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Home My WebLink AboutDAQ-2024-0074571 DAQC-331-24 Site ID 15513 (B4) MEMORANDUM TO: STACK TEST FILE – CITATION OIL & GAS CORPORATION – Pineview Gas Plant THROUGH: Rik Ombach, Minor Source Oil and Gas Compliance Section Manager FROM: Kyle Greenberg, Environmental Scientist DATE: April 11, 2024 SUBJECT: Sources: Engine 1: White Superior 8G825; SN: 270349 Contact: Robert J. Redweik: 281-891-1000 Location: Summit County, UT Test Contractor: Oasis Emissions Consultants Permit/AO#: DAQE-AN155130002-22, dated August 15, 2022 Action Code: TR Subject: Review of stack test report dated January 22, 2024 On January 26, 2024, DAQ received a test report for the above listed unit. Testing was performed December 13, 2023, to demonstrate compliance with the emission limits found in condition II.B.6 of DAQE-AN155130002-22 and 40 CFR Part 63, Subpart ZZZZ. The calculated test results are: Source Test Date Test Methods Pollutants Tester Results DAQ Results Limits ENG 1 Dec. 13, 2023 10 CO 50.25 ppm@15%O2 0.39 lb/hr 50.251 ppm@15%O2 0.387 lb/hr 270 ppm@15%O2 1.022 lb/hr 7E NOx 0.07 lb/hr 0.074 lb/hr 0.661 lb/hr DEVIATIONS: None. CONCLUSION: The stack test report appears to be acceptable. RECOMMENDATION: The emissions from ENG 1 should be considered to have been in compliance with the emission limits of the AO and 40 CFR Part 63, Subpart ZZZZ during the time of testing. HPV: None. ATTACHMENTS: DAQ stack test review spreadsheets; Citation Oil & Gas Corporation stack test report. Emissions Citation Oil & Gas Corporation Pineview Tank Battery and Gas Plant Summit County, Utah Engine 1: White Superior 8G825; SN: 270349 Test Date: 12/13/2023 Run #1 2 3 Average Start Time 7:32 8:32 9:33 Stop Time 8:32 9:32 10:33 Sample Duration (minutes) 60 60 60 BHP Engine Load - Actual (bhp) 550 550 550 550 DS Stack Diameter (inches) 10.0 10.0 10.0 10.0 PAVG Average (Delta P)½ (" H2O)½0.6450 0.5870 0.5950 0.6090 CP Pitot Tube Constant (unitless) 0.84 0.84 0.84 0.84 TS Stack Temperature (°F) 1101 1101 1106 1103 Pbar Barometric Pressure (" Hg) 23.75 23.75 23.75 23.75 Ps Stack Pressure ('' H2O)0.26 0.24 0.23 0.24 O2%vd O2 (%vd)0.0 0.0 0.0 0.0 CO2%vd CO2 (%vd)10.9 11.1 11.1 11.0 N2%vd N2 (%vd)89.1 88.9 88.9 89.0 dry NOX (ppmvd)19.8 21.1 21.9 20.9 dry CO (ppmvd) 216.9 160.1 157.0 178.0 Run #1 2 3 Average Bws Measured Moisture Content (%/100) 0.155 0.164 0.158 0.159 Bws Saturated Moisture Content (%/100) 1434.451 1434.540 1457.336 1442.109 Bws Actual Moisture Content (%/100) 0.155 0.164 0.158 0.159 MD Molecular Weight Dry (lb/lb-mole) 29.74 29.78 29.78 29.77 MA Molecular Weight Wet (lb/lb-mole) 27.92 27.85 27.92 27.90 VS Gas Velocity (ft/sec) 71.0 64.7 65.6 67.1 FACFM Gas Flow (acfm) 2325 2119 2148 2197 FDSCFM Gas Flow (dscfm) 527 476 484 496 FWSCFM Gas Flow (wscfm) 625 569 575 590 FKWSCFH Gas Flow (kwscfh) 37 34 35 35 FKWSCFM Gas Flow (kwscfm) 1 1 1 1 lb/hr Gas Flow (lb/hr) 2716 2468 2501 2562 Fo Fo (unitless)1.917 1.883 1.883 1.894 wet O2 (%vw)0.0 0.0 0.0 0.0 wet CO2 (%vw)9.2 9.3 9.4 9.3 wet NOX (ppmvw)16.710 17.619 18.415 17.581 15 NOX (ppmvd @ 15% O2)5.584 5.948 6.171 5.901 lb/hr NOX (lb/hr)0.075 0.072 0.076 0.074 0.661 g/bhp-hr NOX (g/bhp-hr)0.062 0.059 0.062 0.061 wet CO (ppmvw) 183.237 133.892 132.257 149.795 15 CO (ppmvd @ 15% O2)61.230 45.201 44.321 50.251 270.0 lb/hr CO (lb/hr) 0.498 0.332 0.331 0.387 1.022 g/bhp-hr CO (g/bhp-hr) 0.411 0.274 0.273 0.319 Permit Limits Field Reference Method Data Reference Method Calculations Page 1 of 1 January 22, 2024 Ms. Alexis North Via E-Mail: R8AirReportEnforcement@epa.gov Office of Enforcement US EPA Region 8 8ENT-AT 1595 Wynkoop Street Denver, CO 80202-1129 Mr. Rik Ombach Via Website: https://utahgov.col.qualtrics.com/jfe/form/SV_3dSxf7JSzy4jwGh Minor Source Compliance Manager Minor Source Completion Section P.O. Box 144820 Salt Lake City, UT 84114-4820 RE: NESHAP ZZZZ & UDEQ DAQ ENGINE EMISSION TEST RESULTS SUBMITTAL CITATION OIL & GAS CORP. PINEVIEW TANK BATTERY AND GAS PLANT (PERMIT #DAQE-AN155130002-22) SUMMIT COUNTY, UTAH Dear Ms. North and Mr. Ombach: Further to our NESHAP ZZZZ and UDEQ DAQ Test Notification and Protocol submittal dated October 12, 2023, Citation Oil & Gas Corp. (Citation) hereby confirms that Oasis Emission Consultants, Inc. (Oasis) has successfully completed compliance emission testing on one (1) 800 horsepower White Superior 8G825 engine located at Citation’s Pineview Tank Battery and Gas Plant near Coalville in Summit County, Utah. On December 13, 2023, compliance emission testing was conducted on ENG-1 (North) and the average NOX and CO levels recorded were found to comply with the emission levels stipulated by the permit and EPA 40 CFR 63, Subpart ZZZZ. A copy of the test report is included in Attachment A. Additionally, a copy of the Notice of Intent/Test Protocol is included as Attachment B. As stated in the Source Test Notification and Protocol Submission, two (2) additional 800 hp White Superior compressor engines (ENG 2 and Recip (South)) are located as this site but are currently out of service or are inoperable at this time. Therefore, emission testing for these two enignes was not performed. If Citation decides to bring these engines back into service, performance testing will be conducted prior to operation. Per the permit and Subpart ZZZZ, subsequent engine testing/compliance demonstrations will be conducted on an annual basis. However, as mentioned in previous correspondence, Citation continues to maintain that these three (3) engines meet the definition of “Remote Stationary RICE” and are not subject to performance test requirements set forth in Subpart ZZZZ. Page 2 of 2 Engine Emission Test Results Pineview Tank Battery and Gas Plant January 22, 2024 If you have any questions or require further information, please contact me at (281) 891-1550 or via e-mail at BRedweik@cogc.com Very truly yours, RJ Redweik Robert J. Redweik VP – EHS and Regulatory Attachments: A – Test Report B – Notice of Intent and Test Protocol C - Correspondence cc: Mr. Rik Ombach, Utah Division of Air Quality, rombach@utah.gov Ms. Alexis North, EPA Region 8, north.alexis@epa.gov ATTACHMENT A Test Report Source Test Report For Citation Oil & Gas Corporation Pineview Tank Battery and Gas Plant Summit County, Utah Test Date: December 13, 2023 Report Date: December 19, 2023 Approval Order: DAQE-AN155130002-22 Engine: White Superior 8G825 SN: 270349 Unit ID: ENG1 (North) Prepared By: Oasis Emission Consultants, Inc. 2730 Commercial Way Rock Springs, WY 82901 December 19, 2023 Mr. Ron Schultz Citation Oil & Gas Corporation 14077 Cutten Road Houston, TX 77069 Dear Mr. Schultz: Re: Engine Emission Testing For Citation Oil & Gas Corporation, Pineview Tank Battery and Gas Plant, Unit ENG1 (North), Approval Order DAQE- AN155130002-22. An air emissions test program was conducted on a White Superior 8G825 engine, operated by Citation Oil & Gas Corporation and designated as Unit ENG1 (North), located at the Pineview Tank Battery and Gas Plant in Summit County, Utah. The purpose of the testing was to demonstrate ongoing compliance with the emissions limits contained in Approval Order DAQE-AN155130002-22 and EPA 40 CFR 63, Subpart ZZZZ, for oxides of nitrogen (NOx) and carbon monoxide (CO). Oasis Emission Consultants, Inc. conducted the testing on December 13, 2023. Approval Oder #DAQE-AN155130002-22 and EPA 40 CFR 63, Subpart ZZZZ Emission Levels The average recorded levels were found to comply with emission levels stipulated in the permit, as shown in the attached report and summarized below. Emission Unit Avg NOx Permit NOx Avg CO Permit CO lbs/hr 0.07 0.661 0.39 1.022 ppmvd@15% O2 5.90 --50.25 270 Catalyst Parameters (Averaged Over 3 Test Runs) Inlet Temp (deg F)DP (in H2O) 1069 N/A Engine Load (Averaged Over 3 Test Runs) Rated BHP Operating BHP % Load 800 550.0 68.8 Testing Protocol The attached report was generated using an extractive FTIR system using methodologies as required by and in accordance with EPA 40 CFR 60(A) Methods 1-3 and EPA 40 CFR 63(A), Method 320, as well as EPA 40 CFR 63, Subpart ZZZZ as outlined in the submitted Source Test Protocol. Quality Assurance Oasis has performed a full review of the raw data and calculated results in this report. Any errors we have encountered have been listed in the body of this report. After performing the review, we are confident that this engine has met all requirements. If you have any questions or require further information, please contact the undersigned at (307) 382-3297. Yours truly, Oasis Emission Consultants, Inc. ________________________________________________ Charles A. Chapman Cember Crawley Manager of Technical Services Environmental Scientist _________________________ Christopher N. Knott, P.Eng. Director, Engineering and Operations SOURCE EMISSION TEST REPORT UDEQ Approval Order #DAQE-AN155130002-22 Test Performed By:Oasis Emission Consultants, Inc. Test Company Contact:Chris Knott 2730 Commercial Way Rock Springs, WY 82901 307.382.3297 Owner/Operator:Citation Oil & Gas Corporation Owner/Operator Contact: Mr. Ron Schultz Facility Name:Pineview Tank Battery and Gas Plant UTM Coordinates: 487,342 m Easting, 4,531,757, m Northing, UTM Zone 12 Summit County, Utah Emission Source:White Superior 8G825 Unit: ENG1 (North) Date of Test:December 13, 2023 Date of Report:December 19, 2023 TABLE OF CONTENTS 1.1 Introduction ..................................................................................................................... 1 2.1 Stack Sampling Location ................................................................................................. 2 3.1 Discussion of NOx and CO Test Results .......................................................................... 4 3.1.1 Source Test 1 ...................................................................................................................................... 4 3.1.2 Source Test 2 ...................................................................................................................................... 4 3.1.3 Source Test 3 ...................................................................................................................................... 4 4.1 Stack Sampling Methods and Procedures ........................................................................ 5 4.2 Equipment Utilization ..................................................................................................... 6 4.3 Process Parameters .......................................................................................................... 7 5.1 Quality Assurance ........................................................................................................... 8 List of Tables and Figures Figure 1 - Sample Port Location ....................................................................................................................... 2 Figure 2 - Sampling Train Schematic – Method 320 .......................................................................................... 6 Table 1 – Insertion Depths of Traverse Points for Stratification Test .................................................................. 2 Table 2 – Location of Traverse Points in Circular Stacks ................................................................................... 3 Table 3 - Test Matrix ........................................................................................................................................ 5 Table 4 - Concentrations and Interference………………………………………………………………………...6 APPENDIX A:NOx and CO Test Data APPENDIX B:Quality Assurance/Calibration Data APPENDIX C:Load Approximation APPENDIX D:Example Calculations and Summary APPENDIX E:Field Notes 1 1.1 Introduction An air emissions test program was conducted on a White Superior 8G825 engine, operated by Citation Oil & Gas Corporation and designated as Unit ENG1 (North), located at the Pineview Tank Battery and Gas Plant in Summit County, Utah. The purpose of the testing was to demonstrate ongoing compliance with the emissions limits contained in Approval Order DAQE-AN155130002-22 and EPA 40 CFR 63, Subpart ZZZZ, for oxides of nitrogen (NOx) and carbon monoxide (CO). The facility is located at 3604 East Chalk Creek Road in Coalville, in Summit County, Utah. UTM Coordinates: 487,342 m Easting, 4,531,757 m Northing, UTM Zone 12 Three one hour test runs were performed on December 13, 2023 to analyze NOx and CO emission levels. Test runs were performed according to methodologies outlined by EPA 40 CFR 60(A) Methods 1-3, EPA 40 CFR (A), Method 320, as well as EPA 40 CFR 63, Subpart ZZZZ. Each one hour test run consisted of 60 readings taken at one minute intervals. Process parameters were recorded during each test run in order to determine the load. Parameters include the engine RPM and intake manifold pressure. The following key personnel were present during testing: Jordan Nix - Compliance Specialist, OEC David Martinez - Compliance Specialist, OEC Jeremy, Citation Oil & Gas Corporation 2 2.1 Stack Sampling Location The facility is located at 3604 East Chalk Creek Road in Coalville, in Summit County, Utah. UTM Coordinates: 487,342 m Easting, 4,531,757 m Northing, UTM Zone 12 Testing was conducted on the White Superior 8G825 engine. The sampling port for moisture, NOx and CO measurements was approximately 0.5 pipe diameters (5”) downstream from the nearest flow disturbance (Distance B) and 2.4 pipe diameters (24”) upstream from the nearest disturbance (Distance A), as seen in Figure 1. The stack sampling location was placed at approximately 50% insertion depth based on an O2 stratification check which demonstrated a non-stratified flow regime. The stratification was conducted according to EPA 40 CFR 75(A), §6.5.6.1 using 3 traverse points determined according to Table 1 below. In accordance with EPA 40 CFR 60(A), Method 1, a total of 16 traverse insertion depths (8 traverse points through each of the 2 ports) were determined according to Table 2 below in order to conduct Method 2. Figure 1 - Sample Port Location Table 1 – Insertion Depths of Traverse Points for Stratification Test Traverse Point Insertion Depth (Percent of Stack Diameter) 1 16.6 2 50.0 3 83.3 10" A B 3 Table 2 – Location of Traverse Points in Circular Stacks 4 3.1 Discussion of NOx and CO Test Results Three, one hour test runs were performed on December 13, 2023 to analyze exhaust NOx and CO emission levels to demonstrate ongoing compliance with the emissions limits contained in the Approval Order #DAQE-AN155130002-22. Testing for NOx and CO were run concurrently with one another. Each test was performed at the maximum achievable load. Measured emissions were below permitted limits. Please refer to the Appendices for a listing of all raw data, calibration error response and calculations performed per EPA 40 CFR 60(A) requirements. 3.1.1 Source Test 1: White Superior 8G825, NOx and CO The first test was performed from 7:32 to 8:31 for NOx and CO. Based on operating parameters recorded during testing, the load was approximated at 550.0 bhp, and the average NOx and CO levels were found to be 0.07 lbs/hr and 0.50 lbs/hr respectively, below limitations. 3.1.2 Source Test 2: White Superior 8G825, NOx and CO The second test was performed from 8:32 to 9:32 for NOx and CO. Based on operating parameters recorded during testing, the load was approximated at 550.0 bhp, and the average NOx and CO levels were found to be 0.07 lbs/hr and 0.33 lbs/hr respectively, below limitations. 3.1.3 Source Test 3: White Superior 8G825, NOx and CO The third test was performed from 9:33 to 10:32 for NOx and CO. Based on operating parameters recorded during testing, the load was approximated at 550.0 bhp, and the average NOx and CO levels were found to be 0.08 lbs/hr and 0.33 lbs/hr respectively, below limitations. Test Run NOx (ppmvd) NOx (lbs/hr) CO (ppmvd) CO (lbs/hr) O2 (%) 1 19.78 0.07 216.90 0.50 0.0 Test Run NOx (ppmvd) NOx (lbs/hr) CO (ppmvd) CO (lbs/hr) O2 (%) 2 21.07 0.07 160.12 0.33 0.0 Test Run NOx (ppmvd) NOx (lbs/hr) CO (ppmvd) CO (lbs/hr) O2 (%) 3 21.86 0.08 157.00 0.33 0.0 5 4.1 Stack Sampling Methods and Procedures Testing followed EPA 40 CFR 60(A) Methods 1-3 & EPA 40 CFR 63(A), Method 320, methodologies per our standard protocol, with no exceptions. Table 3 - Test Matrix Method Title Parameter Reference EPA 40 CFR 60 Appendix A, Method 1 Sample and Velocity Traverses for Stationary Sources Sampling Point Determination https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_1_3.pdf EPA 40 CFR 60 Appendix A, Method 2 Determination of Stack Gas Velocity and Volumetric Flow Rate Exhaust Effluent Flow https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_2.pdf EPA 40 CFR 60 Appendix A, Method 3 Gas Analysis for the Determination of Dry Molecular Weight O2, Dry Volumetric Flow Rate https://www.epa.gov/ sites/production/files/ 2017- 08/documents/metho d_3.pdf EPA 40 CFR 63(A), Method 320 Vapor Phase Organic and Inorganic Emissions by Extractive FTIR Nitrogen Oxides, Carbon Dioxide https://www.epa.gov/ sites/production/files/ 2019- 06/documents/metho d_320.pdf United States. U.S. Environmental Protection Agency. “EMC Promulgated Test Methods.” Air Emission Measurement Center (EMC). 22 February 2021. Web. 23 February 2023. <https://www.epa.gov/emc/emc-promulgated-test-methods>. 6 4.2 Equipment Utilization The following equipment was used during the tests performed at this facility in conjunction with procedures outlined by EPA 40 CFR 60(A) Methods 1-3, EPA 40 CFR 63(A), Method 320, as well as EPA 40 CFR 63, Subpart ZZZZ. • (1) MKS MultiGas 2030 FTIR Continuous Gas Analyzer (0.210 L/min sample flow, 0.014 atmosphere sample pressure, 1 atmosphere cell pressure, 191°C cell temperature) •(1) Laptop Computer for the FTIR Analyzer using MKS MG2000 Software • (1) 75ft or 100ft Heated Teflon Line w/ Heated Sample Probe and Spike Bypass Line •S-Type Pitot Tube c/w 20 ft. Heated Sample Line (coefficient 0.84) • (1) Fyrite O2/CO2 Analyzer •(5) EPA Protocol G1 Calibration Gas (NOx, CO, C3H8, C2H4 and NO2) The MKS Multigas 2030 FTIR Analyzer operated with a spectral resolution of 0.5 cm-1 and a scan time of 30 seconds. The FTIR spectrometer utilizes a multi-pass gas cell with a 5.11 meter effective pathlength. Figure 2 - Sampling Train Schematic – Method 320 Table 4 - Concentrations and Interference 7 The MKS 2030 software provides a Natural Gas Method that is designed to minimize all expected interferences by removing the regions in the quant region where they are most absorbed (i.e. picket fence approach). So, for example, all the water peaks that are greater than about 0.1 abs are removed from the quant region. Since the spectral noise measured (sample spectrum) is in the range of 0.001 absorbance, it is desirable to have any error within this range. The MKS software will match the water calibration spectrum to the sample spectrum at any 1 point in the spectrum to about 1% precision. So, 1% of 0.1 absorbance is 0.001 abs. This is why any peaks greater than this for interfering compounds are usually excluded so they do not interfere. To summarize, the MKS software and the method are designed to minimize any interferences by removing their largest interfering absorptions. 4.3 Process Parameters The engine operating parameters were used in order to determine the load. Parameters include the engine RPM and intake manifold pressure. Results are provided in Appendix C. 8 5.1 Quality Assurance The MKS Multigas 2030 FTIR Analyzer was used to measure NOx and CO on a dry basis. A pre Direct and System calibration measurement was made on compounds of NOx, CO, C3H8 and C2H4. In addition, post System calibrations were made on compounds of NOx, CO, C3H8 and C2H4. Compounds of CO2 and C3H8 were measured for the quality assurance spiking requirements of Method 320. Levels for calibrations and zeroes must be within +/- 5% of the certified calibration gas or response to zero gas, respectively. CTS procedures were followed according to EPA requirements for both pre and post testing. Similarly, QA spiking procedures were followed. Analysis of the CO2 exhaust effluent was used to determine the dilution factor. Steady levels of the CO2 were observed and a sufficient duration of time was allowed to elapse for a representative average. The calibration gas was spiked into the effluent stream using a bypass line at approximately 10% of the sampling rate. The dilution factor was obtained from observation of the stack CO2 behavior using the following equation: CO2AVG – CO2SPIKE DF = ------------------------ CO2 AVG Where:CO2AVG = The average undiluted CO2 stack gas concentration of spike measurements CO2SPIKE = The average diluted CO2 stack gas concentration when spiked The sample recovery was then obtained from the following equation: % REC = (Spike MEAS – Stack MEAS)* (1 – DF) --------------------------------------------------------- CS * DF Where:Spike MEAS = The average diluted stack gas concentration when spiked Stack MEAS = The average undiluted stack gas concentration DF = Dilution factor CS = Certified concentration of calibration standards The Sample Recovery average level for C3H8 was found to be 85.6%, which was within the allowable tolerance of Method 320 (70% to 130%). A summary of all spiking procedures/results can be found in Appendix B. APPENDIX A NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) H2O% (High) 191C Time 1 19.217691 0.709141 19.926832 288.837811 12.533606 7:32:39 12-13-2023 2 17.306686 0.635781 17.942467 115.339346 11.624468 7:33:39 12-13-2023 3 18.119672 0.630771 18.750442 45.443001 16.056267 7:34:39 12-13-2023 4 26.902741 0.972432 27.875173 40.494662 16.743383 7:35:40 12-13-2023 5 16.365911 0.846092 17.212003 63.320123 15.013782 7:36:40 12-13-2023 6 16.156817 0.728591 16.885408 92.794045 18.408775 7:37:40 12-13-2023 7 17.699633 0.810787 18.510419 247.116801 13.874774 7:38:40 12-13-2023 8 20.511754 0.683762 21.195517 454.911185 11.69699 7:39:40 12-13-2023 9 20.53308 0.693074 21.226153 167.253465 11.618636 7:40:41 12-13-2023 10 18.768103 0.843343 19.611446 145.595603 14.970189 7:41:41 12-13-2023 11 18.209895 0.739274 18.949169 104.112326 13.145159 7:42:41 12-13-2023 12 17.233204 0.72943 17.962635 138.88202 11.862177 7:43:41 12-13-2023 13 19.577867 0.707664 20.285531 396.441999 13.741033 7:44:41 12-13-2023 14 21.201776 0.725099 21.926874 442.949301 13.561451 7:45:41 12-13-2023 15 23.869346 0.666231 24.535577 543.21205 12.122698 7:46:42 12-13-2023 16 17.544247 3.667034 21.211281 135.14039 49.585106 7:47:42 12-13-2023 17 17.556058 1.087979 18.644037 89.500888 18.689955 7:48:42 12-13-2023 18 17.107382 0.755713 17.863095 64.244428 13.209659 7:49:42 12-13-2023 19 17.94971 0.628723 18.578434 45.438403 10.722259 7:50:42 12-13-2023 20 20.811008 0.572168 21.383176 38.018357 9.749324 7:51:43 12-13-2023 21 17.045329 0.54556 17.590889 36.524857 8.854685 7:52:43 12-13-2023 22 14.387772 0.529077 14.916849 49.404193 8.593203 7:53:43 12-13-2023 23 14.285596 0.535571 14.821167 82.160952 8.922081 7:54:43 12-13-2023 24 14.717359 0.626837 15.344196 82.860136 11.237308 7:55:43 12-13-2023 25 16.959936 0.607779 17.567715 59.966302 10.124955 7:56:43 12-13-2023 26 15.48201 0.807433 16.289442 48.340082 17.009925 7:57:44 12-13-2023 27 11.922563 2.097192 14.019756 106.381147 36.973454 7:58:44 12-13-2023 28 16.350114 1.604983 17.955098 113.44306 21.308792 7:59:44 12-13-2023 29 16.686675 1.010602 17.697277 156.439482 16.943889 8:00:44 12-13-2023 30 18.310615 0.992522 19.303137 216.104153 17.049778 8:01:44 12-13-2023 31 18.658071 0.776023 19.434094 276.341744 13.128877 8:02:44 12-13-2023 32 19.252404 0.791168 20.043573 171.027367 13.793305 8:03:45 12-13-2023 33 17.304913 0.74436 18.049273 96.435126 12.633036 8:04:45 12-13-2023 34 16.478066 0.789044 17.26711 69.181534 13.462787 8:05:45 12-13-2023 35 17.968578 0.748453 18.717032 51.858725 13.106425 8:06:45 12-13-2023 36 17.060588 0.75499 17.815578 44.241477 13.339334 8:07:45 12-13-2023 37 15.950309 0.78755 16.737859 54.394737 13.604379 8:08:46 12-13-2023 38 16.313775 0.866262 17.180037 58.590436 15.117699 8:09:46 12-13-2023 39 15.403249 0.84569 16.248939 60.537388 14.609023 8:10:46 12-13-2023 40 16.049416 0.897777 16.947194 78.238231 16.08102 8:11:46 12-13-2023 41 16.134858 0.881729 17.016587 76.857581 14.951767 8:12:46 12-13-2023 42 17.225651 1.031261 18.256912 73.301258 16.272477 8:13:46 12-13-2023 43 17.051926 0.962583 18.014509 209.837212 15.849651 8:14:47 12-13-2023 44 20.272976 0.888249 21.161224 516.834298 15.651711 8:15:47 12-13-2023 45 14.288432 7.3139 21.602332 444.672946 51.178528 8:16:47 12-13-2023 46 22.684113 1.771646 24.455759 378.69881 22.619497 8:17:47 12-13-2023 47 21.105103 0.988673 22.093776 250.390958 21.283192 8:18:47 12-13-2023 48 19.733768 0.764298 20.498066 262.259119 18.488074 8:19:47 12-13-2023 49 20.5323 1.178867 21.711167 280.783158 17.247054 8:20:48 12-13-2023 50 20.289042 0.883293 21.172335 268.500061 15.15036 8:21:48 12-13-2023 51 22.117185 0.970064 23.087249 110.468928 15.332502 8:22:48 12-13-2023 52 17.65585 0.746107 18.401957 81.209259 13.634825 8:23:48 12-13-2023 53 18.506613 0.760945 19.267558 230.953407 12.857438 8:24:48 12-13-2023 54 22.009875 0.610099 22.619974 578.37087 10.35351 8:25:48 12-13-2023 55 23.749159 0.643804 24.392963 445.74557 10.199642 8:26:49 12-13-2023 56 22.477586 0.667886 23.145472 286.180444 10.459979 8:27:49 12-13-2023 57 19.331093 0.629343 19.960436 163.455441 10.43173 8:28:49 12-13-2023 58 21.729281 0.698863 22.428144 513.814505 11.42804 8:29:49 12-13-2023 59 28.679184 0.703206 29.38239 1087.736822 11.733995 8:30:49 12-13-2023 60 32.713369 0.708713 33.422081 1182.148722 11.453875 8:31:50 12-13-2023 AVG 18.79 0.98 19.78 216.90 15.52 ppm@15% O2 5.58 61.23 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) 0.06 0.07 0.41 0.50 Calculated Emission Levels ENG1 (North) FTIR Measurements Citation Oil & Gas Corporation Pineview Tank Battery and Gas Plant Run 1 Record Date EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 10 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 0.33 1560 0.26 0.574 Average O2 0.0 (% dry)A 2 1.05 0.38 0.616 Average CO2 11.5 (% dry)A 3 1.94 0.40 0.632 Average N2 + CO 88.5 (% dry)A 4 3.23 0.39 0.624 Dry Molecular Weight 29.84 lb/lbmol A 5 6.77 0.41 0.640 Wet Molecular Weight 28.00 lb/lbmol A 6 8.06 0.42 0.648 ASTM D6348-03 / EPA REFERENCE METHOD 320 A 7 8.95 0.43 0.656 Barometric Pressure 23.75 in Hg A 8 9.50 0.38 0.616 Moisture Content 15.52 %A 9 ASTM D6348-03 / EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 19.78 ppm A 11 Calculated NOx Mass Output 0.07 lbs/hr A 12 Calculated NOx Output 0.06 g/bhp-hr A 13 ASTM D6348-03 / EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 216.90 ppm A 15 Calculated CO Mass Output 0.50 lbs/hr A 16 Calculated CO Output 0.41 g/bhp-hr B 1 0.50 0.44 1560 0.26 0.663 LOAD APPROXIMATION B 2 1.05 0.45 0.671 Estimated Engine Load 550.0 BHP B 3 1.94 0.47 0.686 B 4 3.23 0.48 0.693 B 5 6.77 0.46 0.678 B 6 8.06 0.43 0.656 B 7 8.95 0.42 0.648 B 8 9.50 0.39 0.624 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 0.4 1560 0.3 0.645 Average Stack Gas Velocity 70.96 ft/sec Average Dry Flowrate 527.48 dscfm TEST RUN # 1 NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) H2O% (High) 191C Time 1 34.123692 0.701063 34.824755 1101.382131 11.355646 8:32:50 12-13-2023 2 32.234938 0.664227 32.899166 863.358224 12.068561 8:33:50 12-13-2023 3 31.273325 0.71383 31.987154 669.346613 22.185826 8:34:50 12-13-2023 4 26.462353 4.147801 30.610154 501.659701 31.005747 8:35:50 12-13-2023 5 26.0773 1.710675 27.787975 440.314849 21.180563 8:36:50 12-13-2023 6 23.715572 1.32211 25.037681 290.264398 18.027025 8:37:51 12-13-2023 7 19.960201 0.946528 20.906729 112.93889 15.098772 8:38:51 12-13-2023 8 17.865851 0.894055 18.759906 128.123242 13.184289 8:39:51 12-13-2023 9 18.83164 0.830771 19.662411 192.998644 13.409191 8:40:51 12-13-2023 10 21.768131 0.872342 22.640473 428.25292 14.053428 8:41:51 12-13-2023 11 23.2759 0.850816 24.126716 362.773212 14.197736 8:42:51 12-13-2023 12 21.154701 0.865625 22.020326 232.880149 14.247537 8:43:52 12-13-2023 13 20.478426 0.806423 21.284848 81.538835 13.040983 8:44:52 12-13-2023 14 18.666493 0.826735 19.493228 52.450329 13.707987 8:45:52 12-13-2023 15 17.610286 0.865067 18.475354 161.480734 13.729449 8:46:52 12-13-2023 16 18.082277 0.923306 19.005583 148.110793 15.747615 8:47:52 12-13-2023 17 18.842591 1.031466 19.874058 157.099915 15.930177 8:48:52 12-13-2023 18 18.124443 0.982969 19.107412 168.104244 15.649731 8:49:53 12-13-2023 19 9.212407 3.291467 12.503874 140.110859 43.967382 8:50:53 12-13-2023 20 20.846668 1.564595 22.411263 64.418126 26.578042 8:51:53 12-13-2023 21 17.592637 1.045911 18.638548 82.140927 16.46515 8:52:53 12-13-2023 22 24.065786 0.739411 24.805197 37.11412 12.281385 8:53:53 12-13-2023 23 26.465083 0.685006 27.150089 36.270685 11.028745 8:54:53 12-13-2023 24 15.215492 0.624374 15.839866 46.571816 10.383163 8:55:54 12-13-2023 25 15.726779 0.638494 16.365273 54.385166 11.195073 8:56:54 12-13-2023 26 15.2306 0.714918 15.945518 66.728607 11.670832 8:57:54 12-13-2023 27 18.791326 0.735228 19.526554 38.361294 11.878699 8:58:54 12-13-2023 28 22.57285 0.712458 23.285309 35.417227 11.605375 8:59:54 12-13-2023 29 19.739374 0.730884 20.470258 33.345494 11.832894 9:00:54 12-13-2023 30 15.675884 0.72313 16.399014 38.868402 11.679127 9:01:55 12-13-2023 31 14.466322 0.698404 15.164725 69.058791 12.00271 9:02:55 12-13-2023 32 15.374175 0.758615 16.13279 109.423736 13.668973 9:03:55 12-13-2023 33 11.099226 0.182838 11.282064 177.203034 37.256315 9:04:55 12-13-2023 34 19.472708 2.337811 21.810519 71.672997 26.014317 9:05:55 12-13-2023 35 18.243339 0.93201 19.175348 60.780033 22.605919 9:06:55 12-13-2023 36 21.704893 0.861711 22.566604 35.285638 15.72427 9:07:56 12-13-2023 37 27.411484 0.776269 28.187753 34.142302 12.735412 9:08:56 12-13-2023 38 27.593958 0.78135 28.375307 33.743053 12.505129 9:09:56 12-13-2023 39 51.468443 0.73795 52.206393 32.205972 12.771905 9:10:56 12-13-2023 40 14.306049 0.832678 15.138728 54.653891 13.08999 9:11:56 12-13-2023 41 15.92643 0.830271 16.756701 125.442052 13.175592 9:12:56 12-13-2023 42 17.224342 0.813203 18.037546 109.257536 13.214736 9:13:57 12-13-2023 43 18.243138 0.808917 19.052055 94.024975 12.799587 9:14:57 12-13-2023 44 17.946974 0.855967 18.802941 98.280647 13.686308 9:15:57 12-13-2023 45 17.711985 0.824334 18.53632 151.058201 13.633044 9:16:57 12-13-2023 46 17.855662 0.785273 18.640935 148.295992 12.946528 9:17:57 12-13-2023 47 17.520545 0.817078 18.337623 176.625621 14.061677 9:18:57 12-13-2023 48 18.771274 0.881447 19.652721 205.677312 14.765261 9:19:58 12-13-2023 49 19.319856 1.021021 20.340876 107.586934 16.308114 9:20:58 12-13-2023 50 19.128721 0.958467 20.087188 43.207682 15.772506 9:21:58 12-13-2023 51 16.577202 0.862347 17.439548 46.069182 15.907092 9:22:58 12-13-2023 52 15.932765 0.934934 16.867699 63.870182 14.912478 9:23:58 12-13-2023 53 16.680592 1.044896 17.725489 77.454503 16.762399 9:24:58 12-13-2023 54 15.375697 0.935074 16.310771 65.90487 19.722586 9:25:59 12-13-2023 55 19.661691 5.68327 25.344961 41.257103 36.475598 9:26:59 12-13-2023 56 19.254966 1.545284 20.80025 36.619132 22.576186 9:27:59 12-13-2023 57 17.990783 1.177097 19.16788 35.644397 18.843575 9:28:59 12-13-2023 58 15.05246 0.789267 15.841728 43.656795 14.115863 9:29:59 12-13-2023 59 15.28201 0.768692 16.050702 158.144281 12.88874 9:30:59 12-13-2023 60 17.677312 0.815267 18.492579 333.9379 13.467146 9:32:00 12-13-2023 AVG 20.00 1.07 21.07 160.12 16.38 ppm@15% O2 5.95 45.20 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) 0.06 0.07 0.27 0.33 Calculated Emission Levels Record Date Citation Oil & Gas Corporation Pineview Tank Battery and Gas Plant Run 2 ENG1 (North) FTIR Measurements EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 10 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 0.29 1560 0.24 0.539 Average O2 0.0 (% dry)A 2 1.05 0.33 0.574 Average CO2 11.1 (% dry)A 3 1.94 0.48 0.693 Average N2 + CO 88.9 (% dry)A 4 3.23 0.36 0.600 Dry Molecular Weight 29.78 lb/lbmol A 5 6.77 0.38 0.616 Wet Molecular Weight 27.85 lb/lbmol A 6 8.06 0.34 0.583 ASTM D6348-03 / EPA REFERENCE METHOD 320 A 7 8.95 0.29 0.539 Barometric Pressure 23.75 in Hg A 8 9.50 0.27 0.520 Moisture Content 16.38 %A 9 ASTM D6348-03 / EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 21.07 ppm A 11 Calculated NOx Mass Output 0.07 lbs/hr A 12 Calculated NOx Output 0.06 g/bhp-hr A 13 ASTM D6348-03 / EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 160.12 ppm A 15 Calculated CO Mass Output 0.33 lbs/hr A 16 Calculated CO Output 0.27 g/bhp-hr B 1 0.50 0.33 1560 0.24 0.574 LOAD APPROXIMATION B 2 1.05 0.34 0.583 Estimated Engine Load 550.0 BHP B 3 1.94 0.28 0.529 B 4 3.23 0.38 0.616 B 5 6.77 0.44 0.663 B 6 8.06 0.39 0.624 B 7 8.95 0.32 0.566 B 8 9.50 0.32 0.566 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 0.3 1560 0.2 0.587 Average Stack Gas Velocity 64.67 ft/sec Average Dry Flowrate 475.83 dscfm TEST RUN # 2 NO Dry (ppm) NO2 Dry (ppm) NOx Dry (ppm) CO Dry (ppm) H2O% (High) 191C Time 1 19.84623 0.846913 20.693143 349.813668 13.339151 9:33:00 12-13-2023 2 19.244924 0.999034 20.243958 187.860373 13.454625 9:34:00 12-13-2023 3 19.082649 0.922912 20.00556 78.767129 13.208916 9:35:00 12-13-2023 4 23.724017 0.898735 24.622752 43.711438 13.334592 9:36:00 12-13-2023 5 44.831744 0.821757 45.653501 36.912651 14.167158 9:37:00 12-13-2023 6 16.292846 0.776952 17.069799 53.621716 12.858618 9:38:01 12-13-2023 7 15.968504 0.751081 16.719585 74.130645 13.330917 9:39:01 12-13-2023 8 16.606986 0.872841 17.479827 132.273104 14.853454 9:40:01 12-13-2023 9 17.535629 1.082169 18.617798 157.988686 17.851335 9:41:01 12-13-2023 10 18.885252 0.850483 19.735736 70.12588 15.871356 9:42:01 12-13-2023 11 33.042401 0.732835 33.775236 34.567369 12.859415 9:43:01 12-13-2023 12 30.566866 0.710103 31.276969 34.990865 12.79006 9:44:02 12-13-2023 13 13.243018 2.855469 16.098487 41.552044 29.483511 9:45:02 12-13-2023 14 16.502643 1.181943 17.684585 60.784364 20.551436 9:46:02 12-13-2023 15 16.710416 0.839461 17.549877 80.768581 15.176793 9:47:02 12-13-2023 16 16.132272 0.700463 16.832735 130.634421 12.060692 9:48:02 12-13-2023 17 16.861348 0.667039 17.528387 117.700939 11.478151 9:49:02 12-13-2023 18 16.709344 0.681451 17.390795 111.198729 12.34259 9:50:03 12-13-2023 19 16.832028 0.72769 17.559718 64.303252 12.895612 9:51:03 12-13-2023 20 81.575334 0.726511 82.301845 35.847985 13.009005 9:52:03 12-13-2023 21 29.490011 0.724971 30.214982 34.427777 12.866677 9:53:03 12-13-2023 22 17.594624 0.716919 18.311543 35.657767 12.792531 9:54:03 12-13-2023 23 15.508056 0.856329 16.364386 70.205773 14.959996 9:55:03 12-13-2023 24 16.335179 0.926943 17.262123 87.355471 15.71331 9:56:04 12-13-2023 25 17.259577 0.973709 18.233286 108.987493 15.420628 9:57:04 12-13-2023 26 19.879325 0.9314 20.810725 43.335972 16.372597 9:58:04 12-13-2023 27 16.76876 0.95827 17.72703 95.356545 15.805591 9:59:04 12-13-2023 28 17.630556 0.856208 18.486764 114.59931 15.533983 10:00:04 12-13-2023 29 12.074994 -0.139973 11.93502 149.228381 36.435488 10:01:04 12-13-2023 30 21.975164 1.870771 23.845935 277.001277 25.306395 10:02:05 12-13-2023 31 20.681299 1.083918 21.765217 247.103776 17.604896 10:03:05 12-13-2023 32 20.381455 1.133482 21.514937 142.493486 17.930351 10:04:05 12-13-2023 33 18.900608 0.853117 19.753725 116.155082 14.193837 10:05:05 12-13-2023 34 17.983701 0.725759 18.70946 106.957074 12.543325 10:06:05 12-13-2023 35 18.824047 0.776169 19.600216 264.265205 13.011922 10:07:05 12-13-2023 36 22.658165 0.775563 23.433728 452.043243 12.991346 10:08:06 12-13-2023 37 21.586155 0.747308 22.333463 207.870364 13.058027 10:09:06 12-13-2023 38 19.831336 0.745931 20.577267 62.87139 13.578578 10:10:06 12-13-2023 39 18.928889 0.750392 19.679281 173.059168 13.206382 10:11:06 12-13-2023 40 20.726801 0.797238 21.524039 261.633048 13.716895 10:12:06 12-13-2023 41 19.830157 0.831975 20.662131 179.853656 15.011195 10:13:06 12-13-2023 42 19.33519 1.007298 20.342488 119.554162 16.597076 10:14:06 12-13-2023 43 18.678812 0.988133 19.666945 165.721032 15.957769 10:15:07 12-13-2023 44 20.333154 0.983821 21.316975 214.652603 16.617273 10:16:07 12-13-2023 45 18.352853 0.994839 19.347692 144.359676 18.09068 10:17:07 12-13-2023 46 15.672968 3.250664 18.923633 319.349621 39.4326 10:18:07 12-13-2023 47 23.399026 1.029324 24.428351 585.11054 17.967639 10:19:07 12-13-2023 48 24.293242 0.94884 25.242082 461.831051 15.254716 10:20:07 12-13-2023 49 23.860346 0.781444 24.64179 297.002631 14.107781 10:21:08 12-13-2023 50 24.421022 0.806851 25.227874 68.989167 13.95592 10:22:08 12-13-2023 51 18.230326 0.823384 19.05371 84.268913 14.080567 10:23:08 12-13-2023 52 17.293421 0.895956 18.189376 141.625528 13.943168 10:24:08 12-13-2023 53 21.628395 0.763485 22.391881 431.753648 13.627312 10:25:08 12-13-2023 54 21.002927 0.860453 21.86338 268.350054 14.459031 10:26:08 12-13-2023 55 21.078262 0.770175 21.848437 148.179301 13.368629 10:27:09 12-13-2023 56 18.213307 0.760792 18.974099 93.924363 14.003436 10:28:09 12-13-2023 57 18.53528 0.827719 19.362999 186.497042 14.262664 10:29:09 12-13-2023 58 19.965111 0.893297 20.858408 287.121132 15.405597 10:30:09 12-13-2023 59 19.323991 1.015215 20.339206 175.010966 16.455063 10:31:09 12-13-2023 60 17.36099 0.874496 18.235485 98.65321 14.798965 10:32:09 12-13-2023 AVG 20.93 0.93 21.86 157.00 15.76 ppm@15% O2 6.17 44.32 NOx (g/bhp-hr) NOx (lbs/hr) CO (g/bhp-hr) CO (lbs/hr) 0.06 0.08 0.27 0.33 Calculated Emission Levels FTIR Measurements ENG1 (North) Citation Oil & Gas Corporation Pineview Tank Battery and Gas Plant Run 3 Record Date EPA REFERENCE METHOD 1 EPA REFERENCE METHOD 2 Stack Diameter 10 Inches Kp=85.49 ft/sec Cp=0.84 Traverse Points 16 Port Point Insertion Depth dP Ts Stat P sqrt dP Ports 2 (inches)(in h2O)(deg R)(in H2O) EPA REFERENCE METHOD 3 A 1 0.50 0.25 1565 0.23 0.500 Average O2 0.0 (% dry)A 2 1.05 0.28 0.529 Average CO2 11.1 (% dry)A 3 1.94 0.33 0.574 Average N2 + CO 88.9 (% dry)A 4 3.23 0.38 0.616 Dry Molecular Weight 29.78 lb/lbmol A 5 6.77 0.42 0.648 Wet Molecular Weight 27.92 lb/lbmol A 6 8.06 0.44 0.663 ASTM D6348-03 / EPA REFERENCE METHOD 320 A 7 8.95 0.37 0.608 Barometric Pressure 23.75 in Hg A 8 9.50 0.31 0.557 Moisture Content 15.76 %A 9 ASTM D6348-03 / EPA REFERENCE METHOD 320 A 10 Average Analyzer NOx Level 21.86 ppm A 11 Calculated NOx Mass Output 0.08 lbs/hr A 12 Calculated NOx Output 0.06 g/bhp-hr A 13 ASTM D6348-03 / EPA REFERENCE METHOD 320 A 14 Average Analyzer CO Level 157.00 ppm A 15 Calculated CO Mass Output 0.33 lbs/hr A 16 Calculated CO Output 0.27 g/bhp-hr B 1 0.50 0.29 1565 0.23 0.539 LOAD APPROXIMATION B 2 1.05 0.36 0.600 Estimated Engine Load 550.0 BHP B 3 1.94 0.39 0.624 B 4 3.23 0.46 0.678 B 5 6.77 0.40 0.632 B 6 8.06 0.36 0.600 B 7 8.95 0.37 0.608 B 8 9.50 0.30 0.548 B 9 B 10 B 11 B 12 B 13 B 14 B 15 B 16 Averages 0.4 1565 0.2 0.595 Average Stack Gas Velocity 65.66 ft/sec Average Dry Flowrate 485.12 dscfm TEST RUN # 3 APPENDIX B Date Time NO 191C span NO2 191C span H2O% (high) 191C Formaldehyde 191C Ethylene 191C TE span Propane 191C span Acetaldehyde 191C span CO ppm 191C (1of2) span CO ppm Dry CO2% 191C NOx Wet NOx Dry NM NE HC C3 Temp ( C )Pressure (atm) 12-13-2023 6:55:39 0.608477 -0.246257 0.002066 0.009785 -0.096904 0.610144 -0.554084 0.039347 0.039347 0.015089 0.362221 0.362228 0.107850 188.811111 0.977792 12-13-2023 6:55:47 0.473334 -0.207511 -0.000928 0.048202 0.388866 0.518605 -0.478206 0.038131 0.038130 0.012187 0.265823 0.265821 0.052973 188.890884 0.984857 12-13-2023 6:55:54 0.466643 -0.201085 0.001563 -0.009526 -0.219260 0.374775 -1.031109 0.043728 0.043729 0.009939 0.265558 0.265562 0.021966 189.027802 0.987111 12-13-2023 6:56:02 0.370706 -0.191694 0.001906 -0.004258 -0.010976 0.603870 -0.668504 -0.035574 -0.035574 0.010610 0.179012 0.179015 0.068559 189.136429 0.984021 12-13-2023 6:56:38 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 189.405457 0.985081 12-13-2023 6:56:51 -0.017094 0.036820 0.001341 0.029852 -0.155904 0.113665 -0.123176 0.051459 0.051460 -0.000150 0.019727 0.019727 -0.000795 189.683212 0.985100 12-13-2023 6:56:59 -0.110603 0.014257 -0.001054 0.039540 -0.386407 0.114279 0.105695 -0.030652 -0.030652 0.000097 -0.096345 -0.096344 -0.007203 189.809158 0.985945 12-13-2023 6:57:07 -0.103498 0.049554 0.000595 -0.002646 -0.006324 -0.186977 0.412955 0.085638 0.085638 0.000316 -0.053943 -0.053944 -0.002993 189.873642 0.986619 12-13-2023 6:57:14 0.046615 0.064929 -0.000669 0.058408 -0.142253 -0.063329 0.245139 0.109744 0.109743 -0.005781 0.111544 0.111544 -0.006817 189.929047 0.983395 12-13-2023 6:57:22 -0.123951 0.042162 0.001161 0.060726 0.169788 0.102375 0.241544 0.009863 0.009863 -0.004443 -0.081789 -0.081790 -0.004971 189.970367 0.986855 12-13-2023 6:57:29 -0.114351 0.022557 0.000313 0.038087 -0.053841 -0.111308 0.182617 -0.068473 -0.068473 -0.001724 -0.091793 -0.091793 -0.009451 190.125229 0.985141 12-13-2023 6:57:37 -0.001367 0.042046 -0.001747 -0.025634 -0.225859 -0.328142 0.094923 -0.027775 -0.027774 -0.001398 0.040679 0.040678 0.007076 190.144302 0.985457 12-13-2023 6:57:44 -0.138565 0.015865 -0.000392 0.047834 -0.009822 0.088297 0.574880 0.012128 0.012128 -0.008783 -0.122700 -0.122699 -0.004217 190.202438 0.985633 12-13-2023 6:57:52 -0.074282 0.021947 -0.000272 0.045037 0.001034 -0.352623 0.257292 0.030490 0.030490 -0.001659 -0.052335 -0.052335 0.004372 190.250580 0.985491 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm) 12-13-2023 6:58:15 416.674398 409.579933 407.164265 190.382050 0.985354 12-13-2023 7:01:16 79.407852 191.099426 0.985277 12-13-2023 6:58:22 498.591191 502.111774 501.827476 190.436768 0.984989 12-13-2023 7:01:24 96.948291 191.033508 0.986257 12-13-2023 6:58:30 506.025807 509.488067 508.895225 190.541229 0.986183 12-13-2023 7:01:31 97.948918 191.028961 0.986722 12-13-2023 6:58:37 506.183796 510.386376 509.975517 190.552124 0.985540 12-13-2023 7:01:39 98.275675 191.064728 0.986416 12-13-2023 6:58:45 506.331676 510.798506 511.609598 190.552124 0.985766 12-13-2023 7:01:46 98.483025 191.121613 0.986951 12-13-2023 6:58:52 506.299671 509.957839 510.593483 190.608429 0.985173 12-13-2023 7:01:54 98.546914 191.058029 0.986868 12-13-2023 6:59:00 505.757180 509.923821 510.318356 190.634781 0.985841 12-13-2023 7:02:01 98.766773 191.041687 0.986553 12-13-2023 6:59:07 505.254052 509.653813 510.222519 190.723785 0.985776 12-13-2023 7:02:09 98.660733 191.090164 0.986679 12-13-2023 6:59:15 505.178469 509.661585 508.863421 190.727417 0.985491 12-13-2023 7:02:16 99.039869 191.135239 0.986530 12-13-2023 6:59:22 505.384398 509.566560 509.854629 190.738312 0.986553 12-13-2023 7:02:24 98.853862 191.069839 0.987023 Date Time NO2 191C span Temp ( C )Pressure (atm) 12-13-2023 6:59:47 106.251313 190.895447 0.987720 12-13-2023 6:59:54 139.297487 190.895447 0.986369 12-13-2023 7:00:02 142.249303 190.895447 0.986194 12-13-2023 7:00:09 143.505393 190.943924 0.986162 12-13-2023 7:00:17 144.226194 190.990814 0.986326 12-13-2023 7:00:25 144.629962 190.990814 0.986590 12-13-2023 7:00:32 145.144217 190.991730 0.987579 12-13-2023 7:00:40 145.707067 191.086182 0.986610 12-13-2023 7:00:47 146.012441 191.068710 0.986664 12-13-2023 7:00:55 146.163592 191.012619 0.986825 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm) 12-13-2023 7:02:45 9.400537 1.291237 -0.118521 191.116394 0.987519 12-13-2023 7:04:23 75.231482 191.117447 0.987253 12-13-2023 7:02:52 205.964860 104.211628 75.528141 191.073471 0.987677 12-13-2023 7:04:31 96.717747 191.070740 0.987387 12-13-2023 7:03:00 448.394388 441.527848 433.370956 191.073471 0.986598 12-13-2023 7:04:38 98.681415 191.085281 0.987812 12-13-2023 7:03:07 497.161524 500.629201 500.559145 191.072556 0.987060 12-13-2023 7:04:46 98.821292 191.135468 0.987372 12-13-2023 7:03:15 502.217133 506.121292 504.328540 191.113205 0.987254 12-13-2023 7:04:54 99.027865 191.114349 0.987152 12-13-2023 7:03:22 503.048602 506.940258 505.116727 191.086182 0.987112 12-13-2023 7:05:01 99.140614 191.054398 0.987241 12-13-2023 7:03:30 503.240270 507.267746 504.757885 191.086182 0.987255 12-13-2023 7:05:09 98.892894 191.110031 0.987673 12-13-2023 7:03:37 502.690250 507.220164 504.987208 191.124329 0.987412 12-13-2023 7:05:16 98.620260 191.149765 0.987350 12-13-2023 7:03:45 501.993536 506.423481 504.461791 191.107071 0.987132 12-13-2023 7:05:24 99.010047 191.105255 0.987606 12-13-2023 7:03:52 501.256024 505.382608 504.248013 191.105255 0.987657 12-13-2023 7:05:31 98.513605 191.073471 0.987878 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Ethylene 191C TE Temp ( C )Pressure (atm) 12-13-2023 7:06:01 0.171648 -0.066346 -1.338888 1.258881 191.086182 0.987777 12-13-2023 7:06:09 0.205418 -0.007497 -1.015437 0.966512 191.065521 0.987829 12-13-2023 7:06:16 0.201014 -0.095803 -1.173032 0.739767 191.105255 0.987749 12-13-2023 7:06:24 0.135384 -0.063874 -0.946384 0.772705 191.105255 0.987548 12-13-2023 7:06:31 0.106163 -0.147371 -1.010512 0.685975 191.102875 0.988143 12-13-2023 7:06:39 0.138715 -0.122606 -0.688962 0.747863 191.041687 0.988067 12-13-2023 7:06:46 0.177329 -0.234683 -1.109693 1.056383 191.054398 0.988337 Date Time CO2% 191C Propane 191C span Temp ( C )Pressure (atm) 12-13-2023 7:25:19 9.347878 5.224652 191.035324 0.986270 12-13-2023 7:25:27 9.322847 5.138895 191.035324 0.988692 12-13-2023 7:25:34 9.379087 5.007770 191.035324 0.988930 12-13-2023 7:26:05 9.156345 4.674208 191.035324 0.979951 12-13-2023 7:26:12 9.179144 5.698579 191.035324 0.994314 12-13-2023 7:26:20 6.616167 67.434029 191.035324 0.998860 12-13-2023 7:26:27 0.925056 393.035647 191.035324 1.010038 12-13-2023 7:26:35 0.128578 445.586049 191.035324 0.982927 12-13-2023 7:26:42 4.167452 237.464653 191.035324 0.980383 12-13-2023 7:26:50 7.876214 75.998489 191.035324 0.980842 12-13-2023 7:26:57 8.164325 55.225673 191.035324 0.978106 12-13-2023 7:27:05 8.216459 53.126914 191.035324 0.980184 12-13-2023 7:27:12 8.146812 52.678644 191.035324 0.974738 12-13-2023 7:27:20 8.028510 49.867317 191.005356 0.974113 12-13-2023 7:27:27 8.002997 49.411850 190.953583 0.974340 12-13-2023 7:27:35 8.085713 46.416802 190.952667 0.978606 12-13-2023 7:27:42 8.090781 46.640552 190.952667 0.972897 12-13-2023 7:27:50 8.310783 46.425467 190.952667 0.980704 12-13-2023 7:27:57 8.343901 46.453272 190.952667 0.983131 12-13-2023 7:28:05 8.197171 45.599529 190.920883 0.980810 12-13-2023 7:28:13 8.333455 45.506991 190.876373 0.982920 12-13-2023 7:28:20 8.407284 45.896245 190.904984 0.982082 12-13-2023 7:28:28 8.495255 45.608402 190.971741 0.989472 12-13-2023 7:28:58 8.442420 46.237786 190.971283 0.986066 12-13-2023 7:29:05 8.633530 46.473265 190.984467 0.985635 PRE SYSTEM ZERO Raw Calibration Data BACKGROUND / PRE DIRECT ZERO PRE DIRECT CAL NO2 CAL PRE SYSTEM CAL SAMPLE SPIKE RECOVERY Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm) 12-13-2023 10:39:33 342.528831 342.110349 315.580625 191.060760 0.999004 12-13-2023 10:37:58 79.467180 190.908173 0.998499 12-13-2023 10:39:40 487.329063 489.686462 487.710432 191.060760 0.998292 12-13-2023 10:38:06 95.055096 190.928146 1.008136 12-13-2023 10:39:48 500.285955 503.140610 500.165314 191.060760 0.997851 12-13-2023 10:38:13 96.766992 190.978104 1.006168 12-13-2023 10:39:55 500.722054 504.369549 500.984924 191.060760 0.997100 12-13-2023 10:38:21 96.720839 190.984467 1.005266 12-13-2023 10:40:03 500.527050 503.950399 500.826329 191.060760 0.996764 12-13-2023 10:38:28 96.934512 190.984467 1.005030 12-13-2023 10:40:10 499.074401 503.393939 502.070055 191.060760 0.996459 12-13-2023 10:38:36 97.078633 190.988434 1.004493 12-13-2023 10:40:18 500.525868 504.240770 500.950256 191.060760 0.995890 12-13-2023 10:38:43 97.508878 191.011703 1.003670 12-13-2023 10:40:25 501.145945 505.108549 500.881999 191.060760 0.995002 12-13-2023 10:38:51 98.125609 191.055313 1.003441 12-13-2023 10:40:33 501.903578 505.243273 501.933762 191.060760 0.994888 12-13-2023 10:40:40 501.557738 505.890194 502.584628 191.060760 0.994449 Date Time CO ppm 191C (1of2) span NOx Wet Propane 191C span Temp ( C )Pressure (atm)Date Time Ethylene 191C TE Temp ( C )Pressure (atm) 12-13-2023 10:38:06 0.697318 0.400272 -0.236538 190.928146 1.008136 2023-12-13 10:41:26 -0.029699 191.06076 1.002807 12-13-2023 10:38:13 -0.040627 0.137700 -0.589446 190.978104 1.006168 2023-12-13 10:41:33 0.143886 191.06076 1.002242 12-13-2023 10:38:21 -0.168495 -0.093055 -0.920156 190.984467 1.005266 2023-12-13 10:41:41 0.128861 191.06076 1.00209 12-13-2023 10:38:28 -0.266503 -0.292395 -0.088310 190.984467 1.005030 2023-12-13 10:41:48 0.006843 191.06076 1.001774 12-13-2023 10:38:36 -0.118966 -0.127118 -0.503715 190.988434 1.004493 2023-12-13 10:41:56 0.468367 191.06076 1.002267 12-13-2023 10:38:43 -0.223633 -0.026956 -0.954706 191.011703 1.003670 2023-12-13 10:42:03 0.489941 191.06076 1.002107 12-13-2023 10:38:51 -0.088828 -0.186411 -1.179386 191.055313 1.003441 2023-12-13 10:42:11 -0.075182 191.06076 1.002308 POST SYSTEM ZERO POST SYSTEM CAL PRE TEST 1 508.7 9.3 5.1 8.4 46.0 0.095 85.6% Sensor Analyzer Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Error (%)Error (%) NOx 509.6 509.3 0.0 0.05 -0.01 CO 505.4 506.0 0.0 -0.12 0.00 Propane 509.9 508.7 0.0 0.23 -0.01 Ethylene 98.9 99.84 -0.1 -0.99 -0.10 Sensor System Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Recovery (%)Error (%) NOx 505.4 509.3 -0.1 -0.77 -0.02 CO 501.3 506.0 0.2 -0.94 0.03 Propane 504.2 508.7 -1.0 -0.88 -0.20 Ethylene*98.5 99.84 0.9 -1.33 0.89 Sensor System Cal Zero Cal Zero Cal Zero Response (ppm)Level (ppm)Response (ppm)Recovery (%)Error (%)Drift Error (%)Drift Error (%) NOx 505.9 509.3 0.0 -0.67 -0.01 0.10 0.02 CO 501.6 506.0 0.0 -0.88 -0.01 0.06 0.04 Propane 502.6 508.7 -0.6 -1.20 -0.13 0.33 0.08 Ethylene*98.1 99.84 0.2 -1.72 0.16 0.39 0.73 *CTS Scans are conducted with Ethylene through the sample line. Lf 5.11 Lr Cr Tr Pr Lr/Lf 5.24 98.8 191.1 1.0 1.02 Ls Cs Ts Ps Ls/Lf 5.24 98.6 191.1 1.0 1.03 Pathlength Stack Propane Concentration Stack + Spike CO2 Concentration Stack + Propane Concentration DF Calculated POST SYSTEM CAL PRE SYSTEM CAL % Recovery Propane PRE DIRECT CAL FTIR QA/QC SUMMARY SAMPLE RECOVERY CALCULATIONS Period Spike #Concentration of Propane Cylinder Stack CO2 Concentration CERTIFICATE OF ANALYSIS Grade of Product: EPA PROTOCOL STANDARD Part Number:E05NI99E15A0000 Reference Number:153-402600698-1 Cylinder Number:CC89245 Cylinder Volume:144.0 CF Laboratory:124 - Tooele (SAP) - UT Cylinder Pressure:2015 PSIG PGVP Number:B72022 Valve Outlet:660 Gas Code:CH4,CO,NO,NOX,PPN,BALN Certification Date:Dec 06, 2022 Expiration Date:Dec 06, 2030 Certification performed in accordance with “EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)” document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. The results relate only to the items tested. The report shall not be reproduced except in full without approval of the laboratory. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. ANALYTICAL RESULTS Component Requested Actual Protocol Total Relative Assay Concentration Concentration Method Uncertainty Dates NOX 500.0 PPM 509.3 PPM G1 +/- 0.6% NIST Traceable 11/29/2022, 12/06/2022 CARBON MONOXIDE 500.0 PPM 506.0 PPM G1 +/- 0.8% NIST Traceable 11/29/2022 METHANE 500.0 PPM 504.7 PPM G1 +/- 0.9% NIST Traceable 11/29/2022 NITRIC OXIDE 500.0 PPM 509.3 PPM G1 +/- 0.6% NIST Traceable 11/29/2022, 12/06/2022 PROPANE 500.0 PPM 508.7 PPM G1 +/- 0.7% NIST Traceable 11/29/2022 NITROGEN Balance CALIBRATION STANDARDS Type Lot ID Cylinder No Concentration Uncertainty Expiration Date NTRM 15060527 CC450559 491.9 PPM CARBON MONOXIDE/NITROGEN 0.6%Mar 05, 2027 PRM 12409 D913660 15.01 PPM NITROGEN DIOXIDE/AIR 1.5%Feb 17, 2023 NTRM 08011609 K020818 496.5 PPM METHANE/NITROGEN 0.6%Aug 08, 2024 NTRM 15010116 KAL003474 494.6 PPM NITRIC OXIDE/NITROGEN 0.5%Aug 16, 2027 GMIS 1534012021103 ND73012 4.956 PPM NITROGEN DIOXIDE/NITROGEN 1.6%Jun 15, 2025 NTRM 12010921 ND46380 487 PPM PROPANE/AIR 0.6%Apr 24, 2024 The SRM, NTRM, PRM, or RGM noted above is only in reference to the GMIS used in the assay and not part of the analysis. ANALYTICAL EQUIPMENT Instrument/Make/Model Analytical Principle Last Multipoint Calibration Nicolet iS50 AUP2110269 CO MCO FTIR Nov 03, 2022 Nicolet iS50 AUP2110269 CH4 M1CH4 FTIR Nov 16, 2022 Nicolet iS50 AUP2110269 NO MNO FTIR Nov 10, 2022 Nicolet iS50 AUP2110269 NO2 impurity FTIR NO2 impurity Nov 11, 2022 MKS FTIR C3H8 018143349 FTIR Nov 03, 2022 Triad Data Available Upon Request Airgas Specialty Gases Airgas USA LLC 525 North Industrial Loop Road Tooele, UT 84074 Airgas.com Signature on file Approved for Release Page 1 of 1 CERTIFICATE OF ANALYSIS Grade of Product: EPA PROTOCOL STANDARD Part Number:E02NI99E15W0051 Reference Number:153-402710396-1 Cylinder Number:CC466247 Cylinder Volume:144.0 CF Laboratory:124 - Tooele (SAP) - UT Cylinder Pressure:2015 PSIG PGVP Number:B72023 Valve Outlet:660 Gas Code:NO2,BALN Certification Date:Apr 20, 2023 Expiration Date:Apr 20, 2026 Certification performed in accordance with “EPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)” document EPA 600/R-12/531, using the assay procedures listed. Analytical Methodology does not require correction for analytical interference. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use of this calibration mixture. All concentrations are on a mole/mole basis unless otherwise noted. The results relate only to the items tested. The report shall not be reproduced except in full without approval of the laboratory. Do Not Use This Cylinder below 100 psig, i.e. 0.7 megapascals. ANALYTICAL RESULTS Component Requested Actual Protocol Total Relative Assay Concentration Concentration Method Uncertainty Dates NITROGEN DIOXIDE 150.0 PPM 147.9 PPM G1 +/- 2.0% NIST Traceable 04/13/2023, 04/20/2023 NITROGEN Balance CALIBRATION STANDARDS Type Lot ID Cylinder No Concentration Uncertainty Expiration Date GMIS 1534012021601 CC502090 100.5 PPM NITROGEN DIOXIDE/NITROGEN 1.1%Dec 17, 2024 PRM 12389 D685050 99.0 PPM NITROGEN DIOXIDE/NITROGEN 1.0%Feb 19, 2020 The SRM, NTRM, PRM, or RGM noted above is only in reference to the GMIS used in the assay and not part of the analysis. ANALYTICAL EQUIPMENT Instrument/Make/Model Analytical Principle Last Multipoint Calibration MKS FTIR NO2 018143349 FTIR Apr 06, 2023 Triad Data Available Upon Request PERMANENT NOTES:OXYGEN ADDED TO MAINTAIN STABILITY Airgas Specialty Gases Airgas USA LLC 525 North Industrial Loop Road Tooele, UT 84074 Airgas.com Signature on file Approved for Release Page 1 of 1 CERTIFICATE OF ANALYSIS Grade of Product: PRIMARY STANDARD Part Number:X02NI99P15AD524 Reference Number:153-402805170-1 Cylinder Number:EB0122984 Cylinder Volume:140.0 CF Laboratory:124 - Tooele (SAP) - UT Cylinder Pressure:2015 PSIG Analysis Date:Aug 01, 2023 Valve Outlet:350 Lot Number:153-402805170-1 Expiration Date:Aug 01, 2026 Primary Standard Gas Mixtures are traceable to N.I.S.T. weights and/or N.I.S.T. Gas Mixture reference materials. ANALYTICAL RESULTS Component Req Conc Actual Concentration Analytical (Mole %)Uncertainty ETHYLENE 100.0 PPM 99.84 PPM +/- 1% NITROGEN Balance Airgas Specialty Gases Airgas USA LLC 525 North Industrial Loop Road Tooele, UT 84074 Airgas.com Signature on file Approved for Release Page 1 of 1 CitaƟon – Pineview 12-13-2023 CitaƟon – Pineview 12-13-2023 CitaƟon – Pineview 12-13-2023 Spectral Fit Run 1 Spectral Fit Run 2 Spectral Fit Run 3 Analysis Validation Report - Run 1 Sample Filename: C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000150.LAB Filename for noise: C:\OLT\Data\Golden Spectrum\New FTIR 09-13-23\NEW FTIR 09-13-23_000003.LAB Interferences Filenames: C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000068.LAB C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000069.LAB C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000070.LAB C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000071.LAB C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000072.LAB C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000073.LAB C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000074.LAB C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000075.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 18.08 2.72 16.12 0.18 0.24 3.71 3.71 17.74 17.74 1.62 5.37 0-2795 1.02 Close to DL NO2 191C 0.82 0.41 0.36 0.02 0.02 0.43 0.43 0.58 0.58 0.22 0.12 0-488 0.99 Close to DL N2O 191C 0.75 0.3 0.57 0.02 0.02 0.34 0.34 0.61 0.61 0.03 0.19 0-200 -Close to DL NH3 TE 191C 1.24 27.27 6.11 2.05 3.49 46.55 46.55 9.06 25.36 2.95 2.04 0-2995 -Close to DL H2O% (HIGH) 191C15.33 0.28 -0.01 0.01 0.44 0.44 -0.31 --0-40 -Good FORMALDEHYDE 191C0.08 1.21 0.06 0.13 0.15 1.37 1.37 0.07 1.08 0.01 0.02 0-69 -Close to DL FORMIC ACID 191C TE0.51 7.2 0.74 0.7 0.82 8.43 8.43 1.41 6.51 0.67 0.25 0-466 -Close to DL CH4 2900 CM-1 191C315.31 12.82 -0.83 1.21 25.81 25.81 -6.82 --0-3143 0.96 Good PROPANE 191C 3.8 1.11 6.67 0.11 0.13 1.33 1.33 6.93 6.93 0.26 2.22 0-4976 0.95 Close to DL PROPYLENE 191C TE-1.11 7.76 2.09 0.78 0.93 9.18 9.18 2.84 6.96 0.75 0.7 0-194 -Close to DL ETHANE 191C 21.59 2.23 -0.26 0.4 3.48 3.48 -1.41 --0-1004 -Good ETHYLENE 191C TE3.01 13.91 1.74 1.01 1.24 17.15 17.15 2.82 12.83 1.08 0.58 0-900 -Close to DL CO PPM 191C (1OF2)94.47 3.77 -0.15 0.32 7.76 7.76 -2.05 --0-5010 1.02 Good CO2% 191C 9.68 0.2 -0.01 0.01 0.27 0.27 -0.19 --0-23 -Good CO% 191C (2OF2)0.01 0-0 0 0 0-0--0-8 -Good ACETALDEHYDE 191C0.44 3.5 0.89 0.36 0.47 4.5 4.5 1.52 3.13 0.63 0.3 0-186 0.99 Close to DL ACETYLENE 191C-0.17 3.11 0.41 0.36 0.48 4.11 4.11 0.81 2.76 0.4 0.14 0-1016 -Close to DL SO2 191C 3.67 3.82 1.32 0.24 0.29 4.66 4.66 1.8 3.51 0.48 0.44 0-964 1.02 Close to DL HEXANE 191C -0.1 0.63 0.09 0.06 0.09 0.85 0.85 0.17 0.57 0.08 0.03 0-1000 -Close to DL Analysis Validation Report - Run 2 Sample Filename: C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000206.LAB Filename for noise: C:\OLT\Data\Golden Spectrum\New FTIR 09-13-23\NEW FTIR 09-13-23_000003.LAB Interferences Filenames: C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000068.LAB C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000069.LAB C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000070.LAB C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000071.LAB C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000072.LAB C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000073.LAB C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000074.LAB C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000075.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 14.52 2.6 16.12 0.18 0.24 3.54 3.54 17.74 17.74 1.62 5.37 0-2795 1.02 Close to DL NO2 191C 0.7 0.41 0.36 0.02 0.02 0.43 0.43 0.58 0.58 0.22 0.12 0-488 0.99 Close to DL N2O 191C 0.4 0.3 0.57 0.02 0.02 0.35 0.35 0.61 0.61 0.03 0.19 0-200 -Close to DL NH3 TE 191C -1.72 27.92 6.11 2.05 3.49 47.66 47.66 9.06 26 2.95 2.04 0-2995 -Close to DL H2O% (HIGH) 191C14.06 0.29 -0.01 0.01 0.47 0.47 -0.28 --0-40 -Good FORMALDEHYDE 191C0.06 1.21 0.06 0.13 0.15 1.37 1.37 0.07 1.08 0.01 0.02 0-69 -Close to DL FORMIC ACID 191C TE0.41 7.23 0.74 0.7 0.82 8.47 8.47 1.41 6.54 0.67 0.25 0-466 -Close to DL CH4 2900 CM-1 191C310.39 13.09 -0.83 1.21 26.36 26.36 -6.9 --0-3143 0.96 Good PROPANE 191C3.96 1.11 6.67 0.11 0.13 1.33 1.33 6.93 6.93 0.26 2.22 0-4976 0.95 Close to DL PROPYLENE 191C TE-1.11 7.82 2.09 0.78 0.93 9.26 9.26 2.84 7.02 0.75 0.7 0-194 -Close to DL ETHANE 191C 22.46 2.24 -0.26 0.4 3.49 3.49 -1.4 --0-1004 -Good ETHYLENE 191C TE2.46 14.57 1.74 1.01 1.24 17.97 17.97 2.82 13.51 1.08 0.58 0-900 -Close to DL CO PPM 191C (1OF2)155.13 4.72 -0.15 0.32 9.54 9.54 -3.1 --0-5010 1.02 Good CO2% 191C 9.56 0.2 -0.01 0.01 0.27 0.27 -0.19 --0-23 -Good CO% 191C (2OF2)0.02 0-0 0 0 0-0--0-8 -Good ACETALDEHYDE 191C0.09 3.48 0.89 0.36 0.47 4.47 4.47 1.52 3.12 0.63 0.3 0-186 0.99 Close to DL ACETYLENE 191C-0.3 3.13 0.41 0.36 0.48 4.13 4.13 0.81 2.77 0.4 0.14 0-1016 -Close to DL SO2 191C 3.2 3.51 1.32 0.24 0.29 4.28 4.28 1.8 3.21 0.48 0.44 0-964 1.02 Close to DL HEXANE 191C -0.14 0.64 0.09 0.06 0.09 0.86 0.86 0.17 0.57 0.08 0.03 0-1000 -Close to DL Analysis Validation Report - Run 3 Sample Filename: C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000266.LAB Filename for noise: C:\OLT\Data\Golden Spectrum\New FTIR 09-13-23\NEW FTIR 09-13-23_000003.LAB Interferences Filenames: C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000068.LAB C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000069.LAB C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000070.LAB C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000071.LAB C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000072.LAB C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000073.LAB C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000074.LAB C:\OLT\Data\Citation\Pineview ENG1 N 12-13-23\PINEVIEW ENG1 N 12-13-23_000075.LAB Recipe path: C:\OLT\RECIPES\STEPHEN PYER TEST.MGRCP Gas calibration NameConc MDC3 MDC2 MDC1 MAU FMU*R OCU ~ DL ~ CL ~ Bias Sigma Range Span Comment NO 191C 18.51 2.85 16.12 0.18 0.24 3.89 3.89 17.74 17.74 1.62 5.37 0-2795 1.02 Close to DL NO2 191C 0.92 0.48 0.36 0.02 0.02 0.51 0.51 0.58 0.58 0.22 0.12 0-488 0.99 Close to DL N2O 191C 0.8 0.34 0.57 0.02 0.02 0.39 0.39 0.61 0.61 0.03 0.19 0-200 -Close to DL NH3 TE 191C -1.69 35.49 6.11 2.05 3.49 60.58 60.58 9.06 33.57 2.95 2.04 0-2995 -Close to DL H2O% (HIGH) 191C18 0.41 -0.01 0.01 0.64 0.64 -0.36 --0-40 -Good FORMALDEHYDE 191C0.11 1.19 0.06 0.13 0.15 1.34 1.34 0.07 1.06 0.01 0.02 0-69 -Close to DL FORMIC ACID 191C TE0.48 7.92 0.74 0.7 0.82 9.27 9.27 1.41 7.23 0.67 0.25 0-466 -Close to DL CH4 2900 CM-1 191C324.47 13.64 -0.83 1.21 27.46 27.46 -7.21 --0-3143 0.96 Good PROPANE 191C 6.78 1.2 6.67 0.11 0.13 1.44 1.44 6.93 6.93 0.26 2.22 0-4976 0.95 Close to DL PROPYLENE 191C TE-2.23 8.49 2.09 0.78 0.93 10.04 10.04 2.84 7.66 0.75 0.7 0-194 -Close to DL ETHANE 191C 29.43 2.31 -0.26 0.4 3.6 3.6 -1.32 --0-1004 -Good ETHYLENE 191C TE3.92 18.56 1.74 1.01 1.24 22.89 22.89 2.82 17.46 1.08 0.58 0-900 -Close to DL CO PPM 191C (1OF2)516.89 15.53 -0.15 0.32 29.65 29.65 -10.34 --0-5010 1.02 Good CO2% 191C 9.03 0.22 -0.01 0.01 0.3 0.3 -0.18 --0-23 -Good CO% 191C (2OF2)0.05 0 -0 0 0.01 0.01 -0 --0-8 -Good ACETALDEHYDE 191C0.15 3.41 0.89 0.36 0.47 4.38 4.38 1.52 3.05 0.63 0.3 0-186 0.99 Close to DL ACETYLENE 191C-0.11 3.71 0.41 0.36 0.48 4.9 4.9 0.81 3.36 0.4 0.14 0-1016 -Close to DL SO2 191C 4.58 4.99 1.32 0.24 0.29 6.08 6.08 1.8 4.65 0.48 0.44 0-964 1.02 Close to DL HEXANE 191C -0.14 0.72 0.09 0.06 0.09 0.97 0.97 0.17 0.65 0.08 0.03 0-1000 -Close to DL APPENDIX C APPENDIX D Test Run Flowrate dscfm Approx. BHP Avg O2 % NOx ppmvd NOx g/bhp-hr NOx lbs/hr CO ppmvd CO g/bhp-hr CO lbs/hr Moisture Content % 1 527.48 550.0 0.0 19.78 0.06 0.07 216.90 0.41 0.50 15.52 2 475.83 550.0 0.0 21.07 0.06 0.07 160.12 0.27 0.33 16.38 3 485.12 550.0 0.0 21.86 0.06 0.08 157.00 0.27 0.33 15.76 550.0 0.0 20.90 0.06 0.07 178.00 0.32 0.39 15.89 Summary Average Levels Example Calculations: Citation Oil & Gas Corporation, Pineview Tank Battery and Gas Plant, ENG1 (North) The following is a step-by-step calculation for the first test run conducted on the Pineview Tank Battery and Gas Plant ENG1 (North). Test Parameters Stack Diameter = 10 inches Traverse Points = 16 Ports = 2 Barometric Pressure = 23.75 in Hg Average O2 = 0.0% Average CO2 = 11.5% Load Approximation = 550.0 bhp Moisture Content = 15.52% EPA 40 CFR 60(A) Methods 1-3: Determination of Stack Gas Velocity and Flow Rate Dry Molecular Weight (lb/lbmol) = (0.44 * %CO2) + (0.32 * %O2) + ((0.28 * (%N2 + %CO)) Where: %CO2 – Carbon Dioxide Content Of The Gas = 11.5% %O2 – Oxygen Content Of The Gas = 0.0% %N2 – Nitrogen Content Of The Gas %CO – Carbon Monoxide Content Of The Gas (%N2 +%CO) = (100 - %O2 - %CO2) = (100 – 0.0 – 11.5) = 88.5% Dry = (0.44 * %CO2) + (0.32 * %O2) + ((0.28 * (%N2 + %CO)) = (0.44 * 11.5) + (0.32 * 0.0) + (0.28 * 88.5) = 29.84 lb/lbmol Wet Molecular Weight (lb/lbmol) = MD * (1-BWS) + (18) * BWS Where: MD – Molecular Weight Of The Dry Gas (lb/lbmol) = 29.84 lb/lbmol BWS – Moisture Content Of The Gas (%/100) = 15.52% = MD * (1-BWS) + (18) * BWS = 29.84 * (1 – (15.52/ 100)) + (18 * (15.52/ 100)) = 28.00 lb/lbmol Average Stack Gas Velocity (ft/sec) = Cp * (85.49) *∆PAVG *(TS / (((PS / 13.6) + PB) * MA)) Where: CP – Pitot tube constant (unitless) = 0.84 ∆PAVG – Average square root of the stack gas pitot DP (inches water) = 0.645 in H2O TS – Average stack temperature (R) = 1560 R PB – Barometric pressure (in Hg) = 23.75 in Hg PS – Stack pressure relative to barometric pressure (inches water) = 0.3 in H2O MA – Molecular weight of the wet gas (lb/lbmol) = 28.00 lb/lbmol = Cp * (85.49) *∆PAVG *(TS / (((PS / 13.6) + PB) * MA)) = 0.84 * (85.49) * 0.645 *( 1560 / (((0.3/ 13.6) + 23.75) * 28.00)) =70.96 ft/sec Average Dry Flowrate (dscfm) = 60 * (1-BWS) * VS * * (((DS / 2) / 12))2)* TSTD / TS * (PB + (PS / 13.6)) / 29.92 Where: DS – Diameter of the stack (inches) = 10 inches BWS – Moisture content of the gas (%) = 15.52% TSTD – Standard temperature (528R) TS – Average stack temperature (R) = 1560 R PB – Barometric pressure (in Hg) = 23.75 in Hg PS – Stack pressure relative to barometric pressure (inches water) = 0.3 in H2O VS– Average Stack gas velocity (ft/sec) = 70.96 ft/sec = 60 * (1-BWS) * VS * * (((DS / 2) / 12))2)* TSTD / TS * (PB + (PS / 13.6)) / 29.92 = 60 * (1 - (15.52/ 100)) * 70.96 * * (((10 / 2) / 12))2) * 528 / 1560 * (23.75 + (0.3 / 13.6)) / 29.92 =527.48 dscfm Conversion of Dry Flowrate to m3/hr = Q * 60 * 2.83168*10 -2 Where: Q – Volumetric Flowrate = 527.48 dscfm 2.83168*10 -2 – Conversion factor for cubic feet to cubic meter 60 – Minutes in an hour = Q * 60 * 2.83168*10 -2 = 527.48 *60 * 2.83168*10 -2 =896.1944 m3/hr ASTM D 6348-03: Determination of NOx and CO Emissions From Stationary Sources NOx Emission Rate (g/Bhp-hr) = (Cd * 1.912*10 -3 * Q * T) / HP-hr Where: Cd – Measured NOx concentration in ppm = 19.78 ppm 1.92*10 -3 - Conversion constant for ppm to g/m3 NOx Q – Volumetric Flowrate = 896.1944 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = Bhp = (Cd * 1.912*10 -3 * Q * T) / HP-hr = (19.78 * 1.912*10 -3 * 896.1944 * 1) / =0.06 g/Bhp-hr NOx Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.06 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = Bhp = g/Bhp-hr / 454 * Bhp = 0.06 / 454 * = 0.07 lbs/hr CO Emission Rate (g/Bhp-hr) = (Cd * 1.164*10 -3 * Q * T) / HP-hr Where: Cd – Measured CO concentration in ppm = 216.90 ppm 1.164*10 -3 - Conversion constant for ppm to g/m3 CO Q – Volumetric Flowrate = 896.1944 m3/hr T – Time in Hours of Test Run = 1 hr HP-hr – Unit Brake Horsepower = Bhp = (Cd * 1.164*10 -3 * Q * T) / HP-hr = (216.90 * 1.164*10 -3 * 896.1944 * 1) / =0.41 g/Bhp-hr CO Emission Rate (lbs/hr) = g/Bhp-hr / 454 * Bhp Where: g/Bhp-hr = 0.41 g/Bhp-hr 454 – Conversion factor for g to lbs Bhp - Unit Brake Horsepower = Bhp = g/Bhp-hr / 454 * Bhp = 0.41 / 454 * = 0.50 lbs/hr APPENDIX E FTIR Engine Test Sheet Company Name 7 ~J.,,+-;j)'v\ Location / Unit 1.0. p. InDvil"l"""" Type of Test Completed ~ 'i \I:t Field Technician (s) Jordan Nix ,~yy\ Client Rep and/or State Rep Date 3-grem V \A-P,-)S 7 he 84\.Non-Resettable Run Time Hours 'WJ,.~ t .. 5." ~er\o..Enqine Make cr.D :~t.Enqine Model 'I)") () ::$«;&1Enaine SII\I S\Port Distance A Port Distance B ~l.\ lo"\Exhaust Diameter (inches) Concentration 1\10 (ppm Cylinder #Calibration Gas 509.3 CO (ppm CC89245 ; 506 Propane (ppm) CC89245 508.7 1\102 (ppm) CC89245 147.9 Ethylene ppm CC466247 99.84 Methane ppm EB0122984 504.7 Acetaldehvde ('ppm) CC89245 30.33SG9142412BAL Stack Diagram ..,..,,,...,=",~:~,,.,~,~",~,>,~,;;;""""c<~' '~'-" , 1 8 l 1 1·11 , Test 1 Test 2 Test 3 Time of Reading O.r~z:.. o ~!) e'!.. O'l!-Z-- Atm Pressure (in Hg) Z3· 7-~ ?~ ~ 2:--$ , ii!-6' Atm Temp CF) ;? C> .3c. 3;1 Engine RPM f. 6j:) Jf7:0 66;z... , *Manifold Pres.)lac(") or Boost(psi) or Boost (psia) 'I 1'1 II Manifold Temo (OF) /i, 11.13IC?~ lOt.; Psuction psi) Stage 1 :?~ r- Tsuction ('F) Stage 1 r------r-----. -- Pdischarae (psi) Staae 1 .30 ~# 31 Psuction psi) Stage 2 ...- ~ - Tsuction ('F) Stage 2 -..- Pdischar~ e (psi) Staqe 2 1{j(7 I C{P::;-Ie,::;- Psuction [psi) Staqe 3 --- Tsuction OF) Stage 3 ----Pdischarae (osi) Staae 3 (;10 "'C>D t5D(; Psuction (psi) Stage 4 I I Tsuction CF) Stage 4 I I Pdischarge (psi) Stage 4 Gas Throuahout {mmcf/dl or { l I I Pre Cat Temp ('F) If. 'h ;re;. lOCV JO~ Post Cat Temp ('F) /, 00 {IOO If()~ Cat Differential Pres. (" of H2O) J'l!("J .J.V/:'P'S -' - Humidity% 69 15"4. 0----/ 02% 6 C' 0 C02 % Dry If? ..cp 1/. I //-/ LOAD % (Panel) or (Estimated) /1//9 ...--~-- Ignition Timing CF) 'VI'! --AFR Setting mV (Left Bank) 1'77, +c-rj,.., , ;t, q7:;"'// --, .. .......-----..~» AFR Settinq mV (Riqht Bank) ..----.--." - Rev 8 • Some units show boost in inches of Hg. In this situation please indicate if it is positive (+) or negative(-). Eg: (+12") or (-5") 9/17/2019 COMPANY NAME:Citation COMPANY LOCATION:Pineview ENG 1 N DATE:December 13, 2023 STACK DIAMETER (inches):10 TRAVERSE POINTS:16 2 TEST RUN #1 TEST RUN #2 TEST RUN #3 AVERAGE O2:0 AVERAGE O2:0 AVERAGE O2:0 AVERAGE CO2:11.5 AVERAGE CO2:11.1 AVERAGE CO2:11.1 BARO PRESSURE:23.75 BARO PRESSURE:23.75 BARO PRESSURE:23.75 Point Insertion DepthDP (H2O) Ts (deg R)Stat P (H2O)Point Insertion DepthDP (H2O) Ts (deg R)Stat P (H2O)Point Insertion DepthDP (H2O)Ts (deg R) Stat P (H2O) 1 0.5 0.33 1100 0.26 1 0.5 0.29 1100 0.24 1 0.5 0.25 1105 0.23 2 1.05 0.38 2 1.05 0.33 2 1.05 0.28 3 1.94 0.4 3 1.94 0.48 3 1.94 0.33 4 3.23 0.39 4 3.23 0.36 4 3.23 0.38 5 6.77 0.41 5 6.77 0.38 5 6.77 0.42 6 8.06 0.42 6 8.06 0.34 6 8.06 0.44 7 8.95 0.43 7 8.95 0.29 7 8.95 0.37 8 9.5 0.38 8 9.5 0.27 8 9.5 0.31 9 9 9 10 10 10 11 11 11 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16 1 0.5 0.44 1100 0.26 1 0.5 0.33 1100 0.24 1 0.5 0.29 1105 0.23 2 1.05 0.45 2 1.05 0.34 2 1.05 0.36 3 1.94 0.47 3 1.94 0.28 3 1.94 0.39 4 3.23 0.48 4 3.23 0.38 4 3.23 0.46 5 6.77 0.46 5 6.77 0.44 5 6.77 0.4 6 8.06 0.43 6 8.06 0.39 6 8.06 0.36 7 8.95 0.42 7 8.95 0.32 7 8.95 0.37 8 9.5 0.39 8 9.5 0.32 8 9.5 0.3 9 9 9 10 10 10 11 11 11 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16 Worksheet: O2 Stratification Client:Citation Location:Pineview ENG 1 N Date:2023-12-13 PD:10 DD:24 YES Method 1 Criteria Met UD:5 YES Method 1 Criteria Met Port Point Insertion Depth Reading (inches)(%) A 1 1.66 0.00 A 2 5.00 0.00 A 3 8.33 0.00 A 4 A 5 A 6 A 7 A 8 A 9 A 10 A 11 A 12 Average 0.00 Notes: To demonstrate non-stratified flow and utilize one sampling location O2 may not deviate by more than +/- 0.3% of the average O2 concentration. EPA REFERENCE METHOD 3A (Determination Of Stratification) ATTACHMENT B Notice of Intent and Test Protocol 14077 Cutten Road ꞏ Houston, TX 77069-2212 ꞏ 281.891.1000 October 12, 2023 Ms. Alexis North Via E-mail: R8AirReportEnforcement@epa.gov Office of Enforcement US EPA Region 8 8ENF-AT 1595 Wynkoop Street Denver, CO 80202-1129 Mr. Rik Ombach Via Website: https://utahgov.co1.qualtrics.com/jfe/form/SV_3dSxf7JSzy4jwGh Minor Source Compliance Manager Permitting and Compliance Division P.O. Box 144820 Salt Lake City, UT 84114-4820 Dear Mr. Ombach and Ms. North: SUBJECT: SOURCE TEST NOTIFICATION AND PROTOCOL SUBMISSION CITATION OIL & GAS CORP. PINEVIEW TANK BATTERY AND GAS PLANT PERMIT #DAQE-AN155130002-22 SUMMIT COUNTY, UTAH In order to demonstrate compliance with UDAQ Permit # DAQE-AN155130002-22 and EPA 40 CFR 63, Subpart ZZZZ, Citation Oil & Gas Corp. (Citation) has requested Oasis Emission Consultants, Inc. (Oasis) to perform source emission testing on one (1) 800 hp White Superior 8G825 engine (ENG 1 – North) located at Citation’s Pineview Tank Battery and Gas Plant near Coalville in Summit County, Utah. The White Superior 8G825 engine is designated as existing, non-emergency, 4SRB stationary RICE > 500 HP located at an area source of HAP that is not remote and operates more than 24 hours per calendar year. As such, the engine is being tested to demonstrate compliance with the nitrogen (NOx) and carbon monoxide (CO) performance testing requirements of the UDEA approval order (DAQE-AN155130002-22). In addition, the engine is being tested in accordance with the provisions of RICE MACT EPA 40 CFR 63, Subpart ZZZZ (NESHAP ZZZZ). Testing will be conducted to demonstrate compliance with the EPA CO standard of 270 ppmvd @ 15% O2. Page 2 of 2 Source Test Notification & Protocol Submission Pineview Tank Battery & Gas Plant October 12, 2023 14077 Cutten Road ꞏ Houston, TX 77069-2212 ꞏ 281.891.1000 Oasis is scheduled to conduct the performance testing on the White Superior 8G825 engine on Wednesday, December 13, 2023. We expect to complete all testing within one (1) day. As indicated in the permit (DAQE-AN155130002-22), two additional 800 hp White Superior compressor engines (ENG 2 and Recip (South)) are located at this site and are subject to the same State and Federal performance testing requirements. However, both of these engines are currently out of service or are inoperable at this time. Therefore, emission testing for these two engines is not scheduled at this time. If Citation decides to bring these engines back into service, performance testing will be conducted prior to operation. Attached is a Source Test protocol for your review. If you have any questions or require further information, please contact me at (281) 891-1550 or via e-mail at BRedweik@cogc.com Very truly yours, R J Redweik Robert J. Redweik VP – EHS and Regulatory Attachment: Source Test Protocol UDEQ/EPA Source Test Protocol Approval Order: DAQE-AN155130002-22 Unit ID: ENG1 (North) Citation Oil & Gas Corporation Pineview Tank Battery and Gas Plant, Summit County, Utah October 5, 2023 Prepared By: Oasis Emission Consultants, Inc. 2730 Commercial Way Rock Springs, WY 82901 1.0 INTRODUCTION The purpose of this document is to provide relevant information pertaining to proposed periodic source emission testing at Citation Oil & Gas Corporation’s Pineview Tank Battery and Gas Plant (Unit ID: ENG1 (North)), in Summit County, Utah. Emissions testing will be conducted in accordance with the UDEQ DAQ Approval Order # DAQE-AN155130002-22 (Issuance Date: August 15, 2022) and EPA 40 CFR 63, Subpart ZZZZ (NESHAP ZZZZ). Testing will be conducted by Oasis Emission Consultants, Inc. 1.1 Test Program Organization Approval Order: DAQE-AN155130002-22 Federal Regulations: EPA 40 CFR 63, Subpart ZZZZ Pineview Tank Battery and Gas Plant Unit ENG1 (North) is located at an area source of HAP emissions. The engine is being tested according to the requirements of the National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion Engines (NESHAP) – 40 CFR Part 63, Subpart ZZZZ. Facility / Location: Pineview Tank Battery and Gas Plant (Site ID: 15513) The facility is located at 3604 East Chalk Creek Road in Coalville, in Summit County, Utah. UTM Coordinates: 487,342 m Easting, 4,531,757 m Northing, UTM Zone 12 Emission Source(s): Unit ID: ENG1 (North) – White Superior 8G825 One (1) natural gas fired, non-emergency, 4-stroke rich burn (4SRB) White Superior 8G825 stationary reciprocating internal combustion engine (RICE) rated at 800 horsepower (hp). Client Owner / Operator: Citation Oil & Gas Corporation Address: 14077 Cutten Road Houston, TX 77069-2212 Contact: Ron Schultz, Manager Regulatory Compliance Email: RSchultz@cogc.com Office: (281) 891-1559 Test Company: Oasis Emission Consultants, Inc. Address: 2730 Commercial Way Rock Springs, WY 82901 Contact: Chris Knott, P.Eng., Director, Engineering & Operations Phone: (307) 382-3297 Fax: (307) 382-3327 State Authority: Utah Department Of Environmental Quality Address: PO Box 144820 Salt Lake City, UT 84114-4820 Contact: Rik Ombach, Minor Source Compliance Manager Email: rombach@utah.gov Phone: (801) 536-4164 Stack Test Report Submission: https://utahgov.co1.qualtrics.com/jfe/form/SV_3dSxf7JSzy4jwGh EPA Authority: Office of Enforcement, EPA Region VIII Address: 8ENF-AT 1595 Wynkoop Street Denver, CO 80202-1129 Contact: Alexis North, Environmental Scientist Email: north.alexis@epa.gov Phone: (303) 312-7005 Contact: Michael Stovern Email: stovern.michael@epa.gov Phone: (303) 312-6635 R8AirReportEnforcement Region Email: R8AirReportEnforcement@epa.gov 1.2 TEST PROJECT OBJECTIVE(S) The purpose of the emission compliance demonstration is to satisfy the requirements of UDEQ DAQ Approval Order # DAQE-AN155130002-22 (Issuance Date: August 15, 2022) and EPA 40 CFR 63, Subpart ZZZZ. Testing on the engine to show compliance with the UDEQ DAQ Approval Order # DAQE-AN155130002-22 and EPA 40 CFR 63, Subpart ZZZZ will be conducted concurrently. As required by UDEQ DAQ Approval Order # DAQE-AN155130002-22 Conditions II.B.6.c through II.B.6.c.2, three (3) separate one (1) hour test runs will be conducted on the 4SRB 800 hp White Superior 8G825 engine (Unit ID: ENG1 (North)) to demonstrate compliance with nitrogen oxides (NOx) and carbon monoxide (CO) limitations. The test for NOx and CO will be performed using EPA Reference Methods 1-3 and EPA 40 CFR 63 (A), Method 320. Results from the UDEQ DAQ Approval Order # DAQE-AN155130002-22 compliance test will be reported in units of pounds per hour (lb/hr). The White Superior 8G825 stationary RICE is an affected source equipped with a non-selective catalytic reduction (NSCR) convertor located at an area source of HAP emissions. The engine is being tested according to EPA 40 CFR 63, Subpart ZZZZ requirements for engines at an area source that are considered not remote. As stipulated by Table 6 Condition 15 to Subpart ZZZZ of Part 63, testing will be conducted to demonstrate that the average CO concentration for the White Superior 8G825 engine is less than or equal to 270 ppmvd @ 15% O2. The engine will be tested with the FTIR (EPA 40 CFR 63 (A), Method 320) at the outlet for the measurement of CO. 1.3 Facility Description Citation Oil & Gas Corporation (Citation) operates a crude oil and natural gas tank battery and gas plant at the Pineview Facility. At the tank battery, crude oil, natural gas and produced water are processed from an emulsion stream extracted from wells using electric submersible pumps and pumping units. Fluid from the wellheads enters a separator where the oil and water are separated from gas. The separated gas is sent to the adjoining gas plant. The liquids from the separators are routed to crude oil and produced water storage tanks at the lower portion of the tank battery. Emissions from the crude oil storage tanks are controlled by a flare. The crude oil is sent off site via truck loading while the produced water is piped for off-site injection within the field. Gas is routed to the gas plant. This facility will process up to 146,000 barrels (1 barrel = 42 gallons) of crude oil per year. Produced water from the separator is stored on-site at the upper portion of the tank battery before being shipped off-site through a flowline for injection. The gas plant processes up to 532.2 million standard cubic feet of natural gas per year. The gas plant treats the field gas using glycol and a separator to remove any left-over liquids. The gas is then cooled and compressed for storage in bullet tanks before being piped to the sales point for truck loading. The compliance test will be conducted on the 800 hp White Superior 8G825 natural gas fired, rich-burn engine (Unit ID: ENG1 (North)) that drives a compressor. 2.0 SOURCE TEST PROGRAM DESCRIPTION 2.1 Test Contractor All source emission tests will be performed by Oasis Emission Consultants, Inc., based out of Rock Springs and Sheridan, Wyoming. Processed test results and all raw data captured during the tests are forwarded to Chris Knott, P.Eng., Director of Engineering and Operations and/or Charles Chapman, Manager of Technical Services, for quality control and data checking. Once approved, tests are forwarded to the client. 2.2 Test Date The unit will be tested by Oasis Emission Consultants, Inc. on December 13th, 2023. We expect to complete all testing within a one (1) day time frame. 2.3 Report Date The test report will be submitted to Citation Oil & Gas Corporation no later than 60 days following the test. 2.4 Testing Methodology And Procedures A summary of the unit to be tested is provided below. Approval Order # Unit ID Make & Manufacturer Serial Number Engine HP Max Allowable Nitrogen Oxide (NOx) lb/hr Max Allowable Carbon Monoxide (CO) lb/hr DAQE-AN155130002-22 ENG1 (North) White Superior 8G825 270349 800 0.661 1.022 2.4.1 EPA 40 CFR 63, Subpart ZZZZ Unit ID Make & Manufacturer Serial Number Engine HP EPA CO Standard ENG1 (North) White Superior 8G825 270349 800 270 ppmvd @ 15% O2 The White Superior 8G825 engine is an existing non-emergency 4SRB RICE > 500 HP located at an area source of HAP and is operated more than 24 hours per calendar year. Testing will be conducted to demonstrate that the average CO concentration for the White Superior 8G825 engine is less than or equal to 270 ppmvd @ 15% O2. Emission Measurement Methodologies: Testing on the White Superior 8G825 compressor engine (Unit ID: ENG1 (North)) will consist of three one hour tests post catalyst according to EPA 40 CFR 60 (A), Methods 1-3 and EPA 40 CFR 63 (A), Method 320 for NOx and CO. Oxygen levels will be measured to allow for the correction of CO to 15% O2. Based on the compounds that will be measured, the MKS 2030 analyzer has been configured in the following manner, which is intended to cover all types of natural gas fired engines. The MKS 2030 software provides a Natural Gas Method that is designed to minimize all expected interferences by removing the regions in the quant region where they are most absorbed (ie. picket fence approach). So, for example, all the water peaks that are greater than about 0.1 abs are removed from the quant region. Since the spectral noise measured (sample spectrum) is in the range of 0.001 absorbance, it is desirable to have any error within this range. The MKS software will match the water calibration spectrum to the sample spectrum at any 1 point in the spectrum to about 1% precision. So, 1% of 0.1 absorbance is 0.001 abs. This is why any peaks greater than this for interfering compounds are usually excluded so they do not interfere. To summarize, the MKS software and the method are designed to minimize any interferences by removing their largest interfering absorptions. QA spiking procedures will be followed for pre and/or post testing. Various factors often make determining the exact concentrations for spiking procedures indiscernible prior to testing, even if the engine has been previously tested. Furthermore, it is infeasible to obtain and transport a multitude of gas concentrations for varying analytes. Therefore, a mixed gas bottle with a high enough concentration for multiple engines may be utilized during the spiking procedures. A summary of all spiking procedures/results will be provided in the final test reports. The CO2 present in the native sample will be used as the tracer. There are two components that make up the spike: 90% native and 10% spike. Both the native and spike are being added to the gas cell and measured simultaneously. Since the CO2 concentration for most engines is very stable during testing, the reduction in its concentration when a spike is applied can provide very accurate prediction on the ratio of spike gas to engine emission. The schematic for our sampling system, which is the same as the system provided in Method 320, is shown below. The sampling system is used to draw the sample from the stack at an elevated temperature, remove particulates and push the gas through a secondary heated line into the MKS 2030 analyzer to maintain correct pressure and temperature. There is no reduction in water concentration or any other component. Figure 1: Schematic of FTIR Sampling System. The MKS Multigas 2030 FTIR system inherently converts the wet levels of NOx & CO to dry levels and displays the dry levels to the Compliance Specialist(s) via a computer display. The system is able to perform this conversion due to the FTIR also measuring the moisture content of the effluent stream. Therefore, it is the dry levels that are typically logged. Stack Sampling Location The inner exhaust stack diameter for the White Superior 8G825 engine will be measured by the Oasis Emission Consultants, Inc. Compliance Specialist during the compliance test and will be verified to meet the minimum specifications of a sampling location as defined by EPA Method 1. An aerial lift will be utilized, if needed, to conduct sampling. Figure 2: Sample Location Diagram. Engine Operating Parameters: Engine operating parameters, where applicable, will be recorded for each 1 hr test which may include engine rpm, air/fuel ratio setting(s), suction/discharge pressures etc. Engine Load Approximation: Oasis Emission Consultants Inc. will approximate the engine load using the measured process parameters, such as gas throughput, suction/discharge pressure/temperature; by correlating the intake manifold conditions with the engine manufacture heat balance data; or the engine load. It is expected that the engines will be tested at 90%-110% of the site rated load. Catalyst Parameters: Oasis will record the catalyst parameters (i.e. catalyst inlet temperature and the pressure drop across the catalyst) during each test. Test Methods: All test methods that we intend to utilize are listed below.  EPA 40 CFR 60 Appendix A, Method 1: Method 1 requires measurement of the various physical attributes of a stack to establish appropriate sampling locations.  EPA 40 CFR 60 Appendix A, Method 2: Method 2 provides the means to calculate the average wet velocity for the exhaust effluent gas. This method employs the use of a standard or S-type pitot tube, a thermometer and an inclined manometer. The temperature, static & differential pressures are all used to calculate the average wet velocity. This value may be used in conjunction with the known stack diameter, and measured moisture content (Method 4), to approximate the average dry volumetric flow rate.  EPA 40 CFR 60 Appendix A, Method 3: Method 3 provides the means to calculate the dry molecular weight of the effluent gas. After passing through a gas condenser, O2 & CO2 gas concentrations from the effluent stream are measured by a Fyrite analyzer. Measurements will be taken in conjunction with those from Method 2. The dry molecular weight will be calculated for each of the test runs. The O2 levels will also be used for the correction to 15% O2.  EPA 40 CFR 63 (A), Method 320: NOx, CO and H2O concentrations are obtained by running the engine exhaust through a heated sample line (191 deg C) to an MKS 2030 FTIR analyzer. When a gas sample is introduced in the gas cell, the infrared beam is partially absorbed by the gas species present. The spectral frequencies absorbed and their intensity are due to the atoms associated with the chemical bond and the strength of that bond. The absorption spectrum is unique for each infrared-active gas. The MKS FTIR analyzer measures the absorption spectrum, and its analysis algorithm measures the concentration of each gas using pre-loaded calibrations. The MG2000 software allows for the continuous measurement, display and recording of the sample stream. ATTACHMENT C Correspondence 1 Kurt Seeton From:Kurt Seeton Sent:Thursday, October 12, 2023 10:35 AM To:R8AirReportEnforcement@epa.gov Cc:Andrew Moreno Subject:CITATION OIL & GAS CORP. - SOURCE TEST NOTIFICATION AND PROTOCOL SUBMISSION Attachments:2023 10 12- Pineview Tank Battery & Gas Plant Engine Test NOI.pdf US EPA Region 8/Attention: Ms. Alexis North, On behalf of Citation Oil and Gas Corp. (Citation), KRS Environmental Services, LLC (KRS) is submitting the attached Source Test Notification and Protocol Submission for compliance emission testing on one (1) 800 hp White Superior 8G825 engine located at Citation’s Pineview Tank Battery and Gas Plant near Coalville in Summit County, Utah. Testing is scheduled to be completed on December 13, 2023. Note that KRS has been informed that EPA Region 8 is requesting that hardcopies of these reports not be submitted at this time. Therefore, a hardcopy of this report will not be submitted unless requested. If you have any questions or require further information, please contact Mr. Andrew Moreno at (281) 891-1412 or via e-mail at AMoreno@cogc.com. Regards, Kurt Seeton Principal 5816 CR 605 Burleson, TX 76028 (832) 795 - 4336 1 Kurt Seeton From:noreply@qemailserver.com Sent:Thursday, October 12, 2023 10:42 AM To:Kurt Seeton Subject:Stack Test Report for Citation Oil & Gas Corp. Thank you for submitting a Stack Test report. A DAQ Inspector will be in contact with you shortly. Best Regards, Division of Air Quaility, Complaince Branch Recipient Data: Time Finished: 2023-10-12 09:42:13 MDT IP: 156.146.145.219 ResponseID: R_3KJWQxShyluxbWy Link to View Results: Click Here URL to View Results: https://utahgov.iad1.qualtrics.com/apps/single-response- reports/reports/6TgbwdVzeo01RMlmPMbaDcULByv28B1DoDVMxMvApZrH84SNvogToCGzRveBv%2E0nKQXDl1fkDxR4H e84Y2dPFODz%2Ewwk5I8zNPfLHSfhZTTG7FRg2Eh5968Q8IuC%2EWqSKHAcSRgb8u- Jk13w6mZ7DQN8f%2EL7kZcwbQvInzjHZa09CKPaBg3Jpp3ar57Lk8LV--IuBT%2EBxRD77jlsGlaRbcXYTpfy9drN3s- 66jpA05PXAdu0DVvOG6d10P6-bvNClt6c0UmO9Tq1hq5Ftr3d4EE2WIzTS9XuLQUJkOs3BiLdgH6oh2fHot8M-i8mZ5cr Response Summary: Please provide the following: Company Name: Citation Oil & Gas Corp. Site Name(s): Pineview Tank Battery & Gas Plant Contact Name: Kurt Seeton Contact Email Address: Kseeton@krseserv.com Permit ID(s): AN155130002-22 # of Sites: 1 Test Date: 12/13/2023 Please attach a copy of your Stack Test Protocol or Report here: https://utahgov.co1.qualtrics.com/WRQualtricsControlPanel/File.php?F=F_R5g9Q1pYHUfjQzv