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Home My WebLink AboutDSHW-2024-007785TOOELE CHEMICAL AGENT DISPOSAL FACILITY HAND DELIVERED ?fr'f fr{w UTAH DIVISION OF SOLID & HAZARDOUS WASTE SEGONDARY WASTE DEMONSTRATION TEST REPORT FOR THE METAL PARTS FURNACE Appendix F Revision 0 July 18, 2006 Prepared by: EG&G Defense Materials, Inc. E nvi ronmental Department 11600 Stark Rd. Stockton, UT 8407 1 JIHgfiH 15E.T1 (D rlJo. T' I MPF SWDT REPORT APPENIDIX F SECONDARY WASTE FEED DATA June 912006 APPENDIX F TABLE OF CONTEI{TS SECTION I.O _ SWDT WASTE FEED LOG DATA AND TRACKING FORMS...................F-I SECTION 3.1 3,2 3.3 3.4 3.5 3.6 3.7 3.8 3.9 MPF SWDT REPORT - Rev. 0 Appendix F June 9,2006o F-i aorObe = APPENDIX F SECTION 1.0 SWDT WASTE FEED LOGDATAAND TRACKING FORMS MPF SWDT REPORT - Rev. 0 Appendix F June 9,2006 F-t ltLolui (, o, rL+,cou.EaEoE+J l-ot} .+' (l ,u,E. t-o4o .l - O.-l-oo} .E lo.usol'oE 'F+,0, F-oNo?&{r ,ot-ao?-lud€oto,9=-0 , c, (o ry t= 't aDco @O I - EV . i do q V ,\ ff \J v?tl . u { o \L .te 5 5r - O :k ru !u LJ € ,: 5 ' a= F 1- r € U) a1 a .v a - d. ii .. - E # gI UJ IU U. l tr E. 0 a :l f 3 FF F zz z c? 9 9 u) a o E. E, M. oo o t- l- r- E. 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Uuz,o'TF=F(J _T L (u l L TO LL , F EaPf t gH9u Z!g6 ,E E ohr{ FE ZF - II J 3 E4fr i t =< I z, o I Lu o I .o I dt UJ THI 6l fN ! +H I UNHcI . O A EEiaEi TOCDF WASTE TRACKING FORM MPF MISGELLANEOUS WASTE FEED A. COMPLETED BY CONTROL ROOM OPERATORS MONITORING WASTE TRANSFER 1. Burn Tray Number: 804-6065 (Tray Number - Julian Date) Date Commenced Filling Tray: 3/06/06' Waste Tag #Date in Tray Weight (lbs.)Check Box lt Combustible Comments WIG FG N/A 3/06/2006 36 lbs ./Polyethylene Test Material N/A 3/06/2006 25.3 lbs ./Visor Test Material N/A 3/06/2006 3,9 lbs {Glove Test Material N/A 3/06/2006 260 lbs ',/White DPE Test Material N/A 3/06/2006 15 lbs ./Cannisters (25 ea) ,"-l*-a/r/zc,Dc q L,-.t 5rt. /t;- rr-r L-*,/ N/A il0612ao6 9 lbs 1 Bottle of Bl6ach / wo # 142798 Date Completed Filling Tray:3/06/06 Total Weight:349.21bs B. COMPLETED BY ENVIRONMENTAL SHIFT REP. AND GONTROL ROOM OPERATOR 1. Waste OK to Feed /ArNo'fu',t6leone)?. Non-consecutive feed required, 3. Date Waste MUST BE FED to the MPF: Galculate date by adding 89 days to the oldest container //l TatL 4, Maximum feed temperature 1450 Degrees YES {g (circle one\ 5. Allowed in furnace with rnunitions Notes: ' . lf waste cannot be processed by the MUST BE FED date it MUST be placed into permitted storage prior to exceeding the 90-day storage limit.2. lf waste placed in a tray is from permitted storage the waste must be fed to the MPF as soon as possible not to exceed the next operating day.3. lf waste has no WT number use the date placed in tray to calculate MUSIBE FED.4. Refer to TE-SOP- 092, Appendix K for list of combustible materials. // Control Room Operator SignatukmsL -#uh.Environmental Compliance Signature C. COMPI-ETED BY CONTROL ROOM METAL PARTS FURNACE OPERATORS KWryX 1. Date to MPF (T09):01 t+fiQob Tirne Out Exit Airlock:l5L/0 2. Time in Zone 1 )lt-t1 //,/?comments: A" /Z/''---- Metal Parts Fur{race Operd-tor Signature FAX COMPLETED FORM TO WASTE MANAGEMENT AT X7648 enolx r : i I I I I I I III I I io ! : : : : O:\FO RMS\SOP\092.D 1 . R4C2 TOCDF WASTE TRACKING FORM AEEix.Ei TOCDF-WASTE TRACKING FORM MPF MISGELLANEOUS WASTE FEED A. COMPLETED BY CONTROL ROOM OPERATORS MONITORING WASTE TRANSFER 1. Burn Tray Number: 814-6065 (Tray Number - Julian Date) Date Commenced Filling Tray: 3/06/06 Waste Tag #Date in Tray Weight (lbs.)Check Box lf I Comrnents WIC FH Combustible I N/A 3/06/2006 36 lbs ./Polyethylene Test Material N/A 3/0612006 25.3 lbs ./Visor Test Material N/A 3/06/2006 3.9 lbs {Glove Test Material N/A 3/06/2006 260 lbs ./White DPE Test Material N/A 310612006 15 lbs "/Cannisters (25 ea) t ,/,n-z/e /r*u 4 L*", s j n, /L-r", ,A-t./-.t;J N/A 3/06/2006 9 lbs 1 Bottle of Bleach wo # 142798 Date Cornpleted Filling Tray:3/06/06 Total Weight:349.21bs @ B. GOMPLETED BY ENVIRONMENTAL SHIFT REP. AND CONTROL ROOM OPERATOR 1. Waste OK to Feed 2. Non-consecutive feed required- YES @(circle one)\ 3, Date Waste MUST BE FED to the MPF: Calculate date by adding 89 days to the oldest container Pfi 11ilr }4Afier* 4. Maximunr feed ternperature 1450 Degrees YES tNg (circle onel \ 5. Allowed in furnace with munitions YES G (circle one) '\- Notes:1. lf waste cannot be processed by the MUST BE FED date it MUST be placed into permifted storage prior to exceeding the 90-day storage limit.2. lf waste placed in a tray is from permitted storage the waste must be fed to the MPF as soon as possible not to exceed the next operating day.3- lf waste has no WT number use the date placed in tray to salculate MUST BE FED.4. Refer to TE€OP- 092. Appendix K for list of combustible materials. , , Control Room Operator Signagffi_ f-" {r-1F e -Environmental Compliance Signature c. CoMPLETED BY coNrRoL.RooM MErAL pARrs FURNAGE opERAroRs . %g%###Y :l . Date to MPF (T09):01 PlfrLC ". Time Out Exit Airlock:t'lo8 2. Tirne in Zone 1 l3o;//-=,,e ,4 Comrnents0 lar 7*L w1to*rDor-S vof Tttor-vfi. ihxr'* Wuatus1o'e{{ Metal Part{Furnace Operator S ignature FAX COMPLETED FORM TO WASTE MANAGEMENT AT X7648. enolx ro : , i : : ; I O:\FORMS\SOP\092-D 1 . R4C2 pp TOCDF WASTE TRACKING FORM AEEiaEi TOCDF WASTE TRAGKING FORM MPF MISCELLANEOUS WASTE FEED A. GOMPLETED BY CONTROL ROOM OPERATORS MONITORING WASTE TRANSFER 1. Burn Tray Number: 81 0-6065 (Tray Number - Julian Date) Date Commenced Filling Tray: 3/06/06 Waste Tag #Date in Tray Weight (lbs.)Check Box lf Combustible Comments WIC FE NIA 3/06/2006 36 lbs .l Polyethylene Test Material N/A 3/06/2006 25.3 lbs r/Visor Test Material N/A 3/06/2006 3.9 lbs ./Glove Test Material N/A 3/06/2006 260 lbs "/White DPE Test Material N/A 3/06/2006 15 lbs ./Cannisters (25 ea) Pln 3l ,. /z -,p zl hocs 2n,k- ,^^N N/A 3/06/2006 9 lbs IT 1 Bottle of Bleach w/o # 142798 Date Completed Filling Tray:3/06/06 Total Weight: n rn +all-^ /rr \O+1.A!P!i ,JEs-/ B. COMPLETED BY ENVIRONMENTAL SHIFT REP. AND GONTROL ROOM OPERATOR 1, Waste OK to Feed GrNo (ciiEle one) 2. Non-consecutive feed required. YES G (circle one)\ 3. Date Waste MUST BE FED to the MPF: Calculate date by adding 89 days to the oldest container ;y* ffiorn' 4. Maximurn feed temperature 1450 Degrees YEs ag) (circle one) \-- 5. Allowed in furnace with munitions YES G (circle one)L---- Notes;1. lf waste cannot be processed by the MUST BE FED date it MUST be placed into permitted storage prior to exceeding the 90-day storage limit.2. lf waste placed in a tray is from permitted storage the waste must be fed to the MPF as soon as possible not to exceed the next opemting day.3. lf waste has no WT number use the date placed in tray to calculate MUST BE FED. 4, Refer to TE-SOP- 092. Aopendix K for list of combustible materials. , Environmental Compliance S ignature C. GOMPLETED BY CONTROL ROOM METAL PARTS FURNAGE OPERATORS &sF Wfz EL rn 1. Date to MPF (T09):D1 F^Ae 0b Tirne Out Exit Airlock:IBSL 2. Time in Zone 1 l,4z^1 /.f ---=/ -ry Comments: Mfrftu wBteHf ODfr'( Pot pa'uo A sftrr,, N:ff%t*,N-/ 2 nllEia FA)( COMPLETED FORM TO WASTE MANAGEMENT AT X7648. Appendix F - 7 o O:\FORMS\SOP\092-D 1 .R4C2 TOCDF WASTE TRACKING FORM EEieEi TO.GDF WASTE TRACKING FORM MPF MISCELLANEOUS WASTE FEED A. COMPLETED BY CONTROL ROOM OPERATORS MONITORING W\STE TRANSFER 1. Burn Tray Number: 803-6065 (Tray Number - Julian Date) Date Commenced Filling Tray: 3/06/06 Waste Tag #Date in Tray Weisht (lbs.)Check Box lf I Comments WIC FA Gombustible I N/A 3/06/2006 36 lbs {Polyethyle ne Test Material N/A 3/06/2006 25.3 lbs ./Visor Test Material N/A 3/06/2006 3.9 lbs ./Glove Test Material N/A 3/06/2006 260 lbs .,/White DPE Test Material N/A 3/06/2006 15 lbs ./Cannisters (25 ea) 'ul*3/u/a',, G 4 ls^q s 5V n*'k ,'-:y' ,aL NIA 3/06/2006 I lbs 1 Bottle of Bleach ffix/ffi w.ffi%fl w/o # 142798 Date Completed Filling Trqy,fuflW W-ootoo*Total Weight:349.21bs -f,) B. GOMPLETED BY E.NVIRONMENTAL SHIFT REP. AND CONTROL ROOM OPERATOR 1. Waste Ot<,toc&:bui,'ffi @arnro (circle one) 2. Non-consecutive feed required. YES (Td\ (circre oney- 3. Date Waste MUST BE FED to the MPF: Calculate date by adding 89 days to the oldest container N /p 4. Maxirnum feed ternperature 1450 Degrees YES (b (circle one) 5, Allowed in furnace with munitions YES N(circle one) Notes:1. lf waste cannot be processed by the MUST BE FED date it MUST be placed into. perrnifted storage prior to exceeding the 90-day storage limit.2. lf waste placed in a tray is from permitted storage the waste must be fed to the MPF as soon as possible not to exceed the next operaling day.3. lf waste has no WT number use the date placed in tray to calculate MUST BE FED.4. Refer to fE-SOP- 092, Appendix K for ljst of combustible materials. Enyironrnental Compliance Signature'oorn Operator Sig C. COMPLETED BY CONTROL ROOM METAL PARTS FURNACE OPERATORS 1. Date to MPF (T09):01Mfl Lo L I Time Out Exit Airlock:1755 2- Tirne in Zone 1 /stl L{ I /a comments:'mly* n,*s uor t.2c',,rti' 4-/%.--4#w:*" FAX COMPLETED FORM TO WASTE MANAGEMENTAT X7648.o i : : O :\FO RMS\SOP\092-D 1 . R4C2 TOCDF WASTE TRACKING FORM o AEe,agi TOCDF VVASTE TRACKING FORM MPF MISCELLANEOUS WASTE FEED A" GOMPLETED BY CONTROL ROOM OPERATORS MONITORING WASTE TMNSFER 1. Qurn Tray Number: 81 1-6065 (Tray Number - Julian Date) Date Commenced Filling Tray: 3/06/06 Waste Tag #Date in Tray Weight (lbs.)Clreck Box lf Combustible Comments WIC FD N/A 3/06/2006 36 lbs ./Polyethylene Test Material N/A 3/06/2006 25.3 lbs ./Visor Test Material N/A 3/06/2006 3.9 lbs ./Glove Test Material N/A 3106t2006 260 lbs ^/White DPE Test Material N/A 3/06/2006 15 lbs {Cannisters (25 ea) "r Ia )1"/r"*(-4 L* * r.n,L- tr*t-L*.J N/A 310612006 I lbs t.t 1 Bottle of Bleach wo # 142798 Date Completed Filling Tray:3/06/06 Total Weioht:349.21bs ao B. coMpLErED By ENVrRoNMEurar- sHffitrffiffirffil noorvr opERAroR 1. Waste OK to Feed qMdr w7 2. Non-consecutive feed requlred. YEs @ (circle one)1 3. Date Waste MUST BE FED to the MPF: Calculate date by adding 89 days to the oldest container ffir lrUvt*tfl'* 4. Maximum feed temperature 1450 Degrees YEs (1'.t/ (circle one) 5. Allowed in furnace with rnunitions YES @ (circle one\-- Notes:1. lf waste cannot be processed by the MUST BE FED date it MUST be placed into permitted stonage prior to exceeding the 90-day storage limit.2. lf waste placed in a trayis from permitted storage the waste must be fed to the MPF as soon as possible not to exceed the next operating day.3. If waste has no WT number use the date placed in tray to calculate MUST BE FED.4. Refer to TE-SOP- 092. Appendix K for list of combustlble materials. Afu /-7-'.- Environmental Compllance Signature - L Control Room Operator Signature C. COMPLETED BY CONTROL ROOM METAL PARTS FURNACE OPERATORS 1. Date to MPF (T09):ol MAf-ob Time Out Exit Airlock:t\e7- 2. Time in Zone 1:/1/O comments: o ffi.: Yffim #' H'ffiEbA.ffi* FAX COMPLETED FORM TO WASTE MANAGEMENT AT X7648. s Furnace Operator Appendix F - 9 O:\FORMS\SOP\092-D1 .R4C2 TOCDF WASTE TRACKING FORM : O AEGiaEi TOCDF WASTE TRACKING FORM TVIPF MISGELLAhIEOUS WASTE FEED A. GOMPLETED BY GONTROL ROOM OPERATORS MONITORING WASTE TRANSFER 1. Bum Tray Number: 805.6065 (Tray Number - Julian Date) Date Cornmenced Filling Tray: 3/06/06 Waste Tag #Date in Tray Weight (lbs.)Check Box lf Combustible Comrnents {-Ji-e T c- N/A 3/06/2006 36 lbs ./Polyethylene Test Material N/A 3/06/2006 25.3 lbs ./Visor Test Material N/A 3/06/2006 3.9 lbs-./Glove Test Material N/A 3t06/2006 260 lbs .i -White DPE Test Material N/A 3t06/2006 15 lbs ./Cannisters (25 ea) -lA r /o /"*' 6 4 L^r* io.(r* *J* -.J n<* N/A 3/06/2006 *.elh b.H r##ffi!"# Bleach ffi,._,";q TT: 7t3 ?y ,6u, W wo # 1427s8 Date Completed Filling Tray:3/06/06 Total Weight:349.2lbs B. GOMPLETED BY ENVIRONMENTAL SHIFT REP. AND CONTROL ROOM OPERATOR 1. Waste OK to Feed 2. Non-consecutive feed required. YES @(circle one)- 3. Date Waste MUST BE FED to the MPF: Galculate date by adding 89 days to the oldest container Plr- ffir?ttt'-- 4. Maximum feed temperature 1450 Degrees YES ey (circle one) \' 5. Allowed in furnace with rnu nitions YES '@(circle one)u Notes: 1 . tf waste cannot be processed by the MUST BE FED date it MUST be placed into permitted storage prior to exceeding the 90,day storage limit.2. lf waste placed in a tray is from permitted storage the waste must be fed to the MPF as soon as posslble not to exceed the next operating day.3. lf waste has no WT number use the date placed in tray lo calculate MUST BE FED.4. Refer to TE€OP- 092, Appendix K for list of combustible materials. Control Roorn Operator Signature .?' Environmental Compliance S ignature C. GOMPLETED BY CONTROL ROOM METAL PARTS FURNACE OPERATORS 1. Date to MPF (T09):o'lH4e.ob Time Out Exit Airlock:e7w 2. Time [n Zone 1 t03b Comments:t 1,. Metal FA)( COMPLETED FORM TO WASTE MANAGEMENT AT X7648. 'arts Furnace Operator S nature Appendix F - l0 O:\FO RMS\S OP\092-D 1 .R4C2 TOCDF WASTE TRACKING FORM AEtriaEi TOCDF WASTE TRAGKING FORM MPF MISGELLANEOUS WASTE FEED A. COMPLETED BY CONTROL ROOM OPERATORS MONITORING WASTE TRANSFER 1. Burn Tray Number; 813-6065 (Tray Number - Julian Date) Date Commenced Filling Tray: 3/06/06 Waste Tag #Date in Tray Weight (lbs.)Check Box lf I Comments WIC FF Combustibte I N/A 3/06/2006 36 lbs .l Polyethylene Test Material N/A 3/06/2006 25.3 lbs ./Visor Test Material N/A 3/06/2006 3.9 lbs {Glove Test Material N/A 3/06/2006 260 lbs ./White DPE Test Material N/A 3/06/2006 15 lbs a,l Cannisters (25 ea) * lr,t V u/ze.b l'l L.-,. A^,L-^ ,^---l-,'y' N/A 3/06/2006 I lbs f 1 Bottle of Bleach -.--.-.. jY!r vv/o # 1427e8 3106/06 Total Weight:349.21bs A B. COMPLETED BY ENVIRONMENTALSHIFT REP. AND CONTROL ROOM OPERATOR 1. Waste OK to Feed 2. Non-consecutive feed required; YES G(circle one\-- 3. Date Waste MUST BE FED to the MPF: Galculate date by adding 89 days to the oldest container pt* ffil*fi^/ 4. Ma:rimum feed temperature 1450 DegresI,..*;,, YES EU (circle one) -\'\- i :},riiglififfii:!;i'" 5. Allor,re4 l#Si{ffi ee with rnunitions '''': YES @(circle one) -- Notes: 'l - lf waste cannot be processed by the MUST BE FED date it MUST be plaej[&Jph'permitted storage prior to exceeding the 90-day storage limit.2. tf waste ptaced in a tray is from pennitted storage the waste must ue tea iffiF as soon as possible not to exceed the next operating day. :3. lf waste has no WT number use the date placed in tray to calculate MUST BE FED. 4.. Refer to TE€OP- 092, Appendix K for lisi of combustr''bte materials. / ,,-, Control Room Operator SignatureEnvironmental Compliance Signature G. COMPLETED BY CONTROL ROOM METAL PARTS FURNAGE OPERATORS 1. Date to MPF (T09):01 l"t'A€.O L Time Out Exit Airlock:notu 2. Time in Zone 1 tq5I Comments: XOWhU wPtc;tr EEs tot t*tcwoL t,L,rr* t1A,oL . 4 rts Furnace Operator na FA)( COMPLETED FORM TO WA$TE MANAGEMENT AT X7648. n(lrx o ; : :o l1O:\FO RMS\SOP\092-D1 .R4C2 ppe TOCDF WASTE TRACKING FORM AEEiaEi TOGDF WASTE TRACKING FORM MPF MISGELLANEOUS \A/ASTE FEED A. COMPLETED BY CONTROL ROOM OPERATORS MONITORING WASTE TRANSFER 1. Burn Tray Number: 801-6065 (Tray Number - Julian Date) Date Commenced Filling fray: 3/06/06 Waste Tag #Date in Tray Weight (lbs.)Check Box lf I Cornments WIC FB Combustible I N/A 3/06/2006 36 lbs {Polyethylene Test Material N/A 3/06/2006 25,3 lbs .,,/Visor Test Material N/A 3/06/2006 3,9 lbs .i Glove Test Material N/A 3/06/2006 260 lbs ',/White DPE Test Material N/A 3/06/2006 15 lbs ./Cannisters (25 ea) -lur a/ot,/zoob e-l f,*^ q a -ot,/ i*- ,irok -*:J -r.,N/A 3/06/2006 I lbs lf 1 Bottle of Bleach wo # 1427s8 Date Completed Filling Tray:3/06/06 Total Weight:349.21bs *O B. SOMPLETED BY ENVIRONMENTAL SHIFT REP. AND CONTROL ROOM OPERATOR 1. Waste OK to Feed @rNo(tircle one) 2. Nen-consecutive feed required. YES 6") (circle onep' 3, Date Waste MUST BE FED to the MPF: Calculate date by adding 89 days to the oldest container Y[,+ lzgr y,t+{1t/lfr1-' 4. Maximum feed temperature 1450 Degrees YES (I9 (circle one) 5. Allpwed in furnace with munitions YES 6o-t (circle onelv Notes:.1. lf waste cannot be processed by the MUST BE FED date it MUST be placed into permitted storage prior to 2. 3. 4. exceeding the 90-day storage limit. {,::qf #:I E"'tr ,; 5:l i : - ::o ":*': : th e waste m ust b e "''"-::_:'j" " *ffi ffi \'lf waste has no WT nr.imber use the date placed in tray to calculate MUST BE FED. Refer to TE-SOP- 092, Appendix K for list of combustible materials. ze Environrnental Compliance S ignature Control Room Operator Signature C. GOMPLETED BY CONTROL ROOM METAL PARTS FURNACE OPERATORS 1. Date to MPF (T09):00 144/20 6 Time Out Exit Airlock:IO3O 2. Time in Zone 1:obL| I /-4 CommentS: #tzlrrl-WEr6p1 DoEs Nor !p*-o au,ffv7ru*t-@,,+{zutp Metal Parts rnace Operator Signature FA)( GOMPLETED FORM TO WASTE MANAGEMENT AT X7648. Appendix F - l2 O:\FORMS\SOP\092-D 1 . R4C2 TOCDF WASTE TRACKING FORM TOGDF WA$TE TRACKING FORM MPF MISCELLANEOUS WASTE FEED A. COMPLETED BY CONTROL ROOM OPERATORS MONITORING WASTE TRANSFER 1. Burn Tray Numben 812-6066 (Tray Number - Julian Date) Date Comrnenced Filling Tray: 3/07/06 Waste Tag #Date in Tray Weight (lbs.)Check Box lf Cornbustible Cornments WIC FO N/A 3/07/2006 36 lbs {Polyethylene Test Material N/A 3/07/2006 297 lbs ./Uncontaminated DPE Training Suits N/A u07pao6 I lbs ./1 Boftle of Bleach N/A 3/07/2006 15 lbs Canisters (25 ea) N/A 3t07t2006 4 Bags ./4 Bags Spiking Material wo # 142798 Date Completed Filling Tray:3/07/06 Total Wdight:357 lbs € B. GOMPLETED BY ENVIRONMENTAL SHIFT REP. AND CONTROL ROOM OPERATOR 1. Waste OK to Feed filrorNo J6rde one) 2. Non-consecutive feed required. YES fffii (circle one)"/ 3. Date Waste MUST BE FED to the MPF: Galculate date by 'adding 89 days to the oldest container T*ynslkl,\t MIA. 4. Maxintum feed temperature 1450 Degrees YES rNq (circle on"lv 5. Allowed in furnace with munitions YES fu (circle on*N-" Notes: 1 . lf waste cannot be processed by the MUST BE FED date il MUST be placed into permitted storage prior to 2 exceeding the 90-day storage limit. 6ffi If waste placed in a tray is from permitted storago the waste must be fed to the MPF as WFexceed the next operating day. lf waste has no WT number use the Cate placed in tray to calculate MUST BE FED. Refer to TE€OP- 092. Aooendix K for list of cbmbustible materials. 3 4 Control Room Operator SignatureEnvironmental Compliance Signature C. COMPLETED BY CONTROL ROOM METAL PARTS FURNACE OPERATORS 1. Date to MPF (T09):oD ,.ifip,ob Time Out Exit Airlock:liBq 2. Time in Zone 1:o-1 5? Comments:$zr14l tuErddt boEs &Dr peu.i€ * S --q=f- \vv.., .v. !e F _._, _i;%gg: FAX COMPLETED FORM TO WASTE MANAGEMENT AT X7648. TOCDF WASTE TRACKING FORMO:\FO RMS\SOP\092-D 1 . R4C2 Appendix F o TOCDF WASTE TRAGKING FORM MPF MISGELLANEOUS WASTE FEED A. COMPLETED BY CONTROL ROOM OPERATORS MONITORING WASTE TRANSFER 1. Bum Tray Number: 823-6066 (Tray Number - Julian Date) Date Commenced Filling Ttay: 3to7106 Waste Tag #Date in Tray Weight (lbs.)Check Box lf I Comments WIC FP Combustible I N/A 310712006 36 lbs {Polyethylene Test Material N/A 310712006 295 lbs ./Uncontaminated DPE Training Suits N/A 310712006 I lbs ./1 Bottle of Bleach N/A 310712006 15 lbs Canisters (25 ea) N/A 310712006 4 Bags ./4 Bags Spiking Material wo # 142798 Date Completed Filling Tray:3107/06 Total Weight:355 lbs P B. GOMPLETED BY ENVIRONMENTAL SHIFT REP. AND GONTROL ROOM OPERATOR 1. Waste OK to Feed ffigorNo fficle one) 2. Non-consecutive feed required. YES TG (circle onef'-- 3. Date Waste MUST BE FED to the MPF: Calculate date by' adding 89 days to the oldest container ft';r rt1ft\rf*,\ a tL/ /n 4. Maximum feed temperature 1450 Degrees YES d-9:,(circle one) 5. Allowed in furnace with munitions YES ftI (circle one)--- Notes:1. lf waste cannot be processed by the MU$T BE FED date it MUST be placed into permitted storage prior to exceeding the 90-day storage limit.2. lf waste placed in a tray is from permitted storage the waste must be fed to the MPF as so 3 4 exceed the next operating day lf waste has no WT number use the date placed in tray to calculate MUST BE FED. Refer to TE-SOP- 092, Appendix K for list of combustible materials. Enviionmentat Compliance Signature Control Room Operator Signature G. COMPLETED BY GONTROL ROOM METAL PARTS FURNAGE OPERATORS 1. Date to MPF (T09):o6nA(da Time Out Exit Airlock:t3L5 2. Time in Zone 1 /oq t1 nolx l-..O:\FORMS\SOP\092-D 1 .R4C2 ppe t4 TOCDF WASTE TRACKING FORM TOCDF IIITASTE TRACKING FORM MPF MI$GELLANEOUS WASTE FEED A. GOMPLETED BY CONTROL ROOM OPERATORS MONITORING WASTE TR,ANSFER 1. Burn Tray Number: 808-6066 (Tray Number - Julian Date) Date Commenced Filling Tray: 3/07/06 Waste Tag #Date in Tray Weight (lbs.)Check Box !f Combustible Comrnents WIC FN N/A 310712006 36 lbs .l Polyethylene Test Material N/A 3/07/2006 295 lbs .i Uncontaminated DPE Training Suits N/A 3107t2006 9 lbs v 1 Bottle of Bleach N/A 3t07t2006 15 lbs Canisters (25 ea) N/A 3t07t2006 4 Bags r/4 Bags Spiking Materia! w/o # 142798 Date Completed Filling Tray:3/07/06 Total Weight:3ss lbs +Lj B. COMPLETED BY ENVIRONMENTAL SHIFT REP. AND GONTROL ROOM OPERATOR 1. Waste OK to Feed rGslrNo \r'i6i" one) 2. Non-consecutive feed required. YEs dq(circle one) \-J' 3, Date Waste MUSI BE FED to the MPF: Calculate date by adding 89 days to the oldest container 1tS+nnAlenql 11/1fi 4. Maximum feed temperature 1450 Degrees YES y (circle one) 5. Allowed in furnace with munitions YES TTfu\ (circle one)\--z Notes:1, lf waste cannot be processed by the MUST BE FED date it MUST be ptaced into permitted storage pdor to exceeding the 90-day storage limit.2. lf waste placed in a tray is from permifted storage the waste must be fed to the MPF as soon atc 4 exceed the next operating day. if waste has no WT nurnber use the daie piaced in tray io calculate MUST BE FED. Refer to TE-SOP- 092, Appendix K for list of combustible materials- Control Roorn Operator Signatureronmental Compliance Signature G. COMPLETED BY CONTROL ROOM METAL PARTS FURNACE OPERATORS 1. Date to MPF (T09):o8 velloto Tirne Out Exit Airlock:/q(7 2. Time in Zone 1 lol 5 / O:\FORMS\SOP\092-D 1 . R4C2 Appendix F - l5 TOCDF WASTE TRACKING FORM AEGiaEi TOGDF WASTE TRACKING FORM MPF IVIISGELLANEOUS WASTE FEED A. COMPLETED BY COI.ITROL ROOM OPERATORS MONITORING WASTE TRANSFER 1. Burn Tray Nurnber: 807.6066 (Tray Number - Julian Date) Date Commenced Filling Tray: 3/07/06 Waste Tag #Date in Tray Weight (lbs.)Check Box lf Combustible Comments WIC FM N/A 3/07/2006 36 lbs ./Polyethylene Test Material N/A 3107120a6 292 lbs {Uncontaminated DPE Training Suits N/A 3107t2006 9 lbs {1 Bottle of Bleach NIA 3t0712006 15 lbs Canisters (25 ea) N/A 3t0712006 4 Bags ,v 4 Bags Spiking Material ffiffim Affilr ffi" &, %#W*#ffif,.#l W w/o # 142798 Date Completed Filling Tray:3/07/06 Totat Weight:352 lbs p B. GOMPLETED BY ENVIRONMENTAL SHIFT REP. AND CONTROL ROOM OPERATOR 1. Waste OK to Feed G#orNo (circle one) 2. Non-consecutive feed required- YES ,., N-b, (circle onhl- --- " r.a 3. Date Waste MUST BE FED to the IITPF: Calculate date by adding 89 days to the oldest container Icsr fi,ri14*r*t r"l,\ 4. Maximurn feed temperature 1450 Degrees YES Ng.', ' (circle one) 5. Allowed in furnace with munitions ,/+-- YES ( No/ (circle ondf=-- Notes:L lf waste cannot be processed by the MUST BE FED date it MUST be placed lnto permitted storage priorto exceeding the 90-day storage limit.2- lf waste placed in a tray is frorn permitted storage the waste must be fed to the MPF as soon as possible not to exceed the next operating day.3. lf waste has no WT number use the date placed in tray to calculate MUST BE FED.4- Refer to TE-SOP- 092. Aooendix K for list of combustible materlals. q:t.*-\R Environmental Compliance Signatu re Control Room Operator Signature C. COMPLETED BY CONTROL ROOM METAL PARTS FURNACE OPERATORS 1. Date to MPF (T09):OBIqAc %Time Out Exit Airlock:lb tL{ 2. Time in Zone 1 te.\:.--n ft Cornrnents: # rcr*t Wr,jl*r ilqzs p,or tpul/DE ,SPr El rt(o f'v4,oTtr?*.tftL - fr t-t.*tLO t 4o4ffi"'u$.o I -' -- Metal Parts Furnace Operator Signature FA)( coMpLErED FoRM rowASrE MANAoE$$ilfirdilfllo+4.o O:\FORMS\SOP\092 -D 1 . R4C2 TOGDF WASTE TRACKING FORM o O Appendix F - l7 TOCDF WASTE TRAGKING FORM MPF IUIISCELLANEOUS WASTE FEED A. COMPLETED BY CONTROL ROOM OPERATORS MONITORING WASTE TRANSFER 1. Burn Tray Number: 802-6066 (Tray Number - Julian Date) Date Cornrnenced Filling Tray: 3/07/06 Waste Tag #Date in Tray Weight (lbs.)Check Box lf Combustible Comments WIC FJ N/A 3/07/2006 36 lbs ./Polyethylene Test Material N/A 310712006 295 lbs {Uncontaminated DPE Training Suits N/A 3/07/2006 9 lbs ./1 Bottle of Bleach N/A 3/07#ffi."+ffi,r, llF %,.,.\ /tr 15 lbs Canisters (25 ea) N/A 3/o-qffiffi*t*r ,i*:!;:irtt H 4 Bags ./4 Bags Spiking Material w/o # 142798 Date Completed Filling Tray:3/07/06 Total Weight:355 lbs ry{tt B. COMPLETEo ey ENvIRoNMENTAL SHIFT REP. AND CONTROL ROOM OPERATOR 1. Waste OK to Feed flBorNo [+dre one) 2. Non-consecutive feed required.'=u,",rcle one) $ 3. Date Waste MUST BE FED to the MPF: Calculate date by adding 89 days to the oldest container {esfay1ffi.f,vl *;[ n 4. Maximum feed temperature 1450 Degrees YEs C9(circle one) 5. Allowed in furnace with munitions YES 6d (circle one)- Notes:1. lf waste cannot be processed by the MUST BE FED date it MUST be placed into permitted storage prior to exceeding the 90-day storage limit.2. lf waste placed in a tray is from permitted storage the waste must be fed to the MPF as soon as possibte not to exceed the next operating day.3. If rrvaste has no WT number use the date placed in tray to calculate MUST BE FED.4. Refer to TE€OP- 092. Apoendix K for list of combustible materials, // Environmental Comptiance Signatu re Control Room Operator Signature C. COMPLETED BY GONTROL ROOM METAL PARTS FURNACE OPERATORS 1. Date to MPF (T09):O\ l4R{L ob Time Out Exit Airlock:,/7/< 2. Time in Zone 1:t3L0 Furnace Operator Signa O:\FORMS\SOP\092-D 1 . R4C2 TOCDF WASTE TRACKING FORM : O TOCDF WASTE TRACKING FORM MPF MISCELLANEOU$ WASTE FEED A. GOMPLETED BY CONTROL ROOM OPERATORS.MONITORING WASTE TRANSFER 1. Burn Tray Number: 821-6066 (Tray Number - Julian Date) Date Commenced Filling Tray: 3/07/06 Waste Tag #Date in Tray Weight (lbs.)Check Box lf Combustible Cornrnents WIC FL N/A 3t0vt2006 36 lbs .l Polyethylene Test Material N/A 3t07t2006 296 lbs ./Uncontaminated DPE Training Suits N/A 3107t2006 I lbs ./1 Bottle of Bleach N/A 3t07noa6 15 lbs Canisters (25 ea) NIA 310712006 4 Bags r/4 Bags Spiking Material 1dffi'.,'qfFrlb- %;i.-"Hitii#,*-tW F!'wo # 142798 Date Completed Filling Tray:3/07/06 Total Weight:356 lbs ,p B. COMPLETED BY ENVIRONMENTAL SHIFT REP. AND GONTROL ROOM OPERATOR 1. Waste OK to Feed rfEsbr No f*de one) 2. Non:consecutive feed required. YES AG) (circle on{/ 3. Date Waste MUST BE FED tO the MPF: Calculate date by adding 89 days to the oldest container fcgr ihfihrqt l f'lr' { n 4. Maximum feed temperature 1450 Degrees YES t7(circle one) 5. Allowed in furnace with rnunitions "=t,",rcle """r@ Notes:1. lf waste sannot be processed by the MUST BE FED date it MUST be placed lnto permitted storage prior to exceeding the 90-day storage llmit.2. lf waste placed in a tray is from permltted storage the \,vaste must be fed to the MPF a$ soon as possible not to exceed the next operatlng day.3. lf waste has no WT number use the date placed in tray to calculate MUST BE FED.4. Refer to TE-SOP- 092, Appendix K for list of combustible materials. Environmental Compliance Signature Operator Signature C. COMPLETED BY CONTROL ROOM METAL PARTS FURNACE OPERATORS 1. Date to MPF (T09):oSYt*Lo(a Time Out Exit Airlock:tqDT 2- Time in Zone I t4s) comrn ents: #ror * w? q* f Pqt^ry: Yfwibsgttct*WtLot' Metal P-!-,4f%tvter FAX COMPLETED FORM TO WASTE MANAGEMENT AT X7648. .s F[rnace O:\FORMS\SOP\092-D 1, R4C2 Appendix F - l8 TOCDF WASTE TRACKING FORM TOCDF WASTE TRACKING FORM TVIPF MISGELLANEOUS WASTE FEED A. COMPLETED BY CONTROL ROOM OPERATORS MONITORING WASTE TRANSFER 1, Burn Tray Number: 824-6066 (Tray Number * Julian Date) Date Commenced Filling Tray: 3/07/06 Date in Tray Weight (lbs.)Check Box lf Combustible 297 lbs Uncontaminated DPE Training Suits 310712006 1 Bottle of Bleach Canisters (25 ea) 3n7t2A06 4 Bags Spiking Material w/o # 142798 Total Weight:357 lbs e. coupf;erED By EMnRoNMENTAL sHrFT REp. AND coNTRoL RooM opERAToR GorNo(circle one) 2. Non-consecutive feed required. j3.' Datg Waste ffiUST ,i,' .BE*FED to the MPF: .ICalculate date by adding 89 days to the oldest container [bsf fifttsd*rt 4. Maximum feed temperature 1450 Degrees 5. Allowed in furnace with munitions A*YES T NO (circle on$J Notes:1. If waste cannot be processed by the MUST BE FED date it MUST be placed into permitted storage prior to exceeding the 90-day storage limit.2. lf waste placed in a tay is fiom permitted storage the waste must be fed to the MPF as soon as possiUie'noi to exceed the next operating day- .i lf waste has no WT nurnber use the date placed in tray to calculate MUST BE FED. Refer to TE€OP- 092, Appendix K for list of combustible materials. Control Room bperator SignatureEnvironmental Compliance Signature C. GOMPLETED BY CONTROL ROOM METAL PARTS FURNACE OPERATORS 2. Time in Zone 1: Comrnents: FA)( GOMPLETED FORM TO WASTE MANAGETUENT AT X7 Fuinace Operator Sig O :\F O RMS\S OP\092-D 1 .R4C2 Appendix F -TOCDF WASTE TRACKING FORM TOGDF WASTE TRACKING FORM MPF MISCELLANEOUS WASTE FEED A. COMPLETED BY GONTROL ROOM OPERATORS MONITORING WASTE TRANSFER 1, Burn Tray Number: 818-6066 (Tray Number - Julian Date) Date Comrnenced Filling Tray: 3/07/06 Waste Tag #Date in Tray Weight (lbs.)Gheck Box lf Combustible Cornments WIC FK N/A 310712006 36 lbs {Polyethylene Test Material N/A 310712006 297 lbs ./Uncontaminated DPE Training Suits N/A 3la7no06 9 lbs ./1 Bottle of Bleach N/A 3t0712006 15 lbs Canisters (25 ea) N/A 3t0712006 4 Bags ./4 Bags Spiking Material w/o # 142798 Date Completed Filling Tray:3/07/06 Total Weight:357 lbs B. GOMPLETED BY ENVIRONMENTAL SHIFT REP. AND CONTROL ROOM OPERATOR 1. Waste OK to Feed I#de one) 2. Non-consecutive feed required. YES ffiD (circle one)\.-_,/ 3. Date Waste MUST BE FED to the MPF: Galculate date by adding 89 days to the oldest container *rl(* rrnttdq t {Vin 4. Maxirnum feed temperature 1450 Degrees YES , u9 (circle one) \/ 5. Allowed in furnace with munitions YEs fr-d (circle one) v Notes:1. lf waste cannot be processed by the MUST BE FED date it MU$T be plqced into permitted storage prior to exceeding the 90-day storage limit.2. lf waste placed in a tray is fiom permitted storage the waste must be fed to the MPF as soon as possible not to 3 4 exceed the next operating day lf waste has no WT number use the date placed in tray to calculate MUST BE FED. Refer to TE-SOP- 092, Appendix K for list of combustible materials. ,/ Environmental Com pliance Signature Control Room Operator Signature C, GOMPLETED BY GONTROL ROOM IT'IETAL PARTS FURNACE OPERATOR$ 1. Date to MPF (T09):ONHAD Dl Time Out Exit Airlock:2zoZ 2. Time in Zone 1:i7q1 Cornments: FA)( COMPLETED FORM TO WASTE MANAGEMENT AT X7648. Furnace Operator Si Appendix 20 TOCDF WASTE TRACKING FORMO1FORMS\SOP\092-D 1 . R4C2 AEEiatr TOCDF WASTE TRACKING FORM MPF MISGELLANEOUS I/VASTE FEED A COMPLETED BY CONTROL ROOM OPERATORS MONITORING WASTE TRANSFER 1. Burn Tray Number: 809-6067 (Tray Number - Julian Date) Date Commenced Filling Tray: 3/08/06 Waste Tag #Date in Tray Weight (lbs.)Check Box lf Combustible Cornments WIC FT N/A 3/08/2006 36 lbs ./Polyethylene Test Material N/A 3/08/2006 294 lbs '../Uncontaminated DPE Training Suits N/A 3/08/2006 9 lbs {1 Bottle of Bleach N/A 3/08/2006 15 lbs Canisters (25 ea) N/A 3/08/2006 4 Bags ./4 Bags Spiking Material .#h..ffi. m ffiSa tE!\ %#P,%#diri Yff.,e w/o #'t42798 Date Completed Filling Tray:3/08/06 Total Weight:354 lbs B. COMPLETED BY ETWIRONMENTAL SHIFT REP- AND GONTROL ROOM OPERATOR 1- Waste OK to Feed (GorNo-ffite one) 2. Non-consecutive feed required. YES Ko) (circle one}< 3, Date Waste MU$T BE FED to the MPF: Galculate date by adding 89 days to the oldest container Tp'rFu 4. Maximum feed temperature 1450 Degrees YES qU (circle one) 5. Allowed in furnace with munitions YES G (circle one) \- Notes:1. lf waste cannot be processed by.the MUST BE FED date it MUST be placed into permitted storage prior to exceeding the 9Q-day storage limit.2. lf waste placed in a tray is from permitted storage the waste must be fed to the MPF as soon as possible not to exceed the next operating day.3. lf waste has no WT number use the date placed ln tray to calculate MUST BE FED.4- Refer to TE-SOP- 092. Appendix K for list of combustible materials. Environrnental Cornpliance Signature Control Room Operator Signature G. GOTUPLETED BY CONTROL ROOM METAL PARTS FURNAGE OPERATORS 1. Date to MPF (T09):ox,4Ap 0(Time Out Exit Airlock:2a71 2. Time in Zone 1 t1 tE Comments: FA)( COMPLETED FORM TO WASTE MANAGEMENT AT X7648. Furnace Opdrator Sign o Appendix F - 21 O:\FORMS\SOP\092- D 1 .R4Cz TOCDF WASTE TRACKING FORM o : i i : : :o TOCDF WASTE TRACKING FORM22O:\FO RMS\SOP\O92- D 1 . R4C2 AEEaEi TOCDF VI/,ASTE TRACKING FORM MPF MISGELLANEOUS WASTE FEED A" COMPLETED BY CONTROL ROOM OPERATORS MONITORTNG WASTE TRANSFER 1. Burn Tray Number: 825-6067 (Tray Number - Julian Date) Date Commenced Filling Tray: 3/08/06 Waste Tag #Date in Tray Weight (lbs.)Check Box lf Combustible Comments WIC FW N/A 3/08/2006 36 lbs r/Polyethylene Test Material N/A 3/08/2006 297 lbs ",/Uncontaminated DPE Training Suits N/A 3/08/2006 9 lbs 1 Boftle of Bleach N/A 3/08/2006 15 lbs Canisters (25 ea) N/A 3/08/2006 4 Bags ./4 Bags Spiking Material druffiffiqh%^ffiw%#,ffi* ffi wo # 142798 Date Completed Filling Tray:3r08/06 Total Weight:357 tbs *P B. COMPLETED BY ENVIRONMENTAL SHIFT REP. AND CONTROL ROOM OPERATOR 1. Waste OK to Feed GrorNo lHdle one) 2. Non-consecutive feed required. YES /N-O) (circle on.ft' 3. Date Waste MUST BE FED to the MPF: Calculate date by adding 89 days to the oldest container Tp,t 4. Maxirnum feed temperature 1450 Degrees YES Ca (circte one) \ 5. Allowed in furnace with munitions YES f-6) (circle one)< Notes:1. lf waste cannot be processed by the MUST BE FED date it MUST be placed into permitted storage prior to exceeding the 90-day storage limit.2. lf waste placed in a tray is from permitted storage the waste must be fed to the MPF as soon as possible not to exceed the next operating day.3. lf waste has no WT number use the date placed in tray to calculate MUST BE FED.4. Refer to TE-SOP- 092, Appendix K for list of combustible materials. n kL-/F 4 Environmental Compliance Signature Control Room Operator Signature C. COMPLETED BY GONTROL ROOM METAL PARTS FURNACE OPERATORS 1 Date to MPF (T09):ffiMAECC Time out Exit Airlock: I t C J{ 2. Time in Zone 1 0b40 h Comments:Bfu \ow w9r efir Dac-f l.,of t,v:witL d FAX COMPLETED FORM TO WASTE MANAGEMENT AT X7648. A ^rro..lirr E' - AEEiaEi TOGDF WASTE TRACKING FORM MPF TVIISGELLANEOUS VVASTE FEED A- COMPLETED BY CONTROL ROOM OPERATORS MONITORING WASTE TR.ANSFER 1. Bum Tray Number: 817 -6067 (Tray Nurnber - Julian Date) Date Commenced Filling Tray: 3/08/06 Waste Tag #Date in Tray Weight (lbs.)Check Box lf Combustible Comments WIC FX N/A 3108/2006 36 lbs ./Polyethylene Test Material N/A 3/08/2006 296 lbs ./Uncontaminated DPE Training Suits N/A 3/08/2006 9 lbs ./1 Bottle of Bleach N/A 3/08/2006 15 lbs Canisters (25 ea) N/A 310812006 4"Bags .i 4 Bags Spiking Material w/o # 142798 Date Completed Filling Tray:3108/06 Total Weight:356 lbs P B. COMPLETED BY ENVIRONMENTAL SHIFT REP. AND CONTROL ROOM OPERATOR 1. Waste OK to Feed GorNo (d6leone) 2. Non-consecutive feed required. YES @(circle one) Y 3. Date Vllaste MUST BE FED to the MPF: Galculate date by adding 89 days to the oldest container Ttsr 8W 4. Maximum feed temperature 1450 Degrees YES \-Jg/ (circle one) 5. Allswed in furnace with munitions YES @(circle one)L Notes:1 X#3:::ff[ffBx?f:iJ;?:bv rhe MUsr BE FED dare it MUSr be praced '",. '".,mryffiffiw2. lf waste placed in a tray is from permitted storage the wasle must be fed to the MPF as soWs@ffiBnot toE exceed the next operating day.3. lf waste has no WT number use the date placed in tray to calculate MUST BE FED.4. Refer to TE-SOP- 092, Appendix K for list of combustible materials. Environrnental Compliance S ignatu re Control Room Operator Signature C. COMPLETED BY CONTROL ROOM METAL PARTS FURNACE OPERATORS 1. Date to MPF (T09):ffivt+L Ob Time Out Exit Airlock:/zcl ''/ 2. Time in Zone 1 01 5B /4 comments: *{ffiyrf* Do6 var rttktPL /4'W Qt+'+rlot'A1- ' at. Metal Partd-Furnace Operator Signature FAX COMPLETED FORM TO WASTE MANAGEMENT AT X7648. Appendix F - O :\FORMS\SOP\092-D 1 . R4C2 TOCDF WASTE TRACKING FORM :o Appendix F - 24 AEEiatr TOCDF WASTE TRACKING FORIVI NIPF MISGELLANEOUS WASTE FEED A. COMPLETED BY CONTROL ROOM OPERATORS MONITORING WASTE TRANSFER 1. Burn Tray Nurnber: 815-6067 (Tray Number - Julian Date) Date Commenced Filling Tray: 3/08/06 Waste Tag #Date in Tray Weight (lbs.)Check Box tt Combustible Comrnents WIC FV N/A 3/08/2006 36 lbs ./Polyethylene Test Material N/A 3/08/2006 300 lbs ',/Uncontaminated DPE Training Suits N/A 3/08/2006 9 lbs ./1 Bottle of Bleach N/A 3/0812006 15 lbs Canisters (25 ea) N/A 3/08/2006 4 Bags ./4 Bags Spiking Material w/o # 1427e8 Date Completed Filling Tray:3/08/06 Total Weight:3oo rbs +{r B. COMPLETED BY ENVIRONMENTAL SHIFT REP. AND GONTROL ROOM OPERATOR 1. Waste OK to Feed @orNo(Cirtle one) 2- Non-consecutive feed required. YES .O (circle onb)tq/ 3. Date Waste lvlUST BE FED to the MPF: Galculate date by adding 89 days to the otdest container ff-rL 4. Maxirnurn feed temperature 1450 Degrees YES Qry (circle one) -\ 5. Allowed in furnace with munitions YES G (circle one) \ Notes: 1 . lf waste cannot be processed by the MUST BE FED date it MUST be placed into permitted storage prior to 2. 3. 4. exceeding the 90-day storage limit. 5q lf waste placed in a tray is from permitted storage the wasle must be fed to the MF aE exceed tire next operating Oay. &6dP lf waste has no WT number use the date placed in tray to calculate MUST BE FED. Refer to TE-SOP- 092, Apoendix K for list of combustible materials. ffi,., Environmental Compliance Signature Control Room Operator Signature G. GOMPLETED BY GONTROL ROOM METAL PARTS FURNACE OPERATORS 1. Date to MPF (T09):On gd-{. Ot,Time Out Exit Airlock:t 3L7 2. Time in Zone 1 oq (b /.t/b Comments:Ptarec w&n*r lV": f/ot tr4c'u/tnL- ifrtlrt'* trlttul4tt<"S ffil%_ Metal Parts y'urnace Operator Signature FAX COMPLETED FORM TO WASTE IVIANAGEMENT AT X7648, l O:\FORMS\SOP\092-D 1 .R4CZ TOCDF WASTE TRACKING FORM A EEiaEi TOCDF WASTE TRACKING FORM MPF MISCELLANEOUS WASTE FEED A. CON,IPLETED BY CONTROL ROOM OPERATORS MONITORING WASTE TRANSFER 1. Bum Tray Number: 822-6067 (Tray Nurnber - Julian Date) Date Commenced Filling Tray: 3108/06 Waste Tag #Date in Tray Weight (lbs.)Check Box lf Cornbustible Comments Ut/lC FU N/A 3/08/2006 36 lbs ./Polyethylene Test Material N/A 3/08/2006 295 lbs ./Uncontaminated DPE Training Suits N/A 3/08/2006 I lbs ./1 Bottle of Bleach N/A 3/08/2006 15 lbs Canisters (25 ea) N/A 3/08/2006 4 Bajs ./4 Bags Spiking Material wo # 142798 Date Completed Filling Tray:3/08/06 Total Weight:3s5 lbs *'o) B. COMPLETED BY ENVIRONMENTAL SHIFT REP. AND GONTROL ROOM OPERATOR 1, Waste 0K to Feed 2. Non-consecutive feed required. YES G) (circle one).< 3. Date Ul/aste MUST BE FED to the MPF: Galculate date by adding 89 days to the oldest container TruflU 4. Maxirnum feed temperature 1450 Degrees YES 0g(circle one) \ 5. Allowed in furnace with munitions YES ffi) (circle one)Y Notes:1. lf waste cannot be processed by the MUST BE FED date it MUST be placed into permitted storage prior to exceeding the 90-day storage limit.2. lf waste placed in a tray is from permitted storage the waste must be fed to the MPF as soon as possible not to exceed the next operating day.3. lf waste has no WT numbei use the date placed in tray to calculate MUST BE FED.4. Refer to TE-SOP- 092, Appendix K for list of combustible materials. Environmental Compliance S ignature Lffi Control Room Operator Signature C. COMPLETED BY GONTROL ROOM METAL PARTS FURNAGE OPERATORS 1. Date to MPF (T09):q nlwab Time Out Exit Airlock:t,-.\Er 2. Time in Zone 1 toilg Comments: .@rcrW wF,r0l+r DoEs i" lrtzcuurD( { P tlcPao l'. 'F'fttLt $ qP*O o b 4zr/%* FA)( COMPLETED FORM TO WASTE MANAGEMENT AT X7648. O :\FORMS\SOP\092-D 1 .R4C2 ffi TOCDF WASTE TRACKING FORM TOGDF WASTE TRACKING FORM MPF MISCELLANEOUS WASTE FEED A. COMPLETED BY CONTROL ROOM OPERATORS MONITORING WASTE TRANSFER 1 . Burn Tray Number: 81 9-6067 (Tray Number - Julian Date) Date Cornmenced Filling Tray: 3/08/06 Waste Tag #Date in Tray Weight (lbs.)Check Box lf Combustible Comrnents WIC FS N/A 3/08/2006 36 lbs ./Polyethylene Test Material N/A 3/08/2006 292lbs "1 Uncontaminated DPE Training Suits N/A 3/08/2006 9 lbs ./1 Bottle of Bleach N/A 3/08/2006 15 lbs Calisters (25 ea) N/A 3/08/2006 4 Bags ./4 Bags Spiking Material w/o # 142798 Date Completed Filling Tray:3108/06 Total Weight:352 rb* *d B. GOMPLETED BY ENVIRONMENTAL SHIFT REP. AND CONTROL ROOM OPERATOR 1.Waste OK to Feed @rNo(circle one) 2. Non-consecutive feed required. YES @ (circle one) \ 3. Date Waste MUST BE FED to the MPF: Calculate date by adding 89 days to the oldest container fr;-{Y'|' 4. Maximum feed temperature 1450 Degrees YES sg (circle one) 5. Allowed in furnace with munitions YES (O (circle one) \ Notes:1. lf waste cannot be processed by the MUST BE FED date it MUST be placed into permitted storage prior to exceeding the gO-day storage limit.2. lf waste placed in a tray is from permitted storago the waste must be fed to the MPF as soon as possible not to exceed the next operatlng day-3. lf waste has no WT number use the date placed in tray to calculate MUST BE FED.4. Refer to TE-SOP- 092, Appendix K for list of combustible materials,4 Environmental Compliance Signature Control Room Operator Signature C. COMPLETED BY CONTROL ROOM METAL PARTS FURNACE OPERATORS 1, Date to MPF (T09):o? t'Lft{L 0L Time Out Exit'Airlock:tb't I 2. Time in Zone 1 tLoS A Comments: FAX COMPLETED FORM TO WASTE MANAGEMENT AT X7648. I O:\FORMS\SOP\092-D 1 . R4C2 ffiffiffi TOCDF WASTE TRACKING FORM AEEiaEi TOGDF WASTE TRAGKNG FORM MPF TVIISCELLANEOUS VIJASTE FEED A. COMPLETED BY CONTROL ROOM OPERATORS MONITORING WASTE TRANSFER 1. Burn Tray Number: 81 6-6067 (Tray Number - Julian Date) Date Commenced Filling Tray: 3/08/06 Waste Tag #Date in Tray Weight (lbs.)Check Box lf Combustible Comrnents WIC FR N/A 3/08/2006 36 lbs .i Polyethylene Test Material N/A 3/08/2006 292 lbs ./Uncontaminated DPE Training Suits N/A 3/08/2006 9 lbs ./1 Bottle of Bleach N/A 3/08/2006 15 lbs Canisters (25 ea) N/A 3/08/2006 4 Bags .l 4 Bags Spiking Material 6ffi,hd,ry'i. , - 7:q: :irrA-:jj iRb,# qb*#t(h#,r'i..,,t - iiii :'.11 w/6 # Mzlss Date Completed Filling Tray:3/08/06 Total Weight:3sz ]bs rr"L' B. COMPLETED BY ENVIRONMENTAL SHIFT REP. AND CONTROL ROOM OPERATOR 1. Waste OK to Feed 2. Non-consecutive feed required. YES KO (circle onef{ 3. Date Waste MUST BE FED to the MPF: Calculate date by adding 89 days to the oldest container fr%nL 4. Maxlmurn feed temperature 1450 Degrees YES (TP (circle one) 5. Allowed in furnace with munitions YES (O (circle one) \=- Notes:1- lf waste cannot be processed by the MUST BE FED date it MUST be placed into permifted storage prlor to exceeding the 90-day storage limit.2- lf waste placed in a tray is from permitted storage the waste must be fed to the MPF as soon as possible not to exceed the next operating day.3. lf waste has no WT number use the date placed in tray to calculate MUST BE FED.4- Refer to TE-SOP- 092, Appendix K for list of combustible materials. .4 '_/ EnvironmentaJ Compliance Signature Control Room Operator Signature G. GOMPLETED BY GONTROL ROOM METAL PARTS FURNAGE OPERATORS 1. Date to MPF''(TO9):01 f^A-gob lriruoutExitAirlock' | ,tffi /gAg 2. Time in Zone 1 r s33 ,/ Cornments: ( unOr*t uJfllLt*T poEs Nor I t/4--p6 S h gt'r, P*rEA rtus olta*{ OL, '&ffi* FA)( COMPLETED FORM TO WASTE MANAGEMENT AT X7648. Fumace Opera Appendix F - 27rO:\FORMS\SOP\092-D 1 .R4C2 TOCDF WASTE TRACKING FORM U, N8be 5 APPENDIX F SECTION 2.0 SWDT SPIKING MATERIAL DATA F-28 O\ O (- ) (\ l &'= !> , o. +; q2 &FoBaIJ . . . o< fJ {XEn C)A. o, , -:CB .r i $<o#)d14bo . dH . t- t#o. a(- ) !.- \X? H (- / o OT ._ h .H )- r .g 9r E .s VcS t< (. ) € L) -go D >r 9 .- - s-HO )e# tr o - .= a cc ) (s - q {- ) 2o , l \v ja . \. , '( f J o) , ! EH (\ 5 L! ) ,q o (g (1 LH--a\o -r \J )- a r- a A\ J \- , /EE ts o t< +) 63 c) a a ,\ 0. ) ; - -, i . 1A\"Z r+ i 0rdF{taFE I Fi Fr { r)zfr {Ml- {F{aIF{zFd raaFr 1JF{ a tr { !6t! fr rcF] tr t' { axa()cC&E()C) I! .3€C)aFn '! , =0 . . l f ,g ) a l+ i r. . g o- = .= . g. z c/ ) ? ail:'::::u'*' -7 Ship Date: Customer Number: PICK TICIGT Customer P/O: 1 18873.US Contract: Order Number: 0301587 Tooele Chemical Disposal Facility I t 600 Starck Road Attn: Steve Bailey Stockton, UT 84071 Prepaid F.O.B. Delivered Description Page 1 of 5 2t22D0A6 2/1412006 2/24/2006 00 1 0228 4:44:27PM URS Corporation AtEr: Cheryl Cooper Post OfTice Box 201088 Austin, TX 78720 Ship Via: FEDEX FREIGHT Shipped Units Product 852.000 lb Lot 17523 Use ARSEMC (III) OXIDE, 99.2%pwe, -20 mesh, (Arsenic Triolide; Arsenous Acid), As2O" Left in Lot Location Conection 01583 t617.1 C1/L 852.000 lb t,267.255 Kg t SeU G f t, I packaged As: 40 x 21 .300 lb F1.31+ P- l' j2- Lot 0158316/l.l 9* )5-.15 lxlt,t'+U CFR49-HMI8I Proper Shipping Name: Arsenic trioxide Technical Name: Hazard class: 6,I ID: I.IN I 561 PG: II Label: Toxic Notes; MSDS# I5O ERG# I5I Packaging C onfirmati on Chemicals Free of Irregulari Warning Label: 5,7, 12 RQ: 0.454 kg 4rr* *l- J/.q3 ils Al. (Z /15 z/ .-? z /$t Zt .rf S /lj dt e Lll /b; SZa et , vz/As 7l - {7 /l's U . c{z /4s 2t. V3 /6s zi . Lfz /bs Visual Inspection by Plant Manager qdqignee frAv rsuar mspecuon oy rlaru vrana.q,er or oe$lFBee Performance Check pass " CL{ Eaii Noah ID No# fl,dl? T Container used Packed Per Packing List 8:l[il:, *i: l"':Y"' #f:T:'li * Net Wt 3.l.3ltxTare Wt LjJglB Gross Wt i.l , t4.)U5 (If more than one container used write weights belolr[ n Special Inshrrctions followed Ct:z- Drum Charge ,. N,1.* Shipping W Number of Pieces Shipped Completed by Verified by CADMITIM OXI .7% pure, -200 mesh, CdO .I*{f 366.s20 lb t4742 PAOK&fiOLD NTC Form QA-I5.01, Rev 3 PICK TICKET Customer P/O: I 18873.US Contract: Order Number: 0301587 Tooele Chemical Disposal Facility I 1600 Starck Road Ann: Steve Bailey Stockton, UT 84071 Prepaid F,O.B. Delivered Description Page 2 of 5 Worksheet Date: 2/24D0A6 Order Date: 2/14/20A6 Ship Date: 2/24nA06 Custorner Number: 0010228 URS Coqporation Aftr: Cheryl Cooper Post Office Box 201088 Austin, TX 78720 Ship via: FEDEX FREIGHT Shipped Units Product 8:23:52AM Lot Use Left in Lot Location Correction 0158481/1. r 366j20 lb I t514qft,t 196.628 Kg 57L 4,1 ,v ?' l't8 p - l,l8 Lot: 0 158481/1.1 Sx aa.bstg Packaged As: 40 x 9.163 lb In: CFR49-HM18I MSDS# 342 ERG# 154 WarningLabel:7,1? RQ: Proper Shipping Name: Cadmiurn compounds Technical Name: Hazard class: 6.1 ID: UN2570 PG: III Label: PG III, Marine Pollutant Notes: Dat@;;;W 168.120 Lot l r540 Use Packagin g C onfirmati o n Chemicals Free of Irreg uturi visual Inspection by Plant Manager or d'esigne e 5Z- , Performance Check pass G# , I;t Noah ID No # eo;29 ,, - f*. Container used I , Packed Per Packing List Completed by Verified by CHROMIUM (III) ACETATE, BASIC, HYDRATE, 99%pwe, powder, (Basic Chromic Acetate, Hydrate), Cr3(OH)r(OOCCFIo)r.xHrO Left in Lot Correction I x l+, +7kq -.Jlron,i- q.z?o /ls 7-zq//4 ?'zq//L; *u ?- ?-z?o /15 1'zf / /bs ?-z?o /h 7'z?r rts 7.4o /4, ?- z?/ /Ls o"ry;'168. 120 Ib Packaged As: Location NTC Form QA-15.01, Rev 3 0.021 Kg Appendix F - 31 PICK TICKET Customer P/O: I 18873.US ConEact: Order Number: 0301587 Tooele Chemical Disposal Facility I 1600 Starck Road Attrr: Steve Bailey Stockton, UT 84071 Prepaid F.O.B. Delivered Description Page 3 of 5 Worksheet Date: 2122DA06 Order Date: 2ll4D0A6 Ship Date: 2124D0A6 CustomerNumber: 0010228 URS Corporation Attn: Cheryl Cooper Post Office Box 201088 Austin, TX 78720 Ship Via: FEDEX FREIGHT Shipped Units Product 4:40:27PM 40 x 4.203 lb In: Lot: 0 158635/1 .1 CFR49-HM 18I Proper Shipping Name: Not Regulated Technical Name: Chromium (lll) Acetate, basic, hydrate Hazard class: ID: PG: Label: Notes: MSDS# 1196 ERG# Packaging Confirmation Chemicals Free of Inegulariry Visual Inspection by Plant Manager or Performance Check Pass Noah ID No * Q,flD_- ,,,,._ -Tared Container used I ,1) Packed Per Packing List C Container Was Clean, Undama Compatible with Contents.- , lrA tsn;w;'- l\D (If more than one container used write weights belpry) q Special Insmrctions followed \X9- Drum Charge U ./ k Shipping Wgight ,,4,,11 . 9l Ib* Number of Pieces Shi Completed by Verified by Warning Label: l0 RQ:qws n+' 5"o 862.240 Lot 14954 Use LEAD (rr) OXID .9% pwe, -325 mesh, < 5 rnicrons average, (Lead Monoxide), PbO Left in Lot Location Correction 4- 55L lL A- 355 //2 q-3sY/4//. 3s? /A V-7€Y/L ? i 358 lb ?' Tib /bq e 35t lb Lf _ bss /b ?'asb/b dresignee f 7- Fail 015845911.1 Srt 862.240 lb 514.091 Kg b-1.36 b-' l,3a- Lot: 0 I 5845 9ll .l J.e *ar,egg lx lLl ,o*1 L3ttrqst f t,t Packaged As: 40 x 2r.556 lb Appendix F - 32 NTC Form QA-15.01, Rev 3 PICKTICKET Customer P/O: I 18873.US Contract: Order Number: 0301587 Tooele Chemical Disposal Facility I 1600 Starck Road Atrn: Steve Bailey Stockton, UT 84071 Prepaid F.O.B. Delivered Description Page 4 of5 ol;:'H::"'' Ship Date: Customer Number: znazaa6 2n4t2006 2/24t2006 00 I 0228 4:40:27PM URS Corporation Attn: Cheryl Cooper Post Office Box 201088 Austin, TX 78720 Ship via: FEDEX FREIGHT Shipped Units Product CFR49-HM181 Proper Shipping Name: Not regulated Technical Name: Lead (II) oxide Hazard class: ID: PG: Label: Notes: MSDS# IOIO ERG# Packaging Confinnat ion Warning Label: 9 RQ:7y{fr chemicals Free of Ineg uturiryfrl Visual Inspection by Plant Managexr dgsignee fr(,,,, . . -__ Performance Check pass (f+ Eail_ Noatr ID No ?oi.l,f Pttt ffift Zl Mlb zl -(,"/6 L( '(2t/b z(.L{ lb Z(.Gr tb fze, G3 (b u,u? (b 4.00 ea Container used ), Packed Per Packing List Container Was Clean, Undamaged, and Compatible with Conten Drum Charge , N 'k,.,, Shipping Wei Number of Piecbs Shi Completed by Verified by Material Safefy Data Sheet Project No. 409 41869 .56520. 05 Appendix F - 33 L( -b* (b 4.;y/bZ- c* lb0.0000 0.00 PICK TICKET Customer P/O: 1 18873.US Contract: Order Number: 0301587 Tooele Chemical Disposal Facility 1 1600 Starck Road Attn: Steve Bailey Stockton, UT 84071 Prepaid Description F.O.B. Delivered Page 5 of 5 Wbrksheet Date: 2t22l2OO6 Order Date: 211412006 Ship Date: 212412006 CustomerNumber: 0010228 URS Corporation Athr: Cheryl Cooper Post Office Box 201088 Austin, TX 78720 Ship Via: FEDEX FREIGHT Shipped Units Product 4:44:27PM SPECIAL INSTRUCTIONS: Packaging instnrctions for Arsenic (II$ Oxide, Cadmiurn Oxide an*t-Jaallrl oxide: ar.{. (h*'*o;^(r,ii *ct*{*, b*sTurh.r |rc,l<'& Package in double 1.5 gallon liners wirh nryist ties and labeled with the product label on the outer bag. After the 40 bags have been packaged, place all the bags in a 55 gallon steel dnrm for shipment. Put Subcontract No. and Project No. on the bill of lading. Send a duplicate set of invoices to the same billing address, Attn: Nora Craig uSec,{ *r*f. oo/? vb ,1, PA*il* d4"&€zu Appendix F - 34 CERTIFICA TE OF AT{ALYS$ Code 14742 CADMIUM OXIDE,99.7% pur€, -200 mesh, CdO Lot 0158481/1 .1 C-admium NickeI Iron Lead Manganese 87.30% 0.0000% 0.0002% 0.0002% 0.0000% U U,nu[U^-*Ir.* LL( ll'tu,{ OG All values are maximum and may represent detection limits. NOAH cHEMTcAL Drv. NR66ttXigtf\_oLoGrES coRpoRArIoN 1 Noah Park San Antonio, TX 78249-34W lejennone 210-69f -2000 Fax 210-691-2600 O NTC Form 301, Rev 0 Page 1 of 1 - *"t t 0'r t{ .:Ddrc- floridienne chirnie s. a. CERTIFICAT D'ANALYSE / CERTIFICATE OF ANALYSIS CLIENT ICUSTOMER PRODUIT/PRODUCT No COMII{ANDE / ORDERNbT QUANTITE/ QUANTITY \p DATE fNXTEDITION / E}PEDITION I}ATD 3 Ib.Ot. O5 ' IDENTIF'ICATION : Drumt 6762 to 6937109rc5 ANALYSE CETMTQUE / CHEnflTCALANALYSIS (%) Fe Pb Ni Mn cdo cd 0.0002 0.0002 0.0000 0.0000 99.60 E?.30 Appendix F - 36 L$$F ot6RLl gt / L-[ Umicore USA O}ryDE DE CADMIT'M/ CADMIUM OXIDE of Jun e 2212005 tt00 Lbs L. DIRICQ Laboratory Chief Frrrrr l0/Q? CERTIFICA TE OF A|YAL YSIS C-ode 11540 CHROMILIM (IiI) ACETATE, BASIC, HYDRATE,99% pure,powder, (Basic Chromic Acetate, Hydrate), Cr"(OH)r(OOCCH")r.xHrO Lot Cr Ag AI As B Ba Be Bi Ca Cd Co Cu Fe K la U Mg Mn Mo Na Ni P Pb Pd S Se Si Sn 01s8635ir.1 23.79% < 0.5 ppm < 0.001% <1PPm <1Ppm 2.16 ppm < 0.5 ppm <1PP* 0.0012% 0.8 ppm < 0.5 ppm < 0.5 ppm 0.aa28% <4PP* < 0.5 ppm < 0.5 ppm <2pp* < 0.5 ppm < 0.5 ppm 0.a023% < 0.5 ppm .2 pp* <2pPm <1Ppm 0.014s% .2 ppm .2 ppm .2 ppm All values are maximum and may represent detection limits. NOAH cHEMTcAL Drv. NpfpildffiIp{ol-,ocrEs coRpoRArroN 1 Noah Park San Antonio, TX 78249-3419 ldfephone 210-691-2000 Fax 210-691-2600 NTC Form 301, Rev 0 Page I of 2 CER TIFI CA TE OF A|YALYSIS Code 11t10 CI{ROMIUM (IiI) ACETATE, BASiC, HYDRATE, gg% pure,powder, (Basic Chromic Acetate, Hydrate), Cr^(OH)r(OOCCH.)r.xHrO Lot 0158635/1.1 < 0.5 ppm < 0.5 ppm < 0.001% < 0.5 ppm .2 pp* < 0.5 ppm 1,.62 ppm < 0.5 ppm Sr Ti U V W Y hl Zr r\fu(' \et,; cLo^isr.--'.--/ LL,{, r ./.*r DG All values are maximum and may represent detection limits. NOAH cHEMTcAL Drv. NRd6[il&qrilN_oLocIES coRpoRArIoN 1 Noah Park San Antonio, TX 78249-3ilt9 ]{enhone 210-691-2000 Fax 210-691-2600 NTC Form 301, Rev 0 Page 2 of 2 CERTIFICA TE OF AT{ALYSIS Code 1752i ARSENIC (IID OXIDE, 99.2% pwe,-20 mesh, (Arsenic Trioxide; Arsenous Acid), AsrO. Lot 01 583 t6ll .l Assay (AsrO.) Assay (Sb2O3) 99.18% a.54% /\fu( \ gf* r* C{,"-,*isf\J L4A6ro(t All values are maximum and may represent detection limits. NOAH cHEMrcALDfv. NBAIIf,fiGr#\OLOGTESCORPORATTON 1 Noah Park San Antonio, TX 78241-I{fnT$tle6one 210-691-2000 Fax 210-69r-2600 NTC Form 301, Rev 0 Page 1 of I c, { O ctfrD*An. CERTIFICATX}DE SIS \^$* orB"b3\b /\-l IRIOXIIX) DE ARSEIYICO lntn:1 AggAY (AraOr) gg.ltoh ASSAY (Sb0s) 0.54o/o E"Q, EnrtqueZu[b u.rtm{o,r....}rr.QprulluslxlAL!ilrrn$."*rtfrl&"P*.oo*,rr)ti.r.u5I QtltN.?-7ttl)otlx(tt)3.srsr CERTIFI CA TE OF AATAL YS IS C-ode M954 LEAD gI) OXIDE, 99.9o/opwe, -325 mesh, < 5 microns average/ (Lead Monoxide), PbO Lot 015 84591r.1 PbO, Assay Pb FerOo ee.e5% 0.0s% a.a002% A*L( \Cnr* 0t,,t^i5+_),Z4,Yl*r oce All values are maximum and may represent detection limits. NOAH cHEMrcALDrv. NR6&tEfirIN_oLocrESCoRpoRArroN 1 Noab Park San Antonio, TX 75249-3419 ft[ephone 210-691-2000 Fax 210-691-2600 NTC Form 301, Rev 0 Page 1 of I L-eAd Cx) o p,6e-I o Appendix F - 42 Hammond Lead Products A Division of H A mmond Group, lnc, ,SO-9001 Certified \,$Ftt srsB.t61 /(.t 10 S. Grosstown Rd.Tel 610-327-1400 Fax 610-3274790Pottstown, Pa. 19464 Certificate of Ana lysis Customer: Noah Technologies 1 Noah Park San Antonio, Tx. 78249 fax to 1-210-691-2600 Material Shippers # P.O. # UHP 100Y Litharge 151486 Net Weight Date Shipped Test Results 2,000 lbs 15M59 02t13/06 Production Date Skid#o/o Pb %PbO %Fe2O3 A.D. 02t01/06 0.05 99.95 0.0002 31 .1 (40 bags) USL LSL 0.10 N'A N/A 99.90 0.00{0 N'A g/in3 33 26 Authorized Signature:QC Department o a(r8 o=orlJ 1 APPENDIX F SECTION 3.0 DPE SUIT AIIALYSES DATA MPF SWDT REPORT - Rev. 0 Appendix F June 9,2006 TOCDF F-43 9^, .J APPENDIX F SECTION 3.1 DPE Suit Component Determination MPF SWDT REPORT - Rev. 0 Appendix F June 9,2006 TOCDF F -44 On the morning of January I l, 2006 a team assembled at building 4057, in Area2, to collect samples of DPE material for characterization purposes. DPE suits, used for training purposes, have been collected from other demil sites and are stored in this warehouse. Five suits were selected from this collection and weighed. All five suits consisted of 30 mil DPE material. Four of these suits were large sized and the remaining suit was an extra-large. Upon weighing the complete suits the gloves, face shield, and air connector were removed from each suit and weighed separately. All weights are recorded on the attached table. The material from these five suits has been combined in to 3 sets of samples. Each set consists of a sample of the gloves, face shield, and DPE material. Samples were also collected from new material purchased to represent actual DPE suits. This material is stored on rolls. Three sets of samples were collected from this new material. In total l8 samples have been prepared and shipped to Severn Trent Laboratories for analysis. The samples have been numbered as follows: la New DPE Suit material 1b New Glove material lc New Face Shield material 2a New DPE Suit material 2b New Glove material 2c New Face Shield material 3a New DPE Suit material 3b New Glove material 3c New Face Shield material 4a Used actual DPE Suit Material from suits 7 andZ 4b Used actual Glove material from suits 1 and2 4c Used actual Face Shield material from suits I and2 5a Used actual DPE Suit Material from suits 3 and 5 5b Used actual Glove material from suits 3 and 5 5c Used actual Face Shield material from suits 3 and 5 6a Used actual DPE Suit Material from suit 4 6b Used actual Glove material from suit 4 6c Used actual Face Shield material from suit 4 MPF SWDT REPORT - Rev 0 Appendix F .lune 9,2006 TOCDF F-45 Table F-3-l lists the weights of each component from the suits. This data was used to calculate an average weight percent (Wt%) of each suit component. The weighed samples were then used to prepare the samples listed in Table F-3-2 and the analyses that were requested for each sample. These samples were analyzed and the results are shown in Table F-3-3. There was little difference in the analyses results for the new materials from rolls and the actual suits that were used in the SWDT. Therefore, overall average compositions of the suit components were calculated and shown in Table F-3-4. This information was used to calculate the data shown in Table F-3-5 which shows the composite chlorine, ash, and heat of combustion for a DPE suit. The analytical data on the analyses of the DPE suits are found in Sections F-3.2 through F-3.9. MPF SWDT REPORT - Rev 0 Appendix F .lune 9,2006 TOCDF F -46 DPE Suit Materials.xls Data Evaluation TABLE F-3-I. SUMMARY OF DPE SUIT MATERIALS Appendix F - 47 Suit I Size Large Suit Total 5896.67 gram New Gloves Air Connector White Suit Material 5012.67 sram 5896.67 sram Suit 2 Size Larse I 3.5 lbSuit Total 6123.47 New Gloves 78 gram 286 sramAir Connector 5267.47 gramWhite Suit Material 6123.47 wam Suit 3 Size Larqe 13.5 lbSuit Total 6123.47 gram New Gloves 288 sramAir Connector White Suit Material 5255.47 6123.4'7 sram Suit 4 Size Extra Larse Suit Total 6350.26 gram New Gloves Air Connector White Suit Material 5464.26 erams Total 6350.26 sram Suit 5 Size Suit Total 5896.67 5l 0 gram New Gloves Air Connector White Suit Material 5024.67 5896.67 gramTotal Average Results Average Standard Deviation Visor 8.3 0.37 New Gloves 1.3 0.02 Air Connector 4.8 0.r0 White Suit Material 85.6 0.48 Sil It2006 \oNtr ) I tuX '- F r oo Es C)A.O. 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H ' [q ' :5=t OONI nca $ol '' " " " * -r r - . - - h Y - '{ r l J " ' r ' - . .t - ' . .. .' . . i ' . ' _ ' .r r . . . . . r i . :: i t : : : . :c i -. .. . 4 J iH : : i : 6 9 . 17 : . ' . . ' E i i .: : . . . : i = . 'Hi: c g .t ' I _ Of-\oo\ c1cncn cac! rn NN \?O c!O f- . \oc' 1 Oi qc. . l q\oN rnO Ov1O (n (. JO ooc1O o\ o. lO OC\OqO c\o\ i tni Oc1O co$ ooo\ (nC\ lO qf- i- . ' . . ' . ' . - l 'r | l " ' . ' ( l ) 5: ; : ; ; : f i : .' . ' . ' . . ' . . ' h { .. : . : . : : : 4 . O\f , oooi a. ;$ .i | CNO .. ( r . . . : : E :: 9 ' . :X '. \ Y ' - . ' . v - [, = 1 . . . . . . I ff i :q * : .i t ) . '. . . . ' . . ' . . . H . ': o i: E :> :: : r r i :i 5 :: i D 'r i i i a . . ' f L . l: , i .' : : G .v . . ' . ' H :: . . : : > l OOot qcn \n=q 'H ' . '. ' r R " .. r ! t i .' - . .' . I . ' 't - ' .E ! . (n ' .: . . . . : . : . : . . ; i . .. . - . - ' . - - . r r r . .. : . . ' . ' . ' . . ' r - H ' it s . . . . r . . . '. I . . . . F . '. r. 1 ' . . G) .i - - . ' . " . ' . - uJ . : . : c S . . .. . 1 F ( Z; O\o\ oJNC. ) \ocl \n CNN O\qO Oo. lO t^ ) c- | aO qN ooO(- N \nO vlO tr ) c. lO f- . \o .f , cni ONO<?O f-\oi \ni Ocr lO qrn oood \nc!O \c. ) oo aif h :. a 1 . 'H . ' '. ' . f r . ' .. - ." ' i - ' . .. x ' . .. ): ( ' . :: c l : '. a ) , . O\f , ooO. =qc. l$ \f , .f , cnO ei l: [ f 'b Y 'r - ' Im ; : ; .5 .. . .. . ' i i a 'q 1 :; 6 s >: : : I i :. : o : -. q} j- . . .' . { i i ' 'i ' . H : : : ' : c g \Y . .r " t . .: - : ' . . : . . . . E ca 9co (- l .: . . . . : . . . . . . ; ; i .. : . . : .: . : . . - E \ I .. . . ; , . . ' - r ' H . ,- . . . . . a . . .. t 1 . ' . . ' . . - :E . : : : g ) fi f ; . .: :. i . . . . . . L i i t .. : . . . : . . : E Or. a ) \o\ oq cA rn o\ c\ O9O c. !O O.F- c\ OO qN 9OC. . . l \nO O(nO (nc!O oo i Nc1O ONOqO \ni Oc1O q CNoo \nC. tO t\o f- .4 . . .-:o '{ i f '. i i . ) _, < l !) ln0 l el )) (d l ao )- id(l ) >T { !+ { L()bo Fl - { .Oo\t,Ba UIVbI tIL.U)oq)-6-Li(r )-6:)q) \= r2, o .9C)a I$m h(. )m oOc0 'o dL) troU CO -ooQ l- (0)9-a-oQ €CS()J 0)ao) 63b(d lr lz LoL<C) Ea (, ) J4()z c)C) (/ ) l- r () (/ ) (cF t- . r ECC (o ()N yOg\+.(toFat t- (oU '. I' .' ) n ' .. H . c\ i .4 . - - .. x . :6A. O\ O () C \ t- { - {- )Y6 3 Lr { l- ( qz &FoBU) lL (Fi |< - {z, I tJ . .xE' - 1< tl ^ ) a)A.A. aFrzFr lzo0. ( 13aoUFl- {)aFr l R. (A-trcUtrd a \f I ra T tr tr l l. ]FAFr vxav )e8 , $3 q) r! i! A< A- oa O=l :O N9 \n\?oo .: c g ?l:l l : :. : c l .t j :. 6 u Fr i lt :: a : ,I . '_ ' t i " "\ - / :. r h YH . ).< . . fr :: s ) q) ilFr '. . 4 E :. 0 ) if \ .l - .. : . 'E t .. v .' { r *a c1o\ c' - ) o\ \?O CO i () . :: 0 f , :6 3 : .J l . . . . .i Y . ,. o : :> : (: : C. ) f- . oooi \C\ -f , rnCAO .' A ' . .l r { . (n ' t \oct )O \oq l- . c1 #.. 6 1 . .' . ' t . ' . ' . .. 4 :. : . ! D . .' { r r . .' . ' I . ., \ r Y :t t ' i ( :a.q ) :. : . > :. : . o-.f h \v '. ' * . :' : ( ) .4 . ht ooO\r cact lO CA 'i f l '. ' . 9 r 1 ., * r .a:G ) : :E O -: c s : . :I i . : :( ) : . . L. . .* . ' . (: r\c\ a\ ,r ?CA rnoj o\ \ \q clN oqC\ OqO f- . -q | qN OqO OqO CA\N OqO OqO OqO CJNCO O OqO q\nc' 1 Oq OqO qCA v? \o Oq oqao .- , :e ( .i i :: l t :: ( } '. { r } :' : . E ( I '. 8 ^ ; :: r + .- '. i i ' ,. . . * .a .> . . :: { ) if r .l = t ,. . , r .l t .. v '. { iV) q. . ! \o f- . rn C. . l .1\o OqO co\O v? \o-t OqO O<?O fr .c. i OqO OqO O<?O \f , c. lO CAO O(>O,_ { $cl OqO O nN f- . V?O OqO v?N o: :u xG: . :I i : 'g ) : ' .' * . ' . <: , Of- . \ool =qc\ CA \o,r ; ONc\ t O\?O OrnO N\oCN OO qN c\C\ |' n Ov? rnoJO tn\O coOc1O ONOqO f- .9 \nO On [- - \oo |' nolO 9\o\o -o{- )m()6bo s+Jd+JoFC' (4t<o() \oo\+,a a!Eal At- (-U) q) (r ) -sn-LU) -cq {r aq) \-a l- <tr ts { oH+J o-1()V) t- i Ft<dm Fh$- . ()m o$-om F)tsL, }dU t- ( F1trot<Q d.oo(J S- i ()a-a-oU E63C) -l (. )aC) }. { 63o0 1- 1 cC I \< ra t<OL<C) k<z C) J4Oz )()C)a L<()a 6sF F (-dd ON .A ' . ' . I* t d() #FJ - ' ( L. ( (. )bo FJ < o TABLE F-3-5. AVE,RAGE, DPE ST]IT COMPOSITION Appendix F - 52 DPE Suit Materials.xls Average O sllt 12006 o o o APPENDIX F SE,CTION 3.2 Laboratory Narrative o MPF SWDT REPORT - Rev 0 Appendix F June 9,2006 TOCDF F-s3 STL Knoruille 5815 Middlebrook Pike Knoxville, TN 3792t Tel: 865 291 3000 Fax: www.stl-inc.com STL 865 584 4315 AT.IALYTICAL REFORT DPE SUIT AI{ALYSES Lot #t H5B200154 Craig Yor:ng BGE.G Def ense Materials, Inc . 11500 Stark Road Stockton, IIf 84 071 SBVBRN TREIIT I,ABORATORTBS, INC. March l..7, 2OO5 Appendix F - 54 Kevin S - Woodcock Proj ect Manager Severn Trent Laboratories, lnc. A}.IALYflCALMETHODS W 85820 0154 PAIU\METER AIIALYTICAL METHOD Ash Content ASTM D482-00a Heat of Combustion D5855 ASTM D5865-00 Mercury in Solid Waste (Manual Cold-Vapor) SW845 74?1A Total Chlorine KNOX WC-0015 Trace Inductively Coupled Plasma (ICP) Metals SW846 50108 References: ASTM Annual- Book Of ASTM Standards. KNOX Severn Trent Laboratoribs Knoxville, Facility Standard Operating Procedure Sw845 rrTesE Methods for Evaluating Solid Waste, Physical,/Chemical Methods'r, Third Edition, November 1986 and its updates. Appendix F - 55 SAMPLEW H5B2 00154 WO # SAMPLE# CIJTENT SAMPLE ID SAMPLED SAMP DATE TTME HXQ1X 0 01- HXQ2D 002 HXQ2F 003 HXQzH 004 HXQ2J 00s HXQ2K 005 HXQ2M 007 HXQzP 008 HXQ2Q 0 0 9 HXQ2V 0 r- 0 HXQz0 0r-1 HXQ22 01,2 HXQ24 013 HXQ25. 0r4 HXQ2B 0 Is HXQ3D 01- 5 HXQ3 E 0 r-7 HXQ3F 0r-8 NOTE (S) : SA}4PLE 1-A SAIUPLE ]. -B SAMPLE l- - C SAMPLE 2 -A SAMPLE 2-B SAMPLE 2 -C SAMPLE 3 -A SAMPLE 3 -B SANIPLE 3 _ C SAI{PLE 4 -A SAIvIPLE 4 -B SAMPLE 4-C SAMPLE 5 -A SAMPLE 5 _B SAMPLE 5-C SAMPLE 5 -A SAMPLE 5 -B SAMPLE 5-C SUIT MATERTAL GLOVE MATERTAL FACE SHIELD IvIATERIAL SUTT MATERIAL GLOVE IvIATERTAL FACE SHTELD MATERIAL SUTT MATERIAL GLOVE MATERIAL FACE SHIELD MATERIAL SUIT MATERIAL GTOVE MATERIAL FACE SHTELD MATERTAL SU]T MATERTAL GLOVE MATERIAL FACE SHIELD MATERIAL SUIT N{ATERTAL GLOVE MATERIAL FACE SHTELD MATERIAL oL/1,L/06 o9:00 w/ti,/06 o9:oo oL/tr/ 06 09:00 0L/LI/ 06 09:00 oL/1,L/06 o9:oo fi/1,1,/ 05 og: o0 oL/1,1,/ 06 o9:00 oL/ar/ 06 o9: oo oL/:-:-/ a6 oe: oo oL/tL/ 06 oe: oo 0L/Lr/ 06 o9: o0 0L/1r/ 06 09: 00 oL/rL/ 06 o9: o0 aL/ tL/ 06 09: 00 oL/tL/ o6 o9: oo 0L/rL/06 09:00 oL/1,L/ 06 o9: oo oL/Lr / 06 09 : 00 - The analytical rcsults ofthe samples listed above are presented on the following pages. - All calculations are performed before rounding to avdid round-offerrors in calculated resulrs. - Results noted as "ND' were not deteccd al or above the stated limil. - This report must not be reproduced, except irr full, wihout the written approval ofthe laboratory. - Results for the following parameters are never reported on a dry rveight basis: color, corrosiviry, density, flashpoint, ignilability, layers, odor, paint fiher tesl, pH, porosity pressure, reactivity, redox potenlial, specinc gravity, spot lests, solids, solubility, temperaNre. viscosity, and lvelgbt. Appendix F 56 PRG'ECT NARRATTVE H68200164 The results reported herein are applicable to the samples submitted for analysis only. This report shall not be reproduced except in full, without the written approval of the laboratory. The original chain of custody documentation is included with this report. Sample Receipt Custody seals were not present upon sample receipt at STL Knoxville. Quality Control Unless otherwise noted, all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requitements. Metals Prior to sample preparations for "Total Metals Content," five (5) gram portions of the suit materials were slowly ramped up to 500oC and held for 2 hours to ash organic binders. Therefore, metal results represent five (5) grams of the original material, and ash content was determined by percent (%) difference. A batch matrix spike/matrix spike duplicate was analyzed using a sample from this lot. The recoveries were outside control limits for antimony, arsenic, lead, selenium, silver, tin and thallium. However, the laboratory control sample showed acceptable results indicating that the analysis was in control. The matrix spike/matrix spike duplicate results are, therefore, attributed to matrix effects. Interference check sample result for barium is outside control limits ft 1 times the reporting iimit from zero) due to contamination. The validity of the associated sample result is not affected. STL Knoxville maintains the following certifications, approvals and accreditations: Arkansas DEQ Cert. #0i043-0, California DHS ELAP CerL #2423, Colorado DPHE, Connecticut DPH Cert. #PH-0223, Florida DOH Cert. #E87177, Georgia DIIR Cert. #906 (SDWA, expires 6124105), Hawaii DOH, Illinois EPA Cert. #000687, Indiana DOH Cert. #C- TN-02, Iowa DNR Cert. #375, Kansas DHE Cert. #E-10349, Kentucky DEP Lab ID #90101, Louisiana DEQ Cert. #03079, Louisiana DOHH Cert. #LA030024, Maryland DHMH Cert. #277, Massachusetts DEP Cert. #M-TN009, Michigan DEQ Lab ID #9933, New Jersey DEP Cert. #TN00l, New York DOH Lab #10781, North Carotina DPH Lab ID #21705, North Car.olina DEHNR Cert. #54, Ohio EPA VAP Cert. #CL0059, Oklahoma DEQ ID #9415, PennsylvaniaDEP Cert. #68-00576, South Carolina DHEC Lab ID #84001001, Tennessee DOH Lab ID #02014, Utah DOH Cert, # QUAN3, Virginia DGS Lab ID #00165, Washington DOE Lab #CI20, West Virginia DEP Cert. #345, Wisconsin DNR Lab ID #998044300, US Army Corps of Engineers, Naval Facilities Engirrering Service Center and USDA Soil Permit #5-46424. This list ofapprovals is subject to change and does not imply that laboratory certification is available lor all parameters reported in this envirdrypotdixr$le data report. 57 PRq'EICT NARRATIVE H68200164 The holding time for mercury for all samples associated with this lot was expired upon sample receipt, Sample analysis was performed outside the holding time as per client request. Y{eU*s Ash Content The ash content of the samples was determined using SOP number KNOX-WC-0013 (based on ASTM Methods A4422,D+82, and E830). A ten gram aliquot of sample is fired in a pre-tared crucible at 7 50o + 25o C in a forced-draft muffle furnace. The total weight of ash residue and the crucible is measured on a 4-place analytical balance, and the residue weight is determined by difference. The ratio of the residue weight (mg) and the initial sample weight (kg) is used to calculate the ash content of the sample. Gross Calorific Value The heat of combustion (gross calorific value) of the samples was determined using SOP number KNOX-WC-0010 (based on ASTM Method D5865 for solids and ASTM Method D240 for liquids). A waste feed sample is combusted in an oxygen bomb that has been placed in a bomb calorimeter. The energy released during this combustion process is captured in the calorimeter, and the temperature rise of a water bath surrounding the bomb is measured. The temperature rise is proportional to the heat liberated during the combustion in calories. The gross calorific value is calculated from the temperature rise, the sample weight, and the calibration coefficient of the calorimeter. Certain extraneous sources ofheat are assessed, and the effect ofthese heat sources is accounted for in the calculation, as well as the affect ofvarious accelerants that are added to enhance combustion of the sample. The gross heat of combustion is calculated in units of callg using the following equation: STL Knoxville maintains the following certifications, approvals and accreditations: Arkansas DEQ Cert. #01043-0, Califomia DHS ELAP Cert. #2423, Colorado DPHE, Connecticut DPH Cert. #PH-0223, Florida DOH Ce*. #F,8717'7 , Georgia DNR Cert. #906 (SDWA, expbes 6124105), Hawaii DOH, Illinois EPA Cert, #000687,Indiana DOH Cert. #C- TN-02, Iowa DNR Cert. #375, Kansas DHE Cert. #E-10349, Kentucky DEP Lab ID #90101, Louisiana DEQ Cert. #03079, Louisiana DOHH Cert. #LA030024, Maryland DHMH Cert. #277, Massachusetts DEP Cert. #M-TN009, Michigan DEQ Lab ID #9933, New Jersey DEP Cert. #TN00l, New York DOH Lab #10781, North Carolina DPH Lab lD #21705, North Carolina DEHNR Cert. #64, Ohio EPA VAP Cert. #CL0059, Oklahoma DEQ ID #9415, Pennsylvania DEP Cert. #68-00576, South Carolina DHEC Lab ID #84001001, Tennessee DOH Lab ID #02014, Utah DOH Cert, # QUAN3, Virginia DGS Lab ID #00165, Washington DOE Lab #CI20, West Virginia DEP Cert. #345, Wisconsin DNR Lab ID #998044300, US Army Corps of Engineers, Naval Facilities Engireering Service Center and USDA Soil Permit #5-46424. This list of approvals is subject to change and does not imply that laboratory certification is availabte for all parameters reported in this envirA@txn$le data report. 58 PRqTECT NARRATTVE H68200164 e (gross) = (atEE) - (e' + e' + e' + eo )] m Where: Q (gross) : gross calorific value at constant volume as determined, callg. EE = the heat capacity of the calorimeter, call"C. At = corrected temperature rise as measured by the calorimeter, oC. o1 = Correction for heat of formation of nitric acid in calories, calculated by the calorimeter based on the energy released by the sample. az : Correction for sulfur, which is usually 0. e3 : Correction for fuse wire. e4 = Correction for spike addition that is calculated by the calorimeter using the spike weight benzoic acid equivalent (grams) times the benzoic acid heat of combustion (6318 callgram). m = mass of the sample, g. The results are converted to Btu/lb, as necessary using the following conversion factor: 1 Btr:/lb : 1.8 callgram Total Chlorine The samples were prepared for total chlorine using SOP number KNOX-WC-0O16 (based on ASTM Method E442 and SW-846 Method 5050). The sample is oxidized by combustion in an oxygen flask at atmospheric pressure or a bomb containing oxygen under pressure. The liberated halogen compounds are absorbed primarily as halides in a sodium carbonate/sodium bicarbonate buffer solution. The combustion products are collected by repeated rinsing of the combustion apparatus, and analyzed by ion chromatography in accordance with SOP KNOX-WC-0005 (based on SW-846 Method 9056). The results are calculated using the following equation: C:C.o*xVro.xlooow STL Knoxville maintains the following certifications, approvals and accreditations: Arkansas DEQ Cert. #01043.0, California DHS ELAP Cert. #2423, Colorado DPHE, Connecticut DPH Cert. #PH-0223, Florida DOH Cert.#E87177, Georgia DNR Cert. #906 (SDWA, expies 6124105), Hawaii DOH, Illinois EPA Cert. #000687, Indiana DOH Cert. #C- TN-02, Iowa DNR Cert. #375, Kansas DHE Cert. #E-10349, Kenhrcky DEP Lab ID #90101, Louisiana DEQ Cert. #03079, Louisiana DOHH Cert. #LA030024, Maryland DHMH Cert. #277, Massachusetts DEP Cert. #M-TN009, Michigan DEQ Lab lD fl9933, New Iersey DEP Cert. #TN00l, New York DOH Lab #10781, North Carolina DPH Lab lD #21705, North Carolina DEHNR Cert. #64, Ohio EPA VAP Cert. #CL0059, Oklahoma DEQ ID #9415, Pennsylvania DEP Cert. #68-00576, South Carolina DHEC Lab ID #84001001, Tennessee DOH Lab ID #02014, Utah DOH Ce(. # QUAN3, VirginiaDGS Lab ID #00165, Washington DOE Lab #CI20, West VirginiaDEP Cert.#345, Wisconsin DNR Lab ID #998044300, US Army Corps of Engineers, Naval Facilities Engireering Service Center and USDA Soil Permit #5-46424, This list of approvals is subject to change and does not imply that laboratory certification is available for all parameters reported in this envirdspGnditrSle data report. 59 Where: PRq]ECTNffi H68200L64 concentration of analyte in the sample, rng/kg. concentration of analyte in the combustate, mglL. total volume of combustate, L. weight of sample combusted, g. C C.o* Vro* w STL Knoxvillc maintains the following certifications, approvals and accreditations:, Arkansas DEQ Cert. #0!043-0, Califomia DHS ELAP Cert. #2423, Colorado DPHE, Connecticut DPH Cert. #PH-0223, Florida DOH Cert. #E,87117 , Georgia DNR Cert. #906 (SDWA, expires 5/24105), Hawaii DOH, Illinois EPA Ce(. #000687, Indiana DOH Cert. #C- TN-02, Iowa DNR Cert. #375, Kansas DHE Cert. #E-10349, Kentucky DEP Lab ID #90101, Louisiana DEQ Cen. #03079, Louisiana DOHH Cert. #LA030024, Maryland DHMH Cert.#277, Massachusetts DEP Cert. #M-TN009, Michigan DEQ Lab ID #9933, New Jersey DEP Cert. #TN00l, New York DOH Lab #10781, North Carolina DPH Lab lD#zl70s,North Carolina DEHNR Cert. #64, Ohio EPA VAP Cert. #CL0059, Oklahoma DEQ ID #9415, Pennsylvania DEP Cert. #68-00576, South Carolina DIIEC Lab ID #84001001, Tennessee DOH Lab ID #02014, Utah DOH Cert, # QUAN3, Virginia DGS Lab ID #00165, Washington DOE Lab #C120, West Virginia DEP Cert. #345, Wisconsin DNR Lab ID #998044300, US Army Corps of Engineers, Naval Facilities Engireering Service Center and USDA Soil Permit #5-46424. This tist of approvals is subject to change and does not imply that laboratory certification is available for all parameters reported in this envirdppardhu$lc data report. 60 APPENDIX F SECTION 3.3 Chain of Custody Data MPF SWDT REPORT - Rev 0 Appendix F June 9,2006 TOCDF F-61 t+6 BLoo lt1 Jb EG*G sampte/Anatysis Management Forrn ffiBeffigflEe 57 o 5B &EGidGi sample/Analysis Management Form #FffiAreEflg 59 g&eara Sampte/Anatysis Management Form #mAgmgg This Document is a Record 60 &EGatr Sample/Analysis Management Forrn #FffieffiefiEe Environmentat Review ppen 65 67 "k EGaa sampte/Analysis Management Form ffiB&reflEe 62 &EEiaG sample/Anatysis Management Form €FffiAffigEHe Environmental Review This Document is a Record 63 &EEiaG sampte/Anatysis Management Form #FffiAreEHe Environmental a^t" I /, /.,f *#f;l.:li.X$.*;,iilVEr.$S,:iii:)ft,*s*fliit$i;1i.r$.,i.;*5*]$,iizi..rl{,ti1.?.l!&}gS:iff;;t:rt*i!ffipegEt -*P,,f,J np19,.!i*R,lJS"g"tl.9"F*.*,,.krP;R.1[*PJ,*h'*U Sampred w,CL;, /y'[.,1t . o.r.,'./tr,/a,( rime: //)aa BpARete"se*i 2/./ sampling Equipment: se@" coLlwASA GLAss TUBE scooP THIEF vALvE TRTER OTHER: Sample Type: g€ coMPoslTE Sample Grid: N/A SQUARE TRIANGULAR oTHER: DD 2271 altached: YES AF/DD 1222 allached YES 13 Cornments: ,U /i OPCW Sample Seal # (if applica Ar'il: ,?b Preserva tivetsl: il/ ^t/ Relinqueshed by:Date Time Received -bv: n Date Time tr Comments/-YbA/d ^ (tr 8*{1,-^,aJ-lgdn or0o,'<,)*--'\ lln,,-lL /mtD thffl F,d e*-^ Ror (#t-l t(A/tiia\{+Tiolc o1w ): PRP-OP-021-O1a.R5 This Document is a Record 68 64 db EEiaEi sampte/Anatysis Management Form #&BAffieflHe Environmental Review a^tu,., !/, /a/ This Documenl is a Record 65 *t EEidG sampte/Anatysis Management Form q&ffiAreEHe Environmental Review ppen 70 66 & EEiaGi sampte/Analysis Management Form #BArcEEe Environmental Review 67 & EEiaEi sampte/Anatysis Management Form #effiAffigfiEe Environmental Review ppen 72 6B *foeooa Sampte/Analysis Management Form #mAgreHHg This Document is a Record 69 &EEiaEi sampte/Anatysis Management Form #FffiffiffigEHg Environmental Review 70 &EEiaG sampletAnatysis Management Form #FffieffigEEg Environmental Review This Document is a Record 7t &EGiaG sampte/Anatysis Management Form #ffieffieilHg Environmental Review Sampled by:Date: ..t /rrL / Time: /.?ez BpA Retease #: rt/// sampling Equipmenr: aQEglst- coLrwAsA GLASS TUEE SCOOP THIEF VALVE TRIER OTHERI Sample Type: @ coMPoslTE Sample Grid: N/A souARE TRIANGULAR oTHER: OD 2271 attached: YES @ OPCW Sample Seal # (if applicabley //rf DD 1222 altached: YES l',€t comments: /4*Preservative(s), ..{// rf Commenls PRP-oP-021-01 a.R5 This Document is a Record 72 "k EEiaGi sampte/Analysis Management Form #FffiAffieHHg 73 "t EEiaEi sample/Anatysis Management Form #FtsAffigHHe This Document is a Record 74 #b EEiaEi Sample/Analysis Management Forrn Environrnental Review Dat" ) /"/e/ o \pl i-l -glin \ol t=tHuiifd c)iTi SUE,,, F] *r)40\\13 )-{aOlelFIstEr)lUIEE) I Fr ^ aatl( {r)Etsu'a n& ErI !-]Iarl #lrclJlJI -rXIctzlMl,llE-lal U (/\./ aa {r) Fts() IE-U F.o +)UE R EB E €.E S '6 (J-()E*HE tr g Li tlrt F{E=OOO'<{-') E E'5;,' O EEESEuIcr€ t.l! or- B0 trl Fi t-( F{ F{ F{ F{Etrt]Et]ETl il J H cB tr A. >a)-rq)F fil N I ll a. E C)F L{(l) ooU EN fI F.ugir oiYk r-tgEszzo clt! (J .tf t rf fttrl o)I1, E o) F{ E 0)E8 F.ru(t) 'o -b+r (+{O l-{trgEtrtrOtr SEo LJ {-) ()oU rLao cS >{ (r) 0) -o(d Lr(l)^ ERctdP l-.tr ltOFo,\o.lREfrEO c\l(naoAn '-r -; ao H N(J .H: n ;E,F \O-trF{;d'= \o i?p EpX gEs 0() l-. F-. H (.) -'lb Ey7 i o X<*.H5o I clcaE EO&g> L<o E )-a 6d k C) oo() go +JodP q) u)(l) l{P. ct) o0q)a "(,oC\'+raAHtootr(,) cut{+..|()ti ts8 6. C) 0)o 0,)I< UoU q) iJ o-d C) (n C,)o g. E(d cD 0) {.'q{o G, C)k C) Fap c\.{-)o CB F{ 13 (,) oo(l) t-{ C,'L.(l) d s Hoo q) O. L. L{ cda o) E q-{ o CIJ 0.)t-{o ;80 l.r({ U)(A C)o{) Hq-. 0) )-. l.{o o cS .JE 3t)q) l-. l<.o J4o(.) o)o E o &J A-u5F SH <8"oo (a \OE\O]EF{O tJ) ma)c.)3 ro .9 pag) -9frA. 'EEairi q 6=. bHEStooE8s5tfr{ O{ s r.*)Od+) F. al-{ o) sl+r )-{oo b0 &A. ,E:a o oH ,-i \oO O cO ooq oo d\oNo q o;+', c'So o G, oov)a oo H ooq) & &) O. t{ C\,(A o APPENDIX F SECTION 3.4 Analytical Summary Sheets O F-81TOCDF MPF SWDT REPORT - Rev. 0 APPENDIX F SE,CTION 3.4.I Miscellaneous Tests Results MPF SWDT REPORT - Rev. 0 Appendix F June 9,2006 TOCDF F-82 EG8(i Defense llaterials, Iu.c- Client Salqrl-e ID: SAMPLB 1-A SIIII IBTER.IAL General Cheuristry Lot,-Saq)le #,..: II5B200154-OOL ltork Order #...: HXQ1X rriatri:r- - -: SOLID Date saryrled.--: oL/Lt/06 Date Received- -2 02/20/06 28 RESULT RL UNITS METHOD PREPARATION- PREP A}IAIYSIS DATE BATCH # 50200 28O rns/kg iqs'firr D482-OOa OZIZA-OS|O1106 6059310 Dilutiou Factor: 1,4 MDL... ..t 7!,4 PARAIVIETER Ash Content Gross Calorific 9540 1800 ArU/lb Aslrrr D5865-00 OZlot/Oe 5051129 Va].ue Dllution Factorr L !{Dt ,....: 13O Total Chlori-ae 326000 78100 rwlkg (r{OX WC-0015 Ot/oz-oZ/OelOe 6-OS1J-ZA Dilution Factor: 390.5 lltDIJ... ..2 242OO Appendix F - 83 29 Lot-Saql1.e #. . . 3 H5B200L 54-002 Date Sanpl.ed. .. r OL/lL/OG PARAMETER RESULT RL EG&G Defense t-Iaterials, Tne - Cl.ient, Saqrl.e ID: SADIPIiB 1-B G[0\IE IfiLTERIAL General Che&istry Ilork Order *..-: HXQ2D Date Received. - : 0 2 / 20 / 06 SOLfD PREPARATION- PREP AISAITYSIS DATE BATCH # l.tratrix. UNITS N/IETHOD Ash Content, Gross Ca].orific VaIue Tota1 Chf-orine 1_43 00 24o Ar/kg Dilution Factor z L.2 11200 18OO Brrr/lb Dilution Factor: 1 313000 788oo mg/kg Oilution Factor: 3 94 . ASII{ D482-0Oa MDL.........,.. z 6L.2 ASmt D5865-00 MDL ..,.: l-30 Kr[ox Hc-00L5 MDL .o.,,..,:24400 o2l2S-03 / otl as 5ose31o 03lo3 loo 506LL29 caloz-o3/o;/oG Go6LLz6 Appendix F - 84 KtG Defense uaterials, flrc. Clieut Saqrle ID: SA&!PIiE 1-C trACE SEIBIiD IATERIAL Genera1 Cherristry Iot-San[r1e *. -.: H5B200].64-003 Work Order #-..: I{XQ2F liiatri:r- - -: SOLID Date sary)Ied.. .r ot/L1,/o6 Date Received..2 02/20/06 RESIII,T RL UNITS METHOD 30 PREPARATION- PREP AIIAIYSIS DATE BATCH #PARAMETER Ash Content 3250 2O0 ms/ks AsIIrt D482-OOa O2128-OtlOLlO6 5O5931O Dilutl"oa Factorr 1 !{DL.......,....: 51.0 croas Calorific 99zo 1800 Bru/u Aslu D5865-oo azlo3/o6 6o6t1,29 Va]-ue Dilution Factor: 1 MDL...,........ I 130 Totar c'hlori-ne 4z4ooo 98600 trq,lks xltox wc-oo16 otloz-olloeloe eo5]-]-ze DilutionFactor! 492.9 ![DL.... .: 30600 Appendix F - 85 31 BG&G Defense lliateriars, Inc. e1ient Saq)le ID: SATIPIE 2-A STIIT IAItsRIAII Geueral Chenistry Iot-Sary)Ie #. -.: H58200164-004 Tlork Order #. - -: HXQ2H l4atri:r. ..: SOT,ID Date Saqfled. . . . a1/1l/o6 Date Received. .: 02/20/06 PARAMETER RESULT RL IJNITS METHOD PREPARATION- PREP A}IALYSIS DATE BATCH # DiluLion FacEor: 1 MDI,.......,,.,.: 51.0 cross calorific 9630 1800 BTIr/lb Aslrrt D5865-0O $106106 6O6LA29 \Ial-ue DiLution Factor: 1 MDL.......,..,.: 130 $ota1 Cblori-ue 322000 8O3OO rns/ks m[OX WC-0015 $102-03106106 6O6At26 . DiLution Fact.or: 40L.3 l,lDL. .. .. : 24900 Appendix F - 86 O 32 . BGi6G Defense l{aterials, Itrc. C1ieut Saqr].e ID: SAtrIPI'E 2-B GIO\IB IBTRIAL Geueral- Chenistry Iot-SarEle *...: H5B200154-005 WorkOrder #-..: HXQ2iI l,iatrix- --: SOLTD Date saq[ed--- | o1-/L1./o6 Date Received- -. o2/2o/o5 PARAMETER RESIILT RL TINITS METHOD PREPARATION- PREP AIVALYSIS DATE BATCH # Ash Content 13400 2O0 ns/ks ASTri D482-OOa O2128-BlOu06 50s9310 Dilution tracEor: 1 MDIJ..,.,...,...: 51.0 Gross Calorific 11200 18OO BIII/U, ASIIT| D5855-OO $lOGlOG 6061129 Value Dilution Factor: 1 I,{DL.......,..,. r 130 Total Ch].orine 314000 80?00 rog/ks XIIOX We-0015 03102-03106106 6O6Lt26 Dilution Factorr 403.6 MDL...;,.....,.: 25O00 Appendix F - 87 33 BG&G Defanse lliaterials, Irrc. Clieuts Saqfle ID: IIAMPLB 2-C EACB SIrIEI;D iiAm,IAL cerxeraf Chenistry lot-Saq)1e #. ..: H5B200L64-006 llork Order *. -.: HXQ2K llatrix . .. : SOLrD Date Saq)ted...: ol/lL/o6 Date Received--: 02/20/06 PREPARAITION- PREP PARAMETER RESIIITT RL IINTTS METHOD AI.TALYSTS DATE BATCH # Dilut.ion FacEor: 1 IvfDL ..,,,: 5L.o Gross Ca]-orific 9880 18OO B11,/1b Aslrr Ds855-0O B106106 5051129 Va]-ue DiLution Factori 1 MDL.....,......: 130 Taral Cftl0ri.ne 421000 9s300 rylkg xtrox ne-0016 03102-03106106 606tL25 Dil-ution Factor: 476-4 MDL. . . . .: 29500 Appendix F - 88 34 , AG8G Defense liIaterials, Inc. elient Saqrle ID: SAIIPLE 3-A SIIIT llATRIAfr Gene-ra1 Chenistry Iots-Saryrle #. ..: H58200L64-007 llork Order *...: HXQ2M t6trix- -.: SoLfD Date Saqfled.--2 O!/tL/o6 Date Receiwed.-| 02/20/06 PARJAMETER RESUI.,T RL T,NITS METHOD PREPARATTON_ PREP ANALYSTS DATE BATCH. # Aah coDtent 51900 24O nslkg Asllii I)482-OOa .O2128-oalutl06 5059310 Dilution Factor: 1,2 MDL,... ,,2 5L,2 Gross Calorific 9720 18OO BI'Ir/]-b Asrrrr D5855-0O $106106 5051129 VaI-ue Dilutioo.Factor: 1 MDL..,.......,.: 130 Total Chlori-u.e 324OOO 985OO ns/kg Xr()X IC-0015 03102-03106106 6O6Lt26 Dilutior Factor: 492.6 l{DL... ..: 30500 Appendix F - 89 BGtG DefeEae t'laterials, Tns. Clieut Saqr1e ID: SNIPLB 3-B GI.0VE IATERIAL General- chenistry Iot-Sar4ple #.. -: H58200154-008 Ilork Order #...: HXQ2P Irtatrix. -.: SOLID Date Saqfled- - - 2 01,/Lt/06 Date Received- -. 02/20/06 RESIILT RL T]NITS I{ETHOD 35 PREPARATION- PREP ANAIYSIS DATE BATCH #PAIU\METER A.sh Content 13700 22,O wlks ASlrrr D482-O0a 02128-8101106 5Ose31O Dilutiou Factor3 1.1 MDL. . . .. I 56.1 Gross Ca].orific 11200 1800 Bl,II/tb A.SlrI Ds855-O0 03106105 6O6LL29 va].ue Dilution.Factor:1 MDL ..,..: 130 Total ch1oriue 32OOO0 96000 Es/ks xrrox ne-O015 03102-03106106 6O6LL26 DiLution Factor: 4?9.8 !{DIr,.. .,: 29?0O Appendix F - 90 36 BC,E.G Defeose Uateria].s, Irrc. Clieut Saqile D: SAIIIPIiE 3-e EACE SEIEITD IIAIERIAL Genera3. Cheuistry Iot-Saqfle *. -.: H68200164-009 Eork Order *...: HXO2Q ttlatri-n. . -: SOLfD Date Saqr1ed... ? 01/Lr/06 Date Received. --- 02/20/06 PREPARATION- PREP PARAMETER RESULT RI, I'NITS METHOD A}iIAIJYSIS DATE BATCH # Ash Co.ntent 3760 2OO Ett/kg .A"gIIrt D482-0Oa 02128-8101106 5059310 Dilution Pactor: 1 MDIJ,..,.,..,.. .: 51.0 Gross Calorific gg2o 18OO Bl{I/il} ASTti D5855-OO ff.l06l06 505U29 Va].ue _DilutionFactor:1 MDIJ ....,:130 Total. Chf-orine 422OOO 1O9O0O nslkg XrrOX re-0o16 03103-03/06106 6A61-L26 DiLutidr Factor: 545 l,lDL,... ,: 33800 Appendix F - 9l EG&CI flefense l.Iaterials, Tnc. Client Sarqll-e ID: SAIIPI,E 4-A SIIIT }IBTERIAL General Chemistry Ilork Order #--.3 HXQ2V Date Received. . r 02 / 20 / a6 37 Matrix. . . - . . - l - : SOLID PREPARATION- PREP A}IALYSIS DATE BATCH # I,ot-Sary>Ie S - . . : H6B200164-010 flate Sanpled. . . 3 0L / Ll./ 06 PARAMETER RESIILT Ash Content Gross Ca].orific Va].ue Tota^I- Ctr].orine s0100 RL UNITS METHOD 2o0 ruS/ltg Dilution Factor: l- e?so 1-800 Bflr/u) Dilution Faetor: 1 318oo0 1os00o mO/kg Dilution Factor I 523 .8 ASII{ D482-0Oa I{DL : 5l-.0 AS1!I D5855-O0 MDIJ ......,,1 130 Krrox wc-0016 I{DL,.. , .. .....,: 32500 azlzs -o3 I o:-/ oa Goss3lo a3l06/06 505LL29 03 / 03 - 03 / 06l 06 506 LL26 AppendixO 92 F- 3B reEG DefcnEe liateri"als, IIrc- el.ient Saqfle ID: SAMPLE 4-B GI,OVB IATRIAIT Geueral Chenistry I-ot-Sary)Ie *...: H58200164-011 tlork Order *-. -: IIXQ2O lilatri:r. ..: SOLID Date saq,led-. .. oL/LL/o6 Ilate Received... 02/20/06 PREPARATION- PREP PAR,AMETER RESUI,T RL I,NITS },IETIIOD AI.IALYSIS DATE BATCH # Dilution Factori 1.2 lilDl.... .t 67.2 Grosa Catorific r.13OO 18OO BIU/IJ, ASrr{ D5865-OO 03106105 6O5LL29 val.ue Diluti.on Factorr 1 MDIJ . . .. .: 130 Toral. Chlori-ne 316000 1O7OOO wlkg XNOX, ne-O016 O3lA3-OtlO6lO6 6O6LL25 Dilutlo! Factor: 534,2 MDL.... .: 33100 Appendix F - 93 39 BGEG Defense lriaterials, Illc. Client Sary)Ie ID: SAIIPLB 4-e EA(E SEIBLD InTRIAL General- Chemistry Iot-Sarylle *- . -: H5B200164-OL2 llork Order *-..: llXQ22 lrlatrix- . -: SOLID Date sanE1ed.... |L/Lr/o5 Date Recei.ned..r 02/20/06 PARAMETER RESUIJT RL UNITS METIIOD PREPARATION- PREP ANAIJYSTS DATE BATCH # Ash. content 3440 2OO . wlk:g ASIIir D482-0Oa O2l2S-$lO1l05 5059310 Dilution Factor: 1 MDIr .,...: 51.0 Groas Calorific 9840 18OO BlIr/rb Aslrt D5855-OO 03106106 6061129 Va1ue Dilution Factor: 1 MDIr.,...,..,...: 130 Total Chlori-ne 424000 111OOO ns/ks XNOX re-0o15 03103-03/06106 6O6LL25 Dilutsion tractor! 555.5 MDL... ..: 34500 Appendix F - 94 40 EGI.G Defense lhterials, Inc. C].ielrt Saqrle ID: SAIIPLE 5-A SIIIT HAImIAL Geueral Chenistry Lt-Saryrle *.,.: H68200164-013 lYork Order #.. .: llxQz4 llatrix. -.: SOLID Date saqfled..-z 01,/LL/06 Date Received..r 02/20/06 PREPARATION- PREP PARJAMETER RESIII.T RI, I,NITS IIIETHOD AI{ALYSTS DATE BATCH # Ash Coatent 52600 200 Es/ks A.Slrrr D482-O0a O2128-BlOu05 5Os931O Dilutsion Pactor! 1 I,IDL..,....,..,.: 51.0 Gross Calorific 97LO 18OO B?rlllb Aslrrr D5865-OO 03106106 6O5Lt2g Va].ue DilutionFactor! 1 ttlDl ..,.-: L30 Total chLoriae 322OOO 112OOO wlkg X![OX WC-0015 O3IO3-O3/O 6106 6A6LL26 Dilution Factor: 558 MDIr. . . . .: 34500 Appendix F - 95 4t EG&G Defense llatefials, Irrc. Client Sanple ID: SAilPLE 5-B gIOlrE IiIAIERIAIT Genera-L Cbenistry Iot-Saq>I-e #. - -: H6B200154-014 tlork Order *...: HXQ25 rrlatri:r -..: SOLID Date Saryrled-; -. oL/LL/o6 Date Received.... 02/20/06 PARAMETER RESUIJT RL T NITS IVIETHOD PREPARATION- PREP ANAI,YSIS DATE BATCH # Aah ConteB.t 14s00 260 ns/ks ASTtit D482-0Oa O2128-O1lOuO5 5059310 Dilutioo Factor: 1.3 MDIr,.. ..: 65-3 Gross Calorific 1r.20O 18OO Bfir/rb Aslrl D5865-0O 03106106 6O5AL29 Val-ue, Dilutiofl FacEor: 1 !4DL....,..,....: 130 Total ($rori-ne 310000 111000 wlks xNox wc-0015 a3lB-otlo6lo6 606Lt26 DilutioE Factor: 552.8 MDL.... .: 3.4300 Appendix F - 96 42 BG8G Defense tiaterials, IIc- Client Saqrle ID: SAITIPLE 5-C EACE SHIELD IBIBIIAL ceneral. Ch€nistry Iot-Saqrle *...: 1168200154-015 ltork Order *-..: IIXQ28 liatrix. - -: SoLID Date Saqiled-.. = 01,/LL/o6 Date Received... 02/20/06 PREPARJATION- PREP PARAMETER REST'IJT RL I'NITS METHOD ATIAI'YSIS DATE BATCH + Dilution Factor: 1 MDL .....: 51,0 Gross Cal-orific 9840 18OO B'IU/rb ASXtt D5855-OO 03106106 6O6LL29 VaI-ue DiLuEion Factor: 1 l,{Dt . . .. ,: 130 Total. c'hrori-ne 431ooo 112000 uolkg xNox Be-0016 cB|ca-cal06l06 606LL26 Dilution Factor: 561-.5 l{DIr,.. .,: 34800 Appendix F - 97 43 EGSG Defense lrlaterials, Inc. Client Saqfle ID: SN:|PIiE 6-A St IT IAIERIAL General Cheui.stry Ilot-Sarq1e *,..: H5B200L54-015 tlorkOrder *...:. HX03D ltlatrix- .-: SOLID Datse Saq)ted.---, o7/Lt/06 Ilate Reqei\red..z Oz/zo/oa PARAIVIETER RESIII,T RL I]NITS METHOD PREPARATION- PREP ANAIYSIS DATE BATCH # Asb Content 52300 200 lry,lkg 4.9'r'u D482-ooa o2128-Blol/05 5059310 Dilution Factor: 1 litDl..,.........: 51,0 Grors Calorific 9670 1800 BI'Ir/Ib ASTI. D5865-OO 0E-l06l06 505L129 valrre Dilutiou FacEor: 1 !IDL.......,,...: r.3o :fotal cblorine 333000 111OO0 rns/ks KNOX WC-0O16 03l03-0.J^l06l06 6O6aL26. Dilution Factor: 555.9 MDL... ,,: 34500 Appendix F - 98 o BG&G Defense ll,ateria1s, Tnc. Saq>Ie ID; SAMPITE 6-8 GL0VE }ATER.IAI, Geueral ChenisLry TYork Ordgr #-. -: HXQ3E l-Iatri:r- - -.. - - -.: SOITID Date Received. . 3 02 / 20 / OA 44 PREPARATION- PREP AI{A],YSTS DATE BATCH # Iot-Saq>Ie #-..3 Date Saqlled.---3 P]UU\METER CIieut H6B200L64-0L7 oL/ Lr / os RESIII,T RL T]NITS METHOD Ash. Content Gross Calorific Va]-ue Tota]- Ch].orine L2400 26a El/kg Dilution FacEor: L.3 1r-200 1800 Bfir/Il) Dilution Factor: 1 314ooo LL?OOO rng/kg Dilution Fact,or: 55 9 . 3 ASIIti D482-OOa MDI, : 66 .3 A.Sltt D5865- 00 MDL : 1,3 0 x}Iox wc-0015 MDL.... : 34700 o2lzg-o3 I otl os 6ose31o 03106 loa 606LL29 o3lo3-o3 / oa/ oe Go6LLz6 Appendix F - 99 45 SI.G Defense lrlaLerials, Irrc- Client Saqlte ID: SAIIPLE 6-C EACB SIIIBLD IATtsRIAL General Chenistry Iot-Saqile #...: H6B200154-018 Work Order *...: HXQ3F liatrix. ..: SOLID Date saq)].ed.-.? oL/tL/06 Date Received--. 02/20/06 PARAMETER RESUIJT RL UNTTS METHOD PREPARATTON- PREP A}iIAI,YSTS DATE BATCH # Asb ConteBt 33OO 24O ns/ks ASIIlr D482-0Oa O2128-O3lOuO5 5059310 Dilution Factor: 1.2 MDL.... .: 51.2 Gross Calorific 9840 1800 BTU/rb Aslrr D5855-OO 0al06l06 5051129 Va].ue Dilution Factor: 1 !!DL........,..,: 130 Totsa1 c'hrori-ne 439ooo 109000 rylks xr[ox rle-oo16 0a103-03106106 6o6LL26 Dilution Factsor: 5{7.3 MDL.... .: 33900 Appendix F - 100 46 UBIEOD BI,A}IK REPORT General. Chemistry Client I.ot $-..: H58200L64 tlatri:ro - - - - - - - - : SOLID REPORTING PREPARATTON- PREP AIVAIJYSTS DATE BATCH #PARAMETER RESUIJT LfMIT UNITS METHOD Ash Content Vilork Order #: H0C,J01AA MB lJot-Sample #: H6B280000-310 ND 200 mg/tg ASTM D482-OOa OZ/Za-OZlOrlOe eOSgerO Dilution Factor: 1 Total Chlorine Work Order *: H0GAT1AA l,IB lJot-Sample #: H5-C020000-126 ND 2oo mglks KNox wc-00r6 ot/oz-m/as/oe soettze Dilution Eactor: 1 NOtrB(S): Calculations are performed before rounding to avoid round-off errors in catculated results. Appendix F - 101 47 ffi CONIROIT SAIIPI-.B E\IALITATfON RBPORT General Chemistry Lot-Saryll.e #. . . 3 H5B200L64 ![atrix. . - - - . . - - 3 SOI-rID PREPARATION- PREPPERCEI{T RECO\IERY RPD PARAIVIETER RECOVERY LTMTTS RPD LIMITS METHOD ANALYSTS DATE BATCH # Ash Cont,ent wo# : H0c,I0 1ac- r,cs/ttoc,Jo 1AD- LcsD IJcs IJot - sampl e# : H5B2 8 o 0 0 0 - 3 L 0 r.00 ( go L1-0 )ASTrvr D482-00a 02/28-03/OL/OS 5059310 100 (90 - 110) 0.22 (0.-10) ASTM D482-OOa OZ/Za-OZ/0LI05 50s9310 Dilutsion Factorr 1 Gross Calorific WO#:H0GDK1AA-LCS/H0GDK1AC-LCSD LCS Lot-Sample#: H6CO2OO00-129 value 100 (98 - 102) AsrM D5965-00 oz/sz/oe 606tL29 r.00 (98 - r-02) 0 -o9 (0-2.0) AsrM D5855-00 oz/oElos 6o6tlz9 Dilut.ion Factor: 1 ITCTTB (S) : Calculations are performed before rounding to avoid round-off errors in calculated results. Appendix F - 102 o 4B IABORATORY CIC}IIROIJ SAI{PI'E DATA REPORT General. Chemistry Iot-Sary>Ie #. . . : HOB2O0L54 ldatrix-. - . . . . . . 3 SOIJfD SPIKE MEASI]RED PERCNT PREPARATTON- PREP AI.IAT,YSTS DATE BATCH ,tPARAIT,IETER AMOI,NT AIVIOI]NT I,NITS REEVRY RPD METHOD Ash Contsent WO*:H0C,]01AC-LCS/H0C,J01AD-IJCSD LCS lJot*Sanple#: H5B28OO0O-310 4000 4010 mg/ks 100 ASTM D482-OOa Oz/ZA-OZ/O1106 6Os931O 4000 4O2O mg/fg 100 0.22 ASTIVI D482-00a Oz/ze-oz/or./05 6os931o Dilutioa Factor: 1 Gross Calorific wo#:H0GDKraa-r,cs/uoGDKlAc-TrcsD Lcs Lot-sample#: H6c02ooo0-L29 value 1L400 1L300 Bru/lb 1OO ASTl,r D5865-OO OZ/Ot/Oe 5O6tL29 11400 11300 BTU/l-b 100 0.09 ASTrvr D5865-OO Og/Ol/Oe 6O6]-L29 Dilut.ion Sactor: 1 !r(}fE(s): Calcularions ate perforrned before rounding to avoid round-off errors in calcutated results. Appendix F - 103 49 LABORAITORY COIIIROIT SAI,IPIJB E\IALIIATfON RBPCIRT General Chemi-stry C1ient Lot, #- - .: H6B200154 l.tratriJ(,. - - - - - - - - : SOLID PREPARATION- PREP ANA],YSTS DATE BATCH # PERCEMT RECO\IERY PARAMETER RECO\IERY LIMITS METI{OD Total Chlorine Work Order #: II0GAT1AC LCS Lot-Sample#: I16C020000-126 102 (80 - 120) KNox wc-00r.6 osloz-os/oe/oe 6o6lt26 Dilut.ioa Factors 1 NO{[E (S) : Calculations are perforrned before rounding to avoid round-off errors in calculated results. Appendix F - 104 50 IABORATORY CI}NTROT SA}IPIiE DATA RtsPOR:T General Chentstrry C1ient Iot #...3 H582001-54 ltatrix.. o. - - - -. r SoLrD PREPARATTON_ PREPSPIKE MEASI}RED PERCNT PAIU\METER AIvIOI,NT A}IOUNT I,NITS REC\M,Y METHOD ANALYSIS DAqE BATCH # Work Order #: HOGAT1AC IJCS Lot-Sample#: H6CO20000-L26 10000 10200 mg/kg to2 KNox wc-0016 os/oz-oz/oe/os eoettza Pilution Factor: 1 NOtfE (s) : Total ehlorine Calculations are performed before rounding to avoid round-off errors in calculated results. Appendix F - 105 51 IIAIR,IE SPTNB SAI{PIJB E\IAI'UATTON REPORT General Chemistry Clieut lpt #-..: tI68200164 liiatrix. - ..: SOLID Date Saq)led. . - : 0t/7]./06 Date Received . .. 02/20/06 PERCEMT RECO\TERY RPD PREPARATION- PREP AI{AI,YSIS DATE BATEH #PARAIY1ETER RECOVERY IJIMITS RPD LIMITS METHOD Total Chlorine wo#r HxQ].xrae-us/uxQ1xlA7-MsD Ms IJot-sanple #: H6B2oo164-001 115 (gO LzO)Krrox wc- ooLs 03 / a2-03 / 06 / 05 605 L1-25 t|z (80 - 120) 1.s (0-10) KNox wc-0016 o3/oz-03/oa/oe eosttze Dilution Factor! 1 NOTB (S) : Calculations are performed before rounding to avoid round{If errors in calculated results. Appendix F - 106 52 Client Iot S--.3 H68200154 Date Sarpled- -. 3 AL/LL/05 SAMPIJE SPIKE PARAMETER A},IOUNT AMT T"t"I Chl"rire 326000 39700 326000 39900 NCrrE (S) : lllATRXf SPIKE SAMPITB DA[A. RBFORT General Cheulstry Date Received- - 3 02 / 20 / 06 Itatri:ro . - . . o . . . : SOLrD MEASRD PERCTIIT PREPARATION- PREP AIIALYSIS DATE BATCH #AIVIOI'NT I]NITS RECIIRY RPD METHOD wo#: HXQIXt-le -us/xxQ1x1A7-MSD MS rrot-Sample #: H68200164-001 372OOO mg/kg tL5 KNOX WC-0016 OZ/OZ-OZ/Oe/Oe eOattZe 366000 mg/kg LOz 1.s KNOX WC-00L5 Ol/OZ-OZ/Oe/Oe eOattZe Dilution Factor: 1 Calculations are performed before rounding to avoid round-off enors in calculated results. Appendix F - 107 53 SATIPI,E DTIPLICATB BTTAI,IIATTON REPORT General Chero-istry Client Iot *. - -: H5B200164 Ilork Order #...: IIXQIX-SMP uatrix. : SOLID trxQr.x-DuP Date saq)Ied...: o1/L7/o6 Date Received. -. 02/20/06 DUPLICATE / RPD PREPARATION- PREP A}ilAIJYSIS DATE BATCH #PARA.IVI RESI,I.T RESIILT I,NITS RPD I'IMIT METHOD Gross Calorific VaIue SD Irot-Sample #: H5B200L64-001- 9540 9590 BTU/1b 0.48 (0-10) ASTIVT D5855-OO Ol/OZ/Oe 6O6aL29 DilutioE Factorr 1 Total Chlorine SD Lot-Sample #: H5B2OO154-OO1 325000 326000 mglkg 0.13 (0-10) KNOX We-0015 OZ/OZ-OZ/06/06 606tL26 Dilution tr'actor: 390.6 Appendix F - r08 54 SAI{PIB DUPTJIEATB EIILTTIATTON RBPORT General Chenistry Client Iot +..-: H6B200154 Ytrork Order #-,.: HXQ2o-SMP Uatrix- : SOLID HXO20-DUP Date Saqrled.- -t ot/tt/o6 Ilate Received.-. 02/20/06 DUPLICATE RPD PREPARAUON- PREP AIVALYSJF DATE BATCH #PARAM RESUT,T RESUI,T I]NTTS RPD LIMIT METHOD Gross Calorific SD Lrot - Sample # : . H682 0 01 54 - 01" 1- Value 11300 r.r.200 BTU/Ib 0.58 (0-10) AS${ Ds85s-OO .03/06/06 6061L29 Dilution Facto!: 1 Total Chlorine SD Lot-Sample #: H68200154-011 3L6000 320000 mg/kg 1..3 (0-10) KNOX r{C-0015 03/03-03/06/06 6O6La26 Dilution Factor! 534.2 Appendix F - 109 O Clieut Ipt ff. . . : Date Saqrled. ..3 PAIU\M RESULT H5B2 0 0154 oL/ rL/ a6 DUPLICATE RESUIJT SAITIPIIE DIIPTICAIts E\ITItTIATION REPORT Genera-I ChenisLry Ilork Order S-..3 HXQ3F-SMP HXQ3F-DUP Date Received- - ! 02 / 20 / 06 UNTTS RPD RPD IJTMTT NIETHOD 55 PREPARATION- PREP ANALYSTS .pArE BATCH # H58200L54-0r.8 oz/2s-03 / ot/ o6 6ose31o Ash Content 3300 32s0 mg/kg t. 6 Dilution Factor z 1.2 SD Lrot -Sample # : (o-10) ASTTI D482-00a Appendix I l0 o o o APPENDIX F SECTION 3.4.2 Metals Analyses Results MPF SWDT REPORT - Rev 0 Appendix F June 9,2006 TOCDF F-l11 I,ot-Sarq>Ie S.. .: Date Sampled..,: PARAMETER EG6.G Defense Materials, Inc . Client Saq>Ie fD: SAI{PLE 1-A SUIT I{ATERIAL TOTAT Meta1s H5B20 01 64 - 0 0l 0L / lL / 06 Date Received. . ! 02 / 20 / 06 RESULT REPORTING LIMIT UNITS METHOD Matrix. - PREPARATION- A}TALYSTS DATE : SOLID WORK ORDER # Prep Bat,ch # - Mercury Prep Batch #- Aluminum Ant imony Arsenic Barium Berlr|l ium Boron Cadmium Chromium Cobal- t Copper tead Mangarrese : 5055255 ItD : 6055258 223 ND t[D 424 ND }UD 19-0 ND ND }UD 0-88 o -27 0,0020 mg/kg Oilution Factor: 1 sw846 -7471A 03/08/06 Analysis Time. . : l-3 : 59 MDL 03loB-03/Lo/06 MDL 03/08-a3/10/06 MDL 03/oB-03/ro/oe MDL 03/ oB-o3/l_o /oa MDL 03/08-03/1,0/05 MDL 03/08-03/1,0/06 MDL 03 / oB- 03 /Lo / 06 MDL 03/oB-03/Lo/06 MDL 03/08-03/Lo/06 MDL 03/08-03/La/ae MDL 03/08-03/Lo/06 MDIJ 03/08-03/Lo/06 MDL HXQIX]-AE : 0,010 E(QlXIAF : L.1 HXQ1XtAG : 0.14 HXQIXTA}I : 0.033 rD(Qt-xl-Air : 0.080 HXQ1XlAK : 0.018 HXQT.XTAL : 0.31- rD(Q1X].AM : 0.0082 HXQl-Xl-A}tr : 0.036 HXQr-XIAP : 0 .022 HXQlXlAQ : 0.070 ro(Q1X]_AR : 0.037 m(Qr-xr.AT : 0.0L8 4 .0 nrg/kg SI{845 60L08 Dilution Factor: 0.1 Analysi.s Time. . , 74:o7 0.50 mg/kg SW846 50r0B Dilution Factor: 0.1 Analysis Time. . : 14 zO7 0.20 mg/kg Sw845 50108 Dilution Factor: 0.1 Analysis Time..: 1,4207 0 - 50 nrg/kg sW846 5O10B Dilution Factor: 0. 5 Analysis Time. . : 14 :54 O.1o mg/kg SW846 60108 Dilut.ion FacEor: 0.1 Analysis Tirne,.: 1-4zQ7 2 . O mg/kg SWB45 501-08 Dilut.ion Factor: 0.1 Analysis Time. . : l-4:07 0. osO mg/kg SwB45 6oL0B Dilution Factor: 0.1 Analysis Time..: 14:07 0.15 mg/kg SW845 50L08 Dilut,ion Factor: 0.1 Analysis Time..: L4:O'7 0.50 mg/kg Sw846 50108 Dilution Fact.or: 0.1 Arralysis Time..: 74:o7 0.2s mg/kg SWB45 50108 Dilution Fact,or: 0.1 Analysis Time . - : 14 207 0 .15 nq/kg SW845 50108 DiluEion Fact,or: 0.1- Analysis Time.-: 74:07 0.1s W/kg sll846 60108 DiluEion Factor: 0.1 Analysis Time..: 14:o'l (Continued on nexL page) Appendix F tt2 o BG8G Defense Materials, fnc. Client Sample ID: SAI.{PLB 1-A SUIT IIIATtsRIAL 10 Dfatrix.: SOLf D PREPARATION- WORK AI{IAI,YSTS DATE ORDER # TO{fAIr Metals I,ot-Sarq>1.e S. - - : 1158200164- 00L REPORTING PAIU\METER RESULT LIMIT UNTTS METHOD O zitc NO{[B (s) : NickeI 0-s0 0-40 nrslkg sI{846 60108 O3/OS-O3/L0I05 H(QIXI-AU DiLution Fact,or: 0.1 Analysis Time.. t L4:07 MDL... .. r 0.038 Selenium ND 0.15 mg/kg SW845 50L08 03/08-03/L0l05 HXQI-X1AV Dilut.ion Factor: O.L Analyeis Time..r 14:O? MDL,.. .., O,O+S silver ND 0.30 mg/kg sw845 60108 03/08-03/L0l06 HXQIX]AW Dilution Factorr 0,1 Analysis Time.,r 14:07 MDL..., .: 0.09? Thallium ND G 7.1 mg/kg SW846 5O1OB B/O!-B/LO/06 HXQ1X1AX Dilution Factor: 0,1 Analysis Time,,r !4:Q7 litDIJ... .-: 0.1.0 Tin 8-7 1.0 mg/kg slr845 50108 O3lO8-O3lL0/05 E(Q1X1Ao Dilution Factorr 0.1 Analysis Time,, t L4t07 MDIJ,.. ..: 0.07? o .25 mg/kg sw845 50108 03/ 08-o3/1-ol05 HXQ1XIA1 pilution Factor: 0.1 Analysis Time..: 14:07 MDL... ..: 0.050 0.60 ms/kg sw846 60]-08 O3/O8-O3/L0I06 ffiQLXlA2 Dilution Factor: o.1 Analysis Time, .: L4:07 MDt.., -,: 0-041 Vanadi-um ND 54 .5 C Elevated reporting limit. The reporting limit is elevated due to matrix interference. Appendix F - 113 BGEG Defense }taterials, Inc . C1ient Saqrle ID: SAII{PLB 2-A SUIT MATBRIAT TOTAL Meta1s Ipt-Saq)Ie #...: 1158200154-004 !!atrix. : SOLID Date Samp1ed...: ot/]-:-/oe Datse Received.. z 02/20/06 11 PREPARATION- WORK A}TALYSTS DATE ORDER # REPORTING PARAMETER RESULT LIMTT UNTTS METHOD Prep Batch #--.: 6056255 ' Mercury ND 0.0020 mg/kg sw846 747tA 03/08/06 HXQ2HIAIr Dilution Factorr 1 Analysis Tine..: 14:09 MDIJ.., .,r 0.0L0. Prep Batch $...: 6066258 Aluminum 228 4.0 ms/fg Sw846 60108 oz/oe-oz/t0l06 ExQ2EI-Air DiluEion FacEor: 0.1 Anal.ysis Time..: 14r25 MDL... ,.: 1.1 Anrimony ND 0.50 mg/kg SW845 60108 03/08-a3/L0l05 HXQ2HIAK DiluE.ion Ractor: 0,1 Analysis Time..: 14:25 MDt... ..: 0.14 Arsenic ND 2.0 mg/kg SW845 60108 O3/08-o3/LOl06 HXQ2HIAL Dilution Factor: 0.1 Analysis Time.., 14,25 MDIJ.,. ..: 0.033 Barium 37a 2.o mS/fg Sw845 5o1oB o3lo8-o3lLol06 EI(Q2ELAI.i Dilution Factor: 2 Analysis Time..: 22:58 MDL... ..: 0.32 Berylli-um ND 0.10 mg/kg SW845 60108 O3/08-03/L0l05 HXQ2HIAN Dilution Factor: 0;1 Analysis Time.,, 14,25 t'rDL... ..: 0.018 Boron ND 2.0 nf.g/kg S91846 60108 03/08-03/10/Oe nXQZUrep Dilution Factor: 0.1 Analysis Time..: l-4:25 MDL,.. ..: 0.3L cadmium 2L-3 0.050 nrslkg svr845 50108 03/08-03110106 ID(Q2SlAQ DiluEion FacEor: 0.1 Analysis Aime,.: 14:25 MDL.,. ..: 0.0082 chromium ND 0.15 mg/ks sw846 50108 03108-03/]-0/06 HXQ2HLAR Dilutsion FacEorr 0.1 Analysis Time..: 14r25 MDL.,. ..: 0.036 Cobalt. ND 0.50 mglkg SW845 60L0B 03/08-o3/L0l05 HXQ2HIAT Dilution Pactor: o.L Analysis Time.., 14r25 MDIJ... ..2 0.O22 Copper ND o.zs mg/kg sw846 60L08 fi/a8-03/L0l06 HXQ2HIAU Dilution PacEorr o.l, Analysis Time..: 14:25 MDIr... ,.: 0.0?0 read r-.r. 0.L5 lIg/kg sw845 50r-08 o3lo8-o3lho/06 m(Q2E1AV Dilution Factor: 0.1 Analysis Time..r 14:25 MDL,.. ..: 0.037 lta-nganese 0.33 0.15 nS/kS SW846 60108 O3/O8-O3/LOI05 E(Q2HI-AW Dilution Eactor: 0.1 Analysis Time.. ; 14:25 MDL. .. ..; 0.0L8 (Continued on next page) Appendix F - 114 o L2 EGIG Defense l{atrer.ia1s, Inc . Client Samp1e ID: SAIYIPLE 2 -A SUfT IIATERIAL TOTAT Meta1s Iot-Sanple f; . . . : H58200164-004 REPORTTNG PAIU\METER RESULT LTMIT I]NITS METHOD Nickel 0.s0 0-40 nrei/kg sr{846 60r-08 o3loB-o3/toloe mrQzsrax Dilution Pactorr 0.L Analysis Time.. z 74t25 1..1Dt.... ,: 0.038 Selenium 0.L5 mg/kg SW845 501-08 03/08-03/l-0106 HxQ2HLAo Dilution Factorr 0.1 Analysis Time,.:74t25 MDL... ..r 0.043 Silver ND 0.30 r,l.g/kg Sw846 60108 03/08-03/10/05 HXQ2HLA1 Dilution Factor: o.L Analysis Time.. i L4t25 MDL... - .: 0.09? Thallium IUD G 7.9 ms/kg SW846 50108 OSIOA-O:/10106 HXQ2H1A2 DiluEion FacEor: 0.1 Analysis Time..: 14t25 MDL... - .: 0.10 Tin 8.3 L.O mg/kg sI{846 gOrOs O3lA8-o3/L0/06 IIXQ2ELAA Dilution Factor: 0.1 Analysis time,. t !4t25 MDL.... .t 0.077 Vanadium IID O.2s mg/kg sW846 60108 03/08-o3/Lol05 HXQ2H]-AC pilution Factor: 0.1 Analysis Time.. r L4r25 MDIJ,,.. .: 0:050 ziac 58-5 O.50 w/kg SW845',60r-08 O3lO8-O3/Lol06 E(O2SI-AD Dilution Factor: 0,1 Analysis T:ime.. t a4r25 MDL,... . I 0,041 lloTB (s) : G Elevated r€porting limit. The reporting limit is elevated due to matfix interference. Appendix F - 115 Flatrix. - . . . . . . . r SOLID PREPARATION- WORK ArvALy_s r s pArE-- oRpER .-# BG&G Defense Materials, Inc. Client Sample fD: SAIIIPLB 3 -A SUIT IIU\TBRIAL TOTAT l{etals Iot-Sanple #...: H68200164-007 Matrix. : SOLID Date Sanpled. ..: Oa/Ll./O5 Date Received. . z O2/20/06 13 PREPARATTON- WORK A}{IALYSIS DATE ORDER # REPORTING PARAMETER RESIILT LIMIT UNITS METHOD Prep BaE,ctr #...: 5055255 Mercury ND 0.0020 mglkg sw846'747]-A 03/08/06 HXQ2MLAH Difution Factorr 1 Analysis Time..: 14:LI MDL... ..: 0-010 Prep Batch #...: 5066258 Aluninum 22L 4.0 mglks sw846 50r.08 03108-03/L0/05 rxQ2t'trA.f Dilut.ion Factor: 0.1 Analysis Time..: 14r31 MDL............: 1.1 Antimony ND 0.50 mg/kg sW846 50108 03/08-03/10/06 HXQ2M1AK Dilution Factor: 0.1 Analysis Time.,: 14'31 MDL... ..: 0.14 Arsenj-c ND 0.20 ms/kg SW846 60108 03/08-O3/L0l05 HxQ2M1Ar, DiluEion Factor: 0.1 Analysis Time..: 14:3L MDt,.. ..; 0.033 Barium 374 2.O nrslks SW845 60108 O3lOa-O3/LOlo5 EXQzMLAU Dilution Factorr 2 Analysis Time.,r 23:04 MDL,.. ..: O.32 Beryl l ium IUD Boron ND Cadrnium 20 .6 0.L0 mg/ks sw846 60r-08 o3/08-03/L0l06 HxQ2MlAr,I Dilution Factor: 0,1 Analysis Time.. r 14:31 MDL,.. ..: 0.018 2.A mg/kg SW846 60108 03/o8-03/Lol05 HXQ2MIAP Dilution Factor: 0.1 Analysis Time.,: L4:31 MDIr... ..: 0.31 0.050 rnslkg sw846 50108 031c.8-03/1-0106 ExQ2r.tLAQ Dilution Factor: 0,1 Analysig Time..: 14:31 MDL. -. ..: 0.0082 0.1s mg/kg sw845 50r-0B orloe-og/rolo5 HXQ2MIAR Dilution Factorr 0.1 Analysis Time..: L4:31 MDL... .. r 0.036 0.s0 mg/kg sw845 60108 03/08-03/L0l05 HXQ2M1AT Dilut.ion Fact.or: 0.1 Analysis Time..: 14r31 MDL... ..t O.o22 0.25 mg/kg SW845 50r-0B O3/08-O3/L0I05 HXQ2MTAU Dilut,ion FacEor: 0.1 Analysis Time..: 14r31 MDL.,. ,.: 0.070 0.1s mglkg Sw846 60108 O3/oB-O3/LOloG ExQzI,[Av Dilution Faccor: 0.1 Analysie Time..: 14:31 MDL............: 0.037 Chromium IID Cobalt ND Copper ND Lead o -6'l MaDganese o -27 o .15 nqlfg sw846 60L08 03/08-03/L0105 ExQzI'{lAw Dilution FacE.or: 0.L Analysis Time.,r 14:31 llDL,,. ..: 0.018 (Continued on next page) Appendix F - 116 Lot-Sample S. -.: H58200L64- 007 PAIU\METER RESULT REPORT]NG LIMTT UNITS METHOD BG8G Defense llat,eria1s, fnc . C1ient Sample ID: SAI.IPLB 3 -A SUIT IiIATERIAL TOTAL t{etals t4 l[atrix. . . .. . . . . 3 SOLfD PREPARATTON_ WORK A\TALYSTS DATE ORDER- # Nickel 0 -45 0.40 nrs/lcg sw846 50108 03/08-03/1OlO5 E(Oz!,U.AX Dilut.ion Factor: O.l" Analysis ?ime..: 14:31 MDL..,. .: 0.038 selenium ND O.r-s mg/kg SW846 50r.08 03/O8-O3/L0I06 HXQ2M1A0 Dilution FacEor: 0.1 Analysis ?irne.,r tr4:31 MDL,.. ..: 0.043 silver ND O.3O mg/kg SW845 60108 03/08-03/:10/06 HXQ2MIA1 DiLution Ractor: 0,1 Analysls Time..r 14:31 MDIJ... ..: 0,097 ThaLlium ND G 6.4 mg/kg Sw846 5O1oB OZ/OA-ot/tol05 HXQ2M1A2 Dilution Factor: 0.1 Analysis Time..: 14:31 IIDL,.. ..: 0.10 Tin 8.4 1.o tns/kg Sw845 50108 03/08-03/10/05 EXQ2II{]-A;A Dilution Factor: 0,1 Anal,ysis Time..r 14:31 MDL.... .r 0.0?? vanadium ND 0.2s mg/kg sw845 60108 03/08-03/L0l05 HXQ2M1AC Dilution Factor: O,L Aralysis Time,,: 14:31 !tDL,... .: 0.050 zinlc s4-s 0.60 nvglks sw845 601-08 03/os-03/L0/05 E(QzMll[D Dilutio[ Factor: 0.1 Analysis Time..: 14:31 ItfDL.., ..: 0,041 NOTts (S) : G Elevared reporttng limit. The reponing limit is elevated due to rnatrix interference. Appendix F - 117 15 EGI.G Defense Materials, fnc - Client Samp1e ID: SAI{PLE 4 -A SUIT IIIATBRIAL TOTAIT Metals Lot-Sanple *...: H6B2001-54-O1O llatrix- : SOLID Date Sannpled...z AL/l-]-/05 Date Received,.-z 02/20/06 REPORTTNG PARAMETER RESULT LIMTT UNITS METHOD PREPARATTON- WORK AI'IALYSIS DATE ORDER # Prep Bat.ch S...i 5056255 Mercury h[D 0.0020 mg/kg sW845 747LA 03/08/06 HxQ2vlAlI Dilution Factor! 1 Analysis Time..: 14:L3 MDL.. .. .: 0.010 Prep Batch S...: 6055258 Aluminum 2O9 4.0 rns/ks slr845 60r-08 oz/oa-os/t0l06 Er(QzvrA", Dilution Factor: 0,1 Analysis Time.,: 14:35 MDL... ..: 1.1 Antimony ND 0.50 mg/kg Sw846 50108 03/08-03/1,0/06 HXQ2VLAK Dilution Factorr 0,1 tulalysis Time,.: L4'36 MDL... ..: 0.1.4 Arsenic ND O.2O ng/kg Sw846 SOIOB o3/o8-03/tol05 HxQ2vlAL DifuEion Factor: O.1 Analysis Time,. ' 14:36 MDI,.... ,: 0.033 Barium 27s 0.1-0 mg/kg sw846 60108 o3lo8-o3lLol06 lxQ2vrAlt DiluEion Factsor: 0.1 Analysis Time,. ! 14:36 MDL.... .: 0-016 Beryllium ND 0.10 mg/kg Sw846 50108 B/A8-o3/L0l06 HxQ2vlAN Dilution Factor: 0.1 Analysis 'fime..: L4:36 MDL... ..: 0.018 Boron ND 2.o mg/kg SW846 50i.08 03/og-o3/L0l06 HXO2VI-AP Dilution Fact.or: 0.L Analysis Time..: 14:35 MDL... ..: 0.31 Cadmium 20 -6 o. OsO nrS/Xg SI{845 60108 o3/o8-O3/t0/06 EI(Q2IrI-AQ DiLution Factor: 0,1 Ana1ysie Time..: 14:35 MDL... -.: 0.0082 Chromium ND 0.L5 mg/kg sw846 50108 oz/oa-oz/t0l05 HxQzvlAR oilulion Factor: 0.1 Analysis Time..: 14:36 MDL.... .r 0.036 Cobalt ND 0.50 mg/kg Sw846 50108 03/08-03/10/06 HXQ2V1AT oilution F.actoLr 0.1 Analysis Time. , ' L4:35 MDIr.. . . . t 0.022 copper ND o.25 mg/kg sw846 50108 03/08-03/10/05 HXQ2V1AU Dilution Factsorr 0.1 Analysis Time..: 14:35 MDL,.. .,: 0.0?0 r,ead 0 .80 0.1s mel/kg sw846 60108 03/08-03/L0106 E(Q2\rTAV DiluE.ion Factor: 0.1 Analysis ?ime..r 14:35 MDIr... ..: 0.03? Dilution FacEor: 0.1 Analysis Time..: 1,4!35 MDL... ..: 0.01g (Continued on nexL page) Appendix F - 118 TOTAT FIeLals Iot-Samp1e S. . . : H5B2 00 L64- 01-0 REPORTING PARAMETER RESULT LTMIT UNITS METHOD EGE,G Defense MaLeria1s, Ine. Client, Samp1e fD: $ffip1-,g 4 -A STIIT IIGTERIAL 76 tlatrix.. -.--; SOLID PREPARATION- WORK 4lvA,LYSrS pAqE__ ORpER # NickeI f-.o Selenium ND Silver ND Thal I ium ItD G Tin B-3 Vanadium ND 0.40 nrS/tg S11846 60108 O3/O8-O3{L0/06 E(Q2vrAx pilution Pactor, 0.1 Analysis Time..: 14:35 MDL... .. r 0.038 0.1-s mg/kg sw846 60r-08 03/08-03/10/q0 HxQzvrno pilution Factor: 0.1 Analysis Time..: 14:36 MDL.... .: 0.043 0.30 mg/kg sw84660108 03108-03/!0/06 HxQ2vLAL Dilution Factor! 0.1- Anal.ysis Time,, r 14r.35 MDL.... . ; 0.097 l-L. O mg/kg sw845 5o1oB o3/08-C3/aol05 HxQ2VLA2 Dilutioa Factor: 0.1 Analysis Time..: 14:36 !.tDL.... .: 0.10 1.0 rns/kg sr{845 50L08 03/08-O3/r.0/O5 E(Q2In-AA Dilutj.on Factorr 0.1 Analysis Time..: 14:35 MDL.... .t 0.o17 0.2s mg/kg Sw846 60108 03/o8-o3/t0l05 HxQ2vLAC Dilulion Factor: 0.1 Analysis TLme,.: L4:36 MDL.... . : 0,050 o-50 nrg/kg sr{846 50108 O3/O8-O3/Lol05 E(QzvreD DiluEion Fact.or: 0.1 Lnalysis Time,.: 1,4:36 MDL.... . : 0.041O zinc NO:IE (S) : 76.'7 G Elevated reporting limit. The reporting limit is elevated due to matrix interference. Appendix F - 119 BG&G Defense ltaterials, Inc , Client Sample ID: $AIiIPIfi 5 -A SUIT ITIATERIAt TOTAL Hetals Iot-Sample #-..: H6B200154-013 llatrix. : SOLfD Datse Sanpled...z al/al/06 Date Received..t 02/20/06 L7 PREPAIIJ\TION- WORK ANALYSIS DATE ORDER # REPORTING PARAMETER RESULT LIMTT UNITS METHOD Prep Batch #...: 5055255 Mercury ltD Prep Batctr S...: 5056258 .Lluminum 2L9 0.0020 mg/ks sw845 7471A 03/08/06 HXQ241AH DiluEion Factor: 1 Analysis Time,. r 14;15 MDL.... ,: 0,010 4.0 rnS/kg sw846 60L08 O3lO8-o3/L0l06 EI(Q24LA"T DiluEion Factort 0.1 Analysis Time..r 14:42 I'!DL,.,,..,.....: 1.1 O Anrimony ND 0.60 mg/kg SW846 50108 03/08-03/LO/06 HXQ241AK DiLution EacEor: 0,1 Analysis Time..r 14:42 MDL... ..: 0.14 Arsenic ND 0.20 mg/kg sW846 60108 03/08-03/10/05 HxQ24LAL Dilution Factor: 0.1 Analysis Time.. t 14t42 MDL.... .: 0,033 Barium 35r. 2.O msl/kg sW846 60108 03/08-03/T0106 EXQ24XAU DiLuEion Eactor: 2 Analysis Time.. r 23 r10 MDL... , , t Q.32 Beryllium ND 0.10 mglks sw846 50108 03/08-O3/L1/A6 I{XO241AN Ditution Factor: 0.1 Analysis Time.., la,42 MDt..., .: 0-01.8 Boron ND 2.0 mglks SW846 60108 03/08-O3/LO/06 HXQ24LAP Dilution Factorr 0.1 Analysis Time..r 1e,q2 MDL,.-, .: 0.31 cadmium 20.8 0.050 mg/ks sw846 50108 03/08-03/1-0105 m(Q241-AQ DiLution Factor: 0,1 Analysis Time., r 14:42 MDL,... ,: 0.0082 chromium ND 0.15 mg/kg SW845 50108 03/08-03/L0/06 HXQ241AR Dilution !'actor: 0.1 Analysis Time.. r 14,42 MDL.... .: 0.035 Cobalr ND 0.s0 mg/kg sw846 50108 o3/O9-fi/a0l05 HXQ24LAT Dilution Factor: 0.1 Analysis Time.., 14,42 MDL.... .: 0.02? Copper ND O.2s mg/kg Sw846 50108 03/08-03/10/05 HXQ241AU Dilution Factor: 0,1 Analysis Time.,: L4:42 MDL.... .; 0,070 Lead 0.67 0.1s mg/kg Sw845 50108 o3/o8-o3/L0lo5 HI(Q24LAV Dilution Factor: 0.1 Analysis Time..: 14:42 MDL.... .r 0.037 lilangarrese O -34 o. L5 mglkg Sw845 60108 O3loB-o3/Lo/05 H(Q241Alr Dilution Factor: 0,1 lnalysis Tine..: 14:42 MDL,.. .,: 0.018 (Continued on next page) Appendix F - 120 BGI.G Defense Materials, fnc. Client Sanple ID: SAITIPLE 5-A SUfT MATKRIAL TOTAL MetaIS : H5B20AL64- 013 REPORTING 1B Matrix- . . . . . . - . ! SOLIDIpt-Sanp1e #. PARAMETER RESULT LIMTT UNITS METHOD Nickel Selenium Si lver ThalL ium Tin Vanadium Zi'nrc, NOIE (S) : o .67 }TD ND NDG B.B ND 83-7 0.40 mg/kg Oilution Factor: 0.L 0 . l-s mglkg DiluUion Factor: 0.1 0.30 mg/kg Dilution Factor: 0.l- s . e mg/kg Dilution Factor: 0.L 1.0 mg/kg Dilution Factor: 0 .1 0.25 mg/kg Dilution Factor: 0 .1 0.5O ntg /kg Dilution Factor: 0.1 svr846 5 0108 Analysis Tirne. . : 14 :42 sw845 6010B Analysis Tirne. . : 14 t42 sw845 50108 Analysis Time..: L4242 sw845 60108 Analysis Time..: 14t42 sw846 50108 Analysis Tirne. . : L4 t42 sw84 5 5 0108 Arralysis Tirne, . : .L4 :42 sw845 50108 Analysis Time..: l.4:42 a3 / 08- a3 /Lo / 06 MDI., 93/08- 03 lLo/05 MDIJ 03/ 08- 03/Lo/06 MDL 03/08-03/Lo/06 MDL 03 / 08- 03 /Lo / a6 MDL 03/08-03/Lo/06 MDL 03l 08- 03llo/oe MDI, PREPARATION- AIVALYSTS DATE WORK ORDER # E(Q241At( : 0.038 HXQz4 r_A0 : 0.043 HXQ2 4 1A1 : 0.097 HXQ2 4LA2 : 0.10 E(Qz4IAA : 0 .077 HXQ2 41AC : 0.050 E{Q24l3D : 0.041 C Elevated reporting lirnit. The reporting lirnit is elevated due to matrix interference. Appendix 121 BG8G Defense Mat.erials, fne. Client Sample ID: SalfftlB 5-A SUfT MATERIAL TO|[AI, Meta]-s Lot-Sanple #...: H58200154-01-5 Matrix. : SOLID Date sampled.. -z ot/tt/06 Date Receiwed..t 02/20/06 PAIU\METER RESULT REPORTTNG LTMTT UNTTS METHOD 19 PREPARATION- WORK Ah]ALYSTS DATE ORDER # Prep Batch $. . . : 505 6255 ' Mercury ItD 0.0020 mg/kg, sw845 '?47LA OS/OA/O6 HXQ3D1AII DiluEion Factor: 1 Analysis Time..: 14:1? MDL..., .r 0.010 Prep Batctr #. - - : 505 5258 Aluminum 22L 4.0 ng/ks sw846 50r-oB oslos-os/roloe mrQsnLA., DiluEion Factor: O.L Anafysis Time..: L4:48 MDIr............: 1,1 Arrtimony ND 0 .50 ms/kg SW846 50r-0B 03/08-03/10/05 HXQ3D1AK Dilution Factort .0.L Ana1ysis Time,.: 1.4:48 I',!DL.... .: 0.14 Arsenic ND 0.20 mg/kg SwB45 50108 o3/o9-03/Lol06 HXQ3DI.AT, uilution Factorr 0.1 Analysis Time,,: !.4:48 l,lDrr,... .: 0.033 Barium 367 2.o mO/kg Sw845 50108 O3/o8-o3/L0/o5 EXQ3D1AU Dilution Factor: 2 Analysis Time.. t 23:L6 MDL,.., . r 0.32 Beryllium ND O.1O mg/kg SW846 5O1OB O3l08 -03/tO/06 HXQ3D1AN pilut.ion Factorr 0.1 Analysis Time,,: 1.4:48 MDL.... .: 0.0L8 Boron ND 2.0 mg/kg SW846 601-08 03/08 -03/1-0/A6 HXQ3DIAP Dilut.ion Factorr O.l. Analysis Time.. t L4r48 MDLJ.... .: 0-31 cadmium 26.9 0 .050 nrs/kg sI{845 60108 O3/OS-A3|L0/06 IIXQ3DIAQ Dilut.ion FacEolr O,1 Analysis Time..: L4:48 MDt.... ,: 0.0082 chromium ND 0.15 mg/ks SW845 50108 03/08-03/]-0/05 HXQ3DLAR Dilution FacEorr 0.1 Analysis Time.. t 74t48 MDt..,. .: 0.036 Cobalr ND O.so ras/kg SW845 60108 O3/O8-03/LOI06 HXQ3D1AT Dilution Factorr 0.1 Ana1ysi8 Time,.: L4:48 MDIJ.... -: o-Q22 copper ND 0.25 mg/kS sw845 50108 03/08-03/10/05 HXQ3D1AU Dilution Factor: 0.1 Inalysis Time..: 14:48 MDIJ,,.. .: 0.070 r,ead 0.38 0.1s nrolkg sr{846 60r-08 03108-0311-0/06 E(Q3D1AV DiluEion Factor: 0.1 Analysis Time.. t L4r48 MDt.. ...: 0.03? MangaD,ese 0.29 0.15 mg/kg Sw845' 50108 O3lo8-o3/LOl06 E(Q3D1AW Dilution FacEor: 0.1 Analysis Time.. r 14;48 MDL. ....: 0.018 (Continued on next page) Appendix F - 122 TOTAL Metals I,<>t-San4lle fi . - . : H6B2001 54 - 0 1-5 REPORTING PAIU\METER RESULT LTMIT UNITS METHOD BG&G Defense l{aterials, fnc. Client Saq>Ie ID: SercLB 5-A SUIT I{ATERIAL 20 [IatriJ(. . o . - . . . . i SoLID PREPARATION. WORK A}trALYSTS DATE ORDER # Nickel a -92 Selenium IID Silver ND Tha}lium ND G Tin 9-8 Vanadi-um ItD Zinc NOrts (S) ; 7L.g 0.40 mg/kg sw846 50L08 ollOe-O3/r0/06 E(Q3DLAn Dilution Factor: 0.1 Analysis Time..: L4.r48 MDL... ..: 0.038 0.1s mg/kg sw845 60108 03/08-A3/L0l05 rrXQ3D1Ao DiluEion Fact.or: 0-1 Analysis Time..r 14!48 MDIJ.,. ..: 0.043 o .3o mg/kg sw846 60r-08 03/08-03/1,0/06 rIXQ3D1A1 Dilution Factor: 0.1 Analysis Time..: 14r48 MDL... .-: 0.097 4.3 ms/ks SW846 60108 03/Oe-B/Lo/o6 rrxQ3D1A2 Dilution Factor: 0.1. Ana).ysis Time.,: 14:48 MDL.. - ..: 0,10 1.0 rUlXg sw846 60108 o3/os-o3/Lol06 E(Q3D1A;A Dilution Factor: 0,1 Analysis Time.. r 14:48 MDIr,.. ..: 0.O77 0.25 mg/kg sW845 60108 O3/08-o3/tol06 HXQ3DI.AC pilurion Factor: 0.1 AnalysiS Time..; 14:48. MDL,.. ..: 0.050 0.60 rqg/ks slr846 50108 o3/o8-o3/LOlOS ETQSOLaD Dilution Factor: 0.1 Analysis Time..: 14:48 MDL... ..: 0.041 G Elevated reporting lirnit. The reporting limit is elevated due to rnatrix interference. Append ix F - 123 ,o Client I,ot fi.,.: H58200L64 PARAMETER RESULT MBTEOD BLAIIK REPORT TOTAL Hetals REPORTTNG LIMIT TJNITS METHOD 27 l.Iatrix... - - - . - . r SOLID PREPARATTON- WORK ANALYSIS DATE ORDER # O MB Lot-Sarq)le #: H6C070000-255 Prep Batch *.. .: 6A66255 Mercury ND 0.0020 ms/kg sw846 147LA 03/08/06 H0QR91-AA Dilution Factor! 1 Analysis Time..r 13:49 tilB Irct-Sanqrle #: H5C070000-258 Prep Batch #..., 6055258 Al-uminum ND 4. O mg/kg SWB45 5O1OB fi/Oe-B/LOlOe riOQrerCr Dilut.ion tr'actor ! o. t Analysis Time..: L3:oo Antimony ND 0.60 mg/kg SW846 60108 03/OB-03/1-OI05 HoQTEICL Dilution Factor:0.1 Analysis Time. . : 13 :00 Arsenic ND 0.20 mS/kS sw845 SoLoB o3/o8-o3/Lol05 H0QTEICM Dilut.ion Factor:0.1 Analysis Time..: 13:OO Barium ND 0.L0 mg/kg SW846 60108 O3l08 -03/1-0/05 HOQTE1CN Dilution Factor: 0,1 Analysis Time, , : 13 :00 Beryllium ND 0.10 mg/ks Sw845 5o1oB O3loB- B/ao/05 HoeTEr.cp nilution Factor: 0.1 Analysis Time..: 13:00 Boron ND 2.0 rrtS/kg Sw846 50108 B/0e-03/a0l06 HoQTE1CQ Dilution Factor: 0.1 Analysis Time. . r L3: oO Cadmium ND 0.0s0 mg/kS Sw846 60108 03/08-03/Lol06 H0QTE1CR DiLution Factor! 0.1 Analysie Time. . : 13 :00 Chromium ND 0.15 mSlkg Sw845 50108 03/08-o3/tol05 HOQTE1CT DiluEion FacEor: o,l, Analysis Time. . r 13 :00 cobalt. ND O.sO Tns/kg SW846 6010B 03/08-03/r-0106 H0QTE1CU Oilution FacEor: O,L Analysig Time..: 13r00 (Continued on nexL page) Appendix F - 124 22 IIIBTBOD BI,ANK RBPORT IOTAL Metals C1ient Lot #--.: H5B200164 REPORTING PAIAMETER RESULT LIMIT UNITS METHOD Mat,rix. . . . - . - . . ! SOLID PREPARATION- WORK AIVALYSIS DATE ORDER # Copper ND o.2s mg/kg sw846 50108 o3/08-03/L0l06 HoQTE1CV DiluEion Fact,or: 0.1 Aralysis Time. , : 1.3 :00 r,ead ND 0.15 mg/kg sW845 60108 03/08-03/10/05 HoQTET.CW DiluEion FacEor:0.1 Analysis Time. . : 13 :00 Manganese ND 0.15 mg/kg SW845 50108 o3/08-03/Lol06 HoQTE1CX Dilution Factor: 0.1 Analysis Time..: 13r00 Nickel ND O.4O rilg/kg SW846 601-08 OZ/OA-OL/uO/05 HOQTEICO DiLutio[ Factor: 0.1 Aaalysis Tlme. . : L3 :00 selenium ND 0.15 mg/kg SW846 50108 B/OA-B(LoIo5 HoQTE1CI Dilution Factor: 0.1 Analysis Time..: 13r00 O silver o.3o mg/kg sw846 60108 03/08-O3/t0l05 H0QTE]-C2 Di]ut.ion Factorr 0.1 Analysis Time. . : 13 :00 Thallium ND 4.3 mg/kg sw846 60108 O3/o8-03/1-ol05 HoQTEIC3 Dilut.ion Fact,or: 0.1 Analysis Time., I L3:00 Tin ND 1.0 mg/kg S[,i846 60108 03/08-03/:-0/05 HOQTE]"C4 Dilution Faclori 0.1- Analysis Time.., 13,00 Vanadium ND 0.25 mg/kg SW845 50108 03/08-03/1-010'6 H0QTE1C5 Dilution Factor, 0,1 Analysis Time. . : 13 :00 zinc ND 0 .60 mg/kg SW845 501-OB O3/O8-03/tol06 HOQTET.C6 Dilutio[ Sactor: 0,1 Analysis Time..: 13i00 IiTOTB (S) : Calcularions are performed before rouoding to avoid round-olferrors in calcularcd re$ks. Append ix F - 125 ND 23 I,ABORATORY COMTROT SAII{PI,B BVALIIATION RBPORI- TOTAL Meta}s Client l,ot #. PARAMETER LCS Lot.-Sample#: Mercury LCS Lot-Sample#: Aluminum Ant imony Arsenic Barium Beryl l ium Boron Cadmium Chromium CobaIt. Copper Lead Manganese H5B2 0 0l- 54 PERCENT RECOVERY RECOVERY LIMITS 98 103 LO2 r-03 97 r"03 101 L01 99 1,02 103 METHOD MatriX. .. . . - . . - : SOLID PREPARATION- AT{ALYSIS DATE WORK ORDBR # H5C070000-255 Prep Batch #. 97 (go - 110) sw845 DiLution Fact,or: 1 H5C070000-258 Prep Batch #. . 99 ( go L10 ) sw846 Dilution Factor: l- (ee 110) sw846 Di1ution Factor: L (Ag 110) St^t845 Pi 1uc ion Fact,or : i (eo r-L0) sw846 Pi lut ion Factor ; l- ( go 110 ) sw846 Dilution Factor: 1 (eo 120) sw945 Di lut ion Fact.or r 1 (go L10) sw845 Pilucion Factor: 1 (go 110) sw946 Pilut.ion Fact.or: L (go 110) sw845 Di }ut, ion Factor : L (90 l-l-0) sw845 Pilution FacE,or: 1 ( go 1L0 ) sw846 Dilution Factor: 1 ( 9O 110 ) SW845 Di lut. i on Fact.or : 1 (Continued on 03 / 08 - 03 /70 / 05 HoQrEl-AX Time..: L3:05 03 /08 - 03 / 70 / 06 H0QrELAo Time,., 13:05 03 /oB - 03 / aa / oG HoerElAl Time,.: 1,3:06 03 /08 - 03 / 7a / 06 H0QTEIA2 Time..:13:06 03/08/05 Time,.: L3:51 03/oB-03/to/06 Time..: L3:05 03/oB-03/to/oG Time..:13:05 03/08-03/3,0/06 Time..:13:06 a3/oB-03/1,0/06 Time..', 13:05 03/08-03/ro/06 Time. . : 13 :05 03/oB-03/r-0/06 Ti-me..:13:05 03/08-03/r-0/06 Time.-: 13:05 03/08-03/r0/oe Time. . : 13 :05 . 3 505 5255 7 4_7tA Ana 1ys i s . ! 6056258 50r-08 Analysis 6 0108 Ana lys i s 5 010B Analysis 5 0108 Analysis 60r-08 Analysis 50L0B Analysis 6 01_ 0B Ana Iys i s 501-0B Ana lys i s 50t-0B Analys i s 50l-08 Analysi s 50r-0B Analys i s 5OIOB Ana }ys i s next page) H0QR91AC HoQTE1A3 H0 QTE 144 H0QTET-A5 H0QTElA5 HOQTEIAT H0QTET-A8 H0QTET-A9 HOQTETCA Append ix 126 24 LABORATORY COMIROT SAI{PLB E\fAIIIATfON REPORT TOTAL Metals Client IIot #.-.: H68200].64 PERCENT RECOVERY PAIU\METER RECOVERY LIMITS METHOD Matrif(,. . . . - . . . .. 3 SOLID PREPARATION. ASTALYSTS DATE WORK ORDER # Ni ckel 1,02 (go r.r"0) sw845 50r.08 03/08-03/L0/05 HoQTElcc oi lucion Factor: 1 Analysis Time. . : L3 : 05 selenium 98 (87 - 110) SW845 50108 O3/08-O3/L0I05 HoQTE1CD . DiluEion Factor: I Analysis Time..: 13:05 Si lver Thal1 ium Tin Vanadium Z:,t:rc NOIts (S) : L05 r-0r- r- 04 LA2 LO7 (go 110) sw845501-08 03/08-a3/L0/06 HoQTEI-CE Dilution Factor: 1 Analysis Tirne. , : 13 :05 (90 r-1-0) SW846 50108 03/08-A3/L0/06 H0QTE1CF Dilution Factor: L Analysis Time. . r 13 :05 (go 110) sw845 50108 03/08-03/L0/05 H0QTELCG Dilution Factor: L Analysis Tirne, . : 13 :05 (go 1r-0) sw845 50108 03/08-03/L0/05 HoQTE1CH pilution Factor: 1 Analysis Time. . : 13 :05 (go 1L0) sw846 50108 03/ 0B- 03/Lo/05 HOQTET-CJ oilution Factor: 1 Analysis Time. . : l-3 :05 Calculations are perforrned before rounding to avoid round-off errors in calculated resulu. Appendix F - 127 25 IJ\BORATORY CONTROL SAMPI,B DATA REPORT T0TAL lleta1s PERCNT Matrix-- --..3 SOLID PREPARATION. WORK A}UALYSIS DATE ORDER # Client Lot #--.: H58200154 SPIKE MEASI]RED PAIU\METER AMOTINT AMOUNT UNTTS RECVRY METHOD IrCS lot-Saq)Ie*: H5C070000-255 Prep Batch *...: 6056255 Mercury 0.0s00 0.0485 mg/kg 97 sW845'747l..A 03/08/06 H0QR91AC Dilution Factor: 1 Analysis Tirne..: 13:51 IrCS lot-Sample*: H5C07O0OO-258 Prep Batch *- - -: 6066258 Aluminum 20.o L9.8 mg/kg 99 SW846 50L08 03/08-03/1,0/06 H0QTEI-AX Dilution Factor: 1 Analysis Time.. r 13:06 Antimony 5. oo 4.88 ms/kg 98 sw846 60108 o3/o}.ca/ao,/05 H0QTE1A0 Dilution FacEorr Analysis Time. . | 1.3: 06 Arsenic 1.OO 1.03 mg/kg 1O3 SW845 60108 03108-03/10/06 HOQTE1A1 DiluEion Factor: 1 Analysis fime, . : 13 r 05 Barium r-.00 1.02 ms/kg ro2 sw846 5o1oB E/oe-fi/1-ol05 HoQTEIA2 oilucion FacEorr 1 Analysis Time..: 13106 Beryllium 0.s00 0.5L4 mglkg 103 Sw845 60108 03/08-03/1,0/05 H0QTE1A3 DiluEion Factorr L Analysis Time..: 13:o5 Boron r-o.o 9.77 mg/kg 97 SWB45 50108 03/08-03/LO/05 HoQTE1A4 Dilution FacEor: 1 Analysis Time. . : 13 : 05 Cadmium o.sOO 0.5L5 m /kS 103 Sw845 5O1OB B/oe-C3/LOlO5 HoQTEIA5 Dilution Factorr 1 Analysis Time..r 13:06 chromium 2.00 z.oa ms/k 101 sw846 60108 03/o8-o3/L0l06 H0QTE1A6 Dilution Factor: 1 Analysis Time..: 13:06 cobalt 1.00 1.01 ms/ks 10r- sw846 60108 03/08-03/A0/06 H0QTE1A7 Dilution Factor: I Analysis Time,,: 13:05 Copper 2.50 2.47 mS/kS 99 Sw845 50L0B 03/08-03110/06 H0QTE1AB Dilution FacEor: L Analysis Time.,. 13:05 Lead L.00 L.oz mg/ks L02 sw846 5O1OB 03108-03/r-0106 HOQTE]-A9 DlluEion Fact.orr 1 Analysis Time. . : 13:06 Manganese 1 .00 t. 03 mS/kg 103 SWB45 50108 03/08-03/l-0106 HoQTE1CA Dilution Factor: L Analysis Time..: 1.3:06 (Continued on next page) Appendix F - 128 Client Lot #, P,T]AIvIETER NickeI Selenium Si lver ThaI l iurn Tin Vanadium ZLT'IC NO(IE (S) ; . . 3 H58200]-64 SPIKE IvIEASI.]RED AMOUNT 4Irl9l8.IT I,ABORATORY UNITS Matrix.........3 PREPARATION- ANALYSIS DATE SOLID WORK ORDER # HoQTET.CC H0QTET_CD H0QTElCE H0QTElCF H0QTElCG HoQTElCH H0QTEICJ CONTROT $}I6P1g DATA REPORT TOTAL Metals PERCNT RECVRY METHOD s.00 1. s0 0.500 4 .00 5 .00 2 .00 5. 00 s -1"0 mglkg D i IuE ion 7- .47 mg/kg D i lut ion 0 . s2s mg/kg Oi Lut ion 4.03 mg/kg Pi 1ut ion s.18 mg/kg Di lut ion 2 .03 mg/kg Di Iut ion s.34 mg/kg o i }ut ion ]-02 Factor: l- 98 Factor: 1 L05 Factor: L 101 Factor: 1 104 FacLor: 1 t02 Factor: 1 t07 Factor: 1 sw845 601-08 Analysis Time. sw845 5010B Analysis Time. sI^I845 501-08 Ana lys i s Time . sI^I846 501-0B Analysis Time. sw845 5010B Analysis Time, sw845 50108 Ana lys i s Tirne . sw845 6010E} Analysis Time. 03/08-03/ro/06 13 :06 03/08-03/r0/06 13 :05 03/08- 03/1,0/06 l-3 :06 03/08-03/1,0/05 1,3:06 03/08-03/].0/05 l-3 :06 03/08-03/1.0/06 13:05 03/08-03/to/06 L3:05 Calculations are performed before rounding to avoid round-off errors in calculated results. O Appendix 129 F- o o o APPENDIX F SE,CTION 3.5 ICP Data MPF SWDT REPORT - Rev. 0 Appendix F .lune 9, 2406o TOCDF F-130 APPENDIX F SECTION 3.5.1 ICP Raw Data MPF SWDT REPORT - Rev. 0 Appendix F June 9,2006 TOCDF F-131 L26 STL Knoxville ICP Analysis Cover Sheet Chart Number:ToOtooO Date of Analysis:b-lo- og Instru ment:3U-Analyst:/<y Standard ID# Calibration Std. ID #: bo+1 - 7CCV (l:l dil. of Cal. Std. ID#): ICV ID #:bovb- I ICSA ID #:bb wtt-b ICSAB ID #:b34&b-b CRI ID #:b&b{- lo- g , b&oi-lg- g , Ll,b{- +o' I /paity As Needed Annually Check that argon manifold gas pressure is 80 psi, o Clean nebultzer and drain chamber. o Manufacturer service engineer for scheduled preventi ve maintenance service. Check that nebulizer is not clogged. n Clean filters on back of power unit to renrove dust. o Change vacuum pump oil on STI Check that capillary tubing is clean and in good condition. Replace when needed: n peristaltic pump tubing D sample capillary tubing D autosarnpler sipper probe. Check that peristaltic pump windings are secure. n Clean and lubricate autosampler AITN. Check that high voltage switch is on. n Check that cooling water supply system is full and drain bottle is not full. Check that exhaust fans are working. n Clean air filter on water cooling system. Clean plasnra torch assembly to remove accurnulated deposits. Check spray chamber O-rings Comments: MT026Rl3 .doc,9l20l05 132 727 fnstrument Upload Started Mon Mar 1-3 DaEa Fi Le : UPL$ IC{X Run Log Page 1: : 10:57:48 2005 by SZELAGOK DATA ROOT: <TJA>T031005 . ARC; 1 # WorkOrder Dilution Date Time Batch Lot Inst rument 1 S0 2 51 3S2 4 ICV 5 ICB 6 ICSA]. 7 ICSAB1 8 CRDL]- O 9 CDRLzO IO CRDL4 O 1.1 CCV1 L2 CCB1 13 HoQT2B L4 HoQT2C 1s H0QTEB 15 HoQTEC L7 HOPGEB 18 HOPGEC 1 9 HOPGEL 20 HOLJB 2T HOLJSS 22 HOLJSP 23 CCVz 24 CCB2 25 HOLJBD 26 HXQ1X 27 HXQ1XS 28 HXQ1XD 29 HXQ2H 30 HXQ2M 3 1 HXQ2V 32 HX.Q24 3 3 HXQ3O 34 HXQ1XZ5 3 5 CCV3 3 5 CCB3 37 HOHPE 3 8 HOHPM 39 HOHI\IV 4 O HOHN9 4L HOHPC 42 HOHPF 43 HOHPK 44 HOHPV 1 1 1 I 1 1 '1 1 1 1 1 1 1 I 1 1 1 1 I 1 1 1 1 1 1 10 -MAR -20A6 10 -MAR -2006 10-MAR-2005 10-MAR-2005 10 -MAR -2006 10 -MAR -2006 10-MAR-2006 10 -MAR -2006 10 -MAR - 200 6 10 -tvU\R -2006 10 -MAR -20A6 10 -MAR -2005 l,0-MAR-2006 10-I'IAR-20A6 10-MAR-2006 10 -MAR -2006 10 -MAR -2006 10 -MAR -2006 10-MAR-2046 10-MAR-2006 10-MAR-2006 10-lvlAR-2005 10-I'IAR-2006 10-MAR-2005 10 -MAR -2006 10 -MAR -20A6 10-MAR-2006 10 -MAR -2006 10 -lvU\R - 200 6 10 -I"IAR - 20 0 5 10 -MAR -2005 10 -MAR -2005 10-MAR-2005 10 -Mi\R -2005 10-M'\R-2006 10-MAR-2006 10 -lvIAR -2A06 10-MAR-2005 10-MAR-2006 10-MAR-2005 10-tvlAR-2006 10 -l\,il\R -20O6 10-MAR-2006 10 -lvti\R -2005 11:37:00 11:43 : 00 11 :49: 00 11:55:00 L2:01: 00 L2:07 :00 L2:13 : 00 12:19:00 L2:25: 00 t2:31:00 L2:37 :00 L2:43:00 t2:48: 00 t2:54 :00 13 :00:00 13 :05:00 13 :12:00 13 :18:00 13:24:00 13 :30:00 13:35:00 13:42:00 13:48:00 13 :54:00 14:00:00 L4:07:00 14 :13 :00 14 :19:00 14 : 25 :00 l-4:31 :00 ]-4;35:00 14 : 42:00 l-4:48:00 L4:54 :00 15:03:00 15:09:00 5055257 5056267 5055258 5056258 505531r- 5055311 5055311 5056267 6055267 5056267 60552s8 5056258 5066258 60562s8 5055258 60652s8 60562s8 5056258 50552s8 15 :15:00 5055311 15:25:00 505531L 15:31-:00 6055311 15:37:00 5055311 15:43:00 6065311 15:48:00 5055311 15 :54 :00 5065311 16 : qqpfl8nflffF3-:r 1 ST2 sT2 ST2 sr2 ST2 sr2 ST2 ST2 ST2 ST2 ST2 sT2 H5C070000 sTz H6C070000 sT2 H5C070000 sT2 H5C070000 sT2 H5C050000 sT2 H5C050000 sT2 H5C060000 sTz H5CO3 O 28L ST2 H5C030281 ST2 ST2 ST2 ST2 H5CO3 O 28L ST2 H58200154 ST2 H6B2 0 0154 ST2 H5B2 0 0154 ST2 H6B2 0 0154 ST2 H6B2 0 0154 ST2 H5B2 OO L54 ST2 H5B2OOL64 ST2 H5B20OL54 ST2 H5B2OOL54 ST2 ST2 ST2 H5C020293 ST2 H6C020293 ST2 H5C020293 St2 H5C020293 ST2 H5C 020293 ST2 H5C 020293 ST2 H5C 020293 ST2 H5C020293 ST2 1 1 1 1 1 1 1 1 5 (continued) - l-33 128 Instrument Upload Started Mon Mar 13 Data Fi Ie : UPL$IOIX Run Log Page 2: : 10 : 57 :48 2006 by SZELAGOK DATA ROOT : <TJA>T03L006 .ARC ; 1 # WorkOrder Dilution Date Time Batch LoE Ins t rument 10 -MAR -2006 16 :05 : 00 5055311 ' H5C020293 ST2 1O -t\4AR -20OG 15 : 12 : 00 506531L H5C 020293 ST2 10-MAR-2005 15:53:00 ST2 10-tvIAR-2O06 l7:29t00 ST2 10-MAR-2006 L7:35:00 50553L1 H5C020293 ST2 10-lvIAR-2006 L1 :41:00 605531-L H5C020293 ST2 10 -lv1]\R -2005 L7 :47 :00 5055311 H5C020293 ST2 1 0 -MAR -2006 L1 :53 : 0 0 60553 1L H5C020293 ST2 10 -l{AR -2006 17 :59 :00 5065311 H5C020293 ST2 10-MAR-2005 18:05:00 5055311 H5C020293 ST2 l-0-MAR-2005 18:12:00 50553L1 H5C020293 ST2 10-MAR-2005 LB:18:00 5065311 H6C020293 ST2 1.0 -MAR -2006 1B : 24 t O0 5 0553l-L H5C020293 ST2 10-MAR-2O05 18:30:00 ST2 10-lvU\R-2006 18:37:00 ST2 10-MAR-2006 18:43:00 ST2 10-F!\R-2006 l-8:49:00 5055311 H5C020293 ST2 10-tvlAR-2006 18:55:00 5055311 H5C020293 ST2 10 -tvlAR -2006 19 :01 : 00 5065311 H5C020293 ST2 10-l\4i\R-2006 19:08 :00 5055303 H5C050000 ST2 10-lvlAR-2006 19:14:00 5055303 H5C020253 ST2 10-MAR-2006 19:20:00 505531-5 H582802A2 ST2 10-lvlAR*2006 19:26:OO 6055315 H5B2BO2OZ ST2 10-lvlAR-2006 19:32:00 5065316 H5B28O2O2 ST2 10-tvl,{R-2006 19:39:00 5055315 H58280202 ST2 10-tvIAR-2006 19:45:00 6065315 H5B28A2A2 ST2 10 -MAR -2006 19 : 51 : 00 ST2 10-lvlAR-2006 19:57:00 ST2 10-I,IAR-2005 20:03:00 5055315 H58280202 ST2 10-t{AR-2006 20:10:00 5055315 H58280202 ST2 10 -lvIAR -2006 20 :15 : 00 5055315 H5B280202 ST2 10-tvlAR-2006 2O:22:00 5065316 H5C020293 ST2 10-tvlAR-2o06 2A:28:00 5065315 H6B280202 ST2 10 -[4AR -2006 20 :35 : 00 5065315 H5B2 80202 ST2 10 -t'{AR -2006 2O :41 : 00 6065315 H5C020293 ST2 10-MAR-2006 20:47:00 6055315 H5C020293 ST2 10 -Mi\R -2006 20:53 :00 5055315 H5C020293 ST2 10-lvlAR-2006 20;59:00 ST2 10-l4AR-2005 2\:05:00 ST2 10 -MAR -2006 2l:12 :00 ST2 10 -IvlAR -2006 2A: l-B : 00 5065315 H58280202 Sf2 10-MAR-20O6 2l:24:00 5055315 H5B280202 ST2 10-tvlAR-2006 2L:30:00 6055315 H5C020293 ST2 10-MAR-2006 2L :3Ap$gn6BfF3_03 H5ca202s3 sr2 134 4 5 HOHPX 46 HOHP1 47 CCV4 4 8 CCB4 49 HOHPS 5O HOHPSS 51 HOHPSD 52 HOHQA s 3 HoHQF s4 HoHQM ss HoHQT 55 HoHQX s7 H0HQ2 5 B HOHPs P 5 9 CCV5 50 CCB5 6L H0HQ5 62 HOHRG 63 HOHRT 64 HOPF3L 55 HOHF4 ZLO 56 HOA1 QZZO 57 HOA1R 68 HOAIW 69 H0A11 7 0 H0A12 7I CCV5 72 CCBS 7 3 H0A13 7 4 H0A14 7 5 H0A16 -t 5 H0HR0 77 HOA155 7 8 H0A15D 7 9 HOHTE 8O HOHTES B 1 HOHTED 82 HOHTRP 13 CCVT 84 CCBT B 5 HOA17 85 HoA2Q 87 HOHR4 8 8 HOHHKZLO t- 1 1 I 1 1 1 1 1 1 t 1 1 1 1 1- 1 1 1 1 10 20 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 (continued) - - - l.29 Instrument Upload Started Mon Mar 13 Data File: UPL$KNX Run Log Page 3: : 10:57:48 2005 by SZELAGOK DATA ROOT : <TJA>T031005 .ARC ; 1 # WorkOrder DiluLion Date Time Batch Lot fnsLrument B9 90 91 92 93 94 95 95 97 98 99 100 101 702 d:i 105 107 108 HOHRS HOHEH HOHEO HOHE6 HOHGL HOHE9 CCVB CCB 8 HOHFG HOHFGS HOHFGD HOHFGP HXQ2H220 HXQ2M22O HXQ2 4Z2O HXQ3DZ2O HOHPE25O HXQlXP2 s CCV9 CCB9 1 O 9 HOHPCZ2O 110 HOHPKZSO 111 H0HPXZ50 1,12 CCV10 113 CCB10 114 115 10-MAR-2006 10 -MAR -2006 10-IvIAR-2006 10-MAR-2006 10-MAR-2005 10-lvlAR-2046 10 -MAR -2006 10 -MAR -2005 10-MAR-2005 10-MAR-2045 10 -MAR -2005 t0-tvIAR.2006 10 -lvIAR -2006 10 -MAR -2006 I0 -lvil[R -2006 10 -MAR - 2005 10-MAR-2006 10-Mi\R-2006 10-MAR-2005 10-l4AR-2006 10-MAR-2005 10-MAR-2006 1l_-MAR-2006 11-MAR -2005 11-MAR-2006 r-1-MAR -2005 11-Mj\R -2006 2l:43 :00 2l:49:00 2L:55:00 22:02 :00 22:08:00 22:14:00 22:20:00 22:25:00 22:33 :00 22:39 :00 22:45 :00 22:51 :00 22:58 :00 23:04 :00 23:10:00 23:15:00 23:22:00 23 :29 :00 23:35:00 23:41:00 23:4'7:00 23:53 :00 00:00 :00 00:05:00 00:12 :00 00:18:00 00:25 :00 50553r-5 5055303 505s303 505s303 6055303 6055303 5055303 5055303 5055303 60 66258 6055258 5055258 5056258 5055311 5065311 5055311 606s311 H5C 020293 H5C02 0 253 H5C 020253 H5C 020253 H5C020253 H5C 020253 H5C 020253 H6C02 0 253 H5C 020253 H58200]-64 H5B200L54 H6B2 0 015 4 H682001-54 H6C 020293 H5C 020293 H5C0 2 0 293 H5C0 2 0 293 1 1 1 1 1 1 1 1 1 1 1 1 2 2 2 2 50 1 1 1 20 50 50 1 1 1 1 sr2 ST2 ST2 ST2 ST2 ST2 ST2 ST2 sT2 sT2 sr2 ST2 ST2 ST2 ST2 ST2 ST2 ST2 ST2 ST2 ST2 ST2 ST2 ST2 sT2 sT2 ST2 End of Report Appendix F - 13s o 130 STL Knoxville ICP Chart Review Checklist Method: 601 081200.7 - KNOX-MT-0007, Rev 5 Page I of 2 Chart Name:T-Obtoab Instrument:3r !, I I. Were all exposures for the QC standards used? B. Client Sam le and Sam Results 4. MSiMSD %R and RPD within QC limits'l lf no, list MS/MSD ID and [AutotextJ; A. Calibration/Instrument Run If No. whv is data reoortable? l. Instrument calibrated ner SOP? 2. ICV analyzed at beginning of run & within acceptance limits? (601 0B : 90 - I l0%R and <SYo RSD) QA0.7 _ 95 - 105%R and <3Y, RSD 3. CCV analvzed at reouired freouencv? 4. CCV within acceptance limits? (6010B & SDWA 200 7:90 - I10%R and <5% RSD) (CWA 200.7 = 95 - 105%R If no, list delails: CC 5. ICB/CCB analvzed at required frequenc 6. ICB/CCB within acceptance limits? (Waters/Soils S3x std. dev. of mean blank value and <MDL) (Air/SEP/PM I 0/4U <RL If no, list details: 7. ICSA/ICSAB run at required frequency'? (60108 & SDWA 2A0.7 = beginning of run; CWA 200-7 - be.ginnin.q and end of run U-bs nof *ig 'Cyd kvg, oq 8. ICSAB interferents and analytes within limits? (80 - 120%R 9. ICSA criteria for non-interfering elements rnet? lf no, list analytes' ?iL icslJ Results outside limits due to contamination. U [ics2] Interfering elements not present in sarnple at Ievel which would result in false result >+2x RL. o [ics3J Concentration of affected analyte in sample is more than 10x analyte sienal in ICSA. 10. Reporting Linrit Check Standard (CRDL) within limits? (70-130%R; 80-120%R for DOD QSM; 50-150% for Air/SEP/PM l0i4U) If no, Iist details: l. Were samples with concentrations > the linear range for any parameter diluted and reanalyzed? Comments: 2. For DOD QSIVI projects, were sarnples with concentrations > the high calibration standard for any parameter diluted and reanalyzed'? tr High-calibration check standard analyzed instead of runnins samoles at a dilution. Results + l0o/o. 3. Were RLs elevated due to matrix effects?Comments: 4. Internal standard (lS) response t30% of ICB IS? If no, list cletails: n [isJ High IS response. Sample(s) rerun at dilution. tr Low IS response. Sample(s) reanalyzed. C. Preuaration/Matrix I . Method blank done per prep batch and within limits? (Waters/Soils/Waste - '/z RL; Air/SEP/PM l0/4U <RL) l.f no, list blartk lD and reason, i.e. [AutotextJ : Blank lD [Autotextl Blank ID [Aut_ptex-A n [mb3J No analyte >RL in associated samples.* O [mb4J Sample results >l0x blank. tr [mbs] Insufficient sample for reanalysis.* 2. LCS done per prep batch and within QC limits? IJ'no, list LCS ID. n [cs2l Insufficient sample for reanalysis. O flcs3l LCS recovery > QC limits and sample results are ND. 3. MS/MSD or MS/DUP run at required frequency?n ilcsdl Insufficient sample - lcs/lcsd anal [ms1J [msd1] LCS acceptable - matrix effects. [ms2] [rnsd2J Native analyte > 4x spike level. [ms3] [msd3] Matrix effects and native analye > 4x spike level. 136 MT02 1 Rl4.doc, I 0/l 8/05 [Autotg.xtl MS/MSD lD [4uto!ex-tl. 131 STL Knoxville ICP Chart Review Checklist Method: 60108/20A.7 - KNOX-MT-0007, Rev 5 Page 2 of 2 Chart Name:0b loo 4. Were alt sanrples labelled correctly in the autosampler table? If No. whv is data renortable?C. Preoaration/Matrix OC (continued 5. PDS or PDS/PDSD analyzed at required frequency? PDS ID Spike Level CLQC or Batch 6. Serial dilution done per prep batch? Comments: 57 . Was serial dilution reanalyzed at a dilution? 8. Was the original sample analyzed on same chart as serial dilution?If no, list details: D. Other l. Are nonconformances documented appropriatel 2. Calculations checked for error'? (Document manual calculation checks in comments section. 3. All client/project specific requirements met? (Review PM checklists, Lot Summary or Client Analysis Summary, QAS) List requirements added since log-in: If no, list details: Analyst J-b Date: 5- l?5- O b Comments: \' \I {(/+{'?l{ lfu,t l[,b\\ l,,^olt Y V.lOOl- / l.Ola = I2lo, al rtua ltk. I /d t(4',4 NOTE: Nonconformance menros are required for boltl and italicized [autotext] Appendix 137 statements: F. Bold - deficienCy, italicized - anomoly MT02 I Rl4.doc, I 0/1 8/05 Prof i le l ine : Peak Pos it ion : Peak IntensitU: Peak tlid th : Heu Snec, Sh i ft ffs tBg ,042{2 ,06380S 4864. {g i . 909?? at:0 tF*I 0 T IJ rl tll, L 0l # E H $ neet run $h i f ter Pos i t ion I Appendix F - 138 133 AutoSampler Report Tab1e: NEW 03/70/06 11:09:51 AM Table Name: NEW Autosampler T)4)e: TYPE TJA Sample Positi-ons. 0/1,92 QC Positioos: 6/7,9 # Sets: 1 Rinse Station location is rack -1, pos. -1. Rack # T)lpe Usage #Pos Left Analys es / Pos page 1 Sample Sets SeL# Type Prepare? Description 10 1 1 1 1 Method #Pos Rack# StartPos 1 Aux. (L) Rack 2 Samp1e ( 15mm) 3 Sample ( 15mm) 4 Sample ( 15mm) 5 ampl-e (15mm) srD / acler,AlTr Sampl e s Samples Samples Samples 6 0 0 0 0 1 Normal No Preparation Info Set# Uptake Uptake#2 Final DiI . Factor No Samples Prepared. Rack #1 TRA20505 A92 2 1 O Pos Row col Sample Name Set # #Used Type 1 1 1 S0 2 1 2 51 31352 4 1 4 ICV 515CCV1 616CCV2 717CCV3 BlBCCV4 919CCV5 10 1 10 CCVS 11 1 11 CCVT 12 1 1,2 CCVB 13 1 13 CCV9 (14. . .19 Not Used) Rack #Z Pos Row CoI Sample Name -NA- 1 Standard -NA- 1 Standard -NA- 1 QC Standard -NA- 1 QC Standard -NA- 1- QC Standard -NA- 1 QC SLandard -NA- 1 QC Standard -NA- 1 QC Standard -NA- 1 QC Standard -NA- 1 QC St.andard -NA- 1 QC Standard -NA- 1 QC Standard -NA- 1 QC Standard Set # #Used Type 1 1 1 ICB 2 1 2 ICSA1 3 1 3 ICSAB1 4 1 4 CRDL1O 5 1 5 CDRL2O 6 1 6 CRDL4O 717CCB1 B 1 B HoQT2B 1 -NA- Sample 1 -NA- Sample 1 -NA- Sample 1 -NA- Sample 1 -NA- Samp1e 1 -NA- Samp1e 1 -NA- Sample 1 - NA- Samp le Appendix F - 139 134 Aut.oSampler Report Rack #Z Tab}e: NEW Pos Row CoI Sample Name 03/\0/06 11:09:51 AM Set # #Used Tlpe page 2 9 10 11 72 13 1,4 15 76 77 18 L9 .20 2t 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 3B 39 40 4t 42 43 44 45 46 47 4B Rack #3 9 H0QT2 C 1 0 HoQTEB 11 HoQREC 72 HOPGEB 1 HO PGEC 2 HO PGEL 3 HOLJB 4 HO LLTB S 5 HOLJB P 6 CCB2 7 HOLJBD B HXQ1X 9 HXQ1XS 1 0 HXQ1XD 11 HXQ2H 1,2 HXQ2M 1 HXQ2V 2 HXQ24 , 3 HXQ3D 4 HXQ1XP 5 CCB3 6 HOHPE 7 HOHPM B HOHNV 9 HOHN9 10 HOHPC 11 HOHPF 72 HOHPK 1 HOHPV 2 HOHPX 3 HOHP1 4 CCB4 5 HOHP6 5 HOHP6 S 7 HOHP6D B HOHQA 9 HOHQF 10 H0HQM 11 HOHQT L2 HOHQX 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 -NA- -NA. -NA- -NA- -NA- -NA- -NA- -NA- -NA. -NA- -NA- -NA- -NA- -NA. -NA- -NA- -NA- _NA- -NA. -NA- -NA- -NA- -NA- -NA- _NA- -NA- -NA- -NA- _NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- Set ##Used SampIe Sample SampIe SampIe SampIe SampIe Sample Sample SampIe Sample SampIe SampIe SampIe SampIe SampIe SampIe SampIe SampIe Sample Sampl e SampIe SampIe Sample SampIe SampIe SampIe SampIe SampIe SampIe Sample SampIe SampIe SampIe SampIe Sample Sample Sample SampIe Sample SampIe TypePos Row CoI Sample Name 111 212 313 414 515 616 717 B1B H0HQ2 HOHP5 P CCB5 H0HQ5 HOHRG HOHRT HO PF3 L HOHF4 ZAO 1 1 1 1 1 1 1 1 Appendix 140 -NA- .NA- -NA. -NA- -NA- -NA- _NA- -NA- SampIe SampIe SampIe SampIe SampIe SampIe Sample SampIe 135 AutoSampler Report Rack #: Table: NEW Pos Row CoI Sample Name 03/to/06 11:09:51 AM Set # #Used Type page 3 91 10 1 11 1 1,2 1 13 2 l-42 15 2 15 2 L72 18 2 792 202 21, 2 222 232 242 253 1C 2/JU, J 273 283 293 30 3 31 3 323 33 3 34 3 3s 3 36 3 374 38 4 39 4 40 4 474 424 434 444 454 46 4 474 484 Rack #q H0A1QZ20 HOAlR HOAlW HOA11 HOA12 CCB6 HOA13 HOA14 HOA15 HOHRO HOA15 S HOA15D HOHTE HOHTES HOHTED HOHR4 CCBT LIrlAl ?I I \.r11-L / H0A2Q HOHTEP HOHHKZAO HOHRB HOHEH HOHEO HOHES HOHGL HOHE 9 CCBB HOHFG HOHFGS HOHFGD HOHFGP CCB 9 empty empty empty empty empty empty 9 10 11 1_2 1 2 3 4 5 6 7 B 9 10 11 \2 1 1 L 3 4 5 5 7 B 9 10 11 1_2 1 2 3 4 5 6 7 B 9 10 11 1,2 .NA. -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- _NA- .NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- _NA- _NA- -NA- -NA_ -NA- -NA- -NA- -NA- _NA- -NA- -NA- -NA_ -NA- -NA- -NA. -NA- -NA_ SampIe Sample Sample SampIe Sample Sample Sample Sample Sample Sample SampIe SampIe SampIe Sample Sample Sample SampIe Sample Sample SampIe Sample Sample S arnp 1e Sample Sample Sample SampIe Sample Sample SampIe Sample Sample SampIe Sample -NA- -NA- -NA- -NA_ -NA- -NA- Pos Row Col Sample Name Set. ##Used Type 1 1 1 1 1 1 1 1 1 2 3 4 5 6 -7 B 1 2 3 4 5 6 7 B empty empty empty empty empty empty empty empty 1 1 1 1 1 1 1 1 Appendix F 141 -NA_ -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- _NA- -NA_ 135 AutoSarnpler Report Rack #q Tab1e: NEW Pos Row Col Sample Name 03/70/06 11:09:51 AM Set # #Used T)pe page 4 9 10 11 !2 13 a4 15 16 1,7 1B 79 20 2L 22 23 24 25 26 27 2gi 29 30 31 32 33 34 35 35 37 3B 39 40 41 42 43 44 45 45 47 4B Rack #S Pos Row CoI Sample Name -NA- .NA- -NA- NA_ -NA- .NA- -NA- -NA- -NA- .NA- -NA- .NA_ -NA- -NA- -NA- -NA- -NA'- -NA- -NA- -NA- -NA- .NA- -NA- -NA- -NA- -NA. -NA- -NA- -NA_ -NA- -NA- -NA- -NA- -NA- -NA- -NA- _NA- -NA. _NA- -NA- -NA- -NA. -NA- -NA- -NA- -NA. -NA- -NA- .NA- -NA- -NA- -NA- -NA- -NA. -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- _NA- -NA- -NA- -NA- -NA_ -NA- -NA- -NA- -NA- -NA_ -NA- -NA- -NA- .NA- -NA- -NA- -NA- -NA- Set # #Used T)rpe 9 10 11 72 1 2 3 .4 5 5 7 B 9 10 11 L2 1)L 3 4 5 6 7 B 9 10 11 1,2 1 2 3 4 5 6 7 B 9 10 11 1,2 empEy empty empty empty empEy empty empty empt.y empt.y empty empt y empty empty empty ernpty empt.y empty empty empt y empty empty empty empty empty empty empty empIy empty empty empty empty empty empty empty empty empty empty empty empty empt y 1 2 3 4 5 6 7 B 1 1 1 1 1 1 1 1 1 2 3 4 5 6 7 B empty empty empty empty empty empt y empty empty 1 1 1 1 1 1 1 1 Appendix F - 142 -NA- -NA- .NA- -NA- -NA- -NA- -NA- _NA- -NA. -NA- -NA- -NA- -NA- -NA- -NA- -NA- L37 AutoSampler Report Rack #S Table: NEW Pos Row CoI Samp1e Name 03/to/06 11:09:51 AM Set # #Used Type page 5 9 10 11 1,2 13 a4 15 76 77 1B 1,9 20 2t 22 23 24 25 26 27 28 29 30 31 32 33 34 35 35 37 3B 39 40 47 42 43 44 45 46 47 4B 9 10 11 1_2 1 2 3 4 5 6 7 B 9 10 11 72 1 2 3 4 5 6 7 I 9 10 11 72 1 2 3 4 5 6 7 B 9 10 11 t2 empty empty empty empt.y empty empty empty empty'empty empty empty empty empty empty empty empLy empty empty empty empty empty empty empty empty empt,y empty empty empty empty empty empty empty empt.y empty empty empty empty empt.y empty empty -NA- -NA- -NA- -NA- -NA_ .NA. -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA. -NA- -NA- -NA- -NA- -NA. -NA- -NA- -NA- -NA- _NA_ -NA- -NA- -NA- -NA- -NA- -NA- -NA. -NA- -NA- .NA. -NA- -NA- -NA- -NA- .NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- .NA- -NA- .NA- -NA- -NA- -NA- -NA- .NA- -NA- .NA. -NA- -NA- -NA- -NA- .NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- Appendix 143 13 B Standardi zaLion Rpt . Method: TRA20505 Standard: Run Time: 03/ao/aG 11:37:5t 03/ao/oe 11:43:45 AM A1 . 0247 5 .00028 1 . 14 B 0 . 0247 7 .025 04 .02448 Cr .00296 .00153 s1. 432 .00466 .00254 .001,69 Mn .00025 .00015 57 .07 4 .00035 .00031 .00009 02644 03107 028 67 Ti - .00064 .00009 13 .834 00054 00057 00071 Sb .00783 .00780 99 .632 . 01 1,07 .01348 - .00107 Co - .00049 .00007 1s.058 - .00041 - .00054 - .00054 K_ .25555 .004a9 1.5954 .26A23 .2547 B .25364 00131 00089 00089 O12BB 0115 s 00629 0004s 04129 01480 .00407 .004a6 .00401 Fe - .00059 .00018 26 .1 93 00053 00054 00089 07977 02402 029 43 05393 05415 0542l- Pb/7 .05667 .01855 32 .7 42 . 05 949 .07366 .03 687 .01560 .01326 .01641 Mo - .00154 .00053 34.350 - .00118 -.00274 -.00729 .007l-0 .005s6 .00437 page 1 Ca -.00442 .00008 1.7902 00448 00433 00445 .00086 .00009 - .00036 Na .00307 . 0 01,69 55.018 . 00 484 .00290 . 0 01,47 Sr .00191 .00015 7 . 8867 .00208 .00779 .00a81 EIem Avge SDev ?RSD #r #z #a EIem Avge SDev ?RSD #r #z #: Elem Avge SDev %RSD #r #z #r Elem Avge SDev ?RSD #r #z #: Elem Avge SDev ?RSD #r #z #: SO As Ba - .0088s .00405 .00748 .00003 84 .534 .75745 Be Cd - .05410 .00501 .00015 .00L45 .27 899 24.053 Cu .00111 .00005 5 .4503 . 0 0118 . 0 01,07 . 0 01,07 Ni .00050 .000L7 28 .64a .00058 .00071 .00040 Zn .0001,2 .00414 71,4.05 .00009 .00000 .00027 01465 0]-47 B 01,452 Pb/2 Mg -.01309 .00020 .00150 .00061 1t-. 439 311. BB 01456 0115 5 013 15 Se/ t se/ 2 -.02420 .01509 .00513 .00163 2L.204 10. 832 Ag . L246B .0021_0 1.6870 . 1271,1, .723 44 .1-23 5 0 Lr .00046 .00034 74.059 .00086 . 00 022 .00031 T1 V_ - .02873 .00103 .00237 .00024 B . 0 5'71, 23 .424 B_ .001,79 .00035 19.531 .002a2 .00183 .001-43 P- . 117 37 .00115 .97954 .11730 . 11 625 .1185s Appendix F - 144 Sn Si -.0L027 .01468 .00351 .00008 34.742 .56488 13 9 Standardi zation Rpt. NOTUSED NOTUSED 03/lA/06 11:43:45 5 NOTUSED AM 6 NOTUSED page 2 7 NOTUSED Intstd 1 Mode Counts Elem Y Wavlen 371. 03 0 Avge 223L7 SDev 15 9 . 41,7 9 ?RSD .759L332 2 NOTUSBD #r #z #: 221,22 22400 2243 0 Appendix F 14s 140 Standard:-zaiuion Rpt. MeLhod: TRA20505 Standard: Run Time: 03/Lo/06 11:43:50 03 /to / 06 11 : 49 :42 AIvl A1 5.3965 .0143 .223 1 5 6 .4129 6.3896 6.3870 Cr 8.7607 .0259 .29546 8.7 310 8.7 7BB 8.7723 Mn -l .9617 .0294 .36909 7 .9299 7 .987 9 7 .9573 TI 4 .27 49 .0236 . s5l-20 4 .2495 4.296]' 4 .21 89 Ti 3 .13]-2 .0058 .18415 3 . 1250 3 .1324 3.1363 Sb 3.0148 .0102 .33805 3.0038 3.0240 3.0765 Co 2.8584 .0143 .49883 2 .8431, 2 . 871,3 2 .8607 K- 18.742 .096 .51054 18. 852 18.'702 18. 673 V_ 1.7 869 . oo42 .23'7 33 I .7 821, 7."7 900 1,.7 BB7 Sn 25.800 .099 .38253 25 .681 25.868 25 .845 S1 As 4 .00'75 .0050 .42453 4.0104 4.0103 4.0077 Cu 1.9345 .0079 .41_058 1.9433 1 . 9325 1.921 8 Ni 2.9063 .0157 . s3933 2.BBB5 2 - 9t82 2 .9123 Zn 9 .9497 .03s1 .35274 9.9095 9.9-763 9.9515 Si .50521: .00095 .18834 .50432 .50622 .50510 Ba 8.5835 .0283 .32913 8.5151 8.5744 8. s608 Fe 2 .5928 .0112 .41,589 2 .6802 2 .7 01,1 2 .6964 Se/t 2.71,94 .0153 . s6432 2.72L6 2.7334 2.7 031 B_ 3 .16s1 .00s0 . 15 929 3.1689 3.1672 3.1594 P- 4 .969s .01,49 .29899 4.9550 4.9688 4 - 984'7 Be 18 . 31,2 .0s5 .30298 18.252 18.360 1B . 326 Pb/r- 13 . 067 .057 .43s69 13 .005 13 . 115 13 .081 Se/2 3 .0389 .01-67 .54905 3 .03L4 3 .0580 3 .0273 Mo 5.4559 .0156 .30462 5 .431 B 5 .47 05 5.4595 Cd 18 . 582 . 101 .54L74 18.556 18 -'74A 18. -740 Pb/2 5. B980 .067 2 .97 440 Ag s.5062 .0027 .04855 5.5080 5 . 6 077 s.5031 Li 26 .702 .202 .77418 25.334 25 .01 0 25 .963 page 1 Ca 2s .967 . 119 .45823 25.833 26 .052 25.004 Mg 29.a66 .1,7 B .51135 Na 1.8513 .0058 .31547 1.8566 1. B52t 1.8450 Sr 4L .6 01 .108 .25854 47 - 71_2 41, .595 41, . 49'7 EIern Avge SDev ?RSD #r #z #: Elem Avge SDev ?RSD #r #z #: Elem Avge SDev ?RSD #r #z #: Elem Avge SDev ?RSD #t- #z #: Elem Avge SDev ?RSD #r #z #: 6 6 6 B2l9 28 .9 6 0 9492 29 .269 9228 29.269 Appendix F - 146 141 St.andardi zation Rpt 03/70/05 11:49:42 AM 5 NOTUSED page 2 NOTUSED NOTUSEDNOTUSED NOTUSED NOTUSED IntStd Mode EIem Wavlen Avge SDev ?RSD #r #z #: 1 Count s Y 37l..030 21,32L 131.5450 .6A7 4560 21,47 2 27252 21,238 Appendix F - 147 ]-42 Standard LZat ion Met.hod: TRA20505 Report 03/70/06 11:49:43 AM Slope _ Conc (SrR) /IR Y - intercept - .194-726 - . 0 02462 .002l-69 - .001887 .011583 - .000323 . 017 024 - .001354 .000690 - . 0 02287 .012807 - . 0 04464 .0018'74 . - . 0 0067 6 - .000128 .090051 - .000825 .008837 - . 0 04923 - .045519 - .004090 .012641, - . 0 02242 - .000048 - . 0 02268 .00LL27 - .000071 - .000184 .000820 . 0 01,592 - .1]_9724 - . 0 96951 .000000 .000000 page 1 Date Standardized 03/70/0G 11:43:50 03 / t0 / 06 11 :43 :50 03/ao/06 11:43:50 03/to/06 11:43:50 03 /1,0 / 05 11 :43 : 50 03/a0/06 11:43:50 03/1,0/06 11:43:50 03/:-0/A6 11:43:50 A3/70/06 11:43:50 03/10/06 11:43:50 03/J.0/06 11:43:50 03/70/06 11:43:50 03/70/06 11:43:50 03/1,0/06 11:43:50 03/1,0/a6 11:43:50 03/lo/06 11:43:50 03/1,0/06 11:43:50 03/ao/oa 11:43:50 03/to/06 11:43:50 03/1,0/06 11:43:50 03/1,0/05 11:43:50 03/L0/oG 11:43:50 03/to/06 11:43:50 a3/:-0/a6 11:43:50 03/ao/06 11:43:50 03/1,0/06 11:43:50 03/ao/oe 11:43:50 03/ao/a6 11:43:50 03/1,0/oG 11:43:50 03/1,0/a6 11:43:50 03/:-0/06 11:43:50 03/ t.0/05 11:43:50 *NOT STANDARDIZED *NOT STA\TDARDIZED B1 ement A1 Sb As Ba Be Cd Ca Cr Co Cu Fe Pb/t Pb/2 Mg Mn K_ Ni Se/r Se/2 Ag Na T1 V. Zn B_ Mo Li Sr Ti Sn Si P Wave I en 308.21,5 206. B3B 189 .042 493 .409 313 .042 226 .502 3t'7.933 261 .7 t4 228 . 51,5 324 .1 54 271 .44A 220.351 220 .352 2-79.079 2s7.610 7 66 .49a 231 .604 t96 .02a 196 .022 328.068 330.232 190.864 292 .402 273. Bs5 249.678 202.030 67A.784 421_ .552 334 .94l- 189.989 2BB.15B t7 B .287 220.3s3 796 .026 High std S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 S1 NONE NONE Low std SO SO SO SO SO SO SO SO SO SO SO SO SO SO SO SO SO SO SO SO SO SO SO SO SO SO SO SO SO SO SO SO NONE NONE S lope 7 .8631,9 .314528 .245146 .466232 .215959 .053120 3.85046 .456537 1,.40159 2.0588s 18. 6494 .078776 .l-43 169 3 .4287 0 . 5 0 2421, 1.00]-2s 1.37957 .35s099 .326338 .3 5507 9 .85640s .440025 2.17261, .403883 a .26448 .732939 .153245 .096244 1, . 27 7l.9 .154975 8.15445 .825137 1.00000 1.00000 Pb Se Appendix 148 L43 Analysis Report Method: TRA20505 Run Time: 03/lo/06 Comment: Mode: CONC Corr - EIem AI Units ppm Avge A2.556 SDev .008 ?RSD . 05 275 #r #z #: t2 .57 5 L2 .5 61 t2 .562 Errors QC Pass Value L2.500 Range 10.500 EIem Cr Units ppm Avge 1.0053 SDev .0025 ?RSD .24446 #r #z #s 1.0084 1.0035 1.0058 Errors QC Pass Value 1.0000 Range 10.500 Elem Mn Uni t s pprn Avge 1.021,7 SDev .0039 ?RSD .37139 #r #z #: 1.0248 1.0174 1.0229 EIem TI Uni t s pprn Avge .50570 SDev .00229 ?RSD .452L4 QC Standard Sample Name: 11: 49:46 Factor: 1 Sb pprn .2497 2 .00297 1.1883 .24991 .25258 .24665 03/7a/06 11:55:39 AM Operator: page 1 Cd Ca ppm ppm .25809 25.67l- . 00 025 .062 .09167 .24223 S2 As ppm .2537 3 .00090 .3s587 .2547 5 .25343 . 253 02 Cu ppm 1.0068 .0043 .42335 1. 0a1'7 1.0049 1.0038 N1 ppm 1.021,7 .0025 .24553 1.024]- 1.0191 1.0220 QC Pass 1.0000 10 .500 Zn ppm 1.0527 .0021 .19651 1.0550 1.0610 1.0620 Ba ppm 1.0184 .0024 . 23 928 QC Pass 1.0000 10.500 Fe ppm t2 .695 .033 . 263 67 1-2 .7 28 72 .66l. 72.598 Se/t ppm .25022 .00250 .99865 .2s311 .24855 .24892 NOCHECK B- ppm .997 44 .00494 . 4957 3 1.0031 .99404 .99517 o2t2 .1 . 0326 0L77 1.02'70 01,64 1.0304 Be ppm 1.0300 .0028 .27105 QC Pass 1- 0000 10.500 Pb/t ppm .251,99 .00270 1.07L4 .25185 . 2493 5 - 2547 5 Se/z ppm .25315 .00177 .67759 .25444 . 2s3 82 .2572A Mo ppm 1.0040 .0056 .55283 1.0104 1.0003 1.0014 QC Pass .25830 .257 Bt .25817 Pb/ 2 ppm .25484 .00087 .34253 .25454 .25582 .254L6 Ag pprn .49915 .001,66 .33233 Li ppm 1.0301 .0012 .11887 1.0295 1.0315 1.0293 25 .676 25.6s8 25.-l3B Mg ppm 24 .344 .059 .28510 24.389 24 .254 24 .37 B Na ppm 25 .202 . 115 .45839 Sr ppm 1.0449 .0018 . t-7 702 1 . 0 466 1.0449 1.0430 QC Pass 1 1 1 QC Pass QC Pass .25000 .25000 10. s00 10.500 QC Pass QC Pass .25000 25.000 10. s00 10.500 #r #z #: Errors .50430 .50446 . s0834 QC Pass Co ppm 1.0109 .0035 .3528a 1.0L44 1.0072 1.0109 K- ppm 25.303 .058 .27044 25.242 25.377 25 .291, V_ ppm 1.0111 .0007 . 07 a25 1.0119 1.010s 1.0108 QC Pass QC'Pass QC Pass 1.0000 1.0000 10. s00 10. s00 QC Pass NOCHECK l-2.500 10.500 NOCHECK QC Pass 25.000 10.500 . 50 047 25 .070 . 491 28 25 .285 .49969 25 .25a Errors QC Pass QC Pass Va1ue 1.0000 25.000 Range 10.500 10.500 NOCHECK QC Pass QC Pass .50000 25.000 10.500 10.500 QC Pass QC Pass Appendix F - 149 QC Pass L44 Analysis Report QC Standard 03/ao/oG 11:55:39 AIvl page 2 Value .50000 1.0000 1 . 0000 1 .0000 1. 0000 1.0000 1.0000 Range 10.500 10.500 10.500 10.500 10.500 10.500 10.500 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge 1.0148 .99303 1.0528 L.0238 .25428 .25250 SDev .0015 .00294 .0062 .0044 .00046 .00178 ?RSD .14515 .29609 .58846 .43050 .L7929 .70359 #1 1.0151 .99513 1.0593 a.0242 .2540L .2543L #2 L.0L32 - .98967 1.0519 1.0193 -25403 .2524L #3 1.0152 .99429 7.0470 1.0281 .25481 .25076 Errors QC Pass QC Pass QC Pass QC Pass QC Pass QC Pass Value 1 . 0000 1. 0000 1 : 0000 1 .0000 .25000 .25000 Range 10.500 10.500 10. s00 10.500 10.500 10.500 Intstd 1 Mode CounLs EIem Y Wavlen 371,.030 Avge 22049 . SDev 702 .0964 ?RSD .4630392 #r 2]-958 #z 221,60 #: 22029 234s67 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 150 14 5 Analysis Report QC Standard Method: TRA20505 Sample Name: ICV Run Time: 03/!0/05 11:55:43 Comment : Mode: CONC Corr. Factor: 1 03/70/06 t2:01:35 PM Operator: Sb ppm .24805 - 001,17 .1 1247 . 247 26 .25008 .24582 Co ppm 1 . 0 096 .0079 .77974 1.0777 1.0091 1.0020 As ppm .25621 .00154 .50063 .25'7 44 .25685 .25453 Cu ppm 1.0090 .0042 .47355 1.0L34 1.0085 1.0051 Ni ppm 1.0250 .0051 . s0229 Ba ppm 1.0155 .0038 .37 844 1.0195 1.01s3 1.0118 QC Pass 1.0000 10.500 Fe ppm 12 .566 .091 .71,925 L2.735 L2.700 t2 .562 Se/t ppm .25496 .00424 7.6639 .2592-7 .25482 .250'79 Be ppm 1.0330 .0038 .36550 1.0355 1.0335 1.0290 Pb/L ppm .25s7 0 .00225 . BBl57 .25829 .254]-4 .25468 Se/z ppm .254 5 0 .00188 .14009 .25233 .25544 .2557 3 Mo ppm 1.0038 .0046 .45813 1.0085 1.0033 .99946 QC Pass Cd ppm .2s895 .00109 . 421,7 I .2599s .25910 .257 7 9 Pb /2 ppm .251,92 .0027]- 1.0757 .25028 .25504 .25043 Ag ppm .50011 .00274 .548s5 .50240 . s0085 . 497 07 Li ppm 1.0238 .0047 .45982 1.0287 1.0236 1.0193 QC Pass page 1 Ca ppm 25.5s9 .080 .3119s 25 .645 25 .54l- 25 .490 Mg ppm 24.363 .464 .67392 24 .468 24 .448 24 .1,7 4 Na ppm 25.095 .250 .997 40 25 .37 9 24 .999 24.90'7 Sr ppm 1.0403 .0061 .59045 1.0474 1.0363 1.0372 QC Pass EIem A1 Units ppm Avge 12.515 SDev .064 ?RSD .s0894 #r #z #: 72 .587 t2 .489 t2 .468 Errors QC Pass Value L2.500 Range 10.500 EIem Cr Uni t. s ppm Avge 1.0038 SDev .0085 ?RSD .84977 #r #z #: 1.0099 1.0073 .99404 Errors QC Pass Value 1.0000 Range 10.500 Elem Mn Units ppm Avge 1.0197 SDev .0078 ?RSD .7 6204 #r #z #3 1.0258 1.0224 1.0109 Errors QC Pass Value 1.0000 Range 10.500 EIem TI Units ppm Avge .50638 SDev .00L66 ?RSD .32854 #r #z #: Errors .50725 .50446 .50742 QC Pass K_ ppm 25 .046 .105 .42316 25 .161 25 .022 24.953 QC Pass QC 25.000 1. 10.500 10 V_ ppm 1.0087 .00s6 .55'775 1.013s 1.0101 1.0025 QC Pass B_ ppm 1 . 0 043 .0062 .51673 1.0079 1.0080 .997L9 Pass QC Pass Appendix F - l5l QC Pass QC Pass .25000 .25000 10.500 10.500 QC Pass QC Pass QC Pass 1.0000 .25000 25.000 10.500 10.500 10.500 QC Pass QC Pass 1.0000 1.0000 10.500 10.500 QC Pass NOCHECK l.2.500 10.500 NOCHECK QC Pass 25.000 10.500 1 1 1 0309 0279 o22t Pas s 0000 .500 NOCHECK NOCHECK QC Pass QC Pass .50000 25.000 10.500 10. s00 Zn ppm 1.0655 .0054 .50427 1.0771 1.0648 1.0605 QC L46 Analysis Report QC Standard 03/70/06 t2:01:35 PM page 2 Value .50000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 Range 10.500 10.500 10.500 10.500 10.500 10.500 10.500 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge 1.01-53 .99551 1.0550 1 - 0304 .25357 .25497 SDev .0040 .OO477 .0067 .0038 .00144 .00058 tRSD .39510 .47884 .63667 .37024 .56794 .22597 #1 1-.0206 1 .0001 L.0624 1. 0340 .25336 .25495 #2 1 .0158 .99837 1 . 0565 1. 0309 .25511 .25555 #3 1.01-26 .99109 1.0490 1.0264 .25225 .2s440 Errors QC Pass QC Pass QC Pass QC Pass QC Pass QC Pass Value l-.0000 1.0000 1.0000 1.0000 .25000 .25000 Range 10.500 10.500 10.500 10.500 l-0.500 10.500 Intstd 1 Mode Counts EIem Y Wavlen 37L.030 Avge 27991, SDev 1,62.7801 ?RSD .7 402048 #r 27860 #z 21947 #g 22L73 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 1s2 74"7 Analysis Report Method: TRA2 0505 Sample Name : ICB Run Time: o3/10/06 72:01:38 Comment : Mode : CONC Corr. Factor: 1 03/to/06 72:07:30 PM Operator: Sb ppm .00053 .00053 100.57 .00043 .00006 . 0 0111 Co ppm - .00024 .0002L 84.308 - .00040 - .00001 -.00032 LC Pass . 00 220 -.00220 K- ppm .10930 .00055 .59813 .10877 .11003 .10909 V_ ppm - .00043 .00072 167 .20 -.00t25 .00013 - .00018 LC Pass As ppm .00011 .00181 7621 . 1 .0008s .00L44 - .00195 Cu ppm - .00031 .00035 111 .07 -.0002L -.00003 - .00070 LC Pass .00700 - .00700 Ni ppm -.00053 .00030 56 .284 00019 00075 00064 Zn ppm .00009 .00005 56.165 .00006 .00016 .00005 Ba ppm - .00003 .00002 s3 .355 00001 00004 00003 Fe ppm - .00160 .00597 373 .07 -.00762 .00433 - .00151 LC Pass .04900 -.04900 Se/r ppm .00052 .00365 697.1s .00450 -.00267 -.00426 B_ ppm .001,24 .00061 49.503 .00155 .001,64 .00053 Be ppm .00024 .00014 55 .722 .00010 .00027 .00035 Pb /t ppm - .00169 .00330 194 .66 .00l-74 - .00483 - .00199 Se/z ppm .00036 .0001,7 47.393 .00043 .000]-7 .00049 Mo ppm . 00 t92 .00063 32. B6B .00260 .00135 .00779 LC Pass Cd ppm - .00020 .00007 3 s . 943 00017 00029 00015 Pb/2 ppm .00060 .002a7 350. BB - .00118 .00301 - .00003 Ag ppm .00269 .00022 8.09'77 .00268 .00291, .0024'7 Lr ppm .00049 .00010 n, .114 .00060 .00449 .00039 LC Pass page 1 Ca ppm -.00017 .00104 1,34 .43 - .00110 .00039 - .00151 Mg ppm - .00063 . 0 01,82 288 .37 -.00224 - .00099 .00134 LC Pass .04900 -.04900 Na ppm - .30511 .12404 40 .523 -.23585 - .44932 - -232L6 Sr ppm - .00002 .00002 131.91 - .00004 .00000 - .00001 LC Pass Elem A1 Units ppm Avge - .00405 SDev .00228 %RSD 56.353 #r #z #3 00173 00529 00414 Errors LC Pass High .10s00 Low - .10500 Elem Cr Units ppm Avge - .00015 SDev .00053 ?RSD 329. B O #r #z #r 00009 00020 .00078 Errors LC Pass High .00360 Low - .00360 EIem Mn Uni t. s ppm Avge .00015 SDev .00003 ?RSD L'7 .1-40 #r #z #: 00017 00012 00017 Errors LC Pass High .00180 Low - .00180 El em TI Units ppm Avge .00085 SDev ,0020l. ?RSD 235. O B #r #z #: Errors .00255 .00138 - .00137 LC Pass LC Pass LC Pass .01400 .00330 - .01400 - .00330 LC Pass LC Pass .00150 .00180 - .00150 - .00180 LC Pass LC Pass .00082 .05s00 - .00082 - .06500 NOCHECK NOCHECK LC Pass LC Pass .32200 .00380 -.32200 - . 00380 NOCHECK NOCHECK LC Pass LC Pass .00970 1.4730 - .00970 -1.4730 LC Pass LC Pass Appendix F - 153 14 B Ana1ys i s Report. High Low .01000 - .01000 .00500 - .00s00 Sn ppm - .00099 .00075 75.895 - .00019 -.00168 - .00108 2 NOTUSED .00380 - .00380 Si ppm .00398 .00053 13 .3s2 .00400 .00450 .00344 .03100 - .03100 P_ ppm .00346 .00081 23 .292 .00350 .00425 .00253 .00880 - .00880 Pb ppm . 00 029 .000ss 1,87 . 1-l .00270 -.00270 Se ppm . 00 073 .00729 77 5 . -71, page 2 00130 .00130 03/1,0/06 7,2:07:30 PM Elem Ti Units ppm Avge - .00005 SDev .00015 ?RSD 295.27 #r #z #3 .0001,2 - .00017 - .00010 Errors LC Pass High .00160 Low -.00150 Intstd 1 Mode Counts Blem Y Wavlen 37 7. 0 3 0 Avge 21,9 9 6 SDev 115.0988 ?RSD .527 82L5 #r #z #: 2L882 21_9 91, 22L]-4 LC Pass LC Pass LC Pass .00770 .05500 .02100 -.00170 -.0s500 -.02100 .00025 .002),0 .00086 - .00046 - .00023 .000s6 LC Pass LC Pass .00310 .00430 -.00370 -.00430 s61 NOTUSED NOTUSED NOTUSED 34 NOTUSED NOTUSED Appendix F - ts4 749 Ana1ys i s Repo'rt Method: TRA20505 Samp1e Name: ICSA1 Run Time: 03/a0/06 72;07:33 Comment: Mode: CONC Corr. Factor: 1 03 /to / 06 t2 :13 :25 PM page 1 Operator: El em AI Units ppm Avge 473 .46 SDev 2 .80 ?RSD . 5 9206 #r #z #: 4'70-60 47 6 .21 473.56 Errors LC Pass High 502 .4s Low 397 .55 EIem Cr Units ppm Avge .00503 SDev .00045 ?RSD 9.OOB2 #r #z #g 00532 o 0525 00451 Errors LC Pass High .01s00 Low - .01500 Elem Mn Units ppm Avge -.00140 SDev .00014 ?RSD 10.279 #r #z #: - . 0 01,25 - .00143 - .001s3 Errors LC Pass High .01s00 Low - .01500 E}'em TI Units ppm Avge .00283 SDev .00873 ?RSD 3OB.90 #r #z #: Errors .01289 -.002'78 - .00153 LC Pass LC Pass .05000 .02000 - .05000 - .02000 As Ba ppm ppm .00!43 H.0t28B .00115 .00009 7 9 .927 .7 0520 .00150 H.01,279 .00026 H.07291 .00255 H.0728'7 Cu ppm .00L02 .0002L 20 .428 . 0 01,22 .00104 .00080 Be ppm -.00025 .00013 s0.2l.9 00029 00038 00012 LC High LC Pass .01000 .01000 - .01000 - .01000 Cd Ca ppm ppm - .00189 43a.70 .00033 3.02 17.319 .70069 00152 428.98 00208 434.96 00209 431,.15 LC Pass LC Pass .00s00 602 .45 - .00s00 397.55 Pb/2 Ms ppm ppm -.00257 523.19 .0001,2 4.55 4 .6396 . 85 928 -.00273 519.00 - . 00253 528 .02 -.00275 522.54 Ag ppm .00028 .00032 111.59 .00001 .00063 .00020 Na ppm - .27 599 .15589 56 .484 314a7 10456 40925 Pas s 0000 .0000 Sb ppm .00027 . 0 0l-92 7 09 .74 .0021,7 .00030 - .00165 Co ppm .00038 .00a27 72.474 .00042 .00062 .00008 K- ppm .10381 .00695 5 .6926 .09804 . 111,52 .10188 V_ ppm .00795 .00482 50.515 .01028 .0024]- .01118 Ni ppm - . 0 0047 .00014 29.908 - . 0 0042 - .00036 - .00053 Zn ppm .00234 .00026 11.118 .00261 .00209 .00232 Fe ppm ].94.04 7 .52 .78095 a92 .7 6 195 .71- 193.66 LC Pass 240. 9B 159.02 Se/r ppm . 0 0324 .00382 11,7 . 61 .00620 .00460 - .00107 Pb/1, ppm .002l.6 .00]-49 68.962 .00155 .00383 .00099 Se/z ppm .00010 .00402 39s3.4 -.00227 - .00277 .00474 LC Pass LC Pass .05000 02500 - .05000 - .02s00 NOCHECK NOCHECK LC Pass 602 .4s 397.55 NOCHECK LC Pass .04000 - .04000 NOCHECK NOCHECK LC Pass LC .02000 5. -.02000 -5 B- ppm .00286 .00078 27 .184 .00361 .00291, .002a6 Pass NOCHECK Appendix F - 155 Mo ppm - .00058 .00099 170.63 -.00025 - .00169 .00021, LC Pass Li ppm .00t7t .00039 22 .932 .0021,2 .001-55 .001,34 LC Pass Sr ppm - .00987 .00009 .88019 - .00977 - .0099s - .00988 LC PassLCPass NOCHECK LC 150 o Analysis Report High .02000 Low -.02000 Intstd 1 Mode Counts Elem Y Wavlen 37 l. 0 3 0 Avge 20643 SDev 113.5113 ?RSD . 55 03694 # l- 205s2 #z 20s2s #s 207 s2 03 / L0 / 06 7,2 :73 :25 PM page 2 .04000 .05000 .05000 -.04000 -.0s000 -.0s000 .02000 -.02000 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge -.00093 .00253 .05185 .01,204 - .00048 .00150 SDev .00004 . OO1B7 . 00093 . 00069 . 00058 . 00148 ?RSD 4.7891 73.941 \.1994 5.7401 120.85 98.487 #1 -.00091 .00465 .0s085 .01173 -.00059 .00089 #2 -.00098 .00181 .05270 .01283 .00018 .00043 #3 -.00090 .00112 .05200 .01156 - .00093 .00319 Errors LC Pass LC Pass LC Pass NOCHECK LC Pass LC Pass High .05000 .10000 .50000 .00800 .01000 Low - .05000 - .10000 - - 5OOO0 -.00800 -.01000 234557 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 156 151 Analysis Report Method: TRA20505 Sample Name: ICSAB1 Run Time: 03/70/05 72:73:28 Comment : Mode : CONC Corr. Factor: 1 03/to/06 t2:L9:20 PM Operat or : EIem Units Avge SDev %RSD #r #z #: Errors T1 ppm ,09005 .00226 2 . 5113 .09134 .09138 .08744 LC Pass Sb ppm .54919 .00298 .45885 .64586 .5s009 .65151 LC Pass .7 229 4 .47746 Co ppm .49226 .00360 .73053 .48826 .49330 .49523 K- ppm 10. 967 .046 .41,984 10.989 10 . 915 10. 999 V_ ppm .49951 .00252 .50375 .49663 . 5 01,28 . s0061 LC Pass As ppm .1042l- .0074-7 I .4092 . 10 44'7 .10553 . 10 263 LC Pass .12049 .07951 Cu ppm . 51 926 .00060 .11511 . s1B5B .51943 .51915 Ni ppm .97986 .00922 .94077 .97 0 04 .98833 .981,22 Zn ppm 1.0588 .00s9 . ss39B 0519 07 20 a7 24 Ba ppm . s2229 .00079 . 1s 094 .52231, .521,49 . 523 07 LC Pass .50245 .39755 Fe ppm 98 .421 .581 .69362 97 .370 98.294 98.698 Se /7 ppm .05301 .00272 5 . 1312 .05027 .05305 .05574 B_ ppm 1.0345 .0094 .90788 1.0238 1.0389 1.0410 Be ppm .51531 .0021,6 .4tBB3 . s 1321, . 517 52 . 5151 9 LC Pass .50245 .39755 Pb/7 ppm .04536 .00375 8.2934 .04a]-2 .04830 .04666 Se/2 ppm .0559-7 .00042 .7 4286 . 05 645 .05573 .05572 Mo ppm .98998 .00s19 .5241,3 .98401 .99335 .992s9 LC Pass Cd ppm . 98 672 .00753 .7 6332 .97810 .99203 .99002 LC Pass I .2049 .7 9 510 Pb /2 ppm .05202 .00098 1. BBB5 .0s308 .05114 .0s184 .20691 .20894 .20892 Li ppm 1.105s .0036 .32924 1.1090 1.1077 1.1058 LC Pass page 1 Ca ppm 232. 1 5 1 . 04 .44559 231,.00 233.01 232 .43 LC Pass 3 01 .23 198 .71 Mg ppm 255. 84 1, .96 .75706 253.59 2s6 .1 B 257 - 1,7 10. 977 11 . 21,9 11 . 21,6 Sr ppm 1.0318 .000s .04881 1.0323 1 . 0377 1.0313 LC Pass Elem AI Units ppm Avge 242.72 SDev .35 ?RSD .744 0 3 #r #z #3 242.53 242. s1 243. 13 Errors NOCHECK High Low Blem Cr Units ppm Avge .49 855 SDev .00384 ?RSD .77001 #r. #z #3 . 49 463 .49907 .50228 Errors LC Pass High .60245 Low . 3 9755 Elem Mn Units ppm Avge .50622 SDev 00405 ?RSD . BOO9B #r #z #: . s01BB .s0685 . s0991 Errors LC Pass High .6024s Low 39755 LC Pass LC Pass .60245 .60245 .39755 .39'75s LC PasS NOCHECK NOCHECK LC Pass 120 .49 3 01 .23 79.510 198 .7-t Ag Na ppm ppm .20826 11.135 . 0 01,1,'7 .1,42 . s6156 t .278 0 LC Pass LC Pass 12 .049 7 .2049 7.9510 .79510 NOCHECK NOCHECK LC Pass LC Pass .24 0 9B t2 .049 .15902 7.9510 1 1 1 Pass LC Pass Appendix F - 157 LC Analysis Report 03 / I0 / a6 l-2:79 :20 PM page 2 High .L2049 .6024s 1- -2049 1,.2049 I .2049 7 .2049 7 .2049 Low . 07951 .39755 .79510 .79510 .79510 .79510 .79510 EIem Ti- Sn Si P- Pb Se Units ppm ppm ppm ppm ppm ppm Avge 1. 0317 -99221, 1 .1241- 1,.0526 . 05031- . 05533 SDev .0028 .00762 .0068 .0091 .00064 .00056 eRsD .26848 .76746 .60909 .85353 1.2800 1.1849 #1 L.0287 .98s49 1.1_L64 1.0430 .04957 .05477 #2 L.0324 .1.0005 L.129s 1.0610 .05077 .05517 #3 1.0341 .99066 L.a264 1.0s38 .05058' .0550s Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 1.2049 1-.2049 7.2049 1.2049 .06024 .06024 Low .79510 .7951"0 .79510 .79510 .03976 .03976 152 Intstd 1 Mode Counts Elem Y Wav1en 371.030 Avge 21,213 SDev 94.50727 ?RSD .4455151 #r 2L252 #z 21104 #: 2a273 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - ls8 153 Analysis Report Method: TRA20505 Sample Name: CRDL10 Run Time : o 3 / 10 / aG 72 :1,9 :23 Comment : Mode: CONC Corr. Factor: 1 03 / t0 / 06 12 :25 :75 PM Operator: page 1 Elem AI Units ppm Avge .41259 SDev .00558 %RSD 1.3s3s #r #z #: . 4747 I . 41,6 81 .40626 Errors LC Pass High .s2000 Low .28000 EIem Cr Units ppm Avge . 01 991 SDev .00019 ?RSD . 95 67a #r #z #: .01994 .02018 .01980 Errors NOCHECK High Low E]em Mn Units ppm Avge .03107 SDev .00033 ?RSD 1.0581 #r #z #: 03098 0374 4 03080 Errors NOCHECK High Low Elem T1 Units ppm Avge .03558 SDev .002l-6 zRSD 6.0734 #r #z #: Errors . 03 624 .03734 .03311 Sb ppm - L2443 .00400 3 .21s 9 .12374 .12892 .1,2123 NOCHECK Co ppm - 10 21,9 .00130 7 .27 63 .101,67 .10367 . 101,23 K- ppm 9 .6145 .0423 .44 04 0 9 .6613 9 .6 03 0 9.5790 V_ ppm . 10 792 .0005s .6428t .10200 .10253 .10L23 As ppm .02017 . 0 0 04 B 2.3601 .02051 .01965 .02023 LC Pass .02600 .01400 Cu ppm . 0 4976 .00028 .57344 . 04 9A5 .04944 .O48BB Ni ppm .08204 .00722 I .4824 .08L46 . 0 B 343 .0872a Zn ppm .05673 .0008s t .2665 .06627 .057'70 .0662A Ba ppm .01990 .00009 .47204 .01994 .01997 .01979 NOCHECK Fe ppm .21926 .00880 4 .0732 .22830 - 21,8'7 7 - 21,07 2 Se/t ppm .01597 .00077 1.0898 .01582 . 01 61,6 .01593 NOCHECK B- ppm .407l-3 .0051,4 1.25 15 .40518 .41296 .40326 Be ppm .01068 .00005 .5058s .01062 .01059 .0107s LC Pass .01300 .00700 Pb/1, ppm .01253 .00725 9 .9907 .01110 . 013 45 .01303 Se /z ppm .01508 .00L71 11.707 . 01711, .01422 .01391 Mo ppm .08204 .00106 1.2943 .08253 .0821 6 .08082 Cd ppm .01053 .00005 .54721, .01041 .01057 .01056 Pb/2 ppm .01634 .00093 5 . 5 636 . 017 34 . 015 13 .01553 Ag ppm .021,49 .00042 7.9s33 Li ppm .10523 .00064 .60906 .1059s .10502 . 10 412 Ca ppm 10.308 .064 .51680 10.260 10.380 10 . 284 Mg ppm 9.7 503 .4942 .96559 9 .6932 9. Bs90 9 .6 988 Na ppm 10. 017 .0sB .57"782 Sr ppm .10315 . 0 0 042 .40358 .10294 .10353 .10288 NOCHECK NOCHECK NOCHECK NOCHECK LC Pass NOCHECK NOCHECK NOCHECK .26000 .1,4000 02109 10. t2a 02493 10.100 o2L44 10.011 NOCHECK NOCHECK NOCHECK LC Pass NOCHBCK .03900 .02100 LC Pass NOCHECK Appendix F - 1s9 LC Pass NOCHECK NOCHECK NOCHECK NOCHECK a54 Analysis Report 03/10/06 72:25:\5 PM Pb ppm .01546 .00041 2.63s6 .01s80 .015s5 . 015 01 page 2 Se ppm .01569 . 0 0114 7 .2454 .01700 . 0 1519 .01490 67 NOTUSED NOTUSED High Low 04550 0245 0 Sn ppm .20227 .00477 . 8'7 462 .20032 .2A37 6 .2027 5 .07800 .04200 Si ppm .995s3 .01728 1.1327 .99092 1.0084 .98729 P- ppm .534l-3 .01085 7.7106 . 6220 4 .643 01 .63133 EIem Ti Units ppm Avge .10208 SDev .00061 ?RSD . 5 9956 #r #z #: 70767 a027 B 1017 B Errors NOCHECK High Low Intstd 1 Mode Counts EIem Y V,IavIen 377.030 Avge 221,58 SDev 140.1030 ?RSD .5322922 #r #z #: 2223 9 2l.996 2223 9 NOCHECK NOCHECK 23 NOTUSED NOTUSED NOCHECK LC Pass LC Pass .01950 .019s0 .01050 .01050 45 NOTUSED NOTUSED Appendix F - r60 155 Analysis Report Method: TRA20505 Sample Name: CDRL2) Run Time: 03/70/05 72:25:IB Comment : Mode: CONC Corr. Factor: 1 03/to/05 t2 :10 PM Operator: Sb ppm .06410 .0032]- 5.0131 .06150 .06769 .05310 LC Pass 20.000 - .05000 Co ppm .051s5 .00060 1.1697 .0s093 .0521,3 . 0 51,62 K_ ppm 4 .5440 .01,28 .2827 0 4 .547 9 4 .5545 4 .5297 LC Pass 200.00 -5.0000 V_ ppm .051,87 .00074 I - 431,2 .0s138 .05273 .051s1 LC Pass As ppm . 01010 .00161 15.938 .008s1 .01773 .01005 LC Pass 30.000 - .01000 Cu ppm .02444 .00022 .914l.7 .02433 . 02429 . o247 0 Ni ppm .04048 .00057 L . 4027 .04042 . o 4107 . 03 994 Zn ppm .02551 .00010 .37 284 .02658 .02640 .0265s Ba ppm .00992 .00006 .5061 9 .00990 .00999 .00987 Fe ppm .11330 .00933 8.2387 .10855 .724 0 5 .10729 Se/7 ppm .00472 .00188 39.859 .00s98 .00553 .00256 B_ ppm .20396 . 0 01,42 :59571 .20524 . 20 420 .20244 Be ppm .00s59 .00013 2.3724 .00543 .00s6s .00s58 Pb/1, ppm - .00070 .00257 367.48 .00L76 - .00049 - .00335 Se/z ppm .00647 .00023 3 .6A49 . 00 643 .00625 .00572 Mo ppm .04084 .00049 7 .2042 .04058 . 04]-4]- .04053 LC Pass Cd ppm .005a2 .00001 .2590s .00513 .00511 .00510 Pb/2 ppm .00507 .00L77 34 .902 .00364 .00452 .00705 Ag ppm .01384 .00068 4 .9A62 .01384 . 01 452 .01315 Li ppm .05225 .00024 .45611 .05234 .05243 . 0 51,9'7 LC Pass page 1 Ca ppm 5 .257 9 .0226 .42950 s.2435 s.2839 5.2451 Mg ppm 4 . BB9B .0202 .41323 4 .871,5 4 . 9115 4 . BB64 Na ppm s.0s50 .1866 3.6909 5 . 1067 s .2l.20 4.8492 Sr ppm .05133 .00006 .119'/0 .05136 .05136 .05l-25 LC Pass El-em AI Units ppm Avge .201-94 SDev .00237 ?RSD 1.1753 #r #z #s .20468 .20050 .20064 Errors LC Pass High 700.00 Low - .20000 Elem Cr Units ppm Avge .01533 SDev .00044 ?RSD 2 .8 93 0 #r #z #3 .01584 . 01 512 . 01 502 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge .01554 SDev .00008 ?RSD .53303 #r #z #: 01553 01553 0:l-547 Errors LC Pass High 30.000 Low - .01500 EIem TI Units ppm Avge .00774 SDev .00\46 ?RSD 18.913 #r #z #g Errors .00731, .00555 .00938 LC Pass LC Pass LC Pass 30.000 10.000 - .01000 - .00500 LC Pass LC Pass 40.000 500.00 -.00s00 -s.0000 LC Pass LC Pass 100.00 s0.000 - .05000 - .02500 LC Pass NOCHECK NOCHECK LC Pass 1400.0 700.00 - .10000 -5.0000 LC Pass NOCHECK 100.00 -.04000 NOCHECK LC Pass LC Pass 4.0000 800.00 -.02000 -5.0000 LC Pass LC Pass Appendix F - 161 156 Analysis Report High Low 70.000 -.02000 100.00 - .02500 Sn ppm .10162 . 0 0115 1.1282 .10279 .10237 .10030 40.000 - .04000 .003s5 .00331 .00403 s.0000 - .05000 00550 00541 00565 page 2 10.000 - .05000 7 NOTUSED 03 /1,0 / 06 72 :31 : 1o PM 10.000 40.000 - .02000 - .50000 EIem Ti Units ppm Avge .05158 SDev .00026 ?RSD .497 67 #r #z #: 05140 05L7 4 05190 Errors LC Pass High 40.000 Low - .05000 InEStd 1 Mode Counts Elem Y Wavlen 371,.030 Avge 21 93 0 SDev 67 .29235 ?RSD .3068440 #r #z #3 2L91-9 2tB7 0 22003 Si ppm .506L9 .00247 .48697 . s0343 .508l-7 .s0597 P- ppm .31733 .004]-2 1, .297 B .31734 .32l-44 .31320 Pb Se ppm ppm .00363 .00622 .00037 .000s0 10.139 8.0988 LC Pass LC Pass 40.000 40.000 - .10000 -1.0000 2 NOTUSED 34 NOTUSED NOTUSED LC Pass LC Pass LC Pass 40.000 70.000 30.000 -.30000 -.00400 -.01000 s6 NOTUSED NOTUSED Appendix F 162 757 Analysis Report Method: TRA20505 Sample Name : CRDL4 0 Run Time: 03/l-0/06 12:31:13 Comment ,Mode: CONC Corr. Factor: 1 03 /to / 06 t2 :37 :04 PM Operator: Sb ppm .00018 .00011 59. 479 .00008 .000L7 .00030 Co ppm .02548 .00039 1. s315 .02515 .02591 .02538 LC Pass 100.00 - .05000 K- ppm 2 .1555 .0118 .5491,7 2.74s8 2.1,693 2 . L546 LC Pass 200.00 -5.0000 V_ ppm .02542 .00041, 1.5301 .02545 .02581 .02498 LC Pass As ppm .00465 . 0 0 046 9. B28a .00437 .00519 .00442 Cu ppm .01190 .00004 .35733 .01189 .01185 .01195 Ni ppm .02030 .00022 1.0846 .0200s .02046 .02038 Zn ppm .01l-96 .00015 t.283B .01182 .01195 .01273 Ba ppm .00510 .00006 1 . 1041 .00510 .00s15 .00504 Fe ppm . 05 662 .00384 5.7 855 .05992 .0s754 .0s240 Se /t ppm .00299 . 0 0l.52 50.114 .00757 .00281, .00459 B- ppm .10290 .00056 .54723 .10248 .10268 .10353 Be ppm .002'72 .00014 4 .9490 .00260 .00270 .00287 Pb/t ppm .00108 .00263 243 .22 .00052 - . 0 01,22 .00394 se/2 ppm .00221, . 0 01_22 55.331 .00208 .00105 .00349 Mo ppm .00055 .00052 94 .069 .00106 .000s9 .00002 LC Pass Cd ppm .00258 .00072 4.s436 .0027a .00249 .00253 Pb /2 ppm .00]-34 .00119 89.069 .00131 .00254 .00015 Ag ppm .00872 .00098 11. 221 .00757 .00889 .00950 Li ppm .0250s .00019 .7235s .02618 .02613 .02s83 LC Pass page 1 Ca ppm 2 .597 4 .0185 .-71,726 2 .57 59 2 .6082 2.6081 Mg ppm 2 .4203 .0130 . s3 687 2 .4057 2.4307 2 .4244 Na ppm 2 .6395 .0740 2 .8023 2 .5692 2.6330 2 .7 467 Sr ppm .0254 B .00009 .35630 .02543 .02ssB .0254 3 LC Pass El em Al Uni t s pprn Avge . 103 91 SDev .00690 %RSD 5 .6444 #r #z #3 1118 0 10098 09896 Errors LC Pass High 700.00 Low - .20000 Elern Cr Units ppm Avge .00529 SDev .0002O ?RSD 3.8531 #r #z #: .0050s .00540 .0054l- Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .00169 SDev .00004 ?RSD .54'7 03 #r #z #: .00765 .00774 .00768 Errors LC Pass High 30.000 Low - .01500 EIem T1 Units ppm Avge .00708 SDev .00175 ?RSD 24 .7 40 #t- #z #: Errors .00520 .00737 .00865 LC Pass LC Pass LC Pass 20.000 30".000 - .05000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00500 LC Pass LC Pass 40.000 500.00 - .00500 -5.0000 LC Pass LC Pass 50.000 1400.0 - .02s00 - .10000 NOCHECK NOCHECK LC Pass 700.00 -5.0000 LC Pass NOCHECK NOCHECK LC PaSs LC PASs 100.00 4.0000 800.00 -.04000 -.02000 -5.0000 LC Pass LC Pass Appendix F - 163 158 Analysis Report a3 / 10 / 06 :-2:37 :04 PM Pb ppm .00l-62 .00019 11. 641, . 0 01,47 .00l.66 .00a79 Se ppm .00279 . 0 01,21, 43 .324 .00223 .00796 .004l.7 page 2 10.000 - .0s000 7 NOTUSED High Low 70.000 - .02000 100.00 - .02500 Sn ppm - .0000s .00071 1,455 . B .00001 - .00078 .00063 10.000 - .02000 Si ppm .03'72l- .00234 6 .27 97 .03974 .03575 .03513 40.000 - . s0000 P_ ppm . 16 404 .00184 1 . 1203 . 15 1,92 . 15 520 . 15 499 40.000 5.0000 - .04000 - .0s000 EIem Ti Unit s ppm Avge . 00 002 SDev .00009 ?RSD 445 .64 #r #z #3 00000 00012 .00006 Errors LC Pass High 40 .0 0 0 Low - .05000 Int Std 1 Mode Count. s EIem Y Wavlen 377. 03 0 Avge 21.823 SDev 55.54440 ?RSD .25+iteO #r #z #g 2l-887 277 83 21801 LC Pass LC Pass 40.000 40 .000 - .10000 -1.0000 LC Pass LC Pass LC Pass 40.000 70.000 30.000 -.30000 -.00400 -.01000 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 164 159 Analysis Report QC Standard Method: TRA20505 Sample Name: CCV1 Run Time: 03/a0/06 L2:37:08 Comment : Mode: CONC Corr. Factor: 1 03 /to / 06 t2:43 : oo PM Operator: Pass QC Pass 0000 2.0000 .500 10.500 QC Pass NOCHBCK 2s.000 10.500 page 1 Cd ppm .51557 .00233 .45106 . 517 85 . s1320 . 51557 Ca ppm 51 . 440 .15s .32007 51.615 s1 . 289 51 . 4]-6 Pb/2 Ms ppm ppm .51080 49 .96l- .0015s .326 .30285 .55236 . s1056 s0.3L2 .50933 49.568 . s 1 242 49 .903 NOCHECK QC Pass 50.000 10.500 Ag ppm .99454 .00290 .29181 .997 B1 . 9 9253 . 9 9324 Na ppm 49 .2l.9 .109 .22091 49.331 49 . t]-4 49 .21,3 QC Pass QC Fass 1.0000 s0.000 10.500 10. s00 EIem A1 Units ppm Avge 24 .594 SDev .055 ?RSD .221 5 9 #r #z #: 24.7l-8 24.'734 24 .632 Errors QC Pass Value 25.000 Range 10.500 Elem Cr Unit s ppm Avge 2 .0288 SDev .0L52 ?RSD .'75085 #r #z #3 2 .0453 2 .0153 2 . O25B Errors QC Pass Value 2.A000 Range 10.500 EIem Mn Units ppm Avge 2.0358 SDev . 013 9 ?RSD .58043 #r #z #: 2 .05l-4 2 .0248 2 .03]-4 Errors QC Pass Value 2.0000 Range 10.500 EIem TI Units ppm Avge 1.0070 SDev .0087 ?RSD .86225 #r #z #: Errors 1.0139 .99725 1.0099 QC Pass QC Pass QC Pass QC Pass .50000 .s0000 2.0000 10.500 10.500 10.500 QC Pass QC Pass QC Pass 2.0000 .50000 50.000 10.500 10.500 10.500 Sb ppm . 497 6t .00209 .4a9s8 .49988 .49578 .4971,7 Co ppm 2.0338 .0110 .54030 2. 2. 2. QC 2. 10 o 462 a2s4 029 B As ppm .50103 .00201 .40045 .50238 .49813 .50799 Cu ppm 1- .9582 .0037 .18776 1,.9600 1 . 9 606 1.9540 Ba ppm 1.9853 .0050 .25042 1.9895 1.9BBB 1.9806 Fe ppm 25 .486 .1-37 . s3916 25.530 25.356 25 .473 Se/t ppm . s0250 .00500 1.1945 .50853 .49653 .50243 B- ppm 1.9860 .0090 . 4545 9 t .9961 1.9834 1.9786 Be ppm 2 . OTtt .0058 .33028 2.079e 2 .0659 2.0585 Pb/L ppm .51495 .00770 1, . 4952 .52115 .50533 . 51137 Se/2 ppm .49883 .0042l- .84458 .50040 .49406 .50204 Mo ppm 2 . O20B .0014 .05778 2 .021,4 2 .0]-92 2 .02l-8 QC Pass QC Pass QC Pass 50.000 2.0000 10.500 10.500 NOCHECK NOCHECK K- ppm 49 .420 .094 .18969 49 .459 49.488 49 .3 13 V_ ppm 2 .01-34 .0085 .42425 2 .0232 2 -0081 2.0088 QC Pass Ni ppm 2.0511 .0093 .45223 2.0590 2 .0409 2 .0532 Zn ppm 2.01Bt .0070 .337l-4 0854 07 t4 017 6 Li ppm 2 .0L12 .0051 . 2559 4 2 .01"43 2.0140 2 .0052 QC Pass Sr ppm 2 .0722 .0049 .24525 2 . 01,32 2.0165 2.0068 QC Pass 2 2 2 Pass QC Pass Appendix F - 165 QC 160 Analysis Report QC Standard 03/L0/05 t2-.43:00 PM VaIue Range #r #z #: #r #z #g 1.0000 10.500 2 .0436 2 .0382 2 .0371 20865 213A2 211s8 2.0000 10.500 Sn ppm 2 .037 4 .0095 .46464 2.0450 2 .0-258 2.040s 2.0000 10.500 Si ppm 2 .0 053 .0058 .3 4!3 4 2 .0122 1.9985 2.00s1 2.0000 10.500 P- ppm 2.0808 .0087 . 4t7 42 2 .0904 2.0784 2 . 0736 2.0000 10.500 Pb ppm . 51257 .00343 .659s8 .51458 .50871 .51463 2.0000 10.500 Se ppm . s0039 .00451 .90033 .50344 .49527 . s0250 page 2 2.0000 10. s00 EIem Ti Unj-ts ppm Avge 2 .0397 SDev .0035 ?RSD .1693s Errors QC Pass QC Pass Va1ue 2.0000 2.0000 Range 10.500 10.500 QC Pass QC Pass 2.0000 2.0000 10.500 10.500 QC Pas.s QC Pass .50000 .50000 10.500 10. s00 Intstd 1 Mode Counts EIem Y Wavlen 37 7. 0 3 0 Avge 2 1111 SDev 226.8550 ?RSD 1.07461,7 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F 166 161 Analysis Report Method: TRA20505 Sample Name: CCB1 Run Time : 03 / l0 / 05 a2:43 : 04 Comment : Mode: CONC Corr. Factor: 1 03/70/06 t2:48:55 PM Operatolr: page 1 Cd Ca ppm ppm - .00017 .001,42 .00016 .0010s 95.253 73 .613 EIem A1 Units ppm Avge .00098 SDev 01010 ?RSD 1033 . B #r #z #: - .01100 - .00114 .0092l. Errors LC Pass High .10s00 Low - .10500 EIem Cr Units ppm Avge 00050 SDev .00058 ?RSD 135.61 #r #z #: - .00056 - .00115 .00021, Errors LC Pass High .00360 Low - .00360 EIem Mn Units ppm Avge .00002 SDev .00008 ?RSD 324. B O #r #z #3 .00003 - .00006 .00010 Errors LC Pass High .00180 Low - .00180 EIem TI Units ppm Avge .000'75 SDev .00203 %RSD 277.55 #r #z #3 Errors .00295 - .00106 .00035 LC Pass LC Pass LC Pass .01400 .00330 - .01400 - .00330 Sb ppm .00039 .00299 '774.42 - .00258 .00055 .00330 Co ppm -.00029 .00090 372. 13 - .00422 - .00020 .000s5 K- ppm .11292 .00952 8.4329 .11185 .10398 .72293 V- ppm - .00045 .00224 490.10 -.00265 - .00057 .001,84 LC Pass As ppm .00010 .00094 944.50 - .00080 .00001 .00109 Cu ppm - .00015 .00058 381 .74 - .00069 -.00022 . 0 0 046 Ni ppm - .00070 .00035 49.739 - .00107 -.00039 - .00054 Zn ppm .00007 .00007 101 .7 3 -.00001 .00008 .00014 Ba ppm - .0000s .00013 244.72 - .00019 - .00005 .00008 LC Pass .00160 - .00150 Fe ppm - .00s83 .01947 334.1,6 - .02532 - .00578 . 013 62 Se/t ppm .00008 .00668 8125 . s .00-172 -.00462 -.00286 B- ppm .00153 .00085 52 .373 .00199 .00066 .00224 Be ppm .00007 .00007 99 .987 .00004 .00014 .00002 Pb/7 ppm - .00185 .00466 251-. 9 B .00332 - .00572 - .00314 Se/z ppm .00t74 .00246 14 0 .97 - .00083 .00407 .00l-99 Mo ppm .002s9 .00075 28.905 .00336 .002s6 .00186 LC Pass 00010 0003s 00005 Pb /2 ppm .00041 .00332 B 10 .32 -.00278 .00384 .00016 Ag ppm .00306 .00072 23.559 .00274 .00256 .00389 Lr ppm .0007s .00018 23 .940 .0009s .00061 .00058 LC Pass 000s4 00114 002s8 Mg ppm - .00088 .0061,4 7 07. 10 - . 0 0739 - .0000s .00481 Na ppm -.28978 .224 B B 71 .602 -.25075 - . s3462 - . 0 8'697 Sr ppm - .00001 .00004 436 .02 - .00005 - .00001 .00004 LC Pass LC Pass LC Pass LC Pass .00180 .00082 05s00 -.00180 -.00082 -.05500 LC Pass LC Pass .00220 .00700 -.00220 -.00700 LC Pass NOCHECK .04900 - .04900 NOCHECK LC Pass .04900 - .04900 LC Pass LC Pass .32200 .00380 - .32200 - .00380 NOCHECK NOCHECK LC Pass LC Pass .00970 1,.4730 - .00970 1. 4'730 LC Pass LC Pass Appendix F - 167 762 Analysis Report 03/to/06 1,2:48:55 PM page 2 High .01000 .00s00 .00380 .03100 .00880 .00270 .00130 Low - .01-000 -.00s00 - .00380 -.03100 -.00880 - .00270 -.00130 EIem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge -.00005 - .00037 .01112 .00793 . OOO11 .00152 SDev .00026 -00077 .00368 .00187 .00087 .00080 *RSD 507.08 206.1-L 33.t23 23.61-9 769 -27 52.251 #1 -.00029 .00036 .00725 .00708 -.00029 .00234 #2 - .00011 - .00118 .01151 .00663 .00111 .00149 #3 .OO024 -.00030 .01459 .01_008 -.00048 .00074 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High .00150 .00770 .05s00 .02100 .00370 .00430 Low - .00150 - .00770 - .05500 -.02100 -.00370 - .00430 Intstd 1 Mode Count s EIem Y Wavlen 371. 03 0 Avge 2L959 SDev 100.5931 ?RSD .4580854 #r 27963 #z 220s8 #: 278s7 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 168 163 Analysis Report Method: TRA20505 Sample Name: HOQT2B Run Time: 03/:-0/06 t2:48:58 Comment : Mode: CONC Corr. Factor: 1 03/70/06 t2:54:50 pM Operator: page 1 Cd Ca ppm ppm -.00010 .02594 .00005 .00086 54 .153 3 .3 092 EIem Al Units ppm Avge .01006 SDev .00509 ?RSD 50.554 #r #z #: .01703 .00736 .00578 Errors LC Pass High .20000 Low - .20000 El em Cr UniLs ppm Avge -.00041 SDev .00040 ?RSD 96 .7 81 #r #z #: .00001 - .00045 - .00079 Errors LC Pass High .007s0 Low - .00750 Elem Mn Units ppm Avge .00013 SDev .00006 ?RSD 49 .642 #r #z #3 .00018 .00015 .00005 Errors LC Pass High .007s0 Low - .00750 El em T1 Unit s ppm Avge -.00L47 SDev .00231, ?RSD ]-57 .02 #r #z #: Errors -.00407 .00033 - .00057 LC Pass LC Pass LC Pass .03000 .01000 -.03000 -.01000 LC Pass LC Pass .00s00 .00s00 - .00500 - .00s00 LC Pass LC Pass .00250 2. s000 - .00250 -2. s000 Sb ppm .00148 .00057 38.287 .00702 .00131 .00271, Co ppm - .00021 .00006 26 .537 - .00015 - .00021 -.00021 LC Pass .02500 - .02500 K- ppm .L2380 .00783 6.3236 . 13 25a .121_54 . 117 35 LC Pass 2.5000 -2.5000 V- ppm .00053 .00029 45.788 .00039 .00095 .00055 LC Pass As ppm .00030 .00035 720 .99 .0007a .00008 .00010 Cu ppm .00022 .00032 745 .94 -.00007 .000s6 .0001,7 Ni ppm - . 0 0042 .00025 61. 820 000s0 00063 00013 Zn ppm .00072 .00010 13 .277 .000'74 .00080 .00062 Ba ppm .00088 .00003 3.001,2 .00091 .00087 .00086 Fe ppm .01-738 .00421, 24.204 . 01 455 . 02221, .01538 se/r ppm - .00111 .0016s l-49. 56 .00031 -.00292 - .00071 Be ppm - .00015 .00015 9B .118 -.00034 - .00004 - .00010 Pb/t ppm -.00287 .00\65 57 .7 53 -.00138 - .00257 - . 0 0465 Se/2 ppm .00108 .00057 52 .444 .00105 .000s2 .00L66 Mo ppm . 0 01,47 .00008 5.7 500 .00150 .00135 .00135 LC Pass - .00004 - .00013 - .00012 Pb /2 ppm .0020l. .002a7 a42 .7 B Ag ppm .00295 .00060 20.359 .00364 .00259 .00267 Li ppm .00032 .00002 5.5755 .00032 .00034 .00030 LC Pass 02526 02690 025 65 Mg ppm . 0 0410 .00188 45.800 LC Pass 2.5000 -2. s000 Na ppm - .25972 .08032 30.927 tB29 4 25304 3 431,7 LC Pass 2.5000 -2. s000 Sr ppm .00006 .000a2 28.730 .00004 .00008 .0000s LC Pass - .00012 .00347 .00215 .00252 .00401 .00622 LC Pass LC Pass .01250 .10000 - .0l.250 - .10000 NOCHECK NOCHECK LC Pass NOCHECK .02000 - .02000 NOCHECK LC Pass .01000 - .01000 B- ppm .002],5 .00027 12 .422 .00232 .0018s .00230 Pass LC Pass Appendix F - r69 LC L64 Analysis Report 03/ta/06 72:54:50 PM page 2 .02500 .02500 - .02500 - .02500 Se ppm .00072 .00085 1,17.55 . 0 0118 - .00026 .'0 0 1,24 High Low .01000 - .01000 .012s0 -.01-250 Sn ppm .01083 .00077 7 .1,17 6 . 0116 0 . 010 84 .01006 LC Pass .0s000 - .0s000 2 .02000 -.02000 Si ppm .02441 .00050 2.4s99 .02515 .024L2 .024].2 .10000 - .10000 P_ ppm . 01151 .00a67 ]-4.531 .01256 .00959 .01225 EIem Ti Units ppm Avge .00037 SDev .00014 ?RSD 38.969 #r #z #: .00052 .00035 .00024 Errors LC Pass High .02s00 Low -.02500 rntstd 1 Mode Counts Elem Y Wavlen 371.030 Avge 21-736 SDev 206. 4 04 0 ?RSD .94 96 0 91 #r #z #: 21500 2]-826 2]-882 NOTUSED NOTUSED 45 NOTUSED NOTUSED NOTUSED NOTUSED LC Pass LC Pass .2s000 .15000 - .2s000 - .1s000 .02000 - .02000 Pb ppm .00085 .00084 99 .628 - - 00007 .00103 .00158 LC Pass LC Pass .00400 .00500 - .00400 - .00500 Appendix 170 165 Ana1ysis Report Method: TRA2 05 05 Sample Name : HOQT2C Run Time : 0 3 /a0 /06 \2:54 : 53 Comment : Mode: CONC Corr. Factor: 1 03/1,0/06 o1:oo:45 PM Operator: Sb ppm .48415 .00105 .21,938 .48504 .48298 .48447 Co ppm .09979 .00093 .92835 .09879 .09999 .10051 K- ppm 50.153 .158 .31458 50.245 50.243 49 . 971, V- ppm .20277 .00057 .28t92 .20752 .2024]- .202s8 LC Pass As pprn .09907 .00098 .98476 .0983s .10018 .09859 Cu ppm .247 23 .00035 .L4348 ,24'7 6l .2469 0 .24119 Ni ppm . s0899 .00345 .67778 .50s02 .51067 .51727 Zn ppm .5377l- .00145 .27 2Bt .53004 .53246 .s3263 Ba ppm . 1013-7 .0001.1 .1_7131 .10751 .10131 . L0]-24 LC Pass .11049 .08951 Fe ppm 1.0240 .0117 1 . 1461, 1.011 4 1.0171, 1.0376 Se/t ppm .1,437 7 .00180 7 .2 513 .14507 .1445L . 1-417 a B_ ppm . 9 6292 .00151 . 15 67l- . 9 51,92 . 9 6220 . 9 5466 Be ppm .05128 .0002s . 493 43 .05099 .05135 . 0 5749 LC Pass . 05 525 . 04 47 6 Pb /t ppm .09736 .00280 2 .87 42 .09890 .09904 .094A3 se /z ppm .74560 .00a4'7 1.0059 .74545 .14422 .147 L4 Mo ppm .49844 .00198 .3 9 646 . 49 620 . 49 977 .49994 LC Pass Cd ppm .05109 .0002'7 . s1983 .05084 .05136 .05106 Li ppm .10730 .00050 .46294 .10718 .10734 .10679 LC Pass page 1 Ca ppm 50.962 .155 .32420 50.773 51.076 s1.039 Sr ppm . 51247 .000s9 .11550 . 5127 0 . 51 291_ .51A79 LC Pass Elem Al Units ppm Avge 1.9724 SDev .0015 ?RSD . OBO13 #r #z #3 1.9734 1 . 9732 1 . 97 06 Errors LC Pass High 2.2098 Low \.7902 EIem Cr Units ppm Avge .20 058 SDev .00022 ?RSD .10846 #r #z #: .20033 .20068 .20073 Errors LC Pass High .22098 Low . 17 902 Elern Mn Units ppm Avge .10298 SDev .00019 ?RSD .18528 #r #z #: 1"027 6 10309 10309 Errors LC Pass High . 11 049 Low .08951 EIem T1 Units ppm Avge .40764 SDev .00158 ?RSD .39240 #r #z #: Errors .40187 .39991 .40310 LC Pass LC Pass LC Pass . 55245 . 11 049 .43755 .08851 LC Pass LC Pass . 1 1 449 .21 623 .089s1 .22377 LC Pass NOCHECK 1.1005 .89510 LC Pass LC Pass . 05 525 55 . 245 . 0447 6 44 .7 55 Pb/2 ppm .10377 .00297 2 .8629 Mg ppm 9.63 1B .0434 .45028 .10114 9.5831 . 103L7 9 .6460 .10699 9.6663 NOCHECK LC Pass 11. O4g 8.9s10 Ag Na ppm ppm .05203 48.531 .00036 .1,73 .68B87 .35625 051,62 05224 a5223 48.558 48.789 48. 446 LC Pass LC Pass . 05 525 55 . 245 . 0447 6 44 .7 ss LC Pass LC Pass 55.745 .55245 42 .7 55 .447 55 NOCHECK NOCHECK LC Pass LC Pass Appendix F - 171 L66 Analysis Report .22098 .71902 Sn ppm .51458 .001,94 .37 51,2 . 512-7 6 .5166] . 51438 .55245 .441 55 Si ppm L .65687 .00256 .38912 L.65411 L.6s736 L.6s916 1, .2049 .7 9 510 P_ ppm s.0992 .0253 .49528 5.0704 5.1775 s . 1096 .50245 .39755 Pb ppm . 10 21,6 .00l.72 1.0999 .10095 .10235 . 10 31,7 5 NOTUSED PM .12049 .07951 Se ppm .L4535 .000s9 .402l.6 .t4570 -1,4469 .]-4570 page 2 6 0245 3 9755 03/to/06 o1:oo EIem Ti Units ppm Avge .10324 SDev .00018 ?RSD .t7 9s5 High Low #r #z #: .441,95 .35804 10311 10346 10316 Errors LC Pass High . a2049 Low .07 951 LC Pass LC Low .55245 6 .024s .447 55 3 . 97 55 2 NOTUSED NOCHECK LC Pass LC Pass . 1 1 049 .7657 4 .08951 .1,2977 34 NOTUSED NOTUSED 67 NOTUSED NOTUSED IntStd Mode EIem Wavlen Avge SDev ?RSD #r #z #: 1 Counts Y 377.030 21585 3 9 . 32434 . 1 8 2A846 21550 2762'7 275-l B Appendix F - 172 I I i L67 Analysis Report Method: TRA20505 Sample Name: H0QTEB Run Time: 03/70/AG 13:00:48 Comment : Mode: CONC Corr. Factor: 1 03/J,o/06 o1:05:40 PM Operator: page 1 Cd Ca ppm ppm -.00007 .02457 .00006 .00026 83.535 1.0791 EIem AI UniLs ppm Avge .00479 SDev .00082 ?RSD L7 .14 B #r #z #: .00515 .0038s .00537 Brrors LC Pass High .20000 Low - .20000 EIem Cr Units ppm Avge -.00020 SDev .00031 ?RSD 1s3.30 #r #z #: .00034 00015 .00041 Errors LC Pass High .007s0 Low - .00750 Elem Mn Uni t s pprn Avge .00053 SDev .00005 ?RSD 7 .47 04 #r #z #: 00058 00063 00057 Errors LC Pass High .007s0 Low - .00750 EIem TI Units ppm Avge -.00002 SDev . 0 01,67 ?RSD 9073 .6 #r #z #: Errors .00089 .00100 - .00195 LC Pass LC Pass LC Pass .03000 .01000 -.03000 -.01000 LC Pass LC Pass .00500 .00500 - .00500 - .00s00 LC Pass LC Pass .00250 2.5000 - .00250 -2.5000 Sb ppm .00189 - 0 01,52 85. 422 .00130 .0006s .00372 Co ppm .00007 .00019 250 .92 - .00004 - .00004 .00029 K_ ppm .1,7556 .00467 2 .6247 .1,7 0 3 1 .47893 .1,7745 V_ ppm .00045 .0001s 33.804 .00042 .00032 .00062 LC Pass As ppm .00l-57 .00011 7.0698 .001,70 .00754 .00149 Cu ppm .0002'7 .00015 53 .191 .00043 .00015 .00024 Ni ppm - .00005 .00019 41,4 .57 .00015 -.00424 -.0000s Zn ppm .00163 .00007 4 .537 B .00158 .00766 .00154 Ba ppm . 0 01,02 .00004 4 .0442 .00100 .00099 .00107 Fe ppm .02583 .00453 76 .867 .02420 .02423 . 03 205 Se/t ppm .00136 .00206 151 .35 - .00098 .00290 .002].5 B_ ppm .00320 .00057 t] .823 .00254 .00357 .00349 Be ppm .00008 .00005 55.026 .00004 .00009 .00013 Pb/7 ppm .00008 .0009s 1,721 - 2 - .0000s .00110 - .00079 Se /z ppm .00001 .00080 10434. - .00035 - .00055 .00092 Mo ppm .00119 .00060 50.331 .00147 .00050 .00161 LC Pass -.00009 - .00012 - .00000 Pb /2 ppm .00053 .0021,2 338.99 .00264 - .001s9 .00082 Ag ppm .00596 .00068 9.7276 .0061,9 .00743 .00728 Lr ppm .0002l- .00003 15.820 .00024 .00022 .0001,7 LC Pass 024B 0 02428 024 62 Mg ppm .0034]. . 0 01,07 31.343 .00277 .00288 .00464 Na ppm -.08235 . 04 3 3 3 52 .61"6 - .08148 - .03947 - .12671 Sr ppm .00008 .00002 19. 552 .00008 .00006 .00010 LC Pass LC Pass LC Pass .02500 .01250 - .02500 - .0l-2s0 LC Pass NOCHECK NOCHECK LC Pass .10000 2.5000 - .10000 -2.5000 LC Pass LC Pass 2.5000 .02000 -2. s000 - .02000 NOCHECK NOCHECK LC Pass LC Pass .01000 2.s000 -.01000 -2.5000 LC Pass LC Pass Appendix F - 173 168 Analysis Report 03/to/06 o1:06:40 PM page 2 High .01-000 .01250 .02000 .10000 .02000 .02500 .02500 Low - .01000 -.01250 -.02000 -.10000 -.02000 -.02500 -.02s00 Elem Ti Sn Si P Pb Se Units ppm ppm ppm pp* ppm ppm Avge .00098 .01586 -02662 .01631 .00101 .00079 SDev .00024 .00136 .00007 .00117 .00123 .00095 ?RSD 24.748 8.5055 .26355 7 .1628 1,21,.s2 t2t.02 #1 .001-24 .01490 .02665 .0L542 ..00231 -.00023 #2 .00094 .0152s. .02666 .01763 -.00013 .00093 #3 .00075 .0a742 .02653 .01588 .0008s .00L55 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High .02500 .05000 .25000 .15000 .00400 .00s00 Low - .02500 - .05000 -.25000 -.15000 - .00400 - .00500 fntstd 1 Mode Counts EIem Y Wavlen 377. 03 0 Avge 21-268 SDev 38.95084 ?RSD . 1B 31-467 #r 27287 #z 21224 #3 27298 23456"7 NOTUSED NOTUSBD NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 174 769 Analysis Report Method: TRA20505 Samp1e Name: HOQTEC Run Time: 03/L0/06 13:05:43 Comment : Mode : CONC Corr. Fact.or: 1 03 /1"0 / o5 07 : t2 PM Operatoll: 10090 9.5535 10453 9.7292 10198 9.7 535 page 1 Ca ppm 51.109 . 151 . 29 489 50.974 51.080 51.272 Mg ppm 9 .7 72t . 0521- .53610 Na ppm 48.985 .258 .52648 Sr ppm .5123a .002s5 .49880 . s0943 . 51 432 . 513]-'7 LC Pass Errors LC Pass High 2.2098 Low 1, .7 9 02 El em AI Units ppm Avge 1.9805 SDev . 005 8 ?RSD .29085 #r #z #3 1.9742 1.9823 1. 9853 Elem Units Avge SDev ?RSD #r #z #: Cr ppm .20l-29 .00058 .34035 .20059 . 201 13 . 2020 4 Errors LC Pass High .22098 Low .1,7 902 Elem Mn Units ppm Avge .10324 SDev .00080 %RSD .7 7 322 #r #z #: 70237 10341 10393 Errors LC Pass High . 11049 Low .08951 EI em TI Units ppm Avge .4 0295 SDev - 0 011,1 %RSD .29000 #r #z #: Errors .40198 .40262 .40425 LC Pass LC Pass LC Pass .11049 .2'7623 .08951 .22317 Sb ppm .48776 .00354 .72642 .48358 .49010 .48949 LC Pass . 55 245 . 437 55 Co ppm . 101_02 .00084 . B3 223 .10028 .10085 .10193 K_ ppm s0. s19 . a64 .32427 50.338 s0. 556 s0.562 V- ppm .20309 .00090 .44331 .2020s .2036s .20357 LC Pass As ppm .10269 .00093 .90538 .10469 .10283 .10354 Cu ppm .247 78 . 0 01,82 .73541 .245]-2 .24853 .24790 Ni ppm .51035 .00432 .84578 .50546 . 51207 . s1360 Zn ppm .53398 .003ss .66473 . s3009 .53482 .s3703 Ba ppm .10178 .000s8 .5739s .10113 . 10 225 .10]97 Fe ppm 1.0300 .0077 .74500 1.021,2 1.0355 1.0333 Se/t ppm .14544 .000s9 . 4 0 646 .14555 .744 B 0 . L459'7 B_ ppm .97078 .01091 1.1235 .95862 .91403 .97970 Be ppm .05138 .00023 .44490 .05119 .05131 .05153 Pb/r ppm .09927 .00230 2.3227 .10081 .096s7 . 10 02s Se/2 ppm .14'7 4t .00099 . 6'715 4 .14665 .l.4853 . L47 05 Mo ppm .49915 . 00 532 1.0663 .49363 .49956 . s0425 LC Pass Cd ppm .05749 .00038 .7 31 26 .05109 .0s155 .05184 Pb /2 ppm . 10 247 .00186 1 . 81,52 Ag ppm . 05 252 .00002 . o4323 lrr ppm .1076'7 .00033 .3044L .10734 .10799 .10770 LC Pass LC Pass LC Pass .11049 .11049 .0BBs1 .08951 LC Pass LC Pass LC Pass . 05 525 . 05 525 55 . 245 .04476 .04416 44.755 LC Pass NOCHECK NOCHECK LC Pass 1.100s 11. 049 .89510 8.9510 LC Pass LC Pass 55 - 745 .55245 42 -755 .44755 NOCHECK NOCHECK . 05 257 48 .692 .05250 49.088 .05254 49.A76 LC Pass LC Pass . 05 525 55 . 245 .04476 44.755 LC Pass LC Pass Appendix F - 17s 17 0 Analysis Report High Low .44195 .35804 1.2049 .79s10 P_ ppm 5.145l- .0366 .71040 5.1054 5.1773 s.1528 .60245 .3975s Pb ppm .101,79 .000ss . 53 82A .10725 .10234 .101,78 .1,20 49 .07 951 Se ppm . a47 09 .00048 .32871 .14566 .74-7 61, .1,47 02 page 2 6 0245 39755 03 / r0 / 06 01 : 1,2:35 PM EI em Ti Units ppm Avge .10381 SDev .00062 ?RSD .59855 #r #z #: 10310 1,0 425 10409 Errors LC Pass High .12049 Low .07951 Intstd 1 Mode Counts EIem Y Wavlen 37!.030 Avge 2L572 SDev 45 .853 52 ?RSD -2L3L567 #r #z #: 21465 2l.512 2l.557 22098 77902 .55245 .447 55 Sn Si ppm ppm .51761 L.41981 .00260 .00425 .50189 1. 0L24 . 515 51 L . 41515 . 51 696 L.42083 .52055 L.42345 LC Pass LC Low .55245 5.024s .44755 3.9755 NOCHBCK LC Pass LC Pass . 11 049 .7657 4 .08951 .12977 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F 176 t7 I Ana1ysis Report Method: TRA20505 Sample Name: HOPGEB Run Time: 03/t0/06 13:12:39 Comment : Mode: CONC Corr. Factor: 1 03/J,o/oG o1:18:31 PM Operator: page 1 Cd Ca ppm ppm - .00013 .01095 .00006 .00019 48.003 '7.1,768 El-em Al Units ppm Avge .00751, SDev .00313 ?RSD 4I .5 1 B #r #z #: 01005 00847 00402 Errors LC Pass High .20000 Low - .20000 El em Cr Units ppm Avge - .00058 SDev . 00 O4'7 ?RSD 81.311 #r #z #: - .00078 - .00004 - .00091 Errors LC Pass High .007s0 Low - .00750 Elem Mn Units ppm Avge . 00 024 SDev .00000 %RSD .23 71 B #r #z #: 00024 00025 00024 Errors LC Pass High .007s0 Low - .00750 Bl em TI Units ppm Avge .00264 SDev .00227 ?RSD 85.938 #r #z #: Errors .00010 .00337 .00446 LC Pass LC Pass LC Pass .03000 .01000 - .03000 - .01000 LC Pass LC Pass .00s00 .00s00 - .00s00 - .00500 LC Pass LC Pass .00250 2.5000 - .00250 -2. s000 Sb ppm .00070 .00131 186 .56 .00191 .00089 - .00059 Co ppm .00041 .00029 71,. B5g .00069 .00010 .00043 K- ppm . t6 511 .00]-24 .75009 . t6 519 .15631 . t63 B4 V_ ppm .00051 .00065 1,27.58 . 0 0118 .00048 - .00013 LC Pass As ppm .00029 .00073 250.5s -.00048 .00098 .00037 Cu ppm .00005 .00014 313.15 .00020 .00002 - .00008 Ni ppm .00011 .0004s 405.37 .00019 .00052 -.00038 Zn ppm .00401 .00014 3 .53l.7 .00421 .00392 . 0 0 40-7 Ba ppm .00086 .0000s 6 .7957 .00092 .00084 .00082 Fe ppm . 01 422 .00782 54.991 .0231,2 .00847 . 0110 5 Se/t ppm .00492 .00220 44.780 .00259 .00497 .00709 B- ppm .00303 .00028 9.1193 .00311 .00325 .002'72 Be ppm .00018 .00005 31.030 .00020 .00011 - 00 027 Pb/1, ppm -.00230 .001,46 63 . 492 00399 00144 00148 Se/z ppm - . 0 01,92 .00728 66 .4 05 00057 00310 00209 Mo ppm .00119 .00066 55.373 .00170 . 0 0143 .00045 LC Pass 00008 00011 00020 Pb/2 ppm .000s8 .00054 92.530 .001,2L .00028 - 0 0 02'7 Ag ppm .00596 .000l-7 2.1875 .00606 .00604 .00576 Li ppm .00013 .00006 49 .328 .00018 .00015 .00005 LC Pass 01186 010s9 0L0 42 Mg ppm .00292 .003L7 108.55 .006l.4 .00282 - .00020 Na ppm - .17373 .06799 3s.680 - .10347 - .19707 - .22011- LC Pass 2.5000 -2. s000 Sr ppm .00004 .00004 88. s96 .00008 .00003 .00001 LC Pass LC Pass LC Pass .02500 .012s0 - .02500 - .012s0 LC Pass NOCHECK NOCHECK LC Pass .10000 2.5000 - .10000 -2.5000 LC Pass LC Pass 2.s000 .02000 -2. s000 - .02000 NOCHECK NOCHECK LC Pass .01000 - .01000 O LC Pass LC Pass Appendix F - 177 172 Analysis Report a3/70/06 o1:18:31 PM page 2 High . 01000 . 01250 . 02000 .10000 .02000 .02500 .02500 Low -.01000 -.01250 -.02000 -.10000 -.02000 -.02500 - .02500 EIem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge .00044 .01,420 .02527 .0a775 .00018 .00070 SDev .00018 .00072 .00056 .00173 .00013 .00071 ?RSD 40.7s2 5.L022 2.2229 9.7751- 70.738 102.00 #r .00054 . 01503 . 02s89 .01543 .00003 .00089 #2 .00040 .01386 -02480 -0]-97L .00025 -.00009 #3 .00029 .01370 .025L2 .01710 .OOO24 .OOL29 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High . 02s00 .05000 .25000 .1s000 .00400 . 00s00 Low -.02500 -.05000 -.25000 -.15000 -.00400 -.00500 234557 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED IntStd 1 Mode Counts EIem Y Wav1en 37]-.030 Avge 21577 SDev 33.64570 %RSD .15s9315 #r 2t6t6 #z 215s3 #: 21-5 63 Appendix F - 118 L73 o Analysis Report Method: TRA20505 Sample Name: HOPGEC Run Time: 03/I0/06 13:18:34 Comment : Mode : CONC Corr. Factor: 1 a3/70/06 o1:24:26 PM Operator: Sb ppm .48078 .01229 2.5570 . 489 92 .46580 .48553 LC Pass .60245 -39-l 55 Co ppm .09872 .00336 3 .3 99]- .10726 .09492 .09999 K- ppm 49 - 1,82 1.305 2 .5529 50.721 47 .692 49.734 V_ ppm .19896 .00597 2 .9999 .203s3 .19227 .20115 As ppm .09833 .00259 2.6356 .09981 . 09 s34 .0998s Cu ppm .24203 .00729 3 .04l.2 .2467 4 .23363 .2457 I Ni ppm .50049 .01478 2 .9527 .51097 .48358 . s0690 Zn ppm .525'7 7 . 0 1511 2 .8739 .53102 .50855 .53155 Ba ppm .09967 .00295 2 .9s52 .101,64 .09628 .10108 Fe ppm 1.0153 .0320 3.1s32 1.0415 .97 964 1.0248 Se/t ppm .1,417 9 .00206 I .4515 . 743 02 . 13 942 . 1429 4 B_ ppm .95428 . 026 93 2 .8227 . 971 15 .92322 . 9 5847 Be ppm .0s093 .00119 2.3345 .051,69 .04956 .05155 Pb/1, ppm .09822 .0019s 1.9874 .09782 .096s0 .10034 Se/z ppm .1,4348 .00293 2 .0448 . 1453 4 .]-4009 .]-4500 Mo ppm .491,52 . 016 15 3.2866 .50278 . 47 293 .49944 LC Pass Cd ppm .05039 . 0 0141, 2.7 915 . 0 514'7 .04880 .05091 Pb /2 ppm . 101,07 .00320 3.171,L .10299 . 0 9137 .10285 Ag ppm .05].37 .00259 s.0362 .05335 .04844 .05231, Lr ppm .10505 .00275 2 . 6191 .10702 .10191 . 10 622 LC Pass page 1 Ca ppm 50.345 a -447 2 .8736 51 . 357 48.688 s0.990 Mg ppm 9. s280 .2739 2 -8751, 9 .71 1s 9 .213 1 9 .6s94 Na ppm 48.110 I .21-7 2.5306 48.950 46.713 4B . 665 Sr ppm .50240 .01476 2 .9382 .5134l. .48562 .50815 LC Pass El-em AI Uni t. s ppm Avge 1. 9290 SDev .0578 ?RSD 2 .9 9s0 #r #z #3 1.9585 1.8627 7.9559 Errors LC Pass High 2.4098 Low 1.5902 EI em Cr Uni t, s ppm Avge .L97 44 SDev .00534 ?RSD 2 .7 01 4 #r #z #g 20039 79727 20067 Elem Mn Units ppm Avge . 101,32 SDev .00309 ?RSD 3.0448 LC Pass LC Pass .12049 .l.2049 .079s1 .07951 LC Pass LC Pass LC Pass .06024 .05024 60.245 .03976 .03976 39.755 Errors LC Pass LC Pass High .24098 .12049 Low . 15 902 . O7 951 LC Pass LC Pass .301,23 7.2449 .1987'7 .79510 NOCHECK NOCHECK LC Pass 1,2 .049 7.9s10 #r #z #: 10330 09776 70289 Errors LC Pass High a2049 Low .07951 EIem TI Units ppm Avge .40024 SDev .011,73 %RSD 2.9300 #r #z #: Errors .40457 . 3 B 695 .40918 NOCHECK LC Pass .60245 .39755 NOCHECK NOCHECK LC Pass LC Pass .06024 50.245 .03976 39.7ss LC Pass NOCHECK Appendix F - 179 LC Pass NOCHECK 174 Analysis Report 03 /10 / 06 o1 : 24:26 PM .60245 .39755 Pb ppm .10051 .00270 2.6889 . 10l.7 4 .09753 .10258 .12049 . 019 51 Se ppm . L4328 .0026s 1.8509 .1,4494 .14023 .14468 page 2 6 0245 3 9'155 57 NOTUSED NOTUSED High Low .481,96 .31804 EIem Ti- Units ppm Avge . 10 21,1 SDev .00292 ZRSD 2 .8554 #r #z #: L0423 0987 9 10332 Errors LC Pass High . 1,20 49 Low . 07 951 Intstd 1 Mode Counts EIem Y Wavlen 377. 03 0 Avge 21750 SDev 626. 0351 ?RSD 2 . 87 837 B #r #z #: 21,243 22449 21-557 .60245 . 3 91s5 Sn Si ppm ppm .50903 L.43073 .01542 .01557 3.0295 3.8452 .519L2 L.441BB .491,28 L .41169 . 51 57 0 L.43862 LC Pass LC Low .60245 5.0245 .39755 3.9755 2 NOTUSED P_ ppm 5.0784 .1455 2.86s9 5.1895 4.9135 5 . 132A 34 NOTUSED NOTUSED NOCHECK LC Pass LC Pass .72049 .18074 .07951 .11926 5 NOTUSED Appendix F - 180 ]-75 Analysis Report Method: TRA20505 Sample Name: HOPGEL Run Time: 03/aO/06 13:24':29 Comment : Mode : CONC Corr. Factor: 1 03/70/06 o1:30:21, PM OperatoL: Sb ppm .48593 .00325 .56737 .48527 .49058 .484 B 5 Co ppm .09964 . 00 044 .44507 .09965 .0991,9 .10008 LC Pass .1,20 49 .o'7951 K- ppm 49 .823 .1,44 .28982 49 .7 92 49.980 49 .696 V_ ppm .201,69 .00098 .48606 .2010 5 .2A120 .20282 As ppm .09989 .00015 .15330 .09997 .09999 .09970 Cu ppm . 24 618 . 0 0 04 B .195s9 .24589 .24592 .2467 4 Ni ppm .50434 .001,45 .28980 .50303 .50406 .50592 Zn ppm .53358 .000s6 .10455 .53388 .5330s .5341,r Ba ppm . 1015 5 .0001,7 .15139 . 10].7 3 .10155 .10139 Fe ppm 1 . 0 1,8'7 .0154 1.515s 1.0030 1.0193 1.0339 se/1 ppm .1,4225 .0024-l 1.7 393 .7447 2 . 13 977 .74226 B- ppm .97039 .00406 .47809 . 97 226 .96513 . 9V 3l-7 Be ppm .05]-24 .00020 .381,78 .05105 . 0 51,25 . 0 51,44 Pb /r ppm .09848 .003.32 3.3724 .10183 .09519 .09843 Se/2 ppm .1,4551 .00300 2 .0461 .L4380 .14599 . 1,4 9'7 3 Mo ppm .49950 . 0 01,49 .29779 .49852 .49877 .50l_21, LC Pass Cd ppm .05083 .00034 .5s964 .0508s .05048 . 0 5115 Pb /2 ppm .102]-0 .00244 2.3858 .09929 .10338 .10364 Ag ppm .05098 .00038 .7393s .05087 .05068 .05140 .10654 .10697 .10604 LC Pass page 1 Ca ppm 50. 652 .061 .11947 50.602 50.635 50.720 Mg ppm 9.5992 - 031-2 .32462 9 .6027 9.s667 9.6288 Na ppm 48 . Bt2 . 026 .05240 48.827 48.827 48.'782 .51104 .51202 .51034 LC Pass EIem Al Units ppm Avge 1.9585 SDev .0008 ?RSD .04115 #r #z #3 1. 9580 1.9s83 1.9595 Errors LC Pass High 2.4098 Low 1.5902 EIem Cr Units ppm Avge .20005 SDev .00139 ?RSD .69585 #r #z #3 .20098 .19845 .20072 Errors LC Pass High .24098 Low . 15 902 Elem Mn Uni t. s ppm Avge .10256 SDev .00053 ?RSD .52L67 #r #z #: L027 9 10195 1029 4 Errors LC Pass High . L2049 Low .07 951 EIem TI Units ppm Avge .40 04 3 SDev .00308 ?RSD .7 6923 #r #z #: Errors 39806 39931 40391 LC Pass LC Pass .60245 .]-2049 .39755 .01951 LC Pass LC Pass . L2049 . 06 024 .a7 951 .03916 LC Pass LC Pass .05024 60.245 .03975 39.755 LC Pass LC Pass "301,23 1.2049 .198'77 .79510 NOCHECK NOCHECK LC Pass 72 .049 7.9510 NOCHECK LC Pass .6024s .39755 NOCHECK NOCHECK LC Pass LC Pass .05024 50.245 .03975 39.755 Li Sr ppm ppm .10652 .51113 .00046 .00084 .43476 .t6518 LC Pass NOCHECK Appendix F - 181 LC Pass NOCHECK 776 Analysis Report High Low .48!96 .31804 .72049 .07951 .74443 .44424 .747 56 page 2 60245 397 55 .6024s .39755 Sn Si ppm ppm . 51 44t L.4Bt23 .0007L .00279 . 13 834 .57 962 .51458 ,L.481,23 .51353 - L.47844 .51502 L.48402 LC Pass LC Low .50245 6 .0245 .39755 3.9155 03/to/06 01:30:27 PM . 5 0245 .397ss Elem Ti Units ppm Avge .10366 SDev .00009 ARSD .08355 #r #z #g .10357 .10358 .10374 Errors LC Pass High .1,2049 Low .07951 Intstd 1 Mode Counts EIem Y Wavlen 371. 03 0 Avge 2167 9 SDev 58.15305 %RSD .2682463 #r #z #: 21,676 21,7 3 0 21,6 97 P_ ppm 5.1473 .0435 .84539 5.0971" 5.1743 5.1705 10060 10102 1-0221 Pb Se ppm ppm .10130 .1-4541 .00087 .00186 .85760 1.2828 NOCHECK LC Pass LC Pass .1,2049 .18074 .07951 .11926 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 182 L77 Analysis Report Method: TRA20505 Sample Name: HOLJB Run Time: 03/70/06 13:30:25 Comment : Mode: CONC Corr. Factor: 1 03/lo/06 o1:35:76 PM OperatoL: page 1 Cd Ca ppm ppm - .00384 .96101 .00030 .00367 7.8117 .38222 Elem Al Units ppm Avge 143 - 15 SDev .64 ?RSD .447l-3 #r #z #g 742 . 51 743. 1B 143 .7 9 Errors LC Pass High 700.00 Low - .20000 EIem Cr Units ppm Avge .39150 SDev .00091 ?RSD .23309 #r #z #g 390s9 391s1 39242 Sb ppm .00287 .00285 99 .553 .00005 .00578 .00277 LC Pass 20.000 - .06000 Co ppm . 0129 9 .00030 2 .2992 . 01281- . 0133 4 .01283 K_ ppm 3.3tO1 .0a27 .36434 3.2980 3.3L22 3 .3220 LC Pass 200.00 -5.0000 V- ppm . 5116 3 . 0 01,12 .27806 .51037 .5125L .51200 LC Pass As ppm .061,27 . 0 01,12 1.8311 .0621,2 .061,77 .05000 Cu ppm .07 996 .00010 .1,2269 .07990 .07990 .08007 Ni ppm .04043 .00039 . 9 6a49 .04016 . 0 4027 .o40BB LC Pass 100.00 - .04000 Zn ppm .1-2913 .000'73 .56487 . 1,29 49 . 1,2 915 .13055 Ba ppm .l'1754 .00029 . 1513 1 .4713 4 .17787 .l'7 7 42 Fe ppm 2BB .51 .78 .26857 287 .7 5 288. 6 B 289 .29 Se/t ppm .0079s .001,16 22 .1s 3 .00672 .0071,6 .00997 B_ ppm .00853 .00047 5 .4404 .00858 .00912 .00818 Be ppm .00l-67 .00002 1, .21_21 . 0 01-67 .00159 .00155 Pb/1, ppm .08424 .00274 3.2274 .086s6 .081,26 . 0B 490 se/z ppm .01010 .001,96 19. 427 .00835 .00974 .01222 Mo ppm .00-779 .00038 4 .8204 .00772 .00820 .00746 LC Pass a0377 00417 00358 07 B87 07788 07942 Ag ppm .00s11 .00044 8.5937 .00492 .00479 .00551 Li ppm .10008 .00023 . 233 02 .09981 .10022 .10020 LC Pass 95810 9597 9 9 651-4 3.5283 3.5406 3.5437 Na ppm - .14370 .0267 9 1B . 642 1_2 61,2 13045 1,7 453 Sr ppm . 021 4'7 .00005 .22097 . 021 40 . 02-t 52 .027 4'7 LC Pass LC Pass LC Pdss 30.000 30.000 - . 01000 - .01000 LC Pass LC Pass LC Pass 10.000 40.000 600.00 -.00s00 -.00s00 -5.0000 Pb/ 2 Mg ppm ppm .07872 3.5375 .00078 .0082 .99484 .23100 Errors LC Pass High 100.00 Low - .01000 Elem Units Avge SDev ?RSD #r #z #: Mn ppm .1573l- .00024 .15036 .15705 .15752 .15734 Errors LC Pass High 30.000 Low - .01500 Elem TI Units ppm Avge .00251 SDev . 00 280 ?RSD 111.55 #r #z #: Errors .00074 .00559 .007-l 9 LC Pass LC Pass LC Pass 100.00 50.000 -..0s000 - .02500 LC Pass NOCHECK 1400.0 - .10000 NOCHECK LC Pass 700.00 -s.0000 NOCHECK NOCHECK LC Pass LC Pass 4.0000 800.00 - .02000 -s.0000 LC Pass LC Pass Appendix F - r83 L78 Analysis Report 03/to/06 o1:36:16 PM page 2 High 70.000 100.00 10.000 40.000 40.000 5.0000 10.000 Low - .02000 - .02500 -.02000 - .50000 -.04000 -.05000 - .05000 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge .69548 .01604 7 .5968 .71740 .08098 .00970 SDev .00114 .00056 .0250 .00301 .00135 .001-89 ?RSD .L6329 3.4799 .32932 .42339 L.67L7 L9.432 #1 .5942L .01s41 7.5680 .71015 .08185 .00813 #2 .59s84 .01545 7 .6085 .70927 .07942 .00918 #3 .69639 .Oa627 7 .61-36 .71-484 .08155 .01-1-79 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.O50OO -.1O0OO -1-.0000 -.3OOOO -.OO40O -.O1O0O Int. S td 1 Mode Counts EIem Y Wav1en 377.030 Avge 21,17 6 SDev L42.3015 ?RSD . s1s70s0 #r 21800 #z 21,87 5 # 3 21,65 4 234561 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 184 L79 Analysis Report Method: TRA20505 Samp1e Name: HOLJBS Run Time: o3/70/06 13:36:20 Comment : Mode: CONC Corr. Factor: 1 03/10/06 o1:42:77 PM Operator: Sb ppm .22503 .002s1 1.1091 .228 8 0 .22391 .22539 Co ppm .12495 .00104 .83568 .1-247 B .L2401 .12508 K- ppm 62.800 .098 .15644 62.783 62.906 62 .'7 Al V_ ppm .89280 .00377 .42206 .89367 . B B 861 .89606 LC Pass As ppm .7'7 948 . 0 01,52 .90037 .77835 .18133 .17 87 5 Cu ppm .35382 .00077 .2L827 .3s332 .35477 .35342 Ni ppm .63800 .00385 .50582 . 53 921, . 633 67 .64111 Zn ppm .7 BB54 .000-76 .09666 .7 891,4 .7 871 6 .78901 Ba ppm .45542 .00055 . a23 67 .45580 .45570 .4547 B LC Pass 30.000 - .01000 Fe ppm 300.84 2 .35 .77953 301.40 298 .26 302. B5 Se/r ppm .141 9 5 .00305 2.L501 .a4505 . t41B 4 .1389s B- ppm .8922'7 .00190 .2721 4 .89008 .89337 .89335 Be ppm .05379 .00026 .489s3 .05355 .05373 .05407 Pb/L ppm .20420 .00954 4 .6599 .21325 . 1-9 424 .20511 Se/2 ppm .1451 0 .00192 1.31'75 . L4444 .1,447 6 .1-47 91, Mo ppm . 4547 2 .00352 .7 7 321, .45327 .'4521,6 . 4581 3 LC Pass Cd ppm .04533 .00025 .51054 .-04 649 . 04 647 . 0 4602 7857 1 19539 1959s 0ss9B 05401 05592 Li ppm .30074 .00746 . 487 72 .30087 .30273 .29921 LC Pass page 1 Ca ppm s0.980 .421, .82543 51.048 s0. s30 51.353 18.905 18.722 18. 973 50.430 49 .953 50. 495 Sr ppm .58051 .00050 .0B5ss .5'7997 .58097 .58058 LC Pass EIem AI Units ppm Avge 341.93 SDev L .94 ?RSD . s58s1 #r #z #: 340.59 347 .04 344.15 Errors LC Pass High 700.00 Low - .20000 Blem Cr Units ppm Avge .69929 SDev .00589 ?RSD .98565 #r #z #: 7 0268 6973 6 70383 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .33 642 SDev .00267 zRSD .79507 #r #z #3 337 06 333 49 33873 Errors LC Pass High 30.000 Low - .01500 EIem Tl Units ppm Avge .36446 SDev .00808 ?RSD 2.2155 #r #z #: Errors .37 37 4 .3s90s .36059 LC Pass LC Pass LC Pass 20.000 30.000 - .06000 - .01000 LC Pass LC Pass LC Pass 10.000 40.000 500.00 -.00500 -.00500 -5.0000 Pb/2 Mg ppm ppm .49270 18. 857 .00605 .130 3.1423 .68804 LC Pass LC Pass 100.00 s0.000 - .0s000 - .02500 LC Pass NOCHECK 1400.0 - .10000 NOCHECK LC Pass 700.00 -5.0000 Ag Na ppm ppm .0s531 50.296 .00l-]-2 .290 2 . 0260 .57 665 LC Pass LC Pass 200.00 100.00 -5.0000 -.04000 NOCHECK NOCHECK LC Pass LC Pass 4.0000 800.00 - .02000 -s.0000 LC Pass LC Pass Appendix F - 18s 180 o Analysis Report 03 / to / 06 o1 : 42:Lt PM page 2 High 70.000 100.00 10.000 40.000 40.000 5.0000 10.000 Low -.02000 - .02500 -.02000 -.50000 -.04000 -.05000 - .05000 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge 2.2089 .48026 a3.392 5.9403 .79699 .L4478 SDev .0087 .00224 .035 .0221, .00253 .00050 ?RSD .39256 .46576 .26909 .37128 1.3371 .4L148 #1 2.2018 .481s1 13.384 s.91s0 .19539 .a4497 #2 2.2008 .41768 13.360 5.9559 .19556 .L441t #3 2.21-8]- .48160 13.431 s.9499 .20003 .1-452s' Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.05000 -.10000 -1.0000 -.30000 -.00400 -.01000 Intstd 1 Mode Counts EIem Y Wavlen 37L.030 Avge 21623 SDev 183 .3748 ?RSD . 848O3B9 # r 2L42-t #z 2L'/ 90 #: 216s3 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 186 181 Analysis Report Method: TRA20505 Sample Name: HOLJBP Run Time : 0 3 /70 / 06 13 : 42 :1,5 Comment : Mode: CONC Corr. Factor: 1 03/10/06 01:48:06 PM Operatolr: page 1 Cd Ca ppm ppm - .00095 .20845 .00007 .00075 7.4753 .36140 - . 0 0092 .207 56 -.00103 .20853 -.00089 .2a9t6 Pb/2 Mg ppm ppm .01725 ,.7L1Bg .00428 .00153 7 .64a2 .2a569 Elern AI Units ppm Avge 29 .0 3 5 SDev .147 ?RSD . s0534 #r #z #g 29 .10 0 29 .13 9 28. B5B Errors LC Pass High 700.00 Low -.20000 El em Cr Units ppm Avge . 07 846 SDev . 00 04 0 %RSD .51004 #r #z #: 07853 O7BB3 07803 Sb ppm .00285 . 0 01,62 56.601 .00220 .00L67 .00469 LC Pass 20.000 - .05000 Co ppm .00254 . 00 044 t7 .205 .00248 .0021,4 .00301 K_ ppm .58722 .00959 1.3952 .58260 .58081 .59824 LC Pass 200.00 -s.0000 V- ppm .10288 .00021, . 20 029 .10277 .10311 .10284 LC Pass As ppm .0115s .00 ].L4 9 . B 435 . 0121,4 .01024 .01226 Cu ppm .01545 .00015 1.0582 . 01 529 .01544 .01562 Ni ppm .00754 .000t2 1.5771 .00759 .00763 .00741 LC Pass 100.00 - .04000 Zn ppm . 0271,9 .00014 .50720 . 02'7 07 . 027 34 . 0271,8 Ba ppm . 03 475 .00022 .62415 .03483 . 03 493 . 03 45a Fe ppm 58.2l-4 .206 .35437 58.1"28 sB. 449 58. 064 Se/7 ppm .00070 .00195 217.38 - .00154 .00l.75 .00190 B- ppm .00293 .00064 2r .636 .00351 .002s3 .00261 Be ppm .00070 .00004 5 .2820 .00069 .00467 .0001 4 Pb/7 ppm .01458 .00072 4 .91,32 .01498 . 0137 5 .01501 Se/z ppm .00335 .00150 44.814 . 0 0 489 .00189 .00328 Mo ppm .002-72 .00091 33.297 .003s3 .00\74 .00288 LC Pass 017 15 01,1 57 01703 Ag ppm .00852 .00096 11.237 .00787 .00807 .00962 Li ppm .01945 .00027 1.0532 .01964 .01947 . 01 923 LC Pass .71,019 .71,229 .7 t3 1B LC Pass 700.00 -5.0000 Na ppm -.27180 .03263 1,2 .0 04 - . 3 0361 -.27326 - .23847 Sr ppm .00549 .00001 .23569 .00551 .00549 .00s48 LC Pass LC Pass LC Pass 30.000 30.000 - .01000 - .01000 LC Pass LC Pass LC Pass 10.000 40.000 500.00 -.00s00 -.00500 -s.0000 Errors LC Pass High 100.00 Low - .01000 El em Units Avge SDev ?RSD #r #z #: Mn ppm . 0 3 1,41, .00014 .45313 .0314'7 .031,52 .031,25 Errors LC Pass High 30.000 Low - .01500 El em TI Units ppm Avge .00399 SDev .00288 ?RSD -t 2 .27 6 #r #z #: Errors .00644 .004'72 .00081 LC Pass LC Pass LC Pass 100.00 50.000 - .05000 - .02500 LC Pass NOCHECK NOCHECK 1400.0 - .10000 NOCHECK NOCHECK LC Pass LC Pass 4.0000 800.00 - .02000 -5.0000 LC Pass LC Pass Appendix F - 187 tB2 Analysis Report 03/70/06 01:48:05 PM page 2 High 70.000 100.00 10.000 40.000 40 - 000 5.0000 10.000 Low -. O2OOO - . O25OO - .02000 - .50000 -.04000 -.05000 -. O5O0O Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge .13938 .00355 1.5331 .15279 .01580 .00281 SDev .00097 .00058 .0096 .00154 .00017 .00056 ?RSD .69682 l-5.880 .62456 1.0715 1.0003 a9.824 #1 .L3945 .00300 1.5338 .15110 .01699 .00312 #2 .14031 .00387 1.5423 .75290 .01"667 .002L7 #3 .13837 .00411 L.5232 .:-s437 .07673 . OO31s Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40. oOO 40.000 40. O0o 40. OO0 70. o0o 30.000 Low -.05000 -.10000 -1.0000 -.30000 - .00400 - .01000 Intstd 1 Mode Count s EIem Y Wavl-en 37 7. 0 3 0 Avge 2 13 0B SDev 44 .57 07 B ?RSD .2091,7 22 #r 21309 #z 273s2 #3 27253 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - r88 183 Analysis Report QC SLandard Method: TRA20505 Sample Name: CCV2 Run Time: 03/70/05 13:48:10 Comment : Mode: CONC Corr. Factor: 1 03/lo/06 o1:54:02 PM Operator: page 1 Cd ppm .51207 .00181 .3s395 Ca ppm s0.930 .120 . 23 491, . 51 4L2 51 . 467 .srt45 50.847 .51055 50.876 QC Pass QC Pass . s0000 s0.000 10.500 10.500 Pb/2 Mg ppm ppm . 50 632 49 .826 .00047 .203 .09359 .40792 50682 50589 s0625 s0. 020 49 .6L4 49'.844 Ag Na ppm ppm . 999-/ 1 49 .126 .00328 .249 .32793 .50009 EIem A1 Units ppm Avge 24 .966 SDev .077 ?RSD .30654 #r #z #3 25 .052 24 .907 24.939 Errors QC Pass Value 25.000 Range 10.500 EIem Cr Units ppm Avge 2 .0222 SDev .0105 ?RSD .52027 #r #z #s 2 .0325 2 .0]-]-4 2 .0228 QC Pass QC Pass QC Pass .50000 .s0000 2.0000 10.500 10.500 10.500 Sb ppm . 497 84 .00053 .12-7 45 . 497 83 . 497 2t .49848 Co ppm 2 .0291, .0a24 .61038 2 .043L 2 .0195 2 .0247 K- ppm 49 .7 B9 .]-28 .25'7 65 49. BB4 49 .643 49.839 V_ ppm 2.0119 .0058 .28829 2 .0183 2.0069 2 .0106 QC Pass As ppm . s0l.69 .00292 .58275 .50506 .5002]. .49980 Cu ppm 1.9804 .0042 .20994 1.98s1 1.9774 1.9787 QC Pass 2 .0 000 10.500 Ni ppm 2 . A4tt .0102 .4997l- 2 . 0526 2 .0373 2.0333 Zn ppm 2 .07 48 .0054 .30872 2.0819 2 . O695 2 . 0729 Ba ppm 2 . OO97 . o o2'7 . 13 562 2 .0728 2.0077 2.0085 Fe ppm 25 .429 .093 .3 6449 25 .527 25.343 25 .4]-6 QC Pass 25.000 10.500 Se/1, ppm .50009 .00310 .51BBB . s0323 .49705 .49999 B- ppm 2.0031 .0102 .50818 2.0148 1.9960 1.9985 Be ppm 2.0s93 .0059 .28620 2.0550 2.05s0 2 .0s69 QC Pass 2.0000 10.500 Pb/L ppm .50767 .00s00 . 98 532 .51153 .50198 .50933 Se/z ppm .49818 .00275 . 55 229 .50045 .495j2 . 4989 6 Mo ppm 2 .0263 .0079 .39004 2 .0352 2 . O20t 2 .0236 QC Pass 1.0031 .99649 .99977 Li ppm 2.0358 .0023 .11399 2 . O 3 84 2.0338 2 .0354 QC Pass 49 .91,6 49 .444 49 . Bt7 Sr ppm 2 .020-7 .0043 .2a4tt 2 . 0257 2 .0l.84 2.0180 Errors QC Pass QC Pass Va1ue 2.0000 2.0000 Range 10.500 10.500 NOCHECK NOCHECK QC Pass s0.000 10. s00 Elem Mn Units ppm Avge 2 .0366 SDev .0113 ?RSD . 55 673 #r #z #: 2.0481 2 .0254 2 .0364 Errors QC Pass Value 2.0000 Range 10.500 Elem Tl Unit s ppm Avge 1.0432 SDev .0054 ?RSD . 53 847 #r #z #: Errors .99986 1.0002 1 . 0 094 QC Pass QC Pass QC Pass 50.000 2.0000 10. s00 10.500 NOCHECK NOCHECK QC Pass QC Pass 1.0000 50.000 10.500 10.500 QC Pass QC Pass Appendix F - 189 QC Pass 184 Analysis Report Value 1.0000 Range 10.500 EIem Ti Units ppm Avge 2 .0534 SDev .0042 %RSD .20s33 #r #z #: 2 .0517 2 .0493 2 .0532 Errors QC Pass Value 2.0000 Range 10.500 Intstd 1 Mode Counts Elem Y Wavlen 37a.030 Avge 21509 SDev 189 - 1701 ?RSD . B'7 9 47 93 #r #z #: 21,29L 27616 21627 QC St.andard 03/70/oG o1:54:02 PM page 2 2 .0000 10.500 2.0000 10.500 Sn ppm 2 . 0286 .0068 .33765 2 .0364 2 .0235 2 .0258 2.0000 10 . s00 Si ppm 2.0109 .0099 . 4 91,7 1, 2 .4220 2.0030 2.0078 2.0000 10.500 P- ppm 2.4047 . 01,12 .81580 2.7t94 2.0858 2.7087 2.0000 10.500 Pb ppm .50725 .00l-94 .38277 . s0895 .50514 .50765 QC Pass QC Pass 2.0000 2.0000 10.500 10.500 2 NOTUSED QC Pass QC Pass QC Pass 2.0000 .50000 .s0000 10.500 10.500 10.500 2.0000 10.500 Se ppm . 49 91,6 .00282 .554s0 . 5 0l.71, .49513 .49953 6'7 NOTUSED NOTUSED 345 NOTUSED NOTUSED NOTUSED Appendix F - 190 185 Analysis Report Method: TRA20505 Sample Name: CCB2 Run Time: 03/ao/oe 13:54:05 Comment : Mode: CONC Corr. Factor: 1 03/1,0/05 01: 59:57 PM Operator: page 1 Ca ppm - .00087 .00079 91.030 .00001 - .00153 - .00109 Mg ppm - . 0 01,57 .00295 177.41_ -.00035 .00042 -.00s06 Na ppm -.326s6 .L7935 54.919 - . 3 5664 -.48896 -.13408 Sr ppm - .00001 .00003 3 04 .71 EIem Al Uni t. s ppm Avge .00268 SDev .00384 %RSD l-43 .62 #r #z #s - .00092 .00222 .00673 Errors LC Pass High .10s00 Low - .10500 EIem Cr Units ppm Avge - .00006 SDev .00014 ?RSD 237 .23 #r #z #: - .00002 .00006 - .00021 Errors LC Pass High .00360 Low - .00350 Elem Mn Units ppm Avge - .00001 SDev .00007 ?RSD 519.23 #r #z #s - .00001 - .00008 .00006 Errors LC Pass High .00180 Low - .00180 Elem TI Uni t s pprn Avge .00030 SDev .00257 ?RSD 864 .7 B #r #z #: Errors -.00027 .00310 - .00194 LC Pass LC Pass LC Pass .01400 .00330 -.01400 -.00330 LC Pass LC Pass .00160 .00180 - .00150 - .00180 LC Pass LC Pass .00082 .05s00 - .00082 - .06s00 LC Pass LC Pass .00220 .00700 -.0a220 -.00700 LC Pass NOCHECK .04900 - .04900 NOCHECK LC Pass .04900 - .04900 Sb ppm - .00148 . 0 0118 79.403 -.00279 - . 0 021,3 -.00012 Co ppm -.00427 .00028 104 .71_ 00008 00014 00059 K- ppm .72002 .00680 s.6665 . 11283 .l-20 B B .l-2635 LC Pass .32200 -.32200 V- ppm - .00017 .00034 207.05 .00003 .00003 - .00055 LC Pass As ppm .0001s .00087 555 .73 - .00081 .00038 .00088 Cu ppm - .00034 .00073 214 .53 .00025 -.00012 -.00115 Ni ppm - .00080 .00041 s1. 026 00082 00120 00038 Zn ppm .00005 .0000s 104.11 .00005 -.00001 .00008 Ba ppm - .00001 .00003 287 .48 . 0 0 402 - .00002 - .00003 Fe ppm .00205 .00693 337.90 .00685 .00518 - .00s89 Se/r ppm .00201, .003s6 1,77.51 .00251 - .00180 .00525 B- ppm .00280 .00068 24 .14 3 .00355 .00262 .00224 Be ppm .00025 .00009 37 .052 .00019 .0003s .00020 Pb/t ppm - .00194 .0021 B t43 .57 -.00284 - .00476 . 0 0118 Se/2 ppm - .00041 .00085 206.50 .00036 -.00026 - .00133 Mo ppm .00208 .00109 52 .274 .00333 .00159 .00133 LC Pass Cd ppm - .00020 .00004 24 .87 2 - .00018 - .00025 - .00017 Pb /2 ppm .00091 .0003s 38.060 .00113 .00108 .00051 Ag ppm .00330 .000s3 16 .110 .00278 .00327 .00384 Li ppm .0007-7 .000]-7 21, .640 LC PAss NOCHECK NOCHECK .00380 -.00380 LC Pass LC Pass .00970 L.4730 - .00970 -1.4730 .00094 .00002 .000't6 -.00000 .00061 - .00004 LC Pass LC Pass Appendix F - 191 LC Pass LC Pass 186 Analysis Report 03 /70 / 06 o1 : 59:57 PM page 2 High .01000 .00500 .00380 .03100 .00880 -00270 .00130 Low -.01000 -.00500 -.00380 -.03100 -.00880 - .00210 -.00130 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge -.00003 - - 00105 .00175 .00924 .00043 .00071 SDev .00004 .00008 .00181 .001L1 .00071 .00102 ?RSD 104 .38 B .0915 ]-02 .s9 1,2 .006 A64 .24 143 .35 #1 -.0000s - .00109 .00362. .008s0 .00031 .00141 #z .00001 -.0009s .00000 .01052 - .00021 -.00046 #3 .00005 - .00110 .00167 .00871 .00119 .00118 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High .00150 .00770 .05500 .02100 .00370 .00430 Low -.00160 - .00770 -.05500 - .02100 - .00370 - .00430 Intstd 1 Mode Counts Elem Y Wavlen 37,-. 03 0 Avge 21949 SDev 50. 02267 ?RSD .227 9027 #r 279s0 #z 2L999 #: 2L899 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 192 787 Analysis Report Method: TRA20505 Samp1e Name: HOLJBD Run Time: 03 /a0 / A6 L4:00: 00 Comment : Mode: CONC Corr. Factor: 1 03 / to / 06 o2:05 : 52 PM Operator: Sb ppm . 223 49 .00060 .26880 .22287 .2237 5 .22393 Co ppm .13110 .00564 4.3020 .1,2535 . 13 t32 .13 662 LC Pass 100.00 - .05000 K- ppm 62 .19 B .7 24 1 . 1642 62 .966 61.521 62 . LO2 LC Pass 200.00 -s.0000 V_ ppm .9237 6 .0090s .97 954 . 91 6]-4 .92L3'7 .9337 6 LC Pass As ppm .1BBBB . 0 01,52 .8577]-. .18956 .18703 .19005 Cu ppm .35382 .00348 .98413 .35578 .34980 .35589 Ni ppm .6s567 .00923 1, .4A72 .64580 .55772 .66409 Zn ppm .80381 .00134 . 9127 5 .7 97 46 .8021,4 .81184 Ba ppm .44568 .00394 .88509 . 4497 1 .44190 .44537 Fe ppm 332. 9s 4 . BB I .466s 327. B6 333.40 337.50 Se /t ppm .15136 .00949 6.2683 .7462'7 .L4550 .1,6237 B ppm .89s81 .00923 1.0305 . B 9 439 . BB73B .90s68 Be ppm .0s539 .00133 2.3988 . 05 406 .05538 .05672 Pb/1, ppm .19462 .02524 13.483 . 21,59 5 .20116 .15572 Se/2 ppm .14202 .0oss5 3 .91-73 .1_4447 .74s93 .13555 Mo ppm . 4625 6 .00587 7 .2695 .45766 .46119 .45913 LC Pass Cd ppm . 04 684 .00029 . 6Ll.7 2 . 04 654 . 04 687 .0471,L Pb/ 2 ppm .20388 . o2t7 9 10.689 .182].5 .2037 3 .2257 4 Ag ppm .06267 .00423 6 .7 544 .05796 .05390 .0561s Li ppm .29549 .00493 !.6680 .30090 .29]-25 .29432 LC Pass page 1 Ca ppm 52 .510 .908 I -'7 295 s1.516 52 .71,7 53 . 297 Mg ppm 19. 463 .404 2 . 07 50 19.041 19.502 19 . 847 Na ppm 49.840 .7 32 I .4693 50. 664 49 .592 49.264 Sr ppm .57 469 .00481 .83784 .57965 .57003 .57439 LC Pass Bl ern AI Units ppm Avge 344 .49 SDev 1.-l 4 ?RSD .50549 #r #z #: 344 .44 342.78 345.26 Errors LC Pass High 700.00 Low -.20000 El em Cr Units ppm Avge .13948 SDev .00915 ?RSD a.2377 #r #z #: .72950 .7 4747 .7 47 48 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge .33474 SDev .004]_9 ?RSD 7 .252L #r #z #g .33070 .33 443 .33907 Errors LC Pass High 30.000 Low - .01500 Elem T1 Units ppm Avge .36977 SDev .00-1L6 ?RSD 1.9407 #r #z #: Errors .37 7 27 .366s6 .3 63 67 LC Pass LC Pass LC Pass 20.000 30.000 - .05000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00s00 LC Pass LC Pass 40.000 600.00 - .00500 s.0000 LC Pass LC Pass 50.000 1400.0 - .02500 - .10000 NOCHECK NOCHECK LC Pass 700.00 -5.0000 LC Pass NOCHECK NOCHECK 100.00 - .04000 LC Pass LC Pass 4.0000 800.00 - .02000 -s.0000 LC Pass LC Pass Appendix F - 193 1BB Analysis Report 03 / 10 / aG o2:05 : 52 PM page 2 5.0000 10.000 - .05000 - .05000 Se ppm .1,4547 .00063 . 4337 2 .1,4540 .1_4 5 13 .14487 High Low 70.000 -.02000 100.00 - .02500 Sn ppm .49151 .00857 7 .7 428 .4821,8 .49332 . 499 02 10.000 - .02000 Si ppm 1,2 .93 1 .114 .88354 12.884 12 .847 13 .051 40.000 - .50000 P- ppm 6.0976 .0596 .9'7779 6.0540 5.0734 5.16s6 LC Pass 40.000 - .30000 40.000 -.04000 Pb ppm .20l.23 .00629 3 .1275 .19417 .20327 . 20 625 Elem Ti Units ppm Avge 2 .267 6 SDev - 0:..26 ?RSD .555s0 #r #z #s 2.250-l 2.2500 2 .2827 Errors LC Pass High 40.000 Low - .05000 fntstd 1 Mode Counts EIem Y Wavlen 377.030 Avge 206-l B SDev 617.1873 ?RSD 2.984809 #r #z #: 2L3 49 20548 20135 LC Pass LC Pass 40.000 40.000 - .10000 -1.0000 2 NOTUSED 34 NOTUSED NOTUSED LC Pass LC Pass 70.000 30.000 - .00400 -.01000 567 NOTUSED NOTUSED NOTUSED Appendix F - 194 189 Analysis Report Method: TRA20505 Sample Name: HXQ1X Run Time: 03/a0/06 74:07:19 Comment : Mode: CONC Corr. Factor: 1 03 / to / 05 02:13 : 11 PM Operator: - .0025s -.00322 - .00309 LC Pass 20.000 - .06000 Co ppm .01164 .00084 t .1911 . 011,87 .01234 . 01 071- LC Pass 100.00 - .0s000 K- ppm .40828 . 020 49 5.0L99 .41592 .42305 .3B4BB V- ppm .01255 .00093 '7 .3 910 .01289 .01326 .01150 LC Pass Cu ppm . 03 627 .00008 .278s6 .03618 . 03 629 .03633 Ni ppm .05016 . 0 01,49 2.957s .05138 .05059 .04850 Zn ppm 5 . 451,4 .0263 .48238 5 .4455 5.4801 5 .4285 Fe ppm 1.33L4 . 0115 .87344 1.3272 1.3 446 1.3225 Se/1 ppm - .000s2 .00943 1817.9 .00729 .00245 - .01100 B_ ppm .11185 .00212 1.8956 .11303 . 11 31-2 .10940 Be ppm .00007 .00028 473 .67 - .00017 - .00000 .00038 Pb /7 ppm .09s90 .01204 L2.557 . 10 s4t .09993 .08235 Se/z ppm .007-79 .00407 221.39 - .00240 .00205 .00s72 Mo ppm .00372 .00039 a2 . s69 .0032l. .00346 .00269 LC Pass Cd ppm 1.891 4 .0a24 .651-27 1 . B 948 1.9108 1. BB65 Pb /2 ppm .082s6 .0054s 5 .6444 .0'7872 .0801s .08880 0L9 49 4203 6 01820 Li ppm - 0 0 50'7 .00016 3.0916 .00490 .00522 .00s09 LC Pass page 1 Ca ppm 321 .7 7 2 .35 .72985 32l-. 3 B 324.2a 319. ss Mg ppm 25 .044 . a5'7 .62558 24 .991 25.220 24 .920 34.1'72 34.185 33.432 Sr ppm .7 L7 55 .00084 .11673 .71667 . -717 65 .11-834 LC Pass Elem AI Units ppm Avge 22 .3 07 SDev .01,7 ?RSD . A7 550 #r #z #: 22.306 22.325 22.294 Errors LC Pass High 700.00 Low -.20000 EIem Cr Units ppm Avge .01088 SDev .00128 ?RSD 11.764 #r #z #: 01143 01180 00942 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .027 0 0 SDev .00034 ?RSD t .2639 #r #z #: . 027 01 .a2730 . 026 63 Errors LC Pass High 30.000 Low .01500 EIem TI Units ppm Avge L-.70521 SDev .03'7l_l ?RSD 5 .2626 #r #z #: Errors 6 62'7 6 7 21,33 73153 Low Sb As ppm ppm -.00295 .00155 .00035 .001,22 12.045 73 .903 Ba ppm H3 6 .520 .042 . 11 526 .00289 H36. s4B .00151 H36 .547 .00045 H36.41].. LC Pass LC High LC Pass 30.000 30.000 10.000 -.01000 -.01000 -.00s00 LC Pass LC Pass 40 .000 500.00 - .00500 -5.0000 LC Pass LC Pass s0.000 1400.0 - .02500 - .10000 NOCHECK NOCHECK LC Pass 700.00 -5.0000 Ag Na ppm ppm .01935 33.930 .00109 .431 5 .61,25 I .2697 LC Pass LC Pass 20a.00 100.00 -s.0000 -.04000 NOCHECK NOCHECK LC Pass LC Pass 4 .0000 800.00 - .02000 -s.0000 L- L- L_ LC Pass LC Pass Appendix F - 195 LC 190 Analysis Report 03/1,0/06 o2:13:11 PM page 2 Hj-gh 70.000 100.00 10.000 40.000 40.000 5.0000 10.000 Low - .02000 -.02s00 -.02000 - .50000 - .04000 - .05000 -.05000 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge H49.958 .87014 4.3758 26 .393 .08753 .00136 SDev .326 .00520 .0271 .702 .00058 .00098 zRsD .6s32L .596'75 .63255 .38626 .667t0 72.517 #1 H49.588 .87065 4.3948 26 .394 .08819 .00115 #2 H50.202 .87598 4.3BBs 26 .494 .08731 .00242 #3 H50.08s .865s9 4.3440 26.290 .08708 .00048 Errors LC High LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.05000 -.10000 -1.0000 - .30000 -.00400 - .01000 Intstd 1 Mode Counts EIem Y Wavlen 37L. 03 0 Avge 20875 SDev 201,.2053 ?RSD .9538577 #r 207 6t #z 2a7s6 #: 271A7 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 196 191 Analysis Report Method: TRA20505 Sample Name: HXQ1XS Run Time: 03/70/06 74:13:14 Comment : Mode: CONC Corr. Factor: 1 03 /to / 06 o2 :19 : o5 PM Operatotr: Sb pprn . 1B 024 .00243 1.3498 .18l.22 .18202 .1,7 7 47 LC Pass 20.000 - .05000 Co ppm .10879 .00089 .81459 .10945 .109l=4 .10778 K- ppm 54.778 .181 .33082 54 .939 54.814 54 .582 V_ ppm .18501 .000s6 .30244 .18555 .18583 .18664 LC Pass .0221,6 .02t49 .02242 LC Pass 30.000 - .01000 Cu ppm .287 40 .00047 .15262 .287 7 L .287 62 .28686 Ni ppm .54697 .00250 .457 04 .54684 .549 44 .54445 Zn ppm 6 .9022 .021,5 . 31201, 6.9013 5 .9242 5. BB]-2 H3 6 .525 H36.590 H35.442 LC High 30.000 - .01000 Fe ppm 2 .4228 .0]-2'7 .524 B 1 2 .417 0 2 .4373 2.4139 Se l7 ppm . 0 5l.62 .00443 8.5793 . 05 629 .047 47 .0s110 B- ppm 1.0223 .0022 .21,328 1.0l.99 1.023l_ 1.0240 Be ppm .0s0s9 .00031 .61,006 .05026 .05088 .0s062 LC Pass 10.000 - .00s00 Pb/1- ppm .743 92 .00467 3 .2427 .1,4831 . 13 902 . L4443 Se/2 ppm .04820 .00155 3 .2404 . 04 826 .04973 . 04 66a Mo ppm .22432 .00151 . 5713 5 .22393 .22s98 .22304 LC Pass Cd ppm 2 .6137 .0079 .29511 2 .56-63 2 .6 817 2 . 671,2 LC Pass 40.000 - .00s00 Pb /2 ppm . 13 425 .00204 1.566s .1,2814 . 13 22a .13040 Ag ppm .06727 .000s3 .7 B 918 .11993 . 11 961, . 11 952 LC Pass page 1 Ca ppm 360. B9 1. 81 .50249 350 .32 352 .92 359.43 LC Pass 600.00 -5.0000 Mg ppm 37 .739 . 13 9 .36760 37 .623 37 .893 37 .7 0A Na ppm 79.777 .2'7 9 .3 49 42 7 .227 5 I .2241 t .2216 LC Pass Elem A1 Units ppm Avge 25.372 SDev .092 ?RSD .364 0 9 #r #z #: 25.382 25.347 2s.208 Errors LC Pass High 700.00 Low - .2 000 0 Elem Cr Units ppm Avge .20945 SDev .00061 ?RSD .2937 0 #r #z #: .20905 - 21,015 .2091,4 Errors LC Pass High 100.00 Low - .01000 EI em Mn Units ppm Avge . 13 1,81 SDev .00035 ?RSD .2631 0 #r #z #: .13\52 .13222 .13185 Errors LC Pass High 30.000 Low - .01500 El- em Tl Units ppm Avge L- .25906 SDev .03305 ?RSD 1,2 .'7 6t #r #z #: Errors 22232 28641 25 844 Low As Ba ppm ppm .02202 H35.519 .00048 .074 2.7738 .20324 LC Pass LC Pass 100.00 s0.000 -.0s000 - .02500 LC Pass NOCHECK 14 0 0 . 0 - .10000 NOCHECK LC Pass 700.00 -s.0000 LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHECK NOCHECK LC Pass LC Pass 4.0000 800.00 - .02000 -5.0000 .0670a 79.996 .06788 19.8'72 .0569]- 79.463 Li Sr ppm ppm .11969 7.2246 .00022 .0029 .18204 .23920 L- L- L- LC Pass LC Pass Appendix F - 197 LC 192 Analysis Report 03/to/06 o2:19:05 PM page 2 High 70.000 100.00 l-0.000 40.000 40.000 5.0000 10.000 Low -.02000 -.02500 - .02000 - .50000 -.04000 -.05000 -.05\000 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge H45.504 7.1251 3.7949 27 .55L .L3527 .04969 SDev .118 .0022 .01-05 .073 .00030 .00147 ?RSD .25942 .19502 .27790 .2645s .22004 2.9665 #1 H45.40s 1-.1-227 3.7998 27.492 .13s33 .05131 #2 H4s.63s 7.)-269 3.8022 27 .633 .13495 .04931 #3 H45 .472 1 .1258 3 -7829 2'7 .530 .13s54 .04844 Errors LC High LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.05000 -.10000 -1.0000 - .30000 -.00400 -.01000 Intst.d 1 Mode Counts EIem Y Wavlen 371,.030 Avge 21-006 SDev 113.8169 ?RSD .5418220 #r 2l.017 #Z 2OBBB #: 21774 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 198 193 Analysis Report Method: TRA20505 Sample Name: HXQ1XD Run Time: 03/70/Oe t4:19:09 Comment: Mode : CONC Corr. Fact.or: 1 03/70/06 o2:25:01 PM Operator: Fe ppm 2.5299 .0083 . 3287 7 2.5340 2 .5203 2.53s3 LC Pass 1400.0 - .10000 Se/t ppm . 0 4921 . 00 223 4.5340 .0501 9 .0467 0 .05031 Pb/1 ppm .2L1 5 5 .00370 1.V470 .21,528 .207 89 .27748 Cd ppm 1. BB44 .0128 .67 851 1.8788 1.8753 1.8990 Pb/2 ppm .1927'7 .00282 1 .4652 .19008 . 19 57l. .19253 06s95 05535 06629 Li ppm .72035 .00042 .35321, .72082 .1,2027 .11999 LC Pass page 1 Ca ppm 355.63 1,.15 . 4971 B 355.31 354. 0 5 357.51 Mg ppm 36.694 .205 .55757 36.583 35 .495 36.904 79.035 7 B .1,43 7 B .54l. Sr ppm t.255s .0032 .25524 L .25'12 7.2530 t.2593 LC Pass EIem A1 Units ppm Avge 25.241- SDev .055 ?RSD .21,97 5 #.1 #z #: 25 .297 25 .181 25.257 Errors LC Pass High 700.00 Low -.20000 Elem Cr Units ppm Avge .20 3 54 SDev .00153 %RSD .7 5337 #r #z #: .20359 .20198 .20s04 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge . 133 93 SDev .00082 ?RSD .6l-4 O B #r #z #: . 13 434 .13299 .13 44-l Errors LC Pass High 30.000 Low - .01500 EIem T1 Units ppm Avge L-.39368 SDev . 03 024 ?RSD 1 .6823 #r #z #: Errors L- . 3587 6 L - . 411,47 L- . 41087 LC Pass LC Pass 2A .000 30.000 - .06000 - .01000 As Ba ppm ppm . 023 5 6 H3'7 .49'7 .00048 .111 2.0504 .29598 . 023 1 8 H37 .621 .02410 I137.407 .02339 H37.462 Cu ppm .28682 .00051 . 2l.40 6 .287 09 .286l.2 . 28'7 25 LC Pass 50.000 -.02500 Ni ppm .53202 .00503 .94480 . 53 042 .52798 .53765 Be ppm .04910 .00027 .55880 .04895 .04893 .04942 LC High LC Pass 30.000 10.000 -.01000 - .00500 LC Pass LC Pass 40.000 600.00 -.00500 -5.0000 Sb ppm .18060 .00229 7.2588 .18079 .1,7 822 .18279 Co ppm .10365 .00093 .89s23 . 10 267 .10377 .10452 LC Pass 100.00 - .05000 K- ppm 54 .592 .21,8 .39972 s4 - 836 54 .4]_6 54 .524 LC Pass 200.00 -5.0000 V_ ppm .18873 .00097 . 511,47 .1BBBO .18773 .18966 LC Pass Zn ppm 7 .3070 .0472 . 6 4537 7 .3073 1 .2591 1 .3540 NOCHECK NOCHECK LC Pass 700.00 -5.0000 B_ ppm .98767 .00488 . 49 473 . 9B 2Bt .98153 .9925"7 Pass LC Pass Appendix F - 199 Se/z ppm .05150 .00277 4 .21,24 .04903 .0s238 .05310 Mo ppm .22331 .00L1,7 .52463 .22252 .2227 5 .22466 LC Pass Ag Na ppm ppm .05585 78.573 .00048 .447 .72957 .55879 LC Pass NOCHECK NOCHECK LC Pass LC Pass 100.00 4.0000 800.00 -.04000 .02000 -s.0000 LC Low LC l.94 Analysis Report A3 / 10 / 05 02 :25 :07 PM page 2 High 70 - 000 100.00 10.000 40.000 40.000 5.0000 10.000 Low - .02000 -.02500 - .02000 - .50000 -.04000 -.05000 - .05000 Elem Ti Sn Si P* Pb Se Units ppm ppm ppm ppm ppm ppm Avge H54-847 1.1549 4.7026 27.565 .19948 .05109 SDev .255 .0075 .0228 .L77 .00057 .00130 tRSD .46434 .65387 .48546 .53986 .33788 2.5382 #r H54.905 t.a5g7 4.7079 27 .'778 .19884 .0499s #2 H54 .569 7 .a6a4 4 .6802 2't -462 .200L9 . 05082 #3 H55.068 7.1-'t37 4.7258 2't .7s9 .19940 . Os25o Errors LC High LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low - .05000 - .10000 -1 .0000 - .30000 - .00400 - .01000 Intstd 1 Mode Counts EIem Y Wavlen 371,.030 Avge 21444 SDev 53. 47356 %RSD .2493596 #r 2]-4].2 #z 2]-s06 #: 2L4L5 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 200 195 Analysis Report Method: TRA20505 Sample Name:' HXQ2H Run Time: 03/a0/06 7,4:25:04 , Comment : Mode: CONC Corr. Factor: 1 03/L0/06 o2:30:56 PM Operator: Co ppm .00933 .00061 5 .5757 .00902 .00895 . 010 04 K- ppm .45428 .00297 .65315 .45334 .45191 .457 6a V_ ppm .01583 .00050 3.1749 . 01 526 .01604 . 01 620 LC Pass Cu ppm .03896 .00033 .85010 .03861 . 03 927 .03901 Ni ppm .04994 .00092 1.8468 .05007 .04895 .05078 Zn ppm 5.8481 .0342 .58510 5.8255 5.8313 5 - BB-l 4 Fe ppm 7 .4324 .0150 1.0412 I .4220 I .4250 L .4494 Se/t ppm -.00097 .00044 45 .695 - .00139 - .00101 - .00051 B- ppm .04703 .00083 7.-7 655 .04642 . 04 669 . o4-l 97 Be ppm .00002 .00009 424 .24 - .00001 . o0 ot2 - .0000s Pb/1- ppm .1,2089 .00083 .69007 .t2168 .72002 .1,2097 Se/z ppm .0019s .00085 43 .667 .00105 .00275 .00206 Mo ppm .00424 .00048 11 . 243 .00440 .00370 .0046l- LC Pass Cd ppm 2 .7298 .0143 .66963 2 .7223 2.1208 2.7462 Li ppm .00534 .00016 2.9635 .00551 .00s30 .00520 LC Pass page 1 Ca ppm 319.03 7 .44 .44139 318.10 377. B1 320 .51 Sr ppm .7 27 t5 .00253 .34801 .7 2822 .7 2426 .72898 LC Pass EIem AI Units ppm Avge 22 .7 68 SDev .073 ?RSD .31964 #r #z #3 22.807 22 .684 22.814 Errors LC Pass High 700.00 Low -.20000 Elem Cr Units ppm Avge .0132L SDev .00039 ?RSD 2 .9 854 #l- #z #3 .01335 . 0127 6 .013s0 Errors LC Pass High 100.00 Low - .01000 El em Mn Units ppm Avge . 03 334 SDev .00028 ?RSD . 83 495 #r #z #: 03325 03311 03355 Errors LC Pass High 30.000 Low - .01500 EIem TI Units ppm Avge L- . 7 87 95 SDev .02660 ?RSD 3.3760 #r #z #: Errors 7 5859 81045 79482 Low Sb As ppm ppm - .00s6s .00l-29 .00150 .001,l''7 28.374 90.395 00541 00573 00381 Ba ppm H36.706 . 114 .30960 00014 H36.722 00247 H35.586 001,27 H35.811 LC Pass LC Pass 20 .000 30.000 - .06000 - .01000 LC High LC Pass 30.000 10.000 - .01000 - .00500 LC Pass LC Pass 40 .000 600.00 - .00500 -5.0000 Pb/ 2 ppm .10511 .00082 .7 6862 Mg ppm 19 .481 .]-29 .66309 .10518 19. 428 .10671, 19.386 .10643 19.628 NOCHECK LC Pass 700.00 -5.0000 Ag Na ppm ppm .01804 28.107 .00036 .243 l_.9'709 .85539 . 01'7 83 28 .726 .01784 27.855 .01845 28.340 LC Pass LC Pass 4.0000 800.00 - .02000 -5.0000 LC Pass LC Pass 100.00 50.000 - .05000 - .02500 LC Pass NOCHECK 1400.0 - .10000 LC Pass LC Pass 200.00 100.00 -5.0000 -.04000 NOCHECK NOCHECK L- L. L- LC Pass LC Pass Appendix F - 201 o LC L96 Analysis Report 03/to/06 o2:30:56 PM page 2 High 70.000 100.00 10.000 40.000 40.000 5.0000 10.000 Low -.02000 - .02500 - .02000 - .50000 - .04000 - .0s000 - .05000 EIem Ti Sn si P_ Pb se Units ppm ppm ppm ppm ppm ppm Avge H54.99'7 .83279 5.3698 25.65L .11153 .00132 SDev .220 .00112 .0478 .055 .00030 .00067 ?RSD .39923 .13s05 . 89082 .25383 .2681,0 50 .420 #1 H54.923 .83284 5.3339 25.576 .LLL24 .000s7 #2 H54.823 .83155 5.3515 25.69s .LLLs2 .00183 #3 Hs5.244 .83390 s.qi+t 25.G82 .11184 .00158 Errors LC High LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low - .05000 -.10000 -1.0000 - .30000 -.00400 - .01000 Intstd 1 Mode Counts EIem Y Wavlen 377.030 Avge 21300 SDev 58.38371 %RSD .21 4tAt4 #r 2L2eB #z 2a3s9 #: 21-243 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 202 L97 Analysis Report Method: TRA20505 Samp1e Name: HXQ2M Run Time: 03/a0/06 74:31:00 Comment : Mode: CONC Corr. Factor: 1 03/ta/oG o2:36:51 PM Operator: EIem AI Units ppm Avge 22 .0 7 0 SDev .41a ?RSD 1.8535 #r #z #: 2t.59s 22 .323 22 .292 Errors LC Pass High 700.00 Low -.20000 EIem Cr Unit s ppm Avge .01091 SDev .00L51 ZRSD L4.397 #r #z #g 00913 01208 01154 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge .02684 SDev .00069 ?RSD 2 .557 6 #r #z #3 02606 027 32 o2"7 75 Errors LC Pass High 30.000 Low - .01500 EI em TI Units ppm Avge L-.63012 SDev . 03 695 ?RSD 5. B59O #r #z #: Errors 59148 66485 63583 Low LC Pass LC Pass 20 .000 30.000 - .05000 - .01000 As Ba pprn ppm .00]-25 H36.300 .00115 .645 92 . 002 1, .7 7'/ B .00016 H35.559 .00113 H36 .736 .00246 H36.606 Cu ppm .03035 .00099 3.2640 .02937 .03035 .03135 Fe ppm 1.1762 .0313 2 .6604 1.1449 1.1873 r.2004 Be ppm - .00009 .00024 270.08 .00018 - .00018 -.00027 LC High LC Pass 30.000 10.000 - .01000 - .00500 2.A744 305.58 2.0848 31,7.99 2 .07 65 377 . 91 LC Pass LC Pass 40 .000 500.00 -.00s00 -5.0000 page 1 Cd ppm 2.0s85 .0385 1.8682 Ca ppm 313. B3 7 .1,4 2 .27 65 Pb/2 ppm . 06 486 .001,'76 2.7159 .056'75 .05326 .054s6 Mg ppm 19. 826 .4l.7 2.t050 19.344 20 .07 6 20.0s8 Ag Na ppm ppm . 0 1 443 28 .242 .00767 .665 11.553 2.3ss8 . 01 252 27 .47 6 . 01523 28 . 6-/ 4 .01555 28.57'7 Li ppm .0041 6 .0001s 3.0587 .00460 .00487 .00482 LC Pass Sr ppm .71,068 . 01262 L .17 62 .69611 .7 rB23 -71,'770 LC Pass LC Pass LC Pass 100.00 s0.000 - .05000 - .02500 Sb ppm . 0 011s .00299 260. 03 -.00220 .002l.2 .00353 Co ppm .00749 .00025 3.33s2 .00'72]- .00757 .00710 K- ppm .28823 . 023 92 8.2984 .26068 .30033 .30369 V- ppm .01230 .00093 7 .5429 .01140 .01225 :01325 LC Pass Ni ppm . 0 4531 .00185 4 .07 07 .04323 .04642 .04645 Zn ppm 5 .4473 .1051 1.9300 s.3259 5 . 5 071, 5.5089 Se/r ppm - . 0 0092 .00333 3 6 0 . 40 - . 0 0466 .001-76 .00012 B_ ppm .03444 .00189 5.4772 . 03 233 . 03 s94 .03s06 Pb/7 ppm .07041 .00554 1.8708 .06441, .07534 . 0714 B Se/2 ppm .00328 .001s0 45 .1 40 .00496 .0028s .00205 Mo ppm .0029"7 .00067 22.605 .00249 .00269 .00374 LC Pass LC Pass NOCHECK NOCHECK LC Pass 1400.0 700.00 - .10000 -5.0000 LC Pass LC Pass 200.00 100.00 -s.0000 - .04000 NOCHECK NOCHECK LC Pass LC Pass 4.0000 800.00 - .02000 -5.0000 L- L- L- LC Pass LC Pass Appendix F - 203 LC 198 Analysis Report 03/10/06 02:35:51 PM page 2 High 70.000 100.00 10.000 40.000 40.000 s.0000 10.000 Low -.02000 - .02500 -.02000 -.50000 -.04000 - .05000 -.05000 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge H44.920 .83707 5.2720 26 .506 .06710 .0O22L SDew .882 .0L742 .1084 .440 .00065 .00055 tRSD 1.9531 2.0810 2.0555 1,.6s94 .97009 24.893 #1 H43.903 .81598 5.t470 26.O0]- .06639 .00208 #2 H45.466 -8451,6 5.328s 25 -7L5 -O6't66 .00282 #3 H45.392 . B4B0s 5.3404 25.803 .06724 .00174 Errors LC High LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.05000 -.10000 -1.0000 - .30000 -.00400 - .01000 Intstd 1 Mode Counts Elem Y Wavlen 371. 03 0 Avge 272L6 SDev 303.5018 ?RSD 7.43 1034 #r 27s66 #z 2a041 #: 21,03 4 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 204 t99 Analysis Report Method: TRA20505 Samp1e Name: HXQ2V Run Time: o3/70/06 l-4:35:55 Comment : Mode: CONC Corr. Factor: 1 03 / to / 06 o2:42 47 PM Operator: a3233 03256 03189 - .01805 - .01780 - .02072 Co ppm .01399 .00l.70 12.]-47 .01502 .01492 . 01 203 K- ppm .46649 . 011 44 3 .139 4 .47571 .477 40 .4463-7 LC Pass 200.00 -s.0000 . 0 0 066 -.0001s .00457 Cu ppm .02698 .00018 .68646 .0271,9 .02687 . 02687 Ni ppm .10038 .00055 - 6491,9 .10a12 .09990 .100]-2 LC Pass 100.00 - .04000 Zn ppm 7.6'707 .0615 . 8 011,7 7 .6931 7 .7773 7 .6 010 Ba ppm 27 .925 .055 .23248 2'7.965 2'7 . 9 61, 27 .8 51 LC Pass 30.000 - .01000 Fe ppm 2.4850 .0283 1 . 137 0 2 .507 9 2 .4959 2 .4541, Se /t ppm .00009 . 0 01,32 1485.2 .00115 .00051 -.00139 NOCHECK B_ ppm . o2L7 6 .00110 5.057'7 .o2303 .02108 .021,11 Be ppm .00004 .0007-/ 405.43 - .00016 .00013 .00015 Pb /1, ppm .099l.7 .00350 3 .5293 .10318 .09761 .09572 Se/z ppm - .00052 .00723 236.-79 - .00156 .00083 - .00082 Mo ppm .00]-64 .00026 76.0s0 .0074L .00159 .00193 LC Pass Cd ppm 2.0538 .0220 1.06s9 2.0700 2 . OB2d 2.0393 Pb /2 ppm .05929 .0023-t 3 .42]-3 .06662 . 0171,4 . 07 0l-2 02922 02954 027 45 Li ppm .00422 .00015 3 .422'l .00439 . oo 477 .004l-1- LC Pass page 1 Ca ppm 235. 53 2 .03 .85159 236 .52 236. BB 233 .20 Mg ppm 59.220 .514 .867L7 s9.290 59. 696 58.676 29 .464 29 .797 29.087 Sr ppm .69329 .00l.49 .21,548 . 69 453 . 6937 2 .69153 LC Pass Elem Al Units ppm Avge 20 .925 SDev .058 ?RSD .3271,9 #r #z #: 20.9s9 20 .969 20 .845 Errors LC Pass High 700.00 Low - .20000 ,EIem Cr Units ppm Avge . 0177 B SDev .00078 ?RSD 4 .377 0 #r #z #: 01859 01,'7 71, 01,7 04 Elem Mn Units ppm Avge . 03 226 SDev .00034 %RSD 1.058-7 Sb As ppm ppm - .01865 .00035 .001,27 .00044 6.8310 l.23.96 LC Pass LC Pass 20.000 30.000 - .06000 - .01000 LC Pass LC Pass LC Pass 10.000 40.000 500.00 -.00500 -.00s00 -5.0000 Errors LC Pass LC Pass LC Pass High 100.00 100.00 s0.000 Low -.01000 -.05000 -.02500 LC Pass NOCHECK NOCHECK LC PASS 1400.0 7 00.00 -.10000 -5.0000 Ag Na ppm ppm . 028't 4 29 .249 .00113 .]-94 3.921-7 .66206 #r #z #3 Errors LC Pass High 30.000 Low - .01500 NOCHECK LC Pass LC Pass 4.0000 800.00 - .02000 -5.0000 EIem T1 V_ Units ppm ppm Avge L-1.0171 .02292 SDev .0307 .00137 %RSD 3.0190 5.97-/a #r #z #: Errors L-.9824L .02l-'73 L-1.0408 .02442 L- 1 .0287 .02260 LC Pass LC Pass Appendix F - 20s LC Low LC Pass 200 Analysis Report 03 / to / 06 o2:42:47 PM page 2 Hi-gh 70.000 100.00 10.000 40.000 40.000 s.0000 10.000 Low -.02000 - .02500 - .02000 -.50000 - .04000 -.05000 - .05000 Elem Ti Sn Si P- Pb Se Units ppm ppm ppm ppm ppm ppm Avge H69.497 .83189 4.4397 24.746 .0797a .00004 SDev .391 .00594 .0190 .720 .00057 .00090 *RSD .s6290 .71,442 .42832 .498s5 .71,4sO 2338 .4 #1 H59.518 .83379 4.4337 24.2LO .07923 -.00032 #2 H59.813 .83666 4.46tO 24.22L .08034 .00105 #3 H69.059 .82524 4.4245 24.007 .07955 -.00063 Errors LC High LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.05000 -.10000 -1.0000 -.30000 - .00400 - .01000 Intstd 1 Mode Counts EIem Y WavI en 37 1,. 0 3 0 Avge 20668 SDev 232.4019 ?RSD 1.124426 #r 20495 #z 20s7 B #: 20932 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 206 o O 20r Analysis Report Method: TRA20505 Sample Name: HXQ24 Run Time : 0 3 / a0 / 06 L4 :42 :50 Comment : Mode: CONC Corr. Factor: 1 03 / t0 / 06 02:48 :42 PM Operator: - .00070 - .00001 - .0005s LC Pass 20.000 - .06000 Co ppm .00726 .00048 5.5706 .00574 .00767 .00738 K- ppm . s47 86 .019l-4 3 .4931 .525-7 6 .55908 .55873 V- ppm . 017 5t .00072 4 .0774 . 017l-3 . 017 25 .01843 LC Pass 00004 o 01,22 00236 Cu ppm .047 09 .00051 1.0797 .04755 .0466s .04596 Ni ppm .067l.0 .0007]. 1.0s95 .06'769 .05737 .06634 Zn ppm 8.3597 .03s3 .42237 3295 397 5 3803 Ba ppm H34 .527 .042 .12l-25 H34 .555 H34 ;479 H34 .546 Fe ppm 1 . B 04 5 .0031 . t7 233 1.802A 1.8033 1.8080 Be ppm, .0000s .00013 279.86 -.00009 .00005 .0001,7 LC Pass 10.000 - .00500 Pb/1" ppm .07698 .00307 3.982s .07 697 .08006 .07392 Se/2 ppm .000s0 .00095 792 .21 - .00005 - .00005 .00151 Mo ppm .00s77 .00033 6 .434s .00484 .00ss1 .00515 LC Pass Cd ppm 2 .07 5A . 0 0 94 .45534 2 .0652 2.0841 2 .01 59 Pb/2 ppm .06183 .00115 1.85l.4 .06]-4'7 .05090 .06311 Ag ppm .01860 . 0 01,27 6.8201_ Li ppm .00582 .00006 1.0296 .00579 .00589 .00s79 LC Pass page 1 Ca ppm 269 .42 2 .09 .77586 267 . 04 27 0 .9'7 2-7 0 .25 Mg ppm 35.263 .21,3 .60273 3s.025 35.330 35 .433 Na ppm 37 .463 . ]-t4 .30574 Sr ppm . s01BB .00133 .264 B 5 . s0328 . s0472 . s0054 LC Pass Elem AI Units ppm Avge 2l .927 SDev .015 ?RSD .01 014 #r #z #g 2t .934 2t .924 21, .904 Errors LC Pass High 700.00 Low - .20000 Elem Cr Units ppm Avge . 0113 6 SDev . 00 042 ?RSD 3 .68 95 #r #z #: .01146 . 0117 2 .01090 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .03418 SDev .00020 ?RSD .59954 #r #z #g 03397 03438 03419 Errors LC Pass High 30.000 Low - .01500 Elem TI Units ppm Avge L-.58085 SDev .027 95 ?RSD 4 .81.24 #r #z #: Errors L- .54961 L- . 58946 L-.60349 Sb As ppm ppm - .00042 .0012a .00037 .00115 87 .018 95 .097 LC Pass LC High 30.000 30.000 - .01000 - .01000 LC Pass LC Pass 40 .000 600.00 - .00500 -5.0000 LC Pass LC Pass 100.00 50 .000 - .05000 - .02s00 LC Pass NOCHECK 1400.0 - .10000 NOCHECK LC Pass 700.00 -5.0000 LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHECK NOCHECK .01113 31 .345 .01928 37.573 .01938 31 .4'71, LC Pass LC Pass 4.0000 800.00 - .02000 -5.0000 Se/1, ppm .00]-32 .00722 92 .520 .0020a .00204 - .00009 B- ppm .01996 .000s9 2 .9528 .01964 .02064 .01960 B B B Pass LC Pass Appendix F - 207 LC Low LC 202 Analysis Report High Low #r #z #: #r #z #: 70.000 -.02000 100.00 - .02500 Sn ppm .87 9l_9 .00531 .50449 .87305 .88255 .8819s 40.000 - .04000 Pb ppm .06737 .00031 .45949 .06'7L]- .06772 .06730 5.0000 - .05000 Se ppm . 0 0111 .00023 2t .13 1 .00097 .00098 .00138 page 2 10.000 - .05000 7 NOTUSED 03 / 70 / 06 02:48 :42 PM 10.000 40.000 - .02000 - .50000 EIem Ti Units pprn Avge H42 .082 SDev .099 ?RSD .2364A Si ppm s.0319 .0187 .37 23 6 5.0796 5.0226 s.0534 P- ppm 23 .534 .181 .17 0 44 23 .337 23 .51 0 23 .695 Errors LC High LC Pass High 40.000 40.000 Low -.05000 -.10000 LC Pass LC Pass 40.000 40.000 -1.0000 ..30000 LC Pass LC Pass 70.000 30.000 - .00400 - .01000 H41.958 H42 .1,52 H42 . T25 207 t6 20s85 20585 Intstd 1 Mode Counts EIem Y Wavlen 37 L. 0 3 0 Avge 20629 SDev 7 5 .1,2697 ?RSD .3647828 NOTUSED NOTUSED NOTUSED NOTUSBD NOTUSED Appendix F 208 203 Analysis Report Method: TRA20505 Sample Name: HXQ3D Run Time : 0 3 / t0 / oG t4 :48 :45 Comment : Mode: CONC Corr. Factor: 1 03 / 70 / Oe 02 :54 :37 pM Operator: Sb ppm .00502 .00283 46 .97 B .00913 .00531 .00351 Co ppm .007r1, . 0 0116 15.315 .00843 .00565 .00624 K- ppm .40844 .0171,2 4 .1_927 .42785 .39546 .40201, LC Pass 200.00 -5.0000 V_ ppm .01200 .00150 t2 .477 As ppm .00045 .00053 14 0 .92 .00100 -.00024 .000s7 Cu ppm .04729 .00072 1.5115 .04811 . 04 595 .04681 Ni ppm .09154 .00089 .91372 . 0 9252 .09l.34 .09077 LC Pass 100.00 - .04000 Zn ppm 7 .1,922 .0272 .37 7 69 223s 1_7'7 B 17 52 Ba ppm H35.574 .100 .27956 H3 5 .7 2-7 H35 .576 H35. s39 Fe ppm 1.3332 .0327 2.4501 1.3701 1.3111 1.3178 Be ppm .00013 .00001 5 .2825 .00013 .00013 .00014 Pb/ 7 ppm . 03 632 .00742 20 .43'7 .02775 .04033 .04086 Se/z ppm .00324 .00337 104.0s .00707 .00185 .00077 Mo ppm .00269 .00032 11.824 .0030s .00256 .00246 LC Pass Cd ppm 2.6860 .0139 . 51 62L 2. -)zr. 2. LC 40 1 0l-7 6754 6809 page 1 Ca ppm 261, .42 1.53 .58355 263.18 260.50 260.48 EI em AI Units ppm Avge 22.104 SDev . 04 B ?RSD .21,526 #r #z #: 22 .10 5 22 .151 22.056 Errors LC Pass High 700.00 Low - .20000 EIem Cr Units ppm Avge .01765 SDev - 00059 ?RSD 3. B9OO #r #z #: .01589 .01785 . 01 822 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .028 9 9 SDev .00011 ?RSD .38]-23 #r #z #g 02900 O2BBB 0291,O Errors LC Pass High 30.000 Low -.01500 Elem T1 Units ppm Avge L- . 4261,8 SDev .00990 ?RSD 2 .321,9 #r L-.41s3s #z L - .4284s #: L- . 4347s Errors LC Low LC Pass LC Pass 20.000 30.000 - .06000 -.01000 LC High LC Pass 30.000 10.000 - .01000 - .00500 Pass LC Pass .000 500.00 00500 -s.0000 LC Pass LC Pass 100.00 s0.000 - .05000 - .02500 LC Pass NOCHECK 1400.0 - .10000 NOCHECK LC Pass 700.00 -s.0000 01373 7 0110 9 7 0111 9 7 Se/t ppm -.00293 .00513 209. 3 5 - .01000 .00090 .00032 B- ppm . 0267 7 .00030 1.1405 .02644 .421 04 .02683 Pb/2 ppm .03738 .00452 12 .10 3 .04254 . 03 546 . 03 4]-3 Ag ppm . 01 431, .00105 7 .3730 .01549 .01345 .01400 Li ppm .00587 .00007 1.1'1 82 .00594 .00585 .00s80 LC Pass Mg ppm 26 .1,27 .145 .55389 26 .27 9 25.995 26.090 Na ppm 37.598 .239 .63440 37 .424 3'7.860 37 .8 11 Sr ppm .45497 .00209 .45927 . 4537 3 .45-7 32 . 453 69 LC Pass NOCHECK NOCHECK LC Pass LC Pass 4 .0000 800.00 - .02000 -5.0000 LC Pass LC Pass Appendix F - 209 LC Pass 204 Analysis Report 03 / to / 06 o2 :54 :3-t PM page 2 High 70.000 100.00 10.000 40.000 40.000 5.0000 10.000 Low -.02000 -.02500 - .02000 -.50000 - .04000 - .05000 - .05000 EIem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge 32.355 .97743 4.7841 27 .1,54 .03751 .00152 SDev .106 .00288 .0119 .073 .00058 .00049 ?RSD .32873 .29468 .24873 .26829 1_. s541_ 32.46L #l- 32.477 .98073 4.7894 27 .1"s1- .03811 .00173 #2 32.3L1- .9761-8 4.770q- 27 .083 .O376s .00187 #3 32.278 .97540 4.7924 27 .228 .03695 .00095 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low - .05000 -.10000 -1.0000 -.30000 - .00400 -.01000 Intstd 1 Mode Counts Elem Y Wav1en 37 L. 0 3 0 Avge 207 83 SDev 224 .1,l2]- ?RSD 1.078353 #r 20s24 #z 20922 #3 20e02 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 210 245 Analysis Report Method: TRA20505 Sample Name: HXQ1XP Run Ti-me: 03/70/A6 r.4:54:47 Comment. : Mode: CONC Corr. Factor: 1 03/70/05 03:00 PM Operator: EIem A1 Units ppm Avge 4.3885 SDev .0187 ?RSD .42587 Sb ppm .001,24 . 0 0 04 B 39. 082 . 0 0 1"7'7 .00082 . 0 01,L2 Co ppm .00031 .00030 97 .47 4 .00019 .00009 .00065 K- ppm .L7578 .01874 10. 642 .19-739 .16498 .1,6499 LC Pass 200.00 -s.0000 V_ ppm .00198 .000s0 25 .410 .007.44 .00206 .00244 LC Pass As ppm - .00007 .0004s 59l- .62 .00017 - .000s9 .00022 Cu ppm .0071,0 .00028 3 .9299 .00689 .00699 .00741, Ni ppm .0102L .00084 8.1811 . 0110 9 .01013 .00942 LC Pass 100.00 - .04000 Zn ppm 1 . 1819 .0035 .30870 1814 1859 17 86 Ba ppm 8 .4020 .0304 .36230 B .3 894 8.4'357 B . 3 7 99 LC Pass 30.000 - .01000 Fe ppm .27 47 4 .00747 2 .717 9 .26624 .28023 .27774 Se/7 ppm .00273 . 0 0 446 163 .3s .00782 - .00049 .00085 NOCHECK B- ppm .02159 .0005s 2.5360 .0221,4 .02159 .02104 Be ppm - .00006 .00009 t44 .04 .00072 .00011 00004 LC Pass 10.000 - .00s00 Pb/7 ppm .02203 .00707 32 .101 .02999 .01965 .01646 Se/z ppm - .00117 .00295 252.23 - .00358 - . 0 01,92 .00208 NOCHECK Mo ppm .00044 .00018 40.253 .00026 .00044 .00062 LC Pass Cd ppm . 3 9 641, .00741 - 3 5 4'71, .39-707 .39136 .39479 Pb/2 ppm . 01 571, .00384 22.972 .01238 .01805 .01969 Ag ppm .00754 . 0 0 1,3'7 1B .183 .00911 .00692 .00658 LC Pass 4.0000 - .02000 Li ppm .00726 .00018 L4 .743 .00741 .00l-77 .0011s LC Pass page 1 Ca ppm "70.290 .395 .561,52 7 0 .717 -l 0 .274 59 .939 Mg ppm 5.0a47 . 021,4 .42598 5.0336 5.0189 4.9915 Na ppm 6.5450 .2s33 3.8"703 6.8340 6 .4391 6.361,4 LC Pass 800.00 -5.0000 Sr ppm .74298 .00064 .451,47 .14268 . L437 2 .74253 LC Pass #r #z #g 4.3856 4.4084 4.3714 Errors LC Pass High 700.00 Low -.20000 EIem Unrts Avge SDev ?RSD #r #z #: Cr ppm .00284 .00L23 43 .258 .00421 .0018s .00245 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge .00558 SDev .00017 ?RSD 3 . O5BB #r #z #: Errors High Low .00578 .00553 .00545 LC Pass 30.000 - .01500 EIem Tt Units ppm Avge L- .74940 SDev . 00 877 ?RSD 5.8291. LC Pass LC Pass 20 .000 30.000 - .05000 - .01000 LC Pass LC Pass 40.000 600.00 - .00500 -5.0000 LC Pass LC Pass 100.00 50.000 - .0s000 - .02500 LC Pass NOCHECK 7400.0 - .10000 NOCHECK LC Pass 700.00 -5.0000 #r #z #: Errors 1393s 7547 t 15413 Low 1 1 1 L- L_ L- Pass LC Pass Appendix F - 211 LC LC 206 Analysis Report High Low EIem Ti Units ppm Avge 11. 404 SDev .047 ?RSD .41,524 #r #z #: 11. 423 11. 439 11:3s1 Errors LC Pass High 40.000 Low - .05000 Intstd 1 Mode Counts EIem Y Wavlen 37 l. 0 3 0 Avge 2L37 9 SDev 1,7 4 .1,1,7 2 ?RSD . 81 44366 #r #z #: 2]-t92 2!40 I 21,537 10.000 - .02000 Si ppm .902].9 .01428 1.5829 .91843 .89654 .89150 40.000 - . s0000 P- ppm s.5890 .0121 .2a7 3 0 5.5785 5.5862 5.5023 40.000 -.04000 Pb ppm . 01 892 .00018 .94935 . 01 8'71, .01905 .01899 s.0000 - .05000 Se ppm .00045 .00155 340.68 .00048 - .00111 .00200 page 2 10.000 - .0s000 03/to/06 o3:oo:32 PM 7A .000 100.00 - .02000 - .02s00 Sn ppm . 1,7 911 .00298 1, . 6627 .182s4 .L7778 .1,71 62 LC Pass LC Pass LC Pass 40.000 40.000 40.000 -.10000 -1.0000 -.30000 NOTUSBD NOTUSED 4 NOTUSED LC Pass LC Pass 70.000 30.000 - .00400 - .01000 5 NOTUSED 6 7. NOTUSED NOTUSED Appendix F - 212 207 Analysis Report QC Standard Method: TRA20505 Sample Name: CCV3 Run Time: o3/10/06 15:03:51 Comment: Mode : CONC Corr. Factor: 1 03/to/06 o3:09:44 PM Operator: page 1 Cd Ca ppm ppm . 51222 51 . 1,37 .00046 .04s .09030 .08761 EIem AI Units ppm Avge 24.734 SDev . 03 9 ?RSD .15168 #r #z #: 24.700 24.777 24 .7 27 Errors QC Pass Va1ue 25 .0 0 0 Range 10.500 Elem Cr Units ppm Avge 2 .0357 SDev .0033 ?RSD .15209 #l- #z #: 2 .0349 2 . 0346 2.0405 Errors QC Pass Value 2.0000 Range 10.500 EIem Mn Units ppm Avge 2 .0467 SDev .0029 ?RSD .74401 #r #z #g 2 .0434 2.4475 2 . O49t Errors QC Pass Va1ue 2.0000 Range 10.500 Elem T1 Units ppm Avge 1.0774 SDev .0058 ?RSD .6673l_ #l- #z #: Errors 1.0142 1.0762 1 . 0241 QC Pass QC Pass QC Pass .50000 .50000 10. s00 10.500 QC Pass QC Pass 2.0000 2.0000 10.500 10. s00 QC Pass QC Pass . s0000 s0.000 10.500 10. s00 Sb ppm .50163 .00362 .7 217 I .49992 .50579 .49979 Co ppm 2.0398 .0082 .40188 2 . 0367 2 . O491, 2.0336 QC Pass 2.0000 10. s00 K- ppm 49.598 .707 . 21,510 49 .511 49.485 49 .697 QC Pass 50.000 10.500 V pp* 2 .0220 .0031 . 15]-7 4 2.0189 2 .0220 2 .0250 QC Pass As ppm .50528 .00240 .47 4lt . s0258 .507L6 .50610 Cu ppm 1. 9788 .0048 .24281- 1.974'7 1.9841 1.9776 QC Pass 2.0000 10 .500 Ni ppm 2.0550 .0055 .27 47 0 2 . 051,4 2.0515 2 .0522 Zn ppm 2 .0847 .0025 .1,2214 2 .0820 2 .0871, 2.0850 Ba ppm 2 .01_82 .0019 . 0 9229 2 .0t96 2.0189 2.0161 Fe ppm 25 .542 .039 .1s100 25 .498 2s .557 25 .577 Se/t ppm .50172 .00491 .97891 . s1110 .51004 . s0207 B- ppm 2 .0024 .0117 .s8602 1.989s 2 .0049 2 .01,26 Be ppm 2.0722 .0004 . 019'73 2 . 0122 2 - 071,8 2.0726 Pb/1, ppm . 513'7 4 .00532 1.0363 .51978 .50973 .511,12 Se/2 ppm .50700 .00251 .49498 .5076L .50424 - 509L4 Mo ppm 2 .0332 .0100 .49 034 2 .0298 2 .0445 2 .0255 QC Pass .51168 .51245 .51252 Pb/ 2 ppm . s1272 .00241, .47005 . s1050 .51237 .51528 Ag ppm 1.0036 .0014 .13881 1.0023 1.0035 1.0051 Li ppm 2 .0287 .0080 .39308 2.0359 2 .0207 2.0301 QC Pass 51.184 51.095 51 . 1,32 Mg ppm 50.243 .213 .4237 6 50. 032 50.239 50. 457 Na ppm 49 .421 .063 - 1,267 9 49 .492 49.393 49 .37 6 Sr ppm 2 .01,43 .0043 .21,3 0 g 2 .01,67 2 .0a69 2 .0094 QC Pass QC Pass NOCHECK 25.000 10.500 NOCHECK QC Pass 50.000 10. s00 QC Pass NOCHECK 2.0000 10 . s00 NOCHECK QC Pass QC Pass 1.0000 50.000 10.500 10.500 Pass QC Pass Appendix F - 213 QC 208 Analysis Report QC Standard 03/70/06 o3:09:44 PM Value Range 1.0000 10. s00 2.0000 10.500 Sn ppm 2,.0435 .0005 .02329 2 .0439 2 .0439 2 .0431 QC Pass 2.0000 10. s00 2 NOTUSED 2.0000 10.500 Si ppm 2.0100 .0099 .49456 1_ .9996 2 .0794 2.0110 2.0000 10.500 51_3 92 51187 57452 2.0000 10.500 50915 50555 50710 page 2 2.0000 10.500 Elem Ti Units ppm Avge 2.t518 SDev .0014 ?RSD .05485 #r #z #: 2.76 13 2 .163 4 2.7608 Errors QC Pass Value 2.0000 Range 10.500 IntStd 1 Mode Counts Elem Y WavI en 371,. 0 3 0 Avge 21-231- SDev 87 .40567 ?RSD .4l.15870 #r #z #: 2773 9 213l.4 21,240 2.0000 10.500 P_ ppm 2 .1,492 .0098 .45593 2 .1,428 2 .1,443 2.760s Pb Se ppm ppm .51344 .50760 .00139 .001,37 .27 457 .27 0 84 QC Pass QC Pass 2.0000 2.0000 10.500 10. s00 NOTUSBD NOTUSED QC Pass QC Pass .50000 .50000 10. s00 10. s00 5 NOTUSED NOTUSED NOTUSED o Appendix 214 F- 209 Analysis Report Method: TRA20505 Samp1e Name: CCB3 Run Time: 03/t0/06 15:09:47 Comment : Mode: CONC Corr. Factor: 1 03/70/06 o3:15:39 pM Operatotr: page 1 Cd Ca ppm ppm -.00031 .00047 .00037 .00017 720.04 153.29 EIem AI Units ppm Avge -.00054 SDev .00182 ?RSD 339.22 #r #z #: - . 0 0042 - .00247 .00122 Errors LC Pass High .10s00 Low - .10500 Elem Cr Unit s ppm Avge -.00038 SDev .00057 %RSD 148. 85 #r #z #: - .00104 - .00013 . 00 002 Errors LC Pass High .00350 Low - .00360 Elem Mn Units ppm Avge -.00007 SDev .00023 ?RSD 308.95 #r #z #s - .00034 .00006 .00005 Errors LC Pass High .00180 Low -.00180 EIem TI Units ppm Avge .00048 SDev .00120 ?RSD 252 .1'7 #r #z #: Errors .00019 .00180 - .00056 LC Pass LC Pass LC Pass .01400 .00330 - .01400 - .00330 LC Pass LC Pass .00150 .00180 - .00160 - .00180 LC Pass LC Pass .00082 .05500 - .00082 - .05500 LC Pass LC Pass .00220 .00700 -.00220 -.00700 Sb ppm .00051 .00203 397 .37 .00131 .00202 - .00180 Co ppm - .00017 .00010 57.807 00028 00015 00009 K- ppm .12928 . 01 016 7.8586 . 117 62 .13401 . 13 621 V_ ppm .00007 .00060 87 0 .54 - .000s3 .00068 .00007 LC Pass As ppm - .00030 .00081 268.32 - .00117 - .00017 .00044 Cu ppm .0006s .00035 56.221, .00039 .00105 .00048 Ni ppm -.0a744 .00185 l2B -22 - .00351 - .00089 .00007 Zn ppm .00010 .00005 55.290 .00004 .00014 .00072 Ba ppm .00007 .00006 74.398 .00001 .00010 .00011 Fe ppm .002l_8 .00864 395.71 - .00616 .00160 .01109 se/t ppm - .00318 .00625 196.24 -.01015 - .00131 .00191 Be ppm .00028 .00026 92 .409 .00057 . 00 020 .00007 Pb /7 ppm - .00822 .00900 109.55 018s2 00420 001,92 Se/z ppm .00309 .00391 t26 .69 .00752 .00166 .00009 Mo ppm .00227 .00046 20 .208 .002-72 .00180 .00228 LC Pass -.00072 - .00001 - .00018 Pb/2 ppm .00397 .00449 113 . A7 .00913 .00702 .00175 Ag ppm .00438 .00079 1B . O2'7 Li ppm .00051 .00007 11.078 .00062 .00058 .00054 LC Pass - .00008 .00136 .00014 Mg ppm .00L44 .00794 734. B6 - .00058 .00313 .00186 Na ppm -.7 0807 .82190 116.08 Sr ppm .00000 .00002 519 . 51 - .00001 .00003 - .00001 LC Pass LC Pass NOCHECK NOCHECK LC Pass .04900 .04900 - .04900 - .04900 .00347 L-1.5543 .00484 -.29861 .00484 -.1713s LC Pass LC Pass .32200 .00380 - .32200 - .00380 NOCHECK NOCHECK LC Pass LC Pass .00970 7.4730 -.00970 -1.4730 B- ppm .00196 .00a20 51.054 .000'72 .00206 .00310 Pass LC Pass Appendix F - 21s LC 2L0 Analysis Report 03/to/06 o3:15:39 PM page 2 High .01000 .00s00 .00380 .03100 .00880 .0027o .00130 Low - .01-000 -.00500 -.00380 - .03100 - .00880 - .00270 - .00130 Elem Ti Sn Si p_ pb Se Units ppm ppm ppm ppm ppm ppm Avge .00015 -.00121 .00466 .01276 .00037 .00135 SDev .00024 - 00175 .00821 .00069 .00062 .00055 ?RSD L57.54 1-4s.16 L76.2L 5.4135 155.9s 4].--48L #r .00041 - .00319 .01384 .01,277 . OOO39 .00200 #2 .0001_1 - .00056 .00206 -01-259 - .00026 .00104 #3 - .00005 .00013 -.00194 .013s2 .00099 .001_02 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High .00160 .00770 .0s500 .02100 .00370 .00430 Low - .00160 -.00770 -.05500 -.02100 - .00370 -.00430 Int.Std 1 Mode Counts Elem Y Wavlen 37 7. 0 3 0 Avge 27636 SDev 29.70838 ?RSD . 13 73 0 93 # r 2761,2 #z 27627 #3 2l-659 234557 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 216 27L Analysis Report Method: TRA20505 Sample Name: H0HPE Run Time : 0 3 /Lo / 06 15 : 1,5 :42 Comment : Mode : CONC Corr. Factor: 1 03 / tA / 06 03 : 2L:34 PM Operator: page 1 Cd Ca ppm ppm - .00183 .11094 .00026 .00075 14.035 .57 870 EIem At Uni t. s ppm Avge .35422 SDev .00336 ?RSD . 957 9t #r #z #g 34736 3527 7 353s4 Errors LC Pass High 700.00 Low - .20000 EIem Cr Units ppm Avge . 00 427 SDev .00053 ?RSD L2 .523 #1 #z #g 00485 00381 00414 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge 1.2716 SDev .0762 ?RSD 7 .27 40 #r #z #3 L.289B L .2662 L.25BB Errors LC Pass High 30.000 Low - .01500 Elem T1 Units ppm Avge -.00301 SDev .00207 %RSD 68.610 #r #z #: Errors - .00525 -.0025l. - .00118 LC Pass Sb ppm - .00065 .0006s 99 .547 - .00053 - .00008 - .00137 As ppm .00335 .00070 20 .911 .00322 .00273 .004]-1 LC Pass LC Pass 20.000 30.000 - .06000 - .01000 Co Cu ppm ppm .02366 H382.71- .00026 9.15 1.0926 2.3908 .02339 H392.92 .02390 H375.24 .02367 H379.97 LC Pass 100.00 - .05000 K- ppm .10984 .01396 L2.7a3 V_ ppm .00232 .00070 30.030 .00L55 .00227 .0030s LC Pass Ni ppm H15 2 .49 2 .40 1.5763 Zn ppm 3 .277 B .0311 .94857 3 022 28B4 2428 Ba ppm .24788 .0018s .7 467 7 .24938 .24845 .245 B 1 LC Pass 30.000 - .01000 Fe ppm . 31 41_9 .00294 . 93 668 .31322 .31750 .31185 Se /t ppm .00462 .002s6 55.401 .00756 .00288 .00343 B_ ppm .00554 .00742 18. 467 .00568 .00525 .00469 Be ppm - .00034 .00028 83 .251 00064 00029 00008 Pb /t ppm - .00064 .01301 2045 . 5 . 01 422 - .00613 - .01000 Se/2 ppm . 0 0l-1,1 .00276 236. 05 - . 0 0201, .00260 . 00 292 Mo ppm - .00022 .00012 53 - 32-7 - .00035 - .00016 - .0001s Li ppm .00131 .00028 27 .667 .00100 .00138 .00155 LC Pass Na ppm .11222 . 2413 0 2J.5. 0 1 .39024 - .01087 - .04270 Sr ppm .00442 .00003 .1 327 5 .00443 .00444 .00438 LC Pass LC High LC Pass 50.000 1400.0 - .02500 - .10000 NOCHECK NOCHECK LC Pass 700.00 -5.0000 00154 0 0202 00193 1118 1 11054 1,7_O 41 Pb/2 Mg ppm ppm - .00300 .00440 .00645 .00135 21,4.87 30.71,8 -.01036 .00337 - .00026 .00391 .001,62 .00593 Ag ppm .04711 . 0 0181 3. 83B7 .04926 . 04 6 0 0 . 04 625 LC Pass LC Pass LC Pass 10.000 40.000 500.00 -.00500 -.00500 -5.0000 1,245-l H155.07 09680 H152.10 10814 H150.31 LC Pass LC High NOCHECK 200.00 100.00 -s.0000 -.04000 NOCHECK LC Pass LC Pass 4.0000 800.00 - .02000 -5.0000 3 3 3 Pass LC Pass Appendix F - 2rl LC LC Pass 2L2 Analysis Report 03/lo/oG o3:21:34 PM page 2 s.0000 10.000 - .05000 - .05000 High Low EIem Unit s Avge SDev ?RSD #r #z #: Errors High Low IntStd Mode Elem WavIen Avge SDev ?RSD #r #z #3 70.000 - .02000 Ti ppm .02228 .00015 .7 3283 .02238 .02236 .02209 1 Count. s Y 37L.030 21,567 31,7 .1,092 7 .47 0347 2l-20s 2769 9 2\7 97 100.00 - .02500 Sn ppm H44 .459 .544 1 .2233 H45.073 H44 .265 H44.039 10.000 - .02000 Si ppm .18635 .00725 3 .8890 .1-9368 .18518 .1,7919 40.000 - .50000 P- ppm 11.474 . tt1 1.0l-77 11.579 11 . 49s 11.348 00151 00175 OOlBB 40.000 - .04000 Pb Se ppm ppm - .00175 .00268 .00013 .00100 1.6131 37.257 LC Pass LC High LC Pass 40.000 40.000 40.000 -.0s000 -.10000 -1.0000 LC Pass LC Pass LC Pass 40.000 70.000 30.000 -.30000 -.00400 -.01000 001s5 00301 00345 NOTUSED NOTUSEDNOTUSED NOTUSED NOTUSED NOTUSED Appendix F 218 273 Analysis Report Method: TRA20505 Sample Name: H0HPM Run Time : 03 / 70 / 06 15 : 25:77 Comment : Mode: CONC Corr. Factor: 1 03/ao/06 o3:31:09 PM Operator: page 1 EIem AI UniEs ppm Avge L24 .21- SDev .37 ?RSD .297 84 #r #z #: 1,24.00 t24. 0 0 L24 .64 Errors LC Pass High 7 00.00 Low - .20000 EIem Cr Unit s ppm Avge .10783 SDev .00053 ?RSD .4902a #r #z #3 1O7BB 707 2B 10834 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge 2 .8 13 6 SDev .0089 ?RSD .31583 #r #z #3 2 .8237 2 .8069 2 .81,02 Errors LC Pass High 30.000 Low - .01500 Elem TI Units ppm Avge L- .03104 SDev .00527 ZRSD 76.983 #r #z #g Errors L- . 02496 L- . 03428 L- .03389 LC Pass LC Pass 20.000 30.000 - .05000 -.01000 Sb ppm - .00008 .00104 1335.4 - . 0 01,25 .00029 .00073 Co ppm .44900 .00025 .5171,4 .44926 . o4B7 5 .04899 K- ppm 26.1,49 .055 .20978 26 .16 5 25.794 26.088 LC Pass 204.00 -5.0000 V_ ppm .29'7 0t .00064 .27597 .29772 .29646 .29686 LC Pass As ppm .04 639 .00029 .5301 5 . 04 543 .04656 .04608 Cu ppm .1B1BB .00482 2 .6507 .18726 . 1B 041 .L7797 Ni ppm .0'7 648 .00094 1 .226A .o'7591 .07598 .07757 Zn ppm .44121 .00043 .09611 .44L69 .44089 .441 04 Ba ppm 1.1386 .0004 .0378L 1.1382 1.1385 1.1390 LC Pass 30.000 - .01000 Fe ppm 134.24 .33 .2457 5 L34.59 133 .93 134 .19 Se/t ppm .00088 .00259 29s .32 .00]-70 -.00203 .00296 B- ppm .08911 .00130 1.4553 .08897 .08789 .09047 Be ppm .00621 .00020 3 .2624 .00638 .00626 .00598 Pb/1 ppm .07 665 .00277 3 .5097 . 07'7 27 .07355 .07 910 Se/2 ppm .00656 . 0 0l.4-l 22 .412 .00629 .00816 .00s25 Mo ppm .00558 .00022 3.9069 .00552 .00582 .00539 LC Pass Cd ppm .00017 .00023 135.36 Ca ppm 111.01 .28 .25226 LC Pass LC Pass 100.00 s0.000 - .05000 - .02500 LC Pass NOCHECK 1400.0 - .10000 - .00010 111 .32 .00032 110.78 .00029 110.94 Pb /2 ppm .09721 .00320 3 .5135 .09729 .09438 .08797 Mg ppm 28.734 .050 .77 27 5 28.790 2B .695 28 .7 77 NOCHECK LC Pass 700.00 -s.0000 Ag Na ppm ppm - .00157 6.9981 .00037 .1981 23 .'732 2.8306 - .00120 5. B6s3 -.001s5 6.9033 - .00195 -7 .2258 LC Pass LC Pass 4.0000 800.00 - .02000 -5.0000 Li Sr ppm ppm .09935 .79932 .00010 .001,20 .09875 .15021 .0g931 . 09 946 .09921 LC Pass .79873 --79854 .80071, LC Pass LC Pass LC Pass LC Pass 10.000 40.000 500.00 -.00s00 -.00500 -s.0000 LC Pass NOCHECK NOCHECK 100.00 -.04000 LC Pass LC Pass Appendix F - 219 LC Low 2L4 Analysis Report 03/to/05 o3:31:09 PM page 2 5.0000 10.000 - .05000 -.05000 Se ppm .00499 .00018 3 .5287 .00s05 .00511 .00478 7 NOTUSED High Low 70.000 -.02000 100.00 - .02s00 Sn ppm .02203 .00101 4.5913 .02309 .02193 .02108 LC Pass 40.000 - .10000 2 NOTUSED 10.000 -.02000 Si ppm 13 . 686 .21,2 1.5472 13 . 93 0 13 . 51 9 13 .548 40.000 - .50000 P- ppm 3.9897 .0260 .65208 3.9510 3.9962 4 . 0118 40.000 - .04000 Pb ppm .08678 .00133 1. s298 .0871,2 .0819]- .08532 Elem Ti Units ppm Avge 2 .8856 SDev .0033 ?RSD . 11 464 #r #z #3 2.8884 2 . BB2B 2.BBB6 Errors LC Pass High 40.000 Low - .05000 Intstd 1 Mode Counts Elem Y WavIen 371,.030 Avge 23285 SDev 7 0 .89428 %RSD .3044679 #r #z #: 232L5 23282 23357 LC Pass LC Pass 40.000 40.000 -1.0000 -.30000 34 NOTUSED NOTUSED LC Pass LC Pass 7A .000 30.000 - .00400 - .01000 56 NOTUSED NOTUSED Appendix F - 220 215 Analysis Report Method: TRA20505 Sample Name: H0HNV Run Time: 03/a0/06 15:31,:12 Cornment. : Mode: CONC Corr. Factor: 1 03/to/06 o3:37:04 pM Operat or : page 1 Cd Ca ppm ppm - .00010 .20033 .00007 .00428 56.777 2.1391 EIem AI Units ppm Avge . 015'7 7 SDev .00828 ?RSD 52 . s3 9 #r #z #3 o2528 01184 01018 Errors LC Pass High 700.00 Low - .20000 EIem Cr Units ppm Avge -.00062 SDev .00042 ?RSD 67 .8 5 9 #r #z #: 00091 00014 00080 Errors LC Pass High 100.00 Low - .01000 EI em Mn Units ppm Avge .00381 SDev .00013 ?RSD 3 .47 gg #r #z #: 00395 0037 2 oo37 4 Errors LC Pass High 30.000 Low - .01500 Elem TI Units ppm Avge .00139 SDev .00167 ?RSD A20. 1 5 #r #z #: Errors - .000s3 .0025a .00220 LC Pass LC Pass LC Pass 20.000 30.000 - .05000 - .01000 Sb ppm .00131 .00148 7L2 .92 .00280 - .00015 .00128 Co ppm .00037 .00045 119.85 .00088 .00018 .00005 K_ ppm .11450 .011,75 10 . 262 .127 7 7 .11034 .10540 V_ ppm .00055 .00130 236. 1B .001,94 .0003s - .00054 LC Pass As ppm .00073 . 0 01,22 766.1,7 .00184 - .00057 .00093 Cu ppm .03183 .00524 19. 499 .03811 .03769 .02570 Ni ppm .00011, .00057 93 . BB0 .00148 .00043 .00024 Zn pprn .0019s .00072 6 .7027 .00200 .00203 .00181 Ba ppm .00107 .00017 16.075 .00l.26 .00103 .00092 LC Pass 30.000 - .01000 Fe ppm .79927 .0253 9 3 .1771, .82857 .7 83 67 .7Bs5B Se/t ppm .00303 .00208 68.653 .00225 .00a45 .00539 B- ppm .00581 .00072 72 .402 .0055s .005"76 .00511 Be ppm - .00030 .00020 56.054 - .00053 - .00017 - .00020 Pb/ t ppm - .00137 .00270 1_54. 0 1 -.00059 -.00375 .00024 Se/z ppm - .00116 .00053 45 .645 00081 00090 00777 Mo ppm .00098 .00054 54 .948 .00150 .00099 .00043 LC Pass 0000s 00007 00018 Pb/ 2 ppm . 0 0 041 .00070 472 .63 Ag ppm .00175 .00083 47 .247 .00269 .00139 .00115 Li ppm .00083 .00007 B .121,2 .00090 .00084 .00075 LC Pass . 20 515 .19889 . 19 695 LC Pass 500.00 -s.0000 Mg ppm . o2B 04 . 00 456 1,6 .259 Na ppm -.0376s .2L457 s59. 93 . 1B 528 - .241,43 -.05779 Sr ppm .00022 .00005 20 .17 0 .00026 .00021, .0001,7 LC Pass LC Pass LC Pass 10.000 40 .000 - .00500 - .00500 LC Pass LC Pass 100.00 50.000 - .05000 - .02s00 LC Pass NOCHECK 1400.0 - .10000 00079 .033a2 00083 -02670 .00040 .a2430 NOCHECK LC Pass 700.00 -5.0000 LC Pass LC Pass 200.00 100.00 -s.0000 - .04000 NOCHECK NOCHECK LC Pass LC Pass 4.0000 800.00 - .02000 -5.0000 LC Pass LC Pass Appendix F - 221 2L6 Analysis Report 03/ro/06 o3:37:04 PM page 2 High 70.000 100.00 10.000 40.000 40.000 s.0000 L0.000 Low -.02000 -.02500 -.02000 -. s0000 -.04000 -.05000 -.05000 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge .00085 .0L347 .30588 .02554 .00035 .00059 SDev .00009 .001-12 .01092 .00080 .00052 .00037 ?RSD 10.43s 8.3401_ 3.5588 3.1319 1,42.09 62.804 #1 . OOO94 .0t473 -3L926 .02535 .00089 .00054 #2 .00088 .012ss .30281 .02s50 -.00015 .00025 #3 .00076 .01314 .29859 -02476 .00035 .00098 Errors LC PasS LC Pass LC Pass LC Pass LC Pass LC .PasS High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.05000 -.10000 -1.0000 -.30000 -.00400 -.01000 Int Std 1 Mode Count s EIem Y Wavlen 37 l. 0 3 0 Avge 21885 SDev 326.0854 ?RSD I .48997L #r 27stt #z 22039 #3 22106 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 222 2L7 Analysis Report Method: TRA20505 Sample Name: H0HN9 Run Time: 03/10/0G 15:37:07 Comment : Mode: CONC Corr. Factor: 1 03 /L0 /06 o3 : 42:59 pM Operat.oL: Elem Al Units ppm Avge 11 . 1,65 SDev .073 ?RSD .5s739 #r #z #: 11 . 246 11 . l.02 11.150 Errors LC Pass High 700.00 Low -.20000 EIem Cr Units ppm Avge .11153 SDev .00131 ?RSD 1.17a9 #r #z #: 11304 11082 11073 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge .32621 SDev .00329 ?RSD 1.0069 #r #z #: 32980 32335 32548 Errors LC Pass High 30.000 Low - .01500 EIem T1 Units ppm Avge L- .03359 SDev .00438 ?RSD 72 .992 #r #z #: Errors 028'7 7 03518 03713 Low LC Pass LC Pass 20.000 30.000 - .06000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00500 page 1 Cd Ca ppm ppm -.00029 1s.s56 .00013 .101 43 .390 .65153 -.00029 15.670 - .00017 15. 477 - .00043 15. 520 LC Pass LC Pass 40.000 600.00 - .00s00 -5.0000 LC Pass LC Pass 100.00 50.000 - .0s000 - .02s00 Sb ppm .45927 .00297 . 620 62 .47 260 .45807 . 4671,6 Co ppm .00858 .00026 3 .0329 .00872 .00840 .00892 K- ppm .91s00 .00901 . 9B 448 .92455 . 90 668 . 9137 5 V- ppm .04693 .00059 L .4662 .04772 .04552 .04644 LC Pass As ppm .00s39 . 0 01,49 27 .7 42 .00558 .00371, .00586 Cu ppm .s5690 .00626 1.1234 .56315 . 55 69]- . s5 064 Ni ppm .09'774 .00079 .81180 .09864 .09714 .09744 Zn ppm 4.0253 .0228 . 5 6592 0509 007 4 017 6 Ba ppm 9 .2052 .0581 .63A74 9 .262a 9.1459 9 .207 s Fe ppm 45.342 .384 . 847 75 45 .7 65 45 .074 45.248 Se/t ppm .00-/27 .00193 26 .469 .00551 .00933 .00698 B_ ppm .15150 .00151 .99622 .15300 .1s000 .15782 Be ppm .00033 .00001 3 .3511 .00032 .00033 .00034 Pb /t ppm . 03 467 .00062 1.7 871 .03399 .03519 .03483 Se/2 ppm .00315 .002l=2 s6 .507 .0041 5 . 0 01,32 .00519 Mo ppm .00509 .00006 1.0997 .00510 .00s03 .00514 LC Pass Pb/2 ppm . 03 7 60 .00065 l.v 410 .03704 .03744 . 03 832 Ag ppm .00191 .00035 18.981 .00231 .00183 .00160 Li ppm . 03 322 .00027 .64498 .03340 .03298 .03327 LC Pass Mg pprn 40. 477 .293 .7 2321, 40 .7 98 40.225 40 - 40'7 Na ppm 6.03'7]_ .0801 1.3267 6.].0s8 s.949t 6.0s65 LC Pass 800.00 -s.0000 Sr ppm . 19 61,6 .00l.27 .64843 .19760 .19527 .19566 LC Pass LC Pass NOCHECK NOCHECK LC pass 1400.0 700.00 - .10000 -5.0000 LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHECK NOCHECK LC Pass 4 .0000 - .02000 4 4 4 L- L_ L- Pass LC Pass Appendix F - 223 LC LC 2L8 Analysis Report 03/ta/06 o3:42:59 PM page 2 5.0000 10.000 - .05000 - .05000 Se ppm .00526 .00091 t7 .232 .00537 .00430 .00511 High Low 70.000 - .02000 100.00 - .02500 Sn ppm .03086 .00096 3.1233 .0310s .031,77 .02981 LC Pass 40.000 - .10000 2 NOTUSED 10.000 - .02000 Si ppm 3.1488 . O2BB .91306 3.1808 3 .12s0 3.1408 40.000 - .50000 P_ ppm .61023 .001,77 .289l.6 .61,000 .508s9 .61209 Elem Ti Unit s ppm Avge 2 .4526 SDev .0166 ?RSD .677 97 #r #z #s 2 .47 07 2.4381 2 .4489 Errors LC Pass High 40.000 Low - .05000 Intstd 1 Mode Counts EIem Y Wavlen 371,.030 Avge 21,81 4 SDev A14. 953 6 ?RSD .5255379 #r #z #: 217 44 2]-9 65 2791,L LC Pass LC Pass 40.000 40.000 -1.0000 - .30000 34 NOTUSED NOTUSED 40.000 - .04000 Pb ppm .03'747 .00059 1.5988 .03544 .03'/45 .0376]- LC Pass LC Pass 70.000 30.000 - .00400 - .01000 5 NOTUSED 67 NOTUSED NOTUSED Appendix F 224 2].9 Analysis Report Method: TRA2 0505 Sample Name : HOHPC Run Time: 03/10/06 15:43:02 Comment : Mode: CONC Corr. Factor: 1 03/to/05 o3:48:54 PM Operator: Sb ppm .00001 .00l.20 9289 . 3 - .00057 .00139 - .00078 Co ppm .21,964 .00059 .26672 .21,995 . 21-89 6 .22000 K- ppm 2.3394 .0204 . 8101 0 2 .315 B 2.3451 2.3552 LC Pass 200.00 -5.0000 V- ppm - .00194 .00184 94 -'727 As ppm .01094 .00l-57 15 .296 . 0 1013 .00983 . 01287 Cu ppm . 1,227 2 .00107 . 87 209 . a2340 . L232B - 42149 Ni ppm 1.0648 .0035 .33229 1.0624 1.0531 1.0689 LC Pass 100.00 - .04000 Zn ppm H2B .444 .180 .63232 Ba ppm .00378 .00018 4.8704 .00357 .00391 .00386 Fe ppm . 87 925 .01054 1.1990 .89022 .85919 .87834 Se/r ppm .36s68 .00259 .7OBBB .35269 .36737 .36703 B- ppm .01895 .000'79 4.1,880 . 0 1811 .0190s .01958 Be ppm - .00055 .00010 t4 .849 -.000s5 -.00075 -.00067 Pb/L ppm .09522 .00332 3.4868 .09206 .09491, .09858 Se/z ppm .30115 .00185 . 512'7 7 . 3 0 042 .2997 B .3032s Mo ppm - .00384 .00032 B . 3 982 - .04314 - .00420 - .00358 LC Pass Cd ppm .02136 .00004 . 1B 424 .02139 .02437 .02732 Pb/2 ppm .09274 .00300 3.2359 .09591 .09003 . 0 9221 Ag ppm .04446 .00064 7.44"76 .44457 .0437 6 .44503 LC Pass 4.0000 - .02000 Li ppm .00300 .00043 1,4 - 384 .00256 .00302 .00342 LC Pass page 1 Ca ppm .54440 .003s0 . 5429 6 .642L6 .5426\ .64843 Mg ppm - .7 5110 .00817 1.087A - .7 4251 - .7 5BB4 - .7 5191 Na ppm B4 .3 51 .399 .47301 83.893 84.541 B4 .621, LC Pass 800.00 -5.0000 Sr ppm .00s63 .00001 .1961 9 .00553 .00562 .00554 LC Pass Elem A1 Units ppm Avge .29452 SDev .0061,7 ?RSD 2 .0 955 #r #z #3 .287 42 .297 53 .29861 Errors LC Pass High 700.00 Low - .20000 Elem Cr Units ppm Avge .2557 4 SDev .00243 ?RSD .91404 #r #z #: .25506 .26371_ .26843 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge H82.129 SDev .671 %RSD .81846 #r #z #: H83.330 HB1.99s HB2. B 61 LC Pass LC Pass 20.000 30.000 - .05000 - .01000 LC Pass LC Pass 30.000 10.000 -.01000 - .00500 LC Pass LC Pass 40 .000 500.00 - .00500 -5.0000 LC Pass LC Pass 100.00 50.000 - .05000 - .02500 LC Pass NOCHECK 1400.0 - .10000 NOCHECK LC Pass 700.00 -5.0000 Errors LC High High 30.000 Low - .01500 EIem TI Uni t s pprn Avge 1.2105 SDev .0035 ?RSD 28737 NOCHECK NOCHECK #r #z #: Errors 7.2090 1,.2083 7 .2\46 LC Pass .00016 H28.621, -.00274 H2B.26t -.00325 H28.450 LC High LC Pass Appendix F - 225 LC Pass 220 Analysis Report 03/70/06 o3:48:54 PM page 2 High 70.000 100.00 10.000 40.000 40.000 5.0000 10.000 Low - .02000 - .02500 -.02000 -.50000 - .04000 -.05000 -.0s000 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge .00244 .01339 .39379 .'1,49L2 .0941-0 .32299 SDev . 00064 . 00068 . 00160 .00225 .00171 .00169 ?RSD 26.246 5.0662 .40551 1.5053 1. B15s .52362 #1 .00179 .01-286 .39538 .1-5167 .O9s23 .32749 #2 . 00246 . ,01-4L6 .3937 9 .1-47 42 . 09273 .32265 #3 .00307 .01316 .3921"9 .L4827 .09493 .32482 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.05000 - .10000 -1.0000 -.30000 -.00400 - .01000 Intstd 1 Mode Counts Elem Y Wavlen 371.030 Avge 2L062 SDev 38.00543 ?RSD .1804s27 #r 2]-7a2 #z 2tos6 #: 21027 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 226 22a Analysis Report Method: TRA20505 Samp1e Name: HOHPF Run Time: 03/:-0/oe 15:48:5-t Comment: Mode: CONC Corr. Factor: 1 03/70/06 03:54 PM Operator: 00071 00314 00195 Co ppm .00018 .00030 767 .44 .00035 .0003s - .00017 K- ppm .21,87 6 .00574 3 .0811 .2157 4 . 225 49 .21405 V- ppm .00096 .00089 92 .10 9 .00L0'7 .00178 .00002 LC Pass 0 0293 00408 00154 Cu ppm .0566l- .00673 10 . 1,02 .07290 .06740 .059s2 Ni ppm .00282 .00092 32.580 .00357 .00311 .00779 Zn ppm .03836 .00626 16.304 .04534 . 03 549 .03326 Ba ppm .00438 .00048 10.985 .00490 .00429 .00396 LC Pass 30.000 - .01000 Fe ppm .24061 .00858 3.5055 .24075 .24922 .23787 LC Pass 1400.0 - .10000 Se/t ppm .00816 .00a2s 1s . 265 .00759 .00730 .009s9 NOCHECK B_ ppm .05953 .00084 1, - 4022 .06039 .05949 .05872 Be ppm .00003 .00010 331.30 - .00005 '.00002 .00013 LC Pass 10.000 - .00s00 Pb/ t ppm .00026 .00070 263 . 1B - .00046 .00033 .00093 Se/2 ppm .00385 .00019 4 . 841,4 .00365 .00401 .00392 Mc> ppm .0001-7 .00038 21,9.50 .0004L .00037 -.0a026 LC Pass Cd ppm .000]-7 .00011 63 .16 5 .00025 .00020 .0000s Pb/2 ppm .00a77 .00004 2 .1,582 .00773 .00]-'71 .00180 Ag ppm .00464 .00041 B.8011 .00440 .00511 .0044L Li ppm .00212 .00040 1B . 715 .00254 .00208 .001,75 LC Pass page 1 Ca ppm .94249 .00143 .15183 .94269 .94382 .94097 Mg ppm .13377 .00305 2 .2'7 83 . 13 502 .13599 . 13 029 Na ppm 6.02Ls . o42A .6997 4 5.0195 5 . 0 645 s.9803 Sr ppm .00L29 .00002 t .7 292 .00131 .00130 . 0 01,2'7 LC Pass EIem Al Units ppm Avge . 04 648 SDev .00932 ?RSD 20 .042 #r #z #: 04.158 057 27 04054 Errors LC Pass High 700.00 Low - .20000 EIem Cr Units ppm Avge .00038 SDev .00020 ?RSD 54.580 #r #z #3 .00050 .00034 .00019 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .21534 SDev .05392 ?RSD 19.584 #r #z #: .33483 .261,52 .22958 Errors LC Pass High 30.000 Low - .01500 Elem TI Units ppm Avge -.00401 SDev .00746 ?RSD 36 .53 9 #r #z #: Errors -.00232 -.00492 - - 0 04'/ g LC Pass Sb As ppm ppm -.00193 .00285 .001,22 .00l_28 62. B9B 44.747 LC Pass LC Pass 20.000 30.000 -.05000 - .01000 LC Pass LC Pass 40 .000 600.00 - .00500 -5.0000 LC Pass LC Pass 100.00 50.000 - .05000 - .02500 NOCHECK NOCHECK LC Pass 700.00 -5.0000 LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHECK LC Pass LC Pass 4.0000 800.00 - .02000 -s.0000 LC Pass LC Pass Appendix F - 227 222 Analysis Report 03/70/06 o3:54:49 PM page 2 High 70.000 100.00 10.000 40.000 40.000 5.0000 10.000 Low -.02000 -.02500 - .02000 - . s0000 - .04000 -.05000 - - 05000 EIem Ti Sn Si P- Pb Se Units ppm ppm ppm ppm ppm ppm Avge .00773 .01-933 .02108 .09135 .00183 .00557 SDev .00079 .00164 .00489 .00095 .00025 .00045 *RSD 10.269 8.4920 23 .aB3 1.0530 13.919 7.9053 #1 .007s8 .02079 .025'78 .09169 .00156 .00534 #2 .008s9 .01964 .02743 .09210 .00185 .00548 #3 .OO702 .017s5 .01603 .09027 .0020'7 .00618 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.O5OOO -.10000 -1.OO0O -.3OOOO -.OO40O -.O1OOO Intstd 1 Mode Counts Elem Y Wavlen 371-.030 Avge 21451- SDev 151 .1,7 4a %RSD .7 047 556 #r 213s2 #z 21,37 5 #: 21,625 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 228 223 Analysis Report Method: TRA20505 Samp1e Name: HOHPK Run Time: 03/10/06 15:54:53 Comment : Mode: CONC Corr. Factor: 1 03/Lo/06 o4:oo:45 PM Operator: Ni ppm 3 B . 999 .401 1.0276 39.454 38.843 38. 699 LC Pass 100.00 - .04000 Zn ppm H26.504 . 471, 7.7782 Ba ppm 1,2.333 .053 .50745 L2.405 72.296 12.297 Se/t ppm .14554 .00339 2 .327 6 . 1,493 6 . t443 6 . 1,429 0 B_ ppm 1. 843B .01,29 .10053 1. B57B 1 . 8324 1.8473 Be ppm .0022a .00018 8.0758 .0024l .0021,5 .00207 Pb/1, ppm 4 -321 4 .0185 .42775 4.3477 4 .3115 4 - 3231, Se/z ppm .15775 .00292 1.9215 .74892 .15475 .15158 Mo ppm 11.330 .135 1 . 1924 11 .480 11.289 11.2L9 LC Pass Cd ppm .0264\ .00011 . 427 83 .02652 .02642 .02630 Pb /2 ppm 4 .21 86 . 03 94 .91918 4.2348 4.2896 4 .31,1,2 Ag ppm 1.391,9 .0102 .7 3 492 1.4037 1.3862 1.3851 Li ppm 3 .4923 .0247 .68944 3.5200 3 .47 62 3.4808 LC Pass page 1 Ca ppm 180 .3'l 1.30 .7 228 5 181.85 l.79.85 l'7 9 .4L Mg ppm 8s.009 .804 .94570 85.935 B4 . 489 B4 .604 Pas s .00 0000 Na ppm 67 .4 1B .430 . 63-7 49 67 .9a2 67 .277 67 .727 Sr ppm 1.7263 .0109 .63250 1.7 380 L .7 245 1.7L64 LC Pass EI em A1 Units ppm Avge 135.47 SDev 1. 01 %RSD .7 4334 #r #z #: 136. s9 135.18 734 .64 Errors LC Pass High 700.00 Low - .20000 EIem Cr Units ppm Avge 7 .42L9 SDev .0131 ?RSD .923 B 1 #r #z #: I .43'7 0 1-.4140 L .4745 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge 4 .6 03 B SDev .0625 ?RSD 1.3580 #r #z #: 4 .61 50 4 .567 s 4 .567 9 Errors LC Pass High 30.000 Low - .01500 El em T1 Units ppm Avge L- .26293 SDev .021,62 %RSD B .221,5 #r #z #: Errors 2 40 0-7 283 04 2656 6 Low Sb ppm .50340 .00375 .'7 449 6 .50759 .50223 .50031 LC Pass 20.000 - .05000 As ppm .327 22 .00232 .70804 .32832 .32878 .324s5 Co Cu ppm ppm .82242 Hl55.89 .011-92 a.L2 7.4493 .7]-589 .83501 H158.18 .81751" H156 .31 .81374 HI56.1-7 LC Pass 100.00 - .0s000 K- ppm 34.905 -473 .49530 35.104 34 . BL1 34.794 LC Pass 20a.00 -s.0000 V_ ppm 1.0276 .0081 .7 B92B LC Pass LC Pass LC Pass 30.000 30.000 10.000 -.01000 -.01000 -.00500 LC Pass LC Pass 40.000 500.00 - .00500 -s.0000 Fe ppm 508.57 4 .71 .93679 514 . L7 505 .79 505.06 LC High LC Pass 50.000 1400.0 - .02s00 - .1000d NOCHECK NOCHECK LC 700 -5. NOCHECK NOCHECK LC PASS LC PAss 4.0000 800.00 - .02000 -s.0000 1 1 1 L- L_ L- 0355 H27.048 0209 H26 .2L0 0252 H26 .255 LC High LC Pass Appendix F - 229 LC LC Pass 224 Analysis Report 03/to/06 o4:oo:45 PM page 2 High 70.000 100.00 10.000 40.000 40.000 s.0000 10.000 Low - .02000 -.02s00 -.02000 -.50000 - .04000 -.05000 -.05000 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge 27.670 3.0934 7 .6333 H41.537 4.29s3 .15002 SDev .105 .0238 .0788 .241, .021,4 .00139 ?RSD .48393 .768L7 l- . 0329 .s7947 .49831 .92353 #1 21.790 3.1208 7 .7243 H41.890 4.2729 .L4940 #2 21,.620 3 . 0790 7 .5897 H41 .410. 4 .2975 .15161 #3 21-.598 3.0804 7. s859 H41.611 4.31ss .L4906 Errors LC Pass LC Pass LC Pass LC High LC Pass LC Pass High 40.000 40.000 .40.000 40.000 70.000 30.000 Low -.05000 -.10000 -1.0000 -.30000 -.00400 -.01000 fntstd 1 Mode Count s EIem Y Wavl en 371,. 0 3 0 Avge 21,468 SDev 27 9 .6415 ?RSD 1 .3 02627 #r 27745 #z 2153 9 #: 2l5te 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 230 225 Analysis Report Method: TRA20505 Sample Name: H0HPV Run Time: 03/t0/0G 1G:00:48 Comment : Mode: CONC Corr. Factor: 1 03/1,0/06 o4:06:40 PM Operatolr: Sb ppm - .00005 .00294 5851 .3 -.00336 .00226 .00095 LC Pass 20.000 - .06000 Co ppm - .00005 .00057 1055.0 - .00055 .00050 - .00001 K- ppm .11899 .01962 16 .489 .09894 .13815 .11981 V- ppm .00035 .00058 155.94 -.00032 .00059 .00068 LC Pass As ppm .00087 .00059 79.88s .00008 .00tl-7 . 0 013'7 Cu ppm .03085 .00335 10.861 . 029 07 .03472 . 0287 7 Ni ppm .00421, .00134 31.708 . 0 03]-2 .00570 .00382 Zn ppm .00931 .0021-6 23 .18 B .0082-7 . 01\7 9 .00787 Ba ppm .00160 .00029 18.383 .00139 .00193 .00746 Fe ppm .05849 . 017 5L 25.559 .05516 .08832 .06201" Se /t ppm .00257 .00200 77.896 .00272 .00450 .00050 B_ ppm .00449 .00047 10. 407 .00502 .0041,2 .00435 Be ppm - .00011 .00013 116.50 00025 00001 00007 LC Pass 10.000 - .00500 Pb/ 7 ppm .00310 .00253 84 . 7 07 .00351 .00543 .00025 Se/2 ppm - .00007 .00098 1316.4 .00040 - . 0 0l.21, .00058 Mo ppm .00789 .00346 43. B3B - 011,54 .00746 .00466 LC Pass Cd ppm .00009 .00011 722. 3 9 Pb/ 2 ppm .00051 .00119 233 .7 4 .00047 - .00066 .00772 Ag ppm .001,96 .001s5 1 9 .046 .00032 .00340 .0021"6 Li ppm .00258 .000s8 22 .515 .00308 .00273 .00794 LC Pass page 1 Ca ppm . 0s 443 .00515 9.4ss5 Mg ppm . 04 666 .00686 a4 .711, .04009 .05378 .04511 Na ppm .01582 .21_0 B 5 1332.9 - .11605 .25901 -.09s49 Sr ppm .00030 .00005 1B . 1,28 .00025 .00035 .00029 LC Pass Elem Al Units ppm Avge .01033 SDev .00732 ?RSD 7 0 .832 #r #z #: .00189 . 01 425 .01485 Errors LC Pass High 700.00 Low - .20000 EIem Cr Units ppm Avge .00106 SDev .00100 ?RSD 94 .666 #r #z #: 00005 00206 00106 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge . 00 802 SDev .00020 ?RSD 2 .43 91 #r #z #: 00787 00824 00'7 94 Errors LC Pass High 30.000 Low - .01500 Elem T1 Units ppm Avge -.00434 SDev .00547 ?RSD 724. 6 5 #r #z #: Errors - .01050 -.0003s - .00218 LC Pass LC Pass LC Pass 30.000 30.000 - .01000 - .01000 -.00003 .05075 .0001,7 .05031 .00013 .0s223 LC Pass LC Pass 40 .000 500.00 - .00500 -s.0000 LC Pass LC Pass 100.00 50.000 - .05000 - .02500 LC Pass NOCHECK NOCHECK LC Pass 1,400.0 700.00 - .10000 -5.0000 LC Pass LC Pass 200.00 100.00 -5.0000 -.04000 NOCHECK NOCHECK LC Pass LC Pass 4 .0000 800.00 - .02000 -5.0000 LC Pass LC Pass Appendix F - 231 226 Analysis Report 03/lo/oe o4:05:40 PM page 2 High 70.000 100.00 10.000 40.000 40.000 s.0000 10.000 Low - .02000 -.02500 - .02000 -. s0000 -.04000 -.05000 - .0s000 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge .00099 .0L256 .00505 .06531 ,00183 .001-14 SDev .00055 .00027 .00152 .00232 .00014 .00032 tRsD ss.750 2 -l.825 25.024 3 .5579 7 .81-42 27 .948 #1 .00055 .01-234 .00757 -06266 .00197 .00149 #2 .00163 .0L247 .00509 .05700 .00182 .00105 #3 .00070 .07.286 .00453 .06628 .00159 .00087 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30. O0O Low -.05000 -.10000 -1-0000 -.30000 -.00400 -.01000 fntstd 1 Mode Count s EIem Y Wavlen 37]-. 03 0 Avge 27998 SDev 34.32928 %RSD .1550551 #r 22037 #z 2Le73 #: 21,984 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 232 227 Analysis Report Method: TRA20505 Sample Name: H0HPX Run Time: 03/lA/06 16:05:43 Comment : Mode : CONC Corr. Factor: 1 03 / 1,0 / 06 o4 : 1,2 :35 PM OperatoL: Co ppm .00108 .00049 45 .7 65 .00119 .00054 .001s1 K- ppm .26604 .00748 2.8108 .25704 .25811 . 27 297 V- ppm .00185 .00083 44.587 .0020t .00096 .00260 LC Pass As ppm .0s396 .00742 2 .6302 .05379 .05264 .05546 Cu ppm .05555 .00275 4 .9526 .05371, .05445 .05881 Ni ppm .00099 .00070 7 7 .240 .000s2 .00064 .00479 Zn ppm . 13 963 .00059 .4957L .1401_2 .13884 . 13 994 Ba ppm .04185 .00027 .49563 .04195 .04151 .04l.99 Fe ppm .46354 .00528 1.1397 .46266 .45875 .46927 Se/7 ppm .00927 .0021,4 23.106 .01769 .008s2 .00767 B- ppm .09184 .00181 1.9708 .09368 . 0 91"7 "7 .09006 Be ppm - .00015 .00005 40 .779 - .00022 - .00009 - .00015 Pb/t ppm 71-.631 . 410 .57277 72.045 7 a .224-/l .623 Se/z ppm .00370 .00086 23 .357 - 0031,2 . 0 0328 .00469 Mo ppm .00264 .00062 23.403 .00311 .00l-94 .00286 LC Pass Cd ppm .00094 .00018 18.730 .00107 .00014 .00101 Pb/2 ppm 69. s87 .135 .19577 69.609 69 .447 69.7l-a Ag ppm .00434 .000s6 1,2 .956 Li ppm .00648 .00007 1.0732 .00554 .00640 .00650 LC Pass page 1 Ca ppm 2.3582 .0022 .09237 2.3585 2.3ssB 2.3501 Mg ppm .47897 . 00 547 1, .2925 . 417 40 . 41,4 51 .425 0 0 Na ppm 8.2781 .1118 1.3503 Sr ppm .00699 .00004 .56875 .00703 .00695 .00700 LC Pass EIem Al Uni t. s ppm Avge .28351 SDev .00298 ?RSD 1.0509 #r #z #: Errors LC Pass High 700.00 Low - .20000 Elem Cr Units ppm Avge .01593 SDev .00048 ?RSD 3.0263 #r #z #: 01540 01,6 0 2 0163s Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .341 27 SDev .00182 ?RSD . s253 s #r #z #: .34604 . 3 4640 .34936 Errors LC Pass High 30.000 Low - .01500 EI em TI Units ppm Avge - ..0 0362 SDev .00019 ?RSD 27 .8 6 1 #t- #z #: Errors - .00401 -.00211 - .00413 LC Pass Sb ppm H81.560 .25s .31269 .28370 HB1 .907 .28044 HB 1 . 6-t 6 .28639 H81.398 LC High LC Pass 20 .000 30.000 - .06000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00s00 LC Pass LC Pass 40.000 600.00 - .00500 -5.0000 LC Pass LC Pass 100.00 50.000 - .05000 - .02s00 LC Pass NOCHECK NOCHECK LC Pass 1400.0 700.00 - .10000 -s.0000 LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHECK NOCHECK .00447 8.4039 .00375 8.2401 .00487 8.1902 LC Pass LC Pass 4.0000 800.00 - .02000 -s.0000 LC Pass LC Pass Appendix F - 233 228 Analysis Report 03 / 70 / 06 o4 :12 :35 PM page 2 High 70.000 100.00 10.000 40.000 40.000 5.0000 10.000 Low -.02000 - .02500 - .02000 -.50000 -.04000 -.05000 -.0s000 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge .01135 .01509 .32557 3 .61,32 H70 -268 .00588 SDev .00049 .00084 .00173 .0155 .2O5 .00049 tRSD 4.362t 5.5570 .53099 .4s993 .29144 8.2844 #1 .01137 .01597 .32587 3.6313 H70.427 .00630 #2 .01084 .01499 .32712 3.5987 H70.035 .00535 #3 .01183 .01430 .3237'J, z.eogi H7o.34B .00s99 Errors LC Pass LC Pass LC Pass LC Pass LC High LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.05000 -.10000 -1.0000 - .30000 - .00400 -.01000 InLStd 1 Mode Counts EIem Y Wav1en 371. 03 0 Avge 2L554 SDev 115.8483 ?RSD .5427224 #r 27429 #z 2166A #: 2L5'71, 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 234 o 229 Analysis Report Method: TRA20505 Sample Name: H0HP1 Run Time: o3/10/06 16:L2:39 Comment : Mode: CONC Corr. Factor: 1 03/L0/06 o4:18:31 PM Operator: Sb ppm .01844 .00385 20 .928 . 022'7 B . 017 71, .01541 Co ppm .00009 .00035 410.31 - .00002 - .00021 .00050 K- ppm .220 9 0 .00'743 3 .3613 .21,329 .22127 .22813 V- ppm .00036 .00027 s8.009 .00030 .00059 .00019 LC Pass As ppm - .00001 .00098 7 1,1,2 . L - .00094 - .00012 .00101 Cu ppm .02549 .00624 24 .469 .03151 .02590 .01905 Ni ppm .00063 .00034 53 . s5B .00101 .00037 .000s0 Zn ppm - o 441,4 . 0 0]-24 2 .875'7 -04531 . 04 426 . 04 284 Ba ppm .00233 .0001,7 7.3308 .00242 .00244 .002\4 LC Pass 30.000 - .01000 Fe ppm .86700 . 0 0 843 .97185 . 87 648 .85035 .8641,5 Se/t ppm - .00130 .0023a L76.99 - . 0 0364 - .00125 .00098 B- ppm .00378 .00032 B .4944 .00352 .00369 .0041,4 Be ppm - .00023 .00006 25.688 00029 0'0 022 00018 Pb/ t ppm .003s6 .00081 22 .71,4 .00446 .00333 .00289 Se/2 ppm .00165 .000'71 43 .267 .00138 .00246 .00111 Mo ppm .00148 .000l.7 11.337 .001,46 .00133 .001,66 LC Pass Cd ppm .00003 .00004 t24 .47 .00007 .00003 - .00000 Pb /2 ppm .00522 .00349 66 . BB7 .00908 .00430 .00228 Ag ppm . 0 0181 .00061 33.656 .00]-20 .00]-82 .00242 Li ppm . 0 01,25 .00008 6.3884 . 0 01,32 .001,26 . 0 0116 LC Pass page 1 Ca ppm .80009 .00108 . 13 s25 .80078 .79884 .8006s Mg ppm .04420 .00150 3 . 61,54 .04530 . 04 494 . 04 237 Na ppm 6.1256 .0334 .49593 5 .6929 6.-/596 6 .7 243 Sr ppm .001,69 .000a2 . 9231 t .00471 .001,69 .00168 LC Pass EIem AI Units ppm Avge . 04 849 SDev .00425 ?RSD 8 .77 45 #r #z #3 05031 051s2 o4362 Errors LC Pass High 700.00 Low - .20000 EIem Cr Units ppm Avge .00031 SDev .00018 ?RSD 59.1,25 #r #z #: 00010 00037 00045 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .03746 SDev .00341, ?RSD 9 . L052 #r #z #: 04082 03"7 54 03400 Errors LC Pass High 30.000 Low - .01500 Elem TI Unit s ppm Avge .00011 SDev .00118 ?RSD IO2B .1 #r #z #g Errors -.00026 . 0 01,43 - .00083 LC Pass LC Pass LC Pass 20 .000 30.000 - .05000 - .01000 LC Pass LC Pass LC Pass 10.000 40.000 500.00 -.00500 -.00s00 -5.0000 LC Pass LC Pass 100.00 50.000 - .0s000 - .02s00 LC Pass NOCHECK NOCHECK LC Pass 1400.0 700.00 - .10000 5.0,000 LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHECK NOCHECK LC Pass LC Pass 4.0000 800.00 -.02000 -5.0000 LC Pass LC Pass Appendix F - 235 230 Analysis Report High Low EIem Ti Units ppm Avge .001-72 SDev .00047 ?RSD 27 .57 5 #r #z #r 0 0222 00154 00129 Errors LC Pass High 40 .0 0 0 Low - .05000 Intst,d 1 Mode Counts Elem Y Wavlen 311. 03 0 Avge 21,87 6 SDev 25 .68736 %RSD .1,2]-9 9L4 #r #z #: 2t852 2tB7 2 21,9 05 10.000 - .02000 Si ppm .231,4L .00272 1 . 17'7 1, .23447 .23073 .22909 3 NOTUSED 40.000 - .50000 P_ ppm . 13 849 .00220 1.59L4 .1,4098 .13770 .13679 LC Pass 40.000 - .30000 4 NOTUSED 40.000 - .04000 Pb ppm .00519 .00251, 50.357 .00809 .00444 .00303 s.0000 - .05000 Se ppm .00100 .00085 84 . 564 .00003 .001s9 .00139 page 2 10.000 - .0s000 03/70/06 o4:18:31 PM 70.000 100.00 -.02000 - .02500 Sn ppm . 01 4l-7 . 0 0 1,1,7 8 .2254 .01295 . 01 429 . 01 s27 2 NOTUSED LC Pass LC Pass 40.000 40.000 - .10000 -1.0000 LC Pass LC Pass 70.000 30.000 - .00400 - .01000 5 NOTUSED NOTUSED NOTUSED Appendix F 236 231 AutoSampler Report Table Name: NEW Table: NEW 03/70/06 o4:25:27 PM page 1 10 1 1 1 1 Met hod #Pos Rack# StartPos SampIe Positions: 0 /tgz Rinse Stat.ion location is Racks Rack # Type Aux. (L) Rack Samp1e ( f 6mm) Sample ( 15mm) Sample ( 16mm) Sample ( 15mm) Sample Sets Set# Type Prepare? Autosampler Type: TYPE TJA QC Positions: 5 /tg # Sets: 1 rack -7-, pos. -1. Usage #Pos Left Analys es / Pos 5 0 0 0 0 1 2 3 4 5 srD /ocler,ANr Samples Samples Samples Samples Des cripL ion Normal No Preparation Info Set# Uptake Uptake#2 TRA2 0505 792 FinaI Di1 . Factor No Samples Prepared. Rack # t- Pos Row CoI Sample Name Set ##Used Type 11 21 31 41 51 61 71 B1 91 10 1 11 1 t2 1 13 1 L4 1 (1s. . .1e Rack #Z 1 S0 2 51 352 4 ICV 5 CCV1 6 CCV2 7 CCV3 B CCV4 9 CCVs 10 CCV6 11 CCVT 12 CCVB 13 CCV9 1,4 CCV10 Not Used) -NA- -NA- -NA. -NA- .NA. -NA- -NA- .NA- -NA- -NA- .NA- -NA. -NA- -NA- 1 1 1 1 1 1 1 1 1 1 1 1 1 1 S t andard Standard QC Standard QC Standard QC Standard QC Standard QC Standard QC Standard QC Standard QC Standard QC Standard QC Standard QC Standard QC Standard Pos Row Col Sample Name Set ##Used Type 1 2 3 4 5 6 7 1 1 1 1 1 1 1 1 2 3 4 5 6 1 ICB I CSAl I CSAB 1 CRDL1 O CDRL2 O CRDL4 O CCB 1 1 1 1 1 1 1 1 Appendix F 237 -NA- Samp1e -NA- Sample -NA- Sample -NA- Sample -NA- Sample -NA- Sample -NA- Samp1 e 232 AutoSampler Report Rack #Z Pos Row CoI Sample Name 03/to/oG o4:25:27 PM Set # #Used T)rpe Table: NEW page 2 B 9 10 11 t2 13 1_4 15 1,5 1,7 1B 19 20 27 22 23 24 25 26 27 2B 29 30 31 32 33 34 35 36 37 3B 39 40 41, 42 43 44 45 46 47 4B Rack #g B HoQT2B 9 H0QT2 C 1 0 HoQTEB 11 HoQREC 1,2 HO PGEB 1 HOPGEC 2 HO PGEL 3 HOLJB 4 HOLJE S 5 HOLJS P 6 CCB2 7 HOLJBD B HXQ1X 9 HXQ1XS 10 HXQ1XD '11 HXQ2H 72 HXQ2M 1 HXQ2V 2 HXQ24 3 HXQ3D 4 HXQ1XP 5 CCB3 6 HOHPE 7 HOHPM B HOHNV 9 HOHN9 10 HOHPC 11 HOHPF 1,2 HOHPK 1 HOHPV 2 HOHPX 3 HOHP1 4 CCB4 5 HOHP5 6 HOHPS S 7 HOHP6D B HOHQA 9 HoHQF 10 HoHQM 11 H0HQT t2 HoHQX -NA- Sample -NA- Sample -NA- Sample -NA- Sample -NA- Sample -NA- Sample -NA- Sample -NA- Sample -XA- Sample -NA- Sample -NA- Sample -NA- Sample -NA- Sample -NA- Sample -NA- Sample -NA- Samp1e -NA- Sample -NA- Sample -NA- Sample -NA- Samp1e -NA- Sample -NA- Sample -NA- Sample -NA- Sample -NA- Sample -NA- Sample -NA- Sample -NA- Sample -NA- Sample -NA- Sample -NA- Sample -NA- Sample - NA- Samp le - NA- Samp 1e -NA- Sample -NA- Samp1e -NA- Sample -NA- Sample -NA- Sample -NA- Sample -NA- Sample Set ##Used T)rpePos Row CoI Sample Name 1 2 3 4 5 6 7 1 2 3 4 5 6 '7 1 1 1 1 1 1 1 H0HQ2 HOHPS P CCB5 H0HQ6 HOHRG HOHRT HO PF3 L 1 1 1 1 1 1 1 Appendix F 238 -NA- -NA- -NA- -NA- -NA- _NA- -NA_ Samp 1 e Sample Samp I e Samp 1 e SampIe SampIe Samp 1 e 233 AutoSampler Report Table: NEW Rack #: Pos Row CoI Samp1e Name 03/to/06 o4:25:27 PM Set # #Used Type page 3 B 9 10 11 1,2 13 74 15 1_6 1,7 1B 19 20 21 22 23 24 25 26 27 2B 29 30 31 32 33 34 35 36 37 3B 39 40 4t 42 43 44 45 46 47 4B Rack #q B HOHF4 Z1,O 9 H0A1QZ20 10 HOA1R 11 HOA1W 1,2 H0A11 1 H0A12 2 CCBs 3 . H0A13 4 H0A14 s H0A15 5 HOHRO 7 HOA15 S B HOAl5D 9 HOHTE 1O HOHTES 11 HOHTED 12 HOHTRP 1 CCBT 2 H0A17 3 H0A2Q 4 HOHR4 5 HOHHKZIO 6 HOHRS 7 HOHEH B HOHEO 9 HOHE6 10 HOHGL 11 HOHE9 72 CCBB 1 HOHFG 2 HOHFGS 3 HOHFGD 4 HOHFGP s HxQ2HZ2O 6 HXQ2N\Z2} 7 HX124220 B HXQ3DZ20 9 HOHPEZ5O 10 HXQ1XP25 11 CCB9 A2 HOHPCZ2O -NA- _NA- -NA- -NA- -NA- -NA_ -NA- -NA- -NA- -NA- .NA- -NA- -NA- -NA- -NA- -NA- -NA- .NA- -NA. _NA- -NA- -NA- -NA_ -NA- -NA- -NA_ -NA- -NA. -NA- -NA_ -NA- _NA- -NA_ -NA_ _NA- -NA_ -NA- -NA- -NA- -NA- -NA- Set ##UsedPos Row CoI Sample Name Sample Sampl e Sample Sample SampIe Samp 1 e Samp 1 e Sample SampIe Sample Sample SampIe SampIe Sample Sample Sample Sample SampIe Sample Sample Sarnple Sample SampIe Sample S arnp 1e SampIe Sarnp 1e Sample SampIe Sample SampIe Samp I e Sample Sample Sample Sample SampIe Sample Sample SampIe SampIe Type 1 2 3 4 5 6 '7 1 1 1 1 1 1 1 1 2 3 4 5 6 7 HOHPKZSO HOHPX25O CCBl O ( empt.y ( empty 1 1 1 1 1 1 1 Appendix 239 -NA- Sample - NA- Samp Ie -NA- Sample -NA- Sample -NA- Sample -NA- _NA- -NA- -NA_ F- 234 AutoSampler Report Rack #+ Table: NEW Pos Row CoI Sample Name 03 / 70 / o6 04 :25 :2't PM Set # #Used Type page 4 I 9 10 11 t2 13 1,4 15 16 1,7 18 19 20 21, 22 23 24 25 25 27 2B 29 30 31 32 33 34 35 36 37 3B 39 40 47 42 43 44 45 46 47 4B Rack #5 8 9 10 11 t2 1 2 3 4 5 6 '7 B 9 10 11 t2 1 2 3 4 5 6 1 B 9 10 11 t2 1 2 3 4 5 6 7 B 9 10 11 1,2 empty empty empt.y empty empty empty empty empty empty empty empt.y empty empty empty empty empty empty empt.y empty empty empty empty empty empty empty empty empty empt.y empty empty empty empt y empty empty empty empty empty empt.y empt.y empty empt.y _NA- -NA_ -NA- _NA- -NA- -NA- -NA- -NA- -NA- .NA- -NA- _NA- -NA- _NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA_ -NA- -NA_ _NA_ -NA- -NA- -NA- _NA- -NA_ _NA_ _NA_ -NA- _NA- _NA- -NA- -NA- -NA- _NA- -NA_ -NA- -NA- -NA- -NA- -NA- _NA- -NA- -NA- .NA- _NA- -NA- -NA- _NA- -NA- _NA_ -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA_ -NA- -NA- -NA- -NA- -NA- -NA- -NA_ _NA- -NA- .NA- -NA- -NA- -NA- -NA_ -NA- Pos Row CoI Sample Name Set ##Used Type 1 2 3 4 5 6 "7 1 2 3 4 5 6 7 1 1 1 1 1 1 1 empty empty empty empty empty empty empty 1 1 1 1 1 1 1 Appendix 240 -NA- -NA- -NA- -NA_ -NA- _NA- -NA- -NA. _NA- _NA- -NA- -NA- -NA- _NA- 235 AutoSampler Report Rack #S Table: NEW Pos Row Col Sample Name 03/1,0/06 04:25:27 pM Set # #Used Type page 5 I 9 10 11 1,2 13 74 15 1,6 1,7 1B 19 20 21, 22 23 24 25 25 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41, 42 43 44 45 46 47 4B B 9 10 11 72 1 2 3 4 5 6 7 B 9 10 11 t2 1 2 3 4 5 6 7 B 9 10 11 l2 1 2 3 4 5 6 7 B 9 10 11 a2 empty empty empty empty empty empty empty empty empty empty empty empLy empty empty empty empty ernpLy empty empty empty empty empty empty empty empty empty empty empty empty empty empty empty empt.y empty empty empty empty empty empty empty empty -NA- .NA- -NA- -NA- -NA- .NA- -NA- -NA- -NA- -NA- -NA. -NA- -NA- - IdA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- _NA- -NA- -NA. -NA- -NA- -NA- _NA- -NA. -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- .NA- -NA- -NA- -NA- _NA- -NA- .NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA. -NA- -NA- -NA- -NA- -NA. _NA- _NA- -NA- -NA- -NA- -NA- _NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- -NA- Appendix F - 241 236 Analysis Report QC Standard Method: TRA20505 Sample Name: CCV4 Run Time: 03/70/06 15:53:48 Comment : Mode : CONC Corr. Factor: 1 03/to/06 o4:59:40 PM Operator: Sb ppm .49862 .00s19 1.041,7 .497 48 .50429 .49410 QC Pass .50000 10.500 Co ppm 1.9928 .0149 .-74590 1.9880 2.0095 1.9809 QC Pass 2.0000 10.500 K_ ppm 48.393 .57 9 1.1964 48.510 48.833 41 .-r31 V- ppm 1.9136 - 0l-7]- .86479 1.9725 1.9911 1.9570 QC Pass As ppm .49818 .00220 .44223 .49 915 .49973 . 4956 6 Cu ppm t .9264 .0157 .81443 1.9311 1.9391 7.9088 QC Pass 2.0000 10.500 Ni ppm 2 .0082 .0724 .57842 2.0048 2 .0220 1.9919 Zn ppm 2.0331 . 01,29 .63396 2.03 16 2 .0467 2 .021,7 Ba ppm 1.9688 .0472 .87324 r.97].6 1.9844 1.9504 Fe ppm 24 - 91,7 .1,97 .78958 24.878 25 .13 0 24 .7 42 Se/t ppm .49947 .00185 .36934 .50068 .50038 .49t734 B_ ppm 1.9s19 . 01,42 .72861 1.9572 1.9527 1.9358 Be ppm 2 .0265 .0115 . s6568 2 .0288 2 .0367 2.0141 Pb/1, ppm .50166 .00250 .49900 .50208 .50392 .49897 Se/z ppm .5001s .00460 .91990 .50]-56 .50388 .49s01 Mo ppm 1.9905 .0102 .51014 1.9883 2.0016 1.9816 QC Pass Cd ppm . s0080 - 002'79 . s5792 . 49 9]4 .50403 .49923 50413 50602 s0382 Ag ppm .97 827 .007),4 .7 2954 .98005 .98435 .97041 2.0055 2 .0032 t .9669 QC Pass page 1 Ca ppm s0.048 .29s .58943 49 .992 s0.366 49.784 49 .027 49.488 48 .821, Na ppm 48.5BB .483 .99151 48.783 49 . L1,1 48.155 1.9752 1.9845 1.9s20 EIem A1 Units ppm Avge 24 .1 I 3 SDev .2lB ?RSD .89954 #r #z #: 24 .227 24 .37 6 23 .94'7 Errors QC Pass Value 25 .0 0 0 Range 10.500 Elem Cr Units ppm Avge 1.9840 SDev - 4777 ?RSD .89467 #l- #z #3 1.9815 2 . OO29 1.9677 Errors QC Pass Value 2.0000 Range 10.500 Elem Mn Units ppm Avge 1.9975 SDev .0186 ?RSD .931,92 #r #z #: 1- .9926 2.0180 1.9818 Errors QC Pass Value 2.0000 Range 10.500 EIem T1 Units ppm Avge .9977 4 SDev .00661- ?RSD .66271, #r #z #: Errors .99 911 1.0035 .99056 QC Pass QC Pass QC Pass .50000 2.0000 10.500 10. s00 QC Pass QC Pass QC Pass 2.0000 .50000 s0.000 10.s00 10.500 10.500 Pb/2 Mg ppm ppm . 5 0 456 49 .1-1,2 .00119 .342 .23651, .69530 QC Pass NOCHECK 25.000 10.500 NOCHECK QC Pass s0 - 000 10.500 QC Pass QC Pass s0.000 2.0000 10.500 10.500 NOCHECK NOCHECK QC Pass QC Pass 1.0000 50.000 10.500 10.500 Li Sr ppm ppm 1.9919 1.9706 .021-7 - 01,67 1.0870 .84877 QC Pass QC Pass Appendix F - 242 QC Pass 237 Analysis Report QC Standard 03/La/06 o4:59:40 PM Value Range #r #z #: Int Std Mode EIem WavIen Avge SDev ?RSD #r #z #: 1.0000 10.500 2 .067 4 2 .0842 2 .0s02 1 Count s Y 371,. 0 3 0 22132 12.49702 .327 567 5 22055 22l-43 22a9 B 2.0000 10.500 Sn ppm 1.9970 .0119 .59366 1.9993 2 .001 4 1.9841 2.0000 10.500 Si ppm 1.9s15 .0151 .7 7 261, 1.9542 1.9550 7 .9352 2.0000 10.500 P_ ppm 2.L933 .0138 . 527 s9 2.2088 2.L825 2.L887 2.0000 10.500 Pb ppm .50408 .00l-57 .31131 . s0390 .50573 . s0267 2.0000 10.500 Se ppm . s0025 .00353 .7 2s52 .50158 .50303 .49515 page 2 2.0000 10.500 Elem Ti Units ppm Avge 2 .0673 SDev . 017 0 ?RSD .82237 Errors QC Pass Va1ue 2.OO0O Range 10.500 QC Pass QC Pass 2.0000 2.0000 10.500 10 .500 QC Pass QC Pass QC Pass 2.0000 .s0000 .s0000 10.s00 10.500 10.500 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F 243 238 Analysis Report Method: TRA20505 Sample Name: CCB4 Run Time : 0 3 / t0 / 06 7,7 :29 :1,0 Comment : Mode: CONC Corr. Factor: 1 03/to/05 o5:33:42 pM Operator: page 1 Cd Ca ppm ppm - .00011 .00367 .00003 .00024 22.257 6.614a Elem AI Units ppm Avge - .02928 SDev .00278 ?RSD 9.502]- Elem Cr Units ppm Avge - .00053 SDev .00024 ?RSD 45.497 #r #z #: #l- #z #: #1 #z #g #r #z #3 #r #z #: 027 01, 03238 o2B4s 00027 00057 0007s 00114 00110 00090 .00095 - .00034 .00369 00005 00031 00005 Sb ppm . 0 01-12 .00056 59. 01 9 .00098 .000s4 .00184 Co ppm .00001 .00025 l.729.3 .00018 .00013 -.00027 K_ ppm .05823 .00274 4 .0077 .05633 . 07 ]-37 .06700 V_ ppm - .00005 .00015 253.03 - .00023 .00003 .00003 Sn ppm .00054 .00027 38.398 .00075 .00033 .000s6 As ppm .00072 - 0 0 09'7 135.15 - .00035 . 0 01,52 .00100 Cu ppm .00769 .00030 3. B384 .00771 .00793 .00736 Ni ppm - .00064 .00014 2l .'7 67 00049 oo07l 00066 Zn ppm .00013 .00011 82.346 .00006 .00026 .00008 Si ppm -.02837 .00109 3.8511 027 68 02'7 6B 029s"7 Ba ppm - .00018 .00002 9.8692 00016 00018 00020 Fe ppm .00631 .00311 49 .329 .00531 .00980 .00382 Se/7 ppm .00062 .00073 116. B5 .00139 .00054 -.00006 B_ ppm .0001-7 .00031 181.06 .000s3 .00002 - .00003 P_ ppm . 00 248 . 0 01,46 58.724 .00080 .00343 .00321 Be ppm .00769 .00005 3 .0900 .00163 .00772 .00t7t Pb/7 ppm - .00330 .00155 47.307 00154 00384 00453 Se/2 ppm .00104 .00096 91 . 7 60 - .00006 .00153 .00766 Mo ppm .00039 .00005 13 .772 .00045 .00035 .00036 Pb ppm . 00 072 .00023 794.80 .00024 .00021 - .00015 00009 00011 00014 Pb/ 2 ppm . 0 0115 .00055 48.7 ].4 .00052 .00160 .00131 Ag ppm - .00075 .00017 22 .944 - .00073 - .00059 .00093 Li ppm .00031 .00004 44.480 .00033 .00034 .00026 Se ppm . 0 0118 .00042 35. 473 .00070 .00]-48 .00737 .00372 .00388 .00340 Mg ppm -.00008 .00183 2304.1 . 0 0111 .00084 - .00279 Na ppm -.37345 .11s90 31.035 - .26441, - . 3 607 B - .4951-7 Sr ppm - .00004 .00001 24 .7 03 00004 00003 00004 Elem Mn Unit s ppm Avge .00105 SDev .00013 ?RSD 72 .3 13 Elem Tl Units ppm Avge . 0 01,43 SDev .00205 ?RSD l.43 .45 Elem Ti Units ppm Avge .00014 SDev .00015 ?RSD 109.46 Appendix F - 244 239 o Analysis Report fntstd 1 Mode Counts Elem Y Wav1en 37l.. 03 0 Avge 24889 SDev 1,2 .27569 ?RSD .0490812 #r #z #g 2489 5 2489 6 2487 5 03/1,0/06 o5:33:42 PM page 2 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F 24s 240 Analysis Report Met.hod: TRA20505 Sample Name: H0HP6 Run Time: 03/a0 106 t7:35:02 Comment : Mode: CONC Corr. Factor: 1 03/70/06 o5:41:11 PM Operat or : Sb ppm .00463 .00109 23.500 .0057l- .003s2 .00468 Co. ppm .08783 .00].37 1.5587 .08933 .08752 . 0B 664 K- ppm t9 .235 - 244 7 .2s37 19.509 19 . 7,4a' 19.055 V- ppm .39555 .00754 1.9063 .40425 .39105 .39133 LC Pass As ppm .01436 . 0 01_21, B .4027 .01560 .01430 .01319 Cu ppm .06906 .00069 .994s2 .0697s .05904 .05838 Ni ppm .1509s .00248 7.6430 .1s318 .74993 .7.4 915 Zn ppm .56653 . 0120 6 1.8091 .67985 .66333 .5s639 Ba ppm . 67 a27 . 01024 1 . 5191 .68288 . 6 6'71-4 .6637 B Fe ppm 1,1,7 . 3 B 7 .92 1.5329 119 . s4 116 .75 115.86 Se/r ppm .00643 .00091 t4 - 195 .00567 .00744 .0061,7 B_ ppm .0'7299 .00a64 2 .2441, .07 487 . 07 224 .07185 Be ppm .02643 .00a28 1.0544 . -0257 4 .02632 .0262A Pb/1, ppm .0561,4 .0039s 7 .0344 .05030 .0556-/ .05244 Se/z ppm .00609 .00138 22 .665 .00453 .00650 .007l:5 Mo ppm .00465 .00018 3.9804 .00464 .00448 .00485 LC Pass Cd ppm .00447 .00024 5 .4725 .00473 .00443 .00425 Pb/2 ppm .0sqo3 .00150 2 .7 482 .05533 .05828 .05949 -.00'792 - .00868 - .00914 Li ppm . 124tl .00156 7 .2552 .l-25 9 0 .723 47 .1-23 0 3 LC Pass page 1 Ca ppm 74 - 381 1.208 1.5237 7 5 .129 74.014 73.398 Mg ppm 132 .'7 5 2 .31, 1, .7 432 135.33 a32. 0 9 130. B5 t .6462 1.5253 1, -4115 LC Pass 800.00 -5.0000 Sr ppm .2921,7 .00458 1.5678 . 297 37 .29 04 3 .2887 2 LC Pass EIem A1 Units ppm Avge 153 . 04 SDev 1, .7 6 ?RSD 1.1507 #r #z #: 155.05 1_52. 3 0 151 .75 Errors LC Pass High 700.00 Low - .20000 Elern Cr Units ppm Avge .45722 SDev .00762 ?RSD t - 666s #r #z #s 4657 B 45471, 451,1,7 Errors LC Pass High 100.00 Low - .01000 E]em Mn Units ppm Avge L .6647 SDev .028]- ?RSD 1,.6860 #r #z #: I .6964 I .5541 1 .6430 Errors LC Pass High 30.000 Low - .01500 Elem Tl Units ppm Avge -.00230 SDev .00203 ?RSD 88.25s #r #z #: Errors - .00009 - . 0 02'73 -.00407 LC Pass LC Pass LC Pass 20.000 30.000 - .06000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00500 LC Pass LC Pass 40 .000 500.00 - .00500 -s.0000 LC Pass LC Pass 100.00 50.000 - .05000 - .02500 LC Pass NOCHECK 14 0 0 . 0 - .10000 NOCHECK LC Pass 700.00 -5.0000 Ag Na ppm ppm - .00858 1. s277 .00062 .1,]_74 1.1819 7.5845 LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHECK NOCHECK LC Pass 4 .0000 - .02000 LC Pass LC Pass Appendix F - 246 241, Analysis Report 03/to/06 o5:41:11 PM page 2 High 70.000 100.00 10.000 40.000 40.000 5.0000 10.000 Low 02000 -.02500 -.02000 -. s0000 -.04000 - - 0s000 - .05000 EIem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge .55658 .0L522 4.0702 24.334 .05778 .00648 SDev .040'77 .00043 .0591 .350 .00019 .00114 zRSD 1, -6406 2.81,04 1.5988 L.4784 .33579 17.568 #r . 56859 . 01511 4 .1-473 24 .71-5 . 05794 . 00516 #2 .5s339 .0.1s69 4.0496 24.285 .05784 .OO71-7 #3 .64776 .01485 4.0135 24.002 .05757 .00710 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40. ooo 40. ooo 40. ooo 4o.0OO 70. oo0 30.000 Low - .05000 -.10000 -1.0000 - .30000 - - 00400 - .01000 Intstd 1 Mode Count s EIem Y Wavlen 3'7 7. 0 3 0 Avge 2B1BB SDev 402 .6241 ?RSD I .428345 #r 27770 #z 28222 #g 28s73 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 247 o 242 Analys i s .Report Method: TRA20505 Sample Name: H0HP6S Run Time: o3/a0/05 7'7:41:15 Comment : Mode: CONC Corr. Factor: 1 03 / 70 /oG o5 : 4't :23 PM Operator: Sb ppm .09497 .00579 6.0989 .10l-54 . 0 9233 .0908s Co ppm . 1,49 48 .00595 3.9193 . 15 632 .1,4555 .1,4555 LC Pass 100.00 - .05000 K- ppm 48.506 1, .'7 59 3 .6t96 50.599 47 .266 47 .954 LC Pass 200.00 -s.0000 V- ppm . 549 46 .02558 4 . 6562 .57 824 .52928 .54087 LC Pass As ppm .01573 .00331 4 .37 22 . 07 952 .07347 . 07 426 Cu ppm . 2323 6 .00855 3.7236 .24225 .22627 .228 5 1 LC Pass 50 .000 - .02s00 Ni ppm .46032 .01950 4 .2582 .4829l. .44713 .45033 Zn ppm 1.0697 .0443 4 . L421 1,1,91 0375 0500 Ba ppm .75060 .02805 3.-7 368 . -7 8261 .73062 .7 3 852 Fe ppm r27. 3 1 5.03 4 .1,432 1,27.06 1,77 .7 8 119.09 Se/t ppm .1021 4 .00604 5.8754 .1097L .09950 .09902 B_ ppm .59647 .02150 3 .6042 .62123 .58373 .58427 Be ppm .05625 . 0 0197 3 . s003 .05849 .05480 .05546 Pb /t ppm .l.21s0 .00811 6 .6750 .13058 .11853 .11529 Se/2 ppm .09332 .00248 2.6534 .09511 .09245 .09140 Mo ppm -2L1B1 .00876 4.7353 .227'7 2 .20 s 10 .20861 LC Pass Cd ppm . 03 824 . 0 01,6-l 4 .3597 .04015 .03717 .03739 Pb/2 ppm . 117 54 . 00 227 1.921 s .11982 . 11 529 . 117 5t Ag ppm . 01 656 .00247 74. B9B Li ppm .22530 .00734 3.2565 .23354 . 21,9 46 .22291 LC Pass page 1 Ca ppm 9'7 .332 4.l.34 4 .247 I l-02. 05 94.390 95. 547 Mg ppm 128.23 5 .41 4 .215 0 134.40' 724. 3 5 L25. 93 Na pprn 34.238 1.087 3 . 1152 Sr ppm .58l.23 . 0223 4 3.8428 .50684 .55574 - 5'7113 LC Pass EIem A1 Units ppm Avge 18 5 .3'7 SDev 6 .55 %RSD 3.5872 #r #z #: 792 .94 180.48 1,82 . 69 Errors LC Pass High 700.00 Low - .20000 Elem Cr Units ppm Avge .60072 SDev .02580 ?RSD 4.29s0 #r #z #g 53030 58297 58894 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge 1,.7 082 SDev .067 6 ?RSD 3.9599 #r #z #: 1.7 B5B t .65t9 1 . 6 7 58 Errors LC Pass High 30.000 Low - .01500 Elem T1 Units ppm Avge .237 50 SDev .009]-4 ?RSD 3. B4BO #r #z #a Errors .24805 .23189 .23251 LC Pass LC Pass LC Pass 20 .000 30.000 - .06000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00500 LC Pass LC Pass 40 .000 500.00 - .00s00 -5.0000 LC Pass NOCHECK NOCHECK LC Pass 1400.0 700.00 -.10000 -5.0000 LC Pass NOCHECK NOCHECK 100.00 - .04000 .01940 3s.490 .01489 33.534 .01s41 33. 591, LC Pass LC Pass 4.0000 800.00 - .02000 -5.0000 1 1 1 Pass LC Pass Appendix F - 248 LC 243 Analysis Report 03/Lo/06 o5:4"t:23 PM page 2 High 70.000 100.00 10.000 40.000 40.000 5.0000 10.000 Low -.02000 -.02500 -.02000 -.50000 -.04000 -.05000 -.05000 Elem Ti Sn Si P_ Pb Se UniLs ppm ppm ppm ppm ppm ppm Avge .94055 .29524 2.1-827 25.624 ,11913 .09667 SDev .03745 .01383 .0849 1,.077 .00394 .00365 ?RSD 3.9815 4.6849 3.89L2 4.2052 3 .3085 3 .771,9 #1 .98324 .31115 2.2792 26.84s .1-2368 .10086 #2 .9L32L .28604 2.]-2t4 24.8L7 .a167a .09500 #3 .92520 .28853 2 .t458 2s .20L .11700 .09417 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.00.0 40.000 70.000 30.000 Low -.05000 - .10000 -1.0000 -.30000 - .00400 -.01000 Intstd 1 Mode Counts EIem Y Wavlen 371.030 Avge 34054 SDev 7324 .402 ?RSD 3.889l-22 #r 32s38 #z 34984 #: 34640 234557 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 249 244 Analysis Report Method: TRA20505 Sample Name: H0HP6D Run Time: 03/70/06 l7:47:2'7 Comment: Mode: CONC Corr. Factor: 1 03/to/06 o5:53:35 PM Operator: Sb ppm . 1114 3 .00417 1.0476 .111,75 . 11 013 .11240 Co ppm .1994]- .00151 .75570 .19835 .19872 . 20113 LC Pass 100.00 - .05000 K- ppm 51.081 .749 .24422 60.9s0 51. 049 61 . 243 V_ ppm .6861s .00047 .06893 .68584 .58591 .58659 LC Pass As ppm .09006 .00043 .47908 .08957 .0903s .09026 Cu ppm .28597 .00320 1.1797 .283 5 9 .28472 .2896L LC Pass 50.000 - .02500 Ni ppm .s8002 .00288 .496'7 0 .57902 . 517 7'7 .58326 Zn ppm t.24BB . OOBB .7 0862 2421 2455 25BB Ba ppm 2 .67 59 . 0115 .42843 2 .6663 2.6753 2.6891 ].47. B9 14 B .41 149.30 118 71 L1,67 7 11357 .57274 .67763 .68744 Be ppm .06980 .00018 .26524 . 05 9s9 .0'6988 .05993 .l-7050 .15l.52 .15589 10931 l-L212 l_16L2 .247 47 .24852 .25028 LC Pass Cd ppm . 0 4456 .00019 .42288 .04469 .04435 . 04 46s Pb/2 ppm . 1,6 449 .0045'7 2.7 7BB .150s5 . 1,63 42 .16950 Ag ppm .02860 .00013 .44900 .02856 .028s0 . o2B7 5 Li ppm .27386 .00067 .24326 -2-7341 .27348 .27 453 LC Pass page 1 Ca ppm 115 .25 .09 .0"7948 115 . 19 115.19 115.35 Mg ppm 154 .64 .78 . s 01-42 1s3 .93 154 .53 155 .47 Na ppm 40.976 .707 .26 07 9 4t .029 40.853 47 .04-7 Sr ppm .7 0258 .00294 .4l.805 .'7A055 .7 0L24 .70595 LC Pass Elem AI Units ppm Avge 221.53 SDev 1.08 %RSD .47 473 #r #z #: 226 .7 6 227 .07 228.77 Errors LC Pass High 700.00 Low -.20000 Elem Cr Units ppm Avge .73856 SDev .00267 ?RSD . 3 5101 #r #z #: .7 3 620 .73802 .7 4745 Errors LC Pass High 100.00 Low - .01000 El em Mn Units ppm Avge 7 .9735 SDev .0425 ?RSD . s3 257 #r #z #: 7 .9362 7 .9646 B . 019"7 Errors LC Pass High 30.000 Low - .01500 Elem TI Units ppm Avge .28 95 0 SDev .007'7'7 ?RSD .67058 #r #z #: Errors .29115 .2897 2 .287 53 LC Pass LC Pass LC Pass 20.000 30.000 - .06000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00s00 Fe Pb /1, ppm ppm 148.53 .15297 .77 .00 692 .48051 4.2477 LC Pass LC Pass 40 .000 500.00 - .00s00 -5.0000 LC Pass NOCHECK 1400.0 - .10000 se/t se/2 ppm ppm .11535 .11251- .00259 .00342 2.2290 3.0427 NOCHECK LC Pass 700.00 -5.0000 LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHECK NOCHECK B_ Mo ppm ppm .57 927 .2487 6 .00748 .00142 1.1018 .57 09s LC Pass LC Pass 4 .0000 800.00 - .02000 -s.0000 1 1 1 LC Pass LC Pass Appendix F - 250 245 Analysis Report 03/to/05 o5:53:35 PM page 2 High 70.000 100.00 l-0.000 40.000 40.000 5.0000 10.000 Low - .02000 -.02500 -.02000 -.50000 -.04000 -.05000 - .05000 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge 1.0281 .35178 2.6289 29.605 . l-6435 .11405 SDev . 0040 . 00107 .0248 .1-72 . 00123 . 00144 %RSD .38737 .30478 .94279 .s8265 .74989 1.2636 #1 L .0260 .35176 2 .6074 29 .4L6 . 15418 .a1268 #2 1, .0255 .35286 2 .6232 29 .648 .1-5321, . 113 91 #3 1".0327 .35072 2.6560 29.753 .L6566 .11555 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low - .05000 - .10000 -1.0000 -.30000 - .00400 -.01-000 Intstd 1 Mode Count s EIem Y Wavlen 371.030 Avge 28500 SDev ZOG .8425 ?RSD -72323'73 # r 2B'7 89 #z 28632 #3 2837 9 234s67 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 251 246 Analysis Report Method: TRA20505 Sample Name: HOHQA Run Time: o3/ao/06 t--t:53:39 Comment : Mode: CONC Corr. Factor: 1 03/70/oG o5:59:4-t PM Operator: page 1 Cd Ca ppm ppm .00009 5.8447 .00005 .0220 58.283 .37671 EIem AI Units ppm Avge 3 .2 951 SDev .0191 ?RSD .58086 #r #z #: 3.2986 3 . 31,23 3 .27 45 Errors LC Pass High 700.00 Low - .20000 Elem Cr Units ppm Avge . 03 57 4 SDev .0001'9 ?RSD 53268 #r #z #: 0357 9 03553 03s90 Errors LC Pass High 100.00 Low -.01000 Elem Mn Units ppm Avge .02986 SDev .00027 ?RSD .9l-929 #r #z #3 03005 02998 02954 Errors LC Pass High 30.000 Low - .01500 EIem TI Units ppm Avge -.00128 SDev .00274 ?RSD ]-66. s 0 #r #z #: Errors -.00240 -.00253 .00118 LC Pass LC Pass LC Pass 20 .000 30.000 - .06000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00500 LC Pass LC Pass 40.000 500.00 - .00500 -5.0000 Pb/2 Mg ppm ppm . 00 593 .69267 .00062 .00437 8.9535 .5303s Sb ppm .00311 .0021,5 69 .1-27 .00555 .00150 .00227 Co ppm .00509 .00019 3 .5985 .00513 .00488 .00s25 K- ppm .23072 .001s8 .68595 .23193 .23130 .22893 LC Pass 200.00 -s.0000 V_ ppm . 01 026 .00016 1. s835 . 01042 .01009 . 01 028 LC Pass As ppm .00945 .00054 5.7434 .00956 .00992 .00885 Cu ppm .01220 .000s3 4 .3411 .0128a . 0119 B .01782 Ni ppm .45287 .00285 .62905 .4547 6 .45426 . 4 4959 Zn ppm .04772 .00016 . 3 4202 .047 90 .047s8 .047 67 Ba ppm .08353 .00038 .45950 .0834lr .08395 .08322 Fe ppm 1 . 9344 .0057 .34585 1.9385 1.9378 1 . 9266 Se/t ppm .00279 .00j.24 44 .286 .00304 .00388 .00145 B_ ppm .10889 .00108 .99252 .10962 .10941, .10765 Be ppm . 0 01,43 .00011 7.5780 .00131 .00a43 .001s3 Pb/1, ppm .00733 .00060 8.1900 . 00 666 .00782 .00'752 Se/z ppm .00014 .00116 B5B .79 .00702 - .00118 .00056 Mo ppm .0029-l .00022 7 .3 511 .0031-1 .00301 .00273 LC Pass 00014 00010 00003 .00580 .00639 .00'764 Li ppm .00L66 .00011 5.5683 .00]-78 .00163 .00751 LC Pass 5.8325 s.8701 5. B3L4 69596 69432 68172 Sr ppm .0403 9 .0001s .37 264 .04033 .040s5 . 04 028 LC Pass LC Pass LC Pass 100.00 50.000 - .05000 - .02500 LC Pass NOCHECK 1400.0 - .10000 NOCHECK LC Pass 700.00 -s.0000 Ag Na ppm ppm - .00266 12.901 .00018 .077 5.5796 . s9691, 00265 t2.881 o 0249 1,2 . g g7 00284 1,2.837 LC Pass LC Pass 4.0000 800.00 - .02000 -s.0000 LC Pass NOCHECK NOCHECK 100.00 - .04000 LC Pass LC Pass Appendix F - 252 o 247 Analysis Report 03/70/06 o5:59:47 PM page 2 High 70.000 100.00 10.000 40.000 40.000 5.0000 10.000 Low - .02000 -.02500 -.02000 -.50000 -.04000 -.0s000 -.05000 Elem Ti Sn Si P- Pb Se Units ppm ppm ppm ppm ppm ppm Avge .22991 .00839 L .4089 7.5347 -00744 .00131 SDev .00099 .00072 .01,26 .0131 .00042 .00061 ?RSD .42924 8.6333 .89613 .85314 5.6277 45.29L #1 .22958 . 00917 7 .4201 a .5477 . 00708 . 00198 #2 .231,02 .00774 1.4115 1.5215 .0073s .00079' #3 .2291-3 .00826 1,.39s2 1. s349 .00790 .00117 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.05000 -.10000 -1.0000 -.30000 -.00400 -.01000 Intstd 1 Mode Counts EIem Y WavI en 371,. 0 3 0 Avge 24939 SDev 13 5 .2473 ?RSD .s463279 #t- 24806 #z 24933 #: 2so7 B 234567 NOTUSED NOTUSED NOTUSBD NOTUSED NOTUSED NOTUSED Appendix F - 253 248 Analysis Report Method: TRA20505 Sample Name: HOHQF Run Time: 03/L0/06 77-.59:51 Comment : Mode: CONC Corr. Factor: 1 03/to/06 o5:05:59 PM Operator: LC Pass LC Pass 100.00 50.000 - .0s000 - .02500 K_ Ni ppm ppm 63.2-75 .02538 .206 .00031 .325 19 1.1'745 63.392 63.398 63.039 02654 02 6 61, 025 03 LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 V_ Zn ppm ppm - .00003 .01509 .00055 .000s3 21,63 .7 3 . 515 B - .00028 .01507 .00060 .01563 -.00039 .01451 LC Pass 30.000 - .01000 Cu ppm . 017 45 .00151 9.2400 .01693 .01926 - 01 61,6 Se/r ppm .00938 .0013s t4 .37 B .00975 .00789 . 010 51 B ppm .10l-25 .00l-79 7.7677 .10287 . 101,54 .09933 LC Pass LC Pass Appendix F - 2s4 LC Pass NOCHECK 14 0 0 . 0 - .10000 page 1 Cd Ca pprn ppm -.00012 2.L521 .00013 .0131 115.39 .60'726 .00004 - .00017 - .00021 LC Pass 40.000 - .00500 Pb/ 2 ppm .00567 .00221, 38.933 .00530 .00805 .00368 2.1,595 2.L59B 2.1377 LC Pass 600.00 -s.0000 Mg ppm .51533 .00806 1. s508 .52l,l.2 .52084 .50702 NOCHECK LC Pass 700.00 -5.0000 Ag Na ppm ppm - .0005s 22.513 .0000s .773 B.8323 .76959 - .00050 22.771, -.00056 22.439 - .00050 22.390 Lr ppm .00a74 .00005 3 .492l- .00180 .00774 .00158 LC Pass Sr ppm .01496 .00014 .94237 .01499 .01508 .01480 LC Pass EIem A1 Uni t. s ppm Avge 1.3048 SDev .0148 ?RSD 1.1333 #r #z #3 1 . 31,66 1 . 3 096 1, .2882 Errors LC Pass High 700.00 Low - .20000 Elem Cr Units ppm Avge .00888 SDev .00026 ?RSD 2 .9s99 #r #z #: 00913 00850 00891 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .05034 SDev . 0 01,57 ?RSD 3 .1169 #r #z #: 05014 05199 04BBB Errors LC Pass High 30.000 Low - .01500 Elem TI Units ppm Avge - .00304 SDev .00135 ?RSD 44 .3 6 8 #r #z #g Errors - . 0 0231, -.0022L - .00459 LC Pass Sb As ppm ppm -.00362 .00307 .00041 .00054 11.294 77 .597 .00408 .00369 .00347 .00270 .00331 .00281 LC Pass 20.000 - .05000 Co ppm .00021 .00023 109 .72 - .00000 . 00 046 . 00 077 Ba ppm .02808 .00040 L .42!2 .02814 .02845 .027 66 LC Pass 30.000 - .01000 Fe ppm .90294 . 011-42 1, .2545 .90722 .91150 .89000 Be ppm .00l.78 .00009 5.2895 .00168 .00\82" .00185 LC Pass 10.000 - .00500 Pb/1, ppm .00311 .00292 93 . 934 .00s01 - .00025 .004s6 Se/z ppm .00253 .00l.l.4 45.301 .00385 .00a94 .00180 Mo ppm ,00148 .00042 28 .435 . 0 01a7 .00190 . 0 0745 LC Pass NOCHECK NOCHECK LC Pass LC Pass 4.0000 800.00 - .02000 -s.0000 LC Pass 249 Analysis Report 03/70/06 o6:05:59 PM page 2 High 70.000 l-00.00 L0.000 40.000 40.000 5.0000 L0.000 Low - .02000 -.02500 - .02000 - .50000 - .04000 - .05000 -.05000 Elem Ti Sn Si P_ Pb Se UniLs ppm ppm ppm ppm ppm ppm Avge .03301 .01470 1.2881 36.737 .00521 .00510 SDev .00039 .00103 .0110 .L66 .00083 .0009s ?RSD 1.1,76L 7.0010 .85699 .45L92 15.895 a8.692 #1 .03296 .01552 7.2938 36.8'77 .00s69 .00510 #2 .03342 .013s4 1.2951 36.781 .00559 .0042L #3 .03265 . orsrjg r.2754 38.554 .00426 :oo49g Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.05000 - .10000 -1.0000 - .30000 - .00400 - .01000 IntStd 1 Mode Counts EIem Y Wav1en 37L.030 Avge 24492 SDev 59.50079 %RSD .2429385 #r 24437 #z 24484 #3 24sss 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 2ss 254 Analysis Report Method: TRA20505 Samp1e Name: HOHQM Run Time: o3/70/oG 18:05:03 Comment : Mode : CONC Corr. Factor: 1 03/ao/06 o6:12:11, PM Operator: page 1 Cd Ca ppm ppm .00349 77.872 .00008 .595 2.3138 .16485 Elem Al Units ppm Avge 6 .5909 SDev .0489 ?RSD .7 41 5 1 #r #z #3 6 .5345 6 .6l-59 6 .621,3 Errors LC Pass High 700.00 Low -.20000 EIem Cr Units ppm Avge 11.384 SDev .078 ?RSD .58185 #r #z #3 11.295 11. 433 11. 425 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge 1-.2095 SDev .0097 ?RSD . 80603 #r #z #g 1 . 1982 7 .21,57 L .21,45 Errors LC Pass High 30.000 Low - .01500 EIem TI Units ppm Avge -.00670 SDev .00139 ?RSD 20 .7 53 #r #z #: Errors - .00s58 - .00825 -.00625 LC Pass Sb ppm . OB2BB .00198 2.3858 .08269 .08100 .08494 LC Pass 20.000 - .06000 Co ppm .47 082 .00349 .7 415 5 .46680 . 47 262 .47305 K- ppm .8998s .00094 .10429 .89880 .90011 . 90 062 V_ pprn .01816 .00031 4.7 051 . 01 82a .01844 . 011 83 LC Pass As ppm .00254 .0012L 47 .656 .00118 .00295 .00349 Cu ppm .2747-l .00292 1.3881 .207 06 .21,285 -21"061 Ni ppm .10259 .00093 .90923 .10]-51 .10280 .10339 Zn ppm 1.7372 .0727 .7 2915 7 226 7 453 -l 438 Ba ppm 4 .4342 .0458 1.0329 4 .3 813 4 .461,6 4.4596 Be ppm .001,73 .00025 t4 .262 .0020a .00157 .00151 Pb/ t ppm 62 .269 .558 .89603 67 .626 62.563 62 .6].9 NOCHECK Se/z ppm .00391 .00058 t7 .269 .00466 .00334 .00374 NOCHECK Mo ppm . 011,92 .00031 3 . 0 894 .01151 .01223 .01207 LC Pass .00340 .003s0 .003s5 Pb/2 ppm 50. 657 .892 I . 411,0 59.634 51.2-l 4 6L.063 Ag ppm .00562 .00038 6.1870 .00520 .00574 .00s93 .01061 .01095 .01081 LC Pass 17 .18 B 7 B .l.47 -/ 8 .280 Mg ppm 1.9465 .0140 .72055 1.9305 1.9s69 1.9s21, Na ppm 2.4819 .2505 10. 094 2.]-985 2 .5735 2 .6737 .245 9 0 .25078 .251,02 LC Pass LC Pass LC Pass 30.000 30.000 - .01000 - .01000 LC Pass LC Pass LC Pass 10.000 40.000 500.00 -.00s00 -.00500 -5.0000 LC Pass LC Pass 100.00 50.000 - .05000 - .02s00 Fe ppm 29.479 .238 .80732 29 .205 29 .502 29.531 LC Pass 1400.0 - .10000 Se/r ppm .00484 .00240 49 .599 .00246 .00480 .00726 NOCHECK B_ ppm .0s702 .00094 L .6449 .05594 .05750 .0576].. NOCHECK LC Pass 700.00 -s.0000 LC Pass LC Pass 200.00 100.00 -5.0000 04000 LC Pass LC Pass 4.0000 800.00 - .02000 -s.0000 Li Sr ppm ppm .01079 .24957 .000L7 .00237 1 . 57 82 92545 1 1 1 Pass LC Pass Appendix F - 256 LC 25L Ana1ys i s Report.03/70/oG o5:1,2:17 PM page 2 High 70.000 100.00 10.000 40.000 40.000 5.0000 10.000 Low -.02000 -.02500 - .02000 -.50000 -.04000 -.0s000 -.0s000 Elem Ti Sn Si P_ Pb Se Unj-ts ppm ppm ppm ppm ppm ppm Avge .71-L62 .23666 1 .8242 .68510 61,.),94 .00453 SDev .00424 .00342 .0153 .00380 .779 .00059 ?RSD .59620 L.4459 .84L1_7 . s5318 7 .2728 t2 .96s #1 .70702 .23272 1.8065 .68417 60.298 .00422 #2 .71538 .23880 1.8333 .59048 6L.704 .00415' #3 .71,245 .23848 1.8329 .68367 6L.s82 .00s20 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low --05000 -.10000 -1.0000 -.30000 -.00400 --01000 Intst.d 1 Mode Counts EIem Y WavIen 371,.030 Avge 23934 SDev 233 .2944 ?RSD .97 47 556 #r 24202 #z 23820 #3 2377 9 234567 NOTUSBD NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 257 252 Analysis Report Method: TRA20505 Sample Name: HOHQT Run Time: 03/\0/06 18:1,2:75 Comment. : Mode: CONC Corr. Factor: 1 03/1,0/06 o6:18:23 PM Operator: page 1 Cd Ca ppm ppm -.00006 .11745 .00022 .00276 331.08 2.3509 - .00031 .11474 .00001 .11740 .00011 .l-2023 Pb/2 ppm .01804 .00810 44. BB2 . 027 27 .01501 .01190 Mg ppm .1Bs5B .001-73 .93333 .18643 .18370 .18692 Ag ppm .00100 .00258 257 .44 .00397 - .00043 - .000s4 Na ppm 2 .4357 .27 97 11. 482 2 .7164 2.553s 2 . 6371, Li ppm .00048 .00008 1,1 - 159 .00039 .000s3 .00053 LC Pass Sr ppm .000-l 4 .00003 4 .1,8 14 .00071 .00075 .00077 LC Pass EIem A1 Units ppm Avge .39454 SDev .00159 ?RSD .4025L #r #z #: 3960s 39288 39468 Errors LC Pass High 700.00 Low - .20000 Elem Cr Units ppm Avge - .00051 SDev . 00 096 ?RSD 185 .]s #r #z #g - .00747 - .000s1 .00044 Errors LC Pass High 100.00 Low -.01000 EIem Mn Units ppm Avge .0071,1, SDev .00013 ?RSD 1. BO51 #r #z #: 00725 00709 00700 Errors LC Pass High 30.000 Low - .01500 Elem TI Uni t. s ppm Avge - - 001,62 SDev .003L2 ?RSD a92.52 #r #z #: Errors -.00524 .0004s - .00010 LC Pass LC Pass LC Pass 20.000 30.000 - .06000 . 01000 Sb ppm . 0 011,7 .001,69 744. B 1 .00203 - .00078 .00226 Co ppm .00042 .00040 95 .47 B .00045 - .00000 .00080 K_ ppm .74559 . 0257 6 l7 .693 -1,7533 .1_2997 . 13 ]-49 V_ ppm .00023 .000s9 26A. 5 9 -.0003s .00020 .00083 LC Pass As ppm .00086 .00058 67.305 .000s2 .00053 . 0 01,52 Cu ppm .01633 .00070 4.2818 .01503 .01583 . 01'7 L3 Ni ppm .00006 .00094 1619.6 - .00094 .00019 .00093 Zn ppm .06061 .00051 .84495 .05111 .06008 .0606s Ba ppm . 06 407 .00049 .77013 .05358 .0640s .05457 Fe ppm .07236 .00807 11 - 1,47 . 07 3l-2 .05394 . 0B 002 Se/1, ppm - .00020 .00390 198L.6 - .00468 .00L'77 .00233 B_ ppm .00244 .00100 41,.039 . 0 01,28 .00296 .0030'7 Be ppm .00747 .00004 2 .847 9 - 0 01,45 . 0 01,42 .00137 Pb/ \ ppm .0070s .00335 47 .493 .00980 .00804 .00332 se/z ppm .00184 .00127 69.275 .00330 . 0 0L22 .00099 Mo ppm .000-75 .00020 26.856 .00088 .000s3 .00089 LC Pass LC Pass LC Pass LC Pass LC Pass 30.000 10.000 40.000 600.00 -.01000 -.00s00 -.00s00 -s.0000 LC Pass LC Pass 100.00 50.000 - .0s000 - .02500 LC Pass NOCHECK NOCHECK LC Pass 1400.0 700.00 - .10000 -s.0000 LC Pass LC Pass 200.00 100.00 -5.0000 -.04000 NOCHECK NOCHECK LC Pass LC Pass 4.0000 800.00 -.02000 -5.0000 LC Pass LC Pass Appendix F - 2s8 253 Analysis ReporL 03/to/06 o6:18 PM page 2 5.0000 10.000 - .05000 - .0s000 Se ppm .00l-46 .00045 31. 020 .00094 .001-73 .00l-72 o High Low 70.000 - .02000 100.00 - .02500 Sn ppm .01381 .00145 10.499 . 01 21,3 .01463. .01466 10.000 40.000 - .02000 - .50000 Si ppm 2.5870 . 01,7 4 . 67 t54 2.59s3 2 .567 0 2 .5987 P_ ppm 2 .328t .0072 .30782 2.3362 2.3254 2 .3227 40.000 - .04000 Pb ppm .01477 . 00 532 42 . BA2 . 021_7 6 .01309 .00945 Elem Ti Units ppm Avge .00144 SDev .00015 ?RSD 10.152 #r #z #: .00136 .00734 .00150 Errors LC Pass High 40.000 Low - .05000 Intstd 1 Mode Count s EIem Y Wavlen 371,. 03 0 Avge 24109 SDev 534.L5l-2 ?RSD 2 .21554 6 #r #z #: 23 493 24435 2440 0 LC Pass LC Pass 40 .000 40.000 - .10000 -1.0000 2 NOTUSED LC Pass LC Pass LC Pass 40.000 70.000 30.000 -.30000 -.00400 -.01000 34 NOTUSED NOTUSED s67 NOTUSED NOTUSED NOTUSED Appendix F 259 254 Analysis Report Method: TRA20505 Sample Name: HOHQX Run Time: 03/lo/06 18:a8:25 Comment : Mode : CONC Corr. Factor: 1 03/10/06 o6:24:35 PM Operator: Sb ppm .00477 .00034 7 .20 67 .00441, .00480 .00510 Co ppm .00791 .00033 4.1453 .00824 .00806 .00'760 K- ppm .56BBB .00799 4.4041 . 5'71,67 .57509 . ss987 V_ pprn .0060-7 .000s5 9.1873 .00528 .00649 .00544 LC Pass As ppm .00496 .0007L 1,4.368 .00479 .00s73 . 0 0 434 Cu ppm 4 .6815 .0183 .3907'7 4.6560 4 .67 69 4.-70L7 Ni ppm . 07 254 .00042 . 57 41,9 .07230 . 07302 .07230 Zn ppm 4 .9082 .0055 .13478 4.9009 4 .9\02 4 -9136 Ba ppm 1.3345 .0026 . 1 9l.21, 1.3315 1.3358 1.3361 Fe ppm 24 .97]-. . 04 B .19030 24.936 25 .025 24.953 Se /1 ppm . 01263 .00062 4 .9052 .01286 .01193 .01310 B- ppm .0s90s .00014 .23s93 . 05 92l. .05896 .05898 Be ppm . 0 0111 .00008 7 .622a . 0 0 1,1,-7 . 0 0101 .00774 LC Pass 10.000 - .00500 Pb/1, ppm .201,62 .00782 .90304 .20L7 0 .20340 .199-77 Se/z ppm - 0037L . 00 092 24 .7 63 .00375 .00277 .00461- Mo ppm .05788 .0002L .35995 .05764 .05799 .05800 LC Pass Cd ppm .07050 .0001,2 .15491 .07059 .07036 .07054 Pb /2 ppm .20464 .00205 1.0005 .20598 .2037 9 .20 3 15 0332s 03323 03267 Li ppm .00603 .00005 .84284 .00602 .00608 .00598 LC Pass page 1 Ca ppm 16.236 . 016 .09s89 16.228 15 .254 1,6 .226 Mg ppm 2 .7 827 .0131 .47196 2 .7 847 2.7948 2.7687 6 . 81,82 6.8704 5.7 555 Sr ppm .06151 .00028 .45890 .06130 .06741, .06183 LC Pass EI em A1 Units ppm Avge 187 .78 SDev .90 ?RSD .47 928 #r #z #: 187.03 1,87 - 52 188 .77 Errors LC Pass High 700.00 Low - .20000 EIem Cr Units ppm Avge .'113 42 SDev .00043 %RSD .37'7 7 5 #r #z #: . 1131,4 . 113 92 .11327 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge .37 7 31- SDev .00091 ?RSD .24233 #r #z #: 37746 37815 37 633 Errors LC Pass High 30.000 Low -.01500 Elem TI Units ppm Avge -.00752 SDev . 001 03 ?RSD 13 . 489 #r #z #: Errors - . 0 0643 - .00817 -.00826 LC Pass LC Pass LC Pass LC Pass 20.000 30.000 30.000 -.06000 -.01000 -.01000 LC Pass LC Pass 40.000 600.00 -.00s00 -s.0000 LC Pass LC Pass 100.00 50.000 - .05000 - .02500 LC Pass NOCHECK NOCHECK LC Pass 1400.0 700.00 -.10000 -s.0000 Ag Na ppm ppm .03305 6.8150 .00033 .0s70 .997 0t . 83 672 LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHBCK NOCHECK LC Pass LC Pass 4.0000 800.00 -.02000 -s.0000 LC Pass LC Pass Appendix F - 260 255 Analysis Report 03 / 1,0 / 05 o5 : 24:35 PM page 2 High 70.000 100.00 10.000 40.000 40.000 5.0000 10.000 Low -.02000 - .02500 -.02000 - .50000 - .04000 -.05000 -.05000 EIem ti Sn Si P Pb Se Units ppm ppm ppm pp* ppm ppm Avge .5932L .23436 1 - 0358 9.7338 .20402 .00698 SDev .00835 .00102 .0025 .0417 .00155 .00079 tRSD 1 .4084 .4340L .24300 .49037 .76347 11 .311 #1 .60205 .23330 1.0379 9.72s3 .20555 .00707 #2 .592L2 .23533 1.0330 9.7853 .20407 .0051s #3 . s8546 .2344s 1-,0364 9.6910 -20243 .00772 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass Hi-gh 40.OO0 40.O0O 40.OOO 40.000 70.O0o 30.000 Low -.05OOO -.1O0OO -1.OO0O -.3O0OO -.00400 -.01000 Intstd 1 Mode Counts EIem Y Wav1en 37!. 03 0 Avge 24340 SDev 101 .2966 ?RSD .4]-6a710 #r 2433a #z 24244 #3 24445 234557 NOTUSED NOTUSBD NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 261 256 o Analysis Report Method: TRA20505 Samp1e Name: H0HQ2 Run Time: 03/a0/06 18:24:39 CommenL : Mode: CONC Corr. Factor: 1 03/1,0/oG o6:30:48 PM Operator: page 1 Cd Ca ppm ppm -.00019 7.2952 . 00013 .0226 66 .933 1.7 451 EI em A1 Units ppm Avge .11783 SDev .00382 ?RSD 3.2409 #r #z #: .11411 .7277 4 . 117 65 Errors LC Pass High 700.00 Low - .20000 El em Cr Uni t. s ppm Avge .00438 SDev .00018 ?RSD 4.0753 #r #z #: 00443 00454 00419 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .00650 SDev . 00 067 ?RSD 10.232 #r #z #: .00573 .00681 .00695 Errors LC Pass High 30.000 Low - .01500 EIem TI Units ppm Avge -.00059 SDev .001,64 U RSD 277 . 82 #l- #z #: Errors -.00247 .000l-2 .00058 LC Pass Sb ppm .002L5 .00133 51.852 .00300 .00282 .00062 LC Pass 20.000 - .05000 Co ppm .0049l- .00020 4.1_383 .00574 .00479 .00479 LC Pass 100.00 - .0s000 K_ ppm .1,47 95 .00976 6 . 5 963 .1351 A .15296 . 15 478 LC Pass 200. 00 -s.0000 V_ ppm .00]-72 .00053 55 . 69s .001,73 . 0 0116 .00046 LC Pass As ppm .00720 .00072 s9.603 .00l-99 .00104 .00058 Cu ppm .046l-4 .001,66 3 . s950 . 04 422 .04'7 09 .04709 Ni ppm 30.360 .637 2 .0996 29 .624 30.723 30.733 Zn ppm .1s150 .00291 1. 9580 . 74 811 .15363 .15275 Ba ppm .008s0 .00029 3.3859 .00818 .00852 .00872 Fe ppm .40957 .00429 1.041 9 .40493 .4L3 3 9 .4L039 Se/t ppm .00277 .00728 46 .132 .004l-6 .00764 . 00 257 Be ppm . 00 ]-25 .00017 13.887 .00145 . 00 7:-4 .00116 Pb/t ppm .97s58 . 01501 1.5447 .95838 .9Bs9B . 9B 268 Se/2 ppm .00069 .00066 95.217 .00110 .00105 - .00007 Mo ppm .00184 .00024 12 .813 - 0021,o .00163 .00181 LC Pass 00009 00033 00014 Pb/2 ppm .957 49 .02361 2.4658 . 93 024 .97195 .97 021 Li ppm . 0 0 239 .00041 1,7 .362 .00193 .00249 .00274 LC Pass t .2693 1.3057 1.3107 LC Pass 500.00 -s.000Q Mg ppm .l.4058 .00154 1.0930 . 13 934 .1423 0 .14009 Sr ppm .00318 .00007 1 . 93 04 .00370 .00383 .00382 LC Pass LC Pass LC Pass 30.000 30.000 - .01000 - .01000 LC Pass LC Pass 10.000 40 .000 - .00500 - .00500 LC Pass LC Pass s0.000 1400.0 - .02500 - .10000 NOCHECK NOCHECK LC PasS 700.00 -5.0000 Ag Na ppm ppm -.00245 749.81 .00057 2.30 23.360 1.s361 00311 747.24 00208 1s0 .52 00216 151.68 LC Pass NOCHECK NOCHECK LC PASs LC PASS 100.00 4.0000 800.00 -.04000 -.02000 -s.0000 B- ppm 11 . 1a3 .292 2.4891 11.377 11.859 11 . 902 Pass LC Pass Appendix F - 262 LC 257 Analysis ReporL 03/10/06 o5:30:48 PM page 2 0000 10.000 05000 - .05000 Se ppm .00158 .00059 47 .254 .00243 .001s3 .00107' LC Pass 30.000 - .01000 67 NOTUSED NOTUSED EIem Ti Units ppm Avge .00990 SDev .00011 ?RSD 1.0929 High Low #r #z #: Errors High Low #r #z #: 70.000 -.02000 .00985 .01002 .00982 LC Pass 40.000 - .05000 257 A2 24845 24844 100.00 - .02500 Sn ppm . 01151 .000s0 4 .315 0 .01148 .01103 . 01 202 LC Pass 40.000 - .10000 2 10.000 - .02000 Si ppm .19680 .00660 3.3562 .18918 .20062 .20062 LC Pass 40.000 -1.0000 3 40.000 - .50000 P_ ppm .11788 .00554 4 .6984 .11168 . 11 956 .1,2232 LC Pass 40.000 - .30000 4 40.000 - .04000 Pb ppm .95395 .02071 2.1-488 .94008 . 97 -717 .97 468 LC Pass 70.000 -.00400 5Intstd 1 Mode Counts Elem Y Wavlen 37 l. 0 3 0 Avge 25L34 SDev 500.7606 ?RSD 1.992395 NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 263 258 Analysis ReporL Method: TRA20505 Samp1e Name: HOHP5P Run Time: 03/I0/06 18:30:51 Comment. : Mode: CONC Corr. Factor: 1 03/70/05 oG:37:oo PM Operator: Sb ppm .00084 .00090 106.8s .00]-81 .00021 .00037 Co ppm .o20sB .00039 1. BB75 .02702 .02040 .02031 LC Pass 100.00 - .0s000 K- ppm 3 -'7759 .0427 1.1315 3. B24B 3.7 455 3.7575 LC Pass 200.00 -5.0000 V- ppm .09030 - 0021,3 2 .3532 .09251 .0885'7 .08955 LC Pass As ppm .00305 .00]-44 47 .2L0 .00251, .00470 .00a97 Cu ppm . 0227 5 .00070 3 .0583 .02353 .02253 .02219 Ni pprn .03528 .00036 1.0138 .0355s .03s24 . 03 494 Zn ppm .15550 .002l-3 1 . 3 535 .1s895 .15511 . 15 544 Ba ppm .15161 .00168 1 . 1094 .15352 .1503s .1s09s Fe ppm 27 .426 .3l-7 1.1s53 27 .7 92 27 .232 27 .2s4 Se/t ppm .0031,4 .00325 103 .52 .00072 .00277 .00658 B_ ppm .02689 .00377 t4 .025 .03111 .0257 4 .02383 Be ppm .00696 .00007 1.0260 .00692 .00691, .00704 Pb/t ppm . 01L7 5 .00225 19.111 .00935 . 0121,0 .01380 Se/2 ppm .001s0 .00061 40 .532 .00189 .00181 .00080 Mo ppm .00133 .00035 26 .118 .00110 .00116 .001,72 LC Pass Cd ppm .00101 .00004 4.1464 .00100 .00105 .00098 Pb/2 ppm .01535 .002a6 1,4 - 097 Li ppm .02790 .00043 1.5497 .0284 0 . o2-7 5B . 027 62 LC Pass page 1 Ca ppm 77 .71-7 .797 1.1100 17 .944 t7 .508 t7 .600 Mg ppm 29.242 .350 1.1970 Sr ppm .06705 .00074 1.1033 .05791, .056s5 .05672 LC Pass Elem A1 Units ppm Avge 35.953 SDev .391 ?RSD 1.0867 #r #z #: 36.400 35.578 35.780 Errors LC Pass High 700.00 Low - .20000 EIem Cr Units ppm Avge .10578 SDev . 0 01,44 ?RSD 1.3s70 #r #z #: 10738 10s32 1,0 4 62 Brrors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge .38632 SDev .00481 ?RSD t .2449 #r #z #3 39188 38355 383s4 Errors LC Pass High 30.000 Low - .01500 EIem TI Units ppm Avge .00064 SDev .007L2 ?RSD ),75.t2 #r #z #: Errors - .00034 .00787 .00040 LC Pass LC Pass LC Pass 24.000 30.000 - .05000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00s00 LC Pass LC Pass 40.000 500.00 - .00s00 -5.0000 LC Pass LC Pass 50.000 1400.0 - .02500 - .10000 NOCHECK NOCHECK LC Pass 700.00 -5.0000 LC Pass NOCHECK NOCHECK 100.00 -.04000 01,7 49 29 .645 01539 29.056 01315 29.015 Ag Na ppm ppm - .00429 .19034 .00060 .05381 13 . 990 33 . 526 00354 .11670 00440 .22s00 00483 .22932 LC Pass LC Pass 4.0000 800.00 - .02000 -5.0000 LC Pass LC Pass Appendix F - 264 259 o Analysis Report 03/i,o/06 o5:37:oo PM page 2 High 70.000 100.00 10.000 40.000 40.000 5.0000 10.000 Low -.02000 -.02500 -.02000 -.50000 -.04000 -.05000 - .05000 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge .L5624 .00418 1.3776 5 - 8885 .01456 .00233 SDev .00225 . 00073 - 0190 . 0855 . 00071 . 00071 ?RSD a.446L 1,7 .366 a .3826 7 .4526 4 .8668 30 .431 #1 .15883 .00353 7.3934 5.9832 .0:525 .00158 #2 .L5470 .00500 7.3623 5.8555 .01-457 -OO242 #3 .15518 .00390 1.3591 s.8169 .01-384 .00300 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.0s000 -.10000 -1.0000 -.30000 -.00400 -.01-000 Intstd 1 Mode Counts Elem Y Wavlen 37L. 03 0 Avge 25484 SDev 359.8728 ?RSD L .41,2158 #r 2s081 #z 2ss 96 #: 2577 4 234561 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 265 260 Analysis Report QC Standard Method: TRA20505 Sample Name: CCV5 Run Time: 03/10/05 18:37:03 Comment : Mode: CONC Corr. Factor: 1 a3 /to /06 05 : 43 :12 PM OperatoF: page 1 Cd Ca ppm ppm .45488. 45.480 .00133 .a67 .29155 .36737 .45336 .45582 .45s46 45.312 45 .647 45.480 QC Pass QC Pass .50000 50.000 10.500 10.500 Pb/2 Mg ppm ppm .45385 Q44.51,7 .00464 .1,72 1.0222 .25127 .44961 Q44.390 . 4531,2 Q44. 5 0 0 .45881 Q44.562o EIem Al Units ppm Avge Q22.151 SDev .083 %RSD .37513 #r #z #: Q22. 13 3 Q22 .2ss Q22. 0 9s Errors QC Fail Value 25.000 Range 10.500 EIem Cr Units ppm Avge 1, .7 9 01 SDev .0035 ?RSD .196s0 #r #z #: Q1 . 7 B-77 1_.7947 Q1.7BB4 Sb ppm .45114 .00163 .351-94 .4s186 . 4523 0 .44928 QC Pass . s0000 10 - s00 Co Cu ppm ppm 1. B1B1 Q1 . -t584 .0071 .0053 .39097 .35550 1.8104 Q1 .7s67 1.8243 Q1.76s3 1.81,97 Q1 .7531 Ni ppm 1. B22t .0083 .45681 1.8729 1. B29t 1.8242 As Ba ppm ppm .45456 Q1 . '77 65 .002-78 .0051 .61253 .34059 .45134 Q1 . 7756 .45608 Q1.7829 .45625 Q1 . 77 09 QC Pass QC Fail .50000 2.o000 10.500 10.500 Fe ppm 22.570 . 04 5 .19815 22 .524 22 . 513 22 .57 4 QC Fail QC Pass 2.0000 25.000 10.500 10.500 Se/t ppm .45557 .0026]- .57350 .45289 .45811 . 45571- Be ppm 1.8425 .0053 .28860 1.8369 1.8474 1.8434 QC Pass 2.0000 10. s00 Pb/1- ppm .45355 .00224 .487 56 .45105 .45523 . 4543 9 se/2 ppm .447 84 .00363 .81091 .44403 .44823 .451,25 Ag ppm Q.BB27B . 0 0]-43 .161s0 Na ppm Q44. sB7 .249 .55"798 Errors QC Pass QC Pass Va1ue 2.0000 2-0000 Range 10.500 10.500 NOCHECK NOCHECK QC Fail s0.000 10.500 EIem Mn Units ppm Avge 1.8032 SDev .0054 ?RSD .2977 B #r #z #3 Errors QC Pass Va1ue 2.0000 Range 10.500 EIem TI Units ppm Avge .90898 SDev .00356 ?RSD .39205 #r #z #: Errors K- ppm Q42. s3B .237 .55705 a.79'7'7 Q42.554 1. B084 Q42.766 1. B03s Q42 .293 QC Fail s0.000 10.500 V_ ppm Q1.7B6B . oo47 .263 49 QC Pass NOCHBCK 2 .0 000 10 .500 Zn B- ppm ppm 1.8566 Q1 .151,2 .0079 .0088 .42565 .50439 1.8483 Q1.1428 1 . 8 640 Q1 .'7 604 1.8516 Q1.7503 QC Pass QC Fail Appendix F - 266 NOCHECK QC FaiI QC Fail 1.0000 50.000 10.500 10.500 Mo ppm 1.821,9 . oo92 .50572 8116 1.8007 8294 1. B03s B24B Q1.786B Q. B Bt91 Q44 .4l-5 Q. B 8442 44 .872 Q.BB194 Q44.473 Li Sr ppm ppm 7.79-70 7.1968 .0089 .0074 .49659 .4l_3 9 0 9054s Q1.7833 90890 7.792L 912s8 Q1.7B4B 1 1 1 7 .'7 977 1. B0s3 !.'7934 QC Pass(o QC Pass QC FaiI QC Pass QC Pass 261 Analysis Report QC Standard 03/70/a6 o5:43:72 PM page 2 Value 1.0000 2.0000 2.0000 2.0000 2.0000 2.0000 2.0000 R.ange 10.500 10.500 10.500 10.500 10.500 10.500 l-0.500 EIem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge 1,-8622 1.8L50 Q1 .7801- 2.0078 .4s417 -45072 SDev .0058 .0058 .0045 .0044 .00362 .00305 ?RSD .31161 .31802 .25L87 .22049 .79790 .67744 #1 1.8575 1.8083 Q7.7751 2.0030 .45058 Q.44727 #2 l- .8587 1. B1?9 Ql .7837 2 . 0118 .4541-1 .45181 #3 1.8501 1.8187 'Q1 .781s 2.OOB4 .45783 .4s30'7 Errors QC Pass QC Pass QC Fail QC Pass QC Pass QC Pass Value 2 .0000 2 .0000 2 . 0000 2 .0000 .50000 .50000 Range l-0.500 10.500 10.500 10.500 10.500 10.500 Int S t.d 1 Mode Counts Elem Y Wavlen 37L. 03 0 Avge 24394 SDev 63 .49224 ?RSD .26027 82 #r 24451, #z 24385 #3 2433s 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 267 262 Ana1ys i s .Report Method: TRA20505 Sample Name: CCB5 Run Time: 03/70/oa 18:43:15 Comment : Mode : CONC Corr. Fact.or: 1 03/1,0/05 06:49:24 PM Operator: page 1 Cd Ca ppm ppm - .00015 .00620 .00008 .00080 52.773 l.2.855 00008 .00698 00024 .00624 00013 .00538 EIem AI Units ppm Avge - .03197 SDev .00237 ?RSD 7 .403 B Sb ppm .00036 .00l.25 351. 84 .00045 .00a5'7 - .00095 As ppm .00007 .00030 411 .11 - .00008 - . 0 001,2 . 0 0 042 LC Pass LC Pass .01400 .00330 -.01400 - .00330 Co Cu pprn ppm .00003 H.00926 .00028 .00033 938.75 3.s523 .00007 H.009s1 .00029 H.00939 - . 0 0427 H. 00889 K- ppm .05387 .00326 5.0497 .05020 .05643 . 0s 498 Ni ppm - .00059 .00085 743. 9B .00017 - .00150 - .00043 V- ppm .00016 .00032 205 .32 - .00015 .00050 .000L2 LC Pass Zn ppm .00052 .00015 28.766 .00069 . 0 0 047 . 0 0 04 0 #r #z #: 03091 03033 03468 Errors LC Pass High .10s00 Low - .10500 Elem Cr Units ppm Avge - .00038 SDev .00016 ?RSD 42 .5 B 3 #r #z #: -.00022 -.00039 - .00054 Errors LC Pass High .00350 Low - .00360 EIem Mn Units ppm Avge .00054 SDev .00014 ?RSD 25.588 #r #z #3 00070 00044 00048 Errors LC Pass High .00180 Low - .00180 EIem TI Units ppm Avge .00732 SDev .00155 ?RSD tt7 .25 #r #z #: Errors .00094 .00302 - .00000 LC Pass Ba ppm - .00017 .00004 23 .423 00015 00015 00021 LC Pass .00150 - .00150 Fe ppm .005ss .00455 82 .06'7 .00158 .01052 .00455 Se/t ppm .00131 .00206 757.90 .00369 .0001,2 .00011 B- ppm . 00 42L .00087 20.672 .00519 .00389 .00354 Be ppm .00133 .00005 4.3966 .00132 .00727 .00139 Pb/1, ppm - .00405 .00433 106.97 .00000 -.00862 - .00354 Se/2 ppm .00103 .00101 98.266 .0016s - .00014 .00as7 Mo ppm .00222 .00052 23 .436 .00280 .00205 .00181 LC Pass Pb /2 ppm .00223 .00156 69 .902 .00085 .00392 .00L92 Ag ppm - .00205 .00040 19 . 491, -.00251 - .00187 -.00L7-7 Li ppm .00119 .00023 19. 676 .00742 .00720 .00095 LC Pass Mg ppm .001s9 .00109 5 B . 642 .00070 .00280 .00725 Na ppm -.33352 .09541 28.906 - .23825 - .431,02 - .33L29 Sr ppm .00000 .00001 1566.2 .00000 .00001 - .00001 LC Pass LC Pass LC Pass LC Pass .00180 .00082 .05500 -.00180 -.00082 -.05s00 LC Pass LC High LC Pass .00220 .00700 .04900 -.00220 -.00700 -.04900 NOCHECK NOCHECK LC Pass .04900 - .04900 LC Pass LC Pass .32200 .00380 - .32200 - .00380 NOCHECK NOCHECK LC Pass LC Pass .00970 L.4730 -.00970 -1.4130 o LC Pass LC Pass Appendix F - 268 263 Analysis Report High Low .01000 - .01000 .00500 - .00s00 Sn ppm .000s4 .00037 5B . 596 .00082 .00072 .00059 LC Pass .00770 -.00770 z NOTUSED .00380 - .00380 Si ppm -.02047 .00266 13 . 014 01825 0].91 4 023 43 .00880 - .00880 Pb ppm .00062 .00041 66.aa2 .00105 .00023 .000s8 .00270 - .00270 Se ppm .00742 .00L2L 85.390 .00265 .00023 .00l-37 page 2 .00130 -.00130 03/10/05 o5:49:24 PM EIem Ti Uni t.s ppm Avge .00054 SDev .00055 %RSD 101 .35 #r #z #: 0 0118 0002s 00020 Errors LC Pass High .00160 Low - .00160 IntSLd 1 Mode Counts EIem Y Wav1en 371,.030 Avge 247 85 SDev 1,42 .8295 ?RSD .57 52833 #r #z #: 24972 2463 0 248L7 .03100 - .03100 P_ ppm .00318 .00140 43.93s .00797 .00471- .00287 LC Pass tC Pass .05500 .02100 - .05s00 - .02100 34 NOTUSED NOTUSED LC Pass LC Pass .00370 .00430 - .00370 - .00430 5 NOTUSED 67 NOTUSED NOTUSED Appendix F - 269 264 Analys i- s Report Method: TRA20505 Samp1e Name: H0HQ6 Run Time : 03 / 70 / 06 18 : 49 :28 Comment : Mode: CONC Corr. Factor: 1 03/70/06 o6:55:35 PM Operator: Sb ppm .00025 .00260 L025.2 - .00119 .00326 - .00131 Co ppm .00736 .00018 2.3896 .00726 .00756 .00726 LC Pass 100.00 - .05000 K- ppm .07339 .001,71 2 .3259 . 0715 0 .07500 .o'7356 LC Pass 200.00 -5.0000 V- ppm .00075 . 00 067 89.398 .00013 .001,46 .00056 LC Pass As ppm .00066 .00050 75.977 .00052 . 0 01,21 .00024 Cu ppm .041,07 .00053 1_ .2967 .04048 .041,52 . o 4124 Ni ppm .00706 .0003s 4.9305 .00722 .00730 .00656 Zn ppm .02543 .00013 .49233 .02528 .02548 .02551 Ba ppm .00256 .00013 5.1982 .002s3 .00274 .00245 LC Pass 30.000 - .01000 Fe ppm .05732 .00s33 7 . 9151 .06954 . 07118 .061"24 Se/t pprn .01109 .00782 1,6 .428 .01319 .01003 .01004 B_ ppm .00694 .00027 3.862L .0071,6 .00703 .00654 Be ppm .00].20 .00008 5 .63A7 .00l.l-2 .00721, .00].28 LC Pass 10.000 - .00s00 Pb/ 1 ppm .72502 .003s9 2.8583 . a2912 . L23s2 . a2244 Se/z ppm .01000 - 0 0L45 1,4 - 542 .00884 .009s2 .01163 Mo ppm .00430 .000s5 13 .0s3 .00476 .00361 . 00 446 LC Pass Cd ppm .004s2 .0001_2 22 .574 .00054 .00051 .00040 Pb/2 ppm .1,2865 .00277 2.4502 .12546 . 13 047 .13000 Ag ppm . 13 29s .00025 .18'779 .13308 . 13 266 .13311 Li ppm .00070 .00005 7 .8343 .00061 .00076 .00067 LC Pass page 1 Ca ppm .05583 .00266 4.6'729 .0s851 .05810 .05378 Mg ppm .01034 .00347 33.602 .00734 . 01 445 .00954 Na ppm - .19445 .14398 74.045 - .03249 - .24293 -.30793 Sr ppm .00030 .00002 7.7434 .00029 .00033 .00029 LC Pass EI em A1 Units ppm Avge .20448 SDev .00203 ?RSD .99334 #r #z #: .20542 .20464 .20237 Errors LC Pass High 700.00 Low -.20000 Elem Cr Units ppm Avge . 013 54 SDev .00006 ?RSD .45969 #r #z #: 01351 01348 01354 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .00380 SDev .00059 ?RSD 15.580 #r #z #: 00425 00403 00313 Errors LC Pass High 30.000 Low .01500 Elem T1 Units ppm Avge - .00005 SDev .00267 %RSD 529l- .4 #r #z #: Errors -.00203 .00299 - .00111 LC Pass LC Pass LC Pass 20 .000 30.000 - .06000 - .01000 LC Pass LC Pass 40.000 600.00 -.00s00 -s.0000 LC Pass LC Pass s0.000 1400.0 - .02500 - .10000 NOCHECK NOCHECK LC Pass 700.00 -5.0000 LC Pass NOCHECK NOCHECK 100.00 - .04000 LC Pass LC Pass 4.0000 800.00 - .02000 -s.0000 LC Pass LC Pass Appendix F - 270 265 Analysis Report 03/70/06 o6:55:36 PM 5.0000 - .05000 Se ppm .01064 .00071 6 .6344 .01057 .00998 .01138 page 2 10.000 - .05000 67 NOTUSED NOTUSED High Low 70.000 - .02000 100.00 - .02500 Sn ppm 1.1183 .0014 .12592 1 . 1A57 1.1188 1.11-94 10.000 - .02000 Si ppm 7.7574 .0095 .54002 l.-l 484 1,.-7 565 1.7673 40.000 - . s0000 P_ ppm .82839 .00379 . 457 35 .83275 .82589 I i-.82654 40.000 -.04000 Pb ppm .721 86 .0008s .66118 .12696 .1,2854 .1,27 97 Elem Ti Uni t. s ppm Avge .02L75 SDev . 00 082 ?RSD 3 .'7871 #r #z #: .02269 .02135 .02119 Errors LC Pass High 40 .0 0 0 Low - .05000 Intstd 1 Mode Counts EIem Y Wavlen 371. 03 0 Avge 247 98 SDev 44.55332 ?RSD .1,796669 #r #z #: 248a6 247 47 2483 0 LC Pass LC Pass 40.000 40.000 - .10000 -1.0000 2 NOTUSED LC Pass LC Pass LC Pass 40.000 70.000 30.000 -.30000 -.00400 -.01000 345 NOTUSED NOTUSED NOTUSED Appendix F 271 256 Analysis Report Method: TRA20505 Samp1e Name: H0HRG Run Time: 03/10/06 18:55:40 Comment : Mode: CONC Corr. Factor: 1 03/L0/06 o7:01:49 PM Operator: page 1 Cd Ca ppm ppm - .00020 .1,4426 .00007 .00570 3s.259 3.9s03 Elem Cr Units ppm Avge -.00047 SDev .00033 ?RSD 71, .5 51 Elem AI Units ppm Avge .11503 SDev .00550 ?RSD 4 .7 3'7 0 #r #z #: Errors High Low . 11 432 . L22aB .11159 LC Pass 700.00 - .20000 #r #z #: 00009 00058 00073 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge .00256 SDev .00105 ?RSD 4t .1 0 6 #r #z #: .00271, .00376 .00181 Errors LC Pass High 30.000 Low -.01500 EIem T1 Units ppm Avge .00742 SDev .00390 ?RSD 2-73.51 #r #z #: Errors -.00305 .00325 .00407 LC Pass Sb ppm . 00 0l-7 .000s7 328.34 - .00045 .00035 .00053 LC Pass 20.000 - .05000 Co ppm - .00033 .00034 101 . 62 00072 00011 00016 LC Pass 100.00 - .0s000 K- ppm .798s3 . 01202 1.5049 .79456 . B 1203 .78900 V- ppm - .00063 .00081 130 .22 - .00157 -.00014 - .00017 LC Pass As ppm .00024 .00086 353 .33 -.00072 .00093 .00052 LC Pass 30.000 - .01000 Cu ppm .013s9 .00259 19.033 .01188 .01657 .01232 Ni ppm .00090 .00024 25 .443 .00777 .00080 .00073 Zn ppm .00352 .00071 20 .14 5 .00327 .00432 .00297 Ba ppm .00200 .00048 23.908 .00l.65 .00255 .00180 LC Pass 30.000 - .01000 Fe ppm .061,72 .00958 15.834 .05095 . 07 022 .05220 Se/t ppm .00345 .00255 13.870 .00610 .00101 .00324 B- ppm .00757 .000s1 5 . s 946 .00877 - 007L6 .00757 Be ppm .00a07 .00003 2.2855 .00109 .00105 .00109 LC Pass 10.000 - .00500 Pb/1, ppm - .00151 .00588 389.28 .00406 -.00767 - .00093 Se/2 ppm .00138 .001,94 140. B6 - .00086 .0026]- .00238 Mo ppm .00153 .0002s 1,5 .522 .00180 .00148 .00130 LC Pass - .00013 - .00028 - .00020 LC Pass 40.000 - .00500 Pb/2 ppm . 0 01,92 .00272 L4L .22 - .00059 .00481 .00155 Li ppm .00625 .00031 s.0060 .00s89 .00646 .00639 LC Pass ]-4073 15084 74a22 LC Pass 500.00 -5.0000 Mg ppm .05865 .00348 5 .9302 .05578 .0625r .05765 Sr ppm .00076 .00007 9 .7 41,6 .00069 .00084 .0007s LC Pass LC Pass LC Pass 50.000 1400.0 - .02s00 - .10000 NOCHECK NOCHECK LC Pass 700.00 -s.0000 LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHECK NOCHECK Ag Na ppm ppm -.0039s 135.31 .00033 1,.28 B .2 903 .94232 00385 135.1,2 00359 136 .75 00432 L34 .24 LC Pass LC Pass 4.0000 800.00 - .02000 -5.0000 LC Pass LC Pass Appendix F - 272 267 Analysis Report 03/1,0/06 o-t:01:49 PM page 2 10.000 - .0s000 High Low 70.000 - .02000 100.00 - .02500 Sn ppm .01323 .00058 4 .3869 . 013'7 5 .01250 . 0133 4 10.000 -.02000 Si ppm 28.850 .27 9 .96818 28 .649 29.L77 28 .755 Elem Ti Units ppm Avge .00505 SDev .00024 ?RSD 4.-7222 #r #z #:' 00496 00532 00487 Errors LC Pass High 40 .0 0 0 Low - .05000 Int.St,d 1 Mode Count. s Elem 'Y Wavlen 37 L. 0 3 0 Avge 24859 SDev 148.7791 ?RSD .5984889 #r #z #3 249 63 24689 2492 6 LC Pass LC Pass 40 .000 40.000 - .10000 -1.0000 2 NOTUSED LC Pass LC Pass 40.000 70 - 000 - .30000 - .00400 345 NOTUSED NOTUSED NOTUSED P_ ppm .15358 .00351 2.2062 .75427 .75697 . 1s 982 Pb ppm . 0 01,25 .0001,7 13 .254 .00]-44 .007L4 . 0 0 1,1,7 40.000 40.000 - .50000 - .04000 s.0000 -.05000 Se ppm . 00 235 .00051 25 .1 62 .00l_74 .00236 .00295 LC Pass 30.000 - .01000 67 NOTUSED NOTUSED Appendix F - 273 268 Analysis Report Method: TRA20505 Sample Name: H0HRT Run Time: 03/t0/06 19:o1,:52 Comment : Mode: CONC Corr. Factor: 1 03/to/os o't:oB:01 pM Operator: EIem AI Uni t. s ppm Avge 1.5541 SDev .0117 ?RSD .7 0642 #r #z #: 1.5646 1_.64 15 4.6553 Errors LC Pass High 700.00 Low - .20000 EIem Cr Uni t. s ppm Avge .00257 SDev .00041 ?RSD 15.l-59 #r #z #: .0021,7 .00247 .00295 Errors LC Pass High 100.00 Low - .01000 Elem Mn UniLs ppm Avge .02163 SDev .00038 ?RSD 7.7550 #r #z #3 02l.45 02l-31 02207 Errors LC Pass High 30.000 Low - - 01500 LC Pass LC Pass 20.000 30.000 -.06000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00500 page 1 Cd Ca ppm ppm -.00011 32.027 .00009 .306 76.366 .9s423 00012 32.180 obozo 31.668 00003 32.274 LC Pass LC Pass 40 .000 600.00 - .00500 -5.0000 Elem Units Avge SDev ?RSD #r #z #: Errors T1 ppm - .0015s .004s6 277.08 -.00590 .00135 .00060 LC Pass Sb ppm .05947 .00307 4 .4226 .05814 .06729 . 07 299 Co ppm .00057 .00019 34.134 .000s9 .00037 .00076 K- ppm .82233 .01329 1.6159 .83311 .80748 .82647 V- ppm .00101 - 00033 32 .620 .00098 .00069 .00135 LC Pass As ppm . 0 019-l .00070 35.381 .00204 . 0 01,25 .00264 Cu ppm .06924 .00158 2 .27 53 .05847 .06820 . 0710 5 Ni ppm .00194 .00008 4.1_680 .00197 .001,84 .00l_99 Zn ppm .11566 . 0 0110 .947tB . 1157 2 .11454 .11613 Ba ppm .02427 .00013 .52440 .02424 .02407 .02431 Fe ppm .93833 .00857 .91324 .9390s .92942 . 9 4652 Se/1 ppm .00'772 .00111 1-4 .320 .00798 .00868 .006s1 B- ppm .0232s .0010s 4 .531,7 .02292 .02239 .02442 Be ppm .00119 .00010 8.3801 . 0 01,27 .00722 .00108 Pb/t ppm .00025 .000s6 228. 13 .00030 .00a77 - .00034 Se/2 ppm .00133 .007s4 115.95 - .00043 .0020]- .00242 Mo ppm .00257 .00031 72.239 .00223 .00260 .00286 LC Pass Pb/2 ppm .00685 .00029 4.2300 .007a9 .00666 .00612 -.00424 - .00486 - .0040s Li ppm . 0 0237 .00005 2.1,643 .00226 .00235 .00232 LC Pass Mg ppm 1.0979 .0098 .89478 1.1015 1.0858 1.1054 LC Pass 700.00 -s.0000 6 - 65L1 6.s796 6.7 585 Sr ppm . 05 659 .00045 .79804 .05688 .0560'7 .05682 LC Pass LC Pass LC Pass 100.00 s0.000 - .05000 - .02s00 LC Pass NOCHECK NOCHECK 14 0 0 . 0 - .10000 Ag Na ppm ppm -.00438 6.6533 .00043 .0900 9 .1097 1.3508 LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHECK NOCHECK LC Pass LC Pass 4.0000 800.00 -.02000 -5.0000 LC Pass LC Pass Appendix F - 274 269 Analysis Report 03/aa/06 o7:oB:01 PM page 2 5.0000 10.000 - .0s000 - .05000 Se ppm .00375 .0009s 25.288 .00269 .00450 .00406' LC Pass 30.000 - .01000 67 NOTUSED NOTUSED High Low 70.000 - .02000 100.00 - .02500 Sn ppm .01s15 .00040 2 .6545 .01ss8 .01478 . 01 51,2 LC Pass 40.000 - .10000 10.000 - .02000 Si ppm .9874'7 .05784 5.8703 1.0639 .96422 . g:431 LC Pass 40.000 -1.0000 40.000 - . s0000 P_ ppm 2.0910 .0022 .10494 2.0884 2 .0922 2 .0923 LC Pass 40.000 - .30000 40.000 -.04000 Pb ppm .0050s .00032 5.3522 .00529 .005L7 .00469 LC Pass 10.000 - .00400 EIem Ti Unit s ppm Avge .11689 SDev .00247 ?RSD 2.7111 #r #z #: 719-/ 2 11518 1757 7 Errors LC Pass High 40.000 Low -.05000 Intstd 1 Mode Counts Elem Y Wav1en 377. 03 0 Avge 2514'7 SDev 182.2283 ?RSD .7 24643 0 #r #z #: 2514'7 2s330 249 55 23 NOTUSED NOTUSED 45 NOTUSED NOTUSED Appendix 275 270 Analysis Report Method: TRA20505 Sample Name: HOPF3L Run Time: o3/ao/05 19:08:05 Comment : Mode : CONC Corr. Fact.or : 1 03/to/06 o7:14:13 PM OperatoL: Sb ppm .44021 .00279 .53359 .44263 .44083 . 43'716 Co ppm .09015 .00103 1.14-13 .08938 .09133 .0897s K- ppm 42.332 .256 .50493 42 .460 42.500 42.038 V- ppm .17 911 .00188 1.0487 .17 B 11 . 18 1,28 .a7-794 As ppm .08933 .00105 1.1754 .08989 .0BBt2 .08998 Cu ppm .22693 .00096 .42094 .22622 .22801 .226s5 Ni ppm . 4517 I .00346 -'7 6687 .44915 .45565 .45031 Zn ppm . 49 044 .00263 .53678 .48935 . 493 44 .48852 Ba ppm .08847 .00040 . 449 44 .08864 .08877 .08802 Fe ppm . 917 67 .01398 1.5240 .90688 .93343 .91252 Se/t ppm .127 9 0 .00079 . 61,87 4 .72881 . L27 43 .127 +5 B_ ppm . B328B .00510 .6L199 .8331,2 .83786 . 827 67 Be ppm . 04 6 B 9 .00026 .55483 . 04 6 6 B .0471,8 .04680 Pb/ 7 ppm .08463 .00119 1,.4084 .08542 .08521, .08326 Se/2 ppm .1,2841 .00346 2 .6962 .725 0 B . 13 200 .L2B3s Mo ppm .45333 .00464 1.0224 . 449 53 .45853 .45183 LC Pass Cd ppm .04539 .00036 .80189 .04519 .04581 . 04 51-7 Pb/ 2 ppm .09257 .00773 1 . B 684 .0906s .09394 .09325 .04098 .04223 .04105 Lt_ ppm .093s3 .000s7 .60691, .09391 .09380 .09288 LC Pass page 1 Ca ppm 45 .66A . 3 04 .66553 45 .498 46 .011 45 .413 Mg ppm 8.6358 .07 B6 . 91046 B . 5 987 B .7 261, 8.5826 43 :467 43 .7 4A 43.22L Sr ppm .45l.69 .00153 .339]-4 .45161 .45327 .4502L LC Pass EIem Al Uni t. s ppm Avge 1 .7 037 SDev .0111 ?RSD .5s415 #r #z #g 1.7 048 L .7 l-43 1.6921, Errors LC Pass High 2.4098 Low 1.5902 Elem Cr Units ppm Avge .L777 0 SDev . 0 01,37 ?RSD .77 404 #r #z #: 1,7 7 42 1,7 920 t] 649 Errors LC Pass High .24098 Low . 15 902 EIem Mn Units ppm Avge .09108 SDev .00077 ?RSD .B40B3 #r #z #: 09075 09196 09054 Errors LC Pass High .72049 Low .07 951 Elem TI Units ppm Avge . 3 51,6'7 SDev .00264 ?RSD . -7 2984 #r #z #: Errors .35875 .35388 .3 623 9 LC Pass LC Pass .60245 .L2049 .39755 .01951 LC Pass LC Pass .1,2049 .05024 .07951 .03976 LC Pass LC Pass .06024 60.245 .03976 39.'755 LC Pass LC Pass ..12049 .301-23 .01951 .1987'7 LC Pass NOCHECK 1, .2049 .7 9 510 NOCHECK LC Pass 1,2 .049 7.9510 Ag Na ppm ppm .04L42 43 .477 .00071 .260 1.7 014 .59809 NOCHECK LC Pass .50245 .3 97 s5 NOCHBCK NOCHECK LC Pass LC Pass . 06 024 60 . 245 .03976 39.755 LC Pass NOCHECK Appendix F - 276 LC Pass NOCHECK 27L Analysis Report High .481-96 Low 31804 IntStd 1 Mode Counts EIem Y Wav1en 371,.030 Avge 24397 SDev 168 .5733 ?RSD .69 13 5 B3 #r 24418 #z 2421,9 #: 24554 .50245 .397ss 03/L0/06 o't:14:13 PM page 2 .50245 .1,2049 .60245 .39755 .07 9s1 .39755 Elem Ti Sn si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge .09399 .4661,5 L.7597o 4.8479 .09040 .12858 SDev .00062 .00371 .02193 .0156 .00100 .00209 ?RSD .65679 .79542 2.8864 .34333 1.1043 1,.6244 #1 .09392 .46274 L.781-2'7 4.8s23 .08940 .1-2661- #2 .09464 .47009 L.16041 4. B51B .09140 .1-3077 #3' .09341 .46s61- L.73743 4 -8294 .09041 .L2837 Errors LC Pass LC Pass LC Low NOCHECK LC Pass LC Pass High .72049 .5024s 5.024s Low .07951 .39755 3.9755 . .12049 . 1B 07 4 .47951 .11926 234567 NOTUSED NOTUSBD NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 277 272 Analysis Report Method: TRA20505 Sample Name: H0HF4Z70 Run Time: 03/L0/06 19::-4:L'7 Comment : Mode: CONC Corr. Factor: 1 03/\o/06 o't:20:26 PM Operator: Sb ppm .00203 .00097 47 .932 .00254 .00253 .00091 Co ppm .00034 .000]-7 49.835 .00031 .00052 .00019 LC Pass 100.00 - .05000 K- ppm . 13 463 .00877 5 . 51,-7 0 .727 4L .14439 . 13 208 LC Pass 200.00 -5.0000 V_ ppm .00030 ,00044 744 .62 .00033 .00073 - .00015 LC Pass As ppm .00101 .00084 82.875 .00198 .00057 .00049 Cu ppm .03795 .00095 2.5408 .03684 .03835 . 03 864 Ni ppm .00223 .0001,7 7.4755 .0023s .00204 .00230 LC Pass 100.00 -.04000 Zn ppm t.2915 .0175 1.3573 1, . 271,4 1.3036 1-.2995 Ba ppm . .00398 .00011 2 .7 696 .00388 .00396 .00409 Be ppm .00424 .0001,2 9.4805 .00138 .00720 .00116 Pb/t ppm .0205s .0000s .248 9 5 .02071 .02050 .02065 Se/2 pprn .00164 .00077 47 .3 15 .00074 .00206 .002l.0 Mo ppm .00088 .00027 30.627 . 0 0101 . 0 01,07 .00057 LC Pass Cd ppm .00004 .00007 181 .77 Pb/2 ppm . 026 6s .00004 .15301 . 026 62 .02653 .02569 Li ppm .00051 .00003 5 .67 46 .00064 .00053 .000s7 LC Pass page 1 Ca ppm 1.0186 .0121 1 . 1907 Mg ppm .09289 .00125 1.3511 .09226 .09433 .09207 Sr ppm .00944 .00009 . 917 44 .00934 .00949 .009s0 LC Pass EIem A1 Units ppm Avge . 15 5L7 SDev .00315 ?RSD 1.9098 #r #z #: .16161 .15631 .16-1 60 Errors LC Pass High 700.00 Low -.20000 Elem Cr Units ppm Avge . 01 027 SDev .00011 ?RSD 1 . 10'71- #r #z #: .01040 . 01 02a . 01 020 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .00349 SDev .00019 ?RSD 5.3736 #r #z #g 00336 00340 00370 Errors LC Pass High 30.000 Low - .01500 Elem TI Units ppm Avge .00097 SDev .00108 ?RSD 111 . 65 #r #z #s Errors -.00027 .00744 .001,73 LC Pass LC Pass LC Pass 20 .000 30.000 - .05000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00500 .00010 . 1.0050 .0000s 1.0282 -.00004 1.0227 LC Pass LC Pass 40 .000 600.00 -.00s00 -5.0000 LC Pass LC Pass s0.000 1400.0 - .02500 .10000 NOCHECK NOCHECK LC Pass 700.00 -5.0000 Fe ppm .06315 .00358 5.6542 .06661, .0634]- .05947 Se/t ppm - .000s0 .00119 238.74 .00088 - .00115 -.00723 B_ ppm .00746 .00023 3 .1398 .00769 .00748 .00722 NOCHECK NOCHECK Ag Na ppm ppm -.00427 .16202 .00078 ,o'7654 18.313 47.304 - .00498 .2l-21,6 - .00343 .20011 -.00439 .07 380 LC Pass LC Pass 4.0000 800.00 - .02000 -5.0000 LC Pass LC Pass Appendix F - 278 273 Analysis Report High Low 70.000 - .02000 100.00 - .02500 Sn ppm .00358 .00007 2 .0257 .00360 .00373 .00372 10.000 - .02000 Si ppm .7 6440 .00s91 .7 7 297 .76533 .7 597 9 .Tsrioe 40.000 - .50000 P- ppm 1.5359 .0181 1 . 1810 1.5L54 1.5497 1.5426 LC Pass 40.000 - .30000 40.000 - . 04 0 0 0 Pb ppm .02501 .00003 . 10 832 .02500 . 0249 9 .02504 5.0000 - .05000 Se ppm . 0 01,20 .0001,2 10.155 .00106 .00a27 . 0 01,2-7 page 2 10.000 - .0s000 03 / ao / 05 o-t :20 :26 PM EIem Ti Units ppm Avge .00053 SDev .00003 ?RSD 5.0738 #r #z #: .00452 .000s5 .00052 Errors LC Pass High 40.000 Low - .05000 IntSLd 1 Mode Counts EIem Y Wav1en 37 7. 03 0 Avge 25287 SDev 3 13 .5029 %RSD I .240]-7 4 #r #z #: 2564l. 25045 251,7 5 LC Pass LC Pass 40 .000 40.000 - .10000 -1.0000 2 NOTUSED 34 NOTUSED NOTUSED LC Pass LC Pass 70.000 30.000 - .00400 - .01000 5 NOTUSED 67 NOTUSED NOTUSED Appendix F - 279 274 Analysis Report Method: TRA20505 Sample Name: H0A1eZ2O Run Time: o3/ta/0G 19:20:30 Comment: Mode: CONC Corr. Factor: 1 03/10/AG 07:25:38 PM Operator: page 1 Cd Ca ppm ppm - . 00007 .02334 .00013 .0001 4 169.42 3.1803 Elem AI Units ppm Avge .32506 SDev .00695 ?RSD 2.7392 #r #z #r 3329 6 32235 31987 Errors LC Pass High 700.00 Low - .20000 EIem Cr Units ppm Avge .00033 SDev .00055 ?RSD 195. 85 #r #z #: .00103 -.00026 .00023 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge . 00 052 SDev .00031 ?RSD 59.5s1 #r #z #: OOOBB 00035 00033 Errors LC Pass High 30.000 Low -.01500 EI em T1 Units ppm Avge .00057 SDev .00135 ?RSD 235. s6 #r #z #: Errors - .00020 - . 0 0021, .0021,2 LC Pass Sb ppm 1.5402 .0043 .28152 1.5395 1 . s362 1.5448 LC Pass 20.000 - .06000 Co ppm .000s5 .00083 151.90 .001s0 .00015 - .00001 LC Pass 100.00 -.0s000 K- ppm . 117 82 .01090 9 .2499 .13 022 .11343 .10980 LC Pass 200.00 -5.0000 V- ppm .00040 .00150 397. s9 .0021,4 - .00102 .00010 LC Pass As ppm . 0 0151 .00061 40.060 .00220 . 0 0]-29 .0010s Cu ppm . 01017 .00067 5 . s854 .01094 .0091 0 .00989 LC Pass s0.000 - .02500 Ni ppm - .00012 .0007s 605 .14 .00073 - .00038 - . 0 0072 Zn ppm . 03 275 .00002 .059'/B . 03 2t3 . 03 275 .03271 Ba ppm - .00001 .00016 \522 . B .00018 - .00012 - .00009 Fe ppm .02226 .01598 76.279 . 04 046 .00684 .01948 Se/t ppm -.00040 . 0 01,27 301 .52 - . 0 01,47 - .00064 .00091 B_ ppm .001,77 . 0 0113 66.234 .00302 . 0 0]-02 .00110 Be ppm .00123 .00010 7 . 6128 .00113 . 0 01,24 .00]-32 Pb/ 7 ppm .00583 .00]-29 18.819 .00752 .00-754 .00s35 Se/z ppm .00065 .0008s t29 .62 .0008s .00140 -.00027 Mo ppm .00076 .00025 32 .829 .00104 .00057 .00055 LC Pass .00007 - .00013 - .00017 Pb/2 ppm .01254 .00071, 5.5090 .01183 .01372 .01291 NOCHECK Ag ppm -.00204 - 00094 46.148 Li ppm .00035 .000]-2 32 .941 .00049 .00031 .00027 LC Pass 0241,5 02318 0225 9 Mg ppm .005s5 .00461, 82 .996 .01049 .00138 .00478 LC Pass 700.00 -5.0000 Na ppm -.00928 .27333 2946 . s Sr ppm .00004 .0000s 124 . 82 .00011 .00000 .00002 LC Pass LC Pass LC Pass 30.000 30.000 - .01000 - .01000 LC Pass LC Pass LC Pass 10.000 40.000 500.00 -.00500 -.00500 -5.0000 LC Pass NOCHECK 1400.0 - .10000 LC Pass NOCHECK NOCHECK 100.00 -.04000 - .00099 .30634 -.00232 -.16549 -.00282 -.16768 LC Pass LC Pass 4.0000 800.00 - .02000 -5.0000 LC Pass LC Pass Appendix F - 280 275 Analysis Report High Low 70.000 - .02000 100.00 - .02500 Sn ppm .02090 .00]-77 8.1875 .02287 .01980 .02003 10.000 - .02000 Si ppm 1 . 3 696 .0095 . 6 9205 1.3759 1.3742 1.3587 40.000 - .50000 P_ ppm .04s48 .00187 4 . L].99 .04600 .047 04 .04340 LC Pass 40.000 - .30000 40.000 - .04000 Pb ppm . 01111 .00048 4.3296 .01083 .01t66 .01083 5.0000 - .05000 Se ppm .0005s .00031 47 .67 B .000s5 .00100 .00040 page 2 10.000 - .05000 03 / t0 / 05 07 -.26 :38 PM EIem Ti Units ppm Avge .11154 SDev .00004 ?RSD .03958 #r #z #3 11155 11149 1115 7 Errors LC Pass High 40.000 Low - .05000 Intst.d 1 Mode Counts Elem Y Wavl en 371,. 0 3 0 Avge 2501-7 SDev :.42 .4455 zRSD . s6 9394s #r #z #g 24858 25032 25A57 LC Pass LC Pass 40.000 40 .000 - .10000 -1.0000 z NOTUSED LC Pass LC Pass 70.000 30.000 - .00400 - .01000 345 NOTUSED NOTUSBD NOTUSED 61 NOTUSED NOTUSED o Appendix F - 281 276 Analysis Report Method: TRA20505 Sample Name : H0A1R Run Time: 03/70/oa 19:26:42 Comment : Mode: CONC Corr. Factor: 1 03 /10 / 06 o't :32 :57 PM Operator: Sb ppm .01067 . 0 01,29 72.055 .00974 .012]-4 . 01014 Co ppm .00746 .00015 11.087 .00737 .0015s . 0 01,37 K- ppm . 11615 .00139 1.1944 .11586 .11704 .11455 V_ ppm .00153 .00060 39.246 .00090 .001s9 .0021,0 LC Pass As ppm .00140 .00074 s2.9BB .00070 .00131 .002L8 Cu ppm . 0 4407 .00013 .30277 . 04 41,3 .04392 . o441,7 Ni ppm .0062l. .00048 -1.'7 519 .00591 .00s90 .00676 Zn ppm .11087 . 0 0 046 .4L364 .11139 .11051 . 11 071 Ba ppm .009ss .00002 .22344 .00953 - 0095'7 .0095s Fe ppm 1.2739 .0067 .52392 L.2815 L.2590 L - 271,2 Se/r ppm .00098 .00150 ]-64. 0 0 - .00082 .00226 .00150 B_ ppm .00344 .00026 7 .5059 .00335 .00324 .00373 Be ppm .00138 .00002 1, . 6697 .00138 .00140 .001,36 Pb/1, ppm . 0 0aB4 .00743 77 .585 .00098 .00105 .00348 Se/z ppm .00133 .00093 7 0 .042 .00027 .00158 .00203 Mo ppm .0018s .0000s 2 .4629 .00189 .00180 .00186 LC Pass Cd ppm .00020 .00010 49 .557 .00013 .00015 .00032 Pb/2 ppm .00913 .00054 5.5263 .01029 .00968 .00922 Ag ppm - .00178 .00008 4 .2293 Li ppm .00370 .00002 .54915 .00312 .00370 .00358 LC Pass page 1 Ca ppm .43 053 .00150 .34896 .43202 .42901 .43057 Mg ppm .1s440 .00078 .50289 . 15 524 .1537]. . 15 425 Na ppm - .18564 .20911 712 .64 Sr ppm .00]-95 .00001 . 53 5t2 .00195 .00195 .00L97 LC Pass E}em AI Units ppm Avge .17922 SDev .00315 %RSD t.7 633 #r #z #: 17732 t8286 1,7746 Errors LC Pass High 700.00 Low -.20000 Elem Cr Units ppm Avge . 0033 9 SDev .00004 ?RSD 1.154a #r #z #: 00335 00343 00339 Errors LC Pass High 100.00 Low - .01000 E1em Mn Units ppm Avge .01260 SDev .00004 %RSD .31s95 #r #z #: . 0126]- .01256 .01264 Errors LC Pass High 30.000 Low -.01500 EIem T1 Units ppm Avge -.00030 SDev .00139 ?RSD 455 .44 #t- #z #: Errors - .00141 -.00075 .00l.25 LC Pass LC Pass LC Pass 20.000 30.000 - .06000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00500 LC Pass LC Pass 40.000 500.00 - .00500 -5.0000 LC Pass LC Pass 100.00 s0.000 - .05000 - .02s00 LC Pass NOCHBCK 1400.0 - .10000 NOCHECK LC Pass 700.00 -s.0000 - .00187 - .37257 -.001"74 - .22455 -.00173 .04019 LC Pass LC Pass 200.00 100.00 -s.0000 - .04000 NOCHECK NOCHECK LC Pass LC Pass 4.0000 800.00 -.02000 -5.0000 LC Pass LC Pass Appendix F - 282 277 Analysis Report 03 / aa / 06 o7 :32 :57 PM page 2 High 70.000 100.00 10.000 40.000 40.000 s.0000 10.000 Low -.02000 -.02500 - .02000 - . s0000 -.04000 - .05000 - .0s000 Elem Ti Sn Si P Pb Se Units ppm ppm ppm pp* ppm ppm Avge .02869 .01025 .24954 .07236 .00740 .00149 SDev -OOO27 .OOO77 .00454 . OO1O3 -OOO24 .00113 ?RSD .93752 7 .4798 1. 8l-86 1.4225 3.2402 7s. sB3 #r .02896 .00937 .2s469 .07301 .00147 .00019 #2 .02843 .0105s .2477q .07290 .00713 .0021s #3 .02868 .01073 .246L4 .071L7 .00759 .00213 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low - .05000 -.10000 -1.0000 -.30000 - .00400 - .01000 O Intstd 1 Mode Counts Elem Y Wav1en 371. 03 0 Avge 25421 SDev 58. 09741, ?RSD .232l.990 #r 249s9 #z 25029 #3 2sO7 4 234557 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 283 278 Analysis Report Method : TRA2 05 0 5 Sample Name : H0A1W Run Time: o3/:-0/06 19:32:55 Comment : Mode: CONC Corr. Factor: 1 03/:_0/06 07:39:03 PM OperatoL: page 1 Cd ppm .00254 .00015 6.021,8 .00271, .00242 .00250 Ca ppm 1.90l.2 .0157 .82608 1. B9B9 1. B867 1.9l-79 Pb/ 2 ppm .08540 .0021,3 2 .4979 .08318 .08560 .08742 Mg ppm .28802 .00581 2 .0153 .284 11 .28527 .29469 Ag Na ppm ppm -.00200 38.462 .00070 .231, 34.877 .59966 -.00193 38.60'7 -.002"73 38.195 -.00134 38.584 LC Pass LC Pass 4.0000 800.00 -.02000 -5.0000 Li ppm .0195s .00020 1.0003 .01947 .01940 . 01 917 LC Pass Sr ppm .00827 .00006 .1755s .00822 .00826 .00834 LC Pass EIem AI Uni t. s ppm Avge . 55 45L SDev .00410 ?RSD .7 4011 #r #z #: .55a46 .55290 .55918 Errors LC Pass High 700.00 Low - .20000 Elem Cr Units ppm Avge .00447 SDev .00049 ?RSD 10.896 #r #z #: 00419 00418 00503 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .0521-8 SDev .00056 ?RSD 1.0792 #r #z #: 0577 4 05797 05281 Errors LC Pass High 30.000 Low -.01500 El-em TI Units ppm Avge .00160 SDev .00220 ?RSD 737 .24 #r #z #: Errors . 0 0142 - .000s0 . oo3B9 LC Pass Sb ppm .02652 .00188 7.4744 .02456 .02569 .02830 LC Pass 20.000 - .06000 Co ppm .00315 .00027 8.6302 . 0 03a2 .00289 .00343 K- ppm .46827 .00937 2.0000 .46804 .45901 .4'7774 LC Pass 200.00 -5.0000 V- ppm .000s5 .00061 111 . 28 .00004 .00038 .00l-22 LC Pass As ppm .00806 .00051 5.3118 .00781 .00864 .00772 Cu ppm . 16 s82 .00185 1.1204 .75401 .15573 .1,6772 Ni ppm .00318 .00067 20 .9l-4 .00392 .00263 .00301 Zn ppm 1.1445 .0058 .50841 l_43 4 t3 92 1507 Ba ppm .20894 .00130 .62156 .207 84 .20862 .2]-037 Fe ppm 1.6768 .0148 .88337 1.6750 7 .6629 1.6924 Se/t ppm .00485 .00776 35.399 .00585 .00418 .00351 B- ppm . 07 92s .00085 1 . 0 617 .07990 .07 829 .07 956 Be ppm .00L07 .00001 1.0942 .00105 .00108 .00to7 LC Pass 10.000 - .00500 Pb/L ppm .08429 .00323 3 .830s .08797 .081,94 .08296 Se/2 ppm .00067 .00156 232. 3 5 - .00021 .00248 - .00025 NOCHECK Mo ppm .00915 .00054 5.928s .00873 .00895 .00976 LC Pass LC Pass LC Pass 30.000 30.000 - .01000 - .01000 LC Pass LC Pass 40.000 600.00 - .00s00 -s.0000 LC Pass LC Pass 100.00 50.000 - .0s000 - .02500 LC Pass NOCHECK NOCHECK LC Pass 1400.0 700.00 - .10000 -5.0000 LC Pass NOCHECK 100.00 -.04000 1 1 1 o Pass LC Pass Appendix F - 284 LC 279 Analysis Report 03 / to / o6 0'7 :39:03 PM page 2 5.0000 10.000 - .0s000 - .0s000 Se ppm .0023s . 0 01,02 43 .494 .00242 .00333 .00129 7 NOTUSED High Low 70.000 - .02000 100.00 - .02s00 Sn ppm . 013 52 .00081 5.9245 .01455 .01309 .01323 10.000 - .02000 Si ppm .18933 .0039s .50081 .18730 .78679 .79388 40.000 - . s0000 P- ppm 5.0s09 .0262 . 5 1 91,'l 5.035-7 5.03s9 5.081-2 40.000 -.04000 Pb ppm .08s35 .00076 .89575 .08s05 .08478 .08622 Elem Ti Uni t, s ppm Avge . 03 61,9 SDev . 00 042 ?RSD 1.1626 #r #z #3 . 03 6s4 . 03 572 . 03 529 Errors LC Pass High 40.000 Low - .05000 Int,Std 1 Mode Counts Elem Y WavI en 371. 0 3 0 Avge 246L9 SDev 151 - 7318 ?RSD .6L5345g #r #z #: 24669 247 37 24447 LC Pass LC Pass 40.000 40.000 -.10000 -1.0000 NOTUSED NOTUSED LC Pass LC Pass LC Pass 40.000 70.000 30.000 -.30000 -.00400 -.01000 4 NOTUSED NOTUSED NOTUSED O Appendix F - 28s 280 Analysis Report Method: TRA20505 Samp1e Name: H0A11 Run Time: 03/to/06 19:39:07 Comment : Ittlode : CONC Corr. Factor: 1 03 / 70 / oa o7 :45 :16 PM Operat.or: page 1 Cd Ca ppm ppm -.00002 .04635 .00005 .00115 278.21, 2.482L 00002 00000 .00008 04s57 047 69 0 4571, Pb/2 ppm .0021,2 .00065 30.729 .00138 .00237 .00262 Mg ppm .00649 .00305 47 .221, .00860 .00788 .00297 Ag Na ppm ppm -.00552 .09s34 .00035 .16L42 6 .4923 769. 3 1 -.00517 .26940 - . 00550 . 06 502 -.00588 -.04941 LC Pass LC Pass 4.0000 800.00 -.02000 -s.0000 Li ppm .00031 .00007 2t. B3B .00028 .00038 .00026 LC Pass Sr ppm .00008 .00002 25 .692 .00007 .00010 .00006 LC Pass EIem Al Units ppm A-vge - .03111 SDev .00702 ?RSD 3.2580 #r #z #: - .03049 -.03055 - .03228 Errors LC Pass High 700.00 Low -.20000 Elem Cr Units ppm Avge -.00045 SDev 00032 %RSD 71.058 #r #z #: 00057 00009 00059 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .00138 SDev .00031 ?RSD 22.756 #r #z #: 00111 o 01,"7 2 00130 Errors LC Pass High 30.000 Low - .01500 EIem TI Uni t.s ppm Avge . 00 024 SDev .00775 ?RSD 779 .7 4 #r #z #: Errors -.00172 .0015s .00080 LC Pass LC Pass LC Pass 20.000 30.000 - .05000 - .01000 Sb ppm - .00068 .00113 167 . 05 - .00181 - .00058 .00046 Co ppm .00004 .00077 403.07 .00019 .00008 - .00014 K- ppm .0219s .00433 19.723 .02539 .02338 .01709 LC Pass 200.00 -5.0000 V_ ppm .00018 .00041 237.03 .00053 .00a26 -.00027 LC Pass As ppm .00065 . 0 0]-23 189.72 .00068 .00186 - .00060 Cu ppm .75359 .0072a .15988 .7 5221, .7 541,5 .7 5442 Ni ppm .00010 .00030 290.91 .0000s -.00017 . 0 0 043 Zn ppm .40550 .00090 .22136 .40632 . 4 0 460 .40588 Ba ppm .00135 .00019 74.362 .00119 .00757 .00l.29 LC Pass 30.000 - .01000 Fe ppm .04s55 .00721, 1s . 829 .04396 .05344 . 03 928 Se/t ppm .00159 .00155 97 .807 .00307 - .00003 .00L73 B- ppm .00737 .00050 36 .286 .00191 .00729 .00092 Be pprn .00098 .00007 7 .0659 .00090 .00100 .00104 Pb/1- ppm -.00279 .00055 23 .423 0 0228 0 0256 00353 Se/2 ppm .000'7t .00036 5 0 . 1,57' .00051 .00049 .00172 NOCHECK Mo ppm .00047 .00019 39.892 .00046 .00065 .00029 LC Pass LC Pass LC Pass LC Pass 10.000 40.000 500.00 -.00500 -.00500 -5.0000 LC Pass LC Pass 100.00 50.000 - .05000 - .02500 LC Pass NOCHECK NOCHECK LC Pass 1400.0 700.00 - .10000 s.0000 LC Pass NOCHECK 100.00 - .04000 LC Pass LC Pass Appendix F - 286 28a Analysis Report a3 / rc / 06 o1 :45:L5 PM page 2 High 70.000 100.00 10.000 40.000 40.000 s.0000 10.000 Low -.02000 -.02s00 -.02000 -.50000 -.04000 -.0s000 -.0s000 EIem Ti- Sn Si P_ Pb se Units ppm ppm ppm ppm ppm ppm Avge .00102 .01155 .00205 .01106 .00083 .00131 SDev .00005 .0019s .001,72 .00230 .00034 .00058 ?RSD 4.9873 76.776 83.845 20.'766 40.6L7 44.s42 #1 .00102 .01309 .00357 .01201 .00044 .00168 #2 .00107 .01-244 .00239 -01-272 .00100 .00054 #: .00097 .00942 . oooL8 ' .00844 .00104 . 00160 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.05000 -.10000 -1.0000 -.30000 -.00400 - .01000 Int.Std 1 Mode Counts Elem Y Wavlen 377. 03 0 Avge 25247 SDev 116 .4549 ?RSD 4573 04 1 #r 2s133 #z 25247 #: 25366 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 287 I 282 Analysis Report Method: TRA20505 Sample Name: HOA12 Run Time: o3/10/oG 19:45:20 Comment: Mode: CONC Corr. Factor: 1 03 / 70 / 06 07 :51 :28 pM Operator: EIem Al Uni t. s ppm Avge 1.2875 SDev .0058 ?RSD .52665 #r #z #: 7 .2954 1.2834 1.2839 Errors LC Pass High 700.00 Low -.20000 EIem Cr Uni t. s ppm Avge .01136 SDev .00085 ?RSD 7 .6720 #r #z #: 01053 0113 1 01225 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge .2OBB1 SDev .00l-29 %RSD .61 643 #r #z #: 21030 20798 20Bl'7 Errors LC Pass High 30.000 Low - .01500 EI em TI Uni t, s ppm Avge . 00 A46 SDev .00004 ?RSD 8.1235 #r #z #: Errors .00041 .00047 .00049 LC Pass LC Pass LC Pass 20 .000 30.000 - .06000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00s00 Be ppm .001,02 . 00 0l-2 11.311 . 0 0 1,1,4 .00101 .00091 Pb/7 ppm - .00118 .00378 319.51 - .00554 .00101 .00098 Pb/ 2 ppm .00514 .0024'7 4B .0 91 .00788 .00308 . 0 0 446 Se/z ppm .00037 .00096 2s7. 93 .001,46 - .00002 - .00033 NOCHECK LC Pass 4.0000 -.02000 page 1 Cd Ca ppm ppm - .00009 30.057 .00021 .1,96 228 . t2 . 55 332 -.00026 30.260 - .00015 29.857 .00014 30.045 LC Pass LC Pass 40.000 600.00 - .00500 -5.0000 LC Pass LC Pass 100.00 50.000 - .05000 - .02500 Sb ppm -.00503 .00239 47 .452 00247 00709 00s61 Co ppm . 0 01,44 .00016 10.963 .00l.25 .00153 .001s3 K_ ppm 51.60s .206 .39901 51. 834 51.545 51. 436 LC Pass 200. 0 0 -5.0000 V_ ppm .00374 .00037 9.9426 .00402 .00331 .00388 LC Pass As ppm .00284 .00025 B . 6 999 .00311 .00263 .00278 Cu ppm . 04 942 .00040 . B1BB1 .44981 .04944 .04900 Ni ppm .00455 .00027 5.90l-2 .00425 .00454 .00477 Zn ppm .3 45-7 9 .00184 .53192 .34-762 .34394 .34581 Ba ppm 2.4035 .00'72 .30050 2 .4114 2 .4023 2 .397 2 Fe ppm 2 .81-20 .0193 .58590 2 .8329 2.7948 2.8084 Se/t ppm .00648 .00239 35.872 .00410 . 0 0 647 . OOBBB B_ ppm . 03 292 .00053 1, .6237 .03246 . 03 280 .03351 Pass LC Pass Appendix F - 288 Mo ppm . 0 01,42 .00010 7.0511 .00130 .00148 .00748 LC Pass Li ppm .00495 .00004 .74438 .00497 .00498 .00491 LC Pass Mg ppm s.8930 .0453 .76848 s . 93 9B 5 . B 494 s. BB99 LC Pass 800.00 -5.0000 Sr ppm .08420 .00039 . 4627 4 .08464 .08389 .08408 LC Pass LC Pass NOCHECK NOCHECK LC Pass 1400.0 700.00 - .10000 -s.0000 Ag Na ppm ppm -.00598 .23276 .00048 .29BBB 8.0061 l-28.40 - .00545 - .09900 -.00637 .31532 -.00614 .4809-7 LC Pass NOCHECK 100.00 -.04000 LC 283 Analysis Report High Low 70.000 - .02000 100.00 - .02500 Sn ppm .01434 .00130 9.0745 .01307 .01428 .01567 10.000 - .02000 Si ppm r .2208 .0077 .6315s I .2267 7 .2l.2t 1, .2237 40.000 - .50000 P- ppm 5.5511 .0147 .26436 5.5681 5.5432 5.5421, 40.000 - .04000 Pb ppm .00346 .00058 1,6 - 815 .00381 .00279 .00378 PM s.0000 - .05000 Se ppm .00268 .00030 11 . 20a .00262 .00242 .00301 03/to/06 o7:51 page 2 10.000 - .0s000 El em Ti Units ppm Avge . 05 07 5 SDev . 00 046 %RSD .7 621,6 #r #z #s ,06070 .05033 .05].25 Errors LC Pass High 40 .0 0 0 Low - .05000 Intstd 1 Mode Counts EIem Y Wavlen 371,.030 Avge 25L1,5 SDev 131.1550 ?RSD .5222207 #r #z #: 2497 7 25238 251,29 LC Pass LC Pass 40.000 40.000 - .10000 -1.0000 LC Pass LC 40.000 70 - .30000 Pass LC Pass .000 30.000 00400 - .01000 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 289 284 Analysis Report QC Standard Method: TRA20505 Sample Name: CCV6 Run Time: 03/a0/06 19:51,:32 Comment : Mode : CONC Corr - Factor: 1 03 /a0 / 06 o7 :5't :40 PM Operator: As Ba ppm ppm .4s1 93 Q1 . 7 826 .00069 .0095 .15284 .53589 .4513 1 Q1 . 77 4t .4s180 Q1.7B0B .45267 7 .7 93 0 22 .404 Q22 .32s 22.570 Be ppm 1.8327 .00s0 .27305 1.8308 1. B28B 1.8383 QC Fail QC Pass 2.0000 2.0000 10.500 10.500 Fe Pb/ ! ppm ppm 22 .433 .44954 .t2s .00s32 .55740 1.1838 Cd ppm Q.447A6 .00341, .7 6282 Q.44s70 Q.44472 .45105 Qc Fail . s0000 10.500 Pb/2 ppm .45244 .00223 .49359 .45111 .45119 .45502 NOCHECK Ag ppm Q.B7B1B .0034s .39307 Q.47702 Q.B1s4s Q. B 8206 Li ppm 1. B06s .0030 .16435 1.8031 1 . B 077 1. B0B5 QC Pass page 1 Ca ppm 45. s68 . 131 .28 B 14 45.505 45 .422 45 .677 QC Pass s0.000 10.500 Mg ppm Q44 .064 .2a1 .47870 Q44 Q43 Q44 085 843 264 QC Fail s0.000 10.500 Na ppm 44. BB5 .273 .41399 Q44 .7 45 44.783 45.131 QC Pass 50.000 10. s00 Sr ppm 1. B15B .0117 .64534 1.8059 1. Bt2B 1. B2B1 QC Pass Elem AI Uni t. s ppm Avge Q22.1-77 SDev .1-67 ?RSD .75252 #r #z #: Q22 .027 Q22 .l_42 Q22.351 Errors QC Fail Val-ue 25 .0 0 0 Range 10.500 EIem Cr Units ppm Avge Q1 . 7 7'7 B SDev .0105 ?RSD .s9634 #r #z #: Q1.7789 Q1 . 7 65'7 Q1 .7878 Errors QC Fail Value 2.0000 Range 10.500 EIem Mn Units ppm Avge Ql.7860 SDev .0140 ?RSD .'783 10 #r #z #: Errors QC Fail Value 2.0000 Range 10.500 EIem TI Units ppm Avge .91267 SDev .00535 ?RSD . s8509 QC Pass QC Pass . s0000 . s0000 10.500 10.500 Co Cu ppm ppm 1.BOs7 Q1.7629 . 0173 .0t32 .95'782 .75035 1.7976 Q1 .7s07 1, .7 940 Q1 . 7 609 1. B2s5 Q1.7769 Sb ppm .45518 - 001,45 .32181 .4567 B .45390 .45485 QC Pass 2.0000 10. s00 K- ppm Q42.980 .208 .48308 Qc Fail 50.000 10.500 V- ppm Q1 .-/876 0084 . 47 220 QC Fail 2.0000 10 .500 Ni ppm 1.BOt4 .0148 .82133 7.-7956 1.1904 1.BtB2 Zn ppm 1.8484 .007-l .4]-558 se/t ppm .45343 .00494 1.0895 .45BBB .44925 .452]-'7 B_ ppm Q1 .70s1 .0141 . 829 02 .45565 .44588 . 44'7 L0 Se/2 ppm .44100 .00281 .5s020 .43801 .44726 . 443'7 3 Mo ppm 1.8749 .0148 .81422 QC Pass QC Pass NOCHECK 2s.000 10.500 Q1 . 7 874 Q42 .7 84 Q1 . 77 49 Q42 .9s9 1 . 8 0l.7 Q43 .l.97 QC Pass NOCHECK NOCHECK QC Fail 2.0000 1.0000 10.500 10.500 #r #z #: Errors 91884 Q1.7846 90941 Q1 .7811 90975 1,.7971 8446 Q1.6918 1.8044 8434 Q1 .7036 1.8084 8573 Q1.7200 1.8318 1 1 1 QC Pass QC Fail Appendix F - 290 QC Pass QC Fail 28s Analysis Report QC Standard 03 / to / 06 01 -.57 :40 PM page 2 Value 1-.0000 2.0000 2.0000 2.0000 2.0000 2.0000 2.0000 Range 10.500 10 .500 10 .500 10 .500 10.500 10.500 10 .500 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge 1.8530 1.8020 Q1.7755 1.9208 .45175 Q.4454L SDev . 0099 .0023 . 0145 . 0128 . 00165 . 00132 ?RSD .53496 .13002 .81-789 .55518 .36748 .29686 #l- 1.8461 1 .8019 QL -7656 L -91-47 .45274 Q.44527 #2 1.848s L.7997 QL-7689 .L.gt22 .44s83 Q.44420 #3 1.8543 1.8043 1-.7922 1.9355 .45267 Q.44682 Errors QC Pass QC Pass QC Fail QC Pass QC Pass QC Fail Value 2.0000 2.0000 2.0000 2.0000 .50000 .50000 Range 10.500 10.500 10.500 10.500 10.500 10.500 Intstd 1 Mode Counts EIem Y Wavlen 37 7. 0 3 0 Avge 24591 SDev 155.3580 ?RSD .63L7 551 #r 24472 #z 2468s #: 2457 B 23455'/ NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 291 286 Analysis Report Method: TRA20505 Samp1e Name: CCB6 Run Time: 03/I0/06 19:57:44 Comment : Mode: CONC Corr. Factor: 1 03/to/06 o8:03:53 PM Operatolr: page 1 Cd Ca ppm ppm -.00014 .00754 .00008 .00044 s3 .081 5.6986 EIem AI Units ppm Avge - .04760 SDev .00723 ?RSD 2. s919 As ppm .001,26 .001s8 l-24.83 .00026 .00045 .00308 LC Pass .00330 -.00330 Cu ppm H.00918 .00024 2 .6252 Ni ppm - .000s3 .00033 62 .7 Bs 00049 OOOBB 00022 LC Pass .00380 -.00380 Zn ppm - .00002 .00003 1-29. 55 00005 00000 00001 #r #z #: - .04709 - .0457L - .04901 Errors LC Pass High .10s00 Low - .10500 Elem Cr Units ppm Avge -.00012 SDev .00037 ?RSD 301.78 #r #z #g .00011 - .00055 .00007 Errors LC Pass High .00350 Low -.00360 EIem Mn Units ppm Avge . 00 032 SDev .00001 ?RSD 4 . Os44 #r #z #: 00034 00031 00031 Errors LC Pass High .00180 Low -.00180 EIem TI Uni t, s ppm Avge .00287 SDev .00148 ?RSD 51. 642 #r #z #: Errors .00447 .00154 .00260 LC Pass . 00007 H. 0 0892 -.00009 H.00924 -.00010 H.00939 LC Pass LC High .00220 .00700 -.00220 -.00700 LC Pass NOCHECK .04900 -.04900 NOCHECK LC Pass .o4900 - .04900 Sb ppm - .00095 .00131 135. B6 - .00196 .00052 - .00143 LC Pass .01400 - .01400 Co pprn - .00004 .00010 250 .25 K- ppm .04551 .00816 \7 .928 .047L3 . 03 567 .05274 LC Pass .32200 -.32200 V- ppm - .00039 .00022 56. LB2 - .00059 - .00043 - .00015 LC Pass Ba ppm - .00020 .00004 1,7 - 535 00024 00020 00017 LC Pass .00150 - .00160 Fe ppm -.00234 .00493 21,0.50 - .0036s - .00648 .00311 Se /t ppm . 0 01,72 .00a7L 152 .57 - .00054 .00L22 .00279 B_ ppm .00184 .0002l. 11 . 203 - 001,94 .00161 .00198 Be ppm .001,32 .00004 2.7 035 .00t29 .00131 .00136 LC Pass .00180 - .00180 Pb/7 ppm -.002L3 .00090 42 .77 2 00315 00150 00173 Se/z ppm - .00053 .00101 1e0.07 .00061 - .00091 -.00729 Mo ppm .00782 .00046 25.140 . 00 233 .00168 .0014s LC Pass 00023 00012 00008 LC Pass .00082 - .00082 Pb/2 ppm .00073 .00078 106 .05 .00L5'7 .00002 .00051 Ag ppm -.00290 .00072 24 .817 0 0293 00361 0 02]-7 Li ppm .00098 .00019 18.983 .00119 .00092 .00083 LC Pass .00750 .00722 .00809 LC Pass .05500 - .05s00 Mg ppm - .00035 .00080 226. 15 - .00058 - .00095 .00055 Na ppm -.33002 .09195 29 .682 -.40158 -.35991 -.21840 Sr ppm - .00002 .00001 85.'/98 - .00001 - .00003 - .00000 LC Pass NOCHECK NOCHECK LC Pass LC Pass .00970 1,.4730 -.00910 -1.4730 Pass LC Pass Appendix F - 292 LC 287 Analysis Report 03/L0/06 oB:03:53 PM page 2 High .01000 .00s00 .00380 .03100 .00880 .00270 .00130 Low - .01000 -.00500 -.00380 -.03100 - .00880 - .00270 -.00130 Elem Ti- Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge .00007 .00067 - .01538 -.00145 .00023 .00031 SDev .00012 .00091 .00251 .00093 .00029 .00018 tRSD 165.35 135.78 15.691 64.4sL 123.98 58.091 #1 -.00000 .001-45 -.07374 -.00042 .00047 .00048 #2 .00001 -.00033 - .01653 - .oo224 -.00009 .00012 #3 :00021 .00088 - .01888 -.00159 .00031- .0003s Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High .00150 .0o77o . 05500 .02100 . 00370 . 00430 Low - .001-60 - .OO77O -.05500 -.02100 -.00370 -.00430 Intstd 1 Mode Counts EIem Y Wavlen 377. 03 0 Avge 250L4 SDev 103.1015 %RSD .4t21,681 #r 24s2s #z 25L29 #s 2498s 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 293 288 Analysis Report Method: TRA20505 Sample Name: H0A13 Run Time: 03 /70 / 06 2o:03 :57 Comment : Mode: CONC Corr. Factor: 1 03/70/a6 oB:10:06 PM OperaLor: Sb ppm .00263 .00243 92 .4 01 .00385 .00479 - .00017 Co ppm .00262 .00041 1s.541 .00288 .00283 .0021"5 LC Pass 100.00 - .05000 K- ppm L.44BB .0051 .35199 L .4449 1, . 4459 1, .4545 LC Pass 200.00 -5.0000 V_ ppm -.00026 .00073 285 .1,4 .0001,2 .0002l. -.00110 LC Pass As ppm .01053 .00105 9 .9697 . 0 1l-25 . 01l.02 .00933 Cu ppm .00978 .00022 2 .2165 .00993 .00988 .009s3 LC Pass 50.000 -.02500 Ni ppm .07334 .00024 . 3 3 239 .07362 . 01 324 . 07 3l-7 Zn ppm .09279 .00427 .2B9sB .09298 . 0 9248 .09294 Ba ppm . 017l-0 .00003 .18067 .0171,7 . 011L2 .01106 Fe ppm .39309 . 0 01,32 .33505 .39335 .39425 .39l.66 Se/1 ppm .0071-2 .00118 105.46 .00240 .00006 .00091 B- ppm .07930 .00038 .483s9 . 07 959 .0'7887 .0'7 945 Be ppm .00104 .00003 3 .3503 .00104 .00100 .00107 Pb/1, ppm .00592 .00198 33.498 .00805 .00414 .00556 Se/z ppm .00007 .00097 1392.0 - .00005 .00110 - .00084 Mo ppm .01809 .00045 2 . 5111 .01824 .01846 . 01158 LC Pass Cd ppm .00001 .00003 328 .54 Pb/2 ppm .00583 .00105 15. sl2 .00550 .00802 .00597 00330 00283 o 0269 Li ppm .00437 .00007 1.5706 .00424 .0043L .00437 LC Pass page 1 Ca ppm .27336 .00025 . 0 9l-37 Mg ppm .147 9 0 . 0 01,82 I .231'7 .147 58 ,a4986 . L4525 5 .2867 5 .2417 5.09]-4 Sr ppm .00239 .000a2 .7 0t6 5 .00240 .00240 .00237 LC Pass Elem AI Units ppm Avge .07 3 55 SDev .00423 ?RSD s .7 467 #r #z #: 07 228 07 828 07013 Errors LC Pass High 700.00 Low -.20000 EIem Cr Unit s ppm Avge .00697 SDev .00020 ?RSD 2.9160 #r #z #: 00720 00685 00585 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .01390 SDev .00008 %RSD .60424 #r #z #: 01390 01382 01398 Errors LC Pass Hlgh 30.000 Low - .01500 Elem TI Unit s ppm Avge -.0021-5 SDev .00431 ?RSD 200. 05 #r #z #: Errors -.00694 -.00092 . 0 01,41, LC Pass LC Pass LC Pass 20.000 30.000 - .05000 - . 01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00500 - .00000 .2731,0 .0000s .27 339 - .00002 .27 360 LC Pass LC Pass 40.000 500.00 - .00500 -s.0000 LC Pass NOCHECK 1400.0 - .10000 NOCHECK LC Pass 700.00 -5.0000 Ag Na ppm ppm -.00294 s.2066 .00032 .7022 10.901 1.9637 LC Pass NOCHECK NOCHECK 100.00 -.04000 LC Pass LC Pass 4.0000 800.00 - .02000 -s.0000 LC Pass LC Pass Appendix F - 294 289 Analysis Report 03/70/06 oB:10:05 PM page 2 High 70.000 l-00.00 10.000 40.000 40.000 s.0000 10.000 Low -.02000 -.02500 - .02000 -.50000 -.04000 -.05000 - .05000 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge .03552 -1,4442 .09955 1.3149 .00701 .0OO72 SDev .00039 .00098 .00313 .0037 .00062 .00060 tRSD 1.0870 .580ss 3.143s .279s3 8.7946 83.8s1 #1 .03552 -14s46 .L0277 1 .3145 . O07sO . OO10s #2 .03585 .143s1 .09968 1.3188 .0072L .00107 #3 .03510 .1-4429 .096s1 l-.311s .00632 .00002 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.05000 -.10000 -1.0000 -.30000 -.00400 -.01-000 fntstd 1 Mode Counts Elern Y Wav1en 377.030 Avge 24855 SDev 29 .21592 ?RSD .1175453 #r 24BBs #z 24827 #3 248s2 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 29s 290 Analysis Report Method: TRA20505 Samp1e Name: H0A14 ,.Run Time: 03/ao/06 20:10:09 Comment : Mode : CONC Corr. Fact.or: 1 03/to/06 0B:1G:18 PM Operator: page 1 Cd Ca ppm ppm -.00008 .04s99 .00002 .00036 25 . 1,25 .7 87 62 EIem Al Units ppm Avge - .03969 SDev . 00 634 ?RSD 15 . 9'7 5 #r #z #3 -.04689 - .03493 - .03726 Errors LC Pass High 700.00 Low -.20000 Elem Cr Units ppm Avge .00036 SDev .00082 ?RSD 228.25 #r #z #3 .00109 - .000s2 .00051 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .00153 SDev .00014 ?RSD 9 .2820 #r #z #: .00746 .00159 .00l-43 Errors LC Pass High 30.000 Low - .01500 EIem Tl UniLs ppm Avge .00011 SDev .00075 ?RSD 695. 0 9 #r #z #: Errors - .00020 -.00044 .00096 LC Pass LC Pass LC Pass 20.000 30.000 - .05000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00500 LC Pass LC Pass 40.000 500.00 - .00500 -s.0000 Sb ppm - .00010 .00082 855.03 - . 0 007 4 .00082 - .00036 Co ppm -.00022 .000r2 53 . 452 00033 00010 00022 LC Pass 100.00 - .0s000 K- ppm 1.0148 . 013 9 1.3688 1.0306 1.0045 1.0093 LC Pass 200.00 -5.0000 V_ ppm .00007 .00026 393.62 - .00019 .00005 .00033 LC Pass As ppm .00056 .00074 113 .20 . 0 0115 .00101 -.00020 Cu ppm .00977 .000s3 5 .4158 .00936 .01037 .00957 Ni ppm - .00010 .00063 535.49 .00024 - .00082 .00029 LC Pass 100.00 -.04000 Zn ppm .00188 .00011 5 . B 496 .00200 .00187 .00778 Ba ppm .00980 .00005 .647 4B .00977 .00988 .00971 Fe ppm .10744 .00255 2 .37 t4 . 10 571 .11038 .106L9 Se/t ppm .00215 .00050 21 .51s B- ppm . 13 661 .00024 .11 47 8 .13688 .13650 . 13 645 Be ppm .00094 .00009 9.8972 .00103 .0008s .0009s Pb/1, ppm - .00085 . 0 01,25 144.A7 - .00083 -.002l.3 .00036 Se/2 ppm - .00117 .00053 45 -1-7L Mo ppm .00425 .00 023 s.3305 .00451 .0041,6 .00409 LC Pass - .00006 - .00009 - .00009 Pb/ 2 ppm .00080 .00054 57.098 .00051 .00t{t .00038 -.00239 - .00384 - .00333 LC Pass 4.0000 - .02000 Li ppm .00l-75 .0002l. l.2.184 . 0 0l-54 .00771 .00795 LC Pass 04513 04584 0464l: Mg ppm .02263 .00063 2 .'7 971- .022a1 .02333 .02244 252 .67 2s2 .54 252 .42 LC Pass 800.00 -5.0000 Sr ppm .00796 .00001 .7 0323 .00195 . 0 019-l . 0 0l-97 LC Pass LC Pass LC Pass 50.000 1400.0 - .02500 - .10000 NOCHECK NOCHECK LC Pass 700.00 -s.0000 Ag Na ppm ppm -.00319 2s2.54 .00074 .13 23.764 .05022 .0024s - .00178 .001_48 -.00080 .002s6 -.00092 NOCHECK NOCHECK Pass LC Pass Appendix F - 296 LC 29L Analysis Report 03/70/06 oB:16:18 PM page 2 High 70.000 100.00 10.000 40.000 40.000 5.0000 10.000 Low -.02000 -.02500 -.02000 -.50000 -.04000 -.05000 -.05000 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge .00123 .00938 .03995 -42882 .00065 .00024 SDev .00010 .00072 .00185 .00403 .00012 .00031 tRSD 8.4428 7 .7136 4.6283 .94083 18. s83 L28.64 #1 .00134 .01003 .03788 .43042 .000s4 - - 00009 #z .00123 .00860 .041-40 .43181 .00063 .00028 #3 .00113 .00951 .04062 .42423 .00078 .00052 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.05000 -.1-0000 -1.0000 -.30000 -.00400 -.01000 Intstd 1 Mode Counts EIem Y WavIen 37 1 . 03 O Avge 247 66 SDev 84 .52484 ?RSD .3412966 #r 24681- #z 24BsO #3 247 67 234557 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 297 292 Analysis Report Method: TRA20505 Samp1e Name: H0A16 Run Time : 0 3 /\0 / oG 20 :1-G :22 Comment : Mode: CONC Corr. Factor: 1 03/7.0/oe oB:22:37 PM Operator: Sb ppm .00908 .00153 16.792 .00923 .00749 .01053 Co ppm .002a8 .00036 1,6 .7 94 .002s7 .0021,2 .00184 K_ ppm 1. B862 .0026 . 13 BLz 1. BB91 1. BB41 1. BB54 V_ ppm .00045 .00068 150.55 . 0 01,24 .00010 .00002 LC Pass As ppm .00223 .00036 l-5.054 .00240 .00247 . 0 01,82 Cu ppm .50s06 .00580 .95895 . 61-747 .60372 .60004 Ni ppm . 04 832 .00060 I .24l-9 .04 901 .04793 .04803 Zn ppm 2.0331 .0063 .31119 04 03 0285 0306 Ba ppm .08316 .00079 . 95 237 .08402 .08300 - 0824'7 Fe ppm 1.3779 .0120 .87595 1.3858 1 .3 639 1.3662 Se/r ppm .00475 .00277 56.9-l 0 .00764 .00606 .00655 B_ ppm . 118 91 .00077 .64825 .1197s .11875 . 11 823 Be ppm .00089 .00005 6.8464 .00085 .00085 .00095 Pb/1, ppm .02505 .00316 t2 .615 .021,42 .02558 - 0271,6 Se/z ppm .0021,9 . 0 01,37 62 .445 .00370 .00104 .00183 Mo ppm .00153 .00028 18.290 .00180 . 0 01,24 .00t54 LC Pass Cd ppm .00774 .00010 5.8058 .001,64 .00184 .00L75 Pb/ 2 ppm .03041 .00199 5 .5491, .03268 .02960 .02896 Ag ppm .00s33 .00087 16.269 .00448 .00529 .00621, .002t6 .00209 .00204 LC Pass page 1 Ca ppm 8.7 s13 .026s .30286 8.7326 8.7 398 8.7 817 Mg ppm .'77453 .00374 .5227 B .77877 .1]-3 0 9 .7 L]-7 2 Na ppm 3 .8337 . OB6B 2.2641 3 .7 9s2 3.9331 3.7728 .05484 . 06 432 . 06 405 LC Pass EIem Al UniLs ppm Avge 4 .4717 SDev .027 0 ?RSD .5O3BB #r #z #: 4.5025 4.4503 4 .4523 Errors LC Pass High 700.00 Low -.20000 BIem Cr Uni t. s ppm Avge . 13 290 SDev .00081 ?RSD .51189 #r #z #: 13370 13208 ]-3291, Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge . 03 27 6 SDev . 00 044 ?RSD 1.3338 #r #z #: . 03 325 . 03 261 . 03 24L Errors LC Pass High 30.000 Low - .01500 EIem T1 Units ppm Avge .00036 SDev .00111 ?RSD 309.49 #r #z #: Errors - .00086 .00131 .00063 LC Pass LC Pass LC Pass 20.000 30.000 - .06000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00500 LC Pass LC Pass 40.000 500.00 - .00s00 -s.0000 LC Pass LC Pass 100.00 50.000 - .0s000 - .02s00 LC Pass NOCHECK 1400.0 - .10000 NOCHECK LC Pass 700.00 -5.0000 LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHECK NOCHECK LC Pass LC Pass 4.0000 800.00 - .02000 -s.0000 Li Sr ppm ppm . 00209 . 06 44t .00006 .00040 2.9399 .61632 2 2 2 Pass LC Pass Appendix F - 298 LC 293 Analysis Report 03/70/06 oB:22:3L PM page 2 High 70.000 L00.00 10.000 40.000 40.000 5.0000 10.000 Low - .02000 -.02500 -.02000 - .50000 - .04000 -.05000 -.05000 . Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge .02151 .04092 7 -3473 1.4785 .02911 .00334 SDev .00027 .00002 .0259 - 0033 .00029 .00033 ?RSD 1,.2395 .03615 .35218 .22343 .98548 9.8957 #l- .02181 .04091 7 .3769 1,.4790 .0294L .00330 #2 .02130 .04092 7 .3293 1,.4750 .02908 .00303 #3 .021-42 .04094 '7 .3356 1.4815 .02884 .00359 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.05000 -.10000 -1.0000 -.30000 -.00400 -.01-000 Int.Std 1 Mode Counts Elem Y Wavlen 377. 03 0 Avge 2481,0 SDev 74.47742 ?RSD .2999437 #r 24882 #z 248L6 #3 24734 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 299 o 294 Analysis Report Method: TRA20505 Sample Name: H0HR0 Run Time : 0 3 / La / 06 20 :22 :35 Comment : Mode: CONC Corr. Factor: 1 03/70/oG oB:28:44 pM Operator: Sb ppm .01606 .00]-7a 10.535 .01789 .01578 . 014 51 LC Pass 20.000 -.06000 Co ppm .00347 .00025 7 . tt92 .003s9 .00319 .00354 K- ppm 1.0080 .002s .2507 s 1.0080 1.010s 1.0054 LC Pass 200.00 -s.0000 V_ ppm .00111 .00036 32 . a72 .00100 .00082 .00151 LC Pass As ppm .00263 .00074 28.090 . 0 0 269 . 0 01,87 .00334 LC Pass 30.000 - .01000 Cu ppm .05004 . 0 01,0'/ 2 .1357 . 04 954 . 0 51,27 .04931 Ni ppm .1,2608 .00031 .24233 .12s83 .12642 . 7259 9 Zn ppm .7 3 411 .00238 .32401 .73638 .7 3448 .7 3766 Ba ppm .103s9 .000s0 .48352 .10353 .10412 .1031,2 LC Pass 30.000 - .01000 Fe pprn 1.1701 .0072 . 51507 1.1783 1 . 1668 1.1651 Se/t ppm .00247 .00405 754. 13 -.00220 .00511 .00449 B- ppm . 0 431_7 .00066 1.5367 . 0 4253 .04386 .043l-4 Be ppm .00104 .00010 9 .7 41,3 .007L4 .00094 .00103 LC Pass 10.000 - .00500 Pb/1 pprn .01743 .00474 2'7 .17 B .01233 .02]-59 .01827 Se/2 ppm .00232 .002s7 110.58 .00519 . 0 01,52 .00024 Mo ppm .00135 .00019 13.908 .00155 .00l.21 .00721_ LC Pass Cd ppm .00054 .00009 15 . 6s4 Pb/2 ppm .02861 .00278 9.7276 .031ss .02601 .02826 -.0'0476 - . 0 04 B B -.00424 Li ppm .001,64 .00005 2.9095 .0016s .001-69 .00159 LC Pass page 1 Ca ppm 72 .945 . 010 .01865 Mg ppm .831,73 .00108 .729 65 .83139 .83294 .83087 2.7474 3.0901 3.0580 Sr ppm .091'70 .00034 .37 270 .09199 .09479 .09]_32 LC Pass EIem AI UniLs ppm Avge 1.5475 SDev .0057 ?RSD .35899 #r #z #: 1.5531 1.5480 1.54t7 Errors LC Pass High 700.00 Low -.20000 EIem Cr Units ppm Avge . 01 002 SDev .00026 ?RSD 2 .6311 #r #z #3 00973 01009 01,024 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge . 03 553 SDev . 00 046 ?RSD 1.2907 #r #z #: 03519 03505 03534 Errors LC Pass High 30.000 Low - .01500 Elem TI Unit s ppm Avge -.00093 SDev .00106 ?RSD 113 . 81 #r #z #: Errors - .00008 - .00060 - . 0 021,2 LC Pass 00045 L2. g55 00057 72.935 00061 l_2.945 LC Pass LC Pass 40.000 500.00 - .00s00 -s.0000 LC Pass LC Pass 100.00 s0.000 - .05000 - .02500 LC Pass NOCHECK NOCHECK LC Pass 1400.0 700.00 -.10000 -s.0000 Ag Na ppm ppm -.00463 2.9685 .00034 .1918 7 .2881 6.46t7 LC Pass NOCHECK 100.00 -.04000 NOCHECK LC Pass LC Pass 4.0000 800.00 -.02000 -5.0000 LC Pass LC Pass Appendix F - 300 o 295 Analysis Report 03 / \o / 06 oB : 28:44 PM page 2 5.0000 10.000 - .05000 - .05000 Se ppm .0026s .00062 23.309 .00301 .00300 .00193 LC Pass 30.000 - .01000 61 NOTUSED NOTUSED High Low 70.000 - .02000 100.00 - .02500 Sn ppm . 03 424 .00140 4.0868 . 03 282 . 03 552 . 03 427 10.000 - .02000 Si ppm 1.5845 .0130 .81840 1.5972 1.58s1 1.5773 40.000 - . s0000 P_ ppm .3620s .00123 .3 4072 .36264 .3 6287 .36053 40.000 - .04000 Pb ppm .02529 .00031 t .2250 .025s8 .02497 .02533 EIem Ti Units ppm Avge .42756 SDev .00015 ?RSD . s484 I #r #z #: 027 53 027 42 02772 Errors LC Pass High 40.000 Low -.05000 fnLstd 1 Mode Counts Elem Y Wavlen 37L. 03 0 Avge 25237 SDev 7 9 .69239 ?RSD .31s7737 #r #z #: 251,49 25303 25259 LC Pass LC Pass 40.000 40.000 - .10000 -1.0000 23 NOTUSED NOTUSED LC Pass LC Pass 40.000 70 .000 - .30000 -.00400 45 NOTUSED NOTUSED Appendix F 301 296 Analysis Report Method: TRA20505 Sarnple Name: H0A16S Run Time : 0 3 / l0 / 06 20 :28 :47 Comment : Mode: CONC Corr. Factor: 1 03/70/06 oB:34:57 PM OperatoL: Sb ppm .37 532 .00223 .59438 .37788 .37 37 9 .37 429 LC Pass 20.000 - .06000 Co ppm .09035 .00014 .15977 .09023 .09032 .09051 LC Pass 100.00 - .0s000 K- ppm 45 .253 .250 .54028 46.364 45 .961 46 .428 V_ ppm .l-7509 .00045 . 2593 9 .77 562 .]-7485 .7'7481 LC Pass As ppm .09044 .00743 1.5833 .09136 .0881 9 .09116 LC Pass 30.000 -.01000 Cu ppm .89708 .00333 .37113 . 90 082 .89442 .89601 Ni ppm .49191 .002'7s .55872 .48911 .49203 .49450 Zn ppm 2.-7 051 .0070 . 26 024 2 .7 016 2.7 004 2 -'71-32 Ba ppm .20735 .0005s .31488 .20810 .20690 .207 06 LC Pass 30.000 - .01000 Fe ppm 2.4903 .0059 .27784 2 .4949 2 .4824 2 .4937 Se/t ppm . 13 625 .001s5 1.1385 .13 669 .13453 .13754 NOCHECK B- ppm . 95 61,2 .00398 .41_589 .95729 . 9s 937 .951,69 Be ppm .04558 .00007 . 151_92 .04553 . 04 556 .04556 LC Pass 10.000 - .00500 Pb/1, ppm .11870 .00433 3.5457 .11497 .11768 .723 45 Se/z ppm .13008 .00193 7 .4847 . 13 1,43 .13 094 .1,27 87 Mo ppm .43884 .00084 . 1911 9 .43865 .43811 .43975 LC Pass Cd ppm .04518 .00026 .58100 .045L2 .04495 .04547 Pb/ 2 ppm - 1,210 6 .00097 .8009s .121_7 5 . 1_214 B .1199s Ag ppm .049'7 A .00035 .7 L9 07 . 049 49 .04950 .0s011 Li ppm .09960 .000s9 .59084 .10006 .09894 .09980 LC Pass page 1 Ca ppm 54 .044 .286 .529L5 53 . 906 s3 . Bs3 54.373 Mg ppm 9 .257 B .0280 .30247 9.2363 9 .2477 9.2895 Na ppm 48.363 .267 .5s206 48.256 48 .167 48. 66'7 Sr ppm .5287 4 .00155 .29 442 .52953 .52695 . s297 4 LC Pass El em A1 Units ppm Avge 7 .1,508 SDev .0258 ZRSD .36L27 #r #z #: '7 .1_47 9 7 .1-266 7 .1,780 Errors LC Pass High 700.00 Low - .20000 EIem Cr Units ppm Avge .321-87 SDev .00116 ?RSD .3s992 #r #z #: 32092 32152 32376 Errors LC Pass High 100.00 Low - .01000 El-em Mn Units ppm Avge .12498 SDev .00A1'7 %RSD . 13 727 #r #z #3 1,2576 1249 6 72482 Errors LC Pass High 30.000 Low - .01500 EIem T1 Units ppm Avge .27223 SDev .00139 ?RSD .50993 #r #z #: Errors .27064 . 27 283 . 27 322 LC Pass LC Pass LC Pass 40.000 500.00 -.00500 -s.0000 LC Pass LC Pass 50.000 1400.0 - .02500 - .10000 NOCHECK NOCHECK LC Pass 700.00 -5.0000 LC Pass LC Pass 200.00 100.00 -s.0000 -.04000 NOCHECK LC Pass LC Pass 4.0000 800.00 -.02000 -5.0000 LC Pass LC Pass Appendix F - 302 297 Analysis Report 03/Lo/06 oB:34:57 PM page 2 0000 10.000 05000 - .05000 High Low 70.000 - .02000 100.00 * .02s00 Sn ppm .46253 . 0 01,47 .317L3 .46497 .46742 .45419 LC Pass 40.000 - .10000 2 10.000 40.000 - .02000 - .50000 Si ppm 1.7721 . 0118 .6678s L.7 B4s L.-1708 1, -7 610 LC Pass 40.000 -1.0000 3 P_ ppm 6 .2593 .0107 .17 0 01 6 .27 L5 6.2s78 6 .21 87 40.000 - .04000 Pb ppm .]-2050 .00080 .66099 .11985 .l.20s0 .1,2444 Se ppm . 13 243 .00107 .80517 .133s0 . 13 242 .131,31 Elem Ti Units ppm Avge . 11 B2B SDev .00051 %RSD .43392 #r #z #s .11853 .11769 .11851 Errors LC Pass High 40 .0 0 0 Low -.05000 Int. S t.d 1 Mode Counts EIem Y Wavlen 377. 03 0 Avge 24694 SDev 46 .77238 %RSD .1B94OBO #r #z #: 247 39 24698 24645 LC Pass LC Pass LC Pass 40.000 70.000 30.000 -.30000 -.00400 -.01000 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 303 298 Analysis Report Method: TRA20505 Sample Name: H0A15D Run Time: 03/70/05 20:35:00 Comment; Mode: CONC Corr. Factor: 1 03/to/06 oB:41:09 PM OperatoL: Sb ppm - 3-7 329 .00266 .7 t20t .37 57 t .37045 .37 37 7 LC Pass 20.000 - .06000 Co ppm . 0 9224 .00054 .58254 .09277 . 0 922s .09770 K_ ppm 46 .507 . 1,61 .3sB5s 46. s00 46.800 46 .523 V- ppm .t'7735 . 0 0115 .64913 .t7B6B .l.7558 .71680 LC Pass As ppm .0902]. .00103 1 . 1424 .09104 .08905 .09053 Cu ppm .9052'7 .00373 . 41,76 4 . 9 01,45 .90890 .90545 Ni ppm .4997 0 .00419 . B 3161, .49546 .50383 .49980 Zn ppm 2.'7740 .01,26 .45310 2 .7 646 2.-t BB3 2.'769L Ba ppm .18536 .00055 .29790 .18487 .18595 .18525 Fe ppm 2 - 521,1 .0099 .39189 2 .5290 2 .5244 2 . 5101 Se/t ppm . 13 412 .00258 1 . 9252 .1358s .13382 . 13 L7l B_ ppm . 9 6374 .0036s .37 869 . 9 620s .96721 .96077 Be ppm . 04 621 .00019 .41815 .04602 . 04 644 .0461,9 Pb/7 ppm .11845 .002-l 0 2.2805 .1209 4 .11885 .11558 Se/z ppm . 13 1,43 .00307 2.3357 . 13 1,45 .72835 . 13 449 Mo ppm . 444'7 7 .00395 . BBB36 . 4417 5 .44924 .44332 LC Pass Cd ppm .04505 .00016 .3s143 .04587 .04611 .04618 Pb/ 2 ppm . L231,2 .00168 1 . 3 657 .l-2119 - 1,2427 .1_23 9 0 Ag ppm' .05127 .00049 .95740 .051,28 .0s176 .05078 page 1 Ca ppm 55.139 .242 . 43 927 55.011 55.418 54 .981 Mg ppm 9.4098 .0404 .42950 9 .3967 9 .4552 9.3776 Na ppm 4B .939 .183 .3-7394 48.908 49.136 48. -/74 Sr ppm .53250 .00205 .38495 . 53 057 . 53 4-12 . 5 3 21-1, LC Pass EIem AI Units ppm Avge 1 .2993 SDev .0337 ?RSD .461,32 #r #z #: 7 .2752 7 .3378 7 .2849 Errors LC Pass High 700.00 Low -.20000 EIem Cr Units ppm Avge .32562 SDev .00160 ?RSD .49 054 #r #z #: 32527 32736 32423 Errors LC Pass High 100.00 Low - .01000 EIem Mn Unit s ppm Avge .72696 SDev .00066 ?RSD .51900 #1 #z #: 1,26 6 9 12771 1-2 6 47 Errors LC Pass High 30.000 Low -.01500 Elem TI Units ppm Avge .27744 SDev .00301 ?RSD 1.1105 #r #z #: Errors .26-796 .27319 .27318 LC Pass LC Pass LC Pass 100.00 50.000 - .0s000 - .02s00 LC Pass LC Pass 30.000 30.000 - .01000 - .01000 LC Pass LC Pass LC Pass 10.000 40.000 500.00 -.00500 -.00500 -5.0000 LC Pass NOCHECK NOCHECK LC Pass 1400.0 700.00 - .10000 -5.0000 LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHECK NOCHECK LC Pass LC Pass 4.0000 800.00 -.02000 -s.0000 Li ppm .10006 . 00 022 .22431, . 0 9 981 .10031 .10000 LC PassPass LC Pass Appendix F - 304 LC 299 Analysis Report High Low 70.000 - .02000 40.000 - .04000 1,2757 7227 9 72753 s.0000 - .05000 13353 13045 1338s page 2 10.000 - .05000 03 / to / 06 oB : 4t:09 PM 100.00 - .02500 Sn ppm . 47 147 . 0 0114 .241"67 .47088 . 47 242 .47 020 LC Pass 40.000 - .10000 2 Si ppm 1-744'7 .0123 .70396 7 .141 4 1.7554 7.7 313 P_ ppm 6.3095 .0365 .57 929 5.3073 6.3470 6 .27 40 10.000 40.000 - .02000 - .50000 El em Ti Units ppm Avge .11939 SDev .00051 %RSD .42984 #r #z #: . 11 913 .11998 .11905' Errors LC Pass High 4a.000 Low -.05000 Int Std 1 Mode Count.s EIem Y Wavlen 37L. 03 0 Avge 246L3 SDev 74.62-153 %RSD .3032066 #r #z #3 24602 24544 24692 Pb Se ppm ppm . 7219 5 . 13 261, .00073 .00187 .60165 7.41,25 NOTUSED NOTUSED NOTUSED LC Pass LC Pass 40.000 40.000 -1.0000 - .30000 LC Pass LC Pass 10.000 30.000 - .00400 -.01000 5 NOTUSED NOTUSED NOTUSED Appendix F - 30s 300 Analysis Report Method: TRA2 0505 Samp1e Name : HOHTE Run Time: 03/70/06 20:41:13 Comment : Mode : CONC Corr. Factor: 1 03/70/06 oB:47:22 PM OperatoE: Sb ppm - . 0 oo7 4 .00316 425 .21_ - .00120 .00262 - . 0 0364 LC Pass 20.000 -.06000 Co ppm .00011 .000s2 466 .48 .000]-2 .00053 - .00041 LC Pass 100.00 - .05000 K- ppm .09605 .00907 9 .4424 .08559 .10256 .09990 LC Pass 200.00 -5.0000 V- ppm .00077 .000s9 3 51 .28 - .00019 .00085 - .00016 LC Pass As ppm .00098 .00028 28.057 .00091 .001,29 .00015 LC Pass 30.000 - .01000 Cu ppm .33823 .002'71 .80066 .33565 .34105 .33801 LC Pass s0.000 -.02500 Ni ppm .0027s . 0 0 047 1,6 - 925 .002-/t .00323 .00230 Zn ppm 1,.7499 . 0l-97 1. 1240 7 284 1 67l. 7 540 Ba ppm .00401 .00005 1 . 5115 .00395 .00402 .00407 Fe ppm 1.3].76 . 01,7 9 1.3615 1.2980 1.3332 1.32].5 Se/ 1 ppm .00345 .00088 25 .544 .00384 .00407 .00244 B- ppm .00397 .000s3 13 .485 .00338 .00443 .00409 Be ppm .00772 .00009 7 .5636 . 0 0115 . 0 01-02 . 0 0118 Pb/ L ppm . o7 144 .00115 1.6193 .07 025 . 07 257 - 0'7144 Se /z ppm .00133 .00053 39.99]- .00190 .00084 .00l.25 Mo ppm .00l.77 .000s5 31.558 .00113 .00210 .00209 LC Pass Cd ppm .001,79 .00011 5 .1,-l 86 .00]-82 .00188 .00]-67 Pb/ 2 ppm . 07 420 .00055 . BB285 .07348 .07434 .07 477 Li ppm .001s5 .00013 8 .227 9 .00170 .001s3 . 0 0L44 LC Pass page 1 Ca ppm .7 97 22 .00799 1.0028 .7 8944 .80541 .19581 Mg ppm .0222s .00280 t2 .592 .02022 .02545 .02108 Sr ppm .00070 .00002 3.1294 .00070 .000'73 .00068 LC Pass Elem Al Units ppm Avge - .02610 SDev .00271 ?RSD 10.376 #r #z #: -.02922 -.0241 9 -.02430 Errors LC Pass High 700.00 Low -.20000 Elem Cr Units ppm Avge .00525 SDev .00048 ?RSD 9 .1,251, #r #z #: .00472 .00565 .00539 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge .01208 SDev .00010 ?RSD .7 B47B #r #z #: 01198 oa2t7 01,209 Errors LC Pass High 30.000 Low -.01500 EIem Tt Units ppm Avge .00080 SDev .00089 ?RSD tt2. 01 #r #z #: Errors .00183 .00032 .00024 LC Pass LC Pass LC Pass 30.000 10.000 - .01000 - .00500 LC Pass LC Pass 40.000 500.00 - .00s00 -5.0000 LC Pass NOCHECK NOCHECK LC Pass 1400.0 700.00 - .10000 -5.0000 Ag Na ppm ppm -.00086 .03446 .00100 .10358 116 .07 300.63 00201 .00040 00020 .15078 00037 -.0478l LC Pass NOCHECK NOCHECK LC Pass LC Pass 100.00 4.0000 800.00 -.04000 .02000 -5.0000 1 1 1 Pass LC Pass Appendix F - 306 LC 301 Analysis Report 03/70/06 0B:4'7:22 PM page 2 High 70.000 100.00 10.000 40.000 40.000 5.0000 10.000 Low - .02000 -.02s00 -.02000 - . s0000 -.04000 - .0s000 -.0s000 Elem Ti Sn Si P Pb Se Units ppm ppm ppm pp* ppm ppm Avge .00222 .02043 .03982 1.0425 .01367 .00232 SDev .00012 .00095 .00243 .0135 .00074 .00045 ?RSD 5.2877 4.6929 6.0997 L.2989 1.0070 L9 .61-2 #1 .002L7 .07972 .04197 7.0287 .07281- .00283 #2 .00235 .021-52 .04032 1.05s7 .O14L7 .0022L #3 .002t4 .02005 .03719 1.0431 .07402 .00194 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low - .05000 -. l-0000 -1.0000 -.30000 -.00400 -.01000 Intstd 1 Mode Counts EIem Y Wavlen 37]-. 03 0 Avge 24344 SDev 238.6180 ?RSD . 98 02007 # l- 245]-7 #z 24]-57 #3 24269 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 307 302 Analysis Report Met.hod: TRA20505 Sample Name: H0HTES Run Time : 0 3 / 70 / OA 20 :47 --26 Comment : Mode : CONC Corr. Factor: 1 03/ao/oG oB:53:35 pM OperatoL: Sb ppm .403 0 9 .00525 1.3034 .40279 .39800 .40849 Co ppm .09155 . 0 01,23 1.3465 .09193 .09077 . 0 9255 LC Pass 100.00 - .05000 K- ppm 43.031 .7 26 1.6880 42 .51 0 42 .55-l 43. B5B LC Pass 200. 00 -5.0000 V_ ppm .77998 .00324 1. B01B .1,7996 .17 67 4 .18323 LC Pass As ppm .09004 .00291 3 .2267 .08973 .08730 .09309 Cu ppm .54791 .00948 7 .4624 .647 4t .63870 .65763 LC Pass 50.000 - .02500 Ni ppm .45'772 .0069L 1.5100 .4564-/ .45152 . 4 65L7 Zn ppm 2 .6217 .0418 1. s923 677 4 5920 6738 Ba ppm . 09 486 . 0 0 1-21, 1.2768 .09474 .09371 .09672 Fe ppm 2.604s .0399 1 .5372 2 .5979 2 .57 25 2 .6492 Se/7 ppm . 13 1"20 .00427 3 .2562 . 13 239 .126 46 .134-76 B- ppm .80851 .01230 1.521,5 .80447 .'79891 .82244 Be ppm .04776 .00078 1.6287 .04731 . 04 731 .04866 Pb /1, ppm .18056 .00228 7 .2644 .a7944 .1_790s .18318 Se/z ppm .12873 .00222 \.721 6 .428 7 5 .725s0 .13095 Mo ppm .45452 .00693 1.5386 .44852 .444 B 1 .45823 LC Pass Cd ppm .04745 .00059 1.2514 .041 42 .04581 .04805 Pb/2 ppm .182'75 .00303 7 .65s8 .18017 .18200 .18508 Ag ppm .04271, .00087 2 .0459 .04235 . 0 4207 .043"7 0 Li ppm .09965 .00151 1.5190 .09903 .09Bss .10138 LC Pass page 1 Ca ppm 47.540 .834 1.7 553 47 .15 4 46.958 48.497 LC Pass 500.00 -5.0000 Mg ppm 8.7298 .1306 7.4961, 8.5730 8.6312 B.8792 Na ppm 44 .995 . s55 t .2142 44 .852 44 .528 45 .51 0 Sr ppm - 451 82 .00710 I .5451, .46492 .46200 .47555 LC Pass Elem A1 Units ppm Avge 1.8768 SDev .032L ?RSD 7.7127 #r #z #: 1 . 8 671 1.8s0s 1.9l.25 Errors LC Pass High 700.00 Low - .20000 Elem Cr Units ppm Avge . 18 732 SDev .00258 ?RSD 1.3766 #r #z #: 1B5OB 18551 1,9 029 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge .10813 SDev .00732 ?RSD 7 .2245 #r #z #: 10833 10571 10933 Errors LC Pass High 30.000 Low - .01500 Elem T1 Units ppm Avge .35783 SDev .00787 ?RSD 2.1,404 #r #z #: Errors .36368 .36289 .37690 LC Pass LC Pass LC Pass LC Pass 20.000 30.000 30.000 -.05000 -.01000 -.01000 LC Pass LC Pass 10.000 40.000 - .00s00 - .00500 LC Pass NOCHECK 1400.0 - .10000 NOCHECK LC Pass 700.00 -5.0000 LC Pass NOCHECK NOCHECK 100.00 - .04000 LC Pass LC Pass 4 .0000 800.00 - .02000 -5.0000 2 2 2 Pass LC Pass Appendix F - 308 LC 303 Analysis Report 03/to/06 oB:53:35 PM page 2 High 70.000 100.00 10.000 40.000 40.000 5.0000 10.000 Low - .02000 -.02500 - .02000 - .50000 - .04000 -.05000 - .05000 Elem Ti Sn Si P Pb Se Units ppm ppm ppm pp* ppm ppm Avge .09553 .50325 3 .5389 5.7464 -a824)' .l-2985 SDev .00144 .00941 .0483 .0912 .00268 .00289 ?RSD 1.5043 1.8691- 1.3639 1.5873 '1,.4658 2.2249 #r .09518 .49986 3.5354 s.7210 .18043 .t3025 #2 .09429 .49601- 3.4924 s.6706 .18l-3s .72678 #3 .09710' .51388 3. s887 5.8476 .18545 .132sL Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.05000 -.10000 -1.0000 -.30000 -.00400 -.01000 Intstd 1 Mode Counts EIem Y Wavlen 371. 03 0 Avge 23899 SDev 266. B 993 %RSD 1.11,6761 #r 23889 #z 24].7]- #: 23638 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 309 3 04 Analysis Report Method: TRA20505 Run Time: 03/70/06 Comment: Mode: CONC Corr. EIem A1 Units ppm Avge 7 .7 B3 9 SDev . 014 B ?RSD . 83 02 O #r #z #: 1.7 681 L.'7974 7.1853 Errors LC Pass High 700.00 Low - .20000 Sample Name: HOHTED 20:53:39 03/1,0/06 oB:59:48 PM Operator: F-gtor: 1 Sb ppm .40153 .00565 1, .6 555 .39496 .40825 .40139 As ppm .08920 .00189 2 . t1-46 .08736 .08913 .09113 Ba ppm .09567 .000ss . 57'7 87 .09507 .0961,6 .09578 Fe ppm 2 .97 87 . 0 51"4 I .7 243 2 .9225 3.0232 2 .9904 Se/t ppm .13354 .00385 2.88 19 .13776 . 13 023 . 13 264 B- ppm .8091 6 .00959 1 . 1847 .19878 .81651 .81400 Be ppm .04778 .00050 1.05l-2 .04720 .04811 . 04 B02 Pb /a ppm .18689 .00181 .97041 .18893 . 1B 526 .18547 Se /z ppm .t2803 .00232 1 . Bt37 .1,2537 .1,2908 .12965 Mo ppm .45569 .00529 1.161,4 .45023 .46080 .45503 LC Pass Cd ppm .0474a .00058 1 .4253 Pb/2 ppm .18679 .00356 7 .9597 . 1B 259 ,18933 .18843 0 4029 0 427 1, 0 4225 Li ppm .09982 .00030 , 3 0 456 .09983 .104l.2 .099s1 LC Pass page 1 Ca ppm 47 .699 .558 1.1905 LC Pass 600.00 -5.0000 Mg ppm 8.7 050 .726a 1,.4480 8.5550 B.8105 B .7 473 44 .948 45 .7 4L 45.139 Sr pprn .46939 .00269 .s7398 .467 06 .4-7234 . 4687 7 LC Pass .04667 47 .0'7 5 .04799 4B.18B .04751 47 .833 LC Pass LC Pass LC Pass 20.000 30.000 30.000 -.05000 -.01000 -.01000 LC Pass LC Pass 10.000 40.000 - .00500 - .00500 El em Units Avge SDev ?RSD #r #z #: Cr ppm .18976 .00259 1 .3 571, . 1B 7]-9 .19238 . 1B 97l- Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .11084 SDev .00130 ?RSD 1.1589 #r #z #s 10 94 5 11,20 4 111 01 Errors LC Pass High 30.000 Low - .01500 EIem T1 Units ppm Avge .36663 SDev .00410 ?RSD 1.1189 #r #z #: Errors .36799 .3591 9 .35810 LC Pass LC Pass LC Pass 100.00 50.000 - .0s000 -.02s00 LC Pass NOCHECK 1400.0 - .10000 NOCHECK LC Pass 700.00 -5.0000 Ag Na ppm ppm . 041,7 5 45 .27 6 .00a28 .474 3.0709 .91445 Co ppm . 0 91,43 .00150 1.544s .08979 .092-13 .09178 K_ ppm 43 .07 4 .1,7 5 .40544 42.955 43 .27 4 42 .993 LC Pass 200.00 -5.0000 V_ ppm .1,7958 .00277 1.5105 . a7 652 .18168 .18055 LC Pass Cu ppm . 57 037 .00387 .57794 .66693 . 67 457 .6696A Ni ppm .457 09 .0070]- 1.5327 .44948 .46327 .45851 LC Pass 100.00 -.04000 Zn ppm 2.7 395 .0372 1 . 1382 7 054 7 565 7 465 NOCHECK NOCHECK LC Pass LC Pass 4.0000 800.00 - .02000 -5.0000 2 2 2 Pass LC Pass Appendix F - 310 LC 305 Analysis Report 03/to/06 oB:59:48 PM page 2 High 70.000 l-00.00 10.000 40.000 40.000 s.0000 10.000 Low - .02000 - .02500 - .02000 - .50000 -.04000 -.05000 - .05000 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge .09629 .47984 3 -7374 5.8054 .a8722 .13018 SDev .00091 .00544 .0369 .0567 .00191 .00068 ?RSD .94155 1.1337 .98624 .97640 1.0200 .52551- #1 .09546 .47395 3.7008 5.74L4 .18507 .1-2978 #2 .09726 .4846'7 3 .'1745 s.8326 .18873 .j.2979 #3 . 0951-s .48090 3 .'7368 5. B4s4 . 18786 .13097 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low - .05000 -.10000 -1.0000 -.30000 - .00400 - .01000 Intstd 1 Mode Counts BIem Y Wav1en 37 A. 0 3 0 Avge 24233 SDev 154.3852 SRSD .5370987 #r 2438s #z 24077 #g 24236 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 311 306 Analysis Report Method: TRA2 0505 Sample Name : HOHTRP Run Time: 03/L0/06 20:59:51 Comment : Mod.e : CONC Corr. Factor : 1 03/to/06 o9:05:oo pM Operator: Sb ppm .00087 .00093 106. B3 - .00020 .00150 .00130 Co ppm .00001 .00039 67 91, .2 - .00022 - .00023 .00046 K- ppm .05238 .00532 10. a64 .04530 .05623 .0546]- V_ ppm .00015 .0005s 421. 6 0 -.00040 - .00001 .00087 LC Pass As ppm .00060 .00068 113 .06 .00024 .00018 .00138 Cu ppm . o7 649 . 0 01,28 1.6701 .o7501 .07726 . 0711,8 Ni ppm .00011 .00039 344 .20 -.00032 .00025 .00041 Zn ppm .3s933 .00481 1.3393 .35384 .36285 .36128 Ba ppm .00093 .00015 77 .465 .00075 . 0 0 097 .00105 Fe ppm .263 67 .00698 2 .6484 .256 62 .26380 .27059 Se/t ppm .00351 .00024 6.9633 .00323 .00369 .00350 B_ ppm .002r7 .00028 13 . 014 . 0 0]-92 .002),3 .00248 Be ppm .00084 .00004 4.4555 .00088 .00081 .00084 Pb/r ppm . 013 01 .00080 5.1322 .01392 . 01 247 . 01 263 Se /2 ppm .001,29 .00115 88.769 .00226 .00002 .00160 Mo ppm .00l-07 .00032 3 0 . 384 . 0 0115 .00071 .00l-34 LC Pass Cd ppm .00029 .00011 35 .67 B .00026 .00020 .00041 Pb/2 ppm . 015 54 .00055 3 .610s .01615 .01504 .01545 Ag ppm -.00292 .000s7 19. 6l-9 - .00358 -.00254 -.0026s Lr ppm .00062 .00009 74.550 .00071, .00051 .000s3 LC Pass page 1 Ca ppm .t7770 .00272 1.5378 . t7 440 .1,7705 .7798s Mg ppm .00659 .00286 43.481 .00347 .00718 .00911 Na ppm -.12043 .0827a 68.679 -.16693 - .16943 -.02494 Sr ppm .00020 .00001 6.2111 .00019 .00019 .0002]- LC Pass EIem AI Uni t. s ppm Avge -.04035 SDev .00090 ?RSD 2 .2427 #r #z #3 - . 0 41,1,5 - .03937 -.04052 Errors LC Pass High 700.00 Low -.20000 EIem Cr Units ppm Avge . 0 01,42 SDev 00008 ?RSD 5.5588 #r #z #: . 0 01_47 .00151 .00135 Errors LC Pass High 100.00 Low -.01000 EIem Mn Units ppm Avge . 0033 0 SDev .00042 ?RSD t2 .6s4 #r #z #: .00283 .00363 .00344 Errors LC Pass High 30.000 Low -.01500 EIem T1 Units ppm Avge . 0 01,67 SDev .002L5 ?RSD 1,29 .22 #r #z #: Errors .0041,4 .00053 . 00 023 LC Pass LC Pass LC Pass 20.000 30.000 - .05000 - .01000 LC Pass LC Pass 30.000 10.000 -.01000 - .00500 LC Pass LC Pass 40 .000 500.00 - .00500 -5.0000 LC Pass LC Pass 100.00 50.000 - .0s000 - .02s00 LC Pass NOCHECK 1400.0 - .10000 NOCHECK LC Pass 700.00 -s.0000 LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHECK NOCHECK LC Pass LC Pass 4.0000 800.00 -.02000 -s.0000 LC Pass LC Pass Appendix F - 312 307 Analys i s High Low Elem unl_ t s Avge SDev %RSD #r #z #: Errors High Low IntStd Mode EIem Wavlen Avge SDev ?RSD #r #z #: Report 70.000 - .02000 Ti ppm .00051 .00009 l.7.605 .00046 .0004s .00061 ' 1 Count s Y 371,. 0 3 0 24585 776.8900 .71,95165 24784 24447 24523 100.00 - .02500 Sn ppm .00446 .00011 2.5351 .00436 .00445 .004s8 2 NOTUSED Si ppm -.00851 .0008s 9.8983 OOBB4 00932 007 65 P- ppm . 21,0 42 .001,77 . 81 07]- .2086s .21,205 .21,056 10.000 40.000 - . 02000 - . s0000 40.000 -.04000 Pb ppm .01511 .00053 4 .t7 93 .01581 . 01 459 .01492 LC Pass LC Pass 70.000 30.000 - .00400 - .01000 03/70/06 o9:06:oo PM page 2 5.0000 10.000 - .05000 - .0s000 Se ppm .00232 .00070 30.114 .00281 .001s3 .002ss LC Pass LC Pass 40 .000 40.000 - .05000 - .10000 LC Pass LC Pass 40.000 40.000 -1.0000 - .30000 NOTUSED NOTUSED NOTUSED NOTUSED 7 NOTUSED Appendix F - 313 308 Analysis Report QC Standard Method: TRA20505 Sample Name : CCVT Run Time: 03/a0/05 2l:06:04 Comment : Mode: CONC Corr. Factor: 1 03/to/06 o9:J.2:12 PM Operator: Ba ppm 1.7972 .0137 .764-77 Fe ppm 22 .677 .348 1.5337 22 .657 Q22.340 23.035 Be ppm 1.8523 .0284 1.5332 Mo ppm 1.8429 .0333 1. B07B 1. B3s0 1. Ba43 1.8795 QC Pass Cd ppm .4502l- .00957 2 .1,256 Li ppm 1.8299 .0136 .7 427 I 1.8364 1.8743 1.8391 QC Pass page 1 Ca ppm 46.184 .805 t .7 449 46 .1-62 45.390 47.001 Na ppm 45.538 .462 1.0122 45 .604 45.193 46 .115 Sr ppm 1 . B 440 .0l-94 1 . 0 499 1.84A4 1.8261, 1 . B 645 QC Pass EIem A1 Units ppm Avge 22.551 SDev .27 0 ?RSD 1.19s1 #r #z #: Errors QC Pass Va1ue 25.000 Range 10.500 EIem Cr Units ppm Avge 1, .7 92'7 SDev . O25t ?RSD 1.3978 #r #z #: 4.7936 Q1 .7673 1.81-74 Errors QC Pass Value 2.0000 Range 10.500 Elem Mn Units ppm Avge 1.8013 SDev . 0 239 ?RSD 1.3285 #l- #z #: Elem TI Units ppm Avge .92665 SDev .00891 %RSD .95a7 6 K_ ppm Q43 . s36 .366 . B3 965 V_ ppm 1. B06B .0246 1.3632 1.8080 Q1 . 7 81,6 1.8309 QC Pass Sb ppm .45580 .00929 2 .0329 22 .542 .46 03 1 Q22. 3 01 Q.4 4628 22.840 .46383 As ppm .45309 .007s8 1.5728 QC Pass QC Pass .50000 . s0000 10.500 10. s00 Co Cu ppm ppm 1.8327 Q1.7BBB .0337 .0191 1.840'7 1.0650 1. B24t Q1.7847 1.8040 Q1.7720 1.8699 1.8095 QC Pass QC Fail 2.0000 2.a000 10.500 10.500 Ni ppm 1.8799 .0355 1.949]- 1.81,78 Q1 .7Bss 1. Bs63 . 4509'7 I .19 B 5 Q.44679 Q1.7B2B .46150 1. Bt02 1. Bs33 .44846 1 . B 234 Q.4 4]-64 1 . B 802 .46 0s4 Pb/r ppm .45882 .00604 1 . 31,69 .46077 .45205 .463 6 B Se/ 2 Ag ppm ppm .44660 Q. BBB13 .00518 .01135 1.1503 1.2784 .44580 Q.BBB61 .44187 Q.87654 .4521,4 .89923 QC Pass QC Pass 2.0000 2.0000 10.500 10. s00 QC Pass QC Pass . s0000 s0.000 10.500 10.500 Pb/2 Mg ppm ppm .4s691 Q44 .47 5 .00811 .704 l.'775L 1.5829 .4557 6 Q44 .47 O .44954 Q43 .-775 .46553 45.183 NOCHECK QC Fail 50.000 10.500 QC Pass NOCHECK 25.000 10. s00 Errors QC Pass QC Fail Value 2.0000 50.000 Range 10.500 10.500 L.7999 Q43 .s27 Q1 .7782 Q43.1,75 1.8250 Q43.906 Se/1 ppm .451 6B .0079L 1.7290 .457 06 .45009 .46588 QC Pass NOCHECK 2.0000 10.500 Zn B_ ppm ppm 1.8700 Q1.7004 .0323 .0274 I . 7 291 1, .2426 1.8568 Q1.69ss 1. 83e3 Q1 .6821, 1.9038 Q1.723s QC Pass QC Fail Appendix F - 314 NOCHECK QC FaiI QC Pass 1.0000 s0.000 10. s00 10. s00 #r #z #: Errors .927 Bs . 917 20 . 93 497 QC Pass 309 Analysis Report Value 1.0000 Range 10.500 EIem Ti UniLs ppm Avge 1.8699 SDev .0242 ?RSD 1.292s #r #z #: 1.8588 1.8463 L .8946 QC Standard 2.0000 10.500 2.0000 10.500 Sn Si ppm ppm 1.8191 Q1.7760 .0284 .0264 1.5505 1 .48s9 1. B19B Q1 .7'750 !.791_2 Q1 .7s01 1.8480 1.8029 03/to/06 o9:72:72 PM 2.0000 10.500 P_ ppm 1.9155 .0247 I .2857 1 . 91,64 1. B91B 1.94L2 2.0000 10.500 Pb ppm . 457 93 .00727 1.5872 2.0000 10.500 Se ppm .45051 .00611 1.3563 2.0000 10.500 7 NOTUSED .45769 .44988 .4s078 Q. 4 4489 .46s31 .45705 Errors QC Pass QC Pass Value 2.A000 2.0000 Range 10.500 10.500 QC FaiI QC Pass QC Pass QC Pass 2.0000 2.0000 .50000 .50000 10.500 10.500 10.500 10.500 Intstd 1 Mode Counts EIem Y Wavlen 37 1. 03 0 Avge 243'/ 1, SDev 369. B 955 ?RSD 1.577754 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 315 #r #z #: 24222 247 92 241_O O I 310 : Analysis Report Method: TRA20505 Sample Name: CCBT Run Time : 0 3 / 10 / 06 27 :72 :76 Comment : Mode: CONC Corr. Factor: 1 03/70/06 o9::-B:26 PM Operator: page 1 Cd Ca ppm ppm - .00009 .00814 .00010 .00079 1,14. 83 9.6884 Elem AI Unit s ppm Avge -.04929 SDev .00295 ?RSD s.9928 #r #z #: 05254 04854 0467 B Errors LC Pass High .10s00 Low - .10500 Elem Cr Units ppm Avge -.00012 SDev . 00 064 ?RSD 547 .64 #r #z #: .00057 - .00022 - .00070 Errors LC Pass High .00360 Low - .00360 Elem Mn Units ppm Avge .00044 SDev .00009 ?RSD 2t .066 #r #z #: 000s2 00034 00047 Errors LC Pass High .00180 Low - .00180 Elem T1 Units ppm Avge - .00013 SDev .00180 zRsD 1_37 8 .3 #r #z #3 Errors - . 0 0221, .00093 .00089 LC Pass LC Pass LC Pass .01400 .00330 - .01400 - .00330 LC Pass LC Pass .00150 .00180 -.00160 - .00180 LC Pass LC Pass .00082 .05s00 - .00082 - .05500 Sb ppm -.00303 .00130 42 .947 -.00439 -.90290 - .00180 Co ppm - .00032 .00049 153 .95 K- ppm .0s095 .00281 5 .6285 .04804 .05104 .0537'7 V_ ppm - .00095 .00120 726 .54 -.00216 .00023 - .00091 LC Pass As ppm .00008 . 0 0l.07 1351.5 .00058 .00081 - .00115 Ba ppm -.00024 .00072 s1.90s - .00038 - .00015 - .00019 Fe ppm - .000s8 .00758 1306.1 - .00754 .00750 - .00170 Se/t ppm .0032s . 0 0 469 144.53 .00845 - .00066 .00195 B_ ppm .00250 .000'77 28 .477 .00332 .00204 .0021,4 Be ppm .00097 .00009 8.97t4 .00090 . 0 01,07 .0009s Pb/ t ppm .00000 .00591 205070. .00648 - .00507 - .00140 Se/z ppm - .00053 .00193 306.99 -.00247 .00138 - .00080 Mo ppm .00774 .00053 35.997 . 0 01,57 .00244 . 0 01,22 LC Pass - .00001 - .00019 - .00005 Pb/2 ppm .00020 .00250 7231.1 -.00266 .00t92 .0013s Ag ppm -.002L9 .00a32 74 .7 41, 0 0257 0 0202 00199 Lr ppm .00072 .000t2 76 .427 .00083 .00073 .000s9 LC Pass 001 66 00905 00771: Mg ppm - .00086 .00396 460 .99 -.00484 .00308 - .00082 Na ppm - .16155 .15547 1,02 . 43 .021,22 - .30117 -.2041 0 Sr ppm - .00003 .00004 148.64 - .00007 .00001 - .00003 LC Pass Cu ppm H. 0 0925 .00039 4 .7837 - . 00084 H. 00886 . 00 012 H. 0 0954 -.00023 H.00924 LC Pass LC High .00220 .00700 -.00220 -.00700 LC Pass NOCHECK NOCHECK LC Pass .44900 .04900 -.04900 -.04900 LC Pass LC Pass .32200 .00380 - .32200 - .00380 NOCHECK NOCHECK LC Pass LC Pass .00970 1.4730 -.00970 -1.4730 Ni ppm - .00034 .00042 723.86 .00007 -.00032 -.0007't Zn ppm .00002 .00016 953 .72 - .00017 .00008 .0001s LC Pass LC Pass Appendix F - 316 311 Analysis Report 03/L0/06 o9:tB:26 PM page 2 .00270 .00130 -.00270 - .00130 Se ppm .00096 .00051 52.724 .00145 .00099 .00044 NOTUSED NOTUSED High Low 01000 .01000 .00500 -.00s00 Sn ppm .00108 .00110 101. B9 .00274 - .00006 .00115 .00380 -.00380 Si ppm - .02248 .00323 74 .3 81 - .02554 - .01910 - .02280 .03100 - .03100 P- ppm . 0 01,47 . 0 0115 79.084 .00222 .00013 .00205 LC Pass .02100 - .02100 4 NOTUSED .00880 - .00880 Pb ppm .00060 .00045 7 5 .229 .00087 .00008 .0008s Elem Ti Units ppm Avge .00001 SDev . 00 024 ?RSD 4239 .9 #t- #z #3 -.00027 .00020 .00009 Errors LC Pass High .00150 Low .00160 Intstd 1 Mode Count.s EIem Y Wav1en 371,.030 Avge 2457 O SDev 1,49 . 15 5 3 ?RSD .6071,1,69 #r #z #: 2467 5 24535 24399 LC Pass LC Pass .00'770 .05500 -.00'770 -.05500 NOTUSED NOTUSED LC Pass LC Pass .00370 .00430 -.00370 - .00430 5 NOTUSED Appendix F 317 O 3L2 Analysis Report Method: TRA20505 Sample Name: H0A17 Run Time: 03/70/05 2:..:18:30 CommenL : Mode : CONC Corr. Factor: 1 03/to/05 oe :39 PM Operator: Elem Units Avge SDev ZRSD #r #z #: Errors T1 ppm - 00L29 .0071,4 B7 .9s8 .00044 .00086 .00258 LC Pass Sb ppm .01239 .00180 1,4.538 .01198 .01436 .01083 Co ppm .00362 .00019 5.1224 .00383 .00357 .00347 LC Pass 100.00 -.05000 K_ ppm 1,.7 336 .0055 .32518 1.1351 1,.7273 1.7 383 LC Pass 200. 0 0 -5.0000 V_ ppm - .00014 .000'79 574.06 .00013 .00048 -.00103 LC Pass As ppm .00239 .00018 7.3817 .00225 .00234 .00259 Cu ppm .49254 .00119 .24L7 5 .49324 .49115 .49321, LC Pass s0.000 - .02s00 Ni ppm .0372-7 .00078 2 .0939 .03-792 .03 64L .03750 LC Pass 100.00 - .04000 Zn ppm 7 .57 65 . 0192 .253 B B 7.5590 7 .5622 7 .5984 Ba ppm . 451,7 0 .00030 .06697 .45197 .45131 . 45l-,7 5 Fe ppm 9.0442 .0185 .20420 9.0s09 9.0233 9.0583 Se/t ppm .00645 .00258 40. 023 .00615 .00404 . 0 0 91,'7 B_ ppm .07290 .00029 . 3 97 01, . a7 3 04 . 07 256 .07308 Be ppm .0008s .00009 11.155 .00 074 .00090 .00090 Pb/1- ppm . 0B 61,7 .00330 3 .8261, .08612 .08263 .0891s Se/2 ppm .00226 .00045 20.007 .00195 .002-tB .00206 Mo ppm .00185 .00023 72 .445 .00206 .00161 .00188 LC Pass Cd ppm .00277 .00007 2 .69s7 Pb/2 ppm . 0B 528 .00079 .931s6 .08452 .08611 .08520 Ag ppm .01492 .00029 2 .4725 . 01l-9 6 . 01462 . 0121,9 LC Pass 4.0000 - .02000 Li ppm .00185 .00008 4.1994 .00190 .00188 .00l.76 LC Pass page 1 Ca ppm 13.211 .044 .33558 Mg ppm 1.0a02 .0015 .15373 1.0088 1.0101 1.0119 Na ppm 2 .9599 .1,1_4'l 3.86l-2 3.0749 2.8475 2 .981 4 LC Pass 800.00 -5.0000 Sr ppm .08452 .00007 .08266 .08448 .08449 . 0B 46A LC Pass EIem AI Units ppm Avge 5.6900 SDev .0l-.26 ZRSD .2207 4 #r #z #: 5.6850 s.5806 5 .7 042 Errors LC Pass High 700.00 Low - .20000 Elem Cr Units ppm Avge .4454 0 SDev . 0 01,02 ?RSD .22873 #r #z #: .44456 .44498 .44656 Errors LC Pass High 100.00 Low -.01000 EIem Mn Units ppm Avge .05288 SDev .00046 ?RSD .73585 #r #z #3 0634a 0 5265 0 6257 Errors LC Pass High 30.000 Low - .01500 LC Pass LC Pass 20.000 30.000 -.06000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00s00 .00259 13 . A99 .00265 13. t74 .00279 13.261, LC Pass LC Pass 40.000 600.00 - .00s00 -s.0000 LC Pass NOCHECK NOCHECK LC Pass 1400.0 700.00 - .10000 -5.0000 NOCHECK NOCHECK o LC Pass LC Pass Appendix F - 318 313 Analysis Report 03/LO/06 oe :39 PM 5.0000 - .05000 Se ppm .00395 .00069 1,7 .550 .00364 .00349 .00476 page 2 10.000 - .05000 High Low 70.000 -.02000 100.00 - .02500 1653s 15401 1,6 632 10.000 -.02000 t4 .297 t4.390 74 .455 40.000 - . s0000 P_ ppm 1'. 0 4]-7 .0051 . s8859 1.0397 1.0369 1.0486 40.000 -.04000 Pb ppm .08595 .0008s .99362 .08553 ..0 B 532 . 0B 693 Blern Ti Units ppm Avge .023 3 5 SDev .00014 ?RSD .59250 #r #z #: . 023 47 .023 3 I .02320 Errors LC Pass High 40.000 Low -.05000 Int.St.d 1 Mode Counts EIem Y Wavlen 371.030 Avge 24354 SDev 103 .97 85 ?RSD .4259390 #r #z #: 24245 24451, 243 67 Sn Si ppm ppm .15522 l.4.381 .00116 .079 .70277 .55145 LC Pass LC Pass LC Pass 40.000 40.000 40.000 -.10000 -1.0000 -.30000 NOTUSBD NOTUSED 4 NOTUSED LC Pass LC Pass 70.000 30.000 - .00400 - .01000 NOTUSED NOTUSED NOTUSED Appendix F - 319 3L4 Analysis Report Method: TRA20505 Sample Name: H0A2Q Run Time: 03/70/06 2t:24:43 Comment : Mode: CONC Corr. Factor: 1 03/to/06 o9:30:52 PM Operator: Sb ppm .006l.5 .00083 13 . 492 .00554 . oo 71,0 .00583 Co ppm .00556 .00018 3.3015 .00555 .00575 .00s38 K- ppm 2 .8220 .0097 .3 42tB 2 . 8111 2 - 829'l 2 . B25A LC Pass 200.00 -5.0000 V.- ppm .00308 .00051 15 . 574 .0028L .00367 .00271 LC Pass As ppm .00590 .00022 3.7071 .00578 .00515 .00s75 Cu ppm .55405 .00250 .38296 .55379 .55169 .5s668 Ni ppm . 0 4493 .00038 .83719 . 04 498 . 0 4527 . o4453 Zn ppm 8.3051 .0409 .49288 8.3009 8.34'79 8.2564 Ba ppm . 15 442 .00020 .1,2446 .),6460 .76420 .46446 Fe ppm 7 .4940 .0L47 .98379 t.48B5 1. s106 t .4828 Se/7 ppm . 0 1L1,4 . 0 01,42 72 .'7 52 .00978 . 01262 .01103 B- ppm .09188 .00151 L .1 582 .09239 .09318 .09007 Be ppm .0010s .00009 8.5628 .00098 .00a02 .00115 Pb/ 7 ppm .39730 .00500 I .2597 .39473 . 403 07 .3941,7 Se/z ppm .00941, .00063 6.7 350 . 0101 0 .00885 . 0 0 927 Mo ppm .00188 .00064 33.829 .00236 .002L2 . 0 0115 LC Pass Cd pprn .00363 .00013 3 . 61,52 Pb /2 ppm .39759 .00254 . 53 914 .39558 .40 04 B . 3 9 662 00899 01020 00820 Li ppm .0021,5 .00005 2 .21,2L .0021-2 .00221, .00213 LC Pass page 1 Ca ppm 22.083 . 118 . 53 428 Mg ppm 2 .2346 .0169 .75853 2 .2295 2.2s35 2 .2208 s.8163 6.0100 5.574a Sr ppm .14292 .00020 .74244 . L4292 . L427 2 .L43 13 LC Pass Elem A1 Units ppm Avge 9.5786 SDev .0188 zRSD . 19 667 #r #z #3 9.551 5 9.5846 9.5937 Errors LC Pass High 700.00 Low -.20000 EIem Cr Units ppm Avge .2243 B SDev .00198 ?RSD .88252 #r #z #3 .22393 .226 5 5 .22266 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .06688 SDev .00008 ?RSD .12094 #r #z #: 0657 9 05591 06693 Errors LC Pass High 30.000 Low -.01500 Elem TI Units ppm Avge -.00027 SDev .00095 ?RSD 354 .45 #l- #z #: Errors - . 0 0042 .00075 - .00114 LC Pass LC Pass LC Pass 20.000 30.000 - .05000 - .01000 LC Pass LC Pass 30.000 10.000 = .01000 - .00500 .003s3 22.033 .00378 22.278 .00359 2t.998 LC Pass LC Pass 40.000 600.00 -.00s00 -s.0000 LC Pass LC Pass 100.00 50.000 -.0s000 -.02s00 LC Pass NOCHECK 1400.0 - .10000 NOCHECK LC Pass 700.00 -5.0000 Ag Na ppm ppm .00913 5.8334 .00101 .1686 11.040 2.8905 LC Pass NOCHECK 100.00 -.04000 NOCHECK LC Pass LC Pass 4.0000 800.00 -.02000 -5.0000 LC Pass LC Pass Appendix F - 320 315 Analysis Report High Low 70.000 - .02000 100.00 - .02500 Sn ppm .05544 .00068 1.2269 .05475 .05611 .05s45 10.000 -.02000 Si ppm L4 .7 55 .047 . 3151,7 14.704 L4 -794 1,4 .7 69 40.000 - .50000 P_ ppm 28 .532 .31,7 1.1103 28.672 28 .7 55 28.A70 LC Pass 40.000 - .30000 4 40.000 - .04000 .395'74 .40185 .39508 LC Pass 70.000 - .00400 5 s.0000 - .05000 .01033 .01040 . 01 015 LC Pass 30.000 -.01000 5 page 2 10.000 - .05000 o3 /ao / o6 09:30:52 PM EIem Ti Units ppm Avge .01285 SDev .00005 ?RSD .352L0 #r #z #: OL2B9 O12BB 01280 Errors LC Pass High 40.000 Low -.05000 Int Std 1 Mode Counts Elem Y Wavl en 37 1,. O 3 0 Avge 23 8'7 7 SDev 487.3919 ?RSD .7848331 #r #z #3 23 81,7 237 26 24087 Pb Se ppm ppm .39789 .01029 .00343 .00013 .85260 7.2826 LC Pass LC Pass 40.000 40.000 - .10000 -1.0000 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 321 316 Analysis Report Method: TRA20505 Sample Name: H0HR4 Run Time: 03/:-0/oG 2t:30:5G Comment : Mode: CONC Corr. Factor: 1 03/rc/a6 o9:37:05 pM OperatoL: page 1 Cd Ca ppm ppm -.00003 .20572 .00003 .00348 11,4.52 1.6948 EI em A1 Units ppm Avge - .03725 SDev .00307 ?RSD 8.2322 #r #z #: -.03'794 - .03390 - .03992 Errors LC Pass High 700.00 Low - .20000 EI em Cr Units ppm Avge - .00031 SDev .00025 ?RSD BO.2]-7 #r #z #: 00002 00045 00045 Errors LC Pass High 100.00 Low - .01000 Elem Mn Uni t. s ppm Avge .00099 SDev .00 O2B ?RSD 28 .57 9 #r #z #: 00092 0007s 00130 Errors LC Pass Hi-gh 30.000 Low .01500 EIem T1 Units ppm Avge - .00051 SDev .00053 ?RSD 104.89 #t- #z #: Errors - .00041 - .00108 - .00003 LC Pass Sb ppm .00107 .00724 11s .7 6 .00241, -.00003 .00082 LC Pass 20.000 - .05000 Co ppm .00018 .00037 209 .29 .00051 .00024 -.00022 K- ppm .06s93 .01010 1s.315 .07730 .05799 .05257 V_ ppm .00055 .00062 113 . 42 . 0 0 1_1,4 .00060 -.00010 LC Pass As ppm .00083 .00749 180.47 .00249 .00035 - .00037 LC Pass 30,000 - .01000 Cu ppm .012l-3 .00089 7 .3324 .01784 . 011,43 .01313 Ni ppm .00025 .00044 71 9 .48 .00050 .00051 -.00027 Zn ppm .0257 4 .00088 3.2880 .02770 .02s98 .o2653 Ba ppm .00298 .00077 5.7725 .00293 .00284 .00377 Fe ppm .01541 .00805 52 .322 .02355 .01505 .007s3 Se/t ppm .00188 .00l-64 81 .l-94 .00072 .00115 .00375 Be ppm .00097 .0001,2 72.303 .00083 .00105 .00103 Pb/ t ppm -.0023a .00159 69.273 -.00376 -.00254 - .00060 Se/2 ppm . 0 0l-47 .00159 108.01 .00294 .00769 -.00022 Mo pprn .00081 .00037 45 .502 .00704 .00101 .00038 LC Pass .00001 - .00005 -.00004 Pb/2 ppm .001,94 .00067 34 .6s2 .00247 .0022s .00a]-7 Ag ppm - .00199 .00095 47.779 - .00089 -.00259 -.00248 Li ppm .00031 .00004 13 .110 .00027 .00029 .0003s LC Pass 20892 202].0 20435 Mg ppm .02820 .00275 9 .7 515 . 03 tt6 - 027'7 4 . 0257 I Na ppm - .11087 . 04 644 4t. BB4 - .05909 -.14882 - .12410 Sr ppm .00068 .00003 4 .251-2 .00071 .0005s .00067 LC Pass LC Pass LC Pass 30.000 10.000 - .01000 - .00500 LC Pass LC Pass 40.000 500.00 - .00s00 -s.0000 LC Pass LC Pass 100.00 s0.000 - .05000 - .02500 LC Pass NOCHECK 1400.0 - .10000 NOCHECK LC Pass 700.00 -5.0000 LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHECK NOCHECK LC Pass LC pass 4.0000 800.00 -.02000 -5.0000 B_ ppm .00328 .00039 11 . 9-12 .00373 .0030s .00305 Pass LC Pass Appendix F - 322 LC 3L7 Analysis Report 03/70/06 o9:37:05 PM page 2 High 70.000 100.00 10.000 40.000 40.000 5.0000 10.000 Low -.02000 - .02500 - .02000 - .50000 -.04000 -.05000 - .0s000 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge .00058 .01007 .27707 .02357 .00086 .00190 SDev .00012 .00012 .03863 -00672 .00012 .00054 ?RSD t7 -504 1.1519 13.943 28.511 74.446 28 -278 #1 .00082 .01019 .32062 .03114 .00073 .00249 #2 .00051 .00996 .26365 " .021-27 .00.098 .00180 #3 .00061 .01005 .24594 .01830 .00087 .00143 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low - .05000 - .10000 -1.0000 - .30000 -.00400 - .01000 Intstd 1 Mode Counts EIem Y Wavlen 371-.030 Avge 24480 SDev 4 01 .A7 07 ?RSD 1.538745 #r 24018 #z 24737 #: 24686 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 323 o 318 Analysis Report Method: TRA20505 Sample Name : H0HHKZ10 Run Time: 03/I0/06 27: 37:09 Comment : Mode: CONC Corr. Factor: 1 03/70/06 o9:43:18 PM Operator: page 1 Cd Ca ppm ppm -.00009 .02323 .00004 .00075 42.279 3 .2929 EIem AI Units ppm Avge - .03351 SDev .00482 %RSD t4 .37 9 #r #z #r - . 02863 - .03352 - .03827 Errors LC Pass High 700.00 Low - .20000 El em Cr Units ppm Avge . 00L7 4 SDev .00055 %RSD 37 .454 #r #z #: .0010s .00234 . 0 0182 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .01293 SDev .00011 ?RSD .85550 #r #z #3 .01284 . 013 02 . 01297 Errors LC Pass High 30.000 Low - .01500 Elem TI Units ppm Avge .00332 SDev .00779 %RSD 53.988 #t- #z #: Errors .00498 .00142 .00355 LC Pass LC Pass LC Pass LC Pass 20.000 30.000 30.000 -.05000 -.01000 -.01000 Sb ppm - .00007 . 00 041 573 .47 -..00035 .00048 - .00034 Co ppm - .00018 .00038 208.31 - .00052 .00023 -.00027 K- ppm .03893 .00788 20 .23-7 .04314 .04381 .02984 V- ppm -.00297 .00181 60.802 -.00442 - .0009s -.00354 LC Pass As ppm .00082 .00015 1B. OBB .00094 .00086 .00065 Cu ppm .01479 .00133 8.9899 .01326 . 01 562 .01550 Ni ppm .00t87 .00051 32 .892 .00258 .001s9 .00145 Zn ppm .00330 .00007 2.2309 . 0 0323 .00337 .00330 Ba ppm .00035 .00005 13 .587 .00039 .00039 .00030 Fe ppm .13030 .00895 5. B7'12 .13004 . 13 93 9 .72L4B Se/r ppm .00320 .00075 23 .27 2 .00257 .00302 .00402 B- ppm .00082 .00079 96 .564 .00168 .00066 .000L2 Be ppm .00096 .00013 13. 094 .00082 . 0010 3 .00104 LC Pass 10.000 - .00500 Pb/1. ppm - .00017 .00267 153 0 . 1 .00062 - .00315 .00201, Se/2 ppm - .000s2 .00l.29 246 . O-l - .00180 .00077 - .00053 Mo ppm .00038 .000l-7 45 .604 .000s8 .00029 .00027 LC Pass LC 40 Pb/ 2 ppm .00043 . 0 0a20 280 .44 Ag ppm - .00295 .00061 20 .534 -.00270 -.00252 - .0035s .00087 .00079 .00058 LC Pass Mg ppm 111 . 11 1, .23 1.1037 Na ppm - .24365 .04370 L7.935 - .20428 -.23600 - .29061 .00002 .00006 .00000 LC Pass 00009 .02240 00014 .02391 00006 .02337 Pass LC Pass .000 500.00 00500 -5.0000 LC Pass LC Pass 100.00 50.000 - .05000 - .02s00 LC Pass NOCHECK 1400.0 - .10000 -.00057 111 .87 .00l-72 111 .16 .00024 109.69 NOCHECK LC Pass 700.00 -5.0000 LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHECK NOCHECK LC Pass LC Pass 4.0000 800.00 - ,02000 -s.0000 Li Sr ppm ppm .00078 .00002 .00009 .00003 t2 .062 !!7 . 5 5 LC Pass LC Pass Appendix F - 324 319 Analysis Report 03/1,0/06 o9:43:18 PM page 2 High 70 - 000 100.00 10.000 40.000 40.000 s.0000 10.000 Low -.02000 - .02500 -.02000 -.50000 - .04000 - .05000 -.05000 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge .00018 .00174 .36325 .00491 .O0O72 .00100 SDev .00011 - 00034 .01088 -0021,2 .00054 .00096 ?RSD 61-.302 L9 .428 2.9945 43 .062 75 -376 95 .550 #1 .00009 .00213 .37188 .00662 .00025 - .00006 #2 .00030 .00152 .35585 .00555 .00058 .00180 #3 .0001s .001s7 .3s103 .002s5 .00131- .oot27 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low - .05000 - .10000 -1 .0000 - .30000 - .00400 - . 01000 Intstd 1 Mode Counts EIem Y Wavlen 311. 03 0 Avge 245t.5 SDev 27 A. 83 3 5 ?RSD 1.100290 #r 24350 #3 24892 #z 24602 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 325 320 Analysis Report Method: TRA20505 Samp1e Name : H0HRB Run Time : 0 3 / t0 / 0G 2t :43 :22 Comment : Mode: CONC Corr. Factor: 1 03 /to / 06 o9 : 49 :31 pM OperatoL: EIem A1 Units ppm Avge - .03858 SDev .00351 ?RSD 9.2462 #r #z #s -.03787 -.04244 -.03s41 Errors LC Pass High 700.00 Low -.20000 EIem Cr Units ppm Avge -.00071 SDev .00052 ?RSD 73.180 #r #z #s 00050 00130 00032 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge . 0 01,57 SDev .00010 ?RSD 5.6'749 #r #z #: 00a74 00156 0 0171 Errors LC Pass High 30.000 Low - .01500 EIem TI Units ppm Avge -.00082 SDev .00251, ?RSD 308.11 #r #z #: Errors .00l-94 -.00297 -.00742 LC Pass LC Pass LC Pass 24.000 30.000 - .05000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00500 page 1 Cd Ca ppm ppm -.00010 .45479 .00008 .00464 78.514 1.0195 -.00004 45774 -.00018 .44944 - .00007 .45718 LC Pass LC Pass 40.000 500.00 - .00500 -5.0000 Pb/2 ppm .0026s .00098 37.099 .00265 .00363 .00757 Mg ppm .02587 .00227 8.7740 .02836 .02391 .02534 Ag Na ppm ppm -.00304 2.]-339 .00080 .737s 26.389 6.4436 Sb ppm -.00094 .00138 747.36 .00042 - .00088 - .00235 Co ppm .00002 .00023 71,47 . g .00028 - .00015 - .00006 LC Pass 100.00 - .0s000 K- ppm .11908 .01244 10 . 444 . L2520 .10477 .127 27 V_ ppm .00034 .00066 191 .22 .00093 - .00035 .00046 LC Pass As ppm - .00005 .00097 1653.7 -.00113 .00021 .0007s Cu ppm . 0157 6 .00054 3 .4272 .01634 .0155s .01528 Ni ppm .00613 .00005 .77851 .00675 . 0 0 656 .0061 6 Zn ppm .01047 .00015 1.5592 . 01066 .01035 .01040 Ba ppm .00532 .00003 .63069 .00535 .00529 .00s30 Fe ppm . 03 624 .00509 74.053 . 03 667 .03095 .04111 Se/r ppm - .00117 .00281 245. 1 B -.00401 -.00122 .00712 Be ppm .00081 .00010 11. 842 .000-71 .00090 .00081 Pb/1, ppm - .00359 .00229 62.008 - .0036s - .00600 - .00L42 Se/z ppm .00160 .00019 t2 .161 .00139 .001-54 .00L7B Mo ppm .00108 .00048 44.078 .00140 .000s3 .00131 LC Pass -.00214 -.0039s -.00243 Lr ppm .00089 .00011 t2 .18 0 .0009s .00076 .0009s LC Pass 2 .27l-2 1.9752 2 .2754 Sr ppm . 0 0a52 .00003 I .6669 .001s4 .00L49 .00153 LC Pass LC Pass LC Pass 50.000 1400.0 - .02s00 - .10000 NOCHECK NOCHECK LC Pass 700.00 -s.0000 LC Pass LC Pass 200.00 100.00 -s.0000 - .04000 NOCHECK NOCHECK LC Pass LC Pass 4.4000 800.00 -.02000 -5.0000 B- ppm .00s98 .00055 9 . 1436 .00640 .00536 .006l-9 Pass LC Pass Append ix F - 326 LC 327 Analysis Report 03/to/06 o9:49:31 PM page 2 s.0000 10.000 - .0s000 - .05000 Se ppm .00097 .00108 111.93 - .00012 .00097 .00205 High Low 70.000 - .02000 100.00 - .02500 Sn ppm .01838 .00062 3.3518 . 017 82 . 01 829 .01904 LC Pass 40.000 - .10000 2 EIem Ti UniLs ppm Avge .00103 SDev .00023 %RSD 22 .\7 9 #r #z #: .007L4 .00077 .00119 Errors LC Pass High 40.000 Low - .05000 Intstd 1 Mode Counts Elem Y Wavlen 371.030 Avge 24424 SDev 239.7484 ?RSD .9815940 #r #z #g 242A0 24683 24380 Si ppm .20036 . 0 0 404 2.0184 .24498 .19743 .19859 P_ ppm .35355 .00044 .12494 .35390 .35392 .35314 10.000 40.000 - .02000 -.50000 40.000 - .04000 Pb ppm .00087 .00011 1,2.513 .00088 .00075. .00097 LC Pass LC Pass 70.000 30.000 - .00400 - .01000 LC Pass LC Pass 40 .000 40.000 -1.0000 -.30000 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F 321 322 Mode: CONC Corr. Factor: Analysis Report Method: TRA20505 Run Time: 03/l-0/06 CommenL: Sample Name: H0HEH 2a : 49 :35 03/ta/06 o9:55:45 PM Operator: page 1 Cd ppm .00778 . 00 025 3 . 2518 .00805 .00755 .00173 Ca ppm 9.3s25 .127 5 1.3533 .4962 .2528 .3087 Pb/ 2 ppm .08043 .0018s 2 .297 s Mg ppm 13 . 3 93 .184 1.3708 .0'7946 13.603 .08256 13 .264 .07927 13.311 NOCHECK LC Pass 700.00 -5.0000 Ag Na ppm ppm -.00131 1.038-/ .00120 .3133 9A.476 30.151 - .00002 -.00239 -.00153 1.374"7 .7 54s4 .98589 LC Pass LC Pass 4.0000 800.00 -.02000 -s.0000 Elem Units Avge SDev ?RSD #r #z #: Errors High Low Elem Units Avge SDev ?RSD #r #z #: Errors High Low El em Units Avge SDev %RSD #r #z #: A1 ppm 2.3132 .0285 7.2008 2.4050 2.3587 2.3548 LC Pass 700.00 - .20000 Cr ppm .06764 .00183 2 .967 A .05373 .05033 .06087 LC Pass 100.00 - .01000 Mn ppm .11585 .00l-94 1,.6724 .11809 .11470 . 11 471 Sb ppm .00814 .00051 7.5385 .007q3 .00884 .007'74 Co ppm .01383 .00031 2.233s . 01 41-9 .01366 .0136s LC Pass 100.00 - .05000 K- ppm .32038 .01880 5 . B 695 . 3 4725 .30474 .31s16 V- ppm .01006 .00028 2 . 83-22 .01034 .01006 .00977 LC Pass As ppm .00736 .00059 7.9534 . 0 0174 .00803 . 0 0 692 Cu ppm .11585 .00449 L.2891 . 117 50 .11546 .11459 Ni ppm .08246 .00160 1. 9444 .08424 .08113 .08200 Zn ppm 3.4185 .0451 1.3782 3.4700 3.3865 3.3990 Ba ppm .10204 . 0 011,7 1.1454 .10337 .10159 . 10ll'7 LC Pass 30.000 - .01000 Fe ppm 6.3202 .0998 1.5784 6.4353 5.2590 6.2664 Se/r ppm .00230 .00338 t4'7 . 15 .00s56 - .00119 .00253 Be ppm .00081 .00029 36.260 .00047 .0009s .00101 LC Pass 10.000 - .00s00 Pb/1, ppm . 07 821, .00481 6.1,545 .08347 .07403 .077L2 NOCHECK Se/z ppm .00051 .00090 11 8.50 .00079 .00723 -.00051 NOCHECK Mo ppm . 01 832 .00045 2 .4593 .01880 .01824 . 017 91, LC Pass 9. 9 9 LC Pass LC Pass 20.000 30.000 - .05000 -.01000 LC Pass LC Pass 40.000 600.00 -.00500 -s.0000 LC Pass LC Pass 50.000 1400.0 - .02500 - .10000 Errors LC Pass LC Pass High 30.000 200.00 Low -.01500 -5.0000 LC Pass NOCHECK 100.00 -.04000 o EIem Units Avge SDev ?RSD #r #z #: Errors T1 ppm .00018 .001,46 7 92 .54 -.00].20 .00004 .001,71, LC Pass Li ppm .01159 .00021, 1.8311 .01a82 .0174L . 011s 3 LC Pass Sr ppm .0552s .000-/1, t .2663 .0570-7 .05589 .05580 LC Pass B_ ppm .01280 .00114 8.9263 .01383 .01757 .01300 Pass LC Pass Append ix F - 328 LC 323 Analysis Report 03/to/05 o9:55:45 PM page 2 High 70.000 100.00 10.000 40.000 40.000 5.0000 10.000 Low -.02000 -.02500 -.02000 -.50000 - .04000 -.05000 -.05000 EIem Ti Sn Si P- Pb Se Units ppm ppm ppm ppm ppm ppm Avge .08904 .02920 2.1388 .54815 .08014 .00140 SDev .00154 .00149 .0285 .00471 .00107 .001-10 uRsD L.7292 5.1033 L.3323 .85933 1.3315 78.575 #1 .09082 .03079 2.l-'77s .55242 . OB11B .00258 #2 -08822 .02'184 2.L252 .54893 ..08021 . OOO75 #3 .08809 .02896 2.1,-t-96 . s4310 .07904 - 00079 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.05000 -.10000 -1.0000 -.30000 -.00400 -.01000 Intstd l Mo,Ce Count s EIem Y Wavlen 3'7 \. 0 3 0 Avge 24381- SDev 503.6510 ?RSD 2 .065829 #r 23'799 #z 24668 #g 2467 s 234567 NOTUSBD NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 329 324 Analysis Report Method: TRA20505 Samp1e Name: H0HE0 Run Time: 03/L0/06 21,:55:49 CommenL : Mode: CONC Corr. Factor: 1 03/to/06 10:01:58 pM Operat or : page 1 Cd Ca ppm ppm - .00013 .13805 .00008 .00075 62.901 .54302 Elem A1 UniEs ppm Avge .3584'7 SDev .0021,6 %RSD .50l.32 #r #z #: .35877 .36047 .356L9 Errors LC Pass High 700.00 Low - .20000 EIem Cr Units ppm Avge .0046L SDev .00017 ?RSD 3 .6L32 #r #z #: 00451 00480 o o 452. Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge .00583 SDev .00009 ?RSD 7 .4s1,4 #r #z #: .00sBB .00sBB .00573 Errors LC Pass High 30.000 Low -.01500 El em TI Units ppm Avge .00242 SDev .001,29 ?RSD 53.410 #r #z #: Errors .00354 . 0 0101 .00270 LC Pass Sb ppm - .00002 .0002l. BBB. O1 - .00001 -.00024 .00018 LC Pdss 20.000 - .05000 Co ppm .00041 .00025 62.352 .00065 .00043 .00014 K- ppm .15578 .00509 3.2699 . 15 694 . 15 019 .15020 V- ppm .001,66 .00038 22.780 .00209 .00t L . 0 01,47 LC Pass As ppm .00049 .00067 137. B5 .00113 .00053 - .00021 LC Pass 30.000 - .01000 Cu ppm .02998 .00013 .42398 .03004 .03005 .02983 Ni ppm .01002 .00023 2.2556 .01029 .00990 .00988 Zn ppm .01556 .00007 .42669 .01552 .01556 .01549 Ba ppm .00472 .00004 .7 9213 .00476 .00469 .0047L LC Pass 30.000 - .01000 Fe ppm .643s6 .00449 .7 3220 .61587 .61542 .50838 Se/t ppm .00111 .00155 t40 .32 .00).62 .00234 - .00064 B- ppm .00431, .00029 6 .715 3 .00440 .00454 .00399 Be ppm .00115 .000a2 1.9026 .001,L7 .00113 . 0 0115 Pb/L ppm .00989 .00054 5 .47 63 .01039 .00932 .00996 Se/z ppm .00058 .00068 1,1,1 .45 - .00014 .00056 .001,22 Mo ppm .001,64 .00020 t2 .10 s .00a69 .00181 .00L42 LC Pass 00005 00013 00021 Pb/2 ppm . 01518 .00]2s B .2442 .01662 .014s5 .01437 00190 00163 0 0222 Li ppm .00083 .00003 3 .3A76 .00086 .00082 .00081 LC Pass 13860 13838 1,37 21, Mg ppm .10995 .00307 2.'7 935 .11228 . 1 1 1,1_4 .10648 3.1139 3.2060 3 . 0 91-'7 Sr ppm .00075 .00001 .60814 .00075 .00074 .000'75 LC Pass LC Pass LC Pass LC Pass 10.000 40.000 500.00 -.00500 -.00500 -s.0000 LC Pass LC Pass 100.00 50.000 - .0s000 - .02500 LC Pass NOCHECK 1400.0 - .10000 NOCHECK LC Pass 700.00 -5.0000 Ag Na ppm ppm -.001,92 3.1372 .00030 .0606 '15.479 1.9319 LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHECK NOCHECK LC Pass LC Pass 4 .0000 800.00 - .02000 -5.0000 LC Pass LC Pass Appendix F - 330 325 Analysis Report 03/1,0/06 10:01:58 PM page 2 5.0000 10.000 - .0s000 - .0s000 Se ppm .00105 .00039 37 .499 .00077 .00150 .00088 High Low 70.000 - .02000 100.00 - .02500 Sn ppm .0092s .00069 7 . 5116 .0100s .00893 .00878 10.000 - .02000 Si ppm .43153 .00301 .7]-048 .43354 .43294 .42801 40.000 - .50000 P_ ppm .03000 . 0 0l.42 4.7198 .03100 . 03 062 .02838 40.000 -.04000 Pb ppm . 0137 6 .00091 7.0209 .01487 . 013 17 .01322 Elem Ti Units ppm Avge .02L07 SDev .00011 %RSD .50718 #r #z #: 02L79 02100 02101 Errors LC Pass High 40.000 Low -.05000 Intstd 1 Mode Counts EIem Y Wav1en 37]-. 03 0 Avge 247 92 SDev 94 .65268 ?RSD .38L7807 #r #z ,#3 2483 0 24585 24862 LC Pass LC Pass 40.000 40.000 -.10000 -1.0000 2 NOTUSED LC Pass LC Pass LC Pass 40.000 70.000 30.000 -.30000 -.00400 -.01000 34 NOTUSED NOTUSED s57 NOTUSED NOTUSED NOTUSED Appendix 331 326 Analysis Report Method: TRA20505 Sample Name: H0HE5 Run Time: 03/70/06 22:02:02 Comment : Mode: CONC Corr. Factor: 1 03/t0/06 10:08:11 pM Operator: page 1 Cd Ca ppm ppm - .00002 89.951 .00018 .331 1105.6 .35'764 EIem A1 Units ppm Avge 4 . 0571, SDev .0183 ?RSD .45728 #r #z #3 4.0-759 4.0393 4 .0553 Errors LC Pass High 700.00 Low -.20000 EIem Cr Units ppm Avge . OO 624 SDev .00030 ?RSD 4 .8515 #r #z #s 00s91 00631 006s1 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .08886 SDev .00043 ?RSD .4882-I #r #z #: 08914 OBB35 OB9OB Errors LC Pass High 30.000 Low -.01500 EIem TI Units ppm Avge .00115 SDev .00047 ?RSD 40. 6s1 LC Pass LC Pass 20.000 30.000 - .06000 - .01000 Sb ppm -.00431 .00328 76.133 -.0C-720 -.00499 - . 0 00-l 4 Co ppm .00430 .00008 1 . B 961, .00437 .00421_ .00433 K- ppm . 637 t3 .00869 1.3645 .627 69 .63888 . 6 4487 LC Pass 200.00 -5.0000 V_ ppm .37705 .00228 .60476 .37 923 .37 469 .37 7 26 LC Pass As ppm .00679 .00109 L6.041 .00550 .00705 .00773 Cu ppm .02093 .00051 2 .4207 .02038 .02101 .02138 Ni ppm .1,4093 .00036 .257 l7 .14724 .74053 .74101 LC Pass 100.00 - .04000 Zn ppm .04834 .00029 .60645 .04859 .04841 .04801 Ba ppm .05705 .00025 .44107 .05733 . 0s 699 .05583 LC Pass 3 0 . 0p 0 - .01000 Fe ppm 2.4183 .0239 .98585 2 .42'7 6 2 .3972 2.4351 Se/r ppm .00786 .00237 30.118 .00586 .00725 .01047 B- ppm .02s3 9 .0006s 2.5758 .02508 .02495 - 026a4 Be ppm .00140 .00009 6 . t22B .00a49 .0073-7 .00133 Pb /t ppm .00872 .00396 45.359 .00429 .00998 . 0118 9 Se/2 ppm .001,32 .00165 124 . 82 .00276 .00l-1 0 - .00048 Mo ppm .003s7 .00038 10.776 .00363 .00315 .00392 LC Pass - .00017 89 - .00007 89 .00018 90 Pb/2 ppm .01529 .00237 15.494 .01777 .01504 .01305 B2t 705 327 Pas s .00 0000 Mg ppm 57.857 .313 .45053 68. 044 67 .497 58. O32 1.3021 1.5582 1.8443 LC Pass 800.00 -5.0000 Sr ppm . 46'7 25 .00190 .40680 .46936 .46565 .46675 LC Pass LC Pass LC Pass LC 10.000 40.000 600 -.00500 -.00500 -s. LC Pass LC Pass 100.00 s0.000 -.05000 - .02s00 LC Pass NOCHECK 1400.0 - .10000 NOCHECK LC Pass 700.00 -5.0000 Ag Na ppm ppm - . 00313 1 . s 684 .00066 .2709 2t .244 77 .2-t 2 NOCHECK NOCHECK 00381 00309 a 0248 LC Pass 4.0000 - .02000 Li ppm .06246 .00037 .59543 .05289 . 06 223 . 06 226 LC Pass #r #z #: Errors .00165 .00109 .00072 LC Pass LC Pass LC Pass Appendix F - 332 32'l Analysis Report 03/70/a5 10:08:11 PM page 2 High 70 - 000 100.00 10.000 40.000 40.000 5.0000 10.000 Low -.02000 -.02500 - .02000 - .5O0OO -. O40OO - . O5O0O - .05000 EIem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge .01138 . O15OO 7.31"97 31 .473 .01-353 .00379 SDev .00006 .00075 .0098 .127 .00039 .00031 ?RSD . s0t_09 4.9970 .745s2 .40282 2.8784 8 -2998 #1 . O1l-45 .01431 1.3304 31.618 .01378 .00408 #z .01134 .0.1580 1.3111 3L.382 .01373 .00384 #3 .01136 .01490 L.3777 3a.420 .01308 .00345 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.05000 -.10000 -1.0000 - .30000 -.00400 -.01000 Intstd 1 Mode Counts Elem Y Wavlen 371,.030 Avge 24183 SDev 81.21888 ?RSD .3358475 #r 2427 s #z 24as3 #g 2412L 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - ^la'!JJJ 328 Analysis Report Method: TRA20505 Sample Name: H0HGL Run Time: 03/]-0/05 22:08:15 Comment : Mode: CONC Corr. Factor: 1 03/to/06 1o:74:24 PM Operator: EI em Units Avge SDev %RSD #r #z #3 #r #z #: Errors A1 ppm 7 .29A2 .0391 . 53 s92 '7 .3234 7.3024 7 .247 I . 04 231, .03 654 .03s1s LC Pass Sb ppm .018'7a .00119 6.3423 .01-789 .01877 .02007 Co ppm .19858 .00050 .2507 4 .19BsB .19908 .19808 K- ppm 1, -2050 .0081 . 67 284 1.1958 1,.2083 L . 2110 V_ ppm L- . L4491 .00135 -94150 1,4546 1,443 B 14388 Low As ppm .3s82s .0024s .58320 .35857 .36053 .3ss66 LC Pass 30.000 - .01000 Ni ppm 1.2585 .0093 .7 3227 1,.2580 I .27 53 1,.2725 Zn ppm 4 .867 5 .0249 .51081 4.839s 4 . BB6-/ 4. B'767 Ba ppm 1.9296 .0149 . 7 7113 1 . 93 93 1.93'7]- 1.9725 LC Pass 30.000 - .01000 Se/r ppm .003s8 .00502 1,40 - 20 .00934 .00023 . 0 0115 B- ppm .22569 .00131 .57 987 .22611 . 2267 3 .22422 Be ppm - .00134 .00010 7 .5999 00145 00134 0 0724 LC Pass 10.000 - .00s00 Pb/7 ppm .92814 .00842 . 90 568 . 91 846 . 93 232 .9336s Se/2 ppm .01620 .00924 57.033 .00s63 .02027 . 0227 5 Mo ppm .2697 5 .000s2 .19457 .26946 .26943 .27035 LC Pass Cd ppm .04901 .00524 10.685 Pb/2 ppm .90018 .00979 1- 021,2 . BB9B3 .90332 .90740 Ag ppm .0086-7 - 0 01,27 l.4.533 .00736 .00875 .00989 Li ppm .00755 .00026 3 .407 6 .00727 .00760 .00778 LC Pass page 1 Ca ppm 25.347 .220 .86930 Mg ppm 7 .1002 .0509 .85798 7.03 15 7 .147 B 7 . L2L1, LC Pass 700.00 -s.0000 Na ppm 48 .6 01 . 211, .55697 4B .813 4B .694 48 .296 Sr ppm . 29 628 .00744 .4847 4 .29736 .2968s .29455 LC Pass Errors LC Pass LC Pass High 700.00 20.000 Low -.20000 -.05000 . 05 268 25 .1 03 .04302 25 .4 0 B .05134 25.530 LC Pass LC Pass 40.000 500.00 -.00500 -5.0000 EIem Cr Units ppm Avge 1.0913 SDev .0055 %RSD . s1018 #r #z #: 1.0880 1.0978 1.0882 Errors LC Pass High 100.00 Low - .01000 El em Mn Units ppm Avge 20 .382 SDev .101 ?RSD .49s01 #r #z #: 20 .3 10 20 .497 20 .337 EIem TI Uni[s ppm Avge .03800 SDev .00380 ?RSD 10.001 Cu Fe ppm ppm 1.5587 H3084.4 . 0143 20 .4 .91700 .66]-02 5103 H306l. -4 5630 H3 100.2 5428 H3 0 91 .7 1 1 1OLC Pass LC Pass 100.00 s0.000 - .0s000 - .02s00 LC High NOCHECK NOCHECK 1400.0 - .10000 Errors LC Pass LC Pass High 30.000 200.00 Low -.01500 -5.0000 LC Pass NOCHECK 100.00 -.04000 NOCHECK LC Pass LC Pass 4.0000 800.00 -.02000 -s.0000 L- L- L- LC Pass LC Pass Appendix F - 334 LC 329 Analysis Report 03/70/oG 1o:L4:24 PM page 2 s.0000 10.000 - .05000 - .0s000 Se ppm .01232 .00453 35.'759 .00722 .01387 .01587 o High Low 70.000 - .02000 100.00 - .02s00 Sn ppm . 1513 5 .001,69 1 - 1L45 .15288 .15t64 . a4954 LC Pass 40.000 - .10000 2 NOTUSED 10.000 -.02000 Si ppm 7.0430 .0587 .833s9 5 .97 s5 7.0820 7 .4715 40.000 - . s0000 P_ ppm 3 .47 93 .0080 .22995 3.4774 3 .487 4 3 .47 90 40.000 - .04000 Pb ppm .90993 .00891 .97 97 B .89980 . 913 42 .91658 EI em Ti Units ppm Avge .48376 SDev .00085 ?RSD .77 865 #r #z #: . 4837 7 .48462 .48289 Errors LC Pass High 40 .0 0 0 Low - .05000 Intst.d 1 Mode Counts EIem Y Wav1en 371. 03 0 Avge 22595 SDev 91 . 93 6 83 %RSD .4 0 58943 #t #z #: 227 0L 22545 22538 LC Pass LC Pass 40.000 40.000 -1.0000 - .30000 34 NOTUSED NOTUSED LC Pass LC Pass 70 .000 30.000 -.00400 -.01000 567 NOTUSED NOTUSED NOTUSED Appendix 33s F- 330 Analysis Report Method: TRA20505 Sample Name: H0HE9 Run Time: o3/70/06 22:t4:28 Comment : Mode: CONC Corr. Factor: 1 03/ta/06 1o:20:37 PM Operator: Sb ppm .006'70 .00228 33.986 . 00 417. .00136 .00BsB Co ppm .00395 .00047 11.992 .003'/3 .00363 .00449 LC Pass 100.00 - .05000 K- ppm 2 .6144 .0038 .746L7 2.6101 2.6159 2 . 6l-13 V_ ppm .00088 .00105 119.11 .00018 .00037 .00208 LC Pass As ppm .00379 .00072 19.727 .00296 .00421 .004]-5 Cu ppm .3 4424 .00106 .30868 .3 4409 .3 4537 .3 4326 LC Pass 50.000 - .02500 Ni ppm .04238 .00068 1.6704 . o 4201 .04496 . 0 43]-7 Zn ppm 4 . 51,-7 5 .0746 .32369 4.5007 4 .5244 4 .52-/ 4 Ba ppm .08134 .00007 .090s6 .08134 .08742 .08727 Fe ppm 1 .27 6a .0262 2.0550 7 .2459 7 .2934 7.2891 Se /t ppm .00909 .00]-92 27.075 .00814 .01130 .00784 B_ ppm .11831 .00042 .35401 .11855 .11843 . 117 84 Be ppm . 0 0111 .00001 1.0483 . 0 01,12 .00111' ,00110 Pb/1, ppm .10992 .00071 .10501 .10930 .10966 .11079 Se /z ppm - 0021,4 .00081 37.831 . 0 0]_23 .00240 .00279 Mo ppm .00051 .00027 s3 .009 .00050 .00025 .00079 LC Pass Cd ppm .00233 .00015 6 .2324 Pb/2 ppm .11091 .00113 1.0160 .10965 .11423 .11185 NOCHECK 00150 00230 00275 Li ppm .00144 .00016 11 . 326 .00163 .00136 .001,34 LC Pass page 1 Ca ppm 20 .019 .01 9 .3943'7 Mg ppm 2 .0290 .0089 .44018 2 .0202 2 .0287 2.0381 LC Pass 700.00 -5.0000 4.0815 4 .07 59 4.2380 Sr ppm .18681 .00016 .08333 .18686 .18693 . 1B 653 LC Pass EIem Al Units ppm Avge 5.1835 SDev .0051 ?RSD .09749 #r #z #: s.1829 5.1889 5.1788 Errors LC Pass High 700.00 Low -.20000 Elem Cr Units ppm Avge .31376 SDev .00089 ?RSD .2831-4 #t- #z #: . 3127 4 . 31434 .3142l- Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge . 05 924 SDev .00034 ?RSD . 56 661, #r #z #3 05901 0s909 05963 Errors LC Pass High 30.000 Low - .01500 Elem TI Units ppm Avge -.00033 SDev .00075 ?RSD 226 .07 #r #z #: Errors .00011 - .00120 .00010 LC Pass LC Pass LC Pass 20.000 30.000 - .05000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00500 .00222 19.939 .00227 20 .020 .00249 20.097 LC Pass LC Pass 40.000 500.00 - .00500 -5.0000 LC Pass NOCHECK 1400.0 - .10000 Ag Na ppm ppm .002l.8 4.1318 .00063 .0920 28 .97]- 2 .2260 LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHECK NOCHECK LC Pass LC PaSs 4.0000 800.00 - .02000 -5.0000 LC Pass LC Pass Appendix F - 336 Analysis Report Int.Std 1 Mode Count s EIem Y Wavlen 37 7. 0 3 0 Avge 24305 SDev 60. 99451, %RSD .2s 0 955 0 #r 24375 #z 2427 4 #: 24256 331 03 / t0 /06 1o : 2o:3i PM page 2 High 70.000 100.00 10.000 40.000 40.000 5.0000 l-0.000 Low - .02000 - .02500 -.02000 -.50000 -.04000 -.05000 -.05000 Elem Ti Sn Si P- Pb Se Units ppm ppm ppm ppm ppm ppm Avge .00441 .05374 8.1259 26.81,6 .11099 .00477 SDev .00009 .00075 .0598 .041 .00102 .00094 ?RSD 1. 9856 1.4010 .73554 .L5L22 .91'1 62 1,9 .61,4 #1 .00433 .05335 8.0584 26.861 .10995 .00382 #2 . 00440 .05327 8 .A471 26 .782 .11104 . 00569 #3 .00450 .05461 B.t72a 26.806 .11199 .00480 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass Hi-gh 40.000 40.000 40.000 40.000 70.000 30.000 Low -.05000 -.10000 -1.0000 - .30000 -.00400 - .01000 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 337 332 Analysis Report QC St andard Method: TRA20505 Sample Name: CCVB Run Time: 03/a0/06 22:20:40 Comment. : Mode: CONC Corr. Factor: 1 o3 / to / o6 10:26:49 PM OperatoL: page 1 Ca ppm 46 . 915 .557 7.2075 4'7 .558 46 .490 46 .696 Mg ppm 44 .97 9 .537 1.1933 El em AI Units ppm Avge 22 .934 SDev .27 4 ?RSD 1 . 196-t #r #z #3 23 .241 22.7l.2 22 .849 Errors QC Pass Value 25.000 Range 10.500 EI em Cr Units ppm Avge 1. 8077 SDev . 0237 SRSD 1.3L29 #r #z #3 1.8329 Q1 .7BsB 1.8043 Errors QC Pass Value 2 .0000 Range 10.500 Elem Mn Units ppm Avge 1.81,96 SDev .0228 ?RSD 7.2s10 #r #z #3 Errors QC Pass Va1ue 2 .0000 Range 10.500 Elem T1 Units ppm Avge .9331,4 SDev .00646 %RSD .69 184 #r #z #: Errors .93854 .92s99 .93488 QC Pass QC Pass QC Pass .50000 . s0000 10.500 10.500 QC Pass QC 2.0000 2. 10.500 10 QC Pass QC Pass . s0000 50.000 10. s00 10.500 Sb ppm .46s92 .00378 .810s4 . 47 028 . 453 67 . 45 3 B 0 Co ppm 1.8534 .0211, 1.1378 1.8756 1.8337 1.8510 QC FalI 50.000 10.500 V- ppm 1. B2BB .0223 7 .2204 1.8530 1.8091 1.8242 QC Pass As ppm .45800 .003ss .1 7 544 .46209 .45624 .45558 Cu ppm 1. B13s .0797 1.084'7 Ba ppm 1.8727 .02L9 1.2059 1.837'7 7.797L 1.8033 Fe ppm 22 .925 .286 L.2496 23 .235 22 .67 0 22.870 Se/7 ppm .459s0 .00283 . 61 67-7 . 4579 6 .46014 .45640 Be ppm 1.8753 .0222 1.1831 9005 B5B7 8667 Pas s 0000 .500 Pb/ a ppm .4s953 .00533 1.3783 .4657 8 .45672 .4s508 Se/z ppm .4443]. .00245 .55034 .44695 .4421,2 .44387 Mo ppm 1. B5s3 .0187 1.0051 1. B8s3 1.8482 1.8525 QC Pass Cd ppm .45293 .00527 1.1645 .45 B4 0 .447 87 .45251, Pb/ 2 ppm .46197 .0030s .65120 .46533 .45937 .46120 1 1 1 1 1 1 8357 7 98L BOSB Pas s 0000 .500 45 Q44 44 559 501 877 Pas s 000 500 K- ppm Q44 .225 .51,4 1.1529 1.8429 44.815 7.7975 Q43.875 1.8184 Q43 -984 QC Pass QC 2.0000 2. 10.500 10 QC Pass NOCHECK 25.000 10.500 NOCHECK QC 50 10 1. BB58 1.8408 1.8449 QC Pass Ni ppm 1.8353 .0209 1.14l.3 1. B5BB 1. B1B6 1. B2B5 QC Pass NOCHECK 2.0000 10.500 Zn B- pprn ppm 1. BB70 Q1. 699s'.0L-76 .0210 .93326 7.2380 9067 Q1 .1203 B-7 2"7 Q1 . 67 82 BBlB Q1 . 6999 QC Pass QC FaiI Appendix F - 338 NOCHECK QC Pass QC Pass 1.0000 50.000 10.500 10.500 Ag Na ppm ppm .89760 46 .222 .01116 .532 1.2433 1.1513 . 91 024 46 .804 Q.88913 4s.760 Q. B 9342 46 .1,02 Li Sr ppm ppm 1.8515 1. 8685 .0254 .0225 1.3589 7.2024 1 1 1 1.893'7 1.8505 1.8672 QC Pass 333 Analysis Report QC Standard 03/to/06 1o:26:49 PM page 2 Value 1.0000 2.0000 2.0000 2.0000 2.0000 2.0000 2.0000 Range 10.500 10.500 10.500 10.500 l-0.500 10.500 10.500 Elem Ti Sn Si P_ Pb Se UniLs ppm ppm ppm ppm ppm ppm Avge 1.8885 1.8380 2.01,29 1.9315 .461,49 .44965 SDev .0204 .021-2 .!224 .0260 .00406 -00224 ?RSD 1.0801 1.1513 6.0795 L -3446 .87928 .49'7]_'7 #1 7.9LL2 a.862a 2.1520 1.9601 .46575 .45224 #2 1.87L7 1,.8225 1.9651 1.9093 .45878 ..44841, #3 I.882'7 1,.8294 1. -92L7 L.s2s2 .4s9s3 .44833 Errors QC Pass QC Pass QC Pass QC Pass QC Pass QC Pass Value 2 .0000 2. 0000 2 . 0000 2 . 0000 .50000 .50000 Range 10 .500 10.500 10 .500 10 .500 10 .500 10 .500 Intstd 1 Mode Counts Elem Y Wavl en 37 1-. 0 3 0 Avge 24744 SDev 351.1981 ?RSD L.495990 #r 23730 #z 24309 #: 243e4 23456"7 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 339 334 Analysis Report Method: TRA20505 Sample Name: CCBB Run Time: 03/70/06 22:26:53 Comment : Mode : CONC Corr. Factor: 1 03/70/06 1o:33:a2 PM Operator: Sb ppm - .00082 .002s3 307 .46 .00178 - .00328 - .00097 Co ppm - .00005 .00097 l-740.5 K- ppm .05831 . 021,20 35.351 .08252 .04311 .04930 V- ppm - .00007 .00199 27 85 .2 .00191 -.00207 - .0000s LC Pass As ppm .00107 .00158 145. B3 .00227 - .00071 .00l-66 Ba ppm - .00016 .00015 9B . 2BB .00001 - .00030 - .00018 LC Pass .00160 - .00160 Fe ppm .01228 .02133 l'73 -15 .03201 - .0l-032 .01508 Se/r ppm .00406 .00622 153 .38 .01l-02 .00212 - .00096 B- ppm .00309 .00304 98 .389 .00659 .00108 .00151 Be ppm .00100 .00034 33 .536 .00062 .00115 .00t24 Pb /7 ppm .00L1,2 . 00 826 '739. 55 . 01 0.14 - .00070 - .00608 Se/2 ppm - .00135 .0041-2 302.95 - .00s72 - .00200 .00304 Mo ppm .00775 .00L34 't 6 .829 .00322 .00050 .00L42 LC Pass Cd ppm .00007 .00038 557. B0 .00051 - .00014 - .00015 page 1 Ca ppm . 010 94 .00145 13 .268 .01208 .00930 .01L44 Elem A1 Units ppm Avge -.05476 SDev .00870 ?RSD 15. BBO #r #z #: -.04582 -.06320 - .0s526 Errors LC Pass High .10s00 Low - .10500 E}em Cr Units ppm Avge . 00 012 SDev .00202 ?RSD l.735.9 #r #z #g .00245 - .00]-L2 - .00099 Errors LC Pass High .00360 Low - .00360 EIem Mn Units ppm Avge . 00 042 SDev .00025 %RSD 59.299 #r #z #3 00071 00025 00030 Errors LC Pass High .00180 Low - .00180 Elem TI Units ppm Avge .00095 SDev .00030 ?RSD 31.109 #r #z #: Errors .00071 .00087 .00L29 LC Pass LC Pass LC Pass .01400 .00330 -.01400 - .00330 LC Pass LC Pass LC Pass .00180 .00082 .06500 -.00180 -.00082 -.05500 .00104 H.0l.203 - .00083 H.010s7 -.00038 H.0]-072 LC Pass LC High .00220 .00700 -.00224 -.00700 LC Pass NOCHECK _o4900 -.04900 Pb/2 Ms ppm ppm -.001,12 .00724 .00468 .00590 41,6.51 41 4.49 - .00578 - .00115 .00357 .00700 - .00480 .00l-54 NOCHECK LC Pass .04900 - .04900 Ag Na ppm ppm - .00175 .00248 . 0 0 757 .71 251, 89.757 28117. .00001 .82272 -.00299 -.35213 -.0022-1 - .46315 LC Pass LC Pass .00970 1_.4730 -.00970 -1.4730 Lr ppm .00737 .00034 24.436 .00775 .001,26 .00110 LC Pass Sr ppm .00001 .00007 87t. B3 .00007 - .00006 .00001 LC Pass Cu ppm H.01111 .00080 7 .2406 LC Pass LC Pass .32200 .00380 - .32200 - .00380 NOCHECK NOCHECK Ni ppm - .00001 .00137 2457 2 . .001-57 - .00082 - . 0 0077 Zn ppm .00027 .00014 51. B0B .00042 .00014 .00025 LC Pass LC Pass Appendix F - 340 335 o Analys i s Report.03/70/06 1o:33:02 PM page 2 .00270 .00130 -.00270 -.00130 Se ppm .00073 .00118 151 . 52 .000s4 - .00035 .001,99 EIem Ti Units ppm Avge .00010 SDev .00028 ?RSD 288.29 High Low #r #z #: #r #z #: .01000 -.01000 .00034 -.00020 .0001s 24725 2493 9 24BO 8 .00s00 - .00500 Sn ppm .0009-r .00205 2L3.35 .0033s - .00018 -.00027 2 NOTUSED .00380 -.00380 Si ppm . 0 0 947 .01383 145 .99 .02528 .003s4 - .00040 LC Pass .05500 - .0ss00 3 .03100 - .03100 P- ppm - .00057 .00156 273 . 82 .00119 - . 0 011,2 - .00178 .00880 - .00880 Pb ppm .00008 .00054 765. B9 .00002 - .000s2 .00076 Errors LC Pass LC Pass High .00150 .00770 Low -.00150 -.00770 LC Pass LC Pass LC Pass .02100 .00370 .00430 -.02700 -.00370 -.00430 rntstd 1 Mode Counts EIem Y Wavlen 377. 03 0 Avge 24624 SDev 436. 84 5B ?RSD L.774055 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix 341 F- 336 Analysis Report Method: TRA20505 Sample Name: HOHFG Run Time: 03/r-0/06 22:33:06 Comment. : Mode: CONC Corr. Factor: 1 03/70/06 1o:39:16 PM Operator: page 1 Cd Ca ppm ppm - .00001 .05559 .00009 .00183 153s.9 3.2934 EIem AI Units ppm Avge -.03088 SDev .00242 ?RSD 7 .827 6 El em Units Avge SDev ?RSD #r #z #: Errors - . 02859 - .03064 -.03341 LC Pass 700.00 -.20000 Cr ppm - .00048 .00076 156.48 .00026 -.00]-25 - .00046 LC Pass 100.00 - .01000 Mn ppm .00148 .00035 24 .640 .00787 . 0 0115 .00444 T} ppm .00059 .00056 9s. 571, .00118 .00055 .00005 LC Pass Sb ppm -.00345 .00094 27 .237 0040s 00395 0 0237 LC Pass 20.000 - .05000 Co ppm - .00018 .00021- 116 . 92 - .00035 .0000s -.00024 K- ppm . 05 546 . 01 725 1-7 .184 .05s19 .0537l. .07749 V- ppm .0001,2 .00085 707.90 - .00045 - .00028 .00109 LC Pass As ppm .00248 .00069 27 .949 .00327 .00209 .00206 LC Pass 30.000 - .01000 Cu ppm .02388 .00071 2 .9544 . 0243 9 . 023 07 .0241,6 Ni ppm .002s0 .00073 29.306 .00324 .00178 .00249 Zn pprn .00503 .00020 3.3372 .00sBs .00500 .00525 Ba ppm .00135 .00011 7 .8394 .001,25 .00]-32 . 0 0147 LC Pass 30.000 - .01000 Fe ppm .37310 .007L2 1.9084 .3717 0 .36679 .38082 Se/t pprn .0039s .0034l- 85.329 .00762 .00331 .00087 B_ ppm .00286 .00027 9.5552 .003l-1 .00276 .00265 Be ppm .00087 .00010 11.509 .00076 .0009s .00091 LC Pass 10.000 - .00s00 Pb/1- ppm . 011s 1 .00s95 51.789 . 01 825 .00938 .00591 Se/2 ppm - .00027 .00229 844 - 1,6 -.00282 .00040 .00161 Mo ppm .00]_26 .00030 23.955 .00L49 .00092 .007_37 LC Pass .00009 - .00009 - .00002 Pb/ 2 ppm . 01263 .00313 24 .7 68 .0090s .01403 .01481 Ag ppm -.00]-97 .00094 47 .979 -.00286 -.00206 - .00098 .00083 .00058 .00058 LC Pass 05502 05412 057 64 Mg ppm .00577 .00274 47 .481 .00494 .00354 .00883 Na ppm - .1577-7 .304'77 193 .77 . 1B 494 - .39838 -.25987 .00019 .00018 .00024 LC Pass #r #z #: Errors High Low El em Units Avge SDev ?RSD #r #z #: Errors High Low El em Units Avge SDev %RSD #r #z #: LC Pass LC Pass 40.000 500.00 - .00500 -s.0000 LC Pass LC Pass 100.00 s0.000 - .05000 - .02500 LC Pass NOCHECK 1400,0 - .10000 NOCHECK LC Pass 700.00 -5.0000 Errors LC Pass High 30.000 Low -.01500 LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHECK NOCHECK LC Pass LC Pass 4.0000 800.00 -.02000 -5.0000 Li Sr ppm ppm .00073 .00020 .00009 .00004 11.873 17.634 LC Pass LC Pass Appendix F - 342 337 Analysis Report 03/Lo/06 1o:39:16 PM page 2 High 70.000 100.00 10.000 40.000 40.000 s.0000 10 - 000 Low -.02000 - .02500 - .02000 - .50000 -.04000 - .0s000 -.0s000 Elem Ti Sn Si P Pb Se Units ppm ppm ppm pp* ppm ppm Avge .00220 .01309 .074LL .08044 .01259 .00144 SDev .00011- .00049 .00288 .00330 .00020 .00039 ?RSD 5.1868 3 .7743 3.8911 4.1038 1.565s 27 .1,77 #1 .00223 .01365 .07692 .07720 .0L244 .00099 #2 .00208 .0L272 .07LL6 .08031 .01281 .0-0167 #s .00230 .01290 .07425 .08380 .01251 .00165 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low - .05000 -.10000 -1.0000 -.30000 - .00400 - .01000 Intstd 1 Mode Counts Elem Y Wavlen 37 7. 0 3 0 Avge 24330 SDev 737 .0564 ?RSD .553323L #r 24424 #z 24393 #: 24773 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 343 338 Analysis Report Method: TRA20505 Samp1e Name: H0HFGS Run Time : o 3 / ao / 06 22 :39 :20 Comment : Mode : CONC Corr. Fact.or: 1 03 / 10 / 06 1o : 45:29 PM Operator: Sb ppm .44521, .00366 .821,26 .44538 .44814 .44111 Co ppm .08948 .00033 .37 262 .0897l. .08962 .08909 K_ ppm 43.855 . L25 .28s63 43 .946 43.931 43.-722 LC Pass 200.00 -s.0000 V- ppm .17 7 37 .00062 .34977 .17 7 93 .L'7732 .1,7569 LC Pass As ppm . 0 B 999 .00069 .7 597 9 .08992 .09072 .08934 Cu ppm .23234 .00077 .33 0L7 .23250 .23301 .23150 Ni ppm . 4 4337 .00762 .35518 .442a2 .44521 .4421 9 LC Pass 100.00 - .04000 Zn ppm .48029 .0041 9 .37 3 81 .48042 .48201 .47 843 08940 08914 OB837 1.6527 L .6372 L .6422 Se/1, ppm .127 B9 .00341 2 .'7118 - 124L4 .72858 .13 097 NOCHECK B_ ppm .80260 .00794 .24222 . B 0 446 .80275 .80058 . o 461,7 .04506 .04513 . 0 81,41 .091s3 .09221, NOCHECK Se/2 ppm . a25-l 6 .00115 . 917 89 .t2508 .727 09 .12511 NOCHECK Mo ppm . 4557 5 .00206 .451,49 .45520 .45909 .45596 LC Pass Cd ppm .04358 .00017 .3943s .04349 .04383 . 04 37 0 Pb/2 ppm .09594 .00151 1.6834 .09779 .094'79 .0952s Ag ppm . 03 952 .00015 .31 027 . 03 9s2 . 03 937 . 03 966 Li ppm .09555 .00015 .1,6261 .09556 .09s69 .09s38 LC Pass page 1 Ca ppm 45 .71 2 .055 .a2118 46 .10 9 46 .191 46 .21,6 Mg ppm 8.5289 .0160 .18591 8.5401 8.5350 8.6105 Na ppm 44 .928 .21,4 .47534 44 .6 81 45 .046 45.055 Sr ppm . 457 23 .00131 .2857 3 . 457 37 .45846 .45586 LC Pass El em Al Units ppm Avge 7.7209 SDev .0090 %RSD . 52371, #r #z #: 7.7236 7 .7 282 I .'710 B Errors LC Pass High 700.00 Low - .20000 Elem Cr Units ppm Avge .L7 433 SDev .00097 %RSD .5s531 #r #z #: 1,7 545 77376 1,7 37 8 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge . 0 91-41, SDev .00029 ?RSD . 3 1369 #r #z #: 09143 09168 09111 Errors LC Pass High 30.000 Low - .01500 EIem T1 Units ppm Avge .35967 SDev .00443 ?RSD a.2330 #r #z #: Errors .35457 .36778 .3 6265 LC Pass Ba Be ppm ppm .08897 .04672 .00054 .00005 .60202 .1,2306 LC Pass LC Pass 20.000 30.000 - .06000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00500 Fe Pb /1, ppm ppm 1.5444 .0BB3B .0079 .00505 .4'7 950 5.841,1 LC Pass LC Pass 40 .000 500.00 -.00500 -5.0000 LC Pass LC Pass LC Pass 100.00 50.000 1400.0 -.05000 -.02500 -.10000 NOCHECK LC Pass 700.00 -5.0000 LC Pass LC Pass 4 .0000 800.00 - - 02000 -s.0000 LC Pass LC Pass Appendix F - 344 339 Analysis Report 03/\0/06 10:45:29 PM page 2 High 70.000 100.00 10.000 40.000 40.000 5.0000 10.000 Low -.02000 - .02500 -.02000 -.50000 -.04000 - .05000 -.05000 Elem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge .09662 .46a34 1.21,89 4.7258 .09381 .12676 SDev .00030 .00199 .0070 - 0334 .00089 .00150 tRSD .3a342 .43151 .5'7342 .707't6 .94754 1 . 1832 #1 .09680 .4s9os L -2215 4 .7469 .09283 .L2505 #2 .09679 .46231, 1,.2241 4.7433 .09403 .1-2787 #3 .0962't .46267 L.2L09 4.6872 .09457 .a273s Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.05000 - .10000 -1.0000 -.30000 -.00400 -.01000 Intstd 1 Mode Count. s Elem Y Wavlen 37l-.030 Avge 24407 SDev 7 9 .9312a ?RSD .327 5658 #r 24371 #z 24467 #a 24433 234557 NO-TUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Append ix F - 34s 340 Analysis Report Method: TRA20505 Sample Name: HOHFGD Run Time: 03/]-0/06 22:45:33 Comment : Mode: CONC Corr. Factor: 1 03/1,0/06 10:57:42 PM Operator: Elem AI Units ppm Avge 1,.7564 SDev .0151 ?RSD . 85 996 Sb ppm .43 54 0 .00456 1 . 0 472 .44018 .4349l- .43110 LC Pass 20.000 -.06000 Co ppm .09016 .001,69 1.8730 .0921,1 .0893s .08904 K_ ppm 43 .101 - 1,66 .38522 43 .27 B 43.075 42 .949 LC Pass 200.00 -s.0000 V_ ppm .17 g'7 B .00255 1, . 41,9 4 . 1B 26t .1,7906 .17766 LC Pass Be ppm .04 649 .00040 . B4 982 .04 694 . 04 634 .04620 Pb/1 ppm .09836 .00l.92 1.9479 .09848 .10024 .09639 Se/z ppm .L2611 .00054 .42485 .1"2598 .1,2555 .1_2669 Mo ppm .4527 B .00555 I .2256 .45911 .45045 .44877 LC Pass Cd ppm . 04 477 .00058 1.5408 . 04 495 .0438s .04370 Pb/2 ppm .10s60 .00100 . 9 4449 .10669 .10474 .10537 Ag ppm .04181 .00a34 3 . 1964 .04322 .04165 .04056 Li ppm .09668 .00033 .33929 .09701, .09667 .09636 LC Pass page 1 Ca ppm 45 .9l.2 .452 .98370 46.408 45.807 45 .523 Mg ppm 8. s250 .1,725 1.3199 8.5509 B.4B9B B .4342 Na ppm 44.086 .27 B .63090 44 .357 44 .10 0 43 . B02 Sr ppm .45966 .00284 .51729 . 4 627:7 .4s903 . 45-120 LC Pass #r #z #: 1_.7727 1,.7 535 1.7 430 As ppm .09085 .00109 1.1988 - 09l.-13 . 0 9420 .08964 Cu ppm .2 4217 .00218 . 9 01,22 .24465 .24135 .24052 Ni ppm .44998 .00668 !.4851 .45599 .44927 .443 6 B Zn ppm .41338 .00467 .97364 .47 864 . 47 A42 .47007 Ba ppm .08918 .00076 .85327 .09004 .08891 .0BBs9 Fe ppm 1.1662 .0194 t .6 653 1.1886 1 . 1542 1.1557 Se/1 ppm .1,2845 .00292 2 .27 44 . 1,29 47 . 13 0-72 .L2515 B_ ppm .81395 .010s2 t .2926 .82s96 .80951 .8063't Errors LC Pass High 700.00 Low -.20000 EIem Units Avge SDev ?RSD #r #z #: Cr ppm .77 628 .00345 1.9541 .18019 .17 49 6 .]-1368 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge .09085 SDev .00142 ?RSD 1.559s #r #z #: 09245 09036 0897 5 Errors LC Pass High 30.000 Low - .01500 Elem TI Units ppm Avge .35355 SDev .00328 ?RSD . 90 223 #r #z #: Errors . 3 6 695 .35041 .36332 LC Pass LC Pass LC Pass 100.00 s0.000 - .05000 - .02500 LC Pass LC Pass 30.000 30.000 -.01000 -.01000 LC Pass LC Pass LC Pass 10.000 40.000 600.00 -.00500 -.00500 -5.0000 LC Pass NOCHECK NOCHECK LC Pass 1400.0 700.00 - .10000 -5.0000 LC Pass NOCHECK NOCHECK LC Pass LC Pass 100.00 4.,0000 800.00 -.04000 -.02000 -5.0000 LC Pass LC Pass Appendix F - 346 34A Analysis Report 03/to/oG 1o:51:42 PM page 2 5.0000 10.000 - .05000 - .05000 Se ppm . t27 21 .00054 .50700 .1-27 48 .1,2767 .72647 EIem Ti Units ppm Avge .09538 SDev .00105 %RSD 1.1053 High Low #r #z #: IntStd Mode Elem Wavlen Avge SDev ?RSD #r #z #3 70.000 - .02000 .09642 .09541 .0943a 1 Count s Y 31L.030 23994 311.1183 L .296648 23660 24047 2427 5 100.00 - .02500 Sn ppm .45823 .00459 1.0233 .46327 .457 44 .45399 LC Pass 40.000 - .10000 2 10.000 - .02000 Si ppm 2.4533 .0295 1, - 2020 2 .4852 2 . 4446 2 .4292 40.000 - . s0000 P_ ppm 4 .7 205 .0450 .97355 4.7704 4.-7113 4 .61 98 40.000 -.04000 Pb ppm .10354 .00084 .8073l- .10438 .10352 .10277 Errors LC Pass High 40.000 Low - .05000 LC Pass LC Pass 40.000 40.000 -1.0000 - .30000 LC Pass LC Pass 70.000 30.000 - .00400 -.01000 NOTUSED .NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 347 342 Analysis Report Method: TRA20505 Sample Name: HOHFGP Run Time : 0 3 / 70 / 06 22 :5L :47 Comment : Mode : CONC Corr. Factor: 1 03 /to / 06 10 : 5't :56 PM Operator: page 1 Cd Ca ppm ppm - . 00011 .02954 .00008 .00082 17 .156 2.7 758 EIem A1 Units ppm Avge -.04864 SDev .00140 ?RSD 2.85BB #r #z #: Errors - .00117 .00243 .00099 LC Pass Sb ppm - .00170 .00097 s5. 9\6 -.00232 - .00058 - .002t9 Co ppm - .00007 .0007'7 260. 93 - .00010 .004l"2 -.00022 K- ppm .043 19 .002]-0 4 .8569 .041,44 . 04 267 . a4552 V- ppm - .00004 .00018 473.19 - .00022 - .00004 .00014 LC Pass As ppm . 0 0]-52 .00007 4 .4429 .0Q1s1 . 0 0l-46 .00159 Cu ppm .01183 .00078 5.5657 . 0 11,24 .01153 . 01271 Ni ppm - .00004 .00028 546.75 -.00032 .00024 - .00004 Zn ppm .00238 .0000s 2 .2646 .0023s .00234 .00244 Ba ppm .00012 .00010 83.1-29 .00009 .00004 .00023 Fe ppm . 07 894 .00494 6 .2523 .07s31 .07 696 . 0B 4s6 Se/t ppm .00311 .00156 50.035 .00237 .00201 .00491, B- ppm .00189 .00046 24.068 .00233 .00193 .00l.42 Be ppm .00087 .00002 2.5"794 .00084 .00088 .00088 Pb/1, ppm .00095 .00054 55.31,6 .00045 .00090 .00152 Se/2 ppm .00060 .00091 151. B0 - .00045 .007\4 .00111 Mo ppm .00050 .00019 32 .094 .00080 .00041 .00059 LC Pass 00020 0000s 00007 Pb /2 ppm .00234 .00067 28 .457 .001,95 .00311 .00195 Ag ppm - .00354 .00035 9.9910 - . 0 0394 - .00341 - - 0 032'7 Li ppm .00085 .00007 B .4584 .00094 .00083 .00080 LC Pass 0291,5 029a8 030s9 Mg ppm .00099 . 00 064 54 .449 .00085 .00043 .00158 Na ppm - .20546 . o7 647 37 .1-92 - .253 52 -.23383 - . 11,892 LC Pass 800.00 -5.0000 Sr ppm .00003 .00001 42 .65l- .00004 .00002 .00004 LC Pass #r #z #g 04773 05024 047 94 Errors LC Pass High 700.00 Low - .20000 EIem Cr Units ppm Avge -.00042 SDev .00009 ?RSD 2a.700 #r #z #3 00049 00032 00046 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge . 00 052 SDev .00011 ?RSD 20 .693 #r #z #s 00048 00044 0005s EIem T1 Units ppm Avge .00075 SDev . 0 0181 ?RSD 24L.37 LC Pass LC Pass 20.000 30.000 - .06000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00500 LC Pass LC Pass 40 .000 500.00 - .00500 -5.0000 LC Pass LC Pass 100.00 50.000 - .05000 -.02500 LC Pass NOCHECK NOCHECK LC Pass 1400.0 700.00 - .10000 -5.0000 Errors LC Pass LC Pass High 30.000 200.00 Low -.01500 -5.0000 LC Pass NOCHECK 100.00 - .04000 NOCHECK LC Pass 4.0000 - .02000 LC Pass LC Pass Appendix F - 348 343 Analysis Report High Low 70.000 - .02000 100.00 - .02500 Sn ppm .00247 .00026 10.615 .00244 .00223 .00275 LC Pass 40.000 - .10000 10.000 - .02000 Si ppm - .0005s .000ss 99.810 00021 0002s 0 0118 40.000 - .50000 P_ ppm .013l-2 .00150 11. 44l. .01255 .01198 . 01 482 40.000 - .04000 Pb ppm .00223 .000s7 25 .699 .00l.74 .00286 .00209 5 NOTUSED s.0000 - .05000 Se ppm .00l-73 .00094 54 .453 .00077 .00178 .00266 6 NOTUSED page 2 10.000 - .05000 7 NOTUSED 03/70/06 1o:57:56 PM EIem Ti Units ppm Avge .00046 SDev .00005 ?RSD 11 - 1,7 5 #r #z #g 00041 00051 00045 Errors LC Pass High 40.000 Low - .05000 Intstd 1 Mode Counts Elern Y Wav1en 37L.030 Avge 24723 SDev 39.04030 ?RSD .1579087 #r #z #: 247 68 247 08 24694 234 NOTUSED NOTUSED NOTUSED LC Pass LC Pass 40.000 40.000 -1.0000 - .30000 LC Pass LC Pass 70 .000 30.000 - .00400 - .01000 Appendix F 349 344 Analysis Report Method: TRA20505 Sample Name: HXQ2HZ20 Run Time: 03/t0/0G 22:58:00 Comment : Mode : CONC Corr. Factor: 1 03 /t0 /06 11:04 :09 pM OperatoL: Sb ppm .00060 .00059 99 .22s .00026 . 0 01,28 .0002s LC Pass 20.000 - .050c0 Co ppm .00055 .00015 22.853 .00074 .00075 .00049 LC Pass 100.00 - .05000 K_ ppm .104s8 .01096 10. ABt .09193 . 1 1 1,1,2 .11070 LC Pass 200.00 -5.0000 V_ ppm .00066 .00080 t2t. 5 s . 0 0116 .00110 - . 0 002'7 LC Pass As ppm .00128 .00042 33 .015 .00l-76 .00106 . 0 0101 Cu ppm .01084 .0001s 1.3738 . 01092 .01094 .01067 Ni ppm .00166 . 0 0 04 s 27 .131 .00209 .001,77 . 0 0119 Zn ppm .292'7 7 .00085 .29001 .291,94 .29297 .29350 Ba ppm 1. BBB5 .0042 .22307 1. BB55 1.886'7 1.8933 Fe ppm .07574 .00492 6 .41,02 .07845 . 0B 057 . 0711 9 Se/r ppm .00379 .00151 4l .537 .00270 .00522 .00404 B_ ppm .00349 .00019 5 ,4924 .00344 .00370 .00333 Be ppm .00101 .00008 8.1103 .00099 . 00 094 .00110 Pb/r ppm .00500 .00108 L7 - 934 .00527 .00724 .00s50 Se/2 ppm - .00081 .00113 139. B5 - .001,79 .00043 - .00105 Mo ppm .00062 .00041 66.248 .00022 .00061 .00103 LC Pass Cd ppm .10097 .00069 .68849 .100a7 .10l.32 .10743 Pb/2 ppm .00546 .00059 10.794 .00482 .00560 .00s97 Ag ppm .00141 .00064 43 .673 .00073 .001,"79 .00189 Li ppm .00075 .00003 3 . 9298 .00078 .000'73 .00073 LC Pass page 1 Ca ppm ]-6. s90 .746 .88302 16. 428 15. 628 16 .71,3 LC Pass 500.00 -s.0000 Mg ppm .88661, .00551 .62140 .88026 .88941- .89014 Na ppm 1.379'7 . L1,82 8.9581 1 . 3 967 1.3796 1.1836 Sr ppm .0325s .00013 .4]-119 . 03 2s2 . 03 264 .0321 9 LC Pass Elem AI Units ppm Avge .96149 SDev .00443 ?RSD .46029 #r #z #: 9571,6 95130 95600 Errors LC Pass High 700.00 Low -.20000 EIem Cr Units ppm Avge .00094 SDev .00065 ?RSD 69 .546 #r #z #3 00154 00101 00025 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge .00184 SDev .00003 ?RSD 1.5990 #r #z #: 0 0181 00187 00184 Errors tC Pass High 30.000 Low - .01500 EIem TI Units ppm Avge L- . 02944 SDev .00203 ?RSD 6 .9023 #r #z #: Errors 02'7 9'/ 02859 031,'1 6 Low LC Pass LC Pass 30.000 30.000 - .01000 - .01000 LC Pass LC Pass 10.000 40.000 - .00500 - .00500 LC Pass LC Pass 50.000 1400.0 - . 02500 - .10000 NOCHECK NOCHECK LC Pass 700.00 -s.0000 LC Pass NOCHECK NOCHECK 100.00 -.04000 LC Pass LC Pass 4.0000 800.00 - .02000 -5.0000 L- L- L- LC Pass LC Pass Appendix F - 350 LC 34s Analysis Report High Low 70.000 - .02000 100.00 - .02s00 Sn ppm . 03 926 .00041 1.0447 .03901 . 03 973 .03903 10.000 - .02000 Si ppm .21,842 .00].92 .87909 .27820 .21662 .22044 40.000 - .50000 P_ ppm t .215 5 .0071 . 63 425 7.2069 7 .218 0 1, .2217 40.000 - .04000 Pb ppm .00599 .000s9 9.7 589 .00534 .00648 .0061s 5.0000 - .05000 Se ppm .00103 . 0 01,28 125 .20 -.00021 .00236 .00093 page 2 10.000 - .0s000 03/70/06 11:04:09 PM Elem Ti Units ppm Avge 2 .6834 SDev .0165 ?RSD 61568 #r #z #: 2 .6665 2 . 5 B4 0 2 .6996 Errors LC Pass High 40 .0 0 0 Low -.05000 InEStd 1 Mode Counts EIem Y Wav1en 377.030 Avge 24003 SDev 111 .5852 ?RSD .4648846 #r #z #: 2413a 23 929 23948 LC Pass LC Pass 40.000 40.000 - .10000 -1.0000 2 NOTUSED LC Pass LC Pass LC Pass 40.000 70.000 30.000 -.30000 -.00400 -.01000 34 NOTUSED NOTUSED 567 NOTUSED NOTUSED NOTUSED o Appendix 351 F- 346 Analysis Report Method: TRA20505 Sample Name: HXQ2MZ20 Run Time: 03/ta/0G 23204:13 Comment : Mode: CONC Corr. Factor: 1 03 /ao / 05 11 : ta :22 PM Operat or : Sb ppm -.00092 .001,64 7'7 9 .45 .0009s - .00155 -.00215 LC Pass 20.000 - .05000 Co ppm .00051 .00019 35.755 .00070 .000s0 .00033 LC Pass 100.00 - .05000 K- ppm .07705 .00651 B .4482 .07531 . 0715 B .08425 LC Pass 200.00 -5.0000 V- ppm .00035 .00040 115.38 .00077 .00005 .00081 LC Pass As ppm .00027 .00048 77 5. 10 .00078 .00022 -.00017 Cu ppm .01030 .00048 4 .6373 .01042 .00977 .01071, LC Pass s0.000 - .02500 Ni ppm .00752 .0042l- 13 . 663 .00128 .00165 .00163 Zn ppm .26838 . 0 01,57 .58552 .26815 .26594 .27005 Ba ppm 1. B6B0 .0102 .54317 1.8593 1.8573 1 . B'7'7 5 Fe ppm .06084 .00776 11.764 .05584 .05764 .05904 LC Pass 1400.0 - .10000 Se/r ppm .00111 .00099 89.792 .00048 .00226 .00060 Be ppm .00L07 .00013 11.99] .00095 . 0 01,21, .00104 Pb/ 7 ppm .00040 .002L]_ s30.17 Se/z ppm .00039 .00425 317 .21, -.00035 -.00031 .00183 Mo ppm .00024 .00022 108.55 .00001 .00044 .00015 LC Pass Cd ppm .09535 . 00 a62 . 63 94l- .09s98 .09601 .097A6 Pb /2 ppm .00432 .00].26 29 .248 - .00051 -.00062 .00026 Li ppm . 00 0s2 .00011 2a .044 .00040 .00060 .00057 LC Pass page 1 Ca ppm 15.127 .150 . 929 93 76.08s 16 . 002 16.293 LC Pass 600.00 -s.0000 Mg ppm .89068 .00489 .s4853 . BBBB3 . BB69B .89522 LC Pass 700.00 -5.0000 7 .2404 1.1063 1.1453 Sr ppm .03206 .00023 .7 3 43'7 .03246 . 03 tB2 . 03 229 LC Pass Elem AI Units ppm Avge . 93 491- SDev . 00 529 ?RSD .565'79 #r #z #: 93438 9299L 94045 Errors LC Pass High 700.00 Low - .20000 EIem Cr Units ppm Avge .00031 SDev .00039 ?RSD 126.23 #r #z #: .00072 - .00005 .00025 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .00146 SDev .00005 ?RSD 3 .2]-28 #r #z #: 00149 00141 00149 Errors LC Pass High 30.000 Low -.01500 EIem TI Units ppm Avge L-. 02536 SDev .00459 ?RSD 18. I22 #r #z #: Errors 0297 6 0257 7 020s9 Low LC Pass LC Pass 30.000 30.000 - .01000 - .01000 LC Pass LC Pass 10.000 40.000 - .00500 - .00s00 .00232 .00292 .00073 .00466 - .00185 .00537 NOCHECK NOCHECK Ag Na ppm ppm -.00029 1.1640 .00048 .0689 166.36 5.9237 LC Pass NOCHECK NOCHECK LC Pass LC Pass 100.00 4.0000 800.00 -.04000 -.02000 -5.0000 L- L- L- B- ppm .00232 .00060 25 .7tB .00289 .00231 .00l.1 0 Pass LC Pass Appendix f - 3s2 o LC LC 347 Analysis Report 03/70/06 11:to:22 PM page 2 0000 10.000 05000 - .05000 EIem Ti Units ppm Avge 2.7350 SDev . 014 1 %RSD .55988 High Low #r #z #3 #r #z #: 70.000 - .02000 2 .73 19 2 . L245 2 - 1,51,7 24249 24528 24203 100.00 -.02s00 Sn ppm .03819 .00044 1.1s96 .03845 . 03 844 .03768 2 NOTUSED 10.000 - .02000 Si ppm .21,225 .0023l- 1.0881 .2t151 .21,041 .2'L484 40.000 - .50000 P_ ppm I .23 15 .0134 1.09l.9 r.2300 7.2190 L .2457 40.000 - .04000 Pb ppm .0034l. .00038 11.734 .00313 .00384 .00326 Se ppm .0009s .00073 77 .020 .00026 .00087 .001,77 Errors LC Pass LC Pass High 40.000 40.000 Low -.05000 -.10000 LC Pass LC Pass 40.000 40.000 -1.0000 - .30000 LC Pass LC Pass 70 .000 30.000 - .00400 - .01000 Intstd 1 Mode Counts EIem Y Wavlen 371,.030 Avge 24327 SDev 77 5 .7 357 ?RSD .7224079 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix 3s3 348 Analysis Report Method: TRA2 0505 Sample Name : HXe24Z2O Run Time: 03/l-0/06 23:J,0:2-l Comment : Mode : CONC Corr. Factor: 1 03/to/06 11:16:36 pM Operator: Sb ppm - .00095 .00083 85.1-72 - .00183 - .00087 - .00018 LC Pass 20.000 - .06000 Co ppm .00003 .00023 7 89 .52 .00001 - .00019 .00027 LC Pass 100.00 - .0s000 K- ppm .09983 .0099a 9 .9266 .09401 .09420 . 111,27 LC Pass 200.00 -s.0000 V_ ppm .00004 .00056 1467.7 - .00055 .0001s .0006s LC Pass As ppm - .00014 .000s5 390.20 .00048 -.00057 - .00034 Cu ppm .01077 .00009 .85064 .0105s .01081 .01066 Ni ppm .00254 .000s1 20 .261 .00309 .00207 .00245 Zn ppm .42911 .00258 .50135 .42895 .42661, .431,7 6 Ba ppm 7.7 530 .0132 .7 557 9 7.7573 1.7382 1.7635 Fe ppm .08919 .00462 5.1765 .08s90 .087l.9 .09447 Se/t ppm .00324 .00400 123 . t7 .00722 - . 0 00-/1 .00328 B- ppm . 0 019-l .00105 s3 .338 .00300 .00090 .00200 Be ppm .0010s . 00 022 21 .052 .00080 .00722 .00111 Pb/t ppm .00401 .00401 100.07 .00854 .00091 .00258 Se/z ppm - .00098' .00245 249 .63 - .00380 .00055 .00020 Mo ppm .00064 .00032 50.740 .00027 .000'76 .00088 LC Pass Cd ppm .09630 .00069 .7 17 5a .09624 .09s53 .091)lt Pb /2 pprn .0028s .0021,7 76.339 .00041 .004s7 .00355 Ag ppm .00108 .00073 68.043 .00071 .00059 . 0 01_92 Lr ppm .00059 .00007 11.988 .00052 .00060 .00066 LC Pass page 1 Ca ppm 13 .334 .099 .'74389 13 .2'72 13 .282 13 . 449 Mg ppm 1. 5553 .0184 1 . 181,2 1.5433 1.5462 1.5765 Na ppm 1, .6994 . \624 9.5585 1. BB39 1.5-782 1,-6359 Sr ppm .02264 .00010 .44437 .02266 .02253 . 022'7 3 LC Pass El em Al Units ppm Avge .92575 SDev .00757 ?RSD .81730 #r #z #3 .92s95 .91809 . 93 322 Errors LC Pass High 700.00 Low - .20000 EIem Cr Units ppm Avge .00055 SDev .00041 ?RSD 7 4 .222 #r #z #: 00011 00092 00051 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge .00184 SDev .00006 ?RSD 3.1314 #r #z #: 00190 00179 00182 Errors LC Pass High 30.000 Low - - 01500 EIem T1 Units ppm Avge L-. 02043 SDev .00206 ?RSD 10. OBB #r L- . 02268 #z - .0ae97 #: - .01863 Errors LC Low LC Pass LC Pass 30.000 30.000 - .01000 - .01000 LC Pass LC Pass LC Pass 10.000 40.000 500.00 -.00500 -.00500 s.0000 LC Pass LC Pass 50.000 l.400.0 - .02500 - .10000 NOCHECK NOCHECK LC Pass 700.00 -s.0000 LC Pass NOCHECK 100.00 -.04000 NOCHECK LC Pass LC Pass 4.0000 800.00 - .02000 -s.0000 LC Pass LC Pass Appendix F - 354 349 Analysis Report 03/10/oG 11:76:36 PM page 2 High 70.000 100.00 10.000 40.000 40.000 5.0000 10.000 Low -.02000 - .02500 - .02000 -.50000 - .04000 - .05000 - .05000 EIem Ti Sn Si P_ Pb Se Units ppm ppm ppm ppm ppm ppm Avge 1.9523 . 04030 . 19548 1 . 0894 .00355 . 00073 SDev -0132 .00106 .00062 .0090 .00014 .00071 zRSD .57242 2.6384 .31508 .8272s 3.8724 96.770 #1 1.9s90 .04077 .a9478 1.0894 .00341 .00016 #2 1.9511 .03908 .a95'76 1.0803 .00368 .00051 #3 1-.9768 .04105 .19591 1.0983 .003s7 .00152 ' Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.05000 -.10000 -1.0000 - .30000 -.00400 -.01000 Intstd 1 Mode Counts EIem Y Wav1en 37 7. 0 3 0 Avge 24094 SDev 198 . 118 9 ?RSD .8222905 #r 23984 #z 24322 #: 2397 5 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 355 3s0 Analysis Report Method: TRA20505 Run Time: 03/a0/06 Comment : Mode: CONC Corr. Elem A1 Units ppm Avge .94959 SDev .01017 ?RSD 1.071,2 #r #z #: . 9 451,7 .94255 .96l-34 Errors LC Pass High 700.00 Low - .20000 EIem Cr Units ppm Avge 00091 SDev . 00 046 ?RSD s0. 692 #r #z #: 00101 00132 00041 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .00161 SDev .00008 , %RSD 4.8'723 #r #z #3 00157 00157 00170 Errors LC Pass High 30.000 Low - .01500 EIem T1 Units ppm Avge -.01514 SDev .00263 u RSD 77 .399 #t- #z #: Errors - .07240 - .01536 - - 01,7 65 LC Pass Sample Name: HXQ3DZ20 23:15:40 03/1,0/06 11:22:49 pM Operator: LC Pass LC Pass 20 .000 30.000 - .06000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00500 L2438 72 .923 124]-7' 72. 843 l-2779 13 .155 LC Pass LC Pass 40.000 500.00 - .00500 -5.0000 Fact.or: Sb ppm - .00046 .00053 138.3s .00026 - .00091 - .00073 Co ppm .00039 .00072 184 .3s . 0 0 ),21, - .00005 - .00000 K_ ppm .09l-64 . 01 528 16. 678 . 10 026 .07399 .10055 V_ ppm .00052 . 0 011s 222. s5 .001,78 .00027 - .0004s LC Pass As ppm .00079 .00082 702 .7 4 .00L66 .0005e .00003 Cu ppm .01096 .00030 2 --1373 .01125 .01055 .01098 Ni ppm .00356 .00047 13.2l-8 .003s4 .00309 .00403 Zn ppm .36572 .00476 1.3020 .3 6247 .36351 .3711 9 Ba ppm 1.8344 .0239 1.3005 1. Ba34 1.829s 1 . B 504 Fe ppm .06941, .00784 11.301 .07803 .06269 .05752 Se/t ppm .00t28 .00139 108.45 .00007 .00280 .00091 Be ppm .00094 .00008 8.7 3sB .00103 .00091 .00087 Pb/1, ppm - .00203 .00l'27 6,2 .687 - .00345 - .00168 -.00097 Se/z ppm - .00015 . 0 0118 77!. B9 .00720 - .00073 - .00093 Mo ppm .00082 .00040 48. 532 .00082 . 0 01,22 .00042 LC Pass Cd ppm .1252s .00159 1.3457 Pb/2 ppm .00363 . 0 0l-47 40.585 .00505 .002L1_ .00372 Ag ppm .00026 . 0 0 1,1,2 435.90 .00702 - .00103 .00078 Li ppm .00062 .00001 7.2435 .00053 .00062 .00062 LC Pass page 1 Ca ppm 72 .97 4 .162 7 .2464 Mg ppm 1.1692 .0477 1.5L44 1 . 1662 1.1532 1.1882 Na ppm 7.69'74 .0595 4.0958 7.7260 1 . 6181 1, .7 4 81 Sr ppm .02058 .00027 1.0065 .02052 .42061 .02092 LC Pass LC Pass LC Pass 100.00 50.000 - .0s000 - .02s00 LC Pass NOCHECK 1400.0 - .10000 NOCHECK LC Pass 700.00 -s.0000 LC Pass LC Pass 200.00 100.00 -5.0000 -.04000 NOCHECK NOCHECK LC Pass LC Pass 4.0000 800.00 -.02000 -5.0000 B- ppm .00l-57 .000s9 37 . s03 .00L79 .00091 .00202 Pass LC Pass Appendix F - 356 LC 351 Analysis Report 10.000 - .02000 Si ppm .18905 .00s27 2 -754a .18889 .18393 .19434 LC Pass 40.000 -1.0000 3 40.000 - .50000 P_ ppm 7.2868 .0223 7 .7 322 7.2658 I .2844 1.3L02 LC Pass 40.000 - .30000 4 40.000 -.04000 Pb ppm .00278 .00073 33.623 .00256 .00734 .00265 5.0000 - .05000 Se ppm .00052 .00057 92 .397 . 0 01,12 .000'73 -.00000 page 2 10.000 - .05000 03 / 70 / 05 11 : 22:49 PM High Low El em Units Avge SDev ?RSD #r #z #g 70 .000 100.00 - .02000 - .02s00 Ti ppm t .4985 .0183 1, .221,2 7.4850 1.4900 1. s195 Errors LC Pass High 40.000 Low - .05000 Intstd 1 Mode Counts EIem Y Wavlen 371. 03 0 Avge 24052 SDev 227 . 13 00 ?RSD .9443237 #1 #z #: 23992 243 03 23867 Sn ppm .0447 4 .00093 2 .07 87 .04367 .04535 .04519 LC Pass 40.000 - .10000 2 LC 70 5 Pass LC Pass .000 30.000 00400 - .01000 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F 357 352 Analysis Report Method: TRA20505 Sample Name: H0HPEZ50 Run Time : 0 3 / 70 / 05 23 :22 :53 Comment : Mode: CONC Corr. Factor: 1 03/70/06 11:29:03 pM Operator: page 1 Cd Ca ppm ppm -.00011 .01624 .00009 .00058 79.831 4.2At2 BIem AI Units ppm Avge - .04770 SDev .00086 ?RSD I .7 95 I #r #z #: -.04679 - .04849 -.04781, Errors LC Pass High 700.00 Low -.20000 EIem Cr Units ppm Avge .00051 SDev .00252 ?RSD 494 . 96 #r #z #: .00208 00295 00066 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge -02330 SDev .00021, ?RSD .89769 #r #z #: 02372 02325 02353 Errors LC Pass High 30.000 Low - .01500 EIem TI Units ppm Avge .00080 SDev .00202 ?RSD 251,. 5 0 #r #z #: Errors .00026 .00304 - .00089 LC Pass LC Pass LC Pass 20.000 30.000 - .06000 - .01000 Sb ppm -.00202 . 0 01,25 51.944 00340 o 0l-51 00098 Co ppm .00019 .00033 171.66 - .00006 .00007 .00057 K_ ppm .05815 .0132s 22 .7 B4 .05367 .04774 .47308 V- ppm - .00028 .00028 100.03 - .00055 - .00031 .00001 LC Pass As ppm .00130 .001,77 13 0 .96 .00228 - . 0 0067 .00229 Cu ppm 28. BB6 .327 1.1323 28 .7 84 28 .622 29 .2s2 Ni ppm 3.1644 .0519 I .5402 3.1447 3 .1252 3 .2233 Zn ppm .04501 .00044 .9s900 .04599 .04558 .04647 Ba ppm .0041,3 .00004 .99257 .00409 . 0 0 41,1, .00411 LC Pass 30.000 - .01000 Fe ppm .01981 .01599 80.743 .00670 .03763 .01510 Se/t ppm . 0 01,62 .0027l. t6'7. BB .00459 .00098 -.00072 B_ ppm .00098 .001,22 424.55 .00229 - .00013 .00078 Be ppm .00085 .00077 20 .15 9 .00076 .00105 .00075 Pb/7 ppm -.00067 .00334 500. BB .00318 -.00240 - .00278 Se/z ppm -.00026 . 0 0l-43 552.19 - .00175 . 0 0110 - .00013 Mo ppm .00038 .00038 101 . 1B .00053 - .00006 .00067 LC Pass - .00007 -.00022 - .0000s - .00218 . 0 01,43 .00077 Ag ppm - .000s4 . 0 0 1,1,4 zlt. 5 9 Li ppm .00032 .00002 5 .6022 .00030 .00034 .00034 LC Pass 01576 015 94 0l-7 02 .00031 - .00109 .00089 Na ppm - .13900 .79885 143 - 07 Sr ppm .0000s .00001 22 .987 .00004 .00005 .00007 LC Pass LC Pass LC Pass LC Pass 10.000 40.000 600.00 -.00s00 -.00500 -5.0000 Pb/ 2 Mg ppm ppm - .00001 .00004 .00191 .00702 767L7 . 2851.1 LC Pass LC Pass 100.00 s0.000 - .05000 - .02s00 LC Pass NOCHECK 1400.0 - .10000 NOCHECK LC Pass 700.00 -5.0000 -.00101 .07744 -.00t37 -.3l.362 .00076 - .18081 LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHECK NOCHECK LC Pass LC Pass 4.0000 800.00 -.02000 -s.0000 LC Pass LC Pass Appendix F - 358 353 Analysis Report High Low EIem Ti Units ppm Avge . 00 044 SDev .00006 %RSD 13. 8s2 #r #z #3 00051 00041 00040 Errors LC Pass High 40.000 Low - .05000 Intstd 1 Mode Count, s EIem Y Wavlen 371. 03 0 Avge 24425 SDev 3 53 .8617 %RSD 1 .4487 86 #r #z #: 24400 24790 24 084 70.000 100.00 -.02000 - .02500 Sn ppm .- 84 q23 .01405 7 .662! .84362 .83366 .85142 LC Pass 40.000 - .10000 2 NOTUSED 10.000 - .02000 Si ppm - .0l-743 .00198 11 . 354 - - 01,746 - .0]-940 - . 01,544 LC Pass 40.000 -1.0000 40.000 - .50000 P_ ppm .2081_2 .00263 7 .25 31 .207 2'0 .20607 .2l_1 0 B 40.000 -.04000 Pb ppm .00018 .00033 183 .95 .00001 .000s6 - .00004 LC Pass LC Pass 40.000 70.000 - .30000 - .00400 03/to/05 11:29:03 PM page 2 5.0000 10.000 - .05000 - .05000 Se ppm .00055 .00069 105.08 .00065 .00135 - .00004 LC Pass 30.000 - .01000 34 NOTUSED NOTUSED 567 NOTUSED NOTUSED NOTUSED Appendix F - 3s9 354 Analysis Report Method: TRA20505 Sample Name: HXQ1XP25 Run Time : 0 3 / 10 / 05 23 :29 :07 Comment : Mode: CONC Corr. Factor: 1 03/70/06 11:35:16 PM Operator: Sb ppm . 00 072 .00742 \97.51 -.0002a .00235 .00001 Co ppm .00089 .00048 54 .0L7 .00139 .00083 .00044 LC Pass 100.00 - .05000 K_ ppm .10497 .01081 10.294 .11736 .10001 .097s3 V_ ppm .00116 .00085 72 .652 .00199 . 0 01,20 .00030 LC Pass As ppm . 0 01,12 .00060 53 . 3-11, . 0 0l-71, .00t1,2 .00052 Cu ppm .011s8 . 0 0 045 3.9330 .01191 . 01l.7 7 .01106 LC Pass s0.000 - .02500 Ni ppm .0020l- .00059 34 .602 .00279 .00147 .001,76 Zn ppm .277 26 .00073 . 3 319]. .21-t 9 0 .27546 .217 42 Ba ppm 1.5264 .0111 .7 3 022 1. s215 1 - 51,47 1. s369 Fe ppm .05511 .00397 5.1008 .06880 .06553 .05091 LC Pass 1400.0 - .10000 se/t ppm .002.34 .00245 104 .7-/ .00516 .000'72 .00113 B- ppm .00490 .00070 14.359 00571 00458 00442 Be ppm .00093 .0001s 15 . 544 .00075 .00100 .00103 Pb/7 ppm .00245 .00373 151 .99 .00662 - .000s7 .00132 Se /z ppm .00008 .00086 1098,6 - .00061 .00104 - - 00020 Mo ppm .00081 .00025 30. 621 .00110 .00070 .00064 LC Pass Cd ppm . 07 787 .00081 1.132L .07272 . 07111 .07l.77 Pb/2 ppm .00428 . 0 0151 3s.381 .00258 .00s69 .00446 Ag ppm .00161 .00091 55.409 .00262 .00138 .00084 Li ppm .000s1 .00009 L7 .981 page 1 Ca ppm 13 . 349 .093 .59s90 13 . 426 13 . 246 13 .375 Mg ppm .9131s .00600 .65706 .91951 .90759 .91234 LC Pass 700.00 -5.0000 Na ppm 1.3229 .2992 22 .674 1- . 5682 1.1557 1.1441 Sr ppm .02621 .00018 .69300 EI em AI Uni t. s ppm Avge .7 4945 SDev .00832 ?RSD 1.1097 #r #z #: .7 5867 .7 425t .7 41 17 Errors LC Pass High 700.00 Low 20000 EIem Cr Units ppm Avge .00082 SDev .00100 ?RSD 12A .97 #r #z #: Errors High Low .00195 .00046 .00005 LC Pass 100.00 - .01.000 LC Pass LC Pass 20 .000 30.000 - .05000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 -.00500 LC Pass LC Pass 40.000 600.00 -.00500 -5.0000 NOCHECK NOCHECK EIem Mn Units ppm Avge .00144 SDev .00010 ?RSD 6.8823 #r #z #3 00151 00132 00140 Errors LC Pass High 30.000 Low - .01500 EIem TI Units ppm Avge L- . 0277"7 SDev .00042 %RSD \ .9484 #r L- . 02728 #z L- . 02199 #: L- . 02205 Errors LC Low LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHECK NOCHECK LC Pass LC PAss 4.0000 800.00 -.02000 -5.0000 00050 .02529 00051 .02600 00042 . 02634 LC Pass LC Pass Appendix F - 360 LC Pass LC Pass 355 Analysis Report 03/to/06 11:35:16 PM page 2 High 70.000 100.00 10.000 40.000 40.000 5.0000 10.000 Low -. O2OOO - .02500 -. O2OO0 - .50000 -. O4OO0 -.05000 - .05000 EIem Ti Sn Si P_ Pb Se Unj-ts ppm ppm ppm ppm ppm ppm Avge 2.0334 .03221 .L2268 .99884 .00405 .00114 SDev .0118 .00071 .00242 .00587 .00023 .00055 zRsD .58183 2.2059 1.97s3 .58738 5.5471, 48.045 #1 2 -0393 .03275 .L2547 .99540 .OO42g .00161 #2 2.0198 .03246 ,721,31, 1- 0056 .OO402 -OOa27 #3 2.0412 .03140 .1-2L24' .99550 .00383 .000s4 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low - .05000 - .10000 -1 . 0000 - .30000 - .00400 - .01000 Intstd 1 Mode Counts Elem Y Wavlen 371.030 Avge 23875 SDev 228.5230 ?RSD .9571,6L8 #r 236L2 #z 23986 #: 24 02'7 234567 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 36r 3s6 Analysis Report QC Standard Method: TRA20505 Sample Name: CCVS Run Time : 0 3 / t0 / 06 23 :35 :20 Comment : Mode : CONC Corr - Factor: 1 03/70/06 11:4:-:29 PM Operator: EIem AI Units ppm Avge 22.859 SDev .272 ?RSD 1.1905 Sb ppm . 4629 5 .00557 I .2257 .45697 .46365 .46826 Co ppm 1.855'7 .0296 1. s933 1.8234 1.8622 1. BBL4 QC Pass 2.0000 10. s00 K_ ppm Q43'..980 .327 .74338 QC Fail 50.000 10.500 V_ ppm 1.8265 . o22s 7.2308 1.8021, 1.8309 1.8464 QC Pass As ppm .45690 .00778 1_ .7 032 .44873 .45775 .45423 Cu ppm 1.8084 .0223 L.23 11 Q1 .78s1 1. B]-AT 1.8295 QC Pass 2.0000 10.500 Ni ppm 1.8311 . 0249 1.3572 1.8051 1.8336 1.8546 Zn ppm 1. BB3B . 021,5 1.1422 Ba ppm 1.8139 .0189 1.0413 1.7942 1.8156 1.8319 Fe ppm 22.885 .315 1.3743 22 .549 22.938 23 .1,71 QC Pass 25.000 10.500 Se/1, ppm . 46 3 5 9 .00397 .8s630 .46509 .46658 .45908 Be ppm 1.8722 .0195 1.04]-7 1.8501 1.8793 1. BBTt Pb/r ppm .46351 .00297 .64016 .46590 .46444 .46019 Mo ppm 1.8678 .0310 1.6603 1.8335 1.8756 1 . B 942 Cd ppm .4529L .00490 1.0825 .441 57 .4541,7 .45707 Pb/2 ppm .4s905 .00984 2 - 1,442 Li ppm 1.8396 .0098 .53301 1.8292 1.8410 1. B4B7 QC Pass page 1 Ca ppm 46.859 .480 1.0237 45.315 47 .034 47 .226 Mg ppm 44 .897 .500 1.3367 Sr ppm 1.87]-3 .0193 1.0308 1.8505 1. B748 1. BBB5 QC Pass #r #z #: 22 -57-l 22. BB0 23.720 Errors QC Pass QC Pass Value 25.000 .50000 Range 10.500 10.500 QC Pass QC Pass . s0000 2.0000 10 .500 10. s00 QC Pass QC Pass QC Pass 2.0000 .s0000 s0.000 10.500 10.s00 10.500 EIem Cr Units ppm Avge 1. Bl02 SDev . O22B ?RSD L.2584 #r #z #: Q1 .787A 1.8110 1 . 8325 Errors QC Pass Va1ue 2.0000 Range 10.500 Elem Mn Units ppm Avge 1. B1B5 SDev .0240 ?RSD 1.3184 #r #z #: - 447 81, Q44 .237 .46323 45 .045 .46 6 13 4s . 409 NOCHECK NOCHECK QC Pass 50.000 10.500 1 1 1 '7939 Q43.651 8198 Q43.984 B41B Q44.304 Se/ z Ag ppm ppm .44481 Q.e9449 .00591 .00988 1 .3 41-9 1. 1043 .43797 Q.gB39s .44756 .89599 .44892 . 90354 NOCHECK Na ppm 46 .737 .46a .99823 45.700 46.093 46.618 QC Fail QC Pass 1.0000 s0.000 10.500 10.500 Errors QC Pass Value 2.0000 Range 10.500 Elem TI Units ppm Avge . 93 298 SDev .00801 %RSD .85833 #r #z #: Errors .92380 .93564 .938s0 QC Pass QC Pass NOCHECK 2.0000 10 .500 B- ppm Q1. 6822 .0150 . 9 4919 1 1 1 8501 Q1. 654s BB93 Q1 .6867 9021, Q1 . 6954 QC Pass QC Fail Appendix F - 362 QC Pass 357 Analysis Report QC Standard a3/ta/06 11:41 :29 PM page 2 2.0000 10.500 Value Range 1.0000 10.500 2.0000 10. s00 Sn ppm 1.8290 .0198 1.0845 2 NOTUSED 2.0000 10. s00 Si ppm 1.7 909 .0299 1.5695 QC Pass QC Pass QC Pass 2.0000 2.0000 2.0000 10.500 10.500 10.s00 2.0000 10. s00 Pb Se ppm ppm .46 0 95 .4513 s .00s81 .00351 L.2601 .80009 .4s425 Q.4 4729 . 46413 .454 1B .46448 .45259 QC Pass QC Pass . s0000 . s0000 10. s00 10.500 567 NOTUSED NOTUSED NOTUSED 2.0000 10.500 P- ppm 1 . B 999 .0246 7.2960 1 . B'7 L-t 1.9108 1.9772 2.0000 10.500 EIem Ti Units ppm Avge 1.9153 SDev .0212 ?RSD 1.1082 #r #z #s 1.893'7 1.9193 1.9358 Errors QC Pass Value 2.A000 Range 10.500 InLStd 1 Mode Counts Elem Y Wavlen 31L.030 Avge 243 01, SDev 106 .4877 ?RSD .438204a #r #z #3 244L2 2420 0 24291 8064 Q1.1s92 8370 7..7949 8435 1. 8186 1 1 1 34 NOTUSED NOTUSED Appendix F 363 3sB EIem Al Units ppm Avge -.06135 SDev .00815 ?RSD 13 .289 Analysis Report Method: TRA20505 Sample Name: CCBS Run Time: o3/70/06 23:41:33 Comment : Mode: CONC Corr. Factor: 1 03/to/06 11:47:42 PM Operator: page 1 Cd Ca ppm ppm - .00007 .01116 .0001,2 .00038 474.73 3.4191_ .00004 .01143 -.00019 .01073 - .00005 .011,34 LC Pass LC Pass .00082 .05500 - .00082 - .05500 Pb /2 ppm .00105 .00039 37 . l2t .00066 .00105 .00444 Mg ppm - .00045 .00318 705.s2 .00103 - .00410 - 0 0l_-11, Ag ppm -.00048 .00118 246. 0B -.00040 - .00170 .00066 Na ppm - .1907s .15161 84 .1 23 01459 332].s 22549 Sb ppm - .00155 .00133 80. 4l.4 00145 00307 00043 Co ppm -.00024 .00050 21,2 - 53 K- ppm .01895 .01497 18.960 .08261, . 06 2so .09]-77 LC Pass .3220 0 - .32200 V_ ppm - .00043 .00115 268 . 87 .00002 - .00173 .00043 LC Pass As ppm .00087 .00100 115.09 .00787 .00086- - .00013 Ba ppm - .00019 .00008 42.388 00014 00029 00015 Fe ppm .00282 .01144 406.25 .00138 - .01020 .01l.27 LC Pass .04900 -.04900 Se/t ppm . 0 0l.67 .00310 185 .24 .00276 .00450 -.00464 B- ppm .00256 .00096 3-1 .635 .00367 .00202 .00198 Be ppm .00l.22 .00032 26 .7 45 .0008s .00L49 .00131 Pb/1, ppm - .00199 .0021,5 108.3s - .00093 - .00057 -.00447 Se/z ppm - . 0 01,4'7 .00151 t02 . 87 - .00113 - . 0 031,2 - .00016 Mo ppm .00190 .00095 49 . Bt1 .00298 .00151 .00]-22 LC Pass #r #z #3 - .055s5 -.07077 - .05615 Errors LC Pass High .10s00 Low - .10500 EIem Cr Units ppm Avge -.00042 SDev .00043 ?RSD IO2. 3 B #r #z #3 .00007 - .00059 - . 0 007 4 Errors LC Pass High .00350 Low - .00350 Elem Mn Units ppm Avge .00029 SDev .00006 ?RSD 20 .647 #r #z #: .0003s .00023 .00028 Errors LC Pass High .00180 Low - .00180 Elem Tt Units ppm Avge .00169 SDev .00028 ?RSD A5 .520 #r #z #: Errors .00189 .00737 .00181 LC Pass LC Pass LC Pass .01400 .00330 -.01400 -.00330 LC Pass LC Pass .00160 .00180 - .00160 - .00180 Cu ppm H.00816 .00063 7 .7542 .00005 H.00BB0 -.00082 H.00753 .00005 H.00B1s LC Pass LC High .00220 .00700 -.00220 -.00700 NOCHECK NOCHBCK LC Pass .04900 - .04900 Ni ppm - .00016 .00044 268.55 .00032 -.00027 - .00054 LC Pass .00380 -.00380 Zn ppm .00016 .00001 8. B6s1 .00014 .0001,7 .00015 NOCHECK NOCHECK LC Pass LC Pass .0091 0 1-.4730 -.00970 -1.4730 Li ppm .00133 .00032 23 .7 52 .001,66 .00131 .00103 LC Pass Sr ppm -.00001 .00001 133 . BB - .00000 - .00002 - .00000 LC PassLC Pass LC Pass Appendix F - 364 359 Analysis Report 03 /1,0 / 06 11 : 47 :42 PM page 2 .0021 0 .00130 -.00270 -.00130 Se ppm - .00014 .00034 253 .62 EIem Ti Units ppm Avge .00011 SDev .00012 ?RSD 111.49 High Low #r #z #s Errors High Low #r #z #: .01000 - .01000 - .00003 .00015 .00019 LC Pass .00150 -.00160 240-7 2 25067 24390 .00s00 - .00s00 Sn ppm .00042 .00049 Lt7 .7 5 .00007 .00098 .0002L LC Pass .00770 -.00770 2 .00380 -.00380 Si ppm - .02487 .00228 9 -1,511 02284 02734 02444 LC Pass .05500 - .0ss00 3 .03100 - .03100 P- ppm - .00117 .00245 208 .87 - .00027 -.00394 .00070 LC Pass .02100 - .02100 4 .00880 - .00880 Pb ppm .00048 .000s3 111 . 67 LC Pass .00370 - .00370 5 LC Pass .00430 -.00430 5 00063 .00026 00092 -.00030 .00011 - .00036 Int Std 1 Mode Counts EIem Y Wav1en 371,.030 Avge 245L0 SDev 507 .9984 z RSD 2 . 07 2641, NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix 36s 350 Analysis Report Method : TRA2 05 05 Sample Name : HOHPCZ2 0 Run Time : 0 3 / 70 / 06 23 :47 :46 Comment : Mode: CONC Corr. Factor: 1 03/1,0/oG 11:53:55 PM OperatoL: Sb ppm -.00136 .00064 46 .7 69 00209 00101 00097 LC Pass 20.000 - .05000 Co ppm .00980 .00027 2.7 355 .01003 .00985 .00951 LC Pass 100.00 - .05000 K_ ppm .16386 .00424 2 .5844 .16389 .15 961 .16808 LC Pass 200.00 -5.0000 V- ppm - .00171 .00029 16 .944 -.00192 - .00138 - .00183 LC Pass As ppm .00013 .00L1,2 848.25 - .00113 .00099 .000s4 Cu ppm .01030 .00018 I .7l.02 .01072 .01048 .01029 Ni ppm .44727 .00070 7 .4802 .04651 .047 42 .04788 Zn ppm 4 .1,57 4 .0]-92 .45728 4.l-535 4.A593 4 . AB94 Ba ppm - .00011 .00004 39.720 - .00010 - .00007 - .00016 Fe ppm .03735 .00495 13 . 2s4 .0371,5 .04240 . 03 25t Se/t ppm .00681 .00064 9.3s38 .006s1 .0076a .00648 B- ppm . 0 0111 .00078 '70.001 .00026 .00429 - 001,79 00125 0 0a27 0 0115 Pb/1, ppm .00057 .00378 563 .15 -.00017 .00035 -.00272 .00061 - .00005 .00033 LC Pass .0001 6 .00076 .00074 Pb/ 2 ppm - .00088 .00775 799.33 00339 00320 00381 .00017 .00070 .00080 LC Pass page 1 Ca ppm .04558 .000s1 1.1188 .04509 .04588 .04505 Mg ppm - - 0 31,23 .00140 4.4'727 03181 029 63 43224 Na ppm 3 .7 903 .1,423 3.7 541 3 .65l-7 3.7 831 3.9350 Sr ppm .00022 .00001 4.7413 .00022 .00022 .0002]. LC Pass EIem A1 Units ppm Avge -.04857 SDev .00294 ?RSD 5.0610 #r #z #3 0 4957 04s26 0s089 Errors LC Pass High 700.00 Low - .20000 Elem Cr Units ppm Avge . 013 01 SDev .00097 ?RSD 7 .4525 #r #z #3 01,240 01250 01413 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge H35.043 SDev .118 ?RSD .328 7 O #r #z #: H3 5 . 93 B H3 5 .020 H3 6 .772 Errors LC High High 30.000 Low - .01500 Elem T1 Units ppm Avge . 0177 4 SDev .00148 ?RSD 8.331,4 #r #z #: Errors .01835 .01646 .01882 LC Pass Be Cd ppm ppm .00423 .00076 .00005 .00001 4.8041 1.5439 LC Pass LC Pass 30.000 30.000 - .01000 - .01000 LC Pass LC Pass LC Pass 10.000 40.000 600.00 -.00500 -.00500 -s.0000 LC Pass LC Pass 50.000 1400.0 - .02500 - .10000 NOCHECK NOCHECK LC Pass 700.00 -5.0000 -.00289 .00054 .00027 - .00034 .00464 - .00283 Se/ 2 Ag ppm ppm - .00104 .00347 .001s5 .00032 749.55 9.0755 LC Pass NOCHECK 100.00 - .04000 NOCHECK LC Pass LC Pass 4.0000 800.00 - .02000 -5.0000 Mo Li ppm ppm .00029 .00076 .00033 .0000s 113.38 6.59-7a LC Pass LC Pass Appendix F - 366 361 Analysis Report High Low #r #z #: Errors High Low #r #z #: '70.000 - .02000 .00007 .00019 .00002 LC Pass 40.000 - .05000 240 As 241,53 24008 10.000 - .02000 Si ppm -.00577 .00160 2s .949 LC 40 -1 3 00559 00494 00798 Pas s .000 .0000 40.000 -.50000 P- ppm .00783 .00010 L.2836 .00794 .00778 .007'76 LC Pass 40.000 - .30000 4 40.000 - .04000 - .00010 .00035 .00015 LC Pass 70.000 - .00400 5 5.0000 - .0s000 .00199 .00306 .00058 LC Pass 30.000 - .01000 6 page 2 10.000 - .0s000 03/to/06 11:53:55 PM Elem Ti Units ppm Avge .00009 SDev .00008 ?RSD 88.779 100.00 - .02s00 Sn ppm .00052 .00062 L1,7 . 81 .00074 - .00017 .00100 LC Pass 40.000 - .10000 2 Pb Se ppm ppm .00014 .00191 .00023 .00120 L67. s0 52. s58 Intstd 1 Mode Counts Elem Y Wavlen 377.030 Avge 24055 SDev 84.85725 ?RSD .3527566 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 367 362 Analysis Report Method: TRA20505 Sample Name: HOHPKZS0 Run Time: o3/70/oG 23:53:59 CommenL : Mode: CONC Corr. Factor: 1 03/71,/06 oo:oo:08 AM Operator: Sb ppm .00860 .00134 15 . 567 .00708 .00908 .00963 Co ppm . 01s7 5 .00029 1.8556 .01s42 .01590 .0159s LC Pass 100.00 - .0s000 K_ ppm .46546 .01449 3 .021,5 .45080 .47 8]-2 .4704s V_ ppm .01843 .00045 2.436s . 01828 .01894 .01808 LC Pass As ppm .007l-4 .00081 11.334 .00742 .00777 .00622 Cu ppm 3.5427 .0724 .35010 3 .5320 3 .5563 3.5398 LC Pass s0.000 - .02s00 Ni ppm .1 9 446 .00828 1.0425 .-/8579 .80229 .79531 Zn ppm 1 . 9294 . o72B .66271 9]-6 4 9 420 929-7 Ba ppm .23248 .000s2 .224 0 0 .232l-5 - .23308 .23222 Fe pprn 9 .9969 .08s6 .85554 9.9009 10.055 10. 025 Se/7 ppm .0048s .00180 37.054 .00515 .00280 .00s51 B- ppm . 03 235 .000s6 1.7 390 . 03 299 . 03 216 .03191 Be ppm .00104 .00004 3 .5918 .00101 . 0 0]-02 .00108 Pb/7 ppm .08517 .00185 2.a749 . 0B 665 .08310 .0857s Se/z ppm .00191 .00779 93.241, .00008 .0035s .00202 Mo ppm .2256-/ .0030s 1.350'7 . 2223 4 .22833 . 2263 4 LC Pass Cd ppm .00049 .00008 15 .762 .00053 .00055 .00040 LC Pass 40.000 - .00500 Pb /2 ppm .08487 .00187 2 .201,2 .08323 .0859]- .08447 Ag ppm .0235s .00075 3 . 1666 .02293 .02438 .02334 Lr ppm .05450 .00013 . 1 9337 .06436 . 06 459 . 06 457 LC Pass page 1 Ca ppm 3. B0B5 .0338 .88794 3 .71 07 3.8357 3 .8193 LC Pass 500.00 -5.0000 Mg ppm 1.5780 . 01,42 .89873 1.5527 1 . 5 907 1. s805 Na ppm 1.1319 .0233 2 .0566 1.1083 1 .1327 1.1548 Sr ppm . 03 287 .00014 .42360 .03273 .03301 . 03 286 LC Pass EIem AI Unit s ppm Avge 2 .4755 SDev . 013 B %RSD . 55 928 #r #z #: 2.4606 2.4880 2.4780 Errors LC Pass High 700.00 Low - .20000 Elem Cr Units ppm Avge .02705 SDev . 00 064 ?RSD 2.3528 #r #z #: 02637 027 16 027 63 Errors LC Pass High 100.00 Low - .01000 EIem Mn Units ppm Avge .08861 SDev .00048 ?RSD .54051 #r #z #: OBB13 08909 OBB61 Errors LC Pass High 30.000 Low - .01500 EI em T1 Units ppm Avge -.00448 SDev .00413 ?RSD 92 .777 #r #z #: Errors -.00922 - .00153 - .002s9 LC Pass LC Pass LC Pass 20.000 30.000 - .05000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00s00 LC Pass NOCHECK 1400.0 - .10000 NOCHECK LC Pass 700.00 -5.0000 LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHECK NOCHECK LC Pass LC Pass 4.0000 800.00 - .02000 -5.0000 1 1 1 Pass LC Pass Appendix F - 368 LC 353 Analysis Report 03/tt/06 oo:oo:oB AM page 2 5.0000 10.000 -.05000 - .05000 Se ppm .00320 .00070 22 .042 .00239 .00370 .00350 High Low 70.000 -.02000 100.00 -.02s00 Sn ppm .05000 .00131 2.7783 .059].7 . 05 932 .06151 LC Pass 40.000 - .10000 10.000 - .02000 Si ppm .11867 .00309 2.6038 .11903 . 1,215 6 .11541 LC Pass 40.000 -1.0000 40.000 - . s0000 P_ ppm .81985 .00475 .58106 .81807 .82526 .81625 40.000 -.04000 Pb ppm .08s34 .00064 .74519 .08475 .08501 .08527 Elem Ti Units ppm Avge .42099 SDev .00198 ?RSD .4597 6 #r #z #: .41898 .42293 .42105 Errors LC Pass High 40.000 Low - .05000 Intstd 1 Mode Counts Elem Y Wavlen 371. 03 0 Avge 24299 SDev 1,49.3865 ?RSD .514785]- #r #z #3 24352 24]-3 0 24474 23 NOTUSED NOTUSED LC Pass LC Pass LC Pass 40.000 70.000 30.000 -.30000 -.00400 -.01000 4 NOTUSED 567 NOTUSED NOTUSED NOTUSED Appendix F - 369 364 Analysis Report Method: TRA20505 Sample Name: HOHPXZS0 Run Time: 03/t1,/06 00:00:12 Comment : Mode: CONC Corr. FacLor: 1 03/11 /oe 0O:a6:21, AM Operator: page 1 Cd Ca ppm ppm -.00004 .05248 .00004 00077 10 5 .29 1, .23 07 Elem A1 Units ppm Avge - .05380 SDev .00245 ?RSD 4 .5524 #r #z #: 05358 05L47 0s53s Errors LC Pass High 700.00 Low -.20000 EIem Cr Units ppm Avge .00001 SDev .0002L ?RSD 3694 .9 #r #z #: .00024 -.00018 - .00004 Errors LC Pass High 100.00 Low - .01000 Elem Mn Units ppm Avge .00648 SDev .00011 ?RSD I .1 640 #r #z #: .00660 .00637 .00647 Errors LC Pass High 30.000 Low .01500 Elem Units Avge SDev ?RSD #r #z #: Errors TI ppm .00092 . 0 01,20 1,29 .94 .00077 -.00019 .00279 LC Pass Sb ppm 1.5623 .0059 .37980 1. s686 1.5558 1.5576 Co ppm - .00023 .00006 26 .923 00030 00023 00017 LC Pass 100.00 -.0s000 K- ppm .07374 .00158 2 .27 54 .07556 . o1 299 . 07 25'7 LC Pass 200. 00 -s.0000 V_ ppm ' .00095 .00026 21 .686 - .00079 - . 0 01,26 - .00081 LC Pass As ppm .00150 .00032 21, .17 4 .00161 .00l-14 .001_74 Cu ppm .00835 .00020 2 .3925 .00852 .00813 .00840 Ni ppm -.00022 .0001,7 77.326 00037 00003 00026 Zn ppm .00371, .00010 2.5931 .00381 .00362 . 0 0 369 Ba ppm .00050 .00002 3.4539 .00051 .00052 .00048 Fe ppm .00518 .00159 25.736 .00664 .00748 .00447 Se/1, ppm .00322 .00283 87 . BB7 .0064-7 _ 00l.32 . 0 0 1_B'/ B- ppm .00259 .000s8 22.350 .00266 .00198 .00313 Be ppm .00098 .00014 13 . 925 .00083 .00109 . 0 0]-02 Pb/7 ppm 1 . 31-44 .0071 .53874 1.322s 1.3108 1.3098 Se/2 ppm - .0004s .001,46 323. sB - .00001 .000'74 -.00207 Mo ppm .00091 .00031 34 - 523 .00101 .00116 .00056 LC Pass 00001 00009 00003 Pb/2 ppm 1.3026 .0062 .47781, 1.3067 t.2955 1.3057 Ag ppm -.00ta2 .00015 13 . s9B Li ppm .00058 .00004 6.8147 .00053 .00057 .000s5 LC Pass 06331 a6t7 9 0 6235 Mg ppm .00500 . 0 01,25 20 .7 91, .00742 .00s08 .00551 Na ppm - .0120s .09706 805 .20 Sr ppm .00010 .00001 5. s608 .00010 .00010 .00009 LC Pass LC Pass LC Pass 20.000 30.000 - .06000 - .01000 LC Pass LC Pass 30.000 10.000 - .01000 - .00500 LC Pass LC Pass 40 .000 600.00 -.00500 -5.0000 LC Pass LC Pass 50.000 1400.0 -.02500 - .10000 NOCHECK NOCHECK LC Pass 700.00 -5.0000 -.00099 .09330 -.00109 -.09785 -.00729 -.03161 LC Pass NOCHECK 100.00 - .04000 NOCHECK LC Pass LC Pass 4.0000 800.00 - .02000 -s.0000 LC Pass LC Pass Appendix F - 370 Analysis Report 03/lJ,/06 oo:06:2a AM page 2 High 70.000 100.00 10 - 000 40.000 40.000 5.0000 10.000 Low -.02000 -. O25OO -. O2O0O -.5O0OO -. O4OOO -.05000 -.05000 Elem Ti Sn Si P- Pb Se Units ppm ppm ppm ppm ppm ppm Avge ,00021 .00066 - . 016s3 .06497 1 .3070 .00109 SDev . OOO13 .00125 .00088 .00194 .0057 .00148 ?RSD 63.651 189.11 5.32L6 2.9793 .43845 136-33 #1 .00018 .00209 - .oLs62 .06707 7.3725 .00248 #2 .00009 -.00015 -.01658 .O64sg 1.3010 .OO1-25 #3 .00035 .00003 -.01738 .06325 7.3076 -.00047 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 40.000 40.000 40.000 40.000 70.000 30.000 Low -.05000 -.10000 -1.0000 -.30000 - .00400 -.01000 365 InESt.d 1 Mode Counts EIem Y Wavlen 37]-.030 Avge 24373 SDev 153 .0729 ?RSD .67 07292 #r 24127 #z 24430 #: 24387 234561 NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED NOTUSED Appendix F - 37 1 366 Analysis Report Method: TRA20505 Run Time: 03/Aa/Oe Comment : QC Standard Sample Name : CCV1 0 00 : 05:25 03 / tt / 06 oo : t2:34 AM Operator: EIem Uni ts Avge SDev ?RSD #r #z #: Errors Value Range Elem Units Avge SDev ?RSD #r #z #: VaIue Range EI em Units Avge SDev ?RSD #r #z #: Errors Errors QC Value 2. Range 1 0 EIem Units Avge SDev ?RSD #r #z #: A1 ppm 22 .945 .l-23 .53680 23.085 22.899 22 .852 Cr ppm 1.8359 .0182 .99222 Bs7 6 829 9 8232 Pas s 0000 .500 Mn ppm 1.8455 . ot42 .76992 1. B61B 1. B3B7 1.8359 2.0000 10.500 T1 ppm . 93 699 .00875 .93402 .94650 .93518 .92928 QC Pass Sb ppm . 46 6s6 .00l-44 .30784 . 467 29 .46491 .467 49 Co ppm 1. BB5B .0137 .'72606 1.9016 1. B786 1.8772 K_ ppm Q43 .944 .280 .53 622 Q44.249 Q43 .BB2 Q43 .700 QC Fai I 50.000 10.500 V- ppm 1.8473 .0136 .7 37 27 1.8628 1.8414 1.8376 QC Pass As ppm .4597 9 .00320 .69s51 .46330 .45903 .457 04 Cu ppm 1.8002 .0096 .535].4 1.8109 1.7972 7 .7 923 Ni ppm 1.8597 .0155 .834-74 1.8776 1. Bs20 1.8495 Ba ppm 1.8095 .0l-23 .67861 1.823"7'1 .8042 1.8010 Fe ppm 23 .282 .185 .80016 23 .494 23 .207 23.14s Se/r ppm . 46 424 .00522 1 . 1250 .47 oO2 .46285 .45985 Be ppm 1.8977 .0157 .829L7 1.9153 1.8932 1. B848 Pb/t ppm .46966 .00978 2 .0823 . 4807 2 .46611 . 4 621,6 Se/z ppm .4467 B .00339 .15805 .44647 .45031 . 443 5 5 Mo ppm 1. BBB2 .0104 . s5135 1.9001 1. BB42 1. BB05 Cd ppm .46095 .00455 .98793 .46511 .45925 .457 49 Pb/2 ppm .46491 .002l-5 .46343 Ag ppm .90737 .00753 .83532 .90984 . B9B82 .89s44 Li ppm 1.8337 .0137 .'7 46 63 1 . 84 8 B 1.8302 1 . 8220 QC Pass page 1 Ca ppm 47.769 .429 .89812 48 .242 47 . 65-7 47 .406 Mg ppm 45 .699 .385 . B4 s66 Na ppm 46 .257 .269 .58226 45.554 46 .19 0 46.028 Sr ppm 1.8706 . oL22 .64981 1.8844 1. B55B 1. B6L6 QC Pass Mode : CONC Corr. Factor: QC Pass QC Pass QC Pass 25.000 .50000 .50000 10.500 10.500 10.500 QC Pass QC Pass 2.0000 2.0000 10.500 10.500 QC Pass QC Pass .50000 50.000 10.500 10. s00 1 1 1 QC Pass QC Pass 2.0000 2.0000 10.500 10.500 QC Pass NOCHECK 2s.000 10. s00 .46641 46.138 .46587 45.547 .46244 45 . 41,2 NOCHECK QC Pass 50.000 10.500 Errors QC Pass QC Pass NOCHECK 2.0000 10.500 Zn B_ ppm ppm 1.9039 Q1.6923 .0158 .0118 . B2B2'l .6946'7 1. 92l-8 Q1.70s3 1. B9B0 Q1.6825 1.891,9 Q1 . 6892 QC Pass QC Fail Appendix F - 372 NOCHECK QC Pass QC Pass 1.0000 s0.000 10.500 10.500 QC Pass 357 Analysis Report QC Standard 03/tt/06 oo:t2:34 AM Value Range #r #z #: #r #z #: 1.0000 10.500 1.9370 1.9190 1.9153 23238 237 43 2407 2 2.0000 10.500 Sn pprn 1.8602 .0159 .85509 1. B7B0 1.8553 1.8473 2 NOTUSED 2.0000 10. s00 Si ppm 1. B05B .0131 .7 26 44 1.821-9 1.8002 1.7 983 2.0000 10.500 P_ ppm 1.9100 .0228 1.1950 1.9339 1.9077 1.8884 2.0000 10. s00 Pb ppm .46589 .00454 . 9718 3 . 4'71,6 9 .46629 .46268 2.0000 10 .500 Se ppm .4s290 .00314 .69434 .45466 .454'7 B .44927 page 2 2.0000 10.500 7 NOTUSED EIem Ti Units ppm Avge 1.9237 SDev .0115 ?RSD .50368 Errors QC Pass QC Pass Value 2.A000 2.0000 Range 10.500 10.500 QC Pass QC Pass 2.0000 2.0000 10.500 10.500 34 NOTUSED NOTUSED QC Pass QC Pass . s0000 . s0000 10 . s00 10 .500 56 NOTUSED NOTUSED Intstd 1 Mode Count s Elem Y Wavlen 371.030 Avge 23584 SDev 420.3203 ?RSD 1, .7'7 4693 Appendix 373 368 Analysis Report Met.hod: TRA20505 Samp1e Name: CCB10 Run Time: 03/11,/06 00:72:38 Comment : Mode: CONC Corr. Factor: 1 03/tt/06 oo:tB:47 AM Operator: LC Pass LC Pass .00160 .00180 - .00160 - .00180 page 1 Cd Ca ppm ppm -.00008 .01092 .00011 .00070 134.39 5 .3858 - .00009 .01020 .00003 .01150 - .00019 .01095 LC Pass LC Pass .00082 .05500 - .00082 - .05s00 Pb/ 2 ppm . 0 01,22 .00101 82.598 .00028 .00228 . 0 0110 Mg ppm .00146 .00370 49.598 .00855 .01041 .00331 Ag ppm .00050 .00088 77 6 .12 - . 0 0047 .00l_24 .00072 Na pprn - .23895 . 13 028 54 .52\ 1s569 1,7209 38910 LC Pass LC Pass .00970 7.4730 - .00970 -1. 4730 EIem A1 Units ppm Avge -.05944 SDev .00380 ?RSD 6.4010 Sb ppm - .0005s .00255 393.35 .00032 . 0 0728 - .003s4 LC Pass .01400 - .01400 Co ppm - . 00014 .00026 185.38 LC Pass .00220 -.00220 K- ppm .09410 .00892 9.4835 .08431, .10].77 .09622 LC Pass .322 0 0 -.32200 V_ ppm -.00029 .00109 382.11 - .00017 .000'74 - .00143 LC Pass As ppm .00015 .00089 543 .96 -.00047 . 0 0118 -.00022 LC Pass .00330 -.00330 Cu ppm H.00996 .00039 3 . 9110 LC High .00700 -.00700 Ni ppm - .00012 .00003 24 .941, -.00009 - .00014 - .00014 LC Pass .00380 -.00380 Zn ppm .00015 .00006 38.502 .00014 .0002l. .00010 Ba ppm - .00015 .00009 54 .824 - .00016 - .00007 -.00024 Fe ppm .00s62 .01051 187.06 .00206 . 017 44 -.0a265 Se/t ppm .00398 .00109 21 .3 67 .00423 .00278 .00491 B- ppm .00265 .00088 33.385 .00357 .00274 .00274 Be ppm .00119 .00003 2 .9028 .00115 .00l-21. .00L20 Pb/1, ppm - .00]-57 .00097 58.151 -.00]22 -.00279 - .00101 Se/z ppm .00037 .00188 s06 .99 -.00l-02 .00251- - .00037 Mo ppm .00209 .00727 57 . "71_4 .00312 .00240 .0001 6 LC Pass Li ppm .00l-52 .00028 1B . 202 .001-79 .00L52 .001,24 LC Pass Sr ppm - .00001 .00004 358.64 .00001 .00002 - .00005 LC Pass #r #z #3 - .05672 - .05781 -.06379 Errors LC Pass High .10s00 Low - .10500 EIem Cr Units ppm Avge - .00011 SDev .00055 ?RSD 489. 13 #r #z #: .00036 .00003 - .00073 Errors LC Pass High .00350 Low - .00360 EIem Mn Units ppm Avge . 00 032 SDev .00005 ?RSD 19.64L #r #z #: .00037 .00033 .00025 Errors LC Pass High .00180 Low .00180 EIem T1 Units ppm Avge .00155 SDev .00196 ?RSD A26. 13 #r #z #: Errors -.00024 .00365 .00L25 LC Pass - . 00012 H. 0 0973 .00011 H.01041 -.00041 H.00974 LC Pass NOCHECK NOCHECK LC Pass .04900 .04900 - .04900 -.04900 NOCHECK NOCHECK LC Pass LC Pass Appendix F - 374 369 Analysis Report High Low .01000 - .01000 .00500 - .00500 Sn ppm .00139 .00076 54.731, .001,75 .00191 .000s2 LC Pass .00770 -.00770 2 NOTUSED .00380 -.00380 Si ppm -.02253 . 0 0]-1,7 5.1'782 - . 0 21,63 - .02235 - .02392 .03100 - .03100 P_ ppm .00156 .00193 l-23.56 -.00029 .003ss .00L41, .00880 - .00880 Pb ppm .00073 .00042 s7 .3]-7 .00027 .00109 .00082 .00270 -.04270 Se ppm .00187 .00095 50.524 . 0 01,02 .00289 - 001,72 page 2 .00130 -.00130 03 /1,1, / 05 0 0 : 78 -.47 AM EIem Ti Units ppm Avge .00010 SDev .00030 ?RSD 3l-2 .20 #r #z #: 00019 00034 .'0 0 024 Errors LC Pass High .00150 Low - .00160 rntstd 1 Mode Counts EIem Y Wav1en 371. 03 0 Avge 24759 SDev 99.57778 ?RSD .411,9235 #r #z #: 2427 3 241,1,8 24081 LC Pass LC Pass .05500 .02100 - . Oss00 - .02100 34 NOTUSED NOTUSED LC Pass LC Pass .00370 .00430 -.00370 -.00430 567 NOTUSED NOTUSED NOTUSED Appendix F - 375 370 Analysis Report Method: TRA20505 Run Time: 03/71,/05 Comment : Mode: CONC Corr. El em A1 Unit s ppm Avge -.06073 SDev .00110 ?RSD 1.8776 #r #z #s 05953 05170 05095 Errors LC Pass High 700.00 Low - .20000 EIem Cr Units ppm Avge .00005 SDev .00029 ?RSD 4s4. 5s #r #z #: .00033 -.00024 .00011 Errors LC Pass High 100.00 Low - .01000 03/tt/oG o0:25:01 AM Operator: page 1 Cd Ca ppm ppm - .00004 .01150 .00006 .00051 158.61 4.4188 Sample Name: 00 :18 :51 Factor; 1 Sb ppm .00244 .001,77 70.104 .00437 . 0 0111 .00185 LC Pass 20.000 - .06000 Co ppm .00030 .00072 39.048 .00034 .000]-7 .00040 LC Pass 100.00 - .05000 K- ppm .09029 .00950 10.521 .08305 .08675 .10105 V_ ppm .00064 .00055 j.02. B 0 .00135 .00009 .00047 LC Pass As ppm .00090 . 0 015-7 1,7 4 .25 .00242 - . 0 0072 . 0 0101 LC Pass 30.000 - .01000 Cu ppm .00821 .00025 3.0L s .008s2 .00802 .0082"7 LC Pass 50.000 -.02s00 Ni ppm - .00020 .00010 49 - 563 -.00031 -.00014 - .00014 Zn ppm .00023 .000].2 51.3l-2 .00036 .00014 .00018 Ba ppm - .00013 .00004 27 . BB5 - .00009i .6oo1G - .0001s LC Pass 30.000 - .01000 Fe ppm .01574 .0027a t6 .7BB '. 01 897 .0135-7 .01588 Se/1 ppm .00080 .00099 123 .37 .000'76 - .00017 .00181 B- ppm .001-66 .00055 33.990 .00224 .00111 .00151 Be ppm .00tl.2 .00005 5.4438 .00105 .00L1,7 .00115 Pb/1 ppm -.00331 . 0 0110 33.246 00319 00446 0 022'7 Se/2 ppm - .00051 .00066 129 .40 -.00001 -.00725 -.00026 Mo ppm . 0 01,25 .00025 19. 925 .00L46 .00131 .00091 LC Pass .00000 - .00001 -.00011 Pb/2 ppm .00L4a .00155 111.1s .00022 .00318 .00082 Ag ppm .00041 .00075 184 .71, - .00019 .00016 .00l.24 Li ppm .00086 .000l_2 74.113 .00100 .00082 .00077 LC Pass 01208 0113 2 01111 Mg ppm .00268 .00091 33 ,819 .00373 .002L5 . 00 277 Na ppm - .14733 .1,27 03 86.222 -.02].60 - .27 561, -.14476 Sr ppm .00000 .00001 175.74 .00001 - .00000 .00000 LC Pass LC Pass LC Pass LC Pass 10.000 40.000 600.00 -.00500 -.00s00 -s.0000 LC Pass NOCHECK 14 0 0 . 0 - .10000 NOCHECK LC Pass 700.00 -5.0000 Elem Units Avge SDev ?RSD #r #z #g Mn ppm .00029 .00005 1s . 258 .00031 .00024 .00033 Errors LC Pass High 30.000 Low - .01500 Elem T1 Units ppm Avge . 0 0141, SDev .00135 %RSD 95. 464 #l- #z #: Errors .00155 .00262 - .00004 LC Pass LC Pass LC Pass 200.00 100.00 -5.0000 - .04000 NOCHECK NOCHECK LC Pass LC Pass 4.0000 800.00 - .02000 -5.0000 LC Pass LC Pass Appendix F - 376 37 I Analysis Report High Low 'l 0.000 - .02000 100.00 - .02500 Sn ppm .00084 .00085 101 .-75 .00099 -.00008 . 0 0151 10.000 - .02000 Si ppm - .02l-23 .00138 6.5061 01970 0223 9 021_5 0 40.000 - .04000 Pb ppm .00031 .00081 256.22 5.0000 - .05000 Se ppm .00023 .00072 3]-4. 1 1 page 2 10.000 - .0s000 03/1a/oa oo:25:01 AIvl Elem Ti Units ppm Avge . 00 020 SDev .00011 ?RSD 52 .67 6 #r #z #: .00029 .00008 .00024 Errors LC Pass High 40.000 Low - .05000 fntstd 1' Mode Counts EIem Y Wavlen 371.030 Avge 24L75 SDev 104 .5555 ?RSD .4324921, #r #z #: 24a31 2429 4 24tOO LC Pass LC Pass 40.000 40.000 - .10000 -1.0000 2 NOTUSED 34 NOTUSED NOTUSED - .00050 .000s8 .00113 - .00050 . 00 029 00072 LC Pass LC Pass 70.000 30.000 -.00400 - .01000 557 NOTUSED NOTUSED NOTUSED 40.000 - .50000 P- ppm .00t23 .00078 53 . 84 0 .00035 .00449 .00184 LC Pass 40.000 -.30000 Appendix F 377 372 Analysis Report Method: TRA20505 Run Time: 03/Il/AG Comment : Mode: CONC Corr. EIem AI Units ppm Avge -.05973 SDev .00185 ?RSD 3 .1041 #r #z #s 05014 05774 0613s Errors LC Pass High 700.00 Low - .20000 Elem Cr Units ppm Avge . 00 032 SDev .00088 %RSD 273. 80 #r #z #g .00133 - .00004 - .00032 Errors LC Pass High 100.00 Low . 0100 0 EIem Mn Units ppm Avge .00027 SDev .00010 %RSD 31 .877 #r #z #: 00038 0002s 00018 Errors LC Pass High 30.000 Low - .01500 Elem TI Units ppm Avge - .00088 SDev .00083 ?RSD 95. 092 #1 #z #g Errors - .00105 - .00161 .00003 LC Pass 03/\\/06 oo:31:15 AM Operat.or: page 1 Cd Ca ppm ppm - .00009 .01133 .00010 .00049 111 .97 4.2868 Sample Name: 00 :25 :05 FacLor: 1 Sb ppm .00118 .00158 742 .45 - .00075 .00794 .00234 LC Pass 20.000 - .06000 Co ppm .00001 .00040 3485.0 - .00032 .00045 - .00010 LC Pass 100.00 - .0s000 K- ppm . L41,gg .04048 2B. s11 .11234 .12552 .18811 LC Pass 200.00 -s.0000 V- ppm - .00014 .000s5 407.58 - .00078 .00024 .000].2 LC Pass LC Pass LC Pass 30.000 30.000 - .01000 - .01000 As ppm .00083 .00067 B0.3Bs .00119 .00!23 .00005 Cu ppm .00801 .00030 3 .7 046 .00768 .00813 .00824 LC Pass 50.000 - .02500 Ni ppm - .00030 .00050 169 .04 .00028 - .000s9 - .00058 Zn ppm .00021 .00007 25.364 .00020 .00034 .00028 Ba ppm -.00022 .00006 27.041 -.00029 - .00019 - .00018 Fe ppm .004l.4 .00908 2t9 .46 - .00s30 .00489 . 01281, Se/1 ppm .003s7 .00380 10 6 .37 .00-797 .00087 .00193 B_ ppm .00155 .00081 52 .3 81 .00222 .00180 .00065 Be ppm . 0 0115 .00022 1B . 892 .00093 . 0 01,20 .00136 LC Pass 10.000 - .00500 Pb/t ppm - .00115 .00622 s39.35 .00573 - .0028a - .00638 Se/2 ppm - .00071 .00165 233 .49 - .00134 - .00195 . 0 01,I7 Mo ppm .00071 .00a66 e2 .1s o - .00002 .00091 . 0 01,25 LC Pass .00002 - .00012 - .00017 Pb/2 ppm .00119 .00230 L94.32 Ag ppm .004]-9 .00282 6-l .145 .00207 .003l.2 .00739 Li ppm .00064 .00009 13.976 .00074 .00062 .00056 LC Pass 01084 01181 01133 Mg ppm .00070 .003s3 s05.66 Na ppm - .17058 . 1,62 03 94 .986 - .001s5 - .18564 -.32456 Sr ppm - .00002 .00002 108.51 - .00004 - .00001 - .00001 LC Pass LC Pass LC Pass 40.000 600.00 -.00500 -5.0000 LC Pass NOCHECK 1400.0 - .10000 - .00138 - .00314 .0018s .00382 .00308 .00L4]- NOCHECK LC Pass 700.00 -5.0000 LC PaSs NOCHECK NOCHECK 100.00 -.04000 LC Pass LC Pass 4.0000 800.00 - .02000 -5.0000 LC Pass LC Pass Appendix F - 378 373 Analysis Report 100.00 - .02500 Sn ppm .00080 .00108 134 .73 .00155 .00115 - .00041 2 NOTUSED 10.000 - .02000 Si ppm - . 02323 .00180 7.7483 - .02324 - .02l-43 - .02503 40.000 - . s0000 P_ ppm .0061,2 .00224 36.520 .00s30 .00442 .00855 40.000 -.04000 00150 00081 00045 s.0000 - .0s000 .00204 - . 0 0072 .00773 page 2 10.000 - .0s000 03/a7/06 00:31:15 AM EIem Ti Uni t.s ppm Avge .00006 SDev .00009 ?RSD 1,54. 01 High Low #r #z #g Errors High Low #r #z #: 70.000 -.02000 .00004 00012 00010 23666 23643 22992 Pb Se ppm ppm .00092 .00101 .00053 .00151 57.685 148 .70 LC Pass LC Pass 40.000 40.000 - .05000 - .10000 LC Pass LC Pass 40.000 40 .000 -1.0000 - .30000 34 NOTUSED NOTUSED LC Pass LC Pass 70 .000 30.000 - .00400 - .01000 5 NOTUSED 67 NOTUSED NOTUSED Intstd 1 Mode Counts EIem Y Wavlen 371,.030 Avge 23433 SDev 382.6513 ?RSD 1.532925 Appendix F 379 o o o TOCDF APPENDIX F SECTION 3.5.2 ICP Quality Control Data MPF SWDT REPORT - Rev. 0 Appendix F June 9,2006 F-3 80 STL Knoxville ICP Data Reporting Forrn Appendix F - 381 Units: uglL (ppb) Instrument ID: TJA 6l-E SuperTrace ICP Data File Name: t03 1006.arc 100 O Initial Calibration Verification Elem True Conc ICV l0-Mar-06 l1:55 AM % Found Rec % Found Rec Found % Rec % Found Rec % Found Rec % Found Rec Ag AI As B Ba Be Cd Co Cr Cu Ivln Ni Pb Sb Se Sn T1 V Zn 500.0 12500.0 2s0.0 1000.0 1000.0 1000.0 250.0 1000.0 1 000.0 1 000.0 1 000.0 1000.0 250.0 250.0 250.0 : 1000.0 500.0 1000,0 1000.0 '500. ll 100.0 12514.77 100. I 256.27 102.5 I004.34 100.4 l0l 5.5 I 101.6 1033.02 103.3 259.94 103.6 1009.58 101.0 1 003.76 100.4 1009.01 100.9 I 01 9.69 102.0 rc24.96 102.5 253 .57 I 01.4 748.05 gg.2 254.91 102.0 996.5t gg.7 506.37 101.3 1008.67 100.9 I 065.45 106.5 ICP Report Generator Version 4.2 Form 2A Equivalent O Continuing Calibration Verilication STL Knoxville ICP Data Reporting Forrn Appendix F - 382 101 Units: u/L (ppb) Instrurnent ID: TJA 6l -E SuperTrace ICP Data File Name: t03 l006.arc Elem True Conc CCVI lO-Mar-06 12:37 PM CCV2 l0-Mar-06 l:48 PM CCV3 l0-Mar-06 3:03 PM CCV4 l0-Mar-06 4:53 PM CCV5 l0-Mar-O6 6:37 PM CCV6 l0-Mar-06 7:51 PM % Found Rec % Found Rec % Found Rec Found #,% Found Rec % Found Rec Ag AI As B Ba Be Cd Co Cr Cu Mn Ni Pb Sb Se Sn TI v Zn 1000.0 25000.0 500.0 2000.0 2000.0 2000.0 500.0 2000.0 2000.0 2000.0 2000.0 2000,0 s00.0 500,0 500.0 2000,0 1 000.0 2000,0 2000.0 994.54 99.51 24694.38 98.81 50 I .03 100.21 1e86 00 eesl 1s86.32 ee.3l 2o7l .08 103.61 I 5t 5 .57 103. I I 2033.78 1ot.7l 2028.80 101.41 I 958. 17 97 ,g 2035.83 101.8 2051 .05 102,6 512.67 102,5 497.60 99.5 500.38 100.1 2037.42 101,9 1007.01 100.7 2013.37 100.7 2079.t2 103.9 . 999,77 t 00.01 I24965.95 gg,gl l 501 .69 100.3, 2003.09 100.2 2009,73 100.5 2059.33 103.0 512.07 t02.4 2A29.06 101.5 2022.23 101.1 1980.40 99.0 2036.60 101.8 2041 .06 102.1 507.24 101.4 497.84 99.6 499.15 99.8 2028.56 101.4 1003.16 100.3 2011.91 100.6 2074.75 103.7 r 003.62 t 00.41 24734.47 gg.gl 5as.27 101.11 2}o2.3s loo.ll 2018. I 8 100.91 2A72.20 103.61 stz.zi r oz.4l l 2039.8 1 102.0 2036.65 101.8 1978.80 9g.g 2046.70 102.3 2055.04 102.8 5 13.43 102J 501 .63 100.3 507 .59 l0l .5 2043.61 1A2.2 1017.38 r0r.7 2021 .95 101.1 2084.69 104,2 978.27 97.8 24 1 83 .3 8 96,7 498,17 99 19s1.89 97 1968.78 98 2026.sA r01.31 s00.79 100.21 tgg2.7g 99.6! r 1 984.0 I 99.2 1926.37 96.3 tgg7.47 gg.9 2048.24 100.4 5A4.07 100.8 498.62 gg.7 500.25 100,1 1996.95 99.8 997 .7 4 99.8 1973.56 gg.7 2033.10 101,7 882.77 22161.18 454.5s 1751 . l5 1776.46 1842.s3 454.88 1818.13 t790.07 1758.36 1803.19 1822.06 454.17 451.r4 450.7 I I 8 14.99 908.97 17 86.7 6 1856.60 gg.3l 88.61 eo.el 87.61 88.81 e2.1 1 e1.01 e0.el se.sl I 87.e1 90.2 91.1 90.8 90.2 90.1 90,1 90.9 99.3 92.9 g7g.t7 g7.gl 22t7 | .32 88.71 4st.s2 e0.41 17os.r2 8s.31 17 82.63 8e. 1l 1832.6s e1.61 447 .1s 8e.41 I 80s.73 90.31 I t777 .81 gg.g t7 62.95 gg.l l7g5.g7 gg.3 l80t.42 90.1 451 .7 4 90.3 455.17 91.0 445 .41 gg,1 l g0l.g5 g0.l 912.66 gl.3 1787.61 89.4 1848.4 I 92.4 ICP Report Generator Version 4.2 Form 2A Equivalent O Continuing Calibration Verification STL Knoxville ICP DataReporting Form Appendix F 383 102 Units: ag/L bpb) Instrument ID: TJA 61-E SuperTrace ICP Data File Name: t03 1006.arc Elem True Conc CCVT l0-Mar-06 9:06 PM CCVS l0-Mar-06 l0:20 PM CCV9 l0-Mar-06 1 1:35 PM CCVlO I l -Mar-06 12:06 AM o/o Found Rec % Found Rec % Found Rec % Found Rec % Found Rec % Found Rec Ag AI As B Ba Be Cd Co Cr Cu Mn Ni Pb Sb Se Sn TI V Zn 1000.0 25000.0 500.0 2000,0 2000.0 2000,0 500.0 2000.0 2000,0 2000.0 2000.0 2000.0 s00.0 s00,0 500 ,0 2000,0 1000.0 2000.0 2000.0 ggg. 12 gg.gl 22s60.s4 e0.21 4s3.08 eo.6l 1700.40 8s.01 1797.t5 89.91 1852 3 1 e2.61 450.21 90.01 1832.67 91.6, 1792.72 gg.6i I788.75 89.4 I g0l .33 90.1 1819.86 91.0 457.92 91.6 45 6.80 gl,4 450.60 g0.l I 8 19.68 91.0 926.65 92.7 1806.83 90.3 1869.98 93.5 gg7.5g gg.gl 22e34.3t el,71 4s8.00 el.61 1699.46 95.01 tgl2.67 90.61 I 87s.3 I e3.81 452.g2 90.61 I1853.42 92.7t tgol.67 90.41 1813.53 90.71 lgtg.60 91.0 1835.32 91.8 461.48 92.3 465,91 93.2 449.65 gg.g I 838.03 91.9 933.13 g3.3 1828.78 91.4 1987.04 94,4 894,49 22858.88 456.90 1682.20 1813.90 18'12,15 452.91 I 855.66 l8l0.l7 1808.42 l8l8.5l 1831.t3 460.94 462,9s 45r.35 1828.95 932,97 t826,47 I 883.84 gg.4l e l.4l e l.4l s4.1 | 90.71 I 93.61 90.6 92.9 90.5 90.4 90.9 91,6 92.2 92.6 90.3 91.4 93.3 91.3 94.2 901.36 90,11 22s4s.2s el.81 4ss.78 e2.ol 16s2.32 s4.61 1809.63 90.51 1897 .7 4 !D4.gl 460.95 92,21 I 885.8 1 94.3t I 83 6.8e e l .81 1800. l5 90.0 1845.48 g2.3 t 859.68 93.0 466.8 8 93.4 466.56 93.3 452.90 90.6 I860.t6 93.0 936.98 93.7 1847.25 92.4 1903.90 95,2 Form 2A EquivalentICP Report Generator Version 4.2 - :. STL Knoxville ICP Data Reporting Form Appendix F - 384 Units: ug/L (ppb) Instrurnent ID: TJA 61-E SuperTrace ICP Data File Name: t03 1006.arc 103 O Reportirg Lirnit Standard(s) EIem True Conc CRDLI O l0-Mar-06 12:19 PM % Found Rec % Found Rec % Found Rec Found #.% Found Rec % Found Rec Ag AI As Be Pb Se TI Zn 30.0 400.0 20.0 10.0 15.0 1 s.0 3 5.0 60.0 21.48 71.6 412.59 103.1 20.16 100.9 10.69 106.9 t5.45 103.0 15.69 104.6 35.58 101.7 66.72 lll.2 ICP Reporl Generator Version 4.2 Form 28 Equivalent Reporting Limit Standard(s) STL Knoxville ICP Data Reporting Form Appendix F - 385 104 Units: ug/L (ppb) Instrument ID: TJA 61-E SuperTrace ICP Data File Name: t03 1006.ars o Elem True Conc CDRL2O 10-Mar-06 12:25 PM % Found Rec % Found Rec % Found Rec % Found Rec % Found Rec % Found Rec Ba Cd Co Cr Cu Mn Ni Sb Sn 10.0 5.0 s0.0 r 5.0 25.0 I 5.0 40.0 60.0 r 00.0 9.91 gg.l 5.1 I 102.2 5 I .55 103.1 15.32 102.1 24.44 97.g I 5.54 103.6 40.47 101.2 64.09 106.9 101.61 101.6 ICP Report Generator Version 4,2 Form 28 Equivalent O Reporting Limit Standard(s) ICP Report Generator Version 4.2 STL Knoxville ICP Data Reporting Form Appendix F - 386 105 Units: ugll (ppb) Instrument ID: TJA 6l-E SuperTrace ICP Data File Name: t03 l006.arc Elem True Conc CRDL4O l0-Mar-06 12:31 PM oh Found Rec % Found Rec % Found Rec % Found Rec Found % Rec % Found Rec V 25.0 25 ,41 101.6 Form 28 Equivalent O Initial Calibration Blank(s) STLKnoxvitte 106 ICP Data Reporting Form Units: ug/L (ppb) Instrument ID: TJA 61-E SuperTrace ICP Data File Name: t03 l006.arc B - AnalyAppmdiUOrfirterween IDL and Reporting Limit U - fuialyte concS&fiion is less than IDI- Elern Acceptance Limit ICB 10-Mar-06 12:01 PM Found Flag Found Flag Found Flag Found FIag Found Flag Found FIag Ag AI As B Ba Be Cd Co Cr Cu Mn Ni Pb Sb Se Sn TI V Zn 9.7 105.0 3.3 3 1.0 1.6 1.8 0.8 2.2 3.6 7.0 1.8 3.8 3.1 14.0 ,.14-J 7.1 1 0.0 5.0 3.8 2.7 B 6.8 U 1.2 U 3,2 U 0.t u 0.2 B 0.2 u 0.6 u 1.0 u -0.3 B 0.2 B 0.7 u 0.8 rJ 2.3 U t -i TfI.J U 2.4 I"J 2.7 U t.2 u 0.2 u ICP Report Generator Version 4.2 Form j Equivalent STL Knoxville ICP Data Reporting Form !07 Continuing Calibration Blank(s)Units: ugL (ppb) Instrument ID: TJA 6l-E SuperTrace ICP Data File Narne: t03 l006.iuc B - AndyAppedildimrH*.rween IDL and Reporting Limit U - Analyte concffi&io, is lcss than IDL Elem Acceptance Limit CCB I l0-Mar-06 12:43 PM CCB2 lO-Mar-06 l:54 PM CCB3 10-Mar-06 3:09 PM CCB4 I0-Mar-06 5:29 PM CCB5 10-Mar-06 6:43 PM CCB6 10-Mar-06 7:57 PM Found Flag Found Flag Found Flag Found Flag Found Flag Found FIag Ag AI As B Ba Be Cd Co Cr Cu Mn Ni Pb Sb Se Sn TI V Zn 9.7 105.0 3.3 3 r.0 1.6 1.8 0.8 2,2 3,6 7.0 1.8 3,8 3.7 14.0 4,3 7.7 10,0 5.0 3,8 3.I B 6.8 U 1.2 u 3.2 U 0.1 u 0.2 u 0.2 u 0.6 u 1.0 u 0.3 u 0.1 u 0.7 u 0.8 u 2,3 IJ i.5 B 2.4 U 2,7 IJ 1,2 u 0,2 u 3.3 B 6,9 u t,2 u 3,2 IJ 0,1 u 0,2 B 0.2 0.6 u 1.0 u -0.3 B 0.1 u -0,9 B 0.8 u 2,3 U 1.3 U 2.4 U 2.7 U 1.2 u 0.2 u 4.4 B 6.8 U 1.2 u 3.2 U 0.1 u 0.3 B -0.3 B 0.6 u 1.0 u 0.6 B 0.1 u -1.4 B 0.8 u 2.3 U r.4 B 2.4 U 2.7 U t.2 u 0.2 u 1.3. U -29,3 B 1.2 u 3.2 U -4.2 B 1.7 B 0.2 u 0.6 u 1.0 u 7,7 1.0 B 0.7 u 0.8 u 2.3 U 1.3 U 2.4 U 2.7 IJ 1.2 U 0.2 u -2.0 B -32.0 B 1.2 U 4,2 B -4.2 B 1.3 B 0.2 u 0.6 u r.0 u 9.3 0.5 B 0.7 u 0.8 u 2.3 U 7,4 B 2.4 U ?.7 rl 1.2 u 0.5 B -2.9 B -47.6 B 1.3 B 3,2 U -4.2 B 1.3 B 0,2 u 0.6 u 1.0 u 9.2 0,3 B 0.7 u 0.8 u 2.3 U 1.3 U 2.4 U 2.9 B 1.2 u 0.2 u ICP Report Generator Version 4.2 Form j Equivalent O Continuing Calibration Blank(s) STL Knoxville 108 ICP Data Reporting Form Units: ugll (ppb) Instrument ID: TJA 6l-E SuperTrace ICP Data File Name: t03 1006.arc B - AnalyAppffiildiUo,Fir{erween IDL and Reporting Limit U - Analyte concffiflio, is less than IDL EIem Acceptance Limit CCBT l0-Mar-06 9:12 PM CCBS l0-Mar-06 10:26 PM CCB9 l0-Mar-06 I l:41 PM CCBIO I l -Mar-06 12:12 AM Found Flag Found Flag Found Flag Found Flag Found Flag Found Flag Ag AI As B Ba Be Cd Co Cr Cu Mn Ni Pb Sb Se Sn T1 V Zn 9.7 r 05.0 3.3 31.0 1.6 1.8 0.8 2.2 3.6 7.0 1.8 3.8 3.7 14.0 4.3 1.7 10.0 5.0 3,8 -2.2 B -49.3 B r.2 u 3.2 U -0.2 B 1.0 B 0.2 u 0.6 u 1.0 u 9.2 0.4 B 0.7 u 0.8 u -3.0 B 1.3 U 2.4 U 2,7 U 1.2 u 0,2 u -l .7 B -54.7 B t.2 u 3.2 U -0,1 B r.0 B 0.2 u 0.6. u 1.0 u r 1.l 0.4 B 0,7 u 0.8 u 2,3 U 1.3 u 2.4 U 2,7 U t,2 u 0.3 B 1,3 U -6T,4 B r.2 u 3,? U -0,2 B 1.2 B 0.2 u 0.6 u 1.0 u 8.1 0.3 B 0.t u 0.8 u 2.3 U r.3 u 2.4 U 2.7 U t.2 u 0.2 u 1.3 . U -59.4 B 1.2 U 3.2 U -0.r B 1.2 B 0.2 u 0.6 u 1.0 u 10.0 0.3 B 0.7 u 0.8 u 2.3 U 1.9 B 2.4 U 2,7 U 1.2 U 0.2 u ICP Report Generator Version 4.2 Form j Equivalent STL Knoxville ICP Data Reporting Form Units: ugll (ppb) Instrument ID: TJA 61-E SuperTrace ICP Data File Name: t03 1006.arc 109 O Interference Check Standard A Appendix F - 390 Elem True Conc Reporting Lirnit ICSAl l0-Mar-06 12:07 PM Found Found Found Found Found Ag AI As B Ba Be Ca Cd Co Cr Cu Fe Mg Mn Ni Pb Sb Se Sn TI V Zn 500000 500000 200000 500000 30 ZO 200 10 l0 5 50 15 25 l5 40 15 60 15 r00 35 25 60 .0 473458 I 3 l3 0 431696 -2 0 5 I 194047 s23187 -l 0 0 0 2 ^J 3 8 2 ICP Repoft Generator Version 4.2 Form 4 Equivalent O Interference Check Standard AB STL Knoxville 110 ICP Data Reporting Form Units: ug/L (ppb) lnstrument ID: TJA 61-E SuperTrace ICP Data File Name: t03 1006.arc Appendix F - 391 Elem True Conc ICSABI l0-Mar-06 12:13 PM % Found Rec o/o Found Rec % Found Rec % Found Rec % Found Rec % Found Rec Ag AI As B Ba Be Ca Cd Co Cr Cu Fe Mg lvln Ni Pb Sb Se Sn TI V Zn 200 250000 100 r 000 500 s00 250000 1 000 500 500 500 I 00000 250000 500 l 000 50 600 50 I 000 100 500 _,,1'_ 209.3 104.1 242724.1 97.t 104.2 t04.2 1034.5 103.5 522.3 104.5 5 I 5.3 103. I 232145:7 g2.g 996.7 gg.7 492.3 gg.5 499.6 gg.'7 5 lg.3 103.9 gg 120.5 gg.l 255944.9 102.3 506.2 t0l.z g7g.g gg.0 50.3 I 00.6 649.2 r 08.2 55.3 I I0.7 992.2 gg.2 90. I g0.l 499.5 gg.g l06g.g 106.9 ICP Report Generator Version 4.2 Form 4 Eqttivalent O Serial Dilution(s) STL Knoxville ICP Data Reporting Forrn B - Analyte concentration is between IDL and Reporting Limit U - AnalyepeomdilroF'isress than IDL E - Percent Diffe&S3 ir greater than l0 and [OSl>50 times IDL Units: ugll (ppb) Instrument ID: TJA 61-E SuperTrace ICP Data File Name: t03 1006.arc 111 Element HXOIX HXOlXP Percent Difference Ag AI As B Be Cd Co Cr Cu Mn Ni Pb Sb Se Sn TI V Zn 19.34 22307.25 1.65 B r 1 1.84 0.23 U 1 897.3 5 r1.63 10.88 36.26 26,99 s0.ls 87.52 2.30 U 1.35 B 870.74 2.70U 12.55 54s1.39 37.65 B 2t942.30 6.00 u 1q7.9s B 1.15 U r 982.00 2.85 U 14.15 B 3 5.45 27.90 5r.05 94.5s I l.s0 u 6.s0 u 89s.55 13.50 u 9.85 B 5909.70 94.7 1.6 100.0 3.5 4.5 100.0 30. I 2.? 3.4 1.8 8.0 100.0 2,8 21 .5 8.4 ICP Report Generator Version 4.2 Form 9 Equivalent O Serial Dilution(s) STL Knoxville ICP DataReporting Form \ Units: ugll (ppb) 7l.2 lnstrument ID: TJA 61-E SuperTrace ICP Data FiIe Name: t031006.arc B - Analyte concentration is betrveen IDL and Reporting Limit u - AnalyA,ppmdifrfis{ess than IDL E - Percent DiffeS&3 is greater than l0 and [OS]>50 times IDL Element HXOlX.zS HXOIXPItb Percent Difference Ba 84A2.A2 763r.75 9,2 O ICP Repoft Generator version 4.2 Form 9 Equivalent STL Knoxville ICP Data Reporting Form Instrument Detection Limits Units: ugll (ppb) IDL Completion Date: 13-Jan-06 Instrument ID: TJA 6l-E SuperTrace ICp Data File Name: t031006.arc Element Wavelength (nrn)IDL Ag AI As B Ba Be Cd Co Cr Cu Mn Ni Pb Sb Se Sn TI V Zn 328.A7 3 08.2 I r 89.04 249.68 493.41 3l3.A4 226.50 228.62 267 .7 t 324.7 5 257.61 231_60 220.3s 206.84 196.03 189.99 1 90.86 292.40 213.86 1.3 6.8 1.2 3.2 0.084 0.23 0.23 0.57 1.0 0.26 0.r4 a.7 t 0.79 2.3 1.3 2.4 2.7 1.2 0.23 Appendix F - 394 113 ICP Repon Generator Version 4.2 Form I0 Equivalent lt4 STL Knoxville ICP Data Reporting Formo Inter-El ement Correction Factors lnstrument: Interfering Element TJA 61-E SuperTrace ICP Date of IEC's: Correction Factor(s) s1312005 Aluminum v(0.02ss2s) Antimony Cr(-O.0 1 1 889), Fe(0.000042), Ti( -0.0022) Arsenic Cr(-0.002088), Fe(-0.000006), Mo(-0.00 1 69) Beryllium v(-0.0083 e4) Cadmium Fe(0.00003 7) Chromium Fe(-O.0000 1 8) Cobalt Ti(0.001 8l ) Iron Co(0.0530 I ), V(0.00493 8) Lead AI(0.000433), Co(O.0003 67), Cr(-0.0003 02), Fe(0.000073) Lead Al(-0.00141), Fe(O.000048), Mn(0.000215), Mo(-0.001129), Ni(0.000288), Ti(-0.00061) Nickel Co(O .0021 66) Phosphorus Ar(0.00017) Selenium Co(-0. 000705 ), Fe(-0, 000294), Mn(0.00044) Selenium Co(0. 0003 73), Fe(-O. 000029), Mn(O.0003 5 8) Silicon Al(0 .00022) Silver Ca(O.0000 I 6), Fe(0.000007) Strontium Ca(O.00003 7) Thallium Co(O .002379), Mn(O.001 142), Ti(-0.01067), V(-0 ,027 889) Vanadium Fe(-0.00009), Mg(-0.00 1 3 s) Zinc Cu(O.0007 82), Fe(0.000069), Ni(O.0029 1 1 ) Appendix F - 39sICP Report Generator Version 4.2 I I Equivalent STL Knoxville ICP Data Reporting Form Appendix F - 396 Units: ug[L (ppb) Instrument ID: TJA 61-E SuperTrace ICP Data File Name: t03 1006 ,arc 115 O Linear Dynamic Ranges LDR I)ate:l}-Jan-06 Element Linear Dynamic Range Ag AI As B Ba Be Cd Co Cr Cu Mn Ni Pb Sb Se Sn T1 V Zn 4000.0 700000.0 30000.0 40000.0 30000.0 10000.0 40000.0 100000.0 100000.0 50000.0 30000.0 100000.0 70000.0 20000.0 3 0000.0 40000.0 70000.0 100000.0 10000.0 ICP Report Generator Version 4.2 Form 12 Equivalent J F 116 STL Knoxville Sample ID Nomenclature The laboratory sample ID consists of 5 alpha-numeric characters followed by a suffix in the 6th position that designates the sample type: Suffix Sample Type B C L S D x P A Z# Method Blank Laboratory Control Sample Laboratory Control Sample Duplicate Matrix Spike Matrix Spike Duplicate Sample Duplicate Serial Dilution Post Digestion Spike Dilution; # - Dilution Factor Appendix F 397 ICP Report Generator Version 4.2 APPENDIX F SECTION 3.5.3 ICP Sample Preparation Data MPF SWDT REPORT - Rev 0 Appendix F June 9,2006 TOCDF F-398 38 5 r/ ^ iOooOdoq\f ,d,c\oFrr az N.a) Ta.sBL\atr - AJ - \BL. aB\]rr \ t- il\s'N>4 . ooEE '. 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E 7- l Fr T- (\ l -o -o f+ - $- ED \l\\\ \e$tnU+i EEo\\Lc)B.goi,s(e \\la0+- ahoEL--l-EoU oZtA(u \ \ \ \ \ \ z \ \ \ \ \ a. l -. t.aE\AJ- .h l \a a, la\i BHL ;h .\\a5-q) 'E tq) F(U q)(t r - FC ) (g r\ E( s L{ (t ) E. -gg .t ) \J 3 q- { oo ,g +- , .1 , F -o .E C, EEe tr a oJ r) HZ o-oG , E' q- c/ ) o thhoH< , t F0 ) =( ) ,X < t Et O .. Ct oq ) tr 'l t- E. ; cr :' i l- \r Z <5 c\ .g) a .i H, ss E- tr ( l , (T t ,s tr < ) cr e €E rl < ii o- (X OE+ 6E - (D - (l ) C d (a o ) H* 0. r : oL ' (s H (l ) eEE o. o c) = t- -| a. cg Q. ot cB g (t ; +- ) €a a. - '^ & (n .= LCB 6) b€ - l- |r cs t r l- ho ) rr 5 N c. .o.z(UF(got- i .o-oooJP0)ax0. )o)cd0. )G, trCLoL{o.O. cl (t ) v)c,Ba(J(l )?o. OFaA. l-ohc- - ) aL(, ) tr tr l r. l . ro!- azA" l< ,P 't , (l ) 15aoLop. 0) t- J4o()UoJ!<0)gr&Gl (n(d&p p e + .9 c. , HU IN IeHzE* Px O. rd 0. c (\ , cl 9r ) AN I .E o Eu ! -d:sEO €E 't : l t- . Ex or Y HExo ts ? 8€ 9F 'E o c! -C L '* j L(B t r EO o' t , -q q) fr i E w3 b(s)- . )r a?.LrU)cf ) r/ )xCT , 0. ) c. . (J +,(t ) X (n L- E c( l UE ts t r a) = .h aA* . , 609) J Lr ,9 9 1+ . Ut '6 = c) J 6( )a' 9 a 00 ) h. . (1 .E i I O. - -O > '= 'c U Er # -A a - () = o -k ( s -( J s€ E f €. 8 \o Loao) l{o.o()B0. ) cBL{ l-cO l- .Eo-ot) (J il ,cG c\ .vt c. )O. }{CUU) 63 f{€(l ) cA(l )L{o. <n (r )0)L.q) Lf . roCOO.Uo) a, )C)>O -(6 gHacH} (\ , 9t J a- , F< F ,A l n( J b ' EE : E. g E vG l O . o <M 'Q dc) c 1 x il a' E 6' - J - o El < - -O. = cd E aa I R; t ^ cl l -U 8r E l€ r t V E k- +g E Gt On E3 ; e, C o ;, e- & 4E s U8 E H -a L 9 H€ =6 ' ) L98 f l <€ e j .! p l-oq. ) ()L{ [t - I .I .. S Nc- iNt. J :c L-o)ctroCJ ' F' troED(l )u0 (BJ(() (\ l O.oooEa. )uoGI )4o(oO. $(l ) (, )JtsoUL ,o o. (l )d.E +t () .Ah{aIoJ q)O.Fir . L.otrq)& *.U) .- l-v !t (Jo- rr rUc) .! l:)sl trl.6lZBq) .! a qJ&(! {r aAF ( Fl qr . ( og -I A t- ( ,Y Gq ) ti bO OG I .= R. -l q)a-l c! -,hr .t s fr (u) II 6l t,0) ll l ra,q) --ol aXo-akv, FI l- ]t' .a 390 STL Knoxville Data Quality Checks Internal Standard Date Tirne Lab ID Problem ; 'r.0-ril;:i,e"""s;i'iM HonFos n.'p"#;;i4,iti;'tiil.-8r;R;;;;6)l"tdL:'i3,1e?'ti6I-:'t8;iel)"' l0-Mar-06 5:47 PM H0HP6D Response was 28,600 (130.0% Recovery)! LCL: 15,397 UCL:28,595) k I3-Mar-06 2:13 PM Relative Standard Deviation There were 106 resulls successfullyverified. Date Tirne Lab ID Problern +J+! nat ?r*i,^'^t + I3-lrIar-06 2: I3 PM There were 209 results successfully verified. this lrt' /{n 3-15-oG Appendix F - 404 ICP Report Generator Version 4.2 RQC0s7 Severn Trent Laboratorl-es , Inc. METALS PREP LAG/BATCH SUMMARY Run Date: 3/14/AG Time: 5:34 15 B:00 COMP DATE; 3/OA/OA INITIALS : TN,P - GFA/t,tE IGHT 391 17:00 FLA/ r{ErGr-: LOT WORK NUMBER ORDER BATCH NUIVIBER : 506 5258 PREP DATE: 3/08/06 DUE DATE 3/L3/05 HGlWEIGHT H58200l.64 SOLID H5B2 0 0 \64 SOLID H6B2 0 0 L64 SOLTD H6B2 0 0164 SOLTD H5B 20 0!64 SOLID H68200L64 SOLID i{5c070000 SOLID HXQIX TO DUE HXQlXS HXQTXD HXQ2H TO DUE HXQ2M TO DUE HXQ2V TO DUE HXQz 4 TO DUE HXQ3D TO DUE HOQTEB DUE HO QTEC QC 01 DATE: 01 DATE: 01 DATE: 01 DATE: 01 DATE: 01 DATE: 01 DATE: ICP/-WEIGHT 5'99Li-fu'& 3/L3/oe g g I LEVEL 2 BLAI{K AND CHECK STA}'IDARD ON BATCH MS / MSD A}'ID PDS ON BATCH CURVE PREPPED FOR HG CORRECT SPTKES ADDED SPIKING SOLUTTONS DOCUMENTED ON BATCH LOG COMMENTS : B-BLANK/C-LCS/D-MSD/I-REANALYSIS/L-LCSD/P-SERIAL DLTN/S.MS/X_SAMP DUP/Y-SAIVIP CONF/Z.PDS SPTKING WTTNESSED BY Appendix F - 405 x Severn Trent Laboratori€s, fnc - METALS PREP LOG/narCH SUMMARY Run Date: 3/07/OA Time: 11:52:54 PREP DATE: 3/OA/06 B:00 COMP DATE: 3/08/Oe 17:00 DUE DATE 3/73/05 rNrrrALS , lwD 392 F.Qo c057 BATCH MJMBER: 5056258 ICP ELEMENTS WITHIN THE BATCH: AG AL AS BA BE BX CD CO CR CU MN NI PB SB SE SN TL VX ZN r4s/MsD 1: rcP - 1 rcP - 2 GFAA HG oDD MS,/MSD 2, ICP - 1 TCP.- 2 GFAA HG oDD MS,/MSD 3: ICP - 1 fCP - 2 GFAA Hc ODD CHECK: ICP-1 ICP-2 GFAA HG ODD CHECK DUP: rCP - l- ICP - 2 GFAA HG ODD STANDARD NUMBERS Appendix F - 406 STL Knoxville Metals Prep Spiking Form Analyst, lcnl U Date: a/glolo Batclr: @loloe.S8 393 Nitric Acid: tsSlo37 3001, Hydrogen Peroxide: YVziZQ Hydrofluoric Acid: Spiking Standards: I" Level Ret'iert' & Relinquished By,: lCnr.U )un Level Revierv & Received F'V, ..- il (/\ -, Acid Lot Numbers: Date/Tirne: Date/Tirne:. b- lO- O,C Hydrochloric Acid: E7;;**11. ._ Exp. Date: Exp. Date: Exp. Date: Exp. Date: Exp. Date: Exp. Date: Exp. Date: Exp. Date: Exp. Date: Exp. Date: Exp. Date: Exp. Date: 3005A 3010A 20A.7 Air-Train ILN{03.O I LNIO4.O Air-Train 30r 0A (N{S) 0.05 rnl of _ into 50 ml (LCS) 0.25 ml of _ into 50 rnl 0.5 rnl of YY6P^ga.n.into 50 ml 0.5 rnl of Y_y6ts *zl_into 50 rnl 0.5 rnl of Yit* *+A into 50 rnl 0.5 ml of into 50 ml 0.5 ml of into 50 ml I.0 ml of into 100 ml 1.0 ml of into 100 ml 1.0 ml of into 100 ml 1.0 rnl of into 100 ml 1.0 rnl of into 100 ml KNOX-I P.OOO2 KI{OX-tP-0003 Kh*ox -IP-0004 KNOX -IP-000s KIYOX-IP-0006 KNOX-IP-0007 KNOX-N{T-0006 Ki\ox-N,[T-0009 Comnrents: ICP SOPs (Circle N{ethod Used) NC Grou ndrvaters 3030C Total N'Ietals in Filters Air-Total Soils/!Vaste Aqueous Ontario Hydro CLP Water/Soils J\{MT SEP for As Appendix F - 407 RQC0s7 Severn Trent Laboratories , Inc. METALS PREP LOG/BATCH SUMMARY BATCH NUMBER: 606 5255 PREP DATE: DUE DATE Run Date: 3/l-4/06 Time : 6:34 :00 8:00 COMP DATE: 3/AB/06 rNrrrALS , &UD_ I,OT NTJMBER H68200L64 SOLTD H582 0 0 L64 SOLID H682 0 0 L64 SOLID H68200164 SOLID H5B 20 01-6 4 SOLID H6B2 0 0 A64 SOLTD H5C07'0000 SOLID WORK ORDER HXQlX TO DUE HXQ1XS HXQ1XD HXQ2H TO DUB HXQ2M TO DUE HXQ2V TO DUE HXQ?4 TO DUE HXQ:n TO DUE H0QR9B DUE H0QR9C GFA/WEIGHT t1 FLA/ WErGI-, 3 / o8 / o5 3/L3/06 q.c rcP./wErG_Hr HG / WE IGHT 5Ne .?t &01 DATE: 01 DATE: 01_ DATE: 01 DATE: 01 DATE: 01 DATE: 01 DATE: 3/13/oa 3/L3/06 3/L3/os 3 / L3 / o5 3 / L3 / o5 z/t3/06 a/oo/oo LEVEL 2 BLAI$K A\ID CHECK STA}TDARD ON BATCH MS/MSD A}TD PDS ON BATCH CURVE PREPPED FOR HG CORRECT SPIKES ADDED SPIKING SOLUTIONS DOCUMENTED ON BATCH LOG COMMENTS : B-BI,ANK/C-LCs/D-MSD/I-REANALYSIS/L-tCsD/P-SERIAL DI,TN/s-Ms/x-SAMP DUP/Y-SAMP CoNF/z-PDS SPIKING WITNESSED BY Appendix F - 408 395 STL Knoxville Anal5,st: _ EDrD-. . a 7470A1245.1: KNOX-N{T-0009, Rev. 3 Mercury Prep Spiking Forrn Date' -=J.g lnr- Batch: botob+€F N 747L1245.5: KNOX-N{T-00I0, Rev. 3 Appendix F - 409 Bath Temp, Q5" (Acceptance range 90"-95"C) Sta nda rtl Ty'pe Stan da rtl I D I ntermediate Std. Volu me Used (ml) Final Volume (ml) Fin al Concentratiott (u g/1,)Sou rce Con c.(u g/L) Calibration Std I N/A N/A N/A 50 Blanl Crlibration Std 2 I-CAL- rlol4- lS-3 9pex 100 0.05 50 0.1 Calibration Std 3 T.CAL- \r00 0.I 50 0.2 Calibration Std 4 I.CAL-100 0.25 50 0.s Calibration Std 5 I-CAL-r00 0.5 50 r.0 Calibration Std 6 I-CAL.r00 2.3 50 5.0 Calibration Std 7 r-cAL- c +100 5.0 50 10.0 Stan dard T)'lre Standa rd I D I nterrned iate Std. Volu me Used (ml) Final Volu rne/ \Veight Final C o ncen t rat ionSou rce Conc.(ug/L) ICV I-!'ER- 1o17-lS-3 Itl*ca r00 r.25 50 ml 2.5 uglL CCT'r-cAL- 4d4-t5-3 3Fry r00 2,5 50 ml 5.0 ug/L CRA r-cAL- J J,r00 0.1 50 ml 0.2 uglL Aqueous LCS I.CAL.r00 2.5 50 ml 5.0 u g/L Aq ueous I\1S I-CAL-100 0.5 50 rnl 1.0 ug/L Soil LCS I-CAL- 4ol.l-lS-3 3eqv r00 7(o'3 g 0.83 mgil<g Soil I\'lS r-cAL- J J r00 0.5 0.3 g 0.t7 mgrl<g TCLP i\,IS I-C.{L-r00 2.5 50 ml 5.0 ug/L REACENTS Conc. H2SO4 Lot #:Na 5% KMnO4 ID #:B-blal-1-c-, Conc. HNO3 Lot #:Bsl oT?5% K2SZO3 ID #:D- 2l-zg-f6-Q Conc. HCL Lot #:B>lAt-l SnCl2 Solution lD #:*-?n/ 4-*,-c t?,%,NaCI.NH2OH.HCL lD #:a726t- l-f)Aqua Regia ID #:f-71s8-ll-c N{T059Rl3.doc. I I /08/01 39 6 oJFUJE.oILo=Iav(oc)oNo(oIo) .Eaal , (t ro=oo[r Jar, uJLLFC) [!-)oE. (L I IoEcfE@(!z IO) () !- 4H3 9E -l - A (- . q. ) o€Eg A! cr ( t ) .- a q. l --'( ) c a 3 H ri - a rr i A ti ) d E 9. E :? 6 u o X, d ,9 8 5 .1 3 . h e lt ) r^ r li rH U ., : a I L F ao E- c Z 'o n F EI g ct d EB ; H. o . 9 Gr 0) + SE ; a- 3 r I E- e t< ( . )ot { H 't ( ) 5 AE . F xt r ; 6 EH T EE E .e . a t q -H r r $: H o oZ (' ) : r ( J - rla H U\ Vo 6 o a E- 8 !E d I- A I HE E; Ot + - , U- J g)EE P A .r J f eE -, , P E E a- 9 o) >. . :t JJ .a - ) oc l E g 6i =c o eb u ) ad H 6 ,1 , d, 0. ) c t r . i -c tr . 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I ca \o .J < !f , \oOoC. l ca \oJr r+\ooOhlo\oJ< t+\oOoc{o\oFk \+\ooOc{E\oJ< o o o TOCDF APPENDIX F SECTION 3.6 Mercury Data MPF SWDT REPORT - Rev 0 Appendix F June 9,2006o F-4 I I APPENDIX F SECTION 3.6.1 Mercury Raw Data MPF SWDT REPORT - Rev 0 Appendix F June 9,2006o F -412 376 STL Knoxville Mercury Analysis Cover Sheet Analyst FnrD Instrument Leernan Hydra AA Mercury An alyzer Run Date Blelob Chart Name t-loZo 8o(a Daily Maintenance As Needed Maintenance tr Check tubing.D Adjust/change Hg lamp (typically, every 3 months/every year, respectively). X Check maintenance schedule flags. D Clean optical cell D Lubricate purnp and autosampler arm. n Check gas tank level. The instrument autornatically flags the analyst when the pressure is too low. C Change the drying tube. Appendix 413 F- MT07lRl.doc, l1l2ll02 377 Instrument Upload SLarted Thu Mar 9 Data File: UPLSKIIX Run Log Page 09:35:37 2A05 by DAWSONK DATA ROOT: <LHG>H030805. PRN;1 1 CKz ICV 2 ICB 3 CRA 4 CK3CCV 5 CK1CCB 6 HoQTLB 7 HOQTLC B HoQR9B 9 HOQR9C 1O }IOLJB 11 HOLJBS 12 HO LJBD 13 HXQrX 14 HXQ1XS 15 HXQ1XD 1 6 CK3CCV 1.7 CK1CCB 1 8 HXQ2H 1 9 HXQ2M 20 HXQ2V 2L HXQ24 22 HXQ3D 23 CK3CCV 24 CK1CCB # WorkOrder Di lut i-on DaLe Time BaLch 0B-MAR-2006 13i35:34 0B-MAR-2006 13:37 :23 08-MAR-2006 13:39:11 0B-MAR-2006 L3:40:58 0B-MAR-2006 13:43:26 0B -tvU\R-20A6 13 :45 : 1B 0B-MAR-2006 13:47:04 08-MAR-2005 13:49:02 0B-tvlAR-2006 13 : 51 : 20 0 B -MAR -2005 13 : 53 :22 08 -tvlAR-2005 13 : 55 :21 0 B -MAR -2006 13 : 57 :18 0B -MAR -2005 13 : 59 : 0B 0B -MAR -20A6 l-4:00 :56 0B -MAR -2006 L4 :02:44 0 B -MAR -200G L4 :04 : 4 3 0B-Mi\R -2006 L4 : 07 : 41, 0 B -MAR -2006 L4 :09 :29 0B-MAR-2006 L4:LL:27 0B-Mi\R-2006 L4:L3:25 0 8 -Mi\R -200 6 14 : L5 : 42 08-M,Ul-2006 L4:L7:28 0 B -MAR -2006 14 :L9 :48 0 B -MAR -2006 t4 :22 : A5 1 .00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1,00 1.00 1.00 1.00 r.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 6065252 5065262 60662ss 60662ss 6055262 5056262 6066262 5066255 6066255 50562s5 5066255 6056255 505625s 5056255 60562s5 H5C070000 H5C070000 H6C070000 H6C070000 H5CO 3 O 2BL H5C0 3 0 28l. H5C0302Bt H5B 240L5 4 H5B 20 Ot6 4 }ISB 20 0l-6 4 H5B200L54 H68 20 0]-5 4 H6B2 0 015 4 H6B 20 0L6 4 H58 20 0l.5 4 Ins t rument HG HG HG HG HG HG HG HG HG HG HG HG HG HG HG HG HG HG HG HG HG HG HG HG - End of Report Appendix F - 414 378 IVlethod Nanre: Tpt.std/Sw-846 I 410A,7 41 lA/0.2 RL Element: Hg Chart Number: H030806.PRN Instrunrent Calibrated Every ? Hours: Correlation Coeflicient )l:: CRA Required?: Duplicate RPD: STL Knoxville Method Information 30.0 r 0.5 20.5 10.5 20.5 B C L Z x S D MSA+ 3 Nurnber of Calibration Standards: Run ICV Immediately After Calibration?: Number of Samples Betrveen CCVs: Calculate Duplicates by CLP or SW-846?: CRA Conc. (ugil-): 0.2 ICV Conc. (ug/L): 2.5 CCV Conc. (ug/L): 5 LCS Spike Level (ug/L): 5 MS Spike Level (ug/L): I Position to Signili Blanks: 6 Position to Signity LCS's: 6 Position to Signily LCSI)'s: 6 Position to Signify Dilutions: 6 Position to Signify Duplicates z 6 Position to Signily MS's: 6 Position to Signily IVISD's: 6 Position to Signill,i\{SA's: 6 Concentrations (ug/L) Standard 3 Conc: 0.5 Standard 7 Conc: 0 St:rndirrd I Conc: 0.I Standirrd 5 Conc: 5 Calibration Standard Stand ard 2 Conc: 0.2 Standard 6 Conc: 10 Standard 4 Conc: Standard 8 Conc: 6 Yes l0 SW-846 Protocol 0.2 24 0.995 Yes 20 CR{ ICV CCV LCS NIS/N'ISD Recovery Range: Recovery Range: Recovery Range: Recovery Range: Recovery Range: Letter to Signify Blanks: Letter to Signity LCS's: Letter to Signity LCSD's: Letter to Signify Dilutions: Letter to Signily Duplicates: Letter to Signify MS's: Letter to Signily MSD's: Letters to Signify MSA's: Number of Additions: I 0 ICjB/CCB Check Level (ug/L): 0.0601 IDL (ug/L): Prep Blank Check Level (ugll,): 0. l0l Reporting Linrit (uglL): 0.06 Date of IDL: 121812005 Appendix F 415 o STL Knoxville Mercury Data Review Checklist Method: 7 pt.std/Sw-846 747AN747 1A10.2 RL xNo - I insirumeni' L;"*"n Hydra AA Meiirry An alyzer Run Date: Mar-08-06 I Caf inrition NurnUet .t A. Calibration/lnstrumeni nun OC 1.lnstrumentcirlorateoe,u,ii.+.iiI.{I'?---.. 2.lnstrument calibrated using a minimum of a blank and 5 standards? 3. Do standard absorbanCei ,ncr"iie is standard N/A Yes ; nto iComments :x - | --- ciliuruiion was t,: X Element: i Hg I hours and 6 minutes long 'X concentrations increase? 4. lnstrurnen! calib_r1[e_d wilh gt_anQq15t_q e!_thg_SQ_P leygl!.?_ , ] 5.Correlationcoeff!qign!_grgater1han-qe_q!]elJgl0.99_E?---iCorrelation coefficient was 0.9999-: --.: - 7. ICV withiq sp_e_c.1fLed q_o_n_t1o:l lieLtq? B. ICB analyryd ipnqdiet_ely_efte_rjeV1 . . _:___ 9 I C B wilh i1 q_c_c_qp!a_bl e falgef_ 1 3. All CCB'9_!y_ilhita_ccep_!_qblere!Se?_* _:__ I x i _ _i __ , 14.AllCCB's_i11-alyz9{,i111Ledfately after CqV's? - -L__ _B. Client Sample and QC Sample Results 1. weie ill sampie i"trlti*iininTelinJairange-oitn" -i i 2. Were there any sarnples with results more negative I '1 Was one method Uralf Gpalgq iq€a._h pai"[i__ , - - 2 were all m9t[q0 btan]ss tegs than the sp_gcilt_e_d teygE _ 3, Was an LCSSIgpa_t gq lo_r each patch? 4. Wer_e_all LCS_ r-ec_o_yqrcg ry_ilhi1 QC limits? _ 5. Were matrix spikes, sample duplicates and/or post- I digestion sprhes !'utr A! Igqqifed fieqgercy? ___r 6 Were all mat1i4_qplf_q [ecQ_veries_ w_ithin QQ_tfujlq?_ I 7 Were po_sl-Qigegjiglr_9_pike_recqyelles withi! Qq_l11d!q?_ i I _ IB, Were duplicate RPP_q_y4ht!_aC_ Inilgt _ ._ D. Other 2.Current MDL data on file? "- - '-- r-lx ij,,____l_l, r'--. Tiixi Iiiil-- i - : -i i X i Lc,+ *tr g?oo ile{e.rpis"t a le lot, Analyst: AN D Analyst Comments: __ Date: =lqlrU O Ver Appendix F 416sion 2.1 Report MTO7BR1, 4114t04 380 *".1q ll[J luo3oBo6 r?prcurve I J Il urinUg qatabarr r"Zls f$e Sf,ity Heb €.. lnrlnqitj| - l*uoot I Tptcurve :] Protocol I Llne lnfo Ctl Curw Beset Ruport I crl chart I V Calihdad DatxdlFroto Hewtrl Re[ Abs. 1 052745 ADco$od 'Vilmv 1 oz 0z 0z 08 at 01 02 03 04 05 ffiil- .ffim -,036.lmm .lffi .2m00 .?u.smm .4811.mm 1.01 ?gP !g? 6ffi 210(B fin2 61ffi r156e4 SBSIE Reody ll uinng Databa;e t.iZt5 file Blity Heb € lnn.l lnn+ I *g) A I V Accepted Bti-ffi6- Clffi62 rho fiffisu lrahrdo IS1 Bcp 1p f f f f -.036 ffis ,922-.ffi .011 ,018 6fr8 am{ 33213 fi293 1 1 5624 53381 6 l_El i7@iTpe lthpx -iJ Update Coeffs $prke Coeffs SiD u URSD lnrumot Izo.*urv6 j] Protocol I LIne info Cal Curve Fle,d AI- BtffiE- c@ Report I cm Chart I vr*rur I tr Cdiharcd Ho[ Ab*. v Accepted 105274Ii Accrptcdw Newr- r rrofffie- lrptudel'E, Baplp t- f f az AZ g% az az az 02 03 04 ffi ffi av .1- .1ffim .105.zffim m.5mm 431 1.m00 1.01 s,mm 5.02 10.0m 3.93 2100{ 3Bgl3 61 293 115fl4 53391 5 1 062745 21 003 33f12 61 293 11S34 53815 1ffi2715 005 .922-ffi .011 ,818 -.010 O Cah Coeffs Updats Coelfe 9pike Cosrfs SD u ZHSD 417 Ddaspt/Proto 10 0 ,F STL Knoxville 13:16:01 0B Mar 2006 Line Conc. Units Folder: Protocol: SD/RSD 1 H030806 7pt curve 2 Pa ge 1 381 *** Hg *** Hg *** Hg *** Hg *** Hg *** Hg *** Hg *** Line Hg *** Hg ,r** Hg *** Lr- ne Hg *** Li ne Hg **)k Hg *** Hg *** Hg Standard: 1 Rep: 1 .000 ppb 6306 Standard: 2 Rep:1 .100 ppb 21003 Standard: 3 Rep: 1 .200 ppb 33272 Standard: 4 Rep: 1 .500 ppb 6t293 Standard: 5 Rep: 1 1 . 00 ppb 1 15624 Standard: 6 Rep: 1 5.00 ppb 533815 Standard: -7 Rep: 1 10 . 0 ppb 105 21 45 Check Standard: 2 Ck2icv EIag %Rcv. Found True L02 . 2. 55 2 .5A Samp1e fD: ICB ICB -.04 9 ppb . 000 % Sarnple I D: CRA CRA .224 ppb . 000 % Check Standard: 3 Ck3ccv Flag %Rcv. Found True 101. 5.04 5.00 Sample - .020 S arnp 1e 4 .88 Sampl e -.041 I D: HOQTLB ppb I D : HOQTLC Seq: 0 Seq: 1 Seq: 2 Seq: 3 Seq: 4 Seq: 5 Seqz 6 Seq: 10 Units ppb 13:23:54 1 3 : 26:21 l3:16:01 0B Mar 0o HG 13: t] :41 0B Mar 06 HG 13:19:38 0B Mar 06 13:2\:44 0B Mar 06 HG HG Seq: '7 13:35:34 0B Mar Units SD/RSD ppb .000 % Seq: B 13:31:23 0B Mar . 04 9 Seq: 9 13:39:11 08 Mar .224 0B Mar 06 0B Mar 06 58 0B Mar 06 HG 26 0B Mar 06 HG 06 HG HG HG HG 13:28:11 0B Mar 06 HG 06 HG 06 HG 06 HG Check Standard: 1 Cklccb Seq: 11Flag Found Range (+ / -) Units SD/ RSD -.034 .059 ppb .000 13:40: SD/RSD.000 z 13:43: I 6066262 seq: 12 13:45:18 oB Mar 000 t -.020 13 ppb f D: HOQR9B ppb .000 seq: 4 . BB Seq: 60 6 6255000 % -.041 Appendix F - 418 13:41 :04 0B Mar 0o 13:49:02 0B Mar 0674 HG STL 13:51 Line Knoxvi I 1 e :20 0B Mar 2006 Conc. Units Folder: Protocol: SD/RSD 1 H030806 7pt curve 2 Pa ge 2 382 * * * Sample ID: HOQR9C Hg 4.86 ppb *** Sample ID: H0LJB Hg .570 ppb .,rr** Sample ID: H0LJBS Hg 1.66 ppb *** Sample ID: HOLJBD Hg 1.51 ppb *** Sample ID: HXQ1X Hg - .023 ppb *** Sarnple fD: HXQ1XS Hg 1.10 ppb * rr * Sample I D: HXQ1XD Hg r .08 ppb Seq; 15 13:51:20 0B Mar 4.86 Seg 76 13: 53:22 0B Mar .570 Seq: L1 13:55:21 0B Mar 1. 66 Seq: 18 13:57:18 0B Mar 1,51 Seq: 19 13:59:08 0B Mar .023 Seq: 20 14:00:56 08 Mar 1.10 Segz 2L 14:02:44 08 Mar 1 .08 Seqz 22 14:04:43 0B Mar Units SD/RSD ppb .000 % Seq : 23 L4:01 :41 0B Mar SD/RSD .000 eo Seq: 24 14:09:29 08 Mar . 017 Seq: 25 14: !t:21 0B Mar .026 Seq: 26 14:13:25 0B Mar .019 Seq: 21 L4: 15:42 08 Mar .008 Seq: 28 LA:L-I:28 0B Mar .037 Seq: 29 14:19:48 08 Mar Units SD / RSD ppb .000 eo * * * Check Line Flag Hg * * * Check Line Flag Hg * * * Sample -. 04 3 I D: HXQ2H ppb HXQ2M ppb HXQ2v ppb HXQ2 4 ppb HXQ3 D ppb Hg -.017 *** Sample ID: Hg - .026 *.,k* Sample ID: Hg -.019 *** Sample ID: Hg -. 008 *** Sample ID: Hg -.037 Standard: 3 Ck3ccv 8Rcv. Found r00.5. 00 Standard: 1 Cklccb Found Range(+/-) .000 % 60 6 6262.000 % .000 z .000 % 6066255.000 g .000 g .000 % .059 True 5. 00 Unit s ppb .000 3 .000 B .000 % .000 eo .000 z 3 Ck3ccv Found True 5.01 s.00 06 HG 06 HG 06 HG 06 HG 06 HG 06 HG 06 HG 06 HG 06 HG 05 HG 06 HG 06 HG 05 HG 05 HG *** Check Standard: Line Flag %Rcv. Appendix F 419 Hg 100. 06 HG STL 14:22: Line Knoxville 05 0B Mar 2006 Conc. Units Folder: H030806.Protocol- : Tptcurve SD/RSD 1 2 Seq: 30 SD/RSD.000 r *** Line Hg Check Standard: 1 Cklccb Fl ag Found Range 1+ / - ) Uni t s -.038 .059 ppb 74 :22 :05 0 B Mar Page 383 Appendix F 420 s, P N) o APPENDIX F SECTION 3.6.2 Mercury Quality Control Data MPF SWDT REPORT - Rev 0 Appendix F June 9,2006 TOCDF F -421 118 Initial Calibration Yerification STL Knoxville Mercury Data Reporting Forrn Appendix F 422 Units: ugll @pb) Instrument ID: Leeman HydraAA Hg An Data File Name: H030806.PRN l l I I I I I I I I I l I I Elem True Conc Ck2icv 3t812006 l:35 PM % Found Rec Found ff..%Found Rec % Found Rec % Found Rec % Found Rec Hg 2.5 2,55 102. Mercury Report Generator Version 2.0 Form 2A Equivalent Continuing Calibration Verification STL Knoxville Mercury Data Reporting Form Appendix F - 423 119 Units: ug/L (ppb) lnstrument ID: Leeman HydraAA Hg An Data File Name: H030806.PRN EIern True Conc Ck3ccv 31812006 I:40 PM Ck3ccv 318t2006 2:04 PM Ck3ccv 318/2006 2:19 PM % Found Rec % Found Rec Found ff, oA Found Rec oA Found Rec % Found Rec Hg 5.0 5.04 I 00.8 5.00 100.0 5.0 I 100.2 Mercury Report Generator Version 2.0 Form 2A Equivalent Contract Required Detection Limit Standard(s)Units z ug[L (ppb) Instrument ID: Leeman HydraAA Hg An Data File Name: H030806.PRN STL Knoxville Mercury Data Reporting Forrn Appendix F - 424 !20 O Mercury Report Generator version 2,0 Elem True Conc CRA 31812006 l:39 PM % Found Rec % Found Rec % Found Rec % Found Rec % Found Rec Found ff, Hg 0.2 0.22 112.0 Form 28 Equivalent L2L STL Knoxville Mercury Data Reporting Form Initial Calibration Blank(s)Units: uglL (ppb) Instrument ID: Leeman HydrtuqA Hg An Data File Name: H030806.PRN Mercury ReportGenerator version 2.0 i -Ii*ffiffi1;:L"Ln*andReportingLimit Form 3 Equivatent Elem Repor-ting Lirnit ICB 3t8/2006 1:37 PM Found Flag Found Flag Found Flag Found Flag Found Flag Found Flag Hg 0.2 0.06 u . 722 STL Knoxville Mercury Data Reporting Form Continuing Calibration Blank(s)Units: uglL (ppb) Instrument ID: Leeman HydraAA Hg An Data FiIe Name: H030806.PRN Mercury Reporr Generator version 2.0 i - flli'*HffiTfl]i:ffi i"J, and Reporting Limit Form 3 Equivatent Elem Reporting Lirnit Ck I ccb 3/812006 1:43 PM Ck I ccb 31812006 2:07 PM Ck I ccb 31812006 2:22PM Found FIag Found Flag Found Flag Found Flag Found Flag Found Flag Hg 0.2 0.06 u 0.06 u 0.06 u t23 STL Knoxville Mercury Data Reporting Form Instrument Detection Limits Units: ug/L (ppb) IDL Completion Datezl2/8/2005 Instrument ID: Leeman HydraAA Hg An Data File Name: H030806.PRN Element Wavelength (nm) Reporting Lirnit IDL Hg 2s3.70 0.2 0.06 O Mercury Report Generator version 2.0 Appendix F - 427 Form 10 Equivalent o o o APPENDIX F SECTION 3.7 Ash Data MPF SWDT REPORT - Rev 0 Appendix F June 9,2006o TOCDF F-428 430 STL Knoxville Methods; ASTM Ash Determination Data D-4422,D-482, E830 by Page I of I Review I Narrative Checklist SOP: KNOX-WC-0013, Rev. 2 Batch Number:b0{?3/o Lot Number(s):r/bBoloo/6+ Appendix F - 429 Review ltems A. Calibration N/A Y N If No, why is data reporlable? 2nd { 1 . Was the balance calibration checked prior to use?/ B. CLIENT SAMPLE AND OC SAMPLE Results I . Were all special project requirernents met?/,r/ ?. Were sample IDs verified?/,./ 3 - Were all transcriptions checked?/ 4- Calculations checked for error?J / 5. Final report acceptable? (Results correct, units correct, deviations noted in narrative, and analysis dates conect. ) /v/ C. Preparation/JVtatrix QC I . Method blank done per batch of up to twenty samples?/ 2- LCS done per batch ol'up to twenty samples?/ 3. LCS/LCSD recoveries within laboratory established QC limits? (90-l l)Vo) If no, lisr LCS ID: /lr/ 4. LCS/LCSD RPD within laboratory established QC Iimits? (<107o RPD) If no, lisr LCS ID: /,r/ 5. Was a duplicate sarnple analyzed per batch of up to ten samples or for each trial burn proiect?/ 6. DUP RPD 407c of mean value ? If no, lisr ID:/lr/ 7. Were MS run #'s assigned correctly?/ D. Other l. Are all nonconformances Oorxr": a:propriarely? | J I l/v /) A nalyst ;/-n^ilAl/I\/ W Date: 3 / / / o/a 2n Level Reviewer: fffi-( ri-u>t<x-Q-l I I Date: AZ /n t / O A Comm6ntsy' l I /Comrnents: wc066R3.DOC, 8/22145 43 7 (f )c) \tc{O)oV, (ooooB -a 5oIt r 'E - r$ l+ r: h lar)!FIt it ts a f( >tqr! ls rt \ III .i . -:$ t :t t+t+t l+rt\'=sLl5i \4USE{siL,t I IIItIIIIIIItIIItIIII IIIIItIIIIIIIIIIIIItI o\s? axA, - A ,: . A, .+ E a i 3 e i1 ;- U g o o E b. 9 E: E E -o ri a .H Y 6 tr i : - ; b o = ( o I ! = d a o o0 .c . eE -s > ff cc . - : Bg 6 .9 E v) 'a I EE n2 E s6 7 ) cL .E o o a -. ; N 'a # fi oo . o td A aJE AA OOOO !P \o \o OO OO O F. 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P G .- ( 9 \ zEB c{o\ c. i oo f-sf ,qC\ $f-oc. i <> f-Ornc{ f-ooGIq Ntnf-q o\ t- -OnN \o\oqht \o00q cA .+rr )N r+ca r+oc. i f-f-og f-!f , rnc. i oo \oc\ tqc{ .+o\o\ oq ooo\ inrnci Or\toc. i c! ooOoq o\ oq lneo .f ,q o\o\ og t+<>C>c' i E a. ^ ,G t '6 g F} \o.+\n\ cnq aoNc. ) c. i \n tr - ) \q o\o\@\ ca -f , (\ lq \t\oq \f , ca !+q @f-caq \o \f ,oq ooooc" )q f-\oNoq \o\oOq .+f-q oo f. . r+og \o-f$q ooO(q ooo\ f-\ o\\ o\ CN .fq oo rnoq caca \oq o) .a'6 0 5 t- { f.U o\o c\ t$ r\o orn \f , rn Of- C. l r- - f*cn ra Oc\ I \oca Of- coc\ I o\c{ ooo $tn \r o\ c! c\ { O.A Cf ) f- \o\o *.c- IOX IaNoX Ec{qXA rI ];c\ IoXE ;(\ lqXl' f lA gC\ lOXil { rd=c\oX>J < Ec\ toX,F Iac\ tOX* rI ]NaX>l < d5c\ IoX:J < FNoXJ{ rJ ] .. +c!oX 6NOX>. t { ;c\ loXr. f { rl l rf )C/X il (r )qXht r tcooXE rl ] t&cooX>r < o(JO UOUO>J - { oOOO aF{+,F(u=U Js&r!FFU),r!Jn.aU) Jctr JF!, .2rJ ]OJcmjtaa.C' ) FzoJfr l*CN Ir lUlL , (Jjr!JO. l- a2,a JaCIFh)U)Ihtr!Jo.a Jar!FzG]olom1c! r!JAza FzaJrI ]aIQ() r&UI c\ l rr )Jq. \< a2U) 1ar!FFDaIon rI ]J0. 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F)4 {UmJI&Fz ?oq ) ER F. . v a Foooo t- , oo€ F- 00€ Foooo Foooo F00ao t- . oooo Foo@ F0000 Fooco t- .@oo Foooo Foooo Foooo t- . , 00 co Foooo F00oo Foooo F00oo Faooo F00oo F00oo xa- (a . .q- Ia X EA () J (. ) b : cl . , O tr r i F 'r t r t r Fr 6 t = az c. l (. t ) sf ta ) \o f- ao o\ O c\ l ca .+ rn \o t* - € oo Ocn Oca cn l-o.. 4-FT)z+,oI !f , \o5Oc\ co \o t+\oOoc{ ca \oFf . r+\o()C\ Fq \o il { .f , \oOoc{e\o>L { \t \oOc>c\ lm\o .+\oOONo\o>? { t+\oONm\o t+\oc><>r\ca \o .f9o<>NEA \o , fr -t \oooNFA \o ,n -f \ooOc\ lo\oEE s\oOoc{ ca ff i r+\oOOc\ ca \oE v\oOOc\ co+o +{ _ >J . { rf , \oOoc\m\o \f , \oOOc! ca \oFr rf\oOoc{m\o *+\oOoc. l ca \o t\ooOc! ca \o OO00c!o\o OOOOooNo\oJr COOOooNco \oJ{ 43 2 \f , (>€cncr )?&rfr\OUF(R\r \N\\VN mF( olI 3- B0 = O rt gJ Y .= - = = )j t : x tx ct - E A LVMg Z o= = - = _i; ,{ \s \\ts \\sx O tl \o r- - cc o\ = = I = : : 9 = = I R il S R o o o APPENDIX F SECTION 3.8 Higher Heating Value Data O MPF SWDT REPORT - Rev. 0 Appendix F June 9,2006 TOCDF F -432 434 STL Knoxville lleat of Combustion Data Review / Narrative Checklist Methods: ASTM D5865, D240 by SOP: KNOX-WC-0010, Rev.0 Page I of I Batch Nurnber:6oGtt2? Lot Number(s):H{ B2oo/1,1 Revi*, ltems A. Calibration N/A Y N If No, why is data reportable? 2nd .,J l. Was an initial calibration performed for each bornb/bucket cornbination and were the %RSDs< l%? ,/o./ 2. Was a daily calibration chcck performcd for each bomb/bucket combination and wsre the %D< lo/o? J lr/ B. CLIENT SAMPLE AND QC SAMPLE Resulis 1. Were all special project requirements met?v ,/ 2. Were sample IDs verified?,/ 3. Were all transcriptions checked?,/A/ 4. Calculations checked for enor?'/.-/ 5. lf combustion aids or additives were used, were the gross calorific values of each additive calculated from the averase o[three runs with %RSD<l%2 ,/ 6. Final report acceptable? (Results correct, units correct, dcviations noted in narrative, and preparation/ analysis dates correct.) ,/[btuJ Narrative method description. C. PreDa ration/lVt atrix QC l. LCS/LCSD done per batch of up to lwcnty samples?t/,,/ 2. LCS/LCSD recoveries rvithin laboratory established QC lirnits? (9E-102%| If no, list LCS ID: ,/ l. LCS/LCSD RPD within laboratory establishcd QC lirnits? (<2,0o/o RPD) ,/ 4. Was a duplicate sample analyzed per batch of up to 20 samples?t/ 5. DUP RPD <IO.O% ? If no, list ID:,/o [rpd2J LCS showed acceptable results. Results indicate sample heterogeneity._/ 6. Were MS run #'s assigned conectly?,/ D, Other l. Are all nonconformances documcnted appropriately?t/ NCM #: Analyst: .lntluvqphrc*t lDate: 3/6/o6 z"dt cvclniviiiwiifr.W Z- Cornments:Comments: Appen txr 43 5 caC) (oo,oxooc)o3 -to c) + . ?E ? rT L c l |r t L \J oU oo o\ \o oo oo co CO (n o\ o\ (a ) oo \o co \r ^ ) $ v r- . \o oo \o f- .3 8EE E a A/ \ - -t !, ti l Nooo\O ooC-Oc. lO f-oo{o tr 1o\o\O tr ) f-Oro f-\oONO O\oo\C> o\O.o c\o\OtO oo \o(} \C; No\o\o oocnONCJ tr ) coOc\ lo f-o\O \o\f ,c) ct lo c!Oc!O o\ooo{O o\OoNd rOe{C; rtOo' lO U l- a5$ e E'o L+ ) .t 3 E +. 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S \{fn =- :l :Ii cr t f: . b0o}' ]G{J6caq) -aF.Fl ts60a q) -lFl .l XotIMF]Era T_l _' lll-1Jll rS r- 9 r+ (( G l clI1q . s q-f ooN, , Fl q o o: 6 r . r a i$ f H +. g * ; i, }- l- , t- -l Jr J )' F ,{ t r ) Ug b- ? F a Aro2 Y J T us i 9 5s f f , 2t ? \ S , Bi : a s$ $ +- *^ 6 - .-vF{-, \, .- t-IUBIXczM€AHool{. fottA-AarFIoUca - {o+f6c) l+ { FH olllIIlloI 43 8 caO ,\ f , o\ i{f-OUB T_l ca fr . Ot- {-=-: IUBIX oo A !. ' . A V xj z 't = M HE E s! E \A . I bJ y € .= = ro . tG r e a= -oUct {o .l r ) 6to-I lllllllll]ll1l1 .JrA- ddvl 439 STL Knoxville Sarnple ID: lVork Order Number: Analysis Date: Std. or Determination? Analyst: HoC Drta Worksheet_Revision 2-A92203 xls Tunphle Bornb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-WC-0010 H6B2ooLb+ e oot HXa rx I Ac , /"/ob Dalr Jretl Appendix F - 438 Page I Bomb Calorimeter Data Worksheet Revision I September 9, 2003 Jrrt H e/o/* 9/8/2005 7:16 AM Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Calorimeter Data Report 5100 , 1iz 15* t, -? 1 Parr 1I6t t]:.al,=rimeter Reu, ff5219? Uni t # B 83/8313955, l4r E?; lt l'lode: De ternri nat i u-in I'le t hod: Dgnani i c TgF e: F i n.r 1 Sample ID 23.4 lrlei gh t B,2525 Bnrrrb ID 5 EE l.J.rlue ?I9I.?1EB 5p i ke tlgh t B. l gBI Fuss 18. BBB0Hcid +.1266 5u1fr-rr 0.BBt:18 Ini t. Tenrp !J. ?fEB Temp, Ri=:E l.8913 Jarket. T 3Er,t3BBB Eross Fhat 5384.9821 cal/g 440 STL Knoxville Sample ID: Work Order Number: Analyiis Date: Std. or Determination? Analyst: HoC Drla Worksheet Revision 2 092203.x1s Tcmphte Bornb Calorimeter Data Worksheet Measurernent of Heat of Cornbustion per SOP KNOX-'WC-0010 H6920016{- oor x HXQtXIAS e /? /ob Datr Jrr lt Appendix F - 439 Page I Bomb Calorirneter Data Worksheet Revision I September 9, 2003 Jr.H 3/Llob 9/8/2005 7:16 AM Gross Heat of Cornbustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Calorimeter Data Report 5?2,6,51ci 1587, 86 Parr 1?6b Calorirret,er Rerr, 05?lB?unir+B 83.,03/29A6 15:84:38 l'lode; Dr te rnr i na t, i on l'1e thod: f,,gnanr i c THpe: F i na ISapfe ID 235 l,lqighr 8.?521 Bornb ID 4 EE Ualue 2387. I4II 5p i ke tdgh t B, ZBPB Fuse I g. BBEB Hci d .1. ?327 5ul lur B. ABBB Ini t. Tenrp 13. 6769 Temp. Ri se I . t ZZ? .Tacke t T ?9. 3? l3 Eross lleat 53?6. 5Bg7 calrg l l I l l l i I I I i I i I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I 441 STL Knoxville Sample ID: Work Order Number: Analysis Date: Std. or Determination? Analyst: HoC Data Worksheet Revision 2 092203.x1s Ternplate Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-'\ryC-0010 H 6Bzoo t6t - oo a HxQzDrAc )llloto Dc+r J}{H Bomb Calorimeter Data Worksheet Revision I Septernber 9,2003 Jrrl e/ slo 6 Gross Heat of Combustion (caUg): Gross Heat of Combustion @tu/tb): Bomb Calorimeter Dota Report bLlq.1)o Parr 125b Celorimeter Re,.,', 05?lE? Llni t * g 83/Eg /28E,6 1.5: 28: ?B Hpde: De t.e rnii n$ t i on f'ler,hodr Dgnarrric TUF*I Finel Saryle ID 2# trleight 0.2542 Bonrh I D 3 EE Ua I ue 2193. 21 58 5p i tre trlgh t E . 3B 17 Fuge I 5. BBBB Hcid 4.5441 5ul {ur E. BE0B Ini t. Temp ?3.3865 Temp. Ri=e l, tBlf Jacket T 30.BB6F Gross Fleat 6219.9384 cal/g Appendix F pf68 r 7 t12t2005 3:49 PM 442 STL Knoxville Sarnple ID: Work Order Number: Anhlysis Date: Std. or Determination? Analyst: HoC Data Worksheet Revision 2 092203.x1s Ternplate Bomb Calorimeter Data Worksheet Measurernent of Heat of Conrbustion per SOP KNOX-\ryC-0010 t{6B2oot6+ - eo} HxeaF rAc .,._,,)/>/ob.-._ _ Dc*r* Jlrr! Bomb Calorimeter Data Worksheet Revision I September 9,2A03 JsH ,/6/06 7 t12t2005 3:49 PM Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btuflb): Bomb Calorimeter Dota Report 56r). 51L ffi2+,+1 P.arr 1?66 f,elorinret.er Reu, 8SAIB?Unit # B gSrBg,..2EB6 1S:I6:IEl'lode: Deterrrinat ionl'lethnd: Dgnernic THpe! FinalSarple ID ZS? hteighr B. ?EZs Bonrh I t, 4 EE Ua I ue ?IBf , !47?Spilretilght B. lgg5Fus* lB.Bg0gRcid 4. ?263 SuI lur B. B6BEIni t.. Temp ?J,I74S Ternp. Eise l. 1ABEJacket T rE.rrEEr Gross !.teat ssls.sg2s cal rg Appendix F p"le|rr STL Knoxville Sample ID: Work Order Number: Analysis Date: Std. or Determination? Analyst: Bornb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-WC-0010 H6 g?oot64 - Oo.l HXo ZH r AF " /b /ob D*r Jntl Appendix F - 442 Page I 443 Bomb Calorimeter Data Worksheet Revision I Septernber 9,2003 JlrH s /6 /ob 9ta?ao5 7:16 AM Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Calorimetu Data Report 5950. *oz TLlo ,1L Parr 1?66 ualorirreier Re,,,. BS2LA? Unir * B 85r'86./2088 t3B:08:Ba f'lode: [,etgrmi neuion I1e th,ld: [lgnsnr i c TUpe: F i na ISryle ID 238 ttle i gh t B, ?538 Bomb ID 3 EE l,l.3l ue ?393. BI I'-T Spi ke ttlght B. 1975 Fuse 1'9. ABBB Hcid 4, 1453 Sul lur E. B0BE Ini t,. Temp ?2.44ffi Temp. Ri se I . B3b4 rTatrket T 3B,BB?9 Eross Fleat 5354.4018 calrg o HoC Data Worksheet Revision 2 092203.x1s Tcmplete 444 STL Knoxville Sample ID: Work Order Number: Bomb Calorimeter Data Worksheet Revision I September 9, 2003 Bomb Calorirneter Data Worksheet Measurement of Heat of Combustion per SOP I(NOX-\ryC-0O10 It 6 bzoo l6* - oo5 HxQzJtAc Anrlysis Date: Std. or Determination? Analyst: HoC Data Worksheet Revision 2 092203 xls Tcmpbte .., ,,t&k9-.. Datr Jr* tl Gross Heat of Combustion (caUg): Gross Heat of Cornbustion (Btu/lb): Bomb Colorimeter Data Report bzLb, q+0 il ?oa. 6l o PBrr l?t'6 Calorimeter Rerr. 852182 unit * B 85/86.,?88S E8r15rl7 l'lsdel Det,e rm i na t i on l'le thod: Dgnam i c TUFe: F i ne I Sanple ID 239 tile i gh t g. ?541 Eonrb ID 4 EE Ualue ?387.5990 5p i ke. trlgh t B. 2B6P Fuse 13. 8Bt3BHcid 4.5911 Sul f ur B. BBBB Ini t. Ternp 22.8816 Tenip. Rise 1.21?7 .Iacket T 38. BB18 6ross Heat 62?s.94$2 cal/g J^{H e / 6/o6 Appendix F - 443 Page 1 9/8/2005 7:16 AM STL Knoxville Sample ID; Work Order Numbcr: Analysis Date: Std, or Deterrnination? Analyst: HoC Drta Worksheet Revision 2 092203.x|s Tcrnplete Bomb Calorirmeter Data Worksbeet Measurement of Heat of Combustion per SOP KNOX-WC-0010 Abf:zootL+- oob HXQZK IAC 3/a/ab Detr Jmtl Appendix F 444 Page I 44; Bornb Calorirneter Data Worksheet Revision 1 September 9, 2003 Jrd{ e/3/ ob 9/8/2005 7:16 AM Gross Heat of Cornbustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Calorimeter Data RePort 5+q t, 65b 166+.10 Parr 1?6€' Calol'iffiater Reu. 85? lgzunirsB 83/A6z28g6 8g:56:35 I'lode: 0eterminat ionl'lerhc'd: Dgnarnic TUpe: Final Sanple ID 24r. Lhight B.ZE69 Bomb ID 3 EE Ualue ?393. BSlg 5p i ke tJgh t B. 1968 Fuse I 3. BB9AHcid 4.2128 SuI f ur E. BBAB Ini t. Tenrp ?2.335? Tenrp, Risp 1. 1 14? *I.BCke t T 30. BBBP 6ross l"leat 5491 , GSgs cal/g STL Knoxville Sample ID: Work Order Number: Anatysii Date: Std. or Determination? Analyst: HoC Drta Worksheet Revision 2 092203.x1s Tcnplrte Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-\ryC-0010 Hab2,oo(o* - oo7 446 Bomb Calorirneter Data Worksheet Revision I September 9,2003 J.lat J/o/oL 9/8/2005 7,16 AM F Pqtt, .. Jnrl o Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Colorimeter Data Reporl bAqT .5oz q7t5,5o Parr L266 Calorirneter Reu. 452182 Unit#0 83"86,,2A46 88:43:56 I'lode: [ieterminetion I'lethc,d: Dgnanric TUpe: Final Sample ID 24I trleight 8,2543 Bomb IF 4 EE Ualue 23g7.3BBg Spikeblght B. 19?1 Fuse 15.0ABB ffcid 4,1SbS Sulfur B.BB8I3 Init, T*mp 7?.4739 Ternp. Rise 1.1BBB Jacket T ?9,9986 Gross Heat 5397.5819 cal/g Appendix F - 445 Page I 441 STL Knoxville Sample ID: Work Order Nurnber: Analysis Date: Std. or Deterrnination? Analyst: HoC Data Worksheet Revision 2 092203.x1s Tcmphte Bornb Calorirneter Data Worksheet MeasuremeDt of Heat of Combustion per SOP KNOX-'WC-00I0 A oBl}qatb+ - ao| HXQ?? rAc -.-,-? /b /ob---,. . . 9dr JHH Appendix F - 446 Page I Bomb Calorimeter Data Worksheet Rev ision I September 9, 2003 J,*r4 e/c/ o{ 9/812005 7:16 AM Gross Heat of Combustion (caUg):67r+{, o65 Gross Heat of Combustion (Btu/lb), -, , -r, ,3?2 , ,4 _-_--..-__. Bomb Calorimeter Data Report Parr 1?66 Cslorimeter Reu. B1ZIB? UNit S B 83,'8F,/2866 Bg:81:18 l'lode: Detprminat ionI'tethodl Bgnamic TUpe3 Final Sanple ID 242 trfeighr B, ?S1g Bomb Ir, 3 EE Ua I ue ?393. 4319 Spi ke trlght g, lgBf Fuse 19. BBABRcid 4.514? 5uI fur B. BBAB Ini t, Temp ??.738? Temp. Riss 1, 1g3g Jacket, T 3B.08A6 Gross l-bat 624A.06{z cal/g 448 O STL Knoxville Sample ID: lVork Order Number: Analysis Date: Std. or Determination? Analyst: HoC Deta Wo*sheel Revision 2 092203.x1s Tanphte Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-'WC-0010 H6g1o0tb* - ooq Hxazq rAc Dctr -f rrtfi Appendix F 447 Page I Bomb Calorimeter Data Worksheet Revision I September 9, 2003 Jr.rH e/a/oe Gross Heat of Combustion (caUg): Gross Heat of Cornbustion (Btu/lb): Bomb Calorimeter Dota Report 550q. LL5 1qrl . *o Parr l'lhb rlalorimeter Rer". E5?182 uni t # g g3,a6/29t16 B9; 89: 87 l'lode: [:e [e rnt i nat i an I'le tho'J: Dgnam i r TUpe: Fi na I Sample ID 243 hlei gh t E. ?546 Bonrb I t, 4 EE Ual ue ?387 ' 3BB0 Spik*tdght B.1968Fuse 19.8BBB Hcid 4. 1927 5r-rl f ur B-BABB Ini t. Temp 2?. $BAE Tenrp. RiEe 1. lBBg Jackeu T 38. BE1B 6ross Fhat 5589.6647 calrg STL Knoxville Sarnple ID: Work Order Number: Analysis Date: Std. or Determination? Analyst: HoC Drta Worksheel_Revis ion ?_092203.x|s Tcmplrle Bornb Calorimeter Data Worksbeet Measurement of Heat of Combustion per SOP KNOX-'!VC-0010 H66?oot6+ - or o HXQZVIAF )/b/oL Dctr Jl^tl Appendix F 448 Page I 449 Bomb Calorirneter Data Worksheet Revision I September 9,2003 Jee ll a /b /oL 9/8/2005 7:16 AM Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Cslorimeter Dota Report 5+ t0,1q1 1l 5r. 07 Parr I?66 C.elorimet.er Reu. BS?IB2 uni t. * o o3t96./?Ag6 6g: 2g: ?5 J'lode: f,,etPrmina?ion f'le thod: Dgnam i c Tgpe: Fi na I Sanple ID 244 hleight 0,2553 Bomb ID 3 EE Ualue ?393. B31g 5p i lre trlgh t B. 1992 Fuse 15, BBBEHcid 4. 2846 Sul fur B. BB0A Ini 1". Tenrp ?7.97ff Ternp. Rise 1, 11?B .,IECIEe t T 29.9997 Eross Heat 5418. Z96Z calrg 450 o STL Knoxville Sample ID: H69Zoot64- ott lVorkOrderNumber: Hxdzo (Ac Analysis Date: __ 3 /e/ob Std. or Determination? Datr Analyst' Jre!{ Gross Heat of Combustion (caUg): 6L5+ , 721 Gross Heat of Combustion (Btu/lb)r __ I !_, r! f._S-t Bomb Colorimeter Data Reporl Perr l?bb f,alc,rirrpter Eev' 052182 unit*B 83,,86./2885 09:35137 l'lode: Pe t,rr rnri na t i on I'lEthod: Bgn,trnic TUF'e: Final Smple ID 245 Lrlei ght B. 2558 Bonrb I D 4 EE Ua I ue 23S7. 3880 5p i ke ttlgh t B. ?B5g FuEe 18 . BBBE Hcid 4.5981 5ul{urr B.BBBB Init, Temp 23.8477 Ternp, Rise 1.?198 Jacket T SB,A0ZB 6ross Hea? 5254.729? cal /E Bomb Calorimeter Data Worksheet Revision I Septernber 9, 2003 Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-WC-0010 J^d{ 3/6/ob Appendix F - 449 Page I 9/8/2005 7:16 AMHoC Drla Worksheet_Revis ion 2_092203. xls Tcmphte 451 STL Knoxville Sample ID: Work Order Nurnber: Analysis Dater Std. or Determination? Analyst: HoC Drta Worksheet_Revis ion ?_092203.x!s Tcmphte Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-WC-O0I0 1166 Zoot6* - o tt x ItXOZ0 raF t /u /ob Ds$" Jnlt Appendix F - 450 Page I Bomb Calorimeter Data Worksheet Revision I September 9,2003 Jxd 3/6 /ob 9/8/200s 7:16 AM Gross Heat of Cornbustion (caUg)l bZlZ , A1 0 Gross Heat of Combustion (Btuflb): ... .l lr I Q j.,.,J * Bomb Calorimeter Data Report Parr 1Ib5 Llalorimeter Reu, B52lB2 uni r # B 83./06 t2886 89: 55: 47 I'lode: Determinet ic,nl'lethsd: Dgnanric THF,e; Final Suple ID 246 bJeight B. ?557 Bomb ID 3 EE Ualue !393. BIIS 5p i ke trlgh t, 8. 20SS Fuge I 6. BEAB Rcid 4.5736 Sul fur B, EBBE Ini t. Tenrp 23, 8Sg6 Temp. Rise 1. ?836 Jacket T 38. ulE I 1 6ross Heat 6212.8779 calrg O STL Knoxville Bornb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-\ryC-0010 Sample ID: _ H_6 B Zool.gt :.0. I L Work Order Number.: ,_. S.xS z7.t lL,._ Analysis Date: ? / i! / ob __ 452 Bomb Calorimeter Data Worksheet Revision I Septernber 9,2003 JrH a1e /4 9/8/2005 7 T6 AM Std. or Determination? Analyst: 12ctr Jratl Gross Heat of Combustion (caUg); Gross Heat of Combustion (Btu/lb): Bomb Calorimeter Data Reporl 5+61 ,zbz 1S++.b7 Parr lIbE ualorinieter Reu. g5!18? Uni t * B 83.186 fi886 18: BI; 5t Flode: De te rnr i na t i on l'le thsd: [tgnanr i c THF,e: F i na I Sauple ID ?47 hlei gh t B. 2577 Bornh I t, 4 EE l.Ja l ue ?387, 30BB Spike trlght B. 1971 Fuse IS,8AB6 Hcid 4.2296 5ul lur B. BBBB Init. Tenrp 23.?SB5 Tenrp. His* 1.1?13 -IECket T 3B.OBB1 Gross Heat 5469.26ffi cal/g o HoC Deta Worksheel Tcrnplrte Revision 2 092203.x1s Appendix F - 4s1 Page I STL Knoxville Sample ID: Work Order Nurnber: Analysis Date: Std. or Determination? Analyst: HoC Drta Worksheet Revision 2 Tcmplete Bornb Calorimeter Data Worksheet Measurernent of Heat of Combustion per SOP KNOX-1ryC-0010 H6bZoo(6'l - ot3 HXQT* r AF ,l L Iob DG.tr JrrH Appendix F - 452 Page I 453 Bomb Calorimeter Data Worksheet Revision I September 9, 2003 Jril r/6 /"c 9/8/2005 7:16 AM Gross Heat of Combustion (caUg): Gross Heat of Cornbustion (Btu/lb): Bomb Calorimeler Data Report ,>1 6 ,n1g 1l t3 ,+A Farr 1Z6E Cslorinieter Rer.r. BFZIB? Unit*B E3.-'86,"3805 lBz52r41 l'10de: De te rnr i nat i on I'lethodl Dgnanric THper Finsl Sample ID ?{8 ttleight B. ?548 Bonrh I D 3 EE Ua I ure ?3?3 . BS 19 Spi ke tlght 8,3846 FuEe 15. BBBB Hrid 4. ?3gF 5u1 fur A.AgAg Init. T*nip ??.3817 Tenrp, Eis,? l.12lA J.3rke t T 23, 9995 6ross Fhat 5596.5782 cal/g O 092203.xls 454 I STL Knoxville Sample ID: lVork Order Number: Analysis Date: Std. or Determination? Analyst: HoC Drta Worksheel Revision 2 092203.x1s Temphte Bornb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-\ryC-0010 H6Bz@ l6Ll _ or * Hx AZ5 tAC I /o lob ?o*r JnH Appendix F 453 Page I Bornb Calorirneter Data Worksheet Revision I September 9, 2003 lptl s /s /oL 9/8/2005 7:16 AM Gross Heat of Combustion (caUg): Gross Heat of Conrbustion (Btu/lb): Bomb Cilorimeter Data Report bz+a. r rf o tl ,L5z,25 Parr t36b Calorimeter Reu,. 85?1112 Uni t * B 83196 /2fl86 18: 59: 5? J'lode : De te rrn i na t i onl'lethod: Dgnarrric Tgpe: Final Saple ID ?49 hleight 8.2494 Bornb ID 4 EE Ualue ?387.5880 Spi ke trlgh t 0. 2821 Fuge I 4 . BBBAHcid 4. 5456 Sul f ur B. BEBB Ini t, Temp ??.4.17? Temp. Rige l. 1?45 Jacket T 30,809? Eross Hear 624A.L4VZ calzg 455 STL Knoxville Sample ID: Work Order Number: Analysis Date: Std. or Determination? Analyst: HoC Drta Worksheet Revision 2 092203.x1s Taophte Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-\ryC-0010 H a b?oo i6.+ - ots HXe 26 r Ac t/e/ oL 9etr Jr.rH Appendix F - 454 Page I Bomb Calorirneter Data Worksheet Revision I September 9, 2003 JrrH tlo lo ( et8t2005 7:16 AM Gross Heat of Combustion (caVg): Gross Heat of Combustion (Btu/lb): Bomb Calorimeter Data Report 5+6O.6zo q830, rL Parr 1266 Calorimeter Reu. 45218? Unit#g 83..'BEI2O66 tl:22=l? l'lode: fie t.e rrfi i na t i on I'lethod: Dgnamir TUpe: Final Sanple ID ffi trleight 9.2531 Bomb ltt 3 EE Ualue 2393,8319 Spi ke blgh t B. ?gB9 Fuse 14. BBBB Hcid 4.?2BA Sul f ur g.BAAn Ini t, Tenrp 2?.5735 Tenrp. Rise 1. 1151 Jacket T 38. BB11 Gross Fbat 5465.6195 calrg 456 o STL Knoxville Sample ID: Work Order Number: Analysis Date: Std. or Determination? Analyst: HoC Drta Worksheet Revision 2 092203.x1s Tcmpblo Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-\ryC-0010 H6 oLool 64 - o t6 HXO3D rnF " /6 /o6 Datr J rtH Appendix F - 455 Page I Bornb Calorimeter Data Worksheet Revision I Septernber 9, 2003 JnH B/6 /o3- Gross Heat of Cornbustion (caUg): Gross Heat of Cornbustion (Btu/lb); Bomb Cslorimeter Dsta Report Sltt t78 lbb$, o 3 Parr 1266 Calorimeter Re,.r, B52tB? Unit * A 63;66,,?ABE 11:?9:35 l'lsde: De ta i'rfr i na t i onl'letho'J: Dgnanric Tgpe: Final Saryle ID 251 trle i gh r B. 25BE Bornb I D 4 EE Ua I ue 2387, SBSB Spi t;e tlght 0,2BBg Ftrse 17, BBBARcid 4. 1685 Sul f ur 8. B0AEInit. Ternp ??.7lfrEt Temp, Rise 1,lBSB Jacket T 30, BB13 Gross Fhat 5371. 1280 calrg 457 STL Knoxville Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-1ryC-0010 Sample ID; H6 B zoo t 6tl - o t? WorkOrderNurnber: HxQaE \Ac AnalysisDate: _l/6/oL Std. or Deterrmination? Dctr Analyst: Jr.rH Gross Heat of Combustion (caUg) z 6? 71 , 53t Gross Heat of Combustion (Btu/lb), .. ,. l,l t *,1=25-.. ,- Bomb Calorimeler Data Reporl Pgrr I?,6f;, Calorimeter Reu. g5:102 Unit * 0 63tBdr2BBe, 11:58:35 I'lode r De te rrn i na t, i on l'tethod: Dgnamic THpe: Finel Saryle ID 25i2 l,leight 8.?544 Bornb ID 3 EE [Jal ue 2393. 8319 5p i ke hlgh t B, 2B I 5 Fuse 16. 0BulB Hcid 4,551 I Sul f ur 9.OAAB Ini t, Temp ?2.f468 Ternp. Rise 1 . ?837 Jacket T 29.9989 6ross Fbat 625.7.5.297 calrg Bomb Calorirneter Data Worksheet Revision I September 9, 2003 .ln tl a /e /o6 9/8/2005 7:16 AMHoC Drta Worksheet Revision 2 092203.x1s Tcmphte Appendix F - 4s6 Page I 458 o STL Kuoxville Sample ID: Work Order Number: Analysis Date: Std. or Determination? Analyst: HoC Data Worksheet Revision 2 092203.xts Tcmphte Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-WC-0010 U6b ?-oo l6 t - ot E HXQ } F IAC )/s/ob Ddr uult Appendix F - 457 Page I Bomb Calorimeter Data Worksheet Revision I Septernber 9, 2003 Jm F/ , /6 /o6 9/8/2005 7:16 AM Gross Heat of Combustion (caUg): 6456 , 4 tf Gross Heat of Combustion (Btu/lb): _ 1 E*1. r { Bomb Calorimeter Dato Report Perr 12bb Calorin''pter Rerr. E52Ig? unit * B 03,,86.'2886 11:57:55 Itlode z llet ?rminat ion I'lathod: Dqnsnric THFe: Finsl Saryle ID 2S hlei,lht 8.2565 Bomtr ID 4 EE Ualue 2387.3884 5pi ke trbht B, 2814 Fuse 18. BBB0Flcid 4.2518 Sulfur 8.BBBB In i t . Temp 22,8759 Temp. Ri s* 1 . 12Bg Jacket T 38.ABn 6ross Fhat 5468,4134 cal zg STL Knoxville Sample ID: Work Order Nurnber: Analysis Date: Std, or Deterrnination ? Analyst: HoC Drta Worksheet Revision 2 092203.x1s Tcmphte Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/tb): Bomb Calorimeter Data Report Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-'WC-0010 [1 6 Coz.eoog - vq c HoGDKtAA 5lt/ab Datr -rrr H Appendix F - 458 Page I 459 Bomb Calorimeter Data Worksheet Revision I September 9, 2003 Jl't l{ 5/t /06 9t8t2005 7:16 AM L2.17. I t g ll, 11+. gl F e r r l?b6 Ce l,: ri rfie te r Re'.t. 052192 Unit * B g3/95,'2846 14:16:48 l'lade; Determinat ir,n l'lethod: Dgnanric TUFe: Fingl Sapf e ID 232 lrlei,lht 1,8279 Bamb I D 3 EE l"l.sl ue 13'33. 2 158 5p i tre tlgh t. B. EBBE Fus* 15. BAB8 Flcid 10.26855u1{ur 6.BEBEI I n i t . Ternp 23. 4?2? Tenrp. Eise ! 7t5€. Jacke t T ?9. 99S7 Gross l'har. 6?97. I 182 calrg STL Knoxville Sample ID: Work Order Number: Analysis Date: Std, or Determination? Analyst: HoC Drta Worksheel Revision 2 092203.xts Tanphle Gross Heat of Cornbustion (caUg): Gross Heat of Combustion (Btu/lb); Bomb Calorimeter Data Report Bomb Calorimeter Data Worksheet Measurement of Heat of Cornbustion per SOP KNOX-1ryC-0010 Fl 6Cozloa| - vq L l{0CrDKtAc 5 lt /ob Datr J*tt Appendix F 4s9 Page I 460 Bomb Calorirneter Data Worksheet Revision I September 9, 2003 bzotl . o3O il, ,2), 87 JrH a/t/ob 9/8/2005 7:16 AM Parr 1266 Cslorimeter Rev. 852182UnitSB 83.,03/?.AA6 14:24:f,7 I'lode r De tP rm i na t i cn l,le tho,J: Dgnsrrr i c TUpe: F i na I Saryle ID 233 trleight 8.998? Bomb ID 4 EE Ualue ?3S7.t477 5p i ke blgh t B. BBB0 Fuse 1 7. BBABHcid 9.3€,46 Sul f ur g. BBBBInit, Tentp ?3.5173 Tenip. Ris* ?.6419 Jache t T 38, BB33 6ross lleat 6n l . A3S calrg 46l- STL Knoxville D ilv Calib Check St dard Calorimeter Calibration Worksheet 030306 CCV.Bomb 3.xls Template Calorimeter Calibration Worksheet Revision 0 8t28t03 Calorimeter Calibration Worksheet Determination of Energy Equivalent (EE) per SOP KNOX-WC-0010 ti, 3/8/2006 1:03 PM Pase 1 Appendix F - 460 Initial Calibration Data Calorimeter Sample ID Mean EE cauoc) SD BE (caVoC) BOMB ID:3 ccv-0r 2006-3 ccv-0t2606-3 ccv-Or 3106-3 ccv-020606-3 ccv-021,506-3 ccv-022306-3 ccv-022406-3 ccv-022806-3 ccv-030106-3 ccv-030306-3 0U20106 0U26106 01/3 U06 02106106 021r5/06 02123106 02124106 02128106 03/01t06 03/03106 2394.1599 239s.4889 2392.7 402 2385.687 4 2395.5445 2396j97 4 2392.601s 2391 .9179 2394.2703 2393.s498 u gtton EC a,n Calorimeter Sample ID Calibration Date EE (calfC) ICAL Mean EE (calfC) ,D (%) ccv-030306-3 03103106 2393.5498 2393.2158 0.0% Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-'WC-0010 Bomb Calorimeter Data Worksheet Revision I September 9, 2003 -rr.td t / to/o(2 9/8/2005 7:15 AM 462 STL Knoxville sampleID3 ccY- otzoo6 -7 Work Order Number: r' AualysisDate: ot/zo/ob Std. or Determination? 5+d Analyst: JprH Gross Heat of Combustion (caVg): Gross Heat of Combustion (Btu/Ib): Bomb Colorimeter Data Report HoC Drte Worksheet Revision 2 092203.x1s Tcmphle Appendix F - 461 Page I Fe r r l ibE tl.= I ,:,1- i rne t.e r F18,.,,, Et5!1Uli' -.:t3?:Il:55Unit # L:]pi 1 .,. .? p1 ,, I t:r [:1 E, ['l,]de l 5 t end.3 rd i =.= t.i ,:n [,leth,r,J: [.'gnarni,: TUF*: Finel Sarnple ID 1B hleight, 1. 131371 E,:'rnE, IF f, EE Uslue ?3?4. 1599 5p i t,.e [,],It-r t [t . Elt]H[J Fr-rEe 15. t3fi[il:l llcid 1ff.t]!f,t:l Sultr-rr [t,BEttltit Init. T*rnp :1.filrti T*nrp. E:i=e LEEE1 .J.=,: [':* 1 T J[3, t]tj75 tj rr'=E He; t Et. t3[1fi8 i-.J I ;' U 463 STL Kuoxville Sample IDr Work Order Number: Analysis Date: Bornb Calorirneter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-\ryC-0010 ccv - 0rz6 ob - 3 ,ltc /ob Std. or Determination? 4+l Analyst;.trrtl Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Calorimeter Data Report F.=rr 1lb6 tI: =lurini*t.er E:Er,', r:rillErl-lnit # tl r3l,,IE,,![rr]6 1t:4I:rIrI I'l'--'de I 5 t.=nd.= rd i =e t.i ,rn f'le t hnd: [:rgn.=rri i rr TUF,* I F i n.a I Sample ID l9 lrlei,Ih t 1 , r:lEli E,:rnb IIi 3 EE Ua1ue 23g5.48gg :lp i ke Lilgh t fi . EtitEt:l Fr_r=s, 1 i. B6rll::iF,:id ltjt.lt:ltt 5u1tur rl,rltBr..ir:=r I n i t . Tenip II . 1:I: Terrrp. F:i se I. ar,-l1 .Iar k* t. T itl, tSLlIE tJ r,l== He.r t. E. EBIIE rlE l,-e Bomb Calorirneter Data Worksheet Revision I September 9,2003 Jntl lzr{o6 9/8/2005 7:16 AMHoC Drla Worksheet Revision 2 092203.x1s Tcrnplrte Appendix F - 462 Page I 464 o STL Knoxville Sample ID: Work Order Number: Analysis Date: Std. or Determination? Analyst: HoC Drta Worksheet Revision 2 092203.x1s Tcmphte Gross Heat of Combustion (caUg): Gross Heat of Combustion (BtuAb): Bomb Calorimeter Data Report Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-\ryC-0010 ccv- or3lob -t rl ltlob 6+d Jxl,l Appendix F - 163 Page I Bomb Calorimeter Data Worksheet Revision I September 9, 2003 Jarl t/tt/oo 9/8/2005 7:16 AM F.=rf 13Eb tI: =1,:'firrr*tBf F:E,..,. EII1fi'1 11: lil: itl-lnit. # E tit1,"f,1,,ltlrltf, I'l':de ; 5 t-.=nd.= r'd i =.= t i nn |.'1* t t-n:"J: [ignani i,: f Upe: F i n.= I Sample ID ?B l!il*ight 1. t]tli.? EnmE, Iti f, EE Ualue ?392.746? :ip i lle lrlgh t. tJ . EtSEt] Fus* 1 iJ . tit -lEtltF':id lE. 1I5i 5ulfur tIt.tStI*ItEi I n i t , T*nip :: , I[:158, Tenip. F:i ::E :. E,!E'? ,-IE,: [,.e t T 3t]. ul1 1E tj r-n== Hea t. t-t , EtltlB ce I'"'J 465 STL Knoxville Bornb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-1ryC-0010 Sample ID: ccv - oz obab - ! Work Order Number: -. Analysis Date: _il_9l"6 Std. or Determinatiou? 5+l Analyst: Jr*H Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Calorimeter Data Report F .3 r- r- 1 It-,E [.a I r]r t- i ni* t.* r Fler.r . 85i 1 l:t! Llnif # -1 Bl.,'fif,,-'IrlrrirE 1rl;15:4i I'I,:de ; 5t.=nda rd i =.e t i *n ['l* t l-r,:,J: [:,qrrarrr i r: TUps: F i rr.= I 5ampl e ID 2l hle i Bl-,t El . ?t4.f Er:'ruh i tt f, EE Usl ue 2385. 5874 lp i ke t'J,;h t 13. fiE'r-1E Fr-r=e 14 . EUt:lE tl,:id '3..38f,4 5ulfr_rr _-t.[ttittstlt I n i t . T*nip ItIt, 9!55 T*nip , Fj i se :. h4f,i .-Te': l:.p t. T I'3. 'J']f I tj r*== He.= t. t-i . [ttjr]L;t c.a I .-,1 Bornb Calor irneter Data Worksheet Revision I September 9, 2003 J,4r, ?{./4 9/8/2005 7:1 6 AMHoC Dota Worksheet Revision 2 092203.x1s Tcrnphte Appendix F - 464 Page I 466 STL Knoxville Bomb Calorimeter Data Worksheet Revision I September 9,2003 Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per sop KNox-wc-0010, y*l 4il,{" Sample lDz CCV - o?tf,ob - 3 lVork Order Number:n)/h Anatysis Datei ,,0a. / tS.Ie A .. ._.. Std. or Determination? S+dl , _WAnalyst: Gross Heat of Combustion (caUg'1, , - , -il I t Gross Heat of Combustion @tunb) , Bomb Calorimeter Dato Report Appendix F - P,ggl 2t15t2006 3:48 PMHoC Data Worksheet Revision 2 092203 Ternplate Fa r r- I iht, tl:.= I rrr r- i nie t e i-F',=,r r f5:1tl: 14: 5r,: 4ljl-lnit # -i [t'J.,'I 5..,f -iEE I'1,:de : 5 t.=n,J.a rd i =e t.i ,--irr f,1e t h,:'l: [:'gnanr i ,: TUF,e: Sarnp I e IB ?? r.,fe i ,1h t Ec,rnL, I [i f, EE UaI ue 5p i lre L,lgh t t]t. ltEtltit Fr-rge Ftcid irl.lj.151i Er_rltrrr I rr i t . f *rrip JI . 47rlE Tenip. F.:i =e.Jec lre t. f JE. t:lUi4 6 ]-r:r=:= Hea t FinaI 1 . EBIT 2395.5445 i8. ritBrlu 13. rlrrjrlrl '-r J BE- a.] . l],.-l-t i li. Ull::iBtl ':EIrq 467 STL Knoxville Sample ID: Work Order Number: Analysis Date: Std. or Determination? HoC Drla Worksheel Revision 2 092203.x1s Tcmphle Bornb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-1ryC-O0I0 4CV- 022106 - 3 . z/?z(?q .-- _ 5H Bomb Calorirneter Data Worksheet Revision I September 9, 2003 )Ntqzt/* 9t8t200s 7:16 AM Analyst:Jxtl Gross Heat of Combustion (caVg): Gross Heat of Cornbustion (Btu/Ib): Bomb Calorimeter Dala Reporl F'.=r-r- 1'l'E-,F, rI:-=lnrin'rpt.Er- ElE,,.r. rlrrlrjrfUnit # U rlI-.'':3.."irIBE rlE:4rli;Ig f'.|,:de : :l t.=nd.= rd i =.E t i ,in i'1e t.hnd: [rgrr.:rrr i': TUF,e : F i n.g ISanrple Tb ?S til*i gh t. tt. ,_t!I4 Eunih' Itj .i EE Ualue Zig6. lgf4 5p i lre !.ilqh t. rI . EErrlrl Fr_rE* I f.. _-rr:r[rrl Fl,: i ,J !. '37iE 5u I i u r- rl. EE*:rEIrrit, T*nip I:,tlt11? Trrrip. F:i=,: i.E,f,I+ .J.=,: lre t T rF . '-??'-]4 ri rnsg H,=.= t rl. ErlEr --r ':.3 J .,",J Appendix F - 466 Page I Bomb Calorimeter Data Worksheet Revision I September 9,20A3 Jtut H z/zt /* 9/8/2005 7:15 AM 468 STL Knoxville Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-'WC-0010 Sample ID: ccv - 022406 -, Work Order Number: - Analysis Date: 314+ lou Std. or Determination? Sird Analyst: _____4tl Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Calorimeter Data Report Fer-r 1rEE rl.=lc'rirn*t.er Fi*r..,. rlr:113: Lfrri t. # D Ei,"I4,.,IErlE rtr,_i: EE: :,i I'lnd* : 5 t..=nd; rd i zE t.i ,:,n f'l* th,:d: [runani i ,: TtJp* ! Fi n.= ]SampleID 24 tJEi,lht l.rllE,l Ec,nrE, I ti I EE Ua I ue ?SgZ . EB I s ;1p i ll* lrleh t rl, E*3Er-l Fu=:e 1 I , TJEL,EIlcid l[.::jtj 5u]{ur E.rIuIrlE I n i t . T*nip II, f,4 !I Tenip, F:i E* i , fifi 1 J.r,: li* t T jr:l. rltl1 rI E ros= H*.r t. [r. EEr]rl ,:a 1,'g HoC Data Worksheet Revision 2 092203.x1s Tcmphle Appendix F - 467 Page I 469 STL Knoxville Sample ID: Work Order Number: Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-\ryC-0010 Bomb Calorimeter Data Worksheet Revision I September 9,2003 ..Jx,J /n/ao 9/8/200s 7:16 AM Analysis Date: Std, or Deterrnination? Analyst: HoC Dala Worksheet Revision 2 092203.x1s Tcmplete Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Calorimeter Data Reporl " lz0 /oo *d JIAH Appendix F 468 Page I P.r r r 1:t,b l-:.= I rr, r i rne t.e r F.:8r..,,[15:1t:1! 1 .l: t:lfi: 1 iUnit # rJ Eri.rIE,,IrIrEE, l'ln,Je : 5 t..=ndE rd i =.= t i,:,rr l,Ie t h,:,'J: [ign.=rri i,: f gpe; F i n.= I Sample ID S trt* i gh r. I , [r t ui E,irnh I E) f, EE LraI ue tsgl . glTg :{p i l':* l.{gh t E . r:rrlrlE FuEe I i,, rlBErEll,:i'J ltl.l.fl:r[ 5r_rlfur E.r:lr;1jr6Init'. Terrip :1.'3184 T*rrip. Fji=:E :.t'iEr:-rt .I.3,: [r* t T l,_]. I'_+g: rj r,:== H*e t. [r . lSBEt-i ca I ..-q 470 STL Knoxville Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP I(NOX-'WC-0010 Sample ID; ccV - o?o I o5 - 3 Work Order Number! - Analysis Date: - il_, / o! Std. or Determination? 5+ADetermination? 5+A Analyst: _ _{r^! Gross Heat of Combustion (caUg): Gross Heat of Cornbustion (Btu/lb): Bomb Calorimeter Dsta Report F'.:r-r- 1:hE, rl:;]arirxgtFr- F,:8,...,, ,L-rI?LE: Unit # rJ Ei,.'l:-rl.,tr0rlfi 14:11:-t;:,1 I'l'--,dr : 5 t and = r-d i =.= t. i r:rn ['1e t.h':d: [:,Ungrri i r: TUF,* : F i n.= 1Sarnple ID ?b l.rl*ight 1. [11.;,I E':,nih I tr f, EE Ua1ue ?S94. ZfEs 5p i tre l.rl,Il-, t. Et. rlrUiritrl FuEr L I. fl3r3rlll,-id lr]r. l+iu 5urlfr-rr r]r,rlErlrrlr I n i t " Tenip ':i. 4It,I Terrip, Fli =e :, t,E:.f 'Jac lre t T Jt]. rlrjf, 1 G r,:,s:: Hs.: t Li . l3lirlrrrr ,:.31 ",J Bornb Calorimeter Data Worksheet Revision I Septernber 9,2A03 Jrt{ 3/z / oL 9/8/2005 7:tE AMHoC Data Worksheet_Revision 2_092203.x|s Tcmphle Appendix F - 469 Page 1 STL Knoxville 47 I Bomb Calorimeter Data Worksheet Revision I September 9, 20A3 Jrt H o/s/ob 9t9t2005 7:16 AM Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-WC-00I0 Sample ID: ecv - o3o3ob - 3 Work Order Number: - Analysis Date: ___?J2I "b Std. or Determination? b+a Analyst: JPrx Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/Ib): Bomb Colorimeler Dsta Report P.arr 1?b6 tlat,rriroetpr Eer.,. ErS!1AI Un i t * t3 B3.t13rIABts 1i: 4n: 14 l'lode: 5t.=ndardi ze t i on I'le thod: Dgnanr i c TUF e: F i n.a I Saryle ID 27 tJei ghi I . ErrlBg Bonrb IB 5 EE Ualue ZS9S. HgB Spi tle tlght. B. BBBEI Fuse lf .0BBBRcid 18. A33t 5uI f ur E. BEBA I n i t., Temp !?, 3?E? Tenip , R i se ?. t ESEr Jaclret T 38.8116 Gras= Heat E.0EgB cE I ,'g HoC Orta Worksheet Revision 2 092203,x|s Tunphte Appendix F - 470 Page I 472 STL Knoxville Calorimeter Calibration Worksheet Revision 0 Calorimeter Calibration worksheet 8128103 Determination of Energy Equivalent (EE) per SOP KNOX-WC-0010 3/3/2006 3:13 PMCalorimeter Calibration Worksheet 030306 CCV.Bomb 4.xlsremplate Appel$il F - 47 1 Initial Calibration Data Calorimeter Sample II) Mean EE BOMB ID:4 ccv-012006-4 ccv-O12606-4 ccv-013106-4 ccv-020606-4 ccv-021506-4 ccv-022306-4 ccv-022406-4 ccv-022906-4 ccv-030106-4 ccv-0303 06-4 0t/20106 au26l06 01/3 UA6 02/06106 02lts106 02123106 02t24t06 02128/06 03/01/06 03/03106 2385.7669 2388.0110 2387.5005 2385 .4547 2395.0385 2390.6415 2382.9790 2386.8547 2396.8906 2392,3497 2387.1477 Cslibration Check Standard Calorimeter Sarnple ID ICAL Mean EE (calfC) ccv-030306-4 B/$la6 2392,3497 2387.1477 473 STL Knoxville Sample ID: Work Order Number: Analysis Date: Std. or Determination? Analyst: HoC Drte Worksheel Revision 2 092203 x|s Tcmplele Gross Heat of Combustion (caUg): Gross Heat of Combustiou (Btu/Ib): Bomb Calorimeter Data Report Bomb Calorirneter Data Worksheet Measurernent of Heat of Combustion per SOP KNOX-'WC-0010 ccV- ot 2oo6- + or/zo/ob 5?A JMff Appendix F - 472 Page I Bomb Calorimeter Data Worksheet Revision I September 9, 2003 Jnt{ ,/zn/tL 9/8/2005 7:16 AM PErr 1ir:.b t]:.e1,:rirrietpr F,:P'...,.r=rII l rlt [r!: .]E: 1r,Unit # t:t t:f 1,rltit,'I[tttrE, ['1,f ,J*: 5 t and.= rd i =e t.i'in [']* t.l-rad: [iqn.=ni i c TUF,e: F i ne 1 Sample ID 5S lrlpi'lhr. l.LJ1BI E,:rnh lti + EE tialue 25B5.fGEg 5p i tl* [,Jr1l-r t E . EEtUltf Fu=e 18. t1l]rr-:-rrjr ticid lE. ll1f 5ul f ur E. ffEBrIr Init., Tenip I1.tl[tft, Terrip. F:i=:E i.r,iliE -T.i,: k* t. T IF. !,jEE, tf rn== Hea t rI. t-rrlrlrrl r:.3 I r'-,J STL Knoxville Sample ID: Work Order Numberl Analysis Datel Std. or Deterrnination ? Analyst: HoC Drta Worksheet Revision 2 092203 x|s Tanphle Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX'\ryC-0010 ccv - o tl6ob - 4 r/26(ob 5+d Jpil Appendix F - 473 Page I Bomb Calorimeter Data Worksheet Revision I Septernber 9, 2003 Jrll r l*/ot 9/8n005 7:16 AM 41 4 Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/tb): Bomb Calorimeter Data Report Farr lItt t-:.=Irrrrirnet.er F.:*r.r. rlSIltII Unit. # E El1,'!i,..'Itjttlr. 11:51:litt] l'lode; 5 t and.s rd i =.= t.i,:'n ['lptl-rtr'd: [ign.erriic TUF,*: Firrsl Sample ID 69 l.ile i,lh t E. '37:i4 E,:rrih I[j 4 EE Lralue 2388. Bl tB 5p'i tl* tJght D, tStlEE Fu=:e 11. UlEr:lB 11,: i,J '-i . i,J.ii 5u I t U r E. LSBEE Init. Tenip :?.1I4'-1 Tenrp. Ei=e :.5?fI .Jsc ke t. T I'-f . 'J.J4'-;t ti rn== He.3 t u.i. [tEt-:tE1 ,-a I r",] 475 STL Knoxville Sample ID: Work Order Number: Analysis Date: Std. or Deterrnination? Analyst: HoC Drta Worksheet Revision 2 092203.xts Tampble Gross Heat of Combustion (caUg): Gross lleat of Combustion (Btu/lb): Bornb Calorimeter Data Report Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-1ryC-0010 CcV -olllob ' + I ltt lob 5ra Jnrt Appendix F - 474 Page I Bomb Calorimeter Data Worksheet Revision I September 9, 2003 Jntl t/a/oe 9/8/2005 7:16 AM Fe r r 1:Et, tI:= I,rr I- i nie t e r't:er..'. fi!: L -ii 11: ltjt: f 1l-lnit.# [ ['1,:'Je : 5 t errdE rd i r.= t.i ']n I'lE t.hc'd: [:'gnani i ,: TUF s : F i rr.= I Sanrpl e It, 78 lrle i ,lh t. 1 , 81 ':ri, E,:rnh Ili 4 EE Ualu* 2387.5885 :1pi[;,= t'Jght if,Etitt]t] Fu'se IE,tlt:ttltt fi,:i,J 1t]t.i1'-15 5r_rl{ur U.L-tt_I0tIr I n i t . Tenip I:, 145F Tenrp. F,:i::E j. iLjl:]1 .J.=,:[::xt. T :!.:?E':14 tjr,l=:s H*.3t t3.r3r3U1[r t--J 1 ,' U 476 STL Knoxville Sample ID: Work Order Number: Analysis Date: Std. or Determination? Analyst: HoC Dria Worksheel Revision 2 092203.x1s Tcmplrlo Bornb Calorimeter Data \ilorksheet Measurement of Heat of Combustion per SOP KNOX-WC'0010 eCV -1Zgbob*+ z/ b /"b 5+d JtaFl Appendix F 475 Page I Bomb Calor imeter Data Worksheet Revision I September 9, 2003 JxH z/4 /oe Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Calorimeter Data Report F .3 r r I IE,E l-..i I,: r- i nie t.e r F.:8,,.,. II15I1tJI l_ln i t. # t] fi2..,r]E,..IB[18, 1 lS: i.]: 4f I'1':,'J6,: :l t an,J,= rd i =.= t. i ,rn l'leth*dl [igneniic TUF,et Finel Sample ID 7l tJ*i'lht 1 , [3818 E,:nih' Iti 4 EE Ualue ?385.4547 5p i tl* t'J,;h t tjt. ttttlttl.i Fu=e 1f . [rr:rEr] Ftcid 1r1.8f,5 1 Sultur Er,rjrtlrSEi I n i t . T*nip ?Et. t:tHlE Terrip. F:i =e i. hE^:,-5 J.=c [;s t T I'-?, '-i'.]7i tj r,:,== Hf A t E. fiEEil:i ,:.31 ,',f o 477 STL Knoxville Bomb Calorimeter Data Worksheet Revision I September 9,2003 Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-WC-0010, nevp I SampleID ,..(,.?{ ^ bet{06'* $O-Work Order Number: p I ft Analysis Date: (tX I t dl o Std. or Determination? S Analyst: Gross Heat of Combustion (caUg): N hf Gross Heat of Combustion (BtuAb): P t f( Bomb Cslorimeter Data Report Ferr lIEt, tl:.=lnrinietsr Unit. # B LlI..'15,'Irlr:18 ['I,:,dp: 5 t..3nda r,J i =.= t.i on EE,r..,. t35! 1 tr: 1I: IJI'J: EI ['1e t.l-rc,d: [tqnarn i': TUF'e : F i n.3 I Sample ID 7? trlright 1.Li15'3 E,rnrh It: 4 EE Ualue 2385.4585 5p i k* tJgh t. tl , t-*'t[tt]t Fu=e 1 1., BEt:tEl H,=i,J 18. 1i4h 5ulfur E,EBrjrEr Init. Tenip, !:.51i'3 T*nip. Eli=* f.7t:18t1 .-f .3'; l::* t. T ;Ilf . IJBf,4 E r':,== Hee t E , t:iti1Erl3 ,:-= 1 ,",J HoC Data Worksheet Revision 2 092203 Ternplate Appendix F - P^€Jf 211512006 3:48 PM 478 STL Knoxville Sample ID: Work Order Number: Analysis Date: Std. or l)etermination? HoC Dela Wortsheet Revision 2 092203 xls Tcmplrte Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-\ryC-0010 CoY - 0zzr 06 - rl Bomb Calorimeter Data Worksheet Revision I September 9, 2001 JxH t/zt/o6 z/zt /ot 5+d Analyst:.J^,tH Gross Heat of Combustion (caVg): Gross Heat of Cornbustion (Btu/tb): Bomb Colorimeler Data Report Appendix F - 477 Page I 9/8/2005 7:16 AM F.= r r- 1:frL, tI:.= 1,r, t- i rne t.e r E:P,.,.,. [tII1t-1'] l.{ r_r r -.1 r-t r ,: ut:-l r_r I rl. r_r i ._: -.,Unit # tJ tIJ,'! j,-'Ir:tfiE I'lt',J* : 5 t.and; r-d i =a t. i ,:rr I'le t.h*rj : [!grr.3ni i ,- Tqp*: F i n.= I Sanrple fi) 73 lrle i']h t I . t:1[4f E,:rrrh I [, 4 EE Ualue 2398.641s -ip i [':E [,.1,f l-r t E. litEtt=ttJt Fr-r=* I i , EUI:IIJ t-1,:iC 18.l:1fl1 Suliurr tit.ftt]ttlljt Irrit.. T*rnp :1.'345I T*rnp,. F:i=* !,EEE,{' .J.=,: [::e t. T Jtf , titt]r"j tj r,:== He.= t. -1. l.1t:1[El ,:.3 I .',J 479 STL Knoxville Bomb Calorimeter Data Worksheet Measurernent of Heat of Combustion per SOP KNOX-!YC-0010 Sarnple ID z ,*9{ -o??!* -, * Work Order Number: '' z/z* tobAnalysis Date: Std. or Deterrnination ? Analyst: HoC Orta Worksheet Revision 2 092203.x1s Tcmphte Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Calorimeter Dato Report Bomb Calorimeter Data Worksheet Revision I September 9, 2003 tuH zlzt/oL 5+d rhr lt O Appendix F - 478 Page I Pe r- r 1 :E d, r-:.:1 ,i r i rlrE t.* r-F.'E,J.85:1tJ: t:t'31 t .I: 57Llnit # A riI,'14,'IErrjrE I''lc'de: 5 t.=nd.= rd i =.= t.i on ['l* t hnd: [ign.=ni i ,= TUF,p: F i rra I Sample ID 14 tJei,lht 1 , EttrE! E,:nrh I tr 4 EE Ualue ?SSZ. gpgB 5p i tre trl,rh t- rlr, E+:rrll3 Fr-rEe 1 i . Errglrlficid lE,tlf,iE 5u]fur fi.r]rrSttr:l I n i t , TernE, Ii, 5f,4] Trnrp. F:i =:E i. hi.4E J.:c k* t T 15, FIti I rJ r-,:,E= l-l*a t r] BrlEEl ,:e 1..'g Bornb Calorimeter Data Worksheet Measurement of Heat of Cornbustion per SOP KNOX-\ryC-0010 Bomb Calorimeter Data Worksheet Revision I September 9, 2003 Jnrl zltt/o6 9/8/2005 7:16 AM 480 STL Knoxville Sample ID: _ _ Work Order Nurnber: - Analysis Date: t fzslob Std. or Determination? ,+d Analyst: _ Jltl Gross Heat of Combustion (Btullb): Bomb Calorimeter Dota Report O HoC Drta Worksheel_Revis ion 2 _092?03.xls Tcmplete Appendix F - 419 Page I Parr 1If'E tl..=1,:rirriet*r F.:P,.,,.lJ5:113: 1f,: t:lll: i5Llnit # rl tlii'I:j,-'IrlrlrE, [''l':'rJE: 5 t.en'J.l r-,J i r.= t.i,:rr |.,1* t.h,:,d: [:,qneni i ,: Tgp*: F i n.i I Sarnpl e ID 75 lile i ,3h t Er. .3.3f,I E,rftit, I ti 4 EE Ual ue ?385. 8547 5p i ke [,Jql-r t. tit . ftt:tEt[t FuEe lE . -lEr:tE ll,: i d !, '35',ii :lu l t tr r rl, rlEljrfi Init., T*rrip, I1,Ft:tf,r,T*rnp. Flige :,8,4t:1f .-T.i,: lle t T I! , F'Jij.3 rj r-,:=s H*e t. U , ErBrlrl ,=.3I r'E 487 STL Knoxville Sample ID: tilork Order Number: Bomb Calorimeter Data Worksheet Revision I September 9, 2003 Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP IffOX-\ryC-0010 ccv -o!0to6 -+ Analysis Date: Std. or Determination? Analyst: HoC Data Worksheet Revision 2 092203.x1s Tcmplrte ,/r/ob 5yd JrrH o Gross Heat of Cornbustion (caUg): Gross Heat of Cornbustion (Btu/lb)l Bomb Calorimeter Dila Report F'.3rr lihh u.=l,irinret.er F:er;. Et5:lljr! l-lnit # r:l fi3..r11,-'IrlrlrE 14:iE,t41 ['l'i,Je : 5 t..and.= r,J i =.= t i,=n ['1* t.l-r':,J: [igrrani i r: TUF e: F i na I SampleID 76 lil*i,lht 1.Bl:iEI E':nih Iti 4 EE Ualue 2386,8885 -iFilte I'J']l-rt t:l .tl[-1[.18 Fu=* 1i.t:tt:tt:tt:t tJci'J iE.1tlil 5ulfur tlt .fiEr:ltl I rri t.. Tenip :J . 41 :::3 Tenip. F: i =:E ! . El-itlEl .J.=,: tre t. T i -J . EEB4 ti rn=s He.i t rrr. LIEEE ,:E 1..''q Jmtl a1z/o6 Appendix F - 480 Page I 9/8/2005 7:16 AM 482 STL Knoxville Bornb Calorimeter Data Worksheet Measurement of Heat of Cornbustion per SOP KNOX-WC-0010 Sample ID: CcV- o?0306 - t Work Order Nurnber: - AnalysisDate: I//"6 Std. or Determination? 5+d Analyst3 rnt{ Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btullb): Bomb Calorimeter Dara Report Parr 1?b6 Dalo rinreter Reu. ErSIl t:t3 Unit # 0 83,'83,,?806 13:54:IF I'lodp; 5tanda rdi=a t i on l'let,hod; Dgnanric THF,e: Final Sample ID 77 lrleight I, BBB4 Bornb IF 4 EE Ualte Z3g2. S4gZ 5p i k* trlgh t A, BBBE FuEe I 7. BB0B Hcid 18. 1 191 5ul iur B. EBEE Ini t, Tenrp ?2. ?138 Ternp, Eise ?.67f 1 .Tsc ke t T 3Et . BEIS G ros= Hee t A. BBBI3 tre l,,g Bomb Calorirneter Data Worksheet Revision I September 9,2003 JsJ{ {c/oe 9/8/2005 7:16 AMHoC Drta Worksheet Revision 2 092203.x1s Tcmphle Appendix F - 481 Page I 483 STL Knoxville Calorimeter Cal ibration Worksheet Revision 0 8t28/03 Calorimeter Calibration Worksheet Determination of Energy Equivalent @E) per SOP KNOX-WC-0010 Initial Calibration Data Calorimeter Sample tD BOMB ID=3 ccv-O1260 6-3 ccv-o13106-3 ccv-020606-3 ccv-021506-3 ccv-022306-3 ccv-022406-3 ccv-022806-3 ccv-030106-3 ccv-030306-3 ccv-030606-3 0U26106 0l/3 U06 02106106 021r5/06 02t23t06 02t24106 0u2ua6 03/01106 03/03/06 03106106 2395.4989 2392.7402 2385,6874 2395.5445 2396.7974 2392.6015 2391 .9179 2394.2703 2393.5498 2392.3217 2393.0320 Calibration Check Standard Calorimeter Sample ID ccv-030606-3 03t06106 2392.3217 2393.0320 3/6/2006 8:21 AMCalorimeter Calibration Worksheet 030606 CCV.Bomb 3,xls Template AffidixF - 482 484 STL Knoxville Sample ID: lVork Order Number: Analysis Date: Std, or Determination? Analyst: Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX'\ryC-0010 ccv - 0rz6 ob - 3 'lu'/ob 5+l *trerl Appendix F 483 Page I Bomb Calorimeter Data Worksheet Revision I September 9,2A03 J,l,t{ r/ztlo6 9/8/2005 7:16 AM Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Calorimeter Dots Reporl FErr 1IhE tlaIorirrieter- E:er.r. [jtII1rjr: Unit # B ul..'!b....'I[tEb 11:4i:rIrI ['1,:'J* : 5 tendar,Ji =a t i nn [,1e t.l-rnd I [,gn.irn i ,: TUF,g ! F i n.= 1 Semp le I D 19 Lrl* i st'r t. 1 . rirE7i Eonih I ti f, EE Ualue ZS9S.4BB9 5pi[':e I'lght E.IIELIE Fu=.e If.r3Br:tFtl,:id tE. lr:riI 5ul{ur- E.E=rrlf:-rl:r Ini t, Tenrp 'Ji. liII T*nip. F:iEe !. i,E!I Ja,: lre t f SrIt, Btlf,r, 13 r,=== Hea t tI. fil:]rlrl ,-.3I ,'E l l l i I I I I I I I I I I HoC Drta Wortsheet Tcmpbte Revision 2 092203.x|s 485 o STL Knoxville Sample ID: Work Order Number: Analysis Date: Std. or Determination? Analyst: Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-\ryC-0010 CCV- OtSlob - 3 rllrlob 6+d Jxl,l Appendix F - 484 Page 1 Bornb Calorimeter Data Worksheet Revision I September 9,2003 Jrrrl t/tt/tb Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Calorimeter Dota Report F=r'f 1'lf,t' tI:.:1rI,t-ifnrt*f F;B'.,,. [t5ittl: Unit # tI 81,''i1...'ItIErE, 11:tir1:I'I I'1i,d* : 5 t..aruj.= rd i =.= t i':n fiet.l-rtr'd: [iqrrsnric fUF,e: Fin.EI 9ample ID ?B hlr i gh t 1 . llt 1i.'.1 E,:,trih, I[i 3 EE Ualue ?392.7482 :lpike l,,l'lht. E.tltlttlE Fr-r=e lE,l]rtlrEuir fi,:i,J lfi,1'J5i 5r-rltur Ei ,tl-itll]t I rr i t . Ternp I-*. ItJSh T,=nip. F.:i =* ':. t,:18,'.il .T.s,: ['.8 t. f jE , l:t I L n tj rn== H*.= t. t] . EEEE ,:,3 I,'',I HoC Drta Worksheet Tanphte Revision 2 092203 xls 486 O STL Knoxville Sample ID: Work Order Number: Analysis Date: Std. or Deterrnination? Analyst: HoC Data Worksheet_Revision 2_092203 xls Tcrnphle Bornb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-WC-0010 ccv-Qzo^ab-) z/ o/ob 5+A JpH Appendix F - 485 Page I Bornb Calorimeter Data Worksheet Revision I September 9, 2003 Jflt, {e/4 9/8/2005 7:16 AM Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Calorimeler Dato Report F'err' liEi tl:.aIrr'r'inirtsr F.:*,..r. E5ilEi Unit.# tJ titir'tli,.'Il]ttlr:, ltlt:15:4I li,:dE r 5 t.end.E rd i =s t.i,rn ['let.l-rad: [rgn.=nii,: Tgp,e: Fin.rl Sample ID ?l t]ri ght t:t. .]'-14f, E,=nih I ii f, EE Ugl ue 2585, 6874 5F,i h:s l.,J,Ih t. tl, Ultltittl Fr-rEe I 4 . BBtitE H,=id '-1..j8.14 :'ultr-tr }].t..:l[:18[1 I n i t. , Terrip ltl. !I:'5 TEnrp,. Fl i =e i . b4f,',1 .Jec lre t. T I'J. ,3!i5 E r,:'EE He.= t. t]. ftEt]tlt l--J 1., u 487 STL Knoxville Bomb Calorimeter Data Worksheet Revision 1 Septernber 9,2003 Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per sop KNox-wc-ooto, y*( 4r1{" Sample lD: CCV - oAtfob - 3 Work Order Number:N/h Analysis Date: .0t / t{l eA Std. or Determination? 5+,[- Analyst:>ay Gross Heat of Combustion (caUg) , - ,,.[) ft ,, Gross Heat of Combustion @tu/lAy Bomb Calorimeter Data Report Appendix F - putt6r 2t15t7006 3:48 PMHoC Data Worksheet Revision 2 092203 Template F.=rr- 1IEh tl:.e1':ri[riptFi'F'.=r r [5! 1 fii l4: 5i: 4rll-fnit # tJ titI.., 1 5..,,-:g[:18 I'],:d*: 5 t..and.r rd i =a t. i ,rn f'le thc,,J: [iunrni i c Tgpe: Samp le I D ?? l.rlr i '_f Fr t Ec,nih IIi i EE Uatue 5F,i llr t,J,lh t t]. [[IEE Fr-r=e F,:id 1t3,t:t51! 5r-rl{r-rr I n i t . T*rrip i:'. 47tJE Tenip. F.:i =eJa,- l:* t T 3t3 . -1fi!4 G r,i== Hea t Fin;1 I.. EB'1.,! 2595.5445 ![t. E[t[tE 11. EBBE .-r .'- gE- .d. . E,-l_l t' B. ,lrlrIrE r:.31-r',J 4BB STL Knoxville Sample ID: Work Order Nurnberr Analysis Date: Std. or Determination? Analyst: HoC Drta Worksheet Revision 2 092203.xts Tcmphte Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-'WC-0010 ccv- ozeloe - 3 _ ..,?LLr(o,q _,_.,.., - S.lrd -luH Appendix F - 487 Page I Bomb Calorimeter Data Worksheet Rev ision I September 9, 2003 J$4 42y'e 9/8/2005 7:16 AM Gross Heat of Combustion (caUg): Gross Heat of Cornbustion (Btu/lb): Bomb Calorimeter Data Report F'.3r-r 1rEfi [..r1r]r rirn*t.Er ElE,.r. rlr:,1[:rl Llni t. # tlt L,il.''ii'irlrjrr, r:rg:4r:f : l _l I'l':'Je: _i t.=nd.= r-,J i =.E t.i nnI'letl-r*dl [igrreniir TUF,*: Fin.=I Sarople IO ZJ [,.|*i,Jh t, ' E. ,3!I+ E':rnt, Ili I EE Ualue ZigG. l?f4 5p i tle [r.l,3t-i t. E . t]tlfiE Fu=e 1E, , ErlElEti,:i'J ?.'37f8, 5ultur ll.l:rL=rrl[r I rr i t , T*nip ,J: , r:11 1,-l ferrip. Fl i =e I. hf,I4 .J.=c ['..= t f i5. 'J'j'-j4 li r-,:,=E He = t. E. [rrrE _l r:e I.,'rl 489 STL Knoxville Sample ID: Work Order Numberl Analysis Date: Std. or Determination? HoC Drta Wortsheet Revision 2 Tcmphte Bornb Calorirneter Data Worksheet Measurernent of Heat of Combustion per SOP KNOX-\ryC-0010 ccv- 0224/,6-> 2/z+ I ou 5H Analyst:Jrr d Bomb Calorimeter Data Worksheet Revision I September 9, 2003 J^lH zlzz /oo 9t8t2005 7:16 AM Gross Heat of Cornbustion (caVg): Gross Heat of Combustiou (Btu/lb): Bomb Calorimeter Data Report Appendix F - 488 Page I F'Err lIEE t-:.itr,rinir=t.*r Fler.r. t15! l rjr! t:1,]: U15: Iil-lnit # [r tjlI'' f 4,'Jk1l3{, I'1,;,rJp ; 5 t.and.E rd i =; t.i,:n ['le t hnd I [:,gneni i,: TUF,* ! F i na ISample ID ?4 trteighr 1,8161 E,:rnh' I [:, f, EE Ual ue ?SgZ. 6BlF 5p i lle l.,lgh t [r, urSr]rE Fu=s 1 L r:rErSrl tl,: i ,J 1 t3 . IE2,-l :lu I { u r- rl. tjgrlg I rri t, Tenip ?I f,4'_1,3 T*nip, F.:i =e :, . f iE 1 .-T.=': k* t T ikf . fil:r 1 rI ri r,i::= H*E t Er. rlrlBrl r:E I .r''f 092203.x1s 490 STL Knoxville HoC Drta Worksheet_Revision 2_092203. xls Tcmphlo \ Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per soP KNOX-\ryC-0010 Bomb Calorimeter Data Worksheet Revision I September 9,2003 .Jrtd lx/oo 9/8/2005 7:16 AM Sample ID i CcY - oLZSob -, Work Order Numben - Analysis Date: 2 li| lob Std. or Deterrnination? t+d Analyst: ____ JUH Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btullb): Bomb Colorimeler Dsta Report aD Appendix F - 489 Page I F Err- Iihh rI:=1tr,r-irugt.er F',=, ,t..r_ .-. .r35i l ui 1f, I tItE: 1iUnit # rJ ['Ir',Je : 5 t anda rd i =a t. i':,nf,Iet.hr,,J: [rgn.sniic TUF,e: Fin.=l Sample ID 25 tile i r;h t 1 , [-r 1EiEoniL'Iir 3EEUa1ue ?Sgl.g17g :Ip i lle f.il'Ih t. rI. rlrlr:lr:i Fr-r=e 1 E . r:r _iUIr3lJ,:i.'J lfi.lf,r]r5 5r_rltrrr r:1 .rltir:jB I n i t , Terrip :1 . ?584 Ternp. F; i Ee !. EErlE, -T.3,: [,:e t. T I5. 'j!L:l! ti r,:,=:= HE.i t. B. r]BrjE ,:ts I ,'q 49l. STL Knoxville Sample ID: Work Order Number: Analysis Date: Std. or Determination? HoC Data Worksheet Revision 2 092203 xls Tomphte Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-\ryC-00I0 cCV - O?01 06 .. 3 a/ t/ ob 5+A Appendix F - 490 Page I Bomb Calorimeter Data Worksheet Revision I September 9, 2003 J,re{ 3/z / oL 9/8/2005 7:16 AM Analyst:JnH Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Calorimeter Dota Report F.rrr lihE [:a],:rirript.er F;e,...,, l-.t5;1lf:r:Unit # E r1],.,81,.,.:firlrE 14:l:j:iI ['l,:dE: 5 t.=nd.= rd i =a t.i,:n I'le t.h'=,J: [ign.rrri i c TuF,e ! Fi n.E 1Sample ID ?E [,J*i,]h t. L . r:t1 lI Ec,rrrh I[i f, EE Ualue ?Sg4. Z?BJ :-p i [':e lil,]l-r t. E , Efirlrtl Fr_rsp J. I. rtrlrrlER,:id ltl, 14fl5 5uItr-rr [r,Elil.-rr]Init, T*rnp :J.4?hI T*nip. F.:i=E i,E,B.I,:] J-=': l:.F t. T irl. rJEr l ri r,:E= He.r t D. rlrlr:r _i ,-E 1 '"',1 492 STL Knoxville Bornb Calorimeter Data Worksheet Measurement of Heat of Cornbustion per SOP KNOX-\ryC-0010 Sample ID: ccv - o3o3ob- 3 Work Order Nurnber: - Analysis Date: ?JzbI_ Std. or Deterrnination? 9+e Analyst: _ Jl^ !i Gross Heat of Combustion (caUg); Gross Heat of Combustion (Btu/lb): Bomb Calorimeter Data Report Parr 1?b5 tl.alnrirneter ReL.,. LlSllA?Llnit*B BSiEg/3986 1,3:46:?4 l"lodr; Standa rdi ze t i on l'lethod: Dgnarnic TUpel Fin.=lSarpteID 27 tJeighr l.LtBBg Bnmb ID 5 EE ualue 2r9s. s4gg 5p i ke btgh t B, BBBEr Fuse l f , S0ggtlcid 18.8331 5r-rlfur 0.BBBE Ini t, Temp 2P.3?B? Tenrp. Eise t.6SSgJscket T 3[:f.B116 Gra=:g Heat Er.ESEB ca 1,'g Bomb Calorimeter Data Worksheet Revision I September 9,2003 JrrH e/e/ob 9/8/2005 7:16 AMHoC Deta Worksheet Revision 2 092203.x1s Tcmphte Appendix F - 491 Page I 493 STL Knoxville Sample ID: t#ork Order Nurnber: Analysis Date: Std, or Deterrnination? Analyst: Bomb Calorimeter Data Worksheet Revision I September 9, 2003 o HoC Deta Worksheel_Revision 2 Tcrnplete Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-\ryC-0010 ccv-0? o60b-a t/L/ob b+e JFtH Appendix F 492 Page I Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Colorimeter Data Report Parr 13b6 CElorimeter Rerr. B5!lB2 Uni t * tl 83,'B€,/?8AE 137: lE:4F J'lo'Je: 5 t anda rdi za t ion He t hrrd: Dgnam i c THpe I Fi n.a I Sapfe ID 28 lileight 1 ,8225 Bomb lb 3 EE Ualr.p 2592.3217 5p i ke tlght g, BBBB Fuse 15. BBB0 Hcid 18.2469 5uI fur B. BB0B Ini [. Temp ?8.598S Tenrp, Rigp 2.7189 JEcket T 29.99f9 Gro=s He.:t B, BAE0 ca I ,'g 092203.x]s 494 STL Knoxville alorimeter Calibration Worksheet Revision 0 8t28t03 Calorimeter Calibration Worksheet Determination of Energy Equivalent (EE) per SOP KNOX-WC-0010 3/6/2006 8:22 AMCalorimeter Calibration Worksheet 030606 CCV.Bomb 4.xlsremplate Appopdix F - 493 Initisl Cslibration Data Calorimeter Sample ID Mean EE BOMB ID:4 ccv-01260 6-4 ccv-013 t06-4 ccv-020606-4 ccv-0215a6-4 ccv-022306-4 ccv-a22406-4 ccv-022806-4 ccv-030106-4 ccv-030306-4 ccv-030606-4 0u26106 0u3U06 0u06la6 0211s/06 02t23t06 02t24106 02128/06 03/0 U06 03/03/06 B/A6106 2388.01 10 2387.500s 2385 .4547 2385.03 85 2390.6415 2382.9790 2386.8547 2386.8806 2392.3497 2387.3702 2387,3080 Dailv Calibration Check Standard Calorimeter Sample ID Calibration Date EE (caLfC) ICAL Mean EE (calfC) %D (%) ccv-030606-4 03106t06 2387.3702 2387.3090 4.0% 495 STL Knoxville Sample ID: Work Order Number: Analysis Date: Std. or Determination? Analyst: HoC Drta Worksheet Revision 2 092203.x!s Tcmplrle Bornb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-\ryC-0010 ccv- orlbob-4 t/ z6(ob 5+d Jpil Appendix F - 494 Page I Bomb Calorimeter Data Worksheet Revision I September 9, 2003 Jrll t f*/ot 9/8/2005 7:16 AM Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Calorimeler Dota Report Parr liEE u.=l'rrirn*tEr Fie,.r. EIilrJ2 Unit.# B 811.'!8.''IEttiti, 11:51:r:lB Ilode: 5 t.En'J.= rd i =.= t i,rn f'let.h':d: [tqn.=nrir Tgp,e: Finel Sample tD 69 trleight t3. !784 Enmb lti 4 EE Ualue 2388.8110 5F,i lle l.,Jgh t t3. Et::lEtB Fu=r I 1 . fit:tr]tl tlcid !. i!?i 5uI f ur E. EEIEIE I n i t , Trnip :!. 1I4'1 Tenrp,. F.:i =e 'f . 5?if, -T.3,: lre t T I'i. 3'-14! tj r,:== Hea t t:i. [tEttlL:i r:.3 I r"rJ STL Knoxville 496 Sample ID: CcV- o 13 lob - + Work Order Number: a' Analysis Date: I ltt lob Std. or Determination? 5+a Analyst: Jr,r B Gross lleat of Combustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Calorimeter Data Report Bornb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-'WC-0010 Bornb Calorimeter Data Worksheet Revision I Septernber 9, 2003 Jntl t /s(ob 9/8/2005 7:16 AM o HoC Drta Worksheet Revision 2 092203.x1s Tanptrte Appendix F - 495 Page I F'.= r r 1 lr:,i, lI:.= I rrr t- i rirB t.E r F:E,.r, EIi ]. tl': 11 : lrl: f 1l_lnit # rJ i'l,r'Je : 5 t..3rrrj.= fd i f.3 t. i'I't-r l'le t had: frgrrarn i c TUF *: F i n.= I 5arnple Ib 78 L'Iei,lht l,B1'lrt El,:rnh I ti 4 EE tlal ue 23$7. 50Bs 5F,il-,:e I'l';ht fi,tltritlttJt Fr-r=s 1E,tlLiUE fi':i'J 18.i1!5 5r-r ltur li.gitlE-i I rr i t.. T*nrp, I': , 1 45'l Tenip . F,:i =s ---, 7[t! 1 .J.=,: ['.* t f I'JJ . 'l:j']4 tj r,:== H*.= t Et. StItEB ra I '",J 497 STL Knoxville Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-WC-0010 Sample ID z cc,/ - azobob - * lVork Order Number: -' AnalysisDate: zlb /ob Std. or Determination? 5 +d Analyst: JHH Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btuflb): Bomb Calorimeter Data Report FErr 1rt,b t]:elr,riniet.er Eir,..r. tilstlt]ti LIn i t. # E rlJ..,[rE,'I1trr]i 1E: I.l: 4I I'l,-,,Je : 5 t..=nde rd i =a t.i,:,rr I'l*t.hr'dl [ign.=niic TUF,E: Final Sample ID 71 t,]right l.Er-llEr E,:,rnh, I ti 4 EE Ualue 2385. 4547 5p i tlr l,l,Ih t t:i, l3EtlB Fu=r l f . EtlrJB llcid 1tl.tlI51 5u1{ur l]r,[rrJrErrJr I n i t.. T*rrip :8. B*5i3 Trnrp. F.:i =s ;::. r,Ei5 .J.3,j lre t. T !'J . SIf E tj ro== Hea t [r . BEr]tEr c.31 .',J Bomb Calorirneter Data Worksheet Revision I September 9, 2003 J*tH zftrtc 9/8/2005 7:16 AMHoC Drta Worksheet Revision 2 092203 xls Tcmplete Appendix F - 496 Page I 498 STL Knoxville Work Order Number: Analysis Date: Std. or Determination? Bomb Calorimeter Data Worksheet Revision I September 9,2003 Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-'WC-0010, Rev p t Sample IDt ( ,Q( :.,b,?.1 {o-b.:'l- Analyst: Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Calorimeter Data Report Ptff $-, Nhr Parr 1:E,h ll:elcr-irrietPr Eeq.r. tl5! 1 l:ti- 1 i: Li'J: [tJUnit # tJ LjI'" 15.,'I[ttlt, ['l,:de: 5 t.=nda rd i =.= t i,:n [.lpth,rd: [ign.=rriic TUF,*: Fin.=I Sample ID 7? tql*itfht 1.1115'3 E,=nih I tt 4 EE Ual ue ?385. ASB5 5pi k* lrl'lht B, BEtEt[t Fu=e 11 . EBI:IB l-icid 1fi. 174t,5uliur ET.BBEE I n i t. , Tenrp II . 517'-1 T*rrip . F.:i E* ". iEE-rE J;c [r* t. T Jt]t. IIEI4 !j r':::= He.E t E. ]:t]:tE1B r;.31 ."'l l W,,ffi Appendix F - P^t?7 2t15t2006 3:48 PMHoC Data Worksheet Revision 2 092203 Template 499 STL Knoxville Sample ID: l#ork Order Nurnber: Analysis Date: Std. or Determination? Analyst: HoC Dota Wortsheet Revision 2 092203 xls Temphle Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-'WC-0010 cov - 0?zr 06 - + z/zl lob 5+d *r,rtil Appendix F 498 Page I Bomb Calorimeter Data Worksheet Revision I September 9, 2003 JxH t/zt/o 6 9/8/2005 7.15 AM Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Calorimeter Dsta Report F'.3rr- lIij'E [:.=1,:,r-irriet*r Flgrn,, IJIIlt]1r l_tn i t. # tJ E:,,ii,-':l]Ei, rlrE : 4,i : f, i ['l,:"Je : 5 t and.= rd i =.= t i,:n I'le t.l-r,:'d: [iqn;rn i ,- TUF,* : F i n.l I Sample Ib 73 [r!e i gh t 1 , t]E4i 4 EE Ualue 2398.6415E,:rrrih I [:' 5p i ke lil,lh t, ul. [tEtl:lut Fr-r=e 1 7 . t:ttttltr l:t,:i'J t[t.tltii1 _ir;Itr_rr tl .t]rlrjrtl Init., Ternp !1,I45: T*nip. Ftige :.it,{,f, -L3,: [;:,3 t. T j[t. -t[liF E r':::= Hx: t. t-t, Et:-ltl[t rI.3 I .-'rf 500 o STL KnoxYille Sample ID: Work Order Number: Analysis Date: Std. or l)eterrnination ? Analyst: HoC Drta Worltsheet Revision 2 092203.x1s Tcmphle Gross lleat of Cornbustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Calorimeter Data Report Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-WC-0010 CCV -02Z1o6 - ,/ z/z+ (ob 5+d r}^{tf Appendix F 499 Page I Bomb Calorimeter Data Worksheet Revision I September 9,2003 txH z/zt / ot 9/8/2005 7:16 AM F.=rr 1:tE, t]:alarirrirt*r F.:8t..,.E5:1 ,1I [t'J: 1.];5fLInit # rJ E:.,'I4..,ir]r _rt f'J':rJt : 5 t,andE rd i =; t i E,rrl'lethnd: [rgnsniir TUpe! Fin.3lSample ID ?4 trt*i,lh t I . rltt6! E,rnrt I [r 4 EE UaI ue 2SBZ. BI9B 5p i t':* trlgh t llr. El:-rrllt] Fu=r lf, . Bl:11ffll':id ll::i,li3IE :1_rIiur- rl .rltlgfiIni t,, Terrrp :I, EI4f, Tenrp. F.:i:'e :, tE4E .Je,: ll* t I I'-1 . 'lIE 1 lj r,iEs Hea t. tI. i:rrlrlrS ':,= I ,"'l 501 o STL Knoxville Sample ID: Work Order Number:' Analysis Date: Std. or Determination? Analyst: HoC Data Worksheet Revision 2 092203 x|s Tcmphte Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-WC-0010 ecv -Qzz$06 -+ z I zelob ,+a Jr^H Appendix F 500 Page I Bomb Calorimeter Data Worksheet Revision I September 9, 2003 Jntl zytt/o6 Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Calorimeler Data RePort F.=rr 1ltif. tl:.=]',:rirn*tEr F.:eq.r, [r5!1EI l-ln i t # t] rll.-,iE,,IrlillrE, 1 .l: l:rE: iI I'1,:"Je : 5 t .3nd.a r-d i =.= t.i ,:n [,1* t.h,:,j: [igrr erri i,: Tgpe: F i n.= 1 Sample Tb 75 l'l*i,lht E.:r'-lii E,:rnh, I [j 4 EE ua I ue ?s96. gs47 :Ip i [r* lrl,]h t. l:1. EfiEE Fu=* 1 E. fiB]:18 fic i d '-l , '-158i 5r-r 1 f r-rr E. tlflt]E Init., Tenip, i1.!l3l:E T*rnp. F.:i=:E i.E4titi Je,: lle t T I'.f , F'-18.J t] r':,== H*; t tl. t:ttlt:lE ,:.31,",f 9/8/2005 7:16 AM 502 STL Knoxville Sample ID: Work Order Number: Analysis Date: Std. or Determination? Analyst: HoC Deta Worksheet Revision 2 092203.x1s Tcmphte Bomb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-!YC-0010 ccv -030rc6 -+ 7 /t /ob 5l't J|^H Appendix F - s01 Page I Bomb Calorimeter Data Worksheet Revis ion I September 9,2003 Jntl ep/o6 Gross Heat of Cornbustion (caUg): Gross Heat of Combustion (Btullb): Bomb Calorimeter Data Report Farr litr:, t-:.=lnriniet,Er F.:8,...,, E5':1ll':' Ui-r i t # r:r [r j.'911 ,-'!glri6 1 4: IE : 4 1 l]n,Je : 5 t.anda r'J i =e t i,:,n l'1e t.l'r,:,'J: [.'qn.=ni i': TUF e; F i n.-i I 5smple ID 75 tilei qt-rt, 1 . ulEBi E,:rnt' I ti 4 EE Ualue 2385.8886 5p i ke hlgh t tll. EBt:18 FuEe 17. t-ttittltl llcid 1tI.1H71 Sultr-rr F,fiBEtI I rri t. , T*nip ii. 41 lif, Tenip. F:i =e 'l, EEIB Je': lre t. T 3t] , BEfi4 G rn=:= He.= t tl. I:1L]EE ca I.,'q 9/8/2005 7:16 AM o s03 STL Knoxville Sarnple ID: Work Order Number:' Analysis Date: Std. or Determination? Analyst: HoC Drta Worksheet_Revision 2 -99??03.xls Tcmphle Bornb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-WC-0010 ccv - 0bo?,0b- + 3 /" /ob 5+d Jlrtl Appendix F - 502 Page I Bomb Calorirneter Data Worksheet Revision I September 9, 2003 J*r!( a/*/ol 9/8/2005 7:16 AM Gross Heat of Combustion (caVg): Gross Heat of Combustion (Btu/lb): Bomb Colorimeter Data Reporl Parr 1?b6 tlalorimeter Rpr,,. 115':18? UnitSB 83t83,,?806 13:F4:I! l'lode ; 5 tands rd i=e t i':n f'lethod: Dgrramic THF'e: Fin.a1 SatryIetD n trleighi 1,8894 Bomb IF 4 EE Uah-rc 2392.3497 Spi ke hlght B. BOBE Fu=e 17.0BSE Hcid lB. I 191 Sul {ur B, BB80 Ini t, Terrrp 3?,3158 Ternp. Rise 2,877L J.ec lre t T 58. BB?5 t3 ross Hea t B. BBEB ra l./g 504 STL Knoxville Sample ID: Work Order Number: Analysis Date: Std. or Deterrnination? O HoC Drta Worksheel Revision 2 092203.xts Tcrrrphle Bornb Calorimeter Data Worksheet Measurement of Heat of Combustion per SOP KNOX-WC-00I0 CgV- oaob ob - + t lb I ob 5{-d Appendix F s03 Page I Bomb Calorirneter Data Worksheet Revision I September 9, 2003 .lnH 3/5 lob 9/8/2005 7:1 6 AM Analyst:j*rll Gross Heat of Combustion (caUg): Gross Heat of Combustion (Btu/lb): Bomb Calorimeter Dota Report P.3rr 1?66 Calorinr*ter Reu. AStl0Zunir # B 83./0ts./?BBr, $7:34183 l'1ode: Stsnda rdi rat i onHethc,d; Dgnaniic TUpe: Finel Sapf e ID 78 Ulei gh t I . B?S4 Bomb It,, 4 EE Ualrr AIB?.T?WZ Spi ke t'lght B. EBBEI Fuse lf . BBBBHcid 18,2791 Sulfur 8.t}BtlfrInit, Terrrp t6,5729 Tenip, Rise 2.7251 Jer kr t. T ?9. 9999 ti rs=:= He.= t I . 0BBB ral r'B (.) io 1 o o o APPENDIX F SECTION 3.9 Chlorine Data MPF SWDT REPORT - Rev 0 Appendix F .lune 9, 2006o TOCDF F-504 s06 STL Knoxville IC Initial Calibration Data Review / Narrative Checklist Methods: 300.0,9056, 9057 nnd 26A, SOP: KNOX-WC-0005, Rev.6 ageIo DX ( c,D / nRrA ooaN Annlvsis Datc:t ll *ob Filc ID:A I [4.,- AurDNf -f,op-o I t I Db- AuA] Pase 1 of I Appendix F - 505 WC()52R(r.DOC. s/2/05 I n it iul C ulihratio tt Revi ert, Iteilrs N/A Yes No lf No, rvhy is drrtu reporttrblc? 2nd .l I Were at least 5 levels r:f each turalwe aualyzed'?/ 2. ls lor,r, lcvcl stanclard concentrertion < RL'?// 3. Arr; thu uorrulation coclllcients (r) 20 995; r2ro.9g(l'7 // {. I:'or method 300.0, rvas tlre calilratiorr cnrve proocssccl trsing lincar rcclrcssion'//l'lk 5. lior munuul intcgratcd starrdards. are befbre/atter uhromatograms proviilcrl rvith initials/clatc/reuson'/"/ Rcasons: S=Splil. pcak. lJ-l-lndetected l:eak, I=hrcorrecI trrcak intcgrtrtion. El=Brrselitte con'ec.tiott, W=Wrong pcak c:lttlsert by data sysl,cm [-N Analyst: [) AP h&J-'Dute: t llLlb L Commcnts: "lir*tl an.,il^- Crrllbr6,f,1',6- l^trn- tL*ct,^l .ilr, AaDiOg.2^d cnrlsr {'i* Parr.ae = 6.L- f Pflt* li' l*[Jr- tl r E l()NOZrJ; N4l.Jru*. ?O{P k\,{ } ,.5-Cf , tcfrt- ,Jr-:- '^q 2,!,- &t c,a*.\PrJttP- .,' J(I.1 -Iut/ 2"'l Level ReviclYer: A.-Yn I Datc: \llJlJ../. Comments:*1lv Y o CAL STD #1 = ICWS-7945 Samp/e Name: Vial Number: Sample Type: Cantrol Program. Quantif. Method: Recording Time: Run Tirne (min): CAL STD #1 = ICWS-7945 97 standard ANIONS_AS14A_lodide ANIONS 1111/2006 16:32 28.00 lnjection Volume: 50,0 Channel: ECD_1 Wavelength: r'l.a. Bandwidth: Ir.a. Dilution Factor: 1.0000 Samp/e Weight: 1,0000 Sample Amount: 1.0000 Operator: kaukerc Ti mebase : lC-Aragorn Sequence:A1 1 A_AN IONS+ IOD_01 1 1 06 50 10.0 15.0 200 Appendix F 506 507 Page 1-1 111212006 10:59 AM 265 Chromeleon (c) Dionex 1996-2001 Version 6.60 Build 1428 o^ ,A1 1A_ANIONS+IOD_O1 1 106 #1 [modified by kaurkerc]()U ECD-1 trs 6-Nitrate-N-8.392 hloride - 7-Phosphate-P-10.917 8-Sulfate-12.983 9 - lodide - mtn 4-Nitrite-N-5.817 No.Ret.Time (min.) Peak Name Height (u$) Area uS*min Rel.Area (%) Amount (mq/L) Peak Tvpe 1 2,1e n.a.0.06653 0.010 1,00 n. a.BMB 2 3.29 Fluoride 0.60803 0.073 7.02 0.1 999 BMB 3 4.89 Chloride 0.E9413 0.1 25 12.05 0.4950 BMB 4 5.82 Nitrite-N 1 59707 0.282 27.09 4.47 54 BMB 5 7.43 Bromide 0.1 021 3 0.021 2.02 0 1928 BMB 6 8.39 Nitrate-N 1.24959 0.309 29.64 0.4800 BMB 7 10.92 Phosphate-P 0.33953 0.1 05 10.10 0.47 s2 BMB B 12.98 Su lfate 0.27361 0.091 8.72 4.47 46 BMB I 23.60 lodide 0,03557 0,024 2.35 0.4647 BMB" I d efa u lt-letter/l nteg rat i o n GAL STD #2 = ICWS-7946 Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): CAL STD #2 = ICWS-7946 98 standard ANIONS_AS14A_lodide ANIONS 1111/2006 17 :02 28.00 lnjection Volume: 50.0 Channel: ECD_I Wavelength: rl.a. Bandwidth.' Jl.a. Dilution Factor: 1,0000 Sample Weight: 1.0000 . Sample Amount: 1.0000 Operator; kaukerc Timebase: lC_Aragorn Sequence:A1 1 A_ANIONS+ IQD_01 1 1 06 A1 1A ANIONS+IOD 01 1 106 #2 [modified kau l<erc 4-NitritP-N-5.834 10 0 20.0 Appendix F 507 508 Page 1- 1 111212006 11:00 AM 25 ?.0 15 1,0 0,5 I - lodide .2 265 Chromeleon (c) Dionex 1996-2001 Version 6.60 Build 1428 6-Nitrate-N-8,392 hloride - 7-Phosphate-P-10.934 8 -Sulfate - 13.009 No.Ret.Time (min.l Peak Name Height (u$) Area uS*min Rel.Area t%l Amount (mq/L) Peak Tvpe 1 2.22 n,4.0.1 1 941 0.019 0.84 n.a.BMB 2 3.31 Fluoride 1 .52611 0.1 91 8.60 0.4966 BMB 3 4.91 Chloride 1 .79898 0.256 11.56 0.9866 BMB 4 5. 83 Nitrite-N 3.29836 0.577 26.00 0.9735 BMB 5 7.45 Bromide 0.26137 0.056 2.52 0.491 1 BMB 6 8.39 Nitrate-N 2.61381 0.652 29,38 0 9880 BMB 7 10.93 Phosphate-P 0.7046 1 0.224 10.09 1.0024 BMB I 13.01 Sulf ate 0.57215 0.192 8.65 0.9995 BMB I 23.48 lodide 0.07265 0.053 2.37 0.9808 BMB* d ef a ult_letter/l nteg ration CAL STD #3 = ICWS-7947 Sample Name: Vial Number: Sarnp/e Type: Control Program: Quantif. Method: Recording Time: Run Time (min): GAL STD #3 = ICWS-7947 99 standard ANIONS_AS14A_lodide ANIONS 1111/2006 1 7:33 28.00 lnjection Valume: 50.0 Channel: ECD_1 lMavelengttt: rl.a. Bandwidth.' rl.a. Dilution Factor: 1.0000 Sample Weight: 1.0000 Sample Amount: 1,0000 Operator:kaukerc Timebase: lC-Aragorn Sequence:Al 1 A_AN IONS+lOD_01 1 1 06 41 1A ANIONS+IOD 011106 #3 modified b kaul<erc 5-Nitrite-N-5.800 7-Nitrate-N-8.325 B-Phosphate-P-10.900 9-Sulfate-1?.975 10.0 15.0 509 Page 1-1 111212006 11:00 AM d efa u lt_l ette r/l nteg rati o n Appendix F - 508 ECD 1 10 - lodide -2 Chromeleon (c) Dionex 1996-2001 Version 6.60 Build 1428 No,Ret.Time (min.) Peak Name Height (uS ) Area uS*min Rel.Area (%l Amount (mq/L) Peak Tvpe 1 2.19 n. a.0. 1 7653 0,029 0.52 n. a.BMB 2 3.29 Fluoride 2 25285 a.278 5.1 0 0.7274 BMB 3 3.86 n. a.0.1 1081 0.015 0.27 n. a.BMB 4 4.88 Chloride 4,66092 0.651 11.94 2,4843 BMB 5 5,80 Nitrite-N 8.65095 1.507 27.63 2.4889 BMB 6 7.42 Bromide 0.38881 0.08 1 1.48 0.7278 BMB 7 8.33 Nitrate-N 6.94171 1.683 30.87 2.5041 BMB I 10.90 Phosohate-P 1 .84091 0.580 10.64 2 5353 BMB I 12.98 $ulfate 1,43222 0.490 8,99 2.527s BMB 10 23.1 e lodide 0 1 8e01 0,1 40 2.57 2,5551 BMB* 4 CAL STD #4 = ICWS-7948 Sample Name. Vial Number: Samp/e Type: Control Program: Quantif. Method: Recording Time: Run Time (min): GAL STD #4 = ICWS-7948 100 standard ANIONS_AS1 4A_lodide ANIONS 1111/2006 18:03 28,00 lnjection Volume; 50.0 Channel: ECD_1 Wavelength: n.a. Bandwidth,' rr.a. Dilution Factor: 1.0000 Samp/e Weigltt: 1.0000 Sarnp/e Amount: 1.0000 Operator: kaukerc Timebase: lC_Aragorn Sequence:A1 1 A_ANIONS+ IOD_O1 1 1 06 41 14 ANIONS+IOD 011106 #4 [modified ka u kerc 4-Nitrite-N-5.800 hloride - 10.0 7-Phosphate-P-10.892 B -Sulfate - 12.975 510 Page 1-1 1t12t2006 11.00 AM ECD 1 9 - lodide -2?, 26.s 0 15.0 200 6-Nitrate-N-8.283 No,Ret.Time (min.) Peak Name Height (uS) Area uS*min Rel.Area t%l Amount (rnq/L) Peak Tvpe 1 2.1s n.a.0.24521 0.038 0.34 n. a.BMB 2 3.29 Fluoride 3.1 1 383 0.392 3.49 0.9964 BMB 3 4.8E Chloride 9,977 45 1.389 12.39 5.0254 BM 4 5.80 Nitrite-N 18.37430 3.1 95 28.49 5.0690 M 5 7.40 Bromide 0.54325 0.1 26 1.12 1.0125 M 6 8.28 Nitrate-N 15.05396 3.592 32.03 s.0445 MB 7 10 89 Phosphate-P 3.84028 1.192 10.63 5,0071 BMB I 12 98 Sulfate 2.93663 0.987 8.80 5.0091 BMB I 22.98 lodide 0.40281 0.304 2.71 5.2630 BMB* Appendix F - s09 Chromeleon (c) Dionex 1996-2001 Version 6.60 Build 1 428d efa u lt_l etter/l nteg rat i o n 5 CAL STD #5 = ICWS-7944 Sample Name: CAL STD #5 = ICWS-7944 Vial Number: 101 Sample Type, standard Control Program: ANIONS_AS1 4A_lodide Quantif. Method: ANIONS Recording Time: 111112006 18:34 Run Time (min): 28.00 lnjection Volume: 50.0 Channel: ECD*I Wavelength: rl.a. Bandwidth.' Ir.a. Dilution Factor: 1.0000 Sample Weigltt: 1.0000 Sample Amount: 1.0000 Operator: ka ukerc Timebaso: lC_Aragorn Sequence:Al 1 A_AN IONS+lOD-01 1 1 06 41 1A_ANIONS+lOD_01 1 106 #5 [modified kau kerc s11 Page 1-1 111212006 11:00 AM Chromeleon (c) Dionex 1996-2001 Version 6.60 Build 1428 Appendix F 510 t'-- 20.0 4-Nitrite-N-5.809 6-Nitrate-N-8.259 hloride - 2-Flu L No.Ret.Time (min.) Peak Name Height (uS) Area uS*min Rel.Area (%l Amount (mqll) Peak Tvpe 1 2.20 n.a.0 3601 9 0.063 0.32 n.a.BMB 2 330 F luoride 8.36491 1 .013 5.20 2.5454 BMB 3 4.89 Chloride 21 .46898 2,976 15.28 10.0259 BM 4 5.81 Nitrite-N 28.46595 4.938 25,35 7,5537 M 5 7.40 Bromide 1 39723 0 302 155 2.5446 M b 8.26 Nitrate-N 23.89822 5.654 29.02 7.4946 MB 7 10.89 Phosphate-P 5.97753 1.844 9.47 7,4646 BMB I 12.98 Sulfate 6.09596 2.030 10.42 9.9860 BMB I 22.76 lodide 0.82736 0.659 3.38 1 0.4157 BMB* d efau lt_letter/lnteg ration 6 CAL STD #6 = ICWS-7949 Samp/e Name: Vial Number: Samp/e Type: Control Program: Quantif. Method: Recording Time: Run Time (min): CAL STD #6 = ICWS-7949 102 standard ANIONS_AS14A_lodide ANIONS 1111/2006 1 9:04 28.00 lnjection Volume; 50.0 Channel: EGD_I Wavelengtlt: n.a. Bandwidth: Il.a. Dilution Factor: 1.0000 Sarnp/e Weigltt; 1.0000 S.ample Amount: 1.0000 Operator:kaukerc Timebase: I C_Aragorn Sequence:A1 1 A_AN IONS+lOD_O1 1 1 06 ^ 41 1A_ANIONS+IOD_011106 #6 [modifled by kaukerc, 1 peak manually assrgned] 30.0 US 4-Nitrite-N-5,800 t8-t$trrte-N - s.?17 9-lodide-22.5 mln 20. 50 10.0 15 0 204 5L2 Page 1-'l 1n212a06 11:00 AM 10. Appendix F - sl I Chromeleon (c) Dionex 1996-2001 Version 6.60 Build 1 428 No.Ret.Time (min.) Peak Name Height (uS) Area uS*min Rel.Area (%) Amount (mq/L) Peak Tvpe 1 2.19 n.a.0.55001 0.095 0.33 n. a.BMB 2 3.2s Fluoride 17.64214 2.158 7.48 4.9837 BMB 3 4.88 Chloride 34.69031 4.737 16,41 14.9810 BMb 4 5.80 Nitrite-N 38 .8 17 87 6.642 23 01 9.9374 bMB 5 7.38 Bromide 2.83448 0.575 1.gg 4.9809 BMb 6 8.22 Nitrate-N 33.92124 7.972 27.62 9.9864 bMB 7 10.E6 Phosphate-P 8 39207 2.569 8.90 10.0154 BMB I 12.94 Sulfate 9.s 1 604 3.1 46 10.90 15.0029 BMB I 22.56 lodide 1,26126 0.97 4 3.37 14.4264 BMB^ o defa u lt_l ette ri I nteg rat i o n Operator:kaukerc Timebase: lC_Aragorn Sequence:Al 1 A_ANIONS+lOD_01 1 1 06 defa u !t_lette r 513 Page 1-1 111212006 11:01 AM Appendix F - CHROM E/Calibration(Curr. Pea$ ' 512 Chromeleon (c) Dionex 1996-2001 Version 6.60 Build 1428 tlrulf Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (Nn): CAL STD #6 = !CWS-7949 102 standard ANIONS_AS14A_lodide ANIONS 111112006 19:04 28.00. lnjection Volume: 50.0 Channel: ECD_1 Wavelength: n.a. Bandwidth: n.a. Dilution Factor: 1,0000 Sample Welght: 1.0000 Sample Amount: 1.0000 f Fluoride // ---"-'t" _//"' _F--/'.-//{ ..-Y' No.Ret.Time Peak Name Cal.Type Points Corr.Goeff, Offset Slope Curve min (R) 1 2 3 4 5 6 7 I I ?.19 n.a. 3,29 Fluoride n.a. XOuad / n,a. /ose8e n.a. b n. a. n. a. n.a. 0 0000 3.021 535 0 1 04028 XQuad XQuad XQuad XQuad XQuad XQuad XXQuad 9979 9995 999E e982 9994 9997 9984 0.035167 0.057799 0 008201 0.083473 0.0037 02 0.001264 0.001065 0 0 0 0 0 0 0 0 0 0 0 0 0 0 o 6 6 6 o 6 6 4.88 Chloride 5.80 Nitrite-N 7.38 Bromide 8.22 Nitrate-N 10.86 Phosphate-P 12 94 Sulfate 22,56 lodide 0000 1.788779 0000 3.331886 0000 0.52E219 0000 2.563130 0000 0.219458 0000 0.1 90708 0000 0.052174 Average:0 9990 0.0000 1.4620 0.0368 (fr$'r Sample Name: Vial Number: Samp/e Type: Control Program: Quantif. Method: Recording Time: Run Time (min): GAL STD #6 = ICWS-7949 102 standard ANION$_AS14A_lodide ANIONS 1t11l2006 1e:04 28.00 lnjection Volume; 50,0 Channel: ECD_1 Wavelength: n.a. Bandwidth: rl.a. Dilution Factor: 1.0000 Sample Weight: 1.0000 Sample Amount: 1.0000 Operator:kaukerc Timebase: I C_Aragorn Sequence:A1 1 A_AN IONS+ IOD_01 1 1 06 External 300 defau lt_letter_ s14 Page 1'1 111212006 11:01 AM Appendix F - CHROME/CaIibration(Curr Peald' 5 I 3 Chromeleon (c) Dionex 1996-2001 Version 6.60 Build 1428 ^ Cllq1de \ tHersht frrSL -L{ -/-///,/#- /l No.Ret.Time Peak Name Cal.Type Points Corr.Goeff, Offset SIope Gurve min (R) 1 2 3 4 5 6 7 I I XQuad 6 XQuad 6 XQuad 6 XQuad 6 XQuad 6 XXQuad 6 2.19 n.a n.a. n.a. 3.29 Fluoride XQuad 6 Q.9989 0.0000 3.021535 0.104028 4,EE .Chlorigg , XQqad 6 - o ,q979 0.0000 1.78E779 0.03-5167 5.80 Nitrite-N 7.38 Bromide 8.22 Nitrate-N 10.86 Phosphate-P 12.94 Sulfate 22.56 lodide 0.9995 0.0000 3.331886 0.057799 0.9998 0.0000 0.s28219 0.008201 0.9982 0.0000 2.563130 0.083473 0.9994 0.0000 0.219458 0.003702 0.9997 0.0000 0.1 90708 0.001264 0 s984 0.0000 0.05217 4 0.001 065 Average:0.9990 0.0000 1.4620 0.0368 Sample Name: Vial Number: Samp/e Type: Control Program: Quantif. Method: Recording Time: Run Time (min): CAL STD #6 = ICWS-7949 102 standard ANIONS_AS14A_lodide ANIONS 1111/2006 19:04 28.00 lnjection Volume: S0.0 Channel: ECD_1 Wavelength: n.a. Bandwidth.' n.a. Diltttion Factor: 1.0000 Samp/e Weight: 1.0000 Sample Amount: 1.0000 Operator: kaukerc Timebase: I C_Aragorn Sequence:A1 1 A_AN IONS+lOD_01 1 1 06 default letter Aonendix F - CHROMEl}alibration(Curr.Peak)' 514 515 Page 1-1 1l12t2o}6 11:01 AM Chromeleon (c) Dionex 1996-2001 Version 6,60 Build 1428 Nitrite-N No.Ret.Time Peak Name Cal.Type Points Corr.Goeff. Offset Slope Curve min (R) 1 2 3 4 5 o 7 B I n.a. XQuad XQuad XQuad n.a. 0.e989 yee7s / 0.99e5 2 19 n.a. 29 Fluoride 88 C hloride 80 Nitrite-N n.a. o ,.,b 6 n.a. n.a. n.a. 0,0000 3.021535 0.104028 0.0000 1 .788779 0.035167 0.0000 3.331886 0.057799 3 4 5 7,38 Bromide 8.22 Nitrate-N 10.86 Phosphate-P 12.94 Sulfate 22.56 lodide XQuad XQuad XQuad XQuad XXQuad 6 6 6 o o 0.9996 0.9982 0.9994 0.9997 0.9984 0.0000 0.5?821s 0.0000 2.563130 0.0000 0.219458 0.0000 0.1 9070E 0.0000 0.05217 4 0.008201 0.083473 0.003702 0.001264 0.001065 Average:0.9990 0.0000 1 .4620 0.0368 6,--+'*4t $JfB #6 E.'IGWS-79#)?ril ,/,r/oa. Sample Name: Vial Number: Samp/e Type: Control Program: Quantif. Method: Recording Time: Run Time (min): CAL STD #6 = ICWS-7949 102 standard ANIONS_AS14A*lodide ANIONS 1111/2006 19:04 28.00 lnjection Volume: 50.0 Channel: ECD_1 Wavelength: n.a. Bandwidttt: rl,a. Dilution Factor: 1.0000 Samp/e Weigltt: 1.0000 Sarnp/e Amount: 1.0000 Operalor:kaukerc Timebase:lC_Aragorn Sequence:A1 1 A_ANIONS+lOD_01 1 1 06 default_letter_ 516 Page 1-1 1nu2aa6 11'.024M _ 600 i Anoendix F - CHROME/Calibration(Curr.Peak)' 5 I 5 Chromeleon (c) Dionex 1996-2001 Version 6.60 Build 1428 No.Ret.Time Peak Name Cal.Type Points Gorr.Coeff, Offset Slope Curve min (R) 1 2 3 4 5 6 7 B I 2.19 n.a. 3.29 Fluoride 4.88 Chloride 5.80 Nitrite-N 7.38 Bromide n. a. XQuad XQuad XQuad XQuad n. a. 6 6 6 6 0.9989 0.9979 9.eees /o eees n. a. n. a. 0.0000 3.021 535 0.0000 1.788779 0.0000 3.331886 0 0000 0.528219 n. a. 0.1 04028 0.03s 167 0.057799 0.008201 6 o 6 6 8.22 Nitrate-N 10.86 Phosphate-P 12.94 Sulfate 22.so lodide XQuad XQuad XQuad XXQuad 0,9992 0.9994 0.9997 0.9984 0.0000 2.5631 30 0.083473 0.0000 0.219458 0.003702 0.0000 0 190708 0.001264 0 0000 0.0s2174 0.001065 Average:0. e990 0.0000 1.4620 0.0368 -/-\ ({fftn Sample Name: Vial Number: Sarnple Type: Control Program: Quantif. Method: Recording Time: Run Time (min); GAL STD #6 = ICWS-7949 102 standard ANIoNS_A$14A_lodide ANION$ 1111/2006 1 9:04 28.00 lnjection Volume: 50.0 Channel: ECD_I Wavelength: n.a. Bandwidth.' Il.a. Dilution Factor: 1.0000 Samp/e Weight: 1.0000 Sample Amount: ' 1,0000 Operator:kaukerc Timebase: lC_Aragorn Sequence:A1 1A_ANIONS+lOD_O1 1 1 06 40 Nitrate-N It I 5r7 Page 1-1 1t12t2006 11'.A2AM I ,,+I -o,o No.Ret.Time Peak Name Cal.Type Points Corr.Coeff. Offset Slope Curve min (R) 1 2 3 4 5 6 7 I I 19 n.e. 29 Fluoride 88 Chloride 80 Nitrite-N 38 Bromide 22 Nitrate-N n. a, XQuad XQuad XOuad XQuad XQuad n.a. 0.9989 0 9979 0.9995 0.9998 /o.ee82 2 3 4 5 7 n.a. o 6 o o 6 n.a. n,a. 0.0000 3.021535 0.0000 1.788779 0.0000 3.331886 0.0000 0.528219 0.0000 2.563130 n .4. 0 1 04028 0.035167 0.057799 0.008201 0.083473 XQuad XQuad XXQuad 9e94 9997 9984 0 0 0 6 6 6 10 86 12 94 22 56 Phosphate-P Sulfate lodide 0.0000 0.219458 0.003702 0.0000 0.1 90708 0.001264 0.0000 0.05217 4 0.001 065 Average:0.ee90 0.0000 1.4620 0.0368 Chromeleon (c) Dionex 1996-2001 Version 6.60 Build 1428cHRoME/caIibration(crr p.*roTl;. o - default letter Sarnp/e Name: CAL STD #6 = ICWS-7949 Vial Number: 102 Sample Type.' standard Control Program: ANIONS_AS{4A_lodide Quantif. Method: ANIONS Recording Time. 111112006 19:04 Run Tirne (min): 28.00 lnjection Volume: 50.0 Channel: ECD_1 Wavelength: Il.a. Bandwidth.' n.a. Dilution Factor: 1.0000 Sample Weight: 1.0000 Sample Amount: 1.0000 Operator: kaukerc Timebase: lC_Aragorn Sequence:Al 1 A_ANIONS+ IOD_O1 1 1 06 d ef a u lt_l ette r_ 518 Page 1-1 1t12t2006 11 .02 AM Chromeleon (c) Dionex 1996-2001 Version 6.60 Build 1428 Appendix F - CHROME/Calibration(Curr.Peak) 511 ea [pS-min] No.Ret.Time Peak Name Cal.Type Points Corr.Coeff. Offset Slope Curve min (R) 1 2 3 4 5 6 7 I I 2.19 n. a . 3.29 Fluoride 4.88 Chloride 5.80 Nitrite-N 7.38 Bromide 8,22 Nitrate-N 10.80 Phosphate-P n.a. XQuad X0uad XOuad XQuad XQuad XOuad n. a. o 6 6 6 6 6 n. a. 0.9989 0.9979 0.9995 0. ee98 0.9982 /r eee4 n. a. n.a. 0.0000 3.a21 535 0.0000 1.788779 0.0000 3.331886 0.0000 0.528219 0.0000 2.563130 0.0000 0.219458 n. a, 0.1 04028 0.035167 0.057799 0.008201 0.083473 0.003702 6 o 12.94 Sulfate 22.56 lodide XQuad XXOuad 0 0 0.0000 0.1 90708 0.001264 0.0000 0.05217 4 0.001 065 9997 9984 Average:0.9990 0.0000 1.4620 0.0368 E GAb $TB #E *lGWs,r94e ([l,Thy Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): CAL STD #6 = ICWS-7949 102 standard ANIONS_AS14A_lodide ANIONS 111112406 19:04 28.00 lnjection Volume: 50.0 Channel: ECDrl lilavelength.' n.a. Bandwidth: tr.il. Dilution Factor: 1.0000 Sample Weigltt: 1.0000 Sample Amount: 1.0000. Operator: kaukerc Timebase: lC_Aragorn Sequence:A1 1 A_AN IONS+lOD_01 1 1 06 External 519 Page 1-1 1 t1212006 11,A2 AM I I o soll I I I No.Ret.Time Peak Name Gal.Type Points Corr.Coeff. Offset Slope Curve min (R) 1 2 3 4 5 6 7 I I 2.19 n. a. 3,29 Fluoride 4,88 Chloride 5.80 Nitrite-N 7.38 Bromide 8.22 Nitrate-N 10.86 Phosphate-P 12.94 Sulfate n. a. XQuad XQuad XQuad XQuad XQuad XQuad XQuad n.a. 0.e989 0.9979 0,9995 0.9998 0.9982 o ee94 /o eee7 n.a. 6 6 6 o 6 6 6 n.a. n.a. n.a. 0.0000 3.021 535 0.104028 0.0000 1.788779 0,035167 0.0000 3.331 886 0.057799 0.0000 0.528219 0 008201 0.0000 2.s63130 0.083473 0.0000 0.219458 0 003702 0.0000 0.1 90708 0.001264 22.56 lodide XXQuad 6 0.9984 0.0000 0.052174 0.001065 Average:0 9990 0 0000 1.4620 0.0368 Chromeleon (c) Dionex 1906-2001 Version 6,60 Build 1428 Aooendix F - CHROME/Calibration(Curr.Peak)' 5 I gd efa u lt lette r Operator: kaukerc Timebase: lC_Aragorn Sequence:A1 1 A_AN I ONS+ IOD_01 1 1 06 s20 Page 1-1 1t12t2406 11 .A2 AM (,wt Samp/e Name: CAL STD #6 = ICWS-7949 Vial Number: 102 Sample Type; standard Control Program: ANIONS_AS1 4A_lodide Quantif. Method: ANIONS Recording Time: 1111t?000 19:04 Run Time (min): 28.00 lnjection Volume: 50.0 Channel: ECD_1 Wavelength: Jl.a. Bandwidth: n.a. Dilution Factor: 1.0000 Sample Weight: 1.0000 Samp/e Amount: 1,0000 lodide a [pS'minJ No.Ret.Time Peak Name Cal.Type Points Corr.Goeff. Offset Slope Curve min (R) 1 2 3 4 5 o 7 8 I n. a. XQuad XQuad XQuad XQuad XOuad XQuad XQuad XXQuad n. a. 0.9989 0.9979 0.9995 0.9998 0.9982 0.9994 0 9997 /o.sgat n.a. n.a. 0000 3.021 535 0000 1.788779 0000 3 331 886 0000 0.528219 0000 2.5031 30 0000 0.219458 0000 0.1 90708 0000 0,052174 n. a. 0.1 04028 0.03s167 0,057799 0 .00820 1 0 083473 0 003702 0 001264 0.001065 0 0 0 0 0 0 0 0 2.19 n. a . 3.29 Fluoride 4.88 Chloride 5.80 Nitrite-N 7.3E Bromide 8.22 Nitrate-N 10.86 Phosphate-P 12,94 Sulfate 22 56 lodide n. a. 6 o 6 6 6 6 6 6 Average:0.9990 0.0000 1 ,4620 0 0368 Chrorneleon (c) Dionex 1996-2001 Version 6.60 Build 1428C H RoM E/C a I i bration (C r,,, p**rYOT|}- O default letter 52 7 rq()mr{Fge(t F rg(f )c)UB \o O >roBIq. )u0)H *f i i L' l& ( J \ $ \tt! ab0 ra - \t Fr l t- Ird v: tr ' \nr- o \r}A. 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I3 \ .r C) co OL L= (t l h F. ri Hra . t q. , rt , rIa,$ t- A Ol < r3EF 0) H&z zbH* d,b qy EII, 0 ) ot r *EEz U t \r - Ie) a ,el qc I?. cn2 ICr - f.A-)Ci I+AL^ i- l tr (t ) -o L] F z fr - \ - f-<rTU12iJL)HJ G=[ (. , a" i ef -+ Ap l lf en d i 5? i KF . r- & o c. l r' a Is o) (t lo'9(gL0.xti l 52 5 mC) oohl€Ucee. - t&(f ,()UF +\o hEOEqJt,9q) g, Ed FI - .= o LL U IIt r .q*: ,,u D) u ct- u u t\" ln l- L l- . '5 0 ) 3G .- Ft n= L. . a A sU^ t 5 .- LO\ 7 'J (u qE ll l | l | f , s d, ='o o\n \. I\i I 0tnqtQ . I a\nets . . \o\. r fNrS F s .J rCc t E) c Ho O. Ll \LAEqq;qra ctxtt l o) (l ) L l t-6UO. { \,crrlF t?_ r{ J t) , C) tr q - t or - L= fi 69" 6 F'F)cc q. r ,Bt) lr t Or { J9*EcEO) -i &u ,FPfl+<dq- tf a_ 1'tr20 ) OH l* c, Ez U \L I-. . t ' q_ ) B IE( aa tCt 'H q*>*N I \Js\r z - ) H t<e, ) o€ 3z )" \tJ&r.I aSI tf , . . d -t LJ a^ . . i Cf , + Ap r ,r ; en d 5S XF ln € (} \ rt i (. f r $ *_ e l sl -L _ ,- \ l -J \L -1si (doEo af l gO.xI! I ;l1:. - : t4 taIU_l €L *. . 1 -- - I \_ -l auUoFaafr lHAl{rdilg*oRzrdHeOcfr ra .- z li H 6 * . JE E It r- \ F{ >E b XX E 9U f i qE U E1 - ir u H \ CI€0)iOJ t)& OOO Ei Ir U IEI+u --\r \o IL^ t t \, , t I i) tu I\. , , \ F l- L. 'E ( ) E - n5 HO stf ) ut O\ r rt r ) rcdE-o e, r. a \q s)J )t:S qV^ l \ oVa.i IS nI\ I \, \ fiN r ova fr l?S I .JE1 - 1 ot r f# )A. qL8c a.xfr l c) l- /4 , ol l- . 1 l-C\ , O. \/ . :- t/ - . r\ I I<JrJ u (L ) Cr J 0J L l- 3at a) O. ri \F\3c- )=L1 Lf r Er { Jg uP -cb (I . l ) - r Ez C; . fr -k LL)Es- Ea 0. ) o* It oEz U t \J - IU =, ,\ )? JG ?CRT ta- -l& I .d I^ i- )TF n p0) of z cJ - 3- tr ,EdH /- s ' ' \G(qJ t- ) ci cr .t t Ap p rr i :n d i s4 F-f- oc o c. . l (r a t .s l AL^\ l -. . I \\ _ _ l _ .\ - l jjcqnl-AlJ .EE'exlr l II 'B l CJ I ,a0)U -, l 1l HHl -. - I -- + L *- l U)u(JoEroord*il rdilL*oazldPFIz,o*Era ._ z L; E l A . j= i l F- l dXX = 98 f i 0Q r :E ( U hl d . fr r i F ir Z B FV)UZ)<E*oF-tZFIfr fr rozcfr aFr .dil1( turqilE STL Knoxville Total Halogens Data Review / Narrative Checklist Methods: 5050 and 9056, SOPs: KNOX-WC-0OI6, Rey. I and KNOX-WC-0005' Rev. 6 527 Page I uf I otal Chlorine O Total Fluorine 0 Total Brontine D Total IodineLot Nurnber Analytes: b+fcD- Dlll 0b -- Qr Anall'si.s Dirtc: Sltolvu U,VA-R*'CIht >- AsjbDb ICAL File [D: If No, rvhy is data reportable?Re ticrr I tcrns I . Wcre PM checklists. [,ot Sununary and auy applicable QnS t'r:vtcrrcd'l 2 ICV rvithin 90-ll0%R and ICB/CCB < l12 RL? -1. CCVs/CCBs ruu ut'ter evcrv l0 saruples & end of nut'? 1 ts %D Sl0% tbr each CCV? i Il'CC V lirilr;d. rvus it rcrun onll' ouce'l n [cs3J LCS rccot,ery >l?A"/" and sarnple results <RL.*6 1.C'S4p541lrtah1c.s rvil,hin 80- I 20%R? ll'tut. li:;t L( S /D. n [mb3J No analyte > RL in associated samples. * o [mbBI Sanrple results > 20x hieher than blan]i. -l . Method blanli < RL? lf no, li.st blank ID: 8 MSA4SD dorte Der DreD batch? D Ims3] LCS acceptable indicating sample matrix eflects. Native analyte concentration >4x spike level. 9. MSA4SD within 80-120% recovery and Sl0 RPD? lf no, li,st ID: lU. DUP doue per l(l santoJcs or per trial bum'l O [rpdJ OS anrVor DUP < RL. D lrpd2l LCS acceptable, Samole heteroe,eneit l I DUP RPD < IOO/d? If no, lisr ID: 12. Were MS run #'s assiened correctl D [ht1] fff expired upon receipt D fhtzl Analvsis reouested after HT expirecl.* I 3. Saruple analyses done within holding tirne (HT)? lf no, li,st ,samples: l:1. Were results Drocessed usins correct ICAL? 15. Arc rmsitive results rvithin tlre calibratiou range? l(: [s )utegriltion acceptable lor all san:ples, QC santples trrrtl sterttrlards'l Reasons: S=Split peak, U=Undetected peak, I=lnconect peak mtegration, B=Baseline correction, W=Wrong peak chosen by data svstenr. 17. for rnanual iutegrated standards and QC sanrples, are bcli>r e/aticr cluornatograuls providcd u'itlr in r tia I s/tlutc/reusou'7 18. Calculations checked lbr error? (Document rnanual calculartiort checks. 19. \\'|crc surcatlsltccts checked tbr transcrir:tion enors? O Ielev1] Elevated RLs due to rnatrix irttertenrces2(t. Arc results bclovv RL obtaincd lionr undiluted lC nrns'J leirst o.5 e sautole'l 22. l:6rrepor/,ony? ( Verily results, ItLs, unit.s, qualiliers, I)Fs, datcs. spikes. ) An alvst:Date: 3 }nd l*vet Revieweri Comrnents: 2.Cornments: If No, why is data reportable?Final Review bv: List NCM il:l. Arc all NCMs clocurnented and discussed in narrative? 2. Narrative correct? (Appropriate autotext included and all dcviirtiorrs noted. ) D [chlorJ Total chlorine. 0 [hal] Total clrlorine, tluorine, brotnirte, iodirte. O [tb1]Related PT dara show similar variation. 0 [tb2] Solid sanrples Iikely to be heterogerleous. [l [tb3] Reactive matrix. U ttb4l Mutiphasic sanrples ntn as one analvsis per client. .1 ljor triirl btrnr siunplcs. arc sa:nple resrrlts lr<lnr tlre silnrc tvaste l'eed consistcnt'l (Spread o[ values < 20o/o of il\'8. ) D ltbsl Related PT data show similar variation. D [tb6l Extremely volatile materials suspected. O [tb7] Samples obviously impure (e.g., cloudy, biphasic 4. For trial bum sanrples, do the results agree within l0% of the knowu or presunred values? Cummcn t.s: * Suuh lutit-ru l)rrrst be takerr iu consu]tation rvith client. Norrconlonriirnuc lt)clllos arc required lbr bold and iral ic'izul [autotestJ statenrents: Bold wc08{R0.DOC ,9122t05 = deficiency, italicized = anornoly. 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I r- l -l -l - 3i : l e E$ s E (JEE € A t\olsI(r2rl3od7Nsur \na Irl tu@IdoJAao(r )Eot )V' ()J 53 1 \oo\n(t )Ec{dFI f-o()B IJ.lollllll \ot- { -. \- r , .- rV I SH .. E * A2 EM 'E f r FO ta9€ IIA. u) HE (l ) 0 ) =u D E. s HS /J r t 3*. ,otd ]c , -l_ol .gJa Ap p e n d i x F - s3 0 IoJ tD !.llEHEoU{aq) .Joz t)JrU)o(AaaUJ 532STL Knoxville Dionex IC Runlog Cover Page I nst ru nrcnt: ficr,q ci'1r ")-, frDx-orttr Methotl:al KNox-wc-(x)()3. sw-8{6 006 I /7 19..) f ICS- Ii(XI L I)X-20 - KNOX-\UC-(X)t{- l.:PA 3 t4.() I nstru nr crt t Colr dition.\ Flou'Ratc= i,D rtrL/ntirt Corrducti)nce= rf7.,{80 trs Supprcssor Current = t{l ntA Elucnt GenerAtor = hJ A rtrM KOH Prcssurc= -/.05c1 , psi N{S/IVISD Sp ilic Inl o rmittion Conrrncnt.s:/+.rl f1crn^ t .Ltor i '^c ot.Acs Finitl Conc. \\/c075Rl.6lt li()l Prcyen tiye IVI :ri ntcn iur cc Ditil'r': Gr(tr..k punrp and gas pressure flCtrcck atl lincs for crinrping. leaks aucl discoloration Ar.I!.c-e-ile_d, f Cltange colunrrl artd guard colunrrr f Change colunul and/or guard colunur bcd support U Clcltn conductivit]' cell I Dc-gils puntp hcad n']ren flon' is crratic I Chcclt/rcplace cluant end line filter Contpourtd Spike ID Parcrtt Conc.Spike Added (nrl-)Final Voluruc (nrl-) endi 531 ! Sodirrur Thiosullatc:rddcd to NaOH inrpinger sarrfl Sequence: Operator: C06A_ANtONS_030606 kaukerc s33 Pase t ot//- Printed: 3f712006 9:28.37 AM Title: Datasource: Location. Timebase: #Samples: Aragorn_net IC-ARAGORN lCJragorn 42 Created: Last Update: P))L 3t1 l' "3161200O 10:06:39 AM by wheelerd 31612006 4'.47:A0 PM by kaukerc No,Narne Sample lD lnj. Vol.lnj. Date/Time Dil. Factor 'Multiplier ILiters] Weight 1 6 cAL srD #1 = rcws-7e4s 50.0 1t11l2006 432 20 PM 1.0000 1.0000 2 ffi cAL srD #z= rcws-7946 50.0 1fi1n006 5:02 45 PM 1.0000 1.0000 3 E cAL srD #3 = tcws-7947 50.0 1fi1i2OOG 5:33:1 1 PM 1.0000 1.0000 4 ffi cAL srD #4 = rcws-7948 50.0 1t11t2006 6.03.36 PM 1 0000 1.0000 5 ffi cAL srD #5 = rcws-7944 50.0 1111X2006 6:34:02 PM 1 .0000 1.0000 6 6 cAL srD #6 = rcws-7949 50.0 1l11nAA67:O4:27 PM 1 0000 1.0000 7 ffi tcv = tcws -s142 50.0 3/612006 10:08:39 AM 1.0000 1.0000 8 ffi rcv/DUP= tcws€143 50.0 3rcr2006 10:26:04 AM 1.0000 1.0000 o ffi rcB 50.0 3/6/2006 10:43:30 AM 1 0000 1.0000 10 ffi BoMB BLK= HocATIAA 50.0 3l6l2OOG 11:00:55 AM 1.0000 1.0000 11 ffi BoMB LCS= HoGTAIAc-1/10 50.0 3/6/2006 1 1:18:20 AM 10.0000 1.0000 12 ffi H6B2oo1 64-Hxe1 xlAD-1 /50 50.0 31612006 11:35:46 AM 50.0000 1.0000 13 H682001 64-HXQ1X1AD-1 /1 00 50.0 31612000 1 1:53:11 AM 100.0000 1 0000 14 A H6B2oo1 64-HXe1x1AB-DuP-1/1 oo 50.0 316l?00O 12:10:37 PM 100.0000 1.0000 15 A H6B2oo1 64-HXe1x1A6-MS-1/1 oo 50.0 3tOl2O06 12:28:02 PM 100.0000 1.0000 16 6 HoB2ool 64-HXo1x1A7-MSD-1 /1 oo 50.0 3B2OAG 12:45.28 PM 100.0000 1.0000 17 6 ccv= tcws-a144 50.0 3/612006 1:02:53 PM 1,0000 1.0000 1B CCB 50.0 3l6n0AG 1:20:18 PM 1.0000 1 0000 19 A H6B2oo1 64-HXe2D1 AD-1 /1 oo s0.0 31612006 1.37:44 PM 100.0000 1.0000 20 ffi H6B2oo164-HXezFl AD-1/1 oo 50.0 UG2OO6 1:55:09 PM 100.0000 1.0000 21 ffi H6B2oo164-HXo2H 1 AG- 1 /1 oo 50.0 3t6t2006 2.12:35 PM 100.0000 1 0000 22 ffi H6B2oo164-HXo2J1AD-1/1oo 50.0 3/6/2006 2:30:00 PM 100.0000 1.0000 23 ffi H6B2oo164-HXe2K1AD-1/1oo 500 3rc12}06 2:47 .26 PM 100.0000 1 0000 24 ffi H6B2oo164-Hxe2M1AG-1/1 oo 500 3;16120063:04:51 PM 100.0000 1.0000 25 ffi H6B2oo164-HXo2P1AD-1i1oo 50.0 3/6/2006 3:22.16 PM 100.0000 1.0000 26 ffi H6B2oo1 64-HXe201AD-1 /1 oo 50.0 31612006 3:39:41 PM 100.0000 1.0000 27 A H6B2oo1 64-Hxe2v1AG-1/i oo 50.0 31612006 3:57:07 PM 100.0000 1.0000 28 A H6B2oo1 64-HXe1 x1 A7-MSD-1 /1 oo 50.0 31612406 4:1 4:32PM 100.0000 1.0000 29 ffi ccV= tcws-a144 50.0 3t012006 4:30:57 PM 1.0000 1.0000 30 ffi ccB 50.0 3rcnOOO 4:47:23 PM 1.0000 1.0000 31 6 H6B2oo1 64-HXe2o1AD-111 oo 50.0 3t612006 5.03 48 PM 100.0000 1.0000 32 A HoBzool 64-Hxe2olAE-DUP-1/1 oo 50.0 31612006 5:20:14 PM 100.0000 1 .0000 33 A H6B2oo1 64-HXezzlAD-1r1 oo 50.0 3rcn306 5:36:39 PM 100.0000 1 .0000 34 A H6B2oo1 64-HX ez41AG-1/1 oo 50.0 31612006 5:53:05 PM 100.0000 1.0000 35 ffi H6B2oo1 64-HXe2s1AD-1/1oo 500 31612006 6:09:30 PM 1 00 0000 1 0000 36 ffi H6B2oo1 64-HXezBl AD-l/1oo 50.0 3/6/2006 6:25:55 PM 100.0000 1.0000 37 ffi H6B2oo1 64-HXo3D1AG-1/1 oo 500 3/6/2006 6.42"21 PM 100.0000 1 0000 38 A H6B2oo1 64-HXo3E1AD-1/1 oo 500 3/612006 6:58.47 PM 100.0000 1.0000 39 ffi H6B2oo1 64-HXo3F1AD-1 tloo 50.0 31612006 7:15:12 PM 100.0000 1.0000 40 ffi ccv= tcws-8144 500 31612006 7:31 :38 PM 1 .0000 1.0000 41 ffi ccB 500 316l?006 7:48:04 PM 1 .0000 1 0000 Appendix F - Chrorneleon @ Dionex Corporation, Version 6.50 SP4 Build 10ffi2 Sequence: Operator: C06A_AN10NS_030606 kaukerc 'r^,+1: n Page3.e74 Printed: 3ff l20OG 9:28:37 AM Title: Datasource: Location: Timebase: #Samples. Aragorn_net TCJRAGORN lC_Aragorn 42 ItU,e- 317 l,t, Created: Last Update: 3rcn00610:06:39 AM by wheelerd 3/612006 4:47:00 PM by kaukerc No.Narne Sample lD ln1. Vol.lnj. Dateffime Dil, Factor 'Multiplier ILitersJ Weight 42 ffi sHUrDowN 50.0 3/6/2006 8:04:30 PM 1.0000 1.0000 Appendix F - Chromeleon @ Dionex Corporation, Version 6.50 SP4 Build 10093 3 ICV = ICWS-81 42 Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time. Run Time (min): ICV = ICWS-8142 103 unknown ANIONS-AS14A ANIONS 31612006 10:08 15.00 lnjection Volume: 50.0 Channel: ECD_1 Wavelength: n.a. Bandwidth.' n,a. Dilution Factor: 1.0000 Samp/e Weight: 1.0000 Sample Amount: 1.0000 Operator:wheelerd Timebase:lC_Aragorn Sequence:C06A_ANIONS_030606 Appendix F - 534 535 Page 1-1 3/6/2006 10:47 AM 103,52(l- Chromeleon (c) Dionex 1996-2001 Version 6.60 Build 1 428 030606 #7 [modifi No.Ret.Time (min.) Peak Name Height (uS) Area uS*min Rel.Area 1%l Arnount (rnq/L) Peak Type 1 3.28 Fluoride 2.98520 0.389 6.87 0.9565 BMB 2 4.82 Chloride !----16.006e5 2.158 38.1 4 7,7636 BM 3 s.69 Nitrite-N 18.36000 3.1 11 54.99 5.0653 MB d efa u lt_lette r/l nteg rat i o n o Operator:wheelerd Timebase: lC_Aragorn Sequence:C06A_ANIONS_030606 Appendix F - 535 536 Page 1-1 3/6/2006 10:48 AM t0L?, & Chrorneleon (c) Dionex 1996-2001 Version 6.60 Build 1428 ICV/DUP= ICWS-8143 Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): ICV/DUP= ICWS-8143 104 unknown ANTONSJSl4A ANIONS 31612006 10:26 1 5,00 lnjection Volume: 50.0 Channel: ECD_1 Wavelength: n.a. Bandwidth.' n.a. Dilution Factor: 1.0000 Sample Weight: 1.0000 Sample Amaunt: 1.0000 No.Ret.Time (rnin.) Peak Narne Height (uSl Area uS*min Rel,Area ('/rl Amount (mq/L) Peak Type 1 3.28 Fluoride 2.991 10 0.392 6.80 0.9583 BMB 2 4,82 Chloride ----16.43889 2.205 38.24 7.9481 BM* 3 5.69 Nitrite-N 18.66820 3.170 54.97 5.1 439 MB" defa u lt_letter/l nteg ration Operator:wheelerd Timebase:lC_Aragorn Sequence:C06A_ANIONS_030606 s37 Pag e 1-1 3t6t2006 11.11 AM tcB Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): lcB 105 unknown ANIONS-AS14A ANIONS 3/6/2006 10:43 15.0$ lnjection Volume: 50.0 Channel: ECD-1 Wavelength: t1.a. Bandwidth.' n.a. Dilution Factor: 1.0000 Sample Weight: 1.0000 Sample Amount: 1.0000 No,Ret.Tirne (rnin.) Peak Name Height (uS) Area uS*min Rel.Area (%l Arnount (rnq/L) Peak Tvpe Appendix F - s36 Chromeleon (c) Dionex 1996-2001 Version 6.60 Buitd 1428d efa u lt_l etter/l nteg rati o n 10 BOMB BLK= HOGATIAA Sample Name: Vial Number: Sample Type: Control Program: Quantif. M'ethod: Recording Time: Run Time (min): BOMB BLK= H0GATIAA 139 unknown ANIONS-ASI4A ANIONS 31612006 11:00 15,00 lnjection Volume. 50.0 Channel: ECD_1 lNavelength: It.a. Bandwidth.' n.a. Dilution Factor: 1.0000 Sample Weight: 1.0000 Sample Amount: 1.0000 Operato r:wh ee I erd Ti m e base : lC_Arago rn Sequen ce : C06A_AN I ONS_030606 53 B Page 1-1 3/6/2006 11,26 AM Chromeleon (c) Dionex 1996-2001 Version 6.60 Build 1428 Appendix F - 537 3- Nitrite-N -5.700 1 - 3.834 No.Ret.Time (min.) Peak Narne Height (uS) Area uS*min Rel.Area (%l Arnount (mq/L) Peak Type 1 3.83 n.a.0.1 3300 0.019 0.01 n.a.BMB 2 4.88 Chloride 0.81 186 0.195 0.12 0.44e9 BM 3 5.70 Nitrite-N 30.061 15 5.051 3.02 7.931 1 MB 4 7.78 n.a.161 .990 96.78 n.a.BMB 5 12.7 0 Sulfate 0.36653 0.120 0.07 0.6259 BMB d efa u lt_l ette r/ I nteg ratio n Operato r:wheel erd Time base : lC_Arago rn Seq uence :C06A_AN I ONS_030606 s39 Page 1-1 3/6/2006 11:37 AM Chromeleon (c) Dionex 1996-2001 Version 6.60 Build 1428 Appendix F s38 11 BOMB LCS= HOGTA1AC-1110 Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recarding Time: Run Time (min): BOMB LCS= HOGTA1AC-1/10 140 unknown ANIONS-AS14A ANIONS 3lil2406 11:18 15.00 lnjection Volume, 50.0 Channel: ECD_1 Wavelength: I'l.a. Bandwidth: n.a. Dilution Factor: 10.0000 Sample Weight: 1.0000 Sample Amount: 1.0000 ,/ IONS_030606 #11 [rnodified by wheelerdl No.Ret.Tirne (min.) Peak Name Height (uS) Area uS*min Rel.Area (Yol Amount (mq/L) Peak Type 1 3.28 Fluoride 12,01823 1 .463 7.90 35.4488 BMB 2 4.82 Chloride /21 ,78387 3.054 16.50 101 .5190 BMB 3 5.68 N trite-N 2.56784 0.434 2.34 7.6065 Rd 4 7.96 N trate-N 59.57963 13.545 73.1 6 154.6049 BMB 5 12.70 Sulfate 0.05861 0.018 0.1 0 0.9537 BMB d efa u lt_l etter/l nteg rati o n 1 3 H682001 64-HXQ1 X1AD-1I1 00 Samp/e Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): H6B2001 64-HXQ1 Xl AD-1 1100 142 unknown ANTONSJSl4A ANIONS 31612006 11 :53 15.00 lnjection Volume: Channel: Wavelength: Bandwidth: Dilution Factor: Sample Weight: Sarnple Amount: 50.0 ECD-I n.a. J^J.4. 100.0000 1.0000 1.0000 Operator:wheel erd Timebase: I C_Arago rn Sequence : C06A_AN I ONS_030606 540 Page 1-1 316/2006 12:31 PM Chromeleon (c) Dionex 1996-2001 Version 6.60 Build 1428 Appendix F s39 H682001 64-HXO1 X1 AD-1 /1 00 Ret.Time Rel.Area 833.7186Chloride17.35781 Nitrate-N 165.6346 default letter/lnteg ration 14 H6B200164-HXQ1 X1A8-DUP-1/100 Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): H682001 64-HXQ1 X1 A8-DUP-1 /1 00 143 unknown ANIONS-AS14A ANIONS 31612006 12:10 I 5.00 lnjection Volume: Channel: Wavelength: Bandwidth: Dilution Factor: Sample Weight: Sample Amount: 50.0 ECD-1 11.4. Jl.4. 100.0000 1.0000 1.0000 O perator:wheelerd Ti mebase : IC_Aragorn Seq ue nce :C06A_AN ION S_030606 Appendix F 540 541 Page 1-1 3/6/2006 12:33 PM Chrorneleon (c) Dionex 1996-2001 Version 6.60 Build 1428 20.c06A ANIONS 030606 #14 H6 8200 1 64- HXQ 1 X1 AB- D U P- 1 /1 00 Ret.Tirne Peak Name Height Rel.Area Amount Chloride 17.46025 838.0288 Nitrate-N 4.41435 163 .5173 d efa u lt_l ette r/l nt eg rat io n 1 5 H682001 64-HXQ1X1A6-MS-1/1 00 Sample Name: Vial Number: Samp/e Type: Control Program: Quantif. Method: Recording Time: Run Time (min): H682001 64-HXQ1 Xl A6-MS-1 /1 00 144 unknown ANTONSJSI4A ANIONS U6l2A05 12:28 15.00 lnjection Volume: Channel: Wavelength: Bandwidth: Dilution Factor: Sample Weight: Sample Amount: 50.0 ECD_1 n,a. n.a./ 100.0000 / 1.0000 1.0000 Operator:wheelerd Ti m e base: I C_Aragorn Seq uen ce : C06A_AN I ONS_030606 542 Page 1-1 31612006 12:49 PM H682001 64-HXQ 1 X1 A6-M S-1 /1 00 Appendix F - s4t Chromeleon (c) Dionex 'l 996-2001 Version 6.60 Build 1 428 'l -Fluoride-3.?75 No.Ret.Time (rn in. ) Peak Narne Height (uS) Area uS*min Rel.Area (o/ol Amount (mq/L) Peak Type 1 3.28 Fluoride 1.02541 0123 3.1 0 33.5493 BMB 2 4.82 Chloride ,/19.81639 2.737 69.07 935.6906 BMB 3 8.07 Nitrate-N 4.71844 1.103 27.83 17 4.2056 BMB defa u lt-l ette r/ I nteg rati on 1 6 H682001 64-HXQlXl A7-MSD -1t100 Sample Name: Vial Number: Sample Type: Control Prograrn: Quantif, Method: Recording Time: Run Time (min): H682001 64-HXQ1 X1 A7-MSD-1 /1 00 145 unknown ANIONS-AS14A ANIONS 3/6/200 6 12:45 15.00 Injection Volume: Channel: Wavelength: Bandwidth: Dilution Factor: Sample Weight: Sample Amount: 50.0 ECD-1 n.a. n.a. 100.0000 1.0000 1.0000 Ope rator:wh eele rd Ti me base : I C_Arag o rn Seque nce : C06A_AN I O N S_030606 543 Page 1-1 3/6/2006 1:04 PM Chromeleon (c) Dionex 1996-2001 Version 6.60 Build 1428d efa u lt_lett er llnte g rati on Appendix F 542 H682001 64-HXQ1 X1A7-MS D-1 /100 No.Ret,Time (min.) Peak Name Height (uS) Area uS*rnin Rel.Area flol Amount (mq/L) Peak Tvpe 1 3.28 Fluoride 1.03251 0.141 3.63 33.7790 BMB 2 4.82 Chloride ,/19.41 929 2.680 69.0s 919 .4240 J 8.07 Nitrate-N 4.57814 1.060 27.32 16s .2826 BMB 17 CCV= ICWS-81 44 Sample Name: Vial Number: Sample Type: Control Program: Quantif. Methad: Recording Time: Run Time (min): CCV= ICWS-8144 146 unknown ANTONS.ASI4A ANIONS 31612006 13:02 15.00 lnjection Volume: 50.0 Channel: ECD_I Wavelength: n.a. Bandwidth.' n.a. Dilution Factor: 1.0000 Sample Weight: 1.0000 Sample Amount: - 1,0000 Operator:wheelerd Timebase:lC_Aragorn Sequence:C06A_ANIONS 030606 Appendix F - 543 544 Page 1-1 3/6/2006 1"44 PM bilt Chromeleon (c) Dionex 1996-2001 Version 6 60 Build 1428 030606 #1 7 CCV= ICWS-8144 3-Chloride-4.81 2 - Fluoride - 3.284 No.Ret.Time (min.) Peak Name Height (uS) Area uS*min Rel.Area (o/ol Amount (mq/L) Peak Tvpe 1 2.20 n.a.0.20111 0.033 0.37 n.a.BMB 2 3.28 Fluoride 8.1 8841 1.034 11 .47 2.49s6 BMB 3 4.82 Chloride "/22.6s240 3.014 33.43 10.4972 BM 4 5.69 N trite-N 28.78972 4.868 53.99 7.6306 MB 5 8.12 N trate-N 0.0s421 0.021 0.23 0.0367 BMB b 14,46 n.a.0.24425 0.045 0.50 n. a.BMB d efa ult_letter/l nteg ration Operator:wheelerd Timebase: lCJragorn Sequence:C06A_ANIONS_030606 Appendix F - 544 545 Page 1-1 316/2006 1:45 PM Chromeleon (c) Dionex 1996-2001 Version 6 60 Build 1428 18 CCB Sample Name: Vial Number: Samp/e Type: Control Program! Quantif. Method: Recording Time: Run Time (min): ccB 147 unknown ANIONS-AS14A ANIONS 31612006 13:20 15.00 lnjection Volume: 50.0 Channel: ECD_1 Wavelength: n.a. Bandwidth.' 11.a. Dilution Factor: 1.0000 Sample Weight: 1,0000 Sample Amount: 1.0000 c06A ANTONS 030606 #18 No.Ret.Time (min.) Peak Name Height (uS) Area uS*min Rel.Area (%l Amount (mq/L) Peak Tvpe 1 0.84 n.a.0j7260 0.041 100.00 n.a.BMB defa u lt_l ette r/l nte g ratio n Operator:wheelerd Timebase:IC_Aragorn Sequence:C06A_ANlONS_030606 546 Page 1-1 3i6l2006 2:00 PM Chrorneleon (c) Dionex 1996-2001 Version 6,60 Build 1428 Appendix F - s45 1 9 H682001 64-HXQ2D1 AD -1 11 00 Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): H682001 64-HXQ2Dl AD-l /1 00 148 unknown ANIONS_AS14A ANIONS 3/6/2006 1 3:37 15.00 lnjection Volume: Channel: Wavelength: Bandwidth: Dilution Factor: Sample Weight: Sample Amount: 50.0 ECD-1 n.a. n.a. 100.0000 1.0000 1.0000 c06A ANIONS 030606#19 H682001 64-HXQ2 D1 AD-1 /1 00 1.50 2.00 No.Ret.Tirne (min.) Peak Name Height (uS) Area uS*rnin Rel.Area (%l Amount (rnq/L) Peak Type 1 4.82 C hloride /16.44824 2.306 73.3s 795.2041 BM 2 5.68 N trite-N 0.09572 0,017 0.55 2.8715 MB 3 8.08 N trate-N 3.39914 0.795 25.29 127.3363 BMB 4 12.74 Sulfate 0.08479 0.025 0.81 13.2834 BMB defa u lt_letter/lntegratio n O perator:wheelerd Ti mebase : I C_Aragorn Sequence : C06A_AN I ONS_030606 H6 82001 64-HXQ2F1 AD-1 /1 00 1.50 2,00 547 Page 1-1 3/6/2006 2:15 PM Chromeleon (c) Dionex 1996-2001 Version 6.60 Build 1428 Appendix F - s46 20 H6B.200 164-HXQ2F1 AD -1 t100 t Channel: Wavelength: Bandwidth: Dilution Factor: Sample Weight: Sample Amount: Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): H682001 64-HXQ2F1 AD-1 /1 00 149 unknown AN]ONS-ASl4A ANIONS 31612006 13:55 15.00 50.0 ECD-l n.a, n.a. 100.0000 1.0000 1.0000 No.Ret.Time (min.) Peak Name Height (uS) Area uS*min Rel,Area (%) Arnount (rnq/L) Peak Tvpe 1 4,82 Chloride J 17 .97 517 2.509 75,99 859.61 16 BM 2 5.68 Nitrite-N 0.06788 0.012 0.36 2.4364 MB 3 8.08 Nitrate-N 3.35342 0.781 23.65 125.6882 BMB defau lt_letter/lnteg ratio n O pe rato r:wh e el erd Timebase : lC_Arag orn Seq u e nce: C06A_ANIO NS_030606 Appendix F - 547 548 Page 1-1 3/6/2006 2:35 PM Chromeleon (c) Dionex 1996-2001 Version 6.60 Build 1428 21 H68200164-HXQ2H1 AG-1t1 00 Sample Name: H68200164-HXQ2HI AG-l/100 Vial Number: 150 Sampte Type: unknown Contral Program: ANIONSJS14A Quantif. Method: ANIONS Recording Time: 316/2006 14212 Run Time (min): 15.00 lnjection Volume: Channel: Wavelength: Bandwidth: Dilution Factor: Sample Weight: Sample-Amount: 50,0 ECD-1 n.a. Jl.4. 100.0000 1.0000 'l .0000 Ret,Tirne Peak Narne Height Rel.Area Amount Chloride 16.60973 802.0744 Nitrate-N 3.1 5604 1 18.s551 d efa u !t_l ette r/l nte g rat i on Operator:whe el erd Ti me base: I C_Arago rn Seq u e nce:C06A_AN I O NS_0306 06 c06A ANTONS 030606 #22 H682001 64-HXQ2J 1 AD- 1 /1 00 549 Page 1-1 3/6/2006 2:51 PM Chromeleon (c) Dionex 1996-2001 Version 6.60 Build 1 428 Appendix F - 548 22 H68200164-HXQ2J1AD-1 tl 00 Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): H682001 64-HXQ2J1 AD-1 t100 151 unknown ANTONS-.ASl4A ANIONS 31612006 14:30 15.00 Injection Volume: Channel: Wavelength: Bandwidth: Dilution Factor: Sample Weight: Sample Amount: 50.0 ECD-1 n.a. n.a, 100.0000 1.0000 1.0000 No.Ret.Time (rnin.) Peak Narne Height (uS) Area uS"min Rel.Area (%) Amount (mo/L) Peak Tvpe 1 4.82 Chloride (16.02339 2.249 7 4.35 777.0612 BMB 2 8.07 Nitrate-N 3.21924 0.753 24,90 120.8424 BMB 3 12.70 Sulfate 0.47527 0.023 0.75 1 1 .9018 BMB defa u lt_lette r/l nteg ration Operator:wheelerd Timebase:lC_Aragorn Sequence:C06A_ANIONS_030606 c06A ANTONS 030606 #23 H68200164- 1.50 2.00 Appendix F s49 s50 Page 1-1 3/6/2006 3:07 PM Chromeleon (c) Dionex 1996-2001 Version 6.60 Build 1428 23 H682001 64-HXQ2K1AD -1 t100 Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): H6B2001 64-HXQ2K1 AD-1 /1 00 152 unknown ANIONS-AS14A ANIONS 31612006 14:47 15.00 lnjection Votume: Channel: Wavelength: Bandwidth: Dilution Factor: Sample Weight: Sample Amount: 50.0 ECD-l n.a, n.a. 100,0000 1.0000 1.0000 Ret,Time Peak Name Rel.Area Amount 884.2918Chloride18.56800 Nitrate-N 3.45897 129.4902 defa u lt_lette r/l nteg ratio n Operator:wheelerd Timebase:lC_Aragorn Sequence:C06A_ANIONS_030606 H682001 64-HXQ2M 1 AG- 1 I 1 00 551 Page 1-1 3/6/2006 3:41 PM Chrorneleon (c) Dionex 1996-2001 Version 6.60 Build 1428defau lt -letter/l nteg ration Appendix F - s50 24 H68200 164-HXQ2M1AG-1t1 00 Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): H68200 1 64-HX82M1 AG-1 /1 00 153 unknown ANIONS-AS14A ANIONS 31612006 15:04 15.00 lnjection Volume: Channel: Wavelength: Bandwidth: Dilution Factor: Sample Weight: Sample Amount: 50.0 ECD-1 J1.4. n.a, 100.0000 1.0000 1.0000 Ret.Time Peak Name S*min ArnountHeightRel.Area Chloride 13,281 04 057.4784 Nitrate-N 3.30882 124.0791 O perator:wheele rd Ti mebase : lC_Aragorn Sequence : C06A_AN I ONS_030606 552 Page 1-1 3/6/2006 3:41 PM Chromeleon (c) Dionex 1996-2001 Version 6.60 Build 1428 Appendix F - 551 25 H68200 164-HXQ2P1 AD-1t100 Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): H682001 64-HXQ2Pl AD-l /1 00 154 unknown ANTONS,.ASI4A ANIONS 31612006 15:22 15.00 lnjection Volume: Channel: Wavelength: Bandwidth: Dilution Factor: Sample Weight: Sample Arnount: 50.0 ECD-1 n.a. n.a. 100.0000 1.0000 '1 .0000 H682001 64-HXQ2 P1 AD-1/1 00 1.50 2.00 No.Ret.Time (min.) Peak Name Height (uS) Area uS*rnin Rel.Area (%l Amount (mq/L) Peak Tvpe 1 4.83 Chloride 1/13.48521 1.914 74.67 666.s351 BMB 2 8.08 Nitrate-N 3.31653 0.774 28.58 124.3s73 BMB 3 12.70 Sulfate 0.06836 0.020 0.75 10.6593 BMB d efa u lt_lette r/ I nteg ration Ope rato r:wh eel erd Timebase : lC_Arag o rn Sequence: C06A_AN I ONS_03 0606 Appendix F 552 s53 Page 1-1 3/6/2006 4.14 PM Chromeleon (c) Dionex 1996-200'1 Version 6.60 Build 1 428 26 H682001 64-HXQ2Q1AD-1 /1 00 Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): H6 82001 64-HXQ2Q1 AD-1 /1 00 155 unknown ANIONS-AS14A ANIONS UA2A06 15:39 15.00 lnjection Volume: Channel: Wavelength: Bandwidth: Dilution Factor: Sample Weight: Sample Amount: 50.0 ECD-1 n.a. n.a. 1 00,0000 1.0000 1.0000 18.0 c06A ANTONS 030606 #26 H682001 64-HXQ2Q 1 AD-1/100 ECD 1 16- 14. 12. 10- 8. 6. 4. 2. o. -2. 1.50 2.00 No.Ret.Tirne (min.) Peak Narne / Height (uS) Area uS*rnin Rel.Area f/'l Amount (mq/L) Peak Type 1 4.82 Chloride v 15.96063 2.270 72.91 774.3729 BM 2 5.69 Nitrite-N 0.07901 0.013 0.43 2.3703 MB 3 8.07 Nitrate-N 3.52246 0.830 26.66 131 .7733 BIVIB d efa u lt_lett er llnteg ratio n Operator:wheelerd Timebase: lC_Aragorn Sequence:C06A_ANIONS_030606 Appendix F - 5s3 554 Page 1-1 3/6/2006 4"15 PM Chromeleon (c) Dionex 1996-2001 Version 6.60 Build 1428 27 H682001 64-HXQ2V1 AG -1 1100 Sample Name: VIal Number: Samp/e Type: Control Program: Quantif. Method: Recording Time: Run Time (min): H682001 64-HXQ2VI AG-1 /1 00 156 unknown ANTONSJSl44 ANIONS 31612006 15:57 15,00 lnjection Volume: Channel: Wavelength: Bandwidth: Dilutian Factor: Sample Weight: Sample Amount: 50.0 ECD-1 n.a. n,a. 100.0000 1.0000 1.0000 c06A ANTONS 030606 #27 H682001 64- HXQ2V1 AG-1 /1 00 1-Chloride-4.808 No.Ret.Time (rn in.) Peak Name Height (uS) Area uS*min Rel.Area t%l Amount (rnq/L) Peak Tvpe 1 4.81 Chloride (12,151 15 1,745 67.46 606,8884 BM 2 5.68 N trite-N 0.07466 0.01 5 0.56 2.2398 MB 3 8.06 N trate-N 3.57838 0.827 31 .98 133.7810 BMB defau lt_lette r/l nteg ration 29 CGV= lC\ryS-8l 44 Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): CCV= ICWS-8144 158 unknown ANIONS-AS14A ANIONS 31612006 16:30 14.00 lnjection Volume: 50,0 Channel: ECD_1 Wavelength: n.a. Bandwidth.' n.a. Dilution Factor: 1.0000 Samp/e Weight: 1.0000 Sample Amount: 1.0000 O perato r: ka ukerc Timebase: I C_Aragorn Seq uence :C06A_AN lON S_030606 Appendix F - 554 5s5 Page 1-13 31712006 9:30 AM /orl,* Chromeleon (c) Dionex 1996-2001 Version 6.50 SP4 Build 1000 No.Ret.Time (min.) Peak Name Height (uS) Area uS*min Rel.Area (olol Amount (mq/L) Peak Tvpe 1 2.20 n. a.0.20379 0.033 0.36 n.a.BMB 2 3,28 Fluoride 8,42033 1 .057 11 .56 2.5610 BMB 3 4.82 Chloride /22.96926 3.081 33.66 10.6224 BM 4 5.69 Nitrite-N 29.52442 4.961 54.21 7-804s MB 5 8.1 1 Nitrate-N 0.08992 0.019 4.21 0.0350 BMB defa u lt_letter/l nteg ration 30 CCB Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): ccB 15e unknown ANIONS-AS14A, ANIONS 3/6/2006 16:47 14.00 lnjection Volume: 50.0 Channel: EGD_1 Wavelenglh: n.a. Bandwidth.' n.a. Dilution Factor: 1.0000 Sample Weight: 1.0000 Samp/e Amount: 1.0000 O perato r: kau kerc Tim e base : I CJragorn Seq uen ce:C06A-AN I ONS_03 0606 LI-q Appendix F - 555 556 Page 2-13 31712006 9:30 AM Chromeleon (c) Dionex 1996-2001 Version 6.50 SP4 Build 1000 c06A ANTONS 030606 #30 0.012 -0.000 I - 2.534 2 -Chloride -5.133 tilt,l !/ rnin No,Ret,Tirne (min.) Peak Name Height (uS) Area uS*min Rel.Area %t Arnount (mq/L) Peak Type 1 2.53 n.a.0.06101 0.01 3 s5.3s n.a.BMB 2 5.13 Chloride 0.04234 0.01 1 44,65 0.0237 BMB defa u lt_l ette r/ I nteg ratio n 31 H6B200164-HXQ20 1AD -1t100 Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): H682001 64-HXQ20 1 AD-1 /1 00 160 unknown ANIONS-ASI4A ANIONS 31612006 17:03 14.00 lnjection Volume: Channel: Wavelength: Bandwldth: Dilution Factor: Sample Weight: Sample Amount: 50.0 ECD-1 Jl.a. n.a. 100.0000 1.0000 1.0000 Ope rato r: kaukerc Ti m e base: lC_Ara gorn Seq uen ce : C06A_AN I ONS_030606 030606 #31 H682001 64-HXO201 AD- 1 /1 00 1-Chloride -4.817 557 Page 3-13 31712006 9:30 AM Chromeleon (c) Dionex 1996-2001 Version 6 50 SP4 Build '1 000 Appendix F - s56 No.Ret.Tirne (min.) Peak Name Height (uS) Area uS*min Rel.Area (%l Arnount (mq/L) Peak Tvpe 1 4.82 Chloride /1 1 .80029 1 .727 68.83 591 .0126 BM 2 5.68 Nitrite-N 0,08198 0.016 0.64 2.4593 MB 3 8.06 Nitrate-N 3.28530 0,766 30,53 123.2297 BMB d efa ult_letter/lnteg ration 32 H68200164-HXQ201 AE-DUP-1/1 00 Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): H682001 64-HXQ201 AE-D U P-1 /1 00 161 unknown ANTONS-ASl4A ANIONS 3/6/2006 17:20 14.00 lnjection Volume: Channel: Wavelength: Bandwidth: Dilution Factor: Sample Weight: Sample Amount: 50.0 ECD-1 11.4. n.a, 100.0000 1.0000 1.0000 Operator:kau kerc Timebase: I C_Aragorn Seq uence.C06A_ANl ONS_O30606 Appendix F - s57 5sB Page 4-1 3 3n ,2AAO 9:30 AM / Chromeleon (c) Dionex 1996-2001 Version 6.50 SP4 Build 1000 c06A ANTONS 030606 #32 H68200164-HXQ201AE-DUP-1/100 1 -Chloride - 4.825 3-Nitrate-N-8.067 No,Ret.Tirne (min.) Peak Narne / Height (uS) Area uS*min Rel.Area (%l Amount (rnq/L) Peak Type 1 4.83 Chloride v 12.01421 1.748 67.91 600.7016 BM 2 5.69 Nitrite-N 0.06764 0.016 0.61 2.0292 MB 3 8.07 Nitrate-N 3.44146 0,810 31 .48 128.8602 BMB defa u lt_l ette r/l nt eg ratio n O peralo r: kau kerc Timebase : lC_Arag o rn Seq uence : C06A_AN I ON S_030606 Appendix F 558 030606 #33 H6 8200 1 64-HXQ221AD- 1 I 1 00 559 Page 5-13 3n /20A6 9:30 AM Chromeleon (c) Dionex 1996-2001 Version 6.50 SP4 Build 1000 / 33 H68200164-HXQ221 AD-1/1 00 Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): H6B 200 1 64-H XQ221AD -1 /1 00 162 unknown ANIONS-AS14A ANIONS 31612006 17:36 14.00 Injection Volume: Channel: Wavelength: Bandwidth: Dilution Factor: Sample Weight: Sample Amount: 50.0 ECD-1 Jl.4, n.a. 100.0000 1.0000 1.0000 No,Ret.Tirne (rnin.) Peak Name / Height (uS) Area uS*rnin Rel.Area (%l Amount (rnq/L) Peak Type 1 4.83 Chloride ,/15.67205 2.251 7 4.11 761.9825 BMB 2 8.08 Nitrate-N 3.37957 0,786 25.89 126.6309 BMB d efa u lt_letter/lnteg ratio n Ope rator: kau ke rc Timebase : I C_Aragorn Seq uence:C064_AN I ON5_030606 Appendix F - 559 560 Page 6-13 3n 12A06 9:30 AM Chromeleon (c) Dionex 1996-2001 Version 6.50 SP4 Build 1000 34 H68200164-HXQ241AG -1l1 00 Sample Name: Vial Number: Sample Type: Contral Program: Quantif. Method: Recording Time: Run Time (min): H682001 64-HXQ241 AG-1 /1 00 163 unknown ANIONS-AS14A ANIONS 3/6/2006 17:53 14.00 lnjection Volume: Channel: Wavelength: Bandwidth: Dilution Factor: Sampte Weight: Sample Amount: 50.0 ECD-1 n.a. n.a, 100.0000 1.0000 1.0000 H68200164-HXQ241A No,Ret.Time (min.) Peak Name Height (uS) Area uS*min Rel.Area (%l Amount (rnq/Ll Peak Tvpe 1 4.83 Chloride /11.49958 1.673 61.83 577.3418 BMB 2 8.07 Nitrate-N 4.45172 1.033 38.17 164.8344 BMB O defa u lt_lette r/lnteg ration Operator: kaukerc Ti m e base : lC_Aragorn Seq uence: C064-AN IONS_030606 030606 #35 H682001 64-HXQ25 1 AD-'l /1 00 2-Chloride-4.825 4-Nitrate-N-8.075 5 - Sulfate 551 Page 7 -13 3t7 t2006 9.30 AM Chromeleon (c) Dionex 1996-2001 Version 6.50 SP4 Build 1000 Appendix F 560 35 H682001 64-HXQ251 AD -1 tl 00 Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): H682001 64-HXQ251 AD-l/1 00 '164 unknown ANTONS-ASl4A ANIONS 31612006 18:09 14.00 lnjection Volume: Channel: Wavelength: Bandwidth: Dilution Factor: Sample Weight: Sample Amount: 50.0 ECD_l J1.4. n.a. 100 .oooo / 1.0000 1.0000 No.Ret.Tirne (rnin.) Peak Name Height (uS) Area uS*min Rel.Area (%) Amount (ms/L) Peak Type 1 3,83 n.4.0.05714 0.016 0.65 n.a.BMB 2 4,83 Chloride /11.15121 1.631 66.22 561 .4294 BM 3 5,69 Nitrite-N 0.091 15 0.014 0.58 2.7345 MB 4 B. OB Nitrate-N 3.37383 a.787 31.95 126.4242 BMB 5 12.68 Sulfate 0.04903 0 015 0.59 7,6361 BMB d efa ult_lette r/l nteg ration Operato r: ka u kerc Timebase : I CJrago rn Seq uence: C06A_AN ION S_030606 s62 Page 8-13 3n i2406 9:30 AM Chrorneleon (c) Dionex 1996-2001 Version 6 50 SP4 Build 1000 / Appendix F 561 36 H682001 64-HXQ281AD -1 1100 Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): H682001 64-HXQ281 AD-1 /1 00 165 unknown ANIONS-ASI4A ANIONS 31612006 18:25 14.00 lnjection Volume: Channel: Wavelength: Bandwidth: Dilution Factor: Sample Weight: Sample Amount: 50.0 ECD-1 n.a. n.a, 100.0000 1.0000 1.0000 No.Ret.Time ( rnin.) Peak Narne Height (uS) Area uS*min Rel,Area (%l Amount (mq/L) Peak Tvpe 1 4.82 Chloride ./15.78912 2.245 74.36 767.0143 BMB 2 8.07 Nitrate-N 3.34634 0.77 4 25.64 125.4330 BMB d efa u lt_lette r/l nte g rat i o n Operator:kaukerc Timebase:lC_Aragorn Sequence:C06A_ANIONS_030606 s63 Page 9-13 31712006 9:30 AM Chrorneleon (c) Dionex 1996-2001 Version 6.50 SP4 Build 1000 030606 #37 H6 82001 64-HXQ3D 1 AG-1 I 100 3-Chloride -4.817 5-Nitrate-N-8.058 - Nitrite-N - 5. d efa u lt_l ette r/l nt eg ratio n Appendix F 562 37 H682001 64-HXQ3D1 AG -1 11 00 Sample Name: Vial Number: Sampte Type: Control Program: Quantif. Method: Recording Time: Run Time (min): H682001 64-HXQ3D1 AG-1 /1 00 166 unknown ANTONS-AS14A ANIONS 31612006 18:42 14.00 lnjection Volume: Channel: Wavelength: Bandwidth: Dilution Factor: Sample Weight: Sample Amount: 50.0 ECD-1 11,a. n.a. r.oo. Ioao / 1.0000 1.0000 No,Ret.Time (min.) Peak Name Height (uS) Area uS*min Rel.Area (%l Amount (rnq/L) Peak Type 1 0.73 n.a.0.2s802 0.039 1.34 n,4.BMB 2 4.31 n.4,0.13225 0.424 0.84 n.a.BM 3 4.82 Chloride /11.97997 1.741 60.1 0 599.1 531 M 4 5.68 N trite-N 0.07095 0.012 0.43 2.1287 MB 5 8.06 N trate-N 4.62838 1.081 37.29 171 .0470 BMB 38 H68200164-HXQ3E1AD-1/100 Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): H682001 64-HXQ3El AD-1 /1 00 167 unknown ANTONS..ASl4A ANIONS 3/6/2006 18:58 14.00 lnjection Volume: Channel: Wavelenglh: Bandwidth: Dilution Factor: Sample Weight: Sample Amount: 50.0 ECD-1 11.4, n.a. 100.0000 1 .0000 1.0000 Ope rato r: kau kerc Ti m ebase: I C_Ara gorn Seq uence:C06A_AN I ONS_0306 06 Appendix F - 563 564 Page 10-13 3n 12A06 9:30 AM Chromeleon (c) Dionex 1996-2001 Version 6.50 SP4 Build 1000 / 030606 #38 H682001 64-HXQ3E 1 AD-1 t100 No,Ret.Time (min.) Peak Name Height (uSl Area uS*min Rel.Area (%l Amount (rnq/L) Peak Tvpe 1 4.82 Chloride /1 1 .147 80 1 .610 67.42 561 .2759 BMB 2 8.08 Nitrate-N 3.37720 0.778 32.58 126.5456 BMB d efa u lt_lett er llnteg rati o n Operator: kau kerc Timebase: I C_Aragorn Seq uence :C064_AN IONS_030606 Appendix F - s64 56s Page 1 1-1 3 31712006 9:30 AM Chromeleon (c) Dionex 1996-2001 Version 6.50 SP4 Build 1000 39 H682001 64-HXQ3F1AD -1t100 Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): H682001 64-HXQ3F1 AD-1 /1 00 168 unknown ANIONS-ASl4A ANIONS 31612006 19:15 14,00 lnjection Volume: Channel: Wavelength: Bandwidth: Dilution Factor: Sample Weight: Sample Amount: 50.0 ECD-1 n.a, n.a. 100.0000 1.0000 1.0000 030606 #3e H6B2OO164-HXQ3F1AD. No.Ret.Time (rnin.) Peak Name Height (uS) Area uS*rnin Rel.Area (%l Arnount (mq/L) Peak Type 1 4.81 Ghtoride J 16.59169 2.382 7 5,22 801 .3078 BM 2 5.68 Nitrite-N 0.06699 0.01 5 0.49 2.0099 MB 3 8.06 Nitrate-N 3.27607 0.769 24.30 122.8966 BMB defa u lt_lett erllntegration Operato r: kau kerc Ti m ebase : I C_Aragorn Sequence : C06A_AN IONS_030606 566 Page 12-13 3n n0A6 9:30 AM 40 CCV= ICWS-8 144 Sample Name: Vial Number: Sample Type: Control Program: Quantif. Method: Recording Time: Run Time (min): CCV= ICWS-8144 170 unknown ANTONSJSl4A ANIONS 31612006 19:31 14.02 lnjection Volume: 50.0 Channel: ECD_1 Wavelength: 11.a. Bandwidth.' n.a. Dilution Factor: 1.0000 Sample Weight: 1.0000 Sample Amount: 1.0000 030606 #40 CCV= ICWS-8144 4-Nitrite-N-5.683 ride - 4.808 2 - Fluori - Nitrate-N - 8.083 No.Ret.Time (min.) Peak Name Height (u$) Area uS*rnin Rel.Area (%l Amount (rnq/L) Peak Tvpe 1 2.19 n. a.0.20656 0.033 0.35 n.a.BMB 2 3.28 Fluoride 8.54924 1.074 11 .58 2.5972 BMB J 4.81 Chloride /23.02633 3.122 33.68 10.6449 BM 4 5.68 Nitrite-N 30.01423 5.020 54.16 7.9200 MB 5 8.08 Nitrate-N 0.0901 1 0.021 0.22 0.0351 BMB / rutlor Appendix F - s6s Chromeleon (c) Dionex 1996-2001 Version 6.50 SP4 Build 1000d efa u lt_lette r/l nte g ratio n Operator: kau ke rc Ti mebase: lC_Aragorn Sequence : C06A_AN I ONS_030606 567 Page 13-13 3t712006 9:30 AM 41 CCB Sample Name: Vial Number: Sample Type: Control Program: Quantif, Method: Recording Time: Run Time (min): ccB 171 unknown ANTONS..ASI4A ANIONS 31612006 19:48 14.00 lnjection Volume: 50.0 Channel: ECD_1 Wavelength: n.a. Bandwidth.' n.a. Dilution Factor: 1.0000 Sample Weight: 1.0000 Sample Amount: 1.0000 030606 #410.07 0.05 14,0 No.Ret.Time ( rnin.) Peak Name Height (uS) Area uS*min Rel.Area t%l Amount (mq/L) Peak Type Appendix F s66 Chromeleon (c) Dionex 1996-2001 Version 6.50 SP4 Build 1000defa u lt_lette r/l nteg rati o n ;co !a)).9o)d J:3,) -u a vUoF{0oHilnrdn,Or t4-caZfr l IoilhU) -- zH9 = )- { F F - r- \ h( xx = g; B F< / H Va bf ;L j - A/ t l\ -- \ JC1 - aD tr rr f tBFaOzr<v, Il IiloB']zlr l fr r froZo)r (F.&0.Hil0. 55 8 ca<) ooc\ OOUe(f ,&c" )UB f\ .oo Ei i .= o IL U st. l . r;i \J \s cIn ') (. nL- JJ\ SCtfo( aa tJ .r iIII 'E q)= l- . o '1 , r),S O \, / )0 ) (: r c 4=\o .3tiJ tnI-lni P"to R:. )o tnTT d1Cf \nto ')il , f- l \d \^f- .q() cc ) (t ) c =o o- u fCr (: r)1>,> t- . rxlr l o =c q o L. l (1 ,O. Ii. t \. r r -! ,\ ) .. < r 30ir .t \ Nu ^lIN.v 1 (' : > J \- -a . (: )s N\) f. *t ( )E( ) !. ) L fi 3 d.] r0 t\, lr t)i> . ( \N \ "\-) -{'. /IJ^ 1t$ OL - JRG) - r f; z .^}t lx ) ^, , .X , qg3.Jx. r(I -z3D'z*t -J \ ot3\ .\ J(5 - \l oc(r{ \. J \ s{).J , ln \N\- rJE rc=c ) OF |i o5z U 1 t! ! 'J - Cr " r2Z, I t- t - t .J -2 \.) '2 I tr - t .J -2 r\ '. ) -' 2 ko o€ z .- F . .JJ ]c' i cn nn€,h \ -A ': 3-)+ /\ ' v -. - A),:Aprn pe n ! fi aT, *NJ ti x F 7r - U<J \- co o\ O C! cn \tf , dc,oo(' l.xr!atrc)UUso Document Scanning Form Department: Division: Branch: Section: Facility Name: Facility Number: Tracking Number: Library Number: File Number: ln lOut: Item Date: Date Received: Subject: Privilege Point: Public Excalibur Library Name: Multiple Volumes: Volume Number: Volume Title: Scan Date: OCR Date: Who Done It Environmental Quality Solid and Hazardous \ilaste Hazardous Waste Branch Chemical Demil itarization S ection TOCDF uT5210090002 2006.02485 TOCDF OI27L I 07-18-2006 07-20-2006 Secondary Waste Demonstration Test Report for the Metal Parts Furnace Public ChemDemil Lib YES (oq) TOCDF 01271(ot) 07-26-2006 07-26-2006 REW