DSHW-2010-054053 - 0901a068801e5458

Launch Systems Group
PO Box 707
Brigham City UT 84302
www atk com
July 21, 2009
8200-FY10-025
RECEIVED
JUL 2 7 2009
UTAH DIVISION OF
SOLID & HAZARDOUS WASTE
200=) OZ^IS
Mr Dennis R Downs, Executive Secretary
State of Utah
Department of Environmental Quality
Division of Solid and Hazardous Waste
288N 1460 W
P O Box 144880
Salt Lake City, Utah 84114-4880
Dear Mr Downs
ATTENTION JeffVandel
SUBJECT Final Report - Corrective Measure Pilot Test to Evaluate Ex-Situ
Remediation of Perchlorate Contaminated Soil
ATK Launch Systems - Promontory Facility
EPA ID # UTD009081357
Please find the enclosed report providing results for the evaluation of the ex-situ
remediation of perchlorate contaminated soil pilot test (Corrective Measure Pilot Test
Work Plan, September 2005, Revised Work Plan, July 2007) The report includes
analytical data indicating treatment effectiveness and mitigation strategies utilized to
overcome challenges encountered during execution of the Revised Work Plan Please
direct questions concerning this report to Jason Wells at 435-863-6895
Sincerely
David P Gosen, P E , Dirf c^r
Environmental Services
End
Final Report for Treatment of Perchlorate
Contaminated Soil Piles at E501
RECEIVED
JUL 2 7 2009
UTAH DIVISION OF
SOLID & HAZARDOUS WASTE
JE Wells
Environmental Services
ATK Space Systems
Promontory, Utah
July, 2009
A fK S/niLd Svstcni\ Pel ii/e C (iniJininaU'd Soil ai E5()l
Abstract
In September 2007 (Revised Work Plan for Corrective Measure Pilot Test to Evaluate Ex-Situ
Remediation of Perchlorate Contaminated Soil, July 2007) a pilot project commenced to treat
perchlorate contaminated soil using perchlorate reducing bacteria Effluent from the M-705
bioreactor, located on the ATK Promontory facility, was used to promote microbial perchlorate
reduction The effluent is primarily water with residual volatile orgamc acids that provide a
preferred electron donor source for the perchlorate reducing bacteria Additionally, the effluent
contains high numbers of perchlorate reducing bactena that serve to augment indigenous
perchlorate reducers already in the soil The initial attempt using bioreactor effluent on a pile of
excavated perchlorate contaminated soil led to partial, localized reduction Starting in Apnl
2008, lined roll-off dumpsters were used to facilitate effluent application to the soil and
assurance of optimal reducing conditions Using this setup, approximately 320 tons of soil
contaminated with an average of 800 ppm perchlorate was successfully treated between April
2008 and May 2009
Onginal Pilot Test for Ex-Situ Remediation of Perchlorate Contaminated Soil
Remediation of perchlorate contaminated soil began in October 2005 following the corrective
measure work plan onginally approved by the Utah Division of Solid and Hazardous Waste
(Work Plan for a Corrective-Measure Pilot Test to Evaluate Ex-situ Remediation of Perchlorate-
Contaminated Soil, August 2005) In bnef, the plan evaluated composting the soil with manure
to generate perchlorate reducing conditions However, sampling data showed that perchlorate
reduction did not occur (Table 1 A) Further analysis indicated that the soil mounds did not
become sufficiently anaerobic for measurable reduction of nitrate to occur either (Table IB)
The root cause was attnbuted to the lack of
carbon compounds that could quickly and
easily be metabolized by the microbial
community in the soil This likely led to a
slow response in generating anaerobic,
reducing conditions Additionally, the
manure probably increased nitrate
concentrations in the soil, effectively
prolonging or outright inhibiting any
perchlorate reduction In Fall of 2006, a new
treatment process using M-705 bioreactor
effluent was conceived and bench tested
Test results showed that anaerobic, reducing
conditions could be achieved using the
effluent A revised Work Plan was
submitted to DSHW and approved in July
2007
Table 1A
Test
Perchlorate Levels During Original Pilot
Bio pile
Perchlorate 1(20%)
2
(40%)
3
(60%)
4
(25%)
10/11/2005 295 292 140 486
10/26/2005 478 386 107 325
11/9/2005 537 479 138 439
12/8/2005 704 617 254 647
6/20/2006 734 240 175 254
8/7/2006 524 444 144 411
Table 1B Nitrate Levels Dunng Original Pilot Test
BIO pile
Nitrate-N 1(20%)
2
(40%)
3
(60%)
4
(25%)
8/7/2006 501 709 1190 627
July 2009
Sample Location Perchlorate (mg/kg)
Center 1 8
Surface 481
A TK Spui c SyMciiis Fci ^W()r<jt,: t 'onl^uniiuilcd \riil ui E5i)l
September 2007 Testing on North Soil Mound Used Revised Procedure
In September 2007 bioreactor effluent was applied to
approximately 140 tons of perchlorate contaminated Table 2 North Soil Mound Testing
soil (~ 400 ppm perchlorate) The soil mound was 5'
H X 13' W x 65' L All of the soil was placed over a
10 mil liner laid on asphalt A 12 inch deep x 3 feet
wide trench was formed in the top of the mound A
sump truck transferred effluent into the trench until
lull The effluent was allowed to soak into the mound until liquid was observed seeping from the
bottom edges Five applications of effluent took place between mid September to early
November resulting in just over 6000 gallons of bioreactor injected into the soil However, it
was observed that only the center section of the mound was getting enough effluent to provide
ample electron donor and moisture for perchlorate reducing conditions Attempts to improve
saturation of other areas of the mound only resulted in excess seeping into the containment Soil
samples from the surface (untreated) and center (treated) of the mound were collected in March
2008 Surface samples were considered untreated because little, if any, bioreactor effluent was
in contact with the soil in these areas to create perchlorate reducing conditions Conversely, the
center section was expected to have received sufficient volume of effluent to create reducing
conditions Soil characteristics and perchlorate analysis (Method 314 0) confirmed the
differences as shown in Table 2
Although the results were encouraging, it was apparent that modifications to the protocol needed
to be made to ensure all of the soil could be treated in a more efficient manner
April 2008 Treatment in Lined Roll-off Dumpsters
In April 2008, perchlorate contaminated soil stored in the E-501C impoundment from the
original pilot test was removed and composited on an area of lined asphalt directly adjacent to
the impoundment Six sealable 20 cubic yard roll-off dumpsters were rented and lined with
plastic sheeting Approximately 17 to 18 tons of the composited soil was placed in each
dumpster and the dumpsters were moved into the E-501C impoundment Enough bioreactor
effluent was added to completely saturate the soil The dumpsters were covered with tarps and
allowed to incubate Figure 1 shows the arrangement of dumpsters in E-501C Figure 2 gives a
representation of the soil dunng incubation
My 2000
A TK Space Systems Permmrate Conlaniinaled Soil at ESDI
Figure 1. Arrangement of Dumpsters in E-501C.
Figure 2. Soil During Incubation
-
Sampling and Data Analysis
Samples were taken with a stainless steel soil probe. Four subsamples were collected throughout
the length of the dumpster at a depth of approximately 12 to 16" below the liquid surface. The
subsamples were mixed to create a composite sample for the dumpster. Sampling equipment
Julv 2009
A TK Space Systems Pei-cmbrate Contaminated Soil at E50I
was rinsed with de-ionized water between dumpsters. Perchlorate analysis was performed using
EPA Method 314.0. Analytical data is provided in the Appendix.
Assurance of Microbial reduction
Figures 3 and 4 illustrate microbial perchlorate reduction over time for the first two dumpsters
treated. Samples were taken weekly for the first three weeks of incubation. A final sample was
taken on 5/28/2009.
Figure 3. Microbial Reduction in Dumpster RC
Weekly Perchlorate Levels Following 4/25/2008
Effluent Injection for RC
RC
Weekly Samples
55 mg/Kg
PRG
• 5/2/2008
• 5/9/2008
5/16/2O0S
• 5/28/200S
July 2009
A TK Space Systems Percnu)rate Contaminated Soil at E50I
Figure 4. Microbial Reduction in Dumpster RW
70
60
•Si
e 40
-2 30
20
Weekly Perchlorate Levels Following 4/25/2008
Effluent injection for RW
55 mg/Kg
PRC
I5/2S/2C08
RW
Weekly Simples
Perchlorate Reduction for All Batches
Figure 5 shows a graphical representation of perchlorate reduction for all three full batches (over
100 tons each) treated. A final batch of 20 tons was successfully treated during May 2009.
Dumpster ID indicates position in E-501C and is translated as follows:
RW = Rear West
RC = Rear Center
RE = Rear East
FE = Front East
FC = Front Center
FW = Front West
July 2009
A TK Space Systems Percmorate Contaminated Soil at E50I
Figure 5. Perchlorate Reduction for 100 Ton Batches.
Perchlorate Reduction in Extracted Soil
800 -
750 -
700 -
650 -
600 -
-g- 550 -
a 500 -
£ 450 -n
S 400 -
•5 350 -
o- 500 -
250 -
800 -
750 -
700 -
650 -
600 -
-g- 550 -
a 500 -
£ 450 -n
S 400 -
•5 350 -
o- 500 -
250 -
800 -
750 -
700 -
650 -
600 -
-g- 550 -
a 500 -
£ 450 -n
S 400 -
•5 350 -
o- 500 -
250 -
800 -
750 -
700 -
650 -
600 -
-g- 550 -
a 500 -
£ 450 -n
S 400 -
•5 350 -
o- 500 -
250 -
800 -
750 -
700 -
650 -
600 -
-g- 550 -
a 500 -
£ 450 -n
S 400 -
•5 350 -
o- 500 -
250 -
800 -
750 -
700 -
650 -
600 -
-g- 550 -
a 500 -
£ 450 -n
S 400 -
•5 350 -
o- 500 -
250 -
800 -
750 -
700 -
650 -
600 -
-g- 550 -
a 500 -
£ 450 -n
S 400 -
•5 350 -
o- 500 -
250 -
800 -
750 -
700 -
650 -
600 -
-g- 550 -
a 500 -
£ 450 -n
S 400 -
•5 350 -
o- 500 -
250 -
• Pre
• Batch 1 Post
Batch 2 Post
• Batch 3 Post
800 -
750 -
700 -
650 -
600 -
-g- 550 -
a 500 -
£ 450 -n
S 400 -
•5 350 -
o- 500 -
250 -
• Pre
• Batch 1 Post
Batch 2 Post
• Batch 3 Post
800 -
750 -
700 -
650 -
600 -
-g- 550 -
a 500 -
£ 450 -n
S 400 -
•5 350 -
o- 500 -
250 -
• Pre
• Batch 1 Post
Batch 2 Post
• Batch 3 Post
800 -
750 -
700 -
650 -
600 -
-g- 550 -
a 500 -
£ 450 -n
S 400 -
•5 350 -
o- 500 -
250 -
• Pre
• Batch 1 Post
Batch 2 Post
• Batch 3 Post
800 -
750 -
700 -
650 -
600 -
-g- 550 -
a 500 -
£ 450 -n
S 400 -
•5 350 -
o- 500 -
250 -
• Pre
• Batch 1 Post
Batch 2 Post
• Batch 3 Post
200 -
150 -
100 -
50 -
55 mg/Kg
PRO
200 -
150 -
100 -
50 -
55 mg/Kg
PRO
200 -
150 -
100 -
50 -
55 mg/Kg
PRO
200 -
150 -
100 -
50 -MOND ND ND NO • ;'')(•• NO rjD NO ND (WD
55 mg/Kg
PRO
u
RV-Y RC RE FE FC FW
DumpsterlD
Mobility of Metals
TCLP analysis was performed on samples during Batch 3 incubation. Of the regulated metals
present in the soil, all were well under the regulatory level, Table 2. Additionally, a direct
comparison between treated and untreated soil was performed as shown in Table 3. Iron levels
were slightly higher in the treated soil than the untreated. However, all other metals remained
the same.
Table 2. TCLP Results During Batch 3 Incubation
Metal (ug/L) FW FC
Dump
FE
ster ID
RE RC RW
Regulatory TCLP
level (mg/L)
Arsenic 229 275 305 261 239 231 5
Barium 311 517 514 426 524 525 100
Cadium U U U U U U 1
Chromium U U U U U U 5
Iron 167 149 192 166 234 162 N/A
Lead U U U U U U 5
Manganese 2070 2450 2990 3030 3310 2860 N/A
Selenium U U U U 47 U 1
U U U U Silver U U U U U U 5
Mercury U u U u U U 0.2
July 2009
A t k S/>ace Sysiciin PcixiTioi att Contaiianiit( d Sod al F50I
Table 3 TCLP on RW-2 and Untreated Soil
Metal (ug/L) RW-2 Untreated
Arsenic U U
Barium 1170 1220
Cadium U 27
Chromium U U
iron 409 102
Lead U U
Manganese 4480 3960
Selenium U U
Silver U U
Mercury U U
Conclusion
Approximately 320 tons of perchlorate contaminated soil was fully remediated by saturating soil
witii M-705 bioreactor effluent Using bioreactor effluent as the feed solution eliminates the cost
associated with adding an external refined carbon source Furthermore, the effluent contains
volatile acids that are readily utilized by perchlorate reducmg bacteria During warm months,
perchlorate was reduced to non-detectable levels as quick as 2 to 3 weeks Future process
improvements will focus on strategies to further reduce cost by reducing treatment time
hily 2009
ATK Spate Si ^/t'/;/s Pel CTTIorulc Containiiialed >H)d at E^OI
Appendix
November 2007 Surface vs Treated Sample Results
Client Sample ID E501-NSP-Surface Latwratory Sample ID 0803018-04
Date Sampled 03/12/08 10 05
Sample Description ATK-DLV - P3 Wells / E-501 Samples
Dilution
CAS Number Test Parameter
• TestM^hod ~^p^ j^g -
014797 73-0 PERCHLORATE
Result Units
Perchlorate lo£ Chromatography
481 mg/kg
MDL EQL Factor Analyst Test Date
0 1 04 JMM 03/28/08
Page 4 of 6
Printed 04/03/08 14 40
Listing of Results by Sample
Sample Delivery Group 0803018
Client Sample ID E501-NSP-Center Laboratory Sample ID 0803018-05
Date Sampled 03/12/08 10 35
Sample Description ATK-DLV - P3 Wells / E-501 Samples
Dilution
CAS Number
~ TestMBtliod
ln\ Parameter
EPA 3140
014797-73-0 PERCHLORATE
Result Unrts
Perchlorate - Ion Chromatography
18 mg/kg
MDL EQL Factor Analyst Test Date
01 04 JMM 03/28/08
5/2/2008 Sample Data
Listing of Results by Sample
Sample Delivery Group 0805008
Client Sample ID E501-RW#1 Laboratory Sample ID 0805008-01
Date Sampled 06/02/08 13 55
Sample Descnption ATK-DLV- E-501 Soil Treatment
Date Sampled
Dilution
CAS Number Twt Parimetef
feslUelhoir EPA 3140
014797 73-0 PERCHLORATE
Result Units
Perchlorate - Ion Chromatography
G41 mg/kg
MDL EQL faclQ£ Arwlvst Test Date
10 JMM 05«9/08
Client Sample ID E501-RC#1 Laboratory Sample ID 0805008-02
Date Sampled 06/02/08 14 00
Sample Description ATK DLV- E-501 Soil Treatment
CAS Number Test Parameter
TestUe&ibdf EPA3U0
014797 73-0 PERCHLORATE
Result Units
Parchtorate Ion Chromatogr^ihy
484 mg/kg
MDL
Dilution
EQL Factor Analyst Test Date
10 JMM OSlOSIM
July 20119
y\Tk SpOLL. Si -..'..///S
5/9/2008 and 5/16/2008 Sample Data for RC
PerHlloi ate Cui'iiiiminaU d Sod uJ E5')l
Listing of Results by Sample
Sample Deliveiv Group 0805025
Client Sample ID E501-RC#2 Laboratory Sample ID 0805025-01
Date Sampled 05/09/08 14 00
Sample Description ATK-DLV - E-501 Soil Treatment
Date Sampled
Dilution
CAS Number
\ fesi Methoel l
014797-73^)
Test Paramefei:
EPASUjT
PERCHLORATE
Result Units
Perchlorate - Ion Chrorratography
3 E mg/kg
MBl. EfiU Factor AoalXSS l£SLJQat£
10 JMM 05/28/08
Client Sample ID E501-RC#3 Laboratory Sample ID 0805025-02
Date Sampled 05/16/08 09 00
Sample Description ATK DLV - E-501 Soil Treatment
Date Sampled
CAS Number Test Parameter
[ 1isiiJMi(^ ^ EPAYU^^^^
014797-73-0 PERCHLORATE
Result Units
Perchtorate ion Ctirornalograpf^
U mg/kg
MDL
Dilution
EQL Factor Analyst Test Date
10 JMM 0S/28A)8
lulv 20V') 10
ATK Sj'iite .SJ'S/L7/7S 'oriite Cfiit,iminaicd Soil m E50I
Listing of Results by Sample
Sample Delivery Group 0806002
Client Sample ID E-501-RC#4 Laboratory Sample ID 0806002-01
Date Sampled 05/28/08 13 45
Sample Description ATK-DLV E-501 Soil Treatment
Date Sampled
Dilution
CAS Numbet Test Parameter
EPA 3140
014797 73-0 PERCHLORATE
Result Units
Penrhlorato ton Chromatography
58 mg/kg
IBDL SQL EactSC AoabOt Test Date
10 JMM 06/05/08
Client Sample ID E-501-RW#4 Laboratory Sample ID 0806002-02
Date Sampled 05/28/08 09 15
Sample Description ATK-DLV E 501 Soil Treatment
Date Sampled
CAS Number Test Parameter
Test Method^2 JP^P'"' Z
014797 73-0 PERCHLORATE
Result Units
Perchiorate_ Ion Chromatography
16 4 mg/kg
MDL
Dilution
EQL Factor Analyst Test Date
10 JMM O6I05I0S
Client Sample ID E-501-RE#1 Laboratory Sample ID 0806002-03
Date Sampled 05/28/08 14 00
Sample Description ATK-DLV E-501 Soil Treatment
Date Sampled
Dilution
CAS Number Test Parameter
festUahod ^p^-^Y^
014797 73-0 PERCHLORATE
Result Units
Pen^lorate Ion Chromatography
U mg/kg
MDL EQL Factor Analyst Test Date
10 JMM
Client Sample ID E-501-FE#1 Laboratory Sample ID 0806002-04
Date Sampled 05/28/08 14 15
Sample Descnption ATK-DLV E-501 Soil Treatment
Date Sampled
Dilution
CAS Number
TestUethod
014797-73-0
Test Parameter
EPA 314.0
PERCHLORATE
Result Units
Perchlorate Ion Chromatography
44 7 mg/kg 10 JMM 06/05/08
Client Sample ID E-501-FC#1 Laboratory Sample ID 0806002-05
Date Sampled 05/28/08 09 05
Sample Description ATK DLV E-501 Soil Treatment
Date Sampled
Dilution
CAS Number Test Parameter Result Units MDL EQL Factor Anal; irst Test Date
TestUethod. EPA 3140 Perchlorate Ion Chromatography
014797 73-0 PERCHLORATE 14 7 mgfltg 1 4 10 JMM 06/05^8
Client Sample ID E-501 -FW#1 Laboratory Sample ID 0806002-06
Date Sampled 05/28/08 09 25
Sample Description ATK-DLV E-501 Soil Treatment
Date Sampled
Dilution
CAS Number Test Parameter
TestUethod EPA 3140
014797-730 PERCHLORATE
PerchkHate Ion Chromatography
U mg/kg 10 JMM 06/05/08
Page 3 of 4
PMnted 06>oaos>ros
////)• 2009 11
A Tk S/>aLC Sy\iems Pci.^hloraiL <, onlainnuiledS-'il at £^''/
Listing of Results by Sample
Sample Delivery Group 0807023
Client Sample ID E501-FW-B2 Laboratory Sample ID 0807023-01
Date Sampled 07/22/08 13 10
Sample Description ATK-DLV - E-501 Soil Treatment
Dilution
CAaNunnber Twt Parapittpr
; Test~MMKid~_JPA3140
014797 730 PERCHLORATE
Result Units
Perchlorate Ion Chrornatogn^t^
U mg/kg
MDL, EQL Factor Analyst Test Date
01 04 JMM 03/05/08
Client Sample ID E501-FC-B2 Laboratory Sample ID 0807023-02
Date Sampled 07/22/0813 20
Sample Description ATK-DLV - E-501 Soil Treatment
CAS Number Test Parameter
TestUethod EPA3146
014797 73-0 PERCHLORATE
Result Units MDL
Perchlorate Ion Chromatography
U mg/kg 01
Dilution
EQL Factor Analyst Test Date
04 JMM 08/05/08
Client Sample ID E501-FE-B2 Laboratory Sample ID 0807023-03
Date Sampled 07/22/08 13 30
Sample Description ATK-DLV E 501 Soil Treatment
CAS Numt)er Test Parameter
TestUethod EPA 3140
014797 730 PERCHLORATE
Result Units MDI^
Perchtorate Ion Chromatography
U mg/kg 01
Dilution
EQL Factor Analyst Test Date
04 JMM osiQsme
Client Sample ID E501-RE-B2 Laboratory Sample ID 0807023-04
Date Sampled 07/22/08 13 40
Sample Description ATK DLV E 501 Soil Treatment
Dilution
CAS Number
TestUethod
014797-73-0
Test Parameter
EPA 3140
PERCHLORATE
Result Units
Perchtorate Ion Chromatography
U mg/kg
ftBL EQL EsSiaL Aaat^ Test Date
0 1 04 JMM QBI0SIQ6
Client Sample ID E501-RC-B2 Laboratory Sample ID 0807023-05
Date Sampled 07/22/08 13 55
Sample Description ATK-DLV E-501 Soil Treatment
CAS Number Test Parameter
TestUethod EPA 3140
014797 730 PERCHLORATE
Result Units MDl,
Perchtorate Ion Chromatogi^F>hy
U mglkg 01
Dilution
iSk Factor Anfily^t Test Date
04 JMM Q&OS/OS
Client Sample ID E501-RW B2 Laboratory Sample ID 0807023-06
Date Sampled 07/22/08 14 05
Sample Description ATK-DLV E-501 Soil Treatment
CAS Number Test Parameter
TestUethod EPA 3140
014797-730 PERCHLORATE
Result Units MDL
Perchtorate Ion Chromatography
U mg/kg 01
Dilution
EQL Factor Anah«t Test Date
04 08/05/08
Page 3 Of 4
Prlnfd 08«&08t020
luly 2009 12
A'lk S/iLh i - Sysicins Pel I, nloi ill,: < ^onlnnnnirtcd Soil ai ESDI
Listing of Results by Sample
Sample Delivery Group 0810001
Client Sample ID E501-FW-B3
Sample Description ATK-DLV - E 501 Soil Treatment Samples
Laboratory Sample ID 0810001-01
Date Sampled 09/30/08 1040
CAS Number Test Parameter ResuK Units MDL £S2L
Dilution
Factor Analyst Test Date
TestUethod Perchlorate Ion Chromatography
014797 73-0 PERCHLORATE U mg/kg 1 4 10 JMM 10/10/08
TestUethod Sff-m 1311
1311 EXTRACTION
TCLP Extradton
10/09/2008
00 00
1 MTB
i
10A)9/08
TesiU^hod SWMS 3o m
3010A ACID DIGESTION
Metals DIgastton
10/10/2008
00 00
--
1 MTB 10/10/08
' TestUetlixi SW846 ebm (Water) Matels Analysis by ICP 6010 \
7440-38-2 ARSENIC 229 ug/L 20 100 1 MTB 10/13«J8
7440-39-3 BARIUM 311 ugl 2 10 1 MTB 10/13/08
7440-43-9 CADMIUM U ug/L 1 5 1 MTB 10/13«J8
7440-47 3 CHROMIUM U ug/L 10 50 1 MTB 10/13/08
7439-89-6 IRON 167 ug/L 20 100 1 MTB 10/13/08
7439-92 1 LEAD U ug/L 20 100 1 MTB 10/13/08
7439-96-5 MANGANESE 2070 ug/L 1 5 1 MTB 10/13/08
7782-49-2 SELENIUM U ug/L 30 150 1 MTB 10/13^)8
7440-22-4 SILVER U ug/L 1 5 1 MTB 10/13/08
Sl¥- S46, 7470A Mercury Analysis
7439-97-6 MERCURY U ug/L 03 1 1 TCP 10/13/08
Client Sample ID E501-FC-B3 Laboratory Sample ID 0810001-02
Sample Description ATK-DLV - E-501 Soil Treatment Samples
Date Sampled 09/30/08 10 15
CAS Number Test Parameter Result Uni^ MDL Dilution
Factor Analyst TestD^V)
TestUethod EPA 3140 Perchtorate Ion Chromatography
014797 730 PERCHLORATE 19 8 mg/kg 1 4 10 10/10/08
TestUethod Si¥-84S. 1311
1311 EXTRACTION
TCLP Extraction
10/09/2008 00 00
1 MTB
TestUethod^ SW-S46,X10A
301 OA ACID DIGESTION
Metals Digestton
10/10/2008
00 00
1 MTB 10/10/08
TestU^hod. sw-a4s 6oioB(mei) Metals Analysis by ICP 6010
7440-38-2 ARSENIC 275 ug/L 20 100 1 MTB 10/13/08
7440-39-3 BARIUM 517 ug/L 2 10 1 MTB 10/13X18
7440-43-9 CADMIUM U ug/L 1 5 1 MTB 10/13/08
744047-3 CHROMIUM U ug/L 10 50 1 MTB 10/13/08
7439-8M IRON 149 ug/L 20 100 1 MTB 10/13A)8
7439-92 1 LEAD U ug/L 20 100 1 MTB 10/13A)8
7439-96-5 MANGANESE 2450 ug/L 1 5 1 MTB 10/13A]e
7782-49-2 SELENIUM U ug/L 30 150 1 MTB 10/13/08
7440-22-4 SILVER U ug/L 1 5 1 MTB 10/13/08
TestUethod SW^846,J47aA Mercury Analysis
7439-97-6 MERCURY U ug/L 03 1 1 TCP 10/13/08
Prinfd
Page 4 of?
10/1SM lau
luly 2009 13
ATK Spate Systems ^k Pcunloraic ( i'lilaiiunattdSod m E50I
Listing of Results by Sample
Sample Delivery Group 0810001
Client Sample ID E501 -FE-63
Sample Description ATK DLV - E-501 Soil Treatment Samples
Laboratory Sample ID 0810001 -03
Date Sampled 09/30/08 10 05
CAS Number Ti^t Parameter BSSUll
014797 73-0 PERCHLORATE U mg/kg
TesfUethod SW-S46 1311 TCLPExfracton ~
Dilution
UQk ifik Factor AoaliSl Test Date
10 JMM 10/10/08
1311 EXTKACTION 10/09/2008
00 00
1 MTB 10/09/08
TestUethod SW^XIOA Metals DigMdton
3010AACID DIGESTION 10/10/2008
00 00
1 MTB 10/10/08
TestUethod SW 846 som (Water) Metals Analysis by ICP loiO
7440-38-2 ARSENIC 305 ug/L 20 100 1 MTB 10/13flD8
7440-39-3 BARIUM 514 ug/L 2 10 1 MTB 10/13/08
7440-43-9 CADMIUM U ug/L 1 5 1 MTB 10/13«)8
744047 3 CHROMIUM U ug/L 10 50 1 MTB 10/13/08
7439-89-6 IRON 192 ug/L 20 100 1 MTB 10/13/08
7439-92 1 LEAD U ug/L 20 100 1 MTB 10/13/08
7439-96-5 MANGANESE 2990 ug/L 1 5 1 MTB 10/13rt)8
7782-49-2 SELENIUM U ug/L 30 150 1 MTB 10/13A)S
7440-22-4 SILVER U ugn. 1 5 1 MTB 10/13/08
T^tUethod SWa4S, 7470A Mercury Analysis
7439-97-6 MERCURY U ug/L 03 1 1 TCP 10/13/08
Client Sample ID ES01-RE 83 Laboratory Sample ID 0810001-04
Sample Description ATK-DLV - E-501 Soil Treatment Samples
Date Sampled 09/30/08 10 25
CAS Number Test Parameter Result Unrts MDL
Dilution
Factor Analyst Test Date
festUetttod^ 1PA3140 Perchtorate Ion Chromatogr^hy i
014797 73-0 PERCHLORATE U mg/kg 1 4 10 JMM 10/10/08
TestUethod SW846 1311 TCLP Extraction
1311 EXTRACTION 10/09/2008
00 00
1 MTB 1Q«9/08
TestUethod SW84e 3010A Metals Digestion
3010AACID DIGESTION 10/10/2008
00 00
1 MTB 10/1 QA)8
TestUethod sw-meoioB(Waia) Metals Analysis by ICP 6010
7440-38-2 ARSENIC 261 ug/L 20 100 1 MTB 10/13X18
7440-39-3 B/kRIUM 426 ug/L 2 10 1 MTB 10/13X18
7440-43-9 CADMIUM U ug/L 1 5 1 MTB 10/13«8
7440-47-3 CHROMIUM U ug/L 10 SO 1 MTB 10/13X18
7439-S»« IRON 166 ug/L 20 100 1 MTB 10/13X18
7439-92 1 LEAD U ug/L 20 100 1 MTB 10/13X18
7439-96-5 MANGANESE 3030 ug/L 1 5 1 MTB 10/13X«
7782-49-2 SELENIUM U ug/L 30 150 1 MTB 10/13X18
7440-22-4 SILVER U ug/L 1 5 1 MTB 10/13X18
TestUethod SW-S4e, 7470A Mercury Analysis
7439-97-6 MERCURY U ug/L 03 1 1 TCP 10/13X18
Page 5 of 7
PrintatL I0/is/oat038
lulv 2009 14
A TK Spac e S_i s/i-zj/s Percfiloraie C untammaicdSod ai E^Ol
Listing of Results by Sample
Sample Delivery Group 0810001
Client Sample ID ES01 RC-B3 Laboratory Sample ID 0810001-05
Sample Descripbon ATK DLV E 501 Soil Treatment Samples
Date Sampled 09/30/08 10 30
CAS Number Test Parameter Result Units MDL £fiL
Dilution
Factor Analyst lesLBatfi
[yKTukhod' EPA 3140 Perchtorate kjn Chromatography \ I '..II. „, J
014797 73-0 PERCHLORATE u mg/kg 1 4 10 JMM 10/10X18
Testll^tiod SW-MS 1311
1311 EXTRACTION
TCLP Extraction
10/09/2008
00 00
- --
1 MTB 10X19X18
f TestUethod SWm301M
3010A ACID DIGESTION
Metals Digestton
10/10/2008
00 00
1 MTB 10/10/08
> TestUethod SW 846 66tW(Water) Metels/Analysis by ICP 6010 ..HZ " !
7440-38-2 ARSENIC 239 ug/L 20 100 1 MTB 10/13/08
7440-39-3 BARIUM 524 ug/L 2 10 1 MTB 10/13X18
7440-43-9 CADMIUM U ug/L 1 5 1 MTB 10/13/08
744CM7 3 CHROMIUM U ug/L 10 50 1 MTB 10/13X18
7439-89-6 IRON 234 ug/L 20 100 1 MTB 10/13X18
7439-92 1 LEAD U ug/L 20 100 1 MTB 10/13X18
7439-96-5 MANGANESE 3310 ug/L 1 5 1 MTB 10/13X18
7782-49-2 SELENIUM 47 J ug/L 30 150 1 MTB 10/13/08
7440-22-4 SILVER U ug/L 1 5 1 MTB 10/13/08
TestUethod SW846'7470A Mercury Analysis
7439-97-6 MERCURY U ug/L 03 1 1 TCP 10/13X18
Client Sample ID E501 RW B3 Laboratory Sample ID 0810001-06
Sample Description ATK DLV E 501 Soil Treatment Samples
Date Sampled 09/30/08 10 35
CAS Number
TestUethod
014797 73-0
TestUethod
Test Parameter
EPA 3140
PERCHLORATE
SW-84S, 1311
1311 EXTRACTION
Result Unrts
Perditorate - Ion Chromatography
U mg/kg
TCLP Extraction"
10/090008
00 00
Dilution
MDL EQL Factor Anahrst Test Date
10
TestUethod SWa46,3010A Metals Digestton
3010A ACID DIGESTION 10/10/2008
00 00
TestU^hod SW-846,6010B(Water) Metals Analysis by ICP 6010
7440-3&-2 ARSENIC 231 ug/L
7440-39-3 BARIUM 525 ug/L
7440-43-9 CADMIUM U ug/L
744047-3 CHROMIUM U ug/L
7439-89-6 IRON 162 ug/L
7439-92 1 LEAD U ug/L
7439-96-5 MANGANESE 2860 ug/L
7782-49-2 SELENIUM U ug/L
7440-22-4 SILVER U ug/L
TestUethod SVII-846, 7470A Mercury Analysis
7439-97-6 MERCURY U ug/L
20
2
1
10
20
20
1
30
1
03
100
10
5
50
100
100
5
150
5
JMM
MTB
MTB
MTB
MTB
MTB
MTB
MTB
MTB
MTB
MTB
MTB
TCP
10/10X18
lomxe
10/10X18
10/13X18
10/13X18
10/13X18
10/13/08
10/13X18
10/13X18
10/13X18
10113X18
10/13X18
10/13X18
Page 6 of 7
ro'tsoa tost
luly 2009 15
iTK Spihc Systems f
. •; Enk
oiiue L'onlamtiuiicdSod at E5('
Listing of Results by Sample
Sample Delivery Group 0810032
Client Sample ID E501-FC-B3-RS
Sample Description ATK-DLV - E-501 Soil Treatment
Laboratory Sample ID 0810032-01
Date Sampled 10/20/08 09 50
CAS Number Test Parameter Result Units Ei2L
Dilution
Factor Anah/st Test Date
f TestUethod " SW 84^ 1311
1311 EXTRACTION
TCLP Extractton
10/27/2008
00 00
. . . -•- -1 MTB 10/27/08
1 TestUethod SW-846'xm
3010A ACID DIGESTION
Metals Digestion
10/31/2008
00 00
--~ • - -
1 MTB ia'31/08
: TestUethod 5l»^MS eoiOB(Waferj Metals Afialysis by ICP 6010
7440-38-2 ARSENIC u ug/L 20 100 1 MTB 10/31X18
7440-39-3 BARIUM 1170 ug/L 2 10 1 MTB 10/31X18
7440-43-9 CADMIUM u ug/L 1 5 1 MTB 10/31/08
744047-3 CHROMIUM U ug/L 10 50 1 MTB 10/31X18
743949-6 IRON 409 ug/L 20 100 1 MTB 10/31X18
7439-92 1 LEAD U ug/L 20 100 1 MTB 10/31X18
7439-96-5 MANGANESE 4480 ug/L 1 S 1 MTB 10/31X18
778249-2 SELENIUM U ug/L 30 150 1 MTB 10/31X18
7440-224 SILVER U ug/L 1 5 1 MTB 10/31X18
TesEMetimd SW846, 7470A Mercury Analysis
7439-97-6 MERCURY U ug/L 03 1 1 TCP 11/03X18
Client Sample ID E501 Untreated Laboratory Sample ID 0810032-02
Sample Description ATK-DLV E 501 Soil Treatment
Date Sampled 10/21/08 1110
CAS Number Test Parameter Result Unrts MDL
Dilution
Factor Anahrst Test Date
TestUethod SmS46, 1311
1311 EXTRACTION
TCLP Extractton
10/27/2008
00 00
1 MTB 10/27X18
TestUethod SW846,3010A
3010AACID DIGESTION
Metels Digestton
10/31/^8
00 00
- -
1 MTB 10/31X18
TestUethod SW-846,i010B(Wslei) Metals Analysis by ICP 6010
7440-38-2 ARSENIC U ug/L 20 100 1 MTB 10/31/08
7440-39-3 BARIUM 1220 ug/L 2 10 1 MTB 10/31X18
744043-9 CADMIUM 27J ug/L 1 5 1 MTB 1091X18
744047-3 CHROMIUM U ug/L 10 50 1 MTB 10/31X18
743949-6 IRON 102 ug/L 20 100 1 MTB 10/31X18
7439-92 1 LEAD U ug/L 20 100 1 MTB 10/31X18
7439-96-5 MANGANESE 3960 ug/L 1 5 1 MTB 10/31X18
778249-2 SELENIUM U ug/L 30 ISO 1 MTB 10/31X18
7440-22-4 SILVER U ug/L 1 5 1 MTB 10>O1/08
TestUethod SW846, 7470A Mercury Analysis
7439-97-6 MERCURY U ug/L 03 1 1 TCP 11X13X18
PrinttI
Page 3 of 4
tf/DStW 1026
July 2(109 16
A FK S/.'iH e SyMcms Pei cldoruft- CoiiluiiiU'hited ,Sijd at E "^01
Listing of Results by Sample
Sample Delivery Group 0811019
Client Sample ID E501-FC-B3-RS Laboratory Sample ID 0811019-01
Date Sampled 10/20/08 09 50
Sample Description ATK-DLV - E501 Soil Treatment - Perchlorate
Dilution
CAS Number Test Parameter BsjuK UQH^ MQk IfiL SSSSSO. taOtH^ Test Date
014797 73-0 PERCHLORATE U mg/kg 1 4 10 JMM 11/18/08
Samplmg for Fmal 20 yards
Listing of Results by Sample
Sample Delivery Group 0811023
Client Sample ID E501 Final Batch ' Laboratory Sample ID 0811023-01
Date Sampled 11/17/0811 05
Sample Description ATK-DLV E-501 Soil Treatment
Dilution
CAS Number Test Parameter Resurt UlilSS. UQk SSL EaStfiL bSOt^ Test Date
TestUethod EPA 3140 Perchtorate Ion Chromatography
014797 73-0 PERCHLORATE 18 mg^g 1 4 10 JMM 11/19/08
Listing of Results by Sample
Sample Delivery Group 0812006
Client Sample ID E501-Final-2 Laboratory Sample ID 0812006-01
Date Sampled 12/05/08 13 10
Sample Description ATK-DLV E-501 Soil Treatment
Date Sampled
Dilution
CAS Number Test Parameter B^UU \MS. VBL SQL ESSiSO. AUil^ l£SL
TestUethod EPA3U0 Perchtorate Ion Chromatog^y ^
014797 73-0 PERCHLORATE 18 7 mgrttg 1 4 10 JMM 12/12X18
Listing of Results by Sample
Sample Delivery Group 0905009
Client Sample ID E501 FC-09-1 Laboratory Sample ID 0905009-01
Date Sampled 05/04/0911 15
Sample Description ATK DLV - E-501 Soil
Dilution
CAS Number Test Parameter gfisutt HoBS. USL SQL HSHO. ^JOlOSi leHAalS
. TestU^iod ~EPA3i40 J Perchtorate^ IonClwMratogra^
014797 73-0 PERCHLORATE U mg/kg 1 4 10 JMM 06X17X19
luly 2000 ij