DSHW-2018-005148 - 0901a0688083d884

Div of Waste Management and Radiation Control
JUN - 6 2018
DSHW-Z0(6-00,5t4-5 ENVIRONMENTAL SERVICES'
June 6th, 2018
Mr. John Parry
Utah Department of Environmental Quality
Director-Division of Solid and Hazardous Waste
P.O. Box 144880
Salt Lake City, UT 84114-4880
Dear Mr. Parry,
Brigham Young University, located in Provo, Utah 84602, EPA # UTD009094012, a large quantity
generator, is requesting a temporary emergency license for onsite treatment of 5 potentially
unstable, hazardous waste containers of the following material: Picric Acid (1x100g), Sodium Azide
(2x100g), Diethyl Ether (1x1L), 2-Vinylpyridine (1x100g). We feel the sodium azide will be able to be
approved for shipment, pending further evaluation.
The Reactive Materials Division of Clean Harbors Environmental Services has been contacted to treat
the potentially unstable compounds at BYU. The material in question has been deemed unstable for
transport and disposal and will require treatment prior to shipment.
The process will require two Reactive Materials Field Technicians from Clean Harbors to perform the
following steps:
1. Don personal protective equipment in the event of detonation or deflagration.
2. Enter into the building containing the material carrying a class C explosives magazine Blasters Day
Box. The Blasters Day Box is used to safely carry the potentially explosive material to the remote
opening location and the Portable Remote Unit.
3. The chemicals will then be safely removed from the building and brought to the site of
stabilization and remotely opened with the Portable Remote Opener. The Portable Remote
Opener is a Clean Harbors engineered piece of equipment that has been designed to safely open
potentially explosive chemicals in remote locations where other Clean Harbors standardize
equipment cannot be used. The Portable Unit will be encased with a Kevlar bomb blankets
during the remote opening process.
4. Once the materials have been remotely opened with the Portable Unit they will then be
stabilized, using Clean Harbors Standard Operating Procedure, for future safe transportation and
disposal at a Clean Harbors Incinerator.
The project is estimated to be completed in —1- day and will be performed upon your approval. This
project will be scheduled upon approval, but is preliminarily planned for Thursday 9/15/2016. Once
approved please send all or any accompanying permit documentation to:
Brigham Young University
Chemical Management Building
Provo, UT 84602
Attn: Mr. Alfredo Chandia
Phone: [phone]
If you have any questions or need additional information, please contact me at [phone]
Sincerely,
Jason J. Widdows
Clean Harbors Environmental Services
Reactive Materials Services
WORK PLAN
FOR
CHEMICAL STABILIZATION OF
POTENTIALLY UNSTABLE MATERIAL
AT
Brigham Young University
101 Chemicals Management Building
Provo, UT 84602
EPA ID # UTD009094012
A LARGE QUANTITY GENERATOR
PREPARED BY:
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ENVIRONMENTAL SERVICES'
CLEAN HARBORS ENVIRONMENTAL SERVICES
500 Independence Parkway South
La Porte, TX 77571
By: Jason J. Widdows
Operations Manager, Reactive Material Services
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WORK PLAN
Brigham Young University
TABLE OF CONTENTS
1. INTRODUCTION
2. SCOPE OF WORK/SITE SET-UP
3. CONTAINER HANDLING STRATEGY
4. DISPOSAL OF STABILIZED MATERIALS
5. CONTINGENCY PLAN
6. COMPLIANCE AGREEMENT
7. SITE MAP
8. MSDS
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WORK PLAN
Brigham Young University
1.0 INTRODUCTION
Clean Harbors Environmental Services (CHES) has prepared this Work Plan to govern its
operations stabilizing five (5) potentially unstable containers at Brigham Young University
(BYU).
BYU has the fbllowin material reGuirin! stabilization
Description Quantity
I rior to shisment:
Hazard Designation
Shock Sensitive
Container Size
lx100g Picric Acid 1
Diethyl Ether 1 Peroxide Former lx1L
Sodium Azide 2 Shock Sensitive 2x100g
2-Vinylpyridine 1 Peroxide Former /
Monomer
lx100g
This material will need to be remotely opened and then stabilized prior to disposal by Clean
Harbors Environmental Services.
The Provo Fire Department will be made known of the presence of these materials and will have
final approval for all work to be performed.
LOCATION
Mailing Address: Physical Location:
Brigham Young University Brigham Young University
Chemicals Management Building Chemicals Management Building
Provo, UT 84602 Provo, UT 84602
Contact: Mr. Alfredo Chandia
Phone: [phone]
Email: alfredo chandia(&,byu.edu
DATE/TIME OF STABILIZATION
June 8th, 2018; upon plan approval from the Utah Department of Environmental Quality.
The project is estimated to be completed in 2-4 hours, and will be performed upon your
approval.
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2.0 SCOPE OF WORK/SITE SET-UP
Clean Harbors will arrive on site the scheduled project day in order to set up the Exclusion
Zone. Caution tape shall be set up around the Exclusion Zone in order to keep unauthorized
individuals away. No personnel will be allowed in the Exclusion Zone during the operation
except for the two Reactive Materials Technicians. The Exclusion Zone will have a —100ft.
radius in all directions. The following personnel will be on site and their roles are described:
Two Reactive Materials Technicians: Solely responsible for the movement of containers from
the storage area to the outside Exclusion Zone in order to remotely open and stabilize the
materials. These are the only individuals allowed to handle the unstable material.
BYU: Health & Safety personnel to provide site security and traffic control.
Provo Fire Department will be notified and ready if assistance is needed.
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3.0 CONTAINER HANDLING STRATEGY
PEROXIDE FORMING / POLYMERIZABLE LIQUID HANDLING
A. Peroxide Forming Liquids, Stabilization of lab pack quantities.
Condition of Material/Scenario:
Peroxide formation may be present anywhere in the container, including the side of the
container, the bottom of the container, the threaded cap, or even outside the container. Peroxide
formation in ppm concentrations may not be visually observable and must be identified through
appropriate testing procedures. If any of the following conditions exist the compound may be
explosively unstable and will require stabilization prior to transportation.
A. Material appears to be degraded/contaminated.
B. Material appears to be discolored.
C. Deterioration or distortion of storage container.
D. Gross contamination.
E. Thermal shock. (Sunlight)
F. Oxidation on exterior of container.
G. Age of material exceeds recommended storage time.
Hazard Analysis:
CHEMICAL Peroxide Hazard SOLVENT USED
2-Vinylpyridine Peroxide Former / Monomer MEHQ
Diethyl Ether Peroxide Former FAS / HQ
Peroxides are less volatile than solvent and tend to concentrate in solution or in the container
threads. Experiments have determined that a percentage of 0.008% (80ppm) or more is enough
to initiate explosive decomposition. Peroxides are sensitive to heat, friction and shock. Some
peroxides may explode without being concentrated. (Example: Isopropyl Ether)
Safe Distances:
If Material is improperly handled there is a potential for a reaction, which include fire and/or
deflagration. Remote opening of lab pack quantities require —75 ft. safe distance.
Basic Equipment Overview:
A. Day box.
B. Portable Remote Opener with Kevlar Safety Circle.
C. Stabilization Kit.
D. Fire extinguisher (ABC)
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E. Eyewash/First-aid kit
F. Stabilization jars.
G. MEHQ
H. FAS
I. HQ
Scope of Work:
Removal of the peroxide forming liquid to the Exclusion Zone. Work signs and danger tape will
delineate this area. All work on peroxidizable compounds will be performed in this area.
ABSOLUTELY NO UNAUTHORIZED ENTRY into the Exclusion Zone.
A. To move and open peroxidizable material:
1. Secure work area and transportation route.
2. Ground Portable Remote Opener.
3. Check Fire Extinguisher.
4. Remove chemical from storage area.
5. Secure chemical in day box and transport to remote opener in closed day box.
6. Secure wrist-grounding strap to technician prior to removing chemical from day box.
7. Secure chemical in remote opener.
8. Open container in remote opener.
A. Peroxide / Monomer:
1. Add 0.5 grams to 1 gram of MEHQ per liter of Acryloyl Chloride to insure properly
inhibited. Objective is to achieve 500-1000 ppm of inhibitor per liter of Acryloyl
Chloride.
B. Peroxide destruction procedure:
1. Ensure the peroxide test strips have not exceeded their expiration date. Test liquid by
submersing peroxide strip into peroxide forming material.
2. Submerse strip into Deionized water, wait 5 seconds and record results.
3. If no peroxides are detected, add 100m1 of 10% Hydroquinone solution per 1 liter of
peroxide forming liquid to inhibit any future peroxide formation.
4. If any peroxides are present, destroy them by adding 30% Ferrous Ammonium Sulfate
solution per 1 liter of peroxide forming liquid. Be cautious, since reaction may be vigorous
if high peroxide concentrations are present. At first gently, then subsequently vigorously,
stir mixture with a plastic or glass stirring rod. Retest liquid with peroxide test strip. If still
present, repeat stabilization process. When no peroxides are detected, add 100m1 of 10%
Hydroquinone solution per 1 liter of peroxide forming liquid to inhibit any future peroxide
formation.
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SHOCK SENSITIVE MATERIALS HANDLING
A. Shock Sensitive Compounds, stabilization of lab pack quantities.
Condition of Material/Scenario:
El A. Flammable solids, which are shock sensitive when, dry.
These compounds have low to moderate sensitivity.
1. Picric Acid.
2. Dinitrophenol.
3. Trinitrobenzene.
4. Trinitrotoluene.
5. Picrite.
E2 B. Flammable solids, which are shock sensitive when, dry. These compounds have a
moderate to high sensitivity.
1. Cyclonite.
2. PETN.
3. Nitroglycerine.
4. Nitrosoguandine.
5. Tetryl.
E3 C. Contaminated El, E2 materials and DOT forbidden materials. (Highly Shock
Sensitive)
I. Mercury Fulminate.
2. Lead Azide.
3. Lead Trinitroresorcinate.
4. Diazodinitrophenol.
5. Tetrazene.
Hazard Analysis:
CHEMICAL SHOCK SENSITIVE SOLVENT USED
Picric Acid Shock Sensitive DI Water / Alcohol
Sodium Azide Shock Sensitive Further evaluation and
approve
A. Material may be shock sensitive. Any external energy input may cause high or low order
detonation if any of the following conditions exist.
1. Material appears to be degraded/contaminated.
2. Deterioration or distortion of storage container.
3. Material appears to be discolored.
4. Thermal shock.
5. Mechanical shock.
6. Friction.
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Safe Distances:
If material is improperly handled there is a potential for a reaction, which include fire and/or
high/low order detonation. Remote opening of lab pack quantities require —100 ft. safe
distance.
Basic Equipment Overview:
A. Day box.
B. Portable Remote Opener with Kevlar Safety Circle
C. Stabilization kit.
D. Fire extinguisher (ABC)/eyewash/First-Aid kit
E. Stabilization jars.
F. Deionized water.
G. Solvents (Alcohol)
Scope of Work:
Removal of the El to the Exclusion zone. Work signs and danger tape will delineate this area.
All work on the chemicals will be performed in this area. ABSOLUTELY NO
UNAUTHORIZED ENTRY into the exclusion zone.
A. To move and open shock sensitive material:
1. Secure work area and transportation route.
2. Ground Portable Remote Opener.
3. Check Fire Extinguisher.
4. Remove chemical from storage area.
5. Secure chemical in day box and transport to remote opener in closed day box.
6. Secure wrist-grounding strap to technician prior to removing chemical from day box.
7. Secure chemical in remote opener.
8. Open container in remote opener.
B. Stabilization/deactivation of shock sensitive material:
1. Picric Acid -Thoroughly hydrate/saturate chemical with Deionized Water and Alcohol.
Insure that all solids are saturated and all lumps are broken up with plastic stirrer. Be
sure to wet cap and threads of the container. No more than 1 pound of chemical wet is
acceptable per 1-gallon container.
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4.0 DISPOSAL OF STABILIZED MATERIALS
Once the containers have been remotely opened and stabilized they will be set aside for
packaging during the next scheduled lab pack. They will then be transported to a Clean Harbors
a Clean Harbors approved incinerator. (Aragonite)
5.0 CONTINGENCY PLAN
In the event of fire or explosion, the area shall be evacuated and the Provo Fire Department will
be notified. Clean Harbors personnel will not be involved in fire fighting. Incipient fires can be
fought using a portable fire extinguisher. Clean Harbors employees are first aid certified in the
event an individual is injured. Below are emergency numbers that can be called. Clean Harbors
personnel will not be involved in any contingency plan responses under this plan.
EMERGENCY NUMBERS
Provo Fire Department 9-1-1 or 1-801-852-6321
Ambulance Service 9-1-1
Utah Valley Hospital 1-801-357-7850
1034 N. 500 W
Provo, UT 84604
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6.0 COMPLIANCE AGREEMENT:
All on-site personnel, (i.e., CHE employees and subcontractors), must complete and sign this
section prior to the commencement of site activities for the BYU project.
I have read and understand the contents of this High Hazard Work Plan, and have had all
relevant questions answered to my satisfaction. In addition, I agree to comply with the
conditions/provisions outlined therein:
NAME COMPANY/
(Print) SIGNATURE CHE BRANCH DATE
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7.0 SITE LOCATION
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8.0 MSDS INFORMATION

0.0 3
3.0 Re a c t iv it y
4.0 Personal
5.0 Protection
8.0 3
9.0 E
10.0 Material Safety Data Sheet
11.0 Sodium azide MSDS

12.0 Section 1: Chemical Product and Company Identification

13.0 Product Name: Sodium azide

14.0 Catalog Codes: SLS1363

15.0 CAS#: 26628-22-8

16.0 RTECS: VY8050000

17.0 TSCA: TSCA 8(b) inventory: Sodium azide

18.0 Cl#: Not available.

19.0 Synonym:

20.0 Chemical Name: Hydrazoic Acid, Sodium Salt

21.0 Chemical Formula: NaN3

22.0 Contact Information:

23.0 Sciencelab.com, inc.

24.0 14025 Smith Rd.

25.0 Houston, Texas 77396

26.0 US Sales: 1-800-901-7247

27.0 International Sales: 1-281-441-4400

28.0 Order Online: ScienceLab.com

29.0 CHEMTREC (24HR Emergency Telephone), call:

30.0 1-800-424-9300

31.0 International CHEMTREC, call: 1-703-527-3887

32.0 For non-emergency assistance, call: 1-281-441-4400

33.0 Section 2: Composition and Information on Ingredients

34.0 Composition:

35.0 Name CAS # % by Weight

36.0 Sodium azide 26628-22-8 100

37.0 Toxicological Data on Ingredients: Sodium azide: ORAL (LD50): Acute: 27
mg/kg [Rat]. 27 mg/kg [Mouse]. DERMAL

38.0 (LD50): Acute: 20 mg/kg [Rabbit].

39.0 Section 3: Hazards Identification

40.0 Potential Acute Health Effects:

41.0 Very hazardous in case of skin contact (irritant), of eye contact (irritant).
Hazardous in case of ingestion, of inhalation.

42.0 Slightly hazardous in case of skin contact (permeator). Severe over-exposure
can result in death. Inflammation of the eye
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43.0 is characterized by redness, watering, and itching. Skin inflammation is
characterized by itching, scaling, reddening, or,

44.0 occasionally, blistering.

45.0 Potential Chronic Health Effects:

46.0 CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not
available. TERATOGENIC EFFECTS: Not

47.0 available. DEVELOPMENTAL TOXICITY: Not available. Repeated exposure to
an highly toxic material may produce general

48.0 deterioration of health by an accumulation in one or many human organs.

49.0 Section 4: First Aid Measures

50.0 p. 2

51.0 Eye Contact:

52.0 Check for and remove any contact lenses. Immediately flush eyes with running
water for at least 15 minutes, keeping eyelids

53.0 open. Cold water may be used. Do not use an eye ointment. Seek medical
attention.

54.0 Skin Contact:

55.0 After contact with skin, wash immediately with plenty of water. Gently and
thoroughly wash the contaminated skin with running

56.0 water and non-abrasive soap. Be particularly careful to clean folds, crevices,
creases and groin. Cold water may be used.

57.0 Cover the irritated skin with an emollient. If irritation persists, seek medical
attention. Wash contaminated clothing before

58.0 reusing.

59.0 Serious Skin Contact:

60.0 Wash with a disinfectant soap and cover the contaminated skin with an anti-
bacterial cream. Seek immediate medical

61.0 attention.

62.0 Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate
medical attention.

63.0 Serious Inhalation:

64.0 Evacuate the victim to a safe area as soon as possible. Loosen tight clothing
such as a collar, tie, belt or waistband. If

65.0 breathing is difficult, administer oxygen. If the victim is not breathing, perform
mouth-to-mouth resuscitation. Seek medical

66.0 attention.

67.0 Ingestion:

68.0 Do not induce vomiting. Examine the lips and mouth to ascertain whether the
tissues are damaged, a possible indication that

69.0 the toxic material was ingested; the absence of such signs, however, is not
conclusive. Loosen tight clothing such as a collar,

70.0 tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth
resuscitation. Seek immediate medical attention.

71.0 Serious Ingestion: Not available.

72.0 Section 5: Fire and Explosion Data

73.0 Flammability of the Product: May be combustible at high temperature.

74.0 Auto-Ignition Temperature: Not available.

75.0 Flash Points: Not available.

76.0 Flammable Limits: Not available.

77.0 Products of Combustion: Some metallic oxides.

78.0 Fire Hazards in Presence of Various Substances: Highly flammable in
presence of shocks.
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79.0 Explosion Hazards in Presence of Various Substances:

80.0 Risks of explosion of the product in presence of static discharge: Not available.
Highly explosive in presence of shocks, of

81.0 metals.

82.0 Fire Fighting Media and Instructions:

83.0 SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog
or foam. Do not use water jet.

84.0 Special Remarks on Fire Hazards: Not available.

85.0 Special Remarks on Explosion Hazards: Not available.

86.0 Section 6: Accidental Release Measures

87.0 Small Spill: Use appropriate tools to put the spilled solid in a convenient waste
disposal container.

88.0 Large Spill:

89.0 Use a shovel to put the material into a convenient waste disposal container. Be
careful that the product is not present at a

90.0 concentration level above TLV. Check TLV on the MSDS and with local
authorities.

91.0 Section 7: Handling and Storage

92.0 P. 3

93.0 Precautions:

94.0 Keep locked up Keep away from heat. Keep away from sources of ignition.
Empty containers pose a fire risk, evaporate the

95.0 residue under a fume hood. Ground all equipment containing material. Do not
ingest. Do not breathe dust. Take precautionary

96.0 measures against electrostatic discharges. In case of insufficient ventilation,
wear suitable respiratory equipment If ingested,

97.0 seek medical advice immediately and show the container or the label. Avoid
contact with skin and eyes Keep away from

98.0 incompatibles such as metals.

99.0 Storage:

100.0 Keep container dry. Keep in a cool place. Ground all equipment containing
material. Keep container tightly closed. Keep in a

101.0 cool, well-ventilated place. Highly toxic or infectious materials should be stored
in a separate locked safety storage cabinet or

102.0 room.
103.0 Section 8: Exposure Controls/Personal Protection

104.0 Engineering Controls:

105.0 Use process enclosures, local exhaust ventilation, or other engineering controls
to keep airborne levels below recommended

106.0 exposure limits. If user operations generate dust, fume or mist, use ventilation
to keep exposure to airborne contaminants

107.0 below the exposure limit.

108.0 Personal Protection:

109.0 Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified
respirator or equivalent. Gloves.

110.0 Personal Protection in Case of a Large Spill:

111.0 Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained
breathing apparatus should be used to avoid

112.0 inhalation of the product. Suggested protective clothing might not be sufficient;
consult a specialist BEFORE handling this

113.0 product.
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114.0 Exposure Limits: TWA: 0.29 (mg/m3) from ACGIHConsult local authorities for
acceptable exposure limits.
115.0 Section 9: Physical and Chemical Properties
116.0 Physical state and appearance: Solid.
117.0 Odor: Not available.
118.0 Taste: Not available.
119.0 Molecular Weight: 65.02 g/mole
120.0 Color: Not available.
121.0 pH (1% soln/water): Not available.
122.0 Boiling Point: Not available.
123.0 Melting Point: Decomposes.
124.0 Critical Temperature: Not available.
125.0 Specific Gravity: 1.846 (Water = 1)
126.0 Vapor Pressure: Not applicable.
127.0 Vapor Density: Not available.
128.0 Volatility: Not available.
129.0 Odor Threshold: Not available.
130.0 Water/Oil Dist. Coeff.: Not available.
131.0 lonicity (in Water): Not available.
132.0 Dispersion Properties: See solubility in water.
133.0 p. 4
134.0 Solubility: Soluble in cold water.
135.0 Section 10: Stability and Reactivity Data
136.0 Stability: Unstable.
137.0 Instability Temperature: Not available.
138.0 Conditions of Instability: Not available.
139.0 Incompatibility with various substances: Extremely reactive or incompatible
with metals.
140.0 Corrosivity: Non-corrosive in presence of glass.
141.0 Special Remarks on Reactivity: Not available.
142.0 Special Remarks on Corrosivity: Not available.
143.0 Polymerization: No.
144.0 Section 11: Toxicological information
145.0 Routes of Entry: Eye contact. Inhalation. Ingestion.
146.0 Toxicity to Animals:
147.0 Acute oral toxicity (LD50): 27 mg/kg [Mouse]. Acute dermal toxicity (LD50): 20
mg/kg [Rabbit].
148.0 Chronic Effects on Humans: Not available.
149.0 Other Toxic Effects on Humans:
150.0 Very hazardous in case of skin contact (irritant). Hazardous in case of ingestion,
of inhalation. Slightly hazardous in case of
151.0 skin contact (permeator).
152.0 Special Remarks on Toxicity to Animals: Not available.
153.0 Special Remarks on Chronic Effects on Humans: Not available.
154.0 Special Remarks on other Toxic Effects on Humans: Not available.
155.0 Section 12: Ecological Information
156.0 Ecotoxicity: Not available.
157.0 BOD5 and COD: Not available.
158.0 Products of Biodegradation: Possibly hazardous short/long term degradation
products are to be expected.
159.0 Toxicity of the Products of Biodegradation: The products of degradation are
more toxic.
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160.0 Special Remarks on the Products of Biodegradation: Not available.
161.0 Section 13: Disposal Considerations
162.0 Waste Disposal:
163.0 Section 14: Transport Information
164.0 DOT Classification: CLASS 6.1: Poisonous material.
165.0 P. 5 166.0 Identification: : Sodium azide : UN1867 PG: II
167.0 Special Provisions for Transport: Not available.
168.0 Section 15: Other Regulatory Information
169.0 Federal and State Regulations:
170.0 Pennsylvania RTK: Sodium azide Massachusetts RTK: Sodium azide TSCA
8(b) inventory: Sodium azide SARA
171.0 302/304/311/312 extremely hazardous substances: Sodium azide SARA 313
toxic chemical notification and release reporting:
172.0 Sodium azide CERCLA: Hazardous substances.: Sodium azide
173.0 Other Regulations: OSHA: Hazardous by definition of Hazard Communication
Standard (29 CFR 1910.1200).
174.0 Other Classifications:
175.0 WHMIS (Canada): CLASS D-1A: Material causing immediate and serious toxic
effects (VERY TOXIC).
176.0 DSCL (EEC):
177.0 R38- Irritating to skin. R41- Risk of serious damage to eyes.
178.0 HMIS (U.S.A.):
179.0 Health Hazard: 3
180.0 Fire Hazard: 1
181.0 Reactivity: 3
182.0 Personal Protection: E
183.0 National Fire Protection Association (U.S.A.):
184.0 Health: 3
185.0 Flammability: 1
186.0 Reactivity: 3
187.0 Specific hazard:
188.0 Protective Equipment:
189.0 Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified
respirator or equivalent. Wear appropriate respirator
190.0 when ventilation is inadequate. Splash goggles.
191.0 Section 16: Other Information
192.0 References: Not available.
193.0 Other Special Considerations: Not available.
194.0 Created: 10/11/2005 12:32 PM
195.0 Last Updated: 11/06/2008 12:00 PM
196.0 The information above is believed to be accurate and represents the best
information currently available to us. However, we
197.0 make no warranty of merchantability or any other warranty, express or implied,
with respect to such information, and we assume
198.0 no liability resulting from its use. Users should make their own investigations to
determine the suitability of the information for
199.0 their particular purposes. In no event shall ScienceLab.com be liable for any
claims, losses, or damages of any third party or for
200.0 lost profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if ScienceLab.com
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PICRIC ACID
(NO2)3C6H20H
Carbazotic acid, 2-Hydroxy-1,3,5-trinitroberizene,
Nitroxanthic acid, Phenol tnnitrate, 2,4,6-Trinitrophenol, Picronitnc acid, Melinite, AC-7505, AC-7506, 70978, 70986
For laboratory use only.
Anachemia Canada.
255 Norman.
Lachine (Montreal), Que
H8R 1A3
Section II. Ingredients
aterial Safety ata Sheet
Synonyms
Chemical formula
Material uses WHMIS Protective Clothing TDG Road/Rail
Section L Product Identification and Uses
Not available.
Supplier
CI#
Product name
255 Norman.
Lachine (Montreal), Que
H8R 1A3
PIN: UN1344 PG: I
WHMIS CLASS: B-4 D-16 D-26 E F TDG CLASS: 4 1
1) PICRIC ACID 88-89-1 <70 Exposure limits: ACGIH 1WA 0.1
mg/m3:
2) WATER 7732-18-5 >30 Not established by ACGIH
PICRIC ACID:
ORAL (LD50): Acute: 200 mg/kg (Rat).
ORAL (LDLo)• Acute: 100 mg/kg (Guinea pig). 120 mg/kg (Rabbit).
INTRAPERITONEAL (LD50). Acute: 56300 ug/kg (Mouse).
Toxicity values of the
hazardous ingredients
Name CAS # %
EMERGENCY NUMBERS:
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(CAN) CANUTEC : 1(613) 996-6666 (24hrs)
(USA) Anachemia : 1(518) 297-4444
(CAN) Anachemia : 1(514) 489-5711
TLV
Section V. Toxicological Properties
Harmful by ingestion, inhalation or skin absorption. Poison. Irritant. Target organs: liver, kidneys, blood, skin,
eyes.
75 mg/m3 (PICRIC ACID) is immediately dangerous to life or health.
Section III. Physical Data
Physical state and
appearance / Odor
Percent volatile
pH (1% soln/water)
Freezing point
Boiling point
Vapor pressure
Odor threshold
Specific gravity
Vapor density
Water/oil dist. coeff.
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Evaporation rate
Solubility
»30%
Not available.
120-123°C (Dry)
Explodes above 300°C
1.763 (Water = 1)
7.9 (Air = 1)
1 mmHg @ 195°C
0.0093325
Not available.
Partially soluble in cold water.
Not available.
Yellow, odorless crystals. PICRIC ACID page 2/4
Auto-ignition temperature
Fire degradation
products
Flash point
Fire extinguishing
procedures
Flammable limits
Fire and Explosion
Hazards
300°C
CLOSED CUP: 142 to 150°C
Not available.
Use flooding quantities of water. Do not use carbon dioxide or halogenated compounds. Wear adequate personal
protection to
prevent contact with material or its combustion products. Self contained breathing apparatus with a full facepiece operated in a pressure demand or other positive pressure mode. Evacuate surrounding area Cool containing vessels with flooding
quantities
of water until well after fire is out. Fight fire from maximum distance using unmanned hose or monitor nozzles.
Highly flammable solid. Oxidizing material (contributes to combustion of other materials) Avoid contact with a
combustible material (wood, paper, oil, clothing...). Explodes if heated above 300°C. Explosive when dry. Can
explode
on impact if water content is 10% or below. Container explosion may occur under fire conditions or when heated.
When
contaminated, it is very sensitive. Risk of explosion by shock, friction, fire or other sources of ignition Contact
with
other material may form shock, heat or friction sensitive mixtures Forms very sensitive explosive metallic
compounds
The product is sensitive to impact. The product is sensitive to static discharge. Emits toxic fumes under fire
conditions.
Section IV. Fire and Explosion Data
Effects of Acute
Exposure
Routes of entry Inhalation and ingestion Eye contact, Skin contact. Skin absorption.
Ingestion Inhalation
Skin
Eye Causes severe irritation.
Prolonged exposure may result in skin burns and ulcerations May cause yellow discoloration of the skin and hair. May
cause
allergic skin reaction (dermatitis, eczema, edema, desquamation, etc...). Readily absorbed through skin. See inhalation
and ingestion. May cause sensitization.
Material is irritating to mucous membranes and upper respiratory tract. May cause coughing, fever, headache,
nausea,
vomiting, weakness, muscle pain, ulceration, bronchitis, nephritis, liver, kidney and blood damage, convulsions,
collapse.
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Toxicl Causes gastrointestinal irritation May cause headache, nausea, vomiting, dizziness, fever, prostration,
stupor, diarrhea, abdominal pain, hematuria, nephritis, anuria, polyuria, hepatitis, albuminuria, liver, kidney and blood
damage, convulsions, collapse.
Oxides of carbon and nitrogen.
Section vl. First Aid Measures
Section V. Toxicological Properties
Corrosive to metals. Risk of explosion by shock, friction, fire or other sources of ignition Contact with other
material
may form shock, heat or friction sensitive mixtures. Forms very sensitive explosive metallic compounds.
Hazardous
polymerization will not occur.
If conscious, wash out mouth with water. Have conscious person drink several glasses of water or milk. Induce
vomiting
by sticking finger in throat Lower the head so that the vomit will not reenter the mouth and throat. Seek
immediate
medical attention. Never give anything by mouth to an unconscious or convulsing person.
Hazardous decomp.
products
Stability
Incompatibility Explosive when dry. Keep wetted with >30% water. Conditions to avoid High temperatures, sparks, open flames,
all other sources of ignition, friction, shock, metals, and contamination.
Not available. Contact with metals (especially lead, zinc, iron, copper, calcium, nickel, mercury, aluminum), metal salts, alkaline
materials (plaster, concrete, bases, alkalis, sodium hydroxide, potassium hydroxide, ammonia, amines, lime,
soda ash,
carbonates, etc...) and aromatic hydrocarbons may form friction, shock, and/or heat sensitive materials. May
explode
with oxidizing agents, reducing agents, perchlorates, combustible materials, organic materials, and other
materials.
Section Vll. Reactivity Data
Reaction Products
PICRIC ACID page 3/4
IMMEDIATELY flush eyes with copious quantities of water for at least 15 minutes holding lids apart to ensure
flushing of the entire surface Call a physician. DO NOT use an eye ointment
Remove patient to fresh air. Administer approved oxygen supply if breathing is difficult. Administer artificial
respiration or
CPR if breathing has ceased. Seek immediate medical attention.
Eye contact
Skin contact Inhalation
Ingestion
Immediately flush skin with plenty of water and soap for at least 15 minutes while removing contaminated clothing
and shoes. Call a physician. Wash contaminated clothing before reusing
Effects of Chronic
Overexposure
May cause dermatitis, skin eruptions, anemia, diarrhea, ulceration of the eyes, central nervous system
depression (headache, nausea, vomiting, dizziness, etc .), jaundice and severe nephritis, liver, kidney and blood damage.
Suspect mutagen. Carcinogenic effects: Not available. Teratogenic effects: Not available. Toxicity of the product to the
reproductive system: Not available. To the best of our knowledge the chronic toxicity of this substance has not been fully
investigated. While the company believes the data set forth herein are accurate as of the date hereof, the company makes no
warranty with respect thereto
"People and Technology Creating a Better Environment"
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ENVIRONMENTAL SERVICES'
and expressly disclaims all liability for reliance thereon. Such data are offered solely for your consideration,
investigation and verification.
Section X. Other Information
Waste disposal Storage and Handling
Spill and leak
Protective Clothing in
case of spill and leak
According to all applicable regulations Harmful to aquatic life at very low concentrations Can be dangerous if
allowed to
enter drinking water intakes. Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds, or
rivers.
Evacuate the area. Eliminate all sources of ignition. Keep substance damp using water spray. Sweep up and
place in container for disposal Dilute with a large volume of water. Do not use metal containers. Use non-sparking tools.
Ventilate area and wash spill site after material pick up is complete. DO NOT empty into drains DO NOT touch
spilled
material. Avoid contact with a combustible material (wood, paper, oil, clothing...). DO NOT use metal tools or
equipment.
Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves. Full suit.
Store in a cool place away from heated areas, sparks, and flame Store in a well ventilated area Store away from incompatible materials. Do not add any other material to the container Do not wash down the drain Avoid shock and friction Do not breathe dust. In case of insufficient ventilation, wear suitable
respiratory equipment Keep away from combustible material. Keep away from direct sunlight or strong incandescent light. Keep container tightly closed.
Manipulate under an adequate fume hood Avoid raising dust. Use non-sParking tools. Empty containers may contain a hazardous residue Handle and open container
with care Minimize dust generation and exposure - use dust mask or appropriate protection. Take off immediately all contaminated clothing. Avoid contact
with a combustible material (wood, paper, oil, clothing...). This product must be manipulated by qualified personnel. Do not get in eyes, on skin, or on clothing Wash
well after use. In accordance with good storage and handling practices Do not allow smoking and food consumption while handling Do not use pressure to dispense Since the product is unstable, avoid sudden shocks like dropping or rolling Do not drop, roll or skid container May react if roughly manipulated. Do not
expose closed containers above 25°C Keep above freezing point Can be stored for up to 24 months Keep wetted with >30% water Use explosion proof equipment. Do not use metal containers or lids Discard product after expiration date Prolonged storage at >30°C have been reported to result in a less stable crystalline
form, which is orange in color This material is very shock sensitive In case of accident or if you feel unwell, seek medical advice immediately (show the label when possible ). Ground the container while dispensing. Ground all equipment containing material
Section VIIL Preventive Measures PICRIC ACID page 4/4
Splash goggles. Impervious neoprene gloves, apron, coveralls, and/or other resistant protective clothing Sufficient to protect skin Wear dust mask If more than TLV, do not breathe vapor Wear self-contained breathing apparatus. Do not wear contact lenses. Make eye bath and emergency shower available. Ensure that eyewash station and safety shower is proximal to the work-station location.
Section IX. Protective Measures
Engineering controls Use in a chemical fume hood to keep airborne levels below recommended exposure limits.
Use explosion-proof ventilation
equipment Do not use in unventilated spaces.
Protective clothing
Prepared by MSDS Department/Département de F.S.. Validated 10-Nov-2009
Telephone# [phone]
CAS# 88-89-1
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Code AC-7505
Formula weight
Supersedes
229.11
PICRIC ACID
(NO2)3C6H20H
Carbazotic acid, 2-Hydroxy-1,3,5-trinitrobenzene, Nitroxanthic acid, Phenol trinitrate, 2,4,6-Trinitrophenol,
Picronitric acid, Melinite, AC-7505, AC-7506, 70978, 70986
For laboratory use only. Anachemia Canada.
255 Norman
Lachine (Montreal), Que
H8R 1A3
Section II. Ingredients
Material Safety 1tta Sheet
Synonyms
Chemical formula
Material uses WHMIS Protective Clothing TDG Road/Rail
Section I. Product Identification and Uses
Not available.
Supplier
Product name
255 Norman.
Lachine (Montreal), Que
H8R 1A3 PIN: UN1344 PG: I
WHMIS CLASS: B-4 D-1B D-2B E F TDG CLASS: 4.1 1) PICRIC ACID 88-89-1 <70 Exposure limits: ACGIH TWA 0.1
mg/m3: 2) WATER 7732-18-5 >30 Not established by ACGIH
PICRIC ACID:
ORAL (LD50): Acute: 200 mg/kg (Rat).
ORAL (LDLo): Acute' 100 mg/kg (Guinea pig). 120 mg/kg (Rabbit)
INTRAPERITONEAL (LD50)• Acute: 56300 ug/kg (Mouse)
Toxicity values of the
hazardous ingredients
Name CAS # %
EMERGENCY NUMBERS: (USA) CHEMTREC : 1(800) 424-9300 (24hrs) (CAN) CANUTEC : 1(613) 996-6666 (24hrs)
(USA) Anachemia : 1(518) 297-4444
(CAN) Anachemia : 1(514) 489-5711
TLV
Section V. Toxicological Properties
Harmful by ingestion, inhalation or skin absorption. Poison. Irritant. Target organs: liver, kidneys, blood, skin,
eyes.
75 mg/m3 (PICRIC ACID) is immediately dangerous to life or health.
Section III. Physical Data
Physical state and
appearance / Odor
Percent volatile
pH (1% soln/water)
Freezing point
Boiling point
Vapor pressure
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leanHarbir'
ENVIRONMENTAL SERVICES°
Odor threshold
Specific gravity
Vapor density
Water/oil dist. coeff.
Evaporation rate
Solubility
»30%
Not available.
120-123°C (Dry)
Explodes above 300°C
1.763 (Water = 1)
7.9 (Air = 1)
1 mmHg @ 195°C
0.0093325
Not available.
Partially soluble in cold water
Not available.
Yellow, odorless crystals.
PICRIC ACID page 2/4 Auto-ignition temperature
Fire degradation
products
Flash point
Fire extinguishing
procedures
Flammable limits
Fire and Explosion Hazards
300°C
CLOSED CUP: 142 to 150°C
Not available.
Use flooding quantities of water. Do not use carbon dioxide or halogenated compounds. Wear adequate personal
protection to
prevent contact with material or its combustion products. Self contained breathing apparatus with a full facepiece
operated in a pressure demand or other positive pressure mode Evacuate surrounding area. Cool containing vessels with flooding quantities of water until well after fire is out. Fight fire from maximum distance using unmanned hose or monitor nozzles.
Highly flammable solid. Oxidizing material (contributes to combustion of other materials). Avoid contact with a
combustible material (wood, paper, oil, clothing...). Explodes if heated above 300°C. Explosive when dry. Can
explode
on impact if water content is 10% or below. Container explosion may occur under fire conditions or when heated.
When
contaminated, it is very sensitive. Risk of explosion by shock, friction, fire or other sources of ignition Contact
with
other material may form shock, heat or friction sensitive mixtures. Forms very sensitive explosive metallic
compounds.
The product is sensitive to impact The product is sensitive to static discharge. Emits toxic fumes under fire
conditions.
Section IV. Fire and Explosion Data
Effects of Acute
Exposure
Routes of entry Inhalation and ingestion. Eye contact. Skin contact. Skin absorption.
Ingestion
Inhalation
Skin
Eye Causes severe irritation.
Prolonged exposure may result in skin burns and ulcerations. May cause yellow discoloration of the skin and hair. May
cause
allergic skin reaction (dermatitis, eczema, edema, desquamation, etc...). Readily absorbed through skin. See inhalation
and ingestion. May cause sensitization.
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Material is irritating to mucous membranes and upper respiratory tract. May cause coughing, fever, headache,
nausea, vomiting, weakness, muscle pain, ulceration, bronchitis, nephritis, liver, kidney and blood damage, convulsions,
collapse. Toxici Causes gastrointestinal irritation. May cause headache, nausea, vomiting, dizziness, fever, prostration,
stupor, diarrhea, abdominal pain, hematuria, nephritis, anuria, polyuria, hepatitis, albuminuria, liver, kidney and blood
damage,
convulsions, collapse.
Oxides of carbon and nitrogen.
Section VI. First Aid Measures
Section V. Toxicological Properties
Corrosive to metals Risk of explosion by shock, friction, fire or other sources of ignition. Contact with other
material may form shock, heat or friction sensitive mixtures. Forms very sensitive explosive metallic compounds
Hazardous
polymerization will not occur.
If conscious, wash out mouth with water. Have conscious person drink several glasses of water or milk. Induce
vomiting
by sticking finger in throat Lower the head so that the vomit will not reenter the mouth and throat. Seek
immediate
medical attention. Never give anything by mouth to an unconscious or convulsing person.
Hazardous decomp.
products
Stability
Incompatibility
Explosive when dry. Keep wetted with >30% water. Conditions to avoid: High temperatures, sparks, open flames,
all
other sources of ignition, friction, shock, metals, and contamination.
Not available.
Contact with metals (especially lead, zinc, iron, copper, calcium, nickel, mercury, aluminum), metal salts, alkaline
materials (plaster, concrete, bases, alkalis, sodium hydroxide, potassium hydroxide, ammonia, amines, lime,
soda ash, carbonates, etc...) and aromatic hydrocarbons may form friction, shock, and/or heat sensitive materials May
explode
with oxidizing agents, reducing agents, perchlorates, combustible materials, organic materials, and other
materials.
Section VII. Reactivity Data
Reaction Products
PICRIC ACID page 3/4
IMMEDIATELY flush eyes with copious quantities of water for at least 15 minutes holding lids apart to ensure
flushing of the entire surface. Call a physician. DO NOT use an eye ointment Remove patient to fresh air. Administer approved oxygen supply if breathing is difficult. Administer artificial
respiration or
CPR if breathing has ceased. Seek immediate medical attention.
Eye contact
Skin contact
Inhalation
Ingestion Immediately flush skin with plenty of water and soap for at least 15 minutes while removing contaminated clothing
and
shoes. Call a physician Wash contaminated clothing before reusing.
Effects of Chronic
Overexposure May cause dermatitis, skin eruptions, anemia, diarrhea, ulceration of the eyes, central nervous system
depression (headache, nausea, vomiting, dizziness, etc...), jaundice and severe nephritis, liver, kidney and blood damage.
Suspect mutagen Carcinogenic effects: Not available. Teratogenic effects Not available. Toxicity of the product to the
reproductive
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eanHari?
ENVIRONMENTAL SERVICES'
system: Not available. To the best of our knowledge the chronic toxicity of this substance has not been fully
investigated.
While the company believes the data set forth herein are accurate as of the date hereof, the company makes no
warranty with respect thereto
and expressly disclaims all liability for reliance thereon. Such data are offered solely for your consideration,
investigation and verification.
Section X. Other Information
Waste disposal
Storage and Handling
Spill and leak
Protective Clothing in
case of spill and leak
According to all applicable regulations. Harmful to aquatic life at very low concentrations. Can be dangerous if
allowed to
enter drinking water intakes Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds, or
rivers.
Evacuate the area. Eliminate all sources of ignition. Keep substance damp using water spray. Sweep up and
place in
container for disposal. Dilute with a large volume of water Do not use metal containers. Use non-sparking tools.
Ventilate area and wash spill site after material pick up is complete. DO NOT empty into drains. DO NOT touch
spilled
material. Avoid contact with a combustible material (wood, paper, oil, clothing.. ). DO NOT use metal tools or
equipment.
Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves. Full suit. Store in a cool place away from heated areas, sparks, and flame Store in a well ventilated area Store away from incompatible materials Do not
add any other material to the container Do not wash down the drain Avoid shock and friction Do not breathe dust In case of insufficient ventilation, wear suitable respiratory
equipment Keep away from combustible material Keep away from direct sunlight or strong incandescent light Keep container tightly closed Manipulate under an adequate fume hood. Avoid raising dust Use non-sparking tools Empty containers may contain a hazardous residue Handle and open container with care Minimize dust generation and exposure - use dust mask or appropriate protection. Take off immediately all contaminated clothing Avoid contact
with a combustible material (wood, paper, oil, clothing., ). This product must be manipulated by qualified personnel Do not get in eyes, on skin, or on clothing. Wash well after use In accordance with good storage and handling practices Do not allow smoking and food consumption while handling. Do not use pressure to
dispense Since the product is unstable, avoid sudden shocks like dropping or rolling Do not drop, roll or skid container May react if roughly manipulated Do not expose closed containers above 25°C Keep above freezing point. Can be stored for up to 24 months Keep wetted with >30% water Use explosion proof equipment Do not use
metal containers or lids Discard product after expiration date Prolonged storage at >30°C have been reported to result in a less stable crystalline form, which is orange in color This material is very shock sensitive. In case of accident or if you feel unwell, seek medical advice immediately (show the label
when possible )
Ground the container while dispensing Ground all equipment containing material Section VIII. Preventive Measures PICRIC ACID page 4/4
Splash goggles Impervious neoprene gloves, apron, coveralls, and/or other resistant protective clothing Sufficient to protect
skin Wear dust mask If more than TLV, do not breathe vapor Wear self-contained breathing apparatus Do not wear contact lenses Make eye bath
and emergency shower available Ensure that eyewash station and safety shower is proximal to the work-station location
Section IX. Protective Measures
Engineering controls Use in a chemical fume hood to keep airborne levels below recommended exposure limits
Use explosion-proof ventilation
equipment. Do not use in unventilated spaces Protective clothing
Prepared by MSDS Department/Département de F.S.. Validated 10-Nov-2009
Telephone# [phone]
Highly flammable solid! Toxic! Oxidizing agent. Sensitizer! Suspected mutagen! Dangerously
reactive material! irritant! Do not breathe dust. Avoid all contact with the product. Avoid
prolonged or repeated exposure. Use in a chemical fume hood. Keep away from heat, sparks,
flame, friction, shock, and contaminaton Risk of explosion by shock, friction, fire, other sources
of ignition Keep at temperature not exceeding 25°C. Decomposes violently when heated above
300°C When contaminated, it is very sensitive Contact with other material may form shock,
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ENVIRONMENTAL SERVICES°
SIGMA-ALDRICH
MATERIAL SAFETY DATA SHEET
Date Printed: 04/23/2007
Date Updated: 02/04/2006
Version 1.4
Section 1 - Product and Company Information
Product Name 2-VINYLPYRIDINE, 97%
Product Number 132292
Brand ALDRICH
Company Sigma-Aldrich
Address 3050 Spruce Street
SAINT LOUIS MO 63103 US
Technical Phone: [phone]
Fax: [phone]
Emergency Phone: [phone]
Section 2 - Composition/Information on Ingredient
Substance Name CAS # SARA 313
2-VINYLPYRIDINE MONOMER, STABILIZED 100-69-6 No
Formula C7H7N
Synonyms 2-Ethenylpyridine * Pyridine, 2-ethenyl- (9CI)
alpha-Vinylpyridine * 2-Viny1pyridine
RTECS Number: UU1040000
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Combustible (USA) Flammable (EU). Toxic.
Harmful by inhalation. Toxic if swallowed. Causes burns. May
cause
sensitization by inhalation and skin contact.
Lachrymator. Unpleasant odor.
HMIS RATING
HEALTH: 3*
FLAMMABILITY: 2
REACTIVITY: 1
NFPA RATING
HEALTH: 3
FLAMMABILITY: 2
REACTIVITY: 1
*additional chronic hazards present.
For additional information on toxicity, please refer to
Section 11.
Section 4 - First Aid Measures
ORAL EXPOSURE
If swallowed, wash out mouth with water provided person is
conscious. Call a physician immediately. Do not induce
vomiting.
INHALATION EXPOSURE
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If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give
oxygen.
DERMAL EXPOSURE
In case of skin contact, flush with copious amounts of water
for
at least 15 minutes. Remove contaminated clothing and shoes.
Call a physician.
EYE EXPOSURE
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
Section 5 - Fire Fighting Measures
FLASH POINT
118.4 °F 48 °C Method: closed cup
AUTOIGNITION TEMP
N/A
FLAMMABILITY
N/A
EXTINGUISHING MEDIA
Suitable: Carbon dioxide, dry chemical powder, or appropriate
foam.
FIREFIGHTING
Protective Equipment: Wear self-contained breathing apparatus
and protective clothing to prevent contact with skin and
eyes
Specific Hazard(s): Combustible liquid. Emits toxic fumes
under
fire conditions.
Section 6 - Accidental Release Measures
PROCEDURE TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and
heavy
rubber gloves.
METHODS FOR CLEANING UP
Cover with dry-lime, sand, or soda ash. Place in covered
containers using non-sparking tools and transport outdoors.
Ventilate area and wash spill site after material pickup is
complete.
Section 7 - Handling and Storage
HANDLING
User Exposure: Do not breathe vapor. Do not get in eyes, on
skin, on clothing. Avoid prolonged or repeated exposure.
STORAGE
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Suitable: Keep tightly closed. Keep away from heat and open
flame.
Store at -20°C
SPECIAL REQUIREMENTS
Heat sensitive.
ALDRICH - 132292 www sigma-aldrich.com Page 2
Section 8 - Exposure Controls / PPE
ENGINEERING CONTROLS
Use only in a chemical fume hood. Safety shower and eye bath.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory: Use respirators and components tested and
approved
under appropriate government standards such as NIOSH (US) or
CEN
(EU) Where risk assessment shows air-purifying respirators
are
appropriate use a full-face respirator with multi-purpose
combination (US) or type ABEK (EN 14387) respirator
cartridges as
a backup to engineering controls. If the respirator is the
sole
means of protection, use a full-face supplied air respirator.
Hand: Compatible chemical-resistant gloves.
Eye: Chemical safety goggles.
Other: Faceshield (8-inch minimum).
GENERAL HYGIENE MEASURES
Wash contaminated clothing before reuse. Discard contaminated
shoes. Wash thoroughly after handling.
Section 9 - Physical/Chemical Properties
Appearance Physical State: Clear liquid
Color: Dark - brown
Odor: Unpleasant odor.
Property Value At Temperature or Pressure
Molecular Weight 105.14 AMU
pH 8
BP/BP Range 48.0 - 51.0 °C 12 mmHg
MP/MP Range - 50.0 °C
Freezing Point N/A
Vapor Pressure 10 mmHg 44.5 °C
Vapor Density N/A
Saturated Vapor Conc. N/A
SG/Density 0.974 g/cm3
Bulk Density N/A
Odor Threshold N/A
Volatile% N/A
VOC Content N/A
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Water Content N/A
Solvent Content N/A
Evaporation Rate N/A
Viscosity N/A
Surface Tension N/A
Partition Coefficient N/A
Decomposition Temp. N/A
Flash Point 118.4 °F 48 °C Method: closed cup
Explosion Limits N/A
Flammability N/A
Autoignition Temp N/A
Refractive Index 1.549
Optical Rotation N/A
Miscellaneous Data N/A
Solubility N/A
N/A = not available
Section 10 - Stability and Reactivity
ALDRICH - 132292 www.sigma-aldrich.com Page 3
STABILITY
Stable: Stable.
Conditions to Avoid: Heat.
Materials to Avoid: Strong oxidizing agents, Strong acids,
Strong
bases.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon
dioxide,
Nitrogen oxides.
STABILIZERS PRESENT
Stabilized with 0.1 wt. % tert-butylcatechol.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
Section 11 - Toxicological Information
ROUTE OF EXPOSURE
Skin Contact: Causes burns.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: Causes burns. Lachrymator.
Inhalation: Material is extremely destructive to the tissue
of
the mucous membranes and upper respiratory tract. Harmful if
inhaled.
Ingestion: Toxic if swallowed.
SENSITIZATION
Sensitization: May cause allergic respiratory and skin
reactions
SIGNS AND SYMPTOMS OF EXPOSURE
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To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly
investigated.
Symptoms of exposure may include burning sensation, coughing,
wheezing, laryngitis, shortness of breath, headache, nausea,
and
vomiting. Inhalation may result in spasm, inflammation and
edema
of the larynxand bronchi, chemical pneumonitis, and pulmonary
edema. Material is extremely destructive to tissue of the
mucous
membranes and upper respiratory tract, eyes, and skin.
TOXICITY DATA
Inhalation
Rat
5,500 ppm
LC50
Oral
Rat
100 mg/kg
LD50
Inhalation
Rat
610 mg/m3
LC50
Oral
Mouse
420 mg/kg
LD50
Inhalation
ALDRICH - 132292 www.sigma-aldrich.com Page 4
Mouse
460 mg/m3
LC50
Oral
Mammal
415 mg/kg
LD50
Section 12 - Ecological Information
Section 13 - Disposal Considerations
APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION
Contact a licensed professional waste disposal service to
dispose
of this material. This combustible material may be burned in
a
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chemical incinerator equipped with an afterburner and
scrubber.
Observe all federal, state, and local environmental
regulations.
Section 14 - Transport Information
DOT
Proper Shipping Name: Vinylpyridines, inhibited
UN#: 3073
Class: 6.1
Packing Group: Packing Group II
Hazard Label: Flammable liquid
Hazard Label: Corrosive
PIH: Not PIH
IATA
Proper Shipping Name: Vinylpyridines, stabilized
IATA UN Number: 3073
Hazard Class: 6.1
Packing Group: II
Section 15 - Regulatory Information
EU ADDITIONAL CLASSIFICATION
Symbol of Danger: T
Indication of Danger: Toxic.
R: 10-20-25-34-42/43
Risk Statements: Flammable. Harmful by inhalation. Toxic if
swallowed. Causes burns. May cause sensitization by
inhalation
and skin contact.
S: 16-23-26-36/37/39-45
Safety Statements: Keep away from sources of ignition - no
smoking. Do not breathe vapor. In case of contact with eyes,
rinse immediately with plenty of water and seek medical
advice.
Wear suitable protective clothing, gloves, and eye/face
protection. In case of accident or if you feel unwell, seek
medical advice immediately (show the label where possible).
US CLASSIFICATION AND LABEL TEXT
Indication of Danger: Combustible (USA) Flammable (EU).
Toxic.
Risk Statements: Harmful by inhalation. Toxic if swallowed.
Causes burns. May cause sensitization by inhalation and skin
contact.
Safety Statements: Keep away from sources of ignition - no
smoking. Do not breathe vapor. In case of contact with eyes,
rinse immediately with plenty of water and seek medical
advice.
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ENVIRONMENTAL SERVICES'
Wear suitable protective clothing, gloves, and eye/face
protection. In case of accident or if you feel unwell, seek
medical advice immediately (show the label where possible).
US Statements: Lachrymator. Unpleasant odor.
UNITED STATES REGULATORY INFORMATION
SARA LISTED: No
TSCA INVENTORY ITEM: Yes
CANADA REGULATORY INFORMATION
WHMIS Classification: This product has been classified in
accordance with the hazard criteria of the CPR, and the MSDS
contains all the information required by the CPR.
DSL: Yes
NDSL: No
Section 16 - Other Information
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a
guide. The
information in this document is based on the present state of
OUT
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich
Inc ,
shall not be held liable for any damage resulting from
handling or
from contact with the above product. See reverse side of
invoice
or packing slip for additional terms and conditions of sale.
Copyright 2007 Sigma-Aldrich Co. License granted to make
unlimited
paper copies for internal use only.
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