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HomeMy WebLinkAboutDSHW-2024-007783 RCRA Operation and Maintenance Report At Former Pennzoil Roosevelt Refinery The Pennzoil-Quaker State Company (PQS) d.b.a. SOPUS Products (Shell Oil Products US) EPA# UTD073093874 State of Utah Hazardous Waste Management Program August 13, 2024 Prepared by Hao Zhu Utah Department of Environmental Quality Division of Waste Management and Radiation Control 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 2 - OPERATION AND MAINTENANCE REPORT Dates of Inspection: June 25-26, 2024 Facility: The Pennzoil - Quaker State Company d.b.a. SOPUS Products Approximately 1312 West Highway 40, Roosevelt, Utah 84066 Duchesne County, Utah EPA# UTD073093874 Facility Contact: Buddy Bealer Shell Oil Products US (SOPUS) leroy.bealer@shell.com Facility Consultant: James Carrino, Project Manager AECOM James.Carrino@aecom.com Notification: RCRA Post-Closure Permit Applicable Regulations: State-issued RCRA Post-Closure Permit, 2014, as modified. Utah Hazardous Waste Management Rules, Utah Admin. Code (UAC) R315 Type of Inspection Operation and Maintenance Inspection Report of Annual Groundwater Monitoring Participants: Hao Zhu, Utah Division of Waste Management and Radiation Control (DWMRC) Ethan Upton, DWMRC Quinn Walker, AECOM Nathan Nicolodemos, AECOM Weather: Sunny, 80s-90s oF 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 3 - I. CREDENTIALS, PURPOSE AND SCOPE Staff of the Division Waste Management and Radiation Control (DWMRC) conducted a Resource Conservations and Recovery Act (RCRA) Operation & Maintenance (O&M) inspection on June 25-26, 2023 of the former Pennzoil Refinery (Site), in accordance with the Post-Closure Permit issued jointly to Pennzoil Quaker State Company d.b.a. SOPUS Products (Pennzoil) and Roosevelt Land Investment, LLC (RLI). This inspection was under the authority of Utah Solid and Hazardous Waste Act 19-6-109. Upon arrival on the morning of June 25, 2024, the DWMRC inspectors met Quinn Walker and Nathan Nicolodemos of AECOM, consultant to Pennzoil, who were performing the groundwater monitoring and Site inspection activities at the Site. The purpose and scope of the O&M Inspection was explained to the AECOM personnel as the evaluation of the annual groundwater sampling requirements and the Site conditions in accordance with the requirements of the former refinery's Post-Closure Permit (permit) that was first issued to Pennzoil in 1993 and renewed in 2004 and 2014. The current permit issued in 2014 added RLI as a co-permittee. The AECOM personnel also briefed the inspectors on their sampling/inspection plan and provided an update of the field work completed before the inspectors’ arrival. The June 2024 field activities included the semi-annual Site inspection, groundwater level measurements and light non-aqueous phase liquid (LNAPL) measurements. The scope of the field activities also included collection of the groundwater samples for annual morning required by the permit II. FACILITY DESCRIPTION AND SITE BACKGROUND The Site is located west of Roosevelt City in Duchesne County of Utah. The site location map is shown in Figure 1. Please note that the report figures are extracted from the 2023 Annual Groundwater Monitoring and Site Management Report (DSHW-2023-009831). The geographic location is Section 29, T2S, R1W, Uinta Special Base and Meridian (USBM), approximately at latitude 40o16'48" North and longitude 110o01'02" West. The Site is mostly vacant at the present time, except for the portions inside the former refinery area used for parking of vehicles and storage of equipment, and the front area including an office building and a maintenance shop along US Highway 40 which are leased to Foreland Transportation from RLI, the current property owner. Foreland Transportation is an oil energy company that handles oil-field materials and equipment. Foreland Transportation had leased the property from Pennzoil since 1990s after the refinery was closed. It appears that Foreland has continued to lease the property from RLI since RLI purchased the property from Pennzoil in 2006. The former petroleum refinery operated from 1968 to 1994 processing 5,000 to 7,500 barrels of oil per day while producing gasoline, diesel fuel, fuel gas, butane, and propane. The crude oil 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 4 - was a low sulfur stock produced locally in the nearby Altamont and Bluebell fields of the Uinta Basin and was known as Altamont-Bluebell crude. In September 1994, Pennzoil ceased operations at the refinery and began to dismantle the process units and equipment. The property was first sold to Inland Resources, Inc. (Inland) in 1998. Inland transferred ownership to Silver Eagle Refining. On May 10, 2006, the property was sold to the current ownership of RLI and Western View Partners LLC. Pennzoil retains the environmental liability for contamination relating to its operations prior to the 1998 sale to Inland. This liability was transferred to Pennzoil-Quaker State Company d.b.a. SOPUS Products when Pennzoil was sold in 2002. As a result of past operations, the refinery generated a number of contaminated areas impacted primarily by petroleum hydrocarbons and other contaminants. During the RCRA Facility Assessment (RFA) and RCRA Facility Investigation (RFI) processes, these impacted areas were further identified as 40 Solid Waste Management Units (SWMUs). The SWMU descriptions can be found in 2009 Corrective Action Plan (CAP) prepared by Malcolm Pirnie, Inc. Figures 2 and 3 depict the former refinery layout and the two significant SWMUs that are further described in the below paragraphs. SWMU-P-4, is also known as the Waste Disposal Cell (WDC), a permitted hazardous waste management unit (HWMU), as shown in Figure 3, which consists of the former hazardous waste surface impoundments that were used to treat all refinery wastewater. Figure 3 also shows SWMU 5, named the Hydrocarbon Seep, which was identified as the source area of the Site- wide groundwater contamination during the facility RFI process. The WDC was closed as a HWMU in place with a clay cover and is currently managed under the facility's Post-Closure Permit which was last reissued by the DWMRC in 2014. The Post- Closure Permit includes requirements for monitoring the shallow perched groundwater in six wells located upgradient and downgradient of the WDC, requirements for monitoring the Site- wide wells, and other ongoing Site management and activities to ensure protection of human health and the environment. The permit also includes post-closure care of the WDC and semi- annual Site inspections. The WDC groundwater monitoring well locations, and Site-wide well and piezometer locations are shown in Figure 3. As required by the permit, Pennzoil developed and submitted by its consultant the final CAP for remediating and managing the SWMUs in June 2009. The objective of the CAP was to complete the corrective action process, as required by the post-closure permit, by establishing cleanup objectives, identifying corrective actions, and outlining monitoring requirements for the Site. Prior to the development of the CAP, multi-phased RFI and remediation activities were conducted at the Site between 1995 and 2004, which included a human health risk assessment and the development of Site-specific risk-based remedial action levels. Interim Measures (IM) were conducted at some highly contaminated SWMUs between 2005 and 2007. In-situ 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 5 - landfarming, ex-situ landfarming, bioventing and excavation / off-Site disposal were selected as corrective measures at different SWMUs of the Site. Section 6 of the 2009 CAP also included a Site Management Plan (SMP), as required by R315- 101-7 of the Utah Admin. Code. In February 2010, an environmental covenant (EC) was recorded in Duchesne County by RLI, the property owner, to ensure implementation of the activity and use limitations for the Site. In November 2020, the SMP was updated into a standalone document from the 2009 SMP contained in the CAP. The updates and revisions to the SMP are necessary to reflect the current activities, e.g., the facility inspection frequency from monthly in the past to semiannually and groundwater monitoring frequency from semiannually to annually, as currently required by the Post-Closure Permit. The updated SMP also incorporates the land activity and use limitations specified late in the 2010 EC for the Site. The updated SMP contains the same requirements as in the 2009 version of the SMP on maintaining the Site security, which are also required by the permit. However, the 2010 EC only referred to Section 6 of the 2009 CAP as the SMP companion to the EC. The 2010 EC should also be updated in reference to the 2020 updated SMP. The EC also needs to be updated to reflect the co-permittees of the permit. In 2020, the DWMRC also approved an updated Sampling and Analysis Plan (SAP). Th updated SAP was removed from an attachment of the permit through a Class 3 permit modification that was approved in 2019. The SAP is now a stand-alone document that is referenced by the permit. This allows the SAP to be updated with the most applicable and current information without modifying the permit in the future. The updated SAP also includes a Quality Assurance Project Plan (QAPP) as a part of the United States Environmental Protection Agency’s (USEPA) mandatory quality system. The QAPP was developed in accordance with the USEPA Requirements for Quality Assurance Project Plans, EPA/240/B-01/003, March 2001, to ensure the type and quality of data needed for environmental decisions and to describe the methods for collecting and assessing those data. As a part of the above permit modification requested by the DWMRC, the permit and 2020 SAP now require the full suite of volatile organic compound (VOC) analytes be reported to the DWMRC to meet the fundamental objectives of detection monitoring and Site condition assessment. In the past, many constituents of VOCs associated with the Site contamination were present at the Site but were never reported to the DWMRC because of the limited reporting of the analytes listed in the original permit. The analytical deficiency documented by the inspectors based on split sampling results was corrected in 2020 SAP through a Class 3 permit modification in 2019. The annual groundwater report was also changed in the permit from the Corrective Action Status Report to the Annual Groundwater Monitoring and Site Management Report to reflect the current activities. 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 6 - It is also necessary to note that the 2019 Class 3 permit modification to the 2014 permit added RLI, the current property owner, as one of co-permittees of the permit, with Pennzoil - Quake State Company, d.b.a. Shell Oil Products US (SOPUS). Based on the records, RLI has been a recipient of the permit, annual reports, and correspondence regarding the former Pennzoil refinery Site since its purchase of the property. However, to date, RLI has been non-responsive to the DWMRC’s inquiries about the Site, notifications of planned Site inspections, Site security, Site management requirements, spills, or draft permit renewal. Recently, the Director of the DWMRC sent a letter dated July 9, 2024, via certified mails, to all members of the Roosevelt Land Investment, LLC, in addition to Mr. John Wells who is identified in the permit as a contact person, in order to seek their input on the draft permit renewal. The members of RLI continue to remain non-responsive. III. SITE GEOLOGY AND UPPERMOST AQUIFER The former Pennzoil refinery is located in the northern portion of the Uinta Basin section of the Colorado Plateau. Elevations in the northern Uinta Basin range from approximately 4,650 feet at the confluence of the Green and White Rivers, to more than 13,000 feet in the Uinta Mountains. Ground elevations of processing structures at the refinery lie at an elevation of approximately 5060 feet, with a maximum relief of approximately 25 feet between the southwest (upstream) and northeast (downstream) corners of the property. The geomorphology of the Uinta Basin is dominated by eroded sedimentary rocks, primarily of Tertiary age, which are folded along an east-trending syncline. Part of the basin consists of strongly dissected badlands, represented by the area east of Roosevelt, and part consists of local plateaus, represented by the area west of Roosevelt, where the general land surface is higher. The several levels of the plateaus slope gently southeastward and are pediment surfaces mantled with coarse-grained unconsolidated and semi-consolidated deposits. The existing monitoring well network is established in the uppermost, perched groundwater zone that varies by location beneath the Site, from unconfined in unconsolidated sediments to confined in consolidated sediments. The unconfined zone consists primarily of interbedded clay, silt, sand, and gravel typical of fluvial erosion and deposition in an arid environment. Sediment type changes fairly rapidly in both the vertical and horizontal directions. The materials in the uppermost aquifer are primarily gravels (cobbles) with a sand and silt matrix in the area of the upgradient wells (MW-1 and MW-7), and in the area north of the intermittent stream channel. Around the wastewater treatment ponds the aquifer materials are primarily silty, very fine to fine grained sands with minor amounts of clay. Sandy silts with clay are also present in the area of the surface impoundments and assumed to be near the base of the uppermost aquifer. The depth to groundwater surface in the uppermost zone ranges from approximately 1 to 10 feet below ground surface. The groundwater in the uppermost aquifer is largely present under 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 7 - unconfined conditions. The potentiometric surface map of groundwater elevations in June 2022 is shown in Figure 4. The direction of groundwater flow in the upmost aquifer is generally northeast. The hydraulic conductivity is in the Site range of 0.2 to 16.2 feet/day, the porosity is from 0.25 to 0.35, the hydraulic gradient ranges from 0.007 to 0.038 foot per foot (ft/ft) during the time of the RFI, and the groundwater velocity has been calculated in the range from 0.007 to 0.59 feet/day. Based on groundwater elevation data collected during the 2023 monitoring event, the predominant direction of the perched groundwater flow beneath the former refinery is to the northeast. The hydraulic gradient beneath the WDC is approximately 0.0054 ft/ft to the northeast between wells MW-7 and MW-11. The hydraulic gradient beneath the SWMU P-5 area is approximately 0.0074 ft/ft generally to the northeast between wells MW-24 and MW-109. These gradients are similar to those derived in June 2022 and previous years. IV. GROUNDWATER MONITORING PROGRAM Details and standard practices regarding the groundwater monitoring program data quality assurance and quality control are outlined in the SAP. Below is a summary of the requirements found in the SAP document: Wells to be monitored during post-closure care of the WDC include MW-7, MW-11, MW-12, MW-19, MW-20, and MW-21, located upgradient and downgradient of the WDC (Figure 3). The WDC wells are gauged and sampled in the following order from upgradient to downgradient locations, unless based on field observation or based on the results of prior sampling events. The Site-Wide monitoring wells, located on the eastern half of the property near SWMU P-5, the Hydrocarbon Seepage, including MW-24, MW-105, MW-108, MW-109, and MW-115, are monitored in accordance with the 2009 CAP and 2020 SMP. The Site-Wide monitoring wells are located along the downgradient of the perimeter of the former refinery boundary except for one well, MW-24. The primary purpose of Site-Wide monitoring is to assess the migration of groundwater contamination off the property boundary and the groundwater contamination source. Based on the current Site conditions, LNAPL is still present in a few monitoring wells. In accordance with the updated 2020 SMP and to accurately assess the groundwater potentiometric surface, the following additional wells in the vicinity of the WDC and SWMU P- 5 areas will be gauged for LNAPL thickness, if present, and depth to perched groundwater: MW- 15, MW-17, MW-102, MW-106, MW-107, MW-112, MW-120 and MW-127. Additional monitoring wells and piezometers, which are neither a WDC nor a Site-wide well, observed to have contained LNAPL at some point in the historical record, will be gauged during post-closure care including MW-1, MW116A, MW-117, MW-118, MW-119, MW-121, MW- 122, MW-126, P-1, TP-40, TP-41, and TP-42. Prior to purging and sampling, fluid level measurements will be collected from each designated 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 8 - monitoring well using a decontaminated electronic oil-water interface probe and documented on field log forms. Depth to perched water and depth to LNAPL, if present, below the reference point at the top of each casing will be measured to the nearest 0.01 foot and recorded on the sampling log along with general well characteristics including well diameter, plug and lock presence, type of well pad and condition. The total depth of each well will also be measured and recorded to detect well obstructions or possible silting of the well screen. The volume of water purged will equal three times the computed casing volume where possible. The casing volume is calculated using the total standing depth of water in the well and the well diameter. Wells which are dewatered prior to three well volumes being removed, will be allowed to recharge prior to sampling. No additional purging will be conducted after the wells are initially dewatered. During purging field parameters including pH, specific conductivity, and temperature readings will be obtained approximately every 10 minutes using a flow-through cell and water quality meter. Parameters will be recorded on field sampling forms and/or the project field book. All equipment used for field analyses will be calibrated prior to use according to the manufacturer’s instructions and will be decontaminated prior to use at each well using the procedures described in Section 2.6. The pH values will be measured to the nearest 0.01 unit, conductivity to at least two significant digits, and temperature to the nearest 0.1 degrees Celsius (°C). Samples for analysis of volatile organic compounds will be collected directly from the discharge tubing at reduced flow rates (<100 milliliter per minute, mL/min). Vials for volatile organic analyses will be filled to overflowing with a convex meniscus forming at the mouth of the vial. The lids with Teflon-lined septa will be attached, and the vial will be inverted and gently tapped to check for air bubbles (zero headspace). If bubbles exist, the sample and bottle will be discarded and another new sample container with preservative to be collected a sample using the above procedures until zero headspace is assured. V. WDC MONITORING AND SITE CONTAMINATION STATUS Based on historical groundwater detection monitoring data, it appears that there is no evidence of a release from the WDC. Based on the 2023 Site-Wide monitoring data from the current six wells required by the permit, also as shown in the Figure 5 of this O&M report, it appears that the extent of the groundwater contamination is primarily within the property boundary, except for 1,2 dichloroethane detected in the following perimeter monitoring wells MW-108 (3.79 micrograms per liter (µg/L) and MW-109 (6.25 µg/L) in 2023. LNAPLs were observed in 2023 in wells MW-117, MW-121, MW-126, TP-40, and TP-41, similar to the previous year. During the 2023 monitoring event, in addition to sampling the six Site-Wide monitoring wells, Pennzoil and AECOM also conducted one-time sampling at all other wells that are not currently 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 9 - sampled under the permit. The purpose of the one-time groundwater sampling event was to assess the current groundwater conditions and the Site-Wide monitoring network and to abandon the wells that are no longer needed for the Site in the future. The one-time sampling results that are presented in the revised 2023 Roosevelt Site Assessment Report (DSHW-2024-006540) indicate that benzene was detected at the concentration of 165 μg/L in MW-113, a perimeter well concerning off-Site migration exceeding the maximum contaminant level (MCL) of 5 μg/L. Within SWMU-P5, the benzene was detected at the concentrations of 3770 μg/L in MW-22 and 1670 μg/L in MW-25. Pennzoil sampled these wells again in June 2024 to determine if the current Site-Wide groundwater monitoring network needs to be updated. Based on the results of the 2023 one-time groundwater sampling data Pennzoil and AECOM proposed to abandon some groundwater wells and piezometers in the May 2024 revised Roosevelt Site Assessment Report. The DWMRC approved the proposed well abandonment in July 2024. The implementation of well abandonment is pending. VI. O&M INSPECTION VI.1. Office Preparation The O&M Inspection is designed to determine whether Pennzoil is in compliance with applicable requirements of the permit. Monitoring groundwater in the uppermost aquifer assists in determining whether a release or potential release of hazardous waste constituents may have occurred from the WDC and also in assessing the groundwater quality at other locations of the former refinery. Based on the sampling results, if needed, corrective measures to protect human health and the environment may be considered, according to Utah Admin. Rule R315-101 and the permit. These requirements include inspections for proper O&M of the facility, proper maintenance of groundwater monitoring wells and consistency of groundwater monitoring program. In general, the O&M inspection should identify issues or concerns that should be assessed for future groundwater monitoring events in accordance with the permit. In preparation for the field inspection, DWMRC staff conducted a review of the Pennzoil's SAP including the QAPP, referenced in the permit. The inspectors also conducted reviews of the selected previous annual groundwater monitoring and Site management reports. As a part of the office preparation and follow up review, the inspectors also reviewed the 2023 Annual Groundwater Monitoring and Site Management Report (DSHW-2023-209831). 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 10 - VI.2. Field Inspection and Observation VI.2.1. Observation of Field Crew Quinn Walker and Nathan Nicolodemos of AECOM performed the June 2023 groundwater monitoring and sampling event. Mr. Walker has conducted the field sampling and inspections several times at the Pennzoil Site. At the time of inspection, it appears that both Mr. Walker and Mr. Nicolodemos have experience working on groundwater sampling and investigation (Photo 1). Based on the field observations of sampling activities, the inspectors concluded that the field crew followed the overall groundwater monitoring and sampling procedures as specified in the SAP. In addition, the AECOM personnel were required to conduct an inspection of the WDC and the Site in accordance with the current permit. The inspectors did not observe the AECOM’s Site inspection. The results of the inspection will be included in the 2024 Annual Groundwater Monitoring and Site Management Report. VI.2.2. Site Inspection Narratives The following serves to document the findings and observations of the inspectors at the time, as noted above, when inspection activities were performed of the groundwater sampling activities at the Site. The inspectors also performed inspection and walk-through of the Site. Photos of groundwater monitoring activities and the inspections are included in Attachment 3 of the 2024 O&M Report. Photos 1-2 show the samplers collecting groundwater samples. At the time of inspection, the inspectors again observed oil piping that was stored likely by RLI/the tenant, but not by Pennzoil, on the RLI property (Photos 3-4). It is unknow about the quantity of residual oil left in the piping and the amount of oil that would drain out the piping over time. It appeared that the oil impact to the soil was minimal in comparison with what was observed last year from the different piles of oil piping stored on the property. During the 2023 O&M inspection, the inspector observed oil spills drained out of from the stored piping impacted the soil on the ground over the time. On July 20, 2023, the AECOM project manager provided the DWMRC with a written notice of the spill of waxy crude oil. The notice (DSHW-2023-206633) indicated the oil and stained soil have been cleaned up and disposed of at LaPoint Recycle and Storage, an approved oil disposal facility, based on a statement made by Brad Wells, a property owner representative, to the AECOM project manager. The last year’s piping was later sold to a metal recycler. 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 11 - AECOM also collected confirmation soil samples after the soil removal from the areas where the piping was stored. The sampling results were included in the revised Roosevelt Site Assessment Report (DSHW-2024-006540). For the spill observed last year, the DWMRC requested the co-permittees Pennzoil and RLI address the oil spill in a letter dated August 4, 2023. At the time of inspection, the inspectors also met an AECOM contractor for the proposed fencing around SWMU-P5. VI.3. Identification of Deficiencies and Concerns Based on the inspection conducted during a portion of the sampling event, no deficiencies were identified regarding the annual groundwater monitoring event in accordance with the permit. The inspectors noted that the oil piping was again stored on the ground and discussed the concerns of potential spills from the piping with AECOM samplers. ________________________ _____________________ Hao Zhu Date Environmental Engineer 8/13/2024 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 12 - Attachment 1 – Figures 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 13 - 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 14 - 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 15 - 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 16 - 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 17 - 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 18 - Attachment 2 - Tables 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 19 - Table 1: Post-Closure Analytical Requirements for Groundwater Samples Parameter Container(s) Preservative1 Method Method Detection Limits (µg/L) Volatile Organic Compounds Benzene Carbon disulfide Chlorobenzene Chloroform 1,2-Dibromoethane 1,2-Dichloroethane 1,4-Dioxane Ethylbenzene Methyl ethyl ketone Methylene chloride Styrene Toluene Xylenes2 Three 40-mL glass vials with Teflon-lined septa in caps per sample Additionally, Quality Control samples have additional sample container volumes as specified above. HCl to pH<2 SW 8260D 0.20 0.22 0.18 0.23 0.21 0.20 72 0.19 2.6 1.0 0.28 0.17 0.58 Oil & Grease Two 1 -Liter amber glass HCL volume will be determined prior to sampling EPA 1664A 1,400 Metals Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Lead Magnesium Mercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Two 500 mL plastic HNO3 to pH<2 SW 6010B or 6010C, except SW 7470A for Hg 5.0 8.6 5.0 2.0 0.50 500 3.0 5.0 5.0 5.0 250 0.10 3.0 500 5.0 3.0 400 5.0 10 25 Sulfide One 250 mL plastic Zinc Acetate/ Sodium Hydroxide EPA 376.2 or SM 4500S2 F- 2011 500 Cyanide One 250 mL plastic 50% NaOH to pH>12 SW 9012B 7.0 One 1-Liter No chemical 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 20 - Parameter Container(s) Preservative1 Method Method Detection Limits (µg/L) General Alkalinity Bicarbonate Carbonate Chloride Fluoride Nitrate + Nitrite pH Specific Conductance Sulfate Total Dissolved Solids Plastic for each sample analyte Preservative H2SO4 – (Nitrate + Nitrite) EPA 310.1 or SM2320B-2011 EPA 310.1 or SM2320B-2011 EPA 310.1 or SM2320B-2011 EPA 9056A EPA 9056A EPA 353.2 EPA 9040C EPA 9050AorSM 2510B-2011 EPA 9056A EPA 160.1 or SM 2540C-2011 5,000 5,000 5,000 200 10 80 N/A 10.0 (umhos/cm) 30 7,000 1 Preservative in addition to cooling to 4°-6 °C. 2 Ortho-, meta, and para- isomers, as well as total xylenes 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 21 - Attachment 3 - Photos 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 22 - Attachment 3 - Photos 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 23 - Photo 1 Pennzoil Groundwater Sampling Activity, on June 26, 2024 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 24 - Photo 2 – AECOM Groundwater Sampler Conducting Sampling, June 26, 2024 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 25 - Photo 3 Oil Piping Stored at the Site, June 25, 2024 2024 O&M Report Pennzoil Post-Closure Permit Annual Groundwater Monitoring, EPA ID No. UTD073093874 Page - 26 - Photo 4 – Oil Piping Stored at the Site, June 25, 2024