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HomeMy WebLinkAboutDSHW-2014-004625 - 0901a0688040fbdbMarch 10,2014 8200-FY14-079 Mr. Scott T. Anderson, Executive Secretary State of Utah Department of Environmental Quality Division of Solid and Hazardous Waste 195 N.1950 W. P.O. Box 144880 Salt Lake City, Utah 84114-4880 Re: ATK Launch Systems-Promontory EPA ID number UTD009081357*/ Revised Addendum Air Dispersion Modeling Report for Open Burning and Open Detonation at ATK Launch Systems in Promontory, Utah Dear Mr. Anderson: Enclosed is the Revised Addendum Air Dispersion Modeling Report for Open Burning and Open Detonation (OB/OD) at ATK Launch Systems Inc. ("ATK") in Promontory, Utah. The information from this modeling report is necessary to conduct the Human Health and Ecological Risk Assessments for ATK's OB/OD operations. Please contact me if you have any questions concerning this report. My telephone number is (435)863-2018 or you can contact Blair Palmer at (435)863-2430. Sincerely George E. Gooch, Manager Environmental Compliance cc: JeffVandel ADDENDUM AIR DISPERSION MODELING REPORT FOR OPEN BURNING AND OPEN DETONATION AT ATK LAUNCH SYSTEMS IN PROMONTORY, UTAH Revision Prepared for: Utah Department of Environmental Quality Division of Solid and Hazardous Waste Prepared by: (fit CB&I Environmental & Infrastructure, Inc. 2790 Mosside Boulevard Monroeville, Pennsylvania 15146 Project No. 146690 March 2014 Table of Contents List of Tables iv List of Figures iv List of Attachments iv List of Acronyms & Abbreviations v 1.0 Introduction 1 2.0 Description of Emission Source 3 2.1 Open Burning 3 2.2 Open Detonation 3 3.0 Emission Rates of Regulated Air Pollutants and Air Toxics 4 3.1 NAAQS Analysis 4 3.2 Air Toxics Analysis 5 4.0 Emission Source Parameters 8 4.1 Emission Rate 8 4.1.1 M-136 Stations 8 4.1.2 M-225 Stations 9 4.2 Release Height of Vapor Cloud 9 4.2.1 Open Burning 9 4.2.2 Open Detonation 10 4.3 Initial Dimensions of Vapor Cloud 10 4.3.1 Open Burning 10 43.2 Open Detonation 11 4.4 Other Source Parameters 12 4.4.1 M-136 Stations 12 4.4.2 M-225 Stations 13 4.5 Summary of AERMOD Modeling Parameters 13 4.5.1 M-136 Stations 13 4.5.2 M-225 Stations 16 5.0 Model Defaults and Assumptions 19 6.0 Meteorological Data 20 6.1 Meteorological Data Processing 20 6.2 Land Use and Surface Characteristics 20 7.0 Receptor Grid Layout 22 8.0 Modeled Output 24 8.1 Maximum One-Hour Impact 24 8.2 Maximum Three-Hour and 24-Hour Impacts 24 8.3 Maximum Annual Impact 24 CB&I Environmental S Infrastructure, Inc. jj Addendum to Air Quality Modeling Report " ATK Launch Systems 9.0 Compliance Demonstration with NAAQS and Air Toxic Standards 26 9.1 NAAQS Analysis 26 9.2 Air Toxics Analysis 27 10.0 Development of Air Dispersion Factors for Risk Assessment 30 10.1 Receptor Locations 30 10.2 Pollutant Phases 34 10.3 One-Hour ADF for Concentration 37 10.4 Annual ADF for Concentration 37 10.5 Annual ADF for Deposition 38 10.6 Summary of ADFs 38 11.0 Conclusion 39 Attachments CBSI Environmental I Infrastructure, Inc. iii Addendum to Air Quality Modeling Report ATK Launch Systems List of Tables Table 3-1 Criteria Pollutants Considered in NAAQS Compliance Demonstration Table 3-2 Maximum Emission Factors including Background Concentrations - Criteria Pollutants Table 3-3 Acute and Chronic Air Toxic Screening Levels Table 3-4 Maximum Emission Factors including Background Concentrations - Air Toxics Table 4-1 M-136 Source Parameters Table 4-2 M-136 Actual Emission Rates for Criteria Pollutants Table 4-3 M-136 Actual Emission Rates for Air Toxics Table 4-4 M-225 Source Parameters Table 4-5 M-225 Actual Emission Rates for Criteria Pollutants Table 4-6 M-225 Actual Emission Rates for Air Toxics Table 9-1 Results of Cumulative Impact for M-136 and M-225 - Criteria Pollutants Table 9-2 Results of Cumulative Impact for M-136 and M-225 - Acute One-Hour Air Toxics Table 9-3 Results of Cumulative Impact for M-136 and M-225 - Chronic 24-Hour Air Toxics Table 10-1 Particle Distribution Data List of Figures Figure 7-1 Off-site/Boundary Receptor Grid Layout Figure 10-1 M-136 On-site Receptor Grid Layout Figure 10-2 M-225 On-site Receptor Grid Layout Figure 10-3 Discrete Receptor Grid Layout List of Attachments Attachment 1 Vapor Cloud Heights Attachment 2 Summary of Screened Hours Attachment 3 Detailed Modeling Results Attachment 4 Modeling Inputs/Outputs Attachment 5 Summary of ADFs for the Risk Assessment CB&I Environmental & Infrastructure, Inc iv Addendum to Air Quality Modeling Report ATK Launch Systems List of Acronyms & Abbreviations ug/m3 micrograms per cubic meter ADFs air dispersion factors AERMOD American Meteorological Society/USEPA Regulatory Modeling System ATK ATK Launch Systems g/s grams per second HHRAP Human Health Risk Assessment Protocol km kilometers lbs pounds m meter m/sec meter per second m2 square meter MEI maximum exposed individual mph miles per hour MST Mountain Standard Time NAAQS National Ambient Air Quality Standards NLCD92 National Land Cover Data 1992 NO2 nitrogen dioxide OB open burning OBODM Open Burn/Open Detonation Model OD open detonation ODOBi Open Detonation Open Bum Improved PG Pasquill-Gifford PM particulate matter ppb parts per billion SO2 sulfur dioxide TSLs toxic screening levels UDSHW Utah Department of Environmental Quality, Division of Solid and Hazardous Waste USEPA United States Environmental Protection Agency CBSI Environmental & Infrastructure, Inc. V Addendum to Air Quality Modeling Report ATK Launch Systems 1.0 Introduction ATK Launch Systems (ATK), located 30 miles west of Brigham City, Utah, currently operates open burning (OB) and open detonation (OD) units for the treatment of hazardous waste propellants and propellant-contaminated materials. These treatment units are M-136 and M-225 and are subject to Resource Conservation and Recovery Act, 40 CFR 264, Subpart X permitting requirements for miscellaneous treatment units. The Utah Department of Environmental Quality, Division of Solid and Hazardous Waste (UDSHW) required ATK to conduct human health and ecological risk assessments in support of a new Subpart X permit application. Before the human health and ecological risk assessments can be conducted, an air dispersion modeling analysis must be performed to evaluate the air quality impact of the M-136 and M-225 treatment units. The results of the air dispersion modeling analysis will be entered into human health and ecological risk assessment models to determine the risk from the ATK OB/OD treatment units. ATK submitted a preliminary air dispersion modeling draft report prepared by Tetra Tech for the OB/OD treatment units in March 2012. UDSHW made several comments on this report in a letter dated May 29, 2012. Subsequently, Tetra Tech prepared a final air dispersion modeling report dated July 2012 entitled "Revised Air Dispersion Modeling Assessment Report for Open Burn and Open Detonation Treatment Units at ATK Launch Systems," which is referred to as "preliminary modeling" or "preliminary modeling report" in this document. The preliminary modeling was conducted using the Open Burn/Open Detonation Model (OBODM) per approved protocol, which is included as Section 2.0 of the July 2012 preliminary modeling report. OBODM is specifically designed to predict the air quality impact of OB and OD treatment of obsolete weapons, solid rocket propellants, and associated manufacturing wastes. The OB and OD treatment of waste propellants and propellant-contaminated materials can be classified as instantaneous events for OD treatment and as quasi-continuous events for OB treatment. The model is also designed to use either empirical emission factors such as those derived in the Dugway Proving Ground Bang Box™ or emissions predicted by a products of combustion model. The emission factors used in the preliminary modeling and in this modeling analysis were the results of testing performed in the Open Detonation/Open Burning Improved (ODOBi) test chamber. OBODM calculates peak air concentration, time-weighted air concen- trations, and dosage (time-integrated concentration) for OB and OD releases. It can also consider the effects on concentration and dosage of the gravitational settling and deposition of particulates. CB&I Environmental I Infrastructure, Inc. 1 Addendum to Air Quality Modeling Report ATK Launch Systems However, OBODM has several limitations which constrain the modeling in this application. For example, OBODM can handle only 100 receptors at a time, cannot predict deposition in complex terrain, and uses older algorithms for downwind dispersion of emitted pollutants. To overcome these limitations, ATK proposed a hybrid approach for the air modeling using the OBODM with the American Meteorological Society/U.S. Environmental Protection Agency (USEPA) Regulatory Modeling System (AERMOD) model, which is the USEPA's preferred dispersion model for short range transport (up to 50 kilometers [km]). OBODM has two distinct parts. The first part simulates the OB and OD events and generates initial parameters of the emission cloud (emission rate, cloud height, cloud diameter), and the second part is the downwind dispersion of the emission cloud. The main limitation of OBODM is in the second part (i.e., dispersion). The downwind dispersion is better handled by AERMOD which has practically no limitation on the number of receptors, can easily handle complex terrain, and handles dispersion of emission clouds based on state-of-the-art understanding of atmospheric turbulence. Thus, the revised air quality assessment was conducted using this hybrid approach based on the emission rates derived from ODOBi testing with the initial source parameters from OBODM and using these parameters in AERMOD to predict downwind dispersion and deposition. This report describes the details of this hybrid modeling approach, presents the results of the air quality impact analysis with respect to air quality standards, and presents the dispersion modeling results developed to support the risk assessment. CBJd Environmental i Infrastructure, Inc. 2 Addendum to Air Quality Modeling Report ATK Launch Systems 2.0 Description of Emission Source The two activities in the facility are OB and OD. OB treatment is considered a quasi-continuous source because the treatment event is usually complete within one hour. OD is considered an instantaneous source because treatment is completed within milliseconds. The approach to modeling these two types of events was as follows. 2.1 Open Burning OB results in combustion of the energetics and rapid rise of the hot combustion products due to buoyancy until a final height is reached. At this point, the emission cloud has no upward momentum and starts to disperse downwind. This event was simulated as an elevated volume source with the stack height equal to the final cloud height predicted from OBODM. Details of source parameters are described in Section 4.0. 2.2 Open Detonation OD results in instantaneous combustion and immediate rise of the emission cloud to a final height. The cloud height is based on the reactive waste weight, wind speed, and atmospheric stability. Once elevated, this cloud disperses downwind. This event was simulated as an elevated volume source. Details of source parameters are described in Section 4.0. CB&I Environmental & Infrastructure, Inc. 3 Addendum to Air Quality Modeling Report ATK Launch Systems 3.0 Emission Rates of Regulated Air Pollutants and Air Toxics One of the objectives of the air quality analysis was to determine compliance with all applicable National Ambient Air Quality Standards (NAAQS) and air toxics screening levels. The NAAQS and air toxics modeling pollutants and corresponding emission rates are described below. 3.1 NAAQS Analysis The criteria pollutants considered for NAAQS analysis, the averaging time, and design values are shown in Table 3-1. Table 3-1: Criteria Pollutants Considered in NAAQS Compliance Demonstration Criteria Pollutant NAAQS averaging time Design Concentration Method of Determination of Design Value PM-10 24-Hour 150 ug/m3 Sixth highest of 5 years of meteorological data PM-2.5 24-Hour 35 Ljg/m3 Average of first highest of 5 years of meteorological data PM-2.5 Annual 12 ug/m3 Average of first highest of 5 years of meteorological data S02 1-Hour 75 ppb (195 |jg/m3) Five-year average of the 99th percentile (4th highest) of the annual distribution of daily maximum 1-hour average concentrations SO2 3-Hour 1,300 |jg/m3 Five-year average of 2nd highest (not to be exceeded once per year) NO2 1-Hour 100 ppb (189 ug/m3) Five-year average of the 98th percentile (8th highest) of the annual distribution of daily maximum 1-hour average concentrations NO2 Annual 100 |jg/m3 Maximum over 5 years of meteorological data Notes: Carbon monoxide and lead NAAQS were not included because preliminary modeling, entitled "Revised Air Dispersion Modeling Assessment Report for Open Burn and Open Detonation Treatment Units at ATK Launch Systems" dated July 2012 showed compliance with NAAQS. PM = Particulate matter. NO2 = Nitrogen dioxide. SO2 = Sulfur dioxide. ppb = Parts per billion. yg/m3 = Micrograms per cubic meter. Although each pollutant and averaging period has its own method to determine the design value, for this analysis, each maximum one-hour impact was averaged over the five-year period to obtain an average maximum one-hour impact for NAAQS analysis for all pollutants except PM-10 and annual NO2. This methodology is conservative for NAAQS. For PM-10 and annual NO2, the maximum impact over the five-year period of one-hour and annual average concentrations were considered, respectively. The NAAQS modeling used emission factors from the preliminary modeling. The emission factors were derived from ODOBi testing. These emission factors are maximum values and CB&I Environmental & Infrastructure, Inc. 4 Addendum to Air Quality Modeling Report ATK Launch Systems include background concentrations expressed in pound of pollutant per pound of reactive waste referenced from Table 2-5 of the July 2012 Tetra Tech modeling report. The emission factors for NAAQS are shown Table 3-2. Table 3-2: Maximum Emission Factors including Background Concentrations - Criteria Pollutants Pollutant PM-10 PM-2.5 S02 NO2 Maximum Emission Factor (lb/lb reactive waste) 0.12 0.06 0.0005 0.0064 Reference: July 2012 Tetra Tech modeling report, Table 2-5. 3.2 Air Toxics Analysis Air toxics included in the preliminary modeling dated July 2012 were compared to respective Utah toxic screening levels (TSLs). The acute toxics and corresponding TSLs considered are listed in Table 3-18 of the July 2012 preliminary modeling report. The maximum one-hour concentrations were averaged over the five-year period and compared to the acute TSLs. The chronic air toxics and corresponding TSLs are listed in Tables 3-35 and 3-52 of the preliminary modeling report dated July 2012. The maximum 24-hour concentrations were averaged over the five-year period and compared with the chronic TSLs. The acute one-hour and chronic 24-hour TSLs are shown in Table 3-3. Table 3-3: Acute and Chronic Air Toxic Screening Levels Type of Air Toxic Pollutant Utah TSL Value (MQ/m3) Acute (1-Hour) Air Toxic Isophorone Formaldehyde Hydrogen Chloride Hydrogen Cyanide 1,2,4,-Trichlororbenzene 2,826 37 298 520 3,711 Chronic (24-Hour) Air Toxic 1,4-Dichlorobenzene 2,4-Dinitrotoluene o-Toluidine Phenol CI2 1,1,2-Trichloroethane 1,3-Butadiene 1,4-Dioxane Acetonitrile 2,004 292 642 48 1,819 49 2,402 1,119 CB&I Environmental & Infrastructure, Inc. 5 Addendum to Air Quality Modeling Report ATK Launch Systems Type of Air Toxic Pollutant Utah TSL Value (Mg/m3) Acrylonitrile Benzene Bromoform Carbon Tetrachloride Chlorobenzene Chloroform cis-1,3-Dichloropropene Cumene Styrene Toluene Vinyl Chloride Antimony Arsenic Cadmium Chromium Cobalt Manganese Mercury Nickel Phosphorus Selenium 145 18 172 350 1,535 1,628 151 8,193 2,840 2,512 28 17 0.11 0.02 0.11 0.67 6.7 0.33 1.11 3.3 6.7 The air toxics modeling used emission factors from the preliminary modeling, which was based on emission factors derived from ODOBi testing. The emission factors are the maximum emission rate which includes background concentrations expressed in pound of pollutant per pound reactive waste. The emission factors for all air toxics are shown Table 3-4. Table 3-4: Maximum Emission Factors including Background Concentrations - Air Toxics Type of Air Toxic Pollutant Maximum Emission Factor (lb/lb reactive waste) Acute (1-Hour) Air Toxics Isophorone Formaldehyde Hydrogen Chloride Hydrogen Cyanide 1,2,4,-Trichlororbenzene 5.50E-07 4.70E-05 1.80E-02 2.20E-05 1.30E-06 Chronic (24-Hour) Air Toxics 1,4-Dichlorobenzene 2,4-Dinitrotoluene o-Toluidine Phenol 7.30E-07 5.50E-07 7.00E-06 2.40E-06 CB&I Environmental & Infrastructure, Inc. 6 Addendum to Air Quality Modeling Report ATK Launch Systems Type of Air Toxic Pollutant Maximum Emission Factor (lb/lb reactive waste) Cb 1,1,2-Trichloroethane 1,3-Butadiene 1,4-Dioxane Acetonitrile Acrylonitrile Benzene Bromoform Carbon Tetrachloride Chlorobenzene Chloroform cis-1,3-Dichloropropene Cumene Styrene Toluene Vinyl Chloride Antimony Arsenic Cadmium Chromium Cobalt Manganese Mercury Nickel Phosphorus Selenium 1.20E-02 7.30E-07 2.40E-05 6.40E-07 1.90E-05 1.60E-05 4.70E-05 1.30E-06 1.50E-05 2.50E-06 6.10E-06 1.30E-06 4.20E-07 9.90E-07 1.90E-05 7.60E-06 2.90E-05 5.50E-07 6.10E-07 2.00E-05 6.10E-07 9.40E-05 7.40E-08 5.80E-05 1.10E-04 1.60E-06 Reference: July 2012 Tetra Tech modeling report, Table 2-5. To determine the emission rates used in AERMOD (in grams per second [g/s]), the maximum emission factors were multiplied by the reactive waste weight for each scenario described in Section 4.0. The treatment event for each scenario would be completed within one hour, and only one scenario would occur per hour. Based on these assumptions and since AERMOD considers emissions to be continuous over one hour, the emission rate per treatment event is equivalent to the emission rate per hour. The calculated emission rates used in AERMOD for each scenario are shown in Section 4.0. Additional details on the emission rate determination and sample calculations are included in Section 4.5.1 for M-136 and in Section 4.5.2 for M-225. CB&I Environmental & Infrastructure, Inc. 7 Addendum to Air Quality Modeling Report ATK Launch Systems 4.0 Emission Source Parameters Both the OB and OD events were modeled as elevated volume sources. The source parameters required for dispersion of volume sources are: • Emission rate • Release height of vapor cloud • Initial horizontal and vertical dimensions of the vapor cloud The methodology for determination of these source parameters was based on several discussions with UDSHW as described in this section. 4.1 Emission Rate Emission rates were estimated based on quantity of reactive waste in OB/OD events and the emission factors used in previous modeling referenced from Table 2-5 of the July 2012 preliminary modeling report. Modeling to assess ambient air quality impacts was conducted using the estimated actual emission rates for each scenario. To reduce the number of required model runs, the emission rates for a single pollutant (i.e., PM-2.5) were input to the model. The single pollutant modeling results were then applied to the other pollutants that are part of the impact analysis by scaling the modeled results by the ratio of the desired pollutant emission rate to the modeled emission rate. However, modeling in support of the risk assessment was conducted at a unit emission rate of 1 g/s to allow for application of pollutant-specific emission rates within the risk assessment software. The reactive waste quantities for each of the scenarios were based on the desired permit limits which are listed below. 4.1.1 M-136 Stations M-136 has 14 burn stations (1 through 14) and any one of the following alternative and mutually exclusive scenarios could occur in these stations: Scenario M-136-A • Al: OB in six of Burn Stations 1 through 12 at 16,000 pounds (lbs) in each station totaling 96,000 lbs reactive waste weight per event • A2: 10,000 lbs reactive waste weight per event in Burn Station 13 • A3: 16,000 lbs reactive waste weight per event in Burn Station 14 CB&I Environmental & Infrastructure, Inc. 8 Addendum to Air Quality Modeling Report ATK Launch Systems Scenario M-136-B • B: OB of 125,000 lbs of large rocket motors in Station 14 Scenario M-136-C • C: OD of 600 lbs reactive waste in Stations 13 and 14 each, totaling 1,200 lbs reactive waste weight per event Any one of Scenarios M-136-A, M-136-B, or M-136-C could occur during a single treatment event, and these scenarios would not occur simultaneously. Furthermore, only one treatment event—either Scenario M-136-A, M-136-B, or M-136-C—is considered to occur at M-136 per day. Within AERMOD, each scenario was modeled separately to obtain individual results to evaluate the impact of each of the operating scenarios. 4.1.2 M-225 Stations M-225 has four burn stations (1 through 4) and any one of the following alternative and mutually exclusive scenarios could occur in these stations: Scenario M-225-A • A: OB of 1,125 lbs of reactive waste in each of the Burn Stations 1 through 4 for a total of 4,500 lbs reactive waste weight per event Scenario M-225-B • B: OD of 600 lbs of reactive waste in Station 1 Either of the Scenarios M-225-A or M-225-B could occur during a single treatment event, and these scenarios would not occur simultaneously. Furthermore, only one treatment event—either Scenario M-225-A or M-225-B—is considered to occur at M-225 per day. Within AERMOD, each scenario was modeled separately to obtain individual results to evaluate the impact of each of the operating scenarios. 4.2 Release Height of Vapor Cloud 4.2.1 Open Burning OB results in combustion of the energetics and rapid rise of the hot combustion products due to buoyancy until a final height is reached. At this point, the emission cloud has no upward momentum and starts to disperse downwind. This event was simulated as an elevated volume source with the release height equal to the final cloud height predicted from OBODM. Based on several discussions with UDSHW and its consultant, the following approach was used for determination of cloud heights for OB events. CB&I Environmental & Infrastructure, Inc. 9 Addendum to Air Quality Modeling Report ATK Launch Systems All of the unrestricted hours (i.e., the hours that meet the operating restriction described in Section 5.0) were grouped based on wind speed and stability condition. The wind speeds were grouped in four ranges as identified below: • Category 0: 3.0 miles per hour (mph)-5.0 mph • Category 1: 5.0 mph - 7.5 mph • Category 2: 7.5 mph - 10.0 mph • Category 3: 10.0 mph-12.5 mph • Category 4: 12.5 mph - 15 mph Atmospheric stabilities were grouped in six Pasquill-Gifford (PG) atmospheric stability classes for each of the hours in each of the wind speed categories listed above. The OBODM was used to determine the vapor cloud height for each combination of the PG atmospheric stability class and wind speed categories. The vapor cloud heights were determined for the lower threshold, the higher threshold, and midpoint for each wind speed category. To ensure a conservative impact assessment, the minimum cloud height out of these three wind speeds were considered for each combination of atmospheric stability and wind speed category. This approach was presented in the March 2013 Hybrid Air Modeling Protocol and has been discussed with and accepted by UDSHW. Attachment 1 shows all vapor cloud heights determined by OBODM for each combination of the PG atmospheric stability class and wind speed categories for OB. A summary of the lowest total cloud height for each scenario is also provided. The procedure outlined here for determining the vapor cloud heights specific to meteorological conditions was conducted for each of the scenarios proposed for representing the OB/OD events. In the case of scenarios that consider simultaneous events at multiple burn stations, only one representative burn station was modeled in OBODM for each scenario. The resulting vapor cloud height was then applied to each of the other identical burn stations for that scenario. 4.2.2 Open Detonation The same procedure described for OB was used for determination of vapor cloud height for OD using the OBODM. Attachment 1 shows all vapor cloud heights determined by OBODM for each combination of the PG atmospheric stability class and wind speed categories for OD. A summary of the lowest total cloud height for each scenario is also provided. 4.3 Initial Dimensions of Vapor Cloud 4.3.1 Open Burning During rapid rise of the cloud from the OB, atmospheric air is entrained and the dimension of the cloud increases. OBODM does not calculate the initial release diameter for quasi-continuous CB&I Environmental & Infrastructure, Inc 10 Addendum to Air Quality Modeling Report ATK Launch Systems releases, such as open burns. Therefore, site observations of burn operations were utilized in estimating this parameter. Based on videos of the open burning events, the final dimensions of the cloud at final plume height are typically four to eight times larger than the dimension of the burn pans. As a conservative estimate, the cloud diameter was based on four times the equivalent diameter of the burn pans. Because the burn stations have multiple adjacent burn pans, the equivalent diameter was based on the total area covered by the reactive waste. It is assumed that the vapor cloud plume is a sphere. The burn pan layout was estimated to be four burn pans in a square pattern. Due to the circular shape of the cloud plume, the burn pan equivalent diameter is estimated assuming the burn pan area is circular. A sample calculation to determine the cloud diameter for Scenario M-136A-1 is shown in Example 4-1. Example 4-1: • M-136A-1 single burn pan size: 8 feet by 13 feet • Burn pan area of four M-136A-1 burn pans: 16 feet by 26 feet (square pattern) The initial volume source diameter is estimated to be four times the burn pan equivalent diameter or 28.06 meters (m). Per AERMOD guidance, the initial vertical and horizontal dimensions of an elevated volume source, such as the vapor cloud, were calculated by dividing the initial cloud diameter (i.e., four times equivalent diameter covered by reactive waste on burn pans) by a factor of 4.3. Detailed parameters for all scenarios are provided in Table 4-1. 4.3.2 Open Detonation The initial dimension of the vapor cloud was obtained directly from the OBODM output. As described earlier in this document, OBODM was used to model each combination of wind speed category and PG atmospheric stability considered in this phase of the analysis. OBODM yielded the same initial vapor cloud diameter for each OD scenario modeled, regardless of the meteorological conditions considered. Calculation of vapor cloud dimensions for buoyant sources is described in Section 2.6.3 of Volume 2 of the OBODM User's Guide, dated April 1998. The initial vapor cloud diameter for detonations, as presented in the OBODM output, 4 * Burn Pan Area 4 * 38.65 m2 Burn Pan Equivalent Diameter = n n = 7.01m CB&t Environmental & Infrastructure, Inc. 11 Addendum to Air Quality Modeling Report ATK Launch Systems appears to be calculated using Equation 2-75 of the OBODM User's Guide and is assumed to represent the initial diameter of the cloud immediately after detonation. Note that the initial diameter is the only lateral dimension reported in the OBODM output. Equation 2-75 determines the initial radius as a function of the quantity of material detonated, the effective heat content of the material detonated, and the ambient temperature, among other parameters. For this analysis, the ambient temperature used in OBODM was a default temperature of 293 degrees Kelvin. The modeled ambient temperature was kept constant for each combination of wind speed category and atmospheric stability evaluated. Based on a cursory analysis, variations in the ambient air temperature do not have a significant effect on the initial diameter determined by OBODM. However, at this time, OBODM is not actively supported by its developers or by any regulatory agency, and it is not entirely clear from the User's Guide how the equations presented in Section 2.6.3 are used by the model. The application of the equations for determining cloud dimensions using OBODM is considered an area of uncertainty in this analysis. Per AERMOD guidance, the initial vertical and horizontal dimensions of an elevated volume source, such as the vapor cloud, were calculated by dividing the initial vapor cloud diameter by a factor of 4.3. Detailed parameters for all scenarios are provided in Table 4-4. 4.4 Other Source Parameters 4.4.1 M-136 Stations Burn Stations 1 through 12 are clustered within 100 m of each other. Six of the 12 stations located closest to the western property line (Stations 1, 4, 7, 8, 10, and 11) were modeled as six separate sources. Burn Stations 13 and 14 were modeled separately. From previous modeling and from burn information provided by the facility, the following assumptions were made: • Burn Stations 1 through 12 each consist of four adjacent burn pans. The average dimension of each burn pan is 8 feet by 13 feet, and the burn pan layout per station is approximated as an area of 16 feet by 26 feet. • Burn Station 13 consists of two adjacent burn pans. The average dimension of each pan is 6 feet by 9 feet, and the burn pan layout for this station is approximated as an area of 9 feet by 12 feet. • Burn Station 14 consists of four adjacent burn pans. The average dimension of each burn pan is 8 feet by 13 feet, and the burn pan layout for this station is approximated as an area of 16 feet by 26 feet. • The dimension of the rocket motor burn area at Burn Station 14 is assumed to be 5 feet by 50 feet. CB&I Environmental & Infrastructure, Inc 12 Addendum to Air Quality Modeling Report ATK Launch Systems • The height of burn stations = 1.0 m. • The detonation will be started at ground level. 4.4.2 M-225 Stations Burn Stations 1 through 4 are clustered within 100 m and were modeled as a single source located approximately at the center of the cluster. The OD pit was modeled separately. From previous modeling and from burn information provided by the facility, the following assumptions were made: • Burn Stations 1 through 4 each consist of one burn pan, having an average pan dimension of 6 feet by 17 feet. • The height of burn stations = 1.0 m. • The detonation will be started at ground level. 4.5 Summary of AERMOD Modeling Parameters Based on the information, a summary of the actual parameters used for modeling are described below. 4.5.1 M-136 Stations The source parameters for M-136 are shown in Table 4-1. Table 4-1: M-136 Source Parameters Parameter M-136-A1 M-136-A2 M-136-A3 M-136B M-136-C OB/OD Identification OB OB OB OB OD Daily Quantity Burned (Ib reactive waste) 96,000 10,000 16,000 125,000 1,200 Annual Quantity Burned (Ib reactive waste) 6720,000 840,000 840,000 1,500,000 100,000 Burn Pan Area (m2) 38.65 10.03 38.65 23.23 Burn Pan Equivalent Diameter (m) 7.01 3.57 7.01 5.44 Volume Source Diameter (m) 28.06 14.3 28.06 21.75 19.51 Initial Sigma Y (m) 6.53 3.32 6.53 5.06 4.54 Initial Sigma Z (m) 6.53 3.32 6.53 5.06 4.54 Release height (m) 238 219.3 238 297 189.7 Notes: m2 = Square meter, m = Mefer. To determine the emission rates used in AERMOD, the maximum emission factors described in Section 3.0 were multiplied by the daily quantity burned for each scenario. The actual emission CB&I Environmental & Infrastructure, Inc. 13 Addendum to Air Quality Modeling Report ATK Launch Systems rates were determined based on the reactive waste for each scenario and assuming only one event would occur per hour. A sample calculation for PM-10 for Scenario M-136A-1 is shown Example 4-2. Example 4-2: • M-136A-1 reactive waste: 96,000 lbs • Maximum PM-10 emission factor from Table 3-2: 0.12 lb/lb reactive waste / lb \ lb Emission Rate = 96,000 lb reactive waste * 0.12 — ; \eventJ lb reactive waste = 11,520 lb/event Since AERMOD considers emissions to be continuous over one hour and based on the assumption that each event would occur within one hour, the lb per event is equal to the lb per hour emission rate. / lb \ /lb\ lb Emission Rate = Emission Rate — = 11,520 — \eventJ \hrJ nr Converting to grams per second: Emission Rate ) = 11,52 g\ lb 453.6 g hr ' • — * * hr lb _ =1,451.5-3600 s s The actual emission rates for NAAQS and air toxics are shown in Tables 4-2 and 4-3, respectively. Table 4-2: M-136 Actual Emission Rates for Criteria Pollutants Pollutant Emission Rate (g/s) M-136-A1 M-136-A2 M-136-A3 M-136-B M-136-C PM-10 PM-2.5 S02 NO2 1,451.5 725.8 6.0 77.4 151.2 75.6 0.6 8.1 241.9 121.0 1.0 12.9 1,890.0 945.0 7.9 100.8 18.1 9.1 0.1 1.0 Table 4-3: M-136 Actual Emission Rates for Air Toxics Pollutant Emission Rate (g/s) M-136-A Isophorone 8.45E-03 Formaldehyde 7.22E-01 CB&I Environmental & Infrastructure, Inc. 14 Addendum to Air Quality Modeling Report ATK Launch Systems Pollutant Hydrogen Chloride Hydrogen Cyanide 1,2,4,-Trichlororbenzene 1,4-Dichlorobenzene2 2,4-Dinitrotoluene o-Toluidine Phenol CI2 1,1,2-Trichloroethane 1,3-Butadiene 1,4-Dioxane Acetonitrile Acrylonitrile Benzene Bromoform Carbon Tetrachloride Chlorobenzene Chloroform cis-1,3-Dichloropropene Cumene Styrene Toluene Vinyl Chloride Antimony Arsenic Cadmium Chromium Cobalt Manganese Mercury Nickel Phosphorus Selenium Emission Rate (g/s) M-136-A 2.77E+02 3.38E-01 2.00E-02 1.12E-02 8.45E-03 1.08E-01 3.69E-02 1.84E+02 1.12E-02 3.69E-01 9.84E-03 2.92E-01 2.46E-01 7.22E-01 2.00E-02 2.31 E-01 3.84E-02 9.38E-02 2.00E-02 6.46E-03 1.52E-02 2.92E-01 1.17E-01 4.46E-01 8.45E-03 9.38E-03 3.07E-01 9.38E-03 1.44E+00 1.14E-03 8.92E-01 1.69E+00 2.46E-02 Note: Air toxics modeling was only completed for Scenario M-136-A because that scenario was determined to have the greatest impact. CB&I Environmental & Infrastructure, Inc. 15 Addendum to Air Quality Modeling Report ATK Launch Systems 4.5.2 M-225 Stations The source parameters for Scenarios M-225 are shown in Table 4-4. Table 4-4: M-225 Source Parameters Parameter M-225-A M-225-B OB/OD Identification OB OD Daily Quantity Burned (Ib reactive waste) 4,500 600 Annual Quantity Burned (Ib reactive waste) 55,000 10,000 Burn Pan Area (m2) 9.48 Burn Pan Equivalent Diameter (m) 3.47 Volume Source Diameter (m) 13.89 19.51 Initial Sigma Y (m) 3.23 4.54 Initial Sigma Z (m) 3.23 4.54 Release height (m) 148.8 189.7 To determine the emission rates used in AERMOD, the maximum emission factors described in Section 3.0 were multiplied by the daily quantity burned for each scenario. The actual emission rates were determined based on the reactive waste for each scenario and assuming only one event would occur per hour. A sample calculation for PM-10 for Scenario M-225-A is shown Example 4-3. Example 4-3: • M-225-A reactive waste: 4,500 lbs • Maximum PM-10 emission factor from Table 3-2: 0.12 lb/lb reactive waste / lb \ lb Emission Rate = 4,500 lb reactive waste * 0.12 — : = 540 lb/event \event) lb reactive waste Since AERMOD considers emissions to be continuous over one hour and based on the assumption that each event would occur within one hour, the lb per event is equal to the lb per hour emission rate. ( lb \ (lb\ Emission Rate = Emission Rate I —I — 540 -\event) \hr) nr ( lb \ (lb\ lb ^ • 1 — C-wi i pplrtti Dn+a I 1 — CAI1 Converting to grams per second: /#\ lb 453.6 5 hr g Emission Rate [ — ) — 540 — * —-— * = 68.0 — W hr lb 3600 s s The emission rates for NAAQS and air toxics are shown in Tables 4-5 and 4-6, respectively. CB&I Environmental & Infrastructure, Inc. 16 Addendum to Air Quality Modeling Report ATK Launch Systems Table 4-5: M-225 Actual Emission Rates for Criteria Pollutants Pollutant Emission Rate (g/s) M-225-A M-225-B PM-10 68.0 9.1 PM-2.5 34.0 4.5 S02 0.3 0.04 NO2 3.6 0.5 Table 4-6: M-225 Actual Emission Rates for Air Toxics Pollutant Emission Rate (g/s) M-225-A Isophorone 3.12E-04 Formaldehyde 2.66E-02 Hydrogen Chloride 1.02E+01 Hydrogen Cyanide 1.25E-02 1,2,4,-Trichlororbenzene 7.37E-04 1,4-Dichlorobenzene 4.14E-04 2,4-Dinitrotoluene 3.12E-04 o-Toluidine 3.97E-03 Phenol 1.36E-03 CI2 6.80E+00 1,1,2-Trichloroethane 4.14E-04 1,3-Butadiene 1.36E-02 1,4-Dioxane 3.63E-04 Acetonitrile 1.08E-02 Acrylonitrile 9.07E-03 Benzene 2.66E-02 Bromoform 7.37E-04 Carbon Tetrachloride 8.51 E-03 Chlorobenzene 1.42E-03 Chloroform 3.46E-03 cis-1,3-Dichloropropene 7.37E-04 CB&I Environmental & Infrastructure, Inc. 17 Addendum to Mr Quality Modeling Report ATK Launch Systems Pollutant Cumene Styrene Toluene Vinyl Chloride Antimony Arsenic Cadmium Chromium Cobalt Manganese Mercury Nickel Phosphorus Selenium Emission Rate (g/s) M-225-A 2.38E-04 5.61E-04 1.08E-02 4.31 E-03 1.64E-02 3.12E-04 3.46E-04 1.13E-02 3.46E-04 5.33E-02 4.20E-05 3.29E-02 6.24E-02 9.07E-04 Note: Air toxics modeling was only completed for Scenario M-225-A because that scenario was determined to have the greatest impact. CB&I Environmental & Infrastructure, Inc. 18 Addendum to Air Quality Modeling Report ATK Launch Systems 5.0 Model Defaults and Assumptions USEPA's AERMOD (version 12345) was used for estimating the impact of the vapor cloud on downwind receptors. To ensure the AERMOD results represent a significant refinement, the following restrictions were considered for modeling: • The events will occur only between the hours of 9:00 a.m. Mountain Standard Time (MST) and 6:00 p.m. MST • The wind speed during the events will be between 3 mph and 15 mph • The Clearing Index during the events will be 500 or higher Five years of meteorological data were screened for potential operating hours considering these restrictions. The summary of screened hours is shown in Attachment 2. These hours were modeled for the ambient impact assessment and the risk assessment. Hourly emission rate files were used in AERMOD to ensure modeling occurred only during the hours that met restrictions defined above. The hourly emission rate files identify the emission rate (g/s), release height (m), initial horizontal diameter (m), and initial vertical diameter (m) for each hour of meteorological data. An example of one hour of hourly meteorological data is shown below: SO HOUREMIS 97 01 04 13 M136_A1_1 120.96 218.5 6.53 6.53 With the parameters defined as follows: • Emission rate of 120.96 g/s • Release height of 218.5 m for Stability Class 4 (Class D) and Wind Speed Category 4 (12.5 mph to 15 mph) • Initial horizontal diameter of 6.53 m • Initial vertical diameter of 6.53 m CBSI Environmental & Infrastructure, Inc. 19 Addendum to Air Quality Modeling Report ATK Launch Systems 6.0 Meteorological Data 6.1 Meteorological Data Processing Five years (1997 to 2001) of on-site meteorological data obtained from the site were used in the preliminary modeling. As stated in Section 2.13.1 of the preliminary modeling report, the on-site meteorological data used were collected at the M-245 meteorological monitoring station, located approximately 0.35 km southwest of the M-225 treatment unit at an elevation of about 5,000 feet above mean sea level. The same meteorological data were used after reprocessing the data for AERMOD using the preprocessor, AERMET (version 12345). Non-urban (i.e., rural) land use determined from previous modeling was used in AERMET. The five years (1997 through 2001) of on-site hourly meteorological data were obtained from the site in CD-144 format and included wind speed, wind direction, temperature, and barometric pressure monitored at the site along with concurrent ceiling height and opaque cloud cover from Hill Air Force Base. Twice daily upper air data for Salt Lake City were obtained in Forecast Systems Laboratory format from the National Oceanic and Atmospheric Administration, Earth System Research Laboratory Radiosonde Database. The hourly surface meteorological observations were then used along with the twice daily Salt Lake City upper air data in the AERMET pre-preprocessor to develop surface and vertical profile meteorological databases for use in AERMOD. This processing was conducted in accordance with the latest USEPA AERMOD Implementation Guide dated March 19, 2009. 6.2 Land Use and Surface Characteristics The surface characteristics used in processing the meteorological data in AERMET were developed using the USEPA's AERSURFACE program (version 13016). The AERSURFACE program requires the input of digital land cover data from the United States Geological Survey National Land Cover Data 1992 archives (NLCD92), which it uses to determine the land cover types for the user-specified location. AERSURFACE matches the NLCD92 land cover categories to seasonal values of albedo, Bowen ratio, and surface roughness. Values of surface characteristics are calculated based on the land cover data for the area surrounding the site of the surface meteorological data collection. For this application, land use data were obtained for the area surrounding the ATK site and were used in AERSURFACE to generate values of albedo, Bowen ratio, and surface roughness as a function of the four seasons (i.e., winter, spring, summer, and fall) and for each of six 60-degree directional sectors. This approach of generating surface characteristics at the site of the surface meteorological data collection is consistent with the latest USEPA guidance (i.e., AERMOD Implementation Guide dated March 19, 2009, Ref. 7.7). CB&I Environmental & Infrastructure, Inc. 20 Addendum to Air Quality Modeling Report ATK Launch Systems The specific inputs and assumptions used in the AERSURFACE runs are as follows: • Center latitude (decimal degrees): 41.854 • Center longitude (decimal degrees): -112.432 • Datum: NAD83 • Study radius (km) for surface roughness: 1.0 • Airport? No • Continuous snow cover? No • Surface moisture? Dry • Arid region? Yes • Month/season assignments? Default • Late autumn after frost and harvest, or winter with no snow: 12 1 2 • Winter with continuous snow on the ground: 0 • Transitional spring (partial green coverage, short annuals): 3 4 5 • Midsummer with lush vegetation: 6 7 8 • Autumn with unharvested cropland: 9 10 11 The meteorological data files including the processing data files have been provided in Attachment 4. CB&I Environmental & Infrastructure. Inc 21 Addendum to Air Quality Modeling Report ATK Launch Systems 7.0 Receptor Grid Layout For NAAQS and air toxics analysis, an off-site receptor grid was used to determine the maximum off-site ground level concentrations. The layout of the receptors was as follows: Discrete receptors were placed along the property fence line at 100-m intervals. A Cartesian receptor grid starting from the property line extended up to 10 km in all directions. This Cartesian receptor grid was spaced at 100-m intervals to a distance of 3 km from the facility and at 500-m intervals between 3 km and 10 km from the facility. The off-site/boundary receptor grid is shown in Figure 7-1. >0©©0GO© 00 jHBHHI • G © O (5,8 O O O ( | 0 S 589,6891 Figure 7-1: Off-site/Boundary Receptor Grid Layout CB&I Environmental & Infrastructure, Inc. 22 Addendum to Air Quality Modeling Report ATK Launch Systems The terrain data for each receptor were processed using AERMOD's terrain data preprocessor, AERMAP. Using AERMAP, the base elevation and hill height scale values were determined for each receptor. The digital terrain data were obtained from 1 arc second National Elevation Dataset. The receptor grids used in the modeling conducted in support of the risk assessment are discussed in detail in Section 10.1 and include the off-site receptor grid described above. CB&I Environmental & Infrastructure, Inc. 23 Addendum to Air Quality Modeling Report ATK Launch Systems 8.0 Modeled Output The OB and OD events were considered for only one hour per day. NAAQS compliance was demonstrated by comparing the design modeled concentration for all pollutants and averaging times with the respective NAAQS. The methodologies for one-hour, three-hour, 24-hour, and annual impacts are described as follows. 8.1 Maximum One-Hour Impact AERMOD was used to calculate the maximum one-hour average impact over each year of five years of meteorological data covering all of the unrestricted hours of operation. This is the maximum one-hour average concentration for the OB/OD operations in any day of the year for each of the five years. These five one-hour average impacts for the five years were averaged to obtain the five-year average maximum one-hour impact. 8.2 Maximum Three-Hour and 24-Hour Impacts Because only one hour of OB/OD events will occur in any day (and there is no impact during the remainder of the day), the maximum values of three-hour and 24-hour averages were also based on the one-hour maximum value. For example, the maximum 24-hour average concentration in any year was calculated by dividing the maximum one-hour concentration for that year by a factor of 24 as shown below: Maxx-hr Max2±-hr = 24 Where: •1 Max24.hr = Maximum 24-hour average concentration in ug/m Maxi.hr = Maximum one-hour average concentration in ug/m Similarly, for the maximum three-hour concentrations, the maximum one-hour average is divided by three. The maximum three-hour and 24-hour averages for each of the five years were averaged to obtain the five-year average value for each short-term averaging time. 8.3 Maximum Annual Impact The annual total OB and OD quantities are restricted by permitted levels. To account for this limitation on annual OB/OD quantities, the following calculation was used: CBSI Environmental S Infrastructure, Inc 24 Addendum ID Air Quality Modeling Report ATK Launch Systems -daily Maxannual = - Qgnnual * i UD 7) * LtiKmax 8760 Where: Maxannuai = Maximum annual average concentration in ug/m3 Qannuai = Annual quantity of reactive waste in OB/OD (lbs) Qdaiiy = Daily quantity of reactive waste in OB/OD (lbs) lHRmax = Maximum one-hour impact based on daily reactive waste quantity 8760 = Number of hours per year Note: The term [Qannuai/Qdaiiy] represents the total number of days per year the OB/OD events can occur to reach the annual permitted quantities. This assumes that for each hour the OB/OD operations were carried out to meet the annual quantity, the impact was the same as the maximum one-hour determined previously. This is a conservative assumption. Each year of maximum one-hour average impact obtained from AERMOD was used to calculate the maximum annual impact for each year. The five maximum annual impacts were averaged to obtain the five-year average annual impact. The permitted annual reactive waste quantities for the OB/OD operations are as follows. These quantities were used as the "Qannuai" in the above equation to calculate the maximum annual average concentrations. M-136: M-225: • Scenario Al - Open Burn in Stations 1 throughl2: 6,720,000 lbs • Scenario A2 - Open Burn in Station 13: 840,000 lbs • Scenario A3-Open Burn in Station 14: 840,000 lbs • Scenario B - Large Rocket Motor in Station 14: 1,500,000 lbs • Scenario C - Open Detonation in Stations 13 and 14: 100,000 lbs Scenario A - Open Burn in Stations 1 through 4: 55,000 lbs Scenario B - Open Detonation in Station 1: 10,000 lbs CB&I Environmental & Infrastructure, Inc 25 Addendum to Air Quality Modeling Report ATK Launch Systems 9.0 Compliance Demonstration with NAAQS and Air Toxic Standards One objective of the modeling was to determine compliance with all applicable NAAQS and air toxics. The NAAQS and air toxics modeling results are described as follows: 9.1 NAAQS Analysis NAAQS compliance was demonstrated by comparing the design modeled concentration for all pollutants and averaging times with the respective NAAQS. No background concentrations were added to the design modeled concentration because, as mentioned in Section 3.0, the emission factors used for the modeling included background concentration. For all averaging times and pollutants, Scenarios M-136-A and M-225-A had the highest impact. A flash drive of all modeling results are shown in Attachment 3. The design modeled cumulative results are shown in Table 9-1. Table 9-1: Results of Cumulative Impact for M-136 and M-225 - Criteria Pollutants Pollutant Averaging Time Group Rank Design Model Cone. (M9/m3) NAAQS (Mg'm3) % of NAAQS Exceedance of NAAQS? (Yes/No) PM-2.5 24-HR Annual M136_A 1ST 25.00 35 M225 A 1ST 1.48 35 Total 1ST 26.49 35 M136_A 1ST 5.75 12 M225_A 1ST 0.05 12 Total 1ST 5.81 12 71.44% 4.23% 75.67% 47.95% 0.44% 48.39% No No No No No No PM-10 24-HR M136_A 1ST 57.14 150 M225_A 1ST 3.65 150 Total 1ST 60.79 150 38.10% 2.43% 40.53% No No No NQ2 1-HR Annual M136_A 1ST 64.01 189 M225 A 1ST 3.79 189 Total 1ST 67.80 189 M136 A 1ST 0.70 100 M225_A 1ST 0.007 100 Total 1ST 0.71 100 33.87% 2.01% 35.87% 0.70% 0.007% 0.71% No No No No No No SO2 1-HR 3-HR M136 A 1ST 5.00 195 M225 A 1ST 0.30 195 Total 1ST 5.30 195 M136_A M225_A Total 1ST 1ST 1ST 1.67 0.10 1.77 1300 1300 1300 2.56% 0.15% 2.72% 0.13% 0.01% 0.14% No No No No No No CB&I Environmental & Infrastructure, Inc. 26 Addendum to Air Quality Modeling Report ATK Launch Systems Pollutant Averaging Time Group Rank Design Model Cone. (Mg/m3) NAAQS (Mg/m3) % of NAAQS Exceedance of NAAQS? (Yes/No) CO 1-HR 8-HR M136_A 1ST 64.01 40,000 M225_A 1ST 3.79 40,000 Total 1ST 67.80 40,000 M136_A 1ST 8.00 10,000 M225_A 1ST 0.47 10,000 Total 1ST 8.48 10,000 0.16% 0.01% 0.17% 0.08% 0.005% 0.08% No No No No No No The results for all pollutants and averaging times show compliance with NAAQS. Therefore, no additional modeling was required. A flash drive of all modeling inputs and outputs is provided in Attachment 4. 9.2 Air Toxics Analysis Air toxics results were compared with short-term and long-term TSLs. Results of the NAAQS analysis indicated that Scenarios M-136-A and M-225-A had the highest impact. Therefore, only these scenarios were considered for the air toxics analysis. The design modeled cumulative results for the acute and chronic air toxics are shown in Tables 9-2 and 9-3, respectively. CB&I Environmental & Infrastructure, Inc. 27 Addendum to Air Quality Modeling Report ATK Launch Systems Table 9-2: Results of Cumulative Impact for M-136 and M-225 - Acute One-Hour Air Toxics Air Toxic Acute 1-hr TSL Value Mg/m3 Scenario M136A 1-HR Cone. ug/m3 % ofTSL Exceed TSL? (Yes/No) Scenario M225A 1-HR Cone. ug/m3 % of TSL Exceed TSL? (Yes/No) Total (M136Aand M225A) 1-HR Cone. ug/m3 TSL Exceed TSL? (Yes/No) Isophorone 2,826 0.006 0.0002% No 0.0003 0.00001% No 0.006 0.0002% No Formaldehyde 37 0.470 1.27% No 0.028 0.08% No 0.498 1.35% No Hydrogen Chloride 298 180.034 60.41% No 10.662 3.58% No 190.696 63.99% No Hydrogen Cyanide 520 0.220 0.04% No 0.013 0.003% No 0.233 0.04% No 1,2,4,- Trichlororbenzene 3,711 0.013 0.0004% No 0.001 0.00002% No 0.014 0.0004% No Table 9-3: Results of Cumulative Impact for M-136 and M-225 - Chronic 24-Hour Air Toxics Air Toxic Chronic 24-hr TSL Value ug/m3 Scenario M136A 24-HR Cone. ug/m3 % ofTSL Exceed TSL? (Yes/No) Scenario M225A 24-HR Cone. ug/m3 % of TSL Exceed TSL? (Yes/No) Total (M136Aand M225A) 24-HR Cone. Mg/m3 %of TSL Exceed TSL? (Yes/No) 1,4-Dichlorobenzene 2004 3.04E-04 0.00% No 1.80E-05 0.00% No 3.22E-04 0.00% No 2,4-Dinitrotoluene 2.29E-04 0.00% No 1.36E-05 0.00% No 2.43E-04 0.00% No o-Toluidine 292 2.92E-03 0.00% No 1.73E-04 0.00% No 3.09E-03 0.00% No Phenol 642 1.00E-03 0.00% No 5.92E-05 0.00% No 1.06E-03 0.00% No CI2 48 5.00E+00 10.42% No 2.96E-01 0.62% No 5.30E+00 11.04% No 1,1,2-Trichloroethane 1819 3.04E-04 0.00% No 1.80E-05 0.00% No 3.22E-04 0.00% No 1,3-Butadiene 49 1.00E-02 0.02% No 5.92E-04 0.00% No 1.06E-02 0.02% No 1,4-Dioxane 2402 2.67E-04 0.00% No 1.58E-05 0.00% No 2.83E-04 0.00% No Acetonitrile 1119 7.92E-03 0.00% No 4.69E-04 0.00% No 8.39E-03 0.00% No Acrylonitrile 145 6.67E-03 0.00% No 3.95E-04 0.00% No 7.06E-03 0.00% No Benzene 18 1.96E-02 0.11% No 1.16E-03 0.01% No 2.07E-02 0.12% No Bromoform 172 5.42E-04 0.00% No 3.21 E-05 0.00% No 5.74E-04 0.00% No CB&I Environmental and Infrastructure, Inc. 28 Addendum to Air Quality Modeling Report ATK Launch Systems Air Toxic Chronic 24-hr TSL Value ug/m3 Scenario M136A 24-HR Cone. pg/m3 % of TSL Exceed TSL? (Yes/No) Scenario M225A 24-HR Cone. Mg/m3 % of TSL Exceed TSL? (Yes/No) Total (M136Aand M225A) 24-HR Cone. Mg/m3 %of TSL Exceed TSL? (Yes/No) Carbon Tetrachloride 350 6.25E-03 0.00% No 3.70E-04 0.00% No 6.62E-03 0.00% No Chlorobenzene 1535 1.04E-03 0.00% No 6.17E-05 0.00% No 1.10E-03 0.00% No Chloroform 1628 2.54E-03 0.00% No 1.51E-04 0.00% No 2.69E-03 0.00% No cis-1,3-Dichloropropene 151 5.42E-04 0.00% No 3.21 E-05 0.00% No 5.74E-04 0.00% No Cumene 8193 1.75E-04 0.00% No 1.04E-05 0.00% No 1.85E-04 0.00% No Styrene 2840 4.13E-04 0.00% No 2.44E-05 0.00% No 4.37E-04 0.00% No Toluene 2512 7.92E-03 0.00% No 4.69E-04 0.00% No 8.39E-03 0.00% No Vinyl Chloride 28 3.17E-03 0.01% No 1.88E-04 0.00% No 3.35E-03 0.01% No Antimony 17 1.21E-02 0.07% No 7.16E-04 0.00% No 1.28E-02 0.08% No Arsenic 0.11 2.29E-04 0.21% No 1.36E-05 0.01% No 2.43E-04 0.22% No Cadmium 0.02 2.54E-04 1.27% No 1.51 E-05 0.08% No 2.69E-04 1.35% No Chromium 0.11 8.33E-03 7.58% No 4.94E-04 0.45% No 8.83E-03 8.03% No Cobalt 0.67 2.54E-04 0.04% No 1.51 E-05 0.00% No 2.69E-04 0.04% No Manganese 6.7 3.92E-02 0.58% No 2.32E-03 0.03% No 4.15E-02 0.62% No Mercury 0.33 3.08E-05 0.01% No 1.83E-06 0.00% No 3.27E-05 0.01% No Nickel 1.11 2.42E-02 2.18% No 1.43E-03 0.13% No 2.56E-02 2.31% No Phosphorus 3.3 4.58E-02 1.39% No 2.71 E-03 0.08% No 4.86E-02 1.47% No Selenium 6.7 6.67E-04 0.01% No 3.95E-05 0.00% No 7.06E-04 0.01% No The results for all pollutants and averaging times show compliance with Utah's TSLs. Therefore, no additional modeling was required. A flash drive of all modeling inputs and outputs is provided in Attachment 4. CB&I Environmental and Infrastructure, Inc. 29 Addendum to Air Quality Modeling Report ATK Launch Systems 10.0 Development of Air Dispersion Factors for Risk Assessment In addition to demonstrating compliance with NAAQS and air toxics standards, another objective of the modeling was to develop factors in support of future risk assessment. Human health and ecological risk assessment requires maximum values of one-hour and annual average air dispersion factors (ADFs) for gas concentration, particulate concentration, gas dry deposition, and particulate dry deposition at selected receptor locations. These ADFs were generated using the hybrid OBODM and AERMOD models as described earlier. 10.1 Receptor Locations The ADFs were estimated at the maximum exposed individual (MEI) locations within the facility and off site. The MEI locations are the locations of maximum impact at on-site and off- site locations. The site boundary was included in both on-site and off-site receptor grids for consistency. The on-site receptor grid consisted of a Cartesian grid with 100-m spacing to cover the area bounded by the facility property boundary. The worker safety buffer zones, consisting of an approximate 2,000-foot radius around the M-136 location and an approximate 2,500-foot radius around the M-225 location, were excluded from the on-site receptor grid when modeling each scenario, respectively. These buffer zones represent the area from which field personnel are excluded during OB/OD events. The off-site receptor grid and the site boundary receptors used were as described in Section 7.0 for the air quality assessment. Figures 10-1 and 10-2 show the on-site receptor grids for M-136 and M-225 modeling, respectively. CB&I Environmental and Infrastructure, Inc 30 Addendum to Air Quality Modeling Report ATK Launch Systems Figure 10-1: M-136 On-site Receptor Grid Layout CB&I Environmental and Infrastructure, Inc. q A Addendum to Air Quality Modeling Report ^ ' ATK Launch Systems Figure 10-2: M-225 On-site Receptor Grid Layout In addition, the risk assessment will consider several discrete locations in and around the facility. ADFs were determined for these discrete locations which are listed below: • The Adam's Ranch, which is the closest domestic dwelling to M-136, is located approximately 3 km south-southwest of M-136. • The Holmgren Ranch, which is the closest domestic dwelling to M-225, is located approximately 2 km east-southeast of M-225. • Four facility boundary receptors that are selected based on the annual prevailing wind direction measured over a five-year period (1997 through 2001) at the M-245 meteorological monitoring station. CBSI Environmental and Infrastructure, Inc 32 Addendum to Air Quality Modeling Report ATK Launch Systems • AutoLiv facility, an off-site commercial business located between the M-136 and M-225 treatment units. • Christensen residence, a residential dwelling located due north of ATK. • Blue Creek perennial stream, which runs along the western boundary of M-136. • The Bear River Migratory Bird Refuge, located about 10.5 km south-southwest of M-225. • The Salt Creek Waterfowl Management Area, located 13 km east of ATK. • The Thiokol Ranch Pond (ATK Ranch Pond), which is located approximately 14 km southwest of M-225. • The Howell Dairy Farm just north of the ATK northern property boundary. • The Town of Penrose, located approximately 7 miles southeast of M-136. • The Town of Thatcher, located approximately 7.5 miles due east of M-136. • Two on-site discrete receptors to assess potential risk to ATK workers that are not directly involved with the activities at the M-136 and M-225 treatment units. These on-site discrete receptors represent areas where most non-treatment-related employees spend their time on site. The on-site discrete receptors include the following: - North Plant Main Administration Building and Main Manufacturing Area - 2.5 miles north of M-136 and 6.7 miles north-northwest of M-225. - South Plant Main Administration Building and Main Manufacturing Area - 1.8 miles south of M-136 and 3.9 miles west-northwest of M-225. The discrete receptor grid is shown in Figure 10-3. CB&I Environmental and Infrastructure, Inc 33 Addendum to Air Quality Modeling Report ATK Launch Systems Figure 10-3: Discrete Receptor Grid Layout 10.2 Pollutant Phases The following phases were considered in estimating the ADFs at the on-site MEI, off-site MEI, and discrete receptors: • Gas phase one-hour and annual concentrations • Particle phase one-hour and annual concentrations CB&I Environmental and infrastructure, Inc. 34 Addendum to Air Quality Modeling Report ATK Launch Systems • Particle-bound phase one-hour and annual concentrations • Gas phase annual dry deposition • Particle phase annual dry deposition • Particle-bound phase annual dry deposition Note that ADFs are not estimated for wet deposition. This deposition mechanism is not applicable for this assessment, since treatment operations are not conducted during precipitation events. As input to the risk assessment, the ADFs for each pollutant phase were developed using AERMOD for the M-136 and M-225 scenarios described in Section 4.0 of this document. The ADFs are based on a unit emission rate of 1 g/s for each source within a scenario. The ADFs developed for each scenario will be multiplied by emission rates of specific pollutants in the risk assessment to be conducted by other consultants. Mercury speciation and exposure will be applied within the risk assessment model, which follows guidance for mercury evaluation found in the Human Health Risk Assessment Protocol (HHRAP) for Hazardous Waste Combustion Facilities (USEPA, September 2005). Within AERMOD, the gas phase dry deposition was modeled using a conservative deposition velocity of 0.03 meter per second (m/sec), which is the highest of the default values specified in the HHRAP guidance. This velocity is consistent with the value used in the preliminary modeling performed by Tetra Tech and presented in their modeling report dated July 2012. UDSHW accepted the velocity of 0.03 m/sec in Tetra Tech's modeling. Modeling of the particle and particle-bound phases in AERMOD required the input of particle size distribution data including: particle diameter, the mass distribution for particle phase emissions, the surface area distribution for particle-bound phase emissions, and particle density. The upper and lower bound diameter of each particle size category and the corresponding particle mass fractions were generated by OBODM considering the particle information used in previous modeling by Tetra Tech, which assumed a mass median particle diameter of 30 microns, a standard deviation of 2 microns, and 10 size categories. The mean particle size diameter for each category was calculated from the upper and lower bounds obtained from the OBODM particle data using Equation 3-1 in the HHRAP. For modeling of the particle-bound phase, the equations in Section 3.2.3 of the HHRAP were used to calculate the surface area- weighted distribution of the particle size categories. The particle size distribution data for modeling of particle and particle-bound phases in AERMOD are summarized in Table 10-1. CB&I Environmental and Infrastructure, Inc 35 Addendum to Air Quality Modeling Report ATK Launch Systems Table 10-1: Particle Distribution Data OBODM/Historical Modeling Calculated From HHRAP Guidance Particle Size Category Bounds Mass Fraction Mean Particle Diameter* (Mm) Particle Radius (Mm) Surface Area (Mm)2 Volume (Mm)3 Surface Area/ Volume (Mm)1 Proportion Available Surface Area Fraction of Total Surface Area8 Lower Upper FM R = D/2 S=4*pi*RA2 V=(4/3)*pi*RA3 SN F = (S/V)*FM F/sum(F) 344 2.50 0.02265 2.99 1.50 28.17 14.06 2.00361 4.54E-02 7.72E-02 4.73 3.44 0.05202 4.12 2.06 53.29 36.58 1.45678 7.58E-02 1.29E-01 6.50 4.73 0.09708 5.66 2.83 100.68 95.00 1.05986 1.03E-01 1.75E-01 8.94 6.50 0.14713 7.78 3.89 190.34 246.92 0.77084 1.13E-01 1.93E-01 12.30 8.94 0.18113 10.71 5.35 360.21 642.85 0.56034 1.01E-01 1.73E-01 16.92 12.30 0.18113 14.73 7.37 681.71 1,673.68 0.40731 7.38E-02 1.25E-01 23.27 16.92 0.14713 20.26 10.13 1,289.63 4,354.83 0.29614 4.36E-02 7.41 E-02 32.01 23.27 0.09708 27.87 13.93 2,439.91 11,332.75 0.21530 2.09E-02 3.56E-02 44.04 32.01 0.05202 38.34 19.17 4,617.89 29,508.00 0.15650 8.14E-03 1.38E-02 60.57 44.04 0.02265 52.74 26.37 8,737.29 76,796.06 0.11377 2.58E-03 4.38E-03 Notes: References: 2005 HHRAP Guidance (Section 3.2, Table 3-1). A Mean Particle Diameter (D); USEPA's HHRAP Guidance, September 2005, Equation 3-1: D = [0.25*(Di*3 + DiA2*D2 + Di*D2*2 + D2*3)]A(1/3) Where: Di - lower bound cut of particle size category (ym) D2 = upper bound cut of particle size category f/jm). 8 Surface area-based distribution for particle-bound phase modeling, as described in Section 3.2.3 of USEPA's HHRAP Guidance, September 2005. CB&I Environmental and Infrastructure, Inc. 36 Addendum to Air Quality Modeling Report ATK Launch Systems A particle density of 2.7 grams per cubic meter was applied for this assessment and was assumed to be constant over all particle size categories. This value corresponds to the density of aluminum, which was determined from historical testing to be the most abundant metal in the OB and OD emissions and was the particle density used in previous modeling of the ATK operations. 10.3 One-Hour ADF for Concentration The one-hour ADFs were determined individually for each of the sources representing the operating scenarios for M-136 and M-225 using unit emission rates for emission of gaseous and particulate pollutants. As described for the air quality assessment, the unit emission rates were input to AERMOD for each hour of unrestricted operation. For assessing acute risk, maximum concentrations out of the five years modeled were determined for each modeled scenario at the on-site MEI, off-site MEI, and at each of the discrete receptors, and these concentrations represent the one-hour ADF values. 10.4 Annual ADF for Concentration Annual values of concentration and deposition are used to assess chronic risk and are based on the five-year averages determined from modeling. For developing the annual ADFs, the models were programmed to yield one-hour concentration values at each receptor averaged over the five-year meteorological period. In the same manner as for the annual impacts for the air quality assessment, the annual ADFs were determined individually from the five-year average one-hour concentrations for each modeled scenario as follows: ADFannual 0 1-hr ^ daily 8760 Where: ADFannuai = Maximum annual average concentration in pg/m3 Qannuai = Annual quantity of reactive waste in OB/OD (lbs) Qdaiiy = Daily quantity of reactive waste in OB/OD (lbs) ADF i .hr = 5-year average 1 -hour concentration based on daily reactive waste quantity 8760 = Number of hours per year Note: The term [Qannual/Qdaiiy] represents the total number of days per year the OB/OD events can occur to reach the annual permitted quantities. CBSI Environmental and Infrastructure, Inc 37 Addendum to Air Quality Modeling Report ATK Launch Systems Annual ADFs for the off-site MEI and the on-site MEI were calculated from the highest five- year average one-hour concentration values for each scenario over the respective receptor sets. For the sensitive receptors, annual ADFs were calculated from the five-year average one-hour concentration values at each discrete receptor. 10.5 Annual ADF for Deposition The procedure for determining the annual ADFs for dry deposition was similar to the calculation of the annual ADFs for concentration. First, the five-year average one-hour values for dry deposition were determined and then the annual ADFs were calculated using the equation shown in Section 10.4 above. 10.6 Summary of ADFs The ADFs developed for use in the risk assessment were determined for the M-136 and M-225 scenarios as described above. All modeling files used in determining these ADFs for the risk assessment are included on the flash drive in Attachment 4. Tables of the ADFs for concentration and deposition are presented for the off-site MEI, on-site MEI, and discrete receptors on the flash drive in Attachment 5. Attachment 5 also includes contour plots of the annual particle dry deposition and annual vapor air concentration for the worst-case event for OB and OD at both burn grounds. Combined results for both the on-site and off-site receptors are presented. Scenario M-13 6-A is the worst-case OB scenario for this treatment location and consists of three sub-scenarios: M-136-A1, M-136-A2, and M-136-A3. Each sub-scenario was modeled separately for developing the ADFs, and individual results were obtained for each sub-scenario. Since Scenario M-136-A1 is the driver and contributes the greatest impact compared to M-136-A2 and M-136-A3, results from this sub-scenario have been plotted as representative of M-136-A. Furthermore, Scenario M-136-A1 was modeled considering simultaneous burns in six separate burn stations. Since individual results were obtained for each burn station, the results from one burn station have been plotted and are considered as representative. Similarly, the OD scenario for this treatment area, M-136-C, was modeled considering two separate stations. The results from one station have been plotted as representative of this scenario. CB&I Environmental and Infrastructure, Inc. 38 Addendum to Air Quality Modeling Report ATK Launch Systems 11.0 Conclusion To ensure the AERMOD results represent a significant refinement over the preliminary modeling conducted solely with OBODM and to allow for evaluation of more realistic operating conditions, the air quality modeling results consider that the OB and OD events occur for only one hour per day and must meet the following criteria: • The event will occur only between the hours 9:00 a.m. and 6:00 p.m. MST • The wind speed during the event will be between 3 and 15 mph • The Clearing Index during the events will be 500 or higher The results indicate that Scenarios M-136-A and M-225-A have the greatest impact. The cumulative impact of these two scenarios shows compliance with the NAAQS and Utah's acute and chronic toxic screening levels. Therefore, no additional modeling is required if the above restrictions are met when performing OB and OD events. CB&I Environmental and Infrastructure, Inc 39 Addendum to Air Quality Modeling Report ATK Launch Systems Attachment 1 Vapor Cloud Heights Table A-l OBODM Modeling for Plume Dimensions - M-136 Unit and M-225 Unit, ATK Promontory Open Burning Evaluation of Range of Stability Categories and Wind Speed Groups for Unrestricted Operating Hours Summary of Lowest Total Cloud Heights Wind Speed (mph) | (m/s) Scenario Lowest Total Cloud Height (m) Quantity of Reactive Waste per Burn Station Stability Stability (lb) Class A* Class B** Stability Class C 3-5 1.34 - 2.24 M136 Scenario A-l - OB 16,000 M136 Scenario A-2-OB 10,000 M136 Scenario A-3 - OB 16,000 M136 Scenario B- OB 125,000 M225 Scenario A-OB 1,125 1364.4 1116.4 372.4 1255.3 1116.4 372.4 1364.4 1116.4 372.4 1364.4 1116.4 534.2 335.6 335.6 372.4 5-7.5 2.24-3.35 M136 Scenario A-l-OB 16,000 M136 Scenario A-2 - OB 10,000 M136 Scenario A-3 - OB 16,000 M136 Scenario B-OB 125,000 M225 Scenario A-OB 1,125 1328 930.4 1003.8 836.2 1328 930.4 1364.4 930.4 267.9 222.7 744.4 744.4 744.4 744.4 241.6 7.5-10 3.35-4.47 M136 Scenario A-l - OB 16,000 M136 Scenario A-2 - OB 10,000 M136 Scenario A-3-OB 16,000 M136 Scenario B-OB 125,000 M225 Scenario A-OB 1,125 827.9 626.6 827.9 930.4 166.2 744.4 626.6 744.4 744.4 166.2 10-12.5 4.47-5.59 M136 Scenario A-l - OB 16,000 M136 Scenario A-2 - OB 10,000 M136 Scenario A-3 - OB 16,000 M136Scenario B-OB 125,000 M225 Scenario A - OB 1,125 827.9 626.6 827.9 1116.4 166.2 661.2 500.9 661.2 930.4 132.3 12.5-15 5.59 - 6.71 M136 Scenario A-l - OB 16,000 M136 Scenario A-2 - OB 10,000 M136 Scenario A-3 - OB 16,000 M136Scenario B-OB 125,000 M225 Scenario A-OB 1,125 550.1 417.1 550.1 930.4 109.7 550.1 417.1 550.1 930.4 109.7 * A Stability is only valid for winds < 6 knots (6.9 mph or 3.08 m/s) ** B Stability is not valid at winds > 9 knots (10.364 mph or 4.63 m/s) OBODM automatically adjusted the stability to C for these conditions. lof 5 Attachment Tabic A-2 OBODM Modeling for Plume Dimensions - M-136 Unit and M-225 Unit, ATK Promontory Open Burning Evaluation of Range of StabiBty Categories and Wind Speed Groups for Unrestricted Operating Hours (mph) Speed (m/s) Quantity of Reactive Waste per Bum Station (lb) Stability Category A* Total Cloud Ht(m) Stability Category B« Total Cloud Ht(m) Stability Category C Total Cloud Ht(m) Stability Category D Total Cloud Ht|m) 1.34 M136 Scenario A-l - OB 16,000 1364.4 1116.4 387.2 200 M136 Scenario A-2 - OB 10,000 1364.4 1116.4 372.4 196 M136 Scenario A-3 - OB 16,000 387.2 M136 Scenario B - OB 125,000 1116.4 549.3 M225 Scenario A - OB 1,125 561.6 M136 Scenario A-l -OB 16,000 1364.4 372.4 M136 Scenario A-2 -OB 1364.4 372.4 M136 Scenario A-3 -OB 1364.4 372.4 M136 Scenario B - OB 125,000 M225 Scenario A - OB 1,125 372.4 M136 Scenario A-l - OB 16,000 744.4 M136 Scenario A-2 - OB 10,000 M136 Scenario A-3 - OB 16,000 1116.4 744.4 M136 Scenario B - OB 744.4 M225 Scenario A - OB 1,125 M136 Scenario A-l - OB 16,000 M136 Scenario A-2 - OB 10,000 M136 Scenario A-3 - OB 16,000 M136 Scenario B - OB 125,000 M225 Scenario A - OB 1,125 31S.2 M136 Scenario A-l - OB 744.4 M136 Scenario A-2 - OB 744.4 M136 Scenario A-3 - OB 16,000 M136 Scenario B - OB 125,000 M225 Scenario A - OB 1,125 241.6 M136 Scenario A-l - OB 16,000 M136 Scenario A-2 - OB 10,000 M136 Scenario A-3 - OB 16,000 946.9 M136 Scenario B-OB 125,000 930.4 M225 Scenario A - OB 1,125 190.4 152.5 2of5 Attachment 1 Table A-2 OBODM Modeling for Plume Dimensions - M-136 Unit and M-22S Unit, ATK Promontory Open Burning Evaluation of Range of Stability Categories and Wind Speed Groups for Unrestricted Operating Hours Wind Impn) Speed (m/s) Scenario Quantity of Reactive Waste per Bum Station (lb) Stability Category A* Total Cloud Ht(m) Stability Category B*1 Total Cloud Ht(m) Stability Category C Total Cloud Ht(m) Stability Category D Total Cloud Ht(m) M136 Scenario A-l - OB 16,000 827.9 827.9 235.5 M136 Scenario A-2 -OB 10,000 626.6 626.6 216.4 M136 Scenario A-3-OB 827.9 M136 Scenario B - OB 125,000 930.4 295.7 M225 Scenario A - OB M136 Scenario A-l -OB 16,000 M136 Scenario A-2 -OB 10,000 M136 Scenario A-3 - OB 16,000 M136 Scenario B-OB 125,000 M225 Scenario A - OB 1,125 147.3 5.59 M136 Scenario A-l - OB 16,000 661.2 218.5 M136 Scenario A-2 -OB 10,000 500.9 197 M136 Scenario A-3 -OB 16,000 661.2 M136 Scenario B - OB 125,000 930.4 M225 Scenario A - OB 1,125 M136 Scenario A-l - OB M136 Scenario A-2 - OB 455.2 M136 Scenario A-3 - OB M136 Scenario B - OB 125,000 M225 Scenario A - OB 1,125 119.9 M136 Scenario A-l - OB 16,000 550.1 M136 Scenario A-2 - OB 10,000 M136 Scenario A-3 - OB 16,000 M136 Scenario B - OB 125,000 M22S Scenario A - OB 1,125 109.7 * A Stability Is only valid for winds < 6 knots (6.9 mph or 3.08 m/s) •* B Stability Is not valid at winds > 9 knots (10.364 mph or 4.63 m/i) OBODM automatically adjusted the stability to C for thesa conditions. 3of5 Attachment 1 Table A-3 OBODM Modeling for Plume Dimensions - M-136 Unit and M-225 Unit, ATK Promontory Open Detonation Evaluation of Range of Stability Categories and Wind Speed Groups for Unrestricted Operating Hours Summary of Lowest Total Cloud Heights Wind Speed (mph) (m/s) Scenario Lowest Total Cloud Height (m) Quantity of Reactive Waste per Burn Station Stability Stability (lb) Class A* Class B** Stability Class C 3-5 1.34-2.24 M136 Scenario A-l-OB 16,000 M136 Scenario A-2 - OB 10,000 M136 Scenario A-3-OB 16,000 M136Scenario B-OB 125,000 M136 Scenario C- OD 600 M225 Scenario A - OB 1,125 M225 Scenario B-OD 600 1364.4 1116.4 1255.3 1116.4 1364.4 1116.4 1364.4 1116.4 329.3 329.3 335.6 335.6 329.3 329.3 372.4 372.4 372.4 534.2 329.5 372.4 329.5 5-7.5 2.24-3.35 M136 Scenario A-l - OB 16,000 M136 Scenario A-2 - OB 10,000 M136 Scenario A-3 - OB 16,000 M136Scenario B-OB 125,000 M136 Scenario C- OD 600 M225 Scenario A -OB 1,125 M225 Scenario B - OD 600 1328 930.4 1003.8 836.2 1328 930.4 1364.4 930.4 311.1 297 267.9 222.7 311.1 297 744.4 744.4 744.4 744.4 297.1 241.6 297.1 7.5-10 3.35-4.47 M136 Scenario A-l-OB 16,000 M136 Scenario A-2 - OB 10,000 M136 Scenario A-3 -OB 16,000 M136Scenario B-OB 125,000 M136 Scenario C-OD 600 M225 Scenario A-OB 1,125 M225 Scenario B - OD 600 827.9 626.6 827.9 930.4 276 166.2 276 744.4 626.6 744.4 744.4 276 166.2 276 10-12.5 4.47-5.59 M136 Scenario A-l-OB 16,000 M136 Scenario A-2 - OB 10,000 M136 Scenario A-3 - OB 16,000 M136 Scenario B- OB 125,000 M136Scenario C-OD 600 M225 Scenario A-OB 1,125 M225 Scenario B - OD 600 827.9 626.6 827.9 1116.4 276 166.2 276 661.2 500.9 661.2 930.4 260.8 132.3 260.8 12.5-15 5.59 - 6.71 M136 Scenario A-l - OB 16,000 M136 Scenario A-2 - OB 10,000 M136 Scenario A-3 - OB 16,000 M136 Scenario B - OB 125,000 M136 Scenario C-OD 600 M225 Scenario A-OB 1,125 M225 Scenario B - OD 600 550.1 550.1 417.1 417.1 550.1 550.1 930.4 930.4 248.9 248.9 109.7 109.7 248.9 248.9 * A Stability is only valid for winds < 6 knots (6.9 mph or 3.08 m/s) ** B Stability is not valid at winds > 9 knots (10.364 mph or 4.63 m/s) OBODM automatically adjusted the stability to C for these conditions. 4 of 5 Attachment Table A-4 OBODM Modeling for Plume Dimensions - M-136 Unit end M-225 Unit, ATK Promontory Open Detonation Evaluation of Range of Stability Categories and Wind Speed Groups for Unrestricted Operating Hours (mph) Speed (m/i) quantity of Reactive Waste per Bum Station (lb) Stability Category A* Total Cloud Ht(m) Stability Category Total Cloud Ht(m) Stability Category C Total Cloud Ht(m) Stability Category D Total Cloud Ht|m) 1.34 M136 Scenario C-OD 600 374.9 374.9 375.1 155.3 M225 Scenario B - OD 600 374.9 374.9 375.1 155.3 M136 Scenario C-OD M225 Scenario B-OD 2.24 M136 Scenario C - OD 600 329.3 M225 Scenario B - OD 329.S 2.79 M136 Scenario C-OD 179.8 M225 Scenario B - OD 3.35 M136 Scenario C-OD M225 Scenario B - OD 3.91 M136 Scenario C-OD M225 Scenario B - OD M136 Scenario C-OD 276 276 M225 Scenario B - OD 600 5.03 M136 Scenario C-OD 600 M225 Scenario B - OD 267.9 5.59 M136 Scenario C-OD 260.8 M225 Scenario B - OD 6.15 M136 Scenario C-OD M225 Scenario B - OD 6.71 M136 Scenario C-OD M225 Scenario B - OD * A Stability is onty valid for winds < 6 knots (6.9 mph or 3.08 m/s) B Stability Is not valid at winds > 9 knots (10.364 mph or 4.63 m/s) 5 of 5 Attachment 1 Attachment 2 Summary of Screened Hours ATK Promontory OBOD Modeling Meteorological Data Analysis Restrictions Daytime Operations: Beginning Operating Hour: Last Operating Hour: Clearing Index >= 10 (9 AM) 18 (6 PM) 500 Wind Speed Group M/s MPH Group 0 1.34<=WS<2.24 3-5 Group 1 2.23<=WS<3.35 5-7.5 Group 2 3.35<=WS<4.47 7.5-10 Group 3 4.47<=WS<5.59 10-12.5 Group 4 5.59<=WS<6.71 12.5-15 Unrestricted Hours: Meteorological Year Atmospheric Stability 1.34<=WS<2.24 2.23<=WS<3.35 Wind Speed Groups 3.35<=WS<4.47 4.47<=WS<5.59 5.59<=WS<6.71 1997 Total 33 99 32 120 14 71 233 12 94 55 161 70 121 193 1998 Total 31 86 19 121 13 56 220 24 103 29 156 81 119 200 1999 Total 33 101 42 134 18 86 253 29 133 40 202 69 137 206 2000 Total 34 115 18 102 18 60 235 32 158 57 247 102 168 272 2001 Total 37 142 17 132 24 62 298 20 182 56 258 106 163 270 Grand Total 1 Attachment 2 Attachment 3 Detailed Modeling Results See Attached Flash Drive Attachment 4 Modeling Inputs/Outputs See Attached Flash Drive Attachment 5 Summary of ADFs for the Risk Assessment A1_4: Annual Cone - G, P, PB: Annual Dep • 3 z Cone - G, P, PB; Annual Dep A2, C13: Annual Dep - P, PB A1_10, A1_4, A1_7, A1_8: Annual Dep - P, PB / 11: Annual Dep A1_1, A3, C14: Annual A1 11: Annual Dep-P Dep PB PB A2: 1-hr Cone-G, P, PB A1_10: Annual Cone - G, P, PB: Annual Dep - G A2, B: Annual Cone -G, P, PB; Annual Dep - G HH A3 1-hr Cone- G p. PB A3: Annual Cone - G, P, PB; Annual Dep B: 1-hr Cone - G P, PB A1 7: 1-hr Cone-G. P, PB I ,3 k: A1_1: 1-hr & Annual Cone - G, P, PB; Annual Dep- A1_4:1-hrConc-G, P, PB A1_4, A1_7, A1_8: Annual Cone: G, P, PB; Annual Dep - G A1_10, A1_11: Annual Cone - G, P, PB; Annual Dep - G, P, PB A2: Annual Dep - P C13: Annual Dep - P, PB C13: 1-hr & Annual Cone - G, P, PB; Annual Dep - G A1_11: Annual Cone - G. P, PB; Annual Dep - G C14: 1-hr Cone - G P, PB A1_7, A1_8: Annual Cone - G, P, PB; Annual Dep - G C13: 1-hr & Annual Cone - G, P, PB; Annual Dep - G : 1-hr Cone - G, P, PB C14: Annual Cone - G, P, PB; Annual Dep - G • A1_10, A1_11: 1-hr Cone- G, P, PB • A1_4, A1_7, A1_8: 1 hr Cone - G, P, PB • A1_1: 1-hr Cone - G, P, PB C14: 1-hr Cone - G, P, PB A2, C14: Annual Cone - G, P, PB; Annual Dep - G A3: Annual Cone - G, P, PB; Annual Dep - G 11: 1-hrConc-G, P, PB 1-hr Cone -G, P, PB A1 A1 A2 \ A1_8: 1-hrConc-G P, PB B: Annual Conc-G, P, PB; Annual Dep-G 2: Annual Dep - PB • 1 • * / B: Annual Dep - P, PB A1_4, A1_7, A1_8, A3, C14: Annual Dep - P, PB A3: 1-hrCone-G, P, PB A1_1: Annual Dep -PB • LEGEND: G P PB GAS PARTICLE PARTICLE BOND , Vji. ''.I j 2790 Mosside Boulevard Monroevilte, PA 15146-2792 ATK LAUNCH SYSTEMS, INC. PROMONTORY. UTAH FIGURE A5-1 MAXIMUM ANNUAL AND 1-HOUR CONCENTRATION AND ANNUAL DEPOSITION FOR ONSITE AND OFFSITE RECEPTORS FROM M-136 SOURCES • B 1-hr Cone G, P, PB - Offsite # B: Annual Cone - G; Annual Dep-G B:Annual Cone - G. P. PB: Annual Dep - G B Annual Dep - P, PB id.... A1-hr & Annual Cone - PB B:1-hr Cone - G, Part. PB :1-hrConc-G; P, PB nnual Dep-Part, PB A:Annual Cone - G, P, PB; Annual Dep - G AAnnual Dep - P, PB • B:Annual Conc-P.PB LEGEND m G GAS P PARTICLE PB PARTICLE BOND SCALE 2000 FEET 2790 Mosside Boulevard Monroeville. PA 15146-2792 a> A:1-hr & Annual Cone - G, P; Annual Dep - G, P, PB ATK LAUNCH SYSTEMS, INC PROMONTORY. UTAH FIGURE A5-2 MAXIMUM ANNUAL AND 1-HOUR CONCENTRATION AND ANNUAL DEPOSITION FOR ONSITE AND OFFSITE RECEPTORS FROM M-225 SOURCES Cont ours 0 0002? 0.0005 lj 0007J <vM»t 0.002 0.003 O.OO* 3.1 36 \ NOTE: CONCENTRATION IN (ug/m V(9/s) 2790 Mosside Boulevard Monroeville, PA 15146-2792 ATK LAUNCH SYSTEMS, INC. PROMONTORY, UTAH FIGURE A5-3a ANNUAL 5-YEAR AVERAGE CONCENTRATION FOR OB AT M-136, SCENARIO A1 Contours a.ootvi 0.OOO2S z S i ui fi is s s Ci 001 o z 0.0012 3.0014 100 M-136'- 3? NOTE: DEPOSITION IN (ug/m Vfg/s) 2790 Mosside Boulevard Monroeville, PA 15146-2792 ATK LAUNCH SYSTEMS, INC. PROMONTORY, UTAH FIGURE A5-3b ANNUAL 5-YEAR AVERAGE PARTICLE DRY DEPOSITION FOR OB AT M-136, SCENARIO A1 Contours 0.0005 0.001 B 0025 0 004 0.005 0.006 0 007 If M VA BP* la 4 NOTE: CONCENTRATION IN (ug/m Vte's) SCALE 16000 FEET 2790 Mosside Boulevard Monroeville, PA 15146-2792 ATK LAUNCH SYSTEMS, INC. PROMONTORY. UTAH FIGURE A5-4a ANNUAL 5-YEAR AVERAGE CONCENTRATION FOR OD AT M-136, SCENARIO C "rr g UJ p a j contours 0.00025 0.0005 i oo i '. 00; f 0.002 0.0025 n nn?s M-13© D NOTE: DEPOSITION IN (ug/m ^/(g/s) SCALE 16000 FEET ,4,v;V'".V ,i 2790 Mosside Boulevard Monroeville, PA 15146-2792 ATK LAUNCH SYSTEMS, INC, PROMONTORY, UTAH FIGURE A5-4b ANNUAL 5-YEAR AVERAGE PARTICLE DRY DEPOSITION FOR OD AT M-136, SCENARIO C Contours uriCI [II 2 0.00025 1.1 BOOB (1 1X1876 0.001 0.0015 0 rv fc V .MA225 ^ypv .Jail MOTE CONCENTRATION IN (ug/mV(g/ • If V SCALE 8000 16000 FEET 2790 Mosside Boulevard vlonroeville. PA 15146-2792 ATK LAUNCH SYSTEMS. INC PROMONTORY. UTAH FIGURE A5-5a ANNUAL 5-YEAR AVERAGE CONCENTRATION FOR OB AT M-225 SCENARIO A 5m Q I 5 1 Contours 0.00003 0.00005 0 13001 0.0002 0.0004 0.0006 0.0003 W£25 NOTE DEPOSITION IN (ug/rri )/(g/s) SCALE 3000 16000 FEET 2790 Mosside Boulevard Monroeville. PA 15146-2792 ATK LAUNCH SYSTEMS, INC. PROMONTORY, UTAH FIGURE A5-5D ANNUAL 5-YEAR AVERAGE PARTICLE DRY DEPOSITION FOR OB AT M-225, SCENARIO A »«»< 0.0001 0.00025 o ooes 0 .11107- 0.001 0.001 25 in; \ NOTE: CONCENTRATION IN (ug/m V(g's) SCALE 2790 Mosside Boulevard Monroeville, PA 15146-2792 ATK LAUNCH SYSTEMS, INC. PROMONTORY, UTAH FIGURE A5-6a ANNUAL 5-YEAR AVERAGE CONCENTRATION FOR OD AT M-225. SCENARIO B O.OOODS 0.0001 0.0002 D.oooe 0.0004 0.0005 0.00055 s s /M-225 • t . I. •1 6 s NOTE: DEPOSITION IN (ug/m2)/(g/s) SCALE 300C 5000 FEET ---2790 Mosside Boulevard Monroeville, PA 15146-2792 ATK LAUNCH SYSTEMS, INC PROMONTORY. UTAH FIGURE A5-6b ANNUAL 5-YEAR AVERAGE PARTICLE DRY DEPOSITION FOR OD AT M-225, SCENARIO B See Attached Flasb Drive There is a Non-uploadable CD / Portable Drive / Other Device associated with this document. Please see the facility file for the CD / Portable Drive / Other Device.