DSHW-2018-005682 - 0901a0688085307a

June 20, 2018
Scott Anderson, Director
Utah Division of Waste Management and Radiation Control
P.O. Box 144880
Salt Lake City, Utah 84114-4880
Re: Request for 30-day extension to the 90-day rule
Dear Mr. Anderson,
UTD 070 93/ l[.80
Div of Waste Management
and Radiation Control
JUN 2 0 2018
D S.\-lW-Z.Ot8 -00 5bB 2..
Henkel has four drums with an accumulation date of March 28, 2018. These four drums are two lab
packs (corrosive acids and corrosive bases) and two drums of off-spec raw material (50% caustic soda
solution and Acticide DBU, SDS attached). All of these are unusual/one-time wastes that require
profiling before disposal. At this time, the profiles for these wastes have not been approved. We do not
expect barriers to disposing of these materials, but profiling of these wastes was delayed because the lab
packs also include samples of raw materials that aged out of their retention period on May 26.
Please contact me at 801-975-3174 if you have any questions. You are also welcome to contact me at
[e-mail].
Best regards,
Tracy Price
Manager, Safety, Health and Environmental
Salt Lake City Plant
Henkel
3540 West 1987 South
Salt Lake City, Utah 84104
Phone: [phone]
Direct: 801.975.3174
Tracy.Price@Henkel .com
www.henkel-northamerica.com
THOR ACTICIDE DBU 20
SAFETY DATA SHEET
Printed: 07/03/2014
Revision: 07/02/2014
Supersedes Revision: 06/18/2014

I
Product Code:
Product Name:
Trade Name:
Company Name:
Emergency Contact:
210514
ACTICIDE DBU 20
Biocide
Thor Specialties, Inc.
50 Waterview Drive
Shelton, CT 06484
CHEMTREC [phone]
Acute Toxicity: Oral, Category 4
Serious Eye Damage/Eye Irritation, Category 1
Skin Sensitization, Category 1
GHS Signal Word:
GHS Hazard Phrases:
GHS Precaution Phrases:
GHS Response Phrases:
GHS Storage and Disposal
Phrases:
Danger
H302 - Harmful if swallowed.
H318 - Causes serious eye damage.
H317 - May cause an allergic skin reaction.
P261 - Avoid breathing dust/fume/gas/mistJvapours/spray.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P264 - Wash hands thoroughly after handling.
P301+330+331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+352 - IF ON SKIN: Wash with plenty of soap and water.
P333+313 - If skin irritation or rash occurs, seek medical advice/attention.
P362 - Take off contaminated clothing and wash before re-use.
P304+340 - IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P305+351+338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310 - Immediately call a POISON CENTER or doctor/physician.
P501 - Dispose of contents/container to accordance with national and international
regulations.
Hazard Rating System:
PPE HMIS:
Page: 1
THOR ACTICIDE DBU 20
SAFETY DATA SHEET
Printed: 07/03/2014
Revision. 07/02/2014
Supersedes Revision: 06/18/2014

Potential Health Effects
(Acute and Chronic):
Inhalation:
Skin Contact:
Eye Contact:
Ingestion:
Harmful if inhaled. May cause respiratory tract irritation.
May cause skin irritation. Harmful if absorbed through the skin.
May cause eye irritation.
Harmful if swallowed. May cause irritation of the digestive tract.
OMPOSITION/INFORIVION-ON IN
CAS # Components (Chemical Name) Concentration
10222-01-2 2,2-Dibromo-3-nitrilopropionamide 20.0 %
25322-68-3 Polyethylene glycol 50.0 %
7732-18-5 Water 30.0 %
RRS
Emergency and First Aid
Procedures:
In Case of Inhalation:
In Case of Skin Contact:
In Case of Eye Contact:
In Case of Ingestion:
Note to Physician:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Flush skin with plenty of water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical aid.
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and
lower eyelids. Get medical aid.
Wash mouth out with water. Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Treat symptomatically and supportively.
IN
Flash Pt: NA Method Used: Estimate
Explosive Limits: LEL: No data. UEL: No data.
Autoignition Pt: NA
Suitable Extinguishing Media:Use water spray, dry chemical, carbon dioxide, or chemical foam.
Fire Fighting Instructions: As in any fire, wear a self-contained breathing apparatus in pressure-demand,
MSHA/NIOSH (approved or equivalent), and full protective gear.
Flammable Properties and No data available.
Hazards:
;;c104)Pi
Protective Precautions,
Protective Equipment and
Emergency Procedures:
Environmental Precautions: Avoid release to the environment.
Use proper personal protective equipment as indicated in Section 8.
Steps To Be Taken In Case Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable
Material Is Released Or container.
Spilled:
Page: 2
"NM- MEM
T
THOR
Precautions To Be Taken in
Handling:
Precautions To Be Taken in
Storing:
ACTICIDE DBU 20
SAFETY DATA SHEET
contact with skin and eyes. Keep container
incompatible material. Store away from
Hi11_1
Avoid breathing dust, mist, or vapor. Avoid
tightly closed.
Store in a cool, dry place. Store away from
sparks, flames.
Printed• 07/03/2014
Revision: 07/02/2014
Supersedes Revision: 06/18/2014
CAS # Components (Chemical Name) OSHA TWA ACGIH TWA Other Limits
10222-01-2 2,2-Dibromo-3-nitrilopropionamide No data. No data. No data.
25322-68-3 Polyethylene glycol No data. No data. No data.
7732-18-5 Water No data. No data. No data.
Respiratory Equipment
(Specify Type):
Eye Protection:
Protective Gloves:
Other Protective Clothing:
Engineering Controls
(Ventilation etc.):
Work/Hygienic/Maintenance
Practices:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.
Goggles and face shield.
Wear appropriate protective gloves to prevent skin exposure.
Wear appropriate protective clothing to prevent skin exposure.
Use adequate ventilation to keep airborne concentrations low.
Wash hands before breaks and immediately after handling the product.
Physical States: [ ] Gas [ X ] Liquid [ ] Solid
Appearance and Odor: Yellowish.
chlorine-like.
Freezing Point: -5.00 F (-20.6 C) - -10.00 F (-23.3 C)
Boiling Point: > 70.00 C (158.0 F)
Decomposition Temperature: > 70.00 C (158.0 F)
Autoignition Pt: NA
Flash Pt:
Explosive Limits:
Specific Gravity (Water = 1):
Vapor Pressure (vs. Air or
mm Hg):
Vapor Density (vs. Air = 1):
Evaporation Rate:
Solubility in Water:
NA Method Used: Estimate
LEL: No data. UEL: No data.
1.15+/-0.05
4x10(-5) MM_HG at 25.0 C (77.0 F)
<
< 1
soluble
Page: 3
THOR ACTICIDE DBU 20
SAFETY DATA SHEET
Printed: 07/03/2014
Revision: 07/02/2014
Supersedes Revision: 06/18/2014

pH: 2.83 +/- 0.5 - (10% soln)
Percent Volatile: No data.
r,
Reactivity: acids, Bases, Water.
Stability: Unstable [ ] Stable [ X ]
Conditions To Avoid - Instability: Light, Heat, heating to decomposition. Incompatible materials.
incompatibility - Materials To Avoid: Strong oxidizing agents, Reducing agents, Bases.
Hazardous Decomposition Or
Byproducts:
Possibility of Hazardous Reactions:
Conditions To Avoid - Hazardous
Reactions:
Nitrogen oxides, hydrogen bromide. bromine fumes.
Will occur [ ] Will not occur [ X ]
Product will not undergo polymerization.
Toxicological Information:
Carcinogenicity/Other
Information:
Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects: Mutagenicity: Neurotoxicity: Other Studies:
CAS# 10222-01-2:
Acute toxicity, LD50, Intravenous, Mouse, 10.00 MG/KG; U.S. Army Armament Research
Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals.,
Aberdeen Proving Ground,, Aberdeen Proving Ground, MD 21010, Vol/p/yr: NX#, 7898
Acute toxicity, LD50, Oral, Species: unspecified., 118.0 MG/KG; Pharmacologist.,
American Soc. for Pharmacology and Experimental Therapeutics, 9650 Rockville Pike,
Rockville, MD 20014, Vol/p/yr: 15,226, 1973
Standard Draize Test, Skin, Species: Rabbit, 500.0 MG; Pharmacologist., American Soc.
for Pharmacology and Experimental Therapeutics, 9650 Rockville Pike, Rockville, MD
20014, Vol/p/yr: 15,226, 1973
Standard Draize Test, Eyes, Species: Rabbit, 100.0 MG; Pharmacologist., American Soc.
for Pharmacology and Experimental Therapeutics, 9650 Rockville Pike, Rockville, MD
20014, Vol/p/yr: 15,226, 1973
Carcinogenicity:
CAS# 7732-18-5:
Acute toxicity, LD50, Oral, Rat, 90.00 ML/KG; Food Research., For publisher information,
see JFDSAZ, Champaign, IL, Vol/p/yr: 21,348, 1956
CAS# 10222-01-2: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
NTP? No IARC Monographs? No OSHA Regulated? No
Page: 4
ÐERATI
THOR ACTICIDE DBU 20
SAFETY DATA SHEET
Printed. 07/03/2014
Revision: 07/02/2014
Supersedes Revision: 06/18/2014

12. ECOLOGIC IN

Results of PBT and vPvB
assessment:
No data available.
CAS# 10222-01-2:
LC50, Bluegill (Lepomis macrochirus), 2.300 PPM, 96 H, Mortality; Pesticide Ecotoxicity
Database (Formerly: Environmental Effects Database (EEDB)), Office of Pesticide
Programs, 2000
LC50, Rainbow Trout (Oncorhynchus mykiss), 2.300 PPM, 96 H, Mortality; Pesticide
Ecotoxicity Database (Formerly: Environmental Effects Database (EEDB)), Office of
Pesticide Programs, 2000
Effective concentration to 50% of test organisms., Water Flea (Daphnia magna), 0.900
PPM, 48 H, Intoxication,; Pesticide Ecotoxicity Database (Formerly: Environmental
Effects Database (EEDB)), Office of Pesticide Programs, 2000
Waste Disposal Method: Chemical waste generators must determine whether a discarded chemical is classified as
a hazardous waste. US EPA guidelines for the classification determination are listed in 40
CFR Parts 261. Additionally, waste generators must consult state and local hazardous
waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
LAND TRANSPORT (US DOT):
DOT Proper Shipping Name: Not Regulated.
DOT Hazard Class:
UN/NA Number:
LAND TRANSPORT (Canadian TDG):
TDG Shipping Name: Not Regulated.
UN Number:
Hazard Class: TDG Classification:
MARINE TRANSPORT (IMDG/IMO):
IMDG/IMO Shipping Name: Not Regulated.
UN Number: Packing Group:
Hazard Class:
Marine Pollutant: Yes
AIR TRANSPORT (ICAO/IATA):
ICAO/IATA Shipping Name: Not Regulated.
Page: 5
EG TORY INF
THOR ACTICIDE DBU 20
SAFETY DATA SHEET

Printed: 07/03/2014
Revision 07/02/2014
Supersedes Revision: 06/18/2014
EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists
CAS # Components (Chemical Name) S. 302 (EHS) S. 304 RQ S. 313 (TRI)
10222-01-2 2,2-Dibromo-3-nitrilopropionamide No No No
25322-68-3 Polyethylene glycol No No No
7732-18-5 Water No No No
CAS # Components (Chemical Name) Canadian NPRI Canadian IDL Canadian DSL
10222-01-2 2,2-Dibromo-3-nitrilOpropionamide No No No (NDSL Listed)
25322-68-3 Polyethylene glycol No No Yes
7732-18-5 Water No No Yes
CAS # Components (Chemical Name) International Regulatory Lists
10222-01-2 2,2-Dibromo-3-nitnlopropionamide
25322-68-3 Polyethylene glycol
7732-18-5 Water
Canadian WHMIS Classification: CLASS D, DIVISION 1: Materials Causing Immediate and Serious Toxic Effects
CLASS E: Corrosive Materials
California Proposition 65: Contains chemical listed as carcinogen: Dibromoacetonitrile @ 0.1% max
Based on a 3rd party toxicologist risk assessment, if the EPA label directions are followed as required by law,
exposures are below a 3rd party toxicologist derived NSRL and warnings may not be required.
Revision Date: 07/02/2014
Additional Information About No data available.
This Product:
Company Policy or The information accumulated herein is believed to be accurate based on the information
Disclaimer: provided, although no guarantee or warranty, either expressed or implied is made as to
the accuracy or completeness of this information, whether originating with this company
or not. Recipients are advised to confirm in advance of need that the information is
correct, applicable and suitable to their circumstances. The conditions or methods of
handling, storage, use and disposal of the product and container are beyond our control
and may be beyond our knowledge. For this and other reasons, we do not assume
responsibility and expressly disclaim liability for loss, damage or expense arising out of or
in any way connected with the handling, storage or use of this information or product. If
the product is used as a component in-another product, this information may not be
applicable.
Page: 6