .0000000 I 0.0000000 o.oooooool o.0oooo0o I o.ooooooo
gl,lvcr
I 329.059 0.00oooo0 I 0. ooooooo 0. ooo0oool 0.0000000 I o. ooooooo
Strontium lc,21. Esz 0. oo0oo00 I 0.0000000 o.00000001 o. ooooooo I o. ooo00oo
1rballlum I tro. g6{0.0000000 I o-0000000 o. oooooool o. ooooooo I o. ooooooo
rhorlum I t01.910 0.0000000 I o, ooooo00 0. 00ooooo I o. ooooooo I o. ooooooo
rtn 1199.989 0.0000000 I o. o0oo00o o. ooooooof o. oo0oo0o I o. ooo0ooo
ritanLum I 33{.9{1 0.0000000 | 0.0000000 o. oooooool o- 0000000 | o. oo0oo0o
Uranlurn l rrt. ess o. ooo0000 | o.0000ooo o. ooooooof o. o0oo0oo I o. o0oo000
vanadlurn lzsz ,4oz 0.0000000 I 0.0000000 0.00000001 o.oooooooI 0.0000000
ztnc I arr. Bs6 0.000oooo I 0,0000000 0. 0000000 I 0. 0000000 I 0 . 00000 001
Comcntg r
STL Denve
2lForm xI -IN
151
STLDENWR
o
Coatr act s URg Co::rroration
Total Metals Analvsis
-1lB-
ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY)
Case gAg No. r
Date t 7 12312405
f.Ab
ICP
Codo s S15TDEN
ID !tunberr SUPERTRACE
gDg No. r D5I130198
^nlaly'te
wavG-
lcngth
(nm)Co
Intorelgncnt Correction Factorr
Cr gu
for:
It1n Mo
rlurattrum I
gO8.21E 0.0000000 I 0.0015000 0.00000001 o. ooooooo | 0.0058500
rntlmony I ,06.838 0.0oooooo I o,003gg0o 0.00000001 o-o00o0o0I -0.0055500
rrgenLe I ras .Aaz 0.0000000 I 0.0001700 0. oooooool 0. ooooooo I o . oo031oo
Bar1un Ilss.{og 0.0000000 | 0,0000000 o - oooo0o0l 0.0000000 I o. ooooooo
noryllLurn I afa .A42 0.0000000 | o. ooooooo 0.00000001 o.oooooool o.ooooooo
Boron |.249.679 0.0009800 J o. ooooo00 0. oooooool o, ooooooo l 0.0000000
cadmlun leZ6.s02 -0.0002200 I 0.0000000 o.oo0ooool o-0ooooool 0,0000000
calcLurn I3X9.933 0.ooo00o0 I o_0000000 o.oooooo0l o-ooooo00I 0.0000000
Ctrroral,un |zSz.7L6 0.0000000 I o-0000000 0.oo00oo0l 0-0000000 I -0.0001700
cobalt I 228.615 0.0000000 | o.0oooooo o. ooooooof o. ooooooo J o. ooooooo
acoDnar lna - 753 0. o0o00o0 I 0.0000000 0.00000001 0.00000001 o,0oooooo
/ron lrr :.. c41 o. oBBogoo I o. o03ogoo o. oooooool o. ooooooo I o - ooooooo
Laad lzz0- 3 sL/L -0.0020470 I 0.0000000 0 - 00oo00ol 0.0000000 I -0. 0009600
r,ead lrz0 - 3 5t t2 0, o0ooooo l 0.0000000 0.00000001 0.0000000 I -0.0002500
MaguesLum lz7 9.07I 0-0000000 | o-0000000 o. oooooool o. ooooooo I o. oo0oooo
Manganorc I asz.610 0.0000000 I 0.0000000 o. oooooool o. ooooooo I o - ooooooo
Molybdarrum |zOZ.030 0.0000000 I 0. o0o00oo o . 0000000 I o. ooooooo I o. ooooooo
Nlckol I 231. 6 A4 t2 -0. 0006200 | o. 0000000 o - 00000001 0. ooo00oo I 0.0000000
Scleotum l rgo.0aLlL 0.0005000 I 0.00ooooo 0.0000000 I o. ooo3soo I 0.0000000
sclenl-um 1196.02L12 -0.0001500 I o-0000000 o - oooooool o. ooo22oo I o. ooooooo
gtlicon Ire8. 1sB 0.0000000 ] 0-0000000 0.00000001 0.0000000 I -0.00d3{00
silwer I 3aB.OGB 0.0ooooo0 I 0.0000000 o.oooooool 0.00000001 o.ooooooo
Stront,lrrn I 4e1.552 0.0000000 1 o,0000000 o.ooooooo] o.oooooool 0.0000000
Thlllium I 190.86{o-001-7t701 0.0002900 0.00000001 -0.00{77001 0.0000000
IborJ.um I oO1,910 0.0000000 | o-0000000 o,oooooooI o.oo5o28oI o-ooooooo
Tin I ras.ggg 0.0000000 J o,000oooo o.oooooooI o.oooooooI o-ooooooo
rLtanLum l fr{.9{1 0.00ooooo J 0.0000000 o. oooooool o. ooooooo I o. ooooooo
uranlun I
ga5. 959 0.0000000 | 0.0007600 0.00000001 o. ooooooo I 0.0000000
vanadlum lZlz -{02 0 . oooo000 I -0. 0008?00 o. oo00ooo I o.0o000oo I 0. 0o0oooo
zLnc l213.BsG 0.0000000 I -0.0032900 o. ooo0ooo I o. ooooooo I 0. ooo0ooo
Coments r
STL Denve
Fo:mt XI (PAnt 2l .IN
a52
STL DENVER
Total Metals Analvsis
-118-
ICP INTERELEMENT CORRECTION FACTOR,S (ANNUALLY)
coDtractr tlRS CozrroratLon
Lab Code: S11DEN Care No.3 g.trg No. r
ICP rD lltrnberr gIrPERTR.e,cE Date 2 7 l23l2OO5
Dsr13 0198
rnalft,e
Wave-
lengrtb
(am)Ni
IntGrelcurcnt Corrcctlon Paetors
Pb gb
for:
Se si
.l,lrrntnum I308.218 0.0000000 | o.00oo00o o. o0oo000l o, ooo0o00 l o - ooooooo
rutl.mouy I 206.838 0.0000000 | o.0000000 o. oooooool o. ooooooo ] o. ooooooo
rrronic I 189.042 0.0000000 I 0,0000000 o. oooooool 0 .00ooooo l 0.0000000
sarlr:rn leg3.{09 0. oooo000 I 0.0ooooo0 o-ooooo0ol 0.00000001 0.0000000
Bcrvlll,qm 1313.0{2 0.0000000 I o-0000000 o.000oo0ol 0. oooo000 I 0.0000000
Boron I'19.578 0.0000000 | o-oo0oooo 0. oo0oooo! o, ooooooo l o. ooooooo
cadmLrrn 1226. 504 0.0oooo00 [ o.0o000oo o. oooooool 0.0000000 I 0.0oooooo
Cal.cluur I rrs.933 o-0000000 I 0.0000000 o. oooooool o. ooooooo l 0, ooooooo
Chroml.rrm I a07 .TLG 0.0000000 I o.00ooo0o o. oooooool o. ooooooo I o . ooooooo
cobart, lz,z8.616 0.00027?0 I 0.0000000 0.0ooooooJ o.ooooo00| 0-ooo000o
Copper I rzc. ?s3 0.0oooo0o I o. oo0oo00 o. oooooool o, ooooooo l 0. ooooool
rron lzr 1. {{1 o. oooo000 I o. o000oo0 o - oooooool o. oo0000o I o. o000oo0\
r.cad lzza.3SltL -0.00011100 I 0.0000000 0.00000001 -o. oo0o20o I -0 - 0001020
r,oad 122.0 . 3 sr.t 2 0.00006{0 I o. o0o0o00 0.00000001 -0.0001400 I -0.0000370
Dtagnerl,unr lZZ9. 0?8 o.0000000 J 0.0000000 o . oooooool o. oooo00o I o. oo0ooo0
Mangaaorc ]251.510 0. ooooo0o I 0.0000000 o. oooooool o . ooooooo I o. 0oooooo
uolybdanun I 202.030 o. oo00o00 I o.0000000 o. oooooooJ o. ooooooo I o - ooooooo
rqlchel 1231.6A4/2 0.000oooo I o. o0o0ooo 0.00000001 o. ooo00oo l 0,0000000
gel.eni.un 1196-oaL/L 0,0oooooo I 0.0000000 o. ooooooof o. oooooo0 I o - 000x000
Ealcniun I 195. 0 2L 12 o.0000000 I 0. o0oo000 o. oooooooJ 0. 0000000 I o. o0ooooo
stlLcon I ,98.158 o.0000ooo I 0.0000000 o-ooooooof o-oooooool o.ooooooo
$ll.var I 328.068 o.ooo0000 I 0.0000000 o-oooooool o.ooooooof o-0000000
st,rontirm ll21 .552 0.0000000 I 0-0000000 o. oooooool o - ooooo0o I o. oooo0oo
rr.ht.lll,um Irgo-86{o. ooo000o I o.0000000 o. oooooooJ o. ooooooo I o. ooooooo
rhorium l {01.910 0.0000000 I -0.000{200 o.ooooooof o.oooooool o.0oooooo
rin I 199.989 o. o000oo0 I 0.0000000 o.o0oo000J o,oo0o0ool o.o0o0o00
Dl,tanLum I 33{.9c1 o. oo00o0o | 0.0000000 o.0o0o0oor 0. ooo00oo I o. ooo0ooo
uranitrm I SA5.9s8 o. oo0o000 | 0.0000000 o.0o000ool 0.0000000I o-ooo0ooo
vanadlnrn lZlz . t}z 0.0000000 | o.00oo0oo o. oooooool o. ooooooo ] o. 00o0oo0
zlae I zra.855 0.0000000 | 0.0000000 0.00000001 0.0000000 I 0.0000000/
Cotmcntg:
STL Denve
Fornn Xf (Penf 2)EIN
153
STL DENYER
Contract I URS Cor:noration
Total Metals Analvsis
-1LB-
IC P INTTRELEMENT C ORREC TION FA CTORS (A N I\ruA LLY)
Case No. r gAg No. r
Date: 7 l23l20$s
Lab Codc: STITDEN
ICP ID Ifir[tITCT: SI'PEHPBACE
gDG NO. r D5I130198
rrraLyEa
Wavc-
I-enorth
(rn)
Intaralament correctlon raotors
Er TL
forr
T}USn
Alurninrrm 1308.215 0.0000000 | o. ooooo0o 0 .00000001 0.0000000 I -0.001{t000
AntLmony I 206-83I o-0000000 I o.0000000 o. ooooooof 0.0000000 J 0.0000000
lrsealc I 1S9. otz 0.0000000 | o.0000000 0.0000000f o. ooo0ooo I o. ooooo0o
BarLrrn I {93 .809 0.00ooooo I o.0000000 0.o0oooool o.0ooooool o-o0ooooo
serarlllqm Iffa.A,,2 0-0000000 I 0.0000000 o - oooooool o. o0ooooo I o. ooooooo
Boron lzt9.6?8 o-0000000 I o.0000000 o.oooooool 0-0000000I 0-0000000
cadrnh:n 1225.502 0.0oooooo I o.0o0o0o0 o. oooooool 0.0000000 | 0.0000000
Calclr:m lrrS.933 0.0000000 I o. ooooooo 0.00000001 o-oooooool 0.0031000
Chroml,um Iaez.715 0.0000000 I o.0000ooo 0.00000001 o.oooooool o-oooeloo
Colralt I ,r8.516 0.0000000 I o. ooooooo o.0o24a0o J o. oooooo0 I 0.0000960
..coDgar I aal. zs3 0.0000000 ! o.00o00oo o . oooooool o. ooooooo I 0.0006300
/ron |271 . {{t1 0.0000000 | o-ooooo00 0.00000001 0-0000000 I -0.0o2r000
Lcad 1220.3 SL|L 0.00ooooo I 0.0000000 o. ooooooof o, ooooooo l o. 0010060
Lcad 1220 .3 sLlZ 0.0000000 I 0. ooo00oo 0,00000001 o. ooooooo | 0.001{5oo
![agrnosr,um lz?g, ozg o-0000000 I 0.0000000 0.00000001 0.00000001 -0.01{{000
Mangan€rc 12s7. G10 0.0oooo0o I 0.0000000 o.oooooooJ o.ooooooof o-ooo13oo
Molybd€nlrm lzoz.030 0.0000000 I o.0o0oooo 0.00000001 0.0000000 I -0.000e100
Nlchel 1231.6A112 0-0000000 I 0.0000000 0. 0000000 I -0.0009{00 I 0.0000000
gelexrium I 196.021 1L o. oooooo0 | o. ooo000o o.ooo000of 0,00000001 o-ooo08oo
scleaLurn Itg6.0eLt?0.0oo00oo I o. oooo00o 0.00000001 o.ooo0o0o I o-ooooooo
gtlLcon
J 288.158 0.0312600 I 0-oo0o00o 0.00880001 o-oooooool o.ooo8{oo
sLlwer I328.oEB o.0000000 | o. oo0o0o0 o. oooooool o. oo000oo I 0.0009300
EtrontLum I {21.552 0.0000000 I o.0000000 o.ooo00ool o,oooo000l 0-0000000
rhalll.um I tro. BGd 0,0000000 I o. o0ooooo o. oooooool o. ooooooo J o. ooooooo
trhorl"um l {01.910 0.0000000 | o. ooo00o0 o. oooooool o. oooo000 I o. oo233oo
rla
J 189.989 0.0000000 I o.0000000 0.0oo0oo0l o, ooooooo l o. ooooooo
rLtaalum I 33{.9{1 0,0000000 I 0.0000000 o-oooooool o.ooooooo I o.ooo3ooo
uranitrm I 38s.9SB 0. ooooo00 I 0.0000000 o. oo0ooool o. ooooooo I o. o00ooo0
vanadlum lzlz.lOZ 0.0000000 I 0.0000000 0.00052001 0-0000000I -0.0000600
zlnc I zrt. gs6 0. ooo00oo I o. oooo000 o. oooooool o. oooo0oo I 0. ooo0ooo
Corurrentt r
STL Denve
Form XI (Penf 2'l rN
154
STL DENYER
Total Metals fuialvsis
-trB-
lcp TNTERELEMENT CORRECTION FACTORS (ANNUALLY)
contract,:
I,ab Code s STLDEN cage No.:glg No. r
IeP ID !fimberr 8UPERTRI,CE Dato t 7 l23l2$As
Cormentt r
gDO DrO. t D5I130198
enaltt,cr
Wave-
leagth
(nm)
rntcralcmcnt CorrectLon raetoru for:
Zro. ffhv
rlumtmrm I s08.215 0.0215?00 I 0.0000000 o . os061oo I
rntimony I 306.939 0-0000000 | 0.00ooooo o . ooooooo I
lrrer.Lc I189-0{2 o .0000000 I 0.0000000 o - ooo00o0 I
rarLum I ls3. {09 0.0000000 1 o, ooo0ooo o . oooo0o0 I
sery,lliun Irrr.04?0. ooo18o0 | o.000o0oo o . oooo000 I
Boron lro9-679 o. oo0000o | 0.0000000 o . oo002oo I
Cafrnl,um lzz6. soz 0.0000000 I o,0ooo00o o . 0oooooo I
Calclum I arf.933 o. ooo0000 I 0.0000000 -0 . 00177oo I
Chrornirrn lz6z.TLG o, ooo0000 l 0.0o0ooo0 o. o0oooool
cobalt lzz8 - 515 0.0000000 | 0.0000000 o . oooo0oo I
CoDpcr l*a.253 0-oooooo0 I 0.0000000 o. oo2lsool I Irron lrrl-{t{I.-0.53{?500 I O-O00oooo o. oo4575ol I '
Lead |.?,20.3 SLIL 0.0000000 | o. o00o0oo -o . 003 560o Iread lazo.3 SLtz -0.0003200 I o. oooooo0 o . ooooooo I
!fiagErcrLrrn lrrg. or6 0. ooooo00 I 0.0000000 o - oooo000 I
t.iangranoro 1257-510 o.0000000 I 0. oo00o00 o . ooooooo I
Ifolybdanrun IZOZ.030 0.0000000 I 0. ooooooo o . oo0oooo I
NLclsel 1231.60412 o, ooo0000 I o.0000ooo o - ooooooo I
Sa1enl.um l195.ozLtL 0.0002100 I o-ooooooo -0. a2793oo I
scLcnltm Itg6.AzLlZ o. oooo000 I o. 0000000 -0 . oooz{oo I
gtll.con lz8B.1I8 0.0000000 | o.0000000 o. o0007oo IgLlvcr lrr8-068 0.0000000 I 0.0000000 o - ooo3{90 |
Strontlum llrl.552 0.0000000 I 0-0000000 o . ooooooo I
rlralll,um Ifto.86{0.0 oLL7 00 I 0.00ooooo -o. ooo17ool
rhorium I oOt.910 0.0002000 I o.0oooooo o. 0000000 I
rln 1189.989 0.0000000 I o-0000000 -0. ooo33ool
rltanlun I
gr{. il1 0.0000000 | o-0000000 o . ooooooo I
uranl,urn 1385.958 -0.0090700 I 0.0000000 o. ool2oool
Vanadlusr lrrz.taz 0.0000000 I 0,0000000 0 . oooseoo Izinc I err.856 0.0000000 | 0.0000000 0.0000e30f I t
STL Denvc
,IN
155
Fom. XI (PART 2l
STL DENJ/ER
o
Cou
I.tb
ICP
Stf,IlEN Case
ID Numberr Tiltr' Ia,trcDtd rCP
Total Metals Analvsis
-17-
ICP LINEAR RANGES (QUARTERTTO
gl'g No. t
Drtcr 8 lLGl?AAs
sDG No.: D5I130198
trrot r
Codr:
[rRg CorryoratLon
.Lrrrlytc
Integ,
Ti.nc
( 8cc. )
Conetatntl,on
(nslt)I{
f,],unl.num to 50. oo 1 P
leJ-*inun Ei I 20.00 10 00 In
JCrlol.um Lo 20.00 50 fr
ICa1clr:m Ht 20.00 2000 fr
lPotrsrlrur 20.00 500 lr
IMaOac;l,urn 20.00 2 000 Jr
Jsodl-um Lo 20 .00 10 Ir
f sodiun HL 30 .00
Zlrconiun
10000
50
Ir
,mtontl r
STL Denver Fonn ITTI IN 156
STL DENIIER
Corrtrrots r
IJaID Codc r
URS Cor5loration
StfrDEN Cuc No. r
Total Metals Analvsis
-12-
ICP LINEAR RANGES (QUARTERTY)
SAS No, 3
Drtc t 7 l?,? l?OOs
8DO ilro. r D5r130198
ICP ID !!\rnbrrr ST,PERTRTCE
^lnalltc
fntoef .
rlnc
(Sac. )
ConcentrrELou
(uglr,)u
I nracnLo 15.O0 20 lr
f aarl"un 15.00 25 Jn I
lC1rronLun 15 .00 50 Ir I
I Copper 15 .00 50 In I
I Lcad 15. OO 100 lr
I Niokcl 15.00 50 In I
I Sf lrrcr - I 15.O0 I Ir
JvrnadLun 15-OO 50 Irl
I zinc 15.00 s0 fr
Comcnt;r
STL Denver EoTm XII IN L57
STL DENI/ER
O
Contnc
Totd Metals Analvsis
-12-
ICP LTYEAR RANGES (OUARTERLY)
tr URS Corporatlou
ICP ID ltrmbcr: pB ICpldS Datar 8lLg/2005
SDO ![O. 3 D5I130198
Inalrtr
Integr.
TLurr
(8rc. )
Concantration
(ng/r,)
D[
IcaaurI.rrn J 0.001 [ a Iu I
I Sr1rlnium [ 0.001 J I Iu I
Jo"*"rt,s;
STL Denver forn XII I IN 158
STL DENYER
Total Metrls Analvsis
-13-
PREPARATIONLOG
Cont,ract r
f.ab Codc:
ucthod: P
t RS Corporetion
STLDEIT Ceatl No. r fll.S No.:gDo truo. r D5I130198
PrcD ![cthod:
Aery>Lc fD Prrplratl.on Datso
rnLtiel Volumc I rinal
I volunc (nlr)
Grg-BvIg?-o912 05 91261200s 50.0 I 50. o
GI9r-B$ro 1- O 912 0 5 9126/200s 50,0 I 50.0
qfl-Bwoz-o912 05 9l26laAAs 50,0 I 50.0
Girr-BIiFo2- 0912 05 I'ISI 912612005 50.0 I 50-o
gw-Bwo2-091205 DtSD e l26l200s 50.0 I 50.0
MtrRl,-tlB ac 9t26t200s 50,0 I 50.0
LIB IIS 9126 t2005 50.0 I 50-o
I.}B MSTD e/2612005 50. o I 50.0
u8s266567 912612005 50.0 I 50.0
eEECr stt@Lr 9/261200s 50.0 I 50. o
DUPI{ICLTE CHECX el26/200s 50.0 I 50.0
Coruoentr:
STL Denver
Forn XIII a IN
159
STL DENI/ER
Total Metrls Analvsls
13-
PR.EPARATION LOG
Contrtot r
Lrl, Codc r
Mcthodr P
t Rg Corgora.tlon
SlDLDEN Care Nrl. r g}.g No. r SDO !fO. r D5I130198
PreD Uothodr
flaqrlo ID PrcDrratl,on Date
rnLtLrl. vol.rrnc I rLnal.
I volunc (Brr)
9 t281200s 50,0 I s0,0
GTI-BW01-091205 9t281200s 50.0 I 50.0
GT[-BIr[02 - 0912 O5 9 t28 t2005 50.0 I 50.0
@r-Briro2 -091205 Ms 9 1281200s 50.0 I 50. o
glr-Br{02-091205 DrsD 9l?s 1200s 50-0 I 50,0
MBs2 55557 912812005 50.0 I so. o
CIIECX SN{PI,E 912812005 50. o I 50,0
DUPLICf,TE CHECK 91zIE12005 50.0 I 50,0
Comrnentr I
STL Denver Fom XIII IN
150
STL DENYER
Total Metals Analvsis
13-
PREPARATIONLOG
ConEract r
Lab Codcr
Mcthod.:
IIRS Corporation
STf-DEN Carc IIo. t gfg No. r
ev Prop Matlrod r
9engllc ID PrrprraElon Dato
faitLal Volumo I rLml
I vo1umr (nL)
GI![-B$r92-091205 9130 1200s 10.o I 10-0
G9[-BI'I92-091205 US 9 /30 12005 10.0 I f0.0
GI{-BSr9 2-09120 5 !figD 9130 /2005 10.0 I 10.0
GIflf-BIlIO1- 0912 0 5 9 /30 /2005 10.0 I r0.0
@r-BItIO2 - 0912 0 5 9 t30 t 200s 10. o I 10.0
@r-BIr[02-091205 US 9130/200s 10. o I ro,0
GIfi[-BuIO2-0914O5 MgD 9l3A 1200s 10.0 t 10. o
MB52 69{ 9 5 9130 1200s 10, o I 10.0
CIIECX( SAIIPIJE 9 t3A t 2005 10,0 I 10.0
D3r130198
151
Coluoantse:
STL Denver
trorr XIII - IN
STL DENYER
rotal *.];::
^"olvsls
PREPARATIONLOG
ContrrcE r
r.,ab Codr:
MctsIrod, r
IIRS Corporetion
gTfrDEN Cage No. r S.LS No.:sDo No.: D5I130198
Prrp Mcthodr
Sary>Ie ID PrrparatLon Date
Ini-El,aJ. vol.ttno I rt nal
I vol.urac (nr.,)
GIIiI-B[rr92- 0912 05 e /261200s 50.0 I 50.0
G!{-BUro1- 0912 05 9 1261200s 50.0 I 50 ,0
GTr-Br{o2-O912 05 9126tZ^005 50. o I 50.0
Gil[-Bqloz- 0912 05 Msl 912612005 50.0 I 50-0
GIW-Bur02-0912 05 ![gD 912612005 50. o I s0.0
IM[R.a,-LAB aC 9 126 /2005 50.0 I 50,0
LI.B MS 912612005 50. o I 50.0
f.AB USD 9 t2612005 50.0 I 50.0
M8526655{9126t2005 50. O I S0,0
CEECX gtltPr,E 9 12612005 50.0 I 50.0
DIIPLICATT CIIECK 91261200s 50.0 I 50.0
Connenta r
STL Denver
Foru XIII IN
1,52
STL DENYER
Total M.:ils Analvsis
AI{ALYSIS RT]N LOG
Contract, r
I,ab Code :
Iaatsrrrnrnt
Start DaEc:
IrRg CorporatLon
gT[,DEN
fD !firnbor:
9 177 1200s
Cagc tilo - r
TJA InrrapLd, ICP
S.}A No. r
Dlcthodr
gDc No.: D5f130198
t - Dcnoter ad0Ltional clenents (otber
STL Denver
EI].d Drt,r r 9 127 l2AA5
bhan tho rtaudlerd eLP rhurat,r) ar. reDrercuted on lnothrr Fonu 10
8rrylrc
ID.
Dlr Tlrrc TR
Analytag
.n'
L
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B
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B
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B
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D
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o
r.lIn*1.Il"g
E
.tr
o
N
A
T
L
v 7,
N
c
N
Strd1-B]'rnk 1. OO 15rO0 x Jx I x I [x li
ICf,I;1 1. 00 15:01 x x x x x
rcl'r,2 1. 00 15r08 x x x
rcr,I,1 1.00 15:12 x x x Ix t x
IC.}Ir2 1. 00 15r16 x x x x x
IC\IH 1. 00 LS =2L x x x
I TTL 1. OO 15r25 x x x x x
cg\m 1.00 15:3O x x x
cc,\II,1. 00 15r35 x x x x x
rcB 1. oo 15r39 x x x x x
ALBTD2 1- 00 15r43 x x x x x /
regL 1. 00 15r48 x x x x x I
ICgTB 1. 00 15 r53 x x x x x
CSIIH 1.00 15:58 x x x
csrI,t. o0 l-5 r O3 x x x x x
CCB L. oo 16rO8 x x x x x
Cg\III 1.00 18r06 x x x
CC\lltJ 1- OO 18r1O x x x x x
CCB 1. O0 18 :15 x x x x x
7.7.2f,7rT.1.00 18 :19
7,7,7.2z2 1- 00 18 :2d
2.2z7.7,7,1.00 18 :28
ZZZ7,Z7,1 .00 18 r 33
zzz,zzz 1. 00 18r38 t
MB52 565 67 1. 00 18 r a[3 x x x x x
CHECK gIMPIilT 1. 00 18r{7 x x x x x
DUPITIGLTE CHTCI(1.00 18r51 x x x x x
\y,y,l,y,y,1 ,00 18r55
zzl,zZ,n 5. 00 199O1
ccvH 1.00 19r05 x x x
CCVIJ 1-00 19r10 x x x x x
CCB 1. 00 19 :16 x x x x x
7r7r7rZZZ 1. 00 L9:19
Forn XMN
153
STL DENVER
O
Cont
Total Metals Analvsis
-14-
AI.IALYSIS RUN LOG
reot r LIRS Corlpration
I,d, COdC T SlILDEN Cur No.I SASI ![o. r
fnrtnrncnt rD llhrubrr r Tifn IntraDtd ICP Mcttrodr P
Start Datrr 9 127 l?OOs End Datc: 9 127 /2005
gDg No. r D5I130X,98
8rqrJ.c
ID.
Dlv TLrrc TR
lnel.yt.t
t
L
s
B
I.
I
B
A : l;l rl ;lil;l"l;E
ZZZ7,7,7'1- 00 L9 z?d,
m-Br{02-091205 1. OO 19r29 x x x x x
Gm-BWO2-091205 UA 1.00 19r34 x x x x x
sw-BBro2 -091205 MSID 1.00 19 :38 x x x x x
22,7.27.7,1, OO 19 rl{
z,27,27,7.1. OO 19 :19
T,ZZZZZ 1- OO 19r5{
zzzT,zz 1. 00 19:59
ZT.7,T,7rZ 1- OO 2OrO5
Cg\IH 1. 00 2O:1O x x x
ccur,1. O0 2Or1{x Ix x x x
ceB 1- OO 2Or19 x x x x x
Z7r7'27,7.1. OO 7O t?{,
nzz7,z7,1- Oo 20 t29
Z7r7r7rl7r 1. O0 2O: 34
2,7,7.717'7,1.00 2O:39
7.7.7.7|22 1.00 20: {3
GTr-Brrg?- 091205 1.00 2O:{8 x x x x x
Gtrrr-Bwo t-091205 1. 00 20:53 x x x x x
7t7.Z,7.7.2 1. OO 7O t 5'l
ZZZZT,L 1. OO 2J- r O2
7,Z,Z,Z,7.7,1. 00 21r06
csvH 1. 00 21s11 x x x
cguL 1. O0 21t15 x x x x x
ccB 1- O0 21r2O x x x x x
r - DaDotar additlonal .I.i+ntl (otbcr thal th, rturilrrd CLP .lo.ttti) ar€ rcDrg.D,totl on enothar trorr laSTL Denver - L64
trorar XIV - Ili!
STLDENYER
Total Metals Analvsis
-14'
AI\ALYSERI]NLOG
Contracts r
Lrb Codcr
Inrtnrncnt
Start Dat,e r
lrRg Corlpratl-on
STLDEII
ID Mrmber:
9127 12005
Crgc tilo - r
TifA fat,roptd
StA IUo.3
Method: P
Eted Datcr 9 127 lTOOs
sDs No. t D5f130198
ICP
8ary>Ic
ID.Dlr Time e$R
lnalrrtce
B .l'
u
IJr ![
o
o
g
P
D
P Pr s
I
s fl s
R
h
F
U w r
N
r
E P
Stdl--B].rr'IE 1.00 15:00 x
rCLI,I'1. O0 15rO{x
rcrLz 1. O0 15s08
ICTI,I.1. O0 15r12 x
ICTI,2 1- o0 15r16 x
IC-t'H 1- O0 15:21
ICIIL 1- O0 15r25 x
CSIIH 1. o0 15r3O
CC'\rt,1.0d 15r35 x
ICB 1. O0 15r39 x
ru.igID2 1- od 15: {3 x
ICgr'1- od 15: {8 x
IC TE 1- OG 15r53 x
cgt'Ir 1.O0 15r58
Cglfir 1.O0 16rO3 x
ccB 1. O0 16: 08 lx
cclIII 1- O0 18: O6
cg\Ilr 1. O0 18r10 x
CCB 1- O0 18r15 x
Z,Z,7.7.Z,7,1. Od 18r19
zzzzzz 1 .00 18t2{
zz?,7,7,2 1. O0 18r28
Z7r7r7rZ7.1,O0 18r33
ZZ,LT.ZZ.1, 00 18r38
ra5265567 1. O0 18r43 x
CHECK TDIPI.T 1.00 18: {7 x
DT'PLICtrTE CIIECTS 1- od 18r51 x
Z7.ZZZ7'1. O0 18r56
7,27,7,717r 5.00 19r01
eeur 1. 00 19:05
CCVfr 1. 00 19r10 x
ccB 1.00 19 ;1{x
7,ZZZ7.Z 1.00 19r19
ZZl,l,ZZ 1. 0c 19r2{
STL Denver Forn lfiV r IN 165
STL DENVER
Total Metals Analvsis
-I4-
AhIALYSIS RUN LOG
eontraeE r tr*g coqSroratl-on
9t,rrt Datse : 9 l?7 lilOOs
f,rb Code : STITDEDI Carr ![o. t 8Ag No, r
ID.trur.rt ID t{tuDbort fill InErcpLd ICP ln.tbodr P
gDG No.: D5f130198
End Drt,r r 9 127 lz00s
8rW>1c
ID.DIr l[Lme IR
.f,nr1-ytc;
B J\
u
L
I
M
o
o
g
D
D
P P
tr
s
I
g 8![g
R I I'w I
N
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cnv-Bslo2 -091205 1. O0 19r29 x
Gf,r-Bril02-091205 Msl 1. O0 19 r 3{t x
otr-Briroz-og1305 DrsD 1- o0 L9r38 x
Z7'7,ZZT.1. O0 19r4{
ZZZZZZ 1. O0 19:{9
zzzz7.7,1- O0 19r5{
T.7r7r7r7tz 1. O0 19 ;59
2,7,7,7,712 1. O0 2O:05
CSVH 1- OC 2Or10
cg\,lt 1- 0d 20:11 x
ccB 1.oc 2Or19 x
Z7,ZZZ7.1-00 2O = 2tL
BZZZZZ 1-00 2O t29
7'ZZ7rZ7r 1. O0 2O:3{
7,7,7iZ,Z,7.1. OOI 20:39
27,7.2,7,7,1- 00 2Or43
GW-Brr92 - 0912 05.1. O0 20=18 x
ffi-BTfoI--091205 1- O0 20r53 x
7,7.Z,Z,Z,7,1- O0 2A:57
7.7,7127,7.1. od 2L=O2
TrZrlrl'27.1.OC 21: O6
CSTIH 1.0d 21:11
cg\rL 1.00 21r15 x
ccB 1. OOI 2L z2O x
STL Denver Eorm XIV - IN ]-56
STL DENVER
Total M.lfls Analvsis
A}IALYSE RTJN LOG
Contract:
Lab Codcr
Instnrrucnt
Start Datser
t RS CorryorrtJ.on
Sl[frDml
rD lllrnber:
e /28 t200s
Ca;c No-:
Trfl' Int,rcpLd. fCP
8fSl No. r
Irlothod:
Errd. Date: 9l28l2AAs
8Dc Sb. : D5I130198
Eamgr1e
ID.
D/V rLmc ,tR
lnalfrE,os
l'
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B
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Std,]'-glrnlr 1. OO 10r{5 x x x x x
rce.L1 1. OO 10r49 x x x x x
reAri2 1.00 10:5{x x x
ICI.IJ1 1- OO 10r58 x x x x x
rgf,L2 1. 00 11: O3 x x x x x
IC1ffi 1. OO 11:O7 x x x
rC,VL 1. OO 11r12 x x x x x
CS\IH 1. OO 11 :17 x x x
cgul,1. OO 11:21 x x x x x
reB 1. O0 11s26 x Jx x x x
RIiSTD2 1. OO 11r30 x Ix x x x
ICSA,1,. o0 11r35 x x x x x
resla 1. 00 11:52 x x x x x
cc"vH 1- OO 11r57 x x x
cc'\rL 1. OO 12:O{x x x x x
CCB 1.00 12rO8 x x x x x
T'ZTrZZZ 1.00 L2:LZ
Gf,[-Bs[02-091205 sER,5-OO 12t16 x x x x x
Z7^7,7,7,2,1. O0 LZ z2L
Z7'7'7^ZZ 1.00 12 :25
7.27'27'7.1. OO 12r3O
27.z,7.z.7,,1.00 12r35
7r7r7r7r7t7.1.00 12 :39
7.2,?,27.7.1.00 12r{{
z7.zzz7,1. OO 12r{8
Lz.Zz.ZZ 5. 00 12r52
CCTIH 1.00 L2:57 x x x
Cfiru 1,00 13r01 I I I I I
ccB 1. o0 13:05 x x x x x
. - Darota3 rilillttoual rloantr (othrr thra the lbaldrid clp .Ic.Dta) arG reDreseated on alrothcr Forr 1t
STL Denver
Pom XMN
3,57
STLDENWR
Total Metals Analvsis
-14-
ATTALYSIS RTII{ LOG
ontraets:IrRg Cor:lorrtLon
Ltb Codc:
fnetru[cat
Start Datse:
STLDTN
ID l$umbcr:
91281200s
Cagc No- g
TiIn IntreDtd rCP
gLS No.:
Mettrod: P
Elrd Datc: 9 128/zOAs
sDc No,: D5f130198
grratrrl.6
rD.Dlt Time tR
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rCjLIr2 1- O0 11r03 x
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IgIrI,1.00 11s12 x
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CC'\TL 1. OC 11r21 x
IcB 1- O0 11r25 x
RLgTD2 1- O0 11r30 x
ICg.r.1. Ool 11:35 x
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tcrnr 1. O0 11:57
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ccB 1. O0 12rO8 x
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ce\nr 1- 00 L2 t57
cc\rL 1. O0 13r01 x
ccB 1. O0 13:O5 x
STL Denver Foru XMN 158
STL DENVER
Total M-jils Analvsis
AI\AI,YSIS RTII\I LOG
Contraet r
Irab Codo t
Iutrnrmant
EEart Detcr
URSI CorlrcratLon
ST[,DEN
ID lihrnbcr:
sl29l"oos
Cagc No.:
TifA Intrapld rCP
8AS No.:
Metrhod:
SDc No. r D5f130198
t Drnotes tddlt,lonrl rl-rnrate
STL Denver
End Daro: 9 /29 /2OA5
(otlrrr th"an Eho etandard CIrP olrncatr) ar6 roDr.aautod oa agotbcr fora, 1l
sary)Ie
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.ea,rlytor
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ICAI,I 1. O0 08r55 x
rctl,2 1- O0 09r00 x
ICUH 1- O0 09t0{x
Ievr,1- 00 O9rO9 x
ccuH 1. O0 09r14 x
CSTIL 1.00 O9 :18 x
IcB 1. O0 09r23 x
RI"gtrD2 1. OO O9r27 x
ICgr'1- OO O9r32 x t
ICS}B 1 .00 O9:36 x
ccuH 1. oo O9 t{1 x
ecuL 1- OO O9r46 x
CCB 1. 00 O9:51 x
ccffi 1. O0 1{:57 x
cc-\rL 1.00 15: O1 x
csB 1- OO 15rO5 x
\zzz7,z 1. 00 15:10
T,ZZzzz 1,00 15r1{
z7.zz,zrz 5. OO 15r18
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7f,Z7.7.7.7.1.00 Li t77
7r7rZ7,ZZ 1. OO 15:31
z7,z,7.72 1. OO 15r36
zzzzzz.1. 00 15:{0
m5200507 1. 00 Itr[5 I
CEECK gA!{PIrE 1. O0 15 r49 x
ZCCVH 1.00 15r5{
cc"ull L.00 16;01 x
ZCSVH 1.00 16r0{
CCIIIT 1. 00 15r07 x
Fom XIV fN
L69
STL DENVER
Total M.lil: dnalvsis
AI\ALYSISRUNLOGo
Contraot:
f,ab Code :
Inrtsnrmeut
Stut, Dattl r
t Rg CorlroratLon
gTI"DEN
ID lilurubcr:
9lze 1700s
Cage Ncr. t
T.Ir IntrePid ICP
gLg ![o. :
l{tot}rod.:
End Darer 9 129 12045
sDB IiIo, : D5I130198
Sarqp1rr
ID.
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ccB 1. O0 16:11 x
DUPLIEf,TE CHECK 1. OO 15r15 x
g{-Bwo2-091205 1.00 16r20 x
GW-Br1r02-O91205 sER 5.00 16r25 x
@r-Brrro2-o91205 MEI 1. OO 16:29 x
gH-BWO2-O91205 MsD 1. OO 15r34 x
Grrr-8w92 - og 12 05 1. OO 16r39 x I
GW-![{O].-O91205 1. OO 16r{3 x
?rzZrLf.I.1. OO 16: {8
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cg\rL 1. OO 17r06 x
CcB 1. O0 17 :11 x
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STL Denver
rtendard CLP rloratr) lre roDrorcnEod
FOTM XIII F IN
(other thra tLt oa anotbrr Form t{
L70
STL DENVER
Total M-jil: Arrlvsis
AI\ALYSH RUN LOG
Contract:
Lrl, Codc r
Instnmcnt,
Str,rt Da,tc r
t RS Cor-poratLon
STI,DMT
ID Ntrmbcr:
st27 t2aa5
Cua !fo. r
STIPBHTRTCE
SAg No, :
Methodr
sDc llo. : D5I130198
End, Darcr 9 128/2005
(oEhor tb,au tht tteudrrd CLP rhoruta) a'rc r.Drttoat.d ou rnothcr Fom 1{t
STL
Denotor addltionrl alrrqout,s
Denver
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HIgTD 1. OO 14r36 x x x x x x x x x
HTOII 1.00 l,i t 42 x x x x x x x x x
rg\r1r 1. OO Llt 47 x x x x x x x x x
ccur 1. OO 1{r53 x x x x x I t.l x x x
ICB 1.00 14:58 x x x x x x x x x
RLSTD 1. 00 15:OB x x x x x xl x x x
ICsr 1. O0 15t13 x x x Ix x x x x x
IC.s.l.B 1. OO 15r19 x x x x x xl x x x
T,R 1. OO 15r24 x x x x x xl x x x
ccur l 1 1. OO 15r29 x x x x x 4 x x x /
ECBIl 1. 00 15:35 x x x x x x x x x T
cclrr lzs 1. OO 11:36 x x x x x x x x x
ccB lze 1. 00 11:{1 x x x x x x x x x
IrrE52 565 67 1. O0 11r{5 x x x x x xl x x x
CHECK A.EHPLI 1.00 11r51 x x x lx x xl x x x
DI'PLIC.LTE CHECK 1. O0 11:56 x x x x x xl x x x
rrnIRA-IflB OC 1. oo 12rO1 x x x x x xl x x x
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T,ZZ,ZZZ 1. 00 13:16
Fom XrV IN
1,7 I
STL DETVYER
o
c
Total Metals Analvsis
-14-
ANALYS$ RLIN LOG
ontrrct r IIRS Cor:I>oratLon
f,d, Codc r STLDEN Clrc No. r gll8 Dtro. r
Lngtrnrnrnt ID llfimbrr r SUPBRTR.I,CE Mattrodg P
Etrrt Datr; 9 127 l"OAs End Dntcr 9 12812005
sDGt No, r DSf 130198
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cc,\rr Jze 1. O0 13r31 x x x x x x x x x
ceB I zg 1. 00 13:36 x x x x x xl x x x
GTI-BWO2-091205 1. O0 13: {1 x x x x x x x x x
G9I-B![O2-O91205 Ms 1. O0 7.3 z 47 x x x x x x x x x
s{-Bwo2-oe1205 MsD I., O0 13r52 x x x x x x x x x
?,2717'7,2 2. O0 13r57
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cclnr I 29 1. O0 L4t?A x x x x x x x x x
(]eB I zg 1- OO LIL t26 x x x x x x x x x
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STL Denver L72
Form XIV - IIs
STL DENYER
Total *-:lls Analvsis
ANALYSERUN LOG
Contract:
Lab Codcr
Inrtnrncnt
Bt,rrt Datsc r
URS CorTroratlon
SffJDEN
ID Ilunbor:
9/3012005
Call lilo. t
PE EVt}
gAA No. t
tdrEhodr
End Datsc: 9 l3^O l2OO5
gDO No. t D5IL30198
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0.5 ppb 1. O0 15r05 x
1.0 ppb 1. 00 15: O7 x
?. O Dpb 1- OO 15r08 x
5.O Dpb 1.00 15r10 x
10- 0 pDb 1.00 15:12 x
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cg\r1 1. oo 15r18 x
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STL Denver
Fo:m XfV - fN
1,7 3
STLDENVER
Total M-lils Analvsis
AI{ALYSIS RUN LOGo
ContracE:
fJab Codc t
Instnr.nrcnt
Stsart Datrc;
t RS Corporation
STTDEN
fD l[trmbor r
9/3A12005
Cage DIo. r
PE CITAA
gtg No. t
Mothod:
8Dc No.; D5I130198
gv
Etrd Drtscr 9 l3A l2AO5
r - IlEnot.r rdaltionrl .I.!.rtr (otber thau the rtaadlard cLp .Irr.'rta) rr. r.D!...ateil orr oaoth.s forr 1a
STL Denver
F9I.8 Xr\I - IN
Sam;rlc
ID.
DIY Tiruc BR
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L
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Cg\I6 1. O0 16r59 x
ccB6 1. O0 17r01 x
GH-8W92-O91205 lisD 1-O0 17:O2 x
cw-Bno].-091205 1- O0 1.7 s 0{x
Gts-Bnoz-091205 1. O0 17 :06 x
Grlf -Bwo2 -091205 MA 1. 00 L7 tA7 x
Gffi-BtUo2-O91205 t'rgD 1. OO 17:O9 x
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zz7.,zzz 1. o0 17 r18
cgvT 1- OO 17r19 x
CCBT 1.00 L7 tZL x
a74
STL DETVVER
Total *-11}: Analvsis
AhIALYSIS RIIN LOG
Contract r
Irab Codc:
IrrEUnrmont
gtart Datrr
URSI Corporatl-on
gTI,DEN
ID NUrnbor;
9 /27 12005
Ceto No. t
PE ICPMS
gfS No, r
Methodl
sD(I No.: D5I130198
t{
t
STL
Dcnotag additioua} rlrmrs,ts
Denver
End. Drror 9 128/2AO5
(othrr than thr rtaadrrd eLP rlmrutrl Ltre rGDre..ntrd on r.uoEbsr Forz 1l
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DIP rLmc e6R
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Staad.rrd. 1 1. 00 16: O2 x x
ac std 1 1. OO 15: O6 x x
ac 8td 2 1. OO 16t09 x x
Rf,EITD 1.00 16:13 x x
z7,zz7,z 1.OO L6:Ll
rcgr.1. OO 15r20 x x
rCST.B 1. OO 15r2{x x
R:[!USE 1- OO 16r28 x x
HTOH CHECK 1- OO 16r31 x x
RI![gE 1. oo 15r35 x x /
ac sEd 3 1- OO 16r39 x x T
ac std {1. O0 16r42 x x
BI"artlE 1. OO 17 :16 x x
Standrrd 1 1. OO 17r19 Jx x
ac strd 3 1- oo L7 t23 x x
oc srd I 1. OO L7 t27 x x
ac srd 3 1. OO 21:58 x x
ac sEd L 1. O0 22tAZ x x
rc8l 1- OO 2?: O6 x x
rcg.nB 1- OO 22tA9 x x
RIlUST 1. oo 22r13 x x
ac 8rd 3 1- OO 22 tL-I x x
ac srd {1- 00 22 rZL x x
ac srd 3 I .00 O2 :51 x x
ac srd L 1.00 02r55 x x
MB5266554 1- 00 02r58 x x
CIIECIT Sil'IFI,E l. 00 03r02 x x
DT,PI{ICATE CHECK 1,00 03r06 x x
fIITRA-L,IB AC 1.00 03;09 x x
rlITRA-LtrB aC gER 5.00 03r13 x x
rtwR -r,lB Qc PDS 1.00 03:16 x x
I,IB Ug 1. 00 03r20 x x
Foru XI1I a IN
L75
STL DETWER
Total M-]il: Ar"Ivsis
AI{ALYSIS RUN LOG
Contract r
Irab Codo r
InrtrnrncnE
Start Drtcr
IIBS CorpontLon
SfIJDEI{
fD lGunbcr:
et27 t200s
Cage !{lo. t
PE ICPU.S
gl'g No. r
Mrtshod r
End Datsrr 9 /28/2OA5
gDO No- r D5I1,30198
M
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QC ard 4 1. OO O3:31 x x
Qc srd 3 1. OO 0{:OC x x
ac srd 4 1, 00 04r07 x x
zzzzT.Z 1. O0 O{:11
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srr-8w01-091205 10. oo A4:22 x x
sl-Brro2- 091205 5-OO 08r26 x x
Grur-BITO2-O91205 MA 5. 00 Odr29 x x
@r-Brro2-o91205 MsD 5. O0 04 :33 x x
ac std, 3 1. OO Odt37 x x
0c 8rd I 1.00 0{r4O x x
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STL Denver
Eorm XMN
1,7 5
I.IEIEOD BLBIIK REPORT
Gleneral. Cbernletry
Clteut Iot.
PARAII{ETER
*- - -: D5I13O198 llatrl-x,- - - o - - - . - : WATER
Ammonia aB N
Ch].oride
Fl.uorlde
Nitrate
Ni trate - Ni,trt t.e
Buafate
Total Cyanide
REPORTING
RESTILT IJIIIIT UNfTS METHOD
Work Order #: HLK}IRIAA MB LoE-sample
ND 0. J.O mg/T, MCAWW 350. L
Dllution Fact,or: 1
An.alyeie Time..: OL:00
PREPARATION- PREP
AlrAr,xsrs DATE . BA?CH #
D5I280000- 484
09 / 28 / as s27 1484
1-g B
o-o17
ND
2-5 B
Work Order #: IIru(s81AA
2 -5 rrry,ll'
Dllutrlon Factor; 1
Analysls Tlme..; 1?:00
$Iork Order #: HICtL01AA
B O-10 ng,IL
PLlutLon Factorr 1
Analysis TLme..: 13;15
Work Order #: HITLMQIAjA,
0 . 10 ttg. /I'
Dilution Paetor: 1
Analyeia Time..; 15:30
$Iork Order #: HT.ITFITIAA
o . 10 mg/1,
Dllutlon FacEor: 1
AnalyeJ.e Time. - : O1: O0
Work Order #: HI:ON8IAA,
5-0 W/L
DLlution Paetor: 1
.lnalyeie Time. . : 15 :3O
Work Order #: HK36F1AA
0 - ol-0 mg/I"
DLlution FaeCor: 1
AnalyeLa TLme..: 12:O0
MB Lot-Sample #:
uc,AHr 325 -2
Ds1200000-252
oelLsl os 526325.2
MB Irot-Sample #:
ricAllll 34a -2
D5rI,C0000 -579
oe lL4l os
IUD
MB Lot-SampJ.e #:
McAw!{ 353.2
D5r280000 -708
ae/rllas
52575',19
527 17 08
MB Irot-Sample *:
MCAUm 353 .2
Dsr280000-585
oe /28/ 05 s27L6
o
85
MB L,ot-Sample #:
I.ICBlttt 3-15 -4
DsJ040000-304
LOl0,3las 5277301
ND
MB LoL-Sample #:
sw84 6 eoL aB / 901-2A
D5r210000-539
oe /21-09/zz/ as s264s3e
Calculadons arc pcrformetl before rouoding to rvold round-off errors in calculated rcsuhs.
B Estimrtcd result. Reoult is less thrn RL.
STL Denver 477
o ffi COITIROL SAI'IPI,B BITAITBrIOII NEPORT
General Chenistry
PARAMETER
STL Denver
PERCEMT RECO\IERY
RECOVERY LTMITS
RPD
RPD ITIMITS IvIETHOD
Irlatri:r---.-,, - -: WATER
PREPAR,ATION. PREP
AIVALYSTS DATE BATCH #
5257s79
s25757 I
fot-Saryr1e * - - - : D5f13O198
wo* : HKXK\rraa-r,cs/gIqK\r1-aC-r,CSD LCS lot - Sample# : D5 11 3 0OOO - 504
(97 - 102) swB4G e040B 09/a3/os s256504
(s7 - Lozl 0.14 (o-s.o) sw84c 9o4oB og/ts/os szs6so4
DLlutlon Factor: 1 Analysis TJ,me. . : 11 :47
wo# :IIT,KHRTAC-I,CS/HLKHRI-AD-ICSD LCS Lot-sanple* : D5I280000-484
96 (90 - 1to) McAww 3s0.1 og/2s/as s27L4a4
97 (eO - 11O) 1.4 (0-10) MCArrr{ 3s0.1 O9/28/O5 527L484
DlluElon Fector: 1 AnalysL6 Tim.-: o1:00
pH
100
100
Alrunonta aB N
Chlorl-de
99
99
F'Iuoride
r.0 5
101
rvitrate
90
g2
'rrritrate-Nitrit,e
92
93
Sulfate
103
104
Total Qyanide
1- 07
L08
(n 114 )(et 114) 4,9 (O-15)
Dl-lution Factor; 1
MCAWW 34O .2 09 / 14 / A5
IVICAWII 34A -2 09 / L4 / A5
Analyeie TLme-.: 13:15
Irlo# : HKX581AC-r,CS/HKX581AD-LCSD LCS lrot-Sarq>f e# : D5I2 0000 o -262
(90 - 110) ucAwrr 3zs.z og/Lg/os s263262
(90 - lto) 0.34 (0-10) Melww 32s.2 og/ts/os 526tzgz
Dllution Factor: 1
wo* : EKLLorec- rcs /gKriIrolAD-LcgD Lcg IJot - sample* : D5r14 oo0 o - 579
wo* : HLI,D QIAC-LCS/HIJ,MQLAD- LCSD LCS lrot- Sample# : D5I2 8 0 OO0 - 70I(eo 110) t'tcAww 3s3 ,2(ae 110) 1-.5 (O-10) MeAWlr 353.2
ae/L3/os
osh 3/0s
527 1708
s2? L 708
527 1 585
527 1585
Dilution lr"actor; 1
IrIo* : HLLFLfec- f,cs/fu,LPLlAD- f.csD Lcs Lot - sanple# : D5I2 8 0 o0 0 - 585
(gz L]-,z) t{CAww 353 .2 09 / 28 / Os
(gz LL2) 1,3 (0-10) MCAww 3s3.2 o9/28/as
Dilution Faetor: 1 ar.al-yaLa Time. . : 01:00
WO# : HIroNSfeC-f,CS/gIrONS 1AD-LCSD LeS Irot- Sample* : D5,J04000 0 - 3o4
(eL - L1-2) MCAww 37s.4 tO/os/os 5277304
(91 - 1r.z) o.ss (0-1s) MeAww 37s.r to/otlas sz773o*
Dilution Factor: 1 Aual.yel-e rl-me..: 15:3O
wo# : HK3 6F1AC-I,CS/HTS5FLAD-IJCSD LeS IJot*Sample# : D5I2 10000 - s3 9
(Be - ro9) swB4G goros/gorzx og/zt-a9/zz/05 s264s39
(8e - 10e) 0-93 (0-20) sw846 9OLOF/9A]-2t Oglzr-Og/ZZ/OS 5264s3e
Dllution Factor: 1
(eontinued on next page)
a78
W
Iot-Saryll-e *- - - r D5I130198
PERCENUT RECO\IERY
PARAMETER RECO\IERY LIMTTS
eOI{a?OIr SIIIPITB ffi
Gienera-L Chenistry
RPD
RPD IJIMITS METTIOD
Hatri.]r- . ., o -,, - 3 WATER
PREPARATION- PREP
AI{AITYSTS DATE BATCH #
REPOR:r
TSCITE (S} :
Crlculuionc arc porformod bcforc rourdlng to rvoid round<lff crnott In calculatcd rcsults.
STL Denver a79
o ffi COIUTROIT gAHPfrB DLT[. REPIORT
Geueral- Chemistry
Iot-Saryll-e *- - - ! D5f13O198
SPIKE MEJAST}RED PERCIIT
PARAIUIETER AII{OT}NT AIVTOUNT I]NITS REC"\M,Y RPD TffiTHOD
llatri:r- - - - . - - . . i WATER
PREPARATTON- PREP
AIiTALYSTS DATE BATCH *
IrCS Lot-sample# r D5T28O000-48,0
3so.1 09/28/05 s27r.484
3so.1 a9128/A5 527L484
Tlme..: O1:00
LeS IroL-Sample* : D5f20000o-262
32s -2 ae/L|/As s263262
325 .2 Ae / 18/05 5263262
Tlme. , : 17:00
LCS Iotr-Sample#: DSf 140000-579
340.2 A9/L4/O5 s2s7s79
34A.2 O9/L4/O5 525'7s79
Tima-.: 13:15
teS Lot-Samp1e# : D5I280000-708
353 .2 Oe/* /A5 5271708
353.2 Ae/L3/Os 5271708
Tl-me..: 15:3o
LCS Lot-Sample# : D5fZB00O0 - 585
3s3.2 A9/28/Os 5271685
3s3 ,2 Ae /2e /OS 527158s
Tl-me..; O1-:00
LCS Lot-Sample* : D5LTO4O000-304
3 ?5 .4 rO / 03 /Os 5277304
375 -4 AO/ 03/Os s2773O4
Time. . : 16:30
tCS Lot-Samp1e* : D5r210000-539
eo1 oB/ e0l-2A 09 /2L-0 9 / 2Z/ OS s264s3 9
e01oB/eolzA ae l2L-A9 /22/ 05 s264s3e
TLme..: 1"2:00
pH
Arrrnonia aE N
Chloride
FluorLde
NitraEe
7. O0
7.00
{ .00
4.00
50. o
50. o
5.OO
5. OO
0 .0500
0. 0500
3 _82
3 .88
49 .7
49 .6
5,28
5. 03
wo# : HIo(KVraa-r,cs/gKxKvlAC-IrcsD Lcs IJot - gampl-e# : D5 I13 O 0 0 0 - 5 04
7.O1 No Unirs 100 SW846 9O4OB OgltZ/OS 5256s04
7.O2 l{lo Units 100 0.111 SIT845 90408 ag/tzlos 5256504
. Dllutlon Fastor: 1 Analycle ?lnre.-: 11:47
wO# : HI-TKIIRIAC - LCS I nf,fUR lAD - I,CSD
DLlutlon Factor: I Analyels
wo# : HIQ(S 8 LAC-IreS/Hrc(5I LAD- IreSD
mg/L
nq/I'
mg/r'
wq /t'
Dllutlon Factor: I
mg/T,
mg/r,
DllutLon FacEor: 1
96 MCAWW
9"1 L .4 MCATIII{
99 MCA}TW
99 0.34 MCAWW
Analysls
WO* : HKI,T.O lAC _ LCS /HKIJIJO 1AD _ LCSD
105 MCAWW
101 4.9 .
MCAI{IT
Arralyaia
WO# : III-rI,MQ1AC - LCS /HII,MQI.AD - LCSD
0 . 04 52 rng/L
O - 0459 mg/T-'
90 MCAWW
92 1.5 MCAVSW
erralyel-e
Nl-trat,e-Nit,rlte
. 4.OO
4.oo
Sulfate
25-0
25.O
Total CyanLde
0.100
0 . I-oo
Dl-IutLon Factror; 1
mglr,
rry,/t'
mg/r,
mg /r"
92 MCAVTW
93 1.3 MCAWW
I_03 MCAWW
104 0.88 I.ICAITil{
107 sw84 5
108 0.93 SW845
WO# : HLLFIT1AC -LCs /HIJTFITIAD-LCSD
3. 6g
3 .72
25 .-l
25 _9
Dilut,ion Factor: L AnatrysLs
WO* : HIJ0NB 1AC-IJCS/UI,0WB 1AD-IrCSD
ol-Iution FacEor: 1 ' Ana1ysLe
wo# : HK3 6F1Ae-I,eS/Hrg 6F1.AD-IreSD
0.l-07 nrg/L
o. L08 mg/r
Dilutiog Factor: L AnalyeLs
STL Denver
(continued on nerct page)
180
Iot-Saryl1e *- -.: D5IL3O198
SPIKE ME..ASTIRED
PARJN4ETER AMOI]NT AMOUMT
W COIWNOL SEHPIJB I}AT[, RBtrONHP
Genera-I Chenletry
PERCNT
IINITS RECI/R,Y RPD TYIETIIOD
Uatrix- - - . - - - r - 3 IIIATER
PREPARATTON- PREP
AI{AIJYSIS DATB BATCH #
rwfE (sl :
Calculations arc pcrformd before roundlnt to tvold rotrod-off errorr ln celctrlatod rcsults.
O
STL Denver
o I'IBTRIX APIXE SEHPI|B W NBPORT
ceneral Ch€ol.EtLT
el-ient lot *- - -: D5I130198
Ilate Saryrl"ed--- z O9/20/A5 O9:15 Date Recerirred... O9/21/A5
PERCENT RBCOYT,TERY
RECO\IERY IJIMITS
RPD
PAR.'.AIT{ETER RPD IJTMITS METTIOD
Nitrate-Nitrite
92
91
Total Cfranlde
wo# : Hr(AR91e8 -MS/HKAR9lCg -MSD
1- 10 ) tlCAWt{ 325 .2
110) 0.35 (O-10) MCArirr 32s-2
Dil-ution Factor; 1
Analyaia Time..: 17:00
rilo# r HK2g3 r.DF-MS /UXZ931DG-MSD
1- 1.9 ) tteAWW 3 53 . 2
L19) 0.75 (O-3O) MCABII{ 353.2
Dilution Factor.; ]'
lnalyols Time..: O1:0O
I{atrir- - o - - - - - -: WATER
PREPARATION- PREP
A}IAIJYSIS DATE BATEH #
MS l-,ot-Sample #: D5I1-00153 -003
a9 / rs / os s263262
oe /L8/ as s263252
MS lrot-Sample #: D5I210295-001
oe /28/ as s27158s
oe /2s/ as 527168s
Ch].oride
rWtE(s):
112 N
113 N
32N
56 N,*
(go
(go
(sz
$z
wO*: HICIRSfDU-US/HKAR91D,,-MSD MS Lot-Sary)le #: D5r100153-003
(Be - 109) sws45 90108/9012e. og/zt-09/zz/as s264s39
(Be - 109) 24 (0-20) swg46 sotoz/sotza, os/zt-og/zz/os s264st9
Dilutioa Factor: L
.Baalyeis Tl'me.. : 12:OO
Calculrtions &re pcrformcd before rounding to avoid round<rff crrors in cotcutated resulul.
N Spikat analytc rocovery is outside ststGd conu.ol timlts.
t Relative perpcnt diffueacc (RPD) is outsHs $eted control limirs.
o
' t
..
. t
STL Denver :- 82
C1ient tot S- - -:
Da,te Sarylled'- .. !
SAIVIPITE
PARAMETEB A}{OUM[
Chlorlde
2200
2200
Nitrate-NitriE,e
0.16
0.16
Total Clranide
0.056
IWTB (S} :
}trLIAIT SPTTB AAHPI.E ITATA REFOET
Gerreral Cheurietrry
D5r13 0l_98
09/2o/os 09:I-5 Date Recefured--: a9/2L/os
SPIIG MEASRD
liatrix- - - - - - - - - r wAtER
PREPARATION- PREP.
AI{ATYSIS pATF BATCH *
oe / 18/os s263262
oe / 1-8 / a5 s2 63 262
ae /2a I os 527 L68s
oe /za / as sz7168s
PERCIUT
ATYIOI]NT UNITS REC\IRY RPD II{ETHOD
wo#: IIKARSTC8-MS/HKAR91C9-MSD lrs Lot,-Sample #: D5r100153-003
5O0O 7850 N trtg/L'
5oo0 ?880 N ng/r,
4-OO 3.84 mg/L
4.00 3.81 rg/l'
LLz MCAWW 325.2
113 0.35 IYICAWW 325.2
92 MCAWW 353 .2
91 0 _ 75 MCAI{II 353 .2
Dllutlon Factor: 1
AnalysLs Timc..: 1?:00
IrIO# : HK2ggrOr'-Ug/rK2931DG-MSD MSI r,ot-Sample # : D5r210295-001
Dllutioa Feetori 1
Analyslo Tl.rre.. : O1:00
vlo#: HKARgrpg-us/nxenglDir-MsD Mti Lot-sanple *: D5r1OO153-003
0.100 0.0883 ng/t 32 sw846 gotog/g oglzt-oglzzlas 5264539
Qua1l-f lers: N
O - 056 0.l-OO O -LL2 rg/1, 56
Qualif iers: N, *
Dllut,ion Factor; 1
Analyeie Time- -: 12:O0
ztl SW8{5 eOIAP/9 A9 121-09/22/05 s254s39
Calorlatlon$ tro performd bcforc rounding io evoid round-offcrrors in calctlatod results.
N Spftcrt analyrc rccovery is outside satcd conrrol tfunirs.
t Rolative percctrt differcnco (RPD) ie outsidc sratod conuol limis.
STL Denver 183
o IBTRn SPTxn 8AI.iPI,B E\rAI}tnlfrtON REPIORT
G€neral- Chenistry
Cllent Iot *.--: D5I130t98
Date Saqrl.ed-- -z Og/tz/OS LZ|22 Da,te Received- -. O|/L3/O5
PERCEIIT
PARAMETER FECOVERY
.B,mmonla aa N
87r
99r
Chloride
1.L4 N
I1s N
RECO\IERY
LfMITS
RPD
RPD IJTMTTS METHOD
uatri-x,---!!--.3 GI{
PREPAIULTION- PREP
ANATJYSTS DATE BATCTI #
LoL-SampIe # : D5I130198-004
ae / 2e / os s27I-484ae/28/as s27L484
I,ot-Sarnple * : D5I130198-004
oe / L8l0s s253262
ae /Ls/ as s263262
(e*
(++
r[o#:
130)
13O) 5-3 (O-30)
oiluE.lon Faetor: 1
Analyeie firne. . : O1; OO
wo#;
110 )
110) 0.33 (O-1O)
oilutl.on Factor: 1
Analyel,s Timc. . : 17 ; 00
wo#:
1-07)
lo7) 2.o (0-1O)
Dilutiou FacEor: L
Analyels . Tlme. . : 13 : 15
rfo* :
11_9)
119) 4.9 (O-30)
Di].utLon F.aeEor: 1
Analyel-s Time. . : 01; OO
wo*:
1s3 )
153) 1,5 (O-2L')
Dilut,ion Factor: 1
Analyeie Tlme..; 16:30
WO* r
10s )
109) 1.9 ( O-20)
Dilutlou, Factor: 1
Rnalyeie Time - . : I-2 : o0
HKE3 01DD-MS /IflrJ'lOIDE-MSD MS
MCAI^IT{ 350.1
MCAWW 350.l_
(so
(e0
(ez
(ez
(Be
(ag
HKE3 01C8-MS/XXm 01C9-MSD l4S
MCAUnil 325 -2
MCAWW 325.2
Fruorlde
1og N (al
]'0s ( ez
Nitrate-Nltrite
77
82
Sulfate
190 N, r (as
185 N,I (+S
Total qyanide
57N
s5N
HKE3 O1DA-MS/Hr(E3 01DC-MSD MS
MCAWW 344.2
MCAUII{ 34O .2
Lot-Samp1-e *:
ae/La/as
oe/L4/os
Dsr130198-004
5257579
5257579
HKE3 O1C4 -MS/HrG3 01.C5 -MSD I{S
MCAItm 353 .2
IvICAWRI 353-2
Lot-Sarnple #:
0e/28/os
oe/zB/as
D5IL30198-004
5271685
527 1685
HKE3 01DF-MS/HKE3 oLDG-MSD MS
MCAI{V{ 375 - 4
MCAWW 375.4
Irot-Sarytle # : D5fL30l-98:004
La / 03 /os sz7r3a4
aa / 03 /05 s2773o4
HKE301.DH-IV1S/HXEr OIDJ-MSD MS Lot-Saqrle # : D5r13 0198- OO4
sw845 eo]. oB/eol2A Oe /2L-0 e /22/ AS s26{s3e
sw846 90r. oB/9012A ae l z]--oe / 22 / os s264s3 9
Calculntlort erc pcrformql be,fore rounding to svoid round+ff errors ln cdculated resulrs.
o
N Spikal rnetytc recovery is ouside sated control limits.
I Es,imatod result. Result concelrtradon execds rlre catibration range.
184STL Denver
DMMIT SPIKB SIA}iPI.E DATA NBFORT
General ehamt8trfr
Ctl-ent Lt *--.: D5r130198
Date aaqfleaf.-. = 09/1-2/OS :.,2:22 Date Receiwed--? O9lL3/a5
PARA}FJ. ER
Arnmonia a6
SAIvIPI.,E SPIKE
AII{OTTNT ATIT
N
5,O
5.0
Chlorl-de
5500
5s00
Fluoride
L.2
L.2
Nitrate-Nitrite
o. gg
o.99
Sulfate
650
6so
Tot,aI CyanJ-de
ND
IUD
tlatrixr-r------r GW
PREPARJLTTON- PREP
AI{IAIJYSTS DATE BATCH #
ae / 28 / as 527l-4 8{
ae /zs/ os s27 1484
8 .44 I rftg /I'
B.9O I wrq./t
{ . 06 mg/l'
4.26 mg/L
oi].utJ,on FacEor; 1
McJtWW 350.1
5,3 MCAWI{ 350,1
MCAIIIIil 353.2
4.9 MCAWW 353.2
MEASRD PERCMT
A},lotnrr UNrTS REC\IRY RPD METHOD
wo#: HKE3orop-Ms/uKE3o1DE-MSD lIS Lot-Sary)le #: D5T130198-004
4,00
4,00
s000
5000
5. O0
5.00
4 .00
4. O0
500
500
o.100
0.100
DLlutlon Factor: 1
IBBlyslB flne.,: O1'r0O
9IO*: HKE3OTCe-MS/HKE301C9-MSD MS Lot-saqrle #: D5I130198-004
L7-2OO N nrsll t]-r MCAWW ?25-2 OS/LA/OS 5263262
11300 N rng/r, 1-1s O-33 MeAWlr 32s.2 OS/U/OS s251262
Dilutioll Factor: 1
aaalyaie Tine..; 17:00
9lo#: HKE3OTOe-US/rre3oIDC-I'{SD Mf} Lot-Saqrle #: Dsr130198-004
5.59 N ry/t, r-08 MCAI{W 340.2 Og/t+/oS s2s7sv9
6.46 ng/t los 2-o MeiLww 340.2 og/t+/os 5251579
Dilutim Factor: 1
AnalysLa Timc. . : 13 :15
wo#: HKE3O1C4-MS/HKE301C5-MSD MS rot-Saq)Ie #: D5r130198-004
87
99
77
g2
ae/28/as
oe/28/os 52-71- 6I5
.Inalyele Tl.me. . : 01,; 0O
wo*: HEE3OTOT-US/HKE301DG-MSD MS Lot-Sample #: D5r130198-004
1600 nrs/r, 190 t[CAW]r 375.4 tO/Ol/OS 5277304
QuaIJ-f Lers: N, I
158 o mg/r, 18 5 J. . 5 MCArrniI 375 - 4
Qualif iers: N, f
Dilution Factor: 1
analyels Tl.trre. . : 15: 3O
ao/03los 5277304
rfO#: HKE3ofon-FrS/HKE3O]-DJ-MSD MS r,ot-gample #: D5r130198-004
o-o572 rns/r, s? sI{846 go]-oB/g og/zt-og/zz/os s264s39
Qualif l"ers r N
0.0551 mg/I'
Qrralif iera: N
Dilution FacEor:
Analyal-a Tlme. . :
s6 1.9 sW845 s0108/9 A9/21-09/22/As s264s39
1
12: OO
Cahulations ere performed before rounding to avoid round-offerrors in calculated rcsrlts.
N Spiked analyte rcmvory is ouaide satcd control timits.
I Estimatod rosutt. Re$lt concontretion excecds the calibrarion range.O
STL Denver 185
Clf,ent lot *-. .I
Date Saq)Ied.. ,. 3
PA&N,I RESIIIJT
geliPlrB DIrPfrfeLIB EIIALIBTIODU RBBORT
General ChemiBtry
D5I1-30L98 flork Order *- . . : HKDItnil-SMP
HKDWW-DUP
09 / 09 / os 10: 00 rlate Received. - 3 og / L2 / as
DUPLICATE RPD
liatrfur- - - - - - - 3 yIATER
PREPARATTON- PREP
ANA!.Y. E.T9_p.+TE BATCII #
5256504
185
RESULT IHITS RPD Lrrr{rT MErHgp
8,3
SD lrot-Saqrle #: D5f120209-001
NoUnl.tsO-24 (O-s.O)SWgee 90408 09/13/05
Dllution Factor: 1 AnalycLe Time. - : 12:54
pH
8.4
STL Denver
Sample Receiving Checklist
PM to Complete This Section: Yes
Residual chlorine check required:C
euote#: 44{i/r5
Special Insutctions:
Quarantincd :
Yes . I'lotrx
Nl*, (.t.
Time Zone:
. EDTIEST . CDT/CST'. MDT/I\4ST . PDTPST . OTIIER
Unpacking Checks:
Cooler #(s): .
N/A Yes No
trFD
do
DA
DF
,do
trP D
,atr
tr
c
D
,p
rf
o
,a
uE
Drd
c
Fc
Erorfr
3rJ
Teryeranres ("c)r .< b ..?LI-- 1:?- --- -- 3,7
1. Cooler seals intact? (N/A ifhand delivcred) If no, document on CUR
7- Chain of custody present? If no, document on CIJR.
3. Bottles broken and/or are leaking? ffycs, docrrnent on CllR.
4. Multiphasic saryles obvious? If yes, document on CUR.
5. Propcr container & preserwatives used? (ref. Anachment D of SOP# DEN-QA-0003) If no, docr:rnent on CUR
6. pH of all sasples chcckcd and mcet requirerneuts? If no, document on CUR-
7. Sufficient vohrme provided for aII analysis requxted? (ref- Anacbment D of SOP# DEN-QA-0003) If no,
docrrtrrent on CIJR, and contact P.M bcfore proceeding
Did chain of custody agree with labels ID and samples rcceived? Ifno, document on CUR.
Wcre VOA sanples without headspace? If no, documeut ou CUR.
Wcrc VOA vials preserved? Preservativ e.ElfuCr EJ4IZ"C [sodium Thiosulfare O Ascorbic Acid
Did saryles require preservation with sodirrn thiozulfate?
If yes to #I l, did the sauples contain residual chlorine? If yes, document ou C[JR.
Sediment prcsent in dissolved/filtercd bottles? If yes, document on CUR.
0 14. Is suficient volume prorrded for client requested MS, MSD o, *rt'i* duplir.t*s? If ,0, document on CIIR, ard
contact PM before proceeding.
15. Receipt date(s) > 48 hours past the collestion date(s)? lf yes, notiry PAPM.
16. Are analyses with short holding times requested?
tr F 17. Was a quick Tum Around (TAT) requested?
trrt
Ftr O
STL Denver
\QA\Forms\Sample Receidng\Samplc Receiving Checklist 12 13 04 rcvision l7n3t04
STL Denver
Sample Receiving Checklist
.6
,u
tr
,Z
3
,a
D
fI
T
,a
,u
tr
o Lot#2a{/ffii?fr_
Login Checks;
N/n )'es No
rtDr8.
tt ,z fJ tg.
D
tr
l
tr
tr
D
,g
.7'
Suffrcient voluun providcd for all anall,sis rcguestcdlr (rcf. Attachment D of SOP# DEhl-QA-()003) If no,
documenl on CLI\ antconlacl Pfvl bcfore procceding.
Is sufJicicnt volurnc providcd for client rcquestcd MS, h4SD or matnx duplicarct? If nq documcnt on CUR, and
cornacl Plvl bcforc procecding
20. Did the clrain ofcustody includes "reccivcd b)r'and "rclirrguirhed'by signatures, dates, and timus?
21. tr cre spccial log irr instruclions rcad arrd followed?
22- lltcrc AFCEE rulals logcd for refi-igcrated storagc?
23. \llcre tests logged checkcd against thc COC? \trtrich sarnples u'cre confirmcd?
24- \\,as a Rush forrn cornpleted for guick TAT?
25. \l/as a Short Hold form completed for an), sbort holds?
26. Is "Strict lcof'reguired?
27. liy'ere spccial ar&iving instructions indicalcd il thc General Comrrclrs? If so, u'hat werc the1,?
{"r
Labeling atrd Storage Checks:
{D
{nI
dD
28. Was thc subcontracl COC signcd and sml wit saryles to bot8c prep?
?9. Werc sarrylelabels doubJe-checlpd by a secoud person'/
30. Werc srylebdtlcs aad COC double checJ<ed for dinsolvedrfrltcrod metals by a sccond pcrson?
31. Did tbc sarnple ID, Date, and Tinre from label matcb q'trat was loggcd?
32. \Vcre stickeu for special arcbiviug jnrructions afi:<cd to eadr box and to the ICOC? Sae#27
33. Werc AFCEE rnctals stored rcfrigeratcd?
34. \\rcrc'Stricl ICOC- copics given to satellite storage arcas?
trf
Utr
TIl
Documonl anyproblems rr discrepancies and the actions tal'.an to re.soh,e th^-m on a Condition Upon Receipt Anomaly
Report (CUR).
lniials
STL Denver 1BB
f,mo m mo TD
P
-f
)
r'
$
>"
(.
J
'V
A E $.
,}\\
r
c\
.
-v T(-
_it F-
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STL DenYer
4955 Yanow Street
Aruada, CO 80002
Tel: [phone] Fax;
www.stl-inc.com
STL
303 431 7t7I
A}[AI YTICAL REPORT
Western Zirconium Proj ect
Lot #: D5I09AI76
Sheri O'Connor
URS Corporation
8181 East Tufts Avenue,
Denver, CO 80237
STLDENVER
WW
Linda L. Benkers
Project Manager
September 30, 2A05
Salem Trent Laboratorfes, lnc.
Table Of Contents
Sfan dard Del iverables with Supp orti ng
Report Contents
Sfandard Deliverables
(fne Cover Letter and the Report Cover page are cCInsidered integral
parts o/ this Stundurcl Deliverable package. Thi.s report is incomplete
unless all pages indicated in this Table of Contents are included.)
Documentation
Number of Pages
Check below when
supporting
documentation is
present.
o
o
o
a
a
a
t
a
a
a
Table of Contents
Cnse l{arrative
Executive Surnmary - Detection Highlights
Methods Sunomary
Method/Anal;,st Summary
Lot Sample Summary
Analyticnl Results
QC Data Association Surnmary
QC Evaluation and/or I)ata Reports
Chain-of-Custody
Supp orti ng Doc u m entati o n
(Note: A one-page "I)escription rf Supporting l)ocumentation"
provided at the beginning of this section.).
o Volatile GC/PIS
, Semivolatile GC/MS
r Volatile GC
o Semivolatile GC
. LCIMS or HPLC
r Metals
o General Chernistry
r Radiochemistry
r Subcontracted Data
r.$nnnnnnnnn
STL Denver
Case Narrative
D5I090176
With exceptions noted as flags or footnotes, standard analytical protocols were followed in the
analysis of the samples and no problems were encountered or anomalies observed. All laboratory
quality control samples analyzed in conjunction with the samples in this project were within
established control limits, with any exceptions noted.
The test results presented in this report mcet all requirements ofNELAC, and any exceptions are
noted, This report shall not be reproduced, except in fulI, without written permission from the
laboratory.
Sample Receiving
Eight samples wcre received under chain of custody on September 9,2005. The samples were
received in good condition at temperatues of 3.3"C, 3.8"C, 3.6oC, 4.4"C, and2.7"C.
Please notc that the samples submitted for 82608 analyses only require reporting of Chloroform
only as per client request.
GC/MS Volatiles, SW846 82608
The MS/IvISD associated with batch 5263544 performed on a sample from another client and/or
lot was in control.
The MS/MSD associated wittr batch 5264409 and performed on sample D51090176-003 was in
not control-
No other anomalies were observed.
Total Metals, SW846 60108,6020 & 7474A
Samples D5I090176-002 through 008 were analyzed at dilutions fbr several metals by rnethods
60108 and/or 6020 due to matrix interference and/or high analye concentrations. The reporting
limits are adjusted accordingly.
The method 60108 MS/N{SD associated with batch 5265237 was perforrned on a sample from
another client and/or lot and was in control.
The method 7470A MS/MSD associated with batch 5259473 was performed on a sample from
another client and/or lot.and was not in control for mercury.
The rnethod 6020 MS/I,ISD associated with batch 5265193 was performed on a sample from
another client and/or lot and was not in control.
No other anomalies were obsen'ed.
STL Denver
General Chemistry, Various Methods
Samples D5I090176-002 through 008 were analyzed at dilutions for several compounds due to
high anallc concentrations. The reporting limits are adjusted accordingly and thc associated
data is flaggcd "Q".
Chloride, fluoride, and sulfate were detected in the method blanks at concentralions below the
reporting limits, but above the method detection limits. Associated positive sample rcsults are
flagged "J".
All MS/MSD samples wcre performed on samples .&orn other clients and/or lots and some were
not in control.
The pH duplicate was performed on sample D5I090176-002 and was in control.
No other anomalies were observed.
STL Denver
ErcW W - Iletection Highlights
D5rO9017b
RESULT
REPCRTTNG
LTMIT I,INTTS
AI{ATYTTCAL
METHODPARA},IETER
Gw-se-ogogos og/oalos o9:15 ooz
Cadmium
Aluminum
Arsenic
Barium
Nickel
Vanadium
Z:,nc
Calcium
Iron
Potas s ium
Magnes ium
Sodium
Chloroform
Chloride
Fluoride
NitraEe
Ni trate-Nitrite
Total Cyanide
pH
SuI fate
Ammonia as N
Gn-R2-O90BO5 O9/O8{O5 Ae:25 OO3
Selenium
Aluminurn
Barium
Chrornium
Ni ckel
Vanadium
Zinc
Calcium
fron
Pot,aBsium
Magnes ium
Sodium
Zirconium
Chloride
Fluoride
Ni traEe
NiErate-Nitrit.e
pH
SUI faEe
0.0424 B
1, .7
0 .012 B
0.1s
0.020 B
0.0039 B
0,0077 B
1800
0.025 B
500
550
5900
4.2
19ooo J, Q
0-85 J
500
s00 0
0.0031 B
7_2
3200 J, Q
3000 0
0 - 0050 B
a -76
0.9s
0.0030 B
0.0027 B
0 .0038 B
0 .0095 B
94
0,93
330
120
6900
0.0030 B
l_2000 J, Q
0.85 J
0 .039 B
0.043 B
7.8
s1a J,Q
(Cont-inued on next
0.020
0.10
0.015
0.010
0 - 040
0-01 0
0 .020
2.0
0.10
30
a .24
s0
L.0
1200
0 .10
0 . L0
t0
0,0L0
0.10
500
100
0 . 02 0
0.l-c
o .01_0
0 .010
0.040
0.010
0.020
0 ,20
0 .10
3.0
0.20
50
0 .015
25A
0 .10
0 - 10
0.l_0
0 .10
250
page)
mg /r,
mg/L
Ilrtg/L
mg/ t,
mg/L
rftg/t
mg/1,
mg/t'
vtg/L
mg/L
mg/t
mg/t
tlg/L
IritE/L
mg/L
mg/L
rng/L
rng/L
No Units
mg/L
mg/L
mglL
mg/ I'
mg/L
mg/r,
mg/L
ItftglL
mg/r,
mg/t'
mslL
mg/L
mg/L
mg/L
mg/L
mg/L
^g/Lmg/L
mg/L
No Units
mg/L
sw845 6020
sw845 50108
sw84 6 5 0108
sw845 50r-08
sw846 5010B
sl{845 60108
sw84 5 6 0108
sw84 5 6 0108
sw84 6 5 010B
sw84 5 501 0B
sw84 5 5 0108
sw845 50108
sw845 82508
IYICAI,'II^I 325 -Z
MCAWW 340,2
MCAWW 353.2
MCAI^II^I 353 - 2
swB45 eol oB/ e0r.2A
sw845 90408
MCAIfi^I 315 .1
MeASil^l 350 .1
sw84 6 6020
sw84 5 60r- 08
sw846 50L08
sw84 6 5 0108
sw84 5 6 010E}
sw846 501_08
swB46 50108
s[\I845 501_0B
sw845 60108
SWB45 5O1OB
sw845 601_08
sw845 50108
sw84 5 5 0108
McAww 325 ,2
MCAWW 340 .2
MCAWW 353 .2
MCAWW 353 .2
SWB45 9O4OB
MCAWW 375.4
STL Denver
EreCIITwE W - Iletection lTiglrlights
D5rO90r-7b
RESULT
REPORTING
IJII'IIT UNITS
^AT{ALYTICAf,
IvIETTIODPAIU\MEIrER
GH-R2 -O9O8O5 09 / O8/Os oe :25 OO3
Amrnonl a as N
Grr-ss - ogo8os a9 / a8l os I-0 : 38 004
Selenium
Aluminum
Arsenic
Barium
NickeI
Vanadium
Calcium
f ron
Potas s ium
Magrnesium
Sodium
Zjrconium
Chloride
Fluoride
Nitrate
Nitrate-Nitrite
pH
Sulfate
Ammonia as N
Gn-4ja-o9o805 a9/08/05 1r-:oo oo5
Cadmium
Selenium
Aluminum
Arsenic
Barium
Chromium
Copper
Nickel
I-read
Vanadium
Zinc
Calciurn
fron
Pot ass ium
Magnesium
Sodium
Zirconium
8.5 0
0 - oo22 B
0 .034 B
0 .0045 B
0.20
0.0424 B
0 - 0a27 B
43
0.19
150
92
3000
0.00L7 B
4704 J, Q
0-9s J
0 .l-5
0.16
8.1
390 J, Q
5.5
0 - 0011_
0 - 0083
36
0.0098
a .47
o - 045
o -072
o.o4z
0.028
0-057
0 -21
LL0
32
300
97
6s00
0 .023
o .20 mg/L MCAWW 350 .1
B
B
0_010
0 .l_0
0,015
0 _ 01_0
0.040
0 , 01"0
0 .20
0.10
3.0
0,20
5.0
0.01s
254
0 .l-0
0 ,10
0. L0
0.10
1-0 0
0.10
0.010
0.020
0 .10
0.015
0 .010
0 .01-0
0 .010
0.040
0.0030
0-010
0.020
0.20
0 .10
3.0
0 .20
s0
0 .015
page)
mg/t"
mq/L
mg/L
mg/L
mg/L
r|tg/L
mg/L
mg/L
mg/r,
mglL
mg/L
mg/L
mg/l'
mg/t
mg/L
mglL
No Units
mg/L
mg/t,
mg/L
rr.g/t
mg/1,
m9/t,
mg/ r'
mglL
mg/t'
mg/L
mg/L
mg/r,
I:lrg/t
mg/L
rr.g/L
nrg/t,
mg/L
mg/t
mg/1"
sw846 6024
sw84 5 5 0108
sw845 50L08
sw846 50L0B
sw845 60108
swB45 50108
sw845 501"0B
sw845 6 0I- 08
s![845 50108
sw845 5 0108
sw845 60L08
sw845 60108
MCAWW 325.2
MCAI,II^I 340.2
MCAWW 353.2
IvICAI^n^l 353 ,2
sw845 90408
MCAWW 375.4
MCAWW 350.1
sw845 6020
sw845 5020
sw846 50L08
sw84 6 5 010B
sw846 601.08
sw84 5 5 0108
sw845 601-oB
sw846 601-08
slr84 6 5 0108
sw846 60108
SIr[846 50L0B
sw846 60L08
sw84 5 6 0108
sw84 5 5 0108
sw846 50108
sw84 6 5 0108
sw845 50108
STL Denver
(Continued on next
E)rc,W W - fhtection HiBhlights
D5r090176
RESULT
REPORTING
LIMIT ITNTTS
A}IAIYTICAL
METIIODPAILI\METER
ew-4a-ogogos ogloa/os 11:oo oos
Chloride
Fluoride
Nit.rate
Nitrate -Ni tri t.e
pH
SUI fate
Ammonia a6 N
crr-s4 - o 9oBo5 a9 / o8/os 11 ; 5o 006
Seleniurn
tsarium
Calcium
Iron
Pot assium
Magnesium
Sodium
Zirconium
Chloride
Fluoride
Ni trate
Nitrate -Ni tri te
pH
Sul- f aEe
Ammonia aE N
GW-R4-OeOsOs A9 / 08/05 L2 =4A O07
Selenium
Aluminum
Barium
Chromium
Ni cke 1
Vanadium
Zinc
Calcium
Iron
Potas s ium
Magnes j.um
Sodiurn
Zirconium
Chloride
Fluoride
1100 0 J, Q
1-1 J
0 .059 B
0 .075 B
8.2
880 B, J, Q
5.9
0,0053 B
0.12
59
0.14
290
150
4500
0.0024 B
6700 J, Q
a-74 J
0.19
0 .20
7 .8
1700 J, Q
9.2 0
0.0038 B
2.1
1.5
0. 0048 B
0.0041 B
0.0055 B
0.013 B
55
3.0
210
4g
3200
0.0032 B
51_00 J, Q
1.1 J
(Continued on next,
mg/t MCAww
mg/L MCAww
mg/L lvlcAllw
r;,g/L MCAWw
No Unire SWB45
mg/r, MCAww
mg/r-, MCAww
mg /t" swg{ 6
mg/t, sw84 6
rr,g/t swg45
rng/L SW846
nq/L sI{84 6
ffig/L sl^t846
ll,;rg/t swa46
mg/ t sw84 6
mg/ l, I,lCAwW
mg/t, MCAWW
mg/t MCAww
mg/L MCAWW
No Units SWB45
mg/r-, llcAwuv
mg/L MeAww
2s0
0.10
0.10
0.10
0.10
1000
0.10
0.010
0.010
o .24
0,10
3.0
0.20
5,0
0.015
2s0
0.10
0 .10
0 .10
0 _ 10
250
0.50
0.01_0
0.10
0.010
0.010
0.040
0.010
0 .020
a -20
0-10
3-0
0.20
5.0
0 .0r.s
2s0
0 .10
page )
32s .2
34A -2
353.2
353 -2
904 0B
3-15 . 4
350.1_
6020
60L0B
5 01_0B
6 0108
6 01"08
5 0108
5 01- 08
60L0B
325 ,2
344 -2
3s3.2
353 -2
904 0B
375.4
3s0.1
mg/L
mg/I'
mg/L
rng/L
rng / r,
mg/r-,
mg/r,
mg/L
mg/t
n.g/t'
mgll.,
rl'g/t
mg/t
ms/L
mg/1,
sw845
SWB4 5
SWB4 5
sw84 5
sw84 5
SW84 5
SWB4 5
sw84 5
sw84 5
sw845
sI^I84 6
shl84 6
sI/{84 5
MCAWW
IVlCAWW
5020
60108
6 0108
50r_08
5 0108
50108
60108
60108
60L0B
50108
50L0B
5010B
50108
325 .2
340.2
STL Denver
EXEWffi-I)etection@
DsrO90L76
RESULT
REPORTTNG
I,IMTT UNITS
AIVALYTICAL
METITODPARAMETER
crI-R4-o90BO5 O9l 08/05 L2 z4O OO?
Nitrate
NitraLe -Nitrite
pH
SUI fate
Ammonia ag N
Grv-R3-O9080s O9l O8l A5 14 : L5 008
Cadmium
Selenium
Arsenic
Barium
Nickel
Vanadium
Zinc
Calcium
Iron
Potassium
I"lagnesium
Sodium
Zirconium
Chloroform
Chloride
Fluoride
Nitrate
Nitrate-Nitrite
pH
Sulfate
Ammonia a6 N
0 -42
0 - 43
8-0
3-7 BrJ
'l .9
0.00025 B
0. 0028 B
0.011 B
o.'72
0 ,0031 B
0.0a27 B
0 - 0050 B
43
0.L4
l_5 0
46
2500
0 - 0088 B
0 .18 J
38oo J, Q
L.2 J
1.7
1.8
7 .8
45 J,Q
L40
0 - 1-0
0 ,10
0.L0
5,0
0 .l_0
0.0050
0.010
0.015
0.010
0.040
0.0L0
0 .020
0.20
o - 10
3.0
o .20
5,0
0.015
1,0
250
0 .10
0 .10
0.1_0
0.1,0
25
1-0
mg/t
mg/L
No Units
mg/L
mg/I'
rng /L
mg/r,
mg/L
mg/L
rjts/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
ug/L
mg/L
mg/L
mg/L
mg/L
No Units
mg/L
mg/L
MCAWW 353 .2
sw846 90408
IIICA}.M 3T5 - 4
McAwrd 350 . 1
sw84 6 6020
sw84 5 6A20
sw84 5 6 0108
sw84 5 5 0108
sw845 50108
sw845 60L08
sw84 6 5 0108
sw845 6010B
sw84 5 6 0108
sw845 50108
sw846 50108
sw846 50108
sw845 50108
sw845 82608
MCAWW 325.2
MCAWW 340 .2
MCAWW 3s3 - 2
MCAWW 353.2
sw846 90408
MCAWW 37s.4
MCAWW 3s0 - 1
STL Denver
MEIHODSW
D5rO9o-L76
PARAMETER
AIVAIJYTI CA]J
METHOD
pH Aqueous SW845 90408 SW845 90408
Chloride (Colorimetric, AuEomated Ferricyanide) MCAIIW 325-2 MCAWW 325.2
Fluoride (PotentiomeEric, Ion Selective Eleetrode) MCAWW 340.2 MCAWW 340.2
Inductively Coupled Plasma (ICP) Metale SW846 60108 SW846 3010A
rcP-Ms (5020) sw845 6020 sw8{5 s020A
Mercury in Liguid Waste (Manua] Co1d-Vapor) sw846 747aA sw846 7470A
Nitrate MCAI'IW 353 .2 MCAVW{ 353 .2
Nitrate-Nitrite MCAWW 353.2 McAlIlI 353.2
Nitrogen, Anmonia MCAWW 350.1 MCAWW 350.1
Sulfate MCAWW 375.4 MCAWW 375.4
Total cyanide sw846 90108/901 SW846 90108
Trace Inductively Coupled Plasma (ICP) Metale SW846 60108 SW846 301-0A
volatile organice by Gc/Ms sw846 82608 SW846 5A3A8/?26
Referenceg:
PREPARATION
METHOD
MCAWW
sw84 6
"Methods for Chemical enalysis of Water and WasLes't,
EPA-500 / +-79-020, March 1983 and subeequent revisions.
"Teet Methods for Evaluating Solid tlaste, Phyeical/Chemica1
Methods't, Third Editton, November 1986 and its updat.es.
STL Denver
AI{ALYTICAL
I,lETI{OD
METHOD/ANALYSTW
D5IO90L76
ANAIJYST
MCA!{W 325 .2
MCAI^TI{ 340.2
MCAWW 350 . I
MCAWW 3s3 .2
MCAWW 315.4
sw84 6 5 0108
sw846 50108
sw846 501"08
sw845 6020
sw846 5020
sw845 7470A
sw846 82508
sw846 82508
sw846 eol0B/ 9AL2A
sw846 90408
Referenceg:
MCAW!^I
sw84 5
Claire Likar
Fougere M. Danielle
Claire Likar
Claire Likar
Dusti o. Criqri
Jane1 MoLichka
Janel lvlot ichka
Lyrur-Arrne Trudel I
Thomas LiIl
Thomas tilI
,Janiee S - Collins
Dan Appelhans
Danie1 Kiekel
Dueti O. Criqui
Fougere M. Danie}le
A\IALYST
ID
004382
005481
0 04 382
0 04 382
005s89
aazB62
2862
6645
0 05 929
6929
011-55I
001-008
0L1370
00658e
006481
"Methodg for Chemi.cal Ana1yeis of water and ?ila6tee'r,
EPA-600/4-79-o20, March 1983 and subsequent revisions.
I'Test Methods for Evaluating solid Wa6te, Phyeical/Chemical
Method6", Third Edition, November l-985 and ite updates.
STL Denver
SAIVIPI,EW
D5rO90176
wo # SAMPLE# CLTENT SATqPTJE rD
SAIvIPIED SAII,IP
DATE TIME
HJBt"lJ 001
HJEML O O 2
HJ8lvff 0 03
HJSMX 0 04
HJBMz O O 5
HJBMS O O 5
HJBMS O O 7
HJ8M7 O O B
NoIts (S) z
TB-09080s
GW-5C-090805
GV{-Rz-090805
Gw-s5-090805
cw-4A- 09080s
GW-Sa-09080s
GW-R4-09080s
cw-R3-090805
oe / o 8/os
ae/a8/0s 09:15
09/a8/a5 09:25
a9/08/05 10:38
oel oB/os 11: oo
ae / oB/os t-l :50
09/08/as L2t4o
oe / oBl os 14 : l-5
- Thc anrlytical rmlts of lhc s3mplcs llstcd abovc aro prcseiled m the follo*,ing pages-
- .All calculatiom$ ue pcrforfiEd bcforc rouxlin8 m avold round-off errord in calfllrtcd rcslllB.
- Rcsrlts norcd es "ND" werc nor daatcd at or abovc rhc stitcd lltrrlr.
- Thls rcpon nruu not bc reproduc.Ld, erel)l ln ttlt, wltbo,tt hc wdrcn approvel of thr laboratory.
- Resurts lor ole lbllowing pffieters arc ncvc, rcporac{ o,l a dry wclght baelo: color, corrosivity, dmity. fladrpoint, ignirebility. laycrs, odor,
palnr flllcr !cs, pH, porogity pmwe, redviry, rcdox poEntlal, spcclflc gravlty, ryot bsts. solids, slubiliry, temperatur.. vimsiry, md wcight
STL Denver 10
URS Corporation
Cl-ient Sanple TB- O90BO5
GClrf,S Volati].es
PARAMETER
Iot-sanple f---:
Date Saupled,--3
Prep Date. ,. - - -:
Prep Batch *- - -:
Di]-urion Factor:
D5r090a76-001
0e/08/os
ae/ae/os
5253544
1
Ifork Ordr=r S. . , :
Date Received-.:
analysis Date. . i
Rnalysis Time..3
l,Iethod-.- ---:
RESULT .
ND
PERCENT
RECO\rERY
1_02
118
115
11_ 0
HJBMJlAC
ae/oe/os
oe/2a/os
07:03
sw845 82508
REPORTING
LTMIT I]NITS
1.0 uglL
RECOVERY
LTMTTS
(73 118)
(62 l-2 8 )
(ze 118)
(7t 1L7)
Matrix--D--.-..i WQ
Chloroform
STIRROGATE
Dibromof1uoromethane
L ,Z-Dichloroethane - d4
4 -Bromofluorobenzene
Toluene -d8
STL Denver
IIRS Corporation
Client Sanp}-e ID: cI{-5C-090805
w/b+s volatiles
fot-Saryrl-e #---:
Date Saryrled.- - - :
Prep Dat,g-.,.. .1.
Prep BaLch *- - -:
Dilution Factor:
D5I090L75-002
a9/oB/os o9:L5
oe/Le/os
5253544
1
Irlork Order S. . . :
Datse Received. - r
Analysis Date- -:
Analysis Tirne. - !
Method ---:
RESUIJT
4.2
PERCENT
RECOVERY
103
12L
l_ l-4
105
HJEML]-A9
oe/ae/os
09/2A/as
A1 :23
SWB46 B25OB
REPORTTNG
LTI{IT UNITS
lta-trix. .. O . .. , . r GW
PAIUqIVIETER
ChIorofor:m
SURROGATE
1- O rug/L
RECOVERY
LIMITS
(73 LL8)
(62 128)
(7A 118)
(zt l-17 )
Dibromof luoromethane
L ,2 -Dichloroet,hane -d4
4 - Bromof luorobenzene
Toluene - dB
STL Denver L2
URS Corporati.on
Client Sary>Ie rf): GTI-R2-0908O5
Gcllrs Volatiles
Lot-SaryIe *- - -:
Date Sanpl.ed- -.:
Prep Date ---=
kep Batch *-. -:
Dilution Factor:
D5r090L76-003
a9 / a8/ os 09 :25
oe/20/os
5254409
1
Work Order #- - -:
Date Received..3
Analyeie Date--=
Analysis Time.. l
Dlethodo r o . . . . . . r
RESULg__.____-,_--
I$D
PERCENT
RECOVERY
99
97
88
1L 1_
HJEMV]-A8
ae/oe/as
oe/20/os
12:32
SI^1846 82508
REPORTING
LTT{IT UNITS
Itlatrix. - .. . . . . .
PAIU\METER
Chloroform
SURROGATE
1.0 :ug/L
RECOVBRY
LIMITS
(tt LL8)
(62 128)
(78 Ll-8)
(tt 117)
Dibrorno f luorome thane
L, 2-Dichloroethane - d4
4 -Bromofluorobenzene
Toluene -dB
STL Denver
IIRS Corlrcration
Cl-ient Samp1e ID: GW-SS-O9O8O5
GCII{S Volatsilee
PARAMETER
Iot-Sam;lle *- - -:
Date Sarqlled- - - :
Prep Date- -. - - -'-
Prep Batch *- - - :
Dilution FacEor:
D5r09017 6 - 004
o9 / o8/os 1o :38
ae/2a/as
5264409
1
Work Order *-. -:
Date Reeeived- - i
Analysis Date..3
Analysie Time- -:
l-tethod, o . . . o . . . i
RESULT
}.UD
PERCENT
RECOVERY
HJBMXlAE
0e/0e/05
oe/20/os
13:33
SW845 825OB
REPORTTNG
LIMIT UNITS
1.0 :ug/t'
RECOVtrRY
LIMTTS
(zg lt"B)
(62 128)
(78 118)
(77 1r" 7 )
Matrrix,-,.-,---7 GW
Chloroform
SURROGATE
Dibromofluoromethane
L ,Z-Dichloroethane - d+
4 -Bromofluorobenzene
Toluene -dB
105
l,0s
89
l-03
STL Denver L4
URS Corlrcration
C1ient Sarrple ID: Gf5-44-090805
cic/us Vo1atiles
Iot-Sarryle #- - -:
Date Saup}.ed. - - :
fep Date- -. -.. !
frep Batch #- - -:
Dilution Pactor;
D5r090L76-005
a9 / o8/05 11:00
ae/za/as
5264409
1
Ilork Order #, . . 3
DaEe Received--?
Analysis Date- -:
Analysis Tirne. . l
lIethod- - - - - - :
RESULT
}UD
PERCENT
RECOVERY
104
1 l-0
93
105
H.J8M2 1A8
0e/0el0s
oe/20/a5
l-3 :54
sw845 82508
REPORTING
LIMTT UNITS
1- 0 vglL
RECOVERY
LTMITS
(tt 118)
(az 128)
(78 1t_8)
(tt 117 )
t-lat.ri)c. . - - - - - - . 3 Gw
PARAMETER
Chloroform
SI]RROGATE
Dibromoflucromethane
a ,2 -Dichloroethane -d4
4 -Bromofluorobenzene
Toluene- dg
STL Denver 15
IIRS Cortrroration
Client Sanp1e IDr G1{-S4-O9O8O5
cc/tf,s vol-atilee
Ipt-Sanqrle #- - -:
Date Sanpled- -.:
Prep Datgi,....i
Prep Batch S. . . :
Dilution Factor:
Dsr090L76-005
09/08/0s 11:50
oe/2a/as
5264409
1
t{ork Order #. . . :
Date Received- - :
An^alyeie Date- -:
Anal-yeie Time--=
Method - - -:
RESUIJT
}TD
PERCENT
RECOVERY
106
LL2
94
t07
HJ8M51AB
ae/oe/0s
ae/20ios
L4:L4
sw845 82508
REPORTTNG
IJIMTT UNITS
Hatrix.... ,. .. . r GW
PAIU\METER
Chloroform
SI]RROGATE
l, .0 :ug/L
RECOVERY
LIMITS
Dibromof luoromethane
a, 2-Di ehloroethane - d+
4 -Bromofluorobenzene
Toluene -dB
(73 r-l_B)
(62 l_28)
(za 118)
(tt rr7)
STL Denver 16
URS Corporation
C1ient Sanp1e ID: G1I-R4-O90BO5
GC/I'IS Volatiles
Iot-Saqr1e *..,;
Date Saqt1ed,...r
Prep Datg..o,--!
Prep Batch fi-,.:
Oil-ution Factor:
D5r090L76-007
09/08/a5 12:40
a9/2a/os
5254409
1
Itork Order f,. . . :
Date Received- -:
Anatysis Date. - l
Analyeis Time--=
MeEhod-- ----:
RESULT
ND
PERCENT
RECOVERY
104
108
93
111
PAIU\METER
HJglt{61A8 Matrix...rr...-3 GW
oe/oe/0s
oe/2a/0s
l-4:35
sw845 82508
REPORTTNG
LIMIT !'NITS
Chloroform
SURROGATE
1.0
RECOVERY
LIMTTS
(73 1r,8)
(62 1,28')
(78 118)
(77 117)
lrg/ L
Dibromofluoromethane
t, 2 - Di chloroet,hane - d.+
4 - Bromofluorobenzene
Toluene-d,8
STL Denver
IIRS Corporat,ion
Client Satryle ID: GTI-R3 - O9O8O5
GClI{s volatiles
Iot-Sanqrle f .. -:
Date Sampled- - -=
Prep Datgo. i.. . i
Prep Batch *-. -:
Di].ution Factor:
D5r0901,75-008
09/08/0s 14:15
ae/2a/as
2264409
1
Ifork Order fi. . . :
Date Received, - --
Anal.ysis Date.-i
analysis Tirnr:- -:
Method-- ----:
RESULT .
o-18 J
PERCENT
RECOVERY
99
L05
B9
105
HJBM71A8
a9/as/as
ae/20/as
14 ;55
SWB45 B25OB
REPORTTNG
LIMIT UNTTS
Hatril(.. ----: GW
PARAIvIETER
Chloroforru
SURROGATE
1, O rug/L
RECOVERY
LIMITS
(tt 118)
(oz L2I )(za 118 )(tt 1-17 )
Dibromof luoromethane
L ,2 -Dichloroethane -d4
4 -Bromofluorobenzene
Toluene- d8
NCIrE (S) :
J Lslmarcd result. Rcsult Is less then RL-
STL Denver 1B
Iot-Saq>Ie #. -,:
Date Sarpled. . . i
PAIU\METER
D5I090L76-0A2
09 / oBlos oe :15
RESULT
IIRS Corgrcration
Client Sample fD: cH-5C-O9O8O5
aO|fAL Ftetsals
Date Received. . ! A9 / 09 / A5
REPORTING
LIMIT UNITS METIIOD
tlatrix -:GW
PREPARATION- WORK
ANALYSIS DATE ORDER #
Prep Batctr #.
Mercury
Frep Batch #.
Cadmium
Selenium
Prep Batch # -
Si lver
A]-urninum
J\rssni s
Barium
Calcium
Chromium
Copper
fron
Potaseiurn
: 5259437
ND
; 5265193
o-oo24 B
I{D
: 5265237
}ID
L-7
o-o12 B
0-15
1800
ND
ND
o.025 B
500
0.00020 rl;tg/L
Dilution FacLor: 1
o-020
oi luE ion
o - 040
Di Iut. ion
ng,lL
Factc.rr : 20
mg/L
Factor: 2O
rlf,g/L
Fact,or: L
t|fg,/L
Factor: 1
nlg,lL
Factor: l.
wlL
Factor: 1
vg,/T'
Factor: 1 0
r:ltg/1"
Fact.or : 1
Ir|tg/L
Factor: 1
rng/L
Factor: 1
w/r,
Di Iut, ion Factor : 10
sw845 747AA A9/23/As
Analysis Time. .' 1.8 : 28
sw845 602A
Ana11'sis fimo.
SI^1846 5020
Anaiyei e Time .
HJSML].AU
09 I 23-A9 / 27 I A5 rrJSr,tLlA4
05:L7
a9 I 23 -A9 / 27 / Os H-JBMLI-A5
05 :1?
09 / 23 - A9 / 2s / aS IIJSML1AII
o e : a3
og /23 - o g / 26 | asIr.fBr,ILP
t 27:26
0.0i0
Di lut ion
o-1-o
Dl luc i on
o_o15
Dl lut 1on
0.010
D1lut lon
2-O
Di lut ion
0 . 01,0
Di Iut ion
0.010
Dilution
0 .10
Dilution
30
SI^I84 5 5 0108
Analyeie rirne..
STU846 60108
Analysi s fime. .
slIB45 50LOB
Analysis Time. .
sn845 50108
Analysie Tirne. .
sn845 60108
Analyols Tlme. .
sw845 60108
Analysl e Time. .
sw845 50108
Analyols Tlme. .
sr{845 60108
Analyele Tlme-,
oe /23 - o e l28/ os E;r8ltLrAK
ae / 23 -o 9 / zB / as HJBrru,lAL
a9 / 23 -Oe / 28 / os EJETILLLV
ae / 23 - oe / 28 / os HJBML:.AT,I
09 / 23 - 09 / zB / os H..TBMrrlAN
09 / 23 - 09 / 2e / AS rr^TSULLAI{
a9 I n -as I za / os H.TBHrrar(
09:43
09:43
01:00
09:43
09:{3
2L:26
sw846 60L08
Analyele Time. .
next page)
STL Denver
(Continued on
01:00
Lot-Sanple *.
IIRS Corporation
Client Sample fD: cW-5e-O9O805
TOTAL Meta1s
: D5r090175-002 Matrix...o.,...i GW
REPORTTNG PREPARATION-
AI\TALYSTS DATE
WORK
ORDER #PARAMETER RESg,llq LI}IIIT UNITS METHOD
ldagaesiurn
Sodium
IiIickeI
Lead
Vanadium
Zinc
Zi rconium
HOTB (s) z
660
6900
0-020 B
ND
o_oo39 B
o_oo77 B
TTD
O - 20 rug,/L
Di lution F'actor : l-
50 mg/t
oilution Faet,or; 10
0 - o4o mg/L
Dilution Factor, I
0.0030 mg/L
Pilution Factor r 1
0 - 01,0 rrq,/L
oilution Factor: 1
O. O20 rfig/L
Dllut,lon Factor: I
0.015 mg/l-
Dilutlon Factor: 1
oel23-oe/26/os
ae / 23 -ae /28 / os
oe l23 -ae l28l os
oe / 23-ae /28 / a5
ae/23-os/zfE/as
EJBITIILAO
EJBULLAI-
EJ8lTLLAP
HJEML1AQ
IITST,ILLAR
sw845 50108
Analyeio Time..: 2L:25
sw846 50108
analyeie Time. . : 01 :00
sH845 60108
Analysie Time..: 09:43
sw845 50108
Analysle Time--: o9:43
sn845 50108
Analyeie Time..: 09:43
sw845 50108
Analyeie Time..: 09:43
sw84 6 5 0108
Analyeio Time..: 2L:?5
09 / 23 - O e / 28/ As ETTEULLAT
a9 / 23 - Ae / 26 / As HJBI{rJIA2
B Eslmatr{ result. Rcsult is less than R[..
STL Denver 2A
IIRS Coqporation
Client Sanqrle fD: Gfl-R2-O9OBOS
TOTAIT Metals
I^oL-Sarqlle *---:
Da.te Sarryled...i
PARAIUETER
D5I090L75-003
09 / oB/05 09:25 Date Receiwed -
RESULT
REPORTING
LIMIT I,INTTS
: 09/os/os
METHOD
Dlatrix.:GW
PREPAITJ\TTON- I/IORK
AI{ALYSIS DATE ORDER #
Prep Batch #-
Ivlercury
Prep Batch #-
Cadmium
Selenium
Prep Batch.
Si lver
.Llumimrm
Arsenic
Barium
Calcium
Chromium
Copper
fron
Potassium
: 5 259437
ND
: 5265193
ND
o. oo50 B
#- - -: 5265237
ND
a .16
ND
0 .95
94
o_oo30 B
ND
0-s3
330
0 - 00020 mg/L
Dilution Factor: 1
0 .010
Di Iut i on
o-10
oi 1uE ion
0.015
Dilution
o_o10
Di }ut,l on
o-20
Di ]trui on
0.010
Di 1ut i on
o.010
Di lut i on
o_10
Dl luc ion
ng/L
Faetor: I
tw/L
Factor r 1
mg/L
Factor: 1
rglL
Factor: I
ms/r,
Factor: 1
mg/r
Factor: 1
ng / t''
Fact or : 1
nryJ,/L
Factor: I
oe/23-ae/zB/os
oe/ 23-ae l2B/ os
oe/23-oe/25/os
oe/23-oel28las
ae/23-a9/28los
ae / 23 -oe l2o I os
HJBTVIV1A4
HJEMV1AU
II,JBTffI-;trV
HJ8}T\IIA5
ILIBTI\rUAW
HJSIVIVlAX
EJSI{\IUA6
swB45 747AA 09/23/Os
Analysie ?ime..: 18:33
0.010
Dl lution
o ,020
Dilution
mg/L
Factor: 10
ry/L
Factor: l" 0
sw84 6 502 0 09 / 23 - A9 / 27 / As HJBTWT.AF
Analysio Tlme..: 05:20
sw846 6A2A A9 /23 -09127 / A5 rr^fBIrf\fL'AG
Analysis T'ime. . : 05 :20
3.0 mg/L
Di lut i on F'act or : L
sw846 50108
.Ana1yeis Tiue. - : 09:48
sr{845 50108
Analyele Time..: 21:31
sw846 50108
Anal),sle Time. .' 09 :48
5T1846 60108
Analysis Time..: 09:48
svr845 50108
Analysls TLme.-, 21:31
sIr845 60108
Analyele Time..: 09:48
sw845 60108
Analyeie 'I'ime. . : 09 :48
sw845 50108
Analyols Tlme..: 2I:31
sr{845 50108
Analysie Time,.: 21:31
ae / 23 -09 / 28 / As HJBTfiIIAR
og / ?,3 - og /26 / osrr,Jgt{vr o
09 I 23-09 I 26 I os EtBuvLA,T
STL Denver
(Continued on nexL page)
21
Iot-Saq>le #.
PAIU\METER RESUTT
IIRS Corporation
Client Sarrple ID: GIII-R2-090805
IIOIAL Dtetals
: D5f09A7-75-003
REPORTING
METHODF.lI'tT'L.___ uNrrq
DIatrix. . . . D - - - , : GW
PREPARATION-
AI{ALYSIS DATE
Hagneeium
Sodium
Nickel
Lead
Vanadium
Zi.oc
Zirconium
NOTE (S} :
L20
6900
o.oo2l B
ND
0,0038 B
o-oo95 B
o.0030 B
o -2a rrg,/L
Dilutlon Factor: L
50 w/t
Ollutlon FacEor: L0
O. O4O rrrgll
Di.lution F'actor : 1
0.0030 tltg/L
Dilution Factor: 1
0-010 r,lq,IL
nilution Factor: 1
o - o2o wg/L
Dilutior: Iractor: 1
0 - 015 W/l'
Di Lut ion Fact,or : 1
oe [23 -ae / 281 os
ae / 23 -os l2B I as
oe /23-oe /26 / as
WORK
ORDER #
E.I8!I[VLhA
EJSIIIILAC
ILTET,T\TIJA.O
HJSIvI\r141
HJBTIVLA2
H^}8ITVIL3
IIJBT,T\NAD
sw845 60108
Analyolo Tlme".: 21 r3L
sYrB45 60108
Ana1yslo Tl.me..: 01 :18
srr846 60108
Arralysis Time. . : 09 r48
ae/23-oglzs/os
oe/23-ae/2t;/as
oe /23-oe /28/ as
sw846 60108 oel23-Ae/28/os
Analysie Time.-: 09:48
sI{845 50rOB
Analysia Timo..: 09:48
srr846 60I"08
Ar:alysie Tine, . : 09 :48
sw846 60108
Analyoie Time,.' 21:31
B Estiunted result. Result is less thur ItL.
STL Denver 22
t RS Corporation
Client, Sample ID: GI{-SS-090805
BOtrAL ltletale
Iot,-Sample #.. -: D5I090L76-O04 ltlatrix.......: GW
Date sarrqrled...: 09/08/05 10:38 DaEe Received- -= o9/O9105
REPORTTNG
PAIU\METER RESULT LII,IIT UNTTS METHOD
PREPAIU\TTON- WORK
AIVALYSIS DATE ORDER #
Prep Batch #., . i 5259437
Mercury ND 0.00020 vg/t sw845 747oA a9/n/a5 HJ8MX1A4
Dilutlon Factor: 1 Analyeie Time-,; 18:35
Prep Batch *- - -: 5265193
Cadmium ItD 0.00s0 mg/t sw845 5020 09/23-09/27105 HJBMX1AF
Dilution Factor: 5 Analysie Time., t O5:24
Se1eni rrm 0-0022 B 0.0r.0 wlt sfl846 6020 a9123-o9127/05 EI8lrXljAG
Dilutlon FacEor: 5 Analysls Time.. r o5z24
Prep Batch #.. -: 5265237
silver ND 0.010 mg/r. sw846 50108 O9/23-A9/28l05 HJEMX1AR
Dilution Factor: 1 Analyais Timc..: 09154
Aluminum 0.034 B O.r.O wglt SW845 50108 09123-09126105 ErglgJ
Dilution Factsor: I Analyais ?ime.. r 21151
Arsenic O - OO45 B 0.015 sqlt SW845 501OB O9l2!-O9128lO5 rr^rEidxrAu
D11ut,Ion Eactor: 1 Altalyeie Time..: 09:54
Bariunr o -24 o-o1o wlt sw846 5o1oB o9123-O9/28los U^rSrDnAV
. oilution Factor: t Analysis Time-.: o9r54
calcium 43 o.2o vqll, sw846 5o1oB os/zl-oslz6/o5 rr,J8trxl,As
Dilution Facr-or; 1 Analyaia Tine..: 21:51
chromium ND 0.01"0 mg/t, sw845 50108 09/23-09/28/05 HJSMX1AW
pilurlon Factor: 1 Analyeie Tlme..: 09:54
copper ND 0.010 mg/L SW846 50108 A9/23-O9/28/OS HJ8MXIAX
Dilution FacEorr 1 Anall'sir Time..: 09:54
fron o-19 o-1o I[rg,/L sw845 60108 09/23-09126/05 Eir8rltlftA6
Dllutlon Factor: L Analyele Tlme..: 21:5I
Potassium 150 3-0 W/L slr845 50108 09/23-09126/05 H^]sI,Dfla7
Dilution Factor r I Analysis Time. . : 2l :51
STL Denver
(Continued on next page)
23
Iot-Samglle # -
PAIU\METER RESULT
tlRS Corporat,ion
Client Sample ID: GI{-S5-O908O5
lOirAL Ueta1e
; D5I090175- 004
REPORTING
LIMTT UNTTS
Matrix.........r GW
METIIOD
PREPARATTON-
A}TALYSTS DATE
WORK
ORDER #
Magnesium
Sodiunr
Iilickel
Lead
Vanadirun
Zinc
Zircorrium
N(ITE (S) :
92
3000
0-0024 B
T.TD
o.oo27 B
ND
o. oo17 B
0 .20 rnq/t
Pilut ion Factor : 1
5. O rg/I'
Dl lutlon Pactor : L
0 - 040 nrg/L
Dilutlon Factor: 1
0.0030 mg/L
Dilution Factor: L
0. OLO nq,/L
Dilut.lon Factor: L
0.020 rng/L
Oilution Factor: 1
O. O15 rq/l'
Di lution Eactor : 1
ae/23-oe/26las
aelz3-og/zs/os
ae/23-oelzslos
oe/23-ae/28/as
oe/23-ae/28/as
ILTBI.[XI.AA
HrIE!,IXIAC
ET8HXI.a'O
HJgI,IXIAl
E*I8l'IXIA2
slt845 60108
Rnalygig Time. . ; 21 :5L
srr846 60108
Analysie Time. . : 21 :51
slr845 60108
Analysis Time-. r 09:54
sw845 601_08
Analyaie Tirne. . : o9 : 5{
sw845 50L08
Rnalyeis Time..: 09;54
sw84 5 6 0108
Analyais Time.,r 09r54
sw845 50108
Arralyoie Time. . : 21 : 51
oe I 23 - a9 I 28 / 05 HJBID(]-A3
09 / 23 - o 9 / ze / os Ir^TBIrrxl-AD
B Estimaretl result. Result is hss thur RL.
STL Denver 24
Iot-Sample ff...;
Date SarylJ-ed. - - 3
PAIiAMETER
IIRS Corgrcration
C1ieut Sample ID: G[{-4A-09O805
TOTAL Uetals
D5r090L76-005
a9 / 0B/05 11 ; 00 Date Received. . ! 09 I a9 / 05
RESULT
REPORTING
LIMTT UNTTS IvIETHOD
Matrix.-.....i GW
PREPARATTO!{- WORK
AIVALYSIS DATE ORDER #
Prep Batch #.
Ivlercury
Prep Batctr
Cadm:iurn
Selenium
Prep Batch
Si lver
Atuminum
Argenic
Barium
Calcium
Chromium
Copper
Iron
Potagsiun,
:5259437
ND
#...: 5265193
0-0011 B
0-0083 B
; 5265237
ND
36
o. oo98 B
4.47
110
0.o45
a -o72
32
300
0.00020 mg/L
Dl lutlon FacLor : 1
0-010
ni 1ut ion
o-020
Dr lut ion
nI{/,/L
Factor: 10
trfry,IL
Fact.or : 10
0.0L0 mg/t
ni 1ut l-on Factor : 1
0 - 10 rrq,/L
Dilution Factor: 1
O. O15 W/I'
Dilution Fact.or: 1
O - 01,0 vry,ll,.
oilution FacEor: I
0 - 20 trg/L
Oi luE ion Fact.or : 1
0. O10 W/L
Dilution Pactor: L
O - O1O rng/I'
PiluEion Factor r 1
0.1-0 trg,/L
nilution Factor: 1
3.0 w/t
OiIuEion Factor: 1
HJ8M21.A4
a9 / 23 -o e / zB / os H,rBr{zrAU
oe / 23 - a9 / 28 / 05 HJBr,r2 lAR
os /23 -0 s / 26 / asrlrslrzJ
sw845 7470A Ae/z3/As
Analynis Time..: 18:35
srr846 6020 O9/23-O e/27 I Os rIJ8I.{2LAF
Arralysie Time. . : OS :27
sw845 6020 09123-A9/27 lOS EJElt2rAG
Analysis Tirne. . : 05 :27
#.
sw845
Analysi e
sH846
Analya i o
sn846
Analysi s
sH845
Analysi s
sru845
Anal,ysi s
sw845
Analyoi o
SH845
Analygi g
sw846
Analysi s
6 010B
Time. . r 09:59
601-oB
Time. , : 2L:55
50108
Tine..: o9:59
50108
Tine..: 09:59
60108
Time..: 2t=56
50108
Time-. r 09:59
60108
Time..: C9:59
50108
Tlme..:2L:56
oe /23-ae /28l0s
ae/23-oel26/os
oe/23-oel2B/Os
ae /23 -o s /28/ os
os/23-oe/ze/os
EIB!,I2LAV
IIJS}T2LAs
II,JBT{2IAW
E^T8U2IN(
HJBI{21A6
sI{845 50108
Analysis Time..: 2L:56
on next page)
STL Denver
( Continued
oe In-ae/z6/ os E*TBII2IA7
Lot-sanqrle *.
IIRS Cora>oration
Client Sangrle ID: Gctt-4A-OgO8OS
T0IAL Metals
: DSI090L75-005
REPORTING
Ilatrrix-- ----: GW
PREPARATION-
AIVALYSTS D.A,TE
9[ORK
oRpER *PAIUIMETER RESUTT LIIyIIT UNITS METHOD
Magnesium
Sodium
Nicke1
Iread
Vanadium
Zi.nc
Zirconium
r{o1E (s} :
97
6s00
o -042
o-o28
o-057
o -2L
0-023
0.20 W/L
Dilution Factor: 1
50 nry,/r'
OiluEion Factor: 10
0.040 rrg/t'
nilution Factor: 1
0 - OO3o rrEllt
Pilution Factor: 1
0 - O1-O rg/t,
Dilut.ion Factor: I
o - 020 vqlL
oilution Factor: I
O - o1-5 ug/t
Dilution Factor: 1
s"ItB46
Analyei e
srr846
Analyai s
s'H846
Analyei o
sw845
Rnalysi s
svr846
Analysi s
svr84 5
analyai g
sr{846
Analysi s
60108
Tine..: 2L:56
50108
Time.. r 01:23
a9 / 23 - a9 / 26 I as ETBtrzlaA
09 / 23 - oe / 28 / as rLTBu2rAc
60108 A9/23-09/2BlA5 E^T8I,{21'.jA,O
Time..: 09r59
5oloB o9/23*o9/2s|a5 Efgltzr,Ll
Time. . : 09:59
50108 o9/23-09/2glas E^T8lr2la2
Time..: o9:59
5O1OB A9/23-09/28/As EJsrrl2rL3
Tirne..: 09:59
5OI-OB Oe / 23 - O e/ 25 / Os EJ8![zr"An
Time, - r 2Lt56
B F-stirnaed re.suk. Rcsult is less than RI.,.
STL Denver
IIR.S Corporatsion
C1ient Sanqlle ID: GTI-S4-O9O805
TOtAL Meta]-g
I,ot-SarrE Ie *.. .: D5I090L76-006 Matrix.. -. . -.: GW
Date SaryI.ed- - -= o9/os/05 11:50 Date Received. -z og/og/as
PARAMETER RESULT
REPORTTNG
LTMIT UNITS METHOD
PREPARATION- WORK
AIVALYSTS DATE ORDER #
Prep Batch #---: 5259437
Mercury ND 0.00020 lrlrg/L SW845 747AA 09/23/05 I{JBM51A4
oilution Factor: 1 Analysie Time..; 18;38
Prep Batch #---= 5265193
Cadmium DID 0 - 0050 mg/t sw845 5020 og/23-oe/27 /o5 HJBMSTAF
DiLut.ion Factor: 5 Analyoio Time..: 05r31
seleuium o.oo53 B o-o1o w/t sw845 6020 09123*09/27105 Er8r,IslAG
oilution Factsolr 5 Aralyolo TLme,. ' 05,31
Prep Batch #---: 5265237
S i lver DUD 0-oL0 nglr. swg46 60108 09/23-09/28105 HJBM51AR
oilution Factor: 1 Analyole Tlme-.: 10:04
Aluminum ![D 0 .10 r,flg/t sw845 50108 09/23-09 /26105 IIJ8M51A
Dilution Factor: 1 Analyaia Time.. z 22t0L
Arsenic tdD 0.015 mg/t sw846 60108 O9/23-O9/2SI05 HJ8M51AU
DiluElon Factor! 1 Analyois Time..: 10:04
Bariurn o-12 0-010 w/t sw846 6oloB o9123-ae/28los ErSI.rslAV
Dllution Factorr 1 Analyeie Tirne,.: 10:04
calcirur 59 O-2O Iflg,lr, SW846 60108 09123-09/26105 E^r8lrsl-As
Dllution Factor: 1 Analysie Tlme,.r 22:01
chromium ND o.o1o rng/L sw846 50L08 Ag/23-Og/28,/05 H.,8M51AW
DiluElon Eactor' L Analysia Time.,: t0:04
copper ND 0-010 ms/r, sw846 60108 09/23-09/28/05 HJ8M51AX
DlluElon Eact,or: 1 Analysie Time,,:10:04
Iror.o-L4 o.1o vg,lL sw846 60I-08 O9/23-oe/26l05 S,r8Il5LA6
Dilutio[ Factors ]. Analyais rime..: 22101
potassium 29a 3.0 wll, sw845 50108 agl8-09125/05 HJ8il51A7
Dilution Pactor: 1 Analyeia Time..: 22:01
STL Denver
(Continued on next page)
27
I.ot-Sarylle # -
PABAIVIETER_. __ _ .. BESULT
IIRS Corlrcrat,ion
Client Sample fD: GT{-S4-O9O8O5
IO(IAL Dletals
: D5I090176-005
REPORTING
METHOD
Matrix--.......! GW
LIMIT UNITS
PREPARATION-
AhIALYSIS DATE
WORK
ORDER #
Magnesium
Sodiun
NickeI
Lead
Vanadium
Zinc
Zi'rconium
No1ts (s) :
150
4500
ND
IUD
ND
ND
o. oo?4 B
o_20 vlg/L
Di lut ion Factor : L
5-O rry/L
Di lution Factor: 1
0.040 rrlrg/L
Dilution Factor: 1
0.0030 mg/L
oilution FacEor r 1
0 . 010 mg/t
Dlluclon Factor, 1
0 .020 mg/L
Dilution Factor: 1
0.o15 rg/L
Dilution FacEor: 1,
sw846 50108
Analyelo Tl.me, . : 27 taL
sw846 60108
Analyele Time..r 22zAL
sw845 50108
.Bnalysis Tirne . . : Lo : o4
sw845 50108
Analygie Tirne. . : 10 : 04
sw846 60108
Analysis Time. . : 10 :04
sw845 50108
Analysie Tirne., ; 10 : 0{
sw846 60108
Analyeis Time..: 22:0L
oe/23-oe/26/Os
ae/23-ae/zo / os
oe /23 -ae / 2s / as
oe/23-oe/28/os
ae/23-ae/28/05
B^TB!,I5IAA
EJSIIsLAC
HJ8M5]-AO
HJ8M51A1
HJ8M51A2
os I 23 - os / 28 / 0s HJ8M5 1A3
a9 /23-09 /26/ Os rLTBr.{srAD
B Fsnrnarcd result. Rezuh rs less than RI..
STL Denver 28
Iot-Sarqrle *- - .:
Date Sanpled...!
PAITAIVIETER
URS Corporation
Client Sanp1e ID: GIil-R4-090805
TCXIAIT l-Ieta1e
D5r090L75-007
A9 / 0B/05 L2;40 Date Received- - : oe / A9 / 0s
RESULT
REPORTING
LTIvTIT UNITS METHOD
Matrix-:GW
PREPAIT'\TION- WORK
AIVAIYSIS DATE ORDER #
Prep Batch #.
Mercury
Prep Batch #-
Cadrnium
Selenirur
Prep Batch #-
S i lver
A]-uminum
Arsenic
Barium
Calciunt
Ch,rornium
Copper
Iron
Potagsium
:5259437
IUD
:5265193
DUD
o-oo38 B
: 5265237
ND
2-L
ND
1-5
s5
o. oo48 B
ND
3-0
2LA
0.00020 mg/L
Di lution Factor: L
0.00s0 mg/L
Dilution Factor; 5
O - 01-0 ntg/L
Dilution Factor: 5
rilg/L
FacEor: I
$q/I'
Factor: 1
mg/L
Fact,or: 1
rW/r'
Factor: 1
mg/t
Factor: L
mg/t
Factor: L
mg /t
Fact,or: 1
wg/r'
Pactor: 1
oe/23-oe/28/As
ae/zt-oe/26/ as
oe/23-oe/2e/05
oe/23-oe/28/As
oe l23-ae/26/ as
oe/23-o e/28/os
os/23-0e/28/os
oe/23-oe/26/as
IIJ8I.T6'A.
HJBM61A4
HJ8M51AR
I{J8M5]-AU
IITBHSLAV
EJBIIIGI-;h5
EJSM6IA?T
HJ8M51AX
Ir.T8l.{6r.A5
sw846 747AA A9/23/Os
Analysia Time..: 18:{0
sw845 6020 09/23-09/27/05 HJBrvl5LAF
Analyols Tlme. - , 05 :35
sr{845 5020 A9/23-A9/27 /A5 H,J8!{5LAG
Analyaie Time,.: 05:35
0 ,0l-0
Dl }ut l on
o-10
ol IuL lon
0.0L5
D:Iut ion
o-o10
oi IuE i on
o_20
Di Iu; ion
0 .010
Di lut i on
0.010
ni lut i on
o-10
oilution
3'o w/L
Dilution Factor: 1
SWB45 5O1OB
Analysis Tirne. . : 10 : 09
srr846 60L08
Arralyeie Time. . : 2?z QG
sw845 50108
Analyoio Time..: 10:09
sw845 50108
/\nalyoio Tlme. . : L0 ; 09
s'w845 60108
arralyela Time, . : 22 :06
sTI846 50108
Analysie Time..: 10:09
sIlI84 5 50108
Analysis Tlme. . r 1.0 ; 09
sH846 50108
Analyeie TLme..: 22z06
s'w945 60108
Analyeie Time..: 22:06
nexE page)
oe I 23 -o 9 / ze I os HJBUGTAz
STL Denver
(Continued on
29
Iot-Sarqrle *.
IIRS Corporation
Cl-ient Saryle ID: GW-R4-0908O5
TOTAI, Uetalg
: D5I09 AL7 5 - 007 MatriX...-.....3 GW
REPORTTNG PREPARATION-
AI{ALYSIS DATE
WORK
ORDER #PNUqMETER RESULT LIMIT UNTTS METHOD
Ma.gnesiurn
Sodlum
Iilickel
Lead
V:.nadium
Zinc
Zirconium
NO([E (S)
=
48
3200
0-oo41 B
ND
o-oo55 B
o_ol3 B
o-oo32 B
o-2o rng,lL
oilution Factor: 1
s-O trry,lL
Oilution Factor: I
o -o4o WlL
Dilution Factorr 1
0.0030 mg/L
Dllutlon Factor: 1
0 - 010 vlry,/f'
Dilution Factor: 1
o, o2o mg/t
Pilution Factor: I
O. 015 mglY'
Dilution Factor: 1
sw846 501OB
Analyeie Tlme..: 2?:A6
sH846 50108
Arralysis lime. . : 22 :06
slI846 60108
Analysis Time-.r 10:09
sw845 60r_08
Analysie Time..: i0:09
sH846 60108
Analysie Time. . : 1,0: 09
sw846 60108
Analysia Time..: i0:09
5-W845 50108
Analysls Tlme.,: 22:06
oe / 23 -ae /26 / os
ae/23-ael26/as
oe/23-oelza/os
oe/23-0e/28/os
oe/23*oe/28/os
E.}8U5IAA
E.T8I{51AC
E^}8M6UAO
HJ8M51.A1
E;I8II{5742
a9 / 23 - Ae /28 / as EJ8M6rL3
ae I 23 - ae / 26 / os rrJBt{6LAD
B Estimated re:u,rit. Result i.s le.$s rhan RI..
STL Denver 30
Iot-SatryIe *, - - =Date Sanp1ed.,.i
PAIU{METER
IIRS CorlrcraEion
Client Samp1e ID: GW-R3-09O8O5
TOTAIT ltIetals
D5r090L76-008
09 / 08/05 14 :15 Date Received- . : 09 / a9/ 05
RESULT
REPORTTNG
LIMIT UNITS METHOD
l{atrix.:GW
PREPARATTON. WORK
AI{TALYSIS DATE ORDER #
Frep Bateh #,
Mercury
Prep Batch #.
Cadruium
Sef-enium
Frep Batch #.
Si lver
^A,lurni num
Arserric
Barium
Ca]-cium
Chromium
Copper
Iron
Potassium
: 5259437
ND
:5265193
o - ooo25 B
o-oo28 B
: 5265237
ND
ND
o. o11 B
o -72
43
ND
ND
0 .14
1s0
0.00020 mg/L
Dllutlon Factor: I
0 ,0050 tng/L
Dllutlon Factor r 5
O. OIO vtg/L
Pi.lution FacEor : 5
0 - 010 ntg/ L
Dilut.ion Factor: 1
0 . 10 r;rg/L
Di lution Factor : 1
O - O15 rrrg,/I'
Oilution Factor: 1
0 - 010 vtg/L
Pilution Factor: 1
0 ,2O rrrq/L
Dilutlon Faetor r I
0 . 010 mg/T'
Di lut ion F'actor : J,
0.010 mg/L
Dilution Factor: L
0 - L0 rry/L
Dllut,ton Factor: 1
3.0 ng,lL
D: Lut ion Factor: 1
sw845 501_08
Analysis Time. . : 1-0 :ld
sw84 6 6 0108
Arralyeis Time. . : 22 :Ll
sII845 50108
Analyols Time.,: 10:1{
srr846 50108
Anal1,sis Tirne. . : 10 : 14
sw846 50108
Analyeie Tlme, - : 2? :lt
sw84 5 5 0108
"Arlalyeie Tirne, . : 1"0 : 1,4
s!{845 5010B
Rnalysie Time. . : L0 :14
sIt84 5 501-OB
Analyele Tlrne. . : 22 :7I
sI{845 50108
Analyeia Time..: 22:lL
ael23-0e/26las
ae/23-09/28/os
oe/23-oel28/os
oel23-ael26las
s'r{s45 6020 a9 /23-09 /27 / A5 H,rBtrTLAF
Arralysie Time. . : 05 :38
sw845 6020 OelzA*Oelz7 /As H.rBUTraG
Analyels Time.,: 05:38
sw846 747oA A9/23/0s
Analyeie Tirne.. r LB:41.
HJBM7l-A4
09 I 23 - a9 / 2g / os ITJBIT{zLAu
ae I 23 -0 9 I 28/ 05 ET8M71A\I
a9 / 23 -09 /28 / os HJ8M71AR
os / 23 -as /26 / a5 HJ8M7r^o
ILTEI{7145
HJ8M7].AW
HJ8M71A)(
ILTS[{7I45
ae l 23 -o e / 26 l as ETTBMT rrut
STL Denver
(Continued on next page)
31
Iot-sauple # -
IIRS Corporation
C}-ient Sample ID; GH-R3-Ogo8os
TOTAL Hetals
: D5I090175-008 Hat,rix- - - - -. . . . ! GW
PAITJ\METER RESI]LT
REPORTTNG
LIMTT I}NTTS
O.2O vq,/L
niLution Factor: 1
5.0 ng,lL
Di1ution Factor: L
o-o4o rg/L
Di Iut ion FacLor : l.
0 - 0030 mglL
Dilution Factor r 1
O - O1O nry,/L
Di lution Factor : l-
0 - 02o ng,/L
Dilution Factor: I
0-015 vg,/L
Dllutlon Factor r I
METHOD
PRBPARATION.
ANAI,YSIS DATE
WORK
0RDER #
Magurresium
Sodium
Iitickel
Lead
Vanadium
Zi-nlc
Zirconium
46
2soo
o. oo3t B
tlD
o-0427 B
a
o. oo50 B
o.oo88 B
sw846 60108 Oe/23-oe/2s/OS
Analyais Tirne. . : 22 zLL
ILTEII{7IAA
sn845 50108 O9/23-O9lzSlAS E.IEHTIAC
Arralysis Time. - : 22 :\L
sw846 5O1OB Oe/23-09/28lAs EJ8U71AO
A.nalysis Tirue. . : 1,0 : 1{
sw84 6 5 0108 09 / 23 - A9 / 28 / 0s HJEM?IAI
Analysia Time. . : 10 r14
s?I846 5O1OB 09/23-O9/28/05 lrrr8rr{7rA2
Analysia Tima. . : 10 : 1,4
sw845 60108 A9/23-O 9/28105 ErEUTLiLi
Ana1)rsle Tirne. . : 10 : 14
slr84 5 5 01OB 09 / 23 - 09 / 2S I aS rrr]81,r7 LAD
/rnalysis Tlme. .' 22 :ll
NOTE (S)
=
B Estinurcrl rcsult, Rcsult Is lcss than Rl..
STL Denver 32
Iot-Saryl1e #. . .:
Date Sanpl-ed---:
PAITJIMETER
IIRS Corlrcration
Client Sanqrle ID: GII-SC-O9O8O5
Geuera}. Cherniatry
D5I090L76-002 llork Order *---: HJBML
09/08105 09;15 Date Received..r 09/09/05
RESULT RL UNITS METHOD
tlatrix-- ----: GW
PREPARATION-
A}IALYSIS DATE
PREP
BATCH #
pH
Anmonia as N
Chloride
Fluoride
Nitrate
llitrate-Nitrite
Su].fate
TotaI Cyanide
N0rE (S)
=
Dilution Pactor: 100
0.0O3L B 0-01O rrry/L
Pilution FacEor: I
7-2 O.1O No Urita SI{845 9O4OB Og/OglaS 5252536
Dllution Factor: 1 Analysla Time..: 15:37
3OO0 Q 1OO rylt tcArm 350.1 O9/2O-O9|2L/OS SZeS*Zl
Dllutlon Factor: 1000 Analyels Tlme..: o3:00
19000 J,Q 12OO rg/t UCAWIT 325.2 O9|LB{OS 5263255
Dllutlon FacEor: 500 Anal,yBlo TIme..: 17:00
o-85 J O-1-O w/t, rrtCAWn 340-2 Og/tt/OS 5257s7A
Dilutio! Factor: I Analyais Time.. r 13:15
5OO O-1O nglt lrCArIw 353.2 OglLglos 52655A6
Dllution Factor: 1 Analyaia Tine..: 16100
soo Q
orr,.t3' ,,".of/01 Jffi ii"1.1, or,oo
aelzo-oet2u,s s26sst,!
32OO ir,Q soo IfIq/t ItcAIfvI 3't5-1 OS/ZAIOS s272]-72
Analysis Time. . : L5 :40
sr{845 9O1OB/9O12A A9/21-09/22/ Os s264s3e
Analyele Time. . : 1.2 : 00
RL Rcponing Linrit
a Elcvatetl reponing limit. The rcportlng llmlt Is elcvatcd due lo high anal,vtc lcvcls.
J Merhod blank contarnlnadon. Thc associuted npthod blar& colrtains the target analyte at a rep()ruble level.
ts tstirnatetl rerult. Re.sult is less than RI..
STL Denver 33
L'ot-Samp1e l#...i
Date Saqlled-,-i
PAIUU\,IETER
IIRS Corporation
C1ient Sarqrle fD : GII-R2 - O9OBO5
General Chemistay
D5f090L76-003 }Iork Order #---: HJBI,IV
A9 / 08/05 09 t25 Date Received- - : 09 / 09 / 05
Matrix.......--: GW
PREPAXATTON- PREP
A}IAIJYSIS DATE BATCH #RESULT RIJ IJ}.TITS METHOD
1-A 0.10 tlo Ilrrire SW846 90408 O9|O9/O5 s25.2536
Dilution Factor: I ,rnalysis Tlme.. : !5:42
8-6 Q O.2A vq/t UCAWW 350.1 O9127/O5 s27L4s4
Dilution Factor, 2 Analysis Time-. z 22toQ
tzooo J,Q 25O wlt UCAWH 325-2 O9/]j3rA5 52632ss
pllutlon FacEor: 100 Analyele Time.. r 17:00
0.85 J O-1O v,glr, ITTCAIJW 340-2 O9lL4lO5 525757A
Dl}utlon FacEorr I Analysia Time,.r 13:15
0.039 B O.r,0 w/t MeAm{ 353.2 O9/O9/A5 s26ss86
Dllutlon Factor: 1 Analysie time.,: 16100
0-043 B O.1O ug/t, Ir{CAI{W 353.2 O9|2A-O9/2L/O5 5265552
Dilutlon Factorr 1 furalyola Tlme..: 02:00
5?O J,Q 25A ,rg/t l{CAnW 375.4 OS/ZA/OS 5272L72
nilution E'actor: 50 Analyaie Time..: 15:40
ND O -O1O mg/r, slr846 9O1OBl9o1-2A 09/21-OS/ZZ/OS 5264539
Dilution Factorr 1 Analyeie Tlme..: 12:00
PII
Alrnronia aB IS
Chloride
F]-uoride
Nitrate
Nitrate-Nitrite
Sulfate
Total Cyanide
NcrE (S)
=
RI- Reporting Limit
q Elcva*"d rcponlng llrnlt. The reponing limit is elevated tlue to hlgh analytc levels
J Mcthod blank contaminadon. The associaterl urctltod bknk conuins rhe nrger analyte at a rcportablc lcvcl.
B Estlnratcd resulr. Result is less than RL.
STL Denver 34
Iot-Sample fi.. -:
Date Saq>}ed,.,!
PAIUqMETER
IIRS Corporatsion
C1ient Saryle If): GTI-S5-O9O8O5
@neraJ. ChemlBtrry
D5I090L76-004 Work Order #---r HJBI\D(
09/08/0s 10:38 Datse Received- -: a9/a9/05
RESUTT RL UNTTS METHOD
Hatri:c. , , . . . . . . ; GW
PREPAITJ\TTON- PREP
A}IALYSIS DATE BATCH #
pE
Arrnonia aa t{
Ch]-oride
Fluoride
Nitrate
xitrate-IUitrite
Sulfate
ToEaI Cyanide
DrorE (s) :
nilution Factor: 1
O - 10 trrg/L
Dilution Fact.or: L
8.1
5-s
0-9s
0 _L5
o .16
39O J, Q
IVD
4700 J, Q 25O vq,/L
Dl1ut ion Pactor : 1.00
o-1o W/L
oilution Factor: 1
O.10 tfig/L
Di ]uLion Factor : 1
O.1O vglt'
Di lut,lon Factor : I
1-OO vtg/I'
Dilution Factor: 2A
0.010 mg/L
Dilution Factor: 1
Analyaie Time..: 02:00
ucArrr{ 37s - 4 09/ zfE/ as
Analysle Time..r 15:40
o - l-0 No Uuiro sII845
Analyol o
90408
TLme..: 1.5r50
IUCAWW 350.1
Analyoie Tine. . : 03 :00
IT|CAI{W 325 -2
Analyeie Time..r 17:00
IricAI{W 340.2
AnaLysig Time, . : 13 :15
UCAIIW 353.2
Analyelo Time-., L6:00
ucAr{r{ 353 -2
oe / 0el 0s
09/20-oelzllos
ael 18/os
oe/L4/ os
ae/aelos
ae/2o-oe/27,/as
5252536
5265473
5263255
5257578
5255585
s26ssr2O
5272L72
sw845 eo1oB/e012A oe/TL-oe/22/0s s254s39
Arralysie Time. . : 12 : 00
RL Reportirtg Lirnit
J Method hlurk contlrnination. 'l'he asvrciarcd methcxl blank conains the target analyte at a refx]rtahle level.
0 Elcvatccl rr'porthg tirnlt. Thc rcporting llnft ls clcvatcd duc to lrlgb analytc lcvcls.
STL Denver 35
I,ot-Sary>le #.--:
Date Saqlled. --=
PARAMETER
IIR,S Corporation
C1ient Sarqrle ID : GII-4UA-O90BO5
General Cherui-stry
D5f0901-76-005 llork Order *---: HJBM2
09/ 0Bl05 11 :00 Dat'e Received. - : a9/09/os
Hatrix-- ----i GW
PREPARATION. PREP
AhTALYS IS DATE BATCH #RESULT RL IJI{TTS METHOD
8-2 O-10 l{o Unite SW846 9O4OB O9|O9/O5 5252536
Dilution Pactor: 1 Analyais TIme--: 15:54
5.9 O-10 I',Ig/t rrtcAHrr 350.1 Ogl2v-Ag/z]-l0s s26s473
Dilut.ion Faetor r 1 analysis Time. . r 03 ;00
lrooo J,Q 250 vqlt r.rcArrw 325.2 O9h8/O5 5263255
pllurlon Factor; 100 analysis Time.,: 17:00
1.1 .' O-1O lflglt I,ICAIIW 340-2 O9/L4/O5 52s757s
Dilution FacEor: L Analysie fimc.., 13.15
0-059 B 0-10 ,rglt, lreawr 353-2 og/og/os 5265586
Dilution Factor! 1 Analyols Tlne.., t5r00
o-o?5 B 0-1o us/r ucArfw 3s3-2 oe/2o-a9/2Llos s26sss2
Dilutlon Factor: 1 Analyeie Time. , r 02 ,00
880 B,J,Q 1000 wlt l{cal{ll 375-L o9128/o5 s272r12- oil-ution Factor! 2oO Analyslo tlme..; 15r4o
l'rD 0 - 010 mg/t sw846 9oLoB/9OL2A a9/27-09/22/05 5254539
Dilution Factor; 1 Analyolo Time..: 12:00
pH
Aurnonia aa I[
Chloride
F]-uoride
HiErate
Nitrate-NitriLe
Su].fat,e
Tota1 Cyanide
NOTE (S)
=
RL Rcportlng Lhult
J Method htank contarnination- The associaterl methtxl blank contafuis thc mrgcr artalye il a repornble leve}.
a Elevarcd rcpo,IinS limtt. Thc reporting hnrit i.s elevated due to high urarlyrc levtls.
tl F.stlnratal result. Rcsult l.s less than RI--
STL Denver 36
Iot-Sanqrle *... !
Date Salqll_ed---:
PAIU\METER
IIR^S Corporation
Client Sanp1e ID: GW-S4-090805
General Chemistry
D5f0901,76-006 Work Order #,,.3 HJ8I.15
09/08/05 l"L:50 Date Received--3 a9/09/05
RESULT RL T]NITS IVIETHOD
Irlatrix-- -...r GW
PREPARATION. PREP
ANALYSIS DATE BATCH #
pE
Arunonia a6 H
Chloride
Fluoride
Nitrate
Nitrate-ti[itrite
Sulfate
Total Cyanide
NOTE (S) :
7 -8 0 .10 No ulrits sll846 90408
pilut,ion Factor; 1 Anal},eie Time. . : L5:55
9 -2 0 O .50 vrg/L ITICAI{H 350.1
Dllutlon Factor: s Analysle Time. . : 03 :00
6700 J, Q 25O lfirrg/L UCAWW 325 -2
Dilution Factor: I00 Analyels Tlme. - : 17:00
a .74 J O - 10 vrg/L DICAWH 34A -2
Dllution FacEor: 1 Analyols Tirne..: 13:15
0 - 19 O - 10 ntg/L UCAIiIH 353 -2' Diluiion Factor: 1 Analyels Time. . : 16:00
o.2o o .l-o w/L MCAwyr 353 .2
oilution Factor: 1 nnalysis Tirne. . : 02;00
17OO J, Q 25O wgll, I{CAHH 375 .4
Dilution Fact,or; 50 Analyais Tirne..: 15:40
ND o .010 mg/L SW845 e0108/ 9012A' Dilutlon Factor: L Analysie Time..: 12:00
oe/oe/as
oe/20- 0 e/21/ os
ae /L8l os
oe lL4/ as
oe / oe/ os
5252536
5265473
5263255
5257s78
s255586
as / 20-o s llL/ os szsssrro
oe /2f3/ os 5272L72
09 / 21*Ae /22 I os 5264s39
R[, Reportlng Llmlt
a Hcvatcd rcponing llmit- Thc reponing linrit Ls elevated due to hlgh analym lcvcls.
I Method blank contaminatiun. 'l'he asstriatetl urethat blanlc conralns thc target analyte at a reptlrteble level.
STL Denver 37
plr
IIR^S Corpom.tion
Client Saqrle ID: @I-R4-O9O8O5
Geueral- Chemistry
Lot-Sanple *...: D5I090176-O07 tlork Order *.. - ' HJBM6 ltatrix- - -: G?f
Date sartlrled- - -z a9/08/o5 l2t4a Date Receiwed- -z a9/a9/05
PAI?JIMETER RESULT RL UNITS METHOD
PREPARATION_ PREP
A}IALYSIS DATE BATCH #
8-O O.1-O No Units s1r845 9O4OB O9lO9lO5 52525t5.
DlLutlon Factsor' L Arralyais Time..: 16:01
Amnonia as tr 7.9 O-1O IIIg,lI, UCAHW 350.1 OglzO-OglzL/Os s265473
pllutlon Factorr I Analysis Time,.: 03:00
chloride s1oo. J, Q zso w/t lterwrl 325 -2 o9/L8lo5 52632s5
pilution Faccor; 100 Analysie Tlne..: 17:00
Fluoride 1.1 J O-1O nfq,/L rrrcA$rl 340-2 A9/7-4/Os 525757A
DiluLlon Factor' 1 Analyais Time..: 13;15
rilirrare o.42 0.10 wll rircAlfr 353.2 AglOg/Os s26ss86
Dl}ution Factorr 1 Analyeia Time,,: 16:00
t[iErate-tilitrire o-43 0-1o wll u@nlf 353-2 o9/20-o9/2l/o5 5265552
oilution Factor: 1 Analysls Tirne..: 02100
su]-fate 3.7 B,J 5.0 E€,lt riCAIlIf 375-4 O9|2B/O5 52'12L72
Dilution Factorr 1, Analyaia Time,.: 15:40
toral cyanide ND 0-010 lrftg/L sr,{846 90t08/9oa2A o9/2L-O9/22/05 5264539
Dllutlon FasEorr 1 Analysie Time..: 12:00
NOIB (S)
=
RL Rcponlng Llmlt
J Methrxl blank contaminati()n. 'Ihe associated nr0od blank cosmlns he rarget analytc aI a rcporubh lcvel.
a Elcvand rcporting llmh. Thc rcportlng tlmlt is clcvated duc to high analyte levels.
13 t*tirrrattd rsrrutr. Result is less thatt RL.
STL Denver 3B
t,ot-saqlle #,..:
Date Sampled,.,l
PARAMETER
URS Corporatsion
C}.ient Sanryle ID : cn-R3 - O9O8O5
General Chenistry
llork Order *.--: HJBI,IT
Datse Received.., r 09 / 09 / A5
Rt UNTTS METHOD
tlatrix. . . -. . . , . i GW
PREPARATION- PREP
A}IALYSIS DATE BATCH #
D5I090t76 - 008
ae/oB/os 14:15
RESULT
pH
Amronia aB lI
Chloride
Fluoride
llitrate
Nitrate -Ilitrite
Sulfate
Total Cyanide
NCTIE (S) :
7-tJ
L40
3800
L-2 J
L-7
1-B
4s o:Q
TID
o.10 No unite sw846 90408 ae/ oe / os s2s2s36
Di lution Factor : 1 Arralysle Tlme. . : L6 : 04
ucAtNII 350 .1_
Analysis Time. . : 03 :00
}ICAIIH 325.2
I\nalyeig Time. . : 17 : 00
MCAI{W 34fJ.2
.unalyeie Time. . : 13 : 15
ITiCAIUW 353.2
.l\nalysis Time. . : 16 r 00
ttcAl{w 353 -2
Analyels Time..r 18:oo
trtcAlrl{ 375 -4
Analysis Time. . : 15'-(10
1-O ntg/L
Dl lut.ion Factor r 1 0
J, Q 25O rrfg,/L
25 v{J,lI-s272L72
09 / 20-o 9 /21, I OS s265473
nllutlon F'actor: l0O
o-1o rglL
Dilution FacEor: 1
o-1o rry,lL
Dllutlon Pactor: 1
o - 10 wg,/L
Di Iut ion Faet.or : 1
Dllutlon Factor: 5
0.01-0 mg/L
Dllution Faet,or: I
ae lLsl as
oe lL4/ as
oe/oe/as
oe /27 / as
ae/zls/os
5263255
s257 578
527L706
52715?90
sw846 90108/9012A A9/2L*A9/22/ Os s264s3e
Analyeie Tirne. . ; 1-2 :00
RL Rcportiug Limit
a Ehvarcd rcponlng llrnlt. Thc regrortlng llnrlt ls elevarcd due to hlgh analyte lcvels.
J Mcthod blank connmlnadon. Thc associatcd urcthod blank connins rhe target analyte at a reportahlc level.
STL Denver 39
QC IIATA ASSOCTATTON W
D5rO9017b
Sample PreparaEion and Analysie Control Nurnbers
SAIUPLE#MATRIX
001
002
003
004
WQ
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
Gl,I
GW
GW
AIilAtYTICAI,
METHOD
sw846 8250B
McAhrht 325 .2
IVICAWW 340.2
MCAWId 353.2
MCAfn^I 353 .2
s!{84 5 901 A]H-/ 9012A
s[{845 6020
sw845 74704
sw845 90408
SWB45 82608
sw846 60108
MCAWW 375.4
MCAWW 3s0.1
MCAWW 325.2
MCAWW 340 .2
MCAWW 353 .2
MCAWW 353.2
sw846 9o10B/9012A
sI1I846 5020
sw846 7470A
sw845 90408
sw846 82608
sw845 60108
MCAWW 375 .4
MCAWW 350. L
MCAWW 325.2
MCAWI{ 340 .2
MCAhn/[ 353 .2
MCAWW 353 .2
sw845 90108/9012A
sw845 6A20
sw846 7470A
sw845 90408
sw845 82608
SWB45 501OB
MCAI,II{ 375.4
MCAWW 350.1
(Continued on next
PREP
BATCH # MS RUN#
LEACH
BATCH #
5263544
s26 32 55
5257 57 B
s26ss52
s255586
5264539
s265193
5259437
5252536
5263544
526523-7
527 2]-7 2
5255473
5253255
5257578
526s5s2
5265586
5264539
5255193
5259437
5252535
5264409
526s237
527 21-7 2
527L454
5263255
5257 57 8
5265 s5 2
5255585
s264s39
5265193
s259437
5252s35
s2644 0 9
s255237
5272L72
s255473
5263367
5253L59
5258757
s26s 3 44
5264340
5265t29
5262LA7
5255 14 0
s263357
5265155
527 21_ 0 3
5255288
5263159
52581s7
5265344
5264340
5265L29
s262L07
5255 L4 0
s264292
5265155
5272103
5271305
5263 16 9
52581 57
5265344
5264340
52651,29
5262147
5255140
s264292
526515 5
5272t03
5265288
STL Denver
page)
40
acDATAASSffiONW
D5rO90176
Sample Preparation and Analysis ConLroI
SAMPLE#MATRIX
005 GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
Gnt"
GW
GW
GW
GW
GW
GW
GW
007
008 GW
GW
GW
GW
006
AI{AIJYTICAL
METHOD
MCAWW 325.2
MCAWW 340.2
MCAWW 353 -2
MCAWW 353 .2
sw845 s01aB/ 9012A
sw846 5020
sw845 74744
sw845 90408
SWB4 5 8260lH-
sw846 601_08
MCAWW 375 -4
IvICAWW 35O - 1
MCAWI^I 325 .2
MCAWW 340.2
MCAWW 3s3.2
MCAWW 353.2
swB45 901 OBI 9012A
sw846 6020
sw845 7470A
sw845 90408
sw845 8250B
sw846 601_08
I{C.AWW 375.4
MCAWW 350.1
MCAWW 325,2
MCAI^II^I 340.2
PICAI,'II^I 353.2
MCAI^il^I 353 .2
swB{6 90108/ 90r.2A
sw845 5020
sw846 74'7AA
slv8{5 90408
sw845 82608
sw846 60108
I{CAWI^i 37 5 .4
MCAhTW 350 . L
IyICAWW 325 .2
MCAI,fi^I 340 .2
MCAWW 3s3 .2
MCAWW 353 .2
(Cont.inued on next
LEACH
BATCH #
Numbers
PREP
BATCH #
5263255
5257 57 I
5265552
5255586
5254539
5255l_ 93
5 25 9437
5252s36
s26440 9
5?,55237
5272L7 2
s25547 3
5263255
5257 57 I
s25ss52
s26ss86
s264 53 9
5265 r93
5259437
5252536
5254449
s265237
5272L7 2
526547 3
5253255
s257 57 B
5265552
52655 86
s264 s3 9
526519 3
5259437
5252536
5264409
s26s237
5272L72
s26s473
s2632s5
5257 57 8
s271679
527L746
MS RUN#
5263L69
52sB 15 7
s265344
5264340
s26s]-29
5262L47
525s14 0
5264292
s2651s5
s272103
526s288
525315 9
5258l_ 5 7
52653+4
5264 34 0
s265]-29
5262 r.0 7
5255 14 0
5264292
5265155
527 2 t-0 3
52652 88
5253 r_5 9
525 815 7
526s 344
5264344
5255L29
5252LA7
525514 0
s264292
s2651s5
5272103
52652 I I
5253 15 9
52sBl"s7
527 L432
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
GW
STL Denver
page )
4a
0c DATA ASSOCTATTON SLJMMARY
D5r0 90L7 6
Sample Preparation and Arralysis Control Numbers
SAMPTE#MATRIX
008
AI\TALYTTCAI.,
METHOD
sw846 9ol-aB/eo12A
sw845 5020
sw845 7474A
sw845 9040B
sw846 82508
sw84 6 5 0108
MCAWW 375 -4
MCAWW 350.1
GW
GW
GW
GW
GW
GW
GW
GW
LEACH
BATCH #
PREP
BATCH #
s254s39
525 519 3
52s9437
52525 3 6
5254409
525s237
527 2L7 2
526547 3
I'4S RUhI#
526434A
526sl.z9
s262L07
5255140
5264292
s26s155
527 2L03
5265288
STL Denver 42
C1ient Lot *- - -:
MB Lot-Samp1e #:
Arealysis Date- -:
Dilution Factor:
PAIU\METER
D5r0901,76
D5I2AA000-544
ae/20/as
t_
UHTEOD BLANK REFORT
cC/I{,S Vo1ati}eo
Itork Order *- - -: HK1PL1AA
Prep Date o . .],, : 09/L9/05
Prep Batch #- - -: 5253544
MatriJE. , , - - - . - - r WATER
analyeig Tirne. . 3 00 : 16
METHODRESUIJT
REPORTING
I,IMIT UNITS
Chloroform
SURROGATE
D i. b romo f I uorome thane
I , 2 - Di chloroethane - d4
4 -Bromofluorobenzene
Toluene -dB
NorE (s) :
ND
PERCENT
RECOVERY
103
118
115
103
1-.0 ug/L
RECOVERY
LIMITS
(73 1l-8)
(az 128 )
0 a 118)
(77 1L7)
sw845 82508
Calculations arc ylerforrned before rounding to avoid round-off Errors in calculaterl rcsull"s,
STL Denver 43
C1ient Lot #- - -: D5f090L76
It{B I.ot-Sarq>Ie *: D5fZLA000-409
Analysis Date- - : a9 / 2A / a5
Dilution Factor: t
PAIU${ETBR
Chloroform
SURROGATE
Dibromof luoromethane
7, 2-Dichloroethane - d4
4 -Bromofluorobenzene
Toluene-dB
NOTB (S) :
METHOD BI,AI{K REPORT
GC/I{,S volatiles
Work Order #---. HK27W1AI\
PrepDate :09/20/05
Prep Batch. #---: 52644A9
REPORTING
RESUIJT IJTMIT UNITS
tlatrix- . .. . . . , - r WATER
Analysie Time. . i 11 :48
METHOD
ND
PBRCENT
RECOVERY
101
1"03
B9
L06
1 .0 :ug/L
RECOVERY
LIMITS
(tt l_18)
(az 128)
(78 118)
(tt l-17 )
SWB45 825OB
Calculatlons are perforrncd bclbre roundlng ,o 31,old round-otT errors in calculated rcsult-s.
STL Denver 44
I,ABORATORY COI TROL SAMPI,B EITALTIATTOII RBPORT
eclfis Vo1ar.iles
C1ient Lot *- - - = D5I090L75 Dlork Order *- -
I,CS Lot-SaryIe* : D5I20000 A -544
Prep Date : 09/L9/O5 Analysig Date.
Prep Batch #---: 5253544 Anal.ygis Tirre.
Dilution Factor: 1
HK]"PL].AC- LCS Matrix. -
HK]-PL1AD-LCSD
oe/te/os
23 :36
: WATER
PAIU\METER
PERCENT
RECOVERY
99
97
91,
94
93
95
LO2
104
92
94
RECOVERY
LIIVIITS RPD
PERCENT
RECOVERY
RPD
LTMTTS METHOD
1, l-Diehloroethene
Benzene
Ch[orobenzerae
Toluene
Trichloroethene
SURROGATE
(es L32l
(se L32) 1,8 (O-25),
(zs Lzol
(7s LzO' 2-e (O-zll
0e 118)
(za 1r_81 2.L (0-2Al
(za 118)
( ze 118) 1 - 4 (O -221
17 g L22l
(z g I'22) 1 .1 (O- 23',/,
sw846
s:r{846
slr846
sw846
STT846
sH846
sr{845
srr846
sr[846
sr[845
82608
82608
82508
B26OB
825OB
82508
82508
82608
826OB
82508
Di brorno f luorome t hane
1, 2- Dichloroethane - d4
4 -Bromofluorobenzene
Toluene - dB
NOTE (S) ;
1-00
LO2
LL2
115
L1_2
112
LA2
]-02
RECOVERY
LIMITS
(73 118)
(zg 118)
(52 128)
(az 128)
(ze 1lB)
(78 118)
(tz 1L7 )
(tt 1-17)
Catcularions are pcrlbrnrcrl bctorc rorrncllng ro avold round-off crror.s ln calculated resuks-
Bold print denotes control paranreters
STL Denver
I,ABORATORY COI{ITROL $tr[P1,E DATA RBBORT
ccluS Volatilee
Clieut I.ot #-.-: D5I090175 llork Order *.-.r HKLPLIAC-IrCS ttlatrix- --: WATER
I,CS Lot-Saryr1e*: D5I2000O0-544 HK1PL1AD-tCSD
Prep Date .- og/Lg/os Analyoia Date- -= a9/79/05
ep Batch *...: 5263544 Aaalysie rime. -: 23:36
Dilution Factor: 1
SPIKE
AMOUNT
10. o 9. 88
10.o 9.74
10-o 9.r_1
10. o g.3B
10.o 9-30
I0-0 9-50
10-o aa-2
10-o 10_4
10. o 9 .25
10 . o 9,35
IvIEASURED
AMOUNT UNTTS
PERCENT
RECOVERY RPD METHODPARAMETER
1, I-Dichloroethene
Benzene
Chlorobenzene
Toluene
Trichloroethene
SURROGATE
Dibromof luoromethane
L ,2 -DichloroeEhane -d4
4 -Bromofluorobenzene
Toluene -dB
NOTB (S)
=
]u.g/L
Iug/L
lug/n
ug/L
ug/L
ru.g/L
U,g/L
l.trglI-
ug/l'
rug/f'
PERCENT
RECOVERY
99
97
91-
94
93
95
LA2
104
92
94
RECOVERY
LTMII1 , .(73 118)
(tz 118)(ez 128)
(62 1-2I )
0e 118)
(78 118)
(77 r.17)
(tt 117)
srg846 82608
sw845 82608
sH846 82608
s-n846 82508
sI{846 82508
srr845 82508
sw846 82508
sTr846 82508
STTB45 B25OB
sw846 82608
t _8
2-9
2-L
t_4
1_1
1-00
LA2
1_42
L l_5
:JL2
aL2
LO2
LO2
C.alculatirtns are pertbrnrctl hetbre rounding to evoid round-olf crrors ln calcularcd rcsulrs.
Bold print denotes control pararnccrrs
STL Denver 46
W GC}f;TROIJ SAMPIJE SVALUATTOH RBPORT
GCII{S vo}atiles
Client Lot #- - -:
LCS lot-Saugrle#;
hep Date.-----:
frep Batch #..,:
Dilution Factor:
PAII'\IUETER
D5r090L7b
D51210000-409
as/2a/as
5254409
t_
Work Order *,.
enalysis Date-
Analysis Time-
HK27W1AC-LCS Matrix-- ----: WATER
HK2 7W1AD-LCSD
oe/2a/05
Ll- :07
1, ]--Dichloroethene
Beneene
Ch.Iorobenzene
Tolrrene
Trichloroethene
SIIRROGATE
PERCENT
RECOVERY
7A
70
96
96
97
94
r.04
1_O8
89
91
RECOVERY
LIMITS
(ee 132)
(ee 132)
(ts t 20)
(ts tzall
(z s 118)
(zs 118)
(ts 118)
(ta 118)
(z g L22l
lzg L22\
PERCENT
BECOVERY
98
97
96
98
93
93
1- 07
114
RPD
RPD LTMITS
L -4 (o- 261
0.15 (0-2r_)
2 .6 (O-ZO)
3.9 (0-221
2.2 (O-23)
RECOVERY
LIMITS
(73 118)
(73 118)
(62 128)
(62 128)
(78 lL8)
(ta 118)(tt 1r. r )
(l t LL7't
I,IETI{OD
sr{846 82608
s'F846 82608
sn846 82508
sr{846 82608
sr{846 82608
sw846 82608
sr[846 82508
sw846 82608
SWB46 B25OB
sr{846 82508
Dibromof luoromeLhane
A, 2-Dichloroethane - d+
4 -Bromofluorobenzene
Toluene - dg
NOTE (S} :
Calculadorrs arc prrt'ormetl bcfure rounding ro avoid rourxl-off errors in calculatul results.
t|,otd print rlelrotcs control p:u:unetcrs
STL Denver 47
DsI090L7 6
DSr2LA000-409
ael20/a5
52644A 9
L
LABORATORY COIITROt SAT-IPI,B DATA RBPORT
cc/t{,s volatileg
Irlork Order *- - - =
Analysis Date.. i
Analysis Time. -:
HK27WlAC-LCS Dlatrix.. . ., . ., - . 3
HKz 7W]"AD - LCSD
oe/2al0s
1l-:07
WATERClient lot ff. . . :
LCS l0t'*Sanqrle# =hep Date ---:
fre1> Batsctr *, - , 1
Dilution Factor:
PAIUIMETER UNTTS }4ETHOD
1, l-Dichloroethene
Benzene
Ctr-lorobenzerre
To]-uerre
Trichloroethene
SURROGATE
Dibromof luoromethane
L, 2- DichloroeLhane - d4
4 -Bromofluorobenzene
Toluene - dB
NOTE (S)
=
SPIKE
AIVIOT}NT
10-o 7.05
10 . o 6.95
l_o-o 9-61
10-0 9-50
10-0 9-69
10_o 9-44
10. o 10 -4
10. o 10,8
10. o 8 -92
10.o 9-11
IVIEASURED
AMOIINT
ug/r
lug/L
!u'g/L
wg,/L
rug/I'
rug/T'
wg/L
ug/L
Iu.g/L
t:.g/L
PERCE}IIT
RECOVERY
PERCENT
RECO\IERY RPD
7A
70
96
e6
97
94
104
108
B9
9L
RECOVERY
LIMITS
(tt LL8)
(7t 1L8)
(52 128)
(62 128)
(ze 118)
(ze 118)
177 LL7)
(77 r17)
sw846 82508
sr{846 82608
sI{846 82508
sH845 82608
sw846 82508
sw846 82608
s:w846 82608
sw846 82608
sw846 82608
srr846 82508
L,4
o-15
2-6
3-9
2_2
98
97
96
98
93
93
107
1,1_ 4
Calculadors are perforn:ed beforc ruurrtlil4i m avoid round-oft err$r$ ln calculated resultti.
Bold print rlenotes control para$tetcrs
STL Denver 48
}NTRTX SPTKE SAIITPT,E EI'ALUATION RBPORT
GC/}IS Vo]-atilee
C1ient Iot #- - -:
HS t,ot-sanpJ-e #:
Date Sanqrl-ed---:
Prep Datg., t. .. i
Prep Batch *- - -:
Dilution Factor;
PAIU\METER
Dsr090L7b
D5rL40356-01-0
oe/L4/0s 15:30
ae/Le/os
52635+4
50
Ilork Order f,- - -:
Date Received- -:
AnaJ.ysig Date..3
gnalysie Time-. l
HIL77C1AC - MS
HK.]?ClAD-MSD
oe/L4/05
ae/2a/as
01-:38
RPD
RPD I,IMITS
Matrix-- ----: WATER
METHOD
1, I.-Dich].oroethene
Benzene
Chlorobenzerle
Toluene
Trichloroethene
SURROGATE
105
105
94
93
100
98
113
l]-'z
108
79
PERCENT
RECOVERY
RECOVERY
LIMTTS
(os L32l
(66 132)
(zs 120)
(ts r-20)(zs 118)
(zs 118)
(78 118 )
fie 118)
(tg L22Il
(tg L22l
PERCENT
RECOVERY
98
98
111_
LL2
1-09
1_08
105
103
o - 71 (o- 261
0 - 81 (O- zi.l
1 .5 (O-20)
o -42 (o-221
9 -2 (O-231
sr{845 82508
sw846 82508
sw846 82608
sr{846 82508
sw846 82608
sH845 82608
sr{846 82608
sw845 82508
sw845 82608
sw846 82508
Dibromofluoromethane
L ,2 -Dichloroethane - d4
4 -Bromofluorobenzene
Toluene-dB
I{IOIE (S)
=
RECOVERY
LIMITS
(73 L18)
(73 118)
(az 128)
(62 128)
( 78 l_l_8 )
(78 118)
(tt 117 )
(7t LL7)
Calculntions erc perfirrrned bcfore rouruling to uvoitl rountl-otf crrors in calculatcd rcsults.
ttold prtnt denorcs control poranlcters
STL Denver 49
}{ATRIX SPIKE SAIIIPITE DAIA REPORT
GC/H.s volatileg
Cl.ient Lot *- - -:
MS lot-Sampl-e *:
Date Saryrled,--:
Prep Date -. -:
Prep Batch #- -. =Dilution Factor:
PAIT,\METER
D5r0901?b
DsI140365-010
as/L4/05 15:30
oe/Le/os
5263544
s0
I{ork Order *- - -:
Date Received,.:
Analysis Date. .7
Anal.ygis Time.. !
HK.}7CIAC -MS
HKJTC1AD-MSD
ae/14las
ae/2alos
01:38
I{atrLx-WATER
SAMPLE SPIKE
AMOUNT AIV1T
MEASRD
AMOUNT UNTTS
PERCNT
RECVIRY RPD METHOD
1, l-Dictrloroethene
Benzene
Chlorobenzene
Toluene
I?ich.loroeth,ene
SURROGATE
Dibromof luoromeEhane
A, Z-Dichloroethane - d4
4 -Bromofluorobenzene
Toluene -dB
NO:TE (S} :
ND 5OO
ND 5OO
HD 5OO
r{D 500r[D soo
lrD 500
IirD 500
ND 5OO
1100 soo
1100 500
527
523
469
465
500
492
563
560
16BO
1530
PERCENT
RECOVERY
9B
98
111_
1]_2
l_09
108
10s
103
]u,g/L
1us/L
Iu.glL
rug/T,
ug/t
'uiglLug/L
rug/r'
rug,/r'
us/L
105
105
94
93
100
98
11"3
L7,2
I_08
79
RECOVERY
L.IMITS
(73 118 )
( zr l-18 )(sz a?Bl
Gz L28)
(7e 118 )(78 1"1-8)
(tt 117 )
(77 117)
sw845 82608
o.7L 5W846 82608
sll846 82508
o.81 Sn845 82608
slr846 82508
1- 5 Srr845 82608
svl846 82608
o.42 511846 82608
sII846 82608
9 .2 5r[846 82608
Calurlations are performed bcforc roundlug to al'oitl rrruntl-ulT err()rs in calcularcd rcsults.
Bold print denocs control parffrrcrcrs
STL Denver 50
}IATRIX SPIICE SA}'IPI,E B\IALTIATTON REPORT
cc/us Vo]-atiles
Client Iot #- - - :
!,IS I.ot-Sarple #:
Date Saryrled- - -:
Prep Date ---3
Prep Batch *- - -:
Di].ution FacEor:
D5r090L76
D5r090t75-003
a9 / oB/os o9 :25
oe/2a/os
52644 0 9
1_
Ilork Order *- - -:
Date Received- - :
Arralysis flate. . 3
Analysig Time- -:
IIJBI,ff1A9 -MS
HJEMV1CA-I,ISD
os/ae/os
oe/20/as
L2 :52
Matrix.-...--..! GW
1, I-Dichloroethene
Benzene
Chlorobenzene
Toluene
Trichloroettrene
SURROGATtr
Dibromof luoromethane
L ,2 -Dichloroethane -d4
4 -Bromofluorobenzene
Toluene - dB
NCITE (S) :
53a
58a
104
96
94
94
101
100
91
B4
PERCENT
RECO\ERY
RECOVERY
LIMTTS
(55 - 132)
(65 L32'/,
(7s 12o )
(75 120 )
(zs 118)
(z e l,rg )
(78 r_r_B)
(7s 118)
(tg a22l
(7 e L22l
PERCENT
RECOVERY
1-05
L00
LO7
L07
85
90
98
t0s
RPD
RPD LIMTTS METHOD
sn845 82508
7 -5 (0-261 S11846 82508
5TT846 B25OB
8-0 (o-?L) SWB45 82608
srr846 82508
o.47 (o-2ol sw845 82508
slr846 82508
o . 58 ( O- Z2l 5I{846 82608
sr{846 82508
7 -7 (O-231 SWB45 82508
RECOVERY
LTMTTS
(73 118)
(73 lt"B)
(az LzB)(62 i-28)
( za 118)
0e 118 )
(77 117)
(77 LL7)
Calculations arc pcrlbrmcd bcforc roundilrg to avold round-off crrors in calculatcd rcsults.
Bold print denotes control parameteru
a Spikul auutlyte recover)-. is outside stated control limits-
STL Denver 51
C1ient l,ot *. . , ;
IrtS lot-Sanple #:
Dafe Sarq>Ied---:
Prep Date ---:
Prep Batch *- - -:
Dilution Factor:
PARAMETER
D5I090L76
Dsr090L76-003
ag / oB/os a9 =25oe/20/os
5264449
1
I{AT?TX SPIKB SA}-IPI,E DATA
Gc/u.S Volatiles
hlork Order #. . , l
Date Receiwed- - :
analysig Date- -:
Arral.yeis Time- - 3
REPORT
HJSIVT\11.A9 _MS
HJ8}vn/1CA-MSD
0e/0e/os
oe/20/os
12.q,2LU.JP
Matrix-- ----: GW
SAMPLE SPIKE
AMOUNT AMT
MEASRD
AMOUMT UNITS
PERCNT
REC\IRY
6 - 31 l'Jtglt
5 ,84 lug/T,
L0 .4 tug/L
9 - sG rug/L
e - 36 wg/L
9 - 41 wg/L
l-O .l, lug/L
9. 98 ug/T'
9 -LZ rug/l'
8 - 44 wg/L
PERCENT
RECofr.EBX
105
100
107
1-07
B6
90
9B
105
RPD METHOD
SWB45 B25OB
7 -6 Slr845 82508
sw845 82608
8_O 5I{846 82608
SWB46 82608
o .47 SI{845 82508
sn846 82508
o.68 SWB45 82508
sw846 82508
7 -7 Sr{845 82608
1, l-Dichloroethene
Benzene
Ch,lorobenzerre
Toluene
Trichloroetherre
SURROGATE
ND
ND
![D
ND
ND
ND
ND
![D
ND
ND
10 .0
10-0
10 .0
10-o
10_o
10-o
10 .0
10.0
10. o
10_o
53a
58a
L04
95
94
94
101
100
9l-
84
RECOVERY
LTMITS
Dibromof luoromethane
L, 2-Dichloroethane - d4
4 -Bromofluorobenzene
Toluene - d8
rrolE (s) :
(73 118)
(zg 118)
(02 128)(sz r28)(ze rl8)
0a 118)
(tt 117)
(77 l_17 )
(lalculations are performed before roundlrrg to avoid rounrJ-ol'f crrors ln calculatcd rcsults.
Bold prlnt dcnorcs conrrol parametcrs
a Spikc<l anal-vtc recovery is outsitle stated control limits.
STL Denver 52
!-IHITIOD BLANK REPORT
TOTAL MetaTe
C}ient Lot #.
PARAMETER
: D5f09A776
RESULT
REPORTING
LIMTT UNITS I,IETIIOD
Matrif(. . . o o , . . . i WATER,
PREPARATTON- WORK
AI{AIYSIS DATE ORDER #
IIIB lot-Sarqr1e #: DSI150000-437 Prep Batch *---: 5259437
Mercury ND 0.00020 ,rr,/r, Sw846 7470a,
Pilution Factori f
AnalyolE Time.. : LB!05
! 5265193
sw84 5 6A20
sw846 602A
: 5265237
sw846 5010B
sw846 501-08
0e/23/os HKVPAlAA
a9 / 23 -a9 / 27 / os HK5F2 lAD
oe /23-09 /27 / 05 HKSF2lAM
ae /23-oe /26 / os HKsMArc
Ir{B lot-Sample
CaCmium
#= D5f 220000-l-93 Prep Batch #.-
ND 0.0010 'llrg/L
Di lution Factor : 1
Analyoio Tirne., : L9 :44
}[D 0.0020 rl;rg/f
Di ]uLion Pactor: 1
Analyeie Tirne ., : 19 -.44
Sel-enium
I{B Lot-S;rrE>Ie *: D5f 22O0O0 -237 Prep Batch # -
Aluminum IUD O .10 mg/L
Arsenlc
DiluEion Factor: 1
Analysla Tl,me., : 20 : 58
0.015 mg/L
Dl lutlon Fa ctor : l-
Arralysig Tirne. . : 07 : 59
0.010 mg/L
Di lution F'actor: 1
Analireia Time.. ' 07r59
o -20 r;rg/L
Dilutlon FacEor: I
Analysls Tl,rne. . ; 20 :58
0 - 010 mg/L
Dllution Factor: 1
Analysis Tirne. - : 07 r59
0.010 .r;rg/L
Dilution Factor: t
Rnal1,als Tinne. . : 07 :59
0.10 mg/t
Dllution F'actcr: L
Analyeis Time..: 20:58
Barium
Calcium
Chromium
Copper
Iron
sw846 50108 oe 123-ae /28 / as HKSMA1CH
sw845 501-08 ae 1 23 -oe / 28 / os HKSMA] cJ
sw84 6 5 0108 ae /23-0e/26 / as HKSMAIAE
sw84 6 5 0108 oe / 23 - oe / 28 / os HKSMA1CK
sv[845 6010B 09 / 23 -0e / 28 / A5 HKSMA1CL
ND
}UD
ItD
ND
ItD
STL Denver
ND
(Continued on next page)
ae / 23 -oe / 26 / as HKsr,lArL
I{EIIIOD BI,A}IK REFORT
]rO(fAI, Meta].e
Client Lot #-
PARAMETER
: D5I090175
RESULT
REPORTING
LIMIT UNITS METHOD
Matrix-- ...-3 WATER
PREPARATION. WORK
A}{ALYSIS DATE ORDER #
Lead
Magnesium
Ni cke I
PotaBSium
Si lver
Sodium
Vanadium
Z inc
Zircanium
HOTE (S) :
I{D 0.0030 mg/L
Di lut, ion FaeEor : l-
Analysls Tlme. , : 07 259
0 .20 mg/L
Dilution Factor; 1
nr:alyeie Time. . : 20 : 58
0.040 r:.g/t
Di lution FacEor : 1
irnalysis Tirne. . : 07 : 59
3 .0 mg/L
Pi-Iution Factor: 1
Analirels Time. ., 20 r 58
0.010 mg/L
Di lution Factor : 1
Arral-yeie Tirne . . : 07 :59
5.0 mg/L
Oiluti.on Fact-or r I
Arralyeia Tirne - . : 20 : 58
0.0L0 mg/L
Di lution Factor : 1
Arralysis Time. . : 07 : 59
0-020 mg/L
Dllut. Lon Factor : 1
AnaLysis Time..; 07:59
0 . 015 nrrg/L
Dl lut i. on Faet or : 1
Analysis Tirne. . ; 20 : 58
sw84 6 5 0108 ae / 23 - ae / zB / as HKsIvrArcN
sw846 50108 ae / 23 -a9 /26 / os HK5MA1AL
sw845 60108 oe / 23 -ae / 2U^/ as HKSMA1CM
sw84 6 5 0108 ae / 23 -oe /26 / as HKSMAIAK
sw845 60108 ae / 23 -ae /28 I as HKSMA1CP
sw846 50108 a9 / 23 -A9 /25 / A5 HKSMA1AN
sw845 60108 ae / 23 - ae / zB / as HKSMAIcP
sw84 5 5 010B oe I 23-oe /28 / as HKSMA1CQ
sw845 50108 09 / 23 -A9 / 26 / A5 HKSM.AICR
Calculailorls are pcrlorruutl bofurc rountling to avoid round-off errors in calculated results,
STL Denver 54
I,ABORAIIORY COIilIROIT SA,HPLB EIIALIIATfON REPORT
TOTAT DIetaIs
C]-ient Iot * -
PARAMETER
Iron
PoEas sium
Magnesium
Sodium
Si lver
Aluminum
Arsenic
Barium
: D5I0 9 017 5
PERCEhIT RECOVERY
RECOVERY LIMTTS
94
100
9s
97
r-02
96
99
99
METHOD
Flatrix-- ----3 WA
PREPARATTON-
A}IAIJYSIS DATE WORK ORDER
LCS Lot.-Sanple#: D5I16000A-437 Prep Batch *,,.3 5259437
Mercury 1,00 (gS 114) Sw845 747AA
Dllutlon FacEor: 1 Analyoia
LCS I^ot.-Sary>Ie*: D5T220000-193 Prep Batch *..-= 5265193
Cadmium 97 (sg 1-10) SWB46 5020
Anal)'s i s
6A2A
Analyei s
.. i 5265237
50L08
enalye i s
5 0108
Arralysl o
5 0108
Analyai s
50108
Analyo I s
6 0108
Analysi e
6 0108
Analysi e
60108
Analysl s
5 0l-08
Analysi e
6010E}
Ana lyo i e
next page)
oe/n/as
Tirne..: 18:08
ae/23-oe/27/as
Time. . : 19:48
ae/23-oe/27/as
TLme, - , 19:48
oe/23-ae/26/0s
Tlrne. . : 2I:02
oe/23-ae/251a5
Tlme.. : 2L202
oe/23-oe/25/os
Time..: 21,:02
a9/23-0e/26/os
Time. . : 27t02
ae/23-oe/26/os
Time-.: 21202
ae/23-oe/28/as
Time..: 08:03
ae/23-oe/26/os
Tlme. - : 27,202
ae/23-ae/28/05
Time..: 08:03
0e/23-oe/28/05
Tirne,.: 08;03
H}T/PA1AC
HK5F21AJ
HKs F21.AI{
HK5MAl.AO
HKSMA1.A4
HK5MA1A5
HKsMA1A6
HKsI"IAl-AB
HK5MAlCT
IIK5MA]-CU
HKSMA1CV
HK5MA].CW
Selenium B9
Di lut,lon FacEor : 1
(az LLz) SW846
Dilution Factor: 1
LCS l,otr-Sanp1e*: D5L22000 O -237 Prrep Batch *.
Calcium 92 ( 89 1l- 0 ) sW846
Di lut ion Fact.or , L
(aa 110) sw845
Dilution Factor: I
(a0 111) SWB45
Dilution Factor: 1
(gr l-l-L) sw846
Dilut ion Factor: 1
(91 LLz ) SWB46
Di lution Fact.or : 1
( 8s l-L4 ) SwB46
Dllution FacEor: 1
( 86 to8 ) Sws46
Dilutron Factor: 1
( sg 109) sw845
Dilutlon Faetor: 1
(gr l-13) sw845
Di lutlon FacEor r 1
(Continued on
STL Denver
I,ABORAIIORY COHTROL SN{PI,E HTALUATION REPORT
IOTAL ltlet,a]-s
C]-ient Iot * -
PARAIyIETER .
Chromium
Copper
NickeI
Lead
Vanadium
Zinc
Zirconium
NOTB (S) :
DSr0901,7a
PERCENT
BE.coJ/ERY
9B
100
96
97
99
92
101
RECOVERY
LIMTTS METHOD
( B9 Ltz) SWB46
oilution FasEor; 1
(ee 1r-o) sw846
Dilutr.or, Factor: 1
(go 1r-0) sw845
Dilution Factor: 1
( 91 111 ) Sw846
Di l-ut ion Factor : 1
( 8B 1L2) SWg46
Dilution Factor r I
( 8s 110 ) SWB45
Dilution Factor: 1
(7 5 L25 ) SWB4 5
Dilution Factor: I
60108
5 010E}
Arral1,ei s
6 0108
Analyei s
5 0108
Analyoie
5 0108
Analyei a
5 01_ 08
Analyei g
60108
Mat'rix- - - . . . . . . r WATER
PREPARATTON-
A}IALYSTS DATE WORK ORDER #
a9 / 23 - 09 / 28/ as HKsMA].cx
Anal)'sis Time. . : 08 ; 03
oe / zi -oe / zB / as HKsrvrAleo
Tirne, . : 08:03
a9 / 23 -A9 l zS / 0s HK5D,{A1C1
Time..:08:03
09 / 23 - 09 l28 / As HK5I,rA1C2
Tirne.,: 0B:03
09 / 23 *Ae 128 / 0s HKsrvrAlC3
Time.. r 08:03
09 123 - Ae / 28 / Os HKsrvrAlC4
'firne.,: 08:03
as /23-oe / zG/ as HKsMAlcs
f-alcuiatiors are perforrnrtl hefore rountling to avoid round-off errors in calculated rcsults.
STL Denver 55
LABORATORY COITTROI, $!,ltp6 DATA REBORT
IIO(IAL Hetals
Clierrt Iot *. -.: D5I090L76
SPIKE MEASI]RED
PAITJ\METER AII,IOUNT AIUOUNT TJ}TITS
PERCNT
RECVRY MET}IOD
Matrix-- ----: WATER
PREPANATION- WORK
AT$ALYSIS DATE ORDER #
LCS lrclt-Saryrle# : D5IL5000 A -431 Prep Batch # -
Mercury 0.00500 0.00502 mg/L 100
Pi lution Factor ; I
LCS Iot*Sanrqr1e* : D5T220000 - L93 Prep Batch * -
Cadmium
Selenium
0-0400 0-0388 mg/T,97
oilution Factor: 1
LCS Ipt-Sanple#: D5122000 A -237 Prep
Calcium 50 - O 46 -Z . rfig/L
Batch #.
Iron l-.00 0.938
Dilution Factor:
ng/L
Pllution Pactor:
mg/L
Dilut.lon Factor:
mg/r'
DiluEion Factor r
mg/r,
nllution Factor:
mg/L
Dilution Factor:
mg/L
Dilut iorr Factor:
mg/L
Ullutlon FacEor:
r..|,g/L
Dl }utlon Factor ,
50. 0
Potassirrm 50 , 0
Magnesium 50.0
Sodl-um
Silver
Aluminurn
Arsenic
Barium
50.1-
47 .3
48 ,5
0 .0500 0 .0509
2 .40 1,91
2.00 L.99
2 .00 1. gB
:5259437
sw845 747 AH
Arralysi o Tlrne .
: 5265193
sw845 5020
Analyel e Time ,
sw845 6A2A
Analyoi s Time.
z 5265237
sw845 501_08
iLnalysis Time.
sI1I845 601-08
Analye1o rJ,rne .
sw84 5 5 0108
Arralysl e Tlme ,
sw84 5 5 0108
Analyele Tlme.
sw846 60108
Analyels Tfune.
sw84 5 5 0108
Analysi s Tirne .
SWB45 5O1OB
Analysi s Time.
swB46 60108
Arralyel s Time .
s[{84 5 6 0108
Analysie Time.
oeln/as
: 18:08
a9 / 23 -ae /27 / os
I9:48
ae/23-a9/27/os
19;48
as/23-ae/26/os
27|02
os/23-oe/25/as
2LtO2
ae/23-ae/26/os
2L |02
oe/23-oe/26/as
2), : O2
oe/23-09/26/05
2Lz02
0e/23-oe/28/os
08r03
ae/23-0e/26/as
2l:. Q2
0e/23-ae/28/as
08: O3
oe/23-oel2B/os
08:03
Dilution Factor: L
0.0400 0.0355 mg/T,B9
Hlil/PAlAC
HK5F2 ].A,J
HK5F2I.AIV
HKsMAlAO
HK5M^II1A4
HKsMA].AS
HK5MA1A5
HK5}4A]-A8
HK5IVIA1CT
HK5MA].Ct]
HK5MA1CV
HK5MA]-CW
92
L
94
1
r- o0
1
95
1
97
1
a02
L
96
L
99
1
99
I
STL Denver
( Cont inued on next page)
57
I,ABORATORY COIuTROL SAMPIE DATA REPORT
TOIAIT Fletals
Client Iot *---: D5I090L75
SPII(E MEASTIRED PERCNT
PARiqMETER AMOUMT AMOTINT UNITS RECVRY METIIOD
flatrix : WATER
PREPARATTON- WORK
ANAIJYSIS DATE ORDER #
chromium 0.200 0.195 ms/L 98 SW846 50108 A9123-A9/2A/0S EXSMATCX
Dilution Factor: I Alalyeis TLne.. r 08:03
copper 0.250 0.249 mg/t 10o sw846 60108 a9/23-09/28/0s HK5MA1C0
Dilut.ion Factor: I Allalyais fime..; 08r03
Nickel 0.500 0.4e2 mg/t 96 sw846 60108 Og/Zl-Og/28l05 rrKsMAlC1
Dilution Factor! 1 AnaLvsis Time..: 08:03
Lead 0.500 0.484 rlg/L 97 SW845 50108 09/23-09/28105 HKsMAT-C2
Dll,uElon Factor: X Analysie Tine..: 08:03
vanadium 0.5c0 0.497 tns/L 99 SW846 60108 09/23-09/28105 HK5MA]C3
Dilution Factor. 1 Aralysie Time., r 08:03
zinc 0. s00 0.461 $tg/L 92 SWB46 50108 09/23-09128/05 HK5MA]-C4
. Dilution Factor! L Analyele Tlme..; 08,03
zirconium 0.500 0.504 rLg/L l-01 sw845 50108 09/23-09/26105 HKSMAICs
Dilution Factor: 1 Analyaia Tj.me., t 2LtO2
llcrfE (s) :
Calculalions are performal before rouruIing to avoid round-off srrors in calculated results.
STL Denver 58
I'IATRIX SPIKE SAUPrJE EIIALUATIOII REPORT
llITAL lletrals
Clierrt Irot #--.: D5I090L76
DaEe Saryrled.,. ! 09/07/05 09:55 Date Received,. r 09108/05
Uatri)c. . , . , - . - - : WATER
PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
US Iot-Sauqrle
Mercury
NOIE (S)
=
RPD
RPD LIMITS METHOD
PREPARATION-
ANALYSTS DATE
WORK
oRpER #
*: D5I080243-004 Prep Batch S.. -: 5259437
7s N ( AS 114 ) SW845 7 47 0A
73 N (85 114) :.r (0-10) SW845 747Op^
Dilutlon Factor: 1
Analyeis Tirre. . : 18 : 18
09 / 23 / 0s HJ5JM1CL
oe / 23 / 0s HJSJMIC}!
Calculadons arc pertbrmcd ltcforc roundlng n avoid round-off errors ln calculatcd results.
N Spikcd analyte rccovery is ouside stated control limits.
STL Denver
Client Iot $. . . :
Date Sanpled- - - :
SAMPLE
PARAIyIETER AIvTOUNT
HAIAIX SPTKB SAT'TPT^E DATA REPORT
TOTAL Hetrals
Date Reeeirred - - : 09 / 0B/05
l{atrix-- ----3 WATER
PREPARATTON-
ANALYSIS DATE
DSr09017 6
a9/e7/a5 oe:55
SPII(E MEASRD PERCNT
RESMY RPD METTIODANIOUNT LINITS
WORK
ORDER #
l,ls Lot-SampJ-e #:
Mercury
}TD
}TD
NOTE (S} :
D5f080243 - 004 Prep Bat'ch
0.00500 0.00377 mg/L
Oualifiers; N
0-00s00 0-00365 mg/L
5259437
sw845 74744
3.3 SW846 74704
#. - -:
75
73
oe/n/as
oe/23/os
HJSJMlCL
HJ6JIVII-CM
Qualifiers: N
oilution Factor: 1
Ana).yeis Time. . : L8 : 18
Calcularion$ tre performed bcforc rourrding n avold round-off errors In calculated resulLs.
N Spikect analyrc rccovcry Is oursklc srarcd conrol llmks.
STL Denver 50
IMIIRTX SPIKE SAII{PI,E E\IALIIATION REFORT
I1O([AIT ltleta].e
CIient Lot *.--: D5f090L76
Date Saqr1ed..-! a9/L9/a5 11:l-5 Date Receiwed--: 09/L9/a5
PERCENT RECOVERY
R.ECOVERY LIMITS
RPD
RPD LIMITS },IEIIHCD
Irtatrix. . . . o . . . . !
PREPARATTON-
.A}JALYSTS DATEPAIU\METER
l{,S Lot-Saryr1e *:
Cadmium 95
9'7
Selenium
WATER
WORK
oRpER #
uS lot-sauple *: D5IL9022O-0O2 Prep Batctr *... I 5265237
Aluminum Ne,MsB (83 - 119) SW846 50108
NC,MSB (83 - 119) (0-2s) SW846 60108
Dllutlon Factor: 1
Analyois Tine. . : 21,: 15
Arsenic 101 (84 - L24) SW845 50108
99 (84 - r.24) 1. g (0-2s) SW846 501-08
DlIuEion FacEor3 1
Analysis Time,.; 08:23
Barium 99 (85 - 120) SW846 50108
98 (85 - r.20) 0.59 (0-2s) SWB46 60108
DlLutlon Pactor! 1
Analysia Time- - r 08 r23
Calcium 97 (48 - 153) Sw846 50108
es (48 - 1s3) 0.50 (0-2s) sw846 60108
DlIuElon Factor: 1
Analyeis Time. . r 21 :16
Chromium
80 N
B7
99
98
104
103
D5I190 22A-gA2 Prep Batch #, .
(89 110)
(8e 11ol t.z (o- 20)
Dl Lut1on Factor: 1
Analysie Tirne. . : 2a 206
(ez L12)
( BZ t!2) 6 .6 (O - 2A)
Di lution Pactor: I
Analysie Time-.: 20:05
(73 13s)(rr 13s) 1.1 (o-2s)
Dilutrion Factor: 1
Analygis Time..: 08:23
(sz Lzel
(az 129) 0,34 (o-25\
D1lut ion Factor: 1
Analysis Time. . : 08 :23
a9 / 23 - A9 / 27 / os HKr,{14 LFM
oe / 23 - 0e / 27 / as HKw14 lFN
a9 / 23 - Ae / 27 / As HKlr14LFX
a9 / 23 -A9 / 27 / 0S HKW141F0
: 5255193
sw845 5020
sw845 6A2A
sw845 5020
s}{84 5 6020
sw84 5 5 0108
sw845 60L0B
sw846 60108
sv{845 50108
09/23-09/26/As
oe/23-oe/26/os
HIO{141F5
I{KW141F5
oe/23-oe/28/os
oe/23-oe/28/os
HKVT141F8
HKW1 4 1 F9
ae/23-ae/28/0s
oe/23-ae/28/os
HKW1.4lGC
HKW14 lGD
oe/23-oe/26/os
ae/23-09/26/os
HKW141DW
HKW14lDX
oe / 23 - ae / 28 / 0s HKr{14 lGF
oe / 23 - ae / 28 / os HKw14 lcc
0e / 23 - 09 / 28 I os HKw141-cJ
09 / 23 - 09 / 28 / as HKtrtl4lcK
Copper
STL Denver
(Continued on nexE page)
Client Irot #.
Date Sanpled,
PAITJUI{ETER
I ron
Lead
Magnesium
Ni cke I
Potas eium
Si lver
Sodium
Vanadium
Zinc
PERCENT
RECOVERY
NC, MSB
NC, MSB
96
9s
99
99
95
94
RECO\ERY
LIMITS
IIATRIX SPIKB SAITIPLE EIfiAITUATION REPORT
TOtrAL Fletra]-s
: D5I090176
: 0gllg/as l"l";1"5 Date Received..3 09/L9/aS
llatrirc.- ---.: WATER
PREPAIU\TION- WORK
ANALYFIS DATE ORDER #
oe / 23 - ae / 26 / As HKW14 r.EU
a9 / 23 - oe / 26 / os HIfl^Il-4 r.Ev
oe / 23 - a9 / 28 / As HKwl4lGQ
oe / 23 - a9 / 28 / 0s HKwl41GR
09 / 23 -a9 / 26 / os HKwl4t Eo
09 / 23- 09 / 25 / A5 HKw14lEl
09 / 23 -o9 / 28 / 05 HKw14LGM
ae / 23-ae /28 / os HKW141GN
ae / 23 - ae / zG / os HKwl4t Ew
oe / 23 -ae / 26 / os HKW141EX
ae / 23 -as / 28 / os HKwr- 4LF2
ae / 23 -oe / 28 / os HKw141F3
ae / 23 -oe / 25 / os HKwr-41E4
a9 /23 -09 /26 / os HKW141E5
oe / 23 - 09 / 28 / 05 HKw14l-GU
09 / 23 -09 / 2s/ A5 HKW141GV
os / 23-os / 2s / as HKw141cx
ae / 23 - ae / 28 / as HKw141c0
RPD
RPD LIMTTS METHOD(sz 155)(52 lss) (0-2s)
Piluclon Factor: 1
Arralysie Time. . : 27 :16
(eg 121)
( ag 121) 0 .47 ( 0- 2s)
Pilution Factor: 1
Analyais Time-.: 0B:23
t6z a46)
(az ]46) 0,24 (o-2s)
Dilution Factor: 1
Analyeie Time..: 2l:!6
(B+ 120)
(8a LzO) 1.3 (0-2s\
oilutlon Factor r 1
Arralygis Time. . ; 0B r23
0e 132)
fie L32) O .25 (o-Zsl
oilution Factor r 1
Arralysie Time. . : 2t tL6
(zs L4L)
(zs 141-) 0.31 (O-25l.
Dilution Factor r 1
analysls Time..' 08:23
(zo zo3)(70 2A3) 2.a (0-40)
Dilution Factor: 1
Analysls Tlme..: 2L:16
( ss r-zo )(Bs 1-20) 0.5L (O-2s)
Dilution Factor: 1
Analysis Time..: 08:23
(eo 137)(50 137) O.L9 (O-2s)
oi lut.ion Factor: L
Analyais Time,.: C8:23
sw84 5
SWB4 5
6 0108
60108
L07
t_08
t 04
103
1"00
1_1_0
L01
100
93
94
sw84 5 5 0108
sw84 5 5 0108
sw84 5 5 0108
sw845 50108
sw84 5 5 0108
sw84 6 5 0108
sw84 5 6 010E}
sw845 50108
sw846 5010E}
SWB45 6O].CB
sw846 601_0B
sw845 50108
SWB45 5OlOB
sw845 50L0B
st^I84 6 5 0108
sw846 50108
STL Denver
(Continued on next page)
52
I'IATRIX SPIKE SAUPLE EIIaI,IIATIOII REPORT
TOTAIT Metale
Client Iot #.
Date Sanpled.
PARAL{ETER -ZLrconiurn
lrolE (s) :
PERCENT RECOVERY
RECOVERY LIMITS RPD
: D5I0 9 0L7 6
: 09/L9/05 11:15 Date Received-
t{atrix- - - - r . . . . r WATER
PREPARATTON- WORK
AhIAI,YSIS DATE ORDE-R-#
a9 /23 - o e / 26 / As HKWI4LGa
09 / 23 - oe /25 / As HKW141G3
RPD
LIMTTS
: oe/re/as
METI{OD
107
LO7
(80 120)
(80 72A) 0.20 (o-2s)
oi lut ion Factor : 1
Analyois T:.rne. . ; 21. : 16
sw845 60108
sw846 50108
CalculiUions are prrfortrcd bcforc rouodi[8 lo avold rouDd-off crrors ln calculalcd rcsults.
N Spikcd analyn rccovery is oulqide satcd conrol limits-
NC Thc recovcry and/or RPD wcrc nor calculakd.
MSB'Ilr recovery and RPD wcrc not calmrleterl bccaosc thc samplc amount was trcatcr 0ran four timca ftc spikc mount.
STL Denver 63
Client Iot #- - -:
Date Sanpl-ed- - -:
SAJVIPLE
}IAIRIX SPIKB SAIITPI,E DATA REPORT
TOTAL lrletals
Date Received. . ! 09 /79 / 05
Dlatrix-- ----: VIATERD5r090L76
09/a9/05 r.1:L5
SPIKE MEASRD PERCNT
RECVRY RPD METHOD
PREPARATTON- WORK
ANA],YSTS DATE ORDER #PAITJ\METER AI'{OIINT AMT AMOUNT UNTTS
l,IS Lot.-Sampl-e #:
Cadmium
0 ,014
0 ,014
Selenium
0 .0040
o.o040
lits Iot -Saq>}e *:
^A.luminum
a-,JL
32
Arsenic
0 . 01,4
0.o14
Barium
a .67
o ,67
CalcLum
110
110
D5ft9022O-0OZ Prep Batch *- - -:
0.0400 0.0525 mg/T, 95
0.0400 0-0s31- mg/t-, 97
Dilut ion Pactor: 1
Analysis Time..: 20:06
5265193
sw845 5020
L _2 SWB46 6024
6.6
sw845 6A2A
sw845 5020
: 5265237
ae I 23 - oe / 27 / os HK[^I141FM
09 / 23 - 09 / 27 / os HIoII4l-FN
oe / 23 - ae / 27 / as HKwr-4 1FX
09 / 23 - Ae / 27 / Os IIKW141F o
ae / 23 -ae / 26 / 0s HKw141Fs
a9 / 23 - 09 / 26 / 05 HKw14l-F6
D5I190 22A-AA2 Prep Batch # - -
2.00 55.L mg/L
Qualifiers : NC, MSB
2 . 00 s6 .7 mg/L
Qualif iere : NC, tvISB
Oilution Factor: 1
Analyslg Time, . : 21 :15
0 .0400
0 - 0400
2 .00
2 - 00
2 ,00
2.00
50.0
50.0
0.0362 utg/1,
Qualifiers: N
0 - 0387 mg/L
Dilution Factor:
Analysls Time. .:
2 . OZ mg/T,
l- . e9 mg/L
Dilution Factor:
Ana lya1e Time , . :
2 .66 mg/L
Z .64 mg/L
Pi Lut l on Factor :
Analyeis Time. . ;
ls8 mg/L
1sB mg/L
Dilution Factor:
Analyeis Time. . :
80
87
1
20 ;06
101
99
L
08 :23
99
98
L
08 :23
97
99
I
21 : l-G
1.8
0.59
sw84 5 5 01,08
sw845 601_0B
sw846 50108 Ae/23-Ae/28/0s HKW1-41-F8
sw845 50108 09/23-A9/28/ 0s HKW141F9
sw84 6 6 010B A9 / 23 - 09 / 28 / As HKW]-41GC
sw845 60108 A9/23-A9/28/05 HKWI-41cD
sw845 50108 Ae/23-09/26/0s HKWL41DW
0.60 sw846 6010B 09123-09/26/As HKW141DX
STL Denver
(Continued on next page)
64
IIAtrRIX SPIKE SAIIIPI,E DATA REPORT
TOIIjAL l{eta}a
Client Iot *...: D5I090175
Date Sar4rled...z o9/L9/o5 11:15 Date Received- -= 09/L9/os
SAI{PLE SPIKE
AMOUNT AI,IT
IVlEASRD
AIvIOUNT UNITS
PERCNT
RECVRY RPD METHOD
Matrix. . o . o . -, - r WATER
PREPARATTON-
A}IALYSIS DATE
WORK
oRpER . #PARAMETER
Chromium
Copper
f ron
Lead
Magmesium
Nickel
Potass ium
0 .050
o - 060
0.069 0.250
0.059 o.250
sw846 50108
1.1 SW846 50108
sw846 60r_08
0-34 SI^I845 50108
sw846 50108
sw84 5 5 0108
sw84 6 5 0108
a,47 SWB45 50108
sw84 5 6 010E}
0 .24 SW84 6 5 010I}
L.3
sw84 6 5 0108
sw845 501-08
sw845 50L0B
a .26 SWB4 5 5 0108
09 / 23 - A9 / 28 / As HKW141GF
oe / 23 - oe / 28 / as HKw14 1GG
oe / 23 - oe I 28 / os HKI{141GJ
oe / 23 - oe / 28 / 0s Hro{r-41GK
oe / 23 - 09 / 26 / Os HKwL4 lEU
ae / 23 - oe / 25 / os HKW141EV
a9 / 23 -09 / 28 / 0s HKw14 1GQ
ae / 23- 09 / 28 / 0s HKW14r.GR
oe /23-se / zG / as HKwr4lEo
oe / 23 -ae / 25 I as HKw14IEI
09 / 23 - A9 / 28 / Os HKW14]-GM
a g / 23 - oe / 28 / os HKIiIL 4IGN
oe / 23 -ae I 26 / 0s HKW141EW
ae I 23 - oe / zG / os HKw141Bx
0.200 a .259 IIJtg/L 99
0 - 200 o -2s6 mg/L 98
niluElon Factor; 1
enalyeis ?ime. , : 0B :23
0 . 32 8 mg/L 104
0.32-7 mg/L 103
Dilution Factor: 1
Analysis Tirne. . : 0B: 23
49
49
0 .054
0.054
Z9
29
34
34
L.00
t_.00
0,500
0 .500
50 .0
50_0
50 .0
s0 .0
54 .7 mg/T'
Qualifiers ; NC, MSB
5s .5 mg/L
Qualifiers : NC, MSB
Dilution Factor: 1
Analysig Tirno. . : 2L z1-6
0-047 0-500
a .o47 0.500
0.533 mg/l'
0 .530 mg/T'
oi IuE, ion FacEor :
Analysis Time. . :
7 8 -7 mg/t
78 - s mg/L
DlluElon Factor:
Analyeie Time. . :
A .52L mg/t,
0.514 mg/L
Dilution FacEor:
Analyois TIme. . :
87 -8 mg/L
Bs. I mg/L
Dilution t'actor r
Analysis Time. . :
95
95
L
08 :23
99
99
L
21:16
95
94
1
0B:23
L07
108
1
21 :16
STL Denver
(Continued on next page)
55
I.T"ATRIX SPIKE SA!,IPIJE DATA REPC}RT
rOTAL Metal.e
C1Lant Iot #...: D5I090176 llhErix- -.: WATER
Date SaEpled.... O9/L9/05 11:15 DaEe Received. -r 09/L9/o5
SAMPLE SPIKE MEASRD PERCNT PREPARATION- WORK
PARAMETE4 AMOUMT AI,IT AMOUMT rrNrTq BEC\rRY RPD METHOp ANAr,ySrS DATE ORPER #
Silver
ND 0.0s00 0.0518 rrylL 104 sttt845 50108 09/n-a9/28l05 HKWL41F2
ND 0.0s00 0.0516 n{lg/t 103 0.31, sw846 50108 a9/2?-O9/28/05 HKlfl-41F3
Dllutslon Facror! 1
Analysis Time.-r 08:23
Sodium
r.70 s0.0 222 ms/L 1-00 sw846 6010B A9/23-09/261A5 HIO{14184
170 50.0 226 raslL t-10 2.1 SWB46 60108 09/23-09/26/05 HKW141E5
Dilution Faetor: 1
anaiyelo Tlme.. z 27tL6
Vanadium
a.a79 0-500 0.s82 r.jls/r, 101 sw845 6010B o9/23-09/28l0s HKW141GU
o.079 0.500 0.579 mg/t 100 0-51 sw846 60108 O9/23-O9/2A/05 HKWL41GV
Dilution Fact.or. 1
Analyais Time., r 08:23
Zinc
o .47 O . s00 0 .931 mg/L 93 SW846 60108 O9/23-O9/2SI05 HK}[141GX
o-47 0.s00 0.933 ms/L 94 0.19 SW845 50r-08 O9/23-O9/281O5 HKlt141G0
Dilution Factor: f
Analysis Tioe,.r 08:23
Zirconium
o.ols 0.500 0.s49 mg/L 107 sw846 60L08 o9/23-O9/26l0s HKW141G2
0.or"s 0.s00 0.548 fis/r, 107 0.20 sw845 60108 a9/23-09/26/05 HKW141G3
DiluElon Factor: 1
Analyele Time..: 21r16
rtrr']ryn fel .
Calculations arc pcrforred bcfore rounding to uvoid round-off crrors in calculatcd rcsulB.
N Spikcd aoalyE rctovcry is outsilc starrd contnrl limits.
NC Thc rccovcry aod/or llPD werc nfi calfllaEd-
MSB Thc rccovery arl RPD wcre nrx calculaEd bccausc thc samplc arnourl was grealcr thm four tiGs *re spikc amnt.
STL Denver 65
STL DEIVVER
Contract:
Lab Code:
SOW IIIo. I
Total Metals Analvsis
COVER PAGT]. TNORGANIC ANALYSIS DATA PACKAGE
IIR$ Corporatl.oa gf,xt ![o.: D5I090176
STLDEN Cagc No. t ELS No,:
8uEl].c fD.
Grur-4A- 090805
G9$-5C-090805
Gr{-R2 - 090905
G[v-R3-090805
strr-R{ -o9O 805
@r-s{ -090 80 5
GT{- g5 - 09 0 805
Blcrc ICP lntserekmcnts corrcotrLong applied?
llerc rCP background corrcctl.ons aDDIiod?
If yea-worc ranr data genereted bcforc
aplrlicatlon of background corr.et,Lona?
Counncntse r
Lab 9qppl.tr No.
D5r09 017 6- 00 5
D5r09017 5-O02
D5r09 0 L7 6-003
D5r090L7 6-008
D5rO9 0L7 6- O07
D5r09017 6-005
D5r090175-00{
YeglNo t,ES
YaelNo YES
Yct/No
I certify that thLg d.tr l,eckrgo it ia corqrl{ancc wLth Uhc trrar end coaditl.ons of tshceontract, botb tcchaloall.y and lor eoaEletsenett, f.ot other thalr thc oondicLoaa d;taitedrbovc, Rclcase of thc drtr conttlncd lu tlrl,a hardcoty dtta ;lachegr rnd ia the eomDutar-rordrble drta
Buhittcd on flo5r5ry dl.akctte hag beon autshorized bl' the Laboratory ![anag.r or t]rc Maaager'B dcg:feBoc, ag
vcrllLod by the follorning tLgnatsurc.
sisrnarurs = ,-
''
,' t JK ,ul*rJ.ti tl 't,
Nanc r
:l li-o *
Doo Kattula
Date:ritlc: Data lna}yet
STL Denver COVER PAGIE IN 67
ffisrr
UR,S Corporntion
Totrl Metals Analysis Datr Sheet
Latr Ntme:
LotlSDC Number:
Matrix:
7o tllolsture:
Brsis:
Analysis ltnethod:
tJnlt:
QCI Batch ID:
Stmple Allquot:
Dilution Factor:
sTL t)t:NVt::R
D5l090r 7a
WATER
NiA
lys
f.0.] 0B
nrg/L
5265217
50 rnl
1
Cllent Sample II):
Lab Sample ID:
Lab Workorder:
Date/Tirne Collected:
Date/Tlme Recelved:
Date/Time Leached:
Date/'l'ime Extracted :
DatelTime Analyzul:
Instrument lD:
sw-sc-0eo8o5
pst090l76:0u2
HJSM I.
{}9/(}8i05 09: I 5
09i09i05 09:30
09/23105 I5:30
09/26Ds 21:26
02I
CIAS No.Annlyte Conc.MDL RI,a
7429-90-5 Alurninum t_7 0.01 7 0.10
7439-t{e-6 Iron 0.025 t).021 0.t0 B
7439-95-4 IVlugncsiurn 660 (1.043 0.20
7 410-67 -7 Zirconium 0.00 r 6 0.00t 6 0.0r 5 U
STL Denver
Form I Analysis Datu Sheet Equivalent
5B
ffisrr
URS Corporation
Total Metals Analysis Datr Sheet
Lab Neme:
Lot/SlXl Number:
Mntrix:
o/o Molsture:
Brsis:
Analysis tltethtxl:
tlnlt:
QC Brtch ID:
Sample Allquot:
Dllutlon Fretor:
STI DENVER
p5r090176
WATER
NiA
Ws
6010B
rng/I.
5265237
50 mL
rp
Cllent Sample ID:
Lab Sample It):
Lab WorkOrder:
Date/Tirne Colle*ted:
Dute/Tinre Received:
Date/Tlnre [,erched:
DstdTlme Extrscted:
Date/Tllne Analyzed;
lnstrurnent I D:
cw-sc-090fl95
p5rr)90176-002
IIJSM L
09/08/05 09: 15.
09/09i05 09:3Q
0-9/23/05 I 5:30
09i28i05 0l :00
E]
CAS No.Analyte Conc.MDL RL a
7440-70-2 Calcium 1800 0_34 2.4
7440-(t9-7 Potassium s00 2.4 30
7440-23-5 Sodium 69011 il 50
STL Denver
Form 7 Analysis Data Sheet Equivulent
ffisrt
URS Corporation
Total Metals Anulysis Datt Sheet
Lab Narne:
LoUSDG Number:
Matrlx:
o/, Nloisture:
Basis:
Anrlysls I\{ethod:
Unit:
QC Batch ID:
Stmple Allquot:
Dilutlon Factor:
STL DEIIVER
psr()gCI.l76
WA ER
NiA
Yst
60t rlB
MB/L
5265217
50 rnl.
I
Cllent Sample ID:
Lab Stmple ID:
Lsb Workordcr:
Date/Tlme Collected:
Date/Tlme Recelved:
Date/Time Leached:
Dste/Tlme Extructed:
Dnte/Tlme Analyzed:
Instrurnent ID:
cw-sc-oejl80s
DSI.090176-0()2
HJSML
09/0tt05 0e: [ 5
()9/09/05 09:30
09/23/0s 15:30
Q9/?.fl/05 0e:+3
016
CAS No.Analyte Conc.M [][,RL a
7440-38-2 Arsenic 0,0r 2 0.0044 0.01 5 B
74.40-39-3 Bsriurn 0.15 0.00070 0.0r 0
7 440-47 -1 Chromium 0,0026 0,0026 0-0r 0 U
7440-s0-g Copper 0.0045 0.0045 0.0t0 t]
7439-92-r Lead 0.0026 0.0026 0.0030 U
1444-$2-0 Nickcl 0.020 0.0012 0.040 B
7444-224 Silver 0.0028 0.0028 0.010 U
7444-62-2 Vanadiunr 0.0039 0.0025 0.0t 0 B
)++o-oo-c,Zinc 4.0077 0.()04s 0.020 B
STL Denver
Form I Analysis Data Sheet Eqaivalent
70
ffisTL
URS Corooratlon
Total Metals Analysis Data Sheet
Lab Name: STL DENVER Cllent Sample lD: GW-5C-090805
Lot/SDG Number; D5l09Ql76 Lab Snmplo ID: D51090176002
Metrir! WATER Lab $brkorder: HJSML
To.Nlolsture: N1A Detc/Tlme Collccted; 09/08/05 0915
Basls: WSI Drte./Tlmc Recclved: 09/09i05 09:30
Analysls lllethod: ?470A Date/Tlme Lcached:
Unir mglL Date/Tlme Extracted: 091231fi5 12:50
QC Brrch ID: 525941"1 DEtc/Timc Analyzed: 09!23/05 18:'28
Sample Allquot: lnstrument lD: 0I9
Dilution Factor: L
CA,S No.Anelyte Conc,MD[,RL a
7439-97-6 Ivtercury 0.000044 0.000044 0.00020 TJ
STL Denver
Form I Analysis Data Sheet Equivalent
77
ffisTL
UR*S Corporttion
'fottl Metals Analysis Detn Sheet
Lnb Name:
Lot/SDG Nunrber:
Matrix:
7o Molsture:
Basls:
Analysls Method:
Unlt:
QC Brtch ID:
Sample Aliquot:
Illlutlon Factorl
STL DENVER
D5t090 t 76
W;\rrn
N/A
us
6020
mgil,
s2s5 I 93
50ml ,
2A
Cllent Sample ID:
Lab Sample ID:
Lab \Uorkorder:
Date/Tlme Collected:
DatelTlme Recelved;
Date/Tfune Leached:
Date/Tlrne Extracted:
DatelTlmr Antlyzed:
lngtrument ID:
GW;5C-()q0805
D.sl090l 7r)-002
HJttl'{L
0e/JI[,{05 0e: I s
09i09/05 09;J0
09/23105 I5:30
$91.71t05 05:17
QQ4
CAS No-Analyte Conc.MDL Rl_.a
744043-9 Cadmium 0.0024 0.00080 0.020 B
7782-49-2 Selenium 0.0066 ().0()66 0.040 LJ
STL Denver
Form 1 Analysis Data Sheet Equivalent
72
ffisrr
URS Corporetion
Total Metals Analysls Datr Sheet
Leb Name:
LoUSIIG Number:
Matrix:
7o Molsturc:
Basis:
Annlysls M ethod:
Unit:
QC Batch ID:
Srmple Aliquot:
Dllution l,-actor;
srL DEIi-Yf3
psrCIP!}t z0
WATER
N/A
Ys
601 0B
m8/L
5265237
50 mL
I
Client Srnrple ID:
Lnb Sample ID:
Lab r#orkorder:
Drte/Time Collected:
Date/'l'ime Received:
Date/Tlme Leached:
Drte/Time Extrrcted:
Dsten'ime Analyzcd:
Instrument ID:
GW-R2-090$()s
D51090176-003
HJEM.v
09i()8/05 09:25
()9i09/05 09:30
09i23/()5 I5:30
09/26i05 2l :31
02r
CAS No,Analyte Conc.MDL RL a
742q-90-5 Aluminum 4.76 0.01 7 0.10
7440-70-2 Calcium 94 0.034 0.20
743e-S9-6 lntn 0.93 0.02 r 0.r0
7439-9s4 Magresiurn na 0.043 0.2a
7440-09-7 Potassium 330 0.24 3.0
7440-67-7 Zirconium 0.0030 0.0016 0.015 B
STL Denver
Form I Anolysis Duta Sheet Equivalent
73
Lab Narne:STL DENVER
Lot/SDC Number: D5I090l76
Matrix: W{TEft
"/o Molsture: N/A
Brsls: Wct
Analysis lllethod: (rQ[tlB
Unit: rng/L
QC Batch ID: 5265237
Snmple Allquot: 50 rnL
Dllutlon Frctor: I ()
ffisrt
URS Corporation
Totrl Mrt*ls Anelysis Date Sheet
Client Srmple ID: GW-R2-090805
Lnb Snmple ID; D51090176-003
Lab \L'orkOrder: HJSMV
Date/Time Collected: 09/08/05 09:25
Date/Time Recelved: 09109/05 09;3$
Date/Tlme Leached:
Dnte,/Tlme Extracted: 09/23105 15:30
Date/Tlme Analyzed: 09/28/05 0l : I I
Instrument ID: AZ!-
I
l
CAS No-Analyte Conc.MDL RL a
7440-23-5 Sodiunr 6900 n 50
STL Denver
Form I Analys* Data Sheet Equivalent
74
Lrb Name:$IL DENVER
LotlSDG lrlumber: D51090176
Matrfx: WATER
7o Molsture: NrA
Basis: IrYct
Analvsls lUethod: 601QB
U n it: nrg/[.
QC Bntch tD: 5265237
Sample AIIquot: 50 rnl
Dllutlon Factor: I
ffiSTL
URS Corporetion
Total Metnls Analysis Data Sheet
Client Sarnple ID: GW-R2-090805
Lnb Sample ID: 1151090176-003
Lrb WorkOrder: HJSMV
Datc/Tlme Collected: t)9/0$i05 09:25
Dnte/Tlme Recelved: 09/09/05 09:-]0
Datc/Tlme Leached:
Date/Tlme Extracted: 09i23i()-5 I -s:30
Date/Time Analyzed: 09/28/05 09:48
Instrurnent ID: Ofo
CAS No,Analyte Conc.[{DL RL a
744448-2 Arsenic 0.0044 0.0044 0.0r5 U
7440-39-3 Barium 0.9s 0.00070 0.010
144047-3 Clhronriurn 0.0030 0.0026 0.01t)B
7440-5G8 Coppcr 0.0045 0.0045 0.010 U
7439-92-l Lcad 0.0026 0.0026 0.0030 U
7440-42-0 Nickcl 0.0027 0.0012 0.040 B
7444-224 Silver 0.0028 0.0028 0.0I0 U
7444-62-Z Vanaclium 0.0038 0-002s 0.010 R
7440-66-6 Zinc 0.0095 0.0&45 0.020 B
STL Denver
Form I Analysi.s Dcfa Sheet Equivalent
75
ffi$rt
URS Corporation
Total Metals Anelysis Data Sheet
Lab Name:
LoUSDG Numher:
Matrlx:
7" Moisture:
Basls:
A,nalysis Method:
Unlt:
QC Batch tl):
Srmple Allquot:
Ililutlon Factor:
STL DT..NVER
psrQg_oJ z6
WATER
N/A
Wct
7470 i\
rttglL
52s94t7
l-
Cllcnt Sample ID:
Lab Sarnplo lD:
Lab TrVork0rder:
Date/Time Collected:
Date/Tlme Recelved:
Date/'l'ime Lenchcd:
Date/Time S,xtractedl
Datc/Tlrne Analyzed:
Instrument ID:
GW-R2-090805
DSI090I76-o()3
HJsMV
0oi0.fl/05 09:25
0,9/09i05 09:30
09/23i05 l2:5_0
0.9i23l05 l8:33
otg
CAS No.Analyte Conc.MDL RL a
7439-97-6 Mercury 0.000044 0.000044 0.00020 U
STL Denver
Form I Analysis Data Sheel Equivalent
76
ffisrt
URS Corporadon
Total Metals Analysls Data Sheet
Lrb Name:
LoUSDC Numher:
Iltatrix:
7" I\{olsture:
Bnsis:
Analysls iltethorl:
Unit;
QC Batch tD:
Sample Allquot:
Dllution Frctor:
$]I. D}NYHR
D5t000176
WAT'ER
}IIA
Wet
60"Q
mg!l*
5265 I 93
50 mL
l0
Cllent Snrnple ID:
Lab Sample ID:
Lab Work0rder:
Drte/Time Collected:
Date/Tlme Received:
Date/Tlme Lenched:
Dete/Tlme Extracted:
Dnte/Tlme Analyzed;
Instrument ID:
GW:82-09o8os
Dst0eor 76:003
HJSMV
0e/08i05 lJ9:25
0e/09lQI 09:30
09/23105.15:30
l?/27 !0s 05:20
004
CAS No.Analyte Conc.MDL RL a
744043-q Cadmium 0.00040 0,00040 0.010 U
7792-49-2 Selenium 0_0060 0.0033 0.020 B
STL Denver
Form I Analysis Data Sheet Equivalent
77
ffisTL
URS Corporadon
Tottl Metals Analysls Deta Sheet
Lab Name:
LoUSDf,l Number:
IMatrlx:
7o Molsture:
Basls:
Analysis Method;
Unlt:
QC Batch IDr
Sample Allquot;
Illlutlon Frctor:
STL DENVtrR
Dst090t 76
WAT[,R
NIA
It$
60r Otl
nrglL
s265237
50 mL
I
Cllent Sumple ID;
Lab Sample II):
Lab t#ork0rder:
Date/'l'ime Collected:
Date/Tlme Received:
Date/Time Lenched:
Dste/Tlme Extructed:
Date/Time Annlyzeel:
Instrument ID:
cw-ss-0eq80s
p5r0e0 r7G004
HJSMX
09i08i05 [0:.38.
09/0e105 09:30
09in3/05__ I 5:30
09/26/05 2tf I
92L
CAS No.Analyte Conc.MDL RL a
74?9-90-5 Aluminunr 0.034 0.017 0. I0 B
7+10-70-2 Calcium 43 0.034 0.20
7439-89-6 Iron 0.r9 0.021 0.r0
7 439-95-4 Magncsium 92 0.043 0.20
7440-A9-7 Potassium r60 a.24 3.0
TMfJ-23-5 Srxliurn 3000 t.l 5.0
7444-6i-7 Zircon iurn 0.0017 0.001 6 0.01s B
STL Denver
Form I Analvsis Data Sheet Esuivalent
7B
Lsb Nnnre:STL DENVER
LoUSDG Number: D51090176
Matrix:WATER
o/o Moisture: NiA
Besis: lfet
Analysls Method: 60108
Unlt;m$lL
QC Batch ID: 5265237
Sample Allquot: 5Q.mL
Dilutlon Factor: I
ffisrt
URS Corporation
Totrl Metals Analysis Datn Sheet
Cllent Sample ID: EJM-S5-090805I
Lab Sample ID: D51090176-004
Lab WorkOrder: t-UlM X
Dnte/Tlme Collected: 09/08/05 10:38
Dntc/Tlme Recelved: 0?i09l05 09:30
Date/Tlme Leached:
DatelTtme Extracted: 09/23105 15:30
Date/time Analyzed: 09/28/05 09:54.
Instrument lD:0t0
CAS No,Analyte Cotrc.MDL RL a
7440-38-2 Arscnic 0.0045 0.0044 0.015 B
7440-39-3 Barium 0.20 0,00070 0.0t0
744047-3 Chrorniurn 0.0026 0.0026 0.0t0 U
7440-s0-8 Coppcr 0,0045 0.004s 0.0r0 U
7439-q2-l Lead 0,0026 0.0026 ().0030 LI
7M$-42-0 Nickel 0.0024 0.00r 2 0.040 B
7440-22-4 Silver 0,0028 0.0028 0.010 U
740-62-2 Vanadiurn 0.0027 0.0025 ().0 I 0 B
74/;A-6,G6 7,inc 0.0045 0.004s 0.020 ti
STL Denver
Form I Anolysis Data Sheet Equivalent
79
ffisrr
URS Corporation
Total Metals Andysls Data Sheet
Ltb Ntme:
Lot/SDC Nurnber:
Matrix:
7o Nlolsture:
Brrgis:
Analysls Method:
Unlt:
QO Batch ID:
Srmple Allquot:
Dilution F-actor:
STL DENVER
D51090176
WATEIT
NIA
Wct
7.+7QL
mgi L
5z5e_13L
I
Client Snmple ID:
Lrb Sample ID:
Lnb WorkOrder:
Date/Tlme Collected:
Drte/I'irne Received:
Date/Tlme Leached:
Drte/Tlrne Extrscted:
Date/Tlme Analyrcd:
Instrument If):
GW-#i-0e0805
Dsr0go l76-004
HJsr[X
09/08/05 l0:38
09/09i05 09:30
A9D3|Q5 17:50
091'1i0-5 I 8;35
I}T9
CAS No.Analytc Conc.MDL RL a
7439-91-6 Mercury 0.000044 0.00()044 0.00020 U
STL Denver
Form 1 Analysis Data Sheet Equivalent
BO
ffiSTt
URS CorToratlon
Total Metals Analysls Data Sheet
Lab Name:
LoUSDG Number:
Mrtrix:
o/o MolsfiIre:
Basls:
Analysls Mcthod:
UnIt:
QC Brtch ID:
Sample Allquot:
Dilutinn Factor:
STL DE}.IVER
D51090r 76
WA'I'EIt
NiA
Wet
60?0
ms/.L
5"65 I 93
50 mt
5
Cllent Srmple ID:
Lsb Semple ID:
Lrh Work0rder:
Date/Tlme Collected:
Datef ime Recelved:
Date/Tlme Lesched:
Datefflme Extracted:
DatelTlme Analyzed:
Instrumont ID:
cw-s5-090805
psl0eor 76-004
i-I18MX
09/08/05 I0:38
0e/0e/05 09f0
09123/05 [5;3Q
A9t?7t05 A5:t4
004
CAS No.Analytc Couc"MDL RL a
74.4.043-9 Cadmium 0.00020 0.00020 0,0050 U
778249-2 Selenium 0.0022 0.00 t 6 0.010 B
STL Denver
Form L4nolvsis Data Sheet Egalvalent
81
ffisrt
URS Corooration
Total [Ietals Analpis Date Sheet
Lab Nrme: STL DENVER Cllent Srmple lD: CW4A-090805
l,oUSDG Numbcr: D5l090l7E Lab Sample ID: D-51090176-005
Mltrlx: WATER Lab WorkOrder: HJ8M2
'/o Moisture: NIA Date/limc Collected: 09/08/05 I l:00
Basis: Wct Date/Tlme Recelved: 09/09/05 09:30
Analysis Method: 60108 Date/Tlme Leached:
Unit: mdl, Date/Tlme Extracted: A9l2ll05 15l.10
QC Batch tD: 5265237 Date/Tlmc Andlzcd: 09126105 2l:56
Samplc Aliquot: 50 mL Instrument lD: QZt
Dilution Factor: I
CAS I{o.Analyte Conc.I}TDL RL a
7429-9(r-s Alurninum 36 4.0t7 0.i0
7440-71L7 Calciurn It0 0.034 ().20
7439-89-6 Iron 32 0.02 I 0. l0
7439-9s-4 Magnesiurn 97 0.043 0.24
7440-()9-7 Potassiurn 300 0.24 3.0
741'0-67-7 Zirconlum 0.023 0.00t (r 0.0r s
STL Denver
Form I Analysis Dato Sheet Equivalent
B2
ffisrr
LIRS Corporatlon
Total Metals Analysls Data Sheet
Lnb Name:
LotlSDG Number:
Matrix:
7o l\toisture:
Basls:
Annlysls Method:
tlnit:
QC B*tch ID:
Sample Aliquot:
Dilution Factor:
.sT[. DENVFR
D5ro90l76
WATER
NiA
U$
O()LAP
mgiL
526s?37
50 mL
r0
Client Srmple [D:
Lsb Sample ID:
I,ab trl/orkorder:
Drte/Time Collected:
Date/Tlme Recelved:
Date/Tlme Leached:
Date/Time Extracted:
Date/Tlme .rl,nalyzed :
Jnstrument ID:
GW4A-090q05
851090176-005
HJ8M2
09/08/05 I I:0Q
0oi0q/Q5..09:30
09i23/05 15;3Q
09/28r0s 0l;2J
a2t
CAS No.Anulyte Conc.MDL RL a
744A-23-5 Sodiunr 6s00 II 50
STL Denver
Form I Analvsis Datu Sheet Equivalent
83
ffisrr
URS Corporatlon
Totrl Metals Analysis Data Sheet
Lab Name;
l,oUSDC Nurnber:
Matrlx:
o/o Nlolsturc:
Bosls:
Analysls Method:
Unlt:
QC Batch ID:
Sarnple Aliquot:
Dilutlon Factor:
STL DENVER
D5I090r 76
WATER
N'E
Ssl
(IOJ OE
mB/l
5265217
so.mL
I
CIIent Sanrple ID:
Lab Stmple ID:
Lab Work0rder:
Dnte/Time Collected:
Date/Tlrne Received:
DaterTlme l-,etched:
Dste/Tlme Extrtcted:
Dttefl'ime Anslyzed:
lngtrument ID:
G\1:*A-0eo80s
D-1l090l7co0s
HJ8M2.
09/08/05 I L00
09/0e/05 0e#0
0ei23l05.15:30
0912U05 09:5e
0r6
CAS No,Anrlyte Conc.MDL RL a
7M(t-38-2 Arscnic 0.0098 0.0044 0.0r5 B
7444-39-3 Bariunr $.47 0-00070 0.0t0
744047--"Chronrium 0.045 0.0026 0.0r0
7440-50-8 Copper 4.472 0.0045 0.010
7439-92-l Lcad 0,028 0.()026 0.0030
7440-A2-O Nickel 0.042 0.00I2 0-040
7440-22-4 Silver 0.0028 0,0028 0.0 l0 U
J440-62-2 Vanadiunr 0.067 0.0025 0.0r 0
la+o-oo-o Zinc ll.7l 0.004s 0.020
STL Denver
Form 1 Analysis Dato Sheet Equivalent
B4
ffisrt
URS Corporatlon
Tottl Metrls Analysls Data Sheet
Lab Name:
LotlSDG Number:
Matrix:
Yo Moisture:
Bnsls:
Analysls Method:
Unit:
QC Batch ID:
Sarnplc ,A,liquot:
Dilution Factor:
STL DENVER
D5I090t 76
$/ATEIT
NIA
Wct
7470L
rngiL
5259437
I
Cllent Sarnple II):
Lnb Srmple ID:
Lab \ilorkorder:
Date/fime Collected:
Date/Time Recelved:
Date/Tlme Lerched:
Datc/Tlme Extracted:
Dateftlme Antlyzed:
lnstrument ID:
GW4A-0e0805
psup,0 r 76-00s
HJttM2
09i08/05 I l:00
09t0905 0e:30
09/'110-s I2;50
09/23i05 , l8:36
0.12
CAS No.Annlyte Conc.MDL RL a
7439-97-6 Mercury 0,000M4 0.000044 0.00020 U
STL Denver
Form I Analysis Dota Sheet Equivalent
B5
l,ab Ntrne:srr nENvER
l,ot/SI)G Number: D51090176
Mutrlx: WATER
7o tlfolsture: NlA
Basis: lygl
Analysls Method: 6020
Unit: rngi L
QC Batch lD: 5265193
Sample Allquot: 5() ml,.
Dilution l'nctor: 1!
ffisrl
URS Corporation
Total Metals Analysis Deta Sheet
Cllent Sample ID: GW-4&090805
Lab Sample ID: Ds1090t 76-Q05
Lab Workorder: H.l8M2
Dare/Tlme Collected: 09/08i05 .l I:00
Date/Ttme Received: 09/09/05 09;30
Dtte/'l'irne Lerched:
Ilate/Tlmc Extracted: 09123/f)5 15:30
Date/Time Analyzed: 09lTI/05 A5:27
lnstrument ID: ()04
CAS No.Analyte Conc.MDL RL a
7M0-43-9 Cadnrium 0.001I 0.00040 0.0r 0 B
7782-49-2 Selcnium 0.0083 0.0033 0.020 B
STL Denver
Form I Analysis Dsta Sheet Equivalent
B5
ffisrt
UR,S Corporation
Tottl Metals Analysis Ilatu Sheet
Lab Name:
LotlSDG Number:
Il{atrlx:
o/e Molsture ;
Bnslsl
Anrlysis Method:
Unlt:
QC Brtch ID:
Sample Allquot:
Dllutlon Factor:
sI[, pFNVhB
D5l090l ?6
WATFR
N/A
Wct
60rQE
III8,L
s2'6s?37
f(tnu-
I
Cllent Sample ID:
Lab Sample II):
I,ab \[brkOrder:
DrtelTime Collccted:
DrtelTime Rccelved:
Date/Tlrne Leached:
Date/Tlme Extracted:
Dnte/f irne Annlyzed'.
Ingtrunrent ID:
G\Y-S4-Oeottos
D5r090 r 76-J)()6
HJEM,.
09r08i05 I I :5(l
0o/09i05 09:30
09i23/05 l5:30
09/^6i0J.22:01
021
CAS No.Analyte Conc.MDL RL a
7429-9A-5 Aluminum 0.017 0.017 0.1t)U
7444-70-2 Clalciurn 59 0.034 0.20
7439-89-6 lron 0.14 0.021 ().1 0
7 4_\9-c)5-4 Magncsium 160 0.043 0-20
7440-09-7 Potassium 290 a.24 3.0
7444-n-5 Sodiunr 4600 I.I 5.0
7440-67-7 Zirr,onium 0.0024 0.00 t 6 0.01 5 B
Denver
b-orm 1 Analysis Data Sheet Equivalenl
ffiSTL
URS Corporatlotr
Total Metals Analysis Dttr Sheet
Lab lt{arne:
Lot/SDG Number:
Matrlx:
04 Molsture:
Brsis:
Antlysis Mcthod:
Unlt:
QC Batch ID:
Sample Aliquot:
Dilution Factor:
STL DENVER
D5t090 t 76
WATER
NiA
\\bt
601 0B
mSiI
s261217
50 mL
I
Cllent Sample lD:
Lab Sample ID:
Lab Workorder:
Drte/Tlme Collected:
Date/Time Recelved:
DatelTime l,e&ched:
Date/Tlme Extractedi
Date/Tlme Antlyzed:
Inetrurnent If):
Gw-s4-090805
psr090 r 76-006
HJ8M5
0.91t)8/05 I1:50
09/09/05 09:3!
09/23r'05 1 5:i0
09/r8l05 1,0:0a
a-16
CAS No.Andyte Conc.MDL RL a
744448-2 Arscnic 0.0044 0,0044 0.0I5 r.j
14.l'0-39-3 Barium 0-t2 0.00070 0.0r 0
744047-3 Chromiurn 0.0026 0.0026 0.010 IJ
7440-50-8 Crrpper 0.0045 0.004s 0.01()U
7439-92-1 Lcud 0.0026 0.0026 0.0030 LJ
744U-42-0 Nickcl 0.mt2 0.00 r 2 0.040 LJ
744fi-22-4 Silver 0.0028 0.0028 0.0r0 U
N+o-oz-z Vanadiunr 0.002s 0-002s 0.01 0 U
7M$-66-6 7,inc 0.0045 0.0045 0.020 U
STL Denver
Fny,.trr I lrrnll,rcic l)rrln .lhoot Fnvlrrnlonl
BB
ffisrt
IIRS Corporation
Total Ilfetals Analysis Datt Sheet
Lab Nrme:
LoUSDG Number:
Mntrlx:
7o Moisture;
Basis:
Analysis lVlethotl;
Unit:
QC Batch ID:
Srmple Allquot:
t)ilution Fnctor:
STL T,ENYER
njr090t 76
WATER
NiA
Yc!
7-170A
mg/1.
5?5e411
I
Cllent Sample ID:
Lab Sample ID:
Lab Workorder:
Dete/Tlme Collected:
Dnte/Tinre Received:
Drte/Tlme Lenched;
Drte/Tlme Extracted:
Dntc/Tlme Analyzed:
Instrumeut l.D:
cw-s4:09080s
pst090 r 76-006-
HJ8M5
nrrorvtts I I:f0
09109/Q5 09:30
fi9D3/45 L2:50
0e/2310s I qiig
aI9
CAS No-Analyte Conc,I\{DL RL a
74.\q-97-6 Mercury 0.000044 0.000044 0.00020 U
STL Denver
lI^-- I lunl..nln lt_aJ n |FL-.rl Ea..3,.nlr>*l
B9
ffiSTt
Lm,S Corporttion
Total N(etals Analysis Data Sheet
Lrb Name:
LoI/SIIG Number:
Mttrir:
7o Molsrure:
Basls:
Analysls Method:
Unlt:
QC Bntch ID:
Sample Aliquot:
Dilutlon Fnctor:
S.TI- DTTNVER
Dsl090 t 76
WATER
N/A
UsI
6020
mpL
526s I 93
50 mL
5
Cllent Sarnple ID:
Lsb Sample ID:
Lsb Work0rder:
Dote/Time Collected:
Date/Tlme Recelved:
Date/Tlme Leached:
Dnte/Tlmc Extrncted:
Drtell'ime Analyzed:
Instrumont ID:
GW-f,t09080s
p5r090176-006
HJ8M5
00/08/0-5. I I;50
0910e/()5 t)9:30
09/23105 l5;30
09/27105 05;3,1
aa4
CAS No.Analyte Conc.MDL RL a
744443-9 Cndrniurn 0.00020 0.0t)020 0.0050 IJ
7782-49-2 Sclcnium 0.0053 0.0016 0.010 ts
STL Denver 90
ffiSTL
LIRS Corporution
Total Metrls .{nalysls Data
Lnb Neme:
LoUSDC Number:
Mttrir:
7" Moisture:
Btsis:
Analysls lllethod:
Unlt:
QC Bstch ID:
Stmple Allquot:
tlilution Factor:
sTr..,_EIYyER
D5t090 t76
wA'ttR
NiA
wfi
(r0l0B
rnglL
5165237
50 rnL
I
Sheet
Client Sample ID:
Ltb Snmple ID:
Lab Workorder:
IlatelTime Collccted:
Date/Time Received:
Date/Time Lesched:
Drte/Time Extrscted:
Drtefl'ime Anrlyzed:
Instrument ID:
cw-R4-090805.
pt[0e0176-007
HJStvl6
09/0$i05 I2:a0
f)9/09i05- 09:30
09i 23i()5 I 5:30
agl26rtl5 22.06
02r
C.AS No-Anrlyte Conc.MDL RL a
7429-90-5 Aluminum 2.1 0.017 0.10
7440-70-2 Clalcium 5S 0.034 0.20
7$9-8q-6 Iron 3-0 0.02 r 0- I0
l43e-95-4 Magnesium 48 0.043 0.20
7440-A9-7 Potassium 210 u.24 3,0
7M0-23-5 Sodium 3200 I,I s.0
7 440-67 -7 Zirconium 0.0032 0.0016 0.0r 5 B
STL Denver
Fnrm I Annlvsis nnh Sheet Eouivolcnt
9t
ffiSTL
IJR^S Corporatlon
Total Metals Analysis Data Sheet
Lab Nnme:
Lot/SDG Number:
Mntrix:
7o Molsture:
Brsis:
Analysis Method:
Unlt:
QC Bttch ID:
Sarnple Aliquot:
Dllution Fsctor:
STI,TENVFR
Dsr090r 76
WAIEB
N/A
]YsI
()0108
nrg/[,
5265237
50 m.[.
-L
Client Srmple ID:
Lsb Sample ID:
l,rb Workorder:
Date/fime Collected:
Date/Tlme Recelved:
IlatelTlrne Leached:
DatelJ'irne Ex tracted :
Dete/Tlrne Annlyzed:
Instrument ID:
(iw-R4-090805
psr!)90176-007
HJ8M6
()9/08/05 I2:40
09/09/05 09:30
0923/0s l5:30
09128/05 l0:09
OI0
CAS I\o.Analyte Conc.MDL RL 0
7440-38-2 Arsenic 0.0M4 0.0044 0.0rs U
7440-39-3 Barium 1.5 0.00070 0.0r 0
74l,047-3 Chromiurn 0.0049 0.0026 0.010 B
7440-50-8 Coppcr 0.0045 0.0045 0.0r 0 U
7439-92-l Lead 0.0026 0 t)026 0.0030 U
7440-02-A Nickt:l 0.004I 0.00r 2 0.040 B
1140-?,24 Silver 0.m28 0.0028 0.010 Lj
h+o-oz-z Vanadiunr 0.0055 0.002s 0.0r0 B
7440-66-6 Z.inc 0.013 0.0045 0.020 B
STL Denver
L-avt t I lanl*cic llntn Cha,a) FauirrrtloaO
ffisTI,
IIRS Corporation
Ilotal Metals Analysis Data Sheet
[.,ab Name:
Lot/SDG lt{umber:
Mntrlx:
7o Molsture:
Basis:
Analysls IVIethod:
Unit:
QC Batch ID:
Srmple Allquot:
Dllution liactor:
$TJ/ DTTNVER
p5r090176
WATEIT
NiA
Wet
74'l0A
n'rg/L
95e437
I
Cllent Sarnple ID;
Lab Sample ID:
Leb Work0rder:
Date/Tlme Collected:
Drte/Time Recelved:
Date/Tlmo Lesched:
Date/fime Extracted:
Dtte/Time Analyzed:
Instrument I D:
(iw-R4-090805
p5r090r 76-007
HJRM6
ogiQ$ios I2-40
09i0q/05 09:30
09t23105 I2:50
09i23/05 18:40
0r9
CAS No.Anolyte Conc.MI}L RL a
1439-97-6 Mercury 0.000044 0.000041 0.00020 U
STL Denver
Fnrm I Anolvsis llata Shp.e,f Eouivulent
93
ffisrt
IIRS Corporatlon
Totel Metals Analysis Detl Sheet
Lab Nanre:
LoUSDG l{umber:
Mrtrh:
7o ltlolsture:
Bnsis:
Analysis IVt ethod:
tinit:
QC Batch ID:
Sample Allquot:
Dilutlon Fsctor:
STL DENVER
psrr)gOI76
WATER
NiA
lys
60^0
mgL
s265 I 93
50 mL
5
Client Sample ID:
Lab Sample ID:
Lab Work0rder:
Date/Tlmc Collected:
1)ate/'l'irne Received :
Date/Tlme Leached:
Drte/Time Extmcted:
Date/Tlme Analyzed:
Instrument ID:
GW-R4-0?0[0s
p5r0e0r 76-007
HJ8M6
09/08/05 12:40
()9/(t9i05 09:30
09/23105 l5:30
09/27 t01-Q5:35
004
CAS No.Antlyte Conc,IVIDI.,RL a
7 440-43-e Cadnrium 0.00020 0.00020 0-0050 U
7787-49-2 Sclenium 0.0038 0.0()16 0.010 B
STL Denver
D^r.... f l.-nt-.^i^ raa3- lFr-..^r Dr..'i..nlu.J
94
ffiSTt
URS Corporation
I otal Metals Analysis Dsta Sheet
Lab Name:
LotlSDG Nurnber:
Mntrh:
' Molsture:
Ilasis:
Analysis lltethod:
Unit:
QC Batch ID:
Sample Aliquot:
Dllutlon Fector:
STL DENVJR
psjoeOl76
WATER
NiA
YtrI
60I ()B
rn3&
526s237
50 rnL
I
Client Semple I'D:
Lab Sample lD:
Lrb WorkOrder:
Dnte/Tlme Collected:
Dnte/Tirne Receivetl:
Date/Tlme Leached:
Date/Tlme Extracted:
Date/Time Anslyzed:
Instrument ID:
c;w-R3-09f)805
p5r(L?p l.7r,-008
I.IJ8M7
09i08/()5 I4; I I
Q9/09/05 09:30
09/23i05 I5:30
09126t05 22:11
0zI
CAS No.Antl.vte Conc.MDL RL a
74?9-90-s Aluminunr 0.017 0.017 0.r0 U
7440-70-2 Calcium 43 0.034 0.20
743e-89-6 Irt>n 0.14 0.021 0.r0
7 439-95-4 Magnesiurn 46 0.043 0.20
7 440-A9-7 Pota.ssiurn r50 0.24 3.0
7$A-'23-s Sodium 2500 I.I 5.0
1440-67-7 Zirconium 0.0088 ().fi)t 6 0.0t 5 B
STL Denver
Form I Analusi.s l)ata Sheet Eouivalent
95
ffiSTt
IJRS Corporation
Total Metals Analysls Datt Sheet
Lab Narne:
l,oUSDG Numbcr:
Mntrlx:
7o Molsture:
Brsis:
.A.nalysis Method:
Unlt:
QC Batch ID:
Srmple Allquot:
Dilution l'rctor:
STL DENVER
D5t0q0 t 76
WATER
}UA
}yd
60108
mglL
526s?37
50 mL
I
Cllent Sample ID:
Lnh Snmplc [D:
l,ab Workorder:
Date/Time Collected;
Date/Tlme Recelvod:
Dntc/Tlme Leached;
Dste/Tlme Extracted:
Date/Tlme Analyzed:
Instrument ID:
GW-R3-0e0805
p5l09o l 76-00[
HJ8M7
09/08/05 l4:15.
09/09/05 09:30
00123/05.,, [J:30
09128/05 I (): l4
llt6
CAS No.Analyte Conc.MDL RL a
744A48-2 Ansenic 0.01I 0.0044 0.015 B
7444-N-1 Barium 0.72 0,00070 0.0r0
7 444-47 -3 Chrrrmium 0.0026 0.0026 0.0r 0 U
7440-s0-8 Copper 0.0()4s 0.004s 0.010 TJ
7419-92-l Lead 0.0026 0.0026 0.0030 U
7440-A2-A Nickel 0.0031 0.001 2 0.040 B
tMt\-?2-4 Silver 0.0028 0,0028 0^010 U
f+a-az-z Vanadium 0.0027 0.002s 0.0r0 B
744A-66-6 Zinc 0.00s0 0.0045 0.020 B
STL Denver
Fnrm I Ann.htsi.s l)n.la ,\heel F.ouivnlpnt
96
ffisTL
URS Corporation
Totrl Metrls Analysis Drta Sheet
Lrb Name:
LoUSDG Number:
Motrix:
7o Molstrrrc:
Basls:
Andysls Mcthod:
Unit:
QC Brtch rD:
Sample Aliquot:
Dilution Factor:
STL DFNVER
D5t09() 176
wATEII
N,iA
Wst
747tlA
mg'L
szse3J7
I
Client Sample II):
Lab Semple ID:
Lrb Work0rder:
Dnte/Timc Collccted:
Date/Time Received:
Date/Time Lenched:
Date/Tinre Extmcted:
Dste/Tlme Analyzed:
Instnrment ID:
Gw-83-0e080.5
p51090176-008
HJ$Ivl7
09108/05 l4: l5
09/09105 09:30
09/23105 12:50
$9/23ltt5 18:41
019
CAS No.Anulyte Conc.MT}t RL 0
7419-97-6 I\lercury 0.000044 0.000044 0.00020 I.J
STL Denver
Form I Analvsis Data Sheet Eguivalent
97
Lab Name:STL DENVER
I,ot/SDG Irumber: D5I090176
Nlttrix; WATER
'% Molsture: Nl{
Basls: ltg
Analysls Method: 6020
Unit: mg/[,
QC Batch ID: 52651 93
Sample Allquot: 50 nr[-
Dllutlon Factor: 5
ffi$rt
URS Corporation
Total Metals fuirlysls Drta Sheet
Client Srmple ID: SW-R3-090805
Lab Sarnple tD: D51090176-008
Lab \4brk0rtler: HJSIVIT
Date/Time collecred: ()9.108/05 1a:15
Dtte/Tlme Received: $9/09/05 09:30
Date/Tlme Letched:
Drto/.t.irne Errmctcd: 0q/r3l05 IJ;30
Drte/Tlme Analyzed: 09/2205. tlS:38
Instrument ID: qAl
CAS No,Analvte Conc.MDL RL a
7441t43-9 Cudmium 0.00025 0.00020 0.00s0 B
7782-49-2 Selcnium 0.0028 0.0016 0.0r0 B
STL Denver
Fnylm I Anolvsi"c Tlnlo Shept Euuivalenl
9B
STL DENVER
Total Metals Analvsls
-2A-
INMAL A}ID CONTINUING CALIBRA'I'ION YERTI{CATION
Cortract: tlRS CorDoratsion
L&b Cod,r I STITDEN Cage No - r 8lg No. 3
Inttrl.al Callbrat,ioa Source:
Cont,Lnulng Calibration gourco:
Higrh Purity, Spax
fnorgrnLc VenEurGa
$Do No. r D5f090L7 6
ConccutrrrtLoa tlnttr r mg lL
Alurninurn :l
I afuminum :l lo,ol 38.7s1 ge.c I so-o I le.gsl gz.g I I
Analytc
rnieis,l Crlibratioa
Trtre Fcnrnd *R ( 1)
Contslnulng CallbraELon
![rn. Fo.nd %R( 1] Found BR( 1]u
Calcirrm t I
Calcium II I
Iron Lo I
I rron 4i t_ {10.01 39.011 g7.s I so.ol
49.5gl 99.2
0.5111 LOz'.2
de.o6l es.xl I lPl
Potasrir.rm I
I{agrrcelrrrn I
Sod.Lum to I
Sod{um Hi I
ZLrconirrm I
control tirLits r lrlcrourfr BO-LZAr OtherMrEalsg0-110t ClranldaS5-115
50. Lzl 100.2
19. 64 I 98,2
5.061101,2
(1)
STL Denver
tr'orn II (PrrU 1) IN
99
STL DETWER
Cont,ract I IIRS CorlroratLon
Total l\{etals Analvsis
-7,A-
IN ITIAL A}ID C ONTINTIING C ALIBRATIOI{ IIERIFICATIOII{
Caeo No. I Slg No. :
HLSrh Ptrrity, Spax
Inorganio Vanturca
Lrb Codc r SEITDEN
Initsiel Ct1l.braul.on Source:
Continulng Callbration Eourcar
SDGI No.r D5I090L76
Coaccntration Unl,Ut t mgllt
l,lusrinum .l
l,lustinurn :l {8,271 95.5
CalcLrrm H I {9 " tgl 98.4
Iron Lo I
fron Hr, I {9.6{1 97 ,3
leoucsaLunl .. | | I so.ol I I so,os,lr-go.rJel
Magne aiunr J 19.57I 97-8
J soatum r,o I I I I 5.0 I F.oolro:..zl p I
.trnalrt,r
rul.tl.a]. Calibratsion
Trnre Found %R ( 1)
Cont inrrinfr Crlibratiorr
Tmr lround t,It( 1) Found, tR ( 1)}T
lcarctunrl I I I s.ol I I s.ollroo.elpl
Sodium Hf I
zLreoninn I
(1) Control Limiter Marcutlr B0-120, Othsr Mctal;90-1101 CYanida 85-115
STL Denver Form II (Part, 1) - IN
100
STL DENVER
Total Metals Analvsis
-2A-
INMIAI, ANI} CONTINI.iING CALIBRATION VERIFICATION
C@trrot! IIRS Corporetl,on
IJab Codc r $BLDEN Cagc No.3 SLg No. r gDO NO.: D5f090176
Initirl CaLtbraElon Source;
ConELnuinq Crlibrrtlon Souree:
High Purity, Spax
InorganLc VcnEuras
Aluminun :J
n,lrrminum :l
CalcLum t I
Calclum H I
Iron Lo I
Iron H{. I
Potaseiun I
[uqsnql,riqm I I
Concentratsion Unit,g z mg/l'
0.{ggl 99.8
48.531 97 .L
{.811 96 -2
lL7 .L7l 94 .3
0 .4911 98 .2
47 -t1;l 94.2
50.25) 100.5
I I ao.ol I I rs.E3 I gs.z[rl
lnrllrtc
rnLtlal Callbrat,lon
Tnre X'arad %R ( 1)
Continulng Callbratlon
Tnrc Pound %R ( 1) Fgllnd t6R ( 1)u
I soat.rn l,_o I I s.ol I I s.Lzl roz.ilnl
I se4rqq Eil I 50.o l 49.Lal 98.2 I lpl
Ziroonfum I
( 1) Conf,roL r,init,a t MercurT 80-120t Othor Mctal.a 90-110; CtranLde 85-115
o.{85l 97.O
STL Denver Form fI (ParE 1) IN
STL DE\IYER
Contraot r IIRS Corry>orrtLon
Total Metals Analvsirs
-7A-
INTNAL AND CONTINUING CALIBRATION VERIFICATION
Cur No. t AI.EI No. r
tttgh P,r=ity, SIlo _
Inorganle Vanturcla
Lrb Codo I STLTDEDI
Initl,al Ca1l-bratloa Source :
Continuing Call,bratLon Souree :
SDO luo. r DSf 090175
A1urnl"nufil 'l
I e,ruminum :l
ConccnEratlon UrrtEa t ig lr'
Contlnulng CrlLbrution
Trrrr Fotrad e6R ( 1)
I I I so.ol lg.Bsl s7.7I
t6n(1)
99.6 I P
I lPl
InitiaL Cnlt-brlt,:loa
Truc Found tR(l)
Celcium L J
I carcium Ir I
4.741 94,81 p
I I I so.ol lz.egl ss.nl I lBl
Iron Lo I
Iron Hl I
Potnaaium I
I uagrnesiu,n I I I 2o.ot I
0.{891 97.9 I p
19.1{l gs.l JB I
Sod,l,rrm rro I
Sodium III I
Zl,rconium I
Control LLmita: Morourar 80- L2A;Othcr Mctals 90-110, CyanLde 85-115(1)
STL Denver For:ur II (Part, 1) Il{102
STL DENVER
Total Metals Analvsis
-2A-
INITIAL AND CONTIN UING CALIBRATION I'ERIFICATION
Cotrtract t IJRS CorT,oratlou
Lab Code3 gfLDEN Cagc No. r Srg No,:
rnltl.al Calibratsion Eource t
Cont,l"nulng Call-brarion Sourec r
Ht grh Prrri.ty, Spax
Inorganie Venturaa
SDO No.: D5I090L76
Coacrnt,nt:lon ttrrLtr t mg lI'
I er.rq,Lnum .l I ] I o.so I o.Eoel1o1.g I p I
enalyt,o
rnl-t, I.al, Calj.bratl,on
True Found BR ( 1)
ContLnul,ng Crl.l,IrraEion
Tnra Forrnd tR ( 1) Found ,5R ( 1)Irl
A1uml,Bum :l
Calcium Ll
CaLciun H I
Iron lro I
[rroaHi I I I t 50. o I aB. 1zl sG.3 |ll
Potasrt rrm I 50,0 50.661 101.3 P
Mrgrnc;ium J 20.0 19.511 98.0 P
J soatrun Lo I J s.ol I I s.1glro3.6l PI
SodLum ni I
I zirconL.* I
{9 - 611 99 .?
o,sol I I o.{ezl eg.tlpl
(1) Control LintE,s r Mcrcury B0-L20t Othar MaEah 90-110; CyanJ.do 85-115
STL Denver fom II (Part 1) - IN 103
STL DEIVVER
Contrrct t IIRS CorporatrLon
Total Metals Analvsis
-2A-
IN ITIAL AI.ID C ONTINT]ING CALIBRATION VERIFIC A T ION
Caae No, 3 StA No. :
Et-eh Purl-ty, Spax
Inorgrnnio Ycnturc!
Lab Codas STLDEN
InitLrl Ca1t bration Sourcr:
ConuinuLng ce1J-bratioa gorrcc r
gDG NO. : D5I090L7 6
Corrccntrrtion Unit; s mglt
enallrte
Inltial Ca1Lbratrlon
Tnre found tR ( 1)
Contlnulug CaLLbratl,on
Tnr€t Found esR ( 1) E'ound tR ( 1)tri
Alum,lnurn I 0.257 1102.8
CaleLum t I 1. gg I 99.0
Iron Lo I 0.250 I100.0
leotrsr,i.unl zo.ol zo.rglror.ol I | | l- lplItqgnegiultl ro.ol g.rg I gl.g | ... l._ .- . -_.j . I I Le IIsoai.-tr,oJ a-ol z.otlrol.sl lnl
lziroonrr:nl o.zsl o.zlzlgo.sl I | | I lel
(1) Control l,imLtg r Mereurlr 80- 120;Othcr Motalg 90-1101 Cy'anide 85-115
STL Denver
Forxr II (Part, t) IN
104
STL DENVER
Total Metals Analysis
_2A_
INITIAL AND CONTINT]ING CALIBRATION VERIFICATION
Cotrcott tlRS CorDontlon
LaL Codrs STLDEN Catc No. r SAS No.:
Initl.al CalLbration gouroe s
ConEl"uulng Calibratl.on Souret :
Htgh PrrrLuy, Bpex
InorganLc Vraturog
sDg NO. r D5IO90L7 6
Conscntratlon [Inltsg t mg/L
Analrtr
IniE{a1 CalLbratsion
Tnrc Found e6R ( 1)
Cont lnrrlng Cel'l.bratLon
Trrre Forrnd tR ( 1) Found e6R ( 1)M
lcarcru{nr.l -l I I s.ol .. | | s.oglroo.elpl
I carcruq sl lo.ol -. lo.rs lroo.l I so.o J so.gol roo.r I I I p I[rotanaiu:nl I I I so.o l I I so.4alro1.o I p I
ls.,arqLrol I I s.o I s-ozl rot.c I p I
Sodl.um lri I
( f ) eonEroL r.{ ni gg 3 MarcurT 80-1201 Othcr lrlrt,a1s 90-110r CYanidc 85-115
STL Denver Forn If (Part 1) IN
105
STLDENVER
Contract: IIES Cor?oratLon
Totsl Metals Anslysis
-2A,-
INITIAL AND CONTINTIING CALIBRATION 1IBRIFICATION
Caec No.:gl,S No. t
Htgrh Purl,ty, SDcx
fnorganLc Vcnturco
LrI, Coda r STLDEN
lnitirL celibration Sourcrr
ContLnul.ng CalLbrrt j,on Sourcc:
sDc No.: D5f090176
Concentration Unita r mglr.
CalcLusr t I
CalcLurn II I {9. {91 99 - 0
lporaarlunl I I I so.ol I I so.lslror.qlrl
Sod.Lum Lo I
Sodi.um Hi I
Control Llnltti lirorcrrrtr 80-1201 Othrr Uetals 90-1101 Cyaaide 85-115
5.0{1100.8 I p
(1)
Nnal.ltc
ruLtial Calibration
Trrrc Found e6R ( 1)
Cont, inuLng Caltbratrion
Trrra Found %R ( 1) Found ,6R ( 1)Dt
STL Denver
Fom II (Part 1) IN
105
STL DENVER
Total Metds Analvsis
-2A-
INMIAL AND CONTINUING CAL}BRATIO]Y VERTTICATION
CoDtrrotr t RS eorDorrt:Lot
tab code3 STLDEN Cage No.:gfg No. r
Inittal CalLbration Sourscs
ContrLnul,ng Ca1ibration Eourec:
Hlgh PurLty, SDox
Inorglnie Vanturas
D5r09017 6
ConocntratLon IDTLEg I mgll,
lnalf'tr
InJ,tJ.aI Calibrat,Loa
Bmc Found tR(l)
Cont:Lnulnn Crl.i.bratl,on
Trtrc lr.ound erR ( 1) Found tR ( 1)M
CalcLum L l
Calel,un H
I roter;irurr I
5.0 5 .35 LA7 ,2
50.0 5{, 22} 109, {
I I I so.ol I I sr.sslroz.zlpl
Sodlun r,o I
I soafur* Hr J ll 5.0
so.o I s1.z5l 103.EI
5.17 I 103. {
lpl
( 1) ConLroI LLurlEs:Mareury 80-1?01 OEhu Mrtels 90-I10t CYanlde 85-115
STL Denver
Fomr rI (Part 1) IN
107
STL DENVER
Contrasts r URS Corporatl-on
Total Metals Analysis
-24-
INITIAL AND CONTINUING CALIBRATION VERI}'ICATION
Crrr No- r 8lg No. r
Etgrh prrrltv, Spcx
InorganLe venturea
Leb Codc I BTITDEN
fnit,ial Crll,bration Bource :
Continulng CalLbration Sorrroe r
sDG No. r D5f 090176
Conecntnt,l.on UnLtr r urgl['
I Cl.f ciurn r, I I
lnalytc
lnLtial Cal-ibrrtl,on
frrrc found e6R ( 1)
Cout,Luuing CaLibration
Trnrc Found tR ( 1) tround %R ( 1)u
5,01 s.33 lro6.6l p I
I cerciurn H I 50.0 I s{. s01 109,0 I I lpl
PotBtniurn
Sodl,urn fro J
$odLum IIf I
( 1) Control Liulta r Mercury 80-1201 Othor Dlrtals 90-110; Clzanldc 85-115
51 .12 I LAz.2 I p
5. 13 I 102.6 I P
STL Denver
Forrn II (Part 1) a IN 108
STL DETWER
Total Metals Analysis
INITIAL AND CON'flNUING CALIBRATION VERIFICATION
Coatract! IIRS Corgoration
r.rb Codc r STITDBN Casa gfg No- r
InLtiaI Calibrat,lon Source :
Cont,lnulng CalibntLou Bouree :
Eigh Purlty, Spax
Inorgtnl,c VsntUrSS
Dsr090L7 6
I careitm r, I 2.01
Cooccntratl.on unLEg t rrglt
a.oolroo.ol I I I I
fnrJ.yte
fnieial Crll-bnulon
Trrre f,ound e6R ( 1)
Contlnulng CalLlrratlon
Tnrr Pound e6R ( 1) Found e6R ( 1)!r
[.lotrraium I zo. ol eo.lolroo.sl I I I I lrlls"ar'r,rrcl z.ol ..z.orlroo.sl I I I I lpJ
( 1) ControL LJ.ruits:Meroury 80-1201 Other Meta1t 90-110, Wenide 85-115
STL Denver
Fom II (Part 1) IN
109
STL DENVER
Contract r
I,ab Code:
Total Metals Analvsis
-2A.-
INITIAI, AND CONTINUING CAI,IBRATION VERIFICATION
URS Cor:Doratl-oa
STLDEN Caga No. r gA^8 No.:SDO N0. r D5I09OL76
Inl,t,l,al Crlibrrrtlon Bourco :
Contlnuing CalibratLon Sourcc:
Iaorganio Vanturca
HLgh PrrrLty, Spex
ConccnEratLon UnLcr t urg/L
Analytr
Initiu,l Calibration
Trnrc Eorrnd e5R ( 1)
ContLnu{ng Crl.LbrutLoa
Tnrc Eound e6R ( 1) Found t6R ( 1)lrl
Areenic I 0 .2{3 I 97 .2 0.9931 99,3 0.997 I 99,7
I narium I o .2sl o .25{ 1101. 6 I 0.501 0.502110x.{l o,s11lLaz-llpl
Chrorntum I a.2451 98.{0.5041 100.8 0. {99 I 99.8
o,2{I5 I gg.0 0.5001 100.0 0.5051 101.o I P
Lrea,dt I 0.24,4 I 97.6 0.5021 100.4 0,5011 100.2 I p
I wterer I o.2sl o.z4s I sg.o I o.so I o.sozl 101.t I o.sool ror.a I p I
Eil.var I 0.2{1 I 96.4
l_qanadtqq I o. zsl o.?4gl gg.2 I
0.{931 98.6 0.{921 98.{ I P
o.so I o.sotl 1oo.B l o,so1J1oo.z I p I
Jzinc J o.zsl o .2{o I 95.0 I o,50 I o.so3l 1oo,dl o,5ool1oo.o I p I
( 1) Control rirrits :Mereur^y 80-120;Other Mctal; 90-1101 C1'anLde 85-115
STL Denver Form II (Part 1) IN 110
STL DENVER
Total Metals Analvsis
-24-
INITIAL AN D CONTINUTNG CALIBRATION YERITICATION
IIRS Corporation
STTDEN Cage No.3 g}.9 DIo. 3 SDe LIO.s D5I090175
Coatrrct r
Lab Codc:
fnl,tial CalibrntLon Sourcc r
Cont,l.nulng Calibration Souroe r
fnorgrenic Vcnturct
High Ptrrity, Spax
ConccntratLon UnLEE : mg lL
lnal1t,t
fnitirl CrlLbretlon
Truc Found tR (1)
ContJ.nulng Ca].l.bratLon
|[nrc Found tsR ( 1) Found eER ( 1)M
Jlrconic I 1.0531 105 .3 1.0t51 10{,5 I P
BarLum I
I cnromium I
0.5171 103 . {0.5111 102 -2 I P
I I I o.sol o.srol1o3.zl o.srslros.olpl
J coppcr I I I 1 o.sol o.sarl105-21 o.szslros.elpl
lLcaa. I ,L I I o.sol o.srslror.ol o.srslroz.olT_l
lurcrer I I | | g.sql ,, ,o.qr?lrqr.ol o-sralroz.llel
lsttver I I I J o. s0 I o. so{l r00 .8 I o.sot I 1oo. B I r I
venadirrrn I
lzine I I o.50 I
0.5211 LOI.2 0.521 I 10{ .2 I P
o.52ol 105.21 o.so{[1oo.B I p I
( 1) Control -LlnLts I Mercury 80-120; Other Mctal;90-110, cyarrlde 8s-115
STL Denver
Forgm II (Pert, 1) IN 111
STL DET\TVER
Cont,nct r
Lrb Cod,c r
lnltLal CalibnElon Source:
Contiauing Call"bratioa Sourcrr
Total Metals Analvsis
-2A-
INITIAL AND CONTINTIING CALIBRATION VERII'ICATION
IIRS Corporat,Lon
STIJIEN Caaa No. t Sl8 I[o. r
Iaororanic Vanturag
BDO NO,r D5I090175
High Prrrity, Spcx
Arsenic I
Bariun I
Chrqniurn I
coppar I
Irord I
Ni-chcl I
SLlwer I
I venndLum I I
Concentrrt,Lon Unl,ta t mg lt
I I o.sol
1. 05{l 105. {1.050 I 105.0
0.5161 103 .2 0.50,0 1100.8
0.5191 103.8 0 . 5{11 108 .2
0.5351 107.0 0.5101 102.0 I P
0,5191 103.8 0.528 I 105. 6
0.5171 103 .4 0.5351 107.0
0.5081 101. 6 0.5L21ta2.$
o.szsl to5-oI o.537l,La7.i I r
Anllyta
rnl-Eia1 CalibratLon
Trnre round tR ( 1)
Cont:Lnulng CaI" J.brat l,ou
Trnrc Found e6R ( 1) Pound %R ( 1)Ir!
J ztnc I I o.sol 0.51?l 103.{ I 0.5a7l1o9-t I p I
(1) ControL Lfunits r l,tmcury 80-1201 Other Mctalr 90-110, CYarldc 85-115
STL Denver
Form II (Part 1) IN
1,72
STL DENYER
Totnl Metrls Analvsis
-2L-
INITIAL AND CONTINUING CAI,IBRATION }'ERIFICATION
ConLract: IIREI CorDgratlon
Lab Codai gTtDEN Carc No. 1
NIST
SAg No. I
fnitial Ca].lbration Sourca;
ContLnuing CrlLbrlrtLon Eourccr U1tra Scl,cntLfLe
SDs NO. r D5I090175
Coucrntrrt:lon t]nJ.tg'- mg lL
Ana1.yta
-nitial CalJ.bratl-on
Trnrc round l6R ( 1)
Coatinuing Calibration
Tnre Found %R ( 1) I!'ound e6R ( 1)}T
I uarcurv I o.ooarzzl o.oozrze lroo.o I o.oosooo I o.oolgogl ga.z I o.oosolsl ror-o lcvl
(t) Cont,rol Llmitg:Dloreury 80-120; Other Mrta1g 90-110, Cyanide 85-115
STL Denver Fciur II (Pert 1) IN 113
STL DENVER
contraet: URs cor-goratLon
Total Metals Annlvsis
_2A_
IN ITIAL AT,{D CON T TN UIN G CALIBRAT ION Vf, RIFICATION
Case No-:
NTST
g.Lg Bro. :
Ultra Scientific
f,ab Cod,c: STLDEN
fnitirl CrlLbratl-oa Soureo:
Continuiagr CalLbratsl.on Source :
SIXI NO, r D5f 090176
I t'tcrcury
ConocnBratl,on Unitg : fig lL
I I I o.oorooo I o.oolgzsl gg-s I o.oosozsl roo.s lcvl
ArralyEe
rnLti,e]. CalLbratLon
Tnrc Found tR ( 1)
Continuing Calibration
Tnn Found reR ( 1) Found %R ( 1)Dl
(1)Control t i-rnitc:Mercury 80-1201 Othar Mota1g 90-110; Cyantde 85-115
STL Denver Forn II (Part 1) IN 774
STL DENVER
Total Metals Analvsis
aA-
INI'TIAL AND CONTINUINC CALIBRATION VERIFICATION
Coatract: LrRg CorA)oration
Lab Codc3 gTt DEN Cllc No, t SIS No. r D5r090L7 6
rnl"tl.al CalibrrtLon Source :
Contlnul,ng Call.bntion gourcc:Ultra ScLentiftc
NIST
ConcorrtratLon Un:LEr: ng ll,
.Lrrr16a
rnLtlal Callbration
Trrre Fcnrnd esn ( 1)
Cont,l-nulng Crlibrrtsion
Trrra Forrnd e5R ( 1) round t6R ( 1 )u
0.005000 0 .00517 103,{
( 1) ConEroI r,Lnit g r Mereury 80*LZAt Other tdetals 90-1101 CYunidc 85-115
0,0051{3 102. 9 cv
STL Denver Foru II (Part 1} IN 115
STL DENVER
ConEract: IIRS Coraloratl,on
Total Metals Analvsis
-2A.
tN ITIAL AI.{D CONTINUING CALIBRATION VERIFICATION
Crrc No. r SAS No. l
High hrrl,ty
Inorganlc Vanturcs
Lrab Cod,c: gfIrDEN
rultlll. CalibratLon Boursc r
Continuing Ca1LbraBion Sorrrcc r
sDs No. r D5I090176
Concantratsion uniug z mglL
J caamium o. o{ol o. o{13 1103.2 I o, o5o I o, osoil roo .z I o. o5oo I roo. o I u I
lnaLyta
Initl.a]- Ca1l"braEion
True Found tR ( 1)
Cont,inuing CrlLbration
Tnrc f,'ound tR ( 1) Fouad tR ( 1)t{
Scl'cniurn I o.0401 1100.2
(1) Control Linita:Mercury 80-L2O; Othcr Matals 90-110; CYanlde 85-115
0. 0495 I 99 .0
STL Denver Forn II (Part 1) rN 116
STL DENVER
Total Metals Analvsis
-2;^-
INITIAL AND CONTINUING CALIBRATION YERIFICATION
contrf,ctr IIRS Corporrtl,oa
Lab eodas STtDEN Cage No, r A.LS No.:
Init,la1 cellbrat ion Source :
Contl-nuiag Cal'ibratLon Souroc r
Htgb Prrrity
rnorgranLc VonturGs
D5rO90L7 6
Conccntratioa urrlta t rrgll
rnallrt,c
tnitiat calibntLon
Tnrr r(}und aR ( t )
Coubinulng Calibration
Tnre round ta ( 1 ) Found e6R ( 1)u
Cadmium I 0. 050 0.05011 100.2 I 0.0512 I r02.4 I u
lsercnrupl l. ,l I o.osol q,osoolroo.ol o.ongzl gg.llul
(1) coDtror Linitg: u.rcury 80-120; otbor llctalr 90-110r cyrnidc g5-115
STL DCNVCT forur II ( ParE 1) IN
1,L7
STL DENYER
Contract 3 IIRS Corlpration
Total Metals Analvsis
-2A-
INITIAL AI{T} CONTIN UING CALIBRATIOI{ VE,RIFICATION
Cagc No. t gAg No. r
IlLgh Purl,ty
Inorganl,c Venturcr
Lib Code : STIJDEN
Ini.tia1 calLbratl,ou Source :
Contl-nuing Call,bratLon Sourcc :
BDO NO. r D5I090L76
Concrnt,ratlon Unitr z mg lt'
.ana1ytsr
Inieirl. Calibration
Trnre Found 1,g(l)
Cont,Lrru:Lug Cal. J"bratlon
lfnra Found %R ( 1) forrnd t6R ( 1)u
Cadmiun
Sa}onirrm I
(1) Control l,lnltsr Mcrcury 80-120; Othor llrbals 90-110r CYanidc 85-115
0.0500
0. 0508
STL Denver Fonn II (Part 1) IN 118
STL DENVER
Total Metals Analvsis
-2A-
IN ITIAL AND CONTINUING CALIBRATION \IERIF'ICATION
Contraets IIRS Corpont:lon
Lab Codc: gfLDEN Casc SnS tilo. :
fnl.tlal CeLibratl.on Source :
Cont,Lnul,ng Call,bratLon gourcG r
Hlgrh Purlty
Inorganlc Vontur.g
sDs No. r D5I090176
ConcerrtrrtsLon UnLt,a r &gll.
lceaniur I I I I o.osol o.olasl go.e I lul
lnrLyta
rnl-eLn]' Callbration
'[rnrt Forrnd t6R ( 1)
Continulng Callbratlon
Truc fqrutd tR ( 1 ) round e6R ( 1)u
I serenium I tl I o. oso I o. os13l 102.5 I lul
( 1) ConEroI Liruitr I Dlercurlr 80-1201 Othar Mctal; 90-1101 Crranido 85-115
STL Denver Polm II tPrrt 1) M 119
STL DENVER
Contract: [IRS Corpor6tion
Total Metals Analvsis
-2L-
TNITIAL AI{D CONTINUNG CALTBRATION VERIF.ICATIOT'i
Caac No.:8Ag No. :
Higrh PurLty
Inorgrnio VcnturGa
ralc Code : STITDEN
Initilr1 ca].Lbration Eourocr
ContLnuing crU.bratsion Eouroc:
gDO NO, : D5I090175
Concentration UnLtt r figlt
.Lrralyt,a
lnitiel CallbraBLon
Trnrc Found e6R ( 1)
Contlnulng Ca1l,bratrion
Tnre Found, e6R ( 1) Found eGR ( 1)!d
Ca&nl-rrrr 0.0{11 l10z . I 0.0{951 gg ,0 0.05021 ro0 -{
I s.trnLurn o.olol 0.o3egl gg.sl o.osol o.olgol gs.zl o.osrzlros.llul
(1)Control LLnttg:Mcrcurl' 80-120r Othcr ltlatalg 90-11O; CtranLde 85-115
STL Denver Forn Ir (Pert t) fN 724
STL DEIVT/ER
Total Metals Analvsis
-2A-
IMTIAL AFID CONTINUING CALIBRATION VERIFICATION
cotrtract,r lrRsl corDoratlon
Llb Codas gfLDEN crso No. r SnS No, t
rnl-tLal Call,bration Bouree r
ConEinuing Calibratlon Soursc r
Htgh PurLty
Inorganlc VenturG;
sDc No. : DSf 090L7 6
ConcentratLon tfnitg ; ng I l,
lrraLytc
Inirla1 Calibntlon
rnre Found tR ( 1)
Cont:Lnulag Call,bration
Btrra Found, %R ( 1 ) Fglrnd eria' ( 1)M
Cadmlrrm
Solanl,um I 0 .0502
Control tlnttr: McrcuRI 80-1201 Othor &Iota1a 90-110, Wanidr 85-115
0.0503
o. 0502
(1)
STL Denver
Form II (Part 1) ffi
a21
STL DEIVVER
eontrEct r [IRg corporation
Total Metals Annlvsis
-2A_
INITIAL ATID CONTII{UING CALIBRATION VERIFICATION
Caac No.:8Ag No.:
nigh Purlty
Inorganic VcntutrGo
Lab COdg: STIJ}EN
InLtial Crli.bratLon Elource :
ContsinuLng CalLbration Souree :
gDc No. : D5f 090L76
Concentntlon Unitt t urglt,,
AnaIt&c
rnl,tl,el Callbrabion
Triuc Fotrnd 96n ( l )
ConElnulng crlt bratlon
Trrro Found tR ( 1) Pound tR ( 1)Dt
Cadmium I 0.050 100.8 I 0.0504
[__salqu-!qm I I I I o,oso!c,..oso{l 1oo.Bl o,odgal gs.6Jrul
(1) Control Llnitsr M.rsury 80-1201 Othrr }Ietals 90-110; Ctranlda 85-115
STL Denver Formr II (Part 1) IN 722
STL DENVER
Total Metnls Analvsis
_2B.-
CRDL STANDARD TOR AA AND ICP
Contraet: IIRS Cor:poratLon
Lrb Code: STTDEN
AA CRDL Standard Souree:
ICP CRDfJ SErndard Eorrrcc r
Crrc No. t S.LSI No.:sDo No. r D5I090175
InorganLc Venturcr
ConecnErrt,lon tlnltg = mglt'
CRDIr Standrrd for IeP
rnl-tLa1 fl.arl
Trrrc Found tR Found
CRDL Etrndard for r.A
trnrc Fotrnd tR
lalumiaunl I I ll o.rol 0.1131 ur.ol I I
CalcLum Ir l g I 114.5
Iron Iro I 0.03{o I 113.3
Potacrl"unf
Mrgr:ncrlun I
Sod,tum Lo I
1.14 I I].d.0
0.192 I 95.0
L.L2} LLz.A
lztrcoaiuml I I ll o.oorl o.oosel116.0l I I
STL Denver Forrr If (Part,2l fN
!23
STL,DETW'ER
Total Metals Analysis
-7D.-
CRDL STANDARD FORAAAI\ID ICP
Contnct r IIRS CorT>oration
tAb COdO r STIJDEN
}} CRDI, Standard Souroc g
feP CRDIr sltandrrd Source :
Crr ![o. t Sl'g No. :8DO No. r D5IO9OL76
rnorganlc Vcntures
Concantration unLt,a t mglr'
CaLcLun L I
Arra]-lrbcl
CRDL Stendrrd for nn
Trnrc tround
gRDIr Standard tor ICP
rnitLrl FLnal
Tnre Found, :t,R Found
0.20 0.197 gg.5
Potaert-um I
SodLurr lre I
1,0
1.0
1.01 101. 0
1 .02 102 .0
STL Denver Fom II (Part 2) IN
724
STL DETYI/ER
Total Metals Analvsis
-2U--
CRDL STA}IDARD F'OR AA AND ICP
Contracts r
f-,ab Code :
IIRS CorporatLon
Carr No, t SDG No, : D5I0901,7 6STI,DEN
Al CRDIJ SEendard Sorrroc r
reP CRDL Btsand.ard Souroo:
AASI No. :
Eigh PurLty, BDcx, IaorganLe vcnturoa
CADIr Stand,ard for ICP
rulti.a1 Fl-na]'
Trtre Dotrnd %R Found e5R
CRDL Etand.ard for ^}f,
Tnre Found, tR
.l,racnLc I
ConcrntraE:Lon Unit s : ng lL
o. o10 0.0082 I 82.0
BarLum I 0.0050 o . 005111 Laz .2
Chrourium I 0.010 0.0110 I 110.0
Coppcr I 0-010 0.0114 1 11{,0
I utcter I
0.0030 0,002151 7? .A
I I I I o.olol o.orosl los.ol I
Stlvar I 0.010 0.00971 97.0
Vanadiun I 0.010 0.0113 I 113.0
lzrnc | | J - lI o.ozol_ o.ozszlrzo.ol I I
STL Denver Form II (Part 2 ) IN
a25
STL DEIYVER
Total Metals Analvsis
-2B.-
CRI}L STAI{DARD F'OR AA AND ICP
Contnct r (IRS Corpontl,ou
trb Code : STITDEN
tr. CRDL Ebandard 9ourco:
ICP CRD[, Standard Sourcc r
Caaa No.:
Ultra SclcntLfLo
gl"g No. t sDG No. : D5I090L7 6
CoaccntratLon Unit; r rrgll.l
CRDL AErndard for LL CRDII gtendard for ICP
raitirl rLnrl
Trnre Found tR trorrnd, tR
Mercury I o. ooo2oo 0.00017 gg.0
STL Denver Form II (Part 2l fN
1,26
STL DENVER
Total Metals Analvsis
-2:B-
CRDL STANDARD [.OR AA AI.[D ICP
Contrrct r IIRS Corgoretion
Irab Code i STIrDEII
Af CRDL Standrrd Slourcc:
ICP CRDL Strndard, Slource:
Cagc No. :g.l'$ LIo. t gDO No. r D5I0901,7 6
Inorga'll,c Vanturel
Conccntrratlon UnLtg : W lL
CRDL Etandard. for ICP
rnltLr]. fLnal
I.ound tR found
CRDII St,andard for rA
Trrrc Found tR
Jcadnt.up I I I ll o.oolol o.0g1ogl 100...0.L. I ISclonium I 0.0010 0.000911 91.0
STL Denver Form II (Part 2, M a27
STL DEIVVER
Total Mettls Analvsls
_2:B_
CRDL STAI\DARD FOR AA AND ICP
Coatraet: IIRS CorporatrLon
f,ab Code : SfITDEN
lI CRDIr Standrrd Sourcc:
fCP CRDL Standard Eourerr
Care No. t S.LA lfo. :gDC No,: D5f090176
Inorganl,c Ventsuroa
Conccntntl.on Unl.ta t \gllr
CnDrr Etandard for ICP
rnLt,i.al Fl-na1
I:nrc Found rsn Found %R
CRDIr Btrndard for .[.L
Trrra tr.ound BB
J eramtum I I ll o.oolol o.ooroolroo.ol I I
Salanium I 0,00088 1 88.0
STL Denver Forut If (Prrt 2l - IN 1,28
ffisrr
IIRS Corporation
Totd Metals Analysis Data Sheet
Lab Name:
LoUSDG Number:
Mrtrlx:
o/o lllolsture:
Basls:
Anrly.rls Mcthod:
Unlt:
QC Batch I D;
Sample Aliquot:
Dllution Factor:
STL DENVER,
psrqgo r 76
WATER
YEt
60r0rr
MEIL
5265237
50 mL
I
Cllent Sample ID:
Lab Srnople ID:
Lab lVorkorder:
DatelTtme Collectedr
Date/Time Received:
Date/Tlme Leached:
Dste/Tlmc Extncted;
Dnte/Tlme Analyzed:
Instrument ID:
D5t220000-2378
I-IK5MA
09/23105 l5:30
09/16/05 20:58
0zt
CAS No.Analyte Conc.MDI,Rt a
7429-e0-5 .Alunrinurrr 0.0r 7 0.017 0.r0 U
7439-89-6 Iron 0.02 r 0.02 t 0.t0 IJ
7439-95-4 Magnesiurrr 0.043 0.043 0.20 U
7440-a9-7 Potassiun 0.24 L\.74 3.0 L'
7440-21-5 Sodiurn l.l I.l s.0 TJ
7440-67-7 Zirconium r).00 I6 0.00 r 6 0.01s U
t 440-70-2 Calcium 0.034 0.034 0.20 U
STL Denver
Form i Prep Blank Equivalent
ffi$Tr
IJRS Corpontion
'fotal Metals Analysis Data Sheet
Lab Name: STL DENVER Cllent Sample ID:
Lot/SDG Numbcr: D51090176 Lab Stmplc ID: DS1220000-237B
Matrlx: WA'IER Lob Work0rder: HK5MA
7o Moisture: DetdTlme Collec{ed:
BasIs: W91 Datc/Tlme Rccelved:
Analyrsis Method: 60.108 Date/Tlmclerched:
Untt: mg/L Date/Time Ertracted: A9123i05 15:,30
QC Bntch lD: 5265237 Date/Tlme Analyz.ed: 0928/05 07:59
Srmple Allquot: 50 mL Instrumcnt ID: 016
Dllutlon f'rctor: I
CAS No.Analyte Conc.MDL RL a
744(r--r8-2 Arscnic 0.00.{4 0.0044 0.015 U
7439-92-r Leatl 0.0026 0.0026 0.0030 U
7440-3e-3 Barium 0.00070 0,00070 0.010 IJ
7444-02-0 Nickel 0.0012 0.0012 0.040 LI
744A-?24 Silver 0.0028 0.0028 0.0r0 LI
7440-62-2 Vanudium 0.002s 0.0025 t).0 I t)U
7440-66-6 Zinc 0.004s 0.004s 0.020 U
Wqo-qt-t Chromiulrr 0.0026 0.0026 0.010 t,
7440-50-8 Copper 0.0045 0.004s 0.0r 0 U
STL Denver
Form 3 hep Blank Eouivalent
130
Lab Nsme:STL DENVER
Lot/SDG Number: f)5l0q0176
Mntrix: WATER
7o Molsture:
Brsls: Wet
Analysis Method: 7+7.0A
UnIt: mg&
QC Bntch IIi: 5/12437-
Sample Aliquot:
Dllution Factor: I
ffisrt
URS Corporatlon
Total lWetals Analysis Datn Sheet
Cllent Sample ID:
Lab Srmple ID: Dsl 160000-4378
Lab tilorkorder: HKVPA
Dute/Tlme Collected:
Drte/Time Recelved:
DatelTlme Leschcd:
DmelTime Ertructed: 09/23i05 l2:50
Drte/Tlmc Analyzed: 09/2-]/05 18:06
Instrument lD: 019
CAS No,Analyte Conc.MDL RL a
7439-9-7 -6 Ivtercury 0.000044 0.000044 0,00020 U
STL Denver
Form 3 Prep Blank Equivalent
131
ffi$Tt
IIR^S Corporetion
Total Metnls Anrlyuis Data Sheet
Lab Ntme:
LoUSDG Number:
Matrlx;
'% Molsture:
Basls:
Analysls lllethod:
Unlt:
QC Batch ll):
Snmple Aliquot:
Illlutlon Factor:
STL DENVER
D51090r 76
WATER
Uet
(r020
ilrg/L
s}(t1193
50 rnl
I
Cllent Sarnple ID:
Lrb Sample ID:
Lab Work0rder:
Date/Tlme Collected:
Drte/Time Recelvetl:
Date/Tlme Lenched:
Date/Tlme Extracted:
Drte/Tlme Analyzed:
Instrument ID:
p.sl2?0000-_t 938
HK5F2
091't/05 I 5:30
09/27105 t9.a4
004
CAS No.Annlyte Conc.MDL RI,a
77824e-2 Selenium 0.00033 0,00033 0.0020 U
744043-9 Codrnium 0_000040 0.000040 0.00 r 0 U
STL Denver
Form 3 Prep Blanh Equivabnt
132
STL DEA{VER
Total Metals Analvsis
-3-
BI-ANKS
Contrreu r IIRS Corporation
LEb codc g STIJDEDI
Praparatlon BIanft
PrcparatLon Blauk
Cage No. r
ue,trLx ( toL]../watser) :
ConeentntLon Unitg (nglr, or nglkg) t
gfS No,3
T{},TER
YlglT'
Prcparation
BLarrk
Inltiel
Ct1Lb,
BIank
(ng/r,)
Cont inulng Crll,brrElon
BkrrIE (ngllr)
Dsr O9 017 6
133
Llwnl-rrum f,.ro I 0 .017
Calcir:m r,o 0.052
fron IJo 0. o21
Potegaium 0 .2{
MagnegLum 0 ,043
god,ium Lo 0,032
ziroonl-urn 0.00160
0 .01.7
0. o3l
o,o21
0.2{
0.043
0.031
0 .00150
0.017
0. 03{
o -azl
a .24
0.0{3
0.082
0.00150
0.017
0.03{
a.ozl
a.2l
0.0{3
0 .197
0.001 60
STL Denver Form III - IN
STL DENVER
Total Metals Analvsis
J.
BLANKS
Contsraet r
Irrh Codg:
IIRS Corporetion
Cuc No-:gl.8 No. :sDC NO.: D5I090176STITDITN
Pregaration BlarrIE
PraparetsLon Bhnh
Matrrlx (eotl/water) r WATER
ConcrnEraEion Unl.te (nglL or roglkg) ;ytc/L
rnl.tial
CalLb.
BIaDIE
(roglt l
contsinulng CallbratLou
B1ank (nlgll,l
lczc3c
AlumLnurn Lo I
CalcLum L,o
Irorr Lo
PotaeaLum
MagncaLurn
Bodirrrn fJo
Ziroonirrm
a.aL7
0.03{
0. 021
0 .2{
0.043
0.106
0.00150
STL Denver EoTM III IN
134
STL DENVER
Total Metnls Analysis
-3-
BLANKS
ContraeE:
I.ab Code r
Prcparation
Prcparation
t RS Corporrtl.on
STITDEN Crarr No. r
Blank tiletrdx (soil/watcr) :
Blank Conoantration Unl-ts
glfl No. r gDc Blo- : D5I090176
(ng/L or nglkg) :f,l0lL
Ana1y't,t
rnltl.al
Ce1lb.
B].enIR
(w/1,'t
c
Cont,l,nulng Callbrat ioa
BIBnk 6g l[r)
L c 2 e 3 e
PreDar"aroo
Blrrr r
c !f
Crlciurn Lo
Potr""frrnffi
0..-5l4lu
0 .241 u
0.0311 U
o.o3{lul ... 0.034 Iul o,o3{lu
0 ,2{ l u,l. 0 .24 lu l , ,_.__ 0 .2{ l u
O.03LlUl 0,039181 0.0311U
P
P
;
STL Denver
EoTm III, - IN
135
STL DEIVI,'ER
ConEract; [IR.S Corporatl,on
Total Metals Analysis
-3-
BLANKS
Lab Codcr
Preprrrtl,on
Prcparation
Carr No. I
MatrLx ( rol1./watser) :
Concentratsion Unit;
STI,DIBN Ang No. r sDo No. r D5I090175
BIerrh
BLanIE
u[[lrER
(mg/f, or mg/kg) :![G/I,
Praparat{on
BIa.nh
rnl"t lal
Call.b.
BIash
(mn/L)
Contlnulng Calibration
B1ank (ns/L)
ArrcnLc
BarLum
Chroml,urn
CopDer
Leed
Nickcl
Silver
Vanadirrm
Zinc
0 .00{4 0 .0044
0.00070 0.00070
0.00260 0.00260
o - 0045 0.00{5
o.oa26 0.0426
0.04L2 0 ,0012
0,00280 0.00280
0.0025 0,0025
0.00{5 0.00d5
0,00{{
0.00070
0.00260
0.0045
0.0026
0.0012
0,00280
0.0025
o. o0{5
0.0044
0.00070
0.00260
0.0045
0.0025
0 .0012
0.00290
0,0025
0.0O{ts
0 .00{{
0 .0007 0
o,0026
0. oo{5
0. oo25
0.0012
0.0028
o.0425
o. oo45
STL Denver ForN III TN
135
STL DENVER
Total Metals Analvsis
-3-
BLANKS
Cont,nct r
Lab codcr
IrRg Corporatlon
STLDIEN Cago No. :8Ag No. r SDO NO. r D5f090176
Properatl,on Bl'arrh DtaErl-x (soll/water) t WATBR
PrnparaEl,on B1enk ConccnEration Units (rng/[, or mg/kg] I MG/L
Initl,aI
Cal.l,b.
Bhnl(
(mg lt l
Conts lnulng CaI J,bratl.on
Bhnk (utg/L)PreDarabion
BIank
Lrsonl,c
Barium
C'Irromiunr
Copper
Niokal,
Si]'rrcr
Vanad.Lum
0.00{4
0.00070
0.00260
0.0045
0 . 0026
o.00L2
0.00?go
0.0025
0.0045
0. 00{E
0.00070
0.00260
0. o0{5
0 , 0026
o.0012
0.oo280
0 . 0025
0.0045
STL Denver Eom III IN
L37
STL DENVER
Total Metals Analysis
-3-
BLAI{KS
Contract:
Lrb Code:
Pre;>aretLon
PrparatLon
IIRS Corryrcntl.on
8TI,,DEN Crac No. t
Blank t{etrl,x (soll/water} r
B].enh Conccntratios Unl,C;
gn^8 No. r sDo NO. r D5f090176
(mgl[' or W/Isg) :MG/I,
Ana]'lrt,e
lnLttal
Caltb,
Bhdr
(ngtr,,c
ContLnulng Cal J.bratLon
BlanIG (nglt)
I c Z tC C
PrcprntLon
BIank
c ![
llcroury |O.O0OO{9 I BI -0.000052 lB I -o.ooo0sl- I B CV
STL Denver FoTm III IN 139
_)
STL DENVER
Total Metals Analysts
-3-
BLAI!$KS
Coatreet r
f,ab Coda:
PrcDaration
Prcpuatlon
IIBS Corlroratl.on
gfIrDEN Crse Dilo - t
gl.anlE Matrj.x ( goLl /vatcr ) r
B1ank Conccntratlon Unitr
gAS llo. I SDo NO. t D5I09OL76
UTATER
(msll, or Bg/kg) r ![G/I,
enalyts
rnLtLal
CalLb.
Blanlr(wlr.t c
Continuing Calibration
Blank (mg lLl
1 c 2 c 3 c
Prcalretion
B].rrrk
c M
CadmLum----BalcnLuur
0 ,00oo40lu
0 .0003301 u
0,oooo{ol u I 0.:,.09-9j},1-1Er-l 0: 000040 J u
0.0003301UI 0.0003301U I 0.000330 I U
DI
tI
STL Denver Fom III IN 1,4 0
STL DETVVER
Total Metals Analvsis
-3-
BLANKS
Contraet,:
fJrlc Codc r
Preprretlon
Prcparation
URg CorlroraEton
STLDEhI Can SIo. t
B1ank MetrLx (gol1/water) r
Blank Coneentretion UnJ,ts
8IS llo - :gDO NO.: D5I090L76
T{trTER
(mgll or mg/kg) t UG/t
.[nal-1rEe
rnltlal
Cr1Lb.
BlanIE
(lrs/Ll
c
Cont.inuiog Caltbratlon
Blank (ng/I,)
1 e 2 c 3 e
Preparation
Blanh
e m
Cadml,un
-
SelcnLum
0.0000{0.1Y[, 0.0000{0lu | 0-0000{o I u
0.00033olul 0.0003301u I 0.000330 I u
D!
M
STL Denver
FoTm III IN
L4a
STL DEIVVER
Total Metals Annlvsrs
-3-
BLAI{KS
Contsrrct r
frab Code:
PraDaratlon
PreprretLon
tIRg CorSroratl-oa
$TLDEN Casa No':
Bl-anlr Matrix (tolL/watar) r
Blanlr Conccntration Units
8nS No. t sDo !Io. : D5I090175
(mg/L or rrglks) :UG'/I,
Aor]-lt,c
rnltLol
CII-lb.
BhNIE
(ng/L)
c
Coatinuing Calibration
Blank fuglll
lcze3c
PrcperrtLon
B].f,nlE
c M
Cadmlunr
S.l"rrft -
o. oj).qgj]} I u
0 .0oo33o I u
M
M
STL Denver Forru fII Ilf a42
STL DETVVER
Total Metals Analvsis
-3-
BLANKS
Contract:
f-,d) Codc r
PrGparation
Prcparatsion
IIRS Corporrtl.on
gTT,DEN Catc No. I
Blank llatrix (roLl/watcr) :
Blarrk ConcentratJ.on Unit c
SAg ![o. !sDGl NO.r D5r090176
(W/t, or Eglhg) 3 vtg/L
AnaLytc
InLEirl
Crl,ib.
Bl"inl(
(tnslL)c
CoatLnulng Ca1lbratl,on
Bl,ank (nglL)
1 C 2 c 3 e
PrcDaration
BI-enk
c M
Ca&nir,rn
E"1"ti.-,
o , 0000{01 u
o . 0003301 u
0.0000{olYl.._o.000040 lu I o.0oo0{0 [u
o.000330lUl 0-o0033olu I 0.000330 I u
0,00004
0.00033
U
u
M
D[
STL Denver Form III - IN i,43
STL DEIVI/ER
Total Metals Analvsrs
-3-
BLAI{I(s
ConErast r
f,ab Code :
PraDarrtion
Preparatlon
IIRSI Cor^goratl,on
STLDEI{Clgc No. g
Blank ltrtrLx ( toil/water) :
B]-rnh Concontration unLta
sDG No. r D5I090L76
(mgl[' or tuglkg) r MG/I.,
Anelytc
tnLtl,al
Crl.lb.
BIarrlc(w/\')
e
Continuing CalLbrrtsLon
Bl'an]r lnrgllrl
t c 2 c 3 c
Prcprrrt:Lon
BI.anlc
c M
Cadml-umseffi 0.0000{,qlul 0.000040 lul 0.0000{0.1 u
0.O0o33olul 0.0003301u I 0.000330 I u
M
M
I
I
STL Denver Fom III - IN
a44
STL DEIVVER
Total Metals Analvsis+
ICP INTERFERENCE CIIECK SAMPLE
Contract: URS Corporation
r.ab Coda r STITDEII Caga No. I
ICP ID lilumbcr r T*Il fntreptd ICP
gLSt Ho. :gDs No. r D5f09OL?6
ICg Eourcrr Ht-gh Purlty, Spcx,
Tnr
So1 ..1, SoI ..}B
lg7. 65 t80.83 I 95.2
193 -27 190 -t7
53.13I 105-3
tg3.93l 489.181 97.8
1.168 I 115. I
Coneentrration uaitg):Efl/.I:
fnitial Found
8oI ..1, 8oI .lB
J.
I "inrl rnonnd
IesR J sol ,I sol . [E]lnrlytc
plumfnum Hf I
alcium IIL
Iron IIi
froiaeefum
F n r"aium
Sodium Lo
un IIi
fzlrconium
507 .58 I 502 .70 100.5 I
STL Denver
Dortrt IV IN
145
STL DENVER
Total Metals Analvsis
-4-
ICP INTERFERENCE CHECK SAMPLE
Contraet I IIRS CorDonELon
Lab Codr t STITDEN Crer
ICP ID Nurubcrr T.fA Int,reDtd
No. t
ICP
S.LS No, t SDGI No. r D5I09OL7 6
fCg Souree:Higrh Purity, Spex,
Concent,ratioa UnLts) r mg/Lr
fnitial Eound
SoL,A SoI ..lB
FLnr} forrnd
SoL..}, 8o1 .lB
lcalcium IIt I
Potrssirrm
8od,l,um Lo
lSodium
{98.0{ J t97.s7 I 99.51
Tnre
€lo1 .A SoI.-.LB
5{ .49 I 109. O
53 .90 I 107. I
STL Denver
Pom rV I IN
L46
STL DETVVER
Total Metals Anah'sis
-4-
ICP INTERFERENCE CHECK SAI}TPI,E
Contract r tIRg Corporation
Irab Code : STITDEN
ICP fD Nurnbar: SUPERtrR.trCE
gAS IIo. r sDG No-: D5I090175
ICS Sourcrr ELgrh Purity, Spcx,
Coacrntrat.lon Unite) :tq /r,
Analtrt,c
Trrra
SoI .A CloL.AB
rnLtLal Found I "[nal Forrnd,
Elol .I, 8oL.A.B tR I sot.l So1. .AB x,R
lArsenLc I O.00 2,00 -0.002 1.98 J 99.0 I
JBarLurn 0.00 0 .50 o,oo0 0.521 I 10{ .21
Ihronium 0. oo 0 .50 0,004 0.479 I 95.8 I
lcotpe r 0.00 0. 50 0,001 0.5371 LA7.{l
Lcad I O. O0 1- OO 0.000 o.971 97.O1
Lc eI 0.00 1. O0 0.001 0,9{l 9{.ol
Silvar I O.0O 1.00 0,000 1.0{l 104.01
[vanCdiunr 0.00 0 .50 0,002 0.480 I 96-ol
7,Lnc 0.0 1.0 0.012 o.sol 9o.ol
STL Denver Fom IV - IN
747
STL DENYER
Total Nletals Annlvsis
-4-
ICP INTERI.-ERENCE CHECK SAMPLE
Contraet: IIRS CoreI>ontLon
r,ab Codc I STLDEN
rCP ID llunber: PE ICPUS
Cage No.:SAg llo. t SDGI No. : D5I090L7 6
ICg Sourerr Inorgrnic VantureB
Initial f,ound
8ol .l flol .lB eGR
trnrrr
gol .n, 8o1 ..tB
0.10631 ro6.3l 0.001 0.1031
o. oe88 I
ConccntraELon Urri.ta) I m{Ilr"
FinaI
So]'}'
Forrnd
So1 ..},B
STL Denver Form IV IN 148
STL DENVER
Total Metals Analvsis
-4-
ICP INTERFERENCE CHECK SANTPLE
Contract : IIRS Corporat ion
I{ab Codo: STITDEN
ICP rD Nunbcr s PE ICPUS
Cege No. t 8AS No. t sDo No. r D5I090175
ICg flourccr Inorgranio Vcntureg
Concrnt,ntLon UnLta) I ,E'glL
tnrc I rnitLa1 Found I rLnal Found
lnalyt. I sot.r goI.IB I Sot.l gol.rB e6R I Sot.r BoI .tB tn
fcaamrum 0-00 0.to o.00?o,0996! S9,5I 0,002 0.0999 99.8
Sclaulum 0.oo 0.10{{ I r0{. {o.1051
STL Denver
Form M![
749
ffisrr
URS Corporndon
Total Metals Antlysis Data Sheet
Lab Name:
LoUSDG l\umber:
Matrix:
7o Molsture:
Bssis:
Anatysis N{ethod:
Unit:
QC Batch ID:
MS Sample Allquot:
MS Dllutlon Factor:
STL DENVER
p5r0e0r 76
WATF,R
NiA
Wet
60108
mni L
5''652-17
50 mL
I
Cllent Srmple ID:
MS Lab Sample ID:
MS Lnb Workorder:
Date/Tlme Collected;
DstelTimc ltecclved:
Date/Time Leached:
Dute/Time Extracted:
Date/Tlnre Analyzed:
lnstrument lf):
I-AB MS/MSD
psr tegp0-002s
HKWI4
09/I?i05 t l:15
Ooi t 9105_li;$O
09123/05 l5:30
09/'6105 a I;J6.
QZt
Analyte
Spike
Amount
Strnple
Result C
MS
Result c
o/"
Rec a QC
Lirnit
Alurninunr 2.00 32 55. r MSB NC 83 - r 19
(lalciurn 50.0 I10 rs8 97 48 - 153
lron r.00 49 54.7 MSB NC 52 - 155
Magncsirrnr 50.0 29 78.7 99 62 - 146
Potnsr^ium s0.0 34 87.8 t()l 76 - r32
Sodium 50.0 t?0 222 I00 70 - 203
Zircorriurn 0.s00 0.0t 5 0.549 r07 80 - 120
STL Denver
Form 5A MS Analysis Data Sheet Equivalent
150
o
ffiSTL
URS Corporetion
Total Metals Analysis l)ata Sheet
Lab Nrmc:Cllent Snmple ID: LAB MSil\'lSD
MSD Ltb Sample ID: D51t90220-002Q
MSD Lob WorkOrder: HKWI4
Dttefl'ime Collected: 09/ I 9i05 I 1: 15
Date/Tlme Recelved: 09/I910[-..15:.a0
Dste/Tirno Lcached:
DatelTlme Extracted: 09123105 11:30
DatelTlrne Analyzed: Q212fr/05 2l:16
Instrument ID: 021
STL DENVER
LoUSIIC Number: f)5l0o0l ?6
Matrlx: WATER
7o Molshrre: N/A
Basls: Wet
Analysis Method: 6010.8
Unit: mg/[,
QC Bntch lD: 5]65237
MSD Sarnple Aliquot: 50 rn[.
PISD Dllution Frctor: I
Antlyte Splke
,A.mount
Sample
Result
C MSI}
Result
C 7o Rec a RPD 0
Q(-' Lirnits
7o Rec RPD
Alurninum 2.00 32 56.7 MSB NC NC 83 - 119 25
Calcium s0,0 il0 158 99 0.60 48 - r53 25
lron r.00 49 s5.5 MSB NC NC 52 - r55 25
Magnesiunr 50.0 29 78.5 99 0.24 62 - 146 25
Potassium 50.0 34 88. I r ()8 0.26 76 - ttz 25
fldium s0.0 17t)226 tr0 2.,1 70 - 2A3 40
Zrconirm 0.s00 0.0r5 0.548 107 0.20 80 - r20 25
STL Denver
Form 5A MSD Anolvsis Datu Sheet Equivalent
151
ffi$rr
URS Corporation
Total L{etnls Analysls Data Sheet
Lab Nnme:$TT DEN.VTR
LoUSDG Number: I)slqo0l76
Mttrix: WA'I'ER
Yo Molsture: NIA
Basls: Wst
Analysls Method: 60108
Unlt: rn&''L
QC Batch ID: 5265237
MS Sample Allquot: 50mL
MS Dllutlon Factor: 1
Client Semple ID: LAB M$iMSI-)
lltS Ltb Sample [D: Dsl laq220-002s
MS Lsb \UorkOrder: HKWI4
Date/Tlme Collected: 09/L?{05 I l :15
DatelTime Recelved: 09/19/05 l5;S0
Date/Time Leached:
Date/Tlnre Extracted: 09/23105 15;30
Date/Tlme Analyzed: 09/28i05 08:23
Instrument ID: 0I0
Analyte
Splke
Amount
Sample
Result C
MS
Result C
a/o
Rec a QC
Lirnit
Arscnic 2.00 0,01 4 B 2.02 IOI 84 - 124
Barium 2.00 4.67 2-66 99 8s - r20
Chrtmium 0.200 0.060 4.2s9 99 73 - t35
Copper 0,250 0.069 0-328 104 82 - 129
Lead 0.500 0.054 0.s33 96 89 - 12t
Nickcl 0.s00 0.047 0.s21 9s 84 - 124
Silver 0.0500 0.002E U 0.0s r 8 104 "15 141
Vanadium 0.500 0.079 0.s82 r0r 8s - I2ol
Zinc 0.5tt0 0.47 0.93 r 93 60-137!
STL Denver
b orm 5A IIIS Analysis Data Sheet Equivalent
152
ffisrr
URS Corporation
Total Metals Analysls Drta Sheet
Lab Nnme:
Lot/SDG Number:
Mttrix:
Yo Molsture:
Basis:
Analysis Method:
Unlt:
QC Bntch ID:
tllSD Srmple Aliquot:
MSD Dilution Ftctor:
STL DEhiVER
psr09.0176
WATER
N/A
Wct
601 0B
mIL&
5265237
50 mL
I
Cllont Sample ID:
MSD Lrb Sample ID:
MSD Lab Workorder:
Date/Tlme Collected:
Drte/Tlme Receh'ed:
Datefl'ime Lerched:
Datc/Tlme Extracted:
Date/Tlme Anslyzed:
Instrument I D:
LAB MS/MSp
p5I r 90220-002D
HKWI4
09119/05 I l :15
09/ l9/05 l5:a0
0e/21/05 l5:30
09i2tll05 08:23
016
Analyte Spike
Amount
Snmple
Result
C MSD
Result
C 7o Rec a RPT)a
QC Llmlts
o/o Rec RPt)
Arscn ic 2.00 0.014 B 1.99 99 r.8 84 - t24 25
Bariunr 2.00 0.6'7 2.64 98 0.5t)85 r20 25
Chronriunr 0.200 0.060 0.256 98 I ^l 73 - r35 25
Copper 0.250 0 069 0.32t r03 0.34 8? - tzt)25
I-cad 0.500 0.054 0.s30 95 4.47 89 - 12t 25
$ickel 0.500 0.047 0.5 14 94 1.3 84 - 120 25
Eitr*,(1.(Is00 0_0028 U 0-0516 103 ().3 I 75 - 141 25
Vanadiurn 0.500 0.079 0.579 r00 0.51 85 t20 25
Zinc 0.500 4.47 0.933 94 0.19 60 - 137 25
STL Denver
Form 5A MSD Analysk Dato Sheet Equivulent
153
ffisrt
LJRS Corporation
Totrl Metds Anelysls Data Sheet
Lsb Name:
Lrr/StlG Number:
Mafrlx:
7o Molsture:
Basis:
Analysls lllethod:
Unlt:
QC Bntch ID:
MS Snrnple Aliguot;
llls Dllutlon Frctor:
S,TL DENVER
psr090r 70
WATER
l.liA
UsI
7470A
mglL
s2s24;.7
1
CIIent Sample ID:
MS Lrtb Sunple ID:
MS Lab WorkOrder:
Date/Thne Collected:
DfielTime Received:
Iltte/Tlme Lerched:
Date/Tlme Extracted:
Date/T[mc Annlyzed:
Instrument ID:
r AR MSIMSD
p5r080243-0MS
HJ6JM
09i07i05 09:55
99/08i()5 0e:30
09/23r05 I a;5Q
09123i05 I 8: l8
0r9
Analyte
Spike
Amount
Sample
Result C
MS
Result C
a/o
Rec a QC
Limit
Mercury 0.00500 0,000044 TI a.00377 75 N 85-il4
STL Denver
Form 5n MS Analysis Data Sheet Eguivalent
L54
ffisrt
IJRS Corporation
Total Metals Analysls Data Sheet
Lsb Nrme:
Lot/SDG Number:
Ntttrix:
7o Moisture:
Basls:
Analysis Method:
Unlt:
QC Brtch [D:
MSD Sample rLliquot:
MSD Dilution Factor:
srl. pnhtvHll
psrq9!_1.7s
WATEB
LIA
WsI
747(0A
ms/L
s2s9437
I
Cllent Sample lD:
MSD Lab Srmple ID:
MSD Lrb WorkOrder:
Date/Time Collected:
Date/Tlme Recetved:
Date/Time Loechedl
Ilate/Tlme Extrrcted:
Date/Time Analyzed:
Instrument ID:
LAB MS/MSQ
D.5r080243:0Up
HJ6JM
0q/07/0s QgSs
09/0$/05 0e:30
$9/23/Q5 l2:5$
09/23/0s uL.L8
0r2
Analyte Spike
Amount
Srmple
Result
C tUSD
Result
C o/o Rec a RPD a
QC Limits
o/o Rec RPD
Mcrcury 0.00s00 0.0(x)044 L}0.00365 73 N 3.3 85-lt4 r0
STL Denver
Form 5A IVISD Analvsis Data Sheet Equivalent
155
STL DENVER
Total Metals Analvsis
-5A-
SPII(E SANIPLE R-I]COVERY
ContncB r IIRSI Cor;porltLon
r,ab Code r STITDEN Care No.:SLg No. r 8Dc NO. r D5IO901?5
LcvcJ, ( Iow/med) :LOVTMatrl.x (eol1/water): WATER
t golidr for Sengrlc r 0.0
g.NIPLE NO.
Concentration Units (mg/L or mg/kg dry waLght ) r ![GIL
AnaI-yEr Contro1
r,LmLt, tR
Spiked Sanflle
Rcgulr (ssR) c
SanpLc
Re gults (gR) C
Spike
Addrd (gL)e6R a Ir{
Cadnrium I gg 110 0.0525 o. 01{ I 0.0{00 95 u
I s.Lenl_rurr I gZ - 1,Lz 0.0362 o. oo4o I 0 .040 80 N M
Comuontr: HI${1{1
STL Denver
Form V (PlRlI 1) F rN 156
STL DENYER
Total Metals Analvsis
-5A-
SPI KE SAI}TPLE Rf,COVERY
Contrlct' r URS Corporetl,on
SJIMPITE NO.
IrfB MgD
SDO trlO. : DSf 090175rab Codcr STITDEN Caac No. r glII No.,
Mrtrl,x (roi1/wrt,rrlr UIIITER
e6 8o11de for SanDIe :0.0
Leve1 (Iow/mrd) :
ConcentretLon Unl-te (mgll or mg lh;g dry wcl-ght ) ;IEGIL
AnrLytc Control
rrLmLt 96R
Spikcd Samplc
Result (SSn) c Arrqlle
Rc;ult ( CtR) C
Splkr
Addcd (sf,)eGR a M
I Cadruium I gg - 110 0. 0531 o. 01{ I I o. o4o 97 I{
] SclenLrr.m J gZ LLZ o.o3l7l I o.oocol I o.odo 87 t-t
HIff141
o
Corusrrn
STL Denver Fom v (renf 1) IN 757
STL DENVER
Total Metals Analvsis
-6-
DUPLICATES
Contraet r IIRti Cor5loration
Lab Code 3 8TLDEDI Caaa DIo. r SJIA No. t
Lgvc1 (Iow/mcd) r
t So1l.da for Dtrplicrtsc:
sl}s No. r D5f090175
LOW
0.0
Matrl.x (soil/watser): $If,TtR
t Solida for sarnplc: 0 . 0
s.tr![PLE No.
ConcaatratLon tDrLt,c (rrry/t or mg/kg d4, wcl-ght) r NIGIL
lrraryte I eott'tror
I r,l 'trt sarqrre (s) c ll thrpl'lcatse (D) c RPD Il O Irl
Crdrnirrrn I o. oszs I lJ o. os31 I 1- 2ll M
SclcnLum I o . o 3621 lJ o.0387 I 6,6ll lrl
Corurents r HI(W141
STL Denver
Forur \Jlt IN
STL DE]YVER
Total Metals Analvsis
-58-
POST DIGEST SP1KE SAIVIPI,E RECOVERY
ContracE r IIRS Cortpration
Lrb Codar STLDEN Caec No.:g.Lg !Uo. :SDG ![o. r D5I090L7 6
Mrt,rLx (;oll/watcr): I{}lrER Lovrl ( Lorr/ned) :
ConccatrratLon Urrlts:urglLr
.trarl1t,c ContsroI
r,l.nlt tR
Eplhrd 8enpIc
Rcsu1t (89R1 C
SampLc
Recult (SR) e
89J,hr
lddcd,(sa),6R a u
Cadml-um I 75 125 0 . x9 9429 o.o1{3011 I o.2o 92 .6 M
SclanLrun 175 125 0.181208 o.oo{ossfa 0.20 89.6 M
ComnenE,B r
STL Denver Form V (PIRT 2) IN 159
ffiSTt
URS Corporatiou
Total Metals Analvsis Data
Lrb Nanre:
Lot/StX] Number:
l\f atrlx:
7o Molsture:
Basls:
Anrlysis lYlethod:
Unit:
QC Bntch ID:
Snrnple Aliquot:
Dtlutlon Fsctor:
srr.pJls/EB
D5l090l 76
WATF,B
N/A
WsI
601 0B
mg/[.
5265237
50 rnL
1
Sheet
Cllent Sample ID:
Lab Sample ID:
Lab Workorder:
Date/Time Collected:
DrtelTime Recelved:
Date/Tlme Leached:
Date/Tlme Extracted:
Drte/I'ime Analyzed:
Instrurnent ID:
p5r220000-237s
HKJI\.{A
09/23i05 t5:30
09t261_Q5,2t:02
021
Anrlyte True Found ToRec a LImlts
Alunrinunt 2.00 l.9l 96 86 - 108
Iron t.00 0.938 94 88 - r 10
Magntxiurn 50.0 4',1 .3 95 9I 111
Potassiurn s0.0 s0. r 100 n6- il1
Sodiunr 50.0 48.5 97 9I lt2
Zirconiunt 0.500 0.504 r0r 75 - 125
Clalciunr s0.0 46.2 92 89 - r l0
STL Denver
Form 7 LCS ,4nalysis Dsts Sheet Equivalent
150
ffiSTt
URS Corporetion
Total lVletals Analysis Datn Sheet
Lab Narne:
LoUSDG Number:
Matrlx:
7" Moisture:
Basis:
Anolysis Methorl:
Unlt:
QC Batch ID:
Sample Allquot:
Dllutlon Fnctor:
STL DENVER
psr0g.0-176
WA I'EIT
N/A
Wet
601 0r]
mg/L
5265237
50 mL
I
Cllent Sannple lD;
Lab Sample ID:
Lab Work0rder:
Date/Thne Collected:
Date/Time Receivctl:
DatelTlme Lenchcd:
Date/Tlme Extracted;
Date/Tlme Anrlyzed:
Instrument lD:
DsI220000-237C
HKsM {
09/23i05_j5-;30
09ir 8i0s_0.$ 103
!t0
Analyte True Found ToRec a Llmlts
Arscnic 2.00 r .99 99 89 - r09
Lead 0.500 4.484 97 9r-il1
Barium 2.00 t.gtr 99 93 - r 13
Nickcl 0.s00 0.482 96 90 - I t0
Silvcr 0.0500 0,050e I ()2 85-il4
Vartaclium 0.500 0.497 99 tr8 - I 12
Linc 0.500 0.461 c)2 85 - I I0
)romiurn 0.200 0.r95 98 frg - r 12
6opp",0.250 0.:49 I00 86 - I r0
STL Denver
Form 7 LCS Analvsis Data Sheet Equivalent
151
ffisrr
LIRS Corporadon
Totrl IVletals Analysis Drtr Sheet
Lub Name:
Lot/SDG Number:
Mstrix:
7o Moisture:
Basis:
Analysis Method:
Unit:
QC Batch ID;
Sanrple Allquot:
Dilutlon Faetor:
STL DENVER
Dsl090 176
WATER
N/A
Wet
7474A
mgiL
5259437
I
Client Semple ID:
Lab Sample ID:
Lrb WorkOrder:
llrte/l'ime Collected :
Ilate/Time Received:
Date/Time Lerched:
Date/Tlme Extracted:
Date/'fime Anslyzed:
lnstrumcnt ID:
D5t160000-437C
HKVP.i{
0el23l$5 l2:50
09123/05 I8:08
0r9
Analyte True Found ToRec a l.,imits
Mercury 0.00s00 0.00s02 r00 85 - I 14
STL Denver
h-orm 7 LCS Analvsls Data Sheet Equivalent
L62
ffiSTt
URS Corporation
Total Metals Analysls Data Sheet
Lnb Nrme:
Lot/SDG Nurnber:
Matrix:
7o Molsture:
Bosls:
Analysls lltcthod:
Unlt:
QC Batch ID:
Snmple Allquot:
Dllutlon Fnctor:
STL DENVER
D51090r 76
WATEII
N/A
WEt
60?Q
rngil
s265 I g3
50 mL
I
Cltent Sample ID:
Lab Srmple ID:
l-ab Workorder:
Date/Tlme Collected:
Date/Time Recelved;
Date/Time Leached:
Date/Tlme Extrreted:
Dtte/Time Analyrnd'.
lnstrument ID:
D51220000-193C
HK5F2
Q9/23105 I s:30
09/27 tA5 l9:4&
004
Analyte True Found o/oRec a Llmtts
Selenium 0^()400 0.03s6 89 82 - rr2
Ca<hnium 0.0400 0.03tttt 97 tJ9 - I l0
STL Denver
Form 7 LCS Anatysls Data Sheet Equivalent
153
STL DENVER
Total Metals Analysis
-9-
ICP SERIAL DILUTIONS
Contraet: IIRS CorSroration
SAIIPLE NO.
rMIRA-IJAB aC $IIR
SDGI luO . : D5I0 9 OL7 6
Level (Iow/nod) r
Lab Codcr STLDEN Catc No. t EIASI No. r
Mat,rix (aoil/watar) g WATER
lml1tc
fnitLll Serqplc
Rc;u].t (f )
c
ScrLnl Pilution
Rcsu1t (8)
e
,6
niffor-
.lrco a Dt
I Aluxrlnum I 32.025 t2.161 o,{l P
Calci.tm H 108.99 11{ .49
J
5,0 P
Iron Hl {9. 39 52.26 I 5.8 P
Potasriurn 3{.18 35.55 I {,0 P
Magrncrium 29 .L7 3O, O8 l 3.1 P
Bodiurn IIi L7L-36 L7 6.69 I 3.1 P
Zirconiurr o,01{58 o. o213S le 46.i P
Conccntration tJnl-Er r tug lL
STL Denver
form IX E fN
764
STL DENVER
Total Metals Anslysis
-9-
ICP SERIAL DILUTIONS
Cont,ract: URS Corporution
S.trMPf,E NO.
fMgR.l-LrA^B Qe gtR
sDs No. r D5I090t76
I,cwc]. ( Low/med) :LOW
Irab Coda r STLDEN Carg No.:fIAg No. r
Mat,rlx (soll/water): WTTER
I l,raent c
Brrirrm
ChromLum
CopDor
frOfd
Niokcl
Silwcr
Vanad.ium
Zi.nc
Conccrrt'rlt ion Unitr: DglL
0.0140 0.022a
Initirl 8auplc
RoruLt (r)
Scrlal DLlutlon
Rcsult (8)
0 .05997 0. 05549
0.0 692 0.0701
0 . o5{3 0.0505
0. o{66 0.0{62
0.00290 0 . 01{00
0.0788 0 .0748
STL Denver
FoM IX - IN
155
STL DENYER
Total Metals Annlysis
-9-
ICP SERIAI, DII.,I]TIONS
Contracts: IIRS CorTloration
SAIIPI.E [IO,
I![ERA-L.LB OC gER
sDc No,: D5I090176
L,cvol (low/urd) :
Lab Codc r STITDEII Cur Dlo. !SfA No. t
Matrrlx (soil/wrtcr) r WATER
I cadmlun
Sel.eaium
Concantratsion Uaitg. mg/L
0 .01{301 0 .0L522L
ru'itLa]. grqDlc
Regu]-t (I)
Scrlr]. DLluti.on
Reru1t (S)
o. o0{039 0. oo3740
STL Denver
Fo:cur IX IN
1,6 6
STL DEIVVER
Total Metals Analysis
- r0-
NTETIIOD DETEC'TION LI]IIITS
Contract s IIRS Corfroration
Irab Code 3 STLDEN Carr No. t
rCP ID !$rmber: Tir}. Iatrepld ICP
Flama ^L.f, ID Nuuber:
Ihrrnaca L[, fD Iihrnber r
Slg No, r
Drsor 5 lLA/?-AOS
SDo No. r D5f090L7 6
Analtrtc
Wavc-
lcngth
(nml
Eack-
ground PQr"
(rtg/I,)
DIDL
(ng/r,)![
Aluniuurn t 167,0 0.10 I 0.017 P
nlurnl..nun n 349 .2 1-0 P
Calciultt Ir 3Lt.933'0.20 I 0.03{P
OI,UN II 319.1 10 P
Iron Lo 259.9 0.10 I 0.021 P
Iron 27L.{4L 1,0 P
PotagcLurn 765. {91 .01 4.74 P
gDcEl,u$l 279.079 0.20 I 0.0{P
ur[ Lo 589 ,5 1-01 o.031 P
Sodiun H 818.3 10 P
Zirconlun 339,1 0.0050 0.0016 P
O
Common
STL Denver
Form x fN 767
STL DENVER
Total Metals Analysis
- l0-
METIIOD DETECTION LI1VIITS
ConEract r URS Corfroratiou
Irtb Coda E STLDEN Cago No. I S.f,S No. r
Date:3lLAt2005
sDc lro. r DSI090 L7 6
ICP rD Numbcrr SUPERTRf,CE
tlame AA fD lrhrnbcr:
Fur:nrcc AJt ID ltunbcr r
.Lrraltt,c
Wlve-
lcngth
f nm)
Baok-
ground PQI,
(mg/I,)
MDL
(mg lll u
asalrl.c 199 .A{2 0.010 I 0.0a14 P
Bariun 493 . e09 0.010 o.00070 P
ChromLutr 267 .716 0.010 ,0026 P
opPcr 32t.753 0.0x0 I 0.0045 P
Lca 224. 353 0,0050 0.0026 P
NiokrrI 23L.50{0,0{01 0,00L2 P
Silvcr 328,068 0.010 I 0,0028 P
anad,Lum 292 . lA2 0,010 0.0025 P
Zlnc 206,200 0.020 0.00{5 P
Com,ment,s;
STL Denver Form X fN 158
STL DENYER
Total Metals Analvsis
_ t0 _
METHOD DETECTION LIMITS
Contrrct,: URS Corporetion
LaI) codc: STLDEII
fCP ID ll\unbrr r
gAS No. r
Date: 1LlLZl2004
SDGI No. r D5I090176
fLane .lA ID tll,unbcr I
hrrucc A.f, ID ltumbar:
PE C1IAA
Arrallrtc
Wavo-
lengEh
(run)
Bach-
ground PqL
(ss lLl
llDIr
(urgllr\M
rcular 233 .14 0.00020 0.0000{4 cv
omnonE; I
STL Denver Fo:m )( - IN L6g
STL DETYI/ER
Total 1llctals Analysis
-10-
METHOD DETECTION LIMITS
Contract g IIRS CorDoration
Lab Codes STLDEN
ICP rD Nunborr P[ ICPIII9
7l,rmc IJL ID lit\rmber:
Ittrnacc f,.I fD Mrnbcrr
Cage No, l 8Ag [Io. :
Drtr: 5 ILOlZOAs
sDc NO. r D5I090176
Analtrc,r
Irotopo Back-
grround,PQL
(mg I l,l
}TDL
(ng/r, )
M
Cadmirrrn 111 o. 0010 0 . 0000{ 0 M
Strlcnirrm 82 0. oo50 0.00033 M
Comncnts:
STL Denver Forn X - IN L70
STL DENYER
Total Metals Analvsis
-1lA-
ICP INTERELEMENT CORRECTION FACTORS (AI\I\ruALLY)
coatract: IIRS CozrroratLon
Lab Code: SSDEN Cage No.3
Intrepid ICPICP rD NUmber: TiIA Dater I llg/zOOs
gAg No.3 SDO NO. a D5I090175
analtrtrc
$firve-
lengrtb
(nm)A1
Intorclamant Comectton racton
Ca f's
for:
Mg Ag
Lirr-trttLthI gsg-tgE 0. 0000000 | o. o00ooo0 0,00000001 0.0oooooo I 0. ooooooo
rlurninum lrct,081 0.0000000 I o. ooooooo o.oo182ool o.oo0ooo0] 0.oo0oooo
rtrrmlnum 1309.271 0.0000000 I o.0o0oo0o o.oooo0ool 0.00077ra I 0.ooooooo
antlrnony 1206.838 0.0000000 I 0. ooooooo o. oooooool 0.0000000 I 0.0000000
Arsenle I 189.002 o. ooooooo I 0.0000000 o. oooo0ool 0. 00o0ooo I 0 .0000000
sarl.um I nss. d03 0.0000000 | o. ooooooo o.o0o00o0l 0.00000001 o.ooooo00
aervllLum Jafa.O{2 0.0000000 I o.0o00ooo o.oooooool 0.00000001 o.ooooo00
Boron lztg - 678 0.00000001 o-o00oooo o.oooo000l o.oooo000l o.ooooooo
cafinlum lzz5. 502 0.0000000 [ 0.0000000 o. oooo $2ol o. ooooooo | 0 . ooooooo
calclum I frz. g33 0.0000000 | o. ooo0000 o.o0oo00ol o.o00o32ol o.ooooooo
calcLum ] rre.12B 0.0000000 J o.0oooooo o.oooooo0[ o.0000000I 0.oooooo0
ChromLrrn lZm .?L6 0.0000000 I o.0o0oo0o 0 , 0000000 1 0, 0000000 1 o. ooooooo
cobalt 1229.616 0.0000000 I o. 0000000 0. 0000000 1 0, ooooooo l 0.0000000
coppar I Sz{.253 o. oo0oooo I 0.0000000 -0. 0000200 I 0. 0o0oo00 I 0.0000000
rron lzsg. g4o 0.0000000 I o. ooooooo o.oooooool o.000c0ooI o-0000000
rron |.27 1.4{1 0.0000000 I 0.0000000 0 . o0ooo0o I o. oo2oloo I o. ooooooo
Laad _220.353 0.0000000 I o.0oooo0o o.oooooool o,oooooool o.ooooooo
Llthiuur ,67 0,28{0. oo0000o I 0.0000550 0. ooooooof o.0ooo000 [ o. oooooo0
Iutragnerium l.27 9. 029 0.0000000 I o. ooooo0o o. 0006020 l 0 .0000000 1 0. 0000000
Mansranese lzsz. G10 0.0000000 I 0.0000000 o.oooo0ool 0.0000150! 0.0000000
MolybdGrrum lZaZ.030 0.0000000 I 0,0000000 o. oooooool o, 0000000 I o. ooo0oo0
Nlckcl l 231. 6 0t /2 0.ooo0o0o I o-0000000 0.00000001 o.oooooo0l o.ooooooo
pbogphonrs ItrB.zg7 0.0000000| o-0000000 o. oooooool o. ooooo0o I 0.0000000
Potassium
J zeO,49L o. ooooooo I 0.0000000 o. ooooooof o. oooooo0 I o. ooooooo
Selonirrn I 196. o9o o. ooo000o I o. 000oo0o o.oo00o00l o.00oooool 0.ooooooo
gtll.con Izs1.612 0. 0000000 | 0.0000000 0.0oo0oo0l 0.o0oooool o.ooooooo
gtll"con
I ,ul.61s 0.0000000 | o. 0000000 0.00000001 0,00000001 o-0000000
silvcr I lrg. 069 0,0000000 I o. o0oo0o0 o. oooooool o. ooooooo I o. ooooooo
sodl,um Iugg.Sgz 0.0000000 I 0.0000000 o-oo0o0ool o,ooooooof o,ooooooo
sodlum I gt8.32G o. 00ooooo I o.000ooo0 o. oooooool o, ooooooo l 0.0000000
Strontir:m I tOz .77L o, ooooooo I o. 0001670 0.00000001 o.oooooo0l o.ooooooo
trhallturn lrg0.g6t o. ooo000o I o. 0ooo0oo o. o0o0ooo I o. oooo000 I 0. ooooooo
Corutentg:
STL Denve
Form Xr (PART 1)-IN
a7L
STL DENVER
Total Metals Analvsis
-ltA-
ICP INTERELEMENT CORRECTION FACTORS (AI{hruALL})
Contraet: IIRS Cor:porat,Lon
Lab Code: S1,1TDEN
ICP ID lftrrnber t TiIA
Care No.:
rntreDid reP
glg No. r
Dater I 1L912005
sDc No. r D5I090176
Tlrorl-um I 283 .730 0,000o0oo J 0. 0000000 0.00085001 0.00000001 o-ooooooo
Tr.n I re9.9g9 o.0oo000o [ 0.0000000 o. ooo0ooo I o. ooo0000 l 0 .0000000
rlranLum I 33{.9{1 o. o000ooo I -0.0000320 0 . 00000001 0.00002110 I 0.0000000
uranr.urn lres.gs8 0.0000000 I -0.0001020 -0,000eraol 0.0000000 I 0.0000000
vanadlum lzsz . ltoa o.oooooo0f 0.0000000 0.00010101 -0.00001301 0.0000000
zl,nc 1213.85G 0.0000130 | 0.0000000 0.00oos9ol o. ooooooo I o.0ooo0o0
Conmrenta r
STL Denve
Form XI (PART 1)-IN
l-72
STL DENVER
Total Metals Analvsis
-llB-
ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY)
Cortract: IIRS Conooration
tab Codc: STLDE'II Carc lilo. :
rcP
S.A,S !Io. 3
rCP ID ![umber: TJA Intrepid Dator 811,9 12005
gDc IIO. : Dsf 09 017 6
UI8v6-
lengrth
(utt)
Interelenent Corraet,l,on fectorg for r
BeAnalyt,c CdAgBBa
T. ' 1339-198l)l}^(Ifrtt llrnr I 0.0000000 | 0.0000000 0.00000001 o-0000000I o.ooooo00
rluminun f fOz,081 o. oooo0o0 J 0.0000000 o.oooooo0l 0.00000001 0.0000000
tluminum I 309.?7L o. ooooooo I o. o000o0o o. oooooool 0. ooooooo I 0.0000000
AntLrnony I206.B3I 0.0000000 [ o-0000000 o. ooooooof o, ooooooo I 0.0000000
rrsenLc I189.0i2 0.0000000 | o.000ooo0 o . oooooool 0. oo00o0o I 0.0000000
Barirrm I oS5. tt03 0.0000000 I 0.0000000 o.ooo00ool o.oooooo0l 0.0000000
scrf,LlLum If ff .0{2 0. 0oooo00 I o. 0000000 o. oooooool 0.0000000 [ o. oooooo0
Boron 1219.62g 0.0000000 I o.0oooooo 0. o0o0o00l o.00ooooo I 0.0000000
cadmLum .225.502 o. ooooooo | 0.0000000 o. ooooooof 0. oo0oooo I o. ooooooo
Cal cturn l r rz . 93 3 o.0oo0o0o | 0.0000000 0. o0000oo I 0. ooooooo I 0. 0000000
Carci.um 1318.128 0. 0000000 I o.0000000 0.00000001 0.0000000 1 0,00000001
clrrorniurn I 267 .7LG o-0oooo0o I 0,0000000 0.0000000J o. oooo000 I o. ooooooo\
cobatr |229.616 o. ooooooo J o. 0000000 o, oooooool o,000oooo l 0.0000000
Copper I 32 4.7r3 0.0oo0o0o I 0.0000000 o.0ooooool 0.0oooooo I 0.0000000
rron I etS.9{0 o.0oooooo I 0.0000000 0 . o0o0ooo I 0. 000oooo I o. 0000000
rron l^r1. {{1 0.0000000 I o. oo0o00o 0.00000001 o. ooooooo I 0.0oooooo
Lcad 11220.353 0.0000000 I o. o0ooo00 0 - 00000001 o. 0000000 I o. oooooo0
rlthlum |,67 0. ?E{o, ooooooo I 0.0000000 0. oooooool 0.0oooooo I o. o0oo0oo
lragneslum lZl g. o?g 0.0000000 I o.0o0oooo o-oooooool o.o0oo000I o-ooooooo
MarrgranGrc lZSt. 610 0.0000000 I 0.0000000 o. o0oo00ol o. oooo000 | o. oooooo0
Molybd,onurm lzoz.030 0.0000000 | o. oo0o00o o, ooo0000l 0,0000000 1 o. ooooo00
uickel laa1.6ot/z 0.0000000 | 0.0000000 o. oooooool o - ooooooo I o. ooooooo
Pborphonrs Itr8.287 o, ooooooo l 0.0000000 0.00000001 o. o00oooo I 0. o0o00oo
Potasgium I 200.491 0.0000000 I o.0oooo00 0.00000001 o.ooo000ol o.ooo0ooo
BelenLum I 19G.090 o.0oooooo I 0.0000000 0.00000001 o.oooooo0I o-ooooooo
sllLeon lrSL.6Lz o,o00o0oo | 0.0000000 0.00000001 0.00ooooo | 0.00o0ooo
stllcon
J
rtl, Gls o. oo0oooo | 0.0000000 0.0000000f o, oooo000 l 0. ooooo00
gllver
I 328.069 0 .0000000 1 o. ooo000o o.oooooool 0.00000001 0.0oo0ooo
sodlum I tgg. s92 o. ooooooo I 0.0000000 0.00000001 o, oooooo0 l o, ooooo00
sodlum I ere.326 0. 0000000 I o. 0000000 0.00000001 o.000oooo I o.0o000oo
Stronttr:n I COZ .77L 0. ooooooo | 0.0000000 0.00000001 0.0000000 | 0.00000001
Thrlliull I 190.864 0.0000000 1 0,0000000 o.oooooool o.oooooool o.ooooooo
Corrncnts I
STL Denve
Forra XI (PART 2,IN
1,7 3
STL DENVER
Lab Codc: S1I1TDEN
ICP rD llurnbcr: I:ifA lntrepid ICp
Total Metals AnalYsis
-llB,
ICP INTERELEI}T ENT C ORRECTION FACTORS (A N NTJALLY)
Cage !go. t gAg No. :
Dater I llg l2AA5
gDg NO. r D5I090175
Tlrorlum I283 .730 0.0000000 | 0.0000000 0,00000001 0.0000000 I o. ooooooo
rla I 199.989 o-ooooooo | 0,0000000 0, oooooooJ o.0o00ooo I 0.00o0ooo
rLtanLum I 33 1.94L 0.0000000 I o. ooooo00 0.00000001 0. ooooooo I 0. o0ooooo
uranlurn I385.958 0-0000000 I o.0000000 o. ooooooof o-ooooooo I o. ooooooo
vanadiurn lZlz .l}z o, oooooo0 l 0,0000000 o. oooooool 0.0000000 I o. 0000000
zLnc f zra. BsG o.0o0oooo I 0.0000000 o. oooooool o. ooooooo I o. ooooooo
Corrunentr:
STL Denve
Fom, XI (PART 2l - IN
L74
STL DENVER
Total Metals Analvsis
-ltB-
ICP INTERELEMENT CORRECTION FACTOR.S (ANNUALLY)
Contract: I,RS eorooretion
tab Code: STLDEN Case No. 3
gAg No. t
rCP rD lfiunbar: TifA Introp{d ICp Darc: 8l1g / 2005
SDG NO.: D5I090175
er:allt.e
f{ave-
length
(nm)Co
Interelment Correctlon Fastors
Cr C\r
forr
K lln
Z.;r(,..--r {.crrr 1339 ' L98 0-0000000 I -0.0012800 o. oo000o0l o. oooo00o I o. oooooo0
.l,luffinum l15z-OBL o. ooo0oo0 | 0.0000000 o-oooooool o.oooo000 I 0.oooooo0
Alunlnum 1309.27L 0.0000000 I o.00ooooo o. ooooo00l 0.0000000 I o. ooooooo
rntimony I aO6. 83B 0.0000000 I 0.0000000 o. oooooo0l 0,0000000 1 0,0000000
ArgenLc I feg. O{2 0.0000000 I o .0ooooo0 o-0ooooool 0,00000001 o.ooo00oo
Barl.um loS5-{03 0.0000000 I o. ooooooo o. oooooool o. ooooooo I 0.0000000
Bartrlllura If ff -A42 0.0000000 f 0,0000000 0 - 00oooool o .0000000 | o. ooooooo
Boron 1219.678 o.0oo00o0 | o.0o00o0o 0.0000000[ o, ooo0000 I o. ooooooo
cadmlum |,228.502 o. ooooooo I 0,0000000 o.ooooo0ol 0.00000001 o.ooooooo
Calclurn I f fz.933 0.0000000 | o. ooo00oo o. oooooool 0, oo0oooo f o.0oo0o0o
Calcium f are.12B 0.0000000 J 0.0000000 0.00000001 0.00000001 0.00000001
Ctrromiunr 1267 .7 LG 0.0000000 I o.0oooooo o-oooooool o.ooooooo I 0.ooaa72o
cobalr lzze.616 0.0000000 I 0.0000000 0.00000001 o. oooooo0 I 0.0oooooo
copp€r I aal. ?53 o. o00oooo I 0.0000000 o.oooooool o.oooooool o.ooooooo
rron I zss.g{o 0.0000000 I o.00o00oo o.00000001 0.0000000 I o. oooooo0
rron lrr 1. {cl 0. 1300000 I 0.0000000 0.00000001 o.oooo000l 0.ooooooo
Lcad 1rr0.353 o. ooooooo I 0.0000000 o.oooooool 0.0ooooool 0.0000000
rlthlum l.ero.784 o. ooooooo J 0.0000000 0.o0o00ool 0.oooooool 0.0000000
MagnegLum lrl9.079 o.oo00ooo I 0.0000000 0.00000001 0. 0000000 I -0.003s590
I'Ianganaae lZSt. 610 o. ooooooo I 0.0000000 o. o000oool 0. o0ooooo I o.0000ooo
nolybdoauln lZoz. o30 0.0000000 I 0.0000000 o. oooooool o. ooooooo I o. ooooooo
nLckeL l 231. 6 04 12 0,0000000 I 0.0000000 o.oooo000l o.oooooool o.ooooooo
Phorplronrg lrr},287 0.0000000 I o,0ooooo0 0 - 00000001 o. ooooo00 | 0.0000000
PotarrLusr l re5. {91 o-ooo0ooo I 0.0000000 0.00000001 o. o0ooooo I 0.0000000
seleniun I 19G.090 0.0000000 I 0,0000000 o. oo0ooool 0.0000000 I o. oo0oo00
stlLcon l rsL.GLz o-ooooooo | 0.0000000 o. oooooool o. ooooooo J o. ooooooo
silicon I ,u1.615 0.0000000 | o .0000000 o. oooooo0f 0.0000000 I o. oo0oo00
silver llzg.06g o. oo0oooo | 0.0000000 o.ooooooof o.oooo00oJ o.ooooooo
sodirrn I ug9. stt 0.0000000 I 0.0000000 0.00ooo0oJ o. ooooooo I o. o0ooooo
sodlum I gfg,326 o. o00o00o J 0.0000000 o. ooooooof 0.0000000 [ o. ooooooo
Strontlum I lOz .7"1L 0.0000000 | o.00o0ooo 0 .0000000 | o .0000000 | 0. 0000000 I
rhalllurn lrg0.g6,l 0.0000000 | o-o00oo0o 0.00000001 0.0000000 ! o. oooooo0
Corunentg I
STL Denve
FOrN XI (PART ZI - TN
\75
STL DENYER
Total Metals Analvsis
-IIB-
ICP IN TERE LEMENT C O RRECTTON FA C TORIi (ArVh[rrA LLy)
Contractt Mration
r,ab Code r S1ITDEN
ICP rD !firmberr TiIA
Cara No.3
fntrepid ICP
grS No. r
DatG: 811912005
sDc No.: D5I090176
T{horl,utn 1283 .734 0.0000000 I 0-0000000 0.00000001 o. oo0o000 I o. ooooooo
trrn I rg9.9g9 0.0000000 I o. o0oo00o o.00000001 0. ooooooo I 0. 00o0ooo
TiLani.um I Sg{.9{1 0.0000000 I o. ooo315o o,oooooool o.ooo0o00l 0,o0oooo0
uraal.urn 1s95.958 0. ooo00oo I 0.0000000 o. oooo0ool o. oo0oooo | 0.0000000
vanadLum 1292.4A2 0.0000000 | 0.00 a22go o. ooooooo[ o. ooooooo I o. ooooooo
zLne
1
113.856 0.0000000 | 0.0000000 o, ooo9{{ol o, ooooooo l o . ooooooo
Comncat,s:
STL Denve
Pom XI (PART 2l IIN
STL DENYER
Contract: IIRS Corrnorat-ion
Total Metals Analvsis
-I IB-
ICP INTERELEMENT CORRECfiON FACTOR*S (ANN UALLY)
Cage hlo. :
rCP
g.LS No, g
Date : S l1.gl?AOs
Lab Codc = STITDEN
rcP rD Number r 1[tifA IntreDid
SDc NO* r DSf090175
Wave-
langrth
(nm)
Intcrelmrant Correctlon Faetorg for:
Pb.f,naltt,a NT sbMohla
Z;rc.-,-nic<-rn I33I ' 198 0.0009000 I o. oo0000o o. oooooo-f o. oooooo0 I o.00ooooo
Alumilrum I r0z .081 0.0000000 I 0,0000000 o. o0oooool o. ooo0ooo I o. ooooooo
alurnlnum I309 .z'tt 0.0000000 I 0.0000000 o. ooo0oool o, ooooooo I o.00oo00o
lnrlmony 12A6,838 o.0o0ooo0 I o.000ooo0 o. oooooool o.0ooo0o0 I 0.0oo0ooo
rrsenic I 189. o{2 0.0000000 | o. 0000ooo 0.00000001 0.0000000 I 0. oooooo0
BarLum I {55,403 0.0000000 I o.00ooooo 0,0ooooool 0.0000000 [ 0.0ooooo0
ger^],llfuun IffS.OtL2 0.0000000 I 0. o0oo0oo o. oooooool o, o0ooooo J o. oooooo0
Boron 12{9-6?8 o. ooo0000 I o. 0000000 o.oooo000l 0.oooooool o.oooo00o
Cadurium |.226. 502 o. ooooo0o [ 0.0000000 -0.000Le701 0. 0000000 | 0.0000000
calclum I317-933 o.0000000 I 0.0000000 0.0ooooool 0.0ooooo0 l o, o0000oo
carcium I fr8.128 0,0000000 | 0.0000000 o. oooo000l 0.0000000 I 0.0000000/
Chromlum lz6J.7L6 0.0000000 | o .0o0oooo 0.0000000f 0.0000000 I 0.00000001
cobalr |228.516 0.0000000 I o-0000000 o. oo0ooool o. ooooooo I o. ooooooo
Coppar I 324.753 0,00034100 I 0.0000000 o. ooo0o00l 0,00ooooo J o. oooo000
rron I 259.9{0 o. 0000000 I 0. 0000000 o. oooooool o - ooooooo I 0. ooooooo
rroa l2T 1.4{1 o,6015000 | o. o000ooo 0.00000001 0.0ooooooI o-oooo0o0
read 1220.353 0.0oooo0o I 0.0000000 o. oooooo0l 0.00ooooo I o. 0000000
r,lrhlum I 6?0, ?B{0.0000000 J 0.00ooooo o. oo0ooool 0.0000000 | o. oooo00o
Magrneglum lzr9.a79 -0.0358000 J o. 0000000 0.0000000f o.0000oooI o-oooo000
Manoranose Jzll.610 0.0000000 I o, o0ooo00 0. oooooo0r o. oo0oooo I o. o00oooo
llolybdanum l2A?.030 o. o00oo00 J o. 0000000 o.ooo3s00l 0.oooooo0J o.o0000oo
rvlckel I23t.6Atlz 0.0000000 I o, oooooo0 o. oooo0ool o. ooooo00 I o,00o0ooo
Phorphonrs 1178.287 0. o0ooo0o | 0.0000000 0. ooooooof 0.0000000 | o. oooo000
Potasslun I765.491 o. ooooooo | 0.0000000 o. oooooool 0. oooooo0 | o. o0oo0oo
Selenlum [ 196.090 0,0000000 J 0.0000000 o. ooo0o0o[ o. ooo00o0 I 0.0oooooo
silicon I 2f1.612 0.0092000 J 0. oooo00o 0. ooooooo] 0,00ooooo ] o. ooo0000
gtlLcon
I 251.615 0.0092000 I 0.0000000 0.00000001 0,0000000 1 0. oooo0o0
silver I 329.069 0.0000000 | o.00ooo00 0.00000001- 0,0000000] o'0000000
sodlum I EBg. sgz 0.0000000 | 0.0000000 o. oo0ooool o . ooooooo f o. oooooo0
sodiun I BX8.326 0.0000000 | 0.0000000 0.00000001 o. ooooooo I o. ooooooo
Stronttunr llOZ .77L 0.0000000 I 0.0000000 0.00000001 0. 0000000 I 0.0000000I
Thalliusr I 190.85{0.0000000 I 0.0000000 o. oooooool o. ooooooo I o. ooooooo
Comnent,s:
STL Denve
Form XI (PART 2l -IN
777
STL DENI/ER
Total Metals Analvsis
-118-
IC P INTEREIJMENT C ORREC TION FA CTO TTS (A NNUALLY)
Contract: IIRS CorooratLon
r,ab Code s STIJDEDI
rCP rD lrunbor: TifA
Case Dro. 3
Intrepid ICP
SAg No. r
Datc: 8l1'gl2005
gDC NO. : D5I090L76
t{horlurn I 283 . 73 0 o. ooooooo | 0.0000000 0.00000001 o. o0o0ooo I o. ooooooo
TLn I 189.989 o-ooo0ooo I 0.0000000 0.00000001 o.00oooool o.0o0o0oo
Tltaniusr
1 33{,9{1 0. oooooo0 I 0.0000000 o. oooooool o. oo0oooo l o . ooooooo
uranlurn l3BS.g5B 0.0000000 I o. ooooooo o.ooooo00l o,0ooo00ol 0.ooooooo
vanadlrln l2gz .l}z -0. gL7 s000 I o. o0o0oo0 o.00000001 0.0000000I o.ooooooo
zl.ne Iera,8s6 0.0000000 | o, ooo00o0 o. oo438ool o. ooooooo I o. ooooooo
Coilments:
STL Denver
Form Xf (PIRT 2)ITN
778
STL DET{VER
Total Metals Analvsis
-t18-
ICP INTEREI.,EMENT CORRECTION FACTORS (ANNUALLY)
Coatract: IIRS Cor:ooratLon
Lab Code r S1.ITDEN Care !Io. t
fntrepld fePrCP ID !firmbcr: IFin,Data: I l1.gl2OAS
gAg No.:sDc No.: D5I090L76
Analltc
Wave-
l engrth
(nm)8e
Interelsmont Corroctlon faetom
Si Sn
for:
8r lri
I r .. l33g.1gg/--t !^c'.c?-r . LLrrt I 0.0000000 I o.ooo0ooo o. oooooool o. 0000000 | o. ooooooo
rlunl"num I rez.081 0-0000000 | 0.0000000 o. ooooooo l 0, ooooooo l 0 .0000000
Alumlnum 1309.2?L 0.0000000 I 0 .0000000 o.oo0ooool o.oooooo0l 0.0000000
.trntimorry lra6 . 83 8 o.0oooooo [ 0.0000000 0, oo0o0ool o. ooooooo | 0.0000000
Araonic I ttg.042 0.00oo0oo I 0.0000000 0.00000001 o.oooooo0l o.0oooo0o
sarLurn Iors.{03 0.0000000 I o.ooooooo 0.00000001 0.0000000 I -0.0001930
gerl.lllum lSff .A42 0.0000000 J 0.0000000 0,00000001 0.00000001 o.ooooooo
Boron 12{9.629 0.0000000 I 0.0000000 o.0ooooool o.ooooo00l 0.0000000
cadrrlum 1226. I02 0.0000000 ] 0.0000000 o,oooooool 0.00000001 o.ooooooo
calcium I rrz. g33 o. ooooooo I 0.0000000 0.00000001 o.o000oooJ o.ooooooo
calclun lrra-128 0.0000000 ] 0.0000000 o. oooooool o. oooo0o0 I o. 000ooo0
Chromlum lzit .7L6 0.0000000 | 0.0000000 0.00000001 o.oooo000l 0.0012000
cobalr |12?8.616 0.00ooo0o | 0.0000000 0.oo0ooool o.oooooool 0,0018000
copper Ifat.Ts3;0.0000000 | 0.0000000 0.00000001 o. ooooooo I 0,0000000
rron I 259.9{0 o-0000000 I 0,0000000 o. ooooooof 0.0000000 I o.0oooooo
rrorr lrr1. {{1 o-oooooo0 ! 0.0000000 0.00000001 0.00oooool o.ooooooo
r-aad lrro.353 o. o0o0oo0 I o. o000o0o 0.00000001 o.oo0o00ol 0.0000000
rirhlun I ezo, zg{0.0000000 I 0.0000000 o. oo0ooo0l o. oooo0oo | 0 - 0000000
Magneslun |_279.079 o-oooooo0 | 0.0000000 o, oo0oooo I o. ooooooo I o. ooooooo
Mangan6r6 JZSI. 510 0.0000000 J o.ooooooo o. oooooool 0.0000000 I 0.0000000
Molrrbdanurn |1202. 03 0 0.0000000 | o-ooo0o0o o. ooooooo J 0.0000000 I o. 0000000
ulcker I eai.5 ottz 0.00ooooo I 0-0000000 0,0oo0ooo] o. ooooooo I 0.0000000
ptrosghorrrs
I 178 .287 o. 0000000 I 0.0000000 o.ooooooof o.ooooooof o.ooooooo
Potasglu,m Ir05. {91 o.0000000 I o.0oooooo o. oooooool o. ooooooo I o. ooooooo
solenlun I t96,090 0.0000000 ! o.000oo0o o. oooooool o.00ooooo I o. ooooooo
stlLcon ll251.512 0.0000000 | 0.0000000 o.ooooooof o.0ooooooJ o.oo0oooo
Stllcon
I
zsr. Gli o.0oooooo I 0.0000000 0.00000001 o. oo0000o I o.0oooooo
sLlver lrrg,066-o. ooooooo I o.0o00o0o o. oooooool o. ooooooo I o. ooo35{o
eodlum I utg.59a 0 ,0000000 1 0,0000000 0.0000000f o. ooooooo J 0. ooooooo
sodlum I at8.326 o. 0000000 | 0.0000000 o.ooooooof o.oooooooI 0.oooo0o0
Strontiunr I OOi .tzt 0.0000000 | 0.0000000 0, ooo00o0f o, o0000oo l o. ooooooo
Th8111un I 190 .95{0. 0000000 I 0.0000000 o.oooooool o.oooooool o.ooooooo
Corunentg:
STL Denve
FOrM XI ( PART 2I .IN
179
STL DEJVVER
Total Metals Analvsis
-1lB-
IC P INTERELEMET IT CORRE CTION FA CTORS (ANI\LIALIY)
Contract: IIRS Cor:poratl-on
LeI) Codc 3 STLDEN
rcP ID !ftrmbor r TOA
Cage No. r
Intrepid ICP
grg No. i
Dator 8 /L9 12005
sDo No. t D5I090175
Thorlurn I 283.73O 0.0000000 I 0.0000000 0.00000001 0.0000000 I 0.00ooooo
Ttn I re9.9e9 0.0000000 | o. ooo0o00 o - ooooooo[ o. oo0o000 I 0.00oo0oo
rlranLurn I 33{.941 0.0000000 I 0,0000000 0,0000000J 0.0000000 I o,ooooooo
uranLrrrn JaAs.9i8 0.0000000 J 0.0000000 0. 00oo0ool o. ooooooo I o. ooooooo
vanadlum lzlz.{.az 0.0000000 [ o. 000o0oo o. oooooool o. ooo0000 I 0.000{1oo
zLuc I zrr. 956 0. o00oooo I 0.0000000 0.00000001 o-oooooool o.oo00o00
Conunente:
STL Denve
Porm xI (PART 2l *IN
180
STL DENVER
Total Metals Analvsis
-118-
ICP INTERELEMENT CORRECTION FACTORSI (ANNUALLY)
coneract r
Lab Codes STITDEN Caee ilIo. ;
IntrepJ,d IePf CP fD lUtrmbar: TifA
gfs No- :
Dates 8llg/200s
sDe No.: D5I090175
Lnalytc
Wave-
length
(nm)1r1
rntrrrelemaat Correctlon Factors
UV
for r
Zn ttr
E;rrxon. ecr.rr 1339 - 198 0. oo0oooo I 0.0000000 0 . oooo0ool o. ooooooo I 0.0319000
rlunt ilrB I 152. 081 o. ooooooo I 0.0000000 0.0000000f o. oooooo0 I 0.0000000
trlumLnum lgOg.ZTL 0.0000000 I o.0ooo0oo o. oooooool 0. 0000000 I o. ooo0ooo
tntl,mony f 106.838 0 - 0000000 | o. ooooooo o, oooooool o.0000000 I 0. ooooooo
.urscntc I atg. o{z 0.0000000 | o. ooooooo o . oooooool 0.0000000 I o. ooooooo
Barirrn lAus.t03 o. ooooooo I o.0000000 0.00000001 o. ooooooo | 0. ooo3o3o
Barrrlliun Iaf f .04a 0.0000000 [ 0.0000000 0.00035901 0.0000000 I -0 .0000100
Boron I,09-6T8 o. o00oooo I 0.0000000 0.00000001 o. ooooooo I o. ooooooo
cadrnLum lrZ6. 5oz 0.0000000 I -0.0002070 0,0000000J 0.0000000 I 0. ooo0ooo
CalcLum I f12.933 0.0000000 | 0.0000000 o . oo0o0o0 | 0.0000000 I o. ooooooo
cal-ciurn I afa .Lzg 0.0o0oooo I o. 0000000 0.00000001 0.00000001 0.05590001
chromLrrn lZ6I .7LG 0.0000000 | 0.0007050 0.00000001 0.0000000 I -0.0005970
CoIraIt, lrZS . 616 0.0000000 I 0. o00o0oo o. oo0ooo0l o, oooooo0 l 0.0ooo0oo
coDDer f aal .7s3 0. o0o00o0 I o. o00E42o o,oooooool o.oooooool 0.0023200
rron I zss. gdo 0.0000000 J o. ooooooo o. ooo00ool 0.0000000 | o. oo0oooo
rron lrr1. {{t o.oooo00o I 0.0000000 0.00000001 o. ooooooo I o. oo00oo0
Laad lrr0.3 53 0.0000000 | o,0o0oooo o. oooooool o. 0000000 I o. ooooooo
Ltthium I 0r0. ?94 0.0oo0ooo J 0.0000000 o. oooo0ool o. oooo000 I 0.0000000
Magnesium lZr9.0?9 0.0000000 J o. oo?s6oo 0.00000001 o. 0000000 I -0.0418000
Manganaso lzsl.610 0. 0000000 I 0.00 al,22a -0.00015801 0.0000000 I 0.0000000
r'rolrrb'donurn I 202.030 0.0000000 I -o. ooo7o50 o. oooooool o. ooooooo ] o, oo1z5oo
rulckel lrll .60e/2 o. o000ooo J o.0000000 0.00000001 o. oo0oooo I o. oo0ooo0
Phosphorus I*rg.287 o.ooooo0oI o.0000000 0-00000001 o.ooo0000l 0.0000000
Potaralum 1116. {9L 0.0000000 I 0.0000000 0.0000000f 0.0000000] o.ooooooo
salenir,r:n I tg6.090 0-00oooo0 I 0.0000000 0.0ooo0ool 0.00000001 o.ooooooo
stllcon
J 251 .612 0.0000000 | o,0oo0o00 o.oooooool o.oooooooI o.ooooooo
stricon
I
asr. G1s 0.00oooo0 | o. ooo0oo0 o. oooo0o0l 0.0000000 | 0. ooo0o0o
silver I 32B. oGB 0.0o00ooo I -0.0002200 -0.01{9000f 0.0000000 I 0.0006880
sodlun I Ur9.5t,0.0000000 I o.ooooooo o-oo0o000l o.oooooool o.o0ooooo
sodium I era.3zE o,oo0o0o0 I o.0o0o0o0 o. oooooool 0.0000000 I o. ooooooo
strontltrn ] lOz -77 L 0.0000000 J 0.0000000 0.00000001 0.0000000 [ o .0000000 I
ThaI liurn 1 190 . 86{0.0000000 I o. 0000000 0.00000001 o.0oo0o00 I 0.0o0oooo
Comnent,r:
STL Denve
Form, XI (PART 2)IN
181
STL DENVER
Total Metals Analvsis
-118-
ICP INTERELEMENT CORRECTION FACTOR^$ (ANNUA LL})
ContraCt: IIRS Corcoration
Lab Cod.o r STIJDEN CaBe No, :
rcP rD Nhrrnber: TifA fntreflld ICp
grg No. I
Dater 8 llgl?OOs
sDc No. r D5r090175
rborlum I 283 .730 0.0000000 I 0.0155000 0.0000000J 0.0000000 I o. ooooooo
ri.n I 189. ggg 0.0000000 | o. o00o0oo o. oooooool 0.0000000 I o.0000000
rltaal-um 133 i,gtI:0.0000000 | o.0002850 o. ooooooo I o. o0oooo0 I o. ooooooo
uranium
1 385.958 0.0000000 J 0.0000000 o. 0ooo0o0l 0 - 0000000 I -0 .028?o0o
vanadium IZSZ - {Oz 0.0000000 I -0,0002 t}o o.oooooool 0.00000001 0.0015500
zLae
1
213.856 0.0000000 I o. oooooo0 0.0000000f 0.00000001 0.0000000
Coiltrnents:
STL Denve
Form XI ( PAnr 2l -IN
!82
STL DET{VER
Contract: IIRS Corncoratl-on
Total Metals Analvsis
-1IA-
IC P INTERELEMENT C ORRECTION FACTO RS (A NhTALLY)
Carc !ilo. :grg No.:
Date ; 'l / 23 l?AAs
LaIr Coda r gfI,DEN
ICP rD Numbcr r SIIPER|IRACE
sDc NO. t D5I090175
nnalrt,e
wav€-
lcngrttr
( nrn)A1
rnterclannant CorrsctLon ractorg
Ca Fe
for:
t{g Ag
Alurmtrrlm I308.215 0.0000000 [ o. oo0o00o o , ooolloo I o. o0o029o I o. oooooo0
Antlmony I 205.83I 0.0000000 I o. oooo0o0 o. oooozzol o.0000000 | o. ooo0oo0
Arranie I 189 .o42 o. oooooo0 J 0,0000000 -0.00001601 0.0000000J 0.0000000
sarium 1493.{09 0.0000000 I o.00o0o0o o.oooooooI o.ooo0000I o-ooooooo
ner^1'l1lum If ff .012 0. o0ooo0o I 0.0000000 o, oooooool 0.0oooooo I o, o0000oo
Boron 1219.628 o.0oooooo J o. o0o00o0 -0.00007001 0.0000000 I 0.0000000
cadnl,um 1226. 5oa o. ooooooo I o.0000000 0. ooo1{1ol o. oooo0o0 I 0. ooooooo
calcium I 3L9.933 0.0000550 | 0.0000000 0.00000001 0.0oooooo l o, oo0o0oo
CbronLuur lZ6: .7 LG o - 0ooo0oo I o. 0000000 -0.00001001 0.0000000 I 0.0000000
cobalr t|228.616 0.0000000 | o. 0000000 0.00000001 0.00oooool o.ooo00o0
coDper I azl -?s3 o.00ooooo | 0.0000000 -0.00002501 0,00000,c0f o-0oo0oool
rron lzl t. {{L 0.0000000 I o. ooooooo 0.00000001 0,0003{t00 1 0.0000000\
Laad lrr0 .3 sl.t a 0.0002 97a I o. ooooo0o o.oo013o0l 0.0000050 I o.ooooooo
r,,ead |_220 , 3 s]' t 2 -0.0001800 I 0-0oooo0o o. oooo6ool o. ooooloo I o. ooooooo
Magnarl,urn 127 9.078 0.0000000 I o. ooooooo o.ooooarol o.oooooool o.ooooooo
Mangrancrc l,257. 610 o .0000000 | o. 0000000 -0.0000060t---0.0000200 I 0.0000000
uolybdenurr lzoz.030 o. ooooooo | 0.0000000 -0.00001801 0.0000000 | 0.0000000
rut ckcl 1
231 . 5 A4 /2 0.0000000 | 0.0000000 0.00000001 o.oooo000l o.ooooooo
SctenLum I 195,027-lL -0. 0000030 I 0.0000000 o. ooooo2o[ o. oooo040 I 0.0oo0ooo
SelenLum I 196.02Lt2 o-0000000 I 0,0000000 -0.0001780r o. oo0oooo J 0.0000000
silicon lzea. tsa 0.0000000 I o-oooooo0 o.oooooool o.oooooool o.ooooooo
sLlver l 3zB. 068 0.0000000 J o.000oo0o 0.0000000I o-oooooooI 0-ooooooo
Btrontlum l{21.5s2 0.00ooooo I o. 0000000 o. ooo0oool o. ooooooo I o. ooooo0o
rhalllusr I 190.86{0.0000000 I o. 0000000 0,0000960 1 0. 0000000 1 0,0000000
Ttroriurn I o01.910 0.0000000 I -0.0000250 o.oooooool o.oooooool o.ooooooo
rln I 189.989 0.0000000 J 0.0000000 o. oooooool o. ooooooo I o. ooooooo
rltanium I rr{.941 0.0000000 | 0.0000000 o . ooooooo I
0. oooo20o I 0.0000000
uranlum I 3B5,9SB 0. o0ooo0o I -0.0000300 o, oooSsoof 0. ooo01{0 | 0. 0000000
vanedlrrrn I ,g z. a}z o.ooooo0o[ 0.0000000 -0.0003{001 0.00000001 0.0000000
zLnc l zrf -gs6 o. 0000000 | o. oo00ooo o.oooooooI o.ooooo2ol 0.00oo0oo
Cotunents r
STL Denve
Fom xI (PART 1)-IN
183
STL DETVYER
Contraet: IIR9 CorooratLon
Total Metals Analvsis
-r 1B-
IC P II{TE RELEMENT C ORREC TION FA CTORS (ANI-IUALLY)
Case No. t gAS No.:
Date: 7 12312005
Lab Cod,e: STITDEDI
IcP ID llrrmber r SUPERTBACE
sDc No, I D5I09AL76
Wave-
length
(nm)
fntarclamant Corract,Loa Paetorg for r
Bg
.Lna1tta CdAgBBa
lluminum I gOB .215 0.0000000 | 0.0000000 o. oooooool 0.0000000 I 0.0000000
Anrinrony I206.83I 0.0000000 J 0.0000000 o. oooooool 0. 000oooo I o. ooooooo
rrgenic I f99.0{2 0.0000000 | o.ooooooo o. oooooool 0.0o0o0oo I o. oo00oo0
Barl.urn l{93.{09 0.0000000 I o. ooooooo o. ooCIooool o. ooo0000 I o.00o00oo
BcryIlium If fa .A$2 0.0000000 I o .0000000 o. o0oooool o. ooooooo I o. oooo0o0
Boron 1249.678 0.0000000 I o.0oooo0o o. oooooool o, ooooooo l o. ooooooo
cadnLum lzz6. s02 0,00000001 0.0000000 o - oooooool o. ooooooo | 0.0000000
calcium I ars.933 0 .0000000 J 0,0000000 o - oocooool 0. o00oooo I o. oo000oo
ChromLum |.267. ?18 0.00oo0oo J 0.0000000 0.0000000f o. ooooooo | 0.0000000
colralt lr^g. 515 o. ooooooo I 0.0000000 -0.0012000 I 0.0000000 I 0. 0000000
fonncr |tzt. ?s3 0.0000000 [ o.0000000 0. 0000000f o. ooooo0o I 0 .0000000
Trron 1271.1{1 0.0000000 | 0.0000000 o.oooooool o.000ooool o.0oooo0o
Lcad. l22o .3 ,Lt L 0.0000000 I o. oooo0oo o.o0oo0ool 0.00000001 0.o00oooo
r,ead lzzo.3;Ltz o.00ooooo I o.00oo00o 0.00000001 o,oooooool 0.ooooooo
Magnerlum lZrg,0?8 0.0000000 I o. ooooooo o.ooooooof o.oooooooI o.ooooooo
Dtarrganoae lzst.610 0.0000000 I o. oo0oo0o o. oooooool o. ooooooo J o. ooooooo
Mo1ybd€&rn |,202. 03 0 0.0000000 I o .0000000 0.oooooool 0.00000001 o.oooo0oo
Nlckal I 231.6 OLt?;0.0000000 I o. o00o00o o. oooooool o. ooooooo I o. ooooooo
SclenLrrsr I 1g5 .02 LlL 0.0000000 | o. ooo0oo0 o.00000001 o.ooooooo[ 0.0000000
selenl.um I196.AzL12 0.0000000 J o.o0oooo0 0.0000000[ 0.0000000[ o.ooooooo
otllcon 1288.158 0 - o0ooooo J o. 0000000 o,00oooo0J 0.00000001 o.oooooo0
BLlver I SZe. 06g o-0000000 J 0.0000000 o. oooooool o. ooooooo l o, ooooooo
Stront,lum 1421 . SI2 o. ooo0000 | 0.0000000 0-00000001 o.oooo000l 0.ooooooo
rhalllum I 190.86{0.o0ooo0o I o.0000000 0, 0000000 1 0.000oooo l o. ooooo0o
Tlroriunr I OO1. gLO 0.0000000 I 0,0000000 0.00000001 o.ooooooof o.ooooooo
rLn I 189,989 0.0000000 | o, ooooooo o. ooooooo] o. oo00ooo I o. o0ooooo
rLtanLum
I
,, 4.gl7-o. o00o0oo | 0.0000000 o. ooooooo I o. ooooooo I o. o0000oo
UranLum I 385.9s8 0.00000001 0.0000000 o.oooooool o.ooooo00l 0.0000000
vanadlunr lzlZ.loz 0. 0000000 I o. ooooooo o. oooooool o.0000ooo I o. ooo0000
grnc Iere.856 o. 0000000 I 0.0000000 0.00000001 o.ooo0o00l 0.0000000
FOm XI (PART 2)-IN
1,8 4
Conunonts r
STL Denve
STL DENVER
Total Metals Analvsis
-118-
ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY)
ConLracut IIRS Comorat:lon
tab coder S1,LDEN Case No.:EItg No, :
ICP ID lllrmber: SIIPERTIRACE Datez 7 /2312005
gDc NO. r D5I09AL76
Anaht,o
Wa\ra-
lengrth
(nm)Co
rnterelement Corractl.oa Factorg
Cr Cu
for r
Un Mo
Aluntmrm 1408.215 0.0000000 I 0,001s000 o. oooooool o. ooo0000 | o. oo585oo
Antimony I206-838 o. ooooooo I o.003ggo0 0.00000001 0.0000000 I -0.0055500
rrgenlc l189.o4z o.ooooo00 I 0.0001700 0. oooooo0l o. ooo0000 I o. ooo3100
Barl.um I 493. {09 0.0000000 I o.0oooooo o. oooooool o. o0ooooo J o.00o0ooo
Berrlltum f Sff .A{,2 0.0000000 I o. ooo000o 0. o00ooool 0. 0oooooo [ 0.00ooooo
Boron lro9.6z8 0.0009900 | o.000o0oo o - oooooool o. ooooooo I 0. ooooooo
Cadrnlum |-226, 502 -0. 000 2200 | 0.0000000 o.ooooooffiooooo J o.ocooooo
Ca1cl,um 1319.933 0.0000000 I 0.0000000 0.00000001 0.o00ooool 0.0000000
Chrourlurn I 25 7 .7 LG 0.0000000 J o. 0000000 0.00000001 0.00000001 -0.0001700
CobalL 11118.616 0. 0000000 | o,000oo0o o. ooooooo I 0. o0ooooo I 0. o0o00oo
CopD€r I azn. ?s3 0.0000000 I o.0000000 0.00000001 0.00000001 0.00000001
rron |.27L.44L 0.0886900 I o. oo3oSoo 0.00000001 0.00000001 0-0000000'
Lcad lrr0 . 3 iLt t -0.0020c20 I 0.0000000 0.00000001 0.00000001 -0.0009600
read 1220 . 3 5L 12 0.0000000 | 0.0000000 0.00000001 0,00000001 -0.0002600
Masrnerium 1279.078 0.0000000 I o .0000000 o. ooo000o I 0. 000oooo J o.0oooooo
Manganese lZsl,610 o, ooooooo I o. 0000000 o.000ooool 0.0000000 I o.o0oooo0
Molybdanurn IZOZ.030 0.0000000 I o. ooooooo o.0oooooof o.oooooool o.00o0ooo
Hlckel Jegt-6o4t2 -0. oo0520o I 0.0000000 o.oooooo0l o.ooo0000J o.0o0oooo
Selenlurn l196.0ZttL 0.0005000 I 0.0000000 o.0000oool o. ooo35oo I o. o000ooo
Selcnium I 19 6. AZLIL -0.0001500 | 0,0000000 o. ooooooof o. oooS2oo I o. ooooooo
slll,con l2BB.li8 0.0000000 | o.0o0oooo 0 . 00000001 0, 0000000 I -0 . 00413{00
Sllwer I ,r8.068 0.0000000 | o .0000000 o.000ooool o.oo0ooool o.ooooooo
Stront,ium lL21 .552 0. 0000000 I 0.0000000 o. ooooo00l o. oo0o000 I 0.0000000
Thal1lum I 190.86{0.0017 r70 | 0.0002800 0.00000001 -0. o0{t7?00 I 0.0000000
Thorlu:n I oO1.9LO 0.0000000 | o.00oo00o o. ooooooof o. oo5o28o I o. ooooooo
rtn I te9.9a9 0.0000000 I 0.0000000 o.0ooooool o.oooo000l 0.0000000
rl-tanlum lrr4.9{1 o. oo00o0o | 0.0000000 o. ooooooof o. ooooooo I o. ooooooo
uranium I
gg5. gs8 0.0000000 [ 0 .000?600 0.000ooool 0. o00o0oo J 0.0000000
vanadLum I zga. {04 0. 0000000 I -o , oooS7oo 0. 0000000 1 o.000oooo l 0, ooooooo
zinc I zrr. B5G 0-0000000 I -0,0032900 0.0000000f o. ooooooo I 0. ooooooo,
Corutents:
STL Denve
FOTMXI(PAHT2) . IN
85
ST'L DENVER
Contraet 3 IIR.S CorooratLon
Total Metals Analvsis
-il8-
ICP INTERELEMENT CORRECTION FACTO RS (ANNUALLY)
Cage No. t gAg No. r
Date t 7 lzllzO0s
r,ab Code s STITDEN
ICP rD Mrmber r SIIPERlrR.e,gE
SDc No.: D5I090175
Analrt.e
wavo-
langth
(run)Nl
Intaraleuant CorrcctLon Factorg for s
Pb Sb Se si
^nluml-raum 1308.21s 0.0000000 I 0. oo00ooo o. oooooool 0. 00o00oo I 0.0000000
.il,ntrtmony I 206 . 83 8 0.0000000 I o.000oo0o o.000oooof o-ooooooo I o.oo0oooo
.f,rgonlc I1Bg.o{2 o. o00oooo | 0.0000000 o. oooooooJ o - ooooooo l o. ooo0ooo
sarium I {93.{09 0. ooo0o00 | 0.0000000 0.00000001 o.oooooool o-o0ooooo
Baryl,ltum IffS.O{2 0.0000000 [ o. ooooooo o.oooooool o.ooooooo I 0.0000000
Boron I ,19.678 0.0000000 I o. ooooooo o. ooooooo l o.0oooooo l 0.0000000
Cadmium |,116.502 0.0000000 I o. oo0oooo o. ooooooo l 0,0000000 1 0. 0000000
Calc1un I frs.933 o. oo0oo0o I o. 0000000 o. oo000oo I o. ooooo00 I 0.0000000
Ctrromirrn lzez .716 0.0000000 I o. 0000000 0. o00o0ool o. 0000000 I o. ooooooo
cobalt. 1118.616 0.00a27704 0.0000000 o. oooooool o. ooooooo I o. ooooooo
f onner I 3 ? t, .-t s3 0.00ooooo J o. 0000000 0.0000000J o. oo0o000 I 0. ooooooo
'rron lz, t. {{1 0. o0oo00o I 0.0000000 0.00000001 o-oooooo0l 0.00ooooo
Lcad lzro.3 sL/L -0.0001{00 I 0.0000000 0.00000001 -0.0000200 I -0.0001020
Laad lzz0.3 sL/z 0.00005110 I o.0o0o00o 0.00000001 -0.0001{00 I -0.0000370
Magnesirro lrr 9.0?8 0,0000000 I 0.0000000 o. oooooool o. ooooooo I o. ooooooo
Manganora IZSZ.510 0.0000000 I 0.0000000 o. oooooool o. ooooooo I o. ooooooo
MoLyHaDum |1202.030 o. ooo0ooo I 0.0000000 o. ooooooof o. ooooooo l o, ooooooo
Ntctcel l231.6}4t2 0.0000000 I o. oo000oo o.oooooool o.oooooool o'ooooooo
SelanLnm I 196.021/L 0.0000000 I 0.0000000 o. oooooool o, ooooooo l o. ooolooo
Selenl,tun l196.AzL/z 0.0000000 I 0.0000000 0.oooooooI 0,00ooooo| 0-0000000
sttteon I 288.158 0. 0000000 I o. 0000000 0.0000000 1 0, 0000000 1 o. ooooooo
gilwer I 329.069 0.00000001 o.ooooooo o. oooooool o. 000oo0o I o, o000oo0
Strontium ltZl,552 0.0000000 I o. ooooooo o.ooooooof o.oooooool o.ooooooo
Thallium I tro. 86{0.0000000 | 0.0000000 0.oooooool 0.000oooo l 0,0000000
'ftrorLurn I 101.910 0.0000000 I -0.000 6,20a o.ooooooof o.oooooool o'ooooooo
rin I 189.989 0. ooo00o0 | 0.0000000 0.00000001 o. ooooooo I o. ooooooo
ritanlum
I ,r0.9{1 0.0000000 I o. o00o00o o . ooooooo I o,0o0oo00 I o.00oo0oo
uranlum f tar. gig o. oo000oo I 0.0000000 0.0000000] o-ooooooof 0.0000000
vanadLum IZSZ.{02 0.0000000 I o-0000000 o. ooooooo I o. ooooooo I o. ooooooo
\zinc 1213,956 0.0000000 I 0. 0000000 0.00000001 o.oooooool o.ooo0ooo
Cormrsnts:
STL Denve
Porm xI (PIRT 2)IN
185
STL DENYER
Total Metals Analvsis
-118-
ICP INTEREI,EMENT CORRECTION FACTORS (AI\INTIALLY)
Contract: IrRll CorDontion
Lab Codo t STITDEN Cage No.:gAg No. 3
ICP rD mlltrber: SUPERTRACE Datet 7 123/2OAs
sDc NO. r D5IO9O175
lnaltrEa
wav6-
length
(nm)Sn
rntorelgnent correetlon faetorr
Sr 1[l
for:
T1 U
Alumtnum I 308 .215 0.0000000 I 0.0000000 0.00000001 0.0000000 I -0.0014000
Anrl.mony 1205,838 0.0000000 [ o, o0ooooo 0.0000000f 0.0000000 I o. ooooo00
Arsenl-c ItAg.Aaz 0 - 0000000 I o, ooooooo 0.0000000] 0.0000000 [ o. ooooo00
BarLum
1
d93 .409 0.0000000 I 0.0000000 0.00000001 o.oooo000I o-ooooo0o
Bcrtrlllum IafS.O42 0.0000000 | 0.0000000 o, oooooool o. oooo000 | o. ooooooo
Boron lztt -678 o. ooooooo | 0.0000000 o. oo00oool 0. ooooooo I 0.0000000
CadnrJ,um 1225.502 0.0000000 [ o. ooooooo 0.00000001 o. ooooooo [ 0.0000000
Calclr:m I319.933 0.0000000 I o. o0oo000 0. ooo0oool o. ooooooo I 0.0o31ooo
ClrromLum 126T ,?L5 0.0000000 I 0.0000000 o. ooooooo[ o.0o0oooo I o. 0004100
cobalr |1229.515 0.0000000 | o-o0oo0oo 0.002{{r00J 0.0000000 I 0,0000950
CopDer I 32{. ?s3 0. 0000000 | o. ooooooo o. oooooool o. oooooo0 | 0.0oo53oo
rron )27 t. {{1 0.0000000 I o. ooo0ooo 0 .0000000J 0.0000000 I -0.002{000
read lzz0.3 SL|L 0.0000000 I 0.0000000 o.00o00ool 0.00ooooo I 0.0010060
Lead lr220.35l12 0.0000000 | 0.0000000 o. oooooool 0.00ooooo [ 0.001{600
tttagrnoslrrrn lzl 9.078 0.0000000 I 0.0000000 0 - 00000001 0.0000000 I -0.011[d000
It{anganos€ IZSZ. 610 0.0000000 | 0.0000000 0.00000001 o. ooooo00 I 0. ooo13oo
Molybdenurm I 202.030 0.0000000 I o-oooo000 0.00000001 0.0000000 I -0,0002100
ulckal I23 1,.6A412 o. ooooooo [ 0.0000000 0,0000000] -0.0009400 I 0.0000000
8elenlum
1
196.02LtL 0,0000000 I 0. 0000000 0.00000001 o.0oooooo I o. ooooSoo
Salenium J19 6.AZltZ o. ooooooo J 0,0000000 0.00000001 o. ooooooo l o,0ooo0oo
siltcon legS-158 o - 03 L2600 I 0.0000000 0 . 0088000 J o. ooo0000 I o. oooE{oo
Ellver I frg.068 0.0000000 I 0,0000000 o, oooooool o. ooooooo I o. ooo93oo
Etrontlum 1or1.552 0.0000000 J 0.0000000 0, oooooool 0,0000000 1 0.0ooooo0
Thalltum I 190.96{0.0000000 | o.0000000 0.0000000J o,000oooo l 0.0000000
rhorlum I d01.910 0,0000000 1 0.0000000 o. oooooo0f o. ooo0o00 I 0,0023300
rLn I 189.989 0,0000000 | 0.0000000 o. oooooool o. ooooo0o I 0.0o0ooo0
nLtaalum I,r{,9{1 0.0000000 [ 0.0000000 0. o00o0oo[ o. oooo000 ] o. ooo3o00
uranlum l rts.gSB o. oo0o000 | 0.0000000 o. ooooooof o. ooo000o I o. oo000o0
vsnadlum Irt, .4gz 0.0000000 I 0. ooo00oo 0.00052001 o. 0000000 I -0.0000600
zine [213.856 0.0000000 | 0.0000000 0. o0oo0ool 0.0000000 | o. ooooooo
Form XI (PART 2l IN
B7
Corunents:
STL Denve
STL DETVVER
'fotal Metals Analvsis
-l lB-
I CP INTERELEMENT C ORRECTION FA CTORS (AN}ruALLY)
Contraet r EBS Corrcoration , ,- , ,,. ,_..
r,ab code 3 STTDEN cag6 No.:gAg No. t
ICP rD ![umbor: SUPERTR.a,CE Datet 'l/23/2AOS
gDC NO. : D5I090L76
wavo-
lengrtb
(nm)
fntcrclcmaat, Corractlon Faetor for:
Anallt6 [.hvZt
rlumtrxun 1308.z1.rr o. 02 L6700 I 0. 0000000 o.orooiool
Antlmony I 206.838 0.00ooooo I 0.0000000 o, ooooooo I
trgenlc I rar .otz 0.0000000 | 0,0000000 o . oo 00000 I
Barium I {93 .409 o-oooooo0 I 0.0000000 o. ooooooo I
Ber,rJrlllum laff .A$2 o.0001800 I 0.0000000 o . oo0o0oo I
Boron I ro9.67g 0.0000000 | o.00o0ooo o. oooo2oo I
Cadml.r.rm _226. 502 o. ooooo00 I 0.0000000 o. oooooool
calcLnn I 319.933 0.0000000 I 0.0000000 -o. oo17700l
ctrrornLurn lZ67 .7 !6 0.0000000 I 0-00ooooo o.oooooo0l
cobalt 122s.616 0.0000000 I o.ooo000o o.oooooool
fconner Jrza.753 0.0000000 [ o .0000000 o. oozlsoo I
'rron lzr 1.4c1 -0.53,07500 | O.00ooooo 0-00{5?601
r,sad lzzo . 3 sL/ L 0.0000000I o.ooooooo -o . oo3 55oo I
Laad lrr0.3 sLtz -0.0003200 ] o. 0000000 o .0oooooo I
Masnesiwn |.279.028 o. o0000oo I 0.0000000 o.o0oooool
Manganeso lzsl.610 0.0000000 | 0.0000000 o . oooo0oo I
lrolybdcnuln laOe - 030 0.0000000 | 0.0000000 o - ooooooo I
rsl ckal lrtl . 6 ot / z 0.00o0ooo I o.00ooo00 o . 0oooooo I
sclaniuur 1 196.02L/L 0.0002100 I o. o000oo0 -0. a2793ool
selenLum Itg5.02L/2 0, o0oo000 J o. oooo00o -o. ooo24ool
sllLcon
1
e88.158 0.0000000 ] 0.0000000 o. o00oz0ol
silver I
gr8.068 0.0000000 f 0 .0000000 o. ooo3{90 I
Strontsium 1121. 5s2 o.0ooo00o I 0.0000000 o . ooooo oo J
rhalllum I 190.86{0.0011?00 I o.ooooooo -0. ooo17o0l
rborLum I oO1.9t0 0.00o2ooo ] 0.0000000 o. oooooool
rln I te9.989 o .0000000 I o. oo0o000 -o.ooorrool
rltanlrrm 133{.9d1 0.0000000 I 0.0000000 o, oooooool
Uranium Iass.e58 -0 .0090?oo I 0.000oooo o. ool2oool
vanadlum lzg2.402 0.00o0ooo J o. 0000000 o.oooSgool
zinc\I ,t3 . Bs6 0.0000000 | 0.0000000 o. o0o093o I
Form XI (P.LRT 2l -IN
1BB
comnentg:
STL Denve
STL DEN-}/ER
gTLDIN Cage No- 3
ICP ID liltrmbcr;TirA rnrrcDtd rcP
Total Metals Analvsis
-12-
ICP LINEAR RANGES (OUARTERI,Y)
AtS No. t
Datcr 8lL6l2AAs
SDG, NO. r D5I090176
Contrrcts r
Lrb Codcr
IIRS Corlrontion
.}nalft,c
fntcg.
rLruc
(Src. )
ConconEratlon
(ug/L)
!,1
f efrunlnun Lo I 60.00 fr
[nlunrinunr Ht I 20,00 100 0 Ir
lCa1.eirrn lro 20-00 50 Jn
I Celcium Hi 20.00 2000 Jn
I lron Lo 20.00 Jr
I lron EL 20.00 2000 lp
I Pota;aiurn 20.00 500 Je
JMagrncalurn 20.00 2000 Ir
J Sodturn Lo I 20.00 10
Jsodirrn Hi 20,00 t 10000 Jr
lzlfconnrrnr 20.00 50 In
Comment,s r
STL Denver Font XIf fN 189
STL DENVER
Contrrct t IIRS Corporetton
Total Metals Analvsis
'12'
ICP LINEAR RANGES (QUARTERL}O
SASI No. :
Date = 7 l22l2AO5
Irab Code : STITDEN Carc No. r alxl No. r D5I090r,75
ICP ID !ftrnbcr r SUPERTRACE
.f,nrltta
Inbeg.
Tlrar
(Sec - )
CorrccntraELon
(Eglr.)
D[
] rrarlnLe 15.00 20 Ir
JBe.rirun 15.00 25 Ir
lChromlurn 15.00 50 Jr
J Coppar 15.00 50 Jn
Jflcad 15.00 100 lr
J![rcke1 15.00 s0 Jr
JveardLum 15.00 50 Ie
I ziac 15,00 50 Ir
O"rr.ntsr
STL Denver For:n XII - IN 190
STL DENVER
Contraet: IIRS Cor5rcration
Lrb Codc g STLDBI Cage No, :
reP rD Nrrubar: pB fCpMA
'fotal Metals Analvsis
'12'
ICP I-,INEAR RAT\IGES (QUARTERLY)
g.},S No - :
Datcr 8 lLg l2OO5
sDCl No. r D5f09AL76
earl.ytc
Intclf .
Tl-ura
(8rc. )
Coneontrat:[on
(nglL)t[
I caandr:ra I o. oo1 I t lul
J sclcnium I o, oo1 I 4 lnl
Comrrrnta r
STL Denver Fort XII IN 1,9L
STL DEIVVER
Total Metals Analvsis
13-
PREPARATIONLOG
Coatract 3
Lrb Codcr
Mcttrod: P
IIRS Corporatl.on
STLDEN Cege No. r gfS No. :8DG No.r D5f090176
Prcp Method:
Serplc ID Prcprrat,Ion DrEc
rnl,tlrl volume I rlnal
I volunc (nL)
GTr- se- 09 0 805 9 /23 / 200s 50.0 I so.o
GW-R2 -090 805 9 /23-1200s 50.o I 50.0
Gw-s5- 090805 9/231200s 50.0 I 50.0
GI$I-{.},-090805 9 /23 /2005 50.0 I so.o
Gr{-so-090805 9123/2005 50.0 I so,o
Glr-Rr-090805 9l23t200s 50.0 I 50.0
Grlr[-R3 - 090 805 9 t23 / 200s 50.0 I 50.0
fNrlRA-f,.LIl 0C st23t2005 50.0 I 50.0
I{TB MSi e /2312005 50.0 I 50.0
I,AB MSD 9t23t2005 50.0 I 50. 0
rrB52 65237 e12312005 50.0 I so.o
EHECT( SAIIPIJS 912312005 50.0 I 50.0
Conments:
STL Denver
FOnT XIII I}I
L92
STL DEIYVER
Total Metals Analvsts
13-
PREPARATIOI\i LOG
Contract r
Lab Codci
M.thod s
IIRS CorT>oratlon
STLDEN Cagc No. s
gAg No. r gDGl lso.r D5IO9O175
glr PrcD Mcthod:
Saryllo rD Prcparatioo Drtr
rnitial Volumc I rl"nal
I volurtc (nrr)
IfffRA-LA'Il QC 9/231200s 10.0 I 10.0
I.AB Mg 9123/200s 10.0 I 10.0
T,NB MED 9 /23 / 2005 10.0 I 10.0
GTf-5c-090805 9 /231200s 10.0 I 10.0
gvir-Rz-09080s 9 /2312005 10-0 I 10-o
G$r-Ss-O90805 9/23/2005 10.o I 10-O
crr-4},-090805 9 123 1200s 10.0 I 10.0
Glrrr-94-090805 9t2312005 10 .0 I 10.0
GW-R4-09 080 5 9/23/?00s 10.0 I 10. 0
GV{[-R3 -09 0805 9 123/2005 x.0 .0 I 10.0
MB53 59437 et23l200s 10.0 I 10.0
CIIECTT SIITPLE 9t23/2005 10.0 I 10.0
Comaata:
STL Denver
PorM XIII - IN
193
STL DEIVVER
Total Metals Analvsis
13-
PREPARATION LOG
Contrrct r
Lab Codcr
Mctlrod,:
IIRS Coriporrtion
STITDEN Cerr No. r SASI No. r sDo tro.r D5I090175
MS Prell Mothod:
Sarnrr1e ID PrcDaratlon Datc
fnLtial Volumc I FJ.naI
I volune (nL)
GriI-5C-090805 9/23/2005 50.0 I 50.0
GTII-R2-090805 et23/2005 50.0 I 50.0
GW-Ss-090905 9 / 2s tZOOs 50.0 I 50, o
GTr-4r-090805 e/23t2005 50-0 I 50.o
GT[-S{-090905 9 lz3 /2005 50.0 I 50,0
Gri-R{-09080s 912312005 50,0 I 50.0
csr-R3 -09 0805 e/23/200s 50.0 I 50 .0
rlwrnA-LnB Qc 9 /23 /2005 50.0 I s0.0
IJAB Mg et23/2005 50.0 I 50.0
L}.B MSID 9t23/2005 50.0 I 50.0
I'I852 6519 3 9 /23 /200s 50.0 I 50.0
CHTCK SIMPLT 9/23/2005 50.o I 50.o
Cormontg r
STL Denver
Form XfIf IN
i94
STL DENVER
Total M-lils Analvsis
AI{ALYSNRUN I,OG
Conbract:
rab Codar
fnctrun,ent
Start DaEe:
URg Corporetion
STLDEN
ID lfunrbcr r
9/26/200s
Ca;c No, t
TiIl' fntrcpid ICP
gtg No.:
Mathod,r
End Dare: 9 /26/2005
gDO No.: D5f09AL75
* Denote g addltlonal elmeabr
STL Denver
(oLhcr than tbr rtaadard CLrP rlrurntr) ar. rcprrronted oa eaotbcr
Foru, XfV IN
1t
Samp].o
ID.
Dlv Tlmc e6R
IlnrJ.ytrr
Stdl-Blank 1. 00 09 : tl1 x x x x x x
rcn&1 L. 00 09:O5 x x x x x x
rCTLz 1- OO 09t5O x x x x
ICAIJ]-1. OO O9:53 x x x x x x
ICAL2 1. 00 O9r57 x x x x x x
Ig\ItI 1. 00 1O: O2 x x x x
Ig\ItJ 1. OO 1O: O6 x x x x x x
cg\m 1. OO 10r11 x x x x
CC'\8,1. OO 1Or15 x x x x x x
ICB 1- 00 1O:20 x x x x x x
RI,STD2 1- 00 10 :2{x x x x x x I
rCgA 1.00 1Or29 x x x x x x T
ICSA.B 1. O0 1Or3{x x x x x x
cc,\nt 1.OO 10r39 x x x x
eeuL l_. oo 1Or{3 x x x x x x
CCB 1. O0 1O:08 x x x x x x
CgUH l-. oo 2Or35 x x x x
cgvlt 1.00 2Or39 x x x x x x
ccB 1. O0 2Or4{x x x x x x
ZZZZZT.1. O0 ?Or{8 tl t
ZZT,ZZZ 1-OO 2O:53
MB52 65237 1. O0 2Or58 x x x x x x
CHECK S}ITPLE 1,00 2LtOZ x x x x x x
ItirrRl'-L,AB QC 1.00 21:07 x x x x x x
MrRr-r,AB QC sER 5, 00 21:12 x x x x x x
ITAB MS 1. OO 21r16 x x x x x x
IJAB MSD 1. 00 2Lt2]:x x x x x x
Glil.5C.090805 1. 00 2L:76 x x x
sur-Rz - 0g0g 05 1,00 21r31 x x x x x
CC\M 1.00 21:36 x x x x
cgur,1. O0 ?1:41 x ix x x x x I
CCg 1 .00 21r46 x x x x x x
GW-s5 -0908 05 1.00 2X. r 51 x x x x x x
Forzt
195
STL DENVER
Total M.jil: Analvsis
AI\IALYS$ RUN LOG
Contsraet:
I,ab Code :
In;tnmcnt
Stlrt DaEe:
IrRg CorX>oratl,on
g:rI"DEN
ID $Itrmbor r
9126t7005
Cr;o No. t
T,IA Intraptd ICP
8Ag No. r
McEtrod:
sDo No- : D5I09077 6
t Dcnotor ad&itlonal rlmrntt
STL Denver
und Drtor 9 126|2AAS
(othcr tlran the rtaadard CLP elenenta) ilrc roprooonted on aaobher Fom lt
saql)Ie
ID.
Dls TLme IR
Ina]-rrtseg
.L
L
g
B
I'
a
B
A :f;c
A
c
R
c
o
c
U ;J:M
GI
M
N :lr K s
E
A
o
N
A
T
L
v z
DI
e
N
Grs-{A-090805 1. 00 21r56 x x x x x
(Ier-s0-090805 1. 00 22: OL x x x x x x
fir-R4-0g0g05 1.OO 22tO6 x x x x x x
GTr-R3 -090905 1. OO 27 tLL x x x x IE x
zzzzzz 1. OO 22 116
zzzzzz 1.oo 22 tZL
T,ZZZZZ 1. OO 22 t25
ZZZT.Z7,1. 00 22r30
7,7,ZZZZ 1. OO 22 t35
EE\IH 1, 00 22t(O x x x x
Cg\TT,1. OO 22t44 x x x x x x
ceB 1. OO 22t49 x x x x x x
Pora XMN
L96
STL DEIVVER
Total l\'Ietals Analvsis
-14-
ANALYSIS RTJIY LOG
Contract:
Lrb Codcr
fngtnrncnt
Start Datse:
IIRS CorporatLon
STI,DE![
fD Ntrrnber:
91261200s
Carc No.:
TifA fntrcptd ICP
SAg No. r
Mcthodr
li:nd. Datl r
Dsrog0L76
9 /26 t 2005
8aupIc
rD,DI?fine esR
.lnalyt,eg
B A
u
L
I
Id
o
o
g
P
D
P P
T
s
I
s
Ir,
s
R
U w I
N
T
H r"
gt,d,l-B}rnk 1.O0 O9: tt1 x
rgl,Ll 1.00 O9:45 x
ICAL2 1.ool 09:50
ICALl 1.00 09r53 x
feAlrz 1.00 09 ;57 x
rc\nr 1. O0 10r02
rc'\E 1.00 1OrO6 x
CClIH 1- od 1O:11
cg\rrr 1. OG 1Or15 x
ICB 1.O0 1Or2O x
RITSTD2 1. 00 7.O t 2L x
rcsJ[1. 00 10:29 x
ICSTA 1.O0 10r34 x I
CC,\rH 1.00 10t39
cc\II,1- od 1O :,03 x
ccB 1. O0 1Or48 x
CC\TH 1.00 2Or35
csuL 1,00 2O:39 x
eeB 1 ,00 20:{{x
7r7.7.7.7r7t 1.00 2O: 18
Z7,ZZ7,Z 1. O0 20r53
MB52 55237 1. O0 20r58 x
CHECK S}D,IPLT 1.O0 2Lz02 x
IlWrRI.-rrAB AC 1. od 21r07 x
rI{IIRA-LAB QC gER s. ool 2t-zLZ x
IrRB UB 1. od 21:16 x
IrtrB ttlgD 1.00 21r?1 x
G*r-5C-09080s 1.00 2L 226 x
cw-R2 - 09o805 1.00 21:31 x
eevH 7 .00 2t :36
cc\rr 1.00 2Ltlt x
CCB 1. ool 21r46 x
GTU-S5 - 09 08 0 5 1. 00 21r51 x
cfl-4n,- 0g0g 05 1- 0d 21r55 x
STL Denver Eor:ur XIV - IN ]-97
STL DENVER
Oconr,rf,cr r ,RS corporarLon
Total Metals Analvsis
-14-
ANALYSM RTIN LOG
Irab Code : SffrDElI Cere No. t
Ingtnurcnt fD N\rrnbar: Tiff, fntrcDid ICP
SAS No. t
Dlethodi P
End Date : 9 126 /2005
SDc No. r D5f090176
Sary>le
ID.DI?TLns ,6R
.Lrralftes
B I
U
L
I
![
o
o
a
P
D
P Pr
g
r flil['n.T
E r"
cxr-Er{ -o908 05 1- 0d 22:01 x
Glr-R4 - og 0g05 1,00 22:06 x
cw-R3 - 09 08 05 1. 0d 22:.LL x
zzT,zzz 1,0c 22 tL6
zzzzzT,1. OC 22 tZL
zzz7,z,z 1-OC 2? t25
7r7rTr7r7rz 1, ool 27 e3O
7rl7r7r7r?r 1.ooi 22:35
cclrH 1- 0d 22t4O
eg\rL 1,0c 22241 x
eeB 1-od 22:49 x
STL Denver for:n XMN 198
STLDENWR
Total M-jils Analvsis
ANALYSIS RUI\[ LOG
Contraet:
f,ab Codc r
Instsrumsnt
SEart Dat,e r
IIRS Corporatl,on
STLDEN
ID ![\:rnbcr:
e /27 12005
Cagc No. I
TirA Intrepid, ICP
gAA No.:
Mcthod s
End Date; 9 /2812005
SDo No- r D5I090176
Sa:rglIe
ID.
Dlf Timc %R
lnr1ytcs
.t'
L
g
B
A
s
B
I
slc
"1,:l :l;l;ffiTTIrlrlrl"lil;
Std1 -BIa"nk 1. o0 15r00 lx x x
IC-IL].1.00 15: O{x x x
ICAITZ 1 ,00 15: 08 Ix x
ICAL1 1. O0 15:12 lx x x
ICl,Ir2 1.00 15r15 x x x
IEVH 1.00 15:21 x x
I(IJ.I,1 ,00 LS t25 x x x
cc::TITI 1. O0 15r30 x x
cg\Ir,L. oo 15:35 x x x
ICB 1. 00 15:39 x x x
RITSTD2 1. 00 15r43 x x x
ICSA 1.00 15:EB x x x
rcs.nB 1. 00 L5r53 x x x
cewr 1. o0 15:58 x x
CC\TL 1. OO 15: O3 x x x
eeB 1. OO 15rOB x x x
eg\ru 1. 00 O1: O5 x x
cgvr,1. OO O1:09 x x x
ccB 1. OO 01 :1{x x x
G*r-R2 -090805 10. 00 01:18 x x x
GTT-{A-090805 10.00 01r23 x
Z7'7r7rZZ 1.00 OL t27
Z7.7,ZZZ 1. O0 O1:32
zzzzzz 1. oo O1 r36 -]
CCTfH 1. 00 O1 :{0 x x
cc'\rL 1. OO O1 : t[5 x x x
CCB 1.00 01r49 x x x
r - IrsroEGa addltional aldartB (otbor thaB th€ etr.Edlardl CI:P ol@.Dtt) a!. reDror.lt.d orir rtrothor Eon 1l
STL Denver
for.lr XIV - IN
]-99
STL DEIVVER
Total l\I-:if; Analvsis
ANAI,YSIS RIIN LOG
Contract r
Lab Coda:
Inctnrnoat
Start Dltc r
t Rg Cor.5roratLon
STLDEN
ID !firmbcr r
9127 l2AO5
Cago No.:
SUPERTN.LCE
S.ng No. t
l{cBhod r
gDc No.: D5I090176
P
a
STL
Deuotca addltlonrl elslcatt
Denver
End Date z 9128|?OOs
(othrr thau Ehr rtaadrrd eLP eleoonts) lro roproaosted oa +notbrr Potl 1rt
gaqD,le
I,D.
Dlv Tl-no tR
BTD1-BI,an}E 1- OO 1{r31 x x x x x x x x x
HIgIrD 1.00 1{:36 x x x x x x x x x
HIOH 1, O0 LtL z 12 x x x x x xl x x x
rg\r1l|1- OO Llt47 x x x x x xl x x x
CCTT 1. O0 1{:53 x x x ,(,x.x x x x
rcB 1. O0 14:58 x x x x x x x x x
RLSTD 1.O0 15;08 x x x x x xi x x x
ICSA 1. o0 15 :13 x x x x x x x x x
rcs.trB 1.00 15 :19 x x x x x x x x x
tR 1 .00 15r24 x x x x x x x x x
cc'vr I 1 1. O0 LS t29 x x x x x x x x x
ccBl1.1, 00 15:35 x x x x x x x x x
cc-\m I ar 1. 00 07:{9 x x x x x x x x x
ccB I er 1. OO O7 r5{x x x x x x x x x
MBs2 65237 1. O0 07r59 x x x x x x x x x
CHECK SAIIIPLI 1.00 08r03 x x JC x x x x x x
zzz.zzz 1. OO OSrOB
rDErRt-r.tB 0c 1-OO O8r13 x x x x x x x x x
IlilTRl'-tnB OC gtR 5 .00 08 :18 x x x x x x x x x
rleB D!8 1 .00 08:23 x x x x x x x x x
IJAB DISD 1 .00 08 :28 x x x x x x x x x
7,ZZZ7,Z 1, OO 08:33
zzz?,7.2 f.. oo O8:38
7,227,27.1. O0 08 r{3
cclm 122 1.00 08 :18 x x x Ix x x x x x
ccB lI22 1. 00 08:53 x x x x x x x x x
zzz,zzz 1,00 08:58
l.tIrIr'ltl,X 1. 00 09r01
zz7,z7,z 1.00 09: 08
Z7,Z7.ZZ 1.00 09:13
7,ZZZZ7.I- .00 09:18
zz7,7.zz 1 .00 09r23
717iZ.7,7,7,1.00 09r28
Form XIV - IN
204
STL DENVER
Total *-1ff Analvsis
AITALYSN RIJN LOG
Contract;
f,ab Coda:
Inatnrmant
Start Datsrr
URS Corporation
STLDTN
ID Nuruber:
9 t27 /2005
Casc No.:
gUPERTRACE
S.l.sI No. t
tlcthod r P
End Dare: 9 12812405
(otsber tsha-n tho rta.ude,rd cLP elenonEt) aro ropr.r.otod oa anoth,or Fom 10
gDc No.: D5I090L76
| f,buotes edditiour,L slcnrnt,r
STL Denver
r[ s Il I sls lcl cl clcl clr I pl!{lulHlNl rlslAlul Tlvlzl c
r, l s ls I alE lDIel nlolulu I BlolNlol rl Itlcl.Ll r, I INI N
sanplc I ott Jrlne l%R
09:33
09:38
Gri[*5c-090805 O9r63
(IIil-Rz - 09 0805 O9r48
crw-ss -09080 5 09r5{
cfl-{1,- 090805 O9 :59
e{-ac-090905 1Or0{
s{-R{-090805 10:09
GH-R3-090805 10:1{
tO:19
LO:.ZtL
Form XfV I}[
207
STL DENVER
Total llletals Analysis
-3-
BLANKS
Contract r IIRS Corporetion
Lab Codcr STLDEN Caac No.:S.Lg No-:
Prel>antLon Blnnk Matrix (roLl/watcr) : WITER
Prcarret,Lon EhDk Couce[trrtlon ltnite (E{,lL or D{,lt!9l: ![G./t
8Ds No. r D5f090175
.Lrrelyta
rnltl.al
Crll,lr.
Blar]E
(mg lr.>c
Coatinuing CrlLbrltLon
Blrrrk (mg/Ir)
1 c 2 c 3 C
Prc1raraELon
BLank
c M
Mcrcurlr I -0.0000511 B O.000062 I B I -0.00006118 I -0.000050 I B 0-000046 I U Ctr
STL Denver Fom, III IN
138
STL DEI{VER
Total M.1il: Ao"Ivsis
ATIALYSH RUN LOG
Coatract:
f,rb Codc r
Inrtnrmcnt
Strrt Date:
IIRS Corporat,Lon
STLDEI{
fD ll\rmbcr t
9123t200s
Caac No. t
PE SIIIA
gl,S No. :
Mctlrodr
SIXI No. r D5I090176
S
* Deaotor additlonal thmrratr
TL Denver
crv
End Datcr 9l?3l2AO5
(other than tho rtandard eLP thuoutr) ar. rcDr.tiotrd ou anobhrr Fort 1{
satnpLc
ID.
Dlt Tlno 96R
tna].ytrr
A
L
s
B
A
g ilt c
D
c
.n,
C
R
c
o
C
U
r
IE
P
B
M
o
u
N
H
o
N
r
K s
E
I\
c
til
.tr
T
L
v 7,
N
c
N
Cr1l,b Bla^nJE 1- O0 15r52 x
a.2 PDb 1.O0 15: 5{x
0.5 DDb 1. OO 15:55 x
1.0 DDb 1. OO 15r57 x
2. O 1r1rl)1. OO 15:59 x
5. O DDb 1. O0 16:01 x
10.0 DDb 1.OO 15r02 x
ICB 1. O0 16:O5 tl x i-fr
rg\r 1. OO 16r06 x
cg\r1 1.00 16: O8 x
CCBI'1- OO 16r10 x
Rtr 1. 00 16r11 x
T,ZZZZZ 1. 00 15:13
Z.7.7'lr7'7.l. 00 16:15
7rZZ7rZ7,1.00 15s16
27,27,7,7,1. O0 16:18 t-t
7'7rZZ7rZ 1- 00 16:2O
Z27'27,2 1 .00 16:21,
zzz7.z%1- OO 15t23
zzzT,zz 1. 00 16 :35
7.ZZZY.Zr 1.O0 LG 277
cgv2 1, O0 16:28 x
CCB2 1. O0 16:3O x
ccvS 1. 00 17:{9 x
CCB6 1. O0 17 r 51 x
zz,zzzz 1. O0 17r53
zzztzz 1, OO L7 t5d,
T,T,LU],1.00 17r55
Z7,7,Z7.Z 1. 00 17 :58
Z,ZZ7,Z7,1. 00 17 :59
7'7t7r7rZL 1. 00 18 :01 /
7rYr7rL7r7,1, 00 18;03 T
7,27,2%7,1. O0 18:0{I -l
Forn XfV IN
202
STL DENVER
Total Metals Analvsis
-14-
ANALYSIS RUN LOG
ContracL:
Irab Code :
Ingt:nrnant,
8trrt, Data:
IIRS Corlrorat!.on
gTLDEN
ID lihrmber:
9/23t2005
Caee IiIo. :
PE CVEA
glg No.:
Method,:
sDG No. r D5I090176
gtr
t - Druotca addltlonal elennutr
STL Denver
rrrd Drte r 9 123^ l2AAs
(othcr tlua tbr rtandard etP elenentg) aro rrprcrcutrd on anothor Foru 1{
Srmpl"c
rD-
Dlt Tlma 96R
Analt&as
l'
IJ
g
B
.L
I
B
^L
B
E
c
D
c
.1,
c
R
c
o
c
U
f
E
P
B
![
o
M
N
H
e
![
I
K g
Dv
.['
GI
N
A
T
L l"l
7,
N
c
N
r.r85259{37 1. O0 18r05 x
CHECK BTMPI.IE 1. O0 18r08 x
cc\r,1.00 18:1O x
ccBT 1.00 18 :11 x
Z7r?rZZ7.1- OO 18r13
zT.z7.zr,1.00 18:15
r!*rR.L-r,.AB AC 1. O0 18r16 x
IJ}B Blg 1- 00 18r18 x
I.AB TISD 1. OO 18r20 x
7.ZZ7r7rZ 1. OO 18r21
Z7r7r7^7,2 1.00 18r23
zzzzzz 1, OO 18 :2{
7.227.27.1.O0 LB 226
GDr-5C- O9 0805 1.00 18r28 x
cgvE 1. OO 18 r29 x
CCBg 1. 00 18:31 x
orrr-R2 - 090805 1 .00 18:33 x
cilil-ss-090E05 1. OO 18r35 x
GT[-O.n -O9 0g05 1- OO 18r36 x
cilil-s{ - 09 0805 1. 00 18: 38 x
Grrr-R{-090805 1. 00 18: t0 x
GH-R3-090805 1. 00 18 :41 x
zzzzzz 1. 00 18r43
zzzT,zz 1. oo 18r45
7r7r7r7rzz 1. OO 18r46
ZZTrT,ZZ 1 .00 18 rd8
cev9 1,00 18r5O .l I
CCT9 1 .00 18r51 I
Foro XIV IN
2A3
STL DEIVVER
Total *-jlf Analvsis
ANAI,YSIS RUN LOG
Contract:
LrI) Codc r
Inctrunent
Start DaEe:
t RS Corporatslon
STI,DEN
fD Mrubar:
9 /25 /2005
Cagc ![o. r
PE ICPIIIS
8lg No. t
Dlctrlrod r
gDc No.: D5I090176
M
S
t Denotes addltLonal ohueutr
TL Denver
nnd Drto3 9 l2l lz00s
(otlrer than the standard eLP alernents) aro r.opros€nted on anothtr Pom Lt
8a4pLc
ID.
DIE Tlme tR
Analytca
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ttla
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BIrnk 1. 00 L7 tt6 x x
Standard 1 1 .00 L7:49 x x
oc aE,d 1 L-00 17r53 Ix x
0c srd 2 1. 00 L'l :57 x x
Rt gTD 1- 00 18rOO x x
zz?.7,Z,7,1.00 18 r 04
ICgA 1- OO 18r08 x x
rCSAB 1.00 18 :11 x x
RINgE 1-00 18:15 x x
HIGH CHTCK 1- 00 18r19 x x
RINSE 1. oo LB t22 x x /
QC srd 3 1.00 18:25 x x T
QC SUd {1. 00 18:30 x x
BLarrk 1- 00 19: 17 x x
Standard 1 1,00 19:21 x x
ac srd 3 1. 00 19 :25 x x
ac srd I 1. 00 19:32 x x
oc sr,d 3 1. 00 22tOB x x
aq std, 4 1.00 22:L2 x x
ICg.n'1. OO 22 tL5l lx x
IESAB 1.00 22 r19 x x
RINAT 1. OO 27 r23 x x
ac srd 3 1. OO 22 t27 x x
oc sr,d 4 1- OO 22:34 x x
BIarr]tr 1. 00 2223L x x
St,andard 1 1. 00 22r38 x x
0c srd 3 1, 00 72t41:x x
0c sEd 4 1,00 22r15 x x
ac sud 3 1.00 05 ;02 x x
ac 8ro {1.00 05r06 x x I -l
7,D5T220000-1938 1, 00 05r09 I
1D5T220000- 193C 1. O0 05: 13 \
st0-5c-090805 20.00 05r17 lx x
forn XIV - IN
204
STL DENVER
Total *-1lf Analvsis
ANAI.,YSIS RUN LOG
Contract:
Lab Codc:
Inrtnuncnt
StarE Datcr
t Rg Cor2oratLon
gTI,DEN
ID Nunbcr:
912612005
Caaa No. t
PE ICPUS
Sl8 No. r
DteEtrod:
End Dater 9 /27 l2AA5
SDO No. t
IrI
Dsrog 0 L7 6
Sarq1>Ic
ID.
DI?Elmrl qrR
Inalfrts61a
I
t :lllil:l;l:l :I;I;I l"l;lr
g{-Rz- 09 08 0 5 10. 00 05 :2O x x
ow-s5- 0908 05 5. 00 O5r2{x x
cw-or'- 09080s 10. oo OS t 7,7 x x r
crlr-84-090805 5.00 05 :31 x x
G'n-R{- 0908 05 5.00 05r35 x x
crr-R3-090905 5, 00 05r38 x x
QC strd 3 1. oo 05r42 x x
0c grd I 1. OO 05r{5 x x
r - Delotes rdir,tiotral .I@at. (otler thalr tb. rEal6lril eLP elm.at3) .r€ !.Dr.r.Et.dl oa r.aothcr Fm la
STL Denver
Fom XIV - IN
STL DEIVVER
Total *-j1j1 Analvsis
AhIALYSIS RUIY LOG
Contraetr:
rab Codar
InsErrrnents
Etart Date:
IrRS Cora>oratLon
gTLDEN
fD NUnbcrr
s /27 t200s
Crtc No. t
PE ICPII8
gAS No. I
Mrrttrodr
SD(I No. r D5I090176
M
S
i Druotea addltlonal rlrotp,ta
TL Denver
End Dat,cr 9 /27 /2005
(othor thin tha rtandard CL,p rl.oorotr) ar. rrprorntod on anothcr foru 1{
flrqrlc
ID.
Dly Tlmc e6R
lrralf.tscr
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Bla.n.lr 1. OO 15:58 x x
Etnndls{ 1 1, O0 16r02 x x
QC slrd L 1. OO 15r06 x x
ac srd 2 1. o0 15rO9 x x
RLSTD 1- OO 16r13 x x
Z,ZZ7,ZZ 1. OO 15r17
ICSA 1- O0 16r20 x
I
x
ICBAB 1. O0 L6 224 x t--x
R.rNgE 1. O0 16:38 x x
HIOH CTIECK 1. OO 15:31 x x
RINSE 1. OO 16r35 x x
ac srd 3 1. O0 16: 39 x x I
ac srd {f--oo 15r42 x x
Blarrts 1- OO 17r15 x x
Eltandard 1 1. O0 17 :19 x x
QC sr,d 3 1. 00 L'I t23 x x
QC std I 1. 00 L7:27 x x
QC srd 3 1.00 L9 t3'l x x
oc gtd, tL 1. OO 19r40 x x
HB52 65193 1. OO 19r{{x x
CHECK SAMPLE 1.00 19: {8 x x
Z7,Z7,7,Z 1 .00 19r52
ilurn.L-rJAB Qc 1. OO 19r55 x .t x
IIIIIR.L-L]B OC SER 5, 00 19 :59 lx x
r}f,rnA-LlB oc PDS 1. 00 2AzO2 x x
I,AB MEI 1 .00 20r06 x x
LtrB MSD 1.00 20r10 x x
\LY,\T,L 1.00 20 :13
0C st,d 3 1.00 2O:t7 x x
QC Sud I 1. 00 ZO tZL x x
oc sbd 3 1.00 2L;58 x x I
ac sEd I 1.00 22tAZ x x
rcs.L 1.00 22:06 x x
fom XfV fN
2A6
STLDETVWR
Total M-jil: Attalvsis
A}IALYSIS RUN LOG
Contract:
Lab Codcr
Inrtnrment
gt,art, Dat,c:
URS Corry>orrtion
STLDEN
fD Nunberr
e/27 t200s
Cage AIo. r
PE ICP!{g
Sl^8 lilo. t
Mctlrod r
sDO No.r D5I090175
DT
tr
STL
Deaotu edditlonal elenentr
Denver
Ead Darar 9 /27 l2OA5
(other tbrrn tbr rtandrrd Crp elenrnt;) arr r.Dro;oaEod on cnother Fora t{
8rm5l1c
rD.
DI?rLmc TR
.[nalyteg
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II
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tnI
L
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N
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ICgAE 1. OO 22:09 lx x
RINSE 1-OO 27 tL3 xl x __I
oc sbd, 3 1. 00 22:L7 xl x
ag sEd t 1.O0 22 tXL xJ x
Form XfV fN
207
},IETEOD BLANK REPORT
General Chernistry
Clisrt IoE # -
PAITJII\4ETER
: D5I0 9 01-7 5
RESI-ILT
REPORTTNG
LIMTT UNITS METHOD
l{atri](. . . . , . . . . r WATER
PREPARATTON- PREP
AI$AIJYSIS DATE BATCH #
Ammonia as N
Ammonia aE N
Chloride
Fluoride
Ni t rate
Ni t rate
Ni t rate -Nitrite
Nit rate - Ni tri te
Su]-fate
Work Order #: HLJ851AA
0 .10 mg/L
Dl luE ion Faet,or : L
Analysis Time.. r 22.Qa
Work Order #: HKXST1AA
2 -5 nry,/l'
Oi luU ion Factor : l-
Analyais Timrg. . : i7 : 00
Work Order #: HI(LK7lAA
0 - 10 tDg/L
uilution Factor: I
Analyole Time. . t 13 :15
W<rrk Order #: HK7L21AA
0 . 10 mg/L
Di 1ut ion Fact or : l-
Analyele Time. . : l-5 :00
Work Order #r HLLMMI-AA
0 .10 mg/L
Dilution Factor: 1
Analyois Tirne. . : 16 : 00
Work Order #: HKTHEI-AA
0.10 r;rg/L
Dilut ion Factor: 1
ArraL)rsle Tlme. . : 22 z 0O
Work Order #; HLLD91AA
0.10 rng/L
oiluEion Factor: I
Rnalysis Time. , ; IB :00
Work Order #: HLL531AA
5.0 v, ,/L
ollution Pactor: 1
Analr*eia Time. . : 15 : 40
MB LoE-Sample #:
ucAtrw 325 -2
D5I200000 -255
a9/ 18/05 s2632ss
ND
ND
Work Order #: HK6VPUTA MB Lot-Sample f: D5I22O00O-473
0.r.0 mg/t MCAWW 350.1 09/20/05 s255473
Dilution FacLor: 1
Analysie Timc.. t 22200
MB LoE-Sample #: DsI280000-454
MCAww 3s0-t_ 09/27/A5 527t4s4
1-8 B
0-019 B
MB Lot -Sample # :
}ICAIflI{ 340 .2
D5r140000 -s78
oglLLlos s2s7s78
MB Lot-Samp1e #:
MCAWW 353 .2
Dsr220000-sB5
ae / 09 / os s26ss86ND
}UD
ND
ND
MB LoE-SampIe #:
MCAI^IW 353 - 2
D51280000 -706
ae / ae / as s27]-7 a6
I"IB Lot - Sample # :
MCAI,ftI 353 .2
D5I220000 -552
ae / zo / a5 sz;sssz
I,IB Lot - Sample # ;
MCAWW 353 .2
D5r280000 -679
0e / 27 / 05 527L67 e
fqB Lot - Sample
ucA}Ir{ 375-4
#: D5I290000 -L72
oelzg/os szTzLTz
STL Denver
2.2 B
(Cont,inued on next page)
208
C].ient. I.ot #- - -:
PARAMETER
D5r090L76
REPORTTNG
RESULT LIMIT I}NITS
MHTHOD BI,ANK RBPORT
General Chernistrlr
METHOD
lilatrix. - - - - - : WA,'TER
PREPARATTON- PREP
ANALYSIS DATE BATCH #
Total Cyanide
I.IOTB (S)
=
9ilork Order #: HK35F'1AA
ND 0-010 mg/L
Dl lut ion FacE,or : 1
Analyslo Tlrne. . : LZzQ0
MB Lot-Sample #:
sw845 90108/ 9012A
Dsr210000-539
ae / ?L-ae / 22/ 0s s264s3e
Calculatioos are perforrned beforr rr:untling to avoid round-nff errors in culculrtal results.
B L*imated result. Result is less than RI..
STL Denver 209
T,JIBORATORY COIITROI, SAUPI,E EI''AIJUATION REBORT
General Chemiatrlr
Iot-Sauple * -
PARAMETER
pH
Ammonia a6 N
Ammonia as N
Chloride
Fluoride
Nit raE,e
100
t_00
: D5f09OL75
PERCENT RECOVERY RPD
RECOVERY LTMITS RPD LTMTTS METHOD
Matrix-- ----: WATER
PREPARATION- PREP
A}IALYSIS DATE BATCH #
Lot -Sarnple# : D5I090000 - 536
oe / ae / os szszs36
0e / 09 / 05 5252s36
; 15:43
Lot-Sample# : D5T,22000 A *473
ae /20 / os s26s473
0e/20/os 525547 3
: 22:04
Lot-Sample# : D5I280000 - 454
5271,454
527 L454
5255 5B 5
52655I5
I{o# r HKCTGIAA-LCS /trKCTGlAC-LCSD tCS
(gt L02) sw846 90408
197 Lo2) O-O (o-5.0) SWB45 9o4oB
ol]ution Factor; 1 Analyelo Tlme.
97
97
101
101
100
100
106
1-06
100
l-0 L
( go
(go
( go
(so
WO# r HK5VPLAC-LCS /ILKGVPIAD-LCSD LCS
l-10) UCAIII^I 350-1
110) 0.15 (0-10) I,ICAWI^I 350.1
oilutrion Factor: 1 Analysia time.
wo# : HLJB5lAC -LCS / HLJ8 s lAD- I,CSD LCS
l,Lo) ttCAVn^I 350.1
L10) 0.34 (o-10) MCAWW 350.1
Pilutlon Fact.or : 1 Analyal e rlme -
WO# ; HIO(STIAC-LCS/HI0(5T1AD-LCSD tCS
(go 110) ttCAWW 325.2
(go 110) o-62 (o-10) MCAWW 32s.2
t 22; OA
Lot-Sample# : D5T200000-255
oe/LB/as s26 32 5s
ae/LB/os sz632ss
Dilution Fact.or: 1 Analysis Time..: 17:00
wO# :HKLK7IAC-LCS/IIKLKTlAD-LCSD LCS Lot-Sample# : D5I140000-578
(87 - l14) MCAww 34a.2 og/t+/os s2s7s1g
(87 - 1,14) 0.0 (0-16) MCAWW 340-2 0e/L4l0s s257578
, DiluLion PacEort 1 Analyoio Tlme..: 13:15
WO# :HK7L2LAC-LCS/HK7t21AD-LCSD LCS tot-Sample* : D5I220000-s85
( se 1l-0 )(es L]-o) 1.4 (o-1-o)
Pilution Factor: 1
ae/27/a5
0e/27/0s
McAr/{t{ 353.2 A9/og/A5
MCAen^r 3s3.2 A9/09/05
Rnalyeis Time..: 16:00
Nit rate
97
97
NitraLe-Nitrite
96
95
( 85 110 )(Bq l"10) o.5t (o-1o)
uilution FacEor: 1
MCAhn^I 353 .2
MCAWW 353 .2
Rnalyeia Tirne. . : 16 :00
WO# : HLLMMI-AC-LCS/HLLMMIAD-LCSD IrcS tot -Sample# I D5I2800 0 0 - 7 A 6
ae/as/os 527l-7 05
09 / 09/05 52717A6
WO# :HK7HE1AC-LCS/HK7HE1AD-LCSD LCS tot-Sample# r D5I22000O-552
(s2 - L12) MCAWW 3s3.2 09/2A/05 526sss2
(92 - 1.t21 0.L0 (0-r-0) McAww 353.2 A9/20/As 525sss2
DiluElon Factor: i Anall,gir Time.. z 22:oo
STL Denver
(Continued on next page)
2LO
ffi CONTROL SAITTPLE EI/AI,UATION RBPORT
Genera1- freruistry
I,ot-Sauple *. . . : D5I0901,76
PERCENT RECOVERY RPD
PAIU\METER RECOVERY LTIvITTS RPD LTMTTS METHOD
Ni trare -Ni t ri te
99
99
Ma,trix-- ----: WATER
PREPARATION- PREP
AhTALYSTS DATE BATCH #
I{o# :HLI^D91AC-LCS/HLLD91AD-LCSD tCS Lor-Sample# : D5I280000-579
(gz L12)MCAWW 353 .2 09 I 27 / OS 527]-57 9
09 / 27 / 05 5271,67 9(gz Lt2) o.J.s (o-1o) McAWur 3s3.2
pllutlon Fact,or: 1 Analygis Time..: 18:00
sulfare wo#:HLL531AC-LCS/EIL531AD-LCSD tes Lor-Sample#: D5r290000-a72
i.03 (91 - 112) MCAWW 375.4 A9/28/05 5272A72
106 (91 - 112) 2.6 (o-r.s) MCAWW 37s.4 09/28/05 s272L72
DiLutioR Factsor! 1 Analyola tlme--: 1,5:40
Total Cyanide WO#:HK35F1AC-LCS/HK36FLAD-LCSD LCS r,ot-Sample*: D5r2L0000-539
L07 (89 - r-oe) sw846 g0]-oB/eotzL oe/2a-ae/22/os sz6453e
108 (89 - 10e) 0-93 (0-20) SW846 e0108/9012A 09/2l.-09/2210s s264s39
Dilution Factor: 1 Analysle Tlme..: L2:00
lsorE(s):
Calculatlons arc pcrlbrnrcrl bcforc rouudilrg to avoid nrunrl-off errors in calculated resuhs.
STL Denver 27L
I,ABORATORY CO}TTROL SAI{PT,E DATA REPOR:r
Gerreral Chemietry
totr-Sample #.
PARAMETER
pH
7 ,00
7.00
Ammonia as N
4 .00
4 .00
Ammonia a6 N
4.00
4 .00
Chloride
50 - 0
50 - o
Fluoride
s .00
5.00
Nitrate
0 .0500
0 - 0500
Ni trate
0 .0500
0 .0500
Nit,rate-Nitrit,e
4 .00
4 ,00
: D5I090l-75
SPTI(E MEASURED PERCNT
AMOUNT AMOUNT UNITS RECVRY RPD METHOD
tlatrix-- ----: WATER
PREPARATION- PREP
AIvLLY_9..T,9.-pIIF _ BA,rgI- . iH
LCS Lot-sampie# : D5I140000-578
340 .2 Oe /L4/ 05 s2s7s7\
340 .2 09 / 1,4 / A5 5257 57 8
Time..: 13:15
LCS Lot-Samp1e# : D5I22O000-586
3s3.2 o9/A9/A5 5255585
3s3.2 A9/09/As 5265585
Tlrne-., 15r00
LCS Lot -Sample#: D5T280000- 705
353.2 je/Ae/Os s27L7O6
353.2 A9/oe/os s27L706
Tirne..: 15:00
IrCS Lot-Sample# r D5T220000-552
353 .2 A9 / 20 / Os 526ss52
353-2 Oe/2O/Os sz6sss2
Time..: 22200
WO# ;HKCTGIAA-LCS/HKC7GIAC-LCSD LCS Irot-Sample# ; D5I090000-536
7.03 No Unirs 100 SW846 90408 O9/O9/05 5252536
7.03' No Unirs L00 0.0 SW845 90408 O9/O9/A5 5252536
Dilution FacEor: 1 A:ralyele Tlme.,: 15:43
wO# :HK6VP1AC-LCS/HK5VP1AD-LCSD LCS tot-Sample# : D5I22000a-473
3.88 llrtg/t 97 MCAww 3s0.r- 09/20/As 526s413
3.89 mg/t" 97 0.15 MCAWW 350.1 AS/ZO/OS 526s473
Dllutlon Factor: 1 Analysie TirM..: 22;00
WO# :HLJ85]-AC-ICS/HLJB51AD-LCSD tCS Lot-Sample# : D5r280000-454
4 .03 r,;.gl t 101 MCAWW 350,1 oe/27/as 527 14 54
4 .04 I,IItg/L 1 01 0.34 MCAWW 350. t- 09/27 /Os 527L4s4
Dllution Factor; 1 Analyaia Tlme..: 22,00
wo# :HKX5T1AC-LCS/Hrui5T1AD-LCSD LCS Lot-Sample# : D5r200000-255l3:l IZ',i i:3 0 ., ISffi ilz: ZZ',:Z',',? ?:21:ZT
plIut.lon Factor! 1 Analyels Tlme.., 1?.Oo
wo# : HKLKT 1AC - LCS/XXlrc7 1AD - LCSD
5 .28
5.28
mg/L
rng/ L
Di lution Factor : 1
MCAWI^I
0 .0 t-,icAww
Analysi s
MCAWW
L.4 MCAWW
Analyol a
IUCAWW
O . ].0 MCAWW
rrnalys i s
106
1.0 5
96
96
WO# : HK7L2 1AC - LCS / IIXIL2 1AD - LCSD
0.0s00 mglL
0.0s07 mg/L
3 .85
3 . 85
100
101
Di lut ion Factor : L
mg/L
mg/L
Oiluflon Factor; I
wo# : HL,LMMIAC - LCS /Hlr,UMlAD - LCSD
0 . 0486 mg/t 97 MCAWW
0 . 04 83 rrrg/L 97 0 . 61 MCAWW
Di lut ion Factor : l-Ana lys i s
wo# : HKTHEIAC-LCS /UXIHEIAD-LCSD
STL Denver
(Continued on next page)
21,2
Ni t rate -Ni t ri t.e
T,ABORATORY COITTROL $}I{P1g DATA RBPORT
Genera1. frem:ietrrry
Iot-Samgr1e # - - - : D5I09017 6
SPIKE MEASURED PERCNT
PAIT,{METER A}4OUNT AIVIOUNT UNTTS REC\M,Y RPD METHOD
Matrix. - . . - . . - - 3 WATER
PREPARATTON- PREP
ANALYSIS DATE BATCH #
LCS Lot-Samp1e# : D5TZL0000-539
e01 oB/e012A 09/2L-09/22/ OS 5261s39
901-oB/9012A A9/2t-09 / 221 0s s264s3e
?ime..: l-2:oo
Sul f ate
Total Cyanide
NOIE (S} :
4 .00
4 .00
2s .0
25.0
0 . t_00
0.100
0 .107
0 ,108
v{o* :HLLD9IAC-LCSIHLLD9IAD-LCSD LCS Lot-Sample# : D5r280000-679
3 . 96 mg/t 9s MC.AWW 353 -2 09/27 / 05 527L679
3 .9s mg/t 99 0 .15 MCAWW 353 .2 09/27 / 05 527L679
Dilution Factor: 1 Analyele Time..:18100
wo# :HLIr531AC-1,CS/HLL531AD-ICSD LCS Lots - Sample# : D5r29000 O -172
25.8 mg/t 103 MCAhT{ 37s .4 A9/28/05 52't2L72
26.5 mg/t L05 2.6 MCAWW 375.4 OS/ZA/OS 52721-72
DlluElon FacEor: 1 Analysie Time.. r 15r4o
wo# : HK3 6F1AC- tes /HK36F1AD- LCSD
mg/L
mg/L
Di lution Factor : 1
sw84 5
0.93 SW845
P-na 1ye i e
107
l-0 I
Culculations are perfornred bclbrc roundlrrg to uvuitl round-off orrorc in calcrrlated resrlts.
STL Denver 2L3
C].ient l,ot *.
Date Saqrled-
PARAIvIETER
Ammonia as N
PERCENT RECOVERY
RECOVERY LTMITS
RPD
RPD LIMITS METTIOD
I{AIRIX SPIKE SAI.TPI,E E\TALINTTON REPORT
General Chernistry
; D5f090L76
: 09/07/05 09:55 Date Received-,! 09/08/05
PREPARATTON- PREP
4NALYS_I_1_P_+38 . F+::cH #
MS Lot-Sample #: D5I080243-C04
a9 / 2A - 09 / 21, / 05 5265473
oe / 2a -a9 / 2L/ as s26s473
99
98
94
95
95
95
106
105
9B
1OB N
WO# : HJSJMIDG-I{S /HJ 6.TMIDH-MSD
1_30) l,lcAww 350.1
130) 1.1 (O-30) MCAWW 350.1
Dilutlon FacEor: 1
Analysis Time. . : 03 :00
Ni traLe -Ni t ri te
92
90
Ni trate -Nitri te
92
B8
wo# : HKTI/D1C7 -MS/HKTWIC8 -MSD
(44 130) UCAWW 350.1
(q+ 130) 0 .2L (0-30) MCAWW 3s0.1
ni lution PacEor: 1
.D:ralysis Tirne. . : 22t A0
(90
( e0
WO# : H,J6,JMIDC - MS /H.re.rruLDD -IvISD
110) mcAWW 325.2
1L0) O.L8 (O-1,0) MCAWW 32s,2
Di Lut lon Fact,or : 1
Analyeis Tlme.. ' 17r00
wo# ; HJBGVIDQ- MS/H..TSCV1DR-MSD
(az 107) uc.Aww 340,2
(BZ l-07) 0.4L (O-10) MCAWW 34A.2
nilution FacEor: I
Analysle Tlme..: 13:15
I/{o# : HI(AR91DA-MS/Hr(AR9 IDC-MSD(w 1- 07 ) mcAww 34o .2(et La7) 7.4 (O-10) MCAWW 340,2
Dilution FacEor: 1
Arialyeis Time. . : 13 :15
WO# : HJ35N1CE -l',lS/HJ3 SNICF-MSD
(ez L19) l,tcA}{I^I 353.2
(az 119) 2.L (O-30) MCAWW 3s3.2
Dllution Factor: 1
Analysis Time..: 22zOA
WO# : HJ6.}{1C7 -IvIS /HJ6JI41CB -MSD
(62 - 11s) UCAWW 353.2
(az l-t-e) z,r (o-30) MCAww 353.2
Dilution Factor: L
Analyeis Time--; 18:00
Arnmonia aE N
Chloride
Fluoride
Fluoride
MS Lot-Samp1e #,
oel27/os
oe/27/0s
D5I170191-001_
527 L454
527 L454
IVIS Lot - Sample # :
09/L8/A5
oe/tB/as
D5r080243-004
s2532s5
s2632ss
MS Lot-Sample #:
ae/a4/as
ae/L4/os
DSr090153-001-
5257 57 8
5257 57 B
MS Lot-Samp1e #:
0e/]-4/os
oe/L4/as
D51100153-003
5257 57 B
5257 57 8
MS Lot-Sample #:
ae/20/as
ae/2a/os
D5I070270-002
5265552
5265552
MS LoE-Sample #:
a9/27/A5
oe/27/os
Dsr080243-004
527 L67 9
s27 L67 9
STL Denver
(Coneinued on next page)
2L4
I{ATRIX SPTKE SAI|IPI,E BTALUATION REFORT
Genera)- Chenri-etr1r
C1ient Iotr # -
Datse Saqlled.
PARAI4ETEB,... REgOVERY
Ni trate -Nl t ri te
100
97
SuIf ate
93
7 .2 N, *
Tota1 Cyanide
32N
55 N, *
Total Cyanide
57N
56N
Norts (s) :
- -: D5f090L76
..i 09/a7/as o9:55
PERCENT RECOVERY
LTMITS
(62
(oz
Date Received-: oe/oB/as
RPD
RPD I,IMITS METHOD
WO# ; HI(AR91C5 -}"1S/HKAR9LC7 -MSD
119 ) I,ICAWI^I 353 .2
11"9) 3.3 (O-30) MCAI^II^I 353.2
oilut.lon Factor: L
Analysis Time. . r 02 r00
ltl,atriJ(,. ., .' . - . . ! WATER
PREPARATTON. PREP
A}iIAIJYSIS DATE BATCH #
IvIS Lot-Sarnple #; D5f100153-003
oe / 2a-ae /2]-/ as s25sss2
ae / 20-ae /2L/ as s?^6sss2
MS Lot-Samp1e #; Dsf080243-004
09 / 28 / os 527 21,7 2
09 /28 / 05 5272772
v{o# ; HJsJI{1DJ-MS /UIStM1DK-MSD(as 153) r,lcAWhI 375.4(45 153) SZ (O-21-l vrCAI^rr,I 375.4
Cilution Pactor: I
.Analysis Time. - r 15:40
wo#: HKAR9IDH-MS/HKAR91DJ-MSD MS LoE-Sample #: D5I100153-003
(89'- 109) swBAG goaoB/g}LzA o9/zL-o9/zz/os sz64s39
(89 - 109) 24 (0-20) sw846 go]-oB/gotzA 09/zL-os/zzlos sz64s39
Ollutlon FacEor: 1
AnalyBls Tlme..: 12:00
WO#: HKE301DH-MS/HIG301DJ-MSD MS Loc-Sample #; D5r130198-004
(8e - 10e) sw846 90108/9012A 09/2a-09/22/05 s26453e
(8e - 10e) 1.9 (0-20) sw846 90108/9012A 09/2L-A9/ZZ/OS 5264539
Difution Pactor! 1
' Analyols Time..: 1,2:00
Calculations arc pcrlornrrl bt'lbre rourding to avoirJ round-ofi errors in calculacd resuls.
N Spiked analyrc rccovcr!, ls otrtsltlc staut colilrol limits.
* Relative;rrcent difference (RPD) is ourside sarcd control llmits.
STL Denver 275
Client Iot # -
Date Saupled-
PARAMETER
Ammonia aa
SAIVIPLE SPIKE
ATiOUNT A!17
MEASRD
AMOITNT UNITS
PERgNT
REC\M,Y RPD METHOD
}IATRIX SPIKE SAMPI,E DATA REPORT
Genera1. Chernistrry
: D5I0 9 AL7 6
: 09/07/OS 09;55 Date Receiwed--: A9/08/05
Matrix-- ----: WATER
PREPIEJ\TTON_ PREP
AIVALYSTS DATE BATCH #
N
540
s40
Ammonia as N
o . 02 0
o. 020
Chloride
11000
11000
Fluorlde
0 . 54
0.54
Fluoride
L -2
L -2
NiLrate-Nitrite
o .24
0 ,24
Ni trate -Ni t ri t e
32A
320
2000
2000
4 .00
4 .00
25000
25000
s.00
5.00
5.00
5 .00
4 .00
4 .00
400
400
WO# : IIJ6,ltutroG-mS/H,fe.lMl-DII-I4SD MS Lor-Sample #: D5I080243-004
2520 mg/t 99 MCAr{rd 3s0.1 09/20-09/2r/05 526s473
2490 mg/L 98 L.1 MCAww 350.1 O9/2o-O9/2L/0s s265171
Dilution Factor: I
Analyeie Tlme..: 03:00
WO#: HKTVDICT-MS/HKTVDLCs-MSD MS Lot.-Sample #: D5I1.7o191-001-
3.79 mg/T, 94 MCAWW 350.L 09/27/05 5271454
3.80 tig/r. 95 0.2r- McAww 350.L 09/27/05 527L454
Dllution Factor: 1
Analyeia Time.. t 2?rOO
WO#: HJ6JMIDC-MS/H.T6\TM1-DD-MSD MS Lot-Sample #: D5r080243-004
35100 $rg/1, 9s MCAWW 325.2 O9/18/o5 52532s5
35000 nS/L 95 0.18 McAww 32s.2 oe/Ls/a5 5253255
Dilut.ion Factor! I
AnalysiB Tlme.. r 17:00
wo#: H.rBGvIDQ-MS/HJBGVIDR-MsD MS Irot-sample S, ?:1:::r., :::-_a5 . 83 ng/r, 106 MCAi.Iw 340 .2 09 /L4 / 0s s25757t
5.80 fitg/r, 105 0.41 MCAWW 340 .2 09/L4/05 5257578
Dilution Factor: 1
Analyaia Time.,; 13r15
IIIO#: HKAR9IDA-MS/HKAR9LDC-MSD MS Lot-Sample #: D5I100153-003
.6.L2 mg/t 98 MCAWW 340 .2 O9/L4/O5 525757A
5,59 N mg/t L0S 7.4 MCAWW 340-2 O9/14/O5 52575?S
Dilutlon Factor; 1
Analyoio Time-.: 13:L5
WO#: H,J35N1CE-MS/HJ36N1CF-MSD MS Lot-Sample #: D5I070270-002
3.94 l[.Ilg/t 92 MCAWW 3s3.2 A9/20/05 5265s52
3 -85 ng/t 90 2.L MCAWW 353.2 09/20/Os s265552
Dilution Factorr I
Analysio Tlme-. t 22:OO
WO#: H.I6,JM1C7-MS/HJ5JM1C8-MSD MS Lot-Sample #: D5I080243-004
590 mg/t 92 MCAWW 353.2 O9/27/O5 527L679
675 mg/L 88 2.t MCAWW 3s3.2 Og/Zt /OS 527L679
Dilution Factorr I
Analyeis Time..: 18r00
STL Denver
(Continued on nexE page)
276
MATRIX SPTKB SA}IPI,B DATA REPORT
@neral. Ctreuistry
Cl.ient Lot *. .. : D5I090l-75 Dtatrix. - - : WATER
Date Sarq)Ied-- -: o9/a7/05 09:55 Date Received- -= 09/o8/os
SAIvIPI,E SPIKE I,IEASRD PERCNT PREPARATION- PREP
PAR.AI,IETER A},IOI]NT AMT AMOI,NI I]NITS RECVRY RPD METHOD ANAIYSIS DATE B{TCH #
Nir,rate-Nitrite wo#: HKAR91C6-MS/HKAR91C7-MSD MS Lot-Sample fi: D5r100153-003
0.18 4.OO 4.L7 mg/L 100 I,ICAWW 353.2 09120-09/21/05 5265552
0.L8 4.00 4.O4 ns/r. 97 3.3 MCAWW 3s3.2 O9/2O-09/2a/0s 5265552
Dilullon Faccor: 1
Analysis Time.., 02:00
sulfat,e wo#: HJ6JM1D.7-MS/IIJ6JMIDK-MSD MS Lot,-Sample #: D5I0802a3-004
2500 2500 4850 t",g/L 93 MCArrr^r 375 -4 O9/28/O5 52721-72
2500 zsOO 2690 ms/L 7.2 s7 MCAWW 375.4 A9/28/AE s272t72
Qualifiers: N, *
Dilution Factor: 1
Analysie Time..; 15r40
Total Cyanide WO#: HI(ARaIDH-MS/HKAR91DJ-MSD MS Lot-Sample #; D5I100L53-003
0.056 0.100 0.0883 mg/T, 32
Qualifiers: N
sw846 901 Aa/ g 09 /2t-a9 / 22 / A5 5264s3e
0.056 0.100 0.r,r.2 r;rs/L s5 24 sw846 90108/9 09/21-09/22/0s s26453e
Tota1 Cyanide
Qualifier6: N, r
Dilution Factorr 1
Analyoio Tirne,. : 12r00
wo#: HI(E30IDH-MS/HKE3olD\,-MSD MS Lot-Sample #: DsIL30198-004
ND 0.100 0.0572 rng/L 57
Qualifiers: N
sw846 e01 oB/ e a9 /2L-Ae /22 / 0s s254s3s
rID 0.100 o.0s61 rrls/L 56 1.9 sw845 90108/9 O9/21-A9/22/O5 5264s39
Qualifiers: N
DiluEion FacEor: 1
Analysis Time..: 12:00
NCxrE (s) ,
Calculadolls are performed before roundinll rc avoid round-off crrors in calculated resultt.
N Spiked analyre recovcry is outsidc statcd control limirs.
* Relative pcrccff dillcrcncc (Rl'D) is eiutside stared coDtrol linrits.
STL Denver 277
SAI,IPI,E DT'PLICATE EI']ILIIATIOU RBPORT
Ceneral- cheruistry
Client Ipt #-. -: D5I090176 llork Order #...: H'J8ML-SMP
HJSML-DUP
Date SamFled---:A9/AB/05 09:15 Date Received--: 09/a9la5
DUPLTCATE RPD
PAITJ\M RESULT RESULT UNTTS RPD LIMIT METHOD
[tatrix--.----: GW
PREPARATTON- PREP
AlrArYsrs pArE B43gH _+
5252536
pH
7 ,2 7 ,2 No Unlts 0.0
Pilution Factor: 1
SD Lot-Samp1e #: D5I090L75-002
(o-s.0) sws+e e0408 0eloe/05
Analyeis Tlme. - , L5 z3'l
STL Denver 278
STL Denver
Sample Receiving ChecklistO r* +, )s-r oz o raS . o*o*" *i"J*'"1-1"'i{r1o - .,rr.
Company Name & Sampling Site:L,rts* k)?-
PM to Completc This Sectiou: Ies
Residual chlorine check required:O
No
s
Quote #:
Special Insffuctions:
L{-To{s
Tirae Zone:
. EDT/EST . CDT/CST . MDT/]vIST . PDTIPST ' OTIfiR
Quarantined :
]'es
tr
No
o'tr
Unpacking Checks:
Terrperatures ("C): 3. 3
N/A Yes No
e d tr
{rr
trY
tr{
d*=
ID7I
hx
tr ,,{ rr.
{ e,t6
u (rn
3,{q.tl 7,7T3.r
.-5:s
Cooler seals intact? WA if hand oelivered) Ifno, d.ocument on CLR.
Chain of custod-v present? If no. document on CTJR.
Boules broken and/or are leaking? If yos, document on CLrR.
Mulnpbirsic samples obvious? lf yes, document on CIIR.
Propcr containcr & presavatives used? (ref. Anachment D of SOP# DEN-QA-0003) if no, document on CL,T..
pH of all sarryles checked and meer requireureots? l[no, document on CLts.
Sufficient volume provided for all aaalysis requested? (ref. Atachment D of SOP# DElf-QA-0003) If no,
docurrent on CI"I& aad cootact PM before proceeding.
Did chain of custody agree with labcls ID and samples received? If no, document on CLE*
Wcrc VOA sarrpies without headspace? If no, documcut on CUR-
Were VOA vials preserved? Preservativ".pdCt l/lfl"C trsodiumThiosulfate f Ascorbic Acid
Did sarrples roquire prcsewation rriltr sedjrrm thiosulfate?
If yes to #l l, did the samples contain residual chlorine? If yes, documeDt on CLIR.
Sediment present in dissolved/filtered bonles? lf yes, documeut ou CtlR.
Is sufficient volurne provided for client requested i'{S, MSD or matrix duplicates? If oo, document on CUn, und
contact PM before proceeding.
Receipt date(s) > 48 houn past ttre collcction date(s)? lf yes, notify PA/PM,
Are analyses with short holding times requested?
Was a quick Turn Around (TAT) requested?
qEB
cdce
ID d Ero.
I .y'11.
f ,l f,12
+ c Dt3
ilrrt4
Sf\qrRtrfiX$,61e Recciving\Samplg Receiving Chcckijst tz 13 04 revision iztLita4 279
STL l)enver
Sample Receiving Checklist
L,r u D{Jqt o/7€
Login Checks: lnitials
N/A )'s No 05
d tr I 8. Sufficierrt volume providcd for all anallais rcquestcd? (rcf. Auachrncnt D of SOP# DEhl-QA-0003) If no,
documcnt on CIJII and cofiaa Plr4 hcforc prrrcccding.
t, 19. Ir sufllcient volumc provided for clicnt rcgucstcd [/S, [,lSD or matrir: duplicatcs'/ lf no, documcnl on CUR, and
crilrtaci PJvl bcforc procecding.
20- Did thc clrain of cuuody includcs "reccived b)," and'relinguishcd" b;'signaturcs, dates, and timcs?
21. Were special logir instrurrions rcad ud followed?
22. Wcre AICEE nrxals logged for refrigeratcd srorage?
{ A 23. Wcrc tests lqged checL.eri against thc COC? \\rbic.b samplcs wcre confirm
"d? .41}
ttuod D
b tr s
p!
tr&
D
fl
Labeting and Storage Chccks:
I 28. 'lUas fhc EubcoDtad COC sigmed and scal witb saryles ro bonie prep?
g 29. }\rere srrylelabels doublc-checkcd b1'a secondpcmou?
! 30. I/cre sample botles and COC double cbecLed for dissolved/filtercd mctals b1, a second porson?
ti 31. Did tlre sarrple ID, Date, aud Time fiom label matcb u,bal uas loggad?
! 32. Tilere stickcrr for special archiving instructions affixcd to each bo: and to thc ICOCIT See #27
! 33. Wcre AFCEEmetals stored refrigcrared?
X 34. Werc "Suicl ICOC'copies giverr to satdlitc Btoragc area$?
I)trcumenl anyproblems or discrepanoies and the actions talen io resolvc them on a Condition Upon Receipt Aromaly
Repor{ (CtlR)
rr
,z
,Ftr
P
,ED
,ptr
/tr
D 24. l\ras a Rush form complaed for guick TAT?
D 25- lrrtas a Shoi Hold form completed frrr anyehort holdr'?
il 26. Is'-srric, ICoc'required?
IS -27. l\,ere special archiviug instructions indicaud in tire Geaeral Conrncntsi, lf so, uibat werc they?
STL Denver 220
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$IL Denver
4955 Yanow Street
Arvada, CO 80002
Teh 303 736 0100 Fax:
www,stl-inc.com
STL
303 431 7t7l
ANALYTICAL REPORT
Weste rn Zirconium Proj ect
Lot #: D5I080243
Sheri O'Connor
IJRS Corporation
8181 East Tufts Avenue,
Denver, CO 80237
STL DENVER
UA{"gk
Linda L. Benkers
Project Manager
September 30, 2005
Sevem Trent Laboratrories, lnc.
Table Of Contents
Sfan dard Del iverables with Supp orti ng
Report Contents
Sfandard Deliverables
(ft e Cover Letter ancl the Report Cover poge are considered integral
ports a/'this Standard Deliverahle pacluge. This report is incomplete
uniess all pages lndtcated in this Tahle of Cuntents are included.)
I Table of Contents
. Case Narrative
I Executive Sumrnary - Detection Highlights
r Methods Summary
. Method/Analyst Summary
r Lot Sample Summary
. Analytical Results
. QC Data Association Summary
o QC Evaluation and/or l)ata Reports
. Chain-of-Custody
Supp orti ng D ocu m e ntati o n
(Note: A one-page "l)escription ol Supporting l)ocurnentati.on" rs
provided at the beginning of this section.).
r Volatile GC/MS
. Sernivolatile GC/MS
r Volatile GC
r Semivolatile GC
r LC/IWS or HPJ,C
I lVletals
o General Chemistry
r Radiochemistry
. Subcontracted Data
Documentation
Number of Pages
Check below when
supporting
documentation is
present.nnnnnmEnn
STL Denver
Case Narrative
D5I080243
With exceptions noted as flags or foohrotes, standard analytical protocols were followed in the
analysis of the samples and no problems were encountered or anomalies observed. AII laboratory
quality confrol samples anallzed in conjunction with the samples in this project were within
established control limits, with any exceptions noted.
The test results presented in this report meet all requirements of NELAC, and any exceptions are
noted. This report shall not be reproduced except in full, without written permission from the
laboratory.
Sample Receiving
Eight samples were r."ri.r"d under chain of custody on September 8, 2005. The samplcs were
received in good condition at temperatures of 5.I"C, 3.1"C, 1.4"C, 2.7"C,3.1oC, and 5.7oC.
Please note that the samples submitted for 82608 analyses only require reporting of Chloroform
only as per client request.
GC/IVIS Volatiles, SW846 82608
Samples D5I080243-002 and 004 were analped at dilutions due to high analle concentrations.
The reporting limits are a-djusted accordingly.
The MSIMSD perforrned on sarnple D5I080243-004 was in control.
No anomalies were observed.
Total Metals, SW846 60108,6020 & 74704
Samples D5I080243-002 through 008 were analyzed at dilutions for several metals by methods
60108 and/or 6020 due to matix interference, high analyte concentrations, and/or intemal
standmd failures. The reporting limits are adjustcd accordingly.
The method 60108 MS/MSD associated with batch 5265261was performed on sample
D5I080243-004 and was not in control.
l}re method 7470L MS/MSD associated with batch 5259473 was perfonned on samplc
D5I080243-004 and was not in control for mercury.
The method 6020 MS/IVISD associated with batch 5265172 was performed on sample
D5l08A243-004 and was in control.
No other anomalies were observed.
STL Denver
General Chemistry, Yarious Methods
Samples D51080243-002 tluough 008 were analyzed at dilutions for several compounds due to
high analyte concentrations. The reporting limits are adjusted accordingly and the associated
data is flagged "Q"-
Chloride, fluoride, and sulfate were detected in the method blanks at concentrations below the
reporting limits, but above the method detection limits. Associated positive sample results are
flagged "J".
The MS/IvISD for methods 350.1, 325.2,340.2,351.2,375.4, and 90108/90l2}.were performed
on sample D5I080243-004 and were in control for all parameters except fluoride and sulfate.
All other MSA,ISD samples were performed on samples from other clients and/or lots and rvere
in control.
The pH duplicate was performed on a sample from another client and/or lot and was in control.
No other anomalies were observed.
Denver
EI(ECIJTIVE W - I)etection Highliehts
D5I08A243
RESULT
REPORTING
LIMIT UNITS
.AhTALYTICAIJ
METHODPAIUqMETER
Grr-ser. -0907os oe/ 07 / as 07 ; 00 o0z
Cadmium
Selenium
Barium
NickeI
Z:nc
Calcium
Iron
PoEa6Eium
Magnes ium
Sodium
Zftconium
Chloroform
Chloride
Fluoride
Nitrate
Ni trate-Nitrite
Total Cyanide
pH
SulfaEe
Ammonia as N
GTI-SIO - O90?Os Oe / 07 / As O9 : 38 OO3
Aluminum
Arsenic
Barium
NickeI
Z:,nc
Calcium
fron
Potassium
Magnesium
Sodium
Zirconiurn
Chloride
Fluoride
pH
SuI fate
Ammonia as N
0.0039 B
0 .011- B
0 .13
o -o77
0 - 015 B
1400
0 .1-1 B
450
640
s50 0
0.o24 B
L90
L2000 J, Q
2.4 .]
380
380 0
0 .0053 B
6.9
1900 J, Q
7L0 A
0 .017 B
0.0075 B
0 .37
0.0015 B
0 .0098 B
31
0.20
150
42
r_900
0.00s9 B
2800 J,Q
0.95 J
8.1
79 B,J,Q
5.0
(Continued on next
0.010
0.020
0.01-0
0 .040
0.020
1.0
o.50
15
1.0
25
0.075
6.7
1200
0 .10
0 .10
50
0 .010
0 - 10
100 0
50
0_10
0 .0L5
0 .010
0.040
0 .020
0.20
0,10
3.0
a .20
50
0.015
250
0 .10
0,10
100
0 _ 10
page )
r.g/x
mg/L
mg/L
mg/L
mglI,
mg/L
mg/L
rng / I'
mg/L
m9/L
mg/L
ug/L
mg/L
mg/L
mg/L
mg/L
ms/L
No Units
mg/L
mg/L
mg/L
mg/t
mg/L
mg/L
mglL
mg/L
mg/L
mg/L
mg/L
mg/L
mg/ l-
mg/L
mg/L
No Unibe
$tg / r,
rrlslL
sw846 6020
sw84 5 6020
SI^I845 501-08
sw84 5 6 010E}
sw84 5 5 0108
sw84 5 6 0108
swB4 6 5 0108
sw84 5 5 0108
sw84 5 6 010E}
sw845 50L08
sw84 6 6 0108
SWB45 B25OB
MCAWW 325.2
MCAWW 34A.2
MCAWW 353 .2
I\,tcAww 353 .2
sw845 901Ag^/ 9C12A
s}1I845 90408
MCAWW 375.4
I'ICAUfi{ 350 .1
sw846 50108
sw845 501_08
sw84 6 5 0108
sw846 601-08
sw84 5 6 0108
sw845 50108
sw846 5010B
sw84 5 6 0108
SWB46 5OlOB
sw845 50r-oB
sw845 50108
MCAWW 325.2
MCAWW 340.2
sw845 904 0B
MCAWW 375 .4
MCAWW 350 ,1
STL Denver
EXECIITwE ffi - Iletection Highlights
D5rO80243
RESULT
REPORTTNG
LIMIT UNTTS
A}TALYTTCAL
METHODPAIUIMETER
crr-sr--o9ozo5 og / at / os o9 : 55 oo4
Cadmium
Selenium
Arsenic
Barium
Nickel
Zinc
Calcium
Iron
Potaseium
Magnesiurn
Sodlum
Ztrconium
Chlorof orm
Chloride
Fluoride
Nitrate
Nitrate -Nitrite
Tot,a} Cyanide
pH
SulfaEe
Ammonia as N
GTr-S11-O9O7Os 09 / A7 / As r.r" : r-5 O0s
Selenium
Arsenic
Barium
NlckeI
Calcium
fron
Potass ium
Magnesium
Sodium
Zirconium
Chloride
Fluoride
Nitrate
NitraEe -Ni tri te
pH
Sulfate
Amrnonia as N
0.0039 B
0 .011 B
0 .0078 B
0 .13
0 .080
0 .015 B
1400
o . t-3 B
440
630
s500
0 .021 B
180
11000 J, Q
2-2 J
320
32O 0
0 _ 013
5,9
2500 ,f , Q
s40 0
0 .018 B
0 .0049 B
0 .15
0 .0026 B
170
3-2
550
590
l-4000
0 .064 B
22040 J, Q
0.49 J
0.17
0 .17
7 ,9
2900 J,Q
11 A
0.01_0
0.020
0 - 0l-5
0.010
0,040
0.020
1.0
0.50
15
1.0
25
0.075
6 -7
1200
0 .10
0.10
10
0.01-0
0.10
s00
50
0 - 040
0 .015
0 - 0l_0
0.040
2.4
1.0
30
2,0
s0
0 .15
1200
0.10
0.10
0 . l-0
0 . L0
500
0.50
mg/T,
Ijj'g/t,
mg/L
mg/L
mgll'
mg/L
mg/t
rl;rg/ t'
mg/L
rllg/L
mg/L
mglL
luglL
mg/L
Yng/L
mg/L
mg/L
mg/L
No Unifs
mg/L
mg/ r,
mg/L
mg/L
mg/ t
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
'IjIg/L
mg/L
nrtg/L
No Units
mg/L
mg/t
sw845 6A2A
sw846 6A20
sw845 60108
sw845 50L08
sw84 6 5 0108
sw845 5 01,08
sw845 60108
sw846 6 0108
sw845 50108
sw845 501-08
sw845 501_08
SWB45 SOIOB
sw845 82508
IvtcAww 325 .2
MCAWI^I 34A.2
MCAWW 353.2
I,ICAWW 353 .2
sw846 901-08/9012A
sw845 90408
MCAWW 375 .4
MCAWW 350.1
sw845 5020
sw845 50r-08
sw845 50108
sw846 50108
sw845 50L08
sw845 501-08
sw84 6 5 0108
sw846 501-08
sw845 60108
sr{846 60108
I,ICAWW 325 -2
MCAWW 34A.2
MCAWI,II 353 .2
MCAWW 3s3.2
sw845 90408
MCAVIW 375.4
MCAWW 350.1
STL Denver
(Continued on next page)
EXEffi SM - Iletection Highlights
Dsr0tJ0243
RESULT
REPORTING
LIMIT UNITS
AI$ALYTICAt
METHODPARAMETER
Glr-sz-ogo7os og/oz /os L2=2a oo5
Se I enium
Barium
Nickel
Zinc
Calcium
PotaBBium
Magnesium
Sodium
Chloride
Fluoride
Nitrate
Nitrate -Nitrite
Tota1 Cyanid.e
pH
Sulfate
Ammonia as N
GW-S3-O907O5 Os/A7 /As 13: OO oo7
0. 025 B
0.074
0 .0060 B
0.025 B
224
l_t_00
724
25000
45000 J, Q
1.0 ,J
e.g
LO O
0 .0040 B
7 .7
5700 J, Q
2.4
0 .10
0.050
a .2A
0. L0
2.O
30
2.0
s0
1200
0 .10
0.10
0 . so
0.010
0.1,0
l_200
0.10
0.0L0
0 ,0L5
0 ,0L0
0 .040
0 .010
0-20
0 - L0
3,0
0.20
5-0
250
0 .10
0 .10
100
0,50
0.020
0.015
0 .010
0.040
2.4
l_.0
page)
ms/L
mg/L
mg/L
r;tg/L
'lr.g/L
r;rg/ I'
nLg /L
mg/t
mg/L
rtg/L
mg/t,
mg/L
mg/L
No Units
mg/L
mgll'
mg/l'
mg/L
mglL
mg/L
mg/L
mg/L
mg/r-,
n.g/ t-,
mg/I'
mg/r,
rr;.g/t
mg/t,
No Units
mg/L
mg/L
mg/L
rls/L
mg/L
ng/L
mg/t
mg/L
sw845 5020
sw846 60108
sttil846 501_08
sw846 50r-08
sw846 50108
sw845 50108
sw846 501-08
sw846 60108
MCAWW 325.2
MCAWW 340.2
MCAWW 353 .2
MCAWW 353.2
sw846 901a8/ e012A
sw84 5 904 0B
MCAWW 375 .4
MCAWW 350.1_
sw846 6020
sw845 60L08
sw84 5 5 0108
sw845 50L08
sFI846 501-08
sw84 6 5 0108
sw845 60L08
swB46 50L08
sw846 501OB
swg45 6 01-0B
MCAWW 325,2
MCAWW 340.2
swB45 90408
MCAWIII 375.4
MCAWW 350 .1
sw846 6020
sw84 6 5 010B
sw845 601_08
sw845 60L08
SIAI84 6 6 0108
sw84 5 5 0108
Selenium
Areeni c
Barium
Nickel
Vanadium
Calc ium
Iron
Potas s ium
tvlagnes ium
Sodium
Chloride
Fluoride
pH
Sulfate
Ammonia aB N
Glr-Nz - 090?Os Ae / 07 I OS 13 : 3O OO8
0-0a2L B
0.015
a .2L
0 .0034 B
0.0035 B
39
0 .54
224
55
26,A0
4500 J,Q
0-95 .l
B-1
5OO J, Q
9.8 0
0.0079 B
0.0053 B
0.095
0.0014 B
61
0.25 B
Selenium
Arsenic
Barium
Nickel
Calcium
I ron
STL Denver
(Continued on next
E)rcW W - I)et€cfion l{ighlights
D5rO80243
RESULT
REPORTTNG
LTMIT UNITS
AbIALYTTCAL
METHODPAIU\METER
cw-N2-ogozos ae/ot /os 13:3o oo8
Potaaaium
Magnesium
Sodium
ZLrconium
Chloride
Fluoride
Ni t rate
Ni t.rat,e -Ni trite
pH
Sulfate
Ammonia as N
330
2ga
7500
0 .039 B
1-2000 ,f , Q
O .68 J
0 .23
a .23
8.0
2000 J, Q
5.3
mg/L
Iertg/L
mg/L
mg/L
ms/L
mg /1,
mg/L
rng/ r,
No Units
mg/L
mglL
s!{846 50108
sw845 50108
sw845 50108
sril84 5 5 0108
MCAhnil 325 .2
MCAWW 344 .2
MCAWW 353 .2
MCAWW 353.2
SI^I845 9040B
MCAI,W^I 375.4
MCAWW 350 .1
30
2.4
s0
0 .1"5
2so
o .10
0 .1_0
0 .10
0.10
l-000
0,1-0
STL Denver
METHOI}SW
D5I080243
PAII-]\IqETER
AI{ALYTICAIJ
METHOD
PREPARATION
METHOD
pH Aqueous
Chloride (Colorlmetric, Automated Ferricyanide)
Fluoride (potentiometric, fon Select,ive electrode)
Inductively Coupled Plasma ( ICP) Metals
rcP-MS ( 5020 )
Mercury in Liquid
Ni trate
Ni trat e -Ni tri Ee
Nitrogen, Ammonia
SuI fate
Waste {Manual Co1d-Vapor)
Total Cyanide
Traee fnductiwely Coupled P1asma ( fCP) Metals
VolaEile Organics by cClIrIS
Referencea:
MCAI^N^I
sw84 6
sw845 90408
MCAWW 325 -2
MCAWW 34A.2
sw845 50r-08
sw84 5 6020
sw846 747AA
MCAIil^I 353 -2
MCAWW 353 -2
MCAWW 350 , L
MCAWW 375.4
sw84 5 so1 oB/ eol
SI^I84 5 5 01OEI
sw846 82508
sw845 90408
MCAhn^I 325 .2
MCAWW 344.2
sw845 3 010A
sw846 3020A
sw845 747AA
MCAWW 353 .2
MCAWW 353.2
MCAWVf, 350 ,1
MC^AWW 37 5 .4
sw846 90108
sw845 3 0104
sw84 5 503 0B/ 825
"Methods for Chemical Analysis of Water and Waetee'i,
EPA-500/4-'79-02A, March 1983 and subeequent revisions.
"Tegt Methods for Evaluating Solid !{ast,e, Physical/ChemieaL
Methode", Third Edition, November 1985 and iEs updates.
STL Denver
ANAIJYTTCAL
MEl}IOD
METHOD/ATTIALYSTW
D5rOAO243
AI{ALYST
ANALYST
ID
MCAWI{ 325 . Z
I4CAWW 34A -2
IvICAWW 350 . L
MCAWW 353 .2
plcAww 315 . 4
sw845 60r.08
sw845 50108
sw845 501-08
sw84 5 5 0108
sw845 6020
s}{845 74704
SW845 B25OB
sw845 90108/ s012A
sw846 90408
Refererccg:
MC]\WW
SWB4 5
Claire Likar
Fougere M. Danielle
Claire Likar
C1aire Likar
Dusti O- Criqui
Janel Motiehka
'Janel Motichka
Lynn-Arrne Trudell
Irynn-Ar:ne Trudel}
Thomas LiII
Janice S. CoIlins
Dan Appelhans
Dusti O. Criqui
Fougere M. Danielle
004382
0064 81
0 04 382
0 04 382
005589
002852
2852
006645
5645
006929
011_568
001008
005589
006481
"lvlethods for Chemical Analysis of Water and Wastes " ,
EPA-500/4-79-A2A, March 1983 and su-bseguent revisions.
ttTest MeEhods for Evaluating So1id Wa6te, Physical,/Chemical
I"lethodstr, Third Edition, November 1985 and iEs updates.
STL Denver
SAIVIPI,]ESt}W
D5r080243
WO # SAI'IPLE# CLIENT SAMPLE ID
SAI{PLED SAMP
DATE TTME
HJ5H5 0 01
HJ6H8 0 02
H.J5JL O O 3
HJ6'JM O 04
HJSLTW 0 0 5
HJ6,IX 0 0 5
HJ6J0 0 0 7
H,J5,J1 0 0I
Nolts (S) :
TB-090705
GW-S91-09070s
GW-510-090705
GW-51-090705
GW-51L-09070s
GW-S2-09070s
cw-s3-090705
cw*N2-090705
ae/07/os
09/07/OS 07:00
09/a7/as o9;38
09/07/OS 09:55
09/07/os rl":1,5
ae/a7/05 L2:2A
a9/07/os L3;oo
09/A7/OS 13:30
- The andytical rcsulE of thc sarnplcs listcd abov€ arc prexntal on dlc following pages.
- All cal@lations arc pcffomcd bcfors rourxting t(, avoid &)und-off rnors in crlculatcd rcsul6.
- Results mted as "ND' scrc no{ dcEctcd at or abo}c ri,c stsrcd liDit.
- 'fltls rcport rrost mt be r.produced, exccp In Arll, wkhout dr wrltrn approva-l of the labontory.
- Rcsulls for thc follovins pilameters are Rver rcpomc{t on a dry wclihl basls: color, corrosivily. d€rNity. tlashpoint, igniability. laycrs, odor,
paiil filtcr te$, pl1, poroshy prcssurc. rcacuvily. rodox poEn{ial, sPccific gr8vity, s?oa lcsts, solids. slublllty. rcmpcrarurc, vlscoslry, and wclth[.
STL Denver 10
IIRS Coralorat,ion
Clieut Sarp1e fD: 1ts-090705
cClUS Vol-atiles
Lot-Samlrle #---:
Date Saryr1ed---:
PrepDate--r-.-l
Prep Batctr fi. . - :
Dilution Factor:
DSI080243-001
ae / o7 / os
ae/Le/os
5263359
I
[ilork Order *---=
Date Receirred. - l
Analysig Date--z
Anal.ygig Time.. !
Method - - -:
RESUI,T
ND
PERCENT
RECOVERY
HJ5H5].AA
oe/08/0s
ae/Le/os
1"5:09
sw845 82608
REPORTING
LIMIT T}NITS
1,0 ug/Ir
RECOVERY
LIMITS
(7t 118)
GZ 128)
0a 118 )
(tt 1r-7 )
Matrix...!....,i wQ
PARAMETER
Chloroform
SURROGATE
Dibromof luoromethane
L, 2-Di chloroethane - dq
4 -Bromofluorobenzene
Toluene -dB
85
80
BB
l_03
STL Denver 11
IIRS Corgrcration
Client' Saryrle fD: GT{-S9I--090705
GClIl.S Volatrilee
Iot-Sam5lle #. -.:
DaEe Sanp1ed,...Z
Prep Date?-....!
Prep Batch #. - -:
Di]-ution Pactor:
D5I080243-OA2
a9/a7las or:oo
0e/Le/a5
s263369
5.55
Itork Order #- - -:
Date Receirred- - 3
Arralygig Date. - 3
Analysie Time- - :
Dlethod -
RESULT
190
PERCENT
RECO\MRY
94
8B
88
98
HJ5H81A8
oslos/os
oe/Le/os
16 :30
sw846 82608
REPORTTNG
LTMIT UNTTS
I{atrix-- ----: WG
PARAMETER
Chloroform
SI}RROGATE
6 -7 ugfL
RECOVERY
LTMITS(7r 1l-B)
(62 128)
(7e 1l-8)
(7 t a17l
Dibromof luoromethane
L ,Z-Dichloroethane - d4
4 -Bromofluorobenzene
Toluene - dB
STL Denver 72
IIRfi Coraloration
CIienE Sample ID: GH-SI.O-O9O7O5
GClt{s vo1atsi}es
Iot-Saq>Ie *---:
Date Sarpled- - - :
Prep Date - -.:
Prep Batch *- - -;
Dilution Factor:
D5r080243-003
09/07/as o9;38
oe/Le/os
5263359
I
xlork Order #- - -:
Date Received- - :
Analysis Date..3
analyeis Tine--.
Method.-- .-,i
RESULT -,.
I,[D
PERCENT
RECOVERY
92
90
93
100
HJSJL1AK
oe / o8los
oe/D/as
16 :50
sw846 82508
REPORTING
LIMIT UNTTS
Dlatrix-. -...r WG
PARAMETER
Chloroform
SURROGATE
1 .0 :ug/L
RECOVERY
LTMTTS
(73 118)
(62 128)
(zs L18)
(tt 117)
Dibromofluoromethane
L ,2 -Dichloroethane -d4
4 -Bromofluorobenzene
Toluene -dB
STL Denver 13
Iot-Sauple *- -.;
Date Saryt1ed..-3
Prgp Datg,..--.3
Prep Batch #. - - =Dilution Factor:
IIRS Corporation
Client Sarple ID: GIf,-S1-O90705
GC/!t^s volatilee
Ilork Order #---: HJSJM1AK
Dat.e Received. , 3 09/ 08/ 05
Analysia Date- -: A9/\9/AS
Analysis Time..! 17:lL
ltatriJ(. . . - - - - - -: WGD5I080243 - 004
09/07/as o9:55
0s/Ls/as
5263369
6 .66
Uethod..- -o.: SWB45 82608
PAITJ\METER RESULT
REPORTING
LIMIT UNTTS
Ch.Ioroform
SIIRROGATE
180
PERCE}UT
RECOVERY
6 -7 rug/L
RECOVERY
LIMITS
(tt Lt 8)
(62 a28l
(78 118)
(77 117)
Dibromof }uoromethane
L ,2 -Dichloroethane -d4
4 -Bromofluorobenzene
Toluene -CB
93
B6
88
99
STL Denver L4
IIRS Corporation
Client Sanpl-e ID: GTI-S11-0907O5
cc/u.s volatrilee
Iot-Sanp1e #. - -:
Date Sarylled- - . :
Prep Date -..;
Prep Batch #- - -:
Dilution Factor:
D5r080243 - 005
09 / 07 I a5 1r. ;15
09/Le/os
5263359
1
9[ork Order *. - . :
Date Received- -:
Analygis Date- -:
Analysis Time- - 3
rrfethod. . . ! r . . . . I
REFJLT
ND
PERCENT
RECOVERY
99
1_ 03
94
97
HJSJUIlAU
oe/08/05
0e/7e/a5
l-8: l-3
sw846 82508
REPORTTNG
LIMIT UNITS
Matrix-- ----: WG
PARAMETER
Chloroform
ST]RROGATE
1 . 0 ug/l'
RECOVERY
I,IMITS
Dibromof luoromethane
1, 2- DichloroeEhane - d4
4 - Brornof luorobenz ene
'Ioluene - dB
(73 118)
(az L28)
(78 11B)(7t 117)
STL Denver 15
t RS Corgrcration
Client Sarpln ID: GI{-S2-09O7O5
cC/Ms vo].atiles
Iot-Sanple *---=
Date SarryIed, , .3
Prep Date -. . l
Prep Batch *- - -:
Dilution Factor:
Dsr080243-006
09 / a7 / a5 ]-2:20
oelLe/as
5263369
I
I{ork Order #- - - =Dat€ Received. - 3
Analysis Date..3
Analysis Time- -:
tllethod. . . - , - . - - :
Rq9UrJT
}TD
PERCENT
RECOVERY
99
110
95
95
HJ5,rX1A4
os/08/0s
os/te/a5
18:33
sw845 82608
REPORTING
LTMIT IJI{ITS
Iu{atril(.- -.,-3 WG
PAILJ\METER
Chloroform
SI]RROGATE
1-0 ug/L
RECO\TERY
LIMTTS
(tt 118)
(oz 128)
(7 B 1_1-8 )
(7t l-17 )
D i bromof 1 uo rorne E hane
L ,2 -DichloroeEhane -d4
4 - Brornof }uorobenz ene
Toluene -d8
STL Denver L6
[IR.S Cor;poration
Cl-ient Sanple ID: giI-S3-O9O7O5
GC/It^s volatilee
PARAMETER
Iot-Sam5lle #-. -
=f),ate Sarupled- - -:
Prep Date .. , I
Prep Batch *- - - =Dilution Pactor:
D5r080243-007
0e/07/A5 L3:00
oe/Le/as
5253359
1
Work order #- - -:
Date Received- - g
Analysis Date - .2
Analysis Time- -:
Dlethod- . . - - - :
RESUI;:I
}TD
PERCENT
RECO\IERY
97
101
93
99
HJ6,J01AF
ae/08/os
oe/Le/os
18 :54
sw846 82608
REPORTING
LIMTT UNITS
1 .0 ug/L
RECOVERY
LTMTTS
(tt LL8)
laz 128)
( za 118)
(tt r_17 )
Irtatrix- . . . . - - - - :WG
Chloroform
SIIRROGATE
Dibromof luoromethane
L, 2-Dichloroethane - d4
4 -Bromofluorobenzene
Toluene - dB
STL Denver L7
URS Corporation
Client Sanqrle rD: cII-Ir2-09O7O5
GclHS Volatiles
PzuUUdETER
I.ot-Sampl-e #-. -:
Date Sangrled....3
P-rep Datse-. - - - -:
Prep Batreh *- -.;
Dilution Factor:
D5r0802 43- 008
09/07/as t-3:30
ae/Le/os
5253359
1
Ilork Order f - - -:
Date Received- -:
analyeig Date- -:
Analysis Time- -:
Dlethod-,,. - - - -.;
RBSULT .-
ND
PERCENT
RECCVERY
96
98
93
99
HJ5J1].AP
ae / 0Blos
ae/Lel05
19 :14
sw846 82608
REPORTING
LIMIT IINITS
[Iatrix,. . . - - - - - - :
Chloroform
SI]RROGATE
1-0 ug/L
RECOVERY
LTMITS
fi3 118)
( 6Z 1,29)
(ze 118)
(77 117)
Dibromofluoromethane
A, 2-Dichloroethane - d4
4 -Bromofluorobenzene
Toluene-dB
STL Denver 1B
tlR,S Coqporation
C1ient Sanqrle ff) ; G"ff-S9L-090705
TOTAL lrtetale
Iot-Sarytle #- - -:
Date Saryr1ed.--:
PARAMETER
D5I080243-002
A9l07l05 o7:00 Date Receiwed-: o9/aB/0s
METHOD
l.tatrri](..o.o--
PREPARATION-
AIVALYSIS DATE
:WG
RESULT
REPORTTNG
LIMTT UNITS
Prep Batch #.
Itlereury
Prep Bat'cfr #.
Cadmiurn
Selenium
Prep Batch # -
Si lver
Aluminum
Arsenic
Barirun
Calcium
Chromium
Copper
Iron
Potaesium
; 5259437
DUD
: 5255L72
0-0039 B
o-o11 B
: 525526].,
}TD
IUD
IUD
o .13
14 00
ND
t[D
0.f-1 B
454
0e/23-ae/27/as
oe/23-oe/27 /os
a9 /23 -o e /27 / As
0e/23-oe/27/os
09/23-oe/27/as
ae/23*a9/27 /as
WORK
gFpER #
HJSHBlAU
HJ6H8 1AK
HJ5EBLAIJ
EJ5E8LtrV
H.J6H81AM
HJSHB1AIV
EJsHELAW
0.00020 nrg/L
D:iutlon Factor: 1
0,010
Di lution
0.o20
pi1utLon
tog,/t'
Factor: 10
W/t'
Factor ; I 0
0 . 010 r;rg/L
Dilution Factor : l-
0 .50 mg/I'
Di luE ion Fact,or : 5
0.015 n,g/L
Dllution Factor: 1
O. O1O tug,/L
Dilution Factor: 1
1,0 vry,/L
Dllution Factor: 5
0.010 mg/L
Dilutlon Factor: 1
0, OLO $tg/I'
oilution Factor r L
o - 50 vq/t,
ci }ut.lon Factor ; 5
15 rrslL
Dllution Factor: 5
swB4 6 6 0108
Analyais Time..: 09:53
stl84 5 6 01_08
Analyais TLme..: 0O:09
sw84 5 5 010B
Arralysis Tl.me., : 09 : 53
sTr845 60108
enalysle Time..r 09:53
slr846 50108
Analysis Time.,: 00:09
sw84 5 6 0108
Analysis Time,.: 09:53
sw845 50108
Analysio Tirne. . , 09: 53
sn846 60t oB
Analysis Time..= 00:09
sw846 50108
Analyeie Time..: 00:09
oe / 23- a9 / 27 / As HJ6H81AI1
os / 23 - os / 27 / asHJ6rurolO
sv[84 6 7 47 AA, 09 / 23 / 05
Analysie Time..: 18:13
sw845 5020 Aglz3-Oelz&l0s rLrsHBrA3
Analysia Tlme..: 02:03
sw846 6020 Oel23-09/28/Os rrJ6E8r.A4
enalyels Time. - ; 02 :03
STL Denver
(Continued on next page)
ag /23 -o e /zt / os tr^f6ngr.ur
IpE-Sanple # -
PARAI\,IETER RESUTT LIMIT UNTTS
TIRS CorgroraLion
C1ient Sarqrle fD: GTI-S91-O9O7O5
TOlfAL Hetalg
: D5I0BA243-002
REPORTING
METHOD
Irlatrix,
PREPARATTON-
AI{ALYSTS DATE
;WG
WORK
ORDER #
Iulagureeium
Sodium
Iitickel
Lead
Vanadium
Zinle
Zirconium
NorE (s) :
640
5500
o .o77
NDG
}TD
0.0L6 B
a -424 B
1- 0 rrq,/l'
Pilution Factor: 5
25 tr|{J,/L
Ollution Fact.or; 5
0.040 $q/L
nl]utlon Factor:1
0. o0?0 mg/L
Dilut ion Fact,or : L
0.010 mg/L
oilutlon Factor: 1
0-o2o ug,lL
Pilution Factor: 1
O. O75 vq,/f"
Dllutlon Factor r 5
sw845 60108
Analyois Time.,: 00:09
sYr846 50108
Analysis Time. -: 00:09
srr846 60108
Analyeie Time.-: 09r53
sw846 50r.08
nnalyslo Tlme..: 09:53
SWBA6 6OlOB
Analyeie Time. . : O9: 53
slt845 501OB
Analyeie Time-, r 09:53
sw845 60108
Analyeis Time. . : 00 :09
oe/23-oel27 /os
ae/23-os/27 los
oelz3-oelz7 / os
os/23*as/27/os
09/23-ae/27 /as
EJ6ESIAO
ILTSBBIA1
tr,J5II8LAP
H.T6Ii8lAQ
I{J5H8]-AR
09123-Oe /27 I OS Er6H8r.AT
oe / 23 -ae / 27 / os ILT5E8LA2
B tistinrated rcsult. Rcsult is lcss than RL-
G Elevatcd reponlng linilt. 'lhe reporting limit Is clcvated due to matrix lnlerfcrcncc.
STL Denver 20
Ipt-Sanple #...I
Date Sary>I.ed---:
PARAXIETER
IIRS Cora>oration
Client Sample ID: GT{-S10-O907O5
ToTAL lrtetale
D5r080243-003
a9/07 /05 09:38 Date Received. - Z a9/08/os
RESULT
REPORTING
LI}ITT UNITS },IETHOD
Matrix-:WG
PREPARATIOI{- VIORK
AhTALYSIS DATE ORDER #
Prep Batsch
Mercury
hep Batch #.
Cadmium
Selenium
Prep Batch
Si Iver
Alumirrum
Arsenic
Barium
Ca]-cium
Chromiurn
Copper
fron
Potassium
: 5259437
}TD
: 5 2651,7 2
ND
TID
*- - -: 525526a
}(D
0-017 B
o-oa75 B
0-37
31
ND
ND
0 -20
160
0.00020 ntg/L
Dllution Factor: 1
0.0050 mg/L
Dllution Factor: 5
0 . 010 mgll,
Dllution Factor: 5
0.010 l:lrg/L
Diluti-c,n Factor: 1
O.1O $g/L
Dilut,ion Factor: 1
0 ,015 WI/I'
Pliut:on Factor: 1
0 - Olo u.rtg/L
Pilutlon Factor: 1
O -2o ms/L
Pi lut,lon Factor : L
0 . 010 mg/L
Dilution Factor; 1
0 . 010 mg/ I'
Oilutlon Factor i 1
0.1o qg/L
Dilution Factor: 1
3.0 wry,ll,
Dilution Factor: L
sw845 501-08
Analysis llme..: 09:58
sw845 60108
Analyeis Time-.: 0Az47
s"I{846 50r_08
Analysis Time-.: 09:58
srr845 50108
Analyaia Time..: 09:58
sw846 50108
AnalysiB Time,. ' 00:4-l
sw84 5 5 0108
Ana).ysis Time. . : 09 : 58
sw84 5 5 0108
analysis Time..: 09:58
srr846 50108
Analyeio Ttrne. . : 00 :47
sT845 50108
Analysis Time. . ; 00 :at7
on next page)
ae/23-ael27/os
oe /23-oe /27 I os
oe/23-ae /24/ os
ae/23-oe/27 /os
ael23-oe/27/os
ae/23-oe/24/as
#-
sw845 7 470A Oe / 23 / A5
Analysis Time- . : 1,8 ;15
sw84 5 6020
Analysis rime.
SI^I845 5020
Analysi e Time .
HJ6JL}A5
a9 / 23 -Oe / 28 / AS HJ6,JL1AE
02:A7
oe I 23 - a9 / 28 / as HJ5JL1AF
O2 :07
oe / 23 -a9 / 27 / 0s HJ6JL1AT
os / 23 - as / 24 I osB^r6JL*0
E,.T6iILIAV
E;T6JLILW
EiISiTLIAS
HJSJL]-.AX
HJSJL1AO
H,r5irl,lA7
STL Denver
( Cont inued
a9123 -0 glzq, / os H.]SJIIA8
27
Lot -saupl-e #.
tlR$i Corporation
Client Sanp1e ID: GW-S10-O9OTAS
IIOtAL Ueta1e
: D5f080243-003
REPORTING
lfatrix --.o.): WG
PREPAIT'{TION- WORK
AIIALYSTS DATE ORDER #PAIU\METER RESULT LTMIT UNITS METHOD
Uagrresirrm
Sodium
Nickel
Iread
Vanadium
Zinc
Zirconirm
NOtB (s) :
42
1900
0,0016 B
0.0099 B
o-oos9 B
O.Za rrg,lL
Dilution Factor; 1
50 w/l'
Di lut ion Factor : I 0
0 - 040 vry,/I'
Dilutlon Fact.or: I
0.0030 mgll,
Di luE ion Factor : l.
0.010 mg/r,
nilution FacEor: 1
0 .020 rDg/L
Di luf ion Factor : l-
O - 015 vry,/I'
Dilution Factor: 1
slr845 6010ts
Analysie Time-.: 00:4?
s:tr845 60108
nnalyeis Time-.' 00;14
srr845 60L08
Analysie Tlme..: 09:58
swB46 50108
Analyele Time.,: 09:58
sw846 5010E}
Analysls Time..r 09:58
sr{846 50108
Analysis Time..: o9;58
srr845 50108
Analysis Time-. : 00:47
ae / 23 -a9 I 24/ aS H.r6irLrAA
09 / z3-o g / zt / as E76irr,r-AC
ae / 23 - 09 / 27 I os H.T6JLLAI-
09 / 23 - A9 / 27 / A5 HJ5JL1A2
09 / 23 - Ae / 2t I OS HJ6JLLA3
oe / z3-ae lzt / os EJGJLLA4
oe/23-a9 /24/ Os ET6{IL].AD
B Esrimarcd rczult. Resrlr is lcsc than RI-.
STL Denver 22
I.ot-Sanp1e #. . - : D5IOBA24
Date Sanqr1ed. - . : 09 / A7 / Os
PAIUq}4ETER RESUI,T
IIRS Corporation
Client Sample ID: GTI-SI-090705
TCXIAL Hetal.s
3-004
-09:55 Date Recei'rred--: 09/AB/As
REPORTING
LIMIT I}NITS METHCID
Matri:c.:WG
PREPAR.ATTON- WORK
A}IAI,YSTS DATE ORDER #
Prep Batch #.
Mercury
Prep Batch #-
Cadmium
Sel-eniuur
Prep Batch *.
Si lver
Aluminum
Areenic
Barium
Calcium
Chromium
Copper
Iron
Dotassium
-- 5259437
ND
:5265L72
0-oo39 B
o-o11 B
; 525526L
IID
DID
o. oo7fj B
o_13
1400
ND
hrD
o-a3 B
4{0
oe/23-ael27 los
oe/23*ae/27 /as
oe/23-oe/25/os
ae/23-oel27 /os
0e/23-ae/27/os
oe/23-0e/26/05
HJSJIvflAs
E^f6JUIAV
E.T6JIITI.AI,T
IIJSJITT1AS
HJSJMlAX
HJ6JM1AO
II^f5.]IinA7
0.00020 mg/L,
Di lut ion Fa ctor : l-
o-010
Di lutl on
o - o20
Di lut.i on
rylt
FacEor r 10
try/L
Factor: 10
0 .0050 mg/L
o1 lution FacEor : 1
0.50 mg/L
ollution Factor: 5
O . O15 rrtg/L
Di lutlon FacEor : 1
O - 01-o rrry,/n
DiluElon Factor, l-
1.0 nq,/L
Dilution Factor: 5
0 . 010 mg/L
nilution FacEor: 1
0.010 mg/L
ol lut i on Fact,or : I
O,5O W/L
Di l-ut ion Factor : 5
15 ,rqll
nilution Factor: 5
(ConLinued on
ssr846 747AA 09/23/As
Analysis Time..: 18:16
sw846 6A20 Oe/23-O9/28/A5 Err6arul-iAB
Analysie Time. . : 02 r l"L
swB4 5 502 O 09 / 23 -O9 / 28 / As ltI6irrrrAF
Analyslo Time..: 02:11
sw845 60108
Analyeis Tirne, . : 10 :12
sw846 50108
Anal)'sis TLme. - : 23 :30
sw845 60108
.F.na1)'els Time. . : l-0 : 12
sw846 60108
furalyslo Time..: 10:12
sr{845 60108
Analysis Tlme..: 23:30
s9'I845 60108
Analyele lime..: L0:12
sw846 60108
Analysis Time..: 10:12
sw846 60108
Analyois Tirnc. . : 23 :30
sw846 50108
Analysis Time.. ' 23:30
next page)
ae / 23 -ae l27 / os lrJsJMl-AT
os/23-os/26/osHJ5*rp
STL Denver
a9 / 23 -oe /za / os IT,JGJUIAB
23
Lot-Sarq>le #.
PAI1JUVIETEF BESULT
IIRS Corporation
Client Sanple ID: Grt{-SI-090705
TCItrBL }IEtAIg
: D5I08A243 - 004
REPORTTNG
LIMIT UNITS
t{atrix- - - - . , . . . 3 WG
METHOD
PREPAIT'\TION-
AI{IALYSIS DA?E
WORK
ORDER #
l.Iagnesirun
Sodium
Nickel
Lead
Vanadium
Zj.nc
Zirconiunr
NGIE (S) :
630
ss00
o-o80
0-015 B
o-oz1 B
r.0 $q/L
Dilutlon Factor: 5
25 w/L
Pllution Factor: 5
o-o40 rr'g,/L
Di lut l.on FacEor : 1
o . 0030 mg/L
Dilution Factor: 1
0.010 ms/L
DiLution FacEor: 1
o .020 nq,/T'
oilutlon Factor: 1
o-o75 vlg,/L
Pilut.lon Factor; 5
60108 ae 123-ae /26 / As
Time..: 23:30
5Or.oB Oe /23 -o e /25 / As
Time-.: 23-.30
60r-08 ae / 23-09 / 2t / as
Tirne..: 1orl.2
5or-0B oe /23- 0e lzt / as
Time..: 10:12
60108 Oe/23-Oe/26/OS
Time..:23s30
STUB45
analysl s
srr845
Ana I yei e
sw846
Analyo 1 e
sw84 5
Ana lys i s
SWB4 6
Analys I o
sr{8{5
analyol e
sw846
Analyei s
50108 A9/23-09/27/05 H,J5JM1A2
Time..: lat!2
6o1oB 0e/23-A9/27/as HJSJIVI1A3
Tlme..: 10:12
IIJsJ}IIAA
HTSJULAC
EJSJII!LAI-
tr,J6J}T1A4
H^T6JULBD
B EstinmterJ rcsuh. Rcsult is less Onn RL.
STL Denver
Irot-Sauqlle #-..:
Date Sarylled---:
PARAMETER
LIR^S Co-poraLion
Cl-ient Sarylle ID: GB-S11-09O7O5
T0TAL Uetals
Dsr0B0243-005
A9 / 07 / 0S 11 : 15 Date Received- . ! 09 / 0B/ As
RESULT
REPORTING
TTMIT UNITS IvIETHOD
: 5259437
I,ID sw845 747aA oe /23/ 05
Arralysia Tlme. . : 18 :2i
ttatri:r-:WG
PREPARATION- I{ORK
A}TATYSIS DATE ORDER #
Prep Batrch *-
lrlercury
PreB Batch *.
Cadmiurn
Selenium
Prep Batch #-
Si lver
Aluminum
]1a'sgn i g
Barium
Ca]-cium
Chromium
Copper
Iron
Dotarsir:m
: 5255L72
}TD
o. o18 B
: 5 265261,
ND
ND
o-oo49 B
0.1_6
L-l o
I\ID
}ID
3-2
560
0.00020 mg/L
OiIuEion Factor: 1
0 - 02 0
Di lut. ion
o-o40
Di luE i on
mg/L
Factor: 20
vrg,/t'
Factor: 20
0 . 010 'l;rg/L
Di lut lr:n Factor : L
1 .0 mg/L
Ollution FacEor: 10
O. O15 nr y,/L
ni luf ion Factor : l-
0 ,01o rW/L
DiluClon Factor: 1
2 -o nry,/L
Dilution Faetor: 10
0.010 mg/L
Ullution Factor: 1
0.010 mg/L
Di lution Factor : 1
L.0 W/L
Dilution Faetor: 1O
30 rng/r
Dilution Factor: 10
HJSLTW1AG
s}{8 4 5 6A20 09 / 23 - A9 / 28 / OS H.]5JW1AP
Analyeie Time--: A2235
srr846 5O2o A9123-A9 /281 AS s*T5firLAQ
Itnalyels Tirne. . : 02 :36
sw84 6 5 0108 09 / 23 - 09 / 27 I Os HJ6Jlrrl-A3
Analyeis Time..: i0:32
sw845 50108 Og /23-Os /27 / Os H,J6J*rJ
Arralyeis Tlme. . : 00 : 18
sw846 60108 A9/23-O9/27/O5 Ir,J6in{r-A5
Analyeis Time. . : 10 :32
srr845 60108 A9/23-A9 /27 / A5 H,r6Jr{LA6
nnalygie Time..: 10:32
sw846 50108 A9 123 -Oe / 27 / Os EJsJr[LArr
analysie rime..: 00:18
sw846 50108 Ae/23-09/27 /Os HJsJW1A?
Analyeie Time. . : l-0 :32
svr845 60108 A9/23-0e/27/As HJ5.]WIAA
Analyeis Tlrne. . : 10 : 32
srr845 5O1OB 09 /23 -A9 / 27 / 05 Itr6JT{r-AiI
Analyolo Time..: 00:18
sr{846 50108
Analysie Time,.: 00r18
on next page)
STL Denver
( Continued
09 / 23 -oe / 27 / os EJ6JTTLAK
25
Iot,-SarryIe #- - -:
IIRS Corarorat,ion
Client Sample ID: GI{-S11-O90705
T0TAL Metale
Dsr080243-005 ltatrix- -, o - - - - -: WG
PARAMETER RESULT
REPORTING
LI}4TT UNITS METHOD
PREPARATION-
A}iIALYSTS DATE
WORK
ORDER #
Dtaguesium
Sodium
NickeI
Lead
Vanadium
Zinc
Zireonium
r{oTB (s} :
590
14000
o - 0026 B
NDG
TUD
ND
o-o54 B
2-o ug,ll-
Pi lut, ion Factor : 10
s0 w/L
Di lut lon Factor : 1 0
O . O{O rrry,/L
ni1ut ion Factor: I
0.0070 mg/L
Pilution Factor: 1
0 . 010 mglL
Dilution Factor: L
0.020 mg/L
Dilution Pactor; t
o-].s WlL
Dilutlon Pactor; 1o
sr{845 60108 o9123-Og lZt I AS
Arralysis TLme. . : 00 ; 18
H,TSJTTIAL
5'W845 50108 Oe /23-09 /27 / 05 E^rSJrLAr.r
Rnalygis Time,,: 00:LB
sw8{6 60108 09/23-A9/27 lO5 E^TGJWLAC
Ana1yslo Time.,: 1o:32
sw84 5 5 0108 09 / 23 - A9 / 27 / A5 HJ5,,r.llAD
Ana}ysio Tirne. ., 10 :32
sw846 50108 A9/23-09/27/as HJSJWIAE
Analysia Time. -: 10:32
sw845 60108 Oe/23-A9/27/0s HJsJW1AP
Analyols Time..: 10:32
sw845 60108 Ae/23-A9/27 /O5 H.T6JI{IAN
Arralysie Tl.me. - ; 00 : 1,8
B Estlmared rcsult. Result ls less than RL.
G Elevated rcporting llmit. The reporting limlt is clevatcd duc to rnatrlx iRterferencc.
26STL Denver
[IRS Corporation
Client Sauple ID; Gt{-Sz-O9O7O5
TO{IAL tleta.ls
Irot-Saq>Ie S- -.:
Date Sarylled,..-.
PAIUqIVIETER
D5r080243-005
09 / a7 / AS L2:2A DaEe Received-
RESULT
REPORTTNG
LTMIT UNITS
: o9/oB/as
METHOD
Uatrix.:WG
PREPARATION- WORK
AIVA.LYSIS DATE ORDER *
Prep Batch #.
Mercury
Prep Batch #-
Cadrnium
Selenium
Prep Batch
Si lver
Aluminum
Arsenic
Barium
Calcium
Chromium
Copper
Iron
Potassiutn
: 5 259437
ND
:5265172
ND
0.025 B
#..,: 526526L
ND
ND
IUD
a -a74
220
IVD
}UD
brD
1100
0.00020 nlg/L
Pl lut ion Fact,or : 1
0 .050
Di lutiorr
o-10
Di.lutiorr
mg/L
Factor: 50
rrrtg/L
Factor: 5O
0.050 mg/L
Dilueion Factor: 5
1.0 mg/t
Dilut ion Factor : l- 0
0 . 075 mg/t,
Dilution Factor r 5
O.05o urg,/L
ollutlon Factor: 5
2 -o tI,g,/L
Di Iu t. i on Factor : 1 0
0.050 mg/L
Di lution Factor : 5
0 . 050 rng/t
Dllut.ion Factor: 5
l-. 0 nrg/t
Dl lut ion Factor : 1 0
3 0 vtg/L
Dilut ion F'actor : 10
sw845 60L0B
Anal)rsis Time. . : 12 ;58
sw84 5 6 01,08
Analysis Time..: 00:23
sw845 60108
Ar:,alysi g Tirne. . ; 12 : 58
sI{845 50108
Analyslo Time,.: 12:58
swB45 50108
Analysie Time..: 00:23
sw845 50108
Analysis Tlme. . : 12 :58
sw845 50toB
Analysis Time..: 12:58
sw845 50108
Analysie Time..: 00:23
sw845 50108
Analysis Tirne, , : 00 :23
nexE page)
oe/23-a9/27/As
ae/23-oe/27/as
ae /23-ae /27 / as
oe/23-oelzz /as
ael23-ae/27 /os
oe/23-oe/27/a5
ae/23-oe/27 /os
oe/23-ae/27/os
H,J5,JXr^O
HJ6JXlAG
ILf6JI(IAE
E.}6.IJTI.AR
HJ6.IXlAJ
HJSJXlAK
HJSJXlAT
swB46 747AA 09/23/05
Ana}yele Time. . : ).8t23
HiISJXIAQ
sw846 6020 09/23-09/28/aS HJ5JX1A0
Analysis Time..: 02:40
sn846 6020 oe/23-Oe/2fEl0s ETS.IJ(LA]
Analyeio Time, . : o2: co
HJ6JXlAE
09 / 23 -o g / zt / as H^T5,rxrAu
STL Denver
(Continued on
27
Lot-Saqll-e # -
URS Corporation
Client Sanrpl-e ID: GW-S2-09O7Os
IO{IAL }Ieta}e
: D5I080243-005 Matri](. - - r - . . . . r WG
PREPARATION- WORK
ANALYSIS DATE ORDER #
REPORTING
PARAIVIETER ._ RESUI.{LIMIT UNITS METHOD
[lagrresiurn
Sorf i um
tilicke].
Lead
Vanadium
Zinc
Zixconium
NOIts (S)
=
720
26000
o-0060 B
0-025 B
2-A
rl lut ion
50
Di 1 ut ion
o -2a
pi lut I on
0.0L5
oi 1ut, ion
0 .0s0
Dilutior:
o-10
Di lut ion
0 .15
Dilution
lrrry,/r'
FacE.or : 10
vlg,lL
Factor: 10
V{J,/L
FacEor: 5
r*g/L
Factor: 5
fiig/L
Factor: 5
rrg,/t'
Factor: 5
'tl,g/L
FacE,or : 10
sw845 60108
analysis Time..: 00:23
sr{845 60108
Analygis Time,.: 00:23
sw845 60108
Analyele Time. . : 1.2 :58
09 / 23- 09 I 27 I As rr*rSiXrLV
a9 / 23 - A9 / 27 / Os H^r6JJrrAr{
a9 / 23 -Oe / 27 / As EJ5.IJTLAL
sw845 601-08 09/23-A9/27/A5 HJ5.lXLArvl
Analysie Time. . : 12 :58
sw845 50108 oe/23-oe/27 / a5 HJsJX1AN
Analysie Time. . : i2 :58
sw845 60108 Ae/23-O9/27 /O5 H.I5Jr(LAP
Analysie Tlme. . : 12 :58
sw845 60108 09123-0e/27 /Os HJSJXIN(
Analyeio Time-,: 00:23
B Lstimated rcsult. Resutr Is lcss than RI-.
STL Denver 2B
Ltrt-sanple S.. -:
Date Saryrled- - -:
PAIU\IVIETER
IIRS Corlrcration
Client Saurple ID: GT[-S3-090705
TOTAL Dtetra1e
D5I080243-007
09 / a7 / 05 13 : 00 Datse Received- . r 09 / 0B/05
RESUTT
REPORTING
LTMTT UNITS METI{OD
Flatrix -:WG
PREPAIU\TION. WORK
AhIALYSIS DATE ORDER #
Prep Batch # -
Mercury
Prep Batch f.
Cadmium
Selenium
frep Batch #.
S i lver
Aluminum
Arserric
Bariurn
Calcium
Chromium
Copper
fron
Potassium
: 5259437
ND
: 5265L72
ND
o - oo2]_ B
: 526526L
ND
ND
o_o15
o _2L
39
}TD
ND
0,54
220
0.00020 rng/L
Di- IuE lon Factor : L
0.0050 mg/L
Dilutlon Fact,or: 5
o - o1o trry,lL
Dl 1ut lon Fact,or r 5
0.01-0 mg/L
Dilut,ion Pactor: L
0 . 10 mg/L
Dilution Factor; 1
0 .015 ng/t
Dllut, ion Factor : 1
0 - O1O ng,/T'
oilution Factor: I
O .2O wtg/L
Dilution Pactor: 1
0.010 mg/L
oilut.ion Factor: L
0.010 mg/L
DlluEion Factor: 1
0 - 10 trl;/L
Dil-ution Factor: I
3.0 uq/l'
Dilution Factor: 1
sw845 6A20 A9 / 23 -A9 / 28 / 0s H,J5,J0LAA
Arralygis Tirne. . : aZ t44
sr845 6020 O9123-O9/28/O5 TLTS.IOLAC
Analysig Time..: 02t44
sw845 60108 09/23-A9/27 /05
Analysig Time.,: L0:42
HJSJO IAhI
sw845 50108 Ae/23-A9/24/Os HJ5J01A
Ar:alysia Time. . : 01 : 01
sw845 'r47OA A9/23/O5
Analysig Tirne. . : LB 224
srr846 501oB Oe /23 -O e /27 / As
Arralygis Time, . : L0 :42
slr846 5O1OB Os /23 -O e / 27 I Os
Analygie Time..: 10:42
sw845 5O1OB Oelz3-Ae/24/Os
Analysie Time..: 01:01
sw845 50108 Oe/23-0e/27 /0s
Analyols fLme.,: 1-ot42
sw846 50108 09/23-A9/27 /05
Analyaie Time . . : 10 :4 2
sw845 5O1OB oel23-oe/24/Os
Rnalyeie Time..: 0t:01
HJ6JO ]-AI
ETSJOTAQ
ET6JOLAR
H.T6JOLA2
HJ6JO IAT
HJsJO lAU
E;T5JOI.L}
sr{846 50108 A9/23-0 glZ+lOS rrJ5J01A4
Analysls Ttme, . : 01. : 0L
STL Denver
(Continued on next page)
29
Iot-sampl.e #.
IIRS Corporation
CJ.ient Sarqll.e ID; G!W-S3-O9O7O5
IIOTAL lulet,ale
: D5I080243-007 Hatrix --r..e ; WG
PARJ\METER RESUI,T
REPORTTNG
LIMIT UNTTS METHOD
PREPARATTON-
AI{A],YSIS DATE
WORK
ORDER #
Dlagnesium
Sodium
Dlickel
Iread
Vanadium
ZLnc
Zirconium
NO([E (S)
=
56
2500
o-oo34 B
}ID
o-0036 B
ND
}TD
o-20 w/L
Dilution Factor: L
5,O qglL
Dlluclon Factor: 1
O - O4O W/T,
Dllut ion F actor: I
0.0030 mg/L
DiLurion Pactor: t
o - O1O trg,/L
oilut,ion FacLor: 1
0.020 mg/L
DiluEion Factor: 1
0 - 01-s mg/L
Dilution Factor; L
srr845 60108 A9/23-O9/24los
Anal)rsle Tl.me..; 01 :01
sn845 50108 Os/23-o9124/OS
Analysis Time, . ' 01 :0L
sw845 60].(}8 09/23-A9/27 /os
Arralysia Time- . : L0 r42
sw846 50108 0e/23-a9/27/As
Analyole Tirnc. . : 70 :42
sn845 5O1-OB A9/23-og/zt/OS
Analysis Time. . : 10 :4 2
E^T5JOTtrs
Eir6iroraS
E^T6JOI-AV
HJSJO lAW
E*T6JOIA)(
sw845 50108 09123-0e/27 /as r{J5J01A0
Arralyslo Tlme - . : lA z 42
sw845 50108 09/23-Oe/24/Os HJ6J01,A?
Analysia Time..: 01:01
B F-stimated rcsult. Rosult is less Olan RL.
STL Denver 30
Iot-Sanp1e #, ,.1
Date Sanqlled- - . :
PAIUIIvIETER
UR^S Cor;rcra.tion
Clierrt Sanple ID: GTI-I{2-O9O7O5
TO|IAL FIetaIs
D5I080243-008
09/ 07 / 05 L3 ;30 Date Received- - : a9/ Ae/ 05
RESIILT
REPORTTNG
LTMIT UNITS METHOD
Flatrix-:WG
PREPARATTON. WORK
A}IALYSIS DATE ORDER #
Prep ga.tch * -
Mercury
Prep Batch *.
Cadmium
Selenirmr
Prep Batch #-
Si lver
Aluminum
Arsenic
Barium
Ca]-eium
Chromium
Copper
Iron
Potassium
;5259437
ND
: 5265L72
IID
o-oo79 B
: 526525L
IUD
ND
0. 0063 B
o_095
61
IUD
ND
0,25 B
330
0.00020 mg/t
Dlluti-on Factor r 1
0.01-0
ni lut ion
o-020
Di 1ut Lon
mg/L
Factor: 10
nry,/L
Faetor: 10
0 . 010 mg/t
ni lut.ion Fact,or : r
1 .0 mg/L
Dilution Factor: 10
0. Ol-5 ntg/L
ollution Factor: 1
0.010 ng,/L
Dilutlon Factor r 1
2.A rg/I,
niiution Factor: 10
0 . 010 mg/t
nllution Factor: 1
0.01-0 mg/L
ni lution Factor : 1
1.o W/t
Dllution Factor; 10
oe/23-oe/27/os
0s/23-0e/27/a5
oe/23-oe/27 /ss
oe/23-0e/27 /os
ae lzz-oe/22 / os
ael23-0e/27/as
oe/23-oe/27/os
09 / 23-oe l27 / os
HJ5J1]-AC
HJ5J11A)(
_,_oHJ6Jl-]"AO
ILT5Jl-IAt
E^T6JIIA2
HJ6,ItIAI)
HJ5J11A3
HJSJ]-1A4
EJSJIIAE
sw846 747AA, 09/23/A5
Analyeie Time. - : l-8 :26
sw845 5020 A9/23-oe/28/0s HJ5J11AK
Arralyeis Tlme. . : OZ : 47
sH846 5020 Oe/23-09/28/aS rrrr5J1l-AL
Arralyeie Time - . ; A2 :47
30 ms/t
oi lut ion Factor : 1 0
sw84 5 6 010B
Arralysis TLme, . : 10 ;47
SI^I84 5 50108
Analysls Time..: 00:28
sw845 50108
analyeis Tlme.,: L0:47
srf,845 50L08
Analyele Time. ., 1.0 :47
slr845 501_OB
Analyaie Time,.: 00:28
sw845 60108
Analysis Tlme, . : l0 :47
sw845 60r.08
Analyais TIme..: L0:47
sn845 60r-08
Analyslo Time. . : 00 :28
sr{845 50108
Analysie Time..: 0o:28
STL Denver
(Continued on next page)
ae / 23 -o g I zt / os HJGJT.IAF
IpE-Saryrle # -
PARAMETER RESULT
IIRS Corgrcration
Client Sarple ID: cW-If2-09O7As
TOTAL lttet'a]-e
: D5I080243-008
REPORTING
LIMTT I]NITS
Itratrix-- -....--3 WG
PREPARATION- WORK
ANALYSIS DATE ORDER #METHOD
lIagilresium
So&i-unr
NickeI
Lead
Vanadl-um
Zinc
Zirconium
NCIrE (S) :
28o
Tsoo
o-0014 B
ND
ND
ND
0. o39 B
2 - o nrg,/T.
Di ]ution Factor r 10
50 rrg/l'
ollution Factor: 10
0 - 040 vry,lL
Dilutlon FacEor; 1
0 .0030 llllg/L
Dilution Factor: 1
0.010 mg/t
oilution Factor; 1
0 .020 ntg/L
Dilution Factor: 1
0.15 vlg/L
Piiut ion Fact,or : 10
stu845
Analysi s
sw846
Analyoi e
STT845
Arra lys 1o
slll84 6
Analysio
sw84 5
analygi e
SWB4 5
Arra lya I s
sr{845
nnalygi s
60108 oe/23-09lZ7 /Os Hirs.nrAc
Time..: 00r28
50108 oe/23-09/27 /A5 HJ5J]-1A5
Tlme-.: 10:47
5ol-oB ae/23-ae/27/os HJ5J11A7
TLme,.: 7o147
60108 oe/23-o e/27 /Os
Time-.: 0o:28
501oB o9/23-Oe/27 /Os
Time..: L0:4?
501.0B 0e/23-0e/27/05
Time.. ' I0:4?
50108 oe/23-0e/27 /as
Time..: 00:28
HirS.rl]AE
E^76J1IA5
HJSJ]- ].AA
ILTGJIIA.T
B Esrtnrapcl result. Rcsult is less dran RL.
STL Denver 32
I,ot-Sampl-e #---:
Date Sampr1ed.., !
PAIU\METER
tlRS Cora>oration
Client Sample ID: GI{-S91-090705
General- Chemietrry
Tlork Order f ..-: HJ6HB
Date Rr=ceived- - : Og / OA / OS
MaEri)c, -. , . . . . - 3 WG
PREPARATION-
AIVAI,YSIS DATE
D5r080243-002
a9/07/os 0?:00
PREP
BATCH *
pE
Amnonia aa lI
Ch].oride
F]-rroride
Nitrate
IIit,rate-Nitrite
Sulfate
Total Clanide
NOTE (S) :
Dilution Factor: 20A
0-0053 B 0-01-o ng/I,
DiLution Factor; L
RESULT RL II}ITTS METHOD
5-9 0-10 llo Unirs Srf846 9O40B Og/OA/oS 525Ls27
pllutlon Factol: 1 Analyole Time..: 15:21
7r-0 Q 50 wlt ucAl{r{ 3s0.1 o9/2o-o9l2alo5 526s473
Ditution Factor: soo Analyoio Timo..: 03:00
12000 ir,Q r-2OO w/t r,rcArfr' 325.2 Og/telOS 526325s
Dilution Factor:500 Analysi8 Tlme-.: 17:00
2.4 J 0-10 wlt UeAr{r 340.2 A9lA9lO5 s252s47-
Dilution Faceorr 1 Analysls Tlme.. r 11:30
3AO O-LO ug/t r.icAnTI 3s3-2 O9/A8(O5 s26s584
Dilu!.ion FacEorr 1 Analyslo Tioe,, r 12:00
38O Q sO rq/t HeAnw 3s3 -2 OSIZO-OS/ZL|O5 526s5s2
DiluElon Factor:500 Analyeie Time..r 02:00
r-9o0 J,Q looo wlt ucAnw 375.4 aslze/as 5272L72
Analysis Time., : 1.5 :40
sr{846 901 AB{9012A Oe / 2o-O 9 /zllAs 5263s1O
Analyois Tlme. . : 12 :00
RL Reporting l..lmit
a F.lcvaql reporting limit. Ttrc rcponirrg limit is elevated due to high arurlyte levels-
J Methort btank contanrination. The assoclated me0rorl blank connlns thc target anaJyte at a reponablc lcvcl.
B Fstlmacd resrlt. Result l.s lcss tlmn RL.
STL Denver 33
{IRS Corporation
Client Sample ID: G[{-S1O-O9O7O5
General- Cherrietry
Iot-SaryIe *- - -: psrogOzai-oO3 l{ork Order #...: H,f6JL t{atsrix, ..: WG
Date sampled---: 09/07/05 09:38 Date Received- -: Og/oa/os
PAIUIMETER RESULT RL I]NITS METI{OD
PREPAIUTTION_ PREP
AT{ALYSIS DATE BATCH #
8.1 O.1O No UDita SW846 9O4OB OglOSlOs 525L527
pilution FacEor. 1 Arralyelo flme.. ; 'J-5t24
AEnonia aB N 5-O O.1O w/L ITICAI{II 350-1 O9/2O-O9/2A|A5 5265473
Dilution Factor! 1 Analyaia Time.. r 03:00
Orloride 2800 J,e 25o Wlr, !.tcAlrw 3zs.z ogl].Blos 52632s5
Dilutlon PacE.orr 100 Analysis Timc..: L7:00
Fluoride 0.96.f 0.10 rglr, lrcAlfit 340.2 og/oglos s252s4L
DlluEion FacEor: 1 A$alyeie Timc.,: 11:30
Nit,rare ND 0 - t-0 tw/L MC.AI,IW 353 .2 09 / A8 / 05 52655A4
Dilutlon Eactor: I Analysia Time,,: 12:00
Ni trare - Ni t ri te IUD 0.l-0 rI.s/L MCAWW 3s3 -2 oe/2a-Oel21,/Os 525s552
Dilution Factorr 1 Analyaia Time.,: 02100
sul-fate 79 B,ir,Q LOO Img,lt HcAnW 375-4 O9|2B/OS 5272a72
Dilution Factorr 20 Analysia Timc.. r 15:40
Total cyanlde ND 0.0r.0 r.,,I:q,/L sw845 gO]OBlgoLzA, oe/2o-09/n/a5 s2535r-0
Dilution Factorr 1 analyeia Time..: 12:00
NOTE(S}:
RL Reponing l.imlt
J Mcthod blank contamlnarlorr. 'Ihe associated nrethod blurk contairlr the target Bralytc at a reportahle level.
a blu-vated reponing limit. The reporring limit i.s elevaad due ro high anal-vre levels-
B Estinratcd result. Result is less than RL.
pH
STL Denver 34
Ilot-Sample #... i
Date Sanqlled.--:
PARAMETER
IIRS Corporat.ion
C1ient Saryle fD: GTY-S1-O907O5
@neral Chenietry
D5I080243-004 rlork order #..-! HJSJI'I
09 / a1 / 05 09: 55 Date Received. - 3 09 / 08/05
I{atrix-- ----: WG
PREPARATTON- PREP
ADIAIYSIS DATE BATCH #RESUIJT RL UNTTS METHOD
6-9 O.10 I[o l]rrir8 sW846 9O4OB Aglog/Os 525Ls27
DlluEioil Factor: I Analysie Time,.: 15!25
s4o Q 50 wlt ucAwH 3so-1 o9lza-oglzLlts s265473
. DiluEion Factor: 500 Analyeia Time..: 03r00
l-1ooo J,Q tzoo wlt !{caYtw 325-2 osltg/os 5263255
Dilution Fector: 5o0 A'lalyais time..; Lz.00
2-2 J O.1O wlt ritCAI{W 3it0-2 O9|O9/O5 525254L
Dllution FacEor: 1 eralyeie Time.,, 11:30
12A O.10 wlt UCAWW 3s3-2 Aglvglos s27A1O5
_ Dilution Pactor: 1 Analysie Tlme..r 17100
32o Q 10 "g/t r{CAr.w 3s3 .2 O9lZ7 los s27L579
Dilution Faetor: 100 Analysls Tl,me..:18;00
2500 J,Q soo wlt trcalltf 375.4 o9l28l05 s272L72
Dllution Fastor: 100 Aaalysie Time.,; 15:{0
o-o13 o.o1o uqlt s1rB46 9O1OB/eo12A oel2$-O9l2rlOS SzssSrO
Dilution Factor: 1 Analyolo Tlme..: 12;00
pE
Amnonia as N
Ch].oride
Fluoride
IiUitraEe
Nitratre-Nitritre
Su].fate
Tota1 clranide
IUOTB (S} :
RL Reponlng Uurit
a Elevated rcporting, Iimit. The reporring lhnit is clevated due to hlgh analytc lcvels.
J Metrul blank contzuttlnation. The associatcd nrerhod blrnk contains trc tarjct anelyte at a reportablc hvcl.
STL Denver 35
Iot-sarple #. -.:
Date Saupled,.-3
PAIU\METER
IIRS Corlrcration
Client Sarqrle ID: GTI-S11-090705
General Chemistry
Work Order *---: HJ6,-[$I
Date Received - - = A9 /08/05
RL UNITS METHOD
MatriJC, - . . t - - - - : WG
PREPAIT.I\TTON- PREP
A}IALYSIS DATE BATCH #
D5r0BO243-005
09 / a7 / os r.r- : r-5
RESULT
pH
^Brunonia aB N
Chloride
F].uoride
Nit,rate
Nitrate-Nitsrite
Sulfat,e
Total Cyanide
NOTE (S} :
7.9 0.10 lro Unirs SIt845 90408 AglOs/As 525L521
Dllutlon Pactor: I Analysis rime.., 16i52
11 Q O.sO wl,. uCrI}lW 350-1 Og/zo-oelztlls s265473
Dilution Eactor: 5 Analyels Tlme,. r 03:00
22ooo ir,e Lzoo wlt Mcar{w 12s.2 oglL8los sz6z255
Dllution Factorr 500 Analyais Time,.: 17:00
o-49 J O-rO rglt ugarrlf 340.2 o9la9/o5 525254L
Dilution FacEor: 1 Analyoie Tlme..r 11;30
o-1? o,1o rylr, ucAr{w 351-2 o9/a8lo5 526ss84
Dilutlon Factor: 1 Analyeie Time..: 12:00
0.1? o-1o rrg,/t ucAwn 3s3.2 o9l2o-o9/2l/o5 s265552
Dllution Factorr 1- Analyeia Tlme. -: 02100
29OO ir,Q 5OO w/t llcArre 375.4 A9|2S/O5 5272L'12
Dilution Factor; 100 Analysis lime..; L5r40
IrD 0.010 rr]g/r. SW846 SOrOe/gOrZA 09/2A-oe/27/05 5263s1-0
DlLution trector. 1 Analyeis Time..: 12:00
RL Rcporting Limit
a Hcvarcd rcporting limit. The reportlng limii is elevated duc ro high analyte levels-
I Mcthod blanl contaminatlon. Thc associated method blank contalns iln target analyrc a[ a rcporrnblc levul,
STL Denver 35
Iot-Saugrle #. - -:
Date Saqlled. -. l
PAIULIyIETER
IIRS Corporation
C1ient Sample fD: @{-S2-O9O7O5
General ChemLetrlr
Work Order #..-: HJ5.TX
Date Received., ! 09/AB/A5
RL UNTTS METHOD
t{atrix- -. . D , . - - ! WG
PREPAP3TTON- PREP
AI{AIYSIS DATE BATCH #
D5I080243-005
ae / 07 / os L2:20
RESULT
PII
Alrunorria aa IU
Ch].oride
F].uoride
lititrate
I{itrate-I[itrite
Sulfate
Total cyanide
}TOIE (S) :
7.7 O.1O lto UaitE SW845 90408 O9/O8|O5 525L527
Dilution FacEor: 1 Analyeis time..r 15:57
2.A 0.10 wlt rdcArrw 350.1 ogl2o-oglzllos szesazl
Dllution Factor: 1 Analyele Time. . : 03 :00
4sooo rt,Q 12oo uglt uclrrr 3.25.2 o9ll8/a5 52612ss
Dilution FacEor: 500 Analyeis Time,.: 17:00
1-o J O-1o rr{g,lt, t&aln{ a4o-2 ogloglas s252s4l
Dilution FacEorr 1 AnalyeLe flme..: 1L:3o
9.9 O.1o rqlt ltreArfw 353 -2 O9lO8/05 527t705
Dilution PacCorr 1 Analyele Tirne. -: I?:00
10 O 0 -sO lfrq/L trCAItn 3s3 -2 Oel27 /O5
ol lut ion Factor : 5 Analysie Time . . : 1,8 :00
57OO J, Q 12OO Ifl,Itg/L lrCeHrI 375.4 O9/28/Os
DiluBioo. Factort 250 Analy8is Time,,; 15:40
o.oo4o B o.oro uqlt sw846 9o1oB/9o12A oelzo-oslzllos 526!slo
Dilution Factor: 1 llnalyais Tlme..: 12:00
s27L67s o
5272L72
RL Reponing Linrir
J Method bla* connminatlon. 'lhe assrxiatcd rrctlrod blank conralrrs thr target analyrc at e rc?orutrle level,
0 Elcvated reponlng lirnit. The rcporting linrt i.s elcvarcd due to high analyrc levels.
B Estimacd rcsult. Resuh is lcss rlriur RL.
STL Denver 37
Irot-Saq>Ie #. - -
Date Sanpled- -.
PAIU\METER
IIRS Corporation
Client Sar4rle ID: CTV-S3-090705
General fremistry
Ilork Order #...: HJ5J0
DaEe Received- -: 091 08/05
RL UNITS METHOD
I{atrix- , , o . . . - - i WG
PREPARATION- PREP
A}TALYSTS DATE BATCH #
D5I080243 - 007
09/07/A5 l-3:00
RESULT
pH
Anrnonia as N
Chloride
Fluoride
Ni t,raLe
Witrat€ -Nitriee
Sulfate
Total Cyanide
IiTOTE (s)
=
8.1
e-8 0
O.1O tilo tlnits
oi lut,lon Factor : 1
o - so mg/L
Dilution Factor: 5
sH846
Ana lysis
MCATIW
Ana lyai e
IIICAI{I{
Analyoi s
I.ICAIIII
Ana lys i s
MCAWW
Analyeia
MCAWW
Analys i e
UCAWW
Analyo i s
sw845
Analysi s
90408
Time. . :
350-1
Time. . :
325.2
Tirne. . :
34A .2
Time. - :
353 ,2
Tirne. . :
353 .2
Time, . :
3-15 - 4
ae / oe/ os
17:00
525152-t
s263255
525254A
45OO J, Q 25O rutg/L
o-95 J
Dllution Factor: 100
0 - 10 nrg/l'
Dllution FaeEor: 1
0,l0 mg/L
Dllution FacEor c 1
0 . 10 mg/L
Dllution Factor; 1
5OO ir, Q 1O0 rry/t
DiluEion Factor: 20
0.010 rr:E/L
Pllution Factor: 1
oe/20 -0 9 / 2t/ as s26s473
O3 :00
r?: oo
09/L',/ oS
aeloe/05
l-l-;30
09/08/os s25ss84
12:AA
09 /2A-oe / 2L/ As s26sss2
02 :00
ael28/ os s2721't2
TLme..; 15:40
9010E/9012A 0e /20-0e/ 2a/ as 5263s10
Time,.: l-2:00
RL Rcporting Limit
a Elevated reporting limlt. '['hc reporting tinrlt ls clcvatetl due to hlgh analyr levelr.
J Methnd bfank contarninarlon. '[hc as$ocimed rnctlrod bla* contains the rargo anal-vte at r rcportable level.
STL Denver
Iot-Sanple #...:
Date Sarpled- - -:
PARAMETER
IIRS Corporation
Client Sample ID: GTI-I,I2-O907O5
General Chemiatry
DSf 080243-008 Xlork Order #.. -: HJSJI
09/ a7 105' 1 3 : 30 Date Received, . 3 a9 /A8/05
RESULT RL I]NITS IVIETTIOD
Hatrix-- --,.1 WG
PREPARATION- PREP
^A,I{ALYSTS DATE BATCH *
pH
Anuronia aB N
Ch.Ioride
Fluoride
Nit,rate
Iilitrate -Ni trite
SuIfaEe
Total Cyanide
NOIE (S} :
I - 0 0 - 10 r[o urrits slr846 90408
Dilution Factor; I enalysle Time..: 17:05
5-3 O-1O ttg,/L UCAIII{ 350,l-
Dilutlon FacEor: J. Analysia Time..: 03:00
12oo0 J, Q 25O W/L t CAIIIil 32s.2
pilutlon FacEor r 100 Analyeis Time. . : 17:00
0 .58 J 0 . r-o wg/n ucAr{I{ 3'[o .2
Dilution Factor: 1 Analyois fime. . ' 1L:30
o .23 O . t-O vq,/L lICAr{n 353 .2
' oiluElon Factor: I Analysis Time. , : 12: 00
o -23 O . 10 ttlg/T, }ICAHW 353 .2
Dilut ion Factor: 1 Analysie Tlrue . . : 02 : 00
20oo J,Q l-ooo rrg/L ucAlft{ 375-4
piluclon FacEor: 200 Analysie TLme..: 15:40
t[D 0 .010 mg/L SWB45 90108/ g0t2A
Dilution Factor: 1 enalyeie Time. - : 12;00
ae / 08/os
oe/20-oelzllas
ael 18/os
oe/oe/as
ae / oB/os
52s1527
5255i4'13
s2532ss
525254L
s255584
as lza-os/z:rl os s26s5u, o
ae /zfE/ os 5272L72
a9l2o- oe / 2a/ os s263510
RL Reponin3 l-irnit
J Mc0od blank coutanrlnation. Thc assoclaatl metrod blank contains rhc nrget analytc at it reportable levcl.
a Ehvarcd rcpordng llmit. l'he reporrlng llntit is elevared due to high uralyrc lcvcls.
STL Denver 39
ac DATAASSOCTATTONW
D5r080243
Sample Preparation and Analysis ConErol Numbers
SAMPLE#MATRIX
AIVALYTTCAL
METHOD
LEACH
BATCH #
PREP
Plrg.L-t
5263359
5253255
525254L
526 555 2
52655 B4
525 3 51_ 0
5265L72
5259437
525L527
5263369
52657-6L
5272L72
526547 3
s253255
s25254L
526ss52
526 55 84
5263 51 0
5265L7 2
5259437
s2sLs27
5253369
s26s26L
527 2L7 2
526s47 3
5263255
52 5 2541
527 L67 9
5271705
5253 5l_ 0
5265L7 2
5259437
5251,527
5253359
s255261
527 2772
5255473
MS RUN#
001
002
brQ
WG
WG
WG
WG
WG
I^IG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
sl{84 5 82608
MCAWI^I 325 .2
I,ICAhil^I 340 .2
MCAI,{Iil 353 -2
IvlCAIrll^I 353.2
sw845 90r. aB/ 9AL2A
sw845 5A2A
sw845 7470A
sw845 90408
sw846 82508
sw84 6 5 0108
MCAWW 375.4
MCAWW 350. L
MCAWW 325.2
MCAWW 340 .2
MCAWW 353.2
MCAWW 353 .2
sw845 901A8/901-2A
sw845 5020
sw845 7470A
sw845 9040B
sw846 82508
sw845 60108
MCAWW 175 -4
MCA!,IW 350 .1
MCAvilW 325 -2
IY1CAWW 344 .2
MCAhTW 3s3 -2
MCAWW 3s3 -2
sw845 901A8/90r.2A
sw846 6020
sw845 7470A
sw845 90408
sw846 82508
st^I845 50108
lrcAwlrl 375 .4
MCAI{W 350 .1
(Continued on next
5253254
5253 l_ 5 9
52551_ 0 2
526s344
5263338
526510 5
5262L07
s25sL29
s2632s0
5265L7 9
5272L03
5255288
5263L59
525510 2
5265344
5263338
526510 5
52621A7
525 5L29
5263250
s265]-7 9
5272103
s26s2 8B
5253l_6 9
52551-02
527L432
s7.63338
5265l- 0 5
5262L47
52551-29
5263250
526sL7 9
5272103
5265288
003
004
STL Denver
page)
40
0c rlaTAAssocrATroNw
Dsro80243
Samp1e Preparation and AnalYsie Control Numbers
SAIVIPLE#MATRTX
00s
005
007
008
WG
WG
WG
WG
WG
WG
WG
WG
WG
I^IG
WG
WG
WG
WG
WG
WG
WG
vsG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
WG
AI{ALYTTCAL
TVIETHOD
MCAWW 325 .2
MCAWW 34O .2
MCAWW 353.2
IvICAWW 353 .2
sw845 901OP/ eOl-2A
sw845 6020
sw845 7470P.
sw846 90408
sr{845 82508
sw84 6 6 01-08
MCAIfi^I 37 5 .4
MCAWW 350 .1
MCAWW 325 -2
MCAWW 34A -2
MCAI^IW 353.2
MCAWW 353 .2
sw845 90L08/eo12A
sw846 5020
sw846 747AA.
sv{84 6 904 0B
SW845 B25OB
sw84 6 6 0l-0B
MCAWW 315.4
MCAWW 350 .l-
MCAWW 325.2
MCAWW 34A .2
MCAI^n^l 353 ,2
MCAWW 3s3.2
sw846 901A8/eo12A
SI^IB4 6 6020
sw846 74704
sw846 90408
sw845 82508
sw845 60108
MCAWW 375.4
MCAWW 3s0.l-
MCAWW 325.2
MCAWW 340.2
IvICAWW 353 . 2
IqcAvil}^I 353.2
(Continued on next
LEACH
BATCH #
PREP
BATCH #
s263255
525254L
s265552
5265s84
5263 510
526sL7 2
5259437
525Ls27
s2633 6 9
526526L
5272172
526s47 3
5263255
s2525 4 1
527 L67 9
5271705
s263510
5265L7 2
5259437
s251527
5263359
526s26L
s27 2L7 2
526547 3
5263255
5252s4L
s265552
526s s 84
s263 510
526sL7 2
5259437
5251527
5263359
526526]'
5272L'.12
525547 3
52632 5 5
525254L
52655 s2
5265s B4
MS RUN#
5263 15 e
5255102
s265344
s263338
s2651 05
5262L07
525512 9
52632sO
526sL7 I
s272LA3
s2652 B B
5263 ]-5 9
s255 r_ 0 2
5271,432
5263338
5255l- 0 5
5262L07
5255129
s253250
s265179
s272103
52652I I
5263 169
525s102
52653 44
5263338
s265 1 05
5262107
5255L29
5263250
s26517 9
5272103
5265288
s26315 9
s255102
52653 44
STL Denver
page)
47
AC I}ATAASSO,CI.ATIONW
DsrOAO243
Sample Preparation and Analysis Control Numbers
SAIvIPLE#I{ATRTX
008 WG
WG
WG
WG
WG
WG
WG
WG
AI{ALYTTCAL
I.dETTIOD
swB46 e0r.0B/e0r-2A
sw846 6020
sw845 7474A
sw84 6 904 0B
sw845 82508
sw846 601-08
MCAWW 375.4
MCAWW 350. L
LEACH
BATCH #
PREP
BATCH #
5:2-635L0
5255L72
s259437
525L527
526335e
526525L
s27 2L7 2
526547 3
IvlS RUN#
5253338
526 5l_ 05
5262LA7
5255L29
s263 2s 0
5265L7 9
5272L03
s26s2BB
STL Denver 42
}IEIEOD BT,ATIIK REPORT
cClDrS volatilee
C1ient t'ot *.--, D5I0B0243
MB lot-Sanr4rle #: D5I200000-369
Arralyeis Date - - : 09 / L9 / Os
Dilution Factor: 1
PARAMETER
Chlorof orrn
SURROGATE
Dibromofluoromethane
L , 2 -DichloroeEhane -d4
4 -Bromofluorobenzene
Tol-uene-dB
NOTE (S) :
Tlork Onder *.
Prep Date-,. -
Prep Batch #.
RESUI,T
ND
PERCENT
RECO\ERY
96
94
93
95
I,IMTT UNITS
llatrix... : WATER
Rnalysie Time--: 15:39
IvIETI{OD
HKOQElAA
ae/Le/a5
s263359
REPORTING
L .0 wg/1.
RECOVERY
LTMITg
(ts 118)
(62 L28l
(78 1-18)
(tt 11?)
sw846 82608
Calculadoils arc performcd before roundlng to avoirl rourul-off crrors ln cdculatetl renrlts.
STL Denver 43
ffi CONTROL SAT,IPIJE EYALTIATION RBPORT
cclus volatiles
Client Iot *. - - :
LCS Lot-Saqlle*:
Prep Date -., I
Prep Bat,ctr #. - - :
Dilution Pactor:
PARAMETER
D5I080243 l{ork Order # -
D5I20A000-359
oe/Le/os
s263369
1
Analysis DaEe.
Analysis Time.
PERCENT
RECOVERY
HKoQEI_AC
os/Le/as
15; l-9
Mat,rix- -,-.. - -- r !il.A,TER
1, l-Dichloroetheue
Berrzene
Chlorobenzene
Toluene
Trichloroethene
SURROGATE
D i brorno f 1 uo rome t hane
L, 2- Di chloroethane -d+
4 - Bromof luoroberrzene
Toluene -d8
llorB (s) :
75
97
95
101
95
RECO-vlERY
LIMTTS
rc6 L32l
lts 120)
(zs 118)
QA 118)
09 L22l
PERCENT
RgcovERY
92
B7
92
101
METHOD
sw845 82608
sr{845 82508
srr845 82508
sw846 82508
sn845 82508
RECOVERY
LTMITS .(zr 1r.B)
(62 128)
(78 1"18)(tt 117 )
Calculation$ are pcrfbrrned before roundlng tei avoid round-ol'f crrors in calculorcd rcsults.
Bold print dcnorcs colrtrol paramctcrs
STL Denver 44
C1ient tot #- - -:
IrCS L'ot-sanqr}.e#:
kep Date ---:
Prep Batch *---:
Dilution Factor:
PAIU\METER
D5r080243
D5T200000-369
oe/Le/0s
s263359
1
W COIUTROL SAIIIPI,B DATA REPORT
K/r+s Volat,iles
t{ork Order *.,,; HKOQEIAC
Analyeis Date., i 09 / L9 / 05
Arra1.ysis Time . . Z 15 ; 19
ltatri]E. . . o, . . . . r WATER
PERCENT
RECOVERY METHOD
1, I.-Dichloroethene
Benzeue
Chlsrobenzene
To]-rrene
T:richloroethene
SURROGATE
Dibromofluoromethane
L ,2 -Dichloroethane -d4
4 -Bromofluorobenzene
Toluene - dB
SPIKE
AIyIOIINT
10-o
10_o
10-o
10.o
10.0
MEASURED
AMOUNT
7 -57
9 -74
9-58
10 .1
9 .46
PERCENT
RECOVERY
92
87
92
10l-
UNTTS
Iu.g/L
U.glL
lu.s/L
:uglt,
ruig/L
RECO\MRY
I,IMTTS
76
97
96
101
95
srr845 82508
sYI845 82608
sr{845 A260H_
sH845 82508
sI{845 82508
(zr ].t B)
(az 128)
(zs L18)
(tt LL7)
NO:[B (S} :
Calculatlons arc pcrlormed betbrc rourding to avoirl rountl-off crrors in calculated results.
Bold prlnr dcnocs conrrol parfinctcrs
STL Denver
}TATRIX SPTKE SAHPI;B EI'AITIATION REBORT
GC/Its volatiles
Client Lot *. . . :
US t,ot-Sample *:
Date Saupled...3
Prep Date - -. i
Prep Batch #- - -:
Dilution Faetor:
PARAMETER
D5r080243
D5I080243-004
as/A1/os oe:55
oe/Le/os
5263369
6 .66
Work order l*- - -:
Date Received- - j
Analysie Date- - :
anahrgis Time. . l
HJ5.JIv11.C9 -MS
HJ6'JMLDA-I"ISD
ae/08/os
ae/Le/os
l-7:3L
I{atrix--...-.--! I{G
METHOD
RPD
LIMITS
1, I-Dictr-loroethene
Benzene
Chloroberrzene
Toluene
Trichloroeth.ene
S[]RROGATE
7A
77
105
101
98
96
108
104
99
95
PERCENT
RECO\MRY
RECO\rERY
IJIMITS RPD
(66 L32l
(55 L3Zl 2.O
(75 LzAl
(7s 120) 3-5
( zs 1r-8)(ze 1181 2-6
(78 118)
(78 118) 3-8
(79 L22l
(79 L22) 3 .8
PERCENT
RECOVEg
9s
9s
90
91
92
90
103
97
(o-261
(o- zI-l
( 0 -20)
(o-221
(o-231
RECOVERY
LIMITS
(73 118)
(7t t 18)
(62 128)
(52 1-2 B )
(ze i-18)
(78 118)
(tt r17 )
(tt l-17 )
sH846 82608
srr845' 82608
str845 82608
sn846 82608
slr845 82608
slr846 82508
sr0845 82608
STTB45 82608
slr846 82608
sH846 82608
Dibromofluoromethane
L , 2- Dichloroethane - d4
4 -Bromofluorobenzene
Toluene -dB
lilorcE (s) :
Calculattons Bre perfornrul bcfore roundlng ro avoid round-otT crror$ irr calculated rcsults.
Bold prlrtt rlenores conuol parametcrs
STL Denver
UATRIX SPIXG SAT{PI.E DATA REPORT
GCII{S Vo}ari}ee
C].ient Iot #- - -:
DIS tot-Sarqlle *
=Date Sarryled---:
Prep Datgo !. ... !
Prep Batch fi...:
Di].ution Factor:
PAITJ\METER
D5r080243
D5r080243-004
09/a7/os o9:55
ae/re/as
5263359
6 .66
Work Order #- - -:
Date Received. . i
analygie Date- -:
AnaJ-ysis Tirne- -:
I{J5JIvt1C9 -IvIS
HJSJIVI1DA-},ISD
0e/0810s
oe/Le/a5
l-7;31
Matrix.- ----: WG
METHOD
SAMPLE SPTKE
AMOUNT AIqT
ND 65 -7
ND 66 --l
ND 55.7
r{D 66.7
ND 65.7
ND 65.7
ND 66.7
ND 66.7
ND 66 -7
ND 66.7
MEASRD
AMOUNT TI}TITS
52.2 luglL
5L,2 ug/L
70.L lug/L
67 -6 rug/L
65.5 ug/L
63 .9 vg/L
72.A ug/L
69.4 rug/L
56 - 1 luglL
63.7 :ug/L
PERCENT
RECOVERY
9s
95
90
91
92
90
103
97
PERCIUT
REC\MY RPD
1, l-Dichl-oroethene
Ben'zene
Chlorobenzene
To].uene
Trichloroetlrene
SURROGATE
Dibromo f luoromethane
a, Z-Di chloroethane - d4
4 -Bromofluorobenzene
Toluene -dB
NO|[E (s) :
7A
77 2-O
105
101 3 .6
98
96 2.6
108
104 3-8
99
95 3.8
RECOVERY
ITIIvIITS
(tt 1L8)
(73 118)
(az 128)
(sz 12 8 )(te 118)
(za 118)
{7t 117}
(77 11- 7 )
sr{846 82608
sTr846 82608
S?Y846 82608
sr{845 82508
sI{845 82608
st9845 82608
sw846 82508
srl845 82608
sw846 82508
sw845 82508
CalculadoDs are perforn'red before rounding to avoid round-off err()rs iu calculated results.
Bold print denores control paranreters
STL Denver 47
MHTEOD BIAIIIK REPORT
TOTAL l[gfa] s
C1ient I,ot * -
PARAMETER
: D5I0I 4243
RESUIJT
REPORTTNG
IJIMIT UNITS
tlatri-x ......; WATER
METHOD
PREPAIU\TION- WORK
A}TALYSIS DATE ORDER #
MB Lot-Sanple *: D5I150000-437 Prep Batch *---' 5259437
Mercury ND 0 - 00020 nrg/t, SW846 7470A
Dilution Facto!: 1
Analyslo Tlme.,: 18:06
526517 2
sw84 5 5020
oe/nlas HK1IPA1AA
oe / 23 -oe /28 / as HK4 9N1AA
l{B IoE-Sarqr1e
Cadmium
#= Dsf 220000 -L72 Prep Batch #- -
ND 0-0010 mg/L
DiluEion Faetor: 1
nrralyeie Time. . : 01 :56
ND 0. O02O mg/L
Dilution Factor: 1
Analysle TIme. . : CI :55
Selenium
UB Lot-Sample *= D5f 220000 -26:- Prep Batch #-
Alurninum ND 0 . 10 mg/ Y,
A16enic
Dl1ut,ion Factor: L
Analysio Tlme..: 23;41
0.01s mg/L
Dllution Factor: 1
analyais Time..: 09:23
0 . 01.0 ng/L
Dl lut l on Factor : 1.
Analyels Tlme-.: 09:23
0.20 mg/L
ni Iut ion Factor : 1
Irrralysis Time..: 23 l41-
0.010 Yag/L
Di lution Factor: 1
Analyolo Tlme-., 09:23
0 . 010 mg /1,
Plluuion Pactor: 1
turalysie Time..: 09:23
0 . 1,0 mg/L
Di luLion Factor c 1
Analyoie Time. . : 23 z4L
Barium ND
Calcium
Chromium
Copper
Iron
sw84 6 6020 09 / 23 - A9 / 28 / as HK4 eNt-AC
526525L
sw84 6 5o1oB Oe / 23 / Os HK5QW1AC
sw846 60108 oe /23 -a9 / 27 / As HKSQWI.AD
sw845 50108 oe / 23 - oe / 27 / a5 HKSQWI"AE
sw84 6 50108 0e/23/05 HK5QWlAM
sw84 5 6 0108 oe / 23 - 09 / 2't / 05 HKSQW1AF
sw845 50108 ae / 23-ae /27 / os HKSQWTAG
sw84 6 6 0108 HKsQWT.AN
ND
ND
ND
ND
STL Denver
IrD
(Cont,inued on next page)
ae/23/os
48
UEIEOD BI,ANK REPOR:T
IIOTAL FIetals
C1ient Lot #.
PAIU\METER
: D5f08 0243
RESULT
REPORTING
I,IMTT UNTTS METHOD
lIatri]E. , , . . . , , . r WATER
PREPARATION- WORK
ANALYSTS DATE ORDER #
Iread
lvlagnesi-um
NickeI
PotasBium
Si lver
Sodiurn
Vanadium
ZLn.c
Zirconium
}[D
ND
ND
IilD
0 .0030 mg/L
Ollution Faetor: 1
Analysie Time. . : 09 :23
0 .20 mg/L
Dilut ion Factor : 1
Analysis Time.,r 23:4L
0 . 040 ng/t,
Dilution Factor: 1
Analyeis Time,.: 09:23
3 . 0 trrglL
Dllution Factor: 1
Arralysie Time. . : 23 t4t
0.00s0 rirg/L
Dilution Factor: 1
Arralysie Time. . : 09 223
5. O mg/T'
Dilutlon Factor: 1
Ana:ysie Time. , : 23 247
0.01-0 mg/l'
Oilution Factor: 1
Anal-ysie Time. . : 09 :23
0 ,020 mg/L
Dilution Factor: 1
Analysie Time..: 09:23
0 - 01s mg/L
DiIutlon Factor: L
Analysis Tirne. . r 23 24L
sw84 6 6 0108 oe / 23-a9 /27 / os HKSQW1AJ
sw845 60L0B oe/23los HK5QWlAQ
sw846 601,08 09 / 23 -09 / 27 / 05 HKsQwlAi{
sw845 501-08 oe/23/os HKsQWlAP
sw84 5 5 0108 oe / ?3 - 09 / 27 / OS HKSQWIA]\ND
ND oe/23/os HKsQW'A8o
ND
IUD
}TD
sw845 501_oEI
sw84 6 6 01-0E}oe l23 - oe / 27 / os HKsQvn-AK
sw84 5 5 0108 ae / 23 - oe / 27 I os HKSQrI1AL
sw84 6 6 0108 ae/23/os HKSQW1AT
}UOIE (S) :
Calculatlons arc pcrlornrcrl r,,vh'lbre rouncling to 'avoitl rourd-olf erron irt calcultwd resulu.
STL Denver 49
TJTBORATORY COIITROL SAUPI,B EI'TALTIATIO}I
TOTAL ltletalg
RBPORT
PREPAIU\TION-
A}IALYSIS DATE
MaErix-- ---.= WATERClient l,ot l#.
PARAMETER
LCS Lot-Saqlle*:
Mercury
LCS Lot-Sary>}e#:
Cadrnium
Selenium
LCS lot-sarqrl-e#:
Si lver
Aluminum
Arsenic
Barium
Chromium
Copper
NickeI
Lead
Vanadium
D5r080243
PERCENT RECOVERY
RECO\IERY LIMITS METHOD
DSII-50000 -431 frep Bateh # - -
100 ( Bs 114 ) SW846
D:. Lutiorr Factor : 1
D5I22A000 -172 Prep Batch #. -
95 ( ag r-10 ) sw846
nilutIon Factor: L
(az Ltz ) sw845
DiLution FacLor: 1
DSf 22O0O0 -26L Prep Batch #- -
ae/23/os
Time.,: 18:08
ae/23-oe/28/05
Tlme--: o2:oo
ae/23-oe/28/os
Time.-: 02r00
- : 5259437
7474}.
Analya i a
-: 5265172
6A2A
Ana lys i e
6020
Ana Iys i s
-: 526526L
6 0108
Analysl s
50108
Analyol e
6 0 r_08
Ana lysi s
6 01_ 08
Analyo i o
6 0108
Ana llrei s
6OlCB
Analyei e
6 0108
Analyei s
5 0108
tura lye i s
WORK ORDER #
HIT/PAT.AC
HK4 9N1.AD
HK4 9N1AE
9B
100
102
( as LL4) SWB46
Dllutlon Factor: L
( as 108) sw845
DlluClon FacLor: 1
(ag 1oe) swg46
oilution Factor: 1
( gr 113 ) swa4 G
Dllutlon Factor: L
(89 a]-z) SW846
Oilution FacEor: 1
( 86 1r-0 ) SW845
Dilution Pactor: 1
(gO 110) St^1845
Di lut ion Factor: L
(gr 111) Sw845
Di lution Factor: 1
( ee LLz) Sw845
Di lutiorr Pactor: 1
(Continued on
ae / 23 -oe / 27 / os HKsewJ-AU
Time.,: 09:28
09/23 / 0s HKSQWIAV
Tlrne.,: 23:45
a9 /23-oe /27 / os HKsewlAw
Time. . : 09:28
ae / 23 - ae / 27 / os HKsQwlAx
TJ.me, -: 09:28
oe l 23 -oe / 27 / 05 HKSQWLA0
Time. . : 09:28
ae/ 23 -ae / ?7 / as HKsQwlA]-
Timo. . : 09:28
oe / 23 - oe / 27 / as HKsQwlA2
Time-.: 09:28
a9 /23 - oe / 27 / os HKset.li-A3
Time, . : o9:28
5oloB a9/23-09/27 /05 HKSQW]A4
Analyeie'Iime. . : 09 : 28
next page)
STL Denver 50
I,ABORATORY C1oNIROL SAI.TPIA EV:ALTIATION REPORT
TO:IAL Heta]'s
C1ient Lot # -
PARAMETER
Z:-nc
Calcium
fron
Pota6siurn
Ivlagnesium
Sod i um
Zirconium
NOIE (S} :
D5I080243
PERCENT
RES-O\ERY
93
95
96
l_03
99
1"00
104
Di lution Factor : 1
(eg l-l-0) sw846
Dllution Factor: 1
(85 LL1,) sw846
oi lut lon FacE.or : 1
AnaIys i s
Analyo I o
5 0108
Ar:a lya I s
6 0108
Ana lys i e
RECOVERY
LIMITS IVIETHOD
( 8S Lr-o ) SWB46 5O1oB
Dilution Factor: 1
(eg 110) sw946 50108
I,llatrix. . - - - - : WATER
PREPASATION-
AI$ALYSIS DATE WORK ORDER #
09 / 21 - 09 / 27 / As HKSQWTAS
Time.,: 09t?8
oe / 23 / os HK5QI^]1A6
Tlme..:23t46
a9 / 23 / os HKSQWI-A7
Tl"me.,: 23:46
09/n/as HKsQwlAs
Time..: 23t46
( e1 111 ) SWB46 60108
Pllutlon FacLor: 1
(gr 7L2) SWB46
Dllution Factor: 1
( 75 Lzs ) SW84 6
oilution FacEor: l-
ae/n/a5
Time- -: 23 146
0e/n/as
Tlme..: 23:46
oe/23/os
Tirne. . : 23:46
Analya i s
60L0B
Ana lys i s
6 0108
AnaLys i s
HK5QW1A9
HK5QW].CA
HK5QW1CC
Culculatiuns are perfornred bcforc roundlng to avoid rtuud-off crror.s in calculated rcsults.
STL Denver
ffi COIIIROI, SAT.TPI,B DATA REPORT
I0TAL Dietalo
Client Iot, #---: D5f080243 Dlatrix-- ----= WATER
SPTKE MEASURED PERCNT PREPARATION- }ilORK
PARAMETER AIIOUMI AIvIOUNT IINITS RECVRY METIIOD AIIALYSIS DATE ORDER #
I,CS Iot-Sample*: DSf160000-437 trep Batch *...: 5259437
Mersury 0. 0os00 o. 00502 ng/t" 100 swB45 7470A 09/n/a5 HKVPA1AC
Dllutlon Factorr 1 Analyaia Time..: t8:08
I,CS lot-Saqrle*: D5r22000A-172 Prep Batcb *...: 5265;.-72
Cadmium 0 .0400 0.0378 w/L 95 Sw846 5020 o9/23-og/za/0s HK49N1AD
Dllutlon Factorr 1 Analysis Time., r 02:00
selenium 0 .0400 0.03s2 w/L 88 sw845 6020 o9/23-o9/28l0s HK49N1AE
Dllution Factor: 1 Analysie Time..: 02100
I,CS l,ot-SaryIe#: D51220000-261 Prep Batch f . - -: 526526L
silver o.0s00 0.0489 mg/L 98 Sw846 50108 O9/23-A9/27/A5 HK5QW1AU
DiLution Factor: 1 Analyalo Time-.: 09:28
Aluminum 2 .00 2 .00 r,itg/r, 100 swg46 50108 os/zl/os HKsewl-Av
Dilutior Faccors I Analyels Time.. t 23t46
Areenic 2 .00 L .89 mg/L 95 Slt846 60108 O9/23-O9/27l05 HKsQWI-AVI
Dllutlon Factof,; 1 Arralysie Tim6.. t 09t28
Barium z.ao 2.o4 rltg/L ro2 s!f846 GoloB og/23-09/22l05 HKsevllAx
Dilution Fectorr 1 Analyols Time.. ; OgrZO
chromium 0.200 0.195 ms/T, 98 SW846 50108 O9/23-09/21/As HKsQwlAo
Dilution Factorr 1 Analyais time.. r 09128
copper 0.2s0 0-246 mg/r, 98 sw846 5Or.0B A9/23-0s/27l0s HK5QwlAL
Dllrrtion Factorr 1 ADalyeia Time.. : 09t28
Nicke} 0 -s00 0-48? trlg/L 97 SW846 50108 09/n-A9/2?/05 HK5QW1A2
Dilution Factor! 1 Analyais Tinre.. t O9t28
Lead 0-s00 0-485 mg/L 97 SW846 60108 09/23-O9/27lOs HKsQwlA3
Dl.lutlon Eactorr 1 Analyais Time,. t 09t28
vanadium 0.s00 0.492 tw/L 98 sw845 50108 09/23-09/27105 HK5QW1A4
Dlluclon Factor! 1 Analyeia Time..: 09;28
STL Denver
(Continued on next page)
52
Client Lot. #.
P4.RAr-qEILER _
Zinc
Calcium
fron
PoEaBBium
Magneeium
Sodium
Zirconium
NO{rB (S} :
- - = D5f080243
SPII(E IvIEASURED
Ar\,rorrNT_. +I4o\ll\l}. .
TABORATORY
UNITS
EOITTROL SAIITPI,E DATA REFORT
fUfAt Heta1s
PERC}flT
RECVRY METHOD
Matrix-- --..:
PREPAITJ\TION_
AI{A,LYSTS DATE
WATER
WORK
ORDER #
0 .500 O .464 ntg/L
Di lution
50.0 47,7 mg/L
ni lut ion
1 , 00 0 .964 mg/I'
Ol lut ion
50 . 0 5L .4 rrrg/i
DiluE ion
50 .0 49 .s mg/L
oilution
50.0 50 .0 rng/L
Pi 1ut ion
0 - 500 0.519 mg/t'
ollut ion
swB46 60108 09/23-09/27 / A5 HKSQWIAS
Analyeie Time..: 09:28
sw845 6oloB 09/23/05 HKSQWIAs
Analyeie Tlme. - = 23 r45
sw84 5 5 0108 ae / 23 / Os HKSQW1A7
Analysis TLme..' 23:45
sw846 so toB 09 / 23 / 0s HKSQWI,AB
Analyelo Time..: 23:a6
sw84 5 5 0l- 0B oe / 23 / 05 HK5QW1A9
Analyois Tlme.-' 23:46
sw845 50108 oelz3/os
Analyele Time..: 23:46
sw845 5ot-oB a9/23 105
Analyeie Tl.me- ., 23 :46
HK5QWl,CA
HKSQW1CC
93
F'actor : L
95
Factor: 1
95
Factor: 1
l_03
F'actor: L
99
Factor: 1
100
Factor: 1
104
Factor: 1
Catculariol)s arc pcrlbrmcd bcfore roundlng rc avold round-off errors in calculated rcsuls.
STL Denver 53
IIAItIX SPfKE SAI.{PLE EIfAIIIAfIOfif RBPORT
TOTAL l{eta}s
Cl-ient Iot #...: D5I080243
Date Sam5lled.--3 a9/a7/05 09:55 Datre Receiwed.-r 09/08/05
PERCE}ST RECOVERY RPD
PAIU\METER RECOVERY LIMTTS RPD LTMITS METHOD
Ittatrix-- ----: WG
PREPARATION- WORK
AI\TALYSIS DATE ORDER #
MS loL-SarryIe #:
Ivlercury 75
73
I{SI Iot-Saryrle *,
Cadmium 95
98
Selenium 9l-
100
US Lot-sauple f ;
Alurninum 9 B
1-01
Arsenic 107
L72
Barium 95
99
Calcium
D5f080243-004 Prep Batch #-.
N (AS 114)
N (es 114) 3.3 (0-10)
ni IuE ion Fact,or ; L- Analyeis TLme..' l-B:l.I
D5I0 B0 243 - 0 04 frr=p Batrch * - .
(sg 1L0)
(ag l_1_0) z.o (o-201
D:. Lut ion Factor : 10
Artalysis Time. . : 02 :29
(82 112)
(82 7L2) 7-5 (0-20)
DiLuEion Factor: 1O
Analyels Time..: A2:29
D5f080243-004 Prep Batsch #-
( a: t-t-g )(e: 119) 2.5 (O-25)
Dllution Factorr 5
Analysie Time. - : 23 :54
( s+ L24l
(Ba t24) 4.1 (O-2s)
DlluE ion Factor: 1
Analysis Tlme..; 1A:22
(8S 120)
(85 120) 3.9 (O-25'l
Di lut ion Fact.or : 1
Ana}I'sis Tlme. - : AO t22
(ae 1s3)
(48 1s3) (o-zs)
Di lur ion Pactor : 5
Analyoio fime. . : 23 t54
oe / 23-oe / 28 / a5 HJ5JM1C3
a9 / 23 - oe / zB / os HJG.rl{1c4
ae / 23 - oe / 28 / a5 HJ6.IM1C5
ae / 23 - ae / 28 / os HJ6JI,!1C5
: 5259437
sw846 7470A
sw846 7 47 0A
: 5265L72
sw846 6020
sw846 5020
sw845 602A
sw84 6 602A
; 526526L
sw845 601_08
sw845 5010B
sw846 60108
sw845 60108
sw846 60108
sw846 50108
sw845 501-08
sw84 6 6 0108
oe/T/a5
ael23/os
oe/23-ae/26/05
ae/23-ae/26/as
HJ6JM].CL
HJ6JM].CM
HJ5JMIDQ
HJS,JlrllDR
oe/23-ae/27/as
oe/23-ae/27 / as
HJ6.IM1DT
HJSJM1DU
oe/23-oe/27/os
oe/23-oe/27/os
HJ5.TM1DV
HJSJMlDW
NC, MSB
NC, MSB
oe / 23 - oe / 25 / a5 HJ5JM1CN
09 / 23 - 09 / 26 / 05 HJSJrvrlCP
STL Denver
(Continued on next page)
54
C1ient l,ot, * -
Dat,e Sarpled -
FARAMETER
Chromium
Copper
Iron
Lead
Magnesium
Ni ckel
PoEaBBium
Si lver
Sodiurn
(73 13s)
(73 13sl A
Dt luc i on
Analye i e
}N:[RIX SPIKE SATdPIE EII'AIJIIATION REPORT
TOifAL lrleta]-s
: D5I08O243
: 09/07/05 09:55 Date Receiwed--: 09/08/os
PERCENT RECOVERY RPD
RECOVERY LIMITS RPD LIMITS METI{OD
SWB46 6O1OB
.2 (O-2s) SW846 50108
Factor: 1
Time..: 7A:22
I{atrrix-- ----: WG
PREPARATION- WORK
AT.TALgSTS pATE ORDqR #
ae / 23 -09 /27 / aS HJSJMLDX
ae / 23 - 09 / 27 / AS HJSJM1D0
09 / 23 - ae / 27 / os HJ5JM1A9
09 / 23 *A9 / 27 / A5 H,.]5.IM1CA
og l23 -o9 / 26 / A5 H,J5W1CQ
09 / 23 -Ae / 26 / Os H,J5JM1CR
ae / 23 - 09 / 27 / As HJ5'JMI,CE
ae / 23 -09 / 27 / os HJsirMLCF
ae / 23 -o9/26 / Os HJ5.IM1CV
oe / 23 - ae / 26 / 0s HJSJrul-cw
oe / 23-09 / 27 / 05 HJ5,]M1CC
oe / 23 - a9 / 27 I A5 HJ5JI41CD
09 / 23 -09 / 26 / os HJ5JMICT
09 / 23 - Ae / 26 / A5 HJ5,fM]-CU
ae / 23 - 09 / 21 / As HJG'JlrlDN
ae / 23 - oe / 27 / as HJ6JMI-DP
o9 /23 -A9 /26 / As HJ6.rIvtlCX
09 / 23 - ae / 26 / 0s HJsJIvllC0
B5
89
La7
L22
93
93
93
97
83N
87
130
t_35
NC, MSB
NC, MSB
(89 1-2L) SwB45 60108
(89 1.2L) 3.5 (0-2s) SW845 50108
Di lut ion Factor : I
Analysis Tirne. . : 7O =22
( 82 LZel
(az L29, 4.6 (0*25)
Dilution Factor: L
Analyeie Tlme..: ta:22
(s2 1ss)(s2 1ss) 0.70 (o-25)
Dilution Factor: 5
Arralyoie TLme. . ; 23 r54
(62 145 )(az L45) (0-2s)
Di lution Faetor : 5
A-nalyeie Time. . : 23 254
(a+ r20)(se 120) 3.2 (O-25\
ni Iut, ion Factor r 1
Analyeie Time..: 1-.A:22
0e L32)(75 L32) (0-2s)
Dilution Factor, 5
Analysis Tlme-.: 23:54
(ts 141)
(7S L4r) 4-o (o-?sl
Dilution Faetor: 1
Analysie Time. . r tA 222
(zo 203)
(70 203) (0-40)
Di lut ion Faet,or : 5
Analysis Tinne. . : 23 : 5{
sw846 60108
sw84 5 6 0108
sw846 501_0B
sw84 5 5 010B
sw84 6 5 0108
sw845 50108
sw846 501.08
sw84 5 5 0108
sw845 5010B
sw846 50L08
sw845 50108
sv,I84 6 6 0108
sI^]845 60108
s}1I84 6 5 0108
NC, MSB
NC, MSB
NC, MSB
NC, MSB
STL Denver
(Continued on next page)
55
Client I.ots #.
Date Saryrled.-
PARAMETER
Vanadium
Zinc
Z:-rconium
NOIE (S) ;
D5r0 B0 243
09/a7/os o9:55
PERCENT
RECOVERY
90
93
85
BB
1_03
r05
RECO\TERY
IJIMITS
(eo
(oo
fgo
( B0
I{ATRIX SPTI(E SA}TPI,E EVALITATIOIS REPORT
TC)([AL Metals
Date Receiwed- - : A9 /08/05
DIatrix.WG
PREPARATTON- WORK
ANALYSTS DATE ORDER #
a9 /23 -A9 / 27 / Os HJSJ},r1CG
a9 / 23 -a9 / 27 / as H,J5'JIYIIcH
oe / 23 -ae / 27 / as HJsJM1CJ
ae/23-ae /27 / as HJGJMTcK
oe / 23 - 09 / 26 / 05 r{J5JM1C1
oe / 23 - oe / 26 / a5 HJ6JM1C2
RPD
RPD LII{ITS IyIETHOD(ss L20) sw845 50108
(es L20) 3.+ (o-2s) sw845 50108
Uilutlon Factor: 1
Analysle Tlme..: tO:22
137)
L37) g.: (0-25)
Pi lut, i on Faet or : L
Analysis Time..: 7A 22
120)
LZ}). 2.t (O-25)
ollueion Factor: 5
Analyeis Tirne- . : 23 : 54
sw84 6 5 0108
sw845 5 0108
sw846 501_0B
sw846 6010E}
Calculallons arc pcrformsl bcfore rourxling to svoid round-off crrors ln calculatcd rcsults.
NC Tlrc recovery arxl/or RPD wcrc not calculacd.
MSB Thc rccovery ard RPD wcre rct calculatal becaus thc sarplc amounl war grcarer dlan four ilmcs &c splke aDount.
N Spikcd aBalyte rccovcry ls orlBHc slatcd conlrol limits.
STL Denver 55
IiAIEIX SPTffi SAT'IPI'B DATA RBFORT
TOIIAL lttretal.e
C1ieat Ipt *- - -: D5r080243
Date sanf,rled...: 09/a7/05 09:55 Date Received- -= 09/08/os
SAMPI,E SPTKE
PARAI,IETER AIyIOI.]NI AIVIT
MEASRD
AMOI]I{T UNTTS
PERCNT
REC\IRY RPD METTIOD
FIatri)c.-...,---: WG
PREPARATION- WORK
A}IALYSIS DATE ORDER #
lts Irot-Sanple #:
Mercury
ND
lls Lot-Samtrlle #:
Cadmium
0.0039
0.0039
Selenium
0.011
0.0LL
HS lot-Sary>le *:
Al-uminum
ND
ND
Arsenic
DsI080243- 004 Prep Batch #- -
0.00500 0.00377 mg/L 75
Qualifiers: N
0.00500 0.00355 mg/L
Qualifiers: N
oilut.lon Factor:
Analysie Time. , :
s259437
SI^I845 7470A
3.3 SW845 7474A
526sL72
sw846 6020
2.0 sw845 5020
7 -5
sw845 6020
sw84 6 6020
ae / 23 / as HJSJl,rlCt
ae / 23 I as HJ6Jr{1CM
09 / 23 - A9 /28 / A5 HJ6JrvIlC3
a9 / 23 - A9 / 28 / A5 H.]6..TM1C4
ND 73
1
LB;18
D5r080243 - 004 Prep
0.0400 0.042L mg/T'
0.0400 0.0 43a yllrq/L
Batch #-
0 . 04 00
0.0400
2 .00
2 .00
2 .00
2 .0a
Dilution FacEor:
Ar.alysis Tirne- -:
0.0477 ms/L
0.0s14 mg/L
ni lut lon FacLor :
llnalyeie Time. . ;
2 . a4 mg/L
2.10 mg/L,
Dilut.lon FaeLor r
Analyeis Tlme. . :
2 .1,5 mg/L
2 -24 mg/L
Dilutlon Factor:
Arralyais Time. . :
2 . 04 mg/L
2.L2 ms/L
DiluEion Factor:
Analyeis Time. . :
: 526525L
2.5
95
98
10
A2 :29
91
100
10
O2 t29
98
101_
5
23 :54
107
Ll.2
1
10 :22
9s
99
1
tA 222
oe/23-ae/28/as
ae/23-ae/28105
HJ5'JM1C
HJ6,JM1C5
D5I080243-004 Prep Batch *-
5o1oB A9 123-0e/25 I as HJ6JM1DQ
5or-oB 09/23-A9/26 lAs HJ5JM]-DR
a9 / 23 - 09 / 27 / 05 HJ5.II\,I1DT
09 / 23 - 09 / 27 / os HJSJI,IIDU
sw84 5 5 0108
4.1 SWB45 60108
3,9
SWB4 6
SWB4 5
0.0078 2.00
0.0078 2 .00
Barium
0 .13
0 ,13
sw845 50108 Oe / 23 - 0s I 27 I A5 HJSJM1DV
sw845 50108 A9/23-0e/27 / A5 HJ5.IM1DW
STL Denver
(Continued on next page)
57
Client Iot #- - -:
Date Sarqpled- - - :
SAT{PI,E
PARAMETER AMOT]NT
Calcium
1400
IIATR,IX SPIKE SAUPI,E DATA RBPORT
TOTAIJ Metalg
D5I080243 llatrix- .-: WG
09/o7/05 09:55 Date Received. -= 09/08/a5
SPIKE MEASRD PERCNT PREPARATION- WONT
AIT,IT AMOI]NT UNITS RECVRY RPD METHOD ANAIJYSIS DATE ORDER #
50.0
50 .0
0 .200
0,200
1.00
1- 00
0 .500
0 .500
50 .0
50.0
0.500
0.500
SW84 5
SW84 6
50L0B
5 01081400
ND
ND
ND
ND
0,13
0. L3
530
53 0
0.080
0.080
13 90 mg/L
Qualifiers : NC, MSB
1430 mg/t,
Qualifiers: NC, MSB
ol lut.lon FacE or : 5
Analysls Tlme.,: 23:54
ae/23-ae/25/os
ae/23-oe/26los
HJ6,-llv11-CN
H.J5'JMlCP
Chromium
Copper
Iron
Lead
Magnesium
O , L72 mg/L
0 .180 mgll'
oilutlon FacL,or;
Arrai-ysis Time-. ;
1 . 05 mg/L
1 .05 $tg/L
Pi lutlon Faetor :
Analysie Time. . :
0.466 mgll
0.483 mg/f,
ni lut lon Fact,or :
Analyais Time. . :
oe / 23 - oe / 27 / a5 HJSJMIDX
oe / 23 - ae / 27 / os HJ5JM1D0
ae / 23 - oe / 26 / as HJsJvrlcQ
09 / 23 - 09 / 25 / Os HJ6fi"r1eR
sw84 5 5 0108
0.70 sw846 60108
3.5
B5
B9
1
l,.0:22
Ll7
122
1
L0 :22
93
93
5
23 :54
93
97
1
LO:22
4_2
4.5
sw845 50108
sw845 60108
0 .250 0 .295 mglL
0-2s0 0.30e mg/t
Dilution Factor:
Analysis Time..:
sw846 60108 A9/23-A9/27 /05 HJsJI4r-Ae
sw84 5 6 0108 A9 / 23 - 09 / 27 / As HJ5JM1CA
}TD
ND
677 ng/L
Qualifier6: NC,IvISB
699 mg/L
Qualifiers: NC, MSB
DiIUEion Factor: 5
Arralysie Time - ., 23 : 5{
0.497 N mg/L 83
0.513 'l,r.g/L 87
Dilu:ion Factor: L
tu:alysis T1me..: L0 122
sw84 5 6 0108 Oe / 23 - Oe / 27 / Os HJsJrvllCE
sw845 60L0B 0e/23-09/27/OS HJ5JMICF
sr^r84 5 5 0108 09 / 23 - Oe / 25 / aS HJ6.IM1CV
sw84 6 601-0B A9 / 23 - A9 / 26 / 05 H,J5.IMICW
sw845 60108 09/23-09/27/0s HJsJM1CC
sl{846 50108 A9/23-09/27 / AS HJSJrvllCD
Ni ckel
3.2
STL Denver
(Continued on next page )
5B
UAI TX SPIKE SAI'PI,E DATA REPORT
TCXIAL Metalg
Client Lt *-. -: D5I080243 }latrix- ..: hIG
Date sanpled--. z 09/01/o5 09:55 Date Received- -. ag/og/os
PREPARATTON- WORKsAMPLE sPrKE MEAsRD pg&.mur
PARAMETER Al,lOlrNT AMT AMOUNT UNI?S RECVRY RPD METHOD ANALYSIS DATE ORDER +
PoEassium
44A 50.0 492 mg/L SW846 60108 a9/23-09/26l0s H.]6.TM1CT
Qualifiers: NC,MSB
440 s0.0 509 ns/L SW846 60108 O9/23-a9/26l0s H.l5.lM1eU
Qualifiere: NC,MSB
DiluEion Fact.or: 5
AnalyBiB Time.. t 23:94
Silver
ND 0.0500 0.0653 mg/t 130 sw846 60108 09/23-09/27/05 ITJ5JM1DN
ND 0.0500 0.0680 mg/L 135 4.0 SW846 60L08 A9/23-09/27105 H,J6,IM].DP
Dilution Pactor: 1
Analyole Tlme.. t L0r22
Sodium
s50o so.o 5490 vtg/L sw846 60108 09123-09/26105 IIJS'JMr.CX
Qualifiers: NC,MSB
5500 50.0 s550 $Lg/t, sw845 60108 09/23-09/26/05 HJ6,fMr-C0Hilijjill;,1';'=' O
Analysis Tirno., : 23254
Vanadium
ND 0.s00 0.451 ng/t 90 sw845 60108 09/23-09/27105 HJSJM1CG
ND 0.s00 0.466 mglL 93 3.4 SW846 60108 A9/23-09/2?/0s HJ5JM1CH
Dilution Factorr 1
ItnalyEis Time.. t LQt22
Zirrc
0-or,s 0.s00 0.443 ns/r, 85 sw845 60108 09/23-09/27/os HJ6JM1CJ
0.01s 0.s00 o.4s7 mg/L 88 3.3 sw846 60r.08 09/23-09/2?/05 HJ6JM1CK
D1lution Factorr 1
Analysis Time.. z 7O:22
Zirconium
0.021 0.s00 0 -534 ng/t 103 Sw846 60108 09/21-09/25105 HJ6.IMLC1
0.021 0.s00 0.546 ns/r. 10s 2.L sw845 50108 09/23-09/26/05 HJ5JM1C2
Dilution Factor: 5
Analysia Time. . r 23 :54
I[.9IE (S) : .__ .
Calcllatiorrs are pcrfomEd bctbrc munding lo avoid rourd-off errors h calculatcd rrsults.
NC Tlte recorcry and/or RPD wcrc not calculaul.
MSB Tlu rccovcry and RP[, wefe 0ol calculard becausc thc sarnple amouil *,as greatcr thim lbur tinns rhc spike amounl
N Splkei, analytc rccovery is oulside staEd control limils.
STL Denver s9
STL DENVER
Tontrrot:
L,rb Cod,e r
gow No.:
Total Metals Analvsis
COYERPAGI: - INORGANIC ANALYSIS DATA PACKAGE
IIRS CorlpraElon sDo No.: D5IO8O2{3
STIJDEN Crac llo, :g.LS No. r
SaTplc fD.
GTI-N2 - 09 07 0 5
GW-S10 -09 07 0 5
GW-91-090705
o{-91-090705 llts
GIII-91-090705 MSD
Grf-511-090705
ow-EI2 - 0g 07 05
clr-93-090705
Gtrrl-S91-090705
erG fCP intcreloqcat, corrGetion; afplied?
Ware fCP background, correctiong epgl-iad?
If yGe-vn rG raw drta grtrrrrratred brforc
npplicrtl,on of backgrouDd corrcctrl,ong?
ConuncatE r
Irab sary)L. TIg:
Dsr080 243-008
Dsr080 2tL3-O03
D5r080 243-00{
Dsro80 243-00{s
Dsr 0 80 243- 0 04gD
D5r0802{3-005
D5roB0243-006
D5r 08 02{ 3-0 07
Dsr0 I 02.3 -O02
o
w YaglNo
YcslNo
Ye s/lilo
I ccrELly that thia drtr Dackegc ls Ln eou[rll..ncc wlth the tcral and conditioot of t]rccgntraet, both tcchatctlly and for coryrlctanelg, for other thrn thc condition! dotal].ed
a.bove. RcLerac of thc daEa oontsalacd, Ln thio hardcory drta Dlckage end ln the conDutar-rcadabXc data
rubnitt.d, on fl,oppy d:lrkcttc haa beca ruthorizcd bSr tbe Lrboratorf,r Murgcr or Uhe MaD&glertt doalgmoc, agvcrLlied by thc folloring gLgrnaEurc.
Daa KctEuLa
Date:Title3 Detr Inalystti lr t''/c.i-
STL Denver CO1IER Pe,gE IN
50
ffisrt
URS Corpomtlon
Total Metals Analysis Drta Sheet
I,ab Neme:
Lot/StlG Number;
Matrlx:
7o llIoisture;
Basis:
Analysis Method:
Unlt:
QC Batch ID:
Sumplc Aliquot:
Dilutlon Factor:
STL DENVER
p5 tQfl0243
WATHB
N/A
Wct
60108
mgi L
5265"6 I
50 nr[,
5
Cllent Somplo ID:
Lab Sample ID:
Lah Workorder:
Date/Tlrne Collectcd:
Date/Tlme Recelvcd:
tlute/Time Letchcrl:
Date/Time Extrocted:
Date/Thne Analyzed:
Instl'ument ID:
W
psr0.$Q?93--.002
HI6II8
09/07i05 07:00
09i08/05 09:30
09i23i05 08:00
09i27105 00:09
02r
CAS No.Annlyte Cone-I}TDL RL a
7429-90-5 Aluminunr 0.084 0.084 0.50 U
7440-70-2 Calciurn I 400 0.r7 I.0
7439-89-6 Iron 0.1I 0.10 0.50 B
7439-95-4 Magnesium 640 0.2 t I.0
744$-A9-7 Potassiunr 450 1.2 l5
744(\-?3-5 Sodiurn s500 5,6 25
144.0-67-7 Zirconirrm 0,024 0.0079 ().075 R
STL Denver
Form I Analvsfs Dala Sheet Eoaivalent
6L
ffiSTI,
UILS Corporatlon
Total Illetals Anrlysis Data
[,ab Nrrne:
l.,oUSDG Number:
Illatrix:
7o lVlolsture:
Basls:
Analysis Method:
tlnlt:
QC Brtch ID:
Sample Allquot:
Dllution Fnctor:
SrL DEI\iyAB
psr0802{f
wnTF t(
N.A
fY-I
60t08
mil,L
52bs26t
5omL
l_
Sheet
Client Stmple ID:
l,ab Samplc ID:
Lab Workorder:
DatelTlme Collectcd:
Date/Time Reeeived:
Date/Tlme Leached:
Dnte/Tirne Extructed:
Date/Tirne Anrlyzed:
Instrument ID:
sw-sgt -09070s
D5r080243-002
I IJ6IITt
09/07/05 07:00
0t /0$/05,--09:30
09/?3{Q5, t}8:00
Oe/27l05 (J9:53
aro
CAS No.Analyte Conc.MDL RL a
7440-18-2 Arsenic 0.0044 0.00e1 0.0r5 tl
7440-39-1 Buriunr 0.13 0,00070 0.01t)
744A47-:1 (Jrrontium 0.0026 0.0026 0.010 U
7M0-50-8 Coppcr 0.004s 0.0045 0.010 U
7419-92-l Letrd 0.0026 0.0026 0.0070 UC
7444-02-0 Nickel $,077 0.00 r2 0.040
7410-224 Silver 0.0028 0.0028 0.0r 0 LJ
J44A-62-2 Vanadiurn 0.002s 0-0025 0.0l0 TJ
f++o-oo-o Zinc 0.0I6 0,0045 0.020 B
STL Denver
Form I lnalysis Datu Sheet Equivalent
62
ffisrr
I.JRS Corporution
Totnl l\{etals Analysls Data Sheet
Lab Nrme:
LoUSDG Number:
Mstrlx:
7o Molsture:
Basls:
Annlysis Method:
Unit:
QC Batch ID:
Sample Aliquot:
Dllutlon Factor:
S]L DENVER
p510n0243
WatTER
NJA
Wet
74704
mg/l.
5",L2I17
l-
Client Sarnple ID:
Leb Srmple ID:
Lsb WorkOrdcr:
Datefl'lme Collccted:
Detc/Tlme Recelvctl:
Date/Tlmc Lenched:
Dotelfime Extrncted:
Date/Tlmc Analyzed:
Instrument ID:
GW-S9I -09070s
nsr080243-002
HJ6H8
Q9t07 t$5 $7:Q0
09i08105 f)9:30
09i23/0s t259
()9i23l05. [E: I 3
0r9
CAS No.Anelyte Conc.MDL RL a
7439-L)7 -6 Mtrcury 0.000044 0,0000r+4 0,()0020 LJ
STL Denver
Form I Analvsls Dato Sheet Equivalent
63
ffisrr
URS Corporatlon
Total Metals Analysis Drta Sheet
Lab Name:
Lot/SD(i Numberl
i\{ atrix:
'/o lltolsture:
Basis:
Anrlysis Method:
Unlt:
QC Batch lD:
Sample Allquot:
Dilution Factor:
STL DENVEB
D51080243
WATER
Ni4
Wct
6020
mg/[,
s26st72
50 mL
ta
CIIent Sample ID:
Lab Snmple ID:
Lab Work0rder:
Date/Time Collected:
Date/Thne Received:
Date/Tlme Leached:
Date/Tlme Extracted:
l)tte/Time Analyzed:
Instrument ID:
Gw-$gr -(!9117.0,5
p5t0,$0243-002
H{6Hfi
09/07/05 07:()0
09/08105 (D:30
09/23i05 l5:30
09/28105 02:03
aa4
CAS No.Anrlyte Conc.MDL RL 0
74/,043-9 Cadnrium 0,0039 0.00040 0.0r 0 B
778249-?Selenium 0.011 0.0033 0.020 B
STL Denver
f'orm I Analysis Dota Sheet Equivalent
64
ffiSTL
UR^S Corporatlon
Total Metals Annlysis Data Sheet
Lab Nsme:
LotlSDG Number:
Il{atrix:
o/e Moisture:
Basis:
Analysis Method:
Unit:
QC Batch Il):
Sample Allquot:
Dllution Factor:
STL DENVER
D5108024"3
-wATEB
N/A
Wc!
60108
wgtL
526526 l
s0 tnl
I
Cllent Sample ID:
Lab Sample ID:
Lsb Workorder:
Date/Tlme Collected:
Dntc/Tinre Received:
DatefTlme Leached:
Date/T'ime Extracted:
tlate/Time Analyzed:
Instrument ID:
q.vr-s.I0-090705
Dsr080243-003
HJ6JL
0e/(17/05 091-18
0ei0tt/05 09:30
0e123i05 08:00
09fta/95-04:47
{tzt
CAS No,Anrlyte Conc.IVIDL RL a
7129-90-5 Alumintrm 0.0I7 0_0r7 0.r0 ts
7+4$-74-7.Calcium 3r 0.034 0.20
7439-8e-6 Iron 0.20 0.()21 0.r0
7439-9s4 Magnesiurn 42 0.043 0.20
74r'.4-09-7 Potassiurn r60 Q.Z4 3.0
7 440-67 -7 Zirconium 0.00s9 0.00 t 6 0.() r 5 B
STL Denver
Form I Analrtrs Data Sheet Eoulvulent
55
ffisrt
LIRS Corporation
Total Metals Analysls Deta Sheet
Lnb Namo:
LoUSDC Numbcr:
Matrix;
7o Molsture:
Brsls:
Anrlysls Metbod:
Unit:
QC Bstch ID;
Sample Allquot:
Dllution Factor:
.STL DFNVER
D5t080243
WATF:B
hliA
Wct
6010R
D]S/L
516526 I
50 mL
rc
Client Sarnple ID:
Lab Samplc ID:
Ltb Workordcr:
Dnte/Tlme Collccted:
Dnte/Tlme Received;
Date/Tlme Leeched:
Date/T lme Extr&cted:
Dnte/Ttme Analyzed:
Instrument ID:
Gw-sl0-0t07os
p5 r{)tt0243-Q0,3.
HJ6JI.,
09i07/05 09:3tl
09/08iQ5 09:30
09i23i05 08:00
0e127,l05 00: l4
oet
CAS No.Analyte Conc,MDL RI,a
744()-23-5 Srldium r900 ll _s0
STL Denver
Form 1 Anulvsis Data Sheet Eouivulent
66
ffisrt
UIIS Corporation
Total Metals Analvsis Datt Sheet
Lsb Name:
LoUSDG Number:
Nlatrlx:
7o Molsture:
Brsls:
Annlysls Method:
Unlt:
QC Bntch ID;
Srmple Aliquot:
Dilution Factor:
STI. DENVER
D5 [080243
WATEB
N/A
Wet
60I ()B
rngrL
5265?6 I
50 rnL
I
Cllent Srrnple lD:
Lsb Sample lD:
Lab Work()rder:
Drte/Tirne Collected:
Datc/Time Recelved:
Date/Tlme Leached:
Drte/Tlme Extrncted:
Date/Tlme Anslyzed:
Instrunrent I D:
cw-st O-Q?tr0s
pstQL0243-003
HJ6J I ,
0910705 09:38
09/08/Q5_09:30
09/23i05 08:00
09/27105 ()9:5tl
0L6
CAS No.Analyte Conc.NIDL RL a
7M0-18-2 Arsenic 0.0075 0.0044 0.0r s B
7440-39-3 IJurium 0.37 0.00070 0.010
7440-47-3 Chromium 0.0026 0-0026 0.0r 0 U
7440-s0-8 Copper 0.0045 0.0045 0.0r0 U
7439-92-l Lead 0.0026 0.00?6 0.0030 U
7AA-(t}-Lt Nickcl 0,0016 0.0012 0.040 B
7440-22-4 Silver 0.0028 0.0028 0.010 tJ
7444-62-2 VanarJium 0,002s 0.0025 0.0r0 I.J
7MA-66-6 Zinc 0.009t 0-00.15 0.020 B
STL Denver
Form 1 Anal.y.sis Data Sheet Eouivalent
ffiSTL
IIR^S Corporntlon
Tottl Metals Anelysis Datr Sheet
l-,tb Nnme:
LotlSDG Number:
l\l atrix;
o/o Moisture:
Btrsis:
Anrlysls ll{ethod:
Unit:
QC Batch lD:
Sample Aliqrrot:
Dllutlon Factor:
STL DE\VER
D5,1080"43
WATER
N1A
UsI
7474A
mg/L
525C)417-
l_
Client Sample ID:
Lrb Sample ID:
Lab Workorder:
Date/time Collected:
DntelTtme Recelved:
Dnte/Tlme Leachcd:
Date/Tlme Extrnctecl:
DatelTlme .A,n a |yr.ed'.
Instrument lD:
cw-sl0-0q0705
p5I080243.-Q01
HJ6JL
09/07i05--pq:38
09iQ&r05 09:30
09123105 I ?;5,0
09/23/ftl..U; I s
I)19
CAS No.Antlyte Conc-MDL RI,a
7419-s7 -6 Mercury 0.000044 0.000044 0.00020 U
STL Denver
Form I Anulysis Duta Shcet Equivalent
5B
ffisrt
URS Corporation
Tottl Metals Analysls Data Sheet
Lab Nnme:
LoUSDC Number:
Matrlx:
o/" Nloisture:
Bnsis:
Analysls Method:
Unlt:
QC Bstch ID:
Stmple Allquot:
Dllutlon $'actor:
STL DENVER
p5rp80.43
WATER
N/A
wct
6020
:ntlL
526st72
50 mL
5
Cllent Sample ID:
Lab Srmple lD:
Lab \Uorkorder:
Date/Tlme Collocted:
Dnte/Time Received:
l)ate/Tlme Leached:
Drte/Tlme Extrncted:
Dnte/Ttmc Analyzed:
lnstrument ID:
SIU:Itj-090J05
p5I080243-003
HJ6JL
09/07105 09:38
09i08i05 09:30
09/23105 I5:3()
09i28i05 A2:07
OIJ4
0.010
CAS lt{o-Analyte Conc.TIlDL RL a
744A-$-9 Cadrnium 0.00020 0.0002t)0.00s()U
7782-49-2 Selenium 0.0016 0.0016 U
STL Denver
Form I Anolvsis Datu Sheet Equivulent
69
ffiSTL
URS Corporatlon
Total Metals Analysls Dete Sheet
[,tb Nnme:
LoUSDG Number:
Matrlx:
% Moisture:
Basls:
Antlysis Method:
Unit:
QC Batch [D:
Sample Aliquot:
Dilutlon Frctor:
sTt-pFNVER
p5ro8q?*3
WATER
NiA.
Wct
60lqE
rngiL
s26526t
50 rql
T
Cllent $rmple lD:
Lab Semple Il):
Lab WorkOrder:
Date/Tlme Collected:
Dstefi'inre Recelved;
Dnte/'fime L,etched:
tlate/Tlmc Extracted:
Date/Tlme Antlyzed:
lnstrument ID:
Gly_ s I -000705
D5108()243-00j4.
HJ6JM
09i07i05 09:55
0e./$$rQ-5 0e:30
09/23105 0tJ;00
09l76tLt5 23:30
ozl
CAS No.Anal.vte Conc.}TDL RI,a
1429-9A-5 Alunrinurn 0.084 0.084 0.s0 U
7440-74-2 Calciurn I 400 0.1 7 | .()
7439-89-6 Iron 0.13 0. r0 0.s0 B
7439-954 Magnc-^sium 630 0.21 t.0
7440-09-7 Pottrssium 444 t.2 l5
7440-23-5 Sodium 5500 5.6 25
7440-(17-7 Zirsoniurn 0.021 0.0079 0.075 B
STL Denver
Form 1 Analys'is Data Sheet Eouivalent
ffisrl
LIRS Corporatlon
Total Metals Anrlysls Data Sheet
Lab Name:
LoUSDG Nunrber:
Matrix:
o/o tltoisture:
Brsis:
Analysis Method:
Unit:
QC Batch ID:
Sarnple Aliquot:
Dilutlon Frctor:
STL DENYJB
D5_t080?43
WATFR
NiA
Wst
60r08
mr&
526s261
50 rn.L,
.L
Client Strrrple ID:
Lab Sample ID:
Lab rvYorkorder:
Dste/Tlnre Collected:
Dstell'ime Recelved:
Date/Tlme Leached:
Date/Time Extrtsted:
Date/Tlme Annlyzed:
Instrument ID:
Gw-s,t-0p070I
p51080243-004
HJ6JM
09/07105 09:55
09r'08/()5 09:30
09i23/05 Lttl:00
Ooi " 7/05 l0: 1 2
ot6
CAS No.Anrlyte Conc-MDL RI,a
7440-38-2 Arscnic 0.0078 0,0044 0.()15 B
744()-39-3 Barium 0.13 0.00070 0.010
7440-47 -1 Clhrcrrnium 0.0026 0.0026 0.0r0 tJ
7440-s0-8 Coppe.r 0.0045 0.0045 0.0r 0 LJ
7439-92-l Ltvad 0.0026 0.0026 0.0030 U
744A-A2-A Nickel 0.0E0 0.0012 0.040
7440-22-4 Silver 0_0028 0.0028 0 0050 U
7440-62-2 Vanadir.rm 0.0025 0.002s 0.0 t0 LI
7440-66-6 Zinc 0.0I5 0.0045 0.020 B
STL Denver
Form 1 Analysk Data Sheet Equivalent
77
ffiSTt
URS Corporation
Total l\f,etals Analysis Data Sheet
Lrb Ntme:
Lot/SDG Number:
Mttrix:
"h Molsture:
llrsls:
A,nalysls Method:
Unit:
QC Batch IDr
Sample Allquot:
Dllutioo Frctor:
STL Db.NVER
D5108()243.
WAT'ER
NiA
ws1
747qA
rng/I,
5259437
Cllent Sample ID:
Lnb Srmple ID:
Lab Work0rder:
tlate/Tlme Coltected:
Drte/Tlme Received:
Date/Tlnre Letched;
Date/Tlmc Extrtcted:
Date/-I'ime Analyzed:
Instrument lD:
GW-Sr -090705
Dsr080243-004
HJ6JM
09/07/05- ()9:55
()9108/05,. -09:30
(D/23i05 I2:50
09/23i05 I tl: l6
0r9
CAS No.Anal,vte Conc,MI}L RL a
7439-97-6 Mercurv 0.000044 0.000044 0.00020 U
STL Denver
Form I Anal.ysrs Data Sheet Esuivalent
72
ffisrt
URS Corporution
Total llletals Analysis Data Sheet
[,ab Name:
LoilSDG Number:
Matrlx:
oh Molsture:
Basls:
Analysls Method:
tlnlt:
QC Bntch lD;
Snmple Aliquott
Dllution Fnctor:
STI DENVEB
D5I080243
WA'I'ER
}va
lYs
6020
tngl.
LWst72
50 mL
10
Cllent Sample ID:
Lab Sample tD:
Lab Work0rder:
Date/Ttme Collected:
Dnte/Time Recelved:
Date/Iime Leached:
Dnte/Tlme Extrectctl:
Date/Time Analyzed:
Instrunrent ID:
GW-SI -09070s
ps1080243-004
HJ6JM
09/07/05 09:55
0e/0lji05 09:30
92,?3i05 15:30
()9i28i05 02: I I
Il(){
CAS No.,fumlyte Conc.MDL RL a
744043-9 Caclrrrium 0.0039 0,0fi)40 0.010 B
7182-49-2 Selcnium 0.01I 0.0033 0.020 B
STL Denver
Form J Anabsis Data Sheet Equivalent
73
ffiSTt
UR^S Corporatlon
Total Metals Anrlysis Data
Lsb Narne:
LoUSDG Number:
Iflatrlx:
7o Moisture:
Basls:
Analysls Method:
Unlt:
QC Brtch ID:
Sample Allquot:
Dilution Fnctor:
$IL DENVEB
p51080243
W^TER
N/n
Wet
OQ LOB
rng/L
s26s26l
5o ryL
IO
Sheet
Cllent Snmple ID:
Lsb Somple lD;
Lab Workorder;
Dste/'l'irne Collected :
Date/Tlme Received:
Date/Time Leoched:
Drte/Tfume Extracted:
Dtte/Tlme Annlyzed:
Instrument ID:
GW-SI I -090705
Dsr080243-005
HJ6JW
Q907i05 I I: 15
09i08i05 0e:30
09/23/05- 08;00
09i37it)5 00:1 8
oZL
CAS No.Analytc Conc.MT'L RI,0
7429-9$-s Aluminurn 0.17 0.17 I.0 U
7440-70-2 Calciunt 170 434 2.4
7439-tr9-6 Iron 3.2 0.21 1.0
7439-9s4 Magnesiunr 590 0,43 2.0
7440-09-7 Potassium 560 2.4 30
?444-23-5 Sodium r4000 II 5()
1440-6i -7 Zirconium 0.064 0.01 6 0.ts B
STL Denver
Form I Analysls Data Sheet Eguivalent
74
ffisrt
tlRS Corporution
Total Metals Annlysls Data Sheet
Lab Ntme:
Lot/SDG Number:
Nl atrlx:
7o l\{oisture:
Busls:
Analysls Method:
Unlt:
QC Bntch ID:
Stmple Aliquot:
Dllutlon Factor:
$IL DENVET{
p51080243
WATER
N/n
Wet
60108
m8/L
s265261
50 mL
l_
Cllent Stmple ID:
Lab Srmple lD:
Lab Workorder:
Date/Tlme Collected:
Date/Time Recelved:
Date/Tlme Lesched:
Date/Time Extractetl:
Date/l'irne Analyzed:
Instrument [D;
GW-Sr r -090705
rr5I080243-005
HJ6JW
09i07/05 I l :15
09i08/05 QL30
09i23i05 08:00
t)9i?7i05 I0:32
ar-6
(lAS No.Annlyte Conc,MDL RL 0
7440-38-2 .A,rsgric 0-0049 0.0044 0.0t s B
7444-39-1 Bariurn 0.16 0.00070 0.() t0
744447-3 Chromium 0.0026 0,0026 0 0r0 LJ
7440-50-8 Copper 0.fJ045 0.0045 0.0r 0 t)
7419-92-l Lcad 0-0026 0.0026 0.0070 UG
744A-02-0 Nickcl 0.0026 0.00 r 2 0.040 B
7440-22-4 Silver 0.0028 0.0028 0.0r 0 IJ
7M0-6?-2 Vnnadiurn 0,002s 0.002s 0-0 l0 U
1440-6(t-6 Zinc 0.0045 0.0045 0.020 U
STL Denver
Form 1 Analysls Dato Sheet Egulvalent
75
ffisrr
URS Corporetion
'l'otal Metals Analysis Date Sheet
[,ab Name: STL DENVER ClientSanple lD: GW-Sll-090705
Lot/SDG Number: DI1080243 Lob Srmple lD: D5I080243-005
Matrlr: WATER LabWorkordcr: l'U6iW
7o l\{olsture: NiA Date/Time Collccted: 09/07/05 I I : 15
Bagls: Wct Drte/Tlme Rccelv'ed: 09/08i05 09:30
Analysis Mcthorl: 74704 Dato/Tlme Leached:
Unit: itgl- Date/fimc Ertrocted: A9/23|OS 12:50
QC Betch lD: 5259431 Dotr/Time Analyzed: 09/21/05 t8:21
Srmple Allquot: lnstrument tD: 019
Dilutlon Frctor: I
CAS No,Analyte Cone.I\TDL RL a
7439-97-6 Mercury 0.000044 0.000044 0.00()20 U
STL Denver
Form I Analvsis Dan Sheet Equivalent
76
ffi$Tt
URS Corporadon
Total Metals Analysls Data Sheet
Lrb Name:
LoUSDG Number:
Matrix:
7o Molsture:
Brsis:
Anrlysls Method:
Unit:
QC Bntch ID:
Sample Allquot:
Dllutlon Factor:
STL DENVER
Dst0g0?43
WATIB
NiA
UsI
601r)
mg/L
s26st7z
50 rnl
N
Cllent Snmple lD:
Lrb Snmple ID:
Lab Work0rder:
Date/Time Collected:
Date/Tinre Recelverl:
Date/Time l.,eached:
Dste/Time Extracted:
Dsteftime Analyzed:
lnstrument IDI
$.y.v'"-S I l -090705
n5t080243-005
HJ6JW
09i07i05 I I :15
0e/08r05 p930
09!23t05 t5:3tr
09/28/05 02:36
0g
CAS No.Annlyte Conc.MDL RI,a
744043-9 Cadrnium 0.00080 0.00080 0.020 U
7782-49-2 Selcmiurn 0.0r8 f).00(r(r 0.040 B
STL Denver
Form I Analvsis Data Sheet Eouivalent
77
ffisTL
URS Corporatlon
Total Metels Analysls Data Sheet
Lab Nume:
Lot/SDG Number:
Matrix:
7o Molsture:
Busls:
Anolysis Mothod:
Unit:
QC Batch ID:
Sample Allquot:
Dllution liactor:
S-!-L ne}*vpn
p5r090243
WATER
MA
Us
0ol 0B
mg/L
526s261.
50 rnL
ll}
Cllent Stmple lD:
Lrb Srmple ID:
Lab Work0rder:
Date/Tlme Collected:
Date/Tlme Received:
Date/Tlme Leached:
Date/Tlme Extrtcted:
Dst€/Time Analyzed:
Instrument lD:
(LW-Sz-0e0705
D51080243-006
ru6JX
09/07lrJS l.?il[
0e/08/05 09:30
09/23l0J.. .08:00
0U17i05 0():?3
0zI
CAS No.Analyte Conc.futlL RL a
7429-s0-5 Aluminurn 0.1 7 at7 1.0 L'
7440-10-2 Calcium 220 0.34 2,0
7439-89-6 lron 0.21 0.21 1.0 U
7411)-954 N{agnesium 724 0.43 2.0
7440-09-7 Potassium r I00 2.4 3t)
744A-23-5 Sodium 26000 il 50
7M0-67-7 Zirconiunr 0.0 t6 0.0r6 0.ls U
STL Denver
Form 1 Analysis Dota Sheet Equlvalent
7B
ffisrr
URS Corporution
fotal Metals Analysis Data Sheet
Leb lt{ame:
Lot/SD(i Number:
Mntrix:
o/o Moisture:
Bnsls:
Analysls Method:
Unlt:
QC Batch [D:
Sample Allquot:
Dllution Factor:
STL D.ENVER
Dst080241
WATER
NiA
Wct
60IOR
rrJs&
s265261
50 mL
5.x-
CIIent Sample ID:
Lsb Sample ID:
Lab Workorder;
Dnte/Time Collected:
DrteI[ime Recelved:
l)ate/Tlme Lenchcd:
Dste/'l'ime Extracted:
DateiTlme Anslyzed:
Instrument ID:
GW-S2-09070s
D51080243-006
HJ6.rX
09/A7105 t2:20
09r08/t)s 0P;3-Q
09/23105 Otl:fi)
A9/27105 t7:58
016
CAS No,Anal-vte Conc.MDL RI-a
7440-38-2 Arsenic 0.0?2 0.022 0.07s t
7440-39-3 Bariurn 0.074 0.0035 ().050
744$-47 -3 Chrotnium 0.0r 3 0.013 0.050 U
7440-s0-8 Coppcr a.027 a.a22 0.050 ti
7419-92-l Lead 0.0t3 0.013 0.0 rs I.J
7444-42-0 Nickel 0,0060 0.0058 0.20 ts
7444-22-4 Silver 0.014 0.0 r4 0.0-s0 U
74l,0-62-2 Vanadiurn 0.012 0 012 0.050 U
7440 66-6 Zinc 0,0?5 0.023 ().t0 B
STL Denver
Form I Analvsis Dala Sheet Eouit,ulent
79
ffisrr
LIRS Corporatlon
I'otal NIetaIs Analysis Dett Shcet
Lab Name:
Lot/SDC Number:
Matrix:
7o Moisture:
Basis:
Analysls Method:
Unlt:
QC Batch II):
Sarnple Aliquot:
Dilution Factor:
STL DENVhB
psJO80243
WATER.
N/A
Wet
TqaA
mgiL
5259417
I
Client Stmple ID:
Lnb Sanrple lD:
I,ab t*orkOrder:
Date/Tlme Collected:
Datc/Tlme Received:
Date/Tlme Lenched:
Dste/Time Extrrcted:
Date/Tlme Analyzed:
lnstrument ID:
GW-S2-090705
D5I080n43-006
HJ6JX
{t9/tt7l05 12:20
09i08i05 09:30
09f211$5 12:50
09t23105 l8:2?
gr9
CAS No.Analyte Conc.MDL RL a
7439-1)7-6 lVIercury 0.000044 0.000044 0,00020 Li
STL Denver
Form I Analysis Data Sheet Equivalent
BO
ffisrr
tlRS Corporution
Total i\Ietals Analysis Data Sheet
Lnb Namc:
LoUSDG Nurnlrer:
Mstrix:
o Moi$ture:
Busls:
Anrlysis Il{ ethod;
Unit:
QC Batch lD:
Sarnple Aliquot:
Dilution Fnctor:
sl'L Dm{vElt
psl080243
WATER
N/A
Wet
F-020
rng/L
s?6s112
50 rnl.
50
Client Sample ID:
Lsb Sample ID:
Lsb Work0rder:
Date/Timc Collected:
Dete/Tlme Received:
Date/Tirne Leached:
Dnte/Time Extrrcted:
Date/Tlme Anrlyzed:
Instrument ID:
GW-S2-{)90705
D5I080243-006
HJ6JX
09t07/MJ2:24
09i08/05 ()9:30
09i23/05 l5;30
0912$/05 02:40
004
CAS No.Analyte Conc.MDL RL 0
7444-43-e Cirdnriurn 0.0020 0.0020 0.050 U
778749-Z Sclctium 0.026 0.016 0.10 B
STL Denver
Form I Analysis Data Sheet Eguivalent
81
ffiSTL
URS Corporstion
Total 1lletals Analysis Data
l..ab Name:
LoUSDG Number:
Mntrix:
7o Molsturc:
Brsls:
Analysls l\tethod:
Unlt:
QC Batch ID:
Sample Aliquot:
Dllution Factor:
sTL qENVER
r)51080243
WATER
N/A
Wet
60I ()B
rnPI
5?65',r61
50 rl!.
I
Sheet
Client Sample ID:
I-ab Semple ID:
Lsb Workorder:
Date/Time Collected:
Date/Tlme Rccelved:
Date/Tlme Lenchedl
Dste/Tlme Extracted:
Dnte/Tirne Analyzed:
lnstrument ID:
cw-s3-09070s
D51080243-007
HJ6JO
09/07/05 rJlN
09/08105 09:30
09/-rl05 08:00
09/2{i05--91 :0t
W.
CAS No.Analyte Conc.MDL RL a
7421)-()A-5 Alurninurn 0.0 r7 0.0r 7 0. t0 U
7 440-74-2 (lalcium 39 0.034 0.20
743e-8e-6 Irrrn 0.54 0.02 t 0.I0
743e-e5-4 Magncsiunr 66 0.043 0.20
7444-Q9-7 Pota.ssiurn 220 0.24 _3.0
7440-21-s Sodiurn 2600 t.l 5.0
7MA-67-7 Zirconiurn 0.00r 6 0.0016 0_0 r5 TJ
STL Denver
Form I Anulvsis l)ata Shep.t Eouivnlpnt
B2
ffiSTL
URS Corporatlon
Total Metals Analysls Data Sheet
Lab Nsme:
Lot/SDG Number:
Mttrix:
oh Moisture:
Basis:
Analysis Method:
Unit:
QC Bntch lD:
Srmple Aliquot:
Dilution Factor:
s'I'L PENVER
Ds1080243.
w4l'ER
M
IYat
6.0 r08
rrrg/L
5265161
50 mL
1
Cliont Sample ID:
Lnb Snmple ID:
Lab WorkOrder:
Date/Tlme Collected:
Date/Tlme Received:
DrtdTlme Leached:
Dnte/Time Extracted:
Date/Tlme Anstyzed:
Instrument ID;
GW-S3-090705
ps1080243-007
HJ6JO
09107/05 t 3:0Q
0?/Q$/05 09'10
09/^1/05 08:00
$9/27 /Q5 tQ.:!Z
gt6
CAS No.Annlyte Conc.MDL RI,a
7440-38-2 Arsenic 0.016 0.0044 ().()l 5
7440-39-3 Barium 0.2I 0.00070 t).0 I 0
7440-47-3 (lhrotnium 0.0026 0.0026 0.0 t0 U
7440-s0-S Coppcr 0.0045 0^004s 0.0r 0 I]
7439-92-l Leud 0.0026 0.fi)2fi 0.0030 TJ
7440-02-A Niskcl 0,0034 0.00 r 2 0.040 B
7M0-72-4 Silvcr 0.0028 0.0028 0,0r0 U
7414-62-2 Vanadium 0,0036 0.0025 0.0t0 B
7440-66-6 Zinc 0.004s 0.0045 0.020 TJ
STL Denver
Form I Analysis Data Sheet Eguivalent
ffisrr.
URIi Corporution
Total Metats Analysis Data Sheet
l,rb Name:
Lot/SDG Number:
Matrix:
7o Moisture:
Basls;
Analysls Methrd:
Unlt:
QC Batch ID:
Sample Aliquot:
Dilutlon Frctor:
STL DENVER
p5r!80243
}YA'rER
N/A
UE
147{tA
nrglL
s259{f^7
I
Clicnt Stmple ID:
Lab Snmple ID:
Lab WorkOrder:
Date/Tlme Collected:
Date/Tlme Received:
Date/Tlme Leached:
Date/Tlme Extrocted:
Date/Tlme Anall,zed:
Instrument ID:
cw-s3-090705
D5 t080243-007
HJ6Jo
09/07/05 13:00
09/08/05 09:30
0e/23105 12:5Q
0()/73105 18:24
0r9
CAS No.Analyte Cottc.TvIDL RL a
7439-91-6 Mcrcury 0.000044 0.000044 0.00020 U
STL Denver
Form I Analysls Data Sheet Equh,alent
84
ffisrr
URS Corporntlon
Total Mctals Analysis Dets Sheet
Lrb lYame:
I-,oUSDG Number:
Matrlx:
7o t\lolsturc:
Basis;
Anrlysls Method:
Unit:
QC Batch lD:
Sample Aliquot:
Dilution Fnctor:
STL DENYER
D5108()243
wATlrR
NIA
]Ye!
00zo
ntgil-
5"t65172
50 rnl .
5
Cllent Sample ID:
Lab Sample lD:
Lab \Vorkorder:
Date/Tlme Collocted:
Date/Tlme Received:
DatelTlme Leached:
Date/Tlme Extructed:
Date/Tlmo Antlyr,ed:
Instrument ID:
GW-S3-09070s
p5 r0s0243-007
H.r6J0
09/07/05 l3:00
09/0$/05 09:]0.
09/23/05..IJ:30
0e/2t]/05 Q?:4*.
00{
CAS No.Antlyte Conc,MDL RL a
7+44-43,-9 Cadmiurn 0.00020 0.00020 0.0050 U
7782-49-2 Sclenirrm 0.002I 0.00 r 6 0.010 B
STL Denver
Form I Analysis Data Sheet Equivalent
B5
ffisrt
URS Corporation
Total I\IetaIs Analysls Data Sheet
[,ab Nome:
I,oUSD(i Number:
M atrlx:
7o Moisture:
Basls:
Analysis Method:
Unlt:
QC Batch ID:
Sample Aliquot:
Dllutlon Frctor:
STL DENYER
p51080243
WATEE
N/A
Wct
6010B
}IIfliL
526s261
so tul
]j
Cllent Sample ID:
Lab Sample ID:
Lab Workorder:
Dtte/Time Collected:
Date/Tlme Recelved:
Date/Tlme Leached:
Dnte/Tlme Extracted:
Date/T'ime Analyzed:
Instrurnent lD:
GW-N2-090705
p5r080243-008
HJ6J I
09/07/0,5 13:30
09/08/05 09:30
09/23/05 08:00
{t9/27 lAS A0:28
oZL
(;AS No.Anrlyte Conc,IUDL RL a
7429-94-s Altrminum 0.1 7 0.1 7 t.0 U
74l,0-74-2 Calcium 6l 0.34 2.4
7439-89-6 Iron 025 0.21 r.0 B
7439-95-4 Magnesiurn 2E0 0.43 2.0
744$-09-7 Potassium 330 2.4 30
7440-23-5 Sodiurn 7s00 II s0
7 440-67 -7 Zirconium 0.039 0.0r 6 0.15 B
STL Denver
Form 1 Analysls Datu Sheel Equivalent
B6
ffi$Tt
UR^S Corporaflon
Total Metels Analvsls Data Sheet
Lab Name:
Lot/SDG Number:
Matrlx:
7o Moisture:
Basis:
Analysis Method:
Unit:
QC Brtch lD:
Sample Aliquot:
Dilutlon Frctor:
STL DENVFR
psr080?*l
w,ilFn
NiA
Wet
fiOl0B
mslL
5.'6526t.
50 rnl,
-L
Client Sample ID:
Lnh Stmple ID:
[,ab Work0rder:
DatdTlme Collected:
Dnte/Time Recelvcd:
Date/Thne Leached:
Date/Tlme Ertracted:
Date/Time Anrlyzed:
Instrument ID:
GW-N2-()9()7q5
D5ro8o243-008.
tt.l6J.l
09/t)7/05 I 3;38
09108/05 09:30
0ei2U0L 08:00
0qi27lA5 1047
AI0
CAS IT{o.Analyte Conc.MDL RL a
7440-38-2 Arsenic 0.0063 0.0044 0.01s B
7440-39-3 Barium 0.09s 0.00070 0.010
7 440-47 -3 Chromium 0 0026 0.0026 0.0t 0 U
7440-50-8 Coppcr 0.0045 0.0045 0.0r 0 L'
t41e-e2-l Lcad 0.0026 0.0026 0.0030 LI
7440-02-0 Nickcl 0.0014 0.0012 0.040 B
7+1,4-22-1 Silver 0.0028 0.0028 0.0r0 U
7440-62-2 Vanadium 0^0025 0.002s 0.010 U
7440-66-6 Linc 0.004s 0.0045 0.020 TJ
STL Denver
Form 1 Analysis Data Sheet Equlvalent
B7
ffisrt
IIRS Corporatlon
Total l\Ietals Analysis Drta Sheet
Lab Nnme:
Lot/SDG Number:
Matrlx:
7o llloisture:
Bnsis:
Annlysis Method:
Unlt:
QC Bntch tD:
Srmple Aliquot:
tlllutlon Factor:
STL DENYER
D51080243
WATER
N/A
wsI
7!7AA
mill,
s259437
l-
CIIent Snmple ID:
Lab Sample ID:
Ltb WorkOrderr
Date/Tlme Collec-ted:
Date/Tlme Recclved:
Dste/Tirne Leached:
Dnte/f ime Extracted:
Dnte/l'ime Antlyzed:
Instrument ID:
GW-Nn-09070s
p5 r0,$0243...008
HJ6JI
09/07i05 I 3:3Q
09i08/05 ()9:30
09i23105 I2:50
09i23105 1 8:26
0le
CAS No.Analyte Conc.MDL RL a
7 4]g-L)7 -6 Mercury 0.000044 0.000044 0.00020 TJ
STL Denver
Form I Analysir l)ata Sheet Equivalenl
ffi$rt
URS Corporrtion
Total Metals Analysls Drtt Sheet
Lsb Nome:
LoUSDG Number;
Mrtrlx:
04 Moisture:
Basls:
Andysis Method:
Unlt:
QC Brtch ID:
Sample Atlquot:
Dilution Fnctor:
STL TJfrNVER
psr0802{1
WATER
NrA
Wct
6020
me/L
s76s.17)
50 ntl
l0
Cllent Sample lD:
Ltb Sample ID:
Lab Work0rder;
Datc/Time Collected:
Date/Tlme Received:
Date/Time Leuchetl:
Date/Time Extracted:
tlate/Tlme Analyz.ed:
lnstrument ID:
gw-N2-0q0705
plllfJ80243-008
HJ6J,L
09i07/05 l3:30
09/0810s 09;30
09/23lQ,5 I5:30
1\9128/05 $2:a7
004
CAS No.Analyte Conc.MDL RL a
t44A-43-9 Cadrnium 0.00040 0.00040 0.0r 0 t,l
7782-49-2 Selenium 0.0079 0.0033 0.020 B
STL Denver
Form 1 Analysis Data Sheet Equivalent
89
STL DENVER
Cont,raot: IIRS Corry>oratLon
Total Metals Analysis
-2A-
INTTIAL AT{I} CON TINUING CALIBRATION VERTFTCATION
Caee No. t g.l,S No. t
Higrh Purity, Spe*
InorganLc VenturGa
IJaI) Codc: STLDEN
Inl.tLa1 Cd.tbratsion Sourccr
ContsLnulng Callbratl-on Eourec :
gDg uIO. : D5I080213
Conccntration Unttr : rrgllt
Anallrtc
Ini-ttal Call,bration
Trnrc Found e6R ( 1)
ContrI-nuing Crllbratlon
Trrre Found %R ( 1) Found, t6R (1)M
Alumlnum .l 0.5a21 100-{ I P
Inrurnrnun:J lo.ol ga.sgl gz.al po.ol lg.rol ge.zl I Jpl
Crlcl,um t I 5.051 101.0 I P
I catolum HI 40.01 39.{Gl 98.61 so.oJ t9.8il 99,G1 lpl
lrrour,o I I 1,,,. I o.sol I l. o.srrlroz.slel
Iron Hi I 39.51 I gg.8 5g .371 98 .7 P
Potassirun I
Macmagiurn I
SodLum fro I
Bod,irrm Hi I 39. 27 I 98.2 50 . o51 100 . 1
lzrrcoaiqpl l- I I o.sol. I I o.rgcl gg.el,il
(1) ConEroI L{mtta:Marcury 80-1201 Other Mrt,rls 90-1101 Cy'aulde 85-115
STL Denver Fout rI (Part,1) rN
STL DEIVVER
Total Metals Analvsis
-24-
INITIAL AND CONI'IN UING CALIBRATION VERIFICATION
eoDtrrcts tRS Corporrtion
I.aI) Codr r STLDEN Carr No. t gAg ![o. r
rnLt J-aI Call-bratlon gcrurco r
Continuing Calibration Sourccr
Htgh Purl-ty, gDon
Inorganl,c Vcnturcr
gDc NO,: D5I0802{3
ConconEratLon Units r mglL
.f,nrlyEe
InitLa1 Callbratsion
Trnre Found t6R ( 1)
Contsinuiagr CalibrrtLon
Trrrc Found e6R ( 1) Found tR ( 1)M
lr,rrunraun:L I l_ | o.sol ,,.. I I o.sozlroo.rlel
Aluminum :l lg ,071 98. t P
Celcium t I 5.031 100,5 t P
lcarcrumsl ,. l _ | I so.ol lg.zal gg.sl 1,...,... 1e1
I lron rro I I I I o.sol I I o.sulroz.slBl
Iron Hi I
PotageLurn I
In grr"esiumI I I eo.o I
{g,361 gg,7
50 . 241 100 .5
I I 1e.B8l ss.a[rl
Sod,Lum Lro I 5.02)LOO.l
lgoaiumErl L.. | [ so.ol a?.sil sg.ll I lel
I zirce4lul|I o.so I I I o.csel ee.GIrI
(1) Control fimlUer l,tereur:tr 80-1201 Other Mctals 90-1101 Clranl-de 85-115
STL Denver Form Ir (Part 1) IN
STL DE!,{VER
Contrecu: URS Coqporatton
Total Metals Analvsis_2*
INITTAL AND CONTIN UING CALIBITATION VERIFICATION
Cage [Io. r S^Lg No. t
Higrb hrrl,ty, Sgcx
Iaorganie VanEurol
r,ab Codc r STITDEII
InitLr]. Calibration Bouree:
ContrinuLng CalibratLon Source:
SDs NO, : D5I080243
ConccntratLon unltt t WIL
^Lnaltte
InLtiel Calibration
Tnrc Found e6R ( 1)
Contrinuing CrlibratrJ.on
Tnrc Found t6R ( 1) Found tR ( 1)D!
letuntnum:l I I I o.sol I I o.lzrl ss.olpl
.l,].uml.nutn :l 50.5d1 101.1
lcareiun r,l [.. ,- | I ,.. s.o I I I r.sol ge.o [p Ilcarcimnl | | I .so.ol lg.rel gg.ll 1.. lplIron Lo 0. {9{ I 98.8 I P
Potas;Lum I 50. {11 100.8 I P
lrroaxt I I I I so.ol le.gzl gz.al I lpl
Ir[,r.grnaoLr:nr I 19,591 gg.{ I P
Sodium lro I 5.101 102.0 I P
Sodl,um Hi I 50.751 101.5
lzrrconrulal I I | ..,.o.tol -l I o.aeel szrzlgJ
{1) Control LhitBt Mrrcury 80-120; Othcr Mrtel! 90-110,- C)ranidr 85-115
STL Denver Ponn II (Prrt 1) - fN
92
STL DETWER
Total Metals Analvsis
-2A-
IN ITIAL AND CONTINUING CALIBRATION VERTFICATION
contractr IIRS CorporatLoa
Lab Codc t STITDEDI Crac No.:8lS No. :
InLtia]' CalibratJ,on Souroc:
ContinuLng CrlLbration Slourcc r
ttigh Purlty, Spax
InorganLc VenturoB
gDo No. r D5f 08O2{3
Concentration Unita r mrg/L
}nrIIrUe
rul,tial Cel-J}ration
True Found e6R ( 1)
Continuing Ca1 ibrat ion
Trnrc Fouad tR ( 1) round 96R ( 1)M
.n,lumlnrrrn :l
lnr.r+ingm,l I I I so.ol s1.231 1o2.sl I Irl
Ca].eium t I il.'l 61 95 .2 I P
lcnrci.rltgl I ,, | ,. I s.o.ol rg.zzl ge.rl I lelIron Lo I 0.4951 99,0 I p
Iron IIi I
Potarsium J
I Mrgrrertunl 20. o I I rg.7tl e8,?lpl
Sodlum Lo I
Sodl.um Hf I
I ztrqs,nt.o* | I o.so I I o.l,ezl g't,Llpl
(1) ConE,roL riniee:ltlcrcrrra' 80-120r oEher Matalr 90-1101 cyenidc 85-115
STL Denver Fom II (Part,1) IN
STLDETWER
Coutraet, r URB Corporatioa
Total Metals Analysis
-2A*
INII'[AL AND CONTIN UII\G CALIBRATION VERTFICATION
Cage No. r SAS No.:
Hlgh Ptrrity, Spcx
Inorganlc Venturc;
SDGI NO. I D5I0802{3L,ab Codc r STITDEN
tnitinl Calibratl-on Giourca:
ContLnu:Lng Cal-lbration Sourcc r
Concrntration UnLta t ng llt
.fnrlyte
rnLtial CrlLbration
lPrrre Found tR ( 1)
Contj.nuLng Calibntlon
Tnrl Forrnd e6R ( 1) tround tR ( 1)u
Jtlurninusr :l 0 ,50 0.4551 93,0 I P
lmuruinuu;l I I I so.ol -sr.gol roa.zl I lel
Celelum L l 5.0 {.721 94.11 I p
lcarorunxl. I I I so.ol ae.erl,gz.sl l. lel
Iron to I 0.{g5l 99.01 P
frronni I I I I so.ol ce.szl rz.rl I lpl
Potaaotrrrn I 50 ,0 50.631 101.3 I p
Drrgnastum I 20. o 19.791 99.0 I P
Soditun r,o I 5.0 5.201 10{.0 I P
Sodium Hi I 50. o 3L.2 102,{
lzirsoniurl I I I o.sol I I o..B5l 9?.ol
( 1) Control r,imlts :Dlrrcury 80-L20 t Othcr !{otals 90-110r egranl,de 85-115
STL Denver Forxr II (ParE,1) rN
STL DEN}/ER
Total Metals Analysis
-2A-
INITIAL'AND CONTINUING CALIBRATION VERIFICATION
contract: lrRS Corilr(,ratloq
Irab Ceilc: 9TLDE$I Caaa ![o. 3 ,gAS No. :
Inttlal , Cell,bration Eourctl
Contrj.nuing Cal-ibraELon Ecrtrrce :
Etgrh Purlty, Spex
InorganLc Vcnturaa
sDo No. r D5I080283
Coaeantnt:Lon Untts r r{,ll,
lnalfta
rnLtinl CallbratLon
Trnrc Found tn ( 1)
Contl.nulng CrlLbraELon
Tnra Forrnd, tR ( 1) Found %R ( 1)M
nl-rrrd.rlurn I
I c*t.l-urrr r, I 2.Ol
0.252 1100.8
r'.eel es-sl I I I I lpl
I rroa r,o I o.asl o.2s{ lror.e ! I I rl lpl
I rotaaaLumI zo.ol zo.27lror.rl I I I I lpl
luagrr.si.r.l +o.ol ._ g.sol gs.ol .,- I .l I I ,,.-lpl
Sodl,un I,o I 2.A2 1101 .0 P
ZLrconiuml o,242l 96,g
( 1) Conurol Llnl"t,s r Merourar 80-120; Othar ltleta1s 90-110; gyanldr 85-115
'rr I I'
STL Denver for:n II (Part, X) - IN
95