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DAQ-2024-007436
1 DAQC-CI140160001-24 Site ID 14016 (B1) MEMORANDUM TO: FILE – DESIGNER MARBLE THROUGH: Chad Gilgen, Minor Source Compliance Section Manager FROM: Jared James, Environmental Scientist DATE: February 25, 2024 SUBJECT: FULL COMPLIANCE EVALUATION, Minor, Utah County INSPECTION DATE: February 6, 2024 SOURCE LOCATION: 943 West 240 North Lindon, UT 84042 SOURCE CONTACT(S): James Liston, Bookkeeper: 801-785-8172 james@designermarble.com OPERATING STATUS: Operating PROCESS DESCRIPTION: The Designer Marble source manufactures cultured marble. Cultured marble is used to make countertops, sinks, shower and tub enclosures, etc. First, a gel coat is sprayed into preformed molds, in the spray booth. After being sprayed, the molds are set in a heat tunnel for 15 to 20 minutes. Next, resin from an outside storage tank is mixed and poured into the molds. Once the resin has cured for a minimum of three hours, the cultured marble is taken to the sanding booth (smaller spray booth). Here, the imperfections are taken out for quality control purposes. Finally, the finished product is stored for shipping. The facility has two paint booths. APPLICABLE REGULATIONS: Approval Order (AO) DAQE-AN0140160001-07 dated May 17, 2007. SOURCE EVALUATION: General Conditions: 1. This AO applies to the following company: Site Office Designer Marble 943 West 240 North Lindon, UT 84042 Phone Number (801) 785-8172 Fax Number (801) 785-8078 0 0 2 The equipment listed in this AO shall be operated at the following location: 943 West 240 North, Lindon, Utah County Universal Transverse Mercator (UTM) Coordinate System: 4,465.93 km. Northing, 437.34 km. Easting, Zone 12, UTM datum NAD27 Status: In Compliance. The above information is correct. 2. All definitions, terms, abbreviations, and references used in this AO conform to those used in the UAC R307 and Title 40 of the Code of Federal Regulations (40 CFR). Unless noted otherwise, references cited in these AO conditions refer to those rules. Status: This is not a compliance issue. 3. The limits set forth in this AO shall not be exceeded without prior approval in accordance with R307-401. Status: In Compliance. Designer Marble did not exceed any limits set forth in this AO. 4. Modifications to the equipment or processes approved by this AO that could affect the emissions covered by this AO must be reviewed and approved in accordance with R307 401. Status: In Compliance. Designer Marble has not made any modifications in the equipment or processes approved by this AO. 5. All records referenced in this AO, which are required to be kept by the owner/operator, shall be made available to the Executive Secretary or Executive Secretary’s representative upon request. Records shall be kept for a minimum two years. Status: In Compliance. Designer Marble maintains records for a minimum of two years. 6. Designer Marble shall operate the cultured marble manufacturing operation and shall conduct its operations in accordance with the terms and conditions of this AO, which was written pursuant Designer Marble’s Notice of Intent submitted to the Division of Air Quality (DAQ) on January 22, 2007 and additional information submitted on March 13, 2007. Status: In Compliance. Designer Marble maintained that their operation and processes were consistent with the requirements of this AO. 7. The approved installations shall consist of the following equipment or equivalent*: A. One (1) Styrene storage tank – 6,000 gallon B. One (1) Spray booth equipped with panel filters – 18,000 cfm C. One (1) Spray booth equipped with panel filters – vented inside building Status: In Compliance. There have been no new or unapproved equipment onsite. Designer Marble indicated that the 6,000 gallon tank is currently empty and has been for five plus years. Small quantities of styrene are purchased for their processes. 3 8. Designer Marble shall notify the Executive Secretary in writing when the installation of the equipment listed in Condition 7 has been completed and is operational, as an initial compliance inspection is required. To insure proper credit when notifying the Executive Secretary, send your correspondence to the Executive Secretary, Attn: Compliance Section. Status: In Compliance. The sources AO has been in place since 2007. 9. Visible emissions from any stationary point or fugitive emission source associated with the source or with the control facilities shall not exceed 20% opacity. Visible emissions from the spray booth (7.B) shall not exceed 10% opacity. Opacity observations of emissions from stationary sources shall be conducted in accordance with 40 CFR 60, Appendix A, Method 9. Status: In Compliance. There were no visible emissions observed during this inspection. 10. The following production and/or consumption limits shall not be exceeded: 84,000 gallons of Unsaturated Polyester Resin To determine compliance with a rolling 12-month total, the owner/operator shall calculate a new 12-month total by the twentieth day of each month using data from the previous 12 months. Records of consumption/production shall be kept for all periods when the plant is in operation. Production/Consumption shall be determined by Designer Marble. The records of consumption/production shall be kept on a daily basis. Hours of operation shall be determined by supervisor monitoring and\maintaining of an operations log. Status: In Compliance. The rolling 12-month unsaturated polyester resin consumption from February 2023, through January 2024, indicated 19,771.25 gallons. Volatile Organic Compound (VOC) and Hazardous Air Pollutants (HAPs) Limitations 11. The plant-wide emissions of HAPs from the paint booths and associated operations shall not exceed: 17,900.00 pounds per rolling 12-month period for Styrene 80 pounds per rolling 12-month period for Methyl Methacrylate 280 pounds per rolling 12-month period for Toluene Compliance with each limitation shall be determined on a rolling 12- month total. Based on the twentieth day of each month, a new 12-month total shall be calculated using data from the previous 12 months. The HAP emissions shall be determined by maintaining a record of HAP emitting materials used each month. The record shall include the following data for each material used: A. Name of the HAPs emitting material, such as: paint, adhesive, solvent, thinner, reducers, chemical compounds, toxics, isocyanates, etc. 4 B. Density of each material used (pounds per gallon) C. Percent by weight of all HAP in each material used D. Gallons of each HAP emitting material used E. The amount HAP emitted monthly by each material used shall be calculated by the following procedure: HAP = % HAP by Weight x [Density ( lb )] x Gal Consumed x 1 ton (100) (gal) 2000 lb F. The amount of HAP emitted monthly from all materials used. G. The amount of HAPs reclaimed for the month shall be similarly quantified and\ subtracted from the quantities calculated above to provide the monthly total HAP emissions. Status: In Compliance. The rolling 12-month plant-wide emissions of HAPs from the paint booths and associated operations from February 2023, through January 2024, indicated the following: 4,184.6 pounds per rolling 12-month period for Styrene 22.0 pounds per rolling 12-month period for Methyl Methacrylate 140.4 pounds per rolling 12-month period for Toluene Designer Marble maintains monthly records of all materials used as required by this AO. See the attachment for additional information. Records & Miscellaneous 12. At all times, including periods of startup, shutdown, and malfunction, owners and operators shall, to the extent practicable, maintain and operate any equipment approved under this AO, including associated air pollution control equipment, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on the information available to the Executive Secretary which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. All maintenance performed on the equipment authorized by this AO shall be recorded. Status: In Compliance. Designer Marble indicated that the filters were replaced every three weeks. Filters were in place and appeared to be in good condition. 13. The owner/operator shall comply with R307-107. General Requirements: Unavoidable Breakdowns. Status: In Compliance. Designer Marble stated that there had been no breakdowns since the last inspection. 5 AREA SOURCE RULES EVALUATION The following Area Source Rules were evaluated during this inspection: R307-304. Solvent Cleaning. Status: In Compliance. The source uses Superior Super Flush which has a vapor pressure of 0.288 hPa @ 20ºC (1 hPa = 0.75006 mmHg), which meets 304-5 (2) as an alternative to the limits in Table 1. For all general miscellaneous cleaning operations, a person may use a cleaning material with a VOC composite vapor pressure no greater than 8mm Hg at 20 degrees Celsius. See attached SDS. R307-309. Nonattainment and Maintenance Areas for PM10 and PM2.5: Fugitive Emissions, Fugitive Dust. Status: In Compliance. There were no visible emissions observed during this inspection. The grounds are paved or landscaped. EMISSION INVENTORY: Designer Marble is not required to submit an Emissions Inventory Report. The emissions listed below are an estimate of the total potential emissions. The following information was supplied for supplemental purposes only. Pollutant Ton/yr VOCs 9.15 HAPs 9.15 PREVIOUS ENFORCEMENT ACTIONS: None in the previous five years. COMPLIANCE STATUS & RECOMMENDATIONS: Designer Marble should be considered in compliance with the conditions of AO DAQE-AN0140160001-07, dated May 17, 2007. RECOMMENDATION FOR NEXT INSPECTION: Inspect as usual. ATTACHMENTS: VEO Form, Emails, SDS Sheets, and Consumption Records. SAFETY DATA SHEET 1. Identification S-0280 Super FlushProduct identifier Other means of identification 0300745Product code Superior Industrial Solutions, Inc. P.O. Box 0186 Indianapolis, IN 46206-0186 US General Information: (317) 781-4400 Chemical Emergency: (317) 781-4470 Website: www.relyonsuperior.com SDS Request: SDSInfo@relyonsuperior.com Manufacturer information SolventRecommended use None known.Recommended restrictions 2. Hazard(s) identification Category 4Flammable liquidsPhysical hazards Category 4Acute toxicity, oralHealth hazards Category 2Skin corrosion/irritation Category 2Serious eye damage/eye irritation Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure Not classified.Environmental hazards Not classified.OSHA defined hazards Label elements Signal word Warning Hazard statement H227 Combustible liquid. H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Precautionary statement Prevention P262 Do not get in eyes, on skin, or on clothing. P261 Avoid breathing vapors or mist. P210 Keep away from flames and hot surfaces. - No smoking. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/eye protection/face protection. Response P301 + P330 + P331 If swallowed: Rinse mouth. Do NOT induce vomiting. P310 Immediately call a poison center/doctor. P302 + P350 If on skin: Wash with plenty of water. P362 + P364 Take off contaminated clothing and wash it before reuse. P332 + P313 If skin irritation occurs: Get medical advice/attention. 1 / 7 Material name: S-0280 Super Flush 0300745 Version #: 06 Revision date: 04-13-2022 Issue date: 02-23-2015 SDS US P304 + P340 If inhaled: Remove person to fresh air and keep comfortable for breathing. P312 Call a poison center/doctor if you feel unwell. P305 + P351 + P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/attention. P370 + P378 In case of fire: Use appropriate media to extinguish. Storage P235 Keep cool. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 1119-40-0Dimethyl Glutarate 50-70 34590-94-8(2-Methoxymethylethoxy) Propanol 10-30 627-93-0Dimethyl Adipate 10-30 106-65-0Dimethyl Succinate 10-30 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center or doctor/physician if you feel unwell. Inhalation Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Eye contact Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Ingestion Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May cause redness and pain. Most important symptoms/effects, acute and delayed Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim under observation. Symptoms may be delayed. Indication of immediate medical attention and special treatment needed If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. General information 5. Fire-fighting measures Water fog. Alcohol resistant foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing media The product is combustible, and heating may generate vapors which may form explosive vapor/air mixtures. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment and precautions for firefighters In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods Combustible liquid.General fire hazards 2 / 7 Material name: S-0280 Super Flush 0300745 Version #: 06 Revision date: 04-13-2022 Issue date: 02-23-2015 SDS US 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist/vapors. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Use water spray to reduce vapors or divert vapor cloud drift. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Following product recovery, flush area with water. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid discharge into drains, water courses or onto the ground.Environmental precautions 7. Handling and storage Keep away from open flames, hot surfaces and sources of ignition. Do not taste or swallow. Avoid breathing mist/vapors. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. When using, do not eat, drink or smoke. Provide adequate ventilation. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Precautions for safe handling Keep away from heat, sparks and open flame. Store in a cool, dry place out of direct sunlight. Store in tightly closed container. Store in a well-ventilated place. Keep in an area equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 600 mg/m3(2-Methoxymethylethoxy) Propanol (CAS 34590-94-8) 100 ppm US. ACGIH Threshold Limit Values ValueComponents Type STEL 150 ppm(2-Methoxymethylethoxy) Propanol (CAS 34590-94-8) TWA 100 ppm US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type STEL 900 mg/m3(2-Methoxymethylethoxy) Propanol (CAS 34590-94-8) 150 ppm TWA 600 mg/m3 100 ppm No biological exposure limits noted for the ingredient(s).Biological limit values Exposure guidelines US - California OELs: Skin designation (2-Methoxymethylethoxy) Propanol (CAS 34590-94-8) Can be absorbed through the skin. 3 / 7 Material name: S-0280 Super Flush 0300745 Version #: 06 Revision date: 04-13-2022 Issue date: 02-23-2015 SDS US US - Tennessee OELs: Skin designation Can be absorbed through the skin.(2-Methoxymethylethoxy) Propanol (CAS 34590-94-8) US NIOSH Pocket Guide to Chemical Hazards: Skin designation Can be absorbed through the skin.(2-Methoxymethylethoxy) Propanol (CAS 34590-94-8) US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Can be absorbed through the skin.(2-Methoxymethylethoxy) Propanol (CAS 34590-94-8) Good general ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station and safety shower. Appropriate engineering controls Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles). Face shield is recommended if splashing is possible. Eye/face protection Skin protection Wear appropriate chemical resistant gloves.Hand protection Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.Other If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Chemical respirator with organic vapor cartridge. Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards When using do not smoke. Keep away from food and drink. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Appearance Physical state Color Odor pH Melting point/freezing point Initial boiling point and boiling range Flash point Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) 8.883 lb/gal 1.066 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions. Stable under normal conditions.Chemical stability 4 / 7 Material name: S-0280 Super Flush 0300745 Version #: 06 Revision date: 04-13-2022 Issue date: 02-23-2015 SDS US Clear Liquid Colorless Bubble Gum Not Available Not Determined 373.28 °F (189.6 °C) Estimated 167.0 °F (75.0 °C) Lowest Flashing Component 0.9 % Estimated 14 % Estimated 0.288 hPa @ 20C (1 hPa = 0.75006 mmHg) > 1 (Air = 1) Vapor pressure Vapor pressure temp. Vapor density Solubility(ies) Solubility (water) Auto-ignition temperature Other information Pounds per gallon Specific gravity Appreciable Not Determined No dangerous reaction known under conditions of normal use.Possibility of hazardous reactions Avoid heat, sparks, open flames and other ignition sources. Suitable precautions should be utilized if using this product at temperatures above the flash point. Contact with incompatible materials. Conditions to avoid Strong oxidizing agents.Incompatible materials No hazardous decomposition products are known.Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation May cause irritation to the respiratory system. Prolonged inhalation may be harmful. Skin contact Causes skin irritation. Eye contact Causes serious eye irritation. Ingestion Harmful if swallowed. Symptoms related to the physical, chemical and toxicological characteristics Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May cause redness and pain. Information on toxicological effects Acute toxicity In high concentrations, vapors are anesthetic and may cause headache, fatigue, dizziness and central nervous system effects. Harmful if swallowed. Test ResultsComponents Species (2-Methoxymethylethoxy) Propanol (CAS 34590-94-8) Dermal Acute LD50 Rabbit 9.5 g/kg Causes skin irritation.Skin corrosion/irritation Causes serious eye irritation.Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. This product is not expected to cause skin sensitization.Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity Not classifiable as to carcinogenicity to humans. IARC Monographs. Overall Evaluation of Carcinogenicity Not listed. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) Not listed. US. National Toxicology Program (NTP) Report on Carcinogens Not listed. This product is not expected to cause reproductive or developmental effects.Reproductive toxicity Specific target organ toxicity - single exposure May cause respiratory irritation. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Ecotoxicity No data is available on the degradability of any ingredients in the mixture. Persistence and degradability Bioaccumulative potential 5 / 7 Material name: S-0280 Super Flush 0300745 Version #: 06 Revision date: 04-13-2022 Issue date: 02-23-2015 SDS US Partition coefficient n-octanol / water (log Kow) 0.004(2-Methoxymethylethoxy) Propanol Dimethyl Adipate 1.03 Dimethyl Glutarate 0.62 Dimethyl Succinate 0.35 No data available.Mobility in soil Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation potential. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations.Local disposal regulations Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Contaminated packaging 14. Transport information DOT BULK NA1993UN number Combustible Liquid, n.o.s. (Dipropylene Glycol Monomethyl Ether)Proper shipping name Combustible LiquidHazard class IIIPacking group 128 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US federal regulations Toxic Substances Control Act (TSCA) Restrictions of Use None known TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) Not listed. SARA 302 Extremely hazardous substance Superfund Amendments and Reauthorization Act of 1986 (SARA) Not listed. YesSARA 311/312 Hazardous chemical Flammable (gases, aerosols, liquids, or solids) Acute toxicity (any route of exposure) Skin corrosion or irritation Serious eye damage or eye irritation Specific target organ toxicity (single or repeated exposure) Classified hazard categories SARA 313 (TRI reporting) Not regulated. 6 / 7 Material name: S-0280 Super Flush 0300745 Version #: 06 Revision date: 04-13-2022 Issue date: 02-23-2015 SDS US ERG code DOT NON-BULK Not regulated in a container less than 119 gallons. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Contains component(s) regulated under the Safe Drinking Water Act.Safe Drinking Water Act (SDWA) US state regulations California Proposition 65 This product can expose you to Methanol, which is known to the State of California to cause birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov. WARNING: California Proposition 65 - CRT: Listed date/Developmental toxin Methanol (CAS 67-56-1) Listed: March 16, 2012 International Inventories Country(s) or region Inventory name On inventory (yes/no)* YesAustralia Australian Inventory of Chemical Substances (AICS) YesCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) YesChina Inventory of Existing Chemical Substances in China (IECSC) NoEurope European Inventory of Existing Commercial Chemical Substances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) NoJapan Inventory of Existing and New Chemical Substances (ENCS) YesKorea Existing Chemicals List (ECL) YesNew Zealand New Zealand Inventory YesPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesTaiwanTaiwan Chemical Substance Inventory (TCSI) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 02-23-2015Issue date 04-13-2022Revision date Version #06 Superior Industrial Solutions, Inc. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s sole responsibility to determine whether the particular purpose and use of the product is proper, suitable and safe, and to ensure safe conditions for handling, storage and disposal of the product, and the user assumes all liability for loss, injury, damage or expense arising out of its use. This information is based on data available to us and is accurate to the best of our knowledge at the time of printing. However, no representation or warranty is expressed or implied, including warranties of merchantability or fitness for a particular purpose, regarding the accuracy or completeness of the information contained herein. All materials may present known and unknown hazards and should be used with caution. Buyer assumes all risk and liabilities arising out of these hazards. Buyer accepts and uses this material on these conditions. Disclaimer This document has undergone significant changes and should be reviewed in its entirety.Revision information 7 / 7 Material name: S-0280 Super Flush 0300745 Version #: 06 Revision date: 04-13-2022 Issue date: 02-23-2015 SDS US White Low VOC Gel Coat Unsaturated Polyester Resin Gel Coat Liquid. SAFETY DATA SHEET GHS product identifier Other means of identification Product type Emergency telephone number (with hours of operation) Section 1. Identification : : : : Supplier's details :INTERPLASTIC CORPORATION 1225 Willow Lake Boulevard St. Paul, MN 55110-5145 651.481.6860 White Low VOC Gel Coat Relevant identified uses of the substance or mixture and uses advised against Product code :W-738-LIHN Industrial applications. CHEMTREC 24-Hour Emergency Telephone US and Canada 800.424.9300 Outside US and Canada +1 703.741.5970 Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (inhalation) - Category 4 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) - Category 1 Classification of the substance or mixture : Signal word :Danger Hazard statements :Flammable liquid and vapor. Harmful if inhaled. Causes serious eye irritation. Causes skin irritation. May cause respiratory irritation. Causes damage to organs through prolonged or repeated exposure. (hearing organs) Hazard pictograms : Precautionary statements GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 17% Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 46.6% Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 17% OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision :5/27/2022 Date of previous issue :8/17/2020 Version :2 1/14 White Low VOC Gel Coat W-738-LIHN Section 2. Hazards identification Prevention :Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion- proof electrical, ventilating, lighting and all material-handling equipment. Use only non- sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Response :Get medical attention if you feel unwell. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage :Store in a well-ventilated place. Keep cool. Store containers in a safe place. Disposal :Dispose of contents and container in accordance with all local, regional, national and international regulations. Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Hazards not otherwise classified :None known. Section 3. Composition/information on ingredients There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification :Unsaturated Polyester Resin Gel Coat Substance/mixture : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Any concentration shown as exact is based on formula. VOC content is listed in Section 9. Environmental composition is shown in Section 15. styrene <= 30.0 100-42-5 Titanium dioxide <= 17.0 13463-67-7 talc (none asbestiform)<= 17.0 14807-96-6 Ingredient name %CAS number Section 4. First aid measures Eye contact : Description of necessary first aid measures Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Buffered baby shampoo will aid in removal of resin. Date of issue/Date of revision :5/27/2022 Date of previous issue :8/17/2020 Version :2 2/14 White Low VOC Gel Coat W-738-LIHN Section 4. First aid measures Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention following exposure or if feeling unwell. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Remove contaminated clothing and shoes. Flush contaminated skin with plenty of water. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Skin contact Inhalation Ingestion : : : Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments :No specific treatment. Most important symptoms/effects, acute and delayed Inhalation :Harmful if inhaled. May cause respiratory irritation. No known significant effects or critical hazards.:Ingestion Skin contact :Causes skin irritation. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing No specific data. Adverse symptoms may include the following: irritation redness : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Date of issue/Date of revision :5/27/2022 Date of previous issue :8/17/2020 Version :2 3/14 White Low VOC Gel Coat W-738-LIHN Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use dry chemical, CO₂, water spray (fog) or foam. Extinguishing media : : : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Wear appropriate respiratory protection. Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Absorb with an inert material and transfer the spilled material and absorbent to an appropriate waste disposal container. Wear appropriate respirator when ventilation is inadequate. Wear eye/face protection. Date of issue/Date of revision :5/27/2022 Date of previous issue :8/17/2020 Version :2 4/14 White Low VOC Gel Coat W-738-LIHN Section 6. Accidental release measures Wear protective clothing and eye or face protection: Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Do not store above the following temperature: 38°C (100.4°F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. Store containers in a safe place. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Do not breathe vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling styrene ACGIH TLV (United States, 3/2019). TWA: 20 ppm 8 hours. STEL: 40 ppm 15 minutes. OSHA PEL 1989 (United States, 3/1989). TWA: 50 ppm 8 hours. TWA: 215 mg/m³ 8 hours. STEL: 100 ppm 15 minutes. STEL: 425 mg/m³ 15 minutes. OSHA PEL Z2 (United States, 2/2013). TWA: 100 ppm 8 hours. CEIL: 200 ppm AMP: 600 ppm 5 minutes. NIOSH REL (United States, 10/2016). TWA: 50 ppm 10 hours. TWA: 215 mg/m³ 10 hours. STEL: 100 ppm 15 minutes. STEL: 425 mg/m³ 15 minutes. Titanium dioxide ACGIH TLV (United States, 3/2019). TWA: 10 mg/m³ 8 hours. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits Date of issue/Date of revision :5/27/2022 Date of previous issue :8/17/2020 Version :2 5/14 White Low VOC Gel Coat W-738-LIHN Section 8. Exposure controls/personal protection OSHA PEL 1989 (United States, 3/1989). TWA: 10 mg/m³ 8 hours. Form: Total dust OSHA PEL (United States, 5/2018). TWA: 15 mg/m³ 8 hours. Form: Total dust talc (none asbestiform)OSHA PEL 1989 (United States, 3/1989). TWA: 2 mg/m³ 8 hours. Form: Respirable dust NIOSH REL (United States, 10/2016). TWA: 2 mg/m³ 10 hours. Form: Respirable fraction ACGIH TLV (United States, 3/2019). TWA: 2 mg/m³ 8 hours. Form: Respirable fraction Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Environmental exposure controls :Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Date of issue/Date of revision :5/27/2022 Date of previous issue :8/17/2020 Version :2 6/14 White Low VOC Gel Coat W-738-LIHN Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. Not available. 1.28 to 1.44 3.6 [Air = 1] 0.67 kPa (5 mm Hg) [room temperature] Not available. Aromatic. Sweetish.Odor pH White.Color Evaporation rate <1 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: 31°C (87.8°F) Not available. Not applicable. Viscosity Not available. 0.1 ppmOdor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point :145°C (293°F) Lower and upper explosive (flammable) limits :Lower: 0.9% Upper: 6.8% Solubility in water :Not applicable. VOC content :29.8 % (w/w)As shipped, including monomers and additives. Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions :Hazardous reactions or instability may occur under certain conditions of storage or use. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Hazardous polymerization may occur under certain conditions of storage or use. Keep away from heat and direct sunlight. Keep away from heat and flame. Keep away from oxidizing agents. Reactive or incompatible with the following materials: metals, acids and alkalis. Incompatible with alkali metals. Incompatible with some alkalis. Incompatible with some strong acids. Incompatible with copper alloys, brass. Date of issue/Date of revision :5/27/2022 Date of previous issue :8/17/2020 Version :2 7/14 White Low VOC Gel Coat W-738-LIHN Section 11. Toxicological information Acute toxicity styrene LC50 Inhalation Gas.Rat 2770 ppm 4 hours LC50 Inhalation Vapor Rat 11800 mg/m³4 hours LD50 Oral Rat 2650 mg/kg - Product/ingredient name Result Species Dose Exposure Carcinogenicity Not available. Conclusion/Summary : Mutagenicity Not available. Irritation/Corrosion styrene Eyes - Mild irritant Human -50 ppm - Eyes - Moderate irritant Rabbit -24 hours 100 mg - Eyes - Severe irritant Rabbit -100 mg - Skin - Mild irritant Rabbit -500 mg - Skin - Moderate irritant Rabbit -100 %- Titanium dioxide Skin - Mild irritant Human -72 hours 300 ug I - talc (none asbestiform)Skin - Mild irritant Human -72 hours 300 ug I - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Information on toxicological effects Classification styrene -2A Reasonably anticipated to be a human carcinogen. Titanium dioxide -2B - talc (none asbestiform)-3 - Product/ingredient name NTPIARCOSHA Styrene manufacturers have determined that the weight of evidence for the carcinogenicity of this substance does not meet the criteria for classification. In 2018, styrene was listed by IARC as a probable carcinogen to humans (Group 2A) based on hazard assessment data. The United States NTP listed styrene as reasonably anticipated to be a human carcinogen based on "limited evidence" from studies in humans, "sufficient evidence" from studies in experimental animals, and supporting data on mechanisms of carcinogenesis. The significance of these results for humans has not been established through risk assessment. Titanium dioxide manufacturers have determined that the weight of evidence for the carcinogenicity of this substance does not meet the criteria for classification. Exposure to respirable particles of this substance from the product as shipped is not likely. Exposure to respirable dust is possible when cutting, grinding, or sanding a cured item. Titanium Dioxide is listed as IARC Group 2B possible carcinogen to humans is based on "sufficient evidence" in experimental animals and "inadequate evidence" in humans and respiratory tract exposure to very high concentrations of dust containing titanium dioxide. Date of issue/Date of revision :5/27/2022 Date of previous issue :8/17/2020 Version :2 8/14 White Low VOC Gel Coat W-738-LIHN Section 11. Toxicological information Teratogenicity Not available. Reproductive toxicity Not available. Information on the likely routes of exposure Inhalation :Harmful if inhaled. May cause respiratory irritation. No known significant effects or critical hazards.:Ingestion Skin contact :Causes skin irritation. Causes serious eye irritation.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing No specific data. Adverse symptoms may include the following: irritation redness : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Delayed and immediate effects and also chronic effects from short and long term exposure Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) styrene Category 3 Not applicable.Respiratory tract irritation Name Category Name Category styrene Category 1 Inhalation hearing organs talc (none asbestiform)Category 2 Inhalation Not determined Aspiration hazard Name Result styrene ASPIRATION HAZARD - Category 1 Route of exposure Target organs Route of exposure Target organs :Not available. Potential acute health effects Potential immediate effects :Not available. Short term exposure Potential delayed effects :Not available. A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm for an 8-hour TWA indicated a possible mild hearing loss. Date of issue/Date of revision :5/27/2022 Date of previous issue :8/17/2020 Version :2 9/14 White Low VOC Gel Coat W-738-LIHN Section 11. Toxicological information Not available. Causes damage to organs through prolonged or repeated exposure.General : No known significant effects or critical hazards.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Fertility effects :No known significant effects or critical hazards. Potential chronic health effects Numerical measures of toxicity Oral 7435.6 mg/kg Inhalation (gases)7772.3 ppm Inhalation (vapors)33.11 mg/l Route ATE value Acute toxicity estimates Potential immediate effects :Not available. Long term exposure Potential delayed effects :Not available. Section 12. Ecological information Bioaccumulative potential Product/ingredient name Aquatic half-life Photolysis Biodegradability styrene --Readily Toxicity styrene Acute EC50 1400 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Acute EC50 720 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Acute EC50 4700 µg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 52 mg/l Marine water Crustaceans - Artemia salina 48 hours Acute LC50 4020 µg/l Fresh water Fish - Pimephales promelas 96 hours Chronic NOEC 63 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Titanium dioxide Acute LC50 3 mg/l Fresh water Crustaceans - Ceriodaphnia dubia - Neonate 48 hours Acute LC50 6.5 mg/l Fresh water Daphnia - Daphnia pulex - Neonate 48 hours Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours Product/ingredient name SpeciesResult Exposure Persistence and degradability styrene OECD 70 % - Readily - 28 days -- Product/ingredient name Test DoseResult Inoculum Date of issue/Date of revision :5/27/2022 Date of previous issue :8/17/2020 Version :2 10/14 White Low VOC Gel Coat W-738-LIHN Section 12. Ecological information LogPow BCF Potential Other adverse effects :No known significant effects or critical hazards. Product/ingredient name styrene 0.35 13.49 low Soil/water partition coefficient (KOC) :Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Section 14. Transport information RESIN SOLUTION 3 III RESIN SOLUTION 3 III RESIN SOLUTION UN1866 3 III UN1866 UN1866 Reportable quantity 3381.4 lbs / 1535.1 kg [298.19 gal / 1128.8 L]. Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. DOT Classification IMDGIATA UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards No.No.No. Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3). Mexico Classification UN1866 RESIN SOLUTION 3 III No. DOT Classification TDG Classification : : TDG Classification UN1866 RESIN SOLUTION 3 III No. Date of issue/Date of revision :5/27/2022 Date of previous issue :8/17/2020 Version :2 11/14 White Low VOC Gel Coat W-738-LIHN Section 14. Transport information Special precautions for user Transport in bulk according to Annex II of MARPOL and the IBC Code Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. :Not available. : Section 15. Regulatory information U.S. Federal regulations The following components are listed: STYRENE; PHENYLETHYLENE; TALC; SOAPSTONE; TITANIUM DIOXIDE; TIN DIOXIDE DUST; PRECIPITATED SILICA; Silica, precipitated Clean Water Act (CWA) 307: Naphthenic acids, copper salts; 2-ethylhexanoic acid, copper salt Clean Water Act (CWA) 311: styrene; propionic acid Massachusetts : : SARA 313 Product name CAS number % Form R - Reporting requirements Supplier notification Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) : Clean Air Act Section 602 Class I Substances :Not listed Clean Air Act Section 602 Class II Substances :Not listed New York :The following components are listed: Styrene State regulations TSCA 8(a) PAIR: Siloxanes and Silicones, di-Me; 4-tert-butylpyrocatechol; mequinol TSCA 8(a) CDR Exempt/Partial exemption: Not determined SARA 302/304 SARA 304 RQ :2000000 lbs / 908000 kg [176373.7 gal / 667647.1 L] 1,4-dihydroxybenzene <0.1 Yes.500 / 10000 -100 - Composition/information on ingredients Name %EHS (lbs)(lbs)(gallons)(gallons) SARA 302 TPQ SARA 304 RQ SARA 311/312 Classification :FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (inhalation) - Category 4 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) - Category 1 styrene 100-42-5 <= 30.0 styrene 100-42-5 29.57 Listed If components are "Listed", and additional information is required, contact Supplier using email in Section 16. Date of issue/Date of revision :5/27/2022 Date of previous issue :8/17/2020 Version :2 12/14 White Low VOC Gel Coat W-738-LIHN Section 15. Regulatory information Styrene Titanium dioxide Ethylene Glycol California Prop. 65 New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-; SOAPSTONE; TITANIUM DIOXIDE; TITANIUM OXIDE (TiO2); SILICA, AMORPHOUS, PRECIPITATE & GEL Pennsylvania :The following components are listed: BENZENE, ETHENYL-; TALC; SOAPSTONE DUST; TITANIUM OXIDE; PRECIPITATED SILICA Inventory list Australia :Not determined. Canada :At least one component is not listed in DSL but all such components are listed in NDSL. China :All components are listed or exempted. Europe :Not determined. Japan :Japan inventory (ENCS): Not determined. Japan inventory (ISHL): Not determined. Republic of Korea :All components are listed or exempted. Malaysia :Not determined. New Zealand :All components are listed or exempted. Philippines :Not determined. Taiwan :All components are listed or exempted. Turkey :Not determined. United States :All components are listed or exempted. Thailand :Not determined. Viet Nam :All components are listed or exempted. :The following components are listed. For more information go to www.P65Warnings.ca.gov. Section 16. Other information Hazardous Material Information System (U.S.A.) 2 3 1 1 3 2 * National Fire Protection Association (U.S.A.) Health Special Instability/Reactivity Flammability Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual. Date of issue/Date of revision :5/27/2022 Date of previous issue :8/17/2020 Version :2 13/14 White Low VOC Gel Coat W-738-LIHN Section 16. Other information 5/27/2022 History Date of printing Date of issue/Date of revision Version Prepared by To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Notice to reader Date of previous issue : : : : : Indicates information that has changed from previously issued version. References : Key to abbreviations :ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 5/27/2022 8/17/2020 2 Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Procedure used to derive the classification Classification Justification FLAMMABLE LIQUIDS - Category 3 On basis of test data ACUTE TOXICITY (inhalation) - Category 4 Calculation method SKIN IRRITATION - Category 2 Calculation method EYE IRRITATION - Category 2A Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) - Category 1 Calculation method Health, Safety and Environmental Department For questions about the SDS, contact :iasafety@ip-corporation.com 29 CFR 1910.1200 Hazard Communication Standard, March 2012 CCR Title 27 Division 4 Office of Environmental Health Hazard Assessment (California Prop. 65) American Composites Manufacturers Association Styrene Information and Research Center New form 08-2018 Date of issue/Date of revision :5/27/2022 Date of previous issue :8/17/2020 Version :2 14/14 Dual Purpose Marble Resin Unsaturated Polyester Resin Liquid. SAFETY DATA SHEET GHS product identifier Other means of identification Product type Emergency telephone number (with hours of operation) Section 1. Identification : : : : Supplier's details :INTERPLASTIC CORPORATION 1225 Willow Lake Boulevard St. Paul, MN 55110-5145 651.481.6860 Dual Purpose Marble Resin Relevant identified uses of the substance or mixture and uses advised against Product code :SIL94BA-1921SS Industrial applications. CHEMTREC 24-Hour Emergency Telephone US and Canada 800.424.9300 Outside US and Canada +1 703.741.5970 Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (inhalation) - Category 4 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) - Category 1 Classification of the substance or mixture : Signal word :Danger Hazard statements :Flammable liquid and vapor. Harmful if inhaled. Causes serious eye irritation. Causes skin irritation. May cause respiratory irritation. Causes damage to organs through prolonged or repeated exposure. (hearing organs) Hazard pictograms : Precautionary statements GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 31.1% OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision :6/4/2021 Date of previous issue :9/7/2018 Version :1.01 1/14 Dual Purpose Marble Resin SIL94BA-1921SS Section 2. Hazards identification Prevention :Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion- proof electrical, ventilating, lighting and all material-handling equipment. Use only non- sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Response :Get medical attention if you feel unwell. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage :Store in a well-ventilated place. Keep cool. Store containers in a safe place. Disposal :Dispose of contents and container in accordance with all local, regional, national and international regulations. Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Hazards not otherwise classified :None known. Section 3. Composition/information on ingredients There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification :Unsaturated Polyester Resin Substance/mixture : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Any concentration shown as exact is based on formula. VOC content is listed in Section 9. Environmental composition is shown in Section 15. styrene <= 32.0 100-42-5 Ingredient name %CAS number Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Inhalation : : Description of necessary first aid measures Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Buffered baby shampoo will aid in removal of resin. Date of issue/Date of revision :6/4/2021 Date of previous issue :9/7/2018 Version :1.01 2/14 Dual Purpose Marble Resin SIL94BA-1921SS Section 4. First aid measures Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention following exposure or if feeling unwell. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Remove contaminated clothing and shoes. Flush contaminated skin with plenty of water. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Skin contact Ingestion : : Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments :No specific treatment. Most important symptoms/effects, acute and delayed Inhalation :Harmful if inhaled. May cause respiratory irritation. No known significant effects or critical hazards.:Ingestion Skin contact :Causes skin irritation. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing No specific data. Adverse symptoms may include the following: irritation redness : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Use dry chemical, CO₂, water spray (fog) or foam. Extinguishing media Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Date of issue/Date of revision :6/4/2021 Date of previous issue :9/7/2018 Version :1.01 3/14 Dual Purpose Marble Resin SIL94BA-1921SS Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : : : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Wear appropriate respiratory protection. Wear protective clothing and eye or face protection: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Absorb with an inert material and transfer the spilled material and absorbent to an appropriate waste disposal container. Wear appropriate respirator when ventilation is inadequate. Wear eye/face protection. Date of issue/Date of revision :6/4/2021 Date of previous issue :9/7/2018 Version :1.01 4/14 Dual Purpose Marble Resin SIL94BA-1921SS Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Do not store above the following temperature: 38°C (100.4°F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. Store containers in a safe place. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Do not breathe vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling styrene ACGIH TLV (United States, 3/2019). TWA: 20 ppm 8 hours. STEL: 40 ppm 15 minutes. OSHA PEL 1989 (United States, 3/1989). TWA: 50 ppm 8 hours. TWA: 215 mg/m³ 8 hours. STEL: 100 ppm 15 minutes. STEL: 425 mg/m³ 15 minutes. OSHA PEL Z2 (United States, 2/2013). TWA: 100 ppm 8 hours. CEIL: 200 ppm AMP: 600 ppm 5 minutes. NIOSH REL (United States, 10/2016). TWA: 50 ppm 10 hours. TWA: 215 mg/m³ 10 hours. STEL: 100 ppm 15 minutes. STEL: 425 mg/m³ 15 minutes. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits Date of issue/Date of revision :6/4/2021 Date of previous issue :9/7/2018 Version :1.01 5/14 Dual Purpose Marble Resin SIL94BA-1921SS Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Environmental exposure controls :Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Liquid. Not available. Characteristic.Odor pH VariousColor Evaporation rate <1 (butyl acetate = 1) Flash point Closed cup: 31.1°C (88°F) Not applicable. 0.1 ppmOdor threshold : : : : : : : : Appearance Boiling point :145°C (293°F) Date of issue/Date of revision :6/4/2021 Date of previous issue :9/7/2018 Version :1.01 6/14 Dual Purpose Marble Resin SIL94BA-1921SS Section 9. Physical and chemical properties Vapor pressure Relative density Vapor density Solubility 1 to 1.2 3.6 [Air = 1] 0.67 kPa (5 mm Hg) [room temperature] Not available. Auto-ignition temperature Not available. Not available. Viscosity Not available. Partition coefficient: n- octanol/water : : : : : : : Lower and upper explosive (flammable) limits :Lower: 0.9% Upper: 6.8% Solubility in water :Not applicable. VOC content :31.8 % (w/w)As shipped, including monomers and additives. Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions :Hazardous reactions or instability may occur under certain conditions of storage or use. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Hazardous polymerization may occur under certain conditions of storage or use. Keep away from heat and direct sunlight. Keep away from heat and flame. Keep away from oxidizing agents. Reactive or incompatible with the following materials: metals, acids and alkalis. Incompatible with alkali metals. Incompatible with some alkalis. Incompatible with some strong acids. Incompatible with copper alloys, brass. Section 11. Toxicological information Acute toxicity styrene LC50 Inhalation Gas.Rat 2770 ppm 4 hours LC50 Inhalation Vapor Rat 11800 mg/m³4 hours LD50 Oral Rat 2650 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Information on toxicological effects Date of issue/Date of revision :6/4/2021 Date of previous issue :9/7/2018 Version :1.01 7/14 Dual Purpose Marble Resin SIL94BA-1921SS Section 11. Toxicological information Carcinogenicity Not available. Conclusion/Summary : Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. styrene Eyes - Mild irritant Human -50 ppm - Eyes - Moderate irritant Rabbit -24 hours 100 mg - Eyes - Severe irritant Rabbit -100 mg - Skin - Mild irritant Rabbit -500 mg - Skin - Moderate irritant Rabbit -100 %- Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) styrene Category 3 Not applicable.Respiratory tract irritation Name Category Name Category styrene Category 1 Inhalation hearing organs Aspiration hazard Name Result styrene ASPIRATION HAZARD - Category 1 Route of exposure Target organs Route of exposure Target organs Classification styrene -2A Reasonably anticipated to be a human carcinogen. Product/ingredient name NTPIARCOSHA Styrene manufacturers have determined that the weight of evidence for the carcinogenicity of this substance does not meet the criteria for classification. In 2018, styrene was listed by IARC as a probable carcinogen to humans (Group 2A) based on hazard assessment data. The United States NTP listed styrene as reasonably anticipated to be a human carcinogen based on "limited evidence" from studies in humans, "sufficient evidence" from studies in experimental animals, and supporting data on mechanisms of carcinogenesis. The significance of these results for humans has not been established through risk assessment. A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm for an 8-hour TWA indicated a possible mild hearing loss. Date of issue/Date of revision :6/4/2021 Date of previous issue :9/7/2018 Version :1.01 8/14 Dual Purpose Marble Resin SIL94BA-1921SS Section 11. Toxicological information Not available. Information on the likely routes of exposure Inhalation :Harmful if inhaled. May cause respiratory irritation. No known significant effects or critical hazards.:Ingestion Skin contact :Causes skin irritation. Causes serious eye irritation.:Eye contact Causes damage to organs through prolonged or repeated exposure.General : No known significant effects or critical hazards.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Fertility effects :No known significant effects or critical hazards. Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing No specific data. Adverse symptoms may include the following: irritation redness : : : Eye contact :Adverse symptoms may include the following: pain or irritation watering redness Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 8518.2 mg/kg Inhalation (gases)8904 ppm Inhalation (vapors)37.93 mg/l Route ATE value Acute toxicity estimates :Not available. Potential acute health effects Potential immediate effects :Not available. Short term exposure Potential delayed effects :Not available. Potential immediate effects :Not available. Long term exposure Potential delayed effects :Not available. Date of issue/Date of revision :6/4/2021 Date of previous issue :9/7/2018 Version :1.01 9/14 Dual Purpose Marble Resin SIL94BA-1921SS Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects :No known significant effects or critical hazards. Product/ingredient name styrene 0.35 13.49 low Product/ingredient name Aquatic half-life Photolysis Biodegradability styrene --Readily Toxicity styrene Acute EC50 1400 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Acute EC50 720 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Acute EC50 4700 µg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 52 mg/l Marine water Crustaceans - Artemia salina 48 hours Acute LC50 4020 µg/l Fresh water Fish - Pimephales promelas 96 hours Chronic NOEC 63 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours Product/ingredient name SpeciesResult Exposure Persistence and degradability styrene OECD 70 % - Readily - 28 days -- Product/ingredient name Test DoseResult Inoculum Soil/water partition coefficient (KOC) :Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Date of issue/Date of revision :6/4/2021 Date of previous issue :9/7/2018 Version :1.01 10/14 Dual Purpose Marble Resin SIL94BA-1921SS Section 14. Transport information RESIN SOLUTION 3 III RESIN SOLUTION 3 III RESIN SOLUTION UN1866 3 III UN1866 UN1866 Reportable quantity 3214.4 lbs / 1459.4 kg [350.47 gal / 1326.7 L]. Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. DOT Classification IMDGIATA UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL and the IBC Code No.No.No. Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. :Not available. : Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3). Mexico Classification UN1866 RESIN SOLUTION 3 III No. DOT Classification TDG Classification : : TDG Classification UN1866 RESIN SOLUTION 3 III No. Section 15. Regulatory information U.S. Federal regulations Clean Water Act (CWA) 307: Naphthenic acids, copper salts; 2-ethylhexanoic acid, copper salt Clean Water Act (CWA) 311: styrene : Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) : Clean Air Act Section 602 Class I Substances :Not listed Clean Air Act Section 602 Class II Substances :Not listed TSCA 5(a)2 final significant new use rules: pentane-2,4-dione TSCA 8(a) PAIR: Poly(oxy-1,2-ethanediyl), α-[4-(1,1,3,3-tetramethylbutyl)phenyl]-ω- hydroxy-; pentane-2,4-dione; 4-tert-butylpyrocatechol; triethyl phosphate TSCA 8(a) CDR Exempt/Partial exemption: Not determined TSCA 8(c) calls for record of SAR: triethyl phosphate SARA 302/304 Listed If components are "Listed", and additional information is required, contact Supplier using email in Section 16. Date of issue/Date of revision :6/4/2021 Date of previous issue :9/7/2018 Version :1.01 11/14 Dual Purpose Marble Resin SIL94BA-1921SS Section 15. Regulatory information The following components are listed: STYRENE; PHENYLETHYLENEMassachusetts: SARA 313 Product name CAS number % SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. Styrene Methanol Form R - Reporting requirements Supplier notification California Prop. 65 New York :The following components are listed: Styrene New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL- Pennsylvania :The following components are listed: BENZENE, ETHENYL- State regulations SARA 304 RQ :4982166.3 lbs / 2261903.5 kg [543210.6 gal / 2056275.9 L] 1,4-dihydroxybenzene <0.1 Yes.500 / 10000 -100 - Composition/information on ingredients Name %EHS (lbs)(lbs)(gallons)(gallons) SARA 302 TPQ SARA 304 RQ Inventory list Australia :All components are listed or exempted. Canada :All components are listed or exempted. China :All components are listed or exempted. Europe :Not determined. Japan :Japan inventory (ENCS): Not determined. Japan inventory (ISHL): Not determined. Republic of Korea :All components are listed or exempted. Malaysia :Not determined. New Zealand :Not determined. Philippines :Not determined. Taiwan :All components are listed or exempted. Turkey :Not determined. United States :All components are listed or exempted. Thailand :Not determined. SARA 311/312 Classification :FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (inhalation) - Category 4 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) - Category 1 :The following components are listed. For more information go to www.P65Warnings.ca.gov. styrene 100-42-5 <= 32.0 styrene 100-42-5 31.11 Any concentration shown as exact is based on formula. Date of issue/Date of revision :6/4/2021 Date of previous issue :9/7/2018 Version :1.01 12/14 Dual Purpose Marble Resin SIL94BA-1921SS Section 15. Regulatory information Viet Nam :All components are listed or exempted. Section 16. Other information 6/4/2021 History Date of printing Date of issue/Date of revision Version Prepared by Date of previous issue : : : : : 6/4/2021 9/7/2018 1.01 Hazardous Material Information System (U.S.A.) 2 3 1 1 3 2 * National Fire Protection Association (U.S.A.) Health Special Instability/Reactivity Flammability Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual. Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Procedure used to derive the classification Classification Justification FLAMMABLE LIQUIDS - Category 3 On basis of test data ACUTE TOXICITY (inhalation) - Category 4 Calculation method SKIN IRRITATION - Category 2 Calculation method EYE IRRITATION - Category 2A Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) - Category 1 Calculation method Health, Safety and Environmental Department For questions about the SDS, contact :iasafety@ip-corporation.com New form 08-2018 Date of issue/Date of revision :6/4/2021 Date of previous issue :9/7/2018 Version :1.01 13/14 Dual Purpose Marble Resin SIL94BA-1921SS Section 16. Other information To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Notice to reader Indicates information that has changed from previously issued version. References : Key to abbreviations :ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 29 CFR 1910.1200 Hazard Communication Standard, March 2012 CCR Title 27 Division 4 Office of Environmental Health Hazard Assessment (California Prop. 65) American Composites Manufacturers Association Styrene Information and Research Center Date of issue/Date of revision :6/4/2021 Date of previous issue :9/7/2018 Version :1.01 14/14 MATERIAL SAFETY DATA Chemtrec 24-Hour Emergency Telephone Domestic North America (800) 424-9300 International (800) 527-3887 This MSDS complies with 29 CFR 1910.1200 (Hazard Communications) - 1 - 12/19/10 1. Product and Supplier Identification Product Name: Acetone Product Number: 203D Date of Prep: 12/19/2010 Product Type: 2-Propanone, Westech Acetone Supplier: Fiberlay Inc. 24 S. Idaho S. Seattle, Wa 98134 (206)782-0660 2. Composition/Information On Ingredients CAS No. Chemical Name Concentration 67-64-1 Acetone 99-100% 3. Hazards Identification EMERGENCY OVERVIEW IMMEDIATE CONCERNS: DANGER! Flammable liquid and vapor. May cause eye, skin and respiratory tract irritation. May cause asphyxiation, or brain, lung or other organ injury if inhaled, swallowed or absorbed by the skin. POTENTIAL HEALTH EFFECTS EYES: Liquid is severely irritating to the eyes. High vapor concentrations are also irritating. SKIN: Liquid is mildly irritating to the skin. Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). INGESTION: Ingestion may cause headache, dizziness, fatigue, and central nervous system depression. INHALATION: Vapors may be irritating to the nose, throat, and respiratory tract. Exposure to high vapor concentrations may cause central nervous system (CNS) depression. SIGNS AND SYMPTOMS OF OVEREXPOSURE ACUTE TOXICITY: Irritation as noted above. Early to moderate CNS depression may be evidenced by giddiness, headache, dizziness, and nausea; in extreme cases, unconsciousness and death may occur. MEDICAL CONDITIONS AGGRAVATED: Pre-existing eye and skin disorders may be aggravated by exposure. 4. First Aid Measures EYES: Immediately flush eyes with plenty of water for at least 15 minutes while holding eyelids open. Get medical attention, if irritation occurs or persists. SKIN: Flush skin with water while removing contaminated clothing. If irritation occurs, get medical attention. Do not reuse clothing or shoes until cleaned. Acetone – 203D - 2 - 12/29/10 INGESTION: Do not give liquids if victim is unconscious or drowsy. Otherwise, give 2 glasses of water and induce vomiting by giving 30cc syrup of ipecac (or touching finger to the back of victim's throat). Keep victim's head below hips while vomiting. Call doctor. INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, oxygen should be administered by qualified personnel. Seek immediate medical attention. NOTES TO PHYSICIAN: If victim is a child, give no more than 1 glass of water and 15cc (1 tablespoon) syrup of ipecac. If symptoms such as loss of gag reflex, convulsions or unconsciousness occur before emesis, gastric lavage should be considered following intubation with a cuffed endotracheal tube. 5. Fire Fighting Measures FLASHPOINT AND METHOD: (1°F) FLAMMABLE LIMITS: 0.026 to 0.128 AUTOIGNITION TEMPERATURE: No data available. EXTINGUISHING MEDIA: Use water fog, "alcohol" foam, dry chemical, or CO2. HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide and unidentified organic compounds may be formed during combustion. EXPLOSION HAZARDS: When heated above the flash point, this material emits flammable vapors which, when mixed with air, can burn or be explosive. Fine mists or sprays may be flammable at temperatures below the flash point. FIRE FIGHTING PROCEDURES: WARNING! Flammable Liquid. Clear fire area of unprotected personnel. Do not enter confined fire space without full bunker gear, including a positive pressure NIOSH approved SCBA. Cool fire exposed containers with water. 6. Accidental Release Measures ENVIRONMENTAL PRECAUTIONS WATER SPILL: Keep material out of storm sewers and ditches which lead to waterways. GENERAL PROCEDURES: WARNING. Flammable. Ventilate area of leak or spill. Remove all sources of ignition. Clean-up personnel require protective clothing and respiratory protection from vapors. Only specially trained or qualified personnel should handle the emergency. 7. Handling and Storage GENERAL PROCEDURES: Keep away from heat, sparks, and flame. Surfaces that are hot may ignite even liquid product in the absence of sparks or flame. Extinguish pilot lights, cigarettes and turn off other sources of ignition prior to use and until all vapors are gone. COMMENTS: KEEP OUT OF REACH OF CHILDREN! Empty containers retain product residue (liquid and/or vapor) and can be dangerous. Do not pressurize, cut weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks static electricity, or other sources of ignition; they may explode and cause injury or death. 8. Exposure Controls / Personal Protection EXPOSURE GUIDELINES OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200) EXPOSURE LIMITS OSHA PEL ACGIH TLV Chemical Name ppm mg/m3 ppm mg/m3 Acetone TWA 1000 2400 500 - STEL - - 750 - ENGINEERING CONTROLS: Provide exhaust ventilation sufficient to keep the airborne concentration of this product below its exposure limits. Exhaust air may need to be cleaned by scrubbers or filters to reduce environmental contamination. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: Use chemical safety goggles and/or full face shield where splashing is possible. Acetone – 203D - 3 - 12/29/10 Contact lenses should not be worn when working with this material. Maintain eye wash fountain and quick-drench facilities in work areas. SKIN: Wear resistant gloves (consult your safety equipment supplier). To prevent repeated or prolonged skin contact, wear impervious clothing and boots. RESPIRATORY: If exposure may or does exceed occupational exposure limits (Sec. 8) use a NIOSH approved respirator to prevent overexposure. In accord with 29 CFR 1910.134 use either an atmospheresuppling respirator or an air-purifying respirator for organic vapors. WORK HYGIENIC PRACTICES: Use good personal hygiene when handling this product. Wash hands after use, before eating, drinking, smoking, or using the toilet. OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. COMMENTS: May be harmful or fatal if swallowed. May irritate body tissues. Use with adequate ACETONE Page 3 of 6 ventilation. Avoid breathing vapor. Do not get in eyes, on skin, on clothing. Wash thoroughly after handling. 9. Physical and Chemical Properties PHYSICAL STATE: Liquid ODOR: Fragrant odor. COLOR: Clear, colorless liquid. pH: NA = Not Applicable PERCENT VOLATILE: 100 VAPOR PRESSURE: 180 mmHg at (68°F) VAPOR DENSITY: 99 BOILING POINT: (133°F) to (133°F) FREEZING POINT: (-140°F) MELTING POINT: No data available. FLASHPOINT AND METHOD: (1°F) SOLUBILITY IN WATER: Soluble in most organic solvents, slightly soluble with water. EVAPORATION RATE: Faster than Butyl Acetate. DENSITY: 6.59 SPECIFIC GRAVITY: 0.790 to 0.797 MOLECULAR WEIGHT: 58.1 10. Stability and Reactivity STABLE: Yes HAZARDOUS POLYMERIZATION: No POLYMERIZATION: Avoid heat, flame, and other sources of ignition. CONDITIONS TO AVOID: Avoid heat, sparks, flame and contact with strong oxidizing agents. Prevent vapor accumulation. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and unidentified organic compounds may be formed during combustion. INCOMPATIBLE MATERIALS: Strong oxidizers. 11. Toxicological Information GENERAL COMMENTS: None identified. 12. Ecological Information ECOTOXICOLOGICAL INFORMATION: Keep out of waterways. Acetone – 203D - 4 - 12/29/10 13. Disposal Considerations DISPOSAL METHOD: The preferred options for disposal are to send to licensed reclaimers, or to permitted incinerators. Any disposal practice must be in compliance with federal, state, and local regulations. Do not dump into sewers, ground, or any body of water. EMPTY CONTAINER: KEEP OUT OF REACH OF CHILDREN! Empty containers retain product residue and can be dangerous. Do not pressurize, cut weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks static electricity, or other sources of ignition. RCRA/EPA WASTE INFORMATION: Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. 14. Transport Information DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Acetone PRIMARY HAZARD CLASS/DIVISION: 3 UN/NA NUMBER: UN 1090 PACKING GROUP: II NAERG: 127 LABEL: Flammable liquid 15. Regulatory Information UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) 311/312 HAZARD CATEGORIES: This product should be reported as an immediate (acute) health hazard, delayed (chronic) health hazard, and a fire hazard. FIRE: Yes PRESSURE GENERATING: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes 313 REPORTABLE INGREDIENTS: To the best of our knowledge, this product is not listed as a toxic chemical. 302/304 EMERGENCY PLANNING EMERGENCY PLAN: To the best of our knowledge, this product is not listed as an extremely hazardous substance. 16. Other Information HMIS Rating: Health – 1 / Flammability – 3 / Physical Hazard – 0 / Personal Protection – G NFPA CODES – 1 / 3 / 0 Preparation Date: 12-19-10 Prepared by: Fiberlay Inc Comments: This Material Safety Data Sheet was prepared using information provided by __, Fiberlay Inc, and CCINFO Manufacturer Disclaimer: this information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of Fiberlay, Inc. The data on this sheet relates only to the specific materials designated herein. Fiberlay Inc., assumes no legal responsibility for use or reliance upon this data. Revisions: None Monthly Calculations Raw Data February 2023 to January 2024 Gel Coat 18,370.00 [lb] Resin 19,771.25 [gal] Mold Prep 26.00 [gal] Acetone 7,168.00 [lb] Form 13 ~ Spray Booth Gel Coat HAP HAP VOC VOC EMF % Component [lb] [lb] [ton] [lb] [ton] 0.445 0.39 18,370.00 3,188.11 1.59 3,188.11 1.59 0.03 0.04 18,370.00 22.04 0.01 22.04 0.01 Form 2 Mixing / Pouring Resin HAP HAP VOC VOC EMF % Component [lb] [lb] [ton] [lb] [ton] 0.02 0.315 19,771.25 124.56 0.06 124.56 0.06 Form 2 Mold Prep TR-210 HAP HAP VOC VOC EMF % Component [lb] [lb] [ton] [lb] [ton] 1 0.75 187.20 140.40 0.07 140.40 0.07 Xylene 1 0.0245 187.20 4.59 0.00 4.59 0.00 1 0.0175 187.20 3.28 0.00 3.28 0.00 Acetone HAP HAP VOC VOC EMF % Component [lb] [lb] [ton] [lb] [ton] Acetone 1 1 7168 - - 7168 3.58 Calculated monthly 12 month period calculations 3,312.7 lb / 12 month period 22.0 lb / 12 month period Toluene 140.4 lb / 12 month period Permitted Quantities 17,900.0 lb / 12 month period 80.0 lb / 12 month period Toluene 280.0 lb / 12 month period Styrene Methyl Methacrylate Styrene Toulene Cumene Styrene Methyl Methacrylate Styrene Methyl Methacrylate Monthly Calculations Raw Data February 2023 to January 2024 Gel Coat 18,370.00 [lb] Resin 158,170.00 [lb] Mold Prep 26.00 [gal] Acetone 7,168.00 [lb] Form 13 ~ Spray Booth Gel Coat HAP HAP VOC VOC EMF % Component [lb][lb][ton][lb][ton] Styrene 0.445 0.39 18,370.00 3,188.11 1.59 3,188.11 1.59 Methyl Methacrylate 0.03 0.04 18,370.00 22.04 0.01 22.04 0.01 Form 2 Mixing / Pouring Resin HAP HAP VOC VOC EMF % Component [lb][lb][ton][lb][ton] Styrene 0.02 0.315 158,170.00 996.47 0.50 996.47 0.50 Form 2 Mold Prep TR-210 HAP HAP VOC VOC EMF % Component [lb][lb][ton][lb][ton] Toulene 1 0.75 187.20 140.40 0.07 140.40 0.07 Xylene 1 0.0245 187.20 4.59 0.00 4.59 0.00 Cumene 1 0.0175 187.20 3.28 0.00 3.28 0.00 Acetone HAP HAP VOC VOC EMF % Component [lb][lb][ton][lb][ton] Acetone 1 1 7168 --7168 3.58 Calculated monthly 12 month period calculations Styrene 4,184.6 lb / 12 month period Methyl Methacrylate 22.0 lb / 12 month period Toluene 140.4 lb / 12 month period Permitted Quantities Styrene 17,900.0 lb / 12 month period Methyl Methacrylate 80.0 lb / 12 month period Toluene 280.0 lb / 12 month period Monthly Calculations Jan-16 to Dec-16 Composites One HKRLHA2900 Resin [lb] LOW HAP WHITE MEKP 925 TR 210 (Normal)GEL COAT [lb][lb][gl]Acetone [lb] Feb-23 9600 2.0 Mar-23 9600 2.0 Apr-23 12000 2.0 May-23 9600 2.0 Jun-23 9600 2.0 Jul-23 16800 2.0 Aug-23 7200 3.0 Sep-23 14400 2.0 Oct-23 14400 2.0 Nov-23 22000 2.0 Dec-23 2500 2.0 Jan-24 12100 3.0 Subtotal 139800 0.0 0.0 26.0 0.0 Fiberlay HKRLA1503 980 MEKP LOW HAP CLEAR Catalyst GEL COAT [lb]Acetone [lb] Feb-23 716 Mar-23 Apr-23 1074 May-23 724 Jun-23 716 Jul-23 716 Aug-23 1074 Sep-23 Oct-23 1074 Nov-23 Dec-23 1074 Jan-24 Subtotal 0.0 0.0 7168.0 North American HKRLA1503 LOW HAP CLEAR GEL COAT Feb-23 1570 Mar-23 550 Apr-23 2120 May-23 2120 Jun-23 1100 Jul-23 1020 Aug-23 3140 Sep-23 470 Oct-23 2040 Nov-23 550 Dec-23 1570 Jan-24 2120 Subtotal 18370.0 Total Resin [lb]158170.0 Total Gel Coat [lb]18370.0 Total Mold Prep [gal] 26 Acetone [lb] 7168