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HomeMy WebLinkAboutDSHW-2012-002300 - 0901a068802bc947u'lvision of Solid and Hazardous Waste 23 March 2012 8200-FY12-077 Mr. Scott T. Anderson, Executive Secretary State of Utah Department of Environmental Quality Division of Solid and Hazardous Waste 195 N.1950 W. P.O. Box 144880 Salt Lake City, Utah 84114-4880 Re: ATK Launch Systems-Promontory EPA ID number UTD009081357 Revised Preliminary Air Dispersion Modeling Assessment Draft Report for Open Bum and Open Detonation Treatment Units at ATK Launch Systems for Use in the Human Health and Ecological Risk Assessments Dear Mr. Anderson: Enclosed is the Revised Preliminary Air Dispersion Modeling Assessment Draft Report for the Open Burn and the Open Detonation Treatment Units at ATK Launch Systems Promontory facility. This information is necessary to conduct the Human Health and Ecological Risk Assessments for our OB/OD operations. Please contact me if you have any questions conceming this report. My telephone number is (801)699-0319 or you can contact Blair Palmer at (435)863-2430. / certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the informalion submitted. Based on my inquiry of the person or persons who manage the system, or those persons direcdy responsible for gathering ihe information, the information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. Sincerely George E.'Gooch, Manager Environmental Compliance cc: JeffVandel Division of Solid and Hazardous Waste MAR 2 3 2012 Z(XZ.-0D2SW REVISED PRELIMINARY AIR DISPERSION MODELING ASSESSMENT DRAFT REPORT FOR OPEN BURN AND OPEN DETONATION TREATMENT UNITS AT ATK LAUNCH SYSTEMS BRIGHAM CITY, UTAH MARCH 2012 TABLE OF CONTENTS MARCH 2012 Division of Solid and Hazardous Waste MAR 2 3 2012 SECTION PAGE NO. 1.0 INTRODUCTION 1-1 2.0 AIR DISPERSION MODELING PROTOCOL 2-1 2.1 TERRAIN AND SITE DESCRIPTION 2-1 2.2 TREATMENT LOCATIONS 2-1 2.2.1 M-136 Treatment Unit Description 2-2 2.2.2 M-225 Treatment Unit Description 2-2 2.3 AIR QUALITY DISPERSION MODEL SELECTION 2-3 2.3.1 Fiat and Complex Terrain Modeling 7 2-3 2.4 LAND USE ANALYSIS 2-4 2.5 SURFACE ROUGHNESS HEIGHT 2-5 2.6 OB/OD SOURCE SCENARIOS 2-5 2.7 M-136 TREATMENT QUANTITY SCENARIOS 2-7 2.8 M-225 TREATMENT QUANTITY SCENARIOS 2-7 2.9 SOURCE PARAMETERS 2-7 2.9.1 ODOBi Emissions Testing and Emission Factors 2-7 2.10 MODELING ASSUMPTIONS FOR M-136 AND M-225 2-10 2.11 DEPOSITION MODELING 2-12 2.12 RECEPTOR NETWORKS 2-14 2.12.1 General Receptor Networks 2-14 2.12.2 Discrete Receptor Network 2-15 2.13 METEOROLOGICAL DATA 2-16 2.13.1 Surface Data 2-16 2.13.2 Upper Air Observations (Mixing Height Data) 2-17 2.13.3 Meteorological Preprocessor 2-18 2.14 OBODM MODELING METHODOLOGY 2-18 2.14.1 Discrete Receptors :.2-19 2.14.2 General Grid Receptors 2-20 3.0 AIR DISPERSION MODELING RESULTS 3-1 3.1 PRESENTATION OF RESULTS 3-1 3.2 DISCRETE RECEPTORS 3-2 3.2.1 Compliance with NAAQS 3-3 3.2.2 Compliance with Utah 1-Hour Acute Gas TSLs 3-6 3.2.3 Compliance with Utah 24-Hour Chronic Gas TSLs 3-8 3.2.4 Compliance with Utah 24-Hour Chronic Particulate TSLs 3-10 3.3 GENERAL GRID MAXIMUM IMPACT RECEPTORS.. 3-12 3.3.1 Compliance with NAAQS 3-12 3.3.2 Compliance with Utah 1-Hour Acute Gas TSLs 3-12 3.3.3 Compliance with Utah 24-Hour Chronic Gas TSLs 3-12 3.3.4 Compliance with Utah 24-Hour Chronic Particulate TSLs 3-13 3.3.5 Compliance with OSHA 8-Hour TWA Criteria 3-13 3.4 UNCERTAINTY ANALYSIS 3-13 3.4.1 Uncertainties Due To Emissions Parameters 3-13 3.4.2 Uncertainties Due To Source Parameters 3-13 3.4.3 Uncertainties Due To Meteorological Parameters 3-14 3.4.4 Uncertainties Due To Particle Size 3-14 3.4.5 Uncertainty Due To OBODM 3-15 3.5 SUMMARY AND RECOMMENDATIONS 3-16 031209/P MARCH 2012 TABLE OF CONTENTS (Continued) SECTION REFERENCES. PAGE NO. R-1 APPENDICES A B C D E G H J L ATK DISPERSION MODELING LAND USE ANALYSES FOR M-136 AND M-225 M-245 METEOROLOGICAL DATA AND DATA RECOVERY STATISTICS ANNUAL WIND ROSE PLOTS ATK M-245 METEOROLOGICAL STATION FOR 1997, 1998, 1999, 2000, AND 2001 GAS MODELING RESULTS PARTICULATE MODELING RESULTS GAS DISPERSION FACTORS PARTICULATE DISPERSION FACTORS DISCRETE RECEPTOR MODELING HOURLY AND ANNUAL EMISSION FACTORS AND EMISSION RATES TABLES NUMBER 2-1 M-136 Treatment Unit Sources, Wastes Treated, Modeled Treatment Quantities per Event, Treatment Schedule and Applicable Emission Factors 2-2 M-225 Treatment Unit Sources, Wastes Treated, Modeled Treatment Quantities per Event, Treatment Schedule and Applicable Emission Factors 2-3 M-136 Source Parameters 2-4 M-225 Source Parameters 2-5 1.3 Class Waste Material "Conservative" Maximum Emission Factors (lbs/lb) 2-6 1.3 Class Waste Material "Corrected" Emission Factors (lbs/lb) 2-7 Summary of Deposition Modeling Parameters 2-8 ATK Modeling Analysis Discrete Receptors 2-9 M-136 Maximum General Grid Onsite/Offsite Receptors and Associated Grid Sectors 2- 10 M-225 Maximum General Grid Onsite/Offsite Receptors and Associated Grid Sectors 3- 1 Summary of Adams Ranch Receptor Concentrations in Comparison to NAAQS from M-136 and M-225 Using Conservative and Corrected Emission Factors 3-2 Summary of ATK Ranch Receptor Concentrations in Comparison to NAAQS from M-136 and M- 225 Using Conservative and Corrected Emission Factors 3-3 Summary of Autoliv Receptor Concentrations in Comparison to NAAQS from M-136 and M-225 Using Conservative and Corrected Emission Factors 3-4 Summary of Bear River Bird Refuge Receptor Concentrations in Comparison to NAAQS from M-136 and M-225 Using Conservative and Corrected Emission Factors 031209/P MARCH 2012 TABLES (Continued) NUMBER 3-5 Summary of Blue Creek Receptor Concentrations in Comparison to NAAQS from M-136 and M-225 Using Conservative and Corrected Emission Factors 3-6 Summary of Boundary 1 Receptor Concentrations in Comparison to NAAQS from M-136 and M-225 Using Conservative and Corrected Emission Factors 3-7 Summary of Boundary 2 Receptor Concentrations in Comparison to NAAQS from M-136 and M-225 Using Conservative and Corrected Emission Factors 3-8 Summary of Boundary 3 Receptor Concentrations in Comparison to NAAQS from M-136 and M-225 Using Conservative and Corrected Emission Factors 3-9 Summary of Boundary 4 Receptor Concentrations in Comparison to NAAQS from M-136 and M-225 Using Conservative and Corrected Emission Factors 3-10 Summary of Christensen Ranch Receptor Concentrations in Comparison to NAAQS from M-136 and M-225 Using Conservative and Corrected Emission Factors 3-11 Summary of Holmgren Ranch Pond Receptor Concentrations in Comparison to NAAQS from M-136 and M-225 Using Conservative and Corrected Emission Factors 3-12 Summary of Howell Dairy Receptor Concentrations in Comparison to NAAQS from M-136 and M-225 Using Conservative and Corrected Emission Factors 3-13 Summary of North Plant Main Area Receptor Concentrations in Comparison to NAAQS from M-136 and M-225 Using Conservative and Corrected Emission Factors 3-14 Summary of Penrose Receptor Concentrations in Comparison to NAAQS from M-136 and M-225 Using Conservative and Corrected Emission Factors 3-15 Summary of Salt Creek Waterfowl Management Receptor Concentrations in Comparison to NAAQS from M-136 andM-225 Using Conservative and Corrected Emission Factors 3-16 Summary of South Plant Main Area Receptor Concentrations in Comparison to NAAQS from M-136 and M-225 Using Conservative and Corrected Emission Factors 3-17 Summary of Thatcher Receptor Concentrations in Comparison to NAAQS from M-136 and M-225 Using Conservative and Corrected Emission Factors 3-18 Summary of Adams Ranch 1-Hour Gas Concentrations from Ml 36 and M225 in Comparison to Utah Acute 1-Hour TSLs Using Conservative and Corrected Emission Factors 3-19 Summary of ATK Ranch 1-Hour Gas Concentrations from Ml 36 and M225 in Comparison to Utah Acute 1-Hour TSLs Using Conservative and Corrected Emission Factors 3-20 Summary of Autoliv 1-Hour Gas Concentrations from M136 and M225 in Comparison to Utah Acute 1-Hour TSLs Using Conservative and Corrected Emission Factors 3-21 Summary of Bear River Bird Refuge 1-Hour Gas Concentrations from M136 and M225 in Comparison to Utah Acute 1-Hour TSLs Using Conservative and Corrected Emission Factors 3-22 Summary of Blue Creek 1-Hour Gas Concentrations from M136 and M225 in Comparison to Utah Acute 1-Hour TSLs Using Conservative and Corrected Emission Factors 3-23 Summary of Boundary 1 1-Hour Gas Concentrations from Ml36 and M225 in Comparison to Utah Acute 1-Hour TSLs Using Conservative and Corrected Emission Factors 3-24 Summary of Boundary 2 1-Hour Gas Concentrations from Ml36 and M225 in Comparison to Utah Acute 1-Hour TSLs Using Conservative and Corrected Emission Factors 3-25 Summary of Boundary 3 1-Hour Gas Concentrations from Ml36 and M225 in Comparison to Utah Acute 1-Hour TSLs Using Conservative and Corrected Emission Factors 3-26 Summary of Boundary 4 1-Hour Gas Concentrations from Ml36 and M225 in Comparison to Utah Acute 1-Hour TSLs Using Conservative and Corrected Emission Factors 3-27 Summary of Christian Ranch 1-Hour Gas Concentrations from M136 and M225 in Comparison to Utah Acute 1-Hour TSLs Using Conservative and Corrected Emission Factors 3-28 Summary of Howell Dairy 1-Hour Gas Concentrations from M136 and M225 in Comparison to Utah Acute 1-Hour TSLs Using Conservative and Corrected Emission Factors 3-29 Summary of Holmgren Ranch Pond 1-Hour Gas Concentrations from M136 and M225 in Comparison to Utah Acute 1-Hour TSLs Using Conservative and Corrected Emission Factors 031209/P MARCH 2012 TABLES (Continued) NUMBER 3-30 Summary of North Plant 1-Hour Gas Concentrations from Ml 36 and M225 in Comparison to Utah Acute 1-Hour TSLs Using Conservative and Corrected Emission Factors 3-31 Summary of Penrosel-Hour Gas Concentrations from M136 and M225 in Comparison to Utah Acute 1-Hour TSLs Using Conservative and Corrected Emission Factors 3-32 Summary of Salt Creek Waterfowl Mgmt 1-Hour Gas Concentrations from M136 and M225 in Comparison to Utah Acute 1-Hour TSLs Using Conservative and Corrected Emission Factors 3-33 Summary of South Plant 1-Hour Gas Concentrations from Ml 36 and M225 in Comparison to Utah Acute 1-Hour TSLs Using Conservative and Corrected Emission Factors 3-34 Summary of Thatcher 1-Hour Gas Concentrations from Ml 36 and M225 in Comparison to Utah Acute 1-Hour TSLs Using Conservative and Corrected Emission Factors 3-35 Summary of Adams Ranch 24-Hour Gas Concentrations fronn M136 and M225 in Comparison to Utah 24-Hour Chronic TSLs Using Conservative and Corrected Emission Factors 3-36 Summary of AT Ranch 24-Hour Gas Concentrations from Ml 36 and M225 in Comparison to Utah 24-Hour Chronic TSLs Using Conservative and Corrected Emission Factors 3-37 Summary of Autoliv 24-Hour Gas Concentrations from Ml 36 and M225 in Comparison to Utah 24-Hour Chronic TSLs Using Conservative and Corrected Emission Factors 3-38 Summary of Bear River Bird Refuge 24-Hour Gas Concentrations from Ml36 and M225 in Comparison to Utah 24-Hour Chronic TSLs Using Conservative and Corrected Emission Factors 3-39 Summary of Blue Creek 24-Hour Gas Concentrations from Ml 36 and M225 in Comparison to Utah 24-Hour Chronic TSLs Using Conservative and Corrected Emission Factors 3-40 Summary of Boundary 1 24-Hour Gas Concentrations from Ml36 and M225 in Comparison to Utah 24-Hour Chronic TSLs Using Conservative and Corrected Emission Factors 3-41 Summary of Boundary 2 24-Hour Gas Concentrations from Ml 36 and M225 in Comparison to Utah 24-Hour Chronic TSLs Using Conservative and Corrected Emission Factors 3-42 Summary of Boundary 3 24-Hour Gas Concentrations from Ml 36 and M225 in Comparison to Utah 24-Hour Chronic TSLs Using Conservative and Corrected Emission Factors 3-43 Summary of Boundary 4 24-Hour Gas Concentrations from Ml36 and M225 in Comparison to Utah 24-Hour Chronic TSLs Using Conservative and Corrected Emission Factors 3-44 Summary of Christensen Ranch 24-Hour Gas Concentrations from Ml 36 and M225 in Comparison to Utah 24-Hour Chronic TSLs Using Conservative and Corrected Emission Factors 3-45 Summary of Holmgren Ranch Pond 24-Hour Gas Concentrations from Ml 36 and M225 in Comparison to Utah 24-Hour Chronic TSLs Using Conservative and Corrected Emission Factors 3-46 Summary of Howell Dairy 24-Hour Gas Concentrations from Ml36 and M225 in Comparison to Utah 24-Hour Chronic TSLs Using Conservative and Corrected Emission Factors 3-47 Summary of North Plant 24-Hour Gas Concentrations from Ml36 and M225 in Comparison to Utah 24-Hour Chronic TSLs Using Conservative and Corrected Emission Factors 3-48 Summary of Penrose 24-Hour Gas Concentrations from Ml 36 and M225 in Comparison to Utah 24-Hour Chronic TSLs Using Conservative and Corrected Emission Factors 3-49 Summary of Salt Creek Waterfowl Mgmt 24-Hour Gas Concentrations from Ml36 and M225 in Comparison to Utah 24-Hour Chronic TSLs Using Conservative and Corrected Emission Factors 3-50 Summary of South Plant 24-Hour Gas Concentrations from Ml36 and M225 in Comparison to Utah 24-Hour Chronic TSLs Using Conservative and Corrected Emission Factors 3-51 Summary of Thatcher 24-Hour Gas Concentrations from Ml 36 and M225 in Comparison to Utah 24-Hour Chronic TSLs Using Conservative and Corrected Emission Factors 3-52 Summary of Adams Ranch 24-Hour Particulate Concentrations from Ml 36 and M225 in' Comparison to Utah Chronic 24-Hour TSLs Using Conservative and Corrected Emission Factors 3-53 Summary of ATK Ranch 24-Hour Particulate Concentrations from M136 and M225 in Comparison to Utah Chronic 24-Hour TSLs Using Conservative and Corrected Emission Factors 3-54 Summary of Bear River Bird Refuge 24-Hour Particulate Concentrations from Ml36 and M225 in Comparison to Utah Chronic 24-Hour TSLs Using Conservative and Corrected Emission Factors 031209/P IV MARCH 2012 TABLES (Continued) NUMBER 3-55 Summary of Blue Creek 24-Hour Particulate Concentrations from Ml36 and M225 in Comparison to Utah Chronic 24-Hour TSLs Using Conservative and Corrected Emission Factors 3-56 Summary of Boundary 2 24-Hour Particulate Concentrations from Ml36 and M225 in Comparison to Utah Chronic 24-Hour TSLs Using Conservative and Corrected Emission Factors 3-57 Summary of Boundary 3 24-Hour Particulate Concentrations from Ml 36 and M225 in Comparison to Utah Chronic 24-Hour TSLs Using Conservative and Corrected Emission Factors 3-58 Summary of Boundary 4 24-Hour Particulate Concentrations from M136 and M225 in Comparison to Utah Chronic 24-Hour TSLs Using Conservative and Corrected Emission Factors 3-59 Summary of Christensen Ranch 24-Hour Particulate Concentrations from M136 and M225 in Comparison to Utah Chronic 24-Hour TSLs Using Conservative and Corrected Emission Factors 3-60 Summary of Holmgren Ranch Pond 24-Hour Particulate Concentrations from M136 and M225 in' Comparison to Utah Chronic 24-Hour TSLs Using Conservative and Corrected Emission Factors 3-61 Summary of Howell Dairy 24-Hour Particulate Concentrations from M136 and M225 in Comparison to Utah Chronic 24-Hour TSLs Using Conservative and Corrected Emission Factors 3-62 Summary of North Plant Main Area 24-Hour Particulate Concentrations from M136 and M225 in Comparison to Utah Chronic 24-Hour TSLs Using Conservative and Corrected Emission Factors 3-63 Summary of Penrose 24-Hour Particulate Concentrations from M136 and M225 in Comparison to Utah Chronic 24-Hour TSLs Using Conservative and Corrected Emission Factors 3-64 Summary of Salt Creek Waterfowl Management 24-Hour Particulate Concentrations from Ml 36 and M225 in Comparison to Utah Chronic 24-Hour TSLs Using Conservative and Corrected Emission Factors 3-65 Summary'of South Plant Main Area 24-Hour Particulate Concentrations from Ml36 and M225 in Comparison to Utah Chronic 24-Hour TSLs Using Conservative and Corrected Emission Factors 3-66 Summary of Thatcher 24-Hour Particulate Concentrations from Ml 36 and M225 in Comparison to Utah Chronic 24-Hour TSLs Using Conservative and Corrected Emission Factors FIGURES NUMBER 2-1 Site Location Map 2-2 M-135 Treatment Unit, 3 kilometer General Receptor Grid and Ghd Sectors, 100 Meter Increment 2-3 M-136 Treatment Unit, 3 km to 10 km General Receptor Grid and Grid Sectors, 500 Meter Increment 2-4 M-225 Treatment Unit, 3 kilometer General Receptor Grid and Grid Sector, 100 Meter Increment 2-5 M-225 Treatment Unit, 3 km to 10 km General Receptor Grid and Grid Sectors, 500 Meter Increment 2-6 Location of ATK Promontory M-136 and M-225 Treatment Units and Discrete Receptors 031209/P MARCH 2012 1.0 INTRODUCTION ATK Launch Systems (ATK) Inc., located 28 miles west of Brigham City, Utah currently operates open buming (OB) and open detonation (OD) units for the treatment of hazardous waste propellants and propellant contaminated materials. These treatment units are identified as M-136 and M-225 and are subject to RCRA 40 CFR Subpart X permitting requirements for miscellaneous treatment units. These units are currently operating as interim status facilities. The Utah Department of Environmental Quality Division of Solid and Hazardous Waste (UDSHW) is requiring ATK to conduct new air dispersion modeling, human health, and ecological risk assessments in support of a new Subpart X permit application. In accordance with the Human Health Risk Assessment Protocol (HHRAP) for Hazardous Waste Combustion Facilities (U.S. EPA, 2005) guidance, before the risk assessments can be conducted, an air dispersion modeling analysis must be performed to evaluate the air quality impact of the M-136 and M-225 treatment units. The results of the air dispersion modeling analysis will be input into human health and ecological risk assessment models to determine the potential risk and hazard from the OB/OD treatment units. At the request of ATK, Tetra Tech, Inc. (Tetra Tech) conducted a preliminary full scale modeling analysis (Tetra Tech, 2011b) and submitted it to UDSHW for review and comment in October 2011. This preliminary modeling analysis has been conducted using a UDSHW approved air dispersion modeling protocol (Tetra Tech, 2011a). Technical review of the modeling analysis was conducted by Tech Law and comments were issued in January 2012. Based on Tech Law comments, it was necessary to revise several sections of the original air dispersion modeling protocol relative to M-136 and M-225 proposed treatment quantities and treatment schedule, emission factor tables, and modeling methodology to address impacts to discrete receptors and the general receptor grid, which focused on worst case meteorological events. The revised modeling protocol sections were issued as an addendum (Tetra Tech, 2012) and a new modeling analysis was conducted using the new protocol procedures. The revised preliminary modeling analysis is designed to support human health and ecological risk assessments, and incorporates guidance provided in the Human Health Risk Assessment Protocol for Hazardous Waste Combustion Facilities (U.S.EPA, 2005). Air dispersion modeling and risk assessment for this type of facility typically starts with conservative (health protective) assumptions that are designed to incorporate highly conservative, and often unrealistic modeling and exposure parameters. There are many reasons for this, both historical and practical, and if the risks are acceptable additional refinements may not be required. However, the risk assessment process is designed to be an iterative process, as described in Chapter 1 of the HHRAP guidance (U.S. EPA, 2005), which notes that "you can view risk assessments as an iterative process with a number of available options once risk estimates are 031209/P 1-1 MARCH 2012 produced". This iterative process, showing the various options, is graphically represented in Figure 1-1 of the guidance. Further refinements to this process are often undertaken as a matter of course. The 2005 HHRAP references Guidelines for Ensuring and Maximizing the Quality, Objectivity, Utility, and Integrity, of Information Disseminated by the Environmental Protection Agency (U.S. EPA 2002) that emphasizes that "risk assessments may be performed iteratively, with the first iteration employing protective (conservative) assumptions to identify possible risks" The analysis does not terminate after the first screening, and it is possible that "a more refined, data-intensive risk assessment" is necessary "if potential risks are identified in a screening level assessment" (Page 1-11). It is, therefore, common for additional information to be added to the initial risk assessment "e.g. site-specific information that's more representative of the actual exposure settings" (Page 1-12). Furthermore, the iterative process "enables you to determine if the risks identified in the earlier assessment accurately represent the situation at a given combustion facility" (Page 1-12). Consequently, the initial air dispersion modeling analysis may not be fully representative of the current conditions at ATK's OB/OD treatment areas. This revised preliminary modeling report shows the results of a conservative type of modeling exercise and is based on a number of protective conservative assumptions designed to overestimate the environmental impact of the M-136 and M-225 treatment units, and each step compounds these conservative assumptions into subsequent steps of the assessment process. The modeling process incorporates conservative assumptions about the types of waste being processed; the energy released during treatment and associated plume rise, modeling protocols, worst case meteorological conditions, averaging period concentrations, and plume dispersion and deposition phenomena. In reality, this approach may not actually reflect operating conditions or meteorological conditions at the facility in the future and represents a worst-case analysis. It is ATK's intention to utilize the results in this report to identify in discussions with UDSHW, the areas where conservative, health protective, but facility- related realistic assumptions may be developed to refine the work presented in this dispersion modeling report. The outcome will result in a more realistic evaluation of plume dispersion and risk assessment for a facility that operates within acceptable regulatory limits. ATK typically treats three different waste type packages; one hundred percent pure propellant; 85 percent pure propellant with 15 percent waste materials, and 65 percent pure propellant with 35 percent waste materials. Historically, most the material treated at ATK is either pure propellant or the 85%/15% waste mixture. In this modeling analysis, it was conservatively assumed that the lower level of propellant (65 percent) and higher waste levels (35 percent) were burned, which would overestimate the potential impacts because these trash burns would have lower plume temperature and result in higher air 031209/P 1-2 MARCH 2012 dispersion factors, and this mixture would potentially contain more of the by-products than 100 percent pure propellant. Other areas of potential overestimation that might significantly affect the results in this modeling report are background chemicals, and the method detection limits. For example, ATK's wastes are low in sulfur, but the initiation system used during the burn testing in the ODOBi test chamber uses sulfur containing materials that were not subtracted from the original test results. The test burn results showed sulfur dioxide (SO2) that was too low to be reliably measured, but this report assumes; a) that sulfur is present at reliably measurable levels; b) that it is due to the waste and not the burn initiator; and c) that if it was not detected it was actually present at its method detection limit - In addition, the modeling analysis has assumed that all discrete receptors and maximum impact onsite and offsite receptors impacts come as a result of only worst case meteorological conditions, which may not necessarily be the case during actual treatment events in the future. This assumption will most likely result in an over prediction of the annual average impacts to all receptors. Screening methodology was also utilized to extrapolated 1-hour worst case modeling results to longer averaging periods (3-hour, 8-hour, and 24-hours) for assessing compliance with National Ambient Air Quality Standards (NAAQS), to Utah acute and chronic toxic screening levels, and OSHA 8-hour exposure criteria. 031209/P 1-3 MARCH 2012 2.0 AIR DISPERSION MODELING PROTOCOL The modeling methodology used in this modeling analysis is based on information provided by ATK, technical experts, discussions with comments received from UDSHW, new emissions test data, guidance defined in the HHRAP (U.S.EPA, 2005), and technical review comments provided by Tech Law on the initial preliminary model analysis (Tetra Tech, 2011). Tetra Tech conducted the initial preliminary modeling analysis in 2011 (Tetra Tech, 2011b), using a UDSHW approved air dispersion modeling protocol (Tetra Tech, 2011a). Technical review of the modeling analysis was conducted by Tech Law and comments were issued in January 2012. Based on the review comments, it was necessary to revise the original air dispersion modeling protocol relative to M-136 and M-225 proposed treatment quantities and treatment schedule, emission factor tables, and modeling methodology to address impacts to discrete receptors and the general receptor grid, and .utilized worst case meteorological events to accommodate the proposed new treatment schedule.. The revised modeling protocol was issued as an addendum (Tetra Tech, 2012) and all protocol revisions have been used in the analysis and are incorporated in Section 2.0 ofthis report. 2.1 TERRAIN AND SITE DESCRIPTION The ATK facility is located in the Blue Spring Valley, which is bounded on the east and west by Blue Spring Hills, and the Engineer, and Promontory Mountain Ranges, respectively. Within the Blue Spring Valley, the terrain is characterized by gentle topography that slopes down from the mountain crest at an elevation of approximately 6,060 feet above mean sea level (AMSL) toward the center of the Blue Creek Valley at an elevation of 4,250 feet AMSL. As a result, the surrounding environment extending out to 10 kilometers (km) from each treatment unit can be characterized as complex terrain. For air modeling purposes, terrain is referred to as "complex" if the elevation of the surrounding land, within the assessment area, is above the top of the emission release point Because ATK conducts OB and OD treatment essentially at ground level in burn pans and uncovered pits, all receptors having an elevation greater than the treatment unit base elevation are considered complex terrain receptors. All receptors at or below the treatment unit base elevation are considered to be flat terrain receptors. 2.2 TREATMENT LOCATIONS OB and OD treatment of reactive wastes is conducted at two treatment facilities. The main treatment facility is M-136, which is located centrally to the two main manufacturing sites. A second OB treatment facility is M-225, which is located in a remote development called Plant III. The M-225 unit is located about 9 km southeast of the M-136 unit. The location of both treatment units are shown in Figure 2-1. A 031209/P 2-1 MARCH 2012 description of the treatment unit activities that are conducted at each unit are descnbed in Sections 2.2.1 and 2.2.2. 2.2.1 M-136 Treatment Unit Description M-136 is the primary treatment unit for conducting open burning at ATK. The total annual quantity of waste treated at the M-136 treatment unit is approximately 100 times the annual quantity treated at M-225. The materials treated at M-136 include primary bulk waste propellant, 1.1 and 1.3, contaminated waste, laboratory waste and obsolete rocket motors. The M-136 treatment unit consists of 14 burn stations. OB is conducted at 14 burn stations in unlined or lined (with clay soil) trays seven days a week (Monday through Sunday). OB of obsolete rocket motors is conducted at Burn Station 14. OD of.waste materials is conducted at either Burn Station 13 or 14. Detonation pits are prepared using augers, and then the reactive wastes are placed in the pit uncovered and detonated. A description of M-136 sources, treatment quantities, and treatment schedule assumed in this modeling analysis are present in Table 2-1. 2.2.2 M-225 Treatment Unit Description M-225 receives small amounts of the reactive waste materials from the Plant III propellant development area. These reactive wastes are treated via open burning or open detonation. Reactive wastes are treated in burn pans and include pure double base (1.1) propellants and composite propellants (1.3), as well as, reactive contaminated trash materials such as cloth and paper wipes, metal containers, plastics, and propellant ingredients. The treatment activity at M-225 involves small quantities of waste material. Open detonation treatment of 1.1 pure propellants is conducted at one location within the M-225 fenced area. Detonation pits are usually prepared using augers, and then the reactive wastes are placed in the pit uncovered and detonated. A description of M-225 sources and treatment quantities and treatment schedule assumed in this modeling analysis are present in Table 2-2 031209/P 2-2 MARCH 2012 2.3 AIR QUALITY DISPERSION MODEL SELECTION The HHRAP guidance recommends the use of the Industrial Source Complex Short Term 3 (ISCST3) dispersion model (U.S.EPA, 1995a) for risk assessment evaluations. However, ISCST3 is designed for sources associated with industrial facilities, rather than OB/OD treatment operations. In the case of waste treatment activities at ATK, a special dispersion model is needed to simulate the quasi-continuous and instantaneous plume release cloud rise, and dispersion of OB and OD sources. OB treatment is typically considered as a quasi-continuous source, whereas OD is considered to be an instantaneous source. The United States Environmental Protection Agency (U.S: EPA) maintains a Support Center for Regulatory Air Models called SCRAMS. The only SCRAM model that is specific to OB and OD treatment operations is the Open Burn/Open Detonation Dispersion Model (OBODM) (Kramer, 1997). This model has also been identified by UDSHW as the model of choice .for conducting the ATK air dispersion modeling analysis in support of the human health and ecological risk assessments. OBODM is the preferred model for OB/OD sources and the latest version of the model (1.3.24) was used in this analysis to calculate the air quality impact of emissions from M-136 and M-225. However, OBODM is limited in the number of receptors (100) it can address in a single model run, which necessitates numerous model runs and significantly more post-processing time, particularly in the case of large receptor networks requiring analysis with multiple years of meteorological data. OBDOM is specifically designed to predict air quality impacts (particulate and gas concentrations and particle deposition) from OB and OD treatment; however cannot predict particulate concentrations and deposition in complex terrain. However, an alternate procedure has been develop to estimate particulate concentrations and particle deposition and is discussed in Section 2.11. Because OBODM is specifically designed for OB and OD treatment, it can accommodate source-specific input data regarding treatment operations. This allows OBODM to provide greater detail regarding the spatial and temporal variation of emissions and meteorological conditions, and enhances the model's ability to evaluate individual source impacts. OBODM does not address particle bound modeling. As a result,'this modeling protocol assumes that the calculated particulate concentrations are equal to particle-bound concentrations and modeled particulate gravitational deposition is equal to particle-bound gravitational deposition. 2.3.1 Flat and Complex Terrain Modeling Within a 10 kilometer radius of the ATK facility, the terrain is characterized by topography that slopes down from peak mountain elevations of approximately 6,900 feet above mean sea level (amsl) to flat terrain elevations of approximately 4,200 feet amsl. The M-136 and M-225 treatment units are located at elevations of approximately 4,587 feet amsl and 4,597 feet amsl respectively. 031209/P 2-3 MARCH 2012 OBODM will be used to assess the impact from ATK treatment operation to receptor locations in both flat and complex terrain. A receptor location is defined as a flat terrain receptor if the receptor elevation is equal to or less than the source elevation. A receptor location is defined as complex if the receptor elevation is greater than the source elevation. As a result the surrounding environment extending out to 10 kilometers from the ATK facility can be characterized by a combination of flat and complex terrain relative to the elevation of the M-136 and M-225 treatment units. OBODM has the capability to calculate downwind concentrations for both flat and complex terrain receptors. However, in complex terrain mode, the model cannot be used when calculating concentration with gravitational deposition occurring or gravitational deposition for particulates with appreciable settling velocities. In this assessment, a particle size distribution has been assumed for the particulate and deposition calculations. Further discussion of an alternate methodology for addressing particulate impacts to complex terrain receptors is discussed in Section 2.11. 2.4 LAND USE ANALYSIS Land use information is necessary for the selection of certain air dispersion modeling variables (dispersion coefficients and surface roughness). The land use characteristics surrounding a source of air emission can be determined from the United States Geological Survey (USGS) 7.5-minute topographic maps, aerial photographs, or visual surveys of the area. The land use classification for the area surrounding the M-136 and M-225 treatment units was determined from the Thatcher Mountain 7.5-minute (1:24,000 scale) quadrangle using the Auer method (Auer, 1978), as described in Section 3.3.2.1 of the HHRAP guidance (U.S.EPA, 2005). Using this method, areas are defined as either "rural" or "urban." A radius of 3 km beyond each treatment unit source was given a general inspection to determine whether the area within 3 km is rural or urban according to Auer's (Auer, 1978) definitions. This inspection resulted in a rural classification for both treatment units. The 3 km radius area was broken down into smaller areas (100 meters by 100 meters) for a more detailed inspection. Each small area was then either classified as rural or urban. The total count of rural areas was greater than 50 percent surrounding each treatment unit. As a result, the land use classification is rural for both M-136 and M-225. The results of the land use analysis for both treatment units is presented in Appendix A. 031209/P 2-4 MARCH 2012 2.5 SURFACE ROUGHNESS HEIGHT The surface roughness height used in this modeling analysis is based on the methodology given in Section 3.3.2.2 of the HHRAP guidance (U.S.EPA, 2005). The results of the land use classification described in Section 2.4 and the five-years of meteorological data for the ATK M-245 on-site meteorological monitoring station were used to calculate site-specific surface roughness heights for both treatment units. Based on the HHRAP guidance methodology, all wind sectors were classified as desert shrub land. In this case, the annual site-specific surface roughness height for both treatment units was calculated to be approximately 0.26 meters. 2.6 OB/OD SOURCE SCENARIOS In order to calculate the air quality impact of OB and OD treatment operations, OBODM requires specific information regarding the characteristics of the treatment source. For example, OBODM requires input data indicating the type and amount of material being treated, how it is being treated (OB or OD), the heat content, burn rate of the material, the amount of matenal being treated, the source dimensions, and the plume release height The following OB/OD treatment source scenarios were evaluated in this air dispersion modeling analysis for ATK treatment operations: • OB treatment of pure propellant and energetic-contaminated materials at M-136 and M-225. • OD treatment of energetic waste at M-136 and M-225. The source scenarios assumed for M-136 and M-225 are discussed below. M-136 Treatment Unit Source Scenario The M-136 Unit is the primary treatment location and includes 14 burn stations. All treatment is conducted in pans with the exception of Burn Station 14 obsolete rocket motor treatment, which consists of a bermed area used for the OB of obsolete rocket motors and wastes that are treated in uncovered pits by OD at Stations 13 or 14. Detonation pits are usually prepared using augers, and then the reactive wastes are placed in the pit uncovered and detonated. Although the OBODM model has the capability to model multiple source scenarios and. individual locations in the same model run, computer resources (both computational and memory/output file size) preclude modeling all individual M-136 treatment stations. As a result, certain M-136 treatment stations were consolidated into a single source, where deemed applicable, and as recommended in modeling guidance, in order to accommodate computer resources. 031209/P 2-5 MARCH 2012 U.S. EPA modeling guidance (U.S.EPA, 2000) allows the merging of multiple emission points that are located within close proximity to one another and if the emission points have similar release parameters. In the case of M-136, the 14 burn stations were consolidated into three separate sources with discrete coordinates due to the separation distance between the burn station areas. For example, in the case of M-136 Burn Stations 1-12, all stations are located in one general treatment area that measures approximately 160 x 220 meters. The approximate separation distance from the Burn Station 1-12 area to Burn Station 13 is approximately 200 - 250 meters. The estimated separation distance from Burn Station 13 to Burn Station 14 is about 500 meters. As a result, these two treatment Ideations (Station 13 and 14) were treated as two separate OB sources due to their respective treatment areas and separation distances. OD was assumed to take place at Station 13. The UTM coordinates selected for each of these treatment sources represent the center of the respective treatment operational areas. The four M-136 source areas used in this modeling analysis include the following Burn Stations: Source 1 - representing Burn Stations 1-12 (OB of 1.1, 1.3, and contaminated trash) Source 2 - representing Burn Station 13 (OB of 1.1, 1.3, and contaminated trash) Source 3 - representing Burn Station 14 (OB of 1.1, 1.3, and contaminated trash) Source 4 - representing Burn Station 13 (OD of waste energetics) Source 5 - representing Burn Station 14 treatment of large rocket motors < 26,000 pounds The modeling analysis assumed that M-136 treatment will be conducted in accordance with the treatment schedule shown in Table 2-1. Each source was modeled at a unit emission rate. M-225 Treatment Unit Source Scenario The M-225 Unit is a small area consisting of five burn stations (using lined burn pans) and one detonation pit Detonation pits are usually prepared augers, and then the reactive wastes are placed in the pit uncovered and detonated. The M-225 treatment unit was evaluated as two treatment sources in the modeling analysis: • Source 1 - representing OB in pans (1.1, 1.3, and contaminated trash) • Source 2 - representing OD in pit (1.1 and 1.3 propellants) 031209/P 2-6 MARCH 2012 This modeling analysis assumed that treatment will be conducted in accordance with the treatment schedule shown in Table 2-2 between 0600 to 1800. Each source was modeled at a unit emission rate. Due to the relative small size of the M-225 treatment area, M-225 Source 1 and Source 2 were assigned the same location coordinate. 2.7 M-136 TREATMENT QUANTITY SCENARIOS Table 2-1 presents a listing of the M-136 modeled sources, associated burn stations, waste categories, modeled per event treatment quantity, treatment schedule, total annual treatment quantities and applicable emission factors for each source. The M-136 applicable emission factors are discussed in Section 2.9.1 and are presented in Tables 2-5 and 2-6. Although M-136 treats a variety of wastes (1.1, 1.3, etc.) as described in the modeling protocol (Tetra Tech, 2011), ATK has agreed to use the 1.3 ODOBi emission factors for all M-136 modeled sources. 2.8 M-225 TREATMENT QUANTITY SCENARIOS Table 2-2 presents a listing of the M-225 modeled sources, associated burn stations, waste categories, modeled per event treatment quantity, treatment schedule, total annual treatment quantities and applicable emission factors for each source. The M-225 applicable emission factors are discussed in Section 2.9.1 and are presented in Tables 2-5 and 2-6. Although M-225 treats a variety of wastes (1.1, 1.3, etc.), ATK has agreed to use the 1.3 ODOBi emission factors for all M-225 modeled sources. 2.9 SOURCE PARAMETERS The selection of M-136 and M-225 source parameters used in OBODM is based on information provided by ATK, and guidance associated with HHRAP. A summary of the source parameters for the M-136 and M-225 treatment units are shown in Tables 2-3 and 2-4, respectively. All OB and OD sources were assumed to treat the same class of materials (1.3) as tested in the Open Detonation Open Burning Improved (ODOBi) test chamber from June 7 to 15, 2006 (URS, 2009). The results of the ODOBi testing produced a list of emission factors that were used in this analysis to compute air concentrations and deposition rates. Further information regarding the testing program and the emission factors used in this analysis is discussed in Section 2.9.1. The class of material simulated in the model was assumed to have a heat content value of 1,471 calories/gram (cal/gm). 2.9.1 ODOBi Emissions Testing and Emission Factors Representative characterization of treatment emissions is a necessary component for predicting impacts to the environment and supporting the risk assessment process. The UDSHW has required ATK to 031209/P 2-7 MARCH 2012 conduct emissions testing of Class 1.3 materials in order to establish emission factors for the major class of propellants (Class 1.3) treated at the ATK facilities. The goal of the emission testing program was to identify and quantify emissions from OB of these Class 1.3 propellant waste (PW) materials. The ODOBi test chamber was used to determine emission factors for airborne compounds from three different compositions of ATK Class 1.3 process waste (PW) materials.. Three test items were studied. The first material was 100% Class 1.3 propellant The other two test materials consisted of a mixture of Class 1.3 propellant blended with different percentages of materials such as cloth, paper, paper wipes, plastics, and cleaning items. The tests were conducted from June 7 to 15, 2006 (URS, 2009). Emissions were measured from simulated OB events containing the following propellant wastes mixtures: • Test Material 1 - PW100: 100% ammonium perchlorate (AP) propellant • Test Material 2 - PW85-15: 85% AP + 15% trash • Test Material 3 - PW65-35: 65% AP + 35% trash The airborne target analytes measured included: Carbon dioxide (CO2); Carbon monoxide (CO); Carbonyls; Dioxins/Furans; Hydrogen chloride (HCI), chlorine (CI2), and ammonia (NH3); Hydrogen cyanide (HCN); Metals Nitrogen oxides (NOx) Particulate matter smaller than 2.5 microns (PM2.5); Particulate matter smaller than 10 microns (PMIO); Perchlorates; Semivolatile organic compounds (SVOCs); Sulfur dioxide (SO2) Total suspended solids (TSP); Tracer compound sulfur hexafluoride (SF6); and Volatile organic compounds (VOCs). Average and maximum emission factors were developed from the test results for each detected compound after applying the "non-detect rules." Each emission factor represents the pounds of 031209/P 2-8 MARCH 2012 compound emitted per pound of waste material treated. Since many of the compounds measured may be already present in ambient air, "corrected" emission factors were determined by subtracting the background concentrations. In addition, a more conservative set of emission factors were also developed based on replacing all nondetect results with the minimum detection limit (MDL) and background/blank correction was not performed. The emission factors were also adjusted to compensate for dilution that occurred during sampling. The ODOBi testing did not determine the size distribution of particulate emissions. A condense summary of the test results are presented below: Particulate Material - Particulate material and inorganic gases were the primary emissions from all items. The PW85-15 trash sample produced the highest particulate emissions. PM2.5 constituted 30-40% ofthe total particulate emissions from all test items. Metals and Perchlorates - Aluminum was the predominant metal product in the air samples from each test. Aluminum was a constituent of each test item. Other metals were found at lower levels. The highest emissions were produced by the PW85-15 sample. Perchlorate was not detected in any of the test samples. VOCs and SVOCs - SVOCs were emitted at lower levels. VOCs were generally measured at higher levels than SVOCs. The PW65-35 sample produced the highest concentration of VOCs. Non-methane organic compounds constituted the majority of the VOC emissions. Dioxins and Furans - Most dioxin/furan isomers were reported at picogram levels. Some isomers in the PW85-15 and PW65-35 samples were reported at nanogram levels. The highest emissions were measured from the PW85-15 sample. Carbonyls - Carbonyls were generally measured at very low levels in most samples. HCI, CI2, NH3, and HCN - HCI concentrations were highest in the pure propellant sample. Chlorine levels were not high enough to be distinguished from the backgrounds and blanks. Ammonia and cyanide were found at low levels in some samples. 1 Continuous Emissions Monitoring - The primary gas-phase compound from all test items was CO2. Very little CO was produced in each test, indicating good combustion of the trash samples. NOx was measured at lower levels in all tests. SO2 was too low to be reliably measured. Including the ODOBi testing results, there were other proposed emission factor databases for the treatment of 1.3, 1.1 and category E wastes at M-136 and M-225. Although the emission factors for 1.3 031209/P 2-9 MARCH 2012 and 1.1 materials are based on actual ATK matenals emissions testing, the emission factors for addressing impacts from the treatment of category E wastes while not actual ATK wastes, they are similar and represent the best available at this time. Discussions were conducted between ATK and UDSHW regarding the best approach to represent the maximum impact from all ATK operations and comply with UDSHW's desire to establish a lower and upper bound for ATK emissions. It was determined that the ODOBi 1.3 reactive propellant "conservative" and "corrected" emission factors presented in Tables 2-5 and 2-6, respectively, represent a conservative estimate of ATK emissions. As a result, it was agreed that ATK agreed to utilize the 1.3 ODOBi propellant emission factors given in Tables 2-5 and 2-6 for all emissions sources at M-136 and M-225, regardless of waste category, in order to establish conservative lower and upper bounds for risk assessment Tables 2-5 and 2-6 also highlight the target analytes that were not detected during the OBODi testing. 2.10 MODELING ASSUMPTIONS FOR M-136 AND M-225 The following assumptions were used in the modeling analysis for the M-136 and M-225 treatment units: M-136 Treatment Unit • OB source release is quasi-continuous (volume source). • OD source release is instantaneous (volume source). • Assume the 5 source areas are at the same elevation as Burn Stations 1-12; Elevation = 4,587 feet amsl. The net elevation difference between the 3 source locations is only 36 feet (11 meters). • Run OBODM for each model type (gas, particulate, and deposition) to give the contribution from each M-136 source identified in Table 2-1. • Source dimensions for OB at M-136 are based on average pan size for that treatment area: - Average dimension of pans in Burn Stations 1-12 = 8' x 13' - Average dimension of pans in Burn Stations 13 = 6'X 9' - Dimension of Burn Station 14 rocket motor assumed to be 5' x 50' • The release height for OB at Sources 1, 2, 3, and 5 = 1.0 meter.. • The release height for OD at Source 4 is ground level.. 031209/P 2-10 MARCH 2012 • OD pit diameter is 1.5 meters. • Gas, particulate, and deposition phase OBODM modeling was conducted using a unit emission rate. • Default OBODM particulate and mass distributions were assumed for particulate and deposition . modeling. • OBODM 1-hour air concentrations were used to calculate air concentrations for longer averaging periods using the assumption that only one treatment event occurs per hour. One-hour concentrations were converted to other short term averaging periods using USEPA screening factors (USEPA, 1992). • The OBODM model does not calculate particle bounding concentration. As a result, ATK has assumed that OBODM calculated particulate concentrations are equal to particle-bound concentrations and modeled particulate gravitational deposition is equal to particle-bound gravitational deposition. The values of Fv, fraction of COPC concentration in the vapor phase, found in the HHRAP Companion Data Base will be used in the human health risk assessment to determine the amount of particle-bound constituent that behaves as a gas and (1-Fv) will be used to determine the amount that behaves as particulate. Annual and 1-hour gas, particulate, and deposition ADFs calculated for each M-136 sburce are presented in Appendices G, H, and I, respectively. M-225 Treatment Unit • OB source release is quasi-continuous (volume source). • OD source release is instantaneous (volume source). • Both M-225 sources have the same coordinate and elevation; elevation = 4,597 feet AMSL to consolidate model runs. • Run OBODM for each model type (gas, particulate, and deposition) to give the contribution from each M-225 source identified in Table 2-2. All OBODM input and output files for gas, particulate, and deposition modeling are provided in Appendices D, E, and F, respectively 031209/P 2-11 MARCH 2012 • Each source configuration based on average pan size - Average dimension of pans = 6' x 17' . .- OD pit diameter is 1.5 meter diameter. • Release height for OB = 1.0 meter. • Release height for OD is ground level. • Default OBODM particulate and mass distnbutions were assumed for particulate and deposition modeling. • OBODM 1-hour air concentrations were used to calculate air concentrations for longer averaging periods using the assumption that only one treatment event occurs per hour One-hour concentrations were converted to other short term averaging periods using USEPA screening factors (USEPA, 1992). • The OBODM model does not calculate particle bounding concentration. As a result, ATK has assumed that OBODM calculated particulate concentrations are equal to particle-bound concentrations and modeled particulate gravitational deposition is equal to particle-bound gravitational deposition. The values of Fv, fraction of COPC concentration in the vapor phase, found in the HHRAP Companion Data Base will be used in the human health risk assessment to determine the amount of particle-bound constituent that behaves as a gas and (1-Fv) will be used to determine the amount that behaves as particulate. Annual and 1-hour gas, particulate, and deposition ADFs calculated for each M-225 source are presented in Appendices G, H, and I, respectively. 2.11 DEPOSITION MODELING In addition to calculating 1-hour and annual average ADFs for gases and particulates, OBODM also calculated 1-hour and annual deposition ADFs. Due to the limitations of OBODM, separate model runs were required for the deposition phase. The deposition mechanisms applicable to the M-136 and M-225 treatment units included gravitational settling of particulates. It is important to note that wet deposition is not calculated by OBODM. However, this deposition mechanism is not applicable in the case of ATK because treatment operations are not conducted during precipitation events. Also, OBODM does not calculate deposition of particulates for complex terrain 031209/P 2-12 MARCH 2012 receptors. However, ATK will use OBODM model 1-hour and annual air concentration (pg/m^) results for the "gas" phase at complex terrain receptors to determine complex terrain deposition rates. This approach is consistent with OBODM guidance and HHRAP (USEPA, September, 2005) and is considered to represent a conservative bias because the gas air concentrations calculated are nondepleted (e.g., removal of mass from the cloud as a function of downwind distance is not accounted for). A conservative deposition velocity of 0.03 meters/seconds (m/s) was used for this assessment, which is the default value specified in the HHRAP (U.S.EPA, September, 2005) guidance. As a comparison, the gravitational settling velocity for particles of 2 g/cm^ and 10 pm diameters is reported as approximately 0.01 m/s (DOE 1984, page 755). Deposition in complex terrain will be calculated as follows: Complex terrain 1-hour/annual gravitational dry deposition (pg/m^) = 1-hour or annual gas concentration (pg/m^) x deposition velocity (m/s) The input requirements for OBODM deposition modeling included particle size and mass distribution, median particle size, and specific gravity for calculating the gravitational settling velocity of a particle. This type of information is not available for the sources at M-136 and M-225. In the absence of available particle size information, alternate sources [(NASA, 1973) and (DOE, 1984)] of particle size information were used to establish input parameters for OBODM particulate and deposition modeling. Based on available information, a simple, but conservative approach for conducting the deposition modeling was developed based on the following assumptions: • Assumed density of 2.7 g/cm^ for particulates, which is the density of aluminum. Results from the ODOBi testing indicate aluminum to be the most abundant metal in the OB and OD emissions. • Assumed mass median particle diameter of 30.0 pm. • Assumed particle size standard deviation of 2.0 pm in order to account for a reasonable measure of size distribution variability. • Used OBODM default logarithmic particle size and mass distribution on 10 particle size categories for particulate modeling. • A separate particle bound mass distribution was created using guidance found in Section 3.2.3 of the HHRAP (U.S. EPA, 2005) in support of the human health risk assessment 031209/P 2-13 MARCH 2012 Table 2-7 provides a summary of the gravitational settling parameters that were used for particulate deposition from the M-136 and M-225 treatment unit emissions in OBODM. 2.12 RECEPTOR NETWORKS All receptors used in this modeling analysis are based on a Cartesian grid system (x,y). Two types of receptor networks were used in the anal/sis: general and discrete. A general receptor network is designed to determine the location of the maximum on-site and off-site short term and long term ground level concentrations. The discrete receptor network consists of special human or ecological receptors that are of concern to UDSHW and wilt be evaluated in the human health and ecological risk assessments. Due to the large number of general grid receptors and the OBOD limit of 100 receptors per model run, separate general grid sectors were developed for each ATK treatment unit due to their separation distance (approximately 9 km) and are illustrated in Figures 2-2 through 2-5. Each receptor is assigned a Universal Transverse Mercator (UTM) northing and easting coordinate and terrain elevation. This data was obtained from USGS Digital Elevation Maps (DEM) grids of 1:24,000 at a resolution of 1 meter. 2.12.1 General Receptor Networks The general receptor network for each treatment unit extended out to 10 km and is made up of two separate sub-networks that have different receptor spacing increments. For example, the receptor grid spacing^from the source out to a distance of 3 km is 100 meters. The receptor spacing from 3 km out to 10 km is 500 meters. There are no general grid receptors located beyond 10 km because modeling experience with OB/OD sources has shown that the maximum short term and long term impacts occur well within 10 km (usually within 3 km) of the source. In fact, the initial preliminary air dispersion modeling analysis conducted in October 2011 indicated that maximum offsite impacts from M-136 and M-225 sources occur near or within 5 kilometers for both treatment units. Due to the large separation distance between the M-136 and M-225 treatment units, separate general grid systems were established for M-136 and M-225 treatment units and included both flat terrain and complex terrain receptors. The proposed 0-3 and 3-10 km general grid networks for the M-136 and M-225 treatment units are shown in Figures 2-2 through 2-5. The general grid extending from the M-136 and M-225 treatment areas out to 3 km also includes on-site receptors. At the request of UDSHW, these receptors were used to evaluate on-site worker exposure for non-OB/OD workers located outside of the quantity-distance (Q-D) areas imposed by ATK. 031209/P 2-14 MARCH 2012 As stated previously the OBODM model has a limit of only 100 receptors per model run, which necessitates a very large number of model runs for large receptor grids. Based on the general receptor grids shown in Table 2-2 through 2-5, there are a total of more than 10,000 receptor points. In order to address all of these receptors, it was necessary to break up the 0-3 km and 3-10 km receptor grids for each treatment unit into subsector of 50 receptors or less. The assigned general grid receptor sectors for M-136 and M-225 are shown in Figures 2-2 through 2-5. 2.12.2 Discrete Receptor Network Discrete receptors are defined as special receptors that exist within and beyond the ATK boundary. These locations include the facility boundary, nearby residential dwellings, a local, dairy farm, the closest population centers, and worker exposure at commercial businesses (Autoliv). All discrete receptors, with the exception of Boundary 1 and Autoliv, are located in flat terrain. The' Boundary 1 and Autoliv receptors have elevations that are above the release elevations at M-136 and M-225. The following is a list of discrete receptors that were evaluated in this modeling analysis: • The Adam's Ranch, which is the closest domestic dwelling to M-136 and is located approximately 3 km south-southwest of M-136. • The Holmgren Ranch Pond, which is the closest domestic dwelling to M-225 and is located approximately 2 km east-southeast of M-225. • . The South Plant Administration Building and Main Manufacturing Area is an occupational receptor located approximately 2.5 km south of M-136. • The North Plant Administration Building and Main Manufacturing Area is an occupational receptor located approximately 6.5 km north of M-136. • Four facility boundary receptors that were selected based on the annual prevailing wind directions that were measured over a five-year period (1997 through 2001) at the M-245 meteorological monitoring station. Boundary 1 is a complex terrain receptor. _AII other boundary receptors are located in flat terrain. • Autoliv Facility. This is the commercial business that is located between the M-136 and M-225 treatment units. This receptor is located in complex terrain. 031209/P 2-15 MARCH 2012 • Christensen Ranch. This residential dwelling is located due north of ATK. • Blue Creek perennial stream, which runs along the western boundary of ATK. • Salt Creek Waterfowl Management area located approximately 10 km due east of M-225. • The ATK Ranch Pond, which is located approximately 14 km southwest of M-225. • Howell Dairy Farm located approximately 8 km due north ofthe ATK property boundary. • The town of Thatcher, which is located approximately 12 km east of M-136 and approximately 9 km northeast of M-225. • The town of Penrose, which is located approximately 12 km southeast of M-136 and 6 km east- northeast of M-225. All.discrete receptors, including UTM coordinates, are shown in Figure 2-6 and listed in Table 2-8. 2.13 METEOROLOGICAL DATA The meteorological data requirements for OBODM are historical hourly averages of wind speed and wind direction, atmospheric stability class, air temperature, and urban or rural mixing height These meteorological parameters represent a combination of surface and upper air data and are available from several different sources including the National Weather Service (NWS), military installations or as part of an on-site measurement program. The meteorological data used in an air dispersion modeling analysis should be selected based on spatial and climatological representativeness, as well as, the ability of the data to characterize the transport and dispersion in the area of concern. Spatial and geographical representativeness is best achieved by using validated on-site meteorological data. As a result, "site-specific" measured data is therefore preferred as modeling input (U.S. EPA, 2000), provided appropriate instrumentation and quality assurance procedures are followed and the data is compatible with the requirements of'the dispersion model. 2.13.1 Surface Data This the dispersion modeling analysis utilize five years (1997 through 2001) of on-site meteorological data collected at the ATK M-245 meteorological monitoring station. ATK operates the on-site monitoring station approximately 1.5 km southwest of the M-225 treatment unit at an elevation of about 5,000 feet 031209/P 2-16 MARCH 2012 amsl (see Figure 2-1).. The monitoring station is operated in accordance with the U.S. EPA monitoring guidance for the collection of on-site meteorological data (U.S.EPA,. 2000). The monitoring station consists of a 10-meter tower that collects the following data at the 10-meter level; Wind speed Wind direction The standard deviation of the horizontal wind (sigma theta) Temperature Relative humidity Barometric pressure; and Solar radiation The meteorological parameters used by OBODM are wind speed, wind direction, and air temperature, The data recovery statistics for these parameters in 1997 through 2001, after validation, exceeded the U.S. EPA recommended minimum criteria for an annual meteorological database. Data recovery statistics are presented in Appendix B. Wind roses showing the frequency distribution of wind direction for each year from 1997 through 2001 at the M-245 meteorological monitoring station are presented in Appendix C. 2.13.2 Upper Air Observations (Mixing Height Data) Upper air data, also known as mixing height data, is required to run OBODM. Twice daily mixing heights available from upper air sounding stations are used by the meteorological preprocessor program PCRAMMET (U.S.EPA, 1995b) to calculate hourly rural or urban mixing height for input into OBODM. Upper air sounding data is typically obtained from NWS upper air reporting stations. The number of upper air reporting stations in the United States is limited due to operational requirements and budgetary constraints. As a result, this condition can severely limit the availability of upper air reporting stations near a source. . The closest NWS upper air reporting station to ATK is located in Salt Lake City, which is about 60 miles south of ATK. The next closest NWS upper air reporting station is located in Lander, Wyoming, which is about 190 miles northeast of ATK. Although considerable site-to-site variability is possible for measurements taken close to the surface as compared to upper air measurements, the upper air sounding measurements from Salt Lake City are considered generally representative of a much larger spatial domain, which includes the northern Utah valley. 031209/P 2-17 MARCH 2012 2.13.3 Meteorological Preprocessor The surface observation and mixing height data files for each annual period were preprocessed for input into OBODM using the PCRAMMET meteorological program (U.S.EPA, 1995b), as recommended in the HHRAP guidance (U.S.EPA, 2005). PCRAMMET requires data for all input variables and will not run if data is missing within an hourly record. As a result substitution data must be used to fill data gaps. In the case of the M-245 monitoring station, opaque cloud cover and ceiling height are not measured. As a result additional meteorological data had to be acquired from a representative, local source. The first class reporting station located at Ogden Air Force Base in Ogden, Utah was selected as the local source of missing data. This reporting station is considered to be the closest, most representative and readily available site for providing substitute data based on its location relative to ATK, climatology, valley location relative to surrounding terrain, and similar land use. The Ogden reporting station is located approximately 25 miles south of ATK within the northern Utah valley. Observations missing in 1997 from the M-245 monitoring station were substituted in accordance with U.S. EPA data substitution guidance (U.S. EPA, 2000). Based on the land use analysis discussed in Section 2.4, rural mixing heights were used in this modeling analysis. 2.14 OBODM MODELING METHODOLOGY ATK completed a preliminary modeling assessment for M-136 and M-225 in October 2011 (Tetra Tech, 2011b). In this assessment, the modeling focused on determining the worst case short term and long term impact based on treatment operating hours between 1000 and 1800 hours. Restricting treatment operations can be problematic for ATK due to local climatological conditions which are not always conducive to good dispersion. The revised modeling methodology presented in this protocol is intended to give ATK the flexibility they need to conduct treatment at variable times due to the restrictive climatological conditions and also calculate the worst case impacts associated with the treatment schedules given in Tables 2-1 and 2-2. Rather than designating specific treatment hours in the OBODM model, the revised protocol evaluated the impact of M-136 and M-225 treatment units on the basis of strictly "worst case" meteorological events. The revised modeling protocol utilizes individual worst case meteorological events associated with each treatment source, and discrete and general grid maximum onsite and offsite receptors. The database of worst case events for this modeling analysis were selected from five years of onsite meteorological data' (Appendix B) for a new daily treatment time period (0600 to 1800). Applying this type of methodology is typically referred to as a "screening" assessment and is designed to determine the worst case impact at all receptors of interest regardless of the time of day. The screening procedure is a highly conservative 031209/P 2-18 MARCH 2012 technique that is designed to calculate the maximum, worst case air concentrations at a receptor location. Using this technique overestimates the environmental impact because it assumes that worst case conditions will prevail each time ATK conducts treatment during the year, when in reality it is very unlikely that this will occur. Sections 2.14.1 and 2.14.2 below describe the procedure used to evaluate the worst case impact associated with individual sources at M-136 and M-225 for discrete and general grid receptors, respectively. 2.14.1 Discrete Receptors in the case of discrete receptors, OBODM calculated the individual impact from each treatment source to each discrete receptor using the revised treatment quantities shown in Tables 2-1 and 2-2 using worst case meteorological events. OBODM produced a table of the 50 highest 1-hour ADFs and events for each source at a specific receptor for each year of onsite meteorological data. The 50 highest ADFs for each year of meteorological data were used to compile a master list of 250 worst case 1-hour events for each discrete receptor and source. A database of the 250 worst case 1-hour events for each discrete receptor and source is provided in Appendix B. The master list was then used to compile the required number of worst case annual treatment events for each source based on the annual treatment schedules shown in Tables 2-1 and 2-2 in order to calculate annual average ADFs. Meteorological data files were created for each discrete receptor based on the 250 worst case scenarios possible for five years of onsite meteorological data and used in conjunction with "hourly source strength" files to limit source treatment to the number of events for each source given in Tables 2-1 and 2-2. The maximum model type (gas, particulate, and deposition) ADF for each source and discrete receptor (see Appendices G, H, and I) were used in conjunction with individual source conservative and corrected, hourly and annual emission rates (see Appendix L) to calculate averaging period concentrations and determine compliance with short term and long term National Ambient Air Quality Standards (NAAQS). For example, M-136 Source 1 will conduct treatment twice daily, three times a week for 52 weeks, which is equivalent to 156 annual treatment events. The first treatment event conducted each day of the week will result in 156 annual treatment events as will the second daily treatment event for a total of 312 treatment events at Source 1. The master list of worst case meteorological events was used to compile a total of 156 individual worst case meteorological events to simulate the total number of annual treatment events at Source 1. Likewise, 52 individual worst case meteorological events were identified for M-136 Sources 2 and 3. Source 3 was also evaluated for the treatment of large rocket motors that will be 031209/P 2-19 MARCH 2012 conducted only 3 times per year and therefore, only requires 3 worst case meteorological events, which will be chosen from the list of 52 events for standard OB treatment at Source 3. Source 4 will conduct OD 6 times a year and will require 6 worst case meteorological events. The same procedure will be used for M-225 source impacts to discrete receptors. An example set of data files illustrating the procedure used to calculate short term and long term air concentrations for discrete receptors is presented in Appendix J. 2.14.2 General Grid Receptors The 2011 preliminary model assessment utilized a general receptor grid extending out to 10 km to determine the maximum onsite and offsite impact from each source at M-136 and M-225. Due to the OBODM limit of 100.receptors per model run, 350 individual receptor grid sectors were required to cover the entire 10 km general grid area. Individual general grid receptor maps showing the grid sectors are presented in Appendix K. The results of the preliminary assessment for M-136 and M,-225 indicated that the maximum short term impact from all four M-136 sources, for each model type (gas, particulate, and deposition) occurred within the 3 km grid network (see Figures 3-1, 3-2, 3-3, 3-4, 3-6 and 3-7). The offsite maximum impact locations were primahly located near or along the boundary of ATK property. Using the new lower treatment quantities shown in Table 2-1 and 2-2 is expected to result in lower final plume heights and maximum impacts closer to the ATK boundary and are not expected to extend out beyond 3 km. . In this modeling analysis, ATK utilized the general grid maximum onsite and offsite receptor locations identified in the 2011 preliminary modeling assessment (Tetra Tech) as the focus of the general grid modeling. The general grid maximum impact onsite and offsite locations identified in the 2011 preliminary modeling assessment (UTM coordinates and Grid Sector) for M-136 and M-225 sources and each model type are summarized in Tables 2-9 and 2-10, respectively. In the case of the maximum onsite and offsite general grid receptors identified in Tables 2-9 and 2-10 from the preliminary model analysis in October 2011 (Tetra Tech, 2011), OBODM was used to model the individual impact from each treatment source to each general grid maximum receptor sector using the revised treatment quantities shown in Tables 2-1 and 2-2 for each year of meteorological data. In doing so, OBODM produced a table of the 50 highest 1-hour ADFs and events for each source at each general grid maximum receptor. The 50 highest ADFs for each year of meteorological data were used to compile a master list of 250 worst case events for each sector and source. The master list was then used to compile the required number of worst case annual treatment events for each source based on the annual treatment schedules shown in Tables 2-1 and 2-2, in order to calculate 031209/P 2-20 MARCH 2012 annual average ADFs. The OBODM annual average modeling for each treatment source included the maximum impact sector plus all adjacent sectors out to a distance of 1 km from the maximum impact receptor sector. This methodology was used to facilitate the preparation of ADF iso-contours for these general grid maximum impact areas. The proposed adjacent grid sectors for each treatment source and model type are presented in Tables 2-9 and 2-10. The model type (gas, particulate, and deposition) ADFs for each source and general grid receptor are presented in Appendices G, H, and I. The 1-hour and annual average ADF for each source and general grid receptor was used in conjunction with individual source conservative and corrected, hourly and annual emission rates (see Appendix L) to calculate averaging period concentrations and determine compliance with short term and long term National Ambient Air Quality Standards (NAAQS) and onsite OSHA 8-hour exposure concentration criteria to evaluate on-site worker exposure at the predicted maximum on-site receptor for each treatment unit The 1-hour air concentrations were used to estimate air concentrations for longer averaging periods using USEPA established persistent factors to convert 1-hour averages to other averaging periods. For example, the 2011 preliminary gas modeling assessment (Tetra Tech) determined the general grid maximum impact sector for M-136 Source 1 to occur within the 3 km sector 36C3A (see Table 5-8). This sector was used to model the individual impact from each treatment source to compile a list of 50 worst case events for each year of meteorological data. The worst case events were based on the operating hours 0600 to 1800 for each year of meteorological data. The 50 highest 1-hour ADFs for each year of meteorological data within sector 36C3A were then compiled into a master list of 250 worst case events forthe purpose of calculating annual average impacts. In the case of maximum impact receptor 36C3A, the annual average modeling will include sector 36C3A, plus the sectors 36C3B, 36F3D, 36F3A, 36F30, 36F10B, and 36F10H (see Table 5-8). It is important to note the selection of adjacent sectors included the selection of adjacent 10 km sectors when the maximum 3 km sector occurred on the outer boundary of the 3 km general grid. This situation occurred for the general grid maximum offsite gas model impacts associated with M-136 sources 1, 2, and 3 (see Table 2-8) and M-225 Sources 1 and 2 (see Table 2-9). The OBODM "houriy source file" option was used to calculate annual average ADFs on the basis of worst case meteorological conditions for each source and model type. The same procedure will be used for M-225 source impacts to general grid receptors. An example set of data files illustrating the procedure used to calculate short term and long term air concentrations for discrete receptors is presented in Appendix J. 031209/P 2-21 TABLE 2-1 M-136 TREATMENT UNIT SOURCES, WASTES TREATED, MODELED TREATMENT QUANTITIES PER EVENT, TREATMENT SCHEDULE AND APPLICABLE EMISSION FACTORS ATK PROMONTORY, UTAH Modeled Sources Burn Statlon(s) Treated Reactive Waste Categories Modeled Per Event Treatment Quantity Treatment Events Per Day Per Month or Year Total Treatment Events Per Year Total Annual Burn Limit (lbs.) Applicable Emission Factors For Wastes Treated At Each Source* Source 1 Open Burn 1,2,3,4,5,6,7, 8,9,10,11,12 A, B, C, D, E, F, G, H 12,000 lbs. 2 events per day, 3 days per week 312 3,744,000 1.3 - see Tables 3-5 and 3-6 Source 2 Open Burn 13 A, B, C, D, E, F, G, H 10,000 lbs. Once per week 52 •520,000 1.3 - see Tables 3-5 and 3-6 Source 3 Open Burn 14 A, B, C, D 10,000 lbs. Once per week 52 520,000 1.3 - see Tables 3-5 and 3-6 Source 4 Open Detonation 13&14 C, D, G, H 600 lbs. Once every 2 months 6 3,600 1.3 - see Tables 3-5 and 3-6 Source 5 Open Burn 14 Large Rocket Motors 26,000 lbs. 3 per year 3 78,000 1.3 - see Tables 3-5 and 3-6 ATK has agreed to use 1.3 OBODi emission factors for all M-136 modeled sources. TABLE 2-2 M-225 TREATMENT UNIT SOURCES, WASTES TREATED, MODELED TREATMENT QUANTITIES PER EVENT, TREATMENT SCHEDULE AND APPLICABLE EMISSION FACTORS ATK PROMONTORY, UTAH Treated Modeled Treatment Total Total Applicable Emission Modeled Burn Reactive Per Event Events Per Treatment Annual Factors For Wastes Sources Station(s) Waste Treatment Month Events Per Burn Limit Treated At Each Categories Quantity Year (lbs.) Source* Source 1 Open Burn 1,2,3,4 A, B, C, D, E, F, G, H 2,000 lbs. 2 events per month 24 48,000 1.3 - see Tables 3-5 and 3-6 Source 2 Open Detonation 1 C, D, G, H 400 lbs. Once every two months 6 2,400 1.3 - see Tables 3-5 and 3-6 ATK has agreed to use 1.3 OBODi emission factors for all M-225 modeled sources. TABLE 2-3 M-136 SOURCE PARAMETERS ATK PROMONTORY, UTAH Source Parameter Source 1 - OB Source 2 - OB Source 3 - OB Source 4 - OD Source 5-OB Treatment Operation OB in Pans Burn Stations 1-12 OB in Pans Burn Station 13 OB in Pans Burn Stations 14 OD in Pits Burn Stations 14 OB of Rocket Motors Burn Station 14 Location Center of Bum Station Center of Burn Station Center of Burn Station Center of Burn Station Center of Burn Station Number of sources 1 1 1 1 1 Source Release Type Quasi-continuous Quasi-continuous Quasi-continuous Instantaneous Quasi-continuous Burn/Release Duration (OBODM calculated based on source type) 300 seconds .300 seconds 300 seconds Instantaneous 300 seconds Source Configuration Volume Volume Volume Volume Volume Effective Release Height (m) 1 meter 1 meter 1 meter Ground level 1 meter 1.3 waste heat content 1,471 calories/gram 1,471 calories/gram 1,471 calories/gram 1,471 calories/gram 1,471 calories/gram Unit emission factor 1.0 1.0 1.0 1.0 1.0 TABLE 2-4 M-225 SOURCE PARAMETERS ATK PROMONTORY, UTAH Source Parameter Source 1 Source 2 Treatment Operations OB in Pans OD in pits Location Center of M-225 Unit Center of M-225 Unit Number of sources 1 1 Source Release Type Quasi-continuous Instantaneous Burn/Release Duration (OBODM calculated based on source type) 300 seconds Instantaneous Source Configuration Volume Volume Effective Release Height (m) 1 meter Ground level Source Diameter NA 1.5 meters 1.3 waste heat content 1,471 calories/gram 1,471 calories/gram TABLE 2-5 1.3 CLASS WASTE MATERIAL "CONSERVATIVE" MAXIMUM EMISSION FACTORS (LBS/LB) ATK PROMONTORY, UTAH PAGE 1 OF 7 Analyte Maximum Emission Factor (lbs/lb) Particulates TSP 1.5E-01 PMIO 1.2E-01 PM2.5 6.0E-02 Metals Aluminum 4.0E-02 Antimony 2.9E-05 Arsenic 5.5E-07 Barium 9.8E-06 Cadmium 6.1E-07 Chromium 2.0E-05 Cobalt 6.1E-07 Copper 2.5E-05 Lead 4.1E-05 Magnesium 8.2E-05 Manganese 9.4E-05 Mercury 7.4E-08 Nickel 5.8E-05 Phosphorus 1.1E-G4 Selenium 1.6E-06 Silver 1.2E-G6 Thallium 4.3E-06 Zinc 3.5E-05 Perchlorate 4.9E-07 SVOCs 1,2,4,5-Tetrachlorobenzene 5.5E-07 1,2,4-Trichlorobenzene 6.5E-07 1,2-Dichlorobenzene 5.6E-07 1,3,5-Trinitrobenzene 5.5E-07 1,3-Dichlorobenzene 6.2E-07 1,3-Dinitrobenzene 5.7E-07 1,4-Dichlorobenzene 5.8E-07 1 -Chloronaphthalene 5.5E-07 1-Naphthylamine l.lE-05 2,3,4,6-Tetrachlorophenol 7.1E-07 2,4,5-Trichlorophenol 1.4E-06 2,4,6-Trichlorophenol 1.3E-06 2,4-Dichlorophenol 9.3E-07 2,4-Dimethylphenol 6.9E-06 2,4-Dinitrophenol 2.4E-05 2,4-Dinitrotoluene 5.5E-07 2,6-Dichlorophenol 5.5E-07 TABLE 2-5 1.3 CLASS WASTE MATERIAL "CONSERVATIVE" MAXIMUM EMISSION FACTORS (LBS/LB) ATK PROMONTORY, UTAH PAGE 2 OF 7 Analyte Maximum Emission Factor (lbs/lb) 2,6-Dinitrotoluene 5.6E-07 2-Acetylaminofluorene 5.5E-07 2-Chloronaphthalene 5.5E-07 2-Chlorophenol 1.9E-06 2-Methylnaphthalene 3.6E-06 2-Methylphenol 3.3E-06 2-Naphthylamine l.lE-05 2-Nitroaniline 5.5E-07 2-Nitrophenol 5.5E-07 3,3'-Dichlorobenzidine 8.1E-06 3,3'-Dimethylbenzidine 5.5E-05 3-Methylcholanthrene 5.5E-07 3-Methylphenol & 4-Methylphenol 2.2E-06 3-Nitroaniline 2.2E-06 4,6-Dinitro-2-methylphenol 9.5E-06 4-Aminobiphenyl l.lE-05 4-Bromophenyl phenyl ether 5.5E-07 4-Chloro-3-methylphenol 6.8E-07 4-Chloroaniline 6.6E-06 4-Nitroaniline 2.2E-06 4-Nitrophenol 3.6E-06 7,12-Dimethylbenz(a)anthracene 5.6E-07 Acenaphthene 5.5E-07 Acenaphthylene 5.5E-07 Acetophenone 2.7E-06 Aniline 8.0E-06 Anthracene 5.5E-07 Benzidine 5.6E-05 Benzo(a)anthracene 6.4E-07 Benzo(a)pyrene 5.5E-07 Benzo(b)fluoranthene 1.2E-06 Benzo(ghi)perylene 6.8E-07 Benzo(k)fluoranthene 1.8E-06 Benzoic acid 6.2E-05 Benzyl alcohol 3.8E-05 bis(2-Chloroethoxy)methane 5.5E-07 bis(2-Chloroethyl) ether 6.1E-07 bis(2-Chloroisopropyl) ether 8.3E-07 bis(2-Ethylhexyl) phthalate l.lE-05 Butyl benzyl phthalate 6.7E-07 Carbazole 7.0E-07 Chrysene 7.0E-07 Dibenz(a,h)anthracene 6.6E-07 Dibenzofuran 5.5E-07 Diethyl phthalate 8.0E-07 « TABLE 2-5 -; 1.3 CLASS WASTE MATERIAL "CONSERVATIVE" MAXIMUM EMISSION FACTORS (LBS/LB) ATK PROMONTORY, UTAH PAGE 3 OF 7 Analyte Maximum Emission Factor (lbs/lb) Dimethyl phthalate 5.5E-07 Di-n-butyl phthalate l.lE-05 Di-n-octyl phthalate 3.7E-06 Diphenylamine 5.5E-07 Ethyl methanesulfonate 5.5E-07 Fluoranthene 5.9E-07 Fiuorene 5.5E-07 Hexachlorobenzene 4.7E-06 Hexachlorobutadiene 8.1E-07 Hexachlorocydopentadiene l.lE-05 Hexachloroethane 5.9E-07 Hexachioropropene 7.9E-07 lndeno(1,2,3-cd)pyrene 5.9E-07 Isophorone 5.5E-07 Methyl methanesulfonate 6.0E-07 Naphthalene 1.4E-05 Nitrobenzene 6.2E-07 N-Nitro-o-toluidine 8.8E-06 N-Nitrosodiethylamine 5.5E-07 N-Nitrosodimethylamine 5.5E-07 N-Nitrosodi-n-butylamine 5.5E-07 N-Nitrosodi-n-propylamine 5.5E-07 N-Nitrosodiphenylamine 9.5E-07 N-Nitrosomethylethylamine 9.1E-07 N-Nitrosomorpholine 5.5E-07 o-Toluidine 7.0E-06 p-Dimethylaminoazobenzene 5.5E-07 Pentachlorobenzene 5.5E-07 Pentachloroethane 5.5E-07 Pentachloronitrobenzene 5.5E-07 Pentachlorophenol 2.7E-05 Phenanthrene 7.0E-07 Phenol 2.4E-06 Pyrene 5.8E-07 Pyridine 8.1E-07 DIoxIns/Furans 2,3,7,8-TCDD 2.3E-12 1,2,3,7,8-PeCDD 6.7E-12 1,2,3,4,7,8-HxCDD 3.5E-12 1,2,3,6,7,8-HxCDD 8.9E-12 1,2,3,7,8,9-HxCDD 6.1E-12 1,2,3,4,6,7,8-HpCDD 2.9E-11 OCDD 3.7E-11 2,3,7,8-TCDF 4.0E-11 TABLE 2-5 1.3 CLASS WASTE MATERIAL "CONSERVATIVE" MAXIMUM EMISSION FACTORS (LBS/LB) ATK PROMONTORY, UTAH PAGE 4 OF 7 Analyte Maximum Emission Factor (lbs/lb) 1,2,3,7,8-PeCDF 8.0E-11 2,3,4,7,8-PeCDF 1.6E-10 1,2,3,4,7,8-HxCDF 2.6E-10 1,2,3,6,7,8-HxCDF 1.6E-10 2,3,4,6,7,8-HxCDF 1.9E-10 1,2,3,7,8,9-HxCDF 1.2E-10 1,2,3,4,6,7,8-HpCDF 7.3E-10 1,2,3,4,7,8,9-HpCDF 1.9E-10 OCDF 5.3E-10 Carbonyls 2,5-Dimethylbenzaldehyde 2.7E-05 Acetaldehyde 9.3E-05 Acetone 3.1E-05 Benzaldehyde 1.4E-05 Crotonaldehyde 1.4E-05 Formaldehyde 4.7E-05 Hexanal 1.4E-05 Isopentanal 1.4E-05 m,p-Tolualdehyde 1.4E-05 MEK/Butyraldehydes 1.4E-05 o-Tolualdehyde 4.0E-05 Pentanal 1.7E-05 Propanal 5.2E-05 HCI/CI2/NH3 HCI 1.8E-02 CI2 1.2E-02 NHS 3.2E-05 HCN 2.2E-05 VOCs TNMOC 9.4E-04 1,1,1-Trichloroethane 8.9E-07 1,1,2,2-Tetrachloroethane 4.2E-07 1,1,2-Trichloroethane 7.3E-07 1,1 -Dichloroethane 3.2E-07 1,1-Dichloroethene 4.3E-07 1,2,3-Trimethylbenzene 4.2E-07 1,2,4-Trichlorobenzene 1.3E-06 1,2,4-Trimethylbenzene 5.2E-06 1,2-Dibromomethane (EDB) 8.9E-07 1,2-Dichlorobenzene 4.8E-07 1,2-Dichloroethane 5.4E-07 TABLE 2-5 1.3 CLASS WASTE MATERIAL "CONSERVATIVE" MAXIMUM EMISSION FACTORS (LBS/LB) ATK PROMONTORY, UTAH PAGE 5 OF 7 Analyte Maximum Emission Factor (lbs/lb) 1,2-Dichloropropane 3.7E-07 1,3,5-Trimethylbenzene 2.0E-06 1,3-Butadiene 2.4E-05 1,3-Dichlorobenzene 4.4E-07 1,3-Diethylbenzene 5.0E-07 1,4-Dichlorobenzene 7.3E-07 1,4-Diethylbenzene 6.7E-07 1,4-Dioxane 6.4E-07 1-Butene 2.2E-05 1-Hexene 2.0E-G5 1-Pentene 1.2E-05 2,2,4-Trimethylpentane 2.3E-06 2,2-Dimethylbutane 8.8E-07 2,3,4-Trimethylpentane 2.8E-07 2,3-Dlmethylbutane 2.9E-06 2,3-Dimethylpentane 2.7E-06 2,4-Dimethylpentane l.lE-06 2-Butanone (MEK) 3.9E-06 2-Ethyltoluene 4.5E-07 2-Hexanone 8.7E-07 2-Methylheptane 2.7E-06 2-Methylhexane 4.4E-06 2-Methylpentane l.lE-05 2-Nltropropane 2.8E-06 2-Propanol 3.0E-07 3-Chloropropene 4.7E-06 3-Ethyltoluene 4.8E-06 3-Methylheptane 3.5E-06 3-Methylhexane 5.2E-06 3-Methylpentane 7.1E-06 4-Ethyltoluene 5.3E-06 4-Methyl-2-pentanone 7.0E-07 Acetone 2.4E-05 Acetonitrile 1.9E-05 Acetylene 9.4E-05 Acrylonitrile 1.6E-05 alpha-Chlorotoluene 5.7E-07 Benzene 4.7E-05 Bromodichloromethane 7.8E-07 Bromoform 1.3E-06 Bromomethane 6.2E-07 Butane 1.8E-05 Carbon Disulfide 9.8E-06 Carbon Tetrachloride 1.5E-05 Chloroacetonitrile l.lE-06 TABLE 2-5 1.3 CLASS WASTE MATERIAL "CONSERVATIVE" MAXIMUM EMISSION FACTORS (LBS/LB) ATK PROMONTORY, UTAH PAGE 6 OF 7 Analyte Maximum Emission Factor (lbs/lb) Chlorobenzene 2.5E-06 Chloroethane 2.6E-07 Chloroform 6.1E-06 Chloromethane 1.4E-05 cis-1,2-Dichloroethene 4.6E-07 cis-1,3-Dichloropropene 1.3E-06 cis-2-Butene 1.7E-06 cis-2-Pentene 3.3E-07 Cumene 4.2E-07 Cyclohexane 2.5E-06 Cyclopentane 1.8E-06 Decane 1.7E-05 Dibromochloromethane 8.8E-07 Ethane 2.1E-05 Ethanol 1.6E-06 Ethene 1.8E-04 Ethyl benzene 2.8E-06 Ethyl ether 2.5E-06 Ethyl Methacrylate 1.6E-06 Heptane 7.2E-06 Hexachlorobutadiene 1.7E-06 Hexane 9.8E-06 Isobutane 2.8E-06 Isopentane 2.0E-05 m,p-Xylene l.lE-05 Methacrylonitrile 4.9E-06 Methyl Acrylate 1.2E-06 Methyl Methacrylate 1.6E-06 Methyl tert-butyl ether 4.2E-07 Methylcyclohexane 6.1E-06 Methylcyclopentane 5.6E-06 Methylene chloride 7.1E-06 n-Butylchloride 1.2E-05 Nonane 1.3E-05 Octane 7.5E-06 o-Xylene 3.5E-06 Pentane 1.9E-05 Propane 8.7E-G6 Propylbenzene 1.GE-G6 Propylene 4.9E-G5 Styrene 9.9E-G7 Tetrachloroethene 2.5E-G6 Tetrahydrofuran 9.GE-07 Toluene 1.9E-G5 trans-1,2-Dichloroethene 7.2E-07 TABLE 2-5 1.3 CLASS WASTE MATERIAL "CONSERVATIVE" MAXIMUM EMISSION FACTORS (LBS/LB) ATK PROMONTORY, UTAH PAGE 7 OF 7 Analyte Maximum Emission Factor (lbs/lb) trans-1,3-Dichloropropene 6.1E-07 trans-2-butene 7.7E-G6 trans-2-Pentene 1.7E-06 Trichloroethene 9.4E-G7 Undecane 1.2E-05 Vinyl chloride 7.6E-G6 CEM C02 7.2GE-01 CO 6.40E-03 NOX 6.4GE-G3 S02 5.GGE-04 Highlighted analytes were not detected during the Bang Box testing program HCN - hydrogen cyanide SVOCs - semi-volatile organic compounds VOCs - volatile organic compounds HCL - hydrogen chloride NOX - nitrogen oxide 502 - sulfur dioxide CO - carbon monoxide C02 - carbon dioxide TNMOC-total non-methane organic carbon — OCDD - 1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin OCDF - 1,2,3,4,6,7,8,9-Octachlorodibenzo-p-furan CL2 - chlorine NHS-ammonia TSP - Total suspended particulates PMIO - particulate matter less than 10 microns in aerodynamic diameter PM2.5 - particulate matter less than 2.5 microns in aerodynamic diameter TABLE 2-6 1.3 CLASS WASTE MATERIAL "CORRECTED" EMISSION FACTORS (LBS/LB) ATK PROMONTORY, UTAH PAGE 1 OF 7 Analyte Emission Factor (lbs/lb) Particulates TSP 1.4E-G1 PMIO 8.6E-G2 PM2.5 5.9E-G2 Metals Aluminum 4.GE-G2 Antimony 2.9E-05 Arsenic S.GE-07 Barium 4.9E-06 Cadmium S.1E-07 Chromium 2.GE-05 Cobalt 3.1E-07 Copper 2.5E-05 Lead S.4E-05 Magnesium 2.9E-05 Manganese 9.3E-05 Mercury 3.7E-G8 Nickel 5.8E-G5 Phosphorus 1.0E-G4 Selenium 1.7E-06 Silver 9.5E-07 Thallium 2.1E-G6 Zinc 3.5E-05 Perchlorate 2.5E-07 SVOCs 1,2,4,5-Tetrachlorobenzene 2.7E-07 1,2,4-Trichlorobenzene 3.2E-07 1,2-Dichlorobenzene 2.8E-07 1 ,S,5-Trinitrobenzene 2.7E-07 1 ,S-Dichlorobenzene 3.1E-07 1 ,S-Dinitrobenzene 2.8E-07 1,4-Dichlorobenzene 2.9E-07 1 -Chloronaphthalene 2.7E-07 1-Naphthylamine 5.5E-G6 2,3,4,6-Tetrachlorophenol S.6E-07 2,4,5-Trichlorophenol 7.1E-07 2,4,6-Trichlorophenol #REF! 2,4-Dichlorophenol 9.SE-G7 2,4-Dimethylphenol S.5E-06 2,4-Dinitrophenol 1.2E-05 2,4-Dinitrotoluene S.1E-07 2,6-Dichlorophenol 4.0E-07 TABLE 2-6 1.3 CLASS WASTE MATERIAL "CORRECTED" EMISSION FACTORS (LBS/LB) ATK PROMONTORY, UTAH PAGE 2 OF 7 Analyte Emission Factor (lbs/lb) 2,6-Dinitrotoluene 5.6E-07 2-Acetylaminofluorene 2.7E-07 2-Chloronaphthalene 2.7E-07 2-Chlorophenol 1.9E-06 2-Methylnaphthalene S.6E-06 2-Methylphenol 1.6E-06 2-Naphthylamine 5.5E-G6 2-Nitroaniline 2.7E-07 2-Nitrophenol 3.9E-07 S,3'-Dichlorobenzidine 4.1E-06 S,S'-Dimethylbenzidine 2.7E-05 S-Methylcholanthrene 2.7E-07 3-Methylphenol & 4-Methylphenol 1.1E-06 3-Nitroaniline 1.1E-06 4,6-Dinitro-2-methylphenol 4.8E-06 4-Aminobiphenyl 5.5E-06 4-Bromophenyl phenyl ether 2.7E-07 4-Chloro-S-methylphenol S.4E-07 4-Chloroaniline S.SE-06 4-Nitroaniline 1.1E-06 4-Nitrophenol 1.8E-06 7,12-Dimethylbenz(a)anthracene 2.8E-07 Acenaphthene 2.7E-07 Acenaphthylene 2.7E-07 Acetophenone 2.7E-06 Aniline 4.0E-06 Anthracene 2.7E-07 Benzidine 2.8E-05 Benzo(a)anthracene S.2E-07 Benzo(a)pyrene 2.7E-07 Benzo(b)fluoranthene 6.0E-07 Benzo(ghi)perylene S.4E-07 Benzo(k)fluoranthene 8.8E-07 Benzoic acid 6.2E-05 Benzyl alcohol 1.9E-05 bis(2-Chloroethoxy)methane 2.7E-07 bis(2-Chloroethyl) ether S.1E-07 bis(2-Chloroisopropyl) ether 4.2E-07 bis(2-Ethylhexyl) phthalate 5.5E-G6 Butyl benzyl phthalate 3.SE-07 Carbazole 3.5E-07 Chrysene 3.5E-07 Dibenz(a,h)anthracene 3.3E-07 Dibenzofuran 2.7E-07 Diethyl phthalate 4.GE-G7 TABLE 2-6 ! 1.3 CLASS WASTE MATERIAL "CORRECTED" EMISSION FACTORS (LBS/LB) ATK PROMONTORY, UTAH PAGE 3 OF 7 I Analyte Emission Factor (lbs/lb) Dimethyl phthalate 2.7E-07 Di-n-butyl phthalate 5.5E-06 Di-n-octyl phthalate 3.7E-06 Diphenylamine 2.7E-07 Ethyl methanesulfonate 2.7E-07 Fluoranthene 4.0E-07 Fiuorene 4.2E-07 Hexachlorobenzene 4.7E-06 Hexachlorobutadiene 4.1E-07 Hexachlorocydopentadiene 5.5E-06 Hexachloroethane 3.0E-07 Hexachioropropene 3.9E-07 lndeno(1,2,S-cd)pyrene 3.0E-07 Isophorone 2.7E-07 Methyl methanesulfonate 3.GE-07 Naphthalene 1.3E-05 Nitrobenzene 3.1E-07 N-Nitro-o-toluidine 4.4E-06 N-Nitrosodiethylamine 2.7E-07 N-Nitrosodimethylamine 2.7E-07 N-Nitrosodi-n-butylamine 2.7E-07 N-Nitrosodi-n-propylamine 2.7E-07 N-Nitrosodiphenylamine 4.8E-07 N-Nitrosomethylethylamine 4.5E-07 N-Nitrosomorpholine 2.7E-07 o-Toluidine 3.5E-06 p-Dimethylaminoazobenzene 2.7E-07 Pentachlorobenzene 3.0E-07 Pentachloroethane 2.7E-07 Pentachloronitrobenzene 2.7E-07 Pentachlorophenol 1.4E-05 Phenanthrene 7.GE-07 Phenol 2.1E-06 Pyrene 2.9E-07 Pyridine 4.1E-07 DIoxins/Furans 2,3,7,8-TCDD 1.3E-12 1,2,3,7,8-PeCDD 6.7E-12 1,2,3,4,7,8-HxCDD 3.4E-12 1,2,3,6,7,8-HxCDD 8.9E-12 1,2,3,7,8,9-HxCDD 6.1E-12 1,2,3,4,6,7,8-HpCDD 2.9E-11 OCDD 3.7E-11 2,3,7,8-TCDF 4.0E-11 TABLE 2-6 1.3 CLASS WASTE MATERIAL "CORRECTED" EMISSION FACTORS (LBS/LB) ATK PROMONTORY, UTAH PAGE 4 OF 7 Analyte Emission Factor (lbs/lb) 1,2,3,7,8-PeCDF 8.GE-11 2,3,4,7,8-PeCDF 1.6E-10 1,2,3,4,7,8-HxCDF 2.6E-10 1,2,3,6,7,8-HxCDF 1.6E-1G 2,3,4,6,7,8-HxCDF 1.9E-10 1,2,3,7,8,9-HxCDF 1.2E-10 1,2,3,4,6,7,8-HpCDF 7.3E-1G 1,2,3,4,7,8,9-HpCDF 1.9E-10 OCDF 5.2E-10 Carbonyls 2,5-Dimethylbenzaldehyde 1.4E-G5 Acetaldehyde 7.5E-05 Acetone 1.5E-05 Benzaldehyde 7.3E-06 Crotonaldehyde 6.8E-06 Formaldehyde 4.0E-05 Hexanal 8.2E-06 Isopentanal 6.8E-06 m,p-Tolualdehyde 6.8E-06 MEK/Butyraldehydes 1.2E-05 o-Tolualdehyde 2.3E-05 Pentanal 1.2E-05 Propanal 3.8E-05 HCI/CI2/NH3 HCI 1.8E-G2 012 1.5E-03 NH3 2.2E-05 HCN 1.2E-05 VOCs TNMOC 8.1 E-04 1,1,1-Trichloroethane 4.5E-07 1,1,2,2-Tetrachloroethane 2.1E-07 1,1,2-Trichloroethane 3.6E-07 1,1-Dichloroethane 1.6E-07 1,1-Dichloroethene 2.2E-07 1,2,3-Trimethylbenzene 2.1E-07 1,2,4-Trichlorobenzene 6.3E-07 1,2,4-Trimethylbenzene 5.2E-06 1,2-Dibromoethane (EDB) 4.4E-07 1,2-Dichlorobenzene 2.4E-07 1,2-Dichloroethane 2.7E-G7 TABLE 2-6 1.3 CLASS WASTE MATERIAL "CORRECTED" EMISSION FACTORS (LBS/LB) ATK PROMONTORY, UTAH PAGE 5 OF 7 Analyte Emission Factor (lbs/lb) 1,2-Dichloropropane 1.8E-G7 1,3,5-Trimethylbenzene 2.0E-G6 1,3-Butadiene 2.0E-05 1,3-Dichlorobenzene 2.2E-07 1,3-Diethylbenzene 2.5E-07 1,4-Dichlorobenzene 3.7E-07 1,4-Diethylbenzene 3.3E-G7 1,4-Dioxane 3.2E-G7 1-Butene 2.1E-05 1-Hexene 2.GE-05 1-Pentene 1.2E-05 2,2,4-Trimethylpentane 2.3E-G6 2,2-Dimethylbutane 4.4E-G7 2,3,4-Trimethylpentane 1.4E-07 2,3-Dimethylbutane 2.9E-G6 2,3-Dimethylpentane 2.7E-06 2,4-Dimethylpentane 5.5E-07 2-Butanone (MEK) 3.9E-06 2-Ethyltoluene 2.2E-07 2-Hexanone 4.4E-07 2-Methylheptane 2.7E-06 2-Methylhexane 4.4E-06 2-Methylpentane 5.3E-06 2-Nitropropane 2.8E-06 2-Propanol 1.5E-07 3-Chloropropene 4.7E-06 3-Ethyltoluene 4.8E-06 3-Methylheptane 3.5E-06 3-Methylhexane 5.2E-06 3-Methylpentane 7.1E-06 4-Ethyltoluene 5.3E-06 4-Methyl-2-pentanone 3.5E-07 Acetone 2.3E-05 Acetonitrile 9.2E-06 Acetylene 7.4E-05 Acrylonitrile 1 .OE-05 alpha-Chlorotoluene 2.8E-07 Benzene 4.4E-05 Bromodichloromethane 3.9E-07 Bromoform 6.3E-07 Bromomethane 3.1E-07 Butane 1.8E-G5 Carbon Disulfide 9.4E-06 Carbon Tetrachloride 1.5E-G5 Chloroacetonitrile 5.6E-07 TABLE 2-6 1.3 CLASS WASTE MATERIAL "CORRECTED" EMISSION FACTORS (LBS/LB) ATK PROMONTORY, UTAH PAGE 6 OF 7 Analyte Emission Factor (lbs/lb) Chlorobenzene 2.5E-06 Chloroethane 1.3E-07 Chloroform 6.1E-06 Chloromethane 1.4E-05 cis-1,2-Dichloroethene 2.3E-07 cis-1,3-Dichloropropene 1.3E-06 cis-2-Butene 1.4E-06 cis-2-Pentene 1.7E-07 Cumene 2.1E-07 Cyclohexane 2.5E-G6 Cyclopentane 1.8E-G6 Decane 1.7E-G5 Dibromochloromethane 4.4E-07 Ethane 1.7E-05 Ethanol 1.6E-06 Ethene 1.5E-04 Ethyl Benzene 2.8E-06 Ethyl Ether 1.2E-06 Ethyl Methacrylate 7.8E-07 Heptane 7.2E-06 Hexachlorobutadiene 8.5E-07 Hexane 9.8E-06 Isobutane 2.8E-G6 Isopentane 2.0E-05 m,p-Xylene 1.0E-G5 Methacrylonitrile 4.9E-G6 Methyl Acrylate 5.9E-07 Methyl Methacrylate 8.1E-07 Methyl tert-butyl ether 2.1E-07 Methylcyclohexane 6.1E-06 Methylcyclopentane 5.6E-06 Methylene Chloride 7.1E-06 n-Butylchloride 5.8E-06 Nonane 1.3E-05 Octane 7.5E-06 o-Xylene 3.5E-06 Pentane 1.9E-05 Propane 8.7E-06 Propylbenzene 1 .GE-06 Propylene 4.3E-05 Styrene 9.9E-G7 Tetrachloroethene 2.5E-G6 Tetrahydrofuran 6.4E-G7 Toluene 1.8E-05 trans-1,2-Dichloroethene 3.6E-07 TABLE 2-6 1.3 CLASS WASTE MATERIAL •CORRECTED" EMISSION FACTORS (LBS/LB) ATK PROMONTORY, UTAH PAGE 7 OF 7 Analyte Emission Factor (lbs/lb) trans-1,3-Dichloropropene 3.GE-07 trans-2-butene 7.7E-06 trans-2-Pentene 1.7E-06 Trichloroethene 9.4E-07 Undecane 1.2E-05 Vinyl Chloride 7.6E-G6 CEM C02 6.9E-01 CO 4.7E-03 NOX 5.8E-03 S02 4.1 E-04 Highlighted analytes were not detected during the Bang Box testing program HCN - hydrogen cyanide SVOCs - semi-volatile organic compounds VOCs - volatile organic compounds HCL - hydrogen chloride NOX - nitrogen oxide S02 - sulfur dioxide CO - carbon monoxide 002 - carbon dioxide TNMOC - total non-methane organic carbon OCDD -1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin OCDF -1,2,3,4,6,7,8,9-Octachlorodibenzo-p-furan CL2 - chlorine NHS - ammonia TSP - Total suspended particulates PMIO - particulate matter less than 10 microns in aerodynamic diameter PM2.5 - particulate matter less than 2.5 microns in aerodynamic diameter TABLE 2-7 SUMMARY OF DEPOSITION MODELING PARAMETERS ATK PROMONTORY, UTAH Parameter Particulate/Deposition Phase Emission Surrogate Aluminum (density of 2.7 g/cm^) Emission Factor 1.0 Non-gravitational dry deposition No Gravitational settling Yes Mean particle diameter 30 i^m Particle size standard deviation 2.0 Number of particle size classes 10 Cloud depletion Yes OBODM Output Deposition rate (ng/m^) TABLE 2-8 ATK MODELING ANALYSIS DISCRETE RECEPTORS ATK LAUNCH SYSTEMS PROMONTORY, UTAH Discrete Receptor Name UTM Coordinate Easting Northing Elevation m m m ft ATK Ranch Pond 376670 4599479 1291 4235.564 Boundary #2 379669 4612480 1321 4333.99 Adams Ranch 378256 4613483 1355 4445.538 Blue Creek 379972 4615666 1341 4399.606 Christensen Ranch 381372 4622166 1371 4498.032 Autoliv (complex terrain) 381675 4613810 1480 4855.643 Big Bear River Bird Refuge 382669 4599480 1284 4212,598 Boundary #4 386872 4608166 1295 4248.688 Boundary #3 387872 4610166 1385 4543.963 Holmgren Ranch 388372 4608666 1295 4248.688 Salt Creek Waterfowl Management Area 395169 4611480 1296 4251.969 Thatcher 392321 4616597 1319 4327.428 Penrose 391627 4611823 1300 4265.092 Boundary #1 (complex terrain) 382669 4616480 1542 5059.055 North Plant Mam Administration Building and Mam Manufacturing Area 381140 4619873 1375 4511.155 South Plant Mam Administration Building and Mam Manufacturing area 380488 4613356 1362 4468.504 Howell Dairy 380309 4627652 1388 4553.806 TABLE 2-9 M-136 MAXIMUM GENERAL GRID ONSITE/OFFSITE RECEPTORS AND ASSOCIATED GRID SECTORS ATK LAUNCH SYSTEMS PROMONTORY, UTAH Maximum Short Term Impact Offsite Receptor Maximum Short Term Impact Onsite Receptor Surrounding Sectors Within 1 KM of Maximum Onsite Receptor Source - Model Easting Northing Grid Sector Surrounding Sectors Within - 1 KM of Maximum Offsite Receptor Source - Model Easting Northing Grid Sector Surrounding Sectors Within 1 KM of Maximum Onsite Receptor 1 - Gas 378172 4618166 36C3A 36C3B, 36F3D, 36F3A, 36F30, 36F10B, 36F10H 1 - Gas 380472 4615766 36F3H 36F3F, 36F3G, 36C3M, 36C30 2-Gas 378772 4617766 36C3A 36C3B, 36F3D, 36F3A, 36F30, 36F10B 2-Gas 380772 4615766 36F3H 36F3F, 36F3G, 36C3M, 36C30 3 - Gas 378472 4618366 36C3A 36C3B, 36F3D, 36F3A, 36F3D, 36F10B, 36F10H 3 - Gas 380772 4615766 36F3H 36F3F, 36F3G, 36C3M, 36C30 4 - Gas 378772 4616666 36C3C 36C3B, 36F3D, 36F3E, 36F3P, 36C3D, 36C3E 4-Gas 380672 4615866 36F3H 36F3F, 36F3G, 36C3M, 36C30 1 - Part 379872 4615966 36F3F 36F3G, 36F3H, 36F3E, 36F3P, 36C3D, 36C3E, 36C3F 1 - Part 380472 4615765 36F3H 36F3F, 36F3G, 36C3M, 36C30 2-Part 379872 4615666 36F3F 36F3G, 36F3H, 36F3E, 36F3P, 36C3D, 36C3E, 36C3F, 36F3I 2-Part 380772 4615766 36F3H 36F3F, 36F3G, 36C3M, 36C30 3-Part 379872 4616066 36F3F 36F3G, 36F3H,36F3E, 36F3P, 36C3D, 36C3E, 36C3F, 36C3WW 3 - Part 380772 4615766 36F3H 36F3F 36F3G, 36C3M, 36C30 4-Part 379872 4616166 36F3F 36F3G, 36F3H, 36F3E, 36F3P, 36C3D, 36C3E, 36C3F 4-Part 3.8E+05 4615866 36F3H 36F3F, 36F3G, 36C3M, 36C30 1 - Dep 379572 4616366 36F3F 36F3G, 36F3H,36F3E, 36C3WW, 36C3C, 36C3D, 36C3E, 36C3F 1 - Dep 380472 4615066 36F3H 36F3F, 36F3H, 36C3M, 36C30, 36F3E 2 - Dep 379572 4615066 36F3F 36F3G, 36F3H, 36F3E, 36F3P, 36C3D, 36C3E, 36C3F 2 - Dep 380672 4615266 36F3G 36F3F, 36F3G, 36C3M, 36C30 3 - Dep 379572 4616066 36F3F 36F3G, 36F3H, 36F3E, 36F3P, 36C3D,.36C3E, 36C3F, 36C3WW 3 - Dep 380772 4615466 36F3G 36F3F, 36F3G, 36C3M, 36C30 4-Dep 379572 4615066 36F3F 36F3G, 36F3H, 36F3E, 36F3P, 36C3D, 36C3E, 36C3F 4-Dep 380672 4615066 36F3H 36F3F, 36F3G, 36C3M, 36C30 TABLE 2-10 M-225 MAXIMUM GENERAL GRID ONSITE/OFFSITE RECEPTORS AND ASSOCIATED GRID SECTORS ATK LAUNCH SYSTEMS PROMONTORY, UTAH Maximum Short Term Impact Offsite Receptor Maximum Short Term Impact Onsite Receptor Surrounding Sectors Within 1 KM of Maximum Onsite Receptor Source - Model Easting Northing Sector Surrounding Sectors Within 1 KM of Maximum Offsite Receptor Source - Model Easting Northing Sector Surrounding Sectors Within 1 KM of Maximum Onsite Receptor 1 - Gas 395669 4604980 25C10 E 25C10I, 25F10H 1 - Gas 385669 4610080 25C3I 25C3G, 25C3F,25C3E, 25C3J, 25C3H 2-Gas 387169 4612480 25C30 25C3D, 25C3L, 25C3C,25C10D, 25C10B 2 - Gas 385669 4610080 25C3I 25C3G, 25C3F,25C3E, 25C3J, 25C3H ' 1 - Part 387469 4610080 25F3H 25C3M, 25F3I, 25F3G, 25F3E, 25F3F, 25C3I, 25C3H 1 - Part 386669 4609680 25F3F 25C3H, 25C3I, 25C3J, 25C3K, 25F3D, 25F3E, 25F3H 2-Part 387669 4608580 25F3M 25F3L, 25F3N, 25F10J, 25F10I 2-Part 386669 4609680 25F3F 25C3H, 25C3I, 25C3J, 25C3k, 2SF3D, 25F3E, 25F3H 1 - Dep 387469 4610080 25F3H 25C3M, 25F3I, 25F3G, 25F3E, 25F3F, 25C3I, 25C3H 1 - Dep 386769 4609480 25F3E 25F3G, 25F3H, 25F3F : 25C3I,25C3J, 25C3K, 25F3D, 25F3E 2 - Dep 387469 4610080 25F3H 25C3M, 25F3I, 25F3G, 25F3E, 25F3F, 25C3I, 25C3H 2 - Dep 386889 4609480 25F3E 25F3G, 25F3H, 25F3F, 25C3I,25C3J, 25C3K, 25F3D, 25F3E ' The maximum offsite and onsite receptors in this table represent the maximum impact location detennine with the general grid receptor network. PGH P:\GIS\THIOKOL\MXD\SITEMAP.MXD 03/16/12 SP Idaho Nevada Great Basi Wyoming NP Utah • • .^v^.--.>v, • .'r : -vV .r.-• r "; • "-TC:-Sr'^-v '.r J •••'^^ ), " /Sr'-/:-!. 4'-^^'-r-v--^;-'V , • ' ,'• ^1's.^-Wi';-;'- 'V • .> -••v. •v;'.-'^:>s • ^ '. i .- " -^^.l : ' • : '.-:^ ^ -r .- i ' . -V --tf'-Tliatchert'.:-. / '. . • 80 0 80 ,Engineer. - i -, . - ; \ "" •# Mountain; ' -. '^ ^ S, * Summit M-136 Unit .•:,^sS^;/ '"^-v'-,! ••• .^TTiatcher:^/; ^ <1; \'.^ . . > : ^ • .V / . . 's-:"':.^< ' ^ Mounta^iij^,^ >; ' ; /'^ . ? . ' y -.' / •• • '^ i' y A /•' ' • • •: •• • a - APPENDIX A ATK DISPERSION MODELING LAND USE ANALYSES FOR M-136 AND M-225 [_ M-136 Treatment Unit ³PGH P:\GIS\THIOKOL\MAPDOCS\MXD\M136_LAND_USE_ANALYSIS.MXD 04/19/11 JEE 1,000 1,0000 Meters CONTRACT NUMBER 0 APPROVED BY REVFIGURE NO. APPROVED BY DATE DATE ___ ____ CTO NUMBER ____ FIGURE E-1 ____ 3 KILOMETER RADIUS LAND USE ANALYSIS FOR ATK PROMONTORY M-136 TREATMENT UNIT PROMONTORY, UTAH DATE AS NOTED SCALE DATECHECKED BY DRAWN BY J. ENGLISH 04/19/11 J. LUCAS 04/20/11 DATEREVISED BY ___ ___ Legend [_Treatment Unit Land Use Analysis Grid (100m) Rural Area Urban Area 3-km Buffer Zone Facility Boundary Aerial photograph taken in 2009. [_ M-225 Treatment Unit ³PGH P:\GIS\THIOKOL\MAPDOCS\MXD\M225_LAND_USE_ANALYSIS.MXD 04/20/11 JEE 1,000 1,0000 Meters CONTRACT NUMBER 0 APPROVED BY REVFIGURE NO. APPROVED BY DATE DATE ___ ____ CTO NUMBER ____ FIGURE E-2 ____ 3 KILOMETER RADIUS LAND USE ANALYSIS FOR ATK PROMONTORY M-225 TREATMENT UNIT PROMONTORY, UTAH DATE AS NOTED SCALE DATECHECKED BY DRAWN BY J. ENGLISH 04/19/11 J. LUCAS 04/20/11 DATEREVISED BY ___ ___ Legend [_Treatment Unit Land Use Analysis Grid (100m) Label Rural Area Urban Area 3-km Buffer Facility Boundary Aerial photograph taken in 2009. APPENDIX B M-245 METEOROLOGICAL DATA AND DATA RECOVERY STATISTICS ATK M-225 Meteorological Monitoring Station Data Recovery Statistics After Data Validation For The Annual Periods 1997 Through 2001 Parameter 1997 1998 1999 2000 2001 ID 100 100 100 100 100 YR 100 100 100 100 100 JD 100 100 100 100 100 HR 100 100 100 100 100 WS 94.5 99.2 90.7 99.4 97.8 WD 94.5 96 90.7 99.4 93.7 ST 94.5 96 90.7 99.4 93.7 TEMP 93.3 99.3 90.7 99.4 93.7 MAXT 93.3 99.3 90.7 99.4 93.7 TIMEX 93.3 99.3 90.7 99.4 93.7 MINT 93.3 99.3 90.7 99.4 93.7 TIMEN 93.3 99.3 90.7 99.4 93.7 PREC 94.5 99.3 90.7 99.5 93.2 PRES 94.6 99.3 90.8 99.5 93.9 SR1 94.6 99.3 90.8 99.5 93.9 SR2 94.6 99.3 90.8 99.5 93.9 APPENDIX C ANNUAL WIND ROSE PLOTS ATK M-245 METEOROLOGICAL STATION FOR 1997, 1998, 1999, 2000, AND 2001 APPENDIX D GAS MODELING RESULTS APPENDIX E PARTICULATE MODELING RESULTS APPENDIX G GAS DISPERSION FACTORS APPENDIX H PARTICULATE DISPERSION FACTORS APPENDIX J DISCRETE RECEPTOR MODELING 1. The ADFs were extracted from output files per source and imported into a text file with a special *.MET extension, then imported into excel. These *.MET files are included in Appendix J. 2. M-136 has 312 treatment events per year; however, its divided into two separate treatments per day. Because of this, the top 156 worst-case scenarios were used to develop the meteorological data per receptor. The worst case ADF for Source 1 was doubled to account for two treatment events per day and 312 events per year. Summary for Worst Case MET File Compilation and Air Dispersion Factor Calculations OBODM was initially used to model maximum 1-hour air dispersion factors (ADFs) for gas, particulates, and deposition sources using five years of onsite meteorological data (see Section 2.13 of this report). For each year of onsite meteorological data, OBODM provided the top fifty 1-hour time-average ADFs. At the conclusion of the modeling, the top fifty ADFs for each year of meteorological data were imported into a spreadsheet1 to provide the top 250 worst-case 1-hour scenarios that would be used to develop the meteorological (MET) files to calculate annual ADFs. The steps below show the procedure that was used to develop these MET files. Appendix J of this report contains a folder that includes the input files and output files used with OBODM, each spreadsheet separated by source number, hourly source strength files per unit, and the meteorological file. The example in Appendix J is for Adams Ranch and includes meteorological files generated for both the M- 136 and M-225 units. 1. In each spreadsheet, there is a tab labeled, “Top 250 Cases.” Because the model was ran per year, the sort command was used to sort the ADFs from largest to smallest. 2. Also, in each spreadsheet, there is a tab labeled, “Top XXX Cases,” where XXX is the number of annual treatment events for a given source based on the treatment scheduled shown in Tables 2- 1 and 2-2 of this report. See Table 1. These top cases were re-sorted to have the worst-case scenarios in chronological order to create an easier and more fluid process to develop the meteorological files. Table 1 – Annual Treatment Events Per Unit M-136 Annual Treatment Events M-225 Annual Treatment Events Source 1 3122 Source 1 24 Source 2 52 Source 2 6 Source 3 52 Source 4 6 Source 5 3 3. The worst-case scenarios obtained from the initial modeling were then superimposed onto the 1997 meteorological data from all five years of meteorological data based on the spreadsheet that was developed in Steps 1 and 2. 4. Hourly source strength files were developed to coincide with the meteorological data for both M- 136 and M-225 based on the treatment quantities shown in Tables 2-1 and 2-2 of this report. The hourly source file option was used in OBODM annual modeling runs to calculate annual average air dispersion factors based on the number of annual treatment events in Tables 2-1 and 2-2 and for the remaining hours in the year when M-136 and M-225 units were not operating. APPENDIX L HOURLY AND ANNUAL EMISSION FACTORFS AND EMISISON RATES TABLE OR APPENDIX ??? 1.3 CLASS WASTE MATERIAL PER EVENT (1-HOUR) CONSERVATIVE EMISSION RATES (LBS/HR) ATK PROMONTORY, UTAH PAGE 1 OF 5 1 2 3 4 5 1 2 Particulates TSP 1.5E-01 1.8E+03 1.5E+03 1.5E+03 9.0E+01 3.9E+03 3.0E+02 6.0E+01 PM10 1.2E-01 1.4E+03 1.2E+03 1.2E+03 7.2E+01 3.1E+03 2.4E+02 4.8E+01 PM2.5 6.0E-02 7.2E+02 6.0E+02 6.0E+02 3.6E+01 1.6E+03 1.2E+02 2.4E+01 Metals Aluminum 4.0E-02 4.8E+02 4.0E+02 4.0E+02 2.4E+01 1.0E+03 8.0E+01 1.6E+01 Antimony 2.9E-05 3.5E-01 2.9E-01 2.9E-01 1.7E-02 7.5E-01 5.8E-02 1.2E-02 Arsenic 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 Barium 9.8E-06 1.2E-01 9.8E-02 9.8E-02 5.9E-03 2.5E-01 2.0E-02 3.9E-03 Cadmium 6.1E-07 7.3E-03 6.1E-03 6.1E-03 3.7E-04 1.6E-02 1.2E-03 2.4E-04 Chromium 2.0E-05 2.4E-01 2.0E-01 2.0E-01 1.2E-02 5.2E-01 4.0E-02 8.0E-03 Cobalt 6.1E-07 7.3E-03 6.1E-03 6.1E-03 3.7E-04 1.6E-02 1.2E-03 2.4E-04 Copper 2.5E-05 3.0E-01 2.5E-01 2.5E-01 1.5E-02 6.5E-01 5.0E-02 1.0E-02 Lead 4.1E-05 4.9E-01 4.1E-01 4.1E-01 2.5E-02 1.1E+00 8.2E-02 1.6E-02 Magnesium 8.2E-05 9.8E-01 8.2E-01 8.2E-01 4.9E-02 2.1E+00 1.6E-01 3.3E-02 Manganese 9.4E-05 1.1E+00 9.4E-01 9.4E-01 5.6E-02 2.4E+00 1.9E-01 3.8E-02 Mercury 7.4E-08 8.9E-04 7.4E-04 7.4E-04 4.4E-05 1.9E-03 1.5E-04 3.0E-05 Nickel 5.8E-05 7.0E-01 5.8E-01 5.8E-01 3.5E-02 1.5E+00 1.2E-01 2.3E-02 Phosphorus 1.1E-04 1.3E+00 1.1E+00 1.1E+00 6.6E-02 2.9E+00 2.2E-01 4.4E-02 Selenium 1.6E-06 1.9E-02 1.6E-02 1.6E-02 9.6E-04 4.2E-02 3.2E-03 6.4E-04 Silver 1.2E-06 1.4E-02 1.2E-02 1.2E-02 7.2E-04 3.1E-02 2.4E-03 4.8E-04 Thallium 4.3E-06 5.2E-02 4.3E-02 4.3E-02 2.6E-03 1.1E-01 8.6E-03 1.7E-03 Zinc 3.5E-05 4.2E-01 3.5E-01 3.5E-01 2.1E-02 9.1E-01 7.0E-02 1.4E-02 Perchlorate 4.9E-07 5.2E-02 4.9E-03 4.9E-03 2.9E-04 1.3E-02 9.8E-04 2.0E-04 SVOCs 1,2,4,5-Tetrachlorobenzene 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 1,2,4-Trichlorobenzene 6.5E-07 7.8E-03 6.5E-03 6.5E-03 3.9E-04 1.7E-02 1.3E-03 2.6E-04 1,2-Dichlorobenzene 5.6E-07 6.7E-03 5.6E-03 5.6E-03 3.4E-04 1.5E-02 1.1E-03 2.2E-04 1,3,5-Trinitrobenzene 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 1,3-Dichlorobenzene 6.2E-07 7.4E-03 6.2E-03 6.2E-03 3.7E-04 1.6E-02 1.2E-03 2.5E-04 1,3-Dinitrobenzene 5.7E-07 6.8E-03 5.7E-03 5.7E-03 3.4E-04 1.5E-02 1.1E-03 2.3E-04 1,4-Dichlorobenzene 5.8E-07 7.0E-03 5.8E-03 5.8E-03 3.5E-04 1.5E-02 1.2E-03 2.3E-04 1-Chloronaphthalene 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 1-Naphthylamine 1.1E-05 1.3E-01 1.1E-01 1.1E-01 6.6E-03 2.9E-01 2.2E-02 4.4E-03 2,3,4,6-Tetrachlorophenol 7.1E-07 8.5E-03 7.1E-03 7.1E-03 4.3E-04 1.8E-02 1.4E-03 2.8E-04 2,4,5-Trichlorophenol 1.4E-06 1.7E-02 1.4E-02 1.4E-02 8.4E-04 3.6E-02 2.8E-03 5.6E-04 2,4,6-Trichlorophenol 1.3E-06 1.6E-02 1.3E-02 1.3E-02 7.8E-04 3.4E-02 2.6E-03 5.2E-04 2,4-Dichlorophenol 9.3E-07 1.1E-02 9.3E-03 9.3E-03 5.6E-04 2.4E-02 1.9E-03 3.7E-04 2,4-Dimethylphenol 6.9E-06 8.3E-02 6.9E-02 6.9E-02 4.1E-03 1.8E-01 1.4E-02 2.8E-03 2,4-Dinitrophenol 2.4E-05 2.9E-01 2.4E-01 2.4E-01 1.4E-02 6.2E-01 4.8E-02 9.6E-03 2,4-Dinitrotoluene 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 2,6-Dichlorophenol 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 2,6-Dinitrotoluene 5.6E-07 6.7E-03 5.6E-03 5.6E-03 3.4E-04 1.5E-02 1.1E-03 2.2E-04 2-Acetylaminofluorene 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 2-Chloronaphthalene 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 2-Chlorophenol 1.9E-06 2.3E-02 1.9E-02 1.9E-02 1.1E-03 4.9E-02 3.8E-03 7.6E-04 2-Methylnaphthalene 3.6E-06 4.3E-02 3.6E-02 3.6E-02 2.2E-03 9.4E-02 7.2E-03 1.4E-03 2-Methylphenol 3.3E-06 4.0E-02 3.3E-02 3.3E-02 2.0E-03 8.6E-02 6.6E-03 1.3E-03 2-Naphthylamine 1.1E-05 1.3E-01 1.1E-01 1.1E-01 6.6E-03 2.9E-01 2.2E-02 4.4E-03 2-Nitroaniline 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 2-Nitrophenol 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 3,3'-Dichlorobenzidine 8.1E-06 9.7E-02 8.1E-02 8.1E-02 4.9E-03 2.1E-01 1.6E-02 3.2E-03 3,3'-Dimethylbenzidine 5.5E-05 6.6E-01 5.5E-01 5.5E-01 3.3E-02 1.4E+00 1.1E-01 2.2E-02 3-Methylcholanthrene 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 3-Methylphenol & 4-Methylphenol 2.2E-06 2.6E-02 2.2E-02 2.2E-02 1.3E-03 5.7E-02 4.4E-03 8.8E-04 3-Nitroaniline 2.2E-06 2.6E-02 2.2E-02 2.2E-02 1.3E-03 5.7E-02 4.4E-03 8.8E-04 4,6-Dinitro-2-methylphenol 9.5E-06 1.1E-01 9.5E-02 9.5E-02 5.7E-03 2.5E-01 1.9E-02 3.8E-03 4-Aminobiphenyl 1.1E-05 1.3E-01 1.1E-01 1.1E-01 6.6E-03 2.9E-01 2.2E-02 4.4E-03 4-Bromophenyl phenyl ether 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 4-Chloro-3-methylphenol 6.8E-07 8.2E-03 6.8E-03 6.8E-03 4.1E-04 1.8E-02 1.4E-03 2.7E-04 4-Chloroaniline 6.6E-06 7.9E-02 6.6E-02 6.6E-02 4.0E-03 1.7E-01 1.3E-02 2.6E-03 4-Nitroaniline 2.2E-06 2.6E-02 2.2E-02 2.2E-02 1.3E-03 5.7E-02 4.4E-03 8.8E-04 4-Nitrophenol 3.6E-06 4.3E-02 3.6E-02 3.6E-02 2.2E-03 9.4E-02 7.2E-03 1.4E-03 7,12-Dimethylbenz(a)anthracene 5.6E-07 6.7E-03 5.6E-03 5.6E-03 3.4E-04 1.5E-02 1.1E-03 2.2E-04 Acenaphthene 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 Acenaphthylene 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 Acetophenone 2.7E-06 3.2E-02 2.7E-02 2.7E-02 1.6E-03 7.0E-02 5.4E-03 1.1E-03 Aniline 8.0E-06 9.6E-02 8.0E-02 8.0E-02 4.8E-03 2.1E-01 1.6E-02 3.2E-03 Analyte Conservative Emission Factor (lbs/lb) M-136 Quantities (lbs/hour)M-225 Quantities (lbs/hr) TABLE OR APPENDIX ??? 1.3 CLASS WASTE MATERIAL PER EVENT (1-HOUR) CONSERVATIVE EMISSION RATES (LBS/HR) ATK PROMONTORY, UTAH PAGE 2 OF 5 1 2 3 4 5 1 2 Analyte Conservative Emission Factor (lbs/lb) M-136 Quantities (lbs/hour)M-225 Quantities (lbs/hr) Anthracene 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 Benzidine 5.6E-05 6.7E-01 5.6E-01 5.6E-01 3.4E-02 1.5E+00 1.1E-01 2.2E-02 Benzo(a)anthracene 6.4E-07 7.7E-03 6.4E-03 6.4E-03 3.8E-04 1.7E-02 1.3E-03 2.6E-04 Benzo(a)pyrene 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 Benzo(b)fluoranthene 1.2E-06 1.4E-02 1.2E-02 1.2E-02 7.2E-04 3.1E-02 2.4E-03 4.8E-04 Benzo(ghi)perylene 6.8E-07 8.2E-03 6.8E-03 6.8E-03 4.1E-04 1.8E-02 1.4E-03 2.7E-04 Benzo(k)fluoranthene 1.8E-06 2.2E-02 1.8E-02 1.8E-02 1.1E-03 4.7E-02 3.6E-03 7.2E-04 Benzoic acid 6.2E-05 7.4E-01 6.2E-01 6.2E-01 3.7E-02 1.6E+00 1.2E-01 2.5E-02 Benzyl alcohol 3.8E-05 4.6E-01 3.8E-01 3.8E-01 2.3E-02 9.9E-01 7.6E-02 1.5E-02 bis(2-Chloroethoxy)methane 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 bis(2-Chloroethyl) ether 6.1E-07 7.3E-03 6.1E-03 6.1E-03 3.7E-04 1.6E-02 1.2E-03 2.4E-04 bis(2-Chloroisopropyl) ether 8.3E-07 1.0E-02 8.3E-03 8.3E-03 5.0E-04 2.2E-02 1.7E-03 3.3E-04 bis(2-Ethylhexyl) phthalate 1.1E-05 1.3E-01 1.1E-01 1.1E-01 6.6E-03 2.9E-01 2.2E-02 4.4E-03 Butyl benzyl phthalate 6.7E-07 8.0E-03 6.7E-03 6.7E-03 4.0E-04 1.7E-02 1.3E-03 2.7E-04 Carbazole 7.0E-07 8.4E-03 7.0E-03 7.0E-03 4.2E-04 1.8E-02 1.4E-03 2.8E-04 Chrysene 7.0E-07 8.4E-03 7.0E-03 7.0E-03 4.2E-04 1.8E-02 1.4E-03 2.8E-04 Dibenz(a,h)anthracene 6.6E-07 7.9E-03 6.6E-03 6.6E-03 4.0E-04 1.7E-02 1.3E-03 2.6E-04 Dibenzofuran 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 Diethyl phthalate 8.0E-07 9.6E-03 8.0E-03 8.0E-03 4.8E-04 2.1E-02 1.6E-03 3.2E-04 Dimethyl phthalate 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 Di-n-butyl phthalate 1.1E-05 1.3E-01 1.1E-01 1.1E-01 6.6E-03 2.9E-01 2.2E-02 4.4E-03 Di-n-octyl phthalate 3.7E-06 4.4E-02 3.7E-02 3.7E-02 2.2E-03 9.6E-02 7.4E-03 1.5E-03 Diphenylamine 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 Ethyl methanesulfonate 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 Fluoranthene 5.9E-07 7.1E-03 5.9E-03 5.9E-03 3.5E-04 1.5E-02 1.2E-03 2.4E-04 Fluorene 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 Hexachlorobenzene 4.7E-06 5.6E-02 4.7E-02 4.7E-02 2.8E-03 1.2E-01 9.4E-03 1.9E-03 Hexachlorobutadiene 8.1E-07 9.7E-03 8.1E-03 8.1E-03 4.9E-04 2.1E-02 1.6E-03 3.2E-04 Hexachlorocyclopentadiene 1.1E-05 1.3E-01 1.1E-01 1.1E-01 6.6E-03 2.9E-01 2.2E-02 4.4E-03 Hexachloroethane 5.9E-07 7.1E-03 5.9E-03 5.9E-03 3.5E-04 1.5E-02 1.2E-03 2.4E-04 Hexachloropropene 7.9E-07 9.5E-03 7.9E-03 7.9E-03 4.7E-04 2.1E-02 1.6E-03 3.2E-04 Indeno(1,2,3-cd)pyrene 5.9E-07 7.1E-03 5.9E-03 5.9E-03 3.5E-04 1.5E-02 1.2E-03 2.4E-04 Isophorone 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 Methyl methanesulfonate 6.0E-07 7.2E-03 6.0E-03 6.0E-03 3.6E-04 1.6E-02 1.2E-03 2.4E-04 Naphthalene 1.4E-05 1.7E-01 1.4E-01 1.4E-01 8.4E-03 3.6E-01 2.8E-02 5.6E-03 Nitrobenzene 6.2E-07 7.4E-03 6.2E-03 6.2E-03 3.7E-04 1.6E-02 1.2E-03 2.5E-04 N-Nitro-o-toluidine 8.8E-06 1.1E-01 8.8E-02 8.8E-02 5.3E-03 2.3E-01 1.8E-02 3.5E-03 N-Nitrosodiethylamine 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 N-Nitrosodimethylamine 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 N-Nitrosodi-n-butylamine 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 N-Nitrosodi-n-propylamine 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 N-Nitrosodiphenylamine 9.5E-07 1.1E-02 9.5E-03 9.5E-03 5.7E-04 2.5E-02 1.9E-03 3.8E-04 N-Nitrosomethylethylamine 9.1E-07 1.1E-02 9.1E-03 9.1E-03 5.5E-04 2.4E-02 1.8E-03 3.6E-04 N-Nitrosomorpholine 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 o-Toluidine 7.0E-06 8.4E-02 7.0E-02 7.0E-02 4.2E-03 1.8E-01 1.4E-02 2.8E-03 p-Dimethylaminoazobenzene 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 Pentachlorobenzene 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 Pentachloroethane 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 Pentachloronitrobenzene 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 Pentachlorophenol 2.7E-05 3.2E-01 2.7E-01 2.7E-01 1.6E-02 7.0E-01 5.4E-02 1.1E-02 Phenanthrene 7.0E-07 8.4E-03 7.0E-03 7.0E-03 4.2E-04 1.8E-02 1.4E-03 2.8E-04 Phenol 2.4E-06 2.9E-02 2.4E-02 2.4E-02 1.4E-03 6.2E-02 4.8E-03 9.6E-04 Pyrene 5.8E-07 7.0E-03 5.8E-03 5.8E-03 3.5E-04 1.5E-02 1.2E-03 2.3E-04 Pyridine 8.1E-07 9.7E-03 8.1E-03 8.1E-03 4.9E-04 2.1E-02 1.6E-03 3.2E-04 Dioxins/Furans 2,3,7,8-TCDD 2.3E-12 2.8E-08 2.3E-08 2.3E-08 1.4E-09 6.0E-08 4.6E-09 9.2E-10 1,2,3,7,8-PeCDD 6.7E-12 8.0E-08 6.7E-08 6.7E-08 4.0E-09 1.7E-07 1.3E-08 2.7E-09 1,2,3,4,7,8-HxCDD 3.5E-12 4.2E-08 3.5E-08 3.5E-08 2.1E-09 9.1E-08 7.0E-09 1.4E-09 1,2,3,6,7,8-HxCDD 8.9E-12 1.1E-07 8.9E-08 8.9E-08 5.3E-09 2.3E-07 1.8E-08 3.6E-09 1,2,3,7,8,9-HxCDD 6.1E-12 7.3E-08 6.1E-08 6.1E-08 3.7E-09 1.6E-07 1.2E-08 2.4E-09 1,2,3,4,6,7,8-HpCDD 2.9E-11 3.5E-07 2.9E-07 2.9E-07 1.7E-08 7.5E-07 5.8E-08 1.2E-08 OCDD 3.7E-11 4.4E-07 3.7E-07 3.7E-07 2.2E-08 9.6E-07 7.4E-08 1.5E-08 2,3,7,8-TCDF 4.0E-11 4.8E-07 4.0E-07 4.0E-07 2.4E-08 1.0E-06 8.0E-08 1.6E-08 1,2,3,7,8-PeCDF 8.0E-11 9.6E-07 8.0E-07 8.0E-07 4.8E-08 2.1E-06 1.6E-07 3.2E-08 2,3,4,7,8-PeCDF 1.6E-10 1.9E-06 1.6E-06 1.6E-06 9.6E-08 4.2E-06 3.2E-07 6.4E-08 1,2,3,4,7,8-HxCDF 2.6E-10 3.1E-06 2.6E-06 2.6E-06 1.6E-07 6.8E-06 5.2E-07 1.0E-07 1,2,3,6,7,8-HxCDF 1.6E-10 1.9E-06 1.6E-06 1.6E-06 9.6E-08 4.2E-06 3.2E-07 6.4E-08 2,3,4,6,7,8-HxCDF 1.9E-10 2.3E-06 1.9E-06 1.9E-06 1.1E-07 4.9E-06 3.8E-07 7.6E-08 1,2,3,7,8,9-HxCDF 1.2E-10 1.4E-06 1.2E-06 1.2E-06 7.2E-08 3.1E-06 2.4E-07 4.8E-08 1,2,3,4,6,7,8-HpCDF 7.3E-10 8.8E-06 7.3E-06 7.3E-06 4.4E-07 1.9E-05 1.5E-06 2.9E-07 TABLE OR APPENDIX ??? 1.3 CLASS WASTE MATERIAL PER EVENT (1-HOUR) CONSERVATIVE EMISSION RATES (LBS/HR) ATK PROMONTORY, UTAH PAGE 3 OF 5 1 2 3 4 5 1 2 Analyte Conservative Emission Factor (lbs/lb) M-136 Quantities (lbs/hour)M-225 Quantities (lbs/hr) 1,2,3,4,7,8,9-HpCDF 1.9E-10 2.3E-06 1.9E-06 1.9E-06 1.1E-07 4.9E-06 3.8E-07 7.6E-08 OCDF 5.3E-10 6.4E-06 5.3E-06 5.3E-06 3.2E-07 1.4E-05 1.1E-06 2.1E-07 Carbonyls 2,5-Dimethylbenzaldehyde 2.7E-05 3.2E-01 2.7E-01 2.7E-01 1.6E-02 7.0E-01 5.4E-02 1.1E-02 Acetaldehyde 9.3E-05 1.1E+00 9.3E-01 9.3E-01 5.6E-02 2.4E+00 1.9E-01 3.7E-02 Acetone 3.1E-05 3.7E-01 3.1E-01 3.1E-01 1.9E-02 8.1E-01 6.2E-02 1.2E-02 Benzaldehyde 1.4E-05 1.7E-01 1.4E-01 1.4E-01 8.4E-03 3.6E-01 2.8E-02 5.6E-03 Crotonaldehyde 1.4E-05 1.7E-01 1.4E-01 1.4E-01 8.4E-03 3.6E-01 2.8E-02 5.6E-03 Formaldehyde 4.7E-05 5.6E-01 4.7E-01 4.7E-01 2.8E-02 1.2E+00 9.4E-02 1.9E-02 Hexanal 1.4E-05 1.7E-01 1.4E-01 1.4E-01 8.4E-03 3.6E-01 2.8E-02 5.6E-03 Isopentanal 1.4E-05 1.7E-01 1.4E-01 1.4E-01 8.4E-03 3.6E-01 2.8E-02 5.6E-03 m,p-Tolualdehyde 1.4E-05 1.7E-01 1.4E-01 1.4E-01 8.4E-03 3.6E-01 2.8E-02 5.6E-03 MEK/Butyraldehydes 1.4E-05 1.7E-01 1.4E-01 1.4E-01 8.4E-03 3.6E-01 2.8E-02 5.6E-03 o-Tolualdehyde 4.0E-05 4.8E-01 4.0E-01 4.0E-01 2.4E-02 1.0E+00 8.0E-02 1.6E-02 Pentanal 1.7E-05 2.0E-01 1.7E-01 1.7E-01 1.0E-02 4.4E-01 3.4E-02 6.8E-03 Propanal 5.2E-05 6.2E-01 5.2E-01 5.2E-01 3.1E-02 1.4E+00 1.0E-01 2.1E-02 HCl/Cl2/NH3 HCl 1.8E-02 2.2E+02 1.8E+02 1.8E+02 1.1E+01 4.7E+02 3.6E+01 7.2E+00 Cl2 1.2E-02 1.4E+02 1.2E+02 1.2E+02 7.2E+00 3.1E+02 2.4E+01 4.8E+00 NH3 3.2E-05 3.8E-01 3.2E-01 3.2E-01 1.9E-02 8.3E-01 6.4E-02 1.3E-02 HCN 2.2E-05 2.6E-01 2.2E-01 #REF!1.3E-02 5.7E-01 4.4E-02 8.8E-03 VOCs TNMOC 9.4E-04 1.1E+01 9.4E+00 9.4E+00 5.6E-01 2.4E+01 1.9E+00 3.8E-01 1,1,1-Trichloroethane 8.9E-07 1.1E-02 8.9E-03 8.9E-03 5.3E-04 2.3E-02 1.8E-03 3.6E-04 1,1,2,2-Tetrachloroethane 4.2E-07 5.0E-03 4.2E-03 4.2E-03 2.5E-04 1.1E-02 8.4E-04 1.7E-04 1,1,2-Trichloroethane 7.3E-07 8.8E-03 7.3E-03 7.3E-03 4.4E-04 1.9E-02 1.5E-03 2.9E-04 1,1-Dichloroethane 3.2E-07 3.8E-03 3.2E-03 3.2E-03 1.9E-04 8.3E-03 6.4E-04 1.3E-04 1,1-Dichloroethene 4.3E-07 5.2E-03 4.3E-03 4.3E-03 2.6E-04 1.1E-02 8.6E-04 1.7E-04 1,2,3-Trimethylbenzene 4.2E-07 5.0E-03 4.2E-03 4.2E-03 2.5E-04 1.1E-02 8.4E-04 1.7E-04 1,2,4-Trichlorobenzene 1.3E-06 1.6E-02 1.3E-02 1.3E-02 7.8E-04 3.4E-02 2.6E-03 5.2E-04 1,2,4-Trimethylbenzene 5.2E-06 6.2E-02 5.2E-02 5.2E-02 3.1E-03 1.4E-01 1.0E-02 2.1E-03 1,2-Dibromomethane (EDB)8.9E-07 1.1E-02 8.9E-03 8.9E-03 5.3E-04 2.3E-02 1.8E-03 3.6E-04 1,2-Dichlorobenzene 4.8E-07 5.8E-03 4.8E-03 4.8E-03 2.9E-04 1.2E-02 9.6E-04 1.9E-04 1,2-Dichloroethane 5.4E-07 6.5E-03 5.4E-03 5.4E-03 3.2E-04 1.4E-02 1.1E-03 2.2E-04 1,2-Dichloropropane 3.7E-07 4.4E-03 3.7E-03 3.7E-03 2.2E-04 9.6E-03 7.4E-04 1.5E-04 1,3,5-Trimethylbenzene 2.0E-06 2.4E-02 2.0E-02 2.0E-02 1.2E-03 5.2E-02 4.0E-03 8.0E-04 1,3-Butadiene 2.4E-05 2.9E-01 2.4E-01 2.4E-01 1.4E-02 6.2E-01 4.8E-02 9.6E-03 1,3-Dichlorobenzene 4.4E-07 5.3E-03 4.4E-03 4.4E-03 2.6E-04 1.1E-02 8.8E-04 1.8E-04 1,3-Diethylbenzene 5.0E-07 6.0E-03 5.0E-03 5.0E-03 3.0E-04 1.3E-02 1.0E-03 2.0E-04 1,4-Dichlorobenzene 7.3E-07 8.8E-03 7.3E-03 7.3E-03 4.4E-04 1.9E-02 1.5E-03 2.9E-04 1,4-Diethylbenzene 6.7E-07 8.0E-03 6.7E-03 6.7E-03 4.0E-04 1.7E-02 1.3E-03 2.7E-04 1,4-Dioxane 6.4E-07 7.7E-03 6.4E-03 6.4E-03 3.8E-04 1.7E-02 1.3E-03 2.6E-04 1-Butene 2.2E-05 2.6E-01 2.2E-01 2.2E-01 1.3E-02 5.7E-01 4.4E-02 8.8E-03 1-Hexene 2.0E-05 2.4E-01 2.0E-01 2.0E-01 1.2E-02 5.2E-01 4.0E-02 8.0E-03 1-Pentene 1.2E-05 1.4E-01 1.2E-01 1.2E-01 7.2E-03 3.1E-01 2.4E-02 4.8E-03 2,2,4-Trimethylpentane 2.3E-06 2.8E-02 2.3E-02 2.3E-02 1.4E-03 6.0E-02 4.6E-03 9.2E-04 2,2-Dimethylbutane 8.8E-07 1.1E-02 8.8E-03 8.8E-03 5.3E-04 2.3E-02 1.8E-03 3.5E-04 2,3,4-Trimethylpentane 2.8E-07 3.4E-03 2.8E-03 2.8E-03 1.7E-04 7.3E-03 5.6E-04 1.1E-04 2,3-Dimethylbutane 2.9E-06 3.5E-02 2.9E-02 2.9E-02 1.7E-03 7.5E-02 5.8E-03 1.2E-03 2,3-Dimethylpentane 2.7E-06 3.2E-02 2.7E-02 2.7E-02 1.6E-03 7.0E-02 5.4E-03 1.1E-03 2,4-Dimethylpentane 1.1E-06 1.3E-02 1.1E-02 1.1E-02 6.6E-04 2.9E-02 2.2E-03 4.4E-04 2-Butanone (MEK)3.9E-06 4.7E-02 3.9E-02 3.9E-02 2.3E-03 1.0E-01 7.8E-03 1.6E-03 2-Ethyltoluene 4.5E-07 5.4E-03 4.5E-03 4.5E-03 2.7E-04 1.2E-02 9.0E-04 1.8E-04 2-Hexanone 8.7E-07 1.0E-02 8.7E-03 8.7E-03 5.2E-04 2.3E-02 1.7E-03 3.5E-04 2-Methylheptane 2.7E-06 3.2E-02 2.7E-02 2.7E-02 1.6E-03 7.0E-02 5.4E-03 1.1E-03 2-Methylhexane 4.4E-06 5.3E-02 4.4E-02 4.4E-02 2.6E-03 1.1E-01 8.8E-03 1.8E-03 2-Methylpentane 1.1E-05 1.3E-01 1.1E-01 1.1E-01 6.6E-03 2.9E-01 2.2E-02 4.4E-03 2-Nitropropane 2.8E-06 3.4E-02 2.8E-02 2.8E-02 1.7E-03 7.3E-02 5.6E-03 1.1E-03 2-Propanol 3.0E-07 3.6E-03 3.0E-03 3.0E-03 1.8E-04 7.8E-03 6.0E-04 1.2E-04 3-Chloropropene 4.7E-06 5.6E-02 4.7E-02 4.7E-02 2.8E-03 1.2E-01 9.4E-03 1.9E-03 3-Ethyltoluene 4.8E-06 5.8E-02 4.8E-02 4.8E-02 2.9E-03 1.2E-01 9.6E-03 1.9E-03 3-Methylheptane 3.5E-06 4.2E-02 3.5E-02 3.5E-02 2.1E-03 9.1E-02 7.0E-03 1.4E-03 3-Methylhexane 5.2E-06 6.2E-02 5.2E-02 5.2E-02 3.1E-03 1.4E-01 1.0E-02 2.1E-03 3-Methylpentane 7.1E-06 8.5E-02 7.1E-02 7.1E-02 4.3E-03 1.8E-01 1.4E-02 2.8E-03 4-Ethyltoluene 5.3E-06 6.4E-02 5.3E-02 5.3E-02 3.2E-03 1.4E-01 1.1E-02 2.1E-03 4-Methyl-2-pentanone 7.0E-07 8.4E-03 7.0E-03 7.0E-03 4.2E-04 1.8E-02 1.4E-03 2.8E-04 Acetone 2.4E-05 2.9E-01 2.4E-01 2.4E-01 1.4E-02 6.2E-01 4.8E-02 9.6E-03 TABLE OR APPENDIX ??? 1.3 CLASS WASTE MATERIAL PER EVENT (1-HOUR) CONSERVATIVE EMISSION RATES (LBS/HR) ATK PROMONTORY, UTAH PAGE 4 OF 5 1 2 3 4 5 1 2 Analyte Conservative Emission Factor (lbs/lb) M-136 Quantities (lbs/hour)M-225 Quantities (lbs/hr) Acetonitrile 1.9E-05 2.3E-01 1.9E-01 1.9E-01 1.1E-02 4.9E-01 3.8E-02 7.6E-03 Acetylene 9.4E-05 1.1E+00 9.4E-01 9.4E-01 5.6E-02 2.4E+00 1.9E-01 3.8E-02 Acrylonitrile 1.6E-05 1.9E-01 1.6E-01 1.6E-01 9.6E-03 4.2E-01 3.2E-02 6.4E-03 alpha-Chlorotoluene 5.7E-07 6.8E-03 5.7E-03 5.7E-03 3.4E-04 1.5E-02 1.1E-03 2.3E-04 Benzene 4.7E-05 5.6E-01 4.7E-01 4.7E-01 2.8E-02 1.2E+00 9.4E-02 1.9E-02 Bromodichloromethane 7.8E-07 9.4E-03 7.8E-03 7.8E-03 4.7E-04 2.0E-02 1.6E-03 3.1E-04 Bromoform 1.3E-06 1.6E-02 1.3E-02 1.3E-02 7.8E-04 3.4E-02 2.6E-03 5.2E-04 Bromomethane 6.2E-07 7.4E-03 6.2E-03 6.2E-03 3.7E-04 1.6E-02 1.2E-03 2.5E-04 Butane 1.8E-05 2.2E-01 1.8E-01 1.8E-01 1.1E-02 4.7E-01 3.6E-02 7.2E-03 Carbon Disulfide 9.8E-06 1.2E-01 9.8E-02 9.8E-02 5.9E-03 2.5E-01 2.0E-02 3.9E-03 Carbon Tetrachloride 1.5E-05 1.8E-01 1.5E-01 1.5E-01 9.0E-03 3.9E-01 3.0E-02 6.0E-03 Chloroacetonitrile 1.1E-06 1.3E-02 1.1E-02 1.1E-02 6.6E-04 2.9E-02 2.2E-03 4.4E-04 Chlorobenzene 2.5E-06 3.0E-02 2.5E-02 2.5E-02 1.5E-03 6.5E-02 5.0E-03 1.0E-03 Chloroethane 2.6E-07 3.1E-03 2.6E-03 2.6E-03 1.6E-04 6.8E-03 5.2E-04 1.0E-04 Chloroform 6.1E-06 7.3E-02 6.1E-02 6.1E-02 3.7E-03 1.6E-01 1.2E-02 2.4E-03 Chloromethane 1.4E-05 1.7E-01 1.4E-01 1.4E-01 8.4E-03 3.6E-01 2.8E-02 5.6E-03 cis-1,2-Dichloroethene 4.6E-07 5.5E-03 4.6E-03 4.6E-03 2.8E-04 1.2E-02 9.2E-04 1.8E-04 cis-1,3-Dichloropropene 1.3E-06 1.6E-02 1.3E-02 1.3E-02 7.8E-04 3.4E-02 2.6E-03 5.2E-04 cis-2-Butene 1.7E-06 2.0E-02 1.7E-02 1.7E-02 1.0E-03 4.4E-02 3.4E-03 6.8E-04 cis-2-Pentene 3.3E-07 4.0E-03 3.3E-03 3.3E-03 2.0E-04 8.6E-03 6.6E-04 1.3E-04 Cumene 4.2E-07 5.0E-03 4.2E-03 4.2E-03 2.5E-04 1.1E-02 8.4E-04 1.7E-04 Cyclohexane 2.5E-06 3.0E-02 2.5E-02 2.5E-02 1.5E-03 6.5E-02 5.0E-03 1.0E-03 Cyclopentane 1.8E-06 2.2E-02 1.8E-02 1.8E-02 1.1E-03 4.7E-02 3.6E-03 7.2E-04 Decane 1.7E-05 2.0E-01 1.7E-01 1.7E-01 1.0E-02 4.4E-01 3.4E-02 6.8E-03 Dibromochloromethane 8.8E-07 1.1E-02 8.8E-03 8.8E-03 5.3E-04 2.3E-02 1.8E-03 3.5E-04 Ethane 2.1E-05 2.5E-01 2.1E-01 2.1E-01 1.3E-02 5.5E-01 4.2E-02 8.4E-03 Ethanol 1.6E-06 1.9E-02 1.6E-02 1.6E-02 9.6E-04 4.2E-02 3.2E-03 6.4E-04 Ethene 1.8E-04 2.2E+00 1.8E+00 1.8E+00 1.1E-01 4.7E+00 3.6E-01 7.2E-02 Ethyl benzene 2.8E-06 3.4E-02 2.8E-02 2.8E-02 1.7E-03 7.3E-02 5.6E-03 1.1E-03 Ethyl ether 2.5E-06 3.0E-02 2.5E-02 2.5E-02 1.5E-03 6.5E-02 5.0E-03 1.0E-03 Ethyl Methacrylate 1.6E-06 1.9E-02 1.6E-02 1.6E-02 9.6E-04 4.2E-02 3.2E-03 6.4E-04 Heptane 7.2E-06 8.6E-02 7.2E-02 7.2E-02 4.3E-03 1.9E-01 1.4E-02 2.9E-03 Hexachlorobutadiene 1.7E-06 2.0E-02 1.7E-02 1.7E-02 1.0E-03 4.4E-02 3.4E-03 6.8E-04 Hexane 9.8E-06 1.2E-01 9.8E-02 9.8E-02 5.9E-03 2.5E-01 2.0E-02 3.9E-03 Isobutane 2.8E-06 3.4E-02 2.8E-02 2.8E-02 1.7E-03 7.3E-02 5.6E-03 1.1E-03 Isopentane 2.0E-05 2.4E-01 2.0E-01 2.0E-01 1.2E-02 5.2E-01 4.0E-02 8.0E-03 m,p-Xylene 1.1E-05 1.3E-01 1.1E-01 1.1E-01 6.6E-03 2.9E-01 2.2E-02 4.4E-03 Methacrylonitrile 4.9E-06 5.9E-02 4.9E-02 4.9E-02 2.9E-03 1.3E-01 9.8E-03 2.0E-03 Methyl Acrylate 1.2E-06 1.4E-02 1.2E-02 1.2E-02 7.2E-04 3.1E-02 2.4E-03 4.8E-04 Methyl Methacrylate 1.6E-06 1.9E-02 1.6E-02 1.6E-02 9.6E-04 4.2E-02 3.2E-03 6.4E-04 Methyl tert-butyl ether 4.2E-07 5.0E-03 4.2E-03 4.2E-03 2.5E-04 1.1E-02 8.4E-04 1.7E-04 Methylcyclohexane 6.1E-06 7.3E-02 6.1E-02 6.1E-02 3.7E-03 1.6E-01 1.2E-02 2.4E-03 Methylcyclopentane 5.6E-06 6.7E-02 5.6E-02 5.6E-02 3.4E-03 1.5E-01 1.1E-02 2.2E-03 Methylene chloride 7.1E-06 8.5E-02 7.1E-02 7.1E-02 4.3E-03 1.8E-01 1.4E-02 2.8E-03 n-Butylchloride 1.2E-05 1.4E-01 1.2E-01 1.2E-01 7.2E-03 3.1E-01 2.4E-02 4.8E-03 Nonane 1.3E-05 1.6E-01 1.3E-01 1.3E-01 7.8E-03 3.4E-01 2.6E-02 5.2E-03 Octane 7.5E-06 9.0E-02 7.5E-02 7.5E-02 4.5E-03 2.0E-01 1.5E-02 3.0E-03 o-Xylene 3.5E-06 4.2E-02 3.5E-02 3.5E-02 2.1E-03 9.1E-02 7.0E-03 1.4E-03 Pentane 1.9E-05 2.3E-01 1.9E-01 1.9E-01 1.1E-02 4.9E-01 3.8E-02 7.6E-03 Propane 8.7E-06 1.0E-01 8.7E-02 8.7E-02 5.2E-03 2.3E-01 1.7E-02 3.5E-03 Propylbenzene 1.0E-06 1.2E-02 1.0E-02 1.0E-02 6.0E-04 2.6E-02 2.0E-03 4.0E-04 Propylene 4.9E-05 5.9E-01 4.9E-01 4.9E-01 2.9E-02 1.3E+00 9.8E-02 2.0E-02 Styrene 9.9E-07 1.2E-02 9.9E-03 9.9E-03 5.9E-04 2.6E-02 2.0E-03 4.0E-04 Tetrachloroethene 2.5E-06 3.0E-02 2.5E-02 2.5E-02 1.5E-03 6.5E-02 5.0E-03 1.0E-03 Tetrahydrofuran 9.0E-07 1.1E-02 9.0E-03 9.0E-03 5.4E-04 2.3E-02 1.8E-03 3.6E-04 Toluene 1.9E-05 2.3E-01 1.9E-01 1.9E-01 1.1E-02 4.9E-01 3.8E-02 7.6E-03 trans-1,2-Dichloroethene 7.2E-07 8.6E-03 7.2E-03 7.2E-03 4.3E-04 1.9E-02 1.4E-03 2.9E-04 trans-1,3-Dichloropropene 6.1E-07 7.3E-03 6.1E-03 6.1E-03 3.7E-04 1.6E-02 1.2E-03 2.4E-04 trans-2-butene 7.7E-06 9.2E-02 7.7E-02 7.7E-02 4.6E-03 2.0E-01 1.5E-02 3.1E-03 trans-2-Pentene 1.7E-06 2.0E-02 1.7E-02 1.7E-02 1.0E-03 4.4E-02 3.4E-03 6.8E-04 Trichloroethene 9.4E-07 1.1E-02 9.4E-03 9.4E-03 5.6E-04 2.4E-02 1.9E-03 3.8E-04 Undecane 1.2E-05 1.4E-01 1.2E-01 1.2E-01 7.2E-03 3.1E-01 2.4E-02 4.8E-03 Vinyl chloride 7.6E-06 9.1E-02 7.6E-02 7.6E-02 4.6E-03 2.0E-01 1.5E-02 3.0E-03 CEM CO2 7.20E-01 8.6E+03 7.2E+03 7.2E+03 4.3E+02 1.9E+04 1.4E+03 2.9E+02 CO 6.40E-03 7.7E+01 6.4E+01 6.4E+01 3.8E+00 1.7E+02 1.3E+01 2.6E+00 NOX 6.40E-03 7.7E+01 6.4E+01 6.4E+01 3.8E+00 1.7E+02 1.3E+01 2.6E+00 SO2 5.00E-04 6.0E+00 5.0E+00 5.0E+00 3.0E-01 1.3E+01 1.0E+00 2.0E-01 Highlighted analytes were not detected during the Bang Box testing program TABLE OR APPENDIX ??? 1.3 CLASS WASTE MATERIAL PER EVENT (1-HOUR) CONSERVATIVE EMISSION RATES (LBS/HR) ATK PROMONTORY, UTAH PAGE 5 OF 5 1 2 3 4 5 1 2 Analyte Conservative Emission Factor (lbs/lb) M-136 Quantities (lbs/hour)M-225 Quantities (lbs/hr) CEM - Continuous Emissions Monitoring CL2 - chlorine CO - carbon monoxide CO2 - carbon dioxide HCL - hydrogen chloride HCN - hydrogen cyanide NH3 - ammonia NOX - nitrogen oxide OCDD - 1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin OCDF - 1,2,3,4,6,7,8,9-Octachlorodibenzo-p-furan PM10 - particulate matter less than 10 microns in aerodynamic diameter PM2.5 - particulate matter less than 2.5 microns in aerodynamic diameter SO2 - sulfur dioxide SVOCs - semi-volatile organic compounds TNMOC - total non-methane organic carbon TSP - Total suspended particulates VOCs - volatile organic compounds TABLE OR APPENDIX 3-??? 1.3 CLASS WASTE MATERIAL CONSERVATIVE ANNUAL EMISSION RATES (LBS/YR) ATK PROMONTORY, UTAH PAGE 1 OF 5 1 2 3 4 5 1 2 Particulates TSP 1.5E-01 5.6E+05 7.8E+04 7.8E+04 5.4E+02 1.2E+04 7.2E+03 3.6E+02 PM10 1.2E-01 4.5E+05 6.2E+04 6.2E+04 4.3E+02 9.4E+03 5.8E+03 2.9E+02 PM2.5 6.0E-02 2.2E+05 3.1E+04 3.1E+04 2.2E+02 4.7E+03 2.9E+03 1.4E+02 Metals Aluminum 4.0E-02 1.5E+05 2.1E+04 2.1E+04 1.4E+02 3.1E+03 1.9E+03 9.6E+01 Antimony 2.9E-05 1.1E+02 1.5E+01 1.5E+01 1.0E-01 2.3E+00 1.4E+00 7.0E-02 Arsenic 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 1.3E-03 Barium 9.8E-06 3.7E+01 5.1E+00 5.1E+00 3.5E-02 7.6E-01 4.7E-01 2.4E-02 Cadmium 6.1E-07 2.3E+00 3.2E-01 3.2E-01 2.2E-03 4.8E-02 2.9E-02 1.5E-03 Chromium 2.0E-05 7.5E+01 1.0E+01 1.0E+01 7.2E-02 1.6E+00 9.6E-01 4.8E-02 Cobalt 6.1E-07 2.3E+00 3.2E-01 3.2E-01 2.2E-03 4.8E-02 2.9E-02 1.5E-03 Copper 2.5E-05 9.4E+01 1.3E+01 1.3E+01 9.0E-02 2.0E+00 1.2E+00 6.0E-02 Lead 4.1E-05 1.5E+02 2.1E+01 2.1E+01 1.5E-01 3.2E+00 2.0E+00 9.8E-02 Magnesium 8.2E-05 3.1E+02 4.3E+01 4.3E+01 3.0E-01 6.4E+00 3.9E+00 2.0E-01 Manganese 9.4E-05 3.5E+02 4.9E+01 4.9E+01 3.4E-01 7.3E+00 4.5E+00 2.3E-01 Mercury 7.4E-08 2.8E-01 3.8E-02 3.8E-02 2.7E-04 5.8E-03 3.6E-03 1.8E-04 Nickel 5.8E-05 2.2E+02 3.0E+01 3.0E+01 2.1E-01 4.5E+00 2.8E+00 1.4E-01 Phosphorus 1.1E-04 4.1E+02 5.7E+01 5.7E+01 4.0E-01 8.6E+00 5.3E+00 2.6E-01 Selenium 1.6E-06 6.0E+00 8.3E-01 8.3E-01 5.8E-03 1.2E-01 7.7E-02 3.8E-03 Silver 1.2E-06 4.5E+00 6.2E-01 6.2E-01 4.3E-03 9.4E-02 5.8E-02 2.9E-03 Thallium 4.3E-06 1.6E+01 2.2E+00 2.2E+00 1.5E-02 3.4E-01 2.1E-01 1.0E-02 Zinc 3.5E-05 1.3E+02 1.8E+01 1.8E+01 1.3E-01 2.7E+00 1.7E+00 8.4E-02 Perchlorate 4.9E-07 5.2E-02 2.5E-01 2.5E-01 1.8E-03 3.8E-02 2.4E-02 1.2E-03 SVOCs 1,2,4,5-Tetrachlorobenzene 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 1.3E-03 1,2,4-Trichlorobenzene 6.5E-07 2.4E+00 3.4E-01 3.4E-01 2.3E-03 5.1E-02 3.1E-02 2.6E-04 1,2-Dichlorobenzene 5.6E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.4E-02 2.7E-02 2.2E-04 1,3,5-Trinitrobenzene 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 1,3-Dichlorobenzene 6.2E-07 2.3E+00 3.2E-01 3.2E-01 2.2E-03 4.8E-02 3.0E-02 2.5E-04 1,3-Dinitrobenzene 5.7E-07 2.1E+00 3.0E-01 3.0E-01 2.1E-03 4.4E-02 2.7E-02 2.3E-04 1,4-Dichlorobenzene 5.8E-07 2.2E+00 3.0E-01 3.0E-01 2.1E-03 4.5E-02 2.8E-02 2.3E-04 1-Chloronaphthalene 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 1-Naphthylamine 1.1E-05 4.1E+01 5.7E+00 5.7E+00 4.0E-02 8.6E-01 5.3E-01 4.4E-03 2,3,4,6-Tetrachlorophenol 7.1E-07 2.7E+00 3.7E-01 3.7E-01 2.6E-03 5.5E-02 3.4E-02 2.8E-04 2,4,5-Trichlorophenol 1.4E-06 5.2E+00 7.3E-01 7.3E-01 5.0E-03 1.1E-01 6.7E-02 5.6E-04 2,4,6-Trichlorophenol 1.3E-06 4.9E+00 6.8E-01 6.8E-01 4.7E-03 1.0E-01 6.2E-02 5.2E-04 2,4-Dichlorophenol 9.3E-07 3.5E+00 4.8E-01 4.8E-01 3.3E-03 7.3E-02 4.5E-02 3.7E-04 2,4-Dimethylphenol 6.9E-06 2.6E+01 3.6E+00 3.6E+00 2.5E-02 5.4E-01 3.3E-01 2.8E-03 2,4-Dinitrophenol 2.4E-05 9.0E+01 1.2E+01 1.2E+01 8.6E-02 1.9E+00 1.2E+00 9.6E-03 2,4-Dinitrotoluene 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 2,6-Dichlorophenol 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 2,6-Dinitrotoluene 5.6E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.4E-02 2.7E-02 2.2E-04 2-Acetylaminofluorene 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 2-Chloronaphthalene 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 2-Chlorophenol 1.9E-06 7.1E+00 9.9E-01 9.9E-01 6.8E-03 1.5E-01 9.1E-02 7.6E-04 2-Methylnaphthalene 3.6E-06 1.3E+01 1.9E+00 1.9E+00 1.3E-02 2.8E-01 1.7E-01 1.4E-03 2-Methylphenol 3.3E-06 1.2E+01 1.7E+00 1.7E+00 1.2E-02 2.6E-01 1.6E-01 1.3E-03 2-Naphthylamine 1.1E-05 4.1E+01 5.7E+00 5.7E+00 4.0E-02 8.6E-01 5.3E-01 4.4E-03 2-Nitroaniline 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 2-Nitrophenol 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 3,3'-Dichlorobenzidine 8.1E-06 3.0E+01 4.2E+00 4.2E+00 2.9E-02 6.3E-01 3.9E-01 3.2E-03 3,3'-Dimethylbenzidine 5.5E-05 2.1E+02 2.9E+01 2.9E+01 2.0E-01 4.3E+00 2.6E+00 2.2E-02 3-Methylcholanthrene 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 3-Methylphenol & 4-Methylphenol 2.2E-06 8.2E+00 1.1E+00 1.1E+00 7.9E-03 1.7E-01 1.1E-01 8.8E-04 3-Nitroaniline 2.2E-06 8.2E+00 1.1E+00 1.1E+00 7.9E-03 1.7E-01 1.1E-01 8.8E-04 4,6-Dinitro-2-methylphenol 9.5E-06 3.6E+01 4.9E+00 4.9E+00 3.4E-02 7.4E-01 4.6E-01 3.8E-03 4-Aminobiphenyl 1.1E-05 4.1E+01 5.7E+00 5.7E+00 4.0E-02 8.6E-01 5.3E-01 4.4E-03 4-Bromophenyl phenyl ether 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 4-Chloro-3-methylphenol 6.8E-07 2.5E+00 3.5E-01 3.5E-01 2.4E-03 5.3E-02 3.3E-02 2.7E-04 4-Chloroaniline 6.6E-06 2.5E+01 3.4E+00 3.4E+00 2.4E-02 5.1E-01 3.2E-01 2.6E-03 4-Nitroaniline 2.2E-06 8.2E+00 1.1E+00 1.1E+00 7.9E-03 1.7E-01 1.1E-01 8.8E-04 4-Nitrophenol 3.6E-06 1.3E+01 1.9E+00 1.9E+00 1.3E-02 2.8E-01 1.7E-01 1.4E-03 7,12-Dimethylbenz(a)anthracene 5.6E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.4E-02 2.7E-02 2.2E-04 Acenaphthene 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 Acenaphthylene 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 Acetophenone 2.7E-06 1.0E+01 1.4E+00 1.4E+00 9.7E-03 2.1E-01 1.3E-01 1.1E-03 Aniline 8.0E-06 3.0E+01 4.2E+00 4.2E+00 2.9E-02 6.2E-01 3.8E-01 3.2E-03 Analyte Conservative Emission Factor (lbs/lb) M-136 Quantities (lbs/year)M-225 Quantities (lbs/year) TABLE OR APPENDIX 3-??? 1.3 CLASS WASTE MATERIAL CONSERVATIVE ANNUAL EMISSION RATES (LBS/YR) ATK PROMONTORY, UTAH PAGE 2 OF 5 1 2 3 4 5 1 2 Analyte Conservative Emission Factor (lbs/lb) M-136 Quantities (lbs/year)M-225 Quantities (lbs/year) Anthracene 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 Benzidine 5.6E-05 2.1E+02 2.9E+01 2.9E+01 2.0E-01 4.4E+00 2.7E+00 2.2E-02 Benzo(a)anthracene 6.4E-07 2.4E+00 3.3E-01 3.3E-01 2.3E-03 5.0E-02 3.1E-02 2.6E-04 Benzo(a)pyrene 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 Benzo(b)fluoranthene 1.2E-06 4.5E+00 6.2E-01 6.2E-01 4.3E-03 9.4E-02 5.8E-02 4.8E-04 Benzo(ghi)perylene 6.8E-07 2.5E+00 3.5E-01 3.5E-01 2.4E-03 5.3E-02 3.3E-02 2.7E-04 Benzo(k)fluoranthene 1.8E-06 6.7E+00 9.4E-01 9.4E-01 6.5E-03 1.4E-01 8.6E-02 7.2E-04 Benzoic acid 6.2E-05 2.3E+02 3.2E+01 3.2E+01 2.2E-01 4.8E+00 3.0E+00 2.5E-02 Benzyl alcohol 3.8E-05 1.4E+02 2.0E+01 2.0E+01 1.4E-01 3.0E+00 1.8E+00 1.5E-02 bis(2-Chloroethoxy)methane 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 bis(2-Chloroethyl) ether 6.1E-07 2.3E+00 3.2E-01 3.2E-01 2.2E-03 4.8E-02 2.9E-02 2.4E-04 bis(2-Chloroisopropyl) ether 8.3E-07 3.1E+00 4.3E-01 4.3E-01 3.0E-03 6.5E-02 4.0E-02 3.3E-04 bis(2-Ethylhexyl) phthalate 1.1E-05 4.1E+01 5.7E+00 5.7E+00 4.0E-02 8.6E-01 5.3E-01 4.4E-03 Butyl benzyl phthalate 6.7E-07 2.5E+00 3.5E-01 3.5E-01 2.4E-03 5.2E-02 3.2E-02 2.7E-04 Carbazole 7.0E-07 2.6E+00 3.6E-01 3.6E-01 2.5E-03 5.5E-02 3.4E-02 2.8E-04 Chrysene 7.0E-07 2.6E+00 3.6E-01 3.6E-01 2.5E-03 5.5E-02 3.4E-02 2.8E-04 Dibenz(a,h)anthracene 6.6E-07 2.5E+00 3.4E-01 3.4E-01 2.4E-03 5.1E-02 3.2E-02 2.6E-04 Dibenzofuran 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 Diethyl phthalate 8.0E-07 3.0E+00 4.2E-01 4.2E-01 2.9E-03 6.2E-02 3.8E-02 3.2E-04 Dimethyl phthalate 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 Di-n-butyl phthalate 1.1E-05 4.1E+01 5.7E+00 5.7E+00 4.0E-02 8.6E-01 5.3E-01 4.4E-03 Di-n-octyl phthalate 3.7E-06 1.4E+01 1.9E+00 1.9E+00 1.3E-02 2.9E-01 1.8E-01 1.5E-03 Diphenylamine 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 Ethyl methanesulfonate 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 Fluoranthene 5.9E-07 2.2E+00 3.1E-01 3.1E-01 2.1E-03 4.6E-02 2.8E-02 2.4E-04 Fluorene 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 Hexachlorobenzene 4.7E-06 1.8E+01 2.4E+00 2.4E+00 1.7E-02 3.7E-01 2.3E-01 1.9E-03 Hexachlorobutadiene 8.1E-07 3.0E+00 4.2E-01 4.2E-01 2.9E-03 6.3E-02 3.9E-02 3.2E-04 Hexachlorocyclopentadiene 1.1E-05 4.1E+01 5.7E+00 5.7E+00 4.0E-02 8.6E-01 5.3E-01 4.4E-03 Hexachloroethane 5.9E-07 2.2E+00 3.1E-01 3.1E-01 2.1E-03 4.6E-02 2.8E-02 2.4E-04 Hexachloropropene 7.9E-07 3.0E+00 4.1E-01 4.1E-01 2.8E-03 6.2E-02 3.8E-02 3.2E-04 Indeno(1,2,3-cd)pyrene 5.9E-07 2.2E+00 3.1E-01 3.1E-01 2.1E-03 4.6E-02 2.8E-02 2.4E-04 Isophorone 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 Methyl methanesulfonate 6.0E-07 2.2E+00 3.1E-01 3.1E-01 2.2E-03 4.7E-02 2.9E-02 2.4E-04 Naphthalene 1.4E-05 5.2E+01 7.3E+00 7.3E+00 5.0E-02 1.1E+00 6.7E-01 5.6E-03 Nitrobenzene 6.2E-07 2.3E+00 3.2E-01 3.2E-01 2.2E-03 4.8E-02 3.0E-02 2.5E-04 N-Nitro-o-toluidine 8.8E-06 3.3E+01 4.6E+00 4.6E+00 3.2E-02 6.9E-01 4.2E-01 3.5E-03 N-Nitrosodiethylamine 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 N-Nitrosodimethylamine 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 N-Nitrosodi-n-butylamine 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 N-Nitrosodi-n-propylamine 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 N-Nitrosodiphenylamine 9.5E-07 3.6E+00 4.9E-01 4.9E-01 3.4E-03 7.4E-02 4.6E-02 3.8E-04 N-Nitrosomethylethylamine 9.1E-07 3.4E+00 4.7E-01 4.7E-01 3.3E-03 7.1E-02 4.4E-02 3.6E-04 N-Nitrosomorpholine 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 o-Toluidine 7.0E-06 2.6E+01 3.6E+00 3.6E+00 2.5E-02 5.5E-01 3.4E-01 2.8E-03 p-Dimethylaminoazobenzene 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 Pentachlorobenzene 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 Pentachloroethane 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 Pentachloronitrobenzene 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 2.2E-04 Pentachlorophenol 2.7E-05 1.0E+02 1.4E+01 1.4E+01 9.7E-02 2.1E+00 1.3E+00 1.1E-02 Phenanthrene 7.0E-07 2.6E+00 3.6E-01 3.6E-01 2.5E-03 5.5E-02 3.4E-02 2.8E-04 Phenol 2.4E-06 9.0E+00 1.2E+00 1.2E+00 8.6E-03 1.9E-01 1.2E-01 9.6E-04 Pyrene 5.8E-07 2.2E+00 3.0E-01 3.0E-01 2.1E-03 4.5E-02 2.8E-02 2.3E-04 Pyridine 8.1E-07 3.0E+00 4.2E-01 4.2E-01 2.9E-03 6.3E-02 3.9E-02 3.2E-04 Dioxins/Furans 2,3,7,8-TCDD 2.3E-12 8.6E-06 1.2E-06 1.2E-06 8.3E-09 1.8E-07 1.1E-07 5.5E-09 1,2,3,7,8-PeCDD 6.7E-12 2.5E-05 3.5E-06 3.5E-06 2.4E-08 5.2E-07 3.2E-07 1.6E-08 1,2,3,4,7,8-HxCDD 3.5E-12 1.3E-05 1.8E-06 1.8E-06 1.3E-08 2.7E-07 1.7E-07 8.4E-09 1,2,3,6,7,8-HxCDD 8.9E-12 3.3E-05 4.6E-06 4.6E-06 3.2E-08 6.9E-07 4.3E-07 2.1E-08 1,2,3,7,8,9-HxCDD 6.1E-12 2.3E-05 3.2E-06 3.2E-06 2.2E-08 4.8E-07 2.9E-07 1.5E-08 1,2,3,4,6,7,8-HpCDD 2.9E-11 1.1E-04 1.5E-05 1.5E-05 1.0E-07 2.3E-06 1.4E-06 7.0E-08 OCDD 3.7E-11 1.4E-04 1.9E-05 1.9E-05 1.3E-07 2.9E-06 1.8E-06 8.9E-08 2,3,7,8-TCDF 4.0E-11 1.5E-04 2.1E-05 2.1E-05 1.4E-07 3.1E-06 1.9E-06 9.6E-08 1,2,3,7,8-PeCDF 8.0E-11 3.0E-04 4.2E-05 4.2E-05 2.9E-07 6.2E-06 3.8E-06 1.9E-07 2,3,4,7,8-PeCDF 1.6E-10 6.0E-04 8.3E-05 8.3E-05 5.8E-07 1.2E-05 7.7E-06 3.8E-07 1,2,3,4,7,8-HxCDF 2.6E-10 9.7E-04 1.4E-04 1.4E-04 9.4E-07 2.0E-05 1.2E-05 6.2E-07 1,2,3,6,7,8-HxCDF 1.6E-10 6.0E-04 8.3E-05 8.3E-05 5.8E-07 1.2E-05 7.7E-06 3.8E-07 2,3,4,6,7,8-HxCDF 1.9E-10 7.1E-04 9.9E-05 9.9E-05 6.8E-07 1.5E-05 9.1E-06 4.6E-07 1,2,3,7,8,9-HxCDF 1.2E-10 4.5E-04 6.2E-05 6.2E-05 4.3E-07 9.4E-06 5.8E-06 2.9E-07 1,2,3,4,6,7,8-HpCDF 7.3E-10 2.7E-03 3.8E-04 3.8E-04 2.6E-06 5.7E-05 3.5E-05 1.8E-06 TABLE OR APPENDIX 3-??? 1.3 CLASS WASTE MATERIAL CONSERVATIVE ANNUAL EMISSION RATES (LBS/YR) ATK PROMONTORY, UTAH PAGE 3 OF 5 1 2 3 4 5 1 2 Analyte Conservative Emission Factor (lbs/lb) M-136 Quantities (lbs/year)M-225 Quantities (lbs/year) 1,2,3,4,7,8,9-HpCDF 1.9E-10 7.1E-04 9.9E-05 9.9E-05 6.8E-07 1.5E-05 9.1E-06 4.6E-07 OCDF 5.3E-10 2.0E-03 2.8E-04 2.8E-04 1.9E-06 4.1E-05 1.1E-06 1.3E-06 Carbonyls 2,5-Dimethylbenzaldehyde 2.7E-05 1.0E+02 1.4E+01 1.4E+01 9.7E-02 2.1E+00 1.3E+00 6.5E-02 Acetaldehyde 9.3E-05 3.5E+02 4.8E+01 4.8E+01 3.3E-01 7.3E+00 4.5E+00 2.2E-01 Acetone 3.1E-05 1.2E+02 1.6E+01 1.6E+01 1.1E-01 2.4E+00 1.5E+00 7.4E-02 Benzaldehyde 1.4E-05 5.2E+01 7.3E+00 7.3E+00 5.0E-02 1.1E+00 6.7E-01 3.4E-02 Crotonaldehyde 1.4E-05 5.2E+01 7.3E+00 7.3E+00 5.0E-02 1.1E+00 6.7E-01 3.4E-02 Formaldehyde 4.7E-05 1.8E+02 2.4E+01 2.4E+01 1.7E-01 3.7E+00 2.3E+00 1.1E-01 Hexanal 1.4E-05 5.2E+01 7.3E+00 7.3E+00 5.0E-02 1.1E+00 6.7E-01 3.4E-02 Isopentanal 1.4E-05 5.2E+01 7.3E+00 7.3E+00 5.0E-02 1.1E+00 6.7E-01 3.4E-02 m,p-Tolualdehyde 1.4E-05 5.2E+01 7.3E+00 7.3E+00 5.0E-02 1.1E+00 6.7E-01 3.4E-02 MEK/Butyraldehydes 1.4E-05 5.2E+01 7.3E+00 7.3E+00 5.0E-02 1.1E+00 6.7E-01 3.4E-02 o-Tolualdehyde 4.0E-05 1.5E+02 2.1E+01 2.1E+01 1.4E-01 3.1E+00 1.9E+00 9.6E-02 Pentanal 1.7E-05 6.4E+01 8.8E+00 8.8E+00 6.1E-02 1.3E+00 8.2E-01 4.1E-02 Propanal 5.2E-05 1.9E+02 2.7E+01 2.7E+01 1.9E-01 4.1E+00 2.5E+00 1.2E-01 HCl/Cl2/NH3 HCl 1.8E-02 6.7E+04 9.4E+03 9.4E+03 6.5E+01 1.4E+03 8.6E+02 4.3E+01 Cl2 1.2E-02 4.5E+04 6.2E+03 6.2E+03 4.3E+01 9.4E+02 5.8E+02 2.9E+01 NH3 3.2E-05 1.2E+02 1.7E+01 1.7E+01 1.2E-01 2.5E+00 1.5E+00 7.7E-02 HCN 2.2E-05 8.2E+01 1.1E+01 #REF!7.9E-02 1.7E+00 1.1E+00 5.3E-02 VOCs TNMOC 9.4E-04 3.5E+03 4.9E+02 4.9E+02 3.4E+00 7.3E+01 4.5E+01 2.3E+00 1,1,1-Trichloroethane 8.9E-07 3.3E+00 4.6E-01 4.6E-01 3.2E-03 6.9E-02 4.3E-02 2.1E-03 1,1,2,2-Tetrachloroethane 4.2E-07 1.6E+00 2.2E-01 2.2E-01 1.5E-03 3.3E-02 2.0E-02 1.0E-03 1,1,2-Trichloroethane 7.3E-07 2.7E+00 3.8E-01 3.8E-01 2.6E-03 5.7E-02 3.5E-02 1.8E-03 1,1-Dichloroethane 3.2E-07 1.2E+00 1.7E-01 1.7E-01 1.2E-03 2.5E-02 1.5E-02 7.7E-04 1,1-Dichloroethene 4.3E-07 1.6E+00 2.2E-01 2.2E-01 1.5E-03 3.4E-02 2.1E-02 1.0E-03 1,2,3-Trimethylbenzene 4.2E-07 1.6E+00 2.2E-01 2.2E-01 1.5E-03 3.3E-02 2.0E-02 1.0E-03 1,2,4-Trichlorobenzene 1.3E-06 4.9E+00 6.8E-01 6.8E-01 4.7E-03 1.0E-01 6.2E-02 3.1E-03 1,2,4-Trimethylbenzene 5.2E-06 1.9E+01 2.7E+00 2.7E+00 1.9E-02 4.1E-01 2.5E-01 1.2E-02 1,2-Dibromomethane (EDB)8.9E-07 3.3E+00 4.6E-01 4.6E-01 3.2E-03 6.9E-02 4.3E-02 2.1E-03 1,2-Dichlorobenzene 4.8E-07 1.8E+00 2.5E-01 2.5E-01 1.7E-03 3.7E-02 2.3E-02 1.2E-03 1,2-Dichloroethane 5.4E-07 2.0E+00 2.8E-01 2.8E-01 1.9E-03 4.2E-02 2.6E-02 1.3E-03 1,2-Dichloropropane 3.7E-07 1.4E+00 1.9E-01 1.9E-01 1.3E-03 2.9E-02 1.8E-02 8.9E-04 1,3,5-Trimethylbenzene 2.0E-06 7.5E+00 1.0E+00 1.0E+00 7.2E-03 1.6E-01 9.6E-02 4.8E-03 1,3-Butadiene 2.4E-05 9.0E+01 1.2E+01 1.2E+01 8.6E-02 1.9E+00 1.2E+00 5.8E-02 1,3-Dichlorobenzene 4.4E-07 1.6E+00 2.3E-01 2.3E-01 1.6E-03 3.4E-02 2.1E-02 1.1E-03 1,3-Diethylbenzene 5.0E-07 1.9E+00 2.6E-01 2.6E-01 1.8E-03 3.9E-02 2.4E-02 1.2E-03 1,4-Dichlorobenzene 7.3E-07 2.7E+00 3.8E-01 3.8E-01 2.6E-03 5.7E-02 3.5E-02 1.8E-03 1,4-Diethylbenzene 6.7E-07 2.5E+00 3.5E-01 3.5E-01 2.4E-03 5.2E-02 3.2E-02 1.6E-03 1,4-Dioxane 6.4E-07 2.4E+00 3.3E-01 3.3E-01 2.3E-03 5.0E-02 3.1E-02 1.5E-03 1-Butene 2.2E-05 8.2E+01 1.1E+01 1.1E+01 7.9E-02 1.7E+00 1.1E+00 5.3E-02 1-Hexene 2.0E-05 7.5E+01 1.0E+01 1.0E+01 7.2E-02 1.6E+00 9.6E-01 4.8E-02 1-Pentene 1.2E-05 4.5E+01 6.2E+00 6.2E+00 4.3E-02 9.4E-01 5.8E-01 2.9E-02 2,2,4-Trimethylpentane 2.3E-06 8.6E+00 1.2E+00 1.2E+00 8.3E-03 1.8E-01 1.1E-01 5.5E-03 2,2-Dimethylbutane 8.8E-07 3.3E+00 4.6E-01 4.6E-01 3.2E-03 6.9E-02 4.2E-02 2.1E-03 2,3,4-Trimethylpentane 2.8E-07 1.0E+00 1.5E-01 1.5E-01 1.0E-03 2.2E-02 1.3E-02 6.7E-04 2,3-Dimethylbutane 2.9E-06 1.1E+01 1.5E+00 1.5E+00 1.0E-02 2.3E-01 1.4E-01 7.0E-03 2,3-Dimethylpentane 2.7E-06 1.0E+01 1.4E+00 1.4E+00 9.7E-03 2.1E-01 1.3E-01 6.5E-03 2,4-Dimethylpentane 1.1E-06 4.1E+00 5.7E-01 5.7E-01 4.0E-03 8.6E-02 5.3E-02 2.6E-03 2-Butanone (MEK)3.9E-06 1.5E+01 2.0E+00 2.0E+00 1.4E-02 3.0E-01 1.9E-01 9.4E-03 2-Ethyltoluene 4.5E-07 1.7E+00 2.3E-01 2.3E-01 1.6E-03 3.5E-02 2.2E-02 1.1E-03 2-Hexanone 8.7E-07 3.3E+00 4.5E-01 4.5E-01 3.1E-03 6.8E-02 4.2E-02 2.1E-03 2-Methylheptane 2.7E-06 1.0E+01 1.4E+00 1.4E+00 9.7E-03 2.1E-01 1.3E-01 6.5E-03 2-Methylhexane 4.4E-06 1.6E+01 2.3E+00 2.3E+00 1.6E-02 3.4E-01 2.1E-01 1.1E-02 2-Methylpentane 1.1E-05 4.1E+01 5.7E+00 5.7E+00 4.0E-02 8.6E-01 5.3E-01 2.6E-02 2-Nitropropane 2.8E-06 1.0E+01 1.5E+00 1.5E+00 1.0E-02 2.2E-01 1.3E-01 6.7E-03 2-Propanol 3.0E-07 1.1E+00 1.6E-01 1.6E-01 1.1E-03 2.3E-02 1.4E-02 7.2E-04 3-Chloropropene 4.7E-06 1.8E+01 2.4E+00 2.4E+00 1.7E-02 3.7E-01 2.3E-01 1.1E-02 3-Ethyltoluene 4.8E-06 1.8E+01 2.5E+00 2.5E+00 1.7E-02 3.7E-01 2.3E-01 1.2E-02 3-Methylheptane 3.5E-06 1.3E+01 1.8E+00 1.8E+00 1.3E-02 2.7E-01 1.7E-01 8.4E-03 3-Methylhexane 5.2E-06 1.9E+01 2.7E+00 2.7E+00 1.9E-02 4.1E-01 2.5E-01 1.2E-02 3-Methylpentane 7.1E-06 2.7E+01 3.7E+00 3.7E+00 2.6E-02 5.5E-01 3.4E-01 1.7E-02 4-Ethyltoluene 5.3E-06 2.0E+01 2.8E+00 2.8E+00 1.9E-02 4.1E-01 2.5E-01 1.3E-02 4-Methyl-2-pentanone 7.0E-07 2.6E+00 3.6E-01 3.6E-01 2.5E-03 5.5E-02 3.4E-02 1.7E-03 Acetone 2.4E-05 9.0E+01 1.2E+01 1.2E+01 8.6E-02 1.9E+00 1.2E+00 5.8E-02 TABLE OR APPENDIX 3-??? 1.3 CLASS WASTE MATERIAL CONSERVATIVE ANNUAL EMISSION RATES (LBS/YR) ATK PROMONTORY, UTAH PAGE 4 OF 5 1 2 3 4 5 1 2 Analyte Conservative Emission Factor (lbs/lb) M-136 Quantities (lbs/year)M-225 Quantities (lbs/year) Acetonitrile 1.9E-05 7.1E+01 9.9E+00 9.9E+00 6.8E-02 1.5E+00 9.1E-01 4.6E-02 Acetylene 9.4E-05 3.5E+02 4.9E+01 4.9E+01 3.4E-01 7.3E+00 4.5E+00 2.3E-01 Acrylonitrile 1.6E-05 6.0E+01 8.3E+00 8.3E+00 5.8E-02 1.2E+00 7.7E-01 3.8E-02 alpha-Chlorotoluene 5.7E-07 2.1E+00 3.0E-01 3.0E-01 2.1E-03 4.4E-02 2.7E-02 1.4E-03 Benzene 4.7E-05 1.8E+02 2.4E+01 2.4E+01 1.7E-01 3.7E+00 2.3E+00 1.1E-01 Bromodichloromethane 7.8E-07 2.9E+00 4.1E-01 4.1E-01 2.8E-03 6.1E-02 3.7E-02 1.9E-03 Bromoform 1.3E-06 4.9E+00 6.8E-01 6.8E-01 4.7E-03 1.0E-01 6.2E-02 3.1E-03 Bromomethane 6.2E-07 2.3E+00 3.2E-01 3.2E-01 2.2E-03 4.8E-02 3.0E-02 1.5E-03 Butane 1.8E-05 6.7E+01 9.4E+00 9.4E+00 6.5E-02 1.4E+00 8.6E-01 4.3E-02 Carbon Disulfide 9.8E-06 3.7E+01 5.1E+00 5.1E+00 3.5E-02 7.6E-01 4.7E-01 2.4E-02 Carbon Tetrachloride 1.5E-05 5.6E+01 7.8E+00 7.8E+00 5.4E-02 1.2E+00 7.2E-01 3.6E-02 Chloroacetonitrile 1.1E-06 4.1E+00 5.7E-01 5.7E-01 4.0E-03 8.6E-02 5.3E-02 2.6E-03 Chlorobenzene 2.5E-06 9.4E+00 1.3E+00 1.3E+00 9.0E-03 2.0E-01 1.2E-01 6.0E-03 Chloroethane 2.6E-07 9.7E-01 1.4E-01 1.4E-01 9.4E-04 2.0E-02 1.2E-02 6.2E-04 Chloroform 6.1E-06 2.3E+01 3.2E+00 3.2E+00 2.2E-02 4.8E-01 2.9E-01 1.5E-02 Chloromethane 1.4E-05 5.2E+01 7.3E+00 7.3E+00 5.0E-02 1.1E+00 6.7E-01 3.4E-02 cis-1,2-Dichloroethene 4.6E-07 1.7E+00 2.4E-01 2.4E-01 1.7E-03 3.6E-02 2.2E-02 1.1E-03 cis-1,3-Dichloropropene 1.3E-06 4.9E+00 6.8E-01 6.8E-01 4.7E-03 1.0E-01 6.2E-02 3.1E-03 cis-2-Butene 1.7E-06 6.4E+00 8.8E-01 8.8E-01 6.1E-03 1.3E-01 8.2E-02 4.1E-03 cis-2-Pentene 3.3E-07 1.2E+00 1.7E-01 1.7E-01 1.2E-03 2.6E-02 1.6E-02 7.9E-04 Cumene 4.2E-07 1.6E+00 2.2E-01 2.2E-01 1.5E-03 3.3E-02 2.0E-02 1.0E-03 Cyclohexane 2.5E-06 9.4E+00 1.3E+00 1.3E+00 9.0E-03 2.0E-01 1.2E-01 6.0E-03 Cyclopentane 1.8E-06 6.7E+00 9.4E-01 9.4E-01 6.5E-03 1.4E-01 8.6E-02 4.3E-03 Decane 1.7E-05 6.4E+01 8.8E+00 8.8E+00 6.1E-02 1.3E+00 8.2E-01 4.1E-02 Dibromochloromethane 8.8E-07 3.3E+00 4.6E-01 4.6E-01 3.2E-03 6.9E-02 4.2E-02 2.1E-03 Ethane 2.1E-05 7.9E+01 1.1E+01 1.1E+01 7.6E-02 1.6E+00 1.0E+00 5.0E-02 Ethanol 1.6E-06 6.0E+00 8.3E-01 8.3E-01 5.8E-03 1.2E-01 7.7E-02 3.8E-03 Ethene 1.8E-04 6.7E+02 9.4E+01 9.4E+01 6.5E-01 1.4E+01 8.6E+00 4.3E-01 Ethyl benzene 2.8E-06 1.0E+01 1.5E+00 1.5E+00 1.0E-02 2.2E-01 1.3E-01 6.7E-03 Ethyl ether 2.5E-06 9.4E+00 1.3E+00 1.3E+00 9.0E-03 2.0E-01 1.2E-01 6.0E-03 Ethyl Methacrylate 1.6E-06 6.0E+00 8.3E-01 8.3E-01 5.8E-03 1.2E-01 7.7E-02 3.8E-03 Heptane 7.2E-06 2.7E+01 3.7E+00 3.7E+00 2.6E-02 5.6E-01 3.5E-01 1.7E-02 Hexachlorobutadiene 1.7E-06 6.4E+00 8.8E-01 8.8E-01 6.1E-03 1.3E-01 8.2E-02 4.1E-03 Hexane 9.8E-06 3.7E+01 5.1E+00 5.1E+00 3.5E-02 7.6E-01 4.7E-01 2.4E-02 Isobutane 2.8E-06 1.0E+01 1.5E+00 1.5E+00 1.0E-02 2.2E-01 1.3E-01 6.7E-03 Isopentane 2.0E-05 7.5E+01 1.0E+01 1.0E+01 7.2E-02 1.6E+00 9.6E-01 4.8E-02 m,p-Xylene 1.1E-05 4.1E+01 5.7E+00 5.7E+00 4.0E-02 8.6E-01 5.3E-01 2.6E-02 Methacrylonitrile 4.9E-06 1.8E+01 2.5E+00 2.5E+00 1.8E-02 3.8E-01 2.4E-01 1.2E-02 Methyl Acrylate 1.2E-06 4.5E+00 6.2E-01 6.2E-01 4.3E-03 9.4E-02 5.8E-02 2.9E-03 Methyl Methacrylate 1.6E-06 6.0E+00 8.3E-01 8.3E-01 5.8E-03 1.2E-01 7.7E-02 3.8E-03 Methyl tert-butyl ether 4.2E-07 1.6E+00 2.2E-01 2.2E-01 1.5E-03 3.3E-02 2.0E-02 1.0E-03 Methylcyclohexane 6.1E-06 2.3E+01 3.2E+00 3.2E+00 2.2E-02 4.8E-01 2.9E-01 1.5E-02 Methylcyclopentane 5.6E-06 2.1E+01 2.9E+00 2.9E+00 2.0E-02 4.4E-01 2.7E-01 1.3E-02 Methylene chloride 7.1E-06 2.7E+01 3.7E+00 3.7E+00 2.6E-02 5.5E-01 3.4E-01 1.7E-02 n-Butylchloride 1.2E-05 4.5E+01 6.2E+00 6.2E+00 4.3E-02 9.4E-01 5.8E-01 2.9E-02 Nonane 1.3E-05 4.9E+01 6.8E+00 6.8E+00 4.7E-02 1.0E+00 6.2E-01 3.1E-02 Octane 7.5E-06 2.8E+01 3.9E+00 3.9E+00 2.7E-02 5.9E-01 3.6E-01 1.8E-02 o-Xylene 3.5E-06 1.3E+01 1.8E+00 1.8E+00 1.3E-02 2.7E-01 1.7E-01 8.4E-03 Pentane 1.9E-05 7.1E+01 9.9E+00 9.9E+00 6.8E-02 1.5E+00 9.1E-01 4.6E-02 Propane 8.7E-06 3.3E+01 4.5E+00 4.5E+00 3.1E-02 6.8E-01 4.2E-01 2.1E-02 Propylbenzene 1.0E-06 3.7E+00 5.2E-01 5.2E-01 3.6E-03 7.8E-02 4.8E-02 2.4E-03 Propylene 4.9E-05 1.8E+02 2.5E+01 2.5E+01 1.8E-01 3.8E+00 2.4E+00 1.2E-01 Styrene 9.9E-07 3.7E+00 5.1E-01 5.1E-01 3.6E-03 7.7E-02 4.8E-02 2.4E-03 Tetrachloroethene 2.5E-06 9.4E+00 1.3E+00 1.3E+00 9.0E-03 2.0E-01 1.2E-01 6.0E-03 Tetrahydrofuran 9.0E-07 3.4E+00 4.7E-01 4.7E-01 3.2E-03 7.0E-02 4.3E-02 2.2E-03 Toluene 1.9E-05 7.1E+01 9.9E+00 9.9E+00 6.8E-02 1.5E+00 9.1E-01 4.6E-02 trans-1,2-Dichloroethene 7.2E-07 2.7E+00 3.7E-01 3.7E-01 2.6E-03 5.6E-02 3.5E-02 1.7E-03 trans-1,3-Dichloropropene 6.1E-07 2.3E+00 3.2E-01 3.2E-01 2.2E-03 4.8E-02 2.9E-02 1.5E-03 trans-2-butene 7.7E-06 2.9E+01 4.0E+00 4.0E+00 2.8E-02 6.0E-01 3.7E-01 1.8E-02 trans-2-Pentene 1.7E-06 6.4E+00 8.8E-01 8.8E-01 6.1E-03 1.3E-01 8.2E-02 4.1E-03 Trichloroethene 9.4E-07 3.5E+00 4.9E-01 4.9E-01 3.4E-03 7.3E-02 4.5E-02 2.3E-03 Undecane 1.2E-05 4.5E+01 6.2E+00 6.2E+00 4.3E-02 9.4E-01 5.8E-01 2.9E-02 Vinyl chloride 7.6E-06 2.8E+01 4.0E+00 4.0E+00 2.7E-02 5.9E-01 3.6E-01 1.8E-02 CEM CO2 7.20E-01 2.7E+06 3.7E+05 3.7E+05 2.6E+03 5.6E+04 3.5E+04 1.7E+03 CO 6.40E-03 2.4E+04 3.3E+03 3.3E+03 2.3E+01 5.0E+02 3.1E+02 1.5E+01 NOX 6.40E-03 2.4E+04 3.3E+03 3.3E+03 2.3E+01 5.0E+02 3.1E+02 1.5E+01 SO2 5.00E-04 1.9E+03 2.6E+02 2.6E+02 1.8E+00 3.9E+01 2.4E+01 1.2E+00 Highlighted analytes were not detected during the Bang Box testing program TABLE OR APPENDIX 3-??? 1.3 CLASS WASTE MATERIAL CONSERVATIVE ANNUAL EMISSION RATES (LBS/YR) ATK PROMONTORY, UTAH PAGE 5 OF 5 1 2 3 4 5 1 2 Analyte Conservative Emission Factor (lbs/lb) M-136 Quantities (lbs/year)M-225 Quantities (lbs/year) CEM - Continuous Emissions Monitoring CL2 - chlorine CO - carbon monoxide CO2 - carbon dioxide HCL - hydrogen chloride HCN - hydrogen cyanide NH3 - ammonia NOX - nitrogen oxide OCDD - 1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin OCDF - 1,2,3,4,6,7,8,9-Octachlorodibenzo-p-furan PM10 - particulate matter less than 10 microns in aerodynamic diameter PM2.5 - particulate matter less than 2.5 microns in aerodynamic diameter SO2 - sulfur dioxide SVOCs - semi-volatile organic compounds TNMOC - total non-methane organic carbon TSP - Total suspended particulates VOCs - volatile organic compounds TABLE OR APPENDIX ??? 1.3 CLASS WASTE MATERIAL PER EVENT (1-HOUR) CORRECTED EMISSION RATES (LBS/HR) ATK PROMONTORY, UTAH PAGE 1 OF 5 1 2 3 4 5 1 2 Particulates TSP 1.4E-01 1.7E+03 1.4E+03 1.4E+03 8.4E+01 3.6E+03 2.8E+02 5.6E+01 PM10 8.6E-02 1.0E+03 8.6E+02 8.6E+02 5.2E+01 2.2E+03 1.7E+02 3.4E+01 PM2.5 5.9E-02 7.1E+02 5.9E+02 5.9E+02 3.5E+01 1.5E+03 1.2E+02 2.4E+01 Metals Aluminum 4.0E-02 4.8E+02 4.0E+02 4.0E+02 2.4E+01 1.0E+03 8.0E+01 1.6E+01 Antimony 2.9E-05 3.5E-01 2.9E-01 2.9E-01 1.7E-02 7.5E-01 5.8E-02 1.2E-02 Arsenic 3.0E-07 3.6E-03 3.0E-03 3.0E-03 1.8E-04 7.8E-03 6.0E-04 1.2E-04 Barium 4.9E-06 5.9E-02 4.9E-02 4.9E-02 2.9E-03 1.3E-01 9.8E-03 2.0E-03 Cadmium 3.1E-07 3.7E-03 3.1E-03 3.1E-03 1.9E-04 8.1E-03 6.2E-04 1.2E-04 Chromium 2.0E-05 2.4E-01 2.0E-01 2.0E-01 1.2E-02 5.2E-01 4.0E-02 8.0E-03 Cobalt 3.1E-07 3.7E-03 3.1E-03 3.1E-03 1.9E-04 8.1E-03 6.2E-04 1.2E-04 Copper 2.5E-05 3.0E-01 2.5E-01 2.5E-01 1.5E-02 6.5E-01 5.0E-02 1.0E-02 Lead 3.4E-05 4.1E-01 3.4E-01 3.4E-01 2.0E-02 8.8E-01 6.8E-02 1.4E-02 Magnesium 2.9E-05 3.5E-01 2.9E-01 2.9E-01 1.7E-02 7.5E-01 5.8E-02 1.2E-02 Manganese 9.3E-05 1.1E+00 9.3E-01 9.3E-01 5.6E-02 2.4E+00 1.9E-01 3.7E-02 Mercury 3.7E-08 4.4E-04 3.7E-04 3.7E-04 2.2E-05 9.6E-04 7.4E-05 1.5E-05 Nickel 5.8E-05 7.0E-01 5.8E-01 5.8E-01 3.5E-02 1.5E+00 1.2E-01 2.3E-02 Phosphorus 1.0E-04 1.2E+00 1.0E+00 1.0E+00 6.0E-02 2.6E+00 2.0E-01 4.0E-02 Selenium 1.7E-06 2.0E-02 1.7E-02 1.7E-02 1.0E-03 4.4E-02 3.4E-03 6.8E-04 Silver 9.5E-07 1.1E-02 9.5E-03 9.5E-03 5.7E-04 2.5E-02 1.9E-03 3.8E-04 Thallium 2.1E-06 2.5E-02 2.1E-02 2.1E-02 1.3E-03 5.5E-02 4.2E-03 8.4E-04 Zinc 3.5E-05 4.2E-01 3.5E-01 3.5E-01 2.1E-02 9.1E-01 7.0E-02 1.4E-02 Perchlorate 2.5E-07 2.7E-02 2.5E-03 2.5E-03 1.5E-04 6.5E-03 5.0E-04 1.0E-04 SVOCs 1,2,4,5-Tetrachlorobenzene 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 1,2,4-Trichlorobenzene 3.2E-07 3.8E-03 3.2E-03 3.2E-03 1.9E-04 8.3E-03 6.4E-04 1.3E-04 1,2-Dichlorobenzene 2.8E-07 3.4E-03 2.8E-03 2.8E-03 1.7E-04 7.3E-03 5.6E-04 1.1E-04 1,3,5-Trinitrobenzene 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 1,3-Dichlorobenzene 3.1E-07 3.7E-03 3.1E-03 3.1E-03 1.9E-04 8.1E-03 6.2E-04 1.2E-04 1,3-Dinitrobenzene 2.8E-07 3.4E-03 2.8E-03 2.8E-03 1.7E-04 7.3E-03 5.6E-04 1.1E-04 1,4-Dichlorobenzene 2.9E-07 3.5E-03 2.9E-03 2.9E-03 1.7E-04 7.5E-03 5.8E-04 1.2E-04 1-Chloronaphthalene 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 1-Naphthylamine 5.5E-06 6.6E-02 5.5E-02 5.5E-02 3.3E-03 1.4E-01 1.1E-02 2.2E-03 2,3,4,6-Tetrachlorophenol 3.6E-07 4.3E-03 3.6E-03 3.6E-03 2.2E-04 9.4E-03 7.2E-04 1.4E-04 2,4,5-Trichlorophenol 7.1E-07 8.5E-03 7.1E-03 7.1E-03 4.3E-04 1.8E-02 1.4E-03 2.8E-04 2,4,6-Trichlorophenol 1.30E-06 1.6E-02 1.3E-02 1.3E-02 7.8E-04 3.4E-02 2.6E-03 5.2E-04 2,4-Dichlorophenol 9.3E-07 1.1E-02 9.3E-03 9.3E-03 5.6E-04 2.4E-02 1.9E-03 3.7E-04 2,4-Dimethylphenol 3.5E-06 4.2E-02 3.5E-02 3.5E-02 2.1E-03 9.1E-02 7.0E-03 1.4E-03 2,4-Dinitrophenol 1.2E-05 1.4E-01 1.2E-01 1.2E-01 7.2E-03 3.1E-01 2.4E-02 4.8E-03 2,4-Dinitrotoluene 3.1E-07 3.7E-03 3.1E-03 3.1E-03 1.9E-04 8.1E-03 6.2E-04 1.2E-04 2,6-Dichlorophenol 4.0E-07 4.8E-03 4.0E-03 4.0E-03 2.4E-04 1.0E-02 8.0E-04 1.6E-04 2,6-Dinitrotoluene 5.6E-07 6.7E-03 5.6E-03 5.6E-03 3.4E-04 1.5E-02 1.1E-03 2.2E-04 2-Acetylaminofluorene 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 2-Chloronaphthalene 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 2-Chlorophenol 1.9E-06 2.3E-02 1.9E-02 1.9E-02 1.1E-03 4.9E-02 3.8E-03 7.6E-04 2-Methylnaphthalene 3.6E-06 4.3E-02 3.6E-02 3.6E-02 2.2E-03 9.4E-02 7.2E-03 1.4E-03 2-Methylphenol 1.6E-06 1.9E-02 1.6E-02 1.6E-02 9.6E-04 4.2E-02 3.2E-03 6.4E-04 2-Naphthylamine 5.5E-06 6.6E-02 5.5E-02 5.5E-02 3.3E-03 1.4E-01 1.1E-02 2.2E-03 2-Nitroaniline 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 2-Nitrophenol 3.9E-07 4.7E-03 3.9E-03 3.9E-03 2.3E-04 1.0E-02 7.8E-04 1.6E-04 3,3'-Dichlorobenzidine 4.1E-06 4.9E-02 4.1E-02 4.1E-02 2.5E-03 1.1E-01 8.2E-03 1.6E-03 3,3'-Dimethylbenzidine 2.7E-05 3.2E-01 2.7E-01 2.7E-01 1.6E-02 7.0E-01 5.4E-02 1.1E-02 3-Methylcholanthrene 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 3-Methylphenol & 4-Methylphenol 1.1E-06 1.3E-02 1.1E-02 1.1E-02 6.6E-04 2.9E-02 2.2E-03 4.4E-04 3-Nitroaniline 1.1E-06 1.3E-02 1.1E-02 1.1E-02 6.6E-04 2.9E-02 2.2E-03 4.4E-04 4,6-Dinitro-2-methylphenol 4.8E-06 5.8E-02 4.8E-02 4.8E-02 2.9E-03 1.2E-01 9.6E-03 1.9E-03 4-Aminobiphenyl 5.5E-06 6.6E-02 5.5E-02 5.5E-02 3.3E-03 1.4E-01 1.1E-02 2.2E-03 4-Bromophenyl phenyl ether 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 4-Chloro-3-methylphenol 3.4E-07 4.1E-03 3.4E-03 3.4E-03 2.0E-04 8.8E-03 6.8E-04 1.4E-04 4-Chloroaniline 3.3E-06 4.0E-02 3.3E-02 3.3E-02 2.0E-03 8.6E-02 6.6E-03 1.3E-03 4-Nitroaniline 1.1E-06 1.3E-02 1.1E-02 1.1E-02 6.6E-04 2.9E-02 2.2E-03 4.4E-04 4-Nitrophenol 1.8E-06 2.2E-02 1.8E-02 1.8E-02 1.1E-03 4.7E-02 3.6E-03 7.2E-04 7,12-Dimethylbenz(a)anthracene 2.8E-07 3.4E-03 2.8E-03 2.8E-03 1.7E-04 7.3E-03 5.6E-04 1.1E-04 Acenaphthene 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 Acenaphthylene 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 Acetophenone 2.7E-06 3.2E-02 2.7E-02 2.7E-02 1.6E-03 7.0E-02 5.4E-03 1.1E-03 Aniline 4.0E-06 4.8E-02 4.0E-02 4.0E-02 2.4E-03 1.0E-01 8.0E-03 1.6E-03 Analyte Corrected Emission Factor (lbs/lb) M-136 Quantities (lbs/hour)M-225 Quantities (lbs/hr) TABLE OR APPENDIX ??? 1.3 CLASS WASTE MATERIAL PER EVENT (1-HOUR) CORRECTED EMISSION RATES (LBS/HR) ATK PROMONTORY, UTAH PAGE 2 OF 5 1 2 3 4 5 1 2 Analyte Corrected Emission Factor (lbs/lb) M-136 Quantities (lbs/hour)M-225 Quantities (lbs/hr) Anthracene 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 Benzidine 2.8E-05 3.4E-01 2.8E-01 2.8E-01 1.7E-02 7.3E-01 5.6E-02 1.1E-02 Benzo(a)anthracene 3.2E-07 3.8E-03 3.2E-03 3.2E-03 1.9E-04 8.3E-03 6.4E-04 1.3E-04 Benzo(a)pyrene 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 Benzo(b)fluoranthene 6.0E-07 7.2E-03 6.0E-03 6.0E-03 3.6E-04 1.6E-02 1.2E-03 2.4E-04 Benzo(ghi)perylene 3.4E-07 4.1E-03 3.4E-03 3.4E-03 2.0E-04 8.8E-03 6.8E-04 1.4E-04 Benzo(k)fluoranthene 8.8E-07 1.1E-02 8.8E-03 8.8E-03 5.3E-04 2.3E-02 1.8E-03 3.5E-04 Benzoic acid 6.2E-05 7.4E-01 6.2E-01 6.2E-01 3.7E-02 1.6E+00 1.2E-01 2.5E-02 Benzyl alcohol 1.9E-05 2.3E-01 1.9E-01 1.9E-01 1.1E-02 4.9E-01 3.8E-02 7.6E-03 bis(2-Chloroethoxy)methane 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 bis(2-Chloroethyl) ether 3.1E-07 3.7E-03 3.1E-03 3.1E-03 1.9E-04 8.1E-03 6.2E-04 1.2E-04 bis(2-Chloroisopropyl) ether 4.2E-07 5.0E-03 4.2E-03 4.2E-03 2.5E-04 1.1E-02 8.4E-04 1.7E-04 bis(2-Ethylhexyl) phthalate 5.5E-06 6.6E-02 5.5E-02 5.5E-02 3.3E-03 1.4E-01 1.1E-02 2.2E-03 Butyl benzyl phthalate 3.3E-07 4.0E-03 3.3E-03 3.3E-03 2.0E-04 8.6E-03 6.6E-04 1.3E-04 Carbazole 3.5E-07 4.2E-03 3.5E-03 3.5E-03 2.1E-04 9.1E-03 7.0E-04 1.4E-04 Chrysene 3.5E-07 4.2E-03 3.5E-03 3.5E-03 2.1E-04 9.1E-03 7.0E-04 1.4E-04 Dibenz(a,h)anthracene 3.3E-07 4.0E-03 3.3E-03 3.3E-03 2.0E-04 8.6E-03 6.6E-04 1.3E-04 Dibenzofuran 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 Diethyl phthalate 4.0E-07 4.8E-03 4.0E-03 4.0E-03 2.4E-04 1.0E-02 8.0E-04 1.6E-04 Dimethyl phthalate 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 Di-n-butyl phthalate 5.5E-06 6.6E-02 5.5E-02 5.5E-02 3.3E-03 1.4E-01 1.1E-02 2.2E-03 Di-n-octyl phthalate 3.7E-06 4.4E-02 3.7E-02 3.7E-02 2.2E-03 9.6E-02 7.4E-03 1.5E-03 Diphenylamine 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 Ethyl methanesulfonate 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 Fluoranthene 4.0E-07 4.8E-03 4.0E-03 4.0E-03 2.4E-04 1.0E-02 8.0E-04 1.6E-04 Fluorene 4.2E-07 5.0E-03 4.2E-03 4.2E-03 2.5E-04 1.1E-02 8.4E-04 1.7E-04 Hexachlorobenzene 4.7E-06 5.6E-02 4.7E-02 4.7E-02 2.8E-03 1.2E-01 9.4E-03 1.9E-03 Hexachlorobutadiene 4.1E-07 4.9E-03 4.1E-03 4.1E-03 2.5E-04 1.1E-02 8.2E-04 1.6E-04 Hexachlorocyclopentadiene 5.5E-06 6.6E-02 5.5E-02 5.5E-02 3.3E-03 1.4E-01 1.1E-02 2.2E-03 Hexachloroethane 3.0E-07 3.6E-03 3.0E-03 3.0E-03 1.8E-04 7.8E-03 6.0E-04 1.2E-04 Hexachloropropene 3.9E-07 4.7E-03 3.9E-03 3.9E-03 2.3E-04 1.0E-02 7.8E-04 1.6E-04 Indeno(1,2,3-cd)pyrene 3.0E-07 3.6E-03 3.0E-03 3.0E-03 1.8E-04 7.8E-03 6.0E-04 1.2E-04 Isophorone 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 Methyl methanesulfonate 3.0E-07 3.6E-03 3.0E-03 3.0E-03 1.8E-04 7.8E-03 6.0E-04 1.2E-04 Naphthalene 1.3E-05 1.6E-01 1.3E-01 1.3E-01 7.8E-03 3.4E-01 2.6E-02 5.2E-03 Nitrobenzene 3.1E-07 3.7E-03 3.1E-03 3.1E-03 1.9E-04 8.1E-03 6.2E-04 1.2E-04 N-Nitro-o-toluidine 4.4E-06 5.3E-02 4.4E-02 4.4E-02 2.6E-03 1.1E-01 8.8E-03 1.8E-03 N-Nitrosodiethylamine 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 N-Nitrosodimethylamine 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 N-Nitrosodi-n-butylamine 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 N-Nitrosodi-n-propylamine 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 N-Nitrosodiphenylamine 4.8E-07 5.8E-03 4.8E-03 4.8E-03 2.9E-04 1.2E-02 9.6E-04 1.9E-04 N-Nitrosomethylethylamine 4.5E-07 5.4E-03 4.5E-03 4.5E-03 2.7E-04 1.2E-02 9.0E-04 1.8E-04 N-Nitrosomorpholine 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 o-Toluidine 3.5E-06 4.2E-02 3.5E-02 3.5E-02 2.1E-03 9.1E-02 7.0E-03 1.4E-03 p-Dimethylaminoazobenzene 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 Pentachlorobenzene 3.0E-07 3.6E-03 3.0E-03 3.0E-03 1.8E-04 7.8E-03 6.0E-04 1.2E-04 Pentachloroethane 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 Pentachloronitrobenzene 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 Pentachlorophenol 1.4E-05 1.7E-01 1.4E-01 1.4E-01 8.4E-03 3.6E-01 2.8E-02 5.6E-03 Phenanthrene 7.0E-07 8.4E-03 7.0E-03 7.0E-03 4.2E-04 1.8E-02 1.4E-03 2.8E-04 Phenol 2.1E-06 2.5E-02 2.1E-02 2.1E-02 1.3E-03 5.5E-02 4.2E-03 8.4E-04 Pyrene 2.9E-07 3.5E-03 2.9E-03 2.9E-03 1.7E-04 7.5E-03 5.8E-04 1.2E-04 Pyridine 4.1E-07 4.9E-03 4.1E-03 4.1E-03 2.5E-04 1.1E-02 8.2E-04 1.6E-04 Dioxins/Furans 2,3,7,8-TCDD 1.3E-12 1.6E-08 1.3E-08 1.3E-08 7.8E-10 3.4E-08 2.6E-09 5.2E-10 1,2,3,7,8-PeCDD 6.7E-12 8.0E-08 6.7E-08 6.7E-08 4.0E-09 1.7E-07 1.3E-08 2.7E-09 1,2,3,4,7,8-HxCDD 3.4E-12 4.1E-08 3.4E-08 3.4E-08 2.0E-09 8.8E-08 6.8E-09 1.4E-09 1,2,3,6,7,8-HxCDD 8.9E-12 1.1E-07 8.9E-08 8.9E-08 5.3E-09 2.3E-07 1.8E-08 3.6E-09 1,2,3,7,8,9-HxCDD 6.1E-12 7.3E-08 6.1E-08 6.1E-08 3.7E-09 1.6E-07 1.2E-08 2.4E-09 1,2,3,4,6,7,8-HpCDD 2.9E-11 3.5E-07 2.9E-07 2.9E-07 1.7E-08 7.5E-07 5.8E-08 1.2E-08 OCDD 3.7E-11 4.4E-07 3.7E-07 3.7E-07 2.2E-08 9.6E-07 7.4E-08 1.5E-08 2,3,7,8-TCDF 4.0E-11 4.8E-07 4.0E-07 4.0E-07 2.4E-08 1.0E-06 8.0E-08 1.6E-08 1,2,3,7,8-PeCDF 8.0E-11 9.6E-07 8.0E-07 8.0E-07 4.8E-08 2.1E-06 1.6E-07 3.2E-08 2,3,4,7,8-PeCDF 1.6E-10 1.9E-06 1.6E-06 1.6E-06 9.6E-08 4.2E-06 3.2E-07 6.4E-08 1,2,3,4,7,8-HxCDF 2.6E-10 3.1E-06 2.6E-06 2.6E-06 1.6E-07 6.8E-06 5.2E-07 1.0E-07 1,2,3,6,7,8-HxCDF 1.6E-10 1.9E-06 1.6E-06 1.6E-06 9.6E-08 4.2E-06 3.2E-07 6.4E-08 2,3,4,6,7,8-HxCDF 1.9E-10 2.3E-06 1.9E-06 1.9E-06 1.1E-07 4.9E-06 3.8E-07 7.6E-08 1,2,3,7,8,9-HxCDF 1.2E-10 1.4E-06 1.2E-06 1.2E-06 7.2E-08 3.1E-06 2.4E-07 4.8E-08 1,2,3,4,6,7,8-HpCDF 7.3E-10 8.8E-06 7.3E-06 7.3E-06 4.4E-07 1.9E-05 1.5E-06 2.9E-07 TABLE OR APPENDIX ??? 1.3 CLASS WASTE MATERIAL PER EVENT (1-HOUR) CORRECTED EMISSION RATES (LBS/HR) ATK PROMONTORY, UTAH PAGE 3 OF 5 1 2 3 4 5 1 2 Analyte Corrected Emission Factor (lbs/lb) M-136 Quantities (lbs/hour)M-225 Quantities (lbs/hr) 1,2,3,4,7,8,9-HpCDF 1.9E-10 2.3E-06 1.9E-06 1.9E-06 1.1E-07 4.9E-06 3.8E-07 7.6E-08 OCDF 5.2E-10 6.2E-06 5.2E-06 5.2E-06 3.1E-07 1.4E-05 1.0E-06 2.1E-07 Carbonyls 2,5-Dimethylbenzaldehyde 1.4E-05 1.7E-01 1.4E-01 1.4E-01 8.4E-03 3.6E-01 2.8E-02 5.6E-03 Acetaldehyde 7.5E-05 9.0E-01 7.5E-01 7.5E-01 4.5E-02 2.0E+00 1.5E-01 3.0E-02 Acetone 1.5E-05 1.8E-01 1.5E-01 1.5E-01 9.0E-03 3.9E-01 3.0E-02 6.0E-03 Benzaldehyde 7.3E-06 8.8E-02 7.3E-02 7.3E-02 4.4E-03 1.9E-01 1.5E-02 2.9E-03 Crotonaldehyde 6.8E-06 8.2E-02 6.8E-02 6.8E-02 4.1E-03 1.8E-01 1.4E-02 2.7E-03 Formaldehyde 4.0E-05 4.8E-01 4.0E-01 4.0E-01 2.4E-02 1.0E+00 8.0E-02 1.6E-02 Hexanal 8.2E-06 9.8E-02 8.2E-02 8.2E-02 4.9E-03 2.1E-01 1.6E-02 3.3E-03 Isopentanal 6.8E-06 8.2E-02 6.8E-02 6.8E-02 4.1E-03 1.8E-01 1.4E-02 2.7E-03 m,p-Tolualdehyde 6.8E-06 8.2E-02 6.8E-02 6.8E-02 4.1E-03 1.8E-01 1.4E-02 2.7E-03 MEK/Butyraldehydes 1.2E-05 1.4E-01 1.2E-01 1.2E-01 7.2E-03 3.1E-01 2.4E-02 4.8E-03 o-Tolualdehyde 2.3E-05 2.8E-01 2.3E-01 2.3E-01 1.4E-02 6.0E-01 4.6E-02 9.2E-03 Pentanal 1.2E-05 1.4E-01 1.2E-01 1.2E-01 7.2E-03 3.1E-01 2.4E-02 4.8E-03 Propanal 3.8E-05 4.6E-01 3.8E-01 3.8E-01 2.3E-02 9.9E-01 7.6E-02 1.5E-02 HCl/Cl2/NH3 HCl 1.8E-02 2.2E+02 1.8E+02 1.8E+02 1.1E+01 4.7E+02 3.6E+01 7.2E+00 Cl2 1.5E-03 1.8E+01 1.5E+01 1.5E+01 9.0E-01 3.9E+01 3.0E+00 6.0E-01 NH3 2.2E-05 2.6E-01 2.2E-01 2.2E-01 1.3E-02 5.7E-01 4.4E-02 8.8E-03 HCN 1.2E-05 1.4E-01 1.2E-01 1.2E-01 7.2E-03 3.1E-01 2.4E-02 4.8E-03 VOCs TNMOC 8.1E-04 9.7E+00 8.1E+00 8.1E+00 4.9E-01 2.1E+01 1.6E+00 3.2E-01 1,1,1-Trichloroethane 4.5E-07 5.4E-03 4.5E-03 4.5E-03 2.7E-04 1.2E-02 9.0E-04 1.8E-04 1,1,2,2-Tetrachloroethane 2.1E-07 2.5E-03 2.1E-03 2.1E-03 1.3E-04 5.5E-03 4.2E-04 8.4E-05 1,1,2-Trichloroethane 3.6E-07 4.3E-03 3.6E-03 3.6E-03 2.2E-04 9.4E-03 7.2E-04 1.4E-04 1,1-Dichloroethane 1.6E-07 1.9E-03 1.6E-03 1.6E-03 9.6E-05 4.2E-03 3.2E-04 6.4E-05 1,1-Dichloroethene 2.2E-07 2.6E-03 2.2E-03 2.2E-03 1.3E-04 5.7E-03 4.4E-04 8.8E-05 1,2,3-Trimethylbenzene 2.1E-07 2.5E-03 2.1E-03 2.1E-03 1.3E-04 5.5E-03 4.2E-04 8.4E-05 1,2,4-Trichlorobenzene 6.3E-07 7.6E-03 6.3E-03 6.3E-03 3.8E-04 1.6E-02 1.3E-03 2.5E-04 1,2,4-Trimethylbenzene 5.2E-06 6.2E-02 5.2E-02 5.2E-02 3.1E-03 1.4E-01 1.0E-02 2.1E-03 1,2-Dibromomethane (EDB)4.4E-07 5.3E-03 4.4E-03 4.4E-03 2.6E-04 1.1E-02 8.8E-04 1.8E-04 1,2-Dichlorobenzene 2.4E-07 2.9E-03 2.4E-03 2.4E-03 1.4E-04 6.2E-03 4.8E-04 9.6E-05 1,2-Dichloroethane 2.7E-07 3.2E-03 2.7E-03 2.7E-03 1.6E-04 7.0E-03 5.4E-04 1.1E-04 1,2-Dichloropropane 1.8E-07 2.2E-03 1.8E-03 1.8E-03 1.1E-04 4.7E-03 3.6E-04 7.2E-05 1,3,5-Trimethylbenzene 2.0E-06 2.4E-02 2.0E-02 2.0E-02 1.2E-03 5.2E-02 4.0E-03 8.0E-04 1,3-Butadiene 2.0E-05 2.4E-01 2.0E-01 2.0E-01 1.2E-02 5.2E-01 4.0E-02 8.0E-03 1,3-Dichlorobenzene 2.2E-07 2.6E-03 2.2E-03 2.2E-03 1.3E-04 5.7E-03 4.4E-04 8.8E-05 1,3-Diethylbenzene 2.5E-07 3.0E-03 2.5E-03 2.5E-03 1.5E-04 6.5E-03 5.0E-04 1.0E-04 1,4-Dichlorobenzene 3.7E-07 4.4E-03 3.7E-03 3.7E-03 2.2E-04 9.6E-03 7.4E-04 1.5E-04 1,4-Diethylbenzene 3.3E-07 4.0E-03 3.3E-03 3.3E-03 2.0E-04 8.6E-03 6.6E-04 1.3E-04 1,4-Dioxane 3.2E-07 3.8E-03 3.2E-03 3.2E-03 1.9E-04 8.3E-03 6.4E-04 1.3E-04 1-Butene 2.1E-05 2.5E-01 2.1E-01 2.1E-01 1.3E-02 5.5E-01 4.2E-02 8.4E-03 1-Hexene 2.0E-05 2.4E-01 2.0E-01 2.0E-01 1.2E-02 5.2E-01 4.0E-02 8.0E-03 1-Pentene 1.2E-05 1.4E-01 1.2E-01 1.2E-01 7.2E-03 3.1E-01 2.4E-02 4.8E-03 2,2,4-Trimethylpentane 2.3E-06 2.8E-02 2.3E-02 2.3E-02 1.4E-03 6.0E-02 4.6E-03 9.2E-04 2,2-Dimethylbutane 4.4E-07 5.3E-03 4.4E-03 4.4E-03 2.6E-04 1.1E-02 8.8E-04 1.8E-04 2,3,4-Trimethylpentane 1.4E-07 1.7E-03 1.4E-03 1.4E-03 8.4E-05 3.6E-03 2.8E-04 5.6E-05 2,3-Dimethylbutane 2.9E-06 3.5E-02 2.9E-02 2.9E-02 1.7E-03 7.5E-02 5.8E-03 1.2E-03 2,3-Dimethylpentane 2.7E-06 3.2E-02 2.7E-02 2.7E-02 1.6E-03 7.0E-02 5.4E-03 1.1E-03 2,4-Dimethylpentane 5.5E-07 6.6E-03 5.5E-03 5.5E-03 3.3E-04 1.4E-02 1.1E-03 2.2E-04 2-Butanone (MEK)3.9E-06 4.7E-02 3.9E-02 3.9E-02 2.3E-03 1.0E-01 7.8E-03 1.6E-03 2-Ethyltoluene 2.2E-07 2.6E-03 2.2E-03 2.2E-03 1.3E-04 5.7E-03 4.4E-04 8.8E-05 2-Hexanone 4.4E-07 5.3E-03 4.4E-03 4.4E-03 2.6E-04 1.1E-02 8.8E-04 1.8E-04 2-Methylheptane 2.7E-06 3.2E-02 2.7E-02 2.7E-02 1.6E-03 7.0E-02 5.4E-03 1.1E-03 2-Methylhexane 4.4E-06 5.3E-02 4.4E-02 4.4E-02 2.6E-03 1.1E-01 8.8E-03 1.8E-03 2-Methylpentane 5.3E-06 6.4E-02 5.3E-02 5.3E-02 3.2E-03 1.4E-01 1.1E-02 2.1E-03 2-Nitropropane 2.8E-06 3.4E-02 2.8E-02 2.8E-02 1.7E-03 7.3E-02 5.6E-03 1.1E-03 2-Propanol 1.5E-07 1.8E-03 1.5E-03 1.5E-03 9.0E-05 3.9E-03 3.0E-04 6.0E-05 3-Chloropropene 4.7E-06 5.6E-02 4.7E-02 4.7E-02 2.8E-03 1.2E-01 9.4E-03 1.9E-03 3-Ethyltoluene 4.8E-06 5.8E-02 4.8E-02 4.8E-02 2.9E-03 1.2E-01 9.6E-03 1.9E-03 3-Methylheptane 3.5E-06 4.2E-02 3.5E-02 3.5E-02 2.1E-03 9.1E-02 7.0E-03 1.4E-03 3-Methylhexane 5.2E-06 6.2E-02 5.2E-02 5.2E-02 3.1E-03 1.4E-01 1.0E-02 2.1E-03 3-Methylpentane 7.1E-06 8.5E-02 7.1E-02 7.1E-02 4.3E-03 1.8E-01 1.4E-02 2.8E-03 4-Ethyltoluene 5.3E-06 6.4E-02 5.3E-02 5.3E-02 3.2E-03 1.4E-01 1.1E-02 2.1E-03 4-Methyl-2-pentanone 3.5E-07 4.2E-03 3.5E-03 3.5E-03 2.1E-04 9.1E-03 7.0E-04 1.4E-04 Acetone 2.3E-05 2.8E-01 2.3E-01 2.3E-01 1.4E-02 6.0E-01 4.6E-02 9.2E-03 TABLE OR APPENDIX ??? 1.3 CLASS WASTE MATERIAL PER EVENT (1-HOUR) CORRECTED EMISSION RATES (LBS/HR) ATK PROMONTORY, UTAH PAGE 4 OF 5 1 2 3 4 5 1 2 Analyte Corrected Emission Factor (lbs/lb) M-136 Quantities (lbs/hour)M-225 Quantities (lbs/hr) Acetonitrile 9.2E-06 1.1E-01 9.2E-02 9.2E-02 5.5E-03 2.4E-01 1.8E-02 3.7E-03 Acetylene 7.4E-05 8.9E-01 7.4E-01 7.4E-01 4.4E-02 1.9E+00 1.5E-01 3.0E-02 Acrylonitrile 1.0E-05 1.2E-01 1.0E-01 1.0E-01 6.0E-03 2.6E-01 2.0E-02 4.0E-03 alpha-Chlorotoluene 2.8E-07 3.4E-03 2.8E-03 2.8E-03 1.7E-04 7.3E-03 5.6E-04 1.1E-04 Benzene 4.4E-05 5.3E-01 4.4E-01 4.4E-01 2.6E-02 1.1E+00 8.8E-02 1.8E-02 Bromodichloromethane 3.9E-07 4.7E-03 3.9E-03 3.9E-03 2.3E-04 1.0E-02 7.8E-04 1.6E-04 Bromoform 6.3E-07 7.6E-03 6.3E-03 6.3E-03 3.8E-04 1.6E-02 1.3E-03 2.5E-04 Bromomethane 3.1E-07 3.7E-03 3.1E-03 3.1E-03 1.9E-04 8.1E-03 6.2E-04 1.2E-04 Butane 1.8E-05 2.2E-01 1.8E-01 1.8E-01 1.1E-02 4.7E-01 3.6E-02 7.2E-03 Carbon Disulfide 9.4E-06 1.1E-01 9.4E-02 9.4E-02 5.6E-03 2.4E-01 1.9E-02 3.8E-03 Carbon Tetrachloride 1.5E-05 1.8E-01 1.5E-01 1.5E-01 9.0E-03 3.9E-01 3.0E-02 6.0E-03 Chloroacetonitrile 5.6E-07 6.7E-03 5.6E-03 5.6E-03 3.4E-04 1.5E-02 1.1E-03 2.2E-04 Chlorobenzene 2.5E-06 3.0E-02 2.5E-02 2.5E-02 1.5E-03 6.5E-02 5.0E-03 1.0E-03 Chloroethane 1.3E-07 1.6E-03 1.3E-03 1.3E-03 7.8E-05 3.4E-03 2.6E-04 5.2E-05 Chloroform 6.1E-06 7.3E-02 6.1E-02 6.1E-02 3.7E-03 1.6E-01 1.2E-02 2.4E-03 Chloromethane 1.4E-05 1.7E-01 1.4E-01 1.4E-01 8.4E-03 3.6E-01 2.8E-02 5.6E-03 cis-1,2-Dichloroethene 2.3E-07 2.8E-03 2.3E-03 2.3E-03 1.4E-04 6.0E-03 4.6E-04 9.2E-05 cis-1,3-Dichloropropene 1.3E-06 1.6E-02 1.3E-02 1.3E-02 7.8E-04 3.4E-02 2.6E-03 5.2E-04 cis-2-Butene 1.4E-06 1.7E-02 1.4E-02 1.4E-02 8.4E-04 3.6E-02 2.8E-03 5.6E-04 cis-2-Pentene 1.7E-07 2.0E-03 1.7E-03 1.7E-03 1.0E-04 4.4E-03 3.4E-04 6.8E-05 Cumene 2.1E-07 2.5E-03 2.1E-03 2.1E-03 1.3E-04 5.5E-03 4.2E-04 8.4E-05 Cyclohexane 2.5E-06 3.0E-02 2.5E-02 2.5E-02 1.5E-03 6.5E-02 5.0E-03 1.0E-03 Cyclopentane 1.8E-06 2.2E-02 1.8E-02 1.8E-02 1.1E-03 4.7E-02 3.6E-03 7.2E-04 Decane 1.7E-05 2.0E-01 1.7E-01 1.7E-01 1.0E-02 4.4E-01 3.4E-02 6.8E-03 Dibromochloromethane 4.4E-07 5.3E-03 4.4E-03 4.4E-03 2.6E-04 1.1E-02 8.8E-04 1.8E-04 Ethane 1.7E-05 2.0E-01 1.7E-01 1.7E-01 1.0E-02 4.4E-01 3.4E-02 6.8E-03 Ethanol 1.6E-06 1.9E-02 1.6E-02 1.6E-02 9.6E-04 4.2E-02 3.2E-03 6.4E-04 Ethene 1.5E-04 1.8E+00 1.5E+00 1.5E+00 9.0E-02 3.9E+00 3.0E-01 6.0E-02 Ethyl benzene 2.8E-06 3.4E-02 2.8E-02 2.8E-02 1.7E-03 7.3E-02 5.6E-03 1.1E-03 Ethyl ether 1.2E-06 1.4E-02 1.2E-02 1.2E-02 7.2E-04 3.1E-02 2.4E-03 4.8E-04 Ethyl Methacrylate 7.8E-07 9.4E-03 7.8E-03 7.8E-03 4.7E-04 2.0E-02 1.6E-03 3.1E-04 Heptane 7.2E-06 8.6E-02 7.2E-02 7.2E-02 4.3E-03 1.9E-01 1.4E-02 2.9E-03 Hexachlorobutadiene 8.5E-07 1.0E-02 8.5E-03 8.5E-03 5.1E-04 2.2E-02 1.7E-03 3.4E-04 Hexane 9.8E-06 1.2E-01 9.8E-02 9.8E-02 5.9E-03 2.5E-01 2.0E-02 3.9E-03 Isobutane 2.8E-06 3.4E-02 2.8E-02 2.8E-02 1.7E-03 7.3E-02 5.6E-03 1.1E-03 Isopentane 2.0E-05 2.4E-01 2.0E-01 2.0E-01 1.2E-02 5.2E-01 4.0E-02 8.0E-03 m,p-Xylene 1.0E-05 1.2E-01 1.0E-01 1.0E-01 6.0E-03 2.6E-01 2.0E-02 4.0E-03 Methacrylonitrile 4.9E-06 5.9E-02 4.9E-02 4.9E-02 2.9E-03 1.3E-01 9.8E-03 2.0E-03 Methyl Acrylate 5.9E-07 7.1E-03 5.9E-03 5.9E-03 3.5E-04 1.5E-02 1.2E-03 2.4E-04 Methyl Methacrylate 8.1E-07 9.7E-03 8.1E-03 8.1E-03 4.9E-04 2.1E-02 1.6E-03 3.2E-04 Methyl tert-butyl ether 2.1E-07 2.5E-03 2.1E-03 2.1E-03 1.3E-04 5.5E-03 4.2E-04 8.4E-05 Methylcyclohexane 6.1E-06 7.3E-02 6.1E-02 6.1E-02 3.7E-03 1.6E-01 1.2E-02 2.4E-03 Methylcyclopentane 5.6E-06 6.7E-02 5.6E-02 5.6E-02 3.4E-03 1.5E-01 1.1E-02 2.2E-03 Methylene chloride 7.1E-06 8.5E-02 7.1E-02 7.1E-02 4.3E-03 1.8E-01 1.4E-02 2.8E-03 n-Butylchloride 5.8E-06 7.0E-02 5.8E-02 5.8E-02 3.5E-03 1.5E-01 1.2E-02 2.3E-03 Nonane 1.3E-05 1.6E-01 1.3E-01 1.3E-01 7.8E-03 3.4E-01 2.6E-02 5.2E-03 Octane 7.5E-06 9.0E-02 7.5E-02 7.5E-02 4.5E-03 2.0E-01 1.5E-02 3.0E-03 o-Xylene 3.5E-06 4.2E-02 3.5E-02 3.5E-02 2.1E-03 9.1E-02 7.0E-03 1.4E-03 Pentane 1.9E-05 2.3E-01 1.9E-01 1.9E-01 1.1E-02 4.9E-01 3.8E-02 7.6E-03 Propane 8.7E-06 1.0E-01 8.7E-02 8.7E-02 5.2E-03 2.3E-01 1.7E-02 3.5E-03 Propylbenzene 1.0E-06 1.2E-02 1.0E-02 1.0E-02 6.0E-04 2.6E-02 2.0E-03 4.0E-04 Propylene 4.3E-05 5.2E-01 4.3E-01 4.3E-01 2.6E-02 1.1E+00 8.6E-02 1.7E-02 Styrene 9.9E-07 1.2E-02 9.9E-03 9.9E-03 5.9E-04 2.6E-02 2.0E-03 4.0E-04 Tetrachloroethene 2.5E-06 3.0E-02 2.5E-02 2.5E-02 1.5E-03 6.5E-02 5.0E-03 1.0E-03 Tetrahydrofuran 6.4E-07 7.7E-03 6.4E-03 6.4E-03 3.8E-04 1.7E-02 1.3E-03 2.6E-04 Toluene 1.8E-05 2.2E-01 1.8E-01 1.8E-01 1.1E-02 4.7E-01 3.6E-02 7.2E-03 trans-1,2-Dichloroethene 3.6E-07 4.3E-03 3.6E-03 3.6E-03 2.2E-04 9.4E-03 7.2E-04 1.4E-04 trans-1,3-Dichloropropene 3.0E-07 3.6E-03 3.0E-03 3.0E-03 1.8E-04 7.8E-03 6.0E-04 1.2E-04 trans-2-butene 7.7E-06 9.2E-02 7.7E-02 7.7E-02 4.6E-03 2.0E-01 1.5E-02 3.1E-03 trans-2-Pentene 1.7E-06 2.0E-02 1.7E-02 1.7E-02 1.0E-03 4.4E-02 3.4E-03 6.8E-04 Trichloroethene 9.4E-07 1.1E-02 9.4E-03 9.4E-03 5.6E-04 2.4E-02 1.9E-03 3.8E-04 Undecane 1.2E-05 1.4E-01 1.2E-01 1.2E-01 7.2E-03 3.1E-01 2.4E-02 4.8E-03 Vinyl chloride 7.6E-06 9.1E-02 7.6E-02 7.6E-02 4.6E-03 2.0E-01 1.5E-02 3.0E-03 CEM CO2 6.9E-01 8.3E+03 6.9E+03 6.9E+03 4.1E+02 1.8E+04 1.4E+03 2.8E+02 CO 4.7E-03 5.6E+01 4.7E+01 4.7E+01 2.8E+00 1.2E+02 9.4E+00 1.9E+00 NOX 5.8E-03 7.0E+01 5.8E+01 5.8E+01 3.5E+00 1.5E+02 1.2E+01 2.3E+00 SO2 4.1E-04 4.9E+00 4.1E+00 4.1E+00 2.5E-01 1.1E+01 8.2E-01 1.6E-01 Highlighted analytes were not detected during the Bang Box testing program TABLE OR APPENDIX ??? 1.3 CLASS WASTE MATERIAL PER EVENT (1-HOUR) CORRECTED EMISSION RATES (LBS/HR) ATK PROMONTORY, UTAH PAGE 5 OF 5 1 2 3 4 5 1 2 Analyte Corrected Emission Factor (lbs/lb) M-136 Quantities (lbs/hour)M-225 Quantities (lbs/hr) CEM - Continuous Emissions Monitoring CL2 - chlorine CO - carbon monoxide CO2 - carbon dioxide HCL - hydrogen chloride HCN - hydrogen cyanide NH3 - ammonia NOX - nitrogen oxide OCDD - 1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin OCDF - 1,2,3,4,6,7,8,9-Octachlorodibenzo-p-furan PM10 - particulate matter less than 10 microns in aerodynamic diameter PM2.5 - particulate matter less than 2.5 microns in aerodynamic diameter SO2 - sulfur dioxide SVOCs - semi-volatile organic compounds TNMOC - total non-methane organic carbon TSP - Total suspended particulates VOCs - volatile organic compounds TABLE OR APPENDIX 3-??? 1.3 CLASS WASTE MATERIAL CORRECTED ANNUAL EMISSION RATES (LBS/YR) ATK PROMONTORY, UTAH PAGE 1 OF 5 1 2 3 4 5 1 2 Particulates TSP 1.4E-01 5.2E+05 7.3E+04 7.3E+04 5.0E+02 1.1E+04 6.7E+03 3.4E+02 PM10 8.6E-02 3.2E+05 4.5E+04 4.5E+04 3.1E+02 6.7E+03 4.1E+03 2.1E+02 PM2.5 5.9E-02 2.2E+05 3.1E+04 3.1E+04 2.1E+02 4.6E+03 2.8E+03 1.4E+02 Metals Aluminum 4.0E-02 1.5E+05 2.1E+04 2.1E+04 1.4E+02 3.1E+03 1.9E+03 9.6E+01 Antimony 2.9E-05 1.1E+02 1.5E+01 1.5E+01 1.0E-01 2.3E+00 1.4E+00 7.0E-02 Arsenic 3.0E-07 1.1E+00 1.6E-01 1.6E-01 1.1E-03 2.3E-02 1.4E-02 7.2E-04 Barium 4.9E-06 1.8E+01 2.5E+00 2.5E+00 1.8E-02 3.8E-01 2.4E-01 1.2E-02 Cadmium 3.1E-07 1.2E+00 1.6E-01 1.6E-01 1.1E-03 2.4E-02 1.5E-02 7.4E-04 Chromium 2.0E-05 7.5E+01 1.0E+01 1.0E+01 7.2E-02 1.6E+00 9.6E-01 4.8E-02 Cobalt 3.1E-07 1.2E+00 1.6E-01 1.6E-01 1.1E-03 2.4E-02 1.5E-02 7.4E-04 Copper 2.5E-05 9.4E+01 1.3E+01 1.3E+01 9.0E-02 2.0E+00 1.2E+00 6.0E-02 Lead 3.4E-05 1.3E+02 1.8E+01 1.8E+01 1.2E-01 2.7E+00 1.6E+00 8.2E-02 Magnesium 2.9E-05 1.1E+02 1.5E+01 1.5E+01 1.0E-01 2.3E+00 1.4E+00 7.0E-02 Manganese 9.3E-05 3.5E+02 4.8E+01 4.8E+01 3.3E-01 7.3E+00 4.5E+00 2.2E-01 Mercury 3.7E-08 1.4E-01 1.9E-02 1.9E-02 1.3E-04 2.9E-03 1.8E-03 8.9E-05 Nickel 5.8E-05 2.2E+02 3.0E+01 3.0E+01 2.1E-01 4.5E+00 2.8E+00 1.4E-01 Phosphorus 1.0E-04 3.7E+02 5.2E+01 5.2E+01 3.6E-01 7.8E+00 4.8E+00 2.4E-01 Selenium 1.7E-06 6.4E+00 8.8E-01 8.8E-01 6.1E-03 1.3E-01 8.2E-02 4.1E-03 Silver 9.5E-07 3.6E+00 4.9E-01 4.9E-01 3.4E-03 7.4E-02 4.6E-02 2.3E-03 Thallium 2.1E-06 7.9E+00 1.1E+00 1.1E+00 7.6E-03 1.6E-01 1.0E-01 5.0E-03 Zinc 3.5E-05 1.3E+02 1.8E+01 1.8E+01 1.3E-01 2.7E+00 1.7E+00 8.4E-02 Perchlorate 2.5E-07 2.7E-02 1.3E-01 1.3E-01 9.0E-04 2.0E-02 1.2E-02 6.0E-04 SVOCs 1,2,4,5-Tetrachlorobenzene 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 6.5E-04 1,2,4-Trichlorobenzene 3.2E-07 1.2E+00 1.7E-01 1.7E-01 1.2E-03 2.5E-02 1.5E-02 1.3E-04 1,2-Dichlorobenzene 2.8E-07 1.0E+00 1.5E-01 1.5E-01 1.0E-03 2.2E-02 1.3E-02 1.1E-04 1,3,5-Trinitrobenzene 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 1,3-Dichlorobenzene 3.1E-07 1.2E+00 1.6E-01 1.6E-01 1.1E-03 2.4E-02 1.5E-02 1.2E-04 1,3-Dinitrobenzene 2.8E-07 1.0E+00 1.5E-01 1.5E-01 1.0E-03 2.2E-02 1.3E-02 1.1E-04 1,4-Dichlorobenzene 2.9E-07 1.1E+00 1.5E-01 1.5E-01 1.0E-03 2.3E-02 1.4E-02 1.2E-04 1-Chloronaphthalene 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 1-Naphthylamine 5.5E-06 2.1E+01 2.9E+00 2.9E+00 2.0E-02 4.3E-01 2.6E-01 2.2E-03 2,3,4,6-Tetrachlorophenol 3.6E-07 1.3E+00 1.9E-01 1.9E-01 1.3E-03 2.8E-02 1.7E-02 1.4E-04 2,4,5-Trichlorophenol 7.1E-07 2.7E+00 3.7E-01 3.7E-01 2.6E-03 5.5E-02 3.4E-02 2.8E-04 2,4,6-Trichlorophenol 1.30E-06 4.9E+00 6.8E-01 6.8E-01 4.7E-03 1.0E-01 6.2E-02 5.2E-04 2,4-Dichlorophenol 9.3E-07 3.5E+00 4.8E-01 4.8E-01 3.3E-03 7.3E-02 4.5E-02 3.7E-04 2,4-Dimethylphenol 3.5E-06 1.3E+01 1.8E+00 1.8E+00 1.3E-02 2.7E-01 1.7E-01 1.4E-03 2,4-Dinitrophenol 1.2E-05 4.5E+01 6.2E+00 6.2E+00 4.3E-02 9.4E-01 5.8E-01 4.8E-03 2,4-Dinitrotoluene 3.1E-07 1.2E+00 1.6E-01 1.6E-01 1.1E-03 2.4E-02 1.5E-02 1.2E-04 2,6-Dichlorophenol 4.0E-07 1.5E+00 2.1E-01 2.1E-01 1.4E-03 3.1E-02 1.9E-02 1.6E-04 2,6-Dinitrotoluene 5.6E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.4E-02 2.7E-02 2.2E-04 2-Acetylaminofluorene 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 2-Chloronaphthalene 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 2-Chlorophenol 1.9E-06 7.1E+00 9.9E-01 9.9E-01 6.8E-03 1.5E-01 9.1E-02 7.6E-04 2-Methylnaphthalene 3.6E-06 1.3E+01 1.9E+00 1.9E+00 1.3E-02 2.8E-01 1.7E-01 1.4E-03 2-Methylphenol 1.6E-06 6.0E+00 8.3E-01 8.3E-01 5.8E-03 1.2E-01 7.7E-02 6.4E-04 2-Naphthylamine 5.5E-06 2.1E+01 2.9E+00 2.9E+00 2.0E-02 4.3E-01 2.6E-01 2.2E-03 2-Nitroaniline 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 2-Nitrophenol 3.9E-07 1.5E+00 2.0E-01 2.0E-01 1.4E-03 3.0E-02 1.9E-02 1.6E-04 3,3'-Dichlorobenzidine 4.1E-06 1.5E+01 2.1E+00 2.1E+00 1.5E-02 3.2E-01 2.0E-01 1.6E-03 3,3'-Dimethylbenzidine 2.7E-05 1.0E+02 1.4E+01 1.4E+01 9.7E-02 2.1E+00 1.3E+00 1.1E-02 3-Methylcholanthrene 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 3-Methylphenol & 4-Methylphenol 1.1E-06 4.1E+00 5.7E-01 5.7E-01 4.0E-03 8.6E-02 5.3E-02 4.4E-04 3-Nitroaniline 1.1E-06 4.1E+00 5.7E-01 5.7E-01 4.0E-03 8.6E-02 5.3E-02 4.4E-04 4,6-Dinitro-2-methylphenol 4.8E-06 1.8E+01 2.5E+00 2.5E+00 1.7E-02 3.7E-01 2.3E-01 1.9E-03 4-Aminobiphenyl 5.5E-06 2.1E+01 2.9E+00 2.9E+00 2.0E-02 4.3E-01 2.6E-01 2.2E-03 4-Bromophenyl phenyl ether 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 4-Chloro-3-methylphenol 3.4E-07 1.3E+00 1.8E-01 1.8E-01 1.2E-03 2.7E-02 1.6E-02 1.4E-04 4-Chloroaniline 3.3E-06 1.2E+01 1.7E+00 1.7E+00 1.2E-02 2.6E-01 1.6E-01 1.3E-03 4-Nitroaniline 1.1E-06 4.1E+00 5.7E-01 5.7E-01 4.0E-03 8.6E-02 5.3E-02 4.4E-04 4-Nitrophenol 1.8E-06 6.7E+00 9.4E-01 9.4E-01 6.5E-03 1.4E-01 8.6E-02 7.2E-04 7,12-Dimethylbenz(a)anthracene 2.8E-07 1.0E+00 1.5E-01 1.5E-01 1.0E-03 2.2E-02 1.3E-02 1.1E-04 Acenaphthene 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 Acenaphthylene 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 Acetophenone 2.7E-06 1.0E+01 1.4E+00 1.4E+00 9.7E-03 2.1E-01 1.3E-01 1.1E-03 Aniline 4.0E-06 1.5E+01 2.1E+00 2.1E+00 1.4E-02 3.1E-01 1.9E-01 1.6E-03 Analyte Corrected Emission Factor (lbs/lb) M-136 Quantities (lbs/year)M-225 Quantities (lbs/year) TABLE OR APPENDIX 3-??? 1.3 CLASS WASTE MATERIAL CORRECTED ANNUAL EMISSION RATES (LBS/YR) ATK PROMONTORY, UTAH PAGE 2 OF 5 1 2 3 4 5 1 2 Analyte Corrected Emission Factor (lbs/lb) M-136 Quantities (lbs/year)M-225 Quantities (lbs/year) Anthracene 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 Benzidine 2.8E-05 1.0E+02 1.5E+01 1.5E+01 1.0E-01 2.2E+00 1.3E+00 1.1E-02 Benzo(a)anthracene 3.2E-07 1.2E+00 1.7E-01 1.7E-01 1.2E-03 2.5E-02 1.5E-02 1.3E-04 Benzo(a)pyrene 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 Benzo(b)fluoranthene 6.0E-07 2.2E+00 3.1E-01 3.1E-01 2.2E-03 4.7E-02 2.9E-02 2.4E-04 Benzo(ghi)perylene 3.4E-07 1.3E+00 1.8E-01 1.8E-01 1.2E-03 2.7E-02 1.6E-02 1.4E-04 Benzo(k)fluoranthene 8.8E-07 3.3E+00 4.6E-01 4.6E-01 3.2E-03 6.9E-02 4.2E-02 3.5E-04 Benzoic acid 6.2E-05 2.3E+02 3.2E+01 3.2E+01 2.2E-01 4.8E+00 3.0E+00 2.5E-02 Benzyl alcohol 1.9E-05 7.1E+01 9.9E+00 9.9E+00 6.8E-02 1.5E+00 9.1E-01 7.6E-03 bis(2-Chloroethoxy)methane 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 bis(2-Chloroethyl) ether 3.1E-07 1.2E+00 1.6E-01 1.6E-01 1.1E-03 2.4E-02 1.5E-02 1.2E-04 bis(2-Chloroisopropyl) ether 4.2E-07 1.6E+00 2.2E-01 2.2E-01 1.5E-03 3.3E-02 2.0E-02 1.7E-04 bis(2-Ethylhexyl) phthalate 5.5E-06 2.1E+01 2.9E+00 2.9E+00 2.0E-02 4.3E-01 2.6E-01 2.2E-03 Butyl benzyl phthalate 3.3E-07 1.2E+00 1.7E-01 1.7E-01 1.2E-03 2.6E-02 1.6E-02 1.3E-04 Carbazole 3.5E-07 1.3E+00 1.8E-01 1.8E-01 1.3E-03 2.7E-02 1.7E-02 1.4E-04 Chrysene 3.5E-07 1.3E+00 1.8E-01 1.8E-01 1.3E-03 2.7E-02 1.7E-02 1.4E-04 Dibenz(a,h)anthracene 3.3E-07 1.2E+00 1.7E-01 1.7E-01 1.2E-03 2.6E-02 1.6E-02 1.3E-04 Dibenzofuran 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 Diethyl phthalate 4.0E-07 1.5E+00 2.1E-01 2.1E-01 1.4E-03 3.1E-02 1.9E-02 1.6E-04 Dimethyl phthalate 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 Di-n-butyl phthalate 5.5E-06 2.1E+01 2.9E+00 2.9E+00 2.0E-02 4.3E-01 2.6E-01 2.2E-03 Di-n-octyl phthalate 3.7E-06 1.4E+01 1.9E+00 1.9E+00 1.3E-02 2.9E-01 1.8E-01 1.5E-03 Diphenylamine 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 Ethyl methanesulfonate 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 Fluoranthene 4.0E-07 1.5E+00 2.1E-01 2.1E-01 1.4E-03 3.1E-02 1.9E-02 1.6E-04 Fluorene 4.2E-07 1.6E+00 2.2E-01 2.2E-01 1.5E-03 3.3E-02 2.0E-02 1.7E-04 Hexachlorobenzene 4.7E-06 1.8E+01 2.4E+00 2.4E+00 1.7E-02 3.7E-01 2.3E-01 1.9E-03 Hexachlorobutadiene 4.1E-07 1.5E+00 2.1E-01 2.1E-01 1.5E-03 3.2E-02 2.0E-02 1.6E-04 Hexachlorocyclopentadiene 5.5E-06 2.1E+01 2.9E+00 2.9E+00 2.0E-02 4.3E-01 2.6E-01 2.2E-03 Hexachloroethane 3.0E-07 1.1E+00 1.6E-01 1.6E-01 1.1E-03 2.3E-02 1.4E-02 1.2E-04 Hexachloropropene 3.9E-07 1.5E+00 2.0E-01 2.0E-01 1.4E-03 3.0E-02 1.9E-02 1.6E-04 Indeno(1,2,3-cd)pyrene 3.0E-07 1.1E+00 1.6E-01 1.6E-01 1.1E-03 2.3E-02 1.4E-02 1.2E-04 Isophorone 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 Methyl methanesulfonate 3.0E-07 1.1E+00 1.6E-01 1.6E-01 1.1E-03 2.3E-02 1.4E-02 1.2E-04 Naphthalene 1.3E-05 4.9E+01 6.8E+00 6.8E+00 4.7E-02 1.0E+00 6.2E-01 5.2E-03 Nitrobenzene 3.1E-07 1.2E+00 1.6E-01 1.6E-01 1.1E-03 2.4E-02 1.5E-02 1.2E-04 N-Nitro-o-toluidine 4.4E-06 1.6E+01 2.3E+00 2.3E+00 1.6E-02 3.4E-01 2.1E-01 1.8E-03 N-Nitrosodiethylamine 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 N-Nitrosodimethylamine 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 N-Nitrosodi-n-butylamine 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 N-Nitrosodi-n-propylamine 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 N-Nitrosodiphenylamine 4.8E-07 1.8E+00 2.5E-01 2.5E-01 1.7E-03 3.7E-02 2.3E-02 1.9E-04 N-Nitrosomethylethylamine 4.5E-07 1.7E+00 2.3E-01 2.3E-01 1.6E-03 3.5E-02 2.2E-02 1.8E-04 N-Nitrosomorpholine 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 o-Toluidine 3.5E-06 1.3E+01 1.8E+00 1.8E+00 1.3E-02 2.7E-01 1.7E-01 1.4E-03 p-Dimethylaminoazobenzene 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 Pentachlorobenzene 3.0E-07 1.1E+00 1.6E-01 1.6E-01 1.1E-03 2.3E-02 1.4E-02 1.2E-04 Pentachloroethane 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 Pentachloronitrobenzene 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 1.1E-04 Pentachlorophenol 1.4E-05 5.2E+01 7.3E+00 7.3E+00 5.0E-02 1.1E+00 6.7E-01 5.6E-03 Phenanthrene 7.0E-07 2.6E+00 3.6E-01 3.6E-01 2.5E-03 5.5E-02 3.4E-02 2.8E-04 Phenol 2.1E-06 7.9E+00 1.1E+00 1.1E+00 7.6E-03 1.6E-01 1.0E-01 8.4E-04 Pyrene 2.9E-07 1.1E+00 1.5E-01 1.5E-01 1.0E-03 2.3E-02 1.4E-02 1.2E-04 Pyridine 4.1E-07 1.5E+00 2.1E-01 2.1E-01 1.5E-03 3.2E-02 2.0E-02 1.6E-04 Dioxins/Furans 2,3,7,8-TCDD 1.3E-12 4.9E-06 6.8E-07 6.8E-07 4.7E-09 1.0E-07 6.2E-08 3.1E-09 1,2,3,7,8-PeCDD 6.7E-12 2.5E-05 3.5E-06 3.5E-06 2.4E-08 5.2E-07 3.2E-07 1.6E-08 1,2,3,4,7,8-HxCDD 3.4E-12 1.3E-05 1.8E-06 1.8E-06 1.2E-08 2.7E-07 1.6E-07 8.2E-09 1,2,3,6,7,8-HxCDD 8.9E-12 3.3E-05 4.6E-06 4.6E-06 3.2E-08 6.9E-07 4.3E-07 2.1E-08 1,2,3,7,8,9-HxCDD 6.1E-12 2.3E-05 3.2E-06 3.2E-06 2.2E-08 4.8E-07 2.9E-07 1.5E-08 1,2,3,4,6,7,8-HpCDD 2.9E-11 1.1E-04 1.5E-05 1.5E-05 1.0E-07 2.3E-06 1.4E-06 7.0E-08 OCDD 3.7E-11 1.4E-04 1.9E-05 1.9E-05 1.3E-07 2.9E-06 1.8E-06 8.9E-08 2,3,7,8-TCDF 4.0E-11 1.5E-04 2.1E-05 2.1E-05 1.4E-07 3.1E-06 1.9E-06 9.6E-08 1,2,3,7,8-PeCDF 8.0E-11 3.0E-04 4.2E-05 4.2E-05 2.9E-07 6.2E-06 3.8E-06 1.9E-07 2,3,4,7,8-PeCDF 1.6E-10 6.0E-04 8.3E-05 8.3E-05 5.8E-07 1.2E-05 7.7E-06 3.8E-07 1,2,3,4,7,8-HxCDF 2.6E-10 9.7E-04 1.4E-04 1.4E-04 9.4E-07 2.0E-05 1.2E-05 6.2E-07 1,2,3,6,7,8-HxCDF 1.6E-10 6.0E-04 8.3E-05 8.3E-05 5.8E-07 1.2E-05 7.7E-06 3.8E-07 2,3,4,6,7,8-HxCDF 1.9E-10 7.1E-04 9.9E-05 9.9E-05 6.8E-07 1.5E-05 9.1E-06 4.6E-07 1,2,3,7,8,9-HxCDF 1.2E-10 4.5E-04 6.2E-05 6.2E-05 4.3E-07 9.4E-06 5.8E-06 2.9E-07 1,2,3,4,6,7,8-HpCDF 7.3E-10 2.7E-03 3.8E-04 3.8E-04 2.6E-06 5.7E-05 3.5E-05 1.8E-06 TABLE OR APPENDIX 3-??? 1.3 CLASS WASTE MATERIAL CORRECTED ANNUAL EMISSION RATES (LBS/YR) ATK PROMONTORY, UTAH PAGE 3 OF 5 1 2 3 4 5 1 2 Analyte Corrected Emission Factor (lbs/lb) M-136 Quantities (lbs/year)M-225 Quantities (lbs/year) 1,2,3,4,7,8,9-HpCDF 1.9E-10 7.1E-04 9.9E-05 9.9E-05 6.8E-07 1.5E-05 9.1E-06 4.6E-07 OCDF 5.2E-10 1.9E-03 2.7E-04 2.7E-04 1.9E-06 4.1E-05 1.0E-06 1.2E-06 Carbonyls 2,5-Dimethylbenzaldehyde 1.4E-05 5.2E+01 7.3E+00 7.3E+00 5.0E-02 1.1E+00 6.7E-01 3.4E-02 Acetaldehyde 7.5E-05 2.8E+02 3.9E+01 3.9E+01 2.7E-01 5.9E+00 3.6E+00 1.8E-01 Acetone 1.5E-05 5.6E+01 7.8E+00 7.8E+00 5.4E-02 1.2E+00 7.2E-01 3.6E-02 Benzaldehyde 7.3E-06 2.7E+01 3.8E+00 3.8E+00 2.6E-02 5.7E-01 3.5E-01 1.8E-02 Crotonaldehyde 6.8E-06 2.5E+01 3.5E+00 3.5E+00 2.4E-02 5.3E-01 3.3E-01 1.6E-02 Formaldehyde 4.0E-05 1.5E+02 2.1E+01 2.1E+01 1.4E-01 3.1E+00 1.9E+00 9.6E-02 Hexanal 8.2E-06 3.1E+01 4.3E+00 4.3E+00 3.0E-02 6.4E-01 3.9E-01 2.0E-02 Isopentanal 6.8E-06 2.5E+01 3.5E+00 3.5E+00 2.4E-02 5.3E-01 3.3E-01 1.6E-02 m,p-Tolualdehyde 6.8E-06 2.5E+01 3.5E+00 3.5E+00 2.4E-02 5.3E-01 3.3E-01 1.6E-02 MEK/Butyraldehydes 1.2E-05 4.5E+01 6.2E+00 6.2E+00 4.3E-02 9.4E-01 5.8E-01 2.9E-02 o-Tolualdehyde 2.3E-05 8.6E+01 1.2E+01 1.2E+01 8.3E-02 1.8E+00 1.1E+00 5.5E-02 Pentanal 1.2E-05 4.5E+01 6.2E+00 6.2E+00 4.3E-02 9.4E-01 5.8E-01 2.9E-02 Propanal 3.8E-05 1.4E+02 2.0E+01 2.0E+01 1.4E-01 3.0E+00 1.8E+00 9.1E-02 HCl/Cl2/NH3 HCl 1.8E-02 6.7E+04 9.4E+03 9.4E+03 6.5E+01 1.4E+03 8.6E+02 4.3E+01 Cl2 1.5E-03 5.6E+03 7.8E+02 7.8E+02 5.4E+00 1.2E+02 7.2E+01 3.6E+00 NH3 2.2E-05 8.2E+01 1.1E+01 1.1E+01 7.9E-02 1.7E+00 1.1E+00 5.3E-02 HCN 1.2E-05 4.5E+01 6.2E+00 #REF!4.3E-02 9.4E-01 5.8E-01 2.9E-02 VOCs TNMOC 8.1E-04 3.0E+03 4.2E+02 4.2E+02 2.9E+00 6.3E+01 3.9E+01 1.9E+00 1,1,1-Trichloroethane 4.5E-07 1.7E+00 2.3E-01 2.3E-01 1.6E-03 3.5E-02 2.2E-02 1.1E-03 1,1,2,2-Tetrachloroethane 2.1E-07 7.9E-01 1.1E-01 1.1E-01 7.6E-04 1.6E-02 1.0E-02 5.0E-04 1,1,2-Trichloroethane 3.6E-07 1.3E+00 1.9E-01 1.9E-01 1.3E-03 2.8E-02 1.7E-02 8.6E-04 1,1-Dichloroethane 1.6E-07 6.0E-01 8.3E-02 8.3E-02 5.8E-04 1.2E-02 7.7E-03 3.8E-04 1,1-Dichloroethene 2.2E-07 8.2E-01 1.1E-01 1.1E-01 7.9E-04 1.7E-02 1.1E-02 5.3E-04 1,2,3-Trimethylbenzene 2.1E-07 7.9E-01 1.1E-01 1.1E-01 7.6E-04 1.6E-02 1.0E-02 5.0E-04 1,2,4-Trichlorobenzene 6.3E-07 2.4E+00 3.3E-01 3.3E-01 2.3E-03 4.9E-02 3.0E-02 1.5E-03 1,2,4-Trimethylbenzene 5.2E-06 1.9E+01 2.7E+00 2.7E+00 1.9E-02 4.1E-01 2.5E-01 1.2E-02 1,2-Dibromomethane (EDB)4.4E-07 1.6E+00 2.3E-01 2.3E-01 1.6E-03 3.4E-02 2.1E-02 1.1E-03 1,2-Dichlorobenzene 2.4E-07 9.0E-01 1.2E-01 1.2E-01 8.6E-04 1.9E-02 1.2E-02 5.8E-04 1,2-Dichloroethane 2.7E-07 1.0E+00 1.4E-01 1.4E-01 9.7E-04 2.1E-02 1.3E-02 6.5E-04 1,2-Dichloropropane 1.8E-07 6.7E-01 9.4E-02 9.4E-02 6.5E-04 1.4E-02 8.6E-03 4.3E-04 1,3,5-Trimethylbenzene 2.0E-06 7.5E+00 1.0E+00 1.0E+00 7.2E-03 1.6E-01 9.6E-02 4.8E-03 1,3-Butadiene 2.0E-05 7.5E+01 1.0E+01 1.0E+01 7.2E-02 1.6E+00 9.6E-01 4.8E-02 1,3-Dichlorobenzene 2.2E-07 8.2E-01 1.1E-01 1.1E-01 7.9E-04 1.7E-02 1.1E-02 5.3E-04 1,3-Diethylbenzene 2.5E-07 9.4E-01 1.3E-01 1.3E-01 9.0E-04 2.0E-02 1.2E-02 6.0E-04 1,4-Dichlorobenzene 3.7E-07 1.4E+00 1.9E-01 1.9E-01 1.3E-03 2.9E-02 1.8E-02 8.9E-04 1,4-Diethylbenzene 3.3E-07 1.2E+00 1.7E-01 1.7E-01 1.2E-03 2.6E-02 1.6E-02 7.9E-04 1,4-Dioxane 3.2E-07 1.2E+00 1.7E-01 1.7E-01 1.2E-03 2.5E-02 1.5E-02 7.7E-04 1-Butene 2.1E-05 7.9E+01 1.1E+01 1.1E+01 7.6E-02 1.6E+00 1.0E+00 5.0E-02 1-Hexene 2.0E-05 7.5E+01 1.0E+01 1.0E+01 7.2E-02 1.6E+00 9.6E-01 4.8E-02 1-Pentene 1.2E-05 4.5E+01 6.2E+00 6.2E+00 4.3E-02 9.4E-01 5.8E-01 2.9E-02 2,2,4-Trimethylpentane 2.3E-06 8.6E+00 1.2E+00 1.2E+00 8.3E-03 1.8E-01 1.1E-01 5.5E-03 2,2-Dimethylbutane 4.4E-07 1.6E+00 2.3E-01 2.3E-01 1.6E-03 3.4E-02 2.1E-02 1.1E-03 2,3,4-Trimethylpentane 1.4E-07 5.2E-01 7.3E-02 7.3E-02 5.0E-04 1.1E-02 6.7E-03 3.4E-04 2,3-Dimethylbutane 2.9E-06 1.1E+01 1.5E+00 1.5E+00 1.0E-02 2.3E-01 1.4E-01 7.0E-03 2,3-Dimethylpentane 2.7E-06 1.0E+01 1.4E+00 1.4E+00 9.7E-03 2.1E-01 1.3E-01 6.5E-03 2,4-Dimethylpentane 5.5E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.3E-02 2.6E-02 1.3E-03 2-Butanone (MEK)3.9E-06 1.5E+01 2.0E+00 2.0E+00 1.4E-02 3.0E-01 1.9E-01 9.4E-03 2-Ethyltoluene 2.2E-07 8.2E-01 1.1E-01 1.1E-01 7.9E-04 1.7E-02 1.1E-02 5.3E-04 2-Hexanone 4.4E-07 1.6E+00 2.3E-01 2.3E-01 1.6E-03 3.4E-02 2.1E-02 1.1E-03 2-Methylheptane 2.7E-06 1.0E+01 1.4E+00 1.4E+00 9.7E-03 2.1E-01 1.3E-01 6.5E-03 2-Methylhexane 4.4E-06 1.6E+01 2.3E+00 2.3E+00 1.6E-02 3.4E-01 2.1E-01 1.1E-02 2-Methylpentane 5.3E-06 2.0E+01 2.8E+00 2.8E+00 1.9E-02 4.1E-01 2.5E-01 1.3E-02 2-Nitropropane 2.8E-06 1.0E+01 1.5E+00 1.5E+00 1.0E-02 2.2E-01 1.3E-01 6.7E-03 2-Propanol 1.5E-07 5.6E-01 7.8E-02 7.8E-02 5.4E-04 1.2E-02 7.2E-03 3.6E-04 3-Chloropropene 4.7E-06 1.8E+01 2.4E+00 2.4E+00 1.7E-02 3.7E-01 2.3E-01 1.1E-02 3-Ethyltoluene 4.8E-06 1.8E+01 2.5E+00 2.5E+00 1.7E-02 3.7E-01 2.3E-01 1.2E-02 3-Methylheptane 3.5E-06 1.3E+01 1.8E+00 1.8E+00 1.3E-02 2.7E-01 1.7E-01 8.4E-03 3-Methylhexane 5.2E-06 1.9E+01 2.7E+00 2.7E+00 1.9E-02 4.1E-01 2.5E-01 1.2E-02 3-Methylpentane 7.1E-06 2.7E+01 3.7E+00 3.7E+00 2.6E-02 5.5E-01 3.4E-01 1.7E-02 4-Ethyltoluene 5.3E-06 2.0E+01 2.8E+00 2.8E+00 1.9E-02 4.1E-01 2.5E-01 1.3E-02 4-Methyl-2-pentanone 3.5E-07 1.3E+00 1.8E-01 1.8E-01 1.3E-03 2.7E-02 1.7E-02 8.4E-04 Acetone 2.3E-05 8.6E+01 1.2E+01 1.2E+01 8.3E-02 1.8E+00 1.1E+00 5.5E-02 TABLE OR APPENDIX 3-??? 1.3 CLASS WASTE MATERIAL CORRECTED ANNUAL EMISSION RATES (LBS/YR) ATK PROMONTORY, UTAH PAGE 4 OF 5 1 2 3 4 5 1 2 Analyte Corrected Emission Factor (lbs/lb) M-136 Quantities (lbs/year)M-225 Quantities (lbs/year) Acetonitrile 9.2E-06 3.4E+01 4.8E+00 4.8E+00 3.3E-02 7.2E-01 4.4E-01 2.2E-02 Acetylene 7.4E-05 2.8E+02 3.8E+01 3.8E+01 2.7E-01 5.8E+00 3.6E+00 1.8E-01 Acrylonitrile 1.0E-05 3.7E+01 5.2E+00 5.2E+00 3.6E-02 7.8E-01 4.8E-01 2.4E-02 alpha-Chlorotoluene 2.8E-07 1.0E+00 1.5E-01 1.5E-01 1.0E-03 2.2E-02 1.3E-02 6.7E-04 Benzene 4.4E-05 1.6E+02 2.3E+01 2.3E+01 1.6E-01 3.4E+00 2.1E+00 1.1E-01 Bromodichloromethane 3.9E-07 1.5E+00 2.0E-01 2.0E-01 1.4E-03 3.0E-02 1.9E-02 9.4E-04 Bromoform 6.3E-07 2.4E+00 3.3E-01 3.3E-01 2.3E-03 4.9E-02 3.0E-02 1.5E-03 Bromomethane 3.1E-07 1.2E+00 1.6E-01 1.6E-01 1.1E-03 2.4E-02 1.5E-02 7.4E-04 Butane 1.8E-05 6.7E+01 9.4E+00 9.4E+00 6.5E-02 1.4E+00 8.6E-01 4.3E-02 Carbon Disulfide 9.4E-06 3.5E+01 4.9E+00 4.9E+00 3.4E-02 7.3E-01 4.5E-01 2.3E-02 Carbon Tetrachloride 1.5E-05 5.6E+01 7.8E+00 7.8E+00 5.4E-02 1.2E+00 7.2E-01 3.6E-02 Chloroacetonitrile 5.6E-07 2.1E+00 2.9E-01 2.9E-01 2.0E-03 4.4E-02 2.7E-02 1.3E-03 Chlorobenzene 2.5E-06 9.4E+00 1.3E+00 1.3E+00 9.0E-03 2.0E-01 1.2E-01 6.0E-03 Chloroethane 1.3E-07 4.9E-01 6.8E-02 6.8E-02 4.7E-04 1.0E-02 6.2E-03 3.1E-04 Chloroform 6.1E-06 2.3E+01 3.2E+00 3.2E+00 2.2E-02 4.8E-01 2.9E-01 1.5E-02 Chloromethane 1.4E-05 5.2E+01 7.3E+00 7.3E+00 5.0E-02 1.1E+00 6.7E-01 3.4E-02 cis-1,2-Dichloroethene 2.3E-07 8.6E-01 1.2E-01 1.2E-01 8.3E-04 1.8E-02 1.1E-02 5.5E-04 cis-1,3-Dichloropropene 1.3E-06 4.9E+00 6.8E-01 6.8E-01 4.7E-03 1.0E-01 6.2E-02 3.1E-03 cis-2-Butene 1.4E-06 5.2E+00 7.3E-01 7.3E-01 5.0E-03 1.1E-01 6.7E-02 3.4E-03 cis-2-Pentene 1.7E-07 6.4E-01 8.8E-02 8.8E-02 6.1E-04 1.3E-02 8.2E-03 4.1E-04 Cumene 2.1E-07 7.9E-01 1.1E-01 1.1E-01 7.6E-04 1.6E-02 1.0E-02 5.0E-04 Cyclohexane 2.5E-06 9.4E+00 1.3E+00 1.3E+00 9.0E-03 2.0E-01 1.2E-01 6.0E-03 Cyclopentane 1.8E-06 6.7E+00 9.4E-01 9.4E-01 6.5E-03 1.4E-01 8.6E-02 4.3E-03 Decane 1.7E-05 6.4E+01 8.8E+00 8.8E+00 6.1E-02 1.3E+00 8.2E-01 4.1E-02 Dibromochloromethane 4.4E-07 1.6E+00 2.3E-01 2.3E-01 1.6E-03 3.4E-02 2.1E-02 1.1E-03 Ethane 1.7E-05 6.4E+01 8.8E+00 8.8E+00 6.1E-02 1.3E+00 8.2E-01 4.1E-02 Ethanol 1.6E-06 6.0E+00 8.3E-01 8.3E-01 5.8E-03 1.2E-01 7.7E-02 3.8E-03 Ethene 1.5E-04 5.6E+02 7.8E+01 7.8E+01 5.4E-01 1.2E+01 7.2E+00 3.6E-01 Ethyl benzene 2.8E-06 1.0E+01 1.5E+00 1.5E+00 1.0E-02 2.2E-01 1.3E-01 6.7E-03 Ethyl ether 1.2E-06 4.5E+00 6.2E-01 6.2E-01 4.3E-03 9.4E-02 5.8E-02 2.9E-03 Ethyl Methacrylate 7.8E-07 2.9E+00 4.1E-01 4.1E-01 2.8E-03 6.1E-02 3.7E-02 1.9E-03 Heptane 7.2E-06 2.7E+01 3.7E+00 3.7E+00 2.6E-02 5.6E-01 3.5E-01 1.7E-02 Hexachlorobutadiene 8.5E-07 3.2E+00 4.4E-01 4.4E-01 3.1E-03 6.6E-02 4.1E-02 2.0E-03 Hexane 9.8E-06 3.7E+01 5.1E+00 5.1E+00 3.5E-02 7.6E-01 4.7E-01 2.4E-02 Isobutane 2.8E-06 1.0E+01 1.5E+00 1.5E+00 1.0E-02 2.2E-01 1.3E-01 6.7E-03 Isopentane 2.0E-05 7.5E+01 1.0E+01 1.0E+01 7.2E-02 1.6E+00 9.6E-01 4.8E-02 m,p-Xylene 1.0E-05 3.7E+01 5.2E+00 5.2E+00 3.6E-02 7.8E-01 4.8E-01 2.4E-02 Methacrylonitrile 4.9E-06 1.8E+01 2.5E+00 2.5E+00 1.8E-02 3.8E-01 2.4E-01 1.2E-02 Methyl Acrylate 5.9E-07 2.2E+00 3.1E-01 3.1E-01 2.1E-03 4.6E-02 2.8E-02 1.4E-03 Methyl Methacrylate 8.1E-07 3.0E+00 4.2E-01 4.2E-01 2.9E-03 6.3E-02 3.9E-02 1.9E-03 Methyl tert-butyl ether 2.1E-07 7.9E-01 1.1E-01 1.1E-01 7.6E-04 1.6E-02 1.0E-02 5.0E-04 Methylcyclohexane 6.1E-06 2.3E+01 3.2E+00 3.2E+00 2.2E-02 4.8E-01 2.9E-01 1.5E-02 Methylcyclopentane 5.6E-06 2.1E+01 2.9E+00 2.9E+00 2.0E-02 4.4E-01 2.7E-01 1.3E-02 Methylene chloride 7.1E-06 2.7E+01 3.7E+00 3.7E+00 2.6E-02 5.5E-01 3.4E-01 1.7E-02 n-Butylchloride 5.8E-06 2.2E+01 3.0E+00 3.0E+00 2.1E-02 4.5E-01 2.8E-01 1.4E-02 Nonane 1.3E-05 4.9E+01 6.8E+00 6.8E+00 4.7E-02 1.0E+00 6.2E-01 3.1E-02 Octane 7.5E-06 2.8E+01 3.9E+00 3.9E+00 2.7E-02 5.9E-01 3.6E-01 1.8E-02 o-Xylene 3.5E-06 1.3E+01 1.8E+00 1.8E+00 1.3E-02 2.7E-01 1.7E-01 8.4E-03 Pentane 1.9E-05 7.1E+01 9.9E+00 9.9E+00 6.8E-02 1.5E+00 9.1E-01 4.6E-02 Propane 8.7E-06 3.3E+01 4.5E+00 4.5E+00 3.1E-02 6.8E-01 4.2E-01 2.1E-02 Propylbenzene 1.0E-06 3.7E+00 5.2E-01 5.2E-01 3.6E-03 7.8E-02 4.8E-02 2.4E-03 Propylene 4.3E-05 1.6E+02 2.2E+01 2.2E+01 1.5E-01 3.4E+00 2.1E+00 1.0E-01 Styrene 9.9E-07 3.7E+00 5.1E-01 5.1E-01 3.6E-03 7.7E-02 4.8E-02 2.4E-03 Tetrachloroethene 2.5E-06 9.4E+00 1.3E+00 1.3E+00 9.0E-03 2.0E-01 1.2E-01 6.0E-03 Tetrahydrofuran 6.4E-07 2.4E+00 3.3E-01 3.3E-01 2.3E-03 5.0E-02 3.1E-02 1.5E-03 Toluene 1.8E-05 6.7E+01 9.4E+00 9.4E+00 6.5E-02 1.4E+00 8.6E-01 4.3E-02 trans-1,2-Dichloroethene 3.6E-07 1.3E+00 1.9E-01 1.9E-01 1.3E-03 2.8E-02 1.7E-02 8.6E-04 trans-1,3-Dichloropropene 3.0E-07 1.1E+00 1.6E-01 1.6E-01 1.1E-03 2.3E-02 1.4E-02 7.2E-04 trans-2-butene 7.7E-06 2.9E+01 4.0E+00 4.0E+00 2.8E-02 6.0E-01 3.7E-01 1.8E-02 trans-2-Pentene 1.7E-06 6.4E+00 8.8E-01 8.8E-01 6.1E-03 1.3E-01 8.2E-02 4.1E-03 Trichloroethene 9.4E-07 3.5E+00 4.9E-01 4.9E-01 3.4E-03 7.3E-02 4.5E-02 2.3E-03 Undecane 1.2E-05 4.5E+01 6.2E+00 6.2E+00 4.3E-02 9.4E-01 5.8E-01 2.9E-02 Vinyl chloride 7.6E-06 2.8E+01 4.0E+00 4.0E+00 2.7E-02 5.9E-01 3.6E-01 1.8E-02 CEM CO2 6.9E-01 2.6E+06 3.6E+05 3.6E+05 2.5E+03 5.4E+04 3.3E+04 1.7E+03 CO 4.7E-03 1.8E+04 2.4E+03 2.4E+03 1.7E+01 3.7E+02 2.3E+02 1.1E+01 NOX 5.8E-03 2.2E+04 3.0E+03 3.0E+03 2.1E+01 4.5E+02 2.8E+02 1.4E+01 SO2 4.1E-04 1.5E+03 2.1E+02 2.1E+02 1.5E+00 3.2E+01 2.0E+01 9.8E-01 Highlighted analytes were not detected during the Bang Box testing program TABLE OR APPENDIX 3-??? 1.3 CLASS WASTE MATERIAL CORRECTED ANNUAL EMISSION RATES (LBS/YR) ATK PROMONTORY, UTAH PAGE 5 OF 5 1 2 3 4 5 1 2 Analyte Corrected Emission Factor (lbs/lb) M-136 Quantities (lbs/year)M-225 Quantities (lbs/year) CEM - Continuous Emissions Monitoring CL2 - chlorine CO - carbon monoxide CO2 - carbon dioxide HCL - hydrogen chloride HCN - hydrogen cyanide NH3 - ammonia NOX - nitrogen oxide OCDD - 1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin OCDF - 1,2,3,4,6,7,8,9-Octachlorodibenzo-p-furan PM10 - particulate matter less than 10 microns in aerodynamic diameter PM2.5 - particulate matter less than 2.5 microns in aerodynamic diameter SO2 - sulfur dioxide SVOCs - semi-volatile organic compounds TNMOC - total non-methane organic carbon TSP - Total suspended particulates VOCs - volatile organic compounds