DSHW-2006-000928 - 0901a06880134af4

REPLY TO
ATTENTION OF:
DEPARTMENT OF THE ARMY
US ARMY CHEMICAL MATERIALS AGENCY
TOOELE CHEMICAL AGENT DISPOSAL FACILITY
11620 STARK ROAD
STOCKTON, UTAH 84071
June 28, 2006
UTA*fl DIVTSION OF
SOLID a HAZARDOUS WASTE
Tooele Chemical Agent Disposal Facility PM-60399
SUBJECT: Tooele Chemical Agent Disposal Facility (TOCDF) Incinerator Upset Conditions
Estimate for 2005
Mr. Dennis Downs, Director
Utah Department ofEnvironmental Quality
Division ofSolid and Hazardous Waste
288 North 1460 West
Salt Lake City, Utah 84116-0690
Dear Mr. Downs:
Please find enclosed three copies ofthe TOCDF Incinerator Upset Conditions Estimate
for 2005. This submission is required per TOCDF Resource Conservation and Recovery Act
Permit Condifion I.M.4.
If you have any questions regarding this issue, please contact Ms. Elizabeth A. Lowes at
[phone] or Mr. Trace Salmon at [phone].
Sincerely,
Gar£>V. McCloskey {
EG&G Defense Materials, Inc.
'CERTIFICATION STATEMENT
Thaddeus A. Kyts
TOCDF Site Project Manager
'CERTIFICATION STATEMENT
Copies Fumished:
CMA Risk Management Directorate (Mr. Stang)
DCD Risk Management Directorate (Mr. Levi)
TOCDF FO Representative (Ms. Lessig)
File
• I CERTIFY UNDER PENALTY OF LAW THAT THIS DOCUMENT AND ALL ATTACHMENTS WERE PREPARED UNDER MY DIRECTION OR SUPERVISION IN ACCORDANCE
WITH A SYSTEM DESIGNED TO ASSURE THAT QUALIFIED PERSONNEL PROPERLY GATHER AND EVALUATE THE INFORMATION SUBMITTED BASED QN MY INQUIRY
QF THE PERSON OR PERSONS WHO MANAGE THE SYSTEM, OR THOSE PERSONS DIRECTLY RESPONSIBLE FOR GATHERING THE INFORMATION, THE INFORMATION
SUBMITTED IS, TQ THE BEST QF MY KNOWLEDGE AND BELIEF. TRUE, ACCURATE AND COMPLETE. I AM AWARE THAT THERE ARE SIGNIFICANT PENALTIES FOR
SUBMITTING FALSE INFORMATION, IN'CLUDING THE POSSIBILITY QF FINE AND IMPRISON'MENT FQR KNOWING VIOLATIONS
Incinerator IJp set Condition
Estimate r 2005
PDARS Review Based
EG&G Defense Materials Incorporated
Tooele Chemical Agent Disposal Facility (TOCDF)
\
June 28,2A06
HANA NELruEAEN
JUid r s ?00$0b,Dz[L
UTAH DIVI$ION OF
SOLID & HAZARDOUS WASTE
HAruD fiHLIVEHED
nffiim,
sorrD & HAzAnDoubtnsrr
Incinerator Upset Condition
Estimate E 2005
PDARS Review Based
EG&G Defense Materials Incorporated
Tooele Chemical Agent Disposal Facility (TOCDF)
Jnne 28,2006
Table of Contents
1.0
2.0
3.0
3.1
3.2
4.0
5.0
6.0
4.2 Increased Particulate/I{etals Emissions................. ........................ 7
t2
l3
6.1 2005 IncineratorHours of Hazardous Waste Operation................ ................... 13
6.2 Daily Totals for LICI Upset Condition Episodes in 2005 ...........21
6.3 Daily Totals for LICZ Upset Condition Episodes in 2005 ........... 23
6.4 Daily Totals for DFS Upset Condition Episodes in 2005 ...........;......... ............24
6.5 Daily Totals for MPF Upset Condition Episodes in 2005 ...........26
6.6 Data Gaps for Incinerators in 2005.... .....................28
6.7 Modifred Emission Rate Multipliers - 1999 to 2005........ ........... 30
Page 2 of30TOCDF Upset Conditions - 2005 6t28t2006
List of Tables
Table 3 - Selected Operating Parameters and Associated Instrument Tag IDs.-..........1................ ........... 9
Table 4 - Logic for Determining Upset Conditions ................ 10
List of Acronyms
ASP
CEMS
CO
COPC
DFS
OF
EPA
GPM
HHRA
HTML
Inwc
JACADS
LIC
MACT
MPF
PAS
PDARS
RCRA
TOCDF
UDSHW
Active Server Pages
Continuous Emission Monitoring System
Carbon Monoxide
Constituents of Potential Concern
Deactivation Furnace System
Degrees Fahrenheit
U.S. Environmental Protection Agency
Gallons per Minute
Human Health Risk Assessment
Hypertext Marlorp Language
Inches of Water Column
Johnston Atoll Chemical Agent Disposal System
Liquid Incinerator
Maximum Available Control Technology
Metal Parts Fumace
Pollution Abatement System
Process Data Acquisition and Recording System
Resource Conservation and Recovery Act
Tooele Chemical Agent Disposal Facility
Utah Department of Environmental Quality (State of Utah), Division of Solid & Hazardous Waste
TOCDF Upset Conditions - 2005 Page 3 of30
1.0 Introduction
The Tooele Chemical Agent Disposal Facility (TOCDF) Human Health Risk Assessment (HHRA)
was performed to determine if there would be chronic indirect health risks associated with the
incineration of chemical agent. This determination was initially made following Environmental
Protection Agency (EPA) protocol, using air dispersion models and analytical results of exhaust gas
sarirpled during the Johnston Atoll Chemical Agent Disposal System (JACADS) agent trial burns.
Emission rates of various Constituents of Potential Concern (COPC), which were determined during
agent trial burns were adjusted using modified emission rate multipliers to ensure that the results of
the HHRA were conservative. The emission rate mlltipliers used in the TOCDF HHRA are based
on the percentage of time each incinerator operates at less than optimal performance (i.e., the
incinerator is operated under upset conditions).
The estimated percentages of time that the incinerators operated under upset conditions in the
TOCDF HHRA are also based on the draft EPA Human Health Risk Assessment Protocol for
Hazardous Waste Combustion Facilities (EPA530-D-98-001A). The Utah Division of Solid and
Hazardous Waste (IIDSIIW) has made it a permit condition to develop an estimate of the operational
time under incinerator upset conditions based on actual operating data. The results of this estimate,
along with the results of the TOCDF agent trial burns, would be u'sed in future iterations of the
TOCDF HHRA. Using HHRA emission rate multipliers based on actual experience allows for a
much more accurate estimate of the risks involved with chemical agent incineration.
2.0 Results
The EPA guidance concerning HHRAs requires the application of emission rate multipliers to
particulate/metals emissions and organic emissions. Organic emissions are products of incomplete
combustion. A comparison of the EPA HHRA protocol emission rate multiplier values to those
determined from a review of the TOCDF Process Data Acquisition and Recording System (PDARS)
data for 2005 shows that the EPA HHRA protocol over-estimates the emission rate multipliers. A
comparison of the results is presented in Table 1.
The actual percentage of time when the TOCDF incinerators were operated under upset conditions is
much less than the values fotrnd in the EPA HHRA guidance. Table 2 presents the amount of time
each incinerator was operated under upset conditions during 2005. The ntrnber of hours each
incinerator operated (i.e., processed hazardous waste) during each day of 2005 can be found in
Attachment 6.1. Data gaps during 2005 (i.e., periods when no data was collected for the
incinerators) are also provided and explained in Attachment 6.6. The data gaps account for
approximately six hours over the year for any parameter at any of the four incinerators, or only
0.07% of the total time for the year.
TOCDF Upset Conditions - 2005 Page-4 of 30 6t28t2006
LICI - Liquid Incinerator #l
LICZ - Liquid Incinerator #2
DFS: Deactivation Furnace System
MPF - Metal Parts Furnace
t The draft EPA Human Health Risk Assessment
includes the following guidance in Chapter 2:
Table 1 - Modified Emission Rate Multipliers
Protocol for Hazardous Waste Combustion Facilities (EPA530-D-98-001 A)
O
Estimating Emissions from Process Upsets: To represent ernission rates during process upsets, multiply the emission rate
developed from trial burn data by 2.8 for organics and 1.45 for metals. These factors are derived by assuming that emissions
during process upsets are l0 times greater than emissions measured during the trial bum. Since the unit does not operate under
upset conditions continually, the factor must be adjusted to aecount for only the period of time, on an annual basis, that the unit
operates under upset conditions. For organic compounds, the facility is assumed to operate as measured during the trial burn 80
percent of the year and operate under upset conditions 20 percent of the year (0.80X1)+(0,20X10):2.8]. For metals, the
combustion unit is assumed to operate as measured during the trial bum 95 percent ofthe year and operate under upset conditions
the remaining 5 percant of the year [(0.95X1)+(0.05X10F1.45].
Based on review of PDARS data generated during calendar year 2005.
3.0 Operational Data Considered
All data analysis was conducted using electronic database systems. These systems include the Microsoft
technologies SQL Server 2000 for the database server, and Hlpertext Marlarp Language (HTML) and
Active Server Pages (ASP) for the website application analysis tool. A user friendly website application,
which is not accessible to the public, has been developed in order to import new data, analyze and export
data, and generate summary and final reports. The website application allows the user to choose the task
at hand and enter date, incinerator, and parameter specific criteria. Through ASP, the form delivers the
Page 5 of30
Non-Peak Performance lncinerator
Emission Rate Multiplier
Percent of Time Non-Peak Performance
Occ urs (P articulate/lVletals
Percent of Time Non-Peak Performance
Occurs (Orsanics
Modified Emission Rate Multiplier
Particulate/lVletals
Modified Emission Rate Multiplier
Table 2 - Percent Ilours of Operation
Metals lParticulate upset conditions total elapsed time (hours)t t.392 1.017 5.16 7.56
Organic upset conditions total elapsed time (hours) t 1.418 0.t92 0.7 5 0. 16
Total hazardous waste processing time (hours) t 873 116 1,452 3,949
Metals lParticulate upset conditions time (percent)0.159 0.875 0.36 0.19
Oreanic upset conditions time (percent)0.162 0.165 0.05 0.004
TOCDF Upset Conditions - 2005 6t28t2006
user's task and criteria into the associated stored procedures, which execute within the database server.
After the database has completed processing the user's request, the website application informs the user
the process is complete and, if requested, provides a link to the document(s) exported by the web
application.
Data from PDARS was initially divided into one-hour intervals and sorted using minimum or maximum
values (as appropriate) to identiff one-hour time blocks where potential upset condition episodes may
have occurred. Each one-hour time block that was identified as containing a potential upset condition
was subjected to frrrther analysis using 30-second PDARS data. The data was atalyzed as follows:
3.1 One-Hour Data Evaluation
One hour data was collected for the required tirne period for all necessary ID tags. Because an upset
condition cannot exist when the individual incinerators are not in opeiation, the initial data sort was
for furnace feed state. Data was included in the database if it met the following conditions:
pounds, (Ten pounds was used to avoid instrument calibration problems; it's not unusual for the
meter to record small values even when the incinerator is not operating.)
proceeding hour (an indication that a nerv tray had entered the fumace in the proceeding or the
current hour).
After furnace feed state was established, each one-hour time block was tested to determine if the
potential existed for increased organic or particulate/metals emissions. This screening was conducted
as follows:
Organics - Each one-hour time block was evaluated to determine if both carbon monoxide (CO)
analyzers recorded values above 100 ppm at any time during the hour.
Particulates/Metals - Each one-hour time block was evaluated to determine if the temperature
exceeded evaluation criteria, the venturi scrubber brine flow fell below evaluation criteria, or the
venturi scrubber difforential pressure exceeded the evaluation criteria at any time during the hour.
The evaluation criteria were based on the levels used for previous HHRA reports.
The evaluation criteria for upset conditions during the one-hour data analysis are described in detail in
Section 4.
3.2 Thirty-Second Data Evaluation
Thirty-second PDARS data for each one hour time block identified in the one
described above was recovered and aralyzed using electronic methods. The logic
criteria for the 30-second data evaluation are described in detail in Section 4.
hour data sort
and evaluation
IOCDF Upset Conditions - 2005 Page 6 of30 6t28t2006
4.0 Definitions of Incinerator Upset Conditions
The definitions of upset conditions for the TOCDF incinerators are based on Maximum Available
Control Technology (MACT) standards. These standards are explained below.
4.1 Increased Organic Emissions
The duration of upset condition episodes resulting in the potential
emissions was determined for each incinerator as defined below.
4.1 .l LICI and LIC}
for increased organic
The uncorrected Pollution Abatement System (PAS) CO concentration was greater than
100 ppm during agent feed or within five minutes after the waste feed was disabled.
4.t.2 DFS
The uncorrected PAS CO concentration was greater than 100 ppm wherr the fumace was
enabled to process waste feed.
4.1.3 MPF
The uncorrected PAS CO concentration was greater than 100 ppm when waste was
present in the primary chamber. The time when waste was charged to the primary
chamber was determined as thetime when the tray number changed.
Calibration events were differentiated from actual high CO events by checking the two CO
Continuous Emission Monitoring Systems (CEMS) against each other. Carbon monoxide CEMS
are never calibrated at the same time. It was assumed that a high CO event was real if both CO
CEMS indicated CO concentrations above 100 ppm simultaneously. The instrument tag IDs
associated with these parameters for each incinerator in PDARS are provided in Table 3. Table 4
provides the logic of the analysis of upset conditions associated with excessive CO emissions.
4.2 IncreasedParticulate/Metals Emissions
The duration of upset condition episodes resulting in a potential increase of particulate/metals
emissions was determined for each incinerator as defined below. These definitions incorporate
TOCDF Resource Conservation and Recovery Act (RCRA) permit limits for the applicable
parameters.
4.2.1 LIC1 and LIC2
The primary chamber exhaust temperature was greater than or equal to 2,850 T, the
venturi scrubber brine flow was less than 106 gallons per minute (gpm), or the venturi
scrubber differential pressure was less than 35 inches water column (inwc) during agent
feed or within 5 minutes after waste feed was disabled.
f.g. 7 of30TOCDF Upset Conditions - 2005
4.2.2 DFS
The kiln exhaust gas temperature was greater than 1,650 oF, the venturi scrubber brine
flow was less than 310 gnr\ or the venturi scrubber differential pressure was less than 30
inwc during waste feed or within 25 minutes after waste feed was stopped.
4.2,3 MPF
The primary chamber zone temperatures were greater than 1,700 oF, the venturi scrubber
brine flow was less than 90 Eprn" or the venturi scrubber differential pressure was less
than 25 inwc when waste was present in the incinerator. It is assumed that waste was
present in the incinerator for 1.5. hours after a tray is loaded into the furnace.
The instrument tag IDs associated with ihese parameters for each incinerator in PDARS are
provided in Table 3.
Page 8 of30
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l
ci

r'

d
p$
g
fro{i
aGILrq)
a
.l
Ih-
afr
(a
t*Or
tsz
5.0 Conclusion
The amount of time TOCDF incinerators are operated under upset conditions is significantly less
than the assumed values used in the EPA HHRA protocol.
The modified emission rate multipliers applied to LIC emissions could be lowered in the next
iteration of the HHRA considering:
' 1. The difference in the EPA protocol assumed values versus actual values as determined by
review of the PDARS data.
2. The ability to instantaneously stop *urt" f""O on the LICs.
3. The short waste residence time associated with a liquid incinerator.
For the I-ICs, the 2005 PDARS data supports an emission rate multiplier of 1.01 for orgaqic
emissions and an emissions rate multiplier of 1.01 and 1.08 for particulate/metals for LICI and
LIC2, respectively
The modified emission rate multipliers applied to DFS and MPF emissions could also be lowered in
the next iteration of the TOCDF HHRA considering the difference in the EPA HHRA proaocol
assumed values versus actual values determined by review of the PDARS data. For the DFS, the
2005 data supports an emission rate multiplier of 1.00 for organic emissions and an emissions rate
multiplier of 1.03 for particulate/metals. For the MPF, the data supports the application of emission
rate multipliers of 1.02 and 1.00 to particulate/metals and organic emissions, respectively.
The percent upset condition hours of operation for the DFS and MPF could potentially fluctuate
more in any given year than that for the LICs because of the longer waste residence time associated
with the incinerator designs. Given that the emission rate multipliers for the DFS and MPF in 2004
and 2005 were below 1.03 for both organic emissions and particulate/metals, the use of the emission
rate multipliers calculated in 2005 for organic ernissions and particulate/metals is reasonable.
TOCDF Upset Conditions - 2005 Page l2 of30 6t28t2006
6.0 Attachments
Attachment 6.1 2005 Incinerator Hours of Hazardous Waste Operation
UU2005 2.333 0.267 10.433
U2l200s 2.283 r.7 t7
u3l200s 8.7 5 7.233 6.583
U4t2005 6.t17
U5l200s 1.05 3.8 17
U6l200s 3.033 1.9 I 8.0 17
u7 l2a0s 5.683 7 .ll7
U8t200s 4.333 4.683
v9l200s 6.15 t9.233
Ut0l200s 5. 133 0.667 8.567
lltv200s 4.s67 3.9r7
Ut2l200s 0.317 8.7 5 tr.4t7
U1312005 1.1 1.567 2.8s
vt4l200s I 1.983 4.1 6.3 83 13.183
Utsl200s 8.333 19.5
urclza}s 1 1.833 9.217 23.983
ur7l200s t.733 r.733 5.133 23.983
Ut8l200s 2.217 12.6
U19l200s 1.65
U201200s 7.1
U2u200s 8.0r7
U2212005 8.3 83 18. I l7
Ll23l200s 0.683 t4.333
U241200s 6,7
U2sl200s 2.3t7
U261200s 2.4s
U271200s 4.867
U281200s 7 .067
U291200s 10.4 t2.033
U301200s 1 1.55
U3U200s 6.467 2.983
21y2005 2.55 0.983 4.883
21212005 6.583 13.55
2131200s I 1.05 16.8
2141200s 14.2 0.167 10.85 15.9
2lsl200s 6 0.9t7 20.933
2161200s 23.733
217 1200s 6.35 1.1 23.783
2181200s 5.567 0.017 14.4 14.35
2t9t200s 4.35 0.05 10.783
2lt0l200s 7.433 0.683 4.633 12.8t7
2ltU200s 9.967 23.267
2ltzl200s 9.283 4.s67 23.983
2lt3l200s 0.8 3.417 23.983
TOCDF Upset Conditions - 2005 Page l3 of30
Attachment 6.1 2005 lncinerator Hours of Hazardous Waste Operation
2lt4l200s 3.2t7 3.9 23.983
2lt5l200s 6.833 19.317
2lt61200s 8.783 0.083
2lt7 1200s 9.0s 4.6 10.45 I 1.033
2lt8l200s 7.2 6.067 I 8. 133
2lt9l200s 6.833 6.5
21201200s 5.233 8.133
212U200s 12.25 9.2 23.667
21221200s 5.8 83 5.5s 23.983
21231200s r.983 6.417 15.233
21241200s 7 .45 t2.383
212sl200s 16.333
21261200s 18.233 t7.617
2127 1200s 9.8 11.583
21281200s r.817 2.567
3lU200s 4.183 8.6 9.2
3121200s 6.9
3131200s 3.3 83
3141200s 14.967
3lsl200s 8.733
3161200s 1.2
3171200s 5.8
3181200s 7.283
3191200s 3.6t7 0.067
3lt0l200s 1.05 t2.8
3ltU200s t.7 5 23.983
3lt2l200s 18.2t7 20.867 23.983
3lt3l200s 6.983 15.05 22.667
3lt4l200s 17 .l 23.983
3ltsl200s 8 23.867
31t612005 7 .533 8.933 23.867
3lt7 1200s 9.2t7 1.9 13.t67 23.983
311,812005 10.467 1.383 2.233 23.983
3lt9l200s r.2 23.067
312012005 23.067 23.567
312U200s 8.417 22.233 t2.533
31221200s 1.65 7.917 0.017
3123t2005 I 1.15 12.717
31241200s 12.25 23.983
3l2sl200s 18.433 23.983
31261200s t2.783 11.667 I 1.85 23.983
3127 1200s 3.133 3.283 6.533 23.983
31281200s 17.2 22.367
312912005 r1.183 t.367
313012005 r0.367 9.633 7.433 23.983
3l3rnjas 8.5 23.983
4lU200s 3.617 4.t33 13.567 23.983
o
6/28t2006TOCDF Upset Conditions - 2005 Page l4 of30
O Attachment 6.1 2005 lncinerator Hours ofHazardous Waste Operation
41212005 2.567 1 8.25 23.983
4131200s 8.05 1.1 1s.483 23.983
41412005 t2.6t7 16.t17 19.3 5 23.983
4lsl200s 4.7 t7 18.983 1 5.333
4161200s 4.5 14.517
417 1200s 9.083 9.533 22.967 9.133
4181200s 3.917 3.917 13.483 23.983
4191200s 0.2t7 0.233 I 3.8 83 t4.283
4lt01200s t3.367 4.467
4ltU200s tt.2 9.15 19.133
4lt2l200s 2.75 2.783 r 6.883
4lt31200s 10.183 8.783
4lt4l200s 12.483 t7.217 12.6
4ltsl200s 15.267 13.6 23.983
4lt6l200s 3.3 83 ll 10.817
4lt7l200s 4.2 14.567
4lt8l200s t3 t7 .15
4lt9D}as 6.2 4.967
41201200s I s.633 1.833
412y200s tr.t67 23.983 23.867
41221200s 13.433 2t.233 9
41231200s 9.933 t6.6
41241200s 9.217 t4.317
4lzsl200s 7 .667 5.983 s.25
4l26l20As 6.4s
41271200s 14.233 10.267 t2.933
41281200s t0.667 13.45 0.s33
41291200s r0.Il7 t7 .267
41301200s 1.1 t2.683
slu200s 18.65 7.217 t.317
sl2l200s 4.45
s13l200s 7 13.517
5t4t200s tr.433 16.ofi 2.783
51s12005 12.15 0.8
5161200s 17.817 20.8 83 1.183
s17l200s 16.2 10.45 13.567
5181200s 10.45 10.933
5191200s 6.133 15.783
slt0l200s 13.4s 13.65
5ltU200s t4.283 7.3 12.217
slr2l200s 18.467 t4.367 8.ls
5lt3l200s 0.067 1 9.833 13.45
slt4l200s 13.8 l7 22.867
5ltsl200s t6.7 3.2 r7.367
5n6t2005 1,2.15 10.833 t5.25
5lt7 12005 9.7 17.3 12.t5
slt8l200s 13.3 83 t2.5t7
TOCDF Upset Conditions - 2005 Page l5 of30 6t28t2006
O
Attachment 6.1 2005 Lrcinerator Hours of Hazardous Waste Operation
5l19l200s 0.55 7.033 8.417
sl20l200s 23 13.083 9.9 '
512U200s 14.667 15.85 t4.4t7
5t22t200s 17 .9t7 10.6
sl23l200s 19.B33 18.283 19.2
sl24l200s 3.s17 1s.683 t2.65
5lzsl200s 5.467 13. 183 s.tt7
sl26l200s 15.467 20.617 0.35
5127 1200s 8967 21,667 23.983
sl281200s 17.8 15.95 8.7 67
512912005 20.65 22.617 5.417
sl30l200s 23.617 10.783
s13U200s 19.4 20.1 83
61112005 9 18 tL.433
6121200s 2.833 I 8.1 67 7 .367
61312005 23.9 r0.233 s.933
6141200s 15.183 8.683
6lsl200s 3.9s
6161200s t4.683
61712005 15.283
6191200s 19.783
6/r01200s 14.133
6lrU200s 10.4
6lt2l200s L7 .55
6l13l200s 9.7
6lt4l200s 13.083
6lt5l200s 10.6 17
6lt6l200s t5.5r7
611712005 9.8r7
6lt81200s s.483
6lt9t200s 15.483
6t20t200s I 1.3
612U200s 0.3
612212005 15.317
61231200s 7.783
61241200s 1 1.817
6l2sl200s 8.9
612612005 3.467
6127 1200s t2.517
61281200s
61291200s 8.867
61301200s 1 8.683
71U2005 23.983
71212005 1 8.0s
7131200s 12.8
71412005 t2.367
71s12005 5.3t7
PageTOCDF Upset Conditions - 2005
o Attachment 6.1 2005 lncinerator Hours of Hazardous Waste Operation
7 /61200s 13.583
717 1200s 7.233
7181200s 0.567 3.067
7191200s 15.55
7lt0l200s 7.533
7ltu200s 12.133
7lt2l200s I 1.65
7l13l200s
7lt4l200s
7lt5n0a5 It.t67
7lt6l200s 4.983
7lt7 1200s 7.t67
7lt8l200s 1 1.65
7l19l200s 17.833
71201200s 19.1
712U200s 2t.067
71221200s 3.6t7
71231200s 5.033
7l24l20As
71251200s 4.4t7
71261200s 4.167
71271200s 6.7 5
71281200s t4.3t7
712912005 0.967 12.633
8lrl200s 1.9
8121200s
8131200s
8141200s t.2s
8151200s
8161200s 5.7 67
817 1200s t2.8
8181200s 19.5
8191200s t6.333
8lr0l200s 3.3
8/11 1200s
8lt2l20as 11.267
8l13l200s t4.9
8l14t200s 1 8.083
8ltsl200s 17 .133
8lt6l200s
8lL7 1200s 3.1
8lt8l200s 3.067
8l19l200s
81201200s 7 .0r7
8l2rDjas 7.883
81221200s
81231200s 7 .017
TOCDF Upset Conditions - 2005 Page 17 of30 6t28t2006
Attachment 6.1 - 2005 Incinerator Hours ofHazardous Waste Operation
81241200s 5
8l2sl200s
81261200s 23.983
8127 1200s 23.983
81281200s 22.8
81291200s 23.983
81301200s 23.983
813U200s 23.983
9ly200s 23.667
9121200s 23.983
9131200s 23.983
9141200s 23.983
9lsl200s 23.983
9161200s 23.333
917 12005 t9.317
9181200s 23.983
9191200s 23.983
9lL0l200s 23.983
91rU2005 23.733
9lt2l200s 23.983
9lt3l200s 23.983
9lt4l200s 13.6t7
9lts12005 tt.25
91r6t2005 23.983
9lt7l200s 23.983
9lt8l200s 23.983
9l19l200s 23.983
9120t200s 23.25
912y200s t8.7
912212005 23.983
91231200s 23.983
9t241200s 23.983
9lzsl200s 23.983
91261200s 23.983
9t27 t2005 23.983
9t28t200s 23.983
9129t200s 23.25
913012005 23.983
10/1 1200s 23.983
101212005 23.983
101312005 t2.033
tal4D005 8.9
t0l5l200s 16.4t7
t0l6l200s 13.7 s
t017 12005 9.367
101812005 3.017
r019l200s 13.6
o
TOCDF Upset Conditions - 2005 Page l8 of30 6t2812006
o
.
Attachment 6.1 2005 Incinerator Hours of Hazardous Waste Operation
,10/10/2005 12.533
10/1 U200s 17.0r7
10/121200s 15
10/131200s 1 1.6
t0lr4l200s t2.05
10/1s1200s 18.783
l0/1 61200s 9.983
10/171200s 16.55
l0/r 8/200s 15.25-
t0lt91200s t2.45
rcl2an00s 9.033
l0l2U200s 9.583
t01221200s t2.933
101231200s rs.4t7
r01241200s 7.033
1,012512005 8.033
1012612005 8.5
1a12712005 2r.067
1,012812005 t3 .7 83
1012912005 3.417
101301200s 4.6
t0l3U200s 4.t33
tUU200s 5.933
rLl4l200s 10.633
tU5l200s 16.25
rU6l200s 2
lU7 1200s 1.85
tU8l200s
lUrv200s 4.167
tUt3l200s 7 .95
rUt4l200s
tUtsl200s 5.983
tUt6l200s 6.2s
rUr7l200s 1.833
tt/2U200s 0.867
tU22l200s .4.2t7
tt/23/2005 3.933
tU241200s 10.0 17
tU25l200s t6.867
LU26l200s 9.583
tU27 12005 t2.s
rU2812005 9.6
tU2912005 3.2
tzlU200s 6.15
t2l3l200s 2.417
t2l4l200s 4.067
tzls12005 8.567
Page 19 of 30TOCDF Upset Conditions - 2005 612812006
a Attachment 6.1 2005 Incinerator Hours of Hazardous Waste Operation
tzl6l200s 5.8s
r2l7l200s 7.4
12191200s t.9t7
Lzlt2l200s 3.167
r2lt3l20as 9.617
tzlt4l200s 15.05
l2ltsl200s 9.4t7
l2lt6l200s t2.l
121171200s 4.683
r2lr8l200s 6.967
l2lt9l200s 2.r33
r21201200s
1212u2005 7 .617
t21251200s 3.267
121261200s 3.1
121271200s 23.983
t212812005 2.05
121301200s 5.2
NOTE: tf no operatior:nl durations are shown flir a particulardate, then the incineratordid not operate on that date.
** Periods when only SDS was processed are not included in this evaluation. This results in the development of a
more conservative emission multiplier because metal and organic concentrations in the SDS are negligible.
For example both LICs processed SDS in the second half of the year after agent operations had been
completed. If the time processing SDS had been included in this evaluation the hours of operation would have
increased significantly resulting in a much lower emission rate multiplier
TOC.DF Upset Conditions - 2005
a
Page 20 of 30 6128t2006
Daily Totals for LIC1 Upset Condition Episodes in 2005
Duration
hh:mm:sec
Event Date
Ut4/200s
2t4t200s
2/5/2005
2t9t200s
2n8t200s
2t22t200s
2126t200s
2t27 t200s
3lt/200s
3lt2t200s
3n3/200s
3lt6t200s
3lt7 t200s
3n8t200s
31261200s
3127 tzo}s
3130t200s
4/U700s
4/4/200s
4/7lzo1s
4t8/200s
4nI/2A05
4n2t200s
4n4/2A0s
4/15t200s
4lt6t200s
4lt8t200s
4t22t200s
4t23t200s
4t24t200s
4t28t200s
4129t200s
sn/200s
s/3t200s
514t2005
516/200s
- 5/7 /2005
5n2t2005
slr6t200s
slt7 t200s
5t20t200s
512U200s
5123t200s
st24t200s
5tzst2005
5126t2005
5127 t200s
51281200s
5129t200s
00:00:30
00:02:00
00:00:30
00:01 :00
00:01:30
00:01 :00
00:00:30
00:02:00
00:01 :30
00:00:30
00:00:30
00:01:30
00:02:30
00:02:00
00:03:30'
00:01 :00
00:03:00
00:01:00
00:02:00
00:01:30
00:01:00
00:01:30
00:01:30
00:00:30
00:02:00
00:00:30
00:02:00
00:01 :00
00:02:00
00:01 :30
00:02:01
00:00:30
00:03:01
00:02:00
00:00:30
00:01 :30
00:03:30
00:02:30
00:01 :00
00:02:00
00:03:30
00:00:30
00:05:31
00:00:30
00:01 :00
00:01 :30
00:03:00
00:00:30
00:02:30
2t9t2005
2t22t200s
2t26t200s
3t26t2005
3t30t2005
4nst2005
4122t200s
4t23t2005
4t29t2005
snt2005
st6t200s
sn2t200s
sl23t200s
st26t2a0s
00:00:30
00:02:30
00:01 :30
00:01 :00
00:18:3 I
00:00:30
00:00:30
00:00:30
00:03:00
00:01 :00
00:01 :30
00:00:30
00:03:30
00: l3:00
2t4/2005
2lsl200s
2n7 t2005
2lt8l200s
3112t2005
yt3Daas
3n6t200s
4141200s
4lt4l200s
4ltst200s
4tr8t200s
4122t2005
4t23t200s
4127 t2005
51312005
il6D0As
s17 t2005
'5nU2005
sn2t200s
st20t200s
sl23/2005
5124/20As
sl26t200s
st27 t200s
st29t200s
613/200s
614/2005
00:02:00
00:03:00
00:01 :00
00:01 :00
00:00:30
00:00:30
00:00:30
00:00:30
00:01 :30
00:01 :00
00:01:30
00:01 :00
00:04:00
00:01 :30
00:01:00
00:01 :00
00:00:30
00:01 :00
00:01 :00
00:01 :00
00:00:30
00:01 :00
00:02:30
00:03:00
00:02:00
00:01 :00
00:00:30
TOCDF Upset Conditions - 2005 Page 2l of30 6t28t2W6
Duration
hh:mm:sec
Event Date Duration
hh:mm:sec
6131200s
6141200s
6n6t200s
00:00:30
00:02:30
00:02:00
NOTE: lfno event dates or durations are shown for a particular parameter, then there were no times for the specified date range and
incinerator when non:peak perfonnance conditions were occurring.
Total Time of Operation under Non-Peak Performance (Upset) Conditions
for LIC1 in 2005 (hours
lug. 22 of30TOCDF Upset Conditions - 2005 6t28t2006
6.3 Daily Totals for LICzUpset Condition Episodes in 2005
NOTE: If no event dates or durations are shown for a particular parameter, then there were.no times for the specifiod date range and
incinerator when non-peak performance conditions were occurring.
for LICZ in 2005 (hours
TOCDF Upset Conditions - 2005
Event Date Duration
hh:mm:sec
Ut4l200s
2lt7 t200s
2/281200s
3lU200s
3126t200s
312712005
31301200s
4n/2005
4t4t200s
417 t2005
4t8t200s
4/tU200s
4n2t200s
00:01 :00
00:01 :00
00:00:30
00:00:30
00:01 :30
00:00:30
00:00:30
00:01 :00
00:01 :00
00:02:00
00:00:30
00:01 :00
00:00:30
Ut4l200s
3lU200s
31261200s
3127 D0A5
3t3012005
4lU200s
4t31200s
4141200s
4171200s
4ltu200s
411212005
00:00:30
00:01 :00
00:02:30
00:01:00
00: l9:00
00:08:00
00:01:00
00:10:30
00: l0:30
00:06:00
00:01 :00
Total Time of Operation under Non-Peak Performance (Upset) Conditions
Page 23 of30 6t28t2006
O 6.4 Daily Totals for DFS Upset Condition Episodes in 2005
TOCDF Upset Conditions - 2005
:mm:sec
4D0DAl5
4t23t200s
sl29t200s
51301200s
00:08:01
00:01 :30
00:09:00
00:26:31
t/3t200s
U4t200s
U tst2005
218/200s
2n0t2005
211U2005
2lr4l200s
3lt/200s
3t5t2005
3n2t2005
3n3t200s
3lt4t200s
3tr5t2005
3t20t200s
3t2U2005
3123t2005
3t24t200s
3t26t200s
3127 /200s
3D8DA05
313U200s
4t2t2005
4t3t2005
4lst200s
4t61200s
417 /2005
411U2005
41t2t2005
4lt7 /2005
4lt8l20as
4t20t200s
4t2U2005
4t22/20A5
41231200s
4D5DA05
4126t200s
41281200s
4t29/2005
5t3t2005
5t4t200s
51612005
s/7 t200s
5n2t2005
5n3t2005
slt4l200s
s/ l 8/2005
5t2U2005
sl23l200s
sl27l200s
5t2912005
00:00:30
00:00:30
00:00:30
00:02:30
00:00:30
00:01:00
00:00:30
00:00:30
00:00:30
00:00:30
00:00:30
00:01:00
00:00:30
00:04:00
00: l5:00
00:00:30
00:00:30
00:00:30
00:01 :00
00:00:30
00:00:30
00:00:30
00:03:01
00:00:30
00:00:30
00:00:30
00:03:00
00:05:01
00:02:01
00:02:00
00:04:30
00:18:00
00:01 :00
00:00:30
00:00:30
00:00:30
00:05:00
00:01 :30
00:01 :01
00:00:30
00:37:32
00:01 :00
00:02:00
00i46:00
00:01 :00
00:3 l:02
00:00:30
00:00:30
00:01 :30
00:04:30
516/200s
51301200s
00:01:00
00:04:30
sl30t200s 00:04:30
6t28t2006Page 24 of30
NOTE: If no event dates or durations are shown for a particular parameter, then there were no times for the specified date range and
incinerator when non-peak performance conditions were occurring.
Total Time of Operation under Non-Peak Performance (Upset) Conditions
for DFS in 2005 (hours)
TOCDF Upset Conditions - 2005 Page 25 of30
o Daily Totals for MPF Upset Condition Episodes in 2005
Event Date Event Date
Ut7 t200s
214t200s
61t4t2005
6ltst200s
7 n8t2005
7 t2v2005
9t13t200s
9lt4t200s
tol3t200s
00:00:30
00:02:30
00:00:30
00:02:30
00:00:30
00:01 :00
00:01 :00
00:00:30
00:00:30
Int200s
u6t200s
u9t2005
Ur6t2005
In7 t2005
U2U2005
213t200s
2/4t200s
2tst2005
216120]05
2/7 t2005
znst200s
2t2U2005
2t22t2005
s19l200s
sn0t200s
slt4t2005
511712005
sng'tzoos
5t3U2005
6lU200s
6121200s
6t4t2005
61s12005
6t7 t200s
6ltU200s
6/13t200s
6lt6t200s
6120t2a0s
61221200s
61241200s
6l2st200s
6/26t200s
6/27 /200s
61291200s
61301200s
7lu200s
719t2005
7 n9t2005
712U2005
712712005
8/t5t200s
8t261200s
812712005
8t28t2005
8129t200s
8130t200s
8/31 t2005
9nt2005
9121200s
00:01 :30
00:01:30
00:01 :00
00:02:00
00:00:30
00:01 :30
00:01 :3 I
0l:28:31
00:03:01
00:00:30
00:00:30
00:00:30
00:02:00
00:00:30
00:00:30
00:00:30
00:00:30
00:03:01
00:00:30
00:01 :01
00:01 :30
00:00:30
00:00:30
00:00:30
00:00:30
00:01 :30
00:01 :00
00:00:30
00:05:30
00:01:00
00:01 :00
00:01 :00
00:01 :30
00:00:30
00:02:00
00:03:30
00:39:30
bo:o I :30
00:00:30
00:51 :05
00:42:31
00:00:30
00:06:00
00: l9:00
00:07:30
00:03:00
00:09:01
00:03:30
00:00:30
00:02:00
2/41200s
2/5t2005
212U2005
7lu200s
7 t2U200s
8/31 12005
9l4DA0s
911412005
91301200s
l0/l U2005
00:07:30
00:01 :00
00:01 :01
00:08:30
00:01 :30
00:00:30
00:01 :01
00:03:30
00:01 :30
00:00:30
7lu200s
t01271200s
00:00:30
00:01:00
TOCDF Upset Conditions - 2005 Page 26 of30 6t28t2006
I
-(
O
o
NQ[E:. If no event dates or duratiors are shown for a particular parameter, then there were no times for the specified date range and
incinerator when non-peak performanoe conditions were occurring.
Total Time of Operation under Non-Peak Performance (Upset) Conditions
for MPF in 2005 (hours
Event Date
9131200s
9t4t2005
9151200s
9161200s
9t712005
9t812005
9t9DA05
9n0t200s
gntt2005
9n2t2005
9l13t200s
9n4t2005
l0/1412005
10/r 8/2005
10t28/2005
tznl200s
00;01:30
00:37:32
00:09:30
00:06:30
00:05:30
00:08:00
00:02:30
00:05:30
00: l2:01
00:01 :00
00:07:00
00:07:00
00:00:30
00:00:30
00:00:30
00:00:30
TOCDF Upset Conditions - 2005 Page 27 of30 6t28t2006
6.6 Data Gaps for Incinerators in 2005
LICI
CO
Int2005 Missing Data for 3:00, 4:00 and
5:00 a.m.Database problems. No data available.
U2412005 Missing data for l8:00.Hard drive replacement, server was down.
3n812005 Data between 311812005 02:25:06
and 02:34:45 does not exist.fhe server went through a reboot at this time.
4Bl200s Missing data for 2:00 a.m.Iime change. Data not available.
9lrsl200s Missine Data for 5:00 p.m.System offline for - I hour.
DP
I lt 12005 Missing Data for 3:00, 4:00 and
5:00 a.m.Database problems. No data available.
U24t2005 Missine data for l8:00.Hard drive replacement, seruer was down.
4131200s Missine data for 2:00 a.m.fime change. Data not available.
9ltsl200s Missing Data for 5:00 p.m.System offline for - I hour.
FLOW
t lt 1200s Missing Data for 3:00, 4:00 and
5:00 a.m.Database problems. No data available.
U2412005 Missine data for l8:00.Hard drive replacement, server was down.
4t31200s Missine data for 2:00 a.m.Iime change. Data not available.
9n5t2005 Missine Data for 5:00 p.m.System offline for - I hour.
TEMP
I I I t2005 Missing Data for 3:00, 4:00 and
5:00 a.m.Database problems. No data available.
U2412005 Missing data for l8:00.Hard drive replacement, server was down.
4t3t2005 Missing data for 2:00 a.m.fime change. Data not available.
9lts12005 Missine Data for 5:00 p.m.System offline for - I hour.
LIC2
CO
I tr t2005 Missing Data for 3:00, 4:00 and
5:00 a.m.Database problems. No data available.
U24t2005 Missine data for l8:00.Hard drive replacement, server was down.
4t31200s Missine data for 2:00 a.m.Iime change. Data not available.
9n5t2005 Missing Data for 5:00 p.m.System offline for - I hour.
DP
Ln12005 Missing Data for 3:00, 4:00 and
5:00 a.m.Database problems. No data available.
U2412005 Missine data for l8:00.Hard drive replacement, server was down.
4t3t200s Missing data for 2:00 a.m.Iime change. Data not available.
9lrs12005 Missine Data for 5:00 p.m.System offline for - I hour.
tUt2l200s Data between llll2l2005 l3: I 3:41
and I 3:22:29 does not exist.Ihe server went through a reboot at this time.
n12912005 Data does not exist for l:00 p.m.Ihe analog acquisition stopped recording the last
Few entries for this hour.
FLOW
uU2005 Missing Datafor 3:00, 4:00 and
5:00 a.m.Database problems. No data available.
U241200s Missing data for 18:00.Hard drive replacement, server was down.
4t3t200s Missing data for 2:00 a.m.Iime change. Data not available.
9lrs12005 Missine Data for 5:00 p.m.System offline for - I hour.
I v1212005 Data between llll2l2005 l3: l3:41
and l3:22:29 does not exist.The server went through a reboot at this time.
I t t29t2005 Data does not exist for l:00 p.m.Ihe analog acquisition stopped recording the last
[ew entries for this hour.
TEMP
t lt 12005
Missing Data for 3:00, 4:00 and
5:00 a.m.Database problems. No data available.
U24DA05 Missine data for l8:00.Hard drive replacement. server was down.
4t3t2005 Missins data for 2:00 a.m.Iime change. Data not available.
9n5t2005 Missins Data for 5:00 p.m.System offline for - I hour.
DFS
CO I I | 12005
Missing Data for 3:00, 4:00 and
5:00 a.m.
Database problerns. No data available.
U2412005 Missine data for l8:00.Hard drive replacanent, server was down.
TOCDF Upset Conditions - 2005 Page 28 of30 6t2812006
DFS
41312005 Missing data for 2:00 a.m.fime chanse. Data not available.
9ltsl200s Missing Data for 5:00 p.m.System offline for - I hour.
DP
U112005 Missing Data for 3:00, 4:00 and
5:00 a.m.Database problems. No data available.
U24t200s Missing data for l8:00.Hard drive replacement, server was down.
41312005 Missing data for 2:00 a.m.Iime change. Data not available.
9n5t200s Missins Data for 5:00 p.m.System offline for - I hour.
FLOW
U24/2005 Missing data for l8:00.Hard drive replacernent, server was down.
4t3t2005 Missing data for 2:00 a.m.fime change. Data not available.
9ltst2005 Missine Data for 5:00 p.m.System offline for - I hour.
TEMP
I I I12005 Missing Data for 3:00, 4:00 and
5:00 a.m.Database problems. No data available.
U24t200s Missine data for l8:00.Hard drive replacement, server was down.
4t312005 Missing data for 2:00 a.m.fime change. Data not available.
91t512005 Missine Data for 5:00 p.m.System offline for - I hour.
MPF
CO
I lt 12005 Missing Data for 3:00, 4:00 and
5:00 a.m.Database problems. No data available.
U24/200s Missing data for l8:00.Hard drive replacement, seryer was down.
4131200s Missing data for 2:00 a.m.Iime change. Data not available.
9n5t200s Missing Data for 5:00 p.m.System offline for - t hour.
DP
UU200s Missing Data for 3:00, 4:00 and
5:00 a.m.Database problems. No data available.
U24t200s Missing data for 18:00.Hard drive replacement, server was down,
3lt8/200s J2:25:06 and 02:34:45 does not
gxist.Ihe server went through a reboot at this time.
48D0Ai5 Missing data for 2:00 a.m.Iime change. Data not available.
9lls12005 Missing Data for 5:00 p.m.System offline for - I hour.
FLOW
I lt 12005 Missing Data for 3:00, 4:00 and
5:00 a.m.Database problems. No data available.
U2412005 Missing data for l8:00.Hard drive replacement, server was down.
3n8t2005 J2:25:06 and 02:34:45 does not
gxist.Ihe server went through a reboot at this time.
4t3t2005 Missine data for 2:00 a.m.Iime change. Data not available.
9lts12005 Missing Data for 5:00 p.m.System offline for - I hour.
TEMP
I lt 12005 Missing Data for 3:00, 4:00 and
5:00 a.m.Database problems. No data available.
U24t2005 Missing data for l8:00.Hard drive replacement, server was down.
vt8t2a0s )2:25:06 and 02:34:45 does not
sxist.fhe server went through a reboot at this time.
413/200s Missing data for 2:00 a.m.Iime change. Data not available.
911512005 Missing Data for 5:00 p.m.System offline for - I hour.
TOCDF Upset Conditions - 2005 Page 29 of30 6t28t2006
a
6.7 Modified Emission Rate Multipliers - 1999 to 2005
O
Percent of Time Non-Peak
Performance Occurs
( Parti cu I ate/lVl et a I s)
0.124 0.039 0.040 0.026 0.047 0.107 0.159
Percent of Time Non-Peak
Performance Occurs (Oreanics)0.120 0.008 0.136 0.003 0.088 0.1 02 0.162
Modified Emission Rate
Multiplier (Particulate/lVl etals l.0l r 1.003 1.004 1.002 1.004 l.0l l.0l
Modified Emission Rate
Multiplier (Oreanics)l.0l I l .001 1.012 1.000 r.008 1.01 l.0l
Percent of Time Non-Peak
Performance Occurs
(P a rt icu late/lVl et a I s)
0.032 0.046 0.059 0.0s3 0.144 0.r49 0.87s
Percent of Time Non-Peak
Performance Occurs (Organics)0.050 0.101 0.051 0.007 0.042 0.133 0.1 6s
Modified Emission Rate
M ultinlier (Particul atellVl etals)1.003 1.004 1.00s 1.005 t.013 I.0r r.08
Modified Emission Rate
Multiplier (Oreanics)1.005 1.009 1.005 1.001 1.004 1.00 1.01
Percent of Time Non-Peak
Performance Occurs
(Pa rti cu I atellVl eta I s)
0.008 0.006 0.00 r 0.000 0.00s 0.006 0.3s6
Percent of Time Non-Peak
Performance Occurs (O rsanics)0.000 0.000 0.000 0.000 0.000 0.000 0.052
Modified Emission Rate
Multiplier (Particulate/lVl etals)r.001 1 .001 1.000 1.000 1.000 1.00 1.03
Modified Emission Rate
Multiplier (Oreanics)1.000 1.000 1.000 1.000 1.000 1.00 1.00
Percent of Time Non-Peak
Performance Occurs
(Particu I atel]Vl etal s)
0.000 0.004 0.002 0.062 0.066 0.145 0.191
Percent of Time Non-Peak
Performance Occurs (Organics)0.000 0.000 0.000 0.000 0.006 0.000 0.004
Modified Emission Rate
Multiplier (Particul atellVl etals)1.000 r.000 1.000 1.006 1.006 1.01 1.02
Modified Emission Rate
Multiplier (Oreanics)1.000 1.000 r.000 1.000 I .001 r.00 1.00
6t28t2006TOCDF Upset Conditions - 2005 Page 30 of30
Document Scanning Form
(One Form for Each f)ocument to be Scanned)
Department: Environmental Quality
Division: Solid and Hazardous Waste
Branch: Hazardous Waste Branch
Section: Chemical Demilitarization
Section
Facility Names TOCDF
Tracking Number: 2002.02212
Library Number: TOCDF01268
File Number:
In / Out: I
Item Date: 6128106
Date Received: 6129106
Subject: Incinerator Upset Condition
Estimate-2005
PDRAS Review Based
hivilege Point: PUBLIC
Excalibur Library Chem'Demil Library
Name:
Multiple Volumes: 0
Volume Number: 0
volume Tifle: TOCDF01268
Scan Date. 7110106
ocR Date: 7110106
Who Done It: KG