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HomeMy WebLinkAboutDAQ-2024-0074011 DAQC-PBR045790001-23 Site ID 4579 (B1) MEMORANDUM TO: FILE – UINTA WAX OPERATING, LLC – RP27S Battery H6UB and H8UB THROUGH: Rik Ombach, Minor Source Oil and Gas Compliance Section Manager FROM: Chris Jensen, Environmental Scientist DATE: December 5, 2023 SUBJECT: OIL AND GAS PERMIT-BY-RULE EVALUATION INSPECTION DATE: November 15, 2023 SOURCE LOCATION: RP27S Battery H6UB and H8UB Lat: 40.200634 Long: -109.945725 Business Office: 5128 Apache Plume Road, Suite 300 Fort Worth, TX 76109 SOURCE TYPE: Tank Battery Duchesne County API: 4301353478, 4301353482, 4301353483, 4301353484, 4301353486, 4301353488 SOURCE CONTACTS: Aimee Cole, Local Contact Phone: 720-384-7365, Email: acole@finleyresources.com Kaylene Bridwell, Corporate Environmental Contact Phone: 405-496-7308, Email: kaylene.bridwell@uintawax.com OPERATING STATUS: Operating PROCESS DESCRIPTION: Oil and gas products are brought to the surface. These products go through a separator where the oil and any water products are sent to storage tanks and the gas is used to power equipment on site (pump jack engine, tank heater, separator, flare, combustor, etc.) Any remaining gas is sent to a pipeline that feeds a local gas plant. The oil and process water in the storage tanks is loaded into tanker trucks and hauled off site for processing and disposal. APPLICABLE REGULATIONS: Utah Administrative Code (UAC) R307-500 Series for the Oil and Gas Industry, and UAC R307-201: Emission Standards: General Emission Standards; and UAC R307-150: Emission Inventories, 40 CFR 60 Subpart OOOOa and 40 CFR 60 Subpart JJJJ. 2 SOURCE EVALUATION: Site Type: PBR-Controlled Controlled by flare Site powered by Engine The source registered: 1,642,500 Estimated Oil BBL. DOGM current 12 month rolling production is: 294,000 BBLs. Utah Statute R307-506 requires a source with throughput greater than 8,000 BBLs to have controls. REGISTERED EQUIPMENT: Engine - Natural Gas 4-Stroke Rich Burn Make - Doosan Model - D14.6L Mfg Year - 2012 Horse Power - 449 Combustion - Natural Gas, Pneumatic, Tank 3 General Provisions 4 VOC emissions are minimized as reasonably practicable by equipment design, maintenance and operation practices. [R307-501-4(1)] In Compliance. This source was found to be clean and well-kept with no visible or fugitive emissions. The source was inspected by AVO and with an OGI camera. 5 Air pollution control equipment is designed and installed appropriately, maintained and operated to control emissions. [R307-501-4(2)] In Compliance. An enclosed combustor is installed and operating properly. The DAQ looked for design and installation parameters such as: the vessel vent line is sloped away from the inlet of the combustor, a two-phase scrubber is used to separate natural aas liquids or condensates, the combustor has a lit pilot with an auto-ignition device, and the inlet to the combustor is controlled by a pressure regulating device. 6 Vessel vent lines are sloped away from the flare inlet or to a separation vessel (scrubber). [R307-501-2] In Compliance. The vent lines are sloped properly. 7 Flare inlet lines are equipped with a fire arrestor, pressure gauge, inlet pressure regulating valve and other components according to the engineering design, the manufacturers specifications or good practices for safety and emissions control. [R307-501-2] In Compliance. The expected components were found installed. 8 Pneumatic Controllers 9 Continuous bleed natural gas-driven pneumatic controllers are in compliance with 40 CFR 60.5390 or 60.5390a as applicable. Exemptions to tagging and record keeping requirements apply to controllers existing before December 1, 2015. [R307-502-4] In Compliance. This source does not use continuous bleed natural gas-driven pneumatic controllers. 10 Flares 11 Any flare has an operational auto-igniter. [R307-503-4] In Compliance. Auto-ignition is managed by the ECD control box. 3 12 Tank Truck Loading 13 Truck loading is done by bottom filling or submerged fill pipe. [R307-504(1)] In Compliance. The truck loading area is suitable for submerged loading and it is routine for truck drivers to load this way. 14 A vapor capture line is used during truck loading if subject to storage vessel emissions controls of R307-506-4(2). Effective July 1, 2019, for sources existing before January 1, 2018, and upon construction for new sources. [R307-504-4(2)] In Compliance. This source has the required vapor capture line installed. 15 Oil and Gas Industry Registration Requirement 16 The source is registered with the DAQ. [R307-505-3(3)] In Compliance. 17 Registration has been updated within 30 days of a company name change, removal or addition of control devices, or termination of operations. [R307-505-3(3)] In Compliance. 18 Storage Vessels 19 Thief hatches are kept closed and latched. [R307-506-4(1)] In Compliance. All hatches were found closed at the start of the evaluation. 20 VOCs from storage vessels are recycled, recovered or controlled by a device that is compliant with R307-508. Exempt if <8000 bbls crude oil per year, <2000 bbls condensate, or if uncontrolled emissions are <4 tons VOC per year. [R307-506-4(2)(a)] In Compliance. Tank emissions are routed to a Steffes 2aas air assisted flare. 21 Emissions from emergency storage vessels are controlled according to R307-506-4(2), or are only used in emergencies, are emptied within 15 days of receiving fluids and are equipped with a liquid level gauge. [R307-506-4(4)] In Compliance. No tanks are uncontrolled or used as an emergency tank. 23 Upon modification, the well site was re-evaluated against the thresholds of R307-506-4(2). [R307-506-4(6)] In Compliance. The DAQ did not identify any modifications or unauthorized equipment. 24 Records for each of the following are kept for three years: Storage vessel vent system inspections (openings, thief hatches, pressure relief devices, bypasses, etc.), if required Monthly crude oil throughput Emission calculations, actuals and sampling data when used to justify an exemption to storage vessel rules Emergency storage vessel usage (dates used, emptied, and volumes), if not controlled per R307-506-4(2)[R307-506-5] In Compliance. The operator provided daily AVO inspection forms and 12 month production totals for all wells on this source. 4 25 VOC Control Devices 26 The VOC control device(s) required by R307-506 or R307-507 has a control efficiency of 95% or greater, operates with no visible emissions and has an operational auto-igniter according to R307-503. [R307-508-3(1)] In Compliance. Yes. This model of flare has been demonstrated to exceed this standard. 27 Monthly AVO inspections are conducted on VOC control devices and associated equipment, and corrective actions are taken within 15 days. [R307-508-3(3)] Out of Compliance. AVOs were conducted and some checks are routinely made to the condition of the flare. The DAQ could not see on the form where the monthly EPA Method 22 check has been performed. 28 The following records are kept: VOC control device efficiency, for life of the equipment Manufacturer operating and maintenance instructions for VOC control devices, for life of the equipment AVO inspections of the VOC control device(s), associated equipment and any repairs, for 3 years. [R307-508-4] In Compliance. The recordkeeping procedures of the operator, concerning these requirements, are found to be orderly and complete. 29 Leak Detection and Repair 30 The source has an emissions monitoring plan. [R307-509-4(1)(a)] In Compliance. A field wide plan was produced to the DAQ for review during the records portion of the evaluation. The DAQ is not pursuing compliance action if this has not been prepared for each individual source. 31 The monitoring plan addresses difficult-to-monitor and unsafe-to-monitor components. [R307-509-4(1)(b)] In Compliance. The plan does. 32 If emissions control is required, monitoring surveys are conducted to observe each fugitive emissions component for fugitive emissions. [R307-509-4(1)(c)] In Compliance. Consistent with the Emissions Monitoring Plan requirement for compliance with NSPS (60) OOOO. 33 Initial monitoring surveys were within 60 days after startup for new sources. Subsequent surveys are semi-annual for regular components, annual for difficult-to-monitor components, and as required by the monitoring plan for unsafe-to-monitor components. [R307-509-4(1)(d)] In Compliance. The operator supplied LDAR inspection forms for review. These inspections were conducted twice a year, no sooner than 4 months apart and no later than 7 months apart as required by 40 CFR (60) OOOO and this requirement. 34 Monitoring surveys are done with OGI equipment or by Method 21. [R307-509-4(1)(e)] In Compliance. The operator uses a Flir GF 320 OGI camera. 5 35 Fugitive leaks are repaired within 15 days unless infeasible, unsafe, etc., as stated in the rule, which require repair within 24 months per the rule. [R307-509-4(1)(f)] In Compliance. The most recent LDAR survey found a leaking control component on October 11, 2023. The valve was rebuilt on October 15, 2023, within the time period required here. 36 Resurvey of the repaired components is completed within 30 days. [R307-509-4(1)(g)] In Compliance. 37 The following records are kept: The emissions monitoring plan, for life of the site LDAR inspections, repairs and resurveys, for 3 years [R307-509-5] In Compliance. The recordkeeping procedures of the operator, concerning these requirements, are found to be orderly and complete. 38 Natural Gas Engines 39 Engines subject to R307-510 (does not have an AO, began operations, installed or modified after January 1, 2016) meet the following limits: Maximum Engine hp Emission Standards in (g/hp-hr) NOx CO VOC HC+NOx >25 hp and < 100 hp - 4.85 - 2.83 >100 hp 1.0 2.0 0.7 - [R307-510-4(1)] In Compliance. Stack testing was completed on the Cat engine installed on the gas lift compressor and emissions were within the limits established by NSPS (60) JJJJ. 40 Affected engines are certified or have an initial performance test per 40 CFR 60.4244. [R307-510-4(2)] In Compliance. The Cat engine on the compressor is tested. See copy attached. The Doosan engine on the generator is known to the DAQ as a certified compliant engine, though no certificate has been presented. 41 Affected engine exhaust vents are vertical and unrestricted. Stacks are 8' or greater if the site horsepower rating is 151 to 305 Stacks are 10' or greater if the site horse power rating is 306 or greater. [R307-510-4(3)] In Compliance. Exhaust stack vents vertically. 42 Engine certifications or initial performance tests required are kept for the life of the engine at the source. [R307-510-5] In Compliance. The Cat engine on the compressor is tested. See copy attached. The Doosan engine on the generator is known to the DAQ as a certified compliant engine, though no certificate has been presented. 6 43 Associated Gas Flaring 44 Associated gas is routed to a process unit for combustion, a sales pipeline or an operating VOC control device, except in an emergency. An emergency release is unanticipated, temporary, infrequent, unavoidable, =24 hrs. and is not due to operator negligence. Low pressure gas from working loss, breathing loss and oil flashing is not "associated gas". [R307-511-4(1)] In Compliance. Associated gas is gathered to a sales line. 45 The following records are kept: The time and date of event Volume of emissions Any corrective action taken for 3 years. [R307-511-5(1)(a)(b)] Out of Compliance. UWO was unable to provide any records in support of compliance with this rule and was unwilling to provide a statement of compliance. It appeared by interview that events where venting does occur are not being tracked or reported. The DAQ asked for a letter stating that there were no events where associated gas are vented to the atmosphere. This request was refused. UWO and the DAQ are considering this requirement in light of the Joint Consent Decree in progress. 46 Visible Emissions 47 Visible emissions, except for unavoidable irregularities that do not exceed three minutes, are within the following opacity limits: Installations constructed on or before 4/25/1971 40% Installations constructed after 4/25/1971 20% Gasoline engines 0% Diesel engines manufactured after 1/1/1973 20% Diesel engines manufactured before 1/1/1973 40% Note: Required VOC control devices shall have no visible emissions per R307-508-3. [R307-201-3] In Compliance. No visible emissions were detected. 55 Emission Inventory: 56 An emissions inventory has been submitted within the past three years. [R307-150-9(1)] In Compliance. The operator submitted for the 2020 emissions inventory. Applicable Federal Regulations: 57 NSPS (Part 60) OOOOa: Standards of Performance for Crude Oil and Natural Gas Facilities for which Construction, Modification or Reconstruction Commenced After September 18, 2015 [40 CFR 60 Subpart OOOOa] Out of Compliance. This source has an Approval Order from the State of Utah with legal and enforceable limits. This source is then exempt from OOOOa for the collection of fugitive emissions components. A monitoring, repair, and record keeping program is in place that would satisfy the requirements of 40 CFR (60) OOOOa for the collection of fugitive emissions components, closed vent system, and storage vessel facilities except that UWO refused to provide evidence that an engineering design assessment of the vapor control system was conducted and certified as required in this subpart (60.5411a(d)(1)). There are not other affected facilities installed. Considering the negotiations in progress with the USEPA and State of Utah on the Joint Consent Decree, UWO declines to provide an engineering design assessment for this source required by this subpart. 7 59 NSPS (Part 60) JJJJ: Standards of Performance for Stationary Spark Ignition Internal Combustion Engines [40 CFR 60 Subpart JJJJ] Out of Compliance. The engines at this source have been performance tested and the emissions were within the limits allowed in this subpart. The recordkeeping and maintenance provisions are not met. Maintenance records were not supplied and assumed not kept by UWO. One engine powers a compressor for artificial lift and the other and the electric generator are part of a paid service. Maintenance is likely performed by the service providers. PREVIOUS ENFORCEMENT ACTIONS: No enforcement actions within the past five years. COMPLIANCE STATUS & RECOMMENDATIONS: Not In Compliance – UWO was unable or unwilling to provide records for several regulations evaluated both State of Utah Rules and Applicable Federal Rules. In almost every case, UWO is refusing to provide the DAQ with the documents needed for proper evaluation due to considerations arising from the negotiations in progress, with the State of Utah and the US EPA on the Joint Consent Decree in progress. The DAQ recommends a Compliance Advisory be submitted to the USEPA for potential inclusion in the Joint Consent Decree being negotiated at this time. RECOMMENDATION FOR NEXT INSPECTION: The DAQ has no recommendations for the next inspector other than what are customary. ATTACHMENTS: Stack test UDAQ Source Test Report CH4-Finley Operating, LLC RP27S Battery H6UB & H8UB, Skoufos Tribal Battery 13-14 Facility Uintah County, Utah October 13, 2021 Federal Regulation: EPA 40 CFR 60, Subpart JJJJ Engine: Cummins KTA19GC SN: 37276975 Unit ID: RP 27 S Prepared By: Oasis Emission Consultants, Inc. 2730 Commercial Way Rock Springs, WY 82901 October 22, 2021 Mr. Jason W. Lachance CH4-Finley Operating, LLC 978 Crescent Road Roosevelt, UT 84066 Dear Mr. Lachance: Re: Engine Emission Testing For CH4-Finley Operating, LLC, RP27S Battery H6UB & H8UB, Skoufos Tribal Battery 13-14 Facility, Unit RP 27 S, EPA 40 CFR 60, Subpart JJJJ. Oasis Emission Consultants, Inc. was requested to perform an annual engine emission test on a Cummins KTA19GC rich burn engine (EPA 40 CFR 60, Subpart JJJJ) located in Uintah County, Utah. Emission Levels The average recorded levels were found to comply with emission limits stipulated by EPA 40 CFR 60, Subpart JJJJ, as shown in the attached report and summarized below. Emission Unit Avg NOx Permit NOx Avg CO Permit CO Avg NMNEHC* Permit VOC g/bhp-hr 0.43 1.0 0.14 2.0 0.03 0.7 *VOC levels reported as NMNEHC C3. Catalyst Parameters (Averaged Over 3 Test Runs) Inlet Temp (deg F)DP (in H2O) 1177 N/A Engine Load (Averaged Over 3 Test Runs) BHP % Load 286.3 75.3 Testing Protocol The attached report was generated using an extractive FTIR system using methodologies as required by EPA 40 CFR 60(A) Methods 1 and 19 & EPA 40 CFR 63(A), Method 320 and/or ASTM D 6348-03, as well as ASTM D6522-00(2005). Quality Assurance Oasis has performed a full review of the raw data and calculated results in this report. Any errors we have encountered have been listed in the body of this report. After performing the review, we are confident that this engine has met the requirements of EPA 40 CFR 60, Subpart JJJJ. If you have any questions or require further information, please contact the undersigned at (307) 382-3297. Yours truly, Oasis Emission Consultants, Inc. _______________________ _________________________ Cember Crawley Charles A. Chapman Environmental Scientist Manager of Technical Services _________________________ Christopher N. Knott, P.Eng. Director, Engineering & Operations TABLE OF CONTENTS 1.1 INTRODUCTION 2.1 EQUIPMENT UTILIZATION 3.1 DISCUSSION OF TEST RESULTS 3.1.1 SOURCE TEST 1 (NOx, CO & NMNEHC) 3.1.2 SOURCE TEST 2 (NOx, CO & NMNEHC) 3.1.3 SOURCE TEST 3 (NOx, CO & NMNEHC) 4.1 STACK SAMPLING LOCATION 4.2 STACK SAMPLING METHODS & PROCEDURES 5.1 QUALITY ASSURANCE APPENDIX A:NOx, CO & NMNEHC TESTS APPENDIX B:QUALITY ASSURANCE/CALIBRATION DATA APPENDIX C:LOAD APPROXIMATION APPENDIX D:METHOD 19 CALCULATIONS APPENDIX E:FIELD NOTES SOURCE EMISSION TEST REPORT Federal Regulation: EPA 40 CFR 60, Subpart JJJJ Test Performed By:Oasis Emission Consultants, Inc. Facility Name:RP27S Battery H6UB & H8UB, Skoufos Tribal Battery 13-14 Facility Unit RP 27 S Emission Source:Cummins KTA19GC Date of Test:October 13, 2021 Date of Report:October 22, 2021 1.1 Introduction The purpose of this source test was to demonstrate that source emissions from a Cummins KTA19GC engine were below maximum allowable levels specified by EPA 40 CFR 60, Subpart JJJJ. The Cummins KTA19GC engine is a rich burn engine that employs a NSCR Catalytic Convertor to regulate emission levels. Three test runs were performed on October 13, 2021 to analyze NOx, CO & VOC emission levels. Test runs were performed according to methodologies outlined by EPA 40 CFR 60(A) Methods 1 and 19, and in the ASTM D 6348-03 & EPA 40 CFR 63(A), Method 320 Protocol. Effluent exhaust was sampled from the engine through an extractive heated Teflon sample line interconnected to an MKS 2030 FTIR analyzer. Each of the three runs consisted of sixty (60) readings taken at one (1) minute intervals. Test runs were observed by the following individuals: Stephen Pyer, OEC Kary, CH4-Finley Jon, Archrock 2.1 Equipment Utilization The following equipment was used during the tests performed at this facility in conjunction with procedures outlined by EPA 40 CFR 60(A) Methods 1 and 19 & EPA 40 CFR 63(A), Method 320 and/or ASTM D 6348-03, as well as ASTM D6522-00(2005). • (1) MKS MultiGas 2030 FTIR Continuous Gas Analyzer • (1) Laptop Computer for the FTIR Analyzer using MKS MG2000 Software • (1) 75ft or 100ft Heated Teflon Line w/ Heated Sample Probe & Spike Bypass Line • (1) Portable O2/CO2 Analyzer • (5) EPA Protocol G1 Calibration Gas (NOx, CO, C3H8, C2H4 & NO2) The MKS Multigas 2030 FTIR Analyzer was used to measure NOx, CO & NMNEHC on a dry basis. A pre Direct and System calibration measurement was made on compounds of NOx, CO, C3H8 & C2H4. In addition, a post System calibration was made on compounds of NOx, CO, C3H8 & C2H4. Compounds of CO2 & NO2 were measured for the quality assurance spiking requirements of EPA 40 CFR 63(A), Method 320 & ASTM D 6348-03. When a gas sample is introduced in the gas cell, the infrared beam is partially absorbed by the gas species present. The spectral frequencies absorbed and their intensity are due to the atoms associated with the chemical bond and the strength of that bond. The absorption spectrum is unique for each infrared-active gas. The MKS Analyzer measures the absorption spectrum, and its analysis algorithm measures the concentration of each gas using pre-loaded calibrations. The MG2000 software allows for the continuous measurement, display and recording of the sample stream. The MKS Multigas 2030 FTIR Analyzer operated with a spectral resolution of 0.5 cm-1 and a scan time of 30 seconds. The FTIR spectrometer utilizes a multi-pass gas cell with a 5.11 meter effective pathlength. 3.1 Discussion of NOx, CO & NMNEHC Test Results Please refer to Appendix A for the raw NOx, CO & NMNEHC test results. Please refer to Appendix B for a listing of all raw data, calibration error response and calculations performed per ASTM & EPA requirements. Overall the average emission levels complied with all requirements. Testing for NOx, CO & NMNEHC were run concurrently with one another. 3.1.1 Source Test 1: Cummins KTA19GC, NOx, CO & NMNEHC The first test was performed from 8:05 to 9:04 for NOx, CO & NMNEHC. Based on the approximated load of 285.0 bhp, the average NOx and CO levels were found to be 0.46 g/bhp-hr and 0.15 g/bhp-hr respectively, below permitted limitations. The NMNEHC level tested at 0.03 g/bhp-hr, which tested in compliance with current EPA standards. 3.1.2 Source Test 2: Cummins KTA19GC, NOx, CO & NMNEHC The second test was performed from 9:06 to 10:05 for NOx, CO & NMNEHC. Based on the approximated load of 288.8 bhp, the average NOx and CO levels were found to be 0.38 g/bhp-hr and 0.11 g/bhp-hr respectively, below permitted limitations. The NMNEHC level tested at 0.03 g/bhp-hr, which tested in compliance with current EPA standards. 3.1.3 Source Test 3: Cummins KTA19GC, NOx, CO & NMNEHC The third test was performed from 10:07 to 11:06 for NOx, CO & NMNEHC. Based on the approximated load of 285.0 bhp, the average NOx and CO levels were found to be 0.44 g/bhp-hr and 0.16 g/bhp-hr respectively, below permitted limitations. The NMNEHC level tested at 0.03 g/bhp-hr, which tested in compliance with current EPA standards. Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) NMNEHC (ppmvd) NMNEHC (g/bhp-hr) O2 (%) 1 104.45 0.46 57.29 0.15 7.48 0.03 0.0 Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) NMNEHC (ppmvd) NMNEHC (g/bhp-hr) O2 (%) 2 86.51 0.38 39.87 0.11 6.74 0.03 0.0 Test Run NOx (ppmvd) NOx (g/bhp-hr) CO (ppmvd) CO (g/bhp-hr) NMNEHC (ppmvd) NMNEHC (g/bhp-hr) O2 (%) 3 98.70 0.44 59.59 0.16 6.20 0.03 0.0 4.1 Stack Sampling Location The sampling port for moisture, flow, NOx, CO and NMNEHC measurements was approximately 3.0 pipe diameters from the nearest upstream flow disturbance and 1.5 pipe diameters from the nearest downstream disturbance. 4.2 Stack Sampling Methods & Procedures Testing followed EPA 40 CFR 60(A) Methods 1 and 19 & EPA 40 CFR 63(A), Method 320 and/or ASTM D 6348-03, as well as ASTM D6522-00(2005) methodologies per our standard protocol, with no exceptions. 5.1 Quality Assurance CTS procedures were followed according to ASTM requirements for both pre and post testing. Similarly, QA spiking procedures were followed. Analysis of the CO2 exhaust effluent was used to determine the dilution factor. Steady levels of the CO2 were observed and a sufficient duration of time was allowed to elapse for a representative average. The calibration gas was spiked into the effluent stream using a bypass line at approximately 10% of the sampling rate. The dilution factor was obtained from observation of the stack CO2 behavior using the following equation: CO2AVG – CO2SPIKE DF = ------------------------ CO2 AVG Where:CO2AVG = The average undiluted CO2 stack gas concentration of spike measurements CO2SPIKE = The average diluted CO2 stack gas concentration when spiked The sample recovery was then obtained from the following equation: % REC = (Spike MEAS – Stack MEAS)* (1 – DF) --------------------------------------------------------- CS * DF Where:Spike MEAS = The average diluted stack gas concentration when spiked Stack MEAS = The average undiluted stack gas concentration DF = Dilution factor CS = Certified concentration of calibration standards The Sample Recovery average level for NO2 was found to be 84.5%, which was within the allowable tolerance of Method 320 (70% to 130%). A summary of all spiking procedures/results can be found in Appendix B. APPENDIX A NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C 1 92.509535 35.076633 7.537526 17.808879 10-13-2021 8:05:21 2 36.893791 86.970331 9.070840 18.302811 10-13-2021 8:06:21 3 61.275817 131.743065 8.813905 14.931369 10-13-2021 8:07:21 4 161.350592 10.853845 6.803113 15.387685 10-13-2021 8:08:21 5 139.735711 14.544843 6.940262 18.098161 10-13-2021 8:09:21 6 52.680071 129.612405 8.829802 16.460616 10-13-2021 8:10:22 7 169.264985 13.740619 7.604582 17.404556 10-13-2021 8:11:22 8 74.98606 13.829738 6.271275 16.338865 10-13-2021 8:12:22 9 96.099102 48.383529 7.585885 16.870444 10-13-2021 8:13:22 10 39.43263 76.660034 8.312371 17.013484 10-13-2021 8:14:22 11 117.199125 65.561366 8.943035 18.220964 10-13-2021 8:15:22 12 375.111984 7.785211 6.236119 18.66669 10-13-2021 8:16:22 13 29.699697 49.16404 7.016699 16.751281 10-13-2021 8:17:23 14 41.897656 162.842786 8.953695 18.322361 10-13-2021 8:18:23 15 58.416329 21.703529 7.778597 16.737768 10-13-2021 8:19:23 16 70.132759 14.653696 7.696645 18.241384 10-13-2021 8:20:23 17 41.855279 50.785775 7.586255 16.792183 10-13-2021 8:21:23 18 51.591571 154.181813 9.507045 17.824957 10-13-2021 8:22:23 19 549.991212 8.385532 7.289967 17.132358 10-13-2021 8:23:23 20 46.432276 20.558598 6.309775 17.443427 10-13-2021 8:24:24 21 124.120163 14.192157 6.135483 16.188772 10-13-2021 8:25:24 22 28.981075 109.959463 8.375605 17.502995 10-13-2021 8:26:24 23 40.418288 57.144998 8.179426 16.29733 10-13-2021 8:27:24 24 60.684715 18.257882 7.261234 16.946771 10-13-2021 8:28:24 25 45.133883 30.60749 7.770776 18.085447 10-13-2021 8:29:24 26 47.009096 250.005388 9.403948 18.684903 10-13-2021 8:30:24 27 440.034555 11.175936 6.206906 17.992488 10-13-2021 8:31:25 28 25.944085 61.304883 6.352511 15.545636 10-13-2021 8:32:25 29 73.157141 23.898893 6.769465 16.894246 10-13-2021 8:33:25 30 27.991912 189.761106 8.574000 17.219344 10-13-2021 8:34:25 31 166.124386 58.0578 8.170760 17.329709 10-13-2021 8:35:25 32 190.596492 10.323143 6.709971 16.668063 10-13-2021 8:36:25 33 140.842883 8.730425 6.005346 17.0089 10-13-2021 8:37:25 34 31.652125 100.572587 6.823684 16.209099 10-13-2021 8:38:25 35 70.799124 249.163107 9.711172 17.389955 10-13-2021 8:39:26 36 235.369172 12.746998 6.958584 18.662832 10-13-2021 8:40:26 37 159.568116 37.457388 6.672720 17.172073 10-13-2021 8:41:26 38 100.750418 131.828298 7.420517 16.249539 10-13-2021 8:42:26 39 94.070316 18.060061 6.252656 16.85037 10-13-2021 8:43:26 40 33.981889 112.410814 8.110275 17.391044 10-13-2021 8:44:26 41 244.996899 25.889766 7.150724 17.223107 10-13-2021 8:45:26 42 27.156895 166.13294 7.716765 16.534561 10-13-2021 8:46:27 43 86.365821 36.1191 7.048180 17.117387 10-13-2021 8:47:27 44 42.536009 29.357929 7.055434 16.934924 10-13-2021 8:48:27 45 83.750831 47.527422 7.486597 16.763337 10-13-2021 8:49:27 46 76.831477 20.493567 7.553450 17.705012 10-13-2021 8:50:27 47 207.005639 18.877 6.833134 16.833026 10-13-2021 8:51:27 48 64.259895 14.631388 6.411015 18.192898 10-13-2021 8:52:27 49 31.711062 92.045307 7.543462 17.506928 10-13-2021 8:53:28 50 245.229332 41.911304 8.170294 17.696282 10-13-2021 8:54:28 51 80.690114 58.781127 6.901029 17.485785 10-13-2021 8:55:28 52 53.354507 24.561563 7.170848 18.588144 10-13-2021 8:56:28 53 29.024651 63.956352 8.124276 18.101283 10-13-2021 8:57:28 54 44.103422 44.8948 7.859324 18.650766 10-13-2021 8:58:28 55 139.759049 23.565822 7.516003 17.407507 10-13-2021 8:59:28 56 127.048221 9.869288 5.667256 18.016214 10-13-2021 9:00:29 57 56.057685 26.744464 7.309883 19.346667 10-13-2021 9:01:29 58 68.802718 13.086913 6.855594 17.223395 10-13-2021 9:02:29 59 36.679362 25.401813 7.822869 17.8668 10-13-2021 9:03:29 60 78.111398 31.107225 7.376169 17.527597 10-13-2021 9:04:29 AVG 104.45 57.29 7.48 17.33 ppm@15% O2 29.49 16.17 2.11 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.46 0.29 0.15 0.10 0.03 0.02 Calculated Emission Levels CH4-Finley Operating, LLC RP27S Battery H6UB & H8UB, Skoufos Tribal Battery 13-14 Run 1 Record FTIR Measurements Date Time RP 27 S NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C 1 66.66345 14.280485 7.432050 17.060513 10-13-2021 9:06:29 2 64.878226 13.265508 6.156369 17.048116 10-13-2021 9:07:29 3 43.128544 39.116517 6.879829 15.837679 10-13-2021 9:08:30 4 64.062183 17.496406 6.433128 17.112898 10-13-2021 9:09:30 5 69.71895 16.823042 6.934150 17.051213 10-13-2021 9:10:30 6 97.490029 11.145662 6.908675 17.56184 10-13-2021 9:11:30 7 81.121013 17.187089 5.932039 18.932463 10-13-2021 9:12:30 8 47.58889 33.598894 7.137370 16.777854 10-13-2021 9:13:30 9 29.234969 47.962163 7.499709 17.136448 10-13-2021 9:14:30 10 133.367966 17.433383 7.536443 17.458701 10-13-2021 9:15:31 11 69.302642 11.851091 6.726528 16.909655 10-13-2021 9:16:31 12 74.949484 14.016737 7.072239 17.851313 10-13-2021 9:17:31 13 38.923133 27.246503 6.513895 16.585445 10-13-2021 9:18:31 14 69.279345 27.028543 7.361097 16.713553 10-13-2021 9:19:31 15 97.863978 10.665734 5.365044 15.697488 10-13-2021 9:20:31 16 75.444803 12.897246 6.519584 17.187578 10-13-2021 9:21:31 17 35.824985 40.135452 6.672619 15.681978 10-13-2021 9:22:31 18 60.331954 34.535585 7.530054 16.994824 10-13-2021 9:23:32 19 49.363084 24.272697 6.987913 16.803391 10-13-2021 9:24:32 20 72.706031 16.658514 6.552671 16.245062 10-13-2021 9:25:32 21 169.954668 11.19285 5.898490 16.249142 10-13-2021 9:26:32 22 57.42233 119.063161 6.912321 17.349445 10-13-2021 9:27:32 23 171.622824 12.670056 6.034931 17.592729 10-13-2021 9:28:32 24 76.16567 13.217884 5.296797 16.561731 10-13-2021 9:29:32 25 41.756541 30.330761 6.994719 16.634923 10-13-2021 9:30:33 26 41.512222 105.914435 7.193330 15.628527 10-13-2021 9:31:33 27 84.167427 15.164466 6.717132 16.975233 10-13-2021 9:32:33 28 29.642017 55.546694 7.698279 17.214248 10-13-2021 9:33:33 29 274.333869 15.903755 6.261519 16.730111 10-13-2021 9:34:33 30 190.365518 8.371488 5.069811 17.928494 10-13-2021 9:35:33 31 32.861046 160.168218 7.292435 17.101936 10-13-2021 9:36:33 32 53.621363 24.140653 5.525667 16.013764 10-13-2021 9:37:34 33 105.064404 27.876048 6.259226 16.221101 10-13-2021 9:38:34 34 129.719026 47.849768 6.098726 16.88368 10-13-2021 9:39:34 35 56.325011 83.808072 6.994452 16.3433 10-13-2021 9:40:34 36 71.123754 22.206895 5.692764 16.763381 10-13-2021 9:41:34 37 80.824304 73.983576 7.281094 16.818214 10-13-2021 9:42:34 38 174.61725 16.253344 14.155804 44.550589 10-13-2021 9:43:34 39 59.874767 65.430137 7.112729 20.985165 10-13-2021 9:44:35 40 92.36159 34.907638 7.253776 19.03784 10-13-2021 9:45:34 41 154.614173 10.305716 5.564739 17.8119 10-13-2021 9:46:35 42 23.092123 115.640919 7.001285 17.045113 10-13-2021 9:47:35 43 111.385064 53.254304 7.502050 18.207182 10-13-2021 9:48:35 44 37.4393 36.014339 7.218125 17.575883 10-13-2021 9:49:35 45 118.809525 29.247458 6.206735 18.177927 10-13-2021 9:50:35 46 203.412358 11.646833 6.045251 17.369832 10-13-2021 9:51:35 47 47.935327 119.998745 6.198531 16.766926 10-13-2021 9:52:35 48 55.965327 90.990778 8.098385 18.371858 10-13-2021 9:53:36 49 96.922315 14.567927 5.511821 16.508854 10-13-2021 9:54:36 50 194.94545 9.162057 5.598160 17.046374 10-13-2021 9:55:36 51 59.348642 13.833273 6.058629 17.789994 10-13-2021 9:56:36 52 32.901653 30.529687 6.506996 16.738833 10-13-2021 9:57:36 53 44.299456 64.534825 7.293586 16.459283 10-13-2021 9:58:36 54 92.056618 15.648686 6.007161 17.385153 10-13-2021 9:59:36 55 43.560533 18.162841 6.335018 16.769941 10-13-2021 10:00:36 56 64.370491 18.531889 7.123588 17.735562 10-13-2021 10:01:37 57 30.811378 79.190787 6.871045 16.855287 10-13-2021 10:02:37 58 352.828314 66.914389 7.755540 18.973847 10-13-2021 10:03:37 59 59.888094 79.842292 5.127706 17.771745 10-13-2021 10:04:37 60 31.369883 122.682888 6.534467 16.730835 10-13-2021 10:05:37 AVG 86.51 39.87 6.74 17.61 ppm@15% O2 24.42 11.26 1.90 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.38 0.24 0.11 0.07 0.03 0.02 Calculated Emission Levels CH4-Finley Operating, LLC RP27S Battery H6UB & H8UB, Skoufos Tribal Battery 13-14 Run 2 Record FTIR Measurements Date Time RP 27 S NOx Dry (ppm) CO Dry (ppm) NMNEHC C3 Dry (ppm) H2O% (High) 191C 1 86.692344 32.834661 6.244066 16.512775 10-13-2021 10:07:37 2 54.945996 90.581403 6.901929 17.533047 10-13-2021 10:08:38 3 178.252798 10.294622 5.369667 17.04473 10-13-2021 10:09:38 4 73.002305 11.746689 5.181042 15.625421 10-13-2021 10:10:38 5 26.361078 81.381141 6.966079 16.372085 10-13-2021 10:11:38 6 129.303291 27.248668 6.417413 16.921665 10-13-2021 10:12:38 7 36.535162 54.359353 6.703533 16.692862 10-13-2021 10:13:38 8 88.351294 113.070329 7.397916 18.719761 10-13-2021 10:14:38 9 109.015608 11.672159 5.533364 16.749073 10-13-2021 10:15:38 10 159.219723 20.017815 5.211800 16.283399 10-13-2021 10:16:39 11 60.185674 138.873742 6.759054 16.443848 10-13-2021 10:17:39 12 213.415548 32.746218 6.244425 16.971144 10-13-2021 10:18:39 13 156.773171 33.704498 4.030416 15.825049 10-13-2021 10:19:39 14 72.128205 111.028341 5.877095 15.926027 10-13-2021 10:20:39 15 26.914838 52.15831 6.591145 17.54568 10-13-2021 10:21:39 16 65.035658 178.652525 8.299286 17.147087 10-13-2021 10:22:39 17 214.054774 28.831889 5.510358 16.954328 10-13-2021 10:23:40 18 63.185934 28.775241 5.258594 15.863321 10-13-2021 10:24:40 19 69.528175 49.456741 5.938926 16.857069 10-13-2021 10:25:40 20 58.659805 41.759471 5.966422 16.168144 10-13-2021 10:26:40 21 33.337482 76.739106 6.863202 17.147876 10-13-2021 10:27:40 22 201.29707 18.829138 5.724965 15.77202 10-13-2021 10:28:40 23 74.499572 13.611276 4.357011 15.861122 10-13-2021 10:29:40 24 32.07059 60.634456 6.263959 15.492977 10-13-2021 10:30:40 25 38.03339 171.930269 8.116134 17.066484 10-13-2021 10:31:40 26 249.876882 12.315944 5.351232 15.669147 10-13-2021 10:32:41 27 135.243584 13.002011 5.046484 15.490891 10-13-2021 10:33:41 28 35.466106 148.032396 7.010610 15.757477 10-13-2021 10:34:41 29 59.592939 37.389978 6.829068 16.729218 10-13-2021 10:35:41 30 72.143058 40.978617 6.082904 16.477541 10-13-2021 10:36:41 31 52.096912 83.357112 6.656727 15.857434 10-13-2021 10:37:41 32 207.996107 12.738386 5.549008 16.379729 10-13-2021 10:38:41 33 213.453642 7.962636 4.525504 15.52969 10-13-2021 10:39:41 34 27.730516 154.02047 6.884282 17.90534 10-13-2021 10:40:42 35 53.106998 79.543545 7.065728 16.761729 10-13-2021 10:41:42 36 34.953133 44.567276 6.712127 15.625775 10-13-2021 10:42:42 37 413.918832 14.185556 5.888492 16.030483 10-13-2021 10:43:42 38 55.674705 58.648435 4.819809 16.445201 10-13-2021 10:44:42 39 33.31315 108.508123 6.375259 15.552428 10-13-2021 10:45:42 40 40.338398 73.425353 7.032575 16.781994 10-13-2021 10:46:42 41 71.159724 252.081158 7.525337 21.738143 10-13-2021 10:47:42 42 213.863138 11.514342 5.375404 16.98479 10-13-2021 10:48:42 43 53.259271 26.632168 6.264981 18.733851 10-13-2021 10:49:43 44 128.894437 9.896583 4.757188 15.947388 10-13-2021 10:50:43 45 33.973762 28.0896 5.985208 16.396408 10-13-2021 10:51:43 46 49.962109 68.899241 6.591145 18.058992 10-13-2021 10:52:43 47 137.860552 63.696115 7.757136 18.68346 10-13-2021 10:53:43 48 105.877876 17.486301 4.536676 16.306891 10-13-2021 10:54:43 49 52.672595 16.683356 5.912157 15.46527 10-13-2021 10:55:43 50 28.256588 41.552626 6.785232 17.607551 10-13-2021 10:56:43 51 40.343407 109.025934 6.772323 15.917012 10-13-2021 10:57:44 52 234.164346 21.093347 6.498157 17.469578 10-13-2021 10:58:44 53 167.580891 11.083171 5.169965 17.492202 10-13-2021 10:59:44 54 27.009097 46.523113 7.057855 18.195885 10-13-2021 11:00:44 55 41.799195 171.206689 7.153407 16.423801 10-13-2021 11:01:44 56 49.735114 41.416665 7.076833 17.861563 10-13-2021 11:02:44 57 55.090775 45.488204 7.148117 18.361418 10-13-2021 11:03:44 58 34.974276 121.601437 7.010384 15.649972 10-13-2021 11:04:44 59 360.010384 10.501577 5.822290 17.239968 10-13-2021 11:05:45 60 29.93599 81.434028 5.381535 15.515205 10-13-2021 11:06:45 AVG 98.70 59.59 6.20 16.74 ppm@15% O2 27.86 16.82 1.75 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) NMNEHC C3 (g/bhp-hr) NMNEHC C3 (lbs/hr) 0.44 0.27 0.16 0.10 0.03 0.02 Calculated Emission Levels CH4-Finley Operating, LLC RP27S Battery H6UB & H8UB, Skoufos Tribal Battery 13-14 Run 3 Record FTIR Measurements Date Time RP 27 S APPENDIX B Date Time NO 191C span NO2 191C span H2O% (high) 191C Formaldehyde 191C Ethylene 191C TE span Propane 191C span Acetaldehyde 191C span CO ppm 191C (1of2) span CO ppm Dry CO2% 191C NOx Wet NOx Dry NM NE HC C3 10-13-2021 7:47:46 0.100222 0.092654 -0.008301 -0.012711 -0.541144 -0.357164 0.101107 0.155058 0.155046 -0.016367 0.192876 0.192860 -0.007681 10-13-2021 7:47:53 -0.053580 0.193047 0.002372 0.112541 -0.502181 -0.995190 0.197808 -0.286553 -0.286560 0.006698 0.139468 0.139471 0.669473 10-13-2021 7:48:01 0.137034 0.055465 -0.003248 0.036837 -0.215966 -0.452027 -0.889004 0.083419 0.083416 0.000068 0.192499 0.192493 0.015453 10-13-2021 7:48:39 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 10-13-2021 7:48:52 -0.061531 -0.103891 0.004041 -0.110919 -0.158754 -1.581858 -0.479308 -0.035841 -0.035843 0.009447 -0.165422 -0.165428 0.040815 10-13-2021 7:48:59 -0.017490 -0.011077 -0.002182 0.158382 -1.105684 -0.190281 -0.444624 -0.414225 -0.414216 0.007698 -0.028567 -0.028567 0.445610 10-13-2021 7:49:07 0.179886 -0.044147 0.001788 -0.101322 -0.921930 -1.155673 -0.284282 0.087982 0.087984 0.015115 0.135738 0.135741 -0.002973 10-13-2021 7:49:15 -0.198758 -0.064100 -0.003496 -0.133722 0.272019 -0.272483 -0.006131 0.072731 0.072729 0.007635 -0.262858 -0.262849 -0.003596 10-13-2021 7:49:22 0.090238 -0.082469 0.010064 0.060667 -0.619409 0.116596 0.199392 0.073556 0.073563 0.000236 0.007769 0.007770 0.021786 10-13-2021 7:49:29 0.069931 -0.063611 0.002863 0.120408 0.986804 0.283510 -0.469353 -0.061496 -0.061498 0.007063 0.006320 0.006320 0.178679 10-13-2021 7:49:37 -0.106533 -0.100095 0.003660 -0.025972 -0.062198 -0.037991 -0.687185 -0.038045 -0.038047 -0.001413 -0.206628 -0.206636 0.007183 10-13-2021 7:49:45 0.011096 -0.084311 0.011929 0.014126 0.103319 0.205383 0.359029 0.117782 0.117796 0.007947 -0.073215 -0.073223 0.006365 10-13-2021 7:49:52 -0.352452 -0.016106 0.001955 0.082258 -0.562228 -0.232040 0.066630 -0.051024 -0.051025 0.003265 -0.368558 -0.368566 0.186935 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Date Time Ethylene 191C TE 10-13-2021 7:50:14 481.949267 463.789730 479.250819 10-13-2021 7:53:18 93.756556 10-13-2021 7:50:22 494.935635 494.508715 494.799730 10-13-2021 7:53:25 95.635702 10-13-2021 7:50:29 496.072394 495.300360 495.959452 10-13-2021 7:53:33 96.147573 10-13-2021 7:50:37 496.402290 494.057264 496.266490 10-13-2021 7:53:40 97.274113 10-13-2021 7:50:44 498.169461 496.721442 503.154055 10-13-2021 7:53:48 94.985124 10-13-2021 7:50:52 498.134331 496.251923 496.177310 10-13-2021 7:53:55 96.342921 10-13-2021 7:50:59 498.669176 497.901724 503.670501 10-13-2021 7:54:03 95.968125 10-13-2021 7:51:07 496.626208 494.196742 499.190205 10-13-2021 7:54:10 97.688515 10-13-2021 7:51:15 497.981480 496.614985 495.638261 10-13-2021 7:51:22 499.353389 497.173298 498.865986 Date Time NO2 191C span 10-13-2021 7:51:42 133.033567 10-13-2021 7:51:49 142.818672 10-13-2021 7:51:57 143.816198 10-13-2021 7:52:05 144.640142 10-13-2021 7:52:12 146.840690 10-13-2021 7:52:20 147.136199 10-13-2021 7:52:27 147.085594 10-13-2021 7:52:35 148.934868 10-13-2021 7:52:42 146.314197 10-13-2021 7:52:50 148.544252 10-13-2021 7:52:57 149.094818 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Date Time Ethylene 191C TE 10-13-2021 7:54:55 408.559756 385.463201 392.898882 10-13-2021 7:56:16 14.970084 10-13-2021 7:55:02 476.329053 470.383873 474.806447 10-13-2021 7:56:23 80.475986 10-13-2021 7:55:10 477.893046 473.130202 478.188005 10-13-2021 7:56:30 88.401010 10-13-2021 7:55:17 483.579348 475.963199 476.867931 10-13-2021 7:56:38 90.392867 10-13-2021 7:55:25 465.456469 463.116742 462.620877 10-13-2021 7:56:46 91.948308 10-13-2021 7:55:32 493.912521 491.332036 489.992296 10-13-2021 7:56:53 91.343345 10-13-2021 7:55:40 496.797006 493.700676 492.113063 10-13-2021 7:57:01 88.672634 10-13-2021 7:55:47 500.365556 496.314727 500.571610 10-13-2021 7:57:08 94.199628 10-13-2021 7:55:55 499.951845 497.553287 500.576079 10-13-2021 7:57:16 97.386493 Raw Calibration Data BACKGROUND NO2 CAL PRE DIRECT CAL PRE SYSTEM CAL Date Time CO2% 191C NO2 191C span 10-13-2021 8:00:15 11.425945 -0.004482 10-13-2021 8:00:22 11.246345 -0.201979 10-13-2021 8:00:30 11.239266 0.042547 10-13-2021 8:00:37 11.197155 0.018909 10-13-2021 8:00:45 11.270028 0.095444 10-13-2021 8:00:52 10.935790 -0.052011 10-13-2021 8:01:15 10.355722 0.161015 10-13-2021 8:01:22 10.614540 0.142469 10-13-2021 8:01:30 5.502086 16.853612 10-13-2021 8:01:37 4.841212 52.919039 10-13-2021 8:01:45 9.398642 14.841892 10-13-2021 8:01:52 9.723387 14.860437 10-13-2021 8:02:00 9.047523 13.404422 10-13-2021 8:02:07 9.725729 14.059159 10-13-2021 8:02:15 10.064938 11.525447 10-13-2021 8:02:22 9.961723 11.565762 10-13-2021 8:02:30 10.003528 10.764080 10-13-2021 8:02:37 9.590644 10.902259 10-13-2021 8:02:45 9.751257 14.162637 10-13-2021 8:02:52 9.775291 14.142430 10-13-2021 8:03:00 9.881029 13.643873 10-13-2021 8:03:15 9.661007 12.630018 10-13-2021 8:03:23 9.229524 11.690871 10-13-2021 8:03:30 9.256851 11.736568 10-13-2021 8:03:38 9.560527 7.634624 10-13-2021 8:03:45 10.089380 1.259836 10-13-2021 8:03:53 10.450932 0.028942 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Date Time Ethylene 191C TE 10-13-2021 11:11:09 488.861951 482.384026 484.902094 10-13-2021 11:09:35 99.599728 10-13-2021 11:11:17 502.519257 496.896235 496.443724 10-13-2021 11:09:42 98.739518 10-13-2021 11:11:24 500.544267 494.410530 494.321127 10-13-2021 11:09:50 99.147612 10-13-2021 11:11:32 503.705077 498.698558 502.028791 10-13-2021 11:09:57 98.617378 10-13-2021 11:11:39 503.572694 497.731669 497.619702 10-13-2021 11:10:05 98.060552 10-13-2021 11:11:47 503.400327 496.877164 498.110048 10-13-2021 11:10:12 98.451860 10-13-2021 11:11:54 503.269233 497.242371 495.292483 10-13-2021 11:10:20 99.275670 10-13-2021 11:12:02 501.646513 495.822473 496.067024 10-13-2021 11:12:09 508.300565 501.275828 504.453809 10-13-2021 11:12:17 506.202757 500.315206 504.165671 POST SYSTEM CAL SAMPLE SPIKE RECOVERY PRE TEST 1 148.7 10.9 0.1 9.8 12.6 0.100 84.5% Sensor Analyzer Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Error (%)Error (%) NOx 497.2 503.9 -0.1 -1.33 -0.01 CO 499.4 501.1 0.0 -0.35 0.00 Propane 498.9 501.6 -0.3 -0.55 -0.07 Ethylene 97.7 100.0 -0.2 -2.31 -0.19 Sensor System Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Recovery (%)Error (%) NOx 497.6 503.9 -0.1 -1.26 -0.01 CO 500.0 501.1 0.0 -0.23 0.00 Propane 500.6 501.6 -0.3 -0.20 -0.07 Ethylene*97.4 100.0 -0.2 -2.61 -0.19 Sensor Analyzer Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Error (%)Error (%) NOx 500.3 503.9 0.2 -0.71 0.03 CO 506.2 501.1 0.0 1.02 -0.01 Propane 504.2 501.6 -0.9 0.51 -0.17 Ethylene 99.3 100.0 0.5 -0.72 0.47 *CTS Scans are conducted with Ethylene through the sample line PRE DIRECT CAL POST SYSTEM CAL % Recovery NO2 Stack NO2 Concentration Stack + Spike CO2 Concentration Stack + NO2 Concentration DF Calculated PRE SYSTEM CAL FTIR QA/QC SUMMARY NO2 SAMPLE RECOVERY CALCULATIONS Period Spike #Concentration of NO2 Cylinder Stack CO2 Concentration CERTIFICATE OF ANALYSIS Grade of Product: EPA Protocol Part Number:E05NI99E15A0000 Reference Number:153-401944513-1 Cylinder Number:EB0067534 Cylinder Volume:144.4 CF Laboratory:124 - Tooele (SAP) - UT Cylinder Pressure:2015 PSIG PGVP Number:B72020 Valve Outlet:660 Gas Code:CH4,CO,NO,NOX,PPN,BALN Certification Date:Nov 05, 2020 Expiration Date:Nov 05, 2028 Certification performed in accordance with “EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)” document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. ANALYTICAL RESULTS Component Requested Actual Protocol Total Relative Assay Concentration Concentration Method Uncertainty Dates NOX 500.0 PPM 504.0 PPM G1 +/- 0.6% NIST Traceable 10/29/2020, 11/05/2020 CARBON MONOXIDE 500.0 PPM 501.1 PPM G1 +/- 0.7% NIST Traceable 10/29/2020 METHANE 500.0 PPM 502.2 PPM G1 +/- 0.7% NIST Traceable 10/29/2020 NITRIC OXIDE 500.0 PPM 503.9 PPM G1 +/- 0.6% NIST Traceable 10/29/2020, 11/05/2020 PROPANE 500.0 PPM 501.6 PPM G1 +/- 0.7% NIST Traceable 11/04/2020 NITROGEN Balance CALIBRATION STANDARDS Type Lot ID Cylinder No Concentration Uncertainty Expiration Date NTRM 13010136 KAL003851 495.4 PPM CARBON MONOXIDE/NITROGEN 0.6%Jul 03, 2024 PRM 12386 D685025 9.91 PPM NITROGEN DIOXIDE/AIR 2.0%Feb 20, 2020 NTRM 16060413 CC471321 500.5 PPM METHANE/AIR 0.6%Nov 20, 2021 NTRM 15010133 KAL004417 494.6 PPM NITRIC OXIDE/NITROGEN 0.5%Sep 01, 2021 GMIS 401203436105 CC513880 4.732 PPM NITROGEN DIOXIDE/NITROGEN 2.1%May 02, 2022 NTRM 01010323 K012489 499.3 PPM PROPANE/AIR 0.6%Jul 02, 2024 The SRM, PRM or RGM noted above is only in reference to the GMIS used in the assay and not part of the analysis. ANALYTICAL EQUIPMENT Instrument/Make/Model Analytical Principle Last Multipoint Calibration Nicolet 6700 AMP0900119 CO MCO FTIR Oct 07, 2020 Nicolet 6700 AMP0900119 CH4 M1CH4 FTIR Oct 02, 2020 Nicolet 6700 AMP0900119 NO MNO FTIR Oct 21, 2020 Nicolet 6700 AMP0900119 NO2 impurity FTIR NO2 impurity Oct 21, 2020 MKS FTIR C3H8 018143349 FTIR Nov 04, 2020 Triad Data Available Upon Request Airgas Specialty Gases Airgas USA, LLC 525 North Industrial Loop Road Tooele, UT 84074 Airgas.com Signature on file Approved for Release Page 1 of 153-401944513-1 CERTIFICATE OF ANALYSIS Grade of Product: EPA Protocol Part Number:E02NI99E15W0051 Reference Number:153-401964426-1 Cylinder Number:CC510365 Cylinder Volume:144.0 CF Laboratory:124 - Tooele (SAP) - UT Cylinder Pressure:2015 PSIG PGVP Number:B72020 Valve Outlet:660 Gas Code:NO2,BALN Certification Date:Dec 02, 2020 Expiration Date:Dec 02, 2023 Certification performed in accordance with “EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)” document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. ANALYTICAL RESULTS Component Requested Actual Protocol Total Relative Assay Concentration Concentration Method Uncertainty Dates NITROGEN DIOXIDE 150.0 PPM 148.7 PPM G1 +/- 2.0% NIST Traceable 11/23/2020, 12/02/2020 NITROGEN Balance CALIBRATION STANDARDS Type Lot ID Cylinder No Concentration Uncertainty Expiration Date GMIS 401424910103 CC506132 95.12 PPM NITROGEN DIOXIDE/NITROGEN 1.1%Feb 07, 2023 PRM 12389 D685050 99.0 PPM NITROGEN DIOXIDE/NITROGEN 1.0%Feb 19, 2020 The SRM, PRM or RGM noted above is only in reference to the GMIS used in the assay and not part of the analysis. ANALYTICAL EQUIPMENT Instrument/Make/Model Analytical Principle Last Multipoint Calibration MKS FTIR NO2 018143349 FTIR Nov 30, 2020 Triad Data Available Upon Request PERMANENT NOTES:OXYGEN ADDED TO MAINTAIN STABILITY Airgas Specialty Gases Airgas USA, LLC 525 North Industrial Loop Road Tooele, UT 84074 Airgas.com Signature on file Approved for Release Page 1 of 153-401964426-1 CERTIFICATE OF ANALYSIS Grade of Product: PRIMARY STANDARD Part Number:X02NI99P15AD524 Reference Number:153-401944566-1 Cylinder Number:CC20974 Cylinder Volume:144.4 CF Laboratory:124 - Tooele (SAP) - UT Cylinder Pressure:2015 PSIG Analysis Date:Oct 26, 2020 Valve Outlet:350 Lot Number:153-401944566-1 Expiration Date:Oct 26, 2023 Primary Standard Gas Mixtures are traceable to N.I.S.T. weights and/or N.I.S.T. Gas Mixture reference materials. ANALYTICAL RESULTS Component Req Conc Actual Concentration Analytical (Mole %)Uncertainty ETHYLENE 100.0 PPM 100.0 PPM +/- 1% NITROGEN Balance Airgas Specialty Gases Airgas USA, LLC 525 North Industrial Loop Road Tooele, UT 84074 Airgas.com Signature on file Approved for Release Page 1 of 153-401944566-1 CH4-Finley – RP27S Battery H6UB & H8UB, Skoufos Tribal Battery 13-14 10-13-2021 CH4-Finley – RP27S Battery H6UB & H8UB, Skoufos Tribal Battery 13-14 10-13-2021 CH4-Finley – RP27S Battery H6UB & H8UB, Skoufos Tribal Battery 13-14 10-13-2021 Instrument Resolution – FWHH – 0.4960 cm-1 which is < 0.55 cm-1 (therefore meets ASTM) Water Frequency – Freq – 3920.0914 cm-1 which is +/- 0.075 of 3920.0952 cm-1 (therefore meets ASTM) Please note: FWHH is the Full Width at Half Height of the resolution. The frequency position is only calculating the center line for one water line in the spectrum. MKS uses 3920.0952 cm-1 since it is a single water line. Spectrum CO NO NO2 Formaldehyde Propane CH4-FINLEY RP 27 S 10-13-21_000005.LAB -0.04 -0.06 -0.10 -0.11 -1.58 CH4-FINLEY RP 27 S 10-13-21_000006.LAB -0.41 -0.02 -0.01 0.16 -0.19 CH4-FINLEY RP 27 S 10-13-21_000007.LAB 0.09 0.18 -0.04 -0.10 -1.16 CH4-FINLEY RP 27 S 10-13-21_000008.LAB 0.07 -0.20 -0.06 -0.13 -0.27 CH4-FINLEY RP 27 S 10-13-21_000009.LAB 0.07 0.09 -0.08 0.06 0.12 CH4-FINLEY RP 27 S 10-13-21_000010.LAB -0.06 0.07 -0.06 0.12 0.28 CH4-FINLEY RP 27 S 10-13-21_000011.LAB -0.04 -0.11 -0.10 -0.03 -0.04 CH4-FINLEY RP 27 S 10-13-21_000012.LAB 0.12 0.01 -0.08 0.01 0.21 Noise Equivalent Absorbance (Standard Deviation)0.16 0.11 0.03 0.10 0.63 MDC #2 0.48 0.34 0.09 0.31 1.90 CO/NO/NO2/Formaldehyde/Propane FTIR Instrument Noise-Limited Minimum Detectable Concentration - MDC#2 Noise Equivalent Absorbance Data APPENDIX C Test Run Load %Site Rated Load, bhp Load Approx., bhp 1 75 380 285.0 2 76 380 288.8 3 75 380 285.0 Engine Load Approximation based on Panel Levels APPENDIX D Test Run Fd Factor BSFC Approx. BHP Avg O2 % NOx ppmvd NOx g/bhp-hr NOx lbs/hr CO ppmvd CO g/bhp-hr CO lbs/hr NMNEHC ppmvd NMNEHC g/bhp-hr NMNEHC lbs/hr Moisture Content % 1 8710 9400 285.0 0.0 104.45 0.46 0.29 57.29 0.15 0.10 7.48 0.03 0.02 17.33 2 8710 9400 288.8 0.0 86.51 0.38 0.24 39.87 0.11 0.07 6.74 0.03 0.02 17.61 3 8710 9400 285.0 0.0 98.70 0.44 0.27 59.59 0.16 0.10 6.20 0.03 0.02 16.74 286.3 0.0 96.56 0.43 0.27 52.25 0.14 0.09 6.81 0.03 0.02 17.23Average Levels EPA Method 19 Calculations APPENDIX E FTIR Eog,ne Test Sheet T t • 1• • -­ -­ Coal'"'''''''"".!Ie' 1... '4 . '00"", '-y.... ­ • [1I00C!>lO £(I(l('f' ...,. , '" CO'~5=. E!lCOll1~ c~", ~ . ~, , • • r .... ••• " • _.