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DAQ-2024-004333
1 DAQC-1342-23 Site ID 14210 (B4) MEMORANDUM TO: STACK TEST FILE – OVINTIV USA INC. – Pleasant Valley Compressor Station THROUGH: Rik Ombach, Minor Source Oil and Gas Compliance Section Manager FROM: Kyle Greenberg, Environmental Scientist DATE: December 13, 2023 SUBJECT: Source: Compressor Engine Unit #5 - Caterpillar G3516 LE - SN: WPW01760 Location: Duchesne County, Utah Contact: Ryan Zillner; 720-876-3144 Tester: Great Plains Analytical Site ID #: 14210 Permit/AO #: DAQE-AN142100007-23, dated September 20, 2023 Subject: Review of Stack Test Report Dated November 8, 2023 On November 20, 2023, Utah Division of Air Quality (DAQ) received a test report for compressor engine unit #5 at Pleasant Valley Compressor Station in Duchesne County, Utah. Testing was performed on November 2, 2023, to demonstrate compliance with the emission limits found in Condition II.B.5 of DAQE-AN142100007-23 and 40 CFR Part 60 Subpart JJJJ. The DAQ-calculated test results are: Source Test Date Test Method Pollutant Tester Results DAQ Results Limits Unit 5 SN: WPW01760 Nov. 2, 2023 ASTM D6348-03 NOx 20.004 ppmvd@15%O2 1.222 lb/hr 0.481 g/hp-hr 20.012 ppmvd@15%O2 1.216 lb/hr 0.479 g/hp-hr 82 ppmvd@15% O2 1.48 lb/hr 1.0 g/hp-hr CO 0.0 ppmvd@15%O2 0.0 lb/hr 0.0 g/hp-hr 0.000 ppmvd@15%O2 0.000 lb/hr 0.000 g/hp-hr 270 ppmvd@15% O2 0.36 lb/hr 2.0 g/hp-hr VOC 13.347 ppmvd@15%O2 0.782 lb/hr 0.307 g/hp-hr 13.352 ppmvd@15%O2 0.779 lb/hr 0.306 g/hp-hr 60 ppmvd@15% O2 0.98 lb/hr 0.70 g/hp-hr DEVIATIONS: None. CONCLUSION: The stack test appears to be acceptable. 2 RECOMMENDATION: It is recommended that the emissions from compressor engine unit #5 should be considered to have been in compliance with its emission limits of NOx, CO, and VOCs during testing. HPV: N/A ATTACHMENTS: DAQ stack test review excel spreadsheets, Ovintiv stack test reports Emissions Ovintiv USA Inc. Pleasant Valley Compressor Station Duchesne County, Utah Unit 5 - Caterpillar G3516 LE - SN:WPW01760 Test Date: 11/2/23 Run #1 2 3 Average Start Time 9:05 10:24 11:39 Stop Time 10:05 11:24 12:39 Sample Duration (minutes)60 60 60 BHP Engine Load - Actual (bhp) 1120 1195 1146 1154 DS Stack Diameter (inches)16.0 16.0 16.0 16.0 PAVG Average (Delta P)½ (" H2O)½1.3252 1.3750 1.3866 1.3623 CP Pitot Tube Constant (unitless)0.99 0.99 0.99 0.99 TS Stack Temperature (°F)743 758 754 752 Pbar Barometric Pressure (" Hg)24.93 24.90 24.90 24.91 Ps Stack Pressure ('' H2O)0.13 0.14 0.14 0.14 O2%vd O2 (%vd)8.7 8.7 8.7 8.7 CO2%vd CO2 (%vd)5.8 5.8 5.8 5.8 N2%vd N2 (%vd)85.5 85.5 85.6 85.5 dry NOX (ppmvd)44.6 40.0 39.7 41.4 dry CO (ppmvd) 0.0 0.0 0.0 0.0 wet NMEOC (ppmvw as C3H8)22.9 25.3 25.6 24.6 Run #1 2 3 Average Bws Measured Moisture Content (%/100)0.112 0.111 0.110 0.111 Bws Saturated Moisture Content (%/100)307.170 333.606 326.513 322.430 Bws Actual Moisture Content (%/100)0.112 0.111 0.110 0.111 MD Molecular Weight Dry (lb/lb-mole)29.28 29.27 29.27 29.27 MA Molecular Weight Wet (lb/lb-mole)28.02 28.02 28.03 28.02 VS Gas Velocity (ft/sec)147.2 153.7 154.8 151.9 FACFM Gas Flow (acfm)12328 12878 12965 12724 FDSCFM Gas Flow (dscfm)4004 4130 4174 4103 FWSCFM Gas Flow (wscfm)4510 4648 4694 4617 FKWSCFH Gas Flow (kwscfh)271 279 282 277 FKWSCFM Gas Flow (kwscfm)5 5 5 5 lb/hr Gas Flow (lb/hr) 19679 20283 20488 20150 Fo Fo (unitless)2.101 2.117 2.126 2.115 wet O2 (%vw)7.7 7.7 7.7 7.7 wet CO2 (%vw)5.2 5.1 5.1 5.1 wet NOX (ppmvw)39.601 35.608 35.294 36.835 15 NOX (ppmvd @ 15% O2)21.552 19.340 19.145 20.012 82.0 lb/hr NOX (lb/hr)1.278 1.184 1.185 1.216 1.5 g/bhp-hr NOX (g/bhp-hr)0.518 0.449 0.469 0.479 1.00 wet CO (ppmvw) 0.000 0.000 0.000 0.000 15 CO (ppmvd @ 15% O2)0.000 0.000 0.000 0.000 270.0 lb/hr CO (lb/hr) 0.000 0.000 0.000 0.000 0.36 g/bhp-hr CO (g/bhp-hr) 0.000 0.000 0.000 0.000 2.0 dry NMEOC (ppmvd as C3H8)25.745 28.444 28.745 27.644 15 NMEOC (ppmvd as C3H8 @ 15% O2)12.446 13.739 13.872 13.352 60 lb/hr NMEOC (lb/hr as C3H8)0.707 0.806 0.823 0.779 0.98 g/bhp-hr NMEOC (g/bhp-hr as C3H8)0.286 0.306 0.326 0.306 0.7 Permit Limits Field Reference Method Data Reference Method Calculations Page 1 of 5 Linearity Ovintiv USA Inc. Pleasant Valley Compressor Station Duchesne County, Utah Unit 5 - Caterpillar G3516 LE - SN:WPW01760 Test Date: 11/2/23 O2 21.2 9.00 0.0 8.6 Linearity Bias (Zero) 0.0 Linearity Bias (Span) 8.9 % 0.00 9.00 21.18 0.0 8.9 20.8 0.0 0.1 0.4 0.0 0.00% 1.46% 1.70% Span Bias Max Calibration Error Bias Check (Zero) Bias Check (Span) 2 3 4 Results 3 Zero Bias 4 Difference 1 4 Response 1 2 Gas Concentration 1 2 3 Linearity Information Gas Span Gas Value/Range Bias Gas Value Page 2 of 5 Run 1 Ovintiv USA Inc.Run 1 Pleasant Valley Compressor Station Duchesne County, Utah Start Time 9:05 Unit 5 - Caterpillar G3516 LE - SN:WPW01760 Run Length 60 Test Date: 11/2/23 Stop Time 10:05 O2 21.2 9.00 0.0 8.6 0.0 8.6 0.0% 1.5% 0.0% 0.0% Corrected O2 % 8.7 Run Length (Minutes) Uncorrected O2 % 60 8.3 Post Test Calibration Calibration Information Instrument Range Span Gas Value Gas Calibration Pretest Calibration Zero% Span% Zero% Span% Absolute Bias (Zero) Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Results Page 3 of 5 Run 2 Ovintiv USA Inc.Run 2 Pleasant Valley Compressor Station Duchesne County, Utah Start Time 10:24 Unit 5 - Caterpillar G3516 LE - SN:WPW01760 Run Length 60 Test Date: 11/2/23 Stop Time 11:24 O2 21.2 9.00 0.0 8.6 0.0 8.6 0.0% 1.5% 0.0% 0.0% Corrected O2 % 8.7 Run Length (Minutes) Uncorrected O2 % 60 8.3 Calibration Information Results Absolute Bias (Zero) Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Span% Span% Gas Instrument Range Post Test Calibration Zero% Span Gas Value Calibration Pretest Calibration Zero% Page 4 of 5 Run 3 Ovintiv USA Inc.Run 3 Pleasant Valley Compressor Station Duchesne County, Utah Start Time 11:39 Unit 5 - Caterpillar G3516 LE - SN:WPW01760 Run Length 60 Test Date: 11/2/23 Stop Time 12:39 O2 21.2 9.00 0.0 8.6 0.0 8.6 0.0% 1.5% 0.0% 0.0% Corrected O2 % 8.7 Run Length (Minutes) Uncorrected O2 % 60 8.3 Absolute Bias (Span) Absolute Drift (Zero) Absolute Drift (Span) Calibration Information Span Gas Value Calibration Pretest Calibration Gas Post Test Calibration Instrument Range Zero% Results Absolute Bias (Zero) Span% Span% Zero% Page 5 of 5 11/08/2023 VIA Stack Test Report Submission: https://utahgov.co1.qualtrics.com/jfe/form/SV_3dSxf7JSzy4jwGh Rik Ombach Manager, Minor Source Compliance Utah Department of Environmental Quality Division of Air Quality 195 North 1950 West Salt Lake City, Utah 84116 RE: Performance Test Reports Ovintiv USA Inc. Pleasant Valley Compressor Station (Approval Order: DAQE-AN142100007-23) Ranch Compressor Station (Approval Order: DAQE-AN14338008-23) Duchesne County Dear Mr. Ombach: Ovintiv USA Inc. is submitting the attached performance test reports for the spark ignition internal combustion engines that are subject to the following requirements: • 40 CFR Part 60 Subpart JJJJ, 40 CFR §60.8, 40 CFR §60.4243(b)(2)(ii), 40 CFR §60.4245(d) • Approval Order II.B Requirements and Limitations Facility Unit Description Manufacturer & Model Serial Number Date of Performance Testing Pleasant Valley Compressor Station Unit 5 Caterpillar G3516LE WPW01760 11/02/2023 Ranch Compressor Station Unit 4 Caterpillar G3606 3XF00116 11/02/2023 Results from the performance tests indicate that the engines have demonstrated compliance with emission limit requirements. If you have any questions, please contact me at 720-876-3144 or ryan.zillner@ovintiv.com. Sincerely, Ryan Zillner Senior Air Quality Engineer Enclosures Performance Test Report Test Type: Initial Test Date: 11/2/2023 Caterpillar G3516 LE Lean Burn (4 Cycle) DOM: 10/26/07 303 W. 3rd St Elk City , OK 73644(580) 225-0403 Test Started:Test Completed:09:05 AM 12:59 PM Source: Unit Number: 5 Serial Number: WPW01760 Engine Hours:45165 Permit #: #DAQE-AN142100007-23 Location: Duchesne County, Utah Prepared on Behalf of: Ovintiv USA Inc. Pleasant Valley Compressor Station 40 CFR Part 60 Subpart JJJJ CO NOx NMNEHC 0.360 1.480 0.980 0.000 1.222 0.782 0.000 41.431 27.645 2.000 1.000 0.700 0.000 0.481 0.307 Pass Pass Pass Pass Pass Pass Federal State Federal State Federal State Results lb/hr Results ppmvd Permit lb/hr Results g/hp-hr Permit g/hp-hr PASS ALL Index Tables Figures Appendices Table 5.1 (Run Summaries)................................................................ Table 6.1 (Volumetric Flow Rate Data)............................................... Table 6.2 (Stack Gas Measurements)................................................. Table 8.1 (Oxygen Calibration)........................................................... Annex Table 1.2.1 (Certified Calibration Bottle Concentrations)......... Annex Table 1.2.2 (Measurement System Capabilities)..................... Annex Table 1.3.1 (Test Specific Target Analytes)............................. Annex Table 4.1 (Measure System Capabilities)................................ Figure 6.1 (Location of Traverse Points per Method 1)....................... Annex Figure 1.4.1 (Sampling Train).................................................. Annex Figure 1.4.2 (Sampling Points)................................................. Annex Figure 1.4.3 (Sampling Port Locations).................................... Certified Calibration Bottle Certificates................................................ Tri Probe Certification via GD-031...................................................... GAS ALT 141_FTIR EPA.................................................................... Tester Qualifications (resume)............................................................ Raw Data............................................................................................ 27 Key Personnel.............................................................................1.0 3 Sampling System........................................................................2.0 3 Methods Used.............................................................................3.0 3 Test Summaries..........................................................................4.0 5 Run Summaries..........................................................................5.0 6 6 Volumetric Flow Rate Data.........................................................6.0 7 7 7 7 Calculations................................................................................7.0 8 9 12 12 13 15 13 14 14 20 25 28 29 Oxygen Calibration.....................................................................9 Engine Parameter Data Sheet....................................................10 QA/QC Results............................................................................11 Signature Page...........................................................................12.0 Appendices.................................................................................13.0 Bottle Certs.................................................................................2014.0 Tri Probe Certification via GD-031..............................................2515.0 GAS ALT 141_FTIR EPA............................................................16.0 Tester Qualifications (resume)....................................................2817.0 D6348 Annexes..........................................................................1211.0 18 19 26 8.0 9.0 10.0 Raw Data....................................................................................2918.0 1.0 Key Personnel GAS, Inc. JW 2.0 Sampling System The sampling system used consisted of a Stainless steel probe, heated Teflon line, gas conditioning system, and a Gasmet model DX4000 FTIR analyzer. The gas conditioning system used was a Gasmet Personal Sampling System with a Zirconium Oxide oxygen sensor. 3.0 Methods Used This extractive FTIR based field test method is used to quantify gas phase concentrations of multiple target analytes (CO, NOX, CH2O, & VOC's) from stationary source effluent. Because an FTIR analyzer is potentially capable of analyzing hundreds of compounds, this test method is not analyte or source specific. The analytes, detection levels, and data quality objectives are expected to change for any particular testing situation. It is the responsibility of the tester to define the target analytes, the associated detection limits for those analytes in the particular source effluent, and the required data quality objectives for each specific test program. Provisions are included in this test method that require the tester to determine critical sampling system and instrument operational parameters, and for the conduct of QA/QC procedures. Testers following this test method will generate data that will allow an independent observer to verify the valid collection, identification, and quantification of the subject target analytes. EPA Method 1 & 1A EPA Method 2 & 2C EPA Method 3A The purpose of the method is to provide guidance for the selection of sampling ports and traverse points at which sampling for air pollutants will be performed pursuant to regulations set forth in this part. This method is applicable for the determination of the average velocity and the volumetric flow rate of a gas stream. The average gas velocity in a stack is determined from the gas density and from measurement of the average velocity head with a standard pitot tube. Velocity readings are taken from each stack at 16 separate traverse points (Table 6.1) and used to determine the engines mass emissions rate, calculated utilizing the formulas seen in section 7.0 of this report. This is a procedure for measuring oxygen (O2) and carbon dioxide (CO2) in stationary source emissions using a continuous instrumental analyzer. Quality assurance and quality control requirements are included to assure that the tester collects data of known quality. Documentation to these specific requirements for equipment, supplies, sample collection and analysis, calculations, and data analysis will be included. ASTM D6348-03 Jeremiah Phillips 3 Aaron King Gas, Inc. 4.0 Test Summary T e s t S u m m a r y Site Verification Photos Gas, Inc. Unit 5 with a serial number of WPW01760 which is a Caterpillar G3516 LE engine located at Pleasant Valley Compressor Station and operated by Ovintiv USA Inc. was tested for emissions of: Carbon Monoxide, Oxides of Nitrogen, and Volatile Organic Compounds. The test was conducted on 11/2/2023 by Aaron King with Great Plains Analytical Services, Inc. All quality assurance and quality control tests were within acceptable tolerances. The engine is a natural gas fired Lean Burn (4 Cycle) engine rated at 1340 brake horse power (BHP) at 1400 RPM. The engine was operating at 1153 BHP and 1398 RPM which is 86.08% of maximum engine load during the test. The test HP calculation can be found on page 8. The engine was running at the maximum load available at the test site. This test will satisfy the testing requirements for 40 CFR Part 60 Subpart JJJJ. Unit 5 is authorized to operate under permit #DAQE-AN142100007-23. 4 4.0 Test Summary Engine/Compressor Specs Pleasant Valley Compressor StationLocation 5Unit ID Make Caterpillar Site Elevation ft.5343 Model G3516 LE Atmospheric Pressure psi.11.95 Serial Number WPW01760 Stack Diameter in.16 mfg. rated hp 1340 Yes 1400 Date of Manufacture 10/26/2007 Engine/Compressor Operation Run 2 Run 3 3 Run AveragesRun 1 Test Horsepower 1120 1195 1146 1153 1395 1400 1400 1398 Percent Load % Intake Manifold Pressure (hg) 83.55%89.19%85.50%86.08% 37.36 40.01 38.18 38.51 Intake Manifold Temperature (F)114.80 116.60 120.20 117.20 Ambient Conditions Ambient Temperature Dry (F)27.00 39.00 44.00 36.67 Exhaust Flow Data Q Stack (dscfh) Q Stack (dscm/hr) 241502.77 248706.28 251343.06 247184.04 6838.53 7042.51 7117.18 6999.41 Moisture Fraction Bws Fuel Consumption (Btu/h[-hr) 0.11 0.11 0.11 0.11 9283.08 9191.55 9251.55 9242.06 Fuel Flow (dscfh) Fuel (btu/scf)1020 1020 1020 1020 O2 F factor 8710.0 8710 8710 8710 Results Method 3A Corrected O2% Dry Moisture %11.17%11.07%11.03%11.09% T e s t S u m m a r y mfg. rated rpm Test RPM 8.69%8.68%8.67%8.68% Permitted Standards Results 5 Catalyst 0.0000.000 Run 1 Run 2 Run 3 3 Run Average Pass Permits 09:05 AM 10:24 AM 11:39 AM 11/2/2023 CO (g/hp-hr)0.000 0.0002.000 Pass StateFederal CO (ppmvw)0.000 0.000 0.000 0.000 CO (ppmvd)0.000 0.000 0.000 0.000 CO (mol wt) 28.01 CO (ppmvd) @15% O2 0.000 0.000 0.000 0.000 Fail CO (ppbvd) @15% O2 0.000 0.000 0.000 0.000 Fail 0.0000.000CO (lbs/hr)0.000 0.0000.360 Pass NOx (g/hp-hr)0.521 0.451 0.471 0.4811.000 Pass NOx (ppmvw)39.600 35.608 35.295 36.834 NOx (ppmvd)44.581 40.041 39.670 41.431 NOx (mol wt) 46.01 22.869 25.295 25.574 24.579NMNEHC (ppmvw) 25.746 28.445 28.743 27.645NMNEHC (ppmvd) NOx (ppbvd) @15% O2 21547.767 19328.691 19136.953 20004.470 Fail NOx (ppmvd) @15% O2 21.548 19.329 19.137 20.004 Fail NMNEHC (mol wt) 44.10 12443.835 13730.794 13865.955 13346.861 FailNMNEHC (ppbvd) @15% O2 0.288 0.307 0.327 0.3070.700 PassNMNEHC (g/hp-hr) 0.711 0.810 0.827 0.7820.980 PassNMNEHC (lbs/hr) 12.444 13.731 13.866 13.347 FailNMNEHC (ppmvd) @15% O2 NOx (lbs/hr)1.285 1.189 1.190 1.2221.480 Pass Gas, Inc. 5.0 Run Summaries Summary Source Run 1 R u n Table 5.1 Run Summaries S u m m a r i e s 6 0.00Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture % 0.00 0.00 38.61 0.00 0.99 0.00 39.60 0.27 22.87 0.18% 7.35% 0.00% 11.17% NMNEHC 0.00 41.71 1.97 43.68 20.74 7.35%11.16% 36.67 49.15 0.67 49.82 40.17 6.85%9.82% 0.00 35.52 0.00 35.52 25.00 7.35%11.18% 0.00 0.00 0.11 0.11 0.21 0.15%0.00% Avg. Wet NO2NO Summary Source Run 2 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 0.00 0.00 0.11 0.11 0.21 0.15%0.00% 0.00 35.78 0.00 35.78 25.12 7.35%11.08% 35.73 48.57 1.43 49.99 38.80 6.84%10.28% 0.00 35.44 0.00 35.44 25.47 7.34%11.07% 0.00 0.00 0.00 0.00 0.30 0.15%0.00% Avg. Wet 0.00 35.61 0.00 35.61 25.30 7.35%11.07% NO2NO Summary Source Run 3 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 0.00 35.08 0.00 35.08 25.73 7.35%11.04% 36.39 48.83 1.22 50.05 38.64 6.83%10.24% 0.00 35.51 0.00 35.51 25.42 7.33%11.02% 0.00 0.00 0.00 0.00 0.07 0.15%0.00% 0.00 0.00 0.00 0.00 0.30 0.15%0.00% Avg. Wet 0.00 35.30 0.00 35.30 25.57 7.34%11.03% NO2NO Gas, Inc. 6.0 Volumetric Flow Rate Data Volumetric Flow Rate Data .99 Stack diameter = Table 6.1. Data used for volumetric flow rate (Method 2) 16 inches or:1.33 feet. or:1.4 Square Feet Run 1 Average Pitot Tube Coefficient Cp(std)= H2O CO2 O2 CO Molecular Weight Stack Gas dry basis (Md) Molecular Weight Stack Gas wet basis (Ms) Stack Static Pressure (Pg) Stack Static Pressure (Pg) Atmospheric Pressure at Location (Pbar) Atmospheric Pressure at Location (Pbar) Absolute Stack Pressure (Ps) Stack Temperature Stack Temperature Stack Temperature Stack Gas Velocity Stack Flow Rate Q Stack Gas Wet Volmetric Flow Rate Stack Gas Dry Volumetric Flow Rate Sample after Back Purge: Within 5% of Last Δpstd reading: Stack Diameter (inches) Inches upstream from disturbance Inches downstream from disturbance scf/hr 2.12 Yes 16.00 156.00 46.00 scf/hr cfs ft/sec Deg R Deg F Deg C "Hg "Hg MBAR "Hg "H20 g/g mole g/g mole ppmd %d %d %d 11.17 29.22 1.76 Inches 2.67 8 13.33 Vo l u m e t r i c F l o w R a t e s Pitot readings are taken for Method 2 calculations using measuring points outlined in Method 1 Figure 6.1 16 Traverse Points Were Used Emissions Sampling Points - 3 point long line sampling probe First Sampling Point Taken @ 16.7% of Stack Diameter Second Sampling Point Taken @ 50% of Stack Diameter Third Sampling Point Taken @ 83.3% of Stack Diameter 5.81 7.36 0.00 843.97 0.13 24.93 25.06 743.00 1202.67 395.00 27.97 147.11 205.41 271879.91 241502.77 Run 2 11.07 29.22 1.89 5.77 7.35 0.00 843.00 0.14 24.90 25.04 758.00 1217.67 403.33 27.98 153.34 214.10 279674.65 248706.28 Run 3 11.03 29.21 1.92 5.75 7.35 0.00 843.00 0.14 24.90 25.04 754.00 1213.67 401.11 27.98 154.36 215.53 282496.81 251343.06 11.09 29.22 1.86 5.77 7.35 0.00 843.32 0.14 24.91 25.04 751.67 1211.34 399.81 27.97 151.62 211.71 278075.91 247233.58 *The exhaust stack did not present cyclonic flow conditions at the sampling location due to the absence of cyclones, inertial demisters, venturi scrubbers, or tangential inlets. * Cyclonic Flow Check (Pass/Fail): PASS Δpstd (in) H2O 1.58 Exhaust Temp F 743.00 Pitot Tube Sampling Points (Velocity) 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 Δpstd Average= Run 1 Table 6.2. Stack gas pressure readings measured with a standard pitot tube use for Volumetric Flow Rate 1.62 1.41 1.49 743.00 744.00 742.00 1.42 1.50 1.78 743.00 743.00 744.00 2.43 2.34 2.24 742.00 743.00 743.00 1.80 741.00 1.44 1.71 1.85 745.00 744.00 742.00 1.68 1.88 1.76 743.00 743.00 743.00 Δpstd = Velocity head measured by the standard pitot tube, (in.) H2O.Run 3 Δpstd (in) H2O 1.17 Exhaust Temp F 754.00 1.61 1.63 1.61 754.00 755.00 753.00 1.51 1.78 2.20 756.00 752.00 754.00 2.62 2.00 2.57 754.00 756.00 753.00 1.96 753.00 2.01 1.95 1.90 754.00 754.00 755.00 2.08 2.12 753.00 754.00 754.001.92 Run 2 Δpstd (in) H2O 1.68 Exhaust Temp F 758.00 1.74 1.72 1.54 758.00 757.00 757.00 1.68 2.14 2.20 761.00 758.00 756.00 1.88 2.50 1.98 757.00 759.00 758.00 1.75 759.00 1.93 1.80 1.71 758.00 760.00 758.00 1.97 1.99 756.00 758.00 1.89 758.00 7 Gas, Inc. 7.0 Calculations Method 2: Determination of Stack Gas Velocity and Volumetric Flow Rate *Note- Use of this method negates the need for any fuel related numbers for emissions calculations Nomenclature Δp(avg) = Velocity head of stack gas, mm H2O (in. H2O).Ps = Absolute stack pressure (Pbar+ Pg), mm Hg (in Hg) 3600 = Conversion Factor, sec/hr. A = Cross-sectional area of stack, m2 (ft2). Bws = Water vapor in the gas stream (from ASTM D6348) Kp = Velocity equation constant. Md = Molecular weight of stack gas, dry basis, g/g-mole (lb./lb.-mole). Ms = Molecular weight of stack gas, wet basis, g/g-mole (lb./lb. -mole). Pstd = Standard absolute pressure, 760 mm Hg (29.92 in. Hg). Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (dscf/hr.). Ts(abs) = Absolute stack temperature, °K (°R). = 460 + Ts for English units. Tstd = Standard absolute temperature, 293°K (528 °R). Vs = Average stack gas velocity, m/sec (ft./sec). *(Observed from Method 3 12.3) Dry Molecular Weight. Equation 3-1 Md = .44(.058)+.32(.087)+.28(.855+0) = 29.223 LB/LB-MOLEMd = .44(%CO2)+.32(%O2)+.28(%N2+%CO) 12.5 Molecular Weight of Stack Gas. Equation 2-6 Ms = 29.223(1 -.11173)+.18.0(.11173) = 27.969 LB/LB-MOLEMs = Md(1-Bws)+18.0(Bws) 12.6 Average Stack Gas Velocity. Equation 2-7 Vs = 85.49*.99*√1.76*√(1202.67/(25.06*27.969)) = 147.11 FT/SECVs = Kp*Cp(std)*√Δpavg*√(Ts(abs)/(Ps*Ms)) 12.7 Average Stack Gas Volumetric Flow Rate. Equation 2-8 Qsd = 3600(1-.112)147.114*1.396((528*25.06)/ (1202.67*29.92)) = 241502.77 DSCF/HRQsd = 3600(1-Bws)Vs*A((Tstd*Ps)/(Ts(abs)*Pstd)) *Standard conversion from feet to meters Q = 241502.771/35.315 = 6838.532 DSCM/HRQ = Qsd/35.315 Emission Rates (Examples use CO Run 1) Nomenclature CO corrected @ 15% O2 453.6= Conversion factor lb. to gram HP= Engines rated Horsepower A = Cross-sectional area of stack, m2 (ft2). BHP/HR. = Brake work of the engine, horsepower-hour (HP-HR.). BTU/HP-HR. = Brake Specific Fuel Consumption (HHV) ER = Emission rate of (CO) in g/HP-hr. F(d )= Volumes of combustion components per unit of heat content, scm/J (scf/million Btu). Q = Stack gas volumetric flow rate, in standard cubic meters per hour, dry basis LB/HR.= Emission rate of (CO) in LB/HR. Mfg.= Manufacturer Exhaust flow rate at 100% (ft3/min) O2 = Concentration of oxygen on a dry basis, percent. ppm= Parts Per Million (CO) ppm@15% O2= PPM corrected to 15% O2 Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (DSCF/HR.). Run Time = Run Time in Minutes TPY= Tons per Year Mol wt.= Mol Weight of CO (28.01) Vs = Average stack gas velocity, m/sec (ft./sec). ppm @ 15% O2 = 0*(20.9-15)/(20.9-8.7%)) = 0 PPM @ 15% O2ppm @ 15% O2 = PPM*((20.9-15%O2)/(20.9-O2)) G/HP HR from 40 CFR Part 60 Subpart JJJJ (0*(1.164*10^-3)*6838.532*(Run Time/60))/1119.627 = 0 G/HP-HRg/hp-hr = (PPM*(1.164*10^-3)*Q*(Run Time/60))/BHP/HR LB/HR from Grams LB/HR = 0*1/453.6*1119.627 = 0 LB/HRlb/hr = ER*1/453.6*BHP-HR TPY TPY = 0*4.38 = 0 TPYTPY = LB/HR. *4.38 Horsepower 1120= 1335.21 - ((69.7-62) / ((69.7-57.3) / 25%))) * 1335.21)BHP/HR = Available HP - ((MFP @100% - Actual MFP inHG) / ((MFP @100% - MFP @75%) / 25%))) * Available HP Wet to Dry PPM 0 = 0*(1/(1-.11))ppm wet * (1/(1-H2O) = ppm dry 8 Cp(std) = Standard pitot tube coefficient; use 0.99 Gas, Inc. 8.1 Calibration error test; how do I confirm my analyzer calibration is correct? After the tester has assembled, prepared and calibrated the sampling system and analyzer, they conduct a 3-point analyzer calibration error test before the first run and again after any failed system bias test or failed drift test. They then introduce the low-, mid-, and high-level calibration gases sequentially in direct calibration mode. At each calibration gas level (low, mid, and high) the calibration error must be within ± 2.0 percent of the calibration span. 8.0 Oxygen Calibration 8.2 Initial system bias and system calibration error checks. Before sampling begins, it is determined whether the high- level or mid-level calibration gas best approximates the emissions and it is used as the upscale gas. The upscale gas is introduced at the probe upstream of all sample- conditioning components in system calibration mode. 8.3 Post-run system bias check and drift assessment - confirming that each sample collected is valid. Sampling may be performed for multiple runs before performing the post-run bias or system calibration error check provided this test is passed at the conclusion of the group of runs. A failed final test in this case will invalidate all runs subsequent to the last passed test. (1) Next, zero gas is introduced as described above. The response must be within 0.5 percent of the upscale gas concentration. (2) Low-level gas reading is observed until it has reached a final, stable value and the results are recorded. The measurement system will be operated at the normal sampling rate during all system bias checks. (3) If the initial system bias specification is not met, corrective action is taken. The applicable calibration error test from Section 8.2.3 of EPA Method 7E is repeated along with the initial system bias check until acceptable results are achieved, after which sampling will begin. The pre- and post-run system bias must be within ± 5.0 percent of the calibration span for the low-level and upscale calibration gases. (1) If the post-run system bias check is not passed, then the run is invalid. The problem is then diagnosed and fixed, then another calibration error test and system bias is passed before repeating the run. (2) After each run, the low-level and upscale drift is calculated, using Equation 7E–4 in Section 12.5 from EPA Method 7E. If the post-run low- and upscale bias checks are passed, but the low-or upscale drift exceeds the specification in Section 13.3, the run data are valid, but a 3-point calibration error test and a system bias check must be performed and passed prior to additional testing. Table 8.1 Oxygen Calibration EPA Method 3A QA Worksheet (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Certified Gas Concentraion Low-Level (%) 0.00% Certified Gas Concentraion Mid-Level (%) Certified Gas Concentraion High-Level (%) (DIRECT) Analyzer Calibration Error (≤ 2%) Certified Concentration Value (%) Direct Calibration Response (%) Absolute Difference (%) Analyzer Calibration Error (%)Analyzer Direct Calibration Response Certified bottle value % 0.00% 0.00% 0.00% Zero Gas % Mid-Level Gas % High-Level Gas % Bias Pre Initial Value Bias Post Inital Values System Calibrations Response Pre (%) 0.00% System Bias (% of Span) Pre System Calibration Response Post (%) System Bias (% of Span) Post Drift (% of Span) 0.00%0.00%0.00%0.00% (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Avg. Gas Concentration (Run 1) Avg. Gas Concentration (Run 2) Avg. Gas Concentration (Run 3) Effluent Gas (Cgas) Run 1 Effluent Gas (Cgas) Run 2 Effluent Gas (Cgas) Run 3 Linearity Check 0.00%0.00%0.00% Method 7E 3.4 To the extent practicable, the measured emissions should be between 20 to 100 percent of the selected calibration span. This may not be practicable in some cases of low concentration measurements or testing for compliance with an emission limit when emissions are substantially less than the limit. 7E 8.5: Note: that you may risk sampling for multiple runs before performing the post-run bias provided you pass this test at the conclusion of the group of runs Upscale Gas Analyzer Calibration Response (%) Zero Gas Upscale Gas EPA Method 3A QA Worksheet Zero Gas Mid-Level Gas High-Level Gas 100% Nitrogen O2 QA/QC Zero Gas %0.00% Mid-Level Gas % High-Level Gas % System Calibration Response Pre (%) System Calibration Response Post (%) Zero Gas % Upscale Cal Zero Gas % Upscale Cal Upscale Used Upscale Used 8.88% 20.82% 8.57% 8.57% 9.00% 9.00% 8.57%8.57% 8.88% 20.82% 9.00% 21.18% 9.00% 21.18% 9.00%21.18% 0.00% 9.00% 21.18% 0.12% 0.36% 0.55% 1.69% 9.00% Span Zero Offset 0.00% 21.18 0.00% 8.88%1.48%1.46%0.00% 8.28% 8.27% 8.26% 8.69% 8.68% 8.67% 9 Gas, Inc. 880.0 880.0 876.7 22.0 23.0 22.7 0.0 0.0 9.0 Engine Parameter Data Sheet Company Site Elevation (ft) Facility Unit ID Date Make Ovintiv USA Inc. Pleasant Valley Compressor Station 11/2/2023 5343 5 Caterpillar Model Serial Number G3516 LE WPW01760 Technician Aaron King Run Start Times 09:05 AM 10:24 AM 11:39 AM 12:59 PM Run 1 Run 2 Run 3 Completed Engine Parameter Data Run 1 Engine Speed (RPM)1395.0 1400.0 1400.0 1398.3 Engine Hours 45162 45163 45164 45165 Intake Manifold Pressure (psi)30.3 31.6 30.7 30.9 Intake Manifold Temp °F 114.8 116.6 120.2 117.2 Engine Load (BHP)1119.6 1195.1 1145.6 1153.5 Ambient Temp °F 27.0 39.0 44.0 36.7 Humidity %52.0 35.0 28.0 38.3 Dew Point °F 11.0 13.0 13.0 12.3 Caterpillar YesCatalyst (Yes or No) AFR Manufacturer/Type Caterpillar Caterpillar Caterpillar 10 Run 3 AverageRun 2 23.0 870.0Discharge Pressure (psi) Suction Pressure (psi) Catalyst Pressure Drop H2O Catalyst Outlet Temp °F Catalyst Inlet Temp °F Gas, Inc. 10.0 QA/QC Results Average:Carbon monoxide CO Gas, Inc. 0.00 R e s u l t s Average:Nitrogen monoxide NO 0.00 Average:Nitrogen dioxide NO2 0.00 Average:NOx 0.00 Average:VOC 0.07 Average:Oxygen 0.20 Pre-test Baseline Results Time: Q A / Q C Value:CTS Bottle Concentration 98.91 Value:CTS Compound Concentration Avg 97.42 Tolerance 2.00% Difference between measured and expected 1.51% CTS Direct to Analyzer Time: Average:Carbon monoxide CO 0.00 Average:Nitrogen monoxide NO 0.00 Average:Nitrogen dioxide NO2 0.00 Average:NOx 0.00 Average:VOC 0.20 Average:Oxygen 0.17 Pre-test System Zero Time: Mechanical Response Time 46 seconds Value:CTS Bottle Concentration 98.91 Value:CTS Compound Concentration Avg 96.79 Tolerance 5.00% Difference between measured and expected 2.14% Pre-test System CTS & Mechanical Response Time 90 secondsEquilibration Response Time Value:Spike Reported 253.20 Value:Spike Expected 252.50 System (Equilibration) Response Time Target (Spike) 45 secondsSystem Zero Response Time 45 secondsSystem Response Time System (Zero) Response Time 11 11.0 D6348 Annexes 1-8 D6348 Annexes 1. Test Plan Requirements Annex 1.2 The test quality objectives completed for the emissions test are demonstrated throughout Annexes 1, 2, 3, 4, 5, 6, 7 & 8 as layed out per ASTM D6348-03. All reference methods, pre-test and post test procedures were within acceptable limits. Data generated during the pre-test and post-test procedures are summarized below in order of the distinctive Annex. Three 60 minute test runs were performed. The final analyte concentrations are the average of each test run. Data was taken at 60 second intervals. Each 60 second measurement was the average of 600 scans. Propane is used as the surrogate compound for the Annex 5 Spiking Technique due to Propane being the VOC that is most commonly found in the combustion process of natural gas. Additionally, the molecular weight of Propane coincides with with molecular weight of VOC's per the EPA. Annex Table 1.2.1 Certified Calibration Bottle Concentrations Bottle Expiration NO2 Ethylene SF6 O2 (%) CC513838 7/12/2026 96.25 9.00% EB0010235 7/13/2031 98.91 CC455713 8/30/2030 21.18% Cylinder # CC79108 Expiration: 5-08-2031 Propane CO NO SF6 Bottle Value 252.50 498.60 247.30 9.73 Analyzer System Response 253.20 492.01 244.56 9.67 Percent Difference 0.28%1.32%1.11%0.63% Annex Table 1.2.2 Measurement System Capabilities SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 97.416 4.924 Spike Direct Propane 252.623 Mechanical Response Time SF6 9.670 CO 489.414 NO 244.395 Ethylene 96.789 46 seconds Analyzer Response Propane 253.196 SF6 9.669 CO 492.009 NO 244.555 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 253.184 CO 493.152 NO 244.649 90 seconds 108 seconds 7.29% 7.12% 7.24% 104.33% 98.39% 96.48% 9.684 12 Gas, Inc. Annex 1.3 Compounds Infrared Analysis Region (cm-1) Expected Concentration Range Measurement System Achievable Minimum Detectable Concentrations Required Measurement System Accuracy and Precision for Test Application CO 2000-2200 0-1200 ppm NO 1875-2138 NO2 2700-2950 VOC 2600-3200 910-1150 2550-2950 CH2O 2550-2850 Interfering Compounds * CO is analyzed in a separate analysis region than CO2 and H2O CO2 Water Vapor 926-1150 3200-3401 Annex Table 1.3.1 Test Specific Target Analytes and Data Quality Objectives 0.16267 ppm 4 ppm 0-1000 ppm 0.4007 ppm 2 ppm 0-100 ppm 0.4899 ppm 2 ppm 0-100 ppm 1.8520 ppm Total VOC's 1 ppm per VOC 0-100 ppm 0.7878 ppm 1 ppm 0-10% 0-22% 0% 0.20% n/a n/a * VOCs compiled of Acetaldehyde, Ethylene, Hexane, and Propane. Annex 1.4 Figure Annex 1.4.1 Sampling Train The testing instrumentation is housed in an enclosed vehicle which is located approximately 45 feet from the source. A heated sample line (sixty feet in length) is attached to the inlet of analyzer system and the source effluent discharges through the FTIR outlet. 13 Gas, Inc. Sampling Point Locations in Inches 16.7%2.672 50%8.000 83.3%13.328 Figure Annex 1.4.3 Sample Port Location Figure Annex 1.4.2 Sampling Points Interior Stack Diameter (inches): Inches Upstream: Inches Downstream: 16 156 46 14 Stack Gas Dry Volumetric Flow Rate (scf/hr): 247233.58 H2O%d @ Sampling Point:11.09 CO2%d @ Sampling Point:5.77 Pressure @ Sampling Point (Pg "H2O):1.86 Temperature @ Sampling Point (Deg F):751.67 Gas, Inc. D6348 Annex 2. Determination of FTIR Measurement System Minimum Detectable Concentrations (MDC#1) Target Analyte Results (ppm) CO 0.1627 NO 0.4007 NO2 0.4899 Ethylene 0.3782 Propane 0.4351 Hexane 0.2233 Acetaldehyde 0.8152 Formaldehyde 0.7878 D6348 Annex 3. FTIR Reference Spectra Calibration Transfer Standard Expected Measured Path Length Validated Ethylene 98.91 97.42 4.924 Passed D6348 Annex 4. Required Pre-Test Procedures Annex Table 1.2.2 Measurement System Capabilities 15 SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 97.416 4.924 Spike Direct Propane 252.623 Mechanical Response Time SF6 9.670 CO 489.414 NO 244.395 Ethylene 96.789 46 seconds Analyzer Response Propane 253.196 SF6 9.669 CO 492.009 NO 244.555 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 253.184 CO 493.152 NO 244.649 90 seconds 108 seconds 7.29% 7.12% 7.24% 104.33% 98.39% 96.48% 9.684 Gas, Inc. D6348 Annex 5. Analyte Spiking Technique Propane Spike Direct SF6 CO NO 252.500 9.730 498.600 247.300 252.623 9.670 489.414 244.395 0.05% 0.62% 1.84% 1.17% +/- 2% +/- 2% +/- 2% +/- 2% Pass Pass Pass Pass Parameter Gas Concentration Measured % Difference Specification Validated 14.685 0.000 Spike Average 33.409 0.705 Dilution Factor 7.291% Expected 32.022 % Recovery 104.330% Specification 70-130% <10% Spike Run 1 via the System Source Output Propane SF6 D6348 Annex 6. Determination of System Performance Parameters Noise Equivalent Absorbance (NEA) RMS High RMS Mid RMS Low Line Position: Demonstrating the peak positions align correctly (Manual Comparison +/- 20%) 0.000 Spike Average 0.688 Dilution Factor 7.115% Expected % Recovery Specification 70-130% <10% Spike Run 2 via the System Source Output Propane SF6 0.000 Spike Average 0.700 Dilution Factor 7.239% Expected % Recovery Specification 70-130% <10% Spike Run 3 via the System Source Output Propane SF6 17.639 33.422 34.643 96.480% 0.000546 0.001675 0.003201 17.114 33.329 33.873 98.390% Line Position Difference:Resolution Difference to Reference0.00%Pass Pass4.65% 16 Gas, Inc. Resolution The Gasmet GICCOR (Genzel Interferometer with Cube Corner Retroreflectors) interferometer is specially designed for maximum optical throughput and maximum signal to noise ratio of 7.72 (cm-1) remaining stable with any vibration and temperature changes. Detector Linerarity The Gasmet DX4000 is a low resolution spectrometer where the aperture is fixed to a maximum angle setting and the detector linearity was tested with an alternate approach. A three point linerarity of the CTS gas was performed and validated. D6348 Annex 7. Preparation of Analytical Quantification Algorithm The analytical accuracy of the quantification algorithm is satisfied via the results from Annex 5 per Annex 7.6 Regression Slope:-4.73669288 Pass Line Position Difference:Resolution Difference to Reference 4.65% D6348 Annex 8. Post Test Quality Assurance/Quality Control Procedures CTS Bottle Concentration: CTS Sample Concentration Average: Difference between measured and expected: Tolerance: 98.91 97.42 1.53% 5.00% POST CTS System Check: Run 1 Points 1 & 2 on CO/NO/Propane Run 2 Points 1 & 2 on CO/NO/Propane Run 3 Points 1 & 2 on CO/NO/Propane Run Data Validation - Automated vs Manual Reading Validated Comments All within 20% All within 20% All within 20% Passed Passed Passed Demonstrates no interferences observed. Demonstrates no interferences observed. Demonstrates no interferences observed. 17 Gas, Inc. 12.0 Signature Page Job/File Name: We certify that based on review of test data, knowledge of those individuals directly responsible for conducting this test, we believe the submitted information to be accurate and complete. Ovintiv USA Inc.; Pleasant Valley Compressor Station; 5; JJJJ 18 Company: Print Name: Signature: Title: Phone Number: Date: Company:G.A.S. Inc.Date: Print Name: Title: 11/2/2023 Emissions Specialist Company:G.A.S. Inc.Date: Print Name: Title: Signature: Phone Number: Chris Oppel Director of Stack Testing 580-225-0403 11/2/2023 Aaron King Gas, Inc. Appendices Gas, Inc. Gas, Inc. CERTIcICATE Oc ANALYSIS Grade of Product: EPA PROTOCOL STANaARa Part Number:E05NI94E15AC014 Reference Number:54-402731888-1 Cylinder Number:CC79108 Cylinder Volume:147.0 CF Laboratory:124 - Chicago (SAP) - IL Cylinder Pressure:2015 PSIG PGVP Number:B12023 Valve Outlet:660 Gas Code:CO,CO2,NO,NOX,PPN,BALN Certification Date:May 08, 2023 Expiration Date:May 08, 2031 Certification performed in accordance with “EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)” document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. The results relate only to the items tested. The report shall not be reproduced except in full without approval of the laboratory. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. ANALYTICAL RESULTS Component Requested Actual Protocol Total Relative Assay Concentration Concentration Method Uncertainty Dates NOX 250.0 PPM 247.3 PPM G1 +/- 0.9% NIST Traceable 05/04/2023, 05/08/2023 NITRIC OXIDE 250.0 PPM 247.3 PPM G1 +/- 0.9% NIST Traceable 05/04/2023, 05/08/2023 PROPANE 250.0 PPM 252.5 PPM G1 +/- 0.7% NIST Traceable 05/04/2023 CARBON MONOXIDE 500.0 PPM 498.6 PPM G1 +/- 0.6% NIST Traceable 05/04/2023 CARBON DIOXIDE 5.000 %5.056 %G1 +/- 0.6% NIST Traceable 05/04/2023 NITROGEN Balance CALIBRATION STANaARaS Type Lot ID Cylinder No Concentration Uncertainty Expiration Date NTRM 20060336 EB0113149 250.3 PPM NITRIC OXIDE/NITROGEN +/- 0.8%Oct 19, 2026 PRM 12409 D913660 15.01 PPM NITROGEN DIOXIDE/AIR +/- 1.5%Feb 18, 2023 GMIS 1534012021105 ND73033 5.012 PPM NITROGEN DIOXIDE/NITROGEN +/- 1.6%Jun 15, 2025 NTRM 200602-13 6162697Y 243.3 PPM PROPANE/AIR +/- 0.5%Mar 17, 2027 NTRM 150605-41 CC453947 491.9 PPM CARBON MONOXIDE/NITROGEN +/- 0.6%Mar 05, 2027 NTRM 13060423 CC413685 7.489 % CARBON DIOXIDE/NITROGEN +/- 0.6%May 14, 2025 The SRM, NTRM, PRM, or RGM noted above is only in reference to the GMIS used in the assay and not part of the analysis. ANALYTICAL EnUIPMENT Instrument/Make/Model Analytical Principle Last Multipoint Calibration Nicolet iS50 AUP2010242 FTIR Apr 05, 2023 CO-1 SIEMENS ULTRAMAT 6E N1J5700 NDIR Apr 26, 2023 Nicolet iS50 AUP2010242 FTIR May 08, 2023 Nicolet iS50 AUP2010242 FTIR May 08, 2023 Nicolet iS50 AUP2110277 FTIR Apr 05, 2023 Triad Data Available Upon Request PERMANENT NOTES:Mixture contains nominal 10ppm Sulfur Hexafluoride as a tracer component. Actual tested value included within the original Certificate of Analysis. Contact the Airgas laboratory if a reprint is required NOTES:Mixture contains nominal 10ppm Sulfur Hexafluoride as a tracer component. Actual tested value included within the original Certificate of Analysis. Contact the Airgas laboratory if a reprint is required SF6 Results: JUE443: 9.76 PPM, EZZ970: 9.74 PPM, KDD300: 9.73 ppm, ESA918: 9.78 PPM, LMZ778: 9.73 PPM, JNX734: 9.76 PPM. Airgas Specialty Gases Airgas USA LLC 12722 S. Wentworth Ave. Chicago, IL 60628 Airgas.com Signature on file Approved for Release Page 1 of 1 Gas, Inc. CERTIcICATE Oc ANALYSIS Grade of Product: EPA PROTOCOL STANaARa Part Number:E03NI90E15W0003 Reference Number:54-402782817-1 Cylinder Number:CC513838 Cylinder Volume:145.0 CF Laboratory:124 - Chicago (SAP) - IL Cylinder Pressure:2015 PSIG PGVP Number:B12023 Valve Outlet:660 Gas Code:NO2,O2,BALN Certification Date:Jul 12, 2023 Expiration Date:Jul 12, 2026 Certification performed in accordance with “EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)” document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. The results relate only to the items tested. The report shall not be reproduced except in full without approval of the laboratory. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. ANALYTICAL RESULTS Component Requested Actual Protocol Total Relative Assay Concentration Concentration Method Uncertainty Dates NITROGEN DIOXIDE 100.0 PPM 96.25 PPM G1 +/- 1.2% NIST Traceable 07/05/2023, 07/12/2023 OXYGEN 9.000 %8.996 %G1 +/- 0.4% NIST Traceable 07/07/2023 NITROGEN Balance CALIBRATION STANaARaS Type Lot ID Cylinder No Concentration Uncertainty Expiration Date GMIS 1534012021603 CC502563 101.4 PPM NITROGEN DIOXIDE/NITROGEN +/- 1.1%Feb 23, 2026 PRM 12420 D887373 98.9 PPM NITROGEN DIOXIDE/AIR +/- 1.0%Feb 23, 2023 NTRM 10010604 K002585 9.967 % OXYGEN/NITROGEN +/- 0.3%Mar 22, 2028 The SRM, NTRM, PRM, or RGM noted above is only in reference to the GMIS used in the assay and not part of the analysis. ANALYTICAL EnUIPMENT Instrument/Make/Model Analytical Principle Last Multipoint Calibration MKS FTIR NO2 017707558 FTIR Jul 11, 2023 O2-1 HORIBA VA-5003 YH82Y07B PARAMAGNETIC Jul 05, 2023 Triad Data Available Upon Request Airgas Specialty Gases Airgas USA LLC 12722 S. Wentworth Ave. Chicago, IL 60628 Airgas.com Signature on file Approved for Release Page 1 of 1 Gas, Inc. CERTIcICATE Oc ANALYSIS Grade of Product: PRIMARY STANaARa Customer:MY SELF STORAGE PLACE, Part Number:X02NI99P15ACVH8 Reference Number:54-402789499-1 Cylinder Number:EB0010235 Cylinder Volume:144.0 CF Laboratory:124 - Chicago (SAP) - IL Cylinder Pressure:2015 PSIG Analysis Date:Jul 13, 2023 Valve Outlet:350 Lot Number:54-402789499-1 Expiration Date:Jul 13, 2031 Primary Standard Gas Mixtures are traceable to N.I.S.T. weights and/or N.I.S.T. Gas Mixture reference materials. ANALYTICAL RESULTS Component Req Conc Actual Concentration Analytical (Mole %)Uncertainty ETHYLENE 100.0 PPM 98.91 PPM +/- 1% NITROGEN Balance Notes:GREAT PLAINS ANALYTICAL, CERTIFIED BY FTIR. Airgas Specialty Gases Airgas USA LLC 12722 S. Wentworth Ave. Chicago, IL 60628 Airgas.com Signature on file Approved for Release Page 1 of 1 Gas, Inc. CERTIcICATE Oc BATCH ANALYSIS Grade of Product: BIP-BUILT IN PURIcIER Part Number:NI BIP300 Reference Number:29-400672389-1 Cylinder Analyzed:TW05-867349 Cylinder Volume:304.0 CF Laboratory:106 - Tulsa Fast Fill (SAP) - OK Cylinder Pressure:2640 PSIG Analysis Date:Feb 10, 2016 Valve Outlet:580 Lot Number:29-400672389-1 ANALYTICAL RESULTS Component Requested Certified Purity Concentration NITROGEN 99.999 %99.999 % OXYGEN 1 PPM 0.94 PPM WATER 1 PPM 0.058 PPM TOTAL HYDROCARBONS 0.1 PPM 0.1 PPM CARBON DIOXIDE 0.5 PPM 0.235 PPM CARBON MONOXIDE 0.5 PPM 0.235 PPM Permanent Notes:This cert includes values from the "fill" side and is not representative of the "use" side purity. Contact an Airgas Sales Representative for this information. Cylinders in Batch: 4263617Y, TW04671107, TW05-831574, TW05-865966, TW05-867349, TW05-867538, TW05-867578, TW05-881687, TW05-881820, TW05-920689, TW05-920760, TW05848694, TW05867441, TW05897265, TW05897512, TW05920678, TW05920686, TW05920695, TW05920781, TW05920874 Impurities verified against analytical standards traceable to NIST by weight and/or analysis. Airgas Mid South region Airgas USA LLC 9741 E. 56th St. North Tulsa, OK 74117 Airgas.com Signature on file Approved for Release Page 1 of 1 Gas, Inc. CERTIcICATE Oc ANALYSIS Grade of Product: EPA PROTOCOL STANaARa Part Number:E02NI79E15A00B1 Reference Number:54-402531082-1 Cylinder Number:CC455713 Cylinder Volume:146.0 CF Laboratory:124 - Chicago (SAP) - IL Cylinder Pressure:2015 PSIG PGVP Number:B12022 Valve Outlet:590 Gas Code:O2,BALN Certification Date:Aug 30, 2022 Expiration Date:Aug 30, 2030 Certification performed in accordance with “EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)” document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. The results relate only to the items tested. The report shall not be reproduced except in full without approval of the laboratory. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. ANALYTICAL RESULTS Component Requested Actual Protocol Total Relative Assay Concentration Concentration Method Uncertainty Dates OXYGEN 21.00 %21.18 %G1 +/- 0.4% NIST Traceable 08/30/2022 NITROGEN Balance CALIBRATION STANaARaS Type Lot ID Cylinder No Concentration Uncertainty Expiration Date NTRM 150104-18 K026588 22.454 % OXYGEN/NITROGEN +/- 0.2%Mar 08, 2027 ANALYTICAL EnUIPMENT Instrument/Make/Model Analytical Principle Last Multipoint Calibration O2-1 HORIBA MPA-510 3VUYL9NR Paramagnetic Aug 11, 2022 Triad Data Available Upon Request Airgas Specialty Gases Airgas USA LLC 12722 S. Wentworth Ave. Chicago, IL 60628 Airgas.com Signature on file Approved for Release Page 1 of 1 ㈱┠伲 Tri Probe Certification CE57IFICA7E 2F ANAL<6I6 GUDGH RI PURGXFW: CER7IFIED S7ANDARD-PROBE PURdXcW SeUfRUPaQce YeUified b\ diUecW cRPSaUiVRQ WR calibUaWiRQ VWaQdaUdV WUaceable WR N.I.S.T. *The SURbe liVWed RQ WhiV fRUP PeeWV Whe PXlWiSRiQW WUaYeUVe UeTXiUePeQW Rf EPA MeWhRd 7e, VecWiRQ 8.4 aV VhRZQ iQ Whe accRPSaQ\iQg daWa. MeWhRd 7e, VecWiRQ 8.4 VWaWeV WhaW Whe PXlWiSRiQW WUaYeUVe UeTXiUePeQW caQ be VaWiVfied b\ VaPSliQg Yia ³a PXlWi-hRle SURbe deVigQed WR VaPSle aW Whe SUeVcUibed SRiQWV ZiWh a flRZ +/- 10 SeUceQW Rf PeaQ flRZ UaWe´. ANAL<7ICAL 5E68L76 *CalibUaWiRQ cRQdXcWed iQ accRUdaQce ZiWh EmiVViRQ MeaVXUemeQW CeQWeU GXideliQe DRcXmeQW ± EMC GD-031 NRWeV: ___________________________________________________ ______________________ $ S S U R Y H G I R U 5 H O H D V H ' D W H Great Plains Analytical Services ͵Ͳ͵ W ͵ d St Elk City, OK, ͵ͶͶ ȋͷͺͲȌʹʹͷǦͲͶͲ͵ Faxǣ ȋͷͺͲȌʹʹͷǦʹͳʹ PaUW NXPbeU: 16S RefeUeQce NXPbeU: 8 LabRUaWRU\: GAS INC. SWack DiaPeWeU: 16" AQaO\ViV DaWe: 1/20/2022 TaUgeW FORZ RaWe: 3L/PiQ LOT NXPbeU: SN: A 8A 16S NXPbeU Rf PRiQWV: 3 RƵŶ η TŽƚal FlŽǁ ;LͬmͿ MeaƐƵƌed FlŽǁ PŽƌƚ A ;LͬmͿ ;Delƚa ƋϭͿ MeaƐƵƌed FlŽǁ PŽƌƚ B ;LͬmͿ ;Delƚa ƋϮͿ MeaƐƵƌed FlŽǁ PŽƌƚ C ;LͬmͿ ;Delƚa ƋϯͿ MHDQ PUREH PRUW 6DPSOHG FORZ (L/P) 5XQ 1 2 L3M 0.720 (8.00䧮) 0.660 (-1.00䧮) 0.620 (-7.00䧮) 0.667 5XQ 2 4 L3M 1.42 (7.85䧮) 1.30 (-1.27䧮) 1.23 (-6.58䧮) 1.32 1/20/22 Probe size: 16S Mr. Jordan Williamson CEO GAS Inc. 303 W. 3rd Street Elk City, OK 73644 Dear Mr. Williamson: We are writing in response to your letter received on September 17, 2020, in which you request the approval of alternative testing procedures. The EPA’s Office of Air Quality Planning and Standards (OAQPS) is the delegated authority for consideration of major alternatives to test methods and procedures as set forth in 40 CFR parts 60 and 63 under which your request must be addressed. GAS Inc. is requesting a change to one of the test methods, ASTM D6348-03, used for conducting performance tests to determine compliance under 40 CFR part 60, Subpart JJJJ – Standards of Performance for Stationary Spark Ignition Internal Combustion Engines (Subpart JJJJ) and 40 CFR part 63, Subpart ZZZZ – National Emissions Standards for Hazardous Air Pollutants for Performance for Stationary Reciprocating Internal Combustion Engines (Subpart ZZZZ). The change being requested will be used to check detector linearity of the Fourier Transform Infrared (FTIR) instrumentation used to conduct this method. Specifically, you are requesting that the procedures of section 8.3.3 of Method 320 (40 CFR part 60, Appendix A), another FTIR-based method allowed under Subparts JJJJ and ZZZZ, be used in lieu of section A6.4.1 of ASTM D6348-03 when conducting testing using ASTM D6348-03 under 40 CFR part 60, Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. In your request, you state that this alternative linearity check procedure will produce consistent results when utilizing either Method 320 or ASTM D6348-03. Additionally, some FTIR instrumentation does not allow for reducing the size of the aperture in the instrument and, thus, it would not be feasible to properly conduct the entirety of the ASTM D6348-03 method in its current form using such an instrument. Based on our understanding of FTIR instrument principles and recognition that the requested alternative determination of detector linearity is both technically sound and contained within Method 320, we are approving the requested change. We believe that this alternative is acceptable for use for use in testing all engines subject to 40 CFR part 60 Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. Also, we will post this letter as ALT-141 on EPA’s website (at www.epa.gov/emc/broadly-applicable-approved-alternative- testmethods) to announce that our approval of this alternative test method is broadly applicable to engines for the purposes of meeting Subparts JJJJ and ZZZZ. March 15, 2021 Sincerely, Steffan M. Johnson, Group Leader Measurement Technology Group If you should have any questions or require further information regarding this approval, please contact David Nash of my staff at 919-541-9425 or email at nash.dave@epa.gov. cc: Sara Ayers, EPA/OECA/OC/MAMPD, (ayres.sara@epa.gov) Melanie King, EPA/OAR/OAQPS/SPPD, (king.melanie@epa.gov) James Leather, EPA Region 6, (leather.james@epa.gov) David Nash, EPA/OAR/OAQPS/AQAD, (nash.dave@epa.gov) Heather Sessing, Oklahoma DEQ, (Heather.sessing@deq.ok.gov) Aaron King GAS, Inc. Type of Sources Tested: info@gasinc.us Stationary Internal Combustion Engines • 4 Stroke Rich Burn Engines • 2 Stroke & 4 Stroke Lean Burn Engines Stationary Natural Gas Fired Generators Stationary Propane Fired Generators Gas Fired Boilers Qualifications: Trained, studied, and fully demonstrates compliance for emissions testing via data collection outlined in the following Reference Methods: • EPA Method 1 & 1A – Sampling & Traverse Points • EPA Method 2 & 2C – Velocity & Volumetric Flow Rate of a Gas Stream • EPA Method 3A – Oxygen • EPA Method 7E – NOX • EPA Method 10 – Carbon Monoxide • EPA Method 25A – Volatile Organic Compounds • ASTM D6348 – Extractive Fourier Transform Infrared Spectroscopy Conducts emissions testing on a weekly basis including, but not limited to, the following test types: Initial Compliance, Biennial Compliance, Semiannual Compliance & Quarterly Compliance. All tests performed are in accordance to any and all Federal & State requirements as applicable (i.e. JJJJ, ZZZZ, 106.512, 117, PEA, etc.). Performed testing in Colorado, Utah, Wyoming, North Dakota, Montana, Kansas, New Mexico, Oklahoma, Texas, Louisiana (land and off-shore), Arkansas, Ohio, Pennsylvania, West Virginia, New York, Kentucky, & Mississippi. • Quarterly Performance Reviews covering ongoing changes with Federal Regulations, State Compliance guidelines, & site-specific safety certifications. Types of Analyzers: • Gasmet DX4000 FTIR • Gasmet Portable Sampling Unit with Zirconium Oxide O2 Sensory • Testo 350 • Flame Ionization Detector 580-225-0403 Gas, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 1 Minute Average Data Sheet Ovintiv USA Inc.Client: Pleasant Valley Compressor Station Unit Number:5 Make:Caterpillar Location:G3516 LEModel: WPW01760Serial Number: RAW Result Data Stability 11/2/2023 06:43 6.4528.7922.125 0.369 5.04452.115 0.000 0.000 0.9070.2620.000 6.457 17.8810.147 2.360 843.028.262.028 0.727 15.24 15.05 180.0 Pre Test Baseline Direct 11/2/2023 06:55 0.0000.000-0.033 0.000 0.0000.000 0.000 0.353 0.0000.0080.033 0.000 0.0000.089 0.000 843.00.060.089 0.000 0.00 0.26 180.0 11/2/2023 06:56 0.0000.000-0.037 0.000 0.0000.000 0.000 0.310 0.0000.0000.264 0.000 0.0000.000 0.000 843.00.090.135 0.000 0.00 0.17 180.0 11/2/2023 06:56 0.0000.000-0.037 0.000 0.0000.000 0.000 0.358 0.0000.1290.102 0.000 0.0000.000 0.000 843.00.060.086 0.000 0.00 0.16 180.0 CTS Direct 11/2/2023 06:59 0.0000.000-0.024 0.000 0.0000.000 0.000 0.050 0.0000.0000.000 97.339 0.0000.000 0.000 843.064.930.056 0.000 0.00 0.24 180.0 11/2/2023 07:00 0.0000.000-0.025 0.000 0.0000.000 0.000 0.084 0.0000.0000.000 97.501 0.0000.000 0.000 843.065.030.040 0.000 0.00 0.24 180.0 11/2/2023 07:00 0.0000.000-0.022 0.000 0.0000.000 0.000 0.021 0.0790.0000.000 97.408 0.0000.000 0.000 843.064.950.009 0.000 0.00 0.24 180.0 21% O2 Direct 11/2/2023 07:10 0.0000.000-0.040 0.000 0.0000.000 0.000 0.460 0.0060.0000.638 0.000 0.0000.000 0.000 843.00.130.199 0.000 0.00 20.82 180.0 11/2/2023 07:10 0.0000.000-0.040 0.000 0.0730.000 0.000 0.358 0.1240.0000.904 0.000 0.0000.000 0.000 843.00.040.059 0.000 0.00 20.85 180.0 11/2/2023 07:11 0.0000.000-0.037 0.000 0.0000.000 0.000 0.329 0.0000.0000.217 0.000 0.0000.000 0.000 843.00.060.094 0.000 0.00 20.80 180.0 NO2 9%O2 Direct 11/2/2023 07:18 95.7550.000-0.036 0.000 0.4200.000 0.148 0.000 0.9610.0401.553 0.000 0.0000.000 0.000 843.00.000.000 0.000 95.75 8.88 180.0 11/2/2023 07:18 95.2910.000-0.037 0.000 0.7470.000 0.139 0.000 1.9010.0001.573 0.000 0.0000.000 0.000 843.00.000.000 0.000 95.29 8.87 180.0 11/2/2023 07:18 95.7560.000-0.036 0.000 0.3560.000 0.138 0.000 1.6980.0001.456 0.000 0.0000.000 0.000 843.00.000.000 0.000 95.76 8.89 180.0 Spike Direct 11/2/2023 07:30 0.000244.165-0.043 4.674 0.000489.740 1.794 1.926 5.0500.5090.000 1.208 252.7980.000 0.000 843.0255.452.774 9.672 244.17 0.02 180.0 11/2/2023 07:31 0.000244.689-0.034 4.671 0.000489.326 1.780 1.780 5.6880.1210.000 1.211 252.6150.000 0.000 843.0255.312.834 9.670 244.69 0.02 180.0 11/2/2023 07:31 0.000244.330-0.037 4.667 0.186489.175 1.790 1.845 5.8020.1570.000 1.236 252.4550.000 0.000 843.0255.282.995 9.667 244.33 0.02 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline System 11/2/2023 07:34 0.0000.000-0.000 0.000 0.0000.000 0.000 1.008 0.0000.0000.115 0.000 0.2310.000 0.000 843.00.290.089 0.000 0.00 0.17 180.0 11/2/2023 07:35 0.0000.000-0.001 0.000 0.0000.000 0.000 0.923 0.2250.0000.114 0.000 0.1510.000 0.000 843.00.180.042 0.000 0.00 0.17 180.0 11/2/2023 07:35 0.0000.000-0.001 0.000 0.0000.000 0.000 0.983 0.0130.0000.000 0.000 0.1260.000 0.000 843.00.130.005 0.000 0.00 0.17 180.0 CTS System with Response Time 11/2/2023 07:37 0.0000.000-0.000 0.000 0.0000.000 0.000 0.383 0.0000.0000.000 96.262 0.1050.000 0.006 843.064.290.000 0.000 0.00 0.24 180.0 11/2/2023 07:38 0.0000.000-0.000 0.000 0.0000.000 0.000 0.389 0.0000.0000.000 96.884 0.0000.000 0.000 843.064.590.000 0.000 0.00 0.23 180.0 11/2/2023 07:38 0.0000.000-0.000 0.000 0.0000.000 0.000 0.406 0.0000.0030.000 97.221 0.0270.000 0.022 843.064.890.000 0.000 0.00 0.23 180.0 NO2 System & 9% with Response Time 11/2/2023 07:59 96.8920.000-0.001 0.000 0.0000.000 0.168 0.269 0.5250.0000.000 0.000 0.0000.369 0.035 843.00.070.000 0.000 96.89 8.56 180.0 11/2/2023 07:59 97.0350.000-0.001 0.000 0.0510.000 0.175 0.176 0.6360.0000.000 0.000 0.0000.547 0.020 843.00.040.000 0.000 97.03 8.57 180.0 11/2/2023 07:59 98.1120.000-0.001 0.000 0.0750.000 0.171 0.198 0.3330.0000.000 0.000 0.0000.577 0.058 843.00.200.129 0.000 98.11 8.57 180.0 Spike System with Response Time 11/2/2023 08:02 0.000244.408-0.001 4.643 0.000491.491 1.763 1.800 5.2500.0370.000 1.262 252.9910.117 0.000 843.0255.782.918 9.661 244.41 0.02 180.0 11/2/2023 08:02 0.000244.404-0.001 4.662 0.000492.163 1.747 1.720 5.1910.0060.000 1.244 253.3600.121 0.000 843.0256.273.128 9.670 244.40 0.02 180.0 11/2/2023 08:03 0.000244.852-0.001 4.641 0.059492.372 1.764 1.812 5.2570.1330.000 1.200 253.2360.087 0.000 843.0255.962.880 9.676 244.85 0.02 180.0 Baseline System with Response Time 11/2/2023 08:06 0.0000.000-0.001 0.000 0.0000.000 0.000 0.346 0.3490.0000.000 0.000 0.2120.000 0.000 843.00.300.131 0.000 0.00 0.19 180.0 11/2/2023 08:06 0.0000.000-0.001 0.000 0.0000.000 0.000 0.262 0.2780.0000.000 0.000 0.1920.000 0.000 843.00.290.153 0.000 0.00 0.19 180.0 11/2/2023 08:07 0.0000.000-0.001 0.000 0.0000.000 0.000 0.330 0.1920.0000.000 0.000 0.1160.000 0.000 843.00.230.177 0.000 0.00 0.18 180.0 Run 1 - A 30minute/60min 11/2/2023 09:05 4.97847.27810.945 5.873 667.5930.000 0.000 0.000 47.4580.0009.765 0.000 12.9660.000 0.991 844.016.131.778 0.000 52.26 7.29 180.0 11/2/2023 09:06 4.54846.87111.236 5.858 670.0500.000 0.000 0.000 47.3870.0009.731 0.000 12.6870.000 0.990 844.015.821.724 0.000 51.42 7.21 180.0 11/2/2023 09:07 4.89346.30710.661 5.891 671.0980.000 0.000 0.000 47.2780.0009.675 0.000 12.7760.000 1.002 844.015.981.802 0.000 51.20 7.42 180.0 11/2/2023 09:08 0.00033.85810.953 5.745 740.6520.000 0.000 0.000 46.3510.00012.589 0.000 17.7050.000 2.285 844.024.943.998 0.000 33.86 7.52 180.0 11/2/2023 09:09 0.00033.42811.720 5.713 721.0570.000 0.000 0.000 42.9040.00013.207 0.000 16.6440.000 2.571 844.024.594.208 0.000 33.43 7.30 180.0 11/2/2023 09:10 0.00038.65411.798 5.771 700.7650.000 0.000 0.000 39.6490.00012.871 0.000 15.6220.000 2.599 844.023.604.173 0.000 38.65 7.40 180.0 11/2/2023 09:11 0.00041.82410.421 5.890 691.2820.000 0.000 0.000 38.4440.00011.768 0.000 15.3240.000 2.578 844.023.264.166 0.000 41.82 7.45 180.0 11/2/2023 09:12 4.02543.84511.318 5.840 673.5770.000 0.000 0.000 48.1880.00010.278 0.000 12.9590.000 1.019 844.016.091.640 0.000 47.87 7.40 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 11/2/2023 09:13 4.33845.11211.605 5.830 671.6570.000 0.000 0.000 47.3450.0009.668 0.000 12.8300.000 1.009 844.015.971.682 0.000 49.45 7.39 180.0 11/2/2023 09:14 5.58545.27410.581 5.893 674.0320.000 0.000 0.000 47.3430.0009.518 0.000 12.8000.000 1.003 844.015.911.657 0.000 50.86 7.38 180.0 11/2/2023 09:15 4.91146.16911.243 5.845 673.9760.000 0.000 0.000 47.2860.0009.723 0.000 12.4930.000 1.005 844.015.651.726 0.000 51.08 7.38 180.0 11/2/2023 09:16 5.47546.79510.945 5.877 669.6250.000 0.000 0.000 47.1220.0009.820 0.000 12.7590.000 1.034 844.015.981.727 0.000 52.27 7.33 180.0 11/2/2023 09:17 5.38847.36110.542 5.915 670.9970.000 0.000 0.000 47.5420.0009.197 0.000 12.8090.000 0.960 844.015.911.774 0.000 52.75 7.35 180.0 11/2/2023 09:18 5.25047.43811.602 5.858 666.2010.000 0.000 0.000 46.8190.00010.023 0.000 12.5900.000 1.042 843.015.851.767 0.000 52.69 7.23 180.0 11/2/2023 09:19 4.49447.76312.991 5.774 664.2220.000 0.000 0.000 46.4980.00010.642 0.000 12.1820.000 1.100 843.015.411.541 0.000 52.26 7.34 180.0 11/2/2023 09:20 5.20145.36510.538 5.921 671.5470.000 0.000 0.000 48.3160.0009.263 0.000 13.0350.000 1.019 844.016.261.772 0.000 50.57 7.38 180.0 11/2/2023 09:21 0.00042.35712.031 5.771 690.7490.000 0.000 0.000 38.8240.00013.018 0.000 15.0450.000 2.620 844.023.094.202 0.000 42.36 7.21 180.0 11/2/2023 09:22 0.00041.22610.893 5.830 696.7380.000 0.000 0.000 39.8100.00012.447 0.000 15.6450.000 2.613 844.023.644.150 0.000 41.23 7.43 180.0 11/2/2023 09:23 0.00040.54710.987 5.830 697.9390.000 0.000 0.000 40.2450.00012.493 0.000 15.8050.000 2.605 844.023.874.276 0.000 40.55 7.34 180.0 11/2/2023 09:24 0.00039.00611.649 5.783 696.3230.000 0.000 0.000 39.8780.00012.673 0.000 15.7540.000 2.588 844.023.794.292 0.000 39.01 7.32 180.0 11/2/2023 09:25 0.00038.48710.529 5.855 698.3110.000 0.000 0.000 40.5310.00012.155 0.000 16.0470.000 2.574 844.023.984.168 0.000 38.49 7.42 180.0 11/2/2023 09:26 0.00038.84610.731 5.834 696.4200.000 0.000 0.000 40.2180.00011.983 0.000 15.9370.000 2.570 844.023.904.240 0.000 38.85 7.23 180.0 11/2/2023 09:27 0.00038.62711.253 5.824 702.1080.000 0.000 0.000 40.5910.00012.525 0.000 15.7080.000 2.638 844.023.784.200 0.000 38.63 7.41 180.0 11/2/2023 09:28 0.00038.50910.484 5.856 701.7180.000 0.000 0.000 40.9060.00011.944 0.000 16.2380.000 2.576 844.024.154.148 0.000 38.51 7.42 180.0 11/2/2023 09:29 0.00038.64812.204 5.742 697.7210.000 0.000 0.000 40.1480.00012.968 0.000 15.7550.000 2.658 844.023.894.234 0.000 38.65 7.21 180.0 11/2/2023 09:30 0.00038.55811.066 5.793 700.3060.000 0.000 0.000 40.4810.00012.398 0.000 16.0870.000 2.610 844.024.104.185 0.000 38.56 7.42 180.0 11/2/2023 09:31 0.00038.61011.485 5.779 698.7320.000 0.000 0.000 40.0470.00012.871 0.000 15.9980.000 2.649 844.024.104.202 0.000 38.61 7.35 180.0 11/2/2023 09:32 0.00037.91410.458 5.846 702.8180.000 0.000 0.000 41.0280.00012.306 0.000 16.2810.000 2.595 844.024.254.174 0.000 37.91 7.39 180.0 11/2/2023 09:33 0.00037.94510.577 5.844 702.3440.000 0.000 0.000 41.0330.00012.053 0.000 16.1020.000 2.611 844.024.104.164 0.000 37.95 7.32 180.0 11/2/2023 09:34 0.00038.52911.480 5.795 699.4050.000 0.000 0.000 40.1920.00012.515 0.000 15.9610.000 2.633 844.024.064.247 0.000 38.53 7.37 180.0 1.97041.70511.164 5.829 689.3320.000 0.000 0.000 43.3290.00011.403 0.000 14.6850.000 1.958 843.9320.7353.201 0.000 43.676 7.354 180.0Avg. Spike 1 11/2/2023 09:44 0.66749.1529.823 5.686 655.56336.668 0.000 0.000 47.1680.0008.268 4.979 33.4090.000 0.990 844.040.172.198 0.705 49.82 6.85 180.0 Run 1 - B 30minute/60min 11/2/2023 09:47 0.00035.37910.570 5.815 705.4510.000 0.000 0.000 43.0140.00012.024 1.379 17.2840.000 2.578 844.026.164.198 0.000 35.38 7.42 180.0 11/2/2023 09:48 0.00035.26310.661 5.820 706.2970.000 0.000 0.000 42.8570.00012.223 1.019 17.0950.000 2.579 844.025.714.170 0.000 35.26 7.41 180.0 11/2/2023 09:49 0.00035.36910.700 5.826 717.1650.000 0.000 0.000 42.5210.00012.035 0.784 16.9670.000 2.570 844.025.444.218 0.000 35.37 7.41 180.0 11/2/2023 09:50 0.00035.65411.220 5.773 715.7670.000 0.000 0.000 42.3210.00012.558 0.618 16.8490.000 2.571 844.025.234.233 0.000 35.65 7.28 180.0 11/2/2023 09:51 0.00035.53812.101 5.720 714.4360.000 0.000 0.000 42.1030.00013.225 0.452 16.6460.000 2.628 844.024.964.134 0.000 35.54 7.38 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 11/2/2023 09:52 0.00035.41210.914 5.799 719.6750.000 0.000 0.000 42.7520.00012.592 0.472 17.0730.000 2.604 844.025.424.230 0.000 35.41 7.39 180.0 11/2/2023 09:53 0.00035.53010.992 5.734 714.2550.000 0.000 0.000 42.4280.00012.790 0.245 16.9000.000 2.620 844.025.134.232 0.000 35.53 7.33 180.0 11/2/2023 09:54 0.00035.44611.149 5.772 714.3630.000 0.000 0.000 42.3880.00012.745 0.215 16.9250.000 2.612 844.025.054.133 0.000 35.45 7.38 180.0 11/2/2023 09:55 0.00035.75410.970 5.817 716.9230.000 0.000 0.000 42.4120.00012.593 0.150 16.9540.000 2.566 844.024.964.162 0.000 35.75 7.38 180.0 11/2/2023 09:56 0.00035.69410.962 5.809 716.4540.000 0.000 0.000 42.3220.00012.803 0.043 16.9280.000 2.613 844.024.964.170 0.000 35.69 7.38 180.0 11/2/2023 09:57 0.00036.01110.973 5.805 713.0740.000 0.000 0.000 41.9300.00012.576 0.000 16.7470.000 2.618 844.024.734.124 0.000 36.01 7.35 180.0 11/2/2023 09:58 0.00036.24611.046 5.796 712.5240.000 0.000 0.000 41.7940.00012.667 0.000 16.7330.000 2.566 844.024.674.201 0.000 36.25 7.37 180.0 11/2/2023 09:59 0.00036.20011.075 5.790 711.4950.000 0.000 0.000 41.7950.00012.915 0.038 16.7970.000 2.613 844.024.854.204 0.000 36.20 7.35 180.0 11/2/2023 10:00 0.00035.79811.117 5.790 712.5390.000 0.000 0.000 41.9260.00012.838 0.003 16.8100.000 2.618 844.024.854.206 0.000 35.80 7.34 180.0 11/2/2023 10:01 0.00035.90211.166 5.780 715.1150.000 0.000 0.000 42.0310.00012.942 0.044 16.9260.000 2.570 844.024.874.159 0.000 35.90 7.34 180.0 11/2/2023 10:02 0.00035.45311.202 5.784 716.1630.000 0.000 0.000 42.1080.00012.797 0.000 16.9050.000 2.539 844.024.834.273 0.000 35.45 7.38 180.0 11/2/2023 10:03 0.00035.83611.214 5.789 715.1040.000 0.000 0.000 41.9830.00012.869 0.000 16.9270.000 2.583 844.024.804.063 0.000 35.84 7.34 180.0 11/2/2023 10:04 0.00035.67711.286 5.801 718.5970.000 0.000 0.000 42.3900.00012.668 0.000 16.9980.000 2.582 844.024.904.102 0.000 35.68 7.36 180.0 11/2/2023 10:05 0.00035.16111.248 5.767 716.6340.000 0.000 0.000 41.9860.00012.653 0.000 16.9160.000 2.545 844.024.774.147 0.000 35.16 7.33 180.0 11/2/2023 10:06 0.00035.34711.299 5.770 712.9970.000 0.000 0.000 41.5560.00012.980 0.000 16.7330.000 2.593 844.024.704.173 0.000 35.35 7.34 180.0 11/2/2023 10:07 0.00035.49311.342 5.768 715.8830.000 0.000 0.000 41.8550.00012.728 0.000 16.9620.000 2.581 844.024.884.135 0.000 35.49 7.35 180.0 11/2/2023 10:08 0.00035.62011.380 5.766 716.1580.000 0.000 0.000 42.1640.00013.251 0.000 16.9790.000 2.612 844.025.084.313 0.000 35.62 7.34 180.0 11/2/2023 10:09 0.00035.28911.374 5.772 713.7890.000 0.000 0.000 41.8440.00013.076 0.000 16.9580.000 2.594 844.024.954.210 0.000 35.29 7.35 180.0 11/2/2023 10:10 0.00035.10711.382 5.776 715.0900.000 0.000 0.000 41.8080.00013.104 0.000 16.8180.000 2.606 844.024.874.263 0.000 35.11 7.32 180.0 11/2/2023 10:11 0.00035.31711.387 5.760 717.9850.000 0.000 0.000 42.3460.00012.889 0.000 16.9950.000 2.579 844.024.874.078 0.000 35.32 7.34 180.0 11/2/2023 10:12 0.00035.34011.382 5.761 722.5290.000 0.000 0.000 42.9060.00012.560 0.000 16.9980.000 2.533 844.024.854.179 0.000 35.34 7.34 180.0 11/2/2023 10:14 0.00035.10511.375 5.762 716.8020.000 0.000 0.000 42.0450.00012.687 0.000 16.9720.000 2.596 844.024.934.154 0.000 35.10 7.33 180.0 11/2/2023 10:15 0.00034.90311.361 5.758 715.1760.000 0.000 0.000 42.0110.00012.784 0.000 16.8930.000 2.569 844.024.774.112 0.000 34.90 7.37 180.0 11/2/2023 10:16 0.00035.45011.333 5.768 715.4240.000 0.000 0.000 41.9350.00012.839 0.000 16.9960.000 2.570 844.025.004.299 0.000 35.45 7.33 180.0 11/2/2023 10:17 0.00035.43011.293 5.768 718.7280.000 0.000 0.000 42.5430.00012.864 0.000 16.9200.000 2.588 844.024.894.197 0.000 35.43 7.35 180.0 0.00035.52411.182 5.781 715.0860.000 0.000 0.000 42.2020.00012.743 0.182 16.9200.000 2.587 844.0025.0034.182 0.000 35.524 7.356 180.0Avg. 0.98538.61511.173 5.805 702.2090.000 0.000 0.000 42.7660.00012.073 0.091 15.8020.000 2.272 843.9722.8693.691 0.000 39.600 7.355 180.0Run 1 Avg: Baseline 1 11/2/2023 10:22 0.1110.0000.001 0.000 0.6430.000 0.000 0.245 0.3390.0000.000 0.000 0.2000.000 0.000 844.00.210.010 0.000 0.11 0.15 180.0 Run 2 - A 30minute/60min 11/2/2023 10:25 0.00036.02911.052 5.767 713.5970.000 0.000 0.000 42.0230.00012.849 0.000 16.9430.000 2.589 843.024.854.098 0.000 36.03 7.33 180.0 11/2/2023 10:26 0.00036.16111.080 5.790 714.2520.000 0.000 0.000 42.0180.00012.762 0.000 16.9670.000 2.584 843.024.934.191 0.000 36.16 7.36 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 11/2/2023 10:27 0.00035.89511.082 5.787 718.7110.000 0.000 0.000 42.4700.00012.617 0.000 17.1330.000 2.589 843.025.114.196 0.000 35.89 7.37 180.0 11/2/2023 10:28 0.00035.22811.051 5.774 725.1390.000 0.000 0.000 43.7160.00012.558 0.000 17.2690.000 2.575 843.025.224.200 0.000 35.23 7.38 180.0 11/2/2023 10:29 0.00035.55811.061 5.770 719.8750.000 0.000 0.000 42.5980.00012.423 0.000 17.1290.000 2.558 843.025.014.156 0.000 35.56 7.36 180.0 11/2/2023 10:30 0.00036.20611.070 5.774 711.8230.000 0.000 0.000 41.5490.00012.400 0.000 16.9010.000 2.628 843.024.974.218 0.000 36.21 7.35 180.0 11/2/2023 10:31 0.00036.27111.097 5.785 712.2960.000 0.000 0.000 41.8880.00012.580 0.000 17.0430.000 2.633 843.025.224.369 0.000 36.27 7.38 180.0 11/2/2023 10:32 0.00035.95811.087 5.784 717.5350.000 0.000 0.000 42.4080.00012.672 0.000 17.2080.000 2.583 843.025.264.330 0.000 35.96 7.36 180.0 11/2/2023 10:33 0.00035.93111.104 5.794 715.2260.000 0.000 0.000 42.2180.00012.233 0.000 16.8500.000 2.589 843.024.814.165 0.000 35.93 7.35 180.0 11/2/2023 10:34 0.00036.03011.052 5.779 714.3260.000 0.000 0.000 42.0450.00012.130 0.000 16.9140.000 2.572 843.024.904.265 0.000 36.03 7.36 180.0 11/2/2023 10:35 0.00035.26211.085 5.797 718.8390.000 0.000 0.000 42.7640.00012.380 0.000 17.1390.000 2.552 843.025.004.131 0.000 35.26 7.38 180.0 11/2/2023 10:36 0.00035.68711.101 5.785 719.4180.000 0.000 0.000 42.7860.00012.692 0.000 17.0680.000 2.605 843.025.114.247 0.000 35.69 7.37 180.0 11/2/2023 10:37 0.00035.24611.074 5.771 719.9670.000 0.000 0.000 42.8950.00012.486 0.000 17.1620.000 2.594 843.025.134.175 0.000 35.25 7.36 180.0 11/2/2023 10:38 0.00035.67111.097 5.773 719.4530.000 0.000 0.000 42.7920.00012.394 0.000 17.1310.000 2.575 843.025.154.302 0.000 35.67 7.36 180.0 11/2/2023 10:39 0.00035.59811.098 5.770 718.9850.000 0.000 0.000 42.5950.00012.653 0.000 17.1110.000 2.593 843.025.074.164 0.000 35.60 7.35 180.0 11/2/2023 10:40 0.00035.65411.089 5.782 714.7380.000 0.000 0.000 42.1310.00012.376 0.000 16.9260.000 2.598 843.024.984.286 0.000 35.65 7.35 180.0 11/2/2023 10:41 0.00035.82211.081 5.785 716.9510.000 0.000 0.000 42.5890.00012.109 0.000 17.0920.000 2.575 843.025.024.165 0.000 35.82 7.36 180.0 11/2/2023 10:42 0.00036.43311.102 5.794 715.4330.000 0.000 0.000 42.4670.00012.422 0.000 17.0440.000 2.606 843.025.104.271 0.000 36.43 7.35 180.0 11/2/2023 10:43 0.00035.68611.077 5.782 722.3140.000 0.000 0.000 43.3390.00012.592 0.000 17.3960.000 2.577 843.025.334.165 0.000 35.69 7.37 180.0 11/2/2023 10:44 0.00035.24111.090 5.785 719.2900.000 0.000 0.000 42.8600.00012.308 0.000 17.3250.000 2.592 843.025.284.163 0.000 35.24 7.36 180.0 11/2/2023 10:45 0.00035.37111.081 5.773 717.0340.000 0.000 0.000 42.8390.00012.360 0.000 17.2540.000 2.614 843.025.284.196 0.000 35.37 7.35 180.0 11/2/2023 10:46 0.00035.42411.071 5.767 716.5770.000 0.000 0.000 42.6650.00012.689 0.000 17.1670.000 2.630 843.025.274.256 0.000 35.42 7.36 180.0 11/2/2023 10:47 0.00035.53211.068 5.767 716.8370.000 0.000 0.000 42.6560.00012.412 0.000 17.1940.000 2.597 843.025.234.267 0.000 35.53 7.36 180.0 11/2/2023 10:49 0.00035.10311.054 5.770 717.6620.000 0.000 0.000 42.6870.00012.480 0.000 17.2020.000 2.569 843.025.144.204 0.000 35.10 7.36 180.0 11/2/2023 10:50 0.00036.10711.057 5.785 713.7270.000 0.000 0.000 42.5770.00012.263 0.000 17.0610.000 2.593 843.025.114.301 0.000 36.11 7.34 180.0 11/2/2023 10:51 0.00036.05311.096 5.798 713.3870.000 0.000 0.000 42.2660.00012.395 0.000 16.8830.000 2.616 843.024.994.312 0.000 36.05 7.36 180.0 11/2/2023 10:52 0.00036.20211.072 5.776 711.3850.000 0.000 0.000 42.6160.00012.088 0.000 17.1720.000 2.617 843.025.234.237 0.000 36.20 7.33 180.0 11/2/2023 10:53 0.00036.10911.076 5.775 710.6710.000 0.000 0.000 42.5510.00012.434 0.000 17.1100.000 2.619 843.025.204.282 0.000 36.11 7.34 180.0 11/2/2023 10:54 0.00035.73811.067 5.764 710.4170.000 0.000 0.000 42.7560.00012.392 0.000 17.2950.000 2.600 843.025.394.344 0.000 35.74 7.34 180.0 11/2/2023 10:55 0.00036.06511.076 5.769 710.1350.000 0.000 0.000 42.8550.00012.434 0.000 17.3290.000 2.595 843.025.394.311 0.000 36.07 7.34 180.0 0.00035.77611.078 5.779 716.2000.000 0.000 0.000 42.5540.00012.453 0.000 17.1140.000 2.594 843.0025.1234.232 0.000 35.776 7.356 180.0Avg. Spike 2 11/2/2023 10:59 1.42748.56510.275 5.695 654.55235.731 0.000 0.000 47.8670.0008.954 2.693 33.3290.000 1.094 843.038.802.235 0.688 49.99 6.84 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Run 2 - B 30minute/60min 11/2/2023 11:03 0.00035.44411.068 5.771 707.7630.000 0.000 0.000 42.7430.00011.893 0.000 17.3630.000 2.651 843.025.554.329 0.000 35.44 7.34 180.0 11/2/2023 11:04 0.00036.08111.059 5.771 711.8390.000 0.000 0.000 42.9410.00012.126 0.000 17.4980.000 2.605 843.025.564.286 0.000 36.08 7.35 180.0 11/2/2023 11:05 0.00035.16411.046 5.772 713.9860.000 0.000 0.000 43.4320.00011.948 0.000 17.4400.000 2.635 843.025.594.318 0.000 35.16 7.35 180.0 11/2/2023 11:06 0.00035.05811.060 5.769 715.4540.000 0.000 0.000 43.1830.00012.022 0.000 17.6120.000 2.542 843.025.574.308 0.000 35.06 7.37 180.0 11/2/2023 11:07 0.00035.35511.055 5.764 714.3490.000 0.000 0.000 42.8930.00012.392 0.000 17.5670.000 2.621 843.025.624.215 0.000 35.35 7.35 180.0 11/2/2023 11:08 0.00034.89211.056 5.750 714.8960.000 0.000 0.000 42.8600.00012.211 0.000 17.4630.000 2.650 843.025.634.305 0.000 34.89 7.35 180.0 11/2/2023 11:09 0.00035.43111.083 5.763 718.3090.000 0.000 0.000 43.0960.00012.035 0.000 17.4650.000 2.613 843.025.564.302 0.000 35.43 7.36 180.0 11/2/2023 11:10 0.00035.03111.074 5.770 716.2640.000 0.000 0.000 42.5990.00011.932 0.000 17.3670.000 2.616 843.025.444.260 0.000 35.03 7.36 180.0 11/2/2023 11:11 0.00035.67711.059 5.759 715.8800.000 0.000 0.000 42.6830.00012.104 0.000 17.2540.000 2.612 843.025.294.213 0.000 35.68 7.34 180.0 11/2/2023 11:12 0.00035.45411.060 5.769 717.9800.000 0.000 0.000 43.0770.00012.111 0.000 17.2600.000 2.611 843.025.304.231 0.000 35.45 7.34 180.0 11/2/2023 11:13 0.00035.56311.058 5.771 716.9240.000 0.000 0.000 42.7920.00011.974 0.000 17.3920.000 2.581 843.025.334.168 0.000 35.56 7.35 180.0 11/2/2023 11:14 0.00035.63611.076 5.772 717.0590.000 0.000 0.000 42.6220.00012.000 0.000 17.3010.000 2.586 843.025.274.199 0.000 35.64 7.36 180.0 11/2/2023 11:15 0.00035.50311.061 5.753 718.2510.000 0.000 0.000 42.9760.00011.921 0.000 17.2920.000 2.608 843.025.424.367 0.000 35.50 7.33 180.0 11/2/2023 11:16 0.00035.57711.050 5.751 721.9830.000 0.000 0.000 43.7140.00012.068 0.000 17.4910.000 2.643 843.025.644.295 0.000 35.58 7.35 180.0 11/2/2023 11:17 0.00034.83111.080 5.758 719.5740.000 0.000 0.000 43.3210.00012.479 0.000 17.3450.000 2.623 843.025.524.390 0.000 34.83 7.34 180.0 11/2/2023 11:18 0.00034.85211.065 5.755 722.5820.000 0.000 0.000 43.5070.00012.076 0.000 17.2150.000 2.573 843.025.204.256 0.000 34.85 7.35 180.0 11/2/2023 11:19 0.00036.10711.055 5.761 713.3140.000 0.000 0.000 42.3790.00011.834 0.000 17.2600.000 2.622 843.025.384.309 0.000 36.11 7.32 180.0 11/2/2023 11:20 0.00035.17711.075 5.761 725.2300.000 0.000 0.000 43.7870.00011.889 0.000 17.4140.000 2.556 843.025.344.225 0.000 35.18 7.34 180.0 11/2/2023 11:21 0.00035.23311.105 5.779 716.8310.000 0.000 0.000 42.6580.00011.943 0.000 17.0500.000 2.574 843.025.034.251 0.000 35.23 7.35 180.0 11/2/2023 11:23 0.00035.35811.063 5.766 714.1740.000 0.000 0.000 42.2890.00011.813 0.000 17.1040.000 2.586 843.025.124.260 0.000 35.36 7.35 180.0 11/2/2023 11:24 0.00035.68511.084 5.757 716.3760.000 0.000 0.000 42.6160.00012.008 0.000 17.2960.000 2.607 843.025.314.201 0.000 35.68 7.35 180.0 11/2/2023 11:25 0.00035.76811.050 5.746 713.8140.000 0.000 0.000 42.3950.00012.210 0.000 17.2760.000 2.634 843.025.344.199 0.000 35.77 7.33 180.0 11/2/2023 11:26 0.00035.32511.072 5.762 718.3000.000 0.000 0.000 43.0050.00011.932 0.000 17.6080.000 2.594 843.025.684.321 0.000 35.33 7.34 180.0 11/2/2023 11:27 0.00035.62711.069 5.765 715.1080.000 0.000 0.000 42.6840.00011.778 0.000 17.4030.000 2.613 843.025.474.262 0.000 35.63 7.33 180.0 11/2/2023 11:28 0.00035.22811.054 5.762 717.5410.000 0.000 0.000 42.6990.00011.971 0.000 17.5490.000 2.600 843.025.494.111 0.000 35.23 7.34 180.0 11/2/2023 11:29 0.00035.60311.083 5.769 715.6850.000 0.000 0.000 42.6980.00012.109 0.000 17.3940.000 2.627 843.025.484.243 0.000 35.60 7.33 180.0 11/2/2023 11:30 0.00035.69911.085 5.769 715.4600.000 0.000 0.000 42.6330.00012.021 0.000 17.5240.000 2.632 843.025.624.249 0.000 35.70 7.33 180.0 11/2/2023 11:31 0.00035.57611.085 5.756 717.6340.000 0.000 0.000 43.4160.00012.060 0.000 17.6540.000 2.638 843.025.754.229 0.000 35.58 7.35 180.0 11/2/2023 11:32 0.00035.50111.071 5.758 716.0400.000 0.000 0.000 42.8370.00011.959 0.000 17.6950.000 2.625 843.025.754.206 0.000 35.50 7.33 180.0 11/2/2023 11:33 0.00035.74111.072 5.755 714.1510.000 0.000 0.000 42.6960.00011.959 0.000 17.6690.000 2.615 843.025.764.290 0.000 35.74 7.33 180.0 0.00035.43911.068 5.763 716.4250.000 0.000 0.000 42.9080.00012.026 0.000 17.4070.000 2.610 843.0025.4674.260 0.000 35.439 7.344 180.0Avg. 0.00035.60711.073 5.771 716.3130.000 0.000 0.000 42.7310.00012.239 0.000 17.2610.000 2.602 843.0025.2954.246 0.000 35.607 7.350 180.0Run 2 Avg: GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline 2 11/2/2023 11:36 0.0000.000-0.000 0.000 0.3760.000 0.000 0.287 0.0760.0000.000 0.000 0.1280.000 0.000 843.00.300.259 0.000 0.00 0.15 180.0 Run 3 - A 30minute/60min 11/2/2023 11:39 0.00035.09111.031 5.741 710.4810.000 0.000 0.000 42.1250.00011.685 0.000 17.5850.000 2.650 843.025.724.254 0.000 35.09 7.30 180.0 11/2/2023 11:40 0.00035.49611.042 5.747 713.7620.000 0.000 0.000 42.4120.00011.480 0.000 17.6260.000 2.630 843.025.864.465 0.000 35.50 7.33 180.0 11/2/2023 11:41 0.00034.97311.067 5.744 713.5880.000 0.000 0.000 42.5390.00011.637 0.000 17.6990.000 2.654 843.025.904.345 0.000 34.97 7.35 180.0 11/2/2023 11:42 0.00035.13411.022 5.736 711.8090.000 0.000 0.000 42.1730.00011.697 0.000 17.5370.000 2.628 843.025.654.282 0.000 35.13 7.34 180.0 11/2/2023 11:43 0.00034.95711.073 5.768 714.4860.000 0.000 0.000 42.4490.00011.672 0.000 17.4640.000 2.650 843.025.674.351 0.000 34.96 7.36 180.0 11/2/2023 11:44 0.00035.12311.056 5.761 713.2510.000 0.000 0.000 42.2760.00011.500 0.000 17.5270.000 2.639 843.025.674.305 0.000 35.12 7.36 180.0 11/2/2023 11:45 0.00035.12311.037 5.750 714.9090.000 0.000 0.000 42.6500.00011.500 0.000 17.7470.000 2.603 843.025.744.184 0.000 35.12 7.37 180.0 11/2/2023 11:46 0.00035.11111.047 5.746 713.0830.000 0.000 0.000 42.4960.00011.498 0.000 17.6220.000 2.610 843.025.764.378 0.000 35.11 7.36 180.0 11/2/2023 11:47 0.00035.17811.036 5.740 713.2630.000 0.000 0.000 42.2910.00011.813 0.000 17.6200.000 2.679 843.025.974.482 0.000 35.18 7.36 180.0 11/2/2023 11:48 0.00034.76111.007 5.734 714.6060.000 0.000 0.000 42.6260.00011.459 0.000 17.7320.000 2.659 843.025.984.391 0.000 34.76 7.37 180.0 11/2/2023 11:49 0.00035.21711.046 5.747 714.9720.000 0.000 0.000 42.4870.00011.486 0.000 17.8990.000 2.624 843.025.944.193 0.000 35.22 7.37 180.0 11/2/2023 11:50 0.00035.57711.047 5.751 711.7350.000 0.000 0.000 42.4120.00011.504 0.000 17.6410.000 2.637 843.025.764.270 0.000 35.58 7.35 180.0 11/2/2023 11:51 0.00034.90411.051 5.753 716.3510.000 0.000 0.000 43.0450.00011.783 0.000 17.7600.000 2.606 843.025.844.298 0.000 34.90 7.37 180.0 11/2/2023 11:52 0.00035.26311.027 5.748 716.6860.000 0.000 0.000 42.8790.00011.337 0.000 17.7750.000 2.606 843.025.844.277 0.000 35.26 7.37 180.0 11/2/2023 11:53 0.00034.79311.028 5.748 714.9870.000 0.000 0.000 42.6400.00011.836 0.000 17.8110.000 2.613 843.025.954.375 0.000 34.79 7.38 180.0 11/2/2023 11:54 0.00034.80411.045 5.746 715.0910.000 0.000 0.000 42.7300.00011.897 0.000 17.7320.000 2.625 843.025.864.316 0.000 34.80 7.37 180.0 11/2/2023 11:55 0.00035.17911.035 5.735 712.0030.000 0.000 0.000 42.3450.00011.519 0.000 17.6560.000 2.646 843.025.814.294 0.000 35.18 7.34 180.0 11/2/2023 11:56 0.00035.29011.046 5.734 715.2130.000 0.000 0.000 42.9210.00011.839 0.000 17.8850.000 2.617 843.025.894.162 0.000 35.29 7.36 180.0 11/2/2023 11:58 0.00034.95411.058 5.751 717.0410.000 0.000 0.000 42.6830.00011.739 0.000 17.7630.000 2.591 843.025.804.290 0.000 34.95 7.36 180.0 11/2/2023 11:59 0.00035.06211.079 5.753 719.6210.000 0.000 0.000 43.2000.00011.799 0.000 17.6110.000 2.601 843.025.624.208 0.000 35.06 7.37 180.0 11/2/2023 12:00 0.00034.87711.051 5.745 717.1230.000 0.000 0.000 43.0250.00011.496 0.000 17.6670.000 2.620 843.025.764.277 0.000 34.88 7.37 180.0 11/2/2023 12:01 0.00034.93711.036 5.732 718.9080.000 0.000 0.000 43.6740.00011.818 0.000 17.6110.000 2.592 843.025.674.307 0.000 34.94 7.35 180.0 11/2/2023 12:02 0.00034.91211.024 5.728 718.4400.000 0.000 0.000 43.7800.00011.647 0.000 17.6860.000 2.593 843.025.754.319 0.000 34.91 7.35 180.0 11/2/2023 12:03 0.00034.70611.029 5.729 716.6270.000 0.000 0.000 43.4380.00011.537 0.000 17.5190.000 2.613 843.025.624.312 0.000 34.71 7.35 180.0 11/2/2023 12:04 0.00034.87411.018 5.728 719.2790.000 0.000 0.000 43.9340.00011.840 0.000 17.6730.000 2.591 843.025.804.412 0.000 34.87 7.35 180.0 11/2/2023 12:05 0.00035.27011.034 5.741 723.2650.000 0.000 0.000 44.5940.00011.732 0.000 17.7190.000 2.427 843.025.364.179 0.000 35.27 7.34 180.0 11/2/2023 12:06 0.00035.04811.023 5.749 719.8370.000 0.000 0.000 43.8980.00011.970 0.000 17.6230.000 2.551 843.025.634.360 0.000 35.05 7.36 180.0 11/2/2023 12:07 0.00035.14511.026 5.752 715.6180.000 0.000 0.000 43.4660.00011.574 0.000 17.3540.000 2.597 843.025.374.234 0.000 35.15 7.35 180.0 11/2/2023 12:08 0.00035.27611.030 5.744 714.7000.000 0.000 0.000 43.4940.00011.575 0.000 17.2170.000 2.589 843.025.214.225 0.000 35.28 7.37 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 11/2/2023 12:09 0.00035.40611.031 5.745 717.1980.000 0.000 0.000 43.7550.00011.759 0.000 17.3990.000 2.594 843.025.404.223 0.000 35.41 7.34 180.0 0.00035.08111.039 5.744 715.5980.000 0.000 0.000 42.9480.00011.654 0.000 17.6390.000 2.611 843.0025.7274.299 0.000 35.081 7.356 180.0Avg. Spike 3 11/2/2023 12:14 1.21748.82910.242 5.678 660.92436.387 0.000 0.000 48.9780.0008.395 2.701 33.4220.000 1.028 843.038.642.045 0.700 50.05 6.83 180.0 Run 3 - B 30minute/60min 11/2/2023 12:17 0.00035.06811.033 5.746 717.3750.000 0.000 0.000 43.2290.00011.781 0.000 17.2020.000 2.608 843.025.234.221 0.000 35.07 7.33 180.0 11/2/2023 12:18 0.00035.28011.015 5.720 719.4680.000 0.000 0.000 43.6220.00011.990 0.000 17.3490.000 2.553 843.025.354.349 0.000 35.28 7.33 180.0 11/2/2023 12:19 0.00035.13411.018 5.756 721.6500.000 0.000 0.000 44.0300.00011.834 0.000 17.4960.000 2.586 843.025.524.271 0.000 35.13 7.33 180.0 11/2/2023 12:20 0.00034.85111.026 5.740 721.1430.000 0.000 0.000 44.0230.00011.803 0.000 17.2020.000 2.593 843.025.224.251 0.000 34.85 7.34 180.0 11/2/2023 12:21 0.00035.02011.025 5.740 721.0530.000 0.000 0.000 43.9870.00011.643 0.000 17.2150.000 2.551 843.025.094.163 0.000 35.02 7.34 180.0 11/2/2023 12:22 0.00035.08411.014 5.741 718.2260.000 0.000 0.000 43.4770.00011.540 0.000 17.1010.000 2.588 843.025.074.186 0.000 35.08 7.34 180.0 11/2/2023 12:23 0.00035.62911.039 5.742 716.5380.000 0.000 0.000 43.1250.00011.965 0.000 16.9820.000 2.543 843.024.854.177 0.000 35.63 7.35 180.0 11/2/2023 12:24 0.00035.84611.052 5.757 715.7190.000 0.000 0.000 43.2460.00011.430 0.000 17.0750.000 2.601 843.025.144.288 0.000 35.85 7.35 180.0 11/2/2023 12:25 0.00035.69811.020 5.731 716.7910.000 0.000 0.000 43.6170.00011.829 0.000 17.2480.000 2.571 843.025.224.238 0.000 35.70 7.35 180.0 11/2/2023 12:26 0.00035.85711.008 5.735 719.2260.000 0.000 0.000 44.2030.00011.763 0.000 17.5950.000 2.588 843.025.634.292 0.000 35.86 7.34 180.0 11/2/2023 12:27 0.00035.85611.046 5.758 716.5010.000 0.000 0.000 43.5300.00011.794 0.000 17.4250.000 2.617 843.025.464.202 0.000 35.86 7.34 180.0 11/2/2023 12:28 0.00035.70710.990 5.753 720.7830.000 0.000 0.000 44.5460.00011.770 0.000 17.7580.000 2.414 843.025.253.992 0.000 35.71 7.34 180.0 11/2/2023 12:29 0.00035.40610.989 5.757 718.6360.000 0.000 0.000 44.1260.00011.639 0.000 17.6430.000 2.583 843.025.664.279 0.000 35.41 7.34 180.0 11/2/2023 12:30 0.00035.83911.023 5.762 712.9850.000 0.000 0.000 43.5110.00011.666 0.000 17.5280.000 2.612 843.025.574.230 0.000 35.84 7.33 180.0 11/2/2023 12:32 0.00035.58410.988 5.739 710.1030.000 0.000 0.000 43.1020.00011.335 0.000 17.3890.000 2.624 843.025.444.201 0.000 35.58 7.33 180.0 11/2/2023 12:33 0.00035.53311.000 5.738 712.8980.000 0.000 0.000 43.3790.00011.604 0.000 17.4770.000 2.604 843.025.514.235 0.000 35.53 7.34 180.0 11/2/2023 12:34 0.00035.35811.026 5.736 718.2620.000 0.000 0.000 43.9120.00011.770 0.000 17.6920.000 2.593 843.025.714.245 0.000 35.36 7.34 180.0 11/2/2023 12:35 0.00035.98310.998 5.742 711.3460.000 0.000 0.000 42.9490.00011.723 0.000 17.5190.000 2.598 843.025.614.339 0.000 35.98 7.33 180.0 11/2/2023 12:36 0.00035.46611.012 5.751 712.7360.000 0.000 0.000 43.0040.00011.552 0.000 17.4810.000 2.628 843.025.574.251 0.000 35.47 7.33 180.0 11/2/2023 12:37 0.00034.97111.006 5.751 716.1480.000 0.000 0.000 43.6970.00011.403 0.000 17.5080.000 2.632 843.025.584.207 0.000 34.97 7.34 180.0 11/2/2023 12:38 0.00035.15310.999 5.754 713.5990.000 0.000 0.000 43.2530.00011.513 0.000 17.5250.000 2.542 843.025.504.342 0.000 35.15 7.34 180.0 11/2/2023 12:39 0.00035.68611.012 5.749 714.1240.000 0.000 0.000 43.1400.00011.788 0.000 17.3870.000 2.559 843.025.394.327 0.000 35.69 7.34 180.0 11/2/2023 12:40 0.00035.59211.018 5.743 714.8170.000 0.000 0.000 43.2190.00011.843 0.000 17.4760.000 2.587 843.025.514.296 0.000 35.59 7.34 180.0 11/2/2023 12:41 0.00035.50011.020 5.739 723.5110.000 0.000 0.000 44.9150.00011.831 0.000 18.0280.000 2.418 843.025.584.070 0.000 35.50 7.34 180.0 11/2/2023 12:42 0.00035.19511.019 5.731 714.8620.000 0.000 0.000 43.4760.00011.842 0.000 17.6630.000 2.586 843.025.704.295 0.000 35.20 7.33 180.0 11/2/2023 12:43 0.00035.51111.026 5.751 714.5090.000 0.000 0.000 43.2200.00011.690 0.000 17.5240.000 2.626 843.025.624.263 0.000 35.51 7.33 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 11/2/2023 12:44 0.00035.74911.056 5.766 710.9740.000 0.000 0.000 42.6210.00012.124 0.000 17.3230.000 2.593 843.025.304.182 0.000 35.75 7.34 180.0 11/2/2023 12:45 0.00036.05111.030 5.764 711.0440.000 0.000 0.000 42.7520.00011.968 0.000 17.2570.000 2.587 843.025.184.132 0.000 36.05 7.34 180.0 11/2/2023 12:46 0.00036.05811.011 5.750 716.0410.000 0.000 0.000 43.2900.00011.713 0.000 17.5130.000 2.583 843.025.484.197 0.000 36.06 7.33 180.0 11/2/2023 12:47 0.00035.58910.998 5.751 718.9720.000 0.000 0.000 43.6220.00011.399 0.000 17.7330.000 2.563 843.025.674.222 0.000 35.59 7.35 180.0 0.00035.50811.017 5.746 716.3350.000 0.000 0.000 43.5270.00011.718 0.000 17.4440.000 2.578 843.0025.4204.231 0.000 35.509 7.338 180.0Avg. 0.00035.29511.028 5.745 715.9660.000 0.000 0.000 43.2380.00011.686 0.000 17.5410.000 2.594 843.0025.5744.265 0.000 35.295 7.347 180.0Run 3 Avg: Baseline 3 11/2/2023 12:51 0.0000.000-0.000 0.000 0.0450.000 0.000 0.428 0.0000.0000.000 0.000 0.0280.000 0.000 842.00.070.063 0.000 0.00 0.15 180.0 Post CTS 11/2/2023 12:54 0.0001.3590.077 0.000 3.9760.000 0.000 0.286 0.0180.0030.000 96.949 0.0000.000 0.000 842.064.640.000 0.000 1.36 0.21 180.0 11/2/2023 12:54 0.0000.0000.043 0.000 1.3340.000 0.000 0.210 0.3490.0000.000 97.776 0.0870.000 0.001 842.065.280.000 0.000 0.00 0.21 180.0 11/2/2023 12:54 0.0000.0000.017 0.000 1.1350.000 0.000 0.162 0.0000.0000.000 97.529 0.0000.000 0.000 842.065.160.212 0.000 0.00 0.21 180.0 Post O2/NO2 11/2/2023 12:56 96.3100.045-0.001 0.000 0.0000.000 0.130 0.260 0.4770.1580.000 0.000 0.0000.000 0.000 842.00.270.408 0.000 96.35 8.56 180.0 11/2/2023 12:57 97.4700.172-0.000 0.000 0.6670.000 0.129 0.356 0.1510.0010.000 0.000 0.0000.000 0.023 842.00.050.000 0.000 97.64 8.57 180.0 11/2/2023 12:57 96.9020.000-0.000 0.000 0.0000.000 0.140 0.375 0.2890.0000.000 0.000 0.0000.000 0.044 842.00.380.438 0.000 96.90 8.58 180.0 Post 5-Gas 11/2/2023 12:59 0.000243.3660.066 4.657 4.217491.604 1.733 1.589 5.9090.1000.000 1.384 252.3310.062 0.000 842.0255.393.202 9.627 243.37 0.16 180.0 11/2/2023 12:59 0.000244.2190.021 4.719 2.413493.347 1.780 1.414 5.4470.0320.381 1.264 253.4650.117 0.000 842.0256.393.127 9.665 244.22 0.02 180.0 11/2/2023 12:59 0.000244.6920.001 4.791 1.909492.817 1.754 1.966 10.0640.2480.000 1.252 253.3940.000 0.000 842.0256.393.239 9.684 244.69 0.02 180.0 11/2/2023 12:59 0.000244.392-0.000 4.803 1.237493.203 1.738 1.740 5.9270.0150.000 1.114 253.3840.000 0.000 842.0256.153.028 9.719 244.39 0.02 180.0 11/2/2023 12:59 0.000245.289-0.000 4.804 0.709494.384 1.752 1.747 5.7230.1430.000 1.187 253.2510.000 0.000 842.0256.053.014 9.693 245.29 0.02 180.0 11/2/2023 12:59 0.000245.933-0.000 4.659 0.000493.559 1.739 1.796 5.5120.5170.000 1.131 253.2780.000 0.000 842.0255.902.795 9.716 245.93 0.02 180.0 End of Test Purge 11/2/2023 13:01 0.0000.374-0.000 0.016 0.4450.000 0.000 0.000 0.0500.0000.000 0.000 1.3060.000 0.000 842.01.460.228 0.000 0.37 0.15 180.0 11/2/2023 13:01 0.0000.000-0.000 0.000 0.0000.000 0.000 0.240 0.4860.0000.000 0.000 0.8420.000 0.000 842.00.840.000 0.000 0.00 0.15 180.0 11/2/2023 13:02 0.0000.000-0.000 0.000 0.0320.000 0.000 0.226 0.0730.0000.000 0.000 0.6640.239 0.000 842.00.860.297 0.000 0.00 0.15 180.0 11/2/2023 13:02 0.0000.000-0.000 0.000 0.0000.000 0.000 0.312 0.1780.0000.000 0.000 0.3870.000 0.000 842.00.410.033 0.000 0.00 0.15 180.0 11/2/2023 13:02 0.0000.000-0.000 0.000 0.0000.000 0.000 0.118 0.0000.0000.000 0.000 0.3280.000 0.000 842.00.330.000 0.000 0.00 0.15 180.0 11/2/2023 13:02 0.0000.000-0.000 0.000 0.0000.000 0.000 0.163 0.0000.0000.000 0.000 0.4640.000 0.000 842.00.610.213 0.000 0.00 0.15 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 11/2/2023 13:02 0.0000.000-0.000 0.000 0.0000.000 0.000 0.370 0.0000.0000.000 0.000 0.3940.404 0.000 842.00.530.210 0.000 0.00 0.15 180.0 11/2/2023 13:02 0.0000.000-0.001 0.000 0.0000.000 0.000 0.208 0.0000.0000.000 0.000 0.3590.389 0.000 842.00.360.000 0.000 0.00 0.15 180.0 GAS, Inc. Performance Test Report Test Type: Initial Test Date: 11/2/2023 Caterpillar G3606 Lean Burn (4 Cycle) DOM: 5/15/23 303 W. 3rd St Elk City , OK 73644(580) 225-0403 Test Started:Test Completed:03:36 PM 07:57 PM Source: Unit Number: Unit 4 Serial Number: 3XF00116 Engine Hours:22811 Permit #: #DAQE-AN143380008-23 Location: Duchesne County, Utah Prepared on Behalf of: Ovintiv USA Inc. Ranch Compressor Station 40 CFR Part 60 Subpart JJJJ CO NOx NMNEHC 7.830 1.960 2.350 0.107 1.636 1.741 6.329 58.767 65.218 2.000 1.000 0.700 0.028 0.425 0.452 Pass Pass Pass Pass Pass Pass Federal State Federal State Federal State Results lb/hr Results ppmvd Permit lb/hr Results g/hp-hr Permit g/hp-hr PASS ALL Index Tables Figures Appendices Table 5.1 (Run Summaries)................................................................ Table 6.1 (Volumetric Flow Rate Data)............................................... Table 6.2 (Stack Gas Measurements)................................................. Table 8.1 (Oxygen Calibration)........................................................... Annex Table 1.2.1 (Certified Calibration Bottle Concentrations)......... Annex Table 1.2.2 (Measurement System Capabilities)..................... Annex Table 1.3.1 (Test Specific Target Analytes)............................. Annex Table 4.1 (Measure System Capabilities)................................ Figure 6.1 (Location of Traverse Points per Method 1)....................... Annex Figure 1.4.1 (Sampling Train).................................................. Annex Figure 1.4.2 (Sampling Points)................................................. Annex Figure 1.4.3 (Sampling Port Locations).................................... Certified Calibration Bottle Certificates................................................ Tri Probe Certification via GD-031...................................................... GAS ALT 141_FTIR EPA.................................................................... Tester Qualifications (resume)............................................................ Raw Data............................................................................................ 27 Key Personnel.............................................................................1.0 3 Sampling System........................................................................2.0 3 Methods Used.............................................................................3.0 3 Test Summaries..........................................................................4.0 5 Run Summaries..........................................................................5.0 6 6 Volumetric Flow Rate Data.........................................................6.0 7 7 7 7 Calculations................................................................................7.0 8 9 12 12 13 15 13 14 14 20 25 28 29 Oxygen Calibration.....................................................................9 Engine Parameter Data Sheet....................................................10 QA/QC Results............................................................................11 Signature Page...........................................................................12.0 Appendices.................................................................................13.0 Bottle Certs.................................................................................2014.0 Tri Probe Certification via GD-031..............................................2515.0 GAS ALT 141_FTIR EPA............................................................16.0 Tester Qualifications (resume)....................................................2817.0 D6348 Annexes..........................................................................1211.0 18 19 26 8.0 9.0 10.0 Raw Data....................................................................................2918.0 1.0 Key Personnel GAS, Inc. Archrock 2.0 Sampling System The sampling system used consisted of a Stainless steel probe, heated Teflon line, gas conditioning system, and a Gasmet model DX4000 FTIR analyzer. The gas conditioning system used was a Gasmet Personal Sampling System with a Zirconium Oxide oxygen sensor. 3.0 Methods Used This extractive FTIR based field test method is used to quantify gas phase concentrations of multiple target analytes (CO, NOX, CH2O, & VOC's) from stationary source effluent. Because an FTIR analyzer is potentially capable of analyzing hundreds of compounds, this test method is not analyte or source specific. The analytes, detection levels, and data quality objectives are expected to change for any particular testing situation. It is the responsibility of the tester to define the target analytes, the associated detection limits for those analytes in the particular source effluent, and the required data quality objectives for each specific test program. Provisions are included in this test method that require the tester to determine critical sampling system and instrument operational parameters, and for the conduct of QA/QC procedures. Testers following this test method will generate data that will allow an independent observer to verify the valid collection, identification, and quantification of the subject target analytes. EPA Method 1 & 1A EPA Method 2 & 2C EPA Method 3A The purpose of the method is to provide guidance for the selection of sampling ports and traverse points at which sampling for air pollutants will be performed pursuant to regulations set forth in this part. This method is applicable for the determination of the average velocity and the volumetric flow rate of a gas stream. The average gas velocity in a stack is determined from the gas density and from measurement of the average velocity head with a standard pitot tube. Velocity readings are taken from each stack at 16 separate traverse points (Table 6.1) and used to determine the engines mass emissions rate, calculated utilizing the formulas seen in section 7.0 of this report. This is a procedure for measuring oxygen (O2) and carbon dioxide (CO2) in stationary source emissions using a continuous instrumental analyzer. Quality assurance and quality control requirements are included to assure that the tester collects data of known quality. Documentation to these specific requirements for equipment, supplies, sample collection and analysis, calculations, and data analysis will be included. ASTM D6348-03 Kevin Jamison 3 Aaron King Gas, Inc. 4.0 Test Summary T e s t S u m m a r y Site Verification Photos Gas, Inc. Unit Unit 4 with a serial number of 3XF00116 which is a Caterpillar G3606 engine located at Ranch Compressor Station and operated by Ovintiv USA Inc. was tested for emissions of: Carbon Monoxide, Oxides of Nitrogen, and Volatile Organic Compounds. The test was conducted on 11/2/2023 by Aaron King with Great Plains Analytical Services, Inc. All quality assurance and quality control tests were within acceptable tolerances. The engine is a natural gas fired Lean Burn (4 Cycle) engine rated at 1775 brake horse power (BHP) at 1000 RPM. The engine was operating at 1745 BHP and 900 RPM which is 98.33% of maximum engine load during the test. The test HP calculation can be found on page 8. The engine was running at the maximum load available at the test site. This test will satisfy the testing requirements for 40 CFR Part 60 Subpart JJJJ. Unit Unit 4 is authorized to operate under permit #DAQE-AN143380008-23. 4 4.0 Test Summary Engine/Compressor Specs Ranch Compressor StationLocation Unit 4Unit ID Make Caterpillar Site Elevation ft.5779 Model G3606 Atmospheric Pressure psi.11.82 Serial Number 3XF00116 Stack Diameter in.20 mfg. rated hp 1775 Yes 1000 Date of Manufacture 5/15/2023 Engine/Compressor Operation Run 2 Run 3 3 Run AveragesRun 1 Test Horsepower 1686 1775 1775 1745 899 900 900 900 Percent Load % Intake Manifold Pressure (hg) 94.99%100.00%100.00%98.33% 43.33 48.62 49.43 47.13 Intake Manifold Temperature (F)137.70 140.40 139.10 139.07 Ambient Conditions Ambient Temperature Dry (F)44.00 54.00 52.00 50.00 Exhaust Flow Data Q Stack (dscfh) Q Stack (dscm/hr) 232723.18 234202.08 232959.82 233295.03 6589.92 6631.80 6596.63 6606.12 Moisture Fraction Bws Fuel Consumption (Btu/h[-hr) 0.09 0.09 0.09 0.09 0 0 0 0 Fuel Flow (dscfh) Fuel (btu/scf)1020 1020 1020 1020 O2 F factor 8710.0 8710 8710 8710 Results Method 3A Corrected O2% Dry Moisture %8.68%8.68%8.70%8.69% T e s t S u m m a r y mfg. rated rpm Test RPM 10.78%10.79%10.81%10.79% Permitted Standards Results 5 Catalyst 0.0270.027 Run 1 Run 2 Run 3 3 Run Average Pass Permits 03:36 PM 04:52 PM 06:09 PM 11/2/2023 CO (g/hp-hr)0.030 0.0282.000 Pass StateFederal CO (ppmvw)5.972 5.709 5.657 5.779 CO (ppmvd)6.539 6.251 6.195 6.329 CO (mol wt) 28.01 CO (ppmvd) @15% O2 3.813 3.649 3.622 3.695 Fail CO (ppbvd) @15% O2 3813.072 3649.185 3621.755 3694.671 Fail 0.1050.106CO (lbs/hr)0.111 0.1077.830 Pass NOx (g/hp-hr)0.444 0.415 0.418 0.4251.000 Pass NOx (ppmvw)54.276 53.054 53.659 53.663 NOx (ppmvd)59.436 58.094 58.770 58.767 NOx (mol wt) 46.01 59.564 60.021 59.076 59.554NMNEHC (ppmvw) 65.226 65.723 64.703 65.218NMNEHC (ppmvd) NOx (ppbvd) @15% O2 34657.674 33911.728 34356.567 34308.656 Fail NOx (ppmvd) @15% O2 34.658 33.912 34.357 34.309 Fail NMNEHC (mol wt) 44.10 38034.301 38365.345 37824.974 38074.873 FailNMNEHC (ppbvd) @15% O2 0.467 0.450 0.441 0.4520.700 PassNMNEHC (g/hp-hr) 1.737 1.761 1.725 1.7412.350 PassNMNEHC (lbs/hr) 38.034 38.365 37.825 38.075 FailNMNEHC (ppmvd) @15% O2 NOx (lbs/hr)1.651 1.624 1.634 1.6361.960 Pass Gas, Inc. 5.0 Run Summaries Summary Source Run 1 R u n Table 5.1 Run Summaries S u m m a r i e s 6 0.00Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture % 5.97 0.00 48.96 0.00 5.31 0.00 54.28 0.27 59.56 0.18% 9.38% 0.00% 8.68% NMNEHC 5.86 48.96 5.35 54.31 59.37 9.38%8.69% 48.70 63.02 0.68 63.69 80.64 8.66%7.97% 6.08 48.96 5.28 54.24 59.76 9.38%8.67% 0.00 0.00 0.00 0.00 0.44 0.16%0.00% Avg. Wet NO2NO Summary Source Run 2 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 0.00 0.00 0.00 0.00 0.44 0.16%0.00% 5.78 48.87 4.46 53.33 59.69 9.39%8.68% 48.42 64.35 1.44 65.79 81.52 8.70%7.99% 5.64 48.54 4.24 52.78 60.35 9.39%8.68% 0.00 0.00 0.00 0.00 0.42 0.17%0.00% Avg. Wet 5.71 48.71 4.35 53.05 60.02 9.39%8.68% NO2NO Summary Source Run 3 Baseline Source Spike Source Baseline PPM Wet CO NOx Oxygen %Moisture %NMNEHC 5.58 49.51 4.55 54.06 58.81 9.40%8.70% 49.26 64.45 0.49 64.94 79.83 8.71%7.98% 5.74 49.09 4.17 53.26 59.34 9.40%8.69% 0.00 0.00 0.00 0.00 0.56 0.19%0.00% 0.00 0.00 0.00 0.00 0.42 0.17%0.00% Avg. Wet 5.66 49.30 4.36 53.66 59.08 9.40%8.70% NO2NO Gas, Inc. 6.0 Volumetric Flow Rate Data Volumetric Flow Rate Data .99 Stack diameter = Table 6.1. Data used for volumetric flow rate (Method 2) 20 inches or:1.67 feet. or:2.18 Square Feet Run 1 Average Pitot Tube Coefficient Cp(std)= H2O CO2 O2 CO Molecular Weight Stack Gas dry basis (Md) Molecular Weight Stack Gas wet basis (Ms) Stack Static Pressure (Pg) Stack Static Pressure (Pg) Atmospheric Pressure at Location (Pbar) Atmospheric Pressure at Location (Pbar) Absolute Stack Pressure (Ps) Stack Temperature Stack Temperature Stack Temperature Stack Gas Velocity Stack Flow Rate Q Stack Gas Wet Volmetric Flow Rate Stack Gas Dry Volumetric Flow Rate Sample after Back Purge: Within 5% of Last Δpstd reading: Stack Diameter (inches) Inches upstream from disturbance Inches downstream from disturbance scf/hr 0.64 Yes 20.00 175.00 50.00 scf/hr cfs ft/sec Deg R Deg F Deg C "Hg "Hg MBAR "Hg "H20 g/g mole g/g mole ppmd %d %d %d 8.68 29.10 0.61 Inches 3.34 10 16.66 Vo l u m e t r i c F l o w R a t e s Pitot readings are taken for Method 2 calculations using measuring points outlined in Method 1 Figure 6.1 16 Traverse Points Were Used Emissions Sampling Points - 3 point long line sampling probe First Sampling Point Taken @ 16.7% of Stack Diameter Second Sampling Point Taken @ 50% of Stack Diameter Third Sampling Point Taken @ 83.3% of Stack Diameter 4.54 9.38 5.97 829.00 0.05 24.49 24.53 675.13 1134.80 357.29 28.14 85.06 185.57 254846.40 232723.18 Run 2 8.68 29.10 0.62 4.52 9.39 5.71 829.00 0.05 24.49 24.53 677.00 1136.67 358.33 28.14 85.74 187.05 256451.84 234202.08 Run 3 8.70 29.10 0.62 4.53 9.40 5.66 829.02 0.05 24.49 24.53 676.00 1135.67 357.78 28.13 85.23 185.93 255153.04 232959.82 8.69 29.10 0.62 4.53 9.39 5.78 829.01 0.05 24.49 24.53 676.04 1135.71 357.80 28.14 85.34 186.18 255485.14 233296.26 *The exhaust stack did not present cyclonic flow conditions at the sampling location due to the absence of cyclones, inertial demisters, venturi scrubbers, or tangential inlets. * Cyclonic Flow Check (Pass/Fail): PASS Δpstd (in) H2O 0.44 Exhaust Temp F 675.00 Pitot Tube Sampling Points (Velocity) 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 Δpstd Average= Run 1 Table 6.2. Stack gas pressure readings measured with a standard pitot tube use for Volumetric Flow Rate 1.07 0.71 0.58 675.00 676.00 674.00 0.51 0.51 0.52 675.00 675.00 674.00 0.56 0.55 0.59 676.00 675.00 674.00 0.57 675.00 0.55 0.54 0.62 674.00 675.00 676.00 0.76 0.75 0.61 678.00 675.00 675.13 Δpstd = Velocity head measured by the standard pitot tube, (in.) H2O.Run 3 Δpstd (in) H2O 0.64 Exhaust Temp F 676.00 0.55 0.58 0.58 676.00 677.00 675.00 0.62 0.65 0.71 676.00 675.00 677.00 0.67 0.66 0.68 675.00 676.00 676.00 0.63 677.00 0.57 0.57 0.53 675.00 676.00 678.00 0.58 0.64 676.00 675.00 676.000.62 Run 2 Δpstd (in) H2O 0.56 Exhaust Temp F 677.00 0.68 0.57 0.62 676.00 677.00 678.00 0.55 0.57 0.57 677.00 676.00 678.00 0.61 0.71 0.66 676.00 676.00 677.00 0.61 678.00 0.57 0.57 0.69 675.00 679.00 677.00 0.73 0.70 678.00 677.00 0.62 677.00 7 Gas, Inc. 7.0 Calculations Method 2: Determination of Stack Gas Velocity and Volumetric Flow Rate *Note- Use of this method negates the need for any fuel related numbers for emissions calculations Nomenclature Δp(avg) = Velocity head of stack gas, mm H2O (in. H2O).Ps = Absolute stack pressure (Pbar+ Pg), mm Hg (in Hg) 3600 = Conversion Factor, sec/hr. A = Cross-sectional area of stack, m2 (ft2). Bws = Water vapor in the gas stream (from ASTM D6348) Kp = Velocity equation constant. Md = Molecular weight of stack gas, dry basis, g/g-mole (lb./lb.-mole). Ms = Molecular weight of stack gas, wet basis, g/g-mole (lb./lb. -mole). Pstd = Standard absolute pressure, 760 mm Hg (29.92 in. Hg). Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (dscf/hr.). Ts(abs) = Absolute stack temperature, °K (°R). = 460 + Ts for English units. Tstd = Standard absolute temperature, 293°K (528 °R). Vs = Average stack gas velocity, m/sec (ft./sec). *(Observed from Method 3 12.3) Dry Molecular Weight. Equation 3-1 Md = .44(.045)+.32(.108)+.28(.846+.001) = 29.102 LB/LB-MOLEMd = .44(%CO2)+.32(%O2)+.28(%N2+%CO) 12.5 Molecular Weight of Stack Gas. Equation 2-6 Ms = 29.102(1 -.08681)+.18.0(.08681) = 28.138 LB/LB-MOLEMs = Md(1-Bws)+18.0(Bws) 12.6 Average Stack Gas Velocity. Equation 2-7 Vs = 85.49*.99*√.61*√(1134.795/(24.53*28.138)) = 85.06 FT/SECVs = Kp*Cp(std)*√Δpavg*√(Ts(abs)/(Ps*Ms)) 12.7 Average Stack Gas Volumetric Flow Rate. Equation 2-8 Qsd = 3600(1-.087)85.06*2.182((528*24.53)/ (1134.795*29.92)) = 232723.18 DSCF/HRQsd = 3600(1-Bws)Vs*A((Tstd*Ps)/(Ts(abs)*Pstd)) *Standard conversion from feet to meters Q = 232723.181/35.315 = 6589.924 DSCM/HRQ = Qsd/35.315 Emission Rates (Examples use CO Run 1) Nomenclature CO corrected @ 15% O2 453.6= Conversion factor lb. to gram HP= Engines rated Horsepower A = Cross-sectional area of stack, m2 (ft2). BHP/HR. = Brake work of the engine, horsepower-hour (HP-HR.). BTU/HP-HR. = Brake Specific Fuel Consumption (HHV) ER = Emission rate of (CO) in g/HP-hr. F(d )= Volumes of combustion components per unit of heat content, scm/J (scf/million Btu). Q = Stack gas volumetric flow rate, in standard cubic meters per hour, dry basis LB/HR.= Emission rate of (CO) in LB/HR. Mfg.= Manufacturer Exhaust flow rate at 100% (ft3/min) O2 = Concentration of oxygen on a dry basis, percent. ppm= Parts Per Million (CO) ppm@15% O2= PPM corrected to 15% O2 Qsd = Dry volumetric stack gas flow rate corrected to standard conditions, dscm/hr. (DSCF/HR.). Run Time = Run Time in Minutes TPY= Tons per Year Mol wt.= Mol Weight of CO (28.01) Vs = Average stack gas velocity, m/sec (ft./sec). ppm @ 15% O2 = 6.539*(20.9-15)/(20.9-10.8%)) = 3.82 PPM @ 15% O2ppm @ 15% O2 = PPM*((20.9-15%O2)/(20.9-O2)) G/HP HR from 40 CFR Part 60 Subpart JJJJ (6.539*(1.164*10^-3)*6589.924*(Run Time/60))/1686 = .03 G/HP-HRg/hp-hr = (PPM*(1.164*10^-3)*Q*(Run Time/60))/BHP/HR LB/HR from Grams LB/HR = .03*1/453.6*1686 = .111 LB/HRlb/hr = ER*1/453.6*BHP-HR TPY TPY = .111*4.38 = .486 TPYTPY = LB/HR. *4.38 Horsepower HP Provided On Site Wet to Dry PPM 6.54 = 5.9715*(1/(1-.09))ppm wet * (1/(1-H2O) = ppm dry 8 Cp(std) = Standard pitot tube coefficient; use 0.99 Gas, Inc. 8.1 Calibration error test; how do I confirm my analyzer calibration is correct? After the tester has assembled, prepared and calibrated the sampling system and analyzer, they conduct a 3-point analyzer calibration error test before the first run and again after any failed system bias test or failed drift test. They then introduce the low-, mid-, and high-level calibration gases sequentially in direct calibration mode. At each calibration gas level (low, mid, and high) the calibration error must be within ± 2.0 percent of the calibration span. 8.0 Oxygen Calibration 8.2 Initial system bias and system calibration error checks. Before sampling begins, it is determined whether the high- level or mid-level calibration gas best approximates the emissions and it is used as the upscale gas. The upscale gas is introduced at the probe upstream of all sample- conditioning components in system calibration mode. 8.3 Post-run system bias check and drift assessment - confirming that each sample collected is valid. Sampling may be performed for multiple runs before performing the post-run bias or system calibration error check provided this test is passed at the conclusion of the group of runs. A failed final test in this case will invalidate all runs subsequent to the last passed test. (1) Next, zero gas is introduced as described above. The response must be within 0.5 percent of the upscale gas concentration. (2) Low-level gas reading is observed until it has reached a final, stable value and the results are recorded. The measurement system will be operated at the normal sampling rate during all system bias checks. (3) If the initial system bias specification is not met, corrective action is taken. The applicable calibration error test from Section 8.2.3 of EPA Method 7E is repeated along with the initial system bias check until acceptable results are achieved, after which sampling will begin. The pre- and post-run system bias must be within ± 5.0 percent of the calibration span for the low-level and upscale calibration gases. (1) If the post-run system bias check is not passed, then the run is invalid. The problem is then diagnosed and fixed, then another calibration error test and system bias is passed before repeating the run. (2) After each run, the low-level and upscale drift is calculated, using Equation 7E–4 in Section 12.5 from EPA Method 7E. If the post-run low- and upscale bias checks are passed, but the low-or upscale drift exceeds the specification in Section 13.3, the run data are valid, but a 3-point calibration error test and a system bias check must be performed and passed prior to additional testing. Table 8.1 Oxygen Calibration EPA Method 3A QA Worksheet (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Certified Gas Concentraion Low-Level (%) 0.00% Certified Gas Concentraion Mid-Level (%) Certified Gas Concentraion High-Level (%) (DIRECT) Analyzer Calibration Error (≤ 2%) Certified Concentration Value (%) Direct Calibration Response (%) Absolute Difference (%) Analyzer Calibration Error (%)Analyzer Direct Calibration Response Certified bottle value % 0.00% 0.00% 0.00% Zero Gas % Mid-Level Gas % High-Level Gas % Bias Pre Initial Value Bias Post Inital Values System Calibrations Response Pre (%) 0.00% System Bias (% of Span) Pre System Calibration Response Post (%) System Bias (% of Span) Post Drift (% of Span) 0.00%0.00%0.00%0.00% (SYSTEM) Calibration Bias Checks (≤ 5%) and Drift Checks (≤ 3%) Avg. Gas Concentration (Run 1) Avg. Gas Concentration (Run 2) Avg. Gas Concentration (Run 3) Effluent Gas (Cgas) Run 1 Effluent Gas (Cgas) Run 2 Effluent Gas (Cgas) Run 3 Linearity Check 0.00%0.00%0.00% Method 7E 3.4 To the extent practicable, the measured emissions should be between 20 to 100 percent of the selected calibration span. This may not be practicable in some cases of low concentration measurements or testing for compliance with an emission limit when emissions are substantially less than the limit. 7E 8.5: Note: that you may risk sampling for multiple runs before performing the post-run bias provided you pass this test at the conclusion of the group of runs Upscale Gas Analyzer Calibration Response (%) Zero Gas Upscale Gas EPA Method 3A QA Worksheet Zero Gas Mid-Level Gas High-Level Gas 100% Nitrogen O2 QA/QC Zero Gas %0.00% Mid-Level Gas % High-Level Gas % System Calibration Response Pre (%) System Calibration Response Post (%) Zero Gas % Upscale Cal Zero Gas % Upscale Cal Upscale Used Upscale Used 8.88% 20.82% 8.57% 8.58% 9.00% 9.00% 8.58%8.57% 8.88% 20.82% 9.00% 21.18% 9.00% 21.18% 9.00%21.18% 0.00% 9.00% 21.18% 0.12% 0.36% 0.55% 1.69% 9.00% Span Zero Offset 0.00% 21.18 0.00% 8.88%1.48%1.42%0.00% 10.28% 10.29% 10.30% 10.78% 10.79% 10.81% 9 Gas, Inc. 885.0 877.6 878.9 24.8 24.9 23.7 531.0 532.0 533.7 126.0 126.0 125.3 9.0 Engine Parameter Data Sheet Company Site Elevation (ft) Facility Unit ID Date Make Ovintiv USA Inc. Ranch Compressor Station 11/2/2023 5779 Unit 4 Caterpillar Model Serial Number G3606 3XF00116 Technician Aaron King Run Start Times 03:36 PM 04:52 PM 06:09 PM 07:57 PM Run 1 Run 2 Run 3 Completed Engine Parameter Data Run 1 Engine Speed (RPM)899.0 900.0 900.0 899.7 Engine Hours 22808 22809 22810 22811 Intake Manifold Pressure (psi)33.1 35.7 36.1 35.0 Intake Manifold Temp °F 137.7 140.4 139.1 139.1 Engine Load (BHP)1686.0 1775.0 1775.0 1745.3 Ambient Temp °F 44.0 54.0 52.0 50.0 Humidity %28.0 18.0 19.0 21.7 Dew Point °F 13.0 11.0 11.0 11.7 Caterpillar YesCatalyst (Yes or No) AFR Manufacturer/Type Caterpillar Caterpillar Caterpillar 10 Run 3 AverageRun 2 21.5 874.0Discharge Pressure (psi) Suction Pressure (psi) 538.0 124.0 Catalyst Pressure Drop H2O Catalyst Outlet Temp °F Catalyst Inlet Temp °F Gas, Inc. 10.0 QA/QC Results Average:Carbon monoxide CO Gas, Inc. 0.00 R e s u l t s Average:Nitrogen monoxide NO 0.00 Average:Nitrogen dioxide NO2 0.00 Average:NOx 0.00 Average:VOC 0.07 Average:Oxygen 0.20 Pre-test Baseline Results Time: Q A / Q C Value:CTS Bottle Concentration 98.91 Value:CTS Compound Concentration Avg 97.42 Tolerance 2.00% Difference between measured and expected 1.51% CTS Direct to Analyzer Time: Average:Carbon monoxide CO 0.00 Average:Nitrogen monoxide NO 0.00 Average:Nitrogen dioxide NO2 0.00 Average:NOx 0.00 Average:VOC 0.20 Average:Oxygen 0.17 Pre-test System Zero Time: Mechanical Response Time 46 seconds Value:CTS Bottle Concentration 98.91 Value:CTS Compound Concentration Avg 96.79 Tolerance 5.00% Difference between measured and expected 2.14% Pre-test System CTS & Mechanical Response Time 90 secondsEquilibration Response Time Value:Spike Reported 253.20 Value:Spike Expected 252.50 System (Equilibration) Response Time Target (Spike) 45 secondsSystem Zero Response Time 45 secondsSystem Response Time System (Zero) Response Time 11 11.0 D6348 Annexes 1-8 D6348 Annexes 1. Test Plan Requirements Annex 1.2 The test quality objectives completed for the emissions test are demonstrated throughout Annexes 1, 2, 3, 4, 5, 6, 7 & 8 as layed out per ASTM D6348-03. All reference methods, pre-test and post test procedures were within acceptable limits. Data generated during the pre-test and post-test procedures are summarized below in order of the distinctive Annex. Three 60 minute test runs were performed. The final analyte concentrations are the average of each test run. Data was taken at 60 second intervals. Each 60 second measurement was the average of 600 scans. Propane is used as the surrogate compound for the Annex 5 Spiking Technique due to Propane being the VOC that is most commonly found in the combustion process of natural gas. Additionally, the molecular weight of Propane coincides with with molecular weight of VOC's per the EPA. Annex Table 1.2.1 Certified Calibration Bottle Concentrations Bottle Expiration NO2 Ethylene SF6 O2 (%) CC513838 7/12/2026 96.25 9.00% EB0010235 7/13/2031 98.91 CC455713 8/30/2030 21.18% Cylinder # CC79108 Expiration: 5-08-2031 Propane CO NO SF6 Bottle Value 252.50 498.60 247.30 9.73 Analyzer System Response 253.20 492.01 244.56 9.67 Percent Difference 0.28%1.32%1.11%0.63% Annex Table 1.2.2 Measurement System Capabilities SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 97.416 4.924 Spike Direct Propane 252.623 Mechanical Response Time SF6 9.670 CO 489.414 NO 244.395 Ethylene 96.789 46 seconds Analyzer Response Propane 253.196 SF6 9.669 CO 492.009 NO 244.555 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 253.240 CO 491.851 NO 244.859 90 seconds 108 seconds 7.90% 7.94% 8.13% 98.79% 99.90% 98.87% 9.650 12 Gas, Inc. Annex 1.3 Compounds Infrared Analysis Region (cm-1) Expected Concentration Range Measurement System Achievable Minimum Detectable Concentrations Required Measurement System Accuracy and Precision for Test Application CO 2000-2200 0-1200 ppm NO 1875-2138 NO2 2700-2950 VOC 2600-3200 910-1150 2550-2950 CH2O 2550-2850 Interfering Compounds * CO is analyzed in a separate analysis region than CO2 and H2O CO2 Water Vapor 926-1150 3200-3401 Annex Table 1.3.1 Test Specific Target Analytes and Data Quality Objectives 0.16267 ppm 4 ppm 0-1000 ppm 0.4007 ppm 2 ppm 0-100 ppm 0.4899 ppm 2 ppm 0-100 ppm 1.8520 ppm Total VOC's 1 ppm per VOC 0-100 ppm 0.7878 ppm 1 ppm 0-10% 0-22% 0% 0.20% n/a n/a * VOCs compiled of Acetaldehyde, Ethylene, Hexane, and Propane. Annex 1.4 Figure Annex 1.4.1 Sampling Train The testing instrumentation is housed in an enclosed vehicle which is located approximately 45 feet from the source. A heated sample line (sixty feet in length) is attached to the inlet of analyzer system and the source effluent discharges through the FTIR outlet. 13 Gas, Inc. Sampling Point Locations in Inches 16.7%3.340 50%10.000 83.3%16.660 Figure Annex 1.4.3 Sample Port Location Figure Annex 1.4.2 Sampling Points Interior Stack Diameter (inches): Inches Upstream: Inches Downstream: 20 175 50 14 Stack Gas Dry Volumetric Flow Rate (scf/hr): 233296.26 H2O%d @ Sampling Point:8.69 CO2%d @ Sampling Point:4.53 Pressure @ Sampling Point (Pg "H2O):0.62 Temperature @ Sampling Point (Deg F):676.04 Gas, Inc. D6348 Annex 2. Determination of FTIR Measurement System Minimum Detectable Concentrations (MDC#1) Target Analyte Results (ppm) CO 0.1627 NO 0.4007 NO2 0.4899 Ethylene 0.3782 Propane 0.4351 Hexane 0.2233 Acetaldehyde 0.8152 Formaldehyde 0.7878 D6348 Annex 3. FTIR Reference Spectra Calibration Transfer Standard Expected Measured Path Length Validated Ethylene 98.91 97.42 4.924 Passed D6348 Annex 4. Required Pre-Test Procedures Annex Table 1.2.2 Measurement System Capabilities 15 SF6 Parameter Measured Gas Concentration (ppm)Path Length Equilibration Time Dilution Factor % Recovery Path Length Ethylene 97.416 4.924 Spike Direct Propane 252.623 Mechanical Response Time SF6 9.670 CO 489.414 NO 244.395 Ethylene 96.789 46 seconds Analyzer Response Propane 253.196 SF6 9.669 CO 492.009 NO 244.555 Analyte Spike Recovery Propane & SF6 System Zero Nitrogen Post Spike System Propane 253.240 CO 491.851 NO 244.859 90 seconds 108 seconds 7.90% 7.94% 8.13% 98.79% 99.90% 98.87% 9.650 Gas, Inc. D6348 Annex 5. Analyte Spiking Technique Propane Spike Direct SF6 CO NO 252.500 9.730 498.600 247.300 252.623 9.670 489.414 244.395 0.05% 0.62% 1.84% 1.17% +/- 2% +/- 2% +/- 2% +/- 2% Pass Pass Pass Pass Parameter Gas Concentration Measured % Difference Specification Validated 48.020 0.000 Spike Average 63.395 0.764 Dilution Factor 7.901% Expected 64.174 % Recovery 98.790% Specification 70-130% <10% Spike Run 1 via the System Source Output Propane SF6 D6348 Annex 6. Determination of System Performance Parameters Noise Equivalent Absorbance (NEA) RMS High RMS Mid RMS Low Line Position: Demonstrating the peak positions align correctly (Manual Comparison +/- 20%) 0.000 Spike Average 0.768 Dilution Factor 7.942% Expected % Recovery Specification 70-130% <10% Spike Run 2 via the System Source Output Propane SF6 0.000 Spike Average 0.786 Dilution Factor 8.128% Expected % Recovery Specification 70-130% <10% Spike Run 3 via the System Source Output Propane SF6 47.314 63.270 63.996 98.870% 0.000546 0.001675 0.003201 48.108 64.274 64.336 99.900% Line Position Difference:Resolution Difference to Reference0.00%Pass Pass4.65% 16 Gas, Inc. Resolution The Gasmet GICCOR (Genzel Interferometer with Cube Corner Retroreflectors) interferometer is specially designed for maximum optical throughput and maximum signal to noise ratio of 7.72 (cm-1) remaining stable with any vibration and temperature changes. Detector Linerarity The Gasmet DX4000 is a low resolution spectrometer where the aperture is fixed to a maximum angle setting and the detector linearity was tested with an alternate approach. A three point linerarity of the CTS gas was performed and validated. D6348 Annex 7. Preparation of Analytical Quantification Algorithm The analytical accuracy of the quantification algorithm is satisfied via the results from Annex 5 per Annex 7.6 Regression Slope:-4.73669288 Pass Line Position Difference:Resolution Difference to Reference 4.65% D6348 Annex 8. Post Test Quality Assurance/Quality Control Procedures CTS Bottle Concentration: CTS Sample Concentration Average: Difference between measured and expected: Tolerance: 98.91 99.02 0.11% 5.00% POST CTS System Check: Run 1 Points 1 & 2 on CO/NO/Propane Run 2 Points 1 & 2 on CO/NO/Propane Run 3 Points 1 & 2 on CO/NO/Propane Run Data Validation - Automated vs Manual Reading Validated Comments All within 20% All within 20% All within 20% Passed Passed Passed Demonstrates no interferences observed. Demonstrates no interferences observed. Demonstrates no interferences observed. 17 Gas, Inc. 12.0 Signature Page Job/File Name: We certify that based on review of test data, knowledge of those individuals directly responsible for conducting this test, we believe the submitted information to be accurate and complete. Ovintiv USA Inc.; Ranch Compressor Station; Unit 4; JJJJ 18 Company: Print Name: Signature: Title: Phone Number: Date: Company:G.A.S. Inc.Date: Print Name: Title: 11/2/2023 Emissions Specialist Company:G.A.S. Inc.Date: Print Name: Title: Signature: Phone Number: Chris Oppel Director of Stack Testing 580-225-0403 11/2/2023 Aaron King Gas, Inc. Appendices Gas, Inc. Gas, Inc. CERTIcICATE Oc ANALYSIS Grade of Product: EPA PROTOCOL STANaARa Part Number:E05NI94E15AC014 Reference Number:54-402731888-1 Cylinder Number:CC79108 Cylinder Volume:147.0 CF Laboratory:124 - Chicago (SAP) - IL Cylinder Pressure:2015 PSIG PGVP Number:B12023 Valve Outlet:660 Gas Code:CO,CO2,NO,NOX,PPN,BALN Certification Date:May 08, 2023 Expiration Date:May 08, 2031 Certification performed in accordance with “EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)” document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. The results relate only to the items tested. The report shall not be reproduced except in full without approval of the laboratory. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. ANALYTICAL RESULTS Component Requested Actual Protocol Total Relative Assay Concentration Concentration Method Uncertainty Dates NOX 250.0 PPM 247.3 PPM G1 +/- 0.9% NIST Traceable 05/04/2023, 05/08/2023 NITRIC OXIDE 250.0 PPM 247.3 PPM G1 +/- 0.9% NIST Traceable 05/04/2023, 05/08/2023 PROPANE 250.0 PPM 252.5 PPM G1 +/- 0.7% NIST Traceable 05/04/2023 CARBON MONOXIDE 500.0 PPM 498.6 PPM G1 +/- 0.6% NIST Traceable 05/04/2023 CARBON DIOXIDE 5.000 %5.056 %G1 +/- 0.6% NIST Traceable 05/04/2023 NITROGEN Balance CALIBRATION STANaARaS Type Lot ID Cylinder No Concentration Uncertainty Expiration Date NTRM 20060336 EB0113149 250.3 PPM NITRIC OXIDE/NITROGEN +/- 0.8%Oct 19, 2026 PRM 12409 D913660 15.01 PPM NITROGEN DIOXIDE/AIR +/- 1.5%Feb 18, 2023 GMIS 1534012021105 ND73033 5.012 PPM NITROGEN DIOXIDE/NITROGEN +/- 1.6%Jun 15, 2025 NTRM 200602-13 6162697Y 243.3 PPM PROPANE/AIR +/- 0.5%Mar 17, 2027 NTRM 150605-41 CC453947 491.9 PPM CARBON MONOXIDE/NITROGEN +/- 0.6%Mar 05, 2027 NTRM 13060423 CC413685 7.489 % CARBON DIOXIDE/NITROGEN +/- 0.6%May 14, 2025 The SRM, NTRM, PRM, or RGM noted above is only in reference to the GMIS used in the assay and not part of the analysis. ANALYTICAL EnUIPMENT Instrument/Make/Model Analytical Principle Last Multipoint Calibration Nicolet iS50 AUP2010242 FTIR Apr 05, 2023 CO-1 SIEMENS ULTRAMAT 6E N1J5700 NDIR Apr 26, 2023 Nicolet iS50 AUP2010242 FTIR May 08, 2023 Nicolet iS50 AUP2010242 FTIR May 08, 2023 Nicolet iS50 AUP2110277 FTIR Apr 05, 2023 Triad Data Available Upon Request PERMANENT NOTES:Mixture contains nominal 10ppm Sulfur Hexafluoride as a tracer component. Actual tested value included within the original Certificate of Analysis. Contact the Airgas laboratory if a reprint is required NOTES:Mixture contains nominal 10ppm Sulfur Hexafluoride as a tracer component. Actual tested value included within the original Certificate of Analysis. Contact the Airgas laboratory if a reprint is required SF6 Results: JUE443: 9.76 PPM, EZZ970: 9.74 PPM, KDD300: 9.73 ppm, ESA918: 9.78 PPM, LMZ778: 9.73 PPM, JNX734: 9.76 PPM. Airgas Specialty Gases Airgas USA LLC 12722 S. Wentworth Ave. Chicago, IL 60628 Airgas.com Signature on file Approved for Release Page 1 of 1 Gas, Inc. CERTIcICATE Oc ANALYSIS Grade of Product: EPA PROTOCOL STANaARa Part Number:E03NI90E15W0003 Reference Number:54-402782817-1 Cylinder Number:CC513838 Cylinder Volume:145.0 CF Laboratory:124 - Chicago (SAP) - IL Cylinder Pressure:2015 PSIG PGVP Number:B12023 Valve Outlet:660 Gas Code:NO2,O2,BALN Certification Date:Jul 12, 2023 Expiration Date:Jul 12, 2026 Certification performed in accordance with “EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)” document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. The results relate only to the items tested. The report shall not be reproduced except in full without approval of the laboratory. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. ANALYTICAL RESULTS Component Requested Actual Protocol Total Relative Assay Concentration Concentration Method Uncertainty Dates NITROGEN DIOXIDE 100.0 PPM 96.25 PPM G1 +/- 1.2% NIST Traceable 07/05/2023, 07/12/2023 OXYGEN 9.000 %8.996 %G1 +/- 0.4% NIST Traceable 07/07/2023 NITROGEN Balance CALIBRATION STANaARaS Type Lot ID Cylinder No Concentration Uncertainty Expiration Date GMIS 1534012021603 CC502563 101.4 PPM NITROGEN DIOXIDE/NITROGEN +/- 1.1%Feb 23, 2026 PRM 12420 D887373 98.9 PPM NITROGEN DIOXIDE/AIR +/- 1.0%Feb 23, 2023 NTRM 10010604 K002585 9.967 % OXYGEN/NITROGEN +/- 0.3%Mar 22, 2028 The SRM, NTRM, PRM, or RGM noted above is only in reference to the GMIS used in the assay and not part of the analysis. ANALYTICAL EnUIPMENT Instrument/Make/Model Analytical Principle Last Multipoint Calibration MKS FTIR NO2 017707558 FTIR Jul 11, 2023 O2-1 HORIBA VA-5003 YH82Y07B PARAMAGNETIC Jul 05, 2023 Triad Data Available Upon Request Airgas Specialty Gases Airgas USA LLC 12722 S. Wentworth Ave. Chicago, IL 60628 Airgas.com Signature on file Approved for Release Page 1 of 1 Gas, Inc. CERTIcICATE Oc ANALYSIS Grade of Product: PRIMARY STANaARa Customer:MY SELF STORAGE PLACE, Part Number:X02NI99P15ACVH8 Reference Number:54-402789499-1 Cylinder Number:EB0010235 Cylinder Volume:144.0 CF Laboratory:124 - Chicago (SAP) - IL Cylinder Pressure:2015 PSIG Analysis Date:Jul 13, 2023 Valve Outlet:350 Lot Number:54-402789499-1 Expiration Date:Jul 13, 2031 Primary Standard Gas Mixtures are traceable to N.I.S.T. weights and/or N.I.S.T. Gas Mixture reference materials. ANALYTICAL RESULTS Component Req Conc Actual Concentration Analytical (Mole %)Uncertainty ETHYLENE 100.0 PPM 98.91 PPM +/- 1% NITROGEN Balance Notes:GREAT PLAINS ANALYTICAL, CERTIFIED BY FTIR. Airgas Specialty Gases Airgas USA LLC 12722 S. Wentworth Ave. Chicago, IL 60628 Airgas.com Signature on file Approved for Release Page 1 of 1 Gas, Inc. CERTIcICATE Oc BATCH ANALYSIS Grade of Product: BIP-BUILT IN PURIcIER Part Number:NI BIP300 Reference Number:29-400672389-1 Cylinder Analyzed:TW05-867349 Cylinder Volume:304.0 CF Laboratory:106 - Tulsa Fast Fill (SAP) - OK Cylinder Pressure:2640 PSIG Analysis Date:Feb 10, 2016 Valve Outlet:580 Lot Number:29-400672389-1 ANALYTICAL RESULTS Component Requested Certified Purity Concentration NITROGEN 99.999 %99.999 % OXYGEN 1 PPM 0.94 PPM WATER 1 PPM 0.058 PPM TOTAL HYDROCARBONS 0.1 PPM 0.1 PPM CARBON DIOXIDE 0.5 PPM 0.235 PPM CARBON MONOXIDE 0.5 PPM 0.235 PPM Permanent Notes:This cert includes values from the "fill" side and is not representative of the "use" side purity. Contact an Airgas Sales Representative for this information. Cylinders in Batch: 4263617Y, TW04671107, TW05-831574, TW05-865966, TW05-867349, TW05-867538, TW05-867578, TW05-881687, TW05-881820, TW05-920689, TW05-920760, TW05848694, TW05867441, TW05897265, TW05897512, TW05920678, TW05920686, TW05920695, TW05920781, TW05920874 Impurities verified against analytical standards traceable to NIST by weight and/or analysis. Airgas Mid South region Airgas USA LLC 9741 E. 56th St. North Tulsa, OK 74117 Airgas.com Signature on file Approved for Release Page 1 of 1 Gas, Inc. CERTIcICATE Oc ANALYSIS Grade of Product: EPA PROTOCOL STANaARa Part Number:E02NI79E15A00B1 Reference Number:54-402531082-1 Cylinder Number:CC455713 Cylinder Volume:146.0 CF Laboratory:124 - Chicago (SAP) - IL Cylinder Pressure:2015 PSIG PGVP Number:B12022 Valve Outlet:590 Gas Code:O2,BALN Certification Date:Aug 30, 2022 Expiration Date:Aug 30, 2030 Certification performed in accordance with “EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)” document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. The results relate only to the items tested. The report shall not be reproduced except in full without approval of the laboratory. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. ANALYTICAL RESULTS Component Requested Actual Protocol Total Relative Assay Concentration Concentration Method Uncertainty Dates OXYGEN 21.00 %21.18 %G1 +/- 0.4% NIST Traceable 08/30/2022 NITROGEN Balance CALIBRATION STANaARaS Type Lot ID Cylinder No Concentration Uncertainty Expiration Date NTRM 150104-18 K026588 22.454 % OXYGEN/NITROGEN +/- 0.2%Mar 08, 2027 ANALYTICAL EnUIPMENT Instrument/Make/Model Analytical Principle Last Multipoint Calibration O2-1 HORIBA MPA-510 3VUYL9NR Paramagnetic Aug 11, 2022 Triad Data Available Upon Request Airgas Specialty Gases Airgas USA LLC 12722 S. Wentworth Ave. Chicago, IL 60628 Airgas.com Signature on file Approved for Release Page 1 of 1 ㈱┠伲 Tri Probe Certification CE57IFICA7E 2F ANAL<6I6 GUDGH RI PURGXFW: CER7IFIED S7ANDARD-PROBE PURdXcW SeUfRUPaQce YeUified b\ diUecW cRPSaUiVRQ WR calibUaWiRQ VWaQdaUdV WUaceable WR N.I.S.T. *The SURbe liVWed RQ WhiV fRUP PeeWV Whe PXlWiSRiQW WUaYeUVe UeTXiUePeQW Rf EPA MeWhRd 7e, VecWiRQ 8.4 aV VhRZQ iQ Whe accRPSaQ\iQg daWa. MeWhRd 7e, VecWiRQ 8.4 VWaWeV WhaW Whe PXlWiSRiQW WUaYeUVe UeTXiUePeQW caQ be VaWiVfied b\ VaPSliQg Yia ³a PXlWi-hRle SURbe deVigQed WR VaPSle aW Whe SUeVcUibed SRiQWV ZiWh a flRZ +/- 10 SeUceQW Rf PeaQ flRZ UaWe´. ANAL<7ICAL 5E68L76 *CalibUaWiRQ cRQdXcWed iQ accRUdaQce ZiWh EmiVViRQ MeaVXUemeQW CeQWeU GXideliQe DRcXmeQW ± EMC GD-031 NRWeV: ___________________________________________________ ______________________ $ S S U R Y H G I R U 5 H O H D V H ' D W H Great Plains Analytical Services ͵Ͳ͵ W ͵ d St Elk City, OK, ͵ͶͶ ȋͷͺͲȌʹʹͷǦͲͶͲ͵ Faxǣ ȋͷͺͲȌʹʹͷǦʹͳʹ PaUW NXPbeU: 20S RefeUeQce NXPbeU: 8 LabRUaWRU\: GAS INC. SWack DiaPeWeU: 20" AQal\ViV DaWe: 1/20/2022 TaUgeW FlRZ RaWe: 3L/PiQ LOT NXPbeU: SN: A 8A 20S NXPbeU Rf PRiQWV: 3 RƵŶ η TŽƚal FlŽǁ ;LͬmͿ MeaƐƵƌed FlŽǁ PŽƌƚ A ;LͬmͿ ;Delƚa ƋϭͿ MeaƐƵƌed FlŽǁ PŽƌƚ B ;LͬmͿ ;Delƚa ƋϮͿ MeaƐƵƌed FlŽǁ PŽƌƚ C ;LͬmͿ ;Delƚa ƋϯͿ MHDQ PUREH PRUW 6DPSOHG FORZ (L/P) 5XQ 1 2 L3M 0.720 (8.54䧮) 0.650 (-2.01䧮) 0.620 (-6.53䧮) 0.663 5XQ 2 4 L3M 1.42 (7.30䧮) 1.31 (-1.01䧮) 1.24 (-6.30䧮) 1.32 1/20/22 Probe size: 20S Mr. Jordan Williamson CEO GAS Inc. 303 W. 3rd Street Elk City, OK 73644 Dear Mr. Williamson: We are writing in response to your letter received on September 17, 2020, in which you request the approval of alternative testing procedures. The EPA’s Office of Air Quality Planning and Standards (OAQPS) is the delegated authority for consideration of major alternatives to test methods and procedures as set forth in 40 CFR parts 60 and 63 under which your request must be addressed. GAS Inc. is requesting a change to one of the test methods, ASTM D6348-03, used for conducting performance tests to determine compliance under 40 CFR part 60, Subpart JJJJ – Standards of Performance for Stationary Spark Ignition Internal Combustion Engines (Subpart JJJJ) and 40 CFR part 63, Subpart ZZZZ – National Emissions Standards for Hazardous Air Pollutants for Performance for Stationary Reciprocating Internal Combustion Engines (Subpart ZZZZ). The change being requested will be used to check detector linearity of the Fourier Transform Infrared (FTIR) instrumentation used to conduct this method. Specifically, you are requesting that the procedures of section 8.3.3 of Method 320 (40 CFR part 60, Appendix A), another FTIR-based method allowed under Subparts JJJJ and ZZZZ, be used in lieu of section A6.4.1 of ASTM D6348-03 when conducting testing using ASTM D6348-03 under 40 CFR part 60, Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. In your request, you state that this alternative linearity check procedure will produce consistent results when utilizing either Method 320 or ASTM D6348-03. Additionally, some FTIR instrumentation does not allow for reducing the size of the aperture in the instrument and, thus, it would not be feasible to properly conduct the entirety of the ASTM D6348-03 method in its current form using such an instrument. Based on our understanding of FTIR instrument principles and recognition that the requested alternative determination of detector linearity is both technically sound and contained within Method 320, we are approving the requested change. We believe that this alternative is acceptable for use for use in testing all engines subject to 40 CFR part 60 Subpart JJJJ and 40 CFR part 63, Subpart ZZZZ. Also, we will post this letter as ALT-141 on EPA’s website (at www.epa.gov/emc/broadly-applicable-approved-alternative- testmethods) to announce that our approval of this alternative test method is broadly applicable to engines for the purposes of meeting Subparts JJJJ and ZZZZ. March 15, 2021 Sincerely, Steffan M. Johnson, Group Leader Measurement Technology Group If you should have any questions or require further information regarding this approval, please contact David Nash of my staff at 919-541-9425 or email at nash.dave@epa.gov. cc: Sara Ayers, EPA/OECA/OC/MAMPD, (ayres.sara@epa.gov) Melanie King, EPA/OAR/OAQPS/SPPD, (king.melanie@epa.gov) James Leather, EPA Region 6, (leather.james@epa.gov) David Nash, EPA/OAR/OAQPS/AQAD, (nash.dave@epa.gov) Heather Sessing, Oklahoma DEQ, (Heather.sessing@deq.ok.gov) Aaron King GAS, Inc. Type of Sources Tested: info@gasinc.us Stationary Internal Combustion Engines • 4 Stroke Rich Burn Engines • 2 Stroke & 4 Stroke Lean Burn Engines Stationary Natural Gas Fired Generators Stationary Propane Fired Generators Gas Fired Boilers Qualifications: Trained, studied, and fully demonstrates compliance for emissions testing via data collection outlined in the following Reference Methods: • EPA Method 1 & 1A – Sampling & Traverse Points • EPA Method 2 & 2C – Velocity & Volumetric Flow Rate of a Gas Stream • EPA Method 3A – Oxygen • EPA Method 7E – NOX • EPA Method 10 – Carbon Monoxide • EPA Method 25A – Volatile Organic Compounds • ASTM D6348 – Extractive Fourier Transform Infrared Spectroscopy Conducts emissions testing on a weekly basis including, but not limited to, the following test types: Initial Compliance, Biennial Compliance, Semiannual Compliance & Quarterly Compliance. All tests performed are in accordance to any and all Federal & State requirements as applicable (i.e. JJJJ, ZZZZ, 106.512, 117, PEA, etc.). Performed testing in Colorado, Utah, Wyoming, North Dakota, Montana, Kansas, New Mexico, Oklahoma, Texas, Louisiana (land and off-shore), Arkansas, Ohio, Pennsylvania, West Virginia, New York, Kentucky, & Mississippi. • Quarterly Performance Reviews covering ongoing changes with Federal Regulations, State Compliance guidelines, & site-specific safety certifications. Types of Analyzers: • Gasmet DX4000 FTIR • Gasmet Portable Sampling Unit with Zirconium Oxide O2 Sensory • Testo 350 • Flame Ionization Detector 580-225-0403 Gas, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 1 Minute Average Data Sheet Ovintiv USA Inc.Client: Ranch Compressor Station Unit Number:Unit 4 Make:Caterpillar Location:G3606Model: 3XF00116Serial Number: RAW Result Data Stability 11/2/2023 06:43 6.4528.7922.125 0.369 5.04452.115 0.000 0.000 0.9070.2620.000 6.457 17.8810.147 2.360 843.028.262.028 0.727 15.24 15.05 180.0 Pre Test Baseline Direct 11/2/2023 06:55 0.0000.000-0.033 0.000 0.0000.000 0.000 0.353 0.0000.0080.033 0.000 0.0000.089 0.000 843.00.060.089 0.000 0.00 0.26 180.0 11/2/2023 06:56 0.0000.000-0.037 0.000 0.0000.000 0.000 0.310 0.0000.0000.264 0.000 0.0000.000 0.000 843.00.090.135 0.000 0.00 0.17 180.0 11/2/2023 06:56 0.0000.000-0.037 0.000 0.0000.000 0.000 0.358 0.0000.1290.102 0.000 0.0000.000 0.000 843.00.060.086 0.000 0.00 0.16 180.0 CTS Direct 11/2/2023 06:59 0.0000.000-0.024 0.000 0.0000.000 0.000 0.050 0.0000.0000.000 97.339 0.0000.000 0.000 843.064.930.056 0.000 0.00 0.24 180.0 11/2/2023 07:00 0.0000.000-0.025 0.000 0.0000.000 0.000 0.084 0.0000.0000.000 97.501 0.0000.000 0.000 843.065.030.040 0.000 0.00 0.24 180.0 11/2/2023 07:00 0.0000.000-0.022 0.000 0.0000.000 0.000 0.021 0.0790.0000.000 97.408 0.0000.000 0.000 843.064.950.009 0.000 0.00 0.24 180.0 21% O2 Direct 11/2/2023 07:10 0.0000.000-0.040 0.000 0.0000.000 0.000 0.460 0.0060.0000.638 0.000 0.0000.000 0.000 843.00.130.199 0.000 0.00 20.82 180.0 11/2/2023 07:10 0.0000.000-0.040 0.000 0.0730.000 0.000 0.358 0.1240.0000.904 0.000 0.0000.000 0.000 843.00.040.059 0.000 0.00 20.85 180.0 11/2/2023 07:11 0.0000.000-0.037 0.000 0.0000.000 0.000 0.329 0.0000.0000.217 0.000 0.0000.000 0.000 843.00.060.094 0.000 0.00 20.80 180.0 NO2 9%O2 Direct 11/2/2023 07:18 95.7550.000-0.036 0.000 0.4200.000 0.148 0.000 0.9610.0401.553 0.000 0.0000.000 0.000 843.00.000.000 0.000 95.75 8.88 180.0 11/2/2023 07:18 95.2910.000-0.037 0.000 0.7470.000 0.139 0.000 1.9010.0001.573 0.000 0.0000.000 0.000 843.00.000.000 0.000 95.29 8.87 180.0 11/2/2023 07:18 95.7560.000-0.036 0.000 0.3560.000 0.138 0.000 1.6980.0001.456 0.000 0.0000.000 0.000 843.00.000.000 0.000 95.76 8.89 180.0 Spike Direct 11/2/2023 07:30 0.000244.165-0.043 4.674 0.000489.740 1.794 1.926 5.0500.5090.000 1.208 252.7980.000 0.000 843.0255.452.774 9.672 244.17 0.02 180.0 11/2/2023 07:31 0.000244.689-0.034 4.671 0.000489.326 1.780 1.780 5.6880.1210.000 1.211 252.6150.000 0.000 843.0255.312.834 9.670 244.69 0.02 180.0 11/2/2023 07:31 0.000244.330-0.037 4.667 0.186489.175 1.790 1.845 5.8020.1570.000 1.236 252.4550.000 0.000 843.0255.282.995 9.667 244.33 0.02 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline System 11/2/2023 07:34 0.0000.000-0.000 0.000 0.0000.000 0.000 1.008 0.0000.0000.115 0.000 0.2310.000 0.000 843.00.290.089 0.000 0.00 0.17 180.0 11/2/2023 07:35 0.0000.000-0.001 0.000 0.0000.000 0.000 0.923 0.2250.0000.114 0.000 0.1510.000 0.000 843.00.180.042 0.000 0.00 0.17 180.0 11/2/2023 07:35 0.0000.000-0.001 0.000 0.0000.000 0.000 0.983 0.0130.0000.000 0.000 0.1260.000 0.000 843.00.130.005 0.000 0.00 0.17 180.0 CTS System with Response Time 11/2/2023 07:37 0.0000.000-0.000 0.000 0.0000.000 0.000 0.383 0.0000.0000.000 96.262 0.1050.000 0.006 843.064.290.000 0.000 0.00 0.24 180.0 11/2/2023 07:38 0.0000.000-0.000 0.000 0.0000.000 0.000 0.389 0.0000.0000.000 96.884 0.0000.000 0.000 843.064.590.000 0.000 0.00 0.23 180.0 11/2/2023 07:38 0.0000.000-0.000 0.000 0.0000.000 0.000 0.406 0.0000.0030.000 97.221 0.0270.000 0.022 843.064.890.000 0.000 0.00 0.23 180.0 NO2 System & 9% with Response Time 11/2/2023 07:59 96.8920.000-0.001 0.000 0.0000.000 0.168 0.269 0.5250.0000.000 0.000 0.0000.369 0.035 843.00.070.000 0.000 96.89 8.56 180.0 11/2/2023 07:59 97.0350.000-0.001 0.000 0.0510.000 0.175 0.176 0.6360.0000.000 0.000 0.0000.547 0.020 843.00.040.000 0.000 97.03 8.57 180.0 11/2/2023 07:59 98.1120.000-0.001 0.000 0.0750.000 0.171 0.198 0.3330.0000.000 0.000 0.0000.577 0.058 843.00.200.129 0.000 98.11 8.57 180.0 Spike System with Response Time 11/2/2023 08:02 0.000244.408-0.001 4.643 0.000491.491 1.763 1.800 5.2500.0370.000 1.262 252.9910.117 0.000 843.0255.782.918 9.661 244.41 0.02 180.0 11/2/2023 08:02 0.000244.404-0.001 4.662 0.000492.163 1.747 1.720 5.1910.0060.000 1.244 253.3600.121 0.000 843.0256.273.128 9.670 244.40 0.02 180.0 11/2/2023 08:03 0.000244.852-0.001 4.641 0.059492.372 1.764 1.812 5.2570.1330.000 1.200 253.2360.087 0.000 843.0255.962.880 9.676 244.85 0.02 180.0 Baseline System with Response Time 11/2/2023 08:06 0.0000.000-0.001 0.000 0.0000.000 0.000 0.346 0.3490.0000.000 0.000 0.2120.000 0.000 843.00.300.131 0.000 0.00 0.19 180.0 11/2/2023 08:06 0.0000.000-0.001 0.000 0.0000.000 0.000 0.262 0.2780.0000.000 0.000 0.1920.000 0.000 843.00.290.153 0.000 0.00 0.19 180.0 11/2/2023 08:07 0.0000.000-0.001 0.000 0.0000.000 0.000 0.330 0.1920.0000.000 0.000 0.1160.000 0.000 843.00.230.177 0.000 0.00 0.18 180.0 Run 1 - A 30minute/60min 11/2/2023 15:37 4.36948.5828.666 4.546 1109.8935.933 0.000 0.000 112.3230.00015.111 0.104 49.2750.000 4.735 829.061.043.345 0.000 52.95 9.39 180.0 11/2/2023 15:38 5.20049.6938.670 4.540 1115.6495.857 0.000 0.000 112.9670.00014.903 0.137 49.4150.000 4.649 829.061.023.328 0.000 54.89 9.39 180.0 11/2/2023 15:39 5.78850.2588.655 4.536 1115.2625.868 0.000 0.000 112.8570.00014.964 0.066 49.4240.000 4.701 829.061.053.263 0.000 56.05 9.39 180.0 11/2/2023 15:40 5.70250.8318.692 4.554 1113.6925.817 0.000 0.039 111.7840.00014.873 0.170 49.0500.000 4.759 829.060.893.311 0.000 56.53 9.40 180.0 11/2/2023 15:41 5.91451.9048.693 4.554 1107.0645.904 0.000 0.033 110.2040.00014.721 0.000 48.6930.000 4.665 829.060.243.321 0.000 57.82 9.39 180.0 11/2/2023 15:42 5.43251.1138.701 4.560 1111.8555.903 0.000 0.000 110.6890.00014.566 0.000 48.5600.000 4.675 829.060.073.236 0.000 56.54 9.40 180.0 11/2/2023 15:43 5.39448.8858.700 4.553 1124.0266.029 0.000 0.000 112.8440.00014.664 0.000 48.9430.000 4.634 829.060.363.227 0.000 54.28 9.39 180.0 11/2/2023 15:44 4.91047.5378.664 4.527 1125.0436.058 0.000 0.018 113.1010.00014.589 0.021 49.2370.000 4.649 829.060.713.237 0.000 52.45 9.41 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 11/2/2023 15:45 4.44348.9558.685 4.536 1109.1785.801 0.000 0.000 110.5250.00014.660 0.000 48.6270.000 4.661 829.060.193.363 0.000 53.40 9.39 180.0 11/2/2023 15:46 3.81446.4878.650 4.522 1113.9635.770 0.000 0.000 111.4680.00014.666 0.070 48.8710.000 4.699 829.060.513.286 0.000 50.30 9.40 180.0 11/2/2023 15:47 4.90949.1288.695 4.549 1112.3145.850 0.000 0.011 110.7420.00014.494 0.000 48.5260.000 4.653 829.060.043.309 0.000 54.04 9.37 180.0 11/2/2023 15:48 5.34348.8048.684 4.542 1113.6795.806 0.000 0.038 111.2820.00014.585 0.000 48.3260.000 4.655 829.059.823.273 0.000 54.15 9.39 180.0 11/2/2023 15:49 5.11749.4548.690 4.552 1107.8305.941 0.000 0.048 110.1570.00014.457 0.000 48.0390.000 4.653 829.059.583.358 0.000 54.57 9.39 180.0 11/2/2023 15:50 5.35149.8158.701 4.553 1115.4566.032 0.000 0.033 111.1340.00014.482 0.007 47.9650.000 4.571 829.059.253.208 0.000 55.17 9.38 180.0 11/2/2023 15:51 5.17348.7838.677 4.535 1104.9365.826 0.000 0.063 109.9020.00014.643 0.000 47.7130.000 4.623 829.059.183.326 0.000 53.96 9.39 180.0 11/2/2023 15:52 5.44747.8848.680 4.519 1123.0005.771 0.000 0.046 113.0360.00014.196 0.000 47.9680.000 4.500 829.059.103.204 0.000 53.33 9.38 180.0 11/2/2023 15:53 5.06247.9678.682 4.529 1126.8855.646 0.000 0.018 113.4830.00014.551 0.000 48.1710.000 4.559 829.059.563.405 0.000 53.03 9.40 180.0 11/2/2023 15:54 4.95946.6498.676 4.526 1125.0265.878 0.000 0.000 113.1710.00014.322 0.000 47.5030.000 4.455 829.058.653.353 0.000 51.61 9.35 180.0 11/2/2023 15:55 5.31748.6558.709 4.545 1120.8495.881 0.000 0.000 112.2440.00014.530 0.000 46.9370.000 4.452 829.058.023.260 0.000 53.97 9.38 180.0 11/2/2023 15:56 6.15348.8848.702 4.534 1136.9225.894 0.000 0.023 114.9740.00016.500 0.000 47.5220.000 4.401 829.058.463.203 0.000 55.04 9.38 180.0 11/2/2023 15:57 6.17548.4558.706 4.531 1126.8255.969 0.000 0.023 113.8650.00016.416 0.000 47.1040.000 4.401 829.058.093.281 0.000 54.63 9.38 180.0 11/2/2023 15:58 5.12848.1528.694 4.535 1118.3495.774 0.000 0.022 112.2190.00014.199 0.000 46.9190.000 4.467 829.058.073.322 0.000 53.28 9.39 180.0 11/2/2023 15:59 4.48446.6998.680 4.523 1117.1165.814 0.000 0.000 112.4390.00014.259 0.000 47.0980.000 4.457 829.058.213.297 0.000 51.18 9.37 180.0 11/2/2023 16:00 5.00748.7588.696 4.529 1117.2565.724 0.000 0.038 111.8110.00014.319 0.000 47.0950.000 4.546 829.058.363.255 0.000 53.76 9.38 180.0 11/2/2023 16:01 5.55948.1598.691 4.522 1126.6175.739 0.000 0.000 113.6660.00014.490 0.000 47.6070.000 4.475 829.058.823.402 0.000 53.72 9.37 180.0 11/2/2023 16:02 5.52248.5838.691 4.529 1120.1375.903 0.000 0.032 112.3910.00014.669 0.000 47.1960.000 4.493 829.058.373.274 0.000 54.11 9.39 180.0 11/2/2023 16:03 4.84947.3788.673 4.533 1120.5285.879 0.000 0.000 112.5390.00014.439 0.000 47.3810.000 4.487 829.058.593.347 0.000 52.23 9.37 180.0 11/2/2023 16:04 7.08050.6808.702 4.547 1115.8705.824 0.000 0.010 111.6340.00014.510 0.016 47.0850.000 4.423 829.058.143.295 0.000 57.76 9.37 180.0 11/2/2023 16:05 6.56250.2908.712 4.541 1121.5655.934 0.000 0.000 112.3880.00014.545 0.000 47.2400.000 4.454 829.058.343.286 0.000 56.85 9.37 180.0 11/2/2023 16:06 6.40551.4068.711 4.543 1114.8645.801 0.000 0.000 111.6340.00014.861 0.000 47.1140.000 4.507 829.058.343.316 0.000 57.81 9.38 180.0 5.35248.9618.688 4.538 1117.7225.861 0.000 0.017 112.1160.00014.706 0.020 48.0200.000 4.569 829.0059.3693.296 0.000 54.314 9.384 180.0Avg. Spike 1 11/2/2023 16:12 0.67563.0177.967 4.525 1004.77248.704 0.036 0.000 89.8550.00013.961 4.938 63.3950.000 5.693 829.080.643.845 0.764 63.69 8.66 180.0 Run 1 - B 30minute/60min 11/2/2023 16:16 10.45949.1858.680 4.527 1099.7686.064 0.000 0.000 105.4790.00014.620 1.538 45.9180.000 5.258 829.059.733.406 0.000 59.64 9.39 180.0 11/2/2023 16:17 4.74148.5698.676 4.529 1103.9715.992 0.000 0.000 106.3990.00014.700 1.278 46.4410.000 5.250 829.059.983.284 0.000 53.31 9.37 180.0 11/2/2023 16:18 4.43148.1028.683 4.536 1106.1386.122 0.000 0.000 111.9280.00014.746 1.007 48.1140.000 4.539 829.060.053.275 0.000 52.53 9.39 180.0 11/2/2023 16:19 5.44448.7858.647 4.531 1111.9346.194 0.000 0.008 111.5560.00014.377 0.753 48.0600.000 4.537 829.059.853.320 0.000 54.23 9.37 180.0 11/2/2023 16:20 5.97749.6148.659 4.536 1108.5836.067 0.000 0.000 110.3150.00014.476 0.735 47.9210.000 4.533 829.059.683.306 0.000 55.59 9.39 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 11/2/2023 16:21 4.78247.6778.666 4.535 1107.8126.017 0.000 0.000 110.9050.00014.662 0.418 48.0580.000 4.537 829.059.593.273 0.000 52.46 9.38 180.0 11/2/2023 16:22 5.32448.3398.670 4.531 1110.0546.080 0.000 0.027 111.2590.00014.465 0.465 48.0280.000 4.580 829.059.773.404 0.000 53.66 9.37 180.0 11/2/2023 16:23 5.30749.4878.690 4.536 1113.0296.152 0.000 0.000 111.5970.00014.926 0.447 47.9140.000 4.595 829.059.653.374 0.000 54.79 9.39 180.0 11/2/2023 16:24 5.00150.2198.705 4.541 1104.5755.899 0.000 0.000 110.1360.00014.910 0.581 47.7690.000 4.632 829.059.673.374 0.000 55.22 9.39 180.0 11/2/2023 16:25 5.06151.2118.705 4.545 1106.9125.990 0.000 0.035 110.4290.00014.857 0.558 47.8760.000 4.606 829.059.753.430 0.000 56.27 9.36 180.0 11/2/2023 16:26 5.11149.0858.687 4.542 1111.6196.059 0.000 0.016 111.5620.00014.905 0.544 48.0950.000 4.624 829.059.943.356 0.000 54.20 9.37 180.0 11/2/2023 16:27 5.49749.7828.687 4.553 1116.8966.236 0.000 0.010 112.3390.00014.463 0.658 48.0390.000 4.549 829.059.733.231 0.000 55.28 9.38 180.0 11/2/2023 16:28 4.50548.4778.664 4.546 1106.7796.110 0.000 0.000 111.1330.00015.165 0.688 47.8770.000 4.577 829.059.643.226 0.000 52.98 9.38 180.0 11/2/2023 16:29 4.66749.0578.654 4.537 1104.6026.071 0.000 0.000 111.2270.00014.450 0.623 47.6870.000 4.535 829.059.283.168 0.000 53.72 9.39 180.0 11/2/2023 16:30 4.53848.9348.669 4.533 1111.2866.177 0.000 0.000 111.9210.00014.258 0.641 48.1150.000 4.585 829.059.993.410 0.000 53.47 9.38 180.0 11/2/2023 16:31 5.72348.4458.662 4.530 1110.0405.948 0.000 0.000 112.4350.00014.678 0.700 48.2860.000 4.543 829.060.043.302 0.000 54.17 9.36 180.0 11/2/2023 16:32 5.25249.3568.647 4.521 1109.3716.049 0.000 0.000 112.1390.00014.695 0.804 48.0720.000 4.594 829.059.993.294 0.000 54.61 9.38 180.0 11/2/2023 16:33 4.34547.1328.631 4.520 1115.3106.118 0.000 0.000 112.6320.00014.396 0.597 48.3420.000 4.586 829.060.113.292 0.000 51.48 9.37 180.0 11/2/2023 16:34 5.15848.8298.674 4.549 1111.1336.154 0.000 0.022 112.0730.00014.351 0.518 47.9820.000 4.560 829.059.583.192 0.000 53.99 9.38 180.0 11/2/2023 16:35 5.47148.1878.680 4.551 1119.9726.196 0.000 0.000 112.9370.00014.338 0.518 48.1030.000 4.557 829.059.723.228 0.000 53.66 9.41 180.0 11/2/2023 16:36 5.69049.4958.693 4.548 1115.5816.054 0.000 0.000 112.1930.00014.515 0.672 47.9450.000 4.528 829.059.603.233 0.000 55.19 9.36 180.0 11/2/2023 16:37 5.59949.5628.677 4.541 1114.4106.160 0.000 0.000 112.2080.00014.359 0.497 47.9420.000 4.570 829.059.603.276 0.000 55.16 9.37 180.0 11/2/2023 16:38 4.42448.4118.678 4.539 1104.0845.977 0.000 0.000 110.8110.00014.703 0.484 47.9930.000 4.601 829.059.713.287 0.000 52.84 9.38 180.0 11/2/2023 16:39 5.17349.0538.677 4.527 1104.5326.018 0.000 0.000 110.6280.00014.542 0.599 48.0290.000 4.590 829.059.853.361 0.000 54.23 9.41 180.0 11/2/2023 16:40 4.86149.6368.697 4.543 1114.7926.054 0.000 0.000 111.9060.00014.858 0.573 48.1360.000 4.620 829.059.973.314 0.000 54.50 9.40 180.0 11/2/2023 16:41 4.75148.0628.683 4.540 1117.5726.150 0.000 0.000 112.4950.00014.629 0.500 48.2480.000 4.560 829.059.883.274 0.000 52.81 9.41 180.0 11/2/2023 16:42 5.10947.9708.676 4.548 1108.1056.071 0.000 0.000 111.2160.00014.607 0.487 47.9240.000 4.624 829.059.653.228 0.000 53.08 9.40 180.0 11/2/2023 16:43 5.33949.5968.685 4.549 1100.5726.156 0.000 0.000 109.8000.00014.635 0.508 47.6260.000 4.616 829.059.413.317 0.000 54.93 9.39 180.0 11/2/2023 16:45 5.13048.5948.654 4.526 1105.2866.058 0.000 0.046 110.8640.00014.343 0.414 48.0920.000 4.580 829.059.793.387 0.000 53.72 9.38 180.0 11/2/2023 16:46 5.44149.9918.677 4.539 1102.4686.056 0.000 0.000 110.6050.00014.715 0.451 47.7330.000 4.647 829.059.563.346 0.000 55.43 9.40 180.0 5.27748.9618.674 4.538 1109.2406.082 0.000 0.005 111.1040.00014.611 0.642 47.8790.000 4.624 829.0059.7593.306 0.000 54.238 9.383 180.0Avg. 5.31548.9618.681 4.538 1113.4815.971 0.000 0.011 111.6100.00014.659 0.331 47.9490.000 4.596 829.0059.5643.301 0.000 54.276 9.384 180.0Run 1 Avg: Baseline 1 11/2/2023 16:50 0.0000.000-0.000 0.000 0.7100.000 0.000 0.212 0.1140.0000.000 0.000 0.1130.000 0.000 829.00.440.490 0.000 0.00 0.16 180.0 Run 2 - A 30minute/60min 11/2/2023 16:53 4.69549.1308.652 4.514 1093.8136.008 0.000 0.071 108.1340.00014.514 0.022 47.7930.000 4.617 829.059.303.391 0.000 53.82 9.28 180.0 11/2/2023 16:54 5.09748.8228.664 4.515 1104.3725.948 0.000 0.081 109.9770.00014.393 0.008 48.1220.000 4.618 829.059.623.379 0.000 53.92 9.35 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 11/2/2023 16:55 4.25347.7138.651 4.514 1106.1635.963 0.000 0.000 110.1610.00014.606 0.132 48.2360.000 4.596 829.059.753.350 0.000 51.97 9.37 180.0 11/2/2023 16:56 4.12048.2158.645 4.505 1095.5155.699 0.000 0.082 108.0820.00014.288 0.000 47.8660.000 4.648 829.059.463.453 0.000 52.34 9.43 180.0 11/2/2023 16:57 4.93947.3128.649 4.525 1108.1276.021 0.000 0.004 110.3880.00014.293 0.019 48.3240.000 4.552 829.059.603.233 0.000 52.25 9.40 180.0 11/2/2023 16:58 4.56948.8738.669 4.541 1101.4435.934 0.000 0.000 108.6760.00014.308 0.000 47.8360.000 4.635 829.059.313.310 0.000 53.44 9.38 180.0 11/2/2023 16:59 5.96850.5388.702 4.543 1104.3265.909 0.000 0.000 109.2270.00014.256 0.000 47.6930.000 4.575 829.059.043.301 0.000 56.51 9.41 180.0 11/2/2023 17:00 4.39548.9008.695 4.541 1104.9865.979 0.000 0.012 109.4480.00014.411 0.000 48.0300.000 4.648 829.059.573.373 0.000 53.30 9.42 180.0 11/2/2023 17:01 4.07148.4968.685 4.533 1098.8975.899 0.000 0.000 109.0510.00014.108 0.000 48.1340.000 4.663 829.059.733.411 0.000 52.57 9.41 180.0 11/2/2023 17:02 3.85248.7318.672 4.519 1103.1625.852 0.000 0.004 109.7640.00014.365 0.000 48.1490.000 4.602 829.059.633.411 0.000 52.58 9.40 180.0 11/2/2023 17:03 3.62148.9188.677 4.516 1095.9125.767 0.000 0.047 108.1160.00014.221 0.000 47.9790.000 4.677 829.059.623.437 0.000 52.54 9.41 180.0 11/2/2023 17:04 4.73547.8948.657 4.522 1097.8455.816 0.000 0.000 108.3260.00014.083 0.076 47.8930.000 4.660 829.059.583.475 0.000 52.63 9.40 180.0 11/2/2023 17:05 4.67048.7158.672 4.528 1104.4345.906 0.000 0.019 109.4490.00014.409 0.000 47.9970.000 4.615 829.059.423.284 0.000 53.38 9.41 180.0 11/2/2023 17:06 4.41648.7168.689 4.533 1104.2555.827 0.000 0.000 109.3960.00014.129 0.000 47.8990.000 4.630 829.059.403.358 0.000 53.13 9.41 180.0 11/2/2023 17:07 4.43548.6468.700 4.537 1113.1165.790 0.000 0.000 111.0610.00014.278 0.000 48.3100.000 4.574 829.059.743.423 0.000 53.08 9.42 180.0 11/2/2023 17:08 4.98248.7958.688 4.527 1108.5195.764 0.000 0.000 110.7870.00014.417 0.000 48.3300.000 4.577 829.059.753.394 0.000 53.78 9.40 180.0 11/2/2023 17:09 4.25547.7808.700 4.538 1101.5705.733 0.000 0.017 110.0420.00014.259 0.000 48.2750.000 4.704 829.060.003.482 0.000 52.04 9.38 180.0 11/2/2023 17:10 3.61048.5608.683 4.517 1097.2375.639 0.000 0.032 109.5280.00014.100 0.000 48.1840.000 4.682 829.059.863.474 0.000 52.17 9.40 180.0 11/2/2023 17:11 5.09248.6468.677 4.528 1115.2405.754 0.000 0.000 112.8660.00014.260 0.000 48.8540.000 4.634 829.060.333.315 0.000 53.74 9.42 180.0 11/2/2023 17:12 4.19648.2888.681 4.528 1098.8745.689 0.000 0.000 110.3550.00014.110 0.000 48.2410.000 4.657 829.059.833.418 0.000 52.48 9.40 180.0 11/2/2023 17:13 4.04449.4018.677 4.534 1088.1165.744 0.000 0.000 108.6300.00014.060 0.007 47.5450.000 4.719 829.059.303.472 0.000 53.45 9.40 180.0 11/2/2023 17:14 4.50948.7918.670 4.529 1091.7695.715 0.000 0.000 108.4470.00014.149 0.000 48.0420.000 4.714 829.059.783.471 0.000 53.30 9.37 180.0 11/2/2023 17:15 5.41850.3908.684 4.531 1099.9565.616 0.000 0.000 109.8460.00014.043 0.000 48.1100.000 4.662 829.059.743.461 0.000 55.81 9.38 180.0 11/2/2023 17:16 3.60048.4428.674 4.510 1105.4105.692 0.000 0.000 111.3000.00014.212 0.000 48.5520.000 4.699 829.060.233.412 0.000 52.04 9.39 180.0 11/2/2023 17:17 4.07449.3268.694 4.529 1100.9075.722 0.000 0.051 110.2660.00014.391 0.000 48.1130.000 4.703 829.059.913.581 0.000 53.40 9.42 180.0 11/2/2023 17:19 4.85650.7158.713 4.542 1098.5185.610 0.000 0.039 109.7510.00014.278 0.001 48.1250.000 4.672 829.059.743.407 0.000 55.57 9.39 180.0 11/2/2023 17:20 4.91950.4228.694 4.535 1100.6415.676 0.000 0.003 110.2740.00014.406 0.027 48.1910.000 4.668 829.059.883.497 0.000 55.34 9.38 180.0 11/2/2023 17:21 4.13848.8618.669 4.524 1096.3535.525 0.000 0.000 110.1680.00014.002 0.000 48.1490.000 4.676 829.059.833.488 0.000 53.00 9.37 180.0 11/2/2023 17:22 3.73247.8188.642 4.513 1096.1165.701 0.000 0.000 110.5330.00013.933 0.000 48.2700.000 4.722 829.060.013.448 0.000 51.55 9.38 180.0 11/2/2023 17:23 4.47550.3528.690 4.537 1088.2775.606 0.000 0.006 108.7510.00014.308 0.027 47.9870.000 4.718 829.059.733.438 0.000 54.83 9.40 180.0 4.45848.8748.677 4.527 1100.7965.783 0.000 0.016 109.6930.00014.253 0.011 48.1080.000 4.651 829.0059.6903.412 0.000 53.332 9.393 180.0Avg. Spike 2 11/2/2023 17:27 1.44364.3497.988 4.548 985.98848.416 0.000 0.000 88.5100.00013.922 2.957 64.2740.000 6.238 829.081.524.191 0.768 65.79 8.70 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Run 2 - B 30minute/60min 11/2/2023 17:30 4.56649.0618.658 4.518 1095.4465.887 0.000 0.053 110.0120.00014.218 0.013 48.6540.000 4.703 829.060.303.346 0.000 53.63 9.39 180.0 11/2/2023 17:31 4.12248.4938.657 4.518 1095.0815.689 0.000 0.087 109.8650.00014.330 0.033 48.6790.000 4.757 829.060.563.520 0.000 52.62 9.40 180.0 11/2/2023 17:32 4.19748.1668.664 4.511 1102.8145.678 0.000 0.000 111.0960.00014.133 0.000 49.1040.000 4.750 829.060.933.495 0.000 52.36 9.37 180.0 11/2/2023 17:33 3.77048.1128.682 4.523 1104.8685.617 0.000 0.001 110.5660.00014.264 0.000 49.2170.000 4.750 829.061.043.487 0.000 51.88 9.41 180.0 11/2/2023 17:34 3.67947.4368.670 4.517 1107.5315.522 0.000 0.015 111.0520.00016.378 0.022 49.2800.000 4.694 829.060.983.437 0.000 51.12 9.39 180.0 11/2/2023 17:35 3.78948.6158.677 4.520 1105.0445.583 0.000 0.000 110.1040.00014.226 0.000 48.9140.000 4.723 829.060.723.544 0.000 52.40 9.40 180.0 11/2/2023 17:36 3.97449.1798.701 4.536 1102.4715.637 0.000 0.015 110.2790.00014.334 0.029 48.7100.000 4.696 829.060.353.348 0.000 53.15 9.45 180.0 11/2/2023 17:37 4.03548.5018.690 4.537 1105.1775.675 0.000 0.000 111.0920.00014.246 0.000 49.1300.000 4.658 829.060.733.421 0.000 52.54 9.39 180.0 11/2/2023 17:38 3.80648.2528.672 4.531 1099.5225.631 0.000 0.000 110.4500.00014.089 0.000 48.7470.000 4.729 829.060.523.479 0.000 52.06 9.38 180.0 11/2/2023 17:39 4.40849.1108.672 4.518 1091.8975.576 0.000 0.040 109.2400.00013.887 0.014 48.5080.000 4.735 829.060.253.390 0.000 53.52 9.38 180.0 11/2/2023 17:40 3.23947.3658.654 4.506 1095.5175.525 0.000 0.000 110.0750.00013.858 0.000 48.9470.000 4.762 829.060.743.398 0.000 50.60 9.37 180.0 11/2/2023 17:41 5.17349.2078.669 4.508 1106.2495.535 0.000 0.000 111.0800.00014.340 0.000 49.1090.000 4.716 829.060.863.473 0.000 54.38 9.39 180.0 11/2/2023 17:42 4.56747.6858.657 4.508 1114.2225.588 0.000 0.000 112.1720.00013.728 0.000 49.4140.000 4.702 829.061.133.476 0.000 52.25 9.38 180.0 11/2/2023 17:43 4.38347.4788.669 4.521 1107.9665.692 0.000 0.000 110.6330.00014.113 0.021 48.9360.000 4.697 829.060.673.493 0.000 51.86 9.39 180.0 11/2/2023 17:44 4.99948.0778.678 4.524 1106.5345.715 0.000 0.003 110.3540.00013.933 0.006 48.6570.000 4.661 829.060.243.388 0.000 53.08 9.40 180.0 11/2/2023 17:45 4.24048.4868.670 4.521 1109.3255.512 0.000 0.000 110.5180.00013.941 0.028 48.6420.000 4.661 829.060.263.409 0.000 52.73 9.39 180.0 11/2/2023 17:46 5.62747.5338.640 4.506 1116.2355.618 0.000 0.000 112.2070.00013.899 0.057 49.2590.000 4.602 829.060.763.391 0.000 53.16 9.37 180.0 11/2/2023 17:47 4.66849.0368.671 4.512 1102.3125.563 0.000 0.000 109.7340.00013.800 0.000 48.5450.000 4.723 829.060.283.428 0.000 53.70 9.37 180.0 11/2/2023 17:48 4.39748.4118.685 4.512 1101.7455.501 0.000 0.000 109.7950.00014.062 0.021 48.4620.000 4.660 829.060.153.533 0.000 52.81 9.40 180.0 11/2/2023 17:49 3.67148.2198.674 4.504 1101.7345.495 0.000 0.000 110.0440.00014.199 0.000 48.4240.000 4.700 829.060.093.406 0.000 51.89 9.38 180.0 11/2/2023 17:50 3.74947.8708.663 4.523 1108.8035.686 0.000 0.000 110.9810.00014.111 0.000 48.7630.000 4.647 829.060.353.447 0.000 51.62 9.40 180.0 11/2/2023 17:51 3.82949.0758.676 4.524 1102.8165.708 0.000 0.000 109.9760.00014.224 0.000 48.4270.000 4.645 829.060.003.426 0.000 52.90 9.41 180.0 11/2/2023 17:52 4.16048.7088.670 4.522 1098.2355.723 0.000 0.000 108.8670.00014.119 0.000 48.3190.000 4.642 829.059.883.415 0.000 52.87 9.40 180.0 11/2/2023 17:54 3.64649.5288.689 4.522 1089.5945.607 0.000 0.000 107.5090.00014.313 0.000 47.8510.000 4.704 829.059.523.385 0.000 53.17 9.40 180.0 11/2/2023 17:55 4.70649.9828.678 4.512 1098.8095.619 0.000 0.031 108.5960.00014.297 0.000 48.2230.000 4.678 829.059.813.344 0.000 54.69 9.42 180.0 11/2/2023 17:56 3.75548.5098.672 4.519 1101.0055.656 0.000 0.000 108.8470.00014.148 0.092 48.4590.000 4.723 829.060.273.462 0.000 52.26 9.39 180.0 11/2/2023 17:57 4.65749.1898.692 4.520 1102.0725.771 0.000 0.000 108.9530.00014.055 0.053 48.2870.000 4.664 829.059.903.381 0.000 53.85 9.40 180.0 11/2/2023 17:58 4.09449.1498.697 4.533 1099.7385.640 0.000 0.000 108.3210.00013.967 0.000 48.0940.000 4.677 829.059.793.515 0.000 53.24 9.41 180.0 11/2/2023 17:59 4.68948.7688.701 4.537 1109.0815.717 0.000 0.000 110.2490.00014.037 0.000 48.3080.000 4.623 829.059.803.366 0.000 53.46 9.38 180.0 11/2/2023 18:00 4.49648.9538.687 4.532 1106.6045.690 0.000 0.023 110.2000.00014.094 0.000 48.2430.000 4.610 829.059.683.326 0.000 53.45 9.41 180.0 4.23648.5388.675 4.520 1102.9485.635 0.000 0.009 110.0960.00014.178 0.013 48.6770.000 4.690 829.0060.3523.431 0.000 52.775 9.394 180.0Avg. 4.34748.7068.676 4.523 1101.8725.709 0.000 0.012 109.8940.00014.216 0.012 48.3920.000 4.670 829.0060.0213.421 0.000 53.054 9.393 180.0Run 2 Avg: GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) Baseline 2 11/2/2023 18:06 0.0000.000-0.001 0.000 0.1990.000 0.000 0.335 0.0000.0000.000 0.000 0.0280.000 0.000 829.00.420.589 0.000 0.00 0.17 180.0 Run 3 - A 30minute/60min 11/2/2023 18:10 4.07649.0038.695 4.508 1098.0365.529 0.000 0.147 107.9700.00013.792 0.000 47.6380.000 4.641 829.059.213.434 0.000 53.08 9.36 180.0 11/2/2023 18:11 3.26247.9698.683 4.511 1100.9745.532 0.000 0.101 108.6620.00014.009 0.000 47.9690.000 4.645 829.059.643.566 0.000 51.23 9.38 180.0 11/2/2023 18:12 4.35649.3428.689 4.512 1108.0625.549 0.000 0.007 109.9380.00014.241 0.000 47.9510.000 4.633 829.059.543.488 0.000 53.70 9.38 180.0 11/2/2023 18:13 4.39349.9348.701 4.528 1104.0395.488 0.000 0.049 108.8120.00014.286 0.000 47.5310.000 4.656 829.059.113.406 0.000 54.33 9.41 180.0 11/2/2023 18:14 4.00847.9968.693 4.518 1107.0555.660 0.000 0.000 109.4770.00013.812 0.000 47.5440.000 4.572 829.058.973.426 0.000 52.00 9.39 180.0 11/2/2023 18:15 4.67949.4878.711 4.528 1104.7035.640 0.000 0.041 108.7930.00015.823 0.000 47.3420.000 4.608 829.058.813.380 0.000 54.17 9.41 180.0 11/2/2023 18:16 5.98151.0318.712 4.535 1118.0915.572 0.000 0.000 110.8730.00013.915 0.000 47.8980.000 4.578 829.059.353.444 0.000 57.01 9.39 180.0 11/2/2023 18:17 5.07749.7938.714 4.518 1109.6635.503 0.000 0.061 109.4700.00016.094 0.000 47.5880.000 4.596 829.059.093.465 0.000 54.87 9.43 180.0 11/2/2023 18:18 4.23049.5028.711 4.522 1101.5345.598 0.000 0.000 108.5620.00014.165 0.000 47.2430.000 4.649 829.058.803.386 0.000 53.73 9.40 180.0 11/2/2023 18:19 3.03848.4938.708 4.526 1105.3635.592 0.000 0.000 109.3110.00014.174 0.000 47.6000.000 4.610 829.059.133.467 0.000 51.53 9.41 180.0 11/2/2023 18:20 4.26448.3048.681 4.509 1102.3665.633 0.000 0.000 108.8470.00013.751 0.000 47.5590.000 4.596 829.059.053.443 0.000 52.57 9.38 180.0 11/2/2023 18:21 5.57550.4728.694 4.528 1105.0355.719 0.000 0.017 108.3960.00013.778 0.000 47.4420.000 4.577 829.058.963.549 0.000 56.05 9.41 180.0 11/2/2023 18:22 5.09051.0378.698 4.537 1093.5135.601 0.000 0.000 106.5480.00013.583 0.000 46.8530.000 4.613 829.058.343.388 0.000 56.13 9.42 180.0 11/2/2023 18:23 4.18349.3688.664 4.504 1094.0045.630 0.000 0.043 106.9620.00013.611 0.000 46.8670.000 4.672 829.058.533.485 0.000 53.55 9.43 180.0 11/2/2023 18:24 4.23948.6588.673 4.501 1100.6365.412 0.000 0.027 108.3530.00015.759 0.000 47.3230.000 4.555 829.058.683.363 0.000 52.90 9.39 180.0 11/2/2023 18:25 4.87050.0318.723 4.540 1106.2675.568 0.000 0.000 109.2440.00014.149 0.005 47.0830.000 4.610 829.058.643.503 0.000 54.90 9.40 180.0 11/2/2023 18:26 4.33350.8108.724 4.521 1100.8125.449 0.000 0.000 107.8680.00013.806 0.000 47.1930.000 4.602 829.058.743.515 0.000 55.14 9.40 180.0 11/2/2023 18:27 4.82449.8088.712 4.517 1096.5795.568 0.000 0.062 107.5610.00014.039 0.000 46.9000.000 4.626 829.058.443.435 0.000 54.63 9.42 180.0 11/2/2023 18:29 3.50349.0478.689 4.524 1094.1495.603 0.000 0.000 107.1030.00013.796 0.000 46.9160.000 4.611 829.058.463.478 0.000 52.55 9.41 180.0 11/2/2023 18:30 5.33249.8158.732 4.539 1106.9955.685 0.000 0.013 109.0250.00016.019 0.017 47.0720.000 4.563 829.058.473.384 0.000 55.15 9.42 180.0 11/2/2023 18:31 4.08649.6038.715 4.534 1101.3045.513 0.000 0.012 108.1000.00015.761 0.000 46.8510.000 4.599 829.058.393.514 0.000 53.69 9.40 180.0 11/2/2023 18:32 4.62548.9978.688 4.517 1104.1665.647 0.000 0.074 108.9830.00013.936 0.000 47.0300.000 4.535 829.058.353.376 0.000 53.62 9.42 180.0 11/2/2023 18:33 4.39349.3498.687 4.522 1100.5195.625 0.000 0.007 107.8980.00016.050 0.000 47.0100.000 4.627 829.058.583.479 0.000 53.74 9.42 180.0 11/2/2023 18:34 4.27048.2448.702 4.520 1107.5965.498 0.000 0.016 109.4770.00013.804 0.000 47.5510.000 4.598 829.059.143.589 0.000 52.51 9.40 180.0 11/2/2023 18:35 4.84949.5968.715 4.527 1107.2235.606 0.000 0.000 109.3430.00014.071 0.000 47.4070.000 4.637 829.058.983.450 0.000 54.44 9.41 180.0 11/2/2023 18:36 4.57550.0028.714 4.530 1102.1865.519 0.000 0.000 108.5540.00014.089 0.000 46.9830.000 4.623 829.058.553.487 0.000 54.58 9.41 180.0 11/2/2023 18:37 4.85349.8928.707 4.530 1101.4405.542 0.000 0.000 108.4030.00014.163 0.000 47.0270.000 4.506 829.058.293.378 0.000 54.75 9.42 180.0 11/2/2023 18:38 5.59549.3558.708 4.536 1112.2805.595 0.000 0.049 110.2360.00013.765 0.000 47.4680.000 4.552 829.058.843.407 0.000 54.95 9.41 180.0 11/2/2023 18:39 5.94550.5288.701 4.540 1109.9415.615 0.000 0.000 110.2780.00013.812 0.000 47.4430.000 4.528 829.058.783.419 0.000 56.47 9.41 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 11/2/2023 18:40 3.99749.7258.707 4.534 1098.5395.575 0.000 0.000 109.2800.00014.074 0.000 47.1380.000 4.562 829.058.553.432 0.000 53.72 9.41 180.0 4.55049.5068.702 4.524 1103.4365.576 0.000 0.024 108.7440.00014.338 0.001 47.3140.000 4.599 829.0058.8143.451 0.000 54.056 9.405 180.0Avg. Spike 3 11/2/2023 18:45 0.49264.4497.976 4.530 989.54049.262 0.032 0.043 86.8910.00013.688 2.724 63.2700.000 6.064 829.079.833.915 0.786 64.94 8.71 180.0 Run 3 - B 30minute/60min 11/2/2023 18:48 5.19550.1728.704 4.520 1093.1635.844 0.000 0.000 106.8390.00014.124 0.000 46.8250.000 4.563 829.058.293.509 0.000 55.37 9.41 180.0 11/2/2023 18:49 4.32849.3478.709 4.526 1101.1025.815 0.000 0.000 107.5950.00014.243 0.000 47.2540.000 4.624 829.058.843.506 0.000 53.67 9.40 180.0 11/2/2023 18:50 4.91950.6938.706 4.530 1093.2525.554 0.000 0.000 106.3180.00014.384 0.000 46.8110.000 4.596 829.058.343.510 0.000 55.61 9.40 180.0 11/2/2023 18:51 4.62349.0398.681 4.516 1106.3815.666 0.000 0.000 108.5200.00014.215 0.000 47.2100.000 4.572 830.058.663.451 0.000 53.66 9.41 180.0 11/2/2023 18:52 4.84950.0328.711 4.538 1104.4735.754 0.000 0.000 107.7700.00014.435 0.000 46.9810.000 4.525 829.058.273.355 0.000 54.88 9.41 180.0 11/2/2023 18:53 4.30450.9648.726 4.552 1097.4445.718 0.000 0.000 107.2730.00014.301 0.000 46.3800.000 4.541 829.057.713.376 0.000 55.27 9.41 180.0 11/2/2023 18:54 3.75049.0408.700 4.525 1101.3835.666 0.000 0.000 108.1480.00014.079 0.000 46.8790.000 4.561 829.058.313.465 0.000 52.79 9.42 180.0 11/2/2023 18:55 4.45650.7518.713 4.531 1098.5155.713 0.000 0.000 107.9540.00014.417 0.000 47.0730.000 4.626 829.058.643.466 0.000 55.21 9.41 180.0 11/2/2023 18:56 4.54851.6488.721 4.538 1101.3115.817 0.000 0.025 108.2500.00014.095 0.025 47.2270.000 4.635 829.058.723.309 0.000 56.20 9.39 180.0 11/2/2023 18:57 4.31049.7578.690 4.523 1094.4795.641 0.000 0.000 106.7790.00014.075 0.000 47.5410.000 4.706 829.059.283.491 0.000 54.07 9.40 180.0 11/2/2023 18:58 4.78850.2098.706 4.521 1101.3735.701 0.000 0.001 107.8010.00014.460 0.025 47.2680.000 4.616 829.058.873.526 0.000 55.00 9.40 180.0 11/2/2023 18:59 3.81346.8398.688 4.517 1112.9455.844 0.000 0.000 110.2670.00013.927 0.000 47.4920.000 4.567 829.058.873.371 0.000 50.65 9.39 180.0 11/2/2023 19:00 4.66149.2858.714 4.530 1111.0275.927 0.000 0.000 109.6610.00014.121 0.000 47.3430.000 4.565 829.058.773.442 0.000 53.95 9.41 180.0 11/2/2023 19:01 4.66349.6898.697 4.529 1100.3225.822 0.000 0.037 108.0330.00014.235 0.000 47.5710.000 4.602 829.059.113.504 0.000 54.35 9.41 180.0 11/2/2023 19:03 3.94849.1768.681 4.518 1089.7285.838 0.000 0.000 106.2160.00014.273 0.000 47.1270.000 4.611 829.058.693.509 0.000 53.12 9.42 180.0 11/2/2023 19:04 4.23349.0788.698 4.525 1089.6595.809 0.000 0.000 106.5020.00014.168 0.000 47.2860.000 4.644 829.058.943.547 0.000 53.31 9.40 180.0 11/2/2023 19:05 3.47348.5618.695 4.525 1092.9155.797 0.000 0.053 107.2220.00014.306 0.000 47.8590.000 4.717 829.059.703.605 0.000 52.03 9.41 180.0 11/2/2023 19:06 3.45349.0238.688 4.521 1090.6495.734 0.000 0.023 107.4660.00014.263 0.000 47.8860.000 4.741 829.059.643.409 0.000 52.48 9.40 180.0 11/2/2023 19:07 3.32547.5338.666 4.522 1097.0685.751 0.000 0.038 108.2340.00014.178 0.000 48.4010.000 4.728 829.060.163.451 0.000 50.86 9.39 180.0 11/2/2023 19:08 3.88848.8198.690 4.542 1090.8875.765 0.000 0.000 107.1350.00014.362 0.000 48.2640.000 4.754 829.060.043.402 0.000 52.71 9.41 180.0 11/2/2023 19:09 4.41647.9428.681 4.532 1099.4685.710 0.000 0.000 108.6900.00014.234 0.000 48.5580.000 4.753 829.060.363.451 0.000 52.36 9.39 180.0 11/2/2023 19:10 4.16149.0518.680 4.523 1099.9185.604 0.000 0.098 108.8530.00014.220 0.000 48.4280.000 4.714 829.060.073.318 0.000 53.21 9.40 180.0 11/2/2023 19:11 3.95749.0868.708 4.534 1096.6255.707 0.000 0.000 108.1150.00014.282 0.000 48.3760.000 4.773 829.060.273.518 0.000 53.04 9.41 180.0 11/2/2023 19:12 4.10849.0588.693 4.529 1096.8675.735 0.000 0.021 108.2300.00014.335 0.000 48.4340.000 4.749 829.060.163.347 0.000 53.17 9.39 180.0 11/2/2023 19:13 4.32149.4788.684 4.523 1092.0185.716 0.000 0.077 107.3920.00014.214 0.000 48.4220.000 4.757 829.060.263.493 0.000 53.80 9.41 180.0 11/2/2023 19:14 3.66549.2718.685 4.528 1092.2595.724 0.000 0.000 107.3370.00014.766 0.000 48.1480.000 4.749 829.059.983.505 0.000 52.94 9.41 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 11/2/2023 19:15 3.42547.8488.665 4.523 1091.1945.621 0.000 0.017 107.3610.00014.061 0.000 48.1220.000 4.756 829.059.983.517 0.000 51.27 9.40 180.0 11/2/2023 19:16 4.17147.9218.689 4.535 1099.3555.742 0.000 0.035 108.5090.00014.477 0.000 48.2720.000 4.741 829.060.033.409 0.000 52.09 9.40 180.0 11/2/2023 19:17 3.85346.3188.680 4.531 1108.4945.692 0.000 0.053 109.8950.00014.106 0.000 48.9730.000 4.654 829.060.523.354 0.000 50.17 9.39 180.0 11/2/2023 19:18 3.52747.0598.677 4.522 1103.1475.678 0.000 0.013 109.1750.00014.362 0.000 48.7760.000 4.774 829.060.643.476 0.000 50.59 9.38 180.0 4.17149.0908.694 4.528 1098.2475.737 0.000 0.016 107.9180.00014.257 0.002 47.7060.000 4.664 829.0359.3373.453 0.000 53.261 9.403 180.0Avg. 4.36149.2988.698 4.526 1100.8425.656 0.000 0.020 108.3310.00014.297 0.001 47.5100.000 4.632 829.0259.0763.452 0.000 53.659 9.404 180.0Run 3 Avg: Baseline 3 11/2/2023 19:47 0.0000.000-0.001 0.000 0.4000.000 0.000 0.206 0.0670.0000.000 0.000 0.1700.000 0.000 830.00.560.577 0.000 0.00 0.19 180.0 Post CTS 11/2/2023 19:50 0.0001.526-0.000 0.000 0.0000.000 0.000 0.000 0.0000.0000.000 98.866 0.0000.000 0.000 832.066.420.761 0.000 1.53 0.18 180.0 11/2/2023 19:50 0.0001.063-0.001 0.000 0.0000.000 0.000 0.000 0.0000.0000.000 99.057 0.0210.000 0.000 832.066.430.550 0.000 1.06 0.19 180.0 11/2/2023 19:50 0.0001.429-0.000 0.000 0.0000.000 0.000 0.000 0.0000.0000.000 99.148 0.0000.000 0.000 832.066.580.713 0.000 1.43 0.19 180.0 Post O2/NO2 11/2/2023 19:55 97.4610.000-0.001 0.000 0.0000.000 0.255 0.144 0.0000.0000.000 0.000 0.0000.492 0.000 835.00.330.498 0.000 97.46 8.57 180.0 11/2/2023 19:55 98.0740.000-0.001 0.000 0.0000.000 0.255 0.177 0.0360.0000.000 0.000 0.0000.000 0.018 835.00.440.599 0.000 98.07 8.58 180.0 11/2/2023 19:55 98.8490.000-0.001 0.000 0.0000.000 0.239 0.287 0.0000.0000.000 0.000 0.0000.123 0.000 835.00.490.728 0.000 98.85 8.59 180.0 Post 5-Gas 11/2/2023 19:56 0.000243.639-0.001 4.644 0.008489.360 1.759 1.412 5.0490.1780.000 1.414 251.7100.028 0.000 836.0254.883.334 9.606 243.64 0.02 180.0 11/2/2023 19:56 0.000244.808-0.001 4.635 0.000491.069 1.761 1.739 4.8460.0890.622 1.404 252.5950.000 0.000 836.0255.573.062 9.617 244.81 0.02 180.0 11/2/2023 19:57 0.000245.775-0.001 4.634 0.351492.854 1.760 1.424 4.8040.0870.000 1.228 253.2770.000 0.000 836.0256.333.344 9.675 245.78 0.22 180.0 11/2/2023 19:57 0.000244.878-0.001 4.644 0.307492.306 1.791 1.693 4.2700.0750.000 1.346 253.9320.000 0.000 836.0257.013.270 9.656 244.88 0.12 180.0 11/2/2023 19:57 0.000244.717-0.001 4.643 0.000492.759 1.753 1.268 4.3290.0050.000 1.260 254.1350.141 0.000 836.0257.053.120 9.668 244.72 0.02 180.0 11/2/2023 19:57 0.000245.334-0.001 4.652 0.000492.756 1.791 1.415 4.2620.0701.014 1.273 253.7890.000 0.000 836.0256.512.813 9.680 245.33 0.02 180.0 End of Test Purge 11/2/2023 19:59 0.0000.000-0.001 0.000 0.0000.000 0.112 0.000 0.0000.0000.000 0.000 0.7940.000 0.000 836.01.170.559 0.000 0.00 0.17 180.0 11/2/2023 19:59 0.0000.000-0.001 0.000 0.0000.000 0.089 0.124 0.0000.0000.000 0.000 0.5990.000 0.000 836.01.030.653 0.000 0.00 0.17 180.0 11/2/2023 19:59 0.2780.000-0.001 0.000 0.0000.000 0.063 0.172 0.0000.0000.000 0.000 0.2740.000 0.000 836.00.470.293 0.000 0.28 0.17 180.0 11/2/2023 19:59 0.0000.000-0.001 0.000 0.0000.000 0.035 0.123 0.0000.0000.000 0.000 0.3120.137 0.000 836.00.600.428 0.000 0.00 0.17 180.0 11/2/2023 19:59 0.0000.000-0.001 0.000 0.0000.000 0.015 0.150 0.0000.0000.000 0.000 0.0970.000 0.000 836.00.410.476 0.000 0.00 0.17 180.0 11/2/2023 20:00 0.4600.000-0.001 0.000 0.0000.000 0.007 0.160 0.0900.0000.000 0.000 0.1020.000 0.000 836.00.400.446 0.000 0.46 0.17 180.0 GAS, Inc. Date Time H2O (%) CO2 (%) CO (ppmvw) NO (ppmvw) NO2 (ppmvw) CH4 (ppmvw) N2O (ppmvw) NH3 (ppmvw) SO2 (ppmvw) C2H4 (ppmvw) HCL (ppmvw) HF (ppmvw) C2H6 (ppmvw) C3H8 (ppmvw) C6H14 (ppmvw) C2H4O (ppmvw) SF6 (ppmvw) Nox (ppmvw) VOC (ppmvw) Oxygen (%) Cell Temp (C). Ambient Press. (mbar) 11/2/2023 20:00 0.3240.000-0.001 0.000 0.0000.000 0.000 0.178 0.0000.0000.000 0.000 0.1430.000 0.000 836.00.500.529 0.000 0.32 0.18 180.0 11/2/2023 20:00 0.0000.000-0.001 0.000 0.0000.000 0.008 0.000 0.0000.0000.000 0.000 0.0960.000 0.000 836.00.490.594 0.000 0.00 0.16 180.0 GAS, Inc.