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HomeMy WebLinkAboutDSHW-2018-005932 - 0901a0688085cb3bsQG/VSQG COMPLIANCE ASSISTANCE VISIT WASTE MANAGEI"ITNT d RAOIATION CONTROL Date of Visit: Facility Name: Address: County: Contact Person: Phone Number: EPA ID # (if applicable) Generator Status: Number of Employees: Weather Conditions: Arrival / Departure Time: Report Prepared By: Names of lnspectors: LHD Notifications / Date: Latitude / Longitude: June 12,2018 SealMaster Utah 6778 West 2100 South West Valley City, UT 84128 Salt Lake County John Moody, Vice President, SealMaster (8Or) 2s2-8996 None VSQG 6 Mostly Sunny, 65oF 10:25 AM / 1 1:30 AM Denny Schantz Denny Schantz, DWMRC Jon Parry, DWMRC John Hoggan, Salt Lake County Health Salt Lake County Task Force Meeting, June 6, 2018 40.7 2021 9, -I 12.05321 | Facility Description/Activities : The facility is a franchise operation of SealMaster, which has nationwide business locations. The facility property was formerly owned by A-1 Auto Parts, when it was purchased by SealMaster Utah in the fall of 2016. SealMaster Utah conducted renovations of the property and facilities, and fully opened for business in January 2017 . SealMaster is a global supplier of pavement maintenance supplies and equipment, and the West Valley City facility consists of a manufacturing plant, distribution center and retail showroom, and is intended to serve the entire state of Utah. The facility distributes a full Page I of7 SQG/CESQG COMPLIANCE ASSISTANCE VISIT line of related sealing and asphalt conditioning products; however, the manufacturing operations conducted at the site are limited to the production of the standard pavement sealer and polymer-modified pavement sealer products only. The main indoor facility building consists of the following general sections, from southernmost to northernmost: o A showroom and reception area, where products and equipment are displayed.o Administrative areas, with offices and a small product QA laboratory.o A warehouse area for stocks of distributed products and general supplies.o A production area, where feedstock products are stored and mixing/blending equipment used to produce and store the pavement sealer products. Outside of the main facility building, generally to the north, is a very large yard area. Additional items of note in the outside yard area include the following:o Just outside the northwest side of the main building are two, double-walled asphalt storage tanks and a limestone storage silo.o Outside the west side of the building, near the west property boundary are manway access locations to two, underground oil/water separator units.. Approximately 100 feet north of the oil/water separator manway access points are two adjacent concretelined impoundments, into which washout residues (water is the washout medium) from bulk pavement sealer tank vessels are directed for drying. Mr. Moody referred to these as "retention basins".o Further north and slightly east (50 yards, estimated) of the "retention basins" is a concrete-walled, three-partition dry bulk material pile storage area that contains bays that were being used for (1) the dried washout residues, which are removed from the "retention basin", (2) Gravel from prior landscaping, (3) Dirt from prior landscaping.o Additionally, in areas generally north of the main building, the facility stages large bulk product mobile tank trailers, and other equipment that serves to transport products to, or apply products, at customer sites. The impetus for the site visit came as the result of Salt Lake County Health approaching DWMRC representatives at the June 6,2018 Salt Lake County Environmental Crimes Task Force Meeting about some alleged reported activities at the SealMaster facility, from a source that was not identified. Based upon the information provided by Salt Lake County Health personnel, DWMRC representatives agreed to conduct a site visit to SealMaster, which was coordinated with Salt Lake County Health. At approximately 10:25 AM, DWMRC inspectors arrived and presented credentials to Charles Tea, Account Consultant of SealMaster Utah. Mr. Tea contacted the senior site person, John Moody, Vice President of SealMaster Utah by cell phone, and Mr. Moody arrived to meet the inspectors a short time later. Mr. Moody granted access to the inspectors, and offered to give a full site walkabout. The walkabout included a tour of the main inside building, followed by areas of interest outside the main building Page2 of7 (primarily to the west and north side areas of the outside yard). Mr. Moody explained the general process of manufacture of the pavement sealer (and polymer-modified pavement sealer). The manufacturing area consists of multi-level storage racks containing totes of feedstock materials, and other feedstock materials, which are blended and mixed with asphalt to produce the pavement sealer products that are ultimately delivered to customer locations for application. SealMaster personnel later provided copies of SDS sheets for "MasterSeal Pavement Sealer", and "Polymer Modified MasterSeal Ultra Blend Sealer", which are the products manufactured. Both products contain asphalt, limestone, kaolin, and bentonite clays. The polymer-modified product also contains quartz. Product quality information presented during the inspection indicated that pH of these products was 10.1. SDS sheets also indicate that the product, as mixed is not a RCRA hazardous waste, and is non-flammable. Mr. Moody showed the inspectors the location of the manway accesses to the underground oil/water separators, and explained that the wastewater, after oil separation, is directed to the POTW. He then showed the inspectors two concrete-lined basins to the north of the oil/water separators access location, which he referred to as "retention basins", and explained that these areas were used to contain mobile bulk tank washout residues from customer-supplied bulk tank trailers. Water is used for washout of the bulk tanks, and the removed residues are put into the retention basins for drying. After the residues have dried, they are transferred to a three-partition storage bay in a different location that contains the dried residues in a pile. Periodically, (Mr. Moody estimated about one bulk transport load per year) the residues are loaded and transported to a landfill. During the inspection, the southern retention basin was collecting active washout residues for drying, and the northern portion was dry and contained some residue material that had not yet been moved to the three-partition storage bay. The southern basin contained significant liquid, but no appreciable VOC odors were noticed to be volatilizing from the residues. The dry residues in the three-partition bay were observed, and appeared to be essentially dry, with no liquids observed, and the material was slightly flexible, similar, but more rigid than tire rubber. The inspection team then returned to the showroom area for additional questions, and SealMaster personnel provided SDS sheets for the pavement sealer products. They also displayed a copy of a stormwater discharge permit (#T20160369, West Valley City Public Works). They could not immediately locate a copy of the industrial wastewater discharge permit, but stated that it was with the POTW. The facility stated that it did generate small quantities of used oil periodically (equipment maintenance), and utilized LED lighting. It was suggested that the facility might consider having the sealer tank washout residues analyzed for RCRA metals, RCRA volatiles and RCRA semivolatiles, for the purposes of more definitively characterizing the sealer tank washout residues. The inspection team thanked SealMaster personnel for their participation, and then departed the site at approximately I l:30 AM. Page 3 of 7 Findings: Although the pavement sealer tank washout residue management methods did not appear to violate any hazardous waste regulations, there could possibly be regulatory concerns arising from the use of the "retention basins" (which were, in actuality, evaporation basins used to dry the material out prior to disposal as a solid waste). Assistance Provided: Inspectors provided SealMaster personnel with a copy of the Waste Management & Radiation Control "Small Business Assistance Program" package, and explained that the package included helpful information for complying in circumstances in which they could generate a hazardous waste in the future. The suggestion was also made that SealMaster should consider performing charactertzation testing (RCRA-regulated metals, RCRA-regulated volatiles, and RCRA-regulated semivolatiles, being of primary concern) on the sealer tank washout residues, for the purpose of being able to demonstrate by analysis that the material is not a characteristic hazardous waste. Follow-up Actions: There was no generated hazardous waste observed during the inspection, and the facility appeared to be in compliance with requirements at the time of the inspection. No additional DWMRC follow-up actions are believed to be necessary at this time. Information from the inspection was provided by email to Woody Campbell, of DWQ, for an assessment of any potential concerns arising from the inspection observations. Inspection Photos: ,W3" EW$ , n0:g Photo 1: Underground Oil/lVater Separator boundary of property, looking north) Pase 4 of 7 AccessMutwcty'Locations (western , Jo s onud uouradsul ary {o auu rc flo paup 3u1aq sanprsar fioqsDw Iury ralDas ruautatnd Sutuloquoc '{.1tadotd lo aprs uJa$au 3uo7n ,,utsDg uouuapy,, lfiog :€ olorld $paLluou-quou Sutqooy'Sutppnq urcu {otatuor lsauq1tou lo aplsruo syuDJ aSotolg t1nqdsy puD olls a7uolg auo$aur.I :Z oloqd luDl JaI0as.{"! $aA LIflos aqt sprDwot 3ut4oo1 {tp Sututoluot 'K1tadoil {o aprs uJa$?u 3uo1o -r'- 'sanptsat noqsDlr luDI Dpas gauatod ,.u!sog uorluapa,, Qto67 :? oloqd ,.*,i,'w#t** on eastern Signature and Date:A+,4.e*2 6/13/2018 Attachments: 1. SDS for "MasterSeal Pavement Sealer"2. SDS for "Polymer Modified MasterSeal Ultra Blend Sealer', @ Jl' MasterSeal Pavement Sealer SDS.pdf q Polymer Modified MasterSeal Ultra Blend Sealer SDS.pdf PageT of 7 lssuing Date 23-June-2O14 Revision Date 29-July-2015 SAFETY DATA SHEET Revision Number 'l Recommended Use of the Chemlcal and Restrictions on Use GHS Product ldentafier Produc{ Name: Other Means of ldentification Product Gode(s): Synonyms Recommended Use: Uses Advised Againstr Suoolie/s Details Supplier Address SealMaster Locations Nationwide www.sealmaster. net 1-800-341-7325 Emerqencv Teleohone Number Emergency Telephone Number ilaste6eal Pavem€nt Sealer si010 None No lnformation Available No lnformation Available Manufacturer Address SealMaster Locations Nationwide www.sealmaster. net 1-800-341-7325 Chemtrec 1-800-424-9300 Classification This chemical is not considered hazardous according to the OSHA Hazard Communication Standard 2012 (29 CFR 1910.1200). GHS Label Elements, lncludino Precautlonary StatemenG Emergency Overview Signal Word Warning rHarmful if swallowed .May cause skin irritation State:Odor: -- Page 1 Precautionary Statements Prevention General Advice Storage Disposal Hazard Not Otherwise Classified (HNOC) May cause initation of respiratory tract. Contact with eyes may cause initation. May cause initation. Ingestion may cause stomach discomfort. Inhalation: Eye Gontac{: Skln Contact: Ingestion: oNone. Keep container tightly closed .Dispose of material/containers in accordance with the appropriate state, regional, or local regulations. Not Chemical Name CAS Number Weiqht %Trade Secret Limestone 1317-65-3 20-4,0 Asohah ao52424 2o.4,O Kaolin 1332-58-7 <10 Bentonite 1302-78.9 <10 *The exact percentage of composition has been withheld as a trade secret. Descriotion of Necessarv Firct-Aid teasures Eye Contact Skin Gontact lnhalation Ingestlon Rinse thoroughly with plenty of water, also under the eyelids. lf symptoms persist, call a physician. Wash off immediately with soap and plenty of water. ln the case of skin initation or allergic reactions, see a physician. Move to fresh air. lf symptoms persist, call a physician. Drink plenty of water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Consult a physician if necessary. Most lmoortant Symptoms/Effec{s. Acute and Delaved Most lmportant Symptoma/Effects No information available Indication of lmmediate Medical Attention and Special Treatment Needed. lf Necessarv Notos to Physician Treat Symptomatically. May cause sensitization by skin contact. Suitable Extinouishino tledia Carbon Dioide (COz). Dry Chemical. Foam. Water Fog. Unsuitable Extinguishing iledia CAUTION: Use of water spray when fighting fire may be inefficient. Soecific Hazards Arisino from the Chemical No information available Exolosion Data Sensltivity to ilechanical lmpact Sensitivity to Static Discharge Protective Eouioment and Precautions for Firefiohters As in any fire, wear self-contained breathing apparatus pressure- demand MSHA/NIOSH (approved or equivalent) and full protective gear. None None Page2 Perconal Precautons. Protectlve Eoulpment. and Emeroencv Procedures Personal Precautions: Environmental Precautions Environmental Precautions: llethods and llaterials for Contalnment and Cleanino Uo Method3 for Containment: Methods for Cleaning Up: Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Use personal protective equipment. See Section 12 for additional Ecological Information Prevent further leakage or spillage if safe to do so. Dam up. Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. Clean contaminated surface thoroughly. Precautions for Safe Handlino Handling: Condltions for Safe Storaoe. Includlno Anv lncomoatibilities Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes, and clothing. Wear personal protective equipment. Avoid breathing vapors or mists. Do not eat, drink, or smoke when using this product. Wash thoroughly after handling. Storage: lncompatible Products: Keep container tightly closed Strong oxidizing agents. Acids. Control Parameters Exposure Guidelines Ghemical Name ACGIH TLV OSHA PEL NIOSH IOLH Limestone 1317-6S3 TWA: 15mg/m" TWA: 5 mg/m3 (vacated) TWA: 15 mg/m3 (vacated) TWA: 5 mo/m3 TWA: 5 mg/m3 respirable dust TWA 10 mg/m3 total dust Asphalt 8052424 TWA: 0.5 mg/m3 benzene soluble aerosol fume, inhalable fraction Ceiling: 5 mg/m3 fume 15 min. Kaolin 1332-58-7 TWA:'15 mg/m3 total dust TWA: 5 mg/m3 respirable fraction (vacated) TWA: 10 mg/m3 total dust (vacated) TWA 5 mg/m3 resoirable fraction TWA: 15 mg/m" total dust TWA: 5 mg/m3 respirable dust Bentonite 1302-78-9 TWA 1 mg/m3 respirable fraction Aoorooriate Enqineerinq Gontrole Engineering ileasures:Showers Eyewash Stations Ventilation Systems Indivldual Protecllon Measures. such as Personal Protective Eouioment Eye/Face Protection: Skin and Body Protection: Respiratory Protec{ion: Hygiene Measures: lf splashes are likely to occur, wear: Safety glasses with side shields. lmpervious gloves. No protective equipment is needed under normal use conditions. lf exposure limits are exceeded or initation is experienced, NIOSH/MSHA approved respiratory protection should De wom. Handle in accordance with good industrial hygiene and safety practice. Page 3 Information on Basic Phvsical and Chemical Prooerties Physical State: LiquidOdor: Asphaltic Prooertn pH Melting PoinURange Boiling PoinUBoiling Range Flash Point Evaporation Rate Flammability (solid, gas) Flammabillty Llmlts in Ar Upper fiammability limit Lower fi ammability limit Vapor Pressure Vapor Density Speclftc Density Water Solubility Solubility in other solvents Partition coefficlent: n{ctanol/water Autoignition Temperature Decomposition Temperature Viscosity Flammable Propoilies Explosive Properties Oxidizing Properties Other Information VOC Content Values No data available No data available 100" c No data available No data available No datia available No data available No data available No data available No data available 1.24 @77 F Easily dispersible No data available No data available No data available No data available No data available Not Flammable No data available No data available Less than 15 g/l Appearance: Black Odor Threshold: No Information Available Remarks/f,lethod None known None known None known None known None known None known None known None known None known None known None known None known None known None known None known Reactivity: Chemical Stabilatf Possibility of Hazardous Reactions: Hazardous Polymerization : Conditions to Avoid: Incompatible Materials: Hazardous Decomposition Products: No data available Stable under recommended storage conditions. None under normal processing. Hazardous polymerization does not occur. None known Strong oxidizing agents. Acids. Carbon Monoxide (CO), Carbon Dioxide (COe), Hydrogen Sulfide, Nitrogen Dioxide Information on Likelv Routes of Exoosure Product Information lnhalation: Eye Contact: Skin Gontact: Ingestion: May cause initation of respiratory tract. Contact with eyes may cause initation. May cause initation. Ingestion may cause stomach discomfort. Ghemical Name LD50 Oral LD50 Dermal LD5{l Inhalation Asohalt 5000 mo/ko (Rat)>2000 mo/ko (Rabbii) Bentonite >5000 mo/ko (Rat) Svmotoms Related to the Phrcical. Chemical. and Toxicolooical Characteristics Synptoms:No information available. Page 4 Delaved and lmmediate Effec{s and also Chronac Effects from Short and Lonq Term Exposure Sensitization: Mutagenic Effec'ts: Garcinogenicity: No information available. No information available. The table below indicates whether each agency has listed any ingredient as a carcinogen. The IARC, NTP, and OSHA do not tist asphalt as a carcinogen. ln general, the oxidation of polycyclic aromatic hydrocarbons destroys their carcinogenic potential. Petroleum asphalt, shale oil asphalts, and coal tars show distinc{ variation in their relative carcinogenicity for experimental animals. Chemical Name ACGIH IARC NTP OSHA Asohah A3 Group 28 Reasonablv Anticioated X AGGIH: (Anerican Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IRAG: (lnternational Agency for Research on Cancer) Group 28 - Possibly Carcinogenic to Humans NTP: (Nationa! Toxicity Program) Reasonably Anticipated - Reasonably Anticipated to be a Human Carcinogen OSHIU (Occupational Safety & Health Administration) X - Present Reproductive Toxicity: STOT - Single Exposure: STOT - Repeated Exposure: Aspiration Hazard: LD50 Oral: LD50 Dermal No information available. No information available. No information available. No information available. 12542 mgkg; Acute toxicity estimate 6181 mg/kg, Acute toxicity estimate Numerical Measures of Toxicitv - Product The following values arc calculated based on Chapter 3.1 of the GHS docurnent Ecotoxicitv The environmental impact of this product has not been fully investigated. Ghemical Name Toxicity to Algae Toxicity to Fish Toxicity to ilicrooroanisms Daphnia tagna (Water Flea) Bentonite 1302-78-9 LC50 96 h: 8.0-19.0 g/L (Salmo gairdneri) LC50 96 h: = 19000 mg/L static (Oncorhynchus mvkiss) Persistence and Degradability: Bioaccumulation No information available. Chemical Name Loo Pow Asphalt 6..006 Other Mverse Effects:No information available. Waste Disposal ilethods: Gontaminated Packaging: This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or othenrvise comes in contact with a hazardous waste, if chemical additions are made to this material, orif thematerial isprocessedorotherwisealtered. Consult40CFR261 todetermine wfrether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements. Do not re-use empty containers. DOT:Not regulated Proe ( lnternational Inventories TSCA- Complies DSUNDSL - Complies Leoend TSCA- United States Toxic Substiances Control Act Section 8(b) Inventory DSUNDSL - Canadian Domestic Substances LisUNon-Domestic Substances List U.S. Federal Requlations Section 313 of Title lll of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product conlains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Paft 372: SARA 311/312 Hazard Gateoories Acute Health Hazard No Chronic Health Hazard No Fire Hazard No Sudden Release ofPressure Hazard No Reac{ive Hazard No Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 't22.42). CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific requirements at the local, regional, or state level pertaining to releases of this material. U.S. State Reoulations California Proposition 65:This product does not contain any Proposition 65 chemicals. U,S. State Rioht-To-Know Reoulations 'X designates that the ingredients are listed on the state right to know list. U.S. EPA Label Information EPA Pesticide Registration Number:Not applicable Ghemical Name GAS Number Weight %l'At{AJlS- tnresnoro Values % Asphaft 8052424 2040 0.1 Ghemical Name New Jersey Massachusetts Pennsvlvania lllinois Rhode lsland Limestone X x X X AsDhalt X X X X Kaolin x X X X Carbon Black X X X X x NFPA Health Hazard: 1 HMIS Health Hazard: 1 Revision Date: Revision Note: 29-July-201 5 Suoersedes 2$June-201 4. Flammability: 0 Flammability: 0 Instability: 0 Physical Hazard: 0 Physical and Chemical Hazards- Personal Protection: X General Disclaimer The information provided on this SDS is correct to the best of our knowledge, information, and belief at the date of itspublication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. Page 6 lssuing Date 13-Oct-2016 Revision Date SAFETY DATA SHEET Revision Number 0 Recommended Use of the Chemical and Restrictions on Use Recommended Use: No Information Available GHS Product ldentifier Product Name: Other teans of ldentification Product Code(s): Synonyms Uses Advised Against: Supplier Address SealMaster Locations Nationwide www.sealmaster. net 1-80G.341-7325 Emergency Telephone Number Precautionary StatementsPrevention Inhalation: Eye Contact: Skin Contact: Ingestion: Polymer Modifted Mssterseal Ultra Blend Sealer s1093 None No information Available Manufac'turer Addr?ss SealMaster Locations Nationwide www.sealmaster. net 1-800-341-7325 Chemtrec 1 -800-424-9300 Classification This chemical is not considered hazardous according to the OSFIA Hazard Communication Standard 2012 (29 CFR 1910.1200). GHS Label Elements. lncludinq Precautionarv Statements Emergency Overview May cause irritation of respiratory tract. Contact with eyes may cause initation. May cause irritation. lngestion may cause stomach discomfort. General Advace .NoneStorage r Keep container tighty closedDispoial .Dispose of material/containers in accordance with the appropriate state, regional, or local regulations. Hazard t{ot Otherwise Classilied (HNOG) Not applicable Page 1 Signal Word Warning rHarmful if swallowed rMay cause skin initation Black State:Odor: 'The exact percentage of composition has Skin Contac-t lnhalation Ingestion Descriotion of Necessarv First-Aid lleasures Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. lf symptoms persist, call a physician. Wash off immediately with soap and plenty of water. In the case of skin irritation or allergic reactions, see a physician. Move to fresh air. lf synptoms persist, call a physician. Drink plenty of water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Consult a physician if necessary. Most lmoortant Swrotoms/Effects. Acute and DelanedMostlmportantSymptoms/Effects No informationavailable Suitable Extinouishino Media Carbon Diofde (COr). Dry Chemical. Foam. Water Fog. Unsuitable Extlnguishing Media CAUTION: Use of water spray when fighting fire may be inefficient. Soecific Hazards Arisino from the Chemical No information available Exolosion Data Sensitivity to Mechanica! lmpact None Sensitivity to Static Discharge None Protective Equioment and Precautions for Firefiohlers As in any fire, wear self-contained breathing apparatus pressure- demand MSHA/NIOSH (approved or equivalent) and full protective gear. Personal Precautions. Protective Eouioment. and Emeroencv Procedures Personal Precautions: Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Use personal protective equipment. Environmental Precautions Environmental Precautions:See Section 12 for additional Ecological Information Methods and Materials for Containment and Gleaninq Up Methods for Containment: Prevent further leakage or spillage if safe to do so. llethods for Gleaning Up:Dam up. Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. Clean contaminated surface thoroughly. May cause sensitization by skin contact. Precautions for Safe Handlinq Handling:Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes, and clothing. Wear personal protective equipment. Avoid breathing vapors or mists. Do not eat, drink, or smoke when using this product. Wash thoroughly after handling. Page2 Gonditions for Safe Storaoe. lncludlno Anv IncomoatibilftiesStorage: Keep container tightly closed lncompatible Products:Strong oxidizing agents. Acids. Control Paramoters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Limestone 1317-65-3 TWA: 15 mg/m" TWA:5 mg/m3 (vacated) TWA: 15 mg/m3 (vacated) TWA: 5 mo/m3 TWA: 5 mg/m3 respirable dust TWA 10 mg/m" total dust Asphalt 8052424 TWA: 0.5 mg/m3 benzene soluble aerosol fume, inhalable fraclion Ceiling: 5 mg/msfume 15 min. QuarE 1480S60.7 TWA:0.025 mg/m" respirable fraction 30/(%SiO2+2) mg/m3 TWA, Total Dust; 250(%SiO2+5) mppcf TWA, respirable fraction; 101(o/oSiO2+2) mg/m3 TWA, respirable TWA: 0.1 mq/m" (vacated) IDLH: 50 mg/m3 respirable dust TWA: 0.05 mg/m3 respirable dust Kaolin 1332-58-7 TWA: 15 mg/m3 total dust TWA: 5 mg/m3 respirable fraction (vacated) TWA: 10 mg/m3 total dust(vacated) TWA 5 mq/m3 resoirable fraction TWA: 15 mg/m3 total dust TWA: 5 mg/m3 respirable dust Eentonrte 1302-78-9 TWA 1mg/mr resoirable fraction Appropriate Enqineerinq Gontrols Engineering Measureg: Showers Eyewash Stations Ventilation Systems Eye/Face Protection: Skin and Body Protection: Respiratory Protection: Hyglene Measures: are likely to @cur, wear: Safety glasses with side shields. lmpervious gloves. No protective equipment is needed under normal use conditions. lf exposure limits are exceeded or initation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Handle in accordance with good industrial hygiene and safety practice. Information on Basic Phvsical and Chemical Prooerties Physical State: Liquid Odor:Asphaltic Prooertv pH llelting PoinURange Boiling PoinUBolling Range Flash Point Evaporation Rate Flammability (solid, gas) Flammability Limits in Ar Upper ffammability limit Lower f,ammability limit Vapor Pressure Vapor Densityr Specific Denslty Water Solubilityr Solubility in other solvents Partition coefficient: n-octanol/water Autoignition Temperature Decomposition Temperature Viscosity Values No data available No data available 100" c No data available No data available No data available No data available No data available No data available No data available 1.Oc.^1.32@77 F Easily dispersible No data available No data available No data available No data available No data available Appearance: Black Odor Threshold: No lnformation Available Remarks/llethod None known None known None known None known None known None known None known None known None known None known None known None known None known None known None known Page 3 Flammable Properties Explosive Properties Oxidizing Properties VOG Gontent Not Flammable No data available No data available Lessthan 159/l Reactivity: Chemical Stability: Possibility of Hazardous Reac{ions: Hazardous Pollmerization: Gonditions to Avoid: Incompatible tderials: Hazardous Decomposition Products: No data available Stable under recommended storage conditions. None under normal processing. Hazardous polymerization does not occur. None known Strong oxidilng agents. Acids. Carbon Monoxide (CO), Carbon Dioxide (CG), Hydrogen Sulfide, Nitrogen Dioxide Information on Likelv Routes of Exoosure Product lnformation lnhalation: Eye Contact: Skin Contact: lngestion: Synptoms: Mutagenic Effects: Garcinogenicity: Reproduc{ive Toxicity: STOT - Single Exposure: STOT - Repeated Erposurer Aspiration Hazard: LD50 Oral: LD5{l Dermal May cause initation of respiratory tract. Contact with eyes may cause initation. May cause initation. Ingestion may cause stomach discomfort. No information available. No information available. No information available. No information available. 12542 mglkg; Acute toxicity estimate 6181 mg/kg, Acute toxicity estimate Svmptoms Related to the Phnsical. Chemical. and Toxicoloolcal Characteristics No information available. No information No information available. The table below indicates whether each agency has listed any ingredient as a carcinogen. The IARC, NTP, and OSHA do not list asphalt as a carcinogen. In general, the oxidation of polycyclic aromatic hydrocarbons destroys their carcinogenic potential. Petroleum asphalt, shale oil asphalts, and coal tars show distinct variation in their relative carcinogenicity for experimental animals. This product contains crystalline silica (quartz) in a non-respirable form. Inhalation of crystalline silica is unlikely to occur from exposure to this producl. AGGIH: (American Gonference of Governmental Industrial HygienisG) A3 - Animal Carcinogen A2 - Suspected Human Carcinogen IRAC: (lntemational Agency for Research on Gancer) Group 28 - Possibly Carcinogenic to Humans Group 1 - Carcinogenic to Humans NTP: (National Toxicity Program) Reasonably Anticipated - Reasonably Anticipated to be a Human Carcinogen Known - Known Human Carcinogen OSHA (Occupational Safety & Health Mministrataon) X - Present Numerical Measures of Toxicitv - Product The following values are cahulated based on Chapter 3.1 of the GHS documenl Chemical ilame LD50 Oral LD50 Dermal LO50 hhalation Asphalt 5000 mq/ko (Rat)>2000 morko (Rabbit) Quartz 500 mq/kq (Rat) Bentonite >5000 ms/ks (Rat) Chemical Name ACGIH IARC NTP OSHA Asphalt A3 Group 28 Reasonably Aniicioated X Quartz A2 Grouo 1 Known X Page 4 Ecotoxicitv The environmental impact of this Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Microordanisms Daphnia Magna lWater Fleal Bentonite 1302-7&9 LC50 96 h: 8.0-1 9.0 g/L (Salmo gairdneri) LC50 96 h: = 19000 mg/L static (Oncorhynchus mvkiss) Persistence and Oegradability: Bioaccumulation No information available. Chemical Name Loo Pow Asphalt 6.006 Other Adverse Effects:No information available. Waste Disposal Methods:This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste. if chemical additions are made to this material, or if the material is orocessed or othenrvise altered. Consult 40 CFR 261 to determine wtrether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements. Do nol re.use empty containers.Gontaminated Packaging: Not regulated Internationa! Inventories TSCA- Complies DSUNDSL - Complies Leoend TSCA- United States Toxic Substances Control Act Section 8(b) Inventory DSUNDSL - Canadian Domestic Substances LisUNon-Domestic Substances List U.S. Federal Reoulations Section313ofTitlelll oftheSuperfundAmendmentsandReauthorizationActof 1986(SARA). Thisproductcontainsachemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: SARA 311/312 Hazard Cateoories Acute Health Hazard No Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.2'l and 40 CFR 122.421. Ghemical Name GAS Number Weight %SARA 313 - Threshold Values % Asohalt 8052424 2040 0.1 Page 5 CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific requirements at the local, regional, or state level pertaining to releases of this material. U.S. State Reoulations California Proposition 65: Chemical Name GAS Number California ProD. 65 QuarE 1480&6G7 Carcinoqen U.S. State Riqht-To-l(now Requlataons "X" designates that the ingredients are listed on the state right to know list. U.S. EPA Label lnformation EPA Pesticide Registration Number:Not applicable Ghemical Name l{ew Jersev ltassachusetts Pennsylvania lllinois Rhode lsland Limestone X X X x Asphalt X X X X Quartz X X X X Kaolin X X X X NFPA Health Hazard: 1 HMIS Health Hazard: 1 Flammability: Flammability: Instability: 0 Physical Hazard: 0 Physical and Chemical Hazards- Personal Protection: X 0 0 Revision Date: Revislon Note: 13-Oct-2016 No information available. The information provided on this SDS is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific materiat designated and may not be yalid for such material used in combination with any other material or in any process, unless specified in tho text, Page 6