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HomeMy WebLinkAboutDSHW-2013-003920 - 0901a0688038da50Division of Solid and Hazardous Waste JUN 1 h 20)3 2013-003^20 June 14,2013 8200-FY14-027 Mr. Scott T. Anderson, Executive Secretary State of Utah Department of Environmental Quality Division of Solid and Hazardous Waste 195 N.1950 W. P.O. Box 144880 Salt Lake City, Utah 84114-4880 Re: ATK Launch Systems-Promontory EPA ID number UTD009081357 Addendum Air Dispersion Modeling Report for Open Burning and Open Detonation at ATK Launch Systems in Promontory, Utah Dear Mr. Anderson: Enclosed is the Addendum Air Dispersion Modeling Report for Open Burning and Open Detonation (OB/OD) at ATK Launch Systems Inc. ("ATK") in Promontory, Utah. The information from this modeling report is necessary to conduct the Human Health and Ecological Risk Assessments for ATK's OB/OD operations. Please contact me if you have any questions concerning this report. My telephone number is (435)863-2018 or you can contact Blair Palmer at (435)863-2430. Sincerely George E. Gooch, Manager Environmental Compliance cc: JeffVandel ADDENDUM Division of Solid and Hazardous Waste JUN 1 4 2013 2O13-0D3J2D AIR DISPERSION MODELING REPORT FOR OPEN BURNING AND OPEN DETONATION AT ATK LAUNCH SYSTEMS IN PROMONTORY, UTAH Prepared for: Utah Department of Environmental Quality Division of Solid and Hazardous Waste Prepared by: ft Shaw Envkonmental, Inc. A CB&I Company 2790 Mosside Blvd Monroeville, PA 15146 Project No. 146690 June 2013 Table of Contents List of Tables iv List of Attachments iv List of Acronyms & Abbreviations v 1.0 Introduction 1 2.0 Description of Emission Source 3 2.1 Open Burn 3 2.2 Open Detonation 3 3.0 Emission Rates of Regulated Air Pollutants and Air Toxics 4 3.1 NAAQS Analysis 4 3.2 Air Toxics Analysis 5 4.0 Emission Source Parameters 9 4.1 Emission Rate 9 4.1.1 M-136 Stations 9 4.1.2 M-225 Stations 10 4.2 Release Height of Vapor Cloud 10 4.2.1 Open Burning 10 4.2.2 Open Detonation 11 4.3 Initial Dimensions of Vapor Cloud 11 4.3.1 Open Burning 11 4.3.2 Open Detonation 11 4.4 Other Source Parameters 12 4.4.1 M-136 Stations 12 4.4.2 M-225 Stations 12 4.5 Summary of AERMOD Modeling Parameters 12 4.5.1 M-136 Stations 13 4.5.2 M-225 Stations 15 5.0 Model Defaults and Assumptions 17 6.0 Meteorological Data 18 7.0 Receptor Grid Layout 19 8.0 Modeled Output 20 8.1 Maximum One-Hour Impact 20 8.2 Maximum Three-Hour and 24-Hour Impacts 20 8.3 Maximum Annual Impact 20 9.0 Compliance Demonstration with NAAQS and Air Toxic Standards 22 9.1 NAAQS Analysis 22 9.2 Air Toxics Analysis 23 Shaw Environmental, Inc. jj Addendum to Air Quality Modeling Report " i ATK Launch Systems 10.0 Development of Air Dispersion Factors for Risk Assessment 26 10.1 Receptor Locations 26 10.2 Pollutant Phases 27 10.3 One-Hour ADF for Concentration 30 10.4 Annual ADF for Concentration 30 10.5 Annual ADF for Deposition 31 10.6 Summary of ADFs 31 11.0 Conclusion 32 Attachments Shaw Environmental, Inc iii Addendum to Air Quality Modeling Report ATK Launch Systems List of Tables Table 3-1 Criteria Pollutants Considered in NAAQS Compliance Demonstration Table 3-2 Maximum Emission Rates including Background Concentrations - Criteria Pollutants Table 3-3 Acute and Chronic Air Toxic Screening Levels Table 3-4 Maximum Emission Rates including Background Concentrations - Air Toxics Table 4-1 M-136 Source Parameters Table 4-2 M-136 Actual Emission Rates for Criteria Pollutants Table 4-3 M-136 Actual Emission Rates for Air Toxics Table 4-4 M-225 Source Parameters Table 4-5 M-225 Actual Emission Rates for Criteria Pollutants Table 4-6 M-225 Actual Emission Rates for Air Toxics Table 9-1 Results of Cumulative Impact for M-136 and M-225 - Criteria Pollutants Table 9-2 Results of Cumulative Impact for M-136 and M-225 - Acute One-Hour Air Toxics Table 9-3 Results of Cumulative Impact for M-136 and M-225 - Chronic 24-Hour Air Toxics Table 10-1 Particle Distribution Data List of Attachments Attachment 1 Example for the Cloud Height Calculation Attachment 2 Summary of Screened Hours Attachment 3 Detailed Modeling Results Attachment 4 Modeling Inputs/Outputs Attachment 5 Summary of ADFs for the Risk Assessment Shaw Environmental, Inc. iv Addendum to Air Quality Modeling Report ATK Launch Systems List of Acronyms & Abbreviations u.g/m3 micrograms per cubic meter ADFs air dispersion factors AERMOD American Meteorological Society/USEPA Regulatory Modeling System ATK ATK Launch Systems MST Mountain Standard Time g/s grams per second HHRAP Human Health Risk Assessment Protocol km kilometers lbs pounds m meter m2 square meter MEI maximum exposed individual min minute mph miles per hour NAAQS National Ambient Air Quality Standards NO2 nitrogen dioxide OB open burning OBODM Open Burn/Open Detonation Model OD open detonation PG Pasquill-Gifford PM particulate matter ppb parts per billion sec second SO2 sulfur dioxide TSLs toxic screening levels UDSHW Utah Department of Environmental Quality, Division of Solid and Hazardous Waste USEPA U.S. Environmental Protection Agency Shaw Environmental, Inc V Addendum to Air Quality Modeling Report ATK Launch Systems 1.0 Introduction ATK Launch Systems (ATK), located 30 miles west of Brigham City, Utah, currently operates open burning (OB) and open detonation (OD) units for the treatment of hazardous waste propellants and propellant-contaminated materials. These treatment units are M-136 and M-225 and are subject to Resource Conservation and Recovery Act, 40 CFR 264, Subpart X permitting requirements for miscellaneous treatment units. The Utah Department of Environmental Quality, Division of Solid and Hazardous Waste (UDSHW) required ATK to conduct human health and ecological risk assessments in support of a new Subpart X permit application. Before the human health and ecological risk assessments can be conducted, an air dispersion modeling analysis must be performed to evaluate the air quality impact of the M-136 and M-225 treatment units. The results of the air dispersion modeling analysis will be entered into human health and ecological risk assessment models to determine the risk from the ATK OB/OD treatment units. ATK submitted a preliminary air dispersion modeling draft report for the OB/OD treatment units in March 2012. UDSHW made several comments on this report in a letter dated May 29, 2012. The preliminary modeling was conducted using the Open Burn/Open Detonation Model (OBODM) per approved protocol. OBODM is specifically designed to predict the air quality impact of OB and OD treatment of obsolete weapons, solid rocket propellants, and associated manufacturing wastes. The OB and OD treatment of waste propellants and propellant- contaminated materials can be classified as instantaneous events for OD treatment and as quasi- continuous events for OB treatment. The model is also designed to use either empirical emission factors such as those derived in the Dugway Proving Ground Bang Box™ or emissions predicted by a products of combustion model. OBODM calculates peak air concentration, time-weighted air concentrations, and dosage (time-integrated concentration) for OB and OD releases. It can also consider the effects on concentration and dosage of the gravitational settling and deposition of particulates. However, OBODM has several limitations which constrain the modeling in this application. For example, OBODM can handle only 100 receptors at a time, cannot predict deposition in complex terrain, and uses older algorithms for downwind dispersion of emitted pollutants. To overcome these limitations, ATK proposed a hybrid approach for the air modeling using the OBODM with the American Meteorological Society/U.S. Environmental Protection Agency (USEPA) Regulatory Modeling System (AERMOD) model, which is the USEPA's preferred dispersion model for short range transport (up to 50 kilometers [km]). OBODM has two distinct Shaw Environmental, Inc. 1 Addendum to Air Quality Modeling Report ATK Launch Systems parts. The first part simulates the OB and OD events and generates initial parameters of the emission cloud (emission rate, cloud height, cloud diameter), and the second part is the downwind dispersion of the emission cloud. The main limitation of OBODM is in the second part (i.e., dispersion). The downwind dispersion is better handled by AERMOD which has practically no limitation on number of receptors, can easily handle complex terrain, and handles dispersion of emission clouds based on state-of-the-art understanding of atmospheric turbulence. Thus, the revised air quality assessment was conducted using this hybrid approach based on the emission rates and initial source parameters from OBODM and using these parameters in AERMOD to predict downwind dispersion and deposition. This report describes the details of this hybrid modeling approach. Shaw Environmental, Inc. 2 Addendum to Air Quality Modeling Repoit ATK Launch Systems 2.0 Description of Emission Source The two activities in the facility are OB and OD. OB treatment is considered a quasi-continuous source because the treatment event is usually complete within one hour. OD is considered an instantaneous source because treatment is completed within milliseconds. The approach to modeling these two types of events was as follows. 2.1 Open Bum OB results in combustion of the energetics and rapid rise of the hot combustion products due to buoyancy until a final height is reached. At this point, the emission cloud has no upward momentum and starts to disperse downwind. This event was simulated as an elevated volume source with the stack height equal to the final cloud height predicted from OBODM. Details of source parameters are described in Section 4.0. 2.2 Open Detonation OD results in instantaneous combustion and immediate rise of the emission cloud to a final height. The cloud height is based on the reactive waste weight, wind speed, and atmospheric stability. Once elevated, this cloud disperses downwind. This event was simulated as an elevated volume source. Details of source parameters are described in Section 4.0. Shaw Environmental, Inc. 3 Addendum to Air Quality Modeling Report ATK Launch Systems 3.0 Emission Rates of Regulated Air Pollutants and Air Toxics The objective of the air quality analysis was to determine compliance with all applicable National Ambient Air Quality Standards (NAAQS) and air toxics. The NAAQS and air toxics modeling pollutants and corresponding emission rates are described below. 3.1 NAAQS Analysis The criteria pollutants considered for NAAQS analysis, the averaging time, and design values are shown in Table 3-1. Table 3-1: Criteria Pollutants Considered in NAAQS Compliance Demonstration Criteria Pollutant NAAQS averaging time Design Concentration Method of Determination of Design Value PM-10 24-Hour 150 ug/m3 Sixth highest of 5 years of meteorological data PM-2.5 24-Hour 35 (jg/m3 Average of first highest of 5 years of meteorological data PM-2.5 Annual 12 ug/m3 Average of first highest of 5 years of meteorological data S02 1-Hour 75 ppb (195 ug/m3) Five-year average of the 99th percentile (4th highest) of the annual distribution of daily maximum 1-hour average concentrations SO2 3-Hour 1,300 ug/m3 Five-year average of 2nd highest (not to be exceeded once per year) NO2 1-Hour 100 ppb (189 ug/m3) Five-year average of the 98th percentile (8th highest) of the annual distribution of daily maximum 1-hour average concentrations NO2 Annual 100 ug/m3 Maximum over 5 years of meteorological data Notes: Carbon monoxide and lead NAAQS were not included because previous modeling showed compliance with NAAQS. PM = Particulate matter. NO2 = Nitrogen dioxide. SO2 - Sulfur dioxide, ppb = Parts per billion. ji/g/m3 = Micrograms per cubic meter. Although each pollutant and averaging period has its own method to determine the design value, for this analysis, each maximum one-hour impact was averaged over the five-year period to obtain an average maximum one-hour impact for NAAQS analysis for all pollutants except PM-10 and annual NO2. This methodology is conservative for NAAQS. For PM-10 and annual NO2, the maximum impact over the five-year period of one-hour and annual average concentrations were considered, respectively. The NAAQS modeling used emission rates from the preliminary modeling. The emission factors are maximum values and include background concentrations expressed in pound of pollutant per Shaw Environmental, Inc. 4 Addendum to Air Quality Modeling Report ATK Launch Systems pound of reactive waste referenced from Table 2-5 of the 2012 TetraTech Modeling Report. The emission rates for NAAQS are shown Table 3-2. Table 3-2: Maximum Emission Rates including Background Concentrations - Criteria Pollutants Pollutant PM-10 PM-2.5 S02 NO2 Maximum Emission Rate (lb/lb reactive waste) 0.12 0.06 0.0005 0.0064 Reference: 2012 TetraTech Modeling Report, Table 2-5. 3.2 Air Toxics Analysis Air toxics included in the preliminary modeling dated March 2012 were compared to respective Utah toxic screening levels (TSLs). The acute toxics and corresponding TSLs considered are listed in Table 3-18 of the March 2012 modeling report. The maximum one-hour concentrations were averaged over the five-year period and compared to the acute TSLs. The chronic air toxics and corresponding TSLs are listed in Tables 3-35 and 3-52 of the preliminary modeling report dated March 2012. The maximum 24-hour concentrations were averaged over the five-year period and compared with the chronic TSLs. The acute one-hour and chronic 24-hour TSLs are shown in Table 3-3. Table 3-3: Acute and Chronic Air Toxic Screening Levels Type of Air Toxic Pollutant Utah TSL Value (ug/m3) Acute (1-Hour) Air Toxic Isophorone Formaldehyde Hydrogen Chloride Hydrogen Cyanide 1,2,4,-Trichlororbenzene 2,826 37 298 520 3,71" Chronic (24-Hour) Air Toxic 1,4-Dichlorobenzene 2,4-Dinitrotoluene o-Toluidine Phenol CI2 1,1,2-Trichloroethane 1,3-Butadiene 2,004 292 642 48 1,819 49 Shaw Environmental, Inc. 5 Addendum to Air Quality Modeling Report ATK Launch Systems Type of Air Toxic Pollutant Utah TSL Value (ug/m3) 1,4-Dioxane Acrylonitrile Benzene Bromoform Carbon Tetrachloride Chlorobenzene Chloroform cis-1,3-Dichioropropene Cumene Styrene Toluene Vinyl Chloride Antimony Arsenic Cadmium Chromium Cobalt Manganese Mercury Nickel Phosphorus Selenium 2,402 48 53 172 350 1,535 1,628 151 8,193 2,840 2,512 28 17 0.33 0.02 0.11 0.77 6.7 0.33 1.1' 3.3 3.7 The air toxics modeling used emission factors from the preliminary modeling. The emission factors are the maximum emission rate which includes background concentrations expressed in pound of pollutant per pound reactive waste. The emission rates for all air toxics are shown Table 3-4. Table 3-4: Maximum Emission Rates including Background Concentrations - Air Toxics Type of Air Toxic Pollutant Maximum Emission Rate ''B (lb/lb reactive waste) '••:>• Acute (1-Hour) Air Toxics Isophorone 5.50E-07 Formaldehyde 4.70E-05 Shaw Environmental, Inc. 6 Addendum to Air Quality Modeling Report ATK Launch Systems Type of Air Toxic Pollutant Maximum Emission Rate (lb/lb reactive waste) Hydrogen Chloride Hydrogen Cyanide 1,2,4,-Trichlororbenzene 1.80E-02 2.20E-05 1.30E-06 Chronic (24-Hour) Air Toxics 1,4-Dichlorobenzene 2,4-Dinitrotoluene o-Toluidine Phenol Cb 1,1,2-Trichloroethane 1,3-Butadiene 1,4-Dioxane Acrylonitrile Benzene Bromoform Carbon Tetrachloride Chlorobenzene Chloroform cis-1,3-Dichloropropene Cumene Styrene Toluene Vinyl Chloride Antimony Arsenic Cadmium Chromium Cobalt Manganese Mercury Nickel Phosphorus Selenium 7.30E-07 5.50E-07 7.00E-06 2.40E-06 1.20E-02 7.30E-07 2.40E-05 6.40E-07 1.60E-05 4.70E-05 1.30E-06 1.50E-05 2.50E-06 6.10E-06 1.30E-06 4.20E-07 9.90E-07 1.90E-05 7.60E-06 2.90E-05 5.50E-07 6.10E-07 2.00E-05 6.10E-07 9.40E-05 7.40E-08 5.80E-05 1.10E-04 1.60E-06 Reference: 2012 TetraTech Modeling Report, Table 2-5. Shaw Environmental, Inc 7 Addendum to Air Quality Modeling Report ATK Launch Systems To determine the emission rates used in AERMOD (in grams per second [g/s]), the maximum emission factors were multiplied by the reactive waste weight for each scenario described in Section 4.0. The emission rates used in AERMOD for each scenario are shown in Section 4.0. Shaw Environmental, Inc. 8 Addendum to Air Quality Modeling Report ATK Launch Systems 4.0 Emission Source Parameters Both the OB and OD events were modeled as elevated volume sources. The source parameters required for dispersion of volume sources are: • Emission rate • Release height of vapor cloud • Initial horizontal and vertical dimensions of the vapor cloud The methodology for determination of these source parameters was based on several discussions with UDSHW as described in this section. 4.1 Emission Rate Emission rates were estimated based on quantity of reactive waste in OB/OD events and the emission factors used in previous modeling referenced from Table 2-5 of the March 2012 modeling report. Modeling to assess ambient air quality impacts was conducted using the estimated actual emission rates for each scenario. To reduce the number of required model runs, the emission rates for a single pollutant (i.e., PM-2.5) were input to the model. The single pollutant modeling results were then applied to the other pollutants that are part of the impact analysis by scaling the modeled results by the ratio of the desired pollutant emission rate to the modeled emission rate. However, modeling in support of the risk assessment was conducted at a unit emission rate of 1 g/s to allow for application of pollutant-specific emission rates within the risk assessment software. The reactive waste quantities for each of the scenarios were based on the desired permit limits which are listed below. 4.1.1 M-136 Stations M-136 has 14 burn stations (1 through 14) and any one of the following alternative and mutually exclusive scenarios could occur in these stations: Scenario M-136-A • AI: OB in six of Burn Stations 1 through 12 at 16,000 pounds (lbs) in each station totaling to 96,000 lbs reactive waste weight per event • A2: 10,000 lbs reactive waste weight per event in Burn Station 13 • A3: 16,000 lbs reactive waste weight per event in Burn Station 14 I Shaw Environmental, Inc 9 Addendum to Air Quality Modeling Report ATK Launch Systems Scenario M-136-B • B: OB of 125,000 lbs of large rocket motors in Station 14 Scenario M-136-C • C: OD of 600 lbs reactive waste in Stations 13 and 14 each, totaling 1,200 lbs reactive waste weight per event 4.1.2 M-225 Stations M-225 has four burn stations (1 through 4) and any one of the following alternative and mutually exclusive scenarios could occur in these stations: Scenario M-225-A • A: OB of 1,125 lbs of reactive waste in each of the Burn Stations 1 through 4 for a total of 4,500 lbs reactive waste weight per event Scenario M-225-B • B: OD of 600 lbs of reactive waste in Station 1 4.2 Release Height of Vapor Cloud 4.2.1 Open Burning OB results in combustion of the energetics and rapid rise of the hot combustion products due to buoyancy until a final height is reached. At this point, the emission cloud has no upward momentum and starts to disperse downwind. This event was simulated as an elevated volume source with the release height equal to the final cloud height predicted from OBODM. Based on several discussions with UDSHW and its consultant, the following approach was used for determination of cloud heights for OB events. All of the unrestricted hours (i.e., the hours that meet the operating restriction described in Section 5.0 were grouped based on wind speed and stability condition. The wind speeds were grouped in four ranges as identified below: • Category 0: 3.0 miles per hour (mph) - 5.0 mph • Category 1: 5.0 mph - 7.5 mph • Category 2: 7.5 mph - 10.0 mph • Category 3: 10.0 mph - 12.5 mph • Category 4: 12.5 mph - 15 mph Atmospheric stabilities were grouped in six Pasquill-Gifford (PG) atmospheric stability classes for each of the hours in each of the wind speed categories listed above. Shaw Environmental, Inc 10 Addendum to Air Quality Modeling Report ATK Launch Systems The OBODM was used to determine the vapor cloud height for each combination of the PG atmospheric stability class and wind speed categories. The vapor cloud heights were determined for the lower threshold, the higher threshold, and midpoint for each wind speed category. To ensure a conservative impact assessment, the minimum cloud height out of these three wind speeds were considered for each combination of atmospheric stability and wind speed category. Attachment 1 shows an example for the cloud height calculation. The procedure outlined here for determining the vapor cloud heights specific to meteorological conditions was conducted for each of the scenarios proposed for representing the OB/OD events. In the case of scenarios that consider simultaneous events at multiple burn stations, only one representative burn station was modeled in OBODM for each scenario. The resulting vapor cloud height was then applied to each of the other identical burn stations for that scenario. 4.2.2 Open Detonation The same procedure described for OB was used for determination of vapor cloud height for OD using the OBODM. 4.3 Initial Dimensions of Vapor Cloud 4.3.1 Open Burning During rapid rise of the cloud from the OB, atmospheric air is entrained and the dimension of the cloud increases. Based on videos of the open burning events, the final dimensions of the cloud at final plume height are typically four to eight times larger than the dimension of the burn pans. As a conservative estimate, the cloud diameter was based on four times the equivalent diameter of the burn pans. Because the burn stations have multiple adjacent burn pans, the equivalent diameter was based on the total area covered by the reactive waste. It is assumed that the vapor cloud plume is a sphere. Per AERMOD guidance, the initial vertical and horizontal dimensions of an elevated volume source, such as the vapor cloud, were calculated by dividing the initial cloud diameter (i.e., four times equivalent diameter covered by reactive waste on burn pans) by a factor of 4.3. 4.3.2 Open Detonation The initial dimension of the vapor cloud was obtained directly from the OBODM for each combination of wind speed category and atmospheric stability. Per AERMOD guidance, the initial vertical and horizontal dimensions of an elevated volume source such as the vapor cloud were calculated by dividing the initial vapor cloud diameter by a factor of 4.3. Shaw Environmental, Inc. 11 Addendum to Air Quality Modeling Report ATK Launch Systems 4.4 Other Source Parameters 4.4.1 M-136 Stations Burn Stations 1 through 12 are clustered within 100 meters of each other. Six of the 12 stations located closest to the western property line (Stations 1, 4, 7, 8, 10, and 11) were modeled as six separate sources. Burn Stations 13 and 14 were modeled separately. From previous modeling and from burn information provided by the facility, the following assumptions were made: • Burn Stations 1 through 12 each consist of four adjacent burn pans. The average dimension of each burn pan is 8 feet by 13 feet, and the burn pan layout per station is approximated as an area of 16 feet by 26 feet. • Burn Station 13 consists of two adjacent burn pans. The average dimension of each pan is 6 feet by 9 feet, and the burn pan layout for this station is approximated as an area of 9 feet by 12 feet. • Burn Station 14 consists of four adjacent burn pans. The average dimension of each burn pan is 8 feet by 13 feet, and the burn pan layout for this station is approximated as an area of 16 feet by 26 feet. • The dimension of the rocket motor burn area at Burn Station 14 is assumed to be 5 feet by 50 feet. • The height of burn stations = 1.0 meter. • The detonation will be started at ground level. 4.4.2 M-225 Stations Burn Stations 1 through 4 are clustered within 100 meters and were modeled as a single source located approximately at the center of the cluster. The OD pit was modeled separately. From previous modeling and from burn information provided by the facility, the following assumptions were made: • Burn Stations 1 through 4 each consist of one burn pan, having an average pan dimension of 6 feet by 17 feet. • The height of burn stations = 1.0 meter. • The detonation will be started at ground level. 4.5 Summary of AERMOD Modeling Parameters Based on the information, a summary of the actual parameters used for modeling are described below. Shaw Environmental, Inc. 12 Addendum to Air Quality Modeling Report ATK Launch Systems 4.5.1 M-136 Stations The source parameters for M-136 are shown in Table 4-1. Table 4-1: M-136 Source Parameters Parameter M-136-A1 M-136-A2 M-136-A3 M-136B M-136-C Daily Quantity Burned (lb reactive waste) 96,000 10,000 16,000 125,000 1,200 Annual Quantity Burned (lb reactive waste) 6,720,000 840,000 840,000 1,500,000 100,000 Burn Duration 15-45 min 15-45 min 15-45 min 15-45 min 5 sec Burn Pan Area (m2) 38.65 10.03 38.65 23.23 Burn Pan Equivalent Diameter (m) 7.01 3.57 7.01 5.44 Volume Source Diameter (m) 28.06 14.3 28.06 21.75 19.51 Initial Sigma Y (m) 6.53 3.32 i.53 5.06 4.54 Initial Sigma Z (m) 6.53 3.32 6.53 5.06 4.54 Release height (m) 238 219.3 238 297 189.7 Notes: min = Minute, sec = Seconds. m2 = Square meter, m = Meter. To determine the emission rates used in AERMOD, the maximum emission factors described in Section 4.0 were multiplied by the daily quantity burned for each scenario. The emission rates for NAAQS and air toxics are shown in Tables 4-2 and 4-3, respectively. Table 4-2: M-136 Actual Emission Rates for Criteria Pollutants Pollutant PM-10 PM-2.5 S02 NO2 Emission Rate (g/s) M-136-A1 1,451.5 725.8 6.0 77.4 M-136-A2 151.2 75.6 0.6 8.1 M-136-A3 241.9 121.0 1.0 12.9 M-136-B 1,890.0 945.0 7.9 100.8 M-136-C 18.1 9.1 0.1 1.0 Table 4-3: M-136 Actual Emission Rates for Air Toxics Pollutant Emission Rate (g/s) • M-136-A Isophorone 8.45E-03 Formaldehyde 7.22E-01 Shaw Environmental, Inc. 13 Addendum to Air Quality Modeling Report ATK Launch Systems Pollutant Hydrogen Chloride Hydrogen Cyanide 1,2,4,-Trichlororbenzene 1,4-Dichlorobenzene2 2,4-Dinitrotoluene o-Toluidine Phenol CI2 1,1,2-Trichloroethane 1,3-Butadiene 1,4-Dioxane Acrylonitrile Benzene Bromoform Carbon Tetrachloride Chlorobenzene Chloroform cis-1,3-Dichloropropene Cumene Styrene Toluene Vinyl Chloride Antimony Arsenic Cadmium Chromium Cobalt Manganese Mercury Nickel Phosphorus Selenium Emission Rate (g/s) M-136-A 2.77E+02 3.38E-01 2.00E-02 1.12E-02 8.45E-03 1.08E-01 3.69E-02 1.84E+02 1.12E-02 3.69E-01 9.84E-03 2.46E-01 7.22E-01 2.00E-02 2.31 E-01 3.84E-02 9.38E-02 2.00E-02 6.46E-03 1.52E-02 2.92E-01 1.17E-01 4.46E-01 8.45E-03 9.38E-03 3.07E-01 9.38E-03 1.44E+00 1.14E-03 8.92E-01 1.69E+00 2.46E-02 Note: Air Toxics modeling was only completed for Scenario M-136-A because that scenario was determined to have the greatest impact. Shaw Environmental, Inc. 14 Addendum to Air Quality Modeling Report ATK Launch Systems 4.5.2 M-225 Stations The source parameters for scenarios M-225 are shown in Table 4-4. Table 4-4: M-225 Source Parameters Parameter Daily Quantity Burned (lb reactive waste) Annual Quantity Burned (lb reactive waste) Burn Duration Burn Pan Area (m2) Burn Pan Equivalent Diameter (m) Volume Source Diameter (m) Initial Sigma Y (m) Initial Sigma Z (m) Release height (m) M-22S-A 4,500 55,000 15-45 min 9.48 3.47 13.89 3.23 3.23 148.8 M-225-B 600 10,000 5 sec 19.51 4.54 4.54 189.7 To determine the emission rates used in AERMOD, the maximum emission factors described in Section 3.0 were multiplied by the daily quantity burned for each scenario. The emission rates for NAAQS and air toxics are shown in Tables 4-5 and 4-6, respectively. Table 4-5: M-225 Actual Emission Rates for Criteria Pollutants Pollutant PM-10 PM-2.5 S02 NO2 Emission Rate (g/s) M-225-A 68.0 34.0 0.3 3.6 M-225-B 9.1 4.5 0.04 0.5 Table 4-6: M-225 Actual Emission Rates for Air Toxics Pollutant Emission Rate (g/s) M-225-A Isophorone 3.12E-04 Formaldehyde 2.66E-02 Hydrogen Chloride 1.02E+01 Hydrogen Cyanide 1.25E-02 1,2,4,-Trichlororbenzene 7.37E-04 Shaw Environmental, Inc. 15 Addendum to Air Quality Modeling Report ATK Launch Systems Pollutant 1,4-Dichlorobenzene 2,4-Dinitrotoluene o-Toluidine Phenol CI2 1,1,2-Trichloroethane 1,3-Butadiene 1,4-Dioxane Acrylonitrile Benzene Bromoform Carbon Tetrachloride Chlorobenzene Chloroform cis-1,3-Dichloropropene Cumene Styrene Toluene Vinyl Chloride Antimony Arsenic Cadmium Chromium Cobalt Manganese Mercury Nickel Phosphorus Selenium Emission Rate • (g/s) M-225-A 4.14E-04 3.12E-04 3.97E-03 1.36E-03 6.80E+00 4.14E-04 1.36E-02 3.63E-04 9.07E-03 2.66E-02 7.37E-04 8.51 E-03 1.42E-03 3.46E-03 7.37E-04 2.38E-04 5.61 E-04 1.08E-02 4.31 E-03 1.64E-02 3.12E-04 3.46E-04 1.13E-02 3.46E-04 5.33E-02 4.20E-05 3.29E-02 6.24E-02 9.07E-04 Note: Air Toxics modeling was only completed for Scenario M-225-A because that scenario was determined to have the greatest impact. Shaw Environmental, Inc 16 Addendum to Air Quality Modeling Report ATK Launch Systems 5.0 Model Defaults and Assumptions The latest version of USEPA's AERMOD model (version 12345) was used for estimating the impact of the vapor cloud on downwind receptors. To ensure the AERMOD results represent a significant refinement, the following restrictions were considered for modeling: • The events will occur only between the hours 9:00 a.m. Mountain Standard Time (MST) and 6:00 p.m. MST • The wind speed during the events will be between 3 mph and 15 mph • The Clearing Index during the events will be 500 or higher Five years of meteorological data were screened for potential operating hours considering these restrictions. The summary of screened hours is shown in Attachment 2. These hours were modeled for the ambient impact assessment and the risk assessment. Shaw Environmental. Inc. 17 Addendum to Air Quality Modeling Report ATK Launch Systems 6.0 Meteorological Data Five years (1997 to 2001) of on-site meteorological data obtained from the site were used in the preliminary modeling. The same meteorological data were used after reprocessing the data for AERMOD using the latest version of the preprocessor, AERMET (version 12345). Non-urban (i.e., rural) land use determined from previous modeling was used in AERMET. The five years (1997 through 2001) of on-site hourly meteorological data were obtained from the site in CD-144 format and included wind speed, wind direction, temperature, and barometric pressure monitored at the site along with concurrent ceiling height and opaque cloud cover from Hill Air Force Base. Twice daily upper air data for Salt Lake City was obtained in Forecast Systems Laboratory format from the National Oceanic and Atmospheric Administration, Earth System Research Laboratory Radiosonde Database. The hourly surface meteorological observations were then used along with the twice daily Salt Lake City upper air data in the AERMET pre-preprocessor to develop surface and vertical profile meteorological databases for use in AERMOD. This processing was conducted in accordance with the latest USEPA AERMOD Implementation Guide dated March 19, 2009. Refer to the March 2013 protocol for details on the land use and surface characteristics used in processing the meteorological data. Shaw Environmental, Inc 18 Addendum to Air Quality Modeling Report ATK Launch Systems 7.0 Receptor Grid Layout For NAAQS and air toxics analysis, an off-site receptor grid was used to determine the maximum off-site ground level concentrations. The layout of the receptors was as follows: Discrete receptors were placed along the property fence line at 100-meter intervals. A Cartesian receptor grid starting from the property line extended up to 10 km in all directions. This Cartesian receptor grid was spaced at 100-meter intervals to a distance of 3 km from the facility and at 500-meter intervals between 3 km and 10 km from the facility. The terrain data for each receptor were processed using AERMOD's terrain data preprocessor, AERMAP. Using AERMAP, the base elevation and hill height scale values were determined for each receptor. The digital terrain data were obtained from 1 arc second National Elevation Dataset. The receptor grids used in the modeling conducted in support of the risk assessment are discussed in detail in Section 10.1 and include the off-site receptor grid described above. Shaw Environmental, Inc. 19 Addendum to Air Quality Modeling Report ATK Launch Systems 8.0 Modeled Output The OB and OD events were considered for only one hour per day. NAAQS compliance was demonstrated by comparing the design modeled concentration for all pollutants and averaging times with the respective NAAQS. The methodologies for one-hour, three-hour, 24-hour, and annual impact are described as follows. 8.1 Maximum One-Hour Impact AERMOD was used to calculate the maximum one-hour average impact over each year of five years of meteorological data covering all of the unrestricted hours of operation. This is the maximum one-hour average concentration for the OB/OD operations in any day of the year for each of the five years. These five one-hour average impacts for the five years were averaged to obtain the five-year average maximum one-hour impact. 8.2 Maximum Three-Hour and 24-Hour Impacts Because only one hour of OB/OD events will occur in any day (and there is no impact during the remainder of the day), the maximum values of three-hour and 24-hour averages were also based on the one-hour maximum value. For example, the maximum 24-hour average concentration in any year was calculated by dividing the maximum one-hour concentration for that year by a factor of 24 as shown below: Max^r Max24-hr=—24— Where: Max24.hr = Maximum 24-hour average concentration in ug/m3 Maxi-hr = Maximum one-hour average concentration in u,g/m3 Similarly, for the maximum three-hour concentrations, the maximum one-hour average is divided by three. The maximum three-hour and 24-hour averages for each of the five years were averaged to obtain the five-year average value for each short-term averaging time. 8.3 Maximum Annual Impact The annual total OB and OD quantities are restricted by permitted levels. To account for this limitation on annual OB/OD quantities, the following calculation was used: Shaw Environmental, Inc 20 Addendum to Air Quality Modeling Report ATK Launch Systems Where: Max annual -2 = Maximum annual average concentration in ug/m Qannual Annual quantity of reactive waste in OB/OD (lbs) Qdaily Daily quantity of reactive waste in OB/OD (lbs) 1HR, -max Maximum one-hour impact based on daily reactive waste quantity 8760 Number of hours per year Note: The term [Qannuai/Qdaiiy] represents the total number of days per year the OB/OD events can occur to reach the annual permitted quantities. This assumes that for each hour the OB/OD operations were carried out to meet the annual quantity, the impact was the same as the maximum one-hour determined previously. This is a conservative assumption. Each year of maximum one-hour average impact obtained from AERMOD was used to calculate the maximum annual impact for each year. The five maximum annual impacts were averaged to obtain the five-year average annual impact. The permitted annual reactive waste quantities for the OB/OD operations are as follows. These quantities were used as the "Qannual" in the above equation to calculate the maximum annual average concentrations. M136: Scenario AI - Open Burn in Stations 1 throughl2: 6,720,000 lbs Scenario A2 - Open Burn in Station 13: 840,000 lbs Scenario A3 - Open Burn in Station 14: 840,000 lbs Scenario B - Large Rocket Motor in Station 14: 1,500,000 lbs Scenario C - Open Detonation in Stations 13 and 14: 100,000 lbs M225: Scenario A - Open Burn in Stations 1 through 4: Scenario B - Open Detonation in Station 1: 55,000 lbs 10,000 lbs Shaw Environmental, Inc 21 Addendum to Air Quality Modeling Report ATK Launch Systems 9.0 Compliance Demonstration with NAAQS and Air Toxic Standards The objective of the modeling was to determine compliance with all applicable NAAQS and air toxics. The NAAQS and air toxics modeling results are described as follows: 9.1 NAAQS Analysis NAAQS compliance was demonstrated by comparing the design modeled concentration for all pollutants and averaging times with the respective NAAQS. No background concentrations were added to the design modeled concentration because, as mentioned in Section 3.0, the emission factors used for the modeling included background concentration. For all averaging times and pollutants, scenarios M-136A and M-225-A had the highest impact. Details of all modeling results are shown in Attachment 3. The design modeled cumulative results are shown in Table 9-1. Table 9-1: Results of Cumulative Impact for M-136 and M-225 - Criteria Pollutants Pollutant Averaging Time Group Rank Design Model Cone. (ugmi3) NAAQS (Mg/m3) % of NAAQS Exceedance of NAAQS? (Y/N) M136 A 1ST 25.00 35 71.44% No 24-HR M225 A 1ST 1.48 35 4.23% No PM-2.5 Total 1ST 26.49 35 75.67% No M136 A 1ST 5.75 12 47.95% No Annual M225 A 1ST 0.05 12 0.44% No Total 1ST 5.81 12 48.39% No M136 A 1ST 57.14 150 38.10% No PM-10 24-HR M225 A 1ST 3.65 150 2.43% No Total 1ST 60.79 150 40.53% No M136_A 1ST 64.01 189 33.87% No 1-HR M225_A 1ST 3.79 189 2.01% No N02 Total 1ST 67.80 189 35.87% No M136 A 1ST 0.70 100 0.70% No SO2 Annual 1-HR 3-HR M225_A Total M136_A M225_A Total M136_A M225_A Total 1ST 1ST 1ST 1ST 1ST 1ST 1ST 1ST 0.007 0.71 5.00 0.30 5.30 1.67 0.10 1.77 100 100 195 195 195 1300 1300 1300 0.007% 0.71% 2.56% 0.15% 2.72% 0.13% 0.01% 0.14% No No No No No No No No Shaw Environmental, Inc 22 Addendum to Air Quality Modeling Report ATK Launch Systems Pollutant Averaging Time Group Rank Design Model Cone. (ug/m3) NAAQS (ug/m3) % of NAAQS Exceedance of NAAQS? (Y/N) CO 1-HR 8-HR M136 A 1ST 64.01 40,000 M225 A 1ST 3.79 40,000 Total 1ST 67.80 40,000 M136 A 1ST 8.00 10,000 M225_A Total 1ST 1ST 0.47 8.48 10,000 10,000 0.16% 0.01% 0.17% 0.08% 0.005% 0.08% No No No No No No The results for all pollutants and averaging times show compliance with NAAQS. Therefore, no additional modeling was required. A flash drive of all modeling inputs and outputs is provided in Attachment 4. 9.2 Air Toxics Analysis Air toxics results were compared with short-term and long-term TSLs. Results of the NAAQS analysis indicated that scenarios M-136-A and M-225-A had the highest impact. Therefore, only these scenarios were considered for the air toxics analysis. The design modeled cumulative results for the acute and chronic air toxics are shown in Tables 9-2 and 9-3, respectively. Shaw Environmental, Inc 23 Addendum to Air Quality Modeling Report ATK Launch Systems Table 9-2: Results of Cumulative Impact for M-136 and M-225 - Acute One-Hour Air Toxics Air Toxic Acute 1-hr TSL Value ug/m3 Scenario M136A 1-HR Cone. ug/m3 % ofTSL Exceed TSL? (Y/N) Scenario M225A 1-HR Cone. ug/m3 % ofTSL Exceed TSL? (Y/N) Total (M136Aand M225A) 1-HR Cone. ug/m3 %of TSL Exceed TSL? (Y/N) Isophorone 2,826 0.006 0.0002% No 0.0003 0.00001% No 0.006 0.0002% Formaldehyde 37 0.470 1.27% No 0.028 0.08% No 0.498 1.35% Hydrogen Chloride 298 180.034 60.41% No 10.662 3.58% No 190.696 63.99% Hydrogen Cyanide 520 0.220 0.04% No 0.013 0.003% No 0.233 0.04% 1.2,4,- Trichlororbenzene 3,711 0.013 0.0004% No 0.001 0.00002% No 0.014 0.0004% Table 9-3: Results of Cumulative Impact for M-136 and M-225 - Chronic 24-Hour Air Toxics : Air Toxic Chronic 24-hr TSL Value ug/m3 Scenario M136A 24-HR Cone. ug/m3 % ofTSL Exceed TSL? (Y/N) Scenario NI225A 24-HR Cone. ug/m3 % of TSL Exceed TSL? (Y/N) Total (M136A and M225A) 24-HR Cone. ug/m3 %of TSL Exceed TSL? (Y/N) 1,4-Dichlorobenzene 2004 3.04E-04 0.00% No 1.80E-05 0.00% No 3.22E-04 0.00% No 2,4-Dinitrotoluene 2.29E-04 0.00% No 1.36E-05 0.00% No 2.43E-04 0.00% No o-Toluidine 292 2.92E-03 0.00% No 1.73E-04 0.00% No 3.09E-03 0.00% No Phenol 642 1.00E-03 0.00% No 5.92E-05 0.00% No 1.06E-03 0.00% No CI2 48 5.00E+00 10.42% No 2.96E-01 0.62% No 5.30E+00 11.04% No 1,1,2-Trichloroethane 1819 3.04E-04 0.00% No 1.80E-05 0.00% No 3.22E-04 0.00% No 1,3-Butadiene 49 1.00E-02 0.02% No 5.92E-04 0.00% No 1.06E-02 0.02% No 1,4-Dioxane 2402 2.67E-04 0.00% No 1.58E-05 0.00% No 2.83E-04 0.00% No Acrylonitrile 48 6.67E-03 0.01% No 3.95E-04 0.00% No 7.06E-03 0.01% No Benzene 1.96E-02 0.04% No 1.16E-03 0.00% No 2.07E-02 0.04% No Bromoform 172 5.42E-04 0.00% No 3.21 E-05 0.00% No 5.74E-04 0.00% No Carbon Tetrachloride 350 6.25E-03 0.00% No 3.70E-04 0.00% No 6.62E-03 0.00% No Shaw Environmental, Inc 24 Addendum to Air Quality Modeling Report ATK Launch Systems Air Toxic Chronic 24-hr TSL Value ug/m3 Scenario M136A 24-HR Cone. ug/m3 % of TSL Exceed TSL? (Y/N) Scenario M225A 24-HR Cone. ug/m3 % ofTSL Exceed TSL? (Y/N) Total (M136Aand M225A) 24-HR Cone. ug/m3 %of TSL Exceed TSL? (Y/N) Chlorobenzene 1535 1.04E-03 0.00% No 6.17E-05 0.00% No 1.10E-03 0.00% Chloroform 1628 2.54E-03 0.00% No 1.51E-04 0.00% No 2.69E-03 0.00% cis-1,3-Dichloropropene 151 5.42E-04 0.00% No 3.21E-05 0.00% No 5.74E-04 0.00% Cumene 8193 1.75E-04 0.00% No 1.04E-05 0.00% No 1.85E-04 0.00% Styrene 2840 4.13E-04 0.00% No 2.44E-05 0.00% No 4.37E-04 0.00% Toluene 2512 7.92E-03 0.00% No 4.69E-04 0.00% No 8.39E-03 0.00% Vinyl Chloride 28 3.17E-03 0.01% No 1.88E-04 0.00% No 3.35E-03 0.01% Antimony 17 1.21E-02 0.07% No 7.16E-04 0.00% No 1.28E-02 0.08% Arsenic 0.33 2.29E-04 0.07% No 1.36E-05 0.00% No 2.43E-04 0.07% Cadmium 0.02 2.54E-04 1.27% No 1.51E-05 0.08% No 2.69E-04 1.35% Chromium 0.11 8.33E-03 7.58% No 4.94E-04 0.45% No 8.83E-03 8.03% Cobalt 0.77 2.54E-04 0.03% No 1.51E-05 0.00% No 2.69E-04 0.03% Manganese 6.7 3.92E-02 0.58% No 2.32E-03 0.03% No 4.15E-02 0.62% Mercury 0.33 3.08E-05 0.01% No 1.83E-06 0.00% No 3.27E-05 0.01% Nickel 1.11 2.42E-02 2.18% No 1.43E-03 0.13% No 2.56E-02 2.31% Phosphorus 3.3 4.58E-02 1.39% No 2.71 E-03 0.08% No 4.86E-02 1.47% Selenium 6.7 6.67E-04 0.01% No 3.95E-05 0.00% No 7.06E-04 0.01% The results for all pollutants and averaging times show compliance with Utah's TSLs. Therefore, no additional modeling was required. A flash drive of all modeling inputs and outputs is provided in Attachment 4. Shaw Environmental, Inc. 25 Addendum to Air Quality Modeling Report ATK Launch Systems 10.0 Development of Air Dispersion Factors for Risk Assessment Human health and ecological risk assessment requires maximum values of one-hour and annual average air dispersion factors (ADFs) for gas concentration, particulate concentration, gas dry deposition, and particulate dry deposition at selected receptor locations. These ADFs were generated using the hybrid OBODM and AERMOD models as described earlier. 10.1 Receptor Locations The ADFs were estimated at the maximum exposed individual (MEI) locations within the facility and off site. The MEI locations are the locations of maximum impact at on-site and off- site locations. The site boundary was included in both on-site and off-site receptor grids for consistency. The on-site receptor grid consisted of a Cartesian grid with 100-meter spacing to cover the area bounded by the facility property boundary. The worker safety buffer zones, consisting of approximately a 2,000-foot radius around the M-136 location and approximately a 2,500-foot radius around the M-225 location, were excluded from the on-site receptor grid when modeling each scenario, respectively. These buffer zones represent the area from which field personnel are excluded during OB/OD events. The off-site receptor grid and the site boundary receptors used were as described in Section 7.0 for the air quality assessment. In addition, the risk assessment was conducted at several discrete locations in and around the facility. ADFs were determined for these discrete locations which are listed below: • The Adam's Ranch, which is the closest domestic dwelling to M-136, is located approximately 3 km south-southwest of M-136. • The Holmgren Ranch, which is the closest domestic dwelling to M-225, is located approximately 2 km east-southeast of M-225. • Four facility boundary receptors that are selected based on the annual prevailing wind direction measured over a five-year period (1997 through 2001) at the M-245 meteorological monitoring station. • AutoLiv facility, an off-site commercial business located between the M-136 and M-225 treatment units. • Christensen residence, a residential dwelling located due north of ATK. • Blue Creek perennial stream, which runs along the western boundary of M-136. • The Bear River Migratory Bird Refuge, located about 10.5 km south-southwest of M-225. Shaw Environmental, Inc. 26 Addendum to Air Quality Modeling Report ATK Launch Systems • The Salt Creek Waterfowl Management Area, located 13 km east of ATK. • The Thiokol Ranch Pond (ATK Ranch Pond), which is located approximately 14 km southwest of M-225. • The Howell Dairy Farm just north of the ATK northern property boundary. • The Town of Penrose, located approximately 7 miles southeast of M-136. • The Town of Thatcher, located approximately 7.5 miles due east of M-136. • Two on-site discrete receptors to assess potential risk to ATK workers that are not directly involved with the activities at the M-136 and M-225 treatment units. These on-site discrete receptors represent areas where most non-treatment-related employees spend their time on site. The on-site discrete receptors include the following: - North Plant Main Administration Building and Main Manufacturing Area - 2.5 miles north of M-136 and 6.7 miles north-northwest of M-225. - South Plant Main Administration Building and Main Manufacturing Area - 1.8 miles south of M-136 and 3.9 miles west-northwest of M-225. 10.2 Pollutant Phases The following phases were considered in estimating the ADFs at the on-site MEI, off-site MEI, and discrete receptors: • Gas phase one-hour and annual concentrations • Particle phase one-hour and annual concentrations • Particle bound phase one-hour and annual concentrations • Gas phase annual dry deposition • Particle phase annual dry deposition • Particle-bound phase annual dry deposition Note that ADFs are not estimated for wet deposition. This deposition mechanism is not applicable for this assessment, since treatment operations are not conducted during precipitation events. As input to the risk assessment, the ADFs for each pollutant phase were developed using AERMOD for the M-136 and M-225 scenarios described in Section 4.0 of this document. The ADFs are based on a unit emission rate of 1 g/s for each source within a scenario. The ADFs developed for each scenario will be multiplied by emission rates of specific pollutants in the risk assessment to be conducted by other consultants. Mercury speciation and exposure will be applied within the risk assessment model, which follows guidance for mercury evaluation Shaw Environmental, Inc. 27 Addendum to Air Quality Modeling Report ATK Launch Systems found in the Human Health Risk Assessment Protocol (HHRAP) for Hazardous Waste Combustion Facilities (USEPA, September 2005). Within AERMOD, the gas phase dry deposition was modeled using a conservative deposition velocity of 0.03 m/sec, which is the default value specified in the HHRAP guidance. Modeling of the particle and particle-bound phases in AERMOD required the input of particle size distribution data including: particle diameter, the mass distribution for particle phase emissions, the surface area distribution for particle-bound phase emissions, and particle density. The upper and lower bound diameter of each particle size category and the corresponding particle mass fractions were generated by OBODM considering the particle information used in previous modeling by Terra Tech, which assumed a mass median particle diameter of 30 microns, a standard deviation of 2 microns, and 10 size categories. The mean particle size diameter for each category was calculated from the upper and lower bounds obtained from the OBODM particle data using Equation 3-1 in the HHRAP. For modeling of the particle-bound phase, the equations in Section 3.2.3 of the HHRAP were used to calculate the surface area- weighted distribution of the particle size categories. The particle size distribution data for modeling of particle and particle-bound phases in AERMOD are summarized in Table 10-1. Shaw Environmental, Inc. 28 Addendum to Air Quality Modeling Report ATK Launch Systems Table 10-1: Particle Distribution Data OBODM/Historical Modeling Calculai :ed From HHRAP Guidance Particle Size Category Bounds (Mm) Mass Fraction Mean Particle Diameter* (Mm) Particle Radius (Mm) Surface Area (Mm)2 Volume (Mm)3 Surface Area/ Volume (Mm)1 Proportion Available Surface Area Fraction of Total Surface Area8 Lower 3.44 Upper 2.50 FM R=D/2 S=4*pi*RA2 V=(4/3)*pi*RA3 S/V F = (S/V)*FM 0.02265 2.99 1.50 28.17 14.06 2.00361 4.54E-02 F/sum(F) 7.72E-02 4.73 3.44 0.05202 4.12 2.06 53.29 36.58 1.45678 7.58E-02 1.29E-01 6.50 4.73 0.09708 5.66 2.83 100.68 95.00 1.05986 1.03E-01 1.75E-01 8.94 6.50 0.14713 7.78 3.89 190.34 246.92 0.77084 1.13E-01 1.93E-01 12.30 8.94 0.18113 10.71 5.35 360.21 642.85 0.56034 1.01E-01 1.73E-01 16.92 12.30 0.18113 14.73 7.37 681.71 1,673.68 0.40731 7.38E-02 1.25E-01 23.27 16.92 0.14713 20.26 10.13 1,289.63 4,354.83 0.29614 4.36E-02 7.41E-02 32.01 23.27 0.09708 27.87 13.93 2,439.91 11,332.75 0.21530 2.09E-02 3.56E-02 44.04 32.01 0.05202 38.34 19.17 4,617.89 29,508.00 0.15650 8.14E-03 1.38E-02 60.57 44.04 0.02265 52.74 26.37 8,737.29 76,796.06 0.11377 2.58E-03 4.38E-03 Notes: References: 2005 HHRAP Guidance (Section 3.2, Table 3-1). A Mean Particle Diameter (D); USEPA's HHRAP Guidance, September 2005, Equation 3-1: D = [0.25* (Di* 3 + 01*2*02 + 01' D2 A2 + D2 A 3)]" (1/3) Where: Di = lower bound cut of particle size category (iim) D2 = upper bound cut of particle size category f/jmj. 8 Surface area-based distribution for particle-bound phase modeling, as descnbed in Section 3.2.3 of USEPA's HHRAP Guidance, September 2005. Shaw Environmental. Inc 29 Addendum to Air Quality Modeling Report ATK Launch Systems A particle density of 2.7 grams per cubic meter was applied for this assessment and was assumed to be constant over all particle size categories. This value corresponds to the density of aluminum, which was determined from historical testing to be the most abundant metal in the OB and OD emissions and was the particle density used in previous modeling of the ATK operations. 10.3 One-Hour ADF for Concentration The one-hour ADFs were determined individually for each of the sources representing the operating scenarios for M-136 and M-225 using unit emission rates for emission of gaseous and particulate pollutants. As described for the air quality assessment, the unit emission rates were input to AERMOD for each hour of unrestricted operation. For assessing acute risk, maximum concentrations out of the five years modeled were determined for each modeled scenario at the on-site MEI, off-site MEI, and at each of the discrete receptors, and these concentrations represent the one-hour ADF values. 10.4 Annual ADF for Concentration Annual values of concentration and deposition are used to assess chronic risk and are based on the five-year averages determined from modeling. For developing the annual ADFs, the models were programmed to yield one-hour concentration values at each receptor averaged over the five-year meteorological period. In the same manner as for the annual impacts for the air quality assessment, the annual ADFs were determined individually from the five-year average one-hour concentrations for each modeled scenario as follows: ^annual ADF - da'*y riurannual ^ dailv 8760 Where: ADFannuai = Maximum annual average concentration in ug/m3 Qannual = Annual quantity of reactive waste in OB/OD (lbs) Qdaiiy = Daily quantity of reactive waste in OB/OD (lbs) ADFi.hr = 5-year average 1-hour concentration based on daily reactive waste quantity 8760 - Number of hours per year Note: The term [Qannual/Qdaiiy] represents the total number of days per year the OB/OD events can occur to reach the annual permitted quantities. Shaw Environmental, Inc 30 Addendum to Air Quality Modeling Report ATK Launch Systems Annual ADFs for the off-site MEI and the on-site MEI were calculated from the highest five- year average one-hour concentration values for each scenario over the respective receptor sets. For the sensitive receptors, annual ADFs were calculated from the five-year average one-hour concentration values at each discrete receptor. 10.5 Annual ADF for Deposition The procedure for determining the annual ADFs for dry deposition was similar to the calculation of the annual ADFs for concentration. First, the five-year average one-hour values for dry deposition were determined and then the annual ADFs were calculated using the equation shown in Section 10.4 above. 10.6 Summary of ADFs The ADFs developed for use in the risk assessment were determined for the M-136 and M-225 scenarios as described above. The ADFs for concentration and deposition are presented for the off-site MEI, on-site MEI, and discrete receptors on the flash drive in Attachment 5. All modeling files used in determining these ADFs for the risk assessment are included on the flash drive in Attachment 4. Shaw Environmental, Inc 31 Addendum to Air Quality Modeling Report ATK Launch Systems 11.0 Conclusion To ensure the AERMOD results represent a significant refinement, the air quality modeling results consider that the OB and OD events occur for only one hour per day and must meet the following criteria: • The event will occur only between the hours 9:00 a.m. and 6:00 p.m. MST • The wind speed during the event will be between 3 and 15 mph • The Clearing Index during the events will be 500 or higher The results indicate that Scenarios M-136-A and M-225-A have the greatest impact. The cumulative impact of these two scenarios shows compliance with the NAAQS and Utah's acute and chronic toxic screening levels. Therefore, no additional modeling is required if the above restrictions are met when performing OB and OD events. Shaw Environmental, Inc. 32 Addendum to Air Quality Modeling Report ATK Launch Systems Attachment 1 Example for the Cloud Height Calculation OBODM Modeling for Plume Dimensions - M-136 Unit and M-225 Unit, ATK Promontory Wind Speed Category: 10-12.5 mph Atmospheric Stability: D (neutral) Wind Speed (mph) (m/s) Scenario Quantity of Reactive Waste per Burn Station (lb) Stability Category D Vapor Cloud Ht (m) 10 4.47 M136 Scenar M136 Scenar M136 Scenari M136 Scenari M136 Scenari M225 Scenari M225 Scenari oA-l-OB o A-2 - OB o A-3 - OB oB-OB oC-OD oA-OB o B-OD 16,000 10,000 16,000 125,000 600 1,125 600 235.5 216.4 235.5 295.7 189.7 145.7 189.7 11.25 5.03 M136 Scenari o A-l - OB M136 Scenari o A-2 - OB M136 Scenar o A-3 - OB M136 Scenari o B-OB M136 Scenari oC-OD M225 Scenari o A-OB M225 Scenari o B-OD 16,000 10,000 16,000 125,000 600 1,125 600 223.4 202.6 223.4 289.6 189.7 147.3 189.7 12.5 5.59 M136 Scenari o A-l-OB M136 Scenari o A-2 - OB M136 Scenar o A-3 - OB M136 Scenar o B-OB M136 Scenar oC-OD M225 Scenar oA-OB M225 Scenar o B-OD 16,000 10,000 16,000 125,000 600 1,125 600 218.5 197 218.5 287.1 189.7 132.3 189.7 Shows the minimum cloud height that wi combination of wind speed category and II be considered in AERMOD for this atmospheric stability. Cloud heights will be determined for other combinations of wind speed category and atmospheric stability using the same approach. Attachment 2 Summary of Screened Hours ATK Promontory OBOD Modeling Meteorological Data Analysis Restrictions Daytime Operations: Beginning Operating Hour: Last Operating Hour: Clearing Index >= 10 (9 AM) 18 (6 PM) 500 Wind Speed Group M/s MPH Group 0 1.34<=WS<2.24 3-5 Group 1 2.23<=WS<3.35 5-7.5 Group 2 3.35<=WS<4.47 7.5-10 Group 3 4.47<=WS<5.59 10-12.5 Group 4 5.59<=WS<6.71 12.5-15 Unrestricted Hours: Meteorological Year Atmospheric Stability 1.34<=WS<2.24 2.23<=WS<3.35 Wind Speed Groups 3.35<=WS<4.47 4.47<=WS<5.59 S.59<=WS<6.71 1997 Total 33 99 32 120 14 71 233 12 94 55 161 70 121 193 1998 Total 31 86 19 121 13 56 220 24 103 29 156 81 119 200 1999 Total 33 101 42 134 18 86 253 29 133 40 202 69 137 206 2000 Total 34 115 18 102 18 60 235 32 158 57 247 102 168 272 2001 Total 37 142 17 132 24 62 298 20 182 56 258 106 163 270 Grand Total Attachment 3 Detailed Modeling Results NAAQS ATK AERMOD Results Summary Pollutant Averaging Time Group Rank Cone. (ug/m3) NAAQS (ug/m3) %of NAAQS Exceedance of NAAQS? (Y/N) PM2.5 M136 A 1ST 25.00 35 71.44% 24-HR M225 A 1ST 1.48 35 4.23% Total 1ST 26.49 35 75.67% No No No PM2.5 M136 A 1ST 5.75 12 47.95% Annual M225 A 1ST 0.05 12 0.44% Total 1ST 5.81 12 48.39% No No No PM10 M136 A 1ST 57.14 150 38.10% 24-HR M225 A 1ST 3.65 150 2.43% Total 1ST 60.79 150 40.53% No No No N02 M136 A 1ST 64.01 189 33.87% 1-HR M225 A 1ST 3.79 189 2.01% Total 1ST 67.80 189 35.87% No No No N02 M136 A 1ST 0.70 100 0.70% Annual M225 A 1ST 0.007 100 0.007% Total 1ST 0.71 100 0.71% No No No S02 M136 A 1ST 5.00 195 2.56% 1-HR M225 A 1ST 0.30 195 0.15% Total 1ST 5.30 195 2.72% No No No S02 M136 A 1ST 1.67 1300 0.13% 3-HR M225 A 1ST 0.10 1300 0.01% Total 1ST 1.77 1300 0.14% No No No CO M136 A 1ST 64.01 40,000 0.16% 1-HR M225 A 1ST 3.79 40,000 0.01% Total 1ST 67.80 40,000 0.17% No No No CO M136 A 1ST 8.00 10,000 0.08% 8-HR M225_A Total 1ST 1ST 0.47 8.48 10,000 10,000 0.005% 0.08% No No No ATK AERMOD Results: M-136 Summary - CO Source M136-A1 M136-A2 M136-A3 M136-B M136-C PM2.5 Emission Rate 725.8 g/s 75.6 121.0 945.0 9.1 CO Emission Rate 77.4 g/s g/s g/s g/s g/s 8.1 12.9 100.8 1.0 g/s g/s g/s g/s Average 1-HR Maximum Concentration (1997-2001) Pollutant Averaging Time Group Rank Cone. (ug/m3) NAAQS (ug/m3) % of NAAQS Exceedance of NAAQS? (Y/N) CO 1-HR M136 A 1ST 64.01 40,000 0.16% No CO 1-HR M136 B 1ST 49.44 40,000 0.12% No CO 1-HR M136 C 1ST 0.88 40,000 0.002% No Average 8-HR Maximum Concentration (1997-2001) Pollutant Averaging Time Group Rank Cone. (ug/m3) NAAQS (ug/m3) % of NAAQS Exceedance of NAAQS? (Y/N) CO 8-HR M136 A 1ST 8.00 10,000 0.08% No CO 8-HR M136 B 1ST 6.18 10,000 0.06% No CO 8-HR M136 C 1ST 0.11 10,000 0.001% No ATK AERMOD Results: M-136 Sc A: M-136A1, M-136A2, M-136A3 Source M136-A1 M136-A2 M136-A3 Total PM2.5 Emission Rate CO Emission Rate 72S.8 75.6 121.0 922.3 g/s g/s g/s g/s 77.4 8.1 12.9 98.4 g/s g/s g/s g/s Operation Limits: CO 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 CO 1-HR ALL 1ST 382362.02 4617770.93 1472.66 59.26 1998 CO 1-HR ALL 1ST 379830.93 4616206.59 1344.98 73.14 1999 CO 1-HR ALL 1ST 379400 4616400 1454.41 66.15 2000 CO 1-HR ALL 1ST 379300 4615400 1464.83 63.06 2001 CO 1-HR ALL 1ST 382362.65 4616770.93 1506.33 58.45 Ave 64.01 CO 8-HR Results Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 CO 8-HR ALL 1ST 382362.02 4617770.93 1472.66 7.41 1998 CO 8-HR ALL 1ST 379830.93 4616206.59 1344.98 9.14 1999 CO 8-HR ALL 1ST 379400 4616400 1454.41 8.27 2000 CO 8-HR ALL 1ST 379300 4615400 1464.83 7.88 2001 CO 8-HR ALL 1ST 382362.65 4616770.93 1506.33 Ave 7.31 8.00 ATK AERMOD Results: M-136 Sc B: M-136B Source PM2.5 Emission Rate M136-B 945.0 g/s CO Emission Rate 100.8 g/s Operation Limits: CO 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) Time 1997 CO 1-HR ALL 1ST 379500 4616300 1408.87 42.07 97090818 1998 CO 1-HR ALL 1ST 379832.7 4616406.58 1344.62 66.96 98091718 1999 CO 1-HR ALL 1ST 379400 4616600 1451.13 51.23 99092218 2000 CO 1-HR ALL 1ST 379200 4615400 1482.7 42.49 00022117 2001 CO 1-HR ALL 1ST 382600 4617000 1560.47 44.45 01033018 Ave 49.44 CO 8-HR Results Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 CO 8-HR ALL 1ST 379500 4616300 1408.87 5.26 1998 CO 8-HR ALL 1ST 379832.7 4616406.58 1344.62 8.37 1999 CO 8-HR ALL 1ST 379400 4616600 1451.13 6.40 2000 CO 8-HR ALL 1ST 379200 4615400 1482.7 5.31 2001 CO 8-HR ALL 1ST 382600 4617000 1560.47 Ave 5.56 6.18 ATK AERMOD Results: M-136 ScC: M-136C Source PM2.5 Emission Rate M136-C 9.1 g/s CO Emission Rate 1.0 g/s Operation Limits: CO 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) Time 1997 CO 1-HR ALL 1ST 379600 4616300 1382.01 0.82 97090818 1998 CO 1-HR ALL 1ST 379831.82 4616306.59 1344.3 0.89 98091718 1999 CO 1-HR ALL 1ST 379600 4616500 1387.94 1.05 99092218 2000 CO 1-HR ALL 1ST 379500 4615600 1399.48 0.81 00022117 2001 CO 1-HR ALL 1ST 379600 4616100 1384.21 0.84 01041818 Ave 0.88 CO 8-HR Results Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 CO 8-HR ALL 1ST 379600 4616300 1382.01 0.10 1998 CO 8-HR ALL 1ST 379831.82 4616306.59 1344.3 0.11 1999 CO 8-HR ALL 1ST 379600 4616500 1387.94 0.13 2000 CO 8-HR ALL 1ST 379500 4615600 1399.48 0.10 2001 CO 8-HR ALL 1ST 379600 4616100 1384.21 Ave 0.11 0.11 ATK AERMOD Results: M-136 Summary - N02 Source PM2.5 Emission Rate M136-A1 725.8 g/s M136-A2 75.6 g/s M136-A3 121.0 g/s M136-B 945.0 g/s M136-C 9.1 g/s N02 Emission Rate 77.4 8.1 12.9 100.8 1.0 g/s g/s g/s g/s g/s Average 1-HR Maximum Concentration (1997-2001) Pollutant Averaging Time Group Rank Cone. (ug/m3) NAAQS (ug/m3) % of NAAQS Exceedance of NAAQS? (Y/N) N02 1-HR M136 A 1ST 64.01 189 33.87% No N02 1-HR M136 B 1ST 49.44 189 26.16% No N02 1-HR M136 C 1ST 0.88 189 0.47% No Maximum Annual Maximum Concentration (1997-2001) Pollutant Averaging Time Group Rank Cone. (ug/m3) NAAQS (ug/m3) % of NAAQS Exceedance of NAAQS? (Y/N) N02 Annual M136 A 1ST 0.70 100 0.70% No NQ2 N02 Annual Annual M136_B M136 C 1ST 1ST 0.09 0.01 100 100 0.09% 0.01% No No ATK AERMOD Results: M-136 Sc A: M-136A1, M-136A2, M-136A3 Source M136-A1 M136-A2 M136-A3 Total PM2.5 Emission Rate N02 Emission Rate 725.8 75.6 121.0 922.3 g/s g/s g/s g/s 77.4 8.1 12.9 98.4 g/s g/s g/s g/s Operation Limits: N02 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) Time 1997 N02 1-HR ALL 1ST 382362.02 4617770.93 1472.66 59.26 97032918 1998 N02 1-HR ALL 1ST 379830.93 4616206.59 1344.98 73.14 98091718 1999 N02 1-HR ALL 1ST 379400 4616400 1454.41 66.15 99092218 2000 N02 1-HR ALL 1ST 379300 4615400 1464.83 63.06 00022117 2001 N02 1-HR ALL 1ST 382362.65 4616770.93 1506.33 Ave Max 58.45 64.01 73.14 01033018 ATK AERMOD Results: M-136 Sc B: M-136B Source PM2.5 Emission Rate N02 Emission Rate M136-B 945.0 g/s 100.8 g/s Operation Limits: N02 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) Time 1997 N02 1-HR ALL 1ST 379500 4616300 1408.87 42.07 97090818 1998 N02 1-HR ALL 1ST 379832.7 4616406.58 1344.62 66.96 98091718 1999 N02 1-HR ALL 1ST 379400 4616600 1451.13 51.23 99092218 2000 N02 1-HR ALL 1ST 379200 4615400 1482.7 42.49 00022117 2001 N02 1-HR ALL 1ST 382600 4617000 1560.47 Ave Max 44.45 49.44 66.96 01033018 ATK AERMOD Results: M-136 Sc C: M-136C Source PM2.5 Emission Rate M136-C 9.1 g/s N02 Emission Rate 1.0 g/s Operation Limits: N02 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) Time 1997 N02 1-HR ALL 1ST 379600 4616300 1382.01 0.817827 97090818 1998 N02 1-HR ALL 1ST 379831.82 4616306.59 1344.3 0.889116 98091718 1999 N02 1-HR ALL 1ST 379600 4616500 1387.94 1.045471 99092218 2000 N02 1-HR ALL 1ST 379500 4615600 1399.48 0.806849 00022117 2001 N02 1-HR ALL 1ST 379600 4616100 1384.21 Ave Max 0.84253 0.88 1.05 01041818 ATK AERMOD Results: M-136 Annual Calculations Scenario A Daily Quantity (lbs) Annual Quantity (lbs) Days/Year Maximum Days/Year At 84 Days/Year Total (lbs) Stations 1-12 96,000 6,720,000 70 8,064,000 Station 13 10,000 840,000 84 84 840,000 10,248,000 Station 14 16,000 840,000 52.5 1,344,000 Max 24-HR Impact: Annual Impact at 84 Days/Year: 3.05 0.70 ug/m3 ug/m 3 Scenario B Station 14 Daily Quantity (lbs) 125,000 Annual Quantity (lbs) 1,500,000 Days/Year 12 Max 24-HR Impact: 2.79 ug/m3 Annual Impact at 12 Days/Year: 0.09 ug/m3 Scenario C Stations 13 and 14 Daily Quantity (lbs) 1,200 Annual Quantity (lbs) 100,000 Days/Year 84 Max 24-HR Impact: Annual Impact at 84 Days/Year: 0.04 0.01 ug/m3 ug/m3 ATK AERMOD Results: M-136 Summary - PM10 Source PM2.5 Emission Rate M136-A1 725.8 g/s M136-A2 75.6 g/s M136-A3 121.0 g/s M136-B 945.0 g/s M136-C 9.1 g/s PM10 Emission Rate 1451.5 g/s 151.2 241.9 1890.0 18.1 g/s g/s g/s g/s Average 1-HR Concentration (1997-2001) Pollutant Averaging Time Group Rank Cone. (ug/m3) PM10 1-HR M136 A 1ST 1200.22 PM10 1-HR M136 B 1ST 926.96 PM10 1-HR M136 C 1ST 16.51 Maximum 24-HR Concentration (1997-2001) Pollutant Averaging Time Group Rank Cone. (ug/m3) NAAQS (ug/m3) % of NAAQS Exceedance of NAAQS? (Y/N) PM10 24-HR M136 A 1ST 57.14 150 38.10% No PM10 PM10 24-HR 24-HR M136_B M136 C 1ST 1ST 52.31 0.82 150 150 34.87% 0.54% No No ATK AERMOD Results: M-136 Sc A: M-136A1, M-136A2, M-136A3 Source M136-A1 M136-A2 M136-A3 Total PM2.5 Emission Rate PM10 Emission Rate 725.8 75.6 121.0 922.3 g/s g/s g/s g/s 1451.5 g/s 151.2 g/s 241.9 g/s 1844.6 g/s Operation Limits: PM10 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) Time 1997 PM10 1-HR ALL 1ST 382362.02 4617770.93 1472.66 1111.05 97032918 1998 PM10 1-HR ALL 1ST 379830.93 4616206.59 1344.98 1371.45 98091718 1999 PM10 1-HR ALL 1ST 379400 4616400 1454.41 1240.38 99092218 2000 PM10 1-HR ALL 1ST 379300 4615400 1464.83 1182.36 00022117 2001 PM10 1-HR ALL 1ST 382362.65 4616770.93 1506.33 1095.88 01033018 Ave 1200.22 PM10 24-HR Results Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 PM10 24-HR ALL 1ST 382362.02 4617770.93 1472.66 46.29 1998 PM10 24-HR ALL 1ST 379830.93 4616206.59 1344.98 57.14 1999 PM10 24-HR ALL 1ST 379400 4616400 1454.41 51.68 2000 PM10 24-HR ALL 1ST 379300 4615400 1464.83 49.27 2001 PM10 24-HR ALL 1ST 382362.65 4616770.93 1506.33 Max 45.66 57.14 ATK AERMOD Results: M-136 Sc B: M-136B Source PM2.5 Emission Rate PM10 Emission Rate M136-B 945.0 g/s 1890.0 g/s Operation Limits: PM10 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year 1997 Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) Time PM10 1-HR ALL 1ST 379500 4616300 1408.87 788.76306 97090818 1998 PM10 1-HR ALL 1ST 379832.7 4616406.58 1344.62 1255.4544 98091718 1999 PM10 1-HR ALL 1ST 379400 4616600 1451.13 960.47638 99092218 2000 PM10 1-HR ALL 1ST 379200 4615400 1482.7 796.72006 00022117 2001 PM10 1-HR ALL 1ST 382600 4617000 1560.47 833.39556 01033018 Ave 926.96 PM10 24-HR Results Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 PM10 24-HR ALL 1ST 379500 4616300 1408.87 32.87 1998 PM10 24-HR ALL 1ST 379832.7 4616406.58 1344.62 52.31 1999 PM10 24-HR ALL 1ST 379400 4616600 1451.13 40.02 2000 PM10 24-HR ALL 1ST 379200 4615400 1482.7 33.20 2001 PM10 24-HR ALL 1ST 382600 4617000 1560.47 Max 34.72 52.31 ATK AERMOD Results: M-136 Sc C: M-136C Source PM2.5 Emission Rate PM10 Emission Rate M136-C 9.1 g/s 18.1 g/s Operation Limits: PM10 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) Time 1997 PM10 1-HR ALL 1ST 379600 4616300 1382.01 15.33426 97090818 1998 PM10 1-HR ALL 1ST 379831.82 4616306.59 1344.3 16.67092 98091718 1999 PM10 1-HR ALL 1ST 379600 4616500 1387.94 19.60258 99092218 2000 PM10 1-HR ALL 1ST 379500 4615600 1399.48 15.12842 00022117 2001 PM10 1-HR ALL 1ST 379600 4616100 1384.21 15.79744 01041818 Ave 16.51 PM10 24-HR Results Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 PM10 24-HR ALL 1ST 379600 4616300 1382.01 0.64 1998 PM10 24-HR ALL 1ST 379831.82 4616306.59 1344.3 0.69 1999 PM10 24-HR ALL 1ST 379600 4616500 1387.94 0.82 2000 PM10 24-HR ALL 1ST 379500 4615600 1399.48 0.63 2001 PM10 24-HR ALL 1ST 379600 4616100 1384.21 Max 0.66 0.82 ATK AERMOD Results: M-136 Summary - PM2.5 Source M136-A1 M136-A2 M136-A3 M136-B M136-C PM2.5 Emission Rate 725.8 g/s 75.6 121.0 945.0 9.1 g/s g/s g/s g/s Average 1-HR Maximum Concentration (1997-2001) Pollutant Averaging Time Group Rank Cone. (ug/m3) PM2.5 1-HR M136 A 1ST 600.11 PM2.5 1-HR M136 B 1ST 463.48 PM2.5 1-HR M136 C 1ST 8.25 Average 24-HR Maximum Concentration (1997-2001) Pollutant Averaging Time Group Rank Cone. (ug/m3) NAAQS (ug/m3) % of NAAQS Exceedance of NAAQS? (Y/N) PM2.5 24-HR M136 A 1ST 25.00 35 71.44% No PM2.5 24-HR M136 B 1ST 19.31 35 55.18% No PM2.5 24-HR M136 C 1ST 0.34 35 0.98% No Average Annual Maximum Concentration (1997-2001) Pollutant Averaging Time Group Rank Cone. (ug/m3) NAAQS (ug/m3) % of NAAQS Exceedance of NAAQS? (Y/N) PM2.5 PM2.5 PM2.5 Annual Annual Annual M136_A M136_B M136 C 1ST 1ST 1ST 5.75 0.63 0.08 12 12 12 47.95% 5.29% 0.66% No No No ATK AERMOD Results: M-136 Sc A: M-136A1, M-136A2, M-136A3 Source PM2.5 Emission Rate M136-A1 725.8 g/s M136-A2 75.6 g/s M136-A3 121.0 g/s Operation Limits: PM2.5 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) Time 1997 PM2.5 1-HR ALL 1ST 382362.02 4617770.93 1472.66 555.525 97032918 1998 PM2.5 1-HR ALL 1ST 379830.93 4616206.59 1344.98 685.7226 98091718 1999 PM2.5 1-HR ALL 1ST 379400 4616400 1454.41 620.1922 99092218 2000 PM2.5 1-HR ALL 1ST 379300 4615400 1464.83 591.1811 00022117 2001 PM2.5 1-HR ALL 1ST 382362.65 4616770.93 1506.33 547.9388 01033018 Ave 600.11 PM2.5 24-HR Results Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 PM2.5 24-HR ALL 1ST 382362.02 4617770.93 1472.66 23.15 1998 PM2.5 24-HR ALL 1ST 379830.93 4616206.59 1344.98 28.57 1999 PM2.5 24-HR ALL 1ST 379400 4616400 1454.41 25.84 2000 PM2.5 24-HR ALL 1ST 379300 4615400 1464.83 24.63 2001 PM2.5 24-HR ALL 1ST 382362.65 4616770.93 1506.33 Ave 22.83 25.00 ATK AERMOD Results: M-136 Sc B: M-136B Source PM2.5 Emission Rate M136-B 945.0 g/s Operation Limits: PM2.5 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) Time 1997 PM2.5 1-HR ALL 1ST 379500 4616300 1408.87 394.3815 97090818 1998 PM2.5 1-HR ALL 1ST 379832.7 4616406.58 1344.62 627.7272 98091718 1999 PM2.5 1-HR ALL 1ST 379400 4616600 1451.13 480.2382 99092218 2000 PM2.5 1-HR ALL 1ST 379200 4615400 1482.7 398.36 00022117 2001 PM2.5 1-HR ALL 1ST 382600 4617000 1560.47 Ave 416.6978 463.48 01033018 PM2.5 24-HR Results Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 PM2.5 24-HR ALL 1ST 379500 4616300 1408.87 16.43 1998 PM2.5 24-HR ALL 1ST 379832.7 4616406.58 1344.62 26.16 1999 PM2.5 24-HR ALL 1ST 379400 4616600 1451.13 20.01 2000 PM2.5 24-HR ALL 1ST 379200 4615400 1482.7 16.60 2001 PM2.5 24-HR ALL 1ST 382600 4617000 1560.47 Ave 17.36 19.31 ATK AERMOD Results: M-136 Sc C: M-136C Source PM2.5 Emission Rate M136-C 9.1 g/s Operation Limits: PM2.5 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) - Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) Time 1997 PM2.5 1-HR ALL 1ST 379600 4616300 1382.01 7.66713 97090818 1998 PM2.5 1-HR ALL 1ST 379831.82 4616306.59 1344.3 8.33546 98091718 1999 PM2.5 1-HR ALL 1ST 379600 4616500 1387.94 9.80129 99092218 2000 PM2.5 1-HR ALL 1ST 379500 4615600 1399.48 7.56421 00022117 2001 PM2.5 1-HR ALL 1ST 379600 4616100 1384.21 7.89872 01041818 Ave 8.25 PM2.5 24-HR Results Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 PM2.5 24-HR ALL 1ST 379600 4616300 1382.01 0.32 1998 PM2.5 24-HR ALL 1ST 379831.82 4616306.59 1344.3 0.35 1999 PM2.5 24-HR ALL 1ST 379600 4616500 1387.94 0.41 2000 PM2.5 24-HR ALL 1ST 379500 4615600 1399.48 0.32 2001 PM2.5 24-HR ALL 1ST 379600 4616100 1384.21 Ave 0.33 0.34 ATK AERMOD Results: M-136 Annual Calculations Station 14 16,000 840,000 52.5 1,344,000 Max 24-HR Impact: 25.00 ug/m3 Annual Impact at 84 Days/Year: 5.75 ug/m3 Scenario A Stations 1-12 Station 13 Daily Quantity (lbs) 96,000 10,000 Annual Quantity (lbs) 6,720,000 840,000 Days/Year 70 84 Maximum Days/Year 84 At 84 Days/Year 8,064,000 840,000 Total (lbs) 10,248,000 Scenario B Station 14 Daily Quantity (lbs) 125,000 Annual Quantity (lbs) 1,500,000 Days/Year 12 Max 24-HR Impact: 19.31 ug/m3 Annual Impact at 12 Days/Year: 0.63 ug/m3 Scenario C Stations 13 and 14 Daily Quantity (lbs) 1,200 Annual Quantity (lbs) 100,000 Days/Year 84 Max 24-HR Impact: 0.34 ug/m3 Annual Impact at 84 Days/Year: 0.08 ug/m3 ATK AERMOD Results: M-136 Summary -S02 Source M136-A1 M136-A2 M136-A3 M136-B M136-C PM2.5 Emission Rate 725.8 g/s 75.6 121.0 945.0 9.1 g/s g/s g/s g/s S02 Emission Rate 6.0 g/s 0.6 g/s 1.0 g/s 7.9 " g/s 0.1 g/s Average 1-HR Maximum Concentration (1997-2001) Pollutant Averaging Time Group Rank Cone. (ug/m3) NAAQS (ug/m3) % of NAAQS Exceedance of NAAQS? (Y/N) S02 1-HR M136 A 1ST 5.00 195 2.56% No S02 1-HR M136 B 1ST 3.86 195 1.98% No S02 1-HR M136 C 1ST 0.07 195 0.04% No Average 3-HR Maximum Concentration (1997-2001) Pollutant Averaging Time Group Rank Cone. (ug/m3) NAAQS (ug/m3) % of NAAQS Exceedance of NAAQS? (Y/N) S02 3-HR M136 A 1ST 1.67 1,300 0.13% No SQ2 S02 3-HR 3-HR M136_B M136 C 1ST 1ST 1.29 0.02 1,300 1,300 0.10% 0.00% No No ATK AERMOD Results: M-136 Sc A: M-136A1, M-136A2, M-136A3 Source M136-A1 M136-A2 M136-A3 Total PM2.5 Emission Rate S02 Emission Rate 725.8 75.6 121.0 922.3 g/s g/s g/s g/s 6.0 0.6 1.0 7.7 g/s g/s g/s g/s Operation Limits: 502 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) Time 1997 S02 1-HR ALL 1ST 382362.02 4617770.93 1472.66 4.63 97032918 1998 S02 1-HR ALL 1ST 379830.93 4616206.59 1344.98 5.71 98091718 1999 S02 1-HR ALL 1ST 379400 4616400 1454.41 5.17 99092218 2000 S02 1-HR ALL 1ST 379300 4615400 1464.83 4.93 00022117 2001 S02 1-HR ALL 1ST 382362.65 4616770.93 1506.33 4.57 01033018 Ave 5.00 S02 3-HR Results Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 S02 3-HR ALL 1ST 382362.02 4617770.93 1472.66 1.54 1998 S02 3-HR ALL 1ST 379830.93 4616206.59 1344.98 1.90 1999 S02 3-HR ALL 1ST 379400 4616400 1454.41 1.72 2000 S02 3-HR ALL 1ST 379300 4615400 1464.83 1.64 2001 S02 3-HR ALL 1ST 382362.65 4616770.93 1506.33 Ave 1.52 1.67 ATK AERMOD Results: M-136 Sc B: M-136B Source PM2.5 Emission Rate M136-B 945.0 g/s S02 Emission Rate 7.9 g/s Operation Limits: S02 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (mj Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) Time 1997 S02 1-HR ALL 1ST 379500 4616300 1408.87 3.29 97090818 1998 S02 1-HR ALL 1ST 379832.7 4616406.58 1344.62 5.23 98091718 1999 S02 1-HR ALL 1ST 379400 4616600 1451.13 4.00 99092218 2000 S02 1-HR ALL 1ST 379200 4615400 1482.7 3.32 00022117 2001 S02 1-HR ALL 1ST 382600 4617000 1560.47 3.47 01033018 Ave 3.86 S02 3-HR Results Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 S02 3-HR ALL 1ST 379500 4616300 1408.87 1.10 1998 S02 3-HR ALL 1ST 379832.7 4616406.58 1344.62 1.74 1999 S02 3-HR ALL 1ST 379400 4616600 1451.13 1.33 2000 S02 3-HR ALL 1ST 379200 4615400 1482.7 1.11 2001 S02 3-HR ALL 1ST 382600 4617000 1560.47 Ave 1.16 1.29 ATK AERMOD Results: M-136 Sc C: M-136C Source PM2.5 Emission Rate M136-C 9.1 g/s S02 Emission Rate 0.1 g/s Operation Limits: S02 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) Time 1997 S02 1-HR ALL 1ST 379600 4616300 1382.01 0.063893 97090818 1998 S02 1-HR ALL 1ST 379831.82 4616306.59 1344.3 0.069462 98091718 1999 S02 1-HR ALL 1ST 379600 4616500 1387.94 0.081677 99092218 2000 S02 1-HR ALL 1ST 379500 4615600 1399.48 0.063035 00022117 2001 S02 1-HR ALL 1ST 379600 4616100 1384.21 0.065823 01041818 Ave 0.07 S02 3-HR Results Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 S02 3-HR ALL 1ST 379600 4616300 1382.01 0.02 1998 S02 3-HR ALL 1ST 379831.82 4616306.59 1344.3 0.02 1999 S02 3-HR ALL 1ST 379600 4616500 1387.94 0.03 2000 S02 3-HR ALL 1ST 379500 4615600 1399.48 0.02 2001 S02 3-HR ALL 1ST 379600 4616100 1384.21 Ave 0.02 0.02 ATK AERMOD Results: M-225 Summary - CO Source PM2.5 Emission Rate M225-A 34.0 g/s M225-B 4.5 g/s CO Emission Rate 3.6 g/s 0.5 g/s Average 1-HR Maximum Concentration (1997-2001) Pollutant Averaging Time Group Rank Cone. (ug/m3) NAAQS (ug/m3) % of NAAQS Exceedance of NAAQS? (Y/N) CO 1-HR M225 A 1ST 3.79 40,000 0.01% No CO 1-HR M225 B 1ST 0.34 40,000 0.001% No Average 8-HR Maximum Concentration (1997-2001) Pollutant Averaging Time Group Rank Cone. (ug/m3) NAAQS (ug/m3) % of NAAQS Exceedance of NAAQS? (Y/N) CO 8-HR M225 A 1ST 0.47 10,000 0.005% No CO 8-HR M225 B 1ST 0.04 10,000 0.0004% No ATK AERMOD Results: M-225 Sc A: M-225A Source PM2.5 Emission Rate M225-A 34.0 g/s CO Emission Rate 3.6 g/s Operation Limits: CO 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) Time 1997 CO 1-HR ALL 1ST 387300 4610300 1382.75 4.32 97040818 1998 CO 1-HR ALL 1ST 387266.82 4611352 1430.36 3.29 98120216 1999 CO 1-HR ALL 1ST 387300 4610600 1400.49 4.67 99121416 2000 CO 1-HR ALL 1ST 386552.26 4608450.55 1299.93 3.07 00031418 2001 CO 1-HR ALL 1ST 387270.82 4610952.02 1417.59 3.61 01031318 Ave 3.79 CO 8-HR Results Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 CO 8-HR ALL 1ST 387300 4610300 1382.75 0.539533 1998 CO 8-HR ALL 1ST 387266.82 4611352 1430.36 0.411376 1999 CO 8-HR ALL 1ST 387300 4610600 1400.49 0.584094 2000 CO 8-HR ALL 1ST 386552.26 4608450.55 1299.93 0.383736 2001 CO 8-HR ALL 1ST 387270.82 4610952.02 1417.59 Ave 0.450649 0.47 ATK AERMOD Results: M-225 Sc B: M-225B Source PM2.5 Emission Rate M225-B 4.5 g/s CO Emission Rate 0.5 g/s Operation Limits: CO 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) Time 1997 CO 1-HR ALL 1ST 387260.82 4611951.97 1461.87 0.37629547 97032918 1998 CO 1-HR ALL 1ST 387266.82 4611352 1430.36 0.30881813 98120216 1999 CO 1-HR ALL 1ST 387300 4610600 1400.49 0.3263392 99121416 2000 CO 1-HR ALL 1ST 385597.32 4607805.49 1297.85 0.32178667 00040118 2001 CO 1-HR ALL 1ST 387270.82 4610952.02 1417.59 0.3471296 01033018 Ave 0.34 CO 8-HR Results Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 CO 8-HR ALL 1ST 387260.82 4611951.97 1461.87 0.04703693 1998 CO 8-HR ALL 1ST 387266.82 4611352 1430.36 0.03860227 1999 CO 8-HR ALL 1ST 387300 4610600 1400.49 0.0407924 2000 CO 8-HR ALL 1ST 385597.32 4607805.49 1297.85 0.04022333 2001 CO 8-HR ALL 1ST 387270.82 4610952.02 1417.59 Ave 0.0433912 0.04 ATK AERMOD Results: M-225 Summary - N02 Source PM2.5 Emission Rate M225-A 34.0 g/s M225-B 4.5 g/s N02 Emission Rate 3.6 g/s 0.5 g/s Average 1-HR Maximum Concentration (1997-2001) Pollutant Averaging Time Group Rank Cone. (ug/m3) NAAQS (ug/m3) % of NAAQS Exceedance of NAAQS? (Y/N) N02 1-HR M225 A 1ST 3.79 189 2.01% No N02 1-HR M225 B 1ST 0.34 189 0.18% No Maximum Annual Maximum Concentration (1997-2001) Pollutant Averaging Time Group Rank Cone. (ug/m3) NAAQS (ug/m3) % of NAAQS Exceedance of NAAQS? (Y/N) N02 Annual M225 A 1ST 0.007 100 0.007% No N02 Annual M225 B 1ST 0.001 100 0.001% No ATK AERMOO Results: M-225 Sc A: M-225A Source PM2.5 Emission Rate M225-A 34.0 g/s N02 Emission Rate 3.6 g/s Operation Limits: N02 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) Time 1997 N02 1-HR ALL 1ST 387300 4610300 1382.75 4.316261 97040818 1998 N02 1-HR ALL 1ST 387266.82 4611352 1430.36 3.291007 98120216 1999 N02 1-HR ALL 1ST 387300 4610600 1400.49 4.672755 99121416 2000 N02 1-HR ALL 1ST 386552.26 4608450.55 1299.93 3.069888 00031418 2001 N02 1-HR ALL 1ST 387270.82 4610952.02 1417.59 Ave Max 3.60519 3.79 4.67 01031318 ATK AERMOD Results: M-225 Sc B: M-225B Source PM2.5 Emission Rate M225-B 4.5 g/s N02 Emission Rate 0.5 g/s Operation Limits: N02 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) Time 1997 N02 1-HR ALL 1ST 387260.82 4611951.97 1461.87 0.376295 97032918 1998 N02 1-HR ALL 1ST 387266.82 4611352 1430.36 0.308818 98120216 1999 N02 1-HR ALL 1ST 387300 4610600 1400.49 0.326339 99121416 2000 N02 1-HR ALL 1ST 385597.32 4607805.49 1297.85 0.321787 00040118 2001 N02 1-HR ALL 1ST 387270.82 4610952.02 1417.59 Ave Max 0.34713 0.34 0.38 01033018 ATK AERMOD Results: M-225 Annual Calculations Scenario A Stations 1-4 Daily Quantity (lbs) 4,500 Annual Quantity (lbs) 55,000 Days/Year 13 Max 24-HR Impact: 0.19 ug/m3 Annual Impact at 13 Days/Year: 0.007 ug/m3 Scenario B Station 1 Daily Quantity (lbs) 600 Annual Quantity (lbs) 10,000 Days/Year 17 Max 24-HR Impact: Annual Impact at 17 Days/Year: 0.02 0.001 ug/m 3 ug/m 3 ATK AERMOD Results: M-225 Summary - PM10 Source PM2.5 Emission Rate M225-A 34.0 g/s M225-B 4.5 g/s PM10 Emission Rate 68.0 g/s 9.1 g/s Average 1-HR Maximum Concentration (1997-2001) Pollutant Averaging Time Group Rank Cone. (ug/m3) PM10 1-HR M225 A 1ST 71.08 PM10 1-HR M225 B 1ST 6.30 Maximum 24-HR Concentration (1997-2001) Pollutant Averaging Time Group Rank Cone. (ug/m3) NAAQS (ug/m3) % of NAAQS Exceedance of NAAQS? (Y/N) PM10 PM10 24-HR 24-HR M225_A M225 B 1ST 1ST 3.65 0.29 150 150 2.43% 0.20% No No ATK AERMOD Results: M-225 Sc A: M-225A Source PM2.5 Emission Rate PM10 Emission Rate M225-A 34.0 g/s 68.0 g/s Operation Limits: PM10 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) Time 1997 PM10 1-HR ALL 1ST 387300 4610300 1382.75 80.9299 97040818 1998 PM10 1-HR ALL 1ST 387266.82 4611352 1430.36 61.70638 98120216 1999 PM10 1-HR ALL 1ST 387300 4610600 1400.49 87.61416 99121416 2000 PM10 1-HR ALL 1ST 386552.26 4608450.55 1299.93 57.5604 00031418 2001 PM10 1-HR ALL 1ST 387270.82 4610952.02 1417.59 67.59732 01031318 Ave 71.08 PM10 24-HR Results Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 PM10 24-HR ALL 1ST 387300 4610300 1382.75 3.37 1998 PM10 24-HR ALL 1ST 387266.82 4611352 1430.36 2.57 1999 PM10 24-HR ALL 1ST 387300 4610600 1400.49 3.65 2000 PM10 24-HR ALL 1ST 386552.26 4608450.55 1299.93 2.40 2001 PM10 24-HR ALL 1ST 387270.82 4610952.02 1417.59 Max 2.82 3.65 ATK AERMOD Results: M-225 Sc B: M-225B Source PM2.5 Emission Rate PM10 Emission Rate M225-B 4.5 g/s 9.1 g/s Operation Limits: PM10 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) Time 1997 PM10 1-HR ALL 1ST 387260.82 4611951.97 1461.87 7.05554 97032918 1998 PM10 1-HR ALL 1ST 387266.82 4611352 1430.36 5.79034 98120216 1999 PM10 1-HR ALL 1ST 387300 4610600 1400.49 6.11886 99121416 2000 PM10 1-HR ALL 1ST 385597.32 4607805.49 1297.85 6.0335 00040118 2001 PM10 1-HR ALL 1ST 387270.82 4610952.02 1417.59 6.50868 01033018 Ave 6.30 PM10 24-HR Results Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 PM10 24-HR ALL 1ST 387260.82 4611951.97 1461.87 0.29 1998 PM10 24-HR ALL 1ST 387266.82 4611352 1430.36 0.24 1999 PM10 24-HR ALL 1ST 387300 4610600 1400.49 0.25 2000 PM10 24-HR ALL 1ST 385597.32 4607805.49 1297.85 0.25 2001 PM10 24-HR ALL 1ST 387270.82 4610952.02 1417.59 Max 0.27 0.29 ATK AERMOD Results: M-225 Summary - PM2.5 Source PM2.5 Emission Rate M225-A 34.0 g/s M225-B 4.5 g/s Average 1-HR Maximum Concentration (1997-2001) Pollutant PM2.5 PM2.5 Averaging Time 1-HR 1-HR Group M225 A M225 B Rank 1ST 1ST Cone. (ug/m3) 35.54 3.15 Average 24-HR Maximum Concentration (1997-2001) Pollutant Averaging Time Group Rank Cone. (ug/m3) NAAQS (ug/m3) % of NAAQS Exceedance of NAAQS? (Y/N) PM2.5 24-HR M225 A 1ST 1.48 35 4.23% No PM2.5 24-HR M225 B 1ST 0.13 35 0.38% No Average Annual Maximum Concentration (1997-2001) Pollutant Averaging Time Group Rank Cone. (ug/m3) NAAQS (ug/m3) % of NAAQS Exceedance of NAAQS? (Y/N) PM2.5 PM2.5 Annual Annual M225_A M225 B 1ST 1ST 0.05 0.01 12 12 0.44% 0.05% No No ATK AERMOD Results: M-225 Sc A: M-225A Source PM2.5 Emission Rate M225-A # 34.0 g/s Operation Limits: PM2.5 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) Time 1997 PM2.5 1-HR ALL 1ST 387300 4610300 1382.75 40.46495 97040818 1998 PM2.5 1-HR ALL 1ST 387266.82 4611352 1430.36 30.85319 98120216 1999 PM2.5 1-HR ALL 1ST 387300 4610600 1400.49 43.80708 99121416 2000 PM2.5 1-HR ALL 1ST 386552.26 4608450.55 1299.93 28.7802 00031418 2001 PM2.5 1-HR ALL 1ST 387270.82 4610952.02 1417.59 Ave 33.79866 35.54 01031318 PM2.5 24-HR Results Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 PM2.5 24-HR ALL 1ST 387300 4610300 1382.75 1.69 1998 PM2.5 24-HR ALL 1ST 387266.82 4611352 1430.36 1.29 1999 PM2.5 24-HR ALL 1ST 387300 4610600 1400.49 1.83 2000 PM2.5 24-HR ALL 1ST 386552.26 4608450.55 1299.93 1.20 2001 PM2.5 24-HR ALL 1ST 387270.82 4610952.02 1417.59 Ave 1.41 1.48 ATK AERMOD Results: M-225 Sc B: M-225B Source PM2.5 Emission Rate M225-B 4.5 g/s Operation Limits: PM2.5 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 PM2.5 1-HR ALL 1ST 387260.82 4611951.97 1461.87 3.52777 1998 PM2.5 1-HR ALL 1ST 387266.82 4611352 1430.36 2.89517 1999 PM2.5 1-HR ALL 1ST 387300 4610600 1400.49 3.05943 2000 PM2.5 1-HR ALL 1ST 385597.32 4607805.49 1297.85 3.01675 2001 PM2.5 1-HR ALL 1ST 387270.82 4610952.02 1417.59 3.25434 Ave 3.15 PM2.5 24-HR Results Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 PM2.5 24-HR ALL 1ST 387260.82 4611951.97 1461.87 0.15 1998 PM2.5 24-HR ALL 1ST 387266.82 4611352 1430.36 0.12 1999 PM2.5 24-HR ALL 1ST 387300 4610600 1400.49 0.13 2000 PM2.5 24-HR ALL 1ST 385597.32 4607805.49 1297.85 0.13 2001 PM2.5 24-HR ALL 1ST 387270.82 4610952.02 1417.59 Ave 0.14 0.13 ATK AERMOD Results: M-225 Annual Calculations Scenario A Stations 1-4 Daily Quantity (lbs) 4,500 Annual Quantity (lbs) 55,000 Days/Year 13 Max 24-HR Impact: 1.48 ug/m3 Annual Impact at 13 Days/Year: 0.05 ug/m3 Scenario B Station 1 Daily Quantity (lbs) 600 Annual Quantity (lbs) 10,000 Days/Year 17 Max 24-HR Impact: 0.13 ug/m3 Annual Impact at 17 Days/Year: 0.01 ug/m3 ATK AERMOD Results: M-225 Summary -S02 Source PM2.5 Emission Rate M225-A 34.0 g/s M225-B 4.5 g/s S02 Emission Rate 0.3 g/s 0.04 g/s Average 1-HR Maximum Concentration (1997-2001) Pollutant Averaging Time Group Rank Cone. (ug/m3) NAAQS (ug/m3) % of NAAQS Exceedance of NAAQS? (Y/N) S02 1-HR M225 A 1ST 0.30 195 0.15% No S02 1-HR M225 B 1ST 0.03 195 0.01% No Averaga 3-HR Maximum Concentration (1997-2001) Pollutant Averaging Time Group Rank Cone. (ug/m3) NAAQS (ug/m3) % of NAAQS Exceedance of NAAQS? (Y/N) S02 3-HR M225 A 1ST 0.10 1300 0.01% No S02 3-HR M225 B 1ST 0.01 1300 0.00% No ATK AERMOD Results: M-225 ScA: M-225A Source PM2.5 Emission Rate M225-A 34.0 g/s S02 Emission Rate 0.3 g/s Operation Limits: S02 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 S02 1-HR ALL 1ST 387300 4610300 1382.75 0.337208 1998 S02 1-HR ALL 1ST 387266.82 4611352 1430.36 0.25711 1999 S02 1-HR ALL 1ST 387300 4610600 1400.49 0.365059 2000 S02 1-HR ALL 1ST 386552.26 4608450.55 1299.93 0.239835 2001 S02 1-HR ALL 1ST 387270.82 4610952.02 1417.59 0.281656 Ave 0.30 S02 3-HR Results Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 S02 3-HR ALL 1ST 387300 4610300 1382.75 0.112403 1998 S02 3-HR ALL 1ST 387266.82 4611352 1430.36 0.085703 1999 S02 3-HR ALL 1ST 387300 4610600 1400.49 0.121686 2000 S02 3-HR ALL 1ST 386552.26 4608450.55 1299.93 0.079945 2001 S02 3-HR ALL 1ST 387270.82 4610952.02 1417.59 Ave 0.093885 0.10 ATK AERMOD Results: M-225 Sc B: M-225B Source PM2.5 Emission Rate M225-B 4.5 g/s S02 Emission Rate 0.04 g/s Operation Limits: S02 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 S02 1-HR ALL 1ST 387260.82 4611951.97 1461.87 0.029398 1998 S02 1-HR ALL 1ST 387266.82 4611352 1430.36 0.024126 1999 S02 1-HR ALL 1ST 387300 4610600 1400.49 0.025495 2000 S02 1-HR ALL 1ST 385597.32 4607805.49 1297.85 0.02514 2001 S02 1-HR ALL 1ST 387270.82 4610952.02 1417.59 0.02712 Ave 0.03 502 3-HR Results Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1997 S02 3-HR ALL 1ST 387260.82 4611951.97 1461.87 0.009799 1998 S02 3-HR ALL 1ST 387266.82 4611352 1430.36 0.008042 1999 S02 3-HR ALL 1ST 387300 4610600 1400.49 0.008498 2000 S02 3-HR ALL 1ST 385597.32 4607805.49 1297.85 0.00838 2001 S02 3-HR ALL 1ST 387270.82 4610952.02 1417.59 Ave 0.00904 0.01 Air Toxics ATK Air Toxics Analysis: Utah Acute 1-hr TSL M136A and M225A Maximum PM2.5 Emission Factor = 6.00E-02 (Table 2-5, Tetratech 2012 Protocol, includes background cone) lb/lb Reactive Waste Scenario Reactive Waste (lbs) PM2.5 Emission Rate (lb/event) (Ib/hr) (g/s) M136 Scenario A-Total OB 122,000 7320 0 7320.0 M225 Scenario A - OB 4,500 AERMOD RESULTS Operation Limits: M-136A: PM2.5 1-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Averaging Time Group Easting (X) (m) Northing (Y) (m) Elevation (m) Cone. (ug/m3) M136A 1472.66 97032918 1344.98 685.72261 PM2 S 1454.41 620.19215 2000 4616770.93 1506 33 600.11 M-225A: PM2.5 1-HR Results Year Pollutant Averaging Time Group Rank Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) 1-HR M225A 1382.75 40 46495 1ST 4610952.02 1417.59 Ave 35.54 AIR TOXICS RESULTS Air Toxics- Emission Rates ]/lb Reactive Wast Isophorone Formaldehyde Hydrogen Chloride (HCI) Hydrogen Cyanide (HC) 1,2,4,-Tnchlororbenzene2 5.50E-07 1.80E-02 1.30E-06 Scenario M136A Emission Rate (lb/event) 0 1 (Ib/hr) 0.1 (g/s) Scenario M225A Emission Rate (lb/event) 0.002 0.01 (Ib/hr) 81.0 (g/s) 1. Max EF referenced from Table 2-5, Tetratech 2012 Protocol, includes background cone. 2. Used Max EF for 1,2,4,-Tnchlororbenzene. Two different emission rates were listed in Table 2-5. Air Toxics: Toxic Screening Level Analysis Acute 1-hr TSL Value ug/m3 Scenario M136A ug/m3 % of TSL Exceed TSL? (Y/N) Scenario M225A 1-HR Cone ug/m3 % of TSL Exceed TSL? (Y/N) Total (M136Aand M225A) 1-HR Cone ug/m3 % ofTSL Exceed TSL? (Y/N) Isophorone 2,826 0 006 Formaldehyde Hydrogen Chloride (HCI) Hydrogen Cyanide (HC) 1,2,4,-Tnchlororbenzene 3,711 ATK Air Toxics Analysis: Utah Chronic 24-hr TSL M136A and M225A Maximum PM2 S Emission Factor = 6 00E-02 (Table 2-5, Tetratech 2012 Protocol, includes background cone) lb/lb Reactive Waste Reactive Waste (lbs) PM2.5 Emission Rate (lb/event) (Ib/hr) (g/s) M136 Scenario A-Total OB 7320.0 M225 Scenario A - OB 4,500 AERMOD RESULTS Operation Limits: M-136A: PM2 5 24-HR Results CI >= 500 Hours: Between 10-18 1.34 m/s <= WS<= 6.71 m/s Specific release height based on wind speed and stability Averaging Time Group Easting (X) (m) Northing (Y) (m) Base Elevation (m) Cone. (ug/m3) M136A M-225A: PM2.5 24-HR Results Averaging Time Group Easting (X) M Northing (Y) (m) Base Elevation (n Cone (ug/m3) M225A AIR TOXICS RESULTS Air Toxics: Emission Rates Max EF* (lb/lb Reactive Waste) Scenario M136A Emission Rate (Ib/eventl (Ib/hr) (g/s) Scenario M225A Emission Rate (lb/event) (Ib/hr) (g/s) 1,4-Dichlorobenzene 7.30E-07 8.91E-02 2,4-Dinitrotoluene 1,1,2-Trichloroethane 1,4-Dioxane Acrylonitnle Benzene Carbon Tetrachloride Chlorobenzene Chloroform cis-l,3-Dichloropropene Cumene Styrena Toluene Vinyl Chloride Antimony Manganese Mercury Nickel Phosphorus Selenium 1. Max EF referenced from Table 2-5, Tetratech 2012 Protocol, includes background cone. 2. Used Max EF for 1,4-Dichlorobenzana. Two different emission rates were listed in Table ATK Air Toxics Analysis: Utah Chronic 24-hr TSL M136A and M225A Air Toxics: Toxic Screening Level Analysis Air Toxic Chronic 24-hr TSL Value ug/m3 Scenario M136A ug/m3 Exceed TSL? (Y/N) Scenario M225A ug/m3 Exceed TSL? (Y/N) Total (M136A and M225A) 24-HR Cone ug/m3 % of TSL Exceed TSL? (Y/N) 1,4-Dichlorobenzene 3.22E-04 2,4-Dinitrotoluene 1,1.2-Tnchloroethane 1,3-Butadiene 1,4-Dioxane Acrylonitnle Benzene Carbon Tetrachloride Chloro benzene cis-l,3-Dichloropropene Styrene Vinyl Chloride Antimony Arsenic Cobalt Manganese Mercury Nickel Phosphorus Selenium Attachment 4 Modeling Inputs/Outputs See Attached Flash Drive Attachment 5 Summary of ADFs for the Risk Assessment See Attached Flash Drive There is a Non-uploadable CD / Portable Drive / Other Device associated with this document. Please see the facility file for the CD / Portable Drive / Other Device.