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HomeMy WebLinkAboutDSHW-2013-002018 - 0901a068803515edFebruary 22, 2013 8200-FY13-065 Division of Solid and Hazardous Waste Mr. Scott T. Anderson, Director p£g ^ 2 2013 Utah Department of Environmental Quality 0 D\rZ. —rv\n A. Division of Solid and Hazardous Waste /-Ul Z) CAJ/U)\(0 195 North 1950 West P.O. Box 144880 Salt Lake City, Utah 84114-4880 Re: ATK Launch Systems Inc. EPA ID number UTD009081357 Addendum to Air Dispersion Modeling Protocol for Open Burning and Open Detonation Treatment Units Dear Mr. Anderson: ATK Launch Systems Inc. ("ATK") has finalized the AERMOD Hybrid Modeling Protocol Addendum (enclosed) for the open burning and open detonation (OBOD) treatment facilities as requested in your January 24, 2013 letter. The AERMOD Hybrid modeling results will be used to conduct the Human Health Risk Assessments for our OBOD operations. Also enclosed is a CD containing the missing OBODM model input/output files for peak concentrations and annual gravitation deposition results for the discrete and general grid receptors from the July 24, 2012 OBODM modeling report. Due to the size of these modeling files, they were stored in two different locations and were inadvertently missed in the submittal of the modeling report in July 2012. If you have any questions, please contact Blair Palmer at (435) 863-2430 or me at (801) 251-4643. Sincerely, Robert Ingersoll Director, Environmental Services ATK Launch Systems Inc. cc: JeffVandel ADDENDUM Solid AIR DISPERSION MODELING PROTOCOL FOR OPEN BURNING AND OPEN DETONATION AT ATK LAUNCH SYSTEMS IN PROMONTORY, UTAH Prepared for. Utah Department of Environmental Quality Division of Solid and Hazardous Waste Prepared by: CB&I 1401 Enclave Parkway, Suite 250 Houston, Texas 77077 Project No. 146690 February 2013 Table of Contents List of Tables iii List of Attachments iii List of Acronyms & Abbreviations iv 1.0 Introduction 1 2.0 Modeling Scenarios 3 2.1 M-136 Burn Stations 3 2.2 M-225 Burn Stations 3 2.3 Operating Restrictions 3 3.0 Source Input Parameters 4 3.1 Emission Rate 4 3.1.1 M-136 Stations 4 3.1.2 M-225 Stations 5 3.2 Release Height of Vapor Cloud 5 3.2.1 Open Burning 5 3.2.2 Open Detonation 6 3.3 Initial Dimensions of Vapor Cloud 6 3.3.1 Open Burning 6 3.3.2 Open Detonation 6 3.4 Other Source Parameters 7 3.4.1 M-136 Stations 7 3.4.2 M-225 Stations 8 4.0 AERMOD Input Data Processing 9 4.1 Meteorological Data Processing 9 4.2 Land Use and Surface Characteristics 9 4.3 Terrain Data Processing 10 4.4 Receptor Grids 10 5.0 Compliance Demonstration for Ambient Impacts 11 5.1 Design Model Value Determination 11 5.2 Background Concentration 13 5.3 NAAQS Compliance Demonstration 13 5.4 Air Toxics Compliance Demonstration 15 6.0 Risk Assessment Input Data 17 6.1 Receptor Locations 17 6.2 Pollutant Phases 18 6.3 1 -Hour ADF for Concentration 18 6.4 Annual ADF for Concentration 19 6.5 Annual ADF for Deposition 19 7.0 Receptor Grid 20 8.0 Report 21 Attachments Addendum Air Dispersion Modeling Protocol II ATK Launch Systems Promontory. Utah List of Tables Table 2-1 Source Parameters for Open Burns Table 2-2 Source Parameters for Open Detonations Table 4-1 Criteria Pollutants Considered in NAAQS Compliance Demonstration Table 4-2 Acute Air Toxics and TSLs Table 4-3 Chronic Air Toxics and TSLs List of Attachments Attachment 1 Summary of Screened Hours Attachment 2 Typical Cloud Height Calculation Addendum Air Dispersion Modeling Protocol III ATK Launch Systems Promontory. Utah List of Acronyms & Abbreviations u g/m3 micrograms per cubic meter ADFs air dispersion factors ATK ATK Launch Systems CST Central Standard Time km kilometer(s) lbs pounds MEI maximum exposed individual mph miles per hour NAAQS National Ambient Air Quality Standard NO2 nitrogen dioxide OB open burning OBODM Open Burn Open Detonation Model OD open detonation PG Pasquill-Gifford PM-10 Particulate matter with aerodynamic diameter of 10 microns or less PM-2.5 Particulate matter with aerodynamic diameter of 2.5 microns or less ppb parts per billion SO2 sulfur dioxide TSL Toxic Screening Level UDSHW Utah Department of Environmental Quality, Division of Solid and Hazardous Waste USGS United States Geological Survey Addendum Air Dispersion Modeling Protocol IV ATK Launch Systems Promontory, Utah 1.0 Introduction ATK Launch Systems (ATK), located 30 miles west of Brigham City, Utah, currently operates open burning (OB) and open detonation (OD) units for the treatment of hazardous waste propellants and propellant-contaminated materials. These treatment units are M-136 and M-225 and are subject to Resource Conservation and Recovery Act, 40 CFR 264, Subpart X permitting requirements for miscellaneous treatment units. The Utah Department of Environmental Quality, Division of Solid and Hazardous Waste (UDSHW) is requiring ATK to conduct human health and ecological risk assessments in support of a new Subpart X permit application. Before the human health and ecological risk assessments can be conducted, an air dispersion modeling analysis must be performed to evaluate the air quality impact of the M-136 and M-225 treatment units. The results of the air dispersion modeling analysis will be input into human health and ecological risk assessment models to determine the risk from the ATK OB/OD treatment units. This document provides a discussion of the protocol that will be used to conduct the modeling analysis. ATK submitted a preliminary air dispersion modeling draft report for the OB/OD treatment units in March 2012. UDSHW made several comments on that report in a letter dated May 29, 2012. This protocol is revised based on several subsequent discussions with the UDSHW. The preliminary modeling was conducted using the Open Burn Open Detonation Model (OBODM) per approved protocol. OBODM is specifically designed to predict the air quality impact of OB and OD treatment of obsolete weapons, solid rocket propellants, and associated manufacturing wastes. The OB and OD treatment of waste propellants and propellant- contaminated materials can be classified as instantaneous events for OD treatment and as quasi- continuous events for OB treatment The model is also designed to use either empirical emission factors such as those derived in the Dugway Proving Ground Bang Box™ or emissions predicted by a products of combustion model. OBODM calculates peak air concentration, time-weighted air concentrations, and dosage (time-integrated concentration) for OB and OD releases. It can also consider the effects on concentration and dosage of the gravitational settling and deposition of particulates. However, OBODM has also several limitations which constrain the modeling in this application. For example, OBODM can handle only 100 receptors at a time, cannot predict deposition in complex terrain, and uses older algorithms for downwind dispersion of emitted pollutants. To overcome these limitations, ATK proposed a hybrid approach for the air modeling using the OBODM with the AERMOD model, which is the U.S. Environmental Protection Agency's Addendum Air Dispersion Modeling Protocol 1 ATK Launch Systems Promontory, Utah (USEPA) preferred dispersion model for short range transport (up to 50 kilometers). OBODM has two distinct parts The first part simulates the OB and OD events and generates initial parameters of the emission cloud (emission rate, cloud height, cloud diameter). The second part is the downwind dispersion of the emission cloud. The main limitation of OBODM is in the second part (i.e. dispersion). The downwind dispersion is better handled by AERMOD which has practically no limitation on number of receptors, can easily handle complex terrain, and handles dispersion of emission clouds based on state-of-the-art understanding of atmospheric turbulence. Thus, the revised air quality assessment will be conducted using a hybrid approach using the emission rates and initial source parameters from OBODM and utilizing these parameters in AERMOD to predict downwind dispersion and deposition. This addendum describes the details of this hybrid modeling approach. This addendum describes only the revisions to the earlier modeling protocol for this project. All information not specifically addressed in this addendum (e.g., process description, waste characteristics) will remain the same as in the earlier protocol and has not been repeated in this addendum. Addendum Air Dispersion Modeling Protocol 2 ATK Launch Systems Promontory Utah 2.0 Modeling Scenarios The two activities in the facility will be OB and OD OB treatment is considered a quasi- continuous source because the treatment event is usually complete within one hour. OD is considered as an instantaneous source because treatment is completed within milliseconds. M-136 has 14 burn stations (1 through 14) and any one of the following alternative and mutually exclusive scenarios could occur in these stations: • Scenario M-136-A: OB in each of Burn Stations 1 through 14 • Scenario M-136-B: OB of large rocket motors in Station 14 • Scenario M-136-C: OD in Stations 13 and 14 Any one of these scenarios could occur once a day. 2.2 M-225 Burn Stations M-225 has four burn stations (1 through 4) and any one of the following alternative and mutually exclusive scenarios could occur in these stations: • Scenario M-225-A: OB in each of Burn Stations 1 through 4 • Scenario M-225-B: OD in Station 1 Any one of these scenarios could occur once a day 2.3 Operating Restrictions The following restrictions will be applied to any one of the OB and OD event scenarios: • The event will occur only between the hours 9:00 a m. Mountain Time (MT) to 6 p.m. MT • The wind speed during the event will be between 3 miles per hour (mph) and 15 mph • The Clearing Index (CI) during the events will be 500 or higher Five years of meteorological data (1997 through 2001) used in previous modeling were screened for potential operating hours considering these restrictions. The summary of screened hours is shown in Attachment 1. These hours will be modeled for the ambient impact assessment. 2.1 M-136 Burn Stations Addendum Air Dispersion Modeling Protocol 3 ATK Launch Systems Promontory, Utah 3.0 Source Input Parameters Both the OB and OD events will be modeled as elevated volume sources. The source parameters required for dispersion of volume sources are: • Emission rate • Release height of vapor cloud • Initial horizontal and vertical dimensions of the vapor cloud The methodology for determination of these source parameters based on several discussions with UDSHW is described in this section. 3.1 Emission Rate Emission rates will be estimated based on quantities of reactive waste in OB/OD events and the emission factors used in previous modeling referenced from Table 2-5 of the March 2012 modeling report Modeling to assess ambient air quality impacts will be conducted using the estimated actual emission rates for each scenario. To reduce the number of required model runs, the emission rates for a single pollutant (i e., PM-2.5) will be input to the model. The single pollutant modeling results will then be applied to the other pollutants that are part of the impact analysis by scaling the modeled results by the ratio of the desired pollutant emission rate to the modeled emission rate. However, modeling in support of the risk assessment will be conducted at a unit emission rate of 1 g/s to allow for application of pollutant-specific emission rates within the risk assessment software The reactive waste quantities for each of the scenarios will be based on the desired permit limits which are listed below. 3.1.1 M-136 Stations M-136 has 14 burn stations (1 through 14) and any one of the following alternative and mutually exclusive scenarios could occur in these stations: Scenario M-136-A • Al: OB in six of Burn Stations 1 through 12 at 16,000 pounds (lbs) in each station totaling to 96,000 lbs reactive waste weight per event • A2: 10,000 lbs reactive waste weight per event in Burn Station 13 • A3- 16,000 lbs reactive waste weight per event in Burn Station 14 Addendum Air Dispersion Modeling Protocol 4 ATK Launch Systems Promontory Utah Scenario M-136-B • B: OB of 125,000 lbs of large rocket motors in Station 14 Scenario M-136-C • C: OD of 600 lbs reactive waste in Stations 13 and 14 each, totaling to 1,200 lbs reactive waste weight per event 3.1.2 M-225 Stations M-225 has four burn stations (1 through 4) and any one ofthe following alternative and mutually exclusive scenarios could occur in these stations: Scenario M-225-A • A OB of 1,125 lbs of reactive waste in each of the Burn Stations 1 through 4 for a total of 4,500 lbs reactive waste weight per event Scenario M-225-B • B: OD of 600 lbs of reactive waste in Station 1 3.2 Release Height of Vapor Cloud 3.2.1 Open Burning Open burning results in combustion of the energetics and rapid rise of the hot combustion products due to buoyancy until a final height is reached. At this point, the emission cloud has no upward momentum and starts to disperse downwind. This event will be simulated as an elevated volume source with the release height equal to the final cloud height predicted from OBODM. Based on several discussions with UDSHW and its consultant, the following approach will be used for determination of cloud heights for OB events. All of the unrestricted hours (i.e., the hours that meet the operating restriction described in Section 2.3) will be grouped based on wind speed and stability condition. The wind speeds will be grouped in five ranges as identified below: • Category 2: 3.0 mph - 5.0 mph • Category 2: 5.0 mph - 7.5 mph • Category 3: 7 5 mph - 10.0 mph • Category 4: 10.0 mph - 12.5 mph • Category 5- 12 5 mph - 15 mph Atmospheric stabilities will be grouped in six Pasquill-Gifford (PG) atmospheric stability classes for each of the hours in each of the wind speed categories listed above. Addendum Air Dispersion Modeling Protocol 5 ATK Launch Systems Promontory, Utah The OBODM will be used to determine the vapor cloud height for each combination of the PG atmospheric stability class and wind speed categories. The vapor cloud heights will be determined for the lower threshold, the higher threshold, and midpoint for each wind speed category. To ensure conservative impact assessment, the minimum cloud height out of these three wind speeds will be considered for each combination of atmospheric stability and wind speed category. Attachment 2 shows an example for the cloud height calculation. The procedure outlined here for determining the vapor cloud heights specific to meteorological conditions will be conducted for each of the scenarios proposed for representing the OB/OD events. In the case of scenarios that consider simultaneous events at multiple burn stations, only one representative burn station will be modeled in OBODM for each scenario The resulting vapor cloud height will then be applied to each of the other identical burn stations for that scenario. 3.2.2 Open Detonation The same procedure described for open burning will be used for determination of vapor cloud height for OD using the OBODM. 3.3 Initial Dimensions of Vapor Cloud 3.3.1 Open Burning During rapid rise of the cloud from the OB, atmospheric air is entrained and the dimension of the cloud increases. Based on videos of the open burning events, the final dimensions of the cloud at final plume height are typically four to eight times larger than the dimension of the burn pans. As a conservative estimate, the cloud diameter will be based on four times the equivalent diameter of the burn pans. Because the burn stations have multiple adjacent burn pans, the equivalent diameter will be based on the total area covered by the reactive wastes. It is assumed that the vapor cloud plume is a sphere Per AERMOD model guidance, the initial vertical and horizontal dimensions of an elevated volume source, such as the vapor cloud, will be calculated by dividing the initial cloud diameter (i.e., four times equivalent diameter covered by reactive wastes on burn pans) by a factor of 4.3. 3.3.2 Open Detonation The initial dimension of the vapor cloud will be obtained directly from the OBODM for each combination of wind speed category and atmospheric stability. Per AERMOD model guidance, the initial vertical and horizontal dimensions of an elevated volume source such as the vapor cloud will be calculated by dividing the initial vapor cloud diameter by a factor of 4.3. Tables 2-1 and 2-2 show the summary of the derivation of the source parameters for OBs and OD for dispersion modeling with AERMOD Addendum Air Dispersnn Modeling Protocol 6 ATK Launch Systems Promontory, Utah Table 2-1: Source Parameters for Open Burns Parameter Derivation Source Type Elevated volume source Emission Rate Based on proposed reactive waste quantities and emission factors used in previous modeling Release Height Calculated for each combination of wind speed category and atmospheric stability for the unrestricted hours using OBODM Initial Vapor Cloud Diameter Based on four times total area covered by reactive wastes in burn pans Initial Sigma Y Calculated by dividing initial vapor cloud diameter by 4.3 Initial Sigma Z Calculated by dividing initial vapor cloud diameter by 4.3 Table 2-2: Source Parameters for Open Detonation Parameter Derivation Source Type Elevated volume source Emission Rate Based on proposed reactive waste quantities and emission factors used in previous modeling Release Height Calculated for each combination of wind speed category and atmospheric stability for the unrestricted hours using OBODM Initial Vapor Cloud Diameter Calculated for each combination of wind speed category and atmospheric stability for the unrestricted hours using OBODM Initial Sigma Y Calculated by dividing initial vapor cloud diameter from OBODM by 4.3 Initial Sigma Z Calculated by dividing initial vapor cloud diameter from OBODM by 4.3 3.4 Other Source Parameters 3.4.1 M-136 Stations Burn Stations 1 through 12 are clustered within 100 meters of each other. Six of the 12 stations located closest to the western property line (Stations 1, 4, 7, 8, 10, and 11) will be modeled as six separate sources. Burn Stations 13 and 14 will be modeled separately. From previous modeling and from burn information provided by the facility, the following assumptions will be made: • Burn Stations 1 through 12 each consist of 4 adjacent burn pans. The average dimension of each burn pan is 8 feet by 13 feet, and the burn pan layout per station is approximated as an area of 16 feet by 26 feet • Burn Station 13 consists of 2 adjacent burn pans The average dimension of each pan is 6 feet by 9 feet, and the burn pan layout for this station is approximated as an area of 9 feet by 12 feet. Addendum Air Dispersion Modeling Protocol 7 ATK Launch Systems Promontory, Utah • Burn Station 14 consists of 4 adjacent burn pans. The average dimension of each burn pan is 8 feet by 13 feet, and the burn pan layout for this station is approximated as an area of 16 feet by 26 feet. • Dimension of the rocket motor burn area at Burn Station 14 assumed to be 5 feet by 50 feet • The height of burn stations = 1.0 meter • The detonation will be started at ground level 3.4.2 M-225 Stations Burn Stations 1 through 4 are clustered within 100 meters and will be modeled as a single source located approximately at the center of the cluster. The OD pit will be modeled separately. From previous modeling and from burn information provided by the facility, the following assumptions will be made: • Burn Stations 1 through 4 each consist of one burn pan, having an average pan dimension of 6 feet by 17 feet • The height of burn stations = 1.0 meter • The detonation will be started at ground level Addendum Air Dispersion Modeling Protocol 8 ATK Launch Systems Promontory, Utah 4.0 AERMOD Input Data Processing The latest version of USEPA's AERMOD model (version 12345) will be used for estimating concentration and deposition of the vapor cloud on downwind receptors. AERMOD requires processing of several key input parameters. These are discussed in this section. 4.1 Meteorological Data Processing Five years (1997 through 2001) of on-site meteorological data obtained from the site have been used in previous modeling. The same meteorological data will be used after reprocessing the data for AERMOD using the latest version of the preprocessor, AERMET (version 12345). Non-urban (l e., rural) land use determined from previous modeling will be used in AERMET. The five years (1997 through 2001) of on-site hourly meteorological data will be obtained from the site in CD-144 format and will include wind speed, wind direction, temperature, and barometric pressure monitored at the site along with concurrent ceiling height and opaque cloud cover from Hill Air Force Base. Twice daily upper air data for Salt Lake City will be obtained in Forecast Systems Laboratory (FSL) format from the National Oceanic and Atmospheric Administration, Earth System Research Laboratory (NOAA/ESRL) Radiosonde Database. The hourly surface meteorological observations will then be used along with the twice daily Salt Lake City upper air data in the AERMET pre-preprocessor to develop surface and vertical profile meteorological data bases for use in AERMOD. This processing will be conducted in accordance with the latest USEPA AERMOD Implementation Guide dated March 19, 2009. 4.2 Land Use and Surface Characteristics The surface characteristics to be used in processing the meteorological data in AERMET will be developed using the EPA AERSURFACE program. The AERSURFACE program requires the input of digital land cover data from the U.S. Geological Survey (USGS) National Land Cover Data 1992 archives (NLCD92), which it uses to determine the land cover types for the user- specified location. AERSURFACE matches the NLCD92 land cover categories to seasonal values of albedo, Bowen ratio, and surface roughness. Values of surface characteristics are calculated based on the land cover data for the area surrounding the site of the surface meteorological data collection. For this application, the land use data will be obtained for the area surrounding the ATK Launch Systems site and will be used in AERSURFACE to generate values of albedo, Bowen ratio, and surface roughness as a function of the four seasons (I e. winter, spring, summer, and fall) and for each of six 60-degree directional sectors. This approach of generating surface characteristics at the site of the surface meteorological data collection is consistent with the latest EPA guidance (i.e., AERMOD Implementation Guide dated March 19, 2009, Ref. 7.7). Addendum Air Dispersion Modeling Protocol 9 ATK Launch Systems Promontory, Utah The specific inputs and assumptions used in the AERSURFACE runs are as follows • Center Latitude (decimal degrees): 41.854 • Center Longitude (decimal degrees): -112.432 • Datum: NAD83 • Study radius (km) for surface roughness: 1.0 • Airport? No • Continuous snow cover? No • Surface moisture9 Dry • Arid region? Yes • Month/Season assignments? Default • Late autumn after frost and harvest, or winter with no snow 12 1 2 • Winter with continuous snow on the ground: 0 • Transitional spring (partial green coverage, short annuals): 3 4 5 • Midsummer with lush vegetation: 6 7 8 • Autumn with unharvested cropland 9 10 11 4.3 Terrain Data Processing Terrain data processing will occur for all sources and receptors. The terrain data will be processed using AERMOD's terrain data preprocessor, AMS/EPA Regulatory Model Terrain Pre-processor (AERMAP). Using AERMAP, the base elevation and hill height scale values will be determined for each receptor and source. The digital terrain data will be obtained from the 1 arc second NED provided by the United States Geological Survey's (USGS) The National Map Viewer. 4.4 Receptor Grids For NAAQS and air toxics analysis, an offsite receptor grid will be used to determine the maximum off-site ground-level concentrations. The layout of the receptors will be as follows: Discrete receptors will be placed along the property fence line at 100-meter (m) intervals. A Cartesian receptor grid starting from the property line will extend up to 10 km in all directions. This Cartesian receptor grid will spaced at 100-m intervals to a distance of 3 km from the facility and at 500-m intervals between 3 km and 10 km from the facility. As mentioned in Section 4.3, the terrain data for each receptor will be processed using AERMOD's terrain data preprocessor, AERMAP Using AERMAP, the base elevation and hill height scale values will be determined for each receptor. The digital terrain data will be obtained froml arc second NED. Addendum Air Dispersion Modeling Protocol 10 ATK Launch Systems Promontory. Utah 5.0 Compliance Demonstration for Ambient Impacts Compliance demonstration for ambient impact will include: • Ensuring that the NAAQS for criteria pollutants are not exceeded at any public receptor on the site boundary and beyond • Ensuring that the TSLs are not exceeded at any public receptor on the site boundary and beyond This section describes the methodology for demonstration compliance with these two ambient impact criteria. 5.1 Design Model Value Determination NAAQS compliance will be demonstrated by comparing the design modeled concentration for all pollutants and averaging times with the respective NAAQS. The criteria pollutants to be considered for NAAQS analysis, the averaging time, and design values are shown in Table 5-1 Table 5-1: Criteria Pollutants Considered in NAAQS Compliance Demonstration Criteria Pollutant NAAQS averaging time Design Concentration Method of Determination of Design Value PM-10 24-hour 150 |ig/m3 6th highest of 5 years of meteorological data PM-2 5 24-hour 35 ug/m3 Average of first highest of 5 years of meteorological data PM-2 5 Annual 15 ug/m3 Average of first highest of 5 years of meteorological data S02 1-hour 75 ppb (195 ug/m3) 5-year average of the 99th percentile (4th highest) of the annual distribution of daily maximum 1-hour average concentrations S02 3-hour 1,300 ug/m3 5-year average of 2nd highest (not to be exceeded once per year) N02 1-hour 100 ppb (189 ug/m3) 5-year average of the 98th percentile (8th highest) of the annual distribution of daily maximum 1-hour average concentrations N02 Annual 100 ug/m3 Maximum over 5 years of meteorological data Notes i) Annual PM-10 NAAQS has been revoked, n) 24-hour and annual SO2 NAAQS has been revoked, 111) CO and Lead NAAQS are not included because previous modeling showed compliance with NAAQS (or both pollutants Maximum 1-Hour Impact AERMOD will be used to calculate the maximum 1-hour average impact over each year of five years of meteorological data covering all of the unrestricted hours of operation. This is the maximum 1-hour average concentration for the OB/OD operations in any day of the year for Addendum Air Dispersion Modeling Protocol 11 ATK Launch Systems Promontory, Utah each of the five years. These five 1-hour average impacts for the five years will be averaged to obtain the five-year average maximum 1-hour impact. Maximum 3-Hour and 24-Hour Impacts Because only one hour of OB/OD events will occur in any day (and there is no impact during the remainder of the day), the maximum values of 3-hour and 24-hour averages will be also based on the 1-hour maximum value. For example, the maximum 24-hour average concentration in any year will be calculated by dividing the maximum 1-hour concentration for that year by a factor of 24 as shown below Where: Max24-hr Maxl-hr Max24-hr = Max 1-hr 24 = Maximum 24-hour average concentration in \ig/m = Maximum 1-hour average concentration in ug/m3 Similarly, for the maximum 3-hour concentrations, the maximum 1-hour average is divided by 3. The maximum 3-hour and 24-hour averages for each of the five years will be averaged to obtain the five-year average value for each short-term averaging time. Maximum Annual Impact The annual total OB and OD quantities are restricted by permitted levels. To account for this limitation on annual OB/OD quantities, the following calculation will be used: Q Max, annual _ Q daily 8760 Where- Maxannual Qannual Qdaily lHRmax 8760 = Maximum annual average concentration in ug/m = Annual quantity of reactive wastes in OB/OD (lbs) = Daily quantity of reactive wastes in OB/OD (lbs) = Maximum 1-hour impact based on daily reactive wastes quantity = Number of hours per year Note: The term [Qannual/Qdaily] represents the total number of days per year the OB/OD events can occur to reach the annual permitted quantities. Addendum Air Dispersion Modeling Protocol 12 ATK Launch Systems Promontory, Utah This assumes that for each hour the OB/OD operations will be carried out to meet the annual quantity, the impact will be same as the maximum 1-hour determined previously. This is a conservative assumption. Each year of maximum 1-hour average impact obtained from AERMOD will be used to calculate the maximum annual impact for each year. The five maximum annual impacts will be averaged to obtain the five-year average annual impact The permitted annual reactive waste quantities for the OBOD operations are as follows. These quantities will be used as the "Qannual" in the above equation to calculate the maximum annual average concentrations. M136: Scenario Al - Open Burn in Stations 1-12: 6,720,000 lbs Scenario A2 - Open Burn in Station 13: 840,000 lbs Scenario A3 - Open Burn in Station 14: 840,000 lbs Scenario B - Large Rocket Motor in Station 14): 1,500,000 lbs Scenario C - Open Detonation in Station 13 & 14: 100,000 lbs M225: Scenario A - Open Burn in Stations 1-4' 55,000 lbs Scenario B - Open Detonation in Station 1: 10,000 lbs 5.2 Background Concentration No background concentrations will be added to the design modeled concentration because as mentioned in the protocol dated March 2011, the emission factors used for the modeling include background concentration. 5.3 NAAQS Compliance Demonstration The NAAQS compliance demonstration for each pollutant and averaging time will be as follows. 24-Hour PM-10 NAAQS The design value of NAAQS for 24-hour PM-10 NAAQS is sixth highest over five years of meteorological data Initially, the first highest 24-hour average over the five years will be compared to the NAAQS as a conservative approach If this shows exceedance of NAAQS, then the sixth highest 1-hour concentration over the five years of meteorological data will be obtained from AERMOD and will be used to determine the sixth highest 24-hour average concentration by dividing by a factor of 24. This sixth highest 24-hour average concentration will be used for comparison with the NAAQS Addendum Air Dispersion Modeling Protocol 13 ATK Launch Systems Promontory, Utah 24-Hour PM-2.5 NAAQS The design value of the 24-hour PM-2.5 NAAQS is the average of five years of highest 24-hour impact. For compliance demonstration with this NAAQS, the highest 24-hour average for all five years will be averaged and compared with the NAAQS. Annual PM-2.5 NAAQS The design value of the annual PM-2.5 NAAQS is the average of five years of highest annual impact. For compliance demonstration with this NAAQS, the highest annual average for all five years will be averaged and compared with the NAAQS. 1-Hour S02 NAAQS The design value for 1-hour SO2 NAAQS is the five-year average of the 99th percentile of the annual distribution of daily maximum 1-hour average concentrations. Initially, the five-year average of the maximum 1-hour concentration will be compared to the NAAQS as a conservative approach If this shows exceedance of NAAQS, then AERMOD will be used to calculate the fourth highest daily maximum (i.e., 99th percentile) for each year. The five fourth highest daily maximums (one for each year) will be averaged and compared with the NAAQS. 3-Hour S02 NAAQS The design value for 3-hour SO2 NAAQS is the five-year average of second highest 3-hour maximum concentrations for each year (not to be exceeded once per year). Initially, the five-year average of the maximum 3-hour concentration will be calculated by dividing the five-year average 1-hour concentration from AERMOD by a factor of 3 as described earlier. This value will be compared with the NAAQS as a conservative approach. If this shows exceedance of NAAQS, then the second highest 3-hour maximum for each year will be calculated using the same approach. The five second highest 3-hour average concentrations will be averaged and compared with the NAAQS. 1-Hour N02 NAAQS The design value for 1-hour NO2 NAAQS is the five-year average of the 98th percentile (eighth highest) of the annual distribution of daily maximum 1-hour average concentrations. Initially, the five-year average of the maximum 1-hour concentration will be compared to the NAAQS as a conservative approach. If this shows exceedance of NAAQS, then AERMOD will be used to calculate the eighth highest daily maximum (i.e., 98th percentile) for each year. The five eighth highest daily maximums (one for each year) will be averaged and compared with the NAAQS. Addendum Air Dispersion Modeling Protocol 14 ATK Launch Systems Promontory, Utah NOx emissions from OD and OBs are primarily NO, which slowly converts in the atmosphere to NO2. In addition, NO2 is titrated in the atmosphere by ground level ozone. As a screening analysis, all of NOx will be considered NO2 and atmospheric titration will not be considered. If required in a refined analysis, both of these mechanisms will be considered per USEPA's established procedure and published literatures. Annual N02 NAAQS The design value of the annual NO2 NAAQS is the maximum of the highest annual impacts from each of the five years modeled. For compliance demonstration with this NAAQS, the highest annual average from an individual year will be compared with the NAAQS. 5.4 Air Toxics Compliance Demonstration Acute Toxic Screening Levels Air toxics included in the preliminary modeling report dated March 2012 will be compared to respective TSLs. The acute air toxics and corresponding TSLs to be considered are listed in Table 3-18 of the March 2012 modeling report and are reproduced in Table 4-2. The five-year average of maximum 1-hour concentrations from AERMOD will be compared with these TSLs. Table 4-2: Acute Air Toxics and TSLs Pollutant Isophorone Formaldehyde Hydrogen Chloride (HCI) Hydrogen Cyanide (HC) 1,2,4,-Trichlororbenzene Utah Acute 1-hrTSL Value (ug/m3) 2,826 37 298 520 3,711 Chronic TSLs The chronic air toxics and corresponding TSLs are listed in Tables 3-35 and 3-52 of the preliminary modeling report dated March 2012 and are reproduced in Table 4-3. The five-year average of maximum 24-hour concentration will be compared with these TSLs. Table 4-3: Chronic Air Toxics and TSLs Pollutant 1,4-Dichlorobenzene 2,4-Dinitrotoluene o-Toluidine Utah Chronic 24-hr TSL Value (yg/m3) 2004 292 Addendum Air Dispersion Modeling Protocol 15 ATK Launch Systems Promontory, Utah Pollutant Phenol Utah Chronic 24-hr TSL Value (pg/m3) 642 CI2 48 1,1,2-Trichloroethane 1819 1,3-Butadiene 49 1,4-Dioxane 2402 Acryionitriie 48 Benzene 53 Bromoform 172 Carbon Tetrachloride 350 Chlorobenzene 1535 Chloroform 1628 cis-1,3-Dichloropropene Cumene Styrene Toluene Vinyl Chloride Antimony Arsenic Cadmium Chromium Cobalt Manganese Mercury Nickel Phosphorus Selenium 151 8193 2840 2512 28 17 0.33 0.02 0.11 0.77 6.7 0.33 1.11 3.3 6.7 Addendum Air Dispersion Modeling Protocol 16 ATK Launch Systems Promontory, Utah 6.0 Risk Assessment Input Data Human health and ecological risk assessment requires maximum values of 1-hour and annual average air dispersion factors (ADFs) for gas concentration, particulate concentration, gas dry deposition, and particulate dry deposition at selected discrete receptors. These ADFs will be generated using the hybrid OBODM and AERMOD models as described earlier. 6.1 Receptor Locations The ADFs will be estimated at maximum exposed individual (MEI) locations within the facility and off site. The MEI locations are the locations of maximum impact at on-site and off-site locations. The site boundary will be included in both on-site and off-site receptor grids for consistency. In addition, per previous protocol, risk assessment will be conducted at several discrete locations in and around the facility listed as follows: • The Adam's Ranch, which is the closest domestic dwelling to M-136, is located approximately 3 kilometers (km) south-southwest of M-136. • The Holmgren Ranch, which is the closest domestic dwelling to M-225, is located approximately 2 km east-southeast of M-225. • Four facility boundary receptors that are selected based on the annual prevailing wind direction measured over a five-year period (1997 through 2001) at the M-245 meteorological monitoring station • AutoLiv facility. This is an off-site commercial business located between the M-136 and M- 225 treatment units. • Christensen residence. This residential dwelling is located due north of ATK. • Blue Creek perennial stream, which runs along the western boundary of M-136. • The Bear River Migratory Bird Refuge, located about 10.5 km south-southwest of M-225. • The Salt Creek Waterfowl Management Area, located 13 km east of ATK. • The Thiokol Ranch Pond (ATK Ranch Pond), which is located approximately 14 km southwest of M-225. • The Howell Dairy Farm just north of the ATK northern property boundary. • The Town of Penrose, located approximately 7 miles southeast of M-136. • The Town of Thatcher, located approximately 7 5 miles due east of M-136. Addendum Air Dispersion Modeling Protocol 17 ATK Launch Systems Promontory, Utah • Two on-site discrete receptors to assess potential risk to ATK workers that are not directly involved with the activities at the M-136 and M-225 treatment units. The proposed new on- site receptors represent areas where most non-treatment-related employees spend their time on site The new on-site discrete receptors include the following: - North Plant Main Administration Building and Main Manufacturing Area - 2.5 miles north of M-136 and 6.7 miles north-northwest of M-225 - South Plant Main Administration Building and Main Manufacturing Area - 1.8 miles south of M-136 and 3.9 miles west-northwest of M-225. As input to the risk assessment, 1-hour average and annual average ADFs will be developed using AERMOD for the scenarios reported in Section 4.4.1.2 of the modeling protocol dated January 2012. 6.2 Pollutant Phases The following phases will be considered in estimating the ADFs at the on-site MEI, off-site MEI, and discrete receptors: • Gas phase air 1-hour and annual concentrations • Particle phase 1-hour and annual concentrations • Particle bound phase 1 -hour and annual concentrations • Gas phase annual dry deposition • Particle phase annual dry deposition • Particle bound phase annual dry deposition The ADFs will be based on unit emission rate. These ADFs will be multiplied by emission rates of specific pollutants in the risk assessment to be conducted by other consultants. Gas phase dry deposition will be determined by the AERMOD model. As detailed in the previous modeling protocol by Tetra Tech, gas dry deposition will be modeling using a conservative deposition velocity of 0.03 meters/seconds (m/s), which is the default value specified in the HHRAP (U.S.EPA, September, 2005) guidance. Mercury speciation and exposure will be applied within the risk assessment model, which follows HHRAP guidance for mercury evaluation. 6.3 1-Hour ADF for Concentration This will be determined individually for each of the operating scenarios for M-136 and M-225 using unit emission rate for emission of gaseous and particulate pollutants. Emission rate will be input to AERMOD for each hour of unrestricted operation. The maximum concentrations will Addendum Air Dispersion Modeling Protocol 18 ATK Launch Systems Promontory, Utah be determined for each year at the on-site MEI, off-site MEI, and at each of the discrete receptors and averaged to provide five-year averaged maximum 1-hour ADF values. 6.4 Annual ADF for Concentration This will be determined individually from the 1-hour ADF concentration as follows: QjmrmoL * ADF^ A DP - ^daily annual ~ Q76Q Where: ADFannual = Maximum annual average concentration in [xg/m3 Qannual = Annual quantity of reactive wastes in OB/OD (lbs) Qdaily = Daily quantity of reactive wastes in OB/OD (lbs) ADFl-hr = Maximum 1-hour ADF based on daily reactive wastes quantity 8760 = Number of hours per year Note: The term [Qannual/Qdaily] represents the total number of days per year the OB/OD events can occur to reach the annual permitted quantities. Annual ADF will be calculated for each of the five years of meteorological data at each receptor and averaged to provide five-year average annual values. 6.5 Annual ADF for Deposition The procedure will be similar to the calculation of the annual ADF for concentration. First, the 1-hour ADF for deposition will be determined and then annual ADF will be determined using the equation shown in Section 5.4 above. Physical characteristics of particulates such as mass mean diameter, size distribution, and density will be used as listed in previous deposition modeling by TetraTech. Addendum Air Dispersion Modeling Protocol 19 ATK Launch Systems Promontory Utah 7.0 Receptor Grid For NAAQS and air toxics analysis, a Cartesian receptor grid will be used starting from the boundary of the facility and extending to 10 km from M-136 and M-225 in all directions. The grid will have spacing of 100 meters up to a 3-km distance and a spacing of 500 meters between 3 km to 10 km. A similar grid will be developed for on-site MEI modeling. Terrain elevations for each receptor will be obtained from national elevation dataset files and running the preprocessor, AERMAP. Addendum Air Dispersion Modeling Protocol 20 ATK Launch Systems Promontory, Utah 8.0 Report On completion of the analysis, a report will be submitted to UDSHW which will include the following: • Background and purpose of modeling • Description of the emission source (OB/OD) • Emission rates of regulated air pollutants and air toxics • Emission source parameters • Model defaults and assumptions • Meteorological data • Receptor grid layout and discrete receptors • Compliance demonstration with NAAQS and TSLs • ADFs at on-site MEI, off-site MEI, and at selected receptors for risk assessment Electronic copies of all model input and output files will be submitted via a compact disc. Addendum Air Dispersion Modeling Protocol 21 ATK Launch Systems Promontory Utah Attachment 1 Summary of Screened Hours ATK Promontory OBOD Modeling Meteorological Data Analysis Restrictions Daytime Operations Beginning Operating Hour Last Operating Hour Clearing Index >= 10 (9 AM) 18 (6 PM) 500 Wind Speed Group M/s MPH Group 0 1 34<=WS<2 24 3-5 Group 1 2 23<=WS<3 35 5-7 5 Group 2 3 35<=WS<4 47 7 5-10 Group 3 4 47<=WS<5 59 10-12 5 Group 4 5 59<=WS<6 71 12 5-15 Unrestricted Hours Meteorological Year Atmospheric Stability 1.34<=WS<2.24 2.23<=WS<3 35 Wind Speed Groups 3.35<=WS<4.47 4.47<=WS<5 59 5.59<=WS<6.71 1997 Total 33 99 32 120 14 71 233 12 94 55 161 70 121 193 1998 Total 31 86 19 121 13 56 220 24 103 29 156 81 119 200 1999 Total 33 101 42 134 18 86 253 29 133 40 202 69 137 206 2000 Total 34 115 18 102 18 60 235 32 158 57 247 102 168 272 2001 Total 37 142 17 132 24 62 298 20 182 56 258 106 163 270 Grand Total Attachment 2 Typical Cloud Height Calculation OBODM Modeling for Plume Dimensions - M-136 Unit and M-225 Unit, ATK Promontory Wind Speed Category: 10-12.5 mph Atmospheric Stability: D (neutral) Wind Speed (mph) (m/s) Scenario Munition Quantity per Burn Station (lbs) Stability Category D Vapor Cloud Ht (m) 10 4.47 M136 Scenario A-l - OB M136 Scenar M136Scenari M136 Scenar M136 Scenar M225 Scenar M225 Scenar 16,000 o A-2 - OB 10,000 o A-3 - OB 16,000 o B-OB 125,000 oC-OD 600 o A-OB 1,125 o B-OD 600 235.5 216.4 235.5 295.7 189.7 145.7 189.7 11.25 5.03 M136 Scenar o A-l - OB 16,000 M136 Scenar o A-2-OB 10,000 M136 Scenar o A-3 - OB 16,000 M136 Scenar o B-OB 125,000 M136 Scenar oC-OD 600 M225 Scenar oA-OB 1,125 M225 Scenar o B-OD 600 223.4 202.6 223.4 289.6 189.7 147.3 189.7 12.5 5.59 M136 Scenar o A-l - OB 16,000 M136 Scenar o A-2 - OB 10,000 M136 Scenar o A-3 - OB 16,000 M136 Scenar o B-OB 125,000 M136 Scenar oC-OD 600 M225 Scenar oA-OB 1,125 M225 Scenario B - OD 600 218.5 197 218.5 287.1 189.7 132.3 189.7 Shows the minimum cloud height that will be considered in AERMOD for this combination of wind speed category and atmospheric stability. Cloud heights will be determined for other combinations of wind speed categroy and atmospheric stability using the same approach. There is a Non-uploadable CD associated with this document. Please see the facility file for the CD.